SDS: 0038053

Date Prepared: 06/26/2013

MATERIAL SAFETY DATA SHEET

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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: ZEH 2017

Synonyms: None

Chemical Family: Aliphatic amine

Molecular Formula: Mixture

Molecular Weight: Mixture

Allnex USA Inc., 1950 Lake Park Drive, Smyrna, Georgia 30080, USA

For Product and all Non-Emergency Information call +1-678-255-4691 or contact us at: http://www.allnex.com/contact

EMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call:

Asia Pacific (Carechem 24):

 Australia: +61 2801 44558

 China (PRC): +86 10 5100 3039

 Japan: +81 345 789 341

 New Zealand: +64 9929 1483

 All Others: +65 3158 1074

Europe/Africa/Middle East (Carechem 24):

 Europe, Middle East, Africa, Israel: +44 (0) 1235 239 670

 Middle East, Africa (Arabic speaking countries): +44 (0) 1235 239 671

Latin America (Carechem 24):

 Brazil: +55 113 711 9144

 Mexico and all others: +52-555-004-8763

Canada and USA (Carechem 24 - NCEC ED29003275): +1-866-928-0789 (toll free) or +1-215-207-0061

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2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

APPEARANCE AND ODOR:

Color: clear colorless to slightly yellow

Appearance: liquid

Odor: amine

STATEMENTS OF HAZARD:

POTENTIAL HEALTH EFFECTS

EFFECTS OF EXPOSURE:

The estimated acute oral (rat) LD50, acute dermal (rabbit) LD50 and 4-hour inhalation (rat) LC50 values for this

material are 500 mg/kg, 4580 mg/kg and 1.6 mg/l, respectively. Direct contact with this material may cause eye and

skin burns. Repeated or prolonged dermal contact may cause allergic skin reactions. Refer to Section 11 for

toxicology information on the regulated components of this product.

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HARMFUL IF SWALLOWED

HARMFUL IF INHALED

CAUSES BURNS OF EYES AND SKIN

MAY CAUSE ALLERGIC SKIN REACTION

DANGER!
3. COMPOSITION/INFORMATION ON INGREDIENTS

OSHA REGULATED COMPONENTS

Component / CAS No. % Carcinogen

2-Propenenitrile, reaction products with 3-amino-1,5,5-

trimethylcyclohexanemethanamine

90530-15-7

75 - 90 -

Isophoronediamine

2855-13-2

10 - 24 -

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4. FIRST AID MEASURES

Eye Contact:

Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention immediately.

Skin Contact:

Wash immediately with plenty of water and soap. Remove contaminated clothing and shoes without delay. Obtain

medical attention. Do not reuse contaminated clothing without laundering. Destroy or thoroughly clean shoes before

reuse.

Ingestion:

If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by

mouth to an unconscious person.

Inhalation:

Remove to fresh air. If breathing is difficult, give oxygen. Apply artificial respiration if patient is not breathing. Obtain

medical attention immediately.

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5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media:

Use water spray or fog, carbon dioxide or dry chemical.

Protective Equipment:

Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See

MSDS Section 8 (Exposure Controls/Personal Protection).

Special Hazards:

Keep containers cool by spraying with water if exposed to fire.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions:

Where exposure level is not known, wear approved, positive pressure, self-contained respirator. Where exposure level is

known, wear approved respirator suitable for level of exposure. In addition to the protective clothing/equipment in Section

8, wear a two piece PVC suit with hood or PVC overalls with hood.

Methods For Cleaning Up:

Cover spills with some inert absorbent. Sweep up into containers for disposal. Flush spill area with water.

Environmental Precautions:

None known

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7. HANDLING AND STORAGE

HANDLING

Precautionary Measures: Do not get in eyes, on skin or on clothing. Avoid prolonged or repeated contact with skin.

Avoid breathing vapor.

Special Handling Statements: Provide good ventilation of working area (local exhaust ventilation if necessary). During

processing and handling of the product, comply with the indicative occupational exposure limit values.

STORAGE

Store in a cool, dry, well ventilated place and keep container tightly closed. Observe the general rules of industrial fire

protection.

Storage Temperature: Store at 0 - 30 °C 32 - 86 °F

Reason: Quality.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures:

Utilize a closed system process where feasible. Where this material is not used in a closed system, good enclosure and

local exhaust ventilation should be provided to control exposure.

Respiratory Protection:

For operations where inhalation exposure can occur, use an approved respirator recommended by an industrial hygienist

after an evaluation of the operation. Where inhalation exposure cannot occur, no respiratory protection is required. A full

facepiece respirator also provides eye and face protection.

Eye Protection:

Prevent eye and skin contact. Provide eye wash fountain and safety shower in close proximity to points of potential

exposure. Wear eye/face protection such as chemical splash proof goggles or face shield.

Skin Protection:

Prevent contamination of skin or clothing when removing protective equipment. Wear impermeable gloves and suitable

protective clothing.

Hand Protection:

Nitrile or fluorinated rubber gloves. Consider the porosity and elasticity data of the glove manufacturer and the specific

conditons in the work place. Barrier creams may help to protect the exposed areas of the skin, they should however not

be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension,

colour, flexibility etc) is noticed.

Additional Advice:

Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before

eating, drinking, or smoking, wash face and hands thoroughly with soap and water.

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Exposure Limit(s)

No values have been established.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Color: clear colorless to slightly yellow

Appearance: liquid

Odor: amine

Boiling Point: 178 °C 352.4 °F

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9. PHYSICAL AND CHEMICAL PROPERTIES

Melting Point: -34 °C -29.2 °F

Vapor Pressure: <0.01hPa @ 30 °C

Specific Gravity/Density: 0.97 g/cm3

Vapor Density: Not available

Percent Volatile (% by wt.): Not available

pH: ~12 DIN ISO 976

Saturation In Air (% By Vol.): Not available

Evaporation Rate: Not available

Solubility In Water: Complete

Volatile Organic Content: Not available

Flash Point: >100 °C 212 °F DIN EN ISO 2719

Flammable Limits (% By Vol): Not available

Autoignition Temperature: Not available

Decomposition Temperature: Not available

Partition coefficient (noctanol/water):

Not available

Odor Threshold: Not available

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10. STABILITY AND REACTIVITY

Stability: Stable

Conditions To Avoid: Protect from heat and direct sunlight.

Polymerization: Will not occur

Conditions To Avoid: None known

Materials To Avoid: Isocyanates

Epoxides, acrylates, strong oxidizers, acids, aldehydes, acetones, organic halides

Hazardous Decomposition

Products:

acrylonitrile

Nitrous gases

Carbon dioxide

Carbon monoxide (CO)

Acrid smoke and irritating fumes.

hydrogen cyanide (HCN)

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11. TOXICOLOGICAL INFORMATION

Toxicological information for the product is found under Section 2. HAZARDS IDENTIFICATION.

Toxicological information on the regulated components of this product is as follows:

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12. ECOLOGICAL INFORMATION

Isophoronediamine has an acute oral (rat) LD50 value of 1030 mg/kg. Direct contact may cause severe eye and skin

irritation. Isophoronediamine cause marked sensitization when tested in laboratory animals. Isophoronediamine was not

mutagenic in the Ames assay.

Print Date: 06/26/2013 Page 4 of 7

The toxicological properties of 2-propenenitrile, reaction products with 3-amino-1,5,5-trimethylcyclohexanemethanamine

have not been fully investigated. Direct contact with this material may cause severe eye and skin irritation. This material

may be absorbed through the skin and may cause skin sensitization.

ZEH 2017 SDS: 0038053
12. ECOLOGICAL INFORMATION

This material is not classified as dangerous for the environment. The ecological assessment for this material is based on

an evaluation of its components.

ECOTOXICITY

Not available

BIOACCUMULATIVE POTENTIAL

Not available

PERSISTENCE AND DEGRADABILITY

Not available

MOBILITY IN SOIL

Not available

OTHER ADVERSE EFFECTS

HAZARD TO THE OZONE LAYER

Not available

13. DISPOSAL CONSIDERATIONS

The information on RCRA waste classification and disposal methodology provided below applies only to the product, as

supplied. If the material has been altered or contaminated, or it has exceeded its recommended shelf life, the guidance

may be inapplicable. Hazardous waste classification under federal regulations (40 CFR Part 261 et seq) is dependent

upon whether a material is a RCRA "listed hazardous waste" or has any of the four RCRA "hazardous waste

characteristics." Refer to 40 CFR Part 261.33 to determine if a given material to be disposed of is a RCRA "listed

hazardous waste"; information contained in Section 15 of this MSDS is not intended to indicate if the product is a "listed

hazardous waste." RCRA Hazardous Waste Characteristics: There are four characteristics defined in 40 CFR Section

261.21-61.24: Ignitability, Corrosivity, Reactivity, and Toxicity. To determine Ignitability, see Section 9 of this MSDS

(flash point). For Corrosivity, see Sections 9 and 14 (pH and DOT corrosivity). For Reactivity, see Section 10

(incompatible materials). For Toxicity, see Section 3 (composition). Federal regulations are subject to change. State and

local requirements, which may differ from or be more stringent than the federal regulations, may also apply to the

classification of the material if it is to be disposed. The Company encourages the recycle, recovery and reuse of

materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organic materials

classified as RCRA hazardous wastes be disposed of by thermal treatment or incineration at EPA approved facilities.

The Company has provided the foregoing for information only; the person generating the waste is responsible for

determining the waste classification and disposal method.

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14. TRANSPORT INFORMATION

This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific

requirements.

US DOT

Dangerous Goods? X

Proper Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.

Hazard Class: 8

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Packing Group: III

UN/ID Number: UN2735

Transport Label Required: Corrosive

Technical Name (N.O.S.): Cyanethylated isophoronediamine

TRANSPORT CANADA

Dangerous Goods? X

Proper Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.

Hazard Class: 8

Packing Group: III

UN Number: UN2735

Transport Label Required: Corrosive

Technical Name (N.O.S.): Cyanethylated isophoronediamine

ICAO / IATA

Dangerous Goods? X

UN Proper Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.

Transport Hazard Class: 8

Packing Group: III

UN Number: UN2735

Transport Label Required: Corrosive

Technical Name (N.O.S.): Cyanethylated isophoronediamine

IMO

Dangerous Goods? X

UN Proper Shipping Name: POLYAMINES, LIQUID, CORROSIVE, N.O.S.

Transport Hazard Class: 8

UN Number: UN2735

Packing Group: III

Transport Label Required: Corrosive

Technical Name (N.O.S.): Cyanethylated isophoronediamine

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15. REGULATORY INFORMATION

Inventory Information

United States (USA): One or more components of this product are NOT included on the U.S. Toxic Substances

Control Act (TSCA) Inventory. The chemical, physical, and toxicological properties of this material have not been

fully investigated. Its handling or use may be hazardous, and it must be used under the supervision of technically

qualified individuals. Materials not included on the TSCA Inventory may only be used for research and

development (R&D) purposes or in other TSCA exempt activities.

This product is manufactured for export only in compliance with Section 12(a) of the Toxic Substances Control Act,

15 U. S. C. 2601 et. seq.

Canada: One or more components of this product are NOT included on the Canadian Domestic Substances List

(DSL).

European Economic Area (including EU): When purchased from a Allnex legal entity based in the EEA (EU or

Norway), this product is compliant with the registration of the REACH Regulation (EC) No. 1907/2006 as all its

components are either excluded, exempt, pre-registered and/or registered.

Australia: One or more components of this product have NOT yet been included in the Australian Inventory of

Chemical Substances (AICS) or assessed by NICNAS.

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China: All components of this product are included on the Chinese inventory or are not required to be listed on the

Chinese inventory.

Japan: All components of this product are included on the Japanese (ENCS) inventory or are not required to be

listed on the Japanese inventory.

Korea: One or more components of this product are NOT included on the Korean (ECL) inventory.

Philippines: One or more components of this product are NOT included on the Philippine (PICCS) inventory.

OTHER ENVIRONMENTAL INFORMATION

The following components of this product may be subject to reporting requirements pursuant to Section 313 of CERCLA

(40 CFR 372), Section 12(b) of TSCA, or may be subject to release reporting requirements (40 CFR 307, 40 CFR 311,

etc.) See Section 13 for information on waste classification and waste disposal of this product.

This product does not contain any components regulated under these sections of the EPA

PRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARA

• Acute

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16. OTHER INFORMATION

NFPA Hazard Rating (National Fire Protection Association)

Health: 3 - Materials that, under emergency conditions, can cause serious or permanent injury.

Fire: 1 - Materials that must be preheated before ignition can occur.

Instability: 1 - Materials that in themselves are normally stable, but that can become unstable at elevated

temperatures and pressures.

Reasons For Issue: New Company Identification

Date Prepared: 06/26/2013

Date of last significant revision: 06/01/2013

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This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission,

inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and

verification. Before using any product, read its label.

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