# EZE 431

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# •WRrI0N



# P.O.
Box 1346 Prttsburgh,

PA 15230-1346 Phone--(41 2)494-8000 CHEMTREC

1 -800-424-9300 MATERIAL
SAFETY

DATA SHEET Section

1. PRODUCT IDENTIFICATION PRODUCT

NAME:

EZE 431 CHEMICAL DESCRIPTION:

Aliphatic hydrocarbon PRODUCT

CLASS:
Industrial
cleaner MSDS CODE:

E312 Section

2. INFORMATION

ON INGREDIENTS

CAS

%by Chemical

Name

Number

Weight

OSHA

PEL

ACGIH

TLV Isoparaffinic hydrocarbon

64742-48-9

100
None establishesd

TWA

300 ppm (supplier recommendation) Section

3. HAZARDS IDENTIFICATION*********************



# EMERGENCY OVERVIEW Clear liquid

with

a mild solvent

odor. WARNING! May cause

eye, skin
and respiratory

tract irritation. Aspiration

may cause

lung damage. Combustible

liquid

and vapor.*********************



# UC 191997“‘0 

# r*********************************************************** 

# PRIMARY ROUTES

OF ENTRY:

Eye and skin contact, inhalation TARGET ORGANS:

Eye, skin, mucous membranes,

central nervous system,

lung MEDICAL CONDITIONS AGGRAVATED

BY EXPOSURE:

Skin contact

may aggravate

an existing dermatitus condition. POTENTIAL

HEALTH EFFECTS: EYE CONTACT:

This product

may cause some minor irritation

upon contact

with

the eye. MSDS Code:
E312 Issue Date:

08/1 2/97

Page

1 Continued

on Page

2EZE 431SKINCONTACT:Prolongedorrepeatedcontactwiththeskinmaydryanddefattheskin,leadingtoirritationanddermatitis.Thisproductisnotexpectedtobeabsorbedthroughtheskininharmfulamountsortoproduceanallergicskinreaction.INGESTION:Minimallytoxic.However,smallamountsofthisproductaspiratedintotherespiratorysystemduringingestionorvomitingmaycausemildtoseverepulmonaryinjury,possiblyprogressingtodeath.INHALATION:Highvapor/aerosolconcentrations(greaterthanapproximately1000ppm)areirritatingtotheeyesandtherepiratorytractandmaycauseheadaches,dizziness,anesthesia,drowsiness,andothercentralnervoussystemeffects.SUBCHRONIC,CHRONIC:Theproductwasadministeredbyinhalationtoratsfor6hours/day,5days/weekfor12weeksatconcentrationsof0,300,or900ppm.Notreatment-relatedmortalityoccurred.Therewerenosignificantalterationsinhematologyorclinicalchemistryparameters.Bodyweightsweredecreasedinmaletreatmentgroups.Relativemeankidneyweightsweresignificantlyelevatedinmalesat300and900ppm,andrelativemeanliverweightswereelevatedinmalesat900ppm.Histologicalfindingswerelimitedtothekidneysofmaleratsandwereindicativeoflighthydrocarbonnephropathy.Thesekidneyeffectsarearesultoftheaccumulationofalpha-2u-globulin,aproteinspecifictothemalerat,intheproximalrenaltubule.Thesekidneyeffectsarespecifictomaleratsandarenotconsideredtobeofbiologicalrelevancetohumans.CARCINOGENICITY:NTP:*Noingredientslistedinthissection*IARC:*Noingredientslistedinthissection*OSHA:*Noingredientslistedinthissection* Section

4. FIRST

AID MEASURESEYECONTACT:Incaseofcontact,immediatelyflusheyeswithplentyofwater.Seekmedicalaidifirritationpersists.SKINCONTACT:Incaseofcontact,flushskinwithplentyofwater.Removecontaminatedclothing.Seekmedicalaidifirritationpersists.Washclothingbeforereuse.INGESTION:Ifswallowed,doNOTinducevomiting.Seekmedicalaidimmediately.Nevergiveanythingbymouthtoanunconsciousperson.INHALATION:Ifinhaled,removetofreshair.Ifnotbreathing,giveartificialrespiration.Ifbreathingisdifficult,giveoxygen.Seekmedicalaid. Section

5. FIRE-FIGHTING
MEASURESFLASHPOINT:104°FThisproductisacombustibleliquid.MSDSCode:E312Page2IssueDate:08/12/97ContinuedonPage3EZE 431

I LOWER FLAMMABLE

LIMIT:

1 .2%

UPPER FLAMMABLE

LIMIT:

9.6% AUTO-IGNITION TEMPERATURE:

559°F EXTINGUISHING

MEDIA:

Use foam, carbon dioxide

or dry chemical. FIRE-FIGHTING INSTRUCTIONS:

Exercise caution

when fighting

any chemical

fire.

A self-contained breathing apparatus

and protective
clothing

are essential. Use water

to keep fire-exposed containers

cool. FIRE

& EXPLOSION HAZARDS:

Vapors

are heavier

than

air and may travel along

the ground

or
be moved

by ventilation

and ignited

by pilot lights,
other flames, sparks, heaters, smoking,
electric motors

or other ignition sources

at locations
distant

from material handling

point. Never

use cutting

or welding

torch

on or near drum (even empty); product

(or even residue)

can ignite explosively.

All five gallon

pails

and larger metal containers

should

be grounded. DECOMPOSITION

PRODUCTS:

Thermal decomposition

or combustion

may produce
carbon dioxide,
carbon monoxide,

and various hydrocarbons. NFPA RATINGS:

Health

1 Flammability=

2 Reactivity=

0 Special Hazard= None Hazard
rating scale: 0=Miriimal

1 =Slight 2=Moderate 3=Serious 4=Severe Section

6. ACCIDENTAL

RELEASE MEASURES STEPS

TO

BE TAKEN

IF MATERIAL

IS RELEASED

OR SPILLED: Remove

all sources

of ignition. Wearing appropriate
personal protective equipment,

contain

spill, collect

onto non-combustible

absorbent

like sand

or earth

and place

into suitable container.

Do not use sawdust,

wood chips

or other cellulosic materials

to absorb

the spill. Keep spills

and cleaning
runoff

out

of municipal

sewers

and open bodies

of water. Section

7. HANDLING

AND STORAGE HANDLING:

Avoid contact

with eyes. Avoid prolonged

or repeated contact

with skin. Avoid breathing

vapor

or mist. Keep away from heat

and flame. Use with adequate ventilation. Wash thoroughly

after handling.

Keep container

closed when

not

in use. STORAGE:

Store

in

a cool, well-ventilated

area away from incompatible
materials. Keep away from heat

and flame. Protect material

from direct sunlight. Section

8. EXPOSURE CONTROLS

I PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT: EYE/FACE PROTECTION:

Chemical

splash goggles

and face shield MSDS
Code:

E31

2

Page

3 Issue Date: 08/12/97

Continued

on Page

4[SKINPROTECTION:ChemicalresistantglovesRESPIRATORYPROTECTION:Ifairborneconcentrationsbecomeirritating,useaNIOSHapprovedrespiratorinaccordancewithOSHArespiratoryprotectionrequirements(29CFR1910.134).ENGINEERINGCONTROLS:Theuseofmechanicaldilutionventilationisrecommendedwheneverthisproduct-isusedinaconfinedspace,isheatedaboveambienttemperaturesorisagitated.Becauseuseconditionswillvarydependinguponcustomerapplications,specificsafehandlingproceduresshouldbedevelopedbyapersonknowledgeableoftheintendeduseconditionsandequipment. Section

9. PHYSICAL

AND CHEMICAL PROPERTIESBOILINGPOINT:320-351°FSOLUBILITYINWATER:NegligibleVAPORPRESSURE:2mmHg

@68°FSPECIFICGRAVITY:0.75

@60°FVAPORDENSITY(air=l):4.94pH:Notapplicable%VOLATILEBYWEIGHT:100FREEZINGPOINT:<-76°FAPPEARANCEANDODOR:Clearliquidwithamildsolventodor.VISCOSITY:1.3cSt

@77°F Section

10. STABILITY

AND REACTIVITYCHEMICALSTABILITY:StableHAZARDOUSPOLYMERIZATION:WillnotoccurCONDITIONSTOAVOID:Keepawayfromheatandflame.Avoidhightemperatures.INCOMPATIBILITY:StrongoxidizingagentsDECOMPOSITIONPRODUCTS:Thermaldecompositionorcombustionmayproducecarbondioxide,carbonmonoxide,andvarioushydrocarbons. Section

11. TOXICOLOGICAL INFORMATIONONPRODUCT:ProductOralLD50(rat):>10g!KgProductDermalLD50(rabbit):>3.16g/KgMSDSCode:E312Page4IssueDate:08/12/97ContinuedonPage5—

II_LI...1,I

I•Section12.ECOLOGICALINFORMATIONONPRODUCT:Aquatictoxicitydata:96hrLC50(fatheadminnow):5,000mg/ISection13.DiSPOSALCONSIDERATIONSRCRASTATUS:Discardedproduct,assold,wouldbeconsideredaRCRAHazardousWastebasedonthecharacteristicofignitability.TheEPAHazardousWasteNumberisDOOl.DISPOSAL:Disposeofinaccordancewithlocal,stateandfederalregulations.Section14.TRANSPORTINFORMATIONDOTCLASSIFICATION:Class/Division:3(Note,however,that49CFR173.120(b)(2)oftheDOTregulationsallowsaflammableliquidwithaflashpointatorabove38°C(100°F)tobereclassedasa“combustibleliquid”fordomestictransportationpurposes,ifit(1)doesnotmeetthedefinitionofanyotherhazardclassand(2)isnotbeingtransportedbyvesseloraircraft,unlessothermeansoftransportationisimpracticable.)ProperShippingName:Petroleumdistillates,n.o.s.Label:FlammableliquidPackingGroup:IllIDNumber:UN1268Section15.REGULATORYINFORMATIONOSHAHazardCommunicationStatus:HazardousTSCA:TheingredientsofthisproductarelistedontheToxicSubstancesControlAct(TSCA)ChemicalSubstancesInventory.CERCLAreportablequantityofEPAhazardoussubstancesinproduct:ChemicalNameNoingredientsofthisproducthaveCERCLAreportablequantities.ProductRQ:Notapplicable(NotifyEPAofproductspillsexceedingthisamount.)SARATITLEIll:Section302ExtremelyHazardousSubstances:ChemicalNameCAS#RQTPQTherearenoSARA302ExtremelyHazardousSubstancesinthisproduct.MSDSCode:E312Page5IssueDate:08/12/97ContinuedonPage6—

EZE431 Section

311
and 312 Health

and Physical Hazards: Immediate

Delayed

Fire

Pressure

Reactivity [yes]

[no]

[yes]

[no]

(no] Section

313 Toxic Chemicals: Chemical

Name

CAS

#

% by Weight There

are

no reportable

SARA

313 Toxic Chemicals

in this product. Section

16. OTHER INFORMATION HMIS RATINGS:

Health=

1

Flammability=

2

Reactivity=

0 Personal Protective Equipment=

X (to

be specified

by user depending

on use conditions) Hazard
rating scale: O=Minimal

1 =Slight 2=Moderate 3=Serious 4=Severe MSDS REVISION SUMMARY:

Reason

for reissue: Update

to new format. WhiLe

this information

and reco4mnendations

set forth herein

are beUeved

to

be accurate

as

of the date hereof,
CALGON CORPORATION

MAKES

NO WARRANTY

WITH RESPECT HERETO

AND DISCLAIMS

ALL LIABILITY

FROM RELIANCE THEREON. PREPARED

BY:

J.J. Kowalski MSDS
Code:
E312

Page

6 Issue Date: 08/12/97

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