**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1 1,505 8,481 8,421 1,273 0.70 40.9 0.21 0.11 BDL 0.84 0.11 81.6 DLL 0.03
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2 1,528 8,598 8,503 1,273 1.10 40.9 0.22 0.11 BDL 0.87 0.11 126 DLL 0.03
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3 1,525 8,519 8,408 1,286 1.30 40.9 0.21 0.11 BDL 0.84 0.11 BDL 122 DLL 0.03
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1 3,827 20,011 19,811 1,323 1.00 29.4 0.43 0.11 BDL 2.03 0.43 506 DLL 8.37
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2 3,747 20,394 20,210 1,335 0.90 29.5 0.44 0.11 BDL 2.39 0.44 572 DLL 12.3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3 4,037 21,015 20,784 1,321 1.10 29.7 0.43 0.11 BDL 1.83 0.32 552 DLL 18.30
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1 4,271 20,596 20,369 1,184 1.10 17.0 0.72 0.31 5.28 0.21 14.5 DLL 0.03
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2 4,640 22,060 21,729 1,217 1.50 17.6 0.81 0.20 5.47 0.20 17.6 DLL 0.03
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3 4,657 22,253 21,852 1,263 1.80 17.0 0.72 0.31 5.28 0.21 28.2 DLL 0.03
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1 28,767 28,767 1,186 0 22.1 0 0 6.50 1.50 115 12.9
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2 29,033 29,033 1,193 0 23.8 0 0 5.90 1.30 139 14.8
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3 28,833 28,833 1,198 0 22.8 0 0 6.40 1.40 122 14.5

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1 28,420 992 ADL 3.1ADL 21.5ADL 0.90ADL 0.15 DLL 4.00ADL 0.11 DLL 30.9 DLL 0.76

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2 28,320 981 ADL 3.1ADL 21.5ADL 0.89ADL 0.12 DLL 3.87ADL 0.09 DLL 41.9 DLL 1.24

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3 28,411 981 ADL 2.8ADL 20.9ADL 0.88ADL 0.18 DLL 3.86ADL 0.09 DLL 25.0 DLL 0.93

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1 3,766 889 ADL 3.1ADL 47.3ADL 0.02 BDL 0.02 DLL 1.34ADL 0.25ADL 4.06 BDL 0.11

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2 3,394 1,000 ADL 3.1ADL 39.9ADL 0.06 DLL 0.02 DLL 0.72ADL 0.04 DLL 2.60 BDL 0.11

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 3,256 904 ADL 2.8ADL 35.0ADL 0.08 DLL 0.02 BDL 0.80ADL 0.04 DLL 5.46 BDL 0.11 Form Approved OMB Control No. 2060- Approval Expires**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 Form Approved OMB Control No. 2060- Approval Expires

Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

BDL 11.5 0.15 209,041 86,230 2,479 0.53 BDL 134,679 4,651 0.53 BDL 44,104 67,615 1,592 1,217 1,554

11.5 0.15 202,936 82,721 2,380 0.54 BDL 136,429 4,490 0.54 BDL 44,981 68,954 1,639 1,179 1,515

BDL 10.9 0.17 198,784 84,252 2,569 0.55 BDL 133,275 4,684 0.55 BDL 51,593 68,098 1,548 1,257 1,701

29.5 0.34 285,832 115,501 6,783 0.53 BDL 113,271 13,323 0.53 BDL 50,775 35,533 3,846 3,282 4,959
30.6 0.46 275,317 113,348 6,775 0.54 BDL 114,581 13,684 0.54 BDL 54,366 34,297 4,219 3,562 4,992
32.7 0.36 278,916 123,709 6,628 0.54 BDL 124,397 12,803 0.54 BDL 47,143 28,321 3,652 3,012 3,905

BDL 7.65 0.03 BDL 446,943 108,394 62,126 0.52 BDL 47,763 62,864 3.10 3,414 6,986 1,135 998 856

BDL 8.18 0.03 BDL 404,469 107,934 78,780 0.51 BDL 51,252 68,925 3.04 3,958 7,986 1,616 1,667 1,267

BDL 8.83 0.03 BDL 370,656 123,807 74,471 0.49 BDL 59,444 87,441 3.89 3,866 8,316 1,860 1,906 1,314

3.42 0.25 BDL 329,507 145,047 76,219 44,805 62,284 12,119 7,087 904 7,928 4,374

4.27 0.25 BDL 324,100 143,630 76,913 45,235 64,148 12,150 7,682 1,676 9,739 5,123
4.04 0.25 BDL 317,192 144,533 77,677 44,579 66,191 11,740 7,505 2,699 10,292 5,351

DLL 0.68ADL 0.10 DLL 400,495 ADL 165,994 ADL 83,627 ADL 21,017 ADL 18,435 ADL 9,275 ADL 19,058 ADL

DLL 1.08ADL 0.18 DLL 400,495 ADL 163,028 ADL 81,752 ADL 19,510 ADL 17,827 ADL 8,893 ADL 19,624 ADL

DLL 0.52ADL 0.04 BDL 399,259 ADL 164,154 ADL 81,933 ADL 19,275 ADL 18,652 ADL 8,791 ADL 18,950 ADL

BDL 0.08 BDL 0.04 BDL 201,280 ADL 96,904 ADL 366 ADL 98,981 ADL 2.00 DLL 22,617 ADL 26,918 ADL

BDL 0.08 BDL 0.04 BDL 214,699 ADL 117,771 ADL 5,722 ADL 118,765 ADL 2.59 ADL 25,143 ADL 33,058 ADL

BDL 0.08 BDL 0.04 BDL 228,348 ADL 104,519 ADL 6,712 ADL 98,042 ADL 1.86 DLL 21,628 ADL 28,360 ADL**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 Form Approved OMB Control No. 2060- Approval Expires

590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)

0.53 BDL 37.5 3,085 7,884 269 321 94.0 183 228 146 269 47.9 0.53 BDL
0.54 BDL 35.7 3,099 8,103 265 310 91.5 178 222 141 263 47.0 0.54 BDL
0.55 BDL 34.5 3,182 8,335 277 327 96.6 188 233 149 277 49.8 0.55 BDL
0.53 BDL 90.9 6,159 8,323 604 840 239 487 604 365 701 121 19.09
0.54 BDL 92.4 7,003 9,746 686 959 278 563 694 415 811 139 23.61
0.54 BDL 88.3 5,851 7,772 579 813 253 479 582 359 686 130 21.54
0.52 BDL 52.8 2,113 6,670 134 54.8 54.8 99.3 158 44.5 185 19.7 0.52 BDL
0.51 BDL 90.2 2,306 7,190 154 73.0 71.0 127 198 73.0 228 25.3 0.51 BDL
0.49 BDL 108 2,104 6,652 147 81.7 74.9 133 193 81.7 220 27.2 0.49 BDL

4,489 4,708 7,597
4,351 5,557 7,944
4,197 5,330 7,665

1,481 ADL 4,112 ADL

1,441 ADL 3,943 ADL

1,367 ADL 4,001 ADL

5,141 ADL 3,967 ADL

6,041 ADL 4,773 ADL

5,304 ADL 4,243 ADL**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 Form Approved OMB Control No. 2060- Approval Expires

Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

7.14 16.49 1.16 77.0 11.0 116 5,456
6.40 15.30 1.09 80.3 10.4 115 5,704
6.85 16.12 1.10 90.4 11.0 121 5,936
159 40.6 6.29 10.2 26.7 257 12,948

171 46.9 7.73 11.6 31.4 292 14,457
178 43.2 6.57 11.4 28.3 283 13,356
2.07 6.21 0.52 BDL 2.07 6.21 44.5 2,636
13.2 8.11 3.04 3.04 8.11 52.7 3,023
3.89 8.76 2.92 3.89 8.76 53.5 3,097
1,814
1,785
1,861

59.6ADL 1,870

87.8ADL 1,929

71.4ADL 1,810

415ADL 6,700

440 ADL 7,407

381 ADL 6,958**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 Form Approved OMB Control No. 2060- Approval Expires

Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

Laboratory analysis standards for 2,3-Pentadiene and Cyclopentadiene were not available.**Fuel Gas Data**

**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 1
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 2
CA5A0280 Steam Power

Plant Mix drum for fuel

gas system 11045.2 8/15/2011 3
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/15/2011 1
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 2
CA5A0280 Unit 233 Mix drum for fuel gas system 11045.2 8/17/2011 3
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 1
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 2
CA5A0320 T-1201 Mix Drum for fuel gas 11084.5 8/8/2011 3
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 1
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 2
DE1A0360 Main Main Fuel gas line 454-83 7/13/2011 3

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 South Plant South Plant Fuel Gas Line 11-217 7/6/2011 3

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 1

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 2

IL2A0400 115/125 115/125 Fuel Gas Line 11-217 7/6/2011 3 Form Approved OMB Control No. 2060- Approval Expires

Other comments

Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+

Fixed Gas and Hydrocarbon analysis values have been nomalized to 100%**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd) LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 2994.442 1015.4 0 0.05 BDL 0.01 BDL 1.53 0.32 0.01 1 BDL 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 3000.098 1013.8 0 0.05 BDL 0.01 BDL 1.53 0.3 0.01 1 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3 3002.448 1014.4 0 0.05 BDL 0.01 BDL 1.52 0.34 0.01 1 BDL 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1 72,290 968ADL 3.12ADL 21.1ADL 0.35ADL 0.20ADL 5.57ADL 0.81ADL 84.5 29.1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2 77,171 1003ADL 2.95ADL 19.7ADL 0.34ADL 0.21ADL 5.5ADL 0.8ADL 82.9 26.3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3 77,331 1006ADL 2.78ADL 18.7ADL 0.35ADL 0.21ADL 5.64ADL 0.77ADL 171 28.0

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1 710 No major units down 1201 2.50 43.3 0.02 BDL 0.04 1.18 0.6 1.00 BDL 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2 682 No major units down 1126 2.71 45.0 0.02 BDL 0.03 1.14 0.61 1.00 BDL 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3 668 No major units down 1146 2.78 44.7 0.02 BDL 0.03 1.23 0.58 5.17 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1 28,030 No major units down 1,131 2.93 27.6 3.99 0.18 6.32 0.43 106 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2 28,298 No major units down 100 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3 27,850 No major units down 1,128 2.52 23.6 4.28 0.23 11.0 1.70 65 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1 52,256 No major units down 906 2.51 33.0 0.45 0.02 BDL 4.98 0.72 144 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2 51,433 No major units down 963 2.62 34.3 0.57 0.03 2.63 0.18 192 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3 52,331 No major units down 931 2.68 34.2 0.65 0.03 2.95 0.23 183 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1 56,107 972ADL 2.99ADL 26.5ADL 0.21ADL 0.26ADL 1.41ADL 0.05 DLL 5.46 BDL 1.58

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2 56,251 931ADL 2.76ADL 27.1ADL 0.20ADL 0.25ADL 1.30ADL 0.04 DLL 2.40 BDL 0.13

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 56,076 940 0 2.80ADL 26.3ADL 0.19 DLL 0.24ADL 1.34ADL 0.05 DLL 2.75 BDL 0.13**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd) BDL 1 BDL 1 BDL 960300 15400 100 BDL 100 BDL 3000 100 BDL 10 BDL 600 700 100 BDL 100 BDL 100 BDL

1 BDL 1 BDL 962000 14200 100 BDL 100 BDL 3000 100 BDL 10 BDL 600 600 100 BDL 100 BDL 100 BDL BDL 1 BDL 1 BDL 960600 15200 100 BDL 100 BDL 3000 100 BDL 10 BDL 600 700 100 BDL 100 BDL 100 BDL

ADL 29.1ADL 0 BDL 460,563 ADL 123,017 ADL 54,497 ADL 32,173 ADL 13,443 ADL 8,168 ADL 13,163 ADL

ADL 27.6ADL 0 BDL 457,321 ADL 142,117 ADL 52,215 ADL 34,149 ADL 12,838 ADL 7,884 ADL 12,725 ADL

ADL 28.3ADL 0 BDL 467,784 ADL 140,644 ADL 52,288 ADL 34,755 ADL 12,649 ADL 7,549 ADL 12,533 ADL

BDL 1 BDL 1 BDL 254,910 144,550 1,683 29,573 4,990 15,574 65,364

BDL 1 BDL 1 BDL 247,965 140,513 1,614 30,128 4,901 13,134 62,427

BDL 1 BDL 1 BDL 250,749 144,399 1,582 34,035 5,304 10,595 58,130

BDL 1 BDL 1 BDL 527,280 22,069 5,709 17,717 21,406 3,494 8,122

BDL 1 BDL 1 BDL

BDL 1 BDL 1 BDL 504,834 20,149 6,828 20,254 24,360 2,782 4,679

BDL 1 BDL 1 BDL 381,717 101,255 12,446 69,140 13,345 5,337 12,116

BDL 1 BDL 1 BDL 364,003 114,295 14,490 79,060 16,437 5,700 13,742

BDL 1 BDL 1 BDL 377,276 101,651 14,884 71,279 17,130 6,149 15,224

ADL 0.27ADL 0.05 BDL 488,609 ADL 123,039 ADL 36,959 ADL 42,271 ADL 7,512 ADL 12,581 ADL 11,918 ADL

BDL 0.09 BDL 0.05 BDL 495,681 ADL 128,493 ADL 34,117 ADL 41,767 ADL 7,556 ADL 13,162 ADL 11,538 ADL

BDL 0.09 BDL 0.05 BDL 500,000 ADL 108,940 ADL 33,623 ADL 41,824 ADL 7,327 ADL 11,341 ADL 11,539 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd) 10 BDL 100 BDL 200 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 100 BDL 200 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 100 BDL 200 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL

1,935 ADL 8,246 ADL

2,449 ADL 8,276 ADL

2,382 ADL 8,224 ADL
3,662 8,806
3,628 8,015
3,378 7,557
2,068 2,575

615 1,768
1,522 5,858
1,791 6,579
1,848 7,155

2,853 ADL 5,826 ADL

2,968 ADL 5,619 ADL

2,514 ADL 5,503 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 110 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 100 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 10 BDL 100

80.0ADL 3,557

125ADL 3,633

120ADL 3,608

411 19,605

400 19,503

386 18,772

316 4,194 1Air in test sample. Data not valid so not included.

274 3,371

324 5,968

354 6,700

305 7,274

69.4ADL 2,783

64.2ADL 2,716

65.7ADL 2,728**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294)

3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294) 3The labs were granted permission to report non-alkane compounds as a total based on the response of the alkanes (Appendix H). Results are available in report summary (pgs. EM-BRRF-00287 through EM-BRRF-00294)**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 1 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 2 LA3C0520 H-501 H-501 Fuel Gas 611191 09/06/2011 3

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 1

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 2

LA3C0560 339 Mix Drum for Fuel Gas System F2 142753 5/18/2011 3

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 1

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 2

LA3C0590 D-810 ICN EM-BRRF-0281- 1460 6/29/2011 3

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 1

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 2

LA3C0590 D-1A HPBL EM-BRRF-0281- 1460 6/30/2011 3

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 1

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 2

LA3C0590 D-1 NSPS EM-BRRF-0281- 1460 8/3/2011 3

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 1

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 2

LA3C0610 Unti 43 Fuel Gas Line 11-236 7/15/2011 3 Other comments

Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+
CO and TRS are BDL. There is not coker gas in this fuel gas. CO and TRS are BDL. There is not coker gas in this fuel gas. CO is BDL. There is not coker gas in this fuel gas. There is coker gas in this fuel gas. There is coker gas in this fuel gas. There is coker gas in this fuel gas. CO2 is BDL. There is coker gas in this fuel gas. There is coker gas in this fuel gas. There is coker gas in this fuel gas. Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+ Unidentified C2 as Ethane is assigned to Ethylene -Unidentified C3 as Propane is assigned to Propylene -Unidentified C4 as Butane is assigned to 1-Butene -Unidentified C5 as Pentane is assigned to 1-Pentene -Unidentified C6 Hexane & C7 as Heptane is assigned to Other C6+**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679) 1,795 8,153 8,064 Due to the Silvertip Pipeline spill incident on July 3, 2011, the refinery has operated at reduced rates along with abnormal feeds to the process units. Therefore, the fuel gas sampling performed on July 6, 2011, is not representative of normal operations. 1,012 1.14 23.9 0.57 0.02 BDL 5.67 0.51 46.4 DLL 0.61

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686) 1,773 8,083 7,996 Due to the Silvertip Pipeline spill incident on July 3, 2011, the refinery has operated at reduced rates along with abnormal feeds to the process units. Therefore, the fuel gas sampling performed on July 6, 2011, is not representative of normal operations. 985 1.12 24.6 0.57 0.02 5.81 0.56 50.7 DLL 0.57

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687) 1,818 8,167 8,069 Due to the Silvertip Pipeline spill incident on July 3, 2011, the refinery has operated at reduced rates along with abnormal feeds to the process units. Therefore, the fuel gas sampling performed on July 6, 2011, is not representative of normal operations. 983 1.16 24.3 0.56 0.02 BDL 5.73 0.57 52.2 DLL 0.58
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 11,380 9,381 9,381 881 0 25.5 0.57 0.04 BDL 11.3 0.14 DLL 0.94 BDL 0.49
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2 1,358 9,185 9,185 877 0 25.8 0.61 0.04 BDL 11.1 0.11 DLL 0.56 BDL 0.12
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3 1,368 9,256 9,256 868 0 24.8 0.55 0.11 BDL 11.3 0.86 DLL 0.56 BDL 0.12

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1 3,797 21,535 21,535 886 0 38.2 0.26 DLL 0.09 BDL 6.24 0.29 DLL 27.8 DLL 25.1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2 3,781 21,555 21,555 903 0 38.8 0.25 DLL 0.09 BDL 5.85 0.21 DLL 22.2 DLL 20.0

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 3,773 21,575 21,575 849 0 37.5 0.25 DLL 0.09 BDL 8.71 1.21 25.3 DLL 22.7 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 82.7 344.2 344.2 933.9 0 23 0.4 4.6 8.9 1.9 36.11 DLL 35.41 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 84.87 353.2 353.2 982.9 0 24.1 0.4 5.1 5.5 1.2 32.75 DLL 38.56 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3 87.54 364.3 364.3 937.2 0 23 0.5 4.7 7.7 1.8 40.45 DLL 34.58
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1 1718.22 7517.2 7517.2 1031.9 0 26.2 0.8 1.6 6.1 1.4 38.87 DLL 37.76

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 1578.79 6994.1 6994.1 1013.9 0 25.7 0 1.6 5.4 1.1 44.08 DLL 40.73 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 1581.7 6913.6 6913.6 996.7 0 25.7 0 1.5 6.6 1.4 38.26 DLL 35.42**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687)

NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 1
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

DLL 0.87 0.02 BDL 358,000 140,133 79,478 47,877 35,882 7,929 13,120

DLL 0.87 0.02 BDL 350,000 128,300 78,505 47,487 35,254 8,170 13,284

DLL 0.86 0.02 BDL 345,000 130,702 77,790 47,773 35,115 8,431 13,535

DLL 0.08 BDL 0.05 BDL289,000 168,654 102,787 8,745 37,672 457 3,502

BDL 0.08 BDL 0.05 BDL 293,000 159,788 113,819 8,270 34,174 348 2,716

BDL 0.08 BDL 0.05 BDL 287,000 182,189 103,282 6,460 28,620 230 1,881

0.89 0.05 BDL 244,000 122,794 53,106 47,929 19,599 3,042 15,546

0.64 0.05 BDL 244,000 129,271 53,866 47,170 21,076 3,179 15,523

0.66 0.05 BDL 239,000 123,731 51,265 46,513 16,315 2,815 14,523 0.25 BDL 0.25 BDL 382257 91310 62414 0 21198 47029 0 3576 0 4445 8838 4429 0.25 BDL 0.25 BDL 393512 96866 62838 0 22709 49136 0 3617 7268 3450 8240 3947 0.25 BDL 0.25 BDL 392668 95303 63870 0 19250 45675 0 3571 7044 2477 3936 0
0.25 BDL 0.25 BDL 368251 114642 62340 0 36695 49309 0 3695 7283 4594 8906 4550

0.25 BDL 0.25 BDL 394246 103434 60216 0 36620 48718 0 3141 7150 1979 3426 0
0.25 BDL 0.25 BDL 390279 104268 57747 0 36543 42248 0 1929 6742 0 6593 3880**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687)

NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 1
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)

469 3,023

452 2,900

465 2,946
22.6 486

13.8 298
10.4 238

2,467 14,450

2,517 14,555

2,003 11,241 0 1183 72 582 0 0 0 0 0 0 0 0 0 0 1239 101 580 0 0 0 0 0 0 0 0 0 0 1155 96 462 0 0 0 0 0 0 0 0 0 0 1245 139 637 0 0 0 0 0 0 0 0 0

0 1159 165 562 0 0 0 0 0 0 0 0 0
0 1032 140 485 0 0 0 0 0 0 0 0 0**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687)

NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 1
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

36.0 1,743 Used FAQ Test 006 - to calculate moisture by stoichiometric calculations. Used FAQ Test 026 - for sampling with Silonite coated steel containers and suma canisters. Used refinery instrumentation (i.e.,orifice plate) to calculate fuel gas flow rate (approved by Gerri Garwood of EPA in email dated 6/14/11).

35.4 1,730 Used FAQ Test 006 - to calculate moisture by stoichiometric calculations. Used FAQ Test 026 - for sampling with Silonite coated steel containers and suma canisters. Used refinery instrumentation (i.e.,orifice plate) to calculate fuel gas flow rate (approved by Gerri Garwood of EPA in email dated 6/14/11).

35.5 1,653 Used FAQ Test 006 - to calculate moisture by stoichiometric calculations. Used FAQ Test 026 - for sampling with Silonite coated steel containers and suma canisters. Used refinery instrumentation (i.e.,orifice plate) to calculate fuel gas flow rate (approved by Gerri Garwood of EPA in email dated 6/14/11).
0.48 BDL 43.7 BDL
0.50 BDL 12.2 BDL
1.18 BDL 12.3 BDL

48.3 2,794

55.0 2,951

46.8 2,373 0 0 0 0 0 0 0 0 1371 0 0 0 0 0 0 0 0 1430 0 0 0 0 0 0 0 0 1413 0 0 0 0 0 0 0 0 1419

0 0 0 0 0 0 0 0 1439
0 0 0 0 0 0 0 0 1428**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687)

NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 1
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

Used FAQ Test 003 - Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as ethane assumed to be ethylene, C3 as propane assumed to be propylene, C4 as butane assumed to be 1-butene, and C5 as pentane assumed to be 1-pentene. Hexane, C6 as hexane, heptane, and C7 as heptane were summed and reported as "other C6+" (Hexane=50.4, C6 as Hexane=509, Heptane=55.3, C7 as Heptane=1128). Used FAQ Test 027 -to measure and calculate TRS (measured as sulfur) with the following sulfur compounds (H2S=0.61, COS=0.873, CS2=<0.0225, MeSH=<0.088, others as MeSH=39.7, DMS=<0.06, DMDS=2.50)

Used FAQ Test 003 - Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as ethane assumed to be ethylene, C3 as propane assumed to be propylene, C4 as butane assumed to be 1-butene, and C5 as pentane assumed to be 1-pentene. Hexane, C6 as hexane, heptane, and C7 as heptane were summed and reported as "other C6+" (Hexane=50.1, C6 as Hexane=502, Heptane=54.6, C7 as Heptane=1123). Used FAQ Test 027 -to measure and calculate TRS (measured as sulfur) with the following sulfur compounds (H2S=0.57, COS=0.872, CS2=<0.0225, MeSH=3.34, others as MeSH=40.1, DMS=<0.06, DMDS=2.86)

Used FAQ Test 003 - Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as ethane assumed to be ethylene, C3 as propane assumed to be propylene, C4 as butane assumed to be 1-butene, and C5 as pentane assumed to be 1-pentene. Hexane, C6 as hexane, heptane, and C7 as heptane were summed and reported as "other C6+" (Hexane=50.9, C6 as Hexane=504, Heptane=54.3, C7 as Heptane=1044). Used FAQ Test 027 -to measure and calculate TRS (measured as sulfur) with the following sulfur compounds (H2S=0.58, COS=0.864, CS2=<0.0225, MeSH=<0.088, others as MeSH=41.1, DMS=<0.06, DMDS=4.71) For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen, C6 as hexane, and hydrogen sulfide. For Run 2 the following results are between the detection limit and the quantifiable limit: oxygen and C6 as hexane. For Run 3 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, pentane, C6 as hexane, and C7 as heptane.

For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen and carbon monoxide.

For Run 2 the following results are between the detection limit and the quantifiable limit: oxygen and carbon monoxide.

For Run 3 the following results are between the detection limit and the quantifiable limit: carbon monoxide. For Test Report 0611- 75: Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported by laboratory as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system ExxonMobil

Billings Refinery Fuel Gas Sampling Report 7/6/2011 Run #1: (Canister #1011 and Vessel #1679)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #2: (Canister #1358 and Vessel #1686)

MT4A790 D-934 Mix drum for entire refinery-wide fuel gas system Fuel_Gas_Samp

ling Report 7/6/2011 Run #3: (Canister #1601 and Vessel #1687)

NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 1
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 2
NJ1A0850 FGBW D-9 Sweet Gas Drum 0611-75 6/28/2011 3

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 1

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 2

NJ1A0850 CNHBWT602, DSU-1- T101, DSU-2- T403, DSU-2- T-403 D-10 Sour Gas

Drum 0611-75 6/28/2011 3 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9422 Plant 9-4 RFG K.O. 781-105-R1 07/19/2011 3
OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 1

OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-9307 Plant 9-2//9-3 RFG K.O. 781-105-R1 07/20/2011 3 Other comments

H2S has results between the detection limit and the quantifiable limit. CO2 and carbonyl sulfide are below detection limits. Refer to Test Report for procedures used, measurements made, standards used, and/or statistical procedures for analytical data reported from the lab as "nondetect" or "below detection level." This fuel gas includes gas from a coking unit.

H2S and CO2 has results between the detection limit and the quantifiable limit. Carbonyl sulfide is below detection limit. Refer to Test Report for procedures used, measurements made, standards used, and/or statistical procedures for analytical data reported from the lab as "nondetect" or "below detection level." This fuel gas includes gas from a coking unit. H2S has results between the detection limit and the quantifiable limit. CO2 and carbonyl sulfide are below detection limits. Refer to Test Report for procedures used, measurements made, standards used, and/or statistical procedures for "nondetect" or "below detection level."
CO2 is below detection limit. This fuel gas includes gas from a coking unit.

Analysis condcuted following ICR FAQ Test-003 Q: What changes can I make from the ICR for sampling and analysis of the compounds on Table 1.6 of Component 4? A: Table 1.6 of Component 4 of the ICR requires testing for the C1 through C5 Hydrocarbons (HCs). You may still use Method 18 to obtain this information; however, we are aware that some of the standards for these compounds are either unavailable are hard to obtain in a timely fashion. As an alternative, we will accept data collected using the RCRA Risk Burn Guidance procedure for measuring total organics with BP <100 (C1-C7 HCs), referred to as the Field Gas Chromatography (FGC) fraction of Total Organic Emissions or TOE. Information and the procedure can be found at the following links: http://www.epa.gov/wastes/hazard/tsd/td/combust/pdfs/burn.pdf - FGC described (Section 5.1.4 ~ p108) ANDhttp://www.epa.gov/wastes/hazard/tsd/td/combust/pdfs/apxb0927.pdf - FGC procedure (Section B-7 ~ p78). Report the data collected using this procedure as described in the Risk Burn Guidance procedure for FGC analysis.**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd) OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 429.49 1224.8 1224.8 977.5 0 24.8 0.4 3.7 5.7 1.2 33.65 DLL 29.84 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 438.96 1251.8 1251.8 969.6 0 23.4 0.4 4.6 6.6 1.5 35.53 DLL 34.04 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 435.56 1242.1 1242.1 966.4 0 25.7 0.5 4.9 6.4 1.3 39.92 DLL 36.31 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 4070.16 16368.2 16368.2 988.9 0 31.9 0.5 4.2 7.5 1.7 60.66 DLL 59.67 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 3957.8 15865.7 15865.7 1026.7 0 33.1 0.6 1.4 6.1 1.2 52 DLL 48.84 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3 3976.3 15813.1 15813.1 999.9 0 31.4 0 1.4 6.7 1.3 48.57 DLL 44.52

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1 2,037 434ADL 0.07 0 78.4ADL 0.04 BDL 0.04 BDL 13.6 BDL 3.34 BDL 0.85 BDL 0.85

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2 2,028 438ADL 0.13 0 78.7ADL 0.05 BDL 0.04 BDL 14.2 BDL 3.60 BDL 0.89 BDL 0.89

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3 2,027 443ADL 0.07 0 78.6ADL 0.04 BDL 0.04 BDL 13.2 BDL 3.33 BDL 0.83 BDL 0.83

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1 3,166 689ADL 0.20 0 52.9ADL 0.05ADL 0.24ADL 13.7 BDL 3.47 BDL 7,654 ADL 7,589

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2 2,738 692ADL 0.27 0 55.1ADL 0.06ADL 0.19ADL 13.5 BDL 3.41 BDL 8,450 ADL 8,356

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3 2,954 684ADL 0.27 0 56.4ADL 0.05ADL 0.17ADL 13.7 BDL 3.45 BDL 5,295 ADL 5,234

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1 6,716 709 ADL 0.33 0 52.5ADL 0.06ADL 0.24ADL 12.9 BDL 3.25 BDL 7,937 ADL 7,844

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2 6,826 714 ADL 0.27 0 53.7ADL 0.05ADL 0.21ADL 12.7 BDL 3.21 BDL 7,664 ADL 7,565

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3 6,847 697 ADL 0.27 0 55.4ADL 0.05ADL 0.18ADL 13.0 BDL 3.29 BDL 7,942 ADL 7,851

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1 1,832 839 ADL 0.27 0 57.8ADL 0.04 BDL 0.04 BDL 12.6 BDL 3.19 BDL 1,850 ADL 1,846

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2 2,947 841 ADL 0.27 0 57.7ADL 0.04 BDL 0.04 BDL 12.5 BDL 3.17 BDL 1,724 ADL 1,720

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3 2,917 603 ADL 0.27 0 43.6ADL 0.06 BDL 0.06 BDL 30.6ADL 4.77 BDL 1,102 ADL 1,100

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1 1,721 630 ADL 0.19 0 54.5ADL 0.04 BDL 0.12ADL 12.7 BDL 3.21 BDL 8,301 ADL 8,224

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2 1,713 631 ADL 0.16 0 58.4ADL 0.04 BDL 0.28ADL 12.0 BDL 3.03 BDL 9,970 ADL 9,906

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 1,717 596 ADL 0.16 0 54.2ADL 0.04 BDL 0.35ADL 12.5 BDL 3.15 BDL 6,996 ADL 6,964**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd) 0.25 BDL 0.25 BDL 402638 98008 62366 0 21165 45607 0 3626 2393 4116 8719 4380 0.25 BDL 0.25 BDL 393385 95437 62848 0 21561 49080 0 3645 7303 2462 6820 2521 0.25 BDL 0.25 BDL 348051 106673 69981 0 23999 53556 0 3677 7454 2036 4538 409 0.25 BDL 0.25 BDL 248069 127518 74936 0 38721 57639 0 3760 7959 4644 9166 4745 0.25 BDL 0.25 BDL 242681 134811 79254 0 47694 61275 0 3665 8315 1904 4232 384 0.25 BDL 0.25 BDL 288444 121756 70508 0 43411 51815 0 2552 7728 0 7155 0

BDL 0.85 BDL 0.85 BDL 75,300 ADL 51,948 ADL 1,701 BDL 8.51 BDL 24,484 ADL 851 BDL 595 BDL 851 BDL 434 BDL

BDL 0.89 BDL 0.89 BDL 77,036 ADL 51,747 ADL 1,782 BDL 8.91 BDL 24,909 ADL 891 BDL 624 BDL 891 BDL 455 BDL

BDL 0.83 BDL 0.83 BDL 78,148 ADL 52,355 ADL 1,651 BDL 8.26 BDL 26,040 ADL 826 BDL 578 BDL 826 BDL 421 BDL

ADL 0.86 BDL 0.86 BDL 242,279 ADL 85,967 ADL 4,096 ADL 23.8 ADL 49,852 ADL 7,490 ADL 5,309 ADL 2,239 ADL 1,228 ADL

ADL 0.85 BDL 0.85 BDL 218,655 ADL 87,467 ADL 4,092 ADL 21.6 ADL 52,484 ADL 7,608 ADL 6,365 ADL 2,832 ADL 1,363 ADL

ADL 0.86 BDL 0.86 BDL 209,666 ADL 87,048 ADL 3,946 ADL 10.7 ADL 52,668 ADL 7,314 ADL 6,184 ADL 2,772 ADL 1,322 ADL

ADL 0.81 BDL 0.81 BDL 243,942 ADL 82,904 ADL 4,204 ADL 27.1 ADL 51,962 ADL 7,589 ADL 9,153 ADL 3,938 ADL 1,312 ADL

ADL 0.80 BDL 0.80 BDL 226,254 ADL 84,043 ADL 4,032 ADL 90.0 ADL 55,077 ADL 7,490 ADL 10,931 ADL 4,724 ADL 1,398 ADL

ADL 0.82 BDL 0.82 BDL 215,144 ADL 84,235 ADL 3,916 ADL 30.4 ADL 53,784 ADL 7,273 ADL 9,249 ADL 4,084 ADL 1,333 ADL

ADL 0.79 BDL 0.79 BDL 100,855 ADL 92,687 ADL 1,584 BDL 55.0 ADL 109,102 ADL 792 BDL 26,488 ADL 24,789 ADL 404 BDL

ADL 0.79 BDL 0.79 BDL 97,806 ADL 92,252 ADL 1,574 BDL 22.9 ADL 110,538 ADL 787 BDL 26,595 ADL 25,607 ADL 401 BDL

ADL 1.18 BDL 1.18 BDL 82,533 BDL 64,875 ADL 2,366 BDL 11.8 BDL 77,998 ADL 1,183 BDL 19,126 ADL 18,088 ADL 604 BDL

ADL 0.80 BDL 9.07ADL 253,261 ADL 64,970 ADL 2,571 ADL 54.4 ADL 36,395 ADL 4,963 ADL 4,479 ADL 1,584 ADL 800 ADL

ADL 0.75 BDL 0.75 BDL 240,917 ADL 64,164 ADL 2,415 ADL 128 ADL 37,425 ADL 4,681 ADL 4,347 ADL 1,694 ADL 831 ADL

ADL 0.78 BDL 0.78 BDL 258,399 ADL 54,861 ADL 2,390 ADL 96.4 ADL 32,985 ADL 4,465 ADL 3,135 ADL 1,319 ADL 621 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd) 0 1247 122 609 0 0 0 0 0 0 0 0 0 0 1256 113 589 0 0 0 0 0 0 0 0 0 0 1314 124 548 0 0 0 0 0 0 0 0 0 0 1442 105 671 0 0 0 0 0 0 0 0 0 0 1456 74 638 0 0 0 0 0 0 0 0 0 0 1265 145 545 0 0 0 0 0 0 0 0 0

425 BDL 1,242 BDL 2,552 BDL 2,268 ADL

446 BDL 1,301 BDL 2,674 BDL 2,601 ADL

413 BDL 1,206 BDL 2,477 BDL 2,322 ADL

431 BDL 1,656 ADL 2,585 BDL 5,051 ADL

424 BDL 1,777 ADL 2,542 BDL 5,396 ADL

429 BDL 1,828 ADL 2,572 BDL 5,455 ADL

404 BDL 1,633 ADL 2,423 BDL 4,989 ADL

399 BDL 1,716 ADL 2,391 BDL 5,046 ADL

409 BDL 1,737 ADL 2,452 BDL 5,908 ADL

396 BDL 3,362 ADL 6,028 ADL 2,051 ADL

394 BDL 3,337 ADL 6,097 ADL 2,131 ADL

592 BDL 2,440 ADL 4,431 ADL 1,459 ADL

399 BDL 1,262 ADL 2,389 BDL 4,331 ADL

376 BDL 1,250 ADL 2,254 BDL 3,735 ADL

391 BDL 1,141 BDL 2,344 BDL 3,423 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments 0 0 0 0 0 0 0 0 1450 0 0 0 0 0 0 0 0 1427 0 0 0 0 0 0 0 0 1439 0 0 0 0 0 0 0 0 1450 0 0 0 0 0 0 0 0 1462 0 0 0 0 0 0 0 0 1451

29.5ADL 492 ADL

28.9ADL 741 ADL

30.8ADL 541 ADL

36.9ADL 756 ADL

36.9ADL 716 ADL

38.7ADL 736 ADL

40.4ADL 688 ADL

50.9ADL 691 ADL

79.6ADL 864 ADL

48.1ADL 609 ADL

48.1ADL 565 ADL

35.6ADL 318 ADL

47.9ADL 689ADL

43.0ADL 545ADL

33.8ADL 497ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 1 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 2 OH2A0940 V-9506 Plant 9-5 RFG K.O. 781-105-R1 07/19/2011 3 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 1 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 2 OH2A0940 V-436 V436 RFG K.O. 781-105-R1 07/20/2011 3

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 1

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 2

OK2C0980 Plat ABS-7112 Absorber Mix Drum 11HOLLYTO102- C 8/2/2011 3

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 1

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 2

OK2C0980 BH-5911 Boilerhouse Mix Drum 11HOLLYTO102-

E 8/3/2011 3

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 1

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 2

OK2C0980 CDU-1022 Crude Unit Mix Drum 11HOLLYTO102-

D 8/3/2011 3

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 1

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 2

OK2C0980 Plat/Unif3213 Platformer Mix

Drum 11HOLLYTO102-

B 8/2/2011 3

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 1

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 2

OK2C0980 LEU-8013 LEU Unit Mix Drum 11HOLLYTO102 8/1/2011 3 Other comments

-Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1 522 811 ADL 0.12 0 12.1ADL 0.04 BDL 0.50ADL 13.8 BDL 3.49 BDL 1,637 ADL 1,620

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2 519 844 ADL 0.16 0 0.20ADL 0.04 BDL 1.66ADL 11.5 BDL 2.91 BDL 0.72 BDL 0.72

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3 527 826 ADL 0.13 0 0.31ADL 0.04 BDL 1.59ADL 13.5 BDL 3.41 BDL 46.8ADL 45.6

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 24,992 963 28669.67213 900.327869 84.26 8973.0 0 0.0 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1448 2,056 2,039 640 0.84 47.0 0.25 0.05 9.23 0.09 19.6 BDL 10.3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2 454 2,031 2,014 534 0.84 37.0 0.24 0.05 21.2 3.45 22.3 BDL 9.48
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3 457 2,052 2,036 646 0.79 44.7 0.29 0.05 9.97 0.07 22.1 BDL 8.38

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1 106,382 188,538 179,424 105 4.83 13.9 16.2 9.79 57.9 0.78 208 6.65
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2 105,335 187,634 179,327 128 4.43 13.6 16.0 9.74 57.0 0.74 200 7.02
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3 105,037 188,964 181,928 107 3.72 13.6 15.9 9.81 57.0 0.75 210 6.96
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1 7,145 32,897 32,567 675 1.00 37.5 0.17 0.35 8.72 0.08 33.0 BDL 26.8

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2 7,346 33,639 33,270 662 1.10 36.9 0.17 0.33 8.80 0.07 40.4 BDL 31.0

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3 7,744 34,092 33,725 696 1.08 38.7 0.18 0.32 8.83 0.07 48.6 BDL 35.1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1 1,177 5,047 4,995 696 1.04 38.4 0.32 0.32 10.7 0.12 71.2 BDL 47.5

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2 1,188 5,193 5,142 680 0.97 39.6 0.32 0.32 10.3 0.07 67.6 BDL 40.2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3 1,127 4,935 4,888 713 0.94 39.6 0.32 0.32 8.38 0.08 64.8 BDL 37.6

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1 11,468 49,568 48,991 724 1.16 37.5 0.24 0.17 7.06 0.08 66.0 BDL 53.3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2 11,894 51,970 51,333 725 1.23 38.6 0.24 0.17 7.06 0.07 72.2 BDL 56.1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 11,484 49,070 48,525 767 1.11 34.7 0.22 0.32 6.25 0.06 62.0 BDL 53.9**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

ADL 0.87 BDL 0.87 BDL 731,114 ADL 44,720 ADL 1,732 BDL 14.9 ADL 14,398 ADL 1,532 ADL 1,680 ADL 866 BDL 442 BDL

BDL 0.72 BDL 0.72 BDL 909,853 ADL 14,577 ADL 1,442 BDL 7.21 BDL 2,236 ADL 721 BDL 505 BDL 721 BDL 368 BDL

ADL 0.85 BDL 0.85 BDL 889,599 ADL 14,666 ADL 1,692 BDL 8.46 BDL 2,624 BDL 846 BDL 593 BDL 846 BDL 432 BDL

32,847 12,064 8,856 - 2,460 2,442 230 242 99 252 43

0.10 BDL 0.05 BDL293,464 65,642 15,153 27,805 9,312 2,729 2,253
0.10 BDL 0.05 BDL 250,099 55,569 13,128 22,793 8,690 1,984 1,805
0.10 BDL 0.05 BDL 308,428 68,063 16,297 26,826 10,195 1,954 2,038

167 4.76 15,447 400 112 40.3 34.5 3.65 BDL 13.4

157 5.32 15,381 387 109 37.5 32.9 3.13 BDL 82.1
168 5.37 15,476 387 109 38.2 33.5 3.66 BDL 18.0
0.10 BDL 0.05 BDL 424,261 49,888 9,623 23,005 6,067 4,259 2,609

0.10 BDL 0.05 BDL 413,542 48,707 9,517 22,692 6,744 4,331 2,590

0.10 BDL 0.05 BDL 404,360 54,535 10,214 25,768 8,127 4,698 2,995

0.10 BDL 0.05 BDL 344,598 79,329 17,159 30,014 13,872 2,484 3,176

0.10 BDL 0.05 BDL 341,299 74,652 17,390 27,635 13,648 2,149 2,928

0.10 BDL 0.05 BDL 355,337 81,991 18,191 30,114 15,262 2,291 3,123

0.15 BDL 0.04 BDL 407,744 63,343 12,730 24,944 17,411 3,270 3,848

0.18 BDL 0.04 BDL 289,548 63,584 13,275 26,019 22,814 3,218 3,792

0.06 BDL 0.04 BDL 437,865 58,367 12,261 27,445 31,480 2,814 3,170**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)

434 BDL 1,265 BDL 2,598 BDL 1,354 ADL

361 BDL 1,053 BDL 2,163 BDL 95.2ADL

424 BDL 1,236 BDL 2,538 BDL 70.2ADL

- 194 574 9.180328

218 350
193 193
213 213

0.87 BDL 4.16 BDL
0.85 BDL 1540
0.67 BDL 45.1
1,052 1080

1,109 1080

1,148 1117

201 485

196 488

176 444

530 1,694

510 1,608

470 1,552**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

20.7ADL 390ADL

0.14 BDL 90.4ADL

1.40ADL 91.6ADL

288.9 271.00ADL 270.00ADL 281.00ADL
165 5,194 EQL

138 4,124

147 4,374

54.9 46.9 DLL

54.1 3,971 DLL
52.3 513 DLL
208 4,899

218 4,959

225 5,102

186 3,393

175 2,977

169 2,670

360 3,586

315 3,338

304 3,315**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table Unclear whether any of these values are above or below detection limit. Cis-butene and trans-butene combined and reported as 2-Butene on this table. ASTM D 1946-90 , with GC-FID ASTM D 1946-90 , with GC-FID ASTM D 1946-90 , with GC-FID For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen and carbon monoxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: carbon monoxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: oxygen and carbon monoxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 1 the following results are between the detection limit and the quantifiable limit: butane, pentane, hexane, C6 as hexane, and heptane. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: butane, pentane, hexane, and heptane. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: butane, hexane, C6 as hexane, and heptane. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, and carbon dioxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, carbon dioxide, and carbonyl sulfide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: oxygen, carbon monoxide, carbon dioxide, and carbonyl sulfide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: carbon monoxide, carbon dioxide, and carbonyl sulfide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Test Report 0611- 93: Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported by laboratory as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as ethane assumed to be ethylene, C3 as propane assumed to be propylene, C4 as butane assumed to be 1-butene, and C5 as pentane assumed to be 1-pentene. Hexane, C6 as hexane, For Test Report 0711- 01: Samples were analyzed for C1-C7 plus benzene according to RCRA Risk Burn Guidance procedure for FGC analysis and are reported by laboratory as follows:**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 1

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 2

OK2C0980 MEK-8131 MEK Unit Mix Drum 11HOLLYTO102- A 8/1/2011 3

PA1A1020 Fuel Gas Grab Sample Average 6/1/2011

through 7/31/2011 PA1A1020 Fuel Gas 47839 7/12/2011 1 PA1A1020 Fuel Gas 47839 7/12/2011 2 PA1A1020 Fuel Gas 47839 7/12/2011 3
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 1
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 2
TX3B1160 FXK RBG/D315 184381.0000.0 000 6/22/2011 3

TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 1
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 2
TX3B1160 FXK LBG 184381.0000.0 000 6/23/2011 3
TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 1

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 2

TX3B1160 HSK D853 184381.0000.0 000 6/24/2011 3

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 1

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 2

TX3B1160 DCU D616 184381.0000.0 000 6/24/2011 3

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 1

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 2

TX3B1160 UTIL D291 184381.0000.0 000 7/15/2011 3 Other comments -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result These values are the average of two months' worth of 3-hour averages (fuel gas flow rate) and daily grab samples (constituent concentrations). Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd

Run 2 was found to have had air in-leakage during sample collection. Results may not be valid.**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1 1,338 4,327 4,277 824 1.16 58.5 0.08 0.06 2.65 0.06 28.7 BDL 21.4
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2 1,586 4,833 4,753 794 1.65 57.0 0.11 0.06 2.81 0.06 36.5 BDL 30.4
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3 1,343 4,069 3,965 979 2.54 50.3 0.10 0.06 2.62 0.06 61.5 BDL 48.9

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1 2,119 8,565 8,473 861 1.08 0.61 0.06 1.70 0.70 0.06 3.63 BDL 0.10
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2 2,152 8,684 8,588 884 1.11 0.65 0.07 1.64 0.51 0.06 1.87 BDL 0.10
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3 2,182 8,803 8,705 892 1.11 0.60 0.06 1.61 0.56 0.05 0.96 BDL 0.10
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1 1,931 7,901 7,831 720 0.89 31.3 1.10 0.59 5.58 0.06 13.1 BDL 0.89
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2 2,061 8,203 8,086 638 1.42 30.5 1.77 0.54 12.6 2.00 15.0 BDL 4.64
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3 2,043 7,972 7,815 712 1.97 34.4 1.93 0.60 5.65 0.06 21.4 BDL 9.28

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1 8,995 35,600 35,600 922 0 19.2 0.70 1.30 3.60 1.30 39.7 22.0

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2 9,009 35,159 35,159 928 0 20.7 0.90 1.20 2.50 1.00 47.9 23.9

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3 9,217 36,183 36,183 928 0 19.4 0.90 1.30 2.50 1.00 38.5 17.9

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1 15,453 1,214 8630ADL 750 ADL 30 ADL 90 ADL 20 ADL 45 ADL 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2 15,453 1,232 8570ADL 740 ADL 30 ADL 90 ADL 20 ADL 16 ADL 1

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3 15,453 1,226 8690ADL 730 ADL 20 ADL 110 ADL 20 ADL 94 ADL 1

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1 2,826 1192.9 45860 ADL 110 ADL 90 ADL 1920 ADL 60 ADL 3 ADL 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2 2,826 1165.5 46130 ADL 130 ADL 100 ADL 1090 ADL 20 ADL 2 ADL 1

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 2,826 1423.2 38260 ADL 130 ADL 20 ADL 580 ADL 10 ADL 4 ADL 1**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

0.06 BDL 0.04 BDL 217,522 59,974 5,540 21,347 12,793 4,218 22,052
0.07 BDL 0.04 BDL 233,859 58,766 7,769 21,925 10,982 4,995 24,505
0.07 BDL 0.04 BDL 251,387 61,765 9,428 22,245 19,613 10,549 60,264

BDL 0.56 0.04 BDL 911,839 19,209 20.4 2,967 0.76 BDL 649 740

BDL 0.06 BDL 0.04 BDL 946,505 19,059 14.2 2,903 0.82 BDL 619 652

BDL 0.06 BDL 0.04 BDL 956,617 19,355 16.8 2,757 0.74 BDL 580 563

BDL 5.58 0.04 BDL 491,358 47,214 10,927 16,715 11,941 2,879 3,086

0.56 0.04 BDL 424,036 41,457 10,383 14,604 10,873 2,440 2,702
0.24 BDL 0.04 BDL 473,333 47,323 11,010 17,089 12,233 2,768 3,078

0.67 0.25 BDL 608,133 83,405 8,655 7,123 3,912 5,080 2,868 1,224 1,438 1,111

1.61 0.25 BDL 598,047 87,670 9,625 9,086 4,713 3,969 1,691 550 656 802

0.82 0.25 BDL 617,812 85,559 8,612 8,366 4,041 3,585 1,463 550 1,187 594

BDL 61930 ADL 19570 ADL 2400 ADL 1 BDL 2940 ADL 1770 ADL 1 BDL 690 ADL 220 ADL 250 ADL 220 ADL 0.22 ADL

BDL 60570 ADL 20100 ADL 2370 ADL 1 BDL 3610 ADL 2050 ADL 1 BDL 670 ADL 220 ADL 240 ADL 310 ADL 0.23 ADL

BDL 60970 ADL 19600 ADL 2320 ADL 1 BDL 3690 ADL 2030 ADL 1 BDL 660 ADL 220 ADL 240 ADL 310 ADL 0.23 ADL

BDL 16990 ADL 13260 ADL 980 ADL 1 BDL 9900 ADL 110 ADL 4 ADL 4200 ADL 2960 ADL 80 ADL 690 ADL 0.09 ADL

BDL 17800 ADL 12940 ADL 1960 ADL 1 BDL 8740 ADL 380 ADL 1 BDL 4060 ADL 2670 ADL 80 ADL 1570 ADL 0.01 ADL

BDL 18020 ADL 14740 ADL 40 ADL 1 BDL 12020 ADL 130 ADL 1 BDL 7260 ADL 4530 ADL 130 ADL 550 ADL 0.16 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)
2,333 24,037
1,082 17,817
880 23,518

176 391
161 309
150 269
662 2,230
612 2,345
675 2,500

272 1,588 1,948 500 BDL

301 1,964 2,426 500 BDL

228 1,573 1,997 500 BDL

1 BDL 10 ADL 70 ADL 1 BDL 33 ADL 1 BDL 1 BDL 28 ADL 1 BDL 1 BDL

1 BDL 8 ADL 30 ADL 1 BDL 26 ADL 1 BDL 1 BDL 35 ADL 1 BDL 1 BDL

1 BDL 7 ADL 20 ADL 1 BDL 39 ADL 1 BDL 1 BDL 35 ADL 1 BDL 1 BDL

1 BDL 6 ADL 810 ADL 6 ADL 24 ADL 1 BDL 1 BDL 49 ADL 1 BDL 1 BDL

1 BDL 1 BDL 720 ADL 8 ADL 10 ADL 1 BDL 1 BDL 6 ADL 1 BDL 1 BDL

1 BDL 1 BDL 1070 ADL 8 ADL 5 ADL 1 BDL 1 BDL 5 ADL 1 BDL 1 BDL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

737 26,753
690 22,490
879 28,358

80.4 2,096
46.1 940
38.1 658
306 2,180
296 2,424
292 2,878

500 BDL 1,589 For Method 15: no sample dilution required and USEPA Protocol standard cal gases used to calibrate GC. Method 4 not used due to safety concerns.

500 BDL 1,635 For Method 15: no sample dilution required and USEPA Protocol standard cal gases used to calibrate GC. Method 4 not used due to safety concerns.

500 BDL 1,576 For Method 15: no sample dilution required and USEPA Protocol standard cal gases used to calibrate GC. Method 4 not used due to safety concerns.

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 32 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 45 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 45 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments For Run 1 the following results are between the detection limit and the quantifiable limit: carbon monoxide and hydrogen sulfide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 2 the following results are between the detection limit and the quantifiable limit: carbon monoxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS. For Run 3 the following results are between the detection limit and the quantifiable limit: carbon monoxide. Hydrogen Sulfide concentrations obtained from 40 CFR 60 Subpart J – facility H2S CMS.

For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen. For Run 2 the following results are between the detection limit and the quantifiable limit: nitrogen. For Run 3 the following results are between the detection limit and the quantifiable limit: nitrogen. For Run 1 the following results are between the detection limit and the quantifiable limit: oxygen and hydrogen sulfide. For Run 2 the following results are between the detection limit and the quantifiable limit: carbon dioxide. For Run 3 the following results are between the detection limit and the quantifiable limit: oxygen and carbonyl sulfide.

For Method 15: no citrate buffer needed to scrub out SO2 and a recovery study was performed per Method 18.

For Method 15: no citrate buffer needed to scrub out SO2 and a recovery study was performed per Method 18.

For Method 15: no citrate buffer needed to scrub out SO2 and a recovery study was performed per Method 18. laboratory as follows: Ethane, C2 as ethane, propane, C3 as propane, butane, C4 as butane, pentane, C5 as pentane, hexane, C6 as hexane, benzene, heptane, and C7 as heptane. Alkenes reported as carbon number do not include alkanes. C2 as ethane assumed to be ethylene, C3 as propane assumed to be propylene, C4 as butane assumed to be 1-butene, and C5 as pentane assumed to**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 1
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 2
TX3B1160 HU9 D301 184381.0000.0 000 7/16/2011 3

TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 1
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 2
TX3B1160 PS7 D714 184381.0000.0 000 7/16/2011 3
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 1
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 2
TX3B1160 PS3 T332 184381.0000.0 000 7/17/2011 3

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 1

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 2

TX3B1200 338D0408 Fuel Gas Mixing Pot ARI No. H866- 33 7/28/2011 3

VI6A1530 D8535 Coker

Fuel Gas D8535-1 Coker Fuel

Gas 111928-1 6/15/2011 1

VI6A1531 D8535 Coker

Fuel Gas D8535-2 Coker Fuel

Gas 111928-2 6/15/2011 2

VI6A1532 D8535 Coker

Fuel Gas D8535-3 Coker Fuel

Gas 111928-3 6/15/2011 3

VI6A1533 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-4 6/14/2011 1

VI6A1534 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-5 6/14/2011 2

VI6A1535 D905 West

Area 2 Fuel Gas D905-1 West Area 2

Fuel Gas 111928-6 6/15/2011 3 Other comments

Run 2 was found to have had air in-leakage during sample collection. Results may not be valid.

Analytical results for Other C6+ represent n-Hexane.

Analytical results for Other C6+ represent n-Hexane.

Analytical results for Other C6+ represent n-Hexane. Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1 502 1188.7 48720 ADL 90 ADL 110 ADL 1390 ADL 30 ADL 1 ADL 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2 502 1156.5 51200 ADL 90 ADL 40 ADL 450 ADL 20 ADL 1 ADL 1

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3 2,826 1451.1 40240 ADL 90 ADL 60 ADL 320 ADL 10 ADL 3 ADL 1

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1 1158.8 48590 ADL 100 ADL 40 ADL 1640 ADL 330 ADL 1 ADL 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2 1197 48570 ADL 100 ADL 30 ADL 540 ADL 60 ADL 2 ADL 1

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3 1389.4 39960 ADL 150 ADL 10 ADL 370 ADL 60 ADL 1 ADL 1

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1 23,946 2299.4 4930 ADL 40 ADL 100 ADL 760 ADL 20 ADL 36 ADL 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2 23,946 2281.6 5880 ADL 50 ADL 120 ADL 890 ADL 20 ADL 12 ADL 1

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3 23,946 2296.4 5860 ADL 40 ADL 100 ADL 780 ADL 30 ADL 6 ADL 1

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1 7,368 1345.6 24490 ADL 300 ADL 260 ADL 5220 ADL 950 ADL 11 ADL 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2 7,368 1169.1 20360 ADL 240 ADL 200 ADL 16890 ADL 4270 ADL 11 ADL 1

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 7,368 1420.9 25650 ADL 340 ADL 210 ADL 1980 ADL 50 ADL 32 ADL 1**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

BDL 15370 ADL 12670 ADL 250 ADL 1 BDL 9900 ADL 60 ADL 1 BDL 4710 ADL 3070 ADL 60 ADL 340 ADL 0.07 ADL

BDL 15490 ADL 12000 ADL 560 ADL 1 BDL 8960 ADL 320 ADL 1 BDL 4340 ADL 2850 ADL 70 ADL 330 ADL 0.07 ADL

BDL 15780 ADL 12990 ADL 30 ADL 1 BDL 10760 ADL 100 ADL 1 BDL 10350 ADL 6250 ADL 120 ADL 460 ADL 0.11 ADL

BDL 16050 ADL 12700 ADL 70 ADL 1 BDL 10110 ADL 60 ADL 1 BDL 4160 ADL 3010 ADL 70 ADL 370 ADL 0.07 ADL

BDL 16220 ADL 12920 ADL 170 ADL 1 BDL 10160 ADL 80 ADL 1 BDL 4680 ADL 3040 ADL 80 ADL 410 ADL 0.08 ADL

BDL 17450 ADL 14990 ADL 30 ADL 1 BDL 12250 ADL 120 ADL 1 BDL 6290 ADL 3850 ADL 130 ADL 540 ADL 0.13 ADL

BDL 4660 ADL 2320 ADL 1980 ADL 1 BDL 15090 ADL 52470 ADL 1 BDL 1990 ADL 6060 ADL 2530 ADL 3760 ADL 2.76 ADL

BDL 5190 ADL 2650 ADL 2300 ADL 1 BDL 14180 ADL 49770 ADL 1 BDL 1870 ADL 5880 ADL 2330 ADL 4510 ADL 2.68 ADL

BDL 4400 ADL 2270 ADL 1830 ADL 1 BDL 14840 ADL 51490 ADL 1 BDL 1830 ADL 5750 ADL 2340 ADL 4320 ADL 2.57 ADL

BDL 27240 ADL 15210 ADL 5200 ADL 1 BDL 8760 ADL 900 ADL 1 BDL 4940 ADL 3080 ADL 110 ADL 270 ADL 0.1 ADL

BDL 22120 ADL 12250 ADL 3960 ADL 1 BDL 7120 ADL 700 ADL 1 BDL 5060 ADL 2660 ADL 290 ADL 980 ADL 0.26 ADL

BDL 29140 ADL 15070 ADL 4310 ADL 1 BDL 8180 ADL 650 ADL 1 BDL 6440 ADL 2800 ADL 420 ADL 1770 ADL 0.35 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)

1 BDL 1 BDL 760 ADL 5 ADL 4 ADL 1 BDL 1 BDL 3 ADL 1 BDL 1 BDL

1 BDL 1 BDL 770 ADL 5.375 ADL 5 ADL 1 BDL 1 BDL 4 ADL 1 BDL 1 BDL

1 BDL 1 BDL 760 ADL 5.125 ADL 3 ADL 1 BDL 1 BDL 3 ADL 1 BDL 1 BDL

1 BDL 1 BDL 830 ADL 6.125 ADL 3 ADL 1 BDL 1 BDL 3 ADL 1 BDL 1 BDL

1 BDL 1 BDL 900 ADL 6.875 ADL 4 ADL 1 BDL 1 BDL 3 ADL 1 BDL 1 BDL

1 BDL 1 BDL 1180 ADL 9.125 ADL 4 ADL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 110 ADL 10 ADL 1 BDL 35 ADL 1 BDL 1 BDL 63 ADL 1 BDL 1 BDL

1 BDL 120 ADL 10 ADL 1 BDL 33 ADL 1 BDL 1 BDL 60 ADL 1 BDL 1 BDL

1 BDL 120 ADL 10 ADL 1 BDL 26 ADL 1 BDL 1 BDL 55 ADL 1 BDL 1 BDL

1 BDL 3 ADL 810 ADL 4.875 ADL 39 ADL 1 BDL 1 BDL 24 ADL 1 BDL 1 BDL

1 BDL 6 ADL 670 ADL 4.25 ADL 47 ADL 1 BDL 1 BDL 42 ADL 1 BDL 1 BDL

1 BDL 10 ADL 640 ADL 3.625 ADL 41 ADL 1 BDL 1 BDL 43 ADL 1 BDL 1 BDL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 28 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 31 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 22 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 34 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 36 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 53 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 20 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 16 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 12 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1536 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-7 6/14/2011 1

VI6A1537 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-8 6/14/2011 2

VI6A1538 D1110 West

Area 1 Fuel Gas D1110-1 West Area

1 Fuel Gas 111928-9 6/15/2011 3

VI6A1539 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-10 6/14/2011 1

VI6A1540 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-11 6/14/2011 2

VI6A1541 D2112 West

Area 2 Fuel Gas D2112-1 West Area

2 Fuel Gas 111928-12 6/15/2011 3

VI6A1542 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-13 6/14/2011 1

VI6A1543 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-14 6/14/2011 2

VI6A1544 D7939 FCCU

Fuel Gas D7939-1 FCCU Fuel

Gas 111928-15 6/14/2011 3

VI6A1545 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-16 6/14/2011 1

VI6A1546 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-17 6/14/2011 2

VI6A1547 D3307 East

Area 3 Fuel Gas D3307-1 East Area

3 Fuel Gas 111928-18 6/14/2011 3 Other comments Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date Enter the fuel gas flow rate or usage rates from measurement data, company records, or engineering analyses. Use 1 atm and 60°F as standard conditions. Enter the fuel gas higher heating value (HHV) content and general composition data Enter the sulfur compound composition data **Field:** Process Throughput or Production Rate CAS No. >> 1333-74-0 630-08-0 124-38-9 7727-37-9 7782-44-7 CAS No. >> 7783-06-4

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number Actual Fuel Gas Flow Rate (acfm) Standard

Fuel Gas Flow Rate (scfm) Dry Standard

Fuel Gas Flow Rate (dscfm) Production comment HHV (Btu/scf) Moisture

Content (vol%) Hydrogen

(vol%, dry basis) Carbon

monoxide (vol%, dry basis) Carbon

dioxide (vol%, dry basis) Nitrogen

(vol%, dry basis) Oxygen

(vol%, dry basis) TRS

(ppmvd) Hydrogen

sulfide (ppmvd)

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1 35,799 1583.4 22560 ADL 280 ADL 220 ADL 2740 ADL 300 ADL 10 ADL 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2 35,799 1482.7 22690 ADL 280 ADL 210 ADL 5320 ADL 1050 ADL 5 ADL 1

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3 35,799 1541.7 24010 ADL 320 ADL 200 ADL 1560 ADL 40 ADL 12 ADL 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1 803 980 ADL 0.50 ADL 9.41 ADL 1.96 EQL 1.19 EQL 15.7 ADL 2.95 BDL 16.2 DLL 15.1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2 758 980 ADL 0.53 ADL 9.46 ADL 1.97 EQL 1.21 EQL 15.1 ADL 2.81 BDL 16.5 DLL 15.4

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3 720 980 ADL 0.60 ADL 9.38 ADL 1.98 EQL 1.19 EQL 15.7 ADL 2.85 BDL 58.5 DLL 55.3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1 10,079 1,160 ADL 0.43ADL 16.5ADL 0.90ADL 0.60ADL 11.4ADL 2.75 BDL 358.1 DLL 353

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2 9,879 1,230 ADL 0.43ADL 15.9ADL 0.92ADL 0.56ADL 11.0ADL 2.77 BDL 48.0 DLL 44.1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3 9,961 1,200 ADL 0.47ADL 15.5ADL 0.92ADL 0.58ADL 12.1ADL 2.77 BDL 43.6 DLL 40.5

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1 3,729 460 ADL 0.40ADL 17.2ADL 0.25ADL 0.21ADL 45.0ADL 11.0ADL 0.68 BDL 0.68

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2 3,830 910 ADL 0.33ADL 41.3ADL 0.48ADL 0.34ADL 10.9 BDL 2.77 BDL 26.8 DLL 25.6

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3 3,717 990 ADL 0.37ADL 33.3ADL 0.57ADL 0.42ADL 11.0 BDL 2.79 BDL 27.5 DLL 26.0

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1 4,217 1,180 ADL 0.47 ADL 28.4ADL 0.03 BDL 0.22 ADL 10.7 BDL 2.71 BDL 33.1 DLL 6.96

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2 4,192 1,240 ADL 0.47 ADL 29.0 ADL 0.04 BDL 0.23 ADL 11.3 BDL 2.85 BDL 32.2 DLL 7.49

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 4,195 1,240 ADL 0.53 ADL 28.8 ADL 0.03 BDL 0.22 ADL 10.7 BDL 2.71 BDL 32.2 DLL 7.33**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 Enter the organic compound composition data 463-58-1 75-15-0 74-82-8 74-84-0 74-85-1 74-86-2 74-98-6 115-07-1 463-49-0 106-97-8 75-28-5 106-98-9 107-01-7 115-11-7 Carbonyl sulfide (ppmvd) Carbon

disulfide (ppmvd) Methane

(ppmvd) Ethane

(ppmvd) Ethylene

(ppmvd) Acetylene

(ppmvd) Propane

(ppmvd) Propylene

(ppmvd) Propadiene

(ppmvd) n-Butane

(ppmvd) Isobutane

(ppmvd) 1-Butene

(ppmvd) 2-Butene

(ppmvd) Isobutene

(ppmvd)

BDL 25230 ADL 13830 ADL 4800 ADL 1 BDL 7910 ADL 810 ADL 1 BDL 9030 ADL 3410 ADL 880 ADL 3190 ADL 0.78 ADL

BDL 24750 ADL 13600 ADL 4670 ADL 1 BDL 7730 ADL 800 ADL 1 BDL 8200 ADL 3240 ADL 790 ADL 3060 ADL 0.72 ADL

BDL 27210 ADL 14340 ADL 3960 ADL 1 BDL 7800 ADL 600 ADL 1 BDL 8860 ADL 2850 ADL 880 ADL 3940 ADL 0.74 ADL

ADL 1.03 ADL 0.73 BDL 354,775 ADL 142,332 EQL 136,889 EQL 14.7 BDL 12,276 ADL 55,894 EQL 1,339 ADL 8,221 ADL 3,486 DLL 1,894 ADL

ADL 1.11 ADL 0.70 BDL 357,976 ADL 143,801 EQL 137,773 EQL 14.0 BDL 12,491 ADL 56,324 EQL 1,338 ADL 8,205 ADL 3,457 DLL 1,887 ADL

ADL 1.16 ADL 0.71 BDL 354,804 ADL 142,491 EQL 136,415 EQL 14.2 BDL 12,582 ADL 56,737 EQL 1,361 ADL 8,202 ADL 3,510 DLL 1,884 ADL

ADL 0.68 BDL 0.68 BDL 331,828 ADL 111,647 ADL 59,280 ADL 13.7 BDL 62,834 ADL 27,888 ADL 63,006 ADL 22,320 ADL 4,341 ADL 1,917 ADL

ADL 0.69 BDL 0.69 BDL 304,738 ADL 120,467 ADL 62,318 ADL 13.8 BDL 73,706 ADL 28,054 ADL 75,789 ADL 27,744 ADL 2,057 BDL 1,759 ADL

ADL 0.69 BDL 0.69 BDL 308,177 ADL 119,056 ADL 61,734 ADL 13.8 BDL 70,840 ADL 28,266 ADL 69,946 ADL 25,364 ADL 3,381 ADL 1,732 ADL

BDL 0.68 BDL 0.68 BDL 124,737 ADL 44,797 ADL 18,249 ADL 13.7 BDL 28,509 ADL 9,035 ADL 21,009 ADL 7,658 ADL 2,041 BDL 552 ADL

ADL 0.69 BDL 0.69 BDL 221,051 ADL 88,779 ADL 33,807 ADL 13.8 BDL 59,239 ADL 17,131 ADL 40,472 ADL 16,260 ADL 2,050 BDL 1,003 ADL

ADL 0.69 BDL 0.69 BDL 268,757 ADL 97,672 ADL 40,540 ADL 13.9 BDL 62,117 ADL 20,757 ADL 45,920 ADL 17,303 ADL 2,871 ADL 1,184 ADL

ADL 0.67 BDL 0.67 BDL 346,422 ADL 73,137 EQL 1,346 BDL 13.5 BDL 134,963 EQL 673 BDL 58,081 EQL 56,031 EQL 2,012 DLL 344 BDL

ADL 0.71 BDL 0.71 BDL 351,464 ADL 75,985 EQL 1,417 BDL 14.2 BDL 142,533 EQL 754 BDL 61,292 EQL 60,253 EQL 2,190 DLL 362 BDL

ADL 0.67 BDL 0.67 BDL 352,261 ADL 76,597 EQL 1,347 BDL 13.5 BDL 142,314 EQL 674 BDL 62,814 EQL 60,690 EQL 2,014 DLL 344 BDL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 590-19-2 106-99-0 109-66-0 78-78-4 287-92-3 109-67-1 627-20-3 646-04-8 563-46-2 563-45-1 513-35-9 142-29-0 591-95-7
1,2- Butadiene (ppmvd) 1,3-

Butadiene (ppmvd) n-Pentane

(ppmvd) 2-

Methylbutane (ppmvd) Cyclopentane

(ppmvd) 1-

Pentene (ppmvd) Cis-2-

pentene (ppmvd) Trans-2-

pentene (ppmvd) 2-Methyl-1-

butene (ppmvd) 3-Methyl-1-

butene (ppmvd) 2-Methyl2-butene (ppmvd) Cylcopentene

(ppmvd) 1,2-

Pentadiene (ppmvd)

1 BDL 10 ADL 710 ADL 4.75 ADL 52 ADL 1 BDL 1 BDL 59 ADL 1 BDL 1 BDL

1 BDL 10 ADL 660 ADL 4.625 ADL 50 ADL 1 BDL 1 BDL 58 ADL 1 BDL 1 BDL

1 BDL 20 ADL 570 ADL 25 ADL 44 ADL 1 BDL 1 BDL 70 ADL 1 BDL 1 BDL

367 BDL 1,071 BDL 2,201 BDL 419 ADL

350 BDL 1,020 BDL 2,096 BDL 362 ADL

355 BDL 1,035 BDL 2,128 BDL 395 ADL

341 BDL 3,826 ADL 14,661 ADL 7,842 ADL

344 BDL 4,531 ADL 16,307 ADL 6,529 ADL

345 BDL 4,325 ADL 15,554 ADL 7,022 ADL

341 BDL 1,418 BDL 5,272 ADL 2,704 ADL

344 BDL 2,810 ADL 11,001 ADL 4,915 ADL

346 BDL 2,687 ADL 11,384 ADL 5,592 ADL

337 BDL 3,170 ADL 4,269 ADL 2,980 ADL

355 BDL 3,351 ADL 4,643 ADL 2,703 ADL

337 BDL 3,534 ADL 4,849 ADL 3,245 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 Note any sample collection method deviations 1574-41-0 2004-70-8 591-93-5 591-96-8 598-25-4 78-79-5 542-92-7 71-43-2 Comments
1-cis-3- Pentadiene (ppmvd) 1-trans-3-

Pentadiene (ppmvd) 1,4-

Pentadiene (ppmvd) 2,3-

Pentadiene (ppmvd) 3-Methyl1,2- butadiene (ppmvd) 2-Methyl1,3- butadiene (ppmvd) Cyclopentadiene

(ppmvd) Benzene

(ppmvd) other C6+

(ppmvd) Sampling comments

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 24 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 18 ADL

1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 1 BDL 13 ADL

4.28 ADL 105 ADL

4.90 ADL 96 ADL

2.75 ADL 106 ADL

157ADL 417 ADL

133ADL 231 ADL

168ADL 171 ADL

125ADL 718 ADL

382ADL 385 ADL

305ADL 290 ADL

126 ADL 412 ADL

151 ADL 329 ADL

160 ADL 383 ADL**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 Note any analytical deviations Note any QA issues, such as unusal blanks

Analytical comments QA Comments

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table

-t-2-Butene & 1-Butene results are reported together and assigned to 1-Butene on this table**Instruction:** General source description, e.g., mix drum for X,Y,Z units; mix drum for Assign a unique

ID for each test report Enter start date **Field:**

Facility ID Number Fuel gas mix

drum ID General DescriptionTest Report ID Test Date (mm/dd/yyyy) Run

Number

VI6A1548 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-19 6/14/2011 1

VI6A1549 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-20 6/14/2011 2

VI6A1550 D3354 East

Area 3 Fuel Gas D3354-1 East Area

3 111928-21 6/14/2011 3

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 1

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 2

WA5A1430 ABS Fluid Catalytic Cracking (FCC) Absorber Fuel Gas System NW11CP106-A 5/23/2011 3

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 1

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 2

WA5A1430 Refinery Refinery Fuel Gas System NW11CP106-B 5/24/2011 3

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 1

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 2

WA5A1430 Reformer Reformer Unit Fuel Gas System NW11CP106-C 5/25/2011 3

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 1

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 2

WA5A1440 V-20 Tank V-20 fuel gas accumulator for the Refinery Fuel Gas System NW11USO105 5/18/2011 3 Other comments Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table Constituent concentrations provided in Mol%; values multiplied by 1000 to estimate concentrations in ppmvd. t-2-Butene & cis2-Butene results are reported together and assigned to 2-Butene on this table -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result -Unidentified C2-C6 as Pentane is assigned to 1-Pentene -Unidentified C7 as Heptane is assigned to Other C6+ -Not able to assign c-2-Butene result

# Instructions for Refinery Testing Supplement - Version 2 for Fuel Gas

**1) Fuel gas sampling data should be entered in the "FuelGas_Data-Version2" tab**  **2) Data should be entered into the white cells only; blue cells are intended for calculations**  **3) A list of pollutants, their CAS No./Pollutant Code, and their pollutant category are provided in the "Pollutants" tab**  **4) Guidance for process data to report is provided below:** 

**5) If your results are below detection limit then report your results as the detection limit with a less than (“<”) symbol in front of the value.**  **If your results are between the detection limit and the quantifiable limit (i.e., may be flagged with a “J”), then note in the appropriate comments column of the template which compounds have results between the detection limit and the quantifiable limit.**  **For fuel gas treatment sampling**, “throughput/production”is the quantity of fuel gas input to the unit. Throughput units are scfm; use 60 (15.56°C)and 1 atmosphere as “standard conditions” for fuel gas treatment.

## A list of pollutants, their CAS No./Pollutant Code, and their pollutant category are provided in the "Pollutants" tab

**If your results are below detection limit then report your results as the detection limit with a less than (“<”) symbol in front of the value. If your results are between the detection limit and the quantifiable limit (i.e., may be flagged with a “J”), then note in the**  **appropriate comments column of the template which compounds have results between the detection limit and the quantifiable limit.** Form Approved 03/28/2011 OMB Control No. 2060-0657



## , “throughput/production”is the quantity of fuel gas input to the unit. Throughput units are scfm; use 60°F