Secretariat of Transport and Communications

THIS DOCUMENT SHOULD NOT BE USED TO

DETERMINE COMPLIANCE WITH THE

DANGEROUS GOODS REGULATIONS

OR

TO CREATE WORKER SAFETY DOCUMENTS

FOR SPECIFIC CHEMICALS

U.S. Department of Transportation

Pipeline and Hazardous Materials Safety Administration

NOT FOR SALE

This document is distributed free of charge to Public Safety Organization

and may not be resold.
QUANTITY

1 TANK TRUCK UN1219 ISOPROPANOL 3 II 12,000 LITERS

ID NUMBER

EMERGENCY CONTACT

1-000-000-0000

EXAMPLE OF EMERGENCY 

CONTACT TELEPHONE NUMBER

NO. & TYPE

OF PACKAGES

SHIPPING NAME

HAZARD CLASS

OR DIVISION NO.

PACKING GROUP

SHIPPING DOCUMENTS (PAPERS)*

The shipping document provides vital information when responding to a

hazardous materials/dangerous goods** incident. The shipping document

contains information needed to identify the materials involved. Use this

information to initiate protective actions for your own safety and the safety of the

public. The shipping document contains the 4-digit ID number (see yellowbordered pages) preceded by the letters UN or NA, the proper shipping name

(see blue-bordered pages), the hazard class or division of the material(s), and,

where appropriate, the Packing Group. The shipping document will also display

a 24-hour emergency response telephone number. In addition, there must be

information available that describes the hazards of the material which can be

used in the mitigation of an incident. The information must be entered on or be

with the shipping document. This requirement may be satisfied by attaching a

guide from the ERG2008 to the shipping document, or by having the entire

guidebook available for ready reference. Shipping documents are required for

most dangerous goods in transportation. Shipping documents are kept in

• the cab of the motor vehicle,

• the possession of the train crew member,

• a holder on the bridge of a vessel, or

• an aircraft pilot’s possession.

The 4-digit ID Number may be shown on the diamond-shaped placard or on

an adjacent orange panel displayed on the ends and sides of a cargo tank,

vehicle or rail car.

* For the purposes of this guidebook, the terms shipping document/shipping paper are synonymous.

** For the purposes of this guidebook, the terms hazardous materials/dangerous goods are synonymous.

EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER

A Numbered or

Placard

A Placard 

and an 

Orange Panel

1219

1219 FLAMMABLE
DANGEROUS GOODS

STEP ONE: IDENTIFY THE MATERIAL. USE ANY OF THE FOLLOW

• IDENTIFICATION NUMBER (4-DIGIT ID) FROM A PLACARD, OR

PAPER OR PACKAGE (after UN/NA)

• NAME OF THE MATERIAL FROM A SHIPPING DOCUMENT OR PAC

STEP TWO: IDENTIFY 3-DIGIT GUIDE NUMBER USE:

• ID NUMBER INDEX in yellow-bordered pages or

• NAME OF MATERIAL INDEX in blue-bordered pages

Guide number supplemented with the letter “P” indicates that the m

polymerization if subjected to heat or contamination.

INDEX ENTRIES HIGHLIGHTED IN GREEN are TIH (Toxic Inhalation 

warfare agent or a Dangerous Water Reactive Material (produces toxic 

IDENTIFY ID NUMBER AND NAME OF MATERIAL IN TABLE 1 

PROTECTIVE ACTION DISTANCES (the green-bordered pages

PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions pag

required, use the information jointly with the 3-digit guide.

STEP THREE: TURN TO THE NUMBERED GUIDE (the orange-bordered 

USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT F

(EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CO

NOTE: IF ABOVE STEPS CANNOT BE COMPLETED AND PLACARD 

16-17; use 3-digit guide next to placard; PROCEED TO NUMBERED GUID

If shipping document is available, call emergency response telephone n

emergency response telephone is not available, IMMEDIATELY CALL 

response agency listed in the back of this guidebook. Provide as m

such as the name of the carrier (trucking company or railroad) and vehicule 

TOA GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED T

GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL 

AVAILABLE.

AS A LAST RESORT: IF ONLY THE CONTAINER CAN BE IDENTIFIED

RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages18-1

INFORMATION ASSOCIATED WITH THESE CONTAINERS IS FOR W

WhitePages 1_14 Eng.pmd 2/14/01
Page 2

transportation incident involving dangerous goods. It is primarily a g

responders in quickly identifying the specific or generic hazards o

involved in the incident, and protecting themselves and the gene

the initial response phase of the incident. For the purposes of this guid

response phase” is that period following arrival at the scene of an inciden

presence and/or identification of dangerous goods is confirmed, protective 

securement are initiated, and assistance of qualified personnel is requested

to provide information on the physical or chemical properties of dangero

This guidebook will assist responders in making initial decisions upon arr

of a dangerous goods incident. It should not be considered as a substitu

response training, knowledge or sound judgment. ERG2008 does not ad

circumstances that may be associated with a dangerous goods incide

designed for use at a dangerous goods incident occurring on a highwa

mindful that there may be limited value in its application at fixed facility l

ERG2008 incorporates dangerous goods lists from the most recen

Recommendations as well as from other international and national regula

are not listed individually by either proper shipping name or ID Number. T

appear under the general heading “Explosives” on the first page of the 

(yellow-bordered pages) and alphabetically in the Name of Material ind

pages). Also, the letter “P” following the guide number in the yellow-b

bordered pages identifies those materials which present a polymerizat

certain conditions, for example: Acrolein, stabilized 131P.

First responders at the scene of a dangerous goods incident should seek 

information about any material in question as soon as possible. The inf

by contacting the appropriate emergency response agency, by callin

response telephone number on the shipping document, or by consulting 

or accompanying the shipping document, may be more specific and a

guidebook in providing guidance for the materials involved.

BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEB

according to the requirements of the U.S. Department of Labor’s Occupa

Health Administration (OSHA, 29 CFR 1910.120), and regulations is

Environmental Protection Agency (EPA, 40 CFR Part 311), first responde

regarding the use of this guidebook.

WhitePages 1_14 Eng.pmd 2/14/02
1090 127 Acetone

2-Blue-bordered pages: Index list of dangerous goods in alph

name. This section quickly identifies the guide to be consulted from 

involved. This list displays the name of the material followed by 

response guide and 4-digit ID number.

For example: Name of Material GUIDE No. I

Sulfuric acid 137 

3-Orange-bordered pages: This section is the most important 

because it is where all safety recommendations are provided. 

individual guides, presented in a two-page format. Each 

recommendations and emergency response information to protec

The left hand page provides safety related information whereas the 

emergency response guidance and activities for fire situations, s

first aid. Each guide is designed to cover a group of materials which 

and toxicological characteristics.

The guide title identifies the general hazards of the dangerous go

For example: GUIDE 124 - Gases-Toxic and/or Corrosive-O

Each guide is divided into three main sections: the first section des

that the material may display in terms of fire/explosion and healt

The highest potential is listed first. The emergency responder s

first. This allows the responder to make decisions regarding the pr

response team as well as the surrounding population.

The second section outlines suggested public safetymeasures bas

It provides general information regarding immediate isolation of the in

type of protective clothing and respiratory protection. Suggested evac

for small and large spills and for fire situations (fragmentation hazard

to consult the tables listing Toxic Inhalation Hazard (TIH) materials, ch

water-reactive materials (green-bordered pages) when the material i

bordered and blue-bordered pages.

The third section covers emergency response actions, including f

precautions for incidents which involve fire, spill or chemi

WhitePages 1_14 Eng.pmd 2/14/03
Page 4

(yellow-bordered pages) and alphabetic (blue-bordered pages) lists of the 

table provides distances for both small (approximately 200 liters or le

300 kilograms or less for solids when spilled in water) and large spills (m

for liquids and more than 300 kilograms for solids when spilled in water) 

materials. The list is further subdivided into daytime and nighttime s

necessary due to varying atmospheric conditions which greatly affec

hazardous area. The distances change from daytime to nighttime due 

and dispersion conditions in the air. During the night, the air is general

causes the material to disperse less and therefore create a toxic zone wh

would usually occur during the day. During the day, a more active atmos

greater dispersion of the material resulting in a lower concentration of t

surrounding air. The actual area where toxic levels are reached will b

increased dispersion). In fact, it is the quantity or concentration of the m

poses problems not its mere presence. Table 2 lists, by ID number orde

produce large amounts of Toxic Inhalation Hazard (TIH) gases when sp

identifies the TIH gases produced. These Water Reactive materials are 

Table 1 as their name is immediately followed by (when spilled in water)

this material is NOT spilled in water, Table 1 and Table 2 do not apply an

will be found within the appropriate orange guide.

The “Initial Isolation Distance” is a distance within which all persons sho

for evacuation in all directions from the actual spill/leak source. It is a 

which defines a circle (Initial Isolation Zone) within which persons ma

dangerous concentrations upwind of the source and may be exposed 

concentrations downwind of the source. For example, in the case of 

toxic, n.o.s., ID No. 1955, Inhalation Hazard Zone A, the isolation distanc

100 meters, therefore, representing an evacuation circle of 200 meters i

For the same material, the “Protective Action Distance” for a small spill is 

a daytime incident and 2.1 kilometers for a nighttime incident, these dist

downwind distance from the spill/leak source within which Protective 

implemented. Protective Actions are those steps taken to preserve the he

emergency responders and the public. People in this area could be 

sheltered in-place. For more information, consult pages 293 to 299.

What is a TIH? It is a gas or volatile liquid which is known to be so toxic to 

a hazard to health during transportation, or in the absence of adequat

WhitePages 1_14 Eng.pmd 2/14/04
glossary.

ISOLATION AND EVACUATION DISTANCE

Isolation or evacuation distances are shown in the guides (orange-b

Table 1 - Initial Isolation and Protective Action Distances (green-bo

confuse users not thoroughly familiar with ERG2008.

It is important to note that some guides refer only to non-TIH materials 

both TIH and non-TIH materials (21 guides) and some (5 guid

Water-reactive materials (WRM). A guide refers to both TIH and non-

see GUIDE 131) when the following sentence appears under the title 

Table 1 - Initial Isolation and Protective Action Distances fo

For non-highlighted materials, increase, in the downwind direction, 

distance shown under ‘PUBLIC SAFETY.’” A guide refers only to T

example see GUIDE 124) when the following sentence appears und

Spill: “See Table 1 - Initial Isolation and Protective Action Distances”

do not appear in a guide, then this particular guide refers only to non-

see GUIDE 128).

In order to identify appropriate isolation and protective action distanc

If you are dealing with a TIH/WRM/Chemical warfare material (high

lists), the isolation and evacuation distances are found directly in t

The guides (orange-bordered pages) also remind the user to refer to 

for evacuation specific information involving highlighted materials.

If you are dealing with a non-TIH material but the guide refers 

materials, an immediate isolation distance is provided under the hea

precautionary measure to prevent injuries. It applies to the non-TIH 

for evacuation purposes, the guide informs the user under the title EVA

for non-highlighted materials, in the downwind direction, if necessa

distance listed under “PUBLIC SAFETY”. For example, GUIDE 131 – 

instructs the user to: "As an immediate precautionary measure, isol

least 50 meters (150 feet) in all directions." In case of a large spill, 

expanded from 50 meters to a distance deemed as safe by the O

emergency responders.

If you are dealing with a non-TIH material and the guide refers only 

immediate isolation and evacuation distances are specified as act

(orange-bordered pages) and are not referenced in the green-borde

WhitePages 1_14 Eng.pmd 2/14/05
Page 6

outside the safety perimeter. Allow enough room to move and remove you

IDENTIFY THE HAZARDS. Placards, container labels, shipping documen

data sheets, Rail Car and Road Trailer Identification Charts, and/or knowl

on the scene are valuable information sources. Evaluate all available inform

the recommended guide to reduce immediate risks. Additional informa

the shipper or obtained from another authoritative source, may cha

emphasis or details found in the guide. Remember, the guide provi

important and worst case scenario information for the initial response in r

or class of dangerous goods. As more material-specific information beco

response should be tailored to the situation.

ASSESS THE SITUATION. Consider the following:

- Is there a fire, a spill or a leak?

- What are the weather conditions?

- What is the terrain like?

- Who/what is at risk: people, property or the environm

- What actions should be taken: Is an evacuation nece

Is diking necessary? What resources (human and e

required and are readily available?

- What can be done immediately?

OBTAIN HELP. Advise your headquarters to notify responsible agen

assistance from qualified personnel.

DECIDE ON SITE ENTRY. Any efforts made to rescue persons, prote

environment must be weighed against the possibility that you could be

problem. Enter the area only when wearing appropriate protective gear (s

CLOTHING, page 348).

RESPOND. Respond in an appropriate manner. Establish a command 

communication. Rescue casualties where possible and evacuate if nec

control of the site. Continually reassess the situation and modify the resp

The first duty is to consider the safety of people in the immediate area, in

ABOVE ALL. Do not walk into or touch spilled material. Avoid inhalation 

and vapors, even if no dangerous goods are known to be involved. Do 

gases or vapors are harmless because of lack of a smell—odorless gas

be harmful. Use CAUTION when handling empty containers because the

hazards until they are cleaned and purged of all residues.

WhitePages 1_14 Eng.pmd 2/14/06
information beyond what is available in this guidebook should oc

1. ORGANIZATION/AGENCY

Notify your organization/agency. This will set in motion a series 

information provided. Actions may range from dispatching add

the scene to activating the local emergency response plan. Ens

departments have been notified.

2. EMERGENCY RESPONSE TELEPHONE NUMBER

Locate and call the telephone number listed on the shipping 

answering the phone at the listed emergency response number 

the materials and mitigation actions to be taken, or must hav

person who has the required knowledge.

3. NATIONAL ASSISTANCE

Contact the appropriate emergency response agency listed on t

guidebook when the emergency response telephone number 

shipping papers. Upon receipt of a call describing the nature 

will provide immediate advice on handling the early stages of th

also contact the shipper or manufacturer of the material for mo

request on-scene assistance when necessary.

Collect and provide as much of the following information as can safely 

of-command and specialists contacted for technical guidance:

Your name, call back telephone number, FAX number

Location and nature of problem (spill, fire, etc.)

Name and identification number of material(s) involved

Shipper/consignee/point of origin

Carrier name, rail car or truck number

Container type and size

Quantity of material transported/released

Local conditions (weather, terrain, proximity to schools, hospita

Injuries and exposures

Local emergency services that have been notified

WhitePages 1_14 Eng.pmd 2/14/07
Page 8

In an emergency, CANUTEC may be called collect at

613-996-6666 (24 hours)

*666 cellular (Press Star 666, Canada only)

In a non-emergency situation, please call the information line at 613-992-4

2. PROVINCIAL AGENCIES

Although technical information and emergency response assistance ca

CANUTEC, there are federal and provincial regulations requiring the rep

goods incidents to certain authorities.

The following list of provincial agencies is supplied for your convenience.

Province Emergency Authority and/or

Telephone Number

Alberta .........................................Local Police and Provincial Author

1-800-272-9600* or 780-422-9600

British Columbia ..........................Local Police and Provincial Author

1-800-663-3456

Manitoba ......................................Provincial Authority 204-945-4888 

Local Police or fire brigade, as app

New Brunswick ............................Local Police or 1-800-565-1633**

or 902-426-6030

Newfoundland and Labrador.......Local Police and 709-772-2083

Northwest Territories ...................867-920-8130

Nova Scotia .................................Local Police or 1-800-565-1633** 

902-426-6030

Nunavut Territory .........................Local Police and 1-800-693-1666 

867-979-6262

Ontario .........................................Local Police

Prince Edward Island .................. Local Police or 1-800-565-1633** 

902-426-6030

Quebec ........................................Local Police

Saskatchewan .............................Local Police or 1-800-667-7525

Yukon Territory ............................867-667-7244

* This number is not accessible from outside Alberta.

** This number is not accessible from outside of New Brunswick, Nova Scotia or P

WhitePages 1_14 Eng.pmd 2/14/08
b. an incident involving infectious substances;

c. an accidental release from a cylinder that has suffered a cat

d. an incident where the shipping documents display CANUTE

613-996-6666 as the emergency telephone number; or

e. a dangerous goods incident in which a railway vehicle, a shi

aerodrome or an air cargo facility is involved.

WhitePages 1_14 Eng.pmd 2/14/09
Page 10

703-527-3887 (Collect calls are accepted)

2. CHEMTEL, INC., a 24-hour emergency response communication service, 

follows:

CALL CHEMTEL, INC. (24 hours)

1-888-255-3924

(Toll-free in the U.S., Canada, Puerto Rico and the U.S. Virgin 

For calls originating elsewhere:

813-248-0585 (Collect calls are accepted)

3. INFOTRAC, a 24-hour emergency response communication service, can be 

CALL INFOTRAC (24 hours)

1-800-535-5053

(Toll-free in the U.S., Canada, and the U.S. Virgin Island

For calls originating elsewhere:

352-323-3500 (Collect calls are accepted)

4. 3E COMPANY, a 24-hour emergency response communication service, 

follows:

CALL 3E COMPANY (24 hours)

1-800-451-8346

(Toll-free in the U.S., Canada, and the U.S. Virgin Island

For calls originating elsewhere:

760-602-8703 (Collect calls are accepted)

The emergency response information services shown above have requested to b

of emergency response information and have agreed to provide emergency resp

all callers. They maintain periodically updated lists of state and Federal radia

provide information and technical assistance on handling incidents involving rad

WhitePages 1_14 Eng.pmd 2/14/010
6. NATIONWIDE POISON CONTROL CENTER (United States Only

Emergency and information calls are answered by the nearest Po

1-800-222-1222 (toll-free in the U.S.).

The above numbers are for emergencies only.

NATIONAL RESPONSE CENTER (NRC)

The NRC, which is operated by the U.S. Coast Guard, receives report

goods and hazardous substances are spilled. After receiving notification 

immediately notify the appropriate Federal On-Scene Coordinator and c

Federal law requires that anyone who releases into the environment 

hazardous substance (including oil when water is, or may be affected) 

marine pollutant, must immediately notify the NRC. When in doubt as to w

equals the required reporting levels for these materials, the NRC should 

CALL NRC (24 hours)

1-800-424-8802

(Toll-free in the U.S., Canada, and the U.S. Virgin 

202-267-2675 in the District of Columbia

Calling the emergency response telephone number, CHEMTREC®, C

or 3E COMPANY, does not constitute compliance with regulatory re

WhitePages 1_14 Eng.pmd 2/14/011
Page 12

5559-1588

For calls originating elsewhere, call

+52-55-5559-1588

2. CENACOM, the National Center for Communications of the Civil Protect

reached as follows:

CALL CENACOM (24 hours)

01-800-00-413-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan A

5128-0000 exts. 11470, 11471, 11472, 11473, 11474, 11475, 1147

For calls originating elsewhere, call

+52-55-5128-0000 exts. 11470, 11471, 11472, 11474, 11475 a

ARGENTINA

1. CIQUIME (Chemistry Information Center for Emergencies) a 24-hour em

information service, can be reached as follows:

CALL CIQUIME (24 hours)

0-800-222-2933 in the Republic of Argentina

For calls originating elsewhere, call

+54-11-4613-1100

BRAZIL

1. PRÓ-QUÍMICA a 24-hour emergency response information service, can be 

CALL PRÓ-QUÍMICA (24 hours)

0-800-118270 in the Federal Republic of Brazil

For calls originating elsewhere, call

+55-11-232-1144

WhitePages 1_14 Eng.pmd 2/14/012
For calls originating elsewhere, call

+57-1-288-6012

WhitePages 1_14 Eng.pmd 2/14/013
Page 14

parentheses (when applicable), must appear on the shipping document after ea

name.

Class 1 - Explosives

Division 1.1 Explosives with a mass explosion hazard

Division 1.2 Explosives with a projection hazard

Division 1.3 Explosives with predominantly a fire hazard

Division 1.4 Explosives with no significant blast hazard

Division 1.5 Very insensitive explosives with a mass explos

Division 1.6 Extremely insensitive articles

Class 2 - Gases

Division 2.1 Flammable gases

Division 2.2 Non-flammable, non-toxic* gases

Division 2.3 Toxic* gases

Class 3 - Flammable liquids (and Combustible liquids [U.S.])

Class 4 - Flammable solids; Spontaneously combustible materials; and Da

materials/Water-reactive substances

Division 4.1 Flammable solids

Division 4.2 Spontaneously combustible materials

Division 4.3 Water-reactive substances/Dangerous when w

Class 5 - Oxidizing substances and Organic peroxides

Division 5.1 Oxidizing substances

Division 5.2 Organic peroxides

Class 6 - Toxic* substances and Infectious substances

Division 6.1 Toxic*substances

Division 6.2 Infectious substances

Class 7 - Radioactive materials

Class 8 - Corrosive substances

Class 9 - Miscellaneous hazardous materials/Products, Substances or Or

* The words “poison” or “poisonous” are synonymous with the word “toxic”.

WhitePages 1_14 Eng.pmd 2/14/014
dangerous goods. As you approach a reported or suspe

incident involving a placarded vehicle:

1. Approach the incident cautiously from upwind to a 

can safely identify and/or read the placard or orange 

wind direction allows, consider approaching the inci

binoculars, if available.

2. Match the vehicle placard(s) with one of the placa

next two pages.

3. Consult the numbered guide associated with the 

that information for now. For example, a FLAMMA

leads to GUIDE 127. A CORROSIVE (Class 8) placard 

multiple placards point to more than one guide, initially us

guide (i.e., the guide requiring the greatest degree of p

4. Remember that the guides associated with the plac

significant risk and/or hazard information.

5. When specific information, such as ID number or shi

available, the more specific guide recommended f

be consulted.

6. If GUIDE 111 is being used because only the DA

placard is displayed or the nature of the spilled, leakin

is not known, as soon as possible, get more 

concerning the material(s) involved.

7. Asterisks (*) on orange placards represent explo

Group” letters; refer to the Glossary (page 357).

8. Double asterisks (**) on orange placards represe

explosive.

WhitePages 15_26 Eng.pmd 3/25/015
Page 16

WhitePages 15_26 Eng.pmd 3/25/016
WhitePages 15_26 Eng.pmd 3/25/017
Page 18

CAUTION: Emergency response personnel must be aware that rail tan

in construction, fittings and purpose. Tank cars could transport products t

liquids or gases. The products may be under pressure. It is essential 

identified by consulting shipping documents or train consist or contacting 

before emergency response is initiated.

The information stenciled on the sides or ends of tank cars, as illustrate

used to identify the product utilizing:

a. the commodity name shown; or

b. the other information shown, especially reporting marks and car nu

when supplied to a dispatch center, will facilitate the identification o

* The recommended guides should be considered as last resort 

cannot be identified by any other means.

WhitePages 15_26 Eng.pmd 3/25/018
CAUTION: This chart depicts only the most general shapes of 

response personnel must be aware that there are many variat

illustrated above, that are used for shipping chemical products. T

for the most hazardous products that may be transported in thes

* The recommended guides should be considered as last 

cannot be identified by any other means.

WhitePages 15_26 Eng.pmd 3/25/019
Page 20

The hazard identification code in the top half of the orange panel consis

digits. In general, the digits indicate the following hazards:

2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL RE

3 - FLAMMABILITY OF LIQUIDS (VAPORS) AND GASES OR 

LIQUID

4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID

5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT

6 - TOXICITY OR RISK OF INFECTION

7 - RADIOACTIVITY

8 - CORROSIVITY

9 - MISCELLANEOUS DANGEROUS SUBSTANCE

• Doubling of a digit indicates an intensification of that particular haza

• Where the hazard associated with a material can be adequat

single digit, the digit is followed by a zero (i.e. 30, 40, 50).

• A hazard identification code prefixed by the letter “X” indicates 

will react dangerously with water (i.e. X88).

• When 9 appears as a 2nd or 3rd digit, this may present a ris

violent reaction.

WhitePages 15_26 Eng.pmd 3/25/020
3 egeaed queed gas, aabe

225 Refrigerated liquefied gas, oxidizing (fire-intensifying)

23 Flammable gas

236 Flammable gas, toxic

239 Flammable gas which can spontaneously lead to viole

25 Oxidizing (fire-intensifying) gas

26 Toxic gas

263 Toxic gas, flammable

265 Toxic gas, oxidizing (fire-intensifying)

266 Highly toxic gas

268 Toxic gas, corrosive

30 Flammable liquid

323 Flammable liquid which reacts with water, emitting flam

X323 Flammable liquid which reacts dangerously with water

33 Highly flammable liquid

333 Pyrophoric liquid

X333 Pyrophoric liquid which reacts dangerously with water

336 Highly flammable liquid, toxic

338 Highly flammable liquid, corrosive

X338 Highly flammable liquid, corrosive, which reacts dange

339 Highly flammable liquid which can spontaneously lead 

36 Flammable liquid, toxic, or self-heating liquid, toxic

362 Flammable liquid, toxic, which reacts with water, emitti

X362 Flammable liquid, toxic, which reacts dangerously with wa

368 Flammable liquid, toxic, corrosive

38 Flammable liquid, corrosive or self-heating liquid, corro

382 Flammable liquid, corrosive, which reacts with water, e

X382 Flammable liquid, corrosive, which reacts dangerously with w

39 Flammable liquid which can spontaneously lead to viol

40 Flammable solid, or self-reactive material, or self-heati

423 Solid which reacts with water, emitting flammable gas

WhitePages 15_26 Eng.pmd 3/25/021
Page 22

46 Flammable solid, toxic, or self-heating solid, toxic

462 Toxic solid which reacts with water, emitting flammable gas

X462 Solid which reacts dangerously with water, emitting toxic gas

48 Flammable or self-heating solid, corrosive

482 Corrosive solid which reacts with water, emitting flammable ga

X482 Solid which reacts dangerously with water, emitting corrosive 

50 Oxidizing (fire-intensifying) substance

539 Flammable organic peroxide

55 Strongly oxidizing (fire-intensifying) substance

556 Strongly oxidizing (fire-intensifying) substance, toxic

558 Strongly oxidizing (fire-intensifying) substance, corrosive

559 Strongly oxidizing (fire-intensifying) substance which can spon

violent reaction

56 Oxidizing (fire-intensifying) substance, toxic

568 Oxidizing (fire-intensifying) substance, toxic, corrosive

58 Oxidizing (fire-intensifying) substance, corrosive

59 Oxidizing (fire intensifying) substance which can spontaneously lea

60 Toxic material

606 Infectious substance

623 Toxic liquid which reacts with water, emitting flammable gas

63 Toxic liquid, flammable

638 Toxic liquid, flammable, corrosive

639 Toxic liquid, flammable, which can spontaneously lead to viole

64 Toxic solid, flammable or self-heating

642 Toxic solid which reacts with water, emitting flammable gas

65 Toxic material, oxidizing (fire-intensifying)

66 Highly toxic material

663 Highly toxic liquid, flammable

664 Highly toxic solid, flammable or self-heating

665 Highly toxic material, oxidizing (fire-intensifying)

668 Highly toxic material, corrosive

WhitePages 15_26 Eng.pmd 3/25/022
72 Radioactive gas

723 Radioactive gas, flammable

73 Radioactive liquid, flammable

74 Radioactive solid, flammable

75 Radioactive material, oxidizing (fire-intensifying)

76 Radioactive material, toxic

78 Radioactive material, corrosive

80 Corrosive material

X80 Corrosive material which reacts dangerously with wate

823 Corrosive liquid which reacts with water, emitting flamm

83 Corrosive liquid, flammable

X83 Corrosive liquid, flammable, which reacts dangerously 

839 Corrosive liquid, flammable, which can spontaneously 

X839 Corrosive liquid, flammable, which can spontaneously 

and which reacts dangerously with water

84 Corrosive solid, flammable or self-heating

842 Corrosive solid which reacts with water, emitting flamm

85 Corrosive material, oxidizing (fire-intensifying)

856 Corrosive material, oxidizing (fire-intensifying) and toxi

86 Corrosive material, toxic

88 Highly corrosive material

X88 Highly corrosive material which reacts dangerously wit

883 Highly corrosive liquid, flammable

884 Highly corrosive solid, flammable or self-heating

885 Highly corrosive material, oxidizing (fire-intensifying)

886 Highly corrosive material, toxic

X886 Highly corrosive material, toxic, which reacts dangerou

89 Corrosive material which can spontaneously lead to vio

90 Miscellaneous dangerous substance; environmentally 

99 Miscellaneous dangerous substance transported at ele

WhitePages 15_26 Eng.pmd 3/25/023
Page 24

Liquid Pipelines

Surface indications of a liquid pipeline leak can include:

• Liquids bubbling from the ground

• “Oil slick” on flowing or standing water

• Flames that appear to be coming from the ground

• Vapor clouds

Structures – Storage Tanks, Valves, Pump Stations, Aerial Patrol Marke

Signs – Will often appear at road, railroad, and water crossings. Signs m

at property boundaries. The signs will include the operator’s name, pro

and an emergency phone number for the operator. Warning, Caution, or D

on the signs.

WhitePages 15_26 Eng.pmd 3/25/024
In winter, melted snow over the pipeline

Gas Transmission pipelines are large-diameter, steel lines trans

or corrosive gas at very high pressure.

Structures – Compressor Station Buildings, Valves, Metering Stations

Signs – Will often appear at road, railroad, and water crossings. 

at property boundaries. The signs will include the operator’s na

and an emergency phone number for the operator. Warning, Caut

on the signs.

Natural gas Distribution pipelines are typically smaller-diameter

pipelines and may be steel, plastic, or cast iron. Natural gas is d

customers through distribution pipelines.

Regulator stations, customer meters & regulators, and valve box 

only aboveground indications of gas distribution pipelines.

Should you notice a leak or a spill, remember to only approach 

identify the emergency telephone number for the company and 

well as 911. Be cautious concerning the risks of asphyxiation, fl

danger of a potential explosion.

If you know the material involved, identify the three-digit guide n

name in the alphabetical list (blue-bordered pages) and then by u

number, consult the recommendations outlined in the recommen

WhitePages 15_26 Eng.pmd 3/25/025
Page 26

Note: If an entry is highlighted in green in either the yellow-bordered 

pages AND THERE IS NO FIRE, go directly to Table 1 - Initial Isola

Action Distances (green bordered pages) and look up the ID nu

material to obtain initial isolation and protective action distance

FIRE, or IF A FIRE IS INVOLVED, ALSO CONSULT the assign

bordered pages) and apply as appropriate the evacuation inform

PUBLIC SAFETY. Please remember that, if the name in Tabl

(when spilled in water), and the material has not been spilled 

does not apply and safety distances can be found within the ap

WhitePages 15_26 Eng.pmd 3/25/026
—— 114 Explosive C

—— 112 Explosives, division 1.1, 1.2,

1.3, 1.5 or 1.6

—— 114 Explosives, division 1.4

—— 153 Toxins

1001 116 Acetylene

1001 116 Acetylene, dissolved

1002 122 Air, compressed

1003 122 Air, refrigerated liquid

(cryogenic liquid)

1003 122 Air, refrigerated liquid

(cryogenic liquid), nonpressurized

1005 125 Ammonia, anhydrous

1005 125 Anhydrous ammonia

1006 121 Argon

1006 121 Argon, compressed

1008 125 Boron trifluoride

1008 125 Boron trifluoride, compressed

1009 126 Bromotrifluoromethane

1009 126 Refrigerant gas R-13B1

1010 116P Butadienes, stabilized

1010 116P Butadienes and hydrocarbon

mixture, stabilized

1011 115 Butane

1011 115 Butane mixture

1012 115 Butylene

1013 120 Carbon dioxide

1014 122 Oxygen 

mixtu

1015 126 Carbon 

oxide 

1015 126 Nitrous 

dioxi

1016 119 Carbon 

1016 119 Carbon 

1017 124 Chlorin

1018 126 Chlorod

1018 126 Refrige

1020 126 Chlorop

1020 126 Refrige

1021 126 1-Chlor

tetra

1021 126 Chlorot

1021 126 Refrige

1022 126 Chlorot

1022 126 Refrige

1023 119 Coal ga

1023 119 Coal ga

1026 119 Cyanog

1026 119 Cyanog

1027 115 Cyclop

1028 126 Dichlor

1028 126 Refrige

1029 126 Dichlor

1029 126 Refrige

Numeric 27-96 Eng.pmd 3/25/027
Page 28

1051 117 AC

1051 117 Hydrocyan

solutions

Hydroge

1051 117 Hydrogen c

stabilize

1051 117 Hydrogen c

1052 125 Hydrogen f

1053 117 Hydrogen s

1053 117 Hydrogen s

1055 115 Isobutylene

1056 121 Krypton

1056 121 Krypton, co

1057 115 Lighter refi

(flammab

1057 115 Lighters (ci

(flammab

1058 120 Liquefied g

charged 

Carbon d

1060 116P Methylacet

Propadie

stabilize

1060 116P Propadiene 

Methylac

stabilize

1061 118 Methylamin

1062 123 Methyl brom

1063 115 Methyl chlo

1035 115 Ethane, compressed

1036 118 Ethylamine

1037 115 Ethyl chloride

1038 115 Ethylene, refrigerated liquid

(cryogenic liquid)

1039 115 Ethyl methyl ether

1039 115 Methyl ethyl ether

1040 119P Ethylene oxide

1040 119P Ethylene oxide with Nitrogen

1041 115 Carbon dioxide and Ethylene

oxide mixture, with more than

9% but not more than 87%

Ethylene oxide

1041 115 Carbon dioxide and Ethylene

oxide mixtures, with more

than 6% Ethylene oxide

1041 115 Ethylene oxide and Carbon

dioxide mixture, with more

than 9% but not more than

87% Ethylene oxide

1041 115 Ethylene oxide and Carbon

dioxide mixtures, with more

than 6 % Ethylene oxide

1043 125 Fertilizer, ammoniating solution,

with free Ammonia

1044 126 Fire extinguishers with

compressed gas

1044 126 Fire extinguishers with

liquefied gas

1045 124 Fluorine

1045 124 Fluorine, compressed

Numeric 27-96 Eng.pmd 3/25/028
1067 124 Dinitrogen tetroxide

1067 124 Nitrogen dioxide

1069 125 Nitrosyl chloride

1070 122 Nitrous oxide

1070 122 Nitrous oxide, compressed

1071 119 Oil gas

1071 119 Oil gas, compressed

1072 122 Oxygen

1072 122 Oxygen, compressed

1073 122 Oxygen, refrigerated liquid

(cryogenic liquid)

1075 115 Butane

1075 115 Butane mixture

1075 115 Butylene

1075 115 Isobutane

1075 115 Isobutane mixture

1075 115 Isobutylene

1075 115 Liquefied petroleum gas

1075 115 LPG

1075 115 Petroleum gases, liquefied

1075 115 Propane

1075 115 Propane mixture

1075 115 Propylene

1076 125 CG

1076 125 Diphosgene

1076 125 DP

1076 125 Phosgene

1080 126 Sulphu

1081 116P Tetraflu

1082 119P Trifluor

stabi

1083 118 Trimeth

1085 116P Vinyl br

1086 116P Vinyl ch

1087 116P Vinyl m

1088 127 Acetal

1089 129 Acetald

1090 127 Aceton

1091 127 Aceton

1092 131P Acrolei

1093 131P Acrylon

1098 131 Allyl alc

1099 131 Allyl bro

1100 131 Allyl ch

1104 129 Amyl ac

1105 129 Amyl al

1105 129 Pentan

1106 132 Amylam

1107 129 Amyl ch

1108 128 n-Amyl

1108 128 1-Pente

1109 129 Amyl fo

1110 127 n-Amyl 

1110 127 Amyl m

Numeric 27-96 Eng.pmd 3/25/029
Page 30

1123 129 Butyl acetates

1125 132 n-Butylamine

1126 130 1-Bromobutane

1126 130 n-Butyl bromide

1127 130 Butyl chloride

1127 130 Chlorobutanes

1128 129 n-Butyl formate

1129 129 Butyraldehyde

1130 128 Camphor oil

1131 131 Carbon bisulfide

1131 131 Carbon bisulphide

1131 131 Carbon disulfide

1131 131 Carbon disulphide

1133 128 Adhesives (flammable)

1134 130 Chlorobenzene

1135 131 Ethylene chlorohydrin

1136 128 Coal tar distillates, flammable

1139 127 Coating solution

1143 131P Crotonaldehyde

1143 131P Crotonaldehyde, stabilized

1144 128 Crotonylene

1145 128 Cyclohexane

1146 128 Cyclopentane

1147 130 Decahydronaphthalene

1148 129 Diacetone alcohol

1149 128 Butyl ethers

1149 128 Dibutyl ethers

1155 127 Ethyl ether

1156 127 Diethyl keto

1157 128 Diisobutyl k

1158 132 Diisopropy

1159 127 Diisopropy

1160 132 Dimethylam

solution

1160 132 Dimethylam

1161 129 Dimethyl ca

1162 155 Dimethyldic

1163 131 1,1-Dimeth

1163 131 Dimethylhy

unsymme

1164 130 Dimethyl su

1164 130 Dimethyl su

1165 127 Dioxane

1166 127 Dioxolane

1167 128P Divinyl ethe

1169 127 Extracts, a

1170 127 Ethanol

1170 127 Ethanol, so

1170 127 Ethyl alcoh

1170 127 Ethyl alcoh

1171 127 Ethylene gl

1172 129 Ethylene gl

acetate

1173 129 Ethyl aceta

1175 130 Ethylbenze

Numeric 27-96 Eng.pmd 3/25/030
1181 155 Ethyl chloroacetate

1182 155 Ethyl chloroformate

1183 139 Ethyldichlorosilane

1184 131 Ethylene dichloride

1185 131P Ethyleneimine, stabilized

1188 127 Ethylene glycol monomethyl

ether

1189 129 Ethylene glycol monomethyl

ether acetate

1190 129 Ethyl formate

1191 129 Ethylhexaldehydes

1191 129 Octyl aldehydes

1192 129 Ethyl lactate

1193 127 Ethyl methyl ketone

1193 127 Methyl ethyl ketone

1194 131 Ethyl nitrite, solution

1195 129 Ethyl propionate

1196 155 Ethyltrichlorosilane

1197 127 Extracts, flavoring, liquid

1197 127 Extracts, flavouring, liquid

1198 132 Formaldehyde, solution,

flammable

1198 132 Formaldehyde, solutions

(Formalin)

1199 132P Furaldehydes

1199 132P Furfural

1199 132P Furfuraldehydes

1201 127 Fusel oil

1203 128 Gasolin

1203 128 Motor s

1203 128 Petrol

1204 127 Nitrogly

alcoh

1% N

1206 128 Heptan

1207 130 Hexald

1208 128 Hexane

1208 128 Neohex

1210 129 Ink, pri

1210 129 Printing 

1210 129 Printing 

1212 129 Isobuta

1212 129 Isobuty

1213 129 Isobuty

1214 132 Isobuty

1216 128 Isoocte

1218 130P Isopren

1219 129 Isoprop

1219 129 Isoprop

1220 129 Isoprop

1221 132 Isoprop

1222 130 Isoprop

1223 128 Kerose

1224 127 Ketone

Numeric 27-96 Eng.pmd 3/25/031
Page 32

poisonous, n.o.s.

1228 131 Mercaptans, liquid, flammable,

toxic, n.o.s.

1229 129 Mesityl oxide

1230 131 Methanol

1230 131 Methyl alcohol

1231 129 Methyl acetate

1233 130 Methylamyl acetate

1234 127 Methylal

1235 132 Methylamine, aqueous solution

1237 129 Methyl butyrate

1238 155 Methyl chloroformate

1239 131 Methyl chloromethyl ether

1242 139 Methyldichlorosilane

1243 129 Methyl formate

1244 131 Methylhydrazine

1245 127 Methyl isobutyl ketone

1246 127P Methyl isopropenyl ketone,

stabilized

1247 129P Methyl methacrylate monomer,

stabilized

1248 129 Methyl propionate

1249 127 Methyl propyl ketone

1250 155 Methyltrichlorosilane

1251 131P Methyl vinyl ketone, stabilized

1259 131 Nickel carbonyl

1261 129 Nitromethane

1265 128 Isopentane

1265 128 n-Pentane

1265 128 Pentanes

1266 127 Perfumery 

flammab

1267 128 Petroleum 

1268 128 Petroleum 

1268 128 Petroleum 

1270 128 Oil, petrole

1270 128 Petroleum 

1272 129 Pine oil

1274 129 n-Propanol

1274 129 normal Pro

1274 129 Propyl alco

1275 129 Propionald

1276 129 n-Propyl ac

1277 132 Monopropy

1277 132 Propylamin

1278 129 1-Chloropr

1278 129 Propyl chlo

1279 130 1,2-Dichlor

1279 130 Dichloropro

1279 130 Propylene d

1280 127P Propylene o

1281 129 Propyl form

1282 129 Pyridine

1286 127 Rosin oil

Numeric 27-96 Eng.pmd 3/25/032
1293 127 Tinctures, medicinal

1294 130 Toluene

1295 139 Trichlorosilane

1296 132 Triethylamine

1297 132 Trimethylamine, aqueous

solution

1298 155 Trimethylchlorosilane

1299 128 Turpentine

1300 128 Turpentine substitute

1301 129P Vinyl acetate, stabilized

1302 127P Vinyl ethyl ether, stabilized

1303 130P Vinylidene chloride, stabilized

1304 127P Vinyl isobutyl ether, stabilized

1305 155P Vinyltrichlorosilane

1305 155P Vinyltrichlorosilane, stabilized

1306 129 Wood preservatives, liquid

1307 130 Xylenes

1308 170 Zirconium metal, liquid

suspension

1308 170 Zirconium suspended in a

flammable liquid

1308 170 Zirconium suspended in a liquid

(flammable)

1309 170 Aluminum powder, coated

1310 113 Ammonium picrate, wetted with

not less than 10% water

1312 133 Borneol

1313 133 Calcium resinate

1322 113 Dinitror

not le

1323 170 Ferroce

1324 133 Films, n

1325 133 Flamma

1325 133 Flamma

1325 133 Fusee (

1325 133 Medicin

n.o.s

1326 170 Hafnium 

less 

1327 133 Bhusa, 

conta

1327 133 Hay, we

with 

1327 133 Straw, w

conta

1328 133 Hexam

1328 133 Hexam

1330 133 Mangan

1331 133 Matche

1332 133 Metalde

1333 170 Cerium

1334 133 Naphth

1334 133 Naphth

1336 113 Nitrogu

with 

1336 113 Nitrogu

less 

Numeric 27-96 Eng.pmd 3/25/033
Page 34

1338 133 Phosphorus, amorphous, red

1338 133 Red phosphorus

1338 133 Red phosphorus, amorphous

1339 139 Phosphorus heptasulfide, free

from yellow and white

Phosphorus

1339 139 Phosphorus heptasulphide, free

from yellow and white

Phosphorus

1340 139 Phosphorus pentasulfide, free

from yellow and white

Phosphorus

1340 139 Phosphorus pentasulphide, free

from yellow and white

Phosphorus

1341 139 Phosphorus sesquisulfide, free

from yellow and white

Phosphorus

1341 139 Phosphorus sesquisulphide,

free from yellow and white

Phosphorus

1343 139 Phosphorus trisulfide, free from

yellow and white Phosphorus

1343 139 Phosphorus trisulphide, free

from yellow and white

Phosphorus

1344 113 Picric acid, wet, with not less

than 10% water

1344 113 Picric acid, wetted with not less

than 30% water

1344 113 Trinitrophenol, wetted with not

less than 30% water

1348 113 Sodium din

wetted w

water

1348 113 Sodium din

wetted

1349 113 Sodium pic

not less t

1350 133 Sulfur

1350 133 Sulphur

1352 170 Titanium po

not less t

1353 133 Fabrics imp

nitrated N

1353 133 Fibers impr

nitrated N

1353 133 Fibres impr

nitrated N

1353 133 Toe puffs, n

1354 113 Trinitroben

less than 

1355 113 Trinitroben

not less t

1356 113 TNT, wette

30% wat

1356 113 Trinitrotolu

less than 

1357 113 Urea nitrate

than 20% 

1358 170 Zirconium m

Numeric 27-96 Eng.pmd 3/25/034
1362 133 Carbon, activated

1363 135 Copra

1364 133 Cotton waste, oily

1365 133 Cotton

1365 133 Cotton, wet

1366 135 Diethylzinc

1369 135 p-Nitrosodimethylaniline

1370 135 Dimethylzinc

1372 133 Fiber, animal or vegetable,

n.o.s., burnt, wet or damp

1372 133 Fibers, animal or vegetable,

burnt, wet or damp

1372 133 Fibres, animal or vegetable,

burnt, wet or damp

1373 133 Fabrics, animal or vegetable or

synthetic, n.o.s. with oil

1373 133 Fibers, animal or vegetable or

synthetic, n.o.s. with oil

1373 133 Fibres, animal or vegetable or

synthetic, n.o.s. with oil

1374 133 Fish meal, unstabilized

1374 133 Fish scrap, unstabilized

1376 135 Iron oxide, spent

1376 135 Iron sponge, spent

1378 170 Metal catalyst, wetted

1379 133 Paper, unsaturated oil treated

1380 135 Pentaborane

1381 136 Phosphorus, white, dry or under

water or in solution

1381 136 Yellow 

1381 136 Yellow 

1382 135 Potass

1382 135 Potass

30% 

1382 135 Potass

30% 

1382 135 Potass

1382 135 Potass

than 

cryst

1382 135 Potass

than 

1383 135 Alumin

1383 135 Pyroph

1383 135 Pyroph

1384 135 Sodium 

1384 135 Sodium 

1384 135 Sodium 

1385 135 Sodium 

1385 135 Sodium 

30% 

1385 135 Sodium 

1385 135 Sodium 

30% 

1386 135 Seed ca

oil an

mois

1387 133 Wool w

Numeric 27-96 Eng.pmd 3/25/035
Page 36

1392 138 Alkaline earth metal amalgam

1392 138 Alkaline earth metal amalgam,

liquid

1393 138 Alkaline earth metal alloy, n.o.s.

1394 138 Aluminum carbide

1395 139 Aluminum ferrosilicon powder

1396 138 Aluminum powder, uncoated

1397 139 Aluminum phosphide

1398 138 Aluminum silicon powder,

uncoated

1400 138 Barium

1401 138 Calcium

1402 138 Calcium carbide

1403 138 Calcium cyanamide, with more

than 0.1% Calcium carbide

1404 138 Calcium hydride

1405 138 Calcium silicide

1406 138 Calcium silicon

1407 138 Caesium

1407 138 Cesium

1408 139 Ferrosilicon

1409 1388 Hydrides, metal, n.o.s.

1409 138 Metal hydrides, water-reactive,

n.o.s.

1410 138 Lithium aluminum hydride

1411 138 Lithium aluminum hydride,

ethereal

1418 138 Magnesium 

1419 139 Magnesium 

1420 138 Potassium, 

1420 138 Potassium, 

1421 138 Alkali meta

1422 138 Potassium 

1422 138 Potassium 

1422 138 Sodium pot

1422 138 Sodium pot

1423 138 Rubidium

1423 138 Rubidium m

1426 138 Sodium bor

1427 138 Sodium hyd

1428 138 Sodium

1431 138 Sodium me

1431 138 Sodium me

1432 139 Sodium pho

1433 139 Stannic pho

1435 138 Zinc ashes

1435 138 Zinc dross

1435 138 Zinc residu

1435 138 Zinc skimm

1436 138 Zinc dust

1436 138 Zinc powde

1437 138 Zirconium h

1438 140 Aluminum n

1439 141 Ammonium 

Numeric 27-96 Eng.pmd 3/25/036
1447 141 Barium perchlorate

1447 141 Barium perchlorate, solid

1448 141 Barium permanganate

1449 141 Barium peroxide

1450 141 Bromates, inorganic, n.o.s.

1451 140 Caesium nitrate

1451 140 Cesium nitrate

1452 140 Calcium chlorate

1453 140 Calcium chlorite

1454 140 Calcium nitrate

1455 140 Calcium perchlorate

1456 140 Calcium permanganate

1457 140 Calcium peroxide

1458 140 Borate and Chlorate mixtures

1458 140 Chlorate and Borate mixtures

1459 140 Chlorate and Magnesium

chloride mixture

1459 140 Chlorate and Magnesium

chloride mixture, solid

1459 140 Magnesium chloride and

Chlorate mixture

1459 140 Magnesium chloride and

Chlorate mixture, solid

1461 140 Chlorates, inorganic, n.o.s.

1462 143 Chlorites, inorganic, n.o.s.

1463 141 Chromic acid, solid

1463 141 Chromium trioxide, anhydrous

1465 140 Didymium nitrate

1471 140 Lithium 

1471 140 Lithium 

1471 140 Lithium 

dry

1472 143 Lithium 

1473 140 Magnes

1474 140 Magnes

1475 140 Magnes

1476 140 Magnes

1477 140 Nitrates

1479 140 Oxidizi

1481 140 Perchlo

1482 140 Perman

n.o.s

1483 140 Peroxid

1484 140 Potass

1485 140 Potass

1486 140 Potass

1487 140 Potass

nitrit

1487 140 Sodium 

nitra

1488 140 Potass

1489 140 Potass

1490 140 Potass

1491 144 Potass

1492 140 Potass

1492 140 Potass

Numeric 27-96 Eng.pmd 3/25/037
Page 38

nitrate mixture

1499 140 Sodium nitrate and Potassium

nitrate mixture

1500 140 Sodium nitrite

1502 140 Sodium perchlorate

1503 140 Sodium permanganate

1504 144 Sodium peroxide

1505 140 Sodium persulfate

1505 140 Sodium persulphate

1506 143 Strontium chlorate

1506 143 Strontium chlorate, solid

1506 143 Strontium chlorate, solution

1507 140 Strontium nitrate

1508 140 Strontium perchlorate

1509 143 Strontium peroxide

1510 143 Tetranitromethane

1511 140 Urea hydrogen peroxide

1512 140 Zinc ammonium nitrite

1513 140 Zinc chlorate

1514 140 Zinc nitrate

1515 140 Zinc permanganate

1516 143 Zinc peroxide

1517 113 Zirconium picramate, wetted

with not less than 20% water

1541 155 Acetone cyanohydrin, stabilized

1544 151 Alkaloids, solid, n.o.s.

(poisonous)

1549 157 Antimony c

n.o.s.

1549 157 Antimony c

solid, n.o

1549 157 Antimony tr

1549 157 Antimony tr

1549 157 Antimony tr

1549 157 Antimony tr

1550 151 Antimony la

1551 151 Antimony p

1553 154 Arsenic aci

1554 154 Arsenic aci

1555 151 Arsenic bro

1556 152 Arsenic com

1556 152 Arsenic com

n.o.s., in

1556 152 MD

1556 152 Methyldich

1556 152 PD

1557 152 Arsenic com

1557 152 Arsenic com

inorganic

1557 152 Arsenic sul

1557 152 Arsenic sul

1557 152 Arsenic tris

1557 152 Arsenic tris

1558 152 Arsenic

1559 151 Arsenic pen

Numeric 27-96 Eng.pmd 3/25/038
1566 154 Beryllium compound, n.o.s.

1567 134 Beryllium powder

1569 131 Bromoacetone

1570 152 Brucine

1571 113 Barium azide, wetted with not

less than 50% water

1572 151 Cacodylic acid

1573 151 Calcium arsenate

1574 151 Calcium arsenate and Calcium

arsenite mixture, solid

1574 151 Calcium arsenite, solid

1574 151 Calcium arsenite and Calcium

arsenate mixture, solid

1575 157 Calcium cyanide

1577 153 Chlorodinitrobenzenes

1577 153 Chlorodinitrobenzenes, liquid

1577 153 Chlorodinitrobenzenes, solid

1577 153 Dinitrochlorobenzenes

1578 152 Chloronitrobenzenes

1578 152 Chloronitrobenzenes, liquid

1578 152 Chloronitrobenzenes, solid

1579 153 4-Chloro-o-toluidine

hydrochloride

1579 153 4-Chloro-o-toluidine

hydrochloride, solid

1580 154 Chloropicrin

1581 123 Chloropicrin and Methyl bromide

mixture

1585 151 Copper 

1586 151 Copper 

1587 151 Copper 

1588 157 Cyanid

1588 157 Cyanide

1589 125 CK

1589 125 Cyanog

1590 153 Dichlor

1590 153 Dichlor

1590 153 Dichlor

1591 152 o-Dichl

1593 160 Dichlor

1593 160 Methyle

1594 152 Diethyl 

1594 152 Diethyl 

1595 156 Dimeth

1595 156 Dimeth

1596 153 Dinitroa

1597 152 Dinitrob

1597 152 Dinitrob

1597 152 Dinitrob

1598 153 Dinitro-

1599 153 Dinitrop

1600 152 Dinitrot

1601 151 Disinfe

n.o.s

1601 151 Disinfe

Numeric 27-96 Eng.pmd 3/25/039
Page 40

1602 151 Dye intermediate, liquid, toxic,

n.o.s.

1603 155 Ethyl bromoacetate

1604 132 Ethylenediamine

1605 154 Ethylene dibromide

1606 151 Ferric arsenate

1607 151 Ferric arsenite

1608 151 Ferrous arsenate

1610 159 Halogenated irritating liquid, n.o.s.

1611 151 Hexaethyl tetraphosphate

1611 151 Hexaethyl tetraphosphate, liquid

1611 151 Hexaethyl tetraphosphate, solid

1612 123 Hexaethyl tetraphosphate and

compressed gas mixture

1613 154 Hydrocyanic acid, aqueous

solution, with less than 5%

Hydrogen cyanide

1613 154 Hydrocyanic acid, aqueous

solution, with not more than

20% Hydrogen cyanide

1613 154 Hydrogen cyanide, aqueous

solution, with not more than

20% Hydrogen cyanide

1614 152 Hydrogen cyanide, stabilized

(absorbed)

1616 151 Lead acetate

1617 151 Lead arsenates

1618 151 Lead arsenites

1620 151 Lead cyanide

1621 151 London purple

1629 151 Mercury ac

1630 151 Mercury am

1631 154 Mercury be

1634 154 Mercuric br

1634 154 Mercurous 

1634 154 Mercury bro

1636 154 Mercuric cy

1636 154 Mercury cy

1637 151 Mercury glu

1638 151 Mercury iod

1639 151 Mercury nu

1640 151 Mercury ole

1641 151 Mercury ox

1642 151 Mercuric ox

1642 151 Mercury ox

desensit

1643 151 Mercury po

1644 151 Mercury sa

1645 151 Mercuric su

1645 151 Mercuric su

1645 151 Mercury su

1645 151 Mercury su

1646 151 Mercury thi

1647 151 Ethylene di

bromide 

1647 151 Methyl brom

dibromid

1648 127 Acetonitrile

Numeric 27-96 Eng.pmd 3/25/040
1650 153 Naphthylamine (beta), solid

1651 153 Naphthylthiourea

1652 153 Naphthylurea

1653 151 Nickel cyanide

1654 151 Nicotine

1655 151 Nicotine compound, solid, n.o.s.

1655 151 Nicotine preparation, solid, n.o.s.

1656 151 Nicotine hydrochloride

1656 151 Nicotine hydrochloride, liquid

1656 151 Nicotine hydrochloride, solid

1656 151 Nicotine hydrochloride, solution

1657 151 Nicotine salicylate

1658 151 Nicotine sulfate, solid

1658 151 Nicotine sulfate, solution

1658 151 Nicotine sulphate, solid

1658 151 Nicotine sulphate, solution

1659 151 Nicotine tartrate

1660 124 Nitric oxide

1660 124 Nitric oxide, compressed

1661 153 Nitroanilines

1662 152 Nitrobenzene

1663 153 Nitrophenols

1664 152 Nitrotoluenes

1664 152 Nitrotoluenes, liquid

1664 152 Nitrotoluenes, solid

1665 152 Nitroxylenes

1665 152 Nitroxylenes, liquid

1674 151 Phenyl

1677 151 Potass

1678 154 Potass

1679 157 Potass

1680 157 Potass

1680 157 Potass

1683 151 Silver a

1684 151 Silver c

1685 151 Sodium 

1686 154 Sodium 

solut

1687 153 Sodium 

1688 152 Sodium 

1689 157 Sodium 

1689 157 Sodium 

1690 154 Sodium 

1690 154 Sodium 

1691 151 Strontiu

1692 151 Strychn

1692 151 Strychn

1693 159 Tear ga

1693 159 Tear ga

1693 159 Tear ga

1694 159 Bromob

1694 159 Bromob

1694 159 Bromob

1694 159 CA

Numeric 27-96 Eng.pmd 3/25/041
Page 42

1698 154 Diphenylamine chloroarsine

1698 154 DM

1699 151 DA

1699 151 Diphenylchloroarsine

1699 151 Diphenylchloroarsine, liquid

1699 151 Diphenylchloroarsine, solid

1700 159 Tear gas candles

1700 159 Tear gas grenades

1701 152 Xylyl bromide

1701 152 Xylyl bromide, liquid

1702 151 1,1,2,2-Tetrachloroethane

1702 151 Tetrachloroethane

1704 153 Tetraethyl dithiopyrophosphate

1704 153 Tetraethyl dithiopyrophosphate,

mixture, dry or liquid

1707 151 Thallium compound, n.o.s.

1707 151 Thallium sulfate, solid

1707 151 Thallium sulphate, solid

1708 153 Toluidines

1708 153 Toluidines, liquid

1708 153 Toluidines, solid

1709 151 2,4-Toluenediamine

1709 151 2,4-Toluylenediamine

1709 151 2,4-Toluylenediamine, solid

1710 160 Trichloroethylene

1711 153 Xylidines

1711 153 Xylidines, liquid

mixture

1713 151 Zinc cyanid

1714 139 Zinc phosp

1715 137 Acetic anhy

1716 156 Acetyl brom

1717 155 Acetyl chlo

1718 153 Acid butyl p

1718 153 Butyl acid p

1719 154 Caustic alk

1722 155 Allyl chloro

1722 155 Allyl chloro

1723 132 Allyl iodide

1724 155 Allyltrichlo

1725 137 Aluminum b

1726 137 Aluminum c

1727 154 Ammonium 

1727 154 Ammonium 

solid

1727 154 Ammonium 

solid

1728 155 Amyltrichlo

1729 156 Anisoyl chl

1730 157 Antimony p

1731 157 Antimony p

solution

1732 157 Antimony p

1733 157 Antimony tr

1733 157 Antimony tr

Numeric 27-96 Eng.pmd 3/25/042
1740 154 Hydrogendifluorides, n.o.s.

1740 154 Hydrogendifluorides, solid,

n.o.s.

1741 125 Boron trichloride

1742 157 Boron trifluoride acetic acid

complex

1742 157 Boron trifluoride acetic acid

complex, liquid

1743 157 Boron trifluoride propionic acid

complex

1743 157 Boron trifluoride propionic acid

complex, liquid

1744 154 Bromine

1744 154 Bromine, solution

1744 154 Bromine, solution (Inhalation

Hazard Zone A)

1744 154 Bromine, solution (Inhalation

Hazard Zone B)

1745 144 Bromine pentafluoride

1746 144 Bromine trifluoride

1747 155 Butyltrichlorosilane

1748 140 Calcium hypochlorite, dry

1748 140 Calcium hypochlorite mixture,

dry, with more than 39%

available Chlorine (8.8%

available Oxygen)

1749 124 Chlorine trifluoride

1750 153 Chloroacetic acid, liquid

1750 153 Chloroacetic acid, solution

1754 137 Chloros

1754 137 Chloros

Sulp

1754 137 Sulfur t

Chlo

1754 137 Sulphu

Chlo

1755 154 Chromi

1756 154 Chromi

1757 154 Chromi

1758 137 Chromi

1759 154 Corrosi

1759 154 Ferrous 

1759 154 Medicin

1760 154 Chemic

1760 154 Compo

(corr

1760 154 Compo

liquid 

1760 154 Corrosi

1760 154 Ferrous 

1760 154 Medicin

1760 154 Titaniu

1760 154 Titaniu

1761 154 Cupriet

1762 156 Cyclohe

1763 156 Cyclohe

1764 153 Dichlor

Numeric 27-96 Eng.pmd 3/25/043
Page 44

1770 153 Diphenylmethyl bromide

1771 156 Dodecyltrichlorosilane

1773 157 Ferric chloride

1773 157 Ferric chloride, anhydrous

1774 154 Fire extinguisher charges,

corrosive liquid

1775 154 Fluoboric acid

1775 154 Fluoroboric acid

1776 154 Fluorophosphoric acid,

anhydrous

1777 137 Fluorosulfonic acid

1777 137 Fluorosulphonic acid

1778 154 Fluorosilicic acid

1778 154 Fluosilicic acid

1778 154 Hydrofluorosilicic acid

1779 153 Formic acid

1779 153 Formic acid, with more than 85%

acid

1780 156 Fumaryl chloride

1781 156 Hexadecyltrichlorosilane

1782 154 Hexafluorophosphoric acid

1783 153 Hexamethylenediamine,

solution

1784 156 Hexyltrichlorosilane

1786 157 Hydrofluoric acid and Sulfuric

acid mixture

1786 157 Hydrofluoric acid and Sulphuric

acid mixture

1788 154 Hydrobrom

1788 154 Hydrobrom

1789 157 Hydrochlor

1789 157 Hydrochlor

1789 157 Muriatic ac

1790 157 Hydrofluori

1790 157 Hydrofluori

1791 154 Hypochlori

1791 154 Hypochlori

than 5% 

1792 157 Iodine mon

1793 153 Isopropyl a

1794 154 Lead sulfat

free acid

1794 154 Lead sulph

3% free a

1796 157 Nitrating ac

1798 157 Aqua regia

1798 157 Nitrohydroc

1799 156 Nonyltrichl

1800 156 Octadecylt

1801 156 Octyltrichlo

1802 140 Perchloric 

than 50% 

1803 153 Phenolsulfo

1803 153 Phenolsulp

1804 156 Phenyltrich

1805 154 Phosphoric 

Numeric 27-96 Eng.pmd 3/25/044
1809 137 Phosphorus trichloride

1810 137 Phosphorus oxychloride

1811 154 Potassium hydrogendifluoride

1811 154 Potassium hydrogen difluoride,

solid

1812 154 Potassium fluoride

1812 154 Potassium fluoride, solid

1813 154 Caustic potash, dry, solid

1813 154 Potassium hydroxide, dry, solid

1813 154 Potassium hydroxide, flake

1813 154 Potassium hydroxide, solid

1814 154 Caustic potash, liquid

1814 154 Caustic potash, solution

1814 154 Potassium hydroxide, solution

1815 132 Propionyl chloride

1816 155 Propyltrichlorosilane

1817 137 Pyrosulfuryl chloride

1817 137 Pyrosulphuryl chloride

1818 157 Silicon tetrachloride

1819 154 Sodium aluminate, solution

1823 154 Caustic soda, bead

1823 154 Caustic soda, flake

1823 154 Caustic soda, granular

1823 154 Caustic soda, solid

1823 154 Sodium hydroxide, bead

1823 154 Sodium hydroxide, dry

1823 154 Sodium hydroxide, flake

1827 137 Stannic 

1827 137 Tin tetr

1828 137 Sulfur c

1828 137 Sulphu

1829 137 Sulfur t

1829 137 Sulfur t

1829 137 Sulfur t

1829 137 Sulphu

1829 137 Sulphu

1829 137 Sulphu

1830 137 Sulfuric 

1830 137 Sulfuric 

51% 

1830 137 Sulphu

1830 137 Sulphu

51% 

1831 137 Sulfuric 

1831 137 Sulfuric 

than 

1831 137 Sulfuric 

less 

trioxi

1831 137 Sulphu

1831 137 Sulphu

than 

1831 137 Sulphu

less 

trioxi

1832 137 Sulfuric 

Numeric 27-96 Eng.pmd 3/25/045
Page 46

hydroxide

1835 153 Tetramethylammonium

hydroxide, solution

1836 137 Thionyl chloride

1837 157 Thiophosphoryl chloride

1838 137 Titanium tetrachloride

1839 153 Trichloroacetic acid

1840 154 Zinc chloride, solution

1841 171 Acetaldehyde ammonia

1843 141 Ammonium dinitro-o-cresolate

1843 141 Ammonium dinitro-o-cresolate,

solid

1845 120 Carbon dioxide, solid

1845 120 Dry ice

1846 151 Carbon tetrachloride

1847 153 Potassium sulfide, hydrated,

with not less than 30% water

of crystallization

1847 153 Potassium sulfide, hydrated,

with not less than 30% water

of hydration

1847 153 Potassium sulphide, hydrated,

with not less than 30% water

of crystallization

1847 153 Potassium sulphide, hydrated,

with not less than 30% water

of hydration

1848 132 Propionic acid

1848 132 Propionic acid, with not less

than 10% and less than 90%

acid

1854 135 Barium allo

1855 135 Calcium, m

pyrophor

1855 135 Calcium, py

1855 135 Calcium all

1856 133 Rags, oily

1857 133 Textile was

1858 126 Hexafluoro

1858 126 Refrigerant 

1859 125 Silicon tetr

1859 125 Silicon tetr

compres

1860 116P Vinyl fluorid

1862 130 Ethyl croto

1863 128 Fuel, aviati

1865 131 n-Propyl ni

1866 127 Resin solut

1868 134 Decaboran

1869 138 Magnesium

1869 138 Magnesium

or ribbon

1869 138 Magnesium 

than 50% 

pellets, t

1870 138 Potassium 

1871 170 Titanium hy

1872 141 Lead dioxid

1873 143 Perchloric 

50% but 

acid

Numeric 27-96 Eng.pmd 3/25/046
1891 131 Ethyl bromide

1892 151 ED

1892 151 Ethyldichloroarsine

1894 151 Phenylmercuric hydroxide

1895 151 Phenylmercuric nitrate

1897 160 Perchloroethylene

1897 160 Tetrachloroethylene

1898 156 Acetyl iodide

1902 153 Diisooctyl acid phosphate

1903 153 Disinfectant, liquid, corrosive,

n.o.s.

1903 153 Disinfectants, corrosive, liquid,

n.o.s.

1905 154 Selenic acid

1906 153 Acid, sludge

1906 153 Sludge acid

1907 154 Soda lime, with more than 4%

Sodium hydroxide

1908 154 Chlorite solution

1908 154 Chlorite solution, with more than

5% available Chlorine

1908 154 Sodium chlorite, solution, with

more than 5% available Chlorine

1910 157 Calcium oxide

1911 119 Diborane

1911 119 Diborane, compressed

1911 119 Diborane mixtures

1915 127 Cyclohe

1916 152 2,2'-Dic

1916 152 Dichlor

1917 129P Ethyl ac

1918 130 Cumen

1918 130 Isoprop

1919 129P Methyl 

1920 128 Nonane

1921 131P Propyle

1922 132 Pyrrolid

1923 135 Calcium 

1923 135 Calcium 

1923 135 Calcium 

1928 135 Methyl 

Ethy

1929 135 Potass

1929 135 Potass

1929 135 Potass

1931 171 Zinc dit

1931 171 Zinc hy

1931 171 Zinc hy

1932 135 Zirconi

1935 157 Cyanid

1938 156 Bromoa

1938 156 Bromoa

1939 137 Phosph

1939 137 Phosph

Numeric 27-96 Eng.pmd 3/25/047
Page 48

1945 133 Matches, wax vesta

1950 126 Aerosol dispensers

1950 126 Aerosols

1951 120 Argon, refrigerated liquid

(cryogenic liquid)

1952 126 Carbon dioxide and Ethylene

oxide mixtures, with not more

than 6% Ethylene oxide

1952 126 Carbon dioxide and Ethylene

oxide mixtures, with not more

than 9% Ethylene oxide

1952 126 Ethylene oxide and Carbon

dioxide mixtures, with not

more than 6% Ethylene oxide

1952 126 Ethylene oxide and Carbon

dioxide mixtures, with not

more than 9% Ethylene oxide

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Compressed gas, flammable,

toxic, n.o.s. (Inhalation

Hazard Zone A)

toxic, n.o

Hazard Z

1953 119 Compresse

flammab

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1953 119 Compresse

flammab

Hazard Z

1954 115 Compressed 

1954 115 Dispersant 

(flammab

Numeric 27-96 Eng.pmd 3/25/048
1955 123 Compressed gas, poisonous,

n.o.s.

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone A)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone B)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone C)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone D)

1955 123 Compressed gas, toxic, n.o.s.

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone A)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone B)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone C)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone D)

1955 123 Organic phosphate compound

mixed with compressed gas

1955 123 Organic phosphate mixed with

compressed gas

1955 123 Organic phosphorus compound

mixed with compressed gas

1956 126 Accumulators, pressurized,

pneumatic or hydraulic

1958 126 Dichlor

1958 126 Refrige

1959 116P 1,1-Difl

1959 116P Refrige

1960 115 Engine 

1961 115 Ethane

1961 115 Ethane

refrig

1961 115 Propan

refrig

1962 116P Ethylen

1962 116P Ethylen

1963 120 Helium

(cryo

1964 115 Hydroc

n.o.s

1964 115 Hydroc

comp

1965 115 Hydroca

1965 115 Hydroc

lique

1966 115 Hydrog

(cryo

1967 123 Insectic

n.o.s

1967 123 Insectic

1967 123 Parathi

mixtu

1968 126 Insectic

Numeric 27-96 Eng.pmd 3/25/049
Page 50

1971 115 Natural gas, compressed

1972 115 Liquefied natural gas (cryogenic

liquid)

1972 115 LNG (cryogenic liquid)

1972 115 Methane, refrigerated liquid

(cryogenic liquid)

1972 115 Natural gas, refrigerated liquid

(cryogenic liquid)

1973 126 Chlorodifluoromethane and

Chloropentafluoroethane

mixture

1973 126 Chloropentafluoroethane and

Chlorodifluoromethane

mixture

1973 126 Refrigerant gas R-502

1974 126 Bromochlorodifluoromethane

1974 126 Chlorodifluorobromomethane

1974 126 Refrigerant gas R-12B1

1975 124 Dinitrogen tetroxide and Nitric

oxide mixture

1975 124 Nitric oxide and Dinitrogen

tetroxide mixture

1975 124 Nitric oxide and Nitrogen dioxide

mixture

1975 124 Nitric oxide and Nitrogen

tetroxide mixture

1975 124 Nitrogen dioxide and Nitric oxide

mixture

1975 124 Nitrogen tetroxide and Nitric

oxide mixture

1979 121 Rare gases 

1979 121 Rare gases 

compres

1980 121 Oxygen an

1980 121 Oxygen and 

compres

1980 121 Rare gases 

1980 121 Rare gases 

compres

1981 121 Nitrogen an

1981 121 Nitrogen an

mixture, 

1981 121 Rare gases 

1981 121 Rare gases 

mixture, 

1982 126 Refrigerant 

1982 126 Refrigerant 

compres

1982 126 Tetrafluoro

1982 126 Tetrafluoro

compres

1983 126 1-Chloro-2

1983 126 Chlorotriflu

1983 126 Refrigerant 

1984 126 Refrigerant 

1984 126 Trifluorome

1986 131 Alcohols, fl

n.o.s.

1986 131 Alcohols, fl

Numeric 27-96 Eng.pmd 3/25/050
1988 131 Aldehydes, flammable,

poisonous, n.o.s.

1988 131 Aldehydes, flammable, toxic,

n.o.s.

1988 131 Aldehydes, poisonous, n.o.s.

1988 131 Aldehydes, toxic, n.o.s.

1989 129 Aldehydes, n.o.s.

1990 129 Benzaldehyde

1991 131P Chloroprene, stabilized

1992 131 Flammable liquid, poisonous,

n.o.s.

1992 131 Flammable liquid, toxic, n.o.s.

1993 128 Combustible liquid, n.o.s.

1993 128 Compound, cleaning liquid

(flammable)

1993 128 Compound, tree or weed killing,

liquid (flammable)

1993 128 Diesel fuel

1993 128 Flammable liquid, n.o.s.

1993 128 Fuel oil

1993 128 Medicines, flammable, liquid,

n.o.s.

1993 128 Refrigerating machine

1994 131 Iron pentacarbonyl

1999 130 Asphalt

1999 130 Tars, liquid

2000 133 Celluloid, in blocks, rods, rolls,

sheets, tubes, etc., except

scrap

2003 135 Metal a

n.o.s

2004 135 Magnes

2005 135 Magnes

2006 135 Plastic

spon

n.o.s

2006 135 Plastics

self-h

2008 135 Zirconi

2009 135 Zirconi

strips 

2010 138 Magnes

2011 139 Magnes

2012 139 Potass

2013 139 Strontiu

2014 140 Hydrog

solut

20% 

Hydr

as ne

2015 143 Hydrog

solut

than 

2015 143 Hydrog

2016 151 Ammun

non-e

2016 151 Ammun

non-e

Numeric 27-96 Eng.pmd 3/25/051
Page 52

2022 153 Cresylic acid

2023 131P 1-Chloro-2,3-epoxypropane

2023 131P Epichlorohydrin

2024 151 Mercury compound, liquid, n.o.s.

2025 151 Mercury compound, solid, n.o.s.

2026 151 Phenylmercuric compound,

n.o.s.

2027 151 Sodium arsenite, solid

2028 153 Bombs, smoke, non-explosive,

with corrosive liquid, without

initiating device

2029 132 Hydrazine, anhydrous

2029 132 Hydrazine, aqueous solutions,

with more than 64% Hydrazine

2030 153 Hydrazine, aqueous solution,

with more than 37% Hydrazine

2030 153 Hydrazine, aqueous solution,

with not less than 37% but not

more than 64% Hydrazine

2030 153 Hydrazine hydrate

2031 157 Nitric acid, other than red fuming

2032 157 Nitric acid, fuming

2032 157 Nitric acid, red fuming

2033 154 Potassium monoxide

2034 115 Hydrogen and Methane mixture,

compressed

2034 115 Methane and Hydrogen mixture,

compressed

2035 115 Refrigerant gas R-143a

gas

2038 152 Dinitrotolue

2038 152 Dinitrotolue

2038 152 Dinitrotolue

2044 115 2,2-Dimeth

2045 130 Isobutyl ald

2045 130 Isobutyrald

2046 130 Cymenes

2047 129 Dichloropro

2048 130 Dicyclopen

2049 130 Diethylben

2050 128 Diisobutyle

compoun

2051 132 2-Dimethyl

2051 132 Dimethylet

2052 128 Dipentene

2053 129 Methylamy

2053 129 Methyl isob

2053 129 M.I.B.C.

2054 132 Morpholine

2055 128P Styrene mo

2056 127 Tetrahydro

2057 128 Tripropylen

2058 129 Valeraldeh

2059 127 Nitrocellulo

flammab

2059 127 Nitrocellulo

flammab

Numeric 27-96 Eng.pmd 3/25/052
2069 140 Ammonium nitrate mixed

fertilizers

2070 143 Ammonium nitrate fertilizers,

with Phosphate or Potash

2071 140 Ammonium nitrate fertilizer, with

not more than 0.4%

combustible material

2071 140 Ammonium nitrate fertilizers

2072 140 Ammonium nitrate fertilizer, n.o.s.

2072 140 Ammonium nitrate fertilizers

2073 125 Ammonia, solution, with more

than 35% but not more than

50% Ammonia

2074 153P Acrylamide

2074 153P Acrylamide, solid

2075 153 Chloral, anhydrous, stabilized

2076 153 Cresols

2076 153 Cresols, liquid

2076 153 Cresols, solid

2077 153 alpha-Naphthylamine

2077 153 Naphthylamine (alpha)

2078 156 Toluene diisocyanate

2079 154 Diethylenetriamine

2186 125 Hydrogen chloride, refrigerated

liquid

2187 120 Carbon dioxide, refrigerated

liquid

2188 119 Arsine

2188 119 SA

2193 126 Hexaflu

2193 126 Hexaflu

2193 126 Refrige

2193 126 Refrige

comp

2194 125 Seleniu

2195 125 Telluriu

2196 125 Tungste

2197 125 Hydrog

2198 125 Phosph

2198 125 Phosph

comp

2199 119 Phosph

2200 116P Propad

2201 122 Nitrous 

2202 117 Hydrog

2203 116 Silane

2203 116 Silane, 

2204 119 Carbon

2204 119 Carbon

2205 153 Adipon

2206 155 Isocyan

n.o.s

2206 155 Isocyan

2206 155 Isocyan

2206 155 Isocyan

2206 155 Isocyan

Numeric 27-96 Eng.pmd 3/25/053
Page 54

(Formalin) (corrosive)

2210 135 Maneb

2210 135 Maneb preparation, with not less

than 60% Maneb

2211 133 Polymeric beads, expandable

2211 133 Polystyrene beads, expandable

2212 171 Asbestos

2212 171 Asbestos, blue

2212 171 Asbestos, brown

2212 171 Blue asbestos

2212 171 Brown asbestos

2213 133 Paraformaldehyde

2214 156 Phthalic anhydride

2215 156 Maleic acid

2215 156 Maleic anhydride

2215 156 Maleic anhydride, molten

2216 171 Fish meal, stabilized

2216 171 Fish scrap, stabilized

2217 135 Seed cake, with not more than

1.5% oil and not more than

11% moisture

2218 132P Acrylic acid, stabilized

2219 129 Allyl glycidyl ether

2222 128 Anisole

2224 152 Benzonitrile

2225 156 Benzenesulfonyl chloride

2225 156 Benzenesulphonyl chloride

2235 153 Chlorobenz

2235 153 Chlorobenz

2236 156 3-Chloro-4

isocyana

2236 156 3-Chloro-4

isocyana

2237 153 Chloronitro

2238 129 Chlorotolue

2239 153 Chlorotolui

2239 153 Chlorotolui

2239 153 Chlorotolui

2240 154 Chromosul

2240 154 Chromosul

2241 128 Cyclohepta

2242 128 Cyclohepte

2243 130 Cyclohexyl 

2244 129 Cyclopenta

2245 128 Cyclopenta

2246 128 Cyclopente

2247 128 n-Decane

2248 132 Di-n-butyla

2249 131 Dichlorodim

symmetr

2250 156 Dichloroph

2251 128P Bicyclo[2.2

stabilize

2251 128P 2,5-Norbor

2252 127 1,2-Dimeth

Numeric 27-96 Eng.pmd 3/25/054
2258 132 1,3-Propylenediamine

2259 153 Triethylenetetramine

2260 132 Tripropylamine

2261 153 Xylenols

2261 153 Xylenols, solid

2262 156 Dimethylcarbamoyl chloride

2263 128 Dimethylcyclohexanes

2264 132 N,N-Dimethylcyclohexylamine

2264 132 Dimethylcyclohexylamine

2265 129 N,N-Dimethylformamide

2266 132 Dimethyl-N-propylamine

2267 156 Dimethyl thiophosphoryl

chloride

2269 153 3,3'-Iminodipropylamine

2270 132 Ethylamine, aqueous solution,

with not less than 50% but not

more than 70% Ethylamine

2271 128 Ethyl amyl ketone

2272 153 N-Ethylaniline

2273 153 2-Ethylaniline

2274 153 N-Ethyl-N-benzylaniline

2275 129 2-Ethylbutanol

2276 132 2-Ethylhexylamine

2277 130P Ethyl methacrylate

2277 130P Ethyl methacrylate, stabilized

2278 128 n-Heptene

2279 151 Hexachlorobutadiene

2280 153 Hexamethylenediamine, solid

2287 128 Isohept

2288 128 Isohexe

2289 153 Isophor

2290 156 IPDI

2290 156 Isophor

2291 151 Lead co

2293 128 4-Metho

2294 153 N-Meth

2295 155 Methyl 

2296 128 Methylc

2297 128 Methylc

2298 128 Methylc

2299 155 Methyl 

2300 153 2-Meth

2301 128 2-Meth

2302 127 5-Meth

2303 128 Isoprop

2304 133 Naphth

2305 153 Nitrobe

2305 153 Nitrobe

2306 152 Nitrobe

2306 152 Nitrobe

2307 152 3-Nitro

2308 157 Nitrosy

2308 157 Nitrosy

2308 157 Nitrosy

2308 157 Nitrosy

Numeric 27-96 Eng.pmd 3/25/055
Page 56

2311 153 Phenetidines

2312 153 Phenol, molten

2313 129 Picolines

2315 171 Articles containing Polychlorinated

biphenyls (PCB)

2315 171 PCB

2315 171 Polychlorinated biphenyls

2315 171 Polychlorinated biphenyls, liquid

2315 171 Polychlorinated biphenyls, solid

2316 157 Sodium cuprocyanide, solid

2317 157 Sodium cuprocyanide, solution

2318 135 Sodium hydrosulfide, solid, with

less than 25% water of

crystallization

2318 135 Sodium hydrosulfide, with less

than 25% water of

crystallization

2318 135 Sodium hydrosulphide, solid,

with less than 25% water of

crystallization

2318 135 Sodium hydrosulphide, with less

than 25% water of

crystallization

2319 128 Terpene hydrocarbons, n.o.s.

2320 153 Tetraethylenepentamine

2321 153 Trichlorobenzenes, liquid

2322 152 Trichlorobutene

2323 130 Triethyl phosphite

2324 128 Triisobutylene

2330 128 Undecane

2331 154 Zinc chlorid

2332 129 Acetaldehy

2333 131 Allyl acetat

2334 131 Allylamine

2335 131 Allyl ethyl e

2336 131 Allyl format

2337 131 Phenyl mer

2338 127 Benzotriflu

2339 130 2-Bromobu

2340 130 2-Bromoeth

2341 130 1-Bromo-3-

2342 130 Bromometh

2343 130 2-Bromope

2344 129 2-Bromopro

2344 129 Bromoprop

2345 130 3-Bromopro

2346 127 Butanedion

2346 127 Diacetyl

2347 130 Butyl merca

2348 129P Butyl acryla

2350 127 Butyl methy

2351 129 Butyl nitrite

2352 127P Butyl vinyl 

2353 132 Butyryl chlo

2354 131 Chlorometh

2356 129 2-Chloropr

Numeric 27-96 Eng.pmd 3/25/056
2363 129 Ethyl mercaptan

2364 128 n-Propyl benzene

2366 128 Diethyl carbonate

2367 130 alpha-Methylvaleraldehyde

2367 130 Methyl valeraldehyde (alpha)

2368 128 alpha-Pinene

2368 128 Pinene (alpha)

2369 152 Ethylene glycol monobutyl ether

2370 128 1-Hexene

2371 128 Isopentenes

2372 129 1,2-Di-(dimethylamino)ethane

2373 127 Diethoxymethane

2374 127 3,3-Diethoxypropene

2375 129 Diethyl sulfide

2375 129 Diethyl sulphide

2376 127 2,3-Dihydropyran

2377 127 1,1-Dimethoxyethane

2378 131 2-Dimethylaminoacetonitrile

2379 132 1,3-Dimethylbutylamine

2380 127 Dimethyldiethoxysilane

2381 130 Dimethyl disulfide

2381 130 Dimethyl disulphide

2382 131 1,2-Dimethylhydrazine

2382 131 Dimethylhydrazine, symmetrical

2383 132 Dipropylamine

2384 127 Di-n-propyl ether

2384 127 Dipropyl ether

2391 129 Iodome

2392 129 Iodopro

2393 129 Isobuty

2394 129 Isobuty

2395 132 Isobuty

2396 131P Methac

2397 127 3-Meth

2398 127 Methyl 

2399 132 1-Meth

2400 130 Methyl 

2401 132 Piperid

2402 130 Propan

2403 129P Isoprop

2404 131 Propion

2405 129 Isoprop

2406 127 Isoprop

2407 155 Isoprop

2409 129 Isoprop

2410 129 1,2,3,6

2410 129 1,2,5,6

2411 131 Butyron

2412 130 Tetrahy

2413 128 Tetrapr

2414 130 Thiophe

2416 129 Trimeth

2417 125 Carbon

2417 125 Carbon

Numeric 27-96 Eng.pmd 3/25/057
Page 58

2422 126 Refrigerant gas R-1318

2424 126 Octafluoropropane

2424 126 Refrigerant gas R-218

2426 140 Ammonium nitrate, liquid (hot

concentrated solution)

2427 140 Potassium chlorate, aqueous

solution

2427 140 Potassium chlorate, solution

2428 140 Sodium chlorate, aqueous

solution

2429 140 Calcium chlorate, aqueous

solution

2429 140 Calcium chlorate, solution

2430 153 Alkyl phenols, solid, n.o.s.

(including C2-C12

homologues)

2431 153 Anisidines

2431 153 Anisidines, liquid

2431 153 Anisidines, solid

2432 153 N,N-Diethylaniline

2433 152 Chloronitrotoluenes

2433 152 Chloronitrotoluenes, liquid

2433 152 Chloronitrotoluenes, solid

2434 156 Dibenzyldichlorosilane

2435 156 Ethylphenyldichlorosilane

2436 129 Thioacetic acid

2437 156 Methylphenyldichlorosilane

2438 132 Trimethylacetyl chloride

2442 156 Trichloroac

2443 137 Vanadium o

2444 137 Vanadium t

2445 135 Lithium alk

2445 135 Lithium alk

2446 153 Nitrocresol

2446 153 Nitrocresol

2447 136 Phosphoru

2447 136 White phos

2447 136 Yellow pho

2448 133 Sulfur, mol

2448 133 Sulphur, m

2451 122 Nitrogen tri

2451 122 Nitrogen tri

2452 116P Ethylacetyl

2453 115 Ethyl fluori

2453 115 Refrigerant 

2454 115 Methyl fluo

2454 115 Refrigerant 

2455 116 Methyl nitri

2456 130P 2-Chloropr

2457 128 2,3-Dimeth

2458 130 Hexadiene

2459 128 2-Methyl-1

2460 128 2-Methyl-2

2461 128 Methylpent

2463 138 Aluminum h

Numeric 27-96 Eng.pmd 3/25/058
2467 140 Sodium percarbonates

2468 140 Trichloroisocyanuric acid, dry

2468 140 (mono)-(Trichloro)-tetra-

(monopotassium dichloro)-

penta-s-triazinetrione, dry

2469 140 Zinc bromate

2470 152 Phenylacetonitrile, liquid

2471 154 Osmium tetroxide

2473 154 Sodium arsanilate

2474 157 Thiophosgene

2475 157 Vanadium trichloride

2477 131 Methyl isothiocyanate

2478 155 Isocyanate solution, flammable,

poisonous, n.o.s.

2478 155 Isocyanate solution, flammable,

toxic, n.o.s.

2478 155 Isocyanate solutions, n.o.s.

2478 155 Isocyanates, flammable,

poisonous, n.o.s.

2478 155 Isocyanates, flammable, toxic,

n.o.s.

2478 155 Isocyanates, n.o.s.

2480 155 Methyl isocyanate

2481 155 Ethyl isocyanate

2482 155 n-Propyl isocyanate

2483 155 Isopropyl isocyanate

2484 155 tert-Butyl isocyanate

2485 155 n-Butyl isocyanate

2491 153 Monoet

2493 132 Hexam

2495 144 Iodine p

2496 156 Propion

2498 129 1,2,3,6

Tetra

2501 152 1-Azirid

(Tris

2501 152 Tri-(1-a

oxide

2501 152 Tris-(1-

oxide

2502 132 Valeryl 

2503 137 Zirconi

2504 159 Acetyle

2504 159 Tetrabr

2505 154 Ammon

2506 154 Ammon

2506 154 Ammon

2507 154 Chlorop

2508 156 Molybd

2509 154 Potass

2509 154 Potass

2511 153 2-Chlor

2511 153 2-Chlor

2511 153 2-Chlor

2512 152 Aminop

2513 156 Bromoa

Numeric 27-96 Eng.pmd 3/25/059
Page 60

2517 115 Refrigerant gas R-142b

2518 153 1,5,9-Cyclododecatriene

2520 130P Cyclooctadienes

2521 131P Diketene, stabilized

2522 153P 2-Dimethylaminoethyl

methacrylate

2522 153P Dimethylaminoethyl

methacrylate

2524 129 Ethyl orthoformate

2525 156 Ethyl oxalate

2526 132 Furfurylamine

2527 129P Isobutyl acrylate, stabilized

2528 130 Isobutyl isobutyrate

2529 132 Isobutyric acid

2530 132 Isobutyric anhydride

2531 153P Methacrylic acid, stabilized

2533 156 Methyl trichloroacetate

2534 119 Methylchlorosilane

2535 132 4-Methylmorpholine

2535 132 N-Methylmorpholine

2535 132 Methylmorpholine

2536 127 Methyltetrahydrofuran

2538 133 Nitronaphthalene

2541 128 Terpinolene

2542 153 Tributylamine

2545 135 Hafnium powder, dry

2546 135 Titanium powder, dry

2555 113 Nitrocellulo

less than 

2556 113 Nitrocellulo

2556 113 Nitrocellulo

25% alco

2557 133 Nitrocellulo

2557 133 Nitrocellulo

pigment

2557 133 Nitrocellulo

plasticiz

2557 133 Nitrocellulo

pigment

2557 133 Nitrocellulo

pigment 

2557 133 Nitrocellulo

plasticiz

2558 131 Epibromoh

2560 129 2-Methylpe

2561 128 3-Methyl-1

2564 153 Trichloroac

2565 153 Dicyclohex

2567 154 Sodium pen

2570 154 Cadmium c

2571 156 Alkylsulfuri

2571 156 Alkylsulphu

2571 156 Ethylsulfur

2571 156 Ethylsulphu

2572 153 Phenylhydr

2573 141 Thallium ch

Numeric 27-96 Eng.pmd 3/25/060
2581 154 Aluminum chloride, solution

2582 154 Ferric chloride, solution

2583 153 Alkyl sulfonic acids, solid, with

more than 5% free Sulfuric

acid

2583 153 Alkyl sulphonic acids, solid, with

more than 5% free Sulphuric

acid

2583 153 Aryl sulfonic acids, solid, with

more than 5% free Sulfuric

acid

2583 153 Aryl sulphonic acids, solid, with

more than 5% free Sulphuric

acid

2584 153 Alkyl sulfonic acids, liquid, with

more than 5% free Sulfuric acid

2584 153 Alkyl sulphonic acids, liquid,

with more than 5% free

Sulphuric acid

2584 153 Aryl sulfonic acids, liquid, with

more than 5% free Sulfuric

acid

2584 153 Aryl sulphonic acids, liquid, with

more than 5% free Sulphuric

acid

2584 153 Dodecylbenzenesulfonic acid

2584 153 Dodecylbenzenesulphonic acid

2585 153 Alkyl sulfonic acids, solid, with

not more than 5% free Sulfuric

acid

not m

Sulp

2586 153 Alkyl su

more 

2586 153 Alkyl su

with 

Sulp

2586 153 Aryl sul

not m

acid

2586 153 Aryl sul

not m

Sulp

2587 153 Benzoq

2588 151 Pesticid

2588 151 Pesticid

n.o.s

2588 151 Pesticid

2589 155 Vinyl ch

2590 171 Asbesto

2590 171 White a

2591 120 Xenon, 

(cryo

2599 126 Chlorot

Triflu

mixtu

60% 

2599 126 Refrige

Refri

azeo

Refri

Numeric 27-96 Eng.pmd 3/25/061
Page 62

gg

approximately 60%

Refrigerant gas R-13)

2599 126 Trifluoromethane and

Chlorotrifluoromethane

azeotropic mixture with

approximately 60%

Chlorotrifluoromethane

2600 119 Carbon monoxide and Hydrogen

mixture

2600 119 Carbon monoxide and Hydrogen

mixture, compressed

2600 119 Hydrogen and Carbon monoxide

mixture

2600 119 Hydrogen and Carbon monoxide

mixture, compressed

2601 115 Cyclobutane

2602 126 Dichlorodifluoromethane and

Difluoroethane azeotropic

mixture with approximately

74% Dichlorodifluoromethane

2602 126 Difluoroethane and

Dichlorodifluoromethane

azeotropic mixture with

approximately 74%

Dichlorodifluoromethane

2602 126 Refrigerant gas R-12 and

Refrigerant gas R-152a

azeotropic mixture with 74%

Refrigerant gas R-12

2602 126 Refrigerant gas R-152a and

Refrigerant gas R-12

azeotropic mixture with 74%

Refrigerant gas R-12

2604 132 Boron triflu

2605 155 Methoxyme

2606 155 Methyl orth

2607 129P Acrolein dim

2608 129 Nitropropa

2609 156 Triallyl bora

2610 132 Triallylamin

2611 131 Propylene c

2612 127 Methyl prop

2614 129 Methallyl a

2615 127 Ethyl propy

2616 129 Triisopropy

2617 129 Methylcyclo

2618 130P Vinyltoluen

2619 132 Benzyldime

2620 130 Amyl butyra

2621 127 Acetyl meth

2622 131P Glycidalde

2623 133 Firelighters

flammab

2624 138 Magnesium 

2626 140 Chloric acid

with not m

Chloric a

2627 140 Nitrites, ino

2628 151 Potassium 

2629 151 Sodium fluo

2630 151 Selenates

Numeric 27-96 Eng.pmd 3/25/062
2646 151 Hexachlorocyclopentadiene

2647 153 Malononitrile

2648 154 1,2-Dibromobutan-3-one

2649 153 1,3-Dichloroacetone

2650 153 1,1-Dichloro-1-nitroethane

2651 153 4,4'-Diaminodiphenylmethane

2653 156 Benzyl iodide

2655 151 Potassium fluorosilicate

2655 151 Potassium silicofluoride

2656 154 Quinoline

2657 153 Selenium disulfide

2657 153 Selenium disulphide

2658 152 Selenium powder

2659 151 Sodium chloroacetate

2660 153 Mononitrotoluidines

2660 153 Nitrotoluidines (mono)

2661 153 Hexachloroacetone

2662 153 Hydroquinone

2662 153 Hydroquinone, solid

2664 160 Dibromomethane

2666 156 Ethyl cyanoacetate

2667 152 Butyltoluenes

2668 131 Chloroacetonitrile

2669 152 Chlorocresols

2669 152 Chlorocresols, liquid

2669 152 Chlorocresols, solid

2669 152 Chlorocresols, solution

2672 154 Ammon

than 

35% 

2673 151 2-Amin

2674 154 Sodium 

2674 154 Sodium 

2676 119 Stibine

2677 154 Rubidiu

2678 154 Rubidiu

2678 154 Rubidiu

2679 154 Lithium 

2680 154 Lithium 

2680 154 Lithium 

2680 154 Lithium 

2681 154 Caesiu

2681 154 Cesium 

2682 157 Caesiu

2682 157 Cesium 

2683 132 Ammon

2683 132 Ammon

2684 132 3-Dieth

2684 132 Diethyl

2685 132 N,N-Die

2686 132 2-Dieth

2686 132 Diethyl

2687 133 Dicyclo

2688 159 1-Brom

2688 159 1-Chlor

Numeric 27-96 Eng.pmd 3/25/063
Page 64

n.o.s.

2693 154 Bisulfites, inorganic, aqueous

solution, n.o.s.

2693 154 Bisulphites, aqueous solution,

n.o.s.

2693 154 Bisulphites, inorganic, aqueous

solution, n.o.s.

2698 156 Tetrahydrophthalic anhydrides

2699 154 Trifluoroacetic acid

2705 153P 1-Pentol

2707 127 Dimethyldioxanes

2708 127 Butoxyl

2709 128 Butylbenzenes

2710 128 Dipropyl ketone

2711 129 Dibromobenzene

2713 153 Acridine

2714 133 Zinc resinate

2715 133 Aluminum resinate

2716 153 1,4-Butynediol

2717 133 Camphor

2717 133 Camphor, synthetic

2719 141 Barium bromate

2720 141 Chromium nitrate

2721 141 Copper chlorate

2722 140 Lithium nitrate

2723 140 Magnesium chlorate

2724 140 Manganese nitrate

2725 140 Nickel nitrate

2730 152 Nitroanisol

2732 152 Nitrobromo

2732 152 Nitrobromo

2732 152 Nitrobromo

2733 132 Alkylamine

2733 132 Amines, fla

n.o.s.

2733 132 Polyalkylam

2733 132 Polyamines

corrosive

2734 132 Alkylamine

2734 132 Amines, liq

flammab

2734 132 Polyalkylam

2734 132 Polyamines

flammab

2735 153 Alkylamine

2735 153 Amines, liq

2735 153 Polyalkylam

2735 153 Polyamines

n.o.s.

2738 153 N-Butylanil

2739 156 Butyric anh

2740 155 n-Propyl ch

2741 141 Barium hyp

than 22% 

2742 155 sec-Butyl c

2742 155 Chloroform

Numeric 27-96 Eng.pmd 3/25/064
2744 155 Cyclobutyl chloroformate

2745 157 Chloromethyl chloroformate

2746 156 Phenyl chloroformate

2747 156 tert-Butylcyclohexyl

chloroformate

2748 156 2-Ethylhexyl chloroformate

2749 130 Tetramethylsilane

2750 153 1,3-Dichloropropanol-2

2751 155 Diethylthiophosphoryl chloride

2752 127 1,2-Epoxy-3-ethoxypropane

2753 153 N-Ethylbenzyltoluidines

2753 153 N-Ethylbenzyltoluidines, liquid

2753 153 N-Ethylbenzyltoluidines, solid

2754 153 N-Ethyltoluidines

2757 151 Carbamate pesticide, solid,

poisonous

2757 151 Carbamate pesticide, solid, toxic

2758 131 Carbamate pesticide, liquid,

flammable, poisonous

2758 131 Carbamate pesticide, liquid,

flammable, toxic

2759 151 Arsenical pesticide, solid,

poisonous

2759 151 Arsenical pesticide, solid, toxic

2760 131 Arsenical pesticide, liquid,

flammable, poisonous

2760 131 Arsenical pesticide, liquid,

flammable, toxic

2762 131 Aldrin, 

2762 131 Organo

flamm

2762 131 Organo

flamm

2763 151 Triazin

poiso

2763 151 Triazin

2764 131 Triazin

flamm

2764 131 Triazin

flamm

2765 152 Phenox

poiso

2765 152 Phenox

2766 131 Phenox

flamm

2766 131 Phenox

flamm

2767 151 Phenyl 

poiso

2767 151 Phenyl 

toxic

2768 131 Phenyl 

flamm

2768 131 Phenyl 

flamm

2769 151 Benzoic 

solid

2769 151 Benzoic 

solid

Numeric 27-96 Eng.pmd 3/25/065
Page 66

solid, toxic

2771 151 Thiocarbamate pesticide, solid,

poisonous

2771 151 Thiocarbamate pesticide, solid,

toxic

2772 131 Dithiocarbamate pesticide,

liquid, flammable, poisonous

2772 131 Dithiocarbamate pesticide,

liquid, flammable, toxic

2772 131 Thiocarbamate pesticide, liquid,

flammable, poisonous

2772 131 Thiocarbamate pesticide, liquid,

flammable, toxic

2773 151 Phthalimide derivative pesticide,

solid, poisonous

2773 151 Phthalimide derivative pesticide,

solid, toxic

2774 131 Phthalimide derivative pesticide,

liquid, flammable, poisonous

2774 131 Phthalimide derivative pesticide,

liquid, flammable, toxic

2775 151 Copper based pesticide, solid,

poisonous

2775 151 Copper based pesticide, solid,

toxic

2776 131 Copper based pesticide, liquid,

flammable, poisonous

2776 131 Copper based pesticide, liquid,

flammable, toxic

2777 151 Mercury based pesticide, solid,

poisonous

pesticide

2779 153 Substituted 

pesticide

2780 131 Substituted 

pesticide

poisonou

2780 131 Substituted 

pesticide

toxic

2781 151 Bipyridilium 

poisonou

2781 151 Bipyridilium 

toxic

2782 131 Bipyridilium 

flammab

2782 131 Bipyridilium 

flammab

2783 152 Methyl para

2783 152 Organopho

solid, po

2783 152 Organopho

solid, tox

2783 152 Parathion

2783 152 Tetraethyl 

2784 131 Organopho

liquid, fla

2784 131 Organopho

liquid, fla

2785 152 4-Thiapent

2785 152 Thia-4-pen

Numeric 27-96 Eng.pmd 3/25/066
2788 153 Organotin compound, liquid, n.o.s.

2789 132 Acetic acid, glacial

2789 132 Acetic acid, solution, more than

80% acid

2790 153 Acetic acid, solution, more than

10% but not more than 80%

acid

2793 170 Ferrous metal borings,

shavings, turnings or cuttings

2794 154 Batteries, wet, filled with acid

2795 154 Batteries, wet, filled with alkali

2796 157 Battery fluid, acid

2796 157 Sulfuric acid, with not more than

51% acid

2796 157 Sulphuric acid, with not more

than 51% acid

2797 154 Battery fluid, alkali

2797 154 Battery fluid, alkali, with battery

2797 154 Battery fluid, alkali, with

electronic equipment or

actuating device

2798 137 Benzene phosphorus dichloride

2798 137 Phenylphosphorus dichloride

2799 137 Benzene phosphorus

thiodichloride

2799 137 Phenylphosphorus

thiodichloride

2800 154 Batteries, wet, non-spillable

2801 154 Dye, liquid, corrosive, n.o.s.

2807 171 Magnet

2809 172 Mercur

2809 172 Mercur

2810 153 Buzz

2810 153 BZ

2810 153 Compo

liquid 

2810 153 CS

2810 153 DC

2810 153 GA

2810 153 GB

2810 153 GD

2810 153 GF

2810 153 H

2810 153 HD

2810 153 HL

2810 153 HN-1

2810 153 HN-2

2810 153 HN-3

2810 153 L (Lewi

2810 153 Lewisit

2810 153 Mustard

2810 153 Mustard 

2810 153 Poison 

2810 153 Poisono

2810 153 Poisono

(Inha

Numeric 27-96 Eng.pmd 3/25/067
Page 68

2810 153 Sarin

2810 153 Soman

2810 153 Tabun

2810 153 Thickened GD

2810 153 Toxic liquid, n.o.s.

2810 153 Toxic liquid, n.o.s. (Inhalation

Hazard Zone A)

2810 153 Toxic liquid, n.o.s. (Inhalation

Hazard Zone B)

2810 153 Toxic liquid, organic, n.o.s.

2810 153 Toxic liquid, organic, n.o.s.

(Inhalation Hazard Zone A)

2810 153 Toxic liquid, organic, n.o.s.

(Inhalation Hazard Zone B)

2810 153 VX

2811 154 CX

2811 154 Poisonous solid, organic, n.o.s.

2811 154 Selenium oxide

2811 154 Toxic solid, organic, n.o.s.

2812 154 Sodium aluminate, solid

2813 138 Water-reactive solid, n.o.s.

2814 158 Infectious substance, affecting

humans

2815 153 N-Aminoethylpiperazine

2817 154 Ammonium bifluoride, solution

2817 154 Ammonium hydrogendifluoride,

solution

2817 154 Ammonium hydrogen fluoride,

solution

2822 153 2-Chloropy

2823 153 Crotonic ac

2823 153 Crotonic ac

2823 153 Crotonic ac

2826 155 Ethyl chloro

2829 153 Caproic ac

2829 153 Hexanoic a

2830 139 Lithium ferr

2831 160 1,1,1-Trich

2834 154 Phosphoro

2834 154 Phosphoro

2835 138 Sodium alu

2837 154 Bisulfates, 

2837 154 Bisulphates

2837 154 Sodium bis

2837 154 Sodium bis

2837 154 Sodium hyd

solution

2837 154 Sodium hyd

solution

2838 129P Vinyl butyra

2839 153 Aldol

2840 129 Butyraldox

2841 131 Di-n-amyla

2842 129 Nitroethane

2844 138 Calcium ma

2845 135 Ethyl phosp

anhydrou

Numeric 27-96 Eng.pmd 3/25/068
2850 128 Propylene tetramer

2851 157 Boron trifluoride, dihydrate

2852 113 Dipicryl sulfide, wetted with not

less than 10% water

2852 113 Dipicryl sulphide, wetted with

not less than 10% water

2853 151 Magnesium fluorosilicate

2853 151 Magnesium silicofluoride

2854 151 Ammonium fluorosilicate

2854 151 Ammonium silicofluoride

2855 151 Zinc fluorosilicate

2855 151 Zinc silicofluoride

2856 151 Fluorosilicates, n.o.s.

2856 151 Silicofluorides, n.o.s.

2857 126 Refrigerating machines,

containing Ammonia solutions

(UN2672)

2857 126 Refrigerating machines,

containing non-flammable,

non-poisonous gases

2857 126 Refrigerating machines,

containing non-flammable,

non-toxic gases

2858 170 Zirconium, dry, coiled wire,

finished metal sheets or strips

2859 154 Ammonium metavanadate

2861 151 Ammonium polyvanadate

2862 151 Vanadium pentoxide

2870 135 Alumin

devic

2871 170 Antimo

2872 159 Dibrom

2873 153 Dibutyl

2874 153 Furfury

2875 151 Hexach

2876 153 Resorc

2878 170 Titaniu

2878 170 Titaniu

2879 157 Seleniu

2880 140 Calcium 

with 

more 

2880 140 Calcium 

mixtu

5.5% 

wate

2881 135 Metal c

2881 135 Nickel c

2900 158 Infectio

anim

2901 124 Bromin

2902 151 Pesticid

n.o.s

2902 151 Pesticid

2903 131 Pesticid

flamm

2903 131 Pesticid

flamm

Numeric 27-96 Eng.pmd 3/25/069
Page 70

2907 133 Isosorbide dinitrate mixture

2908 161 Radioactive material, excepted

package, empty packaging

2909 161 Radioactive material, excepted

package, articles

manufactured from depleted

Uranium

2909 161 Radioactive material, excepted

package, articles

manufactured from natural

Thorium

2909 161 Radioactive material, excepted

package, articles

manufactured from natural

Uranium

2910 161 Radioactive material, excepted

package, articles

manufactured from depleted

Uranium

2910 161 Radioactive material, excepted

package, articles

manufactured from natural

Thorium

2910 161 Radioactive material, excepted

package, articles

manufactured from natural

Uranium

2910 161 Radioactive material, excepted

package, empty packaging

2910 161 Radioactive material, excepted

package, instruments or

articles

specific a

2912 162 Radioactive 

specific a

fissile or 

2913 162 Radioactive 

contamin

2913 162 Radioactive 

contamin

non fissi

2913 162 Radioactive 

contamin

II) non fis

excepted

2915 163 Radioactive 

package 

non fissi

2916 163 Radioactive 

package 

excepted

2917 163 Radioactive 

package 

excepted

2918 165 Radioactive 

n.o.s.

2919 163 Radioactive 

transpor

arrangem

fissile-ex

2920 132 Corrosive li

2920 132 Dichlorobu

2921 134 Corrosive s

Numeric 27-96 Eng.pmd 3/25/070
2924 132 Flammable liquid, corrosive, n.o.s

2925 134 Flammable solid, corrosive, n.o.s.

2925 134 Flammable solid, corrosive,

organic, n.o.s.

2926 134 Flammable solid, poisonous,

n.o.s.

2926 134 Flammable solid, poisonous,

organic, n.o.s.

2926 134 Flammable solid, toxic, organic,

n.o.s.

2927 154 Ethyl phosphonothioic

dichloride, anhydrous

2927 154 Ethyl phosphorodichloridate

2927 154 Poisonous liquid, corrosive,

n.o.s.

2927 154 Poisonous liquid, corrosive,

n.o.s. (Inhalation Hazard

Zone A)

2927 154 Poisonous liquid, corrosive,

n.o.s. (Inhalation Hazard

Zone B)

2927 154 Poisonous liquid, corrosive,

organic, n.o.s.

2927 154 Poisonous liquid, corrosive,

organic, n.o.s. (Inhalation

Hazard Zone A)

2927 154 Poisonous liquid, corrosive,

organic, n.o.s. (Inhalation

Hazard Zone B)

2927 154 Toxic liquid, corrosive, n.o.s.

n.o.s

Zone 

2927 154 Toxic li

n.o.s

Zone 

2928 154 Poisono

2928 154 Toxic s

n.o.s

2929 131 Poisono

n.o.s

2929 131 Poisono

n.o.s

Zone 

2929 131 Poisono

n.o.s

Zone 

2929 131 Poisono

orga

2929 131 Poisono

orga

Haza

2929 131 Poisono

orga

Haza

2929 131 Toxic li

2929 131 Toxic li

(Inha

2929 131 Toxic li

(Inha

2929 131 Toxic li

n.o.s

Numeric 27-96 Eng.pmd 3/25/071
Page 72

2930 134 Poisonous solid, flammable,

organic, n.o.s.

2930 134 Toxic solid, flammable, n.o.s.

2930 134 Toxic solid, flammable, organic,

n.o.s.

2931 151 Vanadyl sulfate

2931 151 Vanadyl sulphate

2933 129 Methyl 2-chloropropionate

2934 129 Isopropyl 2-chloropropionate

2935 129 Ethyl 2-chloropropionate

2936 153 Thiolactic acid

2937 153 alpha-Methylbenzyl alcohol

2937 153 alpha-Methylbenzyl alcohol,

liquid

2937 153 Methylbenzyl alcohol (alpha)

2938 152 Methyl benzoate

2940 135 Cyclooctadiene phosphines

2940 135 9-Phosphabicyclononanes

2941 153 Fluoroanilines

2942 153 2-Trifluoromethylaniline

2943 129 Tetrahydrofurfurylamine

2945 132 N-Methylbutylamine

2946 153 2-Amino-5-diethylaminopentane

2947 155 Isopropyl chloroacetate

2948 153 3-Trifluoromethylaniline

2949 154 Sodium hydrosulfide, with not

less than 25% water of

crystallization

2965 139 Boron triflu

etherate

2966 153 Thioglycol

2967 154 Sulfamic ac

2967 154 Sulphamic 

2968 135 Maneb, sta

2968 135 Maneb prep

2969 171 Castor bea

flake

2974 164 Radioactive 

form, n.o

2975 162 Thorium me

2976 162 Thorium nit

2977 166 Radioactive 

hexafluo

2977 166 Uranium he

containin

Uranium

2978 166 Radioactive 

hexafluo

2978 166 Uranium he

2978 166 Uranium he

or fissile

2979 162 Uranium m

2980 162 Uranyl nitra

solution

2981 162 Uranyl nitra

2982 163 Radioactive 

Numeric 27-96 Eng.pmd 3/25/072
solution, with not less than 8%

but less than 20% Hydrogen

peroxide

2985 155 Chlorosilanes, flammable,

corrosive, n.o.s.

2985 155 Chlorosilanes, n.o.s.

2986 155 Chlorosilanes, corrosive,

flammable, n.o.s.

2986 155 Chlorosilanes, n.o.s.

2987 156 Chlorosilanes, corrosive, n.o.s.

2987 156 Chlorosilanes, n.o.s.

2988 139 Chlorosilanes, n.o.s.

2988 139 Chlorosilanes, water-reactive,

flammable, corrosive, n.o.s.

2989 133 Lead phosphite, dibasic

2990 171 Life-saving appliances, selfinflating

2991 131 Carbamate pesticide, liquid,

poisonous, flammable

2991 131 Carbamate pesticide, liquid,

toxic, flammable

2992 151 Carbamate pesticide, liquid,

poisonous

2992 151 Carbamate pesticide, liquid,

toxic

2993 131 Arsenical pesticide, liquid,

poisonous, flammable

2993 131 Arsenical pesticide, liquid, toxic,

flammable

2994 151 Arsenical pesticide, liquid,

poisonous

2996 151 Organo

toxic

2997 131 Triazin

poiso

2997 131 Triazin

flamm

2998 151 Triazin

poiso

2998 151 Triazin

2999 131 Phenox

poiso

2999 131 Phenox

flamm

3000 152 Phenox

poiso

3000 152 Phenox

3001 131 Phenyl 

poiso

3001 131 Phenyl 

toxic

3002 151 Phenyl 

poiso

3002 151 Phenyl 

toxic

3003 131 Benzoic 

liquid

3003 131 Benzoic 

liquid

3004 151 Benzoic 

liquid

Numeric 27-96 Eng.pmd 3/25/073
Page 74

poisonous, flammable

3005 131 Thiocarbamate pesticide, liquid,

toxic, flammable

3006 151 Dithiocarbamate pesticide,

liquid, poisonous

3006 151 Dithiocarbamate pesticide,

liquid, toxic

3006 151 Thiocarbamate pesticide, liquid,

poisonous

3006 151 Thiocarbamate pesticide, liquid,

toxic

3007 131 Phthalimide derivative pesticide,

liquid, poisonous, flammable

3007 131 Phthalimide derivative pesticide,

liquid, toxic, flammable

3008 151 Phthalimide derivative pesticide,

liquid, poisonous

3008 151 Phthalimide derivative pesticide,

liquid, toxic

3009 131 Copper based pesticide, liquid,

poisonous, flammable

3009 131 Copper based pesticide, liquid,

toxic, flammable

3010 151 Copper based pesticide, liquid,

poisonous

3010 151 Copper based pesticide, liquid,

toxic

3011 131 Mercury based pesticide, liquid,

poisonous, flammable

3011 131 Mercury based pesticide, liquid,

toxic, flammable

3013 131 Substituted 

pesticide

flammab

3014 153 Substituted 

pesticide

3014 153 Substituted 

pesticide

3015 131 Bipyridilium 

poisonou

3015 131 Bipyridilium 

toxic, fla

3016 151 Bipyridilium 

poisonou

3016 151 Bipyridilium 

toxic

3017 131 Organopho

liquid, po

3017 131 Organopho

liquid, to

3018 152 Methyl para

3018 152 Organopho

liquid, po

3018 152 Organopho

liquid, to

3018 152 Tetraethyl 

3019 131 Organotin p

poisonou

3019 131 Organotin p

toxic, fla

3020 153 Organotin p

poisonou

Numeric 27-96 Eng.pmd 3/25/074
3023 131 2Methyl2heptanethiol

3023 131 tert-Octyl mercaptan

3024 131 Coumarin derivative pesticide,

liquid, flammable, poisonous

3024 131 Coumarin derivative pesticide,

liquid, flammable, toxic

3025 131 Coumarin derivative pesticide,

liquid, poisonous, flammable

3025 131 Coumarin derivative pesticide,

liquid, toxic, flammable

3026 151 Coumarin derivative pesticide,

liquid, poisonous

3026 151 Coumarin derivative pesticide,

liquid, toxic

3027 151 Coumarin derivative pesticide,

solid, poisonous

3027 151 Coumarin derivative pesticide,

solid, toxic

3028 154 Batteries, dry, containing

Potassium hydroxide solid

3048 157 Aluminum phosphide pesticide

3049 138 Metal alkyl halides, n.o.s.

3049 138 Metal alkyl halides, waterreactive, n.o.s.

3049 138 Metal aryl halides, n.o.s.

3049 138 Metal aryl halides, waterreactive, n.o.s.

3050 138 Metal alkyl hydrides, n.o.s.

3050 138 Metal alkyl hydrides, waterreactive, n.o.s.

3052 135 Alumin

3053 135 Magnes

3054 129 Cyclohe

3054 129 Cyclohe

3055 154 2-(2-Am

3056 129 n-Hepta

3057 125 Trifluor

3064 127 Nitrogly

alcoh

but n

Nitro

3065 127 Alcoho

3066 153 Paint (c

3066 153 Paint re

(corr

3070 126 Dichlor

Ethy

not m

oxide

3070 126 Dichlor

Ethy

not m

oxide

3070 126 Ethylen

Dich

mixtu

12.5% 

3070 126 Ethylen

Dich

mixtu

12% 

Numeric 27-96 Eng.pmd 3/25/075
Page 76

flammable, n.o.s.

3072 171 Life-saving appliances, not selfinflating

3073 131P Vinylpyridines, stabilized

3076 138 Aluminum alkyl hydrides

3077 171 Environmentally hazardous

substances, solid, n.o.s.

3077 171 Hazardous waste, solid, n.o.s.

3077 171 Other regulated substances,

solid, n.o.s.

3078 138 Cerium, turnings or gritty powder

3079 131P Methacrylonitrile, stabilized

3080 155 Isocyanate solution, poisonous,

flammable, n.o.s.

3080 155 Isocyanate solution, toxic,

flammable, n.o.s.

3080 155 Isocyanate solutions, n.o.s.

3080 155 Isocyanates, n.o.s.

3080 155 Isocyanates, poisonous,

flammable, n.o.s.

3080 155 Isocyanates, toxic, flammable,

n.o.s.

3082 171 Environmentally hazardous

substances, liquid, n.o.s.

3082 171 Hazardous waste, liquid, n.o.s.

3082 171 Other regulated substances,

liquid, n.o.s.

3083 124 Perchloryl fluoride

3088 135 Self-heatin

3089 170 Metal powd

3090 138 Lithium bat

3090 138 Lithium bat

cathode

3090 138 Lithium me

(includin

batteries

3091 138 Lithium bat

equipme

3091 138 Lithium bat

equipme

3091 138 Lithium me

containe

(includin

batteries

3091 138 Lithium me

with equ

lithium a

3092 129 1-Methoxy-

3093 140 Corrosive li

3094 138 Corrosive l

n.o.s.

3094 138 Corrosive l

contact w

flammab

3095 136 Corrosive s

n.o.s.

3096 138 Corrosive s

n.o.s.

Numeric 27-96 Eng.pmd 3/25/076
3099 142 Oxidizing liquid, toxic, n.o.s.

3100 135 Oxidizing solid, self-heating,

n.o.s.

3101 146 Organic peroxide type B, liquid

3102 146 Organic peroxide type B, solid

3103 146 Organic peroxide type C, liquid

3104 146 Organic peroxide type C, solid

3105 145 Organic peroxide type D, liquid

3106 145 Organic peroxide type D, solid

3107 145 Organic peroxide type E, liquid

3108 145 Organic peroxide type E, solid

3109 145 Organic peroxide type F, liquid

3110 145 Organic peroxide type F, solid

3111 148 Organic peroxide type B, liquid,

temperature controlled

3112 148 Organic peroxide type B, solid,

temperature controlled

3113 148 Organic peroxide type C, liquid,

temperature controlled

3114 148 Organic peroxide type C, solid,

temperature controlled

3115 148 Organic peroxide type D, liquid,

temperature controlled

3116 148 Organic peroxide type D, solid,

temperature controlled

3117 148 Organic peroxide type E, liquid,

temperature controlled

3118 148 Organic peroxide type E, solid,

temperature controlled

n.o.s

3122 142 Poisono

n.o.s

Zone 

3122 142 Poisono

n.o.s

Zone 

3122 142 Toxic li

3122 142 Toxic li

(Inha

3122 142 Toxic li

(Inha

3123 139 Poisono

react

3123 139 Poisono

react

Haza

3123 139 Poisono

react

Haza

3123 139 Poisono

conta

flamm

3123 139 Poisono

conta

flamm

(Inha

3123 139 Poisono

conta

flamm

(Inha

Numeric 27-96 Eng.pmd 3/25/077
Page 78

Zone B)

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s.

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone A)

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone B)

3124 136 Poisonous solid, self-heating,

n.o.s.

3124 136 Toxic solid, self-heating, n.o.s.

3125 139 Poisonous solid, water-reactive,

n.o.s.

3125 139 Poisonous solid, which in

contact with water emits

flammable gases, n.o.s.

3125 139 Toxic solid, water-reactive,

n.o.s.

3125 139 Toxic solid, which in contact with

water emits flammable gases,

n.o.s.

3126 136 Self-heating solid, corrosive,

organic, n.o.s.

3127 135 Self-heating solid, oxidizing,

n.o.s.

3128 136 Self-heating solid, poisonous,

organic, n.o.s.

n.o.s.

3131 138 Water-reac

n.o.s.

3132 138 Water-reac

n.o.s.

3133 138 Water-reac

n.o.s.

3134 139 Water-reac

n.o.s.

3134 139 Water-react

3135 138 Water-reac

heating, 

3136 120 Trifluorome

liquid

3137 140 Oxidizing s

3138 115 Acetylene, 

Propylen

refrigera

at least 7

not more 

Acetylen

6% Propy

3138 115 Ethylene, A

Propylen

refrigera

at least 7

not more 

Acetylen

6% Propy

Numeric 27-96 Eng.pmd 3/25/078
g q, 

3140 151 Alkaloids, liquid, n.o.s.

(poisonous)

3140 151 Alkaloid salts, liquid, n.o.s.

(poisonous)

3141 157 Antimony compound, inorganic,

liquid, n.o.s.

3142 151 Disinfectant, liquid, poisonous,

n.o.s.

3142 151 Disinfectant, liquid, toxic, n.o.s.

3142 151 Disinfectants, liquid, n.o.s.

(poisonous)

3143 151 Dye, solid, poisonous, n.o.s.

3143 151 Dye, solid, toxic, n.o.s.

3143 151 Dye intermediate, solid,

poisonous, n.o.s.

3143 151 Dye intermediate, solid, toxic,

n.o.s.

3144 151 Nicotine compound, liquid,

n.o.s.

3144 151 Nicotine preparation, liquid,

n.o.s.

3145 153 Alkyl phenols, liquid, n.o.s.

(including C2-C12

homologues)

3146 153 Organotin compound, solid,

n.o.s.

3147 154 Dye, solid, corrosive, n.o.s.

3147 154 Dye intermediate, solid,

corrosive, n.o.s.

3148 138 Water-reactive liquid, n.o.s.

3150 115 Hydroc

devic

3151 171 Polyha

liquid

3151 171 Polyha

liquid

3152 171 Polyha

solid

3152 171 Polyha

solid

3153 115 Perfluo

3153 115 Perfluo

3154 115 Perfluo

3154 115 Perfluo

3155 154 Pentac

3156 122 Compre

n.o.s

3157 122 Liquefie

3158 120 Gas, re

3159 126 Refrige

3159 126 1,1,1,2

3160 119 Liquefie

flamm

3160 119 Liquefie

flamm

Haza

3160 119 Liquefie

flamm

Haza

Numeric 27-96 Eng.pmd 3/25/079
Page 80

n.o.s.

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone A)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone B)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone C)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone D)

3161 115 Liquefied gas, flammable, n.o.s.

3162 123 Liquefied gas, poisonous, n.o.s.

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone A)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone B)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone C)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone D)

3162 123 Liquefied gas, toxic, n.o.s.

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone A)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone B)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone C)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone D)

3165 131 Aircraft hyd

tank

3166 128 Engines, in

flammab

3166 128 Engines, in

flammab

3166 128 Engines, in

including 

machine

3166 128 Vehicle, fla

3166 128 Vehicle, fla

powered

3167 115 Gas sample

flammab

refrigera

3168 119 Gas sample

poisonou

not refrig

3168 119 Gas sample

toxic, fla

refrigera

3169 123 Gas sample

poisonou

refrigera

3169 123 Gas sample

toxic, n.o

liquid

3170 138 Aluminum d

3170 138 Aluminum p

by-produ

3170 138 Aluminum r

Numeric 27-96 Eng.pmd 3/25/080
3172 153 Toxins, extracted from living

sources, liquid, n.o.s.

3172 153 Toxins, extracted from living

sources, n.o.s.

3172 153 Toxins, extracted from living

sources, solid, n.o.s.

3174 135 Titanium disulfide

3174 135 Titanium disulphide

3175 133 Solids containing flammable

liquid, n.o.s.

3176 133 Flammable solid, organic,

molten, n.o.s.

3178 133 Flammable solid, inorganic, n.o.s.

3178 133 Smokeless powder for small

arms

3179 134 Flammable solid, poisonous,

inorganic, n.o.s.

3179 134 Flammable solid, toxic,

inorganic, n.o.s.

3180 134 Flammable solid, corrosive,

inorganic, n.o.s.

3180 134 Flammable solid, inorganic,

corrosive, n.o.s.

3181 133 Metal salts of organic

compounds, flammable, n.o.s.

3182 170 Metal hydrides, flammable, n.o.s.

3183 135 Self-heating liquid, organic, n.o.s.

3184 136 Self-heating liquid, poisonous,

organic, n.o.s.

inorg

3187 136 Self-he

inorg

3188 136 Self-he

inorg

3189 135 Metal p

3189 135 Self-he

3190 135 Self-he

n.o.s

3191 136 Self-he

poiso

3191 136 Self-he

toxic

3191 136 Self-he

inorg

3191 136 Self-he

inorg

3192 136 Self-he

inorg

3194 135 Pyropho

3200 135 Pyropho

3203 135 Pyroph

comp

3203 135 Pyroph

comp

n.o.s

3205 135 Alkaline 

n.o.s

3206 136 Alkali m

heati

Numeric 27-96 Eng.pmd 3/25/081
Page 82

solution, water-reactive,

flammable, n.o.s.

3208 138 Metallic substance, waterreactive, n.o.s.

3209 138 Metallic substance, waterreactive, self-heating, n.o.s.

3210 140 Chlorates, inorganic, aqueous

solution, n.o.s.

3211 140 Perchlorates, inorganic,

aqueous solution, n.o.s.

3212 140 Hypochlorites, inorganic, n.o.s.

3213 140 Bromates, inorganic, aqueous

solution, n.o.s.

3214 140 Permanganates, inorganic,

aqueous solution, n.o.s.

3215 140 Persulfates, inorganic, n.o.s.

3215 140 Persulphates, inorganic, n.o.s.

3216 140 Persulfates, inorganic, aqueous

solution, n.o.s.

3216 140 Persulphates, inorganic,

aqueous solution, n.o.s.

3217 140 Percarbonates, inorganic, n.o.s.

3218 140 Nitrates, inorganic, aqueous

solution, n.o.s.

3219 140 Nitrites, inorganic, aqueous

solution, n.o.s.

3220 126 Pentafluoroethane

3220 126 Refrigerant gas R-125

3221 149 Self-reactive liquid type B

3222 149 Self-reactive solid type B

3229 149 Self-reactiv

3230 149 Self-reactiv

3231 150 Self-reactiv

temperat

3232 150 Self-reactiv

temperat

3233 150 Self-reactiv

temperat

3234 150 Self-reactiv

temperat

3235 150 Self-reactiv

temperat

3236 150 Self-reactiv

temperat

3237 150 Self-reactiv

temperat

3238 150 Self-reactiv

temperat

3239 150 Self-reactiv

temperat

3240 150 Self-reactiv

temperat

3241 133 2-Bromo-2-

3-diol

3242 149 Azodicarbo

3243 151 Solids cont

liquid, n.

3243 151 Solids cont

n.o.s.

3244 154 Solids cont

liquid, n.

Numeric 27-96 Eng.pmd 3/25/082
anhydrous

3248 131 Medicine, liquid, flammable,

poisonous, n.o.s.

3248 131 Medicine, liquid, flammable,

toxic, n.o.s.

3249 151 Medicine, solid, poisonous, n.o.s.

3249 151 Medicine, solid, toxic, n.o.s.

3250 153 Chloroacetic acid, molten

3251 133 Isosorbide-5-mononitrate

3252 115 Difluoromethane

3252 115 Refrigerant gas R-32

3253 154 Disodium trioxosilicate

3253 154 Disodium trioxosilicate,

pentahydrate

3254 135 Tributylphosphane

3254 135 Tributylphosphine

3255 135 tert-Butyl hypochlorite

3256 128 Elevated temperature liquid,

flammable, n.o.s., with flash

point above 37.8°C (100°F),

at or above its flash point

3256 128 Elevated temperature liquid,

flammable, n.o.s., with flash

point above 60.5°C (141°F),

at or above its flash point

3257 128 Elevated temperature liquid,

n.o.s., at or above 100°C

(212°F), and below its flash

point

3261 154 Corrosi

n.o.s

3262 154 Corrosi

inorg

3263 154 Corrosi

n.o.s

3264 154 Corrosi

inorg

3265 153 Corrosi

n.o.s

3266 154 Corrosi

inorg

3267 153 Corrosi

n.o.s

3268 171 Air bag 

3268 171 Air bag 

3268 171 Air bag 

3268 171 Air bag 

3268 171 Seat-be

3268 171 Seat-be

3268 171 Seat-be

pyrot

3269 128 Polyest

3270 133 Nitroce

3271 127 Ethers, 

3272 127 Esters, 

3273 131 Nitriles

n.o.s

Numeric 27-96 Eng.pmd 3/25/083
Page 84

3276 151 Nitriles, poisonous, liquid,

n.o.s.

3276 151 Nitriles, poisonous, n.o.s.

3276 151 Nitriles, toxic, liquid, n.o.s.

3276 151 Nitriles, toxic, n.o.s.

3277 154 Chloroformates, poisonous,

corrosive, n.o.s.

3277 154 Chloroformates, toxic,

corrosive, n.o.s.

3278 151 Organophosphorus compound,

poisonous, liquid, n.o.s.

3278 151 Organophosphorus compound,

poisonous, n.o.s.

3278 151 Organophosphorus compound,

toxic, liquid, n.o.s.

3278 151 Organophosphorus compound,

toxic, n.o.s.

3279 131 Organophosphorus compound,

poisonous, flammable, n.o.s.

3279 131 Organophosphorus compound,

toxic, flammable, n.o.s.

3280 151 Organoarsenic compound,

liquid, n.o.s.

3280 151 Organoarsenic compound, n.o.s.

3281 151 Metal carbonyls, liquid, n.o.s.

3281 151 Metal carbonyls, n.o.s.

3282 151 Organometallic compound,

poisonous, liquid, n.o.s.

3282 151 Organometallic compound,

poisonous, n.o.s.

3284 151 Tellurium c

3285 151 Vanadium c

3286 131 Flammable 

corrosive

3286 131 Flammable 

corrosive

3287 151 Poisonous 

n.o.s.

3287 151 Poisonous 

n.o.s. (In

Zone A)

3287 151 Poisonous 

n.o.s. (In

Zone B)

3287 151 Toxic liquid

3287 151 Toxic liquid

(Inhalati

3287 151 Toxic liquid

(Inhalati

3288 151 Poisonous 

n.o.s.

3288 151 Toxic solid

3289 154 Poisonous 

inorganic

3289 154 Poisonous 

inorganic

Hazard Z

3289 154 Poisonous 

inorganic

Hazard Z

Numeric 27-96 Eng.pmd 3/25/084
Hazard Zone B)

3290 154 Poisonous solid, corrosive,

inorganic, n.o.s.

3290 154 Toxic solid, corrosive, inorganic,

n.o.s.

3291 158 (Bio)Medical waste, n.o.s.

3291 158 Clinical waste, unspecified,

n.o.s.

3291 158 Medical waste, n.o.s.

3291 158 Regulated medical waste, n.o.s.

3292 138 Batteries, containing Sodium

3292 138 Cells, containing Sodium

3293 152 Hydrazine, aqueous solution,

with not more than 37%

Hydrazine

3294 131 Hydrogen cyanide, solution in

alcohol, with not more than

45% Hydrogen cyanide

3295 128 Hydrocarbons, liquid, n.o.s.

3296 126 Heptafluoropropane

3296 126 Refrigerant gas R-227

3297 126 Chlorotetrafluoroethane and

Ethylene oxide mixture, with

not more than 8.8% Ethylene

oxide

3297 126 Ethylene oxide and

Chlorotetrafluoroethane

mixture, with not more than

8.8% Ethylene oxide

3299 126 Ethylen

Tetra

with 

Ethy

3299 126 Tetraflu

oxide 

than 

3300 119P Carbon 

oxide 

87% 

3300 119P Ethylen

dioxi

than 

3301 136 Corrosi

n.o.s

3302 152 2-Dime

3303 124 Compre

oxidi

3303 124 Compre

oxidi

Haza

3303 124 Compre

oxidi

Haza

3303 124 Compre

oxidi

Haza

3303 124 Compre

oxidi

Haza

3303 124 Compre

oxidi

Numeric 27-96 Eng.pmd 3/25/085
Page 86

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3303 124 Compressed gas, toxic,

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s.

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3304 123 Compressed gas, toxic,

corrosive, n.o.s.

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

(Inhalati

3305 119 Compresse

flammab

(Inhalati

3305 119 Compresse

flammab

(Inhalati

3305 119 Compresse

flammab

3305 119 Compresse

flammab

(Inhalati

3305 119 Compresse

flammab

(Inhalati

3305 119 Compresse

flammab

(Inhalati

3305 119 Compresse

flammab

(Inhalati

3306 124 Compresse

oxidizing

3306 124 Compresse

oxidizing

(Inhalati

3306 124 Compresse

oxidizing

(Inhalati

3306 124 Compresse

oxidizing

(Inhalati

Numeric 27-96 Eng.pmd 3/25/086
(Inhalation Hazard Zone A)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s.

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s.

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone A)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone B)

corro

3308 123 Liquefie

corro

Haza

3308 123 Liquefie

corro

Haza

3308 123 Liquefie

corro

Haza

3308 123 Liquefie

corro

Haza

3308 123 Liquefie

n.o.s

3308 123 Liquefie

n.o.s

Zone 

3308 123 Liquefie

n.o.s

Zone 

3308 123 Liquefie

n.o.s

Zone 

3308 123 Liquefie

n.o.s

Zone 

3309 119 Liquefie

flamm

3309 119 Liquefie

flamm

(Inha

Numeric 27-96 Eng.pmd 3/25/087
Page 88

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s.

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s.

corrosive

Hazard Z

3310 124 Liquefied g

corrosive

Hazard Z

3311 122 Gas, refrige

oxidizing

3312 115 Gas, refrige

flammab

3313 135 Organic pig

3314 171 Plastic mol

3314 171 Plastics mo

3315 151 Chemical s

3315 151 Chemical s

liquid

3315 151 Chemical s

solid

3315 151 Chemical s

3315 151 Chemical s

3315 151 Chemical s

3316 171 Chemical k

3316 171 First aid kit

3317 113 2-Amino-4,

wetted w

water

3318 125 Ammonia s

than 50% 

3319 113 Nitroglycer

desensit

with mor

more tha

Numeric 27-96 Eng.pmd 3/25/088
y

than 40% Sodium hydroxide

3321 162 Radioactive material, low

specific activity (LSA-II) non

fissile or fissile-excepted

3322 162 Radioactive material, low

specific activity (LSA-III) non

fissile or fissile-excepted

3323 163 Radioactive material, Type C

package

3324 165 Radioactive material, low specific

activity (LSA-II), fissile

3325 165 Radioactive material, low specific

activity (LSA-III), fissile

3326 165 Radioactive material, surface

contaminated objects (SCO-I),

fissile

3326 165 Radioactive material, surface

contaminated objects (SCO-II),

fissile

3327 165 Radioactive material, Type A

package, fissile, non-special

form

3328 165 Radioactive material, Type B(U)

package, fissile

3329 165 Radioactive material, Type B(M)

package, fissile

3330 165 Radioactive material, Type C

package, fissile

3331 165 Radioactive material,

transported under special

arrangement, fissile

3334 171 Self-de

press

3335 171 Aviatio

3336 130 Mercap

flamm

3336 130 Mercap

n.o.s

3337 126 Refrige

3338 126 Refrige

3339 126 Refrige

3340 126 Refrige

3341 135 Thioure

3342 135 Xantha

3343 113 Nitrogly

dese

flamm

more 

3344 113 Pentae

mixtu

n.o.s

not m

3344 113 Pentae

mixtu

n.o.s

not m

3344 113 PETN m

solid

10% 

PETN

3345 153 Phenox

pesti

Numeric 27-96 Eng.pmd 3/25/089
Page 90

toxic

3347 131 Phenoxyacetic acid derivative

pesticide, liquid, poisonous,

flammable

3347 131 Phenoxyacetic acid derivative

pesticide, liquid, toxic,

flammable

3348 153 Phenoxyacetic acid derivative

pesticide, liquid, poisonous

3348 153 Phenoxyacetic acid derivative

pesticide, liquid, toxic

3349 151 Pyrethroid pesticide, solid,

poisonous

3349 151 Pyrethroid pesticide, solid, toxic

3350 131 Pyrethroid pesticide, liquid,

flammable, poisonous

3350 131 Pyrethroid pesticide, liquid,

flammable, toxic

3351 131 Pyrethroid pesticide, liquid,

poisonous, flammable

3351 131 Pyrethroid pesticide, liquid,

toxic, flammable

3352 151 Pyrethroid pesticide, liquid,

poisonous

3352 151 Pyrethroid pesticide, liquid, toxic

3353 126 Air bag inflators, compressed gas

3353 126 Air bag modules, compressed gas

3353 126 Seat-belt pre-tensioners,

compressed gas

3354 115 Insecticide gas, flammable, n.o.s.

Hazard Z

3355 119 Insecticide 

flammab

Hazard Z

3355 119 Insecticide 

flammab

Hazard Z

3355 119 Insecticide 

flammab

3355 119 Insecticide 

flammab

Hazard Z

3355 119 Insecticide 

flammab

Hazard Z

3355 119 Insecticide 

flammab

Hazard Z

3355 119 Insecticide 

flammab

Hazard Z

3356 140 Oxygen gen

3356 140 Oxygen gen

spent

3357 113 Nitroglycer

desensit

with not m

Nitroglyc

3358 115 Refrigerati

containin

poisonou

Numeric 27-96 Eng.pmd 3/25/090
3361 156 Chlorosilanes, poisonous,

corrosive, n.o.s.

3361 156 Chlorosilanes, toxic, corrosive,

n.o.s.

3362 155 Chlorosilanes, poisonous,

corrosive, flammable, n.o.s.

3362 155 Chlorosilanes, toxic, corrosive,

flammable, n.o.s.

3363 171 Dangerous goods in apparatus

3363 171 Dangerous goods in machinery

3364 113 Picric acid, wetted with not less

than 10% water

3364 113 Trinitrophenol, wetted with not

less than 10% water

3365 113 Picryl chloride, wetted with not

less than 10% water

3365 113 Trinitrochlorobenzene, wetted

with not less than 10% water

3366 113 TNT, wetted with not less than

10% water

3366 113 Trinitrotoluene, wetted with not

less than 10% water

3367 113 Trinitrobenzene, wetted with not

less than 10% water

3368 113 Trinitrobenzoic acid, wetted with

not less than 10% water

3369 113 Sodium dinitro-o-cresolate,

wetted with not less than 10%

water

3370 113 Urea nitrate, wetted with not less

than 10% water

3373 158 Diagno

3374 116 Acetyle

3375 140 Ammon

3375 140 Ammon

3375 140 Ammon

3376 113 4-Nitro

less 

3377 140 Sodium 

3378 140 Sodium 

perox

3379 128 Desens

n.o.s

3380 133 Desens

n.o.s

3381 151 Poisono

n.o.s

Zone 

3381 151 Toxic b

(Inha

3382 151 Poisono

n.o.s

Zone 

3382 151 Toxic b

(Inha

3383 131 Poisono

flamm

Haza

3383 131 Toxic b

flamm

Haza

Numeric 27-96 Eng.pmd 3/25/091
Page 92

water-reactive, n.o.s.

(Inhalation Hazard Zone A)

3385 139 Toxic by inhalation liquid, waterreactive, n.o.s. (Inhalation

Hazard Zone A)

3386 139 Poisonous by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

3386 139 Toxic by inhalation liquid, waterreactive, n.o.s. (Inhalation

Hazard Zone B)

3387 142 Poisonous by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3387 142 Toxic by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3388 142 Poisonous by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3388 142 Toxic by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3389 154 Poisonous by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3389 154 Toxic by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3390 154 Poisonous by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3393 135 Organomet

solid, py

reactive

3394 135 Organomet

liquid, py

reactive

3395 135 Organomet

solid, wa

3396 138 Organomet

solid, wa

flammab

3397 138 Organomet

solid, wa

heating

3398 135 Organomet

liquid, wa

3399 138 Organomet

liquid, wa

flammab

3400 138 Organomet

solid, se

3401 138 Alkali meta

3402 138 Alkaline ea

solid

3403 138 Potassium, 

3404 138 Potassium 

3404 138 Sodium pot

3405 141 Barium chlo

3406 141 Barium per

3407 140 Chlorate an

chloride 

Numeric 27-96 Eng.pmd 3/25/092
3411 153 betaNaphthylamine, solution

3411 153 Naphthylamine (beta), solution

3412 153 Formic acid, with not less than

5% but less than 10% acid

3412 153 Formic acid, with not less than

10% but not more than 85%

acid

3413 157 Potassium cyanide, solution

3414 157 Sodium cyanide, solution

3415 154 Sodium fluoride, solution

3416 153 Chloroacetophenone, liquid

3417 152 Xylyl bromide, solid

3418 151 2,4-Toluylenediamine, solution

3419 157 Boron trifluoride acetic acid

complex, solid

3420 157 Boron trifluoride propionic acid

complex, solid

3421 154 Potassium hydrogen difluoride,

solution

3422 154 Potassium fluoride, solution

3423 153 Tetramethylammonium

hydroxide, solid

3424 141 Ammonium dinitro-o-cresolate,

solution

3425 156 Bromoacetic acid, solid

3426 153P Acrylamide, solution

3427 153 Chlorobenzyl chlorides, solid

3428 156 3-Chloro-4-methylphenyl

isocyanate, solid

3429 153 Chlorotoluidines, liquid

3436 151 Hexaflu

solid

3437 152 Chloroc

3438 153 alpha-M

solid

3439 151 Nitriles

3439 151 Nitriles

3440 151 Seleniu

n.o.s

3441 153 Chlorod

3442 153 Dichlor

3443 152 Dinitrob

3444 151 Nicotin

3445 151 Nicotin

3445 151 Nicotin

3446 152 Nitrotol

3447 152 Nitroxy

3448 159 Tear ga

3449 159 Bromob

3450 151 Diphen

3451 153 Toluidin

3452 153 Xylidine

3453 154 Phosph

3454 152 Dinitrot

3455 153 Cresols

3456 157 Nitrosy

3456 157 Nitrosy

Numeric 27-96 Eng.pmd 3/25/093
Page 94

sources, solid, n.o.s.

3463 132 Propionic acid, with not less

than 90% acid

3464 151 Organophosphorus compound,

poisonous, solid, n.o.s.

3464 151 Organophosphorus compound,

toxic, solid, n.o.s.

3465 151 Organoarsenic compound, solid,

n.o.s.

3466 151 Metal carbonyls, solid, n.o.s.

3467 151 Organometallic compound,

poisonous, solid, n.o.s.

3467 151 Organometallic compound,

toxic, solid, n.o.s.

3468 115 Hydrogen in a metal hydride

storage system

3468 115 Hydrogen in a metal hydride

storage system contained in

equipment

3468 115 Hydrogen in a metal hydride

storage system packed with

equipment

3469 132 Paint, flammable, corrosive

3469 132 Paint related material,

flammable, corrosive

3470 132 Paint, corrosive, flammable

3470 132 Paint related material,

corrosive, flammable

3471 154 Hydrogendifluorides, solution,

n.o.s.

equipme

flammab

3474 113 1-Hydroxyb

anhydrou

less than 

3475 127 Ethanol and 

with mor

3475 127 Ethanol and 

with mor

3475 127 Ethanol and 

more tha

3475 127 Gasoline a

with mor

3475 127 Motor spirit 

with mor

3475 127 Petrol and 

more tha

3476 138 Fuel cell ca

equipme

reactive 

3476 138 Fuel cell ca

water-re

3476 138 Fuel cell ca

equipme

reactive 

3477 153 Fuel cell ca

equipme

corrosive 

3477 153 Fuel cell ca

corrosive 

Numeric 27-96 Eng.pmd 3/25/094
liquefied flammable gas

3478 115 Fuel cell cartridges packed with

equipment, containing

liquefied flammable gas

3479 115 Fuel cell cartridges contained in

equipment, containing

hydrogen in metal hydride

3479 115 Fuel cell cartridges, containing

hydrogen in metal hydride

3479 115 Fuel cell cartridges packed with

equipment, containing

hydrogen in metal hydride

3480 147 Lithium ion batteries (including

lithium ion polymer batteries)

3481 147 Lithium ion batteries contained

in equipment (including

lithium ion polymer batteries)

3481 147 Lithium ion batteries packed with

equipment (including lithium

ion polymer batteries)

8000 171 Consumer commodity

8013 171 Gas generator assemblies

8038 171 Heat producing article

9035 123 Gas identification set

9163 171 Zirconium sulfate

9163 171 Zirconium sulphate

9191 143 Chlorine dioxide, hydrate, frozen

9192 167 Fluorine, refrigerated liquid

(cryogenic liquid)

9195 135 Metal alkyl, solution, n.o.s.

triflu

9269 132 Trimeth

9279 115 Hydrog

hydri

Numeric 27-96 Eng.pmd 3/25/095
Note: If an entry is highlighted in green in either the yellow-bordered 

pages AND THERE IS NO FIRE, go directly to Table 1 - Initial Isola

Action Distances (green bordered pages) and look up the ID nu

material to obtain initial isolation and protective action distance

FIRE, or IF A FIRE IS INVOLVED, ALSO CONSULT the assign

bordered pages) and apply as appropriate the evacuation inform

PUBLIC SAFETY. Please remember that, if the name in Table 

(when spilled in water), and the material has not been spilled in w

not apply and safety distances can be found within the appropri

Page 96

Numeric 27-96 Eng.pmd 3/25/096
y

Acetic acid, glacial 132 2789

Acetic acid, solution, more than 153 2790

10% but not more than 80%

acid

Acetic acid, solution, more than 132 2789

80% acid

Acetic anhydride 137 1715

Acetone 127 1090

Acetone cyanohydrin, stabilized 155 1541

Acetone oils 127 1091

Acetonitrile 127 1648

Acetyl bromide 156 1716

Acetyl chloride 155 1717

Acetylene 116 1001

Acetylene, dissolved 116 1001

Acetylene, solvent free 116 3374

Acetylene, Ethylene and 115 3138

Propylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

Acetylene tetrabromide 159 2504

Acetyl iodide 156 1898

Acetyl methyl carbinol 127 2621

Acid, sludge 153 1906

Acid butyl phosphate 153 1718

Acridine 153 2713

Acrolein, stabilized 131P 1092

Acrolein dimer, stabilized 129P 2607

Adhesives (flamma

Adiponitrile 

Aerosol dispensers 

Aerosols 

Air, compressed 

Air, refrigerated liq

(cryogenic liquid)

Air, refrigerated liqu

(cryogenic liquid)

pressurized

Air bag inflators 

Air bag inflators, com

Air bag inflators, py

Air bag modules 

Air bag modules, com

Air bag modules, py

Aircraft hydraulic po

tank

Alcoholates solutio

alcohol

Alcoholic beverage

Alcohols, flammable

n.o.s.

Alcohols, flammabl

n.o.s.

Alcohols, n.o.s. 

Alcohols, poisonou

Alcohols, toxic, n.o

Aldehydes, flamma

poisonous, n.o.s.

Alpha 97-166 Eng.pmd 3/25/097
Page 98

Aldrin, liquid 131 2762

Aldrin, solid 151 2761

Alkali metal alcoholates, self- 136 3206

heating, corrosive, n.o.s.

Alkali metal alloy, liquid, n.o.s. 138 1421

Alkali metal amalgam 138 1389

Alkali metal amalgam, liquid 138 1389

Alkali metal amalgam, solid 138 1389

Alkali metal amalgam, solid 138 3401

Alkali metal amides 139 1390

Alkali metal dispersion 138 1391

Alkaline earth metal 135 3205

alcoholates, n.o.s.

Alkaline earth metal alloy, n.o.s. 138 1393

Alkaline earth metal amalgam 138 1392

Alkaline earth metal amalgam, 138 1392

liquid

Alkaline earth metal amalgam, 138 3402

solid

Alkaline earth metal dispersion 138 1391

Alkaloids, liquid, n.o.s. 151 3140

(poisonous)

Alkaloids, solid, n.o.s. 151 1544

(poisonous)

Alkaloid salts, liquid, n.o.s. 151 3140

(poisonous)

Alkaloid salts, solid, n.o.s. 151 1544

(poisonous)

Alkylamines, n.o.s. 132 2733

homologues)

Alkyl sulfonic acids, liq

more than 5% free Su

acid

Alkyl sulfonic acids, liq

not more than 5% free 

acid

Alkyl sulfonic acids, so

more than 5% free Su

acid

Alkyl sulfonic acids, so

not more than 5% free 

acid

Alkylsulfuric acids 

Alkyl sulphonic acids, l

with more than 5% fre

Sulphuric acid

Alkyl sulphonic acids, l

with not more than 5% 

Sulphuric acid

Alkyl sulphonic acids, s

more than 5% free Su

acid

Alkyl sulphonic acids, s

not more than 5% free

Sulphuric acid

Alkylsulphuric acids 

Allyl acetate 

Allyl alcohol 

Allylamine 

Allyl bromide 

Alpha 97-166 Eng.pmd 3/25/098
Allyl iodide 132 1723

Allyl isothiocyanate, stabilized 155 1545

Allyltrichlorosilane, stabilized 155 1724

Aluminum, molten 169 9260

Aluminum alkyl halides 135 3052

Aluminum alkyl halides, liquid 135 3052

Aluminum alkyl halides, solid 135 3052

Aluminum alkyl halides, solid 135 3461

Aluminum alkyl hydrides 138 3076

Aluminum alkyls 135 3051

Aluminum borohydride 135 2870

Aluminum borohydride in 135 2870

devices

Aluminum bromide, anhydrous 137 1725

Aluminum bromide, solution 154 2580

Aluminum carbide 138 1394

Aluminum chloride, anhydrous 137 1726

Aluminum chloride, solution 154 2581

Aluminum dross 138 3170

Aluminum ferrosilicon powder 139 1395

Aluminum hydride 138 2463

Aluminum nitrate 140 1438

Aluminum phosphide 139 1397

Aluminum phosphide pesticide 157 3048

Aluminum powder, coated 170 1309

Aluminum powder, pyrophoric 135 1383

Aluminum powder, uncoated 138 1396

Aluminum smelting 

Amines, flammable

n.o.s.

Amines, liquid, corr

flammable, n.o.s.

Amines, liquid, corr

Amines, solid, corr

2-Amino-4-chloroph

2-Amino-5-diethylam

2-Amino-4,6-dinitrop

wetted with not le

water

2-(2-Aminoethoxy)e

N-Aminoethylpipera

Aminophenols 

Aminopyridines 

Ammonia, anhydrou

Ammonia, solution, 

than 10% but not 

35% Ammonia

Ammonia, solution, 

than 35% but not 

50% Ammonia

Ammonia solution, 

than 50% Ammon

Ammonium arsenat

Ammonium bifluorid

Ammonium bifluorid

Ammonium dichrom

Ammonium dinitro-

Alpha 97-166 Eng.pmd 3/25/099
Page 100

Ammonium hydrogendifluoride, 154 1727

solid

Ammonium hydrogendifluoride, 154 2817

solution

Ammonium hydrogen fluoride, 154 1727

solid

Ammonium hydrogen fluoride, 154 2817

solution

Ammonium hydrogen sulfate 154 2506

Ammonium hydrogen sulphate 154 2506

Ammonium hydroxide 154 2672

Ammonium hydroxide, with more 154 2672

than 10% but not more than

35% Ammonia

Ammonium metavanadate 154 2859

Ammonium nitrate, liquid (hot 140 2426

concentrated solution)

Ammonium nitrate, with not more 140 1942

than 0.2% combustible

substances

Ammonium nitrate emulsion 140 3375

Ammonium nitrate fertilizer, 140 2072

n.o.s.

Ammonium nitrate fertilizer, with 140 2071

not more than 0.4%

combustible material

Ammonium nitrate fertilizers 140 2067

Ammonium nitrate fertilizers 140 2071

Ammonium nitrate fertilizers 140 2072

Ammonium nitrate fertilizers, 140 2069

with Ammonium sulfate

mixtures

Ammonium nitrate gel 

Ammonium nitrate mixe

fertilizers

Ammonium nitrate suspe

Ammonium perchlorate 

Ammonium persulfate 

Ammonium persulphate 

Ammonium picrate, wet

not less than 10% wa

Ammonium polysulfide, 

Ammonium polysulphid

solution

Ammonium polyvanada

Ammonium silicofluorid

Ammonium sulfide, solu

Ammonium sulphide, so

Ammunition, poisonous

non-explosive

Ammunition, tear-produ

non-explosive

Ammunition, toxic, 

non-explosive

Amyl acetates 

Amyl acid phosphate 

Amyl alcohols 

Amylamines 

Amyl butyrates 

Amyl chloride 

Alpha 97-166 Eng.pmd 3/25/0100
Amyl nitrite 129 1113

Amyltrichlorosilane 155 1728

Anhydrous ammonia 125 1005

Aniline 153 1547

Aniline hydrochloride 153 1548

Anisidines 153 2431

Anisidines, liquid 153 2431

Anisidines, solid 153 2431

Anisole 128 2222

Anisoyl chloride 156 1729

Antimony compound, inorganic, 157 3141

liquid, n.o.s.

Antimony compound, inorganic, 157 1549

n.o.s.

Antimony compound, inorganic, 157 1549

solid, n.o.s.

Antimony lactate 151 1550

Antimony pentachloride, liquid 157 1730

Antimony pentachloride, 157 1731

solution

Antimony pentafluoride 157 1732

Antimony potassium tartrate 151 1551

Antimony powder 170 2871

Antimony tribromide, solid 157 1549

Antimony tribromide, solution 157 1549

Antimony trichloride 157 1733

Antimony trichloride, liquid 157 1733

Antimony trichloride, solid 157 1733

Argon, refrigerated 

(cryogenic liquid)

Arsenic 

Arsenic acid, liquid 

Arsenic acid, solid 

Arsenical dust 

Arsenical pesticide, 

flammable, poiso

Arsenical pesticide, 

flammable, toxic

Arsenical pesticide, 

poisonous

Arsenical pesticide, 

poisonous, flamm

Arsenical pesticide

Arsenical pesticide

flammable

Arsenical pesticide

poisonous

Arsenical pesticide

Arsenic bromide 

Arsenic chloride 

Arsenic compound, 

Arsenic compound, 

n.o.s., inorganic

Arsenic compound, 

Arsenic compound, 

inorganic

Arsenic pentoxide 

Arsenic sulfide 

Alpha 97-166 Eng.pmd 3/25/0101
Page 102

Articles containing 171 2315

Polychlorinated biphenyls

(PCB)

Articles, pressurized, hydraulic 126 3164

(containing non-flammable

gas)

Articles, pressurized, pneumatic 126 3164

(containing non-flammable

gas)

Aryl sulfonic acids, liquid, with 153 2584

more than 5% free Sulfuric

acid

Aryl sulfonic acids, liquid, with 153 2586

not more than 5% free Sulfuric

acid

Aryl sulfonic acids, solid, with 153 2583

more than 5% free Sulfuric

acid

Aryl sulfonic acids, solid, with 153 2585

not more than 5% free Sulfuric

acid

Aryl sulphonic acids, liquid, with 153 2584

more than 5% free Sulphuric

acid

Aryl sulphonic acids, liquid, with 153 2586

not more than 5% free

Sulphuric acid

Aryl sulphonic acids, solid, with 153 2583

more than 5% free Sulphuric

acid

Aryl sulphonic acids, solid, with 153 2585

not more than 5% free

Sulphuric acid

Aviation regulated solid

1-Aziridinyl phosphine 

(Tris)

Azodicarbonamide 

Barium 

Barium alloys, pyropho

Barium azide, wetted w

less than 50% water

Barium bromate 

Barium chlorate 

Barium chlorate, solid 

Barium chlorate, solutio

Barium compound, n.o.

Barium cyanide 

Barium hypochlorite, wi

than 22% available C

Barium nitrate 

Barium oxide 

Barium perchlorate 

Barium perchlorate, so

Barium perchlorate, so

Barium permanganate 

Barium peroxide 

Batteries, containing S

Batteries, dry, containi

Potassium hydroxide 

Batteries, wet, filled wit

Batteries, wet, filled wit

Alpha 97-166 Eng.pmd 3/25/0102
actuating device

Battery-powered equipment (wet 154 3171

battery)

Battery-powered vehicle (wet 154 3171

battery)

Benzaldehyde 129 1990

Benzene 130 1114

Benzene phosphorus dichloride 137 2798

Benzene phosphorus 137 2799

thiodichloride

Benzenesulfonyl chloride 156 2225

Benzenesulphonyl chloride 156 2225

Benzidine 153 1885

Benzoic derivative pesticide, 131 2770

liquid, flammable, poisonous

Benzoic derivative pesticide, 131 2770

liquid, flammable, toxic

Benzoic derivative pesticide, 151 3004

liquid, poisonous

Benzoic derivative pesticide, 131 3003

liquid, poisonous, flammable

Benzoic derivative pesticide, 151 3004

liquid, toxic

Benzoic derivative pesticide, 131 3003

liquid, toxic, flammable

Benzoic derivative pesticide, 151 2769

solid, poisonous

Benzoic derivative pesticide, 151 2769

solid, toxic

Benzonitrile 152 2224

Benzyl chloroforma

Benzyldimethylami

Benzylidene chlorid

Benzyl iodide 

Beryllium compoun

Beryllium nitrate 

Beryllium powder 

Bhusa, wet, damp o

contaminated wit

Bicyclo[2.2.1]hepta

stabilized

Biological agents 

Biological substanc

(Bio)Medical waste

Bipyridilium pestici

flammable, poiso

Bipyridilium pestici

flammable, toxic

Bipyridilium pestici

poisonous

Bipyridilium pesticid

poisonous, flamm

Bipyridilium pesticid

toxic

Bipyridilium pesticid

toxic, flammable

Bipyridilium pestici

poisonous

Bipyridilium pestici

toxic

Alpha 97-166 Eng.pmd 3/25/0103
Page 104

Bisulphites, aqueous solution, 154 2693

n.o.s.

Bisulphites, inorganic, aqueous 154 2693

solution, n.o.s.

Blasting agent, n.o.s. 112 ——

Bleaching powder 140 2208

Blue asbestos 171 2212

Bombs, smoke, non-explosive, 153 2028

with corrosive liquid, without

initiating device

Borate and Chlorate mixtures 140 1458

Borneol 133 1312

Boron tribromide 157 2692

Boron trichloride 125 1741

Boron trifluoride 125 1008

Boron trifluoride, compressed 125 1008

Boron trifluoride, dihydrate 157 2851

Boron trifluoride acetic acid 157 1742

complex

Boron trifluoride acetic acid 157 1742

complex, liquid

Boron trifluoride acetic acid 157 3419

complex, solid

Boron trifluoride diethyl etherate 132 2604

Boron trifluoride dimethyl 139 2965

etherate

Boron trifluoride propionic acid 157 1743

complex

Boron trifluoride propionic acid 157 1743

complex, liquid

Bromine, solution 

Bromine, solution (Inha

Hazard Zone A)

Bromine, solution (Inha

Hazard Zone B)

Bromine chloride 

Bromine pentafluoride 

Bromine trifluoride 

Bromoacetic acid 

Bromoacetic acid, solid 

Bromoacetic acid, solu

Bromoacetone 

Bromoacetyl bromide 

Bromobenzene 

Bromobenzyl cyanides 

Bromobenzyl cyanides

Bromobenzyl cyanides

Bromobenzyl cyanides

1-Bromobutane 

2-Bromobutane 

Bromochlorodifluorome

Bromochloromethane 

1-Bromo-3-chloropropa

2-Bromoethyl ethyl ethe

Bromoform 

1-Bromo-3-methylbutan

Bromomethylpropanes 

2-Bromo-2-nitropropan

Alpha 97-166 Eng.pmd 3/25/0104
Brown asbestos 171 2212

Brucine 152 1570

Butadienes, stabilized 116P 1010

Butadienes and hydrocarbon 116P 1010

mixture, stabilized

Butane 115 1011

Butane 115 1075

Butanedione 127 2346

Butane mixture 115 1011

Butane mixture 115 1075

Butanols 129 1120

Butoxyl 127 2708

Butyl acetates 129 1123

Butyl acid phosphate 153 1718

Butyl acrylates, stabilized 129P 2348

n-Butylamine 132 1125

N-Butylaniline 153 2738

Butylbenzenes 128 2709

n-Butyl bromide 130 1126

Butyl chloride 130 1127

n-Butyl chloroformate 155 2743

sec-Butyl chloroformate 155 2742

tert-Butylcyclohexyl 156 2747

chloroformate

Butylene 115 1012

Butylene 115 1075

1,2-Butylene oxide, stabilized 127P 3022

Butyl mercaptan 

n-Butyl methacrylat

Butyl methyl ether 

Butyl nitrites 

Butyl propionates 

Butyltoluenes 

Butyltrichlorosilane 

5-tert-Butyl-2,4,6-t

m-xylene

Butyl vinyl ether, st

1,4-Butynediol 

Butyraldehyde 

Butyraldoxime 

Butyric acid 

Butyric anhydride 

Butyronitrile 

Butyryl chloride 

Buzz 

BZ 

CA 

Cacodylic acid 

Cadmium compoun

Caesium 

Caesium hydroxide 

Caesium hydroxide

Caesium nitrate 

Calcium 

Alpha 97-166 Eng.pmd 3/25/0105
Page 106

arsenite mixture, solid

Calcium arsenite, solid 151 1574

Calcium arsenite and Calcium 151 1574

arsenate mixture, solid

Calcium carbide 138 1402

Calcium chlorate 140 1452

Calcium chlorate, aqueous 140 2429

solution

Calcium chlorate, solution 140 2429

Calcium chlorite 140 1453

Calcium cyanamide, with more 138 1403

than 0.1% Calcium carbide

Calcium cyanide 157 1575

Calcium dithionite 135 1923

Calcium hydride 138 1404

Calcium hydrosulfite 135 1923

Calcium hydrosulphite 135 1923

Calcium hypochlorite, dry 140 1748

Calcium hypochlorite, hydrated, 140 2880

with not less than 5.5% but not

more than 16% water

Calcium hypochlorite, hydrated 140 2880

mixture, with not less than

5.5% but not more than 16%

water

Calcium hypochlorite mixture, 140 2208

dry, with more than 10% but

not more than 39% available

Chlorine

Calcium perchlorate 

Calcium permanganate 

Calcium peroxide 

Calcium phosphide 

Calcium resinate 

Calcium resinate, fused 

Calcium silicide 

Calcium silicon 

Camphor 

Camphor, synthetic 

Camphor oil 

Caproic acid 

Carbamate pesticide, li

flammable, poisonou

Carbamate pesticide, li

flammable, toxic

Carbamate pesticide, liq

poisonous

Carbamate pesticide, li

poisonous, flammable

Carbamate pesticide, liq

toxic

Carbamate pesticide, liq

toxic, flammable

Carbamate pesticide, s

poisonous

Carbamate pesticide, so

toxic

Carbon, activated 

Alpha 97-166 Eng.pmd 3/25/0106
Carbon dioxide, refrigerated 120 2187

liquid

Carbon dioxide, solid 120 1845

Carbon dioxide and Ethylene 115 1041

oxide mixture, with more than

9% but not more than 87%

Ethylene oxide

Carbon dioxide and Ethylene 119P 3300

oxide mixture, with more than

87% Ethylene oxide

Carbon dioxide and Ethylene 115 1041

oxide mixtures, with more

than 6% Ethylene oxide

Carbon dioxide and Ethylene 126 1952

oxide mixtures, with not more

than 6% Ethylene oxide

Carbon dioxide and Ethylene 126 1952

oxide mixtures, with not more

than 9% Ethylene oxide

Carbon dioxide and Nitrous 126 1015

oxide mixture

Carbon dioxide and Oxygen 122 1014

mixture

Carbon dioxide and Oxygen 122 1014

mixture, compressed

Carbon disulfide 131 1131

Carbon disulphide 131 1131

Carbon monoxide 119 1016

Carbon monoxide, compressed 119 1016

Carbon monoxide, refrigerated 168 9202

liquid (cryogenic liquid)

Carbonyl fluoride 

Carbonyl fluoride, c

Carbonyl sulfide 

Carbonyl sulphide 

Castor beans, meal

flake

Caustic alkali liquid

Caustic potash, dry

Caustic potash, liqu

Caustic potash, solu

Caustic soda, bead 

Caustic soda, flake 

Caustic soda, granu

Caustic soda, solid 

Caustic soda, solut

Cells, containing So

Celluloid, in blocks

sheets, tubes, et

scrap

Celluloid, scrap 

Cerium, slabs, ingo

Cerium, turnings or 

Cesium 

Cesium hydroxide 

Cesium hydroxide, 

Cesium nitrate 

CG 

Charcoal 

Alpha 97-166 Eng.pmd 3/25/0107
Page 108

solid

Chemical sample, toxic 151 3315

Chemical sample, toxic liquid 151 3315

Chemical sample, toxic solid 151 3315

Chloral, anhydrous, stabilized 153 2075

Chlorate and Borate mixtures 140 1458

Chlorate and Magnesium 140 1459

chloride mixture

Chlorate and Magnesium 140 1459

chloride mixture, solid

Chlorate and Magnesium 140 3407

chloride mixture, solution

Chlorates, inorganic, aqueous 140 3210

solution, n.o.s.

Chlorates, inorganic, n.o.s. 140 1461

Chloric acid, aqueous solution, 140 2626

with not more than 10%

Chloric acid

Chlorine 124 1017

Chlorine dioxide, hydrate, frozen 143 9191

Chlorine pentafluoride 124 2548

Chlorine trifluoride 124 1749

Chlorite solution 154 1908

Chlorite solution, with more than 154 1908

5% available Chlorine

Chlorites, inorganic, n.o.s. 143 1462

Chloroacetaldehyde 153 2232

Chloroacetic acid, liquid 153 1750

Chloroacetic acid, molten 153 3250

Chloroacetophenone, l

Chloroacetophenone, s

Chloroacetyl chloride 

Chloroanilines, liquid 

Chloroanilines, solid 

Chloroanisidines 

Chlorobenzene 

Chlorobenzotrifluorides 

Chlorobenzyl chlorides 

Chlorobenzyl chlorides

Chlorobenzyl chlorides

1-Chloro-3-bromopropa

Chlorobutanes 

Chlorocresols 

Chlorocresols, liquid 

Chlorocresols, solid 

Chlorocresols, solid 

Chlorocresols, solution 

Chlorodifluorobromome

1-Chloro-1,1-difluoroet

Chlorodifluoroethanes 

Chlorodifluoromethane 

Chlorodifluoromethane a

Chloropentafluoroetha

Chlorodinitrobenzenes 

Chlorodinitrobenzenes, 

Chlorodinitrobenzenes, 

Alpha 97-166 Eng.pmd 3/25/0108
corrosive, flammable, n.o.s.

Chloroformates, poisonous, 154 3277

corrosive, n.o.s.

Chloroformates, toxic, 155 2742

corrosive, flammable, n.o.s.

Chloroformates, toxic, 154 3277

corrosive, n.o.s.

Chloromethyl chloroformate 157 2745

Chloromethyl ethyl ether 131 2354

3-Chloro-4-methylphenyl 156 2236

isocyanate

3-Chloro-4-methylphenyl 156 2236

isocyanate, liquid

3-Chloro-4-methylphenyl 156 3428

isocyanate, solid

Chloronitroanilines 153 2237

Chloronitrobenzenes 152 1578

Chloronitrobenzenes, liquid 152 1578

Chloronitrobenzenes, liquid 152 3409

Chloronitrobenzenes, solid 152 1578

Chloronitrotoluenes 152 2433

Chloronitrotoluenes, liquid 152 2433

Chloronitrotoluenes, solid 152 2433

Chloronitrotoluenes, solid 152 3457

Chloropentafluoroethane 126 1020

Chloropentafluoroethane and 126 1973

Chlorodifluoromethane

mixture

Chlorophenates, liquid 154 2904

Chloropicrin 

Chloropicrin and Me

mixture

Chloropicrin and Me

mixture

Chloropicrin mixtur

Chloropivaloyl chlo

Chloroplatinic acid

Chloroprene, stabil

1-Chloropropane 

2-Chloropropane 

3-Chloropropanol-1 

2-Chloropropene 

2-Chloropropionic a

2-Chloropropionic a

2-Chloropropionic a

2-Chloropyridine 

Chlorosilanes, corr

flammable, n.o.s

Chlorosilanes, corr

Chlorosilanes, flam

corrosive, n.o.s.

Chlorosilanes, n.o.

Chlorosilanes, n.o.

Chlorosilanes, n.o.

Chlorosilanes, n.o.

Chlorosilanes, pois

corrosive, flamm

Alpha 97-166 Eng.pmd 3/25/0109
Page 110

flammable, corrosive, n.o.s.

Chlorosulfonic acid 137 1754

Chlorosulfonic acid and Sulfur 137 1754

trioxide mixture

Chlorosulphonic acid 137 1754

Chlorosulphonic acid and 137 1754

Sulphur trioxide mixture

1-Chloro-1,2,2,2- 126 1021

tetrafluoroethane

Chlorotetrafluoroethane 126 1021

Chlorotetrafluoroethane and 126 3297

Ethylene oxide mixture, with

not more than 8.8% Ethylene

oxide

Chlorotoluenes 129 2238

4-Chloro-o-toluidine 153 1579

hydrochloride

4-Chloro-o-toluidine 153 1579

hydrochloride, solid

4-Chloro-o-toluidine 153 3410

hydrochloride, solution

Chlorotoluidines 153 2239

Chlorotoluidines, liquid 153 2239

Chlorotoluidines, liquid 153 3429

Chlorotoluidines, solid 153 2239

1-Chloro-2,2,2-trifluoroethane 126 1983

Chlorotrifluoroethane 126 1983

Chlorotrifluoromethane 126 1022

Chromic fluoride, solutio

Chromium nitrate 

Chromium oxychloride 

Chromium trioxide, anh

Chromosulfuric acid 

Chromosulphuric acid 

CK 

Clinical specimens 

Clinical waste, unspeci

n.o.s.

CN 

Coal gas 

Coal gas, compressed 

Coal tar distillates, flam

Coating solution 

Cobalt naphthenates, p

Cobalt resinate, precip

Combustible liquid, n.o

Compound, cleaning liq

(corrosive)

Compound, cleaning liq

(flammable)

Compound, tree or wee

liquid (corrosive)

Compound, tree or wee

liquid (flammable)

Compound, tree or wee

liquid (toxic)

Alpha 97-166 Eng.pmd 3/25/0110
Hazard Zone B)

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, n.o.s. 126 1956

Compressed gas, oxidizing, 122 3156

n.o.s.

Compressed gas, poisonous, 123 3304

corrosive, n.o.s.

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone C)

(Inhalation Haza

Compressed gas, p

flammable, corro

(Inhalation Haza

Compressed gas, p

flammable, corro

(Inhalation Haza

Compressed gas, p

flammable, corro

(Inhalation Haza

Compressed gas, p

flammable, n.o.s

Compressed gas, p

flammable, n.o.s

Hazard Zone A)

Compressed gas, p

flammable, n.o.s

Hazard Zone B)

Compressed gas, p

flammable, n.o.s

Hazard Zone C)

Compressed gas, p

flammable, n.o.s

Hazard Zone D)

Compressed gas, p

n.o.s.

Compressed gas, p

n.o.s. (Inhalation 

Zone A)

Compressed gas, p

n.o.s. (Inhalation 

Zone B)

Alpha 97-166 Eng.pmd 3/25/0111
Page 112

oxidizing, corrosive, n.o.s.

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s.

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, toxic, 123 3304

corrosive, n.o.s.

Compressed gas, toxic, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone A)

corrosive, n.o.s. (Inh

Hazard Zone D)

Compressed gas, toxic

flammable, corrosive

Compressed gas, toxic

flammable, corrosive

(Inhalation Hazard Z

Compressed gas, toxic

flammable, corrosive

(Inhalation Hazard Z

Compressed gas, toxic

flammable, corrosive

(Inhalation Hazard Z

Compressed gas, toxic

flammable, corrosive

(Inhalation Hazard Z

Compressed gas, toxic

flammable, n.o.s.

Compressed gas, toxic

flammable, n.o.s. (In

Hazard Zone A)

Compressed gas, toxic

flammable, n.o.s. (In

Hazard Zone B)

Compressed gas, toxic

flammable, n.o.s. (In

Hazard Zone C)

Compressed gas, toxic

flammable, n.o.s. (In

Hazard Zone D)

Compressed gas, toxic

Alpha 97-166 Eng.pmd 3/25/0112
(Inhalation Hazard Zone D)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s.

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

Consumer commodity 171 8000

Copper acetoarsenite 151 1585

Copper based pesti

poisonous, flamm

Copper based pesti

toxic

Copper based pesti

toxic, flammable

Copper based pesti

poisonous

Copper based pesti

toxic

Copper chlorate 

Copper chloride 

Copper cyanide 

Copra 

Corrosive liquid, ac

inorganic, n.o.s.

Corrosive liquid, ac

n.o.s.

Corrosive liquid, ba

inorganic, n.o.s.

Corrosive liquid, ba

n.o.s.

Corrosive liquid, fla

n.o.s.

Corrosive liquid, n.

Corrosive liquid, ox

n.o.s.

Corrosive liquid, po

n.o.s.

Alpha 97-166 Eng.pmd 3/25/0113
Page 114

flammable gases, n.o.s.

Corrosive solid, acidic, 154 3260

inorganic, n.o.s.

Corrosive solid, acidic, organic, 154 3261

n.o.s.

Corrosive solid, basic, 154 3262

inorganic, n.o.s.

Corrosive solid, basic, organic, 154 3263

n.o.s.

Corrosive solid, flammable, n.o.s. 134 2921

Corrosive solid, n.o.s. 154 1759

Corrosive solid, oxidizing, n.o.s. 140 3084

Corrosive solid, poisonous, 154 2923

n.o.s.

Corrosive solid, self-heating, 136 3095

n.o.s.

Corrosive solid, toxic, n.o.s. 154 2923

Corrosive solid, water-reactive, 138 3096

n.o.s.

Corrosive solid, which in contact 138 3096

with water emits flammable

gases, n.o.s.

Cotton 133 1365

Cotton, wet 133 1365

Cotton waste, oily 133 1364

Coumarin derivative pesticide, 131 3024

liquid, flammable, poisonous

Coumarin derivative pesticide, 131 3024

liquid, flammable, toxic

liquid, toxic, flammab

Coumarin derivative pe

solid, poisonous

Coumarin derivative pe

solid, toxic

Cresols 

Cresols, liquid 

Cresols, solid 

Cresols, solid 

Cresylic acid 

Crotonaldehyde 

Crotonaldehyde, stabil

Crotonic acid 

Crotonic acid, liquid 

Crotonic acid, liquid 

Crotonic acid, solid 

Crotonylene 

CS 

Cumene 

Cupriethylenediamine, 

CX 

Cyanide solution, n.o.s

Cyanides, inorganic, n.

Cyanides, inorganic, so

n.o.s.

Cyanogen 

Cyanogen bromide 

Alpha 97-166 Eng.pmd 3/25/0114
Cycloheptane 128 2241

Cycloheptatriene 131 2603

Cycloheptene 128 2242

Cyclohexane 128 1145

Cyclohexanethiol 129 3054

Cyclohexanone 127 1915

Cyclohexene 130 2256

Cyclohexenyltrichlorosilane 156 1762

Cyclohexyl acetate 130 2243

Cyclohexylamine 132 2357

Cyclohexyl isocyanate 155 2488

Cyclohexyl mercaptan 129 3054

Cyclohexyltrichlorosilane 156 1763

Cyclooctadiene phosphines 135 2940

Cyclooctadienes 130P 2520

Cyclooctatetraene 128P 2358

Cyclopentane 128 1146

Cyclopentanol 129 2244

Cyclopentanone 128 2245

Cyclopentene 128 2246

Cyclopropane 115 1027

Cymenes 130 2046

DA 151 1699

Dangerous goods in apparatus 171 3363

Dangerous goods in machinery 171 3363

DC 153 2810

liquid, n.o.s.

Desensitized explo

solid, n.o.s.

Deuterium 

Deuterium, compres

Devices, small, hyd

powered, with rel

Diacetone alcohol 

Diacetyl 

Diagnostic specime

Diallylamine 

Diallyl ether 

4,4'-Diaminodipheny

Di-n-amylamine 

Dibenzyldichlorosil

Diborane 

Diborane, compres

Diborane mixtures 

Dibromobenzene 

1,2-Dibromobutan-

Dibromochloroprop

Dibromodifluorome

Dibromomethane 

Di-n-butylamine 

Dibutylaminoethan

Dibutyl ethers 

Dichloroacetic acid 

1,3-Dichloroaceton

Alpha 97-166 Eng.pmd 3/25/0115
Page 116

Dichlorobutene 132 2920

2,2'-Dichlorodiethyl ether 152 1916

Dichlorodifluoromethane 126 1028

Dichlorodifluoromethane and 126 2602

Difluoroethane azeotropic

mixture with approximately

74% Dichlorodifluoromethane

Dichlorodifluoromethane and 126 3070

Ethylene oxide mixture, with

not more than 12.5% Ethylene

oxide

Dichlorodifluoromethane and 126 3070

Ethylene oxide mixture, with

not more than 12% Ethylene

oxide

Dichlorodimethyl ether, 131 2249

symmetrical

1,1-Dichloroethane 130 2362

1,2-Dichloroethylene 130P 1150

Dichloroethylene 130P 1150

Dichloroethyl ether 152 1916

Dichlorofluoromethane 126 1029

Dichloroisocyanuric acid, dry 140 2465

Dichloroisocyanuric acid salts 140 2465

Dichloroisopropyl ether 153 2490

Dichloromethane 160 1593

1,1-Dichloro-1-nitroethane 153 2650

Dichloropentanes 130 1152

Dichlorophenyl isocyanates 156 2250

1,2-Dichloro-1,1,2,2- 

tetrafluoroethane

Dichlorotetrafluoroethan

3,5-Dichloro-2,4,6- 

trifluoropyridine

Dicyclohexylamine 

Dicyclohexylammonium 

Dicyclopentadiene 

1,2-Di-(dimethylamino)

Didymium nitrate 

Dieldrin 

Diesel fuel 

Diesel fuel 

Diethoxymethane 

3,3-Diethoxypropene 

Diethylamine 

2-Diethylaminoethanol 

Diethylaminoethanol 

3-Diethylaminopropyla

Diethylaminopropylami

N,N-Diethylaniline 

Diethylbenzene 

Diethyl carbonate 

Diethyldichlorosilane 

Diethylenetriamine 

Diethyl ether 

N,N-Diethylethylenedia

Alpha 97-166 Eng.pmd 3/25/0116
Diethylzinc 135 1366

Difluorochloroethanes 115 2517

1,1-Difluoroethane 115 1030

Difluoroethane 115 1030

Difluoroethane and 126 2602

Dichlorodifluoromethane

azeotropic mixture with

approximately 74%

Dichlorodifluoromethane

1,1-Difluoroethylene 116P 1959

Difluoromethane 115 3252

Difluorophosphoric acid, 154 1768

anhydrous

2,3-Dihydropyran 127 2376

Diisobutylamine 132 2361

Diisobutylene, isomeric 128 2050

compounds

Diisobutyl ketone 128 1157

Diisooctyl acid phosphate 153 1902

Diisopropylamine 132 1158

Diisopropyl ether 127 1159

Diketene, stabilized 131P 2521

1,1-Dimethoxyethane 127 2377

1,2-Dimethoxyethane 127 2252

Dimethylamine, anhydrous 118 1032

Dimethylamine, aqueous 132 1160

solution

Dimethylamine, solution 132 1160

2-Dimethylaminoacetonitrile 131 2378

N,NDimethylanilin

2,3-Dimethylbutane 

1,3-Dimethylbutylam

Dimethylcarbamoyl 

Dimethyl carbonate 

Dimethylcyclohexa

N,N-Dimethylcyclo

Dimethylcyclohexy

Dimethyldichlorosil

Dimethyldiethoxysi

Dimethyldioxanes 

Dimethyl disulfide 

Dimethyl disulphide 

Dimethylethanolam

Dimethyl ether 

N,N-Dimethylforma

1,1-Dimethylhydraz

1,2-Dimethylhydraz

Dimethylhydrazine

Dimethylhydrazine

unsymmetrical

2,2-Dimethylpropan

Dimethyl-N-propyla

Dimethyl sulfate 

Dimethyl sulfide 

Dimethyl sulphate 

Dimethyl sulphide 

Dimethyl thiophosp

Alpha 97-166 Eng.pmd 3/25/0117
Page 118

Dinitrochlorobenzenes 153 1577

Dinitro-o-cresol 153 1598

Dinitrogen tetroxide 124 1067

Dinitrogen tetroxide and Nitric 124 1975

oxide mixture

Dinitrophenol, solution 153 1599

Dinitrophenol, wetted with not 113 1320

less than 15% water

Dinitrophenolates, wetted with 113 1321

not less than 15% water

Dinitroresorcinol, wetted with 113 1322

not less than 15% water

Dinitrotoluenes 152 2038

Dinitrotoluenes, liquid 152 2038

Dinitrotoluenes, molten 152 1600

Dinitrotoluenes, solid 152 2038

Dinitrotoluenes, solid 152 3454

Dioxane 127 1165

Dioxolane 127 1166

Dipentene 128 2052

Diphenylamine chloroarsine 154 1698

Diphenylchloroarsine 151 1699

Diphenylchloroarsine, liquid 151 1699

Diphenylchloroarsine, solid 151 1699

Diphenylchloroarsine, solid 151 3450

Diphenyldichlorosilane 156 1769

Diphenylmethyl bromide 153 1770

Diphosgene 125 1076

Dipropyl ether 

Dipropyl ketone 

Disinfectant, liquid, cor

n.o.s.

Disinfectant, liquid, pois

n.o.s.

Disinfectant, liquid, tox

Disinfectant, solid, poison

Disinfectant, solid, toxi

Disinfectants, corrosive

n.o.s.

Disinfectants, liquid, n.o

(poisonous)

Disinfectants, solid, n.o

(poisonous)

Disodium trioxosilicate 

Disodium trioxosilicate, 

pentahydrate

Dispersant gas, n.o.s. 

Dispersant gas, n.o.s. 

(flammable)

Dithiocarbamate pestic

liquid, flammable, poi

Dithiocarbamate pesticid

liquid, flammable, tox

Dithiocarbamate pesticid

liquid, poisonous

Dithiocarbamate pesticid

liquid, poisonous, fla

Dithiocarbamate pestic

liquid, toxic

Alpha 97-166 Eng.pmd 3/25/0118
DM 154 1698

Dodecylbenzenesulfonic acid 153 2584

Dodecylbenzenesulphonic acid 153 2584

Dodecyltrichlorosilane 156 1771

DP 125 1076

Dry ice 120 1845

Dye, liquid, corrosive, n.o.s. 154 2801

Dye, liquid, poisonous, n.o.s. 151 1602

Dye, liquid, toxic, n.o.s. 151 1602

Dye, solid, corrosive, n.o.s. 154 3147

Dye, solid, poisonous, n.o.s. 151 3143

Dye, solid, toxic, n.o.s. 151 3143

Dye intermediate, liquid, 154 2801

corrosive, n.o.s.

Dye intermediate, liquid, 151 1602

poisonous, n.o.s.

Dye intermediate, liquid, toxic, 151 1602

n.o.s.

Dye intermediate, solid, 154 3147

corrosive, n.o.s.

Dye intermediate, solid, 151 3143

poisonous, n.o.s.

Dye intermediate, solid, toxic, 151 3143

n.o.s.

ED 151 1892

Elevated temperature liquid, 128 3256

flammable, n.o.s., with flash

point above 37.8°C (100°F),

at or above its flash point

Elevated temperatu

n.o.s., at or abov

(464°F)

Engine starting fluid 

Engines, internal co

flammable gas po

Engines, internal co

flammable liquid p

Engines, internal co

including when fit

machinery or veh

Environmentally haz

substances, liqui

Environmentally ha

substances, solid

Epibromohydrin 

Epichlorohydrin 

1,2-Epoxy-3-ethoxy

Esters, n.o.s. 

Ethane 

Ethane, compressed 

Ethane, refrigerated 

Ethane-Propane mix

refrigerated liquid

Ethanol 

Ethanol and gasolin

with more than 10

Ethanol and motor s

with more than 1

Alpha 97-166 Eng.pmd 3/25/0119
Page 120

Ethyl acetate 129 1173

Ethylacetylene, stabilized 116P 2452

Ethyl acrylate, stabilized 129P 1917

Ethyl alcohol 127 1170

Ethyl alcohol, solution 127 1170

Ethylamine 118 1036

Ethylamine, aqueous solution, 132 2270

with not less than 50% but not

more than 70% Ethylamine

Ethyl amyl ketone 128 2271

2-Ethylaniline 153 2273

N-Ethylaniline 153 2272

Ethylbenzene 130 1175

N-Ethyl-N-benzylaniline 153 2274

N-Ethylbenzyltoluidines 153 2753

N-Ethylbenzyltoluidines, liquid 153 2753

N-Ethylbenzyltoluidines, solid 153 2753

N-Ethylbenzyltoluidines, solid 153 3460

Ethyl borate 129 1176

Ethyl bromide 131 1891

Ethyl bromoacetate 155 1603

2-Ethylbutanol 129 2275

2-Ethylbutyl acetate 130 1177

Ethylbutyl acetate 130 1177

Ethyl butyl ether 127 1179

2-Ethylbutyraldehyde 130 1178

Ethyl butyrate 130 1180

Ethyl chloride 115 1037

Ethyldichloroarsine 

Ethyldichlorosilane 

Ethylene 

Ethylene, Acetylene an

Propylene in mixture

refrigerated liquid con

at least 71.5% Ethyle

not more than 22.5%

Acetylene and not mo

6% Propylene

Ethylene, compressed 

Ethylene, refrigerated li

(cryogenic liquid)

Ethylene chlorohydrin 

Ethylenediamine 

Ethylene dibromide 

Ethylene dibromide and 

bromide mixture, liqu

Ethylene dichloride 

Ethylene glycol diethyl 

Ethylene glycol monobu

Ethylene glycol monoet

Ethylene glycol monoet

acetate

Ethylene glycol monomet

Ethylene glycol monom

ether acetate

Ethyleneimine, stabiliz

Ethylene oxide 

Alpha 97-166 Eng.pmd 3/25/0120
Ethylene oxide and Carbon 115 1041

dioxide mixtures, with more

than 6 % Ethylene oxide

Ethylene oxide and Carbon 126 1952

dioxide mixtures, with not

more than 6% Ethylene oxide

Ethylene oxide and Carbon 126 1952

dioxide mixtures, with not

more than 9% Ethylene oxide

Ethylene oxide and 126 3297

Chlorotetrafluoroethane

mixture, with not more than

8.8% Ethylene oxide

Ethylene oxide and 126 3070

Dichlorodifluoromethane

mixture, with not more than

12.5% Ethylene oxide

Ethylene oxide and 126 3070

Dichlorodifluoromethane

mixtures, with not more than

12% Ethylene oxide

Ethylene oxide and 126 3298

Pentafluoroethane mixture,

with not more than 7.9%

Ethylene oxide

Ethylene oxide and Propylene 129P 2983

oxide mixture, with not more

than 30% Ethylene oxide

Ethylene oxide and 126 3299

Tetrafluoroethane mixture,

with not more than 5.6%

Ethylene oxide

Ethylene oxide with Nitrogen 119P 1040

Ethyl isobutyrate 

Ethyl isocyanate 

Ethyl lactate 

Ethyl mercaptan 

Ethyl methacrylate 

Ethyl methacrylate, 

Ethyl methyl ether 

Ethyl methyl ketone 

Ethyl nitrite, solutio

Ethyl orthoformate 

Ethyl oxalate 

Ethylphenyldichloro

Ethyl phosphonothi

dichloride, anhyd

Ethyl phosphonous 

anhydrous

Ethyl phosphorodic

1-Ethylpiperidine 

Ethyl propionate 

Ethyl propyl ether 

Ethyl silicate 

Ethylsulfuric acid 

Ethylsulphuric acid 

N-Ethyltoluidines 

Ethyltrichlorosilane 

Explosive A 

Explosive B 

Alpha 97-166 Eng.pmd 3/25/0121
Page 122

Extracts, flavouring, liquid 127 1197

Fabrics, animal or vegetable 133 1373

or synthetic, n.o.s. with oil

Fabrics impregnated with weakly 133 1353

nitrated Nitrocellulose, n.o.s.

Ferric arsenate 151 1606

Ferric arsenite 151 1607

Ferric chloride 157 1773

Ferric chloride, anhydrous 157 1773

Ferric chloride, solution 154 2582

Ferric nitrate 140 1466

Ferrocerium 170 1323

Ferrosilicon 139 1408

Ferrous arsenate 151 1608

Ferrous chloride, solid 154 1759

Ferrous chloride, solution 154 1760

Ferrous metal borings, 170 2793

shavings, turnings or cuttings

Fertilizer, ammoniating solution, 125 1043

with free Ammonia

Fiber, animal or vegetable, 133 1372

n.o.s., burnt, wet or damp

Fibers, animal or vegetable 133 1373

or synthetic, n.o.s. with oil

Fibers, animal or vegetable, 133 1372

burnt, wet or damp

Fibers, vegetable, dry 133 3360

Fibers impregnated with weakly 133 1353

nitrated Nitrocellulose, n.o.s.

Films, nitrocellulose ba

Fire extinguisher charg

corrosive liquid

Fire extinguishers with 

compressed gas

Fire extinguishers with 

liquefied gas

Firelighters, solid, with 

flammable liquid

First aid kit 

Fish meal, stabilized 

Fish meal, unstabilized 

Fish scrap, stabilized 

Fish scrap, unstabilized 

Flammable liquid, corro

n.o.s

Flammable liquid, n.o.s

Flammable liquid, poiso

corrosive, n.o.s.

Flammable liquid, poiso

n.o.s.

Flammable liquid, toxic

corrosive, n.o.s.

Flammable liquid, toxic

Flammable solid, corros

inorganic, n.o.s.

Flammable solid, corros

n.o.s.

Flammable solid, corro

organic, n.o.s.

Alpha 97-166 Eng.pmd 3/25/0122
Flammable solid, organic, n.o.s. 133 1325

Flammable solid, oxidizing, 140 3097

n.o.s.

Flammable solid, poisonous, 134 3179

inorganic, n.o.s.

Flammable solid, poisonous, 134 2926

n.o.s.

Flammable solid, poisonous, 134 2926

organic, n.o.s.

Flammable solid, toxic, 134 3179

inorganic, n.o.s.

Flammable solid, toxic, organic, 134 2926

n.o.s.

Fluoboric acid 154 1775

Fluorine 124 1045

Fluorine, compressed 124 1045

Fluorine, refrigerated liquid 167 9192

(cryogenic liquid)

Fluoroacetic acid 154 2642

Fluoroanilines 153 2941

Fluorobenzene 130 2387

Fluoroboric acid 154 1775

Fluorophosphoric acid, 154 1776

anhydrous

Fluorosilicates, n.o.s. 151 2856

Fluorosilicic acid 154 1778

Fluorosulfonic acid 137 1777

Fluorosulphonic acid 137 1777

Fluorotoluenes 130 2388

Formic acid 

Formic acid, with m

85% acid

Formic acid, with no

5% but less than 

Formic acid, with no

10% but not more 

85% acid

Fuel, aviation, turb

Fuel cell cartridges 

in equipment, co

corrosive substa

Fuel cell cartridges 

in equipment, co

flammable liquids

Fuel cell cartridges 

equipment, conta

hydrogen in meta

Fuel cell cartridges 

equipment, conta

liquefied flamma

Fuel cell cartridges 

equipment, conta

water-reactive su

Fuel cell cartridges

corrosive substa

Fuel cell cartridges

flammable liquids

Fuel cell cartridges

hydrogen in meta

Fuel cell cartridges

liquefied flamma

Alpha 97-166 Eng.pmd 3/25/0123
Page 124

flammable liquids

Fuel cell cartridges packed with 115 3479

equipment, containing

hydrogen in metal hydride

Fuel cell cartridges packed with 115 3478

equipment, containing

liquefied flammable gas

Fuel cell cartridges packed with 138 3476

equipment, containing

water-reactive substances

Fuel oil 128 1202

Fuel oil 128 1993

Fuel oil, no. 1,2,4,5,6 128 1202

Fumaryl chloride 156 1780

Fumigated unit 171 3359

Furaldehydes 132P 1199

Furan 128 2389

Furfural 132P 1199

Furfuraldehydes 132P 1199

Furfuryl alcohol 153 2874

Furfurylamine 132 2526

Fusee (rail or highway) 133 1325

Fusel oil 127 1201

GA 153 2810

Gallium 172 2803

Gas, refrigerated liquid, 115 3312

flammable, n.o.s.

Gas, refrigerated liquid, n.o.s. 120 3158

Gas oil 

Gasoline 

Gasoline and ethanol m

with more than 10% 

Gas sample, non-press

flammable, n.o.s., no

refrigerated liquid

Gas sample, non-press

poisonous, flammabl

not refrigerated liquid

Gas sample, non-press

poisonous, n.o.s., no

refrigerated liquid

Gas sample, non-press

toxic, flammable, n.o

refrigerated liquid

Gas sample, non-press

toxic, n.o.s., not refrig

liquid

GB 

GD 

Genetically modified m

organisms

Genetically modified or

Germane 

GF 

Glycerol alpha- 

monochlorohydrin

Glycidaldehyde 

Guanidine nitrate 

Alpha 97-166 Eng.pmd 3/25/0124
Hay, wet, damp or contaminated 133 1327

with oil

Hazardous waste, liquid, n.o.s. 171 3082

Hazardous waste, solid, n.o.s. 171 3077

HD 153 2810

Heating oil, light 128 1202

Heat producing article 171 8038

Helium 121 1046

Helium, compressed 121 1046

Helium, refrigerated liquid 120 1963

(cryogenic liquid)

Heptafluoropropane 126 3296

n-Heptaldehyde 129 3056

Heptanes 128 1206

n-Heptene 128 2278

Hexachloroacetone 153 2661

Hexachlorobenzene 152 2729

Hexachlorobutadiene 151 2279

Hexachlorocyclopentadiene 151 2646

Hexachlorophene 151 2875

Hexadecyltrichlorosilane 156 1781

Hexadiene 130 2458

Hexaethyl tetraphosphate 151 1611

Hexaethyl tetraphosphate, liquid 151 1611

Hexaethyl tetraphosphate, solid 151 1611

Hexaethyl tetraphosphate and 123 1612

compressed gas mixture

Hexafluoroacetone 125 2420

Hexafluoroethane, 

Hexafluorophospho

Hexafluoropropylen

Hexafluoropropylen

Hexaldehyde 

Hexamethylenediam

Hexamethylenediam

solution

Hexamethylene diis

Hexamethyleneimin

Hexamethylenetetra

Hexamine 

Hexanes 

Hexanoic acid 

Hexanols 

1-Hexene 

Hexyltrichlorosilan

HL 

HN-1 

HN-2 

HN-3 

Hydrazine, anhydro

Hydrazine, aqueou

with more than 3

Hydrazine

Hydrazine, aqueou

with not less than 

more than 64% H

Alpha 97-166 Eng.pmd 3/25/0125
Page 126

Hydriodic acid 154 1787

Hydriodic acid, solution 154 1787

Hydrobromic acid 154 1788

Hydrobromic acid, solution 154 1788

Hydrocarbon gas, compressed, 115 1964

n.o.s.

Hydrocarbon gas, liquefied, 115 1965

n.o.s.

Hydrocarbon gas mixture, 115 1964

compressed, n.o.s.

Hydrocarbon gas mixture, 115 1965

liquefied, n.o.s.

Hydrocarbon gas refills for small 115 3150

devices, with release device

Hydrocarbons, liquid, n.o.s. 128 3295

Hydrochloric acid 157 1789

Hydrochloric acid, solution 157 1789

Hydrocyanic acid, aqueous 154 1613

solution, with less than 5%

Hydrogen cyanide

Hydrocyanic acid, aqueous 154 1613

solution, with not more than

20% Hydrogen cyanide

Hydrocyanic acid, aqueous 117 1051

solutions, with more than 20%

Hydrogen cyanide

Hydrofluoric acid 157 1790

Hydrofluoric acid, solution 157 1790

Hydrofluoric acid and Sulfuric 157 1786

acid mixture

yg, p

Hydrogen in a metal hy

storage system

Hydrogen in a metal hyd

storage system conta

equipment

Hydrogen in a metal hyd

storage system packe

equipment

Hydrogen, refrigerated 

(cryogenic liquid)

Hydrogen and Carbon m

mixture

Hydrogen and Carbon m

mixture, compressed

Hydrogen and Methane 

compressed

Hydrogen bromide, anh

Hydrogen chloride, anh

Hydrogen chloride, refr

liquid

Hydrogen cyanide, anh

stabilized

Hydrogen cyanide, aqu

solution, with not mor

20% Hydrogen cyanid

Hydrogen cyanide, solu

alcohol, with not mor

45% Hydrogen cyanid

Hydrogen cyanide, stab

Hydrogen cyanide, stab

(absorbed)

Alpha 97-166 Eng.pmd 3/25/0126
yg, y

Hydrogen peroxide, aqueous 143 2015

solution, stabilized, with more

than 60% Hydrogen peroxide

Hydrogen peroxide, aqueous 140 2984

solution, with not less than 8%

but less than 20% Hydrogen

peroxide

Hydrogen peroxide, aqueous 140 2014

solution, with not less than

20% but not more than 60%

Hydrogen peroxide (stabilized

as necessary)

Hydrogen peroxide, stabilized 143 2015

Hydrogen peroxide and 140 3149

Peroxyacetic acid mixture,

with acid(s), water and not

more than 5% Peroxyacetic

acid, stabilized

Hydrogen selenide, anhydrous 117 2202

Hydrogen sulfide 117 1053

Hydrogen sulphide 117 1053

Hydroquinone 153 2662

Hydroquinone, solid 153 2662

Hydroquinone, solution 153 3435

1-Hydroxybenzotriazole, 113 3474

anhydrous, wetted with not

less than 20% water

Hydroxylamine sulfate 154 2865

Hydroxylamine sulphate 154 2865

Hypochlorite solution 154 1791

humans

Ink, printer’s, flamm

Insecticide gas, flam

Insecticide gas, flam

Insecticide gas, n.o

Insecticide gas, poi

flammable, n.o.s

Insecticide gas, poi

flammable, n.o.s

(Inhalation Haza

Insecticide gas, poi

flammable, n.o.s

(Inhalation Haza

Insecticide gas, poi

flammable, n.o.s

(Inhalation Haza

Insecticide gas, poi

flammable, n.o.s

(Inhalation Haza

Insecticide gas, poi

n.o.s.

Insecticide gas, tox

n.o.s.

Insecticide gas, tox

n.o.s.

(Inhalation Haza

Insecticide gas, tox

n.o.s.

(Inhalation Haza

Insecticide gas, tox

n.o.s.

(Inhalation Haza

Alpha 97-166 Eng.pmd 3/25/0127
Page 128

2Iodobutane 129 2390

Iodomethylpropanes 129 2391

Iodopropanes 129 2392

IPDI 156 2290

Iron oxide, spent 135 1376

Iron pentacarbonyl 131 1994

Iron sponge, spent 135 1376

Isobutane 115 1075

Isobutane 115 1969

Isobutane mixture 115 1075

Isobutane mixture 115 1969

Isobutanol 129 1212

Isobutyl acetate 129 1213

Isobutyl acrylate, stabilized 129P 2527

Isobutyl alcohol 129 1212

Isobutyl aldehyde 130 2045

Isobutylamine 132 1214

Isobutyl chloroformate 155 2742

Isobutylene 115 1055

Isobutylene 115 1075

Isobutyl formate 129 2393

Isobutyl isobutyrate 130 2528

Isobutyl isocyanate 155 2486

Isobutyl methacrylate, stabilized 130P 2283

Isobutyl propionate 129 2394

Isobutyraldehyde 130 2045

Isobutyric acid 132 2529

toxic, n.o.s.

Isocyanate solution, po

flammable, n.o.s.

Isocyanate solution, po

n.o.s.

Isocyanate solution, tox

flammable, n.o.s.

Isocyanate solution, tox

Isocyanate solutions, n

Isocyanate solutions, n

Isocyanate solutions, n

Isocyanates, flammable

poisonous, n.o.s.

Isocyanates, flammable

n.o.s.

Isocyanates, n.o.s. 

Isocyanates, n.o.s. 

Isocyanates, n.o.s. 

Isocyanates, poisonous

flammable, n.o.s.

Isocyanates, poisonous

Isocyanates, toxic, flam

n.o.s.

Isocyanates, toxic, n.o.

Isocyanatobenzotrifluo

Isoheptenes 

Isohexenes 

Isooctane 

Isooctenes 

Alpha 97-166 Eng.pmd 3/25/0128
Isopropenyl acetate 129P 2403

Isopropenylbenzene 128 2303

Isopropyl acetate 129 1220

Isopropyl acid phosphate 153 1793

Isopropyl alcohol 129 1219

Isopropylamine 132 1221

Isopropylbenzene 130 1918

Isopropyl butyrate 129 2405

Isopropyl chloroacetate 155 2947

Isopropyl chloroformate 155 2407

Isopropyl 2-chloropropionate 129 2934

Isopropyl isobutyrate 127 2406

Isopropyl isocyanate 155 2483

Isopropyl nitrate 130 1222

Isopropyl propionate 129 2409

Isosorbide dinitrate mixture 133 2907

Isosorbide-5-mononitrate 133 3251

Kerosene 128 1223

Ketones, liquid, n.o.s. 127 1224

Krypton 121 1056

Krypton, compressed 121 1056

Krypton, refrigerated liquid 120 1970

(cryogenic liquid)

L (Lewisite) 153 2810

Lead acetate 151 1616

Lead arsenates 151 1617

Lead arsenites 151 1618

Lead perchlorate, s

Lead perchlorate, s

Lead phosphite, dib

Lead sulfate, with m

free acid

Lead sulphate, with 

3% free acid

Lewisite 

Life-saving applian

inflating

Life-saving applian

inflating

Lighter refills (cigare

(flammable gas)

Lighters (cigarettes

(flammable gas)

Lighters for cigars, c

(flammable liquid

Liquefied gas, flam

Liquefied gas, n.o.s

Liquefied gas, oxid

Liquefied gas, pois

corrosive, n.o.s.

Liquefied gas, pois

corrosive, n.o.s. 

Hazard Zone A)

Liquefied gas, pois

corrosive, n.o.s. 

Hazard Zone B)

Alpha 97-166 Eng.pmd 3/25/0129
Page 130

flammable, corrosive, n.o.s.

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s.

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, poisonous, n.o.s. 123 3162

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone B)

oxidizing, corrosive, 

(Inhalation Hazard Z

Liquefied gas, poisonou

oxidizing, corrosive, 

(Inhalation Hazard Z

Liquefied gas, poisonou

oxidizing, corrosive, 

(Inhalation Hazard Z

Liquefied gas, poisonou

oxidizing, corrosive, 

(Inhalation Hazard Z

Liquefied gas, poisonou

oxidizing, n.o.s.

Liquefied gas, poisonou

oxidizing, n.o.s. (Inh

Hazard Zone A)

Liquefied gas, poisonou

oxidizing, n.o.s. (Inh

Hazard Zone B)

Liquefied gas, poisonou

oxidizing, n.o.s. (Inh

Hazard Zone C)

Liquefied gas, poisonou

oxidizing, n.o.s. (Inh

Hazard Zone D)

Liquefied gas, toxic, co

n.o.s.

Liquefied gas, toxic, co

n.o.s. (Inhalation Ha

Zone A)

Liquefied gas, toxic, co

n.o.s. (Inhalation Ha

Zone B)

Alpha 97-166 Eng.pmd 3/25/0130
corrosive, n.o.s.

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, toxic, flammable, 119 3160

n.o.s.

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone A)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone B)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone C)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone D)

Liquefied gas, toxic, n.o.s. 123 3162

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone A)

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone B)

corrosive, n.o.s. 

Hazard Zone A)

Liquefied gas, toxic

corrosive, n.o.s. 

Hazard Zone B)

Liquefied gas, toxic

corrosive, n.o.s. 

Hazard Zone C)

Liquefied gas, toxic

corrosive, n.o.s. 

Hazard Zone D)

Liquefied gas, toxic

n.o.s.

Liquefied gas, toxic

n.o.s. (Inhalation 

Zone A)

Liquefied gas, toxic

n.o.s. (Inhalation 

Zone B)

Liquefied gas, toxic

n.o.s. (Inhalation 

Zone C)

Liquefied gas, toxic

n.o.s. (Inhalation 

Zone D)

Liquefied gases, no

charged with Nitr

Carbon dioxide o

Liquefied natural ga

liquid)

Liquefied petroleum 

Lithium 

Alpha 97-166 Eng.pmd 3/25/0131
Page 132

Lithium amide 139 1412

Lithium batteries 138 3090

Lithium batteries, liquid or solid 138 3090

cathode

Lithium batteries contained in 138 3091

equipment

Lithium batteries packed with 138 3091

equipment

Lithium borohydride 138 1413

Lithium ferrosilicon 139 2830

Lithium hydride 138 1414

Lithium hydride, fused solid 138 2805

Lithium hydroxide 154 2680

Lithium hydroxide, monohydrate 154 2680

Lithium hydroxide, solid 154 2680

Lithium hydroxide, solution 154 2679

Lithium hypochlorite, dry 140 1471

Lithium hypochlorite mixture 140 1471

Lithium hypochlorite mixtures, 140 1471

dry

Lithium ion batteries contained 147 3481

in equipment (including

lithium ion polymer batteries)

Lithium ion batteries (including 147 3480

lithium ion polymer batteries)

Lithium ion batteries packed with 147 3481

equipment (including lithium ion

polymer batteries)

with equipment (inclu

lithium alloy batterie

Lithium nitrate 

Lithium nitride 

Lithium peroxide 

Lithium silicon 

LNG (cryogenic liquid) 

London purple 

LPG 

Magnesium 

Magnesium, in pellets, 

or ribbons

Magnesium alkyls 

Magnesium alloys, with 

than 50% Magnesium

pellets, turnings or ri

Magnesium alloys powd

Magnesium aluminum p

Magnesium arsenate 

Magnesium bromate 

Magnesium chlorate 

Magnesium chloride an

Chlorate mixture

Magnesium chloride and 

Chlorate mixture, sol

Magnesium chloride an

Chlorate mixture, solu

Magnesium diamide 

Magnesium diphenyl 

Alpha 97-166 Eng.pmd 3/25/0132
Magnesium phosphide 139 2011

Magnesium powder 138 1418

Magnesium silicide 138 2624

Magnesium silicofluoride 151 2853

Magnetized material 171 2807

Maleic acid 156 2215

Maleic anhydride 156 2215

Maleic anhydride, molten 156 2215

Malononitrile 153 2647

Maneb 135 2210

Maneb, stabilized 135 2968

Maneb preparation, stabilized 135 2968

Maneb preparation, with not less 135 2210

than 60% Maneb

Manganese nitrate 140 2724

Manganese resinate 133 1330

Matches, fusee 133 2254

Matches, safety 133 1944

Matches, “strike anywhere” 133 1331

Matches, wax “vesta” 133 1945

MD 152 1556

Medical waste, n.o.s. 158 3291

Medicine, liquid, flammable, 131 3248

poisonous, n.o.s.

Medicine, liquid, flammable, 131 3248

toxic, n.o.s.

Medicine, liquid, poisonous, 151 1851

n.o.s.

Medicines, corrosiv

n.o.s.

Medicines, flammab

n.o.s.

Medicines, flammab

n.o.s.

Mercaptan mixture, 

flammable, n.o.s.

Mercaptan mixture, 

flammable, poiso

Mercaptan mixture, 

flammable, toxic

Mercaptan mixture, 

poisonous, flamm

Mercaptan mixture, 

flammable, n.o.s

Mercaptans, liquid, 

n.o.s.

Mercaptans, liquid, 

poisonous, n.o.s

Mercaptans, liquid, 

toxic, n.o.s.

Mercaptans, liquid, 

flammable, n.o.s

Mercaptans, liquid, 

flammable, n.o.s

Mercuric arsenate 

Mercuric bromide 

Mercuric chloride 

Mercuric cyanide 

Mercuric nitrate 

Alpha 97-166 Eng.pmd 3/25/0133
Page 134

Mercury 172 2809

Mercury acetate 151 1629

Mercury ammonium chloride 151 1630

Mercury based pesticide, liquid, 131 2778

flammable, poisonous

Mercury based pesticide, liquid, 131 2778

flammable, toxic

Mercury based pesticide, liquid, 151 3012

poisonous

Mercury based pesticide, liquid, 131 3011

poisonous, flammable

Mercury based pesticide, liquid, 151 3012

toxic

Mercury based pesticide, liquid, 131 3011

toxic, flammable

Mercury based pesticide, solid, 151 2777

poisonous

Mercury based pesticide, solid, 151 2777

toxic

Mercury benzoate 154 1631

Mercury bromides 154 1634

Mercury compound, liquid, n.o.s. 151 2024

Mercury compound, solid, n.o.s. 151 2025

Mercury cyanide 154 1636

Mercury gluconate 151 1637

Mercury iodide 151 1638

Mercury metal 172 2809

Mercury nucleate 151 1639

Mercury oleate 151 1640

Mercury sulphate 

Mercury thiocyanate 

Mesityl oxide 

Metal alkyl, solution, n.

Metal alkyl halides, n.o

Metal alkyl halides, wat

reactive, n.o.s.

Metal alkyl hydrides, n.

Metal alkyl hydrides, wa

reactive, n.o.s.

Metal alkyls, n.o.s. 

Metal alkyls, water-rea

n.o.s.

Metal aryl halides, n.o.

Metal aryl halides, wate

reactive, n.o.s.

Metal aryl hydrides, n.o

Metal aryl hydrides, wa

reactive, n.o.s.

Metal aryls, n.o.s 

Metal aryls, water-reac

n.o.s.

Metal carbonyls, liquid, 

Metal carbonyls, n.o.s. 

Metal carbonyls, solid, 

Metal catalyst, dry 

Metal catalyst, wetted 

Metaldehyde 

Metal hydrides, flammab

Alpha 97-166 Eng.pmd 3/25/0134
Metal powder, self-heating, n.o.s. 135 3189

Metal salts of organic 133 3181

compounds, flammable, n.o.s.

Methacrylaldehyde, stabilized 131P 2396

Methacrylic acid, stabilized 153P 2531

Methacrylonitrile, stabilized 131P 3079

Methallyl alcohol 129 2614

Methane 115 1971

Methane, compressed 115 1971

Methane, refrigerated liquid 115 1972

(cryogenic liquid)

Methane and Hydrogen mixture, 115 2034

compressed

Methanesulfonyl chloride 156 3246

Methanesulphonyl chloride 156 3246

Methanol 131 1230

Methoxymethyl isocyanate 155 2605

4-Methoxy-4-methyl- 128 2293

pentan-2-one

1-Methoxy-2-propanol 129 3092

Methyl acetate 129 1231

Methylacetylene and 116P 1060

Propadiene mixture,

stabilized

Methyl acrylate, stabilized 129P 1919

Methylal 127 1234

Methyl alcohol 131 1230

Methylallyl chloride 130P 2554

Methyl benzoate 

alpha-Methylbenzy

alpha-Methylbenzy

liquid

alpha-Methylbenzy

solid

Methylbenzyl alcoh

Methyl bromide 

Methyl bromide and 

mixture

Methyl bromide and 

dibromide mixtur

Methyl bromoaceta

2-Methylbutanal 

3-Methylbutan-2-on

2-Methyl-1-butene 

2-Methyl-2-butene 

3-Methyl-1-butene 

N-Methylbutylamin

Methyl tert-butyl et

Methyl butyrate 

Methyl chloride 

Methyl chloride and 

mixture

Methyl chloride and 

chloride mixture

Methyl chloroaceta

Methyl chloroforma

Alpha 97-166 Eng.pmd 3/25/0135
Page 136

Methylcyclohexanone 128 2297

Methylcyclopentane 128 2298

Methyl dichloroacetate 155 2299

Methyldichloroarsine 152 1556

Methyldichlorosilane 139 1242

Methylene chloride 160 1593

Methylene chloride and Methyl 115 1912

chloride mixture

Methyl ethyl ether 115 1039

Methyl ethyl ketone 127 1193

2-Methyl-5-ethylpyridine 153 2300

Methyl fluoride 115 2454

Methyl formate 129 1243

2-Methylfuran 128 2301

2-Methyl-2-heptanethiol 131 3023

5-Methylhexan-2-one 127 2302

Methylhydrazine 131 1244

Methyl iodide 151 2644

Methyl isobutyl carbinol 129 2053

Methyl isobutyl ketone 127 1245

Methyl isocyanate 155 2480

Methyl isopropenyl ketone, 127P 1246

stabilized

Methyl isothiocyanate 131 2477

Methyl isovalerate 130 2400

Methyl magnesium bromide in 135 1928

Ethyl ether

Methyl nitrite 

Methyl orthosilicate 

Methyl parathion, liquid 

Methyl parathion, solid 

Methylpentadiene 

2-Methylpentan-2-ol 

Methylphenyldichloros

Methyl phosphonic dich

Methyl phosphonous di

1-Methylpiperidine 

Methyl propionate 

Methyl propyl ether 

Methyl propyl ketone 

Methyltetrahydrofuran 

Methyl trichloroacetate 

Methyltrichlorosilane 

alpha-Methylvaleraldeh

Methyl valeraldehyde (

Methyl vinyl ketone, sta

M.I.B.C. 

Molybdenum pentachlo

Monoethanolamine 

Mononitrotoluidines 

Monopropylamine 

Morpholine 

Motor fuel anti-knock m

Motor spirit 

Alpha 97-166 Eng.pmd 3/25/0136
Naphthalene, crude 133 1334

Naphthalene, molten 133 2304

Naphthalene, refined 133 1334

alpha-Naphthylamine 153 2077

Naphthylamine (alpha) 153 2077

beta-Naphthylamine 153 1650

beta-Naphthylamine, solid 153 1650

beta-Naphthylamine, solution 153 3411

Naphthylamine (beta) 153 1650

Naphthylamine (beta), solid 153 1650

Naphthylamine (beta), solution 153 3411

Naphthylthiourea 153 1651

Naphthylurea 153 1652

Natural gas, compressed 115 1971

Natural gas, refrigerated liquid 115 1972

(cryogenic liquid)

Neohexane 128 1208

Neon 121 1065

Neon, compressed 121 1065

Neon, refrigerated liquid 120 1913

(cryogenic liquid)

Nickel carbonyl 131 1259

Nickel catalyst, dry 135 2881

Nickel cyanide 151 1653

Nickel nitrate 140 2725

Nickel nitrite 140 2726

Nicotine 151 1654

Nicotine hydrochlor

Nicotine hydrochlor

Nicotine preparatio

n.o.s.

Nicotine preparatio

n.o.s.

Nicotine salicylate 

Nicotine sulfate, so

Nicotine sulfate, so

Nicotine sulfate, so

Nicotine sulphate, s

Nicotine sulphate, s

Nicotine sulphate, s

Nicotine tartrate 

Nitrates, inorganic, 

solution, n.o.s.

Nitrates, inorganic, 

Nitrating acid mixtu

Nitrating acid mixtu

Nitric acid, fuming 

Nitric acid, other th

Nitric acid, red fum

Nitric oxide 

Nitric oxide, compre

Nitric oxide and Din

tetroxide mixture

Nitric oxide and Nit

mixture

Alpha 97-166 Eng.pmd 3/25/0137
Page 138

Nitriles, poisonous, liquid, n.o.s. 151 3276

Nitriles, poisonous, n.o.s. 151 3276

Nitriles, poisonous, solid, n.o.s. 151 3439

Nitriles, toxic, flammable, n.o.s. 131 3275

Nitriles, toxic, liquid, n.o.s. 151 3276

Nitriles, toxic, n.o.s. 151 3276

Nitriles, toxic, solid, n.o.s. 151 3439

Nitrites, inorganic, aqueous 140 3219

solution, n.o.s.

Nitrites, inorganic, n.o.s. 140 2627

Nitroanilines 153 1661

Nitroanisoles 152 2730

Nitroanisoles, liquid 152 2730

Nitroanisoles, solid 152 2730

Nitroanisoles, solid 152 3458

Nitrobenzene 152 1662

Nitrobenzenesulfonic acid 153 2305

Nitrobenzenesulphonic acid 153 2305

Nitrobenzotrifluorides 152 2306

Nitrobenzotrifluorides, liquid 152 2306

Nitrobenzotrifluorides, solid 152 3431

Nitrobromobenzenes 152 2732

Nitrobromobenzenes, liquid 152 2732

Nitrobromobenzenes, solid 152 2732

Nitrobromobenzenes, solid 152 3459

Nitrocellulose 133 2557

Nitrocellulose membrane filters 133 3270

pigment and plasticiz

Nitrocellulose mixture, 

plasticizer

Nitrocellulose, solution

flammable

Nitrocellulose, solution

flammable liquid

Nitrocellulose with alco

Nitrocellulose with not 

25% alcohol

Nitrocellulose with wate

less than 25% water

3-Nitro-4-chlorobenzot

Nitrocresols 

Nitrocresols, liquid 

Nitrocresols, solid 

Nitroethane 

Nitrogen 

Nitrogen, compressed 

Nitrogen, refrigerated l

(cryogenic liquid)

Nitrogen and Rare gase

Nitrogen and Rare gase

mixture, compressed

Nitrogen dioxide 

Nitrogen dioxide and N

mixture

Nitrogen tetroxide and 

oxide mixture

Alpha 97-166 Eng.pmd 3/25/0138
Nitroglycerin, solution in 127 1204

alcohol, with not more than

1% Nitroglycerin

Nitroglycerin mixture, 113 3343

desensitized, liquid, flammable,

n.o.s., with not more than 30%

Nitroglycerin

Nitroglycerin mixture, 113 3357

desensitized, liquid, n.o.s.,

with not more than 30%

Nitroglycerin

Nitroglycerin mixture, 113 3319

desensitized, solid, n.o.s.,

with more than 2% but not more

than 10% Nitroglycerin

Nitroglycerin mixture with more 113 3319

than 2% but not more than 10%

Nitroglycerin, desensitized

Nitroguanidine (Picrite), wetted 113 1336

with not less than 20% water

Nitroguanidine, wetted with not 113 1336

less than 20% water

Nitrohydrochloric acid 157 1798

Nitromethane 129 1261

Nitronaphthalene 133 2538

Nitrophenols 153 1663

4-Nitrophenylhydrazine, with not 113 3376

less than 30% water

Nitropropanes 129 2608

p-Nitrosodimethylaniline 135 1369

Nitrosylsulfuric acid

Nitrosylsulfuric acid

Nitrosylsulfuric acid

Nitrosylsulphuric ac

Nitrosylsulphuric ac

Nitrosylsulphuric ac

Nitrosylsulphuric ac

Nitrotoluenes 

Nitrotoluenes, liqui

Nitrotoluenes, solid 

Nitrotoluenes, solid 

Nitrotoluidines (mo

Nitrous oxide 

Nitrous oxide, comp

Nitrous oxide, refrig

Nitrous oxide and C

dioxide mixture

Nitroxylenes 

Nitroxylenes, liquid 

Nitroxylenes, solid 

Nitroxylenes, solid 

Nonanes 

Nonyltrichlorosilan

2,5-Norbornadiene

Octadecyltrichloros

Octadiene 

Octafluorobut-2-en

Alpha 97-166 Eng.pmd 3/25/0139
Page 140

Oil, petroleum 128 1270

Oil gas 119 1071

Oil gas, compressed 119 1071

Organic peroxide type B, liquid 146 3101

Organic peroxide type B, liquid, 148 3111

temperature controlled

Organic peroxide type B, solid 146 3102

Organic peroxide type B, solid, 148 3112

temperature controlled

Organic peroxide type C, liquid 146 3103

Organic peroxide type C, liquid, 148 3113

temperature controlled

Organic peroxide type C, solid 146 3104

Organic peroxide type C, solid, 148 3114

temperature controlled

Organic peroxide type D, liquid 145 3105

Organic peroxide type D, liquid, 148 3115

temperature controlled

Organic peroxide type D, solid 145 3106

Organic peroxide type D, solid, 148 3116

temperature controlled

Organic peroxide type E, liquid 145 3107

Organic peroxide type E, liquid, 148 3117

temperature controlled

Organic peroxide type E, solid 145 3108

Organic peroxide type E, solid, 148 3118

temperature controlled

Organic peroxide type F, liquid 145 3109

Organic phosphate mix

compressed gas

Organic phosphorus co

mixed with compress

Organic pigments, self-

Organoarsenic compou

liquid, n.o.s.

Organoarsenic compou

Organoarsenic compou

solid, n.o.s.

Organochlorine pestici

flammable, poisonou

Organochlorine pestici

flammable, toxic

Organochlorine pesticid

poisonous

Organochlorine pesticid

poisonous, flammable

Organochlorine pestici

toxic

Organochlorine pestici

toxic, flammable

Organochlorine pestici

poisonous

Organochlorine pesticid

toxic

Organometallic compou

poisonous, liquid, n.o

Organometallic compou

poisonous, n.o.s.

Alpha 97-166 Eng.pmd 3/25/0140
toxic, n.o.s.

Organometallic compound, 151 3467

toxic, solid, n.o.s.

Organometallic compound, 138 3207

water-reactive, flammable, n.o.s.

Organometallic compound 138 3207

dispersion, water-reactive,

flammable, n.o.s.

Organometallic compound 138 3207

solution, water-reactive,

flammable, n.o.s.

Organometallic substance, 135 3392

liquid, pyrophoric

Organometallic substance, 135 3394

liquid, pyrophoric,

water-reactive

Organometallic substance, 135 3398

liquid, water-reactive

Organometallic substance, 138 3399

liquid, water-reactive,

flammable

Organometallic substance, 135 3391

solid, pyrophoric

Organometallic substance, 135 3393

solid, pyrophoric,

water-reactive

Organometallic substance, 138 3400

solid, self-heating

Organometallic substance, 135 3395

solid, water-reactive

poisonous, flamm

Organophosphorus 

poisonous, liquid

Organophosphorus 

poisonous, n.o.s

Organophosphorus 

poisonous, solid, 

Organophosphorus 

toxic, flammable

Organophosphorus 

toxic, liquid, n.o.

Organophosphorus 

toxic, n.o.s.

Organophosphorus 

toxic, solid, n.o.s

Organophosphorus 

liquid, flammable

Organophosphorus 

liquid, flammable

Organophosphorus 

liquid, poisonous

Organophosphorus 

liquid, poisonous

Organophosphorus 

liquid, toxic

Organophosphorus 

liquid, toxic, flam

Organophosphorus 

solid, poisonous

Organophosphorus 

solid, toxic

Alpha 97-166 Eng.pmd 3/25/0141
Page 142

flammable, toxic

Organotin pesticide, liquid, 153 3020

poisonous

Organotin pesticide, liquid, 131 3019

poisonous, flammable

Organotin pesticide, liquid, toxic 153 3020

Organotin pesticide, liquid, 131 3019

toxic, flammable

Organotin pesticide, solid, 153 2786

poisonous

Organotin pesticide, solid, toxic 153 2786

Osmium tetroxide 154 2471

Other regulated substances, 171 3082

liquid, n.o.s.

Other regulated substances, 171 3077

solid, n.o.s.

Oxidizing liquid, corrosive, 140 3098

n.o.s.

Oxidizing liquid, n.o.s. 140 3139

Oxidizing liquid, poisonous, n.o.s. 142 3099

Oxidizing liquid, toxic, n.o.s. 142 3099

Oxidizing solid, corrosive, n.o.s. 140 3085

Oxidizing solid, flammable, 140 3137

n.o.s.

Oxidizing solid, n.o.s. 140 1479

Oxidizing solid, poisonous, 141 3087

n.o.s.

Oxidizing solid, self-heating, 135 3100

n.o.s.

(cryogenic liquid)

Oxygen and Carbon dio

mixture

Oxygen and Carbon dio

mixture, compressed

Oxygen and Rare gases 

Oxygen and Rare gases 

compressed

Oxygen difluoride 

Oxygen difluoride, com

Oxygen generator, che

Oxygen generator, che

spent

Paint (corrosive) 

Paint, corrosive, flamm

Paint (flammable) 

Paint, flammable, corro

Paint related material 

(corrosive)

Paint related material, 

corrosive, flammable

Paint related material 

(flammable)

Paint related material, 

flammable, corrosive

Paper, unsaturated oil t

Paraformaldehyde 

Paraldehyde 

Parathion 

Alpha 97-166 Eng.pmd 3/25/0142
Pentachlorophenol 154 3155

Pentaerythrite tetranitrate 113 3344

mixture,desensitized, solid,

n.o.s., with more than 10%

but not more than 20% PETN

Pentaerythritol tetranitrate 113 3344

mixture, desensitized, solid,

n.o.s., with more than 10%

but not more than 20% PETN

Pentafluoroethane 126 3220

Pentafluoroethane and Ethylene 126 3298

oxide mixture, with not more

than 7.9% Ethylene oxide

Pentamethylheptane 128 2286

Pentan-2,4-dione 131 2310

n-Pentane 128 1265

2,4-Pentanedione 131 2310

Pentane-2,4-dione 131 2310

Pentanes 128 1265

Pentanols 129 1105

1-Pentene 128 1108

1-Pentol 153P 2705

Percarbonates, inorganic, n.o.s. 140 3217

Perchlorates, inorganic, 140 3211

aqueous solution, n.o.s.

Perchlorates, inorganic, n.o.s. 140 1481

Perchloric acid, with more than 143 1873

50% but not more than 72%

acid

Perfluoro(ethyl viny

Perfluoromethyl vin

Perfluoro(methyl vi

Perfumery products

flammable solven

Permanganates, ino

aqueous solution

Permanganates, in

n.o.s.

Peroxides, inorgan

Persulfates, inorga

solution, n.o.s.

Persulfates, inorga

Persulphates, inorg

aqueous solution

Persulphates, inorg

Pesticide, liquid, fla

poisonous, n.o.s.

Pesticide, liquid, fla

toxic, n.o.s.

Pesticide, liquid, po

flammable, n.o.s.

Pesticide, liquid, po

n.o.s.

Pesticide, liquid, to

flammable, n.o.s.

Pesticide, liquid, to

Pesticide, solid, po

Pesticide, solid, po

n.o.s.

Alpha 97-166 Eng.pmd 3/25/0143
Page 144

more than 10% ethanol

Petroleum crude oil 128 1267

Petroleum distillates, n.o.s. 128 1268

Petroleum gases, liquefied 115 1075

Petroleum oil 128 1270

Petroleum products, n.o.s. 128 1268

Phenacyl bromide 153 2645

Phenetidines 153 2311

Phenol, molten 153 2312

Phenol, solid 153 1671

Phenol solution 153 2821

Phenolates, liquid 154 2904

Phenolates, solid 154 2905

Phenolsulfonic acid, liquid 153 1803

Phenolsulphonic acid, liquid 153 1803

Phenoxyacetic acid derivative 131 3346

pesticide, liquid, flammable,

poisonous

Phenoxyacetic acid derivative 131 3346

pesticide, liquid, flammable,

toxic

Phenoxyacetic acid derivative 153 3348

pesticide, liquid, poisonous

Phenoxyacetic acid derivative 131 3347

pesticide, liquid, poisonous,

flammable

Phenoxyacetic acid derivative 153 3348

pesticide, liquid, toxic

Phenoxy pesticide, liqu

flammable, poisonous

Phenoxy pesticide, liqu

flammable, toxic

Phenoxy pesticide, liqu

poisonous

Phenoxy pesticide, liqu

poisonous, flammabl

Phenoxy pesticide, liqu

Phenoxy pesticide, liqu

flammable

Phenoxy pesticide, soli

poisonous

Phenoxy pesticide, sol

Phenylacetonitrile, liqu

Phenylacetyl chloride 

Phenylcarbylamine chlo

Phenyl chloroformate 

Phenylenediamines 

Phenylhydrazine 

Phenyl isocyanate 

Phenyl mercaptan 

Phenylmercuric acetate 

Phenylmercuric compo

n.o.s.

Phenylmercuric hydrox

Phenylmercuric nitrate 

Phenylphosphorus dich

Alpha 97-166 Eng.pmd 3/25/0144
Phenyl urea pesticide, liquid, 151 3002

poisonous

Phenyl urea pesticide, liquid, 131 3001

poisonous, flammable

Phenyl urea pesticide, liquid, 151 3002

toxic

Phenyl urea pesticide, liquid, 131 3001

toxic, flammable

Phenyl urea pesticide, solid, 151 2767

poisonous

Phenyl urea pesticide, solid, 151 2767

toxic

Phosgene 125 1076

9-Phosphabicyclononanes 135 2940

Phosphine 119 2199

Phosphoric acid 154 1805

Phosphoric acid, liquid 154 1805

Phosphoric acid, solid 154 1805

Phosphoric acid, solid 154 3453

Phosphoric acid, solution 154 1805

Phosphorous acid 154 2834

Phosphorous acid, ortho 154 2834

Phosphorus, amorphous 133 1338

Phosphorus, amorphous, red 133 1338

Phosphorus, white, dry or under 136 1381

water or in solution

Phosphorus, white, molten 136 2447

Phosphorus, yellow, dry or under 136 1381

water or in solution

Phosphorus oxybro

Phosphorus oxybro

Phosphorus oxychl

Phosphorus pentab

Phosphorus pentac

Phosphorus pentaf

Phosphorus pentaf

compressed

Phosphorus pentas

from yellow and w

Phosphorus

Phosphorus pentas

from yellow and w

Phosphorus

Phosphorus pentox

Phosphorus sesqui

from yellow and w

Phosphorus

Phosphorus sesqui

free from yellow a

Phosphorus

Phosphorus tribrom

Phosphorus trichlo

Phosphorus trioxide 

Phosphorus trisulfi

yellow and white 

Phosphorus trisulph

from yellow and w

Phosphorus

Phthalic anhydride 

Alpha 97-166 Eng.pmd 3/25/0145
Page 146

pesticide, liquid, poisonous

Phthalimide derivative 131 3007

pesticide, liquid, poisonous,

flammable

Phthalimide derivative 151 3008

pesticide, liquid, toxic

Phthalimide derivative 131 3007

pesticide, liquid, toxic,

flammable

Phthalimide derivative 151 2773

pesticide, solid, poisonous

Phthalimide derivative 151 2773

pesticide, solid, toxic

Picolines 129 2313

Picric acid, wet, with not less 113 1344

than 10% water

Picric acid, wetted with not less 113 3364

than 10% water

Picrite, wetted 113 1336

Picryl chloride, wetted with not 113 3365

less than 10% water

Picric acid, wetted with not 113 1344

less than 30% water

alpha-Pinene 128 2368

Pinene (alpha) 128 2368

Pine oil 129 1272

Piperazine 153 2579

Piperidine 132 2401

Plastic molding compound 171 3314

Poisonous by inhalation 

corrosive, n.o.s. (Inh

Hazard Zone A)

Poisonous by inhalation 

corrosive, n.o.s. (Inh

Hazard Zone B)

Poisonous by inhalation 

flammable, n.o.s. (In

Hazard Zone A)

Poisonous by inhalation 

flammable, n.o.s. (In

Hazard Zone B)

Poisonous by inhalation 

n.o.s. (Inhalation Ha

Zone A)

Poisonous by inhalation 

n.o.s. (Inhalation Ha

Zone B)

Poisonous by inhalation 

oxidizing, n.o.s. (Inh

Hazard Zone A)

Poisonous by inhalation 

oxidizing, n.o.s. (Inh

Hazard Zone B)

Poisonous by inhalation 

water-reactive, n.o.s

(Inhalation Hazard Z

Poisonous by inhalation 

water-reactive, n.o.s

(Inhalation Hazard Z

Poisonous liquid, corro

inorganic, n.o.s.

Alpha 97-166 Eng.pmd 3/25/0146
n.o.s.

Poisonous liquid, corrosive, 154 2927

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, corrosive, 154 2927

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, corrosive, 154 2927

organic, n.o.s.

Poisonous liquid, corrosive, 154 2927

organic, n.o.s. (Inhalation

Hazard Zone A)

Poisonous liquid, corrosive, 154 2927

organic, n.o.s. (Inhalation

Hazard Zone B)

Poisonous liquid, flammable, 131 2929

n.o.s.

Poisonous liquid, flammable, 131 2929

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, flammable, 131 2929

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, flammable, 131 2929

organic, n.o.s.

Poisonous liquid, flammable, 131 2929

organic, n.o.s. (Inhalation

Hazard Zone A)

Poisonous liquid, flammable, 131 2929

organic, n.o.s. (Inhalation

Hazard Zone B)

Poisonous liquid, inorganic, 151 3287

n.o.s.

Poisonous liquid, n

(Inhalation Haza

Poisonous liquid, n

(Inhalation Haza

Poisonous liquid, o

Poisonous liquid, o

(Inhalation Haza

Poisonous liquid, o

(Inhalation Haza

Poisonous liquid, o

n.o.s.

Poisonous liquid, o

n.o.s. (Inhalation 

Zone A)

Poisonous liquid, o

n.o.s. (Inhalation 

Zone B)

Poisonous liquid, w

reactive, n.o.s.

Poisonous liquid, w

reactive, n.o.s. (I

Hazard Zone A)

Poisonous liquid, w

reactive, n.o.s. (I

Hazard Zone B)

Poisonous liquid, w

contact with wate

flammable gases

Poisonous liquid, w

contact with wate

flammable gases

(Inhalation Haza

Alpha 97-166 Eng.pmd 3/25/0147
Page 148

n.o.s.

Poisonous solid, flammable, 134 2930

n.o.s.

Poisonous solid, flammable, 134 2930

organic, n.o.s.

Poisonous solid, inorganic, 151 3288

n.o.s.

Poisonous solid, organic, n.o.s. 154 2811

Poisonous solid, oxidizing, 141 3086

n.o.s.

Poisonous solid, self-heating, 136 3124

n.o.s.

Poisonous solid, water-reactive, 139 3125

n.o.s.

Poisonous solid, which in 139 3125

contact with water emits

flammable gases, n.o.s.

Polyalkylamines, n.o.s. 132 2733

Polyalkylamines, n.o.s. 132 2734

Polyalkylamines, n.o.s. 153 2735

Polyamines, flammable, 132 2733

corrosive, n.o.s.

Polyamines, liquid, corrosive, 132 2734

flammable, n.o.s.

Polyamines, liquid, corrosive, 153 2735

n.o.s.

Polyamines, solid, corrosive, 154 3259

n.o.s.

Polychlorinated biphenyls 171 2315

Polychlorinated biphenyls, liquid 171 2315

solid

Polyhalogenated terphe

liquid

Polyhalogenated terphe

solid

Polymeric beads, expa

Polystyrene beads, exp

Potassium 

Potassium, metal 

Potassium, metal alloys 

Potassium, metal alloys

Potassium, metal alloys

Potassium arsenate 

Potassium arsenite 

Potassium borohydride 

Potassium bromate 

Potassium chlorate 

Potassium chlorate, aq

solution

Potassium chlorate, so

Potassium cuprocyanid

Potassium cyanide 

Potassium cyanide, sol

Potassium cyanide, sol

Potassium dithionite 

Potassium fluoride 

Potassium fluoride, sol

Potassium fluoride, sol

Alpha 97-166 Eng.pmd 3/25/0148
solution

Potassium hydrogen sulfate 154 2509

Potassium hydrogen sulphate 154 2509

Potassium hydrosulfite 135 1929

Potassium hydrosulphite 135 1929

Potassium hydroxide, dry, solid 154 1813

Potassium hydroxide, flake 154 1813

Potassium hydroxide, solid 154 1813

Potassium hydroxide, solution 154 1814

Potassium metavanadate 151 2864

Potassium monoxide 154 2033

Potassium nitrate 140 1486

Potassium nitrate and Sodium 140 1499

nitrate mixture

Potassium nitrate and Sodium 140 1487

nitrite mixture

Potassium nitrite 140 1488

Potassium perchlorate 140 1489

Potassium permanganate 140 1490

Potassium peroxide 144 1491

Potassium persulfate 140 1492

Potassium persulphate 140 1492

Potassium phosphide 139 2012

Potassium silicofluoride 151 2655

Potassium sodium alloys 138 1422

Potassium sodium alloys, liquid 138 1422

Potassium sodium alloys, solid 138 3404

Potassium sulfide, anhydrous 135 1382

30% water of crys

Potassium sulfide, 

30% water of hyd

Potassium sulphide

Potassium sulphide

with not less than 

of crystallization

Potassium sulphide

with not less than 

of hydration

Potassium sulphide

than 30% water o

crystallization

Potassium sulphide

than 30% water o

Potassium superox

Printing ink, flamma

Printing ink related 

Propadiene, stabili

Propadiene and 

Methylacetylene 

stabilized

Propane 

Propane 

Propane-Ethane mi

refrigerated liquid

Propane mixture 

Propane mixture 

Propanethiols 

n-Propanol 

Alpha 97-166 Eng.pmd 3/25/0149
Page 150

Propionic acid, with not less 132 3463

than 90% acid

Propionic anhydride 156 2496

Propionitrile 131 2404

Propionyl chloride 132 1815

n-Propyl acetate 129 1276

normal Propyl alcohol 129 1274

Propyl alcohol, normal 129 1274

Propylamine 132 1277

n-Propyl benzene 128 2364

Propyl chloride 129 1278

n-Propyl chloroformate 155 2740

Propylene 115 1075

Propylene 115 1077

Propylene, Ethylene and 115 3138

Acetylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

Propylene chlorohydrin 131 2611

1,2-Propylenediamine 132 2258

1,3-Propylenediamine 132 2258

Propylene dichloride 130 1279

Propyleneimine, stabilized 131P 1921

Propylene oxide 127P 1280

Propylene oxide and Ethylene 129P 2983

oxide mixture, with not more

than 30% Ethylene oxide

flammable, poisonou

Pyrethroid pesticide, liq

flammable, toxic

Pyrethroid pesticide, liq

poisonous

Pyrethroid pesticide, liq

poisonous, flammable

Pyrethroid pesticide, liq

Pyrethroid pesticide, liq

flammable

Pyrethroid pesticide, so

poisonous

Pyrethroid pesticide, so

Pyridine 

Pyrophoric alloy, n.o.s. 

Pyrophoric liquid, inorg

n.o.s.

Pyrophoric liquid, n.o.s

Pyrophoric liquid, orga

Pyrophoric metal, n.o.s

Pyrophoric organometa

compound, n.o.s.

Pyrophoric organometa

compound, water-rea

n.o.s.

Pyrophoric solid, inorga

n.o.s.

Pyrophoric solid, n.o.s. 

Pyrophoric solid, organ

Alpha 97-166 Eng.pmd 3/25/0150
from depleted Uranium

Radioactive material, excepted 161 2910

package, articles manufactured

from depleted Uranium

Radioactive material, excepted 161 2909

package, articles manufactured

from natural Thorium

Radioactive material, excepted 161 2910

package, articles manufactured

from natural Thorium

Radioactive material, excepted 161 2909

package, articles manufactured

from natural Uranium

Radioactive material, excepted 161 2910

package, articles manufactured

from natural Uranium

Radioactive material, excepted 161 2908

package, empty packaging

Radioactive material, excepted 161 2910

package, empty packaging

Radioactive material, excepted 161 2910

package, instruments or

articles

Radioactive material, excepted 161 2911

package, instruments or

articles

Radioactive material, excepted 161 2910

package, limited quantity of

material

Radioactive material, fissile, 165 2918

n.o.s.

Radioactive material, low 162 2912

specific activity (LSA), n.o.s.

non fissile or fiss

Radioactive materia

specific activity (

Radioactive materia

specific activity (

non fissile or fiss

Radioactive materia

Radioactive materia

form, n.o.s.

Radioactive materia

contaminated obj

Radioactive materia

contaminated obj

(SCO-I), fissile

Radioactive materia

contaminated obj

non fissile or fiss

Radioactive materia

contaminated obj

(SCO-II), fissile

Radioactive materia

contaminated obj

non fissile or fiss

Radioactive materia

transported unde

arrangement, fis

Radioactive materia

transported unde

arrangement non 

fissile-excepted

Radioactive materia

package, fissile, 

form

Alpha 97-166 Eng.pmd 3/25/0151
Page 152

non fissile or fissile-excepted

Radioactive material, Type B(M) 165 3329

package, fissile

Radioactive material, Type B(M) 163 2917

package non fissile or

fissile-excepted

Radioactive material, Type B(U) 165 3328

package, fissile

Radioactive material, Type B(U) 163 2916

package non fissile or

fissile-excepted

Radioactive material, Type C 163 3323

package

Radioactive material, Type C 165 3330

package, fissile

Radioactive material, Uranium 166 2978

hexafluoride

Radioactive material, Uranium 166 2977

hexafluoride, fissile

Rags, oily 133 1856

Rare gases and Nitrogen mixture 121 1981

Rare gases and Nitrogen 121 1981

mixture, compressed

Rare gases and Oxygen mixture 121 1980

Rare gases and Oxygen mixture, 121 1980

compressed

Rare gases mixture 121 1979

Rare gases mixture, compressed 121 1979

Receptacles, small, containing 115 2037

gas

Refrigerant gas R-12 an

Refrigerant gas R-152

azeotropic mixture w

Refrigerant gas R-12

Refrigerant gas R-12B1 

Refrigerant gas R-13 

Refrigerant gas R-13 an

Refrigerant gas R-23

azeotropic mixture w

Refrigerant gas R-13

Refrigerant gas R-13B1 

Refrigerant gas R-14 

Refrigerant gas R-14, 

compressed

Refrigerant gas R-21 

Refrigerant gas R-22 

Refrigerant gas R-23 

Refrigerant gas R-23 an

Refrigerant gas R-13

azeotropic mixture w

Refrigerant gas R-13

Refrigerant gas R-32 

Refrigerant gas R-40 

Refrigerant gas R-41 

Refrigerant gas R-114 

Refrigerant gas R-115 

Refrigerant gas R-116 

Refrigerant gas R-116, 

compressed

Refrigerant gas R-124 

Alpha 97-166 Eng.pmd 3/25/0152
Refrigerant gas R-152a and 126 2602

Refrigerant gas R-12

azeotropic mixture with 74%

Refrigerant gas R-12

Refrigerant gas R-161 115 2453

Refrigerant gas R-218 126 2424

Refrigerant gas R-227 126 3296

Refrigerant gas R-404A 126 3337

Refrigerant gas R-407A 126 3338

Refrigerant gas R-407B 126 3339

Refrigerant gas R-407C 126 3340

Refrigerant gas R-500 126 2602

(azeotropic mixture of

Refrigerant gas R-12 and

Refrigerant gas R-152a with

approximately 74%

Refrigerant gas R-12)

Refrigerant gas R-502 126 1973

Refrigerant gas R-503 126 2599

(azeotropic mixture of

Refrigerant gas R-13 and

Refrigerant gas R-23 with

approximately 60%

Refrigerant gas R-13)

Refrigerant gas R-1132a 116P 1959

Refrigerant gas R-1216 126 1858

Refrigerant gas R-1318 126 2422

Refrigerant gas RC-318 126 1976

Refrigerating machine 128 1993

Refrigerating mach

containing flamm

non-poisonous, l

Refrigerating machin

flammable, non-t

gases

Refrigerating mach

containing non-fla

non-poisonous g

Refrigerating mach

containing non-fl

non-toxic gases

Regulated medical 

Resin solution 

Resorcinol 

Rosin oil 

Rubber scrap, powd

granulated

Rubber shoddy, pow

granulated

Rubber solution 

Rubidium 

Rubidium hydroxide 

Rubidium hydroxide

Rubidium hydroxide

Rubidium metal 

SA 

Sarin 

Seat-belt modules 

Seat-belt pre-tensio

Alpha 97-166 Eng.pmd 3/25/0153
Page 154

Seed cake, with not more than 135 2217

1.5% oil and not more than

11% moisture

Selenates 151 2630

Selenic acid 154 1905

Selenites 151 2630

Selenium compound, liquid, 151 3440

n.o.s.

Selenium compound, n.o.s. 151 3283

Selenium compound, solid, 151 3283

n.o.s.

Selenium disulfide 153 2657

Selenium disulphide 153 2657

Selenium hexafluoride 125 2194

Selenium oxide 154 2811

Selenium oxychloride 157 2879

Selenium powder 152 2658

Self-defense spray, non- 171 3334

pressurized

Self-heating liquid, corrosive, 136 3188

inorganic, n.o.s.

Self-heating liquid, corrosive, 136 3185

organic, n.o.s.

Self-heating liquid, inorganic, 135 3186

n.o.s.

Self-heating liquid, organic, 135 3183

n.o.s.

Self-heating liquid, poisonous, 136 3187

inorganic, n.o.s.

n.o.s.

Self-heating solid, corr

inorganic, n.o.s.

Self-heating solid, corr

organic, n.o.s.

Self-heating solid, inorg

n.o.s.

Self-heating solid, inor

poisonous, n.o.s.

Self-heating solid, inor

toxic, n.o.s.

Self-heating solid, orga

n.o.s.

Self-heating solid, oxid

n.o.s.

Self-heating solid, poiso

inorganic, n.o.s.

Self-heating solid, pois

organic, n.o.s.

Self-heating solid, toxic

inorganic, n.o.s.

Self-heating solid, toxic

organic, n.o.s.

Self-reactive liquid type 

Self-reactive liquid type 

temperature controll

Self-reactive liquid type 

Self-reactive liquid type 

temperature controll

Self-reactive liquid type 

Alpha 97-166 Eng.pmd 3/25/0154
Selfreactive liquid type F, 150 3239

temperature controlled

Self-reactive solid type B 149 3222

Self-reactive solid type B, 150 3232

temperature controlled

Self-reactive solid type C 149 3224

Self-reactive solid type C, 150 3234

temperature controlled

Self-reactive solid type D 149 3226

Self-reactive solid type D, 150 3236

temperature controlled

Self-reactive solid type E 149 3228

Self-reactive solid type E, 150 3238

temperature controlled

Self-reactive solid type F 149 3230

Self-reactive solid type F, 150 3240

temperature controlled

Shale oil 128 1288

Silane 116 2203

Silicofluorides, n.o.s. 151 2856

Silane, compressed 116 2203

Silicon powder, amorphous 170 1346

Silicon tetrachloride 157 1818

Silicon tetrafluoride 125 1859

Silicon tetrafluoride, 125 1859

compressed

Silver arsenite 151 1683

Silver cyanide 151 1684

Silver nitrate 140 1493

Sodium 

Sodium aluminate, 

Sodium aluminate, 

Sodium aluminum h

Sodium ammonium 

Sodium arsanilate 

Sodium arsenate 

Sodium arsenite, aq

solution

Sodium arsenite, so

Sodium azide 

Sodium bisulfate, so

Sodium bisulphate, 

Sodium borohydrid

Sodium borohydrid

hydroxide solutio

more than 12% S

borohydride and 

than 40% Sodium 

Sodium bromate 

Sodium cacodylate 

Sodium carbonate p

Sodium chlorate 

Sodium chlorate, aq

solution

Sodium chlorite 

Sodium chlorite, so

more than 5% av

Chlorine

Alpha 97-166 Eng.pmd 3/25/0155
Page 156

Sodium dichloroisocyanurate 140 2465

Sodium dichloro-s-triazinetrione 140 2465

Sodium dinitro-o-cresolate, 113 3369

wetted with not less than 10%

water

Sodium dinitro-o-cresolate, 113 1348

wetted with not less than 15%

water

Sodium dinitro-ortho-cresolate, 113 1348

wetted

Sodium dithionite 135 1384

Sodium fluoride 154 1690

Sodium fluoride, solid 154 1690

Sodium fluoride, solution 154 3415

Sodium fluoroacetate 151 2629

Sodium fluorosilicate 154 2674

Sodium hydride 138 1427

Sodium hydrogendifluoride 154 2439

Sodium hydrogen sulfate, 154 2837

solution

Sodium hydrogen sulphate, 154 2837

solution

Sodium hydrosulfide, solid, 135 2318

with less than 25% water of

crystallization

Sodium hydrosulfide, solution 154 2922

Sodium hydrosulfide, with less 135 2318

than 25% water of

crystallization

Sodium hydrosulphide, 

Sodium hydrosulphide, 

than 25% water of

crystallization

Sodium hydrosulphide, 

less than 25% water 

crystallization

Sodium hydrosulphite 

Sodium hydroxide, bea

Sodium hydroxide, dry 

Sodium hydroxide, flak

Sodium hydroxide, gran

Sodium hydroxide, soli

Sodium hydroxide, solu

Sodium methylate 

Sodium methylate, dry 

Sodium methylate, solu

alcohol

Sodium monoxide 

Sodium nitrate 

Sodium nitrate and Pot

nitrate mixture

Sodium nitrite 

Sodium nitrite and Pota

nitrate mixture

Sodium pentachlorophen

Sodium perborate 

monohydrate

Alpha 97-166 Eng.pmd 3/25/0156
Sodium persulfate 140 1505

Sodium persulphate 140 1505

Sodium phosphide 139 1432

Sodium picramate, wetted with 113 1349

not less than 20% water

Sodium potassium alloys 138 1422

Sodium potassium alloys, liquid 138 1422

Sodium potassium alloys, solid 138 3404

Sodium selenite 151 2630

Sodium silicofluoride 154 2674

Sodium sulfide, anhydrous 135 1385

Sodium sulfide, hydrated, with 153 1849

not less than 30% water

Sodium sulfide, with less than 135 1385

30% water of crystallization

Sodium sulphide, anhydrous 135 1385

Sodium sulphide, hydrated, with 153 1849

not less than 30% water

Sodium sulphide, with less than 135 1385

30% water of crystallization

Sodium superoxide 143 2547

Solids containing corrosive 154 3244

liquid, n.o.s.

Solids containing flammable 133 3175

liquid, n.o.s.

Solids containing poisonous 151 3243

liquid, n.o.s.

Solids containing toxic liquid, 151 3243

n.o.s.

Soman 153 2810

Strontium arsenite 

Strontium chlorate 

Strontium chlorate, 

Strontium chlorate, 

Strontium nitrate 

Strontium perchlora

Strontium peroxide 

Strontium phosphid

Strychnine 

Strychnine salts 

Styrene monomer, 

Substituted nitroph

pesticide, liquid, f

poisonous

Substituted nitroph

pesticide, liquid, 

toxic

Substituted nitrophe

pesticide, liquid, 

Substituted nitrophe

pesticide, liquid, 

flammable

Substituted nitrophe

pesticide, liquid, 

Substituted nitroph

pesticide, liquid, 

flammable

Substituted nitroph

pesticide, solid, p

Alpha 97-166 Eng.pmd 3/25/0157
Page 158

Sulfur dioxide 125 1079

Sulfur hexafluoride 126 1080

Sulfuric acid 137 1830

Sulfuric acid, fuming 137 1831

Sulfuric acid, fuming, with less 137 1831

than 30% free Sulfur trioxide

Sulfuric acid, fuming, with not 137 1831

less than 30% free Sulfur

trioxide

Sulfuric acid, spent 137 1832

Sulfuric acid, with more than 137 1830

51% acid

Sulfuric acid, with not more than 157 2796

51% acid

Sulfuric acid and Hydrofluoric 157 1786

acid mixture

Sulfurous acid 154 1833

Sulfur tetrafluoride 125 2418

Sulfur trioxide, inhibited 137 1829

Sulfur trioxide, stabilized 137 1829

Sulfur trioxide, uninhibited 137 1829

Sulfur trioxide and 137 1754

Chlorosulfonic acid mixture

Sulfuryl chloride 137 1834

Sulfuryl fluoride 123 2191

Sulphamic acid 154 2967

Sulphur 133 1350

Sulphur, molten 133 2448

Sulphur chlorides 137 1828

Sulphuric acid, fuming, 

less than 30% free S

trioxide

Sulphuric acid, spent 

Sulphuric acid, with mo

51% acid

Sulphuric acid, with not 

than 51% acid

Sulphuric acid and Hyd

acid mixture

Sulphurous acid 

Sulphur tetrafluoride 

Sulphur trioxide, inhibit

Sulphur trioxide, stabili

Sulphur trioxide, uninh

Sulphur trioxide and 

Chlorosulphonic acid 

Sulphuryl chloride 

Sulphuryl fluoride 

Tabun 

Tars, liquid 

Tear gas candles 

Tear gas devices 

Tear gas grenades 

Tear gas substance, liq

n.o.s.

Tear gas substance, so

Tear gas substance, so

Alpha 97-166 Eng.pmd 3/25/0158
Tetrachloroethane 151 1702

Tetrachloroethylene 160 1897

Tetraethyl dithiopyrophosphate 153 1704

Tetraethyl dithiopyrophosphate, 153 1704

mixture, dry or liquid

Tetraethylenepentamine 153 2320

Tetraethyl lead, liquid 131 1649

Tetraethyl pyrophosphate, liquid 152 3018

Tetraethyl pyrophosphate, solid 152 2783

Tetraethyl silicate 129 1292

1,1,1,2-Tetrafluoroethane 126 3159

Tetrafluoroethane and Ethylene 126 3299

oxide mixture, with not more

than 5.6% Ethylene oxide

Tetrafluoroethylene, stabilized 116P 1081

Tetrafluoromethane 126 1982

Tetrafluoromethane, 126 1982

compressed

1,2,3,6-Tetrahydro- 129 2498

benzaldehyde

Tetrahydrofuran 127 2056

Tetrahydrofurfurylamine 129 2943

Tetrahydrophthalic anhydrides 156 2698

1,2,3,6-Tetrahydropyridine 129 2410

1,2,5,6-Tetrahydropyridine 129 2410

Tetrahydrothiophene 130 2412

Tetramethylammonium 153 1835

hydroxide

Tetrapropyl orthotit

Textile waste, wet 

Thallium chlorate 

Thallium compound

Thallium nitrate 

Thallium sulfate, so

Thallium sulphate, 

4-Thiapentanal 

Thia-4-pentanal 

Thickened GD 

Thioacetic acid 

Thiocarbamate pes

flammable, poiso

Thiocarbamate pest

flammable, toxic

Thiocarbamate pes

poisonous

Thiocarbamate pes

poisonous, flamm

Thiocarbamate pes

toxic

Thiocarbamate pes

toxic, flammable

Thiocarbamate pes

poisonous

Thiocarbamate pes

toxic

Thioglycol 

Thioglycolic acid 

Alpha 97-166 Eng.pmd 3/25/0159
Page 160

Thorium metal, pyrophoric 162 2975

Thorium nitrate, solid 162 2976

Tinctures, medicinal 127 1293

Tin tetrachloride 137 1827

Tin tetrachloride, pentahydrate 154 2440

Titanium disulfide 135 3174

Titanium disulphide 135 3174

Titanium hydride 170 1871

Titanium powder, dry 135 2546

Titanium powder, wetted with 170 1352

not less than 25% water

Titanium sponge granules 170 2878

Titanium sponge powders 170 2878

Titanium sulfate, solution 154 1760

Titanium sulphate, solution 154 1760

Titanium tetrachloride 137 1838

Titanium trichloride, pyrophoric 135 2441

Titanium trichloride mixture 157 2869

Titanium trichloride mixture, 135 2441

pyrophoric

TNT, wetted with not less than 113 3366

10% water

TNT, wetted with not less than 113 1356

30% water

Toe puffs, nitrocellulose base 133 1353

Toluene 130 1294

2,4-Toluenediamine 151 1709

2,4-Toluylenediamine, 

2,4-Toluylenediamine, 

Toxic by inhalation liqu

corrosive, n.o.s. (Inh

Hazard Zone A)

Toxic by inhalation liqu

corrosive, n.o.s. (Inh

Hazard Zone B)

Toxic by inhalation liqu

flammable, n.o.s. (In

Hazard Zone A)

Toxic by inhalation liqu

flammable, n.o.s. (In

Hazard Zone B)

Toxic by inhalation liqu

(Inhalation Hazard Z

Toxic by inhalation liqu

(Inhalation Hazard Z

Toxic by inhalation liqu

oxidizing, n.o.s. (Inh

Hazard Zone A)

Toxic by inhalation liqu

oxidizing, n.o.s. (Inh

Hazard Zone B)

Toxic by inhalation liqu

water-reactive, n.o.s

(Inhalation Hazard Z

Toxic by inhalation liqu

water-reactive, n.o.s

(Inhalation Hazard Z

Toxic liquid, corrosive, 

inorganic, n.o.s.

Alpha 97-166 Eng.pmd 3/25/0160
Toxic liquid, corrosive, n.o.s. 154 2927

(Inhalation Hazard Zone A)

Toxic liquid, corrosive, n.o.s. 154 2927

(Inhalation Hazard Zone B)

Toxic liquid, corrosive, organic, 154 2927

n.o.s.

Toxic liquid, corrosive, organic, 154 2927

n.o.s. (Inhalation Hazard

Zone A)

Toxic liquid, corrosive, organic, 154 2927

n.o.s. (Inhalation Hazard

Zone B)

Toxic liquid, flammable, n.o.s. 131 2929

Toxic liquid, flammable, n.o.s. 131 2929

(Inhalation Hazard Zone A)

Toxic liquid, flammable, n.o.s. 131 2929

(Inhalation Hazard Zone B)

Toxic liquid, flammable, organic, 131 2929

n.o.s.

Toxic liquid, flammable, organic, 131 2929

n.o.s. (Inhalation Hazard

Zone A)

Toxic liquid, flammable, organic, 131 2929

n.o.s. (Inhalation Hazard

Zone B)

Toxic liquid, inorganic, n.o.s. 151 3287

Toxic liquid, inorganic, n.o.s. 151 3287

(Inhalation Hazard Zone A)

Toxic liquid, inorganic, n.o.s. 151 3287

(Inhalation Hazard Zone B)

q, g

(Inhalation Haza

Toxic liquid, organi

(Inhalation Haza

Toxic liquid, oxidizi

Toxic liquid, oxidizi

(Inhalation Haza

Toxic liquid, oxidizi

(Inhalation Haza

Toxic liquid, water-

n.o.s.

Toxic liquid, water-

n.o.s. (Inhalation 

Zone A)

Toxic liquid, water-

n.o.s. (Inhalation 

Zone B)

Toxic liquid, which 

with water emits 

gases, n.o.s.

Toxic liquid, which 

with water emits 

gases, n.o.s. (Inh

Hazard Zone A)

Toxic liquid, which 

with water emits 

gases, n.o.s. (Inh

Hazard Zone B)

Toxic solid, corrosi

n.o.s.

Toxic solid, corrosi

n.o.s.

Toxic solid, flamma

Alpha 97-166 Eng.pmd 3/25/0161
Page 162

Toxic solid, water-reactive, 139 3125

n.o.s.

Toxic solid, which in contact with 139 3125

water emits flammable gases,

n.o.s.

Toxins 153 ——

Toxins, extracted from living 153 3172

sources, liquid, n.o.s.

Toxins, extracted from living 153 3172

sources, n.o.s.

Toxins, extracted from living 153 3172

sources, solid, n.o.s.

Toxins, extracted from living 153 3462

sources, solid, n.o.s.

Triallylamine 132 2610

Triallyl borate 156 2609

Triazine pesticide, liquid, 131 2764

flammable, poisonous

Triazine pesticide, liquid, 131 2764

flammable, toxic

Triazine pesticide, liquid, 151 2998

poisonous

Triazine pesticide, liquid, 131 2997

poisonous, flammable

Triazine pesticide, liquid, toxic 151 2998

Triazine pesticide, liquid, toxic, 131 2997

flammable

Triazine pesticide, solid, 151 2763

poisonous

Triazine pesticide, solid, toxic 151 2763

Trichloroacetic acid, so

Trichloroacetyl chloride 

Trichlorobenzenes, liqu

Trichlorobutene 

1,1,1-Trichloroethane 

Trichloroethylene 

Trichloroisocyanuric ac

Trichlorosilane 

(mono)-(Trichloro)-tetr

(monopotassium dich

penta-s-triazinetrione

Tricresyl phosphate 

Triethylamine 

Triethylenetetramine 

Triethyl phosphite 

Trifluoroacetic acid 

Trifluoroacetyl chloride 

Trifluorochloroethylene

stabilized

1,1,1-Trifluoroethane 

Trifluoroethane, compr

Trifluoromethane 

Trifluoromethane, refrig

liquid

Trifluoromethane and 

Chlorotrifluorometha

azeotropic mixture w

approximately 60%

Chlorotrifluorometha

Alpha 97-166 Eng.pmd 3/25/0162
Trimethylamine, anhydrous 118 1083

Trimethylamine, aqueous 132 1297

solution

1,3,5-Trimethylbenzene 129 2325

Trimethyl borate 129 2416

Trimethylchlorosilane 155 1298

Trimethylcyclohexylamine 153 2326

Trimethylhexamethylenediamines 153 2327

Trimethylhexamethylene 156 2328

diisocyanate

Trimethyl phosphite 130 2329

Trinitrobenzene, wetted with not 113 3367

less than 10% water

Trinitrobenzene, wetted with not 113 1354

less than 30% water

Trinitrobenzoic acid, wetted with 113 3368

not less than 10% water

Trinitrobenzoic acid, wetted with 113 1355

not less than 30% water

Trinitrochlorobenzene, wetted 113 3365

with not less than 10% water

Trinitrophenol, wetted with not 113 3364

less than 10% water

Trinitrophenol, wetted with not 113 1344

less than 30% water

Trinitrotoluene, wetted with not 113 3366

less than 10% water

Trinitrotoluene, wetted with not 113 1356

less than 30% water

Tripropylamine 132 2260

Undecane 

Uranium hexafluori

Uranium hexafluori

containing more 

Uranium-235

Uranium hexafluori

non fissile or fiss

Uranium metal, pyr

Uranyl nitrate, hexa

solution

Uranyl nitrate, solid 

Urea hydrogen pero

Urea nitrate, wetted 

than 10% water

Urea nitrate, wetted 

than 20% water

Valeraldehyde 

Valeryl chloride 

Vanadium compoun

Vanadium oxytrichl

Vanadium pentoxid

Vanadium tetrachlo

Vanadium trichlorid

Vanadyl sulfate 

Vanadyl sulphate 

Vehicle, flammable 

Vehicle, flammable 

powered

Vinyl acetate, stabi

Alpha 97-166 Eng.pmd 3/25/0163
Page 164

Vinylidene chloride, stabilized 130P 1303

Vinyl isobutyl ether, stabilized 127P 1304

Vinyl methyl ether, stabilized 116P 1087

Vinylpyridines, stabilized 131P 3073

Vinyltoluenes, stabilized 130P 2618

Vinyltrichlorosilane 155P 1305

Vinyltrichlorosilane, stabilized 155P 1305

VX 153 2810

Water-reactive liquid, corrosive, 138 3129

n.o.s.

Water-reactive liquid, n.o.s. 138 3148

Water-reactive liquid, 139 3130

poisonous, n.o.s.

Water-reactive liquid, toxic, 139 3130

n.o.s.

Water-reactive solid, corrosive, 138 3131

n.o.s.

Water-reactive solid, flammable, 138 3132

n.o.s.

Water-reactive solid, n.o.s. 138 2813

Water-reactive solid, oxidizing, 138 3133

n.o.s.

Water-reactive solid, poisonous, 139 3134

n.o.s.

Water-reactive solid, self- 138 3135

heating, n.o.s.

Water-reactive solid, toxic, n.o.s. 139 3134

Wheelchair, electric, with 154 3171

batteries

Wool waste, wet 

Xanthates 

Xenon 

Xenon, compressed 

Xenon, refrigerated liqu

(cryogenic liquid)

Xylenes 

Xylenols 

Xylenols, liquid 

Xylenols, solid 

Xylidines 

Xylidines, liquid 

Xylidines, solid 

Xylidines, solid 

Xylyl bromide 

Xylyl bromide, liquid 

Xylyl bromide, solid 

Yellow phosphorus, dry 

Yellow phosphorus, in s

Yellow phosphorus, mo

Yellow phosphorus, und

Zinc ammonium nitrite 

Zinc arsenate 

Zinc arsenate and Zinc 

mixture

Zinc arsenite 

Zinc arsenite and Zinc a

mixture

Alpha 97-166 Eng.pmd 3/25/0164
Zinc dithionite 171 1931

Zinc dross 138 1435

Zinc dust 138 1436

Zinc fluorosilicate 151 2855

Zinc hydrosulfite 171 1931

Zinc hydrosulphite 171 1931

Zinc nitrate 140 1514

Zinc permanganate 140 1515

Zinc peroxide 143 1516

Zinc phosphide 139 1714

Zinc powder 138 1436

Zinc residue 138 1435

Zinc resinate 133 2714

Zinc silicofluoride 151 2855

Zinc skimmings 138 1435

Zirconium, dry, coiled wire, 170 2858

finished metal sheets or strips

Zirconium, dry, finished sheets, 135 2009

strips or coiled wire

Zirconium hydride 138 1437

Zirconium metal, liquid 170 1308

suspension

Zirconium metal, powder, wet 170 1358

Zirconium nitrate 140 2728

Zirconium picramate, wetted 113 1517

with not less than 20% water

Zirconium powder, dry 135 2008

flammable liquid

Zirconium suspend

(flammable)

Zirconium tetrachlo

Alpha 97-166 Eng.pmd 3/25/0165
Page 166

Alpha 97-166 Eng.pmd 3/25/0166
GUIDES

GuidePages 167_291 Eng.pmd 3/25/0167
Page 168

• Ruptured cylinders may rocket.

HEALTH

• Inhalation, ingestion or contact with substance may cause severe inj

disease or death.

• High concentration of gas may cause asphyxiation without warning.

• Contact may cause burns to skin and eyes.

• Fire or contact with water may produce irritating, toxic and/or corros

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters' protective clothing provides limited protection i

ONLY; it may not be effective in spill situations.

EVACUATION

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0168
• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Cool containers with flooding quantities of water until well after fire 

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Keep combustibles (wood, paper, oil, etc.) away from spilled mate

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined area

Small Spill • Take up with sand or other non-combustible absorbent 

containers for later disposal.

Large Spill • Dike far ahead of liquid spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Shower and wash with soap and water.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0169
Page 170

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in 

• Move people out of line of sight of the scene and away from windows.

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protec

EVACUATION

Large Spill

• Consider initial evacuation for 800 meters (1/2 mile) in all directions

Fire

• If rail car or trailer is involved in a fire and heavily encased explosives s

artillery projectiles are suspected, ISOLATE for 1600 meters (1 mile) in 

initiate evacuation including emergency responders for 1600 meters (1 

directions.

• When heavily encased explosives are not involved, evacuate the area f

(1/2 mile) in all directions.

* For information on "Compatibility Group" letters

refer to the Glossary section.

GuidePages 167_291 Eng.pmd 3/25/0170
TIRE or VEHICLE Fire

• Use plenty of water - FLOOD it! If water is not available, use CO

• If possible, and WITHOUT RISK, use unmanned hose holders or m

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by 

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (

DETONATORS.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

* For information on "Compatibility Group" lett

refer to the Glossary section.

GuidePages 167_291 Eng.pmd 3/25/0171
Page 172

Runoff to sewer may create fire or explosion hazard.

HEALTH

• Some are toxic and may be fatal if inhaled, swallowed or absorbed throu

• Contact may cause burns to skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• Isolate spill or leak area immediately for at least 100 meters (330 feet) i

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited prote

EVACUATION

Large Spill

• Consider initial evacuation for 500 meters (1/3 mile) in all direction

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0172
TIRE or VEHICLE Fire

• Use plenty of water - FLOOD it! If water is not available, use CO

• If possible, and WITHOUT RISK, use unmanned hose holders or m

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by 

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

Small Spill

• Flush area with flooding quantities of water.

Large Spill

• Wet down with water and dike for later disposal.

• KEEP “WETTED” PRODUCT WET BY SLOWLY ADDING FLOODIN

WATER.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0173
Page 174

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• Isolate spill or leak area immediately for at least 100 meters (330 feet) in 

• Move people out of line of sight of the scene and away from windows.

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protec

EVACUATION

Large Spill

• Consider initial evacuation for 250 meters (800 feet) in all direction

Fire

• If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile

also initiate evacuation including emergency responders for 500 meters 

directions.

* For information on "Compatibility Group" letter

refer to the Glossary section.

GuidePages 167_291 Eng.pmd 3/25/0174
TIRE or VEHICLE Fire

• Use plenty of water - FLOOD it! If water is not available, use CO

• If possible, and WITHOUT RISK, use unmanned hose holders or m

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by 

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (

DETONATORS.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

SUPPLEMENTAL INFORMATIO

• Packages bearing the 1.4S label or packages containing materia

designed or packaged in such a manner that when involved in a fire

with localized detonations and projection of fragments.

• Effects are usually confined to immediate vicinity of packages.

• If fire threatens cargo area containing packages bearing the 1.4S la

containing material classified as 1.4S, consider isolating at least 1

directions. Fight fire with normal precautions from a reasonable dis

* For information on "Compatibility Group" let

refer to the Glossary section.

GuidePages 167_291 Eng.pmd 3/25/0175
Page 176

(UN1966) and Methane (UN1971) are lighter than air and will rise. H

Deuterium fires are difficult to detect since they burn with an invisi

an alternate method of detection (thermal camera, broom handle, e

• Vapors may travel to source of ignition and flash back.

• Cylinders exposed to fire may vent and release flammable gas throug

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Some may be irritating if inhaled at high concentrations.

• Contact with gas or liquefied gas may cause burns, severe injury and

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

• Always wear thermal protective clothing when handling refrigerated/

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mil

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 m

directions; also, consider initial evacuation for 1600 meters (1 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0176
y 

2

Large Fire

• Water spray or fog.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than 

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Do not direct water at spill or source of leak.

• Prevent spreading of vapors through sewers, ventilation systems a

• Isolate area until gas has dispersed.

CAUTION: When in contact with refrigerated/cryogenic liquids, m

brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Clothing frozen to the skin should be thawed before being removed

• In case of contact with liquefied gas, thaw frosted parts with lukew

• In case of burns, immediately cool affected skin for as long as pos

not remove clothing if adhering to skin. • Keep victim war

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0177
Page 178

involved in a fire.

• Vapors from liquefied gas are initially heavier than air and spread along 

• Vapors may travel to source of ignition and flash back.

• Cylinders exposed to fire may vent and release flammable gas throug

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Some may be toxic if inhaled at high concentrations.

• Contact with gas or liquefied gas may cause burns, severe injury and

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mil

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 m

directions; also, consider initial evacuation for 1600 meters (1 mile) 

GuidePages 167_291 Eng.pmd 3/25/0178
• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Stop leak if you can do it without risk.

• Do not touch or walk through spilled material.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of burns, immediately cool affected skin for as long as p

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0179
Page 180

Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• These materials are extremely flammable.

• May form explosive mixtures with air.

• May be ignited by heat, sparks or flames.

• Vapors from liquefied gas are initially heavier than air and spread along 

• Vapors may travel to source of ignition and flash back.

• Runoff may create fire or explosion hazard.

• Cylinders exposed to fire may vent and release toxic and flammable gas 

relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 mete

directions; also, consider initial evacuation for 1600 meters (1 mile) i

GuidePages 167_291 Eng.pmd 3/25/0180
• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holder

• Cool containers with flooding quantities of water until well after f

• Do not direct water at source of leak or safety devices; icing ma

• Withdraw immediately in case of rising sound from venting safe

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or fl

• All equipment used when handling the product must be grounded

• Fully encapsulating, vapor protective clothing should be worn fo

no fire. • Do not touch or walk through spilled material

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Av

to contact spilled material. • Do not direct water at spill or s

• If possible, turn leaking containers so that gas escapes rather th

• Prevent entry into waterways, sewers, basements or confined a

• Isolate area until gas has dispersed.

• Consider igniting spill or leak to eliminate toxic gas concerns.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of burns, immediately cool affected skin for as long as p

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0181
Page 182

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release flammable gas throug

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• May cause toxic effects if inhaled.

• Vapors are extremely irritating.

• Contact with gas or liquefied gas may cause burns, severe injury and

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas. • Ventilate closed spaces before entering

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mil

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 m

directions; also, consider initial evacuation for 1600 meters (1 mile) i

GuidePages 167_291 Eng.pmd 3/25/0182
• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than 

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• Do not direct water at spill or source of leak.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of burns, immediately cool affected skin for as long as p

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0183
Page 184

• Flammable; may be ignited by heat, sparks or flames.

• May form explosive mixtures with air.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Vapors from liquefied gas are initially heavier than air and spread alo

• Vapors may travel to source of ignition and flash back.

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release toxic and flammable 

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

• Runoff may create fire or explosion hazard.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away. • Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas. • Ventilate closed spaces before entering

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highlig

non-highlighted materials, increase, in the downwind direction, as neces

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 mete

directions; also, consider initial evacuation for 1600 meters (1 mile) i

GuidePages 167_291 Eng.pmd 3/25/0184
expansion foam. • Move containers from fire area if yo

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holder

• Cool containers with flooding quantities of water until well after f

• Do not direct water at source of leak or safety devices; icing ma

• Withdraw immediately in case of rising sound from venting safe

discoloration of tank. • ALWAYS stay away from tanks eng

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or fl

• All equipment used when handling the product must be grounded

• Fully encapsulating, vapor protective clothing should be worn for sp

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Av

to contact spilled material.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium ex

vapors.

• If possible, turn leaking containers so that gas escapes rather th

• Prevent entry into waterways, sewers, basements or confined a

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of burns, immediately cool affected skin for as long as p

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0185
Page 186

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

• Always wear thermal protective clothing when handling refrigerated/

solids.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0186
• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Allow substance to evaporate.

• Ventilate the area.

CAUTION: When in contact with refrigerated/cryogenic liquids, m

brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being remov

• In case of contact with liquefied gas, thaw frosted parts with luk

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0187
Page 188

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0188
• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Allow substance to evaporate.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0189
Page 190

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Contact with gas or liquefied gas may cause burns, severe injury and

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

• Always wear thermal protective clothing when handling refrigerated/

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 500 meters (1/3 mil

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0190
• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than 

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined area

• Allow substance to evaporate.

• Isolate area until gas has dispersed.

CAUTION: When in contact with refrigerated/cryogenic liquids, m

brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Clothing frozen to the skin should be thawed before being remov

• In case of contact with liquefied gas, thaw frosted parts with luk

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0191
Page 192

FIRE OR EXPLOSION

• Some may burn but none ignite readily.

• Vapors from liquefied gas are initially heavier than air and spread along 

• Cylinders exposed to fire may vent and release toxic and/or corrosiv

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highlig

non-highlighted materials, increase, in the downwind direction, as neces

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0192
• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• Do not direct water at spill or source of leak.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0193
Page 194

• Substance does not burn but will support combustion.

• Vapors from liquefied gas are initially heavier than air and spread along 

• These are strong oxidizers and will react vigorously or explosively with 

including fuels.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Some will react violently with air, moist air and/or water.

• Cylinders exposed to fire may vent and release toxic and/or corrosiv

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0194
Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

fire.

• Do not touch or walk through spilled material.

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Isolate area until gas has dispersed.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being remov

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0195
Page 196

FIRE OR EXPLOSION

• Some may burn but none ignite readily.

• Vapors from liquefied gas are initially heavier than air and spread along 

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release toxic and/or corrosiv

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 mete

directions; also, consider initial evacuation for 1600 meters (1 mile) i

GuidePages 167_291 Eng.pmd 3/25/0196
• Do not get water inside containers.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank. • ALWAYS stay away from tanks engu

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material. • Isolate area until gas has dispersed

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical se

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with luk

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• In case of contact with Hydrogen fluoride, anhydrous (UN1

eyes with water for 5 minutes; then, for skin exposures rub on a 

combination; for eyes flush with a water/calcium solution for 15 

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0197
Page 198

• Vapors from liquefied gas are initially heavier than air and spread along 

• Contact with gas or liquefied gas may cause burns, severe injury and/or 

• Fire may produce irritating, corrosive and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 500 meters (1/3 mil

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0198
• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• Some of these materials, if spilled, may evaporate leaving a flamm

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Allow substance to evaporate.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukew

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0199
Page 200

Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 fe

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0200
Water spray, fog or alcohol-resistant foam.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; i

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible mate

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in clos

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes. • Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as pos

not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0201
Page 202

Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

• Substance may be transported hot.

• If molten aluminum is involved, refer to GUIDE 169.

HEALTH

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 fe

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0202
y , 

2

, py g

Large Fire

• Water spray, fog or regular foam.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you 

• Prevent entry into waterways, sewers, basements or confined a

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible m

transfer to containers. • Use clean non-sparking tools to col

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in clos

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as pos

Do not remove clothing if adhering to skin. • Keep victim warm a

• Ensure that medical personnel are aware of the material(s) involve

to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0203
Page 204

Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or absorbed through skin.

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 fe

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0204
g

• Water spray, fog or alcohol-resistant foam.

• Do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; i

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you 

• Prevent entry into waterways, sewers, basements or confined a

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible m

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spill • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in c

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical ser

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as pos

Do not remove clothing if adhering to skin. • Keep victim warm a

• Effects of exposure (inhalation, ingestion or skin contact) to subst

• Ensure that medical personnel are aware of the material(s) involve

to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0205
Page 206

Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or absorbed through skin.

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 fe

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0206
Water spray, fog or regular foam.

• Do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; i

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible mate

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spill • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in clos

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servi

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as pos

Do not remove clothing if adhering to skin. • Keep victim warm a

• Effects of exposure (inhalation, ingestion or skin contact) to subst

• Ensure that medical personnel are aware of the material(s) involve

to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0207
Page 208

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flam

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and co

confined areas (sewers, basements, tanks).

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

non-highlighted materials, increase, in the downwind direction, as nece

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0208
• Dike fire-control water for later disposal; do not scatter the materia

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; i

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you 

• Prevent entry into waterways, sewers, basements or confined a

• A vapor suppressing foam may be used to reduce vapors.

Small Spill • Absorb with earth, sand or other non-combustible mat

transfer to containers for later disposal.

• Use clean non-sparking tools to collect absorbed material.

Large Spill • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in clos

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhale

artificial respiration with the aid of a pocket mask equipped wi

other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as pos

Do not remove clothing if adhering to skin. • Keep victim warm a

• Effects of exposure (inhalation, ingestion or skin contact) to subst

• Ensure that medical personnel are aware of the material(s) involve

to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0209
Page 210

(, , )

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively wh

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or ingested/swallowed.

• Contact with substance may cause severe burns to skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highlig

non-highlighted materials, increase, in the downwind direction, as neces

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters 

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0210
Do not get water inside containers.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you 

• Prevent entry into waterways, sewers, basements or confined a

• A vapor suppressing foam may be used to reduce vapors.

• Absorb with earth, sand or other non-combustible material and tr

containers (except for Hydrazine).

• Use clean non-sparking tools to collect absorbed material.

Large Spill • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in clos

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhale

artificial respiration with the aid of a pocket mask equipped wi

other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• In case of burns, immediately cool affected skin for as long as pos

not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0211
Page 212

Substance may be transported in a molten form at a temperature that m

point.

• May re-ignite after fire is extinguished.

HEALTH

• Fire may produce irritating and/or toxic gases.

• Contact may cause burns to skin and eyes.

• Contact with molten substance may cause severe burns to skin and eye

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited prote

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet)

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0212
Fire Involving Metal Pigments or Pastes (e.g. “Aluminum Paste”

• Aluminum Paste fires should be treated as a combustible metal fire

graphite powder, dry sodium chloride based extinguishers, G-1® o

Also, see GUIDE 170.

Fire involving Tanks or Car/Trailer Loads

• Cool containers with flooding quantities of water until well after fire 

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

Small Dry Spill

• With clean shovel place material into clean, dry container and cove

containers from spill area.

Large Spill

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Removal of solidified molten material from skin requires medical a

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0213
Page 214

Containers may explode when heated.

HEALTH

• TOXIC; inhalation, ingestion or skin contact with material may cause se

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic a

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by 

may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in 

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0214
• Use water spray or fog; do not use straight streams.

• Do not get water inside containers.

• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Stop leak if you can do it without risk.

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Prevent entry into waterways, sewers, basements or confined area

• Use clean non-sparking tools to collect material and place it into lo

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0215
Page 216

• May re-ignite after fire is extinguished.

• Runoff may create fire or explosion hazard.

• Containers may explode when heated.

HEALTH

• Fire will produce irritating, corrosive and/or toxic gases.

• Inhalation of decomposition products may cause severe injury or dea

• Contact with substance may cause severe burns to skin and eyes.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0216
Small Fire

• Dry chemical, soda ash, lime or DRY sand, EXCEPT for UN1384, U

Large Fire

• DRY sand, dry chemical, soda ash or lime, EXCEPT for UN1384, U

withdraw from area and let fire burn.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers or in contact with substance.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills 

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material. • Stop leak if you 

Small Spill

EXCEPTION: For spills of Xanthates, UN3342 and for Dithion

Hydrosulphite), UN1384, UN1923 and UN1929, dissolve in 5 

collect for proper disposal.

• Cover with DRY earth, DRY sand or other non-combustible mate

sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into lo

containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes. • Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0217
Page 218

• Containers may explode when heated.

HEALTH

• Fire will produce irritating, corrosive and/or toxic gases.

• TOXIC; ingestion of substance or inhalation of decomposition produc

injury or death.

• Contact with substance may cause severe burns to skin and eyes.

• Some effects may be experienced due to skin absorption.

• Runoff from fire control may be corrosive and/or toxic and cause pollutio

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

• For Phosphorus (UN1381): Special aluminized protective cloth

worn when direct contact with the substance is possible.

EVACUATION

Spill

• Consider initial downwind evacuation for at least 300 meters (1000 fe

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0218
• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

• Do not touch damaged containers or spilled material unless wear

protective clothing.

• Stop leak if you can do it without risk.

Small Spill

• Cover with water, sand or earth. Shovel into metal container and k

Large Spill

• Dike for later disposal and cover with wet sand or earth.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, keep exposed skin areas immer

with wet bandages until medical attention is received.

• Removal of solidified molten material from skin requires medical a

• Remove and isolate contaminated clothing and shoes at the site a

container filled with water. Fire hazard if allowed to dry.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0219
Page 220

y y

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE

materials may burn, but none ignite readily.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Substance will react with water (some violently), releasing corrosive an

runoff.

• Flammable/toxic gases may accumulate in confined areas (basement, t

cars, etc.).

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed area

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0220
• Flood fire area with large quantities of water, while knocking down 

insufficient water supply: knock down vapors only.

Fire involving Tanks or Car/Trailer Loads

• Cool containers with flooding quantities of water until well after fire 

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills 

• Do not touch damaged containers or spilled material unless wearin

clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors; do not put water directly on leak

container.

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

Small Spill • Cover with DRY earth, DRY sand or other non-combus

with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into lo

containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Removal of solidified molten material from skin requires medica

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0221
Page 222

• Some are transported in highly flammable liquids.

• Runoff may create fire or explosion hazard.

HEALTH

• Inhalation or contact with vapors, substance or decomposition products 

injury or death.

• May produce corrosive solutions on contact with water.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate the area before entry.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

non-highlighted materials, increase, in the downwind direction, as nece

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0222
Move containers from fire area if you can do it without risk.

Fire Involving Metals or Powders (Aluminum, Lithium, Magnesiu

• Use dry chemical, DRY sand, sodium chloride powder, graphite po

powder; in addition, for Lithium you may use Lith-X® powder or co

Also, see GUIDE 170.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• DO NOT GET WATER on spilled substance or inside containers

Small Spill • Cover with DRY earth, DRY sand or other non-combus

with plastic sheet to minimize spreading or contact with rain.

• Dike for later disposal; do not apply water unless directed to do so

Powder Spill • Cover powder spill with plastic sheet or tarp to minim

spreading and keep powder dry.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, wipe from skin immediately; 

running water for at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0223
Page 224

• Some are transported in highly flammable liquids.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Highly toxic: contact with water produces toxic gas, may be fatal if in

• Inhalation or contact with vapors, substance or decomposition produ

severe injury or death.

• May produce corrosive solutions on contact with water.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate the area before entry.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0224
expansion foam; DO NOT USE dry chemicals, soda ash or lime 

(large or small) as they may release large quantities of hydroge

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holder

• Cool containers with flooding quantities of water until well after f

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safe

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for sp

• ELIMINATE all ignition sources (no smoking, flares, sparks or fl

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• DO NOT GET WATER on spilled substance or inside contain

• Use water spray to reduce vapors or divert vapor cloud drift. Av

to contact spilled material.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expa

vapors.

Small Spill • Cover with DRY earth, DRY sand or other non-combus

with plastic sheet to minimize spreading or contact with rain.

• Dike for later disposal; do not apply water unless directed to do so

Powder Spill • Cover powder spill with plastic sheet or tarp to minim

spreading and keep powder dry.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVIS

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, wipe from skin immediately; 

running water for at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0225
Page 226

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Inhalation, ingestion or contact (skin, eyes) with vapors or substance m

injury, burns or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0226
• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Do not get water inside containers.

Small Dry Spill

• With clean shovel place material into clean, dry container and cove

containers from spill area.

Small Liquid Spill

• Use a non-combustible material like vermiculite or sand to soak up 

into a container for later disposal.

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Following product recovery, flush area with water.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0227
Page 228

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Toxic by ingestion.

• Inhalation of dust is toxic.

• Fire may produce irritating, corrosive and/or toxic gases.

• Contact with substance may cause severe burns to skin and eyes.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0228
• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

Small Dry Spill

• With clean shovel place material into clean, dry container and cove

containers from spill area.

Large Spill

• Dike far ahead of spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0229
Page 230

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors or subs

severe injury, burns or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Toxic/flammable fumes may accumulate in confined areas (basement, t

etc.).

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0230
• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Fully encapsulating, vapor protective clothing should be worn for s

leaks with no fire.

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift.

• Do not get water inside containers.

Small Liquid Spill

• Use a non-combustible material like vermiculite or sand to soak up 

into a container for later disposal.

Large Spill

• Dike far ahead of liquid spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhale

artificial respiration with the aid of a pocket mask equipped wi

other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0231
Page 232

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts o

cause severe injury, burns or death.

• Fire may produce irritating and/or toxic gases.

• Toxic fumes or dust may accumulate in confined areas (basement, tank

etc.).

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0232
• Move containers from fire area if you can do it without risk.

• Do not get water inside containers: a violent reaction may occur.

Fire involving Tanks or Car/Trailer Loads

• Cool containers with flooding quantities of water until well after fire 

• Dike fire-control water for later disposal.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Use water spray to reduce vapors or divert vapor cloud drift.

• Prevent entry into waterways, sewers, basements or confined area

Small Spill

• Flush area with flooding quantities of water.

Large Spill

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVIS

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0233
Page 234

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation or contact with vapor, substance, or decompositio

cause severe injury or death.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0234
• Do not move cargo or vehicle if cargo has been exposed to heat.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• DO NOT GET WATER on spilled substance or inside containers

Small Spill

• Cover with DRY earth, DRY sand or other non-combustible materia

sheet to minimize spreading or contact with rain.

Large Spill

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVIS

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhale

artificial respiration with the aid of a pocket mask equipped wi

other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0235
Page 236

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injur

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0236
• Do not move cargo or vehicle if cargo has been exposed to heat.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Keep substance wet using water spray.

• Stop leak if you can do it without risk.

Small Spill

• Take up with inert, damp, non-combustible material using clean no

place into loosely covered plastic containers for later disposal.

Large Spill

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0237
Page 238

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injur

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0238
• Do not move cargo or vehicle if cargo has been exposed to heat.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Keep substance wet using water spray.

• Stop leak if you can do it without risk.

Small Spill

• Take up with inert, damp, non-combustible material using clean no

place into loosely covered plastic containers for later disposal.

Large Spill

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0239
Page 240

HEALTH

• Contact with battery electrolyte may be irritating to skin, eyes and muc

• Fire will produce irritating, corrosive and/or toxic gases.

• Burning batteries may produce toxic hydrogen fluoride gas (see GUIDE 

• Fumes may cause dizziness or suffocation.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for a

feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited prote

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet)

Fire

• If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mi

also initiate evacuation including emergency responders for 500 meters 

directions.

GuidePages 167_291 Eng.pmd 3/25/0240
SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames 

• Do not touch or walk through spilled material.

• Absorb with earth, sand or other non-combustible material.

• Leaking batteries and contaminated absorbent material should be pla

containers.

FIRST AID

• Move victim to fresh air.

• Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with 

least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involved a

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0241
Page 242

May be ignited by heat, sparks or flames.

• May burn rapidly with flare-burning effect.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injur

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• DO NOT allow the substance to warm up. Obtain liquid nitrogen

cooling. If none can be obtained, evacuate the area immediately.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0242
Flood fire area with water from a distance.

• Use water spray or fog; do not use straight streams.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Keep combustibles (wood, paper, oil, etc.) away from spilled mater

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spill

• Take up with inert, damp, non-combustible material using clean no

place into loosely covered plastic containers for later disposal.

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0243
Page 244

gg

• Vapors or dust may form explosive mixtures with air.

HEALTH

• Inhalation or contact with vapors, substance or decomposition produ

severe injury or death.

• May produce irritating, toxic and/or corrosive gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 250 meters (800 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0244
Fire involving Tanks or Car/Trailer Loads

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spill

• Take up with inert, damp, non-combustible material using clean no

place into loosely covered plastic containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0245
Page 246

• May be ignited by heat, sparks or flames.

• Some may decompose explosively when heated or involved in a fire.

• May burn violently. Decomposition may be self-accelerating and produc

large amounts of gases.

• Vapors or dust may form explosive mixtures with air.

HEALTH

• Inhalation or contact with vapors, substance or decomposition produ

severe injury or death.

• May produce irritating, toxic and/or corrosive gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• DO NOT allow the substance to warm up. Obtain liquid nitrogen

cooling. If none can be obtained, evacuate the area immediately.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 250 meters (800 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0246
Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spill

• Take up with inert, damp, non-combustible material using clean no

place into loosely covered plastic containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0247
Page 248

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose u

produce corrosive and/or toxic fumes.

• Containers may explode when heated.

• Runoff may pollute waterways.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0248
• Dike fire-control water for later disposal; do not scatter the materia

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• Cover with plastic sheet to prevent spreading.

• Absorb or cover with dry earth, sand or other non-combustible mate

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0249
Page 250

• Runoff from fire control or dilution water may be corrosive and/or toxic a

FIRE OR EXPLOSION

• Combustible material: may burn but does not ignite readily.

• Containers may explode when heated.

• Runoff may pollute waterways.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0250
• Dike fire-control water for later disposal; do not scatter the materia

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or fl

• Do not touch damaged containers or spilled material unless wear

protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined a

• Cover with plastic sheet to prevent spreading.

• Absorb or cover with dry earth, sand or other non-combustible m

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0251
Page 252

Runoff from fire control or dilution water may be corrosive and/or toxic a

FIRE OR EXPLOSION

• Combustible material: may burn but does not ignite readily.

• When heated, vapors may form explosive mixtures with air: indoors, ou

explosion hazards.

• Those substances designated with a "P" may polymerize explosively w

involved in a fire.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated.

• Runoff may pollute waterways.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed area

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0252
• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• Absorb or cover with dry earth, sand or other non-combustible mat

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0253
Page 254

• Runoff from fire control or dilution water may be corrosive and/or toxic a

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose u

produce corrosive and/or toxic fumes.

• Some are oxidizers and may ignite combustibles (wood, paper, oil, cloth

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0254
• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• Absorb or cover with dry earth, sand or other non-combustible mat

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0255
Page 256

gy pypy 

involved in a fire.

• Substance will react with water (some violently) releasing flammabl

gases and runoff.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dus

may cause severe injury, burns or death.

• Bromoacetates and chloroacetates are extremely irritating/lach

• Reaction with water or moist air will release toxic, corrosive or flamm

• Reaction with water may generate much heat that will increase the conce

fumes in the air.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic an

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed area

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highlig

non-highlighted materials, increase, in the downwind direction, as neces

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters 

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0256
expansion foam.

• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holder

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after f

• Withdraw immediately in case of rising sound from venting safe

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or fl

• All equipment used when handling the product must be grounded

• Do not touch damaged containers or spilled material unless wea

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium ex

reduce vapors.

• DO NOT GET WATER on spilled substance or inside contain

• Use water spray to reduce vapors or divert vapor cloud drift. Av

to contact spilled material.

• Prevent entry into waterways, sewers, basements or confined a

Small Spill • Cover with DRY earth, DRY sand or other non-combust

plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loo

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical ser

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0257
Page 258

py pg g

confined areas (sewers, basements, tanks).

• Vapors may travel to source of ignition and flash back.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dus

may cause severe injury, burns or death.

• Contact with molten substance may cause severe burns to skin and 

• Reaction with water or moist air will release toxic, corrosive or flamm

• Reaction with water may generate much heat that will increase the conc

fumes in the air.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and ca

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed area

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0258
• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expa

reduce vapors.

• DO NOT GET WATER on spilled substance or inside containers

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid a

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined area

Small Spill • Cover with DRY earth, DRY sand or other non-combus

with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into lo

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0259
Page 260

pg, g

• Runoff from fire control or dilution water may be corrosive and/or toxic an

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose 

produce corrosive and/or toxic fumes.

• Vapors may accumulate in confined areas (basement, tanks, hopper/ta

• Substance will react with water (some violently), releasing corrosive an

runoff.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0260
py g; g

• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• DO NOT GET WATER INSIDE CONTAINERS.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined area

Small Spill • Cover with DRY earth, DRY sand or other non-combus

with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into lo

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or in

give artificial respiration with the aid of a pocket mask equ

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected s

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to sub

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0261
Page 262

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Some may be transported in flammable liquids.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Obtain identity of substance involved.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited prote

GuidePages 167_291 Eng.pmd 3/25/0262
• Move containers from fire area if you can do it without risk.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Do not touch damaged containers or spilled material unless wearin

appropriate protective clothing.

• Absorb with earth, sand or other non-combustible material.

• Cover damaged package or spilled material with damp towel or rag 

bleach or other disinfectant.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERV

FIRST AID

• Move victim to a safe isolated area.

CAUTION: Victim may be a source of contamination.

• Call 911 or emergency medical service.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Effects of exposure (inhalation, ingestion or skin contact) to substa

• For further assistance, contact your local Poison Control Cent

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0263
Page 264

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Containers may explode when heated.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

non-highlighted materials, increase, in the downwind direction, as nece

distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0264
• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Fully encapsulating, vapor protective clothing should be worn for spills 

Small Spill

• Take up with sand or other non-combustible absorbent material an

containers for later disposal.

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhale

artificial respiration with the aid of a pocket mask equipped wi

other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected ski

• Keep victim warm and quiet.

• Effects should disappear after individual has been exposed to fres

approximately 10 minutes.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0265
Page 266

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Most vapors are heavier than air.

• Air/vapor mixtures may explode when ignited.

• Container may explode in heat of fire.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0266
• Dike fire-control water for later disposal; do not scatter the materia

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Stop leak if you can do it without risk.

Small Liquid Spill

• Take up with sand, earth or other non-combustible absorbent mate

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected ski

• Wash skin with soap and water.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0267
Page 268

• Some radioactive materials cannot be detected by commonly available 

• Packages do not have RADIOACTIVE I, II, or III labels. Some may have 

may have the word “Radioactive” in the package marking.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Many have cardboard outer packaging; content (physically large or sma

different physical forms.

• Radioactivity does not change flammability or other properties of materi

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and othe

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation 

responsible for decisions about radiological consequences and closure 

• As an immediate precautionary measure, isolate spill or leak area for 

(75 feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be con

decontamination and cleanup until instructions are received from Radia

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and struc

protective clothing will provide adequate protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, conside

evacuation distance of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0268
Dry chemical, CO2

, water spray or regular foam.

Large Fire

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Cover liquid spill with sand, earth or other non-combustible absorb

• Cover powder spill with plastic sheet or tarp to minimize spreading

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Injured persons contaminated by contact with released material ar

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0269
Page 270

bulk container, hazard will vary from low to moderate. Level of hazard will d

amount of radioactivity, the kind of material it is in, and/or the surfaces it is o

• Some material may be released from packages during accidents of mod

risks to people are not great.

• Released radioactive materials or contaminated objects usually will be visib

• Some exclusive use shipments of bulk and packaged materials will not have 

labels. Placards, markings and shipping papers provide identification.

• Some packages may have a “RADIOACTIVE” label and a second haz

second hazard is usually greater than the radiation hazard; so follow 

as the response GUIDE for the second hazard class label.

• Some radioactive materials cannot be detected by commonly availab

• Runoff from control of cargo fire may cause low-level pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Uranium and Thorium metal cuttings may ignite spontaneously if exp

GUIDE 136).

• Nitrates are oxidizers and may ignite other combustibles (see GUIDE 

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Pa

Shipping Paper not available or no answer, refer to appropriate 

number listed on the inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and othe

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation 

responsible for decisions about radiological consequences and closure 

• As an immediate precautionary measure, isolate spill or leak area for 

(75 feet) in all directions. • Stay upwind. • Keep unauthorized pe

• Detain or isolate uninjured persons or equipment suspected to be con

decontamination and cleanup until instructions are received from Radia

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and struc

protective clothing will provide adequate protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, conside

evacuation distance of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0270
Dry chemical, CO2

, water spray or regular foam.

Large Fire

• Water spray, fog (flooding amounts).

• Dike fire-control water for later disposal.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Cover liquid spill with sand, earth or other non-combustible abso

• Dike to collect large liquid spills.

• Cover powder spill with plastic sheet or tarp to minimize spread

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, wipe from skin immediately; flus

running water for at least 20 minutes.

• Injured persons contaminated by contact with released material ar

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0271
Page 272

pggy 

• Type B packages, and the rarely occurring Type C packages, (large and small, us

most hazardous amounts. They can be identified by package markings or by shipping 

conditions may exist only if contents are released or package shielding fai

evaluation and testing of packages, these conditions would be expected only 

severity.

• The rarely occurring "Special Arrangement" shipments may be of Type A, Type B or Ty

type will be marked on packages, and shipment details will be on shipping paper

• Radioactive White-I labels indicate radiation levels outside single, isolated, undam

low (less than 0.005 mSv/h (0.5 mrem/h)).

• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation leve

(TI) on the label identifies the maximum radiation level in mrem/h one meter from a sing

package.

• Some radioactive materials cannot be detected by commonly available instrume

• Water from cargo fire control may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Radioactivity does not change flammability or other properties of materials.

• Type B packages are designed and evaluated to withstand total engulfment 

temperatures of 800°C (1475°F) for a period of 30 minutes.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper firs

not available or no answer, refer to appropriate telephone number liste

cover.

• Priorities for rescue, life-saving, first aid, fire control and othe

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Autho

responsible for decisions about radiological consequences and closure of e

• As an immediate precautionary measure, isolate spill or leak area for 

(75 feet) in all directions. • Stay upwind. • Keep unauthorized pe

• Detain or isolate uninjured persons or equipment suspected to be contamin

decontamination and cleanup until instructions are received from Radiation 

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structura

protective clothing will provide adequate protection against internal radiatio

external radiation exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an 

distance of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0272
• Water spray, fog (flooding amounts).

• Dike fire-control water for later disposal.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seld

packaging failure. Most packaging for liquid content have inner contai

absorbent materials.

• Cover liquid spill with sand, earth or other non-combustible abso

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with 

minutes.

• Injured persons contaminated by contact with released material are no

care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, t

themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0273
Page 274

yppg(, , , , ) ypy 

or by shipping papers contain non-life endangering amounts. Radioactive source

“Type A” packages are damaged in moderately severe accidents.

• Type B packages, and the rarely occurring Type C packages, (large and small, u

the most hazardous amounts. They can be identified by package markings or by 

threatening conditions may exist only if contents are released or package shield

design, evaluation and testing of packages, these conditions would be ex

accidents of utmost severity.

• Radioactive White-I labels indicate radiation levels outside single, isolated, und

very low (less than 0.005 mSv/h (0.5 mrem/h)).

• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation lev

index (TI) on the label identifies the maximum radiation level in mrem/h one mete

isolated, undamaged package.

• Radiation from the package contents, usually in durable metal capsules, can be 

radiation instruments.

• Water from cargo fire control is not expected to cause pollution.

FIRE OR EXPLOSION

• Packagings can burn completely without risk of content loss from sealed source 

• Radioactivity does not change flammability or other properties of materials.

• Radioactive source capsules and Type B packages are designed and evaluated 

engulfment in flames at temperatures of 800°C (1475°F) for a period of 30 minut

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If S

available or no answer, refer to appropriate telephone number listed on the 

• Priorities for rescue, life-saving, first aid, fire control and other h

than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority 

for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at l

feet) in all directions.

• Stay upwind. • Keep unauthorized personnel away.

• Delay final cleanup until instructions or advice is received from Radiation Author

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural fire

clothing will provide adequate protection against internal radiation exposure, bu

exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initia

of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0274
g

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seld

packaging failure. Contents are seldom liquid. Content is usually a me

released from package.

• If source capsule is identified as being out of package, DO NOT TOUC

advice from Radiation Authority.

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Persons exposed to special form sources are not likely to be contamin

material.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Injured persons contaminated by contact with released material are no

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, t

themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0275
Page 276

to control releases and to prevent a fission chain reaction under severe tr

• Type B(U)F, B(M)F and CF packages (identified by markings on packages or shi

potentially life endangering amounts. Because of design, evaluation and 

fission chain reactions are prevented and releases are not expected to be 

all accidents except those of utmost severity.

• The rarely occurring "Special Arrangement" shipments may be of Type AF, BF o

Package type will be marked on packages, and shipment details will be on shipp

• The transport index (TI) shown on labels or a shipping paper might not ind

level at one meter from a single, isolated, undamaged package; instead, i

controls needed during transport because of the fissile properties of the m

Alternatively, the fissile nature of the contents may be indicated by a crit

(CSI) on a special FISSILE label or on the shipping paper.

• Some radioactive materials cannot be detected by commonly available i

• Water from cargo fire control is not expected to cause pollution.

FIRE OR EXPLOSION

• These materials are seldom flammable. Packages are designed to withstan

damage to contents.

• Radioactivity does not change flammability or other properties of materials.

• Type AF, IF, B(U)F, B(M)F and CF packages are designed and evaluated to 

engulfment in flames at temperatures of 800°C (1475°F) for a period of 30 m

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper firs

not available or no answer, refer to appropriate telephone number liste

cover.

• Priorities for rescue, life-saving, first aid, fire control and othe

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Autho

responsible for decisions about radiological consequences and closure of e

• As an immediate precautionary measure, isolate spill or leak area for 

(75 feet) in all directions. • Stay upwind. • Keep unauthorized pe

• Detain or isolate uninjured persons or equipment suspected to be contamin

decontamination and cleanup until instructions are received from Radiation 

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and stru

protective clothing will provide adequate protection against internal radiatio

external radiation exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, cons

evacuation distance of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0276
g

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seld

packaging failure. Most packaging for liquid content have inner contai

absorbent materials.

Liquid Spill

• Package contents are seldom liquid. If any radioactive contamination 

release is present, it probably will be low-level.

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with 

20 minutes.

• Injured persons contaminated by contact with released material are no

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, t

themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0277
Page 278

• If inhaled, may be fatal.

• Direct contact causes burns to skin, eyes, and respiratory tract.

• Low-level radioactive material; very low radiation hazard to people.

• Runoff from control of cargo fire may cause low-level pollution.

FIRE OR EXPLOSION

• Substance does not burn. • The material may react violently w

• Containers in protective overpacks (horizontal cylindrical shape with 

downs), are identified with "AF", "B(U)F" or "H(U)" on shipping paper

the overpacks. They are designed and evaluated to withstand severe co

total engulfment in flames at temperatures of 800°C (1475°F) for a perio

• Bare filled cylinders, identified with UN2978 as part of the marking (may 

or H(M)), may rupture in heat of engulfing fire; bare empty (except for re

not rupture in fires.

• Radioactivity does not change flammability or other properties of materi

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper f

Paper not available or no answer, refer to appropriate telephone num

inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and other haz

than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Au

responsible for decisions about radiological consequences and closu

• As an immediate precautionary measure, isolate spill or leak area for 

(75 feet) in all directions. • Stay upwind. • Keep unauthorized pe

• Detain or isolate uninjured persons or equipment suspected to be con

decontamination and cleanup until instructions are received from Rad

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

EVACUATION

Large Spill

• See Table 1 - Initial Isolation and Protective Action Distances.

Fire

• When a large quantity of this material is involved in a major fire, conside

evacuation distance of 300 meters (1000 feet) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0278
py, g g

• Cool containers with flooding quantities of water until well after fire 

• If this is impossible, withdraw from area and let fire burn.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Without fire or smoke, leak will be evident by visible and irritating v

forming at the point of release.

• Use fine water spray to reduce vapors; do not put water directly on 

from container.

• Residue buildup may self-seal small leaks.

• Dike far ahead of spill to collect runoff water.

FIRST AID

• Call 911 or emergency medical service.

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Effects of exposure (inhalation, ingestion or skin contact) to subst

• Injured persons contaminated by contact with released material ar

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves and prevent spread of contamination.

GuidePages 167_291 Eng.pmd 3/25/0279
Page 280

FIRE OR EXPLOSION

• Substance does not burn but will support combustion.

• This is a strong oxidizer and will react vigorously or explosively with ma

including fuels.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

• Always wear thermal protective clothing when handling refrigerated/

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 mete

directions; also, consider initial evacuation for 1600 meters (1 mile) in 

GuidePages 167_291 Eng.pmd 3/25/0280
Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; 

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• If you have not donned special protective clothing approved for this 

yourself to any risk of this material touching you.

• Do not direct water at spill or source of leak.

• A fine water spray remotely directed to the edge of the spill pool ca

maintain a hot flare fire that will burn the spilled material in a contr

• Keep combustibles (wood, paper, oil, etc.) away from spilled mate

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Isolate area until gas has dispersed.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being remov

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0281
Page 282

• EXTREMELY FLAMMABLE.

• May be ignited by heat, sparks or flames.

• Flame may be invisible.

• Containers may explode when heated.

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Vapors from liquefied gas are initially heavier than air and spread along 

• Vapors may travel to source of ignition and flash back.

• Runoff may create fire or explosion hazard.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and co

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended b

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection i

ONLY; it is not effective in spill situations where direct contact with th

possible.

• Always wear thermal protective clothing when handling refrigerated/

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meter

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0282
• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders o

• Cool containers with flooding quantities of water until well after fire 

• Do not direct water at source of leak or safety devices; icing may o

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for s

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid 

contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than 

• Prevent entry into waterways, sewers, basements or confined area

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with lukew

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0283
Page 284

Contact with containers or other materials, including cold, wet or dirty to

explosion.

• Contact with concrete will cause spalling and small pops.

HEALTH

• Contact causes severe burns to skin and eyes.

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear flame retardant structural firefighters’ protective clothing, includ

helmet and gloves, this will provide limited thermal protection.

GuidePages 167_291 Eng.pmd 3/25/0284
SPILL OR LEAK

• Do not touch or walk through spilled material.

• Do not attempt to stop leak, due to danger of explosion.

• Keep combustibles (wood, paper, oil, etc.) away from spilled mate

• Substance is very fluid, spreads quickly, and may splash. Do not tr

shovels or other objects.

• Dike far ahead of spill; use dry sand to contain the flow of material.

• Where possible allow molten material to solidify naturally.

• Avoid contact even after material solidifies. Molten, heated and co

look alike; do not touch unless you know it is cold.

• Clean up under the supervision of an expert after material has solid

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• For severe burns, immediate medical attention is required.

• Removal of solidified molten material from skin requires medica

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

GuidePages 167_291 Eng.pmd 3/25/0285
Page 286

• Containers may explode when heated.

• May re-ignite after fire is extinguished.

HEALTH

• Oxides from metallic fires are a severe health hazard.

• Inhalation or contact with substance or decomposition products may ca

severe injury or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in a

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Stay upwind.

• Keep unauthorized personnel away.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 50 meters (160 feet

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) in a

GuidePages 167_291 Eng.pmd 3/25/0286
• Confining and smothering metal fires is preferable rather than appl

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• If impossible to extinguish, protect surroundings and allow fire to b

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flam

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0287
Page 288

• Contact may cause burns to skin and eyes.

• Inhalation of Asbestos dust may have a damaging effect on the lungs.

• Fire may produce irritating, corrosive and/or toxic gases.

• Some liquids produce vapors that may cause dizziness or suffocation

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all 

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) f

• Keep unauthorized personnel away.

• Stay upwind.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Spill

• See Table 1 - Initial Isolation and Protective Action Distances for highli

For non-highlighted materials, increase, in the downwind direction, as n

isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 me

directions; also, consider initial evacuation for 800 meters (1/2 mile) 

GuidePages 167_291 Eng.pmd 3/25/0288
• Move containers from fire area if you can do it without risk.

• Dike fire-control water for later disposal.

Fire involving Tanks

• Cool containers with flooding quantities of water until well after fire 

• Withdraw immediately in case of rising sound from venting safety d

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent dust cloud.

• Avoid inhalation of asbestos dust.

Small Dry Spill

• With clean shovel place material into clean, dry container and cove

containers from spill area.

Small Spill

• Take up with sand or other non-combustible absorbent material an

into containers for later disposal.

Large Spill

• Dike far ahead of liquid spill for later disposal.

• Cover powder spill with plastic sheet or tarp to minimize spreading

• Prevent entry into waterways, sewers, basements or confined area

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes w

least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involve

protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0289
Page 290

corrosive and/or toxic fumes.

• Runoff may pollute waterways.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper 

Paper not available or no answer, refer to appropriate telephone nu

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at 

(150 feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited pro

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 fee

Fire

• When any large container is involved in a fire, consider initial evacua

(1/3 mile) in all directions.

GuidePages 167_291 Eng.pmd 3/25/0290
appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined area

• Do not use steel or aluminum tools or equipment.

• Cover with earth, sand or other non-combustible material followed 

minimize spreading or contact with rain.

• For mercury, use a mercury spill kit.

• Mercury spill areas may be subsequently treated with calcium sulp

with sodium thiosulphate/sodium thiosulfate wash to neutralize any 

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical servic

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eye

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) invo

precautions to protect themselves.

GuidePages 167_291 Eng.pmd 3/25/0291

Page 292

WhitePages 292_297 Eng.pmd 2/14/0292
technically qualified emergency response personnel are available

likely to be affected during the first 30 minutes after materia

increase with time.

The Initial Isolation Zone defines an area SURROUNDING the 

may be exposed to dangerous (upwind) and life threatening (dow

material. The Protective Action Zone defines an area DOWNW

which persons may become incapacitated and unable to take prot

serious or irreversible health effects. Table 1 provides specific gui

spills occurring day or night.

Adjusting distances for a specific incident involves many interdepen

be made only by personnel technically qualified to make such adju

no precise guidance can be provided in this document to aid in adju

however, general guidance follows.

Factors That May Change the Protective Action 

The GUIDE for a material (orange-bordered pages) clearly ind

EVACUATION – Fire, the evacuation distance required to prote

hazard of a large container. If the material becomes involved in 

may become less important than the fire or explosion hazard.

If more than one tank car, cargo tank, portable tank, or large cylind

is leaking, LARGE SPILL distances may need to be increased.

For a material with a protective action distance of 11.0+ km (7.0+ m

can be larger in certain atmospheric conditions. If the dangero

channeled in a valley or between many tall buildings, distances m

in Table 1 due to less mixing of the plume with the atmosphere. 

with known strong inversions or snow cover, or occurring near 

increase of the protective action distance because airborne conta

more slowly and may travel much farther downwind. In such case

action distance may be more appropriate. In addition, protective 

larger for liquid spills when either the material or outdoor temperat

Materials which react with water to produce large amounts of 

in Table 1 - Initial Isolation and Protective Action Distan

WhitePages 292_297 Eng.pmd 2/14/0293
Page 294

When a water-reactive TIH producing material is spilled into a river or stre

the toxic gas may move with the current and stretch from the spill point 

substantial distance.

Initial isolation and protective action distances in this guidebook are deriv

data on transportation incidents and the use of statistical models. For wo

involving the instantaneous release of the entire contents of a package (

terrorism, sabotage or catastrophic accident) the distances may increase 

such events, doubling of the initial isolation and protective action distance

absence of other information.

WhitePages 292_297 Eng.pmd 2/14/0294
Proper evaluation of the factors listed below will determine the ef

or in-place protection. The importance of these factors ca

conditions. In specific emergencies, other factors may ne

considered as well. This list indicates what kind of information ma

initial decision.

The Dangerous Goods

· Degree of health hazard

· Chemical and physical properties

· Amount involved

· Containment/control of release

· Rate of vapor movement

The Population Threatened

· Location

· Number of people

· Time available to evacuate or shelter in-

· Ability to control evacuation or shelter in

· Building types and availability

· Special institutions or populations, e.g., 

hospitals, prisons

Weather Conditions

· Effect on vapor and cloud movement

· Potential for change

· Effect on evacuation or protection in-pla

WhitePages 292_297 Eng.pmd 2/14/0295
Page 296

Isolate Hazard Area and Deny Entry means keep everybody away fro

are not directly involved in emergency response operations. Unprot

responders should not be allowed to enter the isolation zone. This “isola

first to establish control over the area of operations. This is the 

protective actions that may follow. See Table 1 - Isolation and Protective 

(green-bordered pages) for more detailed information on specific materi

Evacuate means move all people from a threatened area to a safer plac

evacuation, there must be enough time for people to be warned, to get re

an area. If there is enough time, evacuation is the best protective action. 

people nearby and those outdoors in direct view of the scene. Whe

arrives, expand the area to be evacuated downwind and crosswind to a

recommended in this guidebook. Even after people move to the distanc

they may not be completely safe from harm. They should not be permitte

such distances. Send evacuees to a definite place, by a specific route, fa

they will not have to be moved again if the wind shifts.

Shelter In-Place means people should seek shelter inside a building a

until the danger passes. Sheltering in-place is used when evacuating 

cause greater risk than staying where they are, or when an evacu

performed. Direct the people inside to close all doors and windows a

ventilating, heating and cooling systems. In-place protection may 

option if (a) the vapors are flammable; (b) if it will take a long time for th

area; or (c) if buildings cannot be closed tightly. Vehicles can offer som

short period if the windows are closed and the ventilating systems are 

are not as effective as buildings for in-place protection.

It is vital to maintain communications with competent persons insid

that they are advised about changing conditions. Persons protected-in

warned to stay far from windows because of the danger from glass an

fragments in a fire and/or explosion.

Every dangerous goods incident is different. Each will have spec

concerns. Action to protect the public must be selected carefully. Thes

with initial decisions on how to protect the public. Officials must c

information and monitor the situation until the threat is removed.

WhitePages 292_297 Eng.pmd 2/14/0296
gpg

For each chemical, thousands of hypothetical releases were mo

statistical variation in both release amount and atmospheric co

statistical sample, the 90% percentile Protective Action Distanc

category was selected to appear in the Table. A brief description o

below. A detailed report outlining the methodology and data used 

Initial Isolation and Protective Action Distances may be obtained f

of Transportation, Pipeline and Hazardous Materials Safety Adm

Release amounts and emission rates into the atmosphere were sta

(1) data from the U.S. DOT HMIS database; (2) container types and size

specified in 49 CFR §172.101 and Part 173; (3) physical properties of t

(4) atmospheric data from a historical database. The emission mode

vapor due to evaporation of pools on the ground, direct release of vap

combination of both, as would occur for liquefied gases which can flash t

mixture and an evaporating pool. In addition, the emission model also 

toxic vapor by-products generated from spilling water-reactive materials 

releases of approximately 200 liters (300 kg for solids)or less are co

spills that involve quantities greater than 200 liters (300 kg for solids) a

An exception to this is certain chemical warfare agents where Small S

2 kg, and Large Spills include releases up to 25 kg. These agents are 

HD, HL, HN1, HN2, HN3, L and VX.

Downwind dispersion of the vapor was estimated for each cas

parameters affecting the dispersion, and the emission rate, were sele

from a database containing hourly meteorological data from 120 c

Canada and Mexico. The dispersion calculation accounted for the 

rate from the source as well as the density of the vapor plume (i.e., 

atmospheric mixing is less effective at dispersing vapor plumes d

night were separated in the analysis. In Table 1, “Day” refers to time 

before sunset, while “Night” includes all hours between sunset and 

Toxicological short-term exposure guidelines for the materials w

the downwind distance to which persons may become incapaci

protective action or may incur serious health effects. When availab

guidelines were chosen from AEGL-2 or ERPG-2 emergency r

AEGL-2 values being the first choice. For materials that do not 

values, emergency response guidelines estimated from lethal co

from animal studies were used, as recommended by an independ

experts from industry and academia.

WhitePages 292_297 Eng.pmd 2/14/0297

Page 298

• Found the three-digit guide for that material in order to consult 

actions recommended jointly with this table;

• Noted the wind direction.

(2) Look in Table 1 (the green-bordered pages) for the ID Number and Na

involved in the incident. Some ID Numbers have more than one shipp

look for the specific name of the material. (If the shipping name 

Table 1 lists more than one name for the same ID Number, use 

largest protective action distances.)

(3) Determine if the incident involves a SMALL or LARGE spill and 

Generally, a SMALL SPILL is one which involves a single, small pac

containing up to approximately 200 liters), a small cylinder, or a sma

package. A LARGE SPILL is one which involves a spill from a 

multiple spills from many small packages. DAY is any time after s

sunset. NIGHT is any time between sunset and sunrise.

(4) Look up the INITIAL ISOLATION DISTANCE.

Direct all persons to move, in a crosswind

direction, away from the spill to the

distance specified—in meters and feet.

(5) Look up the initial PROTECTIVE ACTION DISTANCE shown in Ta

material, spill size, and whether day or night, Table 1 gives the down

kilometers and miles— for which protective actions should be conside

purposes, the Protective Action Zone (i.e., the area in which peo

harmful exposure) is a square, whose length and width are the same 

distance shown in Table 1.

Initial Isolation

Zone

In

D

Spill

TIH 298_299 Eng.pmd 2/14/0298
circle. The larger circle represents the INITIAL ISOLATION 

NOTE 1: See “Introduction To Table 1 - Initial Isolation 

Distances” for factors which may increase or dec

Distances.

NOTE 2: See Table 2 – Water-Reactive Materials which Prod

list of gases produced when these materials are sp

Call the emergency response telephone number listed on the 

appropriate response agency as soon as possible for additional in

safety precautions, and mitigation procedures.

Protective

Action Zone

Initial

Isolation

Zone

Wind Direction

Spill

Downwind Distance

TIH 298_299 Eng.pmd 2/14/0299
30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

d

60 m (200 ft) 0.4 km (0.3 mi) 1.6 km (1.0 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 8.0 km (5.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.5 mi) 150 m (500 ft) 1.0 km (0.7 mi) 3.5 km (2.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.8 km (0.5 mi) 3.1 km (1.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.5 km (1.0 mi) 4.5 km (2.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi)

 100 m (300 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 1000 m (3000 ft) 3.8 km (2.4 mi) 7.2 km (4.5 mi)

60 m (200 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 400 m (1250 ft) 1.6 km (1.0 mi) 4.1 km (2.5 mi)

%

stabilized

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 3.6 km (2.2 mi)

3/25/08, 1:37 PM 300

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"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 800 m (2500 ft) 4.2 km (2.6 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)

 200 m (600 ft) 1.1 km (0.7 mi) 4.0 km (2.5 mi) 1000 m (3000 ft) 7.5 km (4.7 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km 0.3 mi)

 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.5 mi) 200 m (600 ft) 1.1 km (0.7 mi) 2.6 km (1.6 mi)

100 m (300 ft) 0.7 km (0.4 mi) 2.6 km (1.6 mi) 500 m (1500 ft) 3.3 km (2.0 mi) 9.7 km (6.1 mi)

60 m (200 ft) 0.3 km (0.2 mi) 1.2 km (0.7 mi) 400 m (1250 ft) 2.1 km (1.3 mi) 5.7 km (3.6 mi)

d 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.0 km (0.6 mi)

100 m (300 ft) 1.1 km (0.7 mi) 3.3 km (2.0 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.2 km (0.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.4 mi) 100 m (300 ft) 1.3 km (0.8 mi) 2.4 km (1.5 mi)

cal

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)

3/25/08, 1:37 PM 301

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30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.1 km (0.7 mi) 2.2 km (1.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi)

30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.2 km (0.8 mi) 2.5 km (1.6 mi)

30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 200 m (600 ft) 2.5 km (1.5 mi) 5.1 km (3.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)

30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.5 km (1.0 mi) 2.5 km (1.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)

150 m (500 ft) 1.6 km (1.0 mi) 3.6 km (2.3 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km 7.0+ mi)

150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.3 km (1.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)

3/25/08, 1:37 PM 302

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"+" means distance can be larger in certain atmospheric conditions

60 m (200 ft) 0.7 km (0.4 mi) 2.3 km (1.4 mi) 400 m (1250 ft) 4.6 km (2.9 mi) 8.9 km (5.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.7 mi)

60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi) 600 m (2000 ft) 5.7 km (3.6 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi)

e 60 m (200 ft) 0.4 km (0.3 mi) 1.7 km (1.1 mi) 600 m (2000 ft) 5.3 km (3.3 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 400 m (1250 ft) 3.5 km (2.2 mi) 10.6 km (6.6 mi)

30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.0 km (0.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 1.0 km (0.7 mi)

 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.4 mi) 150 m (500 ft) 0.7 km (0.4 mi) 2.2 km (1.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)

3/25/08, 1:37 PM 303

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30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi) 100 m (300 ft) 1.1 km (0.7 mi) 2.3 km (1.5 mi)

30 m (100 ft) 0.4 km (0.3 mi) 1.0 km (0.6 mi) 150 m (500 ft) 1.9 km (1.2 mi) 3.3 km (2.1 mi)

e 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 2.1 km (1.3 mi) 5.9 km (3.7 mi)

n

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi)

30 m (100 ft) 0.4 km (0.3 mi) 1.0 km (0.6 mi) 150 m (500 ft) 1.9 km (1.2 mi) 3.3 km (2.1 mi)

 60 m (200 ft) 0.4 km (0.3 mi) 1.5 km (1.0 mi) 600 m (2000 ft) 4.1 km (2.5 mi) 8.0 km (5.0 mi)

100 m (300 ft) 0.4 km (0.3 mi) 1.5 km (0.9 mi) 400 m (1250 ft) 3.1 km (2.0 mi) 6.8 km (4.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

100 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 400 m (1250 ft) 3.5 km (2.2 mi) 8.1 km (5.1 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.1 km (0.7 mi)

3/25/08, 1:37 PM 304

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 100 m (300 ft) 0.8 km (0.5 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)

 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 100 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi)

apon) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi)

 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 200 m (600 ft) 1.0 km (0.6 mi) 3.8 km (2.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.7 km (1.1 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.8 km (1.8 mi)

3/25/08, 1:37 PM 305

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.2 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.2 km (0.8 mi) 4.0 km (2.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.6 km (0.4 mi) 1.5 km (1.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)

60 m (200 ft) 0.6 km (0.4 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 3.1 km (1.9 mi) 6.6 km (4.1 mi)

30 m (100 ft) 0.5 km (0.3 mi) 1.1 km (0.7 mi) 150 m (500 ft) 1.9 km (1.2 mi) 3.4 km (2.1 mi)

30 m (100 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 150 m (500 ft) 1.5 km (0.9 mi) 3.2 km (2.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.2 km (2.6 mi)

3/25/08, 1:37 PM 306

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

60 m (200 ft) 0.4 km (0.3 mi) 1.8 km (1.1 mi) 400 m (1250 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)

30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.3 km (1.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.9 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

3/25/08, 1:37 PM 307

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c 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

on land)

c 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

 water)

60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 2.2 km (1.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.1 km (0.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi)

3/25/08, 1:37 PM 308

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.5 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.2 mi)

30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.5 km (0.9 mi) 3.0 km (1.9 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.8 km (1.7 mi)30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.4 mi) 100 m (300 ft) 1.1 km (0.7 mi) 2.0 km (1.3 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.3 km (1.4 mi)

3/25/08, 1:37 PM 309

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.9 km (1.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.2 km (0.8 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.2 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.2 km (0.8 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.2 km (0.8 mi)

60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

xide

ioxide

3/25/08, 1:37 PM 310

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.2 mi)

30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi) 100 m (300 ft) 0.9 km (0.6 mi) 1.9 km (1.2 mi)30 m (100 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi) 300 m (1000 ft) 3.3 km (2.1 mi) 7.5 km (4.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi)

d

 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.8 km (0.5 mi) 1.9 km (1.2 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 0.9 km (0.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.4 km (0.9 mi)

60 m (200 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 4.3 km (2.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)

3/25/08, 1:37 PM 311

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

3/25/08, 1:37 PM 312

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

3/25/08, 1:37 PM 313

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

o.s. 100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

o.s.

o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 1.0 km (0.6 mi) 3.2 km (2.0 mi)o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 1.0 km (0.6 mi) 3.2 km (2.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

3/25/08, 1:37 PM 314

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

e

100 m (300 ft) 0.9 km (0.6 mi) 2.1 km (1.3 mi) 500 m (1500 ft) 5.5 km (3.5 mi) 8.9 km (5.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.3 km (1.5 mi)

60 m (200 ft) 0.4 km (0.3 mi) 1.6 km (1.0 mi) 500 m (1500 ft) 4.8 km (3.0 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.7 mi) 400 m (1250 ft) 3.1 km (2.0 mi) 9.4 km (5.9 mi)

30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 400 m (1250 ft) 3.0 km (1.9 mi) 9.4 km (5.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

3/25/08, 1:37 PM 315

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200 m (600 ft) 1.1 km (0.7 mi) 4.0 km (2.5 mi) 1000 m (3000 ft) 7.0 km (4.4 mi) 11.0+ km (7.0+ mi)

400 m (1250 ft) 2.0 km (1.3 mi) 5.5 km (3.4 mi) 1000 m (3000 ft) 9.2 km (5.7 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 800 m (2500 ft) 4.2 km (2.6 mi) 10.3 km (6.4 mi)

800 m (2500 ft) 5.3 km (3.3 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 4.9 km (3.1 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 0.9 km (0.5 mi) 2.8 km (1.8 mi)

60 m (200 ft) 0.4 km (0.3 mi) 1.9 km (1.2 mi) 500 m (1500 ft) 2.9 km (1.8 mi) 6.4 km (4.0 mi)

200 m (600 ft) 1.2 km (0.8 mi) 4.3 km (2.7 mi) 1000 m (3000 ft) 9.4 km (5.9 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 1.0 km (0.6 mi) 2.9 km (1.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 150 m (500 ft) 1.0 km (0.6 mi) 3.2 km (2.0 mi)

30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 200 m (600 ft) 1.3 km (0.8 mi) 3.8 km (2.4 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

200 m (600 ft) 1.3 km (0.8 mi) 4.6 km (2.9 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 500 m (1500 ft) 3.3 km (2.1 mi) 8.7 km (5.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 100 m (300 ft) 0.9 km (0.5 mi) 1.5 km (0.9 mi)

3/25/08, 1:37 PM 316

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.7 km (1.1 mi) 3.0 km (1.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

n water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 100 m (300 ft) 1.0 km (0.6 mi) 1.7 km (1.1 mi)

d in water) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 0.9 km (0.5 mi) 3.0 km (1.9 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.6 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

60 m (200 ft) 0.3 km (0.2 mi) 1.5 km (0.9 mi) 1000 m (3000 ft) 8.4 km (5.2 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.1 km (0.7 mi)

3/25/08, 1:37 PM 317

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30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.3 km (0.8 mi)

60 m (200 ft) 0.7 km (0.4 mi) 2.0 km (1.3 mi) 300 m (1000 ft) 3.1 km (1.9 mi) 5.3 km (3.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

150 m (500 ft) 1.8 km (1.1 mi) 5.3 km (3.3 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

150 m (500 ft) 1.5 km (1.0 mi) 3.8 km (2.4 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

100 m (300 ft) 1.2 km (0.8 mi) 2.8 km (1.7 mi) 800 m (2500 ft) 9.6 km (6.0 mi) 11.0+ km (7.0+ mi)

100 m (300 ft) 1.3 km (0.8 mi) 3.0 km (1.9 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

100 m (300 ft) 1.1 km (0.7 mi) 2.6 km (1.6 mi) 800 m (2500 ft) 9.3 km (5.8 mi) 11.0+ km (7.0+ mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.7 km (1.1 mi) 400 m (1250 ft) 4.8 km (3.0 mi) 6.9 km (4.3 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 400 m (1250 ft) 4.8 km (3.0 mi) 7.4 km (4.6 mi)

30 m (100 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.5 km (1.6 mi)30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi) 100 m (300 ft) 1.0 km (0.6 mi) 1.4 km (0.9 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.2 km (0.8 mi) 4.2 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 300 m (1000 ft) 1.6 km (1.0 mi) 4.3 km (2.7 mi)

60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi) 400 m (1250 ft) 2.3 km (1.4 mi) 6.5 km (4.1 mi)

3/25/08, 1:37 PM 318

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"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.5 km (1.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.5 km (0.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1500 ft) 2.8 km (1.7 mi) 7.2 km (4.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.5 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 1.0 km (0.6 mi) 3.0 km (1.9 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.3 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

n) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi)

3/25/08, 1:37 PM 319

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 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 0.5 km (0.3 mi) 2.0 km (1.3 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.6 km (0.4 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 800 m (2500 ft) 2.3 km (1.4 mi) 4.5 km (2.8 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.7 km (1.1 mi) 2.4 km (1.5 mi) 60 m (200 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.9 km (0.6 mi) 1.1 km (0.7 mi) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.4 km (0.3 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi)

n) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi)n) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)n) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi)

pon)

pon) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.4 km (0.3 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

3/25/08, 1:37 PM 320

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

on) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.7 km (1.1 mi) 2.4 km (1.5 mi)

on) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.6 km (0.4 mi) 0.7 km (0.4 mi)

60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.7 km (1.1 mi) 2.4 km (1.5 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

60 m (200 ft) 0.8 km (0.5mi) 1.8 km (1.1 mi) 400 m (1250 ft) 4.8 km (3.0 mi) 7.4 km (4.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.4 km (0.3 mi) 30 m (100 ft) 0.1 km (0.1 mi) 0.7 km (0.4 mi) 100 m (300 ft) 0.5 km (0.3 mi) 2.3 km (1.4 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)

30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi)

30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 200 m (600 ft) 2.6 km (1.6 mi) 4.5 km (2.8 mi)

30 m (100 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 400 m (1250 ft) 2.4 km (1.5 mi) 6.5 km (4.0 mi)

3/25/08, 1:37 PM 321

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30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

s.

s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

anic, 100 m (300 ft) 1.2 km (0.8 mi) 2.8 km (1.8 mi) 600 m (2000 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

anic, n.o.s.

anic, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

100 m (300 ft) 1.2 km (0.8 mi) 2.8 km (1.8 mi) 600 m (2000 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

e A)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

e B)

3/25/08, 1:37 PM 322

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)60 m (200 ft) 0.7 km (0.4 mi) 2.3 km (1.4 mi) 400 m (1250 ft) 4.6 km (2.9 mi) 8.9 km (5.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

100 m (300 ft) 1.1 km (0.7 mi) 2.6 km (1.6 mi) 600 m (2000 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

e A)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

e B)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.3 km (1.4 mi)

3/25/08, 1:37 PM 323

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e

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)

60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi) 600 m (2000 ft) 5.8 km (3.6 mi) 11.0+ km (7.0+ mi)

3/25/08, 1:37 PM 324

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

30 m (100 ft) 0.2 km (0.2 mi) 1.0 km (0.7 mi) 800 m (2500 ft) 4.6 km (2.9 mi) 11.0+ km (7.0+ mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.9 km (0.5 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 500 m (1500 ft) 3.1 km (2.0 mi) 8.4 km (5.2 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

s.

s. 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.0 km (0.6 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.0 km (0.6 mi)

 n.o.s. 60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

e A)

3/25/08, 1:37 PM 325

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)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

ct

ases,

e A)

ct 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

ases,

e B)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

e A)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

e B)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

h

e A)

h 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

,

e B)

3/25/08, 1:37 PM 326

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

e A)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

e B)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

e C)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

e D)

100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 1.0 km (0.6 mi) 3.2 km (2.0 mi)

3/25/08, 1:37 PM 327

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100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 1.0 km (0.6 mi) 3.2 km (2.0 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.9 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.9 km (0.5 mi)

30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 200 m (600 ft) 2.6 km (1.6 mi) 4.5 km (2.8 mi)

3/25/08, 1:37 PM 328

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

e A)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

e B)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.2 km (0.8 mi)

60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

3/25/08, 1:37 PM 329

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30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 200 m (600 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)

100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

3/25/08, 1:37 PM 330

Downloaded from http://www.everyspec.com
"+" means distance can be larger in certain atmospheric conditions

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

150 m (500 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 400 m (1250 ft) 2.4 km (1.5 mi) 6.5 km (4.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 3.6 km (2.2 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

150 m (500 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 800 m (2500 ft) 4.2 km (2.6 mi) 10.3 km (6.4 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

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100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)

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100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

e A)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)

e B)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

e C)

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30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 400 m (1250 ft) 2.4 km (1.5 mi) 6.5 km (4.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 3.6 km (2.2 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

n.o.s. 150 m (500 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

e A)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 400 m (1250 ft) 2.4 km (1.5 mi) 6.5 km (4.0 mi)

e B)

30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 3.6 km (2.2 mi)

e C)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

e D)

100 m (300 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 800 m (2500 ft) 4.2 km (2.6 mi) 10.3 km (6.4 mi)

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100 m (300 ft) 0.7 km (0.4 mi) 2.5 km (1.6 mi) 800 m (2500 ft) 4.7 km (2.9 mi) 10.3 km (6.4 mi)

30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 800 m (2500 ft) 4.2 km (2.6 mi) 10.3 km (6.4 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)

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60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.6 mi) 500 m (1500 ft) 2.7 km (1.7 mi) 7.2 km (4.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.8 km (0.5 mi) 2.3 km (1.4 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.5 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 8.9 km (5.6 mi)

30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 400 m (1250 ft) 1.9 km (1.2 mi) 4.8 km (3.0 mi)30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.7 km (0.5 mi) 2.7 km (1.7 mi)

sive, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

.o.s.

sive, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)

ammable,

)

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60 m (200 ft) 0.7 km (0.4 mi) 2.3 km (1.4 mi) 400 m (1250 ft) 4.6 km (2.9 mi) 8.9 km (5.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)60 m (200 ft) 0.8 km (0.5 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 2.9 km (1.8 mi) 5.7 km (3.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

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30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 200 m (600 ft) 0.7 km (0.5 mi) 2.5 km (1.6 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi)

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 Next Page for Table of Water-Reactive Materials Which Produce Toxic Gases

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30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.0 km (0.7 mi) 2.0 km (1.3 mi)

3/25/08, 1:37 PM 341

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Chemical Symbols for TIH Gases:

Br 2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2S Hydrogen sulphide

NH3 Ammonia

P

N

S

S

Page 342 Use this list only when material is spilled in w

1242 139 Methyldichlorosilane 

1250 155 Methyltrichlorosilane 

1295 139 Trichlorosilane 

1298 155 Trimethylchlorosilane 

1305 155P Vinyltrichlorosilane 

1305 155P Vinyltrichlorosilane, stabilized 

1340 139 Phosphorus pentasulfide, free from yellow and white Phosphoru

1340 139 Phosphorus pentasulphide, free from yellow and white Phospho

1360 139 Calcium phosphide 

1384 135 Sodium dithionite 

1384 135 Sodium hydrosulfite 

1384 135 Sodium hydrosulphite 

1397 139 Aluminum phosphide 

1412 139 Lithium amide 

1419 139 Magnesium aluminum phosphide 

1432 139 Sodium phosphide 

1541 155 Acetone cyanohydrin, stabilized 

1680 157 Potassium cyanide 

1680 157 Potassium cyanide, solid 

1689 157 Sodium cyanide 

1689 157 Sodium cyanide, solid 

WR 342_347 Eng.pmd 2/14/0342
Chemical Symbols for TIH Gases:

Br2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2

S Hydrogen sulphide

NH3 Ammonia

Use this list only when material is spilled in 

1725 137 Aluminum bromide, anhydrous 

1726 137 Aluminum chloride, anhydrous 

1728 155 Amyltrichlorosilane 

1732 157 Antimony pentafluoride 

1741 125 Boron trichloride 

1745 144 Bromine pentafluoride 

1746 144 Bromine trifluoride 

1747 155 Butyltrichlorosilane 

1752 156 Chloroacetyl chloride 

1753 156 Chlorophenyltrichlorosilane 

1754 137 Chlorosulfonic acid 

1754 137 Chlorosulfonic acid and Sulfur trioxide mixture 

1754 137 Chlorosulphonic acid 

1754 137 Chlorosulphonic acid and Sulphur trioxide mixture 

1754 137 Sulfur trioxide and Chlorosulfonic acid 

1754 137 Sulphur trioxide and Chlorosulphonic acid 

1758 137 Chromium oxychloride 

1762 156 Cyclohexenyltrichlorosilane 

1763 156 Cyclohexyltrichlorosilane 

1765 156 Dichloroacetyl chloride 

1766 156 Dichlorophenyltrichlorosilane 

WR 342_347 Eng.pmd 2/14/0343
Chemical Symbols for TIH Gases:

Br 2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2S Hydrogen sulphide

NH3 Ammonia

P

N

S

S

Page 344 Use this list only when material is spilled in w

1777 137 Fluorosulfonic acid 

1777 137 Fluorosulphonic acid 

1781 156 Hexadecyltrichlorosilane 

1784 156 Hexyltrichlorosilane 

1799 156 Nonyltrichlorosilane 

1800 156 Octadecyltrichlorosilane 

1801 156 Octyltrichlorosilane 

1804 156 Phenyltrichlorosilane 

1806 137 Phosphorus pentachloride 

1808 137 Phosphorus tribromide 

1809 137 Phosphorus trichloride 

1810 137 Phosphorus oxychloride 

1815 132 Propionyl chloride 

1816 155 Propyltrichlorosilane 

1818 157 Silicon tetrachloride 

1828 137 Sulfur chlorides 

1828 137 Sulphur chlorides 

1834 137 Sulfuryl chloride 

1834 137 Sulphuryl chloride 

1836 137 Thionyl chloride 

1838 137 Titanium tetrachloride 

WR 342_347 Eng.pmd 2/14/0344
Chemical Symbols for TIH Gases:

Br2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2

S Hydrogen sulphide

NH3 Ammonia

Use this list only when material is spilled in 

1923 135 Calcium hydrosulphite 

1929 135 Potassium dithionite 

1929 135 Potassium hydrosulfite 

1929 135 Potassium hydrosulphite 

1931 171 Zinc dithionite 

1931 171 Zinc hydrosulfite 

1931 171 Zinc hydrosulphite 

2004 135 Magnesium diamide 

2011 139 Magnesium phosphide 

2012 139 Potassium phosphide 

2013 139 Strontium phosphide 

2308 157 Nitrosylsulfuric acid 

2308 157 Nitrosylsulfuric acid, liquid 

2308 157 Nitrosylsulfuric acid, solid 

2308 157 Nitrosylsulphuric acid 

2308 157 Nitrosylsulphuric acid, liquid 

2308 157 Nitrosylsulphuric acid, solid 

2353 132 Butyryl chloride 

2395 132 Isobutyryl chloride 

2434 156 Dibenzyldichlorosilane 

2435 156 Ethylphenyldichlorosilane 

WR 342_347 Eng.pmd 2/14/0345
Chemical Symbols for TIH Gases:

Br 2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2S Hydrogen sulphide

NH3 Ammonia

P

N

S

S

Page 346 Use this list only when material is spilled in w

2692 157 Boron tribromide 

2806 138 Lithium nitride 

2977 166 Radioactive material, Uranium hexafluoride, fissile 

2977 166 Uranium hexafluoride, fissile containing more than 1% 

Uranium-235

2978 166 Radioactive material, Uranium hexafluoride 

2978 166 Uranium hexafluoride 

2978 166 Uranium hexafluoride non fissile or fissile-excepted 

2985 155 Chlorosilanes, flammable, corrosive, n.o.s. 

2985 155 Chlorosilanes, n.o.s. 

2986 155 Chlorosilanes, corrosive, flammable, n.o.s. 

2986 155 Chlorosilanes, n.o.s. 

2987 156 Chlorosilanes, corrosive, n.o.s. 

2987 156 Chlorosilanes, n.o.s. 

2988 139 Chlorosilanes, n.o.s. 

2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. 

3048 157 Aluminum phosphide pesticide 

3049 138 Metal alkyl halides, n.o.s. 

3049 138 Metal alkyl halides, water-reactive, n.o.s. 

3049 138 Metal aryl halides, n.o.s. 

3049 138 Metal aryl halides, water-reactive, n.o.s. 

WR 342_347 Eng.pmd 2/14/0346
Chemical Symbols for TIH Gases:

Br2 Bromine

Cl 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2S Hydrogen sulfide

H2

S Hydrogen sulphide

NH3 Ammonia

Use this list only when material is spilled in 

3361 156 Chlorosilanes, poisonous, corrosive, n.o.s. 

3361 156 Chlorosilanes, toxic, corrosive, n.o.s. 

3362 155 Chlorosilanes, poisonous, corrosive, flammable, n.o.s. 

3362 155 Chlorosilanes, toxic, corrosive, flammable, n.o.s. 

3456 157 Nitrosylsulfuric acid, solid 

3456 157 Nitrosylsulphuric acid, solid 

3461 135 Aluminum alkyl halides, solid 

9191 143 Chlorine dioxide, hydrate, frozen 

WR 342_347 Eng.pmd 2/14/0347
Page 348

during structural fire fighting operations. It includes a helmet, coat, pants, 

a hood to cover parts of the head not protected by the helmet and facepi

must be used with full-facepiece positive pressure self-contained breathing a

This protective clothing should, at a minimum, meet the OSHA Fire B

(29 CFR 1910.156). Structural fire fighters’ protective clothing provides 

from heat and cold, but may not provide adequate protection from the 

liquids that are encountered during dangerous goods incidents. Each 

statement about the use of SFPC in incidents involving those materials r

guide. Some guides state that SFPC provides limited protection. In those ca

wearing SFPC and SCBA may be able to perform an expedient, that is q

operation. However, this type of operation can place the responder at 

injury or death. The incident commander makes the decision to perform t

if an overriding benefit can be gained (i.e., perform an immediate rescue, 

control a leak, etc.). The coverall-type protective clothing customarily wo

forests or wildlands is not SFPC and is not recommended nor referred to 

guidebook.

Positive Pressure Self-Contained Breathing Apparatus (SCBA). This a

a constant, positive pressure flow of air within the facepiece, even if one in

doing heavy work. Use apparatus certified by NIOSH and the Departm

Safety and Health Administration in accordance with 42 CFR Part 84. Us

with the requirements for respiratory protection specified in OSHA 2

(Respiratory Protection) and/or 29 CFR 1910.156 (f) (Fire Brigades Stan

cartridge respirators or other filtering masks are not acceptable substitutes fo

self-contained breathing apparatus. Demand-type SCBA does not meet t

1910.156 (f)(1)(i) of the Fire Brigades Standard. If it is suspected that a 

Agent (CW) is involved, the use of NIOSH-certified respirators with CB

highly recommended.

Chemical Protective Clothing and Equipment. Safe use of this type of 

and equipment requires specific skills developed through training and 

generally not available to, or used by, first responders. This type of spe

protect against one chemical, yet be readily permeated by chemicals fo

designed. Therefore, protective clothing should not be used unless it is c

released material. This type of special clothing offers little or no protection 

or cold. Examples of this type of equipment have been described as (1

WhitePages 348_370 Eng.pmd 2/14/0348
* Consult glossary for additional protection levels under the headi

WhitePages 348_370 Eng.pmd 2/14/0349
Page 350

Fires involving a spill of flammable liquids are generally controlled by app

foam to the surface of the burning material. Fighting flammable liquid f

concentrate which is chemically compatible with the burning material, co

foam concentrate with water and air, and careful application and mainte

blanket. There are two general types of fire fighting foam: regular and 

Examples of regular foam are protein-base, fluoroprotein, and aqueous 

(AFFF). Some flammable liquids, including many petroleum products, ca

applying regular foam. Other flammable liquids, including polar solvents 

which are water soluble) such as alcohols and ketones, have different ch

A fire involving these materials cannot be easily controlled with regular f

application of alcohol-resistant foam. Polar-solvent fires may be difficult to c

a higher foam application rate than other flammable liquid fires (see NFPA

11 and 11A for further information). Refer to the appropriate guide to deter

foam is recommended. Although it is impossible to make specific reco

flammable liquids which have subsidiary corrosive or toxic hazards, alco

may be effective for many of these materials. The emergency response 

on the shipping document, or the appropriate emergency response a

contacted as soon as possible for guidance on the proper fire extinguish

The final selection of the agent and method depends on many factors 

location, exposure hazards, size of the fire, environmental concerns, as we

of extinguishing agents and equipment at the scene.

WATER REACTIVE MATERIALS

Water is sometimes used to flush spills and to reduce or direct vapors 

Some of the materials covered by the guidebook can react violently or eve

water. In these cases, consider letting the fire burn or leaving the spil

prevent its spreading by diking) until additional technical advice can b

applicable guides clearly warn you of these potentially dangerous reactions

require technical advice since

(1) water getting inside a ruptured or leaking container may ca

(2) water may be needed to cool adjoining containers to prev

(exploding) or further spread of the fires;

(3) water may be effective in mitigating an incident involving a wat

only if it can be applied at a sufficient flooding rate for an ext

WhitePages 348_370 Eng.pmd 2/14/0350
ggy pp

emergency response agency.

VAPOR CONTROL

Limiting the amount of vapor released from a pool of flammable 

operational concern. It requires the use of proper protective clothin

appropriate chemical agents, and skilled personnel. Before enga

advice from an authoritative source as to the proper tactics.

There are several ways to minimize the amount of vapors esca

liquids, such as special foams, adsorbing agents, absorbing agents

To be effective, these vapor control methods must be selected for the 

and performed in a manner that will mitigate, not worsen, the incid

Where specific materials are known, such as at manufacturing 

desirable for the dangerous goods response team to prearrange w

select and stockpile these control agents in advance of a spill. In 

may not have the most effective vapor control agent for the mat

likely to have only water and only one type of fire fighting foam 

available foam is inappropriate for use, they are likely to use water 

is being used to form a vapor seal, care must be taken not to churn 

during application. Vapors that do not react with water may be di

using the air currents surrounding the water spray. Before using wa

to safely control vapor emission or to suppress ignition, obtain te

specific chemical name identification.

WhitePages 348_370 Eng.pmd 2/14/0351
Page 352

DIFFERENCES BETWEEN A CHEMICAL, BIOLOGICAL AND RADIOL

Chemical and biological agents as well as radioactive materials can be disp

breathe, the water we drink, or on surfaces we physically contact. Dispersio

as simple as opening a container, using conventional (garden) spray devices

detonating an improvised explosive device.

Chemical Incidents are characterized by the rapid onset of medical sym

hours) and easily observed signatures (colored residue, dead foliage, pu

insects and animals).

Biological Incidents are characterized by the onset of symptoms in hours 

there will be no characteristic signatures because biological agents are us

colorless. Because of the delayed onset of symptoms in a biological 

affected may be greater due to the movement of infected individuals.

Radiological Incidents are characterized by the onset of symptoms, if any, 

longer. Typically, there will be no characteristic signatures because radioa

usually odorless and colorless. Specialized equipment is required to determ

affected area, and whether the level of radioactivity presents an immediate o

hazard. Because radioactivity is not detectable without special equipment, the 

be greater due to the migration of contaminated individuals.

At the levels created by most probable sources, not enough radiation would 

people or cause severe illness. In a radiological incident generated by 

Radiological Dispersal Device (RDD), in which a conventional explosive is d

radioactive contamination, the primary hazard is from the explosion. However

materials dispersed in the air could contaminate up to several city blocks

possibly panic, and requiring potentially costly cleanup.

INDICATORS OF A POSSIBLE CHEMICAL INCIDENT

Dead animals/birds/fish Not just an occasional road kill, but nume

and domestic, small and large), birds, a

area.

WhitePages 348_370 Eng.pmd 2/14/0352
o eoays poa

odor is completely out of chara

Unusual numbers of dying or Health problems including naus

sick people (mass casualties) in breathing, convulsions, localiz

(reddening of eyes/nerve age

(reddening of skin/vesicant sym

Pattern of casualties Casualties will likely be distribut

by the air ventilation system.

Blisters/rashes Numerous individuals experienc

blisters, weals (like bee stings), 

Illness in confined area Different casualty rates for peop

outdoors dependent on where t

Unusual liquid droplets Numerous surfaces exhibit oily dr

surfaces have an oily film. (No 

Different looking areas Not just a patch of dead weeds, 

food crops, and/or lawns that 

withered. (No current drought.)

Low-lying clouds Low-lying cloud/fog-like conditio

its surroundings.

Unusual metal debris Unexplained bomb/munitions-l

contains a liquid.

INDICATORS OF A POSSIBLE BIOLOGICAL INCIDENT

Unusual numbers of sick or Any number of symptoms ma

dying people or animals occur hours to days after an in

time required before symptoms 

on the agent used.

Unscheduled and unusual Especially if outdoors during p

spray being disseminated

Abandoned spray devices Devices may not have distinct 

WhitePages 348_370 Eng.pmd 2/14/0353
Page 354

Glowing material Strongly radioactive material ma

radioluminescence.

Sick people/animals In very improbable scenarios there may b

of sick or dying people or animals. Cas

hours to days or weeks after an incident 

time required before symptoms are obse

on the radioactive material used, and t

Possible symptoms include skin redden

PERSONAL SAFETY CONSIDERATIONS

When approaching a scene that may involve CB agents or radioactive m

critical consideration is the safety of oneself and other responders. Prote

respiratory protection of appropriate level of safety must be used. In inc

suspected that CBRN materials have been used as weapons, NIOSH-c

with CBRN protection are highly recommended. Be aware that the presence 

of CB agents or radioactive materials may not be verifiable, especially in the 

or radiological agents. The following actions/measures to be considered 

either a chemical, biological or radiological incident. The guidance is gen

all encompassing, and its applicability should be evaluated on a case-by-

Approach and response strategies. Protect yourself and use a safe ap

any exposure time, maximize the distance between you and the item tha

you, use cover as protection and wear appropriate personal protectiv

respiratory protection). Identify and estimate the hazard by using indic

above. Isolate the area and secure the scene; potentially contaminated 

isolated and decontaminated as soon as possible. To the extent possible

limit the spread of contamination. In the event of a chemical incident, the 

odors is not necessarily an indication of reduced vapor concentrations. 

deaden the senses giving the false perception that the chemical is no lon

If there is any indication that an area may be contaminated with radioactive m

the site of any non-accidental explosion, responder personnel sho

with radiation detection equipment that would alert them if they are enteri

WhitePages 348_370 Eng.pmd 2/14/0354
NOTIFY your local police by calling 911.

• Set up Incident command upwind and uphill of the area.

• Do NOT touch or move suspicious packages/containers.

• Be cautious regarding potential presence of secondary de

Explosive Devices, IEDs).

• Avoid contamination.

• Limit access to only those responsible for rescue of victim

unknown materials or devices.

• Evacuate and isolate individuals potentially exposed to da

hazardous materials.

• Isolate contaminated areas and secure the scene for anal

Decontamination measures. Emergency responders s

decontamination procedures (flush-strip-flush). Mass casualty deco

as soon as possible by stripping (all clothing) and flushing (soap 

agents are involved or suspected, careful washing and use of a br

chemical agents are suspected, the most important and effective 

that done within the first one or two minutes. If possible, further d

performed using a 0.5% hypochlorite solution (1 part household b

water). If biological agents are suspected, a contact time of 10 

allowed before rinsing. The solution can be used on soft tissue 

used in eyes or open wounds of the abdomen, chest, head, or spin

contact the agencies listed in this guidebook.

For persons contaminated with radioactive material, remove them 

necessary. Remove their clothing and place it in a clearly marked se

plastic bag, for later testing. Use decontamination methods described 

the skin, e.g., from shaving, or overly vigorous brushing. External rad

intact skin surface rarely causes a high enough dose to be a hazard 

person or the first responders. For this reason, except in very u

injured person who is also radiologically contaminated should be m

care to minimize the spread of the contamination to the e

decontamination measures are initiated.

NOTE: The above information was developed in part by the Depar

(Canada), the U.S. Department of the Army, Aberdeen Proving 

Bureau of Investigation (FBI).

WhitePages 348_370 Eng.pmd 2/14/0355
Page 356

4 hours, and 8 hours) and are distinguished b

of severity of toxic effects; see AEGL-1, AEGL

AEGL-1 AEGL-1 is the airborne concentration (expre

million or milligrams per cubic meter [ppm 

substance above which it is predicted that the g

including susceptible individuals, could ex

discomfort, irritation, or certain asymptoma

effects. However, the effects are not disabling 

and reversible upon cessation of exposure.

AEGL-2 AEGL-2 is the airborne concentration (expr

mg/m3

) of a substance above which it is predict

population, including susceptible individuals, 

irreversible or other serious, long-lasting adve

or an impaired ability to escape.

AEGL-3 AEGL-3 is the airborne concentration (expr

mg/m3) of a substance above which it is predict

population, including susceptible individuals, 

life-threatening health effects or death.

Alcohol resistant foam A foam that is resistant to “polar” chemicals su

esters which may break down other types of f

Biological agents Living organisms that cause disease, sicknes

humans. Anthrax and Ebola are examples of 

Refer to GUIDE 158.

Blister agents (vesicants) Substances that cause blistering of the skin. E

liquid or vapor contact with any exposed tissue 

Mustard (H), Distilled Mustard (HD), Nitrogen 

Lewisite (L) are blister agents.

Symptoms: Red eyes, skin irritation, burnin

upper respiratory damage, cough, hoarseness

WhitePages 348_370 Eng.pmd 2/14/0356
seizures, coma.

Burn Refers to either a chemical or therma

caused by corrosive substances an

cryogenic gases, hot molten substanc

CBRN Chemical, biological, radiological or nu

Choking agents Substances that cause physical injury 

through inhalation. In extreme cases, m

become filled with liquid (pulmonary ed

lack of oxygen; hence, the victim is “ch

a choking agent.

Symptoms: Irritation to eyes/nose/th

nausea and vomiting, burning of expo

CO2 Carbon dioxide gas.

Cold zone Area where the command post and s

necessary to control the incident are loc

to as the clean zone, green zone o

documents. (EPA Standard Operating 

29 CFR 1910.120, NFPA 472)

Combustible liquid Liquids which have a flash point greate

below 93oC (200oF). U.S. regulations 

with a flash point between 38oC (100oF

reclassed as a combustible liquid.

Compatibility Group Letters identify explosives that are d

Class 1 materials are considered to b

be transported together without signific

probability of an incident or, for a give

of the effects of such an incident.

A Substances which are expected 

soon after fire reaches them.

WhitePages 348_370 Eng.pmd 2/14/0357
Page 358

D Substances or articles which may mas

blast and/or fragment hazard) when ex

E&F Articles which may mass detonate in a 

G Substances and articles which may m

give off smoke or toxic gases.

H Articles which in a fire may eject haza

and dense white smoke.

J Articles which may mass explode.

K Articles which in a fire may eject haza

and toxic gases.

L Substances and articles which presen

and could be activated by exposure to 

N Articles which contain only extremely 

detonating substances and demonstra

probability of accidental ignition or pro

S Packaged substances or articles whic

initiated, produce effects that are usually 

immediate vicinity.

Control zones Designated areas at dangerous goods incident

and the degree of hazard. Many terms are used 

zones; however, in this guidebook, these zones 

hot/exclusion/red/restricted zone, warm/contam

yellow/limited access zone, and cold/support/

(EPA Standard Operating Safety Guidelines

1910.120, NFPA 472)

Cryogenic liquid A refrigerated, liquefied gas that has a bo

than -90o

C (-130oF) at atmospheric pressure.

Dangerous Water Produces significant toxic gas when it comes in 

Reactive Material

WhitePages 348_370 Eng.pmd 2/14/0358
soon as possible. Since the methods used 

and equipment differ from one chemic

chemical manufacturer, through the ag

back cover, to determine the appropriate 

clothing and equipment should be remo

a controlled area (warm/contamination red

until cleanup procedures can be initiated

clothing and equipment cannot be dec

disposed of in a proper manner.

Dry chemical A preparation designed for fighting f

liquids, pyrophoric substances an

Common types contain sodium bic

bicarbonate.

Edema The accumulation of an excessive amo

and tissues. Pulmonary edema is an e

in the lungs, for instance, after inhalatio

to lung tissue.

ERPG(s) Emergency Response Planning Guid

to provide estimates of concentration 

could reasonably anticipate observin

see ERPG-1, ERPG-2 and ERPG-3.

ERPG-1 The maximum airborne concentration 

nearly all individuals could be expose

experiencing more than mild, transient 

without perceiving a clearly defined obj

ERPG-2 The maximum airborne concentration 

nearly all individuals could be expose

experiencing or developing irreversib

effects or symptoms that could impair a

protective action.

WhitePages 348_370 Eng.pmd 2/14/0359
Page 360

Flash point Lowest temperature at which a liquid or solid 

such a concentration that, when the vapor com

the surface of the liquid or solid, a flammable 

Hence, the lower the flash point, the more flamm

Hazard zones HAZARD ZONE A: Gases: LC50 of less tha

(Inhalation Hazard 200 ppm,

Zones) Liquids: V equal to or gre

LC50 and LC50 less than 

200 ppm,

HAZARD ZONE B: Gases: LC50 greater tha

less than or equal to 100

Liquids: V equal to or gre

LC50; LC50 less than or e

and criteria for Hazard Zo

HAZARD ZONE C: LC50 greater than 1000 

than or equal to 3000 pp

HAZARD ZONE D: LC50 greater than 3000 

than or equal to 5000 pp

Hot zone Area immediately surrounding a dangerous go

extends far enough to prevent adverse effe

dangerous goods to personnel outside the zo

also referred to as exclusion zone, red zone o

other documents. (EPA Standard Operating S

OSHA 29 CFR 1910.120, NFPA 472)

IED See “Improvised Explosive Device”.

Immiscible In this guidebook, means that a material does n

water.

Improvised Explosive A bomb that is manufactured from comm

Device homemade explosives.

Large spill A spill that involves quantities that are greater 

liquids and greater than 300 kilograms for sol

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Mass explosion Explosion which affects almost th

instantaneously.

mg/m3 Milligrams of a material per cubic met

Miscible In this guidebook, means that a materia

mL/m3 Milliliters of a material per cubic mete

1 ppm)

Nerve agents Substances that interfere with the 

Exposure is primarily through contact w

eyes) and secondarily through inhala

(GA), Sarin (GB), Soman (GD) and VX 

Symptoms: Pinpoint pupils, extreme h

in the chest, dyspnea, runny nose

unresponsiveness, seizures.

Non-polar See “Immiscible”.

n.o.s. These letters refer to “not otherwise spe

use this description are generic names 

n.o.s.” This means that the actual 

corrosive liquid is not listed in the regula

name must be used to describe it on s

Noxious In this guidebook, means that a ma

injurious to health or physical well-bein

Oxidizer A chemical which supplies its own oxyg

combustible material burn more readil

P The letter “P” following a guide numb

and blue-bordered pages identifies 

polymerize violently under high tem

contamination with other products. 

produce heat and high pressure buildu

explode or rupture. (See polymerizati

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Page 362

PG See Packing Group

pH pH is a value that represents the acidity or a

solution. Pure water has a pH of 7. A pH value b

acid solution (a pH of 1 is extremely acidic). A pH 

an alkaline solution (a pH of 14 is extremely al

alkalies (bases) are commonly referred to as co

PIH Poison Inhalation Hazard. Term used to de

volatile liquids that are toxic when inhaled. (S

Polar See “Miscible”.

Polymerization This term describes a chemical reaction w

associated with the production of plastic subs

the individual molecules of the chemical (liquid 

each other to produce what can be describe

These chains can be formed in many useful a

known example is the styrofoam (polystyrene

is formed when liquid molecules of styrene rea

or polymerize forming a solid, therefore chang

styrene to polystyrene (poly means many).

ppm Parts per million. (1 ppm equals 1 mL/m3

)

Protective clothing Includes both respiratory and physical protec

assign a level of protection to clothing or re

separately. These levels were accepted and de

organizations such as U.S. Coast Guard, NIOS

Level A: SCBA plus totally encapsulating c

clothing (permeation resistant).

Level B: SCBA plus hooded chemical resista

suit).

Level C: Full or half-face respirator plus 

resistant clothing (splash suit).

Level D: Coverall with no respiratory protecti

WhitePages 348_370 Eng.pmd 2/14/0362
hazard conditions during normal 

emergencies. If the identity and telepho

are not known by emergency responde

response plan, the information can be o

listed on the inside back cover. The

updated list of radiation authorities.

Radioactivity The property of some substances to em

harmful radiation.

Refrigerated liquid See “Cryogenic liquid”.

Small spill A spill that involves quantities that ar

liquids and less than 300 kilograms fo

Straight (solid) stream Method used to apply or distribute wat

The water is delivered under pressure fo

straight (solid) stream, approximately 

through an imaginary circle 38 cm (15 

breaking point. Hose (solid or straight) s

to cool tanks and other equipment expos

or for washing burning spills away from 

straight streams will cause a spill fire to s

when directed into open containers of fl

liquids.

TIH Toxic Inhalation Hazard. Term used to d

liquids that are toxic when inhaled. (Sa

V Saturated vapor concentration in ai

(volatility) at 20oC and standard atmos

Vapor density Weight of a volume of pure vapor or 

compared to the weight of an equal vol

temperature and pressure. A vapor densit

that the vapor is lighter than air and 

density greater than 1 (one) indicates 

than air and may travel along the grou

WhitePages 348_370 Eng.pmd 2/14/0363
Page 364

through holes in containers or tanks.

Warm zone Area between Hot and Cold zones wher

equipment decontamination and hot zone sup

includes control points for the access corridor 

reducing the spread of contamination. Also 

contamination reduction corridor (CRC), conta

zone (CRZ), yellow zone or limited acce

documents. (EPA Standard Operating Safety 

29 CFR 1910.120, NFPA 472)

Water-sensitive Substances which may produce flamma

decomposition products upon contact with wa

Water spray (fog) Method or way to apply or distribute water. T

divided to provide for high heat absorption. Wa

can range from about 10 to 90 degrees. Wa

can be used to extinguish or control the burn

provide exposure protection for personnel, equ

etc. (This method can be used to absorb 

down vapors or disperse vapors. Direct a w

rather than a straight (solid) stream, into th

accomplish any of the above).

Water spray is particularly effective on fires of flam

volatile solids having flash points above 37.8oC 

Regardless of the above, water spray can be us

flammable liquids with low flash points. The effe

particularly on the method of application. Wi

even gasoline spill fires of some types have 

when coordinated hose lines were used to sw

the surface of the liquid. Furthermore, water spr

has frequently been used with success in e

involving flammable liquids with high flash poin

liquids) by causing frothing to occur only on th

foaming action blankets and extinguishes the f

WhitePages 348_370 Eng.pmd 2/14/0364
ppgp

Safety Administration, (PHMSA) Office of Hazardous Materials In

ERG2008 is based on earlier Transport Canada, U.S. DOT, and Secr

and Transport emergency response guidebooks. ERG2008 is pub

English, French and Spanish. The Emergency Response Guideboo

printed in other languages, including Chinese, German, Hebrew, Japa

Hungarian, Polish, Turkish and Thai.

We encourage countries that wish to participate in future editions of the 

emergency response center information for inclusion. Please cont

telephone numbers in the paragraph below.

DISTRIBUTION OF THIS GUIDEBOOK

The primary objective is to place one copy of the ERG2008 in each p

service vehicle through distribution to Federal, state, provincia

authorities. The distribution of this guidebook is being accomplis

cooperation of a network of key agencies. Emergency service or

yet received copies of ERG2008 should contact the respective d

country, state or province. In the U.S., information about the d

location may be obtained from the Office of Hazardous Materials 

hazmat.dot.gov or call 202-366-4900. In Canada, contact CANUTE

the web site at http://www.canutec.gc.ca for information. In Mexico

1275 or 684-0188 or via email at iflores@sct.gob.mx. In Arg

011-4613-1100, or via the web site at http://www.ciquime

gre2008@ciquime.org.ar

REPRODUCTION and RESALE

Copies of this document which are provided free of charge to fire, po

services may not be resold. ERG2008 (PHH50-ERG2008) may be 

permission subject to the following:

The names and the seals of the participating governments may no

of this document unless that copy accurately reproduces the entire 

coloration) of this document without modification. In addition, the 

address must be displayed on the outside back cover of each co

placed on the center of the back cover.

WhitePages 348_370 Eng.pmd 2/14/0365
Page 366

Canada K1A 0N5

Phone: 613-992-4624 (information)

Fax: 613-954-5101

Email: canutec@tc.gc.ca

In the U.S.:

U. S. Department of Transportation

 Pipeline and Hazardous Materials Safety Administratio

Office of Hazardous Materials Initiatives and Training (PHH

Washington, DC 20590-0001

Phone: 202-366-4900

Fax: 202-366-7342

Email: ERG2008@dot.gov

In Mexico:

Secretariat for Communications and Transport

Land Transport Directorate

Hazardous Materials and Wastes Directorate

Calz. de las Bombas No. 411-9 piso

Col. San Bartolo Coapa

Coyoacan 04800, D.F.

Mexico

Phone and Fax: +52-55-5684-1275 and 684-0188

In Argentina:

Chemistry Information Center for Emergencies (CIQUIM

Juan Bautista Alberdi 2986

C1406GSS Buenos Aires, Argentina

Tel. +54-11-4613-1100 Fax (011) 4613-3707

Email: gre2008@ciquime.org.ar

WhitePages 348_370 Eng.pmd 2/14/0366
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Page 368

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Page

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370
DOT/PHMSA

http://hazmat.dot.gov/pubs/erg/guidebook.h

TRANSPORT CANADA

http://www.tc.gc.ca/canutec/en/guide/guide.h

CIQUIME

http://www.ciquime.org.ar

This guidebook incorporates changes date

WhitePages 348_370 Eng.pmd 2/14/0369
Page 37

+52-55-5559-1588

2. CENACOM

01-800-00-413-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan A

5128-0000 exts. 11470, 11471, 11472, 11473, 11474, 11475, 1147

For calls originating elsewhere, call

+52-55-5128-0000 exts. 11470, 11471, 11472, 11474, 11475 a

ARGENTINA

1. CIQUIME

0-800-222-2933 in the Republic of Argentina

For calls originating elsewhere, call

+54-11-4613-1100

BRAZIL

1. PRÓ-QUÍMICA

0-800-118270

(Toll-free in Brazil)

For calls originating elsewhere, call

+55-11-232-1144

(Collect calls are accepted)

COLOMBIA

1. CISPROQUIM

01-800-091-6012 in Colombia

For calls originating in Bogotá, Colombia call

288-6012

For calls originating elsewhere call

+57-1-288-6012

For additional details see the section entiitled “WHO TO CALL FOR 

WhitePages 348_370 Eng.pmd 2/14/0370

2
QUANTITY

1 TANK TRUCK UN1219 ISOPROPANOL 3 II 12,000 LITERS

ID NUMBER

EMERGENCY CONTACT

1-000-000-0000

EXAMPLE OF EMERGENCY 

CONTACT TELEPHONE NUMBER

NO. & TYPE

OF PACKAGES

SHIPPING NAME

HAZARD CLASS

OR DIVISION NO.

PACKING GROUP

SHIPPING DOCUMENTS (PAPERS)*

The shipping document provides vital information when responding to a

hazardous materials/dangerous goods** incident. The shipping document

contains information needed to identify the materials involved. Use this

information to initiate protective actions for your own safety and the safety of the

public. The shipping document contains the 4-digit ID number (see yellowbordered pages) preceded by the letters UN or NA, the proper shipping name

(see blue-bordered pages), the hazard class or division of the material(s), and,

where appropriate, the Packing Group. The shipping document will also display

a 24-hour emergency response telephone number. In addition, there must be

information available that describes the hazards of the material which can be

used in the mitigation of an incident. The information must be entered on or be

with the shipping document. This requirement may be satisfied by attaching a

guide from the ERG2008 to the shipping document, or by having the entire

guidebook available for ready reference. Shipping documents are required for

most dangerous goods in transportation. Shipping documents are kept in

• the cab of the motor vehicle,

• the possession of the train crew member,

• a holder on the bridge of a vessel, or

• an aircraft pilot’s possession.

The 4-digit ID Number may be shown on the diamond-shaped placard or on

an adjacent orange panel displayed on the ends and sides of a cargo tank,

vehicle or rail car.

* For the purposes of this guidebook, the terms shipping document/shipping paper are synonymous.

** For the purposes of this guidebook, the terms hazardous materials/dangerous goods are synonymous.

EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER

A Numbered or

Placard

A Placard 

and an 

Orange Panel

1219

1219 FLAMMABLE
Secretariat of Transport and Communications

THIS DOCUMENT SHOULD NOT BE USED TO

DETERMINE COMPLIANCE WITH THE

DANGEROUS GOODS REGULATIONS

OR

TO CREATE WORKER SAFETY DOCUMENTS

FOR SPECIFIC CHEMICALS

U.S. Department of Transportation

Pipeline and Hazardous Materials Safety Administration

NOT FOR SALE

This document is distributed free of charge to Public Safety Organization

and may not be resold.