Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 1 of 8

01. GENERAL INFORMATION

Cray Valley USA, LLC

Oaklands Corporate Center

468 Thomas Jones Way 

Exton, Pennsylvania 19341 

Emergency phone number:

800/424-9300 (CHEMTREC)

Product information:

610/363-4100

 

GENERIC NAME

Zinc Cinnamate

DOT PROPER SHIPPING NAME UN/NA NUMBER 

N/AP N/AP

DOT HAZARD CLASS

Not regulated 

02. SUMMARY OF HAZARDS

WARNING

PHYSICAL HAZARDS: May form combustible dust-air mixtures

ACUTE HEALTH EFFECTS: Suspect eye irritation hazard

 (SHORT-TERM) Suspect skin irritation hazard

 Suspect respiratory tract irritation 

 hazard

 Suspect skin absorption hazard

 Suspect slight ingestion hazard

CHRONIC HEALTH EFFECTS: No chronic health effects data are known to 

 (LONG-TERM) exist for this product or either of its 

 components.

 

03. COMPONENTS

COMPONENT NAME CAS NUMBER % COMPOSITION (BY WT.)

Zinc Cinnamate 18957-59-0 GT 95

TSCA status: Not listed on the US EPA TSCA inventory. Section 5(h)(3) 

limitations apply. For research and development use only. See MSDS 

attachment for details.

Zinc oxide LT 5
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 2 of 8

trans-Cinnamic acid 140-10-3 LT 5

04. PHYSICAL AND CHEMICAL DATA

BOILING POINT pH

N/DA N/DA

FREEZING POINT DRY POINT

N/DA N/DA

SPECIFIC GRAVITY (H20=1 at 39.2F) VOLATILE CHARACTERISTICS

N/DA Negligible

VISCOSITY UNITS, TEMP. (Brookfield) SOLUBILITY IN WATER

N/AP Insoluble

VAPOR PRESSURE STABILITY

N/DA Stable

VAPOR SP GR (AIR=1 at 60 - 90F) HAZARDOUS POLYMERIZATION

N/DA Not expected to occur

APPEARANCE AND ODOR

Off-white powder

CONDITIONS AND MATERIALS TO AVOID

Elevated temperatures, excessive heat, open flames, dusting conditions, 

prolonged storage; 

Strong oxidizing agents, acids, bases, aluminum, magnesium, moisture

HAZARDOUS DECOMPOSITION PRODUCTS

Acrid smoke-fumes/carbon monoxide/carbon dioxide/sulfur oxides/sodium 

oxides and perhaps other toxic vapors may be released during a fire involving 

this product.

05. OCCUPATIONAL EXPOSURE LIMITS

SUBSTANCE SOURCE DATE TYPE VALUE TIME

 No PELs or TLVs have been established for the main component of this 

product.

Zinc oxide ACGIH 2011 TWA 2 MG/M3(repirable) 8 HOURS

STEL 10 MG/M3(repirable)8 HOURS

06. FIRE AND EXPLOSION

FLASH POINT: METHOD (Estimated) AUTOIGNITION TEMP.: METHOD

N/DA N/DA
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 3 of 8

FLAMMABLE LIMITS (% VOLUME IN AIR)

LOWER: N/DA UPPER: N/DA

FIRE AND EXPLOSION HAZARDS

When mixed with air and exposed to ignition source, sufficient flammable 

dust may exist to burn in open or explode if confined. Use good housekeeping practices to avoid rendering dust airborne. Flammable vapors may 

also be present from over heating/melting/decomposition. Vapors may cause 

fire/explosion if source of ignition is presnt. 

EXTINGUISHING MEDIA

Dry chemical

CO2

Water spray

Foam

SPECIAL FIREFIGHTING PROCEDURES

Do not enter fire area without proper protection. See section on 

decomposition products possible. Fight fire from safe distance/protected 

location. Apply aqueous extinguishing media carefully to prevent 

frothing/steam explosion. Use water spray/fog for cooling. Avoid contact 

with molten product to prevent serious burns. Avoid raising powdered 

materials into airborne dust, creating an explosion hazard. Notify 

authorities if liquid enters sewer/public waters.

07. HEALTH HAZARDS

ROUTES OF EXPOSURE

INHALATION 

Airborne dust or vapors/aerosols generated during processing may cause 

respiratory tract irritation. Excessive exposure may cause cough, mucous 

production and shortness of breath. 

EYE CONTACT -- PRIMARY ROUTE

Although no appropriate human or animal health effects data are known to 

exist, this material is expected to cause eye irritation. Dust from this 

product may cause eye irritation. Symptoms of irritation may include 

redness, tearing or excessive blinking.

SKIN ABSORPTION

Although no appropriate human or animal health effects data are known to 

exist, this material is expected to be a health hazard by skin absorption.

SKIN IRRITATION -- PRIMARY ROUTE

Although no appropriate human or animal health effects data are known to 

exist, this material is expected to be a skin irritant. Symptoms of 

irritation may include localized redness or rash and swelling.
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 4 of 8

INGESTION

Although no appropriate human or animal health effects data are known to 

exist, this material is expected to be a slight ingestion hazard.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

No additional medical information found.

08. PROTECTIVE EQUIPMENT / CONTROL MEASURES

RESPIRATORY PROTECTION

No occupational exposure standards have been developed for this material. 

Where exposure through inhalation may occur from use, NIOSH/MSHA approved 

respiratory protection equipment is recommended.

EYE PROTECTION

Eye protection such as chemical splash goggles and/or face shield must be 

worn when possibility exists for eye contact due to splashing or spraying 

liquid, airborne particles, or vapor. Contact lenses should not be worn.

SKIN PROTECTION

When skin contact is possible, protective clothing including gloves, apron, 

sleeves, boots, head and face protection should be worn. This equipment 

must be cleaned thoroughly after each use. Use nitrile or natural rubber 

gloves/skin protection.

ENGINEERING CONTROLS

Provide local exhaust or general room ventilation to minimize exposure to 

dust. If mechanical ventilation is used, electrical systems should conform 

to National Electric Code (NFPA 70); electrical equipment must be suitable 

for the classification of the area where it is installed. Guidance on area 

classification can be found in NFPA 499.

OTHER HYGIENIC PRACTICES

Emergency eye wash fountains and safety showers should be available in the 

immediate vicinity of any potential exposure.

OTHER WORK PRACTICES

Use good personal hygiene practices. Wash hands before eating, drinking, 

smoking, or using toilet facilities. Promptly remove soiled clothing/wash 

thoroughly before reuse. Shower after work using plenty of soap and water.

09. EMERGENCY AND FIRST AID

INHALATION

If overcome by exposure, remove victim to fresh air immediately. Give 

oxygen or artificial respiration as needed. Obtain emergency medical 

attention. Prompt action is essential.

EYE CONTACT

In case of eye contact, immediately rinse with clean water for 20-30 

minutes. Retract eyelids often. Obtain emergency medical attention.

SKIN CONTACT
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 5 of 8

Immediately remove contaminated clothing. Wash skin thoroughly with mild 

soap/water. Flush w/lukewarm water for 15 minutes. If sticky, a waterless 

cleaner may be used. Seek medical attention if ill effect or irritation 

develops.

INGESTION

Ingestion unlikely. However, if ingested, obtain emergency medical 

attention.

EMERGENCY MEDICAL TREATMENT PROCEDURES

Treat symptomatically.

10. SPILL AND DISPOSAL

PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED

Spilled or released material poses a dust explosion hazard if it becomes 

airborne in the presence of an ignition source. Extinguish all ignition 

sources. Avoid generating dust. Use protective equipment during cleanup. 

On land, vacuum, using equipment which avoids ignition risk, or sweep (with 

a broom that has non-synthetic bristles). Place into suitable disposal 

containers. On water, contain/minimize dispersion/collect. May 

contaminate water supplies. Report per regulatory requirements.

Discharge into the environment must be avoided; may be harmful to aquatic 

life.

WASTE DISPOSAL METHODS

Non-contaminated product is not a RCRA hazardous waste. However, 

contaminated product/soil/water may be a RCRA/OSHA hazardous waste due to 

the potential for internal heat generation (see 40CFR 261 and 29 CFR 1910). 

It is the responsibility of the generator to determine at the time of disposal 

whether the product meets the criteria of a hazardous waste. Use registered 

transporters. Waste management options include metals recovery or 

landfilling solids at permitted sites. Assure emissions comply with 

applicable regulations. Dilute aqueous waste may biodegrade; avoid 

overloading/poisoning plant biomass. Assure effluent complies with 

applicable regulations. 

11. ADDITIONAL PRECAUTIONS

HANDLING AND STORAGE PROCEDURES

Store product in a cool, dry place away from strong oxidizing and reducing 

agents. Preferably, store in an air-conditioned area where the ambient 

temperature does not exceed about 80F. Keep containers tightly closed until 

ready to use to avoid loss of activity. For optimum results, use within 

6 months of receipt. This product is not expected to present an explosion 

hazard during normal trnasportation and storage operations. However, when 

dispersed in air and subject to sufficient energy of ignition, it is a 

potential dust explosion hazard. Minimize the potential for dust explosion 

by eliminating/controlling ignition sources (bond and ground) and using good 
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 6 of 8

housekeeping practices during storage, transfer, handling and use to avoid 

excessive dust accumulation. Electrical equipment must be grounded and 

conform to the national electric code. In instances where this material 

is bulk conveyed, or where processing may result in a dusty atmosphere, refer 

to the latest edition of the National Fire Protection Association (NFPA) 

654 publication, "Standard for the Prevention of Fire & Dust Explosions in 

the Chemical,Dye, Pharmaceutical, and Plastics Industries" for complete 

discussion of dust explosion prevention and control measures. 

DECONTAMINATION PROCEDURES

Follow standard plant procedures or supervisor's instructions for 

decontamination operations.

12. LABEL INFORMATION

USE STATEMENT

NOT ON US EPA INVENTORY - FOR RESEARCH AND DEVELOPMENT USE ONLY

SIGNAL WORD

WARNING!

PHYSICAL HAZARDS

MAY FORM COMBUSTIBLE DUST-AIR MIXTURES

HEALTH HAZARDS

MAY CAUSE EYE,SKIN AND RESPIRATORY IRRITATION

PRECAUTIONARY MEASURES

DO NOT HANDLE NEAR HEAT, SPARKS OR OPEN FLAME.

AVOID EXCESSIVE HEAT/HIGH TEMPERATURES.

AVOID ACCUMULATION OF DUST IN ENCLOSED SPACE.

PREVENT MOISTURE CONTACT.

KEEP CONTAINER CLOSED WHEN NOT IN USE.

USE ONLY WITH ADEQUATE VENTILATION/PERSONAL PROTECTION.

AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.

AVOID BREATHING VAPORS/DUSTS.

WASH THOROUGHLY AFTER HANDLING.

BEFORE USING PRODUCT, READ MATERIAL SAFETY DATA SHEET.

13. SUPPLEMENT

NPCA - HMIS RATING

Health 2

Flammability 3(DUST)

Reactivity 0

Personal protection** j

REGULATORY INFORMATION

TSCA STATUS:
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 7 of 8

TSCA status: Not listed on the US EPA TSCA inventory. Section 5(h)(3) 

limitations apply. For research and development use only. See MSDS 

attachment for details.

CALIFORNIA PROPOSITION 65:

California Proposition 65 Information: this product does not contain any 

substances known to the state of California to cause cancer and/or 

reproductive harm.

*Note - qualifiers and codes used in this MSDS

EQ = Equal; AP = Approximately; LT = Less Than; GT = Greater Than;

TR = Trace; UK = Unknown; N/AP = Not Applicable; N/P = No Applicable 

Information Found; N/DA = No Data Available

14. DISCLAIMERS

Sartomer USA, LLC believes that the information and recommendations 

contained herein (including data and statements) are accurate as of the date 

hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OR 

MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE 

CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided 

herein relates only to the specific product designated and may not be valid 

where such product is used in combination with any other materials or in 

any process. Further, since the conditions and methods of use are beyond 

the control of Sartomer USA, LLC, Sartomer USA, LLC expressly disclaims any 

and all liability as to any results obtained or arising from any use of the 

product or reliance on such information.MSDS Attachment

Dear Customer:

This product which we are supplying to you is not listed on the United States 

Environmental Protection Agency’s Toxic Substances Control Act (TSCA) 

inventory and must be used for research and development evaluation only --

it may not be used, processed or distributed for a commercial purpose in 

the United States. 

Under TSCA’s research and development exemption, 40 CFR 720.36 (1), you must 

ensure that you:

1. Use this product solely for research and development activities;

2. Have a technically qualified individual directly supervise all stages 

of your research and development activities;
Cray Valley USA, LLC

Material Safety Data Sheet

Product: CVX50005 Revised Date: 12-05-2011

MSDS ID: S-002956

Date Printed: 12-05-2011 Page: 8 of 8

3. Evaluate and inform all persons engaged in your research and development 

activities of any potential health risks associated with this product, as 

well as companies or persons to whom this product is distributed; 

4. Notify companies or persons to whom this product is distributed that this 

product may be used for research and development only.

Please refer to 40 CFR 720.36 and 720.78 for complete information on the 

TSCA R&D exemption. Additionally, please review the material safety data 

sheet (MSDS), which includes an evaluation of the potential health risks 

associated with this product.