SDS: 0038053 Date Prepared: 06/26/2013 

## MATERIAL SAFETY DATA SHEET

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## 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: 

### ZEH 2017 Synonyms: None Chemical Family: Aliphatic amine Molecular Formula: Mixture Molecular Weight: Mixture Allnex USA Inc., 1950 Lake Park Dr ive, Smyrna, Georgia 30080, USA For Product and all Non-Emergency Information call +1-678-255-4691 or contact us a t: http://www.allnex.com/contact EMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call: Asia Pacific (Carechem 24): Australia: +61 2801 44558 China (PRC): +86 10 5100 3039 Japan: +81 345 789 341 New Zealand: +64 9929 1483 All Others: +65 3158 1074 Europe/Africa/Middle East (Carechem 24): Europe, Middle East, Africa, Israel: +44 (0) 1235 239 670 Middle East, Africa (Arabic speaking countries): +44 (0) 1235 239 671 Latin America (Carechem 24): Brazil: +55 113 711 9144 Mexico and all others: +52-555-004-8763 Canada and USA (Carechem 24 - NCEC ED29003275): +1-866-928-0789 (toll free) or +1-215-207-0061



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## 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPEARANCE AND ODOR: Color: clear colorless to slightly yellow Appearance: liquid Odor: amine STATEMENTS OF HAZARD:

POTENTIAL HEALTH EFFECTS
EFFECTS OF EXPOSURE: The estimated acute oral (rat) LD50, acute dermal (rabbi t) LD50 and 4-hour inhalation (rat) LC50 values for this material are 500 mg/kg, 4580 mg/kg and 1.6 mg/l, respectively . Direct contact with this material may cause eye and skin burns. Repeated or prolonged dermal c ontact may cause allergic skin reactions. Refer to Section 11 for toxicology information on the regulated components of this product.



### _____________________________________________________________________________ HARMFUL IF SWALLOWED HARMFUL IF INHALED CAUSES BURNS OF EYES AND SKIN MAY CAUSE ALLERGIC SKIN REACTION DANGER!

## 3. COMPOSITION/INFORMATION ON INGREDIENTS OSHA REGULATED COMPONENTS Component / CAS No. % Carcinogen 2-Propenenitrile, reaction products with 3-amino-1,5,5- trimethylcyclohexanemethanamine 90530-15-7 75 - 90 -

Isophoronediamine 2855-13-2 10 - 24 -

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## 4. FIRST AID MEASURES Eye Contact: Rinse immediately with plenty of water for at leas t 15 minutes. Obtain medical attention immediately. Skin Contact: Wash immediately with plenty of water and soap. Remo ve contaminated clothing and shoes without delay. Obtain medical attention. Do not reuse c ontaminated clothing without laundering. Destroy or thoroughly clean shoes before reuse. Ingestion: If swallowed, call a physician immediately. Only induce vomiti ng at the instruction of a phy sician. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If breathing is difficu lt, give oxygen. Apply artificial respiration if patient is not breathing. Obtain medical attention immediately.

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## 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use water spray or fog, carbon dioxide or dry chemical. Protective Equipment: Firefighters, and others exposed, wear se lf-contained breathing apparatus. Wear full fi refighting protective clothing. See MSDS Section 8 (Exposure C ontrols/Personal Protection). Special Hazards: Keep containers cool by spraying with water if exposed to fire.

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## 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Where exposure level is not known, w ear approved, positive pressure, self-cont ained respirator. Where exposure level is known, wear approved respirator suitable fo r level of exposure. In addition to the protective clothing/equipment in Section 8, wear a two piece PVC suit wi th hood or PVC overalls with hood. Methods For Cleaning Up: Cover spills with some inert absorbent. Sweep up into containers for disposal. Flush spill area with water. Environmental Precautions: None known Page 2 of 7 ZEH 2017 SDS: 0038053 Print Date: 06/26/2013−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 

## 7. HANDLING AND STORAGE HANDLING Precautionary Measures: Do not get in eyes, on skin or on clothing. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Special Handling Statements: Provide good ventilation of working area (local exhaust ventilation if necessary). During processing and handling of the product, comply with t he indicative occupational exposure limit values. STORAGE Store in a cool, dry, well ventilated place and keep container tightly closed. Observe the general rules of industrial fire protection. Storage Temperature: Store at 0 - 30 °C 32 - 86 °F Reason: Quality.



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## 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Utilize a closed system process where feasible. Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure. Respiratory Protection: For operations where inhalation exposure can occur, use an approved respirator recommended by an industrial hygienist after an evaluation of the operation. Where inhalation exposure cannot occur, no resp iratory protection is required. A full facepiece respirator also provides eye and face protection. Eye Protection: Prevent eye and skin contact. Provide eye wash fountain and safety shower in cl ose proximity to points of potential exposure. Wear eye/face protection such as c hemical splash proof goggles or face shield. Skin Protection: Prevent contamination of skin or cl othing when removing protective equipment. Wear impermeable gloves and suitable protective clothing. Hand Protection: Nitrile or fluorinated rubber gloves. Cons ider the porosity and elasticity data of the glove manufacturer and the specific conditons in the work place. Barrier creams may help to pr otect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves i mmediately when torn or any change in appearance (dimension, colour, flexibility etc) is noticed. Additional Advice: Food, beverages, and tobacco products should not be carried, stored, or consumed where this ma terial is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water.

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### Exposure Limit(s)
No values have been established.

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## 9. PHYSICAL AND CHEMICAL PROPERTIES Color: clear colorless to slightly yellow Appearance: liquid Odor: amine Boiling Point: 178 °C 352.4 °F Page 3 of 7 ZEH 2017 SDS: 0038053 Print Date: 06/26/2013

## 9. PHYSICAL AND CHEMICAL PROPERTIES Melting Point: -34 °C -29.2 °F Vapor Pressure: <0.01hPa @ 30 °C Specific Gravity/Density: 0.97 g/cm3 Vapor Density: Not available Percent Volatile (% by wt.): Not available pH: ~12 DIN ISO 976 Saturation In Air (% By Vol.): Not available Evaporation Rate: Not available Solubility In Water: Complete Volatile Organic Content: Not available Flash Point: >100 °C 212 °F DIN EN ISO 2719 Flammable Limits (% By Vol): Not available Autoignition Temperature: Not available Decomposition Temperature: Not availablePartition coefficient (noctanol/water): Not available
Odor Threshold: Not available



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## 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Protect from heat and direct sunlight. Polymerization: Will not occur Conditions To Avoid: None known Materials To Avoid: Isocyanates Epoxides, acrylates, strong oxidizers, acids, aldehydes, acetones, organic halides Hazardous Decomposition Products: acrylonitrile Nitrous gases Carbon dioxide Carbon monoxide (CO) Acrid smoke and irritating fumes. hydrogen cyanide (HCN)

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## 11. TOXICOLOGICAL INFORMATION Toxicological information for the product is found under Section 2. HAZARDS IDENTIFICATION. Toxicological information on the regulated components of this product is as follows:



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## 12. ECOLOGICAL INFORMATION Isophoronediamine has an acute oral (rat) LD50 value of 1030 mg /kg. Direct contact may cause severe eye and skin irritation. Isophoronediamine cause mark ed sensitization when tested in laboratory animals. Isophoronediamine was not mutagenic in the Ames assay. Print Date: 06/26/2013 Page 4 of 7

The toxicological properties of 2-propenenitrile, reaction products with 3-amino-1,5,5- trimethylcyclohexanemethanamine have not been fully investigated. Direct contact with this mate rial may cause severe eye and skin irritation. This material may be absorbed through the skin and may cause skin sensitization. ZEH 2017 SDS: 0038053

## 12. ECOLOGICAL INFORMATION This material is not classified as dangerous for the environmen t. The ecological assessment for this material is based on an evaluation of its components. ECOTOXICITY Not available

BIOACCUMULATIVE POTENTIAL Not available PERSISTENCE AND DEGRADABILITY Not available

MOBILITY IN SOIL Not available OTHER ADVERSE EFFECTS HAZARD TO THE OZONE LAYER Not available 

## 13. DISPOSAL CONSIDERATIONS The information on RCRA waste classification and disposal methodology provided below applies only to the product, as supplied. If the material has been altered or contaminat ed, or it has exceeded its re commended shelf life, the guidance may be inapplicable. Hazardous waste classification under federal regulations (40 CFR Part 261 et seq) is dependent upon whether a material is a RCRA "listed hazardous wast e" or has any of the four RCRA "hazardous waste characteristics." Refer to 40 CFR Part 261.33 to determine if a given material to be disposed of is a RCRA "listed hazardous waste"; information contained in Section 15 of this MS DS is not intended to indicate if the product is a "listed hazardous waste." RCRA Hazardous Waste C haracteristics: There are four characteristics defined in 40 CFR Section 261.21-61.24: Ignitability, Corrosivity, Reactivity, and Toxicity . To determine Ignitability, see Section 9 of this MSDS (flash point). For Corrosivity, see Sections 9 and 14 (p H and DOT corrosivity). For Reactivity, see Section 10 (incompatible materials). For Toxicity, see Section 3 (compos ition). Federal regulations are subject to change. State and local requirements, which may differ from or be more st ringent than the federal regulations, may also apply to the classification of the material if it is to be disposed. The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organic materials classified as RCRA hazardous wastes be disposed of by t hermal treatment or incineration at EPA approved facilities. The Company has provided the foregoing for information onl y; the person generating the waste is responsible for determining the waste classification and disposal method.

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## 14. TRANSPORT INFORMATION This section provides basic shipping classification informati on. Refer to appropriate transportation regulations for specific requirements. US DOT Dangerous Goods? X Proper Shipping Name: POLYAMIN ES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 ZEH 2017 SDS: 0038053 Print Date: 06/26/2013 Page 5 of 7Packing Group: III UN/ID Number: UN2735 Transport Label Required: Corrosive Technical Name (N.O.S.): Cyanethylated isophoronediamine

TRANSPORT CANADA Dangerous Goods? X Proper Shipping Name: POLYAMIN ES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 Packing Group: III UN Number: UN2735 Transport Label Required: Corrosive Technical Name (N.O.S.): Cyanethylated isophoronediamine

ICAO / IATA Dangerous Goods? X UN Proper Shipping Name: POLYAMIN ES, LIQUID, CORROSIVE, N.O.S. Transport Hazard Class: 8 Packing Group: III UN Number: UN2735 Transport Label Required: Corrosive Technical Name (N.O.S.): Cyanethylated isophoronediamine

IMO Dangerous Goods? X UN Proper Shipping Name: POLYAMIN ES, LIQUID, CORROSIVE, N.O.S. Transport Hazard Class: 8 UN Number: UN2735 Packing Group: III Transport Label Required: Corrosive Technical Name (N.O.S.): Cyanethylated isophoronediamine



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## 15. REGULATORY INFORMATION Inventory Information United States (USA): One or more components of this product are NOT included on the U.S. Toxic Substances Control Act (TSCA) Inventory. The chemical, physical, and toxicological properties of this material have not been fully investigated. Its handling or use may be hazardous , and it must be used under the supervision of technically qualified individuals. Materials not included on the TSCA Inventory may only be used for research and development (R&D) purposes or in other TSCA exempt activities. This product is manufactured for export only in compliance with Section 12(a) of the Toxic Substances Control Act, 15 U. S. C. 2601 et. seq. Canada: One or more components of this product are NOT included on the Canadian Domestic Substances List (DSL). European Economic Area (including EU): When purchased from a Allnex legal entity based in the EEA (EU or Norway), this product is compliant with the registra tion of the REACH Regulation (EC) No. 1907/2006 as all its components are either excluded, exemp t, pre-registered and/or registered. Australia: One or more components of this product have NO T yet been included in the Australian Inventory of Chemical Substances (AIC S) or assessed by NICNAS. ZEH 2017 SDS: 0038053 Print Date: 06/26/2013 Page 6 of 7China: All components of this product are included on the Chines e inventory or are not required to be listed on the Chinese inventory. Japan: All components of this product are included on the J apanese (ENCS) inventory or are not required to be listed on the Japanese inventory. Korea: One or more components of this product are NOT included on the Korean (ECL) inventory. Philippines: One or more components of this product are NOT included on the Philippine (PICCS) inventory. OTHER ENVIRONMENTAL INFORMATION The following components of this product may be subject to reporting requirements pursuant to Section 313 of CERCLA (40 CFR 372), Section 12(b) of TSCA, or may be subject to release reporting requirements (40 CFR 307, 40 CFR 311, etc.) See Section 13 for information on waste cl assification and waste disposal of this product. This product does not contain any components regulated under these sections of the EPA PRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARA • Acute



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## 16. OTHER INFORMATION NFPA Hazard Rating (National Fire Protection Association) Health: 3 - Materials that, under emergency condi tions, can cause serious or permanent injury. Fire: 1 - Materials that must be preheated before ignition can occur. Instability: 1 - Materials that in themselves are nor mally stable, but that can become unstable at elevated temperatures and pressures. Reasons For Issue: New Company Identification Date Prepared: 06/26/2013 Date of last significant revision: 06/01/2013

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