P.1 

OAR Box 1672 

Prepped by Charmelle Mathews 

Document Number: 

yti ll-B-3 

Docket Number: 

A-98-13 

Printed 9/30/2008 11:01:00 AM Sheet 10 of 132 
CZ. £____. C__5 

O 

TO: 

FROM: 

MEMORANDUM 

Project File 

Organic Liquids Distribution NESHAP 

ESD Project No. 96/05 

BerndHaneke [(J^ 

Pacific Environmental Services, Inc. 

A 98 13 

11:6-3 

P.2 

DATE: August 12,1998 — _ _ 

SUBJECT: April 24,1998 Site Visit to Ashland Chemical Company, Houston, Texas 

I. Purpose 

The purpose of this site visit was to tour the facility in an effort to educate EPA and 

contractor personnel concerning organic liquids distribution operations and to collect information 

related to air emissions from the operations. This work is in support ofthe development of 

national emission standards for hazardous air pollutants (NESHAP) for the organic liquids 

distribution (non-gasoline) source category. 

II. Location 

Ashland Chemical Company, Division of Ashland Inc. 

8901 Old Galveston Road 

Houston, Texas 77034 

April 24,1998 (12:45 p.m. - 3:30 p.m.) 

III. Participants 

Ashland Chemical Company 

Scott Colonna - Plant Manager 

Richard Wright - Senior Engineer 

U.S. Environmental Protection Agency 

Steve Shedd - Project Officer, OAQPS/ESD/WCPG 

Research Triangle Park, NC 

Pacific Environmental Services. Inc. 

Bernd Haneke - RTP, NC 

Greg LaFlam - RTP, NC 
P.3 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 2 

IV. Pre-Tour Discussion 

EPA Introduction 

After the participants introduced themselves, Steve Shedd, EPA, began the meeting by 

discussing the background ofthe EPA's regulation of hazardous air pollutant (HAP) emissions. 

Prior to the Clean Air Act Amendments of 1990 (CAAA), HAP regulations were risk-based and 

a limited number of regulations were completed. The CAAA included a specific HAP list and 

prescribed that rules be developed for categories of sources (industrial types). The stringency of 

the Organic Liquids Distribution (non-Gasoline) NESHAP for existing sources will be based on 

"floor" levels of control representing the control achieved by the average ofthe best performing 

12 percent of sources in this category. The standards are slated to be proposed in 1999, with 

promulgation of the final rule in November 2000. 

Mr. Shedd mentioned that the EPA has prepared an industry questionnaire and distributed 

it to trade organizations for their review and comment. The questionnaire, when final, will be 

sent to approximately 160 companies in this industry. He also described the EPA's procedures 

for handling information the company considers to be confidential business information (CBI). 

Ashland will have an opportunity to review the draft site visit report prepared by the EPA project 

team, and to comment on its accuracy and identify any CBI. The report with any CBI removed 

will be made a part of the public record for this rulemaking. The representatives of Ashland 

Chemical Company were asked to identify whether any ofthe information in the conversations 

and handouts was confidential. No information during the conversations was noted by the 

Ashland representatives to be confidential. 

Facility Processes 

Ashland Chemical Company is a diversified company that handles a wide variety of 

chemicals in liquid and solid state. The Houston facility warehouses specialty chemicals for 

numerous clients, and it also produces special liquid blends of chemicals. The company 

describes this site as a chemical distribution facility, and as such uses Standard Industry 

Classification (SIC) code 5169, "Chemicals and Allied Products, Not Elsewhere Classified." 

Approximately 80 percent of Ashland's customer base is for chemicals. The Ashland 

representatives estimated that there are 60 to 70 facilities nationwide that are similar to this 

facility. 

Depending upon demand, Ashland Chemical Co. operates on a flexible schedule. It 

usually operates 5 or 7 days per week (presently 5 days at 2 shifts), and 52 weeks per year. The 

hours operated per day will vary with utilization and immediate requirements. Mr. Scott 

Colonna indicated that at present, the facility was operating at approximately 25 percent 

-2-
P.4 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 3 

capacity. Furthermore, Mr. Colonna indicated that the Houston facility employs 32 people. 

Liquids enter the Ashland facility by either railcar, tank truck, or as pre-packaged 

materials. From these entry points, liquids can follow numerous routes. Liquids can either be 

transferred to storage vessels for direct packaging, or they can be directed to blending tanks. 

Following the blending/storage tanks, liquids can then be filled into tank trucks or smaller 

containers, such as 5 gallon containers or totes. Containers up to 55-gallon drum size are splash 

filled. Portable tote tanks are either splash filled or have a built-in lance for submerged filling. 

Totes range in size from 350 gallons (filled to 330 gallons) up to 550 gallons. In the case of 

railcars, liquids can be transferred directly into tank trucks (Attachment 1). 

Ashland can blend products in multiple modes. At the facility, liquids can be blended 

either in 55-gallon drums, various sizes of totes, or in a tank truck itself. No in-line blending is 

performed. Additionally, Ashland operates a 4,000 and an 8,500 gallon blending tank. The 

tanks are mounted side-by-side in a rack and are attached to a scale. Blending in these vessels 

occurs by weight due to its higher degree of accuracy. These tanks have agitators which serve to 

homogenize the blend within the tanks. Mr. Wright informed the EPA project team that Ashland 

also uses nitrogen sparging to homogenize blends within containers, but is moving away from 

this practice due to high levels of emissions. 

The facility has at its disposal 45 vertical storage tanks (Attachment 2) ranging in size 

from 4,000 to 30,500 gallons. Numerous tanks at the facility are equipped with internal floating 

roofs (depending upon the liquid stored), while others are only equipped with fixed roofs. The 

storage tanks are divided into six active tank farms (Tank farms 4A-4F, see Attachment 3). The 

floating roof tanks are inspected visually every 6 month, and every 5 years the primary rim seal 

is inspected through vessel entry. The fixed roof tanks have no controls except conservation 

vents. 

Three tank truck loading positions at two loading racks are available at the facility. The 

racks are located under a large roof, and have truck weighing scales for product filling accuracy 

needs. Trucks are bottom loaded, typically with no vapor balance or vapor collection. However, 

we were told that some customers do request that their vapors be collected at this location. 

Ashland owns 10 of its own tank trucks. The facility can also receive products by rail, and is 

currently receiving jet fuel antifreeze by this mode of transportation. 

The facility operates one solvent drumming area. At this facility, solvents are splash 

loaded into a variety of containers. Containers that are to be filled are placed on a conveyor belt 

to efficiently move them through the filling cycle. Vapors emanating from the filling process are 

captured by a ventilation system which routes the vapors through the roof. 

Ashland Chemical Company also operates three warehouses in which it stores both 

<b 
P.5 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 4 

liquids and bulk solids. In total, the facility has over 49,500 square feet of storage space. 

Included in this storage space are areas dedicated for liquids, solids, cold storage, and United 

States Pharmacopeia (U.S.P.) grade chemicals. 

Throughputs by emissions category for 1997 were: 

Storage Tanks -

Blending Tanks -

Bulk Loading -

Container Filling ~ 

2,264,797 gallons 

277,646 gallons 

1,650,332 gallons 

1,001,153 gallons. 

Mr. Colonna informed the EPA project team that blending constituted approximately 5 to 10 

percent ofthe business at the Houston facility. 

From the emissions information supplied by Mr. Rick Wright, some ofthe major liquids 

moving through the Ashland facility include (Attachment 4): 

Table 1. Principal Liquids Handled in 1997 

Organic Liquid 

Methyl Ethyl Ketone 

Hexane 

Methanol 

Toluene 

Xylene 

Ethyl Benzene 

Glycol Ether EB 

1997 12-Month Throughput 

(gal) 

83,059 

337,605 

470,959 

212,134 

250,263 

179,693 

116,566 

Emissions from Ashland Chemical Company 

Mr. Wright informed the EPA project team that Ashland Chemical Company had made a 

$150,000 investment to develop an emissions tracking software package suitable to its 

operations. The software package, called the Ashland Air Compliance Information System 

(AACIS), tracks emissions monthly by product (Attachment 5), as is necessary for reporting 

emissions to the Texas Natural Resources Conservation Commission (TNRCC). 

u 
P.6 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 5 

From Attachment 5, it is apparent that the Houston facility is an area source, with an 

emissions breakdown as shown in Table 2: 

Table 2. 1997 Emissions from Ashland Chemical Company, Houston, Texas 

Emissions Category 

Storage Tanks 

Blending Tanks 

Bulk Loading 

Container Filling 

Equipment Fugitives 

HAP EMISSIONS TOTAL (lb) 

HAP EMISSIONS TOTAL (tpy) 

12-Month Throughput (gal) 

2,264,797 

277,646 

1,650,332 

1,001,153 

N/A 

N/A 

N/A 

12-Month Emissions (lb) 

2,865.97 

759.22 

1,757.22 

1,497.35 

2,033.56 

8,913.32 

4.46 

In addition to this, the facility emits 8 tons per year (tpy) of volatile organic compounds (VOC). 

Ashland Chemical Company uses AP-42 "Compilation of Air Pollution Emission 

Factors, Chapter 12 - Storage of Organic Liquids" and the Texas Natural Resources 

Commission's "Technical Guidance Package for Chemical Sources - Storage Tanks" to calculate 

emissions from storage vessels and loading operations. 

To calculate fugitive emissions, Ashland Chemical Company uses the synthetic organic 

chemical manufacturing industry (SOCMI) emissions factors. Ashland calculates that it has 

approximately 8 pumps and 200 valves. The rest ofthe equipment contributing to fugitive 

emissions are fittings, flanges, etc. 

Fugitive Emissions Monitoring 

The TNRCC (Attachment 6) prescribes certain procedures for checking and inspecting 

fugitive emissions. To begin with, the TNRCC mandates that operation without visible liquid 

leaks or spills shall be maintained at all loading/unloading facilities, regardless of vapor pressure. 

Furthermore, any liquid spill must be reported to the TNRCC and cleaned up immediately so as 

to minimize air emissions. 

Accessible valves need to be monitored on a quarterly basis by leak-checking for fugitive 

emissions using an approved gas analyzer. Pump and compressor seals need to be monitored at 

least quarterly using a gas analyzer. If leaks are found to be in excess of 10,000 ppmv they must 

5 
P.7 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 6 

be repaired per TNRCC regulations within 15 days after the leak has been identified. Ashland 

personnel informed the EPA project team that leaks are repaired immediately following 

identification/detection. 

Control Measures 

As the Ashland facility has very low emissions, not many control technologies are 

utilized. The most prevalent control technologies utilized at the facility are: 

1. Submerged fill pipes in totes 

2. Internal floating roofs on vertical storage tanks 

3. One scrubber to control corrosive vapors (non-organic) 

Add-on control technologies such as carbon adsorption or thermal oxidation are not utilized at 

the Houston facility. Vapor recovery on tank trucks is also not used at the Houston facility. 

Ashland Chemical Company does use thermal oxidation to control vapors at a similar facility in 

California. 

Wastewater Generation and Treatment 

Ashland Chemical Company does not generate or treat any organic wastewater. Ashland 

does operate a scrubber which it uses to neutralize vapors from the drumming of corrosives. The 

scrubber effluent is discharged to a publicly owned treatment works (POTW) sanitary sewer. 

No permit is required for stormwater discharge, and all stormwater is routed into grassed 

dikes and waterways. At times these are checked for oily sheens, and the facility has the 

capability for sampling stormwater using gas chromatography. 

The facility does not generate any semi-aqueous liquids (i.e., containing between 10-90 

percent solids, or sludge). 

V. Plant Tour 

Following the sit-down discussion, Mr. Wright and Mr. Colonna took the EPA project 

team on a tour ofthe facility. The warehouses, viewed first, contained both bulk dry goods and 

liquids stored by business group. Among the goods stored here were vegetable oil, polyester 

resins, catalysts, and polystyrene pellets. Drums (55 gal) containing U.S.P. grade isopropyl 

alcohol were also observed, as well as numerous drums containing flammable organic liquids. 

At the end of a warehouse, the EPA project team was shown the corrosive drumming area 

(for acid loading) as well as its associated scrubber. Vapors from the loading of acids are 

c 
P.8 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 7 

neutralized in the caustic soda (NaOH) based scrubber. 

Following the corrosives loading area, the railcar unloading facility was observed. At 

this site Ashland was unloading jet fuel antifreeze. From the railcars the antifreeze (glycol ether 

dm) is transferred to tank trucks. The loading/unloading arm used to pump the liquid from the 

rail car, as well as its associated pump, were observed. 

Next to the rail car unloading facility was a warehouse that contained numerous sizes of 

totes. The totes were predominantly manufactured of stainless steel and were either cylindrical 

or cubical. Totes made of polyvinyl chloride (PVC) were also observed on the site. On the top 

ofthe cubical totes two openings were seen, one for filling, and one for venting. Additionally, 

the totes had a discharge valve at the bottom so as to completely evacuate the storage space. Mr. 

Colonna explained to the EPA project team that the totes were pressure tested every 30 months 

as required by the Department of Transportation (DOT). 

Mr. Colonna and Mr. Wright then took the EPA project team to the container/drum filling 

area. At this site drums or other liquid containers could be placed on a conveyor belt and filled 

using nozzles. Vapors emanating from the filling operation were first collected at the filling site 

and subsequently vented to the atmosphere by a blower. 

Next to the container filling facility the two blending tanks were observed. Mounted on a 

steel structure, the two tanks were attached to a weight measuring scale to permit precise 

blending of chemicals. Mr. Colonna described to the EPA project team how agitators, mounted 

on the roofs ofthe blending tanks, are used to homogenize the blends. 

Close to the blending vessels two 500 gallon molecular sieves were observed that served 

to produce dry liquids (i.e., containing no water). The molecular sieves have a desiccant bed that 

removes water from ethyl benzene and odorless mineral spirits. 

Following the molecular sieves, the EPA project team was led to the tank truck loading 

area. The loading racks with two truck spots were seen, as well as the scales that permit the 

liquids to be filled with greater accuracy than volume meters. The loading racks were not 

equipped with any vapor recovery mechanisms. Pumps, valves, and hoses associated with the 

loading rack were explained to the team. 

The tank farms were subsequently scrutinized by the EPA project team. The fixed roof 

tanks, as well as the internal floating roof tanks were examined and discussed. Explosion hazard 

due to lightning strikes with tanks storing methanol was discussed, as well as ways to prevent 

this by using internal floating roofs. 

Located near the tank farms was the firewater pond, which was briefly observed and 

n 
P.9 

Site Visit Memo/Ashland Chemical Co. 

August 12,1998 

Page 8 

discussed, as well as a building with cold storage capabilities. 

Empty tank trucks were also seen that were capable of having vapor recovery. Numerous 

tank trucks were scrutinized and discussed. From conversations with the Ashland representatives 

it became apparent that Ashland was not using the vapor recovery features on its tank trucks. 

VI. Post Tour Discussion 

A brief post-tour discussion was held in which the EPA project team requested copies of 

the air emissions inventory and TNRCC operating permit. Photocopies ofthe documents were 

made and distributed to the project team. Following this, the EPA project team thanked the 

Ashland personnel and the tour was concluded. 

VII. Action Items 

The EPA project team informed the Ashland representatives that it would be preparing a 

memorandum for its review and comment. No further action items were identified at this time. 

% 
P.10 

ATTACHMENT 1 
Organic Liquids 

Figure 3-1 

Process Flow Diagram 

••..A*:.. 

o 

Glycol Ether DM 

• 

Truck 

Loading 

TR-2 

Inbound 

Rail Car 

Ethyl benzene 

H 

Inbound 

Truck 

TR-1 

Prepackaged 

Materials 

-> Customer 

Includes tanks 

2,3,806 6-38. 

Storage 

Tank 

Blend 

Tank 

Includes tanks 

S,101.and 102. 

Truck 

Loading 

TR-1 

Includes alI 

container f111ing 

actlvlties. 

Container 

Filling 

TOTE-I 

-> Customer 

-> Warehouse or Customer 

Inorganic (Corrosive) Liquids 

J*.^**^' ; 

Inbound 

Truck 

TR-3 

Tanks 40-43 

Storage 

Tank 

' ' 

Container 

Fl11Ing 

CORR-1 

Contrc 

scrub! 

>l led 

jer. 

. 

by a 

—T 

Truck 

Loading 

TR-3 

Warehouse or Customer 

» 
P.12 

ATTACHMENT 2 

U 
P.13 

• 

TANK * 

WEST 

1 

2 

3 

4 

5 

6 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 

EAST 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

38 

CAPACITY 

GALS 

4000 

6000 

7100 

12900 

21300 

21300 

16400 

21300 

- 20100 

20100 

30500 

30500 

30500 

30500 • 

30500 

30500 

12000 

12000 

12000 

12000 

12000 

12000 

15000 

15000 

15000 

15000 

15000 

15000 

15000 

15000 

PRODUCT 

' 

GLYCOL ETHER DB 

DEiSEL 

• 

BLEND TANK 

METHYLENE CHLORIDE 

METHYL ETHYL KETONE 

n-BUTYL ACETATE 

HEXANE 

METHANOL 

ISOPROPANOL -' 

EMPTY 

TOLUENE 

XYLENE 

ACETONE 

ETHYLBENZENE 

OMS 

GUN CLEANER 

HI SOL 10 

GLYCOL ETHER PM 

METHYL tvAMYL KETONE 

METHYL ISOBUTYL KETONE 

TEXANOL ESTER ALCOHOL 

DIOCTYL PHTHALATE(DOP) 

ETHYLENE GLYCOL 

GLYCOL ETHER EB 

MINERAL SPIRITS 66 

REGULAR MINERAL SPIRITS 

SOLVENT 140-66 

VM&P NAPTHA 

n-BUTANOL 

KWIK DRI66 

I 

75% 

GALS 

3000 

4500 

0 

5325 

9875 

15975 

15975 

14550 

15975 

15075 

15075 

22875 

22875 

22875 

22875 

•22875 

322875 

9000 

9000 

9000 

9000 

9000 

9000 

11250 

11250 

11250 

11250 

11250 

11250-

11250 

1'250 

J75% 

FEET 

10*5" 

11*11-1/2" 

0 

16*5-1/2" 

22*6" 

2_T8" 

22*5-1/2" 

221T 

23*3-1/4" 

23*3-1/4" 

2T-1/4" 

27-1/4" 

27-1/4" 

27-1/4" 

27-1/4" 

27-V4" 

AoSEMONT OR STRAP? 

QUANTITY 

\1&\ _ 

<2t2-

aapd 

5^3 . 

\3S^ _ 

-n^nL 

s??<43. 

• 

29 it 

aaio_ 

s&TO 

. (t^loHQsrto 

9.°L4 

4235-

M?4 

49fcA 

V3€G>.._ 

2141 _ 

' ttoS 

3S1L 

(eCo^fr 

\3£srm 

3^05 " 

-3<fc>-

k?3& 

J?S(ol 

Qd±-

— A . 

• 
ATTACHMENTS 

13 
o 

§ 

o 00 CM 

9 in 

D O X 

KEY AREA PLAN 

SCALE. NONE 

nrNrRAi mTC 

PROPERTY LINES HAVE BEEN TRANSFERRED FROI THE 

ORIGINAL PLOT PLAN AND HAVE BEEN CONFIRMED AGAINST 

THC PROPERTY LEGAL DESCRIPTION 

ANY RELATIONSHIP BETWEEN PLOTTED PROPERTY LINES 

AND PLANT PHYSICAL FACILITIES CAN KIT BE GUARANTEED 

WITHCJT A CLOSED PROPERTY SURVEY. 

STORAGE TANK 

HEIGHTS 

TANK! 

1 

a 

3 

4 

3 

6 

7 

8 

9 10 11 12 13 14 13 16 17 18 19 20 21 22 23 24 23 26 27 28 29 30 31 32 33 34 33 36 37 38 40 41 42 43 44 

101 

102 

HEIGHT 

»FT> 

14.00 

1300 

16X0 

16X0 

12X0 

22.00 

22X0 

2200 

22X0 

22X0 

2200 

22X0 

30X0 

30X0 

30X0 

30X0 

31.00 

31X0 

36X0 

36X0 

36X0 

36X0 

36X0 

36X0 

21-58 

2L38 

21.98 

21.38 

21.38 

21.38 

24.33 

24.33 

24.33 34 33 

24.33 

2433 

243 3 

24.33 

33.00 

33X0 

33X0 

3300 

33X0 

13J7 

1067 

PERMIT ADMENMENT R-54 7 

Woodward-Clyde Consultants 

Engineer-ng ti sciences applied to 

the earth it its environment 

Houston. Texos 

ASHLAND CHEMICAL COMPANY 

HOUSTON FACILITY 

SOLE: 

NOTED 

UAOE BY:PR. 

CHECKED BY. 

0A IE: 01/23/96 

DATE: 

FILE N a 

95T228 

HOUSTON TERMINAL PLOT PLAN 

FIGURE 

2 - 2 

\H 
P.16 

ATTACHMENT 4 

\5 
-6"^ 

Hazardous Air Pollutant Throughput Data 

Ashland Chemical Company 

Houston, TX Facility 

Calendar Year 1997 

Product Code 

3001440 

3001450 

3001650 

3001950 

3002420 

3002430 

3002500 

3002930 

3002990 

3020656 

3060000 

3070000 

3071000 

3110250 

3210000 

3220000 

3310000 

3353000 

3365000 

3370000 

3370008 

3405900 

3405942 

3540000 

3590000 

3600500 

3620000 

3639200 

3639220 

3752000 

3752200 

3753000 

3931140 

3968496 

3968520 

3970000 

7020840 

7021000 

7030400 

7030550 

7030800 

7138011 

7350000 

7430000 

7440363 

Product Description 

Hi Sol 10 

Hi Sol 15 

Toluene 

Xylene - mixed isomers 

rvHexane 

Hexasol 

Lacofene 

VM&P Naphtha High Initial 

VM&P Naphtha 

ARDRIL2957 

Glycol Ether DB 

Glycol Ether EB 

Glycol Ether EB Acetate 

Glycol Ether DE-LG 

Dibutyl Phthalate 

Diethanolamine 99% 

Dioctyl Phthalate 

Ethylbenzene 99% 

Ethylene Dichloride 

Ethylene Glycol 

Ethylene Glycol Polyester Grade 

Glycol Ether EP 

Glycol Ether DM Fuel Additive 

Methyl Ethyl Ketone 

Methylene Chloride 

Glycol Ether DM Fuel Additive 

Methyl Isobutyl Ketone 

Muriatic Add 20 degree Baume 

Muriatic Acid 22 degree Baume 

Perchloroethylene 

Perchkxoethvtene Reforming Grade 

Perchtoroethylene Ruorocarbon Grade 

Styrene Monomer 

1.1.1-Trichloroethane Dioxane Free 

1,1.1-Trichloroethane 

Trtchkxoethylene 

AmbitnUCN 

Antifreeze 

Ethanol Spec Ind Anvd 4082 

Ethanol Spec Ind Anyd 4135 

Ethanol Spec Ind 190 Proof 4085 

Ethanol SDA 23H190 Proof 

Methanol 

Ethanol Proprietary 190 Proof 3224 

Houston Gun Cleaner 

% HAP (by weight) 

10 

10 

100 

100 

100 

35 

7 

10.9 

10 

2 

100 

100 

100 

100 

100 

99 

100 

99 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

95 

94 

5.2 

9.8 

5.4 

1.4 

100 

5.5 

59.4 

Blend Usage 

14.049 

1.785 

53.187 

47.120 

77.406 

. 

8.970 

. 

15.462 

5.057 

. 

960 

63 

. 

5 

. 

. 

. 

. 

1 

. 

2.253 

. 

25.299 

7.803 

. 

7.371 

. 

. 

74 

. 

. 

. 

. 

. 

. 

1.197 

. 

. 

1.961 

. 

. 

7.340 

. 

48.583 

Drum Filling 

43.580 

12,210 

41.887 

23.608 

12.149 

. 

3.214 

9.258 

18.037 

. 

13.964 

41.168 

. 

5.231 

9.467 

945 

9.263 

8.220 

1.010 

25.838 

4.306 

5.441 

56.1 SB 

30.581 

25.416 

55.887 

5.542 

64.632 

44.537 

4.884 

104 

3.106 

67.017 

2.960 

3.030 

6.703 

. 

1.045 

540 

4.212 

648 

14.685 

169.830 

15.336 

935 

Portable Tank Filling 

6.915 

. 

12.559 

3,735 

. 

. 

3.077 

. 

. 

. 

10.294 

17.481 

. 

. 

. 

7.108 

. 

. 

. 

2,282 

. 

. 

. 

20,420 

4,105 

. 

. 

12.818 

. 

. 

2.341 

. 

2.798 

. 

. 

. 

. 

. 

. 

. 

. 

. 

10,184 

. 

-

Small Container Filling 

188 

490 

19 

3.753 

. 

. 

3.546 

• 

50 

. 

10 

202 

-

. 

. 

. 

. 

. 

. 

4 

-

49 

-

1,274 

391 

816 

14 

. 

. 

. 

-

. 

290 

228 

24 

10 

. 

. 

. 

10 

. 

. 

70 

10 

-

Bulk Loading 

200,346 

8,227 

160.151 

175.652 

262.921 

2.739 

7.829 

12.282 

5.787 

. 

1.620 

64.853 

. 

. 

. 

. 

12.272 

161,125 

-

11.485 

-

4,208 

22.976 

12,730 

19,959 

245,214 

8.104 

4.992 

. 

3.358 

689 

. 

. -

. 

• 

3,251 

• 

. 

-

2.690 

. 

• 

287,310 

11,035 

18,650 

Purchases 

269,950 

18,345 

249,663 

250,269 

337.610 

7,593 

7,829 

21.852 

27,073 

5,057 

20.818 

130,144 

. 

5,415 

9,419 

9,109 

21,644 

179,699 

1,098 

39,693 

4.967 

7.713 

68.021 

92,014 

42.373 

266.662 

22.911 

76.243 

45.140 

7.835 

1.508 

3.029 

67.857 

3.122 

3.129 

10.469 

1.197 

1.099 

544 

4.745 

704 

14.977 

478.543 

15.642 

-

Comments 

Xylene. Cumene 

Naphthalene 

n-Hexane 

Toluene 

Xylene. Ethylbenzene 

Xylene. Ethylbenzene 

Diethanolamine 

Diethylene Glycol Monobutyl Ether 

Ethylene Glycol Monobutyl Ether 

Ethylene Glycol Monobutyl Ether Acetate 

Diethylene Glycol Monoetnyl Ether 

Di-.2-ethvlhexvl. Phthalate 

Ethylene Glycol Monopropyl Ether 

Diethylene Glycol Monomethyl Ether 

Diethylene Glycol Monomethyl Ether 

Hydrochloric Add 

Hydrochloric Add 

Ethylene Glycol 

Ethylene Glycol 

Methanol, Methyl Isobutyl Ketone 

Methanol. Methyl Isobutyl Ketone 

Methanol. Methyl Isobutyl Ketone 

Methyl Isobutyl Ketone. Methanol 

Methanol. Methyl Isobutyl Ketone 

Toluene. Methyl Ethyl Ketone. Methanol, Xylene 

Note: Ail throughput data is In gallons. 

Pagel 
G3R591-1 ASHLAND CHEMICAL COMPANY DATE: 

PAGE 1 THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE TIME: 

WHSE: 28 Old Galveston Road Warehouse FROM 01/01/97 TO 12/31/97 

This Report Is To Be Given To The PLANT MANAGER. 

All Quantities Are In GALLONS Unless Specified To The Right Of The Column BULK SHIP QUANTITY. 

PRODUCT DESCRIPTION 

2001960 ADVASOL 150 

2008000 CYCLOHEXANE 

2024600 PANASOL AN-2K 

2200058 A 8000 D 

2200078 A 8000 E 

2206010 ALKOTE RETARDER 

2206330 VT 4 BLEND 

2207065 CSD R 7 K 69 

2209467 BROCH STEINS H G 

2215800 BLEND 7362 

2227081 B 8669 

_ ^ 2239936 PIPING TECH THINNER 

2240647 CB 191 

224064 9 SEMAC SOLVENT A 1 

2265522 LACQUER THINNER G 

2269348 CB 116 

2286959 TYPE WASH M (REV) 

2286966 GYRO 1 FORMULA WT 

2287005 QUALITY POT WASH 

4/14/98 

6:24 AM 

BLEND 

LACQUER TH 

BLEND 

QUANTITY 

21 

0 

550 

993 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

FILL 

DRUMS 

4,400 

9,515 

6,435 

1,540 

330 

0 

12,760 

0 

1,705 

110 

1,430 

770 

495 

2,805 

4,675 

0 

55 

0 

55 

QUANTITY 

TOTES SMALL 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

CC 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

4 

9 

8 

427 

711 

954 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

BULK SHIP 

QUANTITY 

0 

0 

0 

0 

0 

2,241 

0 

2,000 

0 

3 

0 

0 

0 

0 

0 

1,255 

0 

2,970 

0 
-4 

G3R591-1 

PAGE 2 

WHSE: 28 

PRODUCT 

2287011 

2299229 

2299230 

2308162 

2308979 

2311281 

2311311 

2311709 

2311719 

2313477 

2317352 

2317492 

2317692 

2318312 

2319212 

2319982 

2320784 

2321593 

2324652 

2357544 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse FROM 01/01/97 TO 12/31/97 

DESCRIPTION 

BHT TOLUENE BLEND 

ACME WASH 104 A 

CSD PREMIUM 103 

THINNER 28056 

R 7 K 58 SW 

RETARDER G 

SEMAC SOLVENT A 

SUTTON BLEND 2 

SUTTON BLEND 1 

ACROTHANE REDUCER 255 C 157 

DTL 10 B 

EXPOXY REDUCER 

AMSCO SOLV A 

HERMIES BLEND 5610 

THINNER 27309 (REV) 

GOOSENECK JULY A 

E 100 BLANKET & ROLLER WA 

GYROS 1 FORMULA 

SW 1 LACQUER THINNER (REV) 

6-75-498 

BLEND 

QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

2,020 

0 

0 

0 

0 

0 

0 

0 

DRUMS 

1.320 

0 

0 

330 

165 

1,100 

330 

0 

0 

0 

0 

0 

0 

55 

220 

0 

0 

935 

3,300 

2,200 

FILL QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 * 

0 

0 

0 

SMALL CC 

0 

900 

0 

0 

5,125 

0 

0 

0 

0 

20 

260 

610 

0 

0 

0 

0 

0 

0 

2,425 

0 

DATE: 4/14/98 

TIME: 6:24 AM 

PURCHASE BULK SHIP 

QUANTITY QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

8,508 

536 

0 

0 

0 

0 

990 

1,003 

0 

0 

0 

2,024 

0 

0 

5,960 

997 

4.730 

0 

0 
G3R591-1 

PAGE 3 

WHSE: 28 

PRODUCT 

2364090 

2371705 

2376037 

2488000 

2524000 

2592050 

2699510 

2703397 

2703994 

2703999 

2704008 

2704009 

2704012 

^_ 2704026 

— £ > 2704031 

2704039 

2704353 

2704517 

2704814 

2705357 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Old Galveston Road Warehouse 

DESCRIPTION 

SPRAY GUN CLEANER 

1007 BLEND 

33 THINNER 1 

KEROSENE 

MINERAL SEAL OIL 

RETARD SOLVENT 2 

WHITE MINERAL OIL 70 TECHNICAL 

PSC 1287 

SUBSTITUTE 529 REV 

SOLVENT 20253 A 

AMSCO SOLV A (REV) 

CSD TT T 306 E TYPE II (REV) 

NAGEL ROLLER WASH (REV) 

GYRO 5 REVISED WT 

PSC 1299 

ETHYL KEROSENE 

FOSTER MS BLEND 

602 ENAMEL REDUCER REVISED 

MINERAL SPIRITS 66 MAACO 

BB 2895 

FROM 01/01/9 7 TO 12/31/9 7 

BLEND 

QUANTITY 

0 

0 

0 

6,953 

0 

22,069 

77 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

990 

FILL 

DRUMS 

3 

8 

4 

,025 

0 

0 

,360 

0 

990 

0 

275 

,320 

0 

0 

0 

220 

0 

0 

0 

0 

55 

0 

0 

QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

3,032 

961 

0 

0 

0 

0 

0 

651 

0 

0 

0 

0 

0 

SMALL CC 

0 

505 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

10 

3 

13 

0 

0 

0 

645 

140 

932 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

BULK SHIP 

QUANTITY 

0 

3,882 

299 

749 

500 

8 

0 

0 

0 

29,978 

2,003 

991 

0 

2,970 

0 

20,196 

1,040 

0 

15,037 

0 
G3R591-1 ASHLAND CHEMICAL COMPANY 

PAGE 4 THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

WHSE: 28 Old Galveston Road Warehouse 

O 

PRODUCT DESCRIPTION 

2706085 GOOSENECK JULY B 

2706216 601 ENAMEL REDUCER REVISED 

2707205 AUTOWASH 2500. SEE PC 27 

2707646 CG 44 SEE PC 270 

2708114 DTR 600 (015) 

2708566 MS RULE 66 S 100 

2784359 BLEND 7717 

2788180 CCC 100 SOLVENT 

2788197 LOCKO SPECIAL BLEND B 1 REV (0 

2852011 INSCO CLEANER SOLVENT S 

2857045 USS 25 B 

2858098 JAX BLEND 103 

2858391 LOCKO SPECIAL BLEND B 1 REV 

2870167 SUPER VM&P NAPHTHA (028) 

2883100 SOLVENT BLEND 9 

2883254 NAGEL ROLLER WASH 

2891392 SOLVENT 20253 

2897902 WAX & GREASE REMOVER 33 0 A 

2898142 THINNER 21121 A 

2899533 PRINTER SERVICE T 20REVISEDSSE 

FROM 01/01/97 TO 12/31/97 

FILL QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

0 

' 0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

BLEND 

QUANTITY 

0 

0 

6,698 

385 

0 

0 

0 

615 

0 

2,627 

0 

0 

770 

0 

0 

275 

24,358 

0 

106 

1,653 

DRUMS 

0 

385 

0 

0 

0 

0 

0 

0 

880 

0 

165 

0 

0 

770 

0 

0 

0 

534 

0 

0 

SMALL CC 

0 

0 

0 

0 

180 

0 

0 

140 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

DATE: 4/14/98 

TIME: 6:24 AM 

PURCHASE BULK SHIP 

QUANTITY QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

3.77S 

0 

0 

0 

0 

2,006 

10,853 

0 

0 

2,627 

1 

4,903 

0 

0 

84,958 

0 

24,358 

0 

0 

0 
FROM 01/01/97 TO 12/31/97 

^ 

G3R591-1 ASHLAND CHEMICAL COMPANY 

PAGE 5 THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

WHSE: 28 Old Galveston Road Warehouse 

PRODUCT DESCRIPTION 

2913670 STX 104 

2922710 STX 150 

2927696 TT T 306 CA TYPE II 

3001061 SURE SOL 202 

3001440 HI SOL 10 

3001450 HI SOL 15 

3001850 TOLUENE 

3001950 XYLENE 

3002155 CONOSOL C-200 

3002400 HEPTANE 

3002420 HEXANE 

3002430 HEXASOL 

3002485 KWIK DRI 66 

3002490 KWIK DRI NONEXEMPT 

3002500 LACOLENE 

3002530 MINERAL SPIRITS 

3002550 MINERAL SPIRITS 66 

3002553 MINERAL SPIRITS 200 HT 

3002555 MINERAL SPIRITS 4% 

3002600 MINERAL SPIRITS 

DATE: 4/14/98 

TIME: 6:24 AM 

AROMATIC 

SOLVENT 

NONEXEMPT 

HT 

AROMATICS 

ODORLESS 

BLEND 

QUANTITY 

0 

0 

0 

0 

14,049 

1,785 

53,187 

47,120 

0 

425 

77,406 

0 

2,919 

216 . 

8,970 

20,258 

564 

9,021 

1,914 

35,915 

FILL 

DRUMS 

0 

0 

0 

2,196 

43,580 

12,210 

41,887 

23,608 

5,720 

8,088 

12,149 

0 

8,135 

0 

3,214 

18,027 

49,966 

4,888 

0 

28,045 

QUANTITY 

TOTES 

6 

12 

3 

3 

0 

0 

0 

0 

915 

0 

559 

735 

0 

0 

0 

0 

0 

0 

077 

0 

943 

0 

0 

641 

SMALL CC 

0 

0 

0 

0 

188 

490 

19 

3,753 

0 

14 

0 

0 

0 

0 

0 

3,546 

0 

0 

0 

25 

PURCHASE 

QUANTITY 

0 

0 

0 

2,235 

269,950 

18,345 

249,663 

250,269 

6,726 

28,919 

337,610 

7,593 

18,642 

0 

7,829 

90,336 

77,196 

15,923 

3,500 

451,100 

BULK SHIP 

QUANTITY 

2,985 

513 

2,180 

0 

200,346 

8,227 

160,151 

175,652 

925 

21,827 

262,921 

2,739 

21,634 

0 

0 

62,308 

34,041 

5,796 

0 

407,314 
^ 

^ 

G3R591-1 

PAGE 6 

WHSE: 28 

PRODUCT 

3002755 

3002820 

300283-0 

3002890 

3002930 

3002945 

3002990 

3003543 

3010000 

3010001 

3012351 

3013069 

3013070 

3013080 

3013088 

3015732 

3018712 

3020000 

3020656 

3020666 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Old Galveston Road Warehouse 

DESCRIPTION 

MINERAL SPIRITS 

SOLVENT 140 

SOLVENT 14 0-66 

SOLVENT 14 0 3% 

VM&P NAPHTHA HI 

VM&P NAPHTHA W 66 

VM&P NAPHTHA 

IBEX 115 

ACETONE 

ACETONE ACS 

AMBITROL 40-60 

LIFE GUARD 1600-B 

ACETIC ACID 84% 

ACETIC ACID 99.5% 

IP GT A 415 BLEND A 

ALKAMIDE WRS-166 

MEA 85% LOW GRAVITY 

AMYL ACETATE PRIMARY 

ARDRIL 2957 

ARTRAD 1194 

FROM 01/01/97 TO 12/31/97 

135 EC (SH 

NONEXEMPT 

AROMATICS 

INITIAL N 

BLEND 

QUANTITY 

9,856 

0 

133 

20,702 

0 

34,230 

15,462 

0 

36,187 

0 

0 

0 

0 

0 

0 

3,032 

0 

0 

5,057 

0 

FILL 

DRUMS 

5,016 

28,118 

4,458 

60,632 

9,258 

19,253 

18,037 

0 

126,771 

1,354 

0 

1,052 

25,173 

5,646 

0 

0 

0 

18,216 

0 

329 

QUANTITY 

TOTES 

1 

1 

9 

11 

058 

0 

0 

0 

0 

0 

0 

910 

298 

0 

0 

0 

0 

0 

0 

0 

021 

0 

0 

0 

SMALL CC 

0 

0 

0 

0 

0 

75 

50 

0 

115 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

8,548 

29,315 

3,533 

153,963 

21,852 

92,694 

27,073 

0 

256,570 

1,462 

0 

0 

24,040 

5,709 

0 

0 

0 

18,680 

2,891 

0 

BULK SHIP 

QUANTITY 

0 

0 

4,976 

69,190 

12,282 

28,002 

5,787 

71,879 

82,724 

0 

2,993 

43,395 

0 

O 

37,108 

0 

705 

0 

0 

0 
G3R591-1 

PAGE 7 

WHSE: 28 

PRODUCT 

3020667 

3024863 

3060000 

3060320 

3070000 

3071000 

3090130 

3090314 

3090495 

3090501 

3090509 

3090510 

3090528 

3091010 

3095862 

3095973 

3110250 

3120010 

3120020 

3135010 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Old Galveston Road Warehouse 

DESCRIPTION 

ARZOLINE 215 

BENZYL ALCOHOL TECH GRADE 

GLYCOL ETHER DB 

BUTYL BENZYL PHTHALATE 

GLYCOL ETHER EB 

GLYCOL ETHER EB ACETATE 

BUTYROLACTONE 

WET SOL A 

IBEX XTRA ESW REVISED 

LIFE GUARD 1700 

FOSTER MINERAL SPIRITS 2 

LUBE B XM 

PC 1000 

CITRIC ACID LIQ 40% USE PC 392-

CALAMIDE CW-100 

BUTYLATED HYDROXY TOLUENE F 

GLYCOL ETHER DE-LG 

POLYETHYLENE GLYCOL 200 

POLYETHYLENE GLYCOL 400 

CASTOR OIL IND. GRADE #1 

FROM 01/01/97 TO 12/31/97 

BLEND 

QUANTITY 

7,230 

0 

0 

0 

960 

63 

0 

0 

0 

0 

0 

0 

0 

0 

0 

3,231 

0 

0 

0 

0 

FILL 

DRUMS 

0 

5,108 

13,964 

12,634 

41,168 

110 

2,860 

0 

80,000 

165 

0 

0 

54 

0 

54 

0 

5,231 

0 

0 

0 

QUANTITY 

TOTES 

10 

17, 

2 

0 

0 

294 

0 

481 

0 

0 

0 

0 

0 

0 

0 

0 

0 

473 

0 

0 

0 

0 

0 

SMALL CC 

0 

0 

10 

0 

202 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

.0 

8 

0 

5 

PURCHASE 

QUANTITY 

6 

5 

20 

14 

130 

2 

2 

s 

850 

183 

818 

898 

144 

0 

930 

0 

0 

0 

0 

0 

0 

947 

545 

0 

415 

0 

0 

0 

BULK SHIP 

QUANTITY 

0 

6,892 

1,620 

9,414 

64,853 

0 

24 

54,222 

0 

0 

9,006 

17,510 

0 

0 

43 

0 

5 

0 

36 

0 
G3R591-1 ASHLAND CHEMICAL COMPANY 

PAGE 8 THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

WHSE: 28 Old Galveston Road Warehouse 

DATE: 4/14/98 

TIME: 6:24 AM 

FROM 01/01/97 TO 12/31/97 

PRODUCT DESCRIPTION 

3140000 CAUSTIC POTASH 45% LIQUID 

3149824 IBEX 8588 (REVISED) 

3150000 CAUSTIC SODA LIQUID 50% 

3150050 CAUSTIC SODA LIQUID 50% RAYON 

3197183 11-3071 PV FAST YELLOW HG 

3200000 CYCLOHEXANONE 

3201200 CYCLOHEXYLAMINE TECH 

3201870 D-LIMONENE 

3210000 DIBUTYL PHTHALATE 

3220000 DIETHANOLAMINE 99% 

3228000 DIBASIC ESTER 1 

3255000 DIACETONE ALCOHOL 

3260700 DIETHYL ETHANOLAMINE 

3270000 DIETHYLENE GLYCOL 

3275300 DIISOPROPANOLAMINE 99% 

3275320 DIISOPROPANOLAMINE 85% LOW F 

3298000 DIPROPYLENE GLYCOL FRAGRANCE 

3300510 IPA 55-57% 

3300589 DRAKEOL 35 TECH 

3300590 DRAKEOL 5 TECH 

BLEND 

QUANTITY 

0 

0 

0 

0 

0 

328 

0 

36,976 

5 

0 

0 

300 

0 

0 

0 

0 

0 

0 

0 

0 

FILL 

DRUMS 

29,876 

0 

27,945 

65,460 

0 

45,204 

4,062 

33,582 

9,467 

945 

14,550 

386 

6,466 

23,458 

2,970 

0 

10,407 

6,328 

10,150 

1,486 

QUANTITY 

TOTES 

5,577 

0 

1,203 

7,944 

0 

0 

20,925 

0 

0 

7,108 

1,042 

0 

0 

0 

0 

0 

0 

0 

0 

0 

SMALL CC 

0 

0 

0 

0 

0 

24 

0 

25 

0 

0 

4 

4 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

36,719 

0 

38,640 

65,668 

2 

52,105 

23,966 

50,277 

9,419 

9,109 

15,917 

501 

6,646 

24,070 

3,047 

1,259 

10,610 

0 

10,485 

1,530 

BULK SHIP 

QUANTITY 

0 

39,565 

32,331 

586 

0 

10,213 

0 

4,014 

0 

49 

1 

0 

0 

6 

0 

1,259 

0 

36 

0 

1 
G3R591-1 

PAGE 9 

WHSE: 28 

N 

Vr\ 

PRODUCT 

3300900 

3310000 

3311061 

3311202 

3320489 

3320491 

3321050 

3330000 

3331000 

3345000 

3353000 

3365000 

3370000 

3370008 

3375000 

3380000 

3381160 

3386084 

3400219 

3404000 

FROM 01/01/97 TO 12/31/97 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DESCRIPTION 

DODECYLBBNZENE 

DIOCTYL PHTHALATE 

DC SILICONE 200FL 

DC ANTIFOAM H-10 

EMPHOS PS-220 

EMPHOS PS-400 

EPAL 1418 

ETHYL ACETATE 85-88% 

ETHYL ACETATE 99.5% 

ETHYL ACETATE 99% 

ETHYLBENZENE 99% 

ETHYLENE DICHLORIDE 

ETHYLENE GLYCOL 

ETHYLENE GLYCOL POLYI 

ESTER SOLVENT EEP 

ETHYLHEXANOL-2 

EXXATE 1000 

FERRIC SULFATE S0% 

IBEX XTRA ESW 

GLYCERINE 99.5% TECH 

DATE: 4/14/98 

TIME: 6:24 AM 

SULFONIC 

1000 VIS 

EMULSION 

URETHANE 

STER GRAD 

SOLUTION 

BLEND 

QUANTITY 

1,216 

0 

55 

518 

1,915 

2,061 

0 

1,212 

525 

0 

0 

0 

1 

0 

1,345 

0 

0 

0 

0 

0 

FILL 

DRUMS 

18,906 

9,263 

0 

0 

0 

0 

16,271 

1,525 

7,976 

54 

8,220 

977 

25,838 

4,306 

5,334 

3,651 

0 

0 

28,617 

0 

QUANTITY 

TOTES SMALL 

10 

15 

2 

595 

0 

0 

0 

0 

0 

0 

0 

712 

0 

0 

0 

282 

0 

0 

0 

0 

0 

0 

299 

CC 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

4 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

25,609 

21,644 

0 

0 

0 

0 

16,368 

1,711 

17,506 

0 

179,699 

1,098 

39,693 

4,967 

6,447 

3,700 

0 

320 

0 

0 

BULK SHIP 

QUANTITY 

S8 

12,272 

0 

0 

14 

51 

0 

0 

267 

1 

161,125 

33 

11,485 

0 

1,218 

57 

33 

0 

20 

0 
G3R591-1 

PAGE 10 

WHSE: 28 

PRODUCT 

3405092 

3405104 

3405110 

3405120 

3405900 

3405914 

3405942 

3405950 

3455000 

3455080 

3455405 

3455680 

3458500 

K} 3459700 

O * 3460000 

3461712 

3473017 

3473049 

3473090 

3474155 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Old Galveston Road Warehouse 

DESCRIPTION 

GLYCERINE, NATURAL 99.7% USP 

GLYCERINE, SYNTHETIC 99.7% TEC 

GLYCERINE, SYNTHETIC 99.7% USP 

GLYCERINE, NATURAL 99.5% USP 

GLYCOL ETHER;EP 

GLYCOL ETHER DPNP 

GLYCOL ETHER DM FUEL ADDITIVE 

GLYCOL ETHER TB 

CHELATING LIQUID 100 

CHELATING LIQUID 80 

CHELATING LIQUID 120 

HEPTYL ACETATE 

HEXANOL, NORMAL 

HEXYL ACETATE MIXED ISOMERS 

HEXYLENE GLYCOL 

ETHYLS BLEND DC 

HYDROGEN PEROXIDE 35% TECH 

HYSTRENE 3675 

HYDROGEN PEROXIDE 50% 500# 

HOGWASH US (T) 

FROM 01/01/9 7 TO 12/31/9 7 

QUANTITY 

0 

0 

0 

0 

2,253 

781 

0 

0 

0 

0 

0 

9 

0 

16 

0 

0 

0 

0 

0 

0 

DRUMS 

0 

0 

216 

0 

5,441 

0 

56,158 

76,572 

9,378 

3,908 

3,705 

0 

0 

0 

21,405 

440 

0 

0 

0 

0 

UANTIT. 

TOTES 

2,310 

0 

624 

1,194 

0 

0 

0 

0 

4,380 

0 

0 

0 

0 

0 

2,797 

0 

0 

0 

0 

0 

SMALL CC 

10 

0 

0 

0 

49 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

0 

0 

541 

0 

7,713 

0 

68,021 

76,796 

14,234 

3,952 

3,668 

0 

0 

0 

25,285 

0 

1,013 

0 

500 

0 

BULK SHIP 

QUANTITY 

4 

22 

3 

0 

23 

0 

0 

,208 

0 

,976 

0 

,472 

0 

0 

0 

0 

0 

14 

0 

0 

51 

0 

99 
vi 

G3R591-1 

PAGE 11 

WHSE: 28 

PRODUCT 

3479405 

3479410 

3479480 

3479500 

3479600 

3479700 

3490000 

3495000 

3499000 

3500000 

3504712 

3507000 

3514758 

3522505 

3530000 

3540000 

3587100 

3590000 

3600500 

3620000 

FROM 01/01/97 TO 12/31/97 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DESCRIPTION 

IGEPAL CA-620 

IGEPAL CA-630 

IGEPAL RC-520 

IGEPAL CO-430 

IGEPAL CO-530 

IGEPAL CO-630 

ISOBUTYL ACETATE 

ISOBUTANOL 

ISOBUTYL ISOBUTYRATE 

ISOPROPYL ACETATE 

ISOPROPYL ALCOHOL 92 % 

ISOPROPANOL 99% 

LEXEIN X-250 

METHYL NORMAL AMYL KETONE 

MONOETHANOLAMINE 99% 

METHYL ETHYL KETONE 

METHYL NORMAL PROPYL KETONE 

METHYLENE CHLORIDE INDUSTRIA 

GLYCOL ETHER DM FUEL ADDITIVE 

METHYL ISOBUTYL KETONE 

DATE: 4/14/98 

TIME: 6:24 AM 

BLEND 

QUANTITY 

3 

3 

832 

211 

4,637 

1,110 

825 

314 

521 

4,169 

46,335 

110,100 

0 

5,726 

16,481 

25,299 

0 

7,803 

0 

7,371 

------- FILL 

DRUMS 

0 

0 

0 

0 

53 

107 

1,802 

21,874 

1,422 

4,118 

919 

36,525 

540 

13,097 

13,873 

30,581 

0 

25,416 

55,887 

5,542 

QUANTITY 

TOTES 

10 

20 

4 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

320 

0 

0 

332 

420 

0 

105 

0 

0 

SMALL CC 

0 

0 

0 

0 

14 

0 

0 

0 

0 

0 

0 

140 

0 

235 

5 

1,274 

0 

391 

"816 

14 

PURCHASE 

QUANTITY 

0 

0 

0 

0 

0 

0 

1,517 

22,345 

1,694 

8,409 

49,826 

174,503 

0 

79,320 

25,033 

92,014 

985 

42,373 

266,662 

22,911 

BULK SHIP 

QUANTITY 

25 

56, 

12 

19. 

245, 

8, 

5 

0 

0 

0 

0 

0 

0 

2 

0 

0 

0 

541 

0 

005 

63 

730 

976 

959 

214 

104 
^ 

oQ 

G3R591-1 

PAGE 12 

WHSE: 28 

PRODUCT 

3621149 

3635000 

3635700 

3635720 

3639200 

3639220 

3670000 

3670100 

3680000 

3690000 

3700000 

3748172 

3748611 

3749050 

3752000 

3752200 

3753000 

3785020 

3785040 

3801524 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DATE: 4/14/98 

TIME: 6:24 AM 

DESCRIPTION 

MIRAMINE TO 

MORPHOLINE 99% TECH 

METHYL-N 2-PYRROLIDONE 

METHYL-N 2-PYRROLID 

MURIATIC ACID 20 DEGREE 

MURIATIC ACID 22 DEGREE 

BUTYL ACETATE NORMAL 98% 

BUTYL ACETATE NORMAL U G 

BUTANOL NORMAL 

PROPYL ACETATE NORMAL 

PROPANOL, NORMAL 

PARAPOL 2500 

ANTAROX 17R2 

PENTANOL-1 

PERCHLOROETHYLENE HI-STABIL 

PERCHLOROETHYLENE REFORMING 

PERCHLOROETHYLENE FLUOROCAR 

PHOSPHORIC ACID 75% TECH 

PHOSPHORIC ACID 85% TECH 

POLYGLYCOL EP-530 

FROM 01/01/97 TO 12/31/97 

BLEND F I L L QUANTITY 

QUANTITY 

719 

14 

559 

112 

0 

0 

0 

906 

6,314 

2 

4,532 

0 

5,444 

0 

74 

0 

0 

0 

0 

11,451 

DRUMS 

0 

35,873 

8,030 

2,200 

64,632 

44,537 

5,524 

2,829 

2,881 

12,901 

6,782 

263 

0 

0 

4,884 

104 

3,106 

30,126 

10,797 

6,361 

TOTES 

0 

25,576 

0 

0 

12,818 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

2,341 

0 

4,188 

39,363 

0 

SMALL CC 

0 

10 

0 

5 

0 

0 

0 

0 

80 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

0 

53,177 

8,288 

3,430 

76,243 

45,140 

5,586 

3,428 

58,299 

9,769 

11,527 

0 

0 

0 

7,835 

1,508 

3,029 

33,262 

45,899 

15,676 

BULK SHIP 

QUANTITY 

0 

1 

0 

0 

4,992 

0 

0 

1 

50,262 

0 

0 

0 

0 

0 

3,358 

689 

0 

385 

1,955 

0 
G3R591-1 

PAGE 13 

WHSE: 28 

PRODUCT 

3845025 

3854980 

3855100 

3888000 

3900000 

3903000 

3903005 

3912404 

3920000 

3920253 

3921789 

3928705 

3928980 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DATE: 4/14/98 

TIME: 6:24 AM 

FROM 01/01/97 TO 12/31/97 

V ^ 3929012 

3929030 

3929230 

3929790 

3929808 

3931140 

3932500 

DESCRIPTION 

POLYGLYCOL 112-2 

POLYPROPYLENE GLYCOL 2000 

POLYPROPYLENE GLYCOL 4000 

PRIMARY AMYL ALCOHOL 

PROPYLENE GLYCOL INDUSTRIA 

PROPYLENE GLYCOL USP 

PROPYLENE GLYCOL USP KOSHER GR 

LIFE GUARD 3000 

BUTYL ALCOHOL SECONDARY 

XTRA LUBE B 

SODIUM CITRATE SOLUTION 

SODIUM SILICATE 44 DEGREE 

SODIUM XYLENE SULFONATE 

SODIUM SILICATE 40 DEGREE CLE 

SODIUM SILICATE 42 DEGREE 

SODIUM THIOSULFATE 30% TECH 

SOYBEAN OIL, REFINED BLEACHED 

SOYBEAN OIL, REFINED & BLEACHE 

STYRENE MONOMER 50 PPM INHIB 

SULFURIC ACID LP 

BLEND 

QUANTITY 

11,205 

0 

59,516 

0 

27 

17 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

111,943 

0 

0 

FILL 

DRUMS 

9,953 

11,306 

16,290 

10,051 

11,888 

166 

0 

8,322 

6,569 

0 

0 

494 

4,509 

3,909 

955 

0 

0 

21,847 

67,017 

7,807 

QUANTITY 

TOTES 

5 

7 

2 

4 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

307 

633 

0 

0 

0 

030 

798 

410 

SMALL CC 

0 

0 

0 

0 

0 

0 

0 

0 

25 

0 

0 

0 

0 

0 

0 

0 

0 

0 

290 

0 

PURCHASE 

QUANTITY 

17,349 

11,779 

70,677 

10,120 

12,500 

0 

-552 

0 

6,744 

0 

2,905 

496 

6,904 

8,134 

1,005 

367 

42 

113,533 

67,857 

6,671 

BULK SHIP 

QUANTITY 

24 

66 

3 

0 

0 

0 

0 

111 

0 

0 

,561 

2 

,521 

• 0 

0 

0 

1 

0 

0 

0 

0 

0 

,593 
o 

G3R591-1 

PAGE 14 

WHSE: 28 

PRODUCT 

3934100 

3934350 

3955100 

3955150 

3961303 

3965100 

3965110 

3965382 

3965392 

3965400 

3966500 

3968496 

3968520 

3970000 

3980000 

3989160 

3989300 

3989320. 

3990334 

3992000 

FROM 01/01/97 TO 12/31/97 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DESCRIPTION 

SULFURIC ACID 66 DEGREE 

SULFURIC ACID 98% 

TRIETHANOLAMINE 99% 

TRIETHANOLAMINE 99% LOW FREEZE 

SURFACTANT N 095 M 

TERGITOL NP-9 

TERGITOL NP-9.5 

TERPENE EX 

TETRAETHYLENE GLYCOL 

TETRAHYDROFURAN 

TEXANOL ESTER ALCOHOL 

TRICHLOROETHANE 111 W/O DIOXA 

TRICHLOROETHANE 111 INDUSTRIA 

TRICHLOROETHYLENE DEGREASE 

TRIETHYLENE GLYCOL 

GLYCOL ETHER DPM 

GLYCOL ETHER PM 

GLYCOL ETHER PM ACETATE 

DIAMOND SCI 1 

VINYL TOLUENE 50 T 

DATE: 4/14/98 

TIME: 6:24 AM 

BLEND 

QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1,015 

11,545 

1,936 

0 

0 

FILL 

DRUMS 

18,370 

61,237 

9,089 

1,585 

4,241 

28,039 

14,534 

0 

4,553 

0 

7,176 

2,920 

3,030 

6,703 

51,976 

13,532 

8,037 

8,807 

162 

66,406 

QUANTITY 

TOTES 

2 

3 

2 

10 

736 

718 

0 

0 

281 

581 

524 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

686 

SMALL CC 

0 

0 

0 

0 

0 

0 

0 

5 

0 

0 

0 

228 

24 

10 

0 

19 

0 

262 

0 

0 

PURCHASE 

QUANTITY 

19,015 

63,817 

9,223 

1,659 

10,360 

34,590 

24,342 

1 

4,595 

994 

96,771 

3,122 

3,129 

10,469 

49,207 

12,838 

31,297 

14,257 

0 

69,289 

BULK SHIP 

QUANTITY 

0 

561 

1 

0 

4,793 

8,676 

12,015 

54 

0 

0 

86,412 

40 

0 

3,251 

1,655 

858 

11,150 

8,559 

5 

2,086 
^p 

G3R591-1 

PAGE 15 

WHSE: 28 

PRODUCT 

3992172 

3992178 

7020838 

7020840 

7020843 

7021000 

7030400 

7030550 

7030800 

7126500 

7127910 

7130000 

7130280 

7138000 

7138011 

7160270 

7160298 

7350000 

7396000 

7419180 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Old Galveston Road Warehouse 

DESCRIPTION 

WITCONATE 60T 

WITCAMIDE 511 

AMBITROL FL 4 0 

AMBITROL CN 

AMBITROL NTF 

ANTIFREEZE PERMANENT BULK 

ETHANOL SPEC IND ANHY 4082 

ETHANOL SPEC IND ANHY 4135 

ETHANOL SPEC IND 190P 4085 

WATER DEIONIZED 

AMBITROL NTC 

WATER DISTILLED 

INK SOLVENT PM 6193/ DUP FLUID 

ETHANOL SDA 2-B 200 PROOF 

ETHANOL SDA 23H MOD 190 PROOF 

ETHANOL SDA 40-B 200 PROOF 

ETHANOL SDA 3C 200 PROOF 

METHANOL 

OCTANE, NORMAL 

SODIUM HYPOCHLORITE 10% SOLUT 

FROM .01/01/97 TO 12/31/97 

BLEND 

QUANTITY 

25 

18,120 

0 

1,197 

0 

0 

0 

1,961 

0 

119,309 

0 

7,566 

0 

0 

0 

0 

196 

7,340 

0 

0 

DRUMS 

0 

0 

0 

0 

0 

1,045 

540 

4,212 

648 

0 

495 

0 

220 

2,200 

14,685 

22,275 

0 

169,830 

5,775 

0 

FILL QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

10,184 

0 

0 

SMALL CC 

0 

0 

0 

0 

0 

0 

0 

10 

0 

0 

0 

0 

0 

0 

0 

0 

0 

70 

0 

0 

PURCHASE 

QUANTITY 

0 

0 

5,963 

1,194 

1,993 

1,099 

544 

4,745 

704 

20,485 

500 

0 

0 

2,203 

14,977 

20,615 

0 

478,543 

5,760 

22,194 

BULK SHIP 

QUANTITY 

0 

0 

7,687 

0 

1,982 

13S 

0 

2,690 

0 

0 

0 

0 

0 

0 

0 

0 

0 

287,310 

16 

0 
G3R591-1 

PAGE 16 

WHSE: 28 

PRODUCT 

7430000 

7440363 

7490093 

7500586 

7500817 

7500963 

7501123 

7501143 

7501285 

7501367 

7502274 

7502299 

O O 7502301 

7502302 

7502303 

7502304 

7502418 

7502440 

7502487 

7502488 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

DATE: 4/14/98 

TIME: 6:24 AM 

Y

3 

Old Galveston Road Warehouse 

DESCRIPTION 

ETHANOL PROPRIETARY 190P 3224 

HOUSTON GUN CLEANER KK 028-11 

ETHANOL SDA 40-2 190 PROOF 

AMERCOAT 8 CSD A 

BRINER 85 

ALVIN PAINT STRIPPER 

REACTIVE REDUCER 1185 A 

URETHANE REDUCER 870 A 

WS 9142 H REV 

OPTICAL COUPLING FLUID 

DIAMOND SCI 2 

URETHANE REDUCER 885 A (REV) 

LACQUER THINNER 250 C 089 (REV 

URETHANE REDUCER 870 A (REV) 

CSD 7 T 35 R (REV) 

CSD K 120 (REV) 

ICE*BREAKER (TM) 3 03 

METHANOL 99% & WATER 

R C LACQUER THINNER 1 

C&W BLEND 15 (NEW AGE 80) 

FROM 01/01/97 TO 12/31/97 

BLEND 

QUANTITY 

0 

48,583 

0 

0 

0 

0 

0 

525 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

FILL 

DRUMS 

15 

5 

1 

,336 

935 

810 

0 

0 

330 

660 

60 

165 

0 

990 

,210 

0 

330 

0 

0 

55 

,650 

0 

385 

QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

SMALL CC 

10 

0 

0 

0 

0 

0 

0 

0 

0 

0 

5 

45 

140 

5 

0 

0 

0 

0 

0 

0 

PURCHASE 

QUANTITY 

15 642 

0 

853 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

BULK SHIP 

QUANTITY 

11,035 

18,650 

0 

2,525 

1,000 

47 

0 

0 

0 

2 

48 

0 

0 

0 

6,642 

2,000 

0 

0 

1 

0 
G3R591-1 

PAGE 17 

WHSE: 28 

PRODUCT 

7502496 

7502497 

7502525 

7502733 

7505074 

7507345 

7508045 

7510245 

7523036 

7530918 

7531194 

7539000 

{jO 7552600 

\^ 7644121 

7651110 

7651147 

7652078 

7652419 

7652868 

7676667 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DESCRIPTION 

MEDIUM HAPS BLEND 

SLOW HAPS BLEND 

IMS XYLAN A 

CSD 12X 3LT 

CONTINENTAL CLEANER 

CSD 7 T 35 R 

CSD 6096 A3 

T 501 A 

50/50 ANTIFREEZE DI W 

DIAMOND SCI 1 REVISED 

HURST 15 MB COND (A) 

BLENTECH 1 

C 152 

CSD 6096 A 2 

CB 34 

SHERWIN WILLIAMS R 7 K 54 (A) 

T 81772 TYPE 2 

COOPER SOLVENT 1 

EX 45-55 

ICE*BREAKER (TM) 3 05 

FROM 01/01/97 TO 12/31/97 

BLEND 

QUANTITY 

0 

0 

0 

0 

0 

8,231 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

DRUMS 

3, 

3 

3( 

55 

55 

220 

0 

605 

0 

0 

55 

0 

110 

0 

0 

,905 

0 

,520 

,795 

0 

55 

0 

110 

FILL QUANTITY 

TOTES 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

SMALL CC 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

2,710 

0 

0 

0 

0 

DATE: 4/14/98 

TIME: 6:24 AM 

PURCHASE BULK SHIP 

QUANTITY QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

4,088 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

5,109 

0 

8,231 

2,400 

0 

4,088 

5 

498 

23,796 

0 

697 

203 

0 

1,937 

0 

9,997 

0 
^ 

G3R591-1 

PAGE 18 

WHSE: 28 

PRODUCT 

7678766 

7690177 

7691110 

7725522 

7728400 

7834233 

7834383 

7841320 

7875118 

7875730 

7875789 

7876646 

7887252 

7887762 

7892772 

7892782 

7892943 

7894503 

7895653 

7896712 

ASHLAND CHEMICAL COMPANY 

THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE 

Old Galveston Road Warehouse 

DESCRIPTION 

FOSROC SLIP OFF 

FAST WASH 

75-25 BLEND PP 

BROCHSTEINS RETARDER 

INDUSTRIAL METAL FINISHERS 

FAST BASE MAKER A 

URETHANE REDUCER 885 A 

STX 106 C 

RUSSELL STANLEY BLEND 

THINNER 5 

RM BLEND 

CSD 116 E RUBBER REJUVENATOR 

THINNER 27975 

THINNER 29136 ' 

THINNER 1 L (REV) 

URETHANE REDUCER 1170 

US 1660 

WET SOL 

LACQUER THINNER 250 C 089 

ASPT 1 

FROM 01/01/97 TO 12/31/97 

BLEND 

QUANTITY 

0 

0 

0 

0 

0 

0 

654 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

120 

0 

DRUMS 

2 

1 

6 

0 

,255 

55 

165 

55 

165 

0 

0 

0 

,210 

330 

0 

795 

150 

,314 

720 

0 

0 

0 

0 

FILL QUANTITY 

TOTES SMALL CC 

DATE: 4/14/98 

TIME: 6:24 AM 

PURCHASE BULK SHIP 

QUANTITY QUANTITY 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1,004 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

5 

5 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

265 

0 

0 

0 

0 

0 

0 

1 

16,317 

0 

0 

17,948 

0 

0 

0 

0 

6,546 

111,820 

0 

29,726 
G3R591-1 ASHLAND CHEMICAL COMPANY DATE: 4/14/98 

PAGE 19 THROUGH-PLANT USAGE & PURCHASES FOR WAREHOUSE TIME: 6:24 AM 

WHSE: 28 Old Galveston Road Warehouse FROM 01/01/97 TO 12/31/97 

BLEND FILL QUANTITY PURCHASE BULK SHIP 

PRODUCT DESCRIPTION QUANTITY DRUMS TOTES SMALL CC QUANTITY QUANTITY 

7926001 TYPE WASH M 55 0 0 0 0 0 

* * * NORMA L EO J ** * 
Ashland Chemical Company Rolling 12-Month Blending Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dec/97 April 14, 1998 

Page 3 of 5 

102 

102 

7350000 Methanol 

3540000 Methyl Ethyl Ketone 

2 

0 

0 

0 

0 

1 

0 

1 

0 

1 

2.47 

2.68 

6~^ 102 3752000 Perchlorocthylcnc Hi 

STVPDG 

1.64 

3,425 

9,019 

24 

Tank 

ID 

102 

102 

102 

Product 

Code Name 

3001440 Hi Sol 10 

3001450 Hi Sol 15 

3002500 Lacolcnc 

Jan/97 

0 

0 

0 

Feh/97 

0 

0 

0 

Mar/97 

0 

0 

0 

Apr/97 

0 

0 

0 

Monthly Emissions (lbs) 

May/97 

0 

0 

0 

Jun/97 

0 

0 

0 

Jul/97 

0 

0 

0 

Aue/97 

0 

0 

0 

Sep/97 

0 

0 

0 

Oct/97 

0 

0 

0 

Nov/97 

0 

0 

0 

Dec/97 

0 

0 

0 

Avg Emis 

Factor 

(lbs/Kgal) 

0.11 

0.02 

1.45 

12-Month 

TPut 

(gaD 

451 

83 

206 

12-Month 

Emissions 

Gbs) 

0.05 

0.00 

0.30 

8.45 

24.20 

102 

102 

3620000 Methyl Isobutyl Ketone 

3590000 Methylene Chloride 

0 

0 

0 

0 

0 

7 

0 

4 

0 

3 

0 

0 

0 

14 

0 

0 

0 

8 

0 

7 

0 

10 

0 

0 

0.62 

24.15 

2,371 

2,194 

1.46 

52.98 

0.04 

102 3002860 Super Lacolenc 

102 3001850 Toluene 

102 3002990 VM&P Naphtha 

102 3001950 Xylene 

Tank 102 Subtotals: 

5 7020840 AmbitrolCN 

5 3020656 ARDR1L2957 

5 3370000 Ethylene Glycol 

0 

1 

0 

0 

7 

0 

0 

0 

0 

1 

0 

0 

9 

0 

0 

0 

0 

1 

0 

0 

14 

0 

0 

0 

0 

1 

0 

0 

11 

0 

0 

0 

0 

1 

0 

0 

15 

0 

0 

0 

0 

2 

0 

0 

15 

0 

0 

0 

0 

3 

0 

1 

31' 

0 

0 

0 

0 

2 

0 

1 

16 

0 

0 

0 

0 

3 

0 

I 

30 

0 

0 

0 

0 

2 

0 

0 

27 

0 

0 

0 

0 

2 

0 

0 

22 

0 

0 

0 

0 

2 

0 

0 

15 

0 

0 

0 

1.10 

0.97 

0.53 

0.32 

0.00 

0.00 

0.00 

2 

20,940 

470 

14,256 

77,186 

412 

174 

787 

0.00 

20.40 

0.2S 

4.63 

211.34 

0.00 

0.00 

0.00 
Ashland Chemical Company Rolling 12-Month Blending Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 April 14, 1998 

Page 4 of 5 

Monthly Emissions (lbs) Avg Emis 12-Month 12-Month 

Tank 

ID 

5 

5 

Product 

Code Name 

3070000 Glycol Ether EB 

3071000 Glycol Ether EB 

Acetate 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 

0 0 0 0 0 

0 0 0 0 0 

Jun/97 Jul/97 Aug/97 

0 0 0 

0 0 0 

Sep/97 

0 

0 

Oct/97 Nov/97 Dec/97 

0 0 0 

0 0 0 

Factor 

(Ibs/Kgal) 

0.16 

0.01 

irui 

(gal) 

305 

10 

emissions 

(lbs) 

0.05 

0.00 

3405900 Glycol Ether EP 0.07 

3002420 Hexane 13 16 4.41 

3002430 Hexasol 3.65 

3540000 Methyl Ethyl Ketone 2.44 

3620000 Methyl Isobutyl Ketone 0.54 

271 

11-590 

2,832 

921 

0.02 

51.12 

0.03 

5 

:0

 5 

_a s 

5 

3001440 Hi Sol 10 

3001450 Hi Sol 15 

3002500 Lacolcnc 

7350000 Methanol 

0 

0 

0 

3 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

. o 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0.09 

0.02 

1.41 

1.86 

152 

43 

94 

2,430 

0.01 

0.00 

0.13 

4.52 

6.91 

0.50 

5 

5 

5 

5 

5 

5 

3590000 Methylene Chloride 

3752000 Pcrchloroethylene Hi 

STVPDG 

3002860 Super Lacolcne 

3001850 Toluene 

3002990 VM&P Naphtha 

3001950 Xylene 

0 

0 

0 

1 

0 

0 

0 

0 

0 

1 

0 

0 

12 

0 

0 

2 

0 

0 

7 

0 

0 

1 

0 

1 

6 

0 

0 

2 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

23.45 

(N/A) 

1.30 

0.91 

0.49 

0.28 

1,101 

0 

3 

8,360 

352 

6,607 

25.82 

0.00 

0.00 

7.64 

0.17 

1.86 
Ashland Chemical Company Rolling 12-Month Blending Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

Tank Product 

ID Code Name 

Tank S Subtotals: 

12 Months Ending: Dcc/97 April 14,1998 

Page 5 of 5 

Monthly Emissions Gbs) Avg Emis 12-Month 12-Month 

Factor TPut Emissions 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 Dec/97 (lbs/Kgal) (gal) (lbs) 

12 16 25 20 27 0 36,451 98.80 

HAP Totals for Period Ending 12/97: 32 43 68 55 75 47 96 50 94 84 68 47 277,646 759.22 

Total Blending Tank HAP Emissions (tons): 0.38 

^>0 
Ashland Chemical Company Rolling 12-Month Container Filling HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code 

7021000 

3020656 

3968520 

Name 

Antifreeze 

ARDRIL 2957 

Chlorothcne SM Solvent 

Average Submerged Filling: 100% 

Monthly Emissions (lbs) 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jiui/97 Jul/97 Aug/97 Sep/97 Oct/97 Nov/97 

0 0 0 0 0 0 0 0 0 0 0 

0 0 0 0 0 0 0 0 0 0 0 

0000000 9 12 7 0 

Drum 

100% 

0% 

Dcc/97 

0 

0 

0 

Cont 

100% 

0% 

Avg Emis 

Factor 

(lbs/Kgal) 

0.00 

0.00 

9.22 

April 17, 1998 

Page 1 of 3 

12-Month 

TPut 

(gal) 

930 

480 

3,053 

12-Month 

Emissions 

(lbs) 

0.00 

0.00 

28.15 

3210000 Dibulyl Plilhalalc 

3220000 Diethanolamine 

0 0 

0 0 

0 

0 

0 

0 

0 

0 

0.00 

0 0.00 

7430000 Ethanol P M pr 3224 1.40 

7138011 Ethanol SDA 23H MOD 190 

Proof 

1.44 

3353000 Ethylbenzene 0.54 

3365000 Ethylene Dichloride 4.31 

9,464 

8,052 

859 

206 

8,214 

977 

0.0(1 

0.00 

3310000 

A 7418029 

—P* 7030800 

Dioctyl Phthalate 

Ethanol 3A200PF 

Ethanol 4085 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0.00 

1.82 

1.44 

9,257 

73 

35 

0.00 

0.13 

0.05 

1.21 

0.30 

4.41 

4.21 

3370000 

3370008 

3060000 

3110250 

3600500 

Ethylene Glycol 

Ethylene Glycol Polyester Gr 

Glycol Ether DB 

Glycol Ether DE 

Glycol Ether DM Fuel Ad Gd 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

1 

0 

0.00 

0.00 

0.00 

0.75 

0.01 

28,120 

4,304 

24,265 

5,230 

56,700 

0.07 

0.01 

0.03 

3.90 

0.68 
Ashland Chemical Company 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code 

3405942 

3070000 

3071000 

3405900 

3405950 

Name 

GLYCOL ETHER DM 

FUEL ADDITIVE 

Glycol Ether EB 

Glycol Ether EB Acetate 

Glycol Ether EP 

Glycol Ether TB 

Jan/97 

0 

1 

0 

0 

0 

12 Months Ending: 

Fcb/97 

0 

0 

0 

0 

0 

Mar/97 

0 

2 

0 

0 

0 

Dcc/97 

Apr/97 

0 

1 

0 

0 

0 

Rolling 12-Month Container Filling 

Average Splash Filling: 

Average Submerged Filling: 

Monthly Emissions (lbs) 

May/97 

0 

1 

0 

0 

0 

Jun/97 

0 

4 

0 

0 

0 

Jul/97 

0 

2 

0 

0 

0 

Aue/97 

0 

1 

0 

0 

0 

Tote 

0% 

100% 

Sep/97 Oct/97 Nov/97 

0 

1 

0 

0 

0 

0 0 

0 2 

0 0 

0 0 

0 0 

Drum 

100% 

0% 

Dec/97 

0 

1 

0 

0 

0 

Cont 

100% 

0% 

Avg Emis 

Factor 

0bs/Kga0 

0.01 

0.27 

0.02 

0.12 

0.00 

HAP Emissions 

April 17, 1998 

Page 2 of 3 

12-Month 

TPut 

(gaO 

56,157 

59,456 

175 

5,582 

76,568 

12-Month 

Emissions 

(lbs) 

0.81 

15.92 

0.00 

0.67 

0.03 

3002420 

.x; 

3002500 

7350000 

Hexane 12 21 16 16 7.22 12,600 

3002430 Hexasol 6.05 36 

Lacolene 

Methanol 67 14 27 

0 

11 

1.94 783 

39 128 17 11 17 23 2.01 182,429 

90.96 

0.22 

3001440 

3001450 

Hi Sol 10 

Hi Sol 15 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0.12 

0.05 

5,331 

1,272 

0.63 

0.06 

1.52 

366.56 

3540000 

3620000 

3590000 

3639200 

3639220 

3753000 

Methyl Etliyl Ketone 

Methyl Isobutyl Ketone 

Methylene Chloride 

Muriatic Acid 

Muriatic Acid 22* 

Pcrchloroethylcne Freon 

8 

0 

26 

0 

0 

0 

9 

0 

71 

1 

0 

4 

7 

0 

2 

13 

7 

0 

10 

0 

42 

1 

15 

0 

13 

2 

80 

3 

0 

0 

21 

1 

2 

0 

0 

0 

21 

3 

15 

3 

0 

0 

22 

0 

13 

3 

0 

0 

12 

0 

68 

8 

0 

0 

22 

0 

87 

3 

0 

0 

19 

0 

29 

13 

0 

0 

16 

1 

87 

4 

10 

0 

2.87 

0.92 

17.20 

0.62 

0.70 

1.39 

62,101 

9,995 

30,272 

82,435 

44,535 

3,105 

178.06 

9.20 

520.73 

50.96 

31.33 

4.31 
Ashland Chemical Company Rolling 12-Month Container Filling HAP Emissions 

Facility ID: 028 12 Months Ending: Dcc/97 Tote 

Average Splash Filling: 0% 

Drum 

100% 

Cont 

100% April 17, 1998 

Facility Name: Houston, TX 

Product 

Code Name 

Average Submerged Filling: 100% 

Monthly Emissions (lbs) 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 

0% 0% 

Avg Emis 

factor 

Dec/97 (lbs/Kgal) 

12-Month 

TPut 

(gal) 

Page 3 of 3 

12-Month 

Emissions 

(lbs) 

3752000 Perchloroethylene Hi 

STVPDG 

1.62 

3752200 Perchloroethylene Reforming 0.67 

4,956 

2,445 

8.02 

1.64 

3931140 

3002860 

3001850 

3970000 

3002990 

3001950 

Styrene Monomer 50 IN 

Super Lacolene 

Toluene 

Trichloroethylene 

VM&P Naphtha 

Xylene 

1 

0 

2 

4 

1 

1 

2 

0 

4 

0 

0 

1 

0 

0 

7 

5 

0 

1 

1 

0 

9 

2 

0 

2 

0 

0 

13 

5 

0 

1 

2 

0 

7 

0 

0 

2 

5 

0 

9 

0 

0 

1 

3 

0 

13 

0 

0 

1 

1 

0 

8 

8 

0 

1 

4 

0 

8 

0 

0 

2 

2 

0 

9 

2 

0 

3 

2 

0 

9 

6 

0 

2 

0.34 

1.64 

1.22 

4.78 

0.68 

0.41 

70,099 

10 

80,359 

6,711 

2,015 

41,508 

23.61 

0.02 

98.34 

32.05 

1.37 

17.19 

HAP Totals for Period Ending 12/97: 115 107 82 95 130 102 201 93 148 146 101 178 1,001,153 1,497.35 

Total Container Filling HAP Emissions (tons): 0.75 
Ashland Chemical Company Rolling 12-Month Bulk Loading HAP Emissions 

7430000 Ethanol P M pr 3224 0.59 618 

3353000 Ethylbenzene 0.22 161,120 

3365000 Ethylene Dichloridc 1.78 33 

3370000 Ethylene Glycol 0.00 16,138 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code 

7020840 

7021000 

3210000 

3220000 

3310000 

Name 

Ambitrol CN 

Antifreeze 

Dibutyl Phthalate 

Diethanolamine 

Dioctyl Phthalate 

Jan/97 

0 

0 

0 

0 

0 

12 Months Ending: 

Feb/97 

0 

0 

0 

0 

0 

Mar/97 

0 

0 

0 

0 

0 

Dec/97 

Apr/97 

0 

0 

0 

0 

0 

Average Splash Filling: 

Average Submerged Filling: 

Monthly Emissions (lbs) 

May/97 

0 

0 

0 

0 

0 

Jun/97 

0 

0 

0 

0 

0 

Jul/97 

0 

0 

0 

0 

0 

Aug/97 

0 

0 

0 

0 

0 

Sep/97 

0 

0 

0 

0 

0 

Bulk 

0% 

100% 

Ocl/97 Nov/97 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

Dec/97 

0 

0 

0 

0 

0 

Avg Emis 

Factor 

(lbs/Kgal) 

0.00 

0.00 

4.30 

0.00 

0.00 

April 17 

Page 

12-Month 

TPut 

(gal) 

1,137 

80 

4 

49 

12,270 

12-1 

Emi 

1998 

lof 2 

Month 

issions 

(lbs) 

0.00 

0.00 

0.02 

0.00 

0.00 

0.36 

35.42 

0.06 

0.01 

3060000 

3110250 

3600500 

3405942 

3070000 

3405900 

3002420 

3002430 

3001440 

Glycol Ether DB 

Glycol Ether DE 

Glycol Ether DM Fuel Ad Gd 

GLYCOL ETHER DM 

FUEL ADDITIVE 

Glycol Ether EB 

Glycol Ether EP 

Hexane 

Hexasol 

Hi Sol 10 

0 

0 

0 

0 

0 

0 

74 

0 

0 

0 

0 

0 

0 

0 

0 

69 

0 

0 

0 

0 

0 

0 

1 

0 

64 

0 

0 

0 

0 

0 

0 

1 

0 

76 

0 

0 

0 

0 

0 

0 

0 

0 

73 

0 

0 

0 

0 

0 

0 

1 

0 

76 

3 

0 

0 

0 

0 

0 

2 

0 

159 

0 

0 

0 

0 

0 

0 

1 

0 

104 

0 

0 . 

0 

0 

0 

0 

1 

0 

77 

0 

0 

0 

0 

0 

0 

0 

0 

70 

0 

0 

• 0 

0 

0 

0 

1 

0 

63 

0 

0 

0 

0 

0 

0 

0 

0 

68 

0 

0 

0.00 

0.25 

0.00 

0.01 

0.13 

0.05 

2.87 

3.54 

0.05 

1,620 

5 

245,210 

22,974 

65,683 

6,361 

338,182 

959 

21,191 

0.00 

0.00 

1.14 

0.14 

8.73 

0.30 

971.81 

3.39 

1.16 
Ashland Chemical Company Rolling 12-Month Bulk Loading HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 Bulk 

Average Splash Filling: 0% 

Average Submerged Filling: 100% 

April 17,1998 

Page 2 of 2 

7350000 

V5> 

Product 

Code 

3001450 

3002500 

Name 

Hi Sol 15 

Lacolene 

Monthly Emissions Gbs) 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 AujOT Sep/97 

00000000 0 

00000000 0 

Avg Emis 

factor 

Oct/97 Nov/97 Dec/97 (lbs/Kgal) 

0 0 0 0.02 

0 0 0 0.86 

12-Month 

TPut 

(gal) 

1,032 

385 

12-Month 

Emissions 

(lbs) 

0.02 

0.33 

Methanol 17 18 19 20 12 15 17 13 25 36 18 50 0.89 294,718 

3540000 Methyl Ethyl Ketone 1.48 29,237 

3620000 Methyl Isobutyl Ketone 0.39 11,503 

HAP Totals for Period Ending 12/97: 

261.71 

43.29 

4.44 

3590000 

3752000 

3752200 

3001850 

3970000 

3002990 

3001950 

Methylene Chloride 

Perchloroethylene Hi 

STVPDG 

Perchloroethylene Reforming 

Toluene 

Trichloroethylene 

VM&P Naphtha 

Xylene 

11 

0 

0 

1 

0 

0 

2 

0 

0 

0 

7 

0 

0 

2 

37 

O 

0 

11 

0 

0 

3 

19 

0 

0 

9 

0 

0 

3 

12 

0 

0 

17 

0 

0 

3 

0 

1 

0 

3 

0 

0 

5 

55 

0 

0 

8 

0 

0 

5 

11 

0 

0 

5 

0 

0 

2 

41 

1 

0 

4 

4 

0 

3 

54 

0 

0 

8 

2 

0 

4 

20 

0 

0 

11 

0 

0 

3 

16 

0 

0 

15 

1 

0 

5 

10.08 

0.67 

0.57 

0.58 

2.04 

0.30 

0.18 

27,531 

3,356 

689 

169,863 

3,250 

1,942 

213,193 

277.45 

2.24 

0.39 

98.64 

6.61 

0.59 

38.96 

109 105 145 135 125 117 255 143 163 181 120 160 1,650,332 1,757.22 

Total Bulk Loading HAP Emissions (tons): 0.88 
Ashland Chemical Company Rolling 12-Month Fugitive HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 

Product 

Code 

3968520 

3220000 

JC 

Monthly Emissions (lbs) 

Name Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 Dec/97 

Chlorolhene SM Solvent 

3210000 Dibutyl Phthalate 

Diethanolamine 

7430000 Ethanol PM pr 3224 

7138011 Ethanol SDA 23H MOD 190 

Proof 

April 14. 1998 

Page 1 of 3 

12-Month 

Emissions 

(lbs) 

7020840 

7021000 

3020656 

Ambilrol CN 

Antifreeze 

ARDRIL 2957 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0.07 

0.04 

0.03 

0.13 

0.42 

0.36 

3310000 

7418029 

7030800 

Dioctyl Phthalate 

Ethanol 3A200PF 

Ethanol 4085 

13 

0 

0 

11 

0 

0 

13 

0 

0 

12 

0 

0 

13 

0 

0 

12 

0 

0 

13 

0 

0 

13 

0 

0 

12 

0 

0 

13 

0 

0 

12 

0 

0 

13 

0 

0 

149.06 

0.00 

0.00 

0.05 

0.01 

3353000 

3365000 

3370000 

3370008 

3060000 

3110250 

3600500 

Ethylbenzene 

Ethylene Dichloride 

Ethylene Glycol 

Ethylene Glycol Polyester Gr 

Glycol Ether DB 

Glycol Ether DE 

Glycol Ether DM Fuel Ad Gd 

13 

0 

13 

0 

13 

0 

1 

12 

0 

11 

0 

12 

0 

0 

13 

0 

13 

0 

13 

0 

1 

13 

0 

12 

0 

12 

0 

1 

13 

0 

13 

0 

13 

0 

1 

13 

0 

12 

0 

12 

0 

0 

13 

0 

13 

0 

13 

0 

0 

13 

0 

13 

0 

13 

0 

0 

12 

0 

12 

0 

12 

0 

0 

13 

0 

13 

0 

13 

0 

0 

13 

0 

12 

0 

12 

0 

1 

13 

0 

13 

0 

13 

0 

0 

153.08 

0.04 

150.12 

0.19 

149.53 

0.23 

5.75 
Ashland Chemical Company Rolling 12-Month Fugitive HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dec/97 April 14,1998 

Page 2 of 3 

Product 

Code 

Monthly Emissions (lbs) 

Name Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aug/97 Sep/97 Oct/97 Nov/97 Dec/97 

12-Month 

Emissions 

(lbs) 

3405942 

3070000 

3071000 

3405900 

3405950 

3002420 

3002430 

V_J\ 3001440 

3001450 

0000001 

3002500 

7350000 

3540000 

3620000 

3590000 

3639200 

3639220 

GLYCOL ETHER DM 

FUEL ADDITIVE 

Glycol Ether EB 

Glycol Ether EB Acetate 

Glycol Ether EP 

Glycol Ether TB 

Hexane 

Hexasol 

Hi Sol 10 

Hi Sol 15 

Houston Blend Tank Wash 

50/50 

Lacolene 

Methanol 

Methyl Ethyl Ketone 

Methyl Isobutyl Ketone 

Methylene Chloride 

Muriatic Acid 

Muriatic Acid 22' 

0 

13 

0 

0 

0 

14 

.0 

1 

0 

0 

0 

16 

13 

13 

13 

0 

0 

0 

12 

0 

0 

0 

12 

0 

1 

0 

0 

0 

13 

12 

11 

12 

0 

0 

0 

13 

0 

0 

0 

14 

0 

1 

0 

0 

0 

14 

13 

13 

13 

1. 

0 

0 

13 

0 

0 

0 

13 

0 

1 

0 

0 

0 

13 

12 

12 

12 

0 

1 

0 

13 

0 

0 

0 

14 

0 

1 

0 

0 

0 

14 

14 

13 

13 

0 

'• 0 

0 

13 

0 

0 

1 

13 

0 

1 

0 

13 

0 

15 

14 

12 

12 

0 

0 

0 

14 

0 

0 

0 

14 

0 

1 

0 

14 

0 

18 

14 

13 

13 

0 

0 

1 

13 

0 

0 

0 

14 

0 

1 

0 

14 

0 

15 

14 

13 

13 

0 

0 

0 

13 

0 

0 

0 

14 

0 

1 

0 

13 

0 

14 

14 

12 

12 

0 

0 

0 

13 

0 

0 

0 

14 

0 

I 

0 

13 

0 

15 

14 

13 

0 

0 

0 

0 

13 

0 

0 

0 

13 

0 

1 

0 

12 

0 

14 

14 

12 

0 

1 

0 

0 

13 

0 

0 

0 

14 

0 

1 

0 

13 

0 

15 

14 

13 

0 

0 

1 

2.78 

156.27 

0.01 

0.43 

3.38 

162.12 

0.01 

16.05 

0.28 

91.98 

0.21 

174.68 

162.50 

150.37 

113.25 

3.49 

1.97 
Ashland Chemical Company 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code Name 

3753000 Perchloroethylene Freon 

3752000 Perchloroethylene Hi 

STVPDG 

Rolling 12-Month Fugitive 

12 Months Ending: Dcc/97 

Monthly Emissions (lbs) 

Jan/97 Fcb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 Dec/97 

00000000000 0 

00000000000 0 

HAP Emissions 

April 14,1998 

Page 3 of 3 

12-Month 

Emissions 

Obs) 

0.14 

0.27 

3752200 Perchloroethylene Reforming 

3931140 Styrene Monomer 50 IN 

HAP Totals for Period Ending 12/97: 

0.12 

3.10 

3002860 

3001850 

3970000 

J L 3002990 

3001950 

Super Lacolenc 

Toluene 

Trichloroethylene 

VM&P Naphtha 

Xylene 

0 

.13 

0 

1 

13 

0 

12 

0 

1 

12 

0 

14 

0 

1 

13 

0 

13 

0 

1 

13 

0 

30 

0 

1 

14 

0 

16 

0 

1 

14 

0 

17 

0 

1 

15 

0 

17 

0 

1 

14 

0 

17 

0 

1 

13 

0 

17 

0 

1 

14 

0 

17 

0 

1 

14 

0 

18 

0 

1 

14 

0.00 

202.17 

0.34 

15.34 

163.23 

163 145 162 157 181 178 187 182 176 169 164 170 2,033.56 

Total Fugitive HAP Emissions (tons): 1.02 
P.48 

ATTACHMENT 5 

11 
Ashland Chemical Company Total Rolling 12-Month HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

Emissions Categories 

Storage Tanks 

12 Months Ending: Dec/97 

Monthly Emissions (lbs) 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 

182 189 216 243 263 379 392 381 341 

Oct/97 Nov/97 Dec/97 

106 92 82 

12-Month 

TPut (gal) 

2,264,797 

April 17, 1998 

Page 1 of 1 

12-Month 

Emissions (lbs) 

2,865.97 

Blending Tanks 

Bulk Loading 

32 43 68 55 75 47 96 50 94 84 68 47 

109 105 145 135 125 117 255 143 163 181 120 160 

IIAP Totals for Period Ending 12/97: 600 590 673 684 773 822 1,131 850 923 685 545 637 

277,646 

1,650,332 

759.22 

1,757.22 

Container Filling 

Equipment Fugitives 

115 

163 

107 

145 

82 

162 

95 

157 

130 

181 

102 

178 

201 

187 

93 

182 

148 

176 

146 

169 

101 

164 

178 

170 

1,001,153 

(N/A) 

1,497.35 

2,033.56 

8,913.32 

cF^ 

Total HAP Emissions (tons): 

HAP Limit (tons): 

4.46 

(N/A) 
Ashland Chemical Company Total Rolling 12-Month HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 

Product 

Code Name 

Monthly Emissions (lbs) 

Jan/97 Fcb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aug/97 Sep/97 Oct/97 Nov/97 Dec/97 

7020840 AmbilrolCN 

7021000 Antifreeze 

3020656 ARDRIL2957 

3968520 Chlorothene SM Solvent 12 

3210000 Dibutyl Phthalate 

3220000 Diethanolamine 

3310000 Dioctyl Phthalate 13 11 13 12 13 12 13 13 12 

7418029 Ethanol 3A200PF 

— ° 7030800 Ethanol 4085 

7430000 Ethanol PM pr 3224 

7138011 Ethanol SDA 23H MOD 190 

Proof 

3353000 Ethylbenzene 26 23 27 31 28 33 29 35 19 

3365000 Ethylene Dichloridc 

3370000 Ethylene Glycol 13 11 13 12 13 12 13 13 12 

3370008 Ethylene Glycol Polyester Gr 

3060000 Glycol Ether DB 13 12 13 12 13 12 13 13 12 

13 

23 

13 

13 

12 

23 

12 

12 

13 

22 

13 

13 

April 17, 1998 

Page 1 of 3 

12-Month 

Emissions (lbs) 

0.07 

0.04 

0.09 

28.29 

0.44 

0.36 

149.06 

0.34 

0.05 

1.62 

0.30 

317.38 

4.32 

150.42 

0.20 

149.61 

3110250 Glycol Ether DE 

3600500 Glycol Ether DM Fuel Ad Gd 

4.13 

7.58 

J 
Ashland Chemical Company 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code Name 

3405942 GLYCOL ETHER DM FUEL 

ADDITIVE 

3070000 Glycol Ether EB 

3071000 Glycol Ether EB Acetate 

3405900 Glycol Ether EP 

3405950 Glycol Ether TB 

Jan/97 

0 

15 

0 

0 

0 

12 Months Ending: 

Feb/97 

0 

14 

0 

0 

0 

Mar/97 

0 

20 

0 

0 

0 

: Dcc/97 

Apr/97 

0 

18 

0 

0 

0 

Monthly Emissions (lbs) 

May/97 

0 

19 

0 

0 

0 

Jun/97 

0 

25 

0 

0 

1 

Jul/97 

1 

25 

0 

1 

0 

Aue/97 

1 

22 

0 

0 

0 

Sep/97 

1 

17 

0 

0 

0 

Total Rolling 12-Month HAP Emissions 

Oct/97 

1 

17 

0 

0 

0 

Nov/97 

0 

20 

0 

0 

0 

April 17, 1998 

Page 2 of 3 

12-Month 

Dec/97 Emissions (lbs) 

1 3.73 

16 228.05 

0 0.02 

0 1.57 

0 3.41 

3002420 Hexane 136 147 144 148 172 177 249 196 195 168 128 161 

3002430 Hexasol 

OX 

Q . 3001440 Hi Sol 10 

2,023.15 

3.79 

21.20 

3001450 

0000001 

3002500 

7350000 

3540000 

3620000 

3590000 

3639200 

3639220 

3753000 

Hi Sol 15 

Houston Blend Tank Wash 50/50 

Lacolene 

Methanol 

Methyl Ethyl Ketone 

Methyl Isobutyl Ketone 

Methylene Chloride 

Muriatic Acid 

Muriatic Acid 22' 

Perchloroethylene Freon 

0 

0 

0 

116 

37 

16 

149 

0 

0 

0 

0 

0 

0 

56 

42 

17 

186 

1 

0 

4 

0 

0 

0 

73 

47 

18 

199 

14 

7 

0 

0 

0 

0 

54 

48 

19 

221 

1 

16 

0 

0 

0 

0 

53 

54 

22 

260 

3 

0 

0 

0 

104 

0 

87 

76 

19 

168 

0 

0 

0 

0 

107 

0 

181 

72 

28 

283 

4 

0 

0 

0 

105 

0 

63 

69 

19 

194 

3 

0 

0 

0 

99 

1 

70 

58 

18 

290 

8 

0 

0 

0 

13 

0 

70 

70 

20 

162 

3 

0 

0 

0 

13 

0 

62 

62 

17 

80 

14 

0 

0 

0 

13 

0 

99 

53 

18 

103 

4 

10 

0 

0.36 

453.21 

3.25 

984.69 

689.37 

231.32 

2,294.18 

54.45 

33.29 

4.45 

p 

Im 
<J\ 

Ashland Chemical Company 

Facility ID: 028 

Facility Name: Houston, TX 

Product 

Code Name 

3752000 Perchloroethylene Hi STVPDG 

3752200 Perchloroethylene Reforming 

Total Rolling 

12 Months Ending: Dcc/97 

Monthly Emissions Obs) 

Jan/97 Fcb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 Dcc/97 

0000043020 2 1 

10000001000 0 

12-Month HAP Emissions 

April 17, 1998 

Page 3 of 3 

12-Month 

Emissions (lbs) 

10.65 

2.15 

3931140 Styrene Monomer 50 IN 

3002860 Super Lacolene 

HAP Totals for Period Ending 12/97: 600 590 673 684 773 822 1,131 850 923 685 545 637 

Total HAP Emissions (tons): 

HAP Limit (tons): 

26.71 

0.03 

3001850 Toluene 

3970000 Trichloroethylene 

3002990 VM&P Naphtha 

3001950 Xylene 

29 

4 

3 

23 

38 

0 

3 

20 

48 

5 

2 

29 

50 

2 

2 

30 

83 

5 

2 

30 

41 

0 

2 

37 

54 

0 

2 

42 

54 

0 

2 

31 

47 

12 

2 

30 

49 

2 

2 

34 

50 

2 

2 

28 

55 

7 

2 

29 

598.86 

39.00 

23.86 

364.37 

8,913.32 

4.46 

(N/A) 
Ashland Chemical Company Rolling 12-Month Storage Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 April 14, 1998 

Page I of 2 

Tank Product 

ID Code Name 

Monthly Emissions Obs) Work Loss 12-Month 12-Month 

—~ Factor TPut Emissions 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aue/97 Sep/97 Oct/97 Nov/97 Dec/97 (lbs/Kgal) (gal) (lbs) 

13 

15 

16 

18 

19 

2 

20 

22 

24 

24 

24 

24 

24 

24 

24 

24 

24 

24 

3540000 

3002420 

7350000 

3001850 

3001850 

3060000 

3001950 

3353000 

3070000 

3002420 

3001440 

3001450 

3002500 

7350000 

3540000 

3620000 

3001850 

3002990 

Methyl Ethyl Ketone 

Hexane 

Methanol 

Toluene 

Toluene 

Glycol Ether DB 

Xylene 

Ethylbenzene 

Glycol Ether EB 

Hexane 

Hi Sol 10 

Hi Sol 15 

Lacolene 

Methanol 

Methyl Ethyl Ketone 

Methyl Isobutyl Ketone 

Toluene 

VM&P Naphtha 

13 

29 

8 

5 

5 

0 

8 

10 

0 

0 

0 

0 

0 

0 

0 

0 

0 

0 

14 

30 

9 

5 

5 

0 

4 

7 

0 

0 

0 

0 

0 

1 

1 

0 

1 

0 

16 

33 

10 

6 

6 

0 

11 

8 

0 

0 

0 

0 

0 

2 

1 

0 

1 

0 

17 

37 

11 

7 

7 

0 

11 

14 

0 

0 

0 

0 

0 

2 

1 

0 

2 

0 

19 

40 

12 

7 

7 

0 

10 

11 

0 

0 

0 

0 

0 

2 

2 

0 

2 

0 

20 

43 

13 

0 

8 

0 

16 

15 

0 

0 

0 

0 

0 

2 

2 

0 

2 

0 

21 

44 

13 

0 

8 

0 

17 

13 

0 

0 

0 

0 

0 

2 

2 

0 

2 

0 

21 

43 

13 

0 

8 

0 

11 

18 

0 

0 

0 

0 

0 

2 

2 

0 

2 

0 

19 

41 

12 

0 

8 

0 

11 

5 

0 

0 

0 

0 

0 

2 

2 

0 

2 

0 

17 

37 

11 

0 

7 

0 

12 

8 

0 

0 

0 

0 

0 

2 

1 

0 

2 

0 

15 

32 

9 

0 

6 

0 

9 

8 

0 

0 

0 

0 

0 

2 

1 

0 

1 

0 

14 

30 

9 

0 

5 

0 

8 

7 

0 

0 

0 

0 

0 

1 

1 

0 

1 

0 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.33 

0.39 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

0.00 

83,059 

337,605 

470,959 

44,473 

212,134 

17,842 

250,263 

179,693 

1,873 

621 

188 

125 

88 

5,322 

5,638 

621 

18,781 

188 

207.04 

437.60 

130.18 

30.13 

80.32 

0.05 

127.80 

124.47 

0.34 

2.43 

0.01 

0.00 

0.13 

20.63 

15.95 

0.36 

17.84 

0.07 
Ashland Chemical Company Rolling 12-Month Storage Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dcc/97 April 14, 1998 

Page 2 of 2 

Tank Product 

ID Code Name 

Monthly Emissions (lbs) Work Loss 12-Month 

Factor TPut 

Jan/97 Feh/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aug/97 Sep/97 Oct/97 Nov/97 Dec/97 (lbs/Kgal) (gal) 

HAP Totals for Period Ending 12/97: 182 189 216 243 263 379 392 381 341 

12-Month 

Emissions 

(lbs) 

24 

25 

28 

30 

31 

32 

36 

5 

^_TI 

V>* 6 

3001950 

3001440 

3620000 

3310000 

3370000 

3070000 

3002990 

0000001 

3590000 

Xylene 

Hi Sol 10 

Methyl Isobutyl Ketone 

Dioctyl Phthalate 

Ethylene Glycol 

Glycol Ether EB 

VM&P Naphtha 

Houston Blend Tank 

Wash 50/50 

Methylene Chloride 

0 

0 

3 

0 

0 

2 

1 

0 

97 

0 

0 

4 

0 

0 

2 

1 

0 

102 

0 

0 

4 

0 

0 

4 

0 

0 

113 

0 

0 

5 

0 

0 

3 

0 

0 

127 

0 

0 

7 

0 

0 

4 

0 

0 

140 

0 

1 

6 

0 

0 

7 

0 

90 

153 

0 

0 

10 

0 

0 

8 

0 

93 

158 

0 

0 

5 

0 

0 

7 

0 

92 

156 

0 

0 

5 

0 

0 

2 

0 

86 

145 

0 

0 

5 

0 

0 

3 

0 

0 

0 

0 

0 

3 

0 

0 

4 

0 

1 

0 

0 

0 

3 

0 

0 

1 

0 

0 

0 

0.00 

0.10 

0.75 

0.00 

0.00 

0.25 

0.45 

0.93 

0.00 

3,159 

26-342 

19,474 

21,641 

34,730 

116,566 

2,707 

384,000 

26,705 

0.86 

3.19 

61.87 

0.00 

0.22 

46.33 

5.54 

361.23 

1,191.38 

106 92 82 2,264,797 2,865.97 

Total Storage Tank HAP Emissions (tons): 1.43 
Ashland Chemical Company 

Facility ID: 028 

Facility Name: Houston, TX 

Tank 

ID 

101 

101 

101 

101 

101 

101 

101 

^ \ 101 

~ ~ ^ 101 

101 

101 

Product 

Code 

7020840 

3020656 

3210000 

7418029 

3370000 

3070000 

3071000 

3405900 

3002420 

3002430 

3001440 

Name 

Ambitrol CN 

ARDR1L 2957 

Dibutyl Phthalate 

Ethanol 3A200PF 

Ethylene Glycol 

Glycol Ether EB 

Glycol Ether EB 

Acetate 

Glycol Ether EP 

Hexane 

Hexasol 

Hi Sol 10 

Jan/97 

0 

0 

0 

0 

0 

0 

0 

0 

8 

0 

0 

12 Months Ending: Dcc/97 

Feb/97 

0 

0 

0 

0 

0 

0 

0 

0 

15 

0 

0 

Mar/97 

0 

0 

0 

0 

0 

0 

0 

0 

9 

0 

0 

Apr/97 

0 

0 

0 

0 

0 

0 

0 

0 

10 

0 

0 

Monthly Emissions Obs) 

May/97 

0 

0 

0 

0 

0 

0 

0 

0 

19 

0 

0 

Jun/97 

0 

0 

0 

0 

0 

0 

0 

0 

17 

0 

0 

Jul/97 

0 

0 

0 

0 

0 

0 

0 

0 

18 

0 

0 

Aug/97 

0 

0 

0 

0 

0 

0 

0 

0 

18 

0 

0 

Rolling 12-Month Blending Tank HAP Emissions 

Sep/97 

0 

0 

0 

0 

0 

0 

0 

0 

32 

0 

0 

Oct/97 

0 

0 

0 

0 

0 

0 

0 

0 

28 

0 

0 

Nov/97 

0 

0 

0 

0 

0 

0 

0 

0 

12 

0 

0 

Dec/97 

0 

0 

0 

0 

0 

0 

0 

0 

22 

0 

0 

Avg Emis 

Factor 

Gbs/Kgal) 

0.00 

0.00 

0.00 

1.27 

0.00 

0.17 

0.01 

0.08 

4.76 

4.79 

0.11 

April 14, 1998 

Page 1 of 5 

12-Month 

TPut 

(g»D 

493 

208 

3 

109 

2,629 

1,702 

38 

1,347 

43,916 

20 

959 

12-Month 

Emissions 

Obs) 

0.00 

0.00 

0.00 

0.14 

0.00 

0.29 

0.00 

0.11 

208.83 

0.10 

0.10 

101 

101 

101 

3001450 Hi Sol 15 0.02 

3002500 Lacolene 0 1.45 

7350000 Methanol 2.47 

176 

437 

7,260 

0.00 

0.63 

17.96 

101 

101 

101 

3540000 Methyl Ethyl Ketone 

3620000 Methyl Isobutyl Ketone 

3590000 Methylene Chloride 

1 

0 

0 

1 

0 

0 

3 

0 

IS 

2 

0 

9 

2 

0 

7 

8 

0 

1 

6 

1 

29 

7 

0 

1 

4 

0 

16 

7 

1 

14 

7 

0 

21 

4 

0 

0 

2.68 

0.62 

24.21 

19,162 

5,027 

4,651 

51.41 

3.11 

112,58 
Ashland Chemical Company Rolling 12-Month Blending Tank HAP Emissions 

Facility ID: 028 

Facility Name: Houston, TX 

12 Months Ending: Dec/97 April 14,1998 

Page 2 of 5 

Tank Product 

ID Code Name 

Monthly Emissions (lbs) Avg Emis 12-Month 12-Month 

' "~ Factor TPut Emissions 

Jan/97 Feb/97 Mar/97 Apr/97 May/97 Jun/97 Jul/97 Aug/97 Sep/97 Od/97 Nov/97 Dec/97 Gbs/Kgal) (gal) (lbs) 

101 

101 

101 

101 

101 

3752000 

3002860 

3001850 

3002990 

3001950 

Perchloroethylene Hi 

STVPDG 

Super Lacolcnc 

Toluene 

VM&P Naphtha 

Xylene 

Tank 101 Subtotals: 

102 

102 

102 

102 

102 

102 

102 

102 

102 

102 

7020840 

3020656 

3210000 

7418029 

3370000 

3070000 

3071000 

3405900 

3002420 

3002430 

Ambilrol CN 

ARDRIL 2957 

Dibutyl Phthalate 

Ethanol 3A200PF 

Ethylene Glycol 

Glycol Ether EB 

Glycol Ether EB 

Acetate 

Glycol Ether EP 

Hexane 

Hexasol 

0 

0 

1 

0 

0 

14 

0 

0 

0 

0 

0 

0 

0 

0 

4 

0 

0 

0 

2 

0 

I 

19 

0 

0 

0 

0 

0 

0 

0 

0 

7 

0 

0 

0 

2 

0 

0 

30 

0 

0 

0 

0 

0 

0 

0 

O 

4 

0 

0 

0 

2 

0 

1 

24 

0 

0 

0 

0 

0 

0 

0 

0 

5 

0 

0 

0 

3 

0 

1 

32 

0 

0 

0 

0 

0 

0 

0 

0 

9 

0 

0 

0 

3 

0 

0 

32 

0 

0 

0 

0 

0 

0 

0 

0 

8 

0 

0 

0 

6 

0 

3 

65 

0 

0 

0 

0 

0 

0 

0 

0 

9 

0 

0 

0 

5 

0 

1 

34 

0 

0 

0 

0 

0 

0 

0 

0 

9 

0 

0 

0 

6 

0 

1 

64 

0 

0 

0 

0 

0 

0 

0 

0 

15 

0 

0 

0 

5 

0 

1 

57 

0 

0 

0 

0 

0 

0 

0 

0 

13 

0 

0 

0 

4 

0 

0 

46 

0 

0 

0 

0 

0 

0 

0 

0 

6 

0 

0 

0 

4 

0 

0 

32 

0 

0 

0 

0 

0 

0 

0 

0 

11 

0 

1.67 

1.17 

0.97 

0.53 

0.32 

0.00 

0.00 

0.00 

1.28 

0.00 

0.17 

0.01 

0.08 

4.76 

4.51 

50 

4 

44,491 

1,001 

30,326 

164,009 

232 

98 

1 

51 

1,237 

801 

17 

634 

20,664 

• 10 

0.08 

0.00 

43.36 

0.53 

9.84 

449.09 

0.00 

0.00 

0.00 

0.07 

0.00 

0.14 

0.00 

0.05 

98.28 

0.05 
P.57 

ATTACHMENT 6 

6^ 
P.58 

*.;s 

Barry R. McBee, Chairman 

R. B. "Ralph" Marquez. Commissioner 

John M. Baker, Commissioner 

Dan Pearson, Executive Director 

TEXAS NATURAL RESOURCE CONSERVATION COMMISSION 

Protecting Texas by Reducing and Preventing Pollution 

July 15, 1996 

Mr. Daniel Greenwood 

Plant Manager 

ASHLAND CHEMICAL COMPANY 

8901 Galveston Road 

Houston, Texas 77234 

Re: Permit Amendment 

Pennit No. 457 

Houston Distribution Terminal 

Houston, Harris County 

Account ID No. HG-0046-P 

Dear Mr. Greenwood: 

This is in response to your letter dated February 27,1996 and permit application, Form PI-1, 

concerning the proposed amendment to Permit No. 457. We understand that you propose to 

make several changes to the existing facility including the construction of several new storage 

tanks, the addition of new chemicals to the approved list, the addition of a tote filling station, 

and the addition of two new blend tanks. Also, this will acknowledge that your application for 

the above-referenced permit is technically complete as of July 12, 1996. 

Pursuant to 30 TAC Section 116.116(b) (Regulation VI), Permit No. 457 is hereby amended. 

This information will be incorporated into the existing permit file. Enclosed are revised special 

conditions pages and a maximum allowable emission rates table. Please attach these to your 

permit. 

This amendment will be automatically void upon the occurrence of any of the following, as per 

§116.115(b)(1): 

1. Failure to begin construction of the changes authorized by this amendment within 18 months 

from the date of this authorization. 

$1 

P.O. Box 13087 • Austin. Texas 78711-3087 • 512/239-1000 
P.59 

Mr. Daniel Greenwood 

Page 2 

July 15, 1996 

Re: Permit No. 457 

2. Discontinuance of construction of the changes authorized by this amendment for a period of 

18 consecutive months or more. 

3. Not completing the changes authorized by this amendment within a reasonable time. 

We have enclosed two operations certification forms (Form PI-3A and Form PI-3B). 

Section 116.110(b) requires you to certify that operations addressed in this permit are in 

conformance with representations in the permit application. Please file these certifications with 

both the Texas Natural Resource Conservation Commission (TNRCC) New Source Review 

Division in Austin and the appropriate TNRCC Regional Office in a timely manner. 

Your cooperation in this matter is appreciated. If you have further questions, please contact 

Ms. Dana Poppa Vermillion, P.E. of our Office of Air Quality, New Source Review Division 

at (512) 239-1280. 

Sincere! 

Executive Director 

Texas Natural Resource Conservation Commission 

DP/DV/mc 

Enclosures 

cc: Ms. Karen Atkinson, Air Program Manager, Houston 

Mr. David Fetterman, P.E., Environmental Health Division, Bureau of Air Quality 

Control, Department of Health and Human Services, Houston 

Mr. Rob Barrett, Director, Harris County Pollution Control Department, Pasadena 

^ 
P.60 

TEXAS NATURAL RESOURCE CONSERVATION COMMISSION 

Office of Air Quality 

New Source Review Division 

Post Office Box 13087 

Austin, Texas 78711-3087 

FORM PI-3A 

Operations Certification (Part 1 of 2) 

TNRCC Rule 116.110(b)(1)(A) 

For facilities permitted by authority of Title 30 Texas Admininstrative Code, Chapter 116. 

This certification must be signed by an individual with process knowledge in a mangerial capacity and must 

be submitted upon completion of construction and prior to start of operation ofthe authorized facilities. 

Air Permit Number__ TNRCC Air Quality Account Number:; -

Approval date of latest permit action: 

(Important Please use agency approval date as shown on accompanying permit, amendment or other type 

authorization) 

D. Permittee 

Permit Issued To: 

Mailing Address:. 

Technical Contact: (Person, Title, Mailing Address)_ 

Telephone^ ) FAX:( )_ 

IU. Permit Unit Information 

Pennit Unit Name: 

Location: Nearest City County: 

IV. Construction and operating dates for units affected by this pennit approval: 

Check here if no construction is associated with the approved project (go to Section V). 

Check here if portions of the approved project have begun or will begin operation before construction is complete 

(i.e. .staged construction); in this case, please submit separate Forms PI-3A and PI-3B for each portion of each stage 

of construction; show construction start and completion dates and the operation starting date applied to the phase. 

Describe the stage or portion of the project for which this certification is filed: 

Date for start of construction: 

Date for completion of construction: 

Date for proposed start of operation: 

V. A copy of this certification must be sent to the appropriate TNRCC Regional Office (please send original to the 

agency address shown at top of form). 

Regional Office (city) sent to: 

VI. Certification 

I, ____________________________ _ 

Nmrw • please prim or type Tiile - Owner, Plan M-iujcr, President. Vce President, fcirvironmenul Director 

state that I have knowledge of the facts herein set forth and that the same are true and correct to the best of my knowledge. 

I certify that the facilities or changes authorized by the referenced pennit have been accomplished as represented, if those 

representations affect emissions, method of control, or character of emissions. 

DATE __^ _ SIGNATURE 

Note: Original signature in ink required. 

In all cases, a second certification, FORM PI-3B, must be submitted simultaneously with any report of 

testing or monitoring results required by the permit or, if no testing is required, within 60 days of the 

commencement of operation. vmi«o«/n.i996 

_ 
P.61 

n. 

TEXAS NATURAL RESOURCE CONSERVATION COMMISSION 

Office of Air Quality 

New Source Review Division 

Post Office Box 13087 

Austin, Texas 78711-3087 

FORM PI-3B 

Operations Certification (Part 2 of 2) 

TNRCC Rule 116.110(b)(1)(B) 

For facilities permitted by authority of Title 30 Texas Admininstrative Code, Chapter 116. 

This certification must be signed by an individual with process knowledge in a mangerial capacity, and must be 

submitted simultaneously with any report of testing or monitoring results required bv the permit or. if no testing 

or monitoring is required, within 60 days ofthe commencement of operation. 

I. Air Permit Number: 

Approval date of latest pennit action: 

TNRCC Air Quality Account No. 

Submittal date of companion Fonn PI-3A (Part 1 of Operations Certification):, 

Permittee 

Permit Issued'To: 

Mailing Address: ; 

Technical Contact: (Person, Title, Mailing Address)_ 

Telephone^ )_ FAX:( ) 

EQ. Pennit Unit Information 

Pennit Unit Name: 

Location: Nearest City_ County:, 

IV. Construction and operating dates for units affected by this pennit approval: 

Check here, if no construction is associated with the approved project (go to Section V). 

Check here if portions of the approved project have begun or will begin operation before construction is complete 

(i.e.,staged construction); in this case, please submit separate Forms PI-3A and PUB for each portion of each stage of 

constmction; show construction start and completion dates and the operation starting date applied to the phase. Describe 

the stage or portion of the project for which this certification is filed: 

Date for start of construction: • 

Date for completion of construction: 

Date for proposed start of operation: 

V. A copy of this certification must be sent to the appropriate TNRCC Regional Office (please send original to the agency 

address shown at top of form). 

Regional Office (city) sent to: 

VI. Certification 

I. 

Name • please prim or type Title - Owner, Plant Marnier, President, Vice President. Environmental uuecior 

state that I have knowledge of the facts herein set forth and that the same are true and correct to the best of my knowledge. 

I certify that the facility complies with ail terms of the preconstruction permit and that operations of the facility are in 

compliance with the Texas Clean Air Act (Chapter 382, Texas Health & Safety Code) and the rules of the TNRCC. 

DATE SIGNATURE 

Note: Original signature in ink required. 

Versim 04A2/I996 

Co 
P.62 

TEXAS NATURAL RESOURCE CONSERVATION 

COMMISSION 

Affi QUALITY PERMIT • GENERAL CONDITIONS 

AND PERTINENT RULES EFFECTIVE FOR PERMITS ISSUED OR AMENDED 

ON OR AFTER AUGUST 16, 1994 

1. The facilities covered by this permit shall be constructed and operated as specified in the application for the permit AO representations regarding 

construction plans and operation procedures contained in the permit application shall be conditions upon which the permit is issued. Variations from 

these representations shall be unlawful unless the pennit holder first makes application to the Executive Director of the Texas Natural Resource 

Conservation Commission (TNRCC or Commission) to amend this permit in that regard and such amendment is approved. (Title 30 of the Texas 

Administrative Code (30 TAC 116.116)). 

2. Voiding of Permit A permit or pennit amendment is automatically void if the holder fails to begin construction within 18 months of date of 

issuance, discontinues construction for more than 18 consecutive months prior to completion, or fails to complete construction within a reasonable 

time. Upon request, the Executive Director may grant a onetime 18-month extension of the date to begin construction. (30 TAC 116.115(b)(1)). 

3. Construction Progress. Start of construction, construction interruptions exceeding 45 days, and completion of construction shall be reported 

to the appropriate regional office of the TNRCC not later than 15 working days after occurrence of the event (30 TAC 116.115(b)(2)). 

4. Start-up Notification. The appropriate Air Program regional office of the Commission shall be notified prior to the commencement of operations 

of the facilities authorized by the permit in such a manner that a representative of the TNRCC may be present Phased construction, which may 

involve a series of units commencing operations at different times, shall provide separate notification for the commencement of operations for each 

unit (30 TAC 116.115(b)(3)). 

5. Sampling Requirements. If sampling of stacks or process vents is required, the permit holder shall contact the TNRCC Office of Air Quality prior 

to sampling to obtain the proper data forms and procedures. All sampling and testing procedures must be approved by the Executive Director and 

coordinated with the regional representatives of the Commission. The permit holder is also responsible for providing sampling facilities and 

conducting the sampling operations or contracting with an independent sampling consultant (30 TAC 116.115(b)(4)). 

6. Equivalency of Methods. It shad be the responsibility of the permit holder to demonstrate or otherwise justify the equivalency of emission control 

methods, sampling or other emission testing methods, and monitoring methods proposed as alternatives to methods Indicated in the conditions of 

the permit. Alternative methods shall be applied for in writing and must be reviewed and approved by the Executive Director prior to their use in 

fulfilling any requirements ofthe permit (30 TAC 116.115(b)(5)). 

7. Recordkeeping. A dopy of the permit along with information and data sufficient to demonstrate compliance with the permit shall be maintained 

in a file at the plant site and made available at the request of personnel from the TNRCC or any air pollution control program having jurisdiction. For 

facilities that normally operate unattended, this information shall be maintained at the nearest staffed location within Texas specified by the permit 

holder in the permit application. This information shall include, but is not limited to, production records and operating hours. Additional recordkeeping 

requirements may be specified in special conditions attached to the permit Information in the file shall be retained for at least two years following 

the date that the information or data is obtained. (30 TAC 116.115(b)(6)). 

8. Maximum allowable emission rates. The total emissions of air contaminants from any of the sources of emissions listed in the table entitled 

"Emission Sources - Maximum Allowable Emission Rates" shall not exceed the values stated on the table attached to the permit (30 TAC 

116.115(b)(7)). 

9. Maintenance of Emission Control. The facilities covered by the permit shall not be operated unless all air pollution emission capture and 

abatement equipment is maintained in good working order and operating properly during normal facility operations. Notification for upsets and 

maintenance shall be made in accordance with §101.6 and §101.7 of this title (relating to Notification Requirements for Major Upset and Notification 

Requirements for Maintenance). (30 TAC 116.115(b)(8)). 

10. Compliance with Rules. Acceptance of a permit by a permit applicant constitutes an acknowledgement and agreement that the holder will 

comply with all rules, regulations, and orders of the Commission issued in conformity with the Texas Clean Air Act and the conditions precedent to 

the granting of the permit If more than one state or federal rule or regulation or permit condition are applicable, then the most stringent limit or 

condition shall govern and be the standard by which compliance shall be demonstrated. Acceptance includes consent to the entrance of Commission 

employees and agents into the permitted premises at reasonable times to investigate conditions relating to the emission or concentration of air 

contaminants, including compliance with the permit (30 TAC 116.115(b)(9)). 

11. This permit may be appealed pursuant to Section 263.36 of the General Rules of the TNRCC and Section 382.032 of the TCAA Failure to 

take such appeal constitutes acceptance by the applicant of all terms of the permit (Tex Gov't Code Ann. § 2001, etseq.) 

12. This permit may not be transferred, assigned or conveyed by the holder except as provided by rule. (30 TAC 116.110(c)). 

13. There may be additional special conditions attached to a permit upon issuance or modification of the permit Such conditions in a permit may 

be more restrictive than the requirements of 30 TAC 116.115(c). 

14. Emissions from this facility must not cause or contribute to a condition of "air pollution" as defined in Section 382.003(3) of the Texas Clean Air 

Act (TCAA) or violate Section 382.085 of the TCAA. If the Executive Director determines that such a condition or violation occurs, the holder shall 

implement additional abatement measures as necessary to control or prevent Ihe condition or violation. 

Gl 

MS (gtrxono) 
P.63 

/> 

SPECIAL CONDITIONS 

Pennit No. 457 

EMISSION STANDARDS 

1. Each compound listed on the Approved Chemical List for the fixed and internal floating 

roof tanks is limited to the throughput listed on Tables 4-2 thru 4-6 of the amendment 

application submitted February 27, 1996. 

Methylene chloride throughput is also limited to the following short-term rates: 2,000 

gallons per hour for bulk loading, 660 gallons per hour for tote loading, and 330 gallons 

per hour for 55 gallon drums and small containers. 

2. These facilities shall comply with all requirements of Environmental Protection (EPA) 

Agency Regulations on Standards of Performance for New Stationary Sources promulgated 

for Volatile Organic Liquid Storage Vessels in Title 40 Code of Federal Regulations Part 

60 (40 CFR 60), Subpart A, K, and Kb. 

OPERATIONAL LIMITATIONS 

3. Chemicals stored at this facility shall be limited to the approved chemicals listed. 

4. Chemieals in the list "Chemicals Approved for Internal Floating Roof Tanks" may only be 

stored in the internal floating roof tanks at the facility. Chemicals in the list "Chemicals 

Approved for Fixed-Roof Tanks" may be stored either in fixed-roof tanks or internal 

floating roof tanks. 

5. The storage of any one chemical is limited by the number listed in the approved chemical 

lists. This number does not include any material transferred to a blend tank for blending 

purposes. 

6. Cyclohexylamine may be stored in either Tanks No. 19, 21, or 24. Cyclohexylamine may 

only be stored in one tank at a time. 

7. Storage And Loading of Volatile Organic Compounds (VOQ 

A. The control requirements specified in paragraphs B-E of this condition shall not apply 

(1) where the VOC has an aggregate partial pressure of less than 0.5 psia at the 

maximum expected operating temperature or (2) to storage tanks smaller than 25,000 

gallons. 

& 
P.64 

SPECIAL CONDITIONS 

Pennit No. 457 

Page 2 

B. An internal floating deck or "roof or equivalent control shall be installed in all tanks. 

The floating roof shall be equipped with one of the following closure devices between 

the wall of the storage vessel and the edge of the internal floating roof: (1) a 

liquid-mounted seal, (2) two continuous seals mounted one above the other, or (3) a 

mechanical shoe seal. Installation of equivalent control requires prior review and 

approval by the Texas Natural Resource Conservation Commission (TNRCC) 

Executive Director. 

C. An open-top tank containing a floating roof (external floating roof tank) which uses 

double seal or secondary seal technology shall be an approved control alternative to 

an internal floating roof tank provided die primary seal consists of either a mechanical 

shoe seal or a liquid-mounted seal, and the secondary seal is rim-mounted. A 

weadiershield is not approvable as a secondary seal unless specifically reviewed and 

determined to be vapor-tight. 

D. For any tank equipped with a floating roof, the holder of Uiis pennit shall follow 

40 CFR 60.113b, Testing and Procedures, to verify seal integrity. Additionally, the 

permit holder shall follow 40 CFR 60.115b, Reporting and Recordkeeping 

Requirements, to provide records of the dates seals were inspected, seal integrity, and 

corrective actions taken. 

E. The floating roof design shall incorporate sufficient flotation to conform to the 

requirements of American Petroleum Institute (API) Code 650 or an equivalent degree 

of flotation, except that an internal floating cover need not be designed to meet rainfall 

support requirements and the materials of construction may be steel or other materials. 

F. Uninsulated tank exterior surfaces exposed to the sun shall be white or aluminum. 

G. For purposes of assuring compliance with VOC emission limitations, the holder of this 

permit shall maintain a monthly emissions record which describes calculated emissions 

of VOC from all storage tanks and loading operations. The record shall include tank 

or loading point identification number, control method used, tank or vessel capacity 

in gallons, name of the material stored or loaded, VOC molecular weight, VOC 

monthly average temperature in degrees Fahrenheit, VOC vapor pressure at the 

monthly average material temperature in psia, and VOC throughput for the previous 

month and year-to-date. Records of VOC monthly average temperature are not 

required to be kept for unheated tanks which receive liquids that are at or below 

ambient temperatures. These records shall be maintained at the plant site for at least 

two years and be made available to representatives of the TNRCC upon request. 

63 
P.65 

r. 

SPECIAL CONDITIONS 

Permit No. 457 

Page 3 

H. If throughput records are specified in the special conditions of diis permit, the holder 

of this pennit may keep such records in lieu of the records required in paragraph G. 

I. Emissions for tanks and loading operations shall be calculated using: (a) AP-42 

"Compilation of Air Pollution Emission Factors, Chapter 12 - Storage of Organic 

Liquids" and (b) the TNRCC publication titled "Technical Guidance Package for 

Chemical Sources - Storage Tanks." 

J. Operation without visible liquid leaks or spills shall be maintained at all 

loading/unloading facilities, regardless of vapor pressure. This does not apply to 

.momentary dripping associated with the initial connection or disconnection of fittings. 

Sustained dripping from fittings during loading/unloading operations is not permitted. 

Any liquid spill that occurs during loading/unloading activities shall be reported 

pursuant to Sections 101.6 or 101.7 of the TNRCC General Rules and shall be cleaned 

up immediately to minimize air emissions. 

SPECIAL INSPECTION 

8. Floating roof seals shall be inspected and maintained in accordance with applicable 

requirements of EPA Regulations on Standards of Perfonnance for New Stationary Sources 

promulgated for Storage Vessels for Petroleum Liquids in 40 CFR 60, Paragraph 

60.113b(a). 

9. Each physical inspection of the double wiper seals in the internal floating roof tanks shall 

be performed within six months of one another. 

10. Piping. Valves. Flanges. Pumns. and Compressors in Volatile Organic Compounds (VOC) 

Service - 28M 

A. These conditions shall not apply (1) where the VOC has an aggregate partial pressure 

or vapor pressure of less than 0.5 psia at 100°F or at maximum process operating 

temperature if less than 100°F or (2) to piping and valves two inches nominal size and 

smaller or (3) where the operating pressure is at least 5 kilopascals (0.725 psi) below 

ambient pressure. Equipment excluded from this condition shall be identified in a list 

to be made available upon request. 

B. Construction of new and reworked piping, valves, pump systems, and compressor 

systems shall conform to applicable ANSI, API, ASME, or equivalent codes. 

CH 
P.66 

SPECIAL CONDITIONS 

Pennit No. 457 

Page 4 

C. New and reworked underground process pipelines shall contain no buried valves such 

that fugitive emission monitoring is rendered impractical. 

D. To the extent that good engineering practice will permit, new and reworked valves and 

piping connections shall be so located to be reasonably accessible for leak-checking 

during plant operation. Non-accessible valves, as defined in TNRCC Regulation V, 

shall be identified in a list to be made available upon request. 

E. New and reworked piping connections shall be welded or flanged. Screwed 

connections are permissible only on piping smaller than two-inch diameter. No later 

.than the next scheduled quarterly monitoring period after initial installation or 

replacement, all new or reworked connections shall be gas-tested or hydraulicallytested at no less than normal operating pressure and adjustments made as necessary 

to obtain leak-free performance. Flanges shall be inspected by visual, audible, and/or 

olfactory means at least weekly by operating personnel walk-through. 

Each open-ended valve or line shall be equipped widi a cap, blind flange, plug, or a 

second valve. Except during sampling, the second valve shall be closed. 

F. Accessible valves shall be monitored by leak-checking for fugitive emissions at least 

quarterly using an approved gas analyzer. Sealless/leakless valves (including, but not 

limited to, welded bonnet bellows and diaphragm valves) and relief valves equipped 

with a rupture disc upstream or venting to a control device are not required to be 

monitored. For valves equipped with rupture discs, a pressure sensing device shall 

be installed between the relief valve and rupture disc to monitor disc integrity. All 

leaking discs shall be replaced at the earliest opportunity but no later than the next 

process shutdown. 

An approved gas analyzer shall conform to requirements listed in 40 CFR 60.485[a] -

[b]. 

G. Except as may be provided for in the special conditions of this permit, all pump and 

compressor seals shall be monitored with an approved gas analyzer at least quarterly 

or be equipped with a shaft sealing system that prevents or detects emissions of VOC 

from the seal. Seal.systems designed and operated to prevent emissions or seals 

equipped with an automatic seal failure detection and alarm system need not be 

monitored. Seal systems that prevent emissions may include (but are not limited to) 

dual pump seals widi barrier fluid at higher pressure than process pressure or seals 

degassing to vent control systems kept in good working order. 

0 
P.67 

SPECIAL CONDITIONS 

Permit No. 457 

Page 5 

Submerged pumps or sealless pumps (including, but not limited to, diaphragm, 

canned, or magnetic driven pumps) may be used to satisfy the requirements of diis 

condition and need not be monitored. 

H. Damaged or leaking valves, flanges, compressor seals, and pump seals found to be 

emitting VOC in excess of 10,000 ppmv or found by visual inspection to be leaking 

(e.g., dripping process fluids) shall be tagged and replaced or repaired. Every 

reasonable effort shall be made to repair a leaking component as specified in this 

paragraph within 15 days after the leak is found. If the repair of a component would 

require a unit shutdown, die repair may be delayed until the next scheduled shutdown. 

All leaking components which cannot be repaired until a scheduled shutdown shall be 

identified for such repair by tagging. The TNRCC Executive Director, at his 

discretion, may require early unit shutdown or other appropriate action based on the 

number and severity of tagged leaks awaiting shutdown. 

I. The results of the required fugitive monitoring and maintenance program shall be 

made available to the TNRCC Executive Director, or his designated representative, 

upon request. Records shall indicate appropriate dates, test methods, instrument 

readings, repair results, and corrective actions taken for all components. Records of 

flange inspections are not required unless a leak is detected. 

J. Fugitive emission monitoring required by an applicable New Source Performance 

Standard (NSPS), 40 CFR 60, or an applicable National Emission Standard for 

Hazardous Air Pollutants (NESHAPS), 40 CFR 61, may be used in lieu of Items F 

through I of this condition. 

Compliance with the requirements of this condition does not assure compliance with 

requirements of NSPS or NESHAPS and does not constitute approval of alternative 

standards for these regulations. 

Dated 7-15-96 

a 
P.68 

CHEMICALS APPROVED FOR FIXED-ROOF TANKS 

Permit No. 457 

CHEMICAL CAS NUMBER TANKS PERMITTED FOR 

Butanol, n- 71363 

Butanol, sec- 78922 

Butyl Carbitol 112345 

Butyl Cellosolve 111762 

Butyl Cellosolve Acetate 112072 

Diacetone Alcohol 123422 

Diethanolamine 109897 

Diethylene Glycol 111466 

Diethylene Glycol EE 111900 

Diisobutyl Ketone 108838 

Diisopropanolomine 110974 

D-limonene 5989-27-5 

Dimediyl Phthalate 131113 

Dioctyl Phthalate 117817 

Dipropylene Glycol 110985 

Ethylbenzene 100-41-4 

Ethylene Glycol 107211 

Ethylhexanol-2 104767 

Furfuryl Alcohol 98O0O 

Glycol Ether DB 112345 

Glycol Ether DE 111900 

Glycol Ether DE-HG 111773 

Glycol Ether DP 34590948 

Glycol Ether DPM 111762 

Glycol Ether EE Acetate 112254 

Glycol Ether PB 5131668 

Glycol Ether PM 107982 

Heavy Aromatic Naphtha 64742069 

Hexylene Glycol 107415 

Isobutyl Isobutyrate 97858 

Isophorone 78591 

Kwik Dri 8052413 

Methyl Amyl Alcohol 108112 

Methyl Carbitol 111773 

Methylene Chloride 75-09-2 

Methyl Isobutyl Ketone 108101 

Mineral Spirits 1% 8052413 

Mineral Spirits 4% 8052413 

Mineral Spirits 6% 8052413 

1 

1 

ALL 

4 

4 

1 

5 

ALL 

ALL 

2 

17 

1 

2 

2 

ALL 

1 

ALL 

3 

1 

ALL 

ALL 

ALL 

2 

ALL 

2 

19 

1 

ALL 

ALL 

5 

1 

3 

1 

ALL 

1 

2 

1 

1 

1 
P.69 

CHEMICALS APPROVED FOR HXED-ROOF TANKS 

Permit No. 457 

Page 2 

CHEMICAL 

Mineral Spirits 7% 

Mineral Spirits Nonexempt 

Mineral Spirits Odorless 

Morpholine 

Orange Terpene 

Primary Amyl Alcohol 

Propanol normal 

Propasol P 

Propylene Glycol 

Solvent 100 

Solvent 140 

Solvent 140 Nonexempt 

Solvent 500 T 

Solvent 529 

Solvent 529-2 

Texanol Ester AlcoholTriethylene Glycol 

Tripropylene Glycol 

VM&P Naphtha High Initial 

VM&P Naphtha Nonexempt 

VM&P Naphtha Rule 66 

Xylene 

CAS NUMBER 

8052413 • 

8052413 

8052413 

110-91-8 

6895-656-9 

-

71238 

-

57556 

64742956 

64742887 

64742887 

64742967 

64742967 

64742967 

25265774 

112276 

13987014 

64742898 

64742898 

64742898 

1330207 

TANKS PERMITTED FOR 

1 

1 

1 

1 

1 

16 

1 

3 

ALL 

1 

3 

3 

12 

12 

12 

ALL 

4 

15 

1 

3 

1 

3 

Dated, 

7-15^96 

(^ 
P.70 

CHEMICALS APPROVED FOR INTERNAL FLOATING ROOF TANKS 

Pennit No. 457 

CHEMICAL CAS NUMBER TANKS PERMITTED FOR 

Acetone 67641 

Butanol, Tertiary 75650 

Butyl Acetate 123864 

Cellosolve Acetate 111159 

Cyclohexane 110877 

Cyclohexanone 108941 

Cyclohexylamine 108918 

Dibutyl Phthalate 84742 

Diethyl Phthalate 84662 

Diisobutyl Phthalate 84695 

Diisodecyl Phtiialate 26761400 

Diisonon Phthalate 28553120 

Ethanol 190 Proof 64172 

Ethanol 200 Proof 64175 

Ethyl Acetate 141786 

Glycol Ether EB Acetate 110805 

Glycol Ether EE 111159 

Glycol Ether EH 110496 

Glycol Ether EM Acetate 108656 

Glycol Ether PM Acetate 108656 

Gun Cleaner N/A 

Heptane 142825 

Hexane 100543 

Hexasol 64742898 

Isobutanol 78831 

Isobutyl Acetate 110190 

Isopropanol 91% 67630 

Isopropanol 95% 67630 

Isopropanol 99% 67630 

Isopropyl Acetate 108214 

Lacolene 64742898 

Lactol Spirits 

Methanol 67561 

Methyl Amyl Ketone 110430 

Methyl Ethyl Ketone 78933 

Methyl Isoamyl Ketone 110123 

Methyl n-Propyl Ketone 107879 

Monoethanolamine 141435 

n-Pentane 109-66-0 

Perchloroediylene 127184 

4 

3 

ALL 

ALL 

2 

2 

3 

3 

3 

3 

2 

1 

3 

1 

5 

1 

1 

1 

£. 
P.71 

J'-

»•• 

1 

• 

1 • 

CHEMICALS APPROVED FOR INTERNAL FLOATING ROOF TANKS 

Permit No. 457 

Page 2 

CHEMICAL 

Propyl Acetate 

Rubber Solvent 

Shell Sol B 

Styrene Monomer 10-15 

Styrene Monomer 50 IN 

Super Lacolene 

Tetrahydrofuran 

Texanol Isobutyrate 

Toluene . 

Trichloroethane 1,1,1 

Trichloroethylene 

* 

CAS NUMBER 

109604 

64742956 

64742898 

100425 

100425 

64742898 

109999 

6846500 

108883 

71556 

" 79016 

*]0 

TANKS PERMITTED FOR 

1 

4 

3 

1 

1 

3 

5 

1 

2 

ALL 

1 

Dated 7-15-96 
. P/72 

r 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

Pennit No. 457 

This table lists the maximum allowable emission rates and all sources of air contaminants on the applicant's 

property covered by this pennit. The emission rates shown are those derived from information submitted as 

part of the application for pennit and are die maximum rates allowed for these facilities. Any proposed 

increase in emission rates may require an application for a modification of the facilities covered by this .permit. 

Emission 

Point No. (D 

AIR CONTAMINANTS DATA 

Source 

Name (21 

Fixed Roof Tanks (4) 

Blend Tank 101 

Blend Tank 102 

Tank 3 

Tank 4 

Blend Tank 5 

Tank 7 

Tank 8 

Tank 9 

Tank 10 

Tank 11 

Tank 12 

Tank 20 

Tank 22 

Tank 24 

Tank 25 

Tank 26 

Tank 27 

Tank 28 

Tank 29 

Tank 30 

Tank 31 

Tank 32 

Tank 33 

Tank 34 

Tank 35 

Tank 36 

Tank 37 

Tank 38 

Tank 40 

Tank 41 

Tank 42 

Tank 43 

Tank 44 

Air Contaminant 

Name .31 

VOC 

VOC 

MeCl 

VOC 

MeCl 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

Emission Rates * 

lb/hr TPY 

12.48 

31.978 

7,698 0.35 

31.978 

7.698 0.17 

11.307 

11.184 

31.978 

11.329 

11.334 

11.307 

11.345 

11.342 

11.334 

11.330 

11.324 

11.325 

11.325 

11.319 

11.328 

16.42 

11.317 

11.350 

11.330 

11.324 

11.335 

11.350 

11.322 

11.342 

11.346 

11.330 

11.324 

11.324 

11.324 

11.324 

1.533 

1FX 

nl 
P.73 

Permit No. 457 

Page 2 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

AIR CONTAMINANTS DATA 

Emission 

Point No. (11 

1IFR 

• 

2 

3(a) 

3(b) 

FUG1 

FUG 2 

H-l 

Source 

Name (2) 

Floating Roof Tanks (4) 

Tank 6 

Tank 13 

Tank 14 

Tank 15 

Tank 16 

Tank 17 

Tank 18 

Tank 19 

Tank 21 

Tank 23 

Loading 

Drumming 

Corrosive Drumming 

Fugitives (5) 

Truck Washing Fugitives 

Heater 

Air Contaminant 

Name (3) 

VOC 

VOC 

CHC12CH2C1 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

VOC 

MeCl 

VOC 

MeCl 

Inorganic 

VOC 

VOC 

VOC 

NO, 

PM10 

CO 

so2 

Emission Rates * 

lb/hr TPY 

1.08 

0.268 

0.513 0.26 

2.255 

1.407 

0.841 

0.620 

1.425 

1.357 

1.123 

1.050 

1.493 

56.97 2.74 

18.73 0.16 

110.57 5.59 

7.46 0.29 

2.15 0.05 

5.08 2.50 

3.35 0.44 

0.01 0.02 

0.10 0.44 

0.01 0.05 

0.02 0.09 

<0.01 <0.01 

(1) Emission point identification - either specific equipment designation or emission point number from plot 

plan. 

(2) Specific point source name. For fugitive sources use area name or fugitive source name. 

n 
-r. 

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Permit No. 457 

Page 3 

EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

(3) VOC - volatile organic compounds as defined in General Rule 101.1 

MeCl - methylene chloride 

CHC12CH2C1 -1,1,1 trichloroethane 

NOx - nitrogen oxides 

PMl0 - particulate matter less than 10 microns 

CO - carbon monoxide 

S02 - sulfur dioxide 

(4) Allowable reflects the combined annual emissions total from the storage tanks and the maximum hourly 

emissions for each individual tank. 

(5) Fugitive emissions are an estimate only and should not be considered as a maximum allowable emission 

rate. 

* Emission rates are based on and the facilities are limited by die following maximum operating schedule: 

Hrs/day Days/week Weeks/vear or Hrs/year 8.760 

Dated 7-15-96