2007 Emission Inventory, WATER9 Inputs Unit Parameters

BP Products North America, Inc.

‐ Texas City Refinery



### Unit Name Parameter Water 9 Input

Wastewater Temperature ( o C) 29

Length of Aeration Unit (m) 56.8

Width of Aeration Unit (m) 56.8

Depth of Aeration Unit (m) 6.7

Area of Agitation (each aerator, m 2 ) 400

Total Number of Agitators in the Unit 5

Power of agitation (each aerator, HP) 150

Impeller Diameter (cm) 274.32

Impeller Rotation (RPM) 47

Agitator Mechanical Efficiency 0.83

Aerator Effectiveness, alpha 0.83

If there is a plug flow, enter 1 0

Overall Biorate (mg/g bio

‐ hour) 19

Aeration Air Flow (m 3 /s) 0.133

Activated Sludge Biomass (g/l) 3

If covered, then enter 1 0

Agitator Pump Rate (m 3 /s each) 4

pH 7.25

Wastewater Temperature ( o C) 29

Length of Aeration Unit (m) 56.8

Width of Aeration Unit (m) 56.8

Depth of Aeration Unit (m) 6.7

Area of Agitation (each aerator, m 2 ) 400

Total Number of Agitators in the Unit 5

Power of agitation (each aerator, HP) 150

Impeller Diameter (cm) 274.32

Impeller Rotation (RPM) 47

Agitator Mechanical Efficiency 0.83

Aerator Effectiveness, alpha 0.83

If there is a plug flow, enter 1 0

Overall Biorate (mg/g bio

‐ hour) 19

Aeration Air Flow (m 3 /s) 0.133

Activated Sludge Biomass (g/l) 3

If covered, then enter 1 0

Agitator Pump Rate (m 3 /s each) 4

pH 7.25 F

‐ 8 Activated Sludge Unit

F

‐ 9 Activated Sludge Unit

Page 1 of 32007 Emission Inventory, WATER9 Inputs Unit Parameters

BP Products North America, Inc.

‐ Texas City Refinery



### Unit Name Parameter Water 9 Input

Wastewater Temperature ( o C) 29

Secondary Clarifier Diameter (m) 42.7

Secondary Clarifier Depth (m) 5.5

Clarifier Solids Removal Efficiency 0.7

Waterfall Drop Height (cm) 20

Clarifier Weir/Circumference 1

Center Well Present, =1 0

Number of Identical Units in Parallel 0

pH 7.25

Wastewater Temperature ( o C) 29

Secondary Clarifier Diameter (m) 42.7

Secondary Clarifier Depth (m) 5.5

Clarifier Solids Removal Efficiency 0.7

Waterfall Drop Height (cm) 20

Clarifier Weir/Circumference 1

Center Well Present, =1 0

Number of Identical Units in Parallel 0

pH 7.25

Wastewater Temperature ( o C) 29

Open Surface Area of Tank (m 2 ) 89.4

Density of Liquid in Tank (g/cc) 1

Tank Waste Mol. Wt., water=18 18

Unit Storage Time (days) 0

Tank Paint Factor 1

Tank Diameter (m) 10.67

Tank Vapor Space Height (m) 2

Diurnal Temperature Change ( o C) 11

Tank Height (m) 6.1

Oil in Composite Wastewater (%) 0

pH 7.25

Wastewater Temperature ( o C) 29

Open Surface Area of Tank (m 2 ) 147.4113

Density of Liquid in Tank (g/cc) 1

Tank Waste Mol. Wt., water=18 18

Unit Storage Time (days) 0

Tank Paint Factor 1

Tank Diameter (m) 13.7

Tank Vapor Space Height (m) 2

Diurnal Temperature Change ( o C) 11

Tank Height (m) 12.2

Oil in Composite Wastewater (%) 0

pH 7.25 TK

‐ 22 Storage Tank

TK

‐ 30 Storage Tank F

‐ 10 Circular Clarifier

F

‐ 11 Circular Clarifier

Page 2 of 32007EmissionInventory,WATER9InputsChemicalParametersBPProductsNorthAmerica,Inc.‐TexasCityRefineryParameterMolecularWeight 100 17.03 78.11 106.2 83.1 128.2 104.2 92.4 120.2 106.2 106.2 106.17 120.19 120.21VaporPressure,mmHgat25oC 25 7470 95.2 10 185.949 0.23 7.3 30 2.4 8.5 8 7 0.73886 2.1Density 1 0.6818 0.874 0.87 0.97 1.14 0.9 0.87 1.02 1.02 0.86 0.88 1 0.876BoilingPoint(oC) 125‐33.4 80 136.2 64 218 145 110.7 163.037 140 139 144.4 157.876 169Antoine'sCoefficients,a 6.859312 7.55466 6.905048 6.975 6.85249 7.3729 6.945357 6.954 7.07436 7.940135 7.009 6.998 6.873484 8.178473Antoine'sCoefficients,b 1354.71 1002.711 1211.033 1424.255 1103.737 1968.36 1437.432 1344.8 1569.22 2090.317 1462.266 1474.679 1465.873 2342.421Antoine'sCoefficients,c 215.5096 247.885 220.7996 213.21 222.72 222.61 208.38 219.48 209.58 273.16 215.11 213.69 209.2632 273.16Henry'sLawConstantsKartkopf1973MSK,(y/x)25oC 1 3.3799 308.33 437.807 34.722 66.693 150.149 356.67 326.794 389.684 413 269.287 566.888 342.21K,(y/x)100oC10 0 1930 4270 267 710 1720 2100 1.13E+05 3786.025 3250 2550 6594.797 4285.293Dl(cm2/s) 9.57E‐06 6.93E‐05 1.02E‐05 7.80E‐06 1.05E‐05 7.50E‐06 8.00E‐06 8.60E‐06 8.67E‐06 9.34E‐06 7.80E‐06 1.00E‐05 8.57E‐06 7.92E‐06Dv(cm2/s) 0.0782 0.259 0.088 0.075 0.1024 0.059 0.071 0.087 0.0602 0.0737 0.07 0.087 0.0643 0.0606Solubility(ppmw) 210.297 4.82E+05 1796.573 152 3.66E+04 80.318 300 515 2 169.334 200 175 11.451 57HydrolysisRate(l/s) 0 5.60E‐10 0 0 5012 0 0 0 0 0.091 0.07 0.12 0 0Log10Octanol‐Water 0 0.23 2.15 3.15 0.94 3.37 3.16 2.69 3.9997 3.15 3.2 2.95 3.5953 3.63Kmax(mg/g‐hr) 19 19 19.1 6.8 17.56 42.47 31.1 73.48 31.1 40.8 31.1 40.79 15.3 15.3K1(l/g‐hr)1.1 0.043 120 2.1 0.712684 1 0.11 2.4 4.469394 1.8 2.219942 1.8 3.137307 3.23402GenericOrganicMaterialBenzeneMeasured‐Ind.Estim.Yaws&Yang,1992SAmmonia Ethylbenzene MTBE NaphthalenePropylbenzene 1,2,4‐TMBXylene(m‐)Styrene TolueneYaws&Yang,1992S SuperfundYaws&Yang,1992SMackay&Shiu1981LSYaws&Yang,1992S1,3,5‐TMB XyleneMackay&Shiu1981LSDIPPR911Sanemasa(1982)Staudingner1996LSRTIXylene(o‐)DIPPR911Page 3 of 3