1 

Arizona Department of Environmental Quality 

AQS Data Certification Detail Report 

In April 2012, EPA Region 9 performed a Technical Systems Audit (TSA) of the ADEQ Air 

Monitoring Program. The first finding of the audit report was that ADEQ does not have Quality 

Assurance Project Plans (QAPPs) for O3, SO2, NO2, CO, and NCore monitoring; QAPPs for 

PM10 and PM2.5 are outdated. ADEQ provided a corrective action plan to EPA on March 28, 

2013 indicating that ADEQ was committed to developing or updating QAPPS with the goal of 

having approvable plans for all criteria pollutants in place and submitted to EPA as soon as 

possible. The proposed schedule was: 

PM NAAQS QAPP June 28, 2013 

SO2 QAPP September 30, 2013 

Ozone QAPP October 31, 2013 

NO2 and CO QAPPs December 13, 2013 

Specialized PM QAPP addendum February 28, 2014 

Trace level addendum for CO and SO2 April 30, 2014 

We understand the importance of having data that are used directly for regulatory purposes to be 

collected under approved QAPPs. We are applying additional resources to this effort to expedite 

the timeliness of completion and are committed to meeting the above schedule. The NAAQS 

monitoring for CY2014 should all be collected under developed QAPPs. 

We will continue to work with Region 9 staff to meet our QAPP requirement, however, we 

believe the absence of these QAPPs does not prevent certification of 2012 data under the 

definition “...that the previous year of ambient concentration and quality assurance data are 

completely submitted to AQS and that the ambient concentration data are accurate to the best of 

her or his knowledge, taking into consideration the quality assurance findings” as addressed in 

the following certification report. 

SECTION 1 

2012 ADEQ DATA TO BE CERTIFIED 

Tables 1, 2, and 3 in Appendix A list monitors with data reported to AQS requiring certification 

for the year 2012. They include several special purpose monitors (SPM), ADEQ’s State and 

Local Agency Monitoring Station (SLAMS) monitors, monitors in the Photochemical 

Assessment Monitoring Stations (PAMS) program, PM2.5 Chemical Speciation Network (CSN) 

monitors, National Air Toxics Trends Sites (NATTS) monitors, and Urban Air Toxics 

Monitoring Program (UATMP) monitors. A detailed description of these data and monitors 

follows. 
2 

1.1 2012 CRITERIA POLLUTANT DATA FROM ADEQ SLAMS and SPM SITES 

Table 1 in Appendix A lists the sites and parameters with 2012 data that ADEQ reported to AQS 

after completing our data review procedures. Appendix B includes the AQS AMP600 and 

AMP450NC reports verifying submittal completeness of the 2012 data for these monitors. 

While most of the data summarized in the attached reports are accurate and complete, ADEQ 

staff did encounter some challenges throughout the year. The following is a description of these 

challenges as well as some clarifications. 

1.1.1 Ozone Monitoring 

After the issues in 2011 with the internal ozone calibrators, Air Monitoring staff decided to use 

the external Thermo 49C Ozone Calibrators with an external zero air source. The addition of a 

second inline filter has proven effective in preventing particulate matter build-up of the sample 

lines and internal plumbing. This is supported by the data completeness percentage of 100% for 

6 of our 7 ozone sites. The seventh site had 95% data completeness as a result of a single failed 

bi-weekly zero/span/precision check invalidating 16 days of data. 

ADEQ is updating the Ozone network with remote zero/span/precision checks utilizing the 

Teledyne T703 UV Photometric Ozone Calibrator with Internal Zero Air Pump and External 

Zero Air Shut-Off Valve. Please refer to our 2013 Annual Air Monitoring Network Plan for 

more information. 

1.1.2 Carbon Monoxide Trace Level (COTL) Monitoring at ADEQ’s NCore site, JLG 

Supersite 

 

ADEQ operates a trace level carbon monoxide (CO) monitor at the JLG Phoenix Supersite (AQS 

ID 04-013-9997) as part of the NCore requirements. The COTL analyzer as well as the gas 

calibration system experienced some difficulties throughout the year. This was observed with 

the COTL not always meeting the 30ppb acceptance criteria during zero drift verification checks. 

Nearly 50% of these zero drift checks were between 30-100ppb. Additionally, there were 

moisture issues with the zero air scrubbers for the gas calibration system used to perform checks. 

This was discovered and corrected late in the year and as a result all of the 2012 data were 

flagged with the Q2 (Operational Deviations) qualifier flag. ADEQ does not wish to certify 

these Carbon Monoxide Trace Level data for CY2012. ADEQ has purchased and installed a new 

Carbon Monoxide Trace Level instrument in April 2013 that is expected to better meet 

operational requirements. 

1.1.3 Nogales Post Office PM10 and PM2.5 Instruments 

During fourth quarter, the roof at the Nogales Post Office Site where the instruments are located 

was under construction. All instruments were removed and inoperable from 11/20/12 to 

12/13/12. There was a further issue with the PM2.5 Secondary sampler (AQS ID 04-023-0004-

88101-2) at this site which resulted in further data loss. Despite data completeness for CY2012 

being above 75% (85%), this monitor fell short of the 75% quarterly completeness criteria in the 

4th quarter of 2012 (60%). Three samples during this quarter were invalidated due to instrument 
3 

clock issues that resulted in 1-Hr off-set sample start and stop times; i.e., these samples ran from 

0100-0100 rather than the required midnight-to-midnight sampling criteria. 

1.1.4 Douglas Red Cross PM10 Sampler 

The Douglas Red Cross PM10 sampler (AQS ID 04-003-1005-81102-1) did not meet the data 

completeness criteria required for PM10 SLAMS in the second quarter. Despite data 

completeness for CY2012 being above 75% (91%), this monitor fell short of the 75% quarterly 

completeness criteria in the 2nd quarter of 2012 (73%). Six run days during this quarter were 

invalidated due to the routine flow verification failure in April 2012. ADEQ has invested 

heavily in continuous monitors and replaced this sampler with a TEOM PM10 which was 

officially designated the primary sampler for this site on January 1, 2013. 

1.1.5 JLG Supersite Continuous PM10 TEOM Monitor 

The PM10 TEOM at JLG Supersite operated from January 1, 2012 through July 26, 2012. The 

instrument was primarily run for continuous method comparability and bias statistical analysis. 

Although this instrument was not audited in 2012, an audit of the instrument was performed on 

December 8, 2011. This instrument shows good data completeness for the half year it was 

operational at JLG Supersite and the verifications performed show the instrument was operating 

within specifications for PM10. Paired BAM monitors were installed in November, 2010 to meet 

the PMcoarse requirement at ADEQ’s NCore site. The data from these BAM monitors have 

confirmed the suspected biases in the PM10 TEOM data. Due to satisfactory performance of the 

PM10 BAM instrument, ADEQ monitoring staff removed the PM10 unit from operation on July 

26, 2012. 

1.1.6 PM10 and PM2.5 Semi-Annual Flow Audit Completeness 

As mentioned above, the JLG Supersite PM10 TEOM did not receive a flow rate audit in 2012 

however due to the partial year operation and a flow rate audit performed in December of 2011, 

the data are deemed to be accurate and complete to the best of our knowledge. 

There were two other monitors in 2012 which were flagged yellow for only having 70% Flow 

Audit completeness in the AMP600 report in the PM10 Total 0-10um STP (81102) 

INTERMITTENT section. These are the Payson Well Site monitors (04-007-0008-1 and 04-

007-0008-2). They are a collocated pair of Partisol 2000 monitors and both received two flow 

rate audits in 2012, but due to scheduling conflicts they were audited outside of the 5-7 month 

report criteria. These instruments were both audited on June 28, 2012 and then again on 

November 8, 2012; technically there was not exactly 5 months between the audit dates which 

resulted in the AMP600 flagging this data. I certify that for the monitors listed in Table 1 and 

Attachments # 1 and # 2, the ambient concentration data and the quality assurance data are 

completely submitted to AQS and that the ambient data are accurate to the best of my 

knowledge, taking into consideration the quality assurance findings. 
4 

1.1.7 Lead (Pb) Performance Evaluation Program (PEP) Data 

As can be seen in the AMP600 report, the recommendation for the Lead PM10 LC FRM/FEM 

(85129) is to not certify the NCore required monitoring data. This is based solely on the 

Analysis Audit Summary having 50% completeness. The 50% completeness is due to the 

method code only being approved for the second half way of the year. The other flagged 

criterion is the NCore Lead PM10 LC FRM/FEM collocation percent complete which is not 

required at JLG Supersite. ADEQ believes these data to be accurate and complete for the second 

half of 2012 and certify these data. 

1.1.8 Freeport McMoRan PM10 Data 

As can be seen in the AMP600 report, the PM10 collocation summary data from the Miami Golf 

Course site (AQS ID 04-007-8000) shows a collocation CV of 17.04 and this statistic is flagged 

yellow. These instruments are operated by an independent contractor for Freeport McMoRan 

Miami, Inc. (1357). ADEQ became aware of some issues with the Miami Golf Course 

collocation numbers toward the end of CY2011 and into the 1st quarter of 2012. While the 

differences in the collocated values were larger than normal for this period, the calculated CV is 

representative of the precision of the PM10 data. For any data being used for regulatory 

purposes, ADEQ urges the use of these QC metrics to help determine potential error in the 

ambient concentration data. Although we do not control the integrity of these samples the 

AMP600 would recommend these data be certified with an approved QAPP on file. 

As indicated in the 2011 Network Plan, ADEQ met with Freeport-McMoRan to discuss the role 

of Primary Quality Assurance Operator for the Golf Course PM10, Townsite SO2 and Jones 

Ranch SO2 monitors that are submitted to AQS for NAAQS compliance determinations. It was 

decided that ADEQ would install instruments at these sites, perform the PQAO requirements and 

submit these data to AQS. ADEQ installed monitors at these sites in 2012. Data is being 

collected from both the FMMI and ADEQ monitors at these sites for at least one year for 

comparability analysis. 

1.2 2012 DATA FROM ADEQ PAMS MONITORS 

In 2012, ADEQ operated three sites (see Table 2 in Appendix A) for the collection of ozone, 

trace level reactive oxides of Nitrogen (NOy), volatile organic compounds (VOCs), carbonyls, 

and meteorology to comply with PAMS requirements. 

ADEQ contracts the laboratory analysis of their VOC and carbonyl samples to Eastern Research 

Group (ERG). ADEQ staff review the data and then give permission to ERG to load the data to 

AQS upon approval. 

ADEQ reports meteorology data to AQS from all three sites to support the PAMS program. 

Standard meteorology data (ambient temperature, relative humidity, wind speed and wind 

direction) are collected and reported from the JLG Supersite (AQS ID 04-013-9997) and Queen 

Valley site (AQS ID 04-021-8001) while solar radiation and ultra violet radiation data are 

collected and reported from the Vehicle Emissions Laboratory site (AQS ID 04-013-9998). 
5 

Although the annual meteorological data set is complete for JLG Supersite (AQS ID 04-013-

9997) and Vehicle Emissions Laboratory site (AQS ID 04-013-9998), there was a data logger 

issue at the Queen Valley site (AQS ID 04-021-8001). Beginning on 3/29/2012 at 15:00, the 

clock on the Campbell LoggerNet jumped to an incorrect date-time stamp. This issue was not 

corrected until 4/6/2012 at 10:00. All the associated meteorological data was invalidated and the 

result can be seen in the data completeness for the Wind Speed (61103) and Relative Humidity 

(62201) parameters in the AMP450NC. 

The AMP450NC report in Appendix B includes an annual summary of the PAMS parameters 

collected at these sites. Currently, the data from the RASS sampler (wind profiler) are not 

submitted to AQS due to the complexity of the data. 

No precision or accuracy data are required to be reported to AQS for the PAMS data. Routine 

checks and audits of the meteorological equipment are conducted and are used to validate the 

meteorological data before submitting to AQS. 

All PAMS data were carefully reviewed by our DM&QA staff with special attention to the 

quality control checks that were available. I certify that for the monitors listed in Table 2 and the 

AMP450NC report in Appendix B, the ambient concentration data and required quality 

assurance data are completely submitted to AQS and that the ambient data are accurate to the 

best of my knowledge taking into consideration the quality assurance findings. This letter does 

not certify ERG (the analyzing laboratory) operations since those are not within ADEQ’s control.

1.3 2012 DATA FROM ADEQ CSN AND NATTS MONITORS 

Table 3 in Appendix A lists the monitors that are part of the CSN and NATTS monitoring 

programs. 

1.3.1 PM2.5 Chemical Speciation Network (CSN) 

 

ADEQ participates in the CSN program with two monitors operating at the JLG Supersite (Met 

One Super SASS and URG samplers). The samples from these monitors are processed by 

Research Triangle Institute (RTI). ADEQ reviews the data results each month before RTI loads 

the data into their AQS screening group. The AMP450NC report in Appendix B includes an 

annual summary of these data. 

Monthly quality control checks, annual calibrations, and quarterly audits are performed by 

ADEQ staff on the samplers. Until recently, there was is no mechanism to report these QA data 

to RTI or to enter these data into the AQS. RTI has since developed a tool for agencies to upload 

the monthly flow verification and audit data to their website. From there, the data are loaded to 

EPA’s AQS database. For CY2012, ADEQ DM&QA staff successfully loaded all monthly flow 

verification and quarterly flow audit data to the RTI website, which was in turn loaded to the 

AQS database. This letter certifies that the monitors were operated in accordance with the EPA 

QAPP for this program and proper and regular maintenance of the monitors occurred to ensure 
6 

accurate data collection. However, this letter does not certify RTI operations since those are not 

within ADEQ’s control. 

1.3.2 National Air Toxics Trends Sites (NATTS) 

1.3.2.1 PM10 Metals Speciation 

In 2006, ADEQ began PM10 Metals Speciation monitoring at the JLG Supersite. In the past, 

filters used for PM10 NAAQS compliance were first quality assured and weighed internally for 

PM10 mass concentration and then sent to the ERG laboratory in quarterly batches for PM10

speciation analysis. This resulted in significant delays in PM10 speciation data reporting. 

Beginning July 1st, 2009, ADEQ used a continuous PM10 FEM monitor as the primary PM10

monitor for NAAQS compliance, but continued to use the filter-based PM10 monitor for PM10

speciation purposes. This allowed for a more timely analysis of PM10 speciation data by ERG 

(the analyzing laboratory). ADEQ reviews the data results before ERG reports the data into their 

AQS screening group. The AMP450NC report in Appendix B includes an annual summary of 

these data. 

Routine flow verifications, semi-annual calibrations, and semi-annual flow audits were 

performed on this monitor throughout CY 2012. These QC data had been reported to AQS in 

association with the PM10 data that had previously been reported. However, with the closure of 

the PM10 filter-based monitor in AQS, these QC data are no longer able to be reported. 

This letter certifies that the PM10 Metals Speciation monitor was operated according to ADEQ’s 

QAPP for ‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & 

Photochemical Assessment Monitoring Stations’. This letter does not certify ERG operations 

since those are not within ADEQ’s control. 

1.3.2.2 Chrome VI 

In 2006, ADEQ began collection of Chrome VI (Hexavalent Chromium) samples at the JLG 

Supersite. Sample media are provided by ERG and returned to them for analysis. ADEQ’s 

DM&QA staff reviews the data results before ERG reports the data into their AQS screening 

group. The AMP450NC report in Appendix B includes an annual summary of these data. 

Audit procedures for this monitor were developed in 2007 and implemented in the field in 2008 

and continued into CY2012. Additionally, flow checks and maintenance on the monitor were 

performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for 

‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical 

Assessment Monitoring Stations’. All Chrome VI data were carefully reviewed by our Data 

Management & QA staff with special attention to the quality control checks that were available. 

This letter certifies that the monitor was operated following standard operating procedures, and 

proper and regular maintenance of the monitor occurred to ensure accurate data collection. This 

letter does not certify ERG operations since those are not within ADEQ’s control. 

1.3.2.3 Semi-volatile Organic Compounds (SVOCs) 
7 

In July of 2007, ADEQ began collection of semi-volatile organic compounds at the JLG 

Supersite using a PUF sampler. Sample media are provided by ERG and returned to them for 

analysis. The DM&QA staff reviews the data results before ERG reports the data into their AQS 

screening group. The AMP450NC report in Appendix B includes an annual summary of these 

data. 

No precision data are reported to AQS from the PUF sampler. Audit procedures for this monitor 

were developed in 2010 and implemented in the field. Audits on the PUF sampler were 

conducted four times in 2012. Routine flow checks and maintenance on the monitor were also 

performed using the SOP developed by ADEQ in 2006 and contained in ADEQ’s QAPP for 

‘National Air Toxics Trends Stations, Air Toxics Monitoring Program, & Photochemical 

Assessment Monitoring Stations’. All SVOC data were carefully reviewed by our DM&QA staff 

with special attention to the quality control checks that were available. This letter certifies that 

the monitor was operated following standard operating procedures, and proper and regular 

maintenance of the monitor occurred to ensure accurate data collection. This letter does not 

certify ERG operations since those are not within ADEQ’s control. 

1.3.2.4 Volatile Organic Compounds (VOCs) and Carbonyls 

VOC and carbonyl data are collected at the JLG Supersite as part of the NATTS program. VOC 

data are also collected at the South Phoenix site (AQS ID 04-013-4003), which is part of the 

Urban Air Toxics Monitoring Program (UATMP). These monitors are operated by ADEQ staff 

and the samples are analyzed at ERG. The data are then reviewed by ADEQ’s DM&QA staff 

before ERG loads the data to AQS. The AMP450NC report in Appendix B includes an annual 

summary of these data. 

No precision data are reported to AQS from the VOC and Carbonyl samplers and audit 

procedures for these monitors have not yet been developed. All VOC and Carbonyl data were 

carefully reviewed by our DM&QA staff with special attention to the quality control checks that 

were available. This letter does not certify ERG operations since those are not within ADEQ’s 

control. 

Taking into consideration the exceptions mentioned in Section 1.3, I certify that for the monitors 

listed in Tables 2 and 3, and included in Appendix B, the ambient concentration data and the 

required quality assurance data are completely submitted to AQS and that the ambient data are 

accurate to the best of my knowledge, taking into consideration the quality assurance findings. 
8 

SECTION 2 

ADEQ DATA TO BE RE-CERTIFIED 

 

Table 4 in Appendix A list monitor with data reported to AQS requiring re-certification for 

CY2011. 

2.1 JLG Supersite NO2 2011 Monitoring Data 

ADEQ certified 2011 NO2 data collected from JLG Supersite in September, 2012. After learning 

of an exceedance value and further investigation, it was discovered that the data value in 

question was reported during a zero/span/precision check on the instrument. The data point was 

accidentally validated, qualified and loaded to AQS. This data has since been invalidated and I 

certify that for the monitor listed in Table 4, and included in Appendix B as the 2011 AMP600, 

the ambient concentration data and the required quality assurance data are completely submitted 

to AQS and that the ambient data are accurate to the best of my knowledge, taking into 

consideration the quality assurance findings. 
 

APPENDIX A 
Table 1. 2012 Data to be certified in AQS from ADEQ Criteria Pollutant Monitors 

X – Submitted to AQS 

 C – Collocated monitors (POCs 1 & 2) 

 CC – Collocated Continuous monitors (POCs 3 & 4) 

 N – ADEQ does not wish to certify these data due to data quality issues 

SLAMS & SPMs Criteria Pollutant Parameters 

AQS Site ID Site Name Classification 

Pb, Temp, Pres 1-in-6 

14129, 68105, 68108 

Pb, PM10 LC FRM/FEM 

 1-in6days 85129 

O3 44201 

CO 42101 

NO, NO2, NOx 

42601,42602,42603 (POC1) 

SO2 & SO2 5 Min Max 

42401 & 42406 

PM10 81102, 85101 1-in-6 

days 

PM10 81102 Hourly 

(POC 3 and/or POC 4) 

PM2.5 Hourly 88500, 88501 

(POC 3) 

PM2.5 Hourly 88101 

(POC 3) 

PM2.5, Temp, Pres. 1-in-6 

and 1-in-3 days 88101, 

68105, 68108 

04-003-0011 Paul Spur Chemical Lime Plant SLAMS X X 

04-003-1005 Douglas Red Cross SLAMS X X 

04-005-1008 Flagstaff Middle School SLAMS X X X 

04-007-0008 Payson Well Site SLAMS XC

04-007-0009 Miami Ridgeline (ADEQ) SLAMS X 

04-007-0009 Miami Ridgeline (Freeport 

McMoRan) 

SLAMS X 

04-007-0010 Tonto National Monument SLAMS X 

04-007-1001 Hayden Old Jail SLAMS X X 

04-007-8000 Miami Golf Course (Freeport 

McMoRan) 

SLAMS XC 

04-007-8000 Miami Golf Course (ADEQ) SLAMS X X 

04-007-1002 Globe Highway SLAMS XC

04-012-8000 Alamo Lake SLAMS X 

04-013-9997 JLG Supersite SLAMS / 

NCORE X X N X X XCC N X X 

04-015-1003 Bullhead City SLAMS X X 

04-019-0001 Ajo SLAMS X 

04-019-0020 Rillito SLAMS X 

04-021-8001 Queen Valley SLAMS X 

04-023-0004 Nogales Post Office SLAMS / SPM X X N N XC

04-025-2002 Prescott Valley SLAMS / SPM X X 

04-025-8033 Prescott College AQD SLAMS X 

04-027-8011 Yuma Supersite SLAMS / SPM X X X 
Table 2. 2012 Data to be certified in AQS from ADEQ PAMS Parameters 

PAMS Parameters 

Site Name AQS ID PAMS Site 

Type 

VOCs 

Carbonyls 

O3 44201 

NOY 42600 

Wind Speed 61103 

Wind Direction 61104 

Temperature 62101 

Relative Humidity 62201 

Solar Radiation 63301 

Ultraviolet Radiation 63302 

Radar Acoustic Sounding System 

(RASS, profiler) 

Phoenix – JLG 

Supersite 

04-013-9997 SLAMS 

(PAMS - 

Type 2) 

XLR XLR X X X X X X 

Queen Valley 04-021-8001 SLAMS 

(PAMS – 

Type 3) 

XLR X X X X X X 

Phoenix - 

Vehicle 

Emissions 

Laboratory 

04-013-9998 Meteorology NR NR NR NR X X NR

 X – Submitted to AQS 

 NR – Collected but not reported to AQS 

 N – ADEQ does not wish to certify these data due to data quality issues 

 LR – Laboratory reported data to AQS after review by ADEQ 

Table 3. 2012 Data to be certified in AQS from ADEQ NATTS, CSN, and UATMP 

Parameters 

Parameters 

Site Name AQS - ID Classification

PM2.5 Chemical Speciation 

Network (RTI Lab) 

PM10 Metals Speciation 

(ERG Lab) 

Chrome VI 

 (ERG Lab) 

VOCs -- Urban Air Toxics 

(ERG Lab) 

SVOCs -- Urban Air Toxics 

(ERG Lab) 

Carbonyls -- Urban Air Toxics 

(ERG Lab) 

Phoenix – JLG 

Supersite 

04-013-9997 SLAMS, 

CSN, NATTS XLR XLR XLR XLR XLR XLR 

South Phoenix 04-013-4003 SLAMS XLR 

X – Submitted to AQS 

LR – Laboratory reported data to AQS after review by ADEQ. 
Table 4. Data to be re-certified in AQS from ADEQ Monitors 

Compliance 

Parameters 

Site Name AQS ID Classification 

NO2 (42602) 

JLG 

Supersite 

04-013-9997 SLAMS / 

NCore 

X 

(recertify data 

2011) 

X – Submitted to AQS 

LR – Laboratory reported data to AQS after review by ADEQ 

 
APPENDIX B 

 
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

DATA EVALUATION AND CONCURRENCE REPORT

Report Request ID: 1096803 Report Code: AMP600 May. 9, 2013

Selection Criteria Page 1

User ID: JOJ

State County City Site Parameter POC AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

CRITERIA

AGENCY SELECTIONS

Arizona Department Of Environmental 

Quality

Freeport McMoRan Miami, Inc.

SELECTED OPTIONS

MERGE PDF FILES

Option Type Option Value

YES

GLOBAL DATES

2012

Start Date End Date

2012

Tribal

Code
May. 9, 2013 Data Evaluation and Concurrence Report Summary

Page 1 of 4

Certification Year: 2012

Certifying Agency (CA): Arizona Department Of Environmental Quality (0053)

Pollutants in Report:

PQAO

Parameter

Code

Carbon monoxide

Lead (TSP) LC

Lead PM10 LC FRM/FEM

Nitrogen dioxide (NO2)

Ozone

PM10 Total 0-10um STP

PM2.5 - Local Conditions

Sulfur dioxide

42101

14129

85129

42602

44201

81102

88101

42401

Parameter Name

Monitors

Code Evaluated

1

3

1

1

7

18

8

3

Arizona Department Of Environmental Quality 0053

PQAO Code

AQS Site-ID POC

AQS

Recommended

Flag

Cert. Agency

Recommended

Flag Reason for AQS Recommendation

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

81102

81102

85129

88101

88101

88101

88101

88101

88101

88101

1

3

1

1

1

1

3

1

2

1

04-025-2002

04-023-0004

04-013-9997

04-003-1005

04-005-1008

04-013-9997

04-013-9997

04-023-0004

04-023-0004

04-025-2002

N

N

N

N

N

N

N

N

N

N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

PQAO-Level Lead Analysis criteria not met.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

PQAO Name

Summary of 'N' flags for all pollutants:

0

3

0

0

0

0

0

0

1

0

1

1

7

18

8

3

PQAOs in Report:

04/09/12

TSA Date

Monitors Recommended for

Concurrence by AQS

Monitors NOT Recommended

for Concurrence by AQS
May. 9, 2013 Data Evaluation and Concurrence Report Summary

Page 2 of 4

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

88101

42101

42401

42401

42401

42602

44201

44201

44201

44201

44201

44201

44201

81102

81102

81102

81102

81102

81102

1

1

1

3

1

1

1

1

1

1

1

1

1

1

3

3

1

1

1

04-027-8011

04-013-9997

04-007-0009

04-007-1001

04-013-9997

04-013-9997

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

04-003-0011

04-003-0011

04-003-0011

04-003-1005

04-005-1008

04-007-0008

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

N

Y

N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Annual Summary completeness < 70%.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Monitors NOT Recommended

for Concurrence by AQS
May. 9, 2013 Data Evaluation and Concurrence Report Summary

Page 3 of 4

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

81102

81102

81102

81102

81102

81102

81102

81102

81102

81102

81102

81102

2

3

3

3

4

4

1

3

3

3

1

3

04-007-0008

04-007-1001

04-007-8000

04-013-9997

04-013-9997

04-013-9997

04-015-1003

04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-027-8011

N

N

N

N

N

N

N

N

N

N

N

N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Flow Rate Audit completeness < 65%.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Signature of Monitoring Organization Representative: ________________________________________________________

Monitors NOT Recommended

for Concurrence by AQS
May. 9, 2013 Data Evaluation and Concurrence Report Summary

Page 4 of 4

Certification Year: 2012

Certifying Agency (CA): Freeport McMoRan Miami, Inc. (1357)

Pollutants in Report:

PQAO

Parameter

Code

PM10 Total 0-10um STP 81102

Parameter Name

Monitors

Code Evaluated

3

Freeport McMoRan Miami, Inc. 1357

PQAO Code

AQS Site-ID POC

AQS

Recommended

Flag

Cert. Agency

Recommended

Flag Reason for AQS Recommendation

1357

1357

1357

81102

81102

81102

1

2

1

04-007-0009

04-007-8000

04-007-8000

N

N

N

Y

Y

Y

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Quality Assurance Project Plan not approved in 10 

years.

Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name

Summary of 'N' flags for all pollutants:

0 3

PQAOs in Report:

TSA Date

Monitors Recommended for

Concurrence by AQS

Monitors NOT Recommended

for Concurrence by AQS
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2012

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Carbon monoxide (42101) (ppm)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

04-013-9997 SLAMS 0.351 1

Mean

 0.010

Min

 2.968

Max

0

Exceed.

Count

0

Outlier

Count

82

Perc.

Comp.

 5.94

Precision

+5.58

Bias

 92

Complete

100

Complete Bias

Y

PQAO Level

Criteria

N

Aqs Rec 

Flag

N

CA Rec

Flag

N

Epa 

Concur

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

 4.68

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2012

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Nitrogen dioxide (NO2) (42602) (ppb)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

04-013-9997 SLAMS 18.0 1

Mean

 1.0

Min

 66.0

Max Exceed.

Count

0

Outlier

Count

96

Perc.

Comp.

 3.08

Precision

+/-2.55

Bias

 85

Complete

100

Complete Bias

Y

PQAO Level

Criteria

N

Aqs Rec 

Flag

Y

CA Rec

Flag

Epa 

Concur

Submitter Comment The AQS recommended flag is the result of not having

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

- 2.28

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2012

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Ozone (44201) (ppm)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

1

1

1

1

1

1

1

04-005-1008

04-007-0010

04-012-8000

04-013-9997

04-021-8001

04-025-8033

04-027-8011

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

 0.057

 0.064

 0.058

 0.054

 0.064

 0.056

 0.058

Mean

 0.037

 0.038

 0.034

 0.011

 0.038

 0.030

 0.024

Min

 0.084

 0.092

 0.080

 0.097

 0.106

 0.081

 0.100

Max

0

0

0

0

0

0

0

Exceed.

Count

0

0

0

0

0

0

0

Outlier

Count

98

99

97

95

99

98

99

Perc.

Comp.

 1.76

 1.26

 0.78

 3.41

 1.46

 0.66

 1.48

Precision

+/-1.42

+1.99

+/-0.88

+2.91

-1.56

+1.58

+/-1.17

Bias

 100

 100

 100

 88

 100

 100

 100

Complete

100

100

100

100

100

100

100

Complete

 2.04

Bias

Y

Y

Y

Y

Y

Y

Y

PQAO Level

Criteria

N

N

N

N

N

N

N

Aqs Rec 

Flag

Y

Y

Y

Y

Y

Y

Y

CA Rec

Flag

Epa 

Concur

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

Submitter Comment

Submitter Comment

Submitter Comment

Submitter Comment

Submitter Comment

Submitter Comment

Submitter Comment

Parameter

1 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

2.04082

- 3.44

- 2.96

- 3.02

 1.07

- 4.52

 0.47

- 0.39

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N

N

N

N

N

N

N
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2012

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Sulfur dioxide (42401) (ppb)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

1

3

1

04-007-0009

04-007-1001

04-013-9997

SLAMS

SLAMS

SLAMS

 4.4

 10.3

 1.3

Mean

 2.0

 0.0

 0.0

Min

 188.0

 481.0

 9.1

Max Exceed.

Count

0

0

0

Outlier

Count

98

99

99

Perc.

Comp.

 2.93

 3.67

 4.61

Precision

+4.17

+3.58

+/-3.86

Bias

 100

 96

 96

Complete

100

100

100

Complete Bias

Y

Y

Y

PQAO Level

Criteria

N

N

N

Aqs Rec 

Flag

Y

Y

Y

CA Rec

Flag

Epa 

Concur

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

The AQS recommended flag is the result of not having

Submitter Comment

Submitter Comment

Submitter Comment

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

 7.93

 2.85

- 2.43

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/06/1994

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete Bias

%

Complete

Routine Data (ug/m3) Flow Rate Verification Flow Rate Audit Collocation Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-003-0011

04-007-1001

04-007-8000

04-013-9997

04-013-9997

3

3

3

3

4

SLAMS

SLAMS

SLAMS

SLAMS

SLAMS

 26.65

 43.63

 24.41

 35.31

 33.55

-15.0

-22.0

-25.0

 2.0

-6.0

********

********

 234.0

********

********

0

0

0

0

0

62

99

99

98

99

AQS Site ID POC

+/-1.49

-2.14

-2.37

+/-0.73

+/-0.70

100

100

100

100

83

-0.48

-2.47

-1.24

-1.15

+/-

100

100

100

100

0

N

N

N

N

N

Y

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place and no flow rate audit in 2012. 

ADEQ is working to produce QAPPs according to the 

schedule given in our TSA response dated 3/29/2013. 

There was no audit of the instrument in 

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) CONTINUOUS

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/06/1994

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete Bias

%

Complete

Routine Data (ug/m3) Flow Rate Verification Flow Rate Audit Collocation Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-015-1003

04-019-0001

04-019-0020

04-023-0004

04-027-8011

3

3

3

3

3

SLAMS

SLAMS

SLAMS

SPECIAL 

PURPOSE

SLAMS

 21.79

 34.41

 42.94

 48.09

 43.68

-22.0

-38.0

-11.0

 2.0

-37.0

 893.0

********

********

 793.0

********

0

0

0

0

0

98

97

98

92

99

AQS Site ID POC

+/-1.27

+/-0.98

+/-0.75

+/-0.84

+/-2.08

100

100

100

100

100

-0.42

-0.44

+1.11

-1.01

-1.48

100

100

100

100

100

N

N

N

N

N

Y

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/06/1994

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Met?

7 1 1 100 5.49 6.25 Y

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-003-0011

04-003-1005

04-005-1008

04-007-0008

1

1

1

1

SLAMS

SLAMS

SLAMS

SLAMS

 19.17

 31.16

 17.32

 20.43

 4.0

 5.0

 2.0

 6.0

 37.0

 71.0

 38.0

 44.0

0

0

0

0

0

0

0

0

100

91

96

98

AQS Site ID POC

-0.90

-0.88

-1.83

-0.92

100

100

100

70 100 6.25

Y

Y

Y

Y

N

N

N

N

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) INTERMITTENT

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 08/06/1994

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Met?

7 1 1 100 5.49 6.25 Y

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-007-0008

04-015-1003

04-023-0004

04-025-2002

2

1

1

1

QA 

COLLOCA

TED

SLAMS

SLAMS

SLAMS

 20.50

 18.30

 36.67

 12.53

 6.0

 4.0

 7.0

 4.0

 41.0

 35.0

 102.0

 39.0

0

0

0

0

0

0

0

0

100

100

95

95

AQS Site ID POC

-1.15

-0.65

-1.83

-1.04

70

100

100

100

Y

Y

Y

Y

N

N

N

N

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Arizona Department Of Environmental Quality (0053)

Certifying Year:

Certifying Agency:

PM2.5 - Local Conditions (88101) 

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 12/09/1998

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Method Met?

143 6 1 1 100 5.99 6.89 Y

PEP Summary

#

Methods

# Audited

Methods

# PEP

Required

# PEP

Submitted

%

Complete Bias

Criteria

Met?

1 1 8 5 62.5 -15.06 Y

Monitors Summaries

Method

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

PEP

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-003-1005

04-005-1008

04-013-9997

04-013-9997

1

1

1

3

143

143

143

170

SLAMS

SLAMS

SLAMS

SLAMS

 6.72

 5.40

 9.23

 7.91

 2.0

 1.2

 2.3

-5.0

 13.1

 14.1

 52.0

 537.0

0

0

0

0

100

98

99

98

AQS Site ID POC

-0.30

-1.24

-1.30

-1.02

100

100

100

100

Y

Y

Y

Y

Y

Y

Y

Y

N

N

N

N

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

2012

Arizona Department Of Environmental Quality (0053)

Freeport McMoRan Miami, Inc. (1357)

Certifying Year:

Certifying Year:

Certifying Agency:

Certifying Agency:

PM2.5 - Local Conditions (88101) 

Arizona Department Of Environmental Quality (0053)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date: 12/09/1998

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Method Met?

143 6 1 1 100 5.99 6.89 Y

PEP Summary

#

Methods

# Audited

Methods

# PEP

Required

# PEP

Submitted

%

Complete Bias

Criteria

Met?

1 1 8 5 62.5 -15.06 Y

Monitors Summaries

Method

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

PEP

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-023-0004

04-023-0004

04-025-2002

04-027-8011

1

2

1

1

143

143

143

143

SLAMS

QA 

COLLOCA

TED

SLAMS

SLAMS

 9.39

 9.30

 4.47

 8.46

 2.9

 3.9

 1.7

 2.9

 29.0

 26.7

 14.0

 17.0

0

0

0

0

95

85

96

93

AQS Site ID POC

-2.23

-1.62

-0.09

-2.24

100

100

100

100

 6.89 100 Y

Y

Y

Y

Y

Y

Y

Y

N

N

N

N

Y

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N

N
Data Evaluation and Concurrence Report for Particulate Matter

2012

Freeport McMoRan Miami, Inc. (1357)

Certifying Year:

Certifying Agency:

PM10 Total 0-10um STP (81102) INTERMITTENT

Freeport McMoRan Miami, Inc. (1357)

Parameter:

PQAO Name:

Quality Assurance Project Plan Approval Date:

Collocation Summary

# Sites

# Sites 

Req

# Sites 

Collocated

%

Collocated

CV

Est CV UB

Criteria

Met?

2 1 1 100 14.92 17.04 Y

Monitors Summaries

Monitor

Type Mean Min Max

Exceed.

Count

Outlier

Count

%

Complete Bias

%

Complete

Flow Rate Audit Collocation

%

CV Complete

PQAO

Crit. Met

Routine Data (ug/m3) Concurrence Flag

AQS Rec

Flag

CA Rec

Flag

EPA

Concur

04-007-0009

04-007-8000

04-007-8000

1

1

2

INDUSTRI

AL

INDUSTRI

AL

INDUSTRI

AL

 15.79

 18.19

 18.71

 2.0

 4.0

 6.0

 53.0

 45.0

 36.0

0

0

0

0

0

0

100

96

95

AQS Site ID POC

-0.61

-1.90

-1.46

100

100

100

 17.04 100

Y

Y

Y

N

N

N

Y

Y

Y

Submitter Comment:

Submitter Comment:

Submitter Comment:

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

The AQS recommended flag is the result of not having an 

approved QAPP in place. ADEQ is working to produce 

QAPPs according to the schedule given in our TSA 

response dated 3/29/2013.

EPA Comment:

EPA Comment:

EPA Comment:

QAPP

Appr.

N

N

N
Data Concurrence and Evaluation Report for Lead

Certification Year 2012

Certifying Agency Name: Arizona Department Of Environmental Quality (0053)

Lead (TSP) LC (14129)

Lead PM10 LC FRM/FEM (85129)

Arizona Department Of Environmental Quality (0053)

Arizona Department Of Environmental Quality (0053)

PQAO Name:

PQAO Name:

Y

N

Criteria

Met

Criteria

Met

+5.21

-9.44

Bias

Bias

 83

 50

Percent

Complete

Percent

Complete

20

12

Number

Submitted

Number

Submitted

24

24

Number

Required

Number

Required

Y

Criteria

Met

Criteria

Met

Bias

Bias

 0

 0

Percent

Complete

Percent

Complete

0

0

Number of 

Audits

Submitted

Number of 

Audits

Submitted

1

1

Number of 

PEP Audits 

Required

Number of 

PEP Audits 

Required

0

0

Number of 

Methods 

Audited

Number of 

Methods 

Audited

1

1

Number of

Methods

Number of

Methods

Y

Criteria

Met

Criteria

Met

 4.66

 9.72

CV UB

CV UB

 4.01

 3.16

CV

Est

CV

Est

 100

 100

Percent

Collocated

Percent

Collocated

1

1

Number of 

Actual

Colloc Sites

Number of 

Actual

Colloc Sites

1

1

Number of 

Colloc Sites 

Required

Number of 

Colloc Sites 

Required

2

1

Number 

of Sites

Number 

of Sites

Collocation Summary:

Collocation Summary:

01/22/2013

01/22/2013

Quality Assurance Project Plan Approval Date:

Quality Assurance Project Plan Approval Date:

Analysis Audit Summary:

Analysis Audit Summary:

PEP Summary

PEP Summary

AQS Site-ID

AQS Site-ID

POC

POC

Monitor

Type

Monitor

Type

Mean

Mean

Min

Min

Max

Max

Exceed.

Count

Exceed.

Count

Outlier

Count

Outlier

Count

Percent

Comp.

Percent

Comp.

Bias

Bias

Percent

Comp.

Percent

Comp.

CV UB

CV UB

Percent

Comp.

Percent

Comp.

PQAO

Crit. Met

PQAO

Crit. Met

PQAO

Crit. Met

PQAO

Crit. Met

Analysis

Crit. Met

Analysis

Crit. Met

AQS 

Rec. V

AQS 

Rec. V

CA Rec

Value

CA Rec

Value

EPA

Concur

EPA

Concur

Monitors Recommended for Certification

Routine Data (ug/m^3)

Routine Data (ug/m^3)

Flow Rate Audit

Flow Rate Audit

Collocation

Collocation

PEP

PEP

Lead

Lead

Certification

Certification

04-007-1002

04-007-1002

04-007-8000

04-013-9997

1

2

1

1

SLAMS

SLAMS

SLAMS

NATTS

 0.130

 0.126

 0.025

 0.0040

 0.006

 0.003

 0.004

 0.0012

 0.624

 0.648

 0.151

 0.0114

1

2

0

0

0

0

0

0

 98

 91

 100

 100

-2.37

+0.02

-0.78

-0.95

 100

 100

 100

 100

 4.66

 9.72

 100

 20

Y

Y

Y

Y

Y

Y

Y

Y

Y

N

Y

Y

Y

N

Y

Y

Y

Y

Submitter Comment: The AQS recommended flag is the result of partial year FEM method code EPA Comment:

designation. The analysis audit summary information is complete for a 6 month 

period (12 submitted audits). This flag is erroneous. Further, this monitor does 

not require collocatio

Monitors Not Recommended for Certification

QAPP

Appr.

QAPP

Appr.

Y

Y

Y

Y
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

QUICKLOOK ALL PARAMETERS

Report Request ID: 1099159 Report Code: AMP450NC May. 16, 2013

Selection Criteria Page 1

User ID: JOJ

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

ALL

AGENCY SELECTIONS

Arizona Department Of Environmental 

Quality

SELECTED OPTIONS

MERGE PDF FILES

EVENTS PROCESSING

Option Type Option Value

YES

EXCLUDE REGIONALLY CONCURRED EVENTS

SORT ORDER

1

2

3

4

5

6

7

Order Column

STATE_CODE

COUNTY_CODE

SITE_ID

PARAMETER_CODE

POC

DATES

EDT_ID

GLOBAL DATES

2012

Start Date End Date

2012

APPLICABLE STANDARDS

Standard Description

CO 8-hour 1971

Lead 3-Month 2009

Lead 3-Month PM10 Surrogate 2009

Lead Quarterly 1978

NO2 Annual 1971

Ozone 8-Hour 2008

PM10 24-hour 2006

PM25 24-hour 2006

SO2 1-hour 2010
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES

EDT DESCRIPTION

0

1

2

5

NO EVENTS

EVENTS EXCLUDED

EVENTS INCLUDED

EVENTS WITH CONCURRENCE EXCLUDED
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 2 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

3

3

1

2

1

1

1

1

1

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 30

 5456

 225

 30

 2

 61

 61

 56

 56

 61

 5424

 60

 60

 59

 59

 60

37

1160

194

31

15

31.9

666

71

61

13.1

.075

23.0

598

38

30

14.1

36

1038

94

30

9

30.4

664

58

52

12.1

.073

22.7

597

35

29

11.9

34

804

66

29

29.1

663

55

47

11.4

.073

22.1

596

33

27

11.9

28

503

60

25

28.9

663

52

47

11.1

.072

20.5

596

32

26

11.2

19.2*

26.6*

26.2*

16.8*

12.0*

19.00 

659.2 

31.2*

27.5*

6.72 

.0531 

9.69 

591.9 

17.3 

14.1 

5.40 

24 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

81102

81102

81102

85101

85101

68105

68108

81102

85101

88101

44201

68105

68108

81102

85101

88101

Parameter

Site ID:

Site ID:

Site ID:

04-003-0011

04-003-1005

04-005-1008

Paul Spur

Douglas

Flagstaff

City:

City:

City:

Cochise

Cochise

Coconino

Unit

County:

County:

County:

HOUSING AREA, PAUL SPUR

1445-1449 15TH STREET

755 W BONITO

Address:

Address:

Address:

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM10 - LC

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

Ozone

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per million

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

126

079

079

126

126

143

143

126

126

143

087

143

143

126

126

143

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 3 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

2

1

2

1

1

1

3

3

3

3

1

2

1

2

1

2

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 60

 62

 60

 62

 8615

 8605

 5863

 8737

 8712

 8709

 364

 60

 56

 61

 60

 61

 60

44

41

38

36

188.0

421.7

.080

481.0

1350.2

3954

250

.624

.648

37.3

35.2

716

716

40

41

33

34

134.0

266.0

.079

407.0

1114.1

1141

137

.472

.489

36.5

34.5

714

714

37

37

33

33

124.0

257.7

.079

392.0

1072.4

1062

125

.364

.363

36.1

34.3

712

712

36

36

32

32

102.0

257.3

.078

353.0

1032.5

1019

105

.363

.347

35.7

34.0

712

712

20.4 

20.5 

17.7 

17.8 

19.35 

7.68 

.0587 

72.78 

27.75 

43.6 

43.1 

.1304 

.1257 

23.41 

22.45 

708.0 

707.7 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

1 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

1 HOUR

1 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

81102

81102

85101

85101

42401

42406

44201

42401

42406

81102

81102

14129

14129

68105

68105

68108

68108

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

04-007-0008

04-007-0009

04-007-0010

04-007-1001

04-007-1002

Payson

Miami

Tonto National Monument

Hayden

Not in a city

City:

City:

City:

City:

City:

Gila

Gila

Gila

Gila

Gila

Unit

County:

County:

County:

County:

County:

204 W AERO DR

4030 LINDEN STREET

SOUTH OF SR88

JAIL-CANYON DR, HAYDEN

SR 77

Address:

Address:

Address:

Address:

Address:

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM10 - LC

Sulfur dioxide

SO2 max 5-min avg

Ozone

Sulfur dioxide

SO2 max 5-min avg

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Lead (TSP) LC

Lead (TSP) LC

Ambient Temperature

Ambient Temperature

Sample Baro Pressure

Sample Baro Pressure

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per billion

Parts per billion

Parts per million

Parts per billion

Parts per billion

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Millimeters (mercury)

Meth

126

126

126

126

060

060

087

060

060

079

079

191

191

780

780

780

780

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 4 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

3

3

1

6

6

6

6

6

6

6

6

6

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 61

 61

 61

 3791

 158

 5752

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

.151

32.1

684

234

52

.075

.06

6.75

6.08

.04

1.33

1.26

.05

.05

.03

.00

.097

32.0

681

199

52

.075

.03

6.54

5.74

.04

1.15

1.18

.00

.05

.03

.00

.070

30.8

681

143

49

.075

.03

5.79

5.54

.04

1.14

1.17

.00

.05

.03

.00

.064

30.6

681

140

44

.075

.03

5.55

5.52

.03

1.02

1.09

.00

.05

.03

.00

.0254 

19.01 

675.9 

24.4*

23.9*

.0542 

.017 

2.672 

2.649 

.031 

.465 

.599 

.002 

.048 

.033 

.000 

24 HOUR

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

14129

68105

68108

81102

81102

44201

42153

43205

43206

43208

43218

43233

43372

43373

43396

43438

Parameter

Site ID:

Site ID:

Site ID:

04-007-8000

04-012-8000

04-013-4003

Globe

Wenden

Phoenix

City:

City:

City:

Gila

La Paz

Maricopa

Unit

County:

County:

County:

SR 188 & US 60

ALAMO LAKE STATE PARK

33 W TAMARISK AVE, PHOENIX

Address:

Address:

Address:

Lead (TSP) LC

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Ozone

Carbon disulfide

Propylene

Acetylene

Freon 114

1,3-Butadiene

n-Octane

Methyl tert-butyl ether

Tert-amyl methyl ether

tert-Butyl ethyl ether

Ethyl acrylate

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

191

780

780

079

079

087

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 5 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

.61

3.33

.54

.71

.00

.78

.32

.06

.13

.01

.38

.00

.00

.02

.06

.35

.00

.54

3.21

.49

.59

.00

.76

.27

.06

.13

.01

.32

.00

.00

.02

.06

.15

.00

.18

2.21

.47

.59

.00

.71

.21

.06

.13

.00

.31

.00

.00

.02

.05

.15

.00

.18

2.19

.46

.56

.00

.70

.20

.06

.12

.00

.30

.00

.00

.02

.05

.14

.00

.061 

1.251 

.268 

.360 

.000 

.614 

.128 

.034 

.103 

.001 

.274 

.000 

.000 

.010 

.037 

.066 

.000 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43441

43505

43560

43702

43704

43801

43802

43803

43804

43806

43811

43812

43813

43814

43815

43817

43818

Parameter

Site ID: 04-013-4003 City: Phoenix Maricopa

Unit

County: Address: 33 W TAMARISK AVE, PHOENIX

Methyl methacrylate

Acrolein - Unverified

Methyl isobutyl ketone

Acetonitrile

Acrylonitrile

Chloromethane

Dichloromethane

Chloroform

Carbon tetrachloride

Bromoform

Trichlorofluoromethane

Chloroethane

1,1-Dichloroethane

Methyl chloroform

Ethylene dichloride

Tetrachloroethylene

1,1,2,2-Tetrachloroethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 6 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

.02

.00

.21

.59

.04

0

.01

.00

.00

.05

.01

.06

.01

.01

.02

.00

.00

.02

.00

.19

.57

.03

0

.01

.00

.00

.00

.01

.00

.01

.01

.02

.00

.00

.01

.00

.18

.57

.03

0

.01

.00

.00

.00

.01

.00

.01

.01

.02

.00

.00

.01

.00

.18

.56

.03

0

.01

.00

.00

.00

.01

.00

.01

.01

.02

.00

.00

.009 

.000 

.161 

.508 

.009 

.0 

.011 

.000 

.000 

.002 

.009 

.002 

.007 

.012 

.018 

.000 

.000 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43819

43820

43821

43823

43824

43826

43828

43829

43830

43831

43832

43835

43836

43838

43839

43843

43844

Parameter

Site ID: 04-013-4003 City: Phoenix Maricopa

Unit

County: Address: 33 W TAMARISK AVE, PHOENIX

Bromomethane

1,1,2-Trichloroethane

1,1,2-Trichloro-1,2,2-

trifluoroethane

Dichlorodifluoromethane

Trichloroethylene

1,1-Dichloroethylene

Bromodichloromethane

1,2-Dichloropropane

trans-1,3-Dichloropropene

cis-1,3-Dichloropropene

Dibromochloromethane

Chloroprene

Bromochloromethane

trans-1,2-Dichloroethylene

cis-1,2-Dichloroethene

Ethylene dibromide

Hexachlorobutadiene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 7 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

6

6

6

6

6

6

6

6

6

6

6

6

6

6

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 30

 61

 6

.00

10.00

6.36

22.68

3.46

4.15

1.31

4.24

1.27

.08

.06

.07

.64

.12

.00

.00

.00

9.28

5.39

19.95

3.35

3.59

1.13

3.62

.77

.00

.06

.07

.61

.10

.00

.00

.00

9.04

5.17

18.55

2.96

3.58

.92

2.99

.74

.00

.06

.07

.58

.03

.00

.00

.00

8.64

5.12

17.71

2.93

3.50

.91

2.98

.66

.00

.06

.07

.51

.00

.00

.00

.000 

4.302 

2.700 

9.179 

1.551 

1.727 

.489 

1.592 

.393 

.003 

.063 

.072 

.259 

.008 

.000 

.000*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43860

45109

45201

45202

45203

45204

45207

45208

45220

45801

45805

45806

45807

45810

12115

12115

Parameter

Site ID:

Site ID:

04-013-4003

04-013-9997

Phoenix

Phoenix

City:

City:

Maricopa

Maricopa

Unit

County:

County:

33 W TAMARISK AVE, PHOENIX

4530 N 17TH AVENUE

Address:

Address:

Vinyl chloride

m/p Xylene

Benzene

Toluene

Ethylbenzene

o-Xylene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

Styrene

Chlorobenzene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

1,2,4-Trichlorobenzene

Chromium VI (TSP) STP

Chromium VI (TSP) STP

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

920

920

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 8 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

3

3

3

3

3

3

3

3

3

3

3

3

3

3

3

3

3

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

 59

343.000

4.2100

7.0300

5.7600

10.700

1.5500

29.6000

3.0700

.296

2.7500

2.9300

2.9400

.317

.8530

2.670

5.930

2.060

264.000

3.9300

5.3700

5.3600

10.500

1.1900

6.6900

3.0400

.205

2.6100

2.0000

.9390

.315

.1800

.856

1.520

.431

249.000

3.5900

4.2900

4.5000

10.400

.9030

5.3400

2.8800

.142

2.4600

1.8600

.9100

.281

.1780

.816

1.140

.372

243.000

3.5100

4.0200

4.4800

10.400

.7940

3.1200

2.8400

.118

2.2100

1.8300

.7810

.191

.1350

.587

1.120

.340

97.8371 

2.14456 

1.01181 

3.05254 

6.2554 

.32959 

1.17716 

1.49234 

.0209 

1.20875 

.76086 

.21464 

.0596 

.03195 

.1380 

.3129 

.0826 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

17141

17147

17148

17149

17150

17151

17158

17159

17160

17201

17204

17208

17211

17212

17215

17220

17223

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Naphthalene (TSP) STP

Acenaphthene (TSP) STP

Acenaphthylene (TSP) STP

Fluorene (TSP) STP

Phenanthrene (TSP) STP

Anthracene (TSP) STP

Retene (TSP) STP

9-fluorenone (TSP) STP

Cyclopenta[cd]pyrene (TSP) STP

Fluoranthene (TSP) STP

Pyrene (TSP) STP

Chrysene (TSP) STP

Coronene (TSP) STP

Perylene (TSP) STP

Benzo[a]anthracene (TSP) STP

Benzo[b]fluoranthene (TSP) STP

Benzo[k]fluoranthene (TSP) STP

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Meth

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 9 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

3

3

3

3

3

1

6

7

1

1

1

1

1

1

8

9

8

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 59

 59

 59

 59

 59

 7185

 61

 6

 8732

 7914

 7437

 8408

 8408

 8408

 16

 1

 7

 16

 1

 16

2.810

.396

1.940

3.600

2.3600

1.8

.08

.05

9.1

9.6

216.1

266.0

66.0

318.0

169.00

179.00

4.07

.19

.19

.19

.708

.122

.811

.854

.8170

1.7

.08

.05

7.2

9.5

216.0

253.0

64.0

304.0

164.00

.08

.19

.19

.554

.106

.505

.676

.5650

1.7

.08

.04

6.8

9.3

216.0

250.0

63.0

296.0

157.00

.08

.19

.19

.514

.100

.479

.670

.5300

1.6

.07

.04

6.1

8.4

214.9

230.0

62.0

267.0

156.00

.08

.19

.19

.1564 

.0201 

.1685 

.1665 

.15572 

.35 

.030 

.043*

2.33 

1.56 

34.29 

15.82 

18.05 

33.77 

121.213*

179.000*

.652*

.192*

.192*

.192*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG END 

HOUR

24 HOUR

24 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

17224

17231

17237

17242

17243

42101

42153

42153

42401

42406

42600

42601

42602

42603

43102

43102

43127

43141

43141

43142

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Benzo[e]pyrene (TSP) STP

Dibenzo[a,h]anthracene (TSP) STP

Benzo[g,h,i]perylene (TSP) STP

Benzo[a]pyrene (TSP) STP

Indeno[1,2,3-cd]pyrene (TSP) STP

Carbon monoxide

Carbon disulfide

Carbon disulfide

Sulfur dioxide

SO2 max 5-min avg

Reactive oxides of nitrogen (NOy)

Nitric oxide (NO)

Nitrogen dioxide (NO2)

Oxides of nitrogen (NOx)

Total NMOC (non-methane organic 

compound)

Total NMOC (non-methane organic 

compound)

Isobutene & 1-butene

n-Dodecane

n-Dodecane

Tridecene

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

118

118

118

118

118

588

101

101

592

592

591

074

074

074

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 10 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

6

7

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 61

 6

 16

 1

.19

.19

.19

.09

.09

.11

.11

6.01

3.52

4.40

4.22

10.50

3.93

7.08

2.77

1.52

1.04

.19

.09

.11

5.35

3.97

5.90

6.54

2.35

1.26

.19

.09

.11

5.26

3.57

4.64

6.51

2.26

1.18

.19

.09

.11

5.16

3.55

4.56

5.70

1.91

1.15

.192*

.192*

.192*

.092*

.092*

.106*

.106*

3.610*

3.520*

2.768*

4.220*

3.969*

3.930*

2.349 

1.935*

1.028*

1.040*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43142

43143

43143

43144

43144

43145

43145

43202

43202

43203

43203

43204

43204

43205

43205

43205

43205

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Tridecene

n-Tridecane

n-Tridecane

Propyne

Propyne

1-Octene

1-Octene

Ethane

Ethane

Ethylene

Ethylene

Propane

Propane

Propylene

Propylene

Propylene

Propylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

101

101

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 11 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

8

9

6

7

8

9

8

9

8

9

8

9

6

7

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 61

 6

 16

 1

 61

 6

 16

 1

 16

 1

 16

 1

 16

 1

 61

 6

 16

7.76

3.20

1.65

.89

.05

.04

3.25

2.09

1.72

1.13

.25

.07

.22

.10

1.27

.51

.69

5.92

2.48

1.42

.04

.04

3.03

1.57

.22

.22

1.26

.40

.58

5.72

2.04

1.04

.04

.03

2.52

1.26

.22

.21

1.21

.37

.55

5.50

1.77

1.03

.04

.03

2.27

1.24

.22

.10

1.09

.29

.47

2.270 

1.931*

.861*

.888*

.033 

.034*

1.959*

2.090*

1.008*

1.130*

.148*

.073*

.122*

.100*

.400 

.306*

.262*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43206

43206

43206

43206

43208

43208

43212

43212

43214

43214

43216

43216

43217

43217

43218

43218

43218

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Acetylene

Acetylene

Acetylene

Acetylene

Freon 114

Freon 114

n-Butane

n-Butane

Isobutane

Isobutane

trans-2-Butene

trans-2-Butene

cis-2-Butene

cis-2-Butene

1,3-Butadiene

1,3-Butadiene

1,3-Butadiene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

126

126

101

101

126

126

126

126

126

126

126

126

101

101

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 12 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 16

 1

 9

 16

 1

 16

 1

 16

 1

 16

 1

 14

 1

 16

 1

 16

.23

7.59

2.53

11.90

.66

.32

.53

.32

.58

.32

.28

.11

.79

.50

1.84

1.18

1.92

4.65

10.20

.58

.37

.35

.11

.49

1.62

1.69

4.28

8.99

.51

.33

.33

.11

.46

1.20

1.43

2.54

4.40

.50

.31

.28

.11

.43

1.18

1.24

.230*

2.619*

2.530*

5.628*

.305*

.316*

.233*

.320*

.245*

.321*

.118*

.108*

.361*

.500*

1.017*

1.180*

1.088*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43218

43220

43220

43221

43224

43224

43225

43225

43226

43226

43227

43227

43228

43228

43230

43230

43231

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1,3-Butadiene

n-Pentane

n-Pentane

Isopentane

1-Pentene

1-Pentene

2-Methyl-1-butene

2-Methyl-1-butene

trans-2-Pentene

trans-2-Pentene

cis-2-Pentene

cis-2-Pentene

2-Methyl-2-butene

2-Methyl-2-butene

3-Methylpentane

3-Methylpentane

n-Hexane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 13 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

6

7

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 16

 1

 61

 6

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

1.27

.96

.60

1.32

.75

.47

.44

.17

.17

.29

.26

.17

.17

.33

.32

.54

.34

.77

1.28

.73

.46

.17

.27

.17

.33

.46

.74

1.25

.66

.43

.17

.25

.17

.32

.37

.70

1.23

.54

.41

.17

.24

.17

.32

.36

1.270*

.554*

.602*

.550 

.582*

.328*

.442*

.171*

.171*

.190*

.258*

.171*

.171*

.224*

.321*

.318*

.339*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43231

43232

43232

43233

43233

43233

43233

43234

43234

43235

43235

43236

43236

43238

43238

43242

43242

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

n-Hexane

n-Heptane

n-Heptane

n-Octane

n-Octane

n-Octane

n-Octane

4-Methyl-1-pentene

4-Methyl-1-pentene

n-Nonane

n-Nonane

2-Ethyl-1-butene

2-Ethyl-1-butene

n-Decane

n-Decane

Cyclopentane

Cyclopentane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

101

101

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 14 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

2.85

2.04

.50

.39

.17

.17

.17

.17

.87

.54

1.22

.83

1.50

.89

2.44

1.38

.98

2.50

.43

.17

.17

.69

.99

1.20

2.08

.94

2.48

.40

.17

.17

.53

.87

1.15

1.74

.74

2.08

.36

.17

.17

.53

.79

1.10

1.42

.74

1.761*

2.040*

.275*

.392*

.171*

.171*

.171*

.171*

.474*

.541*

.687*

.830*

.909*

.889*

1.319*

1.380*

.559*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43243

43243

43244

43244

43245

43245

43246

43246

43247

43247

43248

43248

43249

43249

43250

43250

43252

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Isoprene

Isoprene

2,2-Dimethylbutane

2,2-Dimethylbutane

1-Hexene

1-Hexene

2-Methyl-1-pentene

2-Methyl-1-pentene

2,4-Dimethylpentane

2,4-Dimethylpentane

Cyclohexane

Cyclohexane

3-Methylhexane

3-Methylhexane

2,2,4-Trimethylpentane

2,2,4-Trimethylpentane

2,3,4-Trimethylpentane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 15 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 16

 1

 16

 1

 15

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

.59

.37

.27

.73

.59

.45

.11

1.08

.56

1.73

1.23

2.11

1.11

.09

.09

.13

.13

.35

.44

.43

.66

1.49

1.50

.09

.13

.30

.37

.11

.64

1.25

1.45

.09

.13

.26

.36

.11

.62

1.18

1.45

.09

.13

.588*

.214*

.270*

.231*

.589*

.152*

.108*

.528*

.561*

.968*

1.230*

1.098*

1.110*

.094*

.094*

.130*

.130*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43252

43253

43253

43256

43256

43257

43257

43261

43261

43262

43262

43263

43263

43279

43279

43282

43282

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

2,3,4-Trimethylpentane

3-Methylheptane

3-Methylheptane

alpha.-Pinene

alpha.-Pinene

beta.-Pinene

beta.-Pinene

Methylcyclohexane

Methylcyclohexane

Methylcyclopentane

Methylcyclopentane

2-Methylhexane

2-Methylhexane

1-Nonene

1-Nonene

3-Methyl-1-butene

3-Methyl-1-butene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 16 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

 1

 16

.13

.13

1.13

.72

3.18

2.12

.17

.17

.17

.17

1.63

.96

.46

.27

.11

.11

.12

.13

.93

2.84

.17

.17

1.28

.42

.11

.12

.13

.74

2.13

.17

.17

1.07

.36

.11

.12

.13

.70

1.92

.17

.17

1.01

.32

.11

.12

.130*

.130*

.622*

.724*

1.793*

2.120*

.171*

.171*

.171*

.171*

.909*

.958*

.208*

.267*

.108*

.108*

.119*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43283

43283

43284

43284

43285

43285

43289

43289

43290

43290

43291

43291

43292

43292

43298

43298

43299

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Cyclopentene

Cyclopentene

2,3-Dimethylbutane

2,3-Dimethylbutane

2-Methylpentane

2-Methylpentane

trans-2-Hexene

trans-2-Hexene

cis-2-Hexene

cis-2-Hexene

2,3-Dimethylpentane

2,3-Dimethylpentane

2-2-3-Trimethylpentane

2-2-3-Trimethylpentane

1-Decene

1-Decene

1-Undecene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 17 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

6

7

6

7

6

7

6

7

6

7

30

31

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 16

 1

 16

 1

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

.12

.11

.11

1.00

.19

.00

.13

.05

.05

.03

.09

.12

.00

.22

.10

4.9

4.1

.11

.49

.00

.00

.05

.05

.03

.03

.00

.00

.19

.00

4.7

4.0

.11

.48

.00

.00

.05

.05

.03

.03

.00

.00

.17

.00

4.7

3.5

.11

.19

.00

.00

.05

.05

.03

.03

.00

.00

.16

.00

4.5

3.2

.119*

.113*

.113*

.278*

.192*

.000 

.022*

.048 

.048*

.033 

.043*

.002 

.000*

.020 

.017*

3.23 

3.28*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43299

43328

43328

43330

43330

43372

43372

43373

43373

43396

43396

43438

43438

43441

43441

43502

43502

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1-Undecene

1-Heptene

1-Heptene

Dodecene

Dodecene

Methyl tert-butyl ether

Methyl tert-butyl ether

Tert-amyl methyl ether

Tert-amyl methyl ether

tert-Butyl ethyl ether

tert-Butyl ethyl ether

Ethyl acrylate

Ethyl acrylate

Methyl methacrylate

Methyl methacrylate

Formaldehyde

Formaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

101

101

101

101

101

101

101

101

101

101

202

202

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 18 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

32

30

31

32

30

31

32

6

7

30

31

32

30

31

32

30

31

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 48

 61

 6

 48

 61

 6

 48

 61

 6

 61

 6

 48

 61

 6

 48

 61

 6

10.2

6.2

4.0

7.6

1.1

.9

1.7

6.42

1.94

1.268

.980

1.552

.0

.0

.0

.7

.6

5.6

6.1

3.7

7.6

1.1

.8

1.2

5.97

1.72

1.196

.836

1.448

.0

.0

.0

.7

.4

5.5

5.8

3.5

4.7

1.1

.7

1.0

4.35

1.44

1.172

.704

1.076

.0

.0

.0

.7

.4

5.5

5.5

3.1

4.7

1.1

.7

1.0

2.61

1.36

1.144

.660

.960

.0

.0

.0

.6

.3

3.49*

3.21 

3.16*

2.73*

.64 

.68*

.57*

1.575 

1.398*

.6496 

.7093*

.5488*

.01 

.01*

.03*

.35 

.37*

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43502

43503

43503

43503

43504

43504

43504

43505

43505

43510

43510

43510

43513

43513

43513

43517

43517

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Formaldehyde

Acetaldehyde

Acetaldehyde

Acetaldehyde

Propionaldehyde

Propionaldehyde

Propionaldehyde

Acrolein - Unverified

Acrolein - Unverified

Butyraldehyde

Butyraldehyde

Butyraldehyde

Isovaleraldehyde

Isovaleraldehyde

Isovaleraldehyde

Hexanaldehyde

Hexanaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

101

101

202

202

202

202

202

202

202

202

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 19 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

32

30

31

32

30

31

32

30

31

32

30

31

32

6

7

6

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 47

 61

 6

 47

 61

 6

 48

 61

 6

 48

 61

 6

 43

 61

 6

 61

 6

1.2

.6

.4

.7

.8

.7

1.6

21.8

14.1

22.7

2.8

1.4

2.9

.75

.43

2.28

.81

1.0

.5

.3

.5

.8

.6

1.2

21.2

13.5

19.1

2.2

1.2

2.0

.72

.40

.66

.62

.6

.5

.3

.4

.8

.5

1.2

19.7

12.5

16.6

2.2

1.2

1.9

.61

.34

.64

.55

.5

.5

.3

.4

.7

.3

1.1

18.5

11.0

16.4

2.1

1.2

1.7

.60

.29

.56

.53

.27*

.26 

.29*

.16*

.38 

.42*

.68*

9.92 

10.27*

11.26*

1.07 

1.06*

.97*

.328 

.300*

.403 

.538*

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43517

43518

43518

43518

43528

43528

43528

43551

43551

43551

43552

43552

43552

43560

43560

43702

43702

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Hexanaldehyde

Valeraldehyde

Valeraldehyde

Valeraldehyde

Crotonaldehyde

Crotonaldehyde

Crotonaldehyde

Acetone

Acetone

Acetone

Methyl ethyl ketone

Methyl ethyl ketone

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl isobutyl ketone

Acetonitrile

Acetonitrile

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 20 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

.77

.15

1.05

.72

6.68

.72

.15

.11

.14

.12

.01

.01

.34

.33

.29

.16

.00

.00

.00

.84

.70

3.27

.26

.14

.11

.14

.11

.01

.00

.34

.30

.19

.00

.00

.00

.00

.82

.62

2.21

.18

.14

.08

.13

.10

.01

.00

.33

.29

.18

.00

.00

.00

.00

.82

.60

.64

.15

.12

.07

.13

.10

.01

.00

.33

.26

.15

.00

.00

.013 

.025*

.639 

.628*

.413 

.257*

.065 

.074*

.109 

.104*

.001 

.002*

.280 

.280*

.025 

.027*

.000 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43704

43704

43801

43801

43802

43802

43803

43803

43804

43804

43806

43806

43811

43811

43812

43812

43813

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Acrylonitrile

Acrylonitrile

Chloromethane

Chloromethane

Dichloromethane

Dichloromethane

Chloroform

Chloroform

Carbon tetrachloride

Carbon tetrachloride

Bromoform

Bromoform

Trichlorofluoromethane

Trichlorofluoromethane

Chloroethane

Chloroethane

1,1-Dichloroethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 21 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

.00

.05

.06

.08

.06

.88

.17

.02

.00

.02

.02

.02

.00

.22

.22

.63

.59

.00

.04

.03

.07

.05

.41

.15

.02

.00

.02

.01

.00

.00

.21

.18

.62

.56

.00

.04

.02

.06

.05

.40

.14

.00

.00

.02

.01

.00

.00

.20

.18

.61

.54

.00

.03

.02

.06

.04

.37

.10

.00

.00

.02

.01

.00

.00

.20

.16

.59

.47

.000*

.019 

.028*

.035 

.039*

.135 

.115*

.001 

.000*

.009 

.011*

.000 

.000*

.164 

.170*

.512 

.512*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43813

43814

43814

43815

43815

43817

43817

43818

43818

43819

43819

43820

43820

43821

43821

43823

43823

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

1,1-Dichloroethane

Methyl chloroform

Methyl chloroform

Ethylene dichloride

Ethylene dichloride

Tetrachloroethylene

Tetrachloroethylene

1,1,2,2-Tetrachloroethane

1,1,2,2-Tetrachloroethane

Bromomethane

Bromomethane

1,1,2-Trichloroethane

1,1,2-Trichloroethane

1,1,2-Trichloro-1,2,2-

trifluoroethane

1,1,2-Trichloro-1,2,2-

trifluoroethane

Dichlorodifluoromethane

Dichlorodifluoromethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 22 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

7

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

.06

.02

0

0

.02

.01

.00

.00

.05

.00

.06

.00

.02

.01

.00

.00

.01

.05

.01

0

0

.01

.01

.00

.00

.00

.00

.00

.00

.02

.01

.00

.00

.01

.03

.00

0

0

.01

.01

.00

.00

.00

.00

.00

.00

.01

.01

.00

.00

.01

.03

.00

0

0

.01

.01

.00

.00

.00

.00

.00

.00

.01

.01

.00

.00

.01

.007 

.005*

.0 

.0*

.011 

.011*

.000 

.000*

.001 

.000*

.001 

.000*

.009 

.009*

.000 

.000*

.007 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43824

43824

43826

43826

43828

43828

43829

43829

43830

43830

43831

43831

43832

43832

43835

43835

43836

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Trichloroethylene

Trichloroethylene

1,1-Dichloroethylene

1,1-Dichloroethylene

Bromodichloromethane

Bromodichloromethane

1,2-Dichloropropane

1,2-Dichloropropane

trans-1,3-Dichloropropene

trans-1,3-Dichloropropene

cis-1,3-Dichloropropene

cis-1,3-Dichloropropene

Dibromochloromethane

Dibromochloromethane

Chloroprene

Chloroprene

Bromochloromethane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 23 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

6

7

6

7

6

7

6

7

6

7

8

9

8

9

1

6

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 6

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 16

 1

 16

 1

 8361

 61

.01

.09

.01

.02

.02

.02

.00

.05

.02

.01

.00

.12

.12

.43

.30

.084

10.24

.01

.06

.01

.02

.02

.01

.00

.05

.00

.00

.00

.12

.39

.083

9.60

.01

.04

.01

.02

.02

.00

.00

.02

.00

.00

.00

.12

.33

.080

9.36

.01

.03

.01

.02

.02

.00

.00

.02

.00

.00

.00

.12

.31

.076

8.96

.007*

.015 

.012*

.018 

.018*

.000 

.000*

.002 

.003*

.000 

.000*

.119*

.119*

.207*

.299*

.0467 

3.592 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43836

43838

43838

43839

43839

43843

43843

43844

43844

43860

43860

43954

43954

43960

43960

44201

45109

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Bromochloromethane

trans-1,2-Dichloroethylene

trans-1,2-Dichloroethylene

cis-1,2-Dichloroethene

cis-1,2-Dichloroethene

Ethylene dibromide

Ethylene dibromide

Hexachlorobutadiene

Hexachlorobutadiene

Vinyl chloride

Vinyl chloride

n-Undecane

n-Undecane

2-Methylheptane

2-Methylheptane

Ozone

m/p Xylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per million

Parts per billion 

Carbon

Meth

101

101

101

101

101

101

101

101

101

101

101

126

126

126

126

087

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 24 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

8

9

6

7

8

9

6

7

8

9

6

7

8

9

6

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 6

 16

 1

 61

 6

 13

 1

 61

 6

 16

 1

 61

 6

 16

 1

 61

 6

4.58

2.54

1.76

6.78

3.01

1.47

.00

23.59

11.62

6.27

4.62

3.60

1.83

.92

.65

4.08

1.81

4.46

2.36

6.00

2.66

1.36

23.38

9.94

5.09

3.45

1.67

.80

3.98

1.78

4.41

1.86

5.38

2.59

1.15

22.47

8.96

4.95

3.30

1.55

.67

3.77

1.77

2.72

1.72

5.20

2.09

.86

22.05

5.93

4.19

3.13

1.06

.55

3.73

1.11

3.491*

1.354*

1.760*

2.404 

2.182*

.808*

.000*

8.251 

7.792*

3.409*

4.620*

1.337 

1.315*

.469*

.650*

1.443 

1.405*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45109

45109

45109

45201

45201

45201

45201

45202

45202

45202

45202

45203

45203

45203

45203

45204

45204

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

m/p Xylene

m/p Xylene

m/p Xylene

Benzene

Benzene

Benzene

Benzene

Toluene

Toluene

Toluene

Toluene

Ethylbenzene

Ethylbenzene

Ethylbenzene

Ethylbenzene

o-Xylene

o-Xylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

101

126

126

101

101

126

126

101

101

126

126

101

101

126

126

101

101

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 25 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

6

7

8

9

6

7

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 16

 1

 61

 6

 16

 1

 61

 6

 16

 1

 16

 1

 16

 1

 16

 1

 16

.99

.70

1.17

.63

.32

.23

3.68

1.87

.86

.67

.21

.17

.16

.08

.38

.07

.53

.96

1.15

.52

.23

3.66

1.59

.82

.21

.14

.30

.53

.74

.97

.44

.21

3.24

1.51

.71

.19

.11

.27

.40

.68

.91

.39

.20

3.06

1.02

.65

.18

.08

.22

.39

.559*

.700*

.406 

.441*

.131*

.230*

1.284 

1.314*

.524*

.672*

.132*

.172*

.031*

.080*

.143*

.068*

.318*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45204

45204

45207

45207

45207

45207

45208

45208

45208

45208

45209

45209

45210

45210

45211

45211

45212

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

o-Xylene

o-Xylene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

n-Propylbenzene

n-Propylbenzene

Isopropylbenzene

Isopropylbenzene

o-Ethyltoluene

o-Ethyltoluene

m-Ethyltoluene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

101

101

126

126

101

101

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 26 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

6

7

8

9

8

9

8

9

30

31

32

30

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 1

 15

 1

 16

 1

 61

 6

 15

 1

 16

 1

 16

 1

 61

 6

 46

 61

.41

.79

.11

.28

.09

.98

.62

.00

.00

.30

.16

.28

.25

1.0

.6

.9

.0

.72

.09

.79

.39

.00

.19

.25

.9

.6

.8

.0

.43

.09

.77

.37

.00

.17

.23

.9

.5

.8

.0

.43

.09

.72

.31

.00

.17

.21

.8

.4

.7

.0

.405*

.267*

.108*

.098*

.086*

.312 

.357*

.000*

.000*

.124*

.160*

.159*

.250*

.42 

.45*

.35*

.02 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45212

45218

45218

45219

45219

45220

45220

45220

45220

45225

45225

45228

45228

45501

45501

45501

45503

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

m-Ethyltoluene

m-Diethylbenzene

m-Diethylbenzene

p-Diethylbenzene

p-Diethylbenzene

Styrene

Styrene

Styrene

Styrene

1,2,3-Trimethylbenzene

1,2,3-Trimethylbenzene

Benzene, 1-ethenyl-4-methyl

Benzene, 1-ethenyl-4-methyl

Benzaldehyde

Benzaldehyde

Benzaldehyde

2,5-Dimethylbenzaldehyde

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

101

101

126

126

126

126

126

126

202

202

202

202

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 27 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

31

32

30

31

32

6

7

6

7

6

7

6

7

6

7

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 6

 48

 56

 6

 43

 61

 6

 61

 6

 61

 6

 61

 6

 61

 6

 8775

 8775

 8775

 8775

.0

.1

.9

.5

1.0

.59

.00

.25

.06

.25

.07

.49

.32

.14

.04

13.4

360.0

115

96

.0

.1

.8

.5

.8

.05

.00

.06

.06

.07

.07

.47

.31

.12

.00

13.2

360.0

115

96

.0

.1

.7

.4

.8

.05

.00

.06

.06

.07

.07

.46

.28

.08

.00

12.4

360.0

114

96

.0

.1

.7

.4

.8

.00

.00

.06

.06

.07

.07

.43

.14

.07

.00

12.4

360.0

114

96

.02*

.08*

.37 

.38*

.38*

.011 

.000*

.066 

.063*

.075 

.072*

.195 

.215*

.009 

.007*

2.49 

172.84 

75.1 

34.9 

24 HOUR

3 HOURS

24 HOUR

24 HOUR

3 HOURS

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

1 HOUR

1 HOUR

1 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45503

45503

45504

45504

45504

45801

45801

45805

45805

45806

45806

45807

45807

45810

45810

61103

61104

62101

62201

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

2,5-Dimethylbenzaldehyde

2,5-Dimethylbenzaldehyde

Tolualdehydes

Tolualdehydes

Tolualdehydes

Chlorobenzene

Chlorobenzene

1,2-Dichlorobenzene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

1,4-Dichlorobenzene

1,2,4-Trichlorobenzene

1,2,4-Trichlorobenzene

Wind Speed - Resultant

Wind Direction - Resultant

Outdoor Temperature

Relative Humidity 

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Knots

Degrees Compass

Degrees Fahrenheit

Percent relative 

humidity

Meth

202

202

202

202

202

101

101

101

101

101

101

101

101

101

101

020

020

021

012

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 28 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

1

7

7

7

1

7

3

3

4

4

1

1

1

1

1

1

1

1

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 122

 122

 121

 122

 122

 122

 121

 122

 362

 8662

 4351

 182

 30

 30

 30

 30

 30

 30

 30

 30

 30

31.3

46.7

38.7

38.4

739

749

738

742

344

4985

4427

329

8.13

2.77

.25

.62

9.73

7.26

.0105

106.00

7.73

31.0

45.6

38.3

38.1

738

744

737

741

120

1633

1993

120

6.35

1.88

.19

.33

5.48

5.34

.0081

62.20

6.55

30.3

45.1

38.1

37.9

737

744

737

740

120

1084

708

108

5.74

1.83

.12

.28

5.35

2.75

.0073

61.80

4.67

29.9

44.2

37.9

37.7

736

743

735

738

118

934

519

97

5.51

1.27

.09

.21

5.06

2.14

.0072

49.60

3.96

15.58 

32.38 

24.00 

23.65 

729.3 

736.1 

728.4 

732.2 

34.8 

35.3 

33.5*

33.1*

2.731*

.760*

.055*

.136*

3.714*

1.327*

.00463*

26.677*

2.526*

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

5

5

5

5

0

0

0

0

0

0

0

0

0

68103

68104

68105

68105

68106

68107

68108

68108

81102

81102

81102

81102

82102

82103

82105

82110

82112

82113

82128

82132

82136

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Ambient Min Temperature

Ambient Max Temperature

Ambient Temperature

Ambient Temperature

Sample Min Baro Pressure

Sample Max Baro Pressure

Sample Baro Pressure

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Antimony PM10 STP

Arsenic PM10 STP

Beryllium PM10 STP

Cadmium PM10 STP

Chromium PM10 STP

Cobalt PM10 STP

Lead PM10 STP

Manganese PM10 STP

Nickel PM10 STP

Degrees Centigrade

Degrees Centigrade

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Millimeters (mercury)

Millimeters (mercury)

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Micrograms/cubic meter

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Meth

810

810

143

810

810

810

143

810

122

122

079

079

202

202

202

202

202

202

202

202

202

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 29 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

1

1

1

1

1

1

1

1

1

1

1

1

1

3

1

3

3

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 30

 30

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 31

 8630

 121

 364

 8683

.02

.61

8.410

1.250

.0900

.4200

10.7

1.4400

.0114

38.800

2.790

.0400

.890

4448.0

52.0

55.9

537.0

.02

.31

8.400

1.240

.0900

.3900

8.8

1.2200

.0101

32.800

2.590

.0300

.640

1348.0

28.8

38.7

202.0

.02

.29

8.200

1.050

.0800

.2700

8.5

.9800

.0073

30.200

2.420

.0300

.460

896.0

27.0

29.5

200.0

.02

.27

7.200

1.010

.0700

.2300

6.9

.7300

.0066

29.500

2.380

.0300

.460

766.0

18.1

25.2

168.0

.010*

.155*

3.2132*

.5990*

.04055*

.12710*

5.35*

.46645*

.00401*

18.9761*

1.5726*

.01493*

.2669*

25.63 

9.23 

7.86 

7.91 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

5

5

82142

82154

85102

85103

85105

85110

85112

85113

85129

85132

85136

85142

85154

86101

88101

88101

88101

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Mercury PM10 STP

Selenium PM10 STP

Antimony PM10 LC

Arsenic PM10 LC

Beryllium PM10 LC

Cadmium PM10 LC

Chromium PM10 LC

Cobalt PM10 LC

Lead PM10 LC FRM/FEM

Manganese PM10 LC

Nickel PM10 LC

Mercury PM10 LC

Selenium PM10 LC

PM10-2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 - Local Conditions

PM2.5 - Local Conditions

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(25 C)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Micrograms/cubic meter

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Nanograms/cubic meter 

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

202

202

202

202

202

202

202

202

202

202

202

202

202

185

143

170

170

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 30 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

.086

.007

1.330

.497

.015

.028

.805

.033

.003

.225

1.750

.044

.023

.853

.016

.042

.013

.063

.003

.655

.053

.011

.019

.372

.025

.003

.025

.398

.044

.023

.496

.011

.028

.013

.056

.003

.564

.030

.010

.019

.357

.017

.002

.018

.360

.043

.023

.388

.010

.021

.013

.054

.002

.405

.030

.009

.014

.313

.011

.002

.018

.299

.043

.023

.385

.007

.017

.008

.0212 

.0005 

.1163 

.0120 

.0039 

.0022 

.1129 

.0024 

.0009 

.0084 

.0738 

.0058 

.0075 

.1560 

.0016 

.0106 

.0031 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88102

88103

88104

88107

88109

88110

88111

88112

88113

88114

88115

88117

88118

88126

88128

88131

88132

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Antimony PM2.5 LC

Arsenic PM2.5 LC

Aluminum PM2.5 LC

Barium PM2.5 LC

Bromine PM2.5 LC

Cadmium PM2.5 LC

Calcium PM2.5 LC

Chromium PM2.5 LC

Cobalt PM2.5 LC

Copper PM2.5 LC

Chlorine PM2.5 LC

Cerium PM2.5 LC

Cesium PM2.5 LC

Iron PM2.5 LC

Lead PM2.5 LC

Indium PM2.5 LC

Manganese PM2.5 LC

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 31 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

 122

.009

.726

.008

.001

.033

.075

.005

4.030

.019

.062

.100

2.190

.003

6.970

.389

.018

1.36

.008

.122

.008

.001

.026

.040

.004

1.820

.019

.029

.045

.829

.001

.488

.362

.012

.92

.005

.108

.008

.001

.025

.035

.004

1.550

.019

.026

.012

.824

.001

.434

.360

.012

.81

.003

.099

.008

.001

.021

.031

.004

1.020

.019

.025

.010

.805

.001

.355

.351

.012

.80

.0005 

.0261 

.0057 

.0011 

.0130 

.0090 

.0017 

.3525 

.0086 

.0089 

.0030 

.3483 

.0010 

.1756 

.0937 

.0041 

.376 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88136

88140

88152

88154

88160

88161

88164

88165

88166

88167

88168

88169

88176

88180

88184

88185

88301

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Nickel PM2.5 LC

Magnesium PM2.5 LC

Phosphorus PM2.5 LC

Selenium PM2.5 LC

Tin PM2.5 LC

Titanium PM2.5 LC

Vanadium PM2.5 LC

Silicon PM2.5 LC

Silver PM2.5 LC

Zinc PM2.5 LC

Strontium PM2.5 LC

Sulfur PM2.5 LC

Rubidium PM2.5 LC

Potassium PM2.5 LC

Sodium PM2.5 LC

Zirconium PM2.5 LC

Ammonium Ion PM2.5 LC

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

812

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 32 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 122

 122

 122

 120

 120

 120

 120

 120

 120

 120

 120

 120

 113

 113

 119

 120

 122

.43

7.53

4.14

14.200

3.010

13.400

2.280

3.590

3.150

1.360

4.730

3.280

6.530

.233

.039

5.440

5.65

.39

.36

3.89

9.490

2.890

9.100

1.440

2.110

2.300

1.160

1.350

2.740

3.320

.152

.033

1.740

2.48

.39

.32

3.62

6.100

2.040

5.910

.872

1.620

2.140

1.060

.827

2.260

3.020

.147

.012

1.050

2.46

.39

.27

2.38

6.060

1.930

5.880

.812

1.440

1.940

1.010

.691

2.260

2.530

.137

.011

.971

2.31

.114 

.109 

.736 

2.4843 

.6034 

2.3269 

.1682 

.5815 

.8343 

.4856 

.2571 

.7606 

.8805 

.0672 

.0022 

.4143 

1.053 

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

88302

88303

88306

88355

88357

88370

88374

88375

88376

88377

88378

88380

88383

88384

88385

88388

88403

Parameter

Site ID: 04-013-9997 City: Phoenix Maricopa

Unit

County: Address: 4530 N 17TH AVENUE

Sodium Ion Pm2.5 LC

Potassium Ion PM2.5 LC

Total Nitrate PM2.5 LC

OC CSN_Rev Unadjusted PM2.5 LC 

TOT

EC CSN_Rev Unadjusted PM2.5 LC 

TOT

OC CSN_Rev Unadjusted PM2.5 LC 

TOR

OC1 CSN_Rev Unadjusted PM2.5 LC

OC2 CSN_Rev Unadjusted PM2.5 LC

OC3 CSN_Rev Unadjusted PM2.5 LC

OC4 CSN_Rev Unadjusted PM2.5 LC

OP CSN_Rev Unadjusted PM2.5 LC 

TOR

EC CSN_Rev Unadjusted PM2.5 LC 

TOR

EC1 CSN_Rev Unadjusted PM2.5 LC

EC2 CSN_Rev Unadjusted PM2.5 LC

EC3 CSN_Rev Unadjusted PM2.5 LC

OP CSN_Rev Unadjusted PM2.5 LC 

TOT

Sulfate PM2.5 LC

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

812

812

812

839

840

838

841

841

841

841

842

831

841

841

841

826

812

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 33 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

3

3

7

1

1

1

3

3

1

3

3

3

3

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 91

 2180

 122

 8784

 8784

 30

 181

 4330

 30

 357

 8578

 363

 8677

 2181

59.0

205.9

49.0

1.54

.07

35

185

893

33

138

1895

239

1671

27.2

23.9

199.1

26.7

1.53

.07

33

74

719

31

116

1318

228

1560

19.1

20.5

170.7

24.6

1.53

.07

32

64

670

30

109

582

127

1267

15.0

20.3

150.9

21.6

1.53

.07

31

45

647

29

109

542

127

1188

14.5

12.76*

12.81 

9.71 

.353 

.016 

18.3*

21.3*

21.8*

17.8*

33.7 

34.4 

42.4 

42.9 

4.30*

24-HR BLK 

AVG

1 HOUR

24 HOUR

1 HOUR

1 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24-HR BLK 

AVG

1 HOUR

1 HOUR

0

0

0

0

0

0

5

5

0

0

0

5

5

0

88500

88500

88502

63301

63302

81102

81102

81102

85101

81102

81102

81102

81102

42600

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

04-013-9997

04-013-9998

04-015-1003

04-019-0001

04-019-0020

04-021-8001

Phoenix

Phoenix

Bullhead City

Ajo

Rillito

Queen Valley

City:

City:

City:

City:

City:

City:

Maricopa

Maricopa

Mohave

Pima

Pima

Pinal

Unit

County:

County:

County:

County:

County:

County:

4530 N 17TH AVENUE

600 N 40TH ST & FILLMORE ST,PHOENIX

BULLHEAD CITY 990 HWY 95

AZ HWY DEPT YARD-WELL RD, AJO

8840 W ROBINSON STREET, RILLITO

10 S QUEEN ANN QUEEN VALLEY

Address:

Address:

Address:

Address:

Address:

Address:

PM2.5 Total Atmospheric

PM2.5 Total Atmospheric

Acceptable PM2.5 AQI & Speciation

Mass

Solar radiation

Ultraviolet radiation

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

Reactive oxides of nitrogen (NOy)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Langleys/minute

Langleys/minute

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Parts per billion

Meth

761

761

810

011

011

126

079

079

126

079

079

079

079

574

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 34 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 15

 47

 5

 21

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

119.00

174.00

.08

4.27

.19

.19

.19

.19

.19

.19

.09

.09

.11

.11

4.78

5.38

3.10

109.00

121.00

.08

.08

.19

.19

.19

.19

.19

.19

.09

.09

.11

.11

4.66

5.20

2.93

91.40

114.00

.08

.08

.19

.19

.19

.19

.19

.19

.09

.09

.11

.11

4.44

4.94

2.66

90.80

102.00

.08

.08

.19

.19

.19

.19

.19

.19

.09

.09

.11

.11

3.89

4.72

2.41

83.547*

59.387*

.083*

.282*

.192*

.192*

.192*

.192*

.192*

.192*

.092*

.092*

.106*

.106*

2.527*

2.549*

1.732*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43102

43102

43127

43127

43141

43141

43142

43142

43143

43143

43144

43144

43145

43145

43202

43202

43203

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

Total NMOC (non-methane organic 

compound)

Total NMOC (non-methane organic 

compound)

Isobutene & 1-butene

Isobutene & 1-butene

n-Dodecane

n-Dodecane

Tridecene

Tridecene

n-Tridecane

n-Tridecane

Propyne

Propyne

1-Octene

1-Octene

Ethane

Ethane

Ethylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 35 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

3.18

2.51

2.85

.80

1.00

.66

.73

.91

1.09

.51

.78

.38

.33

.10

.10

.50

.46

3.01

2.36

2.62

.71

.98

.66

.62

.82

1.08

.28

.45

.18

.32

.10

.10

.44

.44

2.98

2.36

2.61

.55

.80

.55

.60

.65

1.01

.27

.34

.16

.27

.10

.10

.44

.44

2.93

2.16

2.60

.53

.79

.34

.57

.65

.84

.27

.33

.07

.26

.10

.10

.39

.43

1.742*

1.312*

1.190*

.477*

.476*

.320*

.301*

.478*

.435*

.191*

.176*

.106*

.099*

.100*

.100*

.128*

.118*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43203

43204

43204

43205

43205

43206

43206

43212

43212

43214

43214

43216

43216

43217

43217

43218

43218

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

Ethylene

Propane

Propane

Propylene

Propylene

Acetylene

Acetylene

n-Butane

n-Butane

Isobutane

Isobutane

trans-2-Butene

trans-2-Butene

cis-2-Butene

cis-2-Butene

1,3-Butadiene

1,3-Butadiene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 36 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 15

 47

 10

 36

 15

 47

 15

 47

 15

 47

 15

 47

 14

 45

 15

 47

 15

13.10

51.60

7.77

19.60

.38

.44

.13

.13

.08

.08

.11

.11

.13

.13

.17

.28

.31

.50

23.00

4.32

8.54

.36

.43

.13

.13

.08

.08

.11

.11

.13

.13

.08

.24

.18

.49

1.00

4.31

8.32

.34

.42

.13

.13

.08

.08

.11

.11

.13

.13

.08

.22

.17

.49

.72

.66

7.72

.30

.38

.13

.13

.08

.08

.11

.11

.13

.13

.08

.22

.17

1.191*

1.903*

1.843*

2.081*

.159*

.159*

.130*

.130*

.076*

.076*

.108*

.108*

.130*

.130*

.084*

.099*

.098*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43220

43220

43221

43221

43224

43224

43225

43225

43226

43226

43227

43227

43228

43228

43230

43230

43231

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

n-Pentane

n-Pentane

Isopentane

Isopentane

1-Pentene

1-Pentene

2-Methyl-1-butene

2-Methyl-1-butene

trans-2-Pentene

trans-2-Pentene

cis-2-Pentene

cis-2-Pentene

2-Methyl-2-butene

2-Methyl-2-butene

3-Methylpentane

3-Methylpentane

n-Hexane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 37 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

.67

.22

.22

.20

.24

.17

.17

.06

.06

.17

.17

.08

.17

.07

2.46

.95

1.68

.39

.08

.08

.08

.17

.17

.17

.06

.06

.17

.17

.08

.08

.07

.78

.69

1.54

.28

.08

.08

.08

.08

.17

.17

.06

.06

.17

.17

.08

.08

.07

.07

.49

.95

.27

.08

.08

.08

.08

.17

.17

.06

.06

.17

.17

.08

.08

.07

.07

.49

.92

.089*

.085*

.079*

.086*

.083*

.171*

.171*

.062*

.062*

.171*

.171*

.078*

.080*

.075*

.140*

.407*

.518*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43231

43232

43232

43233

43233

43234

43234

43235

43235

43236

43236

43238

43238

43242

43242

43243

43243

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

n-Hexane

n-Heptane

n-Heptane

n-Octane

n-Octane

4-Methyl-1-pentene

4-Methyl-1-pentene

n-Nonane

n-Nonane

2-Ethyl-1-butene

2-Ethyl-1-butene

n-Decane

n-Decane

Cyclopentane

Cyclopentane

Isoprene

Isoprene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 38 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

.10

.10

.17

.17

.17

.17

.09

.09

.42

.25

.62

2.49

.21

.32

.35

.27

.06

.10

.10

.17

.17

.17

.17

.09

.09

.09

.21

.54

1.86

.18

.26

.07

.25

.06

.10

.10

.17

.17

.17

.17

.09

.09

.09

.20

.44

1.17

.17

.23

.07

.24

.06

.10

.10

.17

.17

.17

.17

.09

.09

.09

.09

.40

.56

.15

.21

.07

.20

.06

.099*

.099*

.171*

.171*

.171*

.171*

.087*

.087*

.112*

.098*

.196*

.231*

.089*

.067*

.089*

.090*

.060*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43244

43244

43245

43245

43246

43246

43247

43247

43248

43248

43249

43249

43250

43250

43252

43252

43253

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

2,2-Dimethylbutane

2,2-Dimethylbutane

1-Hexene

1-Hexene

2-Methyl-1-pentene

2-Methyl-1-pentene

2,4-Dimethylpentane

2,4-Dimethylpentane

Cyclohexane

Cyclohexane

3-Methylhexane

3-Methylhexane

2,2,4-Trimethylpentane

2,2,4-Trimethylpentane

2,3,4-Trimethylpentane

2,3,4-Trimethylpentane

3-Methylheptane

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 39 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 47

 15

 47

 15

 46

 15

 46

 15

 47

 15

 47

 15

 47

 15

 47

 15

 45

.06

.11

.27

1.03

.63

.31

.21

.19

.32

.48

1.37

.09

.09

.13

.13

.13

.13

.06

.11

.23

.11

.51

.07

.07

.18

.23

.43

.97

.09

.09

.13

.13

.13

.13

.06

.11

.22

.11

.47

.07

.07

.17

.21

.40

.91

.09

.09

.13

.13

.13

.13

.06

.11

.11

.11

.41

.07

.07

.11

.17

.39

.68

.09

.09

.13

.13

.13

.13

.060*

.108*

.116*

.169*

.148*

.087*

.074*

.086*

.080*

.275*

.265*

.094*

.094*

.130*

.130*

.130*

.130*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43253

43256

43256

43257

43257

43261

43261

43262

43262

43263

43263

43279

43279

43282

43282

43283

43283

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

3-Methylheptane

alpha.-Pinene

alpha.-Pinene

beta.-Pinene

beta.-Pinene

Methylcyclohexane

Methylcyclohexane

Methylcyclopentane

Methylcyclopentane

2-Methylhexane

2-Methylhexane

1-Nonene

1-Nonene

3-Methyl-1-butene

3-Methyl-1-butene

Cyclopentene

Cyclopentene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 40 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 15

 47

 15

 46

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 14

.12

.12

.80

1.48

.17

.17

.17

.17

.11

.26

.11

.11

.11

.11

.12

.12

.11

.12

.12

.47

.91

.17

.17

.17

.17

.11

.11

.11

.11

.11

.11

.12

.12

.11

.12

.12

.46

.83

.17

.17

.17

.17

.11

.11

.11

.11

.11

.11

.12

.12

.11

.12

.12

.44

.81

.17

.17

.17

.17

.11

.11

.11

.11

.11

.11

.12

.12

.11

.121*

.121*

.368*

.371*

.171*

.171*

.171*

.171*

.113*

.116*

.106*

.106*

.108*

.108*

.119*

.119*

.113*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43284

43284

43285

43285

43289

43289

43290

43290

43291

43291

43292

43292

43298

43298

43299

43299

43328

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

2,3-Dimethylbutane

2,3-Dimethylbutane

2-Methylpentane

2-Methylpentane

trans-2-Hexene

trans-2-Hexene

cis-2-Hexene

cis-2-Hexene

2,3-Dimethylpentane

2,3-Dimethylpentane

2-2-3-Trimethylpentane

2-2-3-Trimethylpentane

1-Decene

1-Decene

1-Undecene

1-Undecene

1-Heptene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 41 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

1

8

9

8

9

8

9

8

9

8

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 45

 15

 47

 15

 47

 15

 47

 5871

 15

 47

 6

 20

 15

 47

 15

 47

 15

.11

.62

.75

.12

.12

.06

.06

.082

.22

.69

27.90

19.90

.96

1.92

.21

.24

.15

.11

.19

.62

.12

.12

.06

.06

.080

.19

.28

.00

8.97

.70

1.46

.11

.10

.10

.11

.19

.57

.12

.12

.06

.06

.079

.19

.27

.00

.00

.60

.72

.08

.09

.09

.11

.19

.55

.12

.12

.06

.06

.078

.16

.23

.00

.00

.54

.72

.00

.09

.09

.113*

.220*

.248*

.119*

.119*

.063*

.063*

.0584 

.060*

.055*

4.650*

1.444*

.478*

.385*

.027*

.011*

.034*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

43328

43330

43330

43954

43954

43960

43960

44201

45109

45109

45201

45201

45202

45202

45203

45203

45204

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

1-Heptene

Dodecene

Dodecene

n-Undecane

n-Undecane

2-Methylheptane

2-Methylheptane

Ozone

m/p Xylene

m/p Xylene

Benzene

Benzene

Toluene

Toluene

Ethylbenzene

Ethylbenzene

o-Xylene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per million

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

087

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 42 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

8

9

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 15

 47

 14

 46

 15

 47

.33

.06

.06

.25

.43

.07

.18

.06

.00

.07

.07

.06

.06

.11

.11

.09

.18

.17

.06

.06

.09

.36

.07

.17

.00

.00

.07

.07

.06

.06

.11

.11

.09

.09

.17

.06

.06

.09

.32

.07

.16

.00

.00

.07

.07

.06

.06

.11

.11

.09

.09

.14

.06

.06

.09

.24

.07

.07

.00

.00

.07

.07

.06

.06

.11

.11

.09

.09

.030*

.060*

.060*

.102*

.112*

.069*

.075*

.004*

.000*

.068*

.068*

.061*

.061*

.108*

.108*

.086*

.088*

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45204

45207

45207

45208

45208

45209

45209

45210

45210

45211

45211

45212

45212

45218

45218

45219

45219

Parameter

Site ID: 04-021-8001 City: Queen Valley Pinal

Unit

County: Address: 10 S QUEEN ANN QUEEN VALLEY

o-Xylene

1,3,5-Trimethylbenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene

1,2,4-Trimethylbenzene

n-Propylbenzene

n-Propylbenzene

Isopropylbenzene

Isopropylbenzene

o-Ethyltoluene

o-Ethyltoluene

m-Ethyltoluene

m-Ethyltoluene

m-Diethylbenzene

m-Diethylbenzene

p-Diethylbenzene

p-Diethylbenzene

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Meth

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 43 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

8

9

8

9

8

9

1

1

1

2

1

2

1

2

1

3

3

1

1

2

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 15

 45

 15

 47

 15

 47

 8592

 8592

 8591

 8591

 58

 55

 58

 55

 58

 8110

 337

 58

 58

 52

.95

.66

.05

.18

.09

.09

24.3

360.0

112

100

28.4

29.1

669

668

102

793

169

94

29.0

26.7

.00

.00

.05

.05

.09

.09

23.9

360.0

112

100

27.9

28.5

665

666

72

667

153

65

25.9

22.5

.00

.00

.05

.05

.09

.09

23.5

360.0

112

100

27.4

28.0

665

666

69

635

139

64

23.2

15.9

.00

.00

.05

.05

.09

.09

23.5

360.0

112

99

27.4

28.0

665

665

67

499

123

58

22.7

15.7

.063*

.015*

.052*

.055*

.094*

.094*

6.07 

157.81 

73.5 

29.7 

18.30 

18.73 

662.5 

662.9 

36.7 

48.1 

47.7*

32.7 

9.39 

9.30*

24 HOUR

3 HOURS

24 HOUR

3 HOURS

24 HOUR

3 HOURS

1 HOUR

1 HOUR

1 HOUR

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

1 HOUR

24-HR BLK 

AVG

24 HOUR

24 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

45220

45220

45225

45225

45228

45228

61103

61104

62101

62201

68105

68105

68108

68108

81102

81102

81102

85101

88101

88101

Parameter

Site ID:

Site ID:

04-021-8001

04-023-0004

Queen Valley

Nogales

City:

City:

Pinal

Santa Cruz

Unit

County:

County:

10 S QUEEN ANN QUEEN VALLEY

300 N MORLEY AVE

Address:

Address:

Styrene

Styrene

1,2,3-Trimethylbenzene

1,2,3-Trimethylbenzene

Benzene, 1-ethenyl-4-methyl

Benzene, 1-ethenyl-4-methyl

Wind Speed - Resultant

Wind Direction - Resultant

Outdoor Temperature

Relative Humidity 

Ambient Temperature

Ambient Temperature

Sample Baro Pressure

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

PM2.5 - Local Conditions

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Parts per billion 

Carbon

Knots

Degrees Compass

Degrees Fahrenheit

Percent relative 

humidity

Degrees Centigrade

Degrees Centigrade

Millimeters (mercury)

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Meth

126

126

126

126

126

126

020

020

021

012

143

143

143

143

126

122

122

126

143

143

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 44 of 54

P

O

C PQAO Year

#

Obs

1st Max

Value

2nd Max

Value

3rd Max

Value

4th Max

Value

Arith.

Mean Duration

EDT

3

3

1

1

1

1

1

1

1

1

1

3

3

1

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

0053

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

2012

 219

 5256

 60

 60

 58

 58

 59

 5746

 5859

 59

 59

 365

 8735

 57

89.0

256.0

28.0

640

39

33

14.0

.074

.092

37.9

762

274

1881

17.0

41.0

243.0

27.5

638

35

28

10.8

.073

.082

37.8

762

240

1747

15.8

38.7

238.0

27.5

638

28

24

10.2

.072

.080

37.7

761

220

1709

15.3

36.6

230.0

26.8

637

28

23

9.4

.072

.080

36.1

760

215

1626

14.5

11.67*

11.70*

15.25 

633.7 

12.5 

10.6 

4.47 

.0518 

.0523 

25.29 

753.5 

43.2 

43.7 

8.46 

24-HR BLK 

AVG

1 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

24 HOUR

8-HR RUN 

AVG BEGIN 

HOUR

8-HR RUN 

AVG BEGIN 

HOUR

24 HOUR

24 HOUR

24-HR BLK 

AVG

1 HOUR

24 HOUR

0

0

0

0

0

0

0

0

0

0

0

5

5

0

88501

88501

68105

68108

81102

85101

88101

44201

44201

68105

68108

81102

81102

88101

Parameter

Site ID:

Site ID:

Site ID:

Site ID:

04-023-0004

04-025-2002

04-025-8033

04-027-8011

Nogales

Prescott Valley

Prescott

Yuma

City:

City:

City:

City:

Santa Cruz

Yavapai

Yavapai

Yuma

Unit

County:

County:

County:

County:

300 N MORLEY AVE

7501 E. CIVIC CIRCLE, PRESCOTT VALLEY

330 Grove Avenue

2323 S ARIZONA AVE

Address:

Address:

Address:

Address:

PM2.5 Raw Data

PM2.5 Raw Data

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 - LC

PM2.5 - Local Conditions

Ozone

Ozone

Ambient Temperature

Sample Baro Pressure

PM10 Total 0-10um STP

PM10 Total 0-10um STP

PM2.5 - Local Conditions

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Micrograms/cubic meter

(LC)

Parts per million

Parts per million

Degrees Centigrade

Millimeters (mercury)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(25 C)

Micrograms/cubic meter

(LC)

Meth

731

731

143

143

126

126

143

047

087

143

143

079

079

143

Cert

S

S

S

S

S

S

S

S

S

S

S

S

S

S
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 45 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

12115

14129

17141

17147

17148

17149

17150

17151

17158

17159

17160

17201

17204

17208

17211

17212

17215

17220

17223

17224

17231

17237

17242

17243

42101

42153

42401

42401

42406

42406

42600

42600

42601

920

191

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

118

588

101

060

592

060

592

574

591

074

LO-VOL-XONTECH 920 or 924

Hi-Vol

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

Hi Vol/PUF-XAD-2

INSTRUMENTAL

CANISTER SUBAMBIENT PRESSURE

INSTRUMENTAL

Instrumental

INSTRUMENTAL

Instrumental

Instrumental

Instrumental

INSTRUMENTAL

ION CHROMATOGRAPH UV VISIBLE

Inductively Coupled Plasma-Mass Spectrometry Acid filter 

extraction with nitric and hydrochloric acid

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

GCMS TO-13

Gas Filter Correlation Ecotech EC9830T

MULTI DETECTOR GC

PULSED FLUORESCENT

Ultraviolet Fluorescence EC9850T

PULSED FLUORESCENT

Ultraviolet Fluorescence EC9850T

Chemiluminescence Thermo Electron 42C-Y, 42i-Y

Chemiluminescence Ecotech EC9843

CHEMILUMINESCENCE
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 46 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

42602

42603

43102

43127

43141

43142

43143

43144

43145

43202

43203

43204

43205

43205

43206

43206

43208

43212

43214

43216

43217

43218

43218

43220

43221

43224

43225

43226

43227

43228

43230

43231

43232

43233

074

074

126

126

126

126

126

126

126

126

126

126

101

126

101

126

101

126

126

126

126

101

126

126

126

126

126

126

126

126

126

126

126

101

INSTRUMENTAL

INSTRUMENTAL

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

Canister Subambient Pressure

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

CHEMILUMINESCENCE

CHEMILUMINESCENCE

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

Multi Detector GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 47 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43233

43234

43235

43236

43238

43242

43243

43244

43245

43246

43247

43248

43249

43250

43252

43253

43256

43257

43261

43262

43263

43279

43282

43283

43284

43285

43289

43290

43291

43292

43298

43299

43328

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

126

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 48 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43330

43372

43373

43396

43438

43441

43502

43503

43504

43505

43510

43513

43517

43518

43528

43551

43552

43560

43702

43704

43801

43802

43803

43804

43806

43811

43812

43813

43814

43815

43817

43818

43819

126

101

101

101

101

101

202

202

202

101

202

202

202

202

202

202

202

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

SS CANISTER PRESSURIZED

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

CANISTER SUBAMBIENT PRESSURE

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

Canister Subambient Pressure

Canister Subambient Pressure

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

Multi Detector GC

Multi Detector GC

Multi Detector GC

Multi Detector GC

Multi Detector GC

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

MULTI DETECTOR GC

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

Multi Detector GC

Multi Detector GC

Multi Detector GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 49 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

43820

43821

43823

43824

43826

43828

43829

43830

43831

43832

43835

43836

43838

43839

43843

43844

43860

43954

43960

44201

44201

45109

45109

45201

45201

45202

45202

45203

45203

45204

45204

45207

45207

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

101

126

126

047

087

101

126

101

126

101

126

101

126

101

126

101

126

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

INSTRUMENTAL

INSTRUMENTAL

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

Multi Detector GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

ULTRA VIOLET

ULTRA VIOLET ABSORPTION

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 50 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

45208

45208

45209

45210

45211

45212

45218

45219

45220

45220

45225

45228

45501

45503

45504

45801

45805

45806

45807

45810

61103

61104

62101

62201

63301

63302

68103

68104

68105

68105

68105

68106

68107

101

126

126

126

126

126

126

126

101

126

126

126

202

202

202

101

101

101

101

101

020

020

021

012

011

011

810

810

143

780

810

810

810

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

SILICA-DNPH-CART-KI O3 SCRUB

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE

Canister Subambient Pressure

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

INSTRUMENTAL

Met One SASS

Met One SASS

R & P Model 2000 PM-2.5 FEM Air Sampler

INSTRUMENTAL

Met One SASS

Met One SASS

Met One SASS

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

MULTI DETECTOR GC

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

CRYOGENIC PRECONCENTRATION GC/FID

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

HPLC ULTRAVIOLET ABSORPTION

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

MULTI DETECTOR GC

Multi Detector GC

VECTOR SUMMATION

VECTOR SUMMATION

SPOT READING LEVEL 1

HYGROSCOPIC PLASTIC FILM

PYRANOMETER

UV RADIOMETER (PHOTOMETER)

Electronic

Electronic

Electronic

ELECTRONIC

Electronic

Barometric Sensor
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 51 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

68108

68108

68108

81102

81102

81102

82102

82103

82105

82110

82112

82113

82128

82132

82136

82142

82154

85101

85102

85103

85105

85110

85112

85113

85129

85132

85136

85142

85154

86101

88101

88101

88102

143

780

810

079

122

126

202

202

202

202

202

202

202

202

202

202

202

126

202

202

202

202

202

202

202

202

202

202

202

185

143

170

811

R & P Model 2000 PM-2.5 FEM Air Sampler

INSTRUMENTAL

Met One SASS

INSTRUMENTAL-R&P SA246B-INLET

INSTRUMENT MET ONE 4 MODELS

R - P Co Partisol Model 2000

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R - P Co Partisol Model 2000

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

R&P Model 2000 PM10 Teflon

Met One BAM-1020 System

R & P Model 2000 PM-2.5 Air Sampler w/VSCC

Met One BAM-1020 Mass Monitor w/VSCC

Met One SASS Teflon

Barometric Sensor

Barometric Sensor

BAROMETRIC SENSOR

Barometric Sensor

TEOM-GRAVIMETRIC

BETA ATTENUATION

Gravimetric

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

Gravimetric

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

ICP/MS

Paired Gravimetric Difference

Gravimetric

Beta Attenuation
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 52 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

88103

88104

88107

88109

88110

88111

88112

88113

88114

88115

88117

88118

88126

88128

88131

88132

88136

88140

88152

88154

88160

88161

88164

88165

88166

88167

88168

88169

88176

88180

88184

88185

88301

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

811

812

Met OneSASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Teflon

Met One SASS Nylon

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy dispersive XRF

Energy Dispersive XRF

Energy dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF

Energy Dispersive XRF
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 53 of 54

PARAMETER

METHOD

CODE COLLECTION METHOD ANALYSIS METHOD

METHODS USED IN THIS REPORT

88302

88303

88306

88355

88357

88370

88374

88375

88376

88377

88378

88380

88383

88384

88385

88388

88403

88500

88501

88502

812

812

812

839

840

838

841

841

841

841

842

831

841

841

841

826

812

761

731

810

Met One SASS Nylon

Met One SASS Nylon

Met One SASS Nylon

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter adn Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl

Met One SASS Nylon

PM2.5 VSCC

Met-One BAM-1020 W/PM2.5 SCC

Met One SASS Teflon

Ion Chromatography

Ion Chromatography

Ion Chromatography

Ion Chromatography

OC1+OC2+OC3+OC4+(OP(TOT))=(88374+88375+88376+88377+88388)

EC1+EC2+EC3-(OP(TOT))=(88383+88384+88385-88388))

OC1+OC2+OC3+OC4+(OP(TOR))=(88374+88375+88376+88377+88378)

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A TOR

EC1+EC2+EC3-(OP(TOR))=(88383+88384+88385-88378))

IMPROVE_A

IMPROVE_A

IMPROVE_A

IMPROVE_A TOT

Ion Chromatography

FDMS-Gravimetric

Beta Attenuation

Gravimetric
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

AIR QUALITY SYSTEM

May. 16, 2013

Note: The * indicates that the mean does not

satisfy summary criteria.

QUICKLOOK ALL PARAMETERS

Page 54 of 54

PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION

0053 Arizona Department Of Environmental Quality
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

DATA EVALUATION AND CONCURRENCE REPORT

Report Request ID: 1096804 Report Code: AMP600 May. 9, 2013

Selection Criteria Page 1

User ID: JOJ

State County City Site Parameter POC AQCR UAR CBSA CSA

EPA

Region Method Duration Begin Date End Date

04

GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS

Parameter

Classification Parameter Method Duration

CRITERIA 42602

AGENCY SELECTIONS

Arizona Department Of Environmental 

Quality

SELECTED OPTIONS

MERGE PDF FILES

Option Type Option Value

YES

GLOBAL DATES

2011

Start Date End Date

2011

Tribal

Code
May. 9, 2013 Data Evaluation and Concurrence Report Summary

Page 1 of 1

Certification Year: 2011

Certifying Agency (CA): Arizona Department Of Environmental Quality (0053)

Pollutants in Report:

PQAO

Parameter

Code

Nitrogen dioxide (NO2) 42602

Parameter Name

Monitors

Code Evaluated

1

Arizona Department Of Environmental Quality 0053

PQAO Code

AQS Site-ID POC

AQS

Recommended

Flag

Cert. Agency

Recommended

Flag Reason for AQS Recommendation

0053 42602 1 04-013-9997 N Y Quality Assurance Project Plan not approved in 10 

years.

Signature of Monitoring Organization Representative: ________________________________________________________

PQAO Name

Summary of 'N' flags for all pollutants:

0 1

PQAOs in Report:

04/09/12

TSA Date

Monitors Recommended for

Concurrence by AQS

Monitors NOT Recommended

for Concurrence by AQS
Data Evaluation and Concurrence Report for Gaseous Pollutants

Certifying Year 2011

Certifying Agency Code Arizona Department Of Environmental Quality (0053)

Nitrogen dioxide (NO2) (42602) (ppb)

PQAO Name Arizona Department Of Environmental Quality (0053)

QAPP Approval Date 08/06/1994

04-013-9997 SLAMS 16.8 1

Mean

 1.0

Min

 59.0

Max Exceed.

Count

0

Outlier

Count

99

Perc.

Comp.

 2.96

Precision

+/-2.51

Bias

 81

Complete

100

Complete Bias

Y

PQAO Level

Criteria

N

Aqs Rec 

Flag

Y

CA Rec

Flag

Epa 

Concur

Submitter Comment ADEQ is working to produce QAPPs according to the 

Parameter

0 Y

NPAP Audit Summary: Number of Valid Audits NPAP Bias Criteria Met

- 2.84

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

AQS 

Site ID

POC Monitor

Type

Bias QAPP

Appr.

N
Data Evaluation and Concurrence Report for Particulate Matter
Data Concurrence and Evaluation Report for Lead