## 1 Arizona Department of Environmental Quality AQS Data Certification Detail Report In April 2012, EPA Region 9 performed a Tech nical Systems Audit (TSA) of the ADEQ Air Monitoring Program. The first finding of the a udit report was that ADEQ does not have Quality Assurance Project Plans (QAPPs) for O 3 

## , SO 2 

## , NO 2 

## , CO, and NCore monitoring; QAPPs for PM 10 

## and PM 2.5 

## are outdated. ADEQ provided a corr ective action plan to EPA on March 28, 2013 indicating that ADEQ was committed to deve loping or updating QAPPS with the goal of having approvable plans for all criteria polluta nts in place and submitted to EPA as soon as possible. The proposed schedule was: PM NAAQS QAPP June 28, 2013 SO2 QAPP September 30, 2013 Ozone QAPP October 31, 2013 NO2 and CO QAPPs December 13, 2013 Specialized PM QAPP addendum February 28, 2014 Trace level addendum for CO and SO2 April 30, 2014 We understand the importance of having data that ar e used directly for regulatory purposes to be collected under approved QAPPs. We are applying additional resource s to this effort to expedite the timeliness of completion and are committed to meeting the above schedule. The NAAQS monitoring for CY2014 should all be collected under developed QAPPs. We will continue to work with Region 9 sta ff to meet our QAPP requirement, however, we believe the absence of these QAPPs does not prevent certification of 2012 data under the definition “...that the previous year of ambient concentration and quality assurance data are completely submitted to AQS and that the ambient concentration data are accurate to the best of her or his knowledge, taking into consideration the quality assurance findings” as addressed in the following certification report. SECTION 1 2012 ADEQ DATA TO BE CERTIFIED Tables 1, 2, and 3 in Appendix A list monitors with data reported to AQS requiring certification for the year 2012. They include several specia l purpose monitors (SPM), ADEQ’s State and Local Agency Monitoring Sta tion (SLAMS) monitors, monito rs in the Photochemical Assessment Monitoring Sta tions (PAMS) program, PM 2.5 

## Chemical Speciation Network (CSN) monitors, National Air Toxics Trends Sites (NATTS) monitors, and Urban Air Toxics Monitoring Program (UATMP) monitors. A detail ed description of these data and monitors follows.

## 2 1.1 2012 CRITERIA POLLUTANT DATA FR OM ADEQ SLAMS and SPM SITES Table 1 in Appendix A lists the sites and paramete rs with 2012 data that ADEQ reported to AQS after completing our data review procedur es. Appendix B includes the AQS AMP600 and AMP450NC reports verifying submittal completene ss of the 2012 data for these monitors. While most of the data summarized in the at tached reports are accurate and complete, ADEQ staff did encounter some challenges throughout the year. The following is a description of these challenges as well as some clarifications. 1.1.1 Ozone Monitoring After the issues in 2011 with the internal ozone calibra tors, Air Monitoring staff decided to use the external Thermo 49C Ozone Ca librators with an external zero air source. The addition of a second inline filter has proven effective in preven ting particulate matter build-up of the sample lines and internal plumbing. This is supported by the data completeness percentage of 100% for 6 of our 7 ozone sites. The seventh site had 95 % data completeness as a result of a single failed bi-weekly zero/span/precision check invalidating 16 days of data. ADEQ is updating the Ozone network with remo te zero/span/precision checks utilizing the Teledyne T703 UV Photometric Ozone Calibrator w ith Internal Zero Ai r Pump and External Zero Air Shut-Off Valve. Please refer to our 2013 Annual Air Monitoring Network Plan for more information. 1.1.2 Carbon Monoxide Trace Level (COTL) Monitoring at ADEQ’s NCore site, JLG Supersite ADEQ operates a trace level car bon monoxide (CO) monitor at th e JLG Phoenix Supersite (AQS ID 04-013-9997) as part of the NCore requireme nts. The COTL analyzer as well as the gas calibration system experienced some difficulties throughout the year. This was observed with the COTL not always meeting the 30ppb acceptance cr iteria during zero drift verification checks. Nearly 50% of these zero drift checks were between 30-100ppb. Additionally, there were moisture issues with the zero air scrubbers for th e gas calibration system used to perform checks. This was discovered and corrected late in the year and as a result a ll of the 2012 data were flagged with the Q2 (Operational Deviations) qu alifier flag. ADEQ does not wish to certify these Carbon Monoxide Trace Level data for CY 2012. ADEQ has purchased and installed a new Carbon Monoxide Trace Level instrument in Ap ril 2013 that is expected to better meet operational requirements. 1.1.3 Nogales Post Office PM 10 

## and PM 2.5 

## Instruments During fourth quarter, the roof at the Nogales Po st Office Site where the instruments are located was under construction. All instruments were removed and inoperable from 11/20/12 to 12/13/12. There was a further issue with the PM 2.5 

## Secondary sampler (AQS ID 04-023-0004- 88101-2) at this site which result ed in further data loss. Despite data completeness for CY2012 being above 75% (85%), this monitor fell short of the 75% quarterly comp leteness criteria in the 4 th 

## quarter of 2012 (60%). Three samples during this quarter were invalidated due to instrument

## 3 clock issues that resulted in 1- Hr off-set sample start and stop times; i.e., these samples ran from 0100-0100 rather than the required midnight -to-midnight sampling criteria. 1.1.4 Douglas Red Cross PM 10 

## Sampler The Douglas Red Cross PM 10 

## sampler (AQS ID 04-003-1005-81102- 1) did not meet the data completeness criteria required for PM 10 

## SLAMS in the second qua rter. Despite data completeness for CY2012 being above 75% (91%), th is monitor fell short of the 75% quarterly completeness criteria in the 2 nd 

## quarter of 2012 (73%). Six run days during this quarter were invalidated due to the routine flow verifica tion failure in April 2012. ADEQ has invested heavily in continuous monitors and replaced this sampler with a TEOM PM 10 

## which was officially designated the primary samp ler for this site on January 1, 2013. 1.1.5 JLG Supersite Continuous PM 10 

## TEOM Monitor The PM 10 

## TEOM at JLG Supersite operated from January 1, 2012 through July 26, 2012. The instrument was primarily run for continuous method comparability and bias statistical analysis. Although this instrument was not audited in 2012, an audit of th e instrument was performed on December 8, 2011. This instrument shows good da ta completeness for the half year it was operational at JLG Supersite and the verifications performed show the instrument was operating within specifications for PM 10 

## . Paired BAM monitors were inst alled in November, 2010 to meet the PM coarse 

## requirement at ADEQ’s NCore site. Th e data from these BAM monitors have confirmed the suspected biases in the PM 10 

## TEOM data. Due to satisf actory performance of the PM 10 

## BAM instrument, ADEQ monitoring staff removed the PM 10 

## unit from operation on July 26, 2012. 1.1.6 PM 10 

## and PM 2.5 

## Semi-Annual Flow Audit Completeness As mentioned above, the JLG Supersite PM 10 

## TEOM did not receive a flow rate audit in 2012 however due to the partial year operation and a flow rate audit perfor med in December of 2011, the data are deemed to be accurate and complete to the best of our knowledge. There were two other monitors in 2012 which were flagged yellow for only having 70% Flow Audit completeness in th e AMP600 report in the PM 10 

## Total 0-10um STP (81102) INTERMITTENT section. These are the Payson Well Site monitors (04-007-0008-1 and 04- 007-0008-2). They are a collocated pair of Part isol 2000 monitors and both received two flow rate audits in 2012, but due to scheduling conflict s they were audited ou tside of the 5-7 month report criteria. These instruments were bot h audited on June 28, 2012 and then again on November 8, 2012; technically there was not exac tly 5 months between the audit dates which resulted in the AMP600 flagging this data. I certi fy that for the monitors listed in Table 1 and Attachments # 1 and # 2, the ambient concentra tion data and the quality assurance data are completely submitted to AQS and that the ambi ent data are accurate to the best of my knowledge, taking into consideratio n the quality assurance findings.

## 4 1.1.7 Lead (Pb) Performance Evaluation Program (PEP) Data As can be seen in the AMP600 report, the recommendation for the Lead PM10 LC FRM/FEM (85129) is to not certify the NC ore required monitoring data. This is based solely on the Analysis Audit Summary having 50% completene ss. The 50% completeness is due to the method code only being approved for the second half way of the year. The other flagged criterion is the NCore Lead PM10 LC FRM/FE M collocation percent complete which is not required at JLG Supersite. ADEQ believes these da ta to be accurate and complete for the second half of 2012 and certify these data. 1.1.8 Freeport McMoRan PM 10 

## Data As can be seen in the AMP600 report, the PM 10 

## collocation summary data from the Miami Golf Course site (AQS ID 04-007-8000) shows a colloca tion CV of 17.04 and this statistic is flagged yellow. These instruments are operated by an independent contractor for Freeport McMoRan Miami, Inc. (1357). ADEQ became aware of so me issues with the Miami Golf Course collocation numbers toward the end of CY2011 and into the 1 st 

## quarter of 2012. While the differences in the collocated values were larger than normal for this period, the calculated CV is representative of the precision of the PM 10 

## data. For any data be ing used for regulatory purposes, ADEQ urges the use of these QC metr ics to help determine potential error in the ambient concentration data. Although we do not control the integrity of these samples the AMP600 would recommend these data be ce rtified with an approved QAPP on file. As indicated in the 2011 Network Plan, ADEQ met with Freeport-McMoRan to discuss the role of Primary Quality Assurance Operator for the Golf Course PM10, Townsite SO 2 

## and Jones Ranch SO 2 

## monitors that are submitted to AQS fo r NAAQS compliance determinations. It was decided that ADEQ would install instruments at these sites, perform the PQAO requirements and submit these data to AQS. ADEQ installed mon itors at these sites in 2012. Data is being collected from both the FMMI a nd ADEQ monitors at these site s for at least one year for comparability analysis. 1.2 2012 DATA FROM ADEQ PAMS MONITORS In 2012, ADEQ operated three sites (see Table 2 in Appendix A) for the collection of ozone, trace level reactive oxi des of Nitrogen (NO y 

## ), volatile organic compounds (VOCs), carbonyls, and meteorology to comply with PAMS requirements. ADEQ contracts the laboratory analysis of thei r VOC and carbonyl samples to Eastern Research Group (ERG). ADEQ staff review th e data and then give permission to ERG to load the data to AQS upon approval. ADEQ reports meteorology data to AQS from a ll three sites to suppor t the PAMS program. Standard meteorology data (ambient temper ature, relative humidity, wind speed and wind direction) are collected and re ported from the JLG Supersite (AQS ID 04-013-9997) and Queen Valley site (AQS ID 04-021-8001) while solar radi ation and ultra violet radiation data are collected and reported from the Vehicle Emissi ons Laboratory site ( AQS ID 04-013-9998).

## 5 Although the annual meteorological data set is complete for JLG Supersite (AQS ID 04-013- 9997) and Vehicle Emissions Laboratory site (AQS ID 04-013-9998), there was a data logger issue at the Queen Valley site (AQS ID 04- 021-8001). Beginning on 3/29/2012 at 15:00, the clock on the Campbell LoggerNet jumped to an in correct date-time stamp. This issue was not corrected until 4/6/2012 at 10:00. Al l the associated meteorological data was invalidated and the result can be seen in the data completeness for the Wind Speed (61103) and Relative Humidity (62201) parameters in the AMP450NC. The AMP450NC report in Appendix B includes an annual summary of the PAMS parameters collected at these sites. Currently, the data from the RASS sampler (wind profiler) are not submitted to AQS due to the complexity of the data. No precision or accuracy data are required to be reported to AQS for the PAMS data. Routine checks and audits of the meteorological equipmen t are conducted and are used to validate the meteorological data before submitting to AQS. All PAMS data were carefully reviewed by our DM&QA staff with special attention to the quality control checks that were av ailable. I certify that for the m onitors listed in Table 2 and the AMP450NC report in Appendix B, the ambient concentration data and required quality assurance data are completely submitted to AQS a nd that the ambient data are accurate to the best of my knowledge taking into consideration the qua lity assurance findi ngs. This letter does not certify ERG (the analyzing la boratory) operations si nce those are not within ADEQ’s control. 1.3 2012 DATA FROM ADEQ CS N AND NATTS MONITORS Table 3 in Appendix A lists the monitors that are part of the CSN and NATTS monitoring programs. 1.3.1 PM 2.5 

## Chemical Speciation Network (CSN) ADEQ participates in the CSN program with two monitors operating at the JLG Supersite (Met One Super SASS and URG samplers). The samples from these monitors are processed by Research Triangle Institute (RT I). ADEQ reviews the data resu lts each month before RTI loads the data into their AQS screening group. The AMP450NC report in Appendix B includes an annual summary of these data. Monthly quality control checks, annual calibra tions, and quarterly au dits are performed by ADEQ staff on the samplers. Until recently, ther e was is no mechanism to report these QA data to RTI or to enter these data in to the AQS. RTI has since develope d a tool for agencies to upload the monthly flow verification and au dit data to their website. From there, the data are loaded to EPA’s AQS database. For CY2012, ADEQ DM&QA st aff successfully loaded all monthly flow verification and quarterly flow a udit data to the RTI website, which was in turn loaded to the AQS database. This letter certifies that the m onitors were operated in accordance with the EPA QAPP for this program and proper and regular main tenance of the monitors occurred to ensure

## 6 accurate data collection. Howeve r, this letter does not certify RTI operations since those are not within ADEQ’s control. 1.3.2 National Air Toxics Trends Sites (NATTS) 1.3.2.1 PM 10 

## Metals Speciation In 2006, ADEQ began PM 10 

## Metals Speciation monitoring at th e JLG Supersite. In the past, filters used for PM 10 

## NAAQS compliance were first quality assured and weighed internally for PM 10 

## mass concentration and then sent to the ERG laboratory in quart erly batches for PM 10 

## speciation analysis. This result ed in significant delays in PM 10 

## speciation data reporting. Beginning July 1 st 

## , 2009, ADEQ used a continuous PM 10 

## FEM monitor as the primary PM 10 

## monitor for NAAQS compliance, but c ontinued to use the filter-based PM 10 

## monitor for PM 10 

## speciation purposes. This allowed for a more timely analysis of PM 10 

## speciation data by ERG (the analyzing laboratory). ADEQ reviews the data results before ERG reports the data into their AQS screening group. The AMP450NC report in Appendix B includes an annual summary of these data. Routine flow verifications, semi-annual calib rations, and semi-annual flow audits were performed on this monitor throughout CY 2012. These QC data had been reported to AQS in association with the PM 10 

## data that had previously been repo rted. However, with the closure of the PM 10 

## filter-based monitor in AQS, these QC data are no longer able to be reported. This letter certifies that the PM 10 

## Metals Speciation monitor wa s operated according to ADEQ’s QAPP for ‘ National Air Toxics Trends Stations , Air Toxics Monitoring Program, & Photochemical Assessment Monitoring Stations ’. This letter does not certify ERG operations since those are not within ADEQ’s control. 1.3.2.2 Chrome VI In 2006, ADEQ began collection of Chrome VI (Hexavalent Chromium) samples at the JLG Supersite. Sample media are provided by ERG and returned to them for analysis. ADEQ’s DM&QA staff reviews the data re sults before ERG reports the da ta into their AQS screening group. The AMP450NC report in Appendix B in cludes an annual summary of these data. Audit procedures for this monitor were devel oped in 2007 and implemented in the field in 2008 and continued into CY2012. Additionally, flow checks and maintenance on the monitor were performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for ‘ National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical Assessment Monitoring Stations ’. All Chrome VI data were carefully reviewed by our Data Management & QA staff with special attention to th e quality control checks that were available. This letter certifies that the monitor was opera ted following standard operating procedures, and proper and regular maintenance of the monitor occu rred to ensure accurate data collection. This letter does not certify ERG operations since those are not within ADEQ’s control. 1.3.2.3 Semi-volatile Organic Compounds (SVOCs)

## 7 In July of 2007, ADEQ began collection of se mi-volatile organic compounds at the JLG Supersite using a PUF sampler. Sample media are provided by ERG and returned to them for analysis. The DM&QA staff reviews the data resu lts before ERG reports the data into their AQS screening group. The AMP450NC report in Appendi x B includes an annual summary of these data. No precision data are reported to AQS from the PU F sampler. Audit procedures for this monitor were developed in 2010 and implemented in th e field. Audits on the PUF sampler were conducted four times in 2012. Routine flow checks and maintenance on the monitor were also performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for ‘ National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical Assessment Monitoring Stations ’. All SVOC data were carefully reviewed by our DM&QA staff with special attention to the quali ty control checks that were available. This letter certifies that the monitor was operated following standard op erating procedures, a nd proper and regular maintenance of the monitor occurre d to ensure accurate data co llection. This letter does not certify ERG operations since those are not within ADEQ’s control. 1.3.2.4 Volatile Organic Compounds (VOCs) and Carbonyls VOC and carbonyl data are collect ed at the JLG Supersite as pa rt of the NATTS program. VOC data are also collected at th e South Phoenix site (AQS ID 04-013-4003), which is part of the Urban Air Toxics Monitoring Program (UATMP). These monitors are operated by ADEQ staff and the samples are analyzed at ERG. The da ta are then reviewed by ADEQ’s DM&QA staff before ERG loads the data to AQS. The AM P450NC report in Appendix B includes an annual summary of these data. No precision data are reported to AQS from the VOC and Carbonyl samplers and audit procedures for these monitors have not yet be en developed. All VOC and Carbonyl data were carefully reviewed by our DM&QA staff with special attention to the quality control checks that were available. This letter does not certify ERG operations si nce those are not within ADEQ’s control. Taking into consideration the excep tions mentioned in Section 1.3, I certify that for the monitors listed in Tables 2 and 3, and included in Appe ndix B, the ambient con centration data and the required quality assurance data are completely submitted to AQS and that the ambient data are accurate to the best of my knowledge, taking into consideration the quality assurance findings.

## 8 SECTION 2 ADEQ DATA TO BE RE-CERTIFIED Table 4 in Appendix A list monitor with data reported to AQS requiri ng re-certification for CY2011. 2.1 JLG Supersite NO 2 

## 2011 Monitoring Data ADEQ certified 2011 NO 2 

## data collected from JLG Supersit e in September, 2012. After learning of an exceedance value and further investigati on, it was discovered that the data value in question was reported during a zero/span/precision check on the instrument. The data point was accidentally validated, qualified and loaded to AQS. This data has since been invalidated and I certify that for the monitor listed in Table 4, and included in Appendix B as the 2011 AMP600, the ambient concentration data and the required quality assurance data are completely submitted to AQS and that the ambient data are accurate to the best of my knowledge, taking into consideration the qual ity assurance findings.

## APPENDIX A

## Table 1. 2012 Data to be certified in AQS from ADEQ Criteria Pollutant Monitors

X – Submitted to AQS C 

## – Collocated monitors (POCs 1 & 2) CC 

## – Collocated Continuous monitors (POCs 3 & 4) N – ADEQ does not wish to certify these data due to data quality issues SLAMS & SPMs Criteria Pollutant Parameters

AQS Site ID Site Name ClassificationPb, Temp, Pres 1-in-614129, 68105, 68108Pb, PM10LC FRM/FEM1-in6days 85129O344201CO 42101NO, NO2, NOx42601,42602,42603 (POC1)SO2& SO25 Min Max42401 & 42406PM1081102, 85101 1-in-6daysPM1081102 Hourly(POC 3 and/or POC 4)PM2.5Hourly 88500, 88501(POC 3)PM2.5Hourly 88101(POC 3)PM2.5,Temp, Pres. 1-in-6and 1-in-3 days 88101,68105, 68108



## 04-003-0011 Paul Spur Chemical Lime Plant SLAMS X X 04-003-1005 Douglas Red Cross SLAMS X X 04-005-1008 Flagstaff Middle School SLAMS X X X 04-007-0008 Payson Well Site SLAMS X C 

## 04-007-0009 Miami Ridgeline (ADEQ) SLAMS X 04-007-0009 Miami Ridgeline (Freeport McMoRan) SLAMS X 04-007-0010 Tonto National Monument SLAMS X 04-007-1001 Hayden Old Jail SLAMS X X 04-007-8000 Miami Golf Course (Freeport McMoRan) SLAMS X C 

## 04-007-8000 Miami Golf Course (ADEQ) SLAMS X X 04-007-1002 Globe Highway SLAMS X C 

## 04-012-8000 Alamo Lake SLAMS X 04-013-9997 JLG Supersite SLAMS / NCORE X X N X X X CC 

## N X X 04-015-1003 Bullhead City SLAMS X X 04-019-0001 Ajo SLAMS X 04-019-0020 Rillito SLAMS X 04-021-8001 Queen Valley SLAMS X 04-023-0004 Nogales Post Office SLAMS / SPM X X N N X C 

## 04-025-2002 Prescott Valley SLAMS / SPM X X 04-025-8033 Prescott College AQD SLAMS X 04-027-8011 Yuma Supersite SLAMS / SPM X X X

## Table 2. 2012 Data to be certified in AQS from ADEQ PAMS Parameters PAMS Parameters

Site Name AQS ID PAMS Site TypeVOCsCarbonylsO344201NOY42600Wind Speed 61103Wind Direction 61104Temperature 62101Relative Humidity 62201Solar Radiation 63301Ultraviolet Radiation 63302Radar Acoustic Sounding System(RASS, profiler)



## Phoenix – JLG Supersite 04-013-9997 SLAMS (PAMS - Type 2) X LR 

## X LR 

## X X X X X X Queen Valley 04-021-8001 SLAMS (PAMS – Type 3) X LR 

## X X X X X X Phoenix - Vehicle Emissions Laboratory 04-013-9998 Meteorology NR NR NR NR X X NR X – Submitted to AQS NR – Collected but not reported to AQS N – ADEQ does not wish to certify these data due to data quality issues LR 

## – Laboratory reported data to AQS after review by ADEQ 

## Table 3. 2012 Data to be certified in AQS from ADEQ NATTS, CSN, and UATMP Parameters Parameters

Site Name AQS - ID ClassificationPM2.5 Chemical SpeciationNetwork (RTI Lab)PM10Metals Speciation(ERG Lab)Chrome VI(ERG Lab)VOCs -- Urban Air Toxics(ERG Lab)SVOCs -- Urban Air Toxics(ERG Lab)Carbonyls -- Urban Air Toxics(ERG Lab)



## Phoenix – JLG Supersite 04-013-9997 SLAMS, CSN, NATTS X LR 

## X LR 

## X LR 

## X LR 

## X LR 

## X LR 

## South Phoenix 04-013-4003 SLAMS X LR 

## X – Submitted to AQS LR 

## – Laboratory reported data to AQS after review by ADEQ.

## Table 4. Data to be re-certifi ed in AQS from ADEQ Monitors Compliance Parameters

Site Name AQS ID ClassificationNO2(42602)



## JLG Supersite 04-013-9997 SLAMS / NCore X (recertify data 2011) X – Submitted to AQS LR 

## – Laboratory reported data to AQS after review by ADEQ

## APPENDIX BUNITED STATES ENVIRONMENTAL PROTECTION AGENCY

DATA EVALUATION AND CONCURRENCE REPORT May. 9, 2013 Report Request ID: 1096803 Report Code: AMP600

Selection Criteria Page 1 User ID: JOJ

State County City

Site Parameter POC AQCR UAR CBSA CSA EPA Region Method Duration Begin Date End Date 04 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration CRITERIA AGENCY SELECTIONS Arizona Department Of Environmental Quality Freeport McMoRan Miami, Inc. SELECTED OPTIONS

MERGE PDF FILES Option Type Option Value YES GLOBAL DATES

2012 Start Date End Date 2012 Tribal CodeMay. 9, 2013 

# Data Evaluation and Concurrence Report Summary

Page 1 of 4 2012 

## Certification Year: Certifying Agency (CA): Arizona Department Of Environmental Quality (0053) 

## Pollutants in Report:

PQAO Parameter Code Carbon monoxide Lead (TSP) LC Lead PM10 LC FRM/FEM Nitrogen dioxide (NO2) Ozone PM10 Total 0-10um STP PM2.5 - Local Conditions Sulfur dioxide 42101 14129 85129 42602 44201 81102 88101 42401 

## Parameter Name Monitors Evaluated Code 1

3 1 1 7 18 8 3

0053 Arizona Department Of Environmental Quality 

## PQAO Code

AQS Site-ID POC AQS Recommended Flag Cert. Agency

Recommended Flag Reason for AQS Recommendation 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 81102

81102 85129 88101 88101 88101 88101 88101 88101 88101 1 3 1 1 1 1 3 1 2 1 04-025-2002 04-023-0004 04-013-9997 04-003-1005 04-005-1008 04-013-9997 04-013-9997 04-023-0004 04-023-0004 04-025-2002 N N N N N N N N N N Y

Y Y Y Y Y Y Y Y Y Quality Assurance Project Plan not approved in 10

years. Quality Assurance Project Plan not approved in 10 years. PQAO-Level Lead Analysis criteria not met. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. 

## PQAO Name Summary of 'N' flags for all pollutants: 0 3 0 0 0 0 0 0 1 0 1 1 7 18 8 3 

## PQAOs in Report: 04/09/12 

## TSA Date Monitors Recommended for Concurrence by AQS Monitors NOT Recommended for Concurrence by AQSMay. 9, 2013 

# Data Evaluation and Concurrence Report Summary

Page 2 of 4 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 88101

42101 42401 42401 42401 42602 44201 44201 44201 44201 44201 44201 44201 81102 81102 81102 81102 81102 81102 1 1 1 3 1 1 1 1 1 1 1 1 1 1 3 3 1 1 1 04-027-8011 04-013-9997 04-007-0009 04-007-1001 04-013-9997 04-013-9997 04-005-1008 04-007-0010 04-012-8000 04-013-9997 04-021-8001 04-025-8033 04-027-8011 04-003-0011 04-003-0011 04-003-0011 04-003-1005 04-005-1008 04-007-0008 N N N N N N N N N N N N N N N N N N N Y

N Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Quality Assurance Project Plan not approved in 10

years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Annual Summary completeness < 70%. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. 

## Monitors NOT Recommended

for Concurrence by AQSMay. 9, 2013 

# Data Evaluation and Concurrence Report Summary

Page 3 of 4 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 81102

81102 81102 81102 81102 81102 81102 81102 81102 81102 81102 81102 2 3 3 3 4 4 1 3 3 3 1 3 04-007-0008 04-007-1001 04-007-8000 04-013-9997 04-013-9997 04-013-9997 04-015-1003 04-015-1003 04-019-0001 04-019-0020 04-023-0004 04-027-8011 N N N N N N N N N N N N Y

Y Y Y Y Y Y Y Y Y Y Y Quality Assurance Project Plan not approved in 10

years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Flow Rate Audit completeness < 65%. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. 

## Signature of Monitoring Organization Representative: ________________________________________________________ Monitors NOT Recommended for Concurrence by AQSMay. 9, 2013 

# Data Evaluation and Concurrence Report Summary

Page 4 of 4 2012 

## Certification Year: Certifying Agency (CA): Freeport McMoRan Miami, Inc. (1357) 

## Pollutants in Report:

PQAO Parameter Code PM10 Total 0-10um STP 81102 

## Parameter Name Monitors Evaluated Code 3

1357 Freeport McMoRan Miami, Inc. 

## PQAO Code

AQS Site-ID POC AQS Recommended Flag Cert. Agency

Recommended Flag Reason for AQS Recommendation 1357 1357 1357 81102

81102 81102 1 2 1 04-007-0009 04-007-8000 04-007-8000 N N N Y

Y Y Quality Assurance Project Plan not approved in 10

years. Quality Assurance Project Plan not approved in 10 years. Quality Assurance Project Plan not approved in 10 years. 

## Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name Summary of 'N' flags for all pollutants: 0 3 

## PQAOs in Report: TSA Date Monitors Recommended for Concurrence by AQS Monitors NOT Recommended for Concurrence by AQS

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2012 Certifying Year Certifying Agency Code Arizona Department Of Environmental Quality (0053) Carbon monoxide (42101) (ppm) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 04-013-9997 SLAMS 0.351 Mean 0.010

Min 2.968 Max 0 Exceed. Count 0

Outlier Count 82 Perc. Comp. 5.94

Precision +5.58

Bias 92 Complete 100 Complete Bias Y

PQAO Level Criteria N Aqs Rec Flag N

CA Rec Flag N Epa Concur 

## Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met 

### NPAP Audit Summary:

4.68 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2012 Certifying Year Certifying Agency Code Arizona Department Of Environmental Quality (0053) Nitrogen dioxide (NO2) (42602) (ppb) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 04-013-9997 SLAMS 18.0 Mean 1.0

Min 66.0 Max Exceed. Count 0

Outlier Count 96 Perc. Comp. 3.08

Precision +/-2.55

Bias 85 Complete 100 Complete Bias Y

PQAO Level Criteria N Aqs Rec Flag Y

CA Rec Flag Epa Concur The AQS recommended flag is the result of not having Submitter Comment 

## Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met 

### NPAP Audit Summary:

- 2.28 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2012 Certifying Year Certifying Agency Code Arizona Department Of Environmental Quality (0053) Ozone (44201) (ppm) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 1 1 1 1 1 1 04-005-1008 04-007-0010 04-012-8000 04-013-9997 04-021-8001 04-025-8033 04-027-8011 SLAMS

SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS 0.057

0.064 0.058 0.054 0.064 0.056 0.058 Mean 0.037 0.038 0.034 0.011 0.038 0.030 0.024 Min 0.084 0.092 0.080 0.097 0.106 0.081 0.100 Max 0

0 0 0 0 0 0 Exceed. Count 0

0 0 0 0 0 0 Outlier Count 98

99 97 95 99 98 99 Perc. Comp. 1.76

1.26 0.78 3.41 1.46 0.66 1.48 Precision +/-1.42

+1.99 +/-0.88 +2.91 -1.56 +1.58 +/-1.17 Bias 100

100 100 88 100 100 100 Complete 100 100 100 100 100 100 100 Complete

2.04

Bias Y

Y Y Y Y Y Y PQAO Level Criteria N N N N N N N Aqs Rec Flag Y

Y Y Y Y Y Y CA Rec Flag Epa Concur The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having Submitter Comment Submitter Comment Submitter Comment Submitter Comment Submitter Comment Submitter Comment Submitter Comment 

## Parameter

1 Y Number of Valid Audits NPAP Bias Criteria Met 

### NPAP Audit Summary: 2.04082

- 3.44 - 2.96 - 3.02 1.07 - 4.52 0.47 - 0.39 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N N N N N N N

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2012 Certifying Year Certifying Agency Code Arizona Department Of Environmental Quality (0053) Sulfur dioxide (42401) (ppb) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 3 1 04-007-0009 04-007-1001 04-013-9997 SLAMS

SLAMS SLAMS 4.4

10.3 1.3 Mean 2.0

0.0 0.0 Min 188.0 481.0 9.1 Max Exceed. Count 0

0 0 Outlier Count 98

99 99 Perc. Comp. 2.93

3.67 4.61 Precision +4.17

+3.58 +/-3.86 Bias 100

96 96 Complete 100 100 100 Complete Bias Y Y Y PQAO Level Criteria N N N Aqs Rec Flag Y

Y Y CA Rec Flag Epa Concur The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having The AQS recommended flag is the result of not having Submitter Comment Submitter Comment Submitter Comment 

## Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met 

### NPAP Audit Summary:

7.93 2.85 - 2.43 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N N N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency: PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/06/1994 Quality Assurance Project Plan Approval Date: Monitors Summaries Monitor Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Bias %

Complete Flow Rate Verification Flow Rate Audit Collocation Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-003-0011

04-007-1001

04-007-8000

04-013-9997

04-013-9997 3

3

3

3

4 SLAMS

SLAMS

SLAMS

SLAMS

SLAMS 26.65

43.63

24.41

35.31

33.55 -15.0

-22.0

-25.0

2.0

-6.0 ********

********

234.0

********

******** 0

0

0

0

0 62

99

99

98

99 AQS Site ID POC +/-1.49

-2.14

-2.37

+/-0.73

+/-0.70 100

100

100

100

83 -0.48

-2.47

-1.24

-1.15

+/- 100

100

100

100

0 N

N

N

N

N Y

Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place and no flow rate audit in 2012. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. There was no audit of the instrument in EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency: PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/06/1994 Quality Assurance Project Plan Approval Date: Monitors Summaries Monitor Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Bias %

Complete Flow Rate Verification Flow Rate Audit Collocation Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-027-8011 3

3

3

3

3 SLAMS

SLAMS

SLAMS

SPECIAL PURPOSE

SLAMS 21.79

34.41

42.94

48.09

43.68 -22.0

-38.0

-11.0

2.0

-37.0 893.0

********

********

793.0

******** 0

0

0

0

0 98

97

98

92

99 AQS Site ID POC +/-1.27

+/-0.98

+/-0.75

+/-0.84

+/-2.08 100

100

100

100

100 -0.42

-0.44

+1.11

-1.01

-1.48 100

100

100

100

100 N

N

N

N

N Y

Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency: PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/06/1994 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites # Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? 7 1 1 100 5.49 6.25 Y 

## Monitors Summaries Monitor Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Flow Rate Audit Collocation 

### % Complete CV PQAO

Crit. Met Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-003-0011

04-003-1005

04-005-1008

04-007-0008 1

1

1

1 SLAMS

SLAMS

SLAMS

SLAMS 19.17

31.16

17.32

20.43 4.0

5.0

2.0

6.0 37.0

71.0

38.0

44.0 0

0

0

0 0

0

0

0 100

91

96

98 AQS Site ID POC -0.90

-0.88

-1.83

-0.92 100

100

100

70 100 6.25 Y

Y

Y

Y N

N

N

N Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency: PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 08/06/1994 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites # Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? 7 1 1 100 5.49 6.25 Y 

## Monitors Summaries Monitor Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Flow Rate Audit Collocation 

### % Complete CV PQAO

Crit. Met Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-007-0008

04-015-1003

04-023-0004

04-025-2002 2

1

1

1 QA COLLOCA TED

SLAMS

SLAMS

SLAMS 20.50

18.30

36.67

12.53 6.0

4.0

7.0

4.0 41.0

35.0

102.0

39.0 0

0

0

0 0

0

0

0 100

100

95

95 AQS Site ID POC -1.15

-0.65

-1.83

-1.04 70

100

100

100 Y

Y

Y

Y N

N

N

N Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Arizona Department Of Environmental Quality (0053) Certifying Year: Certifying Agency: PM2.5 - Local Conditions (88101)

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 12/09/1998 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites # Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? Method 143 6 1 1 100 5.99 6.89 Y 

## PEP Summary # Methods # Audited

Methods # PEP

Required # PEP

Submitted %

Complete Bias Criteria Met? 1 1 8 5 62.5 -15.06 Y 

## Monitors Summaries

Method Monitor

Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Flow Rate Audit Collocation 

### % Complete CV PQAO

Crit. Met PEP

PQAO Crit. Met Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-003-1005

04-005-1008

04-013-9997

04-013-9997 1

1

1

3 143

143

143

170 SLAMS

SLAMS

SLAMS

SLAMS 6.72

5.40

9.23

7.91 2.0

1.2

2.3

-5.0 13.1

14.1

52.0

537.0 0

0

0

0 100

98

99

98 AQS Site ID POC -0.30

-1.24

-1.30

-1.02 100

100

100

100 Y

Y

Y

Y Y

Y

Y

Y N

N

N

N Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012

2012 Arizona Department Of Environmental Quality (0053)

Freeport McMoRan Miami, Inc. (1357) Certifying Year:

Certifying Year: Certifying Agency:

Certifying Agency: PM2.5 - Local Conditions (88101)

Arizona Department Of Environmental Quality (0053) Parameter: PQAO Name: 12/09/1998 Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites # Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? Method 143 6 1 1 100 5.99 6.89 Y 

## PEP Summary # Methods # Audited

Methods # PEP

Required # PEP

Submitted %

Complete Bias Criteria Met? 1 1 8 5 62.5 -15.06 Y 

## Monitors Summaries

Method Monitor

Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Flow Rate Audit Collocation 

### % Complete CV PQAO

Crit. Met PEP

PQAO Crit. Met Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-023-0004

04-023-0004

04-025-2002

04-027-8011 1

2

1

1 143

143

143

143 SLAMS

QA COLLOCA TED

SLAMS

SLAMS 9.39

9.30

4.47

8.46 2.9

3.9

1.7

2.9 29.0

26.7

14.0

17.0 0

0

0

0 95

85

96

93 AQS Site ID POC -2.23

-1.62

-0.09

-2.24 100

100

100

100 100 6.89 Y

Y

Y

Y Y

Y

Y

Y N

N

N

N Y

Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

N

# Data Evaluation and Concurrence Report for Particulate Matter

2012 Freeport McMoRan Miami, Inc. (1357) Certifying Year: Certifying Agency: PM10 Total 0-10um STP (81102) INTERMITTENT

Freeport McMoRan Miami, Inc. (1357) Parameter: PQAO Name: Quality Assurance Project Plan Approval Date: Collocation Summary

# Sites # Sites

Req # Sites Collocated %

Collocated CV

Est CV UB Criteria

Met? 2 1 1 100 14.92 17.04 Y 

## Monitors Summaries Monitor Type Mean Min Max Exceed. Count Outlier Count % Complete Bias %

Complete Flow Rate Audit Collocation 

### % Complete CV PQAO

Crit. Met Routine Data (ug/m3) Concurrence Flag 

### AQS Rec Flag CA Rec

Flag EPA Concur 04-007-0009

04-007-8000

04-007-8000 1

1

2 INDUSTRI

AL

INDUSTRI AL

INDUSTRI AL 15.79

18.19

18.71 2.0

4.0

6.0 53.0

45.0

36.0 0

0

0 0

0

0 100

96

95 AQS Site ID POC -0.61

-1.90

-1.46 100

100

100 100 17.04 Y

Y

Y N

N

N Y

Y

Y Submitter Comment:

Submitter Comment:

Submitter Comment: 

### The AQS recommended flag is the result of not having an

approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. The AQS recommended flag is the result of not having an approved QAPP in place. ADEQ is working to produce QAPPs according to the schedule given in our TSA response dated 3/29/2013. EPA Comment:

EPA Comment:

EPA Comment: 

### QAPP Appr. N

N

N

# Data Concurrence and Evaluation Report for Lead 2012 Certification Year Arizona Department Of Environmental Quality (0053) Certifying Agency Name: Lead (TSP) LC (14129)

Lead PM10 LC FRM/FEM (85129)

Arizona Department Of Environmental Quality (0053)

Arizona Department Of Environmental Quality (0053) PQAO Name:

PQAO Name: Y

N Criteria Met

Criteria Met +5.21

-9.44 Bias

Bias 83

50 Percent Complete

Percent Complete 20

12 Number Submitted

Number Submitted 24

24 Number Required

Number Required Y Criteria Met

Criteria Met Bias

Bias 0

0 Percent Complete

Percent Complete 0

0 Number of Audits Submitted

Number of Audits Submitted 1

1 Number of PEP Audits Required

Number of PEP Audits Required 0

0 Number of Methods Audited

Number of Methods Audited 1

1 Number of Methods

Number of Methods Y Criteria Met

Criteria Met 4.66

9.72 CV UB

CV UB 4.01

3.16 CV Est

CV Est 100

100 Percent Collocated

Percent Collocated 1

1 Number of Actual Colloc Sites

Number of Actual Colloc Sites 1

1 Number of Colloc Sites Required

Number of Colloc Sites Required 2

1 Number of Sites

Number of Sites Collocation Summary:

Collocation Summary: 01/22/2013

01/22/2013 Quality Assurance Project Plan Approval Date:

Quality Assurance Project Plan Approval Date: Analysis Audit Summary:

Analysis Audit Summary: PEP Summary

PEP Summary AQS Site-ID

AQS Site-ID POC

POC Monitor Type

Monitor Type Mean

Mean Min

Min Max

Max Exceed. Count

Exceed. Count Outlier

Count

Outlier Count Percent

Comp.

Percent Comp. Bias

Bias Percent

Comp.

Percent Comp. CV UB

CV UB Percent

Comp.

Percent Comp. PQAO

Crit. Met

PQAO Crit. Met PQAO

Crit. Met

PQAO Crit. Met Analysis

Crit. Met

Analysis Crit. Met AQS Rec. V

AQS Rec. V CA Rec Value

CA Rec Value EPA Concur

EPA Concur Monitors Recommended for Certification Routine Data (ug/m^3)

Routine Data (ug/m^3) Flow Rate Audit

Flow Rate Audit Collocation

Collocation PEP

PEP Lead

Lead Certification

Certification 04-007-1002 04-007-1002 04-007-8000

04-013-9997 1

2 1

1 SLAMS SLAMS SLAMS

NATTS 0.130

0.126 0.025

0.0040 0.006

0.003 0.004

0.0012 0.624

0.648 0.151

0.0114 1

2 0

0 0

0 0

0 98

91 100

100 -2.37

+0.02 -0.78

-0.95 100

100 100

100 4.66

9.72 100

20 Y Y Y Y

Y Y Y

Y Y

N Y

Y Y

N Y Y Y

Y Submitter Comment: EPA Comment: The AQS recommended flag is the result of partial year FEM method code designation. The analysis audit summary information is complete for a 6 month period (12 submitted audits). This flag is erroneous. Further, this monitor does not require collocatio Monitors Not Recommended for Certification QAPP Appr.

QAPP Appr. Y Y Y

YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY QUICKLOOK ALL PARAMETERS May. 16, 2013 Report Request ID: 1099159 Report Code: AMP450NC

Selection Criteria Page 1 User ID: JOJ

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration ALL AGENCY SELECTIONS Arizona Department Of Environmental Quality

SELECTED OPTIONS

MERGE PDF FILES EVENTS PROCESSING Option Type Option Value YES EXCLUDE REGIONALLY CONCURRED EVENTS SORT ORDER

1 2 3 4 5 6 7 Order Column

STATE_CODE COUNTY_CODE SITE_ID PARAMETER_CODE POC DATES EDT_ID GLOBAL DATES

2012 Start Date End Date 2012 APPLICABLE STANDARDS Standard Description CO 8-hour 1971 Lead 3-Month 2009 Lead 3-Month PM10 Surrogate 2009 Lead Quarterly 1978 NO2 Annual 1971 Ozone 8-Hour 2008 PM10 24-hour 2006 PM25 24-hour 2006 SO2 1-hour 2010UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013 QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES EDT DESCRIPTION 0 1 2 5 NO EVENTS EVENTS EXCLUDED EVENTS INCLUDED EVENTS WITH CONCURRENCE EXCLUDEDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 2 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 3 3 1 2

1 1 1 1 1

1

1 1 1 1 1 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053

0053

0053 0053 0053 0053 0053 2012 2012 2012 2012 2012

2012 2012 2012 2012 2012

2012

2012 2012 2012 2012 2012 30

5456 225 30 2

61 61 56 56 61

5424

60 60 59 59 60 37

1160 194 31 15

31.9 666 71 61 13.1

.075

23.0 598 38 30 14.1 36

1038 94 30 9

30.4 664 58 52 12.1

.073

22.7 597 35 29 11.9 34

804 66 29

29.1 663 55 47 11.4

.073

22.1 596 33 27 11.9 28

503 60 25

28.9 663 52 47 11.1

.072

20.5 596 32 26 11.2 19.2*

26.6* 26.2* 16.8* 12.0*

19.00 659.2 31.2* 27.5* 6.72

.0531

9.69 591.9 17.3 14.1 5.40 24 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 24 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

8-HR RUN AVG BEGIN HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0

0 0 0 0 0

0

0 0 0 0 0 81102 81102 81102 85101 85101

68105 68108 81102 85101 88101

44201

68105 68108 81102 85101 88101 Parameter Site ID:

Site ID:

Site ID: 04-003-0011

04-003-1005

04-005-1008 Paul Spur

Douglas

Flagstaff City:

City:

City: Cochise

Cochise

Coconino Unit County:

County:

County: HOUSING AREA, PAUL SPUR

1445-1449 15TH STREET

755 W BONITO Address:

Address:

Address: PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 - LC PM10 - LC

Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions

Ozone Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per million Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

126 079 079 126 126

143 143 126 126 143

087

143 143 126 126 143 Cert

S S S

S S S S S

S

S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 3 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 2 1 2

1 1

1

3 3 3 3

1 2 1 2 1 2 0053 0053 0053 0053

0053 0053

0053

0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 2012 2012 2012 2012

2012 2012

2012

2012 2012 2012 2012

2012 2012 2012 2012 2012 2012 60

62 60 62

8615 8605

5863

8737 8712 8709 364

60 56 61 60 61 60 44

41 38 36

188.0 421.7

.080

481.0 1350.2 3954 250

.624 .648 37.3 35.2 716 716 40

41 33 34

134.0 266.0

.079

407.0 1114.1 1141 137

.472 .489 36.5 34.5 714 714 37

37 33 33

124.0 257.7

.079

392.0 1072.4 1062 125

.364 .363 36.1 34.3 712 712 36

36 32 32

102.0 257.3

.078

353.0 1032.5 1019 105

.363 .347 35.7 34.0 712 712 20.4

20.5 17.7 17.8

19.35 7.68

.0587

72.78 27.75 43.6 43.1

.1304 .1257 23.41 22.45 708.0 707.7 24 HOUR 24 HOUR 24 HOUR 24 HOUR

1 HOUR 1 HOUR

8-HR RUN AVG BEGIN HOUR

1 HOUR 1 HOUR 1 HOUR 24-HR BLK AVG

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0

0 0

0

0 0 0 0

0 0 0 0 0 0 81102 81102 85101 85101

42401 42406

44201

42401 42406 81102 81102

14129 14129 68105 68105 68108 68108 Parameter Site ID:

Site ID:

Site ID:

Site ID:

Site ID: 04-007-0008

04-007-0009

04-007-0010

04-007-1001

04-007-1002 Payson

Miami

Tonto National Monument

Hayden

Not in a city City:

City:

City:

City:

City: Gila

Gila

Gila

Gila

Gila Unit County:

County:

County:

County:

County: 204 W AERO DR

4030 LINDEN STREET

SOUTH OF SR88

JAIL-CANYON DR, HAYDEN

SR 77 Address:

Address:

Address:

Address:

Address: PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 - LC PM10 - LC

Sulfur dioxide SO2 max 5-min avg

Ozone

Sulfur dioxide SO2 max 5-min avg PM10 Total 0-10um STP PM10 Total 0-10um STP

Lead (TSP) LC Lead (TSP) LC Ambient Temperature Ambient Temperature Sample Baro Pressure Sample Baro Pressure Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per billion Parts per billion Parts per million

Parts per billion Parts per billion Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Meth

126 126 126 126

060 060

087

060 060 079 079

191 191 780 780 780 780 Cert

S S S S

S S

S

S S S S

S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 4 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 1 1 3 3

1

6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053

0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012

2012

2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 61

61 61 3791 158

5752

30 30 30 30 30 30 30 30 30 30 .151

32.1 684 234 52

.075

.06 6.75 6.08 .04 1.33 1.26 .05 .05 .03 .00 .097

32.0 681 199 52

.075

.03 6.54 5.74 .04 1.15 1.18 .00 .05 .03 .00 .070

30.8 681 143 49

.075

.03 5.79 5.54 .04 1.14 1.17 .00 .05 .03 .00 .064

30.6 681 140 44

.075

.03 5.55 5.52 .03 1.02 1.09 .00 .05 .03 .00 .0254

19.01 675.9 24.4* 23.9*

.0542

.017 2.672 2.649 .031 .465 .599 .002 .048 .033 .000 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG

8-HR RUN AVG BEGIN HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0

0

0 0 0 0 0 0 0 0 0 0 14129 68105 68108 81102 81102

44201

42153 43205 43206 43208 43218 43233 43372 43373 43396 43438 Parameter Site ID:

Site ID:

Site ID: 04-007-8000

04-012-8000

04-013-4003 Globe

Wenden

Phoenix City:

City:

City: Gila

La Paz

Maricopa Unit County:

County:

County: SR 188 & US 60

ALAMO LAKE STATE PARK

33 W TAMARISK AVE, PHOENIX Address:

Address:

Address: Lead (TSP) LC Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP

Ozone

Carbon disulfide Propylene Acetylene Freon 114 1,3-Butadiene n-Octane Methyl tert-butyl ether Tert-amyl methyl ether tert-Butyl ethyl ether Ethyl acrylate Micrograms/cubic meter (LC) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Parts per million

Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

191 780 780 079 079

087

101 101 101 101 101 101 101 101 101 101 Cert

S S S S S

S

S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 5 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 30

30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 .61

3.33 .54 .71 .00 .78 .32 .06 .13 .01 .38 .00 .00 .02 .06 .35 .00 .54

3.21 .49 .59 .00 .76 .27 .06 .13 .01 .32 .00 .00 .02 .06 .15 .00 .18

2.21 .47 .59 .00 .71 .21 .06 .13 .00 .31 .00 .00 .02 .05 .15 .00 .18

2.19 .46 .56 .00 .70 .20 .06 .12 .00 .30 .00 .00 .02 .05 .14 .00 .061

1.251 .268 .360 .000 .614 .128 .034 .103 .001 .274 .000 .000 .010 .037 .066 .000 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43441 43505 43560 43702 43704 43801 43802 43803 43804 43806 43811 43812 43813 43814 43815 43817 43818 Parameter Site ID: 04-013-4003 Phoenix City: Maricopa Unit County: 33 W TAMARISK AVE, PHOENIX Address: Methyl methacrylate Acrolein - Unverified Methyl isobutyl ketone Acetonitrile Acrylonitrile Chloromethane Dichloromethane Chloroform Carbon tetrachloride Bromoform Trichlorofluoromethane Chloroethane 1,1-Dichloroethane Methyl chloroform Ethylene dichloride Tetrachloroethylene 1,1,2,2-Tetrachloroethane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 6 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 30

30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 .02

.00 .21 .59 .04 0 .01 .00 .00 .05 .01 .06 .01 .01 .02 .00 .00 .02

.00 .19 .57 .03 0 .01 .00 .00 .00 .01 .00 .01 .01 .02 .00 .00 .01

.00 .18 .57 .03 0 .01 .00 .00 .00 .01 .00 .01 .01 .02 .00 .00 .01

.00 .18 .56 .03 0 .01 .00 .00 .00 .01 .00 .01 .01 .02 .00 .00 .009

.000 .161 .508 .009 .0 .011 .000 .000 .002 .009 .002 .007 .012 .018 .000 .000 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43819 43820 43821 43823 43824 43826 43828 43829 43830 43831 43832 43835 43836 43838 43839 43843 43844 Parameter Site ID: 04-013-4003 Phoenix City: Maricopa Unit County: 33 W TAMARISK AVE, PHOENIX Address: Bromomethane 1,1,2-Trichloroethane 1,1,2-Trichloro-1,2,2- trifluoroethane Dichlorodifluoromethane Trichloroethylene 1,1-Dichloroethylene Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene cis-1,3-Dichloropropene Dibromochloromethane Chloroprene Bromochloromethane trans-1,2-Dichloroethylene cis-1,2-Dichloroethene Ethylene dibromide Hexachlorobutadiene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 7 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6

6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012

2012 2012 30

30 30 30 30 30 30 30 30 30 30 30 30 30

61 6 .00 10.00 6.36 22.68 3.46 4.15 1.31 4.24 1.27 .08 .06 .07 .64 .12

.00 .00 .00

9.28 5.39 19.95 3.35 3.59 1.13 3.62 .77 .00 .06 .07 .61 .10

.00 .00 .00

9.04 5.17 18.55 2.96 3.58 .92 2.99 .74 .00 .06 .07 .58 .03

.00 .00 .00

8.64 5.12 17.71 2.93 3.50 .91 2.98 .66 .00 .06 .07 .51 .00

.00 .00 .000

4.302 2.700 9.179 1.551 1.727 .489 1.592 .393 .003 .063 .072 .259 .008

.000 .000* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 43860 45109 45201 45202 45203 45204 45207 45208 45220 45801 45805 45806 45807 45810

12115 12115 Parameter Site ID:

Site ID: 04-013-4003

04-013-9997 Phoenix

Phoenix City:

City: Maricopa

Maricopa Unit County:

County: 33 W TAMARISK AVE, PHOENIX

4530 N 17TH AVENUE Address:

Address: Vinyl chloride m/p Xylene Benzene Toluene Ethylbenzene o-Xylene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene Styrene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2,4-Trichlorobenzene

Chromium VI (TSP) STP Chromium VI (TSP) STP Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101

920 920 Cert

S S S S S S S S S S S S S S

S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 8 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 59

59 59 59 59 59 59 59 59 59 59 59 59 59 59 59 59 343.000 4.2100 7.0300 5.7600 10.700 1.5500 29.6000 3.0700 .296 2.7500 2.9300 2.9400 .317 .8530 2.670 5.930 2.060 264.000

3.9300 5.3700 5.3600 10.500 1.1900 6.6900 3.0400 .205 2.6100 2.0000 .9390 .315 .1800 .856 1.520 .431 249.000

3.5900 4.2900 4.5000 10.400 .9030 5.3400 2.8800 .142 2.4600 1.8600 .9100 .281 .1780 .816 1.140 .372 243.000

3.5100 4.0200 4.4800 10.400 .7940 3.1200 2.8400 .118 2.2100 1.8300 .7810 .191 .1350 .587 1.120 .340 97.8371 2.14456 1.01181 3.05254 6.2554 .32959 1.17716 1.49234 .0209 1.20875 .76086 .21464 .0596 .03195 .1380 .3129 .0826 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 17141 17147 17148 17149 17150 17151 17158 17159 17160 17201 17204 17208 17211 17212 17215 17220 17223 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Naphthalene (TSP) STP Acenaphthene (TSP) STP Acenaphthylene (TSP) STP Fluorene (TSP) STP Phenanthrene (TSP) STP Anthracene (TSP) STP Retene (TSP) STP 9-fluorenone (TSP) STP Cyclopenta[cd]pyrene (TSP) STP Fluoranthene (TSP) STP Pyrene (TSP) STP Chrysene (TSP) STP Coronene (TSP) STP Perylene (TSP) STP Benzo[a]anthracene (TSP) STP Benzo[b]fluoranthene (TSP) STP Benzo[k]fluoranthene (TSP) STP Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Meth

118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 9 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3 3 3 3 1

6 7 1 1 1 1 1 1 8 9 8 8 9 8 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012

2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 59

59 59 59 59 7185

61 6 8732 7914 7437 8408 8408 8408 16 1 7 16 1 16 2.810

.396 1.940 3.600 2.3600 1.8

.08 .05 9.1 9.6 216.1 266.0 66.0 318.0 169.00 179.00 4.07 .19 .19 .19 .708

.122 .811 .854 .8170 1.7

.08 .05 7.2 9.5 216.0 253.0 64.0 304.0 164.00

.08 .19

.19 .554

.106 .505 .676 .5650 1.7

.08 .04 6.8 9.3 216.0 250.0 63.0 296.0 157.00

.08 .19

.19 .514

.100 .479 .670 .5300 1.6

.07 .04 6.1 8.4 214.9 230.0 62.0 267.0 156.00

.08 .19

.19 .1564

.0201 .1685 .1665 .15572 .35

.030 .043* 2.33 1.56 34.29 15.82 18.05 33.77 121.213* 179.000* .652* .192* .192* .192* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 8-HR RUN AVG END HOUR 24 HOUR 24 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 17224 17231 17237 17242 17243 42101

42153 42153 42401 42406 42600 42601 42602 42603 43102 43102 43127 43141 43141 43142 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Benzo[e]pyrene (TSP) STP Dibenzo[a,h]anthracene (TSP) STP Benzo[g,h,i]perylene (TSP) STP Benzo[a]pyrene (TSP) STP Indeno[1,2,3-cd]pyrene (TSP) STP Carbon monoxide

Carbon disulfide Carbon disulfide Sulfur dioxide SO2 max 5-min avg Reactive oxides of nitrogen (NOy) Nitric oxide (NO) Nitrogen dioxide (NO2) Oxides of nitrogen (NOx) Total NMOC (non-methane organic compound) Total NMOC (non-methane organic compound) Isobutene & 1-butene n-Dodecane n-Dodecane Tridecene Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Parts per million Parts per billion Carbon Parts per billion Carbon Parts per billion Parts per billion Parts per billion Parts per billion Parts per billion Parts per billion Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

118 118 118 118 118 588

101 101 592 592 591 074 074 074 126 126 126 126 126 126 Cert

S S S S S S

S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 10 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 6 7 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

16 1 16 1 16 1 16 1 16 1 16 1 61 6 16 1 .19

.19 .19 .09 .09 .11 .11 6.01 3.52 4.40 4.22 10.50 3.93 7.08 2.77 1.52 1.04 .19

.09

.11

5.35

3.97

5.90

6.54 2.35 1.26 .19

.09

.11

5.26

3.57

4.64

6.51 2.26 1.18 .19

.09

.11

5.16

3.55

4.56

5.70 1.91 1.15 .192*

.192* .192* .092* .092* .106* .106* 3.610* 3.520* 2.768* 4.220* 3.969* 3.930* 2.349 1.935* 1.028* 1.040* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43142 43143 43143 43144 43144 43145 43145 43202 43202 43203 43203 43204 43204 43205 43205 43205 43205 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Tridecene n-Tridecane n-Tridecane Propyne Propyne 1-Octene 1-Octene Ethane Ethane Ethylene Ethylene Propane Propane Propylene Propylene Propylene Propylene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 101 101 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 11 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 7 8 9 6 7 8 9 8 9 8 9 8 9 6 7 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 61

6 16 1 61 6 16 1 16 1 16 1 16 1 61 6 16 7.76

3.20 1.65 .89 .05 .04 3.25 2.09 1.72 1.13 .25 .07 .22 .10 1.27 .51 .69 5.92

2.48 1.42

.04 .04 3.03

1.57

.22

.22

1.26 .40 .58 5.72

2.04 1.04

.04 .03 2.52

1.26

.22

.21

1.21 .37 .55 5.50

1.77 1.03

.04 .03 2.27

1.24

.22

.10

1.09 .29 .47 2.270

1.931* .861* .888* .033 .034* 1.959* 2.090* 1.008* 1.130* .148* .073* .122* .100* .400 .306* .262* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43206 43206 43206 43206 43208 43208 43212 43212 43214 43214 43216 43216 43217 43217 43218 43218 43218 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Acetylene Acetylene Acetylene Acetylene Freon 114 Freon 114 n-Butane n-Butane Isobutane Isobutane trans-2-Butene trans-2-Butene cis-2-Butene cis-2-Butene 1,3-Butadiene 1,3-Butadiene 1,3-Butadiene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 126 126 101 101 126 126 126 126 126 126 126 126 101 101 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 12 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

16 1 9 16 1 16 1 16 1 16 1 14 1 16 1 16 .23

7.59 2.53 11.90 .66 .32 .53 .32 .58 .32 .28 .11 .79 .50 1.84 1.18 1.92 4.65

10.20 .58

.37

.35

.11

.49

1.62

1.69 4.28

8.99 .51

.33

.33

.11

.46

1.20

1.43 2.54

4.40 .50

.31

.28

.11

.43

1.18

1.24 .230*

2.619* 2.530* 5.628* .305* .316* .233* .320* .245* .321* .118* .108* .361* .500* 1.017* 1.180* 1.088* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43218 43220 43220 43221 43224 43224 43225 43225 43226 43226 43227 43227 43228 43228 43230 43230 43231 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 1,3-Butadiene n-Pentane n-Pentane Isopentane 1-Pentene 1-Pentene 2-Methyl-1-butene 2-Methyl-1-butene trans-2-Pentene trans-2-Pentene cis-2-Pentene cis-2-Pentene 2-Methyl-2-butene 2-Methyl-2-butene 3-Methylpentane 3-Methylpentane n-Hexane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 13 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 6 7 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

16 1 61 6 16 1 16 1 16 1 16 1 16 1 16 1 1.27

.96 .60 1.32 .75 .47 .44 .17 .17 .29 .26 .17 .17 .33 .32 .54 .34 .77

1.28 .73 .46

.17

.27

.17

.33

.46 .74

1.25 .66 .43

.17

.25

.17

.32

.37 .70

1.23 .54 .41

.17

.24

.17

.32

.36 1.270*

.554* .602* .550 .582* .328* .442* .171* .171* .190* .258* .171* .171* .224* .321* .318* .339* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43231 43232 43232 43233 43233 43233 43233 43234 43234 43235 43235 43236 43236 43238 43238 43242 43242 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: n-Hexane n-Heptane n-Heptane n-Octane n-Octane n-Octane n-Octane 4-Methyl-1-pentene 4-Methyl-1-pentene n-Nonane n-Nonane 2-Ethyl-1-butene 2-Ethyl-1-butene n-Decane n-Decane Cyclopentane Cyclopentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 101 101 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 14 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 16

1 16 1 16 1 16 1 16 1 16 1 16 1 16 1 16 2.85

2.04 .50 .39 .17 .17 .17 .17 .87 .54 1.22 .83 1.50 .89 2.44 1.38 .98 2.50

.43

.17

.17

.69

.99

1.20

2.08

.94 2.48

.40

.17

.17

.53

.87

1.15

1.74

.74 2.08

.36

.17

.17

.53

.79

1.10

1.42

.74 1.761*

2.040* .275* .392* .171* .171* .171* .171* .474* .541* .687* .830* .909* .889* 1.319* 1.380* .559* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43243 43243 43244 43244 43245 43245 43246 43246 43247 43247 43248 43248 43249 43249 43250 43250 43252 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Isoprene Isoprene 2,2-Dimethylbutane 2,2-Dimethylbutane 1-Hexene 1-Hexene 2-Methyl-1-pentene 2-Methyl-1-pentene 2,4-Dimethylpentane 2,4-Dimethylpentane Cyclohexane Cyclohexane 3-Methylhexane 3-Methylhexane 2,2,4-Trimethylpentane 2,2,4-Trimethylpentane 2,3,4-Trimethylpentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 15 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

16 1 16 1 15 1 16 1 16 1 16 1 16 1 16 1 .59

.37 .27 .73 .59 .45 .11 1.08 .56 1.73 1.23 2.11 1.11 .09 .09 .13 .13 .35

.44

.43

.66

1.49

1.50

.09

.13 .30

.37

.11

.64

1.25

1.45

.09

.13 .26

.36

.11

.62

1.18

1.45

.09

.13 .588*

.214* .270* .231* .589* .152* .108* .528* .561* .968* 1.230* 1.098* 1.110* .094* .094* .130* .130* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43252 43253 43253 43256 43256 43257 43257 43261 43261 43262 43262 43263 43263 43279 43279 43282 43282 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 2,3,4-Trimethylpentane 3-Methylheptane 3-Methylheptane alpha.-Pinene alpha.-Pinene beta.-Pinene beta.-Pinene Methylcyclohexane Methylcyclohexane Methylcyclopentane Methylcyclopentane 2-Methylhexane 2-Methylhexane 1-Nonene 1-Nonene 3-Methyl-1-butene 3-Methyl-1-butene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 16 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 16

1 16 1 16 1 16 1 16 1 16 1 16 1 16 1 16 .13

.13 1.13 .72 3.18 2.12 .17 .17 .17 .17 1.63 .96 .46 .27 .11 .11 .12 .13

.93

2.84

.17

.17

1.28

.42

.11

.12 .13

.74

2.13

.17

.17

1.07

.36

.11

.12 .13

.70

1.92

.17

.17

1.01

.32

.11

.12 .130*

.130* .622* .724* 1.793* 2.120* .171* .171* .171* .171* .909* .958* .208* .267* .108* .108* .119* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43283 43283 43284 43284 43285 43285 43289 43289 43290 43290 43291 43291 43292 43292 43298 43298 43299 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Cyclopentene Cyclopentene 2,3-Dimethylbutane 2,3-Dimethylbutane 2-Methylpentane 2-Methylpentane trans-2-Hexene trans-2-Hexene cis-2-Hexene cis-2-Hexene 2,3-Dimethylpentane 2,3-Dimethylpentane 2-2-3-Trimethylpentane 2-2-3-Trimethylpentane 1-Decene 1-Decene 1-Undecene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 17 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 6 7 6 7 6 7 6 7 6 7 30 31 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

16 1 16 1 61 6 61 6 61 6 61 6 61 6 61 6 .12

.11 .11 1.00 .19 .00 .13 .05 .05 .03 .09 .12 .00 .22 .10 4.9 4.1 .11

.49

.00 .00 .05 .05 .03 .03 .00 .00 .19 .00 4.7 4.0 .11

.48

.00 .00 .05 .05 .03 .03 .00 .00 .17 .00 4.7 3.5 .11

.19

.00 .00 .05 .05 .03 .03 .00 .00 .16 .00 4.5 3.2 .119*

.113* .113* .278* .192* .000 .022* .048 .048* .033 .043* .002 .000* .020 .017* 3.23 3.28* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43299 43328 43328 43330 43330 43372 43372 43373 43373 43396 43396 43438 43438 43441 43441 43502 43502 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 1-Undecene 1-Heptene 1-Heptene Dodecene Dodecene Methyl tert-butyl ether Methyl tert-butyl ether Tert-amyl methyl ether Tert-amyl methyl ether tert-Butyl ethyl ether tert-Butyl ethyl ether Ethyl acrylate Ethyl acrylate Methyl methacrylate Methyl methacrylate Formaldehyde Formaldehyde Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 101 101 101 101 101 101 101 101 101 101 202 202 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 18 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

32 30 31 32 30 31 32 6 7 30 31 32 30 31 32 30 31 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 48

61 6 48 61 6 48 61 6 61 6 48 61 6 48 61 6 10.2

6.2 4.0 7.6 1.1 .9 1.7 6.42 1.94 1.268 .980 1.552 .0 .0 .0 .7 .6 5.6

6.1 3.7 7.6 1.1 .8 1.2 5.97 1.72 1.196 .836 1.448 .0 .0 .0 .7 .4 5.5

5.8 3.5 4.7 1.1 .7 1.0 4.35 1.44 1.172 .704 1.076 .0 .0 .0 .7 .4 5.5

5.5 3.1 4.7 1.1 .7 1.0 2.61 1.36 1.144 .660 .960 .0 .0 .0 .6 .3 3.49*

3.21 3.16* 2.73* .64 .68* .57* 1.575 1.398* .6496 .7093* .5488* .01 .01* .03* .35 .37* 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43502 43503 43503 43503 43504 43504 43504 43505 43505 43510 43510 43510 43513 43513 43513 43517 43517 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Formaldehyde Acetaldehyde Acetaldehyde Acetaldehyde Propionaldehyde Propionaldehyde Propionaldehyde Acrolein - Unverified Acrolein - Unverified Butyraldehyde Butyraldehyde Butyraldehyde Isovaleraldehyde Isovaleraldehyde Isovaleraldehyde Hexanaldehyde Hexanaldehyde Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

202 202 202 202 202 202 202 101 101 202 202 202 202 202 202 202 202 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 19 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

32 30 31 32 30 31 32 30 31 32 30 31 32 6 7 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 47

61 6 47 61 6 48 61 6 48 61 6 43 61 6 61 6 1.2

.6 .4 .7 .8 .7 1.6 21.8 14.1 22.7 2.8 1.4 2.9 .75 .43 2.28 .81 1.0

.5 .3 .5 .8 .6 1.2 21.2 13.5 19.1 2.2 1.2 2.0 .72 .40 .66 .62 .6

.5 .3 .4 .8 .5 1.2 19.7 12.5 16.6 2.2 1.2 1.9 .61 .34 .64 .55 .5

.5 .3 .4 .7 .3 1.1 18.5 11.0 16.4 2.1 1.2 1.7 .60 .29 .56 .53 .27*

.26 .29* .16* .38 .42* .68* 9.92 10.27* 11.26* 1.07 1.06* .97* .328 .300* .403 .538* 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43517 43518 43518 43518 43528 43528 43528 43551 43551 43551 43552 43552 43552 43560 43560 43702 43702 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Hexanaldehyde Valeraldehyde Valeraldehyde Valeraldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Acetone Acetone Acetone Methyl ethyl ketone Methyl ethyl ketone Methyl ethyl ketone Methyl isobutyl ketone Methyl isobutyl ketone Acetonitrile Acetonitrile Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

202 202 202 202 202 202 202 202 202 202 202 202 202 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 20 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 61

6 61 6 61 6 61 6 61 6 61 6 61 6 61 6 61 .77

.15 1.05 .72 6.68 .72 .15 .11 .14 .12 .01 .01 .34 .33 .29 .16 .00 .00

.00 .84 .70 3.27 .26 .14 .11 .14 .11 .01 .00 .34 .30 .19 .00 .00 .00

.00 .82 .62 2.21 .18 .14 .08 .13 .10 .01 .00 .33 .29 .18 .00 .00 .00

.00 .82 .60 .64 .15 .12 .07 .13 .10 .01 .00 .33 .26 .15 .00 .00 .013

.025* .639 .628* .413 .257* .065 .074* .109 .104* .001 .002* .280 .280* .025 .027* .000 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43704 43704 43801 43801 43802 43802 43803 43803 43804 43804 43806 43806 43811 43811 43812 43812 43813 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Acrylonitrile Acrylonitrile Chloromethane Chloromethane Dichloromethane Dichloromethane Chloroform Chloroform Carbon tetrachloride Carbon tetrachloride Bromoform Bromoform Trichlorofluoromethane Trichlorofluoromethane Chloroethane Chloroethane 1,1-Dichloroethane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 21 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 6

61 6 61 6 61 6 61 6 61 6 61 6 61 6 61 6 .00

.05 .06 .08 .06 .88 .17 .02 .00 .02 .02 .02 .00 .22 .22 .63 .59 .00

.04 .03 .07 .05 .41 .15 .02 .00 .02 .01 .00 .00 .21 .18 .62 .56 .00

.04 .02 .06 .05 .40 .14 .00 .00 .02 .01 .00 .00 .20 .18 .61 .54 .00

.03 .02 .06 .04 .37 .10 .00 .00 .02 .01 .00 .00 .20 .16 .59 .47 .000*

.019 .028* .035 .039* .135 .115* .001 .000* .009 .011* .000 .000* .164 .170* .512 .512* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43813 43814 43814 43815 43815 43817 43817 43818 43818 43819 43819 43820 43820 43821 43821 43823 43823 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 1,1-Dichloroethane Methyl chloroform Methyl chloroform Ethylene dichloride Ethylene dichloride Tetrachloroethylene Tetrachloroethylene 1,1,2,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Bromomethane Bromomethane 1,1,2-Trichloroethane 1,1,2-Trichloroethane 1,1,2-Trichloro-1,2,2- trifluoroethane 1,1,2-Trichloro-1,2,2- trifluoroethane Dichlorodifluoromethane Dichlorodifluoromethane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 22 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 61

6 61 6 61 6 61 6 61 6 61 6 61 6 61 6 61 .06

.02 0 0 .02 .01 .00 .00 .05 .00 .06 .00 .02 .01 .00 .00 .01 .05

.01 0 0 .01 .01 .00 .00 .00 .00 .00 .00 .02 .01 .00 .00 .01 .03

.00 0 0 .01 .01 .00 .00 .00 .00 .00 .00 .01 .01 .00 .00 .01 .03

.00 0 0 .01 .01 .00 .00 .00 .00 .00 .00 .01 .01 .00 .00 .01 .007

.005* .0 .0* .011 .011* .000 .000* .001 .000* .001 .000* .009 .009* .000 .000* .007 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43824 43824 43826 43826 43828 43828 43829 43829 43830 43830 43831 43831 43832 43832 43835 43835 43836 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Trichloroethylene Trichloroethylene 1,1-Dichloroethylene 1,1-Dichloroethylene Bromodichloromethane Bromodichloromethane 1,2-Dichloropropane 1,2-Dichloropropane trans-1,3-Dichloropropene trans-1,3-Dichloropropene cis-1,3-Dichloropropene cis-1,3-Dichloropropene Dibromochloromethane Dibromochloromethane Chloroprene Chloroprene Bromochloromethane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 23 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 6 7 6 7 6 7 6 7 6 7 8 9 8 9 1

6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012

2012 6

61 6 61 6 61 6 61 6 61 6 16 1 16 1 8361

61 .01

.09 .01 .02 .02 .02 .00 .05 .02 .01 .00 .12 .12 .43 .30 .084

10.24 .01

.06 .01 .02 .02 .01 .00 .05 .00 .00 .00 .12

.39

.083

9.60 .01

.04 .01 .02 .02 .00 .00 .02 .00 .00 .00 .12

.33

.080

9.36 .01

.03 .01 .02 .02 .00 .00 .02 .00 .00 .00 .12

.31

.076

8.96 .007*

.015 .012* .018 .018* .000 .000* .002 .003* .000 .000* .119* .119* .207* .299* .0467

3.592 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 8-HR RUN AVG BEGIN HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 43836 43838 43838 43839 43839 43843 43843 43844 43844 43860 43860 43954 43954 43960 43960 44201

45109 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Bromochloromethane trans-1,2-Dichloroethylene trans-1,2-Dichloroethylene cis-1,2-Dichloroethene cis-1,2-Dichloroethene Ethylene dibromide Ethylene dibromide Hexachlorobutadiene Hexachlorobutadiene Vinyl chloride Vinyl chloride n-Undecane n-Undecane 2-Methylheptane 2-Methylheptane Ozone m/p Xylene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per million Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 126 126 126 126 087

101 Cert

S S S S S S S S S S S S S S S S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 24 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 8 9 6 7 8 9 6 7 8 9 6 7 8 9 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 6

16 1 61 6 13 1 61 6 16 1 61 6 16 1 61 6 4.58

2.54 1.76 6.78 3.01 1.47 .00 23.59 11.62 6.27 4.62 3.60 1.83 .92 .65 4.08 1.81 4.46

2.36

6.00 2.66 1.36

23.38 9.94 5.09

3.45 1.67 .80

3.98 1.78 4.41

1.86

5.38 2.59 1.15

22.47 8.96 4.95

3.30 1.55 .67

3.77 1.77 2.72

1.72

5.20 2.09 .86

22.05 5.93 4.19

3.13 1.06 .55

3.73 1.11 3.491*

1.354* 1.760* 2.404 2.182* .808* .000* 8.251 7.792* 3.409* 4.620* 1.337 1.315* .469* .650* 1.443 1.405* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45109 45109 45109 45201 45201 45201 45201 45202 45202 45202 45202 45203 45203 45203 45203 45204 45204 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: m/p Xylene m/p Xylene m/p Xylene Benzene Benzene Benzene Benzene Toluene Toluene Toluene Toluene Ethylbenzene Ethylbenzene Ethylbenzene Ethylbenzene o-Xylene o-Xylene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 126 126 101 101 126 126 101 101 126 126 101 101 126 126 101 101 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 25 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 6 7 8 9 6 7 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 16

1 61 6 16 1 61 6 16 1 16 1 16 1 16 1 16 .99

.70 1.17 .63 .32 .23 3.68 1.87 .86 .67 .21 .17 .16 .08 .38 .07 .53 .96

1.15 .52 .23

3.66 1.59 .82

.21

.14

.30

.53 .74

.97 .44 .21

3.24 1.51 .71

.19

.11

.27

.40 .68

.91 .39 .20

3.06 1.02 .65

.18

.08

.22

.39 .559*

.700* .406 .441* .131* .230* 1.284 1.314* .524* .672* .132* .172* .031* .080* .143* .068* .318* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45204 45204 45207 45207 45207 45207 45208 45208 45208 45208 45209 45209 45210 45210 45211 45211 45212 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: o-Xylene o-Xylene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene n-Propylbenzene n-Propylbenzene Isopropylbenzene Isopropylbenzene o-Ethyltoluene o-Ethyltoluene m-Ethyltoluene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 101 101 126 126 101 101 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 26 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 6 7 8 9 8 9 8 9 30 31 32 30 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 1

15 1 16 1 61 6 15 1 16 1 16 1 61 6 46 61 .41

.79 .11 .28 .09 .98 .62 .00 .00 .30 .16 .28 .25 1.0 .6 .9 .0 .72

.09

.79 .39 .00

.19

.25

.9 .6 .8 .0 .43

.09

.77 .37 .00

.17

.23

.9 .5 .8 .0 .43

.09

.72 .31 .00

.17

.21

.8 .4 .7 .0 .405*

.267* .108* .098* .086* .312 .357* .000* .000* .124* .160* .159* .250* .42 .45* .35* .02 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45212 45218 45218 45219 45219 45220 45220 45220 45220 45225 45225 45228 45228 45501 45501 45501 45503 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: m-Ethyltoluene m-Diethylbenzene m-Diethylbenzene p-Diethylbenzene p-Diethylbenzene Styrene Styrene Styrene Styrene 1,2,3-Trimethylbenzene 1,2,3-Trimethylbenzene Benzene, 1-ethenyl-4-methyl Benzene, 1-ethenyl-4-methyl Benzaldehyde Benzaldehyde Benzaldehyde 2,5-Dimethylbenzaldehyde Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 101 101 126 126 126 126 126 126 202 202 202 202 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 27 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

31 32 30 31 32 6 7 6 7 6 7 6 7 6 7 1 1 1 1 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 6

48 56 6 43 61 6 61 6 61 6 61 6 61 6 8775 8775 8775 8775 .0

.1 .9 .5 1.0 .59 .00 .25 .06 .25 .07 .49 .32 .14 .04 13.4 360.0 115 96 .0

.1 .8 .5 .8 .05 .00 .06 .06 .07 .07 .47 .31 .12 .00 13.2 360.0 115 96 .0

.1 .7 .4 .8 .05 .00 .06 .06 .07 .07 .46 .28 .08 .00 12.4 360.0 114 96 .0

.1 .7 .4 .8 .00 .00 .06 .06 .07 .07 .43 .14 .07 .00 12.4 360.0 114 96 .02*

.08* .37 .38* .38* .011 .000* .066 .063* .075 .072* .195 .215* .009 .007* 2.49 172.84 75.1 34.9 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45503 45503 45504 45504 45504 45801 45801 45805 45805 45806 45806 45807 45807 45810 45810 61103 61104 62101 62201 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 2,5-Dimethylbenzaldehyde 2,5-Dimethylbenzaldehyde Tolualdehydes Tolualdehydes Tolualdehydes Chlorobenzene Chlorobenzene 1,2-Dichlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,4-Dichlorobenzene 1,2,4-Trichlorobenzene 1,2,4-Trichlorobenzene Wind Speed - Resultant Wind Direction - Resultant Outdoor Temperature Relative Humidity Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Knots Degrees Compass Degrees Fahrenheit Percent relative humidity Meth

202 202 202 202 202 101 101 101 101 101 101 101 101 101 101 020 020 021 012 Cert

S S S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 28 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 1 7 7 7 1 7 3 3 4 4 1 1 1 1 1 1 1 1 1 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 122

122 121 122 122 122 121 122 362 8662 4351 182 30 30 30 30 30 30 30 30 30 31.3

46.7 38.7 38.4 739 749 738 742 344 4985 4427 329 8.13 2.77 .25 .62 9.73 7.26 .0105 106.00 7.73 31.0

45.6 38.3 38.1 738 744 737 741 120 1633 1993 120 6.35 1.88 .19 .33 5.48 5.34 .0081 62.20 6.55 30.3

45.1 38.1 37.9 737 744 737 740 120 1084 708 108 5.74 1.83 .12 .28 5.35 2.75 .0073 61.80 4.67 29.9

44.2 37.9 37.7 736 743 735 738 118 934 519 97 5.51 1.27 .09 .21 5.06 2.14 .0072 49.60 3.96 15.58

32.38 24.00 23.65 729.3 736.1 728.4 732.2 34.8 35.3 33.5* 33.1* 2.731* .760* .055* .136* 3.714* 1.327* .00463* 26.677* 2.526* 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24-HR BLK AVG 1 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 5 5 5 5 0 0 0 0 0 0 0 0 0 68103 68104 68105 68105 68106 68107 68108 68108 81102 81102 81102 81102 82102 82103 82105 82110 82112 82113 82128 82132 82136 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Ambient Min Temperature Ambient Max Temperature Ambient Temperature Ambient Temperature Sample Min Baro Pressure Sample Max Baro Pressure Sample Baro Pressure Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP Antimony PM10 STP Arsenic PM10 STP Beryllium PM10 STP Cadmium PM10 STP Chromium PM10 STP Cobalt PM10 STP Lead PM10 STP Manganese PM10 STP Nickel PM10 STP Degrees Centigrade Degrees Centigrade Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Millimeters (mercury) Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Meth

810 810 143 810 810 810 143 810 122 122 079 079 202 202 202 202 202 202 202 202 202 Cert

S S S S S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 29 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 1 1 1 1 1 1 1 1 1 1 1 1 3 1 3 3 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 30

30 31 31 31 31 31 31 31 31 31 31 31 8630 121 364 8683 .02

.61 8.410 1.250 .0900 .4200 10.7 1.4400 .0114 38.800 2.790 .0400 .890 4448.0 52.0 55.9 537.0 .02

.31 8.400 1.240 .0900 .3900 8.8 1.2200 .0101 32.800 2.590 .0300 .640 1348.0 28.8 38.7 202.0 .02

.29 8.200 1.050 .0800 .2700 8.5 .9800 .0073 30.200 2.420 .0300 .460 896.0 27.0 29.5 200.0 .02

.27 7.200 1.010 .0700 .2300 6.9 .7300 .0066 29.500 2.380 .0300 .460 766.0 18.1 25.2 168.0 .010*

.155* 3.2132* .5990* .04055* .12710* 5.35* .46645* .00401* 18.9761* 1.5726* .01493* .2669* 25.63 9.23 7.86 7.91 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24 HOUR 24-HR BLK AVG 1 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 82142 82154 85102 85103 85105 85110 85112 85113 85129 85132 85136 85142 85154 86101 88101 88101 88101 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Mercury PM10 STP Selenium PM10 STP Antimony PM10 LC Arsenic PM10 LC Beryllium PM10 LC Cadmium PM10 LC Chromium PM10 LC Cobalt PM10 LC Lead PM10 LC FRM/FEM Manganese PM10 LC Nickel PM10 LC Mercury PM10 LC Selenium PM10 LC PM10-2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Micrograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

202 202 202 202 202 202 202 202 202 202 202 202 202 185 143 170 170 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 30 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 122

122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 .086

.007 1.330 .497 .015 .028 .805 .033 .003 .225 1.750 .044 .023 .853 .016 .042 .013 .063

.003 .655 .053 .011 .019 .372 .025 .003 .025 .398 .044 .023 .496 .011 .028 .013 .056

.003 .564 .030 .010 .019 .357 .017 .002 .018 .360 .043 .023 .388 .010 .021 .013 .054

.002 .405 .030 .009 .014 .313 .011 .002 .018 .299 .043 .023 .385 .007 .017 .008 .0212

.0005 .1163 .0120 .0039 .0022 .1129 .0024 .0009 .0084 .0738 .0058 .0075 .1560 .0016 .0106 .0031 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88102 88103 88104 88107 88109 88110 88111 88112 88113 88114 88115 88117 88118 88126 88128 88131 88132 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Antimony PM2.5 LC Arsenic PM2.5 LC Aluminum PM2.5 LC Barium PM2.5 LC Bromine PM2.5 LC Cadmium PM2.5 LC Calcium PM2.5 LC Chromium PM2.5 LC Cobalt PM2.5 LC Copper PM2.5 LC Chlorine PM2.5 LC Cerium PM2.5 LC Cesium PM2.5 LC Iron PM2.5 LC Lead PM2.5 LC Indium PM2.5 LC Manganese PM2.5 LC Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 31 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 122

122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 .009

.726 .008 .001 .033 .075 .005 4.030 .019 .062 .100 2.190 .003 6.970 .389 .018 1.36 .008

.122 .008 .001 .026 .040 .004 1.820 .019 .029 .045 .829 .001 .488 .362 .012 .92 .005

.108 .008 .001 .025 .035 .004 1.550 .019 .026 .012 .824 .001 .434 .360 .012 .81 .003

.099 .008 .001 .021 .031 .004 1.020 .019 .025 .010 .805 .001 .355 .351 .012 .80 .0005

.0261 .0057 .0011 .0130 .0090 .0017 .3525 .0086 .0089 .0030 .3483 .0010 .1756 .0937 .0041 .376 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88136 88140 88152 88154 88160 88161 88164 88165 88166 88167 88168 88169 88176 88180 88184 88185 88301 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Nickel PM2.5 LC Magnesium PM2.5 LC Phosphorus PM2.5 LC Selenium PM2.5 LC Tin PM2.5 LC Titanium PM2.5 LC Vanadium PM2.5 LC Silicon PM2.5 LC Silver PM2.5 LC Zinc PM2.5 LC Strontium PM2.5 LC Sulfur PM2.5 LC Rubidium PM2.5 LC Potassium PM2.5 LC Sodium PM2.5 LC Zirconium PM2.5 LC Ammonium Ion PM2.5 LC Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 812 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 32 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 122

122 122 120 120 120 120 120 120 120 120 120 113 113 119 120 122 .43

7.53 4.14 14.200 3.010 13.400 2.280 3.590 3.150 1.360 4.730 3.280 6.530 .233 .039 5.440 5.65 .39

.36 3.89 9.490 2.890 9.100 1.440 2.110 2.300 1.160 1.350 2.740 3.320 .152 .033 1.740 2.48 .39

.32 3.62 6.100 2.040 5.910 .872 1.620 2.140 1.060 .827 2.260 3.020 .147 .012 1.050 2.46 .39

.27 2.38 6.060 1.930 5.880 .812 1.440 1.940 1.010 .691 2.260 2.530 .137 .011 .971 2.31 .114

.109 .736 2.4843 .6034 2.3269 .1682 .5815 .8343 .4856 .2571 .7606 .8805 .0672 .0022 .4143 1.053 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88302 88303 88306 88355 88357 88370 88374 88375 88376 88377 88378 88380 88383 88384 88385 88388 88403 Parameter Site ID: 04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Sodium Ion Pm2.5 LC Potassium Ion PM2.5 LC Total Nitrate PM2.5 LC OC CSN_Rev Unadjusted PM2.5 LC TOT EC CSN_Rev Unadjusted PM2.5 LC TOT OC CSN_Rev Unadjusted PM2.5 LC TOR OC1 CSN_Rev Unadjusted PM2.5 LC OC2 CSN_Rev Unadjusted PM2.5 LC OC3 CSN_Rev Unadjusted PM2.5 LC OC4 CSN_Rev Unadjusted PM2.5 LC OP CSN_Rev Unadjusted PM2.5 LC TOR EC CSN_Rev Unadjusted PM2.5 LC TOR EC1 CSN_Rev Unadjusted PM2.5 LC EC2 CSN_Rev Unadjusted PM2.5 LC EC3 CSN_Rev Unadjusted PM2.5 LC OP CSN_Rev Unadjusted PM2.5 LC TOT Sulfate PM2.5 LC Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

812 812 812 839 840 838 841 841 841 841 842 831 841 841 841 826 812 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 33 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3 7

1 1

1 3 3 1

3 3

3 3

1 0053 0053 0053

0053 0053

0053 0053 0053 0053

0053 0053

0053 0053

0053 2012 2012 2012

2012 2012

2012 2012 2012 2012

2012 2012

2012 2012

2012 91

2180 122

8784 8784

30 181 4330 30

357 8578

363 8677

2181 59.0

205.9 49.0

1.54 .07

35 185 893 33

138 1895

239 1671

27.2 23.9

199.1 26.7

1.53 .07

33 74 719 31

116 1318

228 1560

19.1 20.5

170.7 24.6

1.53 .07

32 64 670 30

109 582

127 1267

15.0 20.3

150.9 21.6

1.53 .07

31 45 647 29

109 542

127 1188

14.5 12.76*

12.81 9.71

.353 .016

18.3* 21.3* 21.8* 17.8*

33.7 34.4

42.4 42.9

4.30* 24-HR BLK AVG 1 HOUR 24 HOUR

1 HOUR 1 HOUR

24 HOUR 24-HR BLK AVG 1 HOUR 24 HOUR

24-HR BLK AVG 1 HOUR

24-HR BLK AVG 1 HOUR

1 HOUR 0

0 0

0 0

0 5 5 0

0 0

5 5

0 88500 88500 88502

63301 63302

81102 81102 81102 85101

81102 81102

81102 81102

42600 Parameter Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

Site ID: 04-013-9997

04-013-9998

04-015-1003

04-019-0001

04-019-0020

04-021-8001 Phoenix

Phoenix

Bullhead City

Ajo

Rillito

Queen Valley City:

City:

City:

City:

City:

City: Maricopa

Maricopa

Mohave

Pima

Pima

Pinal Unit County:

County:

County:

County:

County:

County: 4530 N 17TH AVENUE

600 N 40TH ST & FILLMORE ST,PHOENIX

BULLHEAD CITY 990 HWY 95

AZ HWY DEPT YARD-WELL RD, AJO

8840 W ROBINSON STREET, RILLITO

10 S QUEEN ANN QUEEN VALLEY Address:

Address:

Address:

Address:

Address:

Address: PM2.5 Total Atmospheric PM2.5 Total Atmospheric Acceptable PM2.5 AQI & Speciation Mass

Solar radiation Ultraviolet radiation

PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 - LC

PM10 Total 0-10um STP PM10 Total 0-10um STP

PM10 Total 0-10um STP PM10 Total 0-10um STP

Reactive oxides of nitrogen (NOy) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Langleys/minute Langleys/minute Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Parts per billion Meth

761 761 810

011 011

126 079 079 126

079 079

079 079

574 Cert

S S S

S S

S S S S

S S

S S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 34 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 15

47 5 21 15 47 15 47 15 47 15 47 15 47 15 47 15 119.00 174.00 .08 4.27 .19 .19 .19 .19 .19 .19 .09 .09 .11 .11 4.78 5.38 3.10 109.00

121.00 .08 .08 .19 .19 .19 .19 .19 .19 .09 .09 .11 .11 4.66 5.20 2.93 91.40

114.00 .08 .08 .19 .19 .19 .19 .19 .19 .09 .09 .11 .11 4.44 4.94 2.66 90.80

102.00 .08 .08 .19 .19 .19 .19 .19 .19 .09 .09 .11 .11 3.89 4.72 2.41 83.547*

59.387* .083* .282* .192* .192* .192* .192* .192* .192* .092* .092* .106* .106* 2.527* 2.549* 1.732* 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43102 43102 43127 43127 43141 43141 43142 43142 43143 43143 43144 43144 43145 43145 43202 43202 43203 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: Total NMOC (non-methane organic compound) Total NMOC (non-methane organic compound) Isobutene & 1-butene Isobutene & 1-butene n-Dodecane n-Dodecane Tridecene Tridecene n-Tridecane n-Tridecane Propyne Propyne 1-Octene 1-Octene Ethane Ethane Ethylene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 35 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 47

15 47 15 47 15 47 15 47 15 47 15 47 15 47 15 47 3.18

2.51 2.85 .80 1.00 .66 .73 .91 1.09 .51 .78 .38 .33 .10 .10 .50 .46 3.01

2.36 2.62 .71 .98 .66 .62 .82 1.08 .28 .45 .18 .32 .10 .10 .44 .44 2.98

2.36 2.61 .55 .80 .55 .60 .65 1.01 .27 .34 .16 .27 .10 .10 .44 .44 2.93

2.16 2.60 .53 .79 .34 .57 .65 .84 .27 .33 .07 .26 .10 .10 .39 .43 1.742*

1.312* 1.190* .477* .476* .320* .301* .478* .435* .191* .176* .106* .099* .100* .100* .128* .118* 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43203 43204 43204 43205 43205 43206 43206 43212 43212 43214 43214 43216 43216 43217 43217 43218 43218 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: Ethylene Propane Propane Propylene Propylene Acetylene Acetylene n-Butane n-Butane Isobutane Isobutane trans-2-Butene trans-2-Butene cis-2-Butene cis-2-Butene 1,3-Butadiene 1,3-Butadiene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 36 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 15

47 10 36 15 47 15 47 15 47 15 47 14 45 15 47 15 13.10

51.60 7.77 19.60 .38 .44 .13 .13 .08 .08 .11 .11 .13 .13 .17 .28 .31 .50

23.00 4.32 8.54 .36 .43 .13 .13 .08 .08 .11 .11 .13 .13 .08 .24 .18 .49

1.00 4.31 8.32 .34 .42 .13 .13 .08 .08 .11 .11 .13 .13 .08 .22 .17 .49

.72 .66 7.72 .30 .38 .13 .13 .08 .08 .11 .11 .13 .13 .08 .22 .17 1.191*

1.903* 1.843* 2.081* .159* .159* .130* .130* .076* .076* .108* .108* .130* .130* .084* .099* .098* 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43220 43220 43221 43221 43224 43224 43225 43225 43226 43226 43227 43227 43228 43228 43230 43230 43231 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: n-Pentane n-Pentane Isopentane Isopentane 1-Pentene 1-Pentene 2-Methyl-1-butene 2-Methyl-1-butene trans-2-Pentene trans-2-Pentene cis-2-Pentene cis-2-Pentene 2-Methyl-2-butene 2-Methyl-2-butene 3-Methylpentane 3-Methylpentane n-Hexane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 37 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 47

15 47 15 47 15 47 15 47 15 47 15 47 15 47 15 47 .67

.22 .22 .20 .24 .17 .17 .06 .06 .17 .17 .08 .17 .07 2.46 .95 1.68 .39

.08 .08 .08 .17 .17 .17 .06 .06 .17 .17 .08 .08 .07 .78 .69 1.54 .28

.08 .08 .08 .08 .17 .17 .06 .06 .17 .17 .08 .08 .07 .07 .49 .95 .27

.08 .08 .08 .08 .17 .17 .06 .06 .17 .17 .08 .08 .07 .07 .49 .92 .089*

.085* .079* .086* .083* .171* .171* .062* .062* .171* .171* .078* .080* .075* .140* .407* .518* 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43231 43232 43232 43233 43233 43234 43234 43235 43235 43236 43236 43238 43238 43242 43242 43243 43243 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: n-Hexane n-Heptane n-Heptane n-Octane n-Octane 4-Methyl-1-pentene 4-Methyl-1-pentene n-Nonane n-Nonane 2-Ethyl-1-butene 2-Ethyl-1-butene n-Decane n-Decane Cyclopentane Cyclopentane Isoprene Isoprene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 38 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 15

47 15 47 15 47 15 47 15 47 15 47 15 47 15 47 15 .10

.10 .17 .17 .17 .17 .09 .09 .42 .25 .62 2.49 .21 .32 .35 .27 .06 .10

.10 .17 .17 .17 .17 .09 .09 .09 .21 .54 1.86 .18 .26 .07 .25 .06 .10

.10 .17 .17 .17 .17 .09 .09 .09 .20 .44 1.17 .17 .23 .07 .24 .06 .10

.10 .17 .17 .17 .17 .09 .09 .09 .09 .40 .56 .15 .21 .07 .20 .06 .099*

.099* .171* .171* .171* .171* .087* .087* .112* .098* .196* .231* .089* .067* .089* .090* .060* 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43244 43244 43245 43245 43246 43246 43247 43247 43248 43248 43249 43249 43250 43250 43252 43252 43253 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 2,2-Dimethylbutane 2,2-Dimethylbutane 1-Hexene 1-Hexene 2-Methyl-1-pentene 2-Methyl-1-pentene 2,4-Dimethylpentane 2,4-Dimethylpentane Cyclohexane Cyclohexane 3-Methylhexane 3-Methylhexane 2,2,4-Trimethylpentane 2,2,4-Trimethylpentane 2,3,4-Trimethylpentane 2,3,4-Trimethylpentane 3-Methylheptane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 39 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 47

15 47 15 46 15 46 15 47 15 47 15 47 15 47 15 45 .06

.11 .27 1.03 .63 .31 .21 .19 .32 .48 1.37 .09 .09 .13 .13 .13 .13 .06

.11 .23 .11 .51 .07 .07 .18 .23 .43 .97 .09 .09 .13 .13 .13 .13 .06

.11 .22 .11 .47 .07 .07 .17 .21 .40 .91 .09 .09 .13 .13 .13 .13 .06

.11 .11 .11 .41 .07 .07 .11 .17 .39 .68 .09 .09 .13 .13 .13 .13 .060*

.108* .116* .169* .148* .087* .074* .086* .080* .275* .265* .094* .094* .130* .130* .130* .130* 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43253 43256 43256 43257 43257 43261 43261 43262 43262 43263 43263 43279 43279 43282 43282 43283 43283 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 3-Methylheptane alpha.-Pinene alpha.-Pinene beta.-Pinene beta.-Pinene Methylcyclohexane Methylcyclohexane Methylcyclopentane Methylcyclopentane 2-Methylhexane 2-Methylhexane 1-Nonene 1-Nonene 3-Methyl-1-butene 3-Methyl-1-butene Cyclopentene Cyclopentene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 40 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 15

47 15 46 15 47 15 47 15 47 15 47 15 47 15 47 14 .12

.12 .80 1.48 .17 .17 .17 .17 .11 .26 .11 .11 .11 .11 .12 .12 .11 .12

.12 .47 .91 .17 .17 .17 .17 .11 .11 .11 .11 .11 .11 .12 .12 .11 .12

.12 .46 .83 .17 .17 .17 .17 .11 .11 .11 .11 .11 .11 .12 .12 .11 .12

.12 .44 .81 .17 .17 .17 .17 .11 .11 .11 .11 .11 .11 .12 .12 .11 .121*

.121* .368* .371* .171* .171* .171* .171* .113* .116* .106* .106* .108* .108* .119* .119* .113* 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43284 43284 43285 43285 43289 43289 43290 43290 43291 43291 43292 43292 43298 43298 43299 43299 43328 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 2,3-Dimethylbutane 2,3-Dimethylbutane 2-Methylpentane 2-Methylpentane trans-2-Hexene trans-2-Hexene cis-2-Hexene cis-2-Hexene 2,3-Dimethylpentane 2,3-Dimethylpentane 2-2-3-Trimethylpentane 2-2-3-Trimethylpentane 1-Decene 1-Decene 1-Undecene 1-Undecene 1-Heptene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 41 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 1

8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012

2012 2012 2012 2012 2012 2012 2012 2012 2012 45

15 47 15 47 15 47 5871

15 47 6 20 15 47 15 47 15 .11

.62 .75 .12 .12 .06 .06 .082

.22 .69 27.90 19.90 .96 1.92 .21 .24 .15 .11

.19 .62 .12 .12 .06 .06 .080

.19 .28 .00 8.97 .70 1.46 .11 .10 .10 .11

.19 .57 .12 .12 .06 .06 .079

.19 .27 .00 .00 .60 .72 .08 .09 .09 .11

.19 .55 .12 .12 .06 .06 .078

.16 .23 .00 .00 .54 .72 .00 .09 .09 .113*

.220* .248* .119* .119* .063* .063* .0584

.060* .055* 4.650* 1.444* .478* .385* .027* .011* .034* 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 8-HR RUN AVG BEGIN HOUR 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 43328 43330 43330 43954 43954 43960 43960 44201

45109 45109 45201 45201 45202 45202 45203 45203 45204 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 1-Heptene Dodecene Dodecene n-Undecane n-Undecane 2-Methylheptane 2-Methylheptane Ozone m/p Xylene m/p Xylene Benzene Benzene Toluene Toluene Ethylbenzene Ethylbenzene o-Xylene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per million Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 087

126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S

S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 42 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 47

15 47 15 47 15 47 15 47 15 47 15 47 14 46 15 47 .33

.06 .06 .25 .43 .07 .18 .06 .00 .07 .07 .06 .06 .11 .11 .09 .18 .17

.06 .06 .09 .36 .07 .17 .00 .00 .07 .07 .06 .06 .11 .11 .09 .09 .17

.06 .06 .09 .32 .07 .16 .00 .00 .07 .07 .06 .06 .11 .11 .09 .09 .14

.06 .06 .09 .24 .07 .07 .00 .00 .07 .07 .06 .06 .11 .11 .09 .09 .030*

.060* .060* .102* .112* .069* .075* .004* .000* .068* .068* .061* .061* .108* .108* .086* .088* 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45204 45207 45207 45208 45208 45209 45209 45210 45210 45211 45211 45212 45212 45218 45218 45219 45219 Parameter Site ID: 04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: o-Xylene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene n-Propylbenzene n-Propylbenzene Isopropylbenzene Isopropylbenzene o-Ethyltoluene o-Ethyltoluene m-Ethyltoluene m-Ethyltoluene m-Diethylbenzene m-Diethylbenzene p-Diethylbenzene p-Diethylbenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert

S S S S S S S S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 43 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 1 1 1 2

1 2 1 2 1 3 3 1 1 2 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012

2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 15

45 15 47 15 47 8592 8592 8591 8591

58 55 58 55 58 8110 337 58 58 52 .95

.66 .05 .18 .09 .09 24.3 360.0 112 100

28.4 29.1 669 668 102 793 169 94 29.0 26.7 .00

.00 .05 .05 .09 .09 23.9 360.0 112 100

27.9 28.5 665 666 72 667 153 65 25.9 22.5 .00

.00 .05 .05 .09 .09 23.5 360.0 112 100

27.4 28.0 665 666 69 635 139 64 23.2 15.9 .00

.00 .05 .05 .09 .09 23.5 360.0 112 99

27.4 28.0 665 665 67 499 123 58 22.7 15.7 .063*

.015* .052* .055* .094* .094* 6.07 157.81 73.5 29.7

18.30 18.73 662.5 662.9 36.7 48.1 47.7* 32.7 9.39 9.30* 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 1 HOUR 1 HOUR 1 HOUR 1 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 45220 45220 45225 45225 45228 45228 61103 61104 62101 62201

68105 68105 68108 68108 81102 81102 81102 85101 88101 88101 Parameter Site ID:

Site ID: 04-021-8001

04-023-0004 Queen Valley

Nogales City:

City: Pinal

Santa Cruz Unit County:

County: 10 S QUEEN ANN QUEEN VALLEY

300 N MORLEY AVE Address:

Address: Styrene Styrene 1,2,3-Trimethylbenzene 1,2,3-Trimethylbenzene Benzene, 1-ethenyl-4-methyl Benzene, 1-ethenyl-4-methyl Wind Speed - Resultant Wind Direction - Resultant Outdoor Temperature Relative Humidity

Ambient Temperature Ambient Temperature Sample Baro Pressure Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions PM2.5 - Local Conditions Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Knots Degrees Compass Degrees Fahrenheit Percent relative humidity Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

126 126 126 126 126 126 020 020 021 012

143 143 143 143 126 122 122 126 143 143 Cert

S S S S S S S S S S

S S S S S S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 44 of 54 P O C PQAO Year # Obs 1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3

1 1 1 1 1

1

1

1 1 3 3 1 0053 0053

0053 0053 0053 0053 0053

0053

0053

0053 0053 0053 0053 0053 2012 2012

2012 2012 2012 2012 2012

2012

2012

2012 2012 2012 2012 2012 219

5256

60 60 58 58 59

5746

5859

59 59 365 8735 57 89.0

256.0

28.0 640 39 33 14.0

.074

.092

37.9 762 274 1881 17.0 41.0

243.0

27.5 638 35 28 10.8

.073

.082

37.8 762 240 1747 15.8 38.7

238.0

27.5 638 28 24 10.2

.072

.080

37.7 761 220 1709 15.3 36.6

230.0

26.8 637 28 23 9.4

.072

.080

36.1 760 215 1626 14.5 11.67*

11.70*

15.25 633.7 12.5 10.6 4.47

.0518

.0523

25.29 753.5 43.2 43.7 8.46 24-HR BLK AVG 1 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

8-HR RUN AVG BEGIN HOUR

8-HR RUN AVG BEGIN HOUR 24 HOUR 24 HOUR 24-HR BLK AVG 1 HOUR 24 HOUR 0

0

0 0 0 0 0

0

0

0 0 5 5 0 88501 88501

68105 68108 81102 85101 88101

44201

44201

68105 68108 81102 81102 88101 Parameter Site ID:

Site ID:

Site ID:

Site ID: 04-023-0004

04-025-2002

04-025-8033

04-027-8011 Nogales

Prescott Valley

Prescott

Yuma City:

City:

City:

City: Santa Cruz

Yavapai

Yavapai

Yuma Unit County:

County:

County:

County: 300 N MORLEY AVE

7501 E. CIVIC CIRCLE, PRESCOTT VALLEY

330 Grove Avenue

2323 S ARIZONA AVE Address:

Address:

Address:

Address: PM2.5 Raw Data PM2.5 Raw Data

Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions

Ozone

Ozone Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM2.5 - Local Conditions Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per million

Parts per million Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Meth

731 731

143 143 126 126 143

047

087

143 143 079 079 143 Cert

S S

S S S S S

S

S

S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 45 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

12115 14129 17141 17147 17148 17149 17150 17151 17158 17159 17160 17201 17204 17208 17211 17212 17215 17220 17223 17224 17231 17237 17242 17243 42101 42153 42401 42401 42406 42406 42600 42600 42601 920

191 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 588 101 060 592 060 592 574 591 074 LO-VOL-XONTECH 920 or 924

Hi-Vol Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 INSTRUMENTAL CANISTER SUBAMBIENT PRESSURE INSTRUMENTAL Instrumental INSTRUMENTAL Instrumental Instrumental Instrumental INSTRUMENTAL ION CHROMATOGRAPH UV VISIBLE Inductively Coupled Plasma-Mass Spectrometry Acid filter extraction with nitric and hydrochloric acid GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 Gas Filter Correlation Ecotech EC9830T MULTI DETECTOR GC PULSED FLUORESCENT Ultraviolet Fluorescence EC9850T PULSED FLUORESCENT Ultraviolet Fluorescence EC9850T Chemiluminescence Thermo Electron 42C-Y, 42i-Y Chemiluminescence Ecotech EC9843 CHEMILUMINESCENCEUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 46 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

42602 42603 43102 43127 43141 43142 43143 43144 43145 43202 43203 43204 43205 43205 43206 43206 43208 43212 43214 43216 43217 43218 43218 43220 43221 43224 43225 43226 43227 43228 43230 43231 43232 43233 074

074 126 126 126 126 126 126 126 126 126 126 101 126 101 126 101 126 126 126 126 101 126 126 126 126 126 126 126 126 126 126 126 101 INSTRUMENTAL

INSTRUMENTAL SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED Canister Subambient Pressure SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE CHEMILUMINESCENCE CHEMILUMINESCENCE CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID Multi Detector GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FIDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 47 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43233 43234 43235 43236 43238 43242 43243 43244 43245 43246 43247 43248 43249 43250 43252 43253 43256 43257 43261 43262 43263 43279 43282 43283 43284 43285 43289 43290 43291 43292 43298 43299 43328 126

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FIDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 48 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43330 43372 43373 43396 43438 43441 43502 43503 43504 43505 43510 43513 43517 43518 43528 43551 43552 43560 43702 43704 43801 43802 43803 43804 43806 43811 43812 43813 43814 43815 43817 43818 43819 126

101 101 101 101 101 202 202 202 101 202 202 202 202 202 202 202 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 SS CANISTER PRESSURIZED

Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB CANISTER SUBAMBIENT PRESSURE SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID Multi Detector GC Multi Detector GC Multi Detector GC Multi Detector GC Multi Detector GC HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION MULTI DETECTOR GC HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION Multi Detector GC Multi Detector GC Multi Detector GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GCUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 49 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43820 43821 43823 43824 43826 43828 43829 43830 43831 43832 43835 43836 43838 43839 43843 43844 43860 43954 43960 44201 44201 45109 45109 45201 45201 45202 45202 45203 45203 45204 45204 45207 45207 101

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 126 126 047 087 101 126 101 126 101 126 101 126 101 126 101 126 CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED INSTRUMENTAL INSTRUMENTAL CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC Multi Detector GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID ULTRA VIOLET ULTRA VIOLET ABSORPTION MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GCUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 50 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

45208 45208 45209 45210 45211 45212 45218 45219 45220 45220 45225 45228 45501 45503 45504 45801 45805 45806 45807 45810 61103 61104 62101 62201 63301 63302 68103 68104 68105 68105 68105 68106 68107 101

126 126 126 126 126 126 126 101 126 126 126 202 202 202 101 101 101 101 101 020 020 021 012 011 011 810 810 143 780 810 810 810 CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE Canister Subambient Pressure INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL Met One SASS Met One SASS R & P Model 2000 PM-2.5 FEM Air Sampler INSTRUMENTAL Met One SASS Met One SASS Met One SASS CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC VECTOR SUMMATION VECTOR SUMMATION SPOT READING LEVEL 1 HYGROSCOPIC PLASTIC FILM PYRANOMETER UV RADIOMETER (PHOTOMETER) Electronic Electronic Electronic ELECTRONIC Electronic Barometric SensorUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 51 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

68108 68108 68108 81102 81102 81102 82102 82103 82105 82110 82112 82113 82128 82132 82136 82142 82154 85101 85102 85103 85105 85110 85112 85113 85129 85132 85136 85142 85154 86101 88101 88101 88102 143

780 810 079 122 126 202 202 202 202 202 202 202 202 202 202 202 126 202 202 202 202 202 202 202 202 202 202 202 185 143 170 811 R & P Model 2000 PM-2.5 FEM Air Sampler

INSTRUMENTAL Met One SASS INSTRUMENTAL-R&P SA246B-INLET INSTRUMENT MET ONE 4 MODELS R - P Co Partisol Model 2000 R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R - P Co Partisol Model 2000 R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon Met One BAM-1020 System R & P Model 2000 PM-2.5 Air Sampler w/VSCC Met One BAM-1020 Mass Monitor w/VSCC Met One SASS Teflon Barometric Sensor Barometric Sensor BAROMETRIC SENSOR Barometric Sensor TEOM-GRAVIMETRIC BETA ATTENUATION Gravimetric ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS Gravimetric ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS Paired Gravimetric Difference Gravimetric Beta AttenuationUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 52 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

88103 88104 88107 88109 88110 88111 88112 88113 88114 88115 88117 88118 88126 88128 88131 88132 88136 88140 88152 88154 88160 88161 88164 88165 88166 88167 88168 88169 88176 88180 88184 88185 88301 811

811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 812 Met OneSASS Teflon

Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Nylon Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy Dispersive XRF Energy dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRFUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 53 of 54 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

88302 88303 88306 88355 88357 88370 88374 88375 88376 88377 88378 88380 88383 88384 88385 88388 88403 88500 88501 88502 812

812 812 839 840 838 841 841 841 841 842 831 841 841 841 826 812 761 731 810 Met One SASS Nylon

Met One SASS Nylon Met One SASS Nylon URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl Met One SASS Nylon PM2.5 VSCC Met-One BAM-1020 W/PM2.5 SCC Met One SASS Teflon Ion Chromatography Ion Chromatography Ion Chromatography Ion Chromatography OC1+OC2+OC3+OC4+(OP(TOT))=(88374+88375+88376+88377+88388) EC1+EC2+EC3-(OP(TOT))=(88383+88384+88385-88388)) OC1+OC2+OC3+OC4+(OP(TOR))=(88374+88375+88376+88377+88378) IMPROVE_A IMPROVE_A IMPROVE_A IMPROVE_A IMPROVE_A TOR EC1+EC2+EC3-(OP(TOR))=(88383+88384+88385-88378)) IMPROVE_A IMPROVE_A IMPROVE_A IMPROVE_A TOT Ion Chromatography FDMS-Gravimetric Beta Attenuation GravimetricUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 16, 2013

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 54 of 54 PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION 0053 Arizona Department Of Environmental QualityUNITED STATES ENVIRONMENTAL PROTECTION AGENCY

DATA EVALUATION AND CONCURRENCE REPORT May. 9, 2013 Report Request ID: 1096804 Report Code: AMP600

Selection Criteria Page 1 User ID: JOJ

State County City

Site Parameter POC AQCR UAR CBSA CSA EPA Region Method Duration Begin Date End Date 04 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration CRITERIA 42602 AGENCY SELECTIONS Arizona Department Of Environmental Quality

SELECTED OPTIONS

MERGE PDF FILES Option Type Option Value YES GLOBAL DATES

2011 Start Date End Date 2011 Tribal CodeMay. 9, 2013 

# Data Evaluation and Concurrence Report Summary

Page 1 of 1 2011 

## Certification Year: Certifying Agency (CA): Arizona Department Of Environmental Quality (0053) 

## Pollutants in Report:

PQAO Parameter Code Nitrogen dioxide (NO2) 42602 

## Parameter Name Monitors Evaluated Code 1

0053 Arizona Department Of Environmental Quality 

## PQAO Code

AQS Site-ID POC AQS Recommended Flag Cert. Agency

Recommended Flag Reason for AQS Recommendation 0053 42602 1 04-013-9997 N Y Quality Assurance Project Plan not approved in 10 years. 

## Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name Summary of 'N' flags for all pollutants: 0 1 

## PQAOs in Report: 04/09/12 

## TSA Date Monitors Recommended for Concurrence by AQS Monitors NOT Recommended for Concurrence by AQS

# Data Evaluation and Concurrence Report for Gaseous Pollutants 2011 Certifying Year Certifying Agency Code Arizona Department Of Environmental Quality (0053) Nitrogen dioxide (NO2) (42602) (ppb) Arizona Department Of Environmental Quality (0053) PQAO Name 08/06/1994 QAPP Approval Date

1 04-013-9997 SLAMS 16.8 Mean 1.0

Min 59.0 Max Exceed. Count 0

Outlier Count 99 Perc. Comp. 2.96

Precision +/-2.51

Bias 81 Complete 100 Complete Bias Y

PQAO Level Criteria N Aqs Rec Flag Y

CA Rec Flag Epa Concur ADEQ is working to produce QAPPs according to the Submitter Comment 

## Parameter

0 Y Number of Valid Audits NPAP Bias Criteria Met 

### NPAP Audit Summary:

- 2.84 Routine Data One Point Quality Check Annual PE NPAP Concur. Flag AQS Site ID POC Monitor

Type Bias QAPP Appr. N

# Data Evaluation and Concurrence Report for Particulate Matter

# Data Concurrence and Evaluation Report for Lead