# SOUTHWEST RESEARCH INSTITUTE ®



### SAN ANTONIO, TX ● HOUSTON, TX ● WASHINGTON, DC 

# EPACT/V2/E-89 FUEL BLENDING

FINAL REPORT

NREL Subcontract No. ACI-8-88612-01 US EPA Contract EP-C-07-028, Work Assignments 0-01, 1-04, and 1-10

SwRI ® 

## Project Nos. 03. 03.13363.01, 03.14175.04, 03.14175.10, and 03.14295

Prepared for:

Dr. Douglas Lawson National Renewable Energy Laboratory 1617 Cole Boulevard

Golden, CO 80401

and

Dr. Rafal Sobotowski Environmental Protection Agency 2000 Traverwood Drive Ann Arbor, Michigan 48105

Prepared by:

Kevin A. Whitney Manager, Light-Duty Vehicle Emissions Emissions R&D Department

September 2010

# EPACT/V2/E-89 FUEL BLENDING

FINAL REPORT

NREL Subcontract No. ACI-8-88612-01 US EPA Contract EP-C-07-028, Work Assignments 0-01, 1-04, and 1-10

SwRI ® 

## Project Nos. 03. 03.13363.01, 03.14175.04, 03.14175.10, and 03.14295

Prepared for:

Dr. Douglas Lawson National Renewable Energy Laboratory 1617 Cole Boulevard

Golden, CO 80401

and

Dr. Rafal Sobotowski Environmental Protection Agency 2000 Traverwood Drive Ann Arbor, Michigan 48105

September 2010

Prepared by: Approved by:

_________________________________ ________________________________ Kevin A Whitney, Manager Jeff J. White, Director

EMISSIONS RESEARCH AND DEVELOPMENT DEPARTMENT

ENGINE, EMISSIONS AND VEHI CLE RESEARCH DIVISION

This report shall not be reproduced, ex cept in full, without the written approv al of Southwest Research Institute ®

. Results and discussion given in this report relate only to the test items described in this report.REPORT 03.14295/03-51563E 

### ii FOREWORD

This report covers work the Southwest Rese arch Institute (SwRI®) Office of Automotive Engineering has conducted for the National Renewa ble Energy Laboratory (NREL) and the U.S. Environmental Protection Agency (EPA) in suppor t of the Energy Policy Act of 2005 (EPAct). Section 1506 of EPAct requires EPA to produce an updated fuel effects model representing the 2007 light-duty gasoline fleet, including determinat ion of the emissions impacts of increased renewable fuel use.

This report covers the formulation, analysis, and procurement of test fuels for the EPAct Gasoline Light-Duty Exhaust Fuel Effects Test Pr ogram, also referred to as the EPAct/V2/E-89 Program. It is expected that this report will be an attachment or chapter in the overall EPAct/V2/E-89 Program report prepared by EPA and NREL. Other EPAct/V2/E-89 reports are expected to cover room temperature and 50°F emissi ons testing of three fuel s using nineteen Tier 2 vehicles (known as Phase 1, Phase 2, and Interi m FTP Testing); emissions testing of 28 fuels using sixteen Tier 2 vehicles (Phase 3); room te mperature, 95°F, and 20°F testing of three fuels using six Tier 2 vehicles (Phase 4); and room te mperature, 95°F, and 20°F testing of three fuels using three high-emitting vehicles (Phase 5).

SwRI’s portion of this fuel blending e ffort was funded under NREL Subcontract No. ACI-8-88612-01 and EPA Contract No. EP-C-07- 028, Work Assignments 0-01, 1-04, and 1-10. The project was based on SwRI Proposal Nos. 03-50782C, 03-53262A, 03-51563E and 03- 54753.

The program was identified within SwRI under Project Nos. 03.13363.01, 03.14175.04, 03.14175.10, and 03.14295. The program was monito red by Douglas Lawson of NREL and Rafal Sobotowski of EPA. The SwRI Project Manager was Kevin Wh itney, and the Project Leader was Kevin Brunner. Fuel was blended and supplied by Haltermann Products based on formulations jointly developed by Haltermann and EPA. Dr. Sobotowski of EPA offered substantial assistance in the formul ation and approval of test fuels.

Fuel formulation and procurement occurr ed between March 2008 and May 2009. At the time this report was written, some fuels were st ill being utilized in testing under the EPAct/V2/E89 Program. Details of fuel ha ndling and quality checks to confir m each fuel drum for ethanol content, aromatic content, and T90 are included in individual reports or chapters associated with the testing using specific fuels.REPORT 03.14295/03-51563E 

### iii TABLE OF CONTENTS

Page

FOREWARD ...................................................................................................................... ............ ii

LIST OF FIGURES ............................................................................................................... ........ iv

LIST OF TABLES ................................................................................................................ ......... iv

ACKNOWLEDGEMENTS ............................................................................................................ V

ACRONYMS AND ABBREVIATIONS ...................................................................................... vI

1.0 INTRODUCTION .............................................................................................................. .1 2.0 TECHNICAL APPROACH AND RESULTS .....................................................................2 3.0 CLOSURE ................................................................................................................... ......12

APPENDICES No. of Pages

A - DEATILED FUEL INSPECTION DATA ..........................................................................5 B - FUEL ANALYSES SUMMARY ......................................................................................50 C - DETAILED HYDROCARBON ANALYSIS RESULTS ...............................................600REPORT 03.14295/03-51563E 

### iv LIST OF FIGURES

Figure Page

1 Constant-Temperature Storage of Unopened Fuel Drums .................................................11

LIST OF TABLES

Table Page

1 EPACT/V2/E-89 Gasoline Light-Duty Exhaust Fuel Effects Test Program Fuel Properties ............................................................................................................. ........3

2 Fuel Development Protocol .................................................................................................7REPORT 03.14295/03-51563E 

### v ACKNOWLEDGEMENTS

SwRI acknowledges the following:

• The Department of Energy Office of Bi omass Programs and Office of Vehicle Technologies for their financial support provided through the National Renewable Energy Laboratory

• The Environmental Protection Agency fo r their funding and extensive technical support in the development of these test fuels

• The Coordinating Research Council for providing Fuel 29REPORT 03.14295/03-51563E 

### vi ACRONYMS AND ABBREVIATIONS

°F degrees Fahrenheit IBP initial boiling point API American Petroleum Institute ASTM American Society fo r Testing and Materials Btu British thermal unit CRC Coordinating Research Council DHA detailed hydrocarbon analysis DVPE dry vapor pressure equivalent EPA US Environmental Protection Agency EPAct 2007 Energy Policy Act E10 gasoline containing 10 percent volume denatured ethanol E15 gasoline containing 15 percent volume denatured ethanol E20 gasoline containing 20 percent volume denatured ethanol E85 gasoline containing 85 percent volume denatured ethanol FBP final boiling point FIA flame ionization analyzer
g gram HP Haltermann products IBP initial boiling point Kg kilogram kPa kilopascal lb pound mass mg milligram MJ megajoule mL milliliter MON motor octane number NREL National Renewa ble Energy Laboratory psi pounds per square inch ppm parts per million RON research octane number RVP Reid vapor pressure SwRI Southwest Research Institute vol. volume WAM work assignment managerREPORT 03.03.14295/03-51563E 

### 1 of 12 1.0 INTRODUCTION

The National Renewable Energy Laboratory and the US Environmental Protection Agency (EPA), with support from the Coordi nating Research Council (CRC), are conducting the EPAct Gasoline Light-Duty Exhaust Fuel Effect s Test Program, also referred to as the EPAct/V2/E-89 Program. This emission test progra m includes multiple fuel properties, multiple ambient test temperatures, and different vehi cle technologies. Th is report covers the formulation, analysis, and procurement of the th irty-one test fuels used in the EPAct/V2/E-89 Program. This effort was funded under NREL Subcontract No. ACI-8-88612-01 and EPA Contract No. EP-C-07-028, Work Assignments 0- 01, 1-04, and 1-10. One te st fuel was provided by the Coordinating Research Council.REPORT 03.03.14295/03-51563E 

### 2 of 12 2.0 TECHNICAL APPRO ACH AND RESULTS

Test fuels were procured from Haltermann Products. EPA provided SwRI with target fuel specifications. These test fu els were designed to cover a br oad range of properties and were not representative of commercial fuels. Many of these fuels were extremel y difficult to blend to meet all specification, and in some cases EPA and NREL approved fuel ble nds that did not meet all target specifications. To help the reader und erstand these differences, Table 1 contains target fuel specifications as well as SwRI in spection data of final approved fuels.

Fuels 17, 18, and 19 were the first fuels blended, and were formulated by Haltermann based on EPA’s recommendation and NREL’s acceptan ce. However, based on the challenges of blending these fuels, a formalized fuel developm ent protocol was created. Using this protocol, all other test fuels except Fuel 29 were fo rmulated by Rafal Sobotowski of the EPA in conjunction with Haltermann, who provided EPA with data for all their blendstock components. The final fuel development protocol used for th is program is given in Table 2. Fuel 29 was provided to the program by the Coordinating Research Council.

Detailed fuel inspection results as determin ed by SwRI are provided in Appendix A. The format of Appendix A is the same as an EPA-coordinated EPAct/V 2/E-89 Fuels Round Robin study, which is expected to be separately report ed. All data provided in Appendix A are the same as those SwRI provided to EPA for the r ound robin data study. The inspection data in Appendix A are much more detailed than the in formation provided in Ta ble 1, which includes only the fuel specifications a nd related inspection results.

Over the course of fuel development, Haltermann Products used the following external laboratories for analyses: Dixie, Gage, Core , Inspectorate, Paragon, and Saybolt. Following every set of analyses, Haltermann compiled these inspection results in spreadsheets, which were forwarded to NREL, EPA, and SwRI. These de tailed fuel inspection data are provided for reference in Appendix B.

In addition to the provided inspection data, all fuels except Fuel 29 received detailed hydrocarbon analysis (DHA) using ASTM Method D6729. These results are given in Appendix C. DHA results show that Fuels 17 and 18 contained unusually high amounts of cyclohexane: approximately 18 and 13 volume percent respectivel y. Haltermann used cyclohexane as a one of the fuel blending components in an effort to meet EPA’s request to “match” the three fuels within a 20°F window across as much of the distillation curve as possible.

The data in Appendices A, B, a nd C have also been provided in Excel format as part of the electronic submission of this reportREPORT 03.14295/03-51563E 

### 3 of 12TABLE 1. EPACT/V2/E-89 GASOLINE LIGHT-DUTY EXHAUST FUEL EFFECTS TEST PROGRAMFUEL PROPERTIESa– inspection results from HaltermannNOTE: Properties in bold were varied withinthe fuel matrix. All other properties were held constant.Test Fuel Specification12345678Spec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultDensity, 60oFg/cm3D4052 NA Report 0.7214 Report 0.7224 Report 0.7360 Report 0.7350 Report 0.7578 Report 0.7345 Report 0.7211 Report 0.7203API Gravity, 60oFoAPID4052 NA Report 64.5 Report 64.3 Report 60.7 Report 60.9 Report 55.2 Report 61.1 Report 64.7 Report 64.9Ethanol Content vol. % D5599E0: < 0.1;E10: ± 0.5;E15: ± 0.5;E20: ±0.5;E85: ±210 10.1 0 <0.1 10 10.4 10 9.8 0 <0.2 10 10.6 0 <0.1 0 <0.1Total Content of Oxygenates Otherthan Ethanolvol. % D5599 - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1T10 oF D86 - <158 117 <158 121 <158 142 <158 123 <158 143 <158 137 <158 137 <158 124T50 oF D86 ± 4 150 149 240 236 220 218 220 219 240 236 190 196 190 193 220 222T90 oF D86 ± 5 300 303 340 341 300 300 340 337 300 301 340 344 300 297 300 304FBP oF D86 - <437 368 <437 375 <437 372 <437 371 <437 360 <437 370 <437 359 <437 360DVPE psi D5191 ± 0.25 10.0 10.1 10.0 10.4 7.0 6.8 10.0 10.0 7.0 6.9 7.0 7.2 7.0 7.3 10.0 9.9Aromatics vol. % D1319 ± 1.5 15.0 15.5 15.0 14.1 15.0 15.9 15.0 15.6 35.0 35.8 15.0 15.4 15.0 16.7 15.0 16.0Olefins vol. % D1319 ± 1.5 7 7.5 7 7.2 7 7.3 7 6.9 7 7.0 7 9.0 7 7.3 7 6.2Benzene vol. % D3606 ± 0.15 0.62 0.71 0.62 0.50 0.62 0.75 0.62 0.57 0.62 0.49 0.62 0.82 0.62 0.55 0.62 0.48S mg/kg D5453 ± 5 25 30 25 23 25 26 25 21 25 25 25 22 25 23 25 22(R + M)/2 - Calc. -≥87.0 91≥87.0 92≥87.0 93≥87.0 93≥87.0 91≥87.0 92≥87.0 88≥87.0 92C mass % Calc. - Report 82.2 Report 85.4 Report 82.4 Report 82.2 Report 87.0 Report 81.4 Report 85.3 Report 85.5H mass %D4808Method A- Report 13.6 Report 14.3 Report 14.0 Report 13.9 Report 13.0 Report 14.3 Report 14.2 Report 14.2O mass % D5599 - Report 3.9 Report <0.1 Report 3.9 Report 3.7 Report <0.1 Report 4.0 Report <0.1 Report <0.1Gross Heat of Combustion Btu/lb D4809 - Report 19,318 Report 20,216 Report 19,242 Report 19,312 Report 19,628 Report 19,191 Report 20,125 Report 20,209Water Contentamg/kg E1064 - Report 0.1 Report <0.1 Report 0.1 Report <0.1 Report <0.1 Report 0.1 Report <0.1 Report <0.1Copper Strip Corrosion, 3h at 122oFa- D130 - <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1ASolvent-Washed Gum Contentamg/100 ml D381 - < 5 <0.5 < 5 <0.5 < 5 <0.5 < 5 1.5 < 5 <0.5 < 5 <0.5 < 5 <0.5 < 5 <0.5Oxidation Stabilityaminute D525 - >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240PROPERTY UNIT METHODBLENDINGTOLERANCETEST FUELSE0/E10 FuelsREPORT 03.14295/03-51563E 

### 4 of 12TABLE 1 (CONT'D). EPACT/V2/E-89 GASOLINE LIGHT-DUTY EXHAUST FUEL EFFECTS TEST PROGRAMFUEL PROPERTIESa– inspection results from HaltermannNOTE: Properties in bold werevaried within the fuel matrix. Allother properties were held constant.Test Fuel Specification9 10 11 12 13 14 15 16Spec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultDensity, 60oFg/cm3D4052 NA Report 0.7453 Report 0.7663 Report 0.7601 Report 0.7521 Report 0.7544 Report 0.7227 Report 0.7431 Report 0.7645API Gravity, 60oFoAPID4052 NA Report 58.3 Report 53.1 Report 54.6 Report 56.6 Report 56.0 Report 64.2 Report 58.8 Report 53.5Ethanol Content vol. % D5599E0: < 0.1;E10: ± 0.5;E15: ± 0.5;E20: ±0.5;E85: ±20 <0.1 10 9.9 10 10.2 10 9.9 0 <0.1 0 <0.1 0 <0.1 10 10.6Total Content of Oxygenates Otherthan Ethanolvol. % D5599 - <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1T10 oF D86 - <158 113 <158 137 <158 125 <158 117 <158 137 <158 134 <158 116 <158 140T50 oF D86 ± 4 190 191 220 218 190 196 150 153 220 222 190 192 190 190 220 221T90 oF D86 ± 5 340 341 340 342 300 303 340 342 340 339 340 338 300 299 300 306FBP oF D86 - <437 381 <437 372 <437 361 <437 380 <437 377 <437 369 <437 365 <437 370DVPE psi D5191 ± 0.25 10.0 10.3 7.0 7.0 10.0 9.9 10.0 10.1 7.0 6.9 7.0 7.1 10.0 10.1 7.0 7.0Aromatics vol. % D1319 ± 1.5 35.0 37.3 35.0 35.6 35.0 35.1 35.0 35.1 35.0 33.5 15.0 16.6 35.0 36.7 35.0 36.7Olefins vol. % D1319 ± 1.5 7 6.2 7 6.0 7 6.3 7 6.0 7 5.1 7 7.7 7 7.2 7 6.7Benzene vol. % D3606 ± 0.15 0.62 0.55 0.62 0.58 0.62 0.57 0.62 0.62 0.62 0.53 0.62 0.52 0.62 0.53 0.62 0.65S mg/kg D5453 ± 5 25 23 25 25 25 22 25 19 25 22 25 24 25 23 25 22(R + M)/2 - Calc. -≥87.0 90≥87.0 93≥87.0 92≥87.0 94≥87.0 91≥87.0 88≥87.0 90≥87.0 95C mass % Calc. - Report 87.2 Report 83.5 Report 83.7 Report 83.8 Report 86.6 Report 85.4 Report 87.1 Report 83.3H mass %D4808Method A- Report 12.8 Report 12.7 Report 12.5 Report 12.7 Report 13.6 Report 14.2 Report 12.9 Report 12.6O mass % D5599 - Report <0.1 Report 3.6 Report 3.7 Report 3.6 Report <0.1 Report <0.1 Report <0.1 Report 3.8Gross Heat of Combustion Btu/lb D4809 - Report 19,757 Report 18,958 Report 18,817 Report 18,950 Report 19,729 Report 20,128 Report 19,710 Report 18,769Water Contentamg/kg E1064 - Report <0.1 Report 0.1 Report 0.1 Report 0.1 Report <0.1 Report <0.1 Report <0.1 Report 0.1Copper Strip Corrosion, 3h at 122oFa- D130 - <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1ASolvent-Washed Gum Contentamg/100 ml D381 - < 5 <0.5 < 5 <0.5 < 5 0.5 < 5 <0.5 < 5 1.5 < 5 <0.5 < 5 0.5 < 5 1.0Oxidation Stabilityaminute D525 - >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240PROPERTY UNIT METHODBLENDINGTOLERANCETEST FUELSE0/E10 FuelsREPORT 03.14295/03-51563E 

### 5 of 12TABLE 1 (CONT'D). EPACT/V2/E-89 GASOLINE LIGHT-DUTY EXHAUST FUEL EFFECTS TEST PROGRAMFUEL PROPERTIESa– inspection results from HaltermannNOTE: Properties in bold werevaried within the fuel matrix. Allother properties were held constant.Test Fuel SpecificationSeptember 22, 200817 18 19 20 21 22 23 24Spec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultDensity, 60oFg/cm3D4052 NA Report 0.7581 Report 0.7537 Report 0.7498 Report 0.7429 Report 0.7764 Report 0.7375 Report 0.7485 Report 0.7428API Gravity, 60oFoAPID4052 NA Report 55.1 Report 56.1 Report 57.4 Report 58.9 Report 50.7 Report 60.3 Report 57.5 Report 58.9Ethanol Content vol. % D5599E0: < 0.1;E10: ± 0.5;E15: ± 0.5;E20: ±0.5;E85: ±20 <0.1 9.5 9.4 14.5 14.1 20 19.8 20 20.0 20 20.1 20 20.0 20 20.1Total Content of Oxygenates Otherthan Ethanolvol. % D5599 - <0.1 <0.1 <0.1 <0.1 <0.15 <0.1 <0.2 <0.1 <0.2 <0.1 <0.2 <0.1 <0.2 <0.1 <0.2 <0.1T10 oF D86 - <158 130 <158 134 <158 128 <158 143 <158 142 <158 130 <158 139 <158 129T50 oF D86 ± 4 215 215 202 211 195 181 165 162 165 168 165 163 165 162 165 165T90 oF D86 ± 5 325 323 325 319 325 312 300 300 300 308 300 303 340 338 340 341FBP oF D86 - <437 371 <437 345 <437 350 <437 377 <437 360 <437 377 <437 365 <437 370DVPE psi D5191 ± 0.25 8.9 9.2 8.9 9.0 8.9 9.0 7.0 6.7 7.0 6.9 10.0 10.2 7.0 6.6 10.0 10.2Aromatics vol. % D1319 ± 1.5 29.5 29.5 24.9 22.9 22.6 22.1 15.0 16.3 35.0 34.5 15.0 15.4 15.0 16.5 15.0 15.9Olefins vol. % D1319 ± 1.5 7 6.3 7 5.7 7 6.2 7 7.3 7 7.1 7 7.1 7 7.0 7 6.6Benzene vol. % D3606 ± 0.15 0.62 0.46 0.62 0.68 0.62 0.71 0.62 0.69 0.62 0.72 0.62 0.65 0.62 0.70 0.62 0.71S mg/kg D5453 ± 5 25 23 25 22 25 21 25 23 25 20 25 21 25 22 25 21(R + M)/2 - Calc. -≥87.0 88≥87.0 89≥87.0 89≥87.0 96≥87.0 94≥87.0 95≥87.0 93≥87.0 95C mass % Calc. - Report 86.5 Report 82.9 Report 81.5 Report 78.0 Report 80.7 Report 78.6 Report 77.8 Report 78.4H mass %D4808Method A- Report 13.5 Report 13.7 Report 13.5 Report 14.3 Report 12.2 Report 13.7 Report 14.9 Report 13.9O mass % D5599 - Report <0.1 Report 3.4 Report 5.1 Report 7.4 Report 7.1 Report 7.5 Report 7.4 Report 7.5Gross Heat of Combustion Btu/lb D4809 - Report 19,775 Report 19,117 Report 18,725 Report 18,473 Report 18,021 Report 18,470 Report 18,434 Report 18,447Water Contentamg/kg E1064 - Report <0.1 Report 0.1 Report 0.2 Report <0.1 Report <0.1 Report 0.1 Report <0.1 Report 0.1Copper Strip Corrosion, 3h at 122oFa- D130 - <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1ASolvent-Washed Gum Contentamg/100 ml D381 - < 5 <0.5 < 5 <0.5 < 5 0.5 < 5 <0.5 < 5 0.5 < 5 <0.5 < 5 0.5 < 5 0.5Oxidation Stabilityaminute D525 - >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240 >240E15/E20 FuelsTEST FUELSPROPERTY UNIT METHODBLENDINGTOLERANCERFS2 FuelsREPORT 03.14295/03-51563E 

### 6 of 12TABLE 1 (CONT'D). EPACT/V2/E-89 GASOLINE LIGHT-DUTY EXHAUST FUEL EFFECTS TEST PROGRAMFUEL PROPERTIESa– inspection results from Haltermannb– fuel provided by CRCc– inspection results fromEPA Fuels Round Robin studyNOTE: Properties in bold were varied within the fuel matrix. Allother properties were held constant.Test Fuel Specification25 26 27 2829b30 31Spec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultSpec.SwRIResultcSpec.SwRIResultSpec.SwRIResultDensity, 60oFg/cm3D4052 NA Report 0.7714 Report 0.7624 Report 0.7448 Report 0.7724 Report 0.7797 Report 0.7513 Report 0.7748API Gravity, 60oFoAPID4052 NA Report 51.8 Report 54.0 Report 58.4 Report 51.6 Report 49.8 Report 56.8 Report 51.0Ethanol Content vol. % D5599E0: < 0.1;E10: ± 0.5;E15: ± 0.5;E20: ±0.5;E85: ±220 19.9 15 15.1 15 14.7 15 14.6 81 79.6 10 9.9 20 20.1Total Content of Oxygenates Otherthan Ethanolvol. % D5599 - <0.2 <0.1 <0.15 <0.1 <0.15 <0.1 <0.15 <0.1 <2.0 <0.01 <0.1 <0.1 <0.2 <0.1T10 oF D86 - <158 129 <158 119 <158 143 <158 144 Report 154 <158 115 <158 140T50 oF D86 ± 4 165 167 160 161 220 225 220 219 Report 172 150 152 165 167T90 oF D86 ± 5 340 344 340 344 340 342 300 303 Report 174 325 329 325 330FBP oF D86 - <437 377 <437 376 <437 372 <437 364 Report 266 <437 364 <437 366DVPE psi D5191 ± 0.25 10.0 10.1 10.0 10.0 7.0 6.9 7.0 6.8 6.9 8.9 10.0 10.0 7.0 6.9Aromatics vol. % D1319 ± 1.5 35.0 37.9 35.0 36.9 15.0 16.2 35.0 36.5 Report na 35.0 37.1 35.0 38.0Olefins vol. % D1319 ± 1.5 7 6.8 7 6.8 7 8.1 7 7.2 Report na 7 6.4 7 5.7Benzene vol. % D3606 ± 0.15 0.62 0.75 0.62 0.67 0.62 0.66 0.62 0.69 Report 0.12 0.62 0.70 0.62 0.79S mg/kg D5453 ± 5 25 25 25 23 25 26 25 24 15 16 25 25 25 22(R + M)/2 - Calc. -≥87.0 95≥87.0 95≥87.0 95≥87.0 96 Report na≥87.0 94≥87.0 94C mass % Calc. - Report 81.0 Report 82.1 Report 81.1 Report 82.1 Report 57.7 Report 82.7 Report 80.4H mass %D4808Method A- Report 11.9 Report 12.2 Report 13.9 Report 12.5 Report 12.8 Report 13.8 Report 12.5O mass % D5599 - Report 7.1 Report 5.5 Report 5.5 Report 5.2 Report 27.2 Report 3.7 Report 7.2Gross Heat of Combustion Btu/lb D4809 - Report 17,309 Report 18,524 Report 18,972 Report 18,575 Report 12,925 Report 18,963 Report 18,021Water Contentamg/kg E1064 - Report 0.1 Report 0.1 Report 0.1 Report 0.1 <10,000 9,255 Report <0.1 Report <0.1Copper Strip Corrosion, 3h at 122oFa- D130 - <No. 1 1A <No. 1 1A <No. 1 1A <No. 1 1A na na <No. 1 1A <No. 1 1ASolvent-Washed Gum Contentamg/100 ml D381 - < 5 <0.5 < 5 <0.5 < 5 0.5 < 5 <0.5 < 5 1.9 < 5 <0.5 < 5 0.5Oxidation Stabilityaminute D525 - >240 >240 >240 >240 >240 >240 >240 >240 na na >240 >240 >240 >240PROPERTY UNIT METHODBLENDINGTOLERANCETEST FUELSE15/E20 Fuels E85 CRC FuelsREPORT 03.14295/03-51563E 

### 7 of 12 TABLE 2. FUEL DEV ELOPMENT PROTOCOL

Step 1 : Based on the specification provided in Table 1, the EPA shall generate a recipe for each test fuel and forward it to Haltermann Products (HP) 1



### Step 2 : HP shall prepare a hand blend a nd perform its analysis. The scope of this analysis shall include, at the minimum, D86 di stillation, D1319 FIA and D5191 DVPE

• If the predicted S content of this blend is ≥ 27 ppm, then S by D5453 shall also be measured

• If the predicted benzen e content of this blend ≥ 0.70, then benzen e by D3606 shall also be measured

• If the predicted anti knock index ((R+M)/2) of this blend ≤ 88.0, D2699 research and D2700 motor octane numbers shall also be measured

Note: OptiDist distillation stills shall be used to generate D 86 distillation data for all E10, E15, E20 and E85 fuels

Note: Distillation, FIA, and RVP shall be m easured by HP and a contract laboratory of HP’s choice

Note: For a typical fuel, it is expected that Steps 1 and 2 may be repeated up to three more times; more iterations may be necessary for some fuels.

Step 3 : Once the blend meets the T10, T50, T90, FBP, DVPE, FIA aromatics, FIA olefins, benzene content, S content, ethanol content and anti knock index requirements of the specification provided in Table 1, its inspection data shall be presented to the EPA WAM for approval

Step 4 : Upon approval of the hand blend inspection data, the EPA WAM shal l generate the final specification for the bulk blend of this fuel based on the following table:

1 Communications between EPA and HP will take place via SwRIREPORT 03.14295/03-51563E 

### 8 of 12 TABLE 2 (CONT'D). FUEL DEVELOPMENT PROTOCOLREPORT 03.14295/03-51563E 

### 9 of 12 TABLE 2 (CONT'D). FUEL DEVELOPMENT PROTOCOL

Step 5 : HP shall prepare the bulk blend of the fuel and adjust its properties until it meets the specification defined in Step 4

Note : OptiDist distillation s tills shall be used to generate D86 distillation data for all E10, E15, E20 and E85 fuels

Note : Distillation, FIA, RVP, S content, ben zene content and anti knock index shall be determined by HP

Note : The fuel shall be also analyzed by a c ontract laboratory of HP’s choice in two phases

Phase 1 : Initially, the distillation, FIA, and RVP shall be determined

• S content, benzene content and anti knock index shall also be determined if the criteria listed for these parameters in Step 2 are met

Phase 2 : The remaining fuel properties shall be determined only when the average values of distillation parameters, FIA, RVP, S c ontent, benzene content and anti knock index determined by HP and the contract lab have been shown to meet the requirements of the specification defined in Step 4 (Phase 2). Th ey must also be with in the reproducibility limits of each test method.

Step 6 : Once the inspection data generated by HP and th e contract laboratory indicate that the final blend meets the specification defined in St ep 4, a sample shall be shipped to SWRI for confirmatory analysis

Step 7 : SWRI shall perform tests listed in WA 1-04, contract EP-C-07-028, except for H by D4808 which has been dropped from the EPAct fuel specification

Note: OptiDist distillatio n stills shall be used to generate D86 distillation data for all E10, E15, E20 and E85 fuels

Step 8 : If SwRI analytical results are outside of test reproducibility limits for any parameter, discussions will be necessary among EPA, SwRI , and Haltermann regarding the disposition of the fuel. Otherwise, following review of SwRI and Haltermann results, EPA will approve the bulk blend for shipment to SwRI.

Blending sequence : E0 and E10 fuels will be blended first, followed by E20 fuels, E15 fuels and the E85 fuelREPORT 03.14295/03-51563E 

### 10 of 12 SwRI procured the following fuel amounts:

Number of 55-Gallon Drums
EPA funding NREL fund ing Provided by CRC
Shipped to SwRI Shipped to EPA Shipped to SwRI

Fuel 1 10 Fuel 2 10 Fuel 3 10 Fuel 4 10 Fuel 5 10 Fuel 6 10 Fuel 7 10 Fuel 8 10 Fuel 9 10 Fuel 10 10 Fuel 11 10 Fuel 12 10 Fuel 13 10 Fuel 14 10 Fuel 15 10 Fuel 16 10 Fuel 17 20 4 2 Fuel 18 20 4 2 Fuel 19 20 4 2 Fuel 20 10 Fuel 21 10 Fuel 22 10 Fuel 23 10 Fuel 24 10 Fuel 25 10 Fuel 26 10 Fuel 27 10 Fuel 28 10 Fuel 29 4 Fuel 30 10 Fuel 31 10

For contingency purposes, these amounts includ ed approximately 20 percent more fuel than the anticipated need to complete the progr am. All fuels were maintained in sealed epoxylined 5B drums at a constant temperature of le ss than 75°F (Figure 1). The storage temperature for unopened drums was 70°F ± 5°F. Prior to opening a drum, it was conditioned to a temperature of less than 50°F. Once a drum of fuel was opened, it continued to be stored at 45°F ± 5°F. In an effort to ensure correct drum labeling, during the conduct of the program each time a new drum was opened ethanol content, arom atic content, and T90 were determined usingREPORT 03.14295/03-51563E 

### 11 of 12 a PetroSpec portable gasoline analyz er. PetroSpec analyses were pe rformed as part of individual NREL and EPA contracts and work assignments, some of which are still ongoing. As such, PetroSpec results are not reported here and will be included in appropriate reports for Phases 1, 2, 3, 4, & 5, and Interim FTP Testing.

FIGURE 1. CONSTANT-TEMPERATURE STORAGE OF UNOPENED FUEL DRUMSREPORT 03.14295/03-51563E 

### 12 of 12 3.0 CLOSURE

All analytical results included in the report have also been submitted electronically to NREL and EPA. With the submission of this fina l report, all contracted items of work under the relevant proposals are complete.REPORT 03.14295/03-51563E 

# APPENDIX A

DETAILED FUEL INSPECTION DATAREPORT 03.14295/03-51563E 

### A-1 EPACT/V2/E-89 GASOLINE LIGHT- DUTY EXHAUST FUEL EFFECTS TEST PROGRAM – DETAILED FUEL INSPECTION DATA

FUEL

123456

Density, 60 o F g/cm 3 D4052 0.7214 0.7224 0.7360 0.7350 0.7578 0.7345
API Gravity, 60 o F o API D4052 64.5 64.3 60.7 60.9 55.2 61.1 Ethanol vol. % D5599 10.14 <0.1 10.42 9.83 <0.2 10.55 Total Content of Oxygenates Other Than Ethanol vol. % D5599 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Distillation IBP oF 94 83 109 94 94 109 5% evap oF 113 105 137 113 125 132 10% evap oF 117 121 142 123 143 137 20% evap oF 124 153 149 140 171 143 30% evap oF 131 190 155 151 198 149 40% evap oF 140 218 180 158 221 154 50% evap oF 149 236 218 219 236 196 60% evap oF 177 251 225 243 248 231 70% evap oF 226 272 245 267 260 274 80% evap oF 256 305 260 300 274 315 90% evap oF 303 341 300 337 301 344 95% evap oF 338 353 340 350 324 358
FBP oF 368 375 372 371 360 370 Recovery vol. % 98.4 96.8 98.2 97.6 97.3 97.1
Residue vol. % 1.1 0.9 1.0 0.8 1 1.1
Loss vol. % 0.5 2.3 0.8 1.6 1.7 1.8 DVPE psi D5191 10.05 10.38 6.78 10.00 6.86 7.19 Aromatics vol. % D1319 15.5 14.1 15.9 15.6 35.8 15.4 Olefins vol. % D1319 7.5 7.2 7.3 6.9 7.0 9.0 Benzene vol. % D3606 0.71 0.50 0.75 0.57 0.49 0.82 S mg/kg D5453 30 23 26 21 25 22 RON - D2699 94.9 96 98 97 96 96 MON - D2700 86.7 89 88 88 86 87 (R + M)/2 - Calc. 90.8 92 93 93 91 92 C mass % D5291 mod. 82.16 85.39 82.44 82.23 86.98 81.42 H mass % D5291 mod. 13.60 14.25 14.04 13.90 13.04 14.26 O mass % D5599 3.9 <0.1 3.9 3.7 <0.1 4.0 Gross Heat of Combustion Btu/lb D4809 19,318 20,216 19,242 19,312 19,628 19,191 Toluene vol. % D3606 4.66 3.95 4.46 4.13 11.93 3.94
Water a mass % E-1064 0.052 0.005 0.051 0.063 0.004 0.058

Lead a g/l D3237 - <0.001 - - <0.003 - Copper Strip Corrosion a - D130 1A 1A 1A 1A 1A 1A
Solvent Washed Gum Content a mg/100ml D381 <0.5 <0.5 <0.5 1.5 <0.5 <0.5 Oxidation Stability a min. D525 >240 >240 >240 >240 >240 >240

a – inspection results from Haltermann

b – inspection results from EPA Fuels R ound Robin study TEST METHOD PROPERTY UNIT

D86 (OptiDist or equivalent for

E10, E15 and

E20 fuels)REPORT 03.14295/03-51563E 

### A-2 EPACT/V2/E-89 GASOLINE LIGHT- DUTY EXHAUST FUEL EFFECTS TEST PROGRAM – DETAILED FUEL IN SPECTION DATA (CONT’D)

FUEL

7 8 9 10 11 12

Density, 60 o F g/cm 3 D4052 0.7211 0.7203 0.7453 0.7663 0.7601 0.7521
API Gravity, 60 o F o API D4052 64.7 64.9 58.3 53.1 54.6 56.6
Ethanol vol. % D5599 <0.1 <0.1 <0.1 9.87 10.21 9.85 Total Content of Oxygenates Other Than Ethanol vol. % D5599 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Distillation IBP oF 100 84 84 106 92 92 5% evap oF 128 108 102 131 117 111 10% evap oF 137 124 113 137 125 117 20% evap oF 149 152 129 144 138 124 30% evap oF 161 182 146 151 148 134 40% evap oF 177 205 166 163 157 143 50% evap oF 193 222 191 218 196 153 60% evap oF 210 234 223 263 233 210 70% evap oF 229 248 260 289 253 280 80% evap oF 252 266 292 319 273 312 90% evap oF 297 304 341 342 303 342 95% evap oF 329 332 363 357 336 365
FBP oF 359 360 381 372 361 380 Recovery vol. % 97.9 96.9 97.2 98.0 97.9 97.5
Residue vol. % 0.8 1.1 0.5 1.0 1.0 1.1
Loss vol. % 1.3 2 2.3 1.0 1.1 1.4 DVPE psi D5191 7.32 9.93 10.32 7.02 9.87 10.14 Aromatics vol. % D1319 16.7 16.0 37.3 35.6 35.1 35.1 Olefins vol. % D1319 7.3 6.2 6.2 6.0 6.3 6.0 Benzene vol. % D3606 0.55 0.48 0.55 0.58 0.57 0.62 S mg/kg D5453 23 22 23 25 22 19 RON - D2699 92 96 94 98 98 100 MON - D2700 85 88 85 87 86 88 (R + M)/2 - Calc. 88 92 90 93 92 94 C mass % D5291 mod. 85.32 85.49 87.15 83.49 83.71 83.76 H mass % D5291 mod. 14.20 14.16 12.78 12.67 12.50 12.74 O mass % D5599 <0.1 0 <0.1 3.6 3.7 3.6 Gross Heat of Combustion Btu/lb D4809 20,125 20,209 19,757 18,958 18,817 18,950 Toluene vol. % D3606 5.07 4.31 14.16 8.5 12.77 8.58
Water a mass % E-1064 0.005 <0.1 0.007 0.058 0.055 0.053

Lead a g/l D3237 <0.001 0.001 <0.001 <0.003 - <0.003 Copper Strip Corrosion a - D130 1A 1A 1A 1A 1A 1A
Solvent Washed Gum Content a mg/100ml D381 <0.5 <0.5 <0.5 <0.5 0.5 <0.5 Oxidation Stability a min. D525 >240 >240 >240 >240 >240 >240

a – inspection results from Haltermann

b – inspection results from EPA Fuels R ound Robin study PROPERTY UNIT TEST METHOD

D86 (OptiDist or equivalent for

E10, E15 and

E20 fuels)REPORT 03.14295/03-51563E 

### A-3 EPACT/V2/E-89 GASOLINE LIGHT- DUTY EXHAUST FUEL EFFECTS TEST PROGRAM – DETAILED FUEL IN SPECTION DATA (CONT’D)

FUEL

13 14 15 16 17 18 19

Density, 60 o F g/cm 3 D4052 0.7544 0.7227 0.7431 0.7645 0.7583 0.7536 0.7495
API Gravity, 60 o F o API D4052 56.0 64.2 58.8 53.5 55.1 56.1 57.3 Ethanol vol. % D5599 <0.1 <0.1 <0.1 10.62 <0.1 9.39 13.94 Total Content of Oxygenates Other Than Ethanol vol. % D5599 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Distillation IBP oF 97 99 80 106 89 98 93 5% evap oF 123 124 106 134 116 123 117 10% evap oF 137 134 116 140 130 134 128 20% evap oF 157 146 131 148 158 148 137 30% evap oF 177 159 147 156 182 154 144 40% evap oF 198 174 166 175 199 170 156 50% evap oF 222 192 190 221 215 211 181 60% evap oF 245 210 216 238 235 233 246 70% evap oF 270 236 244 254 264 265 262 80% evap oF 303 277 267 271 296 297 287 90% evap oF 339 338 299 306 323 319 312 95% evap oF 355 354 328 342 339 330 327
FBP oF 377 369 365 370 371 345 350 Recovery vol. % 96.9 97.7 97.8 97.6 98.1 97.8 97.9
Residue vol. % 1 0.6 0.8 1.0 0.8 0.8 0.6
Loss vol. % 2.1 1.7 1.4 1.4 1.1 1.4 1.5 DVPE psi D5191 6.92 7.09 10.06 7.00 9.34 8.99 8.99 Aromatics vol. % D1319 33.5 16.6 36.7 36.7 29.5 22.9 22.06 Olefins vol. % D1319 5.1 7.7 7.2 6.7 6.3 5.7 6.18 Benzene vol. % D3606 0.53 0.52 0.53 0.65 0.46 0.68 0.71 S mg/kg D5453 22 24 23 22 23 22 21 RON - D2699 96 92 95 101 93 94 94 MON - D2700 86 85 85 88 83 85 85 (R + M)/2 - Calc. 91 88 90 95 88 89 89 C mass % D5291 mod. 86.63 85.42 87.06 83.32 86.50 82.92 81.47 H mass % D5291 mod. 13.60 14.24 12.91 12.64 13.50 13.66 13.45 O mass % D5599 <0.1 <0.1 <0.1 3.8 <0.1 3.42 5.08 Gross Heat of Combustion Btu/lb D4809 19,729 20,128 19,710 18,769 19,775 19,117 18,725 Toluene vol. % D3606 12.21 4.42 16.26 12.85 4.59 4.39 6.37
Water a mass % E-1064 <0.1 0.005 0.007 0.057 <0.1 <0.1 <0.1

Lead a g/l D3237 <0.001 <0.001 <0.001 - - - - Copper Strip Corrosion a - D130 1A 1A 1A 1A 1A 0 0
Solvent Washed Gum Content a mg/100ml D381 1.5 <0.5 0.5 1 <0.5 0 0 Oxidation Stability a min. D525 >240 >240 >240 >240 >240 0 0

a – inspection results from Haltermann

b – inspection results from EPA Fuels R ound Robin study PROPERTY UNIT TEST METHOD

D86 (OptiDist or equivalent for

E10, E15 and

E20 fuels)REPORT 03.14295/03-51563E 

### A-4 EPACT/V2/E-89 GASOLINE LIGHT- DUTY EXHAUST FUEL EFFECTS TEST PROGRAM – DETAILED FUEL IN SPECTION DATA (CONT’D)

FUEL

20 21 22 23 24 25

Density, 60 o F g/cm 3 D4052 0.7429 0.7764 0.7375 0.7485 0.7428 0.7714
API Gravity, 60 o F o API D4052 58.9 50.7 60.3 57.5 58.9 51.8
Ethanol vol. % D5599 19.77 20.04 20.06 20.04 20.08 19.91 Total Content of Oxygenates Other Than Ethanol vol. % D5599 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1

Distillation IBP oF 107 109 93 110 91 92 5% evap oF 137 136 121 134 120 119 10% evap oF 143 142 130 139 129 129 20% evap oF 149 150 145 146 144 145 30% evap oF 155 157 154 152 154 155 40% evap oF 159 163 159 157 160 162 50% evap oF 162 168 163 162 165 167 60% evap oF 182 223 168 178 185 237 70% evap oF 234 255 234 272 270 289 80% evap oF 252 277 257 313 310 317 90% evap oF 300 308 303 338 341 344 95% evap oF 338 334 343 351 354 363
FBP oF 377 360 377 365 370 377 Recovery vol. % 98.8 98.2 97.8 98.6 97.6 97.1
Residue vol. % 1.0 1.0 1.0 1.0 1.1 1.1
Loss vol. % 0.2 0.8 1.2 0.4 1.3 1.8 DVPE psi D5191 6.70 6.94 10.22 6.64 10.19 10.10 Aromatics vol. % D1319 16.3 34.5 15.4 16.5 15.9 37.9 Olefins vol. % D1319 7.3 7.1 7.1 7.0 6.6 6.8 Benzene vol. % D3606 0.69 0.72 0.65 0.70 0.71 0.75 S mg/kg D5453 23 20 21 22 21 25 RON - D2699 102 100 101 98 101 101 MON - D2700 90 88 90 87 89 88 (R + M)/2 - Calc. 96 94 95 93 95 95 C mass % D5291 mod. 78.00 80.70 78.64 77.83 78.40 80.97 H mass % D5291 mod. 14.26 12.24 13.71 14.88 13.94 11.85 O mass % D5599 7.4 7.1 7.5 7.4 7.5 7.1 Gross Heat of Combustion Btu/lb D4809 18,473 18,021 18,470 18,434 18,447 17,309 Toluene vol. % D3606 4.15 12.81 4.10 4.06 4.08 8.78
Water a mass % E-1064 <0.1 <0.1 0.105 <0.1 0.103 0.113

Lead a g/l D3237 <0.0003 0.009 0.004 <0.003 0.005 0.001 Copper Strip Corrosion a - D130 1A 1A 1A 1A 1A 1A
Solvent Washed Gum Content a mg/100ml D381 <0.5 0.5 <0.5 0.5 0.5 <0.5 Oxidation Stability a min. D525 >240 >240 >240 >240 >240 >240

a – inspection results from Haltermann

b – inspection results from EPA Fuels R ound Robin study PROPERTY UNIT TEST METHOD

D86 (OptiDist or equivalent for

E10, E15 and

E20 fuels)REPORT 03.14295/03-51563E 

### A-5 EPACT/V2/E-89 GASOLINE LIGHT- DUTY EXHAUST FUEL EFFECTS TEST PROGRAM – DETAILED FUEL IN SPECTION DATA (CONT’D)

FUEL

26 27 28 29 b 30 31

Density, 60 o F g/cm 3 D4052 0.7624 0.7448 0.7724 0.7797 0.7513 0.7748
API Gravity, 60 o F o API D4052 54.0 58.4 51.6 49.8 56.8 51.0 Ethanol vol. % D5599 15.13 14.71 14.59 77.15 9.91 20.08 Total Content of Oxygenates Other Than Ethanol vol. % D5599 <0.1 <0.1 <0.1 <0.01 <0.1 <0.1

Distillation IBP oF 93 111 107 99 92 106 5% evap oF 113 138 136 133 108 134 10% evap oF 119 143 144 154 115 140 20% evap oF 130 153 153 168 125 149 30% evap oF 140 159 159 170 134 156 40% evap oF 151 164 164 171 143 162 50% evap oF 161 225 219 172 152 167 60% evap oF 188 252 241 172 208 236 70% evap oF 280 276 254 173 270 274 80% evap oF 313 316 270 173 298 302 90% evap oF 344 342 303 174 329 330 95% evap oF 357 352 337 176 333 350
FBP oF 376 372 364 266 364 366 Recovery vol. % 97.4 97.5 98.2 na 97.2 97.6
Residue vol. % 1.1 1.0 1.0 na 1.0 1.0
Loss vol. % 1.5 1.5 0.8 na 1.8 1.4 DVPE psi D5191 9.96 6.92 6.80 8.92 10.04 6.88 Aromatics vol. % D1319 36.9 16.2 36.5 - 37.1 38.0 Olefins vol. % D1319 6.8 8.1 7.2 - 6.4 5.7 Benzene vol. % D3606 0.67 0.66 0.69 0.12 0.70 0.79 S mg/kg D5453 23 26 24 16 25 22 RON - D2699 101 100 102 - 100 101 MON - D2700 89 89 90 - 88 88 (R + M)/2 - Calc. 95 95 96 - 94 94 C mass % D5291 mod. 82.09 81.08 82.05 57.74 82.66 80.41 H mass % D5291 mod. 12.18 13.85 12.50 12.80 13.83 12.45 O mass % D5599 5.5 5.5 5.2 27.19 3.7 7.2 Gross Heat of Combustion Btu/lb D4809 18,524 18,972 18,575 12,925 18,963 18,021 Toluene vol. % D3606 8.65 3.91 12.38 - 9.69 9.67
Water a mass % E-1064 0.084 0.088 0.088 0.93 <0.1 <0.1

Lead a g/l D3237 <0.003 <0.003 <0.003 - - <0.003 Copper Strip Corrosion a - D130 1A 1A 1A - 1A 1A
Solvent Washed Gum Content a mg/100ml D381 <0.5 0.5 <0.5 1.9 <0.5 0.5 Oxidation Stability a min. D525 >240 >240 >240 - >240 >240

a – inspection results from Haltermann

b – inspection results from EPA Fuels Round Robin study PROPERTY UNIT TEST METHOD

D86 (OptiDist or equivalent for

E10, E15 and

E20 fuels)REPORT 03.14295/03-51563E 

# APPENDIX B

FUEL ANALYSES SUMMARYREPORT 03.14295/03-51563E 

### B-1EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel1BatchNo.:WL1821GP04 WL1821GP04 WL1821GP04 WL1821GP04 WL1821GP04 WL1821GP04 1D 1D 1D 1DPRODUCTCODE:HF078‐1AnalysisDate:1/14/2009 1/12/2009 1/12/2009 1/9/2009 1/8/2009 1/7/2009 12/10/2008 12/10/2008 12/10/2008 12/10/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidist Optidist OptidistDistillation‐IBPASTMD86°F93.0 93.0 95.5 91.8 92.15% °F111.6 111.9 111.6 111.1 111.110% °F 110 115 120 116.7 116.7 116.6 116.4 116.320% °F120.0 123.4 123.1 123.7 123.530% °F 126 131 136 130.9 130.8 130.6 131.3 131.040% °F139.5 139.5 138.9 139.8 140.050% °F 144 148 152 148.7 148.1 147.7 148.3 148.560% °F170.5 171.8 164.5 177.1 173.170% °F 219 224 229 223.9 224.2 222.1 223.2 223.880% °F252.8 254.5 248.9 254.6 254.990% °F 295 300 305 298.5 299.6 296.8 300.2 299.195% °F333.6 334.1 329.7 334.4 334.5Distillation‐EP °F 437 366.3 366.3 362.5 368.3 366.0Recovery vol% Report98.5 97.8 97.8 97.4 98.4Residue vol% Report1.0 1.1 0.9 1.1 1.0Loss vol% Report0.5 1.1 1.3 1.5 0.6GravityASTMD4052°API Report 64.5 64.6 63.9SpecificGravityASTMD4052‐Report 0.7228 0.7215 0.7242ReidVaporPressureASTMD5191psi 9.85 10.00 10.15 9.90 9.98/9.99 8.00 9.91 10.08 9.95CarbonASTMD5291wtfraction Report 81.5HydrogenASTMD5291wtfraction Report 14.5OxygenASTMD5599wtfraction Report 3.7Oxygen,otherthenETOHASTMD5599vol% 0.10 <0.01EthanolcontentASTMD5599vol% 9.50 10.50 9.59WatercontentASTME1064mg/kg Report520SulfurASTMD5453ppmwt 20 30 34 32 24.6 24Composition,aromatics,correctedASTMD1319vol% 13.5 16.5 15.8 16.2 15.0 14.1 15.8Composition,olefins,correctedASTMD1319vol% 5.8 7.3 8.8 6.5 7.2 6.5 7.2 8.1Composition,saturates,correctedASTMD1319vol% Report 67.7 66.6 68.6 68.9 66.2BenzeneASTMD3606vol% 0.47 0.77 0.59 0.66Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report 94.8MotorOctaneNumberASTMD2700Report 87.3R+MD2699/270087.091.0Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17991.0ANALYST Paragon Core Dixie HP Inspectorate Gage Dixie Core Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-2EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel1BatchNo.:1C 1C 1B 1B 1A 1A 1APRODUCTCODE:HF078‐1AnalysisDate:11/26/2008 11/26/2008 11/11/2008 11/11/2008 11/3/2008 11/3/2008 11/3/2008 3/25/2008 3/24/2008 3/19/2008 3/12/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX Optidist Optidist2 Optidist1Distillation‐IBPASTMD86°F91.3 97.0 95.2 93.5 94.6 94.6 98.5 98.35% °F109.0 113.1 112.6 111.6 112.8 112.1 110.7 110.310% °F 110 115 120 114.7 118.4 117.9 117.3 118.3 117.9 105.2 114.820% °F121.9 125.5 125.1 124.6 125.0 124.6 121.3 121.530% °F 126 131 136 129.6 133.1 132.9 132.5 131.9 131.7 128.1 128.740% °F138.1 142.4 142.1 141.8 139.2 139.2 135.6 135.950% °F 144 148 152 147.1 152.3 152.1 151.8 146.8 146.5143.1 144.060% °F166.1 176.6 172.9 170.1 172.2 181.2 169.3 165.570% °F 219 224 229 219.5 229.7 228.0 229.3 217.3 231.3 218.3 219.680% °F252.8 257.3 256.0 255.0 250.2 273.7 267.4 267.490% °F 295 300 305 297.0 300.0 297.1 293.7 295.8 297.4 299.0 295.995% °F332.8 335.1 333.8 331.7 322.5 314.8 316.8 312.9Distillation‐EP °F 437 366.9 369.6 361.7 364.3 361.8 349.3 350.8 342.8Recovery vol% Report 97.2 98 97.9 97.6 97.8 97.7 97.3 97.3Residue vol% Report 1.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.7 1.0 1.1 1.4 1.2 1.3 1.7 1.7GravityASTMD4052°API Report 64.2 64.1 64.0 60.2 60.2 61.6 61.2SpecificGravityASTMD4052‐Report 0.7229 0.7235 0.7238 0.7382 0.7382 0.7330 0.7345ReidVaporPressureASTMD5191psi 9.85 10.00 10.15 10.03 10.21 10.24 9.90 9.90 10.1110.60CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.5010.28 10.28 9.70WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 30 21Composition,aromatics,correctedASTMD1319vol% 13.5 16.5 14.7 15.2 14.5 14.9 16.2 17.1 16.1 14.9 14.912.4 17.3Composition,olefins,correctedASTMD1319vol% 5.8 7.3 8.8 5.5 7.8 7.7 7.1 6.7 7.5 6.5 7.2 7.2 7.55.4Composition,saturates,correctedASTMD1319vol% Report 69.9 67.1 67.9 68.0 67.1 65.4 67.9 77.9 77.9 80.1 67.5BenzeneASTMD3606vol% 0.47 0.77 0.67Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699Report93.4 91.990.4MotorOctaneNumberASTMD2700Report83.2 83.582.0R+MD2699/270087.088.3 87.786.2Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Dixie JB/INS JB JB Core Inspectorate JB HVD HVD HVD HVDNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-3EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel2BatchNo.:WK0521GP14 WK0521GP14 WK0521GP14 WK0521GP14 2E 2D 2C HB#9 HB#8 HB#7 HB#6 HB#5 HB#4 HB#3 HB#2 HB#1PRODUCTCODE:HF0678‐2AnalysisDate:11/26/2008 11/20/2008 11/18/2008 11/12/2008 10/24/2008 10/20/2008 10/13/2008 3/26/2008 3/26/2008 3/25/2008 3/25/2008 3/24/2008 3/19/2008 3/13/2008 3/13/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 79.3 87.0 82.0 90.5 82.8 85.6 92.1 82.0 82.0 95.0 89.9 82.4 96.0 93.8 91.85% °F 99.2 107.8 97.0 93.2 103.4 104.7 112.7 102.7 102.7 113.2 106.3 97.5 111.9 112.4 106.010% °F 114 119 124 116.4 123.4 117.0 115.9 118.8 119.6 128.5 118.0 118.0 127.5 117.5 109.7 122.7 122.7 118.320% °F 150.9 157.0 152.0 148.1 151.0 150.9 158.2 149.6 149.6 163.6 140.7 135.7 143.9 142.3 138.130% °F 184 189 194 189.0 194.8 190.0 185.4 188.8 186.8 197.7 192.8 192.8 204.8 170.7 169.4 169.0 166.0 162.140% °F 217.8 223.3 218.0 216.1 218.2 218.0 225.4 224.0 224.0 230.1 205.4 205.6 199.4 193.9 190.350% °F 234 238 242 236.6 241.2 237.0 235.4 237.9 239.8 237.0 238.0 238.0 243.0230.2 231.7 226.7 219.8 217.360% °F 251.8 256.6 253.0 250.5 253.9 257.8 248.2 248.5 248.5 253.1 242.2 246.7 243.9 237.9 235.570% °F 268 273 278 271.0 275.4 271.0 269.4 272.7 280.1 258.2 260.9 260.9 266.9 254.0 260.6 257.3 252.9 248.580% °F 304.6 309.9 306.0 302.7 305.6 312.4 274.1 284.3 284.3 293.2 269.5 282.0 279.3 276.4 265.190% °F 335 340 345 337.5 344.5 342.0 323.1 339.4 338.0 325.9 344.2 344.2349.6 311.1 332.6 330.9 334.7 300.395% °F 351.0 357.0 356.0 338.7 352.5 349.2 361.2 367.4 367.4 368.8 355.0 355.6 355.6 358.7 324.5Distillation‐EP °F 437 375.2 381.4 373.0 375.3 371.9 368.4 388.8 392.3 392.3 390.4 388.1 386.5 387.6 392.0 364.3Recovery vol% Report 97.3 97.3 97.0 95.1 97.2 97.2 96.9 97.5 97.5 96.8 97.3 96.6 96.8 97.9 96.3Residue vol% Report 1.1 1.1 1.2 0.9 1.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.6 1.6 1.8 4.0 1.7 1.8 2.1 1.5 1.5 2.2 1.7 2.4 2.2 1.1 2.7GravityASTMD4052°API Report 64.4 64.4 64.5 63.6 64.3 64.9 64.9 63.2 65.5 65.5 65.4 66.0SpecificGravityASTMD4052‐Report 0.7227 0.7222 0.7221 0.7251 0.7227 0.7205 0.7205 0.7268 0.7183 0.7183 0.7185 0.7163 1.0760ReidVaporPressureASTMD5191psi 9.90 10.05 10.20 9.98 10.15 10.20 10.05 10.3900 9.81009.24 11.20 11.20 9.60 10.90 11.48 9.8010.0910.20CarbonASTMD5291wtfraction Report 84.5HydrogenASTMD5291wtfraction Report 15.5OxygenASTMD5599wtfraction Report <0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 0.05 <0.01WatercontentASTME1064mg/kg Report 51SulfurASTMD5453ppmwt 20 30 25 18.28 23 22Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14.2 14.1 15.0 14.2 14.615.0 14.5 14.5 14.5Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 6.3 5.7 6.5 7.4 5.55.8 7.3 7.3 7.3Composition,saturatesASTMD1319vol% Report 79.5 80.2 78.5 78.4 79.979.2 78.2 78.2 78.2BenzeneASTMD3606vol% 0.47 0.77 0.46 0.25 0.29Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report 96.1 96.3 95.6 91.692.4 93.5 93.5MotorOctaneNumberASTMD2700Report 88.4 88.9 88.4 85.185.2 86.2 86.2R+MD2699/270087.092.3 92.6 92.0 88.488.8 89.9 89.9Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 18745ANALYST INS JB Dixie Gage JB JB JB HVD HVD HVD HVD HVD HVD HVD HVDNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-4EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel3BatchNo.:XB0921GP01 XB0921GP01 XB0921GP01 XB0921GP01 XB0921GP01 XB0921GP01 XB0921GP01 XB0921GP01 3G 3G 3G 3G 3FPRODUCTCODE:HF0678‐3AnalysisDate:2/26/2009 2/25/2009 2/23/2009 2/16/2009 2/16/2009 2/13/2009 2/16/2009 2/10/2009 2/2/2009 1/30/2009 1/30/2009 1/29/2009 1/23/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXOptidistOptidistOptidistDistillation‐IBPASTMD86°F 108.3 106.7 107.9 109118.8109.1 110.35% °F 136.1 135.6 137.0 135.9137.5136.0 136.010% °F 136 141 146 141.5 141.4 142.1 141.7141.8141.3 141.620% °F 148.5 148.7 149.1 145.4149148.4 148.630% °F 149 154 159 154.5 154.7 155.3 154.5155.5153.8 154.740% °F 175.5 174.8 182.6 182.5182.7179.3 179.150% °F 215 219 223 216.8 216.8 218.0 218.5218.1219.9 219.060% °F 229.8 231.1 231.8 232.7231.8232.7 234.770% °F 242 247 252 244.4 242.9 243.9 244.9241.3246.3 246.880% °F 258.5 247.7 258.1 259.5259262.3 261.290% °F 295 300 305 297.1 293.7 294.5 296.1293300.9 299.195% °F 333.2 332.7 328.8 334329.9336.0 334.5Distillation‐EP °F 437 373.5 566.4 365.2 372.8370.9372.6 368.7Recovery vol% Report 98.8 98.9 97.7 98.198.197.2 98.3Residue vol% Report 1.0 1.0 1.0 1.00.91.1 1.0Loss vol% Report 0.2 0.1 1.3 0.911.7 0.7GravityASTMD4052°API Report60.660.860.3SpecificGravityASTMD4052‐Report0.7360.7380ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.76 6.48 6.326.346.42 6.31CarbonASTMD5291wtfraction Report81HydrogenASTMD5291wtfraction Report14.4OxygenASTMD5599wtfraction Report3.5Oxygen,otherthenETOHASTMD5599vol% 0.10<0.01EthanolcontentASTMD5599vol% 9.50 10.0 10.50 10.15 9.40WatercontentASTME1064mg/kg Report514.00SulfurASTMD5453ppmwt 20 25 302317.7124Composition,aromatics,correctedASTMD1319vol% 13.8 15.3 16.8 14.6 15.7 15.3 15.3 15.3Composition,olefins,correctedASTMD1319vol% 5.3 6.8 8.3 6.8 7.8 6.2 7.3 6.7Composition,saturates,correctedASTMD1319vol% Report68.7 66.5 68.5 67.4 68.0BenzeneASTMD3606vol% 0.47 0.62 0.77 0.54 0.33Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD269997.7MotorOctaneNumberASTMD270086.9R+MD2699/270087.092.3Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17567ANALYST INS JAM Dixie Core Dixie INS JB Gage Core Dixie INS JB CoreNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-5EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel3BatchNo.:3F 3F 3F 3E 3E 3E 3E 3E 3E 3E 3D 3D 3D 3D 3C 3CPRODUCTCODE:HF0678‐3AnalysisDate:1/23/2009 1/23/2009 1/22/2009 12/30/2008 12/28/2008 12/26/2008 12/22/2008 12/22/2008 12/24/2008 12/22/2008 12/10/2008 12/10/2008 12/10/200812/10/2008 11/26/2008 11/26/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTSMIN TARGET MAX OptidistOptidistOptidistOptidistOptidistOptidistOptidistDistillation‐IBPASTMD86°F110.1 109.6 113.2 111.9 108.5 109.4 102 106.5 107.45% °F136.8 136.4 137.8 138.4 137.3 137.1 132.3 133.6 134.410% °F 136 141 146 142 142.0 142.5 145.0 142.3 142.3 138.5 139.6 140.320% °F148.8 148.9 149.7 150.1 149.2 149.4 147 147.6 147.530% °F 149 154 159 154.2 154.9 156.4 156.3 156.2 155.8 153.9 154.5 151.340% °F181 180.7 190.6 196.4 193.8 186.0 174.2 176.3 172.850% °F 215 219 223 219.6 219.1 221.4223.5222.4 220.5 218.3 220.8 214.760% °F232.5 233.6 230.5 235.1 236.1 235.2 233.1 231.5 228.170% °F 242 247 252 245.1 245.1 241.5 243.6 243.0 247.2 246.4 247.2 244.880% °F259.2 260.4 264.2 264.0 268.7 257.4 261.2 261.4 25890% °F 295 300 305 295.3294.7 305.1 310.8313.2 301.0 298.5 301.1 298.395% °F331.5 332.3 341.1 347.8 350.6 337.8 334.1 334.4 331.2Distillation‐EP °F 437 369.9 372.7 372.4 373.3 437.4 375.6 370.9 372.9 372.4Recovery vol% Report 97.6 98.6 98.4 97.5 97.7 98.8 98.1 98.3 97.6Residue vol% Report 1.0 1.0 1.0 1.1 1.1 1.1 1.0 1.0 1.0Loss vol% Report 1.4 0.4 0.6 1.4 1.2 0.1 0.9 0.7 1.4GravityASTMD4052°API Report 60.2 60.4 60.4 60.1 60.4 60.5SpecificGravityASTMD4052‐Report 0.7380 0.73720.7384 0.7372 0.7369ReidVaporPressureASTMD5191psi 6.65 6.80 6.956.44 6.37 6.24 6.24 6.32 6.416.84 6.83 6.58 6.28CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.0 10.509.9Cal 9.9CalWatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 25 3025Composition,aromatics,correctedASTMD1319vol% 13.8 15.3 16.8 16.0 15.0 15.0 15.8 14.9 13.8 15.4 15.1 14.9Composition,olefins,correctedASTMD1319vol% 5.3 6.8 8.3 7.7 6.1 6.1 7.2 6.3 7.8 8.1 6.4 7.4Composition,saturates,correctedASTMD1319vol% Report 66.2 69.0 69.0 67.1 68.9 68.5 66.6 68.6 67.8BenzeneASTMD3606vol% 0.47 0.62 0.770.35Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Dixie INS JB JB INS Core Core Dixie Inpectorate JB Dixie Core Inspectorate JB Dixie JB/INSNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-6EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel3BatchNo.:3B 3B 3A 3A 3A HB#5 HB#4 HB#3 HB#2 HB#1 HB#2Old HB#1OldPRODUCTCODE:HF0678‐3AnalysisDate:11/11/2008 11/11/2008 11/3/2008 11/3/2008 11/3/2008 4/1/2008 4/2/2008 4/1/2008 3/31/2008 3/27/2008 3/11/2008 3/10/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX Optidist1Distillation‐IBPASTMD86°F108.2 109.6 108.2 105.5 105.3 104.1 87.1 91.0 91.55% °F135.9 134.0 132.4 132.9 131.4 128.4 108.4 128.1 123.110% °F 136 141 146 141.7 141.6 138.5 138.6 137.1 134.9 118.7 138.6 133.420% °F150.1 150.1 146.5 146.5 145.4 145.2 134.7 155.3 149.530% °F 149 154 159 157.1 157.8 153.3 153.9 152.4 154.1 148.4 175.4 170.440% °F175.2 177.1 178.4 179.7 173.2 173.7 157.9 199.9 197.250% °F 215 219 223 222.8 222.2 219.6 219.6 219.9233.8 230.3220.8 220.660% °F238.6 237.6 233.6 232.1 235.4 249.2 252.4 233.3 234.670% °F 242 247 252 249.1 249.8 246.3 244.9 249.5 263.1 266.5 243.7 246.080% °F264.4 262.2 265.1 260.9 270.8 280.0 288.3 259.8 262.790% °F 295 300 305 301.6 288.4 299.0292.5 311.1 309.0 317.8295.9306.095% °F339.9 326.5 324.8 322.3 329.5 326.6 328.9 324.6 329.8Distillation‐EP °F 437 378.2 367.7 355.5 355.5 356.7 356.6 351.5 366.6 369.1Recovery vol% Report 98.7 96.6 97.7 98.3 98.2 98.5 97.4 98.4 98.4Residue vol% Report 1.0 1.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 0.3 2.3 1.3 0.7 0.8 0.5 1.6 0.6 0.6GravityASTMD4052°API Report 60.8 60.1 59.5 59.7 60.8 62.8 65.6 66.2SpecificGravityASTMD4052‐Report 0.736 0.7384 0.7409 0.7399 0.7360 0.7283 0.7178 0.7159ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.78 6.68 6.776.88 7.30 10.907.10 7.40CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.0 10.509.70 9.70 9.70 9.70WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 25 30 22Composition,aromatics,correctedASTMD1319vol% 13.8 15.3 16.8 14.3 14.7 15.6 16.0 16.1 14.9 14.9 14.9 14.4 13.6 14.3 14.3Composition,olefins,correctedASTMD1319vol% 5.3 6.8 8.3 6.5 6.5 6.6 7.8 6.4 8.0 8.0 8.0 5.85.39.3 6.7Composition,saturates,correctedASTMD1319vol% Report 69.2 68.8 67.9 66.2 68.0 67.4 67.4 67.4 79.8 81.1 76.4 78.9BenzeneASTMD3606vol% 0.47 0.62 0.77 0.34Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD269999.2 93.2 93.7 94.595.2MotorOctaneNumberASTMD270088.7 84.8 85.587.5 87.6R+MD2699/270087.094.0 89.0 89.6 91.091.4Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Dixie JB Core Inspectorate JB HVD HVD HVD HVD HVD HVD HVDNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-7EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel4BatchNo.:WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP01 WL0121GP014A 4AHB#2 HB#1PRODUCTCODE:HF0678‐4AnalysisDate:1/15/2009 12/26/2008 12/26/2008 12/20/2008 12/19/2008 12/12/2008 12/12/2008 12/12/200812/10/2008 12/10/2008 12/3/2008 11/25/2008 11/11/2008 11/11/2008 3/31/2008 3/27/2008TEST METHOD UNITS SPECIFICATIONS Results Results Results Results Results Results Results Results Results Results Results ResultsMIN TARGET MAX optidist optidist optidist optidist optidist OptidistOptidist2 Optidist1Distillation‐IBPASTMD86°F90.7 88.7 88.0 92.4 86.1 88.6 92.0 97.9 93.4 94.2 96.4 87.15% °F112.8 116.9 116.3 113.7 113.1 112.4 110.0 111.7 115.5 115.9 113.9 108.410% °F 121 126 131 124.0 126.9 126.7 124.1 123.7 122.7 124.0 121.8 126.1 126.2 121.4 118.720% °F139.0 141.4 141.6 139.6 139.0 138.6 140.0 138.4 142.0 142.1 134.8 134.730% °F 149 154 159 150.6 152.0 152.4 150.9 150.3 150.0 151.0 150.4 153.8 153.9 146.6 148.440% °F157.8 164.2 165.5 161.0 157.8 158.7 158.0 157.1 161.9 162.4 155.8 157.950% °F 215 219 223 218.6 225.4 225.1 218.7 216.5 214.6 216.0 215.8 218.4 218.8 219.0 230.360% °F239.2 242.7 247.7 243.9 240.0 237.1 247.0 241.9 247.1 248.0 250.3 252.470% °F 265 270 275 266.5 272.7 269.3 267.3 259.8 264.6 268.0 262.8 269.8 269.6 273.2 266.580% °F301.8 308.1 309.9 302.4 296.6 294.9 302.0 297.0 301.7 302.8 302.5 288.390% °F 334 339 344 336.2 340.7 342.3 336.1 335.5 334.7 338.0 336.2 339.9 338.9 343.5 317.895% °F350.4 356.4 358.7 350.1 350.0 350.1 355.0 350.4 355.6 355.2 359.3 328.9Distillation‐EP °F 437 368.8 370.1 370.2 369.1 371.0 370.3 375.0 370.8 375.7 375.6 385.4 351.5Recovery vol% Report 97 97.1 97.3 97.3 97.5 97.2 97.3 96.6 97.5 97.5 97.6 97.4Residue vol% Report 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.0 1.0Loss vol% Report 1.9 1.8 1.6 1.6 1.4 1.7 1.6 2.3 1.4 1.4 1.4 1.6GravityASTMD4052°API Report 60.761.4 61.4 61.4 61.0 61.5 62.8SpecificGravityASTMD4052‐Report 0.73610.7340 0.7340 0.7337 0.7352 0.7332 0.7283ReidVaporPressureASTMD5191psi 9.95 10.10 10.25 9.95 9.93 10.00 10.01 10.10 10.05 10.10 9.96 10.90CarbonASTMD5291wtfraction Report78.5HydrogenASTMD5291wtfraction Report15.3OxygenASTMD5599wtfraction Report3.6Oxygen,otherthenETOHASTMD5599wtfraction 0.10<0.01EthanolcontentASTMD5599wt% 9.50 10.50 10.0210.31 9.70WatercontentASTME1064mg/kg Report633656SulfurASTMD5453ppmwt 20 25 30 3023 22 22Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 16.0 15.115.4 14.8 16.5 14.8 15.5 16.0 13.6Composition,olefinsASTMD1319vol% 4.6 6.1 7.6 6.1 6.16.6 6.0 11.1 6.0 6.2 7.85.3Composition,saturatesASTMD1319vol% Report 67.9 68.668.1 69.6 57.5 69.2 68.3 76.2 81.1BenzeneASTMD3606vol% 0.47 0.77 5.100.51 0.40 0.44Existentgum,washedASTMD381mg/100mls 5.01.5ResearchOctaneNumberASTMD2699Report97.2 94.3 93.7MotorOctaneNumberASTMD2700Report87.5 85.1 85.5R+MD2699/270087.092.3 89.7 89.6Corrosion,CopperASTMD13011aOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17918ANALYST Inspectorate JB INS INS JB Core Inspectorate Dixie Inspectorate JB Dixie Gage JB JB HVD HVDNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-8EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel5BatchNo.:XB2321GP01 XB2321GP01 XB2321GP01 XB2321GP01 XB2321GP01 XB2321GP01 5ReBlendB 5ReBlendB 5ReBlendB 5ReBlendBPRODUCTCODE:HF0678‐5AnalysisDate:3/3/2009 3/4/2009 3/2/2009 3/4/2009 2/27/2009 2/26/2009 1/7/2009 1/7/2009 1/7/2009 1/7/2009ShipmentDate:TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX797optidist optidistDistillation‐IBPASTMD86°F89.9 93.593.5 925% °F125.3 126.7130.5 12710% °F 141 146 151 142.4 143.5146.9 144.720% °F170.4 170.3174.9 173.130% °F 196 201 206 197.7 198.2201.7 200.640% °F220.3 221.2223.1 222.850% °F 234 238 242 235.4 236.4238.0 237.560% °F247.2 247.2248.1 247.570% °F 254 259 264 257.8 258258.5 259.280% °F271.8 272.3273.8 274.190% °F 296 301 306 299.7 298.1300.5 300.695% °F322 323.1323.2 323.8Distillation‐EP °F 437 354.3 356.6353.5 354.9Recovery vol% Report 98.5 98.197.8 98.2Residue vol% Report 1.0 1.01.0 1.0Loss vol% Report 0.5 0.91.2 0.8GravityASTMD4052°API Report55.054.8SpecificGravityASTMD4052‐Report0.75850.7595ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.9200 6.76 6.85 6.34 6.88 6.76CarbonASTMD5291wtfraction Report 86HydrogenASTMD5291wtfraction Report 13.6OxygenASTMD5599wtfraction Report <0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 0.05 <0.01WatercontentASTME1064mg/kg Report43SulfurASTMD5453ppmwt 20 30 26Composition,aromaticsASTMD1319vol% 33.5 35.0 36.5 34 34.8 34.0 34.9Composition,olefinsASTMD1319vol% 5.0 6.5 8.0 5.7 7.1 6.3 6.8Composition,saturatesASTMD1319vol% Report 60.3 58.1 59.7 58.3BenzeneASTMD3606vol% 0.47 0.77 0.48Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report 97.2MotorOctaneNumberASTMD2700Report 86.1R+MD2699/270087.0 91.7Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240 >240NetHeatofCombustionASTMD4809‐ABTU/lb Report 18346ANALYST Core Dixie Inspectorate JB Gage Gage Dixie Core Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-9EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel5BatchNo.:WC1121GP02 WC1121GP02 WC1121GP02 WC1121GP02 labblend#6 LB5 LB4 LB3 labblend#2PRODUCTCODE:HF0678‐5AnalysisDate:5/23/2008 4/18/2008 4/9/2008 4/9/2008 2/28/2008 2/26/2008 2/25/2008 2/22/2008 2/20/2008ShipmentDate:TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 95 95 99 99 99 100 102 97 1005% °F 125 125 131 128 131 136 136 131 12910% °F 141 146 151 144 144 148 147 146 150 151 145 14520% °F 172 172 175 174 170 173 174 169 17430% °F 196 201 206 200 200 203 201 198 198 198 195 20540% °F 227 227 228 226 225 220 220 217 23250% °F 234 238 242 244 244 242 241 242 233 233 231 25160% °F 254 254 252 253 253 243 242 241 26970% °F 254 259 264 266 266 263 263 264 253 251 250 26780% °F 278 278 277 277 278 267 266 265 31990% °F 296 301 306 298 298 297 297 298 300 300 300 32995% °F 316 316 315 316 319 323 325 326 335Distillation‐EP °F 437 373 373 352 356 355 358 361 363 362Recovery vol% Report 99 99 98.5 98.5 97.6 97.8 97.8 98.4 97.9Residue vol% Report 0.8 0.8 0.9 0.9 1.0 1.0 1.0 1.0 1.0Loss vol% Report 0.2 0.2 0.6 0.6 1.4 1.2 1.2 0.6 1.1GravityASTMD4052°API Report53.0 53.9 53.8 52.2 52.9 52.7SpecificGravityASTMD4052‐Report0.7672 0.7633 0.7636 0.7704 0.7675 0.7694ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.79 6.49 5.74 6.50 5.96 5.92 7.01 6.58CarbonASTMD5291wtfraction Report86.9HydrogenASTMD5291wtfraction Report12.7OxygenASTMD5599wtfraction Report<0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 0.01EthanolcontentASTMD5599wt% 0.05 <0.01WatercontentASTME1064mg/kg Report52SulfurASTMD5453ppmwt 20 30 23 23 21 9 8Composition,aromaticsASTMD1319vol% 33.5 35.0 36.5 38.6 38.3 38.9 39.8 41.5 45.7 46.3 40.8Composition,olefinsASTMD1319vol% 5.0 6.5 8.0 5.7 5.7 6.8 5.3 6.9 6.5 6.6 5.5Composition,saturatesASTMD1319vol% Report 56.0 56.0 54.3 54.9 51.6 47.8 47.1 53.7BenzeneASTMD3606vol% 0.47 0.77 0.54 0.54 0.44 0.38 0.84 0.40Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report94.0 92.5MotorOctaneNumberASTMD2700Report84.7 83.8R+MD2699/270087.089.4 88.2Corrosion,CopperASTMD1301 1aOxidationstabilityASTMD525minutes 240 >240 >240 >240 220.0NetHeatofCombustionASTMD4809‐ABTU/lb Report 18417 18417 18417ANALYST Dixie Dixie Dixie Dixie JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-10EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel6BatchNo.:XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01PRODUCTCODE:HF0678‐6AnalysisDate:3/11/2009 3/11/2009 3/11/2009 3/6/2009 3/6/2009 3/6/2009 3/5/2009 2/26/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 108.6 106.4 106.1 105.3 107.6 107 102.55% °F 131.3 130.7 129.3 127 128.9 128.8 129.410% °F 131 136 141 136.3 135.7 135 133.9 134.7 134.5 13520% °F 142.7 142.4 141.9 140.7 141.7 141.6 142.130% °F 142 147 152 148.5 147.9 147.5 147.7 147.4 147.5 146.940% °F 153.8 153 152.7 151.9 152.5 151.9 151.750% °F 187 191 195 191.7 189.4 185.6 180.3 185.5 185.3 187.460% °F 229.5 230.3 225.3 222.4 224.7 226.8 226.470% °F 264 269 274 269.6 270.7 264.8 261.9 264.6 265.5 266.380% °F 313.5 313.2 306.8 305.8 308.2 304 310.790% °F 336 341 346 342.4 342.2 338.7 338.2 339.4 339.5 340.495% °F 354.9 354.5 350.6 349.5 350.4 351.1 352.8Distillation‐EP °F 369.7 370.1 367.4 366.1 368.4 370.5 368.5Recovery vol% Report 97.9 97.6 98.3 97.4 98.0 98.0 98.1Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.1 1.4 0.7 1.6 1.0 1.0 0.9GravityASTMD4052°API ReportSpecificGravityASTMD4052‐ReportReidVaporPressureASTMD5191psi 6.70 6.85 7.007.14 7.18CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 30Composition,aromatics,correctedASTMD1319vol% 13.5 15.0 16.5Composition,olefins,correctedASTMD1319vol% 5.5 7.0 8.5Composition,saturates,correctedASTMD1319vol% ReportBenzeneASTMD3606vol% 0.47 0.62 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699ReportMotorOctaneNumberASTMD2700ReportR+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Saybolt Insp JAM Insp JB JB Gage InspNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-11EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel6BatchNo.:XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01 XA0821GP01PRODUCTCODE:HF0678‐6AnalysisDate:2/5/2009 2/3/2009 2/4/2009 1/21/2009 1/21/2009 1/22/2009 1/20/2009 1/20/2009 1/19/2009 1/16/2009 1/14/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX bz,rvp,etoh recheck optidist optidistDistillation‐IBPASTMD86°F 102.3114.3 109.4 110.9 109.95% °F 125.7136.2 132.6 131.9 132.410% °F 131 136 141 133138.9 137.5 136.5 136.820% °F 140.3144.7 143.4 141.9 142.230% °F 142 147 152 146.4154.22 148.8 146.7 147.440% °F 151.2170.6 153 151.3 152.250% °F 187 191 195 181.3196.5 199 194.6 19860% °F 221.1233.2 235 230.7 233.470% °F 264 269 274 260273.4 274.5 269.4 270.180% °F 305.5315.1 315.1 309.3 312.690% °F 336 341 346 339.3343 343.4 338.9 341.495% °F 350.5355.6 356 352.2 351.3Distillation‐EP °F 365.2367.5 370.8 375.5 374.9Recovery vol% Report 96.997.2 97.5 98.4 98.1Residue vol% Report 1.11.0 1.0 1.0 1.2Loss vol% Report 2.01.8 1.5 0.6 0.7GravityASTMD4052°API Report61.1SpecificGravityASTMD4052‐Report0.735ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 7.22 7.14 6.666.96 6.56CarbonASTMD5291wtfraction Report81.3HydrogenASTMD5291wtfraction Report15.2OxygenASTMD5599wtfraction Report3.4Oxygen,otherthenETOHASTMD5599vol% 0.100.01EthanolcontentASTMD5599vol% 9.50 10.50 9.97 9.13WatercontentASTME1064mg/kg Report575.00SulfurASTMD5453ppmwt 20 3022 27 18Composition,aromatics,correctedASTMD1319vol% 13.5 15.0 16.5 15.1 15.6Composition,olefins,correctedASTMD1319vol% 5.5 7.0 8.5 8.1 7.7Composition,saturates,correctedASTMD1319vol% Report66.8 66.7BenzeneASTMD3606vol% 0.47 0.62 0.77 0.61 0.19Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD2699Report95.8MotorOctaneNumberASTMD2700Report85.6R+MD2699/270087.090.7Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17950.0ANALYST Insp Dixie Gage Core Dixie Inspectorate Inspectorate JB Paragon Gage GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-12EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel6BatchNo.:6D 6D 6D 6D 6C 6C 6C 6C 6B 6B 6A 6APRODUCTCODE:HF0678‐6AnalysisDate:12/22/2008 12/22/2008 12/24/2008 12/22/2008 12/15/2008 12/10/2008 12/10/2008 12/10/2008 11/26/2008 11/26/2008 11/11/2008 11/11/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX D86re‐check Optidist Optidist OptidistOptidist2Distillation‐IBPASTMD86°F110.2 110.3 109.7 120.3 111.1 109.9 107.35% °F129.8 131.0 131.5 133.6 130.4 130.2 132.110% °F 131 136 141 135.3 135.7 135.6 137.6 134.7 135.2 137.720% °F141.2 142.1 140.7 142.8 140.4 140.9 144.430% °F 142 147 152 146.9 147.4 146 147.5 145.8 146.4 150.440% °F152.1 151.6 151.5 151.3 150.8 150.6 156.650% °F 187 191 195 189.8 191.4 179.9 188.6 182 184.3 195.860% °F228.3 229.8 220.2 225 221 217.0 229.270% °F 264 269 274 268.0 269.5 259.6 262.3 259 250.8 260.780% °F308.3 312.0 302.8 304.2 303.8 294.8 300.490% °F 336 341 346 340.6 341.5 337.3 338 338.2 335.9 339.895% °F351.3 353.4 349.4 349.2 351.1 350.3 354.5Distillation‐EP °F372.3 379.6 369.7 387.1 371.9 369.1 373.6Recovery vol% Report 97.2 98.3 98.1 98.8 98.1 97.2 98.2Residue vol% Report 1.0 1.0 1.0 0.1 1.1 1.1 1.1Loss vol% Report 1.8 0.7 0.9 1.1 0.8 1.7 0.7GravityASTMD4052°API Report60.7 61.22 61.1 60.3SpecificGravityASTMD4052‐Report0.736 0.734 0.735 0.7377ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 6.66 6.76 6.82 6.75 6.96 6.68 6.57 7.0600CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50 9.9calWatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 3021Composition,aromatics,correctedASTMD1319vol% 13.5 15.0 16.5 15.2 14.5 15 13.6 15.3 14.9 15.4 15.6 14.9Composition,olefins,correctedASTMD1319vol% 5.5 7.0 8.5 6.1 7.5 6.6 7.4 8.1 6.2 7.3 6.8 7.1Composition,saturates,correctedASTMD1319vol% Report 68.7 68.1 68.6 68.7 66.7 69 67.4 67.6 68BenzeneASTMD3606vol% 0.47 0.62 0.770.47Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699ReportMotorOctaneNumberASTMD2700ReportR+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Dixie Inspectorate JB Inspectorate Core Inspectorate JB Dixie JB/INS Dixie JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-13EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel7BatchNo.:WK0521GP13 WK0521GP13 WK0521GP13 WK0521GP13 WK0521GP13 WK0521GP13 7EPRODUCTCODE:HF0678‐7AnalysisDate:12/12/2008 11/18/2008 11/26/200811/20/2008 11/18/2008 11/12/2008 10/20/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 100.0 97.5 105.0 100.0 104.0 100.75%°F 128.0 124.3 132.0 125.0 130.6 127.810%°F 132 137 142 137.0 134.9 141.0 136.0 138.2 137.120%°F 149.0 147.8 153.0 148.0 149.4 149.430%°F 157 162 167 161.0 160.2 165.0 161.0 161.8 162.340%°F 177.0 175.6 180.0 176.0 176.2 177.050%°F 189 193 197 193.0 192.3 196.0 192.0 192.6 192.860%°F 210.0 209.9 214.0 209.0 209.7 209.970%°F 224 229 234 229.0 228.6 232.0 228.0 228.0 228.880%°F 252.0 250.8 255.0 251.0 150.9 252.590%°F 296 301 306 297.0 299.8 302.0 298.0 298.4 300.595%°F 329.0 328.7 333.0 329.0 329.5 332.4Distillation‐EP°F 437 359.0 365.5 363.0 360.0 357.6 359.2Recovery vol% Report 97.9 97.5 97.8 98.5 98.3 97.8Residue vol% Report 0.8 1.1 1.1 1.0 1.0 1.1Loss vol% Report 1.3 1.4 1.1 0.5 0.7 1.1GravityASTMD4052°API Report 64.7 64.7 64.6 64.7SpecificGravityASTMD4052‐Report 0.721 0.722 0.722 0.721ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 7.32 7.09 6.87 7.20 6.98 6.92CarbonASTMD5291wtfraction Report 85.04 84.7HydrogenASTMD5291wtfraction Report 14.38 15.3OxygenASTMD5599wtfraction Report <0.1 <0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.1 <0.01EthanolcontentASTMD5599wt% 0.05 <0.1 <0.01WatercontentASTME1064mg/kg Report50 ttbdSulfurASTMD5453ppmwt 20 30 23 24 19 18 21.00Composition,aromaticsASTMD1319vol% 14.0 16.5 18.016.7 17.6 15.516Composition,olefinsASTMD1319vol% 6.3 7.8 9.37.3 7.1 6.88.1Composition,saturatesASTMD1319vol% Report76 75.3 77.775.7BenzeneASTMD3606vol% 0.47 0.770.55 0.51 0.440.52Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD2699Report92.1 91.290.6MotorOctaneNumberASTMD2700Report84.7 84.283.9(R+M)/2D2699/270087.088.4 87.787.3Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 18813 18722.0ANALYST SWRI Dixie INS JB Dixie Gage JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-14EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel7BatchNo.:labblend#11 labblend#10 labblend#9 labblend#8 labblend#7 labblend#6 labblend#5 labblend#4 labblend#3 labblend#2 labblend#1PRODUCTCODE:HF0678‐7AnalysisDate:3/26/2008 3/24/2008 3/20/2008 3/13/2008 3/12/2008 2/28/2008 2/28/2008 2/22/2008 2/20/2008 2/18/2008 2/14/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXsubmittoSWRIDistcurvefix submitforre‐checkDistillation‐IBPASTMD86°F 101 101 100 102 102 99 99 99 98 94 1155% °F 131 135 129 130 133 130 130 133 133 128 14810% °F 132 137 142 143 145 140 141 143 140 140 142 144 141 16120% °F 157 158 155 156 156 154 154 155 159 160 17930% °F 157 162 167 171 171 169 170 170 167 167 168 175 178 19540% °F 183 184 184 186 184 181 181 182 191 193 20750% °F 189 193 197 196 197 197 200 196.1 194 194 195.3 205 205 21860% °F 208 209 211 215 207 206 206 207 216 213 22970% °F 224 229 234 223 224 228 236 220 219 219 219 228 220 24480% °F 251 253 254 267 244 240 240 242 249 229 27490% °F 296 301 306 300 305 304 311 314 296 296 298 304 249 32395% °F 325 329 329 338 344 330 330 332 335 305 338Distillation‐EP °F 437 368 370 370 380 384 372 372 372 377 379 372Recovery vol% Report 96.7 97.9 96.6 97.2 98.1 97.5 97.5 98.9 98.2 97.8 98.5Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.5 1.0Loss vol% Report 2.3 1.1 2.4 1.8 0.9 1.5 1.5 0.1 0.8 0.7 0.5GravityASTMD4052°API Report 60.4 61.4 61.8 61.8 61.8 62.9 63.7 61.2SpecificGravityASTMD4052‐Report 0.738 0.733 0.732 0.732 0.7319 0.7277 0.7248 0.7345ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 6.50 6.50 6.83 6.80 7.04 7.10 6.70 7.80 6.30CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 0.05WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 309Composition,aromaticsASTMD1319vol% 14.0 16.5 18.0 17.6 16.0 15.9 15.9 15.3 14.2Composition,olefinsASTMD1319vol% 6.3 7.8 9.3 6.0 7.4 7.1 7.1 5.9 6.4Composition,saturatesASTMD1319vol% Report 76.4 76.677 78.8 79.4BenzeneASTMD3606vol% 0.47 0.770.50 0.39Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699Report92.3 92.0MotorOctaneNumberASTMD2700Report84.7 84.2(R+M)/2D2699/270087.088.5 88.1Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST JB JB JB JB JB DixieSvcs JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-15EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel8BatchNo.:WJ1521GP01 WJ1521GP01 WJ1521GP01 WJ1521GP01 WJ1521GP01 WJ1521GP01 8C 8B 8B(Run2) 8BPRODUCTCODE:HF0678‐8AnalysisDate:10/24/2008 10/24/2008 10/22/2008 10/21/2008 10/21/200810/16/2008 10/6/2008 10/3/2008 10/2/2008 10/2/20088C 8B 8B(Run2) 8BTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXRun2 Run1 Optidist Optidist OptidistDistillation‐IBPASTMD86°F88.3 83.0 84.0 90.3 87.0 86.0 82.05% °F105.4 99.0 100.0 104.4 108.0 107.0 104.010% °F 118 123 128 120.7 118.0 118.0 119.8 123.0 121.0 118.020% °F148.3 149.0 148.0 147.7 150.0 148.0 145.030% °F 175 180 185 178.0 179.0 178.0 177.3 180.0 178.0 176.040% °F202.3 203.0 203.0 202.1 204.0 202.0 201.050% °F 217 221 225 219.2 221.0 220.0 219.0 221.0 219.0 218.060% °F232.2 233.0 234.0 232.3 234.0 233.0 232.070% °F 241 246 251 245.1 246.0 245.0 244.2 246.0 244.0 244.080% °F261.1 264.0 263.0 261.5 263.0 260.0 260.090% °F 296 301 306 300.2 301.0 302.0 300.6 301.0 296.0 296.095% °F326.7 331.0 330.0 326.7 330.0 329.0 325.0Distillation‐EP °F 437 357.8 361.0 363.0 360.3 356.0 355.0 357.0Recovery vol% Report 96.2 96.1 96.7 96.4 97.6 97.4 96.7Residue vol% Report 1.0 1.2 1.1 1.0 1.0 1.0 1.1Loss vol% Report 2.8 2.1 2.2 2.6 1.4 1.6 2.2GravityASTMD4052°API Report 65.1 65.2 65.2 65.2 65.2 65.2SpecificGravityASTMD4052‐Report 0.7196 0.7197 0.7193 0.7200 0.7190 0.7190ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 10.28 10.22 10.17 10.1510.33 10.33CarbonASTMD5291wtfraction Report85.2 84.9HydrogenASTMD5291wtfraction Report14.8 14.6OxygenASTMD5599wtfraction Report<0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10<0.01EthanolcontentASTMD5599wt% 0.05<0.01SulfurASTMD5453ppmwt 20 25 30 26 19Composition,aromaticsASTMD1319vol% 14.4 15.9 17.4 15.9 15.3 15.8 15.9 15.0 16.0 16.0Composition,olefinsASTMD1319vol% 5.8 7.3 8.8 6.5 5.1 5.5 7.3 6.4 6.8 6.8Composition,saturatesASTMD1319vol% Report 77.6 79.6 78.7 76.9 78.6 77.2 77.2BenzeneASTMD3606vol% 0.47 0.62 0.77 0.48 0.34 0.33Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD269991.0 95.095.5MotorOctaneNumberASTMD270083.0 87.087.6R+MD2699/270087.0 91.091.6Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report18959.0ANALYST Dixie Gage HP‐jam Dixie Dixie Gage JB Dixie JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-16EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel8BatchNo.:HB#8 HB#7 HB#6 HB#5 HB#4 HB#3 HB#2 HB#1PRODUCTCODE:HF0678‐8AnalysisDate:3/13/2008 3/12/2008 3/11/2008 3/5/2008 3/5/2008 3/4/2008 2/28/2008 2/26/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 91.8 89.7 89.8 91.8 89.3 91.7 91.2 88.45% °F 106.0 108.6 110.5 111.2 109.2 110.6 109.4 108.110% °F 118 123 128 118.3 118.9 119.9 120.3 119.3 120.2 119.2 117.820% °F 138.1 136.2 136.5 138.0 137.4 137.7 135.8 133.130% °F 175 180 185 162.1 158.1 157.4 159.9 160.8 159.0 156.8 151.340% °F 190.3 186.1 184.5 188.7 191.6 187.1 184.4 173.250% °F 217 221 225 217.3214.1 212.4216.4 219.2212.7 212.0 196.460% °F 235.5 232.0 230.8 232.4 234.1 227.5 228.6 210.670% °F 241 246 251 248.5 243.9 243.9 244.4 245.6 238.2 240.4 218.780% °F 265.1 259.8 260.6 260.8 263.5 251.9 258.7 226.290% °F 296 301 306 300.3 299.2 302.1 303.1307.5 290.0 305.5 238.895% °F 324.5 325.9 327.3 328.6 330.6 324.0 327.7 256.7Distillation‐EP °F 437 364.3 363.0 365.4 366.1 366.1 362.1 362.8 311.5Recovery vol% Report 96.3 97.5 97.7 97.9 97.6 97.7 97.3 97.2Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 2.7 1.5 1.3 1.1 1.4 1.3 1.7 1.8GravityASTMD4052°API Report 67.4 67.1 67.9 67.6 68.1 68.3 68.4SpecificGravityASTMD4052‐Report 1.0760 0.7114 0.7125 0.7098 0.7107 0.7091 0.7082 0.7079ReidVaporPressureASTMD5191psi 10.00 10.15 10.3010.20 10.509.90 10.05 9.86 10.14 10.08 10.11CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 0.05SulfurASTMD5453ppmwt 20 25 30Composition,aromaticsASTMD1319vol% 14.4 15.9 17.4 14.5 14.5 13.6 13.7 14.0 13.8 15.2Composition,olefinsASTMD1319vol% 5.8 7.3 8.8 7.3 7.3 6.4 5.5 6.04.87.9Composition,saturatesASTMD1319vol% Report 78.2 78.2 80.0 80.8 80.0 81.4 76.9BenzeneASTMD3606vol% 0.47 0.62 0.77 0.21Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD269991.0 95.0 93.5 94.3 94.5 93.8 94.495.292.7MotorOctaneNumberASTMD270083.0 87.0 86.2 86.9 87.887.7 87.6 88.186.6R+MD2699/270087.0 91.0 89.9 90.691.290.8 91.091.789.7Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST HVD HVD HVD HVD HVD HVD HVD HVDNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-17EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel9BatchNo.:WK0521GP05 WK0521GP05 9G labblend13 labblend13 labblend12 labblend12 labblend11 labblend11 labblend10 labblend10PRODUCTCODE:HF0678‐9AnalysisDate:11/20/2008 11/18/2008 10/27/2008 8/27/2008 8/27/2008 8/27/2008 8/27/2008 8/27/2008 8/27/2008 8/27/2008 8/27/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 83.9 85.0 83.1 86 90 86.9 90 86 91.2 86 90.45% °F 104.8 103.0 105.3 106.7 113 98.6 113 104.9 113.3 107.6 112.810% °F 158 114.1 115.0 115.0 117.5 121 114.3 122 117.5 122.1 117.5 121.820% °F 130.0 131.0 130.8 135.5 137 133.3 138 135.5 139.1 135.5 138.330% °F 146.8 149.0 148.2 154.4 155 153.3 156 155.3 157.6 155.3 156.840% °F 167.7 169.0 168.5 175.1 175 174.9 176 175.1 177.4 175.1 176.850% °F 186 194 192.5 194.0 192.6 194.9 194.7 194.7 194.7 196.7 196.4 194.9 195.760% °F 225.0 227.0 223.2 214.7 214 214.3 213 215.6 215.5 215.6 214.870% °F 260.5 261.0 259.2 244.4 243 243 241 245.3 244.9 246.2 244.380% °F 293.0 290.0 292.7 289.4 289 284.7 285 289.4 289.5 290.3 289.790% °F 335 345 341.9 344.0 342.8 339.8 338 337.8 334.8 334.4 334.5 340.7 337.495% °F 362.8 365.0 364.9 364.1 361 362.7 358 360.5 356.2 363.2 360.3Distillation‐EP °F 379.8 387.0 379.2 395.6 383 379.9 383.4 397.4 379.6 402.8 382.5Recovery vol% Report 97.6 97.8 97.8 99.0 98.7 94.6 99.9 99.0 99.0 99.0 98.8Residue vol% Report 1.1 0.9 1.1 0.5 1.0 1.1 0.1 0.4 1.0 0.6 0.0Loss vol% Report 1.3 1.3 1.1 0.5 0.3 4.3 0.0 0.6 0.0 0.4 0.3GravityASTMD4052°API Report 58.3 58.3 52.45 53.80 52.03 52.07SpecificGravityASTMD4052‐Report 0.746 0.746 0.769 0.764 0.771 0.771ReidVaporPressureASTMD5191psi 9.85 10.15 10.02 10.32 10.02 9.88 9.94 9.86 9.88CarbonASTMD5291wtfraction Report 84HydrogenASTMD5291wtfraction Report 14OxygenASTMD5599wtfraction Report <0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 0.05 <0.01SulfurASTMD5453ppmwt 20 30 20 23Composition,aromaticsASTMD1319vol% 38.5 41.5 35.7 35.4 40.37 37.3 40.8 41.4Composition,olefinsASTMD1319vol% 5.5 8.5 36.4 5.5 7.1 5.88 6.3 6.5 7.0Composition,saturatesASTMD1319vol% Report 6.0 58.8 57.5 53.8 56.4 52.7 51.6BenzeneASTMD3606vol% 0.47 0.77 57.6 0.37 0.42Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD269991.0 95.0 94.6 94.0 96.7 96.7MotorOctaneNumberASTMD270083.0 87.0 85.3 84.7 84.3R+MD2699/270087.0 91.0 90.0 89.4 90.5Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240 >240NetHeatofCombustionASTMD4809‐ABTU/lb Report 18424.0ANALYST Dixie JB Dixie JB JB JB Dixie JB Dixie JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-18EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel9BatchNo.:labblend9 labblend9 labblend9 labblend8 labblend7 labblend6 labblend5 labblend4 labblend3 labblend2 labblend1PRODUCTCODE:HF0678‐9AnalysisDate:8/22/2008 8/22/2008 8/22/2008 3/24/2008 3/20/2008 3/18/2008 3/3/2008 2/29/2008 2/28/2008 2/25/2008 2/22/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 86 84.9 87.7 86 90 89 83 86 87 88 835% °F 99.5 101.7 105.7 107 108 108 105 105 105 107 10310% °F 158 109.4 110.1 114 117 118 119 115 117 116 122 11620% °F 123.8 124 126.5 133 134 135 132 134 135 148 14530% °F 141.8 140.2 142.9 152 153 153 150 155 157 175 17940% °F 165.2 164.7 166.9 172 173 173 172 177 181 197 20950% °F 186 194 199.4 199.4 203 192 192 193 192 197.4 202 217 23560% °F 243.5 243.9 245.8 211 211 213 212 218 225 245 26270% °F 279.5 279 280.1 240 241 241 247 259 263 290 30480% °F 304.7 303.4 304 287 287 285 306 310 312 339 35890% °F 335 345 323.6 330.6 331.1 336 340 329 339 338 338 361 37595% °F 351.5 350.8 350.9 359 363 350 351 350 351 373 381Distillation‐EP °F 382.1 373.3 375.7 388 391 381 377 378 377 395 396Recovery vol% Report 98.0 97.5 98.7 97.4 97.0 97.7 97.4 96.6 97.0 96.9 97.1Residue vol% Report 0.9 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.1 1.5 0.3 1.6 2.0 1.3 1.6 2.4 2.0 2.1 1.9GravityASTMD4052°API Report 55.37 52.66 52.30 52.89 52.95 51.02 52.44SpecificGravityASTMD4052‐Report 0.7572 0.7684 0.769 0.767 0.7671 0.7753 0.7693ReidVaporPressureASTMD5191psi 9.85 10.15 10.22 10.25 10.15 10.08 10.39 9.97 10.49CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 0.05SulfurASTMD5453ppmwt 20 3024 10Composition,aromaticsASTMD1319vol% 38.5 41.5 43.6 40.5 36.2 41.3 43.1 43.8Composition,olefinsASTMD1319vol% 5.5 8.5 5.3 5.7 5.3 4.8 5.47 6.3Composition,saturatesASTMD1319vol% Report 51.153.9 51.4 49.9BenzeneASTMD3606vol% 0.47 0.770.48 0.41Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD269991.0 95.096.2 92.4MotorOctaneNumberASTMD270083.0 87.083.7 81.7R+MD2699/270087.0 91.090.0 87.1Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Dixie JB JB JB JB JB JB/Dixie JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-19EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel10BatchNo.:XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02PRODUCTCODE:HF0678‐10(TR1166)AnalysisDate:4/13/2009 4/11/2009 4/9/2009 4/8/2009 4/7/2009 4/7/2009 4/6/2009 4/2/2009 4/2/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX 958 797 958 958Distillation‐IBPASTMD86°F 107.4 104.4 111.4 105.6 105.4 108.5 114.1 110.55% °F 129.1 130.5 128.1 129.4 128.7 139.5 134.7 128.710% °F 132 137 142 135.9 136.1 134.4 135.7 135.3 140 139.6 135.520% °F 144.1 144.1 142.9 143.8 143.8 145.9 146.1 144.930% °F 146 151 156 151.1 150.8 149.7 150.9 150.6 151.9 152.6 152.240% °F 162.5 160.1 156.7 161 160.8 172 167.4 163.450% °F 217 221 225 217.2 217.9 215.8 215.8 215.7 230.2 223.2 22660% °F 261.3 261.9 260.2 261.5 261.5 269.8 265.9 266.270% °F 289 294 299 291.1 292.5 290.7 287.8 290.6 297.1 293.9 293.980% °F 317.2 317.7 317.1 315.5 316.7 322 319 318.490% °F 337 342 347 339.2 340.5 340 339.4 340.3 343.8 341.4 340.295% °F 355.3 353.8 352 351.9 354.1 357.3 354.8 353.5Distillation‐EP °F 437 375.7 371.3 373.5 371.6 375.6 373.5 377.4 369.1Recovery vol% Report 97.9 98.5 97.9 98.7 97.9 98.6 98.4 98Residue vol% Report 1.0 1.0 0.9 1.0 1.1 1.0 1.0 1.0Loss vol% Report 1.1 0.5 1.2 0.3 1 0.4 0.6 1GravityASTMD4052°API Report52.9SpecificGravityASTMD4052‐Report0.7655ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 7.06 6.87 6.95 6.96CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50 9.83SulfurASTMD5453ppmwt 20 30 25 26 26Composition,aromatics,correctedASTMD1319vol% 33.8 35.3 36.834.2Composition,olefins,correctedASTMD1319vol% 4.9 6.4 7.96.6Composition,saturates,correctedASTMD1319vol% Report49.2BenzeneASTMD3606vol% 0.47 0.77 0.50Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportLeadASTMD3237g/L ReportANALYST HP Inpectorate Gage Dixie JB JB Gage JB GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-20EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel10BatchNo.:XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 XC2521GP02 10G 10G 10G 10GPRODUCTCODE:HF0678‐10(TR1166)AnalysisDate:3/31/2009 4/1/2009 3/31/2009 3/30/2009 3/30/2009 3/27/2009 3/13/2009 3/13/2009 3/12/2009 3/12/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX 797 958797Distillation‐IBPASTMD86°F109.2 111.6 111 115.5 107 108.65% °F133.3 133.5 132.6 133 131.7 13210% °F 132 137 142 138.6 138.7 138 138 137 137.220% °F146.6 145.8 145.7 145.4 144.1 144.730% °F 146 151 156 152.6 152.5 152.3 151.7 151.2 151.440% °F168.2 165.6 164.6 157.8 164.2 163.250% °F 217 221 225 227.8 226.3 225.8 227.8 220.5 221.560% °F270.8 268.1 267.8 267.8 266.1 26670% °F 289 294 299 296.3 293.3 293.7 294.3 294.4 29380% °F321.1 318.7 319 319.1 319.1 317.590% °F 337 342 347 343.5 340.5 341 341.1 343.2 340.895% °F358.2 353.8 354.2 354.9 357.7 354Distillation‐EP °F 437 369.9 371.8 371.9 372 372 371.1Recovery vol% Report 97.6 98.3 98 98.1 98.1 98.6Residue vol% Report 1.0 1.0 1.0 0.9 1.1 1.0Loss vol% Report 1.4 0.7 1 1 0.8 0.4GravityASTMD4052°API Report52.0 46.2 52.6SpecificGravityASTMD4052‐Report 0.7701 0.7711 0.7905 0.7686ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.18 6.07 6.15 6.42 6.26CarbonASTMD5291wtfraction Report 82.6HydrogenASTMD5291wtfraction Report 14OxygenASTMD5599wtfraction Report 3.6Oxygen,otherthenETOHASTMD5599vol% 0.10 <0.01EthanolcontentASTMD5599vol% 9.50 10.50 10.30SulfurASTMD5453ppmwt 20 30 21 19.66 25Composition,aromatics,correctedASTMD1319vol% 33.8 35.3 36.8 36.0 36.0 34.7 35.6Composition,olefins,correctedASTMD1319vol% 4.9 6.4 7.9 5.1 6.9 6 6.8Composition,saturates,correctedASTMD1319vol% Report 48.9 47.1 49.2 47.6BenzeneASTMD3606vol% 0.47 0.77 0.29Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD269999.7MotorOctaneNumberASTMD270086.7R+MD2699/270087.0 93.2Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240 >240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17528.0LeadASTMD3237g/L Report <0.003ANALYST Core Dixie Insp JB JB Gage Core Dixie Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-21EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel10BatchNo.:10F 10F 10F 10F 10E 10E 10E 10EPRODUCTCODE:HF0678‐10(TR1166)AnalysisDate:3/2/2009 3/2/2009 2/27/2009 2/27/2009 1/30/2009 1/30/2009 1/29/2009 1/29/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX 958Distillation‐IBPASTMD86°F105.4 111.8 111.5 111.45% °F129.6 131.1 132.4 132.310% °F 132 137 142 136.2 136.7 137.3 137.520% °F144 144.1 144.3 144.430% °F 146 151 156 150 150.7 150.5 151.140% °F156.2 161 159.4 162.350% °F 217 221 225 216.5 217.1 216.5 215.660% °F262.9 263.9 253.5 252.970% °F 289 294 299 293.4 288 279.0 279.280% °F318.6 318.4 308.0 306.490% °F 337 342 347 341.6 341.1 337.8 337.795% °F354.7 354.7 353.1 353.3Distillation‐EP °F 437 370 371.3 370.2 374.1Recovery vol% Report 98.6 98 97.4 98Residue vol% Report 1.0 1.0 1.1 1.1Loss vol% Report 0.4 1 1.5 0.9GravityASTMD4052°API Report52.7 52.7SpecificGravityASTMD4052‐Report0.7682 0.7681ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.48 6.286.51 6.42CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50SulfurASTMD5453ppmwt 20 30 23 23Composition,aromatics,correctedASTMD1319vol% 33.8 35.3 36.8 33.9 35.7 36 35.5Composition,olefins,correctedASTMD1319vol% 4.9 6.4 7.9 6.4 6.7 5.2 5.9Composition,saturates,correctedASTMD1319vol% Report 49.7 47.6 48.8 48.6BenzeneASTMD3606vol% 0.47 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportLeadASTMD3237g/L ReportANALYST Core Dixie Insp JB Core Dixie Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-22EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel10BatchNo.:10D 10D 10D 10D 10D 10D 10DPRODUCTCODE:HF0678‐10(TR1166)AnalysisDate:12/26/2008 12/23/2008 12/22/2008 12/22/2008 12/28/2008 12/22/2008 12/22/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXRecheck OptidistOptidistDistillation‐IBPASTMD86°F 108.9 101.8 107.2 117.4 107.95% °F 130.8 134.6 130.5 134.6 130.410% °F 132 137 142 136.4 139.4 136.0 139.4 135.920% °F 143.9 146.1 144.0 146.1 143.430% °F 146 151 156 151.0 152.4 151.0 152.4 150.840% °F 158.4 167.2 162.0 167.2 159.950% °F 217 221 225215.1 228.7223.1 228.7 217.560% °F 260.4 268.4 265.8 268.4 262.670% °F 289 294 299 291.0 296.4 293.6 296.4 291.480% °F 316.3 320.3 320.5 320.4 316.790% °F 337 342 347 339.7 341.7 344.0 341.7 340.795% °F 353.1 352.9 360.4 352.9 353.8Distillation‐EP °F 437 370.1 406.5 370.1 406.5 370.4Recovery vol% Report 98.6 98.0 97.1 98 98.2Residue vol% Report 1.0 1.0 1.1 1.0 1.1Loss vol% Report 0.4 1.0 1.8 1 0.7GravityASTMD4052°API Report 52.852.2SpecificGravityASTMD4052‐Report 0.76780.7703ReidVaporPressureASTMD5191psi 6.65 6.80 6.956.606.54 6.65CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50SulfurASTMD5453ppmwt 20 30Composition,aromatics,correctedASTMD1319vol% 33.8 35.3 36.8 35.9 36.3Composition,olefins,correctedASTMD1319vol% 4.9 6.4 7.9 3.9 5.9Composition,saturates,correctedASTMD1319vol% Report 50.3 47.9BenzeneASTMD3606vol% 0.47 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportLeadASTMD3237g/L ReportANALYST JB INS Core Dixie Inspectorate Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-23EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel10BatchNo.:10C 10C 10C 10C 10B 10B 10B 10A 10APRODUCTCODE:HF0678‐10(TR1166)AnalysisDate:12/16/2008 12/9/2008 12/9/2008 12/9/2008 11/26/2008 12/5/2008 11/26/2008 11/11/2008 11/11/2008re‐blendedTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX OptidistOptidistOptidistOptidistOptidistOptidist2 Optidist1Distillation‐IBPASTMD86°F 104.7 101.9 107.4 107.6 105.0 106.3 108.35% °F 127.2 125.5 127.6 132.4 130.6 134.1 134.610% °F 132 137 142 133.3 132.5 133.8 137.6 136.8 140.3 140.420% °F 141.1 141.3 141.6 145.7 144.7 149.1 149.430% °F 146 151 156 149 148.3 149.2 152.5 150.9 156.6 15740% °F 157.2 156 156.2 166.6 163.9 173 174.250% °F 217 221 225 207.6 205.8 206.9 217.3 213.8 227.9 228.660% °F 256.6 254.3 256.1 250.6 245.3 255.4 256.570% °F 289 294 299 288.3 287.1 288.1 278.3 276.3 279.5 279.880% °F 312.5 313.9 314.5 306.4 304.2 306.8 306.990% °F 337 342 347 335.9 337.8 338.6 336.6 334.0 337.6 337.295% °F 351.8 351.6 352.3 353.7 351.6 355 355.1Distillation‐EP °F 437 369.1 368.8 370.9 378.9 368.9 374.6 375Recovery vol% Report 98 97.6 97.9 98.5 97.5 98.5 98.8Residue vol% Report 1.0 1.0 1.0 1.1 1.1 1.0 1.0Loss vol% Report 1 1.4 1.1 0.4 1.4 0.5 0.2GravityASTMD4052°API Report52.6 52.1 52.0SpecificGravityASTMD4052‐Report0.7686 0.7708 0.7710ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 7.01 7.14 6.83 6.35 6.65CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50SulfurASTMD5453ppmwt 20 3022Composition,aromatics,correctedASTMD1319vol% 33.8 35.3 36.8 35.6 34.6 35.2 36.4 34.5 36.2Composition,olefins,correctedASTMD1319vol% 4.9 6.4 7.9 5.8 7.2 5.8 6.8 5.7 6Composition,saturates,correctedASTMD1319vol% Report 48.7 48.3 49.1 46.9 49.9 47.8BenzeneASTMD3606vol% 0.47 0.770.62Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportLeadASTMD3237g/L ReportANALYST JB Core Inspectorate JB Dixie JB JB/INS JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-24EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel11BatchNo.:XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02 XA0821GP02PRODUCTCODE:HF0678‐11AnalysisDate:2/18/2009 2/18/2009 2/17/2009 2/16/2009 2/5/20092/5/2009 2/5/2009 1/20/2009 1/20/2009 1/29/20091/20/2009 1/23/2009 1/20/2009 1/19/2009TEST METHOD UNITS SPECIFICATIONS Results Results Results Results Results Results Results Results Results Results Results Results Results ResultsMIN TARGET MAX HTC1 HTC2 958 797 S‐958 S‐958 S‐797 recheck Optidist recheck OptidistDistillation‐IBPASTMD86°F 92.7 91.2 94.2 90.8 87.5 85.6 85.2 92 86.5 91.4 86.7 87.15% °F 113.7 113.2 114.6 115.4 113.9 112.9 112.6 110 116.3 117.8 113.2 11210% °F 119 124 129 123.4 123.4 123.9 124.5 123.4 122.9 122.5 122 125.2 126.1 122.9 12220% °F 137.1 136.8 137.6 138.0 136.8 135.7 136.6 137 138.2 138.7 136.8 136.330% °F 143 148 153 147.2 147.4 148.2 148.1 147.5 147.0 147.3 148 148.8 148.9 147.2 147.540% °F 155.1 155.3 157.0 156.8 155.8 155.1 156.1 156 156.3 157.2 154.8 155.850% °F 186 190 194 188.6 188.4 190.0 189.8 187.3 185.6 187.7 190 195.9 196.8 187.5 185.460% °F 230.0 229.5 231.0 230.9 228.8 230.1 228.4 231 233.9 234.4 230.2 230.370% °F 245 250 255 250.2 249.3 251.0 251.8 251.5 252.1 251.3 252 253.2 253.8 250.2 251.980% °F 269.4 268.9 269.1 270.3 268.9 269.9 269.3 271 273.1 272.2 269.4 26790% °F 294 299 304 298.0 297.5 299.0 298.2 297.8 298.5 295.6 300 303.9 302.6 298.6 297.895% °F 323.4 323.1 325.5 324.7 323.4 325.1 323.8 329 337.4 333.7 325.5 324.4Distillation‐EP °F 437 358.0 358.7 358.6 357.8 358.7 359.2 357.8 361 368.5 358 355.4 359.4Recovery vol% Report 97.2 97.3 97.5 98.1 97.6 98.0 97.9 98 97.8 97.9 98 97.7Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.8 1.7 1.5 0.9 1.4 1.0 1.1 1 1.2 1.1 1 1.3GravityASTMD4052°API Report54.6SpecificGravityASTMD4052‐Report0.7608ReidVaporPressureASTMD5191psi 9.85 10.159.929.91CarbonASTMD5291wtfraction Report82.6HydrogenASTMD5291wtfraction Report13.6OxygenASTMD5599wtfraction Report3.5Oxygen,otherthenETOHASTMD5599vol% 0.10<0.01EthanolcontentASTMD5599vol% 9.50 10.509.69WatercontentASTME1064mg/kg Report551SulfurASTMD5453ppmwt 20 3027Composition,aromatics,correctedASTMD1319vol% 33.5 35.0 36.534.4 33.8 35.7Composition,olefins,correctedASTMD1319vol% 5.5 8.56.8 7.2 7.0Composition,saturates,correctedASTMD1319vol% Report48.9 49.1 47.3BenzeneASTMD3606vol% 0.47 0.770.50Existentgum,washedASTMD381mg/100mls 5.00.5ResearchOctaneNumberASTMD2699Report97.4MotorOctaneNumberASTMD2700Report85.0R+MD2699/270087.091.2Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17614.0ANALYST Insp Insp JB JB HP HP HP Core Dixie Insp Insp JB JB GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-25EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel11BatchNo.:11G 11G 11G 11G 11F 11F 11F 11E 11E 11D 11D 11C 11C 11C 11B 11APRODUCTCODE:HF0678‐11AnalysisDate:12/22/2008 12/22/2008 12/24/2008 12/22/2008 12/9/2008 12/9/2008 12/9/2008 11/26/2008 11/26/2008 11/11/2008 11/11/2008 11/3/2008 11/3/2008 11/3/2008 10/27/2008 10/22/2008TEST METHOD UNITS SPECIFICATIONS Results Results Results Results RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTSMIN TARGET MAX Optidist Optidist Optidist Optidist Optidist Optidist1Distillation‐IBPASTMD86°F91.2 92.1 89.3 93 88.6 96.5 94.9 86.4 91.45% °F113.2 114.9 113.7 113.6 111.1 116.4 120 109.1 108.810% °F 119 124 129 122.9 124.2 122.8 122.9 121.3 125.2 129.5 119.4 117.520% °F136.7 137.7 137.1 137.3 135.7 138.2 143.4 135.6 131.630% °F 143 148 153 147.3 148.4 148.3 148.4 146.7 148.7 154.4 148.7 144.240% °F156.0 156.4 155.9 157.7 155.3 157.2 164 158.5 154.650% °F 186 190 194 188.7 190.3 193.6 193.9 186.1 178.4 210.8 196.7 175.560% °F229.9 229.6 231.8 232.9 227.4 226 240.9 235.1 228.570% °F 245 250 255 250.1 250.3 250.5 251.1 247.9 252 258.2 251.2 246.980% °F269.0 269.8 269.6 269.3 267.7 273.4 276.2 267.3 26390% °F 294 299 304 298.0 300.3 298 299.7 295.5 303.4 306 297.5 292.495% °F326.1 327.8 325.9 328.1 322.1 331 333 325.8 319.6Distillation‐EP °F 437 360.9 360.6 358.6 362.7 357.7 365.9 364 362.6 359.6Recovery vol% Report 97.4 97.8 97.3 97.6 97.2 97.9 98.8 97.6 97.1Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.6 1.2 1.7 1.4 1.8 1.1 0.2 1.4 1.9GravityASTMD4052°API Report54.4 54.3 54.3 54.5 53.6 54.7 54.1SpecificGravityASTMD4052‐Report0.7612 0.7618 0.7618 0.7606 0.7643 0.7598 0.7623ReidVaporPressureASTMD5191psi 9.85 10.15 9.65 9.74 10.04 10.12 9.75 9.82 9.97 9.59 10.28 10.45CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.5010.50WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 3021Composition,aromatics,correctedASTMD1319vol% 33.5 35.0 36.5 34.7 35.7 35.1 33.5 35.7 36.3 34.4 35.5 35.1 36.0 35.4 37.5 36.2Composition,olefins,correctedASTMD1319vol% 5.5 8.5 5.5 5.8 6.3 6.9 5.9 6.5 5.5 6.7 6.2 6.6 6.4 6 6Composition,saturates,correctedASTMD1319vol% Report 49.9 48.6 48.7 49.6 48.5 47.3 50.1 47.8 48.7 47.4 48.2 46 47.3BenzeneASTMD3606vol% 0.47 0.770.57Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699ReportMotorOctaneNumberASTMD2700ReportR+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Dixie Inspectorate JB Core Inspectorate JB Dixie JB/INS JB JB Core Inspectorate JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-26EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel12BatchNo.:WL1821GP03 WL1821GP03 WL1821GP03 WL1821GP03 WL1821GP03 WL1821GP03 WL1821GP03 WL1821GP03 12C 12C 12C 12B 12B 12B 12B 12A 12APRODUCTCODE:HF078‐12AnalysisDate:1/16/2009 1/16/2009 1/12/2009 1/13/2009 1/9/2009 1/9/2009 1/7/2009 1/7/2009 12/9/2008 12/9/2008 12/9/2008 12/3/2008 12/3/2008 12/3/2008 12/3/2008 11/11/2008 11/11/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTS RESULTSMIN TARGET MAXrecheck optidist optidist optidist optidist Optidist2 Optidist1Distillation‐IBPASTMD86°F92.1 92.9 95.9 88.2 93.6 93.8 91.1 89.9 90.55% °F110.8 111.9 111.6 104.7 109 111.2 111.1 105.3 105.410% °F 109 114 119117.0 117.6 117.7 112.5 115.1 117.2 117.3 111.3 111.620% °F123.8 125.5 126.0 122.2 123.8 125.2 125.1 119.3 118.930% °F 126 131 136133.2 133.9 133.7 130.5 132.2 132.9 132.6 128.1 127.840% °F142.3 143.0 140.7 139.4 141.3 141.3 141.6 140 140.150% °F 147 151 155151.3 151.5 151.0 149.9 151.9 151 150 156.1 155.960% °F200.1 200.8 200.8 182.3 186.4 187.8 183.4 187.5 184.970% °F 267 272 277275.5 276.0 275.9 271.1 272.3 267.4 267.5 268.2 266.280% °F307.7 308.0 307.4 305.2 305.7 298.3 294.2 298.1 29690% °F 334 339 344340.1 339.4 339.3 337.8 339.2 330.4 330 333.1 330.895% °F357.5 357.0 357.1 357 357.3 349.4 348.9 352.5 351.8Distillation‐EP °F 437376.3 373.6 375.6 375.6 376.7 370 371.7 374.2 373.4Recovery vol% Report97.8 97.4 98.0 97.2 97.6 97.2 98.2 97.6 97.7Residue vol% Report1.1 1.1 0.8 1.1 1.1 1.1 1.0 1.1 1.0Loss vol% Report1.1 1.5 1.2 1.7 1.3 1.7 0.8 1.3 1.3GravityASTMD4052°API Report 56.7 56.3 56.4 56.5 56.4 58.9SpecificGravityASTMD4052‐Report 0.7520 0.7539 0.7529 0.7526 0.7529 0.7512ReidVaporPressureASTMD5191psi 9.85 10.00 10.15 10.10 9.99 9.54 9.57/9.56 8.70 10.33 10.31 10.04 9.5300 9.6800 9.3300 10.9300CarbonASTMD5291wtfraction Report82.2HydrogenASTMD5291wtfraction Report13.4OxygenASTMD5599wtfraction Report3.4Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 9.50 10.50 9.83WatercontentASTME1064mg/kg Report523.00SulfurASTMD5453ppmwt 20 30 21 16.421Composition,aromaticsASTMD1319vol% 33.5 35.0 36.5 34.6 37.3 36.7 35.3 33.3 36.4 32.8 35.3 36.8 34.3 36.2Composition,olefinsASTMD1319vol% 4.7 6.2 7.7 6.4 5.9 5.5 5.7 6.8 5.6 6 7.1 6 5.3 6Composition,saturatesASTMD1319vol% Report 49 46.8 47.8 49.1 49.9 48.1 51.3 47.7 48.1 50.4 47.8BenzeneASTMD3606vol% 0.47 0.77 0.52 0.200.39Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report99.9MotorOctaneNumberASTMD2700Report88.5R+MD2699/270087.094.2Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17663.0ANALYST Dixie Gage Core Dixie HP HP Inspectorate Gage Core Inspectorate JB Dixie Core Inspectorate JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-27EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel13BatchNo.:WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02 WJ1521GP02PRODUCTCODE:HF0678‐13AnalysisDate:11/26/2008 11/20/2008 11/13/2008 10/31/2008 10/30/2008 10/24/2008 10/22/2008 10/21/2008 10/21/2008 10/16/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTSRESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXOptidist OptidistRun2 Run1 OptiDistDistillation‐IBPASTMD86°F 93.8 93.2 99.0 97.0 99.9 99.0 99.0 97.25% °F 123.8 125.6 123.0 120.0 125.2 124.0 124.0 124.510% °F 131 136 141 137.6 137.9 137.0 135.0 136.9 137.0 136.0 136.420% °F 157.2 156.8 157.0 156.0 155.1 156.0 155.0 153.730% °F 169 174 179 176.6 176.8 177.0 176.0 174.2 176.0 175.0 174.040% °F 198.4 198.9 199.0 197.0 196.5 198.0 197.0 196.250% °F 215 219 223 221.1 221.0 222.0 219.0 220.6 222.0 222.0 219.960% °F 244.0 244.5 245.0 246.0 245.7 248.0 246.0 244.670% °F 267 272 277 268.4 269.2 270.0 272.0 271.9 275.0 273.0 270.980% °F 301.7 302.5 305.0 307.0 306.1 309.0 308.0 306.590% °F 333 338 343 336.7 337.2 337.0 339.0 338.2 340.0 340.0 338.995% °F 353.1 353.7 356.0 355.0 353.5 355.0 353.0 353.8Distillation‐EP °F 437 373.6 375.6 385.0 390.0 375.4 380.0 377.0 376.9Recovery vol% Report 97.5 97.7 98.5 98.4 97.5 98.5 98.5 97.4Residue vol% Report 1.1 1.1 0.9 0.8 1.0 1.1 1.1 0.9Loss vol% Report 1.4 1.2 0.6 0.8 1.5 0.5 0.5 1.7GravityASTMD4052°API Report 56.0 56.8 56.9‐56.9 56.9SpecificGravityASTMD4052‐Report 0.855 0.752 0.751‐0.752 0.751ReidVaporPressureASTMD5191psi 6.71 6.86 7.01 6.64 6.83 7.060 7.060 6.950 7.05 7.05 6.93CarbonASTMD5291wtfraction Report86.4‐86.5HydrogenASTMD5291wtfraction Report13.6‐13.5OxygenASTMD5599wtfraction Report<0.1‐<0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10<0.01‐<0.01EthanolcontentASTMD5599wt% 0.05<0.01‐<0.01SulfurASTMD5453ppmwt 20 25 3026‐20 13LeadASTMD3237g/l 0.01<0.001‐0.001Composition,aromaticsASTMD1319vol% 32.6 34.1 35.6 34.7 33.9 34.1 31.0 33.6 31.2 31.1Composition,olefinsASTMD1319vol% 4.8 6.3 7.8 6.5 5.2 6.0 7.1 6.8 5.4 5.7Composition,saturatesASTMD1319vol% Report 58.8 60.9 59.9 61.9 59.6 63.4 63.2BenzeneASTMD3606vol% 0.47 0.62 0.770.500 0.45 0.45Existentgum,washedASTMD381mg/100mls 5.01.500‐2.0ResearchOctaneNumberASTMD269991.0 95.095.800‐95.5MotorOctaneNumberASTMD270083.0 87.086.100‐86.5R+MD2699/270087.0 91.090.950‐91.0Corrosion,CopperASTMD13011A‐1AOxidationstabilityASTMD525minutes 240>240‐>240NetHeatofCombustionASTMD4809‐ABTU/lb Report18566.0‐18374.0ANALYST INS JB Dixie Dixie Dixie Gage HP‐jam Dixie Dixie GAGENOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-28EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel13BatchNo.:labblend#9 labblend#8 labblend#7 labblend#6a labblend#6 labblend#5 labblend#4 labblend#3 labblend#2 labblend#1PRODUCTCODE:HF0678‐13AnalysisDate:10/6/2008 10/3/2008 10/2/2008 3/13/2008 3/12/2008 3/4/2008 2/29/2008 2/28/2008 2/26/2008 2/25/2008 2/22/2008 2/20/2008 2/18/200813C 13B 13BTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXOptiDist OptiDist Dist.curvefixDistillation‐IBPASTMD86°F 97 94 106 103 98 98 91 93 91 86 905% °F 125 121 131 132 132 127 120 116 119 104 11610% °F 131 136 141 136 133 145 146 146 140 134 131 133 120 133.920% °F 155 153 167 166 167 162 159 155 160 148 17330% °F 169 174 179 174 174 189 185 187 183 184 181 190 187 20740% °F 195 197 210 202 204 202 205 205 218 224 22550% °F 215 219 223 219 222 230 218 219 218 222 226 239 248 237.860% °F 245 244 254 235 237 234 241 248 258 268 25070% °F 267 272 277 272 268 285 263 261 260 275 283 296 292 26680% °F 305 298 312 325 308 309 324 329 349 318 29990% °F 333 338 343 338 333 334 359 338 337 350 351 370 329 326.195% °F 354 352 349 372.8 352 350 364 366 378 334 333Distillation‐EP °F 437 373 375 376 385 378 377 389 390 398 358 364Recovery vol% Report 97.7 97.2 97.4 97.4 97.8 98.0 97.5 97.3 98.9 96.6 97.1Residue vol% Report 1.1 1.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.2 1.2 1.6 1.6 1.2 1.0 1.5 1.7 0.1 2.4 1.9GravityASTMD4052°API Report 56.9 55.6 51.9 53.45 53.3 52.8 54.0 54.1 54.1SpecificGravityASTMD4052‐Report 0.751 0.757 0.7715 0.7651 0.7659 0.7677 0.7627 0.7626 0.7622ReidVaporPressureASTMD5191psi 6.71 6.86 7.01 6.86 7.04 6.48 7.36 8.27 8.36 8.42 9.90 9.16CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 0.05SulfurASTMD5453ppmwt 20 25 30218.1 7.3LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 32.6 34.1 35.6 34.1 33.7 38.5 42.6 36.1 37.7 36.9 39.3 37.5 41.6 39.3Composition,olefinsASTMD1319vol% 4.8 6.3 7.8 6.3 5.4 6.3 7.0 5.0 4.4 4.7 4.3 3.7 4.9 3.1Composition,saturatesASTMD1319vol% Report 59.6 60.9 55.2 50.4 58.9 57.9 58.3 56.4 58.8 53.5 57.6BenzeneASTMD3606vol% 0.47 0.62 0.770.480.70 0.34Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD269991.0 95.093.6 91.2MotorOctaneNumberASTMD270083.0 87.083.5 82.0R+MD2699/270087.0 91.088.6 86.6Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST JB Dixie JB JB JB JB Dixie JB JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-29EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel14BatchNo.:WK0521GP07 WK0521GP07 WK0521GP07 WK0521GP07 WK0521GP07 14D 14D(a) 14D 14C 14C 14C LB#5 LB#4 LB#3 LB#2 LB#1PRODUCTCODE:HF0678‐14AnalysisDate:11/19/2008 11/26/2008 11/20/2008 11/19/2008 11/12/2008 10/29/2008 10/24/2008 10/20/2008 10/15/2008 10/15/2008 10/13/2008 3/13/2008 3/12/2008 3/11/2008 3/10/2008FIAre‐check OctanerecheckTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F97.4 105.0 101.0 103.1 102.5 103.1 100.8 100.6 101 101 104 97 985% °F122.7 131.0 123.0 126.3 128.8 123.8 128.5 121.4 128 128 132 126 12810% °F 132 137 142 132.9 139.0 134.0 134.6 137.1 134.6 136.7 133.8 137 137 142 136 13820% °F145.7 150.0 146.0 146.3 147.8 147.2 148.6 146.7 151 151 156 151 15130% °F 157 162 167 158.5 163.0 159.0 159.3 161.6 158.9 161.1 159.4 166 166 169 165 16640% °F174.0 178.0 174.0 174.0 176.7 174.2 175.6 173.8 183 183 182 180 18150% °F 188 192 196 191.6 196.2 193.0 191.7 192.1 190.4 191.8 190.1 199 199 195 194 19660% °F210.9 216.0 212.0 210.9 211.9 208.4 210.2 208.9 216 216 207 208 20970% °F 230 235 240 236.2 241.3 237.0 237.2 235.4 234.5 235.7 234.7 236 236 222 223 22380% °F279.5 283.0 281.0 279.1 278.0 280.4 278.4 276.9 270 270 249 252 25190% °F 333 338 434 337.1 343.0 338.0 338.2 337.7 338.0 337.9 337.1 330 330 330 347 31795% °F354.0 359.0 355.0 354.0 354.8 356.0 254.8 354.1 363 363 356 369 340Distillation‐EP °F 437 371.7 377.0 388.0 373.1 372.6 377.6 269.8 369.8 392 392 387 399 378Recovery vol% Report 97.2 98.3 98.5 97.7 98.3 98.1 98.1 95.6 98.1 98.1 97.5 97.1 97.9Residue vol% Report 1.1 1.1 0.9 1.0 1.1 1.1 1.1 1.1 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.7 0.6 0.6 1.3 0.6 0.8 0.8 3.3 0.9 0.9 1.5 1.9 1.1GravityASTMD4052°API Report64.3 64.3 64.2 64.1 60.9 61.7 62.2SpecificGravityASTMD4052‐Report0.723 0.723 0.723 0.723 0.7355 0.7320 0.7306ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 7.18 6.970 7.250 7.030 6.880 6.810 7.29 6.83 7.30 7.30CarbonASTMD5291wtfraction Report84.7HydrogenASTMD5291wtfraction Report15.3OxygenASTMD5599wtfraction Report<0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 0.05 <0.01WatercontentASTME1064mg/kg Report 50 tbdSulfurASTMD5453ppmwt 20 30 25 21 19 23 22LeadASTMD3237g/l 0.01 <0.001Composition,aromaticsASTMD1319vol% 15.0 16.5 18.0 16.5 17 16.9 16.1 16.4 16.3 16.3 16.1 21.4Composition,olefinsASTMD1319vol% 6.4 7.9 9.4 8.4 7.6 7.1 8.7 7.4 5.9 6.5 5.9 6.9Composition,saturatesASTMD1319vol% Report 75.1 75.4 76.0 75.3 76.2 77.8 77.2 78 71.7BenzeneASTMD3606vol% 0.47 0.77 0.49 0.42 0.49 0.55Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report91.5 91.1 90.0 89.5 91.0 92.6MotorOctaneNumberASTMD2700Report85.1 84.6 84.0 83.6 84.2 84.9R+MD2699/270087.088.3 87.9 87.0 86.6 87.6 88.8Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report18388ANALYST Dixie INS JB Dixie Gage JB Dixie JB Dixie JAM JB JB JB JB/Dixie JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-30EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel15BatchNo.:WK0521GP06 WK0521GP06 WK0521GP06 WK0521GP06 WK0521GP06 15F 15F 15E 15D 15D 15D LB#4 LB#3 LB#2 LB#1PRODUCTCODE:HF067‐15AnalysisDate:Report12/12 11/14/2008 11/25/2008 11/20/2008 11/14/2008 11/12/2008 10/27/2008 10/20/2008 10/15/2008 10/15/200810/13/2008 3/26/2008 3/24/2008 3/7/2008 3/5/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTSMIN TARGET MAXDistillation‐IBPASTMD86°F 80.0 84.0 82.0 88.6 84.0 91.6 83.9 84.3 88.7 83.2 88.4 90 90 87 895% °F 106.0 102.0 101.9 108.6 102.0 109.8 106.8 106.5 104.9 106.7 99.7 106 111 110 11210% °F 112 117 122 116.0 114.0 112.9 118.4 114.0 117.7 116.9 116.6 115.7 116.9 113.0 118 121 121 12220% °F 131.0 130.0 128.9 133.3 130.0 131.4 132.5 132.3 131.0 132.1 129.6 135 138 137 13930% °F 144 149 154 147.0 146.0 145.4 149.7 146.0 147.4 148.9 148.8 147.2 148.6 146.2 153 156 155 15740% °F 166.0 167.0 165.1 169.2 167.0 166.8 168.7 168.3 167.0 167.9 165.9 171 175 174 17550% °F 189 191 195 190.0 190.0 188.3 192.6 190.0 189.9 190.9 190.8 189.5 190.2 189.5 188 191 192 19260% °F 216.0 217.0 215.1 219.3 217.0 216.3 217.0 216.2 218.3 216.4 216.2 203 206 209 20570% °F 238 243 248 244.0 242.0 242.1 246.0 242.0 243.1 242.8 243.1 242.6 244.1 244.0 220 225 233 22080% °F 267.0 265.0 264.4 269.7 265.0 265.6 266.0 266.8 286.7 268.7 268.3 247 254 273 23990% °F 295 300 305 299.0 300.0 298.1 303.0 300.0 299.1 300.4 301.4 302.0 301.2 300.2 298 306 321 27795% °F 328.0 330.0 327.1 333.0 330.0 330.4 329.5 330.4 332.6 328.0 327.8 325 327 328 321Distillation‐EP °F 437 365.0 366.0 361.4 368.0 366.0 361.6 361.0 361.9 360.5 363.2 358.0 338 345 350 338Recovery vol% Report 97.8 98.0 96.9 97.8 98.0 98.1 98.3 98 98.1 98.1 95.1 95.8 97.5 97.2 97.5Residue vol% Report 0.8 0.9 1.0 1.0 0.9 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.4 1.0 2.1 1.2 1.0 0.9 0.7 1 0.8 0.8 3.9 3.2 1.5 1.8 1.5GravityASTMD4052°API Report 58.8 58.9 58.9 58.9 58.7 59.3 59.1 53.1 53.1 52.3 52.4SpecificGravityASTMD4052‐Report 0.7434 0.7437 0.7437 0.7433 0.7440 0.7416 0.7425 0.7665 0.7665 0.7699 0.7693ReidVaporPressureASTMD5191psi 9.85 10.00 10.15 10.06 10.16 10.02 10.34 10.18 10.00 9.87 9.74 9.95 9.95 9.66 9.63CarbonASTMD5291wtfraction Report 86.4 86.5 86.5HydrogenASTMD5291wtfraction Report 12.59 13.5 13.5OxygenASTMD5599wtfraction Report <0.1 <0.1 <0.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01 <0.01 <0.01EthanolcontentASTMD5599wt% 0.05 <0.01 <0.01 <0.01WatercontentASTME1064mg/kg Reportx 71 tbdSulfurASTMD5453ppmwt 20 30 22.9 25 21 18.24 25 23 22LeadASTMD3237g/l 0.01 x <0.001 <0.001Composition,aromaticsASTMD1319vol% 34.5 36.0 37.5 36.7 33.4 35.4 33.4 36.2 31.9 33.5 41.3 41.3 41.8 42.4Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 7.2 6.3 7 6.3 6.7 7 5.3 8.6 8.6 5.1 7.3Composition,saturatesASTMD1319vol% Report 60.3 60.3 57.6 60.3 57.1 61.1 61.2 52.5 52.5 52.5 7.3BenzeneASTMD3606vol% 0.47 0.77 0.49 0.49 0.49 0.6 0.58 0.65Existentgum,washedASTMD381mg/100mls 5.0 x 0.5 0.5ResearchOctaneNumberASTMD2699Report 94.7 94.9 94.9 94.5 93.6 93.296.7MotorOctaneNumberASTMD2700Report 84.9 85.2 85.2 84.8 84.2 83.984.0R+MD2699/270087.0 89.8 90.1 90.1 89.7 88.9 88.690.4Corrosion,CopperASTMD1301 x 1A 1AOxidationstabilityASTMD525minutes 240 x >240 >240NetHeatofCombustionASTMD4809‐ABTU/lb Report 18562 18379 18379ANALYST SwRI Dixie INS JB Dixie Gage JB JB Dixie JAM JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-31EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel16BatchNo.:XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 XA0821GP03 16G 16G 16G 16GPRODUCTCODE:HF0678‐16AnalysisDate:2/27/2009 2/19/2009 2/3/2009 1/30/2009 1/23/2009 1/20/2009 1/16/2009 1/16/2009 1/16/2009 12/22/2008 12/22/2008 12/24/2008 12/22/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXetohadj rvpadj rvpadj optidist optidist Optidist OptidistDistillation‐IBPASTMD86°F104.7 107.2 105.8 107.75% °F134.8 134.0 132.1 133.110% °F 134 144140.0 139.5 138.5 139.220% °F148.5 147.6 146.8 147.330% °F 150 160153.5 154.8 154.8 155.140% °F180.0 177.2 171.9 173.350% °F 216 224220.6 220.6 220.2 218.860% °F238.6 238.0 237.3 238.570% °F 246 256253.0 252.1 250.4 251.980% °F269.8 268.1 267.7 268.090% °F 295 305302.0 300.0 299.0 299.795% °F333.3 329.0 329.2 328.8Distillation‐EP °F 437364.5 367.8 366.7 360.7Recovery vol% Report98.3 98.5 97.8 98.4Residue vol% Report1.0 1.0 1.0 1.0Loss vol% Report0.7 0.5 1.2 0.6GravityASTMD4052°API Report53.4 53.2 53.1SpecificGravityASTMD4052‐Report0.7658 0.7659 0.7664ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 6.9500 6.8000 6.4700 6.2600 6.3400 6.5100 6.6300CarbonASTMD5291wtfraction Report79.7HydrogenASTMD5291wtfraction Report13.1OxygenASTMD5599wtfraction Report 3.73.4Oxygen,otherthenETOHASTMD5599vol% 0.10 <0.01<0.01EthanolcontentASTMD5599vol% 9.50 10.50 10.69 10.16 9.98 9.27 9.34WatercontentASTME1064mg/kg Report570.00SulfurASTMD5453ppmwt 20 3026Composition,aromatics,correctedASTMD1319vol% 33.5 35.0 36.534.6 35.6 36.2 34.6 35.5Composition,olefins,correctedASTMD1319vol% 5.5 8.56.6 5.9 5.5 5.2 6.7Composition,saturates,correctedASTMD1319vol% Report49.4 48.5 48.3 50.3 47.9BenzeneASTMD3606vol% 0.47 0.77 0.60 0.33Existentgum,washedASTMD381mg/100mls 5.01.0ResearchOctaneNumberASTMD2699Report100.8MotorOctaneNumberASTMD2700Report88.1R+MD2699/270087.094.4Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17567.0ANALYST Dixie Dixie Dixie Dixie Gage Dixie Core Insp JB Core Dixie Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-32EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel16BatchNo.:16F 16F 16F 16E 16E 16E 16D 16D 16C 16C 16C 16B 16APRODUCTCODE:HF0678‐16AnalysisDate:12/9/2008 12/9/2008 12/9/2008 11/26/2008 11/26/2008 11/26/2008 11/11/2008 11/11/2008 11/3/2008 11/3/2008 11/3/2008 10/27/2008 10/22/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXOptidist Optidist Optidist Optidist Optidist1 OptiDist OptiDist OptiDistDistillation‐IBPASTMD86°F102.7 110.2 106.7 103.0 110.4 108.7 103.6 104.75% °F131.5 131.8 130.9 131.1 135.1 136.1 129 130.210% °F 134 144 137.7 137.8 137.5 137.1 140.9 141.8 137 137.220% °F146.4 146.6 145.1 145.2 149.3 150.8 146.8 146.930% °F 150 160 153.2 154.8 151.9 152.4 157.1 158.7 155.3 155.240% °F171.2 171.8 163.4 160.6 172.4 179.9 174.1 171.950% °F 216 224 221.1 221.3 210.5 212.0 222.4 228.1 221.9 220.160% °F238.1 238.8 232.7 233.3 241.8 245 240 23870% °F 246 256 250.2 252 249.7 249.8 256.9 257.7 252.8 250.480% °F267.8 268 264.9 266.1 273 273.9 268.2 265.590% °F 295 305 298.3 299.6 297 296.3 301.6 302.6 297.1 294.695% °F326.3 329.6 324.9 323.6 328.6 330.9 324.9 322.6Distillation‐EP °F 437 365.5 367.7 360.5 359.7 364.3 361.5 359.2 361.2Recovery vol% Report 97.9 98.3 97.8 98.0 98.6 98.9 97.1 98.3Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.1 0.7 1.2 1.0 0.4 0.1 1.9 0.7GravityASTMD4052°API Report 53.1 53.4 52.5 52.7 52.8 53.7SpecificGravityASTMD4052‐Report 0.7666 0.7654 0.7690 0.7684 0.7677 0.7641ReidVaporPressureASTMD5191psi 6.70 6.85 7.00 6.8600 6.9600 6.7100 6.4700 6.7000 6.6500 6.8200 7.1200CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599vol% 0.10EthanolcontentASTMD5599vol% 9.50 10.50WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 302121Composition,aromatics,correctedASTMD1319vol% 33.5 35.0 36.5 34.5 33.5 35.8 34.0 35.6 33.9 35.4 34.8 34.3 34.8 38.7 35.1Composition,olefins,correctedASTMD1319vol% 5.5 8.5 6.1 7.9 6.3 6.7 7.4 6.0 6.3 6.2 7.6 6.5 6.6 6.8Composition,saturates,correctedASTMD1319vol% Report 49.5 48.7 48.0 49.5 47.1 50.0 48.3 49.0 48.2 48.7 44.2 47.6BenzeneASTMD3606vol% 0.47 0.770.620.39Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699Report98.7 101.2MotorOctaneNumberASTMD2700Report87.3 89.0R+MD2699/270087.093.0 95.1Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Inspectorate JB Dixie JB JB/INS Dixie JB Core Inspectorate JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-33EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel20BatchNo.:XA2121GP01 XA2121GP01 XA2121GP01 XA2121GP01 XA2121GP01 XA2121GP01 XA2121GP01PRODUCTCODE:TR1181AnalysisDate:2/13/2009 2/6/2009 2/8/2009 2/16/2009 2/6/2009 2/5/2009 2/4/2009recheckTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidist optidist(797)Distillation‐IBPASTMD86°F106.3 108.5 107.6 117.15% °F137.7 136.2 135.6 13810% °F 137 142 147 142.7 141.8 141.7 142.520% °F149.7 148.6 149.1 149.930% °F 150 155 160 155.3 154.6 155 155.540% °F159.4 158.6 159.3 159.850% °F 148 162 166 162.7 162 162.2 16360% °F186.3 179.4 176.8 175.170% °F 232 237 242 234 233.4 235.9 23580% °F252 254.4 253.7 251.490% °F 296 301 306 300.9 294.4 297.3 297.595% °F339.4 333.9 335.2 335.3Distillation‐EP °F 437 368.1 368.9 373.3 372.2Recovery vol% Report98.5 97.7 98.4 98.8Residue vol% Report1.0 1.1 1.0 1.0Loss vol% Report0.5 1.2 0.6 0.2GravityASTMD4052°API Report 59.00 58.84 59.02SpecificGravityASTMD4052‐Report 0.7431 0.7434 0.7427ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.66 6.57 6.57CarbonASTMD5291wtfraction Report 70.8HydrogenASTMD5291wtfraction Report 12.7OxygenASTMD5599wtfraction Report 7.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 0.03EthanolcontentASTMD5599wt% 19.50 20.50 20.33SulfurASTMD5453ppmwt 20 30 22 7.79LeadASTMD3237g/l 0.01 <0.0003Composition,aromaticsASTMD1319vol% 14.0 15.5 17.0 15.4 14.3Composition,olefinsASTMD1319vol% 5.7 7.2 8.7 6 7.2Composition,saturatesASTMD1319vol% Report 58.6 58.5BenzeneASTMD3606vol% 0.47 0.77 0.57 0.30Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699101.6MotorOctaneNumberASTMD270095.3R+MD2699/270087.089.0Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17,242ANALYST Dixie Core Dixie Insp Insp JB GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-34EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel20BatchNo.:20C 20C 20C 20C 20B 20B 20B 20B 20A 20A 20APRODUCTCODE:TR1181AnalysisDate:1/7/2009 1/7/2009 1/7/2009 1/7/2009 12/16/2008 12/16/2008 12/16/2008 12/16/2008 12/5/2008 12/5/2008 12/5/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidist optidist optidist optidist optidistDistillation‐IBPASTMD86°F109.4 106.9 106.1 107.3 103.1 109.15% °F137.3 135.9 135.5 134.2 133.5 135.210% °F 137 142 147 142.1 141.8 140.8 140.2 139.7 140.920% °F149.3 149.2 148.5 148.5 148.2 148.830% °F 150 155 160 154.8 155 155.2 154.6 153.9 154.540% °F158.8 159.5 159.6 159.4 158.7 159.350% °F 148 162 166 161.7 163.1 162.7 163.2 161.1 162.660% °F173.6 173 169.3 167.2 169 17170% °F 232 237 242 236.7 238 236.4 237.5 231 233.980% °F256.6 257.1 258.1 253.5 249 252.490% °F 296 301 306 300.8 301 298.5 300.1 291.9 292.695% °F335.6 337.8 337.1 337.7 331.4 332.7Distillation‐EP °F 437 369.8 371.7 375.3 374 372.1 371.1Recovery vol% Report 98.1 98.2 98.2 98.2 97.7 98.3Residue vol% Report 1.1 1.1 1.0 1.1 1.0 1.0Loss vol% Report 0.8 0.7 0.8 0.7 1.3 0.7GravityASTMD4052°API Report58.5 58.5 58.6SpecificGravityASTMD4052‐Report0.7449 0.7448 0.7443ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.6200 6.4500 6.8300 6.8500 6.7900 6.5800 6.7900 6.5500CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 19.50 20.50SulfurASTMD5453ppmwt 20 30LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 14.0 15.5 17.0 15.9 15.1 15 15 14.2 15.3 15.6 15.5Composition,olefinsASTMD1319vol% 5.7 7.2 8.7 6.48 7.9 5.8 6.2 8.2 6.3 6.4 7.9Composition,saturatesASTMD1319vol% Report 57.6 57 59.1 58.7 57.7 58.4 58 56.6BenzeneASTMD3606vol% 0.47 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Dixie Inpectorate JB Core Dixie Inpectorate JB Core Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-35EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel21BatchNo.:XB2321GP02 XB2321GP02 XB2321GP02 XB2321GP02 XB2321GP02 XB2321GP02 XB2321GP02 21A 21A 21A 21APRODUCTCODE:TR1182AnalysisDate:3/3/2009 2/27/2009 2/25/2009 2/26/20092/24/2009 2/24/2009 2/23/2009 1/7/20091/7/2009 1/7/2009 1/7/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX797 optidist optidistDistillation‐IBPASTMD86°F108.6 111.8 108.6 105.45% °F137.1 135.6 132.6 135.310% °F 136 141 146142.6 141.8 140.6 141.520% °F150.9 150.9 149.5 149.930% °F 152 157 162157.6 157.5 156.2 156.940% °F162.7 162.7 161.2 162.550% °F 163 167 171167.7 168.1 166 167.560% °F224.5 217.5 209 215.270% °F 250 255 260256.5 253.4 254.8 254.580% °F274.6 273.5 273.8 275.690% °F 298 303 308305.6 303.7 301.5 304.395% °F334.5 329.2 326.1 329.2Distillation‐EP °F 437361.9 359.4 356.7 359.5Recovery vol% Report98.4 98.4 97.8 98.6Residue vol% Report1.0 1.0 1.0 1.0Loss vol% Report0.6 0.6 1.2 0.4GravityASTMD4052°API Report50.5 50.550.3SpecificGravityASTMD4052‐Report0.7780 0.77750.7783ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.85 6.80 6.42 6.16 6.37 6.44 6.35CarbonASTMD5291wtfraction Report79.9HydrogenASTMD5291wtfraction Report12.9OxygenASTMD5599wtfraction Report7Oxygen,otherthenETOHASTMD5599wtfraction 0.10 <0.01EthanolcontentASTMD5599wt% 19.50 20.0 20.50 20.32SulfurASTMD5453ppmwt 20 30 27 16.8LeadASTMD3237g/l 0.01 0.009Composition,aromaticsASTMD1319vol% 35.0 36.5 38.0 35.0 37.0 35.5 37.3Composition,olefinsASTMD1319vol% 5.1 6.6 8.1 6.6 7.3 6.4 6.8Composition,saturatesASTMD1319vol% Report 38.3 35.7 38.1 35.9BenzeneASTMD3606vol% 0.47 0.77 0.52 0.41Existentgum,washedASTMD381mg/100mls 5.0 0.5ResearchOctaneNumberASTMD2699101.6MotorOctaneNumberASTMD270086.8R+MD2699/270087.094.2Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report16845.0ANALYST Dixie Gage Core Dixie Inspectorate JB Gage Core Dixie Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-36EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel22BatchNo.:WL2621GP02 WL2621GP02 WL2621GP02 WL2621GP02 WL2621GP02 WL2621GP02 WL2621GP02PRODUCTCODE:HF0678‐22AnalysisDate:1/27/2009 1/23/2009 1/15/2009 1/14/2009 1/23/2009 1/14/2009 1/14/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX rvpadj rvpadj recheck optidist optidistDistillation‐IBPASTMD86°F92.5 91.5 91.75%°F119.7 118.3 119.810%°F 122 127 132130.4 129 130.120%°F144.5 144 144.430%°F 147 152 157153.6 153 153.540%°F159.2 159 159.150%°F 158 162 166162.9 162.6 16260%°F168.2 165.9 165.570%°F 227 232 237234 232.7 233.780%°F254.9 253.3 254.490%°F 293 298 303296.4 293.6 298.395%°F333.3 332.3 334.6Distillation‐EP°F 437364.2 364.2 371.4Recovery vol% Report98.1 97.8 97.2Residue vol% Report1.0 1.0 1.1Loss vol% Report0.9 1.2 1.7GravityASTMD4052°API Report 60.1 59.8SpecificGravityASTMD4052‐Report 0.7390 0.7395ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 10.21 9.85 9.74 9.57 9.59CarbonASTMD5291wtfraction Report 77HydrogenASTMD5291wtfraction Report 15.3OxygenASTMD5599wtfraction Report 7.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 0.03EthanolcontentASTMD5599wt% 19.50 20.50 20.58WatercontentASTME1064mg/kg Report 1051SulfurASTMD5453ppmwt 20 30 21LeadASTMD3237g/l 0.01 0.004Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14.6 15.3Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 6.6 6.3Composition,saturatesASTMD1319vol% Report58.8 58.4BenzeneASTMD3606vol% 0.47 0.77 0.56 0.29Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699Report 101.8MotorOctaneNumberASTMD2700Report 89.8R+MD2699/270087.095.8Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17118ANALYST Dixie Gage Dixie Core JB JB InspNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-37EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel22BatchNo.:22B 22B 22B 22B 22A 22A 22A Blend#5 Blend#4 Blend#3 Blend#2 Blend#1PRODUCTCODE:HF0678‐22AnalysisDate:12/16/2008 12/16/2008 12/16/2008 12/16/2008 12/5/2008 12/5/200812/5/2008 3/7/2008 3/5/2008 2/26/2008 2/25/2008 2/23/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidist optidist optidistDistillation‐IBPASTMD86°F90.1 91.1 91 88.5 111 108 108 108 1025% °F115.2 116.2 109.9 110 130 128 124 130 12610% °F 122 127 132 126.2 127.4 116.3 116.1 135 132 131 136 13220% °F141.7 142.7 124.4 124.1 141 138 140 145 14430% °F 147 152 157 152 152.6 133.4 133.1 148 145 149 153 15540% °F158.1 158.6 143.2 143.5 155 153 158 160 16350% °F 158 162 166 162.1 162.6 152.9 153.3 162 161 165 166 16860% °F165.2 166.4 160.3 160.9 168 170 174 177 19170% °F 227 232 237 230.8 232.8 165 166 255 252 252 241 25480% °F251.9 253.9 243.9 245.5 276 276 270 270 27090% °F 293 298 303 295.9 299.1 293.8 294.8 300 299 295 295 29795% °F332.3 337 332.4 332.6 314 314 312 313 315Distillation‐EP °F 437 366.2 371 369.2 365.7 343 342 346 346 351Recovery vol% Report 97.3 97.6 98.1 98.1 98.4 98.1 98 98.2 98.2Residue vol% Report 1.1 1.1 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.6 1.3 0.9 0.9 0.6 0.9 1.0 0.8 0.8GravityASTMD4052°API Report59.4 59.8 49.8 48.9 50.7 51.9 51.6SpecificGravityASTMD4052‐Report0.7411 0.7397 0.7807 0.7842 0.7765 0.7715 0.7727ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 9.94 9.98 9.85 10.07 10.21 10.03 6.74 7.13 7.76 7.18 7.70CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 19.50 20.50WatercontentASTME1064mg/kg ReportSulfurASTMD5453ppmwt 20 30LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14 15.4 14.7 15 16.3 16.5 38.8 42.1 38.1 38.2 39.2Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 5.9 5.5 7.6 6.4 6.8 8.2 7.5 6.5 6.9 7.7 7.6Composition,saturatesASTMD1319vol% Report 60.1 59.1 57.9 58.6 56.9 55.3 32.7 31.4 32.9 32.2 32.2BenzeneASTMD3606vol% 0.47 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699Report104.8MotorOctaneNumberASTMD2700Report88.4R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Dixie Inspectorate JB Core Inspectorate JB JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-38EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel23BatchNo.:XA2121GP02 XA2121GP02 XA2121GP02 XA2121GP02 XA2121GP02 XA2121GP02 XA2121GP02 23A 23A 23A 23APRODUCTCODE:TR1184AnalysisDate:2/23/2009 2/16/2009 2/12/2009 2/12/2009 2/13/2009 2/13/2009 2/10/2009 1/7/2009 1/7/2009 1/7/2009 1/7/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidistDistillation‐IBPASTMD86°F110.8 110.0 109.8 116.8 110.6 108.85% °F131.8 132.8 131.7 133.0 133.2 132.210% °F 133 138 143 138.0 138.6 138.0 138.7 138.3 138.120% °F145.0 145.9 145.4 146.3 145.1 145.430% °F 147 152 157 151.8 151.9 151.8 152.6 151.5 151.740% °F157.2 157.6 157.6 158.0 156.4 157.350% °F 158 162 166 161.2 162.5 162.4 163.0 162.1 162.460% °F167.7 172.6 171.0 174.0 167.9 170.370% °F 265 270 275 270.1 269.5 271.8 272.5 269.3 271.180% °F309.8 311.0 309.8 312.3 310.5 310.790% °F 333 338 343 337.6 338.1 337.6 338.4 338.3 338.195% °F349.2 348.7 349.6 350.1 349.4 349.2Distillation‐EP °F 437 366.0 365.2 365.6 368.4 364.5 363.5Recovery vol% Report97.0 98.4 97.6 97.6 97.7 98.3Residue vol% Report1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report2.0 0.6 1.4 1.4 1.3 0.7GravityASTMD4052°API Report57.5 57.6 57.3SpecificGravityASTMD4052‐Report0.7489 0.7482 0.7495ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.68 6.58 6.60 6.66 6.51CarbonASTMD5291wtfraction Report 77.4HydrogenASTMD5291wtfraction Report 13.9OxygenASTMD5599wtfraction Report 7Oxygen,otherthenETOHASTMD5599wtfraction 0.20 <0.01EthanolcontentASTMD5599wt% 19.50 20.50 20.26SulfurASTMD5453ppmwt 20 30 22 17.3LeadASTMD3237g/l 0.01 <0.003Composition,aromaticsASTMD1319vol% 14.0 15.5 17.0 15.5 16.6 15.4 15.6Composition,olefinsASTMD1319vol% 5.8 7.3 8.8 6.8 7.9 7 7.6Composition,saturatesASTMD1319vol% Report 57.7 55.5 57.6 56.8BenzeneASTMD3606vol% 0.47 0.77 0.68 0.35Existentgum,washedASTMD381mg/100mls 5.0 0.5ResearchOctaneNumberASTMD2699Report 97.2MotorOctaneNumberASTMD2700Report 86.4R+MD2699/270087.091.8Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17152ANALYST Dixie Core Dixie Insp JB JB Gage Dixie Core Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-39EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel24BatchNo.:WL2621GP03 WL2621GP03 WL2621GP03 WL2621GP03 WL2621GP03 WL2621GP03 24B 24B 24B 24BPRODUCTCODE:HF0678‐24AnalysisDate:1/21/2009 1/19/2009 1/16/2009 1/14/2009 1/14/2009 1/14/2009 12/16/2008 12/16/2008 12/16/2008 12/16/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXoptidist optidistoptidist optidistDistillation‐IBPASTMD86°F89.8 91.2 87.9 88.45% °F114 112.3 111.2 111.510% °F 119 124 129125.5 124.1 123.7 123.920% °F141.7 141.4 140.6 14130% °F 147 152 157152.3 152.5 152 152.440% °F159.7 159.3 159.3 159.750% °F 160 164 168164.4 163.9 164 164.660% °F174.2 169.7 169.8 170.470% °F 262 267 272265.1 262.8 265.7 267.380% °F303.6 302.6 305.6 306.190% °F 334 339 344337.6 336.1 337.8 339.195% °F349.8 349.1 350.3 351.2Distillation‐EP °F 437366 367.7 372.1 371.5Recovery vol% Report97.2 96.4 97.2 97.3Residue vol% Report1.1 1.1 1.0 1.1Loss vol% Report1.7 2.5 1.8 1.6GravityASTMD4052°API Report 58.90 58.7958.22SpecificGravityASTMD4052‐Report 0.7436 0.74360.7458ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 10.1600 10.1400 9.9200 9.7700 9.6500 10.18 10.10 10.05CarbonASTMD5291wtfraction Report 78HydrogenASTMD5291wtfraction Report 15.2OxygenASTMD5599wtfraction Report 7.1Oxygen,otherthenETOHASTMD5599wtfraction 0.10 0.03EthanolcontentASTMD5599wt% 19.50 20.50 20.44WatercontentASTMD1064mg/kg Report 1031SulfurASTMD5453ppmwt 20 30 22LeadASTMD3237g/l 0.01 0.005Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14.6 15.9 15 14.2 14.7 14.6Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 7.4 7 6.3 6.6 7.5 6Composition,saturatesASTMD1319vol% Report57.9 57.1 58.7 59.2 57.8 59.4BenzeneASTMD3606vol% 0.47 0.77 0.56 0.32Existentgum,washedASTMD381mg/100mls 5.0 0.5ResearchOctaneNumberASTMD2699Report 100.9MotorOctaneNumberASTMD2700Report 89.6R+MD2699/270087.095.2Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Dixie Gage Dixie Core JB Insp Core Dixie Inspectorate JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-40EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel24BatchNo.:24A 24A 24A LB#7 LB#6 LB#5 LB#4 LB#3 LB#2 LB#1PRODUCTCODE:HF0678‐24AnalysisDate:12/5/2008 12/5/2008 12/5/2008 3/7/2008 3/5/2008 3/3/2008 2/26/2008 2/25/2008 2/23/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidistDistillation‐IBPASTMD86°F90.8 87.3 93 93 91 91 93 94 985% °F114.8 113.3 112 112 109 111 113 114 11910% °F 119 124 129 126.2 125.4 118 118 116 119 122 122 12920% °F143.1 142.9 127 127 127 132 136 135 14330% °F 147 152 157 154.2 154 137 137 138 145 149 148 15440% °F160.2 160.6 149 149 150 157 160 158 16150% °F 160 164 168 164.4 164.6 160 160 161 165 166 164 16460% °F170.5 172.5 167 167 168 169 168 169 17170% °F 262 267 272 255.9 254 223 223 226 243 246 237 24180% °F288.7 288 278 278 280 282 2786 269 27290% °F 334 339 344 331.2 331.5 340 340 342 346 355 347 35595% °F348.5 348.9 356 356 358 361 370 364 371Distillation‐EP °F 437 370.4 368.8 381 381 383 390 393 388 395Recovery vol% Report 97.2 97.3 97.8 97.7 97.7 97.5 97.5 97.5Residue vol% Report 1.1 1.1 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.7 1.6 1 1.5 1.5 1.5 1.5 1.5GravityASTMD4052°API Report 57.98 51.9 52.0 51.7 52.4 52.3 535.0SpecificGravityASTMD4052‐Report 0.7468 0.7716 0.7724 0.7724 0.7696 0.7697 0.7647ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 10.01 10.15 10.05 9.76 10.68 10.19 9.97 9.97 8.86CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.10EthanolcontentASTMD5599wt% 19.50 20.50WatercontentASTMD1064mg/kg ReportSulfurASTMD5453ppmwt 20 306LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14.9 14.8 38.4 38.9 37.3 38.8 35.5 36.4Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 6.2 8.1 9.1 7.8 8.9 7.5 7.4 7.3Composition,saturatesASTMD1319vol% Report 59 57.1 31.5 33.3 32.8 32.7 36.1 35.3BenzeneASTMD3606vol% 0.47 0.770.38Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699Report104.0MotorOctaneNumberASTMD2700Report88.2R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Core Inspectorate JB JB JB JB JB JB JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-41EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel25BatchNo.:XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03 XC1021GP03PRODUCTCODE:TR1186AnalysisDate:3/31/2009 3/26/2009 3/27/2009 3/25/2009 3/20/2009 3/20/2009 3/17/2009 3/17/2009 3/17/2009 3/16/2009 3/16/2009 3/12/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX Optidist recheckDistillation‐IBPASTMD86°F92.7 88.3 86.2 86.8 88.1 95.95% °F117.5 115.2 112.2 110.2 109.2 109.810% °F 123 128 133 128 126.3 123.6 122.5 122 120.720% °F143.7 143.1 141.3 140.5 140.6 138.930% °F 148 153 158 154.3 154 152.7 152.8 152.6 151.740% °F161.5 161.1 160.2 160.5 160.4 159.850% °F 163 167 171 167.3 167.5 166.1 166.7 166.7 166.360% °F214 226.8 177.3 187.3 186.4 178.370% °F 278 283 288 285.8 284.7 281 280 283.6 278.880% °F312.4 314.2 310.1 309.9 309.7 304.790% °F 335 340 345 340.8 342.1 336.9 337.3 337.5 335.595% °F357.5 359.8 352.6 352.8 353.1 351.3Distillation‐EP °F 437 372.2 369.7 370 371.5 371.7 376.2Recovery vol% Report 98 97.1 98 97.4 97.1 96.4Residue vol% Report 1.1 1.1 1.0 1.1 1.1 0.6Loss vol% Report 0.9 1.8 1 1.5 1.8 3.0GravityASTMD4052°API Report51.1 52.2SpecificGravityASTMD4052‐Report0.7750 0.7702ReidVaporPressureASTMD5191psi 10.00 10.15 10.3010.21 10.01 10.11CarbonASTMD5291wtfraction Report79HydrogenASTMD5291wtfraction Report13.7OxygenASTMD5599wtfraction Report7Oxygen,otherthenETOHASTMD5599wtfraction 0.20<0.01EthanolcontentASTMD5599wt% 19.50 20.0 20.5020.23SulfurASTMD5453ppmwt 20 25 30 27 22 21.6 21 21 9.9LeadASTMD3237g/l 0.010.001Composition,aromaticsASTMD1319vol% 34.0 35.5 37.035.4 36Composition,olefinsASTMD1319vol% 5.5 7.0 8.55.44 7.6Composition,saturatesASTMD1319vol% Report39.1 36.4BenzeneASTMD3606vol% 0.47 0.62 0.770.59 0.19Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD2699102.6MotorOctaneNumberASTMD270088.2R+MD2699/270087.095.4Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report16918.0WatercontentASTME1064mg/kg Report1131ANALYST Dixie Saybolt Paragon Gage Dixie Insp Core Dixie Insp JB JB GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-42EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel25BatchNo.:25C 25C 25C 25C 25B 25B 25B 25B 25A 25A 25A 25APRODUCTCODE:TR1186AnalysisDate:3/2/2009 3/2/2009 2/27/2009 2/27/2009 1/23/2009 1/23/2009 1/23/2009 1/22/2009 1/7/2009 1/7/2009 1/7/2009 1/7/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAXoptidist optidist optidist optidistDistillation‐IBPASTMD86°F90.9 96.6 89.8 89.2 91 87.15% °F118 116.2 113.4 111.1 111.6 11010% °F 123 128 133 128.3 126.7 125.6 123.9 122.7 122.620% °F143.2 142.1 143.2 142.2 141.8 141.930% °F 148 153 158 153.3 152.8 154.2 153.7 153.7 154.440% °F160.7 160.4 161.2 161.4 162 162.450% °F 163 167 171 166.8 166.9 167.4 167.3 165.6 168.160% °F189.5 182.8 196 193.7 197.2 196.870% °F 278 283 288 284.4 282.5 285.1 284.2 281.7 28380% °F313 307.4 310.6 309.3 310.1 309.990% °F 335 340 345 340.9 339.1 338.2 336.1 336.9 33695% °F357.8 356.4 353.7 352.9 352.2 352.1Distillation‐EP °F 437 373.1 374 373.6 371 372 372Recovery vol% Report 98 97.3 97.6 97.1 97.1 97.3Residue vol% Report 1.1 1.1 1.0 1.1 1.1 1.1Loss vol% Report 0.9 1.6 1.4 1.8 1.8 1.6GravityASTMD4052°API Report51.8 51.4 51.4SpecificGravityASTMD4052‐Report0.7722 0.7736 0.7736ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 9.68 9.36 10.07 9.94 10.32 10.25CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.20EthanolcontentASTMD5599wt% 19.50 20.0 20.50SulfurASTMD5453ppmwt 20 25 30 22LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 34.0 35.5 37.0 35.1 36 36 37.7 35.4 38.1Composition,olefinsASTMD1319vol% 5.5 7.0 8.5 5.7 5.6 6.1 6.2 6 6.1Composition,saturatesASTMD1319vol% Report 39.2 38.4 37.9 36.2 38.56 35.8BenzeneASTMD3606vol% 0.47 0.62 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportWatercontentASTME1064mg/kg ReportANALYST Dixie Core Insp JB Dixie Core Insp JB Dixie Core Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-43EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel26BatchNo.:XC1621GP01 XC1621GP01 XC1621GP01 XC1621GP01 XC1621GP01 XC1621GP01 XC1621GP01 XC1621GP01 26B 26B 26B 26B 26A 26A 26A 26APRODUCTCODE:HF0678‐26AnalysisDate:4/8/2009 3/30/2009 3/20/2009 3/19/2009 3/25/2009 3/23/2009 3/23/2009 3/18/2009 1/23/2009 1/23/2009 1/23/2009 1/22/2009 1/7/2008 1/7/2008 1/7/2008 1/7/2008TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSRESULTS RESULTSMIN TARGET MAX797 958 optidist optidist optidist optidistDistillation‐IBPASTMD86°F85.7 91.1 91.8 95.5 90.5 90.5 90 88.45% °F107.4 109.3 107.4 110.3 109.2 109.3 109.5 107.510% °F 112 117 122115.6 116.7 115.5 117 117.1 116.8 116.3 115.220% °F126.6 127.5 126.5 126.9 127.6 127.1 126.5 125.930% °F 133 138 143137.6 137.9 137.5 137.7 138.2 137.7 137.1 136.640% °F149.2 149.2 149 148.5 149.2 149.3 148.2 14850% °F 156 160 164159.7 160 160.3 159.3 159.8 160.1 158.6 158.960% °F172.4 175.6 173.7 166.3 172.8 172 165 169.470% °F 272 277 282275.7 277.6 276.8 275.7 278.1 276 271 271.980% °F304.5 307.6 305.1 303.6 306.5 306.7 304.3 303.590% °F 334 339 344338.1 338.1 337.9 335.1 339.6 338.9 337 336.295% °F354.9 357.1 356.3 355.1 357.3 356.5 355.2 355.1Distillation‐EP °F 437373.5 379.6 377.3 379 376.7 375.4 373.8 371.9Recovery vol% Report98 98.1 96.8 97.4 97.4 97.7 97.5 97.7Residue vol% Report1.1 1.1 1.1 0.9 1.1 1.1 1.1 1.1Loss vol% Report0.9 0.8 2.1 1.7 1.5 1.2 1.4 1.2GravityASTMD4052°API Report54.7 54.8 54.6 54.7SpecificGravityASTMD4052‐Report0.7599 0.7595 0.7603 0.7598ReidVaporPressureASTMD5191psi 10.00 10.15 10.30 10.1800 10.0400 10.0500 10.0300 9.9700 10.2900 10.0500CarbonASTMD5291wtfraction Report80.6HydrogenASTMD5291wtfraction Report13.8OxygenASTMD5599wtfraction Report5.2Oxygen,otherthenETOHASTMD5599wtfraction 0.15 <0.01EthanolcontentASTMD5599wt% 14.50 15.50 15.05SulfurASTMD5453ppmwt 20 25 30 24 22 21LeadASTMD3237g/l 0.01 <0.003Composition,aromaticsASTMD1319vol% 35.3 36.8 38.3 35.4 37.3 35.9 37.6 35.6 37.5Composition,olefinsASTMD1319vol% 4.4 5.9 7.4 5.6 5.7 6.4 5.4 5.8 5.9Composition,saturatesASTMD1319vol% Report 43.9 42 42.8 42.1 43.6 41.6BenzeneASTMD3606vol% 0.47 0.62 0.77 0.56 0.20Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699101.6MotorOctaneNumberASTMD270088.0R+MD2699/270087.094.8Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17249.0WaterContentEN1064mg/kg838ANALYST Saybolt Dixie Core Dixie Insp JB JB Gage Core Dixie Insp JB Core Dixie Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-44EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel27BatchNo.:XC2521GP03 XC2521GP03 XC2521GP03 XC2521GP03 XC2521GP03 XC2521GP03 XC2521GP0327C 27C 27C 27C 27CPRODUCTCODE:HF0678‐27(TR1188)AnalysisDate:4/8/2009 4/6/2009 4/2/2009 4/1/2009 3/31/2009 4/1/2009 3/27/2009 3/13/2009 3/13/2009 3/18/2009 3/12/2009 3/12/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX958958Distillation‐IBPASTMD86°F101.5 104.7 110.5 109.7 106.7 101.65% °F134.5 132.3 133.5 137.4 136.5 132.810% °F 138 143 148141.7 141.2 140.9 143.6 141.7 140.920% °F151.5 151.4 151.5 152.5 151.9 150.830% °F 153 158 163155 158.2 158.4 158.6 158.2 157.740% °F163 163.3 163.4 164.3 162.8 162.550% °F 217 221 225223.6 218.1 224.1 223.9 217.8 212.660% °F250.5 251.1 250.5 248 250.1 249.470% °F 274 279 284276.6 274.2 274.6 279.9 277.4 273.980% °F312.5 309.6 311 313.9 313.2 309.190% °F 338 343 348341.4 339.3 340.3 344.1 341.2 339.795% °F354.4 351 352.2 355.6 355.3 351.1Distillation‐EP °F 436368 373.7 373.5 373.6 372.7 370.2Recovery vol% Report97.7 97.6 97.8 97.3 97.9 98Residue vol% Report1.0 1.0 1.2 1.0 1.0 1.0Loss vol% Report1.3 1.4 1 1.7 1.1 1GravityASTMD4052°API Report58.6 58.758.4SpecificGravityASTMD4052‐Report0.7441 0.7442 0.74400.7450ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.91 6.77 6.95 6.84 6.76CarbonASTMD5291wtfraction Report79.3HydrogenASTMD5291wtfraction Report15.9OxygenASTMD5599wtfraction Report5.3Oxygen,otherthenETOHASTMD5599wtfraction 0.15 <0.01EthanolcontentASTMD5599wt% 14.50 15.0 16.50 15.15SulfurASTMD5453ppmwt 20 25 30 26 25.4 20 25.2 24LeadASTMD3237g/l 0.01 <0.003Composition,aromaticsASTMD1319vol% 13.5 15.0 16.5 14.1 14.6 21.25 14.5 16Composition,olefinsASTMD1319vol% 5.1 6.6 8.1 6 7.7 3.06 6.1 7.1Composition,saturatesASTMD1319vol% Report 64.9 62.7 60.69 64.3 61.9BenzeneASTMD3606vol% 0.47 0.62 0.77 0.53 0.19Existentgum,washedASTMD381mg/100mls 5.0 0.5ResearchOctaneNumberASTMD2699100.7MotorOctaneNumberASTMD270089.1R+MD2699/270087.0 91.0 94.9Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17554.0WaterE1064mg/kg Report882ANALYST Dixie Gage Core Dixie Insp JB Gage Dixie Core Saybolt Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-45EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel27BatchNo.: 27B 27B 27B 27B 27B 27B 27B 27B 27A 27A 27A 27APRODUCTCODE:HF0678‐27(TR1188)AnalysisDate:3/4/2009 3/4/2009 2/27/2009 2/26/2009 1/23/2009 1/23/2009 1/23/2009 1/22/2009 1/7/20091/7/2009 1/7/2009 1/7/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX 797Distillation‐IBPASTMD86°F 108.4 110 100.9 107.3 105.4 104.8 104.9 104.75% °F 136.5 137.2 134.4 134 135.7 133.1 131.5 132.910% °F 138 143 148 142.9 143.4 142.2 141.6 142.7 141.6 138.1 139.320% °F 152 152.9 152.1 151.4 152.1 151.7 146.3 147.430% °F 153 158 163 158.8 159.4 158.4 158.4 158.5 158.5 153.1 154.140% °F 164.1 164.2 162.7 162.6 163 163.9 158.2 159.550% °F 217 221 225 226.3 228.5 225 219.5 227.1 220.8 166.1 167.960% °F 254 255.8 250.5 248.5 253 256.4 242.1 245.170% °F 274 279 284 282.4 282.9 280.6 277.3 279.7 281.1 274.3 275.980% °F 319.7 320 316.9 315.2 316.6 316.8 312.5 316.290% °F 338 343 348 344.8 345.4 343.8 342.4 342.9 343.3 342 341.995% °F 357.3 357.9 354.9 353.4 353.5 354.3 352.3 353.7Distillation‐EP °F 436 372.6 373.8 369.5 375.1 372.7 372.2 373.6 374.1Recovery vol% Report 97.9 97.8 98.2 97.9 97.6 97.4 97.6 98.2Residue vol% Report 1.1 1.1 1.0 1.0 1.0 1.1 1.1 1.0Loss vol% Report 1 1.1 0.8 1.1 1.4 1.5 1.3 0.8GravityASTMD4052°API Report58.0 58.9SpecificGravityASTMD4052‐Report0.7467 0.7431ReidVaporPressureASTMD5191psi 6.65 6.80 6.956.75 6.68 6.72 6.51CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.15EthanolcontentASTMD5599wt% 14.50 15.0 16.50SulfurASTMD5453ppmwt 20 25 30LeadASTMD3237g/l 0.01Composition,aromaticsASTMD1319vol% 13.5 15.0 16.514.7 16.2 15 15.2Composition,olefinsASTMD1319vol% 5.1 6.6 8.16.6 7.2 6.3 7.8Composition,saturatesASTMD1319vol% Report63.7 61.6 63.8 62BenzeneASTMD3606vol% 0.47 0.62 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0 91.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportWaterE1064mg/kg ReportANALYST Saybolt Saybolt Insp JB Dixie Core Insp JB Dixie Core Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-46EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel28BatchNo.:XC2521GP04 XC2521GP04 XC2521GP04 XC2521GP04 XC2521GP04 XC2521GP04 28D 28D 28D 28D 28D 28DPRODUCTCODE:HF0678‐28(TR1189)AnalysisDate:4/8/2009 4/2/2009 4/2/2009 4/1/2009 4/1/2009 3/30/2009 3/2/2009 3/2/2009 3/13/2009 3/13/2009 2/27/2009 2/27/2009ShipmentDate:SxtoSaybolt SxtoSayboltTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX797797Distillation‐IBPASTMD86°F100.6 105.6 112.5 109.4 110.1 107.4 110.55% °F135.4 133.8 133.5 140.3 140.1 139.3 138.110% °F 141 146 151 143.5 142.9 142.7 146.3 146.2 145.6 14520% °F153.7 153.3 153.5 154.8 154.3 154 153.630% °F 155 160 165 159.2 160 160.2 160.8 160 160.2 160.140% °F162.6 166.5 166.3 165.2 165.7 166.1 166.250% °F 215 219 223 216.9 215.9 215.8 219 220 218.8 215.360% °F237.8 240.1 240.4 241.4 241.1 241.3 240.370% °F 246 254 259 247.3 253.2 251.4 253.4 254.7 254.1 253.380% °F267.7 268 266.9 270.1 270.3 268.9 269.290% °F 296 301 306 298.4 298.6 297.7 302 301.3 300.4 299.495% °F326 327.5 325.2 330.8 329.2 329.9 328.1Distillation‐EP °F 437 362.4 362.8 363.2 369.6 363.4 363.4 362.1Recovery vol% Report98.5 97.7 97.8 98.9 98.8 98.7 98.2Residue vol% Report1.0 1.0 0.8 1.0 1.0 1.0 1.0Loss vol% Report0.5 1.3 1.4 0.1 0.2 0.3 0.8GravityASTMD4052°API Report 52.12 52.1 52.251.6SpecificGravityASTMD4052‐Report 0.7706 0.7709 0.77010.7729ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.81 6.64 6.77 6.28006.0600CarbonASTMD5291wtfraction Report 80.3HydrogenASTMD5291wtfraction Report 14.1OxygenASTMD5599wtfraction Report 5.2Oxygen,otherthenETOHASTMD5599wtfraction 0.15 <0.01EthanolcontentASTMD5599wt% 14.50 15.0 15.50 14.96SulfurASTMD5453ppmwt 20 30 24 21 21 20LeadASTMD3237g/l<0.003Composition,aromaticsASTMD1319vol% 33.5 35.0 36.5 33.7 34.6 32.4 33.8 36Composition,olefinsASTMD1319vol% 5.4 6.9 8.4 5.4 6.9 6.4 6.2 7.5Composition,saturatesASTMD1319vol% Report 46 43.5 46.2 45 41.5BenzeneASTMD3606vol% 0.47 0.62 0.77 0.54 0.19Existentgum,washedASTMD381mg/100mls 5.0 <0.5ResearchOctaneNumberASTMD2699102.8MotorOctaneNumberASTMD270088.9R+MD2699/270087.095.8Corrosion,CopperASTMD1301 1AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report 17274.0WaterE1064mg/kg Report 881ANALYST Dixie Core Dixie Insp JB Gage Dixie Core Saybolt Saybolt Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-47EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel28BatchNo.:28C 28C 28C 28C 28B 28B 28B 28B 28A 28A 28A 28A 28A 28APRODUCTCODE:HF0678‐28(TR1189)AnalysisDate:1/30/2009 2/2/2009 1/30/2009 1/29/2009 1/23/2009 1.23/09 1/23/2009 1/22/2009 1/7/2009 1/12/2009 1/7/2009 1/7/2009 1/13/2009 1/7/2009ShipmentDate:TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX optidist optidistrecheckDistillation‐IBPASTMD86°F103.4 105.4 109.9 108.8 107.6 102.35% °F134.3 136.8 136.8 135.9 135.3 134.110% °F 141 146 151 143.8 145.2 142.5 142.3 141.8 141.520% °F154.4 155.4 151 150.4 151 150.930% °F 155 160 165 160.1 162.1 156.7 157.2 158.4 158.840% °F166.3 169.7 163.2 163 164.1 165.150% °F 215 219 223 224.7 228.1 186.3 185.5 203.9 203.560% °F245 244.8 235.2 234.5 240.1 240.470% °F 246 254 259 253.6 253.2 250.3 250.1 251.2 251.480% °F269.4 270.2 265.8 266.6 263.3 266.590% °F 296 301 306 299.4 301.6 298.9 297.7 295.3 297.195% °F327.7 328.6 327 327.1 324.1 324.7Distillation‐EP °F 437 361.8 360.9 371.8 370.7 366.4 367.3Recovery vol% Report 97.4 98.2 98.3 98.1 98.5 98Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 1.6 0.8 0.7 0.9 0.5 1GravityASTMD4052°API Report51.4 52.252.1SpecificGravityASTMD4052‐Report0.7737 0.77030.7708ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.6300 6.5500 6.3200 6.2500 6.59006.3800CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.15EthanolcontentASTMD5599wt% 14.50 15.0 15.50SulfurASTMD5453ppmwt 20 30 20LeadASTMD3237g/lComposition,aromaticsASTMD1319vol% 33.5 35.0 36.5 34.2 35.1 34.9 37.4 35.9 35.9 36.3 36Composition,olefinsASTMD1319vol% 5.4 6.9 8.4 5.7 6.7 6.2 6 5.2 5 7.2 6.9Composition,saturatesASTMD1319vol% Report 45.1 43.2 43.9 41.6 43.9 44.1 41.5 42.1BenzeneASTMD3606vol% 0.47 0.62 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportWaterE1064mg/kg ReportANALYST Dixie Core Insp JB Dixie Core Insp JB Dixie Core Core Insp JB JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-48EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel30BatchNo.:XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 XA2121GP03 30A 30A 30A 30APRODUCTCODE:HF0678‐30AnalysisDate:2/18/2009 2/18/2009 2/23/2009 2/17/2009 2/16/2009 2/10/2009 2/6/2009 2/8/2009 2/8/2009 2/4/2009 1/7/2009 1/7/2009 1/7/2009 1/7/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX HTC1 HTC2 958 958 optidist(797) optidist(958)Distillation‐IBPASTMD86°F 89.2 90.3 92.4 89.7 90.6 90.6 92.7 91.7 89.25% °F 110.3 110.8 109.8 108.5 108.2 107.4 109.4 110.1 109.510% °F 111 116 121 116.4 116.6 116.1 115.1 115.0 114.0 115.5 115.8 115.920% °F 125.4 125.4 124.7 124.2 123.8 123.0 123.6 124.3 124.630% °F 128 133 138 134.2 134.1 133.2 133.3 132.8 131.9 132.4 132.9 13340% °F 142.9 142.9 142.6 142.7 142.1 141.9 141.8 142.2 142.350% °F 148 152 156 151.3 151.7 152.8 152.9 152.0 152.2 151.2 152 152.160% °F 199.9 200.7 196.4 195.4 191.5 190.6 194.5 191.3 190.170% °F 262 267 272 268.3 268.3 267.9 266.8 266.3 266.5 266.9 267.5 266.980% °F 294.3 294.4 294.1 294.3 292.8 292.3 294.8 295.1 293.790% °F 321 326 331 323.8 324.1 323.9 323.3 323.0 323.8 324.1 325.9 325.895% °F 341.2 341.6 341.4 341.2 340.5 341.7 341.8 343.7 343.5Distillation‐EP °F 437 363.7 363.6 366.4 363.2 366.5 366.0 364.1 363.8 363.9Recovery vol% Report 98.2 97.9 98.1 97.7 97.8 97.2 97.7 97.4 97.9Residue vol% Report 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Loss vol% Report 0.8 1.1 0.9 1.3 1.2 1.8 1.3 1.6 1.1GravityASTMD4052°API Report56.7 56.9 56.6SpecificGravityASTMD4052‐Report0.7519 0.7510 0.7523ReidVaporPressureASTMD5191psi 9.90 10.05 10.2010.27 10.1500 10.15 9.9300 9.8200CarbonASTMD5291wtfraction Report83HydrogenASTMD5291wtfraction Report13.6OxygenASTMD5599wtfraction Report3.4Oxygen,otherthenETOHASTMD5599wtfraction 0.10<0.01EthanolcontentASTMD5599wt% 9.5 10 10.509.74SulfurASTMD5453ppmwt 20 30 24 19 16.53Composition,aromaticsASTMD1319vol% 34.3 35.8 37.334.1 36.6 35.4 35 36.5Composition,olefinsASTMD1319vol% 4.7 6.2 7.75.7 6.1 6.2 6 6.3Composition,saturatesASTMD1319vol% Report50.2 47.3 48.4 49 47.2BenzeneASTMD3606vol% 0.47 0.62 0.77 0.53 0.19Existentgum,washedASTMD381mg/100mls 5.0<0.5ResearchOctaneNumberASTMD2699Report100.5MotorOctaneNumberASTMD2700Report94.0R+MD2699/270087.087.6Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report17,653ANALYST Insp Insp Dixie JB JB Dixie Core JB JB Gage Dixie Core Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-49EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel31BatchNo.:XC0221GP01 XC0221GP01 XC0221GP01 XC0221GP01 XC0221GP01 XC0221GP01 XC0221GP01 XC0221GP01PRODUCTCODE:TR1263AnalysisDate:3/20/2009 3/13/2009 3/11/2009 3/6/2009 3/9/2009 3/6/2009 3/5/2009 3/4/2009TEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX797Distillation‐IBPASTMD86°F107.3 109.7 114.65% °F130.9 133.3 132.310% °F 133 138 143138.1 139.5 138.620% °F146.8 147.8 147.030% °F 149 154 159154.2 154.9 154.840% °F160.1 161.5 161.150% °F 163 167 171165.4 167.4 166.360% °F210 210.8 220.170% °F 268 273 278272.1 270.3 271.880% °F295.8 297.2 295.590% °F 322 327 332324.3 324.6 325.295% °F341.1 341.7 342.1Distillation‐EP °F 436363.8 365.8 364.1Recovery vol% Report97.7 98.4 98.3Residue vol% Report1.0 1.0 0.8Loss vol% Report1.3 0.6 0.9GravityASTMD4052°API Report50.9 50.82SpecificGravityASTMD4052‐Report0.7757 0.7761ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.85 6.86 6.48 6.32 6.40CarbonASTMD5291wtfraction Report79.5HydrogenASTMD5291wtfraction Report13OxygenASTMD5599wtfraction Report7Oxygen,otherthenETOHASTMD5599wtfraction 0.20<0.01EthanolcontentASTMD5599wt% 19.50 20.0 20.5020.19SulfurASTMD5453ppmwt 20 25 30 27 21 10LeadASTMD3237g/l<0.003Composition,aromaticsASTMD1319vol% 34.3 35.8 37.3 35.4 37Composition,olefinsASTMD1319vol% 4.8 6.3 7.8 5.8 6.8Composition,saturatesASTMD1319vol% Report38.8 36.2BenzeneASTMD3606vol% 0.47 0.62 0.77 0.60 0.30Existentgum,washedASTMD381mg/100mls 5.00.5ResearchOctaneNumberASTMD2699101.9MotorOctaneNumberASTMD270088.0R+MD2699/270087.095.0Corrosion,CopperASTMD13011AOxidationstabilityASTMD525minutes 240>240NetHeatofCombustionASTMD4809‐ABTU/lb Report16855.0ANALYST Dixie Dixie Gage Core Dixie Inspectorate JB GageNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

### B-50EPACT FUEL ANALYSIS SUMMARYPRODUCT:EPAMatrixFuel31BatchNo.:31B 31B 31B 31B 31B 31B 31A 31A 31A 31A 31APRODUCTCODE:TR1263AnalysisDate:2/24/2009 2/23/2009 1/30/2009 2/2/2009 2/1/2009 1/29/2009 1/20/2009 1/7/2009 1/7/2009 1/7/2009 1/7/2009re‐blended re‐blendedTEST METHOD UNITS SPECIFICATIONS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTSMIN TARGET MAX 797 optidist optidist recheckDistillation‐IBPASTMD86°F 107 107.4 111.6 108.6 108.1 106.55% °F 133.3 128.7 132.3 131.7 134.9 132.810% °F 133 138 143 138.7 137 137.4 137.9 140.9 139.820% °F 147.6 146 144.5 147.0 150.1 149.630% °F 149 154 159 154.8 153.9 151.2 154.7 157.5 157.240% °F 161.1 160.8 160.9 161.5 163.3 163.450% °F 163 167 171 166.5 166.6 215.7 167.3 167.5 168.860% °F 223.9 210.1 253.6 214.5 243.3 24270% °F 268 273 278 273.3 272.9 280.0 274.0 276.2 277.380% °F 298.6 297.7 308.1 298.9 303.1 303.190% °F 322 327 332 327.4 326.1 337.8 326.9 329.6 330.295% °F 345.7 343.3 353.8 343.2 345.4 345.6Distillation‐EP °F 436 366.5 365 372.3 365.6 364.6 367.6Recovery vol% Report 98.6 96.8 97.3 98.0 97.8 97.9Residue vol% Report 1.0 1.0 1.1 1.0 1.0 1.0Loss vol% Report 0.4 2.2 1.6 1.0 1.2 1.1GravityASTMD4052°API Report50.749.9SpecificGravityASTMD4052‐Report0.77660.7802ReidVaporPressureASTMD5191psi 6.65 6.80 6.95 6.5900 6.5700 6.5900 6.4400CarbonASTMD5291wtfraction ReportHydrogenASTMD5291wtfraction ReportOxygenASTMD5599wtfraction ReportOxygen,otherthenETOHASTMD5599wtfraction 0.20EthanolcontentASTMD5599wt% 19.50 20.0 20.50SulfurASTMD5453ppmwt 20 25 30 22LeadASTMD3237g/lComposition,aromaticsASTMD1319vol% 34.3 35.8 37.3 36 35.5 36.7 37.2 37Composition,olefinsASTMD1319vol% 4.8 6.3 7.8 6.2 6.4 5.4 5.1 7.6Composition,saturatesASTMD1319vol% Report37.8 38.1 37.8 37.7 35.4BenzeneASTMD3606vol% 0.47 0.62 0.77Existentgum,washedASTMD381mg/100mls 5.0ResearchOctaneNumberASTMD2699MotorOctaneNumberASTMD2700R+MD2699/270087.0Corrosion,CopperASTMD1301OxidationstabilityASTMD525minutes 240NetHeatofCombustionASTMD4809‐ABTU/lb ReportANALYST Insp JB Dixie Core Insp JB Core Dixie Core Insp JBNOTE:Highlightedcellsarenearoroutofspecification.Insomecases,thefuelwasapprovedwithselectpropertiesoutofspecification.Theseapprovalsweremadeonacase‐by‐casebasisbasedonEPA’srecommendation.REPORT 03.14295/03-51563E 

# APPENDIX C

DETAILED HYDROCARBON ANALYSIS RESULTS**Hydrocarbon Expert V4.7 Wed Aug 25 16:51:12 2010**  **Page 1**

24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 10.907 12.118 11.272

I-Paraffins 41.057 44.544 38.393

Aromatics 21.495 17.700 16.790 Mono-Aromatics 20.516 16.957 16.130 Naphthalenes 0.077 0.054 0.049 Naphtheno/Olefino-Benzs 0.159 0.128 0.100 Indenes 0.743 0.561 0.511

Naphthenes 7.436 7.020 7.009 Mono-Naphthenes 7.436 7.020 7.009 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.679 8.170 8.360 n-Olefins 3.263 3.548 3.648 Iso-Olefins 3.747 4.001 3.984 Naphtheno-Olefins 0.642 0.592 0.696 Di-Olefins 0.027 0.028 0.033

Oxygenates 9.308 8.480 16.828

Unidentified 2.117 1.968 1.348

Plus 0.000 0.000 0.000

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Wed Aug 25 16:51:12 2010**  **Page 1**

24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 9.196 8.379 16.672 C3 0.115 0.105 0.162 C4 0.548 0.669 0.797 C5 25.438 29.118 29.598 C6 18.536 19.229 18.217 C7 12.806 11.855 11.170 C8 17.326 16.410 12.988 C9 8.500 7.611 5.765 C10 4.219 3.565 2.632 C11 1.086 0.999 0.592 C12 0.113 0.093 0.058

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Wed Aug 25 16:51:12 2010**  **Page 1**

24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.003 0.005 0.006 C4 0.308 0.383 0.443 C5 4.874 5.596 5.643 C6 3.981 4.340 3.858 C7 0.905 0.952 0.755 C8 0.425 0.435 0.311 C9 0.294 0.295 0.192 C10 0.064 0.063 0.038 C11 0.051 0.049 0.027

I-Paraffins C4 0.040 0.052 0.058 C5 16.263 18.873 18.826 C6 6.876 7.516 6.664 C7 2.656 2.806 2.214 C8 10.720 10.794 7.838 C9 2.975 3.012 1.937 C10 0.834 0.823 0.486 C11 0.680 0.657 0.363 C12 0.013 0.012 0.006

Mono-Aromatics C6 0.831 0.680 0.889 C7 6.056 5.021 5.489 C8 5.652 4.689 4.447 C9 5.090 4.198 3.537 C10 2.486 2.043 1.547 C11 0.300 0.244 0.169 C12 0.101 0.081 0.052

Naphthalenes C10 0.061 0.043 0.040 C11 0.016 0.011 0.009

Naphtheno/Olefino-Benzs C10 0.159 0.128 0.100

Indenes C9 0.124 0.092 0.088 C10 0.614 0.464 0.421 C11 0.005 0.004 0.003

Mono-Naphthenes C5 0.449 0.433 0.535 C6 4.135 3.906 4.104 C7 2.343 2.208 1.993 C8 0.493 0.458 0.367 C9 0.017 0.014 0.011

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Wed Aug 25 16:51:12 2010**  **Page 2**

24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes n-Olefins C4 0.199 0.235 0.297 C5 1.709 1.894 2.036 C6 1.211 1.274 1.202 C7 0.110 0.112 0.093 C11 0.034 0.033 0.020

Iso-Olefins C5 1.909 2.101 2.273 C6 1.065 1.113 1.057 C7 0.737 0.754 0.627 C8 0.036 0.033 0.026

Naphtheno-Olefins C5 0.206 0.192 0.253 C6 0.436 0.400 0.443

Di-Olefins C5 0.027 0.028 0.033

Oxygenates C2 9.196 8.379 16.672 C3 0.112 0.101 0.156

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Wed Aug 25 16:51:12 2010**  **Page 1**

24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 35.78 31.61 5% 79.59 79.45 10% 80.59 80.31 15% 81.59 81.17 20% 94.75 82.03 25% 100.83 95.95 30% 139.74 120.87 35% 154.13 140.43 40% 157.48 154.33 45% 172.52 157.78 50% 173.11 172.58 55% 187.75 173.22 60% 210.19 193.48 65% 230.81 212.27 70% 233.98 230.91 75% 237.97 236.08 80% 255.30 243.75 85% 281.77 277.11 90% 322.42 318.26 95% 352.22 347.32 FBP 388.19 387.31

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.390 74-98-6 P3 Propane 0.003 0.005 0.006 0.788 2 8.612 75-28-5 I4 i-Butane 0.040 0.052 0.058 9.925 3 9.404 115-11-7 K4 Isobutene 0.016 0.019 0.024 4.054 4 9.444 106-98-9 K4 Butene-1 0.019 0.023 0.029 4.953 5 9.793 106-97-8 P4 n-Butane 0.308 0.383 0.443 76.175 6 10.267 624-64-6 K4 t-Butene-2 0.075 0.089 0.112 19.229 7 10.389 463-82-1 I5 2,2-Dimethylpropane 0.057 0.069 0.065 14.063 8 10.987 590-18-1 K4 c-Butene-2 0.089 0.103 0.132 22.743 9 12.745 64-17-5 X2 Ethanol 9.196 8.379 16.672 1011.630 10 13.128 563-45-1 C5 3-Methylbutene-1 0.300 0.344 0.357 76.734

11 14.727 78-78-4 I5 i-Pentane 16.207 18.804 18.761 4032.715 12 16.338 109-67-1 K5 Pentene-1 0.346 0.388 0.412 88.469 13 17.172 563-46-2 C5 2-Methylbutene-1 0.525 0.581 0.626 134.460 14 17.700 109-66-0 P5 n-Pentane 4.874 5.596 5.643 1212.875 15 18.209 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.011 0.013 2.829 16 18.797 646-04-8 K5 t-Pentene-2 0.881 0.977 1.049 225.410 17 19.821 627-20-3 K5 c-Pentene-2 0.483 0.530 0.575 123.614 18 20.491 513-35-9 C5 2-Methylbutene-2 1.084 1.177 1.291 277.414 19 20.823 2004-70-8 E5 1t,3-Pentadiene 0.016 0.017 0.020 4.233 20 22.064 ? Unidentified 0.006 0.006 0.008 1.883

21 22.608 75-83-2 I6 2,2-Dimethylbutane 0.310 0.343 0.300 77.375 22 25.250 142-29-0 B5 Cyclopentene 0.206 0.192 0.253 54.331 23 26.426 ? Unidentified 0.044 0.039 0.061 13.657 24 26.498 71-23-8 X3 n-Propanol 0.112 0.101 0.156 20.102 25 27.092 287-92-3 M5 Cyclopentane 0.449 0.433 0.535 114.905 26 27.833 79-29-8 I6 2,3-Dimethylbutane 0.785 0.853 0.761 196.149 27 28.233 ? Unidentified 0.054 0.052 0.051 16.789 28 28.695 691-38-3 C6 4-Methyl-c-pentene-2 0.047 0.050 0.047 12.061 29 28.918 107-83-5 I6 2-Methylpentane 3.405 3.748 3.300 850.670 30 29.349 674-76-0 C6 4-Methyl-t-pentene-2 0.138 0.148 0.137 35.376

31 31.558 96-14-0 I6 3-Methylpentane 2.376 2.571 2.303 593.542 32 32.722 763-29-1 C6 2-Methylpentene-1 0.237 0.249 0.235 60.619 33 32.943 592-41-6 K6 Hexene-1 0.170 0.180 0.168 43.445 34 35.305 110-54-3 P6 n-Hexane 3.981 4.340 3.858 994.579 35 35.936 13269-52-8 K6 t-Hexene-3 0.279 0.294 0.277 71.401 36 36.414 4050-45-7 K6 t-Hexene-2 0.535 0.563 0.531 136.913 37 36.906 625-27-4 C6 2-Methylpentene-2 0.363 0.377 0.360 92.848 38 37.321 922-62-3 C6 3-Methyl-c-pentene-2 0.281 0.289 0.278 71.798 39 38.254 7688-21-3 K6 c-Hexene-2 0.228 0.237 0.226 58.285 40 39.590 3404-73-7 C7 3,3-Dimethylpentene-1 0.332 0.340 0.283 85.027

41 40.168 96-37-7 M6 Methylcyclopentane 2.373 2.279 2.355 607.301 42 41.741 108-08-7 I7 2,4-Dimethylpentane 0.424 0.453 0.353 106.370 43 42.039 594-56-9 C7 2,3,3-Trimethylbutene-1 0.015 0.015 0.013 3.775

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.277 464-06-2 I7 2,2,3-Trimethylbutane 0.053 0.055 0.044 13.318 45 44.938 ? Unidentified 0.012 0.012 0.013 3.894 46 45.140 71-42-3 Q6 Benzene 0.831 0.680 0.889 229.079 47 45.347 693-89-0 B6 1-Methylcyclopentene 0.388 0.358 0.395 101.725 48 46.162 3404-61-3 C7 3-Methylhexene-1 0.017 0.017 0.014 4.257 49 46.749 3524-73-0 C7 5-Methylhexene-1 0.084 0.087 0.071 21.467 50 47.063 110-82-7 M6 Cyclohexane 1.762 1.628 1.749 451.067 51 47.602 ? Unidentified 0.036 0.037 0.031 11.379 52 48.806 15840-60-5 C7 2-Methyl-c-hexene-3 0.043 0.045 0.037 11.006 53 49.152 3769-23-1 C7 4-Methylhexene-1 0.011 0.011 0.009 2.847

54 49.805 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.054 0.055 0.046 13.838 55 50.197 591-76-4 I7 2-Methylhexane 1.372 1.453 1.143 344.059 56 50.675 110-83-8 B6 Cyclohexene 0.047 0.042 0.048 12.145 57 52.034 589-34-4 I7 3-Methylhexane 0.807 0.844 0.673 202.424 58 52.885 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.242 0.232 0.206 61.894 59 53.471 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.195 0.188 0.166 49.809 60 54.098 822-50-4 M7 1t,2-Dimethylcyclopentane 0.293 0.280 0.249 74.973 61 54.402 C7 C7 - Iso-Olefin - 2 0.024 0.024 0.020 6.018 62 54.689 540-84-1 I8 2,2,4-Trimethylpentane 1.160 1.205 0.848 291.532 63 55.027 592-76-7 K7 Heptene-1 0.031 0.032 0.027 8.050

64 56.365 4914-89-0 C7 3-Methyl-c-hexene-3 0.015 0.015 0.013 3.865 65 56.883 14686-14-7 K7 t-Heptene-3 0.035 0.036 0.030 8.889 66 57.246 6094-02-6 C7 2-Methylhexene-1 0.062 0.064 0.053 15.916 67 57.624 142-82-5 P7 n-Heptane 0.905 0.952 0.755 227.081 68 57.839 7642-10-6 K7 c-Heptene-3 0.026 0.027 0.022 6.690 69 58.118 2738-19-4 C7 2-Methyl-2-hexene 0.028 0.029 0.024 7.239 70 58.363 3899-36-3 C7 3-Methyl-t-hexene-3 0.022 0.022 0.018 5.522 71 58.748 14686-13-6 K7 t-Heptene-2 0.017 0.018 0.015 4.402 72 59.205 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.020 0.019 0.017 5.062 73 59.649 20710-38-8 C7 3-Methyl-t-hexene-2 0.016 0.016 0.014 4.157

74 60.434 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.012 3.666 75 61.070 108-87-2 M7 Methylcyclohexane 1.542 1.440 1.311 394.560 76 62.018 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.038 0.036 0.028 9.687 77 62.423 590-73-8 I8 2,2-Dimethylhexane 0.030 0.031 0.022 7.476 78 63.860 1640-89-7 M7 Ethylcyclopentane 0.052 0.049 0.044 13.312 79 64.512 564-02-3 I8 2,2,3-Trimethylpentane 0.303 0.304 0.221 76.117 80 64.754 592-13-2 I8 2,5-Dimethylhexane 0.645 0.669 0.472 162.099 81 65.092 589-43-5 I8 2,4-Dimethylhexane 0.581 0.597 0.425 146.037 82 65.930 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.035 0.033 0.026 8.961 83 66.333 563-16-6 I8 3,3-Dimethylhexane 0.021 0.022 0.016 5.354

84 67.460 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.030 0.028 0.022 7.567 85 68.098 565-75-3 I8 2,3,4-Trimethylpentane 2.844 2.844 2.080 714.827 86 68.631 108-88-3 Q7 Toluene 6.056 5.021 5.489 1650.972

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 68.778 560-21-4 I8 2,3,3-Trimethylpentane 3.583 3.547 2.619 900.391 88 70.131 C8 C8 - Diolefin - 1 0.012 0.011 0.009 3.017 89 70.432 584-94-1 I8 2,3-Dimethylhexane 0.829 0.837 0.606 208.377 90 71.702 592-27-8 I8 2-Methylheptane 0.242 0.249 0.177 60.786 91 71.961 589-53-7 I8 4-Methylheptane 0.168 0.171 0.123 42.188 92 72.096 ? Unidentified 0.073 0.073 0.054 23.034 93 72.865 M8 1,3-dimethyl-t-cyclohexane 0.173 0.162 0.129 44.347 94 73.024 589-81-1 I8 3-Methylheptane 0.206 0.210 0.150 51.711 95 73.209 619-99-8 I8 3-Ethylhexane 0.109 0.109 0.079 27.295 96 74.105 ? Unidentified 0.027 0.025 0.020 8.494

97 74.936 3522-94-9 I9 2,2,5-Trimethylhexane 2.094 2.129 1.364 527.376 98 75.273 M8 3c-Ethylmethylcyclopentane 0.009 0.009 0.007 2.399 99 75.493 M8 3t-Ethylmethylcyclopentane 0.013 0.012 0.010 3.375 100 75.910 ? Unidentified 0.014 0.014 0.009 4.366 101 76.196 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.074 0.069 0.055 19.011 102 77.567 111-65-9 P8 n-Octane 0.425 0.435 0.311 106.791 103 78.511 ? Unidentified 0.051 0.050 0.034 16.140 104 80.059 1069-53-0 I9 2,3,5-Trimethylhexane 0.346 0.344 0.225 87.074 105 80.619 C8 C9 - IsoOlefin - 1 0.013 0.012 0.010 3.335 106 81.057 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.013 0.012 0.009 3.262

107 81.235 1071-26-7 I9 2,4-Dimethylheptane 0.062 0.063 0.040 15.565 108 81.870 1678-91-7 M8 Ethylcyclohexane 0.107 0.098 0.080 27.459 109 82.197 1072-05-5 I9 2,6-Dimethylheptane 0.096 0.097 0.062 24.096 110 82.676 ? Unidentified 0.020 0.021 0.013 6.335 111 83.130 I9 2,5-Dimethylheptane 0.201 0.202 0.131 50.507 112 83.304 926-82-9 I9 3,5-Dimethylheptane 0.021 0.021 0.014 5.324 113 84.441 100-41-4 Q8 Ethylbenzene 1.020 0.846 0.802 275.975 114 84.621 ? Unidentified 0.026 0.025 0.017 8.075 115 84.862 ? Unidentified 0.031 0.029 0.021 9.743 116 85.671 108-38-3 Q8 m-Xylene 2.565 2.134 2.018 694.152

117 85.820 106-42-3 Q8 p-Xylene 1.157 0.966 0.911 313.155 118 85.966 ? Unidentified 0.060 0.060 0.039 18.870 119 86.221 C8 C9-IsoOlefin-3 0.011 0.010 0.007 2.846 120 86.329 ? Unidentified 0.011 0.011 0.007 3.430 121 87.017 2216-34-4 I9 4-Methyloctane 0.040 0.040 0.026 10.037 122 87.149 3221-61-2 I9 2-Methyloctane 0.055 0.055 0.036 13.832 123 88.015 2216-33-3 I9 3-Methyloctane 0.061 0.061 0.040 15.443 124 88.481 ? Unidentified 0.118 0.125 0.078 37.130 125 88.653 95-47-6 Q8 o-Xylene 0.910 0.743 0.716 246.110 126 89.070 I10 C10 - IsoParaffin - 1 0.400 0.395 0.235 100.835

127 89.643 M9 trans-1,3-Diethylcyclopentane 0.017 0.014 0.011 4.560 128 89.916 14720-74-2 I10 2,2,4-trimethylheptane 0.280 0.277 0.164 70.641 129 91.485 111-84-2 P9 n-Nonane 0.294 0.295 0.192 74.085

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 92.840 98-82-8 Q9 i-Propylbenzene 0.035 0.029 0.025 9.479 131 93.600 ? Unidentified 0.044 0.043 0.026 13.696 132 93.824 15869-87-1 I10 2,2-Dimethyloctane 0.017 0.017 0.010 4.327 133 94.630 15869-89-3 I10 2,5-Dimethyloctane 0.010 0.010 0.006 2.510 134 94.816 I10 C10 - IsoParaffin - 2 0.010 0.010 0.006 2.647 135 95.266 2051-30-1 I10 2,4-Dimethyloctane 0.012 0.012 0.007 2.976 136 95.661 I10 2,6-Dimethyloctane 0.010 0.009 0.006 2.418 137 96.307 103-65-1 Q9 n-Propylbenzene 0.255 0.213 0.177 68.654 138 97.155 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.997 0.829 0.693 268.029 139 97.389 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.475 0.396 0.330 127.589

140 98.015 108-67-8 Q9 1,3,5-Trimethylbenzene 0.634 0.527 0.441 170.506 141 98.684 17301-94-8 I10 4-Methylnonane 0.012 0.011 0.007 2.938 142 98.885 ? Unidentified 0.235 0.233 0.138 73.669 143 99.100 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.388 0.317 0.270 104.326 144 99.663 5911-04-6 I10 3-Methylnonane 0.017 0.016 0.010 4.176 145 100.129 ? Unidentified 0.020 0.014 0.011 6.177 146 100.254 ? Unidentified 0.059 0.057 0.031 18.380 147 100.478 I11 C11-Isoparaffin-2 0.030 0.029 0.016 7.687 148 100.737 95-63-6 Q9 1,2,4-Trimethylbenzene 1.953 1.603 1.357 525.082 149 100.942 ? Unidentified 0.041 0.042 0.025 12.941

150 101.065 ? Unidentified 0.022 0.022 0.013 7.033 151 102.109 17302-01-1 I10 3-Ethyl-3-methylheptane 0.068 0.065 0.036 17.109 152 102.390 538-93-2 Q10 i-Butylbenzene 0.094 0.079 0.058 25.039 153 102.657 124-18-5 P10 n-Decane 0.064 0.063 0.038 16.253 154 102.976 ? Unidentified 0.018 0.017 0.010 5.618 155 103.612 526-73-8 Q9 1,2,3-Trimethylbenzene 0.352 0.283 0.245 94.713 156 104.005 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.014 0.012 0.009 3.714 157 104.194 I11 C11 Isoparaffin-4 0.011 0.010 0.006 2.690 158 104.395 ? Unidentified 0.066 0.055 0.041 20.702 159 104.803 J9 Indan 0.124 0.092 0.088 33.876

160 105.431 J10 Indene 0.435 0.325 0.308 118.912 161 106.148 I11 C11-Isoparaffin-7 0.194 0.187 0.104 48.994 162 106.334 141-93-5 Q10 1,3-Diethylbenzene 0.044 0.037 0.028 11.844 163 106.625 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.649 0.542 0.404 173.548 164 106.918 105-05-5 Q10 1,4-Diethylbenzene 0.214 0.178 0.133 57.206 165 107.176 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.116 0.095 0.072 30.996 166 107.428 135-01-3 Q10 1,2-Diethylbenzene 0.045 0.037 0.028 11.949 167 107.888 ? Unidentified 0.050 0.048 0.027 15.627 168 108.026 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.045 0.037 0.028 11.916 169 108.163 ? Unidentified 0.058 0.057 0.032 18.289

170 108.245 ? Unidentified 0.051 0.049 0.027 15.925 171 108.367 I11 C11- Isoparaffin-11 0.445 0.430 0.238 112.411 172 108.549 ? Unidentified 0.145 0.140 0.077 45.338

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 108.880 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.081 0.067 0.051 21.759 174 108.982 ? Unidentified 0.454 0.372 0.283 142.345 175 109.206 J10 2-Methylindan 0.076 0.057 0.048 20.864 176 109.544 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.256 0.210 0.159 68.453 177 110.101 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.405 0.327 0.252 108.326 178 110.529 ? Unidentified 0.014 0.012 0.007 4.250 179 110.731 693-61-8 K11 2-Undecene, (E)- 0.034 0.033 0.020 8.523 180 110.858 ? Unidentified 0.082 0.080 0.049 25.775 181 111.133 ? Unidentified 0.068 0.057 0.038 21.219 182 111.219 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.064 0.051 0.040 17.039

183 111.532 1120-21-4 P11 n-Undecane 0.051 0.049 0.027 12.912 184 111.688 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.058 0.047 0.033 15.364 185 111.799 ? Unidentified 0.038 0.031 0.021 11.848 186 112.164 Q10 1,2,4,5-Tetramethylbenzene 0.195 0.158 0.122 52.220 187 112.430 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.265 0.214 0.165 70.824 188 112.786 ? Unidentified 0.016 0.013 0.010 4.914 189 112.967 I12 C12 - IsoParaffin - 1 0.013 0.012 0.006 3.168 190 113.294 ? Unidentified 0.022 0.022 0.011 6.961 191 113.585 Q11 C11 - Aromatic - 3 0.045 0.036 0.025 11.872 192 113.763 874-35-1 H10 5-Methylindan 0.077 0.062 0.049 20.644

193 113.903 Q12 1,2-Di-i-propylbenzene 0.032 0.026 0.017 8.578 194 114.118 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.046 0.037 0.026 12.203 195 114.281 Q11 C11 - Aromatic - 4 0.025 0.020 0.014 6.628 196 114.515 824-22-6 J10 4-Methylindan 0.102 0.083 0.065 27.392 197 114.682 ? Unidentified 0.023 0.019 0.013 7.181 198 114.766 824-63-5 H10 2-Methylindan 0.082 0.066 0.052 21.813 199 114.979 ? Unidentified 0.008 0.007 0.005 2.641 200 115.092 538-68-1 Q11 n-Pentylbenzene 0.011 0.009 0.006 2.876 201 115.321 Q11 tert-Pentylbenzene 0.045 0.036 0.025 11.966 202 115.634 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.019 0.016 0.011 5.161

203 115.745 Q11 C11 - Aromatic - 7 0.026 0.022 0.015 6.925 204 116.206 100-18-5 Q12 1,4-Di-i-propylbenzene 0.035 0.028 0.018 9.335 205 116.633 91-20-3 G10 Naphthalene 0.061 0.043 0.040 17.146 206 117.081 J11 1,1-Dimethyl Indane 0.005 0.004 0.003 1.451 207 117.432 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.004 0.003 0.002 1.144 208 117.737 Q12 1,3-Di-n-propylbenzene 0.029 0.023 0.015 7.625 209 117.847 Q11 C11 - Aromatic - 11 0.016 0.014 0.009 4.307 210 118.403 Q11 C11 - Aromatic - 12 0.010 0.008 0.006 2.639 211 123.283 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.006 2.778 212 124.150 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.003 1.542

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.390 74-98-6 Propane 0.003 0.005 0.006 0.788

9.793 106-97-8 n-Butane 0.308 0.383 0.443 76.175 17.700 109-66-0 n-Pentane 4.874 5.596 5.643 1212.875 35.305 110-54-3 n-Hexane 3.981 4.340 3.858 994.579 57.624 142-82-5 n-Heptane 0.905 0.952 0.755 227.081 77.567 111-65-9 n-Octane 0.425 0.435 0.311 106.791 91.485 111-84-2 n-Nonane 0.294 0.295 0.192 74.085 102.657 124-18-5 n-Decane 0.064 0.063 0.038 16.253 111.532 1120-21-4 n-Undecane 0.051 0.049 0.027 12.912

I-Paraffins 8.612 75-28-5 i-Butane 0.040 0.052 0.058 9.925

10.389 463-82-1 2,2-Dimethylpropane 0.057 0.069 0.065 14.063 14.727 78-78-4 i-Pentane 16.207 18.804 18.761 4032.715 22.608 75-83-2 2,2-Dimethylbutane 0.310 0.343 0.300 77.375 27.833 79-29-8 2,3-Dimethylbutane 0.785 0.853 0.761 196.149 28.918 107-83-5 2-Methylpentane 3.405 3.748 3.300 850.670 31.558 96-14-0 3-Methylpentane 2.376 2.571 2.303 593.542 41.741 108-08-7 2,4-Dimethylpentane 0.424 0.453 0.353 106.370 42.277 464-06-2 2,2,3-Trimethylbutane 0.053 0.055 0.044 13.318 50.197 591-76-4 2-Methylhexane 1.372 1.453 1.143 344.059 52.034 589-34-4 3-Methylhexane 0.807 0.844 0.673 202.424 54.689 540-84-1 2,2,4-Trimethylpentane 1.160 1.205 0.848 291.532 62.423 590-73-8 2,2-Dimethylhexane 0.030 0.031 0.022 7.476 64.512 564-02-3 2,2,3-Trimethylpentane 0.303 0.304 0.221 76.117 64.754 592-13-2 2,5-Dimethylhexane 0.645 0.669 0.472 162.099 65.092 589-43-5 2,4-Dimethylhexane 0.581 0.597 0.425 146.037 66.333 563-16-6 3,3-Dimethylhexane 0.021 0.022 0.016 5.354 68.098 565-75-3 2,3,4-Trimethylpentane 2.844 2.844 2.080 714.827 68.778 560-21-4 2,3,3-Trimethylpentane 3.583 3.547 2.619 900.391 70.432 584-94-1 2,3-Dimethylhexane 0.829 0.837 0.606 208.377 71.702 592-27-8 2-Methylheptane 0.242 0.249 0.177 60.786 71.961 589-53-7 4-Methylheptane 0.168 0.171 0.123 42.188 73.024 589-81-1 3-Methylheptane 0.206 0.210 0.150 51.711 73.209 619-99-8 3-Ethylhexane 0.109 0.109 0.079 27.295 74.936 3522-94-9 2,2,5-Trimethylhexane 2.094 2.129 1.364 527.376 80.059 1069-53-0 2,3,5-Trimethylhexane 0.346 0.344 0.225 87.074 81.235 1071-26-7 2,4-Dimethylheptane 0.062 0.063 0.040 15.565 82.197 1072-05-5 2,6-Dimethylheptane 0.096 0.097 0.062 24.096 83.130 2,5-Dimethylheptane 0.201 0.202 0.131 50.507 83.304 926-82-9 3,5-Dimethylheptane 0.021 0.021 0.014 5.324 87.017 2216-34-4 4-Methyloctane 0.040 0.040 0.026 10.037 87.149 3221-61-2 2-Methyloctane 0.055 0.055 0.036 13.832 88.015 2216-33-3 3-Methyloctane 0.061 0.061 0.040 15.443 89.070 C10 - IsoParaffin - 1 0.400 0.395 0.235 100.835 89.916 14720-74-2 2,2,4-trimethylheptane 0.280 0.277 0.164 70.641 93.824 15869-87-1 2,2-Dimethyloctane 0.017 0.017 0.010 4.327 94.630 15869-89-3 2,5-Dimethyloctane 0.010 0.010 0.006 2.510

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 94.816 C10 - IsoParaffin - 2 0.010 0.010 0.006 2.647

95.266 2051-30-1 2,4-Dimethyloctane 0.012 0.012 0.007 2.976 95.661 2,6-Dimethyloctane 0.010 0.009 0.006 2.418 98.684 17301-94-8 4-Methylnonane 0.012 0.011 0.007 2.938 99.663 5911-04-6 3-Methylnonane 0.017 0.016 0.010 4.176 100.478 C11-Isoparaffin-2 0.030 0.029 0.016 7.687 102.109 17302-01-1 3-Ethyl-3-methylheptane 0.068 0.065 0.036 17.109 104.194 C11 Isoparaffin-4 0.011 0.010 0.006 2.690 106.148 C11-Isoparaffin-7 0.194 0.187 0.104 48.994 108.367 C11- Isoparaffin-11 0.445 0.430 0.238 112.411 112.967 C12 - IsoParaffin - 1 0.013 0.012 0.006 3.168

Aromatics Mono-Aromatics 45.140 71-42-3 Benzene 0.831 0.680 0.889 229.079

68.631 108-88-3 Toluene 6.056 5.021 5.489 1650.972 84.441 100-41-4 Ethylbenzene 1.020 0.846 0.802 275.975 85.671 108-38-3 m-Xylene 2.565 2.134 2.018 694.152 85.820 106-42-3 p-Xylene 1.157 0.966 0.911 313.155 88.653 95-47-6 o-Xylene 0.910 0.743 0.716 246.110 92.840 98-82-8 i-Propylbenzene 0.035 0.029 0.025 9.479 96.307 103-65-1 n-Propylbenzene 0.255 0.213 0.177 68.654 97.155 620-14-4 1-Methyl-3-ethylbenzene 0.997 0.829 0.693 268.029 97.389 622-96-8 1-Methyl-4-ethylbenzene 0.475 0.396 0.330 127.589 98.015 108-67-8 1,3,5-Trimethylbenzene 0.634 0.527 0.441 170.506 99.100 611-14-3 1-Methyl-2-ethylbenzene 0.388 0.317 0.270 104.326 100.737 95-63-6 1,2,4-Trimethylbenzene 1.953 1.603 1.357 525.082 102.390 538-93-2 i-Butylbenzene 0.094 0.079 0.058 25.039 103.612 526-73-8 1,2,3-Trimethylbenzene 0.352 0.283 0.245 94.713 104.005 535-77-3 1-Methyl-3-i-propylbenzene 0.014 0.012 0.009 3.714 106.334 141-93-5 1,3-Diethylbenzene 0.044 0.037 0.028 11.844 106.625 1074-43-7 1-Methyl-3-n-propylbenzene 0.649 0.542 0.404 173.548 106.918 105-05-5 1,4-Diethylbenzene 0.214 0.178 0.133 57.206 107.176 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.116 0.095 0.072 30.996 107.428 135-01-3 1,2-Diethylbenzene 0.045 0.037 0.028 11.949 108.026 1074-17-5 1-Methyl-2-n-propylbenzene 0.045 0.037 0.028 11.916 108.880 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.081 0.067 0.051 21.759 109.544 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.256 0.210 0.159 68.453 110.101 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.405 0.327 0.252 108.326 111.219 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.064 0.051 0.040 17.039 111.688 4218-48-8 1-Ethyl-4-i-propylbenzene 0.058 0.047 0.033 15.364 112.164 1,2,4,5-Tetramethylbenzene 0.195 0.158 0.122 52.220 112.430 527-53-7 1,2,3,5-Tetramethylbenzene 0.265 0.214 0.165 70.824 113.585 C11 - Aromatic - 3 0.045 0.036 0.025 11.872 113.903 1,2-Di-i-propylbenzene 0.032 0.026 0.017 8.578 114.118 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.046 0.037 0.026 12.203 114.281 C11 - Aromatic - 4 0.025 0.020 0.014 6.628 115.092 538-68-1 n-Pentylbenzene 0.011 0.009 0.006 2.876

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.321 tert-Pentylbenzene 0.045 0.036 0.025 11.966

115.634 577-55-9 1-Methyl-2-n-butylbenzene 0.019 0.016 0.011 5.161 115.745 C11 - Aromatic - 7 0.026 0.022 0.015 6.925 116.206 100-18-5 1,4-Di-i-propylbenzene 0.035 0.028 0.018 9.335 117.432 7364-19-4 1t-Butyl-4-ethylbenzene 0.004 0.003 0.002 1.144 117.737 1,3-Di-n-propylbenzene 0.029 0.023 0.015 7.625 117.847 C11 - Aromatic - 11 0.016 0.014 0.009 4.307 118.403 C11 - Aromatic - 12 0.010 0.008 0.006 2.639

Naphthalenes 116.633 91-20-3 Naphthalene 0.061 0.043 0.040 17.146

123.283 91-57-6 2-Methylnaphthalene 0.010 0.007 0.006 2.778 124.150 90-12-0 1-Methylnaphthalene 0.006 0.004 0.003 1.542

Naphtheno/Olefino-Benzs

113.763 874-35-1 5-Methylindan 0.077 0.062 0.049 20.644 114.766 824-63-5 2-Methylindan 0.082 0.066 0.052 21.813

Indenes 104.803 Indan 0.124 0.092 0.088 33.876

105.431 Indene 0.435 0.325 0.308 118.912 109.206 2-Methylindan 0.076 0.057 0.048 20.864 114.515 824-22-6 4-Methylindan 0.102 0.083 0.065 27.392 117.081 1,1-Dimethyl Indane 0.005 0.004 0.003 1.451

Naphthenes Mono-Naphthenes 27.092 287-92-3 Cyclopentane 0.449 0.433 0.535 114.905

40.168 96-37-7 Methylcyclopentane 2.373 2.279 2.355 607.301 47.063 110-82-7 Cyclohexane 1.762 1.628 1.749 451.067 52.885 1759-58-6 1t,3-Dimethylcyclopentane 0.242 0.232 0.206 61.894 53.471 2532-58-3 1c,3-Dimethylcyclopentane 0.195 0.188 0.166 49.809 54.098 822-50-4 1t,2-Dimethylcyclopentane 0.293 0.280 0.249 74.973 59.205 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.020 0.019 0.017 5.062 61.070 108-87-2 Methylcyclohexane 1.542 1.440 1.311 394.560 62.018 4516-69-2 1,1,3-Trimethylcyclopentane 0.038 0.036 0.028 9.687 63.860 1640-89-7 Ethylcyclopentane 0.052 0.049 0.044 13.312 65.930 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.035 0.033 0.026 8.961 67.460 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.030 0.028 0.022 7.567 72.865 1,3-dimethyl-t-cyclohexane 0.173 0.162 0.129 44.347 75.273 3c-Ethylmethylcyclopentane 0.009 0.009 0.007 2.399 75.493 3t-Ethylmethylcyclopentane 0.013 0.012 0.010 3.375 76.196 2207-03-6 1t,3-Dimethylcyclohexane 0.074 0.069 0.055 19.011 81.057 2207-01-4 1c,2-Dimethylcyclohexane 0.013 0.012 0.009 3.262 81.870 1678-91-7 Ethylcyclohexane 0.107 0.098 0.080 27.459 89.643 trans-1,3-Diethylcyclopentane 0.017 0.014 0.011 4.560

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.404 115-11-7 Isobutene 0.016 0.019 0.024 4.054

9.444 106-98-9 Butene-1 0.019 0.023 0.029 4.953

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 10.267 624-64-6 t-Butene-2 0.075 0.089 0.112 19.229

10.987 590-18-1 c-Butene-2 0.089 0.103 0.132 22.743 16.338 109-67-1 Pentene-1 0.346 0.388 0.412 88.469 18.797 646-04-8 t-Pentene-2 0.881 0.977 1.049 225.410 19.821 627-20-3 c-Pentene-2 0.483 0.530 0.575 123.614 32.943 592-41-6 Hexene-1 0.170 0.180 0.168 43.445 35.936 13269-52-8 t-Hexene-3 0.279 0.294 0.277 71.401 36.414 4050-45-7 t-Hexene-2 0.535 0.563 0.531 136.913 38.254 7688-21-3 c-Hexene-2 0.228 0.237 0.226 58.285 55.027 592-76-7 Heptene-1 0.031 0.032 0.027 8.050 56.883 14686-14-7 t-Heptene-3 0.035 0.036 0.030 8.889 57.839 7642-10-6 c-Heptene-3 0.026 0.027 0.022 6.690 58.748 14686-13-6 t-Heptene-2 0.017 0.018 0.015 4.402 110.731 693-61-8 2-Undecene, (E)- 0.034 0.033 0.020 8.523

Iso-Olefins 13.128 563-45-1 3-Methylbutene-1 0.300 0.344 0.357 76.734

17.172 563-46-2 2-Methylbutene-1 0.525 0.581 0.626 134.460 20.491 513-35-9 2-Methylbutene-2 1.084 1.177 1.291 277.414 28.695 691-38-3 4-Methyl-c-pentene-2 0.047 0.050 0.047 12.061 29.349 674-76-0 4-Methyl-t-pentene-2 0.138 0.148 0.137 35.376 32.722 763-29-1 2-Methylpentene-1 0.237 0.249 0.235 60.619 36.906 625-27-4 2-Methylpentene-2 0.363 0.377 0.360 92.848 37.321 922-62-3 3-Methyl-c-pentene-2 0.281 0.289 0.278 71.798 39.590 3404-73-7 3,3-Dimethylpentene-1 0.332 0.340 0.283 85.027 42.039 594-56-9 2,3,3-Trimethylbutene-1 0.015 0.015 0.013 3.775 46.162 3404-61-3 3-Methylhexene-1 0.017 0.017 0.014 4.257 46.749 3524-73-0 5-Methylhexene-1 0.084 0.087 0.071 21.467 48.806 15840-60-5 2-Methyl-c-hexene-3 0.043 0.045 0.037 11.006 49.152 3769-23-1 4-Methylhexene-1 0.011 0.011 0.009 2.847 49.805 3404-55-5 4-Methyl-t/c-hexene-2 0.054 0.055 0.046 13.838 54.402 C7 - Iso-Olefin - 2 0.024 0.024 0.020 6.018 56.365 4914-89-0 3-Methyl-c-hexene-3 0.015 0.015 0.013 3.865 57.246 6094-02-6 2-Methylhexene-1 0.062 0.064 0.053 15.916 58.118 2738-19-4 2-Methyl-2-hexene 0.028 0.029 0.024 7.239 58.363 3899-36-3 3-Methyl-t-hexene-3 0.022 0.022 0.018 5.522 59.649 20710-38-8 3-Methyl-t-hexene-2 0.016 0.016 0.014 4.157 60.434 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.012 3.666 70.131 C8 - Diolefin - 1 0.012 0.011 0.009 3.017 80.619 C9 - IsoOlefin - 1 0.013 0.012 0.010 3.335 86.221 C9-IsoOlefin-3 0.011 0.010 0.007 2.846

Naphtheno-Olefins 25.250 142-29-0 Cyclopentene 0.206 0.192 0.253 54.331

45.347 693-89-0 1-Methylcyclopentene 0.388 0.358 0.395 101.725 50.675 110-83-8 Cyclohexene 0.047 0.042 0.048 12.145

Di-Olefins 18.209 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.011 0.013 2.829

20.823 2004-70-8 1t,3-Pentadiene 0.016 0.017 0.020 4.233

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Di-Olefins Oxygenates 12.745 64-17-5 Ethanol 9.196 8.379 16.672 1011.630

26.498 71-23-8 n-Propanol 0.112 0.101 0.156 20.102

Unidentified 22.064 Unidentified 0.006 0.006 0.008 1.883

26.426 Unidentified 0.044 0.039 0.061 13.657 28.233 Unidentified 0.054 0.052 0.051 16.789 44.938 Unidentified 0.012 0.012 0.013 3.894 47.602 Unidentified 0.036 0.037 0.031 11.379 72.096 Unidentified 0.073 0.073 0.054 23.034 74.105 Unidentified 0.027 0.025 0.020 8.494 75.910 Unidentified 0.014 0.014 0.009 4.366 78.511 Unidentified 0.051 0.050 0.034 16.140 82.676 Unidentified 0.020 0.021 0.013 6.335 84.621 Unidentified 0.026 0.025 0.017 8.075 84.862 Unidentified 0.031 0.029 0.021 9.743 85.966 Unidentified 0.060 0.060 0.039 18.870 86.329 Unidentified 0.011 0.011 0.007 3.430 88.481 Unidentified 0.118 0.125 0.078 37.130 93.600 Unidentified 0.044 0.043 0.026 13.696 98.885 Unidentified 0.235 0.233 0.138 73.669 100.129 Unidentified 0.020 0.014 0.011 6.177 100.254 Unidentified 0.059 0.057 0.031 18.380 100.942 Unidentified 0.041 0.042 0.025 12.941 101.065 Unidentified 0.022 0.022 0.013 7.033 102.976 Unidentified 0.018 0.017 0.010 5.618 104.395 Unidentified 0.066 0.055 0.041 20.702 107.888 Unidentified 0.050 0.048 0.027 15.627 108.163 Unidentified 0.058 0.057 0.032 18.289 108.245 Unidentified 0.051 0.049 0.027 15.925 108.549 Unidentified 0.145 0.140 0.077 45.338 108.982 Unidentified 0.454 0.372 0.283 142.345 110.529 Unidentified 0.014 0.012 0.007 4.250 110.858 Unidentified 0.082 0.080 0.049 25.775 111.133 Unidentified 0.068 0.057 0.038 21.219 111.799 Unidentified 0.038 0.031 0.021 11.848 112.786 Unidentified 0.016 0.013 0.010 4.914 113.294 Unidentified 0.022 0.022 0.011 6.961 114.682 Unidentified 0.023 0.019 0.013 7.181 114.979 Unidentified 0.008 0.007 0.005 2.641

Plus

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

Unidentified n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2

2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3 4-Methylhexene-1 4-Methyl-t/c-hexene-2

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane

2,3,4-Trimethylpentane

Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

2,2,5-Trimethylhexane

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF95.090.085.080.075.0 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane C10 - IsoParaffin - 2 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2

1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF Sample: ODDB-91308 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91308 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000004.D\SIG1000004_FID1_A.CDF145.0140.0135.0130.0125.0

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 9.494 11.579 14.880

I-Paraffins 52.502 54.556 46.950

Aromatics 23.810 19.614 20.918 Mono-Aromatics 21.324 17.732 18.928 Naphthalenes 0.126 0.089 0.094 Naphtheno/Olefino-Benzs 0.216 0.175 0.159 Indenes 2.145 1.618 1.737

Naphthenes 1.287 1.235 1.441 Mono-Naphthenes 1.287 1.235 1.441 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.508 8.052 9.629 n-Olefins 3.380 3.707 4.450 Iso-Olefins 3.513 3.770 4.394 Naphtheno-Olefins 0.591 0.549 0.751 Di-Olefins 0.024 0.026 0.034

Oxygenates 0.198 0.179 0.321

Unidentified 5.201 4.786 5.860

Plus 0.000 0.000 0.000

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.199 0.181 0.324 C4 7.925 9.888 13.300 C5 9.788 11.132 13.380 C6 9.084 9.500 10.459 C7 8.451 7.786 8.669 C8 34.173 33.913 29.491 C9 9.859 9.042 7.757 C10 12.601 11.229 9.050 C11 2.511 2.369 1.586 C12 0.208 0.176 0.124

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.002 C4 7.610 9.509 12.756 C5 0.877 1.014 1.185 C6 0.455 0.499 0.514 C7 0.092 0.097 0.090 C8 0.028 0.029 0.024 C9 0.274 0.276 0.208 C10 0.062 0.061 0.042 C11 0.095 0.093 0.059

I-Paraffins C4 0.045 0.059 0.076 C5 4.969 5.801 6.710 C6 4.277 4.698 4.835 C7 2.530 2.702 2.460 C8 28.765 29.389 24.534 C9 4.363 4.447 3.314 C10 5.610 5.571 3.811 C11 1.899 1.846 1.183 C12 0.045 0.043 0.026

Mono-Aromatics C6 0.663 0.545 0.827 C7 5.145 4.293 5.441 C8 5.332 4.450 4.893 C9 4.977 4.129 4.034 C10 4.660 3.866 3.383 C11 0.389 0.319 0.256 C12 0.158 0.128 0.095

Naphthalenes C10 0.104 0.073 0.079 C11 0.022 0.016 0.015

Naphtheno/Olefino-Benzs C10 0.216 0.175 0.159

Indenes C9 0.214 0.161 0.176 C10 1.891 1.427 1.534 C11 0.035 0.026 0.023 C12 0.005 0.004 0.004

Mono-Naphthenes C5 0.109 0.105 0.151 C6 0.892 0.859 1.033 C7 0.170 0.164 0.169 C8 0.032 0.030 0.028

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.032 0.028 0.024 C10 0.053 0.048 0.037

n-Olefins C4 0.270 0.320 0.468 C5 1.800 2.007 2.501 C6 1.222 1.292 1.414 C7 0.017 0.018 0.017 C11 0.071 0.069 0.049

Iso-Olefins C5 1.807 1.990 2.511 C6 1.187 1.246 1.374 C7 0.496 0.511 0.492 C8 0.017 0.016 0.013 C10 0.007 0.007 0.005

Naphtheno-Olefins C5 0.202 0.189 0.289 C6 0.390 0.360 0.462

Di-Olefins C5 0.024 0.026 0.034

Oxygenates C3 0.198 0.179 0.321

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.21 21.07 5% 27.39 26.01 10% 79.94 61.95 15% 96.88 81.49 20% 138.32 100.41 25% 155.78 140.92 30% 197.12 164.98 35% 209.78 209.22 40% 210.50 209.91 45% 230.00 215.65 50% 231.59 230.20 55% 235.89 232.78 60% 237.84 236.60 65% 247.22 238.31 70% 277.14 250.85 75% 296.60 281.40 80% 331.74 320.72 85% 335.68 332.38 90% 358.47 352.22 95% 363.20 363.20 FBP 404.36 399.20

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.391 74-98-6 P3 Propane 0.001 0.001 0.002 0.238 2 8.614 75-28-5 I4 i-Butane 0.045 0.059 0.076 10.860 3 9.406 115-11-7 K4 Isobutene 0.024 0.029 0.041 5.882 4 9.445 106-98-9 K4 Butene-1 0.028 0.034 0.049 6.958 5 9.794 106-97-8 P4 n-Butane 7.610 9.509 12.756 1825.633 6 10.269 624-64-6 K4 t-Butene-2 0.103 0.123 0.178 25.477 7 10.392 463-82-1 I5 2,2-Dimethylpropane 0.016 0.020 0.022 3.924 8 10.990 590-18-1 K4 c-Butene-2 0.115 0.134 0.201 28.695 9 13.132 563-45-1 C5 3-Methylbutene-1 0.079 0.091 0.109 19.531 10 14.711 78-78-4 I5 i-Pentane 4.953 5.781 6.688 1196.406

11 16.335 109-67-1 K5 Pentene-1 0.361 0.408 0.501 89.699 12 17.174 563-46-2 C5 2-Methylbutene-1 0.565 0.628 0.785 140.345 13 17.694 109-66-0 P5 n-Pentane 0.877 1.014 1.185 211.976 14 18.213 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.010 0.014 2.525 15 18.805 646-04-8 K5 t-Pentene-2 0.930 1.038 1.292 231.167 16 19.439 ? Unidentified 0.006 0.007 0.009 1.943 17 19.822 627-20-3 K5 c-Pentene-2 0.509 0.561 0.707 126.428 18 20.493 513-35-9 C5 2-Methylbutene-2 1.164 1.271 1.617 289.185 19 20.830 2004-70-8 E5 1t,3-Pentadiene 0.014 0.015 0.020 3.628 20 22.645 75-83-2 I6 2,2-Dimethylbutane 0.034 0.038 0.039 8.285

21 25.253 142-29-0 B5 Cyclopentene 0.202 0.189 0.289 51.612 22 26.495 71-23-8 X3 n-Propanol 0.198 0.179 0.321 34.490 23 27.103 287-92-3 M5 Cyclopentane 0.109 0.105 0.151 26.962 24 27.841 79-29-8 I6 2,3-Dimethylbutane 1.239 1.355 1.401 300.613 25 28.236 ? Unidentified 0.056 0.055 0.062 17.185 26 28.696 691-38-3 C6 4-Methyl-c-pentene-2 0.049 0.053 0.057 12.274 27 28.909 107-83-5 I6 2-Methylpentane 1.873 2.074 2.117 454.233 28 29.342 674-76-0 C6 4-Methyl-t-pentene-2 0.146 0.157 0.169 36.318 29 31.558 96-14-0 I6 3-Methylpentane 1.130 1.231 1.278 274.132 30 32.719 763-29-1 C6 2-Methylpentene-1 0.248 0.262 0.287 61.701

31 32.942 592-41-6 K6 Hexene-1 0.170 0.181 0.196 42.151 32 35.133 760-21-4 C6 2-Ethylbutene-1 0.076 0.079 0.088 18.784 33 35.289 110-54-3 P6 n-Hexane 0.455 0.499 0.514 110.296 34 35.936 13269-52-8 K6 t-Hexene-3 0.284 0.302 0.329 70.681 35 36.412 4050-45-7 K6 t-Hexene-2 0.539 0.571 0.624 133.884 36 36.904 625-27-4 C6 2-Methylpentene-2 0.378 0.396 0.438 94.017 37 37.312 922-62-3 C6 3-Methyl-c-pentene-2 0.289 0.299 0.335 71.804 38 38.242 7688-21-3 K6 c-Hexene-2 0.229 0.239 0.265 56.822 39 39.582 3404-73-7 C7 3,3-Dimethylpentene-1 0.343 0.354 0.340 85.254 40 40.153 96-37-7 M6 Methylcyclopentane 0.816 0.788 0.944 202.724

41 41.734 108-08-7 I7 2,4-Dimethylpentane 1.061 1.140 1.031 258.258 42 42.041 594-56-9 C7 2,3,3-Trimethylbutene-1 0.012 0.012 0.012 2.989 43 42.281 464-06-2 I7 2,2,3-Trimethylbutane 0.054 0.057 0.053 13.225

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 44.929 ? Unidentified 0.011 0.011 0.013 3.443 45 45.137 71-42-3 Q6 Benzene 0.663 0.545 0.827 177.372 46 45.337 693-89-0 B6 1-Methylcyclopentene 0.352 0.327 0.418 89.681 47 46.159 3404-61-3 C7 3-Methylhexene-1 0.013 0.014 0.013 3.327 48 46.743 3524-73-0 C7 5-Methylhexene-1 0.022 0.023 0.022 5.581 49 47.051 110-82-7 M6 Cyclohexane 0.076 0.071 0.088 18.902 50 47.587 ? Unidentified 0.030 0.031 0.030 9.268 51 48.806 15840-60-5 C7 2-Methyl-c-hexene-3 0.033 0.035 0.033 8.287 52 49.798 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.039 0.040 0.038 9.604 53 50.202 591-76-4 I7 2-Methylhexane 1.135 1.210 1.103 276.336

54 50.670 110-83-8 B6 Cyclohexene 0.037 0.033 0.044 9.213 55 52.028 589-34-4 I7 3-Methylhexane 0.281 0.295 0.273 68.305 56 52.885 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.067 0.065 0.066 16.641 57 53.472 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.043 0.042 0.043 10.746 58 54.101 822-50-4 M7 1t,2-Dimethylcyclopentane 0.033 0.031 0.032 8.102 59 54.750 540-84-1 I8 2,2,4-Trimethylpentane 9.991 10.444 8.522 2437.780 60 56.883 14686-14-7 K7 t-Heptene-3 0.017 0.018 0.017 4.325 61 57.235 6094-02-6 C7 2-Methylhexene-1 0.027 0.028 0.027 6.823 62 57.614 142-82-5 P7 n-Heptane 0.092 0.097 0.090 22.433 63 58.114 2738-19-4 C7 2-Methyl-2-hexene 0.005 0.005 0.005 1.315

64 61.052 108-87-2 M7 Methylcyclohexane 0.028 0.026 0.027 6.859 65 64.513 564-02-3 I8 2,2,3-Trimethylpentane 0.713 0.720 0.608 173.975 66 64.762 592-13-2 I8 2,5-Dimethylhexane 1.590 1.658 1.356 387.889 67 65.100 589-43-5 I8 2,4-Dimethylhexane 1.521 1.571 1.297 371.133 68 68.121 565-75-3 I8 2,3,4-Trimethylpentane 6.067 6.103 5.175 1480.332 69 68.628 108-88-3 Q7 Toluene 5.145 4.293 5.441 1361.918 70 68.800 560-21-4 I8 2,3,3-Trimethylpentane 6.862 6.835 5.853 1674.338 71 70.438 584-94-1 I8 2,3-Dimethylhexane 1.675 1.701 1.428 408.602 72 71.699 592-27-8 I8 2-Methylheptane 0.086 0.089 0.073 21.022 73 71.965 589-53-7 I8 4-Methylheptane 0.184 0.189 0.157 44.962

74 72.096 ? Unidentified 0.138 0.138 0.117 41.908 75 73.022 589-81-1 I8 3-Methylheptane 0.075 0.077 0.064 18.404 76 74.944 3522-94-9 I9 2,2,5-Trimethylhexane 3.375 3.451 2.563 825.027 77 75.910 3875-51-2 M8 i-Propylcyclopentane 0.032 0.030 0.028 7.902 78 77.564 111-65-9 P8 n-Octane 0.028 0.029 0.024 6.759 79 78.507 ? Unidentified 0.078 0.076 0.059 23.702 80 80.057 1069-53-0 I9 2,3,5-Trimethylhexane 0.534 0.535 0.405 130.490 81 81.233 1071-26-7 I9 2,4-Dimethylheptane 0.077 0.078 0.058 18.744 82 82.195 1072-05-5 I9 2,6-Dimethylheptane 0.097 0.099 0.073 23.610 83 83.129 I9 2,5-Dimethylheptane 0.255 0.257 0.193 62.228

84 84.439 100-41-4 Q8 Ethylbenzene 1.009 0.842 0.926 265.092 85 84.617 ? Unidentified 0.035 0.035 0.028 10.715 86 84.858 ? Unidentified 0.029 0.027 0.022 8.815

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 85.666 108-38-3 Q8 m-Xylene 2.374 1.987 2.178 623.536 88 85.815 106-42-3 Q8 p-Xylene 1.112 0.934 1.021 292.195 89 85.963 ? Unidentified 0.081 0.081 0.062 24.719 90 86.220 C8 C9-IsoOlefin-3 0.017 0.016 0.013 4.207 91 86.328 ? Unidentified 0.014 0.014 0.011 4.378 92 87.147 3221-61-2 I9 2-Methyloctane 0.017 0.017 0.013 4.036 93 88.012 2216-33-3 I9 3-Methyloctane 0.010 0.010 0.008 2.537 94 88.480 ? Unidentified 0.162 0.171 0.125 49.219 95 88.650 95-47-6 Q8 o-Xylene 0.836 0.687 0.768 219.714 96 89.068 I10 C10 - IsoParaffin - 1 0.562 0.559 0.385 137.798

97 89.914 14720-74-2 I10 2,2,4-trimethylheptane 0.387 0.385 0.265 94.884 98 91.459 111-84-2 P9 n-Nonane 0.274 0.276 0.208 66.938 99 92.087 4926-90-3 M9 1,1-Methylethylcyclohexane 0.025 0.022 0.019 6.224 100 92.837 98-82-8 Q9 i-Propylbenzene 0.033 0.028 0.027 8.711 101 93.027 ? Unidentified 0.017 0.016 0.013 5.298 102 93.027 ? Unidentified 0.017 0.018 0.012 5.298 103 93.027 ? Unidentified 0.017 0.013 0.012 5.298 104 93.135 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.007 0.006 0.005 1.660 105 93.135 C10 C10-IsoOlefin-4 0.007 0.007 0.005 1.660 106 93.135 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.660

107 93.602 ? Unidentified 0.213 0.212 0.146 64.761 108 93.825 15869-87-1 I10 2,2-Dimethyloctane 0.073 0.073 0.050 17.793 109 94.267 ? Unidentified 0.023 0.017 2.266 7.078 110 94.267 ? Unidentified 0.023 0.024 0.016 7.078 111 94.623 15869-89-3 I10 2,5-Dimethyloctane 0.112 0.111 0.076 27.337 112 95.101 2040-95-1 I10 2,7-Dimethyloctane 0.054 0.053 0.037 13.127 113 95.266 2051-30-1 I10 2,4-Dimethyloctane 0.242 0.241 0.166 59.312 114 95.660 I10 2,6-Dimethyloctane 0.071 0.070 0.048 17.322 115 96.304 103-65-1 Q9 n-Propylbenzene 0.268 0.225 0.217 69.964 116 97.153 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.940 0.787 0.762 245.384

117 97.387 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.442 0.371 0.358 115.423 118 98.013 108-67-8 Q9 1,3,5-Trimethylbenzene 0.652 0.545 0.528 170.112 119 98.902 I10 2,2,6-Trimethyloctane 3.607 3.591 2.470 883.576 120 99.099 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.359 0.295 0.291 93.606 121 99.472 ? Unidentified 0.011 0.011 0.008 3.397 122 99.663 5911-04-6 I10 3-Methylnonane 0.016 0.015 0.011 3.801 123 99.839 ? Unidentified 0.011 0.011 0.007 3.261 124 100.129 ? Unidentified 0.214 0.155 0.134 65.229 125 100.256 ? Unidentified 0.571 0.555 0.356 173.820 126 100.481 I11 C11-Isoparaffin-2 0.306 0.298 0.191 75.057

127 100.737 95-63-6 Q9 1,2,4-Trimethylbenzene 1.933 1.597 1.567 504.588 128 100.945 ? Unidentified 0.352 0.363 0.244 107.019 129 101.066 ? Unidentified 0.208 0.206 0.143 63.457

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 101.323 1678-98-4 M10 i-Butylcyclohexane 0.051 0.046 0.035 12.644 131 101.966 ? Unidentified 0.020 0.018 0.014 6.013 132 102.111 17302-01-1 I10 3-Ethyl-3-methylheptane 0.487 0.474 0.304 119.460 133 102.324 ? Unidentified 0.139 0.118 0.101 42.320 134 102.465 538-93-2 Q10 i-Butylbenzene 0.341 0.289 0.248 88.576 135 102.662 124-18-5 P10 n-Decane 0.062 0.061 0.042 15.142 136 102.976 ? Unidentified 0.131 0.128 0.082 39.935 137 103.468 ? Unidentified 0.016 0.013 0.013 4.772 138 103.614 526-73-8 Q9 1,2,3-Trimethylbenzene 0.349 0.282 0.283 91.056 139 103.978 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.040 0.033 0.029 10.293

140 104.192 I11 C11 Isoparaffin-4 0.057 0.056 0.036 14.100 141 104.397 ? Unidentified 0.280 0.236 0.203 85.224 142 104.803 J9 Indan 0.214 0.161 0.176 56.785 143 105.059 I11 C11-Isoparaffin-5 0.028 0.027 0.017 6.878 144 105.440 J10 Indene 1.607 1.206 1.325 426.325 145 105.857 M10 n-ButylCyclohexane 0.002 0.002 0.001 0.534 146 105.994 ? Unidentified 0.013 0.012 0.009 3.965 147 106.154 I11 C11-Isoparaffin-7 0.582 0.566 0.363 142.769 148 106.335 141-93-5 Q10 1,3-Diethylbenzene 0.049 0.041 0.036 12.828 149 106.634 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.607 1.350 1.167 417.204

150 106.905 105-05-5 Q10 1,4-Diethylbenzene 0.459 0.385 0.333 119.254 151 107.176 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.136 0.112 0.099 35.293 152 107.423 135-01-3 Q10 1,2-Diethylbenzene 0.128 0.105 0.093 33.253 153 107.889 ? Unidentified 0.133 0.130 0.083 40.617 154 108.026 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.056 0.046 0.041 14.536 155 108.164 ? Unidentified 0.132 0.129 0.083 40.238 156 108.245 ? Unidentified 0.123 0.120 0.077 37.475 157 108.369 I11 C11- Isoparaffin-11 0.925 0.899 0.576 226.780 158 108.552 ? Unidentified 0.302 0.293 0.188 91.811 159 108.984 ? Unidentified 0.905 0.746 0.657 275.522

160 109.205 J10 2-Methylindan 0.146 0.110 0.108 38.783 161 109.544 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.368 0.304 0.267 95.474 162 109.703 ? Unidentified 0.063 0.047 0.046 19.169 163 110.102 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.781 0.634 0.567 202.650 164 110.528 ? Unidentified 0.031 0.028 0.020 9.567 165 110.729 693-61-8 K11 2-Undecene, (E)- 0.071 0.069 0.049 17.406 166 110.859 ? Unidentified 0.148 0.145 0.103 45.088 167 111.132 ? Unidentified 0.130 0.110 0.085 39.466 168 111.215 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.083 0.067 0.060 21.476 169 111.532 1120-21-4 P11 n-Undecane 0.095 0.093 0.059 23.348

170 111.688 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.106 0.086 0.070 27.365 171 111.798 ? Unidentified 0.074 0.060 0.048 22.449 172 112.163 Q10 1,2,4,5-Tetramethylbenzene 0.264 0.215 0.192 68.534

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 112.429 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.348 0.283 0.253 90.340 174 112.653 ? Unidentified 0.013 0.011 0.009 4.083 175 112.784 ? Unidentified 0.022 0.018 0.016 6.611 176 112.965 I12 C12 - IsoParaffin - 1 0.028 0.028 0.016 6.984 177 113.296 ? Unidentified 0.036 0.036 0.022 11.096 178 113.447 ? Unidentified 0.014 0.014 0.008 4.326 179 113.654 ? Unidentified 0.071 0.058 0.047 21.743 180 113.760 874-35-1 H10 5-Methylindan 0.108 0.087 0.079 27.938 181 113.901 Q12 1,2-Di-i-propylbenzene 0.048 0.039 0.029 12.271 182 114.117 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.064 0.052 0.042 16.605

183 114.290 Q11 C11 - Aromatic - 4 0.040 0.033 0.027 10.448 184 114.513 824-22-6 J10 4-Methylindan 0.137 0.111 0.101 35.591 185 114.683 ? Unidentified 0.031 0.025 0.020 9.474 186 114.765 824-63-5 H10 2-Methylindan 0.108 0.088 0.080 28.076 187 114.978 ? Unidentified 0.014 0.011 0.009 4.236 188 115.090 538-68-1 Q11 n-Pentylbenzene 0.016 0.013 0.011 4.160 189 115.320 Q11 tert-Pentylbenzene 0.059 0.048 0.039 15.326 190 115.632 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.029 0.024 0.019 7.604 191 115.744 Q11 C11 - Aromatic - 7 0.040 0.034 0.026 10.364 192 116.093 I12 C12 - IsoParaffin - 4 0.016 0.016 0.009 4.203

193 116.205 100-18-5 Q12 1,4-Di-i-propylbenzene 0.054 0.044 0.032 13.846 194 116.636 91-20-3 G10 Naphthalene 0.104 0.073 0.079 28.146 195 116.796 J11 4,7-Dimethyl Indane 0.022 0.017 0.015 5.944 196 116.972 ? Unidentified 0.007 0.006 0.004 2.091 197 117.079 J11 1,1-Dimethyl Indane 0.013 0.009 0.008 3.327 198 117.248 J12 Dimethyl Indane - 1 0.005 0.004 0.004 1.448 199 117.431 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.010 0.008 0.006 2.680 200 117.734 Q12 1,3-Di-n-propylbenzene 0.038 0.031 0.023 9.758 201 117.847 Q11 C11 - Aromatic - 11 0.019 0.017 0.013 5.024 202 118.402 Q11 C11 - Aromatic - 12 0.014 0.012 0.009 3.732

203 122.541 877-44-1 Q12 1,2,4-Triethylbenzene 0.008 0.007 0.005 2.176 204 123.280 91-57-6 G11 2-Methylnaphthalene 0.015 0.011 0.010 4.101 205 124.146 90-12-0 G11 1-Methylnaphthalene 0.007 0.005 0.005 1.903 206 126.171 ? Unidentified 0.009 0.008 0.006 2.827 207 126.171 ? Unidentified 0.009 0.008 0.005 2.827 208 126.171 ? Unidentified 0.009 0.009 0.005 2.827 209 127.135 ? Unidentified 0.003 0.003 0.001 0.914

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.391 74-98-6 Propane 0.001 0.001 0.002 0.238

9.794 106-97-8 n-Butane 7.610 9.509 12.756 1825.633 17.694 109-66-0 n-Pentane 0.877 1.014 1.185 211.976 35.289 110-54-3 n-Hexane 0.455 0.499 0.514 110.296 57.614 142-82-5 n-Heptane 0.092 0.097 0.090 22.433 77.564 111-65-9 n-Octane 0.028 0.029 0.024 6.759 91.459 111-84-2 n-Nonane 0.274 0.276 0.208 66.938 102.662 124-18-5 n-Decane 0.062 0.061 0.042 15.142 111.532 1120-21-4 n-Undecane 0.095 0.093 0.059 23.348

I-Paraffins 8.614 75-28-5 i-Butane 0.045 0.059 0.076 10.860

10.392 463-82-1 2,2-Dimethylpropane 0.016 0.020 0.022 3.924 14.711 78-78-4 i-Pentane 4.953 5.781 6.688 1196.406 22.645 75-83-2 2,2-Dimethylbutane 0.034 0.038 0.039 8.285 27.841 79-29-8 2,3-Dimethylbutane 1.239 1.355 1.401 300.613 28.909 107-83-5 2-Methylpentane 1.873 2.074 2.117 454.233 31.558 96-14-0 3-Methylpentane 1.130 1.231 1.278 274.132 41.734 108-08-7 2,4-Dimethylpentane 1.061 1.140 1.031 258.258 42.281 464-06-2 2,2,3-Trimethylbutane 0.054 0.057 0.053 13.225 50.202 591-76-4 2-Methylhexane 1.135 1.210 1.103 276.336 52.028 589-34-4 3-Methylhexane 0.281 0.295 0.273 68.305 54.750 540-84-1 2,2,4-Trimethylpentane 9.991 10.444 8.522 2437.780 64.513 564-02-3 2,2,3-Trimethylpentane 0.713 0.720 0.608 173.975 64.762 592-13-2 2,5-Dimethylhexane 1.590 1.658 1.356 387.889 65.100 589-43-5 2,4-Dimethylhexane 1.521 1.571 1.297 371.133 68.121 565-75-3 2,3,4-Trimethylpentane 6.067 6.103 5.175 1480.332 68.800 560-21-4 2,3,3-Trimethylpentane 6.862 6.835 5.853 1674.338 70.438 584-94-1 2,3-Dimethylhexane 1.675 1.701 1.428 408.602 71.699 592-27-8 2-Methylheptane 0.086 0.089 0.073 21.022 71.965 589-53-7 4-Methylheptane 0.184 0.189 0.157 44.962 73.022 589-81-1 3-Methylheptane 0.075 0.077 0.064 18.404 74.944 3522-94-9 2,2,5-Trimethylhexane 3.375 3.451 2.563 825.027 80.057 1069-53-0 2,3,5-Trimethylhexane 0.534 0.535 0.405 130.490 81.233 1071-26-7 2,4-Dimethylheptane 0.077 0.078 0.058 18.744 82.195 1072-05-5 2,6-Dimethylheptane 0.097 0.099 0.073 23.610 83.129 2,5-Dimethylheptane 0.255 0.257 0.193 62.228 87.147 3221-61-2 2-Methyloctane 0.017 0.017 0.013 4.036 88.012 2216-33-3 3-Methyloctane 0.010 0.010 0.008 2.537 89.068 C10 - IsoParaffin - 1 0.562 0.559 0.385 137.798 89.914 14720-74-2 2,2,4-trimethylheptane 0.387 0.385 0.265 94.884 93.135 C10-isoparaffin-x 0.000 0.000 0.000 1.660 93.825 15869-87-1 2,2-Dimethyloctane 0.073 0.073 0.050 17.793 94.623 15869-89-3 2,5-Dimethyloctane 0.112 0.111 0.076 27.337 95.101 2040-95-1 2,7-Dimethyloctane 0.054 0.053 0.037 13.127 95.266 2051-30-1 2,4-Dimethyloctane 0.242 0.241 0.166 59.312 95.660 2,6-Dimethyloctane 0.071 0.070 0.048 17.322 98.902 2,2,6-Trimethyloctane 3.607 3.591 2.470 883.576

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 99.663 5911-04-6 3-Methylnonane 0.016 0.015 0.011 3.801

100.481 C11-Isoparaffin-2 0.306 0.298 0.191 75.057 102.111 17302-01-1 3-Ethyl-3-methylheptane 0.487 0.474 0.304 119.460 104.192 C11 Isoparaffin-4 0.057 0.056 0.036 14.100 105.059 C11-Isoparaffin-5 0.028 0.027 0.017 6.878 106.154 C11-Isoparaffin-7 0.582 0.566 0.363 142.769 108.369 C11- Isoparaffin-11 0.925 0.899 0.576 226.780 112.965 C12 - IsoParaffin - 1 0.028 0.028 0.016 6.984 116.093 C12 - IsoParaffin - 4 0.016 0.016 0.009 4.203

Aromatics Mono-Aromatics 45.137 71-42-3 Benzene 0.663 0.545 0.827 177.372

68.628 108-88-3 Toluene 5.145 4.293 5.441 1361.918 84.439 100-41-4 Ethylbenzene 1.009 0.842 0.926 265.092 85.666 108-38-3 m-Xylene 2.374 1.987 2.178 623.536 85.815 106-42-3 p-Xylene 1.112 0.934 1.021 292.195 88.650 95-47-6 o-Xylene 0.836 0.687 0.768 219.714 92.837 98-82-8 i-Propylbenzene 0.033 0.028 0.027 8.711 96.304 103-65-1 n-Propylbenzene 0.268 0.225 0.217 69.964 97.153 620-14-4 1-Methyl-3-ethylbenzene 0.940 0.787 0.762 245.384 97.387 622-96-8 1-Methyl-4-ethylbenzene 0.442 0.371 0.358 115.423 98.013 108-67-8 1,3,5-Trimethylbenzene 0.652 0.545 0.528 170.112 99.099 611-14-3 1-Methyl-2-ethylbenzene 0.359 0.295 0.291 93.606 100.737 95-63-6 1,2,4-Trimethylbenzene 1.933 1.597 1.567 504.588 102.465 538-93-2 i-Butylbenzene 0.341 0.289 0.248 88.576 103.614 526-73-8 1,2,3-Trimethylbenzene 0.349 0.282 0.283 91.056 103.978 535-77-3 1-Methyl-3-i-propylbenzene 0.040 0.033 0.029 10.293 106.335 141-93-5 1,3-Diethylbenzene 0.049 0.041 0.036 12.828 106.634 1074-43-7 1-Methyl-3-n-propylbenzene 1.607 1.350 1.167 417.204 106.905 105-05-5 1,4-Diethylbenzene 0.459 0.385 0.333 119.254 107.176 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.136 0.112 0.099 35.293 107.423 135-01-3 1,2-Diethylbenzene 0.128 0.105 0.093 33.253 108.026 1074-17-5 1-Methyl-2-n-propylbenzene 0.056 0.046 0.041 14.536 109.544 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.368 0.304 0.267 95.474 110.102 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.781 0.634 0.567 202.650 111.215 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.083 0.067 0.060 21.476 111.688 4218-48-8 1-Ethyl-4-i-propylbenzene 0.106 0.086 0.070 27.365 112.163 1,2,4,5-Tetramethylbenzene 0.264 0.215 0.192 68.534 112.429 527-53-7 1,2,3,5-Tetramethylbenzene 0.348 0.283 0.253 90.340 113.901 1,2-Di-i-propylbenzene 0.048 0.039 0.029 12.271 114.117 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.064 0.052 0.042 16.605 114.290 C11 - Aromatic - 4 0.040 0.033 0.027 10.448 115.090 538-68-1 n-Pentylbenzene 0.016 0.013 0.011 4.160 115.320 tert-Pentylbenzene 0.059 0.048 0.039 15.326 115.632 577-55-9 1-Methyl-2-n-butylbenzene 0.029 0.024 0.019 7.604 115.744 C11 - Aromatic - 7 0.040 0.034 0.026 10.364 116.205 100-18-5 1,4-Di-i-propylbenzene 0.054 0.044 0.032 13.846

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 117.431 7364-19-4 1t-Butyl-4-ethylbenzene 0.010 0.008 0.006 2.680

117.734 1,3-Di-n-propylbenzene 0.038 0.031 0.023 9.758 117.847 C11 - Aromatic - 11 0.019 0.017 0.013 5.024 118.402 C11 - Aromatic - 12 0.014 0.012 0.009 3.732 122.541 877-44-1 1,2,4-Triethylbenzene 0.008 0.007 0.005 2.176

Naphthalenes 116.636 91-20-3 Naphthalene 0.104 0.073 0.079 28.146

123.280 91-57-6 2-Methylnaphthalene 0.015 0.011 0.010 4.101 124.146 90-12-0 1-Methylnaphthalene 0.007 0.005 0.005 1.903

Naphtheno/Olefino-Benzs

113.760 874-35-1 5-Methylindan 0.108 0.087 0.079 27.938 114.765 824-63-5 2-Methylindan 0.108 0.088 0.080 28.076

Indenes 104.803 Indan 0.214 0.161 0.176 56.785

105.440 Indene 1.607 1.206 1.325 426.325 109.205 2-Methylindan 0.146 0.110 0.108 38.783 114.513 824-22-6 4-Methylindan 0.137 0.111 0.101 35.591 116.796 4,7-Dimethyl Indane 0.022 0.017 0.015 5.944 117.079 1,1-Dimethyl Indane 0.013 0.009 0.008 3.327 117.248 Dimethyl Indane - 1 0.005 0.004 0.004 1.448

Naphthenes Mono-Naphthenes 27.103 287-92-3 Cyclopentane 0.109 0.105 0.151 26.962

40.153 96-37-7 Methylcyclopentane 0.816 0.788 0.944 202.724 47.051 110-82-7 Cyclohexane 0.076 0.071 0.088 18.902 52.885 1759-58-6 1t,3-Dimethylcyclopentane 0.067 0.065 0.066 16.641 53.472 2532-58-3 1c,3-Dimethylcyclopentane 0.043 0.042 0.043 10.746 54.101 822-50-4 1t,2-Dimethylcyclopentane 0.033 0.031 0.032 8.102 61.052 108-87-2 Methylcyclohexane 0.028 0.026 0.027 6.859 75.910 3875-51-2 i-Propylcyclopentane 0.032 0.030 0.028 7.902 92.087 4926-90-3 1,1-Methylethylcyclohexane 0.025 0.022 0.019 6.224 93.135 696-29-7 1-Methyl-2-propyl-cyclopentan 0.007 0.006 0.005 1.660 101.323 1678-98-4 i-Butylcyclohexane 0.051 0.046 0.035 12.644 105.857 n-ButylCyclohexane 0.002 0.002 0.001 0.534

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.406 115-11-7 Isobutene 0.024 0.029 0.041 5.882

9.445 106-98-9 Butene-1 0.028 0.034 0.049 6.958 10.269 624-64-6 t-Butene-2 0.103 0.123 0.178 25.477 10.990 590-18-1 c-Butene-2 0.115 0.134 0.201 28.695 16.335 109-67-1 Pentene-1 0.361 0.408 0.501 89.699 18.805 646-04-8 t-Pentene-2 0.930 1.038 1.292 231.167 19.822 627-20-3 c-Pentene-2 0.509 0.561 0.707 126.428 32.942 592-41-6 Hexene-1 0.170 0.181 0.196 42.151 35.936 13269-52-8 t-Hexene-3 0.284 0.302 0.329 70.681 36.412 4050-45-7 t-Hexene-2 0.539 0.571 0.624 133.884

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 38.242 7688-21-3 c-Hexene-2 0.229 0.239 0.265 56.822

56.883 14686-14-7 t-Heptene-3 0.017 0.018 0.017 4.325 110.729 693-61-8 2-Undecene, (E)- 0.071 0.069 0.049 17.406

Iso-Olefins 13.132 563-45-1 3-Methylbutene-1 0.079 0.091 0.109 19.531

17.174 563-46-2 2-Methylbutene-1 0.565 0.628 0.785 140.345 20.493 513-35-9 2-Methylbutene-2 1.164 1.271 1.617 289.185 28.696 691-38-3 4-Methyl-c-pentene-2 0.049 0.053 0.057 12.274 29.342 674-76-0 4-Methyl-t-pentene-2 0.146 0.157 0.169 36.318 32.719 763-29-1 2-Methylpentene-1 0.248 0.262 0.287 61.701 35.133 760-21-4 2-Ethylbutene-1 0.076 0.079 0.088 18.784 36.904 625-27-4 2-Methylpentene-2 0.378 0.396 0.438 94.017 37.312 922-62-3 3-Methyl-c-pentene-2 0.289 0.299 0.335 71.804 39.582 3404-73-7 3,3-Dimethylpentene-1 0.343 0.354 0.340 85.254 42.041 594-56-9 2,3,3-Trimethylbutene-1 0.012 0.012 0.012 2.989 46.159 3404-61-3 3-Methylhexene-1 0.013 0.014 0.013 3.327 46.743 3524-73-0 5-Methylhexene-1 0.022 0.023 0.022 5.581 48.806 15840-60-5 2-Methyl-c-hexene-3 0.033 0.035 0.033 8.287 49.798 3404-55-5 4-Methyl-t/c-hexene-2 0.039 0.040 0.038 9.604 57.235 6094-02-6 2-Methylhexene-1 0.027 0.028 0.027 6.823 58.114 2738-19-4 2-Methyl-2-hexene 0.005 0.005 0.005 1.315 86.220 C9-IsoOlefin-3 0.017 0.016 0.013 4.207 93.135 C10-IsoOlefin-4 0.007 0.007 0.005 1.660

Naphtheno-Olefins 25.253 142-29-0 Cyclopentene 0.202 0.189 0.289 51.612

45.337 693-89-0 1-Methylcyclopentene 0.352 0.327 0.418 89.681 50.670 110-83-8 Cyclohexene 0.037 0.033 0.044 9.213

Di-Olefins 18.213 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.010 0.014 2.525

20.830 2004-70-8 1t,3-Pentadiene 0.014 0.015 0.020 3.628

Oxygenates 26.495 71-23-8 n-Propanol 0.198 0.179 0.321 34.490

Unidentified 19.439 Unidentified 0.006 0.007 0.009 1.943

28.236 Unidentified 0.056 0.055 0.062 17.185 44.929 Unidentified 0.011 0.011 0.013 3.443 47.587 Unidentified 0.030 0.031 0.030 9.268 72.096 Unidentified 0.138 0.138 0.117 41.908 78.507 Unidentified 0.078 0.076 0.059 23.702 84.617 Unidentified 0.035 0.035 0.028 10.715 84.858 Unidentified 0.029 0.027 0.022 8.815 85.963 Unidentified 0.081 0.081 0.062 24.719 86.328 Unidentified 0.014 0.014 0.011 4.378 88.480 Unidentified 0.162 0.171 0.125 49.219 93.027 Unidentified 0.017 0.016 0.013 5.298 93.027 Unidentified 0.017 0.018 0.012 5.298 93.027 Unidentified 0.017 0.013 0.012 5.298

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 93.602 Unidentified 0.213 0.212 0.146 64.761

94.267 Unidentified 0.023 0.017 2.266 7.078 94.267 Unidentified 0.023 0.024 0.016 7.078 99.472 Unidentified 0.011 0.011 0.008 3.397 99.839 Unidentified 0.011 0.011 0.007 3.261 100.129 Unidentified 0.214 0.155 0.134 65.229 100.256 Unidentified 0.571 0.555 0.356 173.820 100.945 Unidentified 0.352 0.363 0.244 107.019 101.066 Unidentified 0.208 0.206 0.143 63.457 101.966 Unidentified 0.020 0.018 0.014 6.013 102.324 Unidentified 0.139 0.118 0.101 42.320 102.976 Unidentified 0.131 0.128 0.082 39.935 103.468 Unidentified 0.016 0.013 0.013 4.772 104.397 Unidentified 0.280 0.236 0.203 85.224 105.994 Unidentified 0.013 0.012 0.009 3.965 107.889 Unidentified 0.133 0.130 0.083 40.617 108.164 Unidentified 0.132 0.129 0.083 40.238 108.245 Unidentified 0.123 0.120 0.077 37.475 108.552 Unidentified 0.302 0.293 0.188 91.811 108.984 Unidentified 0.905 0.746 0.657 275.522 109.703 Unidentified 0.063 0.047 0.046 19.169 110.528 Unidentified 0.031 0.028 0.020 9.567 110.859 Unidentified 0.148 0.145 0.103 45.088 111.132 Unidentified 0.130 0.110 0.085 39.466 111.798 Unidentified 0.074 0.060 0.048 22.449 112.653 Unidentified 0.013 0.011 0.009 4.083 112.784 Unidentified 0.022 0.018 0.016 6.611 113.296 Unidentified 0.036 0.036 0.022 11.096 113.447 Unidentified 0.014 0.014 0.008 4.326 113.654 Unidentified 0.071 0.058 0.047 21.743 114.683 Unidentified 0.031 0.025 0.020 9.474 114.978 Unidentified 0.014 0.011 0.009 4.236 116.972 Unidentified 0.007 0.006 0.004 2.091 126.171 Unidentified 0.009 0.008 0.006 2.827 126.171 Unidentified 0.009 0.008 0.005 2.827 126.171 Unidentified 0.009 0.009 0.005 2.827 127.135 Unidentified 0.003 0.003 0.001 0.914

Plus

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

2,2-Dimethylbutane

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2

2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Methylcyclohexane

2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified

3-Methylheptane

2,2,5-Trimethylhexane

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF95.090.085.080.075.0
i-Propylcyclopentane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane

2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene

p-Xylene Unidentified C9-IsoOlefin-3 Unidentified
2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene

2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane Unidentified

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2

1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane Unidentified i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan C11-Isoparaffin-5

Indene n-ButylCyclohexane Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane Unidentified 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,2,4-Triethylbenzene
2-Methylnaphthalene

1-Methylnaphthalene

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF Sample: ODDB-91309 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91309 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000005.D\SIG1000005_FID1_A.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 6.743 7.618 7.467

I-Paraffins 49.355 52.034 42.026

Aromatics 19.783 16.589 16.677 Mono-Aromatics 18.793 15.822 15.960 Naphthalenes 0.134 0.096 0.093 Naphtheno/Olefino-Benzs 0.206 0.170 0.141 Indenes 0.651 0.501 0.482

Naphthenes 4.785 4.592 4.780 Mono-Naphthenes 4.785 4.592 4.780 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.333 7.945 8.650 n-Olefins 3.109 3.443 3.769 Iso-Olefins 3.589 3.901 4.131 Naphtheno-Olefins 0.609 0.572 0.716 Di-Olefins 0.026 0.028 0.034

Oxygenates 9.533 8.844 18.680

Unidentified 2.468 2.378 1.721

Plus 0.000 0.000 0.000

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 9.432 8.752 18.528 C3 0.107 0.102 0.165 C4 1.351 1.699 2.113 C5 9.206 10.589 11.695 C6 13.831 14.626 14.743 C7 11.550 11.013 10.889 C8 36.105 36.126 28.945 C9 10.410 9.818 7.570 C10 4.474 3.918 3.004 C11 0.924 0.858 0.547 C12 0.143 0.120 0.080

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.006 0.009 0.013 C4 1.108 1.402 1.725 C5 1.166 1.364 1.463 C6 2.728 3.029 2.865 C7 0.689 0.738 0.623 C8 0.546 0.569 0.433 C9 0.427 0.435 0.301 C10 0.040 0.040 0.025 C11 0.032 0.032 0.019

I-Paraffins C4 0.053 0.070 0.083 C5 4.200 4.964 5.268 C6 5.287 5.878 5.552 C7 3.274 3.532 2.957 C8 29.426 30.317 23.314 C9 5.226 5.388 3.688 C10 1.322 1.328 0.837 C11 0.550 0.542 0.319 C12 0.016 0.015 0.008

Mono-Aromatics C6 0.735 0.612 0.852 C7 5.234 4.420 5.141 C8 5.547 4.686 4.728 C9 4.640 3.902 3.494 C10 2.229 1.863 1.503 C11 0.285 0.237 0.174 C12 0.123 0.101 0.069

Naphthalenes C10 0.116 0.083 0.082 C11 0.017 0.012 0.011

Naphtheno/Olefino-Benzs C10 0.206 0.170 0.141

Indenes C9 0.076 0.058 0.058 C10 0.559 0.432 0.414 C11 0.011 0.008 0.007 C12 0.004 0.003 0.003

Mono-Naphthenes C5 0.144 0.141 0.185 C6 2.508 2.414 2.697 C7 1.562 1.500 1.440 C8 0.531 0.502 0.429

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.041 0.035 0.029

n-Olefins C4 0.189 0.227 0.305 C5 1.637 1.847 2.112 C6 1.150 1.231 1.236 C7 0.105 0.110 0.097 C11 0.028 0.028 0.018

Iso-Olefins C5 1.837 2.059 2.370 C6 1.010 1.074 1.086 C7 0.685 0.714 0.632 C8 0.054 0.051 0.042 C10 0.002 0.003 0.002

Naphtheno-Olefins C5 0.197 0.187 0.262 C6 0.412 0.386 0.454

Di-Olefins C5 0.026 0.028 0.034

Oxygenates C2 9.432 8.752 18.528 C3 0.101 0.092 0.152

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 24.50 23.49 5% 81.26 80.63 10% 100.96 97.18 15% 144.13 138.61 20% 155.27 153.92 25% 172.43 160.63 30% 173.01 172.73 35% 177.16 175.13 40% 209.25 197.28 45% 210.21 209.76 50% 228.59 212.40 55% 230.95 230.77 60% 234.81 234.05 65% 236.63 235.98 70% 238.01 237.44 75% 243.86 239.11 80% 258.64 254.81 85% 281.77 279.29 90% 320.83 317.38 95% 352.12 336.85 FBP 402.72 389.41

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.391 74-98-6 P3 Propane 0.006 0.009 0.013 1.698 2 8.613 75-28-5 I4 i-Butane 0.053 0.070 0.083 14.393 3 9.405 115-11-7 K4 Isobutene 0.015 0.019 0.024 4.238 4 9.444 106-98-9 K4 Butene-1 0.018 0.022 0.029 5.067 5 9.793 106-97-8 P4 n-Butane 1.108 1.402 1.725 299.818 6 10.267 624-64-6 K4 t-Butene-2 0.071 0.087 0.115 20.025 7 10.390 463-82-1 I5 2,2-Dimethylpropane 0.013 0.016 0.016 3.416 8 10.989 590-18-1 K4 c-Butene-2 0.085 0.100 0.136 23.705 9 12.753 64-17-5 X2 Ethanol 9.432 8.752 18.528 1136.062 10 13.128 563-45-1 C5 3-Methylbutene-1 0.297 0.346 0.383 83.131

11 14.713 78-78-4 I5 i-Pentane 4.188 4.948 5.253 1140.912 12 16.337 109-67-1 K5 Pentene-1 0.331 0.379 0.428 92.873 13 17.165 563-46-2 C5 2-Methylbutene-1 0.503 0.567 0.650 141.068 14 17.696 109-66-0 P5 n-Pentane 1.166 1.364 1.463 317.807 15 18.208 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.994 16 18.798 646-04-8 K5 t-Pentene-2 0.843 0.952 1.088 236.251 17 19.439 ? Unidentified 0.006 0.006 0.007 1.936 18 19.822 627-20-3 K5 c-Pentene-2 0.462 0.516 0.597 129.552 19 20.490 513-35-9 C5 2-Methylbutene-2 1.037 1.146 1.338 290.485 20 20.818 2004-70-8 E5 1t,3-Pentadiene 0.015 0.016 0.020 4.373

21 22.071 ? Unidentified 0.006 0.006 0.008 2.041 22 22.623 75-83-2 I6 2,2-Dimethylbutane 0.077 0.087 0.081 20.997 23 25.249 142-29-0 B5 Cyclopentene 0.197 0.187 0.262 56.828 24 26.430 ? Unidentified 0.045 0.041 0.068 15.395 25 26.504 71-23-8 X3 n-Propanol 0.101 0.092 0.152 19.798 26 27.099 287-92-3 M5 Cyclopentane 0.144 0.141 0.185 40.242 27 27.833 79-29-8 I6 2,3-Dimethylbutane 1.138 1.259 1.195 311.211 28 28.228 ? Unidentified 0.051 0.050 0.052 17.407 29 28.696 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.048 0.048 12.494 30 28.904 107-83-5 I6 2-Methylpentane 2.321 2.602 2.438 635.007

31 29.339 674-76-0 C6 4-Methyl-t-pentene-2 0.131 0.142 0.141 36.738 32 31.547 96-14-0 I6 3-Methylpentane 1.751 1.930 1.839 478.997 33 32.718 763-29-1 C6 2-Methylpentene-1 0.225 0.240 0.242 63.033 34 32.942 592-41-6 K6 Hexene-1 0.161 0.174 0.174 45.242 35 35.303 110-54-3 P6 n-Hexane 2.728 3.029 2.865 746.276 36 35.942 13269-52-8 K6 t-Hexene-3 0.265 0.284 0.285 74.235 37 36.410 4050-45-7 K6 t-Hexene-2 0.508 0.545 0.546 142.292 38 36.900 625-27-4 C6 2-Methylpentene-2 0.344 0.364 0.370 96.344 39 37.313 922-62-3 C6 3-Methyl-c-pentene-2 0.266 0.279 0.286 74.498 40 38.237 7688-21-3 K6 c-Hexene-2 0.216 0.228 0.232 60.446

41 39.588 3404-73-7 C7 3,3-Dimethylpentene-1 0.315 0.329 0.291 88.376 42 40.162 96-37-7 M6 Methylcyclopentane 1.490 1.457 1.602 417.419 43 41.732 108-08-7 I7 2,4-Dimethylpentane 0.971 1.056 0.877 266.530

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.034 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.013 3.988 45 42.276 464-06-2 I7 2,2,3-Trimethylbutane 0.076 0.080 0.068 20.786 46 44.931 ? Unidentified 0.012 0.011 0.013 4.044 47 45.137 71-42-3 Q6 Benzene 0.735 0.612 0.852 221.834 48 45.336 693-89-0 B6 1-Methylcyclopentene 0.367 0.345 0.405 105.417 49 46.159 3404-61-3 C7 3-Methylhexene-1 0.016 0.016 0.014 4.391 50 46.742 3524-73-0 C7 5-Methylhexene-1 0.065 0.068 0.060 18.261 51 47.057 110-82-7 M6 Cyclohexane 1.018 0.958 1.095 285.348 52 47.596 ? Unidentified 0.035 0.036 0.032 11.890 53 48.805 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.038 11.564

54 49.146 3769-23-1 C7 4-Methylhexene-1 0.010 0.011 0.009 2.855 55 49.797 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.053 0.047 14.405 56 50.197 591-76-4 I7 2-Methylhexane 1.566 1.690 1.414 430.088 57 50.669 110-83-8 B6 Cyclohexene 0.045 0.041 0.050 12.602 58 52.028 589-34-4 I7 3-Methylhexane 0.662 0.706 0.598 181.839 59 52.882 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.170 0.166 0.156 47.503 60 53.470 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.131 0.129 0.121 36.786 61 54.094 822-50-4 M7 1t,2-Dimethylcyclopentane 0.187 0.183 0.173 52.531 62 54.429 C7 C7 - Iso-Olefin - 2 0.022 0.022 0.020 6.183 63 54.738 540-84-1 I8 2,2,4-Trimethylpentane 7.470 7.905 5.918 2055.609

64 55.028 592-76-7 K7 Heptene-1 0.030 0.031 0.028 8.377 65 56.359 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.013 4.021 66 56.880 14686-14-7 K7 t-Heptene-3 0.033 0.035 0.031 9.287 67 57.242 6094-02-6 C7 2-Methylhexene-1 0.059 0.062 0.054 16.551 68 57.617 142-82-5 P7 n-Heptane 0.689 0.738 0.623 189.290 69 57.834 7642-10-6 K7 c-Heptene-3 0.025 0.026 0.023 7.035 70 58.113 2738-19-4 C7 2-Methyl-2-hexene 0.027 0.028 0.025 7.601 71 58.359 3899-36-3 C7 3-Methyl-t-hexene-3 0.021 0.022 0.019 5.773 72 58.742 14686-13-6 K7 t-Heptene-2 0.017 0.018 0.016 4.727 73 59.202 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.017 5.174

74 59.644 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.014 4.294 75 60.429 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.013 3.812 76 61.062 108-87-2 M7 Methylcyclohexane 1.017 0.968 0.937 284.936 77 62.012 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.030 0.030 0.025 8.543 78 62.418 590-73-8 I8 2,2-Dimethylhexane 0.030 0.031 0.023 8.132 79 63.857 1640-89-7 M7 Ethylcyclopentane 0.038 0.037 0.035 10.744 80 64.513 564-02-3 I8 2,2,3-Trimethylpentane 0.749 0.766 0.593 206.023 81 64.760 592-13-2 I8 2,5-Dimethylhexane 1.519 1.604 1.204 418.070 82 65.100 589-43-5 I8 2,4-Dimethylhexane 1.433 1.498 1.135 394.285 83 65.930 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.031 0.030 0.025 8.692

84 66.331 563-16-6 I8 3,3-Dimethylhexane 0.021 0.022 0.017 5.883 85 67.461 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.028 0.026 0.022 7.727 86 68.135 565-75-3 I8 2,3,4-Trimethylpentane 6.895 7.022 5.463 1897.493

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 68.637 108-88-3 Q7 Toluene 5.234 4.420 5.141 1562.352 88 68.821 560-21-4 I8 2,3,3-Trimethylpentane 8.453 8.522 6.697 2326.163 89 70.134 C8 C8 - Diolefin - 1 0.012 0.011 0.010 3.324 90 70.441 584-94-1 I8 2,3-Dimethylhexane 1.889 1.942 1.497 519.797 91 71.701 592-27-8 I8 2-Methylheptane 0.303 0.318 0.240 83.514 92 71.961 589-53-7 I8 4-Methylheptane 0.284 0.295 0.225 78.043 93 72.096 ? Unidentified 0.158 0.161 0.126 54.383 94 72.864 M8 1,3-dimethyl-t-cyclohexane 0.181 0.172 0.146 50.735 95 73.023 589-81-1 I8 3-Methylheptane 0.263 0.273 0.208 72.292 96 73.207 619-99-8 I8 3-Ethylhexane 0.117 0.120 0.093 32.285

97 74.103 ? Unidentified 0.030 0.028 0.024 10.196 98 74.950 3522-94-9 I9 2,2,5-Trimethylhexane 3.735 3.866 2.635 1029.771 99 75.272 M8 3c-Ethylmethylcyclopentane 0.011 0.010 0.009 3.060 100 75.495 M8 3t-Ethylmethylcyclopentane 0.015 0.014 0.012 4.182 101 75.910 ? Unidentified 0.029 0.027 0.023 9.886 102 76.198 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.084 0.079 0.068 23.559 103 77.567 111-65-9 P8 n-Octane 0.546 0.569 0.433 150.328 104 78.509 ? Unidentified 0.094 0.093 0.066 32.143 105 80.057 1069-53-0 I9 2,3,5-Trimethylhexane 0.619 0.628 0.437 170.654 106 80.618 C8 C9 - IsoOlefin - 1 0.019 0.018 0.015 5.247

107 81.055 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.016 0.015 0.013 4.451 108 81.233 1071-26-7 I9 2,4-Dimethylheptane 0.113 0.117 0.080 31.196 109 81.869 1678-91-7 M8 Ethylcyclohexane 0.126 0.118 0.101 35.261 110 82.195 1072-05-5 I9 2,6-Dimethylheptane 0.163 0.168 0.115 44.810 111 82.674 ? Unidentified 0.030 0.032 0.021 10.181 112 83.130 I9 2,5-Dimethylheptane 0.340 0.348 0.240 93.846 113 83.300 926-82-9 I9 3,5-Dimethylheptane 0.034 0.034 0.024 9.290 114 84.440 100-41-4 Q8 Ethylbenzene 0.964 0.814 0.821 285.467 115 84.620 ? Unidentified 0.048 0.048 0.035 16.327 116 84.859 ? Unidentified 0.049 0.046 0.035 16.930

117 85.671 108-38-3 Q8 m-Xylene 2.568 2.175 2.189 760.710 118 85.818 106-42-3 Q8 p-Xylene 1.135 0.965 0.967 336.205 119 85.965 ? Unidentified 0.127 0.128 0.089 43.485 120 86.221 C8 C9-IsoOlefin-3 0.024 0.022 0.017 6.657 121 86.328 ? Unidentified 0.022 0.023 0.016 7.717 122 86.618 1067-20-5 I9 3,3-Diethylpentane 0.004 0.004 0.003 1.197 123 87.015 2216-34-4 I9 4-Methyloctane 0.057 0.058 0.040 15.625 124 87.148 3221-61-2 I9 2-Methyloctane 0.076 0.078 0.054 21.082 125 87.850 15869-80-4 I9 Heptane, 3-ethyl- 0.010 0.010 0.007 2.791 126 88.013 2216-33-3 I9 3-Methyloctane 0.075 0.076 0.053 20.696

127 88.480 ? Unidentified 0.205 0.220 0.147 70.483 128 88.652 95-47-6 Q8 o-Xylene 0.880 0.732 0.750 260.821 129 89.068 I10 C10 - IsoParaffin - 1 0.665 0.669 0.423 183.644

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 89.488 3728-57-2 M8 Cyclopentane, 1-methyl-2-propyl- 0.009 0.008 0.008 2.811 131 89.643 M9 trans-1,3-Diethylcyclopentane 0.022 0.018 0.016 6.570 132 89.915 14720-74-2 I10 2,2,4-trimethylheptane 0.469 0.472 0.298 129.541 133 91.476 111-84-2 P9 n-Nonane 0.427 0.435 0.301 117.650 134 92.053 4926-90-3 M9 1,1-Methylethylcyclohexane 0.016 0.015 0.012 4.528 135 92.837 98-82-8 Q9 i-Propylbenzene 0.032 0.027 0.024 9.385 136 93.028 ? Unidentified 0.008 0.008 0.006 2.747 137 93.028 ? Unidentified 0.008 0.008 0.005 2.747 138 93.028 ? Unidentified 0.008 0.006 0.005 2.747 139 93.139 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.002 0.002 0.002 0.683

140 93.139 C10 C10-IsoOlefin-4 0.002 0.003 0.002 0.683 141 93.139 I10 C10-isoparaffin-x 0.000 0.000 0.000 0.683 142 93.600 ? Unidentified 0.085 0.086 0.054 29.069 143 93.824 15869-87-1 I10 2,2-Dimethyloctane 0.030 0.030 0.019 8.266 144 94.630 15869-89-3 I10 2,5-Dimethyloctane 0.017 0.017 0.011 4.671 145 94.814 I10 C10 - IsoParaffin - 2 0.010 0.010 0.006 2.692 146 95.265 2051-30-1 I10 2,4-Dimethyloctane 0.025 0.026 0.016 7.002 147 95.660 I10 2,6-Dimethyloctane 0.013 0.013 0.008 3.658 148 96.305 103-65-1 Q9 n-Propylbenzene 0.275 0.233 0.207 80.905 149 97.155 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.034 0.876 0.779 304.465

150 97.387 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.479 0.408 0.361 141.098 151 98.015 108-67-8 Q9 1,3,5-Trimethylbenzene 0.606 0.513 0.456 178.294 152 98.682 17301-94-8 I10 4-Methylnonane 0.012 0.012 0.007 3.195 153 98.883 ? Unidentified 0.302 0.304 0.192 103.678 154 99.099 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.354 0.294 0.267 104.266 155 99.661 5911-04-6 I10 3-Methylnonane 0.016 0.016 0.010 4.292 156 100.127 ? Unidentified 0.024 0.018 0.014 8.302 157 100.251 ? Unidentified 0.065 0.064 0.038 22.337 158 100.476 I11 C11-Isoparaffin-2 0.036 0.036 0.021 9.990 159 100.733 95-63-6 Q9 1,2,4-Trimethylbenzene 1.654 1.383 1.246 486.978

160 100.941 ? Unidentified 0.046 0.048 0.029 15.652 161 101.062 ? Unidentified 0.028 0.028 0.018 9.462 162 101.320 98-06-6 Q10 t-Butylbenzene 0.007 0.006 0.005 2.012 163 102.108 17302-01-1 I10 3-Ethyl-3-methylheptane 0.066 0.065 0.038 18.229 164 102.456 538-93-2 Q10 i-Butylbenzene 0.080 0.068 0.054 23.371 165 102.595 124-18-5 P10 n-Decane 0.040 0.040 0.025 10.930 166 102.974 ? Unidentified 0.018 0.018 0.011 6.344 167 103.609 526-73-8 Q9 1,2,3-Trimethylbenzene 0.206 0.168 0.155 60.511 168 103.991 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.009 0.008 0.006 2.681 169 104.190 I11 C11 Isoparaffin-4 0.009 0.009 0.005 2.609

170 104.394 ? Unidentified 0.056 0.048 0.038 19.166 171 104.801 J9 Indan 0.076 0.058 0.058 22.715 172 105.429 J10 Indene 0.386 0.293 0.296 115.521

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 106.147 I11 C11-Isoparaffin-7 0.160 0.157 0.092 44.169 174 106.332 141-93-5 Q10 1,3-Diethylbenzene 0.024 0.020 0.016 6.917 175 106.621 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.499 0.424 0.336 146.108 176 106.922 105-05-5 Q10 1,4-Diethylbenzene 0.186 0.158 0.125 54.488 177 107.173 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.109 0.091 0.074 31.943 178 107.428 135-01-3 Q10 1,2-Diethylbenzene 0.039 0.033 0.026 11.502 179 107.886 ? Unidentified 0.040 0.039 0.023 13.584 180 108.025 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.044 0.037 0.029 12.780 181 108.161 ? Unidentified 0.046 0.046 0.027 15.918 182 108.244 ? Unidentified 0.042 0.041 0.024 14.362

183 108.365 I11 C11- Isoparaffin-11 0.345 0.340 0.200 95.418 184 108.550 ? Unidentified 0.111 0.109 0.064 38.149 185 108.877 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.091 0.076 0.061 26.507 186 108.981 ? Unidentified 0.386 0.322 0.260 132.391 187 109.203 J10 2-Methylindan 0.059 0.044 0.040 17.525 188 109.543 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.258 0.216 0.174 75.621 189 110.101 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.336 0.276 0.227 98.408 190 110.528 ? Unidentified 0.011 0.010 0.007 3.900 191 110.729 693-61-8 K11 2-Undecene, (E)- 0.028 0.028 0.018 7.782 192 110.857 ? Unidentified 0.065 0.064 0.042 22.346

193 111.132 ? Unidentified 0.055 0.047 0.033 18.831 194 111.219 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.063 0.052 0.042 18.375 195 111.531 1120-21-4 P11 n-Undecane 0.032 0.032 0.019 8.875 196 111.687 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.043 0.035 0.026 12.478 197 111.798 ? Unidentified 0.026 0.021 0.016 8.785 198 112.162 Q10 1,2,4,5-Tetramethylbenzene 0.204 0.168 0.137 59.668 199 112.430 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.281 0.231 0.189 82.148 200 112.785 ? Unidentified 0.006 0.005 0.004 2.187 201 112.966 I12 C12 - IsoParaffin - 1 0.010 0.010 0.005 2.763 202 113.293 ? Unidentified 0.019 0.019 0.010 6.538

203 113.445 ? Unidentified 0.007 0.007 0.004 2.291 204 113.584 Q11 C11 - Aromatic - 3 0.025 0.021 0.015 7.283 205 113.652 ? Unidentified 0.021 0.017 0.013 7.134 206 113.762 874-35-1 H10 5-Methylindan 0.091 0.075 0.062 26.545 207 113.902 Q12 1,2-Di-i-propylbenzene 0.034 0.028 0.019 9.786 208 114.117 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.045 0.037 0.028 13.171 209 114.286 Q11 C11 - Aromatic - 4 0.029 0.024 0.018 8.592 210 114.513 824-22-6 J10 4-Methylindan 0.115 0.094 0.078 33.536 211 114.765 824-63-5 H10 2-Methylindan 0.115 0.095 0.079 33.795 212 114.978 ? Unidentified 0.009 0.009 0.005 3.121

213 115.091 538-68-1 Q11 n-Pentylbenzene 0.011 0.009 0.006 3.099 214 115.319 Q11 tert-Pentylbenzene 0.044 0.036 0.027 12.909 215 115.633 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.021 0.017 0.013 6.160

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 115.744 Q11 C11 - Aromatic - 7 0.033 0.029 0.020 9.747 217 116.092 I12 C12 - IsoParaffin - 4 0.006 0.005 0.003 1.644 218 116.205 100-18-5 Q12 1,4-Di-i-propylbenzene 0.041 0.033 0.023 11.816 219 116.634 91-20-3 G10 Naphthalene 0.116 0.083 0.082 35.678 220 116.798 ? Unidentified 0.015 0.015 0.008 5.186 221 116.972 ? Unidentified 0.005 0.004 0.003 1.645 222 117.087 J11 1,1-Dimethyl Indane 0.011 0.008 0.007 3.263 223 117.248 J12 Dimethyl Indane - 1 0.004 0.003 0.003 1.334 224 117.432 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.007 0.006 0.004 2.153 225 117.736 Q12 1,3-Di-n-propylbenzene 0.035 0.029 0.020 10.262

226 117.846 Q11 C11 - Aromatic - 11 0.018 0.016 0.011 5.308 227 118.402 Q11 C11 - Aromatic - 12 0.015 0.013 0.009 4.321 228 122.542 877-44-1 Q12 1,2,4-Triethylbenzene 0.006 0.005 0.004 1.826 229 123.281 91-57-6 G11 2-Methylnaphthalene 0.012 0.008 0.007 3.566 230 124.144 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.004 1.706 231 126.172 ? Unidentified 0.008 0.007 0.004 2.619 232 127.137 ? Unidentified 0.002 0.001 0.001 0.586 233 129.864 ? Unidentified 0.003 0.002 0.002 1.129

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.391 74-98-6 Propane 0.006 0.009 0.013 1.698

9.793 106-97-8 n-Butane 1.108 1.402 1.725 299.818 17.696 109-66-0 n-Pentane 1.166 1.364 1.463 317.807 35.303 110-54-3 n-Hexane 2.728 3.029 2.865 746.276 57.617 142-82-5 n-Heptane 0.689 0.738 0.623 189.290 77.567 111-65-9 n-Octane 0.546 0.569 0.433 150.328 91.476 111-84-2 n-Nonane 0.427 0.435 0.301 117.650 102.595 124-18-5 n-Decane 0.040 0.040 0.025 10.930 111.531 1120-21-4 n-Undecane 0.032 0.032 0.019 8.875

I-Paraffins 8.613 75-28-5 i-Butane 0.053 0.070 0.083 14.393

10.390 463-82-1 2,2-Dimethylpropane 0.013 0.016 0.016 3.416 14.713 78-78-4 i-Pentane 4.188 4.948 5.253 1140.912 22.623 75-83-2 2,2-Dimethylbutane 0.077 0.087 0.081 20.997 27.833 79-29-8 2,3-Dimethylbutane 1.138 1.259 1.195 311.211 28.904 107-83-5 2-Methylpentane 2.321 2.602 2.438 635.007 31.547 96-14-0 3-Methylpentane 1.751 1.930 1.839 478.997 41.732 108-08-7 2,4-Dimethylpentane 0.971 1.056 0.877 266.530 42.276 464-06-2 2,2,3-Trimethylbutane 0.076 0.080 0.068 20.786 50.197 591-76-4 2-Methylhexane 1.566 1.690 1.414 430.088 52.028 589-34-4 3-Methylhexane 0.662 0.706 0.598 181.839 54.738 540-84-1 2,2,4-Trimethylpentane 7.470 7.905 5.918 2055.609 62.418 590-73-8 2,2-Dimethylhexane 0.030 0.031 0.023 8.132 64.513 564-02-3 2,2,3-Trimethylpentane 0.749 0.766 0.593 206.023 64.760 592-13-2 2,5-Dimethylhexane 1.519 1.604 1.204 418.070 65.100 589-43-5 2,4-Dimethylhexane 1.433 1.498 1.135 394.285 66.331 563-16-6 3,3-Dimethylhexane 0.021 0.022 0.017 5.883 68.135 565-75-3 2,3,4-Trimethylpentane 6.895 7.022 5.463 1897.493 68.821 560-21-4 2,3,3-Trimethylpentane 8.453 8.522 6.697 2326.163 70.441 584-94-1 2,3-Dimethylhexane 1.889 1.942 1.497 519.797 71.701 592-27-8 2-Methylheptane 0.303 0.318 0.240 83.514 71.961 589-53-7 4-Methylheptane 0.284 0.295 0.225 78.043 73.023 589-81-1 3-Methylheptane 0.263 0.273 0.208 72.292 73.207 619-99-8 3-Ethylhexane 0.117 0.120 0.093 32.285 74.950 3522-94-9 2,2,5-Trimethylhexane 3.735 3.866 2.635 1029.771 80.057 1069-53-0 2,3,5-Trimethylhexane 0.619 0.628 0.437 170.654 81.233 1071-26-7 2,4-Dimethylheptane 0.113 0.117 0.080 31.196 82.195 1072-05-5 2,6-Dimethylheptane 0.163 0.168 0.115 44.810 83.130 2,5-Dimethylheptane 0.340 0.348 0.240 93.846 83.300 926-82-9 3,5-Dimethylheptane 0.034 0.034 0.024 9.290 86.618 1067-20-5 3,3-Diethylpentane 0.004 0.004 0.003 1.197 87.015 2216-34-4 4-Methyloctane 0.057 0.058 0.040 15.625 87.148 3221-61-2 2-Methyloctane 0.076 0.078 0.054 21.082 87.850 15869-80-4 Heptane, 3-ethyl- 0.010 0.010 0.007 2.791 88.013 2216-33-3 3-Methyloctane 0.075 0.076 0.053 20.696 89.068 C10 - IsoParaffin - 1 0.665 0.669 0.423 183.644 89.915 14720-74-2 2,2,4-trimethylheptane 0.469 0.472 0.298 129.541

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 93.139 C10-isoparaffin-x 0.000 0.000 0.000 0.683

93.824 15869-87-1 2,2-Dimethyloctane 0.030 0.030 0.019 8.266 94.630 15869-89-3 2,5-Dimethyloctane 0.017 0.017 0.011 4.671 94.814 C10 - IsoParaffin - 2 0.010 0.010 0.006 2.692 95.265 2051-30-1 2,4-Dimethyloctane 0.025 0.026 0.016 7.002 95.660 2,6-Dimethyloctane 0.013 0.013 0.008 3.658 98.682 17301-94-8 4-Methylnonane 0.012 0.012 0.007 3.195 99.661 5911-04-6 3-Methylnonane 0.016 0.016 0.010 4.292 100.476 C11-Isoparaffin-2 0.036 0.036 0.021 9.990 102.108 17302-01-1 3-Ethyl-3-methylheptane 0.066 0.065 0.038 18.229 104.190 C11 Isoparaffin-4 0.009 0.009 0.005 2.609 106.147 C11-Isoparaffin-7 0.160 0.157 0.092 44.169 108.365 C11- Isoparaffin-11 0.345 0.340 0.200 95.418 112.966 C12 - IsoParaffin - 1 0.010 0.010 0.005 2.763 116.092 C12 - IsoParaffin - 4 0.006 0.005 0.003 1.644

Aromatics Mono-Aromatics 45.137 71-42-3 Benzene 0.735 0.612 0.852 221.834

68.637 108-88-3 Toluene 5.234 4.420 5.141 1562.352 84.440 100-41-4 Ethylbenzene 0.964 0.814 0.821 285.467 85.671 108-38-3 m-Xylene 2.568 2.175 2.189 760.710 85.818 106-42-3 p-Xylene 1.135 0.965 0.967 336.205 88.652 95-47-6 o-Xylene 0.880 0.732 0.750 260.821 92.837 98-82-8 i-Propylbenzene 0.032 0.027 0.024 9.385 96.305 103-65-1 n-Propylbenzene 0.275 0.233 0.207 80.905 97.155 620-14-4 1-Methyl-3-ethylbenzene 1.034 0.876 0.779 304.465 97.387 622-96-8 1-Methyl-4-ethylbenzene 0.479 0.408 0.361 141.098 98.015 108-67-8 1,3,5-Trimethylbenzene 0.606 0.513 0.456 178.294 99.099 611-14-3 1-Methyl-2-ethylbenzene 0.354 0.294 0.267 104.266 100.733 95-63-6 1,2,4-Trimethylbenzene 1.654 1.383 1.246 486.978 101.320 98-06-6 t-Butylbenzene 0.007 0.006 0.005 2.012 102.456 538-93-2 i-Butylbenzene 0.080 0.068 0.054 23.371 103.609 526-73-8 1,2,3-Trimethylbenzene 0.206 0.168 0.155 60.511 103.991 535-77-3 1-Methyl-3-i-propylbenzene 0.009 0.008 0.006 2.681 106.332 141-93-5 1,3-Diethylbenzene 0.024 0.020 0.016 6.917 106.621 1074-43-7 1-Methyl-3-n-propylbenzene 0.499 0.424 0.336 146.108 106.922 105-05-5 1,4-Diethylbenzene 0.186 0.158 0.125 54.488 107.173 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.109 0.091 0.074 31.943 107.428 135-01-3 1,2-Diethylbenzene 0.039 0.033 0.026 11.502 108.025 1074-17-5 1-Methyl-2-n-propylbenzene 0.044 0.037 0.029 12.780 108.877 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.091 0.076 0.061 26.507 109.543 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.258 0.216 0.174 75.621 110.101 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.336 0.276 0.227 98.408 111.219 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.063 0.052 0.042 18.375 111.687 4218-48-8 1-Ethyl-4-i-propylbenzene 0.043 0.035 0.026 12.478 112.162 1,2,4,5-Tetramethylbenzene 0.204 0.168 0.137 59.668 112.430 527-53-7 1,2,3,5-Tetramethylbenzene 0.281 0.231 0.189 82.148

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 113.584 C11 - Aromatic - 3 0.025 0.021 0.015 7.283

113.902 1,2-Di-i-propylbenzene 0.034 0.028 0.019 9.786 114.117 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.045 0.037 0.028 13.171 114.286 C11 - Aromatic - 4 0.029 0.024 0.018 8.592 115.091 538-68-1 n-Pentylbenzene 0.011 0.009 0.006 3.099 115.319 tert-Pentylbenzene 0.044 0.036 0.027 12.909 115.633 577-55-9 1-Methyl-2-n-butylbenzene 0.021 0.017 0.013 6.160 115.744 C11 - Aromatic - 7 0.033 0.029 0.020 9.747 116.205 100-18-5 1,4-Di-i-propylbenzene 0.041 0.033 0.023 11.816 117.432 7364-19-4 1t-Butyl-4-ethylbenzene 0.007 0.006 0.004 2.153 117.736 1,3-Di-n-propylbenzene 0.035 0.029 0.020 10.262 117.846 C11 - Aromatic - 11 0.018 0.016 0.011 5.308 118.402 C11 - Aromatic - 12 0.015 0.013 0.009 4.321 122.542 877-44-1 1,2,4-Triethylbenzene 0.006 0.005 0.004 1.826

Naphthalenes 116.634 91-20-3 Naphthalene 0.116 0.083 0.082 35.678

123.281 91-57-6 2-Methylnaphthalene 0.012 0.008 0.007 3.566 124.144 90-12-0 1-Methylnaphthalene 0.006 0.004 0.004 1.706

Naphtheno/Olefino-Benzs

113.762 874-35-1 5-Methylindan 0.091 0.075 0.062 26.545 114.765 824-63-5 2-Methylindan 0.115 0.095 0.079 33.795

Indenes 104.801 Indan 0.076 0.058 0.058 22.715

105.429 Indene 0.386 0.293 0.296 115.521 109.203 2-Methylindan 0.059 0.044 0.040 17.525 114.513 824-22-6 4-Methylindan 0.115 0.094 0.078 33.536 117.087 1,1-Dimethyl Indane 0.011 0.008 0.007 3.263 117.248 Dimethyl Indane - 1 0.004 0.003 0.003 1.334

Naphthenes Mono-Naphthenes 27.099 287-92-3 Cyclopentane 0.144 0.141 0.185 40.242

40.162 96-37-7 Methylcyclopentane 1.490 1.457 1.602 417.419 47.057 110-82-7 Cyclohexane 1.018 0.958 1.095 285.348 52.882 1759-58-6 1t,3-Dimethylcyclopentane 0.170 0.166 0.156 47.503 53.470 2532-58-3 1c,3-Dimethylcyclopentane 0.131 0.129 0.121 36.786 54.094 822-50-4 1t,2-Dimethylcyclopentane 0.187 0.183 0.173 52.531 59.202 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.017 5.174 61.062 108-87-2 Methylcyclohexane 1.017 0.968 0.937 284.936 62.012 4516-69-2 1,1,3-Trimethylcyclopentane 0.030 0.030 0.025 8.543 63.857 1640-89-7 Ethylcyclopentane 0.038 0.037 0.035 10.744 65.930 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.031 0.030 0.025 8.692 67.461 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.028 0.026 0.022 7.727 72.864 1,3-dimethyl-t-cyclohexane 0.181 0.172 0.146 50.735 75.272 3c-Ethylmethylcyclopentane 0.011 0.010 0.009 3.060 75.495 3t-Ethylmethylcyclopentane 0.015 0.014 0.012 4.182 76.198 2207-03-6 1t,3-Dimethylcyclohexane 0.084 0.079 0.068 23.559 81.055 2207-01-4 1c,2-Dimethylcyclohexane 0.016 0.015 0.013 4.451

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 81.869 1678-91-7 Ethylcyclohexane 0.126 0.118 0.101 35.261

89.488 3728-57-2 Cyclopentane, 1-methyl-2-propyl- 0.009 0.008 0.008 2.811 89.643 trans-1,3-Diethylcyclopentane 0.022 0.018 0.016 6.570 92.053 4926-90-3 1,1-Methylethylcyclohexane 0.016 0.015 0.012 4.528 93.139 696-29-7 1-Methyl-2-propyl-cyclopentan 0.002 0.002 0.002 0.683

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.405 115-11-7 Isobutene 0.015 0.019 0.024 4.238

9.444 106-98-9 Butene-1 0.018 0.022 0.029 5.067 10.267 624-64-6 t-Butene-2 0.071 0.087 0.115 20.025 10.989 590-18-1 c-Butene-2 0.085 0.100 0.136 23.705 16.337 109-67-1 Pentene-1 0.331 0.379 0.428 92.873 18.798 646-04-8 t-Pentene-2 0.843 0.952 1.088 236.251 19.822 627-20-3 c-Pentene-2 0.462 0.516 0.597 129.552 32.942 592-41-6 Hexene-1 0.161 0.174 0.174 45.242 35.942 13269-52-8 t-Hexene-3 0.265 0.284 0.285 74.235 36.410 4050-45-7 t-Hexene-2 0.508 0.545 0.546 142.292 38.237 7688-21-3 c-Hexene-2 0.216 0.228 0.232 60.446 55.028 592-76-7 Heptene-1 0.030 0.031 0.028 8.377 56.880 14686-14-7 t-Heptene-3 0.033 0.035 0.031 9.287 57.834 7642-10-6 c-Heptene-3 0.025 0.026 0.023 7.035 58.742 14686-13-6 t-Heptene-2 0.017 0.018 0.016 4.727 110.729 693-61-8 2-Undecene, (E)- 0.028 0.028 0.018 7.782

Iso-Olefins 13.128 563-45-1 3-Methylbutene-1 0.297 0.346 0.383 83.131

17.165 563-46-2 2-Methylbutene-1 0.503 0.567 0.650 141.068 20.490 513-35-9 2-Methylbutene-2 1.037 1.146 1.338 290.485 28.696 691-38-3 4-Methyl-c-pentene-2 0.045 0.048 0.048 12.494 29.339 674-76-0 4-Methyl-t-pentene-2 0.131 0.142 0.141 36.738 32.718 763-29-1 2-Methylpentene-1 0.225 0.240 0.242 63.033 36.900 625-27-4 2-Methylpentene-2 0.344 0.364 0.370 96.344 37.313 922-62-3 3-Methyl-c-pentene-2 0.266 0.279 0.286 74.498 39.588 3404-73-7 3,3-Dimethylpentene-1 0.315 0.329 0.291 88.376 42.034 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.013 3.988 46.159 3404-61-3 3-Methylhexene-1 0.016 0.016 0.014 4.391 46.742 3524-73-0 5-Methylhexene-1 0.065 0.068 0.060 18.261 48.805 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.038 11.564 49.146 3769-23-1 4-Methylhexene-1 0.010 0.011 0.009 2.855 49.797 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.053 0.047 14.405 54.429 C7 - Iso-Olefin - 2 0.022 0.022 0.020 6.183 56.359 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.013 4.021 57.242 6094-02-6 2-Methylhexene-1 0.059 0.062 0.054 16.551 58.113 2738-19-4 2-Methyl-2-hexene 0.027 0.028 0.025 7.601 58.359 3899-36-3 3-Methyl-t-hexene-3 0.021 0.022 0.019 5.773 59.644 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.014 4.294 60.429 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.013 3.812

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 70.134 C8 - Diolefin - 1 0.012 0.011 0.010 3.324

80.618 C9 - IsoOlefin - 1 0.019 0.018 0.015 5.247 86.221 C9-IsoOlefin-3 0.024 0.022 0.017 6.657 93.139 C10-IsoOlefin-4 0.002 0.003 0.002 0.683

Naphtheno-Olefins 25.249 142-29-0 Cyclopentene 0.197 0.187 0.262 56.828

45.336 693-89-0 1-Methylcyclopentene 0.367 0.345 0.405 105.417 50.669 110-83-8 Cyclohexene 0.045 0.041 0.050 12.602

Di-Olefins 18.208 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.994

20.818 2004-70-8 1t,3-Pentadiene 0.015 0.016 0.020 4.373

Oxygenates 12.753 64-17-5 Ethanol 9.432 8.752 18.528 1136.062

26.504 71-23-8 n-Propanol 0.101 0.092 0.152 19.798

Unidentified 19.439 Unidentified 0.006 0.006 0.007 1.936

22.071 Unidentified 0.006 0.006 0.008 2.041 26.430 Unidentified 0.045 0.041 0.068 15.395 28.228 Unidentified 0.051 0.050 0.052 17.407 44.931 Unidentified 0.012 0.011 0.013 4.044 47.596 Unidentified 0.035 0.036 0.032 11.890 72.096 Unidentified 0.158 0.161 0.126 54.383 74.103 Unidentified 0.030 0.028 0.024 10.196 75.910 Unidentified 0.029 0.027 0.023 9.886 78.509 Unidentified 0.094 0.093 0.066 32.143 82.674 Unidentified 0.030 0.032 0.021 10.181 84.620 Unidentified 0.048 0.048 0.035 16.327 84.859 Unidentified 0.049 0.046 0.035 16.930 85.965 Unidentified 0.127 0.128 0.089 43.485 86.328 Unidentified 0.022 0.023 0.016 7.717 88.480 Unidentified 0.205 0.220 0.147 70.483 93.028 Unidentified 0.008 0.008 0.006 2.747 93.028 Unidentified 0.008 0.008 0.005 2.747 93.028 Unidentified 0.008 0.006 0.005 2.747 93.600 Unidentified 0.085 0.086 0.054 29.069 98.883 Unidentified 0.302 0.304 0.192 103.678 100.127 Unidentified 0.024 0.018 0.014 8.302 100.251 Unidentified 0.065 0.064 0.038 22.337 100.941 Unidentified 0.046 0.048 0.029 15.652 101.062 Unidentified 0.028 0.028 0.018 9.462 102.974 Unidentified 0.018 0.018 0.011 6.344 104.394 Unidentified 0.056 0.048 0.038 19.166 107.886 Unidentified 0.040 0.039 0.023 13.584 108.161 Unidentified 0.046 0.046 0.027 15.918 108.244 Unidentified 0.042 0.041 0.024 14.362 108.550 Unidentified 0.111 0.109 0.064 38.149 108.981 Unidentified 0.386 0.322 0.260 132.391

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 110.528 Unidentified 0.011 0.010 0.007 3.900

110.857 Unidentified 0.065 0.064 0.042 22.346 111.132 Unidentified 0.055 0.047 0.033 18.831 111.798 Unidentified 0.026 0.021 0.016 8.785 112.785 Unidentified 0.006 0.005 0.004 2.187 113.293 Unidentified 0.019 0.019 0.010 6.538 113.445 Unidentified 0.007 0.007 0.004 2.291 113.652 Unidentified 0.021 0.017 0.013 7.134 114.978 Unidentified 0.009 0.009 0.005 3.121 116.798 Unidentified 0.015 0.015 0.008 5.186 116.972 Unidentified 0.005 0.004 0.003 1.645 126.172 Unidentified 0.008 0.007 0.004 2.619 127.137 Unidentified 0.002 0.001 0.001 0.586 129.864 Unidentified 0.003 0.002 0.002 1.129

Plus

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1

n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

Unidentified n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane Unidentified

2-Methyl-c-hexene-3 4-Methylhexene-1 4-Methyl-t/c-hexene-2

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1

n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane

2,2,3-Trimethylpentane

2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

2,2,5-Trimethylhexane

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF95.090.085.080.075.0 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 Cyclopentane, 1-methyl-2-propyl- trans-1,3-Diethylcyclopentane

2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane C10 - IsoParaffin - 2 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified t-Butylbenzene
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,2,4-Triethylbenzene
2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF Sample: ODDB-91310 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91310 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000006.D\SIG1000006_FID1_A.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

Unidentified

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 9.854 11.721 12.377

I-Paraffins 38.721 41.264 32.458

Aromatics 25.136 21.112 20.180 Mono-Aromatics 22.924 19.407 18.567 Naphthalenes 0.105 0.076 0.071 Naphtheno/Olefino-Benzs 0.193 0.160 0.129 Indenes 1.914 1.470 1.413

Naphthenes 4.846 4.672 4.675 Mono-Naphthenes 4.846 4.672 4.675 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.429 8.119 8.663 n-Olefins 3.237 3.613 3.872 Iso-Olefins 3.602 3.945 4.106 Naphtheno-Olefins 0.567 0.536 0.655 Di-Olefins 0.023 0.025 0.030

Oxygenates 8.958 8.358 17.155

Unidentified 5.056 4.753 4.493

Plus 0.000 0.000 0.000

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 8.768 8.183 16.875 C3 0.195 0.182 0.290 C4 5.051 6.413 7.719 C5 11.049 12.809 13.729 C6 11.305 11.968 11.831 C7 11.105 10.482 10.304 C8 23.761 23.570 18.782 C9 10.111 9.257 7.281 C10 11.008 9.907 7.214 C11 2.415 2.326 1.388 C12 0.175 0.149 0.095

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.005 0.008 0.010 C4 4.744 6.035 7.236 C5 1.905 2.240 2.340 C6 1.171 1.307 1.204 C7 0.760 0.818 0.672 C8 0.638 0.669 0.495 C9 0.442 0.454 0.306 C10 0.089 0.090 0.055 C11 0.101 0.100 0.058

I-Paraffins C4 0.056 0.074 0.085 C5 5.085 6.044 6.248 C6 4.654 5.209 4.788 C7 2.411 2.614 2.133 C8 16.842 17.497 13.072 C9 3.393 3.516 2.346 C10 4.411 4.459 2.726 C11 1.841 1.822 1.044 C12 0.029 0.029 0.015

Mono-Aromatics C6 0.687 0.576 0.780 C7 5.623 4.776 5.411 C8 5.611 4.768 4.686 C9 5.995 5.065 4.422 C10 4.492 3.794 2.967 C11 0.370 0.309 0.221 C12 0.146 0.120 0.080

Naphthalenes C10 0.085 0.061 0.059 C11 0.020 0.014 0.012

Naphtheno/Olefino-Benzs C10 0.193 0.160 0.129

Indenes C9 0.213 0.163 0.160 C10 1.689 1.298 1.245 C11 0.011 0.009 0.007

Mono-Naphthenes C5 0.209 0.206 0.264 C6 2.115 2.051 2.228 C7 1.791 1.726 1.617 C8 0.619 0.588 0.490 C9 0.067 0.059 0.047

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.044 0.041 0.028

n-Olefins C4 0.252 0.304 0.398 C5 1.719 1.951 2.173 C6 1.178 1.269 1.241 C7 0.017 0.017 0.015 C11 0.072 0.071 0.045

Iso-Olefins C5 1.916 2.158 2.422 C6 1.127 1.205 1.187 C7 0.504 0.529 0.455 C8 0.051 0.048 0.039 C10 0.005 0.006 0.003

Naphtheno-Olefins C5 0.193 0.184 0.251 C6 0.374 0.352 0.404

Di-Olefins C5 0.023 0.025 0.030

Oxygenates C2 8.768 8.183 16.875 C3 0.190 0.175 0.280

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.52 21.28 5% 34.82 29.07 10% 81.64 80.44 15% 100.27 95.01 20% 142.42 134.41 25% 157.91 145.71 30% 172.65 165.52 35% 173.26 172.82 40% 205.78 176.93 45% 210.40 209.37 50% 230.77 212.26 55% 233.70 230.87 60% 237.08 235.12 65% 245.27 238.10 70% 277.00 254.85 75% 291.73 281.32 80% 324.57 319.97 85% 334.95 332.28 90% 355.84 352.22 95% 363.20 363.20 FBP 402.00 389.03

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.391 74-98-6 P3 Propane 0.005 0.008 0.010 1.346 2 8.613 75-28-5 I4 i-Butane 0.056 0.074 0.085 14.694 3 9.406 115-11-7 K4 Isobutene 0.022 0.027 0.035 6.070 4 9.445 106-98-9 K4 Butene-1 0.026 0.032 0.041 7.066 5 9.794 106-97-8 P4 n-Butane 4.744 6.035 7.236 1251.766 6 10.268 624-64-6 K4 t-Butene-2 0.095 0.116 0.151 26.095 7 10.390 463-82-1 I5 2,2-Dimethylpropane 0.021 0.027 0.026 5.672 8 10.988 590-18-1 K4 c-Butene-2 0.108 0.128 0.171 29.537 9 12.745 64-17-5 X2 Ethanol 8.768 8.183 16.875 1029.989 10 13.130 563-45-1 C5 3-Methylbutene-1 0.268 0.314 0.338 73.137

11 14.713 78-78-4 I5 i-Pentane 5.063 6.018 6.222 1345.320 12 16.335 109-67-1 K5 Pentene-1 0.345 0.396 0.436 94.186 13 17.175 563-46-2 C5 2-Methylbutene-1 0.538 0.609 0.680 146.981 14 17.700 109-66-0 P5 n-Pentane 1.905 2.240 2.340 506.058 15 18.213 78-79-5 E5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.617 16 18.804 646-04-8 K5 t-Pentene-2 0.888 1.009 1.123 242.815 17 19.447 ? Unidentified 0.006 0.007 0.008 2.076 18 19.824 627-20-3 K5 c-Pentene-2 0.486 0.546 0.614 132.821 19 20.489 513-35-9 C5 2-Methylbutene-2 1.110 1.235 1.404 303.484 20 20.818 2004-70-8 E5 1t,3-Pentadiene 0.014 0.015 0.018 3.910

21 22.067 ? Unidentified 0.005 0.005 0.007 1.634 22 22.614 75-83-2 I6 2,2-Dimethylbutane 0.133 0.151 0.137 35.394 23 25.253 142-29-0 B5 Cyclopentene 0.193 0.184 0.251 54.271 24 26.487 71-23-8 X3 n-Propanol 0.190 0.175 0.280 36.331 25 27.103 287-92-3 M5 Cyclopentane 0.209 0.206 0.264 57.120 26 27.831 79-29-8 I6 2,3-Dimethylbutane 0.899 1.000 0.925 239.759 27 28.238 ? Unidentified 0.055 0.054 0.055 18.264 28 28.695 691-38-3 C6 4-Methyl-c-pentene-2 0.047 0.051 0.050 12.848 29 28.908 107-83-5 I6 2-Methylpentane 2.257 2.544 2.322 601.975 30 29.345 674-76-0 C6 4-Methyl-t-pentene-2 0.140 0.153 0.147 38.214

31 31.551 96-14-0 I6 3-Methylpentane 1.366 1.514 1.405 364.340 32 32.718 763-29-1 C6 2-Methylpentene-1 0.238 0.256 0.251 65.016 33 32.940 592-41-6 K6 Hexene-1 0.170 0.185 0.179 46.445 34 35.140 760-21-4 C6 2-Ethylbutene-1 0.065 0.069 0.068 17.712 35 35.291 110-54-3 P6 n-Hexane 1.171 1.307 1.204 312.270 36 35.938 13269-52-8 K6 t-Hexene-3 0.272 0.294 0.287 74.454 37 36.409 4050-45-7 K6 t-Hexene-2 0.516 0.556 0.543 140.949 38 36.902 625-27-4 C6 2-Methylpentene-2 0.361 0.385 0.380 98.710 39 37.312 922-62-3 C6 3-Methyl-c-pentene-2 0.276 0.291 0.291 75.389 40 38.243 7688-21-3 K6 c-Hexene-2 0.219 0.234 0.231 59.980

41 39.588 3404-73-7 C7 3,3-Dimethylpentene-1 0.329 0.345 0.297 89.806 42 40.157 96-37-7 M6 Methylcyclopentane 1.337 1.315 1.409 365.410 43 41.731 108-08-7 I7 2,4-Dimethylpentane 0.654 0.716 0.579 175.234

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.037 594-56-9 C7 2,3,3-Trimethylbutene-1 0.011 0.012 0.010 3.132 45 42.276 464-06-2 I7 2,2,3-Trimethylbutane 0.046 0.050 0.041 12.446 46 44.935 ? Unidentified 0.011 0.011 0.012 3.586 47 45.136 71-42-3 Q6 Benzene 0.687 0.576 0.780 202.176 48 45.339 693-89-0 B6 1-Methylcyclopentene 0.338 0.319 0.365 94.630 49 46.162 3404-61-3 C7 3-Methylhexene-1 0.013 0.014 0.012 3.496 50 46.743 3524-73-0 C7 5-Methylhexene-1 0.051 0.054 0.046 13.935 51 47.054 110-82-7 M6 Cyclohexane 0.778 0.736 0.820 212.680 52 47.596 ? Unidentified 0.029 0.031 0.027 9.827 53 48.805 15840-60-5 C7 2-Methyl-c-hexene-3 0.032 0.034 0.029 8.671

54 49.801 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.037 0.039 0.033 10.097 55 50.197 591-76-4 I7 2-Methylhexane 1.172 1.272 1.037 314.015 56 50.667 110-83-8 B6 Cyclohexene 0.036 0.033 0.039 9.790 57 52.029 589-34-4 I7 3-Methylhexane 0.538 0.576 0.476 144.014 58 52.883 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.152 0.150 0.137 41.597 59 53.470 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.123 0.122 0.111 33.728 60 54.092 822-50-4 M7 1t,2-Dimethylcyclopentane 0.175 0.171 0.158 47.766 61 54.718 540-84-1 I8 2,2,4-Trimethylpentane 4.891 5.206 3.796 1312.640 62 56.882 14686-14-7 K7 t-Heptene-3 0.017 0.017 0.015 4.552 63 57.236 6094-02-6 C7 2-Methylhexene-1 0.026 0.027 0.023 7.021

64 57.617 142-82-5 P7 n-Heptane 0.760 0.818 0.672 203.464 65 58.116 2738-19-4 C7 2-Methyl-2-hexene 0.006 0.006 0.005 1.526 66 61.064 108-87-2 M7 Methylcyclohexane 1.295 1.239 1.169 353.928 67 62.014 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.035 0.034 0.028 9.553 68 62.418 590-73-8 I8 2,2-Dimethylhexane 0.036 0.038 0.028 9.606 69 63.856 1640-89-7 M7 Ethylcyclopentane 0.046 0.044 0.041 12.458 70 64.509 ? Unidentified 0.342 0.351 0.265 114.352 71 64.754 592-13-2 I8 2,5-Dimethylhexane 0.972 1.032 0.754 260.745 72 65.093 589-43-5 I8 2,4-Dimethylhexane 0.929 0.977 0.721 249.300 73 65.927 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.035 0.034 0.028 9.573

74 66.330 563-16-6 I8 3,3-Dimethylhexane 0.026 0.027 0.020 7.040 75 67.458 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.031 0.030 0.025 8.500 76 68.105 565-75-3 I8 2,3,4-Trimethylpentane 3.717 3.807 2.885 997.618 77 68.630 108-88-3 Q7 Toluene 5.623 4.776 5.411 1637.091 78 68.784 560-21-4 I8 2,3,3-Trimethylpentane 4.272 4.332 3.316 1146.564 79 70.129 C8 C8 - Diolefin - 1 0.013 0.013 0.011 3.664 80 70.433 584-94-1 I8 2,3-Dimethylhexane 1.073 1.110 0.833 288.011 81 71.700 592-27-8 I8 2-Methylheptane 0.311 0.328 0.241 83.489 82 71.958 589-53-7 I8 4-Methylheptane 0.211 0.220 0.163 56.522 83 72.096 ? Unidentified 0.089 0.091 0.069 29.749

84 72.863 M8 1,3-dimethyl-t-cyclohexane 0.214 0.205 0.169 58.547 85 73.022 589-81-1 I8 3-Methylheptane 0.268 0.280 0.208 71.971 86 73.207 619-99-8 I8 3-Ethylhexane 0.136 0.140 0.105 36.402

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 74.103 ? Unidentified 0.035 0.033 0.028 11.764 88 74.937 3522-94-9 I9 2,2,5-Trimethylhexane 2.255 2.348 1.559 606.420 89 75.271 M8 3c-Ethylmethylcyclopentane 0.013 0.013 0.010 3.614 90 75.492 M8 3t-Ethylmethylcyclopentane 0.017 0.016 0.013 4.643 91 75.909 ? Unidentified 0.016 0.016 0.011 5.465 92 76.194 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.098 0.093 0.078 26.881 93 77.567 111-65-9 P8 n-Octane 0.638 0.669 0.495 171.241 94 78.510 ? Unidentified 0.055 0.055 0.038 18.377 95 80.056 1069-53-0 I9 2,3,5-Trimethylhexane 0.363 0.370 0.251 97.612 96 80.617 C8 C9 - IsoOlefin - 1 0.022 0.021 0.017 6.013

97 81.052 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.018 0.017 0.014 4.961 98 81.233 1071-26-7 I9 2,4-Dimethylheptane 0.079 0.082 0.055 21.296 99 81.868 1678-91-7 M8 Ethylcyclohexane 0.147 0.138 0.116 40.204 100 82.194 1072-05-5 I9 2,6-Dimethylheptane 0.130 0.135 0.090 34.825 101 82.673 ? Unidentified 0.031 0.034 0.022 10.468 102 83.127 I9 2,5-Dimethylheptane 0.239 0.246 0.165 64.315 103 83.307 926-82-9 I9 3,5-Dimethylheptane 0.031 0.031 0.021 8.270 104 84.440 100-41-4 Q8 Ethylbenzene 1.019 0.866 0.851 294.532 105 84.619 ? Unidentified 0.031 0.031 0.022 10.355 106 84.860 ? Unidentified 0.040 0.038 0.028 13.495

107 85.670 108-38-3 Q8 m-Xylene 2.559 2.180 2.137 739.243 108 85.817 106-42-3 Q8 p-Xylene 1.136 0.972 0.949 328.278 109 85.964 ? Unidentified 0.080 0.081 0.055 26.710 110 86.220 C8 C9-IsoOlefin-3 0.015 0.015 0.011 4.218 111 86.328 ? Unidentified 0.014 0.015 0.010 4.796 112 86.459 I9 3,5-Dimethylheptane 0.012 0.012 0.008 3.133 113 86.618 1067-20-5 I9 3,3-Diethylpentane 0.010 0.010 0.007 2.796 114 87.015 2216-34-4 I9 4-Methyloctane 0.070 0.072 0.048 18.808 115 87.148 3221-61-2 I9 2-Methyloctane 0.096 0.099 0.066 25.681 116 87.850 15869-80-4 I9 Heptane, 3-ethyl- 0.013 0.013 0.009 3.572

117 88.013 2216-33-3 I9 3-Methyloctane 0.096 0.098 0.066 25.793 118 88.480 ? Unidentified 0.113 0.121 0.079 37.683 119 88.651 95-47-6 Q8 o-Xylene 0.896 0.750 0.749 258.967 120 89.067 I10 C10 - IsoParaffin - 1 0.394 0.399 0.246 106.186 121 89.488 3728-57-2 M8 Cyclopentane, 1-methyl-2-propyl- 0.010 0.008 0.008 2.921 122 89.642 M9 trans-1,3-Diethylcyclopentane 0.032 0.027 0.023 9.326 123 89.914 14720-74-2 I10 2,2,4-trimethylheptane 0.295 0.298 0.184 79.366 124 91.493 111-84-2 P9 n-Nonane 0.442 0.454 0.306 118.845 125 92.061 4926-90-3 M9 1,1-Methylethylcyclohexane 0.030 0.027 0.021 8.171 126 92.838 98-82-8 Q9 i-Propylbenzene 0.040 0.034 0.029 11.459

127 93.029 ? Unidentified 0.012 0.011 0.008 4.049 128 93.029 ? Unidentified 0.012 0.013 0.008 4.049 129 93.029 ? Unidentified 0.012 0.009 0.008 4.049

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 93.140 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.005 0.005 0.004 1.444 131 93.140 C10 C10-IsoOlefin-4 0.005 0.006 0.003 1.444 132 93.140 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.444 133 93.601 ? Unidentified 0.162 0.165 0.101 54.403 134 93.824 15869-87-1 I10 2,2-Dimethyloctane 0.058 0.059 0.036 15.626 135 94.269 ? Unidentified 0.014 0.010 1.245 4.701 136 94.269 ? Unidentified 0.014 0.015 0.009 4.701 137 94.625 15869-89-3 I10 2,5-Dimethyloctane 0.085 0.086 0.053 22.890 138 94.812 I10 C10 - IsoParaffin - 2 0.020 0.021 0.013 5.502 139 95.103 2040-95-1 I10 2,7-Dimethyloctane 0.043 0.044 0.027 11.709

140 95.267 2051-30-1 I10 2,4-Dimethyloctane 0.184 0.186 0.115 49.587 141 95.661 I10 2,6-Dimethyloctane 0.064 0.064 0.040 17.222 142 95.821 ? Unidentified 0.004 0.004 0.003 1.448 143 96.306 103-65-1 Q9 n-Propylbenzene 0.311 0.266 0.230 89.331 144 96.516 I10 3-Methyl-5-ethylheptane 0.009 0.009 0.006 2.421 145 97.156 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.147 0.977 0.846 329.185 146 97.389 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.543 0.464 0.401 155.889 147 98.016 108-67-8 Q9 1,3,5-Trimethylbenzene 0.789 0.672 0.582 226.584 148 98.499 15869-85-9 I10 5-Methylnonane 0.009 0.009 0.006 2.467 149 98.688 17301-94-8 I10 4-Methylnonane 0.022 0.022 0.014 5.870

150 98.900 I10 2,2,6-Trimethyloctane 2.806 2.845 1.749 756.161 151 99.100 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.438 0.366 0.323 125.598 152 99.472 ? Unidentified 0.008 0.008 0.005 2.614 153 99.664 5911-04-6 I10 3-Methylnonane 0.024 0.024 0.015 6.488 154 99.839 ? Unidentified 0.009 0.010 0.006 3.124 155 100.130 ? Unidentified 0.167 0.123 0.095 55.868 156 100.257 ? Unidentified 0.452 0.448 0.257 151.398 157 100.480 I11 C11-Isoparaffin-2 0.240 0.238 0.136 64.734 158 100.742 95-63-6 Q9 1,2,4-Trimethylbenzene 2.319 1.950 1.711 665.683 159 100.946 ? Unidentified 0.280 0.294 0.177 93.692

160 101.066 ? Unidentified 0.166 0.166 0.103 55.483 161 101.322 1678-98-4 M10 i-Butylcyclohexane 0.041 0.038 0.026 11.340 162 101.966 ? Unidentified 0.016 0.014 0.010 5.257 163 102.112 17302-01-1 I10 3-Ethyl-3-methylheptane 0.397 0.393 0.225 107.049 164 102.326 ? Unidentified 0.112 0.096 0.074 37.372 165 102.466 538-93-2 Q10 i-Butylbenzene 0.288 0.249 0.190 82.288 166 102.657 124-18-5 P10 n-Decane 0.089 0.090 0.055 23.965 167 102.975 ? Unidentified 0.104 0.103 0.059 34.809 168 103.468 ? Unidentified 0.012 0.010 0.009 4.150 169 103.614 526-73-8 Q9 1,2,3-Trimethylbenzene 0.408 0.336 0.301 117.257

170 103.981 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.035 0.030 0.023 10.133 171 104.193 I11 C11 Isoparaffin-4 0.048 0.047 0.027 12.916 172 104.395 ? Unidentified 0.247 0.212 0.163 82.822

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 104.803 J9 Indan 0.213 0.163 0.160 62.286 174 105.058 I11 C11-Isoparaffin-5 0.026 0.026 0.015 7.047 175 105.439 J10 Indene 1.415 1.081 1.062 412.963 176 105.852 M10 n-ButylCyclohexane 0.002 0.002 0.001 0.648 177 105.994 ? Unidentified 0.012 0.011 0.007 3.888 178 106.154 I11 C11-Isoparaffin-7 0.541 0.535 0.307 145.841 179 106.333 141-93-5 Q10 1,3-Diethylbenzene 0.054 0.046 0.036 15.373 180 106.634 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.591 1.361 1.051 454.260 181 106.906 105-05-5 Q10 1,4-Diethylbenzene 0.436 0.372 0.288 124.455 182 107.175 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.132 0.111 0.088 37.824

183 107.422 135-01-3 Q10 1,2-Diethylbenzene 0.120 0.100 0.079 34.250 184 107.889 ? Unidentified 0.130 0.128 0.074 43.447 185 108.027 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.053 0.045 0.035 15.261 186 108.164 ? Unidentified 0.132 0.132 0.076 44.311 187 108.245 ? Unidentified 0.119 0.118 0.068 39.904 188 108.369 I11 C11- Isoparaffin-11 0.986 0.976 0.559 265.970 189 108.552 ? Unidentified 0.314 0.311 0.178 105.123 190 108.983 ? Unidentified 0.913 0.766 0.603 305.601 191 109.206 J10 2-Methylindan 0.151 0.115 0.101 43.973 192 109.543 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.345 0.291 0.228 98.647

193 109.703 ? Unidentified 0.064 0.049 0.043 21.367 194 110.102 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.807 0.667 0.533 230.373 195 110.527 ? Unidentified 0.033 0.030 0.019 11.146 196 110.729 693-61-8 K11 2-Undecene, (E)- 0.072 0.071 0.045 19.459 197 110.857 ? Unidentified 0.156 0.155 0.099 52.275 198 111.131 ? Unidentified 0.136 0.118 0.081 45.609 199 111.212 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.072 0.059 0.048 20.555 200 111.530 1120-21-4 P11 n-Undecane 0.101 0.100 0.058 27.357 201 111.687 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.111 0.091 0.066 31.440 202 111.799 ? Unidentified 0.077 0.063 0.046 25.634

203 112.163 Q10 1,2,4,5-Tetramethylbenzene 0.241 0.200 0.159 68.841 204 112.429 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.317 0.262 0.209 90.442 205 112.653 ? Unidentified 0.014 0.012 0.009 4.778 206 112.784 ? Unidentified 0.021 0.017 0.014 7.016 207 112.965 I12 C12 - IsoParaffin - 1 0.029 0.029 0.015 7.834 208 113.293 ? Unidentified 0.034 0.035 0.019 11.521 209 113.447 ? Unidentified 0.013 0.013 0.007 4.355 210 113.653 ? Unidentified 0.062 0.051 0.037 20.761 211 113.760 874-35-1 H10 5-Methylindan 0.096 0.080 0.065 27.500 212 113.901 Q12 1,2-Di-i-propylbenzene 0.042 0.035 0.023 11.963

213 114.117 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.058 0.048 0.035 16.420 214 114.287 Q11 C11 - Aromatic - 4 0.036 0.029 0.021 10.117 215 114.513 824-22-6 J10 4-Methylindan 0.123 0.102 0.082 35.082

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 114.681 ? Unidentified 0.028 0.023 0.017 9.459 217 114.764 824-63-5 H10 2-Methylindan 0.097 0.080 0.065 27.579 218 114.977 ? Unidentified 0.012 0.010 0.007 4.058 219 115.090 538-68-1 Q11 n-Pentylbenzene 0.014 0.012 0.009 4.079 220 115.320 Q11 tert-Pentylbenzene 0.054 0.045 0.032 15.323 221 115.631 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.026 0.022 0.016 7.514 222 115.743 Q11 C11 - Aromatic - 7 0.040 0.035 0.024 11.474 223 116.205 100-18-5 Q12 1,4-Di-i-propylbenzene 0.054 0.045 0.030 15.365 224 116.633 91-20-3 G10 Naphthalene 0.085 0.061 0.059 25.418 225 116.797 ? Unidentified 0.012 0.009 0.007 3.973

226 116.973 ? Unidentified 0.005 0.004 0.003 1.612 227 117.078 J11 1,1-Dimethyl Indane 0.011 0.009 0.007 3.339 228 117.430 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.015 0.012 0.008 4.243 229 117.734 Q12 1,3-Di-n-propylbenzene 0.034 0.028 0.019 9.672 230 117.846 Q11 C11 - Aromatic - 11 0.019 0.016 0.011 5.275 231 118.401 Q11 C11 - Aromatic - 12 0.012 0.011 0.007 3.481 232 123.280 91-57-6 G11 2-Methylnaphthalene 0.013 0.010 0.008 3.963 233 124.146 90-12-0 G11 1-Methylnaphthalene 0.007 0.005 0.004 1.992 234 126.170 ? Unidentified 0.005 0.004 0.002 1.621 235 126.170 ? Unidentified 0.005 0.005 0.002 1.621

236 129.861 ? Unidentified 0.003 0.002 0.002 1.025

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.391 74-98-6 Propane 0.005 0.008 0.010 1.346

9.794 106-97-8 n-Butane 4.744 6.035 7.236 1251.766 17.700 109-66-0 n-Pentane 1.905 2.240 2.340 506.058 35.291 110-54-3 n-Hexane 1.171 1.307 1.204 312.270 57.617 142-82-5 n-Heptane 0.760 0.818 0.672 203.464 77.567 111-65-9 n-Octane 0.638 0.669 0.495 171.241 91.493 111-84-2 n-Nonane 0.442 0.454 0.306 118.845 102.657 124-18-5 n-Decane 0.089 0.090 0.055 23.965 111.530 1120-21-4 n-Undecane 0.101 0.100 0.058 27.357

I-Paraffins 8.613 75-28-5 i-Butane 0.056 0.074 0.085 14.694

10.390 463-82-1 2,2-Dimethylpropane 0.021 0.027 0.026 5.672 14.713 78-78-4 i-Pentane 5.063 6.018 6.222 1345.320 22.614 75-83-2 2,2-Dimethylbutane 0.133 0.151 0.137 35.394 27.831 79-29-8 2,3-Dimethylbutane 0.899 1.000 0.925 239.759 28.908 107-83-5 2-Methylpentane 2.257 2.544 2.322 601.975 31.551 96-14-0 3-Methylpentane 1.366 1.514 1.405 364.340 41.731 108-08-7 2,4-Dimethylpentane 0.654 0.716 0.579 175.234 42.276 464-06-2 2,2,3-Trimethylbutane 0.046 0.050 0.041 12.446 50.197 591-76-4 2-Methylhexane 1.172 1.272 1.037 314.015 52.029 589-34-4 3-Methylhexane 0.538 0.576 0.476 144.014 54.718 540-84-1 2,2,4-Trimethylpentane 4.891 5.206 3.796 1312.640 62.418 590-73-8 2,2-Dimethylhexane 0.036 0.038 0.028 9.606 64.754 592-13-2 2,5-Dimethylhexane 0.972 1.032 0.754 260.745 65.093 589-43-5 2,4-Dimethylhexane 0.929 0.977 0.721 249.300 66.330 563-16-6 3,3-Dimethylhexane 0.026 0.027 0.020 7.040 68.105 565-75-3 2,3,4-Trimethylpentane 3.717 3.807 2.885 997.618 68.784 560-21-4 2,3,3-Trimethylpentane 4.272 4.332 3.316 1146.564 70.433 584-94-1 2,3-Dimethylhexane 1.073 1.110 0.833 288.011 71.700 592-27-8 2-Methylheptane 0.311 0.328 0.241 83.489 71.958 589-53-7 4-Methylheptane 0.211 0.220 0.163 56.522 73.022 589-81-1 3-Methylheptane 0.268 0.280 0.208 71.971 73.207 619-99-8 3-Ethylhexane 0.136 0.140 0.105 36.402 74.937 3522-94-9 2,2,5-Trimethylhexane 2.255 2.348 1.559 606.420 80.056 1069-53-0 2,3,5-Trimethylhexane 0.363 0.370 0.251 97.612 81.233 1071-26-7 2,4-Dimethylheptane 0.079 0.082 0.055 21.296 82.194 1072-05-5 2,6-Dimethylheptane 0.130 0.135 0.090 34.825 83.127 2,5-Dimethylheptane 0.239 0.246 0.165 64.315 83.307 926-82-9 3,5-Dimethylheptane 0.031 0.031 0.021 8.270 86.459 3,5-Dimethylheptane 0.012 0.012 0.008 3.133 86.618 1067-20-5 3,3-Diethylpentane 0.010 0.010 0.007 2.796 87.015 2216-34-4 4-Methyloctane 0.070 0.072 0.048 18.808 87.148 3221-61-2 2-Methyloctane 0.096 0.099 0.066 25.681 87.850 15869-80-4 Heptane, 3-ethyl- 0.013 0.013 0.009 3.572 88.013 2216-33-3 3-Methyloctane 0.096 0.098 0.066 25.793 89.067 C10 - IsoParaffin - 1 0.394 0.399 0.246 106.186 89.914 14720-74-2 2,2,4-trimethylheptane 0.295 0.298 0.184 79.366

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 93.140 C10-isoparaffin-x 0.000 0.000 0.000 1.444

93.824 15869-87-1 2,2-Dimethyloctane 0.058 0.059 0.036 15.626 94.625 15869-89-3 2,5-Dimethyloctane 0.085 0.086 0.053 22.890 94.812 C10 - IsoParaffin - 2 0.020 0.021 0.013 5.502 95.103 2040-95-1 2,7-Dimethyloctane 0.043 0.044 0.027 11.709 95.267 2051-30-1 2,4-Dimethyloctane 0.184 0.186 0.115 49.587 95.661 2,6-Dimethyloctane 0.064 0.064 0.040 17.222 96.516 3-Methyl-5-ethylheptane 0.009 0.009 0.006 2.421 98.499 15869-85-9 5-Methylnonane 0.009 0.009 0.006 2.467 98.688 17301-94-8 4-Methylnonane 0.022 0.022 0.014 5.870 98.900 2,2,6-Trimethyloctane 2.806 2.845 1.749 756.161 99.664 5911-04-6 3-Methylnonane 0.024 0.024 0.015 6.488 100.480 C11-Isoparaffin-2 0.240 0.238 0.136 64.734 102.112 17302-01-1 3-Ethyl-3-methylheptane 0.397 0.393 0.225 107.049 104.193 C11 Isoparaffin-4 0.048 0.047 0.027 12.916 105.058 C11-Isoparaffin-5 0.026 0.026 0.015 7.047 106.154 C11-Isoparaffin-7 0.541 0.535 0.307 145.841 108.369 C11- Isoparaffin-11 0.986 0.976 0.559 265.970 112.965 C12 - IsoParaffin - 1 0.029 0.029 0.015 7.834

Aromatics Mono-Aromatics 45.136 71-42-3 Benzene 0.687 0.576 0.780 202.176

68.630 108-88-3 Toluene 5.623 4.776 5.411 1637.091 84.440 100-41-4 Ethylbenzene 1.019 0.866 0.851 294.532 85.670 108-38-3 m-Xylene 2.559 2.180 2.137 739.243 85.817 106-42-3 p-Xylene 1.136 0.972 0.949 328.278 88.651 95-47-6 o-Xylene 0.896 0.750 0.749 258.967 92.838 98-82-8 i-Propylbenzene 0.040 0.034 0.029 11.459 96.306 103-65-1 n-Propylbenzene 0.311 0.266 0.230 89.331 97.156 620-14-4 1-Methyl-3-ethylbenzene 1.147 0.977 0.846 329.185 97.389 622-96-8 1-Methyl-4-ethylbenzene 0.543 0.464 0.401 155.889 98.016 108-67-8 1,3,5-Trimethylbenzene 0.789 0.672 0.582 226.584 99.100 611-14-3 1-Methyl-2-ethylbenzene 0.438 0.366 0.323 125.598 100.742 95-63-6 1,2,4-Trimethylbenzene 2.319 1.950 1.711 665.683 102.466 538-93-2 i-Butylbenzene 0.288 0.249 0.190 82.288 103.614 526-73-8 1,2,3-Trimethylbenzene 0.408 0.336 0.301 117.257 103.981 535-77-3 1-Methyl-3-i-propylbenzene 0.035 0.030 0.023 10.133 106.333 141-93-5 1,3-Diethylbenzene 0.054 0.046 0.036 15.373 106.634 1074-43-7 1-Methyl-3-n-propylbenzene 1.591 1.361 1.051 454.260 106.906 105-05-5 1,4-Diethylbenzene 0.436 0.372 0.288 124.455 107.175 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.132 0.111 0.088 37.824 107.422 135-01-3 1,2-Diethylbenzene 0.120 0.100 0.079 34.250 108.027 1074-17-5 1-Methyl-2-n-propylbenzene 0.053 0.045 0.035 15.261 109.543 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.345 0.291 0.228 98.647 110.102 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.807 0.667 0.533 230.373 111.212 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.072 0.059 0.048 20.555 111.687 4218-48-8 1-Ethyl-4-i-propylbenzene 0.111 0.091 0.066 31.440

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 112.163 1,2,4,5-Tetramethylbenzene 0.241 0.200 0.159 68.841

112.429 527-53-7 1,2,3,5-Tetramethylbenzene 0.317 0.262 0.209 90.442 113.901 1,2-Di-i-propylbenzene 0.042 0.035 0.023 11.963 114.117 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.058 0.048 0.035 16.420 114.287 C11 - Aromatic - 4 0.036 0.029 0.021 10.117 115.090 538-68-1 n-Pentylbenzene 0.014 0.012 0.009 4.079 115.320 tert-Pentylbenzene 0.054 0.045 0.032 15.323 115.631 577-55-9 1-Methyl-2-n-butylbenzene 0.026 0.022 0.016 7.514 115.743 C11 - Aromatic - 7 0.040 0.035 0.024 11.474 116.205 100-18-5 1,4-Di-i-propylbenzene 0.054 0.045 0.030 15.365 117.430 7364-19-4 1t-Butyl-4-ethylbenzene 0.015 0.012 0.008 4.243 117.734 1,3-Di-n-propylbenzene 0.034 0.028 0.019 9.672 117.846 C11 - Aromatic - 11 0.019 0.016 0.011 5.275 118.401 C11 - Aromatic - 12 0.012 0.011 0.007 3.481

Naphthalenes 116.633 91-20-3 Naphthalene 0.085 0.061 0.059 25.418

123.280 91-57-6 2-Methylnaphthalene 0.013 0.010 0.008 3.963 124.146 90-12-0 1-Methylnaphthalene 0.007 0.005 0.004 1.992

Naphtheno/Olefino-Benzs

113.760 874-35-1 5-Methylindan 0.096 0.080 0.065 27.500 114.764 824-63-5 2-Methylindan 0.097 0.080 0.065 27.579

Indenes 104.803 Indan 0.213 0.163 0.160 62.286

105.439 Indene 1.415 1.081 1.062 412.963 109.206 2-Methylindan 0.151 0.115 0.101 43.973 114.513 824-22-6 4-Methylindan 0.123 0.102 0.082 35.082 117.078 1,1-Dimethyl Indane 0.011 0.009 0.007 3.339

Naphthenes Mono-Naphthenes 27.103 287-92-3 Cyclopentane 0.209 0.206 0.264 57.120

40.157 96-37-7 Methylcyclopentane 1.337 1.315 1.409 365.410 47.054 110-82-7 Cyclohexane 0.778 0.736 0.820 212.680 52.883 1759-58-6 1t,3-Dimethylcyclopentane 0.152 0.150 0.137 41.597 53.470 2532-58-3 1c,3-Dimethylcyclopentane 0.123 0.122 0.111 33.728 54.092 822-50-4 1t,2-Dimethylcyclopentane 0.175 0.171 0.158 47.766 61.064 108-87-2 Methylcyclohexane 1.295 1.239 1.169 353.928 62.014 4516-69-2 1,1,3-Trimethylcyclopentane 0.035 0.034 0.028 9.553 63.856 1640-89-7 Ethylcyclopentane 0.046 0.044 0.041 12.458 65.927 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.035 0.034 0.028 9.573 67.458 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.031 0.030 0.025 8.500 72.863 1,3-dimethyl-t-cyclohexane 0.214 0.205 0.169 58.547 75.271 3c-Ethylmethylcyclopentane 0.013 0.013 0.010 3.614 75.492 3t-Ethylmethylcyclopentane 0.017 0.016 0.013 4.643 76.194 2207-03-6 1t,3-Dimethylcyclohexane 0.098 0.093 0.078 26.881 81.052 2207-01-4 1c,2-Dimethylcyclohexane 0.018 0.017 0.014 4.961 81.868 1678-91-7 Ethylcyclohexane 0.147 0.138 0.116 40.204 89.488 3728-57-2 Cyclopentane, 1-methyl-2-propyl- 0.010 0.008 0.008 2.921

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 89.642 trans-1,3-Diethylcyclopentane 0.032 0.027 0.023 9.326

92.061 4926-90-3 1,1-Methylethylcyclohexane 0.030 0.027 0.021 8.171 93.140 696-29-7 1-Methyl-2-propyl-cyclopentan 0.005 0.005 0.004 1.444 101.322 1678-98-4 i-Butylcyclohexane 0.041 0.038 0.026 11.340 105.852 n-ButylCyclohexane 0.002 0.002 0.001 0.648

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.406 115-11-7 Isobutene 0.022 0.027 0.035 6.070

9.445 106-98-9 Butene-1 0.026 0.032 0.041 7.066 10.268 624-64-6 t-Butene-2 0.095 0.116 0.151 26.095 10.988 590-18-1 c-Butene-2 0.108 0.128 0.171 29.537 16.335 109-67-1 Pentene-1 0.345 0.396 0.436 94.186 18.804 646-04-8 t-Pentene-2 0.888 1.009 1.123 242.815 19.824 627-20-3 c-Pentene-2 0.486 0.546 0.614 132.821 32.940 592-41-6 Hexene-1 0.170 0.185 0.179 46.445 35.938 13269-52-8 t-Hexene-3 0.272 0.294 0.287 74.454 36.409 4050-45-7 t-Hexene-2 0.516 0.556 0.543 140.949 38.243 7688-21-3 c-Hexene-2 0.219 0.234 0.231 59.980 56.882 14686-14-7 t-Heptene-3 0.017 0.017 0.015 4.552 110.729 693-61-8 2-Undecene, (E)- 0.072 0.071 0.045 19.459

Iso-Olefins 13.130 563-45-1 3-Methylbutene-1 0.268 0.314 0.338 73.137

17.175 563-46-2 2-Methylbutene-1 0.538 0.609 0.680 146.981 20.489 513-35-9 2-Methylbutene-2 1.110 1.235 1.404 303.484 28.695 691-38-3 4-Methyl-c-pentene-2 0.047 0.051 0.050 12.848 29.345 674-76-0 4-Methyl-t-pentene-2 0.140 0.153 0.147 38.214 32.718 763-29-1 2-Methylpentene-1 0.238 0.256 0.251 65.016 35.140 760-21-4 2-Ethylbutene-1 0.065 0.069 0.068 17.712 36.902 625-27-4 2-Methylpentene-2 0.361 0.385 0.380 98.710 37.312 922-62-3 3-Methyl-c-pentene-2 0.276 0.291 0.291 75.389 39.588 3404-73-7 3,3-Dimethylpentene-1 0.329 0.345 0.297 89.806 42.037 594-56-9 2,3,3-Trimethylbutene-1 0.011 0.012 0.010 3.132 46.162 3404-61-3 3-Methylhexene-1 0.013 0.014 0.012 3.496 46.743 3524-73-0 5-Methylhexene-1 0.051 0.054 0.046 13.935 48.805 15840-60-5 2-Methyl-c-hexene-3 0.032 0.034 0.029 8.671 49.801 3404-55-5 4-Methyl-t/c-hexene-2 0.037 0.039 0.033 10.097 57.236 6094-02-6 2-Methylhexene-1 0.026 0.027 0.023 7.021 58.116 2738-19-4 2-Methyl-2-hexene 0.006 0.006 0.005 1.526 70.129 C8 - Diolefin - 1 0.013 0.013 0.011 3.664 80.617 C9 - IsoOlefin - 1 0.022 0.021 0.017 6.013 86.220 C9-IsoOlefin-3 0.015 0.015 0.011 4.218 93.140 C10-IsoOlefin-4 0.005 0.006 0.003 1.444

Naphtheno-Olefins 25.253 142-29-0 Cyclopentene 0.193 0.184 0.251 54.271

45.339 693-89-0 1-Methylcyclopentene 0.338 0.319 0.365 94.630 50.667 110-83-8 Cyclohexene 0.036 0.033 0.039 9.790

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphtheno-Olefins Di-Olefins 18.213 78-79-5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.617

20.818 2004-70-8 1t,3-Pentadiene 0.014 0.015 0.018 3.910

Oxygenates 12.745 64-17-5 Ethanol 8.768 8.183 16.875 1029.989

26.487 71-23-8 n-Propanol 0.190 0.175 0.280 36.331

Unidentified 19.447 Unidentified 0.006 0.007 0.008 2.076

22.067 Unidentified 0.005 0.005 0.007 1.634 28.238 Unidentified 0.055 0.054 0.055 18.264 44.935 Unidentified 0.011 0.011 0.012 3.586 47.596 Unidentified 0.029 0.031 0.027 9.827 64.509 Unidentified 0.342 0.351 0.265 114.352 72.096 Unidentified 0.089 0.091 0.069 29.749 74.103 Unidentified 0.035 0.033 0.028 11.764 75.909 Unidentified 0.016 0.016 0.011 5.465 78.510 Unidentified 0.055 0.055 0.038 18.377 82.673 Unidentified 0.031 0.034 0.022 10.468 84.619 Unidentified 0.031 0.031 0.022 10.355 84.860 Unidentified 0.040 0.038 0.028 13.495 85.964 Unidentified 0.080 0.081 0.055 26.710 86.328 Unidentified 0.014 0.015 0.010 4.796 88.480 Unidentified 0.113 0.121 0.079 37.683 93.029 Unidentified 0.012 0.011 0.008 4.049 93.029 Unidentified 0.012 0.013 0.008 4.049 93.029 Unidentified 0.012 0.009 0.008 4.049 93.601 Unidentified 0.162 0.165 0.101 54.403 94.269 Unidentified 0.014 0.010 1.245 4.701 94.269 Unidentified 0.014 0.015 0.009 4.701 95.821 Unidentified 0.004 0.004 0.003 1.448 99.472 Unidentified 0.008 0.008 0.005 2.614 99.839 Unidentified 0.009 0.010 0.006 3.124 100.130 Unidentified 0.167 0.123 0.095 55.868 100.257 Unidentified 0.452 0.448 0.257 151.398 100.946 Unidentified 0.280 0.294 0.177 93.692 101.066 Unidentified 0.166 0.166 0.103 55.483 101.966 Unidentified 0.016 0.014 0.010 5.257 102.326 Unidentified 0.112 0.096 0.074 37.372 102.975 Unidentified 0.104 0.103 0.059 34.809 103.468 Unidentified 0.012 0.010 0.009 4.150 104.395 Unidentified 0.247 0.212 0.163 82.822 105.994 Unidentified 0.012 0.011 0.007 3.888 107.889 Unidentified 0.130 0.128 0.074 43.447 108.164 Unidentified 0.132 0.132 0.076 44.311 108.245 Unidentified 0.119 0.118 0.068 39.904 108.552 Unidentified 0.314 0.311 0.178 105.123 108.983 Unidentified 0.913 0.766 0.603 305.601

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 109.703 Unidentified 0.064 0.049 0.043 21.367

110.527 Unidentified 0.033 0.030 0.019 11.146 110.857 Unidentified 0.156 0.155 0.099 52.275 111.131 Unidentified 0.136 0.118 0.081 45.609 111.799 Unidentified 0.077 0.063 0.046 25.634 112.653 Unidentified 0.014 0.012 0.009 4.778 112.784 Unidentified 0.021 0.017 0.014 7.016 113.293 Unidentified 0.034 0.035 0.019 11.521 113.447 Unidentified 0.013 0.013 0.007 4.355 113.653 Unidentified 0.062 0.051 0.037 20.761 114.681 Unidentified 0.028 0.023 0.017 9.459 114.977 Unidentified 0.012 0.010 0.007 4.058 116.797 Unidentified 0.012 0.009 0.007 3.973 116.973 Unidentified 0.005 0.004 0.003 1.612 126.170 Unidentified 0.005 0.004 0.002 1.621 126.170 Unidentified 0.005 0.005 0.002 1.621 129.861 Unidentified 0.003 0.002 0.002 1.025

Plus

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane
Unidentified 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane Toluene

2,3,3-Trimethylpentane

C8 - Diolefin - 1

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified
2,2,5-Trimethylhexane

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF95.090.085.080.075.0 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene

p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified

o-Xylene C10 - IsoParaffin - 1 Cyclopentane, 1-methyl-2-propyl- trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane C10 - IsoParaffin - 2 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane Unidentified n-Propylbenzene 3-Methyl-5-ethylheptane

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane Unidentified

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified

Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane Unidentified i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan C11-Isoparaffin-5 Indene n-ButylCyclohexane Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified

C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF Sample: ODDB-91311 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91311 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000007.D\SIG1000007_FID1_A.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 8.729 10.455 11.199

I-Paraffins 33.099 36.336 31.006

Aromatics 43.990 38.260 41.128 Mono-Aromatics 42.927 37.407 40.310 Naphthalenes 0.132 0.097 0.098 Naphtheno/Olefino-Benzs 0.250 0.212 0.182 Indenes 0.681 0.544 0.538

Naphthenes 5.522 5.473 5.806 Mono-Naphthenes 5.522 5.473 5.806 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.928 7.736 8.677 n-Olefins 3.019 3.458 3.906 Iso-Olefins 3.285 3.670 3.988 Naphtheno-Olefins 0.599 0.582 0.748 Di-Olefins 0.025 0.027 0.035

Oxygenates 0.112 0.106 0.179

Unidentified 1.621 1.634 2.005

Plus 0.000 0.000 0.000

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.119 0.116 0.194 C4 2.824 3.680 4.683 C5 11.839 14.117 15.927 C6 11.198 12.147 12.709 C7 22.973 21.095 23.557 C8 31.822 30.516 27.856 C9 10.326 9.865 8.026 C10 6.387 6.004 4.486 C11 0.744 0.701 0.469 C12 0.146 0.124 0.086

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.007 0.011 0.016 C4 2.583 3.375 4.273 C5 2.607 3.148 3.474 C6 1.508 1.729 1.682 C7 0.876 0.969 0.840 C8 0.638 0.687 0.537 C9 0.443 0.467 0.332 C10 0.057 0.059 0.038 C11 0.011 0.011 0.007

I-Paraffins C4 0.054 0.074 0.090 C5 5.567 6.796 7.419 C6 4.142 4.765 4.621 C7 1.860 2.066 1.785 C8 13.873 14.639 11.678 C9 4.209 4.480 3.155 C10 3.000 3.116 2.016 C11 0.394 0.400 0.242

Mono-Aromatics C6 0.624 0.537 0.768 C7 17.346 15.130 18.100 C8 16.602 14.498 15.035 C9 5.502 4.776 4.401 C10 2.395 2.072 1.716 C11 0.313 0.270 0.203 C12 0.146 0.124 0.086

Naphthalenes C10 0.118 0.087 0.088 C11 0.014 0.011 0.010

Naphtheno/Olefino-Benzs C10 0.250 0.212 0.182

Indenes C9 0.122 0.096 0.099 C10 0.547 0.438 0.431 C11 0.012 0.009 0.008

Mono-Naphthenes C5 0.264 0.268 0.362 C6 2.399 2.387 2.741 C7 2.135 2.116 2.091 C8 0.653 0.637 0.560 C9 0.050 0.045 0.038 C10 0.021 0.020 0.014

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes n-Olefins C4 0.187 0.232 0.320 C5 1.604 1.869 2.198 C6 1.129 1.249 1.289 C7 0.100 0.108 0.098

Iso-Olefins C5 1.581 1.819 2.167 C6 0.991 1.089 1.132 C7 0.656 0.707 0.643 C8 0.057 0.055 0.047

Naphtheno-Olefins C5 0.193 0.189 0.272 C6 0.406 0.393 0.476

Di-Olefins C5 0.025 0.027 0.035

Oxygenates C3 0.112 0.106 0.179

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 22.30 21.82 5% 79.91 79.30 10% 94.11 81.69 15% 121.32 97.04 20% 152.92 138.74 25% 173.34 154.30 30% 208.90 176.97 35% 230.74 210.59 40% 230.84 230.75 45% 230.95 230.87 50% 231.05 230.99 55% 235.77 234.29 60% 238.24 236.99 65% 254.66 241.30 70% 276.24 256.22 75% 280.98 279.06 80% 281.89 281.55 85% 291.84 291.59 90% 324.07 321.56 95% 347.21 336.34 FBP 404.50 401.19

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.390 74-98-6 P3 Propane 0.007 0.011 0.016 1.931 2 8.612 75-28-5 I4 i-Butane 0.054 0.074 0.090 14.889 3 9.405 115-11-7 K4 Isobutene 0.015 0.019 0.025 4.205 4 9.444 106-98-9 K4 Butene-1 0.018 0.023 0.031 5.095 5 9.793 106-97-8 P4 n-Butane 2.583 3.375 4.273 706.418 6 10.268 624-64-6 K4 t-Butene-2 0.071 0.088 0.121 19.989 7 10.390 463-82-1 I5 2,2-Dimethylpropane 0.020 0.026 0.027 5.496 8 10.988 590-18-1 K4 c-Butene-2 0.083 0.102 0.143 23.628 9 13.131 563-45-1 C5 3-Methylbutene-1 0.067 0.081 0.092 19.045 10 14.714 78-78-4 I5 i-Pentane 5.547 6.771 7.392 1527.638

11 16.337 109-67-1 K5 Pentene-1 0.325 0.384 0.446 92.164 12 17.169 563-46-2 C5 2-Methylbutene-1 0.495 0.576 0.679 140.224 13 17.696 109-66-0 P5 n-Pentane 2.607 3.148 3.474 717.875 14 18.207 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.901 15 18.804 646-04-8 K5 t-Pentene-2 0.826 0.964 1.133 234.031 16 19.444 ? Unidentified 0.006 0.007 0.008 1.945 17 19.828 627-20-3 K5 c-Pentene-2 0.452 0.521 0.620 128.015 18 20.489 513-35-9 C5 2-Methylbutene-2 1.018 1.163 1.396 288.432 19 20.825 2004-70-8 E5 1t,3-Pentadiene 0.015 0.016 0.021 4.266 20 22.077 ? Unidentified 0.006 0.006 0.008 1.965

21 22.618 75-83-2 I6 2,2-Dimethylbutane 0.173 0.202 0.193 47.941 22 25.252 142-29-0 B5 Cyclopentene 0.193 0.189 0.272 56.283 23 26.420 ? Unidentified 0.037 0.035 0.059 12.823 24 26.492 71-23-8 X3 n-Propanol 0.112 0.106 0.179 22.154 25 27.105 287-92-3 M5 Cyclopentane 0.264 0.268 0.362 74.721 26 27.837 79-29-8 I6 2,3-Dimethylbutane 0.464 0.530 0.517 128.182 27 28.231 ? Unidentified 0.051 0.052 0.055 17.571 28 28.690 691-38-3 C6 4-Methyl-c-pentene-2 0.043 0.048 0.049 12.156 29 28.909 107-83-5 I6 2-Methylpentane 2.182 2.527 2.435 603.375 30 29.343 674-76-0 C6 4-Methyl-t-pentene-2 0.129 0.145 0.147 36.488

31 31.551 96-14-0 I6 3-Methylpentane 1.323 1.506 1.476 365.693 32 32.728 763-29-1 C6 2-Methylpentene-1 0.222 0.245 0.253 62.795 33 32.942 592-41-6 K6 Hexene-1 0.159 0.178 0.182 45.116 34 35.297 110-54-3 P6 n-Hexane 1.508 1.729 1.682 416.829 35 35.940 13269-52-8 K6 t-Hexene-3 0.260 0.288 0.297 73.558 36 36.412 4050-45-7 K6 t-Hexene-2 0.498 0.551 0.569 141.009 37 36.908 625-27-4 C6 2-Methylpentene-2 0.337 0.369 0.385 95.505 38 37.313 922-62-3 C6 3-Methyl-c-pentene-2 0.260 0.282 0.297 73.741 39 38.244 7688-21-3 K6 c-Hexene-2 0.212 0.232 0.242 60.014 40 39.591 3404-73-7 C7 3,3-Dimethylpentene-1 0.309 0.333 0.303 87.618

41 40.161 96-37-7 M6 Methylcyclopentane 1.457 1.472 1.664 412.630 42 41.741 108-08-7 I7 2,4-Dimethylpentane 0.224 0.252 0.215 62.201 43 42.042 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.014 3.992

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.279 464-06-2 I7 2,2,3-Trimethylbutane 0.025 0.027 0.024 6.945 45 44.937 ? Unidentified 0.012 0.012 0.014 4.097 46 45.140 71-42-3 Q6 Benzene 0.624 0.537 0.768 190.375 47 45.344 693-89-0 B6 1-Methylcyclopentene 0.362 0.351 0.424 105.055 48 46.164 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.015 4.435 49 46.748 3524-73-0 C7 5-Methylhexene-1 0.057 0.062 0.056 16.240 50 47.060 110-82-7 M6 Cyclohexane 0.942 0.915 1.076 266.886 51 47.596 ? Unidentified 0.034 0.037 0.034 11.948 52 48.806 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.044 0.039 11.419 53 49.800 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.055 0.050 14.377

54 50.196 591-76-4 I7 2-Methylhexane 0.978 1.089 0.938 271.379 55 50.674 110-83-8 B6 Cyclohexene 0.044 0.041 0.052 12.514 56 52.032 589-34-4 I7 3-Methylhexane 0.633 0.697 0.608 175.756 57 52.885 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.203 0.205 0.199 57.537 58 53.474 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.163 0.165 0.159 46.110 59 54.094 822-50-4 M7 1t,2-Dimethylcyclopentane 0.241 0.243 0.236 68.257 60 54.398 C7 C7 - Iso-Olefin - 2 0.022 0.023 0.022 6.324 61 54.684 540-84-1 I8 2,2,4-Trimethylpentane 0.250 0.273 0.211 69.577 62 55.028 592-76-7 K7 Heptene-1 0.030 0.032 0.029 8.363 63 56.362 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.014 4.003

64 56.884 14686-14-7 K7 t-Heptene-3 0.032 0.035 0.032 9.165 65 57.246 6094-02-6 C7 2-Methylhexene-1 0.058 0.063 0.056 16.332 66 57.622 142-82-5 P7 n-Heptane 0.876 0.969 0.840 243.113 67 57.837 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.023 6.742 68 58.117 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.026 7.433 69 58.361 3899-36-3 C7 3-Methyl-t-hexene-3 0.020 0.022 0.019 5.618 70 58.745 14686-13-6 K7 t-Heptene-2 0.015 0.016 0.014 4.121 71 59.206 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.018 5.091 72 59.648 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.015 4.321 73 60.432 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.013 3.802

74 61.069 108-87-2 M7 Methylcyclohexane 1.455 1.430 1.425 412.203 75 62.015 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.041 0.041 0.035 11.584 76 62.423 590-73-8 I8 2,2-Dimethylhexane 0.033 0.036 0.028 9.183 77 63.861 1640-89-7 M7 Ethylcyclopentane 0.055 0.055 0.054 15.678 78 64.513 564-02-3 I8 2,2,3-Trimethylpentane 0.422 0.446 0.355 117.429 79 64.757 592-13-2 I8 2,5-Dimethylhexane 0.781 0.852 0.657 217.244 80 65.096 589-43-5 I8 2,4-Dimethylhexane 0.702 0.758 0.591 195.293 81 65.930 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.040 0.040 0.034 11.390 82 66.335 563-16-6 I8 3,3-Dimethylhexane 0.025 0.027 0.021 7.092 83 67.464 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.035 0.035 0.030 9.996

84 68.129 565-75-3 I8 2,3,4-Trimethylpentane 4.456 4.687 3.751 1239.462 85 68.718 108-88-3 Q7 Toluene 17.346 15.130 18.100 5233.747 86 68.837 560-21-4 I8 2,3,3-Trimethylpentane 4.966 5.172 4.180 1381.299

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 70.138 C8 C8 - Diolefin - 1 0.015 0.015 0.013 4.307 88 70.439 584-94-1 I8 2,3-Dimethylhexane 1.244 1.321 1.047 346.086 89 71.704 592-27-8 I8 2-Methylheptane 0.330 0.357 0.277 91.676 90 71.963 589-53-7 I8 4-Methylheptane 0.240 0.258 0.202 66.823 91 72.099 ? Unidentified 0.110 0.115 0.092 38.113 92 72.867 M8 1,3-dimethyl-t-cyclohexane 0.225 0.221 0.193 63.858 93 73.025 589-81-1 I8 3-Methylheptane 0.282 0.302 0.237 78.425 94 73.210 619-99-8 I8 3-Ethylhexane 0.141 0.150 0.119 39.352 95 74.105 ? Unidentified 0.036 0.035 0.031 12.411 96 74.944 3522-94-9 I9 2,2,5-Trimethylhexane 2.875 3.075 2.155 801.339

97 75.274 M8 3c-Ethylmethylcyclopentane 0.013 0.013 0.011 3.696 98 75.495 M8 3t-Ethylmethylcyclopentane 0.018 0.018 0.015 5.120 99 75.911 ? Unidentified 0.021 0.021 0.018 7.347 100 76.197 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.103 0.100 0.088 29.111 101 77.569 111-65-9 P8 n-Octane 0.638 0.687 0.537 177.379 102 78.511 ? Unidentified 0.079 0.077 0.068 27.364 103 80.059 1069-53-0 I9 2,3,5-Trimethylhexane 0.512 0.536 0.384 142.627 104 80.618 C8 C9 - IsoOlefin - 1 0.021 0.021 0.018 6.075 105 81.057 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.019 0.018 0.016 5.270 106 81.235 1071-26-7 I9 2,4-Dimethylheptane 0.096 0.102 0.072 26.839

107 81.870 1678-91-7 M8 Ethylcyclohexane 0.148 0.143 0.127 41.964 108 82.197 1072-05-5 I9 2,6-Dimethylheptane 0.152 0.162 0.114 42.338 109 82.675 ? Unidentified 0.032 0.031 0.027 11.121 110 83.135 I9 2,5-Dimethylheptane 0.303 0.320 0.227 84.432 111 83.309 926-82-9 I9 3,5-Dimethylheptane 0.032 0.034 0.024 8.993 112 84.459 100-41-4 Q8 Ethylbenzene 2.932 2.558 2.656 878.098 113 84.623 ? Unidentified 0.039 0.040 0.030 13.534 114 84.866 ? Unidentified 0.049 0.047 0.037 16.845 115 85.717 108-38-3 Q8 m-Xylene 7.862 6.880 7.121 2354.451 116 85.858 106-42-3 Q8 p-Xylene 3.682 3.234 3.334 1102.488

117 86.224 C8 C9-IsoOlefin-3 0.020 0.020 0.015 5.719 118 86.330 ? Unidentified 0.019 0.019 0.015 6.658 119 87.020 2216-34-4 I9 4-Methyloctane 0.062 0.065 0.046 17.238 120 87.152 3221-61-2 I9 2-Methyloctane 0.084 0.089 0.063 23.458 121 88.016 2216-33-3 I9 3-Methyloctane 0.092 0.097 0.069 25.706 122 88.484 ? Unidentified 0.198 0.219 0.151 68.672 123 88.667 95-47-6 Q8 o-Xylene 2.125 1.826 1.925 636.409 124 89.069 I10 C10 - IsoParaffin - 1 0.626 0.650 0.423 174.741 125 89.490 3728-57-2 M8 Cyclopentane, 1-methyl-2-propyl- 0.010 0.009 0.009 3.090 126 89.644 M9 trans-1,3-Diethylcyclopentane 0.026 0.022 0.020 7.669

127 89.916 14720-74-2 I10 2,2,4-trimethylheptane 0.439 0.457 0.297 122.677 128 91.480 111-84-2 P9 n-Nonane 0.443 0.467 0.332 123.591 129 92.067 4926-90-3 M9 1,1-Methylethylcyclohexane 0.025 0.023 0.019 7.022

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 92.838 98-82-8 Q9 i-Propylbenzene 0.038 0.033 0.030 11.256 131 93.029 ? Unidentified 0.022 0.021 0.017 7.692 132 93.029 ? Unidentified 0.022 0.024 0.015 7.692 133 93.029 ? Unidentified 0.022 0.017 0.015 7.692 134 93.601 ? Unidentified 0.128 0.134 0.087 44.490 135 93.824 15869-87-1 I10 2,2-Dimethyloctane 0.045 0.047 0.030 12.529 136 94.269 ? Unidentified 0.008 0.006 0.778 2.807 137 94.269 ? Unidentified 0.008 0.009 0.006 2.807 138 94.625 15869-89-3 I10 2,5-Dimethyloctane 0.068 0.070 0.046 18.921 139 95.101 2040-95-1 I10 2,7-Dimethyloctane 0.025 0.026 0.017 7.109

140 95.266 2051-30-1 I10 2,4-Dimethyloctane 0.103 0.108 0.070 28.899 141 95.661 I10 2,6-Dimethyloctane 0.038 0.039 0.026 10.618 142 96.305 103-65-1 Q9 n-Propylbenzene 0.307 0.269 0.246 91.310 143 97.156 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.153 1.008 0.922 342.957 144 97.389 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.535 0.470 0.428 159.175 145 98.015 108-67-8 Q9 1,3,5-Trimethylbenzene 0.722 0.631 0.578 214.872 146 98.685 17301-94-8 I10 4-Methylnonane 0.014 0.015 0.010 4.015 147 98.891 I10 2,2,6-Trimethyloctane 1.445 1.504 0.976 403.485 148 99.099 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.398 0.342 0.319 118.476 149 99.662 5911-04-6 I10 3-Methylnonane 0.018 0.019 0.012 5.094

150 100.128 ? Unidentified 0.079 0.060 0.049 27.488 151 100.254 ? Unidentified 0.216 0.220 0.133 75.093 152 100.478 I11 C11-Isoparaffin-2 0.115 0.117 0.071 32.107 153 100.739 95-63-6 Q9 1,2,4-Trimethylbenzene 2.029 1.752 1.623 603.617 154 100.942 ? Unidentified 0.128 0.138 0.088 44.457 155 101.063 ? Unidentified 0.076 0.078 0.051 26.411 156 101.320 1678-98-4 M10 i-Butylcyclohexane 0.021 0.020 0.014 5.975 157 102.108 17302-01-1 I10 3-Ethyl-3-methylheptane 0.178 0.181 0.109 49.656 158 102.461 538-93-2 Q10 i-Butylbenzene 0.183 0.162 0.131 54.023 159 102.652 124-18-5 P10 n-Decane 0.057 0.059 0.038 15.850

160 102.975 ? Unidentified 0.040 0.041 0.025 13.917 161 103.611 526-73-8 Q9 1,2,3-Trimethylbenzene 0.320 0.271 0.256 95.211 162 103.986 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.023 0.020 0.017 6.854 163 104.192 I11 C11 Isoparaffin-4 0.018 0.018 0.011 4.995 164 104.396 ? Unidentified 0.079 0.069 0.056 27.282 165 104.802 J9 Indan 0.122 0.096 0.099 36.951 166 105.430 J10 Indene 0.384 0.301 0.312 116.086 167 106.146 I11 C11-Isoparaffin-7 0.116 0.118 0.071 32.444 168 106.332 141-93-5 Q10 1,3-Diethylbenzene 0.041 0.036 0.029 12.074 169 106.617 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.432 0.379 0.309 127.788

170 106.948 105-05-5 Q10 1,4-Diethylbenzene 0.171 0.150 0.122 50.580 171 107.174 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.149 0.128 0.107 44.095 172 107.439 135-01-3 Q10 1,2-Diethylbenzene 0.025 0.021 0.018 7.329

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 107.886 ? Unidentified 0.017 0.017 0.010 5.741 174 108.025 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.053 0.046 0.038 15.777 175 108.364 I11 C11- Isoparaffin-11 0.145 0.147 0.089 40.533 176 108.549 ? Unidentified 0.030 0.030 0.018 10.360 177 108.876 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.128 0.110 0.092 37.874 178 109.038 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.184 0.158 0.132 54.362 179 109.196 J10 2-Methylindan 0.018 0.014 0.013 5.371 180 109.544 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.296 0.256 0.212 87.465 181 110.097 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.034 0.029 0.024 9.934 182 111.012 Q11 1-Methyl-4-t-butylbenzene 0.018 0.016 0.012 5.316

183 111.222 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.082 0.069 0.059 24.230 184 111.527 1120-21-4 P11 n-Undecane 0.011 0.011 0.007 2.979 185 112.163 Q10 1,2,4,5-Tetramethylbenzene 0.247 0.211 0.177 73.163 186 112.429 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.349 0.297 0.250 103.312 187 113.288 ? Unidentified 0.008 0.008 0.005 2.737 188 113.581 Q11 C11 - Aromatic - 3 0.034 0.029 0.022 10.028 189 113.763 874-35-1 H10 5-Methylindan 0.107 0.091 0.077 31.523 190 113.903 Q12 1,2-Di-i-propylbenzene 0.039 0.034 0.023 11.589 191 114.117 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.058 0.049 0.038 17.138 192 114.274 Q11 C11 - Aromatic - 4 0.030 0.026 0.020 8.867

193 114.514 824-22-6 J10 4-Methylindan 0.145 0.123 0.106 42.951 194 114.765 824-63-5 H10 2-Methylindan 0.143 0.122 0.104 42.465 195 114.978 ? Unidentified 0.010 0.008 0.006 3.345 196 115.091 538-68-1 Q11 n-Pentylbenzene 0.013 0.011 0.009 3.937 197 115.320 Q11 tert-Pentylbenzene 0.059 0.050 0.038 17.315 198 115.633 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.026 0.022 0.017 7.799 199 115.743 Q11 C11 - Aromatic - 7 0.033 0.029 0.021 9.683 200 116.205 100-18-5 Q12 1,4-Di-i-propylbenzene 0.049 0.042 0.029 14.472 201 116.632 91-20-3 G10 Naphthalene 0.118 0.087 0.088 36.509 202 117.090 J11 1,1-Dimethyl Indane 0.012 0.009 0.008 3.651

203 117.431 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.013 0.011 0.008 3.857 204 117.737 Q12 1,3-Di-n-propylbenzene 0.044 0.037 0.026 12.870 205 117.847 Q11 C11 - Aromatic - 11 0.025 0.022 0.016 7.224 206 118.402 17851-27-2 Q11 1-ethyl-2,4,5-trimethylbenzen 0.017 0.015 0.011 4.960 207 123.282 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.006 2.848 208 124.149 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.530

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.390 74-98-6 Propane 0.007 0.011 0.016 1.931

9.793 106-97-8 n-Butane 2.583 3.375 4.273 706.418 17.696 109-66-0 n-Pentane 2.607 3.148 3.474 717.875 35.297 110-54-3 n-Hexane 1.508 1.729 1.682 416.829 57.622 142-82-5 n-Heptane 0.876 0.969 0.840 243.113 77.569 111-65-9 n-Octane 0.638 0.687 0.537 177.379 91.480 111-84-2 n-Nonane 0.443 0.467 0.332 123.591 102.652 124-18-5 n-Decane 0.057 0.059 0.038 15.850 111.527 1120-21-4 n-Undecane 0.011 0.011 0.007 2.979

I-Paraffins 8.612 75-28-5 i-Butane 0.054 0.074 0.090 14.889

10.390 463-82-1 2,2-Dimethylpropane 0.020 0.026 0.027 5.496 14.714 78-78-4 i-Pentane 5.547 6.771 7.392 1527.638 22.618 75-83-2 2,2-Dimethylbutane 0.173 0.202 0.193 47.941 27.837 79-29-8 2,3-Dimethylbutane 0.464 0.530 0.517 128.182 28.909 107-83-5 2-Methylpentane 2.182 2.527 2.435 603.375 31.551 96-14-0 3-Methylpentane 1.323 1.506 1.476 365.693 41.741 108-08-7 2,4-Dimethylpentane 0.224 0.252 0.215 62.201 42.279 464-06-2 2,2,3-Trimethylbutane 0.025 0.027 0.024 6.945 50.196 591-76-4 2-Methylhexane 0.978 1.089 0.938 271.379 52.032 589-34-4 3-Methylhexane 0.633 0.697 0.608 175.756 54.684 540-84-1 2,2,4-Trimethylpentane 0.250 0.273 0.211 69.577 62.423 590-73-8 2,2-Dimethylhexane 0.033 0.036 0.028 9.183 64.513 564-02-3 2,2,3-Trimethylpentane 0.422 0.446 0.355 117.429 64.757 592-13-2 2,5-Dimethylhexane 0.781 0.852 0.657 217.244 65.096 589-43-5 2,4-Dimethylhexane 0.702 0.758 0.591 195.293 66.335 563-16-6 3,3-Dimethylhexane 0.025 0.027 0.021 7.092 68.129 565-75-3 2,3,4-Trimethylpentane 4.456 4.687 3.751 1239.462 68.837 560-21-4 2,3,3-Trimethylpentane 4.966 5.172 4.180 1381.299 70.439 584-94-1 2,3-Dimethylhexane 1.244 1.321 1.047 346.086 71.704 592-27-8 2-Methylheptane 0.330 0.357 0.277 91.676 71.963 589-53-7 4-Methylheptane 0.240 0.258 0.202 66.823 73.025 589-81-1 3-Methylheptane 0.282 0.302 0.237 78.425 73.210 619-99-8 3-Ethylhexane 0.141 0.150 0.119 39.352 74.944 3522-94-9 2,2,5-Trimethylhexane 2.875 3.075 2.155 801.339 80.059 1069-53-0 2,3,5-Trimethylhexane 0.512 0.536 0.384 142.627 81.235 1071-26-7 2,4-Dimethylheptane 0.096 0.102 0.072 26.839 82.197 1072-05-5 2,6-Dimethylheptane 0.152 0.162 0.114 42.338 83.135 2,5-Dimethylheptane 0.303 0.320 0.227 84.432 83.309 926-82-9 3,5-Dimethylheptane 0.032 0.034 0.024 8.993 87.020 2216-34-4 4-Methyloctane 0.062 0.065 0.046 17.238 87.152 3221-61-2 2-Methyloctane 0.084 0.089 0.063 23.458 88.016 2216-33-3 3-Methyloctane 0.092 0.097 0.069 25.706 89.069 C10 - IsoParaffin - 1 0.626 0.650 0.423 174.741 89.916 14720-74-2 2,2,4-trimethylheptane 0.439 0.457 0.297 122.677 93.824 15869-87-1 2,2-Dimethyloctane 0.045 0.047 0.030 12.529 94.625 15869-89-3 2,5-Dimethyloctane 0.068 0.070 0.046 18.921

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 95.101 2040-95-1 2,7-Dimethyloctane 0.025 0.026 0.017 7.109

95.266 2051-30-1 2,4-Dimethyloctane 0.103 0.108 0.070 28.899 95.661 2,6-Dimethyloctane 0.038 0.039 0.026 10.618 98.685 17301-94-8 4-Methylnonane 0.014 0.015 0.010 4.015 98.891 2,2,6-Trimethyloctane 1.445 1.504 0.976 403.485 99.662 5911-04-6 3-Methylnonane 0.018 0.019 0.012 5.094 100.478 C11-Isoparaffin-2 0.115 0.117 0.071 32.107 102.108 17302-01-1 3-Ethyl-3-methylheptane 0.178 0.181 0.109 49.656 104.192 C11 Isoparaffin-4 0.018 0.018 0.011 4.995 106.146 C11-Isoparaffin-7 0.116 0.118 0.071 32.444 108.364 C11- Isoparaffin-11 0.145 0.147 0.089 40.533

Aromatics Mono-Aromatics 45.140 71-42-3 Benzene 0.624 0.537 0.768 190.375

68.718 108-88-3 Toluene 17.346 15.130 18.100 5233.747 84.459 100-41-4 Ethylbenzene 2.932 2.558 2.656 878.098 85.717 108-38-3 m-Xylene 7.862 6.880 7.121 2354.451 85.858 106-42-3 p-Xylene 3.682 3.234 3.334 1102.488 88.667 95-47-6 o-Xylene 2.125 1.826 1.925 636.409 92.838 98-82-8 i-Propylbenzene 0.038 0.033 0.030 11.256 96.305 103-65-1 n-Propylbenzene 0.307 0.269 0.246 91.310 97.156 620-14-4 1-Methyl-3-ethylbenzene 1.153 1.008 0.922 342.957 97.389 622-96-8 1-Methyl-4-ethylbenzene 0.535 0.470 0.428 159.175 98.015 108-67-8 1,3,5-Trimethylbenzene 0.722 0.631 0.578 214.872 99.099 611-14-3 1-Methyl-2-ethylbenzene 0.398 0.342 0.319 118.476 100.739 95-63-6 1,2,4-Trimethylbenzene 2.029 1.752 1.623 603.617 102.461 538-93-2 i-Butylbenzene 0.183 0.162 0.131 54.023 103.611 526-73-8 1,2,3-Trimethylbenzene 0.320 0.271 0.256 95.211 103.986 535-77-3 1-Methyl-3-i-propylbenzene 0.023 0.020 0.017 6.854 106.332 141-93-5 1,3-Diethylbenzene 0.041 0.036 0.029 12.074 106.617 1074-43-7 1-Methyl-3-n-propylbenzene 0.432 0.379 0.309 127.788 106.948 105-05-5 1,4-Diethylbenzene 0.171 0.150 0.122 50.580 107.174 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.149 0.128 0.107 44.095 107.439 135-01-3 1,2-Diethylbenzene 0.025 0.021 0.018 7.329 108.025 1074-17-5 1-Methyl-2-n-propylbenzene 0.053 0.046 0.038 15.777 108.876 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.128 0.110 0.092 37.874 109.038 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.184 0.158 0.132 54.362 109.544 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.296 0.256 0.212 87.465 110.097 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.034 0.029 0.024 9.934 111.012 1-Methyl-4-t-butylbenzene 0.018 0.016 0.012 5.316 111.222 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.082 0.069 0.059 24.230 112.163 1,2,4,5-Tetramethylbenzene 0.247 0.211 0.177 73.163 112.429 527-53-7 1,2,3,5-Tetramethylbenzene 0.349 0.297 0.250 103.312 113.581 C11 - Aromatic - 3 0.034 0.029 0.022 10.028 113.903 1,2-Di-i-propylbenzene 0.039 0.034 0.023 11.589 114.117 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.058 0.049 0.038 17.138 114.274 C11 - Aromatic - 4 0.030 0.026 0.020 8.867

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.091 538-68-1 n-Pentylbenzene 0.013 0.011 0.009 3.937

115.320 tert-Pentylbenzene 0.059 0.050 0.038 17.315 115.633 577-55-9 1-Methyl-2-n-butylbenzene 0.026 0.022 0.017 7.799 115.743 C11 - Aromatic - 7 0.033 0.029 0.021 9.683 116.205 100-18-5 1,4-Di-i-propylbenzene 0.049 0.042 0.029 14.472 117.431 7364-19-4 1t-Butyl-4-ethylbenzene 0.013 0.011 0.008 3.857 117.737 1,3-Di-n-propylbenzene 0.044 0.037 0.026 12.870 117.847 C11 - Aromatic - 11 0.025 0.022 0.016 7.224 118.402 17851-27-2 1-ethyl-2,4,5-trimethylbenzen 0.017 0.015 0.011 4.960

Naphthalenes 116.632 91-20-3 Naphthalene 0.118 0.087 0.088 36.509

123.282 91-57-6 2-Methylnaphthalene 0.009 0.007 0.006 2.848 124.149 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.530

Naphtheno/Olefino-Benzs

113.763 874-35-1 5-Methylindan 0.107 0.091 0.077 31.523 114.765 824-63-5 2-Methylindan 0.143 0.122 0.104 42.465

Indenes 104.802 Indan 0.122 0.096 0.099 36.951

105.430 Indene 0.384 0.301 0.312 116.086 109.196 2-Methylindan 0.018 0.014 0.013 5.371 114.514 824-22-6 4-Methylindan 0.145 0.123 0.106 42.951 117.090 1,1-Dimethyl Indane 0.012 0.009 0.008 3.651

Naphthenes Mono-Naphthenes 27.105 287-92-3 Cyclopentane 0.264 0.268 0.362 74.721

40.161 96-37-7 Methylcyclopentane 1.457 1.472 1.664 412.630 47.060 110-82-7 Cyclohexane 0.942 0.915 1.076 266.886 52.885 1759-58-6 1t,3-Dimethylcyclopentane 0.203 0.205 0.199 57.537 53.474 2532-58-3 1c,3-Dimethylcyclopentane 0.163 0.165 0.159 46.110 54.094 822-50-4 1t,2-Dimethylcyclopentane 0.241 0.243 0.236 68.257 59.206 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.018 5.091 61.069 108-87-2 Methylcyclohexane 1.455 1.430 1.425 412.203 62.015 4516-69-2 1,1,3-Trimethylcyclopentane 0.041 0.041 0.035 11.584 63.861 1640-89-7 Ethylcyclopentane 0.055 0.055 0.054 15.678 65.930 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.040 0.040 0.034 11.390 67.464 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.035 0.035 0.030 9.996 72.867 1,3-dimethyl-t-cyclohexane 0.225 0.221 0.193 63.858 75.274 3c-Ethylmethylcyclopentane 0.013 0.013 0.011 3.696 75.495 3t-Ethylmethylcyclopentane 0.018 0.018 0.015 5.120 76.197 2207-03-6 1t,3-Dimethylcyclohexane 0.103 0.100 0.088 29.111 81.057 2207-01-4 1c,2-Dimethylcyclohexane 0.019 0.018 0.016 5.270 81.870 1678-91-7 Ethylcyclohexane 0.148 0.143 0.127 41.964 89.490 3728-57-2 Cyclopentane, 1-methyl-2-propyl- 0.010 0.009 0.009 3.090 89.644 trans-1,3-Diethylcyclopentane 0.026 0.022 0.020 7.669 92.067 4926-90-3 1,1-Methylethylcyclohexane 0.025 0.023 0.019 7.022 101.320 1678-98-4 i-Butylcyclohexane 0.021 0.020 0.014 5.975

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.405 115-11-7 Isobutene 0.015 0.019 0.025 4.205

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 9.444 106-98-9 Butene-1 0.018 0.023 0.031 5.095

10.268 624-64-6 t-Butene-2 0.071 0.088 0.121 19.989 10.988 590-18-1 c-Butene-2 0.083 0.102 0.143 23.628 16.337 109-67-1 Pentene-1 0.325 0.384 0.446 92.164 18.804 646-04-8 t-Pentene-2 0.826 0.964 1.133 234.031 19.828 627-20-3 c-Pentene-2 0.452 0.521 0.620 128.015 32.942 592-41-6 Hexene-1 0.159 0.178 0.182 45.116 35.940 13269-52-8 t-Hexene-3 0.260 0.288 0.297 73.558 36.412 4050-45-7 t-Hexene-2 0.498 0.551 0.569 141.009 38.244 7688-21-3 c-Hexene-2 0.212 0.232 0.242 60.014 55.028 592-76-7 Heptene-1 0.030 0.032 0.029 8.363 56.884 14686-14-7 t-Heptene-3 0.032 0.035 0.032 9.165 57.837 7642-10-6 c-Heptene-3 0.024 0.026 0.023 6.742 58.745 14686-13-6 t-Heptene-2 0.015 0.016 0.014 4.121

Iso-Olefins 13.131 563-45-1 3-Methylbutene-1 0.067 0.081 0.092 19.045

17.169 563-46-2 2-Methylbutene-1 0.495 0.576 0.679 140.224 20.489 513-35-9 2-Methylbutene-2 1.018 1.163 1.396 288.432 28.690 691-38-3 4-Methyl-c-pentene-2 0.043 0.048 0.049 12.156 29.343 674-76-0 4-Methyl-t-pentene-2 0.129 0.145 0.147 36.488 32.728 763-29-1 2-Methylpentene-1 0.222 0.245 0.253 62.795 36.908 625-27-4 2-Methylpentene-2 0.337 0.369 0.385 95.505 37.313 922-62-3 3-Methyl-c-pentene-2 0.260 0.282 0.297 73.741 39.591 3404-73-7 3,3-Dimethylpentene-1 0.309 0.333 0.303 87.618 42.042 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.014 3.992 46.164 3404-61-3 3-Methylhexene-1 0.016 0.017 0.015 4.435 46.748 3524-73-0 5-Methylhexene-1 0.057 0.062 0.056 16.240 48.806 15840-60-5 2-Methyl-c-hexene-3 0.040 0.044 0.039 11.419 49.800 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.055 0.050 14.377 54.398 C7 - Iso-Olefin - 2 0.022 0.023 0.022 6.324 56.362 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.014 4.003 57.246 6094-02-6 2-Methylhexene-1 0.058 0.063 0.056 16.332 58.117 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.026 7.433 58.361 3899-36-3 3-Methyl-t-hexene-3 0.020 0.022 0.019 5.618 59.648 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.015 4.321 60.432 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.013 3.802 70.138 C8 - Diolefin - 1 0.015 0.015 0.013 4.307 80.618 C9 - IsoOlefin - 1 0.021 0.021 0.018 6.075 86.224 C9-IsoOlefin-3 0.020 0.020 0.015 5.719

Naphtheno-Olefins 25.252 142-29-0 Cyclopentene 0.193 0.189 0.272 56.283

45.344 693-89-0 1-Methylcyclopentene 0.362 0.351 0.424 105.055 50.674 110-83-8 Cyclohexene 0.044 0.041 0.052 12.514

Di-Olefins 18.207 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.901

20.825 2004-70-8 1t,3-Pentadiene 0.015 0.016 0.021 4.266

Oxygenates 26.492 71-23-8 n-Propanol 0.112 0.106 0.179 22.154

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Oxygenates Unidentified 19.444 Unidentified 0.006 0.007 0.008 1.945

22.077 Unidentified 0.006 0.006 0.008 1.965 26.420 Unidentified 0.037 0.035 0.059 12.823 28.231 Unidentified 0.051 0.052 0.055 17.571 44.937 Unidentified 0.012 0.012 0.014 4.097 47.596 Unidentified 0.034 0.037 0.034 11.948 72.099 Unidentified 0.110 0.115 0.092 38.113 74.105 Unidentified 0.036 0.035 0.031 12.411 75.911 Unidentified 0.021 0.021 0.018 7.347 78.511 Unidentified 0.079 0.077 0.068 27.364 82.675 Unidentified 0.032 0.031 0.027 11.121 84.623 Unidentified 0.039 0.040 0.030 13.534 84.866 Unidentified 0.049 0.047 0.037 16.845 86.330 Unidentified 0.019 0.019 0.015 6.658 88.484 Unidentified 0.198 0.219 0.151 68.672 93.029 Unidentified 0.022 0.021 0.017 7.692 93.029 Unidentified 0.022 0.024 0.015 7.692 93.029 Unidentified 0.022 0.017 0.015 7.692 93.601 Unidentified 0.128 0.134 0.087 44.490 94.269 Unidentified 0.008 0.006 0.778 2.807 94.269 Unidentified 0.008 0.009 0.006 2.807 100.128 Unidentified 0.079 0.060 0.049 27.488 100.254 Unidentified 0.216 0.220 0.133 75.093 100.942 Unidentified 0.128 0.138 0.088 44.457 101.063 Unidentified 0.076 0.078 0.051 26.411 102.975 Unidentified 0.040 0.041 0.025 13.917 104.396 Unidentified 0.079 0.069 0.056 27.282 107.886 Unidentified 0.017 0.017 0.010 5.741 108.549 Unidentified 0.030 0.030 0.018 10.360 113.288 Unidentified 0.008 0.008 0.005 2.737 114.978 Unidentified 0.010 0.008 0.006 3.345

Plus

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

Unidentified n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane
Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified
2,2,5-Trimethylhexane

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF95.090.085.080.075.0 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene C9-IsoOlefin-3 Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 Cyclopentane, 1-methyl-2-propyl- trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 1-ethyl-2,4,5-trimethylbenzen

2-Methylnaphthalene

1-Methylnaphthalene

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF Sample: ODDB-91312 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91312 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000017.D\SIG1000017_FID1_A.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 6.856 7.845 7.555

I-Paraffins 41.626 44.836 35.885

Aromatics 24.375 20.489 19.484 Mono-Aromatics 21.929 18.602 17.708 Naphthalenes 0.104 0.075 0.070 Naphtheno/Olefino-Benzs 0.194 0.161 0.129 Indenes 2.148 1.652 1.577

Naphthenes 3.309 3.216 3.407 Mono-Naphthenes 3.309 3.216 3.407 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 8.753 9.551 9.904 n-Olefins 4.609 5.098 5.225 Iso-Olefins 3.506 3.844 3.944 Naphtheno-Olefins 0.613 0.580 0.702 Di-Olefins 0.026 0.028 0.033

Oxygenates 9.688 9.057 18.459

Unidentified 5.393 5.006 5.305

Plus 0.000 0.000 0.000

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 9.506 8.889 18.193 C3 0.182 0.168 0.267 C4 1.266 1.602 1.931 C5 8.230 9.515 10.198 C6 24.737 26.860 25.571 C7 9.511 9.020 8.796 C8 19.219 19.034 15.155 C9 7.222 6.401 5.228 C10 11.881 10.772 7.732 C11 2.677 2.581 1.529 C12 0.178 0.153 0.096

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 1.053 1.342 1.597 C5 0.830 0.978 1.014 C6 4.467 4.998 4.571 C7 0.210 0.226 0.184 C8 0.025 0.026 0.019 C9 0.107 0.110 0.073 C10 0.060 0.060 0.037 C11 0.105 0.104 0.059

I-Paraffins C4 0.021 0.028 0.032 C5 3.608 4.296 4.409 C6 12.698 14.234 12.992 C7 2.835 3.081 2.494 C8 13.722 14.348 10.591 C9 1.439 1.496 0.989 C10 5.219 5.287 3.205 C11 2.046 2.029 1.154 C12 0.038 0.037 0.019

Mono-Aromatics C6 0.830 0.697 0.937 C7 5.273 4.487 5.046 C8 5.472 4.660 4.545 C9 5.488 4.651 4.026 C10 4.320 3.652 2.838 C11 0.405 0.339 0.241 C12 0.140 0.116 0.076

Naphthalenes C10 0.086 0.062 0.059 C11 0.018 0.013 0.011

Naphtheno/Olefino-Benzs C10 0.194 0.161 0.129

Indenes C9 0.184 0.141 0.137 C10 1.936 1.489 1.423 C11 0.028 0.021 0.017

Mono-Naphthenes C5 0.134 0.133 0.168 C6 2.711 2.632 2.840 C7 0.399 0.390 0.358 C9 0.004 0.004 0.003 C10 0.061 0.057 0.039

n-Olefins C4 0.192 0.232 0.302

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.637 1.862 2.058 C6 2.601 2.820 2.725 C7 0.104 0.110 0.094 C11 0.075 0.074 0.047

Iso-Olefins C5 1.798 2.030 2.261 C6 1.013 1.085 1.061 C7 0.690 0.725 0.620 C10 0.004 0.004 0.003

Naphtheno-Olefins C5 0.197 0.188 0.255 C6 0.416 0.392 0.447

Di-Olefins C5 0.026 0.028 0.033

Oxygenates C2 9.506 8.889 18.193 C3 0.182 0.168 0.267

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 25.07 24.01 5% 81.73 80.99 10% 133.69 100.24 15% 139.15 138.19 20% 144.63 140.31 25% 153.05 145.52 30% 155.55 154.43 35% 172.46 157.59 40% 173.02 172.60 45% 177.21 173.21 50% 209.56 193.46 55% 228.46 209.90 60% 230.79 229.87 65% 237.35 232.45 70% 277.56 239.32 75% 303.39 281.69 80% 331.87 322.74 85% 336.04 332.54 90% 358.69 352.22 95% 363.20 363.20 FBP 402.18 393.64

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.611 75-28-5 I4 i-Butane 0.021 0.028 0.032 5.507 2 9.404 115-11-7 K4 Isobutene 0.015 0.019 0.024 4.181 3 9.442 106-98-9 K4 Butene-1 0.019 0.023 0.029 5.037 4 9.791 106-97-8 P4 n-Butane 1.053 1.342 1.597 275.365 5 10.265 624-64-6 K4 t-Butene-2 0.073 0.089 0.114 19.651 6 10.387 463-82-1 I5 2,2-Dimethylpropane 0.008 0.010 0.010 2.212 7 10.986 590-18-1 K4 c-Butene-2 0.086 0.102 0.135 23.193 8 12.745 64-17-5 X2 Ethanol 9.506 8.889 18.193 1107.028 9 13.121 563-45-1 C5 3-Methylbutene-1 0.258 0.303 0.324 69.877 10 14.703 78-78-4 I5 i-Pentane 3.599 4.286 4.398 948.107

11 16.329 109-67-1 K5 Pentene-1 0.332 0.382 0.417 89.856 12 17.170 563-46-2 C5 2-Methylbutene-1 0.504 0.571 0.633 136.420 13 17.690 109-66-0 P5 n-Pentane 0.830 0.978 1.014 218.613 14 18.200 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.910 15 18.796 646-04-8 K5 t-Pentene-2 0.843 0.959 1.059 228.284 16 19.820 627-20-3 K5 c-Pentene-2 0.463 0.521 0.581 125.316 17 20.489 513-35-9 C5 2-Methylbutene-2 1.037 1.155 1.304 280.960 18 20.818 2004-70-8 E5 1t,3-Pentadiene 0.015 0.017 0.020 4.247 19 22.065 ? Unidentified 0.006 0.006 0.008 1.914 20 22.615 75-83-2 I6 2,2-Dimethylbutane 0.101 0.115 0.103 26.713

21 25.246 142-29-0 B5 Cyclopentene 0.197 0.188 0.255 54.978 22 26.486 71-23-8 X3 n-Propanol 0.182 0.168 0.267 34.488 23 27.097 287-92-3 M5 Cyclopentane 0.134 0.133 0.168 36.306 24 27.829 79-29-8 I6 2,3-Dimethylbutane 1.479 1.649 1.513 391.141 25 28.236 ? Unidentified 0.050 0.050 0.050 16.756 26 28.688 691-38-3 C6 4-Methyl-c-pentene-2 0.043 0.047 0.045 11.722 27 28.927 107-83-5 I6 2-Methylpentane 6.385 7.213 6.533 1688.583 28 29.333 674-76-0 C6 4-Methyl-t-pentene-2 0.131 0.144 0.137 35.501 29 31.568 96-14-0 I6 3-Methylpentane 4.733 5.257 4.843 1251.770 30 32.719 763-29-1 C6 2-Methylpentene-1 0.224 0.241 0.235 60.708

31 32.943 592-41-6 K6 Hexene-1 1.605 1.747 1.682 434.942 32 35.306 110-54-3 P6 n-Hexane 4.467 4.998 4.571 1181.419 33 35.934 13269-52-8 K6 t-Hexene-3 0.269 0.291 0.282 72.948 34 36.403 4050-45-7 K6 t-Hexene-2 0.510 0.551 0.534 138.223 35 36.896 625-27-4 C6 2-Methylpentene-2 0.345 0.368 0.361 93.457 36 37.312 922-62-3 C6 3-Methyl-c-pentene-2 0.269 0.285 0.282 72.981 37 38.230 7688-21-3 K6 c-Hexene-2 0.216 0.231 0.227 58.623 38 39.580 3404-73-7 C7 3,3-Dimethylpentene-1 0.318 0.334 0.286 86.204 39 40.153 96-37-7 M6 Methylcyclopentane 1.672 1.648 1.751 452.929 40 41.731 108-08-7 I7 2,4-Dimethylpentane 0.857 0.940 0.754 227.620

41 42.032 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.014 0.012 3.663 42 42.272 464-06-2 I7 2,2,3-Trimethylbutane 0.072 0.077 0.063 19.045 43 44.929 ? Unidentified 0.012 0.012 0.013 3.921

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 45.131 71-42-3 Q6 Benzene 0.830 0.697 0.937 242.286 45 45.334 693-89-0 B6 1-Methylcyclopentene 0.370 0.350 0.397 102.706 46 46.159 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.014 4.268 47 46.742 3524-73-0 C7 5-Methylhexene-1 0.063 0.067 0.057 17.127 48 47.050 110-82-7 M6 Cyclohexane 1.039 0.985 1.088 281.457 49 47.593 ? Unidentified 0.035 0.037 0.032 11.652 50 48.800 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.037 11.222 51 49.146 3769-23-1 C7 4-Methylhexene-1 0.011 0.011 0.010 2.927 52 49.791 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.053 0.055 0.047 14.243 53 50.196 591-76-4 I7 2-Methylhexane 1.344 1.461 1.182 356.780

54 50.669 110-83-8 B6 Cyclohexene 0.046 0.042 0.049 12.422 55 52.025 589-34-4 I7 3-Methylhexane 0.562 0.603 0.494 149.213 56 52.879 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.116 0.115 0.104 31.489 57 53.466 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.080 0.080 0.072 21.787 58 54.096 822-50-4 M7 1t,2-Dimethylcyclopentane 0.094 0.093 0.085 25.565 59 54.418 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.021 6.216 60 54.725 540-84-1 I8 2,2,4-Trimethylpentane 5.835 6.222 4.504 1552.483 61 55.019 592-76-7 K7 Heptene-1 0.030 0.032 0.027 8.231 62 56.355 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.013 3.864 63 56.878 14686-14-7 K7 t-Heptene-3 0.033 0.034 0.029 8.876

64 57.239 6094-02-6 C7 2-Methylhexene-1 0.058 0.062 0.052 15.835 65 57.611 142-82-5 P7 n-Heptane 0.210 0.226 0.184 55.631 66 57.831 7642-10-6 K7 c-Heptene-3 0.025 0.026 0.023 6.797 67 58.110 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.027 0.024 7.119 68 58.355 3899-36-3 C7 3-Methyl-t-hexene-3 0.020 0.021 0.018 5.432 69 58.740 14686-13-6 K7 t-Heptene-2 0.016 0.017 0.014 4.353 70 59.200 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.019 0.018 0.017 5.035 71 59.641 20710-38-8 C7 3-Methyl-t-hexene-2 0.016 0.016 0.014 4.306 72 60.425 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.017 0.017 0.015 4.615 73 61.051 108-87-2 M7 Methylcyclohexane 0.089 0.085 0.080 24.121

74 63.108 ? Unidentified 0.019 0.020 0.015 6.363 75 64.507 564-02-3 I8 2,2,3-Trimethylpentane 0.324 0.334 0.250 86.182 76 64.750 592-13-2 I8 2,5-Dimethylhexane 0.740 0.787 0.571 196.892 77 65.089 589-43-5 I8 2,4-Dimethylhexane 0.711 0.749 0.549 189.097 78 68.091 565-75-3 I8 2,3,4-Trimethylpentane 2.613 2.681 2.017 695.175 79 68.621 108-88-3 Q7 Toluene 5.273 4.487 5.046 1521.901 80 68.764 560-21-4 I8 2,3,3-Trimethylpentane 2.646 2.689 2.042 704.029 81 70.428 584-94-1 I8 2,3-Dimethylhexane 0.691 0.716 0.533 183.818 82 71.695 592-27-8 I8 2-Methylheptane 0.043 0.045 0.033 11.357 83 71.961 589-53-7 I8 4-Methylheptane 0.077 0.081 0.060 20.531

84 72.092 ? Unidentified 0.054 0.055 0.041 17.834 85 73.020 589-81-1 I8 3-Methylheptane 0.042 0.044 0.032 11.085 86 74.926 3522-94-9 I9 2,2,5-Trimethylhexane 1.122 1.170 0.771 299.057

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 75.907 ? Unidentified 0.009 0.008 0.006 2.826 88 77.563 111-65-9 P8 n-Octane 0.025 0.026 0.019 6.608 89 78.506 ? Unidentified 0.026 0.026 0.018 8.529 90 80.054 1069-53-0 I9 2,3,5-Trimethylhexane 0.176 0.180 0.121 46.915 91 81.233 1071-26-7 I9 2,4-Dimethylheptane 0.027 0.028 0.019 7.264 92 82.194 1072-05-5 I9 2,6-Dimethylheptane 0.030 0.031 0.020 7.894 93 83.128 I9 2,5-Dimethylheptane 0.077 0.080 0.053 20.613 94 84.440 100-41-4 Q8 Ethylbenzene 0.982 0.835 0.815 281.186 95 84.617 ? Unidentified 0.012 0.012 0.008 3.921 96 84.859 ? Unidentified 0.010 0.009 0.007 3.248

97 85.669 108-38-3 Q8 m-Xylene 2.519 2.151 2.092 721.507 98 85.817 106-42-3 Q8 p-Xylene 1.160 0.994 0.963 332.176 99 85.963 ? Unidentified 0.026 0.026 0.018 8.624 100 88.011 2216-33-3 I9 3-Methyloctane 0.007 0.007 0.005 1.752 101 88.479 ? Unidentified 0.048 0.052 0.034 15.974 102 88.652 95-47-6 Q8 o-Xylene 0.812 0.681 0.674 232.555 103 89.067 I10 C10 - IsoParaffin - 1 0.172 0.174 0.107 45.911 104 89.913 14720-74-2 I10 2,2,4-trimethylheptane 0.122 0.123 0.075 32.507 105 91.460 111-84-2 P9 n-Nonane 0.107 0.110 0.073 28.498 106 92.085 ? Unidentified 0.011 0.010 0.007 3.546

107 92.838 98-82-8 Q9 i-Propylbenzene 0.030 0.026 0.022 8.569 108 93.028 ? Unidentified 0.011 0.010 0.008 3.580 109 93.028 ? Unidentified 0.011 0.011 0.007 3.580 110 93.028 ? Unidentified 0.011 0.008 0.007 3.580 111 93.138 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.004 0.004 0.003 1.142 112 93.138 C10 C10-IsoOlefin-4 0.004 0.004 0.003 1.142 113 93.138 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.142 114 93.602 ? Unidentified 0.159 0.162 0.099 52.853 115 93.825 15869-87-1 I10 2,2-Dimethyloctane 0.055 0.056 0.034 14.762 116 94.267 ? Unidentified 0.022 0.016 1.949 7.338

117 94.267 ? Unidentified 0.022 0.023 0.014 7.338 118 94.487 ? Unidentified 0.021 0.019 0.015 6.923 119 94.625 15869-89-3 I10 2,5-Dimethyloctane 0.092 0.092 0.057 24.444 120 95.019 ? Unidentified 0.021 0.021 0.013 6.923 121 95.104 2040-95-1 I10 2,7-Dimethyloctane 0.026 0.026 0.016 6.899 122 95.268 2051-30-1 I10 2,4-Dimethyloctane 0.243 0.246 0.151 64.889 123 95.661 I10 2,6-Dimethyloctane 0.069 0.070 0.043 18.544 124 96.306 103-65-1 Q9 n-Propylbenzene 0.331 0.284 0.243 94.310 125 97.155 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.193 1.018 0.875 339.465 126 97.389 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.543 0.465 0.399 154.616

127 98.015 108-67-8 Q9 1,3,5-Trimethylbenzene 0.758 0.646 0.556 215.659 128 98.690 17301-94-8 I10 4-Methylnonane 0.013 0.013 0.008 3.465 129 98.907 I10 2,2,6-Trimethyloctane 3.876 3.937 2.402 1035.316

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 99.100 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.395 0.331 0.290 112.335 131 99.475 ? Unidentified 0.012 0.012 0.007 3.902 132 99.665 5911-04-6 I10 3-Methylnonane 0.019 0.019 0.012 5.104 133 99.841 ? Unidentified 0.011 0.011 0.007 3.552 134 100.131 ? Unidentified 0.222 0.164 0.125 73.829 135 100.258 ? Unidentified 0.622 0.617 0.351 206.582 136 100.481 I11 C11-Isoparaffin-2 0.329 0.326 0.185 87.844 137 100.740 95-63-6 Q9 1,2,4-Trimethylbenzene 2.000 1.685 1.467 569.076 138 100.946 ? Unidentified 0.372 0.391 0.234 123.449 139 101.068 ? Unidentified 0.220 0.222 0.137 73.129

140 101.324 1678-98-4 M10 i-Butylcyclohexane 0.059 0.055 0.037 16.027 141 101.969 ? Unidentified 0.025 0.023 0.016 8.214 142 102.112 17302-01-1 I10 3-Ethyl-3-methylheptane 0.533 0.529 0.301 142.528 143 102.323 ? Unidentified 0.140 0.121 0.092 46.622 144 102.465 ? Unidentified 0.331 0.286 0.217 109.800 145 102.660 124-18-5 P10 n-Decane 0.060 0.060 0.037 15.982 146 102.976 ? Unidentified 0.146 0.145 0.082 48.425 147 103.468 ? Unidentified 0.017 0.014 0.013 5.658 148 103.614 526-73-8 Q9 1,2,3-Trimethylbenzene 0.238 0.196 0.174 67.684 149 103.977 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.039 0.033 0.025 10.974

150 104.193 I11 C11 Isoparaffin-4 0.062 0.061 0.035 16.566 151 104.398 ? Unidentified 0.325 0.280 0.213 107.836 152 104.808 J9 Indan 0.184 0.141 0.137 53.261 153 105.061 I11 C11-Isoparaffin-5 0.027 0.027 0.015 7.346 154 105.442 J10 Indene 1.660 1.270 1.238 480.056 155 105.856 M10 n-ButylCyclohexane 0.002 0.002 0.001 0.589 156 105.995 ? Unidentified 0.013 0.012 0.008 4.456 157 106.156 I11 C11-Isoparaffin-7 0.601 0.596 0.339 160.585 158 106.336 141-93-5 Q10 1,3-Diethylbenzene 0.025 0.022 0.017 7.189 159 106.638 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.731 1.484 1.137 490.089

160 106.904 105-05-5 Q10 1,4-Diethylbenzene 0.439 0.376 0.288 124.232 161 107.177 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.102 0.085 0.067 28.836 162 107.423 135-01-3 Q10 1,2-Diethylbenzene 0.128 0.107 0.084 36.211 163 107.890 ? Unidentified 0.140 0.139 0.079 46.418 164 108.027 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.046 0.039 0.031 13.154 165 108.164 ? Unidentified 0.138 0.137 0.079 45.652 166 108.245 ? Unidentified 0.126 0.125 0.071 41.797 167 108.370 I11 C11- Isoparaffin-11 1.028 1.019 0.580 274.780 168 108.550 ? Unidentified 0.328 0.326 0.185 109.027 169 108.983 ? Unidentified 0.928 0.781 0.610 308.045

170 109.206 J10 2-Methylindan 0.153 0.117 0.102 44.354 171 109.544 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.345 0.291 0.227 97.622 172 109.703 ? Unidentified 0.066 0.050 0.044 21.863

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 110.102 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.834 0.691 0.548 236.002 174 110.528 ? Unidentified 0.034 0.031 0.019 11.232 175 110.730 693-61-8 K11 2-Undecene, (E)- 0.075 0.074 0.047 19.997 176 110.858 ? Unidentified 0.161 0.160 0.101 53.348 177 111.131 ? Unidentified 0.143 0.124 0.085 47.335 178 111.214 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.070 0.058 0.046 19.869 179 111.531 1120-21-4 P11 n-Undecane 0.105 0.104 0.059 28.170 180 111.687 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.114 0.095 0.068 32.259 181 111.798 ? Unidentified 0.080 0.066 0.048 26.517 182 112.164 Q10 1,2,4,5-Tetramethylbenzene 0.242 0.201 0.159 68.488

183 112.430 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.319 0.264 0.209 90.269 184 112.654 ? Unidentified 0.015 0.012 0.009 4.881 185 112.784 ? Unidentified 0.022 0.018 0.015 7.391 186 112.966 I12 C12 - IsoParaffin - 1 0.030 0.030 0.016 8.132 187 113.294 ? Unidentified 0.036 0.036 0.019 11.991 188 113.448 ? Unidentified 0.014 0.014 0.007 4.649 189 113.585 Q11 C11 - Aromatic - 3 0.029 0.024 0.017 8.230 190 113.654 ? Unidentified 0.040 0.033 0.024 13.292 191 113.761 874-35-1 H10 5-Methylindan 0.097 0.080 0.065 27.430 192 113.901 Q12 1,2-Di-i-propylbenzene 0.043 0.036 0.023 12.053

193 114.117 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.058 0.048 0.034 16.342 194 114.293 Q11 C11 - Aromatic - 4 0.037 0.030 0.022 10.358 195 114.514 824-22-6 J10 4-Methylindan 0.123 0.102 0.082 34.770 196 114.682 ? Unidentified 0.028 0.023 0.017 9.294 197 114.765 824-63-5 H10 2-Methylindan 0.097 0.081 0.065 27.522 198 114.978 ? Unidentified 0.012 0.010 0.007 4.092 199 115.090 538-68-1 Q11 n-Pentylbenzene 0.014 0.012 0.009 4.060 200 115.320 Q11 tert-Pentylbenzene 0.053 0.044 0.032 15.033 201 115.633 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.027 0.022 0.016 7.536 202 115.744 Q11 C11 - Aromatic - 7 0.042 0.036 0.025 11.771

203 116.093 I12 C12 - IsoParaffin - 4 0.007 0.007 0.004 2.022 204 116.206 100-18-5 Q12 1,4-Di-i-propylbenzene 0.048 0.040 0.026 13.409 205 116.635 91-20-3 G10 Naphthalene 0.086 0.062 0.059 25.500 206 116.797 J11 4,7-Dimethyl Indane 0.016 0.013 0.010 4.756 207 116.972 ? Unidentified 0.006 0.005 0.003 1.841 208 117.080 J11 1,1-Dimethyl Indane 0.011 0.009 0.007 3.301 209 117.432 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.015 0.013 0.008 4.263 210 117.735 Q12 1,3-Di-n-propylbenzene 0.034 0.028 0.019 9.625 211 117.847 Q11 C11 - Aromatic - 11 0.018 0.016 0.011 5.154 212 118.402 Q11 C11 - Aromatic - 12 0.012 0.011 0.007 3.456

213 123.281 91-57-6 G11 2-Methylnaphthalene 0.012 0.009 0.007 3.554 214 124.145 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.616 215 125.444 ? Unidentified 0.003 0.003 0.002 1.118

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 126.172 ? Unidentified 0.006 0.005 0.003 2.120 217 126.172 ? Unidentified 0.006 0.005 0.003 2.120 218 126.172 ? Unidentified 0.006 0.006 0.003 2.120 219 129.864 ? Unidentified 0.003 0.003 0.002 1.106

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 9.791 106-97-8 n-Butane 1.053 1.342 1.597 275.365

17.690 109-66-0 n-Pentane 0.830 0.978 1.014 218.613 35.306 110-54-3 n-Hexane 4.467 4.998 4.571 1181.419 57.611 142-82-5 n-Heptane 0.210 0.226 0.184 55.631 77.563 111-65-9 n-Octane 0.025 0.026 0.019 6.608 91.460 111-84-2 n-Nonane 0.107 0.110 0.073 28.498 102.660 124-18-5 n-Decane 0.060 0.060 0.037 15.982 111.531 1120-21-4 n-Undecane 0.105 0.104 0.059 28.170

I-Paraffins 8.611 75-28-5 i-Butane 0.021 0.028 0.032 5.507

10.387 463-82-1 2,2-Dimethylpropane 0.008 0.010 0.010 2.212 14.703 78-78-4 i-Pentane 3.599 4.286 4.398 948.107 22.615 75-83-2 2,2-Dimethylbutane 0.101 0.115 0.103 26.713 27.829 79-29-8 2,3-Dimethylbutane 1.479 1.649 1.513 391.141 28.927 107-83-5 2-Methylpentane 6.385 7.213 6.533 1688.583 31.568 96-14-0 3-Methylpentane 4.733 5.257 4.843 1251.770 41.731 108-08-7 2,4-Dimethylpentane 0.857 0.940 0.754 227.620 42.272 464-06-2 2,2,3-Trimethylbutane 0.072 0.077 0.063 19.045 50.196 591-76-4 2-Methylhexane 1.344 1.461 1.182 356.780 52.025 589-34-4 3-Methylhexane 0.562 0.603 0.494 149.213 54.725 540-84-1 2,2,4-Trimethylpentane 5.835 6.222 4.504 1552.483 64.507 564-02-3 2,2,3-Trimethylpentane 0.324 0.334 0.250 86.182 64.750 592-13-2 2,5-Dimethylhexane 0.740 0.787 0.571 196.892 65.089 589-43-5 2,4-Dimethylhexane 0.711 0.749 0.549 189.097 68.091 565-75-3 2,3,4-Trimethylpentane 2.613 2.681 2.017 695.175 68.764 560-21-4 2,3,3-Trimethylpentane 2.646 2.689 2.042 704.029 70.428 584-94-1 2,3-Dimethylhexane 0.691 0.716 0.533 183.818 71.695 592-27-8 2-Methylheptane 0.043 0.045 0.033 11.357 71.961 589-53-7 4-Methylheptane 0.077 0.081 0.060 20.531 73.020 589-81-1 3-Methylheptane 0.042 0.044 0.032 11.085 74.926 3522-94-9 2,2,5-Trimethylhexane 1.122 1.170 0.771 299.057 80.054 1069-53-0 2,3,5-Trimethylhexane 0.176 0.180 0.121 46.915 81.233 1071-26-7 2,4-Dimethylheptane 0.027 0.028 0.019 7.264 82.194 1072-05-5 2,6-Dimethylheptane 0.030 0.031 0.020 7.894 83.128 2,5-Dimethylheptane 0.077 0.080 0.053 20.613 88.011 2216-33-3 3-Methyloctane 0.007 0.007 0.005 1.752 89.067 C10 - IsoParaffin - 1 0.172 0.174 0.107 45.911 89.913 14720-74-2 2,2,4-trimethylheptane 0.122 0.123 0.075 32.507 93.138 C10-isoparaffin-x 0.000 0.000 0.000 1.142 93.825 15869-87-1 2,2-Dimethyloctane 0.055 0.056 0.034 14.762 94.625 15869-89-3 2,5-Dimethyloctane 0.092 0.092 0.057 24.444 95.104 2040-95-1 2,7-Dimethyloctane 0.026 0.026 0.016 6.899 95.268 2051-30-1 2,4-Dimethyloctane 0.243 0.246 0.151 64.889 95.661 2,6-Dimethyloctane 0.069 0.070 0.043 18.544 98.690 17301-94-8 4-Methylnonane 0.013 0.013 0.008 3.465 98.907 2,2,6-Trimethyloctane 3.876 3.937 2.402 1035.316 99.665 5911-04-6 3-Methylnonane 0.019 0.019 0.012 5.104

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 100.481 C11-Isoparaffin-2 0.329 0.326 0.185 87.844

102.112 17302-01-1 3-Ethyl-3-methylheptane 0.533 0.529 0.301 142.528 104.193 C11 Isoparaffin-4 0.062 0.061 0.035 16.566 105.061 C11-Isoparaffin-5 0.027 0.027 0.015 7.346 106.156 C11-Isoparaffin-7 0.601 0.596 0.339 160.585 108.370 C11- Isoparaffin-11 1.028 1.019 0.580 274.780 112.966 C12 - IsoParaffin - 1 0.030 0.030 0.016 8.132 116.093 C12 - IsoParaffin - 4 0.007 0.007 0.004 2.022

Aromatics Mono-Aromatics 45.131 71-42-3 Benzene 0.830 0.697 0.937 242.286

68.621 108-88-3 Toluene 5.273 4.487 5.046 1521.901 84.440 100-41-4 Ethylbenzene 0.982 0.835 0.815 281.186 85.669 108-38-3 m-Xylene 2.519 2.151 2.092 721.507 85.817 106-42-3 p-Xylene 1.160 0.994 0.963 332.176 88.652 95-47-6 o-Xylene 0.812 0.681 0.674 232.555 92.838 98-82-8 i-Propylbenzene 0.030 0.026 0.022 8.569 96.306 103-65-1 n-Propylbenzene 0.331 0.284 0.243 94.310 97.155 620-14-4 1-Methyl-3-ethylbenzene 1.193 1.018 0.875 339.465 97.389 622-96-8 1-Methyl-4-ethylbenzene 0.543 0.465 0.399 154.616 98.015 108-67-8 1,3,5-Trimethylbenzene 0.758 0.646 0.556 215.659 99.100 611-14-3 1-Methyl-2-ethylbenzene 0.395 0.331 0.290 112.335 100.740 95-63-6 1,2,4-Trimethylbenzene 2.000 1.685 1.467 569.076 103.614 526-73-8 1,2,3-Trimethylbenzene 0.238 0.196 0.174 67.684 103.977 535-77-3 1-Methyl-3-i-propylbenzene 0.039 0.033 0.025 10.974 106.336 141-93-5 1,3-Diethylbenzene 0.025 0.022 0.017 7.189 106.638 1074-43-7 1-Methyl-3-n-propylbenzene 1.731 1.484 1.137 490.089 106.904 105-05-5 1,4-Diethylbenzene 0.439 0.376 0.288 124.232 107.177 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.102 0.085 0.067 28.836 107.423 135-01-3 1,2-Diethylbenzene 0.128 0.107 0.084 36.211 108.027 1074-17-5 1-Methyl-2-n-propylbenzene 0.046 0.039 0.031 13.154 109.544 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.345 0.291 0.227 97.622 110.102 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.834 0.691 0.548 236.002 111.214 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.070 0.058 0.046 19.869 111.687 4218-48-8 1-Ethyl-4-i-propylbenzene 0.114 0.095 0.068 32.259 112.164 1,2,4,5-Tetramethylbenzene 0.242 0.201 0.159 68.488 112.430 527-53-7 1,2,3,5-Tetramethylbenzene 0.319 0.264 0.209 90.269 113.585 C11 - Aromatic - 3 0.029 0.024 0.017 8.230 113.901 1,2-Di-i-propylbenzene 0.043 0.036 0.023 12.053 114.117 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.058 0.048 0.034 16.342 114.293 C11 - Aromatic - 4 0.037 0.030 0.022 10.358 115.090 538-68-1 n-Pentylbenzene 0.014 0.012 0.009 4.060 115.320 tert-Pentylbenzene 0.053 0.044 0.032 15.033 115.633 577-55-9 1-Methyl-2-n-butylbenzene 0.027 0.022 0.016 7.536 115.744 C11 - Aromatic - 7 0.042 0.036 0.025 11.771 116.206 100-18-5 1,4-Di-i-propylbenzene 0.048 0.040 0.026 13.409 117.432 7364-19-4 1t-Butyl-4-ethylbenzene 0.015 0.013 0.008 4.263

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 117.735 1,3-Di-n-propylbenzene 0.034 0.028 0.019 9.625

117.847 C11 - Aromatic - 11 0.018 0.016 0.011 5.154 118.402 C11 - Aromatic - 12 0.012 0.011 0.007 3.456

Naphthalenes 116.635 91-20-3 Naphthalene 0.086 0.062 0.059 25.500

123.281 91-57-6 2-Methylnaphthalene 0.012 0.009 0.007 3.554 124.145 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.616

Naphtheno/Olefino-Benzs

113.761 874-35-1 5-Methylindan 0.097 0.080 0.065 27.430 114.765 824-63-5 2-Methylindan 0.097 0.081 0.065 27.522

Indenes 104.808 Indan 0.184 0.141 0.137 53.261

105.442 Indene 1.660 1.270 1.238 480.056 109.206 2-Methylindan 0.153 0.117 0.102 44.354 114.514 824-22-6 4-Methylindan 0.123 0.102 0.082 34.770 116.797 4,7-Dimethyl Indane 0.016 0.013 0.010 4.756 117.080 1,1-Dimethyl Indane 0.011 0.009 0.007 3.301

Naphthenes Mono-Naphthenes 27.097 287-92-3 Cyclopentane 0.134 0.133 0.168 36.306

40.153 96-37-7 Methylcyclopentane 1.672 1.648 1.751 452.929 47.050 110-82-7 Cyclohexane 1.039 0.985 1.088 281.457 52.879 1759-58-6 1t,3-Dimethylcyclopentane 0.116 0.115 0.104 31.489 53.466 2532-58-3 1c,3-Dimethylcyclopentane 0.080 0.080 0.072 21.787 54.096 822-50-4 1t,2-Dimethylcyclopentane 0.094 0.093 0.085 25.565 59.200 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.019 0.018 0.017 5.035 61.051 108-87-2 Methylcyclohexane 0.089 0.085 0.080 24.121 93.138 696-29-7 1-Methyl-2-propyl-cyclopentan 0.004 0.004 0.003 1.142 101.324 1678-98-4 i-Butylcyclohexane 0.059 0.055 0.037 16.027 105.856 n-ButylCyclohexane 0.002 0.002 0.001 0.589

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.404 115-11-7 Isobutene 0.015 0.019 0.024 4.181

9.442 106-98-9 Butene-1 0.019 0.023 0.029 5.037 10.265 624-64-6 t-Butene-2 0.073 0.089 0.114 19.651 10.986 590-18-1 c-Butene-2 0.086 0.102 0.135 23.193 16.329 109-67-1 Pentene-1 0.332 0.382 0.417 89.856 18.796 646-04-8 t-Pentene-2 0.843 0.959 1.059 228.284 19.820 627-20-3 c-Pentene-2 0.463 0.521 0.581 125.316 32.943 592-41-6 Hexene-1 1.605 1.747 1.682 434.942 35.934 13269-52-8 t-Hexene-3 0.269 0.291 0.282 72.948 36.403 4050-45-7 t-Hexene-2 0.510 0.551 0.534 138.223 38.230 7688-21-3 c-Hexene-2 0.216 0.231 0.227 58.623 55.019 592-76-7 Heptene-1 0.030 0.032 0.027 8.231 56.878 14686-14-7 t-Heptene-3 0.033 0.034 0.029 8.876 57.831 7642-10-6 c-Heptene-3 0.025 0.026 0.023 6.797

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 58.740 14686-13-6 t-Heptene-2 0.016 0.017 0.014 4.353

110.730 693-61-8 2-Undecene, (E)- 0.075 0.074 0.047 19.997

Iso-Olefins 13.121 563-45-1 3-Methylbutene-1 0.258 0.303 0.324 69.877

17.170 563-46-2 2-Methylbutene-1 0.504 0.571 0.633 136.420 20.489 513-35-9 2-Methylbutene-2 1.037 1.155 1.304 280.960 28.688 691-38-3 4-Methyl-c-pentene-2 0.043 0.047 0.045 11.722 29.333 674-76-0 4-Methyl-t-pentene-2 0.131 0.144 0.137 35.501 32.719 763-29-1 2-Methylpentene-1 0.224 0.241 0.235 60.708 36.896 625-27-4 2-Methylpentene-2 0.345 0.368 0.361 93.457 37.312 922-62-3 3-Methyl-c-pentene-2 0.269 0.285 0.282 72.981 39.580 3404-73-7 3,3-Dimethylpentene-1 0.318 0.334 0.286 86.204 42.032 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.014 0.012 3.663 46.159 3404-61-3 3-Methylhexene-1 0.016 0.017 0.014 4.268 46.742 3524-73-0 5-Methylhexene-1 0.063 0.067 0.057 17.127 48.800 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.037 11.222 49.146 3769-23-1 4-Methylhexene-1 0.011 0.011 0.010 2.927 49.791 3404-55-5 4-Methyl-t/c-hexene-2 0.053 0.055 0.047 14.243 54.418 C7 - Iso-Olefin - 2 0.023 0.024 0.021 6.216 56.355 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.013 3.864 57.239 6094-02-6 2-Methylhexene-1 0.058 0.062 0.052 15.835 58.110 2738-19-4 2-Methyl-2-hexene 0.026 0.027 0.024 7.119 58.355 3899-36-3 3-Methyl-t-hexene-3 0.020 0.021 0.018 5.432 59.641 20710-38-8 3-Methyl-t-hexene-2 0.016 0.016 0.014 4.306 60.425 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.017 0.017 0.015 4.615 93.138 C10-IsoOlefin-4 0.004 0.004 0.003 1.142

Naphtheno-Olefins 25.246 142-29-0 Cyclopentene 0.197 0.188 0.255 54.978

45.334 693-89-0 1-Methylcyclopentene 0.370 0.350 0.397 102.706 50.669 110-83-8 Cyclohexene 0.046 0.042 0.049 12.422

Di-Olefins 18.200 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.910

20.818 2004-70-8 1t,3-Pentadiene 0.015 0.017 0.020 4.247

Oxygenates 12.745 64-17-5 Ethanol 9.506 8.889 18.193 1107.028

26.486 71-23-8 n-Propanol 0.182 0.168 0.267 34.488

Unidentified 22.065 Unidentified 0.006 0.006 0.008 1.914

28.236 Unidentified 0.050 0.050 0.050 16.756 44.929 Unidentified 0.012 0.012 0.013 3.921 47.593 Unidentified 0.035 0.037 0.032 11.652 63.108 Unidentified 0.019 0.020 0.015 6.363 72.092 Unidentified 0.054 0.055 0.041 17.834 75.907 Unidentified 0.009 0.008 0.006 2.826 78.506 Unidentified 0.026 0.026 0.018 8.529 84.617 Unidentified 0.012 0.012 0.008 3.921 84.859 Unidentified 0.010 0.009 0.007 3.248

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 85.963 Unidentified 0.026 0.026 0.018 8.624

88.479 Unidentified 0.048 0.052 0.034 15.974 92.085 Unidentified 0.011 0.010 0.007 3.546 93.028 Unidentified 0.011 0.010 0.008 3.580 93.028 Unidentified 0.011 0.011 0.007 3.580 93.028 Unidentified 0.011 0.008 0.007 3.580 93.602 Unidentified 0.159 0.162 0.099 52.853 94.267 Unidentified 0.022 0.016 1.949 7.338 94.267 Unidentified 0.022 0.023 0.014 7.338 94.487 Unidentified 0.021 0.019 0.015 6.923 95.019 Unidentified 0.021 0.021 0.013 6.923 99.475 Unidentified 0.012 0.012 0.007 3.902 99.841 Unidentified 0.011 0.011 0.007 3.552 100.131 Unidentified 0.222 0.164 0.125 73.829 100.258 Unidentified 0.622 0.617 0.351 206.582 100.946 Unidentified 0.372 0.391 0.234 123.449 101.068 Unidentified 0.220 0.222 0.137 73.129 101.969 Unidentified 0.025 0.023 0.016 8.214 102.323 Unidentified 0.140 0.121 0.092 46.622 102.465 Unidentified 0.331 0.286 0.217 109.800 102.976 Unidentified 0.146 0.145 0.082 48.425 103.468 Unidentified 0.017 0.014 0.013 5.658 104.398 Unidentified 0.325 0.280 0.213 107.836 105.995 Unidentified 0.013 0.012 0.008 4.456 107.890 Unidentified 0.140 0.139 0.079 46.418 108.164 Unidentified 0.138 0.137 0.079 45.652 108.245 Unidentified 0.126 0.125 0.071 41.797 108.550 Unidentified 0.328 0.326 0.185 109.027 108.983 Unidentified 0.928 0.781 0.610 308.045 109.703 Unidentified 0.066 0.050 0.044 21.863 110.528 Unidentified 0.034 0.031 0.019 11.232 110.858 Unidentified 0.161 0.160 0.101 53.348 111.131 Unidentified 0.143 0.124 0.085 47.335 111.798 Unidentified 0.080 0.066 0.048 26.517 112.654 Unidentified 0.015 0.012 0.009 4.881 112.784 Unidentified 0.022 0.018 0.015 7.391 113.294 Unidentified 0.036 0.036 0.019 11.991 113.448 Unidentified 0.014 0.014 0.007 4.649 113.654 Unidentified 0.040 0.033 0.024 13.292 114.682 Unidentified 0.028 0.023 0.017 9.294 114.978 Unidentified 0.012 0.010 0.007 4.092 116.972 Unidentified 0.006 0.005 0.003 1.841 125.444 Unidentified 0.003 0.003 0.002 1.118 126.172 Unidentified 0.006 0.005 0.003 2.120 126.172 Unidentified 0.006 0.005 0.003 2.120 126.172 Unidentified 0.006 0.006 0.003 2.120 129.864 Unidentified 0.003 0.003 0.002 1.106

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified Plus

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3 4-Methylhexene-1 4-Methyl-t/c-hexene-2

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified

3-Methylheptane

2,2,5-Trimethylhexane

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF95.090.085.080.075.0

Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane

2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane
Unidentified
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane Unidentified 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane 2,2,6-Trimethyloctane

1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane Unidentified

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified

C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane Unidentified Unidentified n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan C11-Isoparaffin-5 Indene n-ButylCyclohexane Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane Unidentified 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF Sample: ODDB-91313 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91313 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000009.D\SIG1000009_FID1_A.CDF145.0140.0135.0130.0125.0 Unidentified

Unidentified

Unidentified

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 11.444 12.660 13.176

I-Paraffins 47.226 50.315 45.963

Aromatics 23.314 19.187 20.473 Mono-Aromatics 22.309 18.420 19.717 Naphthalenes 0.099 0.069 0.071 Naphtheno/Olefino-Benzs 0.240 0.193 0.170 Indenes 0.666 0.504 0.514

Naphthenes 9.372 8.840 10.478 Mono-Naphthenes 9.372 8.840 10.478 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.522 6.949 8.098 n-Olefins 2.912 3.177 3.731 Iso-Olefins 3.065 3.267 3.697 Naphtheno-Olefins 0.523 0.482 0.640 Di-Olefins 0.021 0.022 0.029

Oxygenates 0.174 0.156 0.272

Unidentified 1.947 1.893 1.540

Plus 0.000 0.000 0.000

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.175 0.158 0.275 C4 0.719 0.879 1.175 C5 18.645 21.048 24.460 C6 24.413 25.345 26.918 C7 12.717 11.707 12.509 C8 27.374 26.719 22.917 C9 7.744 6.749 5.953 C10 5.363 4.708 3.701 C11 0.775 0.690 0.478 C12 0.128 0.103 0.074

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.002 C4 0.455 0.564 0.735 C5 3.315 3.800 4.315 C6 6.645 7.234 7.242 C7 0.582 0.611 0.546 C8 0.173 0.177 0.142 C9 0.192 0.192 0.141 C10 0.066 0.065 0.043 C11 0.016 0.015 0.010

I-Paraffins C4 0.032 0.041 0.052 C5 10.489 12.156 13.655 C6 8.513 9.287 9.278 C7 3.404 3.596 3.191 C8 20.493 20.961 16.850 C9 1.859 1.880 1.361 C10 2.046 2.017 1.342 C11 0.391 0.377 0.235

Mono-Aromatics C6 0.683 0.558 0.822 C7 6.716 5.561 6.846 C8 6.490 5.378 5.741 C9 5.555 4.575 4.341 C10 2.401 1.971 1.680 C11 0.335 0.274 0.212 C12 0.128 0.103 0.074

Naphthalenes C10 0.081 0.056 0.059 C11 0.018 0.013 0.012

Naphtheno/Olefino-Benzs C10 0.240 0.193 0.170

Indenes C9 0.138 0.103 0.110 C10 0.513 0.390 0.394 C11 0.015 0.011 0.010

Mono-Naphthenes C5 1.465 1.411 1.962 C6 6.166 5.792 6.882 C7 1.506 1.418 1.440 C8 0.218 0.203 0.183 C10 0.017 0.015 0.011

n-Olefins C4 0.232 0.274 0.389

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.585 1.754 2.123 C6 1.079 1.133 1.204 C7 0.016 0.016 0.015

Iso-Olefins C5 1.591 1.739 2.131 C6 0.981 1.023 1.095 C7 0.493 0.505 0.472

Naphtheno-Olefins C5 0.177 0.165 0.245 C6 0.346 0.317 0.396

Di-Olefins C5 0.021 0.022 0.029

Oxygenates C3 0.174 0.156 0.272

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 30.37 28.15 5% 80.03 79.82 10% 81.59 81.16 15% 96.32 94.14 20% 121.26 100.81 25% 140.51 138.19 30% 154.23 144.81 35% 155.31 154.54 40% 167.48 155.54 45% 177.35 176.43 50% 209.18 191.39 55% 209.80 209.34 60% 210.42 209.93 65% 230.75 210.53 70% 231.02 230.81 75% 237.03 232.66 80% 261.17 238.72 85% 281.92 279.02 90% 323.28 320.50 95% 345.33 335.88 FBP 403.15 390.91

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.390 74-98-6 P3 Propane 0.001 0.001 0.002 0.261 2 8.611 75-28-5 I4 i-Butane 0.032 0.041 0.052 8.316 3 9.404 115-11-7 K4 Isobutene 0.020 0.024 0.034 5.483 4 9.443 106-98-9 K4 Butene-1 0.024 0.029 0.040 6.413 5 9.792 106-97-8 P4 n-Butane 0.455 0.564 0.735 118.589 6 10.266 624-64-6 K4 t-Butene-2 0.088 0.105 0.148 23.854 7 10.388 463-82-1 I5 2,2-Dimethylpropane 0.045 0.055 0.059 11.868 8 10.987 590-18-1 K4 c-Butene-2 0.100 0.116 0.168 27.050 9 13.128 563-45-1 C5 3-Methylbutene-1 0.069 0.079 0.092 18.571 10 14.719 78-78-4 I5 i-Pentane 10.444 12.101 13.596 2743.138

11 16.335 109-67-1 K5 Pentene-1 0.317 0.356 0.425 85.773 12 17.168 563-46-2 C5 2-Methylbutene-1 0.497 0.549 0.666 134.306 13 17.701 109-66-0 P5 n-Pentane 3.315 3.800 4.315 870.648 14 18.206 78-79-5 E5 2-Methyl-1,3-Butadiene 0.009 0.009 0.012 2.388 15 18.801 646-04-8 K5 t-Pentene-2 0.820 0.908 1.098 221.406 16 19.824 627-20-3 K5 c-Pentene-2 0.448 0.491 0.600 121.087 17 20.489 513-35-9 C5 2-Methylbutene-2 1.025 1.111 1.373 276.986 18 20.825 2004-70-8 E5 1t,3-Pentadiene 0.012 0.013 0.017 3.464 19 22.615 75-83-2 I6 2,2-Dimethylbutane 0.615 0.680 0.670 162.169 20 25.243 142-29-0 B5 Cyclopentene 0.177 0.165 0.245 49.352

21 26.491 71-23-8 X3 n-Propanol 0.174 0.156 0.272 32.976 22 27.108 287-92-3 M5 Cyclopentane 1.465 1.411 1.962 395.865 23 27.829 79-29-8 I6 2,3-Dimethylbutane 0.972 1.055 1.060 256.443 24 28.230 ? Unidentified 0.050 0.049 0.053 16.558 25 28.689 691-38-3 C6 4-Methyl-c-pentene-2 0.043 0.045 0.048 11.528 26 28.913 107-83-5 I6 2-Methylpentane 3.670 4.034 4.000 967.867 27 29.337 674-76-0 C6 4-Methyl-t-pentene-2 0.129 0.137 0.144 34.767 28 31.556 96-14-0 I6 3-Methylpentane 3.255 3.517 3.547 858.234 29 32.715 763-29-1 C6 2-Methylpentene-1 0.220 0.230 0.245 59.344 30 32.937 592-41-6 K6 Hexene-1 0.149 0.158 0.167 40.364

31 35.323 110-54-3 P6 n-Hexane 6.645 7.234 7.242 1752.162 32 35.936 13269-52-8 K6 t-Hexene-3 0.251 0.265 0.281 67.927 33 36.408 4050-45-7 K6 t-Hexene-2 0.476 0.501 0.531 128.613 34 36.897 625-27-4 C6 2-Methylpentene-2 0.334 0.347 0.373 90.341 35 37.313 922-62-3 C6 3-Methyl-c-pentene-2 0.256 0.263 0.285 69.049 36 38.233 7688-21-3 K6 c-Hexene-2 0.202 0.210 0.226 54.614 37 39.584 3404-73-7 C7 3,3-Dimethylpentene-1 0.304 0.311 0.291 82.063 38 40.165 96-37-7 M6 Methylcyclopentane 2.886 2.768 3.221 779.767 39 41.733 108-08-7 I7 2,4-Dimethylpentane 0.700 0.746 0.656 185.196 40 42.273 464-06-2 I7 2,2,3-Trimethylbutane 0.088 0.092 0.083 23.332

41 45.136 71-42-3 Q6 Benzene 0.683 0.558 0.822 198.819 42 45.334 693-89-0 B6 1-Methylcyclopentene 0.313 0.288 0.358 86.500 43 46.164 3404-61-3 C7 3-Methylhexene-1 0.012 0.012 0.011 3.214

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 46.752 3524-73-0 C7 5-Methylhexene-1 0.088 0.091 0.084 23.815 45 47.067 110-82-7 M6 Cyclohexane 3.280 3.024 3.660 886.034 46 47.590 ? Unidentified 0.027 0.028 0.026 8.919 47 48.807 15840-60-5 C7 2-Methyl-c-hexene-3 0.030 0.031 0.029 8.066 48 49.797 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.035 0.036 0.033 9.433 49 50.199 591-76-4 I7 2-Methylhexane 1.862 1.969 1.745 492.861 50 50.670 110-83-8 B6 Cyclohexene 0.033 0.029 0.038 8.993 51 52.032 589-34-4 I7 3-Methylhexane 0.755 0.789 0.708 199.861 52 52.883 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.161 0.155 0.154 43.594 53 53.470 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.130 0.126 0.125 35.193

54 54.097 822-50-4 M7 1t,2-Dimethylcyclopentane 0.203 0.194 0.195 54.936 55 54.766 540-84-1 I8 2,2,4-Trimethylpentane 11.643 12.080 9.574 3088.711 56 56.884 14686-14-7 K7 t-Heptene-3 0.016 0.016 0.015 4.191 57 57.240 6094-02-6 C7 2-Methylhexene-1 0.024 0.025 0.023 6.589 58 57.617 142-82-5 P7 n-Heptane 0.582 0.611 0.546 154.096 59 59.432 ? Unidentified 0.459 0.458 0.439 151.754 60 61.062 108-87-2 M7 Methylcyclohexane 0.977 0.912 0.935 264.025 61 62.013 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.021 0.020 0.017 5.577 62 62.420 590-73-8 I8 2,2-Dimethylhexane 0.018 0.019 0.015 4.870 63 63.642 ? Unidentified 0.123 0.118 0.105 40.622

64 63.857 1640-89-7 M7 Ethylcyclopentane 0.033 0.031 0.032 8.981 65 64.510 ? Unidentified 0.321 0.322 0.264 106.239 66 64.754 592-13-2 I8 2,5-Dimethylhexane 0.971 1.005 0.798 257.600 67 65.092 589-43-5 I8 2,4-Dimethylhexane 0.846 0.868 0.696 224.550 68 65.926 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.019 0.017 0.015 5.002 69 67.456 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.015 0.014 0.012 3.928 70 68.096 565-75-3 I8 2,3,4-Trimethylpentane 2.888 2.883 2.375 766.099 71 68.634 108-88-3 Q7 Toluene 6.716 5.561 6.846 1932.795 72 68.773 560-21-4 I8 2,3,3-Trimethylpentane 2.982 2.948 2.452 791.102 73 70.428 584-94-1 I8 2,3-Dimethylhexane 0.740 0.746 0.609 196.347

74 71.695 592-27-8 I8 2-Methylheptane 0.123 0.127 0.101 32.635 75 71.958 589-53-7 I8 4-Methylheptane 0.113 0.115 0.093 29.883 76 72.091 ? Unidentified 0.059 0.059 0.048 19.489 77 72.860 M8 1,3-dimethyl-t-cyclohexane 0.086 0.080 0.072 23.209 78 73.019 589-81-1 I8 3-Methylheptane 0.112 0.113 0.092 29.592 79 73.203 619-99-8 I8 3-Ethylhexane 0.056 0.057 0.046 14.916 80 74.102 ? Unidentified 0.013 0.012 0.011 4.428 81 74.927 3522-94-9 I9 2,2,5-Trimethylhexane 1.370 1.391 1.004 364.251 82 75.904 ? Unidentified 0.010 0.010 0.007 3.365 83 76.189 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.035 0.032 0.029 9.362

84 77.562 111-65-9 P8 n-Octane 0.173 0.177 0.142 45.940 85 78.506 ? Unidentified 0.035 0.033 0.030 11.721 86 80.054 1069-53-0 I9 2,3,5-Trimethylhexane 0.233 0.232 0.171 61.917

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 81.232 1071-26-7 I9 2,4-Dimethylheptane 0.037 0.038 0.027 9.960 88 81.867 1678-91-7 M8 Ethylcyclohexane 0.044 0.040 0.037 11.911 89 82.193 1072-05-5 I9 2,6-Dimethylheptane 0.051 0.052 0.038 13.683 90 82.672 ? Unidentified 0.008 0.007 0.007 2.581 91 83.127 I9 2,5-Dimethylheptane 0.114 0.114 0.083 30.182 92 84.439 100-41-4 Q8 Ethylbenzene 1.230 1.018 1.088 351.186 93 84.858 ? Unidentified 0.018 0.017 0.013 5.985 94 85.671 108-38-3 Q8 m-Xylene 2.930 2.434 2.592 836.731 95 85.819 106-42-3 Q8 p-Xylene 1.400 1.167 1.238 399.740 96 86.326 ? Unidentified 0.015 0.015 0.011 4.852

97 87.013 2216-34-4 I9 4-Methyloctane 0.014 0.014 0.010 3.801 98 87.146 3221-61-2 I9 2-Methyloctane 0.019 0.019 0.014 5.133 99 88.011 2216-33-3 I9 3-Methyloctane 0.020 0.019 0.014 5.192 100 88.478 ? Unidentified 0.082 0.086 0.061 27.065 101 88.651 95-47-6 Q8 o-Xylene 0.931 0.759 0.823 265.782 102 89.065 I10 C10 - IsoParaffin - 1 0.274 0.271 0.181 73.080 103 89.912 14720-74-2 I10 2,2,4-trimethylheptane 0.197 0.194 0.130 52.342 104 91.465 111-84-2 P9 n-Nonane 0.192 0.192 0.141 51.004 105 92.836 98-82-8 Q9 i-Propylbenzene 0.031 0.026 0.024 8.887 106 93.028 ? Unidentified 0.014 0.013 0.010 4.670

107 93.028 ? Unidentified 0.014 0.014 0.009 4.670 108 93.028 ? Unidentified 0.014 0.010 0.009 4.670 109 93.600 ? Unidentified 0.099 0.098 0.065 32.754 110 93.823 15869-87-1 I10 2,2-Dimethyloctane 0.033 0.033 0.022 8.823 111 94.623 15869-89-3 I10 2,5-Dimethyloctane 0.032 0.031 0.021 8.489 112 95.099 2040-95-1 I10 2,7-Dimethyloctane 0.019 0.018 0.012 4.952 113 95.265 2051-30-1 I10 2,4-Dimethyloctane 0.087 0.086 0.057 23.138 114 95.659 I10 2,6-Dimethyloctane 0.029 0.029 0.019 7.772 115 96.304 103-65-1 Q9 n-Propylbenzene 0.276 0.230 0.216 78.426 116 97.153 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.074 0.892 0.840 304.872

117 97.387 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.513 0.428 0.401 145.593 118 98.014 108-67-8 Q9 1,3,5-Trimethylbenzene 0.709 0.589 0.554 201.264 119 98.684 17301-94-8 I10 4-Methylnonane 0.011 0.011 0.007 2.958 120 98.887 I10 2,2,6-Trimethyloctane 1.203 1.188 0.794 320.293 121 99.098 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.417 0.340 0.325 118.194 122 99.660 5911-04-6 I10 3-Methylnonane 0.015 0.015 0.010 4.023 123 100.127 ? Unidentified 0.063 0.045 0.038 20.795 124 100.252 ? Unidentified 0.177 0.171 0.107 58.693 125 100.476 I11 C11-Isoparaffin-2 0.092 0.089 0.056 24.662 126 100.737 95-63-6 Q9 1,2,4-Trimethylbenzene 2.152 1.764 1.681 610.516

127 100.941 ? Unidentified 0.103 0.105 0.069 34.022 128 101.062 ? Unidentified 0.061 0.060 0.040 20.207 129 101.319 1678-98-4 M10 i-Butylcyclohexane 0.017 0.015 0.011 4.544

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 102.107 17302-01-1 I10 3-Ethyl-3-methylheptane 0.147 0.142 0.088 39.105 131 102.454 538-93-2 Q10 i-Butylbenzene 0.162 0.136 0.113 45.695 132 102.656 124-18-5 P10 n-Decane 0.066 0.065 0.043 17.520 133 102.974 ? Unidentified 0.032 0.031 0.019 10.714 134 103.610 526-73-8 Q9 1,2,3-Trimethylbenzene 0.382 0.307 0.299 108.469 135 103.997 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.017 0.014 0.012 4.874 136 104.190 I11 C11 Isoparaffin-4 0.015 0.014 0.009 3.998 137 104.393 ? Unidentified 0.069 0.058 0.048 22.878 138 104.800 J9 Indan 0.138 0.103 0.110 39.897 139 105.428 J10 Indene 0.358 0.266 0.284 103.114

140 106.145 I11 C11-Isoparaffin-7 0.111 0.107 0.067 29.611 141 106.330 141-93-5 Q10 1,3-Diethylbenzene 0.052 0.043 0.037 14.730 142 106.614 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.436 0.364 0.305 123.082 143 106.947 105-05-5 Q10 1,4-Diethylbenzene 0.174 0.145 0.122 49.151 144 107.172 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.143 0.116 0.100 40.294 145 107.440 135-01-3 Q10 1,2-Diethylbenzene 0.027 0.022 0.019 7.499 146 107.884 ? Unidentified 0.017 0.017 0.010 5.756 147 108.023 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.054 0.044 0.038 15.164 148 108.362 I11 C11- Isoparaffin-11 0.172 0.166 0.103 45.876 149 108.548 ? Unidentified 0.036 0.035 0.022 11.972

150 108.875 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.120 0.098 0.084 33.898 151 109.032 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.208 0.171 0.146 58.813 152 109.197 J10 2-Methylindan 0.019 0.014 0.014 5.522 153 109.542 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.275 0.226 0.192 77.546 154 110.097 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.075 0.061 0.053 21.236 155 111.009 Q11 1-Methyl-4-t-butylbenzene 0.020 0.017 0.013 5.753 156 111.219 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.098 0.079 0.068 27.607 157 111.525 1120-21-4 P11 n-Undecane 0.016 0.015 0.010 4.243 158 111.689 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.012 0.010 0.008 3.383 159 112.160 Q10 1,2,4,5-Tetramethylbenzene 0.232 0.188 0.162 65.445

160 112.427 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.329 0.265 0.230 92.747 161 113.289 ? Unidentified 0.009 0.009 0.005 3.017 162 113.581 Q11 C11 - Aromatic - 3 0.042 0.034 0.027 11.936 163 113.761 874-35-1 H10 5-Methylindan 0.098 0.079 0.069 27.578 164 113.901 Q12 1,2-Di-i-propylbenzene 0.042 0.034 0.024 11.683 165 114.115 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.060 0.048 0.038 16.861 166 114.275 Q11 C11 - Aromatic - 4 0.030 0.024 0.019 8.505 167 114.512 824-22-6 J10 4-Methylindan 0.136 0.110 0.097 38.420 168 114.763 824-63-5 H10 2-Methylindan 0.142 0.115 0.101 40.068 169 114.977 ? Unidentified 0.011 0.009 0.007 3.521

170 115.089 538-68-1 Q11 n-Pentylbenzene 0.015 0.012 0.009 4.099 171 115.321 Q11 tert-Pentylbenzene 0.060 0.049 0.038 16.961 172 115.631 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.026 0.021 0.016 7.304

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 115.741 Q11 C11 - Aromatic - 7 0.034 0.029 0.022 9.625 174 116.204 100-18-5 Q12 1,4-Di-i-propylbenzene 0.048 0.038 0.028 13.326 175 116.631 91-20-3 G10 Naphthalene 0.081 0.056 0.059 23.838 176 116.801 ? Unidentified 0.008 0.006 0.005 2.530 177 117.080 J11 1,1-Dimethyl Indane 0.015 0.011 0.010 4.275 178 117.734 Q12 1,3-Di-n-propylbenzene 0.039 0.031 0.023 10.934 179 117.845 Q11 C11 - Aromatic - 11 0.021 0.018 0.014 6.036 180 118.400 Q11 C11 - Aromatic - 12 0.013 0.011 0.008 3.740 181 123.280 91-57-6 G11 2-Methylnaphthalene 0.012 0.009 0.008 3.622 182 124.145 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.004 1.781

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.390 74-98-6 Propane 0.001 0.001 0.002 0.261

9.792 106-97-8 n-Butane 0.455 0.564 0.735 118.589 17.701 109-66-0 n-Pentane 3.315 3.800 4.315 870.648 35.323 110-54-3 n-Hexane 6.645 7.234 7.242 1752.162 57.617 142-82-5 n-Heptane 0.582 0.611 0.546 154.096 77.562 111-65-9 n-Octane 0.173 0.177 0.142 45.940 91.465 111-84-2 n-Nonane 0.192 0.192 0.141 51.004 102.656 124-18-5 n-Decane 0.066 0.065 0.043 17.520 111.525 1120-21-4 n-Undecane 0.016 0.015 0.010 4.243

I-Paraffins 8.611 75-28-5 i-Butane 0.032 0.041 0.052 8.316

10.388 463-82-1 2,2-Dimethylpropane 0.045 0.055 0.059 11.868 14.719 78-78-4 i-Pentane 10.444 12.101 13.596 2743.138 22.615 75-83-2 2,2-Dimethylbutane 0.615 0.680 0.670 162.169 27.829 79-29-8 2,3-Dimethylbutane 0.972 1.055 1.060 256.443 28.913 107-83-5 2-Methylpentane 3.670 4.034 4.000 967.867 31.556 96-14-0 3-Methylpentane 3.255 3.517 3.547 858.234 41.733 108-08-7 2,4-Dimethylpentane 0.700 0.746 0.656 185.196 42.273 464-06-2 2,2,3-Trimethylbutane 0.088 0.092 0.083 23.332 50.199 591-76-4 2-Methylhexane 1.862 1.969 1.745 492.861 52.032 589-34-4 3-Methylhexane 0.755 0.789 0.708 199.861 54.766 540-84-1 2,2,4-Trimethylpentane 11.643 12.080 9.574 3088.711 62.420 590-73-8 2,2-Dimethylhexane 0.018 0.019 0.015 4.870 64.754 592-13-2 2,5-Dimethylhexane 0.971 1.005 0.798 257.600 65.092 589-43-5 2,4-Dimethylhexane 0.846 0.868 0.696 224.550 68.096 565-75-3 2,3,4-Trimethylpentane 2.888 2.883 2.375 766.099 68.773 560-21-4 2,3,3-Trimethylpentane 2.982 2.948 2.452 791.102 70.428 584-94-1 2,3-Dimethylhexane 0.740 0.746 0.609 196.347 71.695 592-27-8 2-Methylheptane 0.123 0.127 0.101 32.635 71.958 589-53-7 4-Methylheptane 0.113 0.115 0.093 29.883 73.019 589-81-1 3-Methylheptane 0.112 0.113 0.092 29.592 73.203 619-99-8 3-Ethylhexane 0.056 0.057 0.046 14.916 74.927 3522-94-9 2,2,5-Trimethylhexane 1.370 1.391 1.004 364.251 80.054 1069-53-0 2,3,5-Trimethylhexane 0.233 0.232 0.171 61.917 81.232 1071-26-7 2,4-Dimethylheptane 0.037 0.038 0.027 9.960 82.193 1072-05-5 2,6-Dimethylheptane 0.051 0.052 0.038 13.683 83.127 2,5-Dimethylheptane 0.114 0.114 0.083 30.182 87.013 2216-34-4 4-Methyloctane 0.014 0.014 0.010 3.801 87.146 3221-61-2 2-Methyloctane 0.019 0.019 0.014 5.133 88.011 2216-33-3 3-Methyloctane 0.020 0.019 0.014 5.192 89.065 C10 - IsoParaffin - 1 0.274 0.271 0.181 73.080 89.912 14720-74-2 2,2,4-trimethylheptane 0.197 0.194 0.130 52.342 93.823 15869-87-1 2,2-Dimethyloctane 0.033 0.033 0.022 8.823 94.623 15869-89-3 2,5-Dimethyloctane 0.032 0.031 0.021 8.489 95.099 2040-95-1 2,7-Dimethyloctane 0.019 0.018 0.012 4.952 95.265 2051-30-1 2,4-Dimethyloctane 0.087 0.086 0.057 23.138 95.659 2,6-Dimethyloctane 0.029 0.029 0.019 7.772

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 98.684 17301-94-8 4-Methylnonane 0.011 0.011 0.007 2.958

98.887 2,2,6-Trimethyloctane 1.203 1.188 0.794 320.293 99.660 5911-04-6 3-Methylnonane 0.015 0.015 0.010 4.023 100.476 C11-Isoparaffin-2 0.092 0.089 0.056 24.662 102.107 17302-01-1 3-Ethyl-3-methylheptane 0.147 0.142 0.088 39.105 104.190 C11 Isoparaffin-4 0.015 0.014 0.009 3.998 106.145 C11-Isoparaffin-7 0.111 0.107 0.067 29.611 108.362 C11- Isoparaffin-11 0.172 0.166 0.103 45.876

Aromatics Mono-Aromatics 45.136 71-42-3 Benzene 0.683 0.558 0.822 198.819

68.634 108-88-3 Toluene 6.716 5.561 6.846 1932.795 84.439 100-41-4 Ethylbenzene 1.230 1.018 1.088 351.186 85.671 108-38-3 m-Xylene 2.930 2.434 2.592 836.731 85.819 106-42-3 p-Xylene 1.400 1.167 1.238 399.740 88.651 95-47-6 o-Xylene 0.931 0.759 0.823 265.782 92.836 98-82-8 i-Propylbenzene 0.031 0.026 0.024 8.887 96.304 103-65-1 n-Propylbenzene 0.276 0.230 0.216 78.426 97.153 620-14-4 1-Methyl-3-ethylbenzene 1.074 0.892 0.840 304.872 97.387 622-96-8 1-Methyl-4-ethylbenzene 0.513 0.428 0.401 145.593 98.014 108-67-8 1,3,5-Trimethylbenzene 0.709 0.589 0.554 201.264 99.098 611-14-3 1-Methyl-2-ethylbenzene 0.417 0.340 0.325 118.194 100.737 95-63-6 1,2,4-Trimethylbenzene 2.152 1.764 1.681 610.516 102.454 538-93-2 i-Butylbenzene 0.162 0.136 0.113 45.695 103.610 526-73-8 1,2,3-Trimethylbenzene 0.382 0.307 0.299 108.469 103.997 535-77-3 1-Methyl-3-i-propylbenzene 0.017 0.014 0.012 4.874 106.330 141-93-5 1,3-Diethylbenzene 0.052 0.043 0.037 14.730 106.614 1074-43-7 1-Methyl-3-n-propylbenzene 0.436 0.364 0.305 123.082 106.947 105-05-5 1,4-Diethylbenzene 0.174 0.145 0.122 49.151 107.172 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.143 0.116 0.100 40.294 107.440 135-01-3 1,2-Diethylbenzene 0.027 0.022 0.019 7.499 108.023 1074-17-5 1-Methyl-2-n-propylbenzene 0.054 0.044 0.038 15.164 108.875 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.120 0.098 0.084 33.898 109.032 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.208 0.171 0.146 58.813 109.542 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.275 0.226 0.192 77.546 110.097 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.075 0.061 0.053 21.236 111.009 1-Methyl-4-t-butylbenzene 0.020 0.017 0.013 5.753 111.219 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.098 0.079 0.068 27.607 111.689 4218-48-8 1-Ethyl-4-i-propylbenzene 0.012 0.010 0.008 3.383 112.160 1,2,4,5-Tetramethylbenzene 0.232 0.188 0.162 65.445 112.427 527-53-7 1,2,3,5-Tetramethylbenzene 0.329 0.265 0.230 92.747 113.581 C11 - Aromatic - 3 0.042 0.034 0.027 11.936 113.901 1,2-Di-i-propylbenzene 0.042 0.034 0.024 11.683 114.115 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.060 0.048 0.038 16.861 114.275 C11 - Aromatic - 4 0.030 0.024 0.019 8.505 115.089 538-68-1 n-Pentylbenzene 0.015 0.012 0.009 4.099 115.321 tert-Pentylbenzene 0.060 0.049 0.038 16.961

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.631 577-55-9 1-Methyl-2-n-butylbenzene 0.026 0.021 0.016 7.304

115.741 C11 - Aromatic - 7 0.034 0.029 0.022 9.625 116.204 100-18-5 1,4-Di-i-propylbenzene 0.048 0.038 0.028 13.326 117.734 1,3-Di-n-propylbenzene 0.039 0.031 0.023 10.934 117.845 C11 - Aromatic - 11 0.021 0.018 0.014 6.036 118.400 C11 - Aromatic - 12 0.013 0.011 0.008 3.740

Naphthalenes 116.631 91-20-3 Naphthalene 0.081 0.056 0.059 23.838

123.280 91-57-6 2-Methylnaphthalene 0.012 0.009 0.008 3.622 124.145 90-12-0 1-Methylnaphthalene 0.006 0.004 0.004 1.781

Naphtheno/Olefino-Benzs

113.761 874-35-1 5-Methylindan 0.098 0.079 0.069 27.578 114.763 824-63-5 2-Methylindan 0.142 0.115 0.101 40.068

Indenes 104.800 Indan 0.138 0.103 0.110 39.897

105.428 Indene 0.358 0.266 0.284 103.114 109.197 2-Methylindan 0.019 0.014 0.014 5.522 114.512 824-22-6 4-Methylindan 0.136 0.110 0.097 38.420 117.080 1,1-Dimethyl Indane 0.015 0.011 0.010 4.275

Naphthenes Mono-Naphthenes 27.108 287-92-3 Cyclopentane 1.465 1.411 1.962 395.865

40.165 96-37-7 Methylcyclopentane 2.886 2.768 3.221 779.767 47.067 110-82-7 Cyclohexane 3.280 3.024 3.660 886.034 52.883 1759-58-6 1t,3-Dimethylcyclopentane 0.161 0.155 0.154 43.594 53.470 2532-58-3 1c,3-Dimethylcyclopentane 0.130 0.126 0.125 35.193 54.097 822-50-4 1t,2-Dimethylcyclopentane 0.203 0.194 0.195 54.936 61.062 108-87-2 Methylcyclohexane 0.977 0.912 0.935 264.025 62.013 4516-69-2 1,1,3-Trimethylcyclopentane 0.021 0.020 0.017 5.577 63.857 1640-89-7 Ethylcyclopentane 0.033 0.031 0.032 8.981 65.926 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.019 0.017 0.015 5.002 67.456 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.015 0.014 0.012 3.928 72.860 1,3-dimethyl-t-cyclohexane 0.086 0.080 0.072 23.209 76.189 2207-03-6 1t,3-Dimethylcyclohexane 0.035 0.032 0.029 9.362 81.867 1678-91-7 Ethylcyclohexane 0.044 0.040 0.037 11.911 101.319 1678-98-4 i-Butylcyclohexane 0.017 0.015 0.011 4.544

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.404 115-11-7 Isobutene 0.020 0.024 0.034 5.483

9.443 106-98-9 Butene-1 0.024 0.029 0.040 6.413 10.266 624-64-6 t-Butene-2 0.088 0.105 0.148 23.854 10.987 590-18-1 c-Butene-2 0.100 0.116 0.168 27.050 16.335 109-67-1 Pentene-1 0.317 0.356 0.425 85.773 18.801 646-04-8 t-Pentene-2 0.820 0.908 1.098 221.406 19.824 627-20-3 c-Pentene-2 0.448 0.491 0.600 121.087 32.937 592-41-6 Hexene-1 0.149 0.158 0.167 40.364

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 35.936 13269-52-8 t-Hexene-3 0.251 0.265 0.281 67.927

36.408 4050-45-7 t-Hexene-2 0.476 0.501 0.531 128.613 38.233 7688-21-3 c-Hexene-2 0.202 0.210 0.226 54.614 56.884 14686-14-7 t-Heptene-3 0.016 0.016 0.015 4.191

Iso-Olefins 13.128 563-45-1 3-Methylbutene-1 0.069 0.079 0.092 18.571

17.168 563-46-2 2-Methylbutene-1 0.497 0.549 0.666 134.306 20.489 513-35-9 2-Methylbutene-2 1.025 1.111 1.373 276.986 28.689 691-38-3 4-Methyl-c-pentene-2 0.043 0.045 0.048 11.528 29.337 674-76-0 4-Methyl-t-pentene-2 0.129 0.137 0.144 34.767 32.715 763-29-1 2-Methylpentene-1 0.220 0.230 0.245 59.344 36.897 625-27-4 2-Methylpentene-2 0.334 0.347 0.373 90.341 37.313 922-62-3 3-Methyl-c-pentene-2 0.256 0.263 0.285 69.049 39.584 3404-73-7 3,3-Dimethylpentene-1 0.304 0.311 0.291 82.063 46.164 3404-61-3 3-Methylhexene-1 0.012 0.012 0.011 3.214 46.752 3524-73-0 5-Methylhexene-1 0.088 0.091 0.084 23.815 48.807 15840-60-5 2-Methyl-c-hexene-3 0.030 0.031 0.029 8.066 49.797 3404-55-5 4-Methyl-t/c-hexene-2 0.035 0.036 0.033 9.433 57.240 6094-02-6 2-Methylhexene-1 0.024 0.025 0.023 6.589

Naphtheno-Olefins 25.243 142-29-0 Cyclopentene 0.177 0.165 0.245 49.352

45.334 693-89-0 1-Methylcyclopentene 0.313 0.288 0.358 86.500 50.670 110-83-8 Cyclohexene 0.033 0.029 0.038 8.993

Di-Olefins 18.206 78-79-5 2-Methyl-1,3-Butadiene 0.009 0.009 0.012 2.388

20.825 2004-70-8 1t,3-Pentadiene 0.012 0.013 0.017 3.464

Oxygenates 26.491 71-23-8 n-Propanol 0.174 0.156 0.272 32.976

Unidentified 28.230 Unidentified 0.050 0.049 0.053 16.558

47.590 Unidentified 0.027 0.028 0.026 8.919 59.432 Unidentified 0.459 0.458 0.439 151.754 63.642 Unidentified 0.123 0.118 0.105 40.622 64.510 Unidentified 0.321 0.322 0.264 106.239 72.091 Unidentified 0.059 0.059 0.048 19.489 74.102 Unidentified 0.013 0.012 0.011 4.428 75.904 Unidentified 0.010 0.010 0.007 3.365 78.506 Unidentified 0.035 0.033 0.030 11.721 82.672 Unidentified 0.008 0.007 0.007 2.581 84.858 Unidentified 0.018 0.017 0.013 5.985 86.326 Unidentified 0.015 0.015 0.011 4.852 88.478 Unidentified 0.082 0.086 0.061 27.065 93.028 Unidentified 0.014 0.013 0.010 4.670 93.028 Unidentified 0.014 0.014 0.009 4.670 93.028 Unidentified 0.014 0.010 0.009 4.670 93.600 Unidentified 0.099 0.098 0.065 32.754 100.127 Unidentified 0.063 0.045 0.038 20.795

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 100.252 Unidentified 0.177 0.171 0.107 58.693

100.941 Unidentified 0.103 0.105 0.069 34.022 101.062 Unidentified 0.061 0.060 0.040 20.207 102.974 Unidentified 0.032 0.031 0.019 10.714 104.393 Unidentified 0.069 0.058 0.048 22.878 107.884 Unidentified 0.017 0.017 0.010 5.756 108.548 Unidentified 0.036 0.035 0.022 11.972 113.289 Unidentified 0.009 0.009 0.005 3.017 114.977 Unidentified 0.011 0.009 0.007 3.521 116.801 Unidentified 0.008 0.006 0.005 2.530

Plus

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

2,2-Dimethylbutane

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane 2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,2,3-Trimethylbutane

Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane

Unidentified

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Unidentified Ethylcyclopentane
Unidentified 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane

1t,2c,3-Trimethylcyclopentane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

2,2,5-Trimethylhexane

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF95.090.085.080.075.0

Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane

Ethylbenzene Unidentified
m-Xylene

p-Xylene Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene Unidentified Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane

2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF Sample: ODDB-91314 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91314 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000010.D\SIG1000010_FID1_A.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 12.781 15.058 18.346

I-Paraffins 51.591 53.212 46.296

Aromatics 22.030 18.057 19.486 Mono-Aromatics 20.939 17.229 18.645 Naphthalenes 0.074 0.052 0.054 Naphtheno/Olefino-Benzs 0.209 0.168 0.151 Indenes 0.807 0.608 0.635

Naphthenes 3.670 3.454 4.023 Mono-Naphthenes 3.670 3.454 4.023 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.545 6.950 8.255 n-Olefins 2.929 3.185 3.814 Iso-Olefins 3.070 3.260 3.760 Naphtheno-Olefins 0.525 0.482 0.653 Di-Olefins 0.021 0.022 0.029

Oxygenates 0.176 0.157 0.279

Unidentified 3.207 3.112 3.315

Plus 0.000 0.000 0.000

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.177 0.159 0.282 C4 7.792 9.620 12.807 C5 10.224 11.514 13.667 C6 13.177 13.634 14.805 C7 10.004 9.109 10.034 C8 38.591 37.840 32.623 C9 10.411 9.427 8.028 C10 5.492 4.766 3.866 C11 0.820 0.734 0.513 C12 0.104 0.083 0.061

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.002 0.003 C4 7.517 9.293 12.342 C5 1.907 2.179 2.523 C6 2.529 2.745 2.801 C7 0.297 0.311 0.283 C8 0.089 0.090 0.074 C9 0.363 0.362 0.270 C10 0.062 0.061 0.042 C11 0.014 0.014 0.009

I-Paraffins C4 0.040 0.051 0.065 C5 4.713 5.445 6.234 C6 5.116 5.562 5.665 C7 2.617 2.758 2.493 C8 32.337 32.648 27.014 C9 4.428 4.463 3.295 C10 1.881 1.845 1.250 C11 0.459 0.441 0.280

Mono-Aromatics C6 0.646 0.526 0.790 C7 5.772 4.764 5.978 C8 6.051 4.996 5.439 C9 5.434 4.459 4.314 C10 2.617 2.143 1.861 C11 0.315 0.256 0.203 C12 0.104 0.083 0.061

Naphthalenes C10 0.055 0.038 0.041 C11 0.019 0.013 0.013

Naphtheno/Olefino-Benzs C10 0.209 0.168 0.151

Indenes C9 0.156 0.116 0.126 C10 0.638 0.483 0.501 C11 0.013 0.009 0.008

Mono-Naphthenes C5 0.207 0.199 0.282 C6 2.472 2.328 2.803 C7 0.843 0.792 0.819 C8 0.094 0.087 0.080 C9 0.031 0.027 0.023 C10 0.023 0.020 0.015

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes n-Olefins C4 0.235 0.276 0.400 C5 1.595 1.760 2.170 C6 1.083 1.133 1.228 C7 0.016 0.016 0.015

Iso-Olefins C5 1.601 1.744 2.178 C6 0.984 1.023 1.116 C7 0.458 0.468 0.445 C8 0.020 0.018 0.015 C10 0.006 0.007 0.004

Naphtheno-Olefins C5 0.179 0.166 0.250 C6 0.346 0.317 0.402

Di-Olefins C5 0.021 0.022 0.029

Oxygenates C3 0.176 0.157 0.279

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.24 21.10 5% 27.49 26.16 10% 80.12 78.85 15% 96.00 81.85 20% 138.22 100.24 25% 154.03 140.27 30% 169.90 154.81 35% 206.70 176.86 40% 209.73 209.26 45% 210.36 209.87 50% 229.51 210.48 55% 230.86 229.99 60% 234.11 231.76 65% 236.86 235.56 70% 238.19 237.39 75% 254.49 238.95 80% 278.11 255.26 85% 292.29 281.91 90% 327.44 321.10 95% 350.87 336.69 FBP 400.85 388.14

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.391 74-98-6 P3 Propane 0.001 0.002 0.003 0.304 2 8.612 75-28-5 I4 i-Butane 0.040 0.051 0.065 9.521 3 9.403 115-11-7 K4 Isobutene 0.020 0.025 0.035 5.059 4 9.442 106-98-9 K4 Butene-1 0.024 0.029 0.041 5.955 5 9.791 106-97-8 P4 n-Butane 7.517 9.293 12.342 1799.592 6 10.265 624-64-6 K4 t-Butene-2 0.089 0.106 0.152 22.150 7 10.388 463-82-1 I5 2,2-Dimethylpropane 0.029 0.035 0.038 6.970 8 10.986 590-18-1 K4 c-Butene-2 0.101 0.117 0.172 25.142 9 13.127 563-45-1 C5 3-Methylbutene-1 0.070 0.079 0.095 17.274 10 14.706 78-78-4 I5 i-Pentane 4.684 5.410 6.195 1129.155

11 16.330 109-67-1 K5 Pentene-1 0.320 0.357 0.435 79.317 12 17.166 563-46-2 C5 2-Methylbutene-1 0.500 0.550 0.681 124.010 13 17.689 109-66-0 P5 n-Pentane 1.907 2.179 2.523 459.763 14 18.203 78-79-5 E5 2-Methyl-1,3-Butadiene 0.008 0.009 0.012 2.169 15 18.795 646-04-8 K5 t-Pentene-2 0.825 0.910 1.122 204.461 16 19.817 627-20-3 K5 c-Pentene-2 0.451 0.492 0.613 111.729 17 20.485 513-35-9 C5 2-Methylbutene-2 1.031 1.114 1.403 255.675 18 20.826 2004-70-8 E5 1t,3-Pentadiene 0.012 0.013 0.017 3.165 19 22.613 75-83-2 I6 2,2-Dimethylbutane 0.124 0.137 0.138 30.126 20 25.243 142-29-0 B5 Cyclopentene 0.179 0.166 0.250 45.591

21 26.486 71-23-8 X3 n-Propanol 0.176 0.157 0.279 30.550 22 27.094 287-92-3 M5 Cyclopentane 0.207 0.199 0.282 51.438 23 27.828 79-29-8 I6 2,3-Dimethylbutane 0.856 0.925 0.948 207.098 24 28.222 ? Unidentified 0.050 0.048 0.054 15.201 25 28.684 691-38-3 C6 4-Methyl-c-pentene-2 0.043 0.046 0.049 10.769 26 28.899 107-83-5 I6 2-Methylpentane 2.394 2.623 2.651 579.326 27 29.332 674-76-0 C6 4-Methyl-t-pentene-2 0.129 0.137 0.147 32.078 28 31.543 96-14-0 I6 3-Methylpentane 1.742 1.877 1.929 421.632 29 32.710 763-29-1 C6 2-Methylpentene-1 0.220 0.230 0.250 54.576 30 32.933 592-41-6 K6 Hexene-1 0.151 0.159 0.171 37.317

31 35.291 110-54-3 P6 n-Hexane 2.529 2.745 2.801 612.125 32 35.929 13269-52-8 K6 t-Hexene-3 0.252 0.264 0.286 62.455 33 36.401 4050-45-7 K6 t-Hexene-2 0.477 0.500 0.541 118.380 34 36.894 625-27-4 C6 2-Methylpentene-2 0.335 0.347 0.380 83.155 35 37.306 922-62-3 C6 3-Methyl-c-pentene-2 0.256 0.263 0.290 63.497 36 38.233 7688-21-3 K6 c-Hexene-2 0.203 0.210 0.230 50.351 37 39.581 3404-73-7 C7 3,3-Dimethylpentene-1 0.305 0.311 0.296 75.555 38 40.153 96-37-7 M6 Methylcyclopentane 1.533 1.465 1.738 380.015 39 41.726 108-08-7 I7 2,4-Dimethylpentane 0.585 0.623 0.557 142.210 40 42.271 464-06-2 I7 2,2,3-Trimethylbutane 0.049 0.051 0.047 11.987

41 45.132 71-42-3 Q6 Benzene 0.646 0.526 0.790 172.575 42 45.337 693-89-0 B6 1-Methylcyclopentene 0.313 0.287 0.364 79.482 43 46.157 3404-61-3 C7 3-Methylhexene-1 0.012 0.012 0.012 3.005

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 46.738 3524-73-0 C7 5-Methylhexene-1 0.054 0.055 0.052 13.343 45 47.047 110-82-7 M6 Cyclohexane 0.939 0.863 1.065 232.871 46 48.801 15840-60-5 C7 2-Methyl-c-hexene-3 0.030 0.031 0.029 7.336 47 49.800 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.033 0.034 0.032 8.173 48 50.197 591-76-4 I7 2-Methylhexane 1.472 1.552 1.402 357.716 49 50.669 110-83-8 B6 Cyclohexene 0.033 0.029 0.039 8.245 50 52.028 589-34-4 I7 3-Methylhexane 0.510 0.532 0.486 124.039 51 52.880 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.112 0.107 0.109 27.833 52 53.473 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.086 0.083 0.084 21.353 53 54.096 822-50-4 M7 1t,2-Dimethylcyclopentane 0.111 0.106 0.108 27.642

54 54.761 540-84-1 I8 2,2,4-Trimethylpentane 11.461 11.852 9.574 2790.355 55 56.884 14686-14-7 K7 t-Heptene-3 0.016 0.016 0.015 3.950 56 57.238 6094-02-6 C7 2-Methylhexene-1 0.025 0.026 0.024 6.224 57 57.615 142-82-5 P7 n-Heptane 0.297 0.311 0.283 72.223 58 61.059 108-87-2 M7 Methylcyclohexane 0.513 0.477 0.499 127.214 59 63.856 1640-89-7 M7 Ethylcyclopentane 0.020 0.019 0.019 4.952 60 64.510 564-02-3 I8 2,2,3-Trimethylpentane 0.663 0.663 0.554 161.495 61 64.758 592-13-2 I8 2,5-Dimethylhexane 1.330 1.373 1.111 323.907 62 65.096 589-43-5 I8 2,4-Dimethylhexane 1.092 1.116 0.912 265.925 63 68.126 565-75-3 I8 2,3,4-Trimethylpentane 6.897 6.863 5.761 1679.101

64 68.633 108-88-3 Q7 Toluene 5.772 4.764 5.978 1524.479 65 68.814 560-21-4 I8 2,3,3-Trimethylpentane 8.803 8.674 7.354 2143.232 66 70.436 584-94-1 I8 2,3-Dimethylhexane 1.645 1.653 1.375 400.609 67 71.698 592-27-8 I8 2-Methylheptane 0.108 0.110 0.090 26.218 68 71.963 589-53-7 I8 4-Methylheptane 0.200 0.203 0.167 48.673 69 72.093 ? Unidentified 0.141 0.141 0.118 42.947 70 72.863 M8 1,3-dimethyl-t-cyclohexane 0.048 0.044 0.040 11.803 71 73.021 589-81-1 I8 3-Methylheptane 0.102 0.104 0.086 24.949 72 73.202 619-99-8 I8 3-Ethylhexane 0.036 0.036 0.030 8.672 73 74.942 3522-94-9 I9 2,2,5-Trimethylhexane 3.275 3.314 2.437 798.940

74 75.909 ? Unidentified 0.025 0.024 0.019 7.558 75 76.194 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.020 0.018 0.017 4.919 76 77.563 111-65-9 P8 n-Octane 0.089 0.090 0.074 21.621 77 78.507 ? Unidentified 0.084 0.081 0.062 25.461 78 80.058 1069-53-0 I9 2,3,5-Trimethylhexane 0.635 0.630 0.473 154.964 79 81.232 1071-26-7 I9 2,4-Dimethylheptane 0.074 0.075 0.055 18.127 80 81.867 1678-91-7 M8 Ethylcyclohexane 0.026 0.024 0.022 6.552 81 82.194 1072-05-5 I9 2,6-Dimethylheptane 0.109 0.110 0.081 26.617 82 82.674 ? Unidentified 0.008 0.009 0.006 2.483 83 83.128 I9 2,5-Dimethylheptane 0.291 0.291 0.217 71.006

84 84.439 100-41-4 Q8 Ethylbenzene 1.019 0.841 0.916 267.051 85 84.617 ? Unidentified 0.046 0.045 0.035 13.925 86 84.857 ? Unidentified 0.038 0.035 0.029 11.560

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 85.669 108-38-3 Q8 m-Xylene 2.759 2.284 2.480 723.115 88 85.817 106-42-3 Q8 p-Xylene 1.267 1.053 1.139 332.164 89 85.963 ? Unidentified 0.095 0.093 0.070 28.711 90 86.219 C8 C9-IsoOlefin-3 0.020 0.018 0.015 4.986 91 86.327 ? Unidentified 0.017 0.017 0.013 5.245 92 87.014 2216-34-4 I9 4-Methyloctane 0.011 0.011 0.008 2.743 93 87.146 3221-61-2 I9 2-Methyloctane 0.016 0.016 0.012 3.945 94 88.011 2216-33-3 I9 3-Methyloctane 0.016 0.016 0.012 3.948 95 88.480 ? Unidentified 0.276 0.289 0.208 83.729 96 88.650 95-47-6 Q8 o-Xylene 1.007 0.818 0.905 263.837

97 89.068 I10 C10 - IsoParaffin - 1 0.808 0.794 0.542 197.423 98 89.914 14720-74-2 I10 2,2,4-trimethylheptane 0.556 0.547 0.373 136.024 99 91.461 111-84-2 P9 n-Nonane 0.363 0.362 0.270 88.528 100 92.083 4926-90-3 M9 1,1-Methylethylcyclohexane 0.024 0.022 0.018 6.022 101 92.837 98-82-8 Q9 i-Propylbenzene 0.033 0.027 0.026 8.478 102 93.028 ? Unidentified 0.017 0.016 0.013 5.221 103 93.028 ? Unidentified 0.017 0.018 0.012 5.221 104 93.028 ? Unidentified 0.017 0.012 0.012 5.221 105 93.133 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.006 0.006 0.005 1.603 106 93.133 C10 C10-IsoOlefin-4 0.006 0.007 0.004 1.603

107 93.133 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.603 108 93.602 ? Unidentified 0.193 0.191 0.129 58.622 109 93.824 15869-87-1 I10 2,2-Dimethyloctane 0.063 0.062 0.042 15.285 110 94.269 ? Unidentified 0.012 0.008 1.105 3.517 111 94.269 ? Unidentified 0.012 0.012 0.008 3.517 112 94.625 15869-89-3 I10 2,5-Dimethyloctane 0.062 0.061 0.042 15.240 113 95.101 2040-95-1 I10 2,7-Dimethyloctane 0.026 0.025 0.017 6.357 114 95.265 2051-30-1 I10 2,4-Dimethyloctane 0.114 0.112 0.076 27.766 115 95.660 I10 2,6-Dimethyloctane 0.037 0.036 0.025 9.036 116 96.303 103-65-1 Q9 n-Propylbenzene 0.262 0.218 0.208 68.313

117 97.152 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.018 0.843 0.808 265.192 118 97.386 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.488 0.406 0.388 127.206 119 98.014 108-67-8 Q9 1,3,5-Trimethylbenzene 0.694 0.574 0.551 180.862 120 98.684 17301-94-8 I10 4-Methylnonane 0.010 0.010 0.007 2.454 121 98.889 ? Unidentified 1.284 1.265 0.861 390.019 122 99.097 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.404 0.329 0.321 105.308 123 99.467 ? Unidentified 0.004 0.004 0.003 1.244 124 99.661 5911-04-6 I10 3-Methylnonane 0.014 0.014 0.009 3.450 125 100.127 ? Unidentified 0.089 0.064 0.054 27.013 126 100.253 ? Unidentified 0.239 0.230 0.146 72.642

127 100.478 I11 C11-Isoparaffin-2 0.128 0.123 0.078 31.380 128 100.736 95-63-6 Q9 1,2,4-Trimethylbenzene 2.134 1.743 1.694 555.657 129 100.941 ? Unidentified 0.143 0.146 0.098 43.555

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 101.063 ? Unidentified 0.086 0.084 0.057 25.995 131 101.320 1678-98-4 M10 i-Butylcyclohexane 0.023 0.020 0.015 5.616 132 101.964 ? Unidentified 0.008 0.007 0.005 2.437 133 102.107 17302-01-1 I10 3-Ethyl-3-methylheptane 0.191 0.184 0.117 46.826 134 102.460 538-93-2 Q10 i-Butylbenzene 0.213 0.179 0.151 55.175 135 102.660 124-18-5 P10 n-Decane 0.062 0.061 0.042 15.250 136 102.974 ? Unidentified 0.045 0.043 0.028 13.737 137 103.611 526-73-8 Q9 1,2,3-Trimethylbenzene 0.400 0.320 0.317 104.112 138 103.992 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.021 0.017 0.015 5.372 139 104.190 I11 C11 Isoparaffin-4 0.021 0.020 0.013 5.086

140 104.395 ? Unidentified 0.093 0.077 0.066 28.152 141 104.800 J9 Indan 0.156 0.116 0.126 41.272 142 105.428 J10 Indene 0.471 0.350 0.381 124.780 143 106.145 I11 C11-Isoparaffin-7 0.147 0.142 0.090 36.015 144 106.331 141-93-5 Q10 1,3-Diethylbenzene 0.055 0.046 0.039 14.329 145 106.617 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.528 0.439 0.376 136.898 146 106.944 105-05-5 Q10 1,4-Diethylbenzene 0.191 0.159 0.136 49.561 147 107.173 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.145 0.118 0.103 37.440 148 107.434 135-01-3 Q10 1,2-Diethylbenzene 0.032 0.026 0.023 8.355 149 107.885 ? Unidentified 0.024 0.023 0.014 7.161

150 108.024 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.051 0.041 0.036 13.086 151 108.160 ? Unidentified 0.024 0.023 0.015 7.141 152 108.242 ? Unidentified 0.021 0.020 0.013 6.319 153 108.362 I11 C11- Isoparaffin-11 0.163 0.156 0.099 39.817 154 108.550 ? Unidentified 0.047 0.045 0.029 14.197 155 108.874 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.114 0.093 0.081 29.579 156 109.028 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.229 0.187 0.163 59.253 157 109.199 J10 2-Methylindan 0.022 0.017 0.016 5.949 158 109.542 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.272 0.223 0.193 70.444 159 110.097 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.090 0.072 0.064 23.357

160 111.009 Q11 1-Methyl-4-t-butylbenzene 0.026 0.022 0.017 6.733 161 111.221 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.099 0.080 0.071 25.729 162 111.528 1120-21-4 P11 n-Undecane 0.014 0.014 0.009 3.507 163 111.689 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.015 0.012 0.010 3.853 164 112.161 Q10 1,2,4,5-Tetramethylbenzene 0.237 0.191 0.169 61.470 165 112.428 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.339 0.273 0.241 87.889 166 113.581 Q11 C11 - Aromatic - 3 0.049 0.040 0.032 12.740 167 113.761 874-35-1 H10 5-Methylindan 0.105 0.084 0.076 27.119 168 113.901 Q12 1,2-Di-i-propylbenzene 0.041 0.033 0.024 10.657 169 114.116 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.058 0.047 0.037 15.015

170 114.278 Q11 C11 - Aromatic - 4 0.027 0.022 0.018 7.015 171 114.512 824-22-6 J10 4-Methylindan 0.145 0.116 0.104 37.454 172 114.680 ? Unidentified 0.026 0.021 0.017 8.049

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 114.764 824-63-5 H10 2-Methylindan 0.104 0.084 0.075 27.061 174 114.977 ? Unidentified 0.010 0.008 0.007 3.113 175 115.089 538-68-1 Q11 n-Pentylbenzene 0.012 0.010 0.008 3.052 176 115.317 Q11 tert-Pentylbenzene 0.056 0.045 0.036 14.562 177 115.632 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.022 0.018 0.014 5.778 178 115.742 Q11 C11 - Aromatic - 7 0.029 0.024 0.019 7.454 179 116.204 100-18-5 Q12 1,4-Di-i-propylbenzene 0.038 0.030 0.022 9.646 180 116.633 91-20-3 G10 Naphthalene 0.055 0.038 0.041 14.950 181 116.797 J11 4,7-Dimethyl Indane 0.008 0.006 0.005 2.148 182 117.080 J11 1,1-Dimethyl Indane 0.005 0.003 0.003 1.223

183 117.735 Q12 1,3-Di-n-propylbenzene 0.025 0.020 0.015 6.398 184 117.846 Q11 C11 - Aromatic - 11 0.012 0.010 0.008 3.082 185 118.401 Q11 C11 - Aromatic - 12 0.008 0.006 0.005 1.973 186 123.280 91-57-6 G11 2-Methylnaphthalene 0.013 0.009 0.009 3.444 187 124.145 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.004 1.708 188 126.171 ? Unidentified 0.004 0.004 0.003 1.353 189 126.171 ? Unidentified 0.004 0.004 0.002 1.353 190 126.171 ? Unidentified 0.004 0.004 0.002 1.353 191 129.863 ? Unidentified 0.004 0.003 0.002 1.077

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.391 74-98-6 Propane 0.001 0.002 0.003 0.304

9.791 106-97-8 n-Butane 7.517 9.293 12.342 1799.592 17.689 109-66-0 n-Pentane 1.907 2.179 2.523 459.763 35.291 110-54-3 n-Hexane 2.529 2.745 2.801 612.125 57.615 142-82-5 n-Heptane 0.297 0.311 0.283 72.223 77.563 111-65-9 n-Octane 0.089 0.090 0.074 21.621 91.461 111-84-2 n-Nonane 0.363 0.362 0.270 88.528 102.660 124-18-5 n-Decane 0.062 0.061 0.042 15.250 111.528 1120-21-4 n-Undecane 0.014 0.014 0.009 3.507

I-Paraffins 8.612 75-28-5 i-Butane 0.040 0.051 0.065 9.521

10.388 463-82-1 2,2-Dimethylpropane 0.029 0.035 0.038 6.970 14.706 78-78-4 i-Pentane 4.684 5.410 6.195 1129.155 22.613 75-83-2 2,2-Dimethylbutane 0.124 0.137 0.138 30.126 27.828 79-29-8 2,3-Dimethylbutane 0.856 0.925 0.948 207.098 28.899 107-83-5 2-Methylpentane 2.394 2.623 2.651 579.326 31.543 96-14-0 3-Methylpentane 1.742 1.877 1.929 421.632 41.726 108-08-7 2,4-Dimethylpentane 0.585 0.623 0.557 142.210 42.271 464-06-2 2,2,3-Trimethylbutane 0.049 0.051 0.047 11.987 50.197 591-76-4 2-Methylhexane 1.472 1.552 1.402 357.716 52.028 589-34-4 3-Methylhexane 0.510 0.532 0.486 124.039 54.761 540-84-1 2,2,4-Trimethylpentane 11.461 11.852 9.574 2790.355 64.510 564-02-3 2,2,3-Trimethylpentane 0.663 0.663 0.554 161.495 64.758 592-13-2 2,5-Dimethylhexane 1.330 1.373 1.111 323.907 65.096 589-43-5 2,4-Dimethylhexane 1.092 1.116 0.912 265.925 68.126 565-75-3 2,3,4-Trimethylpentane 6.897 6.863 5.761 1679.101 68.814 560-21-4 2,3,3-Trimethylpentane 8.803 8.674 7.354 2143.232 70.436 584-94-1 2,3-Dimethylhexane 1.645 1.653 1.375 400.609 71.698 592-27-8 2-Methylheptane 0.108 0.110 0.090 26.218 71.963 589-53-7 4-Methylheptane 0.200 0.203 0.167 48.673 73.021 589-81-1 3-Methylheptane 0.102 0.104 0.086 24.949 73.202 619-99-8 3-Ethylhexane 0.036 0.036 0.030 8.672 74.942 3522-94-9 2,2,5-Trimethylhexane 3.275 3.314 2.437 798.940 80.058 1069-53-0 2,3,5-Trimethylhexane 0.635 0.630 0.473 154.964 81.232 1071-26-7 2,4-Dimethylheptane 0.074 0.075 0.055 18.127 82.194 1072-05-5 2,6-Dimethylheptane 0.109 0.110 0.081 26.617 83.128 2,5-Dimethylheptane 0.291 0.291 0.217 71.006 87.014 2216-34-4 4-Methyloctane 0.011 0.011 0.008 2.743 87.146 3221-61-2 2-Methyloctane 0.016 0.016 0.012 3.945 88.011 2216-33-3 3-Methyloctane 0.016 0.016 0.012 3.948 89.068 C10 - IsoParaffin - 1 0.808 0.794 0.542 197.423 89.914 14720-74-2 2,2,4-trimethylheptane 0.556 0.547 0.373 136.024 93.133 C10-isoparaffin-x 0.000 0.000 0.000 1.603 93.824 15869-87-1 2,2-Dimethyloctane 0.063 0.062 0.042 15.285 94.625 15869-89-3 2,5-Dimethyloctane 0.062 0.061 0.042 15.240 95.101 2040-95-1 2,7-Dimethyloctane 0.026 0.025 0.017 6.357 95.265 2051-30-1 2,4-Dimethyloctane 0.114 0.112 0.076 27.766

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 95.660 2,6-Dimethyloctane 0.037 0.036 0.025 9.036

98.684 17301-94-8 4-Methylnonane 0.010 0.010 0.007 2.454 99.661 5911-04-6 3-Methylnonane 0.014 0.014 0.009 3.450 100.478 C11-Isoparaffin-2 0.128 0.123 0.078 31.380 102.107 17302-01-1 3-Ethyl-3-methylheptane 0.191 0.184 0.117 46.826 104.190 C11 Isoparaffin-4 0.021 0.020 0.013 5.086 106.145 C11-Isoparaffin-7 0.147 0.142 0.090 36.015 108.362 C11- Isoparaffin-11 0.163 0.156 0.099 39.817

Aromatics Mono-Aromatics 45.132 71-42-3 Benzene 0.646 0.526 0.790 172.575

68.633 108-88-3 Toluene 5.772 4.764 5.978 1524.479 84.439 100-41-4 Ethylbenzene 1.019 0.841 0.916 267.051 85.669 108-38-3 m-Xylene 2.759 2.284 2.480 723.115 85.817 106-42-3 p-Xylene 1.267 1.053 1.139 332.164 88.650 95-47-6 o-Xylene 1.007 0.818 0.905 263.837 92.837 98-82-8 i-Propylbenzene 0.033 0.027 0.026 8.478 96.303 103-65-1 n-Propylbenzene 0.262 0.218 0.208 68.313 97.152 620-14-4 1-Methyl-3-ethylbenzene 1.018 0.843 0.808 265.192 97.386 622-96-8 1-Methyl-4-ethylbenzene 0.488 0.406 0.388 127.206 98.014 108-67-8 1,3,5-Trimethylbenzene 0.694 0.574 0.551 180.862 99.097 611-14-3 1-Methyl-2-ethylbenzene 0.404 0.329 0.321 105.308 100.736 95-63-6 1,2,4-Trimethylbenzene 2.134 1.743 1.694 555.657 102.460 538-93-2 i-Butylbenzene 0.213 0.179 0.151 55.175 103.611 526-73-8 1,2,3-Trimethylbenzene 0.400 0.320 0.317 104.112 103.992 535-77-3 1-Methyl-3-i-propylbenzene 0.021 0.017 0.015 5.372 106.331 141-93-5 1,3-Diethylbenzene 0.055 0.046 0.039 14.329 106.617 1074-43-7 1-Methyl-3-n-propylbenzene 0.528 0.439 0.376 136.898 106.944 105-05-5 1,4-Diethylbenzene 0.191 0.159 0.136 49.561 107.173 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.145 0.118 0.103 37.440 107.434 135-01-3 1,2-Diethylbenzene 0.032 0.026 0.023 8.355 108.024 1074-17-5 1-Methyl-2-n-propylbenzene 0.051 0.041 0.036 13.086 108.874 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.114 0.093 0.081 29.579 109.028 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.229 0.187 0.163 59.253 109.542 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.272 0.223 0.193 70.444 110.097 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.090 0.072 0.064 23.357 111.009 1-Methyl-4-t-butylbenzene 0.026 0.022 0.017 6.733 111.221 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.099 0.080 0.071 25.729 111.689 4218-48-8 1-Ethyl-4-i-propylbenzene 0.015 0.012 0.010 3.853 112.161 1,2,4,5-Tetramethylbenzene 0.237 0.191 0.169 61.470 112.428 527-53-7 1,2,3,5-Tetramethylbenzene 0.339 0.273 0.241 87.889 113.581 C11 - Aromatic - 3 0.049 0.040 0.032 12.740 113.901 1,2-Di-i-propylbenzene 0.041 0.033 0.024 10.657 114.116 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.058 0.047 0.037 15.015 114.278 C11 - Aromatic - 4 0.027 0.022 0.018 7.015 115.089 538-68-1 n-Pentylbenzene 0.012 0.010 0.008 3.052 115.317 tert-Pentylbenzene 0.056 0.045 0.036 14.562

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.632 577-55-9 1-Methyl-2-n-butylbenzene 0.022 0.018 0.014 5.778

115.742 C11 - Aromatic - 7 0.029 0.024 0.019 7.454 116.204 100-18-5 1,4-Di-i-propylbenzene 0.038 0.030 0.022 9.646 117.735 1,3-Di-n-propylbenzene 0.025 0.020 0.015 6.398 117.846 C11 - Aromatic - 11 0.012 0.010 0.008 3.082 118.401 C11 - Aromatic - 12 0.008 0.006 0.005 1.973

Naphthalenes 116.633 91-20-3 Naphthalene 0.055 0.038 0.041 14.950

123.280 91-57-6 2-Methylnaphthalene 0.013 0.009 0.009 3.444 124.145 90-12-0 1-Methylnaphthalene 0.006 0.004 0.004 1.708

Naphtheno/Olefino-Benzs

113.761 874-35-1 5-Methylindan 0.105 0.084 0.076 27.119 114.764 824-63-5 2-Methylindan 0.104 0.084 0.075 27.061

Indenes 104.800 Indan 0.156 0.116 0.126 41.272

105.428 Indene 0.471 0.350 0.381 124.780 109.199 2-Methylindan 0.022 0.017 0.016 5.949 114.512 824-22-6 4-Methylindan 0.145 0.116 0.104 37.454 116.797 4,7-Dimethyl Indane 0.008 0.006 0.005 2.148 117.080 1,1-Dimethyl Indane 0.005 0.003 0.003 1.223

Naphthenes Mono-Naphthenes 27.094 287-92-3 Cyclopentane 0.207 0.199 0.282 51.438

40.153 96-37-7 Methylcyclopentane 1.533 1.465 1.738 380.015 47.047 110-82-7 Cyclohexane 0.939 0.863 1.065 232.871 52.880 1759-58-6 1t,3-Dimethylcyclopentane 0.112 0.107 0.109 27.833 53.473 2532-58-3 1c,3-Dimethylcyclopentane 0.086 0.083 0.084 21.353 54.096 822-50-4 1t,2-Dimethylcyclopentane 0.111 0.106 0.108 27.642 61.059 108-87-2 Methylcyclohexane 0.513 0.477 0.499 127.214 63.856 1640-89-7 Ethylcyclopentane 0.020 0.019 0.019 4.952 72.863 1,3-dimethyl-t-cyclohexane 0.048 0.044 0.040 11.803 76.194 2207-03-6 1t,3-Dimethylcyclohexane 0.020 0.018 0.017 4.919 81.867 1678-91-7 Ethylcyclohexane 0.026 0.024 0.022 6.552 92.083 4926-90-3 1,1-Methylethylcyclohexane 0.024 0.022 0.018 6.022 93.133 696-29-7 1-Methyl-2-propyl-cyclopentan 0.006 0.006 0.005 1.603 101.320 1678-98-4 i-Butylcyclohexane 0.023 0.020 0.015 5.616

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.403 115-11-7 Isobutene 0.020 0.025 0.035 5.059

9.442 106-98-9 Butene-1 0.024 0.029 0.041 5.955 10.265 624-64-6 t-Butene-2 0.089 0.106 0.152 22.150 10.986 590-18-1 c-Butene-2 0.101 0.117 0.172 25.142 16.330 109-67-1 Pentene-1 0.320 0.357 0.435 79.317 18.795 646-04-8 t-Pentene-2 0.825 0.910 1.122 204.461 19.817 627-20-3 c-Pentene-2 0.451 0.492 0.613 111.729 32.933 592-41-6 Hexene-1 0.151 0.159 0.171 37.317

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 35.929 13269-52-8 t-Hexene-3 0.252 0.264 0.286 62.455

36.401 4050-45-7 t-Hexene-2 0.477 0.500 0.541 118.380 38.233 7688-21-3 c-Hexene-2 0.203 0.210 0.230 50.351 56.884 14686-14-7 t-Heptene-3 0.016 0.016 0.015 3.950

Iso-Olefins 13.127 563-45-1 3-Methylbutene-1 0.070 0.079 0.095 17.274

17.166 563-46-2 2-Methylbutene-1 0.500 0.550 0.681 124.010 20.485 513-35-9 2-Methylbutene-2 1.031 1.114 1.403 255.675 28.684 691-38-3 4-Methyl-c-pentene-2 0.043 0.046 0.049 10.769 29.332 674-76-0 4-Methyl-t-pentene-2 0.129 0.137 0.147 32.078 32.710 763-29-1 2-Methylpentene-1 0.220 0.230 0.250 54.576 36.894 625-27-4 2-Methylpentene-2 0.335 0.347 0.380 83.155 37.306 922-62-3 3-Methyl-c-pentene-2 0.256 0.263 0.290 63.497 39.581 3404-73-7 3,3-Dimethylpentene-1 0.305 0.311 0.296 75.555 46.157 3404-61-3 3-Methylhexene-1 0.012 0.012 0.012 3.005 46.738 3524-73-0 5-Methylhexene-1 0.054 0.055 0.052 13.343 48.801 15840-60-5 2-Methyl-c-hexene-3 0.030 0.031 0.029 7.336 49.800 3404-55-5 4-Methyl-t/c-hexene-2 0.033 0.034 0.032 8.173 57.238 6094-02-6 2-Methylhexene-1 0.025 0.026 0.024 6.224 86.219 C9-IsoOlefin-3 0.020 0.018 0.015 4.986 93.133 C10-IsoOlefin-4 0.006 0.007 0.004 1.603

Naphtheno-Olefins 25.243 142-29-0 Cyclopentene 0.179 0.166 0.250 45.591

45.337 693-89-0 1-Methylcyclopentene 0.313 0.287 0.364 79.482 50.669 110-83-8 Cyclohexene 0.033 0.029 0.039 8.245

Di-Olefins 18.203 78-79-5 2-Methyl-1,3-Butadiene 0.008 0.009 0.012 2.169

20.826 2004-70-8 1t,3-Pentadiene 0.012 0.013 0.017 3.165

Oxygenates 26.486 71-23-8 n-Propanol 0.176 0.157 0.279 30.550

Unidentified 28.222 Unidentified 0.050 0.048 0.054 15.201

72.093 Unidentified 0.141 0.141 0.118 42.947 75.909 Unidentified 0.025 0.024 0.019 7.558 78.507 Unidentified 0.084 0.081 0.062 25.461 82.674 Unidentified 0.008 0.009 0.006 2.483 84.617 Unidentified 0.046 0.045 0.035 13.925 84.857 Unidentified 0.038 0.035 0.029 11.560 85.963 Unidentified 0.095 0.093 0.070 28.711 86.327 Unidentified 0.017 0.017 0.013 5.245 88.480 Unidentified 0.276 0.289 0.208 83.729 93.028 Unidentified 0.017 0.016 0.013 5.221 93.028 Unidentified 0.017 0.018 0.012 5.221 93.028 Unidentified 0.017 0.012 0.012 5.221 93.602 Unidentified 0.193 0.191 0.129 58.622 94.269 Unidentified 0.012 0.008 1.105 3.517 94.269 Unidentified 0.012 0.012 0.008 3.517

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 98.889 Unidentified 1.284 1.265 0.861 390.019

99.467 Unidentified 0.004 0.004 0.003 1.244 100.127 Unidentified 0.089 0.064 0.054 27.013 100.253 Unidentified 0.239 0.230 0.146 72.642 100.941 Unidentified 0.143 0.146 0.098 43.555 101.063 Unidentified 0.086 0.084 0.057 25.995 101.964 Unidentified 0.008 0.007 0.005 2.437 102.974 Unidentified 0.045 0.043 0.028 13.737 104.395 Unidentified 0.093 0.077 0.066 28.152 107.885 Unidentified 0.024 0.023 0.014 7.161 108.160 Unidentified 0.024 0.023 0.015 7.141 108.242 Unidentified 0.021 0.020 0.013 6.319 108.550 Unidentified 0.047 0.045 0.029 14.197 114.680 Unidentified 0.026 0.021 0.017 8.049 114.977 Unidentified 0.010 0.008 0.007 3.113 126.171 Unidentified 0.004 0.004 0.003 1.353 126.171 Unidentified 0.004 0.004 0.002 1.353 126.171 Unidentified 0.004 0.004 0.002 1.353 129.863 Unidentified 0.004 0.003 0.002 1.077

Plus

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1

n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

2,2-Dimethylbutane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2

2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,2,3-Trimethylbutane

Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane

Methylcyclohexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

2,2,5-Trimethylhexane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF95.090.085.080.075.0

Unidentified 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene

p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane

Unidentified 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2

1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF Sample: ODDB-91315 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91315 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000011.D\SIG1000011_FID1_A.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 13.967 16.585 17.183

I-Paraffins 23.619 27.367 26.260

Aromatics 47.067 40.259 40.242 Mono-Aromatics 44.465 38.173 38.390 Naphthalenes 0.252 0.184 0.177 Naphtheno/Olefino-Benzs 0.756 0.634 0.519 Indenes 1.594 1.268 1.156

Naphthenes 5.847 5.746 6.153 Mono-Naphthenes 5.847 5.746 6.153 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.969 7.721 8.350 n-Olefins 3.107 3.525 3.842 Iso-Olefins 3.277 3.632 3.813 Naphtheno-Olefins 0.563 0.539 0.665 Di-Olefins 0.023 0.025 0.030

Oxygenates 0.188 0.175 0.283

Unidentified 2.344 2.148 1.529

Plus 0.000 0.000 0.000

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.189 0.177 0.285 C4 4.561 5.869 7.131 C5 18.430 21.880 23.317 C6 21.530 23.383 22.919 C7 22.174 19.947 21.525 C8 13.659 11.870 11.640 C9 3.834 3.286 2.891 C10 10.043 8.526 6.847 C11 2.646 2.415 1.584 C12 0.590 0.499 0.331

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.002 0.002 C4 4.275 5.515 6.671 C5 2.361 2.815 2.968 C6 6.582 7.454 6.928 C7 0.454 0.495 0.411 C8 0.122 0.129 0.097 C9 0.031 0.032 0.022 C10 0.043 0.044 0.028 C11 0.099 0.099 0.057

I-Paraffins C4 0.038 0.052 0.060 C5 12.244 14.758 15.393 C6 7.298 8.275 7.681 C7 2.133 2.341 1.930 C8 0.286 0.304 0.227 C9 0.048 0.051 0.034 C10 0.505 0.517 0.316 C11 1.033 1.037 0.599 C12 0.034 0.034 0.018

Mono-Aromatics C6 0.657 0.558 0.763 C7 17.964 15.471 17.684 C8 13.134 11.324 11.221 C9 3.617 3.097 2.730 C10 7.134 6.064 4.821 C11 1.427 1.212 0.873 C12 0.532 0.446 0.297

Naphthalenes C10 0.234 0.170 0.165 C11 0.019 0.014 0.012

Naphtheno/Olefino-Benzs C10 0.756 0.634 0.519

Indenes C9 0.138 0.107 0.106 C10 1.363 1.089 0.993 C11 0.068 0.053 0.042 C12 0.025 0.019 0.015

Mono-Naphthenes C5 0.242 0.242 0.313 C6 4.406 4.330 4.749 C7 1.073 1.052 0.991 C8 0.117 0.114 0.095

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.008 0.008 0.005

n-Olefins C4 0.247 0.303 0.400 C5 1.682 1.936 2.175 C6 1.161 1.268 1.251 C7 0.017 0.018 0.015

Iso-Olefins C5 1.689 1.920 2.184 C6 1.053 1.143 1.135 C7 0.535 0.570 0.494

Naphtheno-Olefins C5 0.190 0.184 0.253 C6 0.373 0.356 0.412

Di-Olefins C5 0.023 0.025 0.030

Oxygenates C3 0.188 0.175 0.283

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.67 21.39 5% 78.84 29.91 10% 80.16 79.64 15% 81.49 80.74 20% 96.52 81.84 25% 138.22 97.08 30% 145.29 138.23 35% 154.76 144.89 40% 157.30 154.52 45% 177.16 155.49 50% 229.03 175.61 55% 229.63 207.32 60% 230.23 229.48 65% 230.83 230.18 70% 277.09 230.88 75% 281.55 278.54 80% 291.76 281.93 85% 347.64 329.27 90% 363.20 362.78 95% 381.20 377.97 FBP 408.42 404.60

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.389 74-98-6 P3 Propane 0.001 0.002 0.002 0.273 2 8.609 75-28-5 I4 i-Butane 0.038 0.052 0.060 9.972 3 9.400 115-11-7 K4 Isobutene 0.022 0.027 0.035 5.822 4 9.439 106-98-9 K4 Butene-1 0.025 0.032 0.041 6.821 5 9.789 106-97-8 P4 n-Butane 4.275 5.515 6.671 1107.495 6 10.262 624-64-6 K4 t-Butene-2 0.094 0.116 0.152 25.244 7 10.385 463-82-1 I5 2,2-Dimethylpropane 0.044 0.055 0.055 11.450 8 10.983 590-18-1 K4 c-Butene-2 0.106 0.128 0.172 28.488 9 13.123 563-45-1 C5 3-Methylbutene-1 0.073 0.087 0.094 19.585 10 14.712 78-78-4 I5 i-Pentane 12.200 14.703 15.338 3182.770

11 16.328 109-67-1 K5 Pentene-1 0.336 0.392 0.435 90.275 12 17.164 563-46-2 C5 2-Methylbutene-1 0.527 0.605 0.681 141.339 13 17.687 109-66-0 P5 n-Pentane 2.361 2.815 2.968 615.837 14 18.201 78-79-5 E5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.543 15 18.790 646-04-8 K5 t-Pentene-2 0.870 1.002 1.125 233.318 16 19.431 ? Unidentified 0.006 0.007 0.008 2.094 17 19.814 627-20-3 K5 c-Pentene-2 0.476 0.542 0.616 127.733 18 20.484 513-35-9 C5 2-Methylbutene-2 1.089 1.228 1.409 292.249 19 20.815 2004-70-8 E5 1t,3-Pentadiene 0.014 0.015 0.018 3.762 20 22.607 75-83-2 I6 2,2-Dimethylbutane 0.153 0.175 0.161 39.957

21 25.241 142-29-0 B5 Cyclopentene 0.190 0.184 0.253 52.437 22 26.483 71-23-8 X3 n-Propanol 0.188 0.175 0.283 35.238 23 27.089 287-92-3 M5 Cyclopentane 0.242 0.242 0.313 64.950 24 27.820 79-29-8 I6 2,3-Dimethylbutane 0.607 0.686 0.639 159.095 25 28.223 ? Unidentified 0.054 0.054 0.055 17.624 26 28.680 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.051 0.049 12.318 27 28.904 107-83-5 I6 2-Methylpentane 3.380 3.864 3.558 885.263 28 29.330 674-76-0 C6 4-Methyl-t-pentene-2 0.138 0.153 0.149 36.992 29 31.550 96-14-0 I6 3-Methylpentane 3.158 3.550 3.324 827.082 30 32.709 763-29-1 C6 2-Methylpentene-1 0.236 0.257 0.254 63.324

31 32.933 592-41-6 K6 Hexene-1 0.161 0.177 0.174 43.204 32 35.316 110-54-3 P6 n-Hexane 6.582 7.454 6.928 1723.994 33 35.930 13269-52-8 K6 t-Hexene-3 0.270 0.296 0.291 72.486 34 36.401 4050-45-7 K6 t-Hexene-2 0.512 0.560 0.552 137.416 35 36.894 625-27-4 C6 2-Methylpentene-2 0.359 0.388 0.387 96.358 36 37.305 922-62-3 C6 3-Methyl-c-pentene-2 0.275 0.294 0.296 73.686 37 38.232 7688-21-3 K6 c-Hexene-2 0.217 0.235 0.234 58.349 38 39.579 3404-73-7 C7 3,3-Dimethylpentene-1 0.326 0.347 0.302 87.579 39 40.158 96-37-7 M6 Methylcyclopentane 2.720 2.713 2.931 729.812 40 41.728 108-08-7 I7 2,4-Dimethylpentane 0.393 0.436 0.356 103.315

41 42.033 594-56-9 C7 2,3,3-Trimethylbutene-1 0.012 0.013 0.011 3.217 42 42.268 464-06-2 I7 2,2,3-Trimethylbutane 0.057 0.062 0.052 15.032 43 44.924 ? Unidentified 0.011 0.011 0.012 3.559

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 45.129 71-42-3 Q6 Benzene 0.657 0.558 0.763 189.866 45 45.332 693-89-0 B6 1-Methylcyclopentene 0.337 0.323 0.372 92.688 46 46.153 3404-61-3 C7 3-Methylhexene-1 0.013 0.014 0.012 3.391 47 46.738 3524-73-0 C7 5-Methylhexene-1 0.083 0.089 0.077 22.306 48 47.053 110-82-7 M6 Cyclohexane 1.686 1.617 1.817 452.441 49 47.587 ? Unidentified 0.029 0.031 0.027 9.598 50 48.798 15840-60-5 C7 2-Methyl-c-hexene-3 0.032 0.034 0.029 8.532 51 49.792 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.037 0.040 0.035 10.022 52 50.186 591-76-4 I7 2-Methylhexane 1.062 1.168 0.961 279.191 53 50.663 110-83-8 B6 Cyclohexene 0.036 0.033 0.039 9.536

54 52.025 589-34-4 I7 3-Methylhexane 0.621 0.675 0.562 163.233 55 52.878 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.136 0.136 0.126 36.581 56 53.463 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.106 0.106 0.098 28.491 57 54.092 822-50-4 M7 1t,2-Dimethylcyclopentane 0.147 0.146 0.136 39.552 58 54.687 540-84-1 I8 2,2,4-Trimethylpentane 0.016 0.017 0.013 4.154 59 56.880 14686-14-7 K7 t-Heptene-3 0.017 0.018 0.015 4.489 60 57.233 6094-02-6 C7 2-Methylhexene-1 0.026 0.028 0.024 6.915 61 57.612 142-82-5 P7 n-Heptane 0.454 0.495 0.411 119.286 62 58.111 2738-19-4 C7 2-Methyl-2-hexene 0.005 0.006 0.005 1.462 63 61.058 108-87-2 M7 Methylcyclohexane 0.660 0.641 0.610 177.137

64 62.011 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.013 0.013 0.011 3.587 65 63.855 1640-89-7 M7 Ethylcyclopentane 0.023 0.022 0.021 6.158 66 64.744 592-13-2 I8 2,5-Dimethylhexane 0.019 0.021 0.015 5.133 67 65.083 589-43-5 I8 2,4-Dimethylhexane 0.026 0.028 0.021 6.837 68 68.705 108-88-3 Q7 Toluene 17.964 15.471 17.684 5134.580 69 70.427 584-94-1 I8 2,3-Dimethylhexane 0.016 0.017 0.013 4.176 70 71.695 592-27-8 I8 2-Methylheptane 0.072 0.077 0.057 18.891 71 71.947 589-53-7 I8 4-Methylheptane 0.031 0.033 0.025 8.180 72 72.859 M8 1,3-dimethyl-t-cyclohexane 0.056 0.054 0.045 14.932 73 73.019 589-81-1 I8 3-Methylheptane 0.068 0.072 0.054 17.960

74 73.201 619-99-8 I8 3-Ethylhexane 0.038 0.040 0.030 9.984 75 74.100 ? Unidentified 0.008 0.008 0.007 2.767 76 76.187 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.022 0.022 0.018 6.012 77 77.561 111-65-9 P8 n-Octane 0.122 0.129 0.097 32.043 78 81.867 1678-91-7 M8 Ethylcyclohexane 0.026 0.025 0.021 6.986 79 82.193 1072-05-5 I9 2,6-Dimethylheptane 0.007 0.007 0.005 1.855 80 83.130 I9 2,5-Dimethylheptane 0.007 0.008 0.005 1.931 81 84.452 100-41-4 Q8 Ethylbenzene 2.515 2.166 2.148 713.310 82 85.699 108-38-3 Q8 m-Xylene 6.074 5.248 5.189 1722.882 83 85.842 106-42-3 Q8 p-Xylene 2.846 2.468 2.432 807.379

84 87.016 2216-34-4 I9 4-Methyloctane 0.009 0.010 0.007 2.434 85 87.148 3221-61-2 I9 2-Methyloctane 0.012 0.013 0.009 3.191 86 88.012 2216-33-3 I9 3-Methyloctane 0.013 0.013 0.009 3.389

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 88.660 95-47-6 Q8 o-Xylene 1.700 1.442 1.452 482.170 88 91.506 111-84-2 P9 n-Nonane 0.031 0.032 0.022 8.054 89 92.837 98-82-8 Q9 i-Propylbenzene 0.035 0.031 0.027 9.922 90 95.264 2051-30-1 I10 2,4-Dimethyloctane 0.010 0.010 0.006 2.570 91 96.303 103-65-1 Q9 n-Propylbenzene 0.188 0.163 0.142 52.919 92 97.149 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.686 0.592 0.518 193.320 93 97.384 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.325 0.282 0.246 91.710 94 98.011 108-67-8 Q9 1,3,5-Trimethylbenzene 0.420 0.362 0.317 118.327 95 98.680 17301-94-8 I10 4-Methylnonane 0.006 0.006 0.004 1.635 96 98.881 I10 2,2,6-Trimethyloctane 0.378 0.388 0.241 99.894

97 99.096 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.272 0.230 0.205 76.615 98 99.659 5911-04-6 I10 3-Methylnonane 0.009 0.009 0.006 2.374 99 100.126 ? Unidentified 0.028 0.021 0.016 9.328 100 100.251 ? Unidentified 0.085 0.086 0.050 28.048 101 100.476 I11 C11-Isoparaffin-2 0.046 0.046 0.026 12.073 102 100.730 95-63-6 Q9 1,2,4-Trimethylbenzene 1.375 1.172 1.038 387.549 103 100.940 ? Unidentified 0.065 0.069 0.042 21.235 104 101.061 ? Unidentified 0.037 0.037 0.023 12.035 105 101.319 1678-98-4 M10 i-Butylcyclohexane 0.008 0.008 0.005 2.164 106 102.106 17302-01-1 I10 3-Ethyl-3-methylheptane 0.103 0.103 0.060 27.186

107 102.464 538-93-2 Q10 i-Butylbenzene 0.127 0.111 0.086 35.470 108 102.658 124-18-5 P10 n-Decane 0.043 0.044 0.028 11.467 109 102.974 ? Unidentified 0.028 0.028 0.016 9.148 110 103.609 526-73-8 Q9 1,2,3-Trimethylbenzene 0.316 0.264 0.239 89.141 111 103.996 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.018 0.015 0.012 4.966 112 104.191 I11 C11 Isoparaffin-4 0.016 0.016 0.009 4.231 113 104.393 ? Unidentified 0.101 0.088 0.068 33.104 114 104.800 J9 Indan 0.138 0.107 0.106 39.478 115 105.432 J10 Indene 0.703 0.545 0.540 201.463 116 106.150 I11 C11-Isoparaffin-7 0.311 0.312 0.181 82.415

117 106.333 141-93-5 Q10 1,3-Diethylbenzene 0.080 0.069 0.054 22.408 118 106.623 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.065 0.924 0.720 298.653 119 106.949 105-05-5 Q10 1,4-Diethylbenzene 0.490 0.425 0.331 137.395 120 107.177 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.384 0.326 0.259 107.630 121 107.437 135-01-3 Q10 1,2-Diethylbenzene 0.085 0.072 0.057 23.801 122 107.889 ? Unidentified 0.081 0.081 0.047 26.540 123 108.027 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.158 0.135 0.107 44.207 124 108.164 ? Unidentified 0.091 0.092 0.054 29.965 125 108.246 ? Unidentified 0.086 0.086 0.050 28.119 126 108.368 I11 C11- Isoparaffin-11 0.660 0.662 0.383 174.791

127 108.551 ? Unidentified 0.225 0.226 0.131 74.011 128 108.881 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.384 0.327 0.260 107.763 129 108.988 ? Unidentified 0.967 0.823 0.654 317.913

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 109.204 J10 2-Methylindan 0.144 0.111 0.099 41.208 131 109.550 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 1.078 0.921 0.729 302.324 132 110.102 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.681 0.571 0.460 190.938 133 110.529 ? Unidentified 0.019 0.018 0.011 6.391 134 110.731 ? Unidentified 0.045 0.045 0.029 14.765 135 110.860 ? Unidentified 0.068 0.069 0.044 22.412 136 111.008 Q11 1-Methyl-4-t-butylbenzene 0.122 0.107 0.074 33.957 137 111.223 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.435 0.364 0.294 122.052 138 111.533 1120-21-4 P11 n-Undecane 0.099 0.099 0.057 26.223 139 111.690 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.109 0.091 0.066 30.315

140 111.800 ? Unidentified 0.053 0.045 0.033 17.543 141 111.905 Q11 C11 - Aromatic - 1 0.027 0.023 0.017 7.629 142 112.170 Q10 1,2,4,5-Tetramethylbenzene 0.902 0.759 0.610 252.910 143 112.439 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 1.247 1.046 0.842 349.483 144 112.636 ? Unidentified 0.016 0.013 0.010 5.132 145 112.791 ? Unidentified 0.020 0.015 0.012 6.457 146 112.968 I12 C12 - IsoParaffin - 1 0.025 0.026 0.014 6.743 147 113.292 ? Unidentified 0.046 0.047 0.026 15.206 148 113.450 ? Unidentified 0.009 0.009 0.005 2.913 149 113.583 Q11 C11 - Aromatic - 3 0.169 0.142 0.104 47.309

150 113.765 874-35-1 H10 5-Methylindan 0.372 0.312 0.255 104.301 151 113.905 Q12 1,2-Di-i-propylbenzene 0.162 0.136 0.091 45.078 152 114.119 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.230 0.193 0.141 64.194 153 114.278 Q11 C11 - Aromatic - 4 0.114 0.096 0.070 31.873 154 114.518 824-22-6 J10 4-Methylindan 0.516 0.433 0.354 144.733 155 114.680 ? Unidentified 0.121 0.101 0.074 39.611 156 114.768 824-63-5 H10 2-Methylindan 0.384 0.322 0.263 107.582 157 114.979 ? Unidentified 0.041 0.034 0.025 13.462 158 115.091 538-68-1 Q11 n-Pentylbenzene 0.057 0.048 0.035 15.895 159 115.322 Q11 tert-Pentylbenzene 0.235 0.197 0.144 65.468

160 115.633 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.104 0.088 0.064 29.161 161 115.743 Q11 C11 - Aromatic - 7 0.133 0.117 0.081 37.116 162 116.074 I12 C12 - IsoParaffin - 4 0.008 0.008 0.004 2.262 163 116.206 100-18-5 Q12 1,4-Di-i-propylbenzene 0.196 0.164 0.109 54.436 164 116.633 91-20-3 G10 Naphthalene 0.234 0.170 0.165 68.549 165 116.842 J11 4,7-Dimethyl Indane 0.014 0.011 0.008 3.888 166 117.081 J11 1,1-Dimethyl Indane 0.055 0.042 0.034 15.707 167 117.250 J12 Dimethyl Indane - 1 0.019 0.015 0.012 5.461 168 117.431 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.027 0.023 0.015 7.636 169 117.565 J12 Dimethyl Indane - 2 0.006 0.004 0.004 1.643

170 117.736 Q12 1,3-Di-n-propylbenzene 0.141 0.118 0.079 39.207 171 117.847 Q11 C11 - Aromatic - 11 0.078 0.068 0.047 21.663 172 118.401 Q11 C11 - Aromatic - 12 0.043 0.038 0.026 12.064

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 119.031 Q11 C11 - Aromatic - 13 0.006 0.005 0.004 1.658 174 119.341 102-25-0 Q12 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.628 175 123.282 91-57-6 G11 2-Methylnaphthalene 0.012 0.009 0.008 3.511 176 124.148 90-12-0 G11 1-Methylnaphthalene 0.007 0.005 0.004 1.909 177 129.863 ? Unidentified 0.004 0.003 0.002 1.349

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.389 74-98-6 Propane 0.001 0.002 0.002 0.273

9.789 106-97-8 n-Butane 4.275 5.515 6.671 1107.495 17.687 109-66-0 n-Pentane 2.361 2.815 2.968 615.837 35.316 110-54-3 n-Hexane 6.582 7.454 6.928 1723.994 57.612 142-82-5 n-Heptane 0.454 0.495 0.411 119.286 77.561 111-65-9 n-Octane 0.122 0.129 0.097 32.043 91.506 111-84-2 n-Nonane 0.031 0.032 0.022 8.054 102.658 124-18-5 n-Decane 0.043 0.044 0.028 11.467 111.533 1120-21-4 n-Undecane 0.099 0.099 0.057 26.223

I-Paraffins 8.609 75-28-5 i-Butane 0.038 0.052 0.060 9.972

10.385 463-82-1 2,2-Dimethylpropane 0.044 0.055 0.055 11.450 14.712 78-78-4 i-Pentane 12.200 14.703 15.338 3182.770 22.607 75-83-2 2,2-Dimethylbutane 0.153 0.175 0.161 39.957 27.820 79-29-8 2,3-Dimethylbutane 0.607 0.686 0.639 159.095 28.904 107-83-5 2-Methylpentane 3.380 3.864 3.558 885.263 31.550 96-14-0 3-Methylpentane 3.158 3.550 3.324 827.082 41.728 108-08-7 2,4-Dimethylpentane 0.393 0.436 0.356 103.315 42.268 464-06-2 2,2,3-Trimethylbutane 0.057 0.062 0.052 15.032 50.186 591-76-4 2-Methylhexane 1.062 1.168 0.961 279.191 52.025 589-34-4 3-Methylhexane 0.621 0.675 0.562 163.233 54.687 540-84-1 2,2,4-Trimethylpentane 0.016 0.017 0.013 4.154 64.744 592-13-2 2,5-Dimethylhexane 0.019 0.021 0.015 5.133 65.083 589-43-5 2,4-Dimethylhexane 0.026 0.028 0.021 6.837 70.427 584-94-1 2,3-Dimethylhexane 0.016 0.017 0.013 4.176 71.695 592-27-8 2-Methylheptane 0.072 0.077 0.057 18.891 71.947 589-53-7 4-Methylheptane 0.031 0.033 0.025 8.180 73.019 589-81-1 3-Methylheptane 0.068 0.072 0.054 17.960 73.201 619-99-8 3-Ethylhexane 0.038 0.040 0.030 9.984 82.193 1072-05-5 2,6-Dimethylheptane 0.007 0.007 0.005 1.855 83.130 2,5-Dimethylheptane 0.007 0.008 0.005 1.931 87.016 2216-34-4 4-Methyloctane 0.009 0.010 0.007 2.434 87.148 3221-61-2 2-Methyloctane 0.012 0.013 0.009 3.191 88.012 2216-33-3 3-Methyloctane 0.013 0.013 0.009 3.389 95.264 2051-30-1 2,4-Dimethyloctane 0.010 0.010 0.006 2.570 98.680 17301-94-8 4-Methylnonane 0.006 0.006 0.004 1.635 98.881 2,2,6-Trimethyloctane 0.378 0.388 0.241 99.894 99.659 5911-04-6 3-Methylnonane 0.009 0.009 0.006 2.374 100.476 C11-Isoparaffin-2 0.046 0.046 0.026 12.073 102.106 17302-01-1 3-Ethyl-3-methylheptane 0.103 0.103 0.060 27.186 104.191 C11 Isoparaffin-4 0.016 0.016 0.009 4.231 106.150 C11-Isoparaffin-7 0.311 0.312 0.181 82.415 108.368 C11- Isoparaffin-11 0.660 0.662 0.383 174.791 112.968 C12 - IsoParaffin - 1 0.025 0.026 0.014 6.743 116.074 C12 - IsoParaffin - 4 0.008 0.008 0.004 2.262

Aromatics Mono-Aromatics 45.129 71-42-3 Benzene 0.657 0.558 0.763 189.866

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 68.705 108-88-3 Toluene 17.964 15.471 17.684 5134.580

84.452 100-41-4 Ethylbenzene 2.515 2.166 2.148 713.310 85.699 108-38-3 m-Xylene 6.074 5.248 5.189 1722.882 85.842 106-42-3 p-Xylene 2.846 2.468 2.432 807.379 88.660 95-47-6 o-Xylene 1.700 1.442 1.452 482.170 92.837 98-82-8 i-Propylbenzene 0.035 0.031 0.027 9.922 96.303 103-65-1 n-Propylbenzene 0.188 0.163 0.142 52.919 97.149 620-14-4 1-Methyl-3-ethylbenzene 0.686 0.592 0.518 193.320 97.384 622-96-8 1-Methyl-4-ethylbenzene 0.325 0.282 0.246 91.710 98.011 108-67-8 1,3,5-Trimethylbenzene 0.420 0.362 0.317 118.327 99.096 611-14-3 1-Methyl-2-ethylbenzene 0.272 0.230 0.205 76.615 100.730 95-63-6 1,2,4-Trimethylbenzene 1.375 1.172 1.038 387.549 102.464 538-93-2 i-Butylbenzene 0.127 0.111 0.086 35.470 103.609 526-73-8 1,2,3-Trimethylbenzene 0.316 0.264 0.239 89.141 103.996 535-77-3 1-Methyl-3-i-propylbenzene 0.018 0.015 0.012 4.966 106.333 141-93-5 1,3-Diethylbenzene 0.080 0.069 0.054 22.408 106.623 1074-43-7 1-Methyl-3-n-propylbenzene 1.065 0.924 0.720 298.653 106.949 105-05-5 1,4-Diethylbenzene 0.490 0.425 0.331 137.395 107.177 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.384 0.326 0.259 107.630 107.437 135-01-3 1,2-Diethylbenzene 0.085 0.072 0.057 23.801 108.027 1074-17-5 1-Methyl-2-n-propylbenzene 0.158 0.135 0.107 44.207 108.881 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.384 0.327 0.260 107.763 109.550 934-80-5 1,2-Dimethyl-4-ethylbenzene 1.078 0.921 0.729 302.324 110.102 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.681 0.571 0.460 190.938 111.008 1-Methyl-4-t-butylbenzene 0.122 0.107 0.074 33.957 111.223 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.435 0.364 0.294 122.052 111.690 4218-48-8 1-Ethyl-4-i-propylbenzene 0.109 0.091 0.066 30.315 111.905 C11 - Aromatic - 1 0.027 0.023 0.017 7.629 112.170 1,2,4,5-Tetramethylbenzene 0.902 0.759 0.610 252.910 112.439 527-53-7 1,2,3,5-Tetramethylbenzene 1.247 1.046 0.842 349.483 113.583 C11 - Aromatic - 3 0.169 0.142 0.104 47.309 113.905 1,2-Di-i-propylbenzene 0.162 0.136 0.091 45.078 114.119 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.230 0.193 0.141 64.194 114.278 C11 - Aromatic - 4 0.114 0.096 0.070 31.873 115.091 538-68-1 n-Pentylbenzene 0.057 0.048 0.035 15.895 115.322 tert-Pentylbenzene 0.235 0.197 0.144 65.468 115.633 577-55-9 1-Methyl-2-n-butylbenzene 0.104 0.088 0.064 29.161 115.743 C11 - Aromatic - 7 0.133 0.117 0.081 37.116 116.206 100-18-5 1,4-Di-i-propylbenzene 0.196 0.164 0.109 54.436 117.431 7364-19-4 1t-Butyl-4-ethylbenzene 0.027 0.023 0.015 7.636 117.736 1,3-Di-n-propylbenzene 0.141 0.118 0.079 39.207 117.847 C11 - Aromatic - 11 0.078 0.068 0.047 21.663 118.401 C11 - Aromatic - 12 0.043 0.038 0.026 12.064 119.031 C11 - Aromatic - 13 0.006 0.005 0.004 1.658 119.341 102-25-0 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.628

Naphthalenes 116.633 91-20-3 Naphthalene 0.234 0.170 0.165 68.549

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphthalenes 123.282 91-57-6 2-Methylnaphthalene 0.012 0.009 0.008 3.511

124.148 90-12-0 1-Methylnaphthalene 0.007 0.005 0.004 1.909

Naphtheno/Olefino-Benzs

113.765 874-35-1 5-Methylindan 0.372 0.312 0.255 104.301 114.768 824-63-5 2-Methylindan 0.384 0.322 0.263 107.582

Indenes 104.800 Indan 0.138 0.107 0.106 39.478

105.432 Indene 0.703 0.545 0.540 201.463 109.204 2-Methylindan 0.144 0.111 0.099 41.208 114.518 824-22-6 4-Methylindan 0.516 0.433 0.354 144.733 116.842 4,7-Dimethyl Indane 0.014 0.011 0.008 3.888 117.081 1,1-Dimethyl Indane 0.055 0.042 0.034 15.707 117.250 Dimethyl Indane - 1 0.019 0.015 0.012 5.461 117.565 Dimethyl Indane - 2 0.006 0.004 0.004 1.643

Naphthenes Mono-Naphthenes 27.089 287-92-3 Cyclopentane 0.242 0.242 0.313 64.950

40.158 96-37-7 Methylcyclopentane 2.720 2.713 2.931 729.812 47.053 110-82-7 Cyclohexane 1.686 1.617 1.817 452.441 52.878 1759-58-6 1t,3-Dimethylcyclopentane 0.136 0.136 0.126 36.581 53.463 2532-58-3 1c,3-Dimethylcyclopentane 0.106 0.106 0.098 28.491 54.092 822-50-4 1t,2-Dimethylcyclopentane 0.147 0.146 0.136 39.552 61.058 108-87-2 Methylcyclohexane 0.660 0.641 0.610 177.137 62.011 4516-69-2 1,1,3-Trimethylcyclopentane 0.013 0.013 0.011 3.587 63.855 1640-89-7 Ethylcyclopentane 0.023 0.022 0.021 6.158 72.859 1,3-dimethyl-t-cyclohexane 0.056 0.054 0.045 14.932 76.187 2207-03-6 1t,3-Dimethylcyclohexane 0.022 0.022 0.018 6.012 81.867 1678-91-7 Ethylcyclohexane 0.026 0.025 0.021 6.986 101.319 1678-98-4 i-Butylcyclohexane 0.008 0.008 0.005 2.164

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.400 115-11-7 Isobutene 0.022 0.027 0.035 5.822

9.439 106-98-9 Butene-1 0.025 0.032 0.041 6.821 10.262 624-64-6 t-Butene-2 0.094 0.116 0.152 25.244 10.983 590-18-1 c-Butene-2 0.106 0.128 0.172 28.488 16.328 109-67-1 Pentene-1 0.336 0.392 0.435 90.275 18.790 646-04-8 t-Pentene-2 0.870 1.002 1.125 233.318 19.814 627-20-3 c-Pentene-2 0.476 0.542 0.616 127.733 32.933 592-41-6 Hexene-1 0.161 0.177 0.174 43.204 35.930 13269-52-8 t-Hexene-3 0.270 0.296 0.291 72.486 36.401 4050-45-7 t-Hexene-2 0.512 0.560 0.552 137.416 38.232 7688-21-3 c-Hexene-2 0.217 0.235 0.234 58.349 56.880 14686-14-7 t-Heptene-3 0.017 0.018 0.015 4.489

Iso-Olefins 13.123 563-45-1 3-Methylbutene-1 0.073 0.087 0.094 19.585

17.164 563-46-2 2-Methylbutene-1 0.527 0.605 0.681 141.339

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 20.484 513-35-9 2-Methylbutene-2 1.089 1.228 1.409 292.249

28.680 691-38-3 4-Methyl-c-pentene-2 0.046 0.051 0.049 12.318 29.330 674-76-0 4-Methyl-t-pentene-2 0.138 0.153 0.149 36.992 32.709 763-29-1 2-Methylpentene-1 0.236 0.257 0.254 63.324 36.894 625-27-4 2-Methylpentene-2 0.359 0.388 0.387 96.358 37.305 922-62-3 3-Methyl-c-pentene-2 0.275 0.294 0.296 73.686 39.579 3404-73-7 3,3-Dimethylpentene-1 0.326 0.347 0.302 87.579 42.033 594-56-9 2,3,3-Trimethylbutene-1 0.012 0.013 0.011 3.217 46.153 3404-61-3 3-Methylhexene-1 0.013 0.014 0.012 3.391 46.738 3524-73-0 5-Methylhexene-1 0.083 0.089 0.077 22.306 48.798 15840-60-5 2-Methyl-c-hexene-3 0.032 0.034 0.029 8.532 49.792 3404-55-5 4-Methyl-t/c-hexene-2 0.037 0.040 0.035 10.022 57.233 6094-02-6 2-Methylhexene-1 0.026 0.028 0.024 6.915 58.111 2738-19-4 2-Methyl-2-hexene 0.005 0.006 0.005 1.462

Naphtheno-Olefins 25.241 142-29-0 Cyclopentene 0.190 0.184 0.253 52.437

45.332 693-89-0 1-Methylcyclopentene 0.337 0.323 0.372 92.688 50.663 110-83-8 Cyclohexene 0.036 0.033 0.039 9.536

Di-Olefins 18.201 78-79-5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.543

20.815 2004-70-8 1t,3-Pentadiene 0.014 0.015 0.018 3.762

Oxygenates 26.483 71-23-8 n-Propanol 0.188 0.175 0.283 35.238

Unidentified 19.431 Unidentified 0.006 0.007 0.008 2.094

28.223 Unidentified 0.054 0.054 0.055 17.624 44.924 Unidentified 0.011 0.011 0.012 3.559 47.587 Unidentified 0.029 0.031 0.027 9.598 74.100 Unidentified 0.008 0.008 0.007 2.767 100.126 Unidentified 0.028 0.021 0.016 9.328 100.251 Unidentified 0.085 0.086 0.050 28.048 100.940 Unidentified 0.065 0.069 0.042 21.235 101.061 Unidentified 0.037 0.037 0.023 12.035 102.974 Unidentified 0.028 0.028 0.016 9.148 104.393 Unidentified 0.101 0.088 0.068 33.104 107.889 Unidentified 0.081 0.081 0.047 26.540 108.164 Unidentified 0.091 0.092 0.054 29.965 108.246 Unidentified 0.086 0.086 0.050 28.119 108.551 Unidentified 0.225 0.226 0.131 74.011 108.988 Unidentified 0.967 0.823 0.654 317.913 110.529 Unidentified 0.019 0.018 0.011 6.391 110.731 Unidentified 0.045 0.045 0.029 14.765 110.860 Unidentified 0.068 0.069 0.044 22.412 111.800 Unidentified 0.053 0.045 0.033 17.543 112.636 Unidentified 0.016 0.013 0.010 5.132 112.791 Unidentified 0.020 0.015 0.012 6.457 113.292 Unidentified 0.046 0.047 0.026 15.206

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 113.450 Unidentified 0.009 0.009 0.005 2.913

114.680 Unidentified 0.121 0.101 0.074 39.611 114.979 Unidentified 0.041 0.034 0.025 13.462 129.863 Unidentified 0.004 0.003 0.002 1.349

Plus

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

2,2-Dimethylbutane

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Methylcyclohexane

1,1,3-Trimethylcyclopentane

Ethylcyclopentane

2,5-Dimethylhexane 2,4-Dimethylhexane

Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane

1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF95.090.085.080.075.0

1t,3-Dimethylcyclohexane

n-Octane

Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene

m-Xylene p-Xylene

4-Methyloctane 2-Methyloctane

3-Methyloctane o-Xylene

n-Nonane

i-Propylbenzene

2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2

1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan

1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified C11 - Aromatic - 1

1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene Dimethyl Indane - 2 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12
C11 - Aromatic - 13 1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF Sample: ODDB-91316 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91316 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000012.D\SIG1000012_FID1_A.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 7.718 9.218 8.649

I-Paraffins 23.428 26.796 21.984

Aromatics 45.586 40.064 37.081 Mono-Aromatics 42.844 37.837 35.128 Naphthalenes 0.254 0.191 0.175 Naphtheno/Olefino-Benzs 0.547 0.472 0.367 Indenes 1.940 1.565 1.411

Naphthenes 4.162 4.207 4.320 Mono-Naphthenes 4.162 4.207 4.320 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.986 7.948 8.103 n-Olefins 2.929 3.406 3.495 Iso-Olefins 3.450 3.941 3.905 Naphtheno-Olefins 0.582 0.573 0.670 Di-Olefins 0.025 0.028 0.032

Oxygenates 8.722 8.486 16.720

Unidentified 3.398 3.280 3.143

Plus 0.000 0.000 0.000

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 8.550 8.321 16.466 C3 0.173 0.166 0.255 C4 1.272 1.676 1.951 C5 8.985 10.805 11.192 C6 21.874 24.679 22.737 C7 15.823 14.791 14.981 C8 13.542 12.311 11.224 C9 11.871 10.586 8.731 C10 11.539 10.538 7.609 C11 2.566 2.492 1.487 C12 0.408 0.355 0.224

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.001 C4 1.079 1.431 1.646 C5 1.652 2.025 2.031 C6 4.380 5.100 4.509 C7 0.285 0.320 0.252 C8 0.053 0.058 0.041 C9 0.069 0.074 0.048 C10 0.102 0.108 0.064 C11 0.097 0.101 0.055

I-Paraffins C4 0.015 0.021 0.023 C5 3.492 4.329 4.295 C6 11.292 13.190 11.626 C7 1.869 2.110 1.655 C8 1.493 1.612 1.160 C9 0.695 0.752 0.481 C10 3.040 3.204 1.877 C11 1.505 1.554 0.854 C12 0.026 0.027 0.013

Mono-Aromatics C6 0.645 0.564 0.733 C7 12.177 10.785 11.726 C8 11.951 10.597 9.987 C9 10.810 9.524 7.980 C10 6.002 5.270 3.968 C11 0.897 0.785 0.537 C12 0.361 0.312 0.198

Naphthalenes C10 0.246 0.184 0.170 C11 0.009 0.007 0.005

Naphtheno/Olefino-Benzs C10 0.547 0.472 0.367

Indenes C9 0.296 0.236 0.222 C10 1.566 1.267 1.141 C11 0.057 0.046 0.035 C12 0.021 0.017 0.013

Mono-Naphthenes C5 0.296 0.305 0.375 C6 3.100 3.128 3.268 C7 0.687 0.695 0.620 C8 0.045 0.044 0.035

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.035 0.034 0.022

n-Olefins C4 0.178 0.224 0.282 C5 1.554 1.840 1.966 C6 1.099 1.234 1.159 C7 0.098 0.107 0.088

Iso-Olefins C5 1.778 2.092 2.249 C6 0.964 1.076 1.017 C7 0.708 0.774 0.640

Naphtheno-Olefins C5 0.188 0.187 0.244 C6 0.394 0.387 0.426

Di-Olefins C5 0.025 0.028 0.032

Oxygenates C2 8.550 8.321 16.466 C3 0.172 0.165 0.254

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 25.05 23.86 5% 81.79 80.86 10% 111.42 97.15 15% 138.92 137.68 20% 144.65 139.76 25% 154.67 145.26 30% 161.16 154.79 35% 172.76 160.79 40% 176.42 172.76 45% 229.82 176.69 50% 230.34 228.56 55% 230.86 230.39 60% 276.01 230.97 65% 281.34 277.06 70% 291.64 281.77 75% 322.60 320.72 80% 332.52 329.36 85% 341.97 335.97 90% 362.56 359.10 95% 372.56 368.14 FBP 404.60 404.60

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.386 74-98-6 P3 Propane 0.001 0.001 0.001 0.159 2 8.607 75-28-5 I4 i-Butane 0.015 0.021 0.023 4.223 3 9.399 115-11-7 K4 Isobutene 0.014 0.018 0.022 4.074 4 9.438 106-98-9 K4 Butene-1 0.017 0.022 0.027 4.884 5 9.787 106-97-8 P4 n-Butane 1.079 1.431 1.646 300.047 6 10.261 624-64-6 K4 t-Butene-2 0.067 0.086 0.107 19.405 7 10.383 463-82-1 I5 2,2-Dimethylpropane 0.009 0.012 0.011 2.575 8 10.981 590-18-1 K4 c-Butene-2 0.080 0.099 0.126 22.975 9 12.739 64-17-5 X2 Ethanol 8.550 8.321 16.466 1058.804 10 13.119 563-45-1 C5 3-Methylbutene-1 0.315 0.386 0.399 90.871

11 14.701 78-78-4 I5 i-Pentane 3.483 4.317 4.283 975.682 12 16.325 109-67-1 K5 Pentene-1 0.315 0.377 0.398 90.649 13 17.162 563-46-2 C5 2-Methylbutene-1 0.478 0.564 0.604 137.656 14 17.687 109-66-0 P5 n-Pentane 1.652 2.025 2.031 462.691 15 18.199 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 2.927 16 18.792 646-04-8 K5 t-Pentene-2 0.801 0.949 1.013 230.692 17 19.812 627-20-3 K5 c-Pentene-2 0.439 0.514 0.556 126.522 18 20.482 513-35-9 C5 2-Methylbutene-2 0.985 1.141 1.245 283.664 19 20.812 2004-70-8 E5 1t,3-Pentadiene 0.015 0.017 0.019 4.358 20 22.061 ? Unidentified 0.006 0.006 0.007 1.971

21 22.606 75-83-2 I6 2,2-Dimethylbutane 0.294 0.348 0.303 82.714 22 25.241 142-29-0 B5 Cyclopentene 0.188 0.187 0.244 55.667 23 26.486 71-23-8 X3 n-Propanol 0.172 0.165 0.254 34.733 24 27.094 287-92-3 M5 Cyclopentane 0.296 0.305 0.375 85.306 25 27.826 79-29-8 I6 2,3-Dimethylbutane 1.092 1.268 1.124 307.138 26 28.226 ? Unidentified 0.048 0.050 0.049 17.082 27 28.687 691-38-3 C6 4-Methyl-c-pentene-2 0.041 0.046 0.043 11.671 28 28.926 107-83-5 I6 2-Methylpentane 6.264 7.365 6.449 1761.717 29 29.334 674-76-0 C6 4-Methyl-t-pentene-2 0.126 0.143 0.133 36.232 30 31.558 96-14-0 I6 3-Methylpentane 3.641 4.209 3.749 1024.040

31 32.713 763-29-1 C6 2-Methylpentene-1 0.215 0.241 0.226 61.837 32 32.937 592-41-6 K6 Hexene-1 0.154 0.175 0.163 44.483 33 35.310 110-54-3 P6 n-Hexane 4.380 5.100 4.509 1231.787 34 35.932 13269-52-8 K6 t-Hexene-3 0.253 0.285 0.267 72.835 35 36.406 4050-45-7 K6 t-Hexene-2 0.486 0.547 0.513 140.069 36 36.898 625-27-4 C6 2-Methylpentene-2 0.329 0.365 0.347 94.769 37 37.310 922-62-3 C6 3-Methyl-c-pentene-2 0.255 0.280 0.268 73.371 38 38.235 7688-21-3 K6 c-Hexene-2 0.206 0.228 0.217 59.259 39 39.585 3404-73-7 C7 3,3-Dimethylpentene-1 0.303 0.331 0.274 87.250 40 40.158 96-37-7 M6 Methylcyclopentane 1.799 1.845 1.896 518.281

41 41.732 108-08-7 I7 2,4-Dimethylpentane 0.331 0.377 0.293 93.328 42 42.035 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.936 43 42.272 464-06-2 I7 2,2,3-Trimethylbutane 0.047 0.053 0.042 13.359

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 44.931 ? Unidentified 0.012 0.012 0.013 4.090 45 45.132 71-42-3 Q6 Benzene 0.645 0.564 0.733 200.223 46 45.337 693-89-0 B6 1-Methylcyclopentene 0.351 0.346 0.379 103.600 47 46.157 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.014 4.490 48 46.743 3524-73-0 C7 5-Methylhexene-1 0.071 0.078 0.064 20.387 49 47.057 110-82-7 M6 Cyclohexane 1.301 1.283 1.371 374.784 50 47.594 3404-72-6 C7 1-Pentene, 2,3-dimethyl- 0.041 0.045 0.037 11.767 51 48.804 15840-60-5 C7 2-Methyl-c-hexene-3 0.039 0.043 0.035 11.187 52 49.148 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.010 3.218 53 49.793 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.054 0.045 14.264

54 50.191 591-76-4 I7 2-Methylhexane 0.946 1.070 0.837 266.976 55 50.668 110-83-8 B6 Cyclohexene 0.043 0.041 0.047 12.431 56 52.029 589-34-4 I7 3-Methylhexane 0.546 0.610 0.484 154.186 57 52.880 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.132 0.135 0.119 37.906 58 53.467 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.096 0.099 0.087 27.606 59 54.091 822-50-4 M7 1t,2-Dimethylcyclopentane 0.122 0.124 0.110 35.025 60 54.391 C7 C7 - Iso-Olefin - 2 0.022 0.024 0.020 6.338 61 54.684 540-84-1 I8 2,2,4-Trimethylpentane 0.048 0.053 0.037 13.557 62 55.023 592-76-7 K7 Heptene-1 0.028 0.031 0.026 8.132 63 56.358 4914-89-0 C7 3-Methyl-c-hexene-3 0.013 0.014 0.012 3.869

64 56.879 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.028 9.019 65 57.241 6094-02-6 C7 2-Methylhexene-1 0.056 0.062 0.051 16.117 66 57.612 142-82-5 P7 n-Heptane 0.285 0.320 0.252 80.332 67 57.832 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.022 6.946 68 58.111 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.023 7.410 69 58.355 3899-36-3 C7 3-Methyl-t-hexene-3 0.020 0.022 0.018 5.647 70 58.741 14686-13-6 K7 t-Heptene-2 0.014 0.015 0.013 4.010 71 59.199 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.016 5.067 72 59.641 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.014 4.308 73 60.425 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.012 3.765

74 61.054 108-87-2 M7 Methylcyclohexane 0.308 0.307 0.278 88.705 75 63.099 ? Unidentified 0.021 0.022 0.017 7.297 76 63.854 1640-89-7 M7 Ethylcyclopentane 0.012 0.012 0.011 3.490 77 64.504 ? Unidentified 0.059 0.064 0.046 20.937 78 64.742 592-13-2 I8 2,5-Dimethylhexane 0.135 0.150 0.105 38.210 79 65.081 589-43-5 I8 2,4-Dimethylhexane 0.126 0.138 0.098 35.610 80 68.080 565-75-3 I8 2,3,4-Trimethylpentane 0.806 0.861 0.626 228.114 81 68.666 108-88-3 Q7 Toluene 12.177 10.785 11.726 3737.342 82 70.423 584-94-1 I8 2,3-Dimethylhexane 0.224 0.241 0.174 63.268 83 71.693 592-27-8 I8 2-Methylheptane 0.048 0.052 0.037 13.473

84 71.954 589-53-7 I8 4-Methylheptane 0.043 0.047 0.033 12.104 85 72.088 ? Unidentified 0.021 0.022 0.016 7.318 86 72.858 M8 1,3-dimethyl-t-cyclohexane 0.022 0.022 0.017 6.349

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 73.017 589-81-1 I8 3-Methylheptane 0.046 0.050 0.036 13.078 88 73.196 619-99-8 I8 3-Ethylhexane 0.018 0.019 0.014 5.079 89 74.919 3522-94-9 I9 2,2,5-Trimethylhexane 0.520 0.565 0.360 147.522 90 76.186 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.009 0.009 0.007 2.691 91 77.560 111-65-9 P8 n-Octane 0.053 0.058 0.041 15.111 92 78.505 ? Unidentified 0.014 0.014 0.011 4.905 93 80.053 1069-53-0 I9 2,3,5-Trimethylhexane 0.090 0.096 0.062 25.466 94 81.231 1071-26-7 I9 2,4-Dimethylheptane 0.014 0.015 0.009 3.862 95 81.865 1678-91-7 M8 Ethylcyclohexane 0.013 0.013 0.011 3.837 96 82.193 1072-05-5 I9 2,6-Dimethylheptane 0.020 0.022 0.014 5.736

97 83.129 I9 2,5-Dimethylheptane 0.043 0.046 0.030 12.123 98 84.449 100-41-4 Q8 Ethylbenzene 2.212 1.959 1.849 673.769 99 85.698 108-38-3 Q8 m-Xylene 5.682 5.049 4.749 1730.792 100 85.840 106-42-3 Q8 p-Xylene 2.586 2.306 2.161 787.582 101 88.011 2216-33-3 I9 3-Methyloctane 0.008 0.009 0.006 2.369 102 88.479 ? Unidentified 0.031 0.035 0.022 11.052 103 88.657 95-47-6 Q8 o-Xylene 1.471 1.283 1.229 447.970 104 89.064 I10 C10 - IsoParaffin - 1 0.108 0.114 0.068 30.799 105 89.910 14720-74-2 I10 2,2,4-trimethylheptane 0.076 0.080 0.047 21.586 106 91.463 111-84-2 P9 n-Nonane 0.069 0.074 0.048 19.654

107 92.836 98-82-8 Q9 i-Propylbenzene 0.032 0.029 0.024 9.820 108 93.600 ? Unidentified 0.078 0.083 0.049 27.637 109 93.823 15869-87-1 I10 2,2-Dimethyloctane 0.028 0.029 0.017 7.829 110 94.265 ? Unidentified 0.011 0.009 1.002 3.987 111 94.265 ? Unidentified 0.011 0.012 0.007 3.987 112 94.621 15869-89-3 I10 2,5-Dimethyloctane 0.064 0.067 0.040 18.208 113 95.101 2040-95-1 I10 2,7-Dimethyloctane 0.028 0.029 0.017 7.876 114 95.266 2051-30-1 I10 2,4-Dimethyloctane 0.126 0.133 0.078 35.702 115 95.663 I10 2,6-Dimethyloctane 0.038 0.040 0.023 10.683 116 96.307 103-65-1 Q9 n-Propylbenzene 0.540 0.481 0.399 163.527

117 97.165 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.178 1.935 1.608 659.245 118 97.395 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.026 0.915 0.757 310.465 119 98.021 108-67-8 Q9 1,3,5-Trimethylbenzene 1.362 1.209 1.006 412.315 120 98.499 15869-85-9 I10 5-Methylnonane 0.010 0.010 0.006 2.777 121 98.690 17301-94-8 I10 4-Methylnonane 0.023 0.024 0.014 6.550 122 98.896 I10 2,2,6-Trimethyloctane 2.172 2.296 1.354 616.965 123 99.103 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.807 0.703 0.595 244.090 124 99.470 ? Unidentified 0.005 0.005 0.003 1.784 125 99.664 5911-04-6 I10 3-Methylnonane 0.033 0.035 0.021 9.423 126 99.843 ? Unidentified 0.006 0.006 0.004 2.067

127 100.130 ? Unidentified 0.127 0.098 0.072 44.950 128 100.258 ? Unidentified 0.361 0.372 0.205 127.351 129 100.480 I11 C11-Isoparaffin-2 0.192 0.198 0.109 54.676

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 100.758 95-63-6 Q9 1,2,4-Trimethylbenzene 4.131 3.622 3.049 1250.078 131 100.944 ? Unidentified 0.220 0.241 0.139 77.618 132 101.065 ? Unidentified 0.131 0.137 0.082 46.234 133 101.321 1678-98-4 M10 i-Butylcyclohexane 0.035 0.034 0.022 10.205 134 102.110 17302-01-1 I10 3-Ethyl-3-methylheptane 0.335 0.346 0.190 95.287 135 102.460 538-93-2 Q10 i-Butylbenzene 0.370 0.333 0.245 111.470 136 102.661 124-18-5 P10 n-Decane 0.102 0.108 0.064 29.086 137 102.975 ? Unidentified 0.085 0.087 0.048 29.901 138 103.616 526-73-8 Q9 1,2,3-Trimethylbenzene 0.734 0.630 0.542 222.095 139 103.990 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.036 0.032 0.024 10.803

140 104.191 I11 C11 Isoparaffin-4 0.038 0.040 0.022 10.895 141 104.394 ? Unidentified 0.211 0.189 0.140 74.544 142 104.802 J9 Indan 0.296 0.236 0.222 90.988 143 105.058 I11 C11-Isoparaffin-5 0.020 0.021 0.011 5.758 144 105.437 J10 Indene 1.131 0.901 0.849 347.983 145 106.153 I11 C11-Isoparaffin-7 0.437 0.451 0.248 124.343 146 106.333 141-93-5 Q10 1,3-Diethylbenzene 0.095 0.085 0.063 28.625 147 106.629 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.477 1.318 0.976 444.653 148 106.940 105-05-5 Q10 1,4-Diethylbenzene 0.493 0.439 0.326 148.512 149 107.176 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.298 0.260 0.197 89.714

150 107.430 135-01-3 Q10 1,2-Diethylbenzene 0.099 0.087 0.066 29.908 151 107.889 ? Unidentified 0.100 0.103 0.057 35.174 152 108.026 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.116 0.102 0.077 34.861 153 108.166 ? Unidentified 0.107 0.111 0.062 37.912 154 108.245 ? Unidentified 0.091 0.094 0.052 32.152 155 108.369 I11 C11- Isoparaffin-11 0.817 0.843 0.464 232.339 156 108.551 ? Unidentified 0.260 0.269 0.148 91.943 157 108.986 ? Unidentified 1.060 0.928 0.700 373.988 158 109.204 J10 2-Methylindan 0.144 0.115 0.097 44.389 159 109.547 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.763 0.670 0.504 229.534

160 110.101 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.683 0.589 0.452 205.632 161 110.528 ? Unidentified 0.028 0.026 0.016 9.800 162 110.729 ? Unidentified 0.048 0.050 0.030 16.947 163 110.859 ? Unidentified 0.075 0.077 0.047 26.330 164 111.000 Q11 1-Methyl-4-t-butylbenzene 0.091 0.082 0.055 27.344 165 111.221 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.312 0.269 0.206 93.946 166 111.531 1120-21-4 P11 n-Undecane 0.097 0.101 0.055 27.701 167 111.689 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.099 0.086 0.060 29.800 168 111.798 ? Unidentified 0.064 0.055 0.038 22.505 169 112.166 Q10 1,2,4,5-Tetramethylbenzene 0.547 0.473 0.361 164.526

170 112.433 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.713 0.615 0.471 214.572 171 112.641 ? Unidentified 0.015 0.013 0.009 5.301 172 112.785 ? Unidentified 0.017 0.014 0.010 6.092

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 112.965 I12 C12 - IsoParaffin - 1 0.026 0.027 0.013 7.357 174 113.291 ? Unidentified 0.052 0.055 0.028 18.438 175 113.583 Q11 C11 - Aromatic - 3 0.094 0.081 0.056 28.237 176 113.763 874-35-1 H10 5-Methylindan 0.235 0.203 0.158 70.839 177 113.903 Q12 1,2-Di-i-propylbenzene 0.085 0.073 0.046 25.263 178 114.118 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.123 0.107 0.074 37.010 179 114.275 Q11 C11 - Aromatic - 4 0.071 0.061 0.042 21.163 180 114.514 824-22-6 J10 4-Methylindan 0.291 0.251 0.195 87.481 181 114.766 824-63-5 H10 2-Methylindan 0.311 0.269 0.209 93.740 182 114.979 ? Unidentified 0.023 0.020 0.014 8.140

183 115.089 538-68-1 Q11 n-Pentylbenzene 0.038 0.033 0.023 11.495 184 115.320 Q11 tert-Pentylbenzene 0.130 0.112 0.078 38.972 185 115.632 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.060 0.052 0.036 18.055 186 115.743 Q11 C11 - Aromatic - 7 0.080 0.072 0.048 23.836 187 116.205 100-18-5 Q12 1,4-Di-i-propylbenzene 0.123 0.106 0.067 36.682 188 116.632 91-20-3 G10 Naphthalene 0.246 0.184 0.170 77.392 189 116.841 J11 4,7-Dimethyl Indane 0.014 0.011 0.008 4.183 190 117.091 J11 1,1-Dimethyl Indane 0.044 0.035 0.026 13.403 191 117.249 J12 Dimethyl Indane - 1 0.021 0.017 0.013 6.512 192 117.430 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.028 0.024 0.015 8.268

193 117.737 Q12 1,3-Di-n-propylbenzene 0.107 0.093 0.059 32.110 194 117.845 Q11 C11 - Aromatic - 11 0.060 0.054 0.036 17.968 195 118.401 Q11 C11 - Aromatic - 12 0.043 0.039 0.026 12.929 196 119.028 Q11 C11 - Aromatic - 13 0.007 0.006 0.004 2.108 197 119.340 102-25-0 Q12 1,3,5-Triethylbenzene 0.012 0.011 0.007 3.721 198 119.990 Q12 C12 - Aromatic - 1 0.006 0.005 0.003 1.898 199 123.281 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.005 2.733

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.386 74-98-6 Propane 0.001 0.001 0.001 0.159

9.787 106-97-8 n-Butane 1.079 1.431 1.646 300.047 17.687 109-66-0 n-Pentane 1.652 2.025 2.031 462.691 35.310 110-54-3 n-Hexane 4.380 5.100 4.509 1231.787 57.612 142-82-5 n-Heptane 0.285 0.320 0.252 80.332 77.560 111-65-9 n-Octane 0.053 0.058 0.041 15.111 91.463 111-84-2 n-Nonane 0.069 0.074 0.048 19.654 102.661 124-18-5 n-Decane 0.102 0.108 0.064 29.086 111.531 1120-21-4 n-Undecane 0.097 0.101 0.055 27.701

I-Paraffins 8.607 75-28-5 i-Butane 0.015 0.021 0.023 4.223

10.383 463-82-1 2,2-Dimethylpropane 0.009 0.012 0.011 2.575 14.701 78-78-4 i-Pentane 3.483 4.317 4.283 975.682 22.606 75-83-2 2,2-Dimethylbutane 0.294 0.348 0.303 82.714 27.826 79-29-8 2,3-Dimethylbutane 1.092 1.268 1.124 307.138 28.926 107-83-5 2-Methylpentane 6.264 7.365 6.449 1761.717 31.558 96-14-0 3-Methylpentane 3.641 4.209 3.749 1024.040 41.732 108-08-7 2,4-Dimethylpentane 0.331 0.377 0.293 93.328 42.272 464-06-2 2,2,3-Trimethylbutane 0.047 0.053 0.042 13.359 50.191 591-76-4 2-Methylhexane 0.946 1.070 0.837 266.976 52.029 589-34-4 3-Methylhexane 0.546 0.610 0.484 154.186 54.684 540-84-1 2,2,4-Trimethylpentane 0.048 0.053 0.037 13.557 64.742 592-13-2 2,5-Dimethylhexane 0.135 0.150 0.105 38.210 65.081 589-43-5 2,4-Dimethylhexane 0.126 0.138 0.098 35.610 68.080 565-75-3 2,3,4-Trimethylpentane 0.806 0.861 0.626 228.114 70.423 584-94-1 2,3-Dimethylhexane 0.224 0.241 0.174 63.268 71.693 592-27-8 2-Methylheptane 0.048 0.052 0.037 13.473 71.954 589-53-7 4-Methylheptane 0.043 0.047 0.033 12.104 73.017 589-81-1 3-Methylheptane 0.046 0.050 0.036 13.078 73.196 619-99-8 3-Ethylhexane 0.018 0.019 0.014 5.079 74.919 3522-94-9 2,2,5-Trimethylhexane 0.520 0.565 0.360 147.522 80.053 1069-53-0 2,3,5-Trimethylhexane 0.090 0.096 0.062 25.466 81.231 1071-26-7 2,4-Dimethylheptane 0.014 0.015 0.009 3.862 82.193 1072-05-5 2,6-Dimethylheptane 0.020 0.022 0.014 5.736 83.129 2,5-Dimethylheptane 0.043 0.046 0.030 12.123 88.011 2216-33-3 3-Methyloctane 0.008 0.009 0.006 2.369 89.064 C10 - IsoParaffin - 1 0.108 0.114 0.068 30.799 89.910 14720-74-2 2,2,4-trimethylheptane 0.076 0.080 0.047 21.586 93.823 15869-87-1 2,2-Dimethyloctane 0.028 0.029 0.017 7.829 94.621 15869-89-3 2,5-Dimethyloctane 0.064 0.067 0.040 18.208 95.101 2040-95-1 2,7-Dimethyloctane 0.028 0.029 0.017 7.876 95.266 2051-30-1 2,4-Dimethyloctane 0.126 0.133 0.078 35.702 95.663 2,6-Dimethyloctane 0.038 0.040 0.023 10.683 98.499 15869-85-9 5-Methylnonane 0.010 0.010 0.006 2.777 98.690 17301-94-8 4-Methylnonane 0.023 0.024 0.014 6.550 98.896 2,2,6-Trimethyloctane 2.172 2.296 1.354 616.965 99.664 5911-04-6 3-Methylnonane 0.033 0.035 0.021 9.423

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 100.480 C11-Isoparaffin-2 0.192 0.198 0.109 54.676

102.110 17302-01-1 3-Ethyl-3-methylheptane 0.335 0.346 0.190 95.287 104.191 C11 Isoparaffin-4 0.038 0.040 0.022 10.895 105.058 C11-Isoparaffin-5 0.020 0.021 0.011 5.758 106.153 C11-Isoparaffin-7 0.437 0.451 0.248 124.343 108.369 C11- Isoparaffin-11 0.817 0.843 0.464 232.339 112.965 C12 - IsoParaffin - 1 0.026 0.027 0.013 7.357

Aromatics Mono-Aromatics 45.132 71-42-3 Benzene 0.645 0.564 0.733 200.223

68.666 108-88-3 Toluene 12.177 10.785 11.726 3737.342 84.449 100-41-4 Ethylbenzene 2.212 1.959 1.849 673.769 85.698 108-38-3 m-Xylene 5.682 5.049 4.749 1730.792 85.840 106-42-3 p-Xylene 2.586 2.306 2.161 787.582 88.657 95-47-6 o-Xylene 1.471 1.283 1.229 447.970 92.836 98-82-8 i-Propylbenzene 0.032 0.029 0.024 9.820 96.307 103-65-1 n-Propylbenzene 0.540 0.481 0.399 163.527 97.165 620-14-4 1-Methyl-3-ethylbenzene 2.178 1.935 1.608 659.245 97.395 622-96-8 1-Methyl-4-ethylbenzene 1.026 0.915 0.757 310.465 98.021 108-67-8 1,3,5-Trimethylbenzene 1.362 1.209 1.006 412.315 99.103 611-14-3 1-Methyl-2-ethylbenzene 0.807 0.703 0.595 244.090 100.758 95-63-6 1,2,4-Trimethylbenzene 4.131 3.622 3.049 1250.078 102.460 538-93-2 i-Butylbenzene 0.370 0.333 0.245 111.470 103.616 526-73-8 1,2,3-Trimethylbenzene 0.734 0.630 0.542 222.095 103.990 535-77-3 1-Methyl-3-i-propylbenzene 0.036 0.032 0.024 10.803 106.333 141-93-5 1,3-Diethylbenzene 0.095 0.085 0.063 28.625 106.629 1074-43-7 1-Methyl-3-n-propylbenzene 1.477 1.318 0.976 444.653 106.940 105-05-5 1,4-Diethylbenzene 0.493 0.439 0.326 148.512 107.176 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.298 0.260 0.197 89.714 107.430 135-01-3 1,2-Diethylbenzene 0.099 0.087 0.066 29.908 108.026 1074-17-5 1-Methyl-2-n-propylbenzene 0.116 0.102 0.077 34.861 109.547 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.763 0.670 0.504 229.534 110.101 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.683 0.589 0.452 205.632 111.000 1-Methyl-4-t-butylbenzene 0.091 0.082 0.055 27.344 111.221 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.312 0.269 0.206 93.946 111.689 4218-48-8 1-Ethyl-4-i-propylbenzene 0.099 0.086 0.060 29.800 112.166 1,2,4,5-Tetramethylbenzene 0.547 0.473 0.361 164.526 112.433 527-53-7 1,2,3,5-Tetramethylbenzene 0.713 0.615 0.471 214.572 113.583 C11 - Aromatic - 3 0.094 0.081 0.056 28.237 113.903 1,2-Di-i-propylbenzene 0.085 0.073 0.046 25.263 114.118 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.123 0.107 0.074 37.010 114.275 C11 - Aromatic - 4 0.071 0.061 0.042 21.163 115.089 538-68-1 n-Pentylbenzene 0.038 0.033 0.023 11.495 115.320 tert-Pentylbenzene 0.130 0.112 0.078 38.972 115.632 577-55-9 1-Methyl-2-n-butylbenzene 0.060 0.052 0.036 18.055 115.743 C11 - Aromatic - 7 0.080 0.072 0.048 23.836 116.205 100-18-5 1,4-Di-i-propylbenzene 0.123 0.106 0.067 36.682

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 117.430 7364-19-4 1t-Butyl-4-ethylbenzene 0.028 0.024 0.015 8.268

117.737 1,3-Di-n-propylbenzene 0.107 0.093 0.059 32.110 117.845 C11 - Aromatic - 11 0.060 0.054 0.036 17.968 118.401 C11 - Aromatic - 12 0.043 0.039 0.026 12.929 119.028 C11 - Aromatic - 13 0.007 0.006 0.004 2.108 119.340 102-25-0 1,3,5-Triethylbenzene 0.012 0.011 0.007 3.721 119.990 C12 - Aromatic - 1 0.006 0.005 0.003 1.898

Naphthalenes 116.632 91-20-3 Naphthalene 0.246 0.184 0.170 77.392

123.281 91-57-6 2-Methylnaphthalene 0.009 0.007 0.005 2.733

Naphtheno/Olefino-Benzs

113.763 874-35-1 5-Methylindan 0.235 0.203 0.158 70.839 114.766 824-63-5 2-Methylindan 0.311 0.269 0.209 93.740

Indenes 104.802 Indan 0.296 0.236 0.222 90.988

105.437 Indene 1.131 0.901 0.849 347.983 109.204 2-Methylindan 0.144 0.115 0.097 44.389 114.514 824-22-6 4-Methylindan 0.291 0.251 0.195 87.481 116.841 4,7-Dimethyl Indane 0.014 0.011 0.008 4.183 117.091 1,1-Dimethyl Indane 0.044 0.035 0.026 13.403 117.249 Dimethyl Indane - 1 0.021 0.017 0.013 6.512

Naphthenes Mono-Naphthenes 27.094 287-92-3 Cyclopentane 0.296 0.305 0.375 85.306

40.158 96-37-7 Methylcyclopentane 1.799 1.845 1.896 518.281 47.057 110-82-7 Cyclohexane 1.301 1.283 1.371 374.784 52.880 1759-58-6 1t,3-Dimethylcyclopentane 0.132 0.135 0.119 37.906 53.467 2532-58-3 1c,3-Dimethylcyclopentane 0.096 0.099 0.087 27.606 54.091 822-50-4 1t,2-Dimethylcyclopentane 0.122 0.124 0.110 35.025 59.199 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.016 5.067 61.054 108-87-2 Methylcyclohexane 0.308 0.307 0.278 88.705 63.854 1640-89-7 Ethylcyclopentane 0.012 0.012 0.011 3.490 72.858 1,3-dimethyl-t-cyclohexane 0.022 0.022 0.017 6.349 76.186 2207-03-6 1t,3-Dimethylcyclohexane 0.009 0.009 0.007 2.691 81.865 1678-91-7 Ethylcyclohexane 0.013 0.013 0.011 3.837 101.321 1678-98-4 i-Butylcyclohexane 0.035 0.034 0.022 10.205

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.399 115-11-7 Isobutene 0.014 0.018 0.022 4.074

9.438 106-98-9 Butene-1 0.017 0.022 0.027 4.884 10.261 624-64-6 t-Butene-2 0.067 0.086 0.107 19.405 10.981 590-18-1 c-Butene-2 0.080 0.099 0.126 22.975 16.325 109-67-1 Pentene-1 0.315 0.377 0.398 90.649 18.792 646-04-8 t-Pentene-2 0.801 0.949 1.013 230.692 19.812 627-20-3 c-Pentene-2 0.439 0.514 0.556 126.522 32.937 592-41-6 Hexene-1 0.154 0.175 0.163 44.483

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 35.932 13269-52-8 t-Hexene-3 0.253 0.285 0.267 72.835

36.406 4050-45-7 t-Hexene-2 0.486 0.547 0.513 140.069 38.235 7688-21-3 c-Hexene-2 0.206 0.228 0.217 59.259 55.023 592-76-7 Heptene-1 0.028 0.031 0.026 8.132 56.879 14686-14-7 t-Heptene-3 0.031 0.034 0.028 9.019 57.832 7642-10-6 c-Heptene-3 0.024 0.026 0.022 6.946 58.741 14686-13-6 t-Heptene-2 0.014 0.015 0.013 4.010

Iso-Olefins 13.119 563-45-1 3-Methylbutene-1 0.315 0.386 0.399 90.871

17.162 563-46-2 2-Methylbutene-1 0.478 0.564 0.604 137.656 20.482 513-35-9 2-Methylbutene-2 0.985 1.141 1.245 283.664 28.687 691-38-3 4-Methyl-c-pentene-2 0.041 0.046 0.043 11.671 29.334 674-76-0 4-Methyl-t-pentene-2 0.126 0.143 0.133 36.232 32.713 763-29-1 2-Methylpentene-1 0.215 0.241 0.226 61.837 36.898 625-27-4 2-Methylpentene-2 0.329 0.365 0.347 94.769 37.310 922-62-3 3-Methyl-c-pentene-2 0.255 0.280 0.268 73.371 39.585 3404-73-7 3,3-Dimethylpentene-1 0.303 0.331 0.274 87.250 42.035 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.936 46.157 3404-61-3 3-Methylhexene-1 0.016 0.017 0.014 4.490 46.743 3524-73-0 5-Methylhexene-1 0.071 0.078 0.064 20.387 47.594 3404-72-6 1-Pentene, 2,3-dimethyl- 0.041 0.045 0.037 11.767 48.804 15840-60-5 2-Methyl-c-hexene-3 0.039 0.043 0.035 11.187 49.148 3769-23-1 4-Methylhexene-1 0.011 0.012 0.010 3.218 49.793 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.054 0.045 14.264 54.391 C7 - Iso-Olefin - 2 0.022 0.024 0.020 6.338 56.358 4914-89-0 3-Methyl-c-hexene-3 0.013 0.014 0.012 3.869 57.241 6094-02-6 2-Methylhexene-1 0.056 0.062 0.051 16.117 58.111 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.023 7.410 58.355 3899-36-3 3-Methyl-t-hexene-3 0.020 0.022 0.018 5.647 59.641 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.014 4.308 60.425 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.012 3.765

Naphtheno-Olefins 25.241 142-29-0 Cyclopentene 0.188 0.187 0.244 55.667

45.337 693-89-0 1-Methylcyclopentene 0.351 0.346 0.379 103.600 50.668 110-83-8 Cyclohexene 0.043 0.041 0.047 12.431

Di-Olefins 18.199 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 2.927

20.812 2004-70-8 1t,3-Pentadiene 0.015 0.017 0.019 4.358

Oxygenates 12.739 64-17-5 Ethanol 8.550 8.321 16.466 1058.804

26.486 71-23-8 n-Propanol 0.172 0.165 0.254 34.733

Unidentified 22.061 Unidentified 0.006 0.006 0.007 1.971

28.226 Unidentified 0.048 0.050 0.049 17.082 44.931 Unidentified 0.012 0.012 0.013 4.090 63.099 Unidentified 0.021 0.022 0.017 7.297 64.504 Unidentified 0.059 0.064 0.046 20.937

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 72.088 Unidentified 0.021 0.022 0.016 7.318

78.505 Unidentified 0.014 0.014 0.011 4.905 88.479 Unidentified 0.031 0.035 0.022 11.052 93.600 Unidentified 0.078 0.083 0.049 27.637 94.265 Unidentified 0.011 0.009 1.002 3.987 94.265 Unidentified 0.011 0.012 0.007 3.987 99.470 Unidentified 0.005 0.005 0.003 1.784 99.843 Unidentified 0.006 0.006 0.004 2.067 100.130 Unidentified 0.127 0.098 0.072 44.950 100.258 Unidentified 0.361 0.372 0.205 127.351 100.944 Unidentified 0.220 0.241 0.139 77.618 101.065 Unidentified 0.131 0.137 0.082 46.234 102.975 Unidentified 0.085 0.087 0.048 29.901 104.394 Unidentified 0.211 0.189 0.140 74.544 107.889 Unidentified 0.100 0.103 0.057 35.174 108.166 Unidentified 0.107 0.111 0.062 37.912 108.245 Unidentified 0.091 0.094 0.052 32.152 108.551 Unidentified 0.260 0.269 0.148 91.943 108.986 Unidentified 1.060 0.928 0.700 373.988 110.528 Unidentified 0.028 0.026 0.016 9.800 110.729 Unidentified 0.048 0.050 0.030 16.947 110.859 Unidentified 0.075 0.077 0.047 26.330 111.798 Unidentified 0.064 0.055 0.038 22.505 112.641 Unidentified 0.015 0.013 0.009 5.301 112.785 Unidentified 0.017 0.014 0.010 6.092 113.291 Unidentified 0.052 0.055 0.028 18.438 114.979 Unidentified 0.023 0.020 0.014 8.140

Plus

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2

c-Pentene-2

2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane

2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane1-Pentene, 2,3-dimethyl2-Methyl-c-hexene-3 4-Methylhexene-1 4-Methyl-t/c-hexene-2

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified
Ethylcyclopentane
Unidentified 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane
Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

2,2,5-Trimethylhexane

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF95.090.085.080.075.0

1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene

m-Xylene p-Xylene

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene

1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane

1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane Unidentified

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified

Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified

1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan C11-Isoparaffin-5 Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified

Unidentified 2-Methylindan

1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12
C11 - Aromatic - 13 1,3,5-Triethylbenzene
C12 - Aromatic - 1

2-Methylnaphthalene

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF Sample: ODDB-91317 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91317 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000013.D\SIG1000013_FID1_A.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 13.004 15.663 14.829

I-Paraffins 17.787 20.361 16.768

Aromatics 44.642 38.930 36.630 Mono-Aromatics 43.740 38.197 36.029 Naphthalenes 0.095 0.070 0.061 Naphtheno/Olefino-Benzs 0.272 0.232 0.174 Indenes 0.536 0.431 0.366

Naphthenes 7.088 7.041 6.622 Mono-Naphthenes 7.088 7.041 6.622 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.367 8.272 8.138 n-Olefins 3.095 3.554 3.520 Iso-Olefins 3.632 4.092 3.912 Naphtheno-Olefins 0.614 0.597 0.673 Di-Olefins 0.026 0.029 0.032

Oxygenates 8.901 8.549 16.245

Unidentified 1.211 1.183 0.768

Plus 0.000 0.000 0.000

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 8.719 8.377 15.990 C3 0.189 0.184 0.270 C4 4.445 5.813 6.472 C5 11.832 14.125 13.999 C6 16.432 17.990 16.331 C7 23.846 22.104 21.435 C8 21.370 19.463 16.779 C9 7.528 6.857 5.219 C10 3.692 3.251 2.329 C11 0.583 0.523 0.328 C12 0.152 0.129 0.079

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.008 0.012 0.015 C4 4.179 5.473 6.075 C5 2.838 3.435 3.323 C6 3.854 4.431 3.779 C7 0.983 1.090 0.829 C8 0.785 0.847 0.581 C9 0.276 0.291 0.182 C10 0.055 0.057 0.033 C11 0.025 0.026 0.014

I-Paraffins C4 0.072 0.099 0.105 C5 4.963 6.074 5.812 C6 5.724 6.594 5.611 C7 2.425 2.700 2.044 C8 2.630 2.814 1.945 C9 1.340 1.424 0.882 C10 0.512 0.533 0.302 C11 0.122 0.124 0.066

Mono-Aromatics C6 0.653 0.563 0.706 C7 17.283 15.111 15.847 C8 17.130 14.993 13.632 C9 5.784 5.036 4.065 C10 2.329 2.011 1.466 C11 0.411 0.354 0.234 C12 0.152 0.129 0.079

Naphthalenes C10 0.080 0.059 0.053 C11 0.015 0.011 0.009

Naphtheno/Olefino-Benzs C10 0.272 0.232 0.174

Indenes C9 0.081 0.064 0.058 C10 0.444 0.359 0.302 C11 0.010 0.008 0.006

Mono-Naphthenes C5 0.284 0.289 0.342 C6 3.615 3.600 3.629 C7 2.361 2.345 2.032 C8 0.781 0.765 0.588 C9 0.047 0.042 0.032

n-Olefins C4 0.194 0.241 0.292

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.646 1.924 1.983 C6 1.155 1.280 1.159 C7 0.101 0.109 0.087

Iso-Olefins C5 1.877 2.180 2.261 C6 1.016 1.119 1.020 C7 0.694 0.749 0.597 C8 0.045 0.044 0.034

Naphtheno-Olefins C5 0.198 0.195 0.246 C6 0.416 0.403 0.428

Di-Olefins C5 0.026 0.029 0.032

Oxygenates C2 8.719 8.377 15.990 C3 0.182 0.172 0.255

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.62 21.32 5% 78.81 29.90 10% 82.90 80.72 15% 100.10 94.99 20% 140.24 116.45 25% 154.52 143.98 30% 160.39 154.56 35% 172.71 159.50 40% 174.38 172.68 45% 197.39 174.38 50% 230.74 197.31 55% 230.85 230.74 60% 230.95 230.86 65% 231.05 230.97 70% 257.58 235.35 75% 279.25 276.89 80% 281.48 280.86 85% 282.26 281.96 90% 321.38 300.27 95% 345.48 336.13 FBP 404.50 401.94

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.389 74-98-6 P3 Propane 0.008 0.012 0.015 1.988 2 8.610 75-28-5 I4 i-Butane 0.072 0.099 0.105 18.561 3 9.403 115-11-7 K4 Isobutene 0.015 0.020 0.023 4.088 4 9.443 106-98-9 K4 Butene-1 0.019 0.024 0.028 4.985 5 9.791 106-97-8 P4 n-Butane 4.179 5.473 6.075 1071.032 6 10.265 624-64-6 K4 t-Butene-2 0.073 0.092 0.110 19.366 7 10.387 463-82-1 I5 2,2-Dimethylpropane 0.021 0.027 0.025 5.505 8 10.986 590-18-1 K4 c-Butene-2 0.087 0.106 0.130 22.981 9 12.742 64-17-5 X2 Ethanol 8.719 8.377 15.990 994.782 10 13.125 563-45-1 C5 3-Methylbutene-1 0.329 0.398 0.397 87.383

11 14.710 78-78-4 I5 i-Pentane 4.942 6.046 5.787 1275.307 12 16.334 109-67-1 K5 Pentene-1 0.334 0.395 0.402 88.578 13 17.172 563-46-2 C5 2-Methylbutene-1 0.507 0.591 0.610 134.487 14 17.700 109-66-0 P5 n-Pentane 2.838 3.435 3.323 732.268 15 18.208 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.012 0.013 2.859 16 18.803 646-04-8 K5 t-Pentene-2 0.847 0.991 1.021 224.950 17 19.442 ? Unidentified 0.006 0.007 0.007 1.857 18 19.825 627-20-3 K5 c-Pentene-2 0.465 0.538 0.560 123.392 19 20.494 513-35-9 C5 2-Methylbutene-2 1.041 1.192 1.255 276.421 20 20.825 2004-70-8 E5 1t,3-Pentadiene 0.016 0.017 0.019 4.254

21 22.078 ? Unidentified 0.006 0.006 0.008 1.924 22 22.622 75-83-2 I6 2,2-Dimethylbutane 0.187 0.218 0.183 48.371 23 25.256 142-29-0 B5 Cyclopentene 0.198 0.195 0.246 54.138 24 26.501 71-23-8 X3 n-Propanol 0.182 0.172 0.255 33.724 25 27.110 287-92-3 M5 Cyclopentane 0.284 0.289 0.342 75.365 26 27.840 79-29-8 I6 2,3-Dimethylbutane 0.550 0.630 0.539 142.540 27 28.242 ? Unidentified 0.051 0.052 0.049 16.633 28 28.701 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.050 0.045 11.856 29 28.922 107-83-5 I6 2-Methylpentane 2.834 3.289 2.778 734.135 30 29.350 674-76-0 C6 4-Methyl-t-pentene-2 0.132 0.149 0.133 35.035

31 31.564 96-14-0 I6 3-Methylpentane 2.153 2.457 2.111 557.837 32 32.730 763-29-1 C6 2-Methylpentene-1 0.226 0.250 0.227 59.949 33 32.953 592-41-6 K6 Hexene-1 0.162 0.181 0.163 43.077 34 35.320 110-54-3 P6 n-Hexane 3.854 4.431 3.779 998.635 35 35.947 13269-52-8 K6 t-Hexene-3 0.266 0.295 0.267 70.539 36 36.422 4050-45-7 K6 t-Hexene-2 0.511 0.567 0.512 135.510 37 36.913 625-27-4 C6 2-Methylpentene-2 0.346 0.379 0.347 91.750 38 37.324 922-62-3 C6 3-Methyl-c-pentene-2 0.268 0.291 0.269 71.051 39 38.250 7688-21-3 K6 c-Hexene-2 0.216 0.237 0.217 57.376 40 39.598 3404-73-7 C7 3,3-Dimethylpentene-1 0.317 0.342 0.273 84.077

41 40.172 96-37-7 M6 Methylcyclopentane 2.055 2.081 2.063 545.518 42 41.744 108-08-7 I7 2,4-Dimethylpentane 0.320 0.361 0.270 83.311 43 42.044 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.834

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.283 464-06-2 I7 2,2,3-Trimethylbutane 0.046 0.051 0.039 11.990 45 44.940 ? Unidentified 0.012 0.012 0.012 3.942 46 45.142 71-42-3 Q6 Benzene 0.653 0.563 0.706 186.666 47 45.346 693-89-0 B6 1-Methylcyclopentene 0.370 0.360 0.381 100.625 48 46.168 3404-61-3 C7 3-Methylhexene-1 0.016 0.018 0.014 4.337 49 46.750 3524-73-0 C7 5-Methylhexene-1 0.082 0.089 0.070 21.674 50 47.066 110-82-7 M6 Cyclohexane 1.559 1.519 1.565 413.927 51 47.602 ? Unidentified 0.035 0.038 0.030 11.476 52 48.809 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.045 0.036 10.972 53 49.804 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.052 0.056 0.045 13.774

54 50.197 591-76-4 I7 2-Methylhexane 1.265 1.413 1.067 329.111 55 50.673 110-83-8 B6 Cyclohexene 0.045 0.043 0.047 12.073 56 52.032 589-34-4 I7 3-Methylhexane 0.793 0.875 0.669 206.268 57 52.883 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.223 0.225 0.191 59.064 58 53.470 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.179 0.183 0.154 47.601 59 54.096 822-50-4 M7 1t,2-Dimethylcyclopentane 0.273 0.276 0.235 72.579 60 54.393 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.019 5.981 61 54.687 540-84-1 I8 2,2,4-Trimethylpentane 0.065 0.071 0.048 16.966 62 55.027 592-76-7 K7 Heptene-1 0.030 0.032 0.026 7.899 63 56.359 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.823

64 56.880 14686-14-7 K7 t-Heptene-3 0.033 0.036 0.028 8.752 65 57.241 6094-02-6 C7 2-Methylhexene-1 0.058 0.064 0.050 15.505 66 57.617 142-82-5 P7 n-Heptane 0.983 1.090 0.829 255.710 67 57.834 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.021 6.362 68 58.112 2738-19-4 C7 2-Methyl-2-hexene 0.027 0.028 0.023 7.104 69 58.354 3899-36-3 C7 3-Methyl-t-hexene-3 0.020 0.022 0.018 5.441 70 58.742 14686-13-6 K7 t-Heptene-2 0.014 0.015 0.012 3.722 71 59.199 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.016 4.931 72 59.643 20710-38-8 C7 3-Methyl-t-hexene-2 0.016 0.017 0.014 4.182 73 60.425 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.012 3.576

74 61.063 108-87-2 M7 Methylcyclohexane 1.610 1.586 1.385 427.242 75 62.010 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.045 0.045 0.034 11.895 76 62.414 590-73-8 I8 2,2-Dimethylhexane 0.036 0.039 0.026 9.292 77 63.852 1640-89-7 M7 Ethylcyclopentane 0.058 0.057 0.050 15.280 78 64.502 564-02-3 I8 2,2,3-Trimethylpentane 0.079 0.084 0.059 20.632 79 64.741 592-13-2 I8 2,5-Dimethylhexane 0.197 0.215 0.146 51.360 80 65.079 589-43-5 I8 2,4-Dimethylhexane 0.192 0.208 0.142 50.169 81 65.919 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.045 0.045 0.034 11.970 82 66.322 563-16-6 I8 3,3-Dimethylhexane 0.029 0.031 0.021 7.459 83 67.450 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.040 0.039 0.030 10.560

84 68.081 565-75-3 I8 2,3,4-Trimethylpentane 0.815 0.859 0.602 212.324 85 68.691 108-88-3 Q7 Toluene 17.283 15.111 15.847 4886.507 86 70.125 C8 C8 - Diolefin - 1 0.017 0.017 0.013 4.553

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 70.421 584-94-1 I8 2,3-Dimethylhexane 0.270 0.287 0.200 70.337 88 71.693 592-27-8 I8 2-Methylheptane 0.332 0.361 0.246 86.538 89 71.947 589-53-7 I8 4-Methylheptane 0.171 0.184 0.126 44.481 90 72.857 M8 1,3-dimethyl-t-cyclohexane 0.269 0.265 0.202 71.384 91 73.016 589-81-1 I8 3-Methylheptane 0.281 0.302 0.208 73.278 92 73.201 619-99-8 I8 3-Ethylhexane 0.163 0.174 0.121 42.581 93 74.097 ? Unidentified 0.043 0.042 0.032 13.913 94 74.917 3522-94-9 I9 2,2,5-Trimethylhexane 0.545 0.584 0.359 142.398 95 75.264 M8 3c-Ethylmethylcyclopentane 0.015 0.015 0.012 4.111 96 75.483 M8 3t-Ethylmethylcyclopentane 0.022 0.022 0.016 5.793

97 76.184 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.124 0.121 0.093 32.920 98 77.562 111-65-9 P8 n-Octane 0.785 0.847 0.581 204.704 99 78.506 ? Unidentified 0.018 0.018 0.014 5.922 100 80.050 1069-53-0 I9 2,3,5-Trimethylhexane 0.103 0.108 0.068 26.782 101 80.613 C8 C9 - IsoOlefin - 1 0.027 0.027 0.021 7.296 102 81.048 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.023 0.022 0.018 6.223 103 81.230 1071-26-7 I9 2,4-Dimethylheptane 0.051 0.055 0.034 13.351 104 81.864 1678-91-7 M8 Ethylcyclohexane 0.197 0.191 0.149 52.401 105 82.191 1072-05-5 I9 2,6-Dimethylheptane 0.097 0.104 0.064 25.415 106 82.669 ? Unidentified 0.041 0.040 0.031 13.439

107 83.128 I9 2,5-Dimethylheptane 0.144 0.152 0.095 37.561 108 83.318 926-82-9 I9 3,5-Dimethylheptane 0.028 0.030 0.019 7.398 109 84.454 100-41-4 Q8 Ethylbenzene 3.147 2.751 2.504 882.957 110 84.863 ? Unidentified 0.028 0.027 0.019 9.026 111 85.710 108-38-3 Q8 m-Xylene 7.983 7.002 6.353 2240.073 112 85.852 106-42-3 Q8 p-Xylene 3.714 3.270 2.956 1042.294 113 86.326 ? Unidentified 0.019 0.018 0.012 6.062 114 86.466 I9 3,5-Dimethylheptane 0.017 0.018 0.011 4.511 115 86.617 1067-20-5 I9 3,3-Diethylpentane 0.014 0.014 0.009 3.578 116 87.016 2216-34-4 I9 4-Methyloctane 0.088 0.093 0.058 23.092

117 87.149 3221-61-2 I9 2-Methyloctane 0.119 0.126 0.078 31.018 118 87.848 15869-80-4 I9 Heptane, 3-ethyl- 0.017 0.018 0.011 4.392 119 88.011 2216-33-3 I9 3-Methyloctane 0.116 0.122 0.077 30.351 120 88.481 ? Unidentified 0.035 0.039 0.023 11.275 121 88.664 95-47-6 Q8 o-Xylene 2.286 1.969 1.819 641.414 122 89.064 I10 C10 - IsoParaffin - 1 0.118 0.123 0.070 30.833 123 89.640 M9 trans-1,3-Diethylcyclopentane 0.031 0.027 0.021 8.749 124 89.914 14720-74-2 I10 2,2,4-trimethylheptane 0.103 0.107 0.061 26.851 125 91.501 111-84-2 P9 n-Nonane 0.276 0.291 0.182 72.003 126 92.026 4926-90-3 M9 1,1-Methylethylcyclohexane 0.016 0.015 0.011 4.243

127 92.836 98-82-8 Q9 i-Propylbenzene 0.040 0.035 0.028 11.076 128 93.591 ? Unidentified 0.017 0.018 0.010 5.603 129 93.817 15869-87-1 I10 2,2-Dimethyloctane 0.011 0.011 0.006 2.807

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 94.627 15869-89-3 I10 2,5-Dimethyloctane 0.009 0.009 0.005 2.341 131 94.812 I10 C10 - IsoParaffin - 2 0.015 0.015 0.009 3.863 132 95.657 I10 2,6-Dimethyloctane 0.011 0.011 0.007 2.892 133 96.303 103-65-1 Q9 n-Propylbenzene 0.331 0.291 0.232 92.212 134 97.154 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.283 1.125 0.902 357.818 135 97.386 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.597 0.525 0.420 166.416 136 98.013 108-67-8 Q9 1,3,5-Trimethylbenzene 0.762 0.667 0.535 212.349 137 98.490 15869-85-9 I10 5-Methylnonane 0.007 0.007 0.004 1.884 138 98.680 17301-94-8 I10 4-Methylnonane 0.018 0.018 0.011 4.644 139 98.881 I10 2,2,6-Trimethyloctane 0.162 0.169 0.096 42.483

140 99.097 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.440 0.379 0.309 122.667 141 99.659 5911-04-6 I10 3-Methylnonane 0.023 0.024 0.014 6.009 142 100.250 ? Unidentified 0.041 0.042 0.022 13.256 143 100.473 I11 C11-Isoparaffin-2 0.016 0.017 0.009 4.264 144 100.735 95-63-6 Q9 1,2,4-Trimethylbenzene 2.073 1.794 1.457 577.860 145 100.937 ? Unidentified 0.023 0.024 0.014 7.368 146 101.060 ? Unidentified 0.011 0.012 0.007 3.680 147 102.105 17302-01-1 I10 3-Ethyl-3-methylheptane 0.036 0.037 0.020 9.473 148 102.384 538-93-2 Q10 i-Butylbenzene 0.054 0.048 0.034 14.909 149 102.592 124-18-5 P10 n-Decane 0.055 0.057 0.033 14.422

150 102.972 ? Unidentified 0.009 0.010 0.005 3.040 151 103.608 526-73-8 Q9 1,2,3-Trimethylbenzene 0.259 0.219 0.182 72.104 152 104.391 ? Unidentified 0.035 0.035 0.019 11.324 153 104.799 J9 Indan 0.081 0.064 0.058 23.076 154 105.426 J10 Indene 0.241 0.190 0.172 68.367 155 106.145 I11 C11-Isoparaffin-7 0.106 0.108 0.057 27.667 156 106.330 141-93-5 Q10 1,3-Diethylbenzene 0.030 0.026 0.019 8.247 157 106.616 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.397 0.350 0.250 110.209 158 106.942 105-05-5 Q10 1,4-Diethylbenzene 0.169 0.149 0.107 46.976 159 107.172 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.131 0.113 0.082 36.330

160 107.433 135-01-3 Q10 1,2-Diethylbenzene 0.030 0.026 0.019 8.401 161 107.885 ? Unidentified 0.027 0.028 0.015 8.893 162 108.023 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.055 0.048 0.035 15.209 163 108.160 ? Unidentified 0.032 0.033 0.017 10.388 164 108.242 ? Unidentified 0.027 0.028 0.015 8.911 165 108.363 ? Unidentified 0.202 0.206 0.109 65.743 166 108.547 ? Unidentified 0.080 0.082 0.043 26.148 167 108.876 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.123 0.106 0.077 34.029 168 108.984 ? Unidentified 0.329 0.284 0.207 106.864 169 109.201 J10 2-Methylindan 0.048 0.037 0.030 13.509

170 109.542 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.327 0.283 0.206 90.659 171 110.097 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.231 0.197 0.145 64.083 172 110.526 ? Unidentified 0.007 0.006 0.004 2.163

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 110.727 ? Unidentified 0.014 0.014 0.008 4.513 174 110.857 ? Unidentified 0.023 0.024 0.014 7.518 175 111.003 Q11 1-Methyl-4-t-butylbenzene 0.036 0.032 0.021 9.986 176 111.218 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.134 0.114 0.084 37.125 177 111.529 1120-21-4 P11 n-Undecane 0.025 0.026 0.014 6.667 178 111.687 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.031 0.027 0.018 8.663 179 111.796 ? Unidentified 0.015 0.013 0.009 5.035 180 112.162 Q10 1,2,4,5-Tetramethylbenzene 0.268 0.229 0.169 74.447 181 112.428 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.379 0.323 0.239 105.147 182 113.289 ? Unidentified 0.013 0.013 0.006 4.107

183 113.581 Q11 C11 - Aromatic - 3 0.049 0.041 0.028 13.434 184 113.761 874-35-1 H10 5-Methylindan 0.112 0.095 0.071 30.969 185 113.901 Q12 1,2-Di-i-propylbenzene 0.047 0.040 0.024 12.929 186 114.115 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.067 0.057 0.038 18.623 187 114.275 Q11 C11 - Aromatic - 4 0.033 0.028 0.019 9.094 188 114.512 824-22-6 J10 4-Methylindan 0.155 0.132 0.099 42.969 189 114.764 824-63-5 H10 2-Methylindan 0.161 0.137 0.103 44.520 190 114.977 ? Unidentified 0.012 0.012 0.006 3.857 191 115.089 538-68-1 Q11 n-Pentylbenzene 0.017 0.014 0.009 4.567 192 115.321 Q11 tert-Pentylbenzene 0.069 0.059 0.040 19.185

193 115.631 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.031 0.026 0.017 8.461 194 115.741 Q11 C11 - Aromatic - 7 0.040 0.035 0.023 10.964 195 116.204 100-18-5 Q12 1,4-Di-i-propylbenzene 0.055 0.047 0.029 15.267 196 116.630 91-20-3 G10 Naphthalene 0.080 0.059 0.053 23.163 197 117.080 J11 1,1-Dimethyl Indane 0.010 0.008 0.006 2.894 198 117.429 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.006 0.005 0.003 1.664 199 117.735 Q12 1,3-Di-n-propylbenzene 0.043 0.037 0.022 11.851 200 117.845 Q11 C11 - Aromatic - 11 0.024 0.021 0.014 6.605 201 118.400 17851-27-2 Q11 1-ethyl-2,4,5-trimethylbenzen 0.014 0.012 0.008 3.807 202 123.281 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.006 2.742

203 124.147 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.501

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.389 74-98-6 Propane 0.008 0.012 0.015 1.988

9.791 106-97-8 n-Butane 4.179 5.473 6.075 1071.032 17.700 109-66-0 n-Pentane 2.838 3.435 3.323 732.268 35.320 110-54-3 n-Hexane 3.854 4.431 3.779 998.635 57.617 142-82-5 n-Heptane 0.983 1.090 0.829 255.710 77.562 111-65-9 n-Octane 0.785 0.847 0.581 204.704 91.501 111-84-2 n-Nonane 0.276 0.291 0.182 72.003 102.592 124-18-5 n-Decane 0.055 0.057 0.033 14.422 111.529 1120-21-4 n-Undecane 0.025 0.026 0.014 6.667

I-Paraffins 8.610 75-28-5 i-Butane 0.072 0.099 0.105 18.561

10.387 463-82-1 2,2-Dimethylpropane 0.021 0.027 0.025 5.505 14.710 78-78-4 i-Pentane 4.942 6.046 5.787 1275.307 22.622 75-83-2 2,2-Dimethylbutane 0.187 0.218 0.183 48.371 27.840 79-29-8 2,3-Dimethylbutane 0.550 0.630 0.539 142.540 28.922 107-83-5 2-Methylpentane 2.834 3.289 2.778 734.135 31.564 96-14-0 3-Methylpentane 2.153 2.457 2.111 557.837 41.744 108-08-7 2,4-Dimethylpentane 0.320 0.361 0.270 83.311 42.283 464-06-2 2,2,3-Trimethylbutane 0.046 0.051 0.039 11.990 50.197 591-76-4 2-Methylhexane 1.265 1.413 1.067 329.111 52.032 589-34-4 3-Methylhexane 0.793 0.875 0.669 206.268 54.687 540-84-1 2,2,4-Trimethylpentane 0.065 0.071 0.048 16.966 62.414 590-73-8 2,2-Dimethylhexane 0.036 0.039 0.026 9.292 64.502 564-02-3 2,2,3-Trimethylpentane 0.079 0.084 0.059 20.632 64.741 592-13-2 2,5-Dimethylhexane 0.197 0.215 0.146 51.360 65.079 589-43-5 2,4-Dimethylhexane 0.192 0.208 0.142 50.169 66.322 563-16-6 3,3-Dimethylhexane 0.029 0.031 0.021 7.459 68.081 565-75-3 2,3,4-Trimethylpentane 0.815 0.859 0.602 212.324 70.421 584-94-1 2,3-Dimethylhexane 0.270 0.287 0.200 70.337 71.693 592-27-8 2-Methylheptane 0.332 0.361 0.246 86.538 71.947 589-53-7 4-Methylheptane 0.171 0.184 0.126 44.481 73.016 589-81-1 3-Methylheptane 0.281 0.302 0.208 73.278 73.201 619-99-8 3-Ethylhexane 0.163 0.174 0.121 42.581 74.917 3522-94-9 2,2,5-Trimethylhexane 0.545 0.584 0.359 142.398 80.050 1069-53-0 2,3,5-Trimethylhexane 0.103 0.108 0.068 26.782 81.230 1071-26-7 2,4-Dimethylheptane 0.051 0.055 0.034 13.351 82.191 1072-05-5 2,6-Dimethylheptane 0.097 0.104 0.064 25.415 83.128 2,5-Dimethylheptane 0.144 0.152 0.095 37.561 83.318 926-82-9 3,5-Dimethylheptane 0.028 0.030 0.019 7.398 86.466 3,5-Dimethylheptane 0.017 0.018 0.011 4.511 86.617 1067-20-5 3,3-Diethylpentane 0.014 0.014 0.009 3.578 87.016 2216-34-4 4-Methyloctane 0.088 0.093 0.058 23.092 87.149 3221-61-2 2-Methyloctane 0.119 0.126 0.078 31.018 87.848 15869-80-4 Heptane, 3-ethyl- 0.017 0.018 0.011 4.392 88.011 2216-33-3 3-Methyloctane 0.116 0.122 0.077 30.351 89.064 C10 - IsoParaffin - 1 0.118 0.123 0.070 30.833 89.914 14720-74-2 2,2,4-trimethylheptane 0.103 0.107 0.061 26.851

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 93.817 15869-87-1 2,2-Dimethyloctane 0.011 0.011 0.006 2.807

94.627 15869-89-3 2,5-Dimethyloctane 0.009 0.009 0.005 2.341 94.812 C10 - IsoParaffin - 2 0.015 0.015 0.009 3.863 95.657 2,6-Dimethyloctane 0.011 0.011 0.007 2.892 98.490 15869-85-9 5-Methylnonane 0.007 0.007 0.004 1.884 98.680 17301-94-8 4-Methylnonane 0.018 0.018 0.011 4.644 98.881 2,2,6-Trimethyloctane 0.162 0.169 0.096 42.483 99.659 5911-04-6 3-Methylnonane 0.023 0.024 0.014 6.009 100.473 C11-Isoparaffin-2 0.016 0.017 0.009 4.264 102.105 17302-01-1 3-Ethyl-3-methylheptane 0.036 0.037 0.020 9.473 106.145 C11-Isoparaffin-7 0.106 0.108 0.057 27.667

Aromatics Mono-Aromatics 45.142 71-42-3 Benzene 0.653 0.563 0.706 186.666

68.691 108-88-3 Toluene 17.283 15.111 15.847 4886.507 84.454 100-41-4 Ethylbenzene 3.147 2.751 2.504 882.957 85.710 108-38-3 m-Xylene 7.983 7.002 6.353 2240.073 85.852 106-42-3 p-Xylene 3.714 3.270 2.956 1042.294 88.664 95-47-6 o-Xylene 2.286 1.969 1.819 641.414 92.836 98-82-8 i-Propylbenzene 0.040 0.035 0.028 11.076 96.303 103-65-1 n-Propylbenzene 0.331 0.291 0.232 92.212 97.154 620-14-4 1-Methyl-3-ethylbenzene 1.283 1.125 0.902 357.818 97.386 622-96-8 1-Methyl-4-ethylbenzene 0.597 0.525 0.420 166.416 98.013 108-67-8 1,3,5-Trimethylbenzene 0.762 0.667 0.535 212.349 99.097 611-14-3 1-Methyl-2-ethylbenzene 0.440 0.379 0.309 122.667 100.735 95-63-6 1,2,4-Trimethylbenzene 2.073 1.794 1.457 577.860 102.384 538-93-2 i-Butylbenzene 0.054 0.048 0.034 14.909 103.608 526-73-8 1,2,3-Trimethylbenzene 0.259 0.219 0.182 72.104 106.330 141-93-5 1,3-Diethylbenzene 0.030 0.026 0.019 8.247 106.616 1074-43-7 1-Methyl-3-n-propylbenzene 0.397 0.350 0.250 110.209 106.942 105-05-5 1,4-Diethylbenzene 0.169 0.149 0.107 46.976 107.172 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.131 0.113 0.082 36.330 107.433 135-01-3 1,2-Diethylbenzene 0.030 0.026 0.019 8.401 108.023 1074-17-5 1-Methyl-2-n-propylbenzene 0.055 0.048 0.035 15.209 108.876 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.123 0.106 0.077 34.029 109.542 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.327 0.283 0.206 90.659 110.097 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.231 0.197 0.145 64.083 111.003 1-Methyl-4-t-butylbenzene 0.036 0.032 0.021 9.986 111.218 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.134 0.114 0.084 37.125 111.687 4218-48-8 1-Ethyl-4-i-propylbenzene 0.031 0.027 0.018 8.663 112.162 1,2,4,5-Tetramethylbenzene 0.268 0.229 0.169 74.447 112.428 527-53-7 1,2,3,5-Tetramethylbenzene 0.379 0.323 0.239 105.147 113.581 C11 - Aromatic - 3 0.049 0.041 0.028 13.434 113.901 1,2-Di-i-propylbenzene 0.047 0.040 0.024 12.929 114.115 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.067 0.057 0.038 18.623 114.275 C11 - Aromatic - 4 0.033 0.028 0.019 9.094 115.089 538-68-1 n-Pentylbenzene 0.017 0.014 0.009 4.567

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.321 tert-Pentylbenzene 0.069 0.059 0.040 19.185

115.631 577-55-9 1-Methyl-2-n-butylbenzene 0.031 0.026 0.017 8.461 115.741 C11 - Aromatic - 7 0.040 0.035 0.023 10.964 116.204 100-18-5 1,4-Di-i-propylbenzene 0.055 0.047 0.029 15.267 117.429 7364-19-4 1t-Butyl-4-ethylbenzene 0.006 0.005 0.003 1.664 117.735 1,3-Di-n-propylbenzene 0.043 0.037 0.022 11.851 117.845 C11 - Aromatic - 11 0.024 0.021 0.014 6.605 118.400 17851-27-2 1-ethyl-2,4,5-trimethylbenzen 0.014 0.012 0.008 3.807

Naphthalenes 116.630 91-20-3 Naphthalene 0.080 0.059 0.053 23.163

123.281 91-57-6 2-Methylnaphthalene 0.010 0.007 0.006 2.742 124.147 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.501

Naphtheno/Olefino-Benzs

113.761 874-35-1 5-Methylindan 0.112 0.095 0.071 30.969 114.764 824-63-5 2-Methylindan 0.161 0.137 0.103 44.520

Indenes 104.799 Indan 0.081 0.064 0.058 23.076

105.426 Indene 0.241 0.190 0.172 68.367 109.201 2-Methylindan 0.048 0.037 0.030 13.509 114.512 824-22-6 4-Methylindan 0.155 0.132 0.099 42.969 117.080 1,1-Dimethyl Indane 0.010 0.008 0.006 2.894

Naphthenes Mono-Naphthenes 27.110 287-92-3 Cyclopentane 0.284 0.289 0.342 75.365

40.172 96-37-7 Methylcyclopentane 2.055 2.081 2.063 545.518 47.066 110-82-7 Cyclohexane 1.559 1.519 1.565 413.927 52.883 1759-58-6 1t,3-Dimethylcyclopentane 0.223 0.225 0.191 59.064 53.470 2532-58-3 1c,3-Dimethylcyclopentane 0.179 0.183 0.154 47.601 54.096 822-50-4 1t,2-Dimethylcyclopentane 0.273 0.276 0.235 72.579 59.199 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.016 4.931 61.063 108-87-2 Methylcyclohexane 1.610 1.586 1.385 427.242 62.010 4516-69-2 1,1,3-Trimethylcyclopentane 0.045 0.045 0.034 11.895 63.852 1640-89-7 Ethylcyclopentane 0.058 0.057 0.050 15.280 65.919 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.045 0.045 0.034 11.970 67.450 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.040 0.039 0.030 10.560 72.857 1,3-dimethyl-t-cyclohexane 0.269 0.265 0.202 71.384 75.264 3c-Ethylmethylcyclopentane 0.015 0.015 0.012 4.111 75.483 3t-Ethylmethylcyclopentane 0.022 0.022 0.016 5.793 76.184 2207-03-6 1t,3-Dimethylcyclohexane 0.124 0.121 0.093 32.920 81.048 2207-01-4 1c,2-Dimethylcyclohexane 0.023 0.022 0.018 6.223 81.864 1678-91-7 Ethylcyclohexane 0.197 0.191 0.149 52.401 89.640 trans-1,3-Diethylcyclopentane 0.031 0.027 0.021 8.749 92.026 4926-90-3 1,1-Methylethylcyclohexane 0.016 0.015 0.011 4.243

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.403 115-11-7 Isobutene 0.015 0.020 0.023 4.088

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 9.443 106-98-9 Butene-1 0.019 0.024 0.028 4.985

10.265 624-64-6 t-Butene-2 0.073 0.092 0.110 19.366 10.986 590-18-1 c-Butene-2 0.087 0.106 0.130 22.981 16.334 109-67-1 Pentene-1 0.334 0.395 0.402 88.578 18.803 646-04-8 t-Pentene-2 0.847 0.991 1.021 224.950 19.825 627-20-3 c-Pentene-2 0.465 0.538 0.560 123.392 32.953 592-41-6 Hexene-1 0.162 0.181 0.163 43.077 35.947 13269-52-8 t-Hexene-3 0.266 0.295 0.267 70.539 36.422 4050-45-7 t-Hexene-2 0.511 0.567 0.512 135.510 38.250 7688-21-3 c-Hexene-2 0.216 0.237 0.217 57.376 55.027 592-76-7 Heptene-1 0.030 0.032 0.026 7.899 56.880 14686-14-7 t-Heptene-3 0.033 0.036 0.028 8.752 57.834 7642-10-6 c-Heptene-3 0.024 0.026 0.021 6.362 58.742 14686-13-6 t-Heptene-2 0.014 0.015 0.012 3.722

Iso-Olefins 13.125 563-45-1 3-Methylbutene-1 0.329 0.398 0.397 87.383

17.172 563-46-2 2-Methylbutene-1 0.507 0.591 0.610 134.487 20.494 513-35-9 2-Methylbutene-2 1.041 1.192 1.255 276.421 28.701 691-38-3 4-Methyl-c-pentene-2 0.045 0.050 0.045 11.856 29.350 674-76-0 4-Methyl-t-pentene-2 0.132 0.149 0.133 35.035 32.730 763-29-1 2-Methylpentene-1 0.226 0.250 0.227 59.949 36.913 625-27-4 2-Methylpentene-2 0.346 0.379 0.347 91.750 37.324 922-62-3 3-Methyl-c-pentene-2 0.268 0.291 0.269 71.051 39.598 3404-73-7 3,3-Dimethylpentene-1 0.317 0.342 0.273 84.077 42.044 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.834 46.168 3404-61-3 3-Methylhexene-1 0.016 0.018 0.014 4.337 46.750 3524-73-0 5-Methylhexene-1 0.082 0.089 0.070 21.674 48.809 15840-60-5 2-Methyl-c-hexene-3 0.041 0.045 0.036 10.972 49.804 3404-55-5 4-Methyl-t/c-hexene-2 0.052 0.056 0.045 13.774 54.393 C7 - Iso-Olefin - 2 0.023 0.024 0.019 5.981 56.359 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.823 57.241 6094-02-6 2-Methylhexene-1 0.058 0.064 0.050 15.505 58.112 2738-19-4 2-Methyl-2-hexene 0.027 0.028 0.023 7.104 58.354 3899-36-3 3-Methyl-t-hexene-3 0.020 0.022 0.018 5.441 59.643 20710-38-8 3-Methyl-t-hexene-2 0.016 0.017 0.014 4.182 60.425 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.012 3.576 70.125 C8 - Diolefin - 1 0.017 0.017 0.013 4.553 80.613 C9 - IsoOlefin - 1 0.027 0.027 0.021 7.296

Naphtheno-Olefins 25.256 142-29-0 Cyclopentene 0.198 0.195 0.246 54.138

45.346 693-89-0 1-Methylcyclopentene 0.370 0.360 0.381 100.625 50.673 110-83-8 Cyclohexene 0.045 0.043 0.047 12.073

Di-Olefins 18.208 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.012 0.013 2.859

20.825 2004-70-8 1t,3-Pentadiene 0.016 0.017 0.019 4.254

Oxygenates 12.742 64-17-5 Ethanol 8.719 8.377 15.990 994.782

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Oxygenates 26.501 71-23-8 n-Propanol 0.182 0.172 0.255 33.724

Unidentified 19.442 Unidentified 0.006 0.007 0.007 1.857

22.078 Unidentified 0.006 0.006 0.008 1.924 28.242 Unidentified 0.051 0.052 0.049 16.633 44.940 Unidentified 0.012 0.012 0.012 3.942 47.602 Unidentified 0.035 0.038 0.030 11.476 74.097 Unidentified 0.043 0.042 0.032 13.913 78.506 Unidentified 0.018 0.018 0.014 5.922 82.669 Unidentified 0.041 0.040 0.031 13.439 84.863 Unidentified 0.028 0.027 0.019 9.026 86.326 Unidentified 0.019 0.018 0.012 6.062 88.481 Unidentified 0.035 0.039 0.023 11.275 93.591 Unidentified 0.017 0.018 0.010 5.603 100.250 Unidentified 0.041 0.042 0.022 13.256 100.937 Unidentified 0.023 0.024 0.014 7.368 101.060 Unidentified 0.011 0.012 0.007 3.680 102.972 Unidentified 0.009 0.010 0.005 3.040 104.391 Unidentified 0.035 0.035 0.019 11.324 107.885 Unidentified 0.027 0.028 0.015 8.893 108.160 Unidentified 0.032 0.033 0.017 10.388 108.242 Unidentified 0.027 0.028 0.015 8.911 108.363 Unidentified 0.202 0.206 0.109 65.743 108.547 Unidentified 0.080 0.082 0.043 26.148 108.984 Unidentified 0.329 0.284 0.207 106.864 110.526 Unidentified 0.007 0.006 0.004 2.163 110.727 Unidentified 0.014 0.014 0.008 4.513 110.857 Unidentified 0.023 0.024 0.014 7.518 111.796 Unidentified 0.015 0.013 0.009 5.035 113.289 Unidentified 0.013 0.013 0.006 4.107 114.977 Unidentified 0.012 0.012 0.006 3.857

Plus

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane
Toluene

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane

1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified
2,2,5-Trimethylhexane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF95.090.085.080.075.0 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene

Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane C10 - IsoParaffin - 2

2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene

Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 1-ethyl-2,4,5-trimethylbenzen

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF Sample: ODDB-91318 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91318 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000014.D\SIG1000014_FID1_A.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 3.414 4.204 4.355

I-Paraffins 32.566 37.842 34.129

Aromatics 45.272 38.847 34.931 Mono-Aromatics 42.987 37.004 33.407 Naphthalenes 0.232 0.170 0.154 Naphtheno/Olefino-Benzs 0.716 0.603 0.462 Indenes 1.336 1.071 0.908

Naphthenes 1.386 1.385 1.418 Mono-Naphthenes 1.386 1.385 1.418 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.518 8.347 8.389 n-Olefins 3.187 3.614 3.642 Iso-Olefins 3.676 4.100 4.018 Naphtheno-Olefins 0.628 0.604 0.696 Di-Olefins 0.026 0.029 0.033

Oxygenates 8.732 8.292 16.092

Unidentified 1.112 1.083 0.684

Plus 0.000 0.000 0.000

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 8.547 8.118 15.829 C3 0.186 0.174 0.264 C4 2.115 2.727 3.115 C5 17.135 20.403 20.410 C6 23.265 26.011 23.201 C7 12.808 11.495 11.727 C8 11.687 10.125 9.388 C9 11.137 9.554 7.909 C10 9.362 7.949 5.994 C11 2.102 1.901 1.191 C12 0.546 0.462 0.288

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 1.890 2.448 2.775 C5 0.819 0.981 0.969 C6 0.426 0.484 0.422 C7 0.095 0.104 0.081 C8 0.018 0.019 0.013 C10 0.099 0.102 0.060 C11 0.066 0.066 0.036

I-Paraffins C4 0.029 0.039 0.043 C5 12.234 14.800 14.467 C6 18.582 21.182 18.398 C7 0.882 0.972 0.751 C8 0.047 0.050 0.035 C10 0.129 0.131 0.074 C11 0.644 0.649 0.351 C12 0.019 0.019 0.010

Mono-Aromatics C6 0.707 0.603 0.773 C7 10.784 9.322 9.986 C8 11.622 10.056 9.340 C9 10.885 9.357 7.727 C10 7.203 6.147 4.579 C11 1.283 1.094 0.738 C12 0.504 0.424 0.265

Naphthalenes C10 0.218 0.159 0.145 C11 0.014 0.011 0.009

Naphtheno/Olefino-Benzs C10 0.716 0.603 0.462

Indenes C9 0.252 0.196 0.182 C10 0.997 0.807 0.675 C11 0.064 0.050 0.037 C12 0.023 0.018 0.014

Mono-Naphthenes C5 0.270 0.272 0.329 C6 0.829 0.827 0.840 C7 0.287 0.286 0.249

n-Olefins C4 0.195 0.240 0.297 C5 1.675 1.935 2.037 C6 1.184 1.298 1.200

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C7 0.102 0.109 0.089 C11 0.032 0.032 0.019

Iso-Olefins C5 1.908 2.190 2.321 C6 1.110 1.208 1.126 C7 0.658 0.702 0.572

Naphtheno-Olefins C5 0.202 0.196 0.253 C6 0.426 0.408 0.442

Di-Olefins C5 0.026 0.029 0.033

Oxygenates C2 8.547 8.118 15.829 C3 0.186 0.174 0.264

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 23.07 22.44 5% 79.42 79.17 10% 80.75 80.26 15% 83.61 81.36 20% 133.76 96.69 25% 138.48 135.45 30% 139.95 138.57 35% 144.73 139.85 40% 154.11 144.40 45% 172.56 145.94 50% 173.20 172.35 55% 216.24 173.01 60% 224.33 214.14 65% 264.63 223.50 70% 281.36 266.81 75% 286.57 281.60 80% 325.06 320.98 85% 336.00 334.33 90% 362.58 355.82 95% 380.31 374.05 FBP 407.09 404.60

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.618 75-28-5 I4 i-Butane 0.029 0.039 0.043 7.802 2 9.412 115-11-7 K4 Isobutene 0.016 0.020 0.024 4.346 3 9.452 106-98-9 K4 Butene-1 0.019 0.024 0.029 5.219 4 9.801 106-97-8 P4 n-Butane 1.890 2.448 2.775 506.033 5 10.277 624-64-6 K4 t-Butene-2 0.074 0.091 0.112 20.424 6 10.399 463-82-1 I5 2,2-Dimethylpropane 0.029 0.036 0.034 7.749 7 11.000 590-18-1 K4 c-Butene-2 0.087 0.105 0.133 24.178 8 12.764 64-17-5 X2 Ethanol 8.547 8.118 15.829 1018.567 9 13.145 563-45-1 C5 3-Methylbutene-1 0.331 0.396 0.403 91.846 10 14.745 78-78-4 I5 i-Pentane 12.205 14.763 14.433 3290.084

11 16.360 109-67-1 K5 Pentene-1 0.339 0.397 0.412 93.993 12 17.198 563-46-2 C5 2-Methylbutene-1 0.515 0.593 0.627 142.805 13 17.722 109-66-0 P5 n-Pentane 0.819 0.981 0.969 220.865 14 18.234 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 3.049 15 18.830 646-04-8 K5 t-Pentene-2 0.862 0.997 1.049 239.110 16 19.469 ? Unidentified 0.006 0.007 0.007 1.974 17 19.852 627-20-3 K5 c-Pentene-2 0.473 0.541 0.576 131.228 18 20.523 513-35-9 C5 2-Methylbutene-2 1.061 1.201 1.291 294.302 19 20.853 2004-70-8 E5 1t,3-Pentadiene 0.016 0.018 0.020 4.514 20 22.104 ? Unidentified 0.006 0.006 0.008 2.024

21 22.649 75-83-2 I6 2,2-Dimethylbutane 0.322 0.371 0.318 87.037 22 25.284 142-29-0 B5 Cyclopentene 0.202 0.196 0.253 57.731 23 26.530 71-23-8 X3 n-Propanol 0.186 0.174 0.264 36.052 24 27.137 287-92-3 M5 Cyclopentane 0.270 0.272 0.329 74.922 25 27.871 79-29-8 I6 2,3-Dimethylbutane 1.591 1.803 1.575 430.647 26 28.273 ? Unidentified 0.053 0.053 0.051 17.943 27 28.738 691-38-3 C6 4-Methyl-c-pentene-2 0.043 0.048 0.044 12.008 28 28.992 107-83-5 I6 2-Methylpentane 10.430 11.969 10.327 2822.785 29 29.383 674-76-0 C6 4-Methyl-t-pentene-2 0.136 0.151 0.137 37.578 30 31.616 96-14-0 I6 3-Methylpentane 6.239 7.039 6.177 1688.612

31 32.755 763-29-1 C6 2-Methylpentene-1 0.232 0.254 0.235 64.237 32 32.979 592-41-6 K6 Hexene-1 0.166 0.184 0.168 46.069 33 35.165 760-21-4 C6 2-Ethylbutene-1 0.071 0.077 0.072 19.694 34 35.323 110-54-3 P6 n-Hexane 0.426 0.484 0.422 115.358 35 35.967 13269-52-8 K6 t-Hexene-3 0.273 0.300 0.276 75.589 36 36.441 4050-45-7 K6 t-Hexene-2 0.523 0.574 0.530 145.033 37 36.933 625-27-4 C6 2-Methylpentene-2 0.354 0.384 0.359 98.249 38 37.344 922-62-3 C6 3-Methyl-c-pentene-2 0.274 0.295 0.278 76.109 39 38.268 7688-21-3 K6 c-Hexene-2 0.222 0.240 0.225 61.522 40 39.613 3404-73-7 C7 3,3-Dimethylpentene-1 0.325 0.348 0.283 90.243

41 40.181 96-37-7 M6 Methylcyclopentane 0.763 0.764 0.774 211.574 42 41.768 108-08-7 I7 2,4-Dimethylpentane 0.152 0.169 0.129 41.289 43 42.062 594-56-9 C7 2,3,3-Trimethylbutene-1 0.011 0.011 0.009 2.930

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 44.952 ? Unidentified 0.012 0.012 0.013 4.227 45 45.154 71-42-3 Q6 Benzene 0.707 0.603 0.773 211.249 46 45.357 693-89-0 B6 1-Methylcyclopentene 0.379 0.365 0.394 107.702 47 46.176 3404-61-3 C7 3-Methylhexene-1 0.017 0.018 0.014 4.587 48 46.760 3524-73-0 C7 5-Methylhexene-1 0.023 0.025 0.020 6.502 49 47.068 110-82-7 M6 Cyclohexane 0.066 0.063 0.067 18.243 50 47.610 ? Unidentified 0.036 0.038 0.031 12.157 51 48.815 15840-60-5 C7 2-Methyl-c-hexene-3 0.042 0.045 0.037 11.660 52 49.160 3769-23-1 C7 4-Methylhexene-1 0.012 0.013 0.011 3.352 53 49.807 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.053 0.056 0.046 14.686

54 50.198 591-76-4 I7 2-Methylhexane 0.444 0.491 0.378 120.723 55 50.676 110-83-8 B6 Cyclohexene 0.046 0.043 0.048 12.859 56 52.032 589-34-4 I7 3-Methylhexane 0.286 0.312 0.243 77.645 57 52.884 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.100 0.100 0.087 27.704 58 53.472 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.067 0.067 0.058 18.498 59 54.098 822-50-4 M7 1t,2-Dimethylcyclopentane 0.059 0.059 0.052 16.442 60 54.396 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.020 6.406 61 55.024 592-76-7 K7 Heptene-1 0.028 0.030 0.024 7.779 62 56.358 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.013 4.011 63 56.879 14686-14-7 K7 t-Heptene-3 0.034 0.036 0.029 9.321

64 57.237 6094-02-6 C7 2-Methylhexene-1 0.060 0.064 0.052 16.594 65 57.610 142-82-5 P7 n-Heptane 0.095 0.104 0.081 25.819 66 57.830 7642-10-6 K7 c-Heptene-3 0.027 0.029 0.023 7.450 67 58.109 2738-19-4 C7 2-Methyl-2-hexene 0.027 0.028 0.024 7.502 68 58.353 3899-36-3 C7 3-Methyl-t-hexene-3 0.021 0.022 0.018 5.726 69 58.737 14686-13-6 K7 t-Heptene-2 0.014 0.014 0.012 3.753 70 59.196 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.016 5.253 71 59.637 20710-38-8 C7 3-Methyl-t-hexene-2 0.016 0.017 0.014 4.475 72 60.423 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.012 3.778 73 61.035 108-87-2 M7 Methylcyclohexane 0.042 0.041 0.037 11.658

74 68.651 108-88-3 Q7 Toluene 10.784 9.322 9.986 3184.956 75 71.685 592-27-8 I8 2-Methylheptane 0.017 0.018 0.013 4.680 76 71.938 589-53-7 I8 4-Methylheptane 0.010 0.010 0.007 2.625 77 73.011 589-81-1 I8 3-Methylheptane 0.020 0.021 0.015 5.419 78 77.555 111-65-9 P8 n-Octane 0.018 0.019 0.013 4.885 79 84.445 100-41-4 Q8 Ethylbenzene 2.185 1.889 1.756 640.555 80 85.692 108-38-3 Q8 m-Xylene 5.346 4.637 4.297 1567.149 81 85.836 106-42-3 Q8 p-Xylene 2.512 2.187 2.019 736.435 82 88.657 95-47-6 Q8 o-Xylene 1.578 1.343 1.268 462.494 83 92.836 98-82-8 Q9 i-Propylbenzene 0.039 0.034 0.028 11.462

84 95.265 2051-30-1 I10 2,4-Dimethyloctane 0.008 0.008 0.005 2.089 85 96.305 103-65-1 Q9 n-Propylbenzene 0.490 0.426 0.348 142.603 86 97.164 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.108 1.827 1.496 613.883

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 97.394 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.013 0.882 0.719 295.144 88 98.022 108-67-8 Q9 1,3,5-Trimethylbenzene 1.391 1.205 0.988 405.233 89 98.496 15869-85-9 I10 5-Methylnonane 0.007 0.007 0.004 1.941 90 98.685 17301-94-8 I10 4-Methylnonane 0.018 0.018 0.011 4.889 91 98.885 ? Unidentified 0.212 0.219 0.127 72.155 92 99.102 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.819 0.697 0.582 238.610 93 99.663 5911-04-6 I10 3-Methylnonane 0.035 0.036 0.021 9.549 94 100.128 ? Unidentified 0.018 0.013 0.010 5.995 95 100.255 ? Unidentified 0.053 0.053 0.029 17.901 96 100.476 I11 C11-Isoparaffin-2 0.029 0.029 0.016 8.000

97 100.757 95-63-6 Q9 1,2,4-Trimethylbenzene 4.265 3.650 3.028 1242.251 98 100.941 ? Unidentified 0.038 0.041 0.023 12.875 99 101.062 ? Unidentified 0.021 0.022 0.013 7.243 100 102.107 17302-01-1 I10 3-Ethyl-3-methylheptane 0.062 0.062 0.034 16.838 101 102.384 538-93-2 Q10 i-Butylbenzene 0.119 0.105 0.076 34.516 102 102.662 124-18-5 P10 n-Decane 0.099 0.102 0.060 27.135 103 102.973 ? Unidentified 0.016 0.017 0.010 5.594 104 103.614 526-73-8 Q9 1,2,3-Trimethylbenzene 0.758 0.635 0.538 220.858 105 104.011 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.022 0.019 0.014 6.377 106 104.192 I11 C11 Isoparaffin-4 0.011 0.011 0.006 2.959

107 104.393 ? Unidentified 0.062 0.054 0.039 20.934 108 104.802 J9 Indan 0.252 0.196 0.182 74.684 109 105.430 J10 Indene 0.411 0.319 0.297 121.557 110 106.149 I11 C11-Isoparaffin-7 0.184 0.185 0.100 50.221 111 106.333 141-93-5 Q10 1,3-Diethylbenzene 0.121 0.105 0.077 35.120 112 106.612 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.847 0.737 0.538 245.270 113 106.952 105-05-5 Q10 1,4-Diethylbenzene 0.352 0.306 0.224 101.935 114 107.049 104-51-8 Q10 n-Butylbenzene 0.077 0.067 0.049 22.398 115 107.176 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.417 0.355 0.265 120.839 116 107.449 135-01-3 Q10 1,2-Diethylbenzene 0.059 0.050 0.037 17.075

117 107.888 ? Unidentified 0.046 0.046 0.025 15.665 118 108.025 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.156 0.134 0.099 45.234 119 108.163 ? Unidentified 0.054 0.055 0.030 18.347 120 108.244 ? Unidentified 0.048 0.048 0.026 16.228 121 108.366 I11 C11- Isoparaffin-11 0.420 0.423 0.229 114.992 122 108.551 ? Unidentified 0.136 0.137 0.074 46.154 123 108.880 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.385 0.329 0.245 111.500 124 109.036 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.830 0.709 0.528 240.423 125 109.201 J10 2-Methylindan 0.093 0.072 0.060 27.469 126 109.549 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.975 0.836 0.620 282.584

127 110.099 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.412 0.347 0.262 119.420 128 110.528 ? Unidentified 0.011 0.010 0.006 3.669 129 110.729 693-61-8 K11 2-Undecene, (E)- 0.032 0.032 0.019 8.655

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 110.859 ? Unidentified 0.039 0.039 0.024 13.207 131 111.010 Q11 1-Methyl-4-t-butylbenzene 0.099 0.088 0.057 28.659 132 111.223 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.370 0.311 0.235 107.190 133 111.533 1120-21-4 P11 n-Undecane 0.066 0.066 0.036 17.952 134 111.691 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.070 0.059 0.041 20.330 135 111.799 ? Unidentified 0.029 0.025 0.017 9.917 136 111.904 Q11 C11 - Aromatic - 1 0.016 0.014 0.009 4.647 137 112.169 Q10 1,2,4,5-Tetramethylbenzene 0.867 0.732 0.551 251.079 138 112.438 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 1.193 1.004 0.758 345.596 139 112.624 ? Unidentified 0.010 0.008 0.006 3.329

140 112.796 ? Unidentified 0.011 0.009 0.007 3.813 141 112.967 I12 C12 - IsoParaffin - 1 0.012 0.012 0.006 3.388 142 113.291 ? Unidentified 0.031 0.032 0.016 10.619 143 113.583 Q11 C11 - Aromatic - 3 0.153 0.129 0.088 44.075 144 113.766 874-35-1 H10 5-Methylindan 0.350 0.295 0.226 101.485 145 113.904 Q12 1,2-Di-i-propylbenzene 0.152 0.128 0.080 43.793 146 114.119 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.217 0.183 0.125 62.662 147 114.278 Q11 C11 - Aromatic - 4 0.105 0.088 0.060 30.286 148 114.517 824-22-6 J10 4-Methylindan 0.493 0.415 0.318 142.830 149 114.680 ? Unidentified 0.115 0.097 0.066 38.983

150 114.768 824-63-5 H10 2-Methylindan 0.366 0.308 0.236 106.043 151 114.979 ? Unidentified 0.038 0.032 0.022 12.859 152 115.091 538-68-1 Q11 n-Pentylbenzene 0.053 0.045 0.031 15.365 153 115.322 Q11 tert-Pentylbenzene 0.224 0.188 0.129 64.488 154 115.634 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.099 0.083 0.057 28.520 155 115.743 Q11 C11 - Aromatic - 7 0.125 0.110 0.072 36.010 156 116.073 I12 C12 - IsoParaffin - 4 0.007 0.007 0.003 1.960 157 116.206 100-18-5 Q12 1,4-Di-i-propylbenzene 0.185 0.156 0.097 53.144 158 116.633 91-20-3 G10 Naphthalene 0.218 0.159 0.145 66.044 159 116.843 J11 4,7-Dimethyl Indane 0.012 0.009 0.007 3.597

160 117.081 J11 1,1-Dimethyl Indane 0.052 0.040 0.030 15.309 161 117.250 J12 Dimethyl Indane - 1 0.018 0.014 0.011 5.350 162 117.431 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.026 0.022 0.014 7.479 163 117.565 J12 Dimethyl Indane - 2 0.005 0.004 0.003 1.557 164 117.735 Q12 1,3-Di-n-propylbenzene 0.135 0.113 0.071 38.715 165 117.847 Q11 C11 - Aromatic - 11 0.074 0.065 0.043 21.340 166 118.402 Q11 C11 - Aromatic - 12 0.042 0.037 0.024 12.031 167 119.030 Q11 C11 - Aromatic - 13 0.006 0.005 0.003 1.606 168 119.340 102-25-0 Q12 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.696 169 123.282 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.006 2.828

170 124.147 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.515 171 125.443 ? Unidentified 0.004 0.003 0.002 1.502 172 129.864 ? Unidentified 0.003 0.002 0.002 1.017

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 132.811 ? Unidentified 0.004 0.004 0.001 1.250

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 9.801 106-97-8 n-Butane 1.890 2.448 2.775 506.033

17.722 109-66-0 n-Pentane 0.819 0.981 0.969 220.865 35.323 110-54-3 n-Hexane 0.426 0.484 0.422 115.358 57.610 142-82-5 n-Heptane 0.095 0.104 0.081 25.819 77.555 111-65-9 n-Octane 0.018 0.019 0.013 4.885 102.662 124-18-5 n-Decane 0.099 0.102 0.060 27.135 111.533 1120-21-4 n-Undecane 0.066 0.066 0.036 17.952

I-Paraffins 8.618 75-28-5 i-Butane 0.029 0.039 0.043 7.802

10.399 463-82-1 2,2-Dimethylpropane 0.029 0.036 0.034 7.749 14.745 78-78-4 i-Pentane 12.205 14.763 14.433 3290.084 22.649 75-83-2 2,2-Dimethylbutane 0.322 0.371 0.318 87.037 27.871 79-29-8 2,3-Dimethylbutane 1.591 1.803 1.575 430.647 28.992 107-83-5 2-Methylpentane 10.430 11.969 10.327 2822.785 31.616 96-14-0 3-Methylpentane 6.239 7.039 6.177 1688.612 41.768 108-08-7 2,4-Dimethylpentane 0.152 0.169 0.129 41.289 50.198 591-76-4 2-Methylhexane 0.444 0.491 0.378 120.723 52.032 589-34-4 3-Methylhexane 0.286 0.312 0.243 77.645 71.685 592-27-8 2-Methylheptane 0.017 0.018 0.013 4.680 71.938 589-53-7 4-Methylheptane 0.010 0.010 0.007 2.625 73.011 589-81-1 3-Methylheptane 0.020 0.021 0.015 5.419 95.265 2051-30-1 2,4-Dimethyloctane 0.008 0.008 0.005 2.089 98.496 15869-85-9 5-Methylnonane 0.007 0.007 0.004 1.941 98.685 17301-94-8 4-Methylnonane 0.018 0.018 0.011 4.889 99.663 5911-04-6 3-Methylnonane 0.035 0.036 0.021 9.549 100.476 C11-Isoparaffin-2 0.029 0.029 0.016 8.000 102.107 17302-01-1 3-Ethyl-3-methylheptane 0.062 0.062 0.034 16.838 104.192 C11 Isoparaffin-4 0.011 0.011 0.006 2.959 106.149 C11-Isoparaffin-7 0.184 0.185 0.100 50.221 108.366 C11- Isoparaffin-11 0.420 0.423 0.229 114.992 112.967 C12 - IsoParaffin - 1 0.012 0.012 0.006 3.388 116.073 C12 - IsoParaffin - 4 0.007 0.007 0.003 1.960

Aromatics Mono-Aromatics 45.154 71-42-3 Benzene 0.707 0.603 0.773 211.249

68.651 108-88-3 Toluene 10.784 9.322 9.986 3184.956 84.445 100-41-4 Ethylbenzene 2.185 1.889 1.756 640.555 85.692 108-38-3 m-Xylene 5.346 4.637 4.297 1567.149 85.836 106-42-3 p-Xylene 2.512 2.187 2.019 736.435 88.657 95-47-6 o-Xylene 1.578 1.343 1.268 462.494 92.836 98-82-8 i-Propylbenzene 0.039 0.034 0.028 11.462 96.305 103-65-1 n-Propylbenzene 0.490 0.426 0.348 142.603 97.164 620-14-4 1-Methyl-3-ethylbenzene 2.108 1.827 1.496 613.883 97.394 622-96-8 1-Methyl-4-ethylbenzene 1.013 0.882 0.719 295.144 98.022 108-67-8 1,3,5-Trimethylbenzene 1.391 1.205 0.988 405.233 99.102 611-14-3 1-Methyl-2-ethylbenzene 0.819 0.697 0.582 238.610 100.757 95-63-6 1,2,4-Trimethylbenzene 4.265 3.650 3.028 1242.251

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 102.384 538-93-2 i-Butylbenzene 0.119 0.105 0.076 34.516

103.614 526-73-8 1,2,3-Trimethylbenzene 0.758 0.635 0.538 220.858 104.011 535-77-3 1-Methyl-3-i-propylbenzene 0.022 0.019 0.014 6.377 106.333 141-93-5 1,3-Diethylbenzene 0.121 0.105 0.077 35.120 106.612 1074-43-7 1-Methyl-3-n-propylbenzene 0.847 0.737 0.538 245.270 106.952 105-05-5 1,4-Diethylbenzene 0.352 0.306 0.224 101.935 107.049 104-51-8 n-Butylbenzene 0.077 0.067 0.049 22.398 107.176 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.417 0.355 0.265 120.839 107.449 135-01-3 1,2-Diethylbenzene 0.059 0.050 0.037 17.075 108.025 1074-17-5 1-Methyl-2-n-propylbenzene 0.156 0.134 0.099 45.234 108.880 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.385 0.329 0.245 111.500 109.036 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.830 0.709 0.528 240.423 109.549 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.975 0.836 0.620 282.584 110.099 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.412 0.347 0.262 119.420 111.010 1-Methyl-4-t-butylbenzene 0.099 0.088 0.057 28.659 111.223 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.370 0.311 0.235 107.190 111.691 4218-48-8 1-Ethyl-4-i-propylbenzene 0.070 0.059 0.041 20.330 111.904 C11 - Aromatic - 1 0.016 0.014 0.009 4.647 112.169 1,2,4,5-Tetramethylbenzene 0.867 0.732 0.551 251.079 112.438 527-53-7 1,2,3,5-Tetramethylbenzene 1.193 1.004 0.758 345.596 113.583 C11 - Aromatic - 3 0.153 0.129 0.088 44.075 113.904 1,2-Di-i-propylbenzene 0.152 0.128 0.080 43.793 114.119 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.217 0.183 0.125 62.662 114.278 C11 - Aromatic - 4 0.105 0.088 0.060 30.286 115.091 538-68-1 n-Pentylbenzene 0.053 0.045 0.031 15.365 115.322 tert-Pentylbenzene 0.224 0.188 0.129 64.488 115.634 577-55-9 1-Methyl-2-n-butylbenzene 0.099 0.083 0.057 28.520 115.743 C11 - Aromatic - 7 0.125 0.110 0.072 36.010 116.206 100-18-5 1,4-Di-i-propylbenzene 0.185 0.156 0.097 53.144 117.431 7364-19-4 1t-Butyl-4-ethylbenzene 0.026 0.022 0.014 7.479 117.735 1,3-Di-n-propylbenzene 0.135 0.113 0.071 38.715 117.847 C11 - Aromatic - 11 0.074 0.065 0.043 21.340 118.402 C11 - Aromatic - 12 0.042 0.037 0.024 12.031 119.030 C11 - Aromatic - 13 0.006 0.005 0.003 1.606 119.340 102-25-0 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.696

Naphthalenes 116.633 91-20-3 Naphthalene 0.218 0.159 0.145 66.044

123.282 91-57-6 2-Methylnaphthalene 0.009 0.007 0.006 2.828 124.147 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.515

Naphtheno/Olefino-Benzs

113.766 874-35-1 5-Methylindan 0.350 0.295 0.226 101.485 114.768 824-63-5 2-Methylindan 0.366 0.308 0.236 106.043

Indenes 104.802 Indan 0.252 0.196 0.182 74.684

105.430 Indene 0.411 0.319 0.297 121.557 109.201 2-Methylindan 0.093 0.072 0.060 27.469 114.517 824-22-6 4-Methylindan 0.493 0.415 0.318 142.830

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Indenes 116.843 4,7-Dimethyl Indane 0.012 0.009 0.007 3.597

117.081 1,1-Dimethyl Indane 0.052 0.040 0.030 15.309 117.250 Dimethyl Indane - 1 0.018 0.014 0.011 5.350 117.565 Dimethyl Indane - 2 0.005 0.004 0.003 1.557

Naphthenes Mono-Naphthenes 27.137 287-92-3 Cyclopentane 0.270 0.272 0.329 74.922

40.181 96-37-7 Methylcyclopentane 0.763 0.764 0.774 211.574 47.068 110-82-7 Cyclohexane 0.066 0.063 0.067 18.243 52.884 1759-58-6 1t,3-Dimethylcyclopentane 0.100 0.100 0.087 27.704 53.472 2532-58-3 1c,3-Dimethylcyclopentane 0.067 0.067 0.058 18.498 54.098 822-50-4 1t,2-Dimethylcyclopentane 0.059 0.059 0.052 16.442 59.196 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.016 5.253 61.035 108-87-2 Methylcyclohexane 0.042 0.041 0.037 11.658

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.412 115-11-7 Isobutene 0.016 0.020 0.024 4.346

9.452 106-98-9 Butene-1 0.019 0.024 0.029 5.219 10.277 624-64-6 t-Butene-2 0.074 0.091 0.112 20.424 11.000 590-18-1 c-Butene-2 0.087 0.105 0.133 24.178 16.360 109-67-1 Pentene-1 0.339 0.397 0.412 93.993 18.830 646-04-8 t-Pentene-2 0.862 0.997 1.049 239.110 19.852 627-20-3 c-Pentene-2 0.473 0.541 0.576 131.228 32.979 592-41-6 Hexene-1 0.166 0.184 0.168 46.069 35.967 13269-52-8 t-Hexene-3 0.273 0.300 0.276 75.589 36.441 4050-45-7 t-Hexene-2 0.523 0.574 0.530 145.033 38.268 7688-21-3 c-Hexene-2 0.222 0.240 0.225 61.522 55.024 592-76-7 Heptene-1 0.028 0.030 0.024 7.779 56.879 14686-14-7 t-Heptene-3 0.034 0.036 0.029 9.321 57.830 7642-10-6 c-Heptene-3 0.027 0.029 0.023 7.450 58.737 14686-13-6 t-Heptene-2 0.014 0.014 0.012 3.753 110.729 693-61-8 2-Undecene, (E)- 0.032 0.032 0.019 8.655

Iso-Olefins 13.145 563-45-1 3-Methylbutene-1 0.331 0.396 0.403 91.846

17.198 563-46-2 2-Methylbutene-1 0.515 0.593 0.627 142.805 20.523 513-35-9 2-Methylbutene-2 1.061 1.201 1.291 294.302 28.738 691-38-3 4-Methyl-c-pentene-2 0.043 0.048 0.044 12.008 29.383 674-76-0 4-Methyl-t-pentene-2 0.136 0.151 0.137 37.578 32.755 763-29-1 2-Methylpentene-1 0.232 0.254 0.235 64.237 35.165 760-21-4 2-Ethylbutene-1 0.071 0.077 0.072 19.694 36.933 625-27-4 2-Methylpentene-2 0.354 0.384 0.359 98.249 37.344 922-62-3 3-Methyl-c-pentene-2 0.274 0.295 0.278 76.109 39.613 3404-73-7 3,3-Dimethylpentene-1 0.325 0.348 0.283 90.243 42.062 594-56-9 2,3,3-Trimethylbutene-1 0.011 0.011 0.009 2.930 46.176 3404-61-3 3-Methylhexene-1 0.017 0.018 0.014 4.587 46.760 3524-73-0 5-Methylhexene-1 0.023 0.025 0.020 6.502

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 48.815 15840-60-5 2-Methyl-c-hexene-3 0.042 0.045 0.037 11.660

49.160 3769-23-1 4-Methylhexene-1 0.012 0.013 0.011 3.352 49.807 3404-55-5 4-Methyl-t/c-hexene-2 0.053 0.056 0.046 14.686 54.396 C7 - Iso-Olefin - 2 0.023 0.024 0.020 6.406 56.358 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.013 4.011 57.237 6094-02-6 2-Methylhexene-1 0.060 0.064 0.052 16.594 58.109 2738-19-4 2-Methyl-2-hexene 0.027 0.028 0.024 7.502 58.353 3899-36-3 3-Methyl-t-hexene-3 0.021 0.022 0.018 5.726 59.637 20710-38-8 3-Methyl-t-hexene-2 0.016 0.017 0.014 4.475 60.423 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.014 0.014 0.012 3.778

Naphtheno-Olefins 25.284 142-29-0 Cyclopentene 0.202 0.196 0.253 57.731

45.357 693-89-0 1-Methylcyclopentene 0.379 0.365 0.394 107.702 50.676 110-83-8 Cyclohexene 0.046 0.043 0.048 12.859

Di-Olefins 18.234 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 3.049

20.853 2004-70-8 1t,3-Pentadiene 0.016 0.018 0.020 4.514

Oxygenates 12.764 64-17-5 Ethanol 8.547 8.118 15.829 1018.567

26.530 71-23-8 n-Propanol 0.186 0.174 0.264 36.052

Unidentified 19.469 Unidentified 0.006 0.007 0.007 1.974

22.104 Unidentified 0.006 0.006 0.008 2.024 28.273 Unidentified 0.053 0.053 0.051 17.943 44.952 Unidentified 0.012 0.012 0.013 4.227 47.610 Unidentified 0.036 0.038 0.031 12.157 98.885 Unidentified 0.212 0.219 0.127 72.155 100.128 Unidentified 0.018 0.013 0.010 5.995 100.255 Unidentified 0.053 0.053 0.029 17.901 100.941 Unidentified 0.038 0.041 0.023 12.875 101.062 Unidentified 0.021 0.022 0.013 7.243 102.973 Unidentified 0.016 0.017 0.010 5.594 104.393 Unidentified 0.062 0.054 0.039 20.934 107.888 Unidentified 0.046 0.046 0.025 15.665 108.163 Unidentified 0.054 0.055 0.030 18.347 108.244 Unidentified 0.048 0.048 0.026 16.228 108.551 Unidentified 0.136 0.137 0.074 46.154 110.528 Unidentified 0.011 0.010 0.006 3.669 110.859 Unidentified 0.039 0.039 0.024 13.207 111.799 Unidentified 0.029 0.025 0.017 9.917 112.624 Unidentified 0.010 0.008 0.006 3.329 112.796 Unidentified 0.011 0.009 0.007 3.813 113.291 Unidentified 0.031 0.032 0.016 10.619 114.680 Unidentified 0.115 0.097 0.066 38.983 114.979 Unidentified 0.038 0.032 0.022 12.859 125.443 Unidentified 0.004 0.003 0.002 1.502 129.864 Unidentified 0.003 0.002 0.002 1.017

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 132.811 Unidentified 0.004 0.004 0.001 1.250

Plus

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane Unidentified

2-Methyl-c-hexene-3 4-Methylhexene-1 4-Methyl-t/c-hexene-2

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-t-hexene-3 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Toluene

2-Methylheptane 4-Methylheptane

3-Methylheptane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF95.090.085.080.075.0

n-Octane

Ethylbenzene

m-Xylene p-Xylene

o-Xylene

i-Propylbenzene

2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 2-Methylindan

1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified C11 - Aromatic - 1

1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Unidentified 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene Dimethyl Indane - 2 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12
C11 - Aromatic - 13 1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF Sample: ODDB-91319 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91319 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000015.D\SIG1000015_FID1_A.CDF145.0140.0135.0130.0125.0 Unidentified

Unidentified

Unidentified

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 9.210 10.918 11.430

I-Paraffins 28.756 32.600 29.644

Aromatics 47.072 40.840 42.347 Mono-Aromatics 44.838 39.031 40.637 Naphthalenes 0.123 0.091 0.090 Naphtheno/Olefino-Benzs 0.578 0.492 0.420 Indenes 1.533 1.227 1.198

Naphthenes 5.419 5.392 5.997 Mono-Naphthenes 5.419 5.392 5.997 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 6.741 7.568 8.511 n-Olefins 3.069 3.521 3.963 Iso-Olefins 3.117 3.504 3.850 Naphtheno-Olefins 0.534 0.519 0.668 Di-Olefins 0.022 0.024 0.031

Oxygenates 0.111 0.105 0.178

Unidentified 2.692 2.578 1.894

Plus 0.000 0.000 0.000

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.112 0.107 0.180 C4 1.807 2.349 3.002 C5 13.617 16.303 18.294 C6 17.895 19.659 20.208 C7 21.903 20.227 22.445 C8 19.824 19.193 17.370 C9 11.545 10.253 9.175 C10 8.125 7.009 5.879 C11 2.165 2.048 1.369 C12 0.315 0.273 0.186

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.002 0.002 C4 1.534 2.006 2.536 C5 2.607 3.152 3.473 C6 4.196 4.818 4.681 C7 0.431 0.478 0.414 C8 0.152 0.164 0.128 C9 0.086 0.090 0.064 C10 0.106 0.110 0.072 C11 0.096 0.098 0.059

I-Paraffins C4 0.037 0.051 0.062 C5 7.294 8.915 9.718 C6 6.924 7.962 7.724 C7 3.071 3.424 2.946 C8 8.807 9.516 7.412 C9 1.139 1.215 0.854 C10 0.401 0.414 0.264 C11 1.056 1.075 0.650 C12 0.027 0.028 0.015

Mono-Aromatics C6 0.610 0.526 0.751 C7 16.637 14.528 17.357 C8 10.697 9.348 9.686 C9 10.024 8.704 8.017 C10 5.705 4.926 4.086 C11 0.877 0.754 0.569 C12 0.288 0.245 0.171

Naphthalenes C10 0.102 0.075 0.076 C11 0.021 0.016 0.014

Naphtheno/Olefino-Benzs C10 0.578 0.492 0.420

Indenes C9 0.261 0.205 0.213 C10 1.223 0.983 0.954 C11 0.049 0.038 0.032

Mono-Naphthenes C5 0.279 0.283 0.383 C6 3.710 3.690 4.237 C7 1.252 1.243 1.226 C8 0.168 0.165 0.144 C10 0.010 0.009 0.007

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes n-Olefins C4 0.236 0.293 0.404 C5 1.614 1.884 2.212 C6 1.102 1.221 1.259 C7 0.016 0.018 0.016 C9 0.035 0.039 0.027 C11 0.065 0.067 0.045

Iso-Olefins C5 1.621 1.868 2.222 C6 1.000 1.100 1.142 C7 0.496 0.536 0.486

Naphtheno-Olefins C5 0.181 0.177 0.255 C6 0.353 0.342 0.413

Di-Olefins C5 0.022 0.024 0.031

Oxygenates C3 0.111 0.105 0.178

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 23.50 22.69 5% 80.11 79.67 10% 87.52 81.50 15% 101.34 96.27 20% 140.23 135.33 25% 154.41 144.17 30% 158.84 154.55 35% 187.04 158.56 40% 209.76 182.15 45% 229.83 209.58 50% 230.21 228.41 55% 230.58 230.18 60% 230.96 230.61 65% 254.84 231.04 70% 281.15 275.47 75% 291.57 281.55 80% 323.22 318.96 85% 335.58 334.04 90% 358.77 352.22 95% 372.94 368.42 FBP 404.60 404.60

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.389 74-98-6 P3 Propane 0.001 0.002 0.002 0.267 2 8.610 75-28-5 I4 i-Butane 0.037 0.051 0.062 9.903 3 9.402 115-11-7 K4 Isobutene 0.020 0.026 0.035 5.622 4 9.441 106-98-9 K4 Butene-1 0.024 0.031 0.042 6.677 5 9.790 106-97-8 P4 n-Butane 1.534 2.006 2.536 406.830 6 10.264 624-64-6 K4 t-Butene-2 0.089 0.112 0.153 24.556 7 10.386 463-82-1 I5 2,2-Dimethylpropane 0.034 0.044 0.046 9.189 8 10.984 590-18-1 K4 c-Butene-2 0.102 0.124 0.174 27.905 9 13.124 563-45-1 C5 3-Methylbutene-1 0.070 0.085 0.096 19.337 10 14.709 78-78-4 I5 i-Pentane 7.259 8.871 9.673 1939.149

11 16.326 109-67-1 K5 Pentene-1 0.323 0.382 0.443 88.811 12 17.162 563-46-2 C5 2-Methylbutene-1 0.507 0.590 0.694 139.210 13 17.690 109-66-0 P5 n-Pentane 2.607 3.152 3.473 696.284 14 18.203 78-79-5 E5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.473 15 18.796 646-04-8 K5 t-Pentene-2 0.835 0.975 1.144 229.307 16 19.815 627-20-3 K5 c-Pentene-2 0.456 0.527 0.625 125.356 17 20.488 513-35-9 C5 2-Methylbutene-2 1.044 1.193 1.431 286.849 18 20.820 2004-70-8 E5 1t,3-Pentadiene 0.013 0.014 0.018 3.642 19 22.069 ? Unidentified 0.005 0.005 0.007 1.531 20 22.613 75-83-2 I6 2,2-Dimethylbutane 0.183 0.213 0.204 49.009

21 25.240 142-29-0 B5 Cyclopentene 0.181 0.177 0.255 51.071 22 26.411 ? Unidentified 0.038 0.036 0.061 12.774 23 26.477 71-23-8 X3 n-Propanol 0.111 0.105 0.178 21.352 24 27.089 287-92-3 M5 Cyclopentane 0.279 0.283 0.383 76.677 25 27.824 79-29-8 I6 2,3-Dimethylbutane 1.230 1.407 1.372 329.850 26 28.224 ? Unidentified 0.051 0.052 0.056 17.235 27 28.682 691-38-3 C6 4-Methyl-c-pentene-2 0.044 0.049 0.050 12.103 28 28.903 107-83-5 I6 2-Methylpentane 3.098 3.591 3.455 830.722 29 29.336 674-76-0 C6 4-Methyl-t-pentene-2 0.132 0.148 0.150 36.167 30 31.543 96-14-0 I6 3-Methylpentane 2.414 2.751 2.692 647.278

31 32.710 763-29-1 C6 2-Methylpentene-1 0.224 0.248 0.256 61.558 32 32.936 592-41-6 K6 Hexene-1 0.155 0.173 0.177 42.683 33 35.302 110-54-3 P6 n-Hexane 4.196 4.818 4.681 1125.424 34 35.928 13269-52-8 K6 t-Hexene-3 0.256 0.284 0.292 70.339 35 36.399 4050-45-7 K6 t-Hexene-2 0.484 0.537 0.553 133.118 36 36.895 625-27-4 C6 2-Methylpentene-2 0.340 0.373 0.388 93.437 37 37.305 922-62-3 C6 3-Methyl-c-pentene-2 0.260 0.282 0.297 71.432 38 38.233 7688-21-3 K6 c-Hexene-2 0.207 0.226 0.236 56.757 39 39.578 3404-73-7 C7 3,3-Dimethylpentene-1 0.311 0.335 0.304 85.343 40 40.155 96-37-7 M6 Methylcyclopentane 2.129 2.153 2.431 584.826

41 41.729 108-08-7 I7 2,4-Dimethylpentane 0.897 1.009 0.860 241.393 42 42.269 464-06-2 I7 2,2,3-Trimethylbutane 0.099 0.109 0.095 26.755 43 44.927 ? Unidentified 0.010 0.010 0.012 3.400

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 45.128 71-42-3 Q6 Benzene 0.610 0.526 0.751 180.590 45 45.336 693-89-0 B6 1-Methylcyclopentene 0.319 0.310 0.373 89.771 46 46.154 3404-61-3 C7 3-Methylhexene-1 0.011 0.012 0.011 3.112 47 46.741 3524-73-0 C7 5-Methylhexene-1 0.080 0.087 0.078 21.944 48 47.056 110-82-7 M6 Cyclohexane 1.581 1.538 1.806 434.417 49 47.589 ? Unidentified 0.028 0.030 0.027 9.343 50 48.800 15840-60-5 C7 2-Methyl-c-hexene-3 0.030 0.033 0.029 8.239 51 49.793 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.034 0.037 0.033 9.400 52 50.192 591-76-4 I7 2-Methylhexane 1.456 1.625 1.397 392.129 53 50.665 110-83-8 B6 Cyclohexene 0.034 0.032 0.040 9.367

54 52.027 589-34-4 I7 3-Methylhexane 0.619 0.682 0.593 166.545 55 52.878 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.146 0.148 0.143 40.200 56 53.467 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.116 0.117 0.113 31.756 57 54.093 822-50-4 M7 1t,2-Dimethylcyclopentane 0.158 0.159 0.155 43.438 58 54.711 540-84-1 I8 2,2,4-Trimethylpentane 4.501 4.926 3.788 1214.468 59 56.879 14686-14-7 K7 t-Heptene-3 0.016 0.018 0.016 4.478 60 57.232 6094-02-6 C7 2-Methylhexene-1 0.025 0.027 0.025 6.952 61 57.613 142-82-5 P7 n-Heptane 0.431 0.478 0.414 116.130 62 58.113 2738-19-4 C7 2-Methyl-2-hexene 0.005 0.005 0.005 1.277 63 61.060 108-87-2 M7 Methylcyclohexane 0.802 0.789 0.785 220.262

64 62.012 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.017 0.017 0.014 4.630 65 62.419 590-73-8 I8 2,2-Dimethylhexane 0.020 0.022 0.017 5.419 66 63.856 1640-89-7 M7 Ethylcyclopentane 0.030 0.030 0.030 8.309 67 64.508 564-02-3 I8 2,2,3-Trimethylpentane 0.296 0.313 0.249 79.766 68 64.750 592-13-2 I8 2,5-Dimethylhexane 0.684 0.747 0.576 184.579 69 65.089 589-43-5 I8 2,4-Dimethylhexane 0.570 0.616 0.479 153.656 70 65.926 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.016 0.016 0.014 4.377 71 68.097 565-75-3 I8 2,3,4-Trimethylpentane 1.925 2.027 1.620 519.307 72 68.693 108-88-3 Q7 Toluene 16.637 14.528 17.357 4869.130 73 70.428 584-94-1 I8 2,3-Dimethylhexane 0.490 0.521 0.412 132.194

74 71.697 592-27-8 I8 2-Methylheptane 0.101 0.109 0.085 27.231 75 71.957 589-53-7 I8 4-Methylheptane 0.081 0.087 0.068 21.896 76 72.092 ? Unidentified 0.037 0.039 0.032 12.619 77 72.862 M8 1,3-dimethyl-t-cyclohexane 0.071 0.070 0.061 19.490 78 73.021 589-81-1 I8 3-Methylheptane 0.092 0.099 0.077 24.815 79 73.204 619-99-8 I8 3-Ethylhexane 0.047 0.050 0.040 12.715 80 74.103 ? Unidentified 0.011 0.010 0.009 3.639 81 74.925 3522-94-9 I9 2,2,5-Trimethylhexane 0.862 0.923 0.646 232.996 82 76.189 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.028 0.027 0.024 7.713 83 77.563 111-65-9 P8 n-Octane 0.152 0.164 0.128 41.057

84 78.507 ? Unidentified 0.017 0.017 0.015 5.779 85 80.054 1069-53-0 I9 2,3,5-Trimethylhexane 0.123 0.129 0.092 33.233 86 81.232 1071-26-7 I9 2,4-Dimethylheptane 0.019 0.020 0.014 5.151

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 81.867 1678-91-7 M8 Ethylcyclohexane 0.037 0.035 0.031 10.074 88 82.194 1072-05-5 I9 2,6-Dimethylheptane 0.032 0.034 0.024 8.706 89 83.130 I9 2,5-Dimethylheptane 0.061 0.065 0.046 16.484 90 84.446 100-41-4 Q8 Ethylbenzene 1.798 1.570 1.628 522.199 91 84.861 ? Unidentified 0.008 0.007 0.006 2.531 92 85.692 108-38-3 Q8 m-Xylene 4.994 4.376 4.523 1450.718 93 85.835 106-42-3 Q8 p-Xylene 2.297 2.020 2.080 667.297 94 87.016 2216-34-4 I9 4-Methyloctane 0.011 0.012 0.008 3.053 95 87.149 3221-61-2 I9 2-Methyloctane 0.015 0.016 0.011 4.036 96 88.012 2216-33-3 I9 3-Methyloctane 0.016 0.016 0.012 4.198

97 88.481 K9 C9-isoolefin 0.035 0.039 0.027 9.721 98 88.659 95-47-6 Q8 o-Xylene 1.607 1.382 1.455 466.792 99 89.067 I10 C10 - IsoParaffin - 1 0.115 0.120 0.078 31.233 100 89.913 14720-74-2 I10 2,2,4-trimethylheptane 0.081 0.085 0.055 22.023 101 91.477 111-84-2 P9 n-Nonane 0.086 0.090 0.064 23.168 102 92.837 98-82-8 Q9 i-Propylbenzene 0.038 0.034 0.031 11.070 103 93.600 ? Unidentified 0.028 0.029 0.019 9.494 104 93.822 15869-87-1 I10 2,2-Dimethyloctane 0.010 0.010 0.007 2.698 105 95.266 2051-30-1 I10 2,4-Dimethyloctane 0.022 0.023 0.015 5.950 106 95.662 I10 2,6-Dimethyloctane 0.010 0.010 0.007 2.644

107 96.307 103-65-1 Q9 n-Propylbenzene 0.431 0.379 0.345 124.442 108 97.163 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.886 1.651 1.508 544.214 109 97.393 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.916 0.805 0.733 264.365 110 98.022 108-67-8 Q9 1,3,5-Trimethylbenzene 1.278 1.118 1.022 368.823 111 98.687 17301-94-8 I10 4-Methylnonane 0.017 0.017 0.011 4.512 112 98.887 ? Unidentified 0.426 0.444 0.288 143.526 113 99.103 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.755 0.649 0.604 217.809 114 99.664 5911-04-6 I10 3-Methylnonane 0.029 0.030 0.020 7.929 115 100.130 ? Unidentified 0.036 0.027 0.022 12.175 116 100.256 ? Unidentified 0.104 0.106 0.064 35.042

117 100.478 I11 C11-Isoparaffin-2 0.059 0.060 0.036 16.005 118 100.755 95-63-6 Q9 1,2,4-Trimethylbenzene 3.994 3.452 3.194 1152.541 119 100.943 ? Unidentified 0.078 0.084 0.053 26.125 120 101.064 ? Unidentified 0.045 0.046 0.030 15.025 121 101.322 1678-98-4 M10 i-Butylcyclohexane 0.010 0.009 0.007 2.651 122 102.109 17302-01-1 I10 3-Ethyl-3-methylheptane 0.117 0.119 0.072 31.663 123 102.388 538-93-2 Q10 i-Butylbenzene 0.176 0.156 0.126 50.492 124 102.662 124-18-5 P10 n-Decane 0.106 0.110 0.072 28.825 125 102.976 ? Unidentified 0.033 0.034 0.020 11.176 126 103.615 526-73-8 Q9 1,2,3-Trimethylbenzene 0.726 0.615 0.581 209.610

127 104.006 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.026 0.023 0.019 7.534 128 104.193 I11 C11 Isoparaffin-4 0.019 0.019 0.011 5.039 129 104.396 ? Unidentified 0.105 0.093 0.075 35.312

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 104.804 J9 Indan 0.261 0.205 0.213 76.622 131 105.434 J10 Indene 0.745 0.585 0.606 218.479 132 106.151 I11 C11-Isoparaffin-7 0.321 0.327 0.198 87.090 133 106.334 141-93-5 Q10 1,3-Diethylbenzene 0.107 0.094 0.077 30.811 134 106.623 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.079 0.949 0.773 309.837 135 106.943 105-05-5 Q10 1,4-Diethylbenzene 0.424 0.373 0.304 121.822 136 107.177 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.299 0.257 0.214 85.906 137 107.434 135-01-3 Q10 1,2-Diethylbenzene 0.085 0.073 0.061 24.410 138 107.889 ? Unidentified 0.083 0.084 0.051 27.896 139 108.027 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.104 0.090 0.074 29.713

140 108.165 ? Unidentified 0.095 0.097 0.059 31.866 141 108.246 ? Unidentified 0.085 0.087 0.052 28.648 142 108.369 I11 C11- Isoparaffin-11 0.658 0.669 0.404 178.339 143 108.552 ? Unidentified 0.225 0.229 0.138 75.739 144 108.882 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.222 0.192 0.159 63.736 145 108.987 ? Unidentified 0.837 0.722 0.600 281.737 146 109.206 J10 2-Methylindan 0.132 0.104 0.096 38.666 147 109.547 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.740 0.640 0.530 212.344 148 110.102 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.710 0.604 0.509 203.833 149 110.529 ? Unidentified 0.029 0.027 0.018 9.678

150 110.730 693-61-8 K11 2-Undecene, (E)- 0.065 0.067 0.045 17.715 151 110.861 ? Unidentified 0.077 0.078 0.052 25.772 152 111.000 Q11 1-Methyl-4-t-butylbenzene 0.090 0.080 0.058 25.705 153 111.222 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.331 0.281 0.237 95.136 154 111.533 1120-21-4 P11 n-Undecane 0.096 0.098 0.059 26.131 155 111.691 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.105 0.090 0.068 30.145 156 111.799 ? Unidentified 0.073 0.062 0.047 24.589 157 112.167 Q10 1,2,4,5-Tetramethylbenzene 0.587 0.501 0.420 168.482 158 112.435 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.814 0.692 0.583 233.637 159 112.649 ? Unidentified 0.014 0.012 0.009 4.800

160 112.788 ? Unidentified 0.022 0.018 0.016 7.298 161 112.967 I12 C12 - IsoParaffin - 1 0.027 0.028 0.015 7.328 162 113.295 ? Unidentified 0.040 0.041 0.023 13.337 163 113.449 ? Unidentified 0.012 0.012 0.007 4.069 164 113.585 Q11 C11 - Aromatic - 3 0.119 0.102 0.077 34.127 165 113.765 874-35-1 H10 5-Methylindan 0.261 0.222 0.190 74.824 166 113.904 Q12 1,2-Di-i-propylbenzene 0.105 0.089 0.062 29.918 167 114.119 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.145 0.123 0.094 41.447 168 114.282 Q11 C11 - Aromatic - 4 0.071 0.060 0.046 20.327 169 114.516 824-22-6 J10 4-Methylindan 0.346 0.295 0.252 99.408

170 114.768 824-63-5 H10 2-Methylindan 0.317 0.270 0.231 91.139 171 114.980 ? Unidentified 0.027 0.023 0.018 9.117 172 115.092 538-68-1 Q11 n-Pentylbenzene 0.030 0.026 0.020 8.691

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 115.323 Q11 tert-Pentylbenzene 0.138 0.118 0.090 39.540 174 115.634 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.058 0.049 0.038 16.606 175 115.744 Q11 C11 - Aromatic - 7 0.079 0.070 0.051 22.475 176 116.207 100-18-5 Q12 1,4-Di-i-propylbenzene 0.110 0.094 0.065 31.401 177 116.636 91-20-3 G10 Naphthalene 0.102 0.075 0.076 30.582 178 116.800 J11 4,7-Dimethyl Indane 0.021 0.016 0.014 6.122 179 117.083 J11 1,1-Dimethyl Indane 0.028 0.022 0.018 8.232 180 117.433 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.022 0.019 0.013 6.377 181 117.736 Q12 1,3-Di-n-propylbenzene 0.051 0.043 0.030 14.398 182 117.847 Q11 C11 - Aromatic - 11 0.026 0.024 0.017 7.558

183 118.403 Q11 C11 - Aromatic - 12 0.014 0.013 0.009 4.018 184 123.282 91-57-6 G11 2-Methylnaphthalene 0.015 0.011 0.010 4.326 185 124.147 90-12-0 G11 1-Methylnaphthalene 0.007 0.005 0.004 1.945 186 126.173 ? Unidentified 0.007 0.006 0.004 2.416 187 126.173 ? Unidentified 0.007 0.007 0.003 2.416

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.389 74-98-6 Propane 0.001 0.002 0.002 0.267

9.790 106-97-8 n-Butane 1.534 2.006 2.536 406.830 17.690 109-66-0 n-Pentane 2.607 3.152 3.473 696.284 35.302 110-54-3 n-Hexane 4.196 4.818 4.681 1125.424 57.613 142-82-5 n-Heptane 0.431 0.478 0.414 116.130 77.563 111-65-9 n-Octane 0.152 0.164 0.128 41.057 91.477 111-84-2 n-Nonane 0.086 0.090 0.064 23.168 102.662 124-18-5 n-Decane 0.106 0.110 0.072 28.825 111.533 1120-21-4 n-Undecane 0.096 0.098 0.059 26.131

I-Paraffins 8.610 75-28-5 i-Butane 0.037 0.051 0.062 9.903

10.386 463-82-1 2,2-Dimethylpropane 0.034 0.044 0.046 9.189 14.709 78-78-4 i-Pentane 7.259 8.871 9.673 1939.149 22.613 75-83-2 2,2-Dimethylbutane 0.183 0.213 0.204 49.009 27.824 79-29-8 2,3-Dimethylbutane 1.230 1.407 1.372 329.850 28.903 107-83-5 2-Methylpentane 3.098 3.591 3.455 830.722 31.543 96-14-0 3-Methylpentane 2.414 2.751 2.692 647.278 41.729 108-08-7 2,4-Dimethylpentane 0.897 1.009 0.860 241.393 42.269 464-06-2 2,2,3-Trimethylbutane 0.099 0.109 0.095 26.755 50.192 591-76-4 2-Methylhexane 1.456 1.625 1.397 392.129 52.027 589-34-4 3-Methylhexane 0.619 0.682 0.593 166.545 54.711 540-84-1 2,2,4-Trimethylpentane 4.501 4.926 3.788 1214.468 62.419 590-73-8 2,2-Dimethylhexane 0.020 0.022 0.017 5.419 64.508 564-02-3 2,2,3-Trimethylpentane 0.296 0.313 0.249 79.766 64.750 592-13-2 2,5-Dimethylhexane 0.684 0.747 0.576 184.579 65.089 589-43-5 2,4-Dimethylhexane 0.570 0.616 0.479 153.656 68.097 565-75-3 2,3,4-Trimethylpentane 1.925 2.027 1.620 519.307 70.428 584-94-1 2,3-Dimethylhexane 0.490 0.521 0.412 132.194 71.697 592-27-8 2-Methylheptane 0.101 0.109 0.085 27.231 71.957 589-53-7 4-Methylheptane 0.081 0.087 0.068 21.896 73.021 589-81-1 3-Methylheptane 0.092 0.099 0.077 24.815 73.204 619-99-8 3-Ethylhexane 0.047 0.050 0.040 12.715 74.925 3522-94-9 2,2,5-Trimethylhexane 0.862 0.923 0.646 232.996 80.054 1069-53-0 2,3,5-Trimethylhexane 0.123 0.129 0.092 33.233 81.232 1071-26-7 2,4-Dimethylheptane 0.019 0.020 0.014 5.151 82.194 1072-05-5 2,6-Dimethylheptane 0.032 0.034 0.024 8.706 83.130 2,5-Dimethylheptane 0.061 0.065 0.046 16.484 87.016 2216-34-4 4-Methyloctane 0.011 0.012 0.008 3.053 87.149 3221-61-2 2-Methyloctane 0.015 0.016 0.011 4.036 88.012 2216-33-3 3-Methyloctane 0.016 0.016 0.012 4.198 89.067 C10 - IsoParaffin - 1 0.115 0.120 0.078 31.233 89.913 14720-74-2 2,2,4-trimethylheptane 0.081 0.085 0.055 22.023 93.822 15869-87-1 2,2-Dimethyloctane 0.010 0.010 0.007 2.698 95.266 2051-30-1 2,4-Dimethyloctane 0.022 0.023 0.015 5.950 95.662 2,6-Dimethyloctane 0.010 0.010 0.007 2.644 98.687 17301-94-8 4-Methylnonane 0.017 0.017 0.011 4.512 99.664 5911-04-6 3-Methylnonane 0.029 0.030 0.020 7.929

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 100.478 C11-Isoparaffin-2 0.059 0.060 0.036 16.005

102.109 17302-01-1 3-Ethyl-3-methylheptane 0.117 0.119 0.072 31.663 104.193 C11 Isoparaffin-4 0.019 0.019 0.011 5.039 106.151 C11-Isoparaffin-7 0.321 0.327 0.198 87.090 108.369 C11- Isoparaffin-11 0.658 0.669 0.404 178.339 112.967 C12 - IsoParaffin - 1 0.027 0.028 0.015 7.328

Aromatics Mono-Aromatics 45.128 71-42-3 Benzene 0.610 0.526 0.751 180.590

68.693 108-88-3 Toluene 16.637 14.528 17.357 4869.130 84.446 100-41-4 Ethylbenzene 1.798 1.570 1.628 522.199 85.692 108-38-3 m-Xylene 4.994 4.376 4.523 1450.718 85.835 106-42-3 p-Xylene 2.297 2.020 2.080 667.297 88.659 95-47-6 o-Xylene 1.607 1.382 1.455 466.792 92.837 98-82-8 i-Propylbenzene 0.038 0.034 0.031 11.070 96.307 103-65-1 n-Propylbenzene 0.431 0.379 0.345 124.442 97.163 620-14-4 1-Methyl-3-ethylbenzene 1.886 1.651 1.508 544.214 97.393 622-96-8 1-Methyl-4-ethylbenzene 0.916 0.805 0.733 264.365 98.022 108-67-8 1,3,5-Trimethylbenzene 1.278 1.118 1.022 368.823 99.103 611-14-3 1-Methyl-2-ethylbenzene 0.755 0.649 0.604 217.809 100.755 95-63-6 1,2,4-Trimethylbenzene 3.994 3.452 3.194 1152.541 102.388 538-93-2 i-Butylbenzene 0.176 0.156 0.126 50.492 103.615 526-73-8 1,2,3-Trimethylbenzene 0.726 0.615 0.581 209.610 104.006 535-77-3 1-Methyl-3-i-propylbenzene 0.026 0.023 0.019 7.534 106.334 141-93-5 1,3-Diethylbenzene 0.107 0.094 0.077 30.811 106.623 1074-43-7 1-Methyl-3-n-propylbenzene 1.079 0.949 0.773 309.837 106.943 105-05-5 1,4-Diethylbenzene 0.424 0.373 0.304 121.822 107.177 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.299 0.257 0.214 85.906 107.434 135-01-3 1,2-Diethylbenzene 0.085 0.073 0.061 24.410 108.027 1074-17-5 1-Methyl-2-n-propylbenzene 0.104 0.090 0.074 29.713 108.882 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.222 0.192 0.159 63.736 109.547 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.740 0.640 0.530 212.344 110.102 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.710 0.604 0.509 203.833 111.000 1-Methyl-4-t-butylbenzene 0.090 0.080 0.058 25.705 111.222 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.331 0.281 0.237 95.136 111.691 4218-48-8 1-Ethyl-4-i-propylbenzene 0.105 0.090 0.068 30.145 112.167 1,2,4,5-Tetramethylbenzene 0.587 0.501 0.420 168.482 112.435 527-53-7 1,2,3,5-Tetramethylbenzene 0.814 0.692 0.583 233.637 113.585 C11 - Aromatic - 3 0.119 0.102 0.077 34.127 113.904 1,2-Di-i-propylbenzene 0.105 0.089 0.062 29.918 114.119 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.145 0.123 0.094 41.447 114.282 C11 - Aromatic - 4 0.071 0.060 0.046 20.327 115.092 538-68-1 n-Pentylbenzene 0.030 0.026 0.020 8.691 115.323 tert-Pentylbenzene 0.138 0.118 0.090 39.540 115.634 577-55-9 1-Methyl-2-n-butylbenzene 0.058 0.049 0.038 16.606 115.744 C11 - Aromatic - 7 0.079 0.070 0.051 22.475 116.207 100-18-5 1,4-Di-i-propylbenzene 0.110 0.094 0.065 31.401

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 117.433 7364-19-4 1t-Butyl-4-ethylbenzene 0.022 0.019 0.013 6.377

117.736 1,3-Di-n-propylbenzene 0.051 0.043 0.030 14.398 117.847 C11 - Aromatic - 11 0.026 0.024 0.017 7.558 118.403 C11 - Aromatic - 12 0.014 0.013 0.009 4.018

Naphthalenes 116.636 91-20-3 Naphthalene 0.102 0.075 0.076 30.582

123.282 91-57-6 2-Methylnaphthalene 0.015 0.011 0.010 4.326 124.147 90-12-0 1-Methylnaphthalene 0.007 0.005 0.004 1.945

Naphtheno/Olefino-Benzs

113.765 874-35-1 5-Methylindan 0.261 0.222 0.190 74.824 114.768 824-63-5 2-Methylindan 0.317 0.270 0.231 91.139

Indenes 104.804 Indan 0.261 0.205 0.213 76.622

105.434 Indene 0.745 0.585 0.606 218.479 109.206 2-Methylindan 0.132 0.104 0.096 38.666 114.516 824-22-6 4-Methylindan 0.346 0.295 0.252 99.408 116.800 4,7-Dimethyl Indane 0.021 0.016 0.014 6.122 117.083 1,1-Dimethyl Indane 0.028 0.022 0.018 8.232

Naphthenes Mono-Naphthenes 27.089 287-92-3 Cyclopentane 0.279 0.283 0.383 76.677

40.155 96-37-7 Methylcyclopentane 2.129 2.153 2.431 584.826 47.056 110-82-7 Cyclohexane 1.581 1.538 1.806 434.417 52.878 1759-58-6 1t,3-Dimethylcyclopentane 0.146 0.148 0.143 40.200 53.467 2532-58-3 1c,3-Dimethylcyclopentane 0.116 0.117 0.113 31.756 54.093 822-50-4 1t,2-Dimethylcyclopentane 0.158 0.159 0.155 43.438 61.060 108-87-2 Methylcyclohexane 0.802 0.789 0.785 220.262 62.012 4516-69-2 1,1,3-Trimethylcyclopentane 0.017 0.017 0.014 4.630 63.856 1640-89-7 Ethylcyclopentane 0.030 0.030 0.030 8.309 65.926 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.016 0.016 0.014 4.377 72.862 1,3-dimethyl-t-cyclohexane 0.071 0.070 0.061 19.490 76.189 2207-03-6 1t,3-Dimethylcyclohexane 0.028 0.027 0.024 7.713 81.867 1678-91-7 Ethylcyclohexane 0.037 0.035 0.031 10.074 101.322 1678-98-4 i-Butylcyclohexane 0.010 0.009 0.007 2.651

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.402 115-11-7 Isobutene 0.020 0.026 0.035 5.622

9.441 106-98-9 Butene-1 0.024 0.031 0.042 6.677 10.264 624-64-6 t-Butene-2 0.089 0.112 0.153 24.556 10.984 590-18-1 c-Butene-2 0.102 0.124 0.174 27.905 16.326 109-67-1 Pentene-1 0.323 0.382 0.443 88.811 18.796 646-04-8 t-Pentene-2 0.835 0.975 1.144 229.307 19.815 627-20-3 c-Pentene-2 0.456 0.527 0.625 125.356 32.936 592-41-6 Hexene-1 0.155 0.173 0.177 42.683 35.928 13269-52-8 t-Hexene-3 0.256 0.284 0.292 70.339 36.399 4050-45-7 t-Hexene-2 0.484 0.537 0.553 133.118

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 38.233 7688-21-3 c-Hexene-2 0.207 0.226 0.236 56.757

56.879 14686-14-7 t-Heptene-3 0.016 0.018 0.016 4.478 88.481 C9-isoolefin 0.035 0.039 0.027 9.721 110.730 693-61-8 2-Undecene, (E)- 0.065 0.067 0.045 17.715

Iso-Olefins 13.124 563-45-1 3-Methylbutene-1 0.070 0.085 0.096 19.337

17.162 563-46-2 2-Methylbutene-1 0.507 0.590 0.694 139.210 20.488 513-35-9 2-Methylbutene-2 1.044 1.193 1.431 286.849 28.682 691-38-3 4-Methyl-c-pentene-2 0.044 0.049 0.050 12.103 29.336 674-76-0 4-Methyl-t-pentene-2 0.132 0.148 0.150 36.167 32.710 763-29-1 2-Methylpentene-1 0.224 0.248 0.256 61.558 36.895 625-27-4 2-Methylpentene-2 0.340 0.373 0.388 93.437 37.305 922-62-3 3-Methyl-c-pentene-2 0.260 0.282 0.297 71.432 39.578 3404-73-7 3,3-Dimethylpentene-1 0.311 0.335 0.304 85.343 46.154 3404-61-3 3-Methylhexene-1 0.011 0.012 0.011 3.112 46.741 3524-73-0 5-Methylhexene-1 0.080 0.087 0.078 21.944 48.800 15840-60-5 2-Methyl-c-hexene-3 0.030 0.033 0.029 8.239 49.793 3404-55-5 4-Methyl-t/c-hexene-2 0.034 0.037 0.033 9.400 57.232 6094-02-6 2-Methylhexene-1 0.025 0.027 0.025 6.952 58.113 2738-19-4 2-Methyl-2-hexene 0.005 0.005 0.005 1.277

Naphtheno-Olefins 25.240 142-29-0 Cyclopentene 0.181 0.177 0.255 51.071

45.336 693-89-0 1-Methylcyclopentene 0.319 0.310 0.373 89.771 50.665 110-83-8 Cyclohexene 0.034 0.032 0.040 9.367

Di-Olefins 18.203 78-79-5 2-Methyl-1,3-Butadiene 0.009 0.010 0.012 2.473

20.820 2004-70-8 1t,3-Pentadiene 0.013 0.014 0.018 3.642

Oxygenates 26.477 71-23-8 n-Propanol 0.111 0.105 0.178 21.352

Unidentified 22.069 Unidentified 0.005 0.005 0.007 1.531

26.411 Unidentified 0.038 0.036 0.061 12.774 28.224 Unidentified 0.051 0.052 0.056 17.235 44.927 Unidentified 0.010 0.010 0.012 3.400 47.589 Unidentified 0.028 0.030 0.027 9.343 72.092 Unidentified 0.037 0.039 0.032 12.619 74.103 Unidentified 0.011 0.010 0.009 3.639 78.507 Unidentified 0.017 0.017 0.015 5.779 84.861 Unidentified 0.008 0.007 0.006 2.531 93.600 Unidentified 0.028 0.029 0.019 9.494 98.887 Unidentified 0.426 0.444 0.288 143.526 100.130 Unidentified 0.036 0.027 0.022 12.175 100.256 Unidentified 0.104 0.106 0.064 35.042 100.943 Unidentified 0.078 0.084 0.053 26.125 101.064 Unidentified 0.045 0.046 0.030 15.025 102.976 Unidentified 0.033 0.034 0.020 11.176 104.396 Unidentified 0.105 0.093 0.075 35.312

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 107.889 Unidentified 0.083 0.084 0.051 27.896

108.165 Unidentified 0.095 0.097 0.059 31.866 108.246 Unidentified 0.085 0.087 0.052 28.648 108.552 Unidentified 0.225 0.229 0.138 75.739 108.987 Unidentified 0.837 0.722 0.600 281.737 110.529 Unidentified 0.029 0.027 0.018 9.678 110.861 Unidentified 0.077 0.078 0.052 25.772 111.799 Unidentified 0.073 0.062 0.047 24.589 112.649 Unidentified 0.014 0.012 0.009 4.800 112.788 Unidentified 0.022 0.018 0.016 7.298 113.295 Unidentified 0.040 0.041 0.023 13.337 113.449 Unidentified 0.012 0.012 0.007 4.069 114.980 Unidentified 0.027 0.023 0.018 9.117 126.173 Unidentified 0.007 0.006 0.004 2.416 126.173 Unidentified 0.007 0.007 0.003 2.416

Plus

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

Unidentified 2,2-Dimethylbutane

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF45.040.035.030.025.0 Cyclopentene

Unidentified n-Propanol Cyclopentane

2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,2,3-Trimethylbutane

Unidentified Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane Unidentified

2-Methyl-c-hexene-3

4-Methyl-t/c-hexene-2

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF70.065.060.055.050.0 2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane

2,3,4-Trimethylpentane
Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

2,2,5-Trimethylhexane

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF95.090.085.080.075.0

1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified
m-Xylene p-Xylene

4-Methyloctane 2-Methyloctane

3-Methyloctane C9-isoolefin o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane

2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified

1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 Unidentified Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF Sample: ODDB-91320 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91320 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG1000018.D\SIG1000018_FID1_A.CDF145.0140.0135.0130.0125.0

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 10.491 11.676 12.131

I-Paraffins 43.167 46.627 43.041

Aromatics 25.125 20.714 21.444 Mono-Aromatics 23.036 19.123 19.847 Naphthalenes 0.129 0.091 0.093 Naphtheno/Olefino-Benzs 0.306 0.248 0.218 Indenes 1.654 1.252 1.285

Naphthenes 8.794 8.354 9.942 Mono-Naphthenes 8.794 8.354 9.942 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.782 8.327 9.682 n-Olefins 3.409 3.739 4.367 Iso-Olefins 3.609 3.872 4.379 Naphtheno-Olefins 0.724 0.675 0.883 Di-Olefins 0.040 0.042 0.052

Oxygenates 0.132 0.119 0.192

Unidentified 4.509 4.182 3.567

Plus 0.000 0.000 0.000

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.082 0.074 0.129 C4 0.744 0.896 1.207 C5 19.256 21.845 25.413 C6 23.872 24.945 26.466 C7 11.566 10.774 11.420 C8 24.611 24.311 20.711 C9 5.555 4.684 4.341 C10 7.232 5.939 5.168 C11 2.325 2.144 1.433 C12 0.249 0.207 0.144

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.002 C4 0.379 0.473 0.616 C5 2.987 3.446 3.908 C6 6.286 6.888 6.887 C7 0.502 0.530 0.473 C8 0.144 0.148 0.119 C9 0.062 0.063 0.046 C10 0.042 0.042 0.028 C11 0.088 0.086 0.053

I-Paraffins C4 0.035 0.045 0.056 C5 10.747 12.534 14.062 C6 8.301 9.115 9.093 C7 3.307 3.516 3.116 C8 18.410 19.094 15.215 C9 0.436 0.443 0.321 C10 0.448 0.440 0.284 C11 1.451 1.409 0.877 C12 0.032 0.031 0.018

Mono-Aromatics C6 0.652 0.536 0.788 C7 5.884 4.903 6.029 C8 5.884 4.907 5.232 C9 4.884 4.048 3.836 C10 4.859 4.017 3.418 C11 0.664 0.543 0.423 C12 0.208 0.169 0.121

Naphthalenes C10 0.109 0.077 0.080 C11 0.020 0.014 0.013

Naphtheno/Olefino-Benzs C10 0.306 0.248 0.218

Indenes C9 0.167 0.125 0.134 C10 1.447 1.097 1.126 C11 0.030 0.023 0.020 C12 0.009 0.006 0.006

Mono-Naphthenes C5 1.519 1.472 2.044 C6 5.809 5.496 6.516 C7 1.268 1.202 1.219 C8 0.173 0.162 0.145

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.005 0.004 0.004 C10 0.020 0.018 0.014

n-Olefins C4 0.280 0.331 0.470 C5 1.879 2.092 2.529 C6 1.162 1.228 1.303 C7 0.018 0.018 0.017 C11 0.071 0.069 0.048

Iso-Olefins C5 1.883 2.071 2.535 C6 1.154 1.212 1.295 C7 0.572 0.589 0.550

Naphtheno-Olefins C5 0.216 0.203 0.299 C6 0.508 0.472 0.584

Di-Olefins C5 0.025 0.027 0.035 C7 0.015 0.015 0.017

Oxygenates C3 0.081 0.073 0.127 C4 0.051 0.046 0.065

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 32.41 29.23 5% 80.02 79.81 10% 81.54 81.11 15% 96.23 93.70 20% 120.18 100.22 25% 140.09 137.63 30% 153.23 144.34 35% 155.20 154.35 40% 161.11 155.40 45% 177.26 172.56 50% 209.20 190.14 55% 209.71 209.29 60% 210.23 209.78 65% 228.48 210.28 70% 230.98 228.77 75% 257.41 231.05 80% 282.29 277.93 85% 332.39 321.66 90% 352.22 348.98 95% 365.79 363.20 FBP 404.60 404.08

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Thu Aug 26 16:41:24 2010**  **Page 1**

24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.553 74-98-6 P3 Propane 0.001 0.001 0.002 0.235 2 8.810 75-28-5 I4 i-Butane 0.035 0.045 0.056 9.068 3 9.623 115-11-7 K4 Isobutene 0.026 0.031 0.043 7.006 4 9.664 106-98-9 K4 Butene-1 0.028 0.034 0.047 7.552 5 10.024 106-97-8 P4 n-Butane 0.379 0.473 0.616 99.231 6 10.510 624-64-6 K4 t-Butene-2 0.106 0.127 0.179 28.830 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.040 0.048 0.052 10.455 8 11.252 590-18-1 K4 c-Butene-2 0.119 0.139 0.201 32.379 9 13.455 563-45-1 C5 3-Methylbutene-1 0.081 0.094 0.110 22.084 10 15.090 78-78-4 I5 i-Pentane 10.707 12.485 14.010 2821.802

11 16.729 109-67-1 K5 Pentene-1 0.377 0.426 0.508 102.255 12 17.582 563-46-2 C5 2-Methylbutene-1 0.589 0.654 0.792 159.588 13 18.121 109-66-0 P5 n-Pentane 2.987 3.446 3.908 787.160 14 18.628 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.801 15 19.239 646-04-8 K5 t-Pentene-2 0.971 1.082 1.307 263.114 16 19.883 ? Unidentified 0.007 0.008 0.009 2.310 17 20.272 627-20-3 K5 c-Pentene-2 0.531 0.585 0.715 143.898 18 20.947 513-35-9 C5 2-Methylbutene-2 1.213 1.323 1.633 328.791 19 21.277 2004-70-8 E5 1t,3-Pentadiene 0.015 0.016 0.021 4.277 20 22.539 1574-41-0 B5 1,3-Cyclopentadiene 0.006 0.007 0.009 1.746

21 23.096 75-83-2 I6 2,2-Dimethylbutane 0.612 0.681 0.671 161.972 22 25.742 142-29-0 B5 Cyclopentene 0.210 0.196 0.290 58.464 23 26.912 71-23-8 X3 n-Propanol 0.081 0.073 0.127 15.363 24 26.992 ? Unidentified 0.071 0.077 0.080 23.617 25 27.612 287-92-3 M5 Cyclopentane 1.519 1.472 2.044 411.671 26 28.339 79-29-8 I6 2,3-Dimethylbutane 0.857 0.936 0.938 226.672 27 28.738 ? Unidentified 0.065 0.064 0.070 21.715 28 29.205 691-38-3 C6 4-Methyl-c-pentene-2 0.053 0.057 0.059 14.376 29 29.427 107-83-5 I6 2-Methylpentane 3.627 4.012 3.973 959.623 30 29.847 674-76-0 C6 4-Methyl-t-pentene-2 0.152 0.163 0.171 41.215

31 32.083 96-14-0 I6 3-Methylpentane 3.205 3.486 3.511 847.965 32 33.234 763-29-1 C6 2-Methylpentene-1 0.259 0.273 0.290 70.189 33 33.459 592-41-6 K6 Hexene-1 0.176 0.187 0.197 47.682 34 35.847 110-54-3 P6 n-Hexane 6.286 6.888 6.887 1663.319 35 36.445 13269-52-8 K6 t-Hexene-3 0.295 0.313 0.331 80.091 36 36.921 4050-45-7 K6 t-Hexene-2 0.452 0.479 0.508 122.651 37 37.045 1120-62-3 B6 3-Methylcyclopentene 0.107 0.101 0.123 28.971 38 37.412 625-27-4 C6 2-Methylpentene-2 0.392 0.410 0.440 106.242 39 37.828 922-62-3 C6 3-Methyl-c-pentene-2 0.298 0.309 0.335 80.887 40 38.749 7688-21-3 K6 c-Hexene-2 0.238 0.248 0.267 64.468

41 40.098 3404-73-7 C7 3,3-Dimethylpentene-1 0.353 0.364 0.340 95.773 42 40.687 96-37-7 M6 Methylcyclopentane 2.831 2.732 3.175 767.258 43 42.240 108-08-7 I7 2,4-Dimethylpentane 0.582 0.625 0.548 154.532

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.538 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.013 0.012 3.408 45 42.784 464-06-2 I7 2,2,3-Trimethylbutane 0.064 0.067 0.060 17.052 46 45.435 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.017 4.082 47 45.641 71-42-3 Q6 Benzene 0.652 0.536 0.788 190.432 48 45.840 693-89-0 B6 1-Methylcyclopentene 0.362 0.336 0.417 100.617 49 46.649 3404-61-3 C7 3-Methylhexene-1 0.013 0.014 0.013 3.607 50 47.245 3524-73-0 C7 5-Methylhexene-1 0.082 0.085 0.078 22.121 51 47.577 110-82-7 M6 Cyclohexane 2.978 2.764 3.341 807.279 52 48.063 71-36-3 X4 n-Butanol 0.051 0.046 0.065 10.479 53 49.278 15840-60-5 C7 2-Methyl-c-hexene-3 0.035 0.036 0.033 9.363

54 50.273 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.041 0.042 0.039 11.053 55 50.679 591-76-4 I7 2-Methylhexane 1.937 2.062 1.825 514.592 56 51.161 110-83-8 B6 Cyclohexene 0.039 0.035 0.045 10.544 57 52.502 589-34-4 I7 3-Methylhexane 0.724 0.762 0.682 192.398 58 53.360 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.150 0.145 0.144 40.687 59 53.947 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.118 0.115 0.114 32.108 60 54.572 822-50-4 M7 1t,2-Dimethylcyclopentane 0.177 0.170 0.170 47.914 61 55.260 540-84-1 I8 2,2,4-Trimethylpentane 13.971 14.589 11.546 3718.827 62 57.340 14686-14-7 K7 t-Heptene-3 0.018 0.018 0.017 4.826 63 57.685 6094-02-6 C7 2-Methylhexene-1 0.028 0.029 0.027 7.647

64 58.062 142-82-5 P7 n-Heptane 0.502 0.530 0.473 133.309 65 58.555 2738-19-4 C7 2-Methyl-2-hexene 0.007 0.007 0.007 1.965 66 59.882 ? Unidentified 0.278 0.280 0.267 92.350 67 61.523 108-87-2 M7 Methylcyclohexane 0.795 0.746 0.764 215.396 68 62.463 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.016 0.016 0.014 4.465 69 62.852 590-73-8 I8 2,2-Dimethylhexane 0.016 0.016 0.013 4.183 70 64.072 ? Unidentified 0.075 0.073 0.064 24.985 71 64.305 1640-89-7 M7 Ethylcyclopentane 0.028 0.026 0.027 7.559 72 64.953 564-02-3 I8 2,2,3-Trimethylpentane 0.277 0.279 0.229 73.640 73 65.180 592-13-2 I8 2,5-Dimethylhexane 0.748 0.780 0.619 199.218

74 65.518 589-43-5 I8 2,4-Dimethylhexane 0.620 0.640 0.513 165.139 75 66.352 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.015 0.014 0.013 4.144 76 66.745 563-16-6 I8 3,3-Dimethylhexane 0.011 0.011 0.009 2.828 77 67.864 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.012 0.011 0.010 3.129 78 68.484 565-75-3 I8 2,3,4-Trimethylpentane 1.267 1.273 1.047 337.123 79 69.030 108-88-3 Q7 Toluene 5.884 4.903 6.029 1699.030 80 69.156 560-21-4 I8 2,3,3-Trimethylpentane 0.944 0.939 0.780 251.324 81 70.796 584-94-1 I8 2,3-Dimethylhexane 0.277 0.281 0.229 73.630 82 72.048 592-27-8 I8 2-Methylheptane 0.092 0.095 0.076 24.474 83 72.309 589-53-7 I8 4-Methylheptane 0.056 0.057 0.046 14.917

84 72.451 ? Unidentified 0.018 0.018 0.015 6.056 85 73.227 M8 1,3-dimethyl-t-cyclohexane 0.068 0.064 0.057 18.470 86 73.364 589-81-1 I8 3-Methylheptane 0.086 0.088 0.071 22.762

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 73.563 619-99-8 I8 3-Ethylhexane 0.046 0.047 0.038 12.239 88 74.463 ? Unidentified 0.011 0.010 0.009 3.534 89 75.251 3522-94-9 I9 2,2,5-Trimethylhexane 0.294 0.300 0.216 78.349 90 76.533 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.027 0.025 0.022 7.184 91 77.871 111-65-9 P8 n-Octane 0.144 0.148 0.119 38.212 92 78.825 ? Unidentified 0.007 0.007 0.006 2.319 93 80.355 1069-53-0 I9 2,3,5-Trimethylhexane 0.043 0.043 0.032 11.415 94 81.522 1071-26-7 I9 2,4-Dimethylheptane 0.012 0.013 0.009 3.281 95 82.177 1678-91-7 M8 Ethylcyclohexane 0.035 0.032 0.029 9.472 96 82.478 1072-05-5 I9 2,6-Dimethylheptane 0.018 0.018 0.013 4.765

97 83.408 I9 2,5-Dimethylheptane 0.028 0.029 0.021 7.530 98 84.734 100-41-4 Q8 Ethylbenzene 1.104 0.920 0.982 316.388 99 85.151 ? Unidentified 0.005 0.005 0.004 1.742 100 85.959 108-38-3 Q8 m-Xylene 2.669 2.231 2.373 764.768 101 86.105 106-42-3 Q8 p-Xylene 1.242 1.042 1.105 355.958 102 87.276 2216-34-4 I9 4-Methyloctane 0.011 0.011 0.008 2.940 103 87.407 3221-61-2 I9 2-Methyloctane 0.014 0.015 0.011 3.853 104 88.272 2216-33-3 I9 3-Methyloctane 0.015 0.015 0.011 4.114 105 88.746 ? Unidentified 0.009 0.009 0.006 2.830 106 88.930 95-47-6 Q8 o-Xylene 0.869 0.714 0.773 249.125

107 89.324 I10 C10 - IsoParaffin - 1 0.035 0.035 0.024 9.468 108 89.913 M9 trans-1,3-Diethylcyclopentane 0.005 0.004 0.004 1.560 109 90.168 14720-74-2 I10 2,2,4-trimethylheptane 0.031 0.030 0.020 8.169 110 91.737 111-84-2 P9 n-Nonane 0.062 0.063 0.046 16.584 111 93.096 98-82-8 Q9 i-Propylbenzene 0.032 0.026 0.025 8.984 112 93.843 ? Unidentified 0.043 0.043 0.029 14.413 113 94.066 15869-87-1 I10 2,2-Dimethyloctane 0.016 0.016 0.011 4.374 114 94.527 ? Unidentified 0.004 0.003 0.411 1.444 115 94.527 ? Unidentified 0.004 0.004 0.003 1.444 116 94.862 15869-89-3 I10 2,5-Dimethyloctane 0.019 0.019 0.013 5.116

117 95.327 2040-95-1 I10 2,7-Dimethyloctane 0.015 0.015 0.010 3.998 118 95.508 2051-30-1 I10 2,4-Dimethyloctane 0.068 0.068 0.045 18.171 119 95.895 I10 2,6-Dimethyloctane 0.020 0.020 0.013 5.383 120 96.555 103-65-1 Q9 n-Propylbenzene 0.249 0.209 0.196 70.985 121 97.401 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.939 0.785 0.738 267.484 122 97.635 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.446 0.374 0.350 126.991 123 98.261 108-67-8 Q9 1,3,5-Trimethylbenzene 0.608 0.507 0.477 173.016 124 98.911 17301-94-8 I10 4-Methylnonane 0.010 0.010 0.007 2.667 125 99.122 ? Unidentified 0.998 0.993 0.662 331.444 126 99.347 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.366 0.300 0.288 104.234

127 99.704 ? Unidentified 0.003 0.003 0.002 1.104 128 99.889 5911-04-6 I10 3-Methylnonane 0.014 0.013 0.009 3.649 129 100.354 ? Unidentified 0.079 0.057 0.048 26.357

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 100.486 ? Unidentified 0.219 0.213 0.133 72.879 131 100.703 I11 C11-Isoparaffin-2 0.117 0.113 0.070 31.207 132 100.980 95-63-6 Q9 1,2,4-Trimethylbenzene 1.887 1.557 1.482 537.379 133 101.167 ? Unidentified 0.148 0.152 0.099 49.063 134 101.289 ? Unidentified 0.085 0.084 0.057 28.354 135 101.553 1678-98-4 M10 i-Butylcyclohexane 0.020 0.018 0.014 5.475 136 102.195 ? Unidentified 0.008 0.008 0.006 2.786 137 102.339 17302-01-1 I10 3-Ethyl-3-methylheptane 0.220 0.213 0.133 58.813 138 102.548 ? Unidentified 0.059 0.057 0.036 19.569 139 102.686 538-93-2 Q10 i-Butylbenzene 0.195 0.165 0.137 55.333

140 102.899 124-18-5 P10 n-Decane 0.042 0.042 0.028 11.236 141 103.201 ? Unidentified 0.058 0.057 0.039 19.391 142 103.689 ? Unidentified 0.008 0.007 0.007 2.795 143 103.854 526-73-8 Q9 1,2,3-Trimethylbenzene 0.357 0.288 0.280 101.644 144 104.204 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.025 0.021 0.018 7.074 145 104.412 I11 C11 Isoparaffin-4 0.030 0.029 0.018 7.968 146 104.619 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.194 0.164 0.137 55.009 147 105.048 J9 Indan 0.167 0.125 0.134 48.420 148 105.648 J10 Indene 1.086 0.814 0.868 314.254 149 106.205 ? Unidentified 0.008 0.007 0.005 2.588

150 106.362 I11 C11-Isoparaffin-7 0.445 0.432 0.269 118.933 151 106.551 141-93-5 Q10 1,3-Diethylbenzene 0.057 0.048 0.040 16.096 152 106.843 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.291 1.084 0.908 365.741 153 107.109 105-05-5 Q10 1,4-Diethylbenzene 0.425 0.356 0.299 120.424 154 107.386 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.182 0.149 0.128 51.507 155 107.623 135-01-3 Q10 1,2-Diethylbenzene 0.106 0.087 0.075 30.062 156 108.086 ? Unidentified 0.111 0.107 0.067 36.719 157 108.237 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.073 0.060 0.051 20.594 158 108.361 ? Unidentified 0.123 0.099 0.096 40.729 159 108.440 ? Unidentified 0.117 0.113 0.070 38.722

160 108.569 I11 C11- Isoparaffin-11 0.860 0.836 0.520 230.181 161 108.749 ? Unidentified 0.291 0.283 0.176 96.728 162 109.173 ? Unidentified 1.032 0.850 0.726 342.565 163 109.398 J10 2-Methylindan 0.158 0.118 0.113 45.732 164 109.745 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.489 0.404 0.344 138.531 165 109.872 ? Unidentified 0.039 0.032 0.027 12.898 166 109.968 ? Unidentified 0.030 0.022 0.021 9.926 167 110.290 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.846 0.686 0.595 239.497 168 110.713 ? Unidentified 0.028 0.025 0.017 9.282 169 110.908 693-61-8 K11 2-Undecene, (E)- 0.071 0.069 0.048 19.099

170 111.042 ? Unidentified 0.161 0.157 0.108 53.412 171 111.313 ? Unidentified 0.138 0.112 0.088 45.861 172 111.414 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.114 0.092 0.080 32.246

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 111.714 1120-21-4 P11 n-Undecane 0.088 0.086 0.053 23.597 174 111.864 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.110 0.089 0.070 31.016 175 111.975 ? Unidentified 0.064 0.052 0.041 21.126 176 112.352 Q10 1,2,4,5-Tetramethylbenzene 0.364 0.296 0.256 102.987 177 112.618 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.498 0.404 0.350 141.055 178 112.825 ? Unidentified 0.012 0.010 0.008 4.127 179 112.958 ? Unidentified 0.017 0.014 0.012 5.787 180 113.132 I12 C12 - IsoParaffin - 1 0.027 0.027 0.015 7.355 181 113.481 ? Unidentified 0.039 0.038 0.021 12.854 182 113.614 ? Unidentified 0.012 0.012 0.007 4.006

183 113.761 Q11 C11 - Aromatic - 3 0.098 0.080 0.063 27.733 184 113.948 874-35-1 H10 5-Methylindan 0.153 0.124 0.109 43.398 185 114.072 Q12 1,2-Di-i-propylbenzene 0.066 0.053 0.038 18.466 186 114.287 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.092 0.074 0.058 25.870 187 114.449 Q11 C11 - Aromatic - 4 0.053 0.043 0.034 14.853 188 114.697 824-22-6 J10 4-Methylindan 0.203 0.165 0.145 57.573 189 114.849 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.058 0.047 0.037 16.408 190 114.944 824-63-5 H10 2-Methylindan 0.153 0.124 0.109 43.236 191 115.147 ? Unidentified 0.018 0.015 0.012 6.016 192 115.259 538-68-1 Q11 n-Pentylbenzene 0.023 0.018 0.014 6.387

193 115.488 Q11 tert-Pentylbenzene 0.091 0.074 0.058 25.596 194 115.800 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.038 0.031 0.024 10.842 195 115.910 Q11 C11 - Aromatic - 7 0.051 0.043 0.032 14.356 196 116.245 I12 C12 - IsoParaffin - 4 0.005 0.004 0.003 1.312 197 116.370 100-18-5 Q12 1,4-Di-i-propylbenzene 0.073 0.059 0.043 20.562 198 116.812 91-20-3 G10 Naphthalene 0.109 0.077 0.080 32.240 199 116.948 J11 4,7-Dimethyl Indane 0.008 0.006 0.005 2.403 200 117.242 J11 1,1-Dimethyl Indane 0.022 0.017 0.014 6.416 201 117.414 J12 Dimethyl Indane - 1 0.009 0.006 0.006 2.471 202 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.013 0.011 0.008 3.785

203 117.894 Q12 1,3-Di-n-propylbenzene 0.056 0.045 0.033 15.718 204 118.006 Q11 C11 - Aromatic - 11 0.031 0.027 0.020 8.794 205 118.559 Q11 C11 - Aromatic - 12 0.019 0.016 0.012 5.268 206 123.439 91-57-6 G11 2-Methylnaphthalene 0.013 0.009 0.009 3.794 207 124.306 90-12-0 G11 1-Methylnaphthalene 0.007 0.005 0.005 2.049 208 130.002 ? Unidentified 0.004 0.003 0.002 1.337

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.553 74-98-6 Propane 0.001 0.001 0.002 0.235

10.024 106-97-8 n-Butane 0.379 0.473 0.616 99.231 18.121 109-66-0 n-Pentane 2.987 3.446 3.908 787.160 35.847 110-54-3 n-Hexane 6.286 6.888 6.887 1663.319 58.062 142-82-5 n-Heptane 0.502 0.530 0.473 133.309 77.871 111-65-9 n-Octane 0.144 0.148 0.119 38.212 91.737 111-84-2 n-Nonane 0.062 0.063 0.046 16.584 102.899 124-18-5 n-Decane 0.042 0.042 0.028 11.236 111.714 1120-21-4 n-Undecane 0.088 0.086 0.053 23.597

I-Paraffins 8.810 75-28-5 i-Butane 0.035 0.045 0.056 9.068

10.637 463-82-1 2,2-Dimethylpropane 0.040 0.048 0.052 10.455 15.090 78-78-4 i-Pentane 10.707 12.485 14.010 2821.802 23.096 75-83-2 2,2-Dimethylbutane 0.612 0.681 0.671 161.972 28.339 79-29-8 2,3-Dimethylbutane 0.857 0.936 0.938 226.672 29.427 107-83-5 2-Methylpentane 3.627 4.012 3.973 959.623 32.083 96-14-0 3-Methylpentane 3.205 3.486 3.511 847.965 42.240 108-08-7 2,4-Dimethylpentane 0.582 0.625 0.548 154.532 42.784 464-06-2 2,2,3-Trimethylbutane 0.064 0.067 0.060 17.052 50.679 591-76-4 2-Methylhexane 1.937 2.062 1.825 514.592 52.502 589-34-4 3-Methylhexane 0.724 0.762 0.682 192.398 55.260 540-84-1 2,2,4-Trimethylpentane 13.971 14.589 11.546 3718.827 62.852 590-73-8 2,2-Dimethylhexane 0.016 0.016 0.013 4.183 64.953 564-02-3 2,2,3-Trimethylpentane 0.277 0.279 0.229 73.640 65.180 592-13-2 2,5-Dimethylhexane 0.748 0.780 0.619 199.218 65.518 589-43-5 2,4-Dimethylhexane 0.620 0.640 0.513 165.139 66.745 563-16-6 3,3-Dimethylhexane 0.011 0.011 0.009 2.828 68.484 565-75-3 2,3,4-Trimethylpentane 1.267 1.273 1.047 337.123 69.156 560-21-4 2,3,3-Trimethylpentane 0.944 0.939 0.780 251.324 70.796 584-94-1 2,3-Dimethylhexane 0.277 0.281 0.229 73.630 72.048 592-27-8 2-Methylheptane 0.092 0.095 0.076 24.474 72.309 589-53-7 4-Methylheptane 0.056 0.057 0.046 14.917 73.364 589-81-1 3-Methylheptane 0.086 0.088 0.071 22.762 73.563 619-99-8 3-Ethylhexane 0.046 0.047 0.038 12.239 75.251 3522-94-9 2,2,5-Trimethylhexane 0.294 0.300 0.216 78.349 80.355 1069-53-0 2,3,5-Trimethylhexane 0.043 0.043 0.032 11.415 81.522 1071-26-7 2,4-Dimethylheptane 0.012 0.013 0.009 3.281 82.478 1072-05-5 2,6-Dimethylheptane 0.018 0.018 0.013 4.765 83.408 2,5-Dimethylheptane 0.028 0.029 0.021 7.530 87.276 2216-34-4 4-Methyloctane 0.011 0.011 0.008 2.940 87.407 3221-61-2 2-Methyloctane 0.014 0.015 0.011 3.853 88.272 2216-33-3 3-Methyloctane 0.015 0.015 0.011 4.114 89.324 C10 - IsoParaffin - 1 0.035 0.035 0.024 9.468 90.168 14720-74-2 2,2,4-trimethylheptane 0.031 0.030 0.020 8.169 94.066 15869-87-1 2,2-Dimethyloctane 0.016 0.016 0.011 4.374 94.862 15869-89-3 2,5-Dimethyloctane 0.019 0.019 0.013 5.116 95.327 2040-95-1 2,7-Dimethyloctane 0.015 0.015 0.010 3.998

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 95.508 2051-30-1 2,4-Dimethyloctane 0.068 0.068 0.045 18.171

95.895 2,6-Dimethyloctane 0.020 0.020 0.013 5.383 98.911 17301-94-8 4-Methylnonane 0.010 0.010 0.007 2.667 99.889 5911-04-6 3-Methylnonane 0.014 0.013 0.009 3.649 100.703 C11-Isoparaffin-2 0.117 0.113 0.070 31.207 102.339 17302-01-1 3-Ethyl-3-methylheptane 0.220 0.213 0.133 58.813 104.412 C11 Isoparaffin-4 0.030 0.029 0.018 7.968 106.362 C11-Isoparaffin-7 0.445 0.432 0.269 118.933 108.569 C11- Isoparaffin-11 0.860 0.836 0.520 230.181 113.132 C12 - IsoParaffin - 1 0.027 0.027 0.015 7.355 116.245 C12 - IsoParaffin - 4 0.005 0.004 0.003 1.312

Aromatics Mono-Aromatics 45.641 71-42-3 Benzene 0.652 0.536 0.788 190.432

69.030 108-88-3 Toluene 5.884 4.903 6.029 1699.030 84.734 100-41-4 Ethylbenzene 1.104 0.920 0.982 316.388 85.959 108-38-3 m-Xylene 2.669 2.231 2.373 764.768 86.105 106-42-3 p-Xylene 1.242 1.042 1.105 355.958 88.930 95-47-6 o-Xylene 0.869 0.714 0.773 249.125 93.096 98-82-8 i-Propylbenzene 0.032 0.026 0.025 8.984 96.555 103-65-1 n-Propylbenzene 0.249 0.209 0.196 70.985 97.401 620-14-4 1-Methyl-3-ethylbenzene 0.939 0.785 0.738 267.484 97.635 622-96-8 1-Methyl-4-ethylbenzene 0.446 0.374 0.350 126.991 98.261 108-67-8 1,3,5-Trimethylbenzene 0.608 0.507 0.477 173.016 99.347 611-14-3 1-Methyl-2-ethylbenzene 0.366 0.300 0.288 104.234 100.980 95-63-6 1,2,4-Trimethylbenzene 1.887 1.557 1.482 537.379 102.686 538-93-2 i-Butylbenzene 0.195 0.165 0.137 55.333 103.854 526-73-8 1,2,3-Trimethylbenzene 0.357 0.288 0.280 101.644 104.204 535-77-3 1-Methyl-3-i-propylbenzene 0.025 0.021 0.018 7.074 104.619 99-87-6 1-Methyl-4-i-propylbenzene 0.194 0.164 0.137 55.009 106.551 141-93-5 1,3-Diethylbenzene 0.057 0.048 0.040 16.096 106.843 1074-43-7 1-Methyl-3-n-propylbenzene 1.291 1.084 0.908 365.741 107.109 105-05-5 1,4-Diethylbenzene 0.425 0.356 0.299 120.424 107.386 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.182 0.149 0.128 51.507 107.623 135-01-3 1,2-Diethylbenzene 0.106 0.087 0.075 30.062 108.237 1074-17-5 1-Methyl-2-n-propylbenzene 0.073 0.060 0.051 20.594 109.745 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.489 0.404 0.344 138.531 110.290 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.846 0.686 0.595 239.497 111.414 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.114 0.092 0.080 32.246 111.864 4218-48-8 1-Ethyl-4-i-propylbenzene 0.110 0.089 0.070 31.016 112.352 1,2,4,5-Tetramethylbenzene 0.364 0.296 0.256 102.987 112.618 527-53-7 1,2,3,5-Tetramethylbenzene 0.498 0.404 0.350 141.055 113.761 C11 - Aromatic - 3 0.098 0.080 0.063 27.733 114.072 1,2-Di-i-propylbenzene 0.066 0.053 0.038 18.466 114.287 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.092 0.074 0.058 25.870 114.449 C11 - Aromatic - 4 0.053 0.043 0.034 14.853 114.849 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.058 0.047 0.037 16.408

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 115.259 538-68-1 n-Pentylbenzene 0.023 0.018 0.014 6.387

115.488 tert-Pentylbenzene 0.091 0.074 0.058 25.596 115.800 577-55-9 1-Methyl-2-n-butylbenzene 0.038 0.031 0.024 10.842 115.910 C11 - Aromatic - 7 0.051 0.043 0.032 14.356 116.370 100-18-5 1,4-Di-i-propylbenzene 0.073 0.059 0.043 20.562 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.013 0.011 0.008 3.785 117.894 1,3-Di-n-propylbenzene 0.056 0.045 0.033 15.718 118.006 C11 - Aromatic - 11 0.031 0.027 0.020 8.794 118.559 C11 - Aromatic - 12 0.019 0.016 0.012 5.268

Naphthalenes 116.812 91-20-3 Naphthalene 0.109 0.077 0.080 32.240

123.439 91-57-6 2-Methylnaphthalene 0.013 0.009 0.009 3.794 124.306 90-12-0 1-Methylnaphthalene 0.007 0.005 0.005 2.049

Naphtheno/Olefino-Benzs

113.948 874-35-1 5-Methylindan 0.153 0.124 0.109 43.398 114.944 824-63-5 2-Methylindan 0.153 0.124 0.109 43.236

Indenes 105.048 Indan 0.167 0.125 0.134 48.420

105.648 Indene 1.086 0.814 0.868 314.254 109.398 2-Methylindan 0.158 0.118 0.113 45.732 114.697 824-22-6 4-Methylindan 0.203 0.165 0.145 57.573 116.948 4,7-Dimethyl Indane 0.008 0.006 0.005 2.403 117.242 1,1-Dimethyl Indane 0.022 0.017 0.014 6.416 117.414 Dimethyl Indane - 1 0.009 0.006 0.006 2.471

Naphthenes Mono-Naphthenes 27.612 287-92-3 Cyclopentane 1.519 1.472 2.044 411.671

40.687 96-37-7 Methylcyclopentane 2.831 2.732 3.175 767.258 47.577 110-82-7 Cyclohexane 2.978 2.764 3.341 807.279 53.360 1759-58-6 1t,3-Dimethylcyclopentane 0.150 0.145 0.144 40.687 53.947 2532-58-3 1c,3-Dimethylcyclopentane 0.118 0.115 0.114 32.108 54.572 822-50-4 1t,2-Dimethylcyclopentane 0.177 0.170 0.170 47.914 61.523 108-87-2 Methylcyclohexane 0.795 0.746 0.764 215.396 62.463 4516-69-2 1,1,3-Trimethylcyclopentane 0.016 0.016 0.014 4.465 64.305 1640-89-7 Ethylcyclopentane 0.028 0.026 0.027 7.559 66.352 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.015 0.014 0.013 4.144 67.864 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.012 0.011 0.010 3.129 73.227 1,3-dimethyl-t-cyclohexane 0.068 0.064 0.057 18.470 76.533 2207-03-6 1t,3-Dimethylcyclohexane 0.027 0.025 0.022 7.184 82.177 1678-91-7 Ethylcyclohexane 0.035 0.032 0.029 9.472 89.913 trans-1,3-Diethylcyclopentane 0.005 0.004 0.004 1.560 101.553 1678-98-4 i-Butylcyclohexane 0.020 0.018 0.014 5.475

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.623 115-11-7 Isobutene 0.026 0.031 0.043 7.006

9.664 106-98-9 Butene-1 0.028 0.034 0.047 7.552

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 10.510 624-64-6 t-Butene-2 0.106 0.127 0.179 28.830

11.252 590-18-1 c-Butene-2 0.119 0.139 0.201 32.379 16.729 109-67-1 Pentene-1 0.377 0.426 0.508 102.255 19.239 646-04-8 t-Pentene-2 0.971 1.082 1.307 263.114 20.272 627-20-3 c-Pentene-2 0.531 0.585 0.715 143.898 33.459 592-41-6 Hexene-1 0.176 0.187 0.197 47.682 36.445 13269-52-8 t-Hexene-3 0.295 0.313 0.331 80.091 36.921 4050-45-7 t-Hexene-2 0.452 0.479 0.508 122.651 38.749 7688-21-3 c-Hexene-2 0.238 0.248 0.267 64.468 57.340 14686-14-7 t-Heptene-3 0.018 0.018 0.017 4.826 110.908 693-61-8 2-Undecene, (E)- 0.071 0.069 0.048 19.099

Iso-Olefins 13.455 563-45-1 3-Methylbutene-1 0.081 0.094 0.110 22.084

17.582 563-46-2 2-Methylbutene-1 0.589 0.654 0.792 159.588 20.947 513-35-9 2-Methylbutene-2 1.213 1.323 1.633 328.791 29.205 691-38-3 4-Methyl-c-pentene-2 0.053 0.057 0.059 14.376 29.847 674-76-0 4-Methyl-t-pentene-2 0.152 0.163 0.171 41.215 33.234 763-29-1 2-Methylpentene-1 0.259 0.273 0.290 70.189 37.412 625-27-4 2-Methylpentene-2 0.392 0.410 0.440 106.242 37.828 922-62-3 3-Methyl-c-pentene-2 0.298 0.309 0.335 80.887 40.098 3404-73-7 3,3-Dimethylpentene-1 0.353 0.364 0.340 95.773 42.538 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.013 0.012 3.408 46.649 3404-61-3 3-Methylhexene-1 0.013 0.014 0.013 3.607 47.245 3524-73-0 5-Methylhexene-1 0.082 0.085 0.078 22.121 49.278 15840-60-5 2-Methyl-c-hexene-3 0.035 0.036 0.033 9.363 50.273 3404-55-5 4-Methyl-t/c-hexene-2 0.041 0.042 0.039 11.053 57.685 6094-02-6 2-Methylhexene-1 0.028 0.029 0.027 7.647 58.555 2738-19-4 2-Methyl-2-hexene 0.007 0.007 0.007 1.965

Naphtheno-Olefins 22.539 1574-41-0 1,3-Cyclopentadiene 0.006 0.007 0.009 1.746

25.742 142-29-0 Cyclopentene 0.210 0.196 0.290 58.464 37.045 1120-62-3 3-Methylcyclopentene 0.107 0.101 0.123 28.971 45.840 693-89-0 1-Methylcyclopentene 0.362 0.336 0.417 100.617 51.161 110-83-8 Cyclohexene 0.039 0.035 0.045 10.544

Di-Olefins 18.628 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.014 2.801

21.277 2004-70-8 1t,3-Pentadiene 0.015 0.016 0.021 4.277 45.435 1528-30-9 C6-Diolefin-1 0.015 0.015 0.017 4.082

Oxygenates 26.912 71-23-8 n-Propanol 0.081 0.073 0.127 15.363

48.063 71-36-3 n-Butanol 0.051 0.046 0.065 10.479

Unidentified 19.883 Unidentified 0.007 0.008 0.009 2.310

26.992 Unidentified 0.071 0.077 0.080 23.617 28.738 Unidentified 0.065 0.064 0.070 21.715 59.882 Unidentified 0.278 0.280 0.267 92.350 64.072 Unidentified 0.075 0.073 0.064 24.985

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 72.451 Unidentified 0.018 0.018 0.015 6.056

74.463 Unidentified 0.011 0.010 0.009 3.534 78.825 Unidentified 0.007 0.007 0.006 2.319 85.151 Unidentified 0.005 0.005 0.004 1.742 88.746 Unidentified 0.009 0.009 0.006 2.830 93.843 Unidentified 0.043 0.043 0.029 14.413 94.527 Unidentified 0.004 0.003 0.411 1.444 94.527 Unidentified 0.004 0.004 0.003 1.444 99.122 Unidentified 0.998 0.993 0.662 331.444 99.704 Unidentified 0.003 0.003 0.002 1.104 100.354 Unidentified 0.079 0.057 0.048 26.357 100.486 Unidentified 0.219 0.213 0.133 72.879 101.167 Unidentified 0.148 0.152 0.099 49.063 101.289 Unidentified 0.085 0.084 0.057 28.354 102.195 Unidentified 0.008 0.008 0.006 2.786 102.548 Unidentified 0.059 0.057 0.036 19.569 103.201 Unidentified 0.058 0.057 0.039 19.391 103.689 Unidentified 0.008 0.007 0.007 2.795 106.205 Unidentified 0.008 0.007 0.005 2.588 108.086 Unidentified 0.111 0.107 0.067 36.719 108.361 Unidentified 0.123 0.099 0.096 40.729 108.440 Unidentified 0.117 0.113 0.070 38.722 108.749 Unidentified 0.291 0.283 0.176 96.728 109.173 Unidentified 1.032 0.850 0.726 342.565 109.872 Unidentified 0.039 0.032 0.027 12.898 109.968 Unidentified 0.030 0.022 0.021 9.926 110.713 Unidentified 0.028 0.025 0.017 9.282 111.042 Unidentified 0.161 0.157 0.108 53.412 111.313 Unidentified 0.138 0.112 0.088 45.861 111.975 Unidentified 0.064 0.052 0.041 21.126 112.825 Unidentified 0.012 0.010 0.008 4.127 112.958 Unidentified 0.017 0.014 0.012 5.787 113.481 Unidentified 0.039 0.038 0.021 12.854 113.614 Unidentified 0.012 0.012 0.007 4.006 115.147 Unidentified 0.018 0.015 0.012 6.016 130.002 Unidentified 0.004 0.003 0.002 1.337

Plus

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Unidentified

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Unidentified Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified
m-Xylene

p-Xylene

4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene
1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane

Unidentified 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane Unidentified i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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24-Aug-10, 17:46:58 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF Sample: ODDB-91321 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91321 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000003.D\SIG2000003_FID2_B.CDF145.0140.0135.0130.0125.0

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 15.166 17.813 18.361

I-Paraffins 26.340 30.029 28.307

Aromatics 43.085 36.374 36.975 Mono-Aromatics 42.174 35.661 36.340 Naphthalenes 0.096 0.069 0.064 Naphtheno/Olefino-Benzs 0.224 0.185 0.149 Indenes 0.591 0.460 0.422

Naphthenes 6.544 6.325 6.605 Mono-Naphthenes 6.544 6.325 6.605 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.575 8.247 8.786 n-Olefins 3.303 3.690 3.961 Iso-Olefins 3.530 3.851 3.982 Naphtheno-Olefins 0.702 0.665 0.796 Di-Olefins 0.039 0.041 0.047

Oxygenates 0.125 0.115 0.169

Unidentified 1.165 1.097 0.797

Plus 0.000 0.000 0.000

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C3 0.079 0.073 0.116 C4 5.216 6.583 7.854 C5 21.676 25.287 26.455 C6 21.269 22.686 21.854 C7 24.293 21.482 22.749 C8 16.388 14.374 13.367 C9 5.486 4.668 3.982 C10 3.365 2.800 2.218 C11 0.902 0.815 0.521 C12 0.164 0.136 0.088

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.002 0.002 0.003 C4 4.842 6.142 7.292 C5 3.777 4.428 4.582 C6 5.710 6.357 5.799 C7 0.558 0.599 0.487 C8 0.174 0.182 0.133 C9 0.049 0.050 0.033 C10 0.026 0.026 0.016 C11 0.027 0.027 0.015

I-Paraffins C4 0.043 0.057 0.065 C5 13.536 16.041 16.419 C6 7.755 8.650 7.876 C7 2.129 2.299 1.860 C8 2.138 2.241 1.638 C9 0.254 0.262 0.174 C10 0.100 0.100 0.059 C11 0.376 0.371 0.210 C12 0.008 0.008 0.004

Mono-Aromatics C6 0.637 0.532 0.713 C7 19.510 16.520 18.532 C8 13.890 11.774 11.450 C9 5.058 4.260 3.683 C10 2.462 2.062 1.605 C11 0.462 0.385 0.273 C12 0.156 0.128 0.084

Naphthalenes C10 0.079 0.056 0.054 C11 0.017 0.013 0.011

Naphtheno/Olefino-Benzs C10 0.224 0.185 0.149

Indenes C9 0.117 0.089 0.087 C10 0.473 0.370 0.335

Mono-Naphthenes C5 0.367 0.362 0.458 C6 4.460 4.313 4.638 C7 1.524 1.467 1.359 C8 0.186 0.177 0.145 C9 0.007 0.006 0.005

n-Olefins C4 0.282 0.340 0.440

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.877 2.125 2.343 C6 1.107 1.188 1.151 C7 0.017 0.018 0.015 C11 0.020 0.019 0.012

Iso-Olefins C5 1.880 2.101 2.346 C6 1.111 1.185 1.155 C7 0.539 0.565 0.481

Naphtheno-Olefins C5 0.213 0.204 0.275 C6 0.489 0.462 0.521

Di-Olefins C5 0.025 0.027 0.032 C7 0.014 0.014 0.015

Oxygenates C3 0.077 0.071 0.113 C4 0.047 0.044 0.056

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.53 21.30 5% 32.49 28.95 10% 79.90 79.44 15% 81.10 80.46 20% 93.48 81.47 25% 99.16 94.27 30% 138.85 99.90 35% 145.72 138.61 40% 154.99 145.16 45% 160.31 154.68 50% 190.98 158.41 55% 230.73 177.10 60% 230.82 210.94 65% 230.91 230.80 70% 231.00 230.91 75% 245.77 231.02 80% 279.56 276.00 85% 281.87 281.34 90% 320.98 291.67 95% 350.02 336.40 FBP 403.28 398.03

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.553 74-98-6 P3 Propane 0.002 0.002 0.003 0.390 2 8.809 75-28-5 I4 i-Butane 0.043 0.057 0.065 10.908 3 9.622 115-11-7 K4 Isobutene 0.026 0.032 0.040 6.684 4 9.664 106-98-9 K4 Butene-1 0.028 0.034 0.043 7.220 5 10.023 106-97-8 P4 n-Butane 4.842 6.142 7.292 1214.581 6 10.509 624-64-6 K4 t-Butene-2 0.107 0.130 0.167 27.870 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.060 0.074 0.073 15.132 8 11.251 590-18-1 K4 c-Butene-2 0.121 0.144 0.189 31.554 9 13.453 563-45-1 C5 3-Methylbutene-1 0.083 0.097 0.103 21.504 10 15.091 78-78-4 I5 i-Pentane 13.476 15.966 16.347 3403.446

11 16.727 109-67-1 K5 Pentene-1 0.378 0.433 0.471 98.111 12 17.581 563-46-2 C5 2-Methylbutene-1 0.590 0.666 0.737 153.394 13 18.121 109-66-0 P5 n-Pentane 3.777 4.428 4.582 953.910 14 18.628 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 2.693 15 19.234 646-04-8 K5 t-Pentene-2 0.970 1.098 1.210 251.892 16 19.878 ? Unidentified 0.007 0.008 0.009 2.217 17 20.265 627-20-3 K5 c-Pentene-2 0.530 0.593 0.661 137.684 18 20.949 513-35-9 C5 2-Methylbutene-2 1.207 1.338 1.506 313.560 19 21.271 2004-70-8 E5 1t,3-Pentadiene 0.015 0.016 0.019 3.977 20 22.541 1574-41-0 B5 1,3-Cyclopentadiene 0.006 0.007 0.008 1.675

21 23.086 75-83-2 I6 2,2-Dimethylbutane 0.251 0.283 0.254 63.532 22 25.750 142-29-0 B5 Cyclopentene 0.207 0.197 0.266 55.409 23 26.904 71-23-8 X3 n-Propanol 0.077 0.071 0.113 14.067 24 26.992 ? Unidentified 0.070 0.077 0.073 22.337 25 27.607 287-92-3 M5 Cyclopentane 0.367 0.362 0.458 95.385 26 28.341 79-29-8 I6 2,3-Dimethylbutane 0.804 0.892 0.817 203.889 27 28.735 ? Unidentified 0.063 0.062 0.062 19.922 28 29.196 691-38-3 C6 4-Methyl-c-pentene-2 0.052 0.056 0.054 13.440 29 29.430 107-83-5 I6 2-Methylpentane 3.651 4.104 3.708 925.860 30 29.838 674-76-0 C6 4-Methyl-t-pentene-2 0.147 0.160 0.153 38.256

31 32.081 96-14-0 I6 3-Methylpentane 3.049 3.370 3.097 773.214 32 33.235 763-29-1 C6 2-Methylpentene-1 0.250 0.268 0.260 64.935 33 33.459 592-41-6 K6 Hexene-1 0.169 0.183 0.176 43.925 34 35.835 110-54-3 P6 n-Hexane 5.710 6.357 5.799 1447.834 35 36.437 13269-52-8 K6 t-Hexene-3 0.283 0.305 0.294 73.510 36 36.916 4050-45-7 K6 t-Hexene-2 0.428 0.460 0.445 111.062 37 37.052 1120-62-3 B6 3-Methylcyclopentene 0.109 0.105 0.116 28.297 38 37.411 625-27-4 C6 2-Methylpentene-2 0.376 0.399 0.391 97.588 39 37.821 922-62-3 C6 3-Methyl-c-pentene-2 0.286 0.301 0.297 74.313 40 38.749 7688-21-3 K6 c-Hexene-2 0.227 0.241 0.236 59.038

41 40.087 3404-73-7 C7 3,3-Dimethylpentene-1 0.338 0.353 0.301 87.687 42 40.684 96-37-7 M6 Methylcyclopentane 2.852 2.796 2.965 740.776 43 42.234 108-08-7 I7 2,4-Dimethylpentane 0.456 0.497 0.398 115.963

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.536 594-56-9 C7 2,3,3-Trimethylbutene-1 0.010 0.010 0.009 2.522 45 42.782 464-06-2 I7 2,2,3-Trimethylbutane 0.053 0.057 0.047 13.584 46 45.426 1528-30-9 E7 C6-Diolefin-1 0.014 0.014 0.015 3.691 47 45.637 71-42-3 Q6 Benzene 0.637 0.532 0.713 178.108 48 45.836 693-89-0 B6 1-Methylcyclopentene 0.344 0.324 0.366 91.415 49 46.642 3404-61-3 C7 3-Methylhexene-1 0.012 0.013 0.011 3.208 50 47.234 3524-73-0 C7 5-Methylhexene-1 0.076 0.081 0.068 19.858 51 47.560 110-82-7 M6 Cyclohexane 1.609 1.517 1.673 417.909 52 48.060 71-36-3 X4 n-Butanol 0.047 0.044 0.056 9.334 53 49.272 15840-60-5 C7 2-Methyl-c-hexene-3 0.033 0.034 0.029 8.463

54 50.266 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.038 0.040 0.034 9.955 55 50.663 591-76-4 I7 2-Methylhexane 1.013 1.096 0.885 257.982 56 50.840 ? Unidentified 0.065 0.069 0.059 20.803 57 51.155 110-83-8 B6 Cyclohexene 0.036 0.033 0.039 9.472 58 52.493 589-34-4 I7 3-Methylhexane 0.607 0.649 0.530 154.584 59 53.354 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.163 0.160 0.145 42.386 60 53.940 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.132 0.130 0.118 34.376 61 54.562 822-50-4 M7 1t,2-Dimethylcyclopentane 0.187 0.182 0.166 48.511 62 55.147 540-84-1 I8 2,2,4-Trimethylpentane 1.008 1.069 0.772 257.064 63 57.332 14686-14-7 K7 t-Heptene-3 0.017 0.018 0.015 4.363

64 57.681 6094-02-6 C7 2-Methylhexene-1 0.027 0.028 0.024 6.925 65 58.057 142-82-5 P7 n-Heptane 0.558 0.599 0.487 142.091 66 58.548 2738-19-4 C7 2-Methyl-2-hexene 0.006 0.006 0.005 1.512 67 61.520 108-87-2 M7 Methylcyclohexane 1.007 0.961 0.898 261.594 68 62.459 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.021 0.021 0.016 5.446 69 62.848 590-73-8 I8 2,2-Dimethylhexane 0.017 0.018 0.013 4.369 70 64.301 1640-89-7 M7 Ethylcyclopentane 0.035 0.034 0.031 9.101 71 64.946 564-02-3 I8 2,2,3-Trimethylpentane 0.047 0.048 0.036 11.955 72 65.169 592-13-2 I8 2,5-Dimethylhexane 0.136 0.144 0.104 34.691 73 65.507 589-43-5 I8 2,4-Dimethylhexane 0.143 0.150 0.110 36.524

74 66.347 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.019 0.019 0.015 4.998 75 66.743 563-16-6 I8 3,3-Dimethylhexane 0.012 0.013 0.009 3.092 76 67.864 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.015 0.014 0.012 3.904 77 68.483 565-75-3 I8 2,3,4-Trimethylpentane 0.352 0.359 0.270 89.806 78 69.119 108-88-3 Q7 Toluene 19.510 16.520 18.532 5398.904 79 70.795 584-94-1 I8 2,3-Dimethylhexane 0.110 0.113 0.084 28.064 80 72.048 592-27-8 I8 2-Methylheptane 0.103 0.109 0.079 26.387 81 72.303 589-53-7 I8 4-Methylheptane 0.060 0.062 0.046 15.241 82 73.225 M8 1,3-dimethyl-t-cyclohexane 0.087 0.083 0.068 22.674 83 73.361 589-81-1 I8 3-Methylheptane 0.094 0.098 0.072 24.015

84 73.563 619-99-8 I8 3-Ethylhexane 0.056 0.057 0.043 14.257 85 74.459 ? Unidentified 0.013 0.012 0.010 4.134 86 75.247 3522-94-9 I9 2,2,5-Trimethylhexane 0.143 0.148 0.097 36.462

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 76.530 ? Unidentified 0.028 0.026 0.022 8.891 88 77.869 111-65-9 P8 n-Octane 0.174 0.182 0.133 44.393 89 80.353 1069-53-0 I9 2,3,5-Trimethylhexane 0.021 0.021 0.014 5.275 90 81.522 1071-26-7 I9 2,4-Dimethylheptane 0.009 0.010 0.006 2.354 91 82.174 1678-91-7 M8 Ethylcyclohexane 0.043 0.040 0.034 11.217 92 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.015 0.016 0.010 3.844 93 82.976 ? Unidentified 0.006 0.006 0.005 1.855 94 83.409 I9 2,5-Dimethylheptane 0.020 0.021 0.014 5.170 95 84.745 100-41-4 Q8 Ethylbenzene 2.658 2.251 2.191 729.994 96 85.989 108-38-3 Q8 m-Xylene 6.429 5.461 5.300 1765.617

97 86.130 106-42-3 Q8 p-Xylene 3.031 2.584 2.499 832.419 98 87.277 2216-34-4 I9 4-Methyloctane 0.013 0.013 0.009 3.221 99 87.408 3221-61-2 I9 2-Methyloctane 0.017 0.017 0.011 4.258 100 88.271 2216-33-3 I9 3-Methyloctane 0.017 0.018 0.012 4.407 101 88.938 95-47-6 Q8 o-Xylene 1.771 1.477 1.460 486.459 102 89.322 I10 C10 - IsoParaffin - 1 0.015 0.015 0.009 3.722 103 89.911 M9 trans-1,3-Diethylcyclopentane 0.007 0.006 0.005 1.877 104 90.171 14720-74-2 I10 2,2,4-trimethylheptane 0.016 0.016 0.010 4.036 105 91.746 111-84-2 P9 n-Nonane 0.049 0.050 0.033 12.527 106 93.095 98-82-8 Q9 i-Propylbenzene 0.035 0.030 0.025 9.521

107 95.505 2051-30-1 I10 2,4-Dimethyloctane 0.006 0.006 0.004 1.633 108 96.554 103-65-1 Q9 n-Propylbenzene 0.249 0.212 0.181 67.984 109 97.400 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.988 0.839 0.719 269.512 110 97.634 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.472 0.402 0.343 128.663 111 98.260 108-67-8 Q9 1,3,5-Trimethylbenzene 0.626 0.531 0.456 170.850 112 98.907 17301-94-8 I10 4-Methylnonane 0.009 0.009 0.006 2.307 113 99.114 ? Unidentified 0.135 0.136 0.083 42.887 114 99.345 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.384 0.320 0.280 104.820 115 99.886 5911-04-6 I10 3-Methylnonane 0.015 0.015 0.009 3.896 116 100.352 ? Unidentified 0.012 0.009 0.007 3.889

117 100.483 ? Unidentified 0.034 0.034 0.019 10.877 118 100.697 I11 C11-Isoparaffin-2 0.019 0.019 0.011 4.922 119 100.977 95-63-6 Q9 1,2,4-Trimethylbenzene 1.950 1.634 1.420 532.008 120 101.163 ? Unidentified 0.026 0.028 0.016 8.382 121 101.286 ? Unidentified 0.014 0.014 0.009 4.511 122 102.335 17302-01-1 I10 3-Ethyl-3-methylheptane 0.039 0.039 0.022 10.039 123 102.625 538-93-2 Q10 i-Butylbenzene 0.065 0.056 0.042 17.548 124 102.804 124-18-5 P10 n-Decane 0.026 0.026 0.016 6.699 125 102.900 ? Unidentified 0.027 0.023 0.018 8.576 126 103.198 ? Unidentified 0.011 0.011 0.006 3.587

127 103.851 526-73-8 Q9 1,2,3-Trimethylbenzene 0.355 0.291 0.259 96.871 128 104.242 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.009 0.008 0.006 2.572 129 104.617 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.042 0.036 0.028 11.524

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 105.044 J9 Indan 0.117 0.089 0.087 32.576 131 105.638 J10 Indene 0.271 0.206 0.201 75.147 132 106.354 I11 C11-Isoparaffin-7 0.115 0.113 0.064 29.383 133 106.547 141-93-5 Q10 1,3-Diethylbenzene 0.051 0.043 0.033 13.806 134 106.825 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.433 0.369 0.282 117.435 135 107.163 105-05-5 Q10 1,4-Diethylbenzene 0.164 0.139 0.107 44.426 136 107.261 104-51-8 Q10 n-Butylbenzene 0.030 0.025 0.019 8.061 137 107.382 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.150 0.125 0.098 40.765 138 107.628 135-01-3 Q10 1,2-Diethylbenzene 0.032 0.027 0.021 8.819 139 108.080 ? Unidentified 0.030 0.029 0.017 9.489

140 108.233 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.058 0.049 0.038 15.841 141 108.354 ? Unidentified 0.034 0.034 0.020 10.972 142 108.435 ? Unidentified 0.032 0.032 0.018 10.312 143 108.562 I11 C11- Isoparaffin-11 0.242 0.239 0.136 62.077 144 108.745 ? Unidentified 0.083 0.082 0.046 26.352 145 109.079 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.119 0.100 0.078 32.365 146 109.168 ? Unidentified 0.344 0.288 0.225 109.572 147 109.395 J10 2-Methylindan 0.051 0.039 0.034 14.229 148 109.741 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.330 0.277 0.215 89.447 149 110.286 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.252 0.208 0.165 68.481

150 110.710 ? Unidentified 0.007 0.006 0.004 2.286 151 110.905 693-61-8 K11 2-Undecene, (E)- 0.020 0.019 0.012 5.034 152 111.039 ? Unidentified 0.025 0.025 0.016 7.993 153 111.195 Q11 1-Methyl-4-t-butylbenzene 0.038 0.032 0.022 10.136 154 111.314 ? Unidentified 0.039 0.032 0.023 12.538 155 111.413 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.095 0.078 0.062 25.748 156 111.710 1120-21-4 P11 n-Undecane 0.027 0.027 0.015 7.046 157 111.864 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.034 0.028 0.020 9.070 158 111.973 ? Unidentified 0.016 0.013 0.010 5.202 159 112.349 Q10 1,2,4,5-Tetramethylbenzene 0.265 0.219 0.173 71.832

160 112.614 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.367 0.302 0.239 99.520 161 113.132 I12 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.058 162 113.482 ? Unidentified 0.016 0.016 0.008 4.955 163 113.755 Q11 C11 - Aromatic - 3 0.053 0.044 0.031 14.402 164 113.946 874-35-1 H10 5-Methylindan 0.109 0.090 0.072 29.604 165 114.071 Q12 1,2-Di-i-propylbenzene 0.047 0.038 0.025 12.530 166 114.285 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.066 0.055 0.039 17.931 167 114.444 Q11 C11 - Aromatic - 4 0.035 0.029 0.021 9.434 168 114.695 824-22-6 J10 4-Methylindan 0.151 0.125 0.100 41.010 169 114.847 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.043 0.035 0.025 11.552

170 114.942 824-63-5 H10 2-Methylindan 0.115 0.095 0.076 31.306 171 115.146 ? Unidentified 0.012 0.012 0.006 3.874 172 115.258 538-68-1 Q11 n-Pentylbenzene 0.017 0.014 0.010 4.471

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 115.487 Q11 tert-Pentylbenzene 0.069 0.057 0.041 18.737 174 115.799 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.030 0.025 0.018 8.150 175 115.908 Q11 C11 - Aromatic - 6 0.039 0.034 0.023 10.674 176 116.368 100-18-5 Q12 1,4-Di-i-propylbenzene 0.054 0.044 0.029 14.492 177 116.811 91-20-3 G10 Naphthalene 0.079 0.056 0.054 22.369 178 117.241 ? Unidentified 0.010 0.008 0.005 3.091 179 117.593 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.013 0.011 0.007 3.552 180 117.894 Q12 1,3-Di-n-propylbenzene 0.042 0.035 0.023 11.349 181 118.005 Q11 C11 - Aromatic - 11 0.024 0.020 0.014 6.397 182 118.559 Q11 C11 - Aromatic - 12 0.014 0.012 0.008 3.792

183 123.439 91-57-6 G11 2-Methylnaphthalene 0.011 0.008 0.007 3.197 184 124.306 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.004 1.712 185 130.003 ? Unidentified 0.003 0.003 0.002 1.090

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.553 74-98-6 Propane 0.002 0.002 0.003 0.390

10.023 106-97-8 n-Butane 4.842 6.142 7.292 1214.581 18.121 109-66-0 n-Pentane 3.777 4.428 4.582 953.910 35.835 110-54-3 n-Hexane 5.710 6.357 5.799 1447.834 58.057 142-82-5 n-Heptane 0.558 0.599 0.487 142.091 77.869 111-65-9 n-Octane 0.174 0.182 0.133 44.393 91.746 111-84-2 n-Nonane 0.049 0.050 0.033 12.527 102.804 124-18-5 n-Decane 0.026 0.026 0.016 6.699 111.710 1120-21-4 n-Undecane 0.027 0.027 0.015 7.046

I-Paraffins 8.809 75-28-5 i-Butane 0.043 0.057 0.065 10.908

10.637 463-82-1 2,2-Dimethylpropane 0.060 0.074 0.073 15.132 15.091 78-78-4 i-Pentane 13.476 15.966 16.347 3403.446 23.086 75-83-2 2,2-Dimethylbutane 0.251 0.283 0.254 63.532 28.341 79-29-8 2,3-Dimethylbutane 0.804 0.892 0.817 203.889 29.430 107-83-5 2-Methylpentane 3.651 4.104 3.708 925.860 32.081 96-14-0 3-Methylpentane 3.049 3.370 3.097 773.214 42.234 108-08-7 2,4-Dimethylpentane 0.456 0.497 0.398 115.963 42.782 464-06-2 2,2,3-Trimethylbutane 0.053 0.057 0.047 13.584 50.663 591-76-4 2-Methylhexane 1.013 1.096 0.885 257.982 52.493 589-34-4 3-Methylhexane 0.607 0.649 0.530 154.584 55.147 540-84-1 2,2,4-Trimethylpentane 1.008 1.069 0.772 257.064 62.848 590-73-8 2,2-Dimethylhexane 0.017 0.018 0.013 4.369 64.946 564-02-3 2,2,3-Trimethylpentane 0.047 0.048 0.036 11.955 65.169 592-13-2 2,5-Dimethylhexane 0.136 0.144 0.104 34.691 65.507 589-43-5 2,4-Dimethylhexane 0.143 0.150 0.110 36.524 66.743 563-16-6 3,3-Dimethylhexane 0.012 0.013 0.009 3.092 68.483 565-75-3 2,3,4-Trimethylpentane 0.352 0.359 0.270 89.806 70.795 584-94-1 2,3-Dimethylhexane 0.110 0.113 0.084 28.064 72.048 592-27-8 2-Methylheptane 0.103 0.109 0.079 26.387 72.303 589-53-7 4-Methylheptane 0.060 0.062 0.046 15.241 73.361 589-81-1 3-Methylheptane 0.094 0.098 0.072 24.015 73.563 619-99-8 3-Ethylhexane 0.056 0.057 0.043 14.257 75.247 3522-94-9 2,2,5-Trimethylhexane 0.143 0.148 0.097 36.462 80.353 1069-53-0 2,3,5-Trimethylhexane 0.021 0.021 0.014 5.275 81.522 1071-26-7 2,4-Dimethylheptane 0.009 0.010 0.006 2.354 82.476 1072-05-5 2,6-Dimethylheptane 0.015 0.016 0.010 3.844 83.409 2,5-Dimethylheptane 0.020 0.021 0.014 5.170 87.277 2216-34-4 4-Methyloctane 0.013 0.013 0.009 3.221 87.408 3221-61-2 2-Methyloctane 0.017 0.017 0.011 4.258 88.271 2216-33-3 3-Methyloctane 0.017 0.018 0.012 4.407 89.322 C10 - IsoParaffin - 1 0.015 0.015 0.009 3.722 90.171 14720-74-2 2,2,4-trimethylheptane 0.016 0.016 0.010 4.036 95.505 2051-30-1 2,4-Dimethyloctane 0.006 0.006 0.004 1.633 98.907 17301-94-8 4-Methylnonane 0.009 0.009 0.006 2.307 99.886 5911-04-6 3-Methylnonane 0.015 0.015 0.009 3.896 100.697 C11-Isoparaffin-2 0.019 0.019 0.011 4.922

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 102.335 17302-01-1 3-Ethyl-3-methylheptane 0.039 0.039 0.022 10.039

106.354 C11-Isoparaffin-7 0.115 0.113 0.064 29.383 108.562 C11- Isoparaffin-11 0.242 0.239 0.136 62.077 113.132 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.058

Aromatics Mono-Aromatics 45.637 71-42-3 Benzene 0.637 0.532 0.713 178.108

69.119 108-88-3 Toluene 19.510 16.520 18.532 5398.904 84.745 100-41-4 Ethylbenzene 2.658 2.251 2.191 729.994 85.989 108-38-3 m-Xylene 6.429 5.461 5.300 1765.617 86.130 106-42-3 p-Xylene 3.031 2.584 2.499 832.419 88.938 95-47-6 o-Xylene 1.771 1.477 1.460 486.459 93.095 98-82-8 i-Propylbenzene 0.035 0.030 0.025 9.521 96.554 103-65-1 n-Propylbenzene 0.249 0.212 0.181 67.984 97.400 620-14-4 1-Methyl-3-ethylbenzene 0.988 0.839 0.719 269.512 97.634 622-96-8 1-Methyl-4-ethylbenzene 0.472 0.402 0.343 128.663 98.260 108-67-8 1,3,5-Trimethylbenzene 0.626 0.531 0.456 170.850 99.345 611-14-3 1-Methyl-2-ethylbenzene 0.384 0.320 0.280 104.820 100.977 95-63-6 1,2,4-Trimethylbenzene 1.950 1.634 1.420 532.008 102.625 538-93-2 i-Butylbenzene 0.065 0.056 0.042 17.548 103.851 526-73-8 1,2,3-Trimethylbenzene 0.355 0.291 0.259 96.871 104.242 535-77-3 1-Methyl-3-i-propylbenzene 0.009 0.008 0.006 2.572 104.617 99-87-6 1-Methyl-4-i-propylbenzene 0.042 0.036 0.028 11.524 106.547 141-93-5 1,3-Diethylbenzene 0.051 0.043 0.033 13.806 106.825 1074-43-7 1-Methyl-3-n-propylbenzene 0.433 0.369 0.282 117.435 107.163 105-05-5 1,4-Diethylbenzene 0.164 0.139 0.107 44.426 107.261 104-51-8 n-Butylbenzene 0.030 0.025 0.019 8.061 107.382 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.150 0.125 0.098 40.765 107.628 135-01-3 1,2-Diethylbenzene 0.032 0.027 0.021 8.819 108.233 1074-17-5 1-Methyl-2-n-propylbenzene 0.058 0.049 0.038 15.841 109.079 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.119 0.100 0.078 32.365 109.741 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.330 0.277 0.215 89.447 110.286 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.252 0.208 0.165 68.481 111.195 1-Methyl-4-t-butylbenzene 0.038 0.032 0.022 10.136 111.413 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.095 0.078 0.062 25.748 111.864 4218-48-8 1-Ethyl-4-i-propylbenzene 0.034 0.028 0.020 9.070 112.349 1,2,4,5-Tetramethylbenzene 0.265 0.219 0.173 71.832 112.614 527-53-7 1,2,3,5-Tetramethylbenzene 0.367 0.302 0.239 99.520 113.755 C11 - Aromatic - 3 0.053 0.044 0.031 14.402 114.071 1,2-Di-i-propylbenzene 0.047 0.038 0.025 12.530 114.285 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.066 0.055 0.039 17.931 114.444 C11 - Aromatic - 4 0.035 0.029 0.021 9.434 114.847 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.043 0.035 0.025 11.552 115.258 538-68-1 n-Pentylbenzene 0.017 0.014 0.010 4.471 115.487 tert-Pentylbenzene 0.069 0.057 0.041 18.737 115.799 577-55-9 1-Methyl-2-n-butylbenzene 0.030 0.025 0.018 8.150 115.908 C11 - Aromatic - 6 0.039 0.034 0.023 10.674

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 116.368 100-18-5 1,4-Di-i-propylbenzene 0.054 0.044 0.029 14.492

117.593 7364-19-4 1t-Butyl-4-ethylbenzene 0.013 0.011 0.007 3.552 117.894 1,3-Di-n-propylbenzene 0.042 0.035 0.023 11.349 118.005 C11 - Aromatic - 11 0.024 0.020 0.014 6.397 118.559 C11 - Aromatic - 12 0.014 0.012 0.008 3.792

Naphthalenes 116.811 91-20-3 Naphthalene 0.079 0.056 0.054 22.369

123.439 91-57-6 2-Methylnaphthalene 0.011 0.008 0.007 3.197 124.306 90-12-0 1-Methylnaphthalene 0.006 0.004 0.004 1.712

Naphtheno/Olefino-Benzs

113.946 874-35-1 5-Methylindan 0.109 0.090 0.072 29.604 114.942 824-63-5 2-Methylindan 0.115 0.095 0.076 31.306

Indenes 105.044 Indan 0.117 0.089 0.087 32.576

105.638 Indene 0.271 0.206 0.201 75.147 109.395 2-Methylindan 0.051 0.039 0.034 14.229 114.695 824-22-6 4-Methylindan 0.151 0.125 0.100 41.010

Naphthenes Mono-Naphthenes 27.607 287-92-3 Cyclopentane 0.367 0.362 0.458 95.385

40.684 96-37-7 Methylcyclopentane 2.852 2.796 2.965 740.776 47.560 110-82-7 Cyclohexane 1.609 1.517 1.673 417.909 53.354 1759-58-6 1t,3-Dimethylcyclopentane 0.163 0.160 0.145 42.386 53.940 2532-58-3 1c,3-Dimethylcyclopentane 0.132 0.130 0.118 34.376 54.562 822-50-4 1t,2-Dimethylcyclopentane 0.187 0.182 0.166 48.511 61.520 108-87-2 Methylcyclohexane 1.007 0.961 0.898 261.594 62.459 4516-69-2 1,1,3-Trimethylcyclopentane 0.021 0.021 0.016 5.446 64.301 1640-89-7 Ethylcyclopentane 0.035 0.034 0.031 9.101 66.347 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.019 0.019 0.015 4.998 67.864 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.015 0.014 0.012 3.904 73.225 1,3-dimethyl-t-cyclohexane 0.087 0.083 0.068 22.674 82.174 1678-91-7 Ethylcyclohexane 0.043 0.040 0.034 11.217 89.911 trans-1,3-Diethylcyclopentane 0.007 0.006 0.005 1.877

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.622 115-11-7 Isobutene 0.026 0.032 0.040 6.684

9.664 106-98-9 Butene-1 0.028 0.034 0.043 7.220 10.509 624-64-6 t-Butene-2 0.107 0.130 0.167 27.870 11.251 590-18-1 c-Butene-2 0.121 0.144 0.189 31.554 16.727 109-67-1 Pentene-1 0.378 0.433 0.471 98.111 19.234 646-04-8 t-Pentene-2 0.970 1.098 1.210 251.892 20.265 627-20-3 c-Pentene-2 0.530 0.593 0.661 137.684 33.459 592-41-6 Hexene-1 0.169 0.183 0.176 43.925 36.437 13269-52-8 t-Hexene-3 0.283 0.305 0.294 73.510 36.916 4050-45-7 t-Hexene-2 0.428 0.460 0.445 111.062 38.749 7688-21-3 c-Hexene-2 0.227 0.241 0.236 59.038

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 57.332 14686-14-7 t-Heptene-3 0.017 0.018 0.015 4.363

110.905 693-61-8 2-Undecene, (E)- 0.020 0.019 0.012 5.034

Iso-Olefins 13.453 563-45-1 3-Methylbutene-1 0.083 0.097 0.103 21.504

17.581 563-46-2 2-Methylbutene-1 0.590 0.666 0.737 153.394 20.949 513-35-9 2-Methylbutene-2 1.207 1.338 1.506 313.560 29.196 691-38-3 4-Methyl-c-pentene-2 0.052 0.056 0.054 13.440 29.838 674-76-0 4-Methyl-t-pentene-2 0.147 0.160 0.153 38.256 33.235 763-29-1 2-Methylpentene-1 0.250 0.268 0.260 64.935 37.411 625-27-4 2-Methylpentene-2 0.376 0.399 0.391 97.588 37.821 922-62-3 3-Methyl-c-pentene-2 0.286 0.301 0.297 74.313 40.087 3404-73-7 3,3-Dimethylpentene-1 0.338 0.353 0.301 87.687 42.536 594-56-9 2,3,3-Trimethylbutene-1 0.010 0.010 0.009 2.522 46.642 3404-61-3 3-Methylhexene-1 0.012 0.013 0.011 3.208 47.234 3524-73-0 5-Methylhexene-1 0.076 0.081 0.068 19.858 49.272 15840-60-5 2-Methyl-c-hexene-3 0.033 0.034 0.029 8.463 50.266 3404-55-5 4-Methyl-t/c-hexene-2 0.038 0.040 0.034 9.955 57.681 6094-02-6 2-Methylhexene-1 0.027 0.028 0.024 6.925 58.548 2738-19-4 2-Methyl-2-hexene 0.006 0.006 0.005 1.512

Naphtheno-Olefins 22.541 1574-41-0 1,3-Cyclopentadiene 0.006 0.007 0.008 1.675

25.750 142-29-0 Cyclopentene 0.207 0.197 0.266 55.409 37.052 1120-62-3 3-Methylcyclopentene 0.109 0.105 0.116 28.297 45.836 693-89-0 1-Methylcyclopentene 0.344 0.324 0.366 91.415 51.155 110-83-8 Cyclohexene 0.036 0.033 0.039 9.472

Di-Olefins 18.628 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 2.693

21.271 2004-70-8 1t,3-Pentadiene 0.015 0.016 0.019 3.977 45.426 1528-30-9 C6-Diolefin-1 0.014 0.014 0.015 3.691

Oxygenates 26.904 71-23-8 n-Propanol 0.077 0.071 0.113 14.067

48.060 71-36-3 n-Butanol 0.047 0.044 0.056 9.334

Unidentified 19.878 Unidentified 0.007 0.008 0.009 2.217

26.992 Unidentified 0.070 0.077 0.073 22.337 28.735 Unidentified 0.063 0.062 0.062 19.922 50.840 Unidentified 0.065 0.069 0.059 20.803 74.459 Unidentified 0.013 0.012 0.010 4.134 76.530 Unidentified 0.028 0.026 0.022 8.891 82.976 Unidentified 0.006 0.006 0.005 1.855 99.114 Unidentified 0.135 0.136 0.083 42.887 100.352 Unidentified 0.012 0.009 0.007 3.889 100.483 Unidentified 0.034 0.034 0.019 10.877 101.163 Unidentified 0.026 0.028 0.016 8.382 101.286 Unidentified 0.014 0.014 0.009 4.511 102.900 Unidentified 0.027 0.023 0.018 8.576 103.198 Unidentified 0.011 0.011 0.006 3.587

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 108.080 Unidentified 0.030 0.029 0.017 9.489

108.354 Unidentified 0.034 0.034 0.020 10.972 108.435 Unidentified 0.032 0.032 0.018 10.312 108.745 Unidentified 0.083 0.082 0.046 26.352 109.168 Unidentified 0.344 0.288 0.225 109.572 110.710 Unidentified 0.007 0.006 0.004 2.286 111.039 Unidentified 0.025 0.025 0.016 7.993 111.314 Unidentified 0.039 0.032 0.023 12.538 111.973 Unidentified 0.016 0.013 0.010 5.202 113.482 Unidentified 0.016 0.016 0.008 4.955 115.146 Unidentified 0.012 0.012 0.006 3.874 117.241 Unidentified 0.010 0.008 0.005 3.091 130.003 Unidentified 0.003 0.003 0.002 1.090

Plus

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2 2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

t-Heptene-3 2-Methylhexene-1 n-Heptane 2-Methyl-2-hexene

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane
Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane

1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

Unidentified

n-Octane

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane

Ethylbenzene

m-Xylene p-Xylene

4-Methyloctane 2-Methyloctane

3-Methyloctane

o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2

1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 6 1,4-Di-i-propylbenzene Naphthalene Unidentified 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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24-Aug-10, 20:15:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF Sample: ODDB-91322 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91322 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000004.D\SIG2000004_FID2_B.CDF145.0140.0135.0130.0125.0

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 6.906 8.243 7.693

I-Paraffins 28.366 31.684 24.604

Aromatics 41.804 36.628 34.990 Mono-Aromatics 40.963 35.943 34.418 Naphthalenes 0.100 0.074 0.066 Naphtheno/Olefino-Benzs 0.226 0.193 0.147 Indenes 0.516 0.418 0.360

Naphthenes 3.699 3.711 3.664 Mono-Naphthenes 3.699 3.711 3.664 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.039 7.921 7.918 n-Olefins 2.948 3.404 3.421 Iso-Olefins 3.351 3.787 3.674 Naphtheno-Olefins 0.699 0.686 0.776 Di-Olefins 0.040 0.044 0.048

Oxygenates 10.889 10.511 20.262

Unidentified 1.297 1.302 0.868

Plus 0.000 0.000 0.000

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 10.756 10.385 20.087 C3 0.079 0.076 0.113 C4 1.304 1.685 1.923 C5 10.808 12.963 13.025 C6 13.960 15.359 14.147 C7 20.559 18.912 18.923 C8 28.531 27.577 22.379 C9 7.887 7.411 5.528 C10 3.784 3.378 2.424 C11 0.854 0.798 0.485 C12 0.181 0.155 0.096

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.002 C4 1.038 1.366 1.537 C5 2.215 2.694 2.641 C6 3.053 3.527 3.048 C7 0.327 0.365 0.281 C8 0.074 0.080 0.056 C9 0.156 0.166 0.105 C10 0.017 0.018 0.010 C11 0.024 0.025 0.013

I-Paraffins C4 0.020 0.028 0.030 C5 4.839 5.950 5.770 C6 5.137 5.945 5.128 C7 2.103 2.358 1.805 C8 12.748 13.664 9.601 C9 2.460 2.640 1.650 C10 0.716 0.749 0.431 C11 0.341 0.350 0.188 C12 0.001 0.001 0.001

Mono-Aromatics C6 0.762 0.660 0.839 C7 16.516 14.511 15.421 C8 15.555 13.681 12.605 C9 5.195 4.545 3.718 C10 2.306 2.002 1.478 C11 0.456 0.395 0.265 C12 0.174 0.150 0.092

Naphthalenes C10 0.085 0.063 0.057 C11 0.015 0.011 0.009

Naphtheno/Olefino-Benzs C10 0.226 0.193 0.147

Indenes C9 0.076 0.060 0.055 C10 0.434 0.353 0.301 C12 0.005 0.004 0.003

Mono-Naphthenes C5 0.211 0.216 0.259 C6 2.497 2.504 2.553 C7 0.847 0.849 0.742 C8 0.144 0.142 0.111

n-Olefins C4 0.191 0.238 0.293

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.620 1.902 1.987 C6 1.022 1.139 1.045 C7 0.098 0.107 0.086 C11 0.017 0.017 0.010

Iso-Olefins C5 1.697 1.973 2.082 C6 0.990 1.096 1.012 C7 0.653 0.708 0.572 C8 0.011 0.010 0.007

Naphtheno-Olefins C5 0.201 0.199 0.254 C6 0.498 0.488 0.522

Di-Olefins C5 0.026 0.029 0.032 C7 0.015 0.015 0.015

Oxygenates C2 10.756 10.385 20.087 C3 0.078 0.074 0.112 C4 0.055 0.052 0.064

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 25.14 23.93 5% 81.10 80.44 10% 97.22 94.84 15% 139.57 131.76 20% 154.53 144.68 25% 172.23 155.08 30% 172.73 172.33 35% 173.24 172.85 40% 197.42 176.07 45% 228.41 209.29 50% 230.13 228.91 55% 230.51 230.22 60% 230.89 230.65 65% 234.98 231.22 70% 239.92 237.34 75% 276.50 255.09 80% 281.21 278.79 85% 282.09 281.76 90% 320.72 292.60 95% 339.72 335.93 FBP 403.56 399.20

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.554 74-98-6 P3 Propane 0.001 0.001 0.002 0.237 2 8.810 75-28-5 I4 i-Butane 0.020 0.028 0.030 5.687 3 9.623 115-11-7 K4 Isobutene 0.016 0.020 0.024 4.578 4 9.665 106-98-9 K4 Butene-1 0.018 0.023 0.027 5.141 5 10.023 106-97-8 P4 n-Butane 1.038 1.366 1.537 289.748 6 10.510 624-64-6 K4 t-Butene-2 0.072 0.091 0.111 20.857 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.016 0.021 0.020 4.627 8 11.251 590-18-1 K4 c-Butene-2 0.085 0.104 0.131 24.611 9 13.062 64-17-5 X2 Ethanol 10.756 10.385 20.087 1280.145 10 13.450 563-45-1 C5 3-Methylbutene-1 0.173 0.210 0.213 50.077

11 15.082 78-78-4 I5 i-Pentane 4.822 5.929 5.750 1355.113 12 16.730 109-67-1 K5 Pentene-1 0.328 0.391 0.403 94.912 13 17.580 563-46-2 C5 2-Methylbutene-1 0.499 0.584 0.612 144.229 14 18.114 109-66-0 P5 n-Pentane 2.215 2.694 2.641 622.394 15 18.626 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 3.050 16 19.233 646-04-8 K5 t-Pentene-2 0.834 0.980 1.023 241.073 17 19.880 ? Unidentified 0.006 0.007 0.007 2.020 18 20.262 627-20-3 K5 c-Pentene-2 0.457 0.531 0.561 132.177 19 20.944 513-35-9 C5 2-Methylbutene-2 1.025 1.179 1.257 296.164 20 21.268 2004-70-8 E5 1t,3-Pentadiene 0.015 0.017 0.019 4.549

21 22.531 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.009 2.052 22 23.095 75-83-2 I6 2,2-Dimethylbutane 0.121 0.142 0.121 34.238 23 25.744 142-29-0 B5 Cyclopentene 0.194 0.191 0.245 57.679 24 26.900 71-23-8 X3 n-Propanol 0.078 0.074 0.112 15.799 25 26.989 ? Unidentified 0.056 0.064 0.058 19.922 26 27.606 287-92-3 M5 Cyclopentane 0.211 0.216 0.259 61.042 27 28.333 79-29-8 I6 2,3-Dimethylbutane 0.750 0.863 0.748 211.474 28 28.732 ? Unidentified 0.052 0.053 0.051 18.373 29 29.193 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.051 0.046 13.117 30 29.418 107-83-5 I6 2-Methylpentane 2.416 2.818 2.412 681.717

31 29.841 674-76-0 C6 4-Methyl-t-pentene-2 0.129 0.146 0.132 37.315 32 32.067 96-14-0 I6 3-Methylpentane 1.850 2.121 1.846 521.798 33 33.229 763-29-1 C6 2-Methylpentene-1 0.221 0.245 0.226 63.771 34 33.450 592-41-6 K6 Hexene-1 0.157 0.177 0.161 45.517 35 35.821 110-54-3 P6 n-Hexane 3.053 3.527 3.048 861.460 36 36.440 13269-52-8 K6 t-Hexene-3 0.259 0.289 0.265 74.877 37 36.916 4050-45-7 K6 t-Hexene-2 0.395 0.441 0.404 114.209 38 37.036 1120-62-3 B6 3-Methylcyclopentene 0.101 0.101 0.106 29.186 39 37.407 625-27-4 C6 2-Methylpentene-2 0.336 0.370 0.343 97.066 40 37.818 922-62-3 C6 3-Methyl-c-pentene-2 0.259 0.283 0.265 74.916

41 38.740 7688-21-3 K6 c-Hexene-2 0.211 0.232 0.215 60.847 42 40.089 3404-73-7 C7 3,3-Dimethylpentene-1 0.305 0.331 0.267 88.098 43 40.675 96-37-7 M6 Methylcyclopentane 1.565 1.592 1.599 452.199

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.230 108-08-7 I7 2,4-Dimethylpentane 0.538 0.609 0.462 152.407 45 42.534 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.014 0.011 3.763 46 42.781 464-06-2 I7 2,2,3-Trimethylbutane 0.047 0.051 0.040 13.209 47 45.426 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.015 4.249 48 45.634 71-42-3 Q6 Benzene 0.762 0.660 0.839 237.175 49 45.833 693-89-0 B6 1-Methylcyclopentene 0.353 0.345 0.370 104.623 50 46.638 3404-61-3 C7 3-Methylhexene-1 0.015 0.016 0.013 4.354 51 47.231 3524-73-0 C7 5-Methylhexene-1 0.054 0.059 0.048 15.678 52 47.553 110-82-7 M6 Cyclohexane 0.932 0.912 0.953 269.515 53 48.056 71-36-3 X4 n-Butanol 0.055 0.052 0.064 11.986

54 49.271 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.044 0.035 11.538 55 49.619 3769-23-1 C7 4-Methylhexene-1 0.012 0.013 0.010 3.337 56 50.261 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.054 0.044 14.467 57 50.664 591-76-4 I7 2-Methylhexane 1.003 1.126 0.861 284.040 58 50.836 ? Unidentified 0.039 0.043 0.035 13.977 59 51.151 110-83-8 B6 Cyclohexene 0.044 0.041 0.046 12.672 60 52.490 589-34-4 I7 3-Methylhexane 0.515 0.571 0.442 145.972 61 53.351 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.139 0.142 0.122 40.249 62 53.937 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.103 0.105 0.090 29.742 63 54.562 822-50-4 M7 1t,2-Dimethylcyclopentane 0.133 0.135 0.116 38.375

64 54.855 C7 C7 - Iso-Olefin - 2 0.022 0.023 0.019 6.381 65 55.166 540-84-1 I8 2,2,4-Trimethylpentane 3.105 3.418 2.338 881.243 66 55.468 592-76-7 K7 Heptene-1 0.029 0.031 0.025 8.271 67 56.801 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.977 68 57.328 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.028 9.103 69 57.683 6094-02-6 C7 2-Methylhexene-1 0.056 0.062 0.049 16.277 70 58.053 142-82-5 P7 n-Heptane 0.327 0.365 0.281 92.763 71 58.271 7642-10-6 K7 c-Heptene-3 0.025 0.027 0.022 7.113 72 58.547 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.027 0.022 7.371 73 58.790 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.021 0.017 5.576

74 59.172 14686-13-6 K7 t-Heptene-2 0.014 0.015 0.012 3.949 75 59.649 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.016 5.236 76 60.074 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.013 4.351 77 60.859 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.672 78 61.513 108-87-2 M7 Methylcyclohexane 0.430 0.425 0.376 124.148 79 63.384 ? Unidentified 0.027 0.029 0.021 9.577 80 64.295 1640-89-7 M7 Ethylcyclopentane 0.024 0.024 0.021 6.964 81 64.948 564-02-3 I8 2,2,3-Trimethylpentane 0.358 0.381 0.270 101.573 82 65.177 592-13-2 I8 2,5-Dimethylhexane 0.729 0.801 0.549 207.023 83 65.514 589-43-5 I8 2,4-Dimethylhexane 0.670 0.728 0.504 190.076

84 68.513 565-75-3 I8 2,3,4-Trimethylpentane 3.335 3.533 2.511 946.399 85 69.118 108-88-3 Q7 Toluene 16.516 14.511 15.421 5084.878 86 69.224 560-21-4 I8 2,3,3-Trimethylpentane 3.366 3.531 2.535 955.458

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 70.801 584-94-1 I8 2,3-Dimethylhexane 0.888 0.950 0.669 252.112 88 72.047 592-27-8 I8 2-Methylheptane 0.080 0.088 0.060 22.779 89 72.316 589-53-7 I8 4-Methylheptane 0.114 0.124 0.086 32.426 90 72.449 ? Unidentified 0.075 0.080 0.057 26.628 91 73.225 M8 1,3-dimethyl-t-cyclohexane 0.033 0.033 0.025 9.569 92 73.361 589-81-1 I8 3-Methylheptane 0.076 0.082 0.057 21.485 93 73.555 619-99-8 I8 3-Ethylhexane 0.026 0.028 0.020 7.458 94 75.260 3522-94-9 I9 2,2,5-Trimethylhexane 1.861 2.004 1.248 529.196 95 76.235 3875-51-2 M8 i-Propylcyclopentane 0.018 0.017 0.013 5.059 96 76.534 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.014 0.014 0.011 4.150

97 77.867 111-65-9 P8 n-Octane 0.074 0.080 0.056 21.014 98 78.820 M8 C8 - MonoNaph - 3 0.058 0.058 0.045 16.896 99 80.353 1069-53-0 I9 2,3,5-Trimethylhexane 0.323 0.340 0.216 91.736 100 81.519 1071-26-7 I9 2,4-Dimethylheptane 0.045 0.048 0.030 12.839 101 82.171 1678-91-7 M8 Ethylcyclohexane 0.021 0.020 0.016 5.986 102 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.058 0.063 0.039 16.547 103 83.411 I9 2,5-Dimethylheptane 0.145 0.155 0.098 41.337 104 84.749 100-41-4 Q8 Ethylbenzene 2.921 2.566 2.367 892.510 105 84.900 ? Unidentified 0.020 0.021 0.014 7.125 106 85.148 ? Unidentified 0.020 0.019 0.013 6.955

107 86.000 108-38-3 Q8 m-Xylene 7.170 6.320 5.810 2190.845 108 86.140 106-42-3 Q8 p-Xylene 3.429 3.034 2.779 1047.780 109 86.490 C8 C9-IsoOlefin-3 0.011 0.010 0.007 3.096 110 86.597 ? Unidentified 0.009 0.009 0.006 3.115 111 87.277 2216-34-4 I9 4-Methyloctane 0.007 0.008 0.005 2.113 112 87.409 3221-61-2 I9 2-Methyloctane 0.010 0.011 0.007 2.976 113 88.270 2216-33-3 I9 3-Methyloctane 0.010 0.011 0.007 2.970 114 88.747 ? Unidentified 0.119 0.133 0.081 42.266 115 88.942 95-47-6 Q8 o-Xylene 2.035 1.761 1.649 621.671 116 89.323 I10 C10 - IsoParaffin - 1 0.371 0.388 0.224 105.583

117 90.165 14720-74-2 I10 2,2,4-trimethylheptane 0.250 0.262 0.151 71.304 118 91.711 111-84-2 P9 n-Nonane 0.156 0.166 0.105 44.343 119 93.094 98-82-8 Q9 i-Propylbenzene 0.032 0.029 0.023 9.854 120 93.840 ? Unidentified 0.043 0.045 0.026 15.189 121 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.014 0.015 0.008 3.989 122 94.865 15869-89-3 I10 2,5-Dimethyloctane 0.005 0.005 0.003 1.487 123 95.505 2051-30-1 I10 2,4-Dimethyloctane 0.011 0.012 0.007 3.199 124 96.553 103-65-1 Q9 n-Propylbenzene 0.297 0.262 0.212 90.093 125 97.401 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.153 1.016 0.825 349.962 126 97.635 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.536 0.474 0.383 162.579

127 98.259 108-67-8 Q9 1,3,5-Trimethylbenzene 0.678 0.597 0.485 205.829 128 98.906 17301-94-8 I10 4-Methylnonane 0.010 0.011 0.006 2.956 129 99.113 ? Unidentified 0.166 0.174 0.100 58.751

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 99.344 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.394 0.341 0.282 119.695 131 99.884 5911-04-6 I10 3-Methylnonane 0.016 0.017 0.010 4.631 132 100.351 ? Unidentified 0.013 0.010 0.007 4.764 133 100.481 ? Unidentified 0.037 0.037 0.020 12.966 134 100.697 I11 C11-Isoparaffin-2 0.020 0.021 0.011 5.847 135 100.977 95-63-6 Q9 1,2,4-Trimethylbenzene 1.871 1.627 1.339 568.018 136 101.163 ? Unidentified 0.026 0.028 0.016 9.046 137 101.284 ? Unidentified 0.015 0.015 0.009 5.207 138 102.334 17302-01-1 I10 3-Ethyl-3-methylheptane 0.038 0.039 0.021 10.942 139 102.627 538-93-2 Q10 i-Butylbenzene 0.054 0.048 0.034 16.250

140 102.801 124-18-5 P10 n-Decane 0.017 0.018 0.010 4.852 141 102.899 ? Unidentified 0.017 0.015 0.011 6.081 142 103.197 ? Unidentified 0.011 0.011 0.006 3.792 143 103.849 526-73-8 Q9 1,2,3-Trimethylbenzene 0.234 0.199 0.167 71.027 144 104.614 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.039 0.035 0.025 11.844 145 105.043 J9 Indan 0.076 0.060 0.055 23.343 146 105.637 J10 Indene 0.239 0.189 0.174 73.690 147 106.352 I11 C11-Isoparaffin-7 0.099 0.101 0.054 28.124 148 106.546 141-93-5 Q10 1,3-Diethylbenzene 0.028 0.025 0.018 8.585 149 106.826 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.365 0.323 0.234 110.217

150 107.162 105-05-5 Q10 1,4-Diethylbenzene 0.140 0.123 0.090 42.193 151 107.260 104-51-8 Q10 n-Butylbenzene 0.024 0.021 0.015 7.124 152 107.381 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.128 0.111 0.082 38.708 153 107.627 135-01-3 Q10 1,2-Diethylbenzene 0.028 0.024 0.018 8.497 154 108.079 ? Unidentified 0.025 0.026 0.014 8.864 155 108.232 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.054 0.047 0.034 16.172 156 108.354 ? Unidentified 0.029 0.030 0.016 10.424 157 108.435 ? Unidentified 0.027 0.028 0.015 9.667 158 108.561 I11 C11- Isoparaffin-11 0.222 0.228 0.122 63.417 159 108.743 ? Unidentified 0.072 0.073 0.039 25.407

160 109.078 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.120 0.104 0.077 36.272 161 109.167 ? Unidentified 0.311 0.270 0.199 110.054 162 109.394 J10 2-Methylindan 0.042 0.033 0.028 13.032 163 109.741 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.328 0.285 0.210 98.972 164 110.286 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.219 0.188 0.141 66.200 165 110.709 ? Unidentified 0.006 0.006 0.004 2.242 166 110.903 693-61-8 K11 2-Undecene, (E)- 0.017 0.017 0.010 4.845 167 111.038 ? Unidentified 0.022 0.023 0.014 7.882 168 111.195 Q11 1-Methyl-4-t-butylbenzene 0.034 0.030 0.020 10.192 169 111.413 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.133 0.113 0.085 40.093

170 111.711 1120-21-4 P11 n-Undecane 0.024 0.025 0.013 6.966 171 111.865 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.030 0.026 0.018 9.085 172 111.972 ? Unidentified 0.015 0.013 0.009 5.198

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 112.348 Q10 1,2,4,5-Tetramethylbenzene 0.269 0.231 0.172 81.212 174 112.614 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.377 0.323 0.242 113.923 175 113.131 I12 C12 - IsoParaffin - 1 0.001 0.001 0.001 0.286 176 113.484 ? Unidentified 0.013 0.014 0.007 4.765 177 113.754 Q11 C11 - Aromatic - 3 0.053 0.045 0.031 15.844 178 113.945 874-35-1 H10 5-Methylindan 0.109 0.094 0.071 33.009 179 114.071 Q12 1,2-Di-i-propylbenzene 0.046 0.040 0.025 13.902 180 114.285 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.066 0.057 0.038 19.852 181 114.445 Q11 C11 - Aromatic - 4 0.035 0.030 0.020 10.503 182 114.694 824-22-6 J10 4-Methylindan 0.153 0.131 0.100 46.330

183 114.846 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.043 0.037 0.025 13.009 184 114.942 824-63-5 H10 2-Methylindan 0.116 0.099 0.076 35.088 185 115.145 ? Unidentified 0.012 0.013 0.006 4.426 186 115.258 538-68-1 Q11 n-Pentylbenzene 0.017 0.015 0.010 5.102 187 115.487 Q11 tert-Pentylbenzene 0.070 0.060 0.040 20.966 188 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.030 0.026 0.017 9.011 189 115.908 Q11 C11 - Aromatic - 6 0.040 0.036 0.023 11.982 190 116.368 100-18-5 Q12 1,4-Di-i-propylbenzene 0.058 0.050 0.031 17.460 191 116.810 91-20-3 G10 Naphthalene 0.085 0.063 0.057 26.861 192 116.945 ? Unidentified 0.007 0.008 0.004 2.642

193 117.241 Q12 C12-Aromatic-1 0.017 0.016 0.009 5.222 194 117.413 J12 Dimethyl Indane - 1 0.005 0.004 0.003 1.693 195 117.593 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.009 0.008 0.005 2.825 196 117.893 Q12 1,3-Di-n-propylbenzene 0.043 0.037 0.023 12.830 197 118.005 Q11 C11 - Aromatic - 11 0.024 0.021 0.014 7.124 198 118.558 Q11 C11 - Aromatic - 12 0.015 0.013 0.009 4.427 199 123.439 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.006 3.084 200 124.305 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.565 201 126.297 ? Unidentified 0.003 0.003 0.001 1.031 202 130.003 ? Unidentified 0.003 0.002 0.002 1.044

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.001 0.001 0.002 0.237

10.023 106-97-8 n-Butane 1.038 1.366 1.537 289.748 18.114 109-66-0 n-Pentane 2.215 2.694 2.641 622.394 35.821 110-54-3 n-Hexane 3.053 3.527 3.048 861.460 58.053 142-82-5 n-Heptane 0.327 0.365 0.281 92.763 77.867 111-65-9 n-Octane 0.074 0.080 0.056 21.014 91.711 111-84-2 n-Nonane 0.156 0.166 0.105 44.343 102.801 124-18-5 n-Decane 0.017 0.018 0.010 4.852 111.711 1120-21-4 n-Undecane 0.024 0.025 0.013 6.966

I-Paraffins 8.810 75-28-5 i-Butane 0.020 0.028 0.030 5.687

10.637 463-82-1 2,2-Dimethylpropane 0.016 0.021 0.020 4.627 15.082 78-78-4 i-Pentane 4.822 5.929 5.750 1355.113 23.095 75-83-2 2,2-Dimethylbutane 0.121 0.142 0.121 34.238 28.333 79-29-8 2,3-Dimethylbutane 0.750 0.863 0.748 211.474 29.418 107-83-5 2-Methylpentane 2.416 2.818 2.412 681.717 32.067 96-14-0 3-Methylpentane 1.850 2.121 1.846 521.798 42.230 108-08-7 2,4-Dimethylpentane 0.538 0.609 0.462 152.407 42.781 464-06-2 2,2,3-Trimethylbutane 0.047 0.051 0.040 13.209 50.664 591-76-4 2-Methylhexane 1.003 1.126 0.861 284.040 52.490 589-34-4 3-Methylhexane 0.515 0.571 0.442 145.972 55.166 540-84-1 2,2,4-Trimethylpentane 3.105 3.418 2.338 881.243 64.948 564-02-3 2,2,3-Trimethylpentane 0.358 0.381 0.270 101.573 65.177 592-13-2 2,5-Dimethylhexane 0.729 0.801 0.549 207.023 65.514 589-43-5 2,4-Dimethylhexane 0.670 0.728 0.504 190.076 68.513 565-75-3 2,3,4-Trimethylpentane 3.335 3.533 2.511 946.399 69.224 560-21-4 2,3,3-Trimethylpentane 3.366 3.531 2.535 955.458 70.801 584-94-1 2,3-Dimethylhexane 0.888 0.950 0.669 252.112 72.047 592-27-8 2-Methylheptane 0.080 0.088 0.060 22.779 72.316 589-53-7 4-Methylheptane 0.114 0.124 0.086 32.426 73.361 589-81-1 3-Methylheptane 0.076 0.082 0.057 21.485 73.555 619-99-8 3-Ethylhexane 0.026 0.028 0.020 7.458 75.260 3522-94-9 2,2,5-Trimethylhexane 1.861 2.004 1.248 529.196 80.353 1069-53-0 2,3,5-Trimethylhexane 0.323 0.340 0.216 91.736 81.519 1071-26-7 2,4-Dimethylheptane 0.045 0.048 0.030 12.839 82.476 1072-05-5 2,6-Dimethylheptane 0.058 0.063 0.039 16.547 83.411 2,5-Dimethylheptane 0.145 0.155 0.098 41.337 87.277 2216-34-4 4-Methyloctane 0.007 0.008 0.005 2.113 87.409 3221-61-2 2-Methyloctane 0.010 0.011 0.007 2.976 88.270 2216-33-3 3-Methyloctane 0.010 0.011 0.007 2.970 89.323 C10 - IsoParaffin - 1 0.371 0.388 0.224 105.583 90.165 14720-74-2 2,2,4-trimethylheptane 0.250 0.262 0.151 71.304 94.064 15869-87-1 2,2-Dimethyloctane 0.014 0.015 0.008 3.989 94.865 15869-89-3 2,5-Dimethyloctane 0.005 0.005 0.003 1.487 95.505 2051-30-1 2,4-Dimethyloctane 0.011 0.012 0.007 3.199 98.906 17301-94-8 4-Methylnonane 0.010 0.011 0.006 2.956 99.884 5911-04-6 3-Methylnonane 0.016 0.017 0.010 4.631

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 100.697 C11-Isoparaffin-2 0.020 0.021 0.011 5.847

102.334 17302-01-1 3-Ethyl-3-methylheptane 0.038 0.039 0.021 10.942 106.352 C11-Isoparaffin-7 0.099 0.101 0.054 28.124 108.561 C11- Isoparaffin-11 0.222 0.228 0.122 63.417 113.131 C12 - IsoParaffin - 1 0.001 0.001 0.001 0.286

Aromatics Mono-Aromatics 45.634 71-42-3 Benzene 0.762 0.660 0.839 237.175

69.118 108-88-3 Toluene 16.516 14.511 15.421 5084.878 84.749 100-41-4 Ethylbenzene 2.921 2.566 2.367 892.510 86.000 108-38-3 m-Xylene 7.170 6.320 5.810 2190.845 86.140 106-42-3 p-Xylene 3.429 3.034 2.779 1047.780 88.942 95-47-6 o-Xylene 2.035 1.761 1.649 621.671 93.094 98-82-8 i-Propylbenzene 0.032 0.029 0.023 9.854 96.553 103-65-1 n-Propylbenzene 0.297 0.262 0.212 90.093 97.401 620-14-4 1-Methyl-3-ethylbenzene 1.153 1.016 0.825 349.962 97.635 622-96-8 1-Methyl-4-ethylbenzene 0.536 0.474 0.383 162.579 98.259 108-67-8 1,3,5-Trimethylbenzene 0.678 0.597 0.485 205.829 99.344 611-14-3 1-Methyl-2-ethylbenzene 0.394 0.341 0.282 119.695 100.977 95-63-6 1,2,4-Trimethylbenzene 1.871 1.627 1.339 568.018 102.627 538-93-2 i-Butylbenzene 0.054 0.048 0.034 16.250 103.849 526-73-8 1,2,3-Trimethylbenzene 0.234 0.199 0.167 71.027 104.614 99-87-6 1-Methyl-4-i-propylbenzene 0.039 0.035 0.025 11.844 106.546 141-93-5 1,3-Diethylbenzene 0.028 0.025 0.018 8.585 106.826 1074-43-7 1-Methyl-3-n-propylbenzene 0.365 0.323 0.234 110.217 107.162 105-05-5 1,4-Diethylbenzene 0.140 0.123 0.090 42.193 107.260 104-51-8 n-Butylbenzene 0.024 0.021 0.015 7.124 107.381 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.128 0.111 0.082 38.708 107.627 135-01-3 1,2-Diethylbenzene 0.028 0.024 0.018 8.497 108.232 1074-17-5 1-Methyl-2-n-propylbenzene 0.054 0.047 0.034 16.172 109.078 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.120 0.104 0.077 36.272 109.741 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.328 0.285 0.210 98.972 110.286 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.219 0.188 0.141 66.200 111.195 1-Methyl-4-t-butylbenzene 0.034 0.030 0.020 10.192 111.413 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.133 0.113 0.085 40.093 111.865 4218-48-8 1-Ethyl-4-i-propylbenzene 0.030 0.026 0.018 9.085 112.348 1,2,4,5-Tetramethylbenzene 0.269 0.231 0.172 81.212 112.614 527-53-7 1,2,3,5-Tetramethylbenzene 0.377 0.323 0.242 113.923 113.754 C11 - Aromatic - 3 0.053 0.045 0.031 15.844 114.071 1,2-Di-i-propylbenzene 0.046 0.040 0.025 13.902 114.285 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.066 0.057 0.038 19.852 114.445 C11 - Aromatic - 4 0.035 0.030 0.020 10.503 114.846 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.043 0.037 0.025 13.009 115.258 538-68-1 n-Pentylbenzene 0.017 0.015 0.010 5.102 115.487 tert-Pentylbenzene 0.070 0.060 0.040 20.966 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.030 0.026 0.017 9.011 115.908 C11 - Aromatic - 6 0.040 0.036 0.023 11.982

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 116.368 100-18-5 1,4-Di-i-propylbenzene 0.058 0.050 0.031 17.460

117.241 C12-Aromatic-1 0.017 0.016 0.009 5.222 117.593 7364-19-4 1t-Butyl-4-ethylbenzene 0.009 0.008 0.005 2.825 117.893 1,3-Di-n-propylbenzene 0.043 0.037 0.023 12.830 118.005 C11 - Aromatic - 11 0.024 0.021 0.014 7.124 118.558 C11 - Aromatic - 12 0.015 0.013 0.009 4.427

Naphthalenes 116.810 91-20-3 Naphthalene 0.085 0.063 0.057 26.861

123.439 91-57-6 2-Methylnaphthalene 0.010 0.007 0.006 3.084 124.305 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.565

Naphtheno/Olefino-Benzs

113.945 874-35-1 5-Methylindan 0.109 0.094 0.071 33.009 114.942 824-63-5 2-Methylindan 0.116 0.099 0.076 35.088

Indenes 105.043 Indan 0.076 0.060 0.055 23.343

105.637 Indene 0.239 0.189 0.174 73.690 109.394 2-Methylindan 0.042 0.033 0.028 13.032 114.694 824-22-6 4-Methylindan 0.153 0.131 0.100 46.330 117.413 Dimethyl Indane - 1 0.005 0.004 0.003 1.693

Naphthenes Mono-Naphthenes 27.606 287-92-3 Cyclopentane 0.211 0.216 0.259 61.042

40.675 96-37-7 Methylcyclopentane 1.565 1.592 1.599 452.199 47.553 110-82-7 Cyclohexane 0.932 0.912 0.953 269.515 53.351 1759-58-6 1t,3-Dimethylcyclopentane 0.139 0.142 0.122 40.249 53.937 2532-58-3 1c,3-Dimethylcyclopentane 0.103 0.105 0.090 29.742 54.562 822-50-4 1t,2-Dimethylcyclopentane 0.133 0.135 0.116 38.375 59.649 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.016 5.236 61.513 108-87-2 Methylcyclohexane 0.430 0.425 0.376 124.148 64.295 1640-89-7 Ethylcyclopentane 0.024 0.024 0.021 6.964 73.225 1,3-dimethyl-t-cyclohexane 0.033 0.033 0.025 9.569 76.235 3875-51-2 i-Propylcyclopentane 0.018 0.017 0.013 5.059 76.534 2207-03-6 1t,3-Dimethylcyclohexane 0.014 0.014 0.011 4.150 78.820 C8 - MonoNaph - 3 0.058 0.058 0.045 16.896 82.171 1678-91-7 Ethylcyclohexane 0.021 0.020 0.016 5.986

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.623 115-11-7 Isobutene 0.016 0.020 0.024 4.578

9.665 106-98-9 Butene-1 0.018 0.023 0.027 5.141 10.510 624-64-6 t-Butene-2 0.072 0.091 0.111 20.857 11.251 590-18-1 c-Butene-2 0.085 0.104 0.131 24.611 16.730 109-67-1 Pentene-1 0.328 0.391 0.403 94.912 19.233 646-04-8 t-Pentene-2 0.834 0.980 1.023 241.073 20.262 627-20-3 c-Pentene-2 0.457 0.531 0.561 132.177 33.450 592-41-6 Hexene-1 0.157 0.177 0.161 45.517 36.440 13269-52-8 t-Hexene-3 0.259 0.289 0.265 74.877

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 36.916 4050-45-7 t-Hexene-2 0.395 0.441 0.404 114.209

38.740 7688-21-3 c-Hexene-2 0.211 0.232 0.215 60.847 55.468 592-76-7 Heptene-1 0.029 0.031 0.025 8.271 57.328 14686-14-7 t-Heptene-3 0.031 0.034 0.028 9.103 58.271 7642-10-6 c-Heptene-3 0.025 0.027 0.022 7.113 59.172 14686-13-6 t-Heptene-2 0.014 0.015 0.012 3.949 110.903 693-61-8 2-Undecene, (E)- 0.017 0.017 0.010 4.845

Iso-Olefins 13.450 563-45-1 3-Methylbutene-1 0.173 0.210 0.213 50.077

17.580 563-46-2 2-Methylbutene-1 0.499 0.584 0.612 144.229 20.944 513-35-9 2-Methylbutene-2 1.025 1.179 1.257 296.164 29.193 691-38-3 4-Methyl-c-pentene-2 0.045 0.051 0.046 13.117 29.841 674-76-0 4-Methyl-t-pentene-2 0.129 0.146 0.132 37.315 33.229 763-29-1 2-Methylpentene-1 0.221 0.245 0.226 63.771 37.407 625-27-4 2-Methylpentene-2 0.336 0.370 0.343 97.066 37.818 922-62-3 3-Methyl-c-pentene-2 0.259 0.283 0.265 74.916 40.089 3404-73-7 3,3-Dimethylpentene-1 0.305 0.331 0.267 88.098 42.534 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.014 0.011 3.763 46.638 3404-61-3 3-Methylhexene-1 0.015 0.016 0.013 4.354 47.231 3524-73-0 5-Methylhexene-1 0.054 0.059 0.048 15.678 49.271 15840-60-5 2-Methyl-c-hexene-3 0.040 0.044 0.035 11.538 49.619 3769-23-1 4-Methylhexene-1 0.012 0.013 0.010 3.337 50.261 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.054 0.044 14.467 54.855 C7 - Iso-Olefin - 2 0.022 0.023 0.019 6.381 56.801 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.977 57.683 6094-02-6 2-Methylhexene-1 0.056 0.062 0.049 16.277 58.547 2738-19-4 2-Methyl-2-hexene 0.026 0.027 0.022 7.371 58.790 10574-36-4 3-Methyl-c-hexene-2 0.019 0.021 0.017 5.576 60.074 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.013 4.351 60.859 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.672 86.490 C9-IsoOlefin-3 0.011 0.010 0.007 3.096

Naphtheno-Olefins 22.531 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.009 2.052

25.744 142-29-0 Cyclopentene 0.194 0.191 0.245 57.679 37.036 1120-62-3 3-Methylcyclopentene 0.101 0.101 0.106 29.186 45.833 693-89-0 1-Methylcyclopentene 0.353 0.345 0.370 104.623 51.151 110-83-8 Cyclohexene 0.044 0.041 0.046 12.672

Di-Olefins 18.626 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.011 0.013 3.050

21.268 2004-70-8 1t,3-Pentadiene 0.015 0.017 0.019 4.549 45.426 1528-30-9 C6-Diolefin-1 0.015 0.015 0.015 4.249

Oxygenates 13.062 64-17-5 Ethanol 10.756 10.385 20.087 1280.145

26.900 71-23-8 n-Propanol 0.078 0.074 0.112 15.799 48.056 71-36-3 n-Butanol 0.055 0.052 0.064 11.986

Unidentified 19.880 Unidentified 0.006 0.007 0.007 2.020

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 26.989 Unidentified 0.056 0.064 0.058 19.922

28.732 Unidentified 0.052 0.053 0.051 18.373 50.836 Unidentified 0.039 0.043 0.035 13.977 63.384 Unidentified 0.027 0.029 0.021 9.577 72.449 Unidentified 0.075 0.080 0.057 26.628 84.900 Unidentified 0.020 0.021 0.014 7.125 85.148 Unidentified 0.020 0.019 0.013 6.955 86.597 Unidentified 0.009 0.009 0.006 3.115 88.747 Unidentified 0.119 0.133 0.081 42.266 93.840 Unidentified 0.043 0.045 0.026 15.189 99.113 Unidentified 0.166 0.174 0.100 58.751 100.351 Unidentified 0.013 0.010 0.007 4.764 100.481 Unidentified 0.037 0.037 0.020 12.966 101.163 Unidentified 0.026 0.028 0.016 9.046 101.284 Unidentified 0.015 0.015 0.009 5.207 102.899 Unidentified 0.017 0.015 0.011 6.081 103.197 Unidentified 0.011 0.011 0.006 3.792 108.079 Unidentified 0.025 0.026 0.014 8.864 108.354 Unidentified 0.029 0.030 0.016 10.424 108.435 Unidentified 0.027 0.028 0.015 9.667 108.743 Unidentified 0.072 0.073 0.039 25.407 109.167 Unidentified 0.311 0.270 0.199 110.054 110.709 Unidentified 0.006 0.006 0.004 2.242 111.038 Unidentified 0.022 0.023 0.014 7.882 111.972 Unidentified 0.015 0.013 0.009 5.198 113.484 Unidentified 0.013 0.014 0.007 4.765 115.145 Unidentified 0.012 0.013 0.006 4.426 116.945 Unidentified 0.007 0.008 0.004 2.642 126.297 Unidentified 0.003 0.003 0.001 1.031 130.003 Unidentified 0.003 0.002 0.002 1.044

Plus

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane
Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

i-Propylcyclopentane 1t,3-Dimethylcyclohexane

n-Octane

C8 - MonoNaph - 3

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene C9-IsoOlefin-3 Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane 2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene
1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 6 1,4-Di-i-propylbenzene Naphthalene Unidentified C12-Aromatic-1 Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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24-Aug-10, 22:43:27 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF Sample: ODDB-91323 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91323 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000005.D\SIG2000005_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Summary by Group

Recovery = 100.00 Group %Wgt %Vol %Mol

Paraffin 7.234 8.810 9.515

I-Paraffins 22.271 24.875 21.153

Aromatics 37.108 32.516 33.093

Mono-Aromatics 36.003 31.605 32.266 Naphthalenes 0.165 0.127 0.121 Naphtheno/Olefino-Ben z 0.497 0.427 0.366 Indenes 0.336 0.267 0.277

Naphthenes 21.259 20.874 23.909

Mono-Naphthenes 20.986 20.612 23.717 Di/Bicyclo-Naphthenes 0.083 0.079 0.052

Olefins 7.129 8.023 8.698

n-Olefins 2.777 3.193 3.564 Iso-Olefins 3.420 3.858 4.130 Naphtheno-Olefins 0.267 0.260 0.362 Di-Olefins 0.227 0.242 0.259

Oxygenates 0.116 0.120 0.128

Plus 0.000 0.000 0.000Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 1

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Summary by Carbon

Recovery = 100.00 

### C# %Wgt %Vol %Mol C4 3.876 5.106 6.498 C5 7.910 9.450 10.785 C6 26.058 26.494 30.087 C7 11.034 10.318 11.449 C8 20.377 19.845 18.095 C9 16.174 14.853 12.909 C10 7.142 6.810 5.063 C11 1.997 1.851 1.287 C12 0.513 0.456 0.305 C13 0.034 0.034 0.018Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 1

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Paraffin C4 3.709 4.895 6.211 C5 0.862 1.051 1.162 C6 0.555 0.643 0.627 C7 0.088 0.098 0.085 C8 0.102 0.111 0.087 C9 0.699 0.744 0.530 C10 0.933 0.976 0.638 C11 0.236 0.242 0.147 C12 0.036 0.037 0.021 C13 0.014 0.014 0.007

I-Paraffins C4 0.030 0.041 0.050 C5 3.458 4.266 4.663 C6 3.513 4.076 3.967 C7 1.536 1.730 1.492 C8 8.775 9.559 7.475 C9 2.009 2.136 1.524 C10 2.381 2.480 1.628 C11 0.548 0.566 0.341 C13 0.020 0.020 0.011

Aromatics C12 0.106 0.091 0.063

Mono-Aromatics C6 0.710 0.617 0.885 C7 8.300 7.312 8.766 C8 11.138 9.812 10.210 C9 12.056 10.565 9.761 C10 2.395 2.095 1.736 C11 1.128 0.968 0.743 C12 0.275 0.236 0.165

Naphthalenes C10 0.132 0.103 0.098 C11 0.033 0.025 0.022

Naphtheno/Olefino-BenzsC10 0.497 0.427 0.366

Indenes C10 0.336 0.267 0.277

Naphthenes C8 0.011 0.011 0.010 C9 0.115 0.112 0.089 C10 0.011 0.010 0.007 C11 0.052 0.050 0.033

Mono-Naphthenes C5 0.104 0.106 0.144Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 2

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Mono-Naphthenes C6 19.262 18.921 22.272 C7 0.289 0.293 0.286 C8 0.222 0.219 0.193 C9 0.826 0.804 0.637 C10 0.187 0.175 0.130 C12 0.096 0.092 0.056

Di/Bicyclo-Naphthenes C10 0.083 0.079 0.052

Olefins C4 0.000 0.000 0.000 C6 0.058 0.064 0.067 C7 0.048 0.053 0.048 C8 0.016 0.017 0.016 C9 0.317 0.337 0.252

n-Olefins C4 0.137 0.170 0.237 C5 1.492 1.756 2.070 C6 0.903 1.009 1.044 C7 0.090 0.098 0.090 C8 0.036 0.038 0.031 C9 0.119 0.121 0.092

Iso-Olefins C5 1.626 1.891 2.257 C6 0.961 1.070 1.111 C7 0.614 0.663 0.608 C9 0.032 0.035 0.025 C10 0.187 0.198 0.130

Naphtheno-Olefins C5 0.191 0.189 0.273 C6 0.076 0.071 0.090

Di-Olefins C5 0.062 0.071 0.089 C6 0.020 0.022 0.024 C7 0.068 0.070 0.073 C8 0.076 0.078 0.073

Oxygenates C5 0.116 0.120 0.128Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 1

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 1 8.665 75-28-5 I4 i-Butane 0.030 0.041 0.050 2 9.390 115-11-7 O4 isobutene 0.000 0.000 0.000 3 9.430 106-98-9 K4 Butene-1 0.013 0.017 0.023 4 9.737 106-97-8 P4 n-Butane 3.709 4.895 6.211 5 10.183 624-64-6 K4 t-Butene-2 0.038 0.048 0.065 6 10.265 463-82-1 I5 2,2-Dimethylpropane 0.064 0.083 0.087 7 10.825 590-18-1 K4 c-Butene-2 0.086 0.106 0.149 8 12.802 563-45-1 C5 3-Methylbutene-1 0.078 0.095 0.108 9 14.153 78-78-4 I5 i-Pentane 3.393 4.183 4.576 10 15.639 109-67-1 K5 Pentene-1 0.294 0.351 0.408

11 16.404 563-46-2 C5 2-Methylbutene-1 0.497 0.584 0.690 12 16.870 109-66-0 P5 n-Pentane 0.862 1.051 1.162 13 17.412 78-79-5 E5 2-Methyl-1,3-Butadiene 0.018 0.020 0.026 14 17.907 646-04-8 K5 t-Pentene-2 0.757 0.892 1.050 15 18.484 598-25-4 E5 3-Methylbutadiene-1,2 0.031 0.037 0.044 16 18.852 627-20-3 K5 c-Pentene-2 0.441 0.513 0.611 17 19.472 513-35-9 C5 2-Methylbutene-2 1.051 1.212 1.459 20 21.064 1574-41-0 E5 1c,3-Pentadiene 0.013 0.014 0.019 21 21.415 75-83-2 I6 2,2-Dimethylbutane 0.081 0.095 0.092 22 23.926 142-29-0 B5 Cyclopentene 0.191 0.189 0.273

24 25.084 691-37-2 C6 4-Methylpentene-1 0.085 0.097 0.098 25 25.643 287-92-3 M5 Cyclopentane 0.104 0.106 0.144 26 26.327 79-29-8 I6 2,3-Dimethylbutane 0.885 1.021 0.999 27 26.739 1634-04-4 X5 Methyl-t-butylether 0.116 0.120 0.128 28 27.175 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.052 0.053 29 27.366 107-83-5 I6 2-Methylpentane 1.568 1.834 1.771 30 27.797 674-76-0 C6 4-Methyl-t-pentene-2 0.146 0.166 0.169 31 29.878 96-14-0 I6 3-Methylpentane 0.979 1.126 1.106 32 31.033 763-29-1 C6 2-Methylpentene-1 0.182 0.203 0.211 33 31.253 592-41-6 K6 Hexene-1 0.140 0.158 0.162

35 33.480 110-54-3 P6 n-Hexane 0.555 0.643 0.627 36 34.14913269-52-8 K6 t-Hexene-3 0.203 0.227 0.235 37 34.609 4050-45-7 K6 t-Hexene-2 0.380 0.426 0.440 38 35.080 625-27-4 C6 2-Methylpentene-2 0.277 0.306 0.320 39 35.333 O6 O13 0.058 0.064 0.067 40 35.465 922-62-3 C6 3-Methyl-c-pentene-2 0.225 0.246 0.260 41 36.378 7688-21-3 K6 c-Hexene-2 0.179 0.198 0.207 43 37.682 3404-73-7 C7 3,3-Dimethylpentene-1 0.234 0.255 0.232 45 38.162 96-37-7 M6 Methylcyclopentane 0.616 0.628 0.712 46 38.970 563-79-1 E7 2,3-Dimethyl-2-Butene 0.017 0.018 0.020

48 39.715 108-08-7 I7 2,4-Dimethylpentane 0.605 0.687 0.587 49 40.217 464-06-2 I7 2,2,3-Trimethylbutane 0.063 0.069 0.061 52 41.934 762-63-0 C7 4,4-Dimethyl-c-pentene-2 0.018 0.019 0.018 53 42.875 E6 Diolefin 0.020 0.022 0.024Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 2

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol

54 43.156 71-42-3 Q6 Benzene 0.710 0.617 0.885 55 44.152 C7 2-Methyl-c-hexene-3 0.042 0.046 0.042 56 45.167 110-82-7 M6 Cyclohexane 18.646 18.293 21.560 58 45.604 692-24-0 C7 2-Methyl-t-hexene-3 0.033 0.037 0.033 62 46.682 7357-93-9 C7 2-Ethyl-3-methylbutene-1 0.038 0.041 0.038 63 47.002 3769-23-1 C7 4-Methylhexene-1 0.022 0.024 0.022 66 47.632 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.034 0.037 0.034 67 47.983 591-76-4 I7 2-Methylhexane 0.594 0.668 0.577 69 48.455 110-83-8 B6 Cyclohexene 0.076 0.071 0.090 74 49.779 589-34-4 I7 3-Methylhexane 0.275 0.306 0.267

75 50.579 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.095 0.097 0.094 76 51.157 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.069 0.070 0.068 78 51.768 822-50-4 M7 1t,2-Dimethylcyclopentane 0.037 0.038 0.037 80 52.461 540-84-1 I8 2,2,4-Trimethylpentane 4.369 4.823 3.722 81 52.940 1541-23-7 E7 1,5-Heptadiene 0.051 0.052 0.054 83 54.104 4914-89-0 C7 3-Methyl-c-hexene-3 0.032 0.034 0.032 84 54.58214686-14-7 K7 t-Heptene-3 0.037 0.041 0.037 85 54.904 O7 C7-Olefin2 0.038 0.042 0.038 86 55.289 142-82-5 P7 n-Heptane 0.088 0.098 0.085 87 55.533 7642-10-6 K7 c-Heptene-3 0.032 0.035 0.032

88 55.856 2738-19-4 C7 2-Methyl-2-hexene 0.027 0.029 0.027 89 56.07510574-36-4 C7 3-Methyl-c-hexene-2 0.044 0.047 0.043 90 56.611 816-79-5 C7 3-Ethylpentene-2 0.020 0.022 0.020 91 56.835 C7 1,5-DM-Cyclopentene 0.040 0.042 0.040 92 57.36520710-38-8 C7 3-Methyl-t-hexene-2 0.028 0.030 0.028 94 58.099 6443-92-1 K7 c-Heptene-2 0.021 0.023 0.021 95 58.576 108-87-2 M7 Methylcyclohexane 0.058 0.057 0.057 96 58.978 1192-18-3 M7 1c,2-Dimethylcyclopentane 0.013 0.014 0.013 98 59.535 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.014 0.014 0.012 105 61.384 1640-89-7 M7 Ethylcyclopentane 0.017 0.017 0.017

106 62.004 564-02-3 I8 2,2,3-Trimethylpentane 0.282 0.301 0.240 107 62.305 592-13-2 I8 2,5-Dimethylhexane 0.592 0.652 0.504 108 62.628 589-43-5 I8 2,4-Dimethylhexane 0.547 0.597 0.466 109 63.418 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.014 0.014 0.012 111 63.852 563-16-6 I8 3,3-Dimethylhexane 0.017 0.019 0.015 112 64.156 O7 O38 0.010 0.010 0.010 115 64.995 O8 C8-Olefin2 0.016 0.017 0.016 116 65.708 565-75-3 I8 2,3,4-Trimethylpentane 1.855 1.970 1.580 117 66.486 108-88-3 Q7 Toluene 8.300 7.312 8.766 118 67.750 E8 C8-Diolefin3 0.054 0.056 0.054

119 68.152 584-94-1 I8 2,3-Dimethylhexane 0.779 0.836 0.664 120 69.499 592-27-8 I8 2-Methylheptane 0.083 0.090 0.070 121 69.733 589-53-7 I8 4-Methylheptane 0.082 0.089 0.070 124 70.866 589-81-1 I8 3-Methylheptane 0.169 0.183 0.144Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 3

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 125 71.864 1002-33-1 E8 1,3-Octadiene 0.022 0.022 0.020 128 72.818 3522-94-9 I9 2,2,5-Trimethylhexane 0.772 0.834 0.586 129 73.097 M8 3c-Ethylmethylcyclopentane 0.021 0.021 0.018 130 73.348 M8 3t-Ethylmethylcyclopentane 0.021 0.021 0.019 131 73.604 111-66-0 M8 2t-Ethylmethylcyclopentane 0.017 0.017 0.015 132 73.78314850-23-8 K8 t-Octene-4 0.028 0.030 0.025 133 74.03116747-50-5 M8 1,1-Methylethylcyclopentane 0.038 0.037 0.033 135 74.34116747-26-5 I9 2,2,4-Trimethylhexane 0.018 0.019 0.014 137 74.776 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.012 0.012 0.010 139 75.13019549-89-4 C9 3,3-Dimethylheptene-1 0.015 0.015 0.011

140 75.316 M8 1c,2c,3-Trimethylcyclopentane 0.030 0.029 0.026 141 75.601 111-65-9 P8 n-Octane 0.102 0.111 0.087 142 76.451 O9 C9-Olefin1 0.072 0.077 0.063 143 77.055 O9 C9-Olefin2 0.019 0.020 0.015 146 77.622 7642-04-8 K8 c-Octene-2 0.008 0.008 0.007 148 78.070 921-47-1 I9 2,3,4-Trimethylhexane 0.146 0.151 0.111 152 79.304 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.037 0.035 0.032 154 79.868 1071-26-7 I9 2,2-Dimethylheptane 0.071 0.077 0.054 155 80.13519550-75-6 C9 t-2,2-Dimethylheptene-3 0.017 0.019 0.013 156 80.29616747-25-4 I9 2,2,3-Trimethylhexane 0.075 0.080 0.057

157 80.677 1068-19-5 I9 4,4-Dimethylheptane 0.049 0.052 0.037 158 81.028 1678-91-7 M8 Ethylcyclohexane 0.020 0.019 0.017 159 81.245 1795-27-3 M9 1c,3c,5-Trimethylcyclohexane 0.089 0.088 0.068 160 81.418 4032-86-4 I9 3,3-Dimethylheptane 0.032 0.034 0.024 162 81.926 3074-75-7 I9 2-Methyl-4-ethylhexane 0.026 0.027 0.020 164 82.409 N8 N8 0.011 0.011 0.010 165 82.776 100-41-4 Q8 Ethylbenzene 9.943 8.759 9.114 166 82.993 7667-60-9 M9 1c,2t,4t-Trimethylcyclohexane 0.396 0.388 0.306 168 83.880 108-38-3 Q8 m-Xylene 0.377 0.334 0.346 169 84.052 106-42-3 Q8 p-Xylene 0.476 0.422 0.436

171 84.793 1067-20-5 I9 3,3-Diethylpentane 0.133 0.135 0.101 172 85.212 2216-34-4 I9 4-Methyloctane 0.117 0.124 0.089 173 85.350 3221-61-2 I9 2-Methyloctane 0.188 0.202 0.143 175 86.046 M9 1c,2t,4c-Trimethylcyclohexane 0.066 0.065 0.050 176 86.228 2216-33-3 I9 3-Methyloctane 0.198 0.210 0.150 178 86.897 95-47-6 Q8 o-Xylene 0.341 0.296 0.313 179 87.278 O9 C9-Olefin4 0.226 0.240 0.174 180 87.636 N9 N18 0.045 0.044 0.035 182 88.113 I9 C9-Isoparaffin1 0.184 0.192 0.140 185 89.35620237-46-0 K9 c-Nonene-3 0.036 0.040 0.028

187 89.785 111-84-2 P9 n-Nonane 0.699 0.744 0.530 188 90.189 4926-90-3 M9 1,1-Methylethylcyclohexane 0.130 0.123 0.100 189 90.546 4984-01-4 C10 3,7-Dimethyloctene-1 0.095 0.104 0.066 190 91.144 98-82-8 Q9 i-Propylbenzene 0.100 0.089 0.081Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 4

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 191 91.440 6434-77-1 K9 c-Nonene-2 0.083 0.081 0.064 192 91.741 N9 N26 0.044 0.042 0.034 193 91.854 696-29-7 M9 i-Propylcyclohexane 0.066 0.063 0.051 194 92.08815869-87-1 I10 2,2-Dimethyloctane 0.116 0.122 0.079 195 92.267 N9 N28 0.026 0.025 0.020 196 92.360 4032-94-4 I10 2,4-Dimethyloctane 0.059 0.062 0.040 197 92.777 2051-30-1 I10 2,6-Dimethyloctane 0.065 0.069 0.045 198 92.92215869-89-3 I10 2,5-Dimethyloctane 0.088 0.092 0.060 201 93.403 I10 I12 0.071 0.074 0.048 202 93.526 2040-95-1 M9 n-Butylcyclopentane 0.079 0.077 0.061

203 93.774 N10 N30 0.011 0.010 0.007 204 93.958 4110-44-5 I10 3,3-Dimethyloctane 0.182 0.188 0.125 205 94.091 I10 I14 0.056 0.059 0.039 207 94.625 103-65-1 Q9 n-Propylbenzene 0.586 0.519 0.474 208 94.80752896-90-9 I10 3-Methyl-5-ethylheptane 0.166 0.174 0.113 212 95.517 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.398 2.118 1.941 213 95.733 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.381 1.225 1.118 215 96.365 108-67-8 Q9 1,3,5-Trimethylbenzene 1.504 1.327 1.217 217 96.82515869-85-9 I10 5-Methylnonane 0.172 0.180 0.118 218 97.01617301-94-8 I10 4-Methylnonane 0.268 0.279 0.183

219 97.167 871-83-0 I10 2-Methylnonane 0.199 0.209 0.136 221 97.421 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.893 0.775 0.723 222 97.666 5881-17-4 I10 3-Ethyloctane 0.156 0.161 0.107 223 98.002 5911-04-6 I10 3-Methylnonane 0.355 0.370 0.243 226 98.558 I10 C10-Isoparaffin1 0.071 0.073 0.048 227 98.797 I10 I19 0.084 0.086 0.057 228 99.127 95-63-6 Q9 1,2,4-Trimethylbenzene 4.188 3.652 3.391 229 99.484 I10 I21 0.174 0.180 0.119 230 99.713 I10 C10-Isoparaffin2 0.099 0.103 0.068 232 100.38819781-18-0 C10 2,3-Dimethyloctene-2 0.092 0.095 0.064

234 100.721 135-98-8 Q10 sec-Butylbenzene 0.093 0.082 0.067 235 100.943 124-18-5 P10 n-Decane 0.933 0.976 0.638 236 101.260 I11 I26 0.063 0.066 0.040 237 101.406 I11 C11-Isoparaffin1 0.061 0.063 0.038 238 101.646 N11 N39 0.052 0.050 0.033 240 101.929 526-73-8 Q9 1,2,3-Trimethylbenzene 1.006 0.859 0.815 241 102.363 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.076 0.067 0.055 245 102.734 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.055 0.049 0.040 247 103.104 496-11-7 J10 2,3-Dihydroindene 0.336 0.267 0.277 248 103.375 7058-01-7 M10 sec-Butylcyclohexane 0.187 0.175 0.130

249 103.744 527-84-4 Q10 1-Methyl-2-i-propylbenzene 0.161 0.141 0.117 250 103.87017362-11-3 I11 3-Ethylnonane 0.062 0.063 0.038 255 104.726 141-93-5 Q10 1,3-Diethylbenzene 0.130 0.115 0.094 256 104.963 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.418 0.371 0.303Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 5

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 258 105.376 105-05-5 Q10 1,4-Diethylbenzene 0.147 0.130 0.106 259 105.600 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.325 0.282 0.236 260 105.859 135-01-3 Q10 1,2-Diethylbenzene 0.088 0.076 0.064 262 106.338 493-02-7 D10 t-Decahydronaphthalene 0.083 0.079 0.052 263 106.626 I11 C11-Isoparaffin3 0.183 0.189 0.114 265 106.934 I11 C11-Isoparaffin4 0.094 0.097 0.058 267 107.263 I11 C11-Isoparaffin5 0.085 0.088 0.053 269 107.626 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.181 0.157 0.131 272 108.189 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.342 0.299 0.248 274 108.761 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.202 0.173 0.146

276 109.533 Q11 4M-1tC4Benz 0.040 0.034 0.029 279 109.939 Q11 1-Methyl-4-t-butylbenzene 0.066 0.059 0.043 280 110.112 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.116 0.099 0.084 281 110.462 1120-21-4 P11 n-Undecane 0.236 0.242 0.147 282 110.643 95-93-2 Q10 1,2,4,5-Tetramethylbenzene 0.062 0.054 0.045 285 111.188 Q11 1-Methyl-1-n-butylbenzene 0.266 0.228 0.175 286 111.499 1074-92-6 Q11 1-t-Butyl-2-methylbenzene 0.374 0.321 0.245 294 112.992 Q11 C11-Aromatic1 0.067 0.058 0.044 295 113.130 874-35-1 H10 5-Methylindan 0.121 0.104 0.089 296 113.327 Q11 C11-Aromatic2 0.092 0.079 0.061

297 113.607 Q11 C11-Aromatic3 0.157 0.135 0.103 298 114.011 824-22-6 H10 4-Methylindan 0.191 0.164 0.141 299 114.347 824-63-5 H10 2-Methylindan 0.185 0.159 0.136 302 115.130 M12 1t-M-2-(4-MP)cyclopentane 0.096 0.092 0.056 305 115.513 Q11 1-Methyl-2-n-butylbenzene 0.038 0.033 0.025 306 115.652 100-18-5 Q12 1,4-Di-i-propylbenzene 0.105 0.090 0.063 308 116.284 119-64-2 G10 1,2,3,4-Tetrahydronaphthalene 0.096 0.076 0.071 310 116.785 91-20-3 G10 Naphthalene 0.036 0.027 0.027 313 117.363 Q12 1t-Butyl-4-ethylbenzene 0.046 0.039 0.027 317 118.243 Q12 1,3-Di-n-propylbenzene 0.053 0.046 0.032

318 118.374 A12 A5 0.106 0.091 0.063 319 119.065 112-40-3 P12 n-Dodecane 0.036 0.037 0.021 325 120.531 102-25-0 Q12 1,3,5-Triethylbenzene 0.011 0.010 0.007 329 121.198 877-44-1 Q12 1,2,4-Triethylbenzene 0.027 0.023 0.016 336 122.541 Q12 1-Methyl-4-n-pentylbenzene 0.021 0.018 0.013 342 123.524 1077-16-3 Q12 n-Hexylbenzene 0.012 0.010 0.007 343 123.748 I13 I49 0.020 0.020 0.011 350 124.932 700-12-9 Q11 Pentamethylbenzene 0.028 0.021 0.018 354 125.810 91-57-6 G11 2-Methylnaphthalene 0.020 0.015 0.013 357 126.386 90-12-0 G11 1-Methylnaphthalene 0.013 0.010 0.009

360 126.764 629-50-5 P13 n-Tridecane 0.014 0.014 0.007Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 1

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Paraffin 9.737 106-97-8 n-Butane 3.709 4.895 6.211 16.870 109-66-0 n-Pentane 0.862 1.051 1.162 33.480 110-54-3 n-Hexane 0.555 0.643 0.627 55.289 142-82-5 n-Heptane 0.088 0.098 0.085 75.601 111-65-9 n-Octane 0.102 0.111 0.087 89.785 111-84-2 n-Nonane 0.699 0.744 0.530 100.943 124-18-5 n-Decane 0.933 0.976 0.638 110.462 1120-21-4 n-Undecane 0.236 0.242 0.147 119.065 112-40-3 n-Dodecane 0.036 0.037 0.021 126.764 629-50-5 n-Tridecane 0.014 0.014 0.007

I-Paraffins 8.665 75-28-5 i-Butane 0.030 0.041 0.050 10.265 463-82-1 2,2-Dimethylpropane 0.064 0.083 0.087 14.153 78-78-4 i-Pentane 3.393 4.183 4.576 21.415 75-83-2 2,2-Dimethylbutane 0.081 0.095 0.092 26.327 79-29-8 2,3-Dimethylbutane 0.885 1.021 0.999 27.366 107-83-5 2-Methylpentane 1.568 1.834 1.771 29.878 96-14-0 3-Methylpentane 0.979 1.126 1.106 39.715 108-08-7 2,4-Dimethylpentane 0.605 0.687 0.587 40.217 464-06-2 2,2,3-Trimethylbutane 0.063 0.069 0.061 47.983 591-76-4 2-Methylhexane 0.594 0.668 0.577 49.779 589-34-4 3-Methylhexane 0.275 0.306 0.267 52.461 540-84-1 2,2,4-Trimethylpentane 4.369 4.823 3.722 62.004 564-02-3 2,2,3-Trimethylpentane 0.282 0.301 0.240 62.305 592-13-2 2,5-Dimethylhexane 0.592 0.652 0.504 62.628 589-43-5 2,4-Dimethylhexane 0.547 0.597 0.466 63.852 563-16-6 3,3-Dimethylhexane 0.017 0.019 0.015 65.708 565-75-3 2,3,4-Trimethylpentane 1.855 1.970 1.580 68.152 584-94-1 2,3-Dimethylhexane 0.779 0.836 0.664 69.499 592-27-8 2-Methylheptane 0.083 0.090 0.070 69.733 589-53-7 4-Methylheptane 0.082 0.089 0.070 70.866 589-81-1 3-Methylheptane 0.169 0.183 0.144 72.818 3522-94-9 2,2,5-Trimethylhexane 0.772 0.834 0.586 74.34116747-26-5 2,2,4-Trimethylhexane 0.018 0.019 0.014 78.070 921-47-1 2,3,4-Trimethylhexane 0.146 0.151 0.111 79.868 1071-26-7 2,2-Dimethylheptane 0.071 0.077 0.054 80.29616747-25-4 2,2,3-Trimethylhexane 0.075 0.080 0.057 80.677 1068-19-5 4,4-Dimethylheptane 0.049 0.052 0.037 81.418 4032-86-4 3,3-Dimethylheptane 0.032 0.034 0.024 81.926 3074-75-7 2-Methyl-4-ethylhexane 0.026 0.027 0.020 84.793 1067-20-5 3,3-Diethylpentane 0.133 0.135 0.101 85.212 2216-34-4 4-Methyloctane 0.117 0.124 0.089 85.350 3221-61-2 2-Methyloctane 0.188 0.202 0.143 86.228 2216-33-3 3-Methyloctane 0.198 0.210 0.150 88.113 C9-Isoparaffin1 0.184 0.192 0.140 92.08815869-87-1 2,2-Dimethyloctane 0.116 0.122 0.079 92.360 4032-94-4 2,4-Dimethyloctane 0.059 0.062 0.040 92.777 2051-30-1 2,6-Dimethyloctane 0.065 0.069 0.045Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 2

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol I-Paraffins 92.92215869-89-3 2,5-Dimethyloctane 0.088 0.092 0.060 93.403 I12 0.071 0.074 0.048 93.958 4110-44-5 3,3-Dimethyloctane 0.182 0.188 0.125 94.091 I14 0.056 0.059 0.039 94.80752896-90-9 3-Methyl-5-ethylheptane 0.166 0.174 0.113 96.82515869-85-9 5-Methylnonane 0.172 0.180 0.118 97.01617301-94-8 4-Methylnonane 0.268 0.279 0.183 97.167 871-83-0 2-Methylnonane 0.199 0.209 0.136 97.666 5881-17-4 3-Ethyloctane 0.156 0.161 0.107 98.002 5911-04-6 3-Methylnonane 0.355 0.370 0.243 98.558 C10-Isoparaffin1 0.071 0.073 0.048 98.797 I19 0.084 0.086 0.057 99.484 I21 0.174 0.180 0.119 99.713 C10-Isoparaffin2 0.099 0.103 0.068 101.260 I26 0.063 0.066 0.040 101.406 C11-Isoparaffin1 0.061 0.063 0.038 103.87017362-11-3 3-Ethylnonane 0.062 0.063 0.038 106.626 C11-Isoparaffin3 0.183 0.189 0.114 106.934 C11-Isoparaffin4 0.094 0.097 0.058 107.263 C11-Isoparaffin5 0.085 0.088 0.053 123.748 I49 0.020 0.020 0.011

Aromatics 118.374 A5 0.106 0.091 0.063

Mono-Aromatics 43.156 71-42-3 Benzene 0.710 0.617 0.885 66.486 108-88-3 Toluene 8.300 7.312 8.766 82.776 100-41-4 Ethylbenzene 9.943 8.759 9.114 83.880 108-38-3 m-Xylene 0.377 0.334 0.346 84.052 106-42-3 p-Xylene 0.476 0.422 0.436 86.897 95-47-6 o-Xylene 0.341 0.296 0.313 91.144 98-82-8 i-Propylbenzene 0.100 0.089 0.081 94.625 103-65-1 n-Propylbenzene 0.586 0.519 0.474 95.517 620-14-4 1-Methyl-3-ethylbenzene 2.398 2.118 1.941 95.733 622-96-8 1-Methyl-4-ethylbenzene 1.381 1.225 1.118 96.365 108-67-8 1,3,5-Trimethylbenzene 1.504 1.327 1.217 97.421 611-14-3 1-Methyl-2-ethylbenzene 0.893 0.775 0.723 99.127 95-63-6 1,2,4-Trimethylbenzene 4.188 3.652 3.391 100.721 135-98-8 sec-Butylbenzene 0.093 0.082 0.067 101.929 526-73-8 1,2,3-Trimethylbenzene 1.006 0.859 0.815 102.363 535-77-3 1-Methyl-3-i-propylbenzene 0.076 0.067 0.055 102.734 99-87-6 1-Methyl-4-i-propylbenzene 0.055 0.049 0.040 103.744 527-84-4 1-Methyl-2-i-propylbenzene 0.161 0.141 0.117 104.726 141-93-5 1,3-Diethylbenzene 0.130 0.115 0.094 104.963 1074-43-7 1-Methyl-3-n-propylbenzene 0.418 0.371 0.303 105.376 105-05-5 1,4-Diethylbenzene 0.147 0.130 0.106 105.600 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.325 0.282 0.236 105.859 135-01-3 1,2-Diethylbenzene 0.088 0.076 0.064 107.626 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.181 0.157 0.131Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 3

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Mono-Aromatics 108.189 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.342 0.299 0.248 108.761 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.202 0.173 0.146 109.533 4M-1tC4Benz 0.040 0.034 0.029 109.939 1-Methyl-4-t-butylbenzene 0.066 0.059 0.043 110.112 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.116 0.099 0.084 110.643 95-93-2 1,2,4,5-Tetramethylbenzene 0.062 0.054 0.045 111.188 1-Methyl-1-n-butylbenzene 0.266 0.228 0.175 111.499 1074-92-6 1-t-Butyl-2-methylbenzene 0.374 0.321 0.245 112.992 C11-Aromatic1 0.067 0.058 0.044 113.327 C11-Aromatic2 0.092 0.079 0.061 113.607 C11-Aromatic3 0.157 0.135 0.103 115.513 1-Methyl-2-n-butylbenzene 0.038 0.033 0.025 115.652 100-18-5 1,4-Di-i-propylbenzene 0.105 0.090 0.063 117.363 1t-Butyl-4-ethylbenzene 0.046 0.039 0.027 118.243 1,3-Di-n-propylbenzene 0.053 0.046 0.032 120.531 102-25-0 1,3,5-Triethylbenzene 0.011 0.010 0.007 121.198 877-44-1 1,2,4-Triethylbenzene 0.027 0.023 0.016 122.541 1-Methyl-4-n-pentylbenzene 0.021 0.018 0.013 123.524 1077-16-3 n-Hexylbenzene 0.012 0.010 0.007 124.932 700-12-9 Pentamethylbenzene 0.028 0.021 0.018

Naphthalenes 116.284 119-64-2 1,2,3,4-Tetrahydronaphthalene 0.096 0.076 0.071 116.785 91-20-3 Naphthalene 0.036 0.027 0.027 125.810 91-57-6 2-Methylnaphthalene 0.020 0.015 0.013 126.386 90-12-0 1-Methylnaphthalene 0.013 0.010 0.009

Naphtheno/Olefi n 113.130 874-35-1 5-Methylindan 0.121 0.104 0.089

114.011 824-22-6 4-Methylindan 0.191 0.164 0.141 114.347 824-63-5 2-Methylindan 0.185 0.159 0.136

Indenes 103.104 496-11-7 2,3-Dihydroindene 0.336 0.267 0.277

Naphthenes 82.409 N8 0.011 0.011 0.010 87.636 N18 0.045 0.044 0.035 91.741 N26 0.044 0.042 0.034 92.267 N28 0.026 0.025 0.020 93.774 N30 0.011 0.010 0.007 101.646 N39 0.052 0.050 0.033

Mono-Naphthen e 25.643 287-92-3 Cyclopentane 0.104 0.106 0.144 38.162 96-37-7 Methylcyclopentane 0.616 0.628 0.712 45.167 110-82-7 Cyclohexane 18.646 18.293 21.560 50.579 2532-58-3 1c,3-Dimethylcyclopentane 0.095 0.097 0.094 51.157 1759-58-6 1t,3-Dimethylcyclopentane 0.069 0.070 0.068 51.768 822-50-4 1t,2-Dimethylcyclopentane 0.037 0.038 0.037 58.576 108-87-2 Methylcyclohexane 0.058 0.057 0.057 58.978 1192-18-3 1c,2-Dimethylcyclopentane 0.013 0.014 0.013 59.535 4516-69-2 1,1,3-Trimethylcyclopentane 0.014 0.014 0.012Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 4

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Mono-Naphthen e 61.384 1640-89-7 Ethylcyclopentane 0.017 0.017 0.017 63.418 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.014 0.014 0.012 73.097 3c-Ethylmethylcyclopentane 0.021 0.021 0.018 73.348 3t-Ethylmethylcyclopentane 0.021 0.021 0.019 73.604 111-66-0 2t-Ethylmethylcyclopentane 0.017 0.017 0.015 74.03116747-50-5 1,1-Methylethylcyclopentane 0.038 0.037 0.033 74.776 2207-03-6 1t,3-Dimethylcyclohexane 0.012 0.012 0.010 75.316 1c,2c,3-Trimethylcyclopentane 0.030 0.029 0.026 79.304 2207-01-4 1c,2-Dimethylcyclohexane 0.037 0.035 0.032 81.028 1678-91-7 Ethylcyclohexane 0.020 0.019 0.017 81.245 1795-27-3 1c,3c,5-Trimethylcyclohexane 0.089 0.088 0.068 82.993 7667-60-9 1c,2t,4t-Trimethylcyclohexane 0.396 0.388 0.306 86.046 1c,2t,4c-Trimethylcyclohexane 0.066 0.065 0.050 90.189 4926-90-3 1,1-Methylethylcyclohexane 0.130 0.123 0.100 91.854 696-29-7 i-Propylcyclohexane 0.066 0.063 0.051 93.526 2040-95-1 n-Butylcyclopentane 0.079 0.077 0.061 103.375 7058-01-7 sec-Butylcyclohexane 0.187 0.175 0.130 115.130 1t-M-2-(4-MP)cyclopentane 0.096 0.092 0.056

Di/Bicyclo-Napht h 106.338 493-02-7 t-Decahydronaphthalene 0.083 0.079 0.052

Olefins 9.390 115-11-7 isobutene 0.000 0.000 0.000 35.333 O13 0.058 0.064 0.067 54.904 C7-Olefin2 0.038 0.042 0.038 64.156 O38 0.010 0.010 0.010 64.995 C8-Olefin2 0.016 0.017 0.016 76.451 C9-Olefin1 0.072 0.077 0.063 77.055 C9-Olefin2 0.019 0.020 0.015 87.278 C9-Olefin4 0.226 0.240 0.174

n-Olefins 9.430 106-98-9 Butene-1 0.013 0.017 0.023 10.183 624-64-6 t-Butene-2 0.038 0.048 0.065 10.825 590-18-1 c-Butene-2 0.086 0.106 0.149 15.639 109-67-1 Pentene-1 0.294 0.351 0.408 17.907 646-04-8 t-Pentene-2 0.757 0.892 1.050 18.852 627-20-3 c-Pentene-2 0.441 0.513 0.611 31.253 592-41-6 Hexene-1 0.140 0.158 0.162 34.14913269-52-8 t-Hexene-3 0.203 0.227 0.235 34.609 4050-45-7 t-Hexene-2 0.380 0.426 0.440 36.378 7688-21-3 c-Hexene-2 0.179 0.198 0.207 54.58214686-14-7 t-Heptene-3 0.037 0.041 0.037 55.533 7642-10-6 c-Heptene-3 0.032 0.035 0.032 58.099 6443-92-1 c-Heptene-2 0.021 0.023 0.021 73.78314850-23-8 t-Octene-4 0.028 0.030 0.025 77.622 7642-04-8 c-Octene-2 0.008 0.008 0.007 89.35620237-46-0 c-Nonene-3 0.036 0.040 0.028 91.440 6434-77-1 c-Nonene-2 0.083 0.081 0.064

Iso-Olefins 12.802 563-45-1 3-Methylbutene-1 0.078 0.095 0.108Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 5

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Iso-Olefins 16.404 563-46-2 2-Methylbutene-1 0.497 0.584 0.690 19.472 513-35-9 2-Methylbutene-2 1.051 1.212 1.459 25.084 691-37-2 4-Methylpentene-1 0.085 0.097 0.098 27.175 691-38-3 4-Methyl-c-pentene-2 0.046 0.052 0.053 27.797 674-76-0 4-Methyl-t-pentene-2 0.146 0.166 0.169 31.033 763-29-1 2-Methylpentene-1 0.182 0.203 0.211 35.080 625-27-4 2-Methylpentene-2 0.277 0.306 0.320 35.465 922-62-3 3-Methyl-c-pentene-2 0.225 0.246 0.260 37.682 3404-73-7 3,3-Dimethylpentene-1 0.234 0.255 0.232 41.934 762-63-0 4,4-Dimethyl-c-pentene-2 0.018 0.019 0.018 44.152 2-Methyl-c-hexene-3 0.042 0.046 0.042 45.604 692-24-0 2-Methyl-t-hexene-3 0.033 0.037 0.033 46.682 7357-93-9 2-Ethyl-3-methylbutene-1 0.038 0.041 0.038 47.002 3769-23-1 4-Methylhexene-1 0.022 0.024 0.022 47.632 3404-55-5 4-Methyl-t/c-hexene-2 0.034 0.037 0.034 54.104 4914-89-0 3-Methyl-c-hexene-3 0.032 0.034 0.032 55.856 2738-19-4 2-Methyl-2-hexene 0.027 0.029 0.027 56.07510574-36-4 3-Methyl-c-hexene-2 0.044 0.047 0.043 56.611 816-79-5 3-Ethylpentene-2 0.020 0.022 0.020 56.835 1,5-DM-Cyclopentene 0.040 0.042 0.040 57.36520710-38-8 3-Methyl-t-hexene-2 0.028 0.030 0.028 75.13019549-89-4 3,3-Dimethylheptene-1 0.015 0.015 0.011 80.13519550-75-6 t-2,2-Dimethylheptene-3 0.017 0.019 0.013 90.546 4984-01-4 3,7-Dimethyloctene-1 0.095 0.104 0.066 100.38819781-18-0 2,3-Dimethyloctene-2 0.092 0.095 0.064

Naphtheno-Olefi n 23.926 142-29-0 Cyclopentene 0.191 0.189 0.273 48.455 110-83-8 Cyclohexene 0.076 0.071 0.090

Di-Olefins 17.412 78-79-5 2-Methyl-1,3-Butadiene 0.018 0.020 0.026 18.484 598-25-4 3-Methylbutadiene-1,2 0.031 0.037 0.044 21.064 1574-41-0 1c,3-Pentadiene 0.013 0.014 0.019 38.970 563-79-1 2,3-Dimethyl-2-Butene 0.017 0.018 0.020 42.875 Diolefin 0.020 0.022 0.024 52.940 1541-23-7 1,5-Heptadiene 0.051 0.052 0.054 67.750 C8-Diolefin3 0.054 0.056 0.054 71.864 1002-33-1 1,3-Octadiene 0.022 0.022 0.020

Oxygenates 26.739 1634-04-4 Methyl-t-butylether 0.116 0.120 0.128

PlusHydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 1

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF222.5020.0017.5015.0012.5010.007.505.002.50

i-Butane

isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane c-Butene-2

3-Methylbutene-1

i-Pentane

Pentene-1
2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene t-Pentene-2 3-Methylbutadiene-1,2 c-Pentene-2 2-Methylbutene-2

1c,3-Pentadiene

2,2-Dimethylbutane

Cyclopentene

4-Methylpentene-1Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 2

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF547.5045.0042.5040.0037.5035.0032.5030.0027.50 Cyclopentane 2,3-Dimethylbutane Methyl-t-butylether 4-Methyl-c-pentene-2 2-Methylpentane

4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane

t-Hexene-3

t-Hexene-2 2-Methylpentene-2 O13

3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane
2,3-Dimethyl-2-Butene
2,4-Dimethylpentane 2,2,3-Trimethylbutane

4,4-Dimethyl-c-pentene-2

Diolefin Benzene

2-Methyl-c-hexene-3

Cyclohexane 2-Methyl-t-hexene-3

2-Ethyl-3-methylbutene-1 4-Methylhexene-1 4-Methyl-t/c-hexene-2 2-Methylhexane Cyclohexene

3-MethylhexaneHydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 3

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF772.5070.0067.5065.0062.5060.0057.5055.0052.50 1c,3-Dimethylcyclopentane 1t,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane 1,5-Heptadiene

3-Methyl-c-hexene-3 t-Heptene-3 C7-Olefin2

n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 3-Ethylpentene-2 1,5-DM-Cyclopentene 3-Methyl-t-hexene-2
c-Heptene-2 Methylcyclohexane 1c,2-Dimethylcyclopentane 1,1,3-Trimethylcyclopentane

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane O38

C8-Olefin2
2,3,4-Trimethylpentane

Toluene

C8-Diolefin3 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane

3-Methylheptane

1,3-Octadiene

2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane 2t-Ethylmethylcyclopentane t-Octene-4 1,1-Methylethylcyclopentane 2,2,4-Trimethylhexane 1t,3-DimethylcyclohexaneHydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 4

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF197.5095.0092.5090.0087.5085.0082.5080.0077.50 3

, 3

- Dimethylheptene

- 1 1c,2c,3-Trimethylcyclopentan e n-Octane

C9-Olefin1
C9-Olefin2
c-Octene-2

2,3,4-Trimethylhexane

1c,2-Dimethylcyclohexane 2,2-Dimethylheptane t-2,2-Dimethylheptene-3 2,2,3-Trimethylhexane 4,4-Dimethylheptane Ethylcyclohexane

1c,3c,5-Trimethylcyclohexane 3,3-Dimethylheptane 2-Methyl-4-ethylhexane N8 Ethylbenzene 1c,2t,4t-Trimethylcyclohexane

m-Xylene p-Xylene
3,3-Diethylpentane 4-Methyloctane 2-Methyloctane 1c,2t,4c-Trimethylcyclohexane

3-Methyloctane

o-Xylene C9-Olefin4 N18

C9-Isoparaffin1

c-Nonene-3 n-Nonane 1,1-Methylethylcyclohexane 3,7-Dimethyloctene-1 i-Propylbenzene c-Nonene-2 N26 i-Propylcyclohexane 2,2-Dimethyloctane N28 2,4-Dimethyloctane 2,6-Dimethyloctane 2,5-Dimethyloctane I12 n-Butylcyclopentane N30 3,3-Dimethyloctane I14 n-Propylbenzene 3-Methyl-5-ethylheptane 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane

4-Methylnonane 2-Methylnonane 1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane C10-Isoparaffin1 I19 1,2,4-Trimethylbenzene

I21 C10-Isoparaffin2Hydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 5

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF1122.50120.00117.50115.00112.50110.00107.50105.00102.50 2,3-Dimethyloctene-2 sec-Butylbenzene n-Decane I26 C11-Isoparaffin1 N39 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene 1-Methyl-4-i-propylbenzene 2,3-Dihydroindene sec-Butylcyclohexane 1-Methyl-2-i-propylbenzene 3-Ethylnonane

1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene t-Decahydronaphthalene C11-Isoparaffin3 C11-Isoparaffin4 C11-Isoparaffin5 1,3-Dimethyl-4-ethylbenzene 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

4M-1tC4Benz 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1,2,4,5-Tetramethylbenzene 1-Methyl-1-n-butylbenzene 1-t-Butyl-2-methylbenzene

C11-Aromatic1 5-Methylindan C11-Aromatic2 C11-Aromatic3 4-Methylindan 2-Methylindan
1t-M-2-(4-MP)cyclopentane 1-Methyl-2-n-butylbenzene 1,4-Di-i-propylbenzene 1,2,3,4-Tetrahydronaphthalene Naphthalene 1t-Butyl-4-ethylbenzene

1,3-Di-n-propylbenzene A5

n-Dodecane

1,3,5-Triethylbenzene 1,2,4-Triethylbenzene

1-Methyl-4-n-pentylbenzene

n-Hexylbenzene I49

Pentameth y lbenzen eHydrocarbon Expert V4.0 Fri Apr 11 11:06:22 2008 Page 6

10-Apr-08, 17:29:10 File: C:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-69590 Parameter: C:\HPCHEM\HCE40\ODDB-69590 ODDB-69590



# Sample ChromatogramC:\HPCHEM\2\DATA\4-10-08\004F0401.D\004F0401_ADC1_B.CDF1147.50145.00142.50140.00137.50135.00132.50130.00127.50 2-Methylnaphthalene 1-Methylnaphthalene

n-TridecaneHydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Summary by Group

Recovery = 100.00 Group %Wgt %Vol %Mol

Paraffin 10.240 12.177 11.986

I-Paraffins 20.915 22.900 17.480

Aromatics 31.538 27.621 26.882

Mono-Aromatics 31.231 27.379 26.646 Naphthalenes 0.015 0.011 0.010 Naphtheno/Olefino-Ben z 0.009 0.008 0.006 Indenes 0.283 0.223 0.219

Naphthenes 17.329 16.922 17.717

Mono-Naphthenes 17.222 16.820 17.650 Di/Bicyclo-Naphthenes 0.078 0.075 0.047

Olefins 5.647 6.250 5.779

n-Olefins 4.777 5.347 5.155 Iso-Olefins 0.594 0.616 0.401 Naphtheno-Olefins 0.000 0.000 0.000 Di-Olefins 0.097 0.099 0.085

Oxygenates 7.659 7.383 15.209

Plus 0.000 0.000 0.000Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Summary by Carbon

Recovery = 100.00 

### C# %Wgt %Vol %Mol C2 7.659 7.383 15.209 C4 2.846 3.741 4.479 C5 1.207 1.467 1.532 C6 28.262 29.900 30.538 C7 13.297 12.911 12.764 C8 16.110 15.267 13.559 C9 13.687 12.450 10.262 C10 9.738 9.629 6.402 C11 0.511 0.494 0.302 C12 0.006 0.006 0.003 C13 0.005 0.005 0.002Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Paraffin C4 2.807 3.688 4.418 C5 0.410 0.498 0.520 C6 5.403 6.232 5.735 C7 0.597 0.664 0.545 C8 0.607 0.657 0.486 C9 0.238 0.253 0.170 C10 0.152 0.158 0.098 C11 0.016 0.016 0.009 C12 0.006 0.006 0.003 C13 0.005 0.005 0.002

I-Paraffins C4 0.039 0.053 0.061 C5 0.749 0.920 0.950 C6 4.172 4.814 4.429 C7 3.836 4.308 3.502 C8 4.269 4.632 3.419 C9 1.389 1.472 0.991 C10 5.977 6.233 3.843 C11 0.485 0.470 0.287

Mono-Aromatics C6 0.722 0.625 0.846 C7 7.495 6.575 7.441 C8 10.457 9.206 9.011 C9 9.937 8.670 7.563 C10 2.614 2.298 1.781 C11 0.006 0.005 0.003

Naphthalenes C10 0.011 0.008 0.008 C11 0.004 0.003 0.003

Naphtheno/Olefino-BenzsC10 0.009 0.008 0.006

Indenes C10 0.283 0.223 0.219

Naphthenes C9 0.028 0.028 0.021

Mono-Naphthenes C5 0.048 0.048 0.062 C6 13.284 12.978 14.440 C7 1.346 1.339 1.254 C8 0.615 0.607 0.501 C9 1.850 1.772 1.341 C10 0.079 0.075 0.052

Di/Bicyclo-Naphthenes C10 0.078 0.075 0.047Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 2

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Di/Bicyclo-Naphthenes Olefins C8 0.054 0.056 0.048 C9 0.125 0.132 0.090

n-Olefins C6 4.669 5.238 5.075 C7 0.004 0.005 0.004 C8 0.011 0.012 0.009 C9 0.082 0.082 0.060 C10 0.010 0.011 0.007

Iso-Olefins C6 0.012 0.013 0.013 C7 0.019 0.021 0.018 C9 0.037 0.042 0.027 C10 0.525 0.541 0.343

Di-Olefins C8 0.097 0.099 0.085

Oxygenates C2 7.659 7.383 15.209Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 1 8.732 75-28-5 I4 i-Butane 0.039 0.053 0.061 2 9.790 106-97-8 P4 n-Butane 2.807 3.688 4.418 3 10.322 463-82-1 I5 2,2-Dimethylpropane 0.011 0.014 0.014 4 12.696 64-17-5 X2 Ethanol 7.659 7.383 15.209 5 14.142 78-78-4 I5 i-Pentane 0.738 0.906 0.936 6 16.834 109-66-0 P5 n-Pentane 0.410 0.498 0.520 7 21.364 75-83-2 I6 2,2-Dimethylbutane 0.056 0.065 0.059 8 25.538 287-92-3 M5 Cyclopentane 0.048 0.048 0.062 9 26.218 79-29-8 I6 2,3-Dimethylbutane 0.457 0.526 0.485 10 27.257 107-83-5 I6 2-Methylpentane 1.720 2.003 1.826

11 29.772 96-14-0 I6 3-Methylpentane 1.939 2.220 2.058 12 31.175 592-41-6 K6 Hexene-1 4.669 5.238 5.075 13 33.440 110-54-3 P6 n-Hexane 5.403 6.232 5.735 15 35.315 922-62-3 C6 3-Methyl-c-pentene-2 0.012 0.013 0.013 16 37.505 3404-73-7 C7 3,3-Dimethylpentene-1 0.008 0.009 0.008 17 38.004 590-35-2 I7 2,2-Dimethylpentane 1.608 1.816 1.468 18 39.553 108-08-7 I7 2,4-Dimethylpentane 0.495 0.559 0.452 19 40.073 464-06-2 I7 2,2,3-Trimethylbutane 0.083 0.092 0.076 20 42.853 71-42-3 Q6 Benzene 0.722 0.625 0.846 21 44.937 110-82-7 M6 Cyclohexane 13.284 12.978 14.440

22 45.344 692-24-0 C7 2-Methyl-t-hexene-3 0.006 0.007 0.006 23 47.828 591-76-4 I7 2-Methylhexane 1.120 1.256 1.023 24 49.613 589-34-4 I7 3-Methylhexane 0.529 0.585 0.483 25 50.414 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.099 0.101 0.092 26 50.987 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.088 0.090 0.082 27 51.592 822-50-4 M7 1t,2-Dimethylcyclopentane 0.130 0.131 0.121 29 52.217 540-84-1 I8 2,2,4-Trimethylpentane 1.830 2.012 1.466 30 55.114 142-82-5 P7 n-Heptane 0.597 0.664 0.545 31 55.80410574-36-4 C7 3-Methyl-c-hexene-2 0.005 0.005 0.004 34 57.895 6443-92-1 K7 c-Heptene-2 0.004 0.005 0.004

35 58.417 108-87-2 M7 Methylcyclohexane 1.022 1.010 0.952 36 58.815 1192-18-3 M7 1c,2-Dimethylcyclopentane 0.007 0.007 0.006 37 59.374 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.037 0.038 0.030 38 59.822 590-73-8 I8 2,2-Dimethylhexane 0.033 0.036 0.026 41 61.834 564-02-3 I8 2,2,3-Trimethylpentane 0.115 0.122 0.092 42 62.121 592-13-2 I8 2,5-Dimethylhexane 0.283 0.311 0.227 43 62.444 589-43-5 I8 2,4-Dimethylhexane 0.254 0.276 0.203 45 63.238 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.037 0.037 0.030 46 63.677 563-16-6 I8 3,3-Dimethylhexane 0.025 0.026 0.020 47 64.820 O8 C8-Olefin2 0.031 0.033 0.029

48 65.504 565-75-3 I8 2,3,4-Trimethylpentane 0.717 0.758 0.574 49 66.212 108-88-3 Q7 Toluene 7.495 6.575 7.441 50 67.285 E8 C8-Diolefin3 0.015 0.016 0.014 51 67.614 E8 C8-Diolefin4 0.030 0.031 0.028Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 2

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol

52 67.976 609-26-7 I8 2-Methyl-3-ethylpentane 0.239 0.255 0.191 53 68.289 4259-00-1 M8 1,1,2-Trimethylcyclopentane 0.010 0.010 0.008 54 68.507 O8 C8-Olefin3 0.023 0.024 0.018 55 69.334 592-27-8 I8 2-Methylheptane 0.281 0.306 0.225 56 69.581 589-53-7 I8 4-Methylheptane 0.116 0.125 0.093 58 69.935 583-48-2 I8 3,4-Dimethylhexane 0.012 0.013 0.010 59 70.438 2207-04-7 M8 1t,4-Dimethylcyclohexane 0.224 0.224 0.183 60 70.693 589-81-1 I8 3-Methylheptane 0.227 0.245 0.182 61 70.807 619-99-8 I8 3-Ethylhexane 0.137 0.146 0.110 62 71.709 1002-33-1 E8 1,3-Octadiene 0.052 0.051 0.043

65 72.652 3522-94-9 I9 2,2,5-Trimethylhexane 0.303 0.326 0.216 66 72.950 M8 3c-Ethylmethylcyclopentane 0.018 0.018 0.015 67 73.175 M8 3t-Ethylmethylcyclopentane 0.023 0.023 0.019 68 73.439 111-66-0 M8 2t-Ethylmethylcyclopentane 0.009 0.009 0.007 69 73.62914850-23-8 K8 t-Octene-4 0.006 0.006 0.005 70 73.86216747-50-5 M8 1,1-Methylethylcyclopentane 0.107 0.104 0.087 71 74.10016747-26-5 I9 2,2,4-Trimethylhexane 0.005 0.006 0.004 72 74.85914919-01-8 K8 t-Octene-3 0.005 0.005 0.004 73 75.159 M8 1c,2c,3-Trimethylcyclopentane 0.070 0.068 0.057 74 75.419 111-65-9 P8 n-Octane 0.607 0.657 0.486

76 76.425 3875-51-2 M8 i-Propylcyclopentane 0.005 0.005 0.004 78 77.927 921-47-1 I9 2,3,4-Trimethylhexane 0.053 0.054 0.038 81 79.158 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.045 0.043 0.036 83 79.713 1071-26-7 I9 2,2-Dimethylheptane 0.181 0.194 0.129 84 79.97219550-75-6 C9 t-2,2-Dimethylheptene-3 0.019 0.021 0.014 85 80.15816747-25-4 I9 2,2,3-Trimethylhexane 0.123 0.131 0.088 86 80.535 1068-19-5 I9 4,4-Dimethylheptane 0.091 0.097 0.065 87 80.889 1678-91-7 M8 Ethylcyclohexane 0.031 0.030 0.025 88 81.110 1795-27-3 M9 1c,3c,5-Trimethylcyclohexane 0.112 0.111 0.081 89 81.286 4032-86-4 I9 3,3-Dimethylheptane 0.042 0.044 0.030

91 81.784 3074-75-7 I9 2-Methyl-4-ethylhexane 0.017 0.018 0.012 93 82.441 100-41-4 Q8 Ethylbenzene 1.981 1.738 1.707 95 82.790 7667-60-9 M9 1c,2t,4t-Trimethylcyclohexane 0.061 0.059 0.044 96 83.043 4588-18-5 C9 2-Methyloctene-1 0.014 0.015 0.010 99 83.797 108-38-3 Q8 m-Xylene 5.953 5.239 5.130 100 83.928 106-42-3 Q8 p-Xylene 2.523 2.229 2.174 101 84.247 3074-71-3 I9 2,3-Dimethylheptane 0.032 0.034 0.023 103 84.672 1067-20-5 I9 3,3-Diethylpentane 0.062 0.062 0.044 104 85.094 2216-34-4 I9 4-Methyloctane 0.110 0.116 0.078 105 85.235 3221-61-2 I9 2-Methyloctane 0.142 0.151 0.101

106 85.547 O9 C9-Olefin3 0.038 0.040 0.027 107 85.924 M9 1c,2t,4c-Trimethylcyclohexane 0.040 0.040 0.029 108 86.101 2216-33-3 I9 3-Methyloctane 0.139 0.146 0.099 111 86.698 7094-26-0 M9 1,1,2-Trimethylcyclohexane 1.013 0.963 0.734Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 3

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 113 87.163 O9 C9-Olefin4 0.087 0.092 0.063 114 87.516 N9 N18 0.021 0.020 0.015 116 87.997 I9 C9-Isoparaffin1 0.089 0.092 0.063 118 88.495 3788-32-7 M9 i-Butylcyclopentane 0.012 0.011 0.008 120 88.98320063-92-8 C9 t-7-Methyloctene-3 0.005 0.005 0.003 121 89.23020237-46-0 K9 c-Nonene-3 0.015 0.016 0.011 124 89.654 111-84-2 P9 n-Nonane 0.238 0.253 0.170 125 90.103 6434-78-2 K9 t-Nonene-2 0.048 0.047 0.035 126 90.402 4984-01-4 C10 3,7-Dimethyloctene-1 0.012 0.013 0.008 128 90.925 98-82-8 Q9 i-Propylbenzene 0.050 0.044 0.038

130 91.256 6434-77-1 K9 c-Nonene-2 0.020 0.019 0.014 132 91.743 696-29-7 M9 i-Propylcyclohexane 0.263 0.249 0.191 133 91.96315869-87-1 I10 2,2-Dimethyloctane 0.083 0.088 0.054 134 92.125 N9 N28 0.007 0.007 0.005 135 92.309 4032-94-4 I10 2,4-Dimethyloctane 0.046 0.048 0.029 136 92.637 2051-30-1 I10 2,6-Dimethyloctane 0.064 0.067 0.041 137 92.81015869-89-3 I10 2,5-Dimethyloctane 0.097 0.101 0.063 139 93.402 2040-95-1 M9 n-Butylcyclopentane 0.350 0.339 0.253 140 93.851 4110-44-5 I10 3,3-Dimethyloctane 0.121 0.125 0.078 142 94.431 103-65-1 Q9 n-Propylbenzene 0.480 0.423 0.365

143 94.70352896-90-9 I10 3-Methyl-5-ethylheptane 0.014 0.014 0.009 146 95.347 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.983 1.745 1.509 147 95.564 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.972 0.859 0.740 150 96.203 108-67-8 Q9 1,3,5-Trimethylbenzene 1.271 1.117 0.967 154 97.160 871-83-0 I10 2-Methylnonane 4.358 4.563 2.802 155 97.254 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.637 0.550 0.485 157 97.902 5911-04-6 I10 3-Methylnonane 0.046 0.047 0.029 161 98.477 I10 C10-Isoparaffin1 0.786 0.808 0.506 162 98.712 I10 I19 0.361 0.371 0.232 163 98.990 95-63-6 Q9 1,2,4-Trimethylbenzene 3.751 3.257 2.855

168 99.833 872-05-9 K10 Decene-1 0.010 0.011 0.007 169 100.156 M10 1t-Methyl-2-n-propylcyclohexanR 0.040 0.038 0.026 170 100.29619781-18-0 C10 2,3-Dimethyloctene-2 0.513 0.528 0.335 171 100.526 135-98-8 Q10 sec-Butylbenzene 0.226 0.199 0.154 173 100.823 124-18-5 P10 n-Decane 0.152 0.158 0.098 175 101.284 I11 C11-Isoparaffin1 0.047 0.049 0.028 177 101.771 526-73-8 Q9 1,2,3-Trimethylbenzene 0.793 0.675 0.604 179 102.177 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.070 0.062 0.048 181 102.560 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.312 0.276 0.212 182 102.915 496-11-7 J10 2,3-Dihydroindene 0.283 0.223 0.219

184 103.275 7058-01-7 M10 sec-Butylcyclohexane 0.039 0.036 0.025 190 104.390 I11 C11-Isoparaffin2 0.370 0.352 0.220 191 104.537 141-93-5 Q10 1,3-Diethylbenzene 0.095 0.083 0.065 192 104.866 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.097 0.969 0.747Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 4

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 194 105.161 105-05-5 Q10 1,4-Diethylbenzene 0.261 0.230 0.178 195 105.441 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.114 0.098 0.078 196 105.719 135-01-3 Q10 1,2-Diethylbenzene 0.078 0.068 0.053 198 106.219 493-02-7 D10 t-Decahydronaphthalene 0.078 0.075 0.047 199 106.316 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.018 0.015 0.012 200 106.508 I11 C11-Isoparaffin3 0.067 0.069 0.039 204 107.264 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.018 0.016 0.013 205 107.419 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.177 0.153 0.120 207 107.987 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.029 0.025 0.020 209 108.652 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.098 0.083 0.067

213 109.649 Q11 1-Methyl-4-t-butylbenzene 0.006 0.005 0.003 214 109.835 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.014 0.012 0.010 215 110.337 1120-21-4 P11 n-Undecane 0.016 0.016 0.009 216 110.486 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.007 0.006 0.005 219 112.903 874-35-1 H10 5-Methylindan 0.009 0.008 0.006 221 116.685 91-20-3 G10 Naphthalene 0.011 0.008 0.008 223 118.896 112-40-3 P12 n-Dodecane 0.006 0.006 0.003 224 126.247 90-12-0 G11 1-Methylnaphthalene 0.004 0.003 0.003 225 126.686 629-50-5 P13 n-Tridecane 0.005 0.005 0.002Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Paraffin 9.790 106-97-8 n-Butane 2.807 3.688 4.418 16.834 109-66-0 n-Pentane 0.410 0.498 0.520 33.440 110-54-3 n-Hexane 5.403 6.232 5.735 55.114 142-82-5 n-Heptane 0.597 0.664 0.545 75.419 111-65-9 n-Octane 0.607 0.657 0.486 89.654 111-84-2 n-Nonane 0.238 0.253 0.170 100.823 124-18-5 n-Decane 0.152 0.158 0.098 110.337 1120-21-4 n-Undecane 0.016 0.016 0.009 118.896 112-40-3 n-Dodecane 0.006 0.006 0.003 126.686 629-50-5 n-Tridecane 0.005 0.005 0.002

I-Paraffins 8.732 75-28-5 i-Butane 0.039 0.053 0.061 10.322 463-82-1 2,2-Dimethylpropane 0.011 0.014 0.014 14.142 78-78-4 i-Pentane 0.738 0.906 0.936 21.364 75-83-2 2,2-Dimethylbutane 0.056 0.065 0.059 26.218 79-29-8 2,3-Dimethylbutane 0.457 0.526 0.485 27.257 107-83-5 2-Methylpentane 1.720 2.003 1.826 29.772 96-14-0 3-Methylpentane 1.939 2.220 2.058 38.004 590-35-2 2,2-Dimethylpentane 1.608 1.816 1.468 39.553 108-08-7 2,4-Dimethylpentane 0.495 0.559 0.452 40.073 464-06-2 2,2,3-Trimethylbutane 0.083 0.092 0.076 47.828 591-76-4 2-Methylhexane 1.120 1.256 1.023 49.613 589-34-4 3-Methylhexane 0.529 0.585 0.483 52.217 540-84-1 2,2,4-Trimethylpentane 1.830 2.012 1.466 59.822 590-73-8 2,2-Dimethylhexane 0.033 0.036 0.026 61.834 564-02-3 2,2,3-Trimethylpentane 0.115 0.122 0.092 62.121 592-13-2 2,5-Dimethylhexane 0.283 0.311 0.227 62.444 589-43-5 2,4-Dimethylhexane 0.254 0.276 0.203 63.677 563-16-6 3,3-Dimethylhexane 0.025 0.026 0.020 65.504 565-75-3 2,3,4-Trimethylpentane 0.717 0.758 0.574 67.976 609-26-7 2-Methyl-3-ethylpentane 0.239 0.255 0.191 69.334 592-27-8 2-Methylheptane 0.281 0.306 0.225 69.581 589-53-7 4-Methylheptane 0.116 0.125 0.093 69.935 583-48-2 3,4-Dimethylhexane 0.012 0.013 0.010 70.693 589-81-1 3-Methylheptane 0.227 0.245 0.182 70.807 619-99-8 3-Ethylhexane 0.137 0.146 0.110 72.652 3522-94-9 2,2,5-Trimethylhexane 0.303 0.326 0.216 74.10016747-26-5 2,2,4-Trimethylhexane 0.005 0.006 0.004 77.927 921-47-1 2,3,4-Trimethylhexane 0.053 0.054 0.038 79.713 1071-26-7 2,2-Dimethylheptane 0.181 0.194 0.129 80.15816747-25-4 2,2,3-Trimethylhexane 0.123 0.131 0.088 80.535 1068-19-5 4,4-Dimethylheptane 0.091 0.097 0.065 81.286 4032-86-4 3,3-Dimethylheptane 0.042 0.044 0.030 81.784 3074-75-7 2-Methyl-4-ethylhexane 0.017 0.018 0.012 84.247 3074-71-3 2,3-Dimethylheptane 0.032 0.034 0.023 84.672 1067-20-5 3,3-Diethylpentane 0.062 0.062 0.044 85.094 2216-34-4 4-Methyloctane 0.110 0.116 0.078 85.235 3221-61-2 2-Methyloctane 0.142 0.151 0.101Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 2

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol I-Paraffins 86.101 2216-33-3 3-Methyloctane 0.139 0.146 0.099 87.997 C9-Isoparaffin1 0.089 0.092 0.063 91.96315869-87-1 2,2-Dimethyloctane 0.083 0.088 0.054 92.309 4032-94-4 2,4-Dimethyloctane 0.046 0.048 0.029 92.637 2051-30-1 2,6-Dimethyloctane 0.064 0.067 0.041 92.81015869-89-3 2,5-Dimethyloctane 0.097 0.101 0.063 93.851 4110-44-5 3,3-Dimethyloctane 0.121 0.125 0.078 94.70352896-90-9 3-Methyl-5-ethylheptane 0.014 0.014 0.009 97.160 871-83-0 2-Methylnonane 4.358 4.563 2.802 97.902 5911-04-6 3-Methylnonane 0.046 0.047 0.029 98.477 C10-Isoparaffin1 0.786 0.808 0.506 98.712 I19 0.361 0.371 0.232 101.284 C11-Isoparaffin1 0.047 0.049 0.028 104.390 C11-Isoparaffin2 0.370 0.352 0.220 106.508 C11-Isoparaffin3 0.067 0.069 0.039

Aromatics

Mono-Aromatics 42.853 71-42-3 Benzene 0.722 0.625 0.846 66.212 108-88-3 Toluene 7.495 6.575 7.441 82.441 100-41-4 Ethylbenzene 1.981 1.738 1.707 83.797 108-38-3 m-Xylene 5.953 5.239 5.130 83.928 106-42-3 p-Xylene 2.523 2.229 2.174 90.925 98-82-8 i-Propylbenzene 0.050 0.044 0.038 94.431 103-65-1 n-Propylbenzene 0.480 0.423 0.365 95.347 620-14-4 1-Methyl-3-ethylbenzene 1.983 1.745 1.509 95.564 622-96-8 1-Methyl-4-ethylbenzene 0.972 0.859 0.740 96.203 108-67-8 1,3,5-Trimethylbenzene 1.271 1.117 0.967 97.254 611-14-3 1-Methyl-2-ethylbenzene 0.637 0.550 0.485 98.990 95-63-6 1,2,4-Trimethylbenzene 3.751 3.257 2.855 100.526 135-98-8 sec-Butylbenzene 0.226 0.199 0.154 101.771 526-73-8 1,2,3-Trimethylbenzene 0.793 0.675 0.604 102.177 535-77-3 1-Methyl-3-i-propylbenzene 0.070 0.062 0.048 102.560 99-87-6 1-Methyl-4-i-propylbenzene 0.312 0.276 0.212 104.537 141-93-5 1,3-Diethylbenzene 0.095 0.083 0.065 104.866 1074-43-7 1-Methyl-3-n-propylbenzene 1.097 0.969 0.747 105.161 105-05-5 1,4-Diethylbenzene 0.261 0.230 0.178 105.441 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.114 0.098 0.078 105.719 135-01-3 1,2-Diethylbenzene 0.078 0.068 0.053 106.316 1074-17-5 1-Methyl-2-n-propylbenzene 0.018 0.015 0.012 107.264 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.018 0.016 0.013 107.419 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.177 0.153 0.120 107.987 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.029 0.025 0.020 108.652 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.098 0.083 0.067 109.649 1-Methyl-4-t-butylbenzene 0.006 0.005 0.003 109.835 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.014 0.012 0.010 110.486 527-53-7 1,2,3,5-Tetramethylbenzene 0.007 0.006 0.005

Naphthalenes 116.685 91-20-3 Naphthalene 0.011 0.008 0.008Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 3

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Naphthalenes 126.247 90-12-0 1-Methylnaphthalene 0.004 0.003 0.003

Naphtheno/Olefi n 112.903 874-35-1 5-Methylindan 0.009 0.008 0.006

Indenes 102.915 496-11-7 2,3-Dihydroindene 0.283 0.223 0.219

Naphthenes 87.516 N18 0.021 0.020 0.015 92.125 N28 0.007 0.007 0.005

Mono-Naphthen e 25.538 287-92-3 Cyclopentane 0.048 0.048 0.062 44.937 110-82-7 Cyclohexane 13.284 12.978 14.440 50.414 2532-58-3 1c,3-Dimethylcyclopentane 0.099 0.101 0.092 50.987 1759-58-6 1t,3-Dimethylcyclopentane 0.088 0.090 0.082 51.592 822-50-4 1t,2-Dimethylcyclopentane 0.130 0.131 0.121 58.417 108-87-2 Methylcyclohexane 1.022 1.010 0.952 58.815 1192-18-3 1c,2-Dimethylcyclopentane 0.007 0.007 0.006 59.374 4516-69-2 1,1,3-Trimethylcyclopentane 0.037 0.038 0.030 63.238 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.037 0.037 0.030 68.289 4259-00-1 1,1,2-Trimethylcyclopentane 0.010 0.010 0.008 70.438 2207-04-7 1t,4-Dimethylcyclohexane 0.224 0.224 0.183 72.950 3c-Ethylmethylcyclopentane 0.018 0.018 0.015 73.175 3t-Ethylmethylcyclopentane 0.023 0.023 0.019 73.439 111-66-0 2t-Ethylmethylcyclopentane 0.009 0.009 0.007 73.86216747-50-5 1,1-Methylethylcyclopentane 0.107 0.104 0.087 75.159 1c,2c,3-Trimethylcyclopentane 0.070 0.068 0.057 76.425 3875-51-2 i-Propylcyclopentane 0.005 0.005 0.004 79.158 2207-01-4 1c,2-Dimethylcyclohexane 0.045 0.043 0.036 80.889 1678-91-7 Ethylcyclohexane 0.031 0.030 0.025 81.110 1795-27-3 1c,3c,5-Trimethylcyclohexane 0.112 0.111 0.081 82.790 7667-60-9 1c,2t,4t-Trimethylcyclohexane 0.061 0.059 0.044 85.924 1c,2t,4c-Trimethylcyclohexane 0.040 0.040 0.029 86.698 7094-26-0 1,1,2-Trimethylcyclohexane 1.013 0.963 0.734 88.495 3788-32-7 i-Butylcyclopentane 0.012 0.011 0.008 91.743 696-29-7 i-Propylcyclohexane 0.263 0.249 0.191 93.402 2040-95-1 n-Butylcyclopentane 0.350 0.339 0.253 100.156 1t-Methyl-2-n-propylcyclohexanR 0.040 0.038 0.026 103.275 7058-01-7 sec-Butylcyclohexane 0.039 0.036 0.025

Di/Bicyclo-Napht h 106.219 493-02-7 t-Decahydronaphthalene 0.078 0.075 0.047

Olefins 64.820 C8-Olefin2 0.031 0.033 0.029 68.507 C8-Olefin3 0.023 0.024 0.018 85.547 C9-Olefin3 0.038 0.040 0.027 87.163 C9-Olefin4 0.087 0.092 0.063

n-Olefins 31.175 592-41-6 Hexene-1 4.669 5.238 5.075 57.895 6443-92-1 c-Heptene-2 0.004 0.005 0.004 73.62914850-23-8 t-Octene-4 0.006 0.006 0.005Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 4

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

n-Olefins 74.85914919-01-8 t-Octene-3 0.005 0.005 0.004 89.23020237-46-0 c-Nonene-3 0.015 0.016 0.011 90.103 6434-78-2 t-Nonene-2 0.048 0.047 0.035 91.256 6434-77-1 c-Nonene-2 0.020 0.019 0.014 99.833 872-05-9 Decene-1 0.010 0.011 0.007

Iso-Olefins 35.315 922-62-3 3-Methyl-c-pentene-2 0.012 0.013 0.013 37.505 3404-73-7 3,3-Dimethylpentene-1 0.008 0.009 0.008 45.344 692-24-0 2-Methyl-t-hexene-3 0.006 0.007 0.006 55.80410574-36-4 3-Methyl-c-hexene-2 0.005 0.005 0.004 79.97219550-75-6 t-2,2-Dimethylheptene-3 0.019 0.021 0.014 83.043 4588-18-5 2-Methyloctene-1 0.014 0.015 0.010 88.98320063-92-8 t-7-Methyloctene-3 0.005 0.005 0.003 90.402 4984-01-4 3,7-Dimethyloctene-1 0.012 0.013 0.008 100.29619781-18-0 2,3-Dimethyloctene-2 0.513 0.528 0.335

Naphtheno-Olefi n Di-Olefins 67.285 C8-Diolefin3 0.015 0.016 0.014 67.614 C8-Diolefin4 0.030 0.031 0.028 71.709 1002-33-1 1,3-Octadiene 0.052 0.051 0.043

Oxygenates 12.696 64-17-5 Ethanol 7.659 7.383 15.209

PlusHydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 1

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF222.5020.0017.5015.0012.5010.007.505.002.50

i-Butane

n-Butane 2,2-Dimethylpropane

Ethanol

i-Pentane

n-Pentane

2,2-DimethylbutaneHydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 2

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF547.5045.0042.5040.0037.5035.0032.5030.0027.50 Cyclopentane 2,3-Dimethylbutane

2-Methylpentane

3-Methylpentane

Hexene-1

n-Hexane

3-Methyl-c-pentene-2

3,3-Dimethylpentene-1 2,2-Dimethylpentane

2,4-Dimethylpentane 2,2,3-Trimethylbutane

Benzene

Cyclohexane 2-Methyl-t-hexene-3

2-Methylhexane

3-MethylhexaneHydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 3

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF772.5070.0067.5065.0062.5060.0057.5055.0052.50 1c,3-Dimethylcyclopentane 1t,3-Dimethylcyclopentane

1t,2-Dimethylcyclopentane 2,2,4-Trimethylpentane

n-Heptane 3-Methyl-c-hexene-2

c-Heptene-2 Methylcyclohexane 1c,2-Dimethylcyclopentane 1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane

2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

C8-Olefin2 2,3,4-Trimethylpentane

Toluene

C8-Diolefin3 C8-Diolefin4 2-Methyl-3-ethylpentane 1,1,2-Trimethylcyclopentane C8-Olefin3

2-Methylheptane 4-Methylheptane 3,4-Dimethylhexane 1t,4-Dimethylcyclohexane 3-Methylheptane 3-Ethylhexane

1,3-Octadiene

2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane 2t-Ethylmethylcyclopentane t-Octene-4 1,1-Methylethylcyclopentane 2,2,4-Trimethylhexane

t-Octene-3Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 4

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF197.5095.0092.5090.0087.5085.0082.5080.0077.50 1c

, 2c

, 3

- Trimethylcyclopentane n-Octane

i-Propylcyclopentane

2,3,4-Trimethylhexane

1c,2-Dimethylcyclohexane 2,2-Dimethylheptane t-2,2-Dimethylheptene-3 2,2,3-Trimethylhexane 4,4-Dimethylheptane Ethylcyclohexane 1c,3c,5-Trimethylcyclohexane 3,3-Dimethylheptane 2-Methyl-4-ethylhexane Ethylbenzene

1c,2t,4t-Trimethylcyclohexane 2-Methyloctene-1
m-Xylene p-Xylene 2,3-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane

2-Methyloctane C9-Olefin3 1c,2t,4c-Trimethylcyclohexane 3-Methyloctane 1,1,2-Trimethylcyclohexane C9-Olefin4 N18

C9-Isoparaffin1 i-Butylcyclopentane t-7-Methyloctene-3 c-Nonene-3 n-Nonane t-Nonene-2 3,7-Dimethyloctene-1

i-Propylbenzene c-Nonene-2 i-Propylcyclohexane 2,2-Dimethyloctane N28 2,4-Dimethyloctane

2,6-Dimethyloctane 2,5-Dimethyloctane n-Butylcyclopentane 3,3-Dimethyloctane n-Propylbenzene 3-Methyl-5-ethylheptane 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene

2-Methylnonane 1-Methyl-2-ethylbenzene 3-Methylnonane C10-Isoparaffin1 I19 1,2,4-Trimethylbenzene

Decene-1Hydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 5

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF1122.50120.00117.50115.00112.50110.00107.50105.00102.50 1t

- Methyl

- 2

- n

- propylcyclohexanR 2,3-Dimethyloctene-2 sec-Butylbenzene n-Decane C11-Isoparaffin1 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene 1-Methyl-4-i-propylbenzene 2,3-Dihydroindene sec-Butylcyclohexane

C11-Isoparaffin2 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene t-Decahydronaphthalene 1-Methyl-2-n-propylbenzene C11-Isoparaffin3
1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1,2,3,5-Tetramethylbenzene

5-Methylindan

Naphthalene

n-DodecaneHydrocarbon Expert V4.0 Tue Jul 01 17:21:08 2008 Page 6

29-Jun-08, 15:09:16 File: C:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF Operator: RAS Sample: ODDB-71719 Parameter: C:\HPCHEM\HCE40\ODDB-71719 ODDB-71719 R.



# Sample ChromatogramC:\HPCHEM\2\DATA\6-29-08\002F0201.D\002F0201_ADC1_B.CDF1147.50145.00142.50140.00137.50135.00132.50130.00127.50 1-Methylnaphthalene n-TridecaneHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Summary by Group

Recovery = 100.00 Group %Wgt %Vol %Mol

Paraffin 10.977 12.565 11.015

I-Paraffins 26.015 28.917 23.032

Aromatics 31.773 27.542 26.225

Mono-Aromatics 31.210 27.099 25.816 Naphthalenes 0.064 0.049 0.042 Naphtheno/Olefino-Ben z 0.043 0.036 0.029 Indenes 0.445 0.348 0.332

Naphthenes 8.725 8.554 7.671

Mono-Naphthenes 8.396 8.239 7.456 Di/Bicyclo-Naphthenes 0.067 0.063 0.038

Olefins 4.083 4.450 3.905

n-Olefins 3.101 3.420 3.145 Iso-Olefins 0.459 0.494 0.332 Naphtheno-Olefins 0.007 0.007 0.009 Di-Olefins 0.214 0.215 0.182

Oxygenates 12.087 11.560 23.113

Unidentified 6.341 6.413 5.040

Plus 0.000 0.000 0.000Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Summary by Carbon

Recovery = 100.00 

### C# %Wgt %Vol %Mol C2 12.079 11.551 23.104 C4 2.693 3.513 4.082 C5 7.949 9.638 9.715 C6 8.971 9.665 9.360 C7 16.083 15.338 14.872 C8 20.364 19.816 16.301 C9 17.077 15.882 12.245 C10 7.022 6.779 4.479 C11 1.293 1.283 0.734 C12 0.120 0.112 0.063 C13 0.010 0.010 0.005Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Paraffin C4 2.633 3.433 3.992 C5 0.981 1.182 1.199 C6 1.306 1.495 1.336 C7 1.606 1.772 1.412 C8 1.672 1.796 1.290 C9 1.267 1.332 0.870 C10 1.202 1.243 0.745 C11 0.260 0.263 0.146 C12 0.042 0.042 0.022 C13 0.007 0.007 0.003

I-Paraffins C4 0.057 0.077 0.086 C5 6.771 8.247 8.270 C6 2.167 2.486 2.216 C7 2.375 2.634 2.089 C8 7.343 7.898 5.664 C9 3.493 3.674 2.400 C10 2.887 2.977 1.788 C11 0.892 0.897 0.504 C12 0.026 0.026 0.013 C13 0.003 0.003 0.001

Aromatics C12 0.011 0.009 0.006

Mono-Aromatics C6 0.656 0.563 0.740 C7 8.665 7.541 8.287 C8 9.279 8.082 7.702 C9 10.671 9.233 7.824 C10 1.821 1.580 1.196 C11 0.079 0.068 0.047 C12 0.037 0.032 0.020

Naphthalenes C10 0.051 0.039 0.035 C11 0.013 0.009 0.008

Naphtheno/Olefino-BenzsC10 0.043 0.036 0.029

Indenes C10 0.445 0.348 0.332

Naphthenes C8 0.005 0.004 0.004 C9 0.202 0.195 0.141 C10 0.006 0.006 0.004 C11 0.049 0.046 0.028

Mono-Naphthenes C5 0.122 0.123 0.153Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 2

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Composite by Carbon

Recovery = 100.00 

### Group C# %Wgt %Vol %Mol Mono-Naphthenes C6 2.081 2.050 2.179 C7 3.390 3.342 3.042 C8 1.677 1.641 1.317 C9 0.825 0.800 0.576 C10 0.298 0.279 0.187 C12 0.003 0.003 0.002

Di/Bicyclo-Naphthenes C10 0.067 0.063 0.038

Olefins C6 0.001 0.001 0.001 C7 0.011 0.012 0.010 C8 0.131 0.135 0.113 C9 0.159 0.166 0.114

n-Olefins C4 0.001 0.001 0.002 C5 0.035 0.040 0.044 C6 2.732 3.041 2.861 C7 0.009 0.010 0.008 C8 0.055 0.057 0.043 C9 0.260 0.260 0.181 C10 0.010 0.010 0.006

Iso-Olefins C5 0.022 0.025 0.027 C6 0.022 0.024 0.023 C7 0.025 0.027 0.023 C9 0.200 0.221 0.140 C10 0.190 0.197 0.120

Naphtheno-Olefins C5 0.004 0.004 0.005 C6 0.003 0.003 0.003

Di-Olefins C5 0.009 0.010 0.012 C6 0.001 0.001 0.001 C7 0.001 0.001 0.001 C8 0.203 0.203 0.169

Oxygenates C2 12.079 11.551 23.104 C4 0.002 0.002 0.002 C5 0.005 0.005 0.005 C6 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 1 7.612 ? Unidentified 0.002 0.003 0.004 2 8.696 75-28-5 I4 i-Butane 0.057 0.077 0.086 3 9.740 106-97-8 P4 n-Butane 2.633 3.433 3.992 4 10.159 624-64-6 K4 t-Butene-2 0.001 0.001 0.001 5 10.276 463-82-1 I5 2,2-Dimethylpropane 0.015 0.020 0.019 6 10.798 590-18-1 K4 c-Butene-2 0.001 0.001 0.001 7 12.708 64-17-5 X2 Ethanol 12.079 11.551 23.104 8 14.140 78-78-4 I5 i-Pentane 6.756 8.227 8.251 9 14.734 ? Unidentified 0.004 0.005 0.007 10 14.814 ? Unidentified 0.002 0.002 0.003

11 14.853 ? Unidentified 0.003 0.004 0.004 12 14.910 ? Unidentified 0.016 0.019 0.020 13 15.238 ? Unidentified 0.001 0.001 0.001 14 15.258 ? Unidentified 0.001 0.002 0.002 15 15.286 ? Unidentified 0.007 0.009 0.009 16 15.546 109-67-1 K5 Pentene-1 0.019 0.022 0.024 17 15.818 ? Unidentified 0.002 0.002 0.003 18 15.878 ? Unidentified 0.004 0.004 0.006 19 15.989 ? Unidentified 0.001 0.001 0.001 20 16.008 ? Unidentified 0.004 0.003 0.005

21 16.115 ? Unidentified 0.001 0.001 0.002 22 16.144 ? Unidentified 0.001 0.001 0.002 23 16.185 ? Unidentified 0.001 0.001 0.001 24 16.301 563-46-2 C5 2-Methylbutene-1 0.012 0.014 0.015 25 16.482 ? Unidentified 0.001 0.002 0.002 26 16.524 ? Unidentified 0.004 0.004 0.005 27 16.754 109-66-0 P5 n-Pentane 0.981 1.182 1.199 28 17.219 78-79-5 E5 2-Methyl-1,3-Butadiene 0.004 0.005 0.005 29 17.318 ? Unidentified 0.001 0.001 0.001 30 17.351 ? Unidentified 0.002 0.002 0.003

31 17.452 ? Unidentified 0.002 0.002 0.002 32 17.503 ? Unidentified 0.001 0.001 0.001 33 17.537 ? Unidentified 0.000 0.001 0.001 34 17.562 ? Unidentified 0.001 0.001 0.001 35 17.589 ? Unidentified 0.001 0.002 0.002 36 17.635 ? Unidentified 0.001 0.001 0.001 37 17.768 646-04-8 K5 t-Pentene-2 0.009 0.010 0.011 38 17.907 ? Unidentified 0.001 0.002 0.002 39 17.968 ? Unidentified 0.002 0.002 0.002 40 18.037 ? Unidentified 0.001 0.001 0.001

41 18.064 ? Unidentified 0.002 0.002 0.003 42 18.190 ? Unidentified 0.002 0.002 0.002 43 18.235 ? Unidentified 0.001 0.001 0.001 44 18.257 ? Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 2

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol

45 18.313 ? Unidentified 0.001 0.001 0.001 46 18.333 ? Unidentified 0.001 0.001 0.001 47 18.397 598-25-4 E5 3-Methylbutadiene-1,2 0.002 0.002 0.002 48 18.463 ? Unidentified 0.001 0.001 0.002 49 18.494 ? Unidentified 0.001 0.001 0.001 50 18.538 ? Unidentified 0.001 0.001 0.001 51 18.578 ? Unidentified 0.001 0.001 0.001 52 18.703 627-20-3 K5 c-Pentene-2 0.007 0.008 0.009 53 18.850 ? Unidentified 0.001 0.001 0.001 54 18.950 ? Unidentified 0.004 0.003 0.004

55 19.063 ? Unidentified 0.001 0.001 0.001 56 19.102 ? Unidentified 0.001 0.001 0.001 57 19.147 75-65-0 X4 t-Butanol 0.001 0.001 0.001 58 19.186 ? Unidentified 0.001 0.001 0.001 59 19.312 513-35-9 C5 2-Methylbutene-2 0.010 0.011 0.012 60 19.480 ? Unidentified 0.001 0.002 0.002 61 19.561 ? Unidentified 0.001 0.001 0.001 62 19.630 2004-70-8 E5 1t,3-Pentadiene 0.002 0.003 0.003 63 19.685 ? Unidentified 0.001 0.001 0.001 64 19.743 ? Unidentified 0.002 0.002 0.002

65 19.795 ? Unidentified 0.001 0.001 0.001 66 19.830 ? Unidentified 0.000 0.000 0.001 67 19.893 ? Unidentified 0.001 0.001 0.002 68 19.939 ? Unidentified 0.001 0.001 0.001 69 19.975 ? Unidentified 0.001 0.001 0.001 70 20.078 ? Unidentified 0.003 0.003 0.003 71 20.161 ? Unidentified 0.001 0.001 0.001 72 20.230 ? Unidentified 0.001 0.001 0.001 73 20.283 ? Unidentified 0.001 0.001 0.001 74 20.307 ? Unidentified 0.000 0.001 0.001

75 20.341 ? Unidentified 0.001 0.001 0.001 76 20.398 ? Unidentified 0.001 0.001 0.001 77 20.564 ? Unidentified 0.003 0.004 0.004 78 20.647 ? Unidentified 0.001 0.001 0.001 79 20.756 ? Unidentified 0.003 0.003 0.004 80 20.855 1574-41-0 E5 1c,3-Pentadiene 0.001 0.001 0.001 81 20.922 ? Unidentified 0.001 0.001 0.001 82 20.947 ? Unidentified 0.000 0.001 0.001 83 21.020 ? Unidentified 0.001 0.001 0.001 84 21.062 ? Unidentified 0.001 0.001 0.001

85 21.092 ? Unidentified 0.001 0.001 0.001 86 21.256 75-83-2 I6 2,2-Dimethylbutane 0.130 0.152 0.133 87 21.447 ? Unidentified 0.002 0.002 0.002 88 21.559 ? Unidentified 0.002 0.002 0.002Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 3

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol

89 21.694 ? Unidentified 0.001 0.001 0.001 90 21.722 ? Unidentified 0.000 0.001 0.000 91 21.750 ? Unidentified 0.001 0.001 0.001 92 21.837 ? Unidentified 0.001 0.001 0.001 93 21.867 ? Unidentified 0.001 0.001 0.001 94 21.981 ? Unidentified 0.001 0.002 0.002 95 22.004 ? Unidentified 0.001 0.001 0.001 96 22.082 ? Unidentified 0.001 0.001 0.001 97 22.122 ? Unidentified 0.000 0.000 0.000 98 22.186 ? Unidentified 0.002 0.002 0.002

99 22.281 ? Unidentified 0.001 0.001 0.001 100 22.330 ? Unidentified 0.001 0.001 0.001 101 22.440 ? Unidentified 0.001 0.001 0.001 102 22.541 ? Unidentified 0.001 0.001 0.002 103 22.592 ? Unidentified 0.001 0.001 0.001 104 22.664 ? Unidentified 0.001 0.001 0.002 105 22.698 ? Unidentified 0.000 0.000 0.001 106 22.784 ? Unidentified 0.001 0.001 0.002 107 22.825 ? Unidentified 0.000 0.000 0.001 108 22.866 ? Unidentified 0.000 0.000 0.001

109 22.931 ? Unidentified 0.001 0.001 0.002 110 23.035 ? Unidentified 0.001 0.001 0.001 111 23.107 ? Unidentified 0.000 0.000 0.001 112 23.160 ? Unidentified 0.001 0.001 0.001 113 23.203 ? Unidentified 0.001 0.001 0.001 114 23.304 ? Unidentified 0.002 0.002 0.002 115 23.412 ? Unidentified 0.000 0.000 0.001 116 23.468 ? Unidentified 0.002 0.002 0.002 117 23.566 ? Unidentified 0.001 0.001 0.001 118 23.704 142-29-0 B5 Cyclopentene 0.004 0.004 0.005

119 23.871 ? Unidentified 0.002 0.002 0.002 120 24.010 ? Unidentified 0.001 0.001 0.001 121 24.040 ? Unidentified 0.001 0.001 0.001 122 24.118 ? Unidentified 0.001 0.001 0.001 123 24.165 ? Unidentified 0.001 0.001 0.001 124 24.205 ? Unidentified 0.001 0.001 0.001 125 24.299 ? Unidentified 0.001 0.001 0.001 126 24.327 ? Unidentified 0.001 0.001 0.001 127 24.428 ? Unidentified 0.001 0.001 0.001 128 24.509 ? Unidentified 0.000 0.001 0.001

129 24.577 ? Unidentified 0.001 0.001 0.001 130 24.608 ? Unidentified 0.001 0.001 0.001 131 24.794 ? Unidentified 0.001 0.002 0.002 132 24.896 691-37-2 C6 4-Methylpentene-1 0.004 0.005 0.004Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 4

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 133 25.015 ? Unidentified 0.001 0.001 0.001 134 25.133 ? Unidentified 0.001 0.001 0.002 135 25.161 ? Unidentified 0.001 0.001 0.001 136 25.193 ? Unidentified 0.000 0.000 0.001 137 25.244 ? Unidentified 0.001 0.001 0.001 138 25.419 287-92-3 M5 Cyclopentane 0.122 0.123 0.153 139 25.626 ? Unidentified 0.001 0.001 0.001 140 25.696 ? Unidentified 0.001 0.001 0.001 141 25.728 ? Unidentified 0.001 0.001 0.001 142 25.782 ? Unidentified 0.001 0.001 0.001

143 25.853 ? Unidentified 0.000 0.001 0.000 144 26.106 79-29-8 I6 2,3-Dimethylbutane 0.483 0.550 0.494 145 26.351 ? Unidentified 0.002 0.002 0.002 146 26.524 1634-04-4 X5 Methyl-t-butylether 0.005 0.005 0.005 147 26.653 ? Unidentified 0.001 0.001 0.001 148 26.735 ? Unidentified 0.001 0.001 0.001 149 26.798 ? Unidentified 0.001 0.001 0.001 150 26.819 ? Unidentified 0.001 0.001 0.001 151 26.870 691-38-3 C6 4-Methyl-c-pentene-2 0.001 0.001 0.001 152 27.126 107-83-5 I6 2-Methylpentane 0.960 1.110 0.982

153 27.558 674-76-0 C6 4-Methyl-t-pentene-2 0.004 0.004 0.004 154 27.702 ? Unidentified 0.000 0.000 0.000 155 27.727 ? Unidentified 0.000 0.000 0.000 156 27.753 ? Unidentified 0.000 0.000 0.000 157 27.839 ? Unidentified 0.001 0.001 0.001 158 27.908 ? Unidentified 0.001 0.001 0.001 159 28.007 ? Unidentified 0.000 0.000 0.000 160 28.062 ? Unidentified 0.001 0.001 0.001 161 28.141 ? Unidentified 0.000 0.001 0.000 162 28.229 ? Unidentified 0.000 0.001 0.000

163 28.332 ? Unidentified 0.000 0.000 0.000 164 28.358 ? Unidentified 0.001 0.001 0.001 165 28.502 ? Unidentified 0.001 0.002 0.001 166 28.558 ? Unidentified 0.000 0.001 0.000 167 28.619 ? Unidentified 0.000 0.000 0.000 168 28.652 ? Unidentified 0.001 0.001 0.001 169 28.729 ? Unidentified 0.000 0.001 0.000 170 28.784 ? Unidentified 0.000 0.001 0.000 171 28.812 ? Unidentified 0.000 0.000 0.000 172 28.896 ? Unidentified 0.001 0.002 0.001

173 29.124 ? Unidentified 0.001 0.001 0.001 174 29.155 ? Unidentified 0.000 0.001 0.000 175 29.252 ? Unidentified 0.000 0.000 0.000 176 29.307 ? Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 5

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 177 29.371 ? Unidentified 0.001 0.001 0.001 178 29.626 96-14-0 I6 3-Methylpentane 0.594 0.675 0.607 179 29.945 ? Unidentified 0.000 0.001 0.000 180 30.037 ? Unidentified 0.000 0.000 0.000 181 30.064 ? Unidentified 0.000 0.000 0.000 182 30.127 ? Unidentified 0.001 0.001 0.001 183 30.207 ? Unidentified 0.001 0.001 0.001 184 30.389 ? Unidentified 0.001 0.001 0.001 185 30.594 ? Unidentified 0.000 0.000 0.000 186 31.005 592-41-6 K6 Hexene-1 2.717 3.024 2.845

187 31.678 ? Unidentified 0.001 0.001 0.001 188 31.721 ? Unidentified 0.001 0.001 0.001 189 31.795 ? Unidentified 0.002 0.002 0.002 190 31.939 ? Unidentified 0.001 0.001 0.001 191 32.053 ? Unidentified 0.001 0.001 0.001 192 32.072 ? Unidentified 0.000 0.000 0.001 193 32.174 ? Unidentified 0.001 0.001 0.001 194 32.211 ? Unidentified 0.001 0.001 0.001 195 32.321 ? Unidentified 0.000 0.000 0.001 196 32.349 ? Unidentified 0.001 0.001 0.001

197 32.463 ? Unidentified 0.000 0.000 0.001 198 32.544 ? Unidentified 0.000 0.000 0.001 199 32.601 ? Unidentified 0.001 0.000 0.001 200 32.693 ? Unidentified 0.000 0.000 0.000 201 32.747 ? Unidentified 0.001 0.001 0.001 202 32.832 ? Unidentified 0.001 0.001 0.001 203 32.880 ? Unidentified 0.000 0.001 0.000 204 32.921 ? Unidentified 0.000 0.000 0.000 205 33.228 110-54-3 P6 n-Hexane 1.306 1.495 1.336 206 33.634 ? Unidentified 0.001 0.002 0.001

207 33.85613269-52-8 K6 t-Hexene-3 0.005 0.006 0.005 208 34.045 ? Unidentified 0.000 0.000 0.000 209 34.072 ? Unidentified 0.000 0.001 0.000 210 34.121 ? Unidentified 0.000 0.000 0.000 211 34.319 4050-45-7 K6 t-Hexene-2 0.007 0.007 0.007 212 34.523 ? Unidentified 0.001 0.001 0.001 213 34.792 625-27-4 C6 2-Methylpentene-2 0.004 0.004 0.004 214 34.935 ? Unidentified 0.001 0.001 0.001 215 35.183 922-62-3 C6 3-Methyl-c-pentene-2 0.010 0.011 0.010 216 35.395 ? Unidentified 0.000 0.000 0.000

217 35.441 ? Unidentified 0.001 0.001 0.001 218 35.554 ? Unidentified 0.001 0.001 0.001 219 35.605 ? Unidentified 0.000 0.001 0.001 220 35.759 O6 O14 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 6

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 221 35.881 ? Unidentified 0.000 0.000 0.000 222 36.080 7688-21-3 K6 c-Hexene-2 0.004 0.004 0.004 223 36.248 ? Unidentified 0.001 0.001 0.001 224 36.512 ? Unidentified 0.000 0.000 0.000 225 36.589 ? Unidentified 0.001 0.001 0.001 226 36.677 ? Unidentified 0.001 0.001 0.001 227 36.811 ? Unidentified 0.000 0.000 0.000 228 37.098 ? Unidentified 0.001 0.001 0.001 229 37.130 ? Unidentified 0.000 0.001 0.000 230 37.188 ? Unidentified 0.000 0.000 0.000

231 37.372 3404-73-7 C7 3,3-Dimethylpentene-1 0.007 0.007 0.006 232 37.861 96-37-7 M6 Methylcyclopentane 0.869 0.875 0.909 233 38.223 ? Unidentified 0.000 0.000 0.001 234 38.383 ? Unidentified 0.001 0.001 0.001 235 38.580 ? Unidentified 0.001 0.001 0.001 236 38.633 ? Unidentified 0.000 0.001 0.001 237 38.685 563-79-1 E7 2,3-Dimethyl-2-Butene 0.001 0.001 0.001 238 38.812 ? Unidentified 0.000 0.000 0.000 239 38.871 ? Unidentified 0.000 0.000 0.000 240 39.033 ? Unidentified 0.001 0.001 0.001

241 39.091 ? Unidentified 0.001 0.001 0.001 242 39.171 ? Unidentified 0.001 0.001 0.001 243 39.411 108-08-7 I7 2,4-Dimethylpentane 0.399 0.448 0.351 244 39.680 594-56-9 C7 2,3,3-Trimethylbutene-1 0.001 0.001 0.001 245 39.932 464-06-2 I7 2,2,3-Trimethylbutane 0.052 0.057 0.046 246 40.226 ? Unidentified 0.001 0.001 0.001 247 40.416 ? Unidentified 0.000 0.000 0.000 248 40.569 ? Unidentified 0.001 0.001 0.001 249 40.640 7385-78-6 C7 3,4-Dimethylpentene-1 0.001 0.001 0.000 250 40.708 ? Unidentified 0.000 0.000 0.000

251 40.824 ? Unidentified 0.000 0.001 0.000 252 40.860 ? Unidentified 0.000 0.000 0.000 253 41.012 ? Unidentified 0.001 0.001 0.001 254 41.068 ? Unidentified 0.001 0.002 0.001 255 41.384 ? Unidentified 0.001 0.001 0.001 256 41.476 ? Unidentified 0.001 0.001 0.000 257 41.586 762-63-0 C7 4,4-Dimethyl-c-pentene-2 0.001 0.001 0.001 258 41.710 ? Unidentified 0.001 0.001 0.001 259 41.895 ? Unidentified 0.001 0.001 0.000 260 41.985 ? Unidentified 0.001 0.001 0.001

261 42.090 ? Unidentified 0.001 0.001 0.000 262 42.251 ? Unidentified 0.001 0.001 0.001 263 42.502 E6 Diolefin 0.001 0.001 0.001 264 42.702 71-42-3 Q6 Benzene 0.656 0.563 0.740Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 7

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 265 43.291 ? Unidentified 0.001 0.001 0.001 266 43.380 ? Unidentified 0.001 0.001 0.000 267 43.481 ? Unidentified 0.001 0.001 0.001 268 43.693 ? Unidentified 0.000 0.000 0.000 269 43.765 C7 2-Methyl-c-hexene-3 0.001 0.001 0.001 270 43.848 ? Unidentified 0.001 0.001 0.000 271 44.271 562-49-2 I7 3,3-Dimethylpentane 0.064 0.069 0.056 272 44.537 110-82-7 M6 Cyclohexane 1.212 1.175 1.269 273 45.121 692-24-0 C7 2-Methyl-t-hexene-3 0.003 0.003 0.002 274 45.278 ? Unidentified 0.001 0.001 0.001

275 45.410 ? Unidentified 0.000 0.000 0.000 276 45.599 71-36-3 X4 n-Butanol 0.001 0.001 0.001 277 45.814 ? Unidentified 0.001 0.001 0.001 278 45.950 ? Unidentified 0.000 0.000 0.001 279 46.054 ? Unidentified 0.001 0.001 0.001 280 46.305 7357-93-9 C7 2-Ethyl-3-methylbutene-1 0.001 0.001 0.001 281 46.670 3769-23-1 C7 4-Methylhexene-1 0.001 0.001 0.001 282 46.824 ? Unidentified 0.001 0.001 0.001 283 47.295 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.002 0.002 0.001 284 47.659 591-76-4 I7 2-Methylhexane 1.191 1.325 1.048

285 48.071 110-83-8 B6 Cyclohexene 0.003 0.003 0.003 286 48.278 ? Unidentified 0.000 0.000 0.001 287 48.344 ? Unidentified 0.001 0.001 0.001 288 48.517 994-05-8 X6 TAME 0.001 0.001 0.001 289 48.799 ? Unidentified 0.001 0.001 0.001 290 48.889 ? Unidentified 0.000 0.000 0.000 291 49.024 ? Unidentified 0.001 0.001 0.001 292 49.135 ? Unidentified 0.001 0.001 0.000 293 49.450 589-34-4 I7 3-Methylhexane 0.669 0.734 0.588 294 49.925 ? Unidentified 0.001 0.001 0.001

295 50.241 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.180 0.183 0.162 296 50.596 ? Unidentified 0.001 0.001 0.001 297 50.810 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.168 0.170 0.151 298 51.100 C7 2-Ethylpentene-1 0.001 0.001 0.001 299 51.163 ? Unidentified 0.001 0.001 0.001 300 51.414 822-50-4 M7 1t,2-Dimethylcyclopentane 0.270 0.271 0.242 301 51.611 ? Unidentified 0.041 0.041 0.037 302 52.072 540-84-1 I8 2,2,4-Trimethylpentane 2.604 2.840 2.009 303 53.029 ? Unidentified 0.001 0.001 0.001 304 53.088 ? Unidentified 0.001 0.001 0.001

305 53.164 ? Unidentified 0.001 0.001 0.000 306 53.234 ? Unidentified 0.001 0.001 0.001 307 53.348 ? Unidentified 0.000 0.001 0.000 308 53.394 ? Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 8

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 309 53.596 ? Unidentified 0.000 0.000 0.000 310 53.725 4914-89-0 C7 3-Methyl-c-hexene-3 0.002 0.002 0.002 311 53.959 ? Unidentified 0.001 0.001 0.001 312 54.189 ? Unidentified 0.002 0.002 0.002 313 54.22414686-14-7 K7 t-Heptene-3 0.001 0.001 0.001 314 54.359 ? Unidentified 0.001 0.001 0.001 315 54.527 ? Unidentified 0.002 0.002 0.002 316 54.627 O7 C7-Olefin2 0.002 0.003 0.002 317 54.975 142-82-5 P7 n-Heptane 1.606 1.772 1.412 318 55.412 ? Unidentified 0.001 0.001 0.001

319 55.475 2738-19-4 C7 2-Methyl-2-hexene 0.004 0.005 0.004 320 55.618 ? Unidentified 0.005 0.005 0.004 321 55.974 ? Unidentified 0.001 0.001 0.001 322 56.031 ? Unidentified 0.001 0.001 0.000 323 56.09814686-13-6 K7 t-Heptene-2 0.003 0.003 0.002 324 56.242 816-79-5 C7 3-Ethylpentene-2 0.002 0.002 0.001 325 56.743 ? Unidentified 2.386 2.504 2.141 326 57.363 ? Unidentified 0.007 0.007 0.006 327 57.595 ? Unidentified 0.001 0.001 0.000 328 57.729 6443-92-1 K7 c-Heptene-2 0.006 0.006 0.005

329 58.291 108-87-2 M7 Methylcyclohexane 2.757 2.704 2.474 330 58.636 1192-18-3 M7 1c,2-Dimethylcyclopentane 0.015 0.015 0.013 331 59.192 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.093 0.094 0.073 332 59.647 590-73-8 I8 2,2-Dimethylhexane 0.082 0.089 0.063 333 59.889 ? Unidentified 0.001 0.001 0.001 334 60.031 ? Unidentified 0.005 0.004 0.003 335 60.174 ? Unidentified 0.001 0.001 0.001 336 60.239 ? Unidentified 0.001 0.002 0.001 337 60.317 ? Unidentified 0.001 0.002 0.001 338 60.387 O7 O35 0.002 0.002 0.002

339 60.521 ? Unidentified 0.003 0.003 0.002 340 60.867 ? Unidentified 0.747 0.769 0.670 341 61.657 564-02-3 I8 2,2,3-Trimethylpentane 0.164 0.173 0.126 342 61.953 592-13-2 I8 2,5-Dimethylhexane 0.445 0.484 0.343 343 62.274 589-43-5 I8 2,4-Dimethylhexane 0.437 0.471 0.337 344 62.520 ? Unidentified 0.010 0.010 0.009 345 63.059 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.099 0.098 0.078 346 63.492 563-16-6 I8 3,3-Dimethylhexane 0.070 0.074 0.054 347 63.811 O7 O38 0.007 0.007 0.006 348 63.980 ? Unidentified 0.002 0.002 0.002

349 64.208 ? Unidentified 0.004 0.004 0.003 350 64.362 ? Unidentified 0.004 0.004 0.003 351 64.635 O8 C8-Olefin2 0.090 0.093 0.081 352 65.327 565-75-3 I8 2,3,4-Trimethylpentane 1.019 1.070 0.786Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 9

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 353 66.046 108-88-3 Q7 Toluene 8.665 7.541 8.287 354 67.115 ? Unidentified 0.019 0.019 0.017 355 67.435 E8 C8-Diolefin4 0.067 0.069 0.060 356 67.812 584-94-1 I8 2,3-Dimethylhexane 0.419 0.443 0.323 357 68.350 O8 C8-Olefin3 0.041 0.042 0.032 358 69.195 592-27-8 I8 2-Methylheptane 0.749 0.810 0.578 359 69.436 589-53-7 I8 4-Methylheptane 0.347 0.371 0.268 360 69.769 583-48-2 I8 3,4-Dimethylhexane 0.027 0.028 0.021 361 70.289 638-04-0 M8 1c,3-Dimethylcyclohexane 0.610 0.604 0.479 362 70.549 589-81-1 I8 3-Methylheptane 0.635 0.679 0.490

363 70.655 619-99-8 I8 3-Ethylhexane 0.346 0.366 0.267 364 71.233 M8 1c,2t,3-Trimethylcyclopentane 0.005 0.005 0.004 365 71.547 1002-33-1 E8 1,3-Octadiene 0.136 0.134 0.108 366 71.724 ? Unidentified 0.016 0.016 0.013 367 71.988 ? Unidentified 0.007 0.007 0.005 368 72.504 3522-94-9 I9 2,2,5-Trimethylhexane 0.437 0.467 0.301 369 72.795 M8 3c-Ethylmethylcyclopentane 0.047 0.046 0.037 370 73.020 M8 3t-Ethylmethylcyclopentane 0.061 0.060 0.048 371 73.285 111-66-0 M8 2t-Ethylmethylcyclopentane 0.022 0.022 0.017 372 73.47614850-23-8 K8 t-Octene-4 0.012 0.013 0.010

373 73.70916747-50-5 M8 1,1-Methylethylcyclopentane 0.311 0.300 0.244 374 74.360 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.005 0.005 0.004 375 74.70614919-01-8 K8 t-Octene-3 0.015 0.016 0.012 376 75.004 M8 1c,2c,3-Trimethylcyclopentane 0.196 0.190 0.154 377 75.307 111-65-9 P8 n-Octane 1.672 1.796 1.290 378 75.91213389-42-9 K8 t-Octene-2 0.005 0.005 0.004 379 76.160 O9 C9-Olefin1 0.032 0.033 0.025 380 76.279 ? Unidentified 0.014 0.015 0.010 381 76.552 O9 C9-Olefin2 0.012 0.012 0.008 382 76.884 ? Unidentified 0.009 0.010 0.006

383 77.222 7642-04-8 K8 c-Octene-2 0.023 0.024 0.018 384 77.482 ? Unidentified 0.003 0.003 0.002 385 77.581 ? Unidentified 0.003 0.003 0.002 386 77.787 C9 2,3,3-Trimethylhexene-1 0.092 0.102 0.065 387 78.115 N8 N3 0.005 0.004 0.004 388 78.392 ? Unidentified 0.070 0.073 0.048 389 78.713 ? Unidentified 0.060 0.062 0.041 390 79.022 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.132 0.125 0.103 391 79.221 ? Unidentified 0.018 0.018 0.015 392 79.575 1071-26-7 I9 2,2-Dimethylheptane 0.532 0.565 0.365

393 79.83519550-75-6 C9 t-2,2-Dimethylheptene-3 0.062 0.069 0.044 394 80.02316747-25-4 I9 2,2,3-Trimethylhexane 0.354 0.374 0.243 395 80.393 1068-19-5 I9 4,4-Dimethylheptane 0.289 0.304 0.198 396 80.745 1678-91-7 M8 Ethylcyclohexane 0.096 0.092 0.075Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 10

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 397 80.975 1795-27-3 M9 1c,3c,5-Trimethylcyclohexane 0.317 0.311 0.222 398 81.148 4032-86-4 I9 3,3-Dimethylheptane 0.132 0.137 0.091 399 81.408 ? Unidentified 0.046 0.051 0.032 400 81.647 3074-75-7 I9 2-Methyl-4-ethylhexane 0.062 0.065 0.043 401 81.990 ? Unidentified 0.014 0.013 0.010 402 82.282 100-41-4 Q8 Ethylbenzene 1.440 1.253 1.195 403 82.435 ? Unidentified 0.038 0.036 0.026 404 82.644 7667-60-9 M9 1c,2t,4t-Trimethylcyclohexane 0.188 0.182 0.131 405 82.897 4588-18-5 C9 2-Methyloctene-1 0.032 0.036 0.022 406 83.210 ? Unidentified 0.054 0.060 0.038

407 83.617 108-38-3 Q8 m-Xylene 4.534 3.958 3.763 408 83.749 106-42-3 Q8 p-Xylene 1.903 1.668 1.580 409 83.862 ? Unidentified 0.173 0.151 0.143 410 84.110 3074-71-3 I9 2,3-Dimethylheptane 0.059 0.062 0.041 411 84.230 ? Unidentified 0.099 0.103 0.068 412 84.538 1067-20-5 I9 3,3-Diethylpentane 0.132 0.132 0.091 413 84.971 2216-34-4 I9 4-Methyloctane 0.354 0.371 0.243 414 85.115 3221-61-2 I9 2-Methyloctane 0.467 0.494 0.321 415 85.395 N9 N15 0.075 0.073 0.053 416 85.791 M9 1c,2t,4c-Trimethylcyclohexane 0.124 0.121 0.087

417 85.981 2216-33-3 I9 3-Methyloctane 0.485 0.508 0.333 418 86.194 ? Unidentified 0.011 0.012 0.008 419 86.388 ? Unidentified 0.072 0.074 0.049 420 86.573 95-47-6 Q8 o-Xylene 1.403 1.202 1.164 421 86.779 ? Unidentified 0.040 0.038 0.028 422 87.033 O9 C9-Olefin4 0.115 0.121 0.081 423 87.385 N9 N18 0.054 0.052 0.038 424 87.527 ? Unidentified 0.161 0.156 0.112 425 87.831 I9 C9-Isoparaffin1 0.189 0.196 0.130 426 88.174 124-11-8 K9 Nonene-1 0.022 0.024 0.015

427 88.361 ? Unidentified 0.024 0.024 0.017 428 88.536 ? Unidentified 0.018 0.018 0.013 429 88.85820063-92-8 C9 t-7-Methyloctene-3 0.013 0.015 0.009 430 89.09220237-46-0 K9 c-Nonene-3 0.041 0.046 0.029 431 89.269 ? Unidentified 0.007 0.007 0.005 432 89.557 111-84-2 P9 n-Nonane 1.267 1.332 0.870 433 89.923 6434-78-2 K9 t-Nonene-2 0.120 0.116 0.084 434 90.280 4984-01-4 C10 3,7-Dimethyloctene-1 0.059 0.064 0.037 435 90.479 ? Unidentified 0.013 0.012 0.009 436 90.797 98-82-8 Q9 i-Propylbenzene 0.176 0.154 0.129

437 91.015 ? Unidentified 0.014 0.013 0.009 438 91.213 6434-77-1 K9 c-Nonene-2 0.077 0.074 0.054 439 91.481 N9 N26 0.047 0.044 0.032 440 91.610 696-29-7 M9 i-Propylcyclohexane 0.085 0.080 0.059Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 11

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 441 91.84215869-87-1 I10 2,2-Dimethyloctane 0.137 0.143 0.085 442 92.008 N9 N28 0.026 0.025 0.018 443 92.117 4032-94-4 I10 2,4-Dimethyloctane 0.037 0.039 0.023 444 92.276 ? Unidentified 0.009 0.009 0.006 445 92.522 2051-30-1 I10 2,6-Dimethyloctane 0.076 0.078 0.047 446 92.69115869-89-3 I10 2,5-Dimethyloctane 0.108 0.112 0.067 447 92.758 ? Unidentified 0.139 0.144 0.086 448 92.925 ? Unidentified 0.024 0.025 0.015 449 93.173 I10 I12 0.088 0.091 0.054 450 93.275 2040-95-1 M9 n-Butylcyclopentane 0.110 0.106 0.077

451 93.528 N10 N30 0.006 0.006 0.004 452 93.728 4110-44-5 I10 3,3-Dimethyloctane 0.233 0.238 0.144 453 93.854 I10 I14 0.055 0.057 0.034 454 94.069 ? Unidentified 0.051 0.052 0.031 455 94.303 103-65-1 Q9 n-Propylbenzene 0.681 0.596 0.499 456 94.57652896-90-9 I10 3-Methyl-5-ethylheptane 0.065 0.068 0.040 457 94.744 ? Unidentified 0.009 0.009 0.005 458 94.874 ? Unidentified 0.013 0.012 0.008 459 94.995 ? Unidentified 0.017 0.016 0.011 460 95.216 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.163 1.888 1.586

461 95.437 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.256 1.101 0.921 462 95.653 ? Unidentified 0.013 0.012 0.010 463 95.782 ? Unidentified 0.005 0.005 0.003 464 96.066 108-67-8 Q9 1,3,5-Trimethylbenzene 1.277 1.113 0.936 465 96.285 ? Unidentified 0.022 0.023 0.014 466 96.422 ? Unidentified 0.031 0.032 0.019 467 96.59115869-85-9 I10 5-Methylnonane 0.166 0.171 0.103 468 96.78717301-94-8 I10 4-Methylnonane 0.297 0.306 0.184 469 96.948 871-83-0 I10 2-Methylnonane 0.751 0.780 0.465 470 97.111 611-14-3 Q9 1-Methyl-2-ethylbenzene 1.137 0.974 0.834

471 97.431 5881-17-4 I10 3-Ethyloctane 0.084 0.086 0.052 472 97.764 5911-04-6 I10 3-Methylnonane 0.394 0.405 0.244 473 97.981 ? Unidentified 0.023 0.022 0.014 474 98.206 ? Unidentified 0.080 0.087 0.051 475 98.314 I10 C10-Isoparaffin1 0.163 0.167 0.101 476 98.569 I10 I19 0.116 0.118 0.072 477 98.815 95-63-6 Q9 1,2,4-Trimethylbenzene 2.674 2.304 1.961 478 98.921 ? Unidentified 0.079 0.081 0.049 479 99.036 1678-98-4 M10 i-Butylcyclohexane 0.127 0.120 0.080 480 99.143 ? Unidentified 0.058 0.059 0.036

481 99.232 I10 I21 0.090 0.092 0.056 482 99.363 ? Unidentified 0.016 0.016 0.010 483 99.464 I10 C10-Isoparaffin2 0.026 0.026 0.016 484 99.560 ? Unidentified 0.017 0.017 0.010Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 12

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 485 99.692 ? Unidentified 0.020 0.020 0.012 486 99.828 872-05-9 K10 Decene-1 0.010 0.010 0.006 487 99.904 ? Unidentified 0.007 0.007 0.004 488 100.014 M10 1t-Methyl-2-n-propylcyclohexanR 0.011 0.010 0.007 489 100.14819781-18-0 C10 2,3-Dimethyloctene-2 0.131 0.134 0.082 490 100.386 ? Unidentified 0.098 0.100 0.060 491 100.502 135-98-8 Q10 sec-Butylbenzene 0.064 0.056 0.042 492 100.726 124-18-5 P10 n-Decane 1.202 1.243 0.745 493 101.039 I11 I26 0.278 0.283 0.157 494 101.415 N11 N39 0.049 0.046 0.028

495 101.647 526-73-8 Q9 1,2,3-Trimethylbenzene 1.307 1.102 0.958 496 101.867 ? Unidentified 0.032 0.033 0.018 497 102.054 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.069 0.060 0.045 498 102.262 ? Unidentified 0.049 0.050 0.027 499 102.338 ? Unidentified 0.041 0.036 0.027 500 102.427 ? Unidentified 0.044 0.038 0.029 501 102.500 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.057 0.050 0.038 502 102.779 496-11-7 J10 2,3-Dihydroindene 0.445 0.348 0.332 503 103.149 7058-01-7 M10 sec-Butylcyclohexane 0.161 0.149 0.101 504 103.377 ? Unidentified 0.019 0.017 0.013

505 103.525 ? Unidentified 0.222 0.191 0.145 506 103.64517362-11-3 I11 3-Ethylnonane 0.072 0.073 0.041 507 103.731 ? Unidentified 0.021 0.020 0.012 508 103.854 ? Unidentified 0.058 0.054 0.033 509 104.061 ? Unidentified 0.012 0.011 0.007 510 104.246 I11 C11-Isoparaffin2 0.169 0.159 0.096 511 104.404 141-93-5 Q10 1,3-Diethylbenzene 0.135 0.118 0.089 512 104.691 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.473 0.414 0.310 513 104.888 ? Unidentified 0.011 0.011 0.006 514 105.045 105-05-5 Q10 1,4-Diethylbenzene 0.193 0.169 0.127

515 105.308 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.221 0.189 0.145 516 105.495 ? Unidentified 0.016 0.015 0.009 517 105.601 135-01-3 Q10 1,2-Diethylbenzene 0.043 0.037 0.028 518 105.906 ? Unidentified 0.039 0.037 0.022 519 106.097 493-02-7 D10 t-Decahydronaphthalene 0.067 0.063 0.038 520 106.180 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.046 0.040 0.030 521 106.397 I11 C11-Isoparaffin3 0.119 0.122 0.067 522 106.566 ? Unidentified 0.088 0.090 0.050 523 106.694 I11 C11-Isoparaffin4 0.104 0.106 0.059 524 106.830 I11 I38 0.021 0.022 0.012

525 107.027 I11 C11-Isoparaffin5 0.101 0.103 0.057 526 107.132 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.100 0.086 0.066 527 107.298 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.150 0.129 0.098 528 107.629 ? Unidentified 0.084 0.086 0.048Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 13

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 529 107.872 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.129 0.111 0.085 530 108.121 I11 I41 0.014 0.014 0.008 531 108.264 I11 I42 0.015 0.015 0.008 532 108.522 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.095 0.080 0.062 533 108.964 ? Unidentified 0.020 0.017 0.013 534 109.160 Q11 4M-1tC4Benz 0.004 0.003 0.002 535 109.320 ? Unidentified 0.021 0.018 0.014 536 109.519 Q11 1-Methyl-4-t-butylbenzene 0.014 0.013 0.008 537 109.715 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.027 0.023 0.018 538 109.899 ? Unidentified 0.007 0.006 0.004

539 110.227 1120-21-4 P11 n-Undecane 0.260 0.263 0.146 540 110.402 95-93-2 Q10 1,2,4,5-Tetramethylbenzene 0.019 0.016 0.013 541 110.572 ? Unidentified 0.017 0.014 0.011 542 110.745 ? Unidentified 0.002 0.002 0.001 543 110.884 Q11 1-Methyl-1-n-butylbenzene 0.015 0.012 0.009 544 111.038 ? Unidentified 0.006 0.005 0.003 545 111.184 1074-92-6 Q11 1-t-Butyl-2-methylbenzene 0.014 0.012 0.008 546 111.350 ? Unidentified 0.006 0.005 0.004 547 111.524 ? Unidentified 0.014 0.012 0.008 548 111.688 ? Unidentified 0.008 0.007 0.005

549 111.859 ? Unidentified 0.011 0.010 0.007 550 111.951 ? Unidentified 0.013 0.011 0.007 551 112.082 ? Unidentified 0.005 0.004 0.003 552 112.247 ? Unidentified 0.006 0.005 0.003 553 112.453 ? Unidentified 0.015 0.013 0.008 554 112.794 874-35-1 H10 5-Methylindan 0.026 0.022 0.017 555 113.018 Q11 C11-Aromatic2 0.011 0.010 0.007 556 113.272 ? Unidentified 0.007 0.006 0.004 557 113.377 Q11 C11-Aromatic3 0.006 0.005 0.003 558 113.458 ? Unidentified 0.014 0.012 0.007

559 113.682 824-22-6 H10 4-Methylindan 0.009 0.008 0.006 560 113.828 ? Unidentified 0.001 0.001 0.001 561 113.948 ? Unidentified 0.005 0.004 0.003 562 114.041 824-63-5 H10 2-Methylindan 0.008 0.007 0.005 563 114.239 ? Unidentified 0.010 0.008 0.005 564 114.442 ? Unidentified 0.007 0.006 0.004 565 114.684 ? Unidentified 0.008 0.008 0.004 566 114.783 M12 1t-M-2-(4-MP)cyclopentane 0.003 0.003 0.002 567 114.887 ? Unidentified 0.006 0.006 0.003 568 115.052 I12 I46 0.011 0.011 0.006

569 115.158 Q11 1-Methyl-2-n-butylbenzene 0.014 0.012 0.008 570 115.347 100-18-5 Q12 1,4-Di-i-propylbenzene 0.006 0.005 0.003 571 115.489 I12 I48 0.015 0.015 0.008 572 115.644 ? Unidentified 0.067 0.068 0.035Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 14

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 573 115.845 119-64-2 G10 1,2,3,4-Tetrahydronaphthalene 0.035 0.027 0.023 574 116.035 ? Unidentified 0.011 0.008 0.007 575 116.300 A12 A6 0.011 0.009 0.006 576 116.421 91-20-3 G10 Naphthalene 0.017 0.012 0.011 577 116.558 ? Unidentified 0.012 0.009 0.008 578 116.758 ? Unidentified 0.010 0.007 0.007 579 116.919 ? Unidentified 0.005 0.005 0.003 580 117.019 ? Unidentified 0.003 0.003 0.002 581 117.129 Q12 1t-Butyl-4-ethylbenzene 0.002 0.001 0.001 582 117.205 ? Unidentified 0.002 0.002 0.001

583 117.366 ? Unidentified 0.005 0.004 0.003 584 117.487 ? Unidentified 0.002 0.002 0.001 585 117.655 ? Unidentified 0.006 0.005 0.003 586 117.913 Q12 1,3-Di-n-propylbenzene 0.012 0.010 0.007 587 118.343 ? Unidentified 0.006 0.005 0.003 588 118.529 ? Unidentified 0.003 0.003 0.001 589 118.769 112-40-3 P12 n-Dodecane 0.042 0.042 0.022 590 118.897 ? Unidentified 0.003 0.003 0.001 591 119.046 ? Unidentified 0.003 0.003 0.001 592 119.292 ? Unidentified 0.002 0.002 0.001

593 119.400 ? Unidentified 0.001 0.001 0.001 594 119.480 ? Unidentified 0.001 0.001 0.000 595 119.628 ? Unidentified 0.002 0.002 0.001 596 119.723 ? Unidentified 0.003 0.002 0.002 597 119.831 ? Unidentified 0.003 0.003 0.002 598 120.066 102-25-0 Q12 1,3,5-Triethylbenzene 0.010 0.008 0.005 599 120.357 ? Unidentified 0.006 0.005 0.003 600 120.564 ? Unidentified 0.002 0.001 0.001 601 120.702 ? Unidentified 0.004 0.003 0.002 602 120.846 877-44-1 Q12 1,2,4-Triethylbenzene 0.003 0.003 0.002

603 120.973 ? Unidentified 0.002 0.002 0.001 604 121.243 ? Unidentified 0.004 0.003 0.002 605 121.372 ? Unidentified 0.001 0.001 0.001 606 121.479 ? Unidentified 0.001 0.001 0.000 607 121.632 ? Unidentified 0.001 0.001 0.001 608 121.827 ? Unidentified 0.001 0.001 0.001 609 121.988 ? Unidentified 0.001 0.000 0.000 610 122.119 Q12 1-Methyl-4-n-pentylbenzene 0.003 0.003 0.002 611 122.317 ? Unidentified 0.001 0.001 0.001 612 122.649 ? Unidentified 0.001 0.001 0.000

613 122.911 ? Unidentified 0.002 0.002 0.001 614 123.060 1077-16-3 Q12 n-Hexylbenzene 0.002 0.002 0.001 615 123.157 ? Unidentified 0.001 0.001 0.001 616 123.399 I13 I49 0.003 0.003 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 15

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Component List

Recovery = 100.00 Pk# Time CASNO Group Component %Wgt %Vol %Mol 617 123.724 ? Unidentified 0.002 0.002 0.001 618 123.928 ? Unidentified 0.001 0.001 0.001 619 124.126 ? Unidentified 0.001 0.001 0.001 620 124.213 ? Unidentified 0.001 0.001 0.001 621 124.420 700-12-9 Q11 Pentamethylbenzene 0.001 0.001 0.001 622 124.525 ? Unidentified 0.003 0.002 0.002 623 125.179 91-57-6 G11 2-Methylnaphthalene 0.009 0.006 0.005 624 125.363 ? Unidentified 0.003 0.002 0.002 625 125.614 ? Unidentified 0.001 0.001 0.001 626 125.970 90-12-0 G11 1-Methylnaphthalene 0.004 0.003 0.002

627 126.135 629-50-5 P13 n-Tridecane 0.007 0.007 0.003 628 126.291 ? Unidentified 0.002 0.002 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Paraffin 9.740 106-97-8 n-Butane 2.633 3.433 3.992 16.754 109-66-0 n-Pentane 0.981 1.182 1.199 33.228 110-54-3 n-Hexane 1.306 1.495 1.336 54.975 142-82-5 n-Heptane 1.606 1.772 1.412 75.307 111-65-9 n-Octane 1.672 1.796 1.290 89.557 111-84-2 n-Nonane 1.267 1.332 0.870 100.726 124-18-5 n-Decane 1.202 1.243 0.745 110.227 1120-21-4 n-Undecane 0.260 0.263 0.146 118.769 112-40-3 n-Dodecane 0.042 0.042 0.022 126.135 629-50-5 n-Tridecane 0.007 0.007 0.003

I-Paraffins 8.696 75-28-5 i-Butane 0.057 0.077 0.086 10.276 463-82-1 2,2-Dimethylpropane 0.015 0.020 0.019 14.140 78-78-4 i-Pentane 6.756 8.227 8.251 21.256 75-83-2 2,2-Dimethylbutane 0.130 0.152 0.133 26.106 79-29-8 2,3-Dimethylbutane 0.483 0.550 0.494 27.126 107-83-5 2-Methylpentane 0.960 1.110 0.982 29.626 96-14-0 3-Methylpentane 0.594 0.675 0.607 39.411 108-08-7 2,4-Dimethylpentane 0.399 0.448 0.351 39.932 464-06-2 2,2,3-Trimethylbutane 0.052 0.057 0.046 44.271 562-49-2 3,3-Dimethylpentane 0.064 0.069 0.056 47.659 591-76-4 2-Methylhexane 1.191 1.325 1.048 49.450 589-34-4 3-Methylhexane 0.669 0.734 0.588 52.072 540-84-1 2,2,4-Trimethylpentane 2.604 2.840 2.009 59.647 590-73-8 2,2-Dimethylhexane 0.082 0.089 0.063 61.657 564-02-3 2,2,3-Trimethylpentane 0.164 0.173 0.126 61.953 592-13-2 2,5-Dimethylhexane 0.445 0.484 0.343 62.274 589-43-5 2,4-Dimethylhexane 0.437 0.471 0.337 63.492 563-16-6 3,3-Dimethylhexane 0.070 0.074 0.054 65.327 565-75-3 2,3,4-Trimethylpentane 1.019 1.070 0.786 67.812 584-94-1 2,3-Dimethylhexane 0.419 0.443 0.323 69.195 592-27-8 2-Methylheptane 0.749 0.810 0.578 69.436 589-53-7 4-Methylheptane 0.347 0.371 0.268 69.769 583-48-2 3,4-Dimethylhexane 0.027 0.028 0.021 70.549 589-81-1 3-Methylheptane 0.635 0.679 0.490 70.655 619-99-8 3-Ethylhexane 0.346 0.366 0.267 72.504 3522-94-9 2,2,5-Trimethylhexane 0.437 0.467 0.301 79.575 1071-26-7 2,2-Dimethylheptane 0.532 0.565 0.365 80.02316747-25-4 2,2,3-Trimethylhexane 0.354 0.374 0.243 80.393 1068-19-5 4,4-Dimethylheptane 0.289 0.304 0.198 81.148 4032-86-4 3,3-Dimethylheptane 0.132 0.137 0.091 81.647 3074-75-7 2-Methyl-4-ethylhexane 0.062 0.065 0.043 84.110 3074-71-3 2,3-Dimethylheptane 0.059 0.062 0.041 84.538 1067-20-5 3,3-Diethylpentane 0.132 0.132 0.091 84.971 2216-34-4 4-Methyloctane 0.354 0.371 0.243 85.115 3221-61-2 2-Methyloctane 0.467 0.494 0.321 85.981 2216-33-3 3-Methyloctane 0.485 0.508 0.333 87.831 C9-Isoparaffin1 0.189 0.196 0.130Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 2

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol I-Paraffins 91.84215869-87-1 2,2-Dimethyloctane 0.137 0.143 0.085 92.117 4032-94-4 2,4-Dimethyloctane 0.037 0.039 0.023 92.522 2051-30-1 2,6-Dimethyloctane 0.076 0.078 0.047 92.69115869-89-3 2,5-Dimethyloctane 0.108 0.112 0.067 93.173 I12 0.088 0.091 0.054 93.728 4110-44-5 3,3-Dimethyloctane 0.233 0.238 0.144 93.854 I14 0.055 0.057 0.034 94.57652896-90-9 3-Methyl-5-ethylheptane 0.065 0.068 0.040 96.59115869-85-9 5-Methylnonane 0.166 0.171 0.103 96.78717301-94-8 4-Methylnonane 0.297 0.306 0.184 96.948 871-83-0 2-Methylnonane 0.751 0.780 0.465 97.431 5881-17-4 3-Ethyloctane 0.084 0.086 0.052 97.764 5911-04-6 3-Methylnonane 0.394 0.405 0.244 98.314 C10-Isoparaffin1 0.163 0.167 0.101 98.569 I19 0.116 0.118 0.072 99.232 I21 0.090 0.092 0.056 99.464 C10-Isoparaffin2 0.026 0.026 0.016 101.039 I26 0.278 0.283 0.157 103.64517362-11-3 3-Ethylnonane 0.072 0.073 0.041 104.246 C11-Isoparaffin2 0.169 0.159 0.096 106.397 C11-Isoparaffin3 0.119 0.122 0.067 106.694 C11-Isoparaffin4 0.104 0.106 0.059 106.830 I38 0.021 0.022 0.012 107.027 C11-Isoparaffin5 0.101 0.103 0.057 108.121 I41 0.014 0.014 0.008 108.264 I42 0.015 0.015 0.008 115.052 I46 0.011 0.011 0.006 115.489 I48 0.015 0.015 0.008 123.399 I49 0.003 0.003 0.001

Aromatics 116.300 A6 0.011 0.009 0.006

Mono-Aromatics 42.702 71-42-3 Benzene 0.656 0.563 0.740 66.046 108-88-3 Toluene 8.665 7.541 8.287 82.282 100-41-4 Ethylbenzene 1.440 1.253 1.195 83.617 108-38-3 m-Xylene 4.534 3.958 3.763 83.749 106-42-3 p-Xylene 1.903 1.668 1.580 86.573 95-47-6 o-Xylene 1.403 1.202 1.164 90.797 98-82-8 i-Propylbenzene 0.176 0.154 0.129 94.303 103-65-1 n-Propylbenzene 0.681 0.596 0.499 95.216 620-14-4 1-Methyl-3-ethylbenzene 2.163 1.888 1.586 95.437 622-96-8 1-Methyl-4-ethylbenzene 1.256 1.101 0.921 96.066 108-67-8 1,3,5-Trimethylbenzene 1.277 1.113 0.936 97.111 611-14-3 1-Methyl-2-ethylbenzene 1.137 0.974 0.834 98.815 95-63-6 1,2,4-Trimethylbenzene 2.674 2.304 1.961 100.502 135-98-8 sec-Butylbenzene 0.064 0.056 0.042 101.647 526-73-8 1,2,3-Trimethylbenzene 1.307 1.102 0.958 102.054 535-77-3 1-Methyl-3-i-propylbenzene 0.069 0.060 0.045Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 3

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Mono-Aromatics 102.500 99-87-6 1-Methyl-4-i-propylbenzene 0.057 0.050 0.038 104.404 141-93-5 1,3-Diethylbenzene 0.135 0.118 0.089 104.691 1074-43-7 1-Methyl-3-n-propylbenzene 0.473 0.414 0.310 105.045 105-05-5 1,4-Diethylbenzene 0.193 0.169 0.127 105.308 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.221 0.189 0.145 105.601 135-01-3 1,2-Diethylbenzene 0.043 0.037 0.028 106.180 1074-17-5 1-Methyl-2-n-propylbenzene 0.046 0.040 0.030 107.132 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.100 0.086 0.066 107.298 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.150 0.129 0.098 107.872 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.129 0.111 0.085 108.522 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.095 0.080 0.062 109.160 4M-1tC4Benz 0.004 0.003 0.002 109.519 1-Methyl-4-t-butylbenzene 0.014 0.013 0.008 109.715 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.027 0.023 0.018 110.402 95-93-2 1,2,4,5-Tetramethylbenzene 0.019 0.016 0.013 110.884 1-Methyl-1-n-butylbenzene 0.015 0.012 0.009 111.184 1074-92-6 1-t-Butyl-2-methylbenzene 0.014 0.012 0.008 113.018 C11-Aromatic2 0.011 0.010 0.007 113.377 C11-Aromatic3 0.006 0.005 0.003 115.158 1-Methyl-2-n-butylbenzene 0.014 0.012 0.008 115.347 100-18-5 1,4-Di-i-propylbenzene 0.006 0.005 0.003 117.129 1t-Butyl-4-ethylbenzene 0.002 0.001 0.001 117.913 1,3-Di-n-propylbenzene 0.012 0.010 0.007 120.066 102-25-0 1,3,5-Triethylbenzene 0.010 0.008 0.005 120.846 877-44-1 1,2,4-Triethylbenzene 0.003 0.003 0.002 122.119 1-Methyl-4-n-pentylbenzene 0.003 0.003 0.002 123.060 1077-16-3 n-Hexylbenzene 0.002 0.002 0.001 124.420 700-12-9 Pentamethylbenzene 0.001 0.001 0.001

Naphthalenes 115.845 119-64-2 1,2,3,4-Tetrahydronaphthalene 0.035 0.027 0.023 116.421 91-20-3 Naphthalene 0.017 0.012 0.011 125.179 91-57-6 2-Methylnaphthalene 0.009 0.006 0.005 125.970 90-12-0 1-Methylnaphthalene 0.004 0.003 0.002

Naphtheno/Olefi n 112.794 874-35-1 5-Methylindan 0.026 0.022 0.017

113.682 824-22-6 4-Methylindan 0.009 0.008 0.006 114.041 824-63-5 2-Methylindan 0.008 0.007 0.005

Indenes 102.779 496-11-7 2,3-Dihydroindene 0.445 0.348 0.332

Naphthenes 78.115 N3 0.005 0.004 0.004 85.395 N15 0.075 0.073 0.053 87.385 N18 0.054 0.052 0.038 91.481 N26 0.047 0.044 0.032 92.008 N28 0.026 0.025 0.018 93.528 N30 0.006 0.006 0.004 101.415 N39 0.049 0.046 0.028

Mono-Naphthen e 25.419 287-92-3 Cyclopentane 0.122 0.123 0.153Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 4

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Mono-Naphthen e 37.861 96-37-7 Methylcyclopentane 0.869 0.875 0.909 44.537 110-82-7 Cyclohexane 1.212 1.175 1.269 50.241 2532-58-3 1c,3-Dimethylcyclopentane 0.180 0.183 0.162 50.810 1759-58-6 1t,3-Dimethylcyclopentane 0.168 0.170 0.151 51.414 822-50-4 1t,2-Dimethylcyclopentane 0.270 0.271 0.242 58.291 108-87-2 Methylcyclohexane 2.757 2.704 2.474 58.636 1192-18-3 1c,2-Dimethylcyclopentane 0.015 0.015 0.013 59.192 4516-69-2 1,1,3-Trimethylcyclopentane 0.093 0.094 0.073 63.059 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.099 0.098 0.078 70.289 638-04-0 1c,3-Dimethylcyclohexane 0.610 0.604 0.479 71.233 1c,2t,3-Trimethylcyclopentane 0.005 0.005 0.004 72.795 3c-Ethylmethylcyclopentane 0.047 0.046 0.037 73.020 3t-Ethylmethylcyclopentane 0.061 0.060 0.048 73.285 111-66-0 2t-Ethylmethylcyclopentane 0.022 0.022 0.017 73.70916747-50-5 1,1-Methylethylcyclopentane 0.311 0.300 0.244 74.360 2207-03-6 1t,3-Dimethylcyclohexane 0.005 0.005 0.004 75.004 1c,2c,3-Trimethylcyclopentane 0.196 0.190 0.154 79.022 2207-01-4 1c,2-Dimethylcyclohexane 0.132 0.125 0.103 80.745 1678-91-7 Ethylcyclohexane 0.096 0.092 0.075 80.975 1795-27-3 1c,3c,5-Trimethylcyclohexane 0.317 0.311 0.222 82.644 7667-60-9 1c,2t,4t-Trimethylcyclohexane 0.188 0.182 0.131 85.791 1c,2t,4c-Trimethylcyclohexane 0.124 0.121 0.087 91.610 696-29-7 i-Propylcyclohexane 0.085 0.080 0.059 93.275 2040-95-1 n-Butylcyclopentane 0.110 0.106 0.077 99.036 1678-98-4 i-Butylcyclohexane 0.127 0.120 0.080 100.014 1t-Methyl-2-n-propylcyclohexanR 0.011 0.010 0.007 103.149 7058-01-7 sec-Butylcyclohexane 0.161 0.149 0.101 114.783 1t-M-2-(4-MP)cyclopentane 0.003 0.003 0.002

Di/Bicyclo-Napht h 106.097 493-02-7 t-Decahydronaphthalene 0.067 0.063 0.038

Olefins 35.759 O14 0.001 0.001 0.001 54.627 C7-Olefin2 0.002 0.003 0.002 60.387 O35 0.002 0.002 0.002 63.811 O38 0.007 0.007 0.006 64.635 C8-Olefin2 0.090 0.093 0.081 68.350 C8-Olefin3 0.041 0.042 0.032 76.160 C9-Olefin1 0.032 0.033 0.025 76.552 C9-Olefin2 0.012 0.012 0.008 87.033 C9-Olefin4 0.115 0.121 0.081

n-Olefins 10.159 624-64-6 t-Butene-2 0.001 0.001 0.001 10.798 590-18-1 c-Butene-2 0.001 0.001 0.001 15.546 109-67-1 Pentene-1 0.019 0.022 0.024 17.768 646-04-8 t-Pentene-2 0.009 0.010 0.011 18.703 627-20-3 c-Pentene-2 0.007 0.008 0.009 31.005 592-41-6 Hexene-1 2.717 3.024 2.845 33.85613269-52-8 t-Hexene-3 0.005 0.006 0.005Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 5

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

n-Olefins 34.319 4050-45-7 t-Hexene-2 0.007 0.007 0.007 36.080 7688-21-3 c-Hexene-2 0.004 0.004 0.004 54.22414686-14-7 t-Heptene-3 0.001 0.001 0.001 56.09814686-13-6 t-Heptene-2 0.003 0.003 0.002 57.729 6443-92-1 c-Heptene-2 0.006 0.006 0.005 73.47614850-23-8 t-Octene-4 0.012 0.013 0.010 74.70614919-01-8 t-Octene-3 0.015 0.016 0.012 75.91213389-42-9 t-Octene-2 0.005 0.005 0.004 77.222 7642-04-8 c-Octene-2 0.023 0.024 0.018 88.174 124-11-8 Nonene-1 0.022 0.024 0.015 89.09220237-46-0 c-Nonene-3 0.041 0.046 0.029 89.923 6434-78-2 t-Nonene-2 0.120 0.116 0.084 91.213 6434-77-1 c-Nonene-2 0.077 0.074 0.054 99.828 872-05-9 Decene-1 0.010 0.010 0.006

Iso-Olefins 16.301 563-46-2 2-Methylbutene-1 0.012 0.014 0.015 19.312 513-35-9 2-Methylbutene-2 0.010 0.011 0.012 24.896 691-37-2 4-Methylpentene-1 0.004 0.005 0.004 26.870 691-38-3 4-Methyl-c-pentene-2 0.001 0.001 0.001 27.558 674-76-0 4-Methyl-t-pentene-2 0.004 0.004 0.004 34.792 625-27-4 2-Methylpentene-2 0.004 0.004 0.004 35.183 922-62-3 3-Methyl-c-pentene-2 0.010 0.011 0.010 37.372 3404-73-7 3,3-Dimethylpentene-1 0.007 0.007 0.006 39.680 594-56-9 2,3,3-Trimethylbutene-1 0.001 0.001 0.001 40.640 7385-78-6 3,4-Dimethylpentene-1 0.001 0.001 0.000 41.586 762-63-0 4,4-Dimethyl-c-pentene-2 0.001 0.001 0.001 43.765 2-Methyl-c-hexene-3 0.001 0.001 0.001 45.121 692-24-0 2-Methyl-t-hexene-3 0.003 0.003 0.002 46.305 7357-93-9 2-Ethyl-3-methylbutene-1 0.001 0.001 0.001 46.670 3769-23-1 4-Methylhexene-1 0.001 0.001 0.001 47.295 3404-55-5 4-Methyl-t/c-hexene-2 0.002 0.002 0.001 51.100 2-Ethylpentene-1 0.001 0.001 0.001 53.725 4914-89-0 3-Methyl-c-hexene-3 0.002 0.002 0.002 55.475 2738-19-4 2-Methyl-2-hexene 0.004 0.005 0.004 56.242 816-79-5 3-Ethylpentene-2 0.002 0.002 0.001 77.787 2,3,3-Trimethylhexene-1 0.092 0.102 0.065 79.83519550-75-6 t-2,2-Dimethylheptene-3 0.062 0.069 0.044 82.897 4588-18-5 2-Methyloctene-1 0.032 0.036 0.022 88.85820063-92-8 t-7-Methyloctene-3 0.013 0.015 0.009 90.280 4984-01-4 3,7-Dimethyloctene-1 0.059 0.064 0.037 100.14819781-18-0 2,3-Dimethyloctene-2 0.131 0.134 0.082

Naphtheno-Olefi n 23.704 142-29-0 Cyclopentene 0.004 0.004 0.005 48.071 110-83-8 Cyclohexene 0.003 0.003 0.003

Di-Olefins 17.219 78-79-5 2-Methyl-1,3-Butadiene 0.004 0.005 0.005 18.397 598-25-4 3-Methylbutadiene-1,2 0.002 0.002 0.002 19.630 2004-70-8 1t,3-Pentadiene 0.002 0.003 0.003Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 6

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol

Di-Olefins 20.855 1574-41-0 1c,3-Pentadiene 0.001 0.001 0.001 38.685 563-79-1 2,3-Dimethyl-2-Butene 0.001 0.001 0.001 42.502 Diolefin 0.001 0.001 0.001 67.435 C8-Diolefin4 0.067 0.069 0.060 71.547 1002-33-1 1,3-Octadiene 0.136 0.134 0.108

Oxygenates 12.708 64-17-5 Ethanol 12.079 11.551 23.104 19.147 75-65-0 t-Butanol 0.001 0.001 0.001 26.524 1634-04-4 Methyl-t-butylether 0.005 0.005 0.005 45.599 71-36-3 n-Butanol 0.001 0.001 0.001 48.517 994-05-8 TAME 0.001 0.001 0.001

Unidentified 7.612 Unidentified 0.002 0.003 0.004 14.734 Unidentified 0.004 0.005 0.007 14.814 Unidentified 0.002 0.002 0.003 14.853 Unidentified 0.003 0.004 0.004 14.910 Unidentified 0.016 0.019 0.020 15.238 Unidentified 0.001 0.001 0.001 15.258 Unidentified 0.001 0.002 0.002 15.286 Unidentified 0.007 0.009 0.009 15.818 Unidentified 0.002 0.002 0.003 15.878 Unidentified 0.004 0.004 0.006 15.989 Unidentified 0.001 0.001 0.001 16.008 Unidentified 0.004 0.003 0.005 16.115 Unidentified 0.001 0.001 0.002 16.144 Unidentified 0.001 0.001 0.002 16.185 Unidentified 0.001 0.001 0.001 16.482 Unidentified 0.001 0.002 0.002 16.524 Unidentified 0.004 0.004 0.005 17.318 Unidentified 0.001 0.001 0.001 17.351 Unidentified 0.002 0.002 0.003 17.452 Unidentified 0.002 0.002 0.002 17.503 Unidentified 0.001 0.001 0.001 17.537 Unidentified 0.000 0.001 0.001 17.562 Unidentified 0.001 0.001 0.001 17.589 Unidentified 0.001 0.002 0.002 17.635 Unidentified 0.001 0.001 0.001 17.907 Unidentified 0.001 0.002 0.002 17.968 Unidentified 0.002 0.002 0.002 18.037 Unidentified 0.001 0.001 0.001 18.064 Unidentified 0.002 0.002 0.003 18.190 Unidentified 0.002 0.002 0.002 18.235 Unidentified 0.001 0.001 0.001 18.257 Unidentified 0.001 0.001 0.001 18.313 Unidentified 0.001 0.001 0.001 18.333 Unidentified 0.001 0.001 0.001 18.463 Unidentified 0.001 0.001 0.002 18.494 Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 7

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 18.538 Unidentified 0.001 0.001 0.001 18.578 Unidentified 0.001 0.001 0.001 18.850 Unidentified 0.001 0.001 0.001 18.950 Unidentified 0.004 0.003 0.004 19.063 Unidentified 0.001 0.001 0.001 19.102 Unidentified 0.001 0.001 0.001 19.186 Unidentified 0.001 0.001 0.001 19.480 Unidentified 0.001 0.002 0.002 19.561 Unidentified 0.001 0.001 0.001 19.685 Unidentified 0.001 0.001 0.001 19.743 Unidentified 0.002 0.002 0.002 19.795 Unidentified 0.001 0.001 0.001 19.830 Unidentified 0.000 0.000 0.001 19.893 Unidentified 0.001 0.001 0.002 19.939 Unidentified 0.001 0.001 0.001 19.975 Unidentified 0.001 0.001 0.001 20.078 Unidentified 0.003 0.003 0.003 20.161 Unidentified 0.001 0.001 0.001 20.230 Unidentified 0.001 0.001 0.001 20.283 Unidentified 0.001 0.001 0.001 20.307 Unidentified 0.000 0.001 0.001 20.341 Unidentified 0.001 0.001 0.001 20.398 Unidentified 0.001 0.001 0.001 20.564 Unidentified 0.003 0.004 0.004 20.647 Unidentified 0.001 0.001 0.001 20.756 Unidentified 0.003 0.003 0.004 20.922 Unidentified 0.001 0.001 0.001 20.947 Unidentified 0.000 0.001 0.001 21.020 Unidentified 0.001 0.001 0.001 21.062 Unidentified 0.001 0.001 0.001 21.092 Unidentified 0.001 0.001 0.001 21.447 Unidentified 0.002 0.002 0.002 21.559 Unidentified 0.002 0.002 0.002 21.694 Unidentified 0.001 0.001 0.001 21.722 Unidentified 0.000 0.001 0.000 21.750 Unidentified 0.001 0.001 0.001 21.837 Unidentified 0.001 0.001 0.001 21.867 Unidentified 0.001 0.001 0.001 21.981 Unidentified 0.001 0.002 0.002 22.004 Unidentified 0.001 0.001 0.001 22.082 Unidentified 0.001 0.001 0.001 22.122 Unidentified 0.000 0.000 0.000 22.186 Unidentified 0.002 0.002 0.002 22.281 Unidentified 0.001 0.001 0.001 22.330 Unidentified 0.001 0.001 0.001 22.440 Unidentified 0.001 0.001 0.001 22.541 Unidentified 0.001 0.001 0.002 22.592 Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 8

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 22.664 Unidentified 0.001 0.001 0.002 22.698 Unidentified 0.000 0.000 0.001 22.784 Unidentified 0.001 0.001 0.002 22.825 Unidentified 0.000 0.000 0.001 22.866 Unidentified 0.000 0.000 0.001 22.931 Unidentified 0.001 0.001 0.002 23.035 Unidentified 0.001 0.001 0.001 23.107 Unidentified 0.000 0.000 0.001 23.160 Unidentified 0.001 0.001 0.001 23.203 Unidentified 0.001 0.001 0.001 23.304 Unidentified 0.002 0.002 0.002 23.412 Unidentified 0.000 0.000 0.001 23.468 Unidentified 0.002 0.002 0.002 23.566 Unidentified 0.001 0.001 0.001 23.871 Unidentified 0.002 0.002 0.002 24.010 Unidentified 0.001 0.001 0.001 24.040 Unidentified 0.001 0.001 0.001 24.118 Unidentified 0.001 0.001 0.001 24.165 Unidentified 0.001 0.001 0.001 24.205 Unidentified 0.001 0.001 0.001 24.299 Unidentified 0.001 0.001 0.001 24.327 Unidentified 0.001 0.001 0.001 24.428 Unidentified 0.001 0.001 0.001 24.509 Unidentified 0.000 0.001 0.001 24.577 Unidentified 0.001 0.001 0.001 24.608 Unidentified 0.001 0.001 0.001 24.794 Unidentified 0.001 0.002 0.002 25.015 Unidentified 0.001 0.001 0.001 25.133 Unidentified 0.001 0.001 0.002 25.161 Unidentified 0.001 0.001 0.001 25.193 Unidentified 0.000 0.000 0.001 25.244 Unidentified 0.001 0.001 0.001 25.626 Unidentified 0.001 0.001 0.001 25.696 Unidentified 0.001 0.001 0.001 25.728 Unidentified 0.001 0.001 0.001 25.782 Unidentified 0.001 0.001 0.001 25.853 Unidentified 0.000 0.001 0.000 26.351 Unidentified 0.002 0.002 0.002 26.653 Unidentified 0.001 0.001 0.001 26.735 Unidentified 0.001 0.001 0.001 26.798 Unidentified 0.001 0.001 0.001 26.819 Unidentified 0.001 0.001 0.001 27.702 Unidentified 0.000 0.000 0.000 27.727 Unidentified 0.000 0.000 0.000 27.753 Unidentified 0.000 0.000 0.000 27.839 Unidentified 0.001 0.001 0.001 27.908 Unidentified 0.001 0.001 0.001 28.007 Unidentified 0.000 0.000 0.000Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 9

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 28.062 Unidentified 0.001 0.001 0.001 28.141 Unidentified 0.000 0.001 0.000 28.229 Unidentified 0.000 0.001 0.000 28.332 Unidentified 0.000 0.000 0.000 28.358 Unidentified 0.001 0.001 0.001 28.502 Unidentified 0.001 0.002 0.001 28.558 Unidentified 0.000 0.001 0.000 28.619 Unidentified 0.000 0.000 0.000 28.652 Unidentified 0.001 0.001 0.001 28.729 Unidentified 0.000 0.001 0.000 28.784 Unidentified 0.000 0.001 0.000 28.812 Unidentified 0.000 0.000 0.000 28.896 Unidentified 0.001 0.002 0.001 29.124 Unidentified 0.001 0.001 0.001 29.155 Unidentified 0.000 0.001 0.000 29.252 Unidentified 0.000 0.000 0.000 29.307 Unidentified 0.001 0.001 0.001 29.371 Unidentified 0.001 0.001 0.001 29.945 Unidentified 0.000 0.001 0.000 30.037 Unidentified 0.000 0.000 0.000 30.064 Unidentified 0.000 0.000 0.000 30.127 Unidentified 0.001 0.001 0.001 30.207 Unidentified 0.001 0.001 0.001 30.389 Unidentified 0.001 0.001 0.001 30.594 Unidentified 0.000 0.000 0.000 31.678 Unidentified 0.001 0.001 0.001 31.721 Unidentified 0.001 0.001 0.001 31.795 Unidentified 0.002 0.002 0.002 31.939 Unidentified 0.001 0.001 0.001 32.053 Unidentified 0.001 0.001 0.001 32.072 Unidentified 0.000 0.000 0.001 32.174 Unidentified 0.001 0.001 0.001 32.211 Unidentified 0.001 0.001 0.001 32.321 Unidentified 0.000 0.000 0.001 32.349 Unidentified 0.001 0.001 0.001 32.463 Unidentified 0.000 0.000 0.001 32.544 Unidentified 0.000 0.000 0.001 32.601 Unidentified 0.001 0.000 0.001 32.693 Unidentified 0.000 0.000 0.000 32.747 Unidentified 0.001 0.001 0.001 32.832 Unidentified 0.001 0.001 0.001 32.880 Unidentified 0.000 0.001 0.000 32.921 Unidentified 0.000 0.000 0.000 33.634 Unidentified 0.001 0.002 0.001 34.045 Unidentified 0.000 0.000 0.000 34.072 Unidentified 0.000 0.001 0.000 34.121 Unidentified 0.000 0.000 0.000 34.523 Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 10

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 34.935 Unidentified 0.001 0.001 0.001 35.395 Unidentified 0.000 0.000 0.000 35.441 Unidentified 0.001 0.001 0.001 35.554 Unidentified 0.001 0.001 0.001 35.605 Unidentified 0.000 0.001 0.001 35.881 Unidentified 0.000 0.000 0.000 36.248 Unidentified 0.001 0.001 0.001 36.512 Unidentified 0.000 0.000 0.000 36.589 Unidentified 0.001 0.001 0.001 36.677 Unidentified 0.001 0.001 0.001 36.811 Unidentified 0.000 0.000 0.000 37.098 Unidentified 0.001 0.001 0.001 37.130 Unidentified 0.000 0.001 0.000 37.188 Unidentified 0.000 0.000 0.000 38.223 Unidentified 0.000 0.000 0.001 38.383 Unidentified 0.001 0.001 0.001 38.580 Unidentified 0.001 0.001 0.001 38.633 Unidentified 0.000 0.001 0.001 38.812 Unidentified 0.000 0.000 0.000 38.871 Unidentified 0.000 0.000 0.000 39.033 Unidentified 0.001 0.001 0.001 39.091 Unidentified 0.001 0.001 0.001 39.171 Unidentified 0.001 0.001 0.001 40.226 Unidentified 0.001 0.001 0.001 40.416 Unidentified 0.000 0.000 0.000 40.569 Unidentified 0.001 0.001 0.001 40.708 Unidentified 0.000 0.000 0.000 40.824 Unidentified 0.000 0.001 0.000 40.860 Unidentified 0.000 0.000 0.000 41.012 Unidentified 0.001 0.001 0.001 41.068 Unidentified 0.001 0.002 0.001 41.384 Unidentified 0.001 0.001 0.001 41.476 Unidentified 0.001 0.001 0.000 41.710 Unidentified 0.001 0.001 0.001 41.895 Unidentified 0.001 0.001 0.000 41.985 Unidentified 0.001 0.001 0.001 42.090 Unidentified 0.001 0.001 0.000 42.251 Unidentified 0.001 0.001 0.001 43.291 Unidentified 0.001 0.001 0.001 43.380 Unidentified 0.001 0.001 0.000 43.481 Unidentified 0.001 0.001 0.001 43.693 Unidentified 0.000 0.000 0.000 43.848 Unidentified 0.001 0.001 0.000 45.278 Unidentified 0.001 0.001 0.001 45.410 Unidentified 0.000 0.000 0.000 45.814 Unidentified 0.001 0.001 0.001 45.950 Unidentified 0.000 0.000 0.001 46.054 Unidentified 0.001 0.001 0.001Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 11

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 46.824 Unidentified 0.001 0.001 0.001 48.278 Unidentified 0.000 0.000 0.001 48.344 Unidentified 0.001 0.001 0.001 48.799 Unidentified 0.001 0.001 0.001 48.889 Unidentified 0.000 0.000 0.000 49.024 Unidentified 0.001 0.001 0.001 49.135 Unidentified 0.001 0.001 0.000 49.925 Unidentified 0.001 0.001 0.001 50.596 Unidentified 0.001 0.001 0.001 51.163 Unidentified 0.001 0.001 0.001 51.611 Unidentified 0.041 0.041 0.037 53.029 Unidentified 0.001 0.001 0.001 53.088 Unidentified 0.001 0.001 0.001 53.164 Unidentified 0.001 0.001 0.000 53.234 Unidentified 0.001 0.001 0.001 53.348 Unidentified 0.000 0.001 0.000 53.394 Unidentified 0.001 0.001 0.001 53.596 Unidentified 0.000 0.000 0.000 53.959 Unidentified 0.001 0.001 0.001 54.189 Unidentified 0.002 0.002 0.002 54.359 Unidentified 0.001 0.001 0.001 54.527 Unidentified 0.002 0.002 0.002 55.412 Unidentified 0.001 0.001 0.001 55.618 Unidentified 0.005 0.005 0.004 55.974 Unidentified 0.001 0.001 0.001 56.031 Unidentified 0.001 0.001 0.000 56.743 Unidentified 2.386 2.504 2.141 57.363 Unidentified 0.007 0.007 0.006 57.595 Unidentified 0.001 0.001 0.000 59.889 Unidentified 0.001 0.001 0.001 60.031 Unidentified 0.005 0.004 0.003 60.174 Unidentified 0.001 0.001 0.001 60.239 Unidentified 0.001 0.002 0.001 60.317 Unidentified 0.001 0.002 0.001 60.521 Unidentified 0.003 0.003 0.002 60.867 Unidentified 0.747 0.769 0.670 62.520 Unidentified 0.010 0.010 0.009 63.980 Unidentified 0.002 0.002 0.002 64.208 Unidentified 0.004 0.004 0.003 64.362 Unidentified 0.004 0.004 0.003 67.115 Unidentified 0.019 0.019 0.017 71.724 Unidentified 0.016 0.016 0.013 71.988 Unidentified 0.007 0.007 0.005 76.279 Unidentified 0.014 0.015 0.010 76.884 Unidentified 0.009 0.010 0.006 77.482 Unidentified 0.003 0.003 0.002 77.581 Unidentified 0.003 0.003 0.002 78.392 Unidentified 0.070 0.073 0.048Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 12

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 78.713 Unidentified 0.060 0.062 0.041 79.221 Unidentified 0.018 0.018 0.015 81.408 Unidentified 0.046 0.051 0.032 81.990 Unidentified 0.014 0.013 0.010 82.435 Unidentified 0.038 0.036 0.026 83.210 Unidentified 0.054 0.060 0.038 83.862 Unidentified 0.173 0.151 0.143 84.230 Unidentified 0.099 0.103 0.068 86.194 Unidentified 0.011 0.012 0.008 86.388 Unidentified 0.072 0.074 0.049 86.779 Unidentified 0.040 0.038 0.028 87.527 Unidentified 0.161 0.156 0.112 88.361 Unidentified 0.024 0.024 0.017 88.536 Unidentified 0.018 0.018 0.013 89.269 Unidentified 0.007 0.007 0.005 90.479 Unidentified 0.013 0.012 0.009 91.015 Unidentified 0.014 0.013 0.009 92.276 Unidentified 0.009 0.009 0.006 92.758 Unidentified 0.139 0.144 0.086 92.925 Unidentified 0.024 0.025 0.015 94.069 Unidentified 0.051 0.052 0.031 94.744 Unidentified 0.009 0.009 0.005 94.874 Unidentified 0.013 0.012 0.008 94.995 Unidentified 0.017 0.016 0.011 95.653 Unidentified 0.013 0.012 0.010 95.782 Unidentified 0.005 0.005 0.003 96.285 Unidentified 0.022 0.023 0.014 96.422 Unidentified 0.031 0.032 0.019 97.981 Unidentified 0.023 0.022 0.014 98.206 Unidentified 0.080 0.087 0.051 98.921 Unidentified 0.079 0.081 0.049 99.143 Unidentified 0.058 0.059 0.036 99.363 Unidentified 0.016 0.016 0.010 99.560 Unidentified 0.017 0.017 0.010 99.692 Unidentified 0.020 0.020 0.012 99.904 Unidentified 0.007 0.007 0.004 100.386 Unidentified 0.098 0.100 0.060 101.867 Unidentified 0.032 0.033 0.018 102.262 Unidentified 0.049 0.050 0.027 102.338 Unidentified 0.041 0.036 0.027 102.427 Unidentified 0.044 0.038 0.029 103.377 Unidentified 0.019 0.017 0.013 103.525 Unidentified 0.222 0.191 0.145 103.731 Unidentified 0.021 0.020 0.012 103.854 Unidentified 0.058 0.054 0.033 104.061 Unidentified 0.012 0.011 0.007 104.888 Unidentified 0.011 0.011 0.006 105.495 Unidentified 0.016 0.015 0.009Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 13

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 105.906 Unidentified 0.039 0.037 0.022 106.566 Unidentified 0.088 0.090 0.050 107.629 Unidentified 0.084 0.086 0.048 108.964 Unidentified 0.020 0.017 0.013 109.320 Unidentified 0.021 0.018 0.014 109.899 Unidentified 0.007 0.006 0.004 110.572 Unidentified 0.017 0.014 0.011 110.745 Unidentified 0.002 0.002 0.001 111.038 Unidentified 0.006 0.005 0.003 111.350 Unidentified 0.006 0.005 0.004 111.524 Unidentified 0.014 0.012 0.008 111.688 Unidentified 0.008 0.007 0.005 111.859 Unidentified 0.011 0.010 0.007 111.951 Unidentified 0.013 0.011 0.007 112.082 Unidentified 0.005 0.004 0.003 112.247 Unidentified 0.006 0.005 0.003 112.453 Unidentified 0.015 0.013 0.008 113.272 Unidentified 0.007 0.006 0.004 113.458 Unidentified 0.014 0.012 0.007 113.828 Unidentified 0.001 0.001 0.001 113.948 Unidentified 0.005 0.004 0.003 114.239 Unidentified 0.010 0.008 0.005 114.442 Unidentified 0.007 0.006 0.004 114.684 Unidentified 0.008 0.008 0.004 114.887 Unidentified 0.006 0.006 0.003 115.644 Unidentified 0.067 0.068 0.035 116.035 Unidentified 0.011 0.008 0.007 116.558 Unidentified 0.012 0.009 0.008 116.758 Unidentified 0.010 0.007 0.007 116.919 Unidentified 0.005 0.005 0.003 117.019 Unidentified 0.003 0.003 0.002 117.205 Unidentified 0.002 0.002 0.001 117.366 Unidentified 0.005 0.004 0.003 117.487 Unidentified 0.002 0.002 0.001 117.655 Unidentified 0.006 0.005 0.003 118.343 Unidentified 0.006 0.005 0.003 118.529 Unidentified 0.003 0.003 0.001 118.897 Unidentified 0.003 0.003 0.001 119.046 Unidentified 0.003 0.003 0.001 119.292 Unidentified 0.002 0.002 0.001 119.400 Unidentified 0.001 0.001 0.001 119.480 Unidentified 0.001 0.001 0.000 119.628 Unidentified 0.002 0.002 0.001 119.723 Unidentified 0.003 0.002 0.002 119.831 Unidentified 0.003 0.003 0.002 120.357 Unidentified 0.006 0.005 0.003 120.564 Unidentified 0.002 0.001 0.001 120.702 Unidentified 0.004 0.003 0.002Hydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 14

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Components by Group

Recovery = 100.00 Group Time CASNO Component %Wgt %Vol %Mol Unidentified 120.973 Unidentified 0.002 0.002 0.001 121.243 Unidentified 0.004 0.003 0.002 121.372 Unidentified 0.001 0.001 0.001 121.479 Unidentified 0.001 0.001 0.000 121.632 Unidentified 0.001 0.001 0.001 121.827 Unidentified 0.001 0.001 0.001 121.988 Unidentified 0.001 0.000 0.000 122.317 Unidentified 0.001 0.001 0.001 122.649 Unidentified 0.001 0.001 0.000 122.911 Unidentified 0.002 0.002 0.001 123.157 Unidentified 0.001 0.001 0.001 123.724 Unidentified 0.002 0.002 0.001 123.928 Unidentified 0.001 0.001 0.001 124.126 Unidentified 0.001 0.001 0.001 124.213 Unidentified 0.001 0.001 0.001 124.525 Unidentified 0.003 0.002 0.002 125.363 Unidentified 0.003 0.002 0.002 125.614 Unidentified 0.001 0.001 0.001 126.291 Unidentified 0.002 0.002 0.001

PlusHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 1

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF222.5020.0017.5015.0012.5010.007.505.002.50

Unidentified

i-Butane

n-Butane t-Butene-2 2,2-Dimethylpropane c-Butene-2

Ethanol

i-Pentane
Unidentified Unidentified Pentene-1 Unidentified 2-Methylbutene-1 Unidentified n-Pentane 2-Methyl-1,3-Butadiene Unidentified t-Pentene-2 Unidentified 3-Methylbutadiene-1,2 c-Pentene-2 Unidentified t-Butanol 2-Methylbutene-2 Unidentified 1t,3-Pentadiene

1c,3-Pentadiene 2,2-Dimethylbutane Unidentified

Cyclopentene Unidentified

4-Meth y l p entene-1 UnidentifiedHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 2

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF547.5045.0042.5040.0037.5035.0032.5030.0027.50 Unidentified U n id en tifi e d U n id en tifi e d Cyclopentane Unidentified 2,3-Dimethylbutane Unidentified Methyl-t-butylether Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2 Unidentified

3-Methylpentane Unidentified

Hexene-1

Unidentified

n-Hexane Unidentified t-Hexene-3 Unidentified t-Hexene-2 Unidentified 2-Methylpentene-2 Unidentified 3-Methyl-c-pentene-2 Unidentified O14 Unidentified c-Hexene-2 Unidentified

Unidentified 3,3-Dimethylpentene-1 Methylcyclopentane Unidentified 2,3-Dimethyl-2-Butene
2,4-Dimethylpentane 2,3,3-Trimethylbutene-1

2,2,3-Trimethylbutane Unidentified 3,4-Dimethylpentene-1

Unidentified 4,4-Dimethyl-c-pentene-2

Diolefin Benzene
Unidentified 2-Methyl-c-hexene-3 3,3-Dimethylpentane Cyclohexane 2-Methyl-t-hexene-3 Unidentified n-Butanol Unidentified 2-Ethyl-3-methylbutene-1 4-Methylhexene-1 Unidentified 4-Methyl-t/c-hexene-2 2-Methylhexane Cyclohexene Unidentified TAME Unidentified 3-Methylhexane UnidentifiedHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 3

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF772.5070.0067.5065.0062.5060.0057.5055.0052.50 1 c, 3

- Di me th y l cyc l open t an e Unidentified 1t,3-Dimethylcyclopentane 2-Ethylpentene-1 Unidentified 1t,2-Dimethylcyclopentane Unidentified 2,2,4-Trimethylpentane

Unidentified 3-Methyl-c-hexene-3 Unidentified t-Heptene-3 C7-Olefin2 n-Heptane Unidentified 2-Methyl-2-hexene Unidentified t-Heptene-2 3-Ethylpentene-2 Unidentified
Unidentified c-Heptene-2 Methylcyclohexane 1c,2-Dimethylcyclopentane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified O35 Unidentified
2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane Unidentified

1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane O38 Unidentified

C8-Olefin2 2,3,4-Trimethylpentane

Toluene

Unidentified C8-Diolefin4 2,3-Dimethylhexane C8-Olefin3

2-Methylheptane 4-Methylheptane 3,4-Dimethylhexane 1c,3-Dimethylcyclohexane 3-Methylheptane 3-Ethylhexane 1c,2t,3-Trimethylcyclopentane 1,3-Octadiene Unidentified Unidentified 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane 2t-Ethylmethylcyclopentane t-Octene-4 1,1-Methylethylcyclopentane 1t,3-Dimethylcyclohexane t-Octene-3 1c 2c 3

- TrimethylcyclopentaneHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 4

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF197.5095.0092.5090.0087.5085.0082.5080.0077.50 n-Octane
t-Octene-2 C9-Olefin1 Unidentified C9-Olefin2 Unidentified c-Octene-2 Unidentified 2,3,3-Trimethylhexene-1 N3 Unidentified Unidentified

1c,2-Dimethylcyclohexane Unidentified 2,2-Dimethylheptane t-2,2-Dimethylheptene-3 2,2,3-Trimethylhexane 4,4-Dimethylheptane Ethylcyclohexane 1c,3c,5-Trimethylcyclohexane 3,3-Dimethylheptane Unidentified 2-Methyl-4-ethylhexane Unidentified Ethylbenzene

Unidentified 1c,2t,4t-Trimethylcyclohexane 2-Methyloctene-1 Unidentified m-Xylene p-Xylene Unidentified 2,3-Dimethylheptane

Unidentified 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane N15 1c,2t,4c-Trimethylcyclohexane 3-Methyloctane Unidentified Unidentified o-Xylene Unidentified

C9-Olefin4 N18 Unidentified C9-Isoparaffin1 Nonene-1 Unidentified Unidentified t-7-Methyloctene-3

c-Nonene-3 Unidentified n-Nonane t-Nonene-2 3,7-Dimethyloctene-1 Unidentified i-Propylbenzene Unidentified

c-Nonene-2 N26

i-Propylcyclohexane

2,2-Dimethyloctane N28 2,4-Dimethyloctane Unidentified

2,6-Dimethyloctane 2,5-Dimethyloctane

Unidentified Unidentified I12 n-Butylcyclopentane N30 3,3-Dimethyloctane

I14 Unidentified n-Propylbenzene 3-Methyl-5-ethylheptane Unidentified Unidentified Unidentified 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene Unidentified Unidentified 1,3,5-Trimethylbenzene Unidentified Unidentified 5-Methylnonane 4-Methylnonane 2-Methylnonane 1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane Unidentified Unidentified C10-Isoparaffin1 I19 1,2,4-Trimethylbenzene

Unidentified i-Butylcyclohexane Unidentified I21 Unidentified C10-Isoparaffin2 Decene-1 Unidentified 1t

- Methyl

- 2

- n

- propylcyclohexanRHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 5

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF1122.50120.00117.50115.00112.50110.00107.50105.00102.50 2

, 3

- Dimethyloctene

- 2 Unidentified sec-Butylbenzene n-Decane I26 N39 1,2,3-Trimethylbenzene Unidentified 1-Methyl-3-i-propylbenzene Unidentified Unidentified 1-Methyl-4-i-propylbenzene 2,3-Dihydroindene sec-Butylcyclohexane Unidentified Unidentified 3-Ethylnonane Unidentified Unidentified Unidentified C11-Isoparaffin2 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene Unidentified 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene Unidentified

1,2-Diethylbenzene Unidentified

t-Decahydronaphthalene 1-Methyl-2-n-propylbenzene C11-Isoparaffin3 Unidentified C11-Isoparaffin4 I38 C11-Isoparaffin5 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene Unidentified 1,2-Dimethyl-4-ethylbenzene I41 I42 1,3-Dimethyl-2-ethylbenzene Unidentified 4M-1tC4Benz Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene Unidentified n-Undecane 1,2,4,5-Tetramethylbenzene Unidentified Unidentified

1-Methyl-1-n-butylbenzene Unidentified 1-t-Butyl-2-methylbenzene Unidentified

Unidentified Unidentified Unidentified Unidentified Unidentified Unidentified 5-Methylindan C11-Aromatic2 Unidentified C11-Aromatic3 Unidentified 4-Methylindan Unidentified Unidentified 2-Methylindan Unidentified Unidentified Unidentified 1t-M-2-(4-MP)cyclopentane I46 1-Methyl-2-n-butylbenzene 1,4-Di-i-propylbenzene

I48 Unidentified

1,2,3,4-Tetrahydronaphthalene Unidentified A6

Naphthalene Unidentified Unidentified Unidentified Unidentified 1t-Butyl-4-ethylbenzene Unidentified 1,3-Di-n-propylbenzene Unidentified n-Dodecane Unidentified

Unidentified 1,3,5-Triethylbenzene Unidentified 1,2,4-Triethylbenzene Unidentified Unidentified

1-Methyl-4-n-pentylbenzene Unidentified Unidentified n-Hexylbenzene I49 Unidentified Pentamethylbenzene UnidentifiedHydrocarbon Expert V4.7 Tue Jul 22 17:54:59 2008 Page 6

21-Jul-08, 23:56:15 File: C:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF Operator: AAD Sample: ODDB-72366 Parameter: C:\HPCHEM\SeparationSystems\HCE4\ODDB-72366 ODDB-72366



# Sample ChromatogramC:\HPCHEM\2\DATA\07-21-08\004F0401.D\004F0401_ADC1_B.CDF1147.50145.00142.50140.00137.50135.00132.50130.00127.50 2

- M e th y l nap hth a l en e Unidentified Unidentified 1-Methylnaphthalene

n-Tridecane Unidentified**Hydrocarbon Expert V4.7 Thu Aug 26 17:04:50 2010**  **Page 1**

25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 3.891 4.430 3.716

I-Paraffins 42.144 45.328 31.970

Aromatics 18.679 15.841 13.777 Mono-Aromatics 17.762 15.124 13.196 Naphthalenes 0.129 0.093 0.078 Naphtheno/Olefino-Benzs 0.178 0.148 0.106 Indenes 0.611 0.477 0.396

Naphthenes 3.473 3.377 3.000 Mono-Naphthenes 3.473 3.377 3.000 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.304 7.991 7.554 n-Olefins 2.999 3.367 3.205 Iso-Olefins 3.554 3.903 3.580 Naphtheno-Olefins 0.710 0.678 0.725 Di-Olefins 0.041 0.043 0.045

Oxygenates 22.675 21.279 38.864

Unidentified 1.833 1.754 1.119

Plus 0.000 0.000 0.000

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 22.540 21.154 38.700 C3 0.087 0.084 0.117 C4 0.783 0.972 1.059 C5 9.218 10.718 10.234 C6 11.237 12.025 10.486 C7 10.695 10.274 8.824 C8 30.880 31.392 21.656 C9 7.573 7.045 4.851 C10 4.092 3.602 2.407 C11 0.933 0.871 0.484 C12 0.129 0.109 0.063

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Thu Aug 26 17:04:50 2010**  **Page 1**

25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.006 0.009 0.011 C4 0.479 0.613 0.652 C5 1.183 1.399 1.297 C6 0.839 0.942 0.770 C7 0.584 0.632 0.461 C8 0.472 0.497 0.327 C9 0.278 0.286 0.171 C10 0.020 0.020 0.011 C11 0.030 0.030 0.015

I-Paraffins C4 0.052 0.069 0.071 C5 4.195 5.014 4.599 C6 5.533 6.226 5.079 C7 2.943 3.210 2.323 C8 24.875 26.123 17.224 C9 2.918 3.041 1.800 C10 1.093 1.111 0.604 C11 0.522 0.520 0.264 C12 0.013 0.013 0.006

Mono-Aromatics C6 0.743 0.626 0.752 C7 5.029 4.295 4.317 C8 5.117 4.373 3.812 C9 4.277 3.638 2.815 C10 2.146 1.816 1.265 C11 0.338 0.284 0.180 C12 0.112 0.094 0.055

Naphthalenes C10 0.112 0.081 0.069 C11 0.017 0.012 0.009

Naphtheno/Olefino-Benzs C10 0.178 0.148 0.106

Indenes C9 0.070 0.054 0.047 C10 0.537 0.420 0.347 C12 0.004 0.003 0.002

Mono-Naphthenes C5 0.150 0.149 0.169 C6 1.501 1.467 1.411 C7 1.409 1.368 1.132 C8 0.376 0.360 0.265 C9 0.030 0.026 0.019

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.007 0.006 0.004

n-Olefins C4 0.197 0.239 0.278 C5 1.666 1.902 1.879 C6 1.040 1.127 0.978 C7 0.069 0.073 0.056 C11 0.026 0.026 0.015

Iso-Olefins C5 1.791 2.027 2.020 C6 1.077 1.158 1.012 C7 0.646 0.680 0.520 C8 0.040 0.038 0.027

Naphtheno-Olefins C5 0.206 0.198 0.239 C6 0.504 0.479 0.485

Di-Olefins C5 0.026 0.029 0.030 C7 0.015 0.015 0.014

Oxygenates C2 22.540 21.154 38.700 C3 0.081 0.075 0.106 C4 0.055 0.051 0.058

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 29.52 27.10 5% 81.81 81.17 10% 114.58 98.81 15% 144.41 139.00 20% 164.42 153.99 25% 172.44 172.31 30% 172.67 172.57 35% 172.91 172.82 40% 173.15 173.08 45% 177.19 176.24 50% 209.29 208.97 55% 209.94 209.71 60% 211.55 210.32 65% 230.81 228.71 70% 234.39 231.05 75% 237.47 236.74 80% 245.89 239.09 85% 279.99 268.46 90% 319.83 291.80 95% 348.60 336.10 FBP 400.46 388.16

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Thu Aug 26 17:04:50 2010**  **Page 1**

25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.554 74-98-6 P3 Propane 0.006 0.009 0.011 1.666 2 8.810 75-28-5 I4 i-Butane 0.052 0.069 0.071 13.823 3 9.624 115-11-7 K4 Isobutene 0.017 0.021 0.023 4.570 4 9.665 106-98-9 K4 Butene-1 0.018 0.023 0.026 5.010 5 10.023 106-97-8 P4 n-Butane 0.479 0.613 0.652 127.567 6 10.510 624-64-6 K4 t-Butene-2 0.074 0.091 0.105 20.522 7 10.638 463-82-1 I5 2,2-Dimethylpropane 0.012 0.015 0.013 3.130 8 11.252 590-18-1 K4 c-Butene-2 0.088 0.105 0.124 24.230 9 13.126 64-17-5 X2 Ethanol 22.540 21.154 38.700 2558.100 10 13.453 563-45-1 C5 3-Methylbutene-1 0.225 0.265 0.254 61.956

11 15.078 78-78-4 I5 i-Pentane 4.183 5.000 4.586 1121.004 12 16.732 109-67-1 K5 Pentene-1 0.338 0.391 0.381 93.178 13 17.583 563-46-2 C5 2-Methylbutene-1 0.514 0.585 0.579 141.572 14 18.116 109-66-0 P5 n-Pentane 1.183 1.399 1.297 317.000 15 18.625 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 3.013 16 19.234 646-04-8 K5 t-Pentene-2 0.858 0.980 0.968 236.495 17 19.877 ? Unidentified 0.006 0.007 0.007 1.976 18 20.269 627-20-3 K5 c-Pentene-2 0.470 0.531 0.530 129.585 19 20.945 513-35-9 C5 2-Methylbutene-2 1.053 1.177 1.187 290.107 20 21.270 2004-70-8 E5 1t,3-Pentadiene 0.016 0.017 0.018 4.430

21 22.537 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.007 0.008 1.979 22 23.096 75-83-2 I6 2,2-Dimethylbutane 0.094 0.107 0.086 25.259 23 25.742 142-29-0 B5 Cyclopentene 0.199 0.191 0.231 56.449 24 26.896 71-23-8 X3 n-Propanol 0.081 0.075 0.106 15.535 25 27.000 ? Unidentified 0.057 0.063 0.054 19.256 26 27.605 287-92-3 M5 Cyclopentane 0.150 0.149 0.169 41.421 27 28.340 79-29-8 I6 2,3-Dimethylbutane 1.146 1.283 1.052 308.342 28 28.736 ? Unidentified 0.053 0.053 0.048 17.997 29 29.203 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.051 0.044 12.794 30 29.421 107-83-5 I6 2-Methylpentane 2.676 3.034 2.456 719.907

31 29.842 674-76-0 C6 4-Methyl-t-pentene-2 0.132 0.145 0.124 36.274 32 32.069 96-14-0 I6 3-Methylpentane 1.617 1.803 1.484 435.084 33 33.225 763-29-1 C6 2-Methylpentene-1 0.224 0.243 0.211 61.862 34 33.446 592-41-6 K6 Hexene-1 0.160 0.175 0.151 44.141 35 35.641 760-21-4 C6 2-Ethylbutene-1 0.069 0.074 0.065 19.089 36 35.800 110-54-3 P6 n-Hexane 0.839 0.942 0.770 225.643 37 36.437 13269-52-8 K6 t-Hexene-3 0.263 0.285 0.247 72.471 38 36.915 4050-45-7 K6 t-Hexene-2 0.403 0.438 0.379 111.187 39 37.041 1120-62-3 B6 3-Methylcyclopentene 0.101 0.098 0.097 27.771 40 37.410 625-27-4 C6 2-Methylpentene-2 0.341 0.366 0.321 94.058

41 37.823 922-62-3 C6 3-Methyl-c-pentene-2 0.264 0.280 0.248 72.747 42 38.740 7688-21-3 K6 c-Hexene-2 0.214 0.229 0.201 58.924 43 40.084 3404-73-7 C7 3,3-Dimethylpentene-1 0.308 0.325 0.248 85.004

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.669 96-37-7 M6 Methylcyclopentane 1.028 1.017 0.966 283.247 45 42.237 108-08-7 I7 2,4-Dimethylpentane 0.820 0.903 0.647 221.463 46 42.535 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.014 0.011 3.669 47 42.781 464-06-2 I7 2,2,3-Trimethylbutane 0.052 0.056 0.041 14.023 48 45.427 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 4.112 49 45.635 71-42-3 Q6 Benzene 0.743 0.626 0.752 220.396 50 45.833 693-89-0 B6 1-Methylcyclopentene 0.359 0.341 0.346 101.275 51 46.640 3404-61-3 C7 3-Methylhexene-1 0.015 0.016 0.012 4.234 52 47.228 3524-73-0 C7 5-Methylhexene-1 0.042 0.044 0.034 11.469 53 47.552 110-82-7 M6 Cyclohexane 0.474 0.450 0.445 130.535

54 48.058 71-36-3 X4 n-Butanol 0.055 0.051 0.058 11.385 55 49.271 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.043 0.032 11.089 56 49.619 3769-23-1 C7 4-Methylhexene-1 0.011 0.011 0.009 3.003 57 50.265 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.053 0.041 13.947 58 50.672 591-76-4 I7 2-Methylhexane 1.518 1.657 1.198 410.084 59 51.153 110-83-8 B6 Cyclohexene 0.044 0.040 0.043 12.219 60 52.492 589-34-4 I7 3-Methylhexane 0.552 0.595 0.436 149.226 61 53.353 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.152 0.150 0.122 41.855 62 53.940 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.117 0.116 0.094 32.205 63 54.566 822-50-4 M7 1t,2-Dimethylcyclopentane 0.160 0.158 0.129 44.160

64 54.899 C7 C7 - Iso-Olefin - 2 0.021 0.022 0.017 5.859 65 55.232 540-84-1 I8 2,2,4-Trimethylpentane 11.022 11.796 7.632 2983.199 66 55.611 M7 C7 - MonoNaph - 1 0.028 0.027 0.020 7.645 67 56.802 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.772 68 57.331 14686-14-7 K7 t-Heptene-3 0.032 0.033 0.025 8.702 69 57.684 6094-02-6 C7 2-Methylhexene-1 0.057 0.060 0.046 15.641 70 58.056 142-82-5 P7 n-Heptane 0.584 0.632 0.461 157.722 71 58.273 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.020 6.752 72 58.547 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.027 0.021 7.167 73 58.791 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.021 0.016 5.445

74 59.172 14686-13-6 K7 t-Heptene-2 0.013 0.014 0.011 3.658 75 59.648 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 4.962 76 60.075 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.015 0.012 4.089 77 60.858 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 3.669 78 61.518 108-87-2 M7 Methylcyclohexane 0.886 0.852 0.714 244.129 79 62.457 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.027 0.026 0.019 7.338 80 62.847 590-73-8 I8 2,2-Dimethylhexane 0.027 0.028 0.018 7.211 81 63.360 ? Unidentified 0.052 0.054 0.038 17.660 82 64.294 1640-89-7 M7 Ethylcyclopentane 0.049 0.047 0.039 13.470 83 64.950 564-02-3 I8 2,2,3-Trimethylpentane 0.546 0.565 0.378 147.830

84 65.182 592-13-2 I8 2,5-Dimethylhexane 1.242 1.326 0.860 336.147 85 65.519 589-43-5 I8 2,4-Dimethylhexane 1.139 1.204 0.789 308.287 86 66.349 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.027 0.026 0.019 7.392

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.741 563-16-6 I8 3,3-Dimethylhexane 0.019 0.020 0.013 5.067 88 67.862 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.024 0.023 0.017 6.647 89 68.509 565-75-3 I8 2,3,4-Trimethylpentane 4.276 4.403 2.961 1157.167 90 69.028 108-88-3 Q7 Toluene 5.029 4.295 4.317 1476.457 91 69.188 560-21-4 I8 2,3,3-Trimethylpentane 4.740 4.833 3.282 1282.747 92 70.514 C8 C8 - Diolefin - 1 0.010 0.010 0.007 2.769 93 70.799 584-94-1 I8 2,3-Dimethylhexane 1.127 1.172 0.780 304.957 94 72.048 592-27-8 I8 2-Methylheptane 0.243 0.258 0.168 65.714 95 72.310 589-53-7 I8 4-Methylheptane 0.185 0.194 0.128 50.063 96 72.448 ? Unidentified 0.089 0.092 0.062 30.210

97 73.224 M8 1,3-dimethyl-t-cyclohexane 0.155 0.149 0.109 42.805 98 73.360 589-81-1 I8 3-Methylheptane 0.210 0.220 0.145 56.789 99 73.561 619-99-8 I8 3-Ethylhexane 0.100 0.104 0.069 27.147 100 74.457 ? Unidentified 0.025 0.024 0.018 8.607 101 75.260 3522-94-9 I9 2,2,5-Trimethylhexane 1.994 2.088 1.230 540.830 102 75.609 M8 3c-Ethylmethylcyclopentane 0.009 0.009 0.006 2.528 103 75.826 M8 3t-Ethylmethylcyclopentane 0.013 0.012 0.009 3.495 104 76.233 ? Unidentified 0.015 0.014 0.010 4.926 105 76.532 ? Unidentified 0.059 0.056 0.041 19.802 106 77.869 111-65-9 P8 n-Octane 0.472 0.497 0.327 127.728

107 78.820 ? Unidentified 0.050 0.048 0.035 16.755 108 80.353 1069-53-0 I9 2,3,5-Trimethylhexane 0.330 0.338 0.203 89.373 109 80.905 C8 C9 - IsoOlefin - 1 0.016 0.015 0.011 4.377 110 81.367 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.013 0.012 0.009 3.629 111 81.518 1071-26-7 I9 2,4-Dimethylheptane 0.069 0.072 0.043 18.763 112 82.173 1678-91-7 M8 Ethylcyclohexane 0.108 0.102 0.076 29.739 113 82.473 1072-05-5 I9 2,6-Dimethylheptane 0.105 0.109 0.065 28.373 114 82.974 ? Unidentified 0.024 0.023 0.017 8.014 115 83.404 I9 2,5-Dimethylheptane 0.201 0.208 0.124 54.408 116 83.580 926-82-9 I9 3,5-Dimethylheptane 0.024 0.025 0.015 6.558

117 84.728 100-41-4 Q8 Ethylbenzene 0.894 0.764 0.666 260.567 118 84.901 ? Unidentified 0.028 0.028 0.018 9.343 119 85.145 ? Unidentified 0.031 0.030 0.020 10.555 120 85.952 108-38-3 Q8 m-Xylene 2.374 2.034 1.769 691.839 121 86.098 106-42-3 Q8 p-Xylene 1.058 0.910 0.789 308.408 122 86.230 ? Unidentified 0.067 0.068 0.041 22.611 123 86.487 C8 C9-IsoOlefin-3 0.014 0.014 0.009 3.924 124 86.594 ? Unidentified 0.013 0.013 0.008 4.223 125 86.751 I9 3,5-Dimethylheptane 0.009 0.009 0.005 2.310 126 86.879 1067-20-5 I9 3,3-Diethylpentane 0.008 0.007 0.005 2.038

127 87.272 2216-34-4 I9 4-Methyloctane 0.047 0.048 0.029 12.776 128 87.404 3221-61-2 I9 2-Methyloctane 0.063 0.065 0.039 17.010 129 88.106 15869-80-4 I9 Heptane, 3-ethyl- 0.008 0.009 0.005 2.293

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 88.267 2216-33-3 I9 3-Methyloctane 0.062 0.063 0.038 16.679 131 88.743 ? Unidentified 0.107 0.116 0.067 36.142 132 88.926 95-47-6 Q8 o-Xylene 0.790 0.665 0.589 230.183 133 89.321 I10 C10 - IsoParaffin - 1 0.344 0.350 0.191 93.372 134 89.909 M9 trans-1,3-Diethylcyclopentane 0.017 0.015 0.011 5.039 135 90.164 14720-74-2 I10 2,2,4-trimethylheptane 0.247 0.251 0.137 67.095 136 91.729 111-84-2 P9 n-Nonane 0.278 0.286 0.171 75.261 137 92.301 4926-90-3 M9 1,1-Methylethylcyclohexane 0.012 0.011 0.008 3.438 138 93.093 98-82-8 Q9 i-Propylbenzene 0.030 0.025 0.019 8.543 139 93.271 ? Unidentified 0.007 0.007 0.005 2.442

140 93.271 ? Unidentified 0.007 0.008 0.004 2.442 141 93.271 ? Unidentified 0.007 0.005 0.004 2.442 142 93.839 ? Unidentified 0.050 0.051 0.028 16.961 143 94.061 15869-87-1 I10 2,2-Dimethyloctane 0.019 0.019 0.010 5.100 144 94.863 15869-89-3 I10 2,5-Dimethyloctane 0.012 0.013 0.007 3.388 145 95.066 I10 C10 - IsoParaffin - 2 0.007 0.007 0.004 1.960 146 95.504 2051-30-1 I10 2,4-Dimethyloctane 0.022 0.022 0.012 6.003 147 95.891 I10 2,6-Dimethyloctane 0.010 0.010 0.006 2.798 148 96.552 103-65-1 Q9 n-Propylbenzene 0.253 0.217 0.166 73.177 149 97.398 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.954 0.817 0.628 276.302

150 97.631 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.442 0.380 0.291 127.883 151 98.257 108-67-8 Q9 1,3,5-Trimethylbenzene 0.557 0.477 0.366 161.221 152 98.905 17301-94-8 I10 4-Methylnonane 0.011 0.011 0.006 3.045 153 99.112 I10 2,2,6-Trimethyloctane 0.344 0.351 0.191 93.565 154 99.342 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.325 0.273 0.214 94.131 155 99.884 5911-04-6 I10 3-Methylnonane 0.015 0.015 0.008 3.948 156 100.349 ? Unidentified 0.023 0.017 0.011 7.617 157 100.480 ? Unidentified 0.060 0.060 0.030 20.252 158 100.696 I11 C11-Isoparaffin-2 0.033 0.033 0.017 9.019 159 100.972 95-63-6 Q9 1,2,4-Trimethylbenzene 1.526 1.290 1.004 441.812

160 101.162 ? Unidentified 0.042 0.045 0.024 14.311 161 101.283 ? Unidentified 0.025 0.026 0.014 8.583 162 101.548 1678-98-4 M10 i-Butylcyclohexane 0.007 0.006 0.004 1.869 163 102.333 17302-01-1 I10 3-Ethyl-3-methylheptane 0.061 0.061 0.031 16.694 164 102.647 538-93-2 Q10 i-Butylbenzene 0.073 0.063 0.043 21.031 165 102.799 124-18-5 P10 n-Decane 0.020 0.020 0.011 5.489 166 102.896 ? Unidentified 0.014 0.012 0.008 4.698 167 103.196 ? Unidentified 0.017 0.017 0.009 5.905 168 103.847 526-73-8 Q9 1,2,3-Trimethylbenzene 0.190 0.158 0.125 55.090 169 104.212 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.008 0.007 0.005 2.444

170 104.406 I11 C11 Isoparaffin-4 0.009 0.009 0.005 2.434 171 104.614 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.062 0.053 0.036 17.809 172 105.043 J9 Indan 0.070 0.054 0.047 20.739

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 105.637 J10 Indene 0.365 0.281 0.245 107.521 174 106.352 I11 C11-Isoparaffin-7 0.152 0.152 0.077 41.437 175 106.545 141-93-5 Q10 1,3-Diethylbenzene 0.023 0.020 0.014 6.684 176 106.830 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.479 0.412 0.282 137.958 177 107.157 105-05-5 Q10 1,4-Diethylbenzene 0.180 0.155 0.106 51.889 178 107.380 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.108 0.091 0.064 31.187 179 107.620 135-01-3 Q10 1,2-Diethylbenzene 0.039 0.033 0.023 11.236 180 108.079 ? Unidentified 0.038 0.038 0.019 12.775 181 108.232 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.043 0.036 0.025 12.367 182 108.353 ? Unidentified 0.045 0.045 0.023 15.040

183 108.435 ? Unidentified 0.041 0.041 0.021 13.925 184 108.561 I11 C11- Isoparaffin-11 0.328 0.326 0.166 89.233 185 108.743 ? Unidentified 0.106 0.106 0.054 35.927 186 109.166 ? Unidentified 0.448 0.378 0.264 151.280 187 109.393 J10 2-Methylindan 0.056 0.043 0.034 16.550 188 109.739 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.268 0.227 0.158 77.278 189 110.285 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.318 0.265 0.187 91.604 190 110.709 ? Unidentified 0.011 0.010 0.006 3.688 191 110.903 693-61-8 K11 2-Undecene, (E)- 0.026 0.026 0.015 7.039 192 111.037 ? Unidentified 0.062 0.062 0.035 20.808

193 111.309 ? Unidentified 0.054 0.047 0.029 18.125 194 111.411 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.060 0.050 0.035 17.256 195 111.709 1120-21-4 P11 n-Undecane 0.030 0.030 0.015 8.135 196 111.861 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.041 0.034 0.022 11.745 197 111.972 ? Unidentified 0.024 0.020 0.013 8.189 198 112.346 Q10 1,2,4,5-Tetramethylbenzene 0.204 0.170 0.120 58.779 199 112.613 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.280 0.233 0.165 80.518 200 112.955 ? Unidentified 0.005 0.004 0.003 1.804 201 113.130 I12 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.293 202 113.484 ? Unidentified 0.019 0.019 0.009 6.391

203 113.609 ? Unidentified 0.006 0.006 0.003 2.050 204 113.760 Q11 C11 - Aromatic - 3 0.050 0.041 0.027 14.268 205 113.944 874-35-1 H10 5-Methylindan 0.090 0.075 0.054 25.798 206 114.069 Q12 1,2-Di-i-propylbenzene 0.033 0.028 0.016 9.526 207 114.284 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.045 0.037 0.024 12.876 208 114.448 Q11 C11 - Aromatic - 4 0.031 0.026 0.016 8.790 209 114.693 824-22-6 J10 4-Methylindan 0.115 0.096 0.069 33.114 210 114.847 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.028 0.023 0.015 7.980 211 114.941 824-63-5 H10 2-Methylindan 0.088 0.073 0.053 25.317 212 115.143 ? Unidentified 0.010 0.010 0.005 3.289

213 115.257 538-68-1 Q11 n-Pentylbenzene 0.011 0.009 0.006 3.227 214 115.484 Q11 tert-Pentylbenzene 0.046 0.039 0.025 13.291 215 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.020 0.017 0.011 5.802

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 115.908 Q11 C11 - Aromatic - 6 0.032 0.028 0.017 9.217 217 116.248 I12 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.205 218 116.367 100-18-5 Q12 1,4-Di-i-propylbenzene 0.038 0.032 0.019 10.926 219 116.809 91-20-3 G10 Naphthalene 0.112 0.081 0.069 33.752 220 116.942 ? Unidentified 0.013 0.013 0.006 4.352 221 117.125 ? Unidentified 0.004 0.003 0.002 1.303 222 117.246 ? Unidentified 0.009 0.008 0.004 3.053 223 117.409 J12 Dimethyl Indane - 1 0.004 0.003 0.002 1.189 224 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.006 0.005 0.003 1.719 225 117.893 Q12 1,3-Di-n-propylbenzene 0.035 0.029 0.017 9.966

226 118.004 Q11 C11 - Aromatic - 11 0.019 0.016 0.010 5.362 227 118.557 Q11 C11 - Aromatic - 12 0.015 0.013 0.008 4.314 228 123.440 91-57-6 G11 2-Methylnaphthalene 0.011 0.008 0.006 3.391 229 124.305 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.596 230 126.296 ? Unidentified 0.007 0.006 0.003 2.243 231 130.001 ? Unidentified 0.003 0.002 0.002 0.999

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.006 0.009 0.011 1.666

10.023 106-97-8 n-Butane 0.479 0.613 0.652 127.567 18.116 109-66-0 n-Pentane 1.183 1.399 1.297 317.000 35.800 110-54-3 n-Hexane 0.839 0.942 0.770 225.643 58.056 142-82-5 n-Heptane 0.584 0.632 0.461 157.722 77.869 111-65-9 n-Octane 0.472 0.497 0.327 127.728 91.729 111-84-2 n-Nonane 0.278 0.286 0.171 75.261 102.799 124-18-5 n-Decane 0.020 0.020 0.011 5.489 111.709 1120-21-4 n-Undecane 0.030 0.030 0.015 8.135

I-Paraffins 8.810 75-28-5 i-Butane 0.052 0.069 0.071 13.823

10.638 463-82-1 2,2-Dimethylpropane 0.012 0.015 0.013 3.130 15.078 78-78-4 i-Pentane 4.183 5.000 4.586 1121.004 23.096 75-83-2 2,2-Dimethylbutane 0.094 0.107 0.086 25.259 28.340 79-29-8 2,3-Dimethylbutane 1.146 1.283 1.052 308.342 29.421 107-83-5 2-Methylpentane 2.676 3.034 2.456 719.907 32.069 96-14-0 3-Methylpentane 1.617 1.803 1.484 435.084 42.237 108-08-7 2,4-Dimethylpentane 0.820 0.903 0.647 221.463 42.781 464-06-2 2,2,3-Trimethylbutane 0.052 0.056 0.041 14.023 50.672 591-76-4 2-Methylhexane 1.518 1.657 1.198 410.084 52.492 589-34-4 3-Methylhexane 0.552 0.595 0.436 149.226 55.232 540-84-1 2,2,4-Trimethylpentane 11.022 11.796 7.632 2983.199 62.847 590-73-8 2,2-Dimethylhexane 0.027 0.028 0.018 7.211 64.950 564-02-3 2,2,3-Trimethylpentane 0.546 0.565 0.378 147.830 65.182 592-13-2 2,5-Dimethylhexane 1.242 1.326 0.860 336.147 65.519 589-43-5 2,4-Dimethylhexane 1.139 1.204 0.789 308.287 66.741 563-16-6 3,3-Dimethylhexane 0.019 0.020 0.013 5.067 68.509 565-75-3 2,3,4-Trimethylpentane 4.276 4.403 2.961 1157.167 69.188 560-21-4 2,3,3-Trimethylpentane 4.740 4.833 3.282 1282.747 70.799 584-94-1 2,3-Dimethylhexane 1.127 1.172 0.780 304.957 72.048 592-27-8 2-Methylheptane 0.243 0.258 0.168 65.714 72.310 589-53-7 4-Methylheptane 0.185 0.194 0.128 50.063 73.360 589-81-1 3-Methylheptane 0.210 0.220 0.145 56.789 73.561 619-99-8 3-Ethylhexane 0.100 0.104 0.069 27.147 75.260 3522-94-9 2,2,5-Trimethylhexane 1.994 2.088 1.230 540.830 80.353 1069-53-0 2,3,5-Trimethylhexane 0.330 0.338 0.203 89.373 81.518 1071-26-7 2,4-Dimethylheptane 0.069 0.072 0.043 18.763 82.473 1072-05-5 2,6-Dimethylheptane 0.105 0.109 0.065 28.373 83.404 2,5-Dimethylheptane 0.201 0.208 0.124 54.408 83.580 926-82-9 3,5-Dimethylheptane 0.024 0.025 0.015 6.558 86.751 3,5-Dimethylheptane 0.009 0.009 0.005 2.310 86.879 1067-20-5 3,3-Diethylpentane 0.008 0.007 0.005 2.038 87.272 2216-34-4 4-Methyloctane 0.047 0.048 0.029 12.776 87.404 3221-61-2 2-Methyloctane 0.063 0.065 0.039 17.010 88.106 15869-80-4 Heptane, 3-ethyl- 0.008 0.009 0.005 2.293 88.267 2216-33-3 3-Methyloctane 0.062 0.063 0.038 16.679 89.321 C10 - IsoParaffin - 1 0.344 0.350 0.191 93.372

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 90.164 14720-74-2 2,2,4-trimethylheptane 0.247 0.251 0.137 67.095

94.061 15869-87-1 2,2-Dimethyloctane 0.019 0.019 0.010 5.100 94.863 15869-89-3 2,5-Dimethyloctane 0.012 0.013 0.007 3.388 95.066 C10 - IsoParaffin - 2 0.007 0.007 0.004 1.960 95.504 2051-30-1 2,4-Dimethyloctane 0.022 0.022 0.012 6.003 95.891 2,6-Dimethyloctane 0.010 0.010 0.006 2.798 98.905 17301-94-8 4-Methylnonane 0.011 0.011 0.006 3.045 99.112 2,2,6-Trimethyloctane 0.344 0.351 0.191 93.565 99.884 5911-04-6 3-Methylnonane 0.015 0.015 0.008 3.948 100.696 C11-Isoparaffin-2 0.033 0.033 0.017 9.019 102.333 17302-01-1 3-Ethyl-3-methylheptane 0.061 0.061 0.031 16.694 104.406 C11 Isoparaffin-4 0.009 0.009 0.005 2.434 106.352 C11-Isoparaffin-7 0.152 0.152 0.077 41.437 108.561 C11- Isoparaffin-11 0.328 0.326 0.166 89.233 113.130 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.293 116.248 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.205

Aromatics Mono-Aromatics 45.635 71-42-3 Benzene 0.743 0.626 0.752 220.396

69.028 108-88-3 Toluene 5.029 4.295 4.317 1476.457 84.728 100-41-4 Ethylbenzene 0.894 0.764 0.666 260.567 85.952 108-38-3 m-Xylene 2.374 2.034 1.769 691.839 86.098 106-42-3 p-Xylene 1.058 0.910 0.789 308.408 88.926 95-47-6 o-Xylene 0.790 0.665 0.589 230.183 93.093 98-82-8 i-Propylbenzene 0.030 0.025 0.019 8.543 96.552 103-65-1 n-Propylbenzene 0.253 0.217 0.166 73.177 97.398 620-14-4 1-Methyl-3-ethylbenzene 0.954 0.817 0.628 276.302 97.631 622-96-8 1-Methyl-4-ethylbenzene 0.442 0.380 0.291 127.883 98.257 108-67-8 1,3,5-Trimethylbenzene 0.557 0.477 0.366 161.221 99.342 611-14-3 1-Methyl-2-ethylbenzene 0.325 0.273 0.214 94.131 100.972 95-63-6 1,2,4-Trimethylbenzene 1.526 1.290 1.004 441.812 102.647 538-93-2 i-Butylbenzene 0.073 0.063 0.043 21.031 103.847 526-73-8 1,2,3-Trimethylbenzene 0.190 0.158 0.125 55.090 104.212 535-77-3 1-Methyl-3-i-propylbenzene 0.008 0.007 0.005 2.444 104.614 99-87-6 1-Methyl-4-i-propylbenzene 0.062 0.053 0.036 17.809 106.545 141-93-5 1,3-Diethylbenzene 0.023 0.020 0.014 6.684 106.830 1074-43-7 1-Methyl-3-n-propylbenzene 0.479 0.412 0.282 137.958 107.157 105-05-5 1,4-Diethylbenzene 0.180 0.155 0.106 51.889 107.380 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.108 0.091 0.064 31.187 107.620 135-01-3 1,2-Diethylbenzene 0.039 0.033 0.023 11.236 108.232 1074-17-5 1-Methyl-2-n-propylbenzene 0.043 0.036 0.025 12.367 109.739 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.268 0.227 0.158 77.278 110.285 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.318 0.265 0.187 91.604 111.411 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.060 0.050 0.035 17.256 111.861 4218-48-8 1-Ethyl-4-i-propylbenzene 0.041 0.034 0.022 11.745 112.346 1,2,4,5-Tetramethylbenzene 0.204 0.170 0.120 58.779 112.613 527-53-7 1,2,3,5-Tetramethylbenzene 0.280 0.233 0.165 80.518

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 113.760 C11 - Aromatic - 3 0.050 0.041 0.027 14.268

114.069 1,2-Di-i-propylbenzene 0.033 0.028 0.016 9.526 114.284 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.045 0.037 0.024 12.876 114.448 C11 - Aromatic - 4 0.031 0.026 0.016 8.790 114.847 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.028 0.023 0.015 7.980 115.257 538-68-1 n-Pentylbenzene 0.011 0.009 0.006 3.227 115.484 tert-Pentylbenzene 0.046 0.039 0.025 13.291 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.020 0.017 0.011 5.802 115.908 C11 - Aromatic - 6 0.032 0.028 0.017 9.217 116.367 100-18-5 1,4-Di-i-propylbenzene 0.038 0.032 0.019 10.926 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.006 0.005 0.003 1.719 117.893 1,3-Di-n-propylbenzene 0.035 0.029 0.017 9.966 118.004 C11 - Aromatic - 11 0.019 0.016 0.010 5.362 118.557 C11 - Aromatic - 12 0.015 0.013 0.008 4.314

Naphthalenes 116.809 91-20-3 Naphthalene 0.112 0.081 0.069 33.752

123.440 91-57-6 2-Methylnaphthalene 0.011 0.008 0.006 3.391 124.305 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.596

Naphtheno/Olefino-Benzs

113.944 874-35-1 5-Methylindan 0.090 0.075 0.054 25.798 114.941 824-63-5 2-Methylindan 0.088 0.073 0.053 25.317

Indenes 105.043 Indan 0.070 0.054 0.047 20.739

105.637 Indene 0.365 0.281 0.245 107.521 109.393 2-Methylindan 0.056 0.043 0.034 16.550 114.693 824-22-6 4-Methylindan 0.115 0.096 0.069 33.114 117.409 Dimethyl Indane - 1 0.004 0.003 0.002 1.189

Naphthenes Mono-Naphthenes 27.605 287-92-3 Cyclopentane 0.150 0.149 0.169 41.421

40.669 96-37-7 Methylcyclopentane 1.028 1.017 0.966 283.247 47.552 110-82-7 Cyclohexane 0.474 0.450 0.445 130.535 53.353 1759-58-6 1t,3-Dimethylcyclopentane 0.152 0.150 0.122 41.855 53.940 2532-58-3 1c,3-Dimethylcyclopentane 0.117 0.116 0.094 32.205 54.566 822-50-4 1t,2-Dimethylcyclopentane 0.160 0.158 0.129 44.160 55.611 C7 - MonoNaph - 1 0.028 0.027 0.020 7.645 59.648 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 4.962 61.518 108-87-2 Methylcyclohexane 0.886 0.852 0.714 244.129 62.457 4516-69-2 1,1,3-Trimethylcyclopentane 0.027 0.026 0.019 7.338 64.294 1640-89-7 Ethylcyclopentane 0.049 0.047 0.039 13.470 66.349 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.027 0.026 0.019 7.392 67.862 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.024 0.023 0.017 6.647 73.224 1,3-dimethyl-t-cyclohexane 0.155 0.149 0.109 42.805 75.609 3c-Ethylmethylcyclopentane 0.009 0.009 0.006 2.528 75.826 3t-Ethylmethylcyclopentane 0.013 0.012 0.009 3.495 81.367 2207-01-4 1c,2-Dimethylcyclohexane 0.013 0.012 0.009 3.629 82.173 1678-91-7 Ethylcyclohexane 0.108 0.102 0.076 29.739

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 89.909 trans-1,3-Diethylcyclopentane 0.017 0.015 0.011 5.039

92.301 4926-90-3 1,1-Methylethylcyclohexane 0.012 0.011 0.008 3.438 101.548 1678-98-4 i-Butylcyclohexane 0.007 0.006 0.004 1.869

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.624 115-11-7 Isobutene 0.017 0.021 0.023 4.570

9.665 106-98-9 Butene-1 0.018 0.023 0.026 5.010 10.510 624-64-6 t-Butene-2 0.074 0.091 0.105 20.522 11.252 590-18-1 c-Butene-2 0.088 0.105 0.124 24.230 16.732 109-67-1 Pentene-1 0.338 0.391 0.381 93.178 19.234 646-04-8 t-Pentene-2 0.858 0.980 0.968 236.495 20.269 627-20-3 c-Pentene-2 0.470 0.531 0.530 129.585 33.446 592-41-6 Hexene-1 0.160 0.175 0.151 44.141 36.437 13269-52-8 t-Hexene-3 0.263 0.285 0.247 72.471 36.915 4050-45-7 t-Hexene-2 0.403 0.438 0.379 111.187 38.740 7688-21-3 c-Hexene-2 0.214 0.229 0.201 58.924 57.331 14686-14-7 t-Heptene-3 0.032 0.033 0.025 8.702 58.273 7642-10-6 c-Heptene-3 0.024 0.026 0.020 6.752 59.172 14686-13-6 t-Heptene-2 0.013 0.014 0.011 3.658 110.903 693-61-8 2-Undecene, (E)- 0.026 0.026 0.015 7.039

Iso-Olefins 13.453 563-45-1 3-Methylbutene-1 0.225 0.265 0.254 61.956

17.583 563-46-2 2-Methylbutene-1 0.514 0.585 0.579 141.572 20.945 513-35-9 2-Methylbutene-2 1.053 1.177 1.187 290.107 29.203 691-38-3 4-Methyl-c-pentene-2 0.046 0.051 0.044 12.794 29.842 674-76-0 4-Methyl-t-pentene-2 0.132 0.145 0.124 36.274 33.225 763-29-1 2-Methylpentene-1 0.224 0.243 0.211 61.862 35.641 760-21-4 2-Ethylbutene-1 0.069 0.074 0.065 19.089 37.410 625-27-4 2-Methylpentene-2 0.341 0.366 0.321 94.058 37.823 922-62-3 3-Methyl-c-pentene-2 0.264 0.280 0.248 72.747 40.084 3404-73-7 3,3-Dimethylpentene-1 0.308 0.325 0.248 85.004 42.535 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.014 0.011 3.669 46.640 3404-61-3 3-Methylhexene-1 0.015 0.016 0.012 4.234 47.228 3524-73-0 5-Methylhexene-1 0.042 0.044 0.034 11.469 49.271 15840-60-5 2-Methyl-c-hexene-3 0.040 0.043 0.032 11.089 49.619 3769-23-1 4-Methylhexene-1 0.011 0.011 0.009 3.003 50.265 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.053 0.041 13.947 54.899 C7 - Iso-Olefin - 2 0.021 0.022 0.017 5.859 56.802 4914-89-0 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.772 57.684 6094-02-6 2-Methylhexene-1 0.057 0.060 0.046 15.641 58.547 2738-19-4 2-Methyl-2-hexene 0.026 0.027 0.021 7.167 58.791 10574-36-4 3-Methyl-c-hexene-2 0.020 0.021 0.016 5.445 60.075 20710-38-8 3-Methyl-t-hexene-2 0.015 0.015 0.012 4.089 60.858 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 3.669 70.514 C8 - Diolefin - 1 0.010 0.010 0.007 2.769 80.905 C9 - IsoOlefin - 1 0.016 0.015 0.011 4.377

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 86.487 C9-IsoOlefin-3 0.014 0.014 0.009 3.924

Naphtheno-Olefins 22.537 1574-41-0 1,3-Cyclopentadiene 0.007 0.007 0.008 1.979

25.742 142-29-0 Cyclopentene 0.199 0.191 0.231 56.449 37.041 1120-62-3 3-Methylcyclopentene 0.101 0.098 0.097 27.771 45.833 693-89-0 1-Methylcyclopentene 0.359 0.341 0.346 101.275 51.153 110-83-8 Cyclohexene 0.044 0.040 0.043 12.219

Di-Olefins 18.625 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 3.013

21.270 2004-70-8 1t,3-Pentadiene 0.016 0.017 0.018 4.430 45.427 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 4.112

Oxygenates 13.126 64-17-5 Ethanol 22.540 21.154 38.700 2558.100

26.896 71-23-8 n-Propanol 0.081 0.075 0.106 15.535 48.058 71-36-3 n-Butanol 0.055 0.051 0.058 11.385

Unidentified 19.877 Unidentified 0.006 0.007 0.007 1.976

27.000 Unidentified 0.057 0.063 0.054 19.256 28.736 Unidentified 0.053 0.053 0.048 17.997 63.360 Unidentified 0.052 0.054 0.038 17.660 72.448 Unidentified 0.089 0.092 0.062 30.210 74.457 Unidentified 0.025 0.024 0.018 8.607 76.233 Unidentified 0.015 0.014 0.010 4.926 76.532 Unidentified 0.059 0.056 0.041 19.802 78.820 Unidentified 0.050 0.048 0.035 16.755 82.974 Unidentified 0.024 0.023 0.017 8.014 84.901 Unidentified 0.028 0.028 0.018 9.343 85.145 Unidentified 0.031 0.030 0.020 10.555 86.230 Unidentified 0.067 0.068 0.041 22.611 86.594 Unidentified 0.013 0.013 0.008 4.223 88.743 Unidentified 0.107 0.116 0.067 36.142 93.271 Unidentified 0.007 0.007 0.005 2.442 93.271 Unidentified 0.007 0.008 0.004 2.442 93.271 Unidentified 0.007 0.005 0.004 2.442 93.839 Unidentified 0.050 0.051 0.028 16.961 100.349 Unidentified 0.023 0.017 0.011 7.617 100.480 Unidentified 0.060 0.060 0.030 20.252 101.162 Unidentified 0.042 0.045 0.024 14.311 101.283 Unidentified 0.025 0.026 0.014 8.583 102.896 Unidentified 0.014 0.012 0.008 4.698 103.196 Unidentified 0.017 0.017 0.009 5.905 108.079 Unidentified 0.038 0.038 0.019 12.775 108.353 Unidentified 0.045 0.045 0.023 15.040 108.435 Unidentified 0.041 0.041 0.021 13.925 108.743 Unidentified 0.106 0.106 0.054 35.927 109.166 Unidentified 0.448 0.378 0.264 151.280 110.709 Unidentified 0.011 0.010 0.006 3.688

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 111.037 Unidentified 0.062 0.062 0.035 20.808

111.309 Unidentified 0.054 0.047 0.029 18.125 111.972 Unidentified 0.024 0.020 0.013 8.189 112.955 Unidentified 0.005 0.004 0.003 1.804 113.484 Unidentified 0.019 0.019 0.009 6.391 113.609 Unidentified 0.006 0.006 0.003 2.050 115.143 Unidentified 0.010 0.010 0.005 3.289 116.942 Unidentified 0.013 0.013 0.006 4.352 117.125 Unidentified 0.004 0.003 0.002 1.303 117.246 Unidentified 0.009 0.008 0.004 3.053 126.296 Unidentified 0.007 0.006 0.003 2.243 130.001 Unidentified 0.003 0.002 0.002 0.999

Plus

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1

n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified

c-Pentene-2

2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1

n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1

Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane C7 - MonoNaph - 1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane

2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene

p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane C10 - IsoParaffin - 2 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 6 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 01:11:34 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF Sample: ODDB-91324 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91324 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000006.D\SIG2000006_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 7.251 8.696 6.920

I-Paraffins 15.239 17.679 12.652

Aromatics 41.806 37.213 31.116 Mono-Aromatics 40.748 36.345 30.468 Naphthalenes 0.132 0.100 0.078 Naphtheno/Olefino-Benzs 0.220 0.191 0.128 Indenes 0.706 0.577 0.442

Naphthenes 5.215 5.296 4.455 Mono-Naphthenes 5.215 5.296 4.455 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.049 8.064 7.070 n-Olefins 2.900 3.403 3.005 Iso-Olefins 3.426 3.935 3.346 Naphtheno-Olefins 0.683 0.681 0.676 Di-Olefins 0.040 0.044 0.042

Oxygenates 22.006 21.592 36.603

Unidentified 1.433 1.459 1.183

Plus 0.000 0.000 0.000

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 21.878 21.468 36.452 C3 0.082 0.083 0.108 C4 1.214 1.593 1.596 C5 9.521 11.575 10.251 C6 13.490 15.037 12.201 C7 21.417 20.135 17.540 C8 18.508 17.133 13.227 C9 6.610 6.102 4.173 C10 5.022 4.653 2.854 C11 0.671 0.628 0.342 C12 0.153 0.133 0.073

Created with novaPDF Printer ( www.novaPDF.com ). Please register to remove this message.**Hydrocarbon Expert V4.7 Fri Aug 27 10:14:49 2010**  **Page 1**

25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.007 0.010 0.011 C4 0.926 1.238 1.223 C5 1.956 2.418 2.081 C6 2.865 3.364 2.552 C7 0.733 0.830 0.561 C8 0.518 0.571 0.348 C9 0.199 0.215 0.119 C10 0.029 0.030 0.015 C11 0.018 0.019 0.009

I-Paraffins C4 0.047 0.066 0.062 C5 3.824 4.778 4.068 C6 4.638 5.457 4.131 C7 1.899 2.159 1.455 C8 2.166 2.365 1.455 C9 1.003 1.090 0.600 C10 1.441 1.531 0.771 C11 0.222 0.231 0.109

Mono-Aromatics C6 0.663 0.584 0.652 C7 16.289 14.546 13.570 C8 15.366 13.738 11.110 C9 5.257 4.672 3.357 C10 2.642 2.339 1.511 C11 0.384 0.339 0.199 C12 0.147 0.128 0.069

Naphthalenes C10 0.118 0.089 0.071 C11 0.014 0.011 0.007

Naphtheno/Olefino-Benzs C10 0.220 0.191 0.128

Indenes C9 0.119 0.095 0.077 C10 0.560 0.460 0.351 C11 0.021 0.017 0.011 C12 0.007 0.005 0.004

Mono-Naphthenes C5 0.203 0.210 0.222 C6 2.805 2.854 2.558 C7 1.734 1.760 1.355 C8 0.429 0.430 0.294 C9 0.032 0.029 0.020

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.013 0.012 0.007

n-Olefins C4 0.187 0.238 0.256 C5 1.599 1.908 1.750 C6 1.006 1.140 0.918 C7 0.096 0.106 0.075 C11 0.012 0.012 0.006

Iso-Olefins C5 1.716 2.031 1.879 C6 1.028 1.156 0.938 C7 0.653 0.719 0.510 C8 0.029 0.029 0.020

Naphtheno-Olefins C5 0.198 0.199 0.223 C6 0.485 0.482 0.453

Di-Olefins C5 0.025 0.029 0.029 C7 0.014 0.015 0.014

Oxygenates C2 21.878 21.468 36.452 C3 0.076 0.073 0.096 C4 0.053 0.051 0.055

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 25.32 23.88 5% 81.75 80.87 10% 100.89 96.79 15% 144.75 138.31 20% 155.48 152.87 25% 172.32 158.64 30% 172.57 172.37 35% 172.82 172.62 40% 173.06 172.87 45% 174.18 173.12 50% 208.82 177.08 55% 230.78 212.13 60% 230.89 230.81 65% 231.01 230.94 70% 243.86 231.06 75% 278.85 276.87 80% 281.46 281.08 85% 282.32 282.07 90% 323.02 321.27 95% 350.79 340.83 FBP 403.88 399.78

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.554 74-98-6 P3 Propane 0.007 0.010 0.011 1.866 2 8.810 75-28-5 I4 i-Butane 0.047 0.066 0.062 13.628 3 9.624 115-11-7 K4 Isobutene 0.015 0.020 0.021 4.617 4 9.665 106-98-9 K4 Butene-1 0.017 0.023 0.024 5.177 5 10.024 106-97-8 P4 n-Butane 0.926 1.238 1.223 266.821 6 10.510 624-64-6 K4 t-Butene-2 0.071 0.091 0.097 21.138 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.011 0.015 0.012 3.299 8 11.250 590-18-1 K4 c-Butene-2 0.084 0.104 0.115 24.994 9 13.136 64-17-5 X2 Ethanol 21.878 21.468 36.452 2688.961 10 13.454 563-45-1 C5 3-Methylbutene-1 0.214 0.264 0.234 63.815

11 15.076 78-78-4 I5 i-Pentane 3.812 4.764 4.056 1106.312 12 16.728 109-67-1 K5 Pentene-1 0.324 0.392 0.355 96.787 13 17.579 563-46-2 C5 2-Methylbutene-1 0.492 0.586 0.539 146.973 14 18.114 109-66-0 P5 n-Pentane 1.956 2.418 2.081 567.543 15 18.629 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.012 0.011 3.130 16 19.235 646-04-8 K5 t-Pentene-2 0.823 0.983 0.901 245.725 17 19.876 ? Unidentified 0.006 0.007 0.006 2.085 18 20.264 627-20-3 K5 c-Pentene-2 0.451 0.533 0.494 134.738 19 20.946 513-35-9 C5 2-Methylbutene-2 1.010 1.181 1.106 301.538 20 21.271 2004-70-8 E5 1t,3-Pentadiene 0.015 0.018 0.017 4.700

21 22.541 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.008 2.088 22 23.095 75-83-2 I6 2,2-Dimethylbutane 0.126 0.150 0.112 36.741 23 25.745 142-29-0 B5 Cyclopentene 0.191 0.192 0.215 58.746 24 26.897 71-23-8 X3 n-Propanol 0.076 0.073 0.096 15.782 25 26.999 ? Unidentified 0.056 0.065 0.051 20.474 26 27.606 287-92-3 M5 Cyclopentane 0.203 0.210 0.222 60.480 27 28.335 79-29-8 I6 2,3-Dimethylbutane 0.449 0.525 0.400 130.697 28 28.734 ? Unidentified 0.054 0.056 0.047 19.662 29 29.190 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.051 0.041 13.314 30 29.422 107-83-5 I6 2-Methylpentane 2.318 2.748 2.065 675.380

31 29.836 674-76-0 C6 4-Methyl-t-pentene-2 0.127 0.146 0.116 37.802 32 32.063 96-14-0 I6 3-Methylpentane 1.745 2.034 1.554 508.409 33 33.224 763-29-1 C6 2-Methylpentene-1 0.216 0.245 0.197 64.584 34 33.448 592-41-6 K6 Hexene-1 0.155 0.177 0.141 46.181 35 35.649 760-21-4 C6 2-Ethylbutene-1 0.057 0.063 0.052 16.939 36 35.812 110-54-3 P6 n-Hexane 2.865 3.364 2.552 834.756 37 36.444 13269-52-8 K6 t-Hexene-3 0.254 0.288 0.232 75.829 38 36.913 4050-45-7 K6 t-Hexene-2 0.391 0.443 0.356 116.663 39 37.040 1120-62-3 B6 3-Methylcyclopentene 0.096 0.097 0.089 28.535 40 37.405 625-27-4 C6 2-Methylpentene-2 0.329 0.369 0.300 98.243

41 37.819 922-62-3 C6 3-Methyl-c-pentene-2 0.255 0.282 0.232 75.981 42 38.740 7688-21-3 K6 c-Hexene-2 0.207 0.231 0.189 61.700 43 40.086 3404-73-7 C7 3,3-Dimethylpentene-1 0.297 0.328 0.232 88.758

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.671 96-37-7 M6 Methylcyclopentane 1.630 1.686 1.487 486.537 45 42.230 108-08-7 I7 2,4-Dimethylpentane 0.278 0.320 0.213 81.360 46 42.529 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.014 0.010 3.926 47 42.776 464-06-2 I7 2,2,3-Trimethylbutane 0.037 0.042 0.029 10.886 48 45.422 1528-30-9 E7 C6-Diolefin-1 0.014 0.015 0.014 4.320 49 45.633 71-42-3 Q6 Benzene 0.663 0.584 0.652 213.261 50 45.832 693-89-0 B6 1-Methylcyclopentene 0.346 0.344 0.324 105.906 51 46.635 3404-61-3 C7 3-Methylhexene-1 0.015 0.017 0.012 4.448 52 47.233 3524-73-0 C7 5-Methylhexene-1 0.068 0.075 0.053 20.179 53 47.555 110-82-7 M6 Cyclohexane 1.175 1.168 1.071 350.637

54 48.053 71-36-3 X4 n-Butanol 0.053 0.051 0.055 11.979 55 49.270 15840-60-5 C7 2-Methyl-c-hexene-3 0.039 0.043 0.030 11.625 56 49.617 3769-23-1 C7 4-Methylhexene-1 0.010 0.011 0.008 3.058 57 50.265 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.049 0.054 0.038 14.576 58 50.659 591-76-4 I7 2-Methylhexane 0.946 1.080 0.725 276.837 59 50.838 ? Unidentified 0.063 0.071 0.051 23.206 60 51.151 110-83-8 B6 Cyclohexene 0.043 0.041 0.040 12.780 61 52.491 589-34-4 I7 3-Methylhexane 0.637 0.718 0.488 186.352 62 53.351 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.179 0.185 0.140 53.382 63 53.936 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.141 0.146 0.110 42.044

64 54.559 822-50-4 M7 1t,2-Dimethylcyclopentane 0.206 0.213 0.161 61.581 65 54.839 C7 C7 - Iso-Olefin - 2 0.021 0.023 0.017 6.409 66 55.142 540-84-1 I8 2,2,4-Trimethylpentane 0.058 0.065 0.039 16.961 67 55.466 592-76-7 K7 Heptene-1 0.028 0.031 0.022 8.311 68 56.799 4914-89-0 C7 3-Methyl-c-hexene-3 0.013 0.014 0.011 4.010 69 57.329 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.024 9.204 70 57.681 6094-02-6 C7 2-Methylhexene-1 0.055 0.061 0.043 16.479 71 58.055 142-82-5 P7 n-Heptane 0.733 0.830 0.561 214.390 72 58.272 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.019 7.071 73 58.546 2738-19-4 C7 2-Methyl-2-hexene 0.025 0.027 0.020 7.518

74 58.790 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.684 75 59.171 14686-13-6 K7 t-Heptene-2 0.013 0.015 0.010 3.986 76 59.647 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.014 5.299 77 60.075 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.012 4.412 78 60.858 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.010 3.732 79 61.519 108-87-2 M7 Methylcyclohexane 1.134 1.141 0.887 338.516 80 62.457 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.032 0.033 0.022 9.620 81 62.846 590-73-8 I8 2,2-Dimethylhexane 0.027 0.030 0.018 8.017 82 63.357 ? Unidentified 0.051 0.055 0.035 18.600 83 64.294 1640-89-7 M7 Ethylcyclopentane 0.056 0.056 0.044 16.693

84 64.943 564-02-3 I8 2,2,3-Trimethylpentane 0.074 0.080 0.050 21.734 85 65.167 592-13-2 I8 2,5-Dimethylhexane 0.169 0.189 0.113 49.503 86 65.504 589-43-5 I8 2,4-Dimethylhexane 0.163 0.180 0.110 47.824

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.343 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.032 0.032 0.022 9.483 88 66.738 563-16-6 I8 3,3-Dimethylhexane 0.021 0.023 0.014 6.121 89 67.859 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.028 0.028 0.019 8.316 90 68.482 565-75-3 I8 2,3,4-Trimethylpentane 0.757 0.815 0.509 221.852 91 69.109 108-88-3 Q7 Toluene 16.289 14.546 13.570 5179.291 92 70.516 C8 C8 - Diolefin - 1 0.012 0.012 0.008 3.613 93 70.793 584-94-1 I8 2,3-Dimethylhexane 0.241 0.261 0.162 70.493 94 72.046 592-27-8 I8 2-Methylheptane 0.237 0.263 0.159 69.534 95 72.301 589-53-7 I8 4-Methylheptane 0.106 0.117 0.071 31.095 96 72.449 ? Unidentified 0.022 0.023 0.015 7.948

97 73.223 M8 1,3-dimethyl-t-cyclohexane 0.178 0.179 0.122 53.236 98 73.360 589-81-1 I8 3-Methylheptane 0.202 0.221 0.135 59.078 99 73.561 619-99-8 I8 3-Ethylhexane 0.111 0.121 0.075 32.604 100 74.456 ? Unidentified 0.029 0.028 0.020 10.431 101 75.247 3522-94-9 I9 2,2,5-Trimethylhexane 0.495 0.542 0.296 145.426 102 75.607 M8 3c-Ethylmethylcyclopentane 0.010 0.010 0.007 3.089 103 75.823 M8 3t-Ethylmethylcyclopentane 0.015 0.015 0.010 4.405 104 76.528 ? Unidentified 0.065 0.065 0.044 23.653 105 77.869 111-65-9 P8 n-Octane 0.518 0.571 0.348 151.827 106 78.822 ? Unidentified 0.015 0.015 0.010 5.428

107 80.350 1069-53-0 I9 2,3,5-Trimethylhexane 0.089 0.095 0.053 26.029 108 80.905 C8 C9 - IsoOlefin - 1 0.017 0.017 0.012 5.132 109 81.364 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.015 0.014 0.010 4.332 110 81.519 1071-26-7 I9 2,4-Dimethylheptane 0.036 0.039 0.022 10.576 111 82.172 1678-91-7 M8 Ethylcyclohexane 0.119 0.118 0.082 35.624 112 82.474 1072-05-5 I9 2,6-Dimethylheptane 0.063 0.069 0.038 18.495 113 82.973 ? Unidentified 0.023 0.023 0.016 8.474 114 83.408 I9 2,5-Dimethylheptane 0.099 0.107 0.059 28.974 115 83.599 926-82-9 I9 3,5-Dimethylheptane 0.018 0.019 0.011 5.227 116 84.747 100-41-4 Q8 Ethylbenzene 2.730 2.437 1.973 861.317

117 85.154 ? Unidentified 0.017 0.017 0.010 6.281 118 86.002 108-38-3 Q8 m-Xylene 7.325 6.562 5.296 2311.502 119 86.140 106-42-3 Q8 p-Xylene 3.381 3.040 2.444 1066.798 120 86.596 ? Unidentified 0.012 0.012 0.007 4.383 121 86.762 I9 3,5-Dimethylheptane 0.010 0.010 0.006 2.838 122 86.881 1067-20-5 I9 3,3-Diethylpentane 0.008 0.008 0.005 2.329 123 87.276 2216-34-4 I9 4-Methyloctane 0.049 0.052 0.029 14.291 124 87.407 3221-61-2 I9 2-Methyloctane 0.064 0.070 0.039 18.913 125 88.107 15869-80-4 I9 Heptane, 3-ethyl- 0.009 0.010 0.006 2.721 126 88.269 2216-33-3 I9 3-Methyloctane 0.064 0.069 0.038 18.740

127 88.745 ? Unidentified 0.033 0.037 0.020 11.959 128 88.941 95-47-6 Q8 o-Xylene 1.930 1.698 1.396 609.177 129 89.320 I10 C10 - IsoParaffin - 1 0.106 0.113 0.057 31.178

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 89.910 M9 trans-1,3-Diethylcyclopentane 0.019 0.017 0.012 6.149 131 90.165 14720-74-2 I10 2,2,4-trimethylheptane 0.088 0.093 0.047 25.752 132 91.741 111-84-2 P9 n-Nonane 0.199 0.215 0.119 58.575 133 92.299 4926-90-3 M9 1,1-Methylethylcyclohexane 0.013 0.012 0.008 3.841 134 93.093 98-82-8 Q9 i-Propylbenzene 0.032 0.028 0.020 9.888 135 93.838 ? Unidentified 0.048 0.052 0.026 17.710 136 94.061 15869-87-1 I10 2,2-Dimethyloctane 0.020 0.021 0.011 5.885 137 94.524 ? Unidentified 0.004 0.003 0.337 1.604 138 94.524 ? Unidentified 0.004 0.005 0.002 1.604 139 94.861 15869-89-3 I10 2,5-Dimethyloctane 0.031 0.033 0.017 9.035

140 95.066 I10 C10 - IsoParaffin - 2 0.011 0.011 0.006 3.153 141 95.326 2040-95-1 I10 2,7-Dimethyloctane 0.015 0.016 0.008 4.522 142 95.504 2051-30-1 I10 2,4-Dimethyloctane 0.061 0.065 0.033 17.847 143 95.892 I10 2,6-Dimethyloctane 0.021 0.022 0.011 6.175 144 96.552 103-65-1 Q9 n-Propylbenzene 0.287 0.258 0.183 90.070 145 97.400 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.108 0.992 0.708 347.428 146 97.634 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.514 0.462 0.328 161.116 147 98.259 108-67-8 Q9 1,3,5-Trimethylbenzene 0.684 0.612 0.437 214.426 148 98.717 15869-85-9 I10 5-Methylnonane 0.006 0.007 0.003 1.877 149 98.906 17301-94-8 I10 4-Methylnonane 0.015 0.016 0.008 4.450

150 99.117 I10 2,2,6-Trimethyloctane 0.922 0.983 0.498 271.438 151 99.343 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.383 0.337 0.245 120.200 152 99.885 5911-04-6 I10 3-Methylnonane 0.018 0.019 0.010 5.214 153 100.350 ? Unidentified 0.052 0.040 0.026 19.071 154 100.482 ? Unidentified 0.143 0.149 0.070 52.277 155 100.697 I11 C11-Isoparaffin-2 0.076 0.079 0.037 22.299 156 100.979 95-63-6 Q9 1,2,4-Trimethylbenzene 1.943 1.718 1.241 609.157 157 101.163 ? Unidentified 0.086 0.095 0.047 31.626 158 101.284 ? Unidentified 0.051 0.054 0.028 18.710 159 101.548 1678-98-4 M10 i-Butylcyclohexane 0.013 0.012 0.007 3.746

160 102.334 17302-01-1 I10 3-Ethyl-3-methylheptane 0.128 0.133 0.063 37.565 161 102.669 538-93-2 Q10 i-Butylbenzene 0.160 0.145 0.092 49.942 162 102.896 124-18-5 P10 n-Decane 0.029 0.030 0.015 8.448 163 103.196 ? Unidentified 0.029 0.030 0.016 10.658 164 103.849 526-73-8 Q9 1,2,3-Trimethylbenzene 0.306 0.265 0.195 95.835 165 104.209 ? Unidentified 0.010 0.009 0.006 3.688 166 104.408 I11 C11 Isoparaffin-4 0.013 0.014 0.007 3.972 167 104.614 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.083 0.075 0.047 25.874 168 105.042 J9 Indan 0.119 0.095 0.077 37.792 169 105.638 J10 Indene 0.374 0.300 0.243 119.045

170 106.352 I11 C11-Isoparaffin-7 0.133 0.138 0.065 39.196 171 106.546 141-93-5 Q10 1,3-Diethylbenzene 0.040 0.036 0.023 12.407 172 106.827 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.491 0.442 0.281 153.197

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 107.162 105-05-5 Q10 1,4-Diethylbenzene 0.188 0.168 0.107 58.495 174 107.380 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.147 0.130 0.084 45.929 175 107.624 135-01-3 Q10 1,2-Diethylbenzene 0.030 0.027 0.017 9.484 176 108.078 ? Unidentified 0.028 0.029 0.014 10.060 177 108.231 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.053 0.047 0.031 16.653 178 108.353 ? Unidentified 0.029 0.025 0.019 10.719 179 108.434 ? Unidentified 0.027 0.028 0.013 9.784 180 108.560 ? Unidentified 0.180 0.187 0.088 65.669 181 108.742 ? Unidentified 0.069 0.072 0.034 25.298 182 109.076 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.119 0.105 0.068 37.101

183 109.165 ? Unidentified 0.170 0.150 0.097 62.321 184 109.235 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.127 0.112 0.073 39.538 185 109.393 J10 2-Methylindan 0.040 0.032 0.023 12.672 186 109.740 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.318 0.281 0.182 99.069 187 110.284 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.172 0.149 0.098 53.519 188 110.708 ? Unidentified 0.004 0.004 0.002 1.621 189 110.903 693-61-8 K11 2-Undecene, (E)- 0.012 0.012 0.006 3.442 190 111.037 ? Unidentified 0.016 0.017 0.009 5.995 191 111.193 Q11 1-Methyl-4-t-butylbenzene 0.026 0.023 0.013 7.982 192 111.413 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.107 0.093 0.061 33.341

193 111.708 1120-21-4 P11 n-Undecane 0.018 0.019 0.009 5.443 194 111.863 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.022 0.019 0.011 6.819 195 111.971 ? Unidentified 0.010 0.009 0.005 3.782 196 112.347 Q10 1,2,4,5-Tetramethylbenzene 0.254 0.222 0.145 79.201 197 112.613 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.353 0.307 0.202 110.152 198 113.481 ? Unidentified 0.013 0.013 0.006 4.607 199 113.753 Q11 C11 - Aromatic - 3 0.040 0.035 0.021 12.375 200 113.944 874-35-1 H10 5-Methylindan 0.109 0.095 0.063 34.083 201 114.069 Q12 1,2-Di-i-propylbenzene 0.039 0.034 0.019 12.169 202 114.284 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.057 0.049 0.029 17.602

203 114.440 Q11 C11 - Aromatic - 4 0.031 0.027 0.016 9.692 204 114.693 824-22-6 J10 4-Methylindan 0.147 0.128 0.085 45.715 205 114.845 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.034 0.030 0.018 10.541 206 114.941 824-63-5 H10 2-Methylindan 0.111 0.096 0.064 34.543 207 115.144 ? Unidentified 0.010 0.010 0.005 3.652 208 115.257 538-68-1 Q11 n-Pentylbenzene 0.013 0.012 0.007 4.185 209 115.484 Q11 tert-Pentylbenzene 0.060 0.052 0.031 18.533 210 115.797 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.027 0.023 0.014 8.262 211 115.906 Q11 C11 - Aromatic - 6 0.033 0.030 0.017 10.235 212 116.367 100-18-5 Q12 1,4-Di-i-propylbenzene 0.050 0.043 0.023 15.327

213 116.810 91-20-3 G10 Naphthalene 0.118 0.089 0.071 38.577 214 117.006 J11 4,7-Dimethyl Indane 0.005 0.004 0.003 1.713 215 117.250 J11 1,1-Dimethyl Indane 0.015 0.012 0.008 4.934

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 117.412 J12 Dimethyl Indane - 1 0.007 0.005 0.004 2.140 217 117.591 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.009 0.008 0.004 2.898 218 117.893 Q12 1,3-Di-n-propylbenzene 0.044 0.038 0.021 13.687 219 118.004 Q11 C11 - Aromatic - 11 0.025 0.023 0.013 7.830 220 118.557 Q11 C11 - Aromatic - 12 0.017 0.016 0.009 5.315 221 119.485 102-25-0 Q12 1,3,5-Triethylbenzene 0.004 0.004 0.002 1.355 222 123.438 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.005 2.903 223 124.304 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.589 224 130.001 ? Unidentified 0.003 0.002 0.001 1.023

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.007 0.010 0.011 1.866

10.024 106-97-8 n-Butane 0.926 1.238 1.223 266.821 18.114 109-66-0 n-Pentane 1.956 2.418 2.081 567.543 35.812 110-54-3 n-Hexane 2.865 3.364 2.552 834.756 58.055 142-82-5 n-Heptane 0.733 0.830 0.561 214.390 77.869 111-65-9 n-Octane 0.518 0.571 0.348 151.827 91.741 111-84-2 n-Nonane 0.199 0.215 0.119 58.575 102.896 124-18-5 n-Decane 0.029 0.030 0.015 8.448 111.708 1120-21-4 n-Undecane 0.018 0.019 0.009 5.443

I-Paraffins 8.810 75-28-5 i-Butane 0.047 0.066 0.062 13.628

10.637 463-82-1 2,2-Dimethylpropane 0.011 0.015 0.012 3.299 15.076 78-78-4 i-Pentane 3.812 4.764 4.056 1106.312 23.095 75-83-2 2,2-Dimethylbutane 0.126 0.150 0.112 36.741 28.335 79-29-8 2,3-Dimethylbutane 0.449 0.525 0.400 130.697 29.422 107-83-5 2-Methylpentane 2.318 2.748 2.065 675.380 32.063 96-14-0 3-Methylpentane 1.745 2.034 1.554 508.409 42.230 108-08-7 2,4-Dimethylpentane 0.278 0.320 0.213 81.360 42.776 464-06-2 2,2,3-Trimethylbutane 0.037 0.042 0.029 10.886 50.659 591-76-4 2-Methylhexane 0.946 1.080 0.725 276.837 52.491 589-34-4 3-Methylhexane 0.637 0.718 0.488 186.352 55.142 540-84-1 2,2,4-Trimethylpentane 0.058 0.065 0.039 16.961 62.846 590-73-8 2,2-Dimethylhexane 0.027 0.030 0.018 8.017 64.943 564-02-3 2,2,3-Trimethylpentane 0.074 0.080 0.050 21.734 65.167 592-13-2 2,5-Dimethylhexane 0.169 0.189 0.113 49.503 65.504 589-43-5 2,4-Dimethylhexane 0.163 0.180 0.110 47.824 66.738 563-16-6 3,3-Dimethylhexane 0.021 0.023 0.014 6.121 68.482 565-75-3 2,3,4-Trimethylpentane 0.757 0.815 0.509 221.852 70.793 584-94-1 2,3-Dimethylhexane 0.241 0.261 0.162 70.493 72.046 592-27-8 2-Methylheptane 0.237 0.263 0.159 69.534 72.301 589-53-7 4-Methylheptane 0.106 0.117 0.071 31.095 73.360 589-81-1 3-Methylheptane 0.202 0.221 0.135 59.078 73.561 619-99-8 3-Ethylhexane 0.111 0.121 0.075 32.604 75.247 3522-94-9 2,2,5-Trimethylhexane 0.495 0.542 0.296 145.426 80.350 1069-53-0 2,3,5-Trimethylhexane 0.089 0.095 0.053 26.029 81.519 1071-26-7 2,4-Dimethylheptane 0.036 0.039 0.022 10.576 82.474 1072-05-5 2,6-Dimethylheptane 0.063 0.069 0.038 18.495 83.408 2,5-Dimethylheptane 0.099 0.107 0.059 28.974 83.599 926-82-9 3,5-Dimethylheptane 0.018 0.019 0.011 5.227 86.762 3,5-Dimethylheptane 0.010 0.010 0.006 2.838 86.881 1067-20-5 3,3-Diethylpentane 0.008 0.008 0.005 2.329 87.276 2216-34-4 4-Methyloctane 0.049 0.052 0.029 14.291 87.407 3221-61-2 2-Methyloctane 0.064 0.070 0.039 18.913 88.107 15869-80-4 Heptane, 3-ethyl- 0.009 0.010 0.006 2.721 88.269 2216-33-3 3-Methyloctane 0.064 0.069 0.038 18.740 89.320 C10 - IsoParaffin - 1 0.106 0.113 0.057 31.178 90.165 14720-74-2 2,2,4-trimethylheptane 0.088 0.093 0.047 25.752

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 94.061 15869-87-1 2,2-Dimethyloctane 0.020 0.021 0.011 5.885

94.861 15869-89-3 2,5-Dimethyloctane 0.031 0.033 0.017 9.035 95.066 C10 - IsoParaffin - 2 0.011 0.011 0.006 3.153 95.326 2040-95-1 2,7-Dimethyloctane 0.015 0.016 0.008 4.522 95.504 2051-30-1 2,4-Dimethyloctane 0.061 0.065 0.033 17.847 95.892 2,6-Dimethyloctane 0.021 0.022 0.011 6.175 98.717 15869-85-9 5-Methylnonane 0.006 0.007 0.003 1.877 98.906 17301-94-8 4-Methylnonane 0.015 0.016 0.008 4.450 99.117 2,2,6-Trimethyloctane 0.922 0.983 0.498 271.438 99.885 5911-04-6 3-Methylnonane 0.018 0.019 0.010 5.214 100.697 C11-Isoparaffin-2 0.076 0.079 0.037 22.299 102.334 17302-01-1 3-Ethyl-3-methylheptane 0.128 0.133 0.063 37.565 104.408 C11 Isoparaffin-4 0.013 0.014 0.007 3.972 106.352 C11-Isoparaffin-7 0.133 0.138 0.065 39.196

Aromatics Mono-Aromatics 45.633 71-42-3 Benzene 0.663 0.584 0.652 213.261

69.109 108-88-3 Toluene 16.289 14.546 13.570 5179.291 84.747 100-41-4 Ethylbenzene 2.730 2.437 1.973 861.317 86.002 108-38-3 m-Xylene 7.325 6.562 5.296 2311.502 86.140 106-42-3 p-Xylene 3.381 3.040 2.444 1066.798 88.941 95-47-6 o-Xylene 1.930 1.698 1.396 609.177 93.093 98-82-8 i-Propylbenzene 0.032 0.028 0.020 9.888 96.552 103-65-1 n-Propylbenzene 0.287 0.258 0.183 90.070 97.400 620-14-4 1-Methyl-3-ethylbenzene 1.108 0.992 0.708 347.428 97.634 622-96-8 1-Methyl-4-ethylbenzene 0.514 0.462 0.328 161.116 98.259 108-67-8 1,3,5-Trimethylbenzene 0.684 0.612 0.437 214.426 99.343 611-14-3 1-Methyl-2-ethylbenzene 0.383 0.337 0.245 120.200 100.979 95-63-6 1,2,4-Trimethylbenzene 1.943 1.718 1.241 609.157 102.669 538-93-2 i-Butylbenzene 0.160 0.145 0.092 49.942 103.849 526-73-8 1,2,3-Trimethylbenzene 0.306 0.265 0.195 95.835 104.614 99-87-6 1-Methyl-4-i-propylbenzene 0.083 0.075 0.047 25.874 106.546 141-93-5 1,3-Diethylbenzene 0.040 0.036 0.023 12.407 106.827 1074-43-7 1-Methyl-3-n-propylbenzene 0.491 0.442 0.281 153.197 107.162 105-05-5 1,4-Diethylbenzene 0.188 0.168 0.107 58.495 107.380 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.147 0.130 0.084 45.929 107.624 135-01-3 1,2-Diethylbenzene 0.030 0.027 0.017 9.484 108.231 1074-17-5 1-Methyl-2-n-propylbenzene 0.053 0.047 0.031 16.653 109.076 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.119 0.105 0.068 37.101 109.235 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.127 0.112 0.073 39.538 109.740 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.318 0.281 0.182 99.069 110.284 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.172 0.149 0.098 53.519 111.193 1-Methyl-4-t-butylbenzene 0.026 0.023 0.013 7.982 111.413 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.107 0.093 0.061 33.341 111.863 4218-48-8 1-Ethyl-4-i-propylbenzene 0.022 0.019 0.011 6.819 112.347 1,2,4,5-Tetramethylbenzene 0.254 0.222 0.145 79.201 112.613 527-53-7 1,2,3,5-Tetramethylbenzene 0.353 0.307 0.202 110.152

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 113.753 C11 - Aromatic - 3 0.040 0.035 0.021 12.375

114.069 1,2-Di-i-propylbenzene 0.039 0.034 0.019 12.169 114.284 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.057 0.049 0.029 17.602 114.440 C11 - Aromatic - 4 0.031 0.027 0.016 9.692 114.845 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.034 0.030 0.018 10.541 115.257 538-68-1 n-Pentylbenzene 0.013 0.012 0.007 4.185 115.484 tert-Pentylbenzene 0.060 0.052 0.031 18.533 115.797 577-55-9 1-Methyl-2-n-butylbenzene 0.027 0.023 0.014 8.262 115.906 C11 - Aromatic - 6 0.033 0.030 0.017 10.235 116.367 100-18-5 1,4-Di-i-propylbenzene 0.050 0.043 0.023 15.327 117.591 7364-19-4 1t-Butyl-4-ethylbenzene 0.009 0.008 0.004 2.898 117.893 1,3-Di-n-propylbenzene 0.044 0.038 0.021 13.687 118.004 C11 - Aromatic - 11 0.025 0.023 0.013 7.830 118.557 C11 - Aromatic - 12 0.017 0.016 0.009 5.315 119.485 102-25-0 1,3,5-Triethylbenzene 0.004 0.004 0.002 1.355

Naphthalenes 116.810 91-20-3 Naphthalene 0.118 0.089 0.071 38.577

123.438 91-57-6 2-Methylnaphthalene 0.009 0.007 0.005 2.903 124.304 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.589

Naphtheno/Olefino-Benzs

113.944 874-35-1 5-Methylindan 0.109 0.095 0.063 34.083 114.941 824-63-5 2-Methylindan 0.111 0.096 0.064 34.543

Indenes 105.042 Indan 0.119 0.095 0.077 37.792

105.638 Indene 0.374 0.300 0.243 119.045 109.393 2-Methylindan 0.040 0.032 0.023 12.672 114.693 824-22-6 4-Methylindan 0.147 0.128 0.085 45.715 117.006 4,7-Dimethyl Indane 0.005 0.004 0.003 1.713 117.250 1,1-Dimethyl Indane 0.015 0.012 0.008 4.934 117.412 Dimethyl Indane - 1 0.007 0.005 0.004 2.140

Naphthenes Mono-Naphthenes 27.606 287-92-3 Cyclopentane 0.203 0.210 0.222 60.480

40.671 96-37-7 Methylcyclopentane 1.630 1.686 1.487 486.537 47.555 110-82-7 Cyclohexane 1.175 1.168 1.071 350.637 53.351 1759-58-6 1t,3-Dimethylcyclopentane 0.179 0.185 0.140 53.382 53.936 2532-58-3 1c,3-Dimethylcyclopentane 0.141 0.146 0.110 42.044 54.559 822-50-4 1t,2-Dimethylcyclopentane 0.206 0.213 0.161 61.581 59.647 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.014 5.299 61.519 108-87-2 Methylcyclohexane 1.134 1.141 0.887 338.516 62.457 4516-69-2 1,1,3-Trimethylcyclopentane 0.032 0.033 0.022 9.620 64.294 1640-89-7 Ethylcyclopentane 0.056 0.056 0.044 16.693 66.343 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.032 0.032 0.022 9.483 67.859 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.028 0.028 0.019 8.316 73.223 1,3-dimethyl-t-cyclohexane 0.178 0.179 0.122 53.236 75.607 3c-Ethylmethylcyclopentane 0.010 0.010 0.007 3.089 75.823 3t-Ethylmethylcyclopentane 0.015 0.015 0.010 4.405

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 81.364 2207-01-4 1c,2-Dimethylcyclohexane 0.015 0.014 0.010 4.332

82.172 1678-91-7 Ethylcyclohexane 0.119 0.118 0.082 35.624 89.910 trans-1,3-Diethylcyclopentane 0.019 0.017 0.012 6.149 92.299 4926-90-3 1,1-Methylethylcyclohexane 0.013 0.012 0.008 3.841 101.548 1678-98-4 i-Butylcyclohexane 0.013 0.012 0.007 3.746

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.624 115-11-7 Isobutene 0.015 0.020 0.021 4.617

9.665 106-98-9 Butene-1 0.017 0.023 0.024 5.177 10.510 624-64-6 t-Butene-2 0.071 0.091 0.097 21.138 11.250 590-18-1 c-Butene-2 0.084 0.104 0.115 24.994 16.728 109-67-1 Pentene-1 0.324 0.392 0.355 96.787 19.235 646-04-8 t-Pentene-2 0.823 0.983 0.901 245.725 20.264 627-20-3 c-Pentene-2 0.451 0.533 0.494 134.738 33.448 592-41-6 Hexene-1 0.155 0.177 0.141 46.181 36.444 13269-52-8 t-Hexene-3 0.254 0.288 0.232 75.829 36.913 4050-45-7 t-Hexene-2 0.391 0.443 0.356 116.663 38.740 7688-21-3 c-Hexene-2 0.207 0.231 0.189 61.700 55.466 592-76-7 Heptene-1 0.028 0.031 0.022 8.311 57.329 14686-14-7 t-Heptene-3 0.031 0.034 0.024 9.204 58.272 7642-10-6 c-Heptene-3 0.024 0.026 0.019 7.071 59.171 14686-13-6 t-Heptene-2 0.013 0.015 0.010 3.986 110.903 693-61-8 2-Undecene, (E)- 0.012 0.012 0.006 3.442

Iso-Olefins 13.454 563-45-1 3-Methylbutene-1 0.214 0.264 0.234 63.815

17.579 563-46-2 2-Methylbutene-1 0.492 0.586 0.539 146.973 20.946 513-35-9 2-Methylbutene-2 1.010 1.181 1.106 301.538 29.190 691-38-3 4-Methyl-c-pentene-2 0.045 0.051 0.041 13.314 29.836 674-76-0 4-Methyl-t-pentene-2 0.127 0.146 0.116 37.802 33.224 763-29-1 2-Methylpentene-1 0.216 0.245 0.197 64.584 35.649 760-21-4 2-Ethylbutene-1 0.057 0.063 0.052 16.939 37.405 625-27-4 2-Methylpentene-2 0.329 0.369 0.300 98.243 37.819 922-62-3 3-Methyl-c-pentene-2 0.255 0.282 0.232 75.981 40.086 3404-73-7 3,3-Dimethylpentene-1 0.297 0.328 0.232 88.758 42.529 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.014 0.010 3.926 46.635 3404-61-3 3-Methylhexene-1 0.015 0.017 0.012 4.448 47.233 3524-73-0 5-Methylhexene-1 0.068 0.075 0.053 20.179 49.270 15840-60-5 2-Methyl-c-hexene-3 0.039 0.043 0.030 11.625 49.617 3769-23-1 4-Methylhexene-1 0.010 0.011 0.008 3.058 50.265 3404-55-5 4-Methyl-t/c-hexene-2 0.049 0.054 0.038 14.576 54.839 C7 - Iso-Olefin - 2 0.021 0.023 0.017 6.409 56.799 4914-89-0 3-Methyl-c-hexene-3 0.013 0.014 0.011 4.010 57.681 6094-02-6 2-Methylhexene-1 0.055 0.061 0.043 16.479 58.546 2738-19-4 2-Methyl-2-hexene 0.025 0.027 0.020 7.518 58.790 10574-36-4 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.684 60.075 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.012 4.412

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 60.858 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.010 3.732

70.516 C8 - Diolefin - 1 0.012 0.012 0.008 3.613 80.905 C9 - IsoOlefin - 1 0.017 0.017 0.012 5.132

Naphtheno-Olefins 22.541 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.008 2.088

25.745 142-29-0 Cyclopentene 0.191 0.192 0.215 58.746 37.040 1120-62-3 3-Methylcyclopentene 0.096 0.097 0.089 28.535 45.832 693-89-0 1-Methylcyclopentene 0.346 0.344 0.324 105.906 51.151 110-83-8 Cyclohexene 0.043 0.041 0.040 12.780

Di-Olefins 18.629 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.012 0.011 3.130

21.271 2004-70-8 1t,3-Pentadiene 0.015 0.018 0.017 4.700 45.422 1528-30-9 C6-Diolefin-1 0.014 0.015 0.014 4.320

Oxygenates 13.136 64-17-5 Ethanol 21.878 21.468 36.452 2688.961

26.897 71-23-8 n-Propanol 0.076 0.073 0.096 15.782 48.053 71-36-3 n-Butanol 0.053 0.051 0.055 11.979

Unidentified 19.876 Unidentified 0.006 0.007 0.006 2.085

26.999 Unidentified 0.056 0.065 0.051 20.474 28.734 Unidentified 0.054 0.056 0.047 19.662 50.838 Unidentified 0.063 0.071 0.051 23.206 63.357 Unidentified 0.051 0.055 0.035 18.600 72.449 Unidentified 0.022 0.023 0.015 7.948 74.456 Unidentified 0.029 0.028 0.020 10.431 76.528 Unidentified 0.065 0.065 0.044 23.653 78.822 Unidentified 0.015 0.015 0.010 5.428 82.973 Unidentified 0.023 0.023 0.016 8.474 85.154 Unidentified 0.017 0.017 0.010 6.281 86.596 Unidentified 0.012 0.012 0.007 4.383 88.745 Unidentified 0.033 0.037 0.020 11.959 93.838 Unidentified 0.048 0.052 0.026 17.710 94.524 Unidentified 0.004 0.003 0.337 1.604 94.524 Unidentified 0.004 0.005 0.002 1.604 100.350 Unidentified 0.052 0.040 0.026 19.071 100.482 Unidentified 0.143 0.149 0.070 52.277 101.163 Unidentified 0.086 0.095 0.047 31.626 101.284 Unidentified 0.051 0.054 0.028 18.710 103.196 Unidentified 0.029 0.030 0.016 10.658 104.209 Unidentified 0.010 0.009 0.006 3.688 108.078 Unidentified 0.028 0.029 0.014 10.060 108.353 Unidentified 0.029 0.025 0.019 10.719 108.434 Unidentified 0.027 0.028 0.013 9.784 108.560 Unidentified 0.180 0.187 0.088 65.669 108.742 Unidentified 0.069 0.072 0.034 25.298 109.165 Unidentified 0.170 0.150 0.097 62.321 110.708 Unidentified 0.004 0.004 0.002 1.621

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 111.037 Unidentified 0.016 0.017 0.009 5.995

111.971 Unidentified 0.010 0.009 0.005 3.782 113.481 Unidentified 0.013 0.013 0.006 4.607 115.144 Unidentified 0.010 0.010 0.005 3.652 130.001 Unidentified 0.003 0.002 0.001 1.023

Plus

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1

Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane
Toluene

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane

Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene

Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane C10 - IsoParaffin - 2 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane

2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified 1,2,3-Trimethylbenzene Unidentified C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 6 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 03:40:31 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF Sample: ODDB-91325 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91325 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000007.D\SIG2000007_FID2_B.CDF145.0140.0135.0130.0125.0

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 8.270 9.957 9.435

I-Paraffins 37.267 39.763 27.546

Aromatics 19.014 16.000 13.683 Mono-Aromatics 18.147 15.327 13.148 Naphthalenes 0.092 0.066 0.054 Naphtheno/Olefino-Benzs 0.163 0.135 0.095 Indenes 0.612 0.473 0.386

Naphthenes 3.337 3.217 2.799 Mono-Naphthenes 3.337 3.217 2.799 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.296 7.918 7.342 n-Olefins 3.008 3.348 3.123 Iso-Olefins 3.545 3.863 3.479 Naphtheno-Olefins 0.702 0.664 0.698 Di-Olefins 0.041 0.043 0.043

Oxygenates 22.772 21.196 38.004

Unidentified 2.044 1.949 1.190

Plus 0.000 0.000 0.000

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 22.639 21.074 37.846 C3 0.084 0.081 0.111 C4 5.248 6.630 6.947 C5 9.128 10.531 9.868 C6 9.545 10.051 8.695 C7 10.587 10.042 8.522 C8 28.318 28.416 19.368 C9 7.751 7.149 4.835 C10 3.920 3.426 2.245 C11 0.621 0.553 0.318 C12 0.115 0.097 0.054

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.006 0.009 0.010 C4 4.928 6.253 6.530 C5 1.146 1.344 1.223 C6 0.789 0.879 0.705 C7 0.541 0.582 0.416 C8 0.522 0.546 0.352 C9 0.284 0.291 0.170 C10 0.024 0.024 0.013 C11 0.030 0.029 0.015

I-Paraffins C4 0.067 0.088 0.089 C5 4.174 4.948 4.455 C6 3.986 4.448 3.563 C7 2.762 2.989 2.123 C8 22.044 22.948 14.862 C9 2.973 3.073 1.785 C10 1.054 1.062 0.567 C11 0.195 0.192 0.096 C12 0.013 0.013 0.006

Mono-Aromatics C6 0.734 0.613 0.723 C7 5.209 4.413 4.354 C8 5.295 4.488 3.841 C9 4.388 3.701 2.812 C10 2.074 1.740 1.190 C11 0.344 0.287 0.179 C12 0.102 0.084 0.048

Naphthalenes C10 0.076 0.054 0.045 C11 0.017 0.012 0.009

Naphtheno/Olefino-Benzs C10 0.163 0.135 0.095

Indenes C9 0.072 0.055 0.047 C10 0.530 0.411 0.334 C11 0.009 0.007 0.005

Mono-Naphthenes C5 0.131 0.129 0.144 C6 1.434 1.390 1.312 C7 1.323 1.275 1.038 C8 0.415 0.394 0.285 C9 0.034 0.029 0.021

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes n-Olefins C4 0.198 0.238 0.271 C5 1.652 1.871 1.814 C6 1.034 1.111 0.946 C7 0.097 0.102 0.076 C11 0.026 0.026 0.015

Iso-Olefins C5 1.795 2.016 1.971 C6 1.069 1.140 0.978 C7 0.639 0.667 0.501 C8 0.043 0.040 0.028

Naphtheno-Olefins C5 0.204 0.195 0.231 C6 0.498 0.470 0.467

Di-Olefins C5 0.026 0.028 0.029 C7 0.015 0.015 0.014

Oxygenates C2 22.639 21.074 37.846 C3 0.079 0.072 0.101 C4 0.055 0.050 0.057

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.49 21.26 5% 31.02 28.77 10% 85.03 80.76 15% 134.41 97.26 20% 153.45 139.34 25% 172.30 155.96 30% 172.54 172.39 35% 172.78 172.65 40% 173.02 172.90 45% 173.26 173.16 50% 197.24 188.33 55% 209.70 209.37 60% 210.48 210.10 65% 230.77 227.37 70% 233.94 230.97 75% 237.17 236.05 80% 254.13 239.03 85% 280.02 268.42 90% 318.96 291.69 95% 343.56 335.66 FBP 392.15 387.69

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.553 74-98-6 P3 Propane 0.006 0.009 0.010 1.525 2 8.810 75-28-5 I4 i-Butane 0.067 0.088 0.089 17.580 3 9.624 115-11-7 K4 Isobutene 0.017 0.021 0.023 4.519 4 9.666 106-98-9 K4 Butene-1 0.018 0.023 0.025 4.989 5 10.025 106-97-8 P4 n-Butane 4.928 6.253 6.530 1292.516 6 10.512 624-64-6 K4 t-Butene-2 0.075 0.091 0.103 20.288 7 10.639 463-82-1 I5 2,2-Dimethylpropane 0.016 0.020 0.017 4.193 8 11.253 590-18-1 K4 c-Butene-2 0.088 0.104 0.121 23.903 9 13.135 64-17-5 X2 Ethanol 22.639 21.074 37.846 2532.266 10 13.454 563-45-1 C5 3-Methylbutene-1 0.241 0.282 0.264 65.368

11 15.084 78-78-4 I5 i-Pentane 4.158 4.929 4.438 1098.132 12 16.734 109-67-1 K5 Pentene-1 0.335 0.385 0.368 91.131 13 17.588 563-46-2 C5 2-Methylbutene-1 0.510 0.576 0.560 138.520 14 18.118 109-66-0 P5 n-Pentane 1.146 1.344 1.223 302.686 15 18.632 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.011 0.012 2.954 16 19.237 646-04-8 K5 t-Pentene-2 0.850 0.964 0.934 231.033 17 19.887 ? Unidentified 0.006 0.007 0.006 1.937 18 20.274 627-20-3 K5 c-Pentene-2 0.466 0.522 0.512 126.617 19 20.949 513-35-9 C5 2-Methylbutene-2 1.044 1.158 1.147 283.651 20 21.274 2004-70-8 E5 1t,3-Pentadiene 0.015 0.017 0.017 4.324

21 22.541 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.007 0.008 1.930 22 23.099 75-83-2 I6 2,2-Dimethylbutane 0.063 0.071 0.056 16.633 23 25.750 142-29-0 B5 Cyclopentene 0.197 0.187 0.223 55.099 24 26.907 71-23-8 X3 n-Propanol 0.079 0.072 0.101 14.942 25 26.998 ? Unidentified 0.057 0.063 0.052 19.089 26 27.615 287-92-3 M5 Cyclopentane 0.131 0.129 0.144 35.572 27 28.348 79-29-8 I6 2,3-Dimethylbutane 1.022 1.134 0.913 270.906 28 28.741 ? Unidentified 0.053 0.053 0.046 17.621 29 29.202 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.050 0.042 12.506 30 29.420 107-83-5 I6 2-Methylpentane 1.809 2.034 1.617 479.677

31 29.844 674-76-0 C6 4-Methyl-t-pentene-2 0.131 0.142 0.120 35.482 32 32.072 96-14-0 I6 3-Methylpentane 1.093 1.208 0.977 289.778 33 33.233 763-29-1 C6 2-Methylpentene-1 0.223 0.239 0.204 60.633 34 33.457 592-41-6 K6 Hexene-1 0.159 0.172 0.146 43.215 35 35.650 760-21-4 C6 2-Ethylbutene-1 0.069 0.073 0.063 18.777 36 35.809 110-54-3 P6 n-Hexane 0.789 0.879 0.705 209.313 37 36.442 13269-52-8 K6 t-Hexene-3 0.261 0.281 0.238 70.789 38 36.923 4050-45-7 K6 t-Hexene-2 0.402 0.433 0.368 109.278 39 37.044 1120-62-3 B6 3-Methylcyclopentene 0.098 0.094 0.092 26.518 40 37.413 625-27-4 C6 2-Methylpentene-2 0.339 0.360 0.310 91.959

41 37.830 922-62-3 C6 3-Methyl-c-pentene-2 0.262 0.275 0.240 71.097 42 38.750 7688-21-3 K6 c-Hexene-2 0.212 0.225 0.194 57.641 43 40.091 3404-73-7 C7 3,3-Dimethylpentene-1 0.307 0.321 0.240 83.280

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.676 96-37-7 M6 Methylcyclopentane 0.998 0.979 0.913 271.044 45 42.237 108-08-7 I7 2,4-Dimethylpentane 0.817 0.892 0.628 217.607 46 42.539 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.013 0.010 3.496 47 42.787 464-06-2 I7 2,2,3-Trimethylbutane 0.051 0.054 0.039 13.581 48 45.436 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 4.023 49 45.644 71-42-3 Q6 Benzene 0.734 0.613 0.723 214.653 50 45.841 693-89-0 B6 1-Methylcyclopentene 0.356 0.336 0.334 99.106 51 46.648 3404-61-3 C7 3-Methylhexene-1 0.015 0.016 0.012 4.180 52 47.236 3524-73-0 C7 5-Methylhexene-1 0.039 0.041 0.031 10.613 53 47.558 110-82-7 M6 Cyclohexane 0.436 0.412 0.399 118.491

54 48.064 71-36-3 X4 n-Butanol 0.055 0.050 0.057 11.294 55 49.279 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.042 0.031 10.864 56 49.627 3769-23-1 C7 4-Methylhexene-1 0.011 0.011 0.008 2.860 57 50.272 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.052 0.039 13.624 58 50.679 591-76-4 I7 2-Methylhexane 1.378 1.492 1.059 366.883 59 51.161 110-83-8 B6 Cyclohexene 0.044 0.040 0.041 11.959 60 52.501 589-34-4 I7 3-Methylhexane 0.515 0.551 0.396 137.192 61 53.361 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.147 0.144 0.115 39.807 62 53.948 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.112 0.111 0.088 30.441 63 54.573 822-50-4 M7 1t,2-Dimethylcyclopentane 0.152 0.148 0.119 41.231

64 54.896 C7 C7 - Iso-Olefin - 2 0.022 0.022 0.017 5.948 65 55.225 540-84-1 I8 2,2,4-Trimethylpentane 9.280 9.851 6.257 2475.508 66 55.484 592-76-7 K7 Heptene-1 0.029 0.030 0.022 7.773 67 56.811 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.707 68 57.339 14686-14-7 K7 t-Heptene-3 0.031 0.033 0.025 8.540 69 57.691 6094-02-6 C7 2-Methylhexene-1 0.056 0.059 0.044 15.264 70 58.063 142-82-5 P7 n-Heptane 0.541 0.582 0.416 144.113 71 58.281 7642-10-6 K7 c-Heptene-3 0.024 0.025 0.019 6.613 72 58.555 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.027 0.020 6.985 73 58.799 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.020 0.015 5.312

74 59.181 14686-13-6 K7 t-Heptene-2 0.013 0.013 0.010 3.520 75 59.658 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.017 0.014 4.834 76 60.084 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.015 0.011 3.975 77 60.867 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.010 3.430 78 61.525 108-87-2 M7 Methylcyclohexane 0.848 0.809 0.665 230.275 79 62.466 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.026 0.025 0.018 7.022 80 62.856 590-73-8 I8 2,2-Dimethylhexane 0.025 0.026 0.017 6.634 81 63.369 ? Unidentified 0.053 0.054 0.037 17.607 82 64.302 1640-89-7 M7 Ethylcyclopentane 0.048 0.046 0.037 12.905 83 64.956 564-02-3 I8 2,2,3-Trimethylpentane 0.502 0.515 0.339 134.040

84 65.188 592-13-2 I8 2,5-Dimethylhexane 1.155 1.223 0.779 308.054 85 65.525 589-43-5 I8 2,4-Dimethylhexane 1.073 1.126 0.724 286.292 86 66.355 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.027 0.026 0.018 7.268

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.749 563-16-6 I8 3,3-Dimethylhexane 0.019 0.019 0.013 4.955 88 67.867 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.024 0.023 0.016 6.434 89 68.512 565-75-3 I8 2,3,4-Trimethylpentane 3.896 3.980 2.627 1039.360 90 69.036 108-88-3 Q7 Toluene 5.209 4.413 4.354 1507.415 91 69.189 560-21-4 I8 2,3,3-Trimethylpentane 4.281 4.330 2.887 1142.059 92 70.520 C8 C8 - Diolefin - 1 0.010 0.010 0.007 2.847 93 70.805 584-94-1 I8 2,3-Dimethylhexane 1.062 1.095 0.716 283.229 94 72.053 592-27-8 I8 2-Methylheptane 0.248 0.261 0.167 66.153 95 72.316 589-53-7 I8 4-Methylheptane 0.181 0.189 0.122 48.361 96 72.456 ? Unidentified 0.085 0.087 0.057 28.284

97 73.230 M8 1,3-dimethyl-t-cyclohexane 0.168 0.160 0.115 45.514 98 73.366 589-81-1 I8 3-Methylheptane 0.215 0.223 0.145 57.248 99 73.567 619-99-8 I8 3-Ethylhexane 0.106 0.109 0.071 28.276 100 74.464 ? Unidentified 0.028 0.026 0.019 9.163 101 75.266 3522-94-9 I9 2,2,5-Trimethylhexane 1.986 2.063 1.193 530.957 102 75.615 M8 3c-Ethylmethylcyclopentane 0.010 0.009 0.007 2.631 103 75.832 M8 3t-Ethylmethylcyclopentane 0.014 0.013 0.010 3.783 104 76.239 ? Unidentified 0.014 0.014 0.010 4.791 105 76.538 ? Unidentified 0.066 0.062 0.045 21.873 106 77.875 111-65-9 P8 n-Octane 0.522 0.546 0.352 139.347

107 78.826 ? Unidentified 0.047 0.044 0.032 15.474 108 80.357 1069-53-0 I9 2,3,5-Trimethylhexane 0.311 0.316 0.187 83.136 109 80.911 C8 C9 - IsoOlefin - 1 0.018 0.017 0.013 5.020 110 81.372 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.016 0.015 0.011 4.288 111 81.523 1071-26-7 I9 2,4-Dimethylheptane 0.071 0.073 0.042 18.897 112 82.177 1678-91-7 M8 Ethylcyclohexane 0.131 0.123 0.090 35.676 113 82.479 1072-05-5 I9 2,6-Dimethylheptane 0.114 0.118 0.068 30.466 114 82.978 ? Unidentified 0.030 0.029 0.021 10.067 115 83.409 I9 2,5-Dimethylheptane 0.205 0.211 0.123 54.806 116 83.588 926-82-9 I9 3,5-Dimethylheptane 0.026 0.027 0.016 7.053

117 84.733 100-41-4 Q8 Ethylbenzene 0.950 0.805 0.689 272.831 118 84.906 ? Unidentified 0.026 0.026 0.016 8.780 119 85.151 ? Unidentified 0.035 0.033 0.021 11.599 120 85.956 108-38-3 Q8 m-Xylene 2.418 2.055 1.754 694.470 121 86.103 106-42-3 Q8 p-Xylene 1.080 0.921 0.783 310.114 122 86.234 ? Unidentified 0.066 0.067 0.040 21.958 123 86.492 C8 C9-IsoOlefin-3 0.014 0.013 0.008 3.694 124 86.598 ? Unidentified 0.012 0.013 0.007 4.134 125 86.755 I9 3,5-Dimethylheptane 0.011 0.011 0.007 3.010 126 86.883 1067-20-5 I9 3,3-Diethylpentane 0.010 0.010 0.006 2.643

127 87.277 2216-34-4 I9 4-Methyloctane 0.063 0.064 0.038 16.803 128 87.408 3221-61-2 I9 2-Methyloctane 0.084 0.086 0.050 22.364 129 88.110 15869-80-4 I9 Heptane, 3-ethyl- 0.011 0.012 0.007 3.041

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 88.271 2216-33-3 I9 3-Methyloctane 0.081 0.082 0.048 21.547 131 88.747 ? Unidentified 0.090 0.097 0.055 30.081 132 88.930 95-47-6 Q8 o-Xylene 0.847 0.707 0.615 243.280 133 89.325 I10 C10 - IsoParaffin - 1 0.310 0.313 0.168 83.102 134 89.913 M9 trans-1,3-Diethylcyclopentane 0.020 0.017 0.012 5.851 135 90.167 14720-74-2 I10 2,2,4-trimethylheptane 0.226 0.229 0.123 60.660 136 91.735 111-84-2 P9 n-Nonane 0.284 0.291 0.170 75.892 137 92.299 4926-90-3 M9 1,1-Methylethylcyclohexane 0.013 0.012 0.008 3.652 138 93.096 98-82-8 Q9 i-Propylbenzene 0.031 0.027 0.020 8.883 139 93.842 ? Unidentified 0.046 0.047 0.025 15.448

140 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.018 0.018 0.010 4.886 141 94.867 15869-89-3 I10 2,5-Dimethyloctane 0.013 0.013 0.007 3.380 142 95.071 I10 C10 - IsoParaffin - 2 0.008 0.008 0.004 2.043 143 95.507 2051-30-1 I10 2,4-Dimethyloctane 0.022 0.023 0.012 5.990 144 95.894 I10 2,6-Dimethyloctane 0.011 0.011 0.006 3.036 145 96.555 103-65-1 Q9 n-Propylbenzene 0.255 0.217 0.163 72.805 146 97.402 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.969 0.824 0.621 276.614 147 97.635 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.449 0.383 0.288 128.209 148 98.260 108-67-8 Q9 1,3,5-Trimethylbenzene 0.572 0.485 0.366 163.135 149 98.718 15869-85-9 I10 5-Methylnonane 0.006 0.006 0.003 1.505

150 98.908 17301-94-8 I10 4-Methylnonane 0.013 0.013 0.007 3.516 151 99.115 I10 2,2,6-Trimethyloctane 0.349 0.353 0.189 93.544 152 99.345 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.333 0.278 0.214 95.141 153 99.887 5911-04-6 I10 3-Methylnonane 0.015 0.016 0.008 4.151 154 100.351 ? Unidentified 0.023 0.017 0.011 7.560 155 100.483 ? Unidentified 0.060 0.059 0.030 20.050 156 100.699 I11 C11-Isoparaffin-2 0.033 0.032 0.016 8.782 157 100.976 95-63-6 Q9 1,2,4-Trimethylbenzene 1.574 1.320 1.009 449.228 158 101.164 ? Unidentified 0.042 0.044 0.023 13.901 159 101.286 ? Unidentified 0.024 0.024 0.013 7.974

160 102.336 17302-01-1 I10 3-Ethyl-3-methylheptane 0.061 0.060 0.030 16.361 161 102.645 538-93-2 Q10 i-Butylbenzene 0.072 0.062 0.042 20.563 162 102.803 124-18-5 P10 n-Decane 0.024 0.024 0.013 6.388 163 102.899 ? Unidentified 0.014 0.012 0.008 4.764 164 103.199 ? Unidentified 0.017 0.017 0.009 5.778 165 103.851 526-73-8 Q9 1,2,3-Trimethylbenzene 0.203 0.167 0.130 57.981 166 104.222 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.009 0.008 0.005 2.564 167 104.410 I11 C11 Isoparaffin-4 0.009 0.009 0.004 2.435 168 104.617 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.062 0.053 0.036 17.648 169 105.046 J9 Indan 0.072 0.055 0.047 20.951

170 105.639 J10 Indene 0.367 0.280 0.239 106.527 171 106.355 I11 C11-Isoparaffin-7 0.153 0.151 0.075 41.018 172 106.548 141-93-5 Q10 1,3-Diethylbenzene 0.023 0.019 0.013 6.486

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 106.833 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.474 0.405 0.272 134.660 174 107.111 105-05-5 Q10 1,4-Diethylbenzene 0.173 0.147 0.099 49.056 175 107.383 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.095 0.079 0.054 26.889 176 107.622 135-01-3 Q10 1,2-Diethylbenzene 0.039 0.033 0.023 11.139 177 108.081 ? Unidentified 0.038 0.038 0.019 12.711 178 108.234 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.040 0.034 0.023 11.478 179 108.356 ? Unidentified 0.044 0.044 0.022 14.778 180 108.436 ? Unidentified 0.042 0.041 0.021 13.975 181 108.563 ? Unidentified 0.266 0.262 0.131 88.381 182 108.745 ? Unidentified 0.107 0.106 0.053 35.632

183 109.168 ? Unidentified 0.437 0.366 0.251 145.523 184 109.395 J10 2-Methylindan 0.055 0.042 0.032 16.018 185 109.741 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.247 0.208 0.142 70.137 186 110.286 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.321 0.265 0.184 91.206 187 110.711 ? Unidentified 0.010 0.009 0.005 3.492 188 110.905 693-61-8 K11 2-Undecene, (E)- 0.026 0.026 0.015 7.119 189 111.039 ? Unidentified 0.056 0.055 0.031 18.523 190 111.311 ? Unidentified 0.060 0.052 0.031 19.842 191 111.413 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.061 0.050 0.035 17.312 192 111.711 1120-21-4 P11 n-Undecane 0.030 0.029 0.015 7.946

193 111.864 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.041 0.034 0.022 11.719 194 111.973 ? Unidentified 0.024 0.020 0.012 7.916 195 112.349 Q10 1,2,4,5-Tetramethylbenzene 0.192 0.159 0.110 54.543 196 112.614 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.264 0.218 0.152 74.976 197 112.957 ? Unidentified 0.006 0.005 0.003 1.854 198 113.131 I12 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.278 199 113.487 ? Unidentified 0.017 0.017 0.008 5.717 200 113.611 ? Unidentified 0.006 0.006 0.003 2.016 201 113.760 Q11 C11 - Aromatic - 3 0.052 0.043 0.027 14.775 202 113.946 874-35-1 H10 5-Methylindan 0.080 0.066 0.047 22.742

203 114.071 Q12 1,2-Di-i-propylbenzene 0.035 0.029 0.017 9.818 204 114.286 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.046 0.038 0.024 13.003 205 114.452 Q11 C11 - Aromatic - 4 0.030 0.024 0.015 8.373 206 114.695 824-22-6 J10 4-Methylindan 0.108 0.089 0.063 30.525 207 114.849 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.031 0.026 0.016 8.813 208 114.942 824-63-5 H10 2-Methylindan 0.083 0.068 0.048 23.516 209 115.146 ? Unidentified 0.010 0.010 0.005 3.399 210 115.259 538-68-1 Q11 n-Pentylbenzene 0.012 0.010 0.006 3.515 211 115.487 Q11 tert-Pentylbenzene 0.049 0.040 0.025 13.728 212 115.799 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.021 0.017 0.011 5.909

213 115.910 Q11 C11 - Aromatic - 7 0.035 0.030 0.018 9.767 214 116.251 I12 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.221 215 116.370 100-18-5 Q12 1,4-Di-i-propylbenzene 0.037 0.031 0.018 10.549

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 116.810 91-20-3 G10 Naphthalene 0.076 0.054 0.045 22.459 217 116.944 ? Unidentified 0.012 0.012 0.006 4.091 218 117.127 ? Unidentified 0.004 0.003 0.002 1.225 219 117.241 J11 1,1-Dimethyl Indane 0.009 0.007 0.005 2.658 220 117.895 Q12 1,3-Di-n-propylbenzene 0.030 0.025 0.014 8.392 221 118.007 Q11 C11 - Aromatic - 11 0.016 0.013 0.008 4.407 222 118.559 Q11 C11 - Aromatic - 12 0.012 0.010 0.006 3.292 223 123.442 91-57-6 G11 2-Methylnaphthalene 0.011 0.008 0.006 3.353 224 124.309 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.587 225 126.298 ? Unidentified 0.007 0.006 0.003 2.235

226 130.004 ? Unidentified 0.003 0.002 0.002 1.013

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.553 74-98-6 Propane 0.006 0.009 0.010 1.525

10.025 106-97-8 n-Butane 4.928 6.253 6.530 1292.516 18.118 109-66-0 n-Pentane 1.146 1.344 1.223 302.686 35.809 110-54-3 n-Hexane 0.789 0.879 0.705 209.313 58.063 142-82-5 n-Heptane 0.541 0.582 0.416 144.113 77.875 111-65-9 n-Octane 0.522 0.546 0.352 139.347 91.735 111-84-2 n-Nonane 0.284 0.291 0.170 75.892 102.803 124-18-5 n-Decane 0.024 0.024 0.013 6.388 111.711 1120-21-4 n-Undecane 0.030 0.029 0.015 7.946

I-Paraffins 8.810 75-28-5 i-Butane 0.067 0.088 0.089 17.580

10.639 463-82-1 2,2-Dimethylpropane 0.016 0.020 0.017 4.193 15.084 78-78-4 i-Pentane 4.158 4.929 4.438 1098.132 23.099 75-83-2 2,2-Dimethylbutane 0.063 0.071 0.056 16.633 28.348 79-29-8 2,3-Dimethylbutane 1.022 1.134 0.913 270.906 29.420 107-83-5 2-Methylpentane 1.809 2.034 1.617 479.677 32.072 96-14-0 3-Methylpentane 1.093 1.208 0.977 289.778 42.237 108-08-7 2,4-Dimethylpentane 0.817 0.892 0.628 217.607 42.787 464-06-2 2,2,3-Trimethylbutane 0.051 0.054 0.039 13.581 50.679 591-76-4 2-Methylhexane 1.378 1.492 1.059 366.883 52.501 589-34-4 3-Methylhexane 0.515 0.551 0.396 137.192 55.225 540-84-1 2,2,4-Trimethylpentane 9.280 9.851 6.257 2475.508 62.856 590-73-8 2,2-Dimethylhexane 0.025 0.026 0.017 6.634 64.956 564-02-3 2,2,3-Trimethylpentane 0.502 0.515 0.339 134.040 65.188 592-13-2 2,5-Dimethylhexane 1.155 1.223 0.779 308.054 65.525 589-43-5 2,4-Dimethylhexane 1.073 1.126 0.724 286.292 66.749 563-16-6 3,3-Dimethylhexane 0.019 0.019 0.013 4.955 68.512 565-75-3 2,3,4-Trimethylpentane 3.896 3.980 2.627 1039.360 69.189 560-21-4 2,3,3-Trimethylpentane 4.281 4.330 2.887 1142.059 70.805 584-94-1 2,3-Dimethylhexane 1.062 1.095 0.716 283.229 72.053 592-27-8 2-Methylheptane 0.248 0.261 0.167 66.153 72.316 589-53-7 4-Methylheptane 0.181 0.189 0.122 48.361 73.366 589-81-1 3-Methylheptane 0.215 0.223 0.145 57.248 73.567 619-99-8 3-Ethylhexane 0.106 0.109 0.071 28.276 75.266 3522-94-9 2,2,5-Trimethylhexane 1.986 2.063 1.193 530.957 80.357 1069-53-0 2,3,5-Trimethylhexane 0.311 0.316 0.187 83.136 81.523 1071-26-7 2,4-Dimethylheptane 0.071 0.073 0.042 18.897 82.479 1072-05-5 2,6-Dimethylheptane 0.114 0.118 0.068 30.466 83.409 2,5-Dimethylheptane 0.205 0.211 0.123 54.806 83.588 926-82-9 3,5-Dimethylheptane 0.026 0.027 0.016 7.053 86.755 3,5-Dimethylheptane 0.011 0.011 0.007 3.010 86.883 1067-20-5 3,3-Diethylpentane 0.010 0.010 0.006 2.643 87.277 2216-34-4 4-Methyloctane 0.063 0.064 0.038 16.803 87.408 3221-61-2 2-Methyloctane 0.084 0.086 0.050 22.364 88.110 15869-80-4 Heptane, 3-ethyl- 0.011 0.012 0.007 3.041 88.271 2216-33-3 3-Methyloctane 0.081 0.082 0.048 21.547 89.325 C10 - IsoParaffin - 1 0.310 0.313 0.168 83.102

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 90.167 14720-74-2 2,2,4-trimethylheptane 0.226 0.229 0.123 60.660

94.064 15869-87-1 2,2-Dimethyloctane 0.018 0.018 0.010 4.886 94.867 15869-89-3 2,5-Dimethyloctane 0.013 0.013 0.007 3.380 95.071 C10 - IsoParaffin - 2 0.008 0.008 0.004 2.043 95.507 2051-30-1 2,4-Dimethyloctane 0.022 0.023 0.012 5.990 95.894 2,6-Dimethyloctane 0.011 0.011 0.006 3.036 98.718 15869-85-9 5-Methylnonane 0.006 0.006 0.003 1.505 98.908 17301-94-8 4-Methylnonane 0.013 0.013 0.007 3.516 99.115 2,2,6-Trimethyloctane 0.349 0.353 0.189 93.544 99.887 5911-04-6 3-Methylnonane 0.015 0.016 0.008 4.151 100.699 C11-Isoparaffin-2 0.033 0.032 0.016 8.782 102.336 17302-01-1 3-Ethyl-3-methylheptane 0.061 0.060 0.030 16.361 104.410 C11 Isoparaffin-4 0.009 0.009 0.004 2.435 106.355 C11-Isoparaffin-7 0.153 0.151 0.075 41.018 113.131 C12 - IsoParaffin - 1 0.008 0.008 0.004 2.278 116.251 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.221

Aromatics Mono-Aromatics 45.644 71-42-3 Benzene 0.734 0.613 0.723 214.653

69.036 108-88-3 Toluene 5.209 4.413 4.354 1507.415 84.733 100-41-4 Ethylbenzene 0.950 0.805 0.689 272.831 85.956 108-38-3 m-Xylene 2.418 2.055 1.754 694.470 86.103 106-42-3 p-Xylene 1.080 0.921 0.783 310.114 88.930 95-47-6 o-Xylene 0.847 0.707 0.615 243.280 93.096 98-82-8 i-Propylbenzene 0.031 0.027 0.020 8.883 96.555 103-65-1 n-Propylbenzene 0.255 0.217 0.163 72.805 97.402 620-14-4 1-Methyl-3-ethylbenzene 0.969 0.824 0.621 276.614 97.635 622-96-8 1-Methyl-4-ethylbenzene 0.449 0.383 0.288 128.209 98.260 108-67-8 1,3,5-Trimethylbenzene 0.572 0.485 0.366 163.135 99.345 611-14-3 1-Methyl-2-ethylbenzene 0.333 0.278 0.214 95.141 100.976 95-63-6 1,2,4-Trimethylbenzene 1.574 1.320 1.009 449.228 102.645 538-93-2 i-Butylbenzene 0.072 0.062 0.042 20.563 103.851 526-73-8 1,2,3-Trimethylbenzene 0.203 0.167 0.130 57.981 104.222 535-77-3 1-Methyl-3-i-propylbenzene 0.009 0.008 0.005 2.564 104.617 99-87-6 1-Methyl-4-i-propylbenzene 0.062 0.053 0.036 17.648 106.548 141-93-5 1,3-Diethylbenzene 0.023 0.019 0.013 6.486 106.833 1074-43-7 1-Methyl-3-n-propylbenzene 0.474 0.405 0.272 134.660 107.111 105-05-5 1,4-Diethylbenzene 0.173 0.147 0.099 49.056 107.383 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.095 0.079 0.054 26.889 107.622 135-01-3 1,2-Diethylbenzene 0.039 0.033 0.023 11.139 108.234 1074-17-5 1-Methyl-2-n-propylbenzene 0.040 0.034 0.023 11.478 109.741 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.247 0.208 0.142 70.137 110.286 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.321 0.265 0.184 91.206 111.413 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.061 0.050 0.035 17.312 111.864 4218-48-8 1-Ethyl-4-i-propylbenzene 0.041 0.034 0.022 11.719 112.349 1,2,4,5-Tetramethylbenzene 0.192 0.159 0.110 54.543 112.614 527-53-7 1,2,3,5-Tetramethylbenzene 0.264 0.218 0.152 74.976

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 113.760 C11 - Aromatic - 3 0.052 0.043 0.027 14.775

114.071 1,2-Di-i-propylbenzene 0.035 0.029 0.017 9.818 114.286 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.046 0.038 0.024 13.003 114.452 C11 - Aromatic - 4 0.030 0.024 0.015 8.373 114.849 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.031 0.026 0.016 8.813 115.259 538-68-1 n-Pentylbenzene 0.012 0.010 0.006 3.515 115.487 tert-Pentylbenzene 0.049 0.040 0.025 13.728 115.799 577-55-9 1-Methyl-2-n-butylbenzene 0.021 0.017 0.011 5.909 115.910 C11 - Aromatic - 7 0.035 0.030 0.018 9.767 116.370 100-18-5 1,4-Di-i-propylbenzene 0.037 0.031 0.018 10.549 117.895 1,3-Di-n-propylbenzene 0.030 0.025 0.014 8.392 118.007 C11 - Aromatic - 11 0.016 0.013 0.008 4.407 118.559 C11 - Aromatic - 12 0.012 0.010 0.006 3.292

Naphthalenes 116.810 91-20-3 Naphthalene 0.076 0.054 0.045 22.459

123.442 91-57-6 2-Methylnaphthalene 0.011 0.008 0.006 3.353 124.309 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.587

Naphtheno/Olefino-Benzs

113.946 874-35-1 5-Methylindan 0.080 0.066 0.047 22.742 114.942 824-63-5 2-Methylindan 0.083 0.068 0.048 23.516

Indenes 105.046 Indan 0.072 0.055 0.047 20.951

105.639 Indene 0.367 0.280 0.239 106.527 109.395 2-Methylindan 0.055 0.042 0.032 16.018 114.695 824-22-6 4-Methylindan 0.108 0.089 0.063 30.525 117.241 1,1-Dimethyl Indane 0.009 0.007 0.005 2.658

Naphthenes Mono-Naphthenes 27.615 287-92-3 Cyclopentane 0.131 0.129 0.144 35.572

40.676 96-37-7 Methylcyclopentane 0.998 0.979 0.913 271.044 47.558 110-82-7 Cyclohexane 0.436 0.412 0.399 118.491 53.361 1759-58-6 1t,3-Dimethylcyclopentane 0.147 0.144 0.115 39.807 53.948 2532-58-3 1c,3-Dimethylcyclopentane 0.112 0.111 0.088 30.441 54.573 822-50-4 1t,2-Dimethylcyclopentane 0.152 0.148 0.119 41.231 59.658 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.017 0.014 4.834 61.525 108-87-2 Methylcyclohexane 0.848 0.809 0.665 230.275 62.466 4516-69-2 1,1,3-Trimethylcyclopentane 0.026 0.025 0.018 7.022 64.302 1640-89-7 Ethylcyclopentane 0.048 0.046 0.037 12.905 66.355 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.027 0.026 0.018 7.268 67.867 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.024 0.023 0.016 6.434 73.230 1,3-dimethyl-t-cyclohexane 0.168 0.160 0.115 45.514 75.615 3c-Ethylmethylcyclopentane 0.010 0.009 0.007 2.631 75.832 3t-Ethylmethylcyclopentane 0.014 0.013 0.010 3.783 81.372 2207-01-4 1c,2-Dimethylcyclohexane 0.016 0.015 0.011 4.288 82.177 1678-91-7 Ethylcyclohexane 0.131 0.123 0.090 35.676 89.913 trans-1,3-Diethylcyclopentane 0.020 0.017 0.012 5.851 92.299 4926-90-3 1,1-Methylethylcyclohexane 0.013 0.012 0.008 3.652

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes Di/Bicyclo-Naphthenes Olefins n-Olefins 9.624 115-11-7 Isobutene 0.017 0.021 0.023 4.519

9.666 106-98-9 Butene-1 0.018 0.023 0.025 4.989 10.512 624-64-6 t-Butene-2 0.075 0.091 0.103 20.288 11.253 590-18-1 c-Butene-2 0.088 0.104 0.121 23.903 16.734 109-67-1 Pentene-1 0.335 0.385 0.368 91.131 19.237 646-04-8 t-Pentene-2 0.850 0.964 0.934 231.033 20.274 627-20-3 c-Pentene-2 0.466 0.522 0.512 126.617 33.457 592-41-6 Hexene-1 0.159 0.172 0.146 43.215 36.442 13269-52-8 t-Hexene-3 0.261 0.281 0.238 70.789 36.923 4050-45-7 t-Hexene-2 0.402 0.433 0.368 109.278 38.750 7688-21-3 c-Hexene-2 0.212 0.225 0.194 57.641 55.484 592-76-7 Heptene-1 0.029 0.030 0.022 7.773 57.339 14686-14-7 t-Heptene-3 0.031 0.033 0.025 8.540 58.281 7642-10-6 c-Heptene-3 0.024 0.025 0.019 6.613 59.181 14686-13-6 t-Heptene-2 0.013 0.013 0.010 3.520 110.905 693-61-8 2-Undecene, (E)- 0.026 0.026 0.015 7.119

Iso-Olefins 13.454 563-45-1 3-Methylbutene-1 0.241 0.282 0.264 65.368

17.588 563-46-2 2-Methylbutene-1 0.510 0.576 0.560 138.520 20.949 513-35-9 2-Methylbutene-2 1.044 1.158 1.147 283.651 29.202 691-38-3 4-Methyl-c-pentene-2 0.046 0.050 0.042 12.506 29.844 674-76-0 4-Methyl-t-pentene-2 0.131 0.142 0.120 35.482 33.233 763-29-1 2-Methylpentene-1 0.223 0.239 0.204 60.633 35.650 760-21-4 2-Ethylbutene-1 0.069 0.073 0.063 18.777 37.413 625-27-4 2-Methylpentene-2 0.339 0.360 0.310 91.959 37.830 922-62-3 3-Methyl-c-pentene-2 0.262 0.275 0.240 71.097 40.091 3404-73-7 3,3-Dimethylpentene-1 0.307 0.321 0.240 83.280 42.539 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.013 0.010 3.496 46.648 3404-61-3 3-Methylhexene-1 0.015 0.016 0.012 4.180 47.236 3524-73-0 5-Methylhexene-1 0.039 0.041 0.031 10.613 49.279 15840-60-5 2-Methyl-c-hexene-3 0.040 0.042 0.031 10.864 49.627 3769-23-1 4-Methylhexene-1 0.011 0.011 0.008 2.860 50.272 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.052 0.039 13.624 54.896 C7 - Iso-Olefin - 2 0.022 0.022 0.017 5.948 56.811 4914-89-0 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.707 57.691 6094-02-6 2-Methylhexene-1 0.056 0.059 0.044 15.264 58.555 2738-19-4 2-Methyl-2-hexene 0.026 0.027 0.020 6.985 58.799 10574-36-4 3-Methyl-c-hexene-2 0.020 0.020 0.015 5.312 60.084 20710-38-8 3-Methyl-t-hexene-2 0.015 0.015 0.011 3.975 60.867 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.010 3.430 70.520 C8 - Diolefin - 1 0.010 0.010 0.007 2.847 80.911 C9 - IsoOlefin - 1 0.018 0.017 0.013 5.020 86.492 C9-IsoOlefin-3 0.014 0.013 0.008 3.694

Naphtheno-Olefins 22.541 1574-41-0 1,3-Cyclopentadiene 0.007 0.007 0.008 1.930

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphtheno-Olefins 25.750 142-29-0 Cyclopentene 0.197 0.187 0.223 55.099

37.044 1120-62-3 3-Methylcyclopentene 0.098 0.094 0.092 26.518 45.841 693-89-0 1-Methylcyclopentene 0.356 0.336 0.334 99.106 51.161 110-83-8 Cyclohexene 0.044 0.040 0.041 11.959

Di-Olefins 18.632 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.011 0.012 2.954

21.274 2004-70-8 1t,3-Pentadiene 0.015 0.017 0.017 4.324 45.436 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 4.023

Oxygenates 13.135 64-17-5 Ethanol 22.639 21.074 37.846 2532.266

26.907 71-23-8 n-Propanol 0.079 0.072 0.101 14.942 48.064 71-36-3 n-Butanol 0.055 0.050 0.057 11.294

Unidentified 19.887 Unidentified 0.006 0.007 0.006 1.937

26.998 Unidentified 0.057 0.063 0.052 19.089 28.741 Unidentified 0.053 0.053 0.046 17.621 63.369 Unidentified 0.053 0.054 0.037 17.607 72.456 Unidentified 0.085 0.087 0.057 28.284 74.464 Unidentified 0.028 0.026 0.019 9.163 76.239 Unidentified 0.014 0.014 0.010 4.791 76.538 Unidentified 0.066 0.062 0.045 21.873 78.826 Unidentified 0.047 0.044 0.032 15.474 82.978 Unidentified 0.030 0.029 0.021 10.067 84.906 Unidentified 0.026 0.026 0.016 8.780 85.151 Unidentified 0.035 0.033 0.021 11.599 86.234 Unidentified 0.066 0.067 0.040 21.958 86.598 Unidentified 0.012 0.013 0.007 4.134 88.747 Unidentified 0.090 0.097 0.055 30.081 93.842 Unidentified 0.046 0.047 0.025 15.448 100.351 Unidentified 0.023 0.017 0.011 7.560 100.483 Unidentified 0.060 0.059 0.030 20.050 101.164 Unidentified 0.042 0.044 0.023 13.901 101.286 Unidentified 0.024 0.024 0.013 7.974 102.899 Unidentified 0.014 0.012 0.008 4.764 103.199 Unidentified 0.017 0.017 0.009 5.778 108.081 Unidentified 0.038 0.038 0.019 12.711 108.356 Unidentified 0.044 0.044 0.022 14.778 108.436 Unidentified 0.042 0.041 0.021 13.975 108.563 Unidentified 0.266 0.262 0.131 88.381 108.745 Unidentified 0.107 0.106 0.053 35.632 109.168 Unidentified 0.437 0.366 0.251 145.523 110.711 Unidentified 0.010 0.009 0.005 3.492 111.039 Unidentified 0.056 0.055 0.031 18.523 111.311 Unidentified 0.060 0.052 0.031 19.842 111.973 Unidentified 0.024 0.020 0.012 7.916 112.957 Unidentified 0.006 0.005 0.003 1.854 113.487 Unidentified 0.017 0.017 0.008 5.717

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 113.611 Unidentified 0.006 0.006 0.003 2.016

115.146 Unidentified 0.010 0.010 0.005 3.399 116.944 Unidentified 0.012 0.012 0.006 4.091 117.127 Unidentified 0.004 0.003 0.002 1.225 126.298 Unidentified 0.007 0.006 0.003 2.235 130.004 Unidentified 0.003 0.002 0.002 1.013

Plus

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2

2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane

Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane Unidentified Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene

p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene

Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane C10 - IsoParaffin - 2 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene
1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Methylnonane

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified Unidentified Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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26-Aug-10, 13:09:57 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF Sample: ODDB-91326 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91326 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000018.D\SIG2000018_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 8.179 9.359 7.395

I-Paraffins 26.371 29.191 20.475

Aromatics 24.723 21.232 17.409 Mono-Aromatics 22.468 19.457 15.965 Naphthalenes 0.110 0.081 0.066 Naphtheno/Olefino-Benzs 0.179 0.151 0.105 Indenes 1.966 1.542 1.273

Naphthenes 6.329 6.239 5.446 Mono-Naphthenes 6.329 6.239 5.446 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.197 7.993 7.271 n-Olefins 2.989 3.403 3.110 Iso-Olefins 3.457 3.856 3.408 Naphtheno-Olefins 0.709 0.688 0.708 Di-Olefins 0.043 0.046 0.046

Oxygenates 22.530 21.487 37.932

Unidentified 4.671 4.499 4.072

Plus 0.000 0.000 0.000

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 22.401 21.366 37.779 C3 0.082 0.081 0.109 C4 0.817 1.034 1.086 C5 8.195 9.640 8.951 C6 20.564 22.607 18.745 C7 11.762 11.416 9.542 C8 10.358 9.857 7.353 C9 6.421 5.759 4.103 C10 12.071 11.141 6.925 C11 2.520 2.479 1.268 C12 0.138 0.121 0.066

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.008 0.012 0.014 C4 0.504 0.656 0.674 C5 1.264 1.519 1.361 C6 4.274 4.878 3.854 C7 0.909 1.000 0.705 C8 0.810 0.867 0.551 C9 0.283 0.297 0.171 C10 0.041 0.043 0.023 C11 0.086 0.087 0.043

I-Paraffins C4 0.068 0.092 0.092 C5 3.123 3.794 3.364 C6 9.714 11.116 8.758 C7 2.492 2.756 1.932 C8 3.057 3.280 2.079 C9 0.863 0.908 0.523 C10 5.079 5.247 2.748 C11 1.949 1.971 0.969 C12 0.026 0.026 0.012

Mono-Aromatics C6 0.724 0.620 0.720 C7 5.523 4.794 4.657 C8 5.794 5.032 4.240 C9 5.097 4.406 3.295 C10 4.822 4.173 2.791 C11 0.400 0.341 0.210 C12 0.109 0.092 0.052

Naphthalenes C10 0.095 0.070 0.058 C11 0.015 0.011 0.008

Naphtheno/Olefino-Benzs C10 0.179 0.151 0.105

Indenes C9 0.106 0.083 0.070 C10 1.847 1.450 1.197 C11 0.009 0.007 0.005 C12 0.004 0.003 0.002

Mono-Naphthenes C5 0.235 0.237 0.260 C6 3.330 3.292 3.074 C7 2.043 2.015 1.617 C8 0.652 0.634 0.452

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.065 0.058 0.040 C10 0.003 0.003 0.002

n-Olefins C4 0.190 0.234 0.262 C5 1.615 1.873 1.789 C6 1.027 1.131 0.948 C7 0.096 0.103 0.076 C11 0.062 0.063 0.034

Iso-Olefins C5 1.730 1.990 1.917 C6 0.993 1.085 0.916 C7 0.685 0.733 0.542 C8 0.045 0.044 0.031 C10 0.004 0.004 0.002

Naphtheno-Olefins C5 0.201 0.196 0.229 C6 0.501 0.484 0.474 C9 0.007 0.007 0.004

Di-Olefins C5 0.027 0.030 0.031 C7 0.015 0.015 0.014

Oxygenates C2 22.401 21.366 37.779 C3 0.074 0.069 0.095 C4 0.055 0.052 0.058

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 28.74 26.29 5% 87.79 81.88 10% 134.95 101.07 15% 140.05 138.76 20% 152.92 144.52 25% 155.61 154.48 30% 172.32 159.22 35% 172.56 172.38 40% 172.80 172.63 45% 173.04 172.88 50% 173.28 173.14 55% 197.13 177.07 60% 228.60 209.01 65% 231.03 230.84 70% 277.05 245.71 75% 291.70 281.73 80% 329.25 321.71 85% 334.61 332.42 90% 358.04 352.22 95% 363.20 363.20 FBP 397.97 388.02

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.553 74-98-6 P3 Propane 0.008 0.012 0.014 2.117 2 8.810 75-28-5 I4 i-Butane 0.068 0.092 0.092 18.575 3 9.624 115-11-7 K4 Isobutene 0.016 0.020 0.022 4.438 4 9.665 106-98-9 K4 Butene-1 0.018 0.022 0.024 4.971 5 10.024 106-97-8 P4 n-Butane 0.504 0.656 0.674 136.813 6 10.510 624-64-6 K4 t-Butene-2 0.072 0.089 0.099 20.107 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.007 0.008 0.007 1.806 8 11.252 590-18-1 K4 c-Butene-2 0.085 0.102 0.117 23.755 9 13.136 64-17-5 X2 Ethanol 22.401 21.366 37.779 2592.448 10 13.454 563-45-1 C5 3-Methylbutene-1 0.212 0.255 0.235 59.661

11 15.077 78-78-4 I5 i-Pentane 3.117 3.786 3.356 851.694 12 16.730 109-67-1 K5 Pentene-1 0.327 0.384 0.362 91.959 13 17.580 563-46-2 C5 2-Methylbutene-1 0.496 0.574 0.550 139.529 14 18.117 109-66-0 P5 n-Pentane 1.264 1.519 1.361 345.443 15 18.627 78-79-5 E5 2-Methyl-1,3-Butadiene 0.012 0.013 0.014 3.463 16 19.236 646-04-8 K5 t-Pentene-2 0.831 0.965 0.921 233.676 17 19.879 ? Unidentified 0.006 0.007 0.006 1.988 18 20.267 627-20-3 K5 c-Pentene-2 0.456 0.523 0.505 128.173 19 20.944 513-35-9 C5 2-Methylbutene-2 1.021 1.161 1.132 287.088 20 21.271 2004-70-8 E5 1t,3-Pentadiene 0.015 0.017 0.017 4.436

21 22.538 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.007 0.008 1.971 22 23.092 75-83-2 I6 2,2-Dimethylbutane 0.216 0.251 0.195 59.275 23 25.740 142-29-0 B5 Cyclopentene 0.194 0.189 0.221 56.071 24 26.902 71-23-8 X3 n-Propanol 0.074 0.069 0.095 14.507 25 26.998 ? Unidentified 0.059 0.066 0.054 20.289 26 27.606 287-92-3 M5 Cyclopentane 0.235 0.237 0.260 66.074 27 28.338 79-29-8 I6 2,3-Dimethylbutane 1.008 1.147 0.909 276.570 28 28.734 ? Unidentified 0.052 0.053 0.046 17.890 29 29.197 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.050 0.041 12.606 30 29.436 107-83-5 I6 2-Methylpentane 5.203 5.995 4.691 1427.392

31 29.846 674-76-0 C6 4-Methyl-t-pentene-2 0.129 0.144 0.119 36.274 32 32.075 96-14-0 I6 3-Methylpentane 3.287 3.724 2.964 901.752 33 33.228 763-29-1 C6 2-Methylpentene-1 0.221 0.243 0.204 62.196 34 33.455 592-41-6 K6 Hexene-1 0.158 0.175 0.146 44.390 35 35.827 110-54-3 P6 n-Hexane 4.274 4.878 3.854 1172.592 36 36.441 13269-52-8 K6 t-Hexene-3 0.260 0.287 0.240 73.101 37 36.917 4050-45-7 K6 t-Hexene-2 0.398 0.438 0.367 111.781 38 37.043 1120-62-3 B6 3-Methylcyclopentene 0.100 0.099 0.095 28.141 39 37.408 625-27-4 C6 2-Methylpentene-2 0.336 0.366 0.311 94.559 40 37.820 922-62-3 C6 3-Methyl-c-pentene-2 0.261 0.281 0.241 73.337

41 38.745 7688-21-3 K6 c-Hexene-2 0.212 0.230 0.195 59.449 42 40.089 3404-73-7 C7 3,3-Dimethylpentene-1 0.307 0.330 0.243 86.391 43 40.678 96-37-7 M6 Methylcyclopentane 1.892 1.902 1.746 531.671

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.233 108-08-7 I7 2,4-Dimethylpentane 0.431 0.483 0.334 118.818 45 42.533 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.011 3.887 46 42.781 464-06-2 I7 2,2,3-Trimethylbutane 0.053 0.058 0.041 14.724 47 45.426 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 4.281 48 45.639 71-42-3 Q6 Benzene 0.724 0.620 0.720 219.241 49 45.833 693-89-0 B6 1-Methylcyclopentene 0.357 0.345 0.338 102.729 50 46.640 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.013 4.507 51 47.236 3524-73-0 C7 5-Methylhexene-1 0.082 0.088 0.065 22.959 52 47.559 110-82-7 M6 Cyclohexane 1.438 1.391 1.328 404.294 53 48.059 71-36-3 X4 n-Butanol 0.055 0.052 0.058 11.742

54 49.272 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.043 0.032 11.193 55 49.622 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.009 3.228 56 50.267 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.054 0.040 14.212 57 50.666 591-76-4 I7 2-Methylhexane 1.231 1.365 0.954 339.006 58 50.841 ? Unidentified 0.068 0.074 0.055 23.503 59 51.153 110-83-8 B6 Cyclohexene 0.044 0.041 0.042 12.426 60 52.493 589-34-4 I7 3-Methylhexane 0.776 0.850 0.602 213.780 61 53.353 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.194 0.195 0.154 54.572 62 53.939 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.154 0.156 0.122 43.326 63 54.561 822-50-4 M7 1t,2-Dimethylcyclopentane 0.234 0.234 0.185 65.793

64 54.847 C7 C7 - Iso-Olefin - 2 0.022 0.023 0.017 6.127 65 55.148 540-84-1 I8 2,2,4-Trimethylpentane 1.102 1.198 0.749 304.018 66 55.468 592-76-7 K7 Heptene-1 0.029 0.031 0.023 8.040 67 56.801 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.872 68 57.331 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.025 8.804 69 57.684 6094-02-6 C7 2-Methylhexene-1 0.056 0.061 0.044 15.758 70 58.060 142-82-5 P7 n-Heptane 0.909 1.000 0.705 250.301 71 58.276 7642-10-6 K7 c-Heptene-3 0.023 0.025 0.019 6.599 72 58.547 2738-19-4 C7 2-Methyl-2-hexene 0.025 0.027 0.020 7.076 73 58.792 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.472

74 59.173 14686-13-6 K7 t-Heptene-2 0.012 0.013 0.010 3.419 75 59.650 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 5.183 76 60.078 20710-38-8 C7 3-Methyl-t-hexene-2 0.016 0.016 0.012 4.415 77 60.860 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.012 0.013 0.010 3.388 78 61.523 108-87-2 M7 Methylcyclohexane 1.377 1.347 1.089 386.953 79 62.459 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.041 0.041 0.028 11.386 80 62.848 590-73-8 I8 2,2-Dimethylhexane 0.034 0.037 0.023 9.453 81 63.359 ? Unidentified 0.054 0.057 0.038 18.669 82 64.297 1640-89-7 M7 Ethylcyclopentane 0.066 0.065 0.052 18.498 83 64.945 564-02-3 I8 2,2,3-Trimethylpentane 0.057 0.060 0.039 15.846

84 65.169 592-13-2 I8 2,5-Dimethylhexane 0.181 0.197 0.123 50.088 85 65.506 589-43-5 I8 2,4-Dimethylhexane 0.191 0.205 0.130 52.699 86 66.345 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.042 0.041 0.029 11.757

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.739 563-16-6 I8 3,3-Dimethylhexane 0.028 0.030 0.019 7.782 88 67.858 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.038 0.037 0.026 10.575 89 68.470 565-75-3 I8 2,3,4-Trimethylpentane 0.409 0.428 0.278 112.781 90 69.019 108-88-3 Q7 Toluene 5.523 4.794 4.657 1653.405 91 70.512 C8 C8 - Diolefin - 1 0.017 0.016 0.012 4.679 92 70.791 584-94-1 I8 2,3-Dimethylhexane 0.160 0.169 0.109 44.175 93 72.049 592-27-8 I8 2-Methylheptane 0.330 0.355 0.224 90.953 94 72.301 589-53-7 I8 4-Methylheptane 0.126 0.135 0.086 34.844 95 72.450 ? Unidentified 0.013 0.014 0.009 4.570 96 73.225 M8 1,3-dimethyl-t-cyclohexane 0.263 0.257 0.182 73.975

97 73.362 589-81-1 I8 3-Methylheptane 0.278 0.297 0.189 76.791 98 73.563 619-99-8 I8 3-Ethylhexane 0.160 0.169 0.109 44.185 99 74.459 ? Unidentified 0.042 0.041 0.029 14.575 100 75.247 3522-94-9 I9 2,2,5-Trimethylhexane 0.178 0.190 0.108 49.329 101 75.609 M8 3c-Ethylmethylcyclopentane 0.015 0.015 0.011 4.346 102 75.825 M8 3t-Ethylmethylcyclopentane 0.022 0.022 0.015 6.221 103 76.530 ? Unidentified 0.100 0.097 0.069 34.502 104 77.875 111-65-9 P8 n-Octane 0.810 0.867 0.551 223.484 105 80.353 1069-53-0 I9 2,3,5-Trimethylhexane 0.030 0.031 0.018 8.275 106 80.908 C8 C9 - IsoOlefin - 1 0.029 0.028 0.020 8.016

107 81.366 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.024 0.022 0.016 6.646 108 81.521 1071-26-7 I9 2,4-Dimethylheptane 0.046 0.048 0.028 12.595 109 82.175 1678-91-7 M8 Ethylcyclohexane 0.199 0.191 0.138 55.853 110 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.088 0.093 0.053 24.338 111 82.976 ? Unidentified 0.041 0.040 0.029 14.247 112 83.406 I9 2,5-Dimethylheptane 0.116 0.122 0.070 32.038 113 83.605 926-82-9 I9 3,5-Dimethylheptane 0.028 0.029 0.017 7.803 114 84.731 100-41-4 Q8 Ethylbenzene 0.992 0.861 0.726 294.651 115 84.922 ? Unidentified 0.013 0.013 0.008 4.399 116 85.153 ? Unidentified 0.030 0.029 0.019 10.450

117 85.958 108-38-3 Q8 m-Xylene 2.730 2.378 1.998 811.298 118 86.104 106-42-3 Q8 p-Xylene 1.181 1.032 0.864 350.901 119 86.231 ? Unidentified 0.038 0.040 0.023 13.185 120 86.596 ? Unidentified 0.014 0.013 0.009 4.787 121 86.755 I9 3,5-Dimethylheptane 0.017 0.018 0.010 4.754 122 86.883 1067-20-5 I9 3,3-Diethylpentane 0.015 0.015 0.009 4.028 123 87.275 2216-34-4 I9 4-Methyloctane 0.091 0.095 0.055 25.046 124 87.407 3221-61-2 I9 2-Methyloctane 0.120 0.127 0.073 33.265 125 87.884 B9 C9 - NaphOlefin - 2 0.007 0.007 0.004 2.014 126 88.108 15869-80-4 I9 Heptane, 3-ethyl- 0.017 0.018 0.010 4.694

127 88.270 2216-33-3 I9 3-Methyloctane 0.117 0.123 0.071 32.451 128 88.930 95-47-6 Q8 o-Xylene 0.891 0.762 0.652 264.656 129 89.322 I10 C10 - IsoParaffin - 1 0.025 0.026 0.014 6.861

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 89.756 3728-57-2 M8 Cyclopentane, 1-methyl-2-propyl- 0.009 0.008 0.007 2.677 131 89.912 M9 trans-1,3-Diethylcyclopentane 0.033 0.029 0.021 9.922 132 90.182 14720-74-2 I10 2,2,4-trimethylheptane 0.046 0.047 0.025 12.611 133 91.748 111-84-2 P9 n-Nonane 0.283 0.297 0.171 78.269 134 92.324 4926-90-3 M9 1,1-Methylethylcyclohexane 0.028 0.026 0.017 7.878 135 93.095 98-82-8 Q9 i-Propylbenzene 0.035 0.031 0.023 10.407 136 93.273 ? Unidentified 0.008 0.008 0.005 2.876 137 93.273 ? Unidentified 0.008 0.009 0.005 2.876 138 93.273 ? Unidentified 0.008 0.006 0.005 2.876 139 93.387 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.004 0.004 0.002 1.119

140 93.387 C10 C10-IsoOlefin-4 0.004 0.004 0.002 1.119 141 93.387 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.119 142 93.843 ? Unidentified 0.150 0.156 0.082 51.658 143 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.054 0.056 0.029 14.888 144 94.526 ? Unidentified 0.019 0.014 1.470 6.512 145 94.526 ? Unidentified 0.019 0.020 0.010 6.512 146 94.722 ? Unidentified 0.022 0.021 0.014 7.613 147 94.862 15869-89-3 I10 2,5-Dimethyloctane 0.093 0.096 0.051 25.784 148 95.068 I10 C10 - IsoParaffin - 2 0.014 0.015 0.008 3.942 149 95.326 2040-95-1 I10 2,7-Dimethyloctane 0.056 0.058 0.030 15.463

150 95.509 2051-30-1 I10 2,4-Dimethyloctane 0.242 0.251 0.132 67.191 151 95.896 I10 2,6-Dimethyloctane 0.075 0.077 0.041 20.711 152 96.060 I10 C10 Isoparaffin -1 0.005 0.005 0.003 1.419 153 96.555 103-65-1 Q9 n-Propylbenzene 0.315 0.275 0.204 93.069 154 96.754 I10 3-Methyl-5-ethylheptane 0.009 0.010 0.005 2.612 155 97.402 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.105 0.962 0.714 326.178 156 97.635 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.497 0.435 0.322 146.856 157 98.260 108-67-8 Q9 1,3,5-Trimethylbenzene 0.711 0.618 0.459 209.794 158 98.725 15869-85-9 I10 5-Methylnonane 0.011 0.011 0.006 2.928 159 98.915 17301-94-8 I10 4-Methylnonane 0.023 0.024 0.013 6.459

160 99.140 I10 2,2,6-Trimethyloctane 3.878 4.017 2.118 1074.551 161 99.346 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.363 0.310 0.235 107.124 162 99.710 ? Unidentified 0.012 0.012 0.007 4.150 163 99.890 5911-04-6 I10 3-Methylnonane 0.023 0.024 0.013 6.427 164 100.074 ? Unidentified 0.013 0.014 0.007 4.393 165 100.356 ? Unidentified 0.224 0.168 0.111 77.047 166 100.489 ? Unidentified 0.619 0.626 0.308 213.181 167 100.705 I11 C11-Isoparaffin-2 0.326 0.330 0.162 90.374 168 100.982 95-63-6 Q9 1,2,4-Trimethylbenzene 1.845 1.585 1.193 544.634 169 101.170 ? Unidentified 0.370 0.397 0.205 127.269

170 101.292 ? Unidentified 0.219 0.225 0.120 75.383 171 101.554 ? Unidentified 0.050 0.051 0.027 17.139 172 102.197 ? Unidentified 0.025 0.024 0.014 8.604

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 102.341 17302-01-1 I10 3-Ethyl-3-methylheptane 0.525 0.531 0.261 145.746 174 102.546 ? Unidentified 0.130 0.131 0.064 44.638 175 102.690 538-93-2 Q10 i-Butylbenzene 0.408 0.360 0.236 119.797 176 102.890 124-18-5 P10 n-Decane 0.041 0.043 0.023 11.485 177 103.200 ? Unidentified 0.129 0.131 0.072 44.497 178 103.689 ? Unidentified 0.019 0.016 0.012 6.517 179 103.855 526-73-8 Q9 1,2,3-Trimethylbenzene 0.225 0.190 0.146 66.529 180 104.195 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.045 0.040 0.026 13.286 181 104.412 I11 C11 Isoparaffin-4 0.064 0.065 0.032 17.757 182 104.619 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.378 0.332 0.219 110.990

183 104.955 ? Unidentified 0.065 0.051 0.043 22.402 184 105.052 J9 Indan 0.106 0.083 0.070 31.900 185 105.265 I11 C11-Isoparaffin-5 0.026 0.026 0.013 7.143 186 105.652 J10 Indene 1.591 1.242 1.046 477.486 187 106.079 M10 n-ButylCyclohexane 0.003 0.003 0.002 0.819 188 106.205 ? Unidentified 0.011 0.011 0.006 3.946 189 106.363 I11 C11-Isoparaffin-7 0.572 0.578 0.284 158.540 190 106.552 141-93-5 Q10 1,3-Diethylbenzene 0.024 0.021 0.014 6.962 191 106.847 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.674 1.463 0.969 491.568 192 107.105 105-05-5 Q10 1,4-Diethylbenzene 0.415 0.362 0.240 121.806

193 107.385 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.104 0.089 0.060 30.440 194 107.621 135-01-3 Q10 1,2-Diethylbenzene 0.116 0.099 0.067 34.073 195 108.084 ? Unidentified 0.127 0.128 0.063 43.588 196 108.237 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.043 0.037 0.025 12.536 197 108.359 ? Unidentified 0.129 0.131 0.065 44.289 198 108.438 ? Unidentified 0.119 0.121 0.059 41.124 199 108.569 I11 C11- Isoparaffin-11 0.961 0.972 0.478 266.662 200 108.747 ? Unidentified 0.306 0.310 0.152 105.438 201 109.171 ? Unidentified 0.861 0.739 0.499 296.547 202 109.397 J10 2-Methylindan 0.142 0.111 0.084 42.717

203 109.743 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.309 0.265 0.179 90.595 204 109.875 ? Unidentified 0.041 0.035 0.024 14.031 205 110.288 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.734 0.620 0.425 215.546 206 110.712 ? Unidentified 0.025 0.023 0.013 8.746 207 110.906 693-61-8 K11 2-Undecene, (E)- 0.062 0.063 0.034 17.283 208 111.039 ? Unidentified 0.139 0.141 0.077 47.762 209 111.311 ? Unidentified 0.120 0.102 0.063 41.477 210 111.411 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.060 0.051 0.035 17.660 211 111.711 1120-21-4 P11 n-Undecane 0.086 0.087 0.043 23.760 212 111.862 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.100 0.084 0.052 29.208

213 111.974 ? Unidentified 0.066 0.056 0.034 22.649 214 112.349 Q10 1,2,4,5-Tetramethylbenzene 0.222 0.188 0.128 65.160 215 112.615 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.291 0.246 0.169 85.580

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 112.827 ? Unidentified 0.013 0.011 0.007 4.609 217 112.956 ? Unidentified 0.017 0.014 0.010 5.759 218 113.131 I12 C12 - IsoParaffin - 1 0.026 0.026 0.012 7.234 219 113.476 ? Unidentified 0.032 0.032 0.014 10.874 220 113.613 ? Unidentified 0.010 0.011 0.005 3.612 221 113.811 Q11 C11 - Aromatic - 3 0.060 0.051 0.032 17.574 222 113.946 874-35-1 H10 5-Methylindan 0.092 0.078 0.054 27.092 223 114.070 Q12 1,2-Di-i-propylbenzene 0.034 0.029 0.016 9.887 224 114.285 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.047 0.040 0.025 13.688 225 114.449 Q11 C11 - Aromatic - 4 0.031 0.026 0.016 9.126

226 114.695 824-22-6 J10 4-Methylindan 0.114 0.096 0.067 33.388 227 114.849 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.027 0.023 0.014 7.966 228 114.942 824-63-5 H10 2-Methylindan 0.087 0.073 0.051 25.506 229 115.145 ? Unidentified 0.010 0.008 0.005 3.392 230 115.258 538-68-1 Q11 n-Pentylbenzene 0.011 0.009 0.006 3.165 231 115.486 Q11 tert-Pentylbenzene 0.045 0.038 0.024 13.191 232 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.019 0.016 0.010 5.615 233 115.909 Q11 C11 - Aromatic - 7 0.027 0.024 0.014 7.936 234 116.369 100-18-5 Q12 1,4-Di-i-propylbenzene 0.036 0.030 0.017 10.472 235 116.811 91-20-3 G10 Naphthalene 0.095 0.070 0.058 29.213

236 117.248 J11 1,1-Dimethyl Indane 0.009 0.007 0.005 2.593 237 117.413 J12 Dimethyl Indane - 1 0.004 0.003 0.002 1.157 238 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.005 0.004 0.003 1.535 239 117.895 Q12 1,3-Di-n-propylbenzene 0.033 0.028 0.016 9.732 240 118.005 Q11 C11 - Aromatic - 11 0.019 0.017 0.010 5.529 241 118.559 Q11 C11 - Aromatic - 12 0.014 0.012 0.007 3.968 242 123.440 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.005 2.931 243 124.306 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.546 244 130.003 ? Unidentified 0.003 0.002 0.002 1.064

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.553 74-98-6 Propane 0.008 0.012 0.014 2.117

10.024 106-97-8 n-Butane 0.504 0.656 0.674 136.813 18.117 109-66-0 n-Pentane 1.264 1.519 1.361 345.443 35.827 110-54-3 n-Hexane 4.274 4.878 3.854 1172.592 58.060 142-82-5 n-Heptane 0.909 1.000 0.705 250.301 77.875 111-65-9 n-Octane 0.810 0.867 0.551 223.484 91.748 111-84-2 n-Nonane 0.283 0.297 0.171 78.269 102.890 124-18-5 n-Decane 0.041 0.043 0.023 11.485 111.711 1120-21-4 n-Undecane 0.086 0.087 0.043 23.760

I-Paraffins 8.810 75-28-5 i-Butane 0.068 0.092 0.092 18.575

10.637 463-82-1 2,2-Dimethylpropane 0.007 0.008 0.007 1.806 15.077 78-78-4 i-Pentane 3.117 3.786 3.356 851.694 23.092 75-83-2 2,2-Dimethylbutane 0.216 0.251 0.195 59.275 28.338 79-29-8 2,3-Dimethylbutane 1.008 1.147 0.909 276.570 29.436 107-83-5 2-Methylpentane 5.203 5.995 4.691 1427.392 32.075 96-14-0 3-Methylpentane 3.287 3.724 2.964 901.752 42.233 108-08-7 2,4-Dimethylpentane 0.431 0.483 0.334 118.818 42.781 464-06-2 2,2,3-Trimethylbutane 0.053 0.058 0.041 14.724 50.666 591-76-4 2-Methylhexane 1.231 1.365 0.954 339.006 52.493 589-34-4 3-Methylhexane 0.776 0.850 0.602 213.780 55.148 540-84-1 2,2,4-Trimethylpentane 1.102 1.198 0.749 304.018 62.848 590-73-8 2,2-Dimethylhexane 0.034 0.037 0.023 9.453 64.945 564-02-3 2,2,3-Trimethylpentane 0.057 0.060 0.039 15.846 65.169 592-13-2 2,5-Dimethylhexane 0.181 0.197 0.123 50.088 65.506 589-43-5 2,4-Dimethylhexane 0.191 0.205 0.130 52.699 66.739 563-16-6 3,3-Dimethylhexane 0.028 0.030 0.019 7.782 68.470 565-75-3 2,3,4-Trimethylpentane 0.409 0.428 0.278 112.781 70.791 584-94-1 2,3-Dimethylhexane 0.160 0.169 0.109 44.175 72.049 592-27-8 2-Methylheptane 0.330 0.355 0.224 90.953 72.301 589-53-7 4-Methylheptane 0.126 0.135 0.086 34.844 73.362 589-81-1 3-Methylheptane 0.278 0.297 0.189 76.791 73.563 619-99-8 3-Ethylhexane 0.160 0.169 0.109 44.185 75.247 3522-94-9 2,2,5-Trimethylhexane 0.178 0.190 0.108 49.329 80.353 1069-53-0 2,3,5-Trimethylhexane 0.030 0.031 0.018 8.275 81.521 1071-26-7 2,4-Dimethylheptane 0.046 0.048 0.028 12.595 82.476 1072-05-5 2,6-Dimethylheptane 0.088 0.093 0.053 24.338 83.406 2,5-Dimethylheptane 0.116 0.122 0.070 32.038 83.605 926-82-9 3,5-Dimethylheptane 0.028 0.029 0.017 7.803 86.755 3,5-Dimethylheptane 0.017 0.018 0.010 4.754 86.883 1067-20-5 3,3-Diethylpentane 0.015 0.015 0.009 4.028 87.275 2216-34-4 4-Methyloctane 0.091 0.095 0.055 25.046 87.407 3221-61-2 2-Methyloctane 0.120 0.127 0.073 33.265 88.108 15869-80-4 Heptane, 3-ethyl- 0.017 0.018 0.010 4.694 88.270 2216-33-3 3-Methyloctane 0.117 0.123 0.071 32.451 89.322 C10 - IsoParaffin - 1 0.025 0.026 0.014 6.861 90.182 14720-74-2 2,2,4-trimethylheptane 0.046 0.047 0.025 12.611

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 93.387 C10-isoparaffin-x 0.000 0.000 0.000 1.119

94.064 15869-87-1 2,2-Dimethyloctane 0.054 0.056 0.029 14.888 94.862 15869-89-3 2,5-Dimethyloctane 0.093 0.096 0.051 25.784 95.068 C10 - IsoParaffin - 2 0.014 0.015 0.008 3.942 95.326 2040-95-1 2,7-Dimethyloctane 0.056 0.058 0.030 15.463 95.509 2051-30-1 2,4-Dimethyloctane 0.242 0.251 0.132 67.191 95.896 2,6-Dimethyloctane 0.075 0.077 0.041 20.711 96.060 C10 Isoparaffin -1 0.005 0.005 0.003 1.419 96.754 3-Methyl-5-ethylheptane 0.009 0.010 0.005 2.612 98.725 15869-85-9 5-Methylnonane 0.011 0.011 0.006 2.928 98.915 17301-94-8 4-Methylnonane 0.023 0.024 0.013 6.459 99.140 2,2,6-Trimethyloctane 3.878 4.017 2.118 1074.551 99.890 5911-04-6 3-Methylnonane 0.023 0.024 0.013 6.427 100.705 C11-Isoparaffin-2 0.326 0.330 0.162 90.374 102.341 17302-01-1 3-Ethyl-3-methylheptane 0.525 0.531 0.261 145.746 104.412 C11 Isoparaffin-4 0.064 0.065 0.032 17.757 105.265 C11-Isoparaffin-5 0.026 0.026 0.013 7.143 106.363 C11-Isoparaffin-7 0.572 0.578 0.284 158.540 108.569 C11- Isoparaffin-11 0.961 0.972 0.478 266.662 113.131 C12 - IsoParaffin - 1 0.026 0.026 0.012 7.234

Aromatics Mono-Aromatics 45.639 71-42-3 Benzene 0.724 0.620 0.720 219.241

69.019 108-88-3 Toluene 5.523 4.794 4.657 1653.405 84.731 100-41-4 Ethylbenzene 0.992 0.861 0.726 294.651 85.958 108-38-3 m-Xylene 2.730 2.378 1.998 811.298 86.104 106-42-3 p-Xylene 1.181 1.032 0.864 350.901 88.930 95-47-6 o-Xylene 0.891 0.762 0.652 264.656 93.095 98-82-8 i-Propylbenzene 0.035 0.031 0.023 10.407 96.555 103-65-1 n-Propylbenzene 0.315 0.275 0.204 93.069 97.402 620-14-4 1-Methyl-3-ethylbenzene 1.105 0.962 0.714 326.178 97.635 622-96-8 1-Methyl-4-ethylbenzene 0.497 0.435 0.322 146.856 98.260 108-67-8 1,3,5-Trimethylbenzene 0.711 0.618 0.459 209.794 99.346 611-14-3 1-Methyl-2-ethylbenzene 0.363 0.310 0.235 107.124 100.982 95-63-6 1,2,4-Trimethylbenzene 1.845 1.585 1.193 544.634 102.690 538-93-2 i-Butylbenzene 0.408 0.360 0.236 119.797 103.855 526-73-8 1,2,3-Trimethylbenzene 0.225 0.190 0.146 66.529 104.195 535-77-3 1-Methyl-3-i-propylbenzene 0.045 0.040 0.026 13.286 104.619 99-87-6 1-Methyl-4-i-propylbenzene 0.378 0.332 0.219 110.990 106.552 141-93-5 1,3-Diethylbenzene 0.024 0.021 0.014 6.962 106.847 1074-43-7 1-Methyl-3-n-propylbenzene 1.674 1.463 0.969 491.568 107.105 105-05-5 1,4-Diethylbenzene 0.415 0.362 0.240 121.806 107.385 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.104 0.089 0.060 30.440 107.621 135-01-3 1,2-Diethylbenzene 0.116 0.099 0.067 34.073 108.237 1074-17-5 1-Methyl-2-n-propylbenzene 0.043 0.037 0.025 12.536 109.743 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.309 0.265 0.179 90.595 110.288 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.734 0.620 0.425 215.546

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 111.411 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.060 0.051 0.035 17.660

111.862 4218-48-8 1-Ethyl-4-i-propylbenzene 0.100 0.084 0.052 29.208 112.349 1,2,4,5-Tetramethylbenzene 0.222 0.188 0.128 65.160 112.615 527-53-7 1,2,3,5-Tetramethylbenzene 0.291 0.246 0.169 85.580 113.811 C11 - Aromatic - 3 0.060 0.051 0.032 17.574 114.070 1,2-Di-i-propylbenzene 0.034 0.029 0.016 9.887 114.285 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.047 0.040 0.025 13.688 114.449 C11 - Aromatic - 4 0.031 0.026 0.016 9.126 114.849 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.027 0.023 0.014 7.966 115.258 538-68-1 n-Pentylbenzene 0.011 0.009 0.006 3.165 115.486 tert-Pentylbenzene 0.045 0.038 0.024 13.191 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.019 0.016 0.010 5.615 115.909 C11 - Aromatic - 7 0.027 0.024 0.014 7.936 116.369 100-18-5 1,4-Di-i-propylbenzene 0.036 0.030 0.017 10.472 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.005 0.004 0.003 1.535 117.895 1,3-Di-n-propylbenzene 0.033 0.028 0.016 9.732 118.005 C11 - Aromatic - 11 0.019 0.017 0.010 5.529 118.559 C11 - Aromatic - 12 0.014 0.012 0.007 3.968

Naphthalenes 116.811 91-20-3 Naphthalene 0.095 0.070 0.058 29.213

123.440 91-57-6 2-Methylnaphthalene 0.010 0.007 0.005 2.931 124.306 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.546

Naphtheno/Olefino-Benzs

113.946 874-35-1 5-Methylindan 0.092 0.078 0.054 27.092 114.942 824-63-5 2-Methylindan 0.087 0.073 0.051 25.506

Indenes 105.052 Indan 0.106 0.083 0.070 31.900

105.652 Indene 1.591 1.242 1.046 477.486 109.397 2-Methylindan 0.142 0.111 0.084 42.717 114.695 824-22-6 4-Methylindan 0.114 0.096 0.067 33.388 117.248 1,1-Dimethyl Indane 0.009 0.007 0.005 2.593 117.413 Dimethyl Indane - 1 0.004 0.003 0.002 1.157

Naphthenes Mono-Naphthenes 27.606 287-92-3 Cyclopentane 0.235 0.237 0.260 66.074

40.678 96-37-7 Methylcyclopentane 1.892 1.902 1.746 531.671 47.559 110-82-7 Cyclohexane 1.438 1.391 1.328 404.294 53.353 1759-58-6 1t,3-Dimethylcyclopentane 0.194 0.195 0.154 54.572 53.939 2532-58-3 1c,3-Dimethylcyclopentane 0.154 0.156 0.122 43.326 54.561 822-50-4 1t,2-Dimethylcyclopentane 0.234 0.234 0.185 65.793 59.650 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 5.183 61.523 108-87-2 Methylcyclohexane 1.377 1.347 1.089 386.953 62.459 4516-69-2 1,1,3-Trimethylcyclopentane 0.041 0.041 0.028 11.386 64.297 1640-89-7 Ethylcyclopentane 0.066 0.065 0.052 18.498 66.345 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.042 0.041 0.029 11.757 67.858 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.038 0.037 0.026 10.575 73.225 1,3-dimethyl-t-cyclohexane 0.263 0.257 0.182 73.975

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 75.609 3c-Ethylmethylcyclopentane 0.015 0.015 0.011 4.346

75.825 3t-Ethylmethylcyclopentane 0.022 0.022 0.015 6.221 81.366 2207-01-4 1c,2-Dimethylcyclohexane 0.024 0.022 0.016 6.646 82.175 1678-91-7 Ethylcyclohexane 0.199 0.191 0.138 55.853 89.756 3728-57-2 Cyclopentane, 1-methyl-2-propyl- 0.009 0.008 0.007 2.677 89.912 trans-1,3-Diethylcyclopentane 0.033 0.029 0.021 9.922 92.324 4926-90-3 1,1-Methylethylcyclohexane 0.028 0.026 0.017 7.878 93.387 696-29-7 1-Methyl-2-propyl-cyclopentan 0.004 0.004 0.002 1.119 106.079 n-ButylCyclohexane 0.003 0.003 0.002 0.819

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.624 115-11-7 Isobutene 0.016 0.020 0.022 4.438

9.665 106-98-9 Butene-1 0.018 0.022 0.024 4.971 10.510 624-64-6 t-Butene-2 0.072 0.089 0.099 20.107 11.252 590-18-1 c-Butene-2 0.085 0.102 0.117 23.755 16.730 109-67-1 Pentene-1 0.327 0.384 0.362 91.959 19.236 646-04-8 t-Pentene-2 0.831 0.965 0.921 233.676 20.267 627-20-3 c-Pentene-2 0.456 0.523 0.505 128.173 33.455 592-41-6 Hexene-1 0.158 0.175 0.146 44.390 36.441 13269-52-8 t-Hexene-3 0.260 0.287 0.240 73.101 36.917 4050-45-7 t-Hexene-2 0.398 0.438 0.367 111.781 38.745 7688-21-3 c-Hexene-2 0.212 0.230 0.195 59.449 55.468 592-76-7 Heptene-1 0.029 0.031 0.023 8.040 57.331 14686-14-7 t-Heptene-3 0.031 0.034 0.025 8.804 58.276 7642-10-6 c-Heptene-3 0.023 0.025 0.019 6.599 59.173 14686-13-6 t-Heptene-2 0.012 0.013 0.010 3.419 110.906 693-61-8 2-Undecene, (E)- 0.062 0.063 0.034 17.283

Iso-Olefins 13.454 563-45-1 3-Methylbutene-1 0.212 0.255 0.235 59.661

17.580 563-46-2 2-Methylbutene-1 0.496 0.574 0.550 139.529 20.944 513-35-9 2-Methylbutene-2 1.021 1.161 1.132 287.088 29.197 691-38-3 4-Methyl-c-pentene-2 0.045 0.050 0.041 12.606 29.846 674-76-0 4-Methyl-t-pentene-2 0.129 0.144 0.119 36.274 33.228 763-29-1 2-Methylpentene-1 0.221 0.243 0.204 62.196 37.408 625-27-4 2-Methylpentene-2 0.336 0.366 0.311 94.559 37.820 922-62-3 3-Methyl-c-pentene-2 0.261 0.281 0.241 73.337 40.089 3404-73-7 3,3-Dimethylpentene-1 0.307 0.330 0.243 86.391 42.533 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.011 3.887 46.640 3404-61-3 3-Methylhexene-1 0.016 0.017 0.013 4.507 47.236 3524-73-0 5-Methylhexene-1 0.082 0.088 0.065 22.959 49.272 15840-60-5 2-Methyl-c-hexene-3 0.040 0.043 0.032 11.193 49.622 3769-23-1 4-Methylhexene-1 0.011 0.012 0.009 3.228 50.267 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.054 0.040 14.212 54.847 C7 - Iso-Olefin - 2 0.022 0.023 0.017 6.127 56.801 4914-89-0 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.872 57.684 6094-02-6 2-Methylhexene-1 0.056 0.061 0.044 15.758

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 58.547 2738-19-4 2-Methyl-2-hexene 0.025 0.027 0.020 7.076

58.792 10574-36-4 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.472 60.078 20710-38-8 3-Methyl-t-hexene-2 0.016 0.016 0.012 4.415 60.860 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.012 0.013 0.010 3.388 70.512 C8 - Diolefin - 1 0.017 0.016 0.012 4.679 80.908 C9 - IsoOlefin - 1 0.029 0.028 0.020 8.016 93.387 C10-IsoOlefin-4 0.004 0.004 0.002 1.119

Naphtheno-Olefins 22.538 1574-41-0 1,3-Cyclopentadiene 0.007 0.007 0.008 1.971

25.740 142-29-0 Cyclopentene 0.194 0.189 0.221 56.071 37.043 1120-62-3 3-Methylcyclopentene 0.100 0.099 0.095 28.141 45.833 693-89-0 1-Methylcyclopentene 0.357 0.345 0.338 102.729 51.153 110-83-8 Cyclohexene 0.044 0.041 0.042 12.426 87.884 C9 - NaphOlefin - 2 0.007 0.007 0.004 2.014

Di-Olefins 18.627 78-79-5 2-Methyl-1,3-Butadiene 0.012 0.013 0.014 3.463

21.271 2004-70-8 1t,3-Pentadiene 0.015 0.017 0.017 4.436 45.426 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 4.281

Oxygenates 13.136 64-17-5 Ethanol 22.401 21.366 37.779 2592.448

26.902 71-23-8 n-Propanol 0.074 0.069 0.095 14.507 48.059 71-36-3 n-Butanol 0.055 0.052 0.058 11.742

Unidentified 19.879 Unidentified 0.006 0.007 0.006 1.988

26.998 Unidentified 0.059 0.066 0.054 20.289 28.734 Unidentified 0.052 0.053 0.046 17.890 50.841 Unidentified 0.068 0.074 0.055 23.503 63.359 Unidentified 0.054 0.057 0.038 18.669 72.450 Unidentified 0.013 0.014 0.009 4.570 74.459 Unidentified 0.042 0.041 0.029 14.575 76.530 Unidentified 0.100 0.097 0.069 34.502 82.976 Unidentified 0.041 0.040 0.029 14.247 84.922 Unidentified 0.013 0.013 0.008 4.399 85.153 Unidentified 0.030 0.029 0.019 10.450 86.231 Unidentified 0.038 0.040 0.023 13.185 86.596 Unidentified 0.014 0.013 0.009 4.787 93.273 Unidentified 0.008 0.008 0.005 2.876 93.273 Unidentified 0.008 0.009 0.005 2.876 93.273 Unidentified 0.008 0.006 0.005 2.876 93.843 Unidentified 0.150 0.156 0.082 51.658 94.526 Unidentified 0.019 0.014 1.470 6.512 94.526 Unidentified 0.019 0.020 0.010 6.512 94.722 Unidentified 0.022 0.021 0.014 7.613 99.710 Unidentified 0.012 0.012 0.007 4.150 100.074 Unidentified 0.013 0.014 0.007 4.393 100.356 Unidentified 0.224 0.168 0.111 77.047 100.489 Unidentified 0.619 0.626 0.308 213.181

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 101.170 Unidentified 0.370 0.397 0.205 127.269

101.292 Unidentified 0.219 0.225 0.120 75.383 101.554 Unidentified 0.050 0.051 0.027 17.139 102.197 Unidentified 0.025 0.024 0.014 8.604 102.546 Unidentified 0.130 0.131 0.064 44.638 103.200 Unidentified 0.129 0.131 0.072 44.497 103.689 Unidentified 0.019 0.016 0.012 6.517 104.955 Unidentified 0.065 0.051 0.043 22.402 106.205 Unidentified 0.011 0.011 0.006 3.946 108.084 Unidentified 0.127 0.128 0.063 43.588 108.359 Unidentified 0.129 0.131 0.065 44.289 108.438 Unidentified 0.119 0.121 0.059 41.124 108.747 Unidentified 0.306 0.310 0.152 105.438 109.171 Unidentified 0.861 0.739 0.499 296.547 109.875 Unidentified 0.041 0.035 0.024 14.031 110.712 Unidentified 0.025 0.023 0.013 8.746 111.039 Unidentified 0.139 0.141 0.077 47.762 111.311 Unidentified 0.120 0.102 0.063 41.477 111.974 Unidentified 0.066 0.056 0.034 22.649 112.827 Unidentified 0.013 0.011 0.007 4.609 112.956 Unidentified 0.017 0.014 0.010 5.759 113.476 Unidentified 0.032 0.032 0.014 10.874 113.613 Unidentified 0.010 0.011 0.005 3.612 115.145 Unidentified 0.010 0.008 0.005 3.392 130.003 Unidentified 0.003 0.002 0.002 1.064

Plus

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified

c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane

2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2

2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1

n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)-

Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane Toluene

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane

Unidentified

n-Octane

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane C9 - NaphOlefin - 2 Heptane, 3-ethyl- 3-Methyloctane o-Xylene C10 - IsoParaffin - 1 Cyclopentane, 1-methyl-2-propyl- trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane C10 - IsoParaffin - 2 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane C10 Isoparaffin -1 n-Propylbenzene 3-Methyl-5-ethylheptane 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified

Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified Unidentified
Unidentified

3-Ethyl-3-methylheptane Unidentified i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Unidentified Indan C11-Isoparaffin-5 Indene n-ButylCyclohexane Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 08:35:09 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF Sample: ODDB-91327 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91327 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000009.D\SIG2000009_FID2_B.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 8.442 10.248 9.404

I-Paraffins 28.876 31.453 21.590

Aromatics 23.029 19.560 16.025 Mono-Aromatics 20.934 17.927 14.709 Naphthalenes 0.092 0.067 0.054 Naphtheno/Olefino-Benzs 0.183 0.153 0.106 Indenes 1.820 1.413 1.156

Naphthenes 3.829 3.738 3.170 Mono-Naphthenes 3.829 3.738 3.170 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.571 8.311 7.472 n-Olefins 3.228 3.620 3.236 Iso-Olefins 3.585 3.960 3.487 Naphtheno-Olefins 0.716 0.687 0.705 Di-Olefins 0.042 0.044 0.044

Oxygenates 23.072 21.767 38.167

Unidentified 5.181 4.922 4.172

Plus 0.000 0.000 0.000

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 22.944 21.648 38.018 C3 0.078 0.077 0.102 C4 4.935 6.318 6.476 C5 9.429 11.020 10.102 C6 12.051 12.985 10.847 C7 10.196 9.729 8.152 C8 16.487 16.257 11.313 C9 6.308 5.658 3.949 C10 10.732 9.825 6.046 C11 1.504 1.427 0.751 C12 0.154 0.133 0.072

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.007 0.010 0.011 C4 4.614 5.935 6.060 C5 1.445 1.718 1.529 C6 0.910 1.027 0.806 C7 0.583 0.635 0.444 C8 0.536 0.568 0.358 C9 0.228 0.237 0.136 C10 0.039 0.040 0.021 C11 0.080 0.080 0.039

I-Paraffins C4 0.066 0.088 0.086 C5 4.094 4.919 4.331 C6 6.112 6.917 5.414 C7 2.180 2.390 1.661 C8 9.730 10.289 6.502 C9 1.206 1.261 0.718 C10 4.570 4.670 2.429 C11 0.890 0.891 0.435 C12 0.029 0.029 0.013

Mono-Aromatics C6 0.772 0.654 0.755 C7 5.223 4.484 4.327 C8 5.679 4.879 4.084 C9 4.729 4.044 3.004 C10 3.964 3.389 2.254 C11 0.442 0.372 0.228 C12 0.125 0.104 0.059

Naphthalenes C10 0.076 0.055 0.045 C11 0.016 0.012 0.009

Naphtheno/Olefino-Benzs C10 0.183 0.153 0.106

Indenes C9 0.099 0.076 0.064 C10 1.702 1.322 1.083 C11 0.019 0.015 0.010

Mono-Naphthenes C5 0.175 0.175 0.190 C6 1.607 1.578 1.457 C7 1.439 1.405 1.119 C8 0.512 0.493 0.348 C9 0.045 0.040 0.027

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C10 0.051 0.048 0.028

n-Olefins C4 0.200 0.244 0.271 C5 1.675 1.922 1.823 C6 1.053 1.147 0.955 C7 0.099 0.105 0.077 C10 0.144 0.145 0.078 C11 0.057 0.057 0.031

Iso-Olefins C5 1.807 2.056 1.967 C6 1.087 1.175 0.986 C7 0.657 0.696 0.511 C8 0.030 0.029 0.020 C10 0.004 0.004 0.002

Naphtheno-Olefins C5 0.207 0.201 0.232 C6 0.509 0.487 0.473

Di-Olefins C5 0.026 0.029 0.030 C7 0.015 0.015 0.014

Oxygenates C2 22.944 21.648 38.018 C3 0.072 0.067 0.091 C4 0.056 0.052 0.058

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.55 21.29 5% 55.00 29.21 10% 87.23 80.98 15% 134.26 97.23 20% 144.68 138.35 25% 161.44 146.09 30% 172.42 172.23 35% 172.66 172.48 40% 172.89 172.73 45% 173.13 172.98 50% 176.90 173.23 55% 209.58 197.14 60% 228.87 210.20 65% 231.05 230.83 70% 251.09 236.75 75% 281.64 277.01 80% 321.45 296.60 85% 332.47 332.04 90% 352.22 349.06 95% 363.20 363.20 FBP 399.20 388.21

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.554 74-98-6 P3 Propane 0.007 0.010 0.011 1.701 2 8.810 75-28-5 I4 i-Butane 0.066 0.088 0.086 17.158 3 9.623 115-11-7 K4 Isobutene 0.017 0.021 0.023 4.515 4 9.665 106-98-9 K4 Butene-1 0.019 0.023 0.025 5.019 5 10.024 106-97-8 P4 n-Butane 4.614 5.935 6.060 1204.963 6 10.510 624-64-6 K4 t-Butene-2 0.075 0.093 0.103 20.396 7 10.638 463-82-1 I5 2,2-Dimethylpropane 0.015 0.019 0.016 4.020 8 11.251 590-18-1 K4 c-Butene-2 0.089 0.107 0.121 24.042 9 13.131 64-17-5 X2 Ethanol 22.944 21.648 38.018 2555.264 10 13.452 563-45-1 C5 3-Methylbutene-1 0.232 0.275 0.252 62.689

11 15.076 78-78-4 I5 i-Pentane 4.078 4.900 4.315 1072.411 12 16.727 109-67-1 K5 Pentene-1 0.340 0.395 0.370 91.909 13 17.580 563-46-2 C5 2-Methylbutene-1 0.516 0.591 0.562 139.634 14 18.113 109-66-0 P5 n-Pentane 1.445 1.718 1.529 379.903 15 18.625 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 2.953 16 19.230 646-04-8 K5 t-Pentene-2 0.862 0.991 0.939 233.275 17 19.879 ? Unidentified 0.006 0.007 0.006 1.958 18 20.266 627-20-3 K5 c-Pentene-2 0.473 0.537 0.515 127.890 19 20.943 513-35-9 C5 2-Methylbutene-2 1.059 1.190 1.153 286.406 20 21.271 2004-70-8 E5 1t,3-Pentadiene 0.016 0.017 0.018 4.394

21 22.536 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.008 1.968 22 23.092 75-83-2 I6 2,2-Dimethylbutane 0.113 0.130 0.100 29.814 23 25.743 142-29-0 B5 Cyclopentene 0.200 0.193 0.224 55.693 24 26.906 71-23-8 X3 n-Propanol 0.072 0.067 0.091 13.578 25 26.995 ? Unidentified 0.063 0.070 0.057 20.863 26 27.608 287-92-3 M5 Cyclopentane 0.175 0.175 0.190 47.269 27 28.339 79-29-8 I6 2,3-Dimethylbutane 0.972 1.094 0.861 256.713 28 28.734 ? Unidentified 0.054 0.054 0.047 17.816 29 29.192 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.051 0.042 12.573 30 29.421 107-83-5 I6 2-Methylpentane 3.123 3.560 2.766 824.449

31 29.842 674-76-0 C6 4-Methyl-t-pentene-2 0.133 0.147 0.120 35.928 32 32.069 96-14-0 I6 3-Methylpentane 1.904 2.134 1.687 502.653 33 33.228 763-29-1 C6 2-Methylpentene-1 0.227 0.247 0.206 61.460 34 33.451 592-41-6 K6 Hexene-1 0.162 0.178 0.147 43.792 35 35.640 760-21-4 C6 2-Ethylbutene-1 0.069 0.074 0.063 18.732 36 35.803 110-54-3 P6 n-Hexane 0.910 1.027 0.806 240.197 37 36.440 13269-52-8 K6 t-Hexene-3 0.266 0.291 0.242 72.033 38 36.917 4050-45-7 K6 t-Hexene-2 0.409 0.446 0.371 110.534 39 37.040 1120-62-3 B6 3-Methylcyclopentene 0.101 0.099 0.094 27.386 40 37.407 625-27-4 C6 2-Methylpentene-2 0.345 0.371 0.313 93.283

41 37.820 922-62-3 C6 3-Methyl-c-pentene-2 0.267 0.284 0.242 72.114 42 38.745 7688-21-3 K6 c-Hexene-2 0.216 0.233 0.196 58.516 43 40.088 3404-73-7 C7 3,3-Dimethylpentene-1 0.313 0.332 0.244 84.790

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.670 96-37-7 M6 Methylcyclopentane 1.090 1.084 0.988 294.735 45 42.232 108-08-7 I7 2,4-Dimethylpentane 0.601 0.665 0.457 159.170 46 42.534 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.014 0.011 3.697 47 42.781 464-06-2 I7 2,2,3-Trimethylbutane 0.040 0.043 0.030 10.557 48 45.426 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 4.127 49 45.640 71-42-3 Q6 Benzene 0.772 0.654 0.755 224.957 50 45.831 693-89-0 B6 1-Methylcyclopentene 0.363 0.347 0.338 100.596 51 46.640 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.012 4.332 52 47.229 3524-73-0 C7 5-Methylhexene-1 0.042 0.045 0.033 11.398 53 47.552 110-82-7 M6 Cyclohexane 0.517 0.494 0.469 139.804

54 48.062 71-36-3 X4 n-Butanol 0.056 0.052 0.058 11.447 55 49.273 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.032 11.021 56 49.621 3769-23-1 C7 4-Methylhexene-1 0.012 0.012 0.009 3.163 57 50.266 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.054 0.040 13.783 58 50.668 591-76-4 I7 2-Methylhexane 1.029 1.129 0.784 272.854 59 50.839 ? Unidentified 0.043 0.046 0.034 14.280 60 51.153 110-83-8 B6 Cyclohexene 0.045 0.041 0.042 12.089 61 52.493 589-34-4 I7 3-Methylhexane 0.510 0.553 0.389 135.220 62 53.353 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.157 0.156 0.122 42.341 63 53.940 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.120 0.120 0.094 32.543

64 54.564 822-50-4 M7 1t,2-Dimethylcyclopentane 0.165 0.163 0.128 44.508 65 54.862 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.018 6.144 66 55.178 540-84-1 I8 2,2,4-Trimethylpentane 4.298 4.625 2.872 1141.598 67 55.472 592-76-7 K7 Heptene-1 0.030 0.032 0.023 7.979 68 56.802 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.774 69 57.333 14686-14-7 K7 t-Heptene-3 0.032 0.034 0.025 8.645 70 57.684 6094-02-6 C7 2-Methylhexene-1 0.058 0.061 0.045 15.564 71 58.058 142-82-5 P7 n-Heptane 0.583 0.635 0.444 154.512 72 58.275 7642-10-6 K7 c-Heptene-3 0.025 0.026 0.019 6.714 73 58.548 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.020 7.127

74 58.793 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.021 0.016 5.430 75 59.174 14686-13-6 K7 t-Heptene-2 0.012 0.013 0.010 3.370 76 59.651 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.014 4.977 77 60.077 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.015 0.012 4.029 78 60.861 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.566 79 61.519 108-87-2 M7 Methylcyclohexane 0.929 0.899 0.722 251.207 80 62.460 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.028 0.027 0.019 7.456 81 62.848 590-73-8 I8 2,2-Dimethylhexane 0.026 0.027 0.017 6.784 82 63.362 ? Unidentified 0.054 0.055 0.037 17.764 83 64.297 1640-89-7 M7 Ethylcyclopentane 0.051 0.049 0.039 13.665

84 64.948 564-02-3 I8 2,2,3-Trimethylpentane 0.210 0.218 0.140 55.721 85 65.174 592-13-2 I8 2,5-Dimethylhexane 0.521 0.559 0.348 138.296 86 65.511 589-43-5 I8 2,4-Dimethylhexane 0.515 0.548 0.344 136.793

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.347 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.028 0.028 0.019 7.682 88 66.741 563-16-6 I8 3,3-Dimethylhexane 0.019 0.020 0.013 5.176 89 67.861 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.025 0.024 0.017 6.762 90 68.482 565-75-3 I8 2,3,4-Trimethylpentane 1.575 1.631 1.052 418.284 91 69.022 108-88-3 Q7 Toluene 5.223 4.484 4.327 1504.641 92 69.155 560-21-4 I8 2,3,3-Trimethylpentane 1.461 1.497 0.976 387.960 93 70.515 C8 C8 - Diolefin - 1 0.011 0.011 0.008 3.012 94 70.794 584-94-1 I8 2,3-Dimethylhexane 0.448 0.468 0.299 119.005 95 72.048 592-27-8 I8 2-Methylheptane 0.231 0.247 0.155 61.459 96 72.305 589-53-7 I8 4-Methylheptane 0.118 0.125 0.079 31.458

97 72.450 ? Unidentified 0.034 0.035 0.023 11.233 98 73.225 M8 1,3-dimethyl-t-cyclohexane 0.174 0.168 0.118 47.086 99 73.361 589-81-1 I8 3-Methylheptane 0.199 0.210 0.133 52.857 100 73.563 619-99-8 I8 3-Ethylhexane 0.108 0.113 0.072 28.780 101 74.459 ? Unidentified 0.028 0.027 0.019 9.378 102 75.250 3522-94-9 I9 2,2,5-Trimethylhexane 0.614 0.647 0.366 163.444 103 75.610 M8 3c-Ethylmethylcyclopentane 0.010 0.010 0.007 2.811 104 75.826 M8 3t-Ethylmethylcyclopentane 0.015 0.014 0.010 4.004 105 76.531 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.081 0.077 0.055 21.835 106 77.871 111-65-9 P8 n-Octane 0.536 0.568 0.358 142.302

107 78.825 ? Unidentified 0.015 0.014 0.010 4.921 108 80.353 1069-53-0 I9 2,3,5-Trimethylhexane 0.091 0.094 0.054 24.323 109 80.907 C8 C9 - IsoOlefin - 1 0.019 0.018 0.013 5.122 110 81.367 2207-01-4 M8 1c,2-Dimethylcyclohexane 0.016 0.015 0.011 4.345 111 81.521 1071-26-7 I9 2,4-Dimethylheptane 0.042 0.044 0.025 11.173 112 82.175 1678-91-7 M8 Ethylcyclohexane 0.135 0.128 0.092 36.557 113 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.071 0.074 0.042 18.848 114 82.976 ? Unidentified 0.029 0.028 0.020 9.515 115 83.405 I9 2,5-Dimethylheptane 0.109 0.113 0.065 28.886 116 83.599 926-82-9 I9 3,5-Dimethylheptane 0.021 0.022 0.013 5.632

117 84.731 100-41-4 Q8 Ethylbenzene 1.023 0.879 0.736 292.627 118 85.151 ? Unidentified 0.035 0.033 0.021 11.579 119 85.955 108-38-3 Q8 m-Xylene 2.607 2.245 1.874 745.305 120 86.102 106-42-3 Q8 p-Xylene 1.167 1.009 0.839 333.671 121 86.231 ? Unidentified 0.035 0.036 0.021 11.662 122 86.597 ? Unidentified 0.013 0.012 0.008 4.302 123 86.754 I9 3,5-Dimethylheptane 0.012 0.012 0.007 3.080 124 86.881 1067-20-5 I9 3,3-Diethylpentane 0.010 0.010 0.006 2.658 125 87.274 2216-34-4 I9 4-Methyloctane 0.062 0.064 0.037 16.590 126 87.406 3221-61-2 I9 2-Methyloctane 0.083 0.086 0.049 21.964

127 88.107 15869-80-4 I9 Heptane, 3-ethyl- 0.011 0.012 0.007 3.059 128 88.269 2216-33-3 I9 3-Methyloctane 0.080 0.083 0.048 21.320 129 88.745 ? Unidentified 0.020 0.022 0.012 6.576

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 88.929 95-47-6 Q8 o-Xylene 0.882 0.746 0.634 252.297 131 89.321 I10 C10 - IsoParaffin - 1 0.079 0.081 0.043 21.135 132 89.910 M9 trans-1,3-Diethylcyclopentane 0.020 0.017 0.012 5.700 133 90.168 14720-74-2 I10 2,2,4-trimethylheptane 0.076 0.077 0.041 20.149 134 91.741 111-84-2 P9 n-Nonane 0.228 0.237 0.136 60.760 135 92.337 4926-90-3 M9 1,1-Methylethylcyclohexane 0.022 0.020 0.013 5.903 136 93.094 98-82-8 Q9 i-Propylbenzene 0.032 0.028 0.020 9.119 137 93.272 ? Unidentified 0.009 0.008 0.005 2.922 138 93.272 ? Unidentified 0.009 0.009 0.005 2.922 139 93.272 ? Unidentified 0.009 0.007 0.005 2.922

140 93.383 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.004 0.003 0.002 0.964 141 93.383 C10 C10-IsoOlefin-4 0.004 0.004 0.002 0.964 142 93.383 I10 C10-isoparaffin-x 0.000 0.000 0.000 0.964 143 93.842 ? Unidentified 0.145 0.149 0.078 47.973 144 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.054 0.055 0.029 14.377 145 94.526 ? Unidentified 0.018 0.013 1.379 5.984 146 94.526 ? Unidentified 0.018 0.019 0.010 5.984 147 94.723 ? Unidentified 0.012 0.011 0.007 3.928 148 94.861 15869-89-3 I10 2,5-Dimethyloctane 0.074 0.075 0.040 19.743 149 95.325 2040-95-1 I10 2,7-Dimethyloctane 0.047 0.048 0.025 12.470

150 95.508 2051-30-1 I10 2,4-Dimethyloctane 0.220 0.225 0.118 58.706 151 95.894 I10 2,6-Dimethyloctane 0.068 0.070 0.037 18.212 152 96.058 I10 C10 Isoparaffin -1 0.006 0.006 0.003 1.626 153 96.555 103-65-1 Q9 n-Propylbenzene 0.291 0.251 0.185 82.590 154 96.753 I10 3-Methyl-5-ethylheptane 0.007 0.007 0.004 1.939 155 97.400 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.011 0.871 0.642 287.357 156 97.634 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.459 0.397 0.292 130.475 157 98.259 108-67-8 Q9 1,3,5-Trimethylbenzene 0.654 0.562 0.415 185.717 158 98.721 15869-85-9 I10 5-Methylnonane 0.009 0.009 0.005 2.455 159 98.913 17301-94-8 I10 4-Methylnonane 0.020 0.020 0.011 5.312

160 99.135 I10 2,2,6-Trimethyloctane 3.428 3.513 1.839 914.097 161 99.345 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.339 0.287 0.215 96.348 162 99.707 ? Unidentified 0.011 0.011 0.006 3.555 163 99.888 5911-04-6 I10 3-Methylnonane 0.020 0.021 0.011 5.423 164 100.073 ? Unidentified 0.011 0.012 0.006 3.778 165 100.354 ? Unidentified 0.201 0.150 0.098 66.600 166 100.487 ? Unidentified 0.542 0.542 0.265 179.602 167 100.702 I11 C11-Isoparaffin-2 0.287 0.287 0.140 76.574 168 100.978 95-63-6 Q9 1,2,4-Trimethylbenzene 1.723 1.465 1.094 489.529 169 101.168 ? Unidentified 0.328 0.348 0.179 108.674

170 101.290 ? Unidentified 0.194 0.197 0.104 64.374 171 101.552 1678-98-4 M10 i-Butylcyclohexane 0.051 0.048 0.028 13.834 172 102.194 ? Unidentified 0.020 0.019 0.011 6.790

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 102.339 17302-01-1 I10 3-Ethyl-3-methylheptane 0.461 0.461 0.225 123.016 174 102.545 ? Unidentified 0.118 0.118 0.058 39.022 175 102.689 538-93-2 Q10 i-Butylbenzene 0.347 0.302 0.197 97.929 176 102.890 124-18-5 P10 n-Decane 0.039 0.040 0.021 10.415 177 103.199 K10 3-Decene 0.144 0.145 0.078 38.585 178 103.688 ? Unidentified 0.016 0.013 0.010 5.353 179 103.853 526-73-8 Q9 1,2,3-Trimethylbenzene 0.220 0.183 0.140 62.413 180 104.194 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.034 0.029 0.019 9.531 181 104.410 I11 C11 Isoparaffin-4 0.053 0.053 0.026 14.271 182 104.618 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.319 0.277 0.182 90.254

183 104.955 ? Unidentified 0.053 0.041 0.034 17.430 184 105.051 J9 Indan 0.099 0.076 0.064 28.493 185 105.264 I11 C11-Isoparaffin-5 0.023 0.023 0.011 6.189 186 105.649 J10 Indene 1.454 1.123 0.939 419.908 187 106.203 ? Unidentified 0.010 0.009 0.005 3.239 188 106.361 I11 C11-Isoparaffin-7 0.527 0.527 0.257 140.559 189 106.551 141-93-5 Q10 1,3-Diethylbenzene 0.026 0.022 0.015 7.353 190 106.845 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.510 1.306 0.859 426.818 191 107.104 ? Unidentified 0.330 0.285 0.188 109.282 192 107.385 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.097 0.082 0.055 27.534

193 107.619 ? Unidentified 0.086 0.073 0.049 28.581 194 108.083 ? Unidentified 0.112 0.112 0.055 37.220 195 108.236 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.042 0.035 0.024 11.738 196 108.358 ? Unidentified 0.119 0.119 0.059 39.323 197 108.437 ? Unidentified 0.109 0.109 0.053 36.190 198 108.567 ? Unidentified 0.712 0.712 0.348 235.829 199 108.746 ? Unidentified 0.277 0.277 0.135 91.656 200 109.170 ? Unidentified 0.809 0.686 0.460 267.972 201 109.396 J10 2-Methylindan 0.129 0.099 0.074 37.142 202 109.742 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.308 0.262 0.175 86.893

203 109.875 ? Unidentified 0.038 0.032 0.021 12.507 204 110.287 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.677 0.566 0.385 191.360 205 110.711 ? Unidentified 0.024 0.021 0.012 7.789 206 110.906 693-61-8 K11 2-Undecene, (E)- 0.057 0.057 0.031 15.290 207 111.039 ? Unidentified 0.130 0.130 0.071 42.983 208 111.310 ? Unidentified 0.115 0.096 0.059 38.040 209 111.410 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.068 0.057 0.039 19.159 210 111.711 1120-21-4 P11 n-Undecane 0.080 0.080 0.039 21.346 211 111.862 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.093 0.078 0.048 26.102 212 111.974 ? Unidentified 0.062 0.052 0.032 20.511

213 112.350 Q10 1,2,4,5-Tetramethylbenzene 0.230 0.193 0.131 64.991 214 112.614 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.306 0.256 0.174 86.457 215 112.824 ? Unidentified 0.013 0.011 0.007 4.221

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 112.956 ? Unidentified 0.016 0.014 0.009 5.448 217 113.131 I12 C12 - IsoParaffin - 1 0.024 0.024 0.011 6.451 218 113.478 ? Unidentified 0.030 0.030 0.013 9.950 219 113.612 ? Unidentified 0.011 0.011 0.005 3.506 220 113.807 Q11 C11 - Aromatic - 3 0.068 0.057 0.035 19.167 221 113.945 874-35-1 H10 5-Methylindan 0.092 0.077 0.053 25.988 222 114.070 Q12 1,2-Di-i-propylbenzene 0.040 0.033 0.019 11.173 223 114.285 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.055 0.046 0.028 15.382 224 114.453 Q11 C11 - Aromatic - 4 0.035 0.029 0.018 9.711 225 114.695 824-22-6 J10 4-Methylindan 0.119 0.100 0.069 33.675

226 114.848 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.034 0.029 0.018 9.688 227 114.942 824-63-5 H10 2-Methylindan 0.091 0.076 0.053 25.695 228 115.145 ? Unidentified 0.012 0.010 0.006 3.878 229 115.259 538-68-1 Q11 n-Pentylbenzene 0.014 0.011 0.007 3.821 230 115.487 Q11 tert-Pentylbenzene 0.054 0.045 0.028 15.200 231 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.023 0.019 0.012 6.497 232 115.909 Q11 C11 - Aromatic - 7 0.037 0.033 0.019 10.467 233 116.250 I12 C12 - IsoParaffin - 4 0.005 0.005 0.002 1.358 234 116.368 100-18-5 Q12 1,4-Di-i-propylbenzene 0.044 0.037 0.021 12.304 235 116.810 91-20-3 G10 Naphthalene 0.076 0.055 0.045 22.500

236 116.944 ? Unidentified 0.010 0.010 0.005 3.372 237 117.241 J11 1,1-Dimethyl Indane 0.019 0.015 0.010 5.459 238 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.009 0.007 0.004 2.392 239 117.893 Q12 1,3-Di-n-propylbenzene 0.033 0.027 0.015 9.141 240 118.005 Q11 C11 - Aromatic - 11 0.018 0.016 0.009 5.002 241 118.558 Q11 C11 - Aromatic - 12 0.012 0.010 0.006 3.343 242 123.441 91-57-6 G11 2-Methylnaphthalene 0.011 0.008 0.006 3.218 243 124.306 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.499 244 126.297 ? Unidentified 0.004 0.004 0.002 1.445 245 126.297 ? Unidentified 0.004 0.004 0.002 1.445

246 126.297 ? Unidentified 0.004 0.004 0.002 1.445 247 130.003 ? Unidentified 0.003 0.002 0.002 1.030

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.007 0.010 0.011 1.701

10.024 106-97-8 n-Butane 4.614 5.935 6.060 1204.963 18.113 109-66-0 n-Pentane 1.445 1.718 1.529 379.903 35.803 110-54-3 n-Hexane 0.910 1.027 0.806 240.197 58.058 142-82-5 n-Heptane 0.583 0.635 0.444 154.512 77.871 111-65-9 n-Octane 0.536 0.568 0.358 142.302 91.741 111-84-2 n-Nonane 0.228 0.237 0.136 60.760 102.890 124-18-5 n-Decane 0.039 0.040 0.021 10.415 111.711 1120-21-4 n-Undecane 0.080 0.080 0.039 21.346

I-Paraffins 8.810 75-28-5 i-Butane 0.066 0.088 0.086 17.158

10.638 463-82-1 2,2-Dimethylpropane 0.015 0.019 0.016 4.020 15.076 78-78-4 i-Pentane 4.078 4.900 4.315 1072.411 23.092 75-83-2 2,2-Dimethylbutane 0.113 0.130 0.100 29.814 28.339 79-29-8 2,3-Dimethylbutane 0.972 1.094 0.861 256.713 29.421 107-83-5 2-Methylpentane 3.123 3.560 2.766 824.449 32.069 96-14-0 3-Methylpentane 1.904 2.134 1.687 502.653 42.232 108-08-7 2,4-Dimethylpentane 0.601 0.665 0.457 159.170 42.781 464-06-2 2,2,3-Trimethylbutane 0.040 0.043 0.030 10.557 50.668 591-76-4 2-Methylhexane 1.029 1.129 0.784 272.854 52.493 589-34-4 3-Methylhexane 0.510 0.553 0.389 135.220 55.178 540-84-1 2,2,4-Trimethylpentane 4.298 4.625 2.872 1141.598 62.848 590-73-8 2,2-Dimethylhexane 0.026 0.027 0.017 6.784 64.948 564-02-3 2,2,3-Trimethylpentane 0.210 0.218 0.140 55.721 65.174 592-13-2 2,5-Dimethylhexane 0.521 0.559 0.348 138.296 65.511 589-43-5 2,4-Dimethylhexane 0.515 0.548 0.344 136.793 66.741 563-16-6 3,3-Dimethylhexane 0.019 0.020 0.013 5.176 68.482 565-75-3 2,3,4-Trimethylpentane 1.575 1.631 1.052 418.284 69.155 560-21-4 2,3,3-Trimethylpentane 1.461 1.497 0.976 387.960 70.794 584-94-1 2,3-Dimethylhexane 0.448 0.468 0.299 119.005 72.048 592-27-8 2-Methylheptane 0.231 0.247 0.155 61.459 72.305 589-53-7 4-Methylheptane 0.118 0.125 0.079 31.458 73.361 589-81-1 3-Methylheptane 0.199 0.210 0.133 52.857 73.563 619-99-8 3-Ethylhexane 0.108 0.113 0.072 28.780 75.250 3522-94-9 2,2,5-Trimethylhexane 0.614 0.647 0.366 163.444 80.353 1069-53-0 2,3,5-Trimethylhexane 0.091 0.094 0.054 24.323 81.521 1071-26-7 2,4-Dimethylheptane 0.042 0.044 0.025 11.173 82.476 1072-05-5 2,6-Dimethylheptane 0.071 0.074 0.042 18.848 83.405 2,5-Dimethylheptane 0.109 0.113 0.065 28.886 83.599 926-82-9 3,5-Dimethylheptane 0.021 0.022 0.013 5.632 86.754 3,5-Dimethylheptane 0.012 0.012 0.007 3.080 86.881 1067-20-5 3,3-Diethylpentane 0.010 0.010 0.006 2.658 87.274 2216-34-4 4-Methyloctane 0.062 0.064 0.037 16.590 87.406 3221-61-2 2-Methyloctane 0.083 0.086 0.049 21.964 88.107 15869-80-4 Heptane, 3-ethyl- 0.011 0.012 0.007 3.059 88.269 2216-33-3 3-Methyloctane 0.080 0.083 0.048 21.320 89.321 C10 - IsoParaffin - 1 0.079 0.081 0.043 21.135

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 90.168 14720-74-2 2,2,4-trimethylheptane 0.076 0.077 0.041 20.149

93.383 C10-isoparaffin-x 0.000 0.000 0.000 0.964 94.064 15869-87-1 2,2-Dimethyloctane 0.054 0.055 0.029 14.377 94.861 15869-89-3 2,5-Dimethyloctane 0.074 0.075 0.040 19.743 95.325 2040-95-1 2,7-Dimethyloctane 0.047 0.048 0.025 12.470 95.508 2051-30-1 2,4-Dimethyloctane 0.220 0.225 0.118 58.706 95.894 2,6-Dimethyloctane 0.068 0.070 0.037 18.212 96.058 C10 Isoparaffin -1 0.006 0.006 0.003 1.626 96.753 3-Methyl-5-ethylheptane 0.007 0.007 0.004 1.939 98.721 15869-85-9 5-Methylnonane 0.009 0.009 0.005 2.455 98.913 17301-94-8 4-Methylnonane 0.020 0.020 0.011 5.312 99.135 2,2,6-Trimethyloctane 3.428 3.513 1.839 914.097 99.888 5911-04-6 3-Methylnonane 0.020 0.021 0.011 5.423 100.702 C11-Isoparaffin-2 0.287 0.287 0.140 76.574 102.339 17302-01-1 3-Ethyl-3-methylheptane 0.461 0.461 0.225 123.016 104.410 C11 Isoparaffin-4 0.053 0.053 0.026 14.271 105.264 C11-Isoparaffin-5 0.023 0.023 0.011 6.189 106.361 C11-Isoparaffin-7 0.527 0.527 0.257 140.559 113.131 C12 - IsoParaffin - 1 0.024 0.024 0.011 6.451 116.250 C12 - IsoParaffin - 4 0.005 0.005 0.002 1.358

Aromatics Mono-Aromatics 45.640 71-42-3 Benzene 0.772 0.654 0.755 224.957

69.022 108-88-3 Toluene 5.223 4.484 4.327 1504.641 84.731 100-41-4 Ethylbenzene 1.023 0.879 0.736 292.627 85.955 108-38-3 m-Xylene 2.607 2.245 1.874 745.305 86.102 106-42-3 p-Xylene 1.167 1.009 0.839 333.671 88.929 95-47-6 o-Xylene 0.882 0.746 0.634 252.297 93.094 98-82-8 i-Propylbenzene 0.032 0.028 0.020 9.119 96.555 103-65-1 n-Propylbenzene 0.291 0.251 0.185 82.590 97.400 620-14-4 1-Methyl-3-ethylbenzene 1.011 0.871 0.642 287.357 97.634 622-96-8 1-Methyl-4-ethylbenzene 0.459 0.397 0.292 130.475 98.259 108-67-8 1,3,5-Trimethylbenzene 0.654 0.562 0.415 185.717 99.345 611-14-3 1-Methyl-2-ethylbenzene 0.339 0.287 0.215 96.348 100.978 95-63-6 1,2,4-Trimethylbenzene 1.723 1.465 1.094 489.529 102.689 538-93-2 i-Butylbenzene 0.347 0.302 0.197 97.929 103.853 526-73-8 1,2,3-Trimethylbenzene 0.220 0.183 0.140 62.413 104.194 535-77-3 1-Methyl-3-i-propylbenzene 0.034 0.029 0.019 9.531 104.618 99-87-6 1-Methyl-4-i-propylbenzene 0.319 0.277 0.182 90.254 106.551 141-93-5 1,3-Diethylbenzene 0.026 0.022 0.015 7.353 106.845 1074-43-7 1-Methyl-3-n-propylbenzene 1.510 1.306 0.859 426.818 107.385 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.097 0.082 0.055 27.534 108.236 1074-17-5 1-Methyl-2-n-propylbenzene 0.042 0.035 0.024 11.738 109.742 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.308 0.262 0.175 86.893 110.287 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.677 0.566 0.385 191.360 111.410 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.068 0.057 0.039 19.159 111.862 4218-48-8 1-Ethyl-4-i-propylbenzene 0.093 0.078 0.048 26.102

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 112.350 1,2,4,5-Tetramethylbenzene 0.230 0.193 0.131 64.991

112.614 527-53-7 1,2,3,5-Tetramethylbenzene 0.306 0.256 0.174 86.457 113.807 C11 - Aromatic - 3 0.068 0.057 0.035 19.167 114.070 1,2-Di-i-propylbenzene 0.040 0.033 0.019 11.173 114.285 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.055 0.046 0.028 15.382 114.453 C11 - Aromatic - 4 0.035 0.029 0.018 9.711 114.848 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.034 0.029 0.018 9.688 115.259 538-68-1 n-Pentylbenzene 0.014 0.011 0.007 3.821 115.487 tert-Pentylbenzene 0.054 0.045 0.028 15.200 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.023 0.019 0.012 6.497 115.909 C11 - Aromatic - 7 0.037 0.033 0.019 10.467 116.368 100-18-5 1,4-Di-i-propylbenzene 0.044 0.037 0.021 12.304 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.009 0.007 0.004 2.392 117.893 1,3-Di-n-propylbenzene 0.033 0.027 0.015 9.141 118.005 C11 - Aromatic - 11 0.018 0.016 0.009 5.002 118.558 C11 - Aromatic - 12 0.012 0.010 0.006 3.343

Naphthalenes 116.810 91-20-3 Naphthalene 0.076 0.055 0.045 22.500

123.441 91-57-6 2-Methylnaphthalene 0.011 0.008 0.006 3.218 124.306 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.499

Naphtheno/Olefino-Benzs

113.945 874-35-1 5-Methylindan 0.092 0.077 0.053 25.988 114.942 824-63-5 2-Methylindan 0.091 0.076 0.053 25.695

Indenes 105.051 Indan 0.099 0.076 0.064 28.493

105.649 Indene 1.454 1.123 0.939 419.908 109.396 2-Methylindan 0.129 0.099 0.074 37.142 114.695 824-22-6 4-Methylindan 0.119 0.100 0.069 33.675 117.241 1,1-Dimethyl Indane 0.019 0.015 0.010 5.459

Naphthenes Mono-Naphthenes 27.608 287-92-3 Cyclopentane 0.175 0.175 0.190 47.269

40.670 96-37-7 Methylcyclopentane 1.090 1.084 0.988 294.735 47.552 110-82-7 Cyclohexane 0.517 0.494 0.469 139.804 53.353 1759-58-6 1t,3-Dimethylcyclopentane 0.157 0.156 0.122 42.341 53.940 2532-58-3 1c,3-Dimethylcyclopentane 0.120 0.120 0.094 32.543 54.564 822-50-4 1t,2-Dimethylcyclopentane 0.165 0.163 0.128 44.508 59.651 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.014 4.977 61.519 108-87-2 Methylcyclohexane 0.929 0.899 0.722 251.207 62.460 4516-69-2 1,1,3-Trimethylcyclopentane 0.028 0.027 0.019 7.456 64.297 1640-89-7 Ethylcyclopentane 0.051 0.049 0.039 13.665 66.347 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.028 0.028 0.019 7.682 67.861 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.025 0.024 0.017 6.762 73.225 1,3-dimethyl-t-cyclohexane 0.174 0.168 0.118 47.086 75.610 3c-Ethylmethylcyclopentane 0.010 0.010 0.007 2.811 75.826 3t-Ethylmethylcyclopentane 0.015 0.014 0.010 4.004 76.531 2207-03-6 1t,3-Dimethylcyclohexane 0.081 0.077 0.055 21.835

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 81.367 2207-01-4 1c,2-Dimethylcyclohexane 0.016 0.015 0.011 4.345

82.175 1678-91-7 Ethylcyclohexane 0.135 0.128 0.092 36.557 89.910 trans-1,3-Diethylcyclopentane 0.020 0.017 0.012 5.700 92.337 4926-90-3 1,1-Methylethylcyclohexane 0.022 0.020 0.013 5.903 93.383 696-29-7 1-Methyl-2-propyl-cyclopentan 0.004 0.003 0.002 0.964 101.552 1678-98-4 i-Butylcyclohexane 0.051 0.048 0.028 13.834

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.623 115-11-7 Isobutene 0.017 0.021 0.023 4.515

9.665 106-98-9 Butene-1 0.019 0.023 0.025 5.019 10.510 624-64-6 t-Butene-2 0.075 0.093 0.103 20.396 11.251 590-18-1 c-Butene-2 0.089 0.107 0.121 24.042 16.727 109-67-1 Pentene-1 0.340 0.395 0.370 91.909 19.230 646-04-8 t-Pentene-2 0.862 0.991 0.939 233.275 20.266 627-20-3 c-Pentene-2 0.473 0.537 0.515 127.890 33.451 592-41-6 Hexene-1 0.162 0.178 0.147 43.792 36.440 13269-52-8 t-Hexene-3 0.266 0.291 0.242 72.033 36.917 4050-45-7 t-Hexene-2 0.409 0.446 0.371 110.534 38.745 7688-21-3 c-Hexene-2 0.216 0.233 0.196 58.516 55.472 592-76-7 Heptene-1 0.030 0.032 0.023 7.979 57.333 14686-14-7 t-Heptene-3 0.032 0.034 0.025 8.645 58.275 7642-10-6 c-Heptene-3 0.025 0.026 0.019 6.714 59.174 14686-13-6 t-Heptene-2 0.012 0.013 0.010 3.370 103.199 3-Decene 0.144 0.145 0.078 38.585 110.906 693-61-8 2-Undecene, (E)- 0.057 0.057 0.031 15.290

Iso-Olefins 13.452 563-45-1 3-Methylbutene-1 0.232 0.275 0.252 62.689

17.580 563-46-2 2-Methylbutene-1 0.516 0.591 0.562 139.634 20.943 513-35-9 2-Methylbutene-2 1.059 1.190 1.153 286.406 29.192 691-38-3 4-Methyl-c-pentene-2 0.046 0.051 0.042 12.573 29.842 674-76-0 4-Methyl-t-pentene-2 0.133 0.147 0.120 35.928 33.228 763-29-1 2-Methylpentene-1 0.227 0.247 0.206 61.460 35.640 760-21-4 2-Ethylbutene-1 0.069 0.074 0.063 18.732 37.407 625-27-4 2-Methylpentene-2 0.345 0.371 0.313 93.283 37.820 922-62-3 3-Methyl-c-pentene-2 0.267 0.284 0.242 72.114 40.088 3404-73-7 3,3-Dimethylpentene-1 0.313 0.332 0.244 84.790 42.534 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.014 0.011 3.697 46.640 3404-61-3 3-Methylhexene-1 0.016 0.017 0.012 4.332 47.229 3524-73-0 5-Methylhexene-1 0.042 0.045 0.033 11.398 49.273 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.032 11.021 49.621 3769-23-1 4-Methylhexene-1 0.012 0.012 0.009 3.163 50.266 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.054 0.040 13.783 54.862 C7 - Iso-Olefin - 2 0.023 0.024 0.018 6.144 56.802 4914-89-0 3-Methyl-c-hexene-3 0.014 0.014 0.011 3.774 57.684 6094-02-6 2-Methylhexene-1 0.058 0.061 0.045 15.564 58.548 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.020 7.127

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 58.793 10574-36-4 3-Methyl-c-hexene-2 0.020 0.021 0.016 5.430

60.077 20710-38-8 3-Methyl-t-hexene-2 0.015 0.015 0.012 4.029 60.861 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.566 70.515 C8 - Diolefin - 1 0.011 0.011 0.008 3.012 80.907 C9 - IsoOlefin - 1 0.019 0.018 0.013 5.122 93.383 C10-IsoOlefin-4 0.004 0.004 0.002 0.964

Naphtheno-Olefins 22.536 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.008 1.968

25.743 142-29-0 Cyclopentene 0.200 0.193 0.224 55.693 37.040 1120-62-3 3-Methylcyclopentene 0.101 0.099 0.094 27.386 45.831 693-89-0 1-Methylcyclopentene 0.363 0.347 0.338 100.596 51.153 110-83-8 Cyclohexene 0.045 0.041 0.042 12.089

Di-Olefins 18.625 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 2.953

21.271 2004-70-8 1t,3-Pentadiene 0.016 0.017 0.018 4.394 45.426 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 4.127

Oxygenates 13.131 64-17-5 Ethanol 22.944 21.648 38.018 2555.264

26.906 71-23-8 n-Propanol 0.072 0.067 0.091 13.578 48.062 71-36-3 n-Butanol 0.056 0.052 0.058 11.447

Unidentified 19.879 Unidentified 0.006 0.007 0.006 1.958

26.995 Unidentified 0.063 0.070 0.057 20.863 28.734 Unidentified 0.054 0.054 0.047 17.816 50.839 Unidentified 0.043 0.046 0.034 14.280 63.362 Unidentified 0.054 0.055 0.037 17.764 72.450 Unidentified 0.034 0.035 0.023 11.233 74.459 Unidentified 0.028 0.027 0.019 9.378 78.825 Unidentified 0.015 0.014 0.010 4.921 82.976 Unidentified 0.029 0.028 0.020 9.515 85.151 Unidentified 0.035 0.033 0.021 11.579 86.231 Unidentified 0.035 0.036 0.021 11.662 86.597 Unidentified 0.013 0.012 0.008 4.302 88.745 Unidentified 0.020 0.022 0.012 6.576 93.272 Unidentified 0.009 0.008 0.005 2.922 93.272 Unidentified 0.009 0.009 0.005 2.922 93.272 Unidentified 0.009 0.007 0.005 2.922 93.842 Unidentified 0.145 0.149 0.078 47.973 94.526 Unidentified 0.018 0.013 1.379 5.984 94.526 Unidentified 0.018 0.019 0.010 5.984 94.723 Unidentified 0.012 0.011 0.007 3.928 99.707 Unidentified 0.011 0.011 0.006 3.555 100.073 Unidentified 0.011 0.012 0.006 3.778 100.354 Unidentified 0.201 0.150 0.098 66.600 100.487 Unidentified 0.542 0.542 0.265 179.602 101.168 Unidentified 0.328 0.348 0.179 108.674 101.290 Unidentified 0.194 0.197 0.104 64.374

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 102.194 Unidentified 0.020 0.019 0.011 6.790

102.545 Unidentified 0.118 0.118 0.058 39.022 103.688 Unidentified 0.016 0.013 0.010 5.353 104.955 Unidentified 0.053 0.041 0.034 17.430 106.203 Unidentified 0.010 0.009 0.005 3.239 107.104 Unidentified 0.330 0.285 0.188 109.282 107.619 Unidentified 0.086 0.073 0.049 28.581 108.083 Unidentified 0.112 0.112 0.055 37.220 108.358 Unidentified 0.119 0.119 0.059 39.323 108.437 Unidentified 0.109 0.109 0.053 36.190 108.567 Unidentified 0.712 0.712 0.348 235.829 108.746 Unidentified 0.277 0.277 0.135 91.656 109.170 Unidentified 0.809 0.686 0.460 267.972 109.875 Unidentified 0.038 0.032 0.021 12.507 110.711 Unidentified 0.024 0.021 0.012 7.789 111.039 Unidentified 0.130 0.130 0.071 42.983 111.310 Unidentified 0.115 0.096 0.059 38.040 111.974 Unidentified 0.062 0.052 0.032 20.511 112.824 Unidentified 0.013 0.011 0.007 4.221 112.956 Unidentified 0.016 0.014 0.009 5.448 113.478 Unidentified 0.030 0.030 0.013 9.950 113.612 Unidentified 0.011 0.011 0.005 3.506 115.145 Unidentified 0.012 0.010 0.006 3.878 116.944 Unidentified 0.010 0.010 0.005 3.372 126.297 Unidentified 0.004 0.004 0.002 1.445 126.297 Unidentified 0.004 0.004 0.002 1.445 126.297 Unidentified 0.004 0.004 0.002 1.445 130.003 Unidentified 0.003 0.002 0.002 1.030

Plus

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1

n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

1t,2c,3-Trimethylcyclopentane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

C8 - Diolefin - 1 2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane 3t-Ethylmethylcyclopentane 1t,3-Dimethylcyclohexane

n-Octane

Unidentified

2,3,5-Trimethylhexane C9 - IsoOlefin - 1 1c,2-Dimethylcyclohexane 2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane 3,5-Dimethylheptane

Ethylbenzene Unidentified
m-Xylene

p-Xylene Unidentified Unidentified 3,5-Dimethylheptane 3,3-Diethylpentane 4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane Unidentified

o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane C10 Isoparaffin -1 n-Propylbenzene 3-Methyl-5-ethylheptane

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene Unidentified 3-Methylnonane

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane Unidentified i-Butylbenzene n-Decane 3-Decene Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Unidentified Indan C11-Isoparaffin-5 Indene Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene Unidentified 1,3-Dimethyl-5-ethylbenzene Unidentified Unidentified 1-Methyl-2-n-propylbenzene Unidentified

Unidentified Unidentified Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 11:02:54 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF Sample: ODDB-91328 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91328 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000010.D\SIG2000010_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 7.734 9.847 9.087

I-Paraffins 15.447 18.031 13.525

Aromatics 42.903 37.798 30.294 Mono-Aromatics 40.715 36.014 28.953 Naphthalenes 0.247 0.186 0.147 Naphtheno/Olefino-Benzs 0.452 0.391 0.263 Indenes 1.488 1.207 0.930

Naphthenes 2.071 2.109 1.891 Mono-Naphthenes 2.071 2.109 1.891 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.117 8.087 7.143 n-Olefins 2.978 3.467 3.071 Iso-Olefins 3.403 3.886 3.339 Naphtheno-Olefins 0.696 0.690 0.690 Di-Olefins 0.040 0.044 0.043

Oxygenates 21.900 21.350 36.487

Unidentified 2.828 2.779 1.573

Plus 0.000 0.000 0.000

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 21.767 21.222 36.330 C3 0.079 0.077 0.102 C4 5.147 6.809 6.803 C5 7.109 8.510 7.701 C6 16.997 19.240 15.334 C7 13.609 12.576 11.220 C8 11.480 10.212 8.311 C9 10.903 9.604 6.977 C10 7.580 6.595 4.398 C11 2.142 2.065 1.082 C12 0.358 0.312 0.170

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.001 0.001 0.001 C4 4.881 6.487 6.457 C5 0.812 0.997 0.865 C6 1.796 2.095 1.603 C7 0.126 0.142 0.097 C8 0.023 0.025 0.015 C9 0.013 0.014 0.008 C11 0.083 0.085 0.041

I-Paraffins C4 0.021 0.030 0.028 C5 2.497 3.100 2.661 C6 10.368 12.139 9.251 C7 1.132 1.280 0.869 C8 0.047 0.052 0.032 C10 0.258 0.269 0.133 C11 1.099 1.136 0.541 C12 0.025 0.026 0.011

Mono-Aromatics C6 0.762 0.667 0.750 C7 11.289 10.016 9.421 C8 11.410 10.136 8.264 C9 10.632 9.384 6.802 C10 5.464 4.802 3.130 C11 0.846 0.739 0.439 C12 0.312 0.270 0.148

Naphthalenes C10 0.233 0.175 0.140 C11 0.014 0.011 0.008

Naphtheno/Olefino-Benzs C10 0.452 0.391 0.263

Indenes C9 0.258 0.206 0.168 C10 1.162 0.947 0.726 C11 0.048 0.038 0.025 C12 0.020 0.016 0.011

Mono-Naphthenes C5 0.244 0.251 0.267 C6 1.503 1.527 1.373 C7 0.313 0.320 0.245 C10 0.011 0.011 0.006

n-Olefins C4 0.190 0.240 0.261

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.615 1.916 1.771 C6 1.023 1.151 0.935 C7 0.096 0.105 0.075 C11 0.053 0.055 0.029

Iso-Olefins C5 1.716 2.017 1.881 C6 1.049 1.171 0.958 C7 0.638 0.698 0.500

Naphtheno-Olefins C5 0.200 0.200 0.226 C6 0.496 0.490 0.464

Di-Olefins C5 0.026 0.029 0.029 C7 0.015 0.015 0.014

Oxygenates C2 21.767 21.222 36.330 C3 0.078 0.075 0.100 C4 0.055 0.052 0.057

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.61 21.35 5% 33.33 28.59 10% 97.17 81.80 15% 138.01 111.42 20% 140.53 138.65 25% 154.40 143.99 30% 172.29 154.33 35% 172.54 172.27 40% 172.79 172.53 45% 173.04 172.78 50% 173.28 173.03 55% 221.36 173.29 60% 226.27 221.51 65% 253.49 227.05 70% 281.21 270.68 75% 282.37 281.68 80% 323.14 321.06 85% 335.32 334.04 90% 358.22 352.22 95% 370.41 368.42 FBP 404.60 404.60

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.554 74-98-6 P3 Propane 0.001 0.001 0.001 0.187 2 8.810 75-28-5 I4 i-Butane 0.021 0.030 0.028 5.549 3 9.623 115-11-7 K4 Isobutene 0.016 0.020 0.022 4.228 4 9.664 106-98-9 K4 Butene-1 0.018 0.023 0.024 4.729 5 10.024 106-97-8 P4 n-Butane 4.881 6.487 6.457 1264.928 6 10.510 624-64-6 K4 t-Butene-2 0.072 0.092 0.099 19.355 7 10.637 463-82-1 I5 2,2-Dimethylpropane 0.006 0.008 0.007 1.616 8 11.250 590-18-1 K4 c-Butene-2 0.085 0.105 0.116 22.797 9 13.124 64-17-5 X2 Ethanol 21.767 21.222 36.330 2405.814 10 13.454 563-45-1 C5 3-Methylbutene-1 0.197 0.242 0.216 52.954

11 15.073 78-78-4 I5 i-Pentane 2.491 3.092 2.654 649.939 12 16.730 109-67-1 K5 Pentene-1 0.328 0.393 0.359 87.931 13 17.577 563-46-2 C5 2-Methylbutene-1 0.497 0.588 0.545 133.516 14 18.111 109-66-0 P5 n-Pentane 0.812 0.997 0.865 211.846 15 18.628 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.012 0.012 2.816 16 19.232 646-04-8 K5 t-Pentene-2 0.832 0.987 0.912 223.252 17 19.882 ? Unidentified 0.006 0.007 0.006 1.907 18 20.263 627-20-3 K5 c-Pentene-2 0.456 0.535 0.500 122.419 19 20.940 513-35-9 C5 2-Methylbutene-2 1.021 1.186 1.120 274.156 20 21.269 2004-70-8 E5 1t,3-Pentadiene 0.015 0.018 0.017 4.261

21 22.534 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.008 1.879 22 23.089 75-83-2 I6 2,2-Dimethylbutane 0.264 0.313 0.235 69.147 23 25.739 142-29-0 B5 Cyclopentene 0.194 0.193 0.219 53.497 24 26.906 71-23-8 X3 n-Propanol 0.078 0.075 0.100 14.745 25 26.991 ? Unidentified 0.056 0.064 0.051 18.364 26 27.604 287-92-3 M5 Cyclopentane 0.244 0.251 0.267 65.362 27 28.334 79-29-8 I6 2,3-Dimethylbutane 1.068 1.242 0.953 279.771 28 28.733 ? Unidentified 0.052 0.054 0.045 17.036 29 29.194 691-38-3 C6 4-Methyl-c-pentene-2 0.044 0.051 0.041 11.916 30 29.438 107-83-5 I6 2-Methylpentane 6.069 7.148 5.415 1589.994

31 29.843 674-76-0 C6 4-Methyl-t-pentene-2 0.128 0.147 0.117 34.450 32 32.074 96-14-0 I6 3-Methylpentane 2.968 3.437 2.648 777.561 33 33.233 763-29-1 C6 2-Methylpentene-1 0.220 0.247 0.201 59.096 34 33.450 592-41-6 K6 Hexene-1 0.157 0.178 0.144 42.227 35 35.642 760-21-4 C6 2-Ethylbutene-1 0.062 0.069 0.057 16.747 36 35.806 110-54-3 P6 n-Hexane 1.796 2.095 1.603 470.606 37 36.439 13269-52-8 K6 t-Hexene-3 0.258 0.291 0.236 69.365 38 36.916 4050-45-7 K6 t-Hexene-2 0.397 0.447 0.363 106.583 39 37.042 1120-62-3 B6 3-Methylcyclopentene 0.098 0.099 0.092 26.242 40 37.406 625-27-4 C6 2-Methylpentene-2 0.335 0.373 0.306 89.849

41 37.820 922-62-3 C6 3-Methyl-c-pentene-2 0.259 0.285 0.236 69.441 42 38.742 7688-21-3 K6 c-Hexene-2 0.210 0.234 0.192 56.392 43 40.086 3404-73-7 C7 3,3-Dimethylpentene-1 0.306 0.336 0.240 82.196

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.671 96-37-7 M6 Methylcyclopentane 1.055 1.085 0.964 283.306 45 42.239 108-08-7 I7 2,4-Dimethylpentane 0.209 0.239 0.160 54.905 46 42.532 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.014 0.010 3.544 47 42.778 464-06-2 I7 2,2,3-Trimethylbutane 0.019 0.021 0.015 4.979 48 45.429 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 3.975 49 45.637 71-42-3 Q6 Benzene 0.762 0.667 0.750 220.346 50 45.833 693-89-0 B6 1-Methylcyclopentene 0.354 0.349 0.331 97.257 51 46.637 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.012 4.167 52 47.230 3524-73-0 C7 5-Methylhexene-1 0.038 0.042 0.030 10.241 53 47.552 110-82-7 M6 Cyclohexane 0.448 0.442 0.409 120.162

54 48.062 71-36-3 X4 n-Butanol 0.055 0.052 0.057 11.090 55 49.272 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.044 0.031 10.677 56 49.619 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.008 2.867 57 50.266 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.055 0.039 13.442 58 50.661 591-76-4 I7 2-Methylhexane 0.552 0.626 0.423 145.154 59 50.840 ? Unidentified 0.024 0.027 0.019 7.980 60 51.152 110-83-8 B6 Cyclohexene 0.044 0.042 0.041 11.800 61 52.491 589-34-4 I7 3-Methylhexane 0.352 0.395 0.270 92.708 62 53.352 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.100 0.103 0.078 26.826 63 53.938 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.068 0.070 0.053 18.197

64 54.563 822-50-4 M7 1t,2-Dimethylcyclopentane 0.069 0.070 0.054 18.403 65 54.842 C7 C7 - Iso-Olefin - 2 0.022 0.023 0.017 5.868 66 55.468 592-76-7 K7 Heptene-1 0.027 0.030 0.021 7.291 67 56.801 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.011 3.660 68 57.332 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.025 8.413 69 57.683 6094-02-6 C7 2-Methylhexene-1 0.056 0.062 0.044 15.137 70 58.053 142-82-5 P7 n-Heptane 0.126 0.142 0.097 33.207 71 58.274 7642-10-6 K7 c-Heptene-3 0.025 0.027 0.019 6.665 72 58.548 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.020 6.845 73 58.793 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.209

74 59.174 14686-13-6 K7 t-Heptene-2 0.013 0.014 0.010 3.395 75 59.650 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.019 0.014 4.888 76 60.077 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.012 3.985 77 60.859 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.431 78 61.507 108-87-2 M7 Methylcyclohexane 0.058 0.058 0.046 15.648 79 63.361 ? Unidentified 0.057 0.061 0.040 18.873 80 69.069 108-88-3 Q7 Toluene 11.289 10.016 9.421 3227.774 81 72.046 592-27-8 I8 2-Methylheptane 0.019 0.020 0.012 4.877 82 72.299 589-53-7 I8 4-Methylheptane 0.010 0.011 0.007 2.552 83 73.361 589-81-1 I8 3-Methylheptane 0.019 0.021 0.013 5.011

84 77.869 111-65-9 P8 n-Octane 0.023 0.025 0.015 6.005 85 84.742 100-41-4 Q8 Ethylbenzene 2.126 1.886 1.540 603.262 86 85.983 108-38-3 Q8 m-Xylene 5.424 4.828 3.928 1539.029

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 86.124 106-42-3 Q8 p-Xylene 2.466 2.203 1.786 699.626 88 88.935 95-47-6 Q8 o-Xylene 1.395 1.219 1.010 395.859 89 91.739 111-84-2 P9 n-Nonane 0.013 0.014 0.008 3.421 90 93.095 98-82-8 Q9 i-Propylbenzene 0.035 0.031 0.023 9.924 91 93.842 ? Unidentified 0.015 0.015 0.008 4.781 92 94.860 15869-89-3 I10 2,5-Dimethyloctane 0.009 0.010 0.005 2.416 93 95.508 2051-30-1 I10 2,4-Dimethyloctane 0.032 0.034 0.017 8.411 94 95.898 I10 2,6-Dimethyloctane 0.010 0.010 0.005 2.548 95 96.557 103-65-1 Q9 n-Propylbenzene 0.546 0.487 0.349 153.898 96 97.412 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.190 1.948 1.401 617.332

97 97.643 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.026 0.916 0.656 289.162 98 98.268 108-67-8 Q9 1,3,5-Trimethylbenzene 1.319 1.173 0.844 371.949 99 98.724 15869-85-9 I10 5-Methylnonane 0.009 0.010 0.005 2.453 100 98.913 17301-94-8 I10 4-Methylnonane 0.022 0.023 0.012 5.861 101 99.119 ? Unidentified 0.568 0.601 0.307 186.648 102 99.349 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.795 0.694 0.509 224.157 103 99.568 5881-17-4 I10 3-Ethyloctane 0.004 0.005 0.002 1.185 104 99.889 5911-04-6 I10 3-Methylnonane 0.031 0.033 0.017 8.312 105 100.353 ? Unidentified 0.045 0.034 0.022 14.684 106 100.487 ? Unidentified 0.128 0.132 0.063 42.031

107 100.701 I11 C11-Isoparaffin-2 0.068 0.070 0.033 18.003 108 100.998 95-63-6 Q9 1,2,4-Trimethylbenzene 4.010 3.522 2.565 1130.624 109 101.165 ? Unidentified 0.085 0.094 0.047 28.053 110 101.287 ? Unidentified 0.050 0.052 0.027 16.373 111 101.551 1678-98-4 M10 i-Butylcyclohexane 0.011 0.011 0.006 3.000 112 102.338 17302-01-1 I10 3-Ethyl-3-methylheptane 0.140 0.145 0.069 37.096 113 102.636 538-93-2 Q10 i-Butylbenzene 0.210 0.189 0.120 58.832 114 102.901 ? Unidentified 0.048 0.043 0.028 15.814 115 103.200 ? Unidentified 0.035 0.036 0.017 11.499 116 103.855 526-73-8 Q9 1,2,3-Trimethylbenzene 0.711 0.612 0.455 200.480

117 104.234 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.024 0.022 0.014 6.805 118 104.411 I11 C11 Isoparaffin-4 0.019 0.020 0.010 5.146 119 104.617 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.134 0.121 0.077 37.701 120 105.046 J9 Indan 0.258 0.206 0.168 74.055 121 105.643 J10 Indene 0.733 0.585 0.477 210.012 122 106.358 I11 C11-Isoparaffin-7 0.318 0.329 0.156 84.204 123 106.549 141-93-5 Q10 1,3-Diethylbenzene 0.097 0.086 0.055 27.102 124 106.834 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.138 1.017 0.652 319.151 125 107.167 105-05-5 Q10 1,4-Diethylbenzene 0.420 0.375 0.240 117.726 126 107.385 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.301 0.264 0.173 84.543

127 107.626 135-01-3 Q10 1,2-Diethylbenzene 0.079 0.069 0.045 22.122 128 108.083 ? Unidentified 0.080 0.082 0.039 26.142 129 108.235 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.103 0.091 0.059 28.968

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 108.358 ? Unidentified 0.091 0.094 0.045 29.838 131 108.437 ? Unidentified 0.083 0.086 0.041 27.434 132 108.566 I11 C11- Isoparaffin-11 0.694 0.717 0.341 183.768 133 108.746 ? Unidentified 0.224 0.232 0.110 73.628 134 109.084 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.209 0.183 0.120 58.511 135 109.170 ? Unidentified 0.812 0.712 0.465 266.890 136 109.397 J10 2-Methylindan 0.127 0.102 0.074 36.451 137 109.745 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.691 0.608 0.396 193.699 138 110.287 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.627 0.541 0.359 175.760 139 110.711 ? Unidentified 0.022 0.020 0.011 7.130

140 110.906 693-61-8 K11 2-Undecene, (E)- 0.053 0.055 0.029 14.139 141 111.040 ? Unidentified 0.101 0.105 0.055 33.160 142 111.192 Q11 1-Methyl-4-t-butylbenzene 0.041 0.037 0.021 11.322 143 111.314 ? Unidentified 0.100 0.087 0.052 32.932 144 111.415 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.163 0.140 0.093 45.632 145 111.712 1120-21-4 P11 n-Undecane 0.083 0.085 0.041 21.905 146 111.864 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.090 0.078 0.047 25.236 147 111.975 ? Unidentified 0.057 0.050 0.030 18.882 148 112.352 Q10 1,2,4,5-Tetramethylbenzene 0.538 0.467 0.308 150.976 149 112.618 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.730 0.631 0.418 204.853

150 112.821 ? Unidentified 0.012 0.010 0.006 3.858 151 112.958 ? Unidentified 0.015 0.013 0.009 4.849 152 113.132 I12 C12 - IsoParaffin - 1 0.020 0.020 0.009 5.230 153 113.482 ? Unidentified 0.035 0.037 0.017 11.625 154 113.613 ? Unidentified 0.007 0.007 0.003 2.309 155 113.757 Q11 C11 - Aromatic - 3 0.096 0.083 0.050 26.882 156 113.947 874-35-1 H10 5-Methylindan 0.229 0.198 0.133 64.313 157 114.072 Q12 1,2-Di-i-propylbenzene 0.083 0.072 0.039 23.143 158 114.286 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.119 0.103 0.062 33.241 159 114.443 Q11 C11 - Aromatic - 4 0.068 0.059 0.035 18.949

160 114.696 824-22-6 J10 4-Methylindan 0.302 0.261 0.175 84.586 161 114.847 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.071 0.061 0.037 19.699 162 114.944 824-63-5 H10 2-Methylindan 0.223 0.192 0.130 62.446 163 115.146 ? Unidentified 0.022 0.023 0.010 7.192 164 115.259 538-68-1 Q11 n-Pentylbenzene 0.028 0.024 0.015 7.833 165 115.486 Q11 tert-Pentylbenzene 0.123 0.107 0.064 34.466 166 115.799 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.055 0.048 0.029 15.369 167 115.908 Q11 C11 - Aromatic - 7 0.070 0.064 0.037 19.675 168 116.238 I12 C12 - IsoParaffin - 4 0.005 0.006 0.002 1.513 169 116.369 100-18-5 Q12 1,4-Di-i-propylbenzene 0.109 0.094 0.052 30.323

170 116.813 91-20-3 G10 Naphthalene 0.233 0.175 0.140 68.466 171 117.007 J11 4,7-Dimethyl Indane 0.011 0.009 0.006 3.158 172 117.252 J11 1,1-Dimethyl Indane 0.037 0.029 0.019 10.480

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 117.414 J12 Dimethyl Indane - 1 0.015 0.012 0.008 4.273 174 117.593 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.017 0.015 0.008 4.694 175 117.733 J12 Dimethyl Indane - 2 0.005 0.004 0.003 1.536 176 117.895 Q12 1,3-Di-n-propylbenzene 0.090 0.078 0.043 25.039 177 118.005 Q11 C11 - Aromatic - 11 0.051 0.046 0.026 14.158 178 118.559 Q11 C11 - Aromatic - 12 0.034 0.030 0.017 9.389 179 119.487 102-25-0 Q12 1,3,5-Triethylbenzene 0.009 0.008 0.004 2.415 180 120.147 Q12 C12 - Aromatic - 1 0.005 0.004 0.002 1.299 181 123.439 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.005 2.635 182 124.306 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.476

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.001 0.001 0.001 0.187

10.024 106-97-8 n-Butane 4.881 6.487 6.457 1264.928 18.111 109-66-0 n-Pentane 0.812 0.997 0.865 211.846 35.806 110-54-3 n-Hexane 1.796 2.095 1.603 470.606 58.053 142-82-5 n-Heptane 0.126 0.142 0.097 33.207 77.869 111-65-9 n-Octane 0.023 0.025 0.015 6.005 91.739 111-84-2 n-Nonane 0.013 0.014 0.008 3.421 111.712 1120-21-4 n-Undecane 0.083 0.085 0.041 21.905

I-Paraffins 8.810 75-28-5 i-Butane 0.021 0.030 0.028 5.549

10.637 463-82-1 2,2-Dimethylpropane 0.006 0.008 0.007 1.616 15.073 78-78-4 i-Pentane 2.491 3.092 2.654 649.939 23.089 75-83-2 2,2-Dimethylbutane 0.264 0.313 0.235 69.147 28.334 79-29-8 2,3-Dimethylbutane 1.068 1.242 0.953 279.771 29.438 107-83-5 2-Methylpentane 6.069 7.148 5.415 1589.994 32.074 96-14-0 3-Methylpentane 2.968 3.437 2.648 777.561 42.239 108-08-7 2,4-Dimethylpentane 0.209 0.239 0.160 54.905 42.778 464-06-2 2,2,3-Trimethylbutane 0.019 0.021 0.015 4.979 50.661 591-76-4 2-Methylhexane 0.552 0.626 0.423 145.154 52.491 589-34-4 3-Methylhexane 0.352 0.395 0.270 92.708 72.046 592-27-8 2-Methylheptane 0.019 0.020 0.012 4.877 72.299 589-53-7 4-Methylheptane 0.010 0.011 0.007 2.552 73.361 589-81-1 3-Methylheptane 0.019 0.021 0.013 5.011 94.860 15869-89-3 2,5-Dimethyloctane 0.009 0.010 0.005 2.416 95.508 2051-30-1 2,4-Dimethyloctane 0.032 0.034 0.017 8.411 95.898 2,6-Dimethyloctane 0.010 0.010 0.005 2.548 98.724 15869-85-9 5-Methylnonane 0.009 0.010 0.005 2.453 98.913 17301-94-8 4-Methylnonane 0.022 0.023 0.012 5.861 99.568 5881-17-4 3-Ethyloctane 0.004 0.005 0.002 1.185 99.889 5911-04-6 3-Methylnonane 0.031 0.033 0.017 8.312 100.701 C11-Isoparaffin-2 0.068 0.070 0.033 18.003 102.338 17302-01-1 3-Ethyl-3-methylheptane 0.140 0.145 0.069 37.096 104.411 C11 Isoparaffin-4 0.019 0.020 0.010 5.146 106.358 C11-Isoparaffin-7 0.318 0.329 0.156 84.204 108.566 C11- Isoparaffin-11 0.694 0.717 0.341 183.768 113.132 C12 - IsoParaffin - 1 0.020 0.020 0.009 5.230 116.238 C12 - IsoParaffin - 4 0.005 0.006 0.002 1.513

Aromatics Mono-Aromatics 45.637 71-42-3 Benzene 0.762 0.667 0.750 220.346

69.069 108-88-3 Toluene 11.289 10.016 9.421 3227.774 84.742 100-41-4 Ethylbenzene 2.126 1.886 1.540 603.262 85.983 108-38-3 m-Xylene 5.424 4.828 3.928 1539.029 86.124 106-42-3 p-Xylene 2.466 2.203 1.786 699.626 88.935 95-47-6 o-Xylene 1.395 1.219 1.010 395.859 93.095 98-82-8 i-Propylbenzene 0.035 0.031 0.023 9.924 96.557 103-65-1 n-Propylbenzene 0.546 0.487 0.349 153.898

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 97.412 620-14-4 1-Methyl-3-ethylbenzene 2.190 1.948 1.401 617.332

97.643 622-96-8 1-Methyl-4-ethylbenzene 1.026 0.916 0.656 289.162 98.268 108-67-8 1,3,5-Trimethylbenzene 1.319 1.173 0.844 371.949 99.349 611-14-3 1-Methyl-2-ethylbenzene 0.795 0.694 0.509 224.157 100.998 95-63-6 1,2,4-Trimethylbenzene 4.010 3.522 2.565 1130.624 102.636 538-93-2 i-Butylbenzene 0.210 0.189 0.120 58.832 103.855 526-73-8 1,2,3-Trimethylbenzene 0.711 0.612 0.455 200.480 104.234 535-77-3 1-Methyl-3-i-propylbenzene 0.024 0.022 0.014 6.805 104.617 99-87-6 1-Methyl-4-i-propylbenzene 0.134 0.121 0.077 37.701 106.549 141-93-5 1,3-Diethylbenzene 0.097 0.086 0.055 27.102 106.834 1074-43-7 1-Methyl-3-n-propylbenzene 1.138 1.017 0.652 319.151 107.167 105-05-5 1,4-Diethylbenzene 0.420 0.375 0.240 117.726 107.385 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.301 0.264 0.173 84.543 107.626 135-01-3 1,2-Diethylbenzene 0.079 0.069 0.045 22.122 108.235 1074-17-5 1-Methyl-2-n-propylbenzene 0.103 0.091 0.059 28.968 109.084 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.209 0.183 0.120 58.511 109.745 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.691 0.608 0.396 193.699 110.287 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.627 0.541 0.359 175.760 111.192 1-Methyl-4-t-butylbenzene 0.041 0.037 0.021 11.322 111.415 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.163 0.140 0.093 45.632 111.864 4218-48-8 1-Ethyl-4-i-propylbenzene 0.090 0.078 0.047 25.236 112.352 1,2,4,5-Tetramethylbenzene 0.538 0.467 0.308 150.976 112.618 527-53-7 1,2,3,5-Tetramethylbenzene 0.730 0.631 0.418 204.853 113.757 C11 - Aromatic - 3 0.096 0.083 0.050 26.882 114.072 1,2-Di-i-propylbenzene 0.083 0.072 0.039 23.143 114.286 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.119 0.103 0.062 33.241 114.443 C11 - Aromatic - 4 0.068 0.059 0.035 18.949 114.847 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.071 0.061 0.037 19.699 115.259 538-68-1 n-Pentylbenzene 0.028 0.024 0.015 7.833 115.486 tert-Pentylbenzene 0.123 0.107 0.064 34.466 115.799 577-55-9 1-Methyl-2-n-butylbenzene 0.055 0.048 0.029 15.369 115.908 C11 - Aromatic - 7 0.070 0.064 0.037 19.675 116.369 100-18-5 1,4-Di-i-propylbenzene 0.109 0.094 0.052 30.323 117.593 7364-19-4 1t-Butyl-4-ethylbenzene 0.017 0.015 0.008 4.694 117.895 1,3-Di-n-propylbenzene 0.090 0.078 0.043 25.039 118.005 C11 - Aromatic - 11 0.051 0.046 0.026 14.158 118.559 C11 - Aromatic - 12 0.034 0.030 0.017 9.389 119.487 102-25-0 1,3,5-Triethylbenzene 0.009 0.008 0.004 2.415 120.147 C12 - Aromatic - 1 0.005 0.004 0.002 1.299

Naphthalenes 116.813 91-20-3 Naphthalene 0.233 0.175 0.140 68.466

123.439 91-57-6 2-Methylnaphthalene 0.009 0.007 0.005 2.635 124.306 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.476

Naphtheno/Olefino-Benzs

113.947 874-35-1 5-Methylindan 0.229 0.198 0.133 64.313 114.944 824-63-5 2-Methylindan 0.223 0.192 0.130 62.446

Indenes 105.046 Indan 0.258 0.206 0.168 74.055

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Indenes 105.643 Indene 0.733 0.585 0.477 210.012

109.397 2-Methylindan 0.127 0.102 0.074 36.451 114.696 824-22-6 4-Methylindan 0.302 0.261 0.175 84.586 117.007 4,7-Dimethyl Indane 0.011 0.009 0.006 3.158 117.252 1,1-Dimethyl Indane 0.037 0.029 0.019 10.480 117.414 Dimethyl Indane - 1 0.015 0.012 0.008 4.273 117.733 Dimethyl Indane - 2 0.005 0.004 0.003 1.536

Naphthenes Mono-Naphthenes 27.604 287-92-3 Cyclopentane 0.244 0.251 0.267 65.362

40.671 96-37-7 Methylcyclopentane 1.055 1.085 0.964 283.306 47.552 110-82-7 Cyclohexane 0.448 0.442 0.409 120.162 53.352 1759-58-6 1t,3-Dimethylcyclopentane 0.100 0.103 0.078 26.826 53.938 2532-58-3 1c,3-Dimethylcyclopentane 0.068 0.070 0.053 18.197 54.563 822-50-4 1t,2-Dimethylcyclopentane 0.069 0.070 0.054 18.403 59.650 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.019 0.014 4.888 61.507 108-87-2 Methylcyclohexane 0.058 0.058 0.046 15.648 101.551 1678-98-4 i-Butylcyclohexane 0.011 0.011 0.006 3.000

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.623 115-11-7 Isobutene 0.016 0.020 0.022 4.228

9.664 106-98-9 Butene-1 0.018 0.023 0.024 4.729 10.510 624-64-6 t-Butene-2 0.072 0.092 0.099 19.355 11.250 590-18-1 c-Butene-2 0.085 0.105 0.116 22.797 16.730 109-67-1 Pentene-1 0.328 0.393 0.359 87.931 19.232 646-04-8 t-Pentene-2 0.832 0.987 0.912 223.252 20.263 627-20-3 c-Pentene-2 0.456 0.535 0.500 122.419 33.450 592-41-6 Hexene-1 0.157 0.178 0.144 42.227 36.439 13269-52-8 t-Hexene-3 0.258 0.291 0.236 69.365 36.916 4050-45-7 t-Hexene-2 0.397 0.447 0.363 106.583 38.742 7688-21-3 c-Hexene-2 0.210 0.234 0.192 56.392 55.468 592-76-7 Heptene-1 0.027 0.030 0.021 7.291 57.332 14686-14-7 t-Heptene-3 0.031 0.034 0.025 8.413 58.274 7642-10-6 c-Heptene-3 0.025 0.027 0.019 6.665 59.174 14686-13-6 t-Heptene-2 0.013 0.014 0.010 3.395 110.906 693-61-8 2-Undecene, (E)- 0.053 0.055 0.029 14.139

Iso-Olefins 13.454 563-45-1 3-Methylbutene-1 0.197 0.242 0.216 52.954

17.577 563-46-2 2-Methylbutene-1 0.497 0.588 0.545 133.516 20.940 513-35-9 2-Methylbutene-2 1.021 1.186 1.120 274.156 29.194 691-38-3 4-Methyl-c-pentene-2 0.044 0.051 0.041 11.916 29.843 674-76-0 4-Methyl-t-pentene-2 0.128 0.147 0.117 34.450 33.233 763-29-1 2-Methylpentene-1 0.220 0.247 0.201 59.096 35.642 760-21-4 2-Ethylbutene-1 0.062 0.069 0.057 16.747 37.406 625-27-4 2-Methylpentene-2 0.335 0.373 0.306 89.849 37.820 922-62-3 3-Methyl-c-pentene-2 0.259 0.285 0.236 69.441

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 40.086 3404-73-7 3,3-Dimethylpentene-1 0.306 0.336 0.240 82.196

42.532 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.014 0.010 3.544 46.637 3404-61-3 3-Methylhexene-1 0.016 0.017 0.012 4.167 47.230 3524-73-0 5-Methylhexene-1 0.038 0.042 0.030 10.241 49.272 15840-60-5 2-Methyl-c-hexene-3 0.040 0.044 0.031 10.677 49.619 3769-23-1 4-Methylhexene-1 0.011 0.012 0.008 2.867 50.266 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.055 0.039 13.442 54.842 C7 - Iso-Olefin - 2 0.022 0.023 0.017 5.868 56.801 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.011 3.660 57.683 6094-02-6 2-Methylhexene-1 0.056 0.062 0.044 15.137 58.548 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.020 6.845 58.793 10574-36-4 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.209 60.077 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.012 3.985 60.859 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.431

Naphtheno-Olefins 22.534 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.008 1.879

25.739 142-29-0 Cyclopentene 0.194 0.193 0.219 53.497 37.042 1120-62-3 3-Methylcyclopentene 0.098 0.099 0.092 26.242 45.833 693-89-0 1-Methylcyclopentene 0.354 0.349 0.331 97.257 51.152 110-83-8 Cyclohexene 0.044 0.042 0.041 11.800

Di-Olefins 18.628 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.012 0.012 2.816

21.269 2004-70-8 1t,3-Pentadiene 0.015 0.018 0.017 4.261 45.429 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 3.975

Oxygenates 13.124 64-17-5 Ethanol 21.767 21.222 36.330 2405.814

26.906 71-23-8 n-Propanol 0.078 0.075 0.100 14.745 48.062 71-36-3 n-Butanol 0.055 0.052 0.057 11.090

Unidentified 19.882 Unidentified 0.006 0.007 0.006 1.907

26.991 Unidentified 0.056 0.064 0.051 18.364 28.733 Unidentified 0.052 0.054 0.045 17.036 50.840 Unidentified 0.024 0.027 0.019 7.980 63.361 Unidentified 0.057 0.061 0.040 18.873 93.842 Unidentified 0.015 0.015 0.008 4.781 99.119 Unidentified 0.568 0.601 0.307 186.648 100.353 Unidentified 0.045 0.034 0.022 14.684 100.487 Unidentified 0.128 0.132 0.063 42.031 101.165 Unidentified 0.085 0.094 0.047 28.053 101.287 Unidentified 0.050 0.052 0.027 16.373 102.901 Unidentified 0.048 0.043 0.028 15.814 103.200 Unidentified 0.035 0.036 0.017 11.499 108.083 Unidentified 0.080 0.082 0.039 26.142 108.358 Unidentified 0.091 0.094 0.045 29.838 108.437 Unidentified 0.083 0.086 0.041 27.434 108.746 Unidentified 0.224 0.232 0.110 73.628 109.170 Unidentified 0.812 0.712 0.465 266.890

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 110.711 Unidentified 0.022 0.020 0.011 7.130

111.040 Unidentified 0.101 0.105 0.055 33.160 111.314 Unidentified 0.100 0.087 0.052 32.932 111.975 Unidentified 0.057 0.050 0.030 18.882 112.821 Unidentified 0.012 0.010 0.006 3.858 112.958 Unidentified 0.015 0.013 0.009 4.849 113.482 Unidentified 0.035 0.037 0.017 11.625 113.613 Unidentified 0.007 0.007 0.003 2.309 115.146 Unidentified 0.022 0.023 0.010 7.192

Plus

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2 2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

Toluene

2-Methylheptane 4-Methylheptane

3-Methylheptane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF95.090.085.080.075.0

n-Octane

Ethylbenzene

m-Xylene p-Xylene

o-Xylene

n-Nonane

i-Propylbenzene

Unidentified

2,5-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene Dimethyl Indane - 2 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,3,5-Triethylbenzene
C12 - Aromatic - 1

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 13:30:15 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF Sample: ODDB-91329 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91329 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000011.D\SIG2000011_FID2_B.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 3.580 4.480 4.343

I-Paraffins 26.765 31.493 26.304

Aromatics 43.296 37.521 31.368 Mono-Aromatics 41.011 35.674 29.940 Naphthalenes 0.336 0.248 0.208 Naphtheno/Olefino-Benzs 0.627 0.533 0.378 Indenes 1.323 1.066 0.842

Naphthenes 1.425 1.438 1.364 Mono-Naphthenes 1.425 1.438 1.364 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.192 8.040 7.486 n-Olefins 2.990 3.428 3.204 Iso-Olefins 3.439 3.863 3.497 Naphtheno-Olefins 0.722 0.705 0.740 Di-Olefins 0.041 0.044 0.045

Oxygenates 16.442 15.774 28.362

Unidentified 1.299 1.253 0.773

Plus 0.000 0.000 0.000

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 16.311 15.650 28.202 C3 0.075 0.071 0.100 C4 2.371 3.069 3.242 C5 16.690 20.062 18.558 C6 17.331 19.450 16.176 C7 12.679 11.479 10.842 C8 11.410 9.988 8.557 C9 10.612 9.198 7.035 C10 8.720 7.509 5.212 C11 2.026 1.866 1.069 C12 0.476 0.406 0.235

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 2.109 2.758 2.890 C5 0.838 1.014 0.926 C6 0.413 0.474 0.382 C7 0.096 0.107 0.077 C8 0.020 0.022 0.014 C9 0.006 0.007 0.004 C10 0.033 0.034 0.018 C11 0.063 0.064 0.032

I-Paraffins C4 0.017 0.023 0.023 C5 11.941 14.589 13.183 C6 12.756 14.704 11.791 C7 0.827 0.920 0.657 C8 0.046 0.050 0.032 C10 0.440 0.456 0.243 C11 0.719 0.732 0.367 C12 0.018 0.019 0.009

Mono-Aromatics C6 0.726 0.626 0.741 C7 10.715 9.355 9.262 C8 11.343 9.915 8.510 C9 10.358 8.996 6.864 C10 6.308 5.442 3.744 C11 1.130 0.973 0.607 C12 0.430 0.366 0.211

Naphthalenes C10 0.320 0.237 0.199 C11 0.015 0.011 0.008

Naphtheno/Olefino-Benzs C10 0.627 0.533 0.378

Indenes C9 0.248 0.195 0.167 C10 0.984 0.801 0.626 C11 0.063 0.049 0.034 C12 0.027 0.021 0.015

Mono-Naphthenes C5 0.313 0.318 0.355 C6 0.809 0.815 0.765 C7 0.297 0.299 0.240 C10 0.007 0.006 0.004

n-Olefins C4 0.189 0.235 0.269

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.637 1.911 1.859 C6 1.044 1.156 0.988 C7 0.084 0.091 0.068 C11 0.035 0.036 0.020

Iso-Olefins C5 1.731 2.001 1.965 C6 1.077 1.183 1.019 C7 0.631 0.679 0.512

Naphtheno-Olefins C5 0.204 0.201 0.239 C6 0.506 0.491 0.490 C7 0.013 0.012 0.011

Di-Olefins C5 0.026 0.029 0.031 C7 0.015 0.015 0.015

Oxygenates C2 16.311 15.650 28.202 C3 0.075 0.071 0.100 C4 0.056 0.053 0.060

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 22.89 22.31 5% 79.44 79.16 10% 80.80 80.27 15% 86.39 81.38 20% 134.21 96.99 25% 138.99 135.70 30% 144.35 139.00 35% 159.47 143.92 40% 172.48 154.03 45% 172.81 172.40 50% 173.14 172.74 55% 220.09 173.09 60% 225.26 197.38 65% 230.43 225.20 70% 280.63 243.86 75% 282.22 281.36 80% 322.54 291.87 85% 335.29 329.33 90% 359.24 352.03 95% 374.16 372.02 FBP 410.01 404.60

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.809 75-28-5 I4 i-Butane 0.017 0.023 0.023 5.177 2 9.621 115-11-7 K4 Isobutene 0.016 0.020 0.022 5.023 3 9.663 106-98-9 K4 Butene-1 0.017 0.022 0.025 5.591 4 10.023 106-97-8 P4 n-Butane 2.109 2.758 2.890 655.608 5 10.509 624-64-6 K4 t-Butene-2 0.072 0.090 0.102 23.066 6 10.637 463-82-1 I5 2,2-Dimethylpropane 0.008 0.010 0.009 2.511 7 11.251 590-18-1 K4 c-Butene-2 0.085 0.103 0.120 27.303 8 13.111 64-17-5 X2 Ethanol 16.311 15.650 28.202 2162.315 9 13.451 563-45-1 C5 3-Methylbutene-1 0.190 0.230 0.216 61.273 10 15.097 78-78-4 I5 i-Pentane 11.933 14.579 13.174 3735.075

11 16.728 109-67-1 K5 Pentene-1 0.331 0.392 0.376 106.701 12 17.580 563-46-2 C5 2-Methylbutene-1 0.504 0.586 0.572 162.173 13 18.112 109-66-0 P5 n-Pentane 0.838 1.014 0.926 262.437 14 18.625 78-79-5 E5 2-Methyl-1,3-Butadiene 0.010 0.012 0.012 3.456 15 19.232 646-04-8 K5 t-Pentene-2 0.843 0.985 0.958 271.448 16 19.879 ? Unidentified 0.006 0.007 0.007 2.292 17 20.266 627-20-3 K5 c-Pentene-2 0.463 0.534 0.525 148.936 18 20.944 513-35-9 C5 2-Methylbutene-2 1.037 1.185 1.177 333.713 19 21.270 2004-70-8 E5 1t,3-Pentadiene 0.016 0.018 0.018 5.211 20 22.535 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.008 2.314

21 23.092 75-83-2 I6 2,2-Dimethylbutane 0.369 0.430 0.341 115.862 22 25.740 142-29-0 B5 Cyclopentene 0.197 0.193 0.230 65.328 23 26.904 71-23-8 X3 n-Propanol 0.075 0.071 0.100 16.972 24 26.995 ? Unidentified 0.059 0.067 0.056 23.426 25 27.606 287-92-3 M5 Cyclopentane 0.313 0.318 0.355 100.758 26 28.342 79-29-8 I6 2,3-Dimethylbutane 1.375 1.573 1.270 431.949 27 28.734 ? Unidentified 0.053 0.054 0.048 20.912 28 29.204 691-38-3 C6 4-Methyl-c-pentene-2 0.045 0.050 0.042 14.401 29 29.461 107-83-5 I6 2-Methylpentane 7.744 8.976 7.158 2433.703 30 29.850 674-76-0 C6 4-Methyl-t-pentene-2 0.131 0.147 0.124 42.030

31 32.083 96-14-0 I6 3-Methylpentane 3.269 3.725 3.021 1027.171 32 33.230 763-29-1 C6 2-Methylpentene-1 0.224 0.248 0.212 72.191 33 33.454 592-41-6 K6 Hexene-1 0.160 0.179 0.152 51.582 34 35.641 760-21-4 C6 2-Ethylbutene-1 0.072 0.079 0.068 23.300 35 35.802 110-54-3 P6 n-Hexane 0.413 0.474 0.382 129.877 36 36.439 13269-52-8 K6 t-Hexene-3 0.263 0.292 0.249 84.733 37 36.918 4050-45-7 K6 t-Hexene-2 0.406 0.450 0.384 130.707 38 37.040 1120-62-3 B6 3-Methylcyclopentene 0.099 0.098 0.096 31.759 39 37.408 625-27-4 C6 2-Methylpentene-2 0.341 0.374 0.323 109.806 40 37.823 922-62-3 C6 3-Methyl-c-pentene-2 0.264 0.286 0.250 84.946

41 38.745 7688-21-3 K6 c-Hexene-2 0.214 0.235 0.203 69.017 42 40.091 3404-73-7 C7 3,3-Dimethylpentene-1 0.311 0.335 0.252 100.051 43 40.670 96-37-7 M6 Methylcyclopentane 0.740 0.748 0.700 238.146

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.243 108-08-7 I7 2,4-Dimethylpentane 0.146 0.164 0.116 46.060 45 42.534 594-56-9 C7 2,3,3-Trimethylbutene-1 0.009 0.010 0.007 2.897 46 44.495 7459-71-4 B7 3,5-Dimethylcyclopentene 0.013 0.012 0.011 4.125 47 45.429 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.015 4.875 48 45.640 71-42-3 Q6 Benzene 0.726 0.626 0.741 251.866 49 45.836 693-89-0 B6 1-Methylcyclopentene 0.362 0.351 0.351 119.252 50 46.643 3404-61-3 C7 3-Methylhexene-1 0.016 0.018 0.013 5.217 51 47.229 3524-73-0 C7 5-Methylhexene-1 0.023 0.025 0.018 7.340 52 47.553 110-82-7 M6 Cyclohexane 0.069 0.067 0.065 22.211 53 48.058 71-36-3 X4 n-Butanol 0.056 0.053 0.060 13.663

54 49.274 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.033 13.058 55 49.621 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.009 3.672 56 50.268 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.051 0.055 0.042 16.512 57 50.661 591-76-4 I7 2-Methylhexane 0.405 0.452 0.322 127.777 58 50.841 ? Unidentified 0.020 0.022 0.017 7.883 59 51.153 110-83-8 B6 Cyclohexene 0.045 0.042 0.044 14.542 60 52.493 589-34-4 I7 3-Methylhexane 0.276 0.304 0.220 87.130 61 53.354 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.097 0.098 0.078 31.087 62 53.940 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.064 0.065 0.052 20.739 63 54.566 822-50-4 M7 1t,2-Dimethylcyclopentane 0.059 0.059 0.048 18.891

64 54.843 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.018 7.276 65 55.470 592-76-7 K7 Heptene-1 0.014 0.015 0.011 4.427 66 55.604 M7 C7 - MonoNaph - 1 0.014 0.013 0.010 4.429 67 56.803 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.011 4.505 68 57.333 14686-14-7 K7 t-Heptene-3 0.032 0.035 0.026 10.417 69 57.685 6094-02-6 C7 2-Methylhexene-1 0.058 0.063 0.047 18.603 70 58.055 142-82-5 P7 n-Heptane 0.096 0.107 0.077 30.404 71 58.276 7642-10-6 K7 c-Heptene-3 0.026 0.028 0.021 8.302 72 58.550 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.021 8.482 73 58.794 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.021 0.016 6.457

74 59.176 14686-13-6 K7 t-Heptene-2 0.012 0.013 0.010 3.954 75 59.653 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.015 6.028 76 60.078 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.012 4.946 77 60.862 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 4.178 78 61.503 108-87-2 M7 Methylcyclohexane 0.045 0.044 0.037 14.529 79 63.365 ? Unidentified 0.045 0.047 0.032 17.677 80 69.082 108-88-3 Q7 Toluene 10.715 9.355 9.262 3674.563 81 72.047 592-27-8 I8 2-Methylheptane 0.018 0.019 0.012 5.541 82 72.301 589-53-7 I8 4-Methylheptane 0.010 0.010 0.007 3.071 83 73.362 589-81-1 I8 3-Methylheptane 0.019 0.021 0.013 6.059

84 77.870 111-65-9 P8 n-Octane 0.020 0.022 0.014 6.465 85 84.746 100-41-4 Q8 Ethylbenzene 2.111 1.843 1.584 718.518 86 85.993 108-38-3 Q8 m-Xylene 5.389 4.721 4.043 1834.259

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 86.132 106-42-3 Q8 p-Xylene 2.444 2.149 1.834 831.977 88 88.939 95-47-6 Q8 o-Xylene 1.398 1.202 1.049 475.836 89 91.751 111-84-2 P9 n-Nonane 0.006 0.007 0.004 1.995 90 93.096 98-82-8 Q9 i-Propylbenzene 0.037 0.032 0.024 12.472 91 95.508 2051-30-1 I10 2,4-Dimethyloctane 0.009 0.009 0.005 2.705 92 96.558 103-65-1 Q9 n-Propylbenzene 0.530 0.466 0.351 179.330 93 97.417 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.130 1.865 1.411 720.185 94 97.646 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.998 0.877 0.661 337.491 95 98.271 108-67-8 Q9 1,3,5-Trimethylbenzene 1.274 1.114 0.844 430.727 96 98.725 15869-85-9 I10 5-Methylnonane 0.009 0.009 0.005 2.729

97 98.914 17301-94-8 I10 4-Methylnonane 0.021 0.021 0.011 6.508 98 99.118 I10 2,2,6-Trimethyloctane 0.297 0.310 0.167 94.413 99 99.351 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.778 0.669 0.516 263.055 100 99.570 5881-17-4 I10 3-Ethyloctane 0.006 0.006 0.003 1.815 101 99.890 5911-04-6 I10 3-Methylnonane 0.031 0.032 0.017 9.723 102 100.354 ? Unidentified 0.020 0.015 0.010 7.865 103 100.488 ? Unidentified 0.059 0.060 0.030 23.427 104 100.701 I11 C11-Isoparaffin-2 0.033 0.033 0.017 10.410 105 101.004 95-63-6 Q9 1,2,4-Trimethylbenzene 3.904 3.375 2.587 1320.248 106 101.166 ? Unidentified 0.042 0.046 0.024 16.645

107 101.288 ? Unidentified 0.025 0.026 0.014 9.938 108 101.551 1678-98-4 M10 i-Butylcyclohexane 0.007 0.006 0.004 2.107 109 102.338 17302-01-1 I10 3-Ethyl-3-methylheptane 0.069 0.070 0.035 21.809 110 102.627 538-93-2 Q10 i-Butylbenzene 0.110 0.098 0.065 37.102 111 102.806 124-18-5 P10 n-Decane 0.033 0.034 0.018 10.422 112 102.902 ? Unidentified 0.044 0.039 0.026 17.297 113 103.200 ? Unidentified 0.019 0.019 0.010 7.375 114 103.856 526-73-8 Q9 1,2,3-Trimethylbenzene 0.707 0.599 0.469 239.171 115 104.244 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.021 0.018 0.012 6.930 116 104.412 I11 C11 Isoparaffin-4 0.012 0.012 0.006 3.736

117 104.617 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.081 0.071 0.048 27.192 118 105.047 J9 Indan 0.248 0.195 0.167 85.272 119 105.643 J10 Indene 0.460 0.362 0.310 158.236 120 106.358 I11 C11-Isoparaffin-7 0.206 0.209 0.105 65.361 121 106.549 141-93-5 Q10 1,3-Diethylbenzene 0.110 0.097 0.066 37.149 122 106.827 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.889 0.782 0.528 299.094 123 107.170 105-05-5 Q10 1,4-Diethylbenzene 0.353 0.310 0.209 118.667 124 107.267 104-51-8 Q10 n-Butylbenzene 0.067 0.059 0.040 22.570 125 107.387 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.396 0.341 0.235 133.245 126 107.644 135-01-3 Q10 1,2-Diethylbenzene 0.061 0.053 0.036 20.540

127 108.084 ? Unidentified 0.052 0.053 0.027 20.644 128 108.236 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.137 0.119 0.081 46.093 129 108.358 ? Unidentified 0.061 0.062 0.031 23.957

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 108.439 ? Unidentified 0.056 0.056 0.028 21.899 131 108.566 I11 C11- Isoparaffin-11 0.469 0.477 0.239 149.073 132 108.747 ? Unidentified 0.152 0.154 0.077 59.856 133 109.084 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.325 0.280 0.193 109.194 134 109.172 ? Unidentified 0.403 0.347 0.239 158.793 135 109.244 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.361 0.312 0.214 121.545 136 109.397 J10 2-Methylindan 0.100 0.079 0.060 34.463 137 109.748 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.890 0.770 0.528 299.351 138 110.288 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.451 0.384 0.268 151.731 139 110.712 ? Unidentified 0.013 0.012 0.007 4.976

140 110.907 693-61-8 K11 2-Undecene, (E)- 0.035 0.036 0.020 11.152 141 111.042 ? Unidentified 0.046 0.047 0.026 17.953 142 111.197 Q11 1-Methyl-4-t-butylbenzene 0.077 0.068 0.041 25.643 143 111.418 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.306 0.259 0.181 102.803 144 111.714 1120-21-4 P11 n-Undecane 0.063 0.064 0.032 20.072 145 111.868 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.068 0.058 0.037 22.807 146 111.976 ? Unidentified 0.034 0.029 0.018 13.307 147 112.083 Q11 C11 - Aromatic - 1 0.007 0.006 0.004 2.456 148 112.356 Q10 1,2,4,5-Tetramethylbenzene 0.739 0.630 0.439 248.541 149 112.623 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 1.011 0.860 0.600 340.155

150 112.813 ? Unidentified 0.009 0.007 0.005 3.466 151 112.962 ? Unidentified 0.011 0.010 0.007 4.451 152 113.134 I12 C12 - IsoParaffin - 1 0.013 0.013 0.006 4.048 153 113.486 ? Unidentified 0.040 0.041 0.019 15.583 154 113.757 Q11 C11 - Aromatic - 3 0.116 0.098 0.062 38.766 155 113.949 874-35-1 H10 5-Methylindan 0.317 0.269 0.191 106.484 156 114.073 Q12 1,2-Di-i-propylbenzene 0.115 0.097 0.056 38.230 157 114.288 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.165 0.140 0.088 55.136 158 114.443 Q11 C11 - Aromatic - 4 0.091 0.077 0.049 30.433 159 114.698 824-22-6 J10 4-Methylindan 0.424 0.360 0.255 142.501

160 114.848 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.098 0.084 0.053 32.973 161 114.946 824-63-5 H10 2-Methylindan 0.310 0.264 0.187 104.407 162 115.146 ? Unidentified 0.030 0.030 0.014 11.648 163 115.260 538-68-1 Q11 n-Pentylbenzene 0.039 0.033 0.021 13.066 164 115.487 Q11 tert-Pentylbenzene 0.172 0.146 0.092 57.548 165 115.800 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.077 0.066 0.041 25.841 166 115.909 Q11 C11 - Aromatic - 7 0.095 0.084 0.051 31.740 167 116.239 I12 C12 - IsoParaffin - 4 0.006 0.006 0.003 1.924 168 116.370 100-18-5 Q12 1,4-Di-i-propylbenzene 0.149 0.127 0.073 49.736 169 116.815 91-20-3 G10 Naphthalene 0.320 0.237 0.199 112.847

170 117.008 J11 4,7-Dimethyl Indane 0.014 0.011 0.007 4.651 171 117.253 J11 1,1-Dimethyl Indane 0.049 0.039 0.027 16.938 172 117.415 J12 Dimethyl Indane - 1 0.020 0.016 0.011 6.967

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 117.593 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.023 0.020 0.011 7.679 174 117.733 J12 Dimethyl Indane - 2 0.007 0.006 0.004 2.412 175 117.895 Q12 1,3-Di-n-propylbenzene 0.125 0.107 0.062 41.855 176 118.006 Q11 C11 - Aromatic - 11 0.071 0.063 0.038 23.710 177 118.559 Q11 C11 - Aromatic - 12 0.047 0.042 0.025 15.884 178 119.189 Q11 C11 - Aromatic - 13 0.007 0.007 0.004 2.459 179 119.487 102-25-0 Q12 1,3,5-Triethylbenzene 0.012 0.010 0.006 4.107 180 120.146 Q12 C12 - Aromatic - 1 0.006 0.005 0.003 2.105 181 123.440 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.006 3.469 182 124.306 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.842

183 130.001 ? Unidentified 0.003 0.002 0.001 1.142

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 10.023 106-97-8 n-Butane 2.109 2.758 2.890 655.608

18.112 109-66-0 n-Pentane 0.838 1.014 0.926 262.437 35.802 110-54-3 n-Hexane 0.413 0.474 0.382 129.877 58.055 142-82-5 n-Heptane 0.096 0.107 0.077 30.404 77.870 111-65-9 n-Octane 0.020 0.022 0.014 6.465 91.751 111-84-2 n-Nonane 0.006 0.007 0.004 1.995 102.806 124-18-5 n-Decane 0.033 0.034 0.018 10.422 111.714 1120-21-4 n-Undecane 0.063 0.064 0.032 20.072

I-Paraffins 8.809 75-28-5 i-Butane 0.017 0.023 0.023 5.177

10.637 463-82-1 2,2-Dimethylpropane 0.008 0.010 0.009 2.511 15.097 78-78-4 i-Pentane 11.933 14.579 13.174 3735.075 23.092 75-83-2 2,2-Dimethylbutane 0.369 0.430 0.341 115.862 28.342 79-29-8 2,3-Dimethylbutane 1.375 1.573 1.270 431.949 29.461 107-83-5 2-Methylpentane 7.744 8.976 7.158 2433.703 32.083 96-14-0 3-Methylpentane 3.269 3.725 3.021 1027.171 42.243 108-08-7 2,4-Dimethylpentane 0.146 0.164 0.116 46.060 50.661 591-76-4 2-Methylhexane 0.405 0.452 0.322 127.777 52.493 589-34-4 3-Methylhexane 0.276 0.304 0.220 87.130 72.047 592-27-8 2-Methylheptane 0.018 0.019 0.012 5.541 72.301 589-53-7 4-Methylheptane 0.010 0.010 0.007 3.071 73.362 589-81-1 3-Methylheptane 0.019 0.021 0.013 6.059 95.508 2051-30-1 2,4-Dimethyloctane 0.009 0.009 0.005 2.705 98.725 15869-85-9 5-Methylnonane 0.009 0.009 0.005 2.729 98.914 17301-94-8 4-Methylnonane 0.021 0.021 0.011 6.508 99.118 2,2,6-Trimethyloctane 0.297 0.310 0.167 94.413 99.570 5881-17-4 3-Ethyloctane 0.006 0.006 0.003 1.815 99.890 5911-04-6 3-Methylnonane 0.031 0.032 0.017 9.723 100.701 C11-Isoparaffin-2 0.033 0.033 0.017 10.410 102.338 17302-01-1 3-Ethyl-3-methylheptane 0.069 0.070 0.035 21.809 104.412 C11 Isoparaffin-4 0.012 0.012 0.006 3.736 106.358 C11-Isoparaffin-7 0.206 0.209 0.105 65.361 108.566 C11- Isoparaffin-11 0.469 0.477 0.239 149.073 113.134 C12 - IsoParaffin - 1 0.013 0.013 0.006 4.048 116.239 C12 - IsoParaffin - 4 0.006 0.006 0.003 1.924

Aromatics Mono-Aromatics 45.640 71-42-3 Benzene 0.726 0.626 0.741 251.866

69.082 108-88-3 Toluene 10.715 9.355 9.262 3674.563 84.746 100-41-4 Ethylbenzene 2.111 1.843 1.584 718.518 85.993 108-38-3 m-Xylene 5.389 4.721 4.043 1834.259 86.132 106-42-3 p-Xylene 2.444 2.149 1.834 831.977 88.939 95-47-6 o-Xylene 1.398 1.202 1.049 475.836 93.096 98-82-8 i-Propylbenzene 0.037 0.032 0.024 12.472 96.558 103-65-1 n-Propylbenzene 0.530 0.466 0.351 179.330 97.417 620-14-4 1-Methyl-3-ethylbenzene 2.130 1.865 1.411 720.185 97.646 622-96-8 1-Methyl-4-ethylbenzene 0.998 0.877 0.661 337.491

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 98.271 108-67-8 1,3,5-Trimethylbenzene 1.274 1.114 0.844 430.727

99.351 611-14-3 1-Methyl-2-ethylbenzene 0.778 0.669 0.516 263.055 101.004 95-63-6 1,2,4-Trimethylbenzene 3.904 3.375 2.587 1320.248 102.627 538-93-2 i-Butylbenzene 0.110 0.098 0.065 37.102 103.856 526-73-8 1,2,3-Trimethylbenzene 0.707 0.599 0.469 239.171 104.244 535-77-3 1-Methyl-3-i-propylbenzene 0.021 0.018 0.012 6.930 104.617 99-87-6 1-Methyl-4-i-propylbenzene 0.081 0.071 0.048 27.192 106.549 141-93-5 1,3-Diethylbenzene 0.110 0.097 0.066 37.149 106.827 1074-43-7 1-Methyl-3-n-propylbenzene 0.889 0.782 0.528 299.094 107.170 105-05-5 1,4-Diethylbenzene 0.353 0.310 0.209 118.667 107.267 104-51-8 n-Butylbenzene 0.067 0.059 0.040 22.570 107.387 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.396 0.341 0.235 133.245 107.644 135-01-3 1,2-Diethylbenzene 0.061 0.053 0.036 20.540 108.236 1074-17-5 1-Methyl-2-n-propylbenzene 0.137 0.119 0.081 46.093 109.084 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.325 0.280 0.193 109.194 109.244 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.361 0.312 0.214 121.545 109.748 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.890 0.770 0.528 299.351 110.288 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.451 0.384 0.268 151.731 111.197 1-Methyl-4-t-butylbenzene 0.077 0.068 0.041 25.643 111.418 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.306 0.259 0.181 102.803 111.868 4218-48-8 1-Ethyl-4-i-propylbenzene 0.068 0.058 0.037 22.807 112.083 C11 - Aromatic - 1 0.007 0.006 0.004 2.456 112.356 1,2,4,5-Tetramethylbenzene 0.739 0.630 0.439 248.541 112.623 527-53-7 1,2,3,5-Tetramethylbenzene 1.011 0.860 0.600 340.155 113.757 C11 - Aromatic - 3 0.116 0.098 0.062 38.766 114.073 1,2-Di-i-propylbenzene 0.115 0.097 0.056 38.230 114.288 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.165 0.140 0.088 55.136 114.443 C11 - Aromatic - 4 0.091 0.077 0.049 30.433 114.848 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.098 0.084 0.053 32.973 115.260 538-68-1 n-Pentylbenzene 0.039 0.033 0.021 13.066 115.487 tert-Pentylbenzene 0.172 0.146 0.092 57.548 115.800 577-55-9 1-Methyl-2-n-butylbenzene 0.077 0.066 0.041 25.841 115.909 C11 - Aromatic - 7 0.095 0.084 0.051 31.740 116.370 100-18-5 1,4-Di-i-propylbenzene 0.149 0.127 0.073 49.736 117.593 7364-19-4 1t-Butyl-4-ethylbenzene 0.023 0.020 0.011 7.679 117.895 1,3-Di-n-propylbenzene 0.125 0.107 0.062 41.855 118.006 C11 - Aromatic - 11 0.071 0.063 0.038 23.710 118.559 C11 - Aromatic - 12 0.047 0.042 0.025 15.884 119.189 C11 - Aromatic - 13 0.007 0.007 0.004 2.459 119.487 102-25-0 1,3,5-Triethylbenzene 0.012 0.010 0.006 4.107 120.146 C12 - Aromatic - 1 0.006 0.005 0.003 2.105

Naphthalenes 116.815 91-20-3 Naphthalene 0.320 0.237 0.199 112.847

123.440 91-57-6 2-Methylnaphthalene 0.010 0.007 0.006 3.469 124.306 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.842

Naphtheno/Olefino-Benzs

113.949 874-35-1 5-Methylindan 0.317 0.269 0.191 106.484

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphtheno/Olefino-Benzs

114.946 824-63-5 2-Methylindan 0.310 0.264 0.187 104.407

Indenes 105.047 Indan 0.248 0.195 0.167 85.272

105.643 Indene 0.460 0.362 0.310 158.236 109.397 2-Methylindan 0.100 0.079 0.060 34.463 114.698 824-22-6 4-Methylindan 0.424 0.360 0.255 142.501 117.008 4,7-Dimethyl Indane 0.014 0.011 0.007 4.651 117.253 1,1-Dimethyl Indane 0.049 0.039 0.027 16.938 117.415 Dimethyl Indane - 1 0.020 0.016 0.011 6.967 117.733 Dimethyl Indane - 2 0.007 0.006 0.004 2.412

Naphthenes Mono-Naphthenes 27.606 287-92-3 Cyclopentane 0.313 0.318 0.355 100.758

40.670 96-37-7 Methylcyclopentane 0.740 0.748 0.700 238.146 47.553 110-82-7 Cyclohexane 0.069 0.067 0.065 22.211 53.354 1759-58-6 1t,3-Dimethylcyclopentane 0.097 0.098 0.078 31.087 53.940 2532-58-3 1c,3-Dimethylcyclopentane 0.064 0.065 0.052 20.739 54.566 822-50-4 1t,2-Dimethylcyclopentane 0.059 0.059 0.048 18.891 55.604 C7 - MonoNaph - 1 0.014 0.013 0.010 4.429 59.653 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.019 0.019 0.015 6.028 61.503 108-87-2 Methylcyclohexane 0.045 0.044 0.037 14.529 101.551 1678-98-4 i-Butylcyclohexane 0.007 0.006 0.004 2.107

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.621 115-11-7 Isobutene 0.016 0.020 0.022 5.023

9.663 106-98-9 Butene-1 0.017 0.022 0.025 5.591 10.509 624-64-6 t-Butene-2 0.072 0.090 0.102 23.066 11.251 590-18-1 c-Butene-2 0.085 0.103 0.120 27.303 16.728 109-67-1 Pentene-1 0.331 0.392 0.376 106.701 19.232 646-04-8 t-Pentene-2 0.843 0.985 0.958 271.448 20.266 627-20-3 c-Pentene-2 0.463 0.534 0.525 148.936 33.454 592-41-6 Hexene-1 0.160 0.179 0.152 51.582 36.439 13269-52-8 t-Hexene-3 0.263 0.292 0.249 84.733 36.918 4050-45-7 t-Hexene-2 0.406 0.450 0.384 130.707 38.745 7688-21-3 c-Hexene-2 0.214 0.235 0.203 69.017 55.470 592-76-7 Heptene-1 0.014 0.015 0.011 4.427 57.333 14686-14-7 t-Heptene-3 0.032 0.035 0.026 10.417 58.276 7642-10-6 c-Heptene-3 0.026 0.028 0.021 8.302 59.176 14686-13-6 t-Heptene-2 0.012 0.013 0.010 3.954 110.907 693-61-8 2-Undecene, (E)- 0.035 0.036 0.020 11.152

Iso-Olefins 13.451 563-45-1 3-Methylbutene-1 0.190 0.230 0.216 61.273

17.580 563-46-2 2-Methylbutene-1 0.504 0.586 0.572 162.173 20.944 513-35-9 2-Methylbutene-2 1.037 1.185 1.177 333.713 29.204 691-38-3 4-Methyl-c-pentene-2 0.045 0.050 0.042 14.401 29.850 674-76-0 4-Methyl-t-pentene-2 0.131 0.147 0.124 42.030

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 33.230 763-29-1 2-Methylpentene-1 0.224 0.248 0.212 72.191

35.641 760-21-4 2-Ethylbutene-1 0.072 0.079 0.068 23.300 37.408 625-27-4 2-Methylpentene-2 0.341 0.374 0.323 109.806 37.823 922-62-3 3-Methyl-c-pentene-2 0.264 0.286 0.250 84.946 40.091 3404-73-7 3,3-Dimethylpentene-1 0.311 0.335 0.252 100.051 42.534 594-56-9 2,3,3-Trimethylbutene-1 0.009 0.010 0.007 2.897 46.643 3404-61-3 3-Methylhexene-1 0.016 0.018 0.013 5.217 47.229 3524-73-0 5-Methylhexene-1 0.023 0.025 0.018 7.340 49.274 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.033 13.058 49.621 3769-23-1 4-Methylhexene-1 0.011 0.012 0.009 3.672 50.268 3404-55-5 4-Methyl-t/c-hexene-2 0.051 0.055 0.042 16.512 54.843 C7 - Iso-Olefin - 2 0.023 0.024 0.018 7.276 56.803 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.011 4.505 57.685 6094-02-6 2-Methylhexene-1 0.058 0.063 0.047 18.603 58.550 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.021 8.482 58.794 10574-36-4 3-Methyl-c-hexene-2 0.020 0.021 0.016 6.457 60.078 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.012 4.946 60.862 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 4.178

Naphtheno-Olefins 22.535 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.008 2.314

25.740 142-29-0 Cyclopentene 0.197 0.193 0.230 65.328 37.040 1120-62-3 3-Methylcyclopentene 0.099 0.098 0.096 31.759 44.495 7459-71-4 3,5-Dimethylcyclopentene 0.013 0.012 0.011 4.125 45.836 693-89-0 1-Methylcyclopentene 0.362 0.351 0.351 119.252 51.153 110-83-8 Cyclohexene 0.045 0.042 0.044 14.542

Di-Olefins 18.625 78-79-5 2-Methyl-1,3-Butadiene 0.010 0.012 0.012 3.456

21.270 2004-70-8 1t,3-Pentadiene 0.016 0.018 0.018 5.211 45.429 1528-30-9 C6-Diolefin-1 0.015 0.015 0.015 4.875

Oxygenates 13.111 64-17-5 Ethanol 16.311 15.650 28.202 2162.315

26.904 71-23-8 n-Propanol 0.075 0.071 0.100 16.972 48.058 71-36-3 n-Butanol 0.056 0.053 0.060 13.663

Unidentified 19.879 Unidentified 0.006 0.007 0.007 2.292

26.995 Unidentified 0.059 0.067 0.056 23.426 28.734 Unidentified 0.053 0.054 0.048 20.912 50.841 Unidentified 0.020 0.022 0.017 7.883 63.365 Unidentified 0.045 0.047 0.032 17.677 100.354 Unidentified 0.020 0.015 0.010 7.865 100.488 Unidentified 0.059 0.060 0.030 23.427 101.166 Unidentified 0.042 0.046 0.024 16.645 101.288 Unidentified 0.025 0.026 0.014 9.938 102.902 Unidentified 0.044 0.039 0.026 17.297 103.200 Unidentified 0.019 0.019 0.010 7.375 108.084 Unidentified 0.052 0.053 0.027 20.644 108.358 Unidentified 0.061 0.062 0.031 23.957

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 108.439 Unidentified 0.056 0.056 0.028 21.899

108.747 Unidentified 0.152 0.154 0.077 59.856 109.172 Unidentified 0.403 0.347 0.239 158.793 110.712 Unidentified 0.013 0.012 0.007 4.976 111.042 Unidentified 0.046 0.047 0.026 17.953 111.976 Unidentified 0.034 0.029 0.018 13.307 112.813 Unidentified 0.009 0.007 0.005 3.466 112.962 Unidentified 0.011 0.010 0.007 4.451 113.486 Unidentified 0.040 0.041 0.019 15.583 115.146 Unidentified 0.030 0.030 0.014 11.648 130.001 Unidentified 0.003 0.002 0.001 1.142

Plus

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1

3,5-Dimethylcyclopentene

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2 2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 Heptene-1 C7 - MonoNaph - 1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

Toluene

2-Methylheptane 4-Methylheptane

3-Methylheptane

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF95.090.085.080.075.0

n-Octane

Ethylbenzene

m-Xylene p-Xylene

o-Xylene

n-Nonane

i-Propylbenzene

2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified C11 - Aromatic - 1 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene Dimethyl Indane - 2 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12
C11 - Aromatic - 13 1,3,5-Triethylbenzene
C12 - Aromatic - 1

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 15:57:03 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF Sample: ODDB-91330 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91330 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000012.D\SIG2000012_FID2_B.CDF145.0140.0135.0130.0125.0

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 4.083 4.804 4.540

I-Paraffins 42.647 45.728 33.265

Aromatics 22.281 18.909 17.099 Mono-Aromatics 20.011 17.143 15.521 Naphthalenes 0.136 0.099 0.088 Naphtheno/Olefino-Benzs 0.173 0.145 0.110 Indenes 1.961 1.522 1.380

Naphthenes 1.643 1.617 1.575 Mono-Naphthenes 1.643 1.617 1.575 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.614 8.382 8.395 n-Olefins 3.191 3.600 3.619 Iso-Olefins 3.641 4.026 3.921 Naphtheno-Olefins 0.739 0.710 0.805 Di-Olefins 0.043 0.046 0.050

Oxygenates 16.687 15.756 30.495

Unidentified 5.045 4.805 4.631

Plus 0.000 0.000 0.000

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 16.550 15.628 30.318 C3 0.079 0.074 0.111 C4 1.683 2.133 2.436 C5 9.089 10.633 10.772 C6 9.900 10.643 9.871 C7 8.867 8.457 7.866 C8 26.247 26.680 19.665 C9 8.277 7.632 5.683 C10 11.654 10.790 7.227 C11 2.439 2.378 1.332 C12 0.171 0.149 0.088

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 1.395 1.796 2.025 C5 0.876 1.042 1.025 C6 0.963 1.088 0.943 C7 0.112 0.122 0.094 C8 0.026 0.028 0.020 C9 0.279 0.290 0.184 C10 0.303 0.309 0.180 C11 0.124 0.124 0.067 C12 0.005 0.005 0.003

I-Paraffins C4 0.021 0.028 0.031 C5 4.282 5.150 5.008 C6 4.383 4.957 4.292 C7 2.569 2.824 2.163 C8 21.317 22.433 15.749 C9 2.671 2.804 1.758 C10 5.502 5.627 3.238 C11 1.868 1.870 1.008 C12 0.034 0.034 0.017

Mono-Aromatics C6 0.720 0.610 0.778 C7 5.106 4.388 4.676 C8 4.880 4.197 3.879 C9 5.060 4.326 3.553 C10 3.757 3.210 2.362 C11 0.363 0.307 0.207 C12 0.125 0.105 0.065

Naphthalenes C10 0.117 0.085 0.077 C11 0.019 0.014 0.011

Naphtheno/Olefino-Benzs C10 0.173 0.145 0.110

Indenes C9 0.223 0.172 0.159 C10 1.721 1.337 1.211 C11 0.011 0.009 0.007 C12 0.006 0.005 0.004

Mono-Naphthenes C5 0.099 0.098 0.119 C6 1.107 1.094 1.110 C7 0.304 0.301 0.262 C8 0.014 0.013 0.010

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.043 0.039 0.029 C10 0.076 0.071 0.046

n-Olefins C4 0.209 0.255 0.314 C5 1.745 2.004 2.100 C6 1.083 1.180 1.086 C7 0.101 0.107 0.087 C11 0.054 0.054 0.032

Iso-Olefins C5 1.845 2.099 2.220 C6 1.120 1.212 1.123 C7 0.661 0.700 0.568 C8 0.010 0.010 0.007 C10 0.005 0.006 0.003

Naphtheno-Olefins C5 0.215 0.209 0.267 C6 0.524 0.501 0.538

Di-Olefins C5 0.028 0.030 0.034 C7 0.016 0.016 0.016

Oxygenates C2 16.550 15.628 30.318 C3 0.079 0.074 0.111 C4 0.058 0.054 0.066

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 23.97 23.13 5% 81.07 80.38 10% 100.74 97.08 15% 144.48 137.87 20% 168.76 154.06 25% 172.53 172.35 30% 172.86 172.69 35% 173.18 173.04 40% 193.37 176.58 45% 209.85 209.42 50% 228.40 210.31 55% 230.67 229.99 60% 235.00 232.43 65% 238.04 236.99 70% 261.54 243.44 75% 291.66 281.24 80% 326.97 320.72 85% 334.28 332.34 90% 352.22 352.22 95% 363.20 363.20 FBP 402.05 388.39

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.806 75-28-5 I4 i-Butane 0.021 0.028 0.031 5.320 2 9.619 115-11-7 K4 Isobutene 0.017 0.022 0.026 4.527 3 9.661 106-98-9 K4 Butene-1 0.019 0.024 0.029 5.030 4 10.020 106-97-8 P4 n-Butane 1.395 1.796 2.025 348.622 5 10.506 624-64-6 K4 t-Butene-2 0.079 0.097 0.119 20.405 6 10.634 463-82-1 I5 2,2-Dimethylpropane 0.016 0.020 0.018 3.956 7 11.247 590-18-1 K4 c-Butene-2 0.093 0.112 0.140 24.087 8 13.087 64-17-5 X2 Ethanol 16.550 15.628 30.318 1763.987 9 13.448 563-45-1 C5 3-Methylbutene-1 0.205 0.244 0.247 53.090 10 15.074 78-78-4 I5 i-Pentane 4.266 5.130 4.990 1073.609

11 16.726 109-67-1 K5 Pentene-1 0.355 0.413 0.427 91.857 12 17.578 563-46-2 C5 2-Methylbutene-1 0.538 0.617 0.648 139.330 13 18.110 109-66-0 P5 n-Pentane 0.876 1.042 1.025 220.468 14 18.624 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.014 2.981 15 19.230 646-04-8 K5 t-Pentene-2 0.898 1.032 1.081 232.434 16 19.876 ? Unidentified 0.006 0.007 0.007 1.963 17 20.264 627-20-3 K5 c-Pentene-2 0.492 0.559 0.592 127.403 18 20.942 513-35-9 C5 2-Methylbutene-2 1.101 1.239 1.325 285.046 19 21.266 2004-70-8 E5 1t,3-Pentadiene 0.016 0.018 0.020 4.394 20 22.532 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.009 1.969

21 23.105 75-83-2 I6 2,2-Dimethylbutane 0.029 0.033 0.028 7.201 22 25.738 142-29-0 B5 Cyclopentene 0.208 0.201 0.258 55.399 23 26.901 71-23-8 X3 n-Propanol 0.079 0.074 0.111 14.373 24 26.992 ? Unidentified 0.062 0.069 0.062 19.690 25 27.606 287-92-3 M5 Cyclopentane 0.099 0.098 0.119 25.503 26 28.339 79-29-8 I6 2,3-Dimethylbutane 1.335 1.504 1.308 337.344 27 28.734 ? Unidentified 0.056 0.056 0.053 17.614 28 29.192 691-38-3 C6 4-Methyl-c-pentene-2 0.048 0.053 0.048 12.495 29 29.415 107-83-5 I6 2-Methylpentane 1.825 2.082 1.787 461.124 30 29.842 674-76-0 C6 4-Methyl-t-pentene-2 0.137 0.152 0.138 35.495

31 32.065 96-14-0 I6 3-Methylpentane 1.194 1.339 1.169 301.639 32 33.229 763-29-1 C6 2-Methylpentene-1 0.234 0.254 0.234 60.522 33 33.453 592-41-6 K6 Hexene-1 0.167 0.183 0.167 43.147 34 35.642 760-21-4 C6 2-Ethylbutene-1 0.071 0.076 0.071 18.449 35 35.804 110-54-3 P6 n-Hexane 0.963 1.088 0.943 243.400 36 36.441 13269-52-8 K6 t-Hexene-3 0.274 0.299 0.274 70.847 37 36.916 4050-45-7 K6 t-Hexene-2 0.421 0.459 0.422 108.872 38 37.041 1120-62-3 B6 3-Methylcyclopentene 0.104 0.101 0.107 26.877 39 37.409 625-27-4 C6 2-Methylpentene-2 0.355 0.383 0.356 91.931 40 37.823 922-62-3 C6 3-Methyl-c-pentene-2 0.274 0.293 0.275 71.033

41 38.745 7688-21-3 K6 c-Hexene-2 0.222 0.239 0.223 57.500 42 40.088 3404-73-7 C7 3,3-Dimethylpentene-1 0.322 0.342 0.277 83.413 43 40.669 96-37-7 M6 Methylcyclopentane 0.891 0.887 0.893 230.581

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.235 108-08-7 I7 2,4-Dimethylpentane 1.014 1.123 0.854 257.280 45 42.536 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.753 46 42.782 464-06-2 I7 2,2,3-Trimethylbutane 0.067 0.073 0.057 17.116 47 45.429 1528-30-9 E7 C6-Diolefin-1 0.016 0.016 0.016 4.066 48 45.638 71-42-3 Q6 Benzene 0.720 0.610 0.778 200.638 49 45.835 693-89-0 B6 1-Methylcyclopentene 0.374 0.357 0.384 99.075 50 46.641 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.014 4.230 51 47.232 3524-73-0 C7 5-Methylhexene-1 0.030 0.032 0.025 7.664 52 47.554 110-82-7 M6 Cyclohexane 0.216 0.207 0.217 56.017 53 48.061 71-36-3 X4 n-Butanol 0.058 0.054 0.066 11.331

54 49.275 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.036 10.725 55 49.625 3769-23-1 C7 4-Methylhexene-1 0.012 0.013 0.010 3.119 56 50.270 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.052 0.055 0.045 13.559 57 50.674 591-76-4 I7 2-Methylhexane 1.123 1.233 0.946 284.818 58 51.155 110-83-8 B6 Cyclohexene 0.046 0.042 0.047 11.959 59 52.494 589-34-4 I7 3-Methylhexane 0.364 0.395 0.307 92.357 60 53.356 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.101 0.100 0.086 26.025 61 53.942 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.068 0.068 0.058 17.525 62 54.568 822-50-4 M7 1t,2-Dimethylcyclopentane 0.066 0.065 0.057 17.051 63 54.881 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.020 6.017

64 55.204 540-84-1 I8 2,2,4-Trimethylpentane 7.529 8.108 5.563 1913.792 65 55.476 592-76-7 K7 Heptene-1 0.030 0.032 0.025 7.655 66 56.806 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.690 67 57.335 14686-14-7 K7 t-Heptene-3 0.033 0.035 0.028 8.520 68 57.686 6094-02-6 C7 2-Methylhexene-1 0.059 0.063 0.051 15.271 69 58.056 142-82-5 P7 n-Heptane 0.112 0.122 0.094 28.296 70 58.277 7642-10-6 K7 c-Heptene-3 0.026 0.028 0.022 6.743 71 58.550 2738-19-4 C7 2-Methyl-2-hexene 0.027 0.028 0.023 6.901 72 58.795 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.021 0.017 5.247 73 59.178 14686-13-6 K7 t-Heptene-2 0.012 0.013 0.010 3.158

74 59.653 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.019 0.018 0.016 4.821 75 60.078 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.013 3.970 76 60.862 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 3.439 77 61.506 108-87-2 M7 Methylcyclohexane 0.052 0.050 0.044 13.334 78 63.373 ? Unidentified 0.044 0.046 0.034 14.036 79 64.954 564-02-3 I8 2,2,3-Trimethylpentane 0.564 0.587 0.417 143.318 80 65.183 592-13-2 I8 2,5-Dimethylhexane 1.172 1.260 0.866 298.008 81 65.522 589-43-5 I8 2,4-Dimethylhexane 1.022 1.087 0.755 259.674 82 68.511 565-75-3 I8 2,3,4-Trimethylpentane 4.452 4.613 3.289 1131.566 83 69.030 108-88-3 Q7 Toluene 5.106 4.388 4.676 1407.813

84 69.192 560-21-4 I8 2,3,3-Trimethylpentane 5.238 5.374 3.870 1331.407 85 70.802 584-94-1 I8 2,3-Dimethylhexane 1.110 1.161 0.820 282.159 86 72.047 592-27-8 I8 2-Methylheptane 0.057 0.061 0.042 14.536

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 72.320 589-53-7 I8 4-Methylheptane 0.122 0.129 0.090 31.045 88 72.451 ? Unidentified 0.090 0.093 0.066 28.487 89 73.362 589-81-1 I8 3-Methylheptane 0.051 0.053 0.037 12.876 90 75.263 3522-94-9 I9 2,2,5-Trimethylhexane 2.047 2.156 1.347 521.317 91 76.237 ? Unidentified 0.015 0.015 0.012 4.900 92 77.870 111-65-9 P8 n-Octane 0.026 0.028 0.020 6.728 93 78.822 ? Unidentified 0.045 0.044 0.034 14.354 94 80.354 1069-53-0 I9 2,3,5-Trimethylhexane 0.319 0.329 0.210 81.284 95 81.520 1071-26-7 I9 2,4-Dimethylheptane 0.043 0.045 0.028 11.027 96 82.166 1678-91-7 M8 Ethylcyclohexane 0.014 0.013 0.010 3.605

97 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.057 0.060 0.037 14.420 98 83.407 I9 2,5-Dimethylheptane 0.138 0.143 0.091 35.048 99 84.730 100-41-4 Q8 Ethylbenzene 0.898 0.771 0.714 245.642 100 84.900 ? Unidentified 0.021 0.021 0.014 6.649 101 85.146 ? Unidentified 0.022 0.021 0.015 6.955 102 85.951 108-38-3 Q8 m-Xylene 2.242 1.932 1.782 613.395 103 86.099 106-42-3 Q8 p-Xylene 1.019 0.881 0.810 278.756 104 86.231 ? Unidentified 0.044 0.045 0.029 13.865 105 86.489 C8 C9-IsoOlefin-3 0.010 0.010 0.007 2.627 106 86.597 ? Unidentified 0.009 0.009 0.006 2.721

107 87.274 2216-34-4 I9 4-Methyloctane 0.017 0.017 0.011 4.248 108 87.406 3221-61-2 I9 2-Methyloctane 0.024 0.025 0.016 6.186 109 88.269 2216-33-3 I9 3-Methyloctane 0.027 0.028 0.018 6.814 110 88.745 ? Unidentified 0.102 0.111 0.068 32.383 111 88.927 95-47-6 Q8 o-Xylene 0.722 0.611 0.574 197.643 112 89.323 I10 C10 - IsoParaffin - 1 0.333 0.341 0.197 84.964 113 89.911 M9 trans-1,3-Diethylcyclopentane 0.013 0.011 0.009 3.649 114 90.166 14720-74-2 I10 2,2,4-trimethylheptane 0.238 0.244 0.141 60.744 115 91.726 111-84-2 P9 n-Nonane 0.279 0.290 0.184 71.166 116 92.334 4926-90-3 M9 1,1-Methylethylcyclohexane 0.025 0.023 0.016 6.368

117 93.094 98-82-8 Q9 i-Propylbenzene 0.029 0.025 0.020 7.776 118 93.273 ? Unidentified 0.012 0.012 0.008 3.868 119 93.273 ? Unidentified 0.012 0.013 0.007 3.868 120 93.273 ? Unidentified 0.012 0.009 0.007 3.868 121 93.385 696-29-7 M9 1-Methyl-2-propyl-cyclopentan 0.005 0.005 0.003 1.355 122 93.385 C10 C10-IsoOlefin-4 0.005 0.006 0.003 1.355 123 93.385 I10 C10-isoparaffin-x 0.000 0.000 0.000 1.355 124 93.842 ? Unidentified 0.173 0.178 0.103 54.945 125 94.063 15869-87-1 I10 2,2-Dimethyloctane 0.074 0.076 0.044 18.961 126 94.525 ? Unidentified 0.019 0.014 1.612 6.055

127 94.525 ? Unidentified 0.019 0.020 0.011 6.055 128 94.724 ? Unidentified 0.023 0.021 0.015 7.282 129 94.863 15869-89-3 I10 2,5-Dimethyloctane 0.108 0.110 0.064 27.484

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 95.068 I10 C10 - IsoParaffin - 2 0.019 0.019 0.011 4.821 131 95.331 2040-95-1 I10 2,7-Dimethyloctane 0.061 0.062 0.036 15.533 132 95.508 2051-30-1 I10 2,4-Dimethyloctane 0.232 0.238 0.138 59.220 133 95.894 I10 2,6-Dimethyloctane 0.092 0.094 0.055 23.570 134 96.061 I10 C10 Isoparaffin -1 0.010 0.010 0.006 2.525 135 96.351 ? Unidentified 0.008 0.008 0.005 2.424 136 96.555 103-65-1 Q9 n-Propylbenzene 0.295 0.255 0.207 80.142 137 96.752 I10 3-Methyl-5-ethylheptane 0.009 0.009 0.005 2.338 138 97.400 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.996 0.858 0.699 270.675 139 97.634 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.456 0.395 0.321 124.111

140 98.259 108-67-8 Q9 1,3,5-Trimethylbenzene 0.672 0.579 0.472 182.761 141 98.724 15869-85-9 I10 5-Methylnonane 0.031 0.032 0.018 7.957 142 98.914 17301-94-8 I10 4-Methylnonane 0.066 0.067 0.039 16.814 143 99.135 I10 2,2,6-Trimethyloctane 3.660 3.754 2.171 934.022 144 99.345 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.361 0.305 0.253 98.153 145 99.564 5881-17-4 I10 3-Ethyloctane 0.009 0.009 0.005 2.360 146 99.707 ? Unidentified 0.012 0.012 0.007 3.720 147 99.888 5911-04-6 I10 3-Methylnonane 0.071 0.072 0.042 18.184 148 100.068 ? Unidentified 0.017 0.018 0.010 5.267 149 100.354 ? Unidentified 0.215 0.160 0.116 68.306

150 100.488 ? Unidentified 0.577 0.578 0.312 183.068 151 100.702 I11 C11-Isoparaffin-2 0.311 0.311 0.168 79.444 152 100.979 95-63-6 Q9 1,2,4-Trimethylbenzene 1.910 1.625 1.341 519.303 153 101.168 ? Unidentified 0.358 0.380 0.215 113.423 154 101.290 ? Unidentified 0.209 0.213 0.124 66.388 155 101.550 1678-98-4 M10 i-Butylcyclohexane 0.065 0.061 0.039 16.878 156 102.195 ? Unidentified 0.023 0.021 0.014 7.253 157 102.339 17302-01-1 I10 3-Ethyl-3-methylheptane 0.489 0.489 0.264 124.873 158 102.546 ? Unidentified 0.123 0.108 0.077 39.065 159 102.688 ? Unidentified 0.281 0.281 0.152 89.115

160 102.805 124-18-5 P10 n-Decane 0.303 0.309 0.180 77.288 161 103.199 ? Unidentified 0.122 0.122 0.066 38.704 162 103.687 ? Unidentified 0.018 0.015 0.013 5.691 163 103.853 526-73-8 Q9 1,2,3-Trimethylbenzene 0.342 0.285 0.240 92.961 164 104.195 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.045 0.039 0.028 12.146 165 104.412 I11 C11 Isoparaffin-4 0.070 0.070 0.038 17.967 166 104.618 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.347 0.302 0.218 93.954 167 105.048 J9 Indan 0.223 0.172 0.159 61.520 168 105.262 I11 C11-Isoparaffin-5 0.048 0.048 0.026 12.185 169 105.649 J10 Indene 1.481 1.145 1.058 409.309

170 106.064 M10 n-ButylCyclohexane 0.011 0.010 0.007 2.821 171 106.204 ? Unidentified 0.010 0.009 0.006 3.057 172 106.361 I11 C11-Isoparaffin-7 0.537 0.538 0.290 137.170

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 106.549 141-93-5 Q10 1,3-Diethylbenzene 0.043 0.037 0.027 11.639 174 106.843 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 1.575 1.363 0.991 426.067 175 107.104 ? Unidentified 0.345 0.298 0.217 109.291 176 107.384 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.120 0.101 0.075 32.393 177 107.619 135-01-3 Q10 1,2-Diethylbenzene 0.115 0.098 0.072 31.144 178 107.898 I11 C11-Isoparaffin-8 0.010 0.010 0.005 2.564 179 108.082 ? Unidentified 0.120 0.120 0.065 37.905 180 108.237 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.051 0.044 0.032 13.838 181 108.354 ? Unidentified 0.135 0.135 0.073 42.788 182 108.436 ? Unidentified 0.106 0.107 0.057 33.726

183 108.566 I11 C11- Isoparaffin-11 0.867 0.869 0.468 221.590 184 108.745 ? Unidentified 0.268 0.268 0.145 84.927 185 108.896 I11 C11- IsoParaffin - 13 0.024 0.025 0.013 6.250 186 109.169 ? Unidentified 0.773 0.657 0.486 245.109 187 109.398 J10 2-Methylindan 0.134 0.104 0.086 37.045 188 109.741 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.288 0.245 0.181 77.768 189 109.868 ? Unidentified 0.036 0.030 0.022 11.326 190 110.286 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.633 0.529 0.398 171.135 191 110.710 ? Unidentified 0.025 0.023 0.013 7.816 192 110.904 693-61-8 K11 2-Undecene, (E)- 0.054 0.054 0.032 13.734

193 111.039 ? Unidentified 0.120 0.121 0.072 38.197 194 111.309 ? Unidentified 0.110 0.096 0.063 34.817 195 111.410 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.062 0.052 0.039 16.741 196 111.698 1120-21-4 P11 n-Undecane 0.124 0.124 0.067 31.591 197 111.861 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.087 0.073 0.050 23.484 198 111.972 ? Unidentified 0.059 0.049 0.033 18.652 199 112.347 Q10 1,2,4,5-Tetramethylbenzene 0.210 0.176 0.132 56.718 200 112.613 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.268 0.224 0.169 72.491 201 112.956 ? Unidentified 0.031 0.026 0.020 9.948 202 113.130 I12 C12 - IsoParaffin - 1 0.026 0.026 0.013 6.726

203 113.483 ? Unidentified 0.034 0.034 0.017 10.663 204 113.609 ? Unidentified 0.012 0.012 0.006 3.772 205 113.811 ? Unidentified 0.056 0.047 0.032 17.887 206 113.944 874-35-1 H10 5-Methylindan 0.089 0.075 0.057 24.087 207 114.069 Q12 1,2-Di-i-propylbenzene 0.033 0.028 0.017 8.818 208 114.284 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.048 0.040 0.028 13.018 209 114.462 Q11 C11 - Aromatic - 4 0.038 0.032 0.021 10.160 210 114.694 824-22-6 J10 4-Methylindan 0.105 0.088 0.067 28.525 211 114.848 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.033 0.028 0.019 8.868 212 114.941 824-63-5 H10 2-Methylindan 0.084 0.070 0.053 22.604

213 115.144 ? Unidentified 0.011 0.009 0.006 3.591 214 115.256 538-68-1 Q11 n-Pentylbenzene 0.015 0.012 0.008 3.959 215 115.485 Q11 tert-Pentylbenzene 0.049 0.041 0.028 13.280

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.020 0.017 0.011 5.358 217 115.911 Q11 C11 - Aromatic - 7 0.033 0.029 0.019 8.977 218 116.090 ? Unidentified 0.005 0.005 0.003 1.663 219 116.245 I12 C12 - IsoParaffin - 4 0.008 0.008 0.004 2.181 220 116.368 100-18-5 Q12 1,4-Di-i-propylbenzene 0.038 0.032 0.020 10.112 221 116.809 91-20-3 G10 Naphthalene 0.117 0.085 0.077 33.249 222 116.942 ? Unidentified 0.018 0.018 0.009 5.791 223 117.124 ? Unidentified 0.006 0.004 0.003 1.756 224 117.247 J11 1,1-Dimethyl Indane 0.011 0.009 0.007 3.176 225 117.410 J12 Dimethyl Indane - 1 0.006 0.005 0.004 1.731

226 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.010 0.008 0.005 2.586 227 117.893 Q12 1,3-Di-n-propylbenzene 0.038 0.032 0.020 10.157 228 118.004 Q11 C11 - Aromatic - 11 0.021 0.018 0.012 5.675 229 118.409 112-40-3 P12 n-Dodecane 0.005 0.005 0.003 1.356 230 118.558 Q11 C11 - Aromatic - 12 0.019 0.016 0.011 5.033 231 122.671 877-44-1 Q12 1,2,4-Triethylbenzene 0.007 0.006 0.004 1.884 232 123.441 91-57-6 G11 2-Methylnaphthalene 0.013 0.009 0.008 3.636 233 124.307 90-12-0 G11 1-Methylnaphthalene 0.006 0.004 0.003 1.644 234 126.296 ? Unidentified 0.009 0.009 0.004 2.982 235 127.262 ? Unidentified 0.003 0.002 0.002 0.932

236 130.003 ? Unidentified 0.003 0.003 0.002 1.043

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 10.020 106-97-8 n-Butane 1.395 1.796 2.025 348.622

18.110 109-66-0 n-Pentane 0.876 1.042 1.025 220.468 35.804 110-54-3 n-Hexane 0.963 1.088 0.943 243.400 58.056 142-82-5 n-Heptane 0.112 0.122 0.094 28.296 77.870 111-65-9 n-Octane 0.026 0.028 0.020 6.728 91.726 111-84-2 n-Nonane 0.279 0.290 0.184 71.166 102.805 124-18-5 n-Decane 0.303 0.309 0.180 77.288 111.698 1120-21-4 n-Undecane 0.124 0.124 0.067 31.591 118.409 112-40-3 n-Dodecane 0.005 0.005 0.003 1.356

I-Paraffins 8.806 75-28-5 i-Butane 0.021 0.028 0.031 5.320

10.634 463-82-1 2,2-Dimethylpropane 0.016 0.020 0.018 3.956 15.074 78-78-4 i-Pentane 4.266 5.130 4.990 1073.609 23.105 75-83-2 2,2-Dimethylbutane 0.029 0.033 0.028 7.201 28.339 79-29-8 2,3-Dimethylbutane 1.335 1.504 1.308 337.344 29.415 107-83-5 2-Methylpentane 1.825 2.082 1.787 461.124 32.065 96-14-0 3-Methylpentane 1.194 1.339 1.169 301.639 42.235 108-08-7 2,4-Dimethylpentane 1.014 1.123 0.854 257.280 42.782 464-06-2 2,2,3-Trimethylbutane 0.067 0.073 0.057 17.116 50.674 591-76-4 2-Methylhexane 1.123 1.233 0.946 284.818 52.494 589-34-4 3-Methylhexane 0.364 0.395 0.307 92.357 55.204 540-84-1 2,2,4-Trimethylpentane 7.529 8.108 5.563 1913.792 64.954 564-02-3 2,2,3-Trimethylpentane 0.564 0.587 0.417 143.318 65.183 592-13-2 2,5-Dimethylhexane 1.172 1.260 0.866 298.008 65.522 589-43-5 2,4-Dimethylhexane 1.022 1.087 0.755 259.674 68.511 565-75-3 2,3,4-Trimethylpentane 4.452 4.613 3.289 1131.566 69.192 560-21-4 2,3,3-Trimethylpentane 5.238 5.374 3.870 1331.407 70.802 584-94-1 2,3-Dimethylhexane 1.110 1.161 0.820 282.159 72.047 592-27-8 2-Methylheptane 0.057 0.061 0.042 14.536 72.320 589-53-7 4-Methylheptane 0.122 0.129 0.090 31.045 73.362 589-81-1 3-Methylheptane 0.051 0.053 0.037 12.876 75.263 3522-94-9 2,2,5-Trimethylhexane 2.047 2.156 1.347 521.317 80.354 1069-53-0 2,3,5-Trimethylhexane 0.319 0.329 0.210 81.284 81.520 1071-26-7 2,4-Dimethylheptane 0.043 0.045 0.028 11.027 82.476 1072-05-5 2,6-Dimethylheptane 0.057 0.060 0.037 14.420 83.407 2,5-Dimethylheptane 0.138 0.143 0.091 35.048 87.274 2216-34-4 4-Methyloctane 0.017 0.017 0.011 4.248 87.406 3221-61-2 2-Methyloctane 0.024 0.025 0.016 6.186 88.269 2216-33-3 3-Methyloctane 0.027 0.028 0.018 6.814 89.323 C10 - IsoParaffin - 1 0.333 0.341 0.197 84.964 90.166 14720-74-2 2,2,4-trimethylheptane 0.238 0.244 0.141 60.744 93.385 C10-isoparaffin-x 0.000 0.000 0.000 1.355 94.063 15869-87-1 2,2-Dimethyloctane 0.074 0.076 0.044 18.961 94.863 15869-89-3 2,5-Dimethyloctane 0.108 0.110 0.064 27.484 95.068 C10 - IsoParaffin - 2 0.019 0.019 0.011 4.821 95.331 2040-95-1 2,7-Dimethyloctane 0.061 0.062 0.036 15.533 95.508 2051-30-1 2,4-Dimethyloctane 0.232 0.238 0.138 59.220

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 95.894 2,6-Dimethyloctane 0.092 0.094 0.055 23.570

96.061 C10 Isoparaffin -1 0.010 0.010 0.006 2.525 96.752 3-Methyl-5-ethylheptane 0.009 0.009 0.005 2.338 98.724 15869-85-9 5-Methylnonane 0.031 0.032 0.018 7.957 98.914 17301-94-8 4-Methylnonane 0.066 0.067 0.039 16.814 99.135 2,2,6-Trimethyloctane 3.660 3.754 2.171 934.022 99.564 5881-17-4 3-Ethyloctane 0.009 0.009 0.005 2.360 99.888 5911-04-6 3-Methylnonane 0.071 0.072 0.042 18.184 100.702 C11-Isoparaffin-2 0.311 0.311 0.168 79.444 102.339 17302-01-1 3-Ethyl-3-methylheptane 0.489 0.489 0.264 124.873 104.412 C11 Isoparaffin-4 0.070 0.070 0.038 17.967 105.262 C11-Isoparaffin-5 0.048 0.048 0.026 12.185 106.361 C11-Isoparaffin-7 0.537 0.538 0.290 137.170 107.898 C11-Isoparaffin-8 0.010 0.010 0.005 2.564 108.566 C11- Isoparaffin-11 0.867 0.869 0.468 221.590 108.896 C11- IsoParaffin - 13 0.024 0.025 0.013 6.250 113.130 C12 - IsoParaffin - 1 0.026 0.026 0.013 6.726 116.245 C12 - IsoParaffin - 4 0.008 0.008 0.004 2.181

Aromatics Mono-Aromatics 45.638 71-42-3 Benzene 0.720 0.610 0.778 200.638

69.030 108-88-3 Toluene 5.106 4.388 4.676 1407.813 84.730 100-41-4 Ethylbenzene 0.898 0.771 0.714 245.642 85.951 108-38-3 m-Xylene 2.242 1.932 1.782 613.395 86.099 106-42-3 p-Xylene 1.019 0.881 0.810 278.756 88.927 95-47-6 o-Xylene 0.722 0.611 0.574 197.643 93.094 98-82-8 i-Propylbenzene 0.029 0.025 0.020 7.776 96.555 103-65-1 n-Propylbenzene 0.295 0.255 0.207 80.142 97.400 620-14-4 1-Methyl-3-ethylbenzene 0.996 0.858 0.699 270.675 97.634 622-96-8 1-Methyl-4-ethylbenzene 0.456 0.395 0.321 124.111 98.259 108-67-8 1,3,5-Trimethylbenzene 0.672 0.579 0.472 182.761 99.345 611-14-3 1-Methyl-2-ethylbenzene 0.361 0.305 0.253 98.153 100.979 95-63-6 1,2,4-Trimethylbenzene 1.910 1.625 1.341 519.303 103.853 526-73-8 1,2,3-Trimethylbenzene 0.342 0.285 0.240 92.961 104.195 535-77-3 1-Methyl-3-i-propylbenzene 0.045 0.039 0.028 12.146 104.618 99-87-6 1-Methyl-4-i-propylbenzene 0.347 0.302 0.218 93.954 106.549 141-93-5 1,3-Diethylbenzene 0.043 0.037 0.027 11.639 106.843 1074-43-7 1-Methyl-3-n-propylbenzene 1.575 1.363 0.991 426.067 107.384 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.120 0.101 0.075 32.393 107.619 135-01-3 1,2-Diethylbenzene 0.115 0.098 0.072 31.144 108.237 1074-17-5 1-Methyl-2-n-propylbenzene 0.051 0.044 0.032 13.838 109.741 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.288 0.245 0.181 77.768 110.286 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.633 0.529 0.398 171.135 111.410 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.062 0.052 0.039 16.741 111.861 4218-48-8 1-Ethyl-4-i-propylbenzene 0.087 0.073 0.050 23.484 112.347 1,2,4,5-Tetramethylbenzene 0.210 0.176 0.132 56.718 112.613 527-53-7 1,2,3,5-Tetramethylbenzene 0.268 0.224 0.169 72.491

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 114.069 1,2-Di-i-propylbenzene 0.033 0.028 0.017 8.818

114.284 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.048 0.040 0.028 13.018 114.462 C11 - Aromatic - 4 0.038 0.032 0.021 10.160 114.848 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.033 0.028 0.019 8.868 115.256 538-68-1 n-Pentylbenzene 0.015 0.012 0.008 3.959 115.485 tert-Pentylbenzene 0.049 0.041 0.028 13.280 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.020 0.017 0.011 5.358 115.911 C11 - Aromatic - 7 0.033 0.029 0.019 8.977 116.368 100-18-5 1,4-Di-i-propylbenzene 0.038 0.032 0.020 10.112 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.010 0.008 0.005 2.586 117.893 1,3-Di-n-propylbenzene 0.038 0.032 0.020 10.157 118.004 C11 - Aromatic - 11 0.021 0.018 0.012 5.675 118.558 C11 - Aromatic - 12 0.019 0.016 0.011 5.033 122.671 877-44-1 1,2,4-Triethylbenzene 0.007 0.006 0.004 1.884

Naphthalenes 116.809 91-20-3 Naphthalene 0.117 0.085 0.077 33.249

123.441 91-57-6 2-Methylnaphthalene 0.013 0.009 0.008 3.636 124.307 90-12-0 1-Methylnaphthalene 0.006 0.004 0.003 1.644

Naphtheno/Olefino-Benzs

113.944 874-35-1 5-Methylindan 0.089 0.075 0.057 24.087 114.941 824-63-5 2-Methylindan 0.084 0.070 0.053 22.604

Indenes 105.048 Indan 0.223 0.172 0.159 61.520

105.649 Indene 1.481 1.145 1.058 409.309 109.398 2-Methylindan 0.134 0.104 0.086 37.045 114.694 824-22-6 4-Methylindan 0.105 0.088 0.067 28.525 117.247 1,1-Dimethyl Indane 0.011 0.009 0.007 3.176 117.410 Dimethyl Indane - 1 0.006 0.005 0.004 1.731

Naphthenes Mono-Naphthenes 27.606 287-92-3 Cyclopentane 0.099 0.098 0.119 25.503

40.669 96-37-7 Methylcyclopentane 0.891 0.887 0.893 230.581 47.554 110-82-7 Cyclohexane 0.216 0.207 0.217 56.017 53.356 1759-58-6 1t,3-Dimethylcyclopentane 0.101 0.100 0.086 26.025 53.942 2532-58-3 1c,3-Dimethylcyclopentane 0.068 0.068 0.058 17.525 54.568 822-50-4 1t,2-Dimethylcyclopentane 0.066 0.065 0.057 17.051 59.653 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.019 0.018 0.016 4.821 61.506 108-87-2 Methylcyclohexane 0.052 0.050 0.044 13.334 82.166 1678-91-7 Ethylcyclohexane 0.014 0.013 0.010 3.605 89.911 trans-1,3-Diethylcyclopentane 0.013 0.011 0.009 3.649 92.334 4926-90-3 1,1-Methylethylcyclohexane 0.025 0.023 0.016 6.368 93.385 696-29-7 1-Methyl-2-propyl-cyclopentan 0.005 0.005 0.003 1.355 101.550 1678-98-4 i-Butylcyclohexane 0.065 0.061 0.039 16.878 106.064 n-ButylCyclohexane 0.011 0.010 0.007 2.821

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.619 115-11-7 Isobutene 0.017 0.022 0.026 4.527

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 9.661 106-98-9 Butene-1 0.019 0.024 0.029 5.030

10.506 624-64-6 t-Butene-2 0.079 0.097 0.119 20.405 11.247 590-18-1 c-Butene-2 0.093 0.112 0.140 24.087 16.726 109-67-1 Pentene-1 0.355 0.413 0.427 91.857 19.230 646-04-8 t-Pentene-2 0.898 1.032 1.081 232.434 20.264 627-20-3 c-Pentene-2 0.492 0.559 0.592 127.403 33.453 592-41-6 Hexene-1 0.167 0.183 0.167 43.147 36.441 13269-52-8 t-Hexene-3 0.274 0.299 0.274 70.847 36.916 4050-45-7 t-Hexene-2 0.421 0.459 0.422 108.872 38.745 7688-21-3 c-Hexene-2 0.222 0.239 0.223 57.500 55.476 592-76-7 Heptene-1 0.030 0.032 0.025 7.655 57.335 14686-14-7 t-Heptene-3 0.033 0.035 0.028 8.520 58.277 7642-10-6 c-Heptene-3 0.026 0.028 0.022 6.743 59.178 14686-13-6 t-Heptene-2 0.012 0.013 0.010 3.158 110.904 693-61-8 2-Undecene, (E)- 0.054 0.054 0.032 13.734

Iso-Olefins 13.448 563-45-1 3-Methylbutene-1 0.205 0.244 0.247 53.090

17.578 563-46-2 2-Methylbutene-1 0.538 0.617 0.648 139.330 20.942 513-35-9 2-Methylbutene-2 1.101 1.239 1.325 285.046 29.192 691-38-3 4-Methyl-c-pentene-2 0.048 0.053 0.048 12.495 29.842 674-76-0 4-Methyl-t-pentene-2 0.137 0.152 0.138 35.495 33.229 763-29-1 2-Methylpentene-1 0.234 0.254 0.234 60.522 35.642 760-21-4 2-Ethylbutene-1 0.071 0.076 0.071 18.449 37.409 625-27-4 2-Methylpentene-2 0.355 0.383 0.356 91.931 37.823 922-62-3 3-Methyl-c-pentene-2 0.274 0.293 0.275 71.033 40.088 3404-73-7 3,3-Dimethylpentene-1 0.322 0.342 0.277 83.413 42.536 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 3.753 46.641 3404-61-3 3-Methylhexene-1 0.016 0.017 0.014 4.230 47.232 3524-73-0 5-Methylhexene-1 0.030 0.032 0.025 7.664 49.275 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.036 10.725 49.625 3769-23-1 4-Methylhexene-1 0.012 0.013 0.010 3.119 50.270 3404-55-5 4-Methyl-t/c-hexene-2 0.052 0.055 0.045 13.559 54.881 C7 - Iso-Olefin - 2 0.023 0.024 0.020 6.017 56.806 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.690 57.686 6094-02-6 2-Methylhexene-1 0.059 0.063 0.051 15.271 58.550 2738-19-4 2-Methyl-2-hexene 0.027 0.028 0.023 6.901 58.795 10574-36-4 3-Methyl-c-hexene-2 0.020 0.021 0.017 5.247 60.078 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.013 3.970 60.862 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.011 3.439 86.489 C9-IsoOlefin-3 0.010 0.010 0.007 2.627 93.385 C10-IsoOlefin-4 0.005 0.006 0.003 1.355

Naphtheno-Olefins 22.532 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.009 1.969

25.738 142-29-0 Cyclopentene 0.208 0.201 0.258 55.399 37.041 1120-62-3 3-Methylcyclopentene 0.104 0.101 0.107 26.877 45.835 693-89-0 1-Methylcyclopentene 0.374 0.357 0.384 99.075 51.155 110-83-8 Cyclohexene 0.046 0.042 0.047 11.959

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphtheno-Olefins Di-Olefins 18.624 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.014 2.981

21.266 2004-70-8 1t,3-Pentadiene 0.016 0.018 0.020 4.394 45.429 1528-30-9 C6-Diolefin-1 0.016 0.016 0.016 4.066

Oxygenates 13.087 64-17-5 Ethanol 16.550 15.628 30.318 1763.987

26.901 71-23-8 n-Propanol 0.079 0.074 0.111 14.373 48.061 71-36-3 n-Butanol 0.058 0.054 0.066 11.331

Unidentified 19.876 Unidentified 0.006 0.007 0.007 1.963

26.992 Unidentified 0.062 0.069 0.062 19.690 28.734 Unidentified 0.056 0.056 0.053 17.614 63.373 Unidentified 0.044 0.046 0.034 14.036 72.451 Unidentified 0.090 0.093 0.066 28.487 76.237 Unidentified 0.015 0.015 0.012 4.900 78.822 Unidentified 0.045 0.044 0.034 14.354 84.900 Unidentified 0.021 0.021 0.014 6.649 85.146 Unidentified 0.022 0.021 0.015 6.955 86.231 Unidentified 0.044 0.045 0.029 13.865 86.597 Unidentified 0.009 0.009 0.006 2.721 88.745 Unidentified 0.102 0.111 0.068 32.383 93.273 Unidentified 0.012 0.012 0.008 3.868 93.273 Unidentified 0.012 0.013 0.007 3.868 93.273 Unidentified 0.012 0.009 0.007 3.868 93.842 Unidentified 0.173 0.178 0.103 54.945 94.525 Unidentified 0.019 0.014 1.612 6.055 94.525 Unidentified 0.019 0.020 0.011 6.055 94.724 Unidentified 0.023 0.021 0.015 7.282 96.351 Unidentified 0.008 0.008 0.005 2.424 99.707 Unidentified 0.012 0.012 0.007 3.720 100.068 Unidentified 0.017 0.018 0.010 5.267 100.354 Unidentified 0.215 0.160 0.116 68.306 100.488 Unidentified 0.577 0.578 0.312 183.068 101.168 Unidentified 0.358 0.380 0.215 113.423 101.290 Unidentified 0.209 0.213 0.124 66.388 102.195 Unidentified 0.023 0.021 0.014 7.253 102.546 Unidentified 0.123 0.108 0.077 39.065 102.688 Unidentified 0.281 0.281 0.152 89.115 103.199 Unidentified 0.122 0.122 0.066 38.704 103.687 Unidentified 0.018 0.015 0.013 5.691 106.204 Unidentified 0.010 0.009 0.006 3.057 107.104 Unidentified 0.345 0.298 0.217 109.291 108.082 Unidentified 0.120 0.120 0.065 37.905 108.354 Unidentified 0.135 0.135 0.073 42.788 108.436 Unidentified 0.106 0.107 0.057 33.726 108.745 Unidentified 0.268 0.268 0.145 84.927 109.169 Unidentified 0.773 0.657 0.486 245.109

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 109.868 Unidentified 0.036 0.030 0.022 11.326

110.710 Unidentified 0.025 0.023 0.013 7.816 111.039 Unidentified 0.120 0.121 0.072 38.197 111.309 Unidentified 0.110 0.096 0.063 34.817 111.972 Unidentified 0.059 0.049 0.033 18.652 112.956 Unidentified 0.031 0.026 0.020 9.948 113.483 Unidentified 0.034 0.034 0.017 10.663 113.609 Unidentified 0.012 0.012 0.006 3.772 113.811 Unidentified 0.056 0.047 0.032 17.887 115.144 Unidentified 0.011 0.009 0.006 3.591 116.090 Unidentified 0.005 0.005 0.003 1.663 116.942 Unidentified 0.018 0.018 0.009 5.791 117.124 Unidentified 0.006 0.004 0.003 1.756 126.296 Unidentified 0.009 0.009 0.004 2.982 127.262 Unidentified 0.003 0.002 0.002 0.932 130.003 Unidentified 0.003 0.003 0.002 1.043

Plus

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

2,2,3-Trimethylpentane

2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified

3-Methylheptane

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene Unidentified C9-IsoOlefin-3 Unidentified 4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane 1,1-Methylethylcyclohexane
i-Propylbenzene Unidentified 1-Methyl-2-propyl-cyclopentan/C10-IsoOlefin-4/C10-isoparaffin-x Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane C10 - IsoParaffin - 2 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane C10 Isoparaffin -1 Unidentified n-Propylbenzene 3-Methyl-5-ethylheptane 1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Ethyloctane Unidentified 3-Methylnonane

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified

Unidentified

Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified Unidentified i-Butylcyclohexane
Unidentified

3-Ethyl-3-methylheptane Unidentified Unidentified n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan C11-Isoparaffin-5 Indene n-ButylCyclohexane Unidentified C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene Unidentified 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene C11-Isoparaffin-8 Unidentified 1-Methyl-2-n-propylbenzene Unidentified C11- Isoparaffin-11 Unidentified C11- IsoParaffin - 13

Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene Unidentified 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 Unidentified C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 n-Dodecane C11 - Aromatic - 12

1,2,4-Triethylbenzene
2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 18:24:02 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF Sample: ODDB-91331 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91331 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000013.D\SIG2000013_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

Unidentified

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 4.593 5.646 5.278

I-Paraffins 28.265 31.378 22.549

Aromatics 40.492 35.745 32.614 Mono-Aromatics 39.596 35.016 32.025 Naphthalenes 0.141 0.105 0.090 Naphtheno/Olefino-Benzs 0.207 0.178 0.130 Indenes 0.549 0.446 0.369

Naphthenes 1.856 1.885 1.807 Mono-Naphthenes 1.856 1.885 1.807 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.240 8.217 7.872 n-Olefins 3.005 3.497 3.371 Iso-Olefins 3.491 3.979 3.701 Naphtheno-Olefins 0.703 0.695 0.753 Di-Olefins 0.041 0.045 0.047

Oxygenates 16.089 15.652 28.934

Unidentified 1.465 1.477 0.946

Plus 0.000 0.000 0.000

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 15.958 15.526 28.767 C3 0.076 0.073 0.106 C4 1.974 2.586 2.814 C5 7.736 9.294 9.038 C6 10.273 11.364 10.073 C7 18.347 16.895 16.346 C8 30.682 30.120 23.155 C9 8.701 8.307 5.872 C10 3.813 3.452 2.354 C11 0.809 0.761 0.444 C12 0.165 0.143 0.084

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 1.703 2.259 2.433 C5 0.821 1.007 0.945 C6 1.709 1.990 1.647 C7 0.120 0.135 0.100 C8 0.021 0.023 0.015 C9 0.177 0.189 0.115 C10 0.016 0.017 0.009 C11 0.025 0.026 0.013

I-Paraffins C4 0.018 0.025 0.026 C5 3.155 3.909 3.631 C6 3.831 4.467 3.692 C7 1.733 1.960 1.436 C8 15.266 16.448 11.099 C9 3.087 3.339 1.999 C10 0.843 0.888 0.490 C11 0.322 0.332 0.171 C12 0.010 0.010 0.005

Mono-Aromatics C6 0.685 0.598 0.728 C7 15.435 13.667 13.912 C8 15.380 13.636 12.031 C9 5.317 4.683 3.674 C10 2.219 1.944 1.373 C11 0.413 0.360 0.231 C12 0.148 0.127 0.076

Naphthalenes C10 0.124 0.093 0.081 C11 0.016 0.012 0.009

Naphtheno/Olefino-Benzs C10 0.207 0.178 0.130

Indenes C9 0.120 0.096 0.084 C10 0.404 0.331 0.271 C11 0.018 0.014 0.010 C12 0.007 0.006 0.004

Mono-Naphthenes C5 0.093 0.096 0.111 C6 1.456 1.477 1.437 C7 0.306 0.313 0.259

n-Olefins C4 0.199 0.250 0.294

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C5 1.659 1.964 1.965 C6 1.033 1.160 1.020 C7 0.098 0.107 0.083 C11 0.015 0.016 0.009

Iso-Olefins C5 1.777 2.085 2.104 C6 1.060 1.182 1.046 C7 0.640 0.698 0.541 C8 0.014 0.014 0.009

Naphtheno-Olefins C5 0.205 0.204 0.250 C6 0.498 0.491 0.504

Di-Olefins C5 0.026 0.030 0.032 C7 0.015 0.015 0.015

Oxygenates C2 15.958 15.526 28.767 C3 0.076 0.073 0.106 C4 0.055 0.053 0.061

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 23.40 22.65 5% 81.59 80.51 10% 133.56 97.90 15% 153.07 140.21 20% 172.26 155.11 25% 172.60 172.38 30% 172.94 172.72 35% 173.28 173.07 40% 209.60 183.48 45% 229.89 210.36 50% 230.30 230.02 55% 230.71 230.48 60% 231.64 230.95 65% 236.93 235.22 70% 246.00 238.21 75% 276.56 254.85 80% 281.23 279.18 85% 282.10 281.80 90% 320.72 301.96 95% 341.62 336.07 FBP 403.54 399.00

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.809 75-28-5 I4 i-Butane 0.018 0.025 0.026 5.016 2 9.622 115-11-7 K4 Isobutene 0.017 0.021 0.025 4.824 3 9.663 106-98-9 K4 Butene-1 0.018 0.024 0.027 5.339 4 10.022 106-97-8 P4 n-Butane 1.703 2.259 2.433 476.606 5 10.507 624-64-6 K4 t-Butene-2 0.075 0.096 0.111 21.798 6 10.635 463-82-1 I5 2,2-Dimethylpropane 0.008 0.010 0.009 2.207 7 11.249 590-18-1 K4 c-Butene-2 0.088 0.109 0.131 25.652 8 13.095 64-17-5 X2 Ethanol 15.958 15.526 28.767 1904.669 9 13.450 563-45-1 C5 3-Methylbutene-1 0.219 0.268 0.259 63.429 10 15.072 78-78-4 I5 i-Pentane 3.147 3.899 3.622 886.785

11 16.725 109-67-1 K5 Pentene-1 0.337 0.404 0.400 97.817 12 17.577 563-46-2 C5 2-Methylbutene-1 0.512 0.604 0.606 148.347 13 18.109 109-66-0 P5 n-Pentane 0.821 1.007 0.945 231.436 14 18.624 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 3.169 15 19.230 646-04-8 K5 t-Pentene-2 0.854 1.011 1.011 247.513 16 19.875 ? Unidentified 0.006 0.007 0.007 2.072 17 20.263 627-20-3 K5 c-Pentene-2 0.468 0.548 0.554 135.641 18 20.940 513-35-9 C5 2-Methylbutene-2 1.046 1.213 1.239 303.329 19 21.266 2004-70-8 E5 1t,3-Pentadiene 0.016 0.018 0.019 4.692 20 22.531 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.009 2.115

21 23.100 75-83-2 I6 2,2-Dimethylbutane 0.028 0.033 0.027 7.928 22 25.738 142-29-0 B5 Cyclopentene 0.198 0.196 0.241 58.959 23 26.899 71-23-8 X3 n-Propanol 0.076 0.073 0.106 15.497 24 26.990 ? Unidentified 0.059 0.067 0.058 20.797 25 27.603 287-92-3 M5 Cyclopentane 0.093 0.096 0.111 27.060 26 28.334 79-29-8 I6 2,3-Dimethylbutane 0.704 0.817 0.678 199.158 27 28.732 ? Unidentified 0.053 0.055 0.050 18.695 28 29.190 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.052 0.045 13.302 29 29.413 107-83-5 I6 2-Methylpentane 1.771 2.082 1.707 501.176 30 29.840 674-76-0 C6 4-Methyl-t-pentene-2 0.130 0.148 0.129 37.750

31 32.064 96-14-0 I6 3-Methylpentane 1.328 1.535 1.280 375.725 32 33.226 763-29-1 C6 2-Methylpentene-1 0.222 0.249 0.219 64.428 33 33.449 592-41-6 K6 Hexene-1 0.162 0.184 0.160 47.021 34 35.642 760-21-4 C6 2-Ethylbutene-1 0.063 0.070 0.062 18.264 35 35.807 110-54-3 P6 n-Hexane 1.709 1.990 1.647 483.546 36 36.437 13269-52-8 K6 t-Hexene-3 0.260 0.293 0.257 75.488 37 36.913 4050-45-7 K6 t-Hexene-2 0.399 0.449 0.394 115.739 38 37.039 1120-62-3 B6 3-Methylcyclopentene 0.099 0.100 0.101 28.830 39 37.407 625-27-4 C6 2-Methylpentene-2 0.338 0.375 0.333 97.894 40 37.820 922-62-3 C6 3-Methyl-c-pentene-2 0.261 0.287 0.257 75.630

41 38.741 7688-21-3 K6 c-Hexene-2 0.211 0.234 0.209 61.253 42 40.086 3404-73-7 C7 3,3-Dimethylpentene-1 0.307 0.335 0.259 88.880 43 40.668 96-37-7 M6 Methylcyclopentane 1.035 1.061 1.021 299.897

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.230 108-08-7 I7 2,4-Dimethylpentane 0.524 0.598 0.434 148.880 45 42.531 594-56-9 C7 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 4.048 46 42.780 464-06-2 I7 2,2,3-Trimethylbutane 0.040 0.045 0.033 11.375 47 45.424 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.015 4.336 48 45.635 71-42-3 Q6 Benzene 0.685 0.598 0.728 213.697 49 45.832 693-89-0 B6 1-Methylcyclopentene 0.355 0.349 0.359 105.295 50 46.637 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.013 4.523 51 47.227 3524-73-0 C7 5-Methylhexene-1 0.037 0.041 0.031 10.776 52 47.550 110-82-7 M6 Cyclohexane 0.422 0.416 0.416 122.239 53 48.057 71-36-3 X4 n-Butanol 0.055 0.053 0.061 12.019

54 49.271 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.044 0.034 11.593 55 49.616 3769-23-1 C7 4-Methylhexene-1 0.012 0.013 0.010 3.344 56 50.264 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.054 0.042 14.460 57 50.663 591-76-4 I7 2-Methylhexane 0.805 0.911 0.667 228.761 58 51.151 110-83-8 B6 Cyclohexene 0.044 0.042 0.044 12.745 59 52.490 589-34-4 I7 3-Methylhexane 0.364 0.406 0.301 103.273 60 53.349 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.100 0.102 0.084 28.855 61 53.936 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.067 0.069 0.057 19.418 62 54.563 822-50-4 M7 1t,2-Dimethylcyclopentane 0.068 0.069 0.057 19.620 63 54.855 C7 C7 - Iso-Olefin - 2 0.022 0.024 0.019 6.500

64 55.165 540-84-1 I8 2,2,4-Trimethylpentane 2.988 3.315 2.172 850.410 65 55.470 592-76-7 K7 Heptene-1 0.028 0.031 0.024 8.182 66 56.801 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.947 67 57.330 14686-14-7 K7 t-Heptene-3 0.032 0.035 0.027 9.157 68 57.683 6094-02-6 C7 2-Methylhexene-1 0.056 0.062 0.048 16.309 69 58.052 142-82-5 P7 n-Heptane 0.120 0.135 0.100 34.163 70 58.272 7642-10-6 K7 c-Heptene-3 0.025 0.027 0.021 7.277 71 58.546 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.022 7.459 72 58.790 10574-36-4 C7 3-Methyl-c-hexene-2 0.020 0.021 0.017 5.684 73 59.173 14686-13-6 K7 t-Heptene-2 0.013 0.014 0.011 3.821

74 59.649 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 5.243 75 60.075 20710-38-8 C7 3-Methyl-t-hexene-2 0.015 0.016 0.013 4.288 76 60.857 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.646 77 61.504 108-87-2 M7 Methylcyclohexane 0.054 0.054 0.046 15.625 78 63.367 ? Unidentified 0.043 0.045 0.032 15.132 79 64.950 564-02-3 I8 2,2,3-Trimethylpentane 0.448 0.481 0.326 127.584 80 65.178 592-13-2 I8 2,5-Dimethylhexane 0.836 0.925 0.608 237.908 81 65.515 589-43-5 I8 2,4-Dimethylhexane 0.739 0.810 0.537 210.382 82 68.522 565-75-3 I8 2,3,4-Trimethylpentane 4.183 4.466 3.041 1190.681 83 69.115 108-88-3 Q7 Toluene 15.435 13.667 13.912 4765.873

84 69.232 560-21-4 I8 2,3,3-Trimethylpentane 4.730 5.001 3.439 1346.437 85 70.803 584-94-1 I8 2,3-Dimethylhexane 1.102 1.188 0.802 313.800 86 72.047 592-27-8 I8 2-Methylheptane 0.059 0.064 0.043 16.668

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 72.319 589-53-7 I8 4-Methylheptane 0.129 0.140 0.094 36.671 88 72.450 ? Unidentified 0.096 0.102 0.070 34.095 89 73.361 589-81-1 I8 3-Methylheptane 0.052 0.057 0.038 14.812 90 75.266 3522-94-9 I9 2,2,5-Trimethylhexane 2.367 2.569 1.533 675.055 91 76.236 ? Unidentified 0.018 0.018 0.014 6.488 92 77.868 111-65-9 P8 n-Octane 0.021 0.023 0.015 6.018 93 78.821 ? Unidentified 0.058 0.058 0.043 20.616 94 80.354 1069-53-0 I9 2,3,5-Trimethylhexane 0.394 0.419 0.255 112.325 95 81.519 1071-26-7 I9 2,4-Dimethylheptane 0.053 0.058 0.035 15.215 96 82.476 1072-05-5 I9 2,6-Dimethylheptane 0.064 0.070 0.042 18.307

97 83.411 I9 2,5-Dimethylheptane 0.187 0.201 0.121 53.362 98 84.749 100-41-4 Q8 Ethylbenzene 2.851 2.524 2.230 873.669 99 84.901 ? Unidentified 0.025 0.026 0.017 8.888 100 85.148 ? Unidentified 0.022 0.022 0.014 7.758 101 86.001 108-38-3 Q8 m-Xylene 7.294 6.479 5.706 2235.133 102 86.140 106-42-3 Q8 p-Xylene 3.389 3.022 2.651 1038.534 103 86.490 C8 C9-IsoOlefin-3 0.014 0.014 0.009 4.152 104 86.597 ? Unidentified 0.012 0.012 0.008 4.181 105 87.408 3221-61-2 I9 2-Methyloctane 0.013 0.014 0.009 3.763 106 88.271 2216-33-3 I9 3-Methyloctane 0.008 0.009 0.005 2.421

107 88.747 ? Unidentified 0.142 0.160 0.093 50.369 108 88.940 95-47-6 Q8 o-Xylene 1.846 1.610 1.444 565.783 109 89.323 I10 C10 - IsoParaffin - 1 0.446 0.471 0.260 127.480 110 90.166 14720-74-2 I10 2,2,4-trimethylheptane 0.301 0.317 0.176 85.947 111 91.710 111-84-2 P9 n-Nonane 0.177 0.189 0.115 50.450 112 93.094 98-82-8 Q9 i-Propylbenzene 0.033 0.029 0.023 9.953 113 93.272 ? Unidentified 0.012 0.012 0.008 4.271 114 93.272 ? Unidentified 0.012 0.013 0.007 4.271 115 93.272 ? Unidentified 0.012 0.009 0.007 4.271 116 93.840 ? Unidentified 0.052 0.055 0.030 18.549

117 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.017 0.018 0.010 4.769 118 94.865 15869-89-3 I10 2,5-Dimethyloctane 0.007 0.008 0.004 2.051 119 95.505 2051-30-1 I10 2,4-Dimethyloctane 0.012 0.013 0.007 3.396 120 96.553 103-65-1 Q9 n-Propylbenzene 0.279 0.248 0.193 84.939 121 97.401 620-14-4 Q9 1-Methyl-3-ethylbenzene 1.081 0.960 0.747 329.098 122 97.633 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.508 0.453 0.351 154.647 123 98.259 108-67-8 Q9 1,3,5-Trimethylbenzene 0.640 0.568 0.442 194.829 124 98.907 17301-94-8 I10 4-Methylnonane 0.009 0.009 0.005 2.482 125 99.112 ? Unidentified 0.167 0.176 0.097 59.137 126 99.344 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.406 0.354 0.280 123.552

127 99.885 5911-04-6 I10 3-Methylnonane 0.014 0.015 0.008 4.114 128 100.350 ? Unidentified 0.012 0.010 0.007 4.414 129 100.481 ? Unidentified 0.036 0.037 0.019 12.795

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 100.696 I11 C11-Isoparaffin-2 0.020 0.021 0.011 5.777 131 100.978 95-63-6 Q9 1,2,4-Trimethylbenzene 2.005 1.757 1.385 610.371 132 101.162 ? Unidentified 0.025 0.027 0.015 8.880 133 101.283 ? Unidentified 0.014 0.015 0.008 5.113 134 102.334 17302-01-1 I10 3-Ethyl-3-methylheptane 0.037 0.039 0.020 10.675 135 102.623 538-93-2 Q10 i-Butylbenzene 0.059 0.053 0.036 17.756 136 102.803 124-18-5 P10 n-Decane 0.016 0.017 0.009 4.591 137 102.899 ? Unidentified 0.024 0.022 0.015 8.680 138 103.197 ? Unidentified 0.010 0.010 0.005 3.529 139 103.849 526-73-8 Q9 1,2,3-Trimethylbenzene 0.366 0.314 0.253 111.433

140 104.241 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.008 0.007 0.005 2.498 141 104.614 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.037 0.033 0.023 11.304 142 105.043 J9 Indan 0.120 0.096 0.084 37.159 143 105.636 J10 Indene 0.227 0.181 0.159 70.184 144 106.352 I11 C11-Isoparaffin-7 0.094 0.097 0.050 26.762 145 106.546 141-93-5 Q10 1,3-Diethylbenzene 0.048 0.043 0.030 14.676 146 106.822 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.394 0.351 0.244 119.298 147 107.163 105-05-5 Q10 1,4-Diethylbenzene 0.147 0.131 0.091 44.524 148 107.260 104-51-8 Q10 n-Butylbenzene 0.030 0.027 0.019 9.170 149 107.381 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.146 0.128 0.091 44.342

150 107.633 135-01-3 Q10 1,2-Diethylbenzene 0.027 0.024 0.017 8.215 151 108.079 ? Unidentified 0.023 0.024 0.012 8.213 152 108.232 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.057 0.050 0.035 17.204 153 108.353 ? Unidentified 0.028 0.029 0.015 9.989 154 108.434 ? Unidentified 0.025 0.026 0.014 9.025 155 108.560 I11 C11- Isoparaffin-11 0.208 0.215 0.111 59.571 156 108.742 ? Unidentified 0.067 0.070 0.036 23.919 157 109.076 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.116 0.102 0.072 35.244 158 109.165 ? Unidentified 0.291 0.255 0.180 103.406 159 109.393 J10 2-Methylindan 0.042 0.033 0.026 12.981

160 109.739 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.309 0.271 0.191 93.639 161 110.284 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.206 0.178 0.128 62.501 162 110.708 ? Unidentified 0.006 0.005 0.003 2.063 163 110.902 693-61-8 K11 2-Undecene, (E)- 0.015 0.016 0.009 4.387 164 111.036 ? Unidentified 0.022 0.023 0.013 7.718 165 111.195 Q11 1-Methyl-4-t-butylbenzene 0.029 0.026 0.016 8.774 166 111.311 ? Unidentified 0.033 0.029 0.019 11.746 167 111.412 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.083 0.071 0.051 25.007 168 111.707 1120-21-4 P11 n-Undecane 0.025 0.026 0.013 7.254 169 111.863 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.027 0.024 0.015 8.251

170 111.972 ? Unidentified 0.014 0.012 0.008 5.004 171 112.346 Q10 1,2,4,5-Tetramethylbenzene 0.235 0.204 0.146 71.287 172 112.612 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.315 0.272 0.195 95.358

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 112.955 J10 C1-Indane - 1 0.005 0.004 0.003 1.440 174 113.131 I12 C12 - IsoParaffin - 1 0.006 0.007 0.003 1.846 175 113.483 ? Unidentified 0.019 0.019 0.009 6.582 176 113.754 Q11 C11 - Aromatic - 3 0.044 0.038 0.025 13.348 177 113.944 874-35-1 H10 5-Methylindan 0.103 0.089 0.065 31.260 178 114.069 Q12 1,2-Di-i-propylbenzene 0.038 0.032 0.019 11.303 179 114.284 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.053 0.046 0.030 15.967 180 114.441 Q11 C11 - Aromatic - 4 0.034 0.029 0.019 10.274 181 114.693 824-22-6 J10 4-Methylindan 0.131 0.113 0.082 39.591 182 114.845 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.039 0.034 0.022 11.910

183 114.940 824-63-5 H10 2-Methylindan 0.103 0.089 0.065 31.331 184 115.144 ? Unidentified 0.011 0.011 0.005 3.825 185 115.256 538-68-1 Q11 n-Pentylbenzene 0.017 0.015 0.010 5.183 186 115.485 Q11 tert-Pentylbenzene 0.058 0.050 0.033 17.591 187 115.797 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.026 0.022 0.014 7.743 188 115.908 Q11 C11 - Aromatic - 7 0.036 0.032 0.020 10.827 189 116.242 I12 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.108 190 116.367 100-18-5 Q12 1,4-Di-i-propylbenzene 0.050 0.043 0.025 14.889 191 116.809 91-20-3 G10 Naphthalene 0.124 0.093 0.081 39.466 192 116.944 ? Unidentified 0.009 0.010 0.005 3.310

193 117.250 J11 1,1-Dimethyl Indane 0.018 0.014 0.010 5.443 194 117.412 J12 Dimethyl Indane - 1 0.007 0.006 0.004 2.186 195 117.592 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.007 0.006 0.004 2.097 196 117.892 Q12 1,3-Di-n-propylbenzene 0.048 0.041 0.025 14.409 197 118.003 Q11 C11 - Aromatic - 11 0.027 0.025 0.015 8.211 198 118.557 Q11 C11 - Aromatic - 12 0.021 0.019 0.012 6.334 199 119.486 102-25-0 Q12 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.670 200 123.439 91-57-6 G11 2-Methylnaphthalene 0.011 0.008 0.006 3.387 201 124.305 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.653 202 126.296 ? Unidentified 0.004 0.004 0.002 1.351

203 130.002 ? Unidentified 0.003 0.002 0.002 1.015

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 10.022 106-97-8 n-Butane 1.703 2.259 2.433 476.606

18.109 109-66-0 n-Pentane 0.821 1.007 0.945 231.436 35.807 110-54-3 n-Hexane 1.709 1.990 1.647 483.546 58.052 142-82-5 n-Heptane 0.120 0.135 0.100 34.163 77.868 111-65-9 n-Octane 0.021 0.023 0.015 6.018 91.710 111-84-2 n-Nonane 0.177 0.189 0.115 50.450 102.803 124-18-5 n-Decane 0.016 0.017 0.009 4.591 111.707 1120-21-4 n-Undecane 0.025 0.026 0.013 7.254

I-Paraffins 8.809 75-28-5 i-Butane 0.018 0.025 0.026 5.016

10.635 463-82-1 2,2-Dimethylpropane 0.008 0.010 0.009 2.207 15.072 78-78-4 i-Pentane 3.147 3.899 3.622 886.785 23.100 75-83-2 2,2-Dimethylbutane 0.028 0.033 0.027 7.928 28.334 79-29-8 2,3-Dimethylbutane 0.704 0.817 0.678 199.158 29.413 107-83-5 2-Methylpentane 1.771 2.082 1.707 501.176 32.064 96-14-0 3-Methylpentane 1.328 1.535 1.280 375.725 42.230 108-08-7 2,4-Dimethylpentane 0.524 0.598 0.434 148.880 42.780 464-06-2 2,2,3-Trimethylbutane 0.040 0.045 0.033 11.375 50.663 591-76-4 2-Methylhexane 0.805 0.911 0.667 228.761 52.490 589-34-4 3-Methylhexane 0.364 0.406 0.301 103.273 55.165 540-84-1 2,2,4-Trimethylpentane 2.988 3.315 2.172 850.410 64.950 564-02-3 2,2,3-Trimethylpentane 0.448 0.481 0.326 127.584 65.178 592-13-2 2,5-Dimethylhexane 0.836 0.925 0.608 237.908 65.515 589-43-5 2,4-Dimethylhexane 0.739 0.810 0.537 210.382 68.522 565-75-3 2,3,4-Trimethylpentane 4.183 4.466 3.041 1190.681 69.232 560-21-4 2,3,3-Trimethylpentane 4.730 5.001 3.439 1346.437 70.803 584-94-1 2,3-Dimethylhexane 1.102 1.188 0.802 313.800 72.047 592-27-8 2-Methylheptane 0.059 0.064 0.043 16.668 72.319 589-53-7 4-Methylheptane 0.129 0.140 0.094 36.671 73.361 589-81-1 3-Methylheptane 0.052 0.057 0.038 14.812 75.266 3522-94-9 2,2,5-Trimethylhexane 2.367 2.569 1.533 675.055 80.354 1069-53-0 2,3,5-Trimethylhexane 0.394 0.419 0.255 112.325 81.519 1071-26-7 2,4-Dimethylheptane 0.053 0.058 0.035 15.215 82.476 1072-05-5 2,6-Dimethylheptane 0.064 0.070 0.042 18.307 83.411 2,5-Dimethylheptane 0.187 0.201 0.121 53.362 87.408 3221-61-2 2-Methyloctane 0.013 0.014 0.009 3.763 88.271 2216-33-3 3-Methyloctane 0.008 0.009 0.005 2.421 89.323 C10 - IsoParaffin - 1 0.446 0.471 0.260 127.480 90.166 14720-74-2 2,2,4-trimethylheptane 0.301 0.317 0.176 85.947 94.064 15869-87-1 2,2-Dimethyloctane 0.017 0.018 0.010 4.769 94.865 15869-89-3 2,5-Dimethyloctane 0.007 0.008 0.004 2.051 95.505 2051-30-1 2,4-Dimethyloctane 0.012 0.013 0.007 3.396 98.907 17301-94-8 4-Methylnonane 0.009 0.009 0.005 2.482 99.885 5911-04-6 3-Methylnonane 0.014 0.015 0.008 4.114 100.696 C11-Isoparaffin-2 0.020 0.021 0.011 5.777 102.334 17302-01-1 3-Ethyl-3-methylheptane 0.037 0.039 0.020 10.675 106.352 C11-Isoparaffin-7 0.094 0.097 0.050 26.762

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 108.560 C11- Isoparaffin-11 0.208 0.215 0.111 59.571

113.131 C12 - IsoParaffin - 1 0.006 0.007 0.003 1.846 116.242 C12 - IsoParaffin - 4 0.004 0.004 0.002 1.108

Aromatics Mono-Aromatics 45.635 71-42-3 Benzene 0.685 0.598 0.728 213.697

69.115 108-88-3 Toluene 15.435 13.667 13.912 4765.873 84.749 100-41-4 Ethylbenzene 2.851 2.524 2.230 873.669 86.001 108-38-3 m-Xylene 7.294 6.479 5.706 2235.133 86.140 106-42-3 p-Xylene 3.389 3.022 2.651 1038.534 88.940 95-47-6 o-Xylene 1.846 1.610 1.444 565.783 93.094 98-82-8 i-Propylbenzene 0.033 0.029 0.023 9.953 96.553 103-65-1 n-Propylbenzene 0.279 0.248 0.193 84.939 97.401 620-14-4 1-Methyl-3-ethylbenzene 1.081 0.960 0.747 329.098 97.633 622-96-8 1-Methyl-4-ethylbenzene 0.508 0.453 0.351 154.647 98.259 108-67-8 1,3,5-Trimethylbenzene 0.640 0.568 0.442 194.829 99.344 611-14-3 1-Methyl-2-ethylbenzene 0.406 0.354 0.280 123.552 100.978 95-63-6 1,2,4-Trimethylbenzene 2.005 1.757 1.385 610.371 102.623 538-93-2 i-Butylbenzene 0.059 0.053 0.036 17.756 103.849 526-73-8 1,2,3-Trimethylbenzene 0.366 0.314 0.253 111.433 104.241 535-77-3 1-Methyl-3-i-propylbenzene 0.008 0.007 0.005 2.498 104.614 99-87-6 1-Methyl-4-i-propylbenzene 0.037 0.033 0.023 11.304 106.546 141-93-5 1,3-Diethylbenzene 0.048 0.043 0.030 14.676 106.822 1074-43-7 1-Methyl-3-n-propylbenzene 0.394 0.351 0.244 119.298 107.163 105-05-5 1,4-Diethylbenzene 0.147 0.131 0.091 44.524 107.260 104-51-8 n-Butylbenzene 0.030 0.027 0.019 9.170 107.381 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.146 0.128 0.091 44.342 107.633 135-01-3 1,2-Diethylbenzene 0.027 0.024 0.017 8.215 108.232 1074-17-5 1-Methyl-2-n-propylbenzene 0.057 0.050 0.035 17.204 109.076 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.116 0.102 0.072 35.244 109.739 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.309 0.271 0.191 93.639 110.284 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.206 0.178 0.128 62.501 111.195 1-Methyl-4-t-butylbenzene 0.029 0.026 0.016 8.774 111.412 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.083 0.071 0.051 25.007 111.863 4218-48-8 1-Ethyl-4-i-propylbenzene 0.027 0.024 0.015 8.251 112.346 1,2,4,5-Tetramethylbenzene 0.235 0.204 0.146 71.287 112.612 527-53-7 1,2,3,5-Tetramethylbenzene 0.315 0.272 0.195 95.358 113.754 C11 - Aromatic - 3 0.044 0.038 0.025 13.348 114.069 1,2-Di-i-propylbenzene 0.038 0.032 0.019 11.303 114.284 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.053 0.046 0.030 15.967 114.441 C11 - Aromatic - 4 0.034 0.029 0.019 10.274 114.845 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.039 0.034 0.022 11.910 115.256 538-68-1 n-Pentylbenzene 0.017 0.015 0.010 5.183 115.485 tert-Pentylbenzene 0.058 0.050 0.033 17.591 115.797 577-55-9 1-Methyl-2-n-butylbenzene 0.026 0.022 0.014 7.743 115.908 C11 - Aromatic - 7 0.036 0.032 0.020 10.827 116.367 100-18-5 1,4-Di-i-propylbenzene 0.050 0.043 0.025 14.889

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 117.592 7364-19-4 1t-Butyl-4-ethylbenzene 0.007 0.006 0.004 2.097

117.892 1,3-Di-n-propylbenzene 0.048 0.041 0.025 14.409 118.003 C11 - Aromatic - 11 0.027 0.025 0.015 8.211 118.557 C11 - Aromatic - 12 0.021 0.019 0.012 6.334 119.486 102-25-0 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.670

Naphthalenes 116.809 91-20-3 Naphthalene 0.124 0.093 0.081 39.466

123.439 91-57-6 2-Methylnaphthalene 0.011 0.008 0.006 3.387 124.305 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.653

Naphtheno/Olefino-Benzs

113.944 874-35-1 5-Methylindan 0.103 0.089 0.065 31.260 114.940 824-63-5 2-Methylindan 0.103 0.089 0.065 31.331

Indenes 105.043 Indan 0.120 0.096 0.084 37.159

105.636 Indene 0.227 0.181 0.159 70.184 109.393 2-Methylindan 0.042 0.033 0.026 12.981 112.955 C1-Indane - 1 0.005 0.004 0.003 1.440 114.693 824-22-6 4-Methylindan 0.131 0.113 0.082 39.591 117.250 1,1-Dimethyl Indane 0.018 0.014 0.010 5.443 117.412 Dimethyl Indane - 1 0.007 0.006 0.004 2.186

Naphthenes Mono-Naphthenes 27.603 287-92-3 Cyclopentane 0.093 0.096 0.111 27.060

40.668 96-37-7 Methylcyclopentane 1.035 1.061 1.021 299.897 47.550 110-82-7 Cyclohexane 0.422 0.416 0.416 122.239 53.349 1759-58-6 1t,3-Dimethylcyclopentane 0.100 0.102 0.084 28.855 53.936 2532-58-3 1c,3-Dimethylcyclopentane 0.067 0.069 0.057 19.418 54.563 822-50-4 1t,2-Dimethylcyclopentane 0.068 0.069 0.057 19.620 59.649 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 5.243 61.504 108-87-2 Methylcyclohexane 0.054 0.054 0.046 15.625

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.622 115-11-7 Isobutene 0.017 0.021 0.025 4.824

9.663 106-98-9 Butene-1 0.018 0.024 0.027 5.339 10.507 624-64-6 t-Butene-2 0.075 0.096 0.111 21.798 11.249 590-18-1 c-Butene-2 0.088 0.109 0.131 25.652 16.725 109-67-1 Pentene-1 0.337 0.404 0.400 97.817 19.230 646-04-8 t-Pentene-2 0.854 1.011 1.011 247.513 20.263 627-20-3 c-Pentene-2 0.468 0.548 0.554 135.641 33.449 592-41-6 Hexene-1 0.162 0.184 0.160 47.021 36.437 13269-52-8 t-Hexene-3 0.260 0.293 0.257 75.488 36.913 4050-45-7 t-Hexene-2 0.399 0.449 0.394 115.739 38.741 7688-21-3 c-Hexene-2 0.211 0.234 0.209 61.253 55.470 592-76-7 Heptene-1 0.028 0.031 0.024 8.182 57.330 14686-14-7 t-Heptene-3 0.032 0.035 0.027 9.157 58.272 7642-10-6 c-Heptene-3 0.025 0.027 0.021 7.277

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  n-Olefins 59.173 14686-13-6 t-Heptene-2 0.013 0.014 0.011 3.821

110.902 693-61-8 2-Undecene, (E)- 0.015 0.016 0.009 4.387

Iso-Olefins 13.450 563-45-1 3-Methylbutene-1 0.219 0.268 0.259 63.429

17.577 563-46-2 2-Methylbutene-1 0.512 0.604 0.606 148.347 20.940 513-35-9 2-Methylbutene-2 1.046 1.213 1.239 303.329 29.190 691-38-3 4-Methyl-c-pentene-2 0.046 0.052 0.045 13.302 29.840 674-76-0 4-Methyl-t-pentene-2 0.130 0.148 0.129 37.750 33.226 763-29-1 2-Methylpentene-1 0.222 0.249 0.219 64.428 35.642 760-21-4 2-Ethylbutene-1 0.063 0.070 0.062 18.264 37.407 625-27-4 2-Methylpentene-2 0.338 0.375 0.333 97.894 37.820 922-62-3 3-Methyl-c-pentene-2 0.261 0.287 0.257 75.630 40.086 3404-73-7 3,3-Dimethylpentene-1 0.307 0.335 0.259 88.880 42.531 594-56-9 2,3,3-Trimethylbutene-1 0.014 0.015 0.012 4.048 46.637 3404-61-3 3-Methylhexene-1 0.016 0.017 0.013 4.523 47.227 3524-73-0 5-Methylhexene-1 0.037 0.041 0.031 10.776 49.271 15840-60-5 2-Methyl-c-hexene-3 0.040 0.044 0.034 11.593 49.616 3769-23-1 4-Methylhexene-1 0.012 0.013 0.010 3.344 50.264 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.054 0.042 14.460 54.855 C7 - Iso-Olefin - 2 0.022 0.024 0.019 6.500 56.801 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.947 57.683 6094-02-6 2-Methylhexene-1 0.056 0.062 0.048 16.309 58.546 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.022 7.459 58.790 10574-36-4 3-Methyl-c-hexene-2 0.020 0.021 0.017 5.684 60.075 20710-38-8 3-Methyl-t-hexene-2 0.015 0.016 0.013 4.288 60.857 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.646 86.490 C9-IsoOlefin-3 0.014 0.014 0.009 4.152

Naphtheno-Olefins 22.531 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.009 2.115

25.738 142-29-0 Cyclopentene 0.198 0.196 0.241 58.959 37.039 1120-62-3 3-Methylcyclopentene 0.099 0.100 0.101 28.830 45.832 693-89-0 1-Methylcyclopentene 0.355 0.349 0.359 105.295 51.151 110-83-8 Cyclohexene 0.044 0.042 0.044 12.745

Di-Olefins 18.624 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 3.169

21.266 2004-70-8 1t,3-Pentadiene 0.016 0.018 0.019 4.692 45.424 1528-30-9 C6-Diolefin-1 0.015 0.015 0.015 4.336

Oxygenates 13.095 64-17-5 Ethanol 15.958 15.526 28.767 1904.669

26.899 71-23-8 n-Propanol 0.076 0.073 0.106 15.497 48.057 71-36-3 n-Butanol 0.055 0.053 0.061 12.019

Unidentified 19.875 Unidentified 0.006 0.007 0.007 2.072

26.990 Unidentified 0.059 0.067 0.058 20.797 28.732 Unidentified 0.053 0.055 0.050 18.695 63.367 Unidentified 0.043 0.045 0.032 15.132 72.450 Unidentified 0.096 0.102 0.070 34.095

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Unidentified 76.236 Unidentified 0.018 0.018 0.014 6.488

78.821 Unidentified 0.058 0.058 0.043 20.616 84.901 Unidentified 0.025 0.026 0.017 8.888 85.148 Unidentified 0.022 0.022 0.014 7.758 86.597 Unidentified 0.012 0.012 0.008 4.181 88.747 Unidentified 0.142 0.160 0.093 50.369 93.272 Unidentified 0.012 0.012 0.008 4.271 93.272 Unidentified 0.012 0.013 0.007 4.271 93.272 Unidentified 0.012 0.009 0.007 4.271 93.840 Unidentified 0.052 0.055 0.030 18.549 99.112 Unidentified 0.167 0.176 0.097 59.137 100.350 Unidentified 0.012 0.010 0.007 4.414 100.481 Unidentified 0.036 0.037 0.019 12.795 101.162 Unidentified 0.025 0.027 0.015 8.880 101.283 Unidentified 0.014 0.015 0.008 5.113 102.899 Unidentified 0.024 0.022 0.015 8.680 103.197 Unidentified 0.010 0.010 0.005 3.529 108.079 Unidentified 0.023 0.024 0.012 8.213 108.353 Unidentified 0.028 0.029 0.015 9.989 108.434 Unidentified 0.025 0.026 0.014 9.025 108.742 Unidentified 0.067 0.070 0.036 23.919 109.165 Unidentified 0.291 0.255 0.180 103.406 110.708 Unidentified 0.006 0.005 0.003 2.063 111.036 Unidentified 0.022 0.023 0.013 7.718 111.311 Unidentified 0.033 0.029 0.019 11.746 111.972 Unidentified 0.014 0.012 0.008 5.004 113.483 Unidentified 0.019 0.019 0.009 6.582 115.144 Unidentified 0.011 0.011 0.005 3.825 116.944 Unidentified 0.009 0.010 0.005 3.310 126.296 Unidentified 0.004 0.004 0.002 1.351 130.002 Unidentified 0.003 0.002 0.002 1.015

Plus

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2

2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane

2,3,4-Trimethylpentane
Toluene 2,3,3-Trimethylpentane

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified

3-Methylheptane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

Unidentified

n-Octane

Unidentified

2,3,5-Trimethylhexane

2,4-Dimethylheptane

2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene Unidentified

m-Xylene p-Xylene C9-IsoOlefin-3 Unidentified
2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1

2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene Unidentified Unidentified 2,2-Dimethyloctane
2,5-Dimethyloctane 2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 4-Methylnonane Unidentified 1-Methyl-2-ethylbenzene 3-Methylnonane

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene C1-Indane - 1 C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 C12 - IsoParaffin - 4 1,4-Di-i-propylbenzene Naphthalene Unidentified 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 20:51:55 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF Sample: ODDB-91332 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91332 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000014.D\SIG2000014_FID2_B.CDF145.0140.0135.0130.0125.0

Unidentified

Unidentified

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 4.061 5.099 2.937

I-Paraffins 5.798 6.839 3.314

Aromatics 6.677 5.948 3.273 Mono-Aromatics 6.588 5.876 3.238 Naphthalenes 0.033 0.025 0.012 Naphtheno/Olefino-Benzs 0.014 0.013 0.005 Indenes 0.042 0.035 0.018

Naphthenes 0.715 0.733 0.423 Mono-Naphthenes 0.715 0.733 0.423 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 0.443 0.549 0.359 n-Olefins 0.337 0.429 0.295 Iso-Olefins 0.106 0.120 0.063 Naphtheno-Olefins 0.000 0.000 0.000 Di-Olefins 0.000 0.000 0.000

Oxygenates 82.109 80.620 89.603

Unidentified 0.197 0.213 0.091

Plus 0.000 0.000 0.000

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 82.109 80.620 89.603 C3 0.007 0.010 0.007 C4 2.040 2.725 1.774 C5 3.749 4.624 2.617 C6 2.008 2.282 1.184 C7 3.810 3.679 2.027 C8 4.280 4.206 1.966 C9 1.459 1.336 0.605 C10 0.300 0.267 0.113 C11 0.042 0.039 0.014

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.007 0.010 0.007 C4 1.528 2.045 1.321 C5 1.652 2.044 1.151 C6 0.399 0.469 0.233 C7 0.289 0.327 0.145 C8 0.138 0.153 0.061 C9 0.036 0.039 0.014 C10 0.008 0.008 0.003 C11 0.004 0.004 0.001

I-Paraffins C4 0.212 0.295 0.183 C5 1.843 2.304 1.284 C6 1.190 1.403 0.694 C7 0.674 0.766 0.338 C8 1.665 1.839 0.733 C9 0.171 0.185 0.067 C10 0.023 0.025 0.008 C11 0.020 0.021 0.007

Mono-Aromatics C6 0.142 0.125 0.091 C7 2.551 2.280 1.392 C8 2.446 2.184 1.158 C9 1.230 1.093 0.514 C10 0.219 0.194 0.082

Naphthalenes C10 0.016 0.012 0.006 C11 0.017 0.013 0.006

Naphtheno/Olefino-Benzs C10 0.014 0.013 0.005

Indenes C9 0.022 0.018 0.009 C10 0.020 0.017 0.008

Mono-Naphthenes C5 0.177 0.184 0.127 C6 0.268 0.274 0.160 C7 0.240 0.244 0.123 C8 0.030 0.030 0.014

n-Olefins C4 0.300 0.385 0.269 C5 0.037 0.044 0.026

Iso-Olefins C5 0.041 0.048 0.029

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Iso-Olefins C6 0.009 0.010 0.005 C7 0.056 0.062 0.029

Oxygenates C2 82.109 80.620 89.603

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 21.70 20.80 5% 93.97 81.46 10% 171.55 171.51 15% 171.66 171.62 20% 171.77 171.74 25% 171.88 171.85 30% 171.99 171.96 35% 172.10 172.07 40% 172.21 172.18 45% 172.32 172.29 50% 172.43 172.41 55% 172.54 172.52 60% 172.65 172.63 65% 172.76 172.74 70% 172.87 172.85 75% 172.98 172.96 80% 173.09 173.07 85% 173.20 173.19 90% 178.77 173.30 95% 235.25 231.00 FBP 336.22 335.51

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.476 ? Unidentified 0.001 0.002 0.001 0.379 2 7.554 74-98-6 P3 Propane 0.007 0.010 0.007 1.953 3 8.808 75-28-5 I4 i-Butane 0.212 0.295 0.183 64.086 4 9.621 115-11-7 K4 Isobutene 0.073 0.095 0.065 22.829 5 9.662 106-98-9 K4 Butene-1 0.055 0.071 0.049 17.123 6 10.021 106-97-8 P4 n-Butane 1.528 2.045 1.321 461.498 7 10.506 624-64-6 K4 t-Butene-2 0.107 0.137 0.096 33.454 8 10.634 463-82-1 I5 2,2-Dimethylpropane 0.009 0.012 0.006 2.810 9 11.247 590-18-1 K4 c-Butene-2 0.066 0.082 0.059 20.543 10 13.405 64-17-5 X2 Ethanol 82.109 80.620 89.603 10578.776

11 15.067 78-78-4 I5 i-Pentane 1.833 2.292 1.277 557.689 12 16.723 109-67-1 K5 Pentene-1 0.008 0.010 0.006 2.513 13 17.574 563-46-2 C5 2-Methylbutene-1 0.014 0.017 0.010 4.365 14 18.105 109-66-0 P5 n-Pentane 1.652 2.044 1.151 502.540 15 19.225 646-04-8 K5 t-Pentene-2 0.019 0.022 0.013 5.850 16 20.258 627-20-3 K5 c-Pentene-2 0.010 0.012 0.007 3.111 17 20.935 513-35-9 C5 2-Methylbutene-2 0.027 0.032 0.019 8.449 18 23.079 75-83-2 I6 2,2-Dimethylbutane 0.069 0.082 0.040 20.959 19 27.595 287-92-3 M5 Cyclopentane 0.177 0.184 0.127 55.278 20 28.325 79-29-8 I6 2,3-Dimethylbutane 0.147 0.172 0.086 44.870

21 29.399 107-83-5 I6 2-Methylpentane 0.632 0.750 0.369 193.017 22 32.051 96-14-0 I6 3-Methylpentane 0.342 0.399 0.200 104.569 23 35.789 110-54-3 P6 n-Hexane 0.399 0.469 0.233 121.978 24 37.397 625-27-4 C6 2-Methylpentene-2 0.009 0.010 0.005 2.835 25 40.078 3404-73-7 C7 3,3-Dimethylpentene-1 0.009 0.010 0.004 2.745 26 40.654 96-37-7 M6 Methylcyclopentane 0.201 0.208 0.120 62.791 27 42.217 108-08-7 I7 2,4-Dimethylpentane 0.074 0.085 0.037 22.613 28 45.625 71-42-3 Q6 Benzene 0.142 0.125 0.091 47.875 29 47.219 3524-73-0 C7 5-Methylhexene-1 0.022 0.024 0.011 6.770 30 47.541 110-82-7 M6 Cyclohexane 0.067 0.067 0.040 20.976

31 50.650 591-76-4 I7 2-Methylhexane 0.323 0.369 0.162 99.136 32 52.480 589-34-4 I7 3-Methylhexane 0.277 0.312 0.139 84.930 33 53.343 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.025 0.026 0.013 7.722 34 53.929 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.022 0.023 0.011 6.930 35 54.555 822-50-4 M7 1t,2-Dimethylcyclopentane 0.029 0.030 0.015 9.026 36 54.670 C7 2-Ethylpentene-1 0.025 0.028 0.013 7.944 37 55.134 540-84-1 I8 2,2,4-Trimethylpentane 0.666 0.745 0.293 204.506 38 58.045 142-82-5 P7 n-Heptane 0.289 0.327 0.145 88.539 39 61.501 108-87-2 M7 Methylcyclohexane 0.094 0.095 0.048 29.471 40 62.839 590-73-8 I8 2,2-Dimethylhexane 0.013 0.015 0.006 4.028

41 63.330 ? Unidentified 0.196 0.211 0.090 75.213 42 64.168 1640-89-7 M7 Ethylcyclopentane 0.070 0.071 0.036 22.047 43 64.936 564-02-3 I8 2,2,3-Trimethylpentane 0.024 0.026 0.011 7.456

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 65.159 592-13-2 I8 2,5-Dimethylhexane 0.084 0.094 0.037 25.953 45 65.497 589-43-5 I8 2,4-Dimethylhexane 0.108 0.120 0.048 33.221 46 66.334 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.009 0.010 0.004 2.959 47 66.731 563-16-6 I8 3,3-Dimethylhexane 0.016 0.017 0.007 4.848 48 68.455 565-75-3 I8 2,3,4-Trimethylpentane 0.277 0.298 0.122 84.965 49 68.984 108-88-3 Q7 Toluene 2.551 2.280 1.392 850.318 50 70.783 584-94-1 I8 2,3-Dimethylhexane 0.091 0.099 0.040 28.040 51 72.038 592-27-8 I8 2-Methylheptane 0.120 0.133 0.053 36.872 52 72.293 589-53-7 I8 4-Methylheptane 0.078 0.086 0.034 23.923 53 73.354 589-81-1 I8 3-Methylheptane 0.153 0.168 0.067 47.044

54 73.519 619-99-8 I8 3-Ethylhexane 0.035 0.038 0.015 10.738 55 75.241 3522-94-9 I9 2,2,5-Trimethylhexane 0.046 0.050 0.018 14.140 56 75.602 M8 3c-Ethylmethylcyclopentane 0.005 0.005 0.002 1.493 57 77.864 111-65-9 P8 n-Octane 0.138 0.153 0.061 42.513 58 80.347 1069-53-0 I9 2,3,5-Trimethylhexane 0.008 0.008 0.003 2.314 59 81.516 1071-26-7 I9 2,4-Dimethylheptane 0.009 0.010 0.003 2.694 60 82.159 1678-91-7 M8 Ethylcyclohexane 0.016 0.016 0.007 5.021 61 82.471 1072-05-5 I9 2,6-Dimethylheptane 0.011 0.012 0.004 3.299 62 83.399 I9 2,5-Dimethylheptane 0.016 0.018 0.006 4.984 63 84.721 100-41-4 Q8 Ethylbenzene 0.402 0.359 0.190 132.895

64 85.937 108-38-3 Q8 m-Xylene 1.042 0.934 0.493 344.612 65 86.087 106-42-3 Q8 p-Xylene 0.441 0.397 0.209 145.825 66 87.270 2216-34-4 I9 4-Methyloctane 0.021 0.023 0.008 6.551 67 87.401 3221-61-2 I9 2-Methyloctane 0.024 0.026 0.010 7.490 68 88.101 15869-80-4 I9 Heptane, 3-ethyl- 0.006 0.006 0.002 1.820 69 88.265 2216-33-3 I9 3-Methyloctane 0.030 0.033 0.012 9.307 70 88.922 95-47-6 Q8 o-Xylene 0.562 0.494 0.266 185.747 71 89.316 I10 C10 - IsoParaffin - 1 0.006 0.006 0.002 1.702 72 91.744 111-84-2 P9 n-Nonane 0.036 0.039 0.014 11.157 73 93.091 98-82-8 Q9 i-Propylbenzene 0.022 0.020 0.009 7.355

74 96.548 103-65-1 Q9 n-Propylbenzene 0.077 0.069 0.032 25.188 75 97.389 620-14-4 Q9 1-Methyl-3-ethylbenzene 0.271 0.243 0.113 89.025 76 97.625 622-96-8 Q9 1-Methyl-4-ethylbenzene 0.119 0.107 0.050 38.990 77 98.250 108-67-8 Q9 1,3,5-Trimethylbenzene 0.127 0.114 0.053 41.883 78 99.111 I10 2,2,6-Trimethyloctane 0.018 0.019 0.006 5.417 79 99.338 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.098 0.086 0.041 32.243 80 100.960 95-63-6 Q9 1,2,4-Trimethylbenzene 0.425 0.376 0.178 139.747 81 102.802 124-18-5 P10 n-Decane 0.008 0.008 0.003 2.335 82 103.843 526-73-8 Q9 1,2,3-Trimethylbenzene 0.091 0.078 0.038 29.778 83 105.039 J9 Indan 0.022 0.018 0.009 7.373

84 105.632 J10 Indene 0.012 0.009 0.005 3.869 85 106.349 I11 C11-Isoparaffin-7 0.005 0.005 0.002 1.504 86 106.542 141-93-5 Q10 1,3-Diethylbenzene 0.009 0.008 0.003 2.822

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 106.803 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.036 0.033 0.014 11.915 88 107.159 105-05-5 Q10 1,4-Diethylbenzene 0.018 0.016 0.007 5.822 89 107.377 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.025 0.022 0.009 8.046 90 108.230 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.007 0.006 0.003 2.314 91 108.558 I11 C11- Isoparaffin-11 0.016 0.016 0.005 4.816 92 109.071 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.017 0.015 0.006 5.486 93 109.234 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.023 0.020 0.009 7.558 94 109.736 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.029 0.026 0.011 9.449 95 110.282 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.009 0.008 0.003 2.930 96 111.411 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.006 0.005 0.002 1.946

97 111.687 1120-21-4 P11 n-Undecane 0.004 0.004 0.001 1.281 98 112.343 Q10 1,2,4,5-Tetramethylbenzene 0.017 0.015 0.006 5.526 99 112.608 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.024 0.021 0.009 7.747 100 113.942 874-35-1 H10 5-Methylindan 0.006 0.005 0.002 1.846 101 114.691 824-22-6 J10 4-Methylindan 0.009 0.007 0.003 2.806 102 114.939 824-63-5 H10 2-Methylindan 0.009 0.008 0.003 2.852 103 116.809 91-20-3 G10 Naphthalene 0.016 0.012 0.006 5.344 104 123.439 91-57-6 G11 2-Methylnaphthalene 0.012 0.009 0.004 4.131 105 124.304 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.002 1.679

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.554 74-98-6 Propane 0.007 0.010 0.007 1.953

10.021 106-97-8 n-Butane 1.528 2.045 1.321 461.498 18.105 109-66-0 n-Pentane 1.652 2.044 1.151 502.540 35.789 110-54-3 n-Hexane 0.399 0.469 0.233 121.978 58.045 142-82-5 n-Heptane 0.289 0.327 0.145 88.539 77.864 111-65-9 n-Octane 0.138 0.153 0.061 42.513 91.744 111-84-2 n-Nonane 0.036 0.039 0.014 11.157 102.802 124-18-5 n-Decane 0.008 0.008 0.003 2.335 111.687 1120-21-4 n-Undecane 0.004 0.004 0.001 1.281

I-Paraffins 8.808 75-28-5 i-Butane 0.212 0.295 0.183 64.086

10.634 463-82-1 2,2-Dimethylpropane 0.009 0.012 0.006 2.810 15.067 78-78-4 i-Pentane 1.833 2.292 1.277 557.689 23.079 75-83-2 2,2-Dimethylbutane 0.069 0.082 0.040 20.959 28.325 79-29-8 2,3-Dimethylbutane 0.147 0.172 0.086 44.870 29.399 107-83-5 2-Methylpentane 0.632 0.750 0.369 193.017 32.051 96-14-0 3-Methylpentane 0.342 0.399 0.200 104.569 42.217 108-08-7 2,4-Dimethylpentane 0.074 0.085 0.037 22.613 50.650 591-76-4 2-Methylhexane 0.323 0.369 0.162 99.136 52.480 589-34-4 3-Methylhexane 0.277 0.312 0.139 84.930 55.134 540-84-1 2,2,4-Trimethylpentane 0.666 0.745 0.293 204.506 62.839 590-73-8 2,2-Dimethylhexane 0.013 0.015 0.006 4.028 64.936 564-02-3 2,2,3-Trimethylpentane 0.024 0.026 0.011 7.456 65.159 592-13-2 2,5-Dimethylhexane 0.084 0.094 0.037 25.953 65.497 589-43-5 2,4-Dimethylhexane 0.108 0.120 0.048 33.221 66.731 563-16-6 3,3-Dimethylhexane 0.016 0.017 0.007 4.848 68.455 565-75-3 2,3,4-Trimethylpentane 0.277 0.298 0.122 84.965 70.783 584-94-1 2,3-Dimethylhexane 0.091 0.099 0.040 28.040 72.038 592-27-8 2-Methylheptane 0.120 0.133 0.053 36.872 72.293 589-53-7 4-Methylheptane 0.078 0.086 0.034 23.923 73.354 589-81-1 3-Methylheptane 0.153 0.168 0.067 47.044 73.519 619-99-8 3-Ethylhexane 0.035 0.038 0.015 10.738 75.241 3522-94-9 2,2,5-Trimethylhexane 0.046 0.050 0.018 14.140 80.347 1069-53-0 2,3,5-Trimethylhexane 0.008 0.008 0.003 2.314 81.516 1071-26-7 2,4-Dimethylheptane 0.009 0.010 0.003 2.694 82.471 1072-05-5 2,6-Dimethylheptane 0.011 0.012 0.004 3.299 83.399 2,5-Dimethylheptane 0.016 0.018 0.006 4.984 87.270 2216-34-4 4-Methyloctane 0.021 0.023 0.008 6.551 87.401 3221-61-2 2-Methyloctane 0.024 0.026 0.010 7.490 88.101 15869-80-4 Heptane, 3-ethyl- 0.006 0.006 0.002 1.820 88.265 2216-33-3 3-Methyloctane 0.030 0.033 0.012 9.307 89.316 C10 - IsoParaffin - 1 0.006 0.006 0.002 1.702 99.111 2,2,6-Trimethyloctane 0.018 0.019 0.006 5.417 106.349 C11-Isoparaffin-7 0.005 0.005 0.002 1.504 108.558 C11- Isoparaffin-11 0.016 0.016 0.005 4.816

Aromatics Mono-Aromatics 45.625 71-42-3 Benzene 0.142 0.125 0.091 47.875

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 68.984 108-88-3 Toluene 2.551 2.280 1.392 850.318

84.721 100-41-4 Ethylbenzene 0.402 0.359 0.190 132.895 85.937 108-38-3 m-Xylene 1.042 0.934 0.493 344.612 86.087 106-42-3 p-Xylene 0.441 0.397 0.209 145.825 88.922 95-47-6 o-Xylene 0.562 0.494 0.266 185.747 93.091 98-82-8 i-Propylbenzene 0.022 0.020 0.009 7.355 96.548 103-65-1 n-Propylbenzene 0.077 0.069 0.032 25.188 97.389 620-14-4 1-Methyl-3-ethylbenzene 0.271 0.243 0.113 89.025 97.625 622-96-8 1-Methyl-4-ethylbenzene 0.119 0.107 0.050 38.990 98.250 108-67-8 1,3,5-Trimethylbenzene 0.127 0.114 0.053 41.883 99.338 611-14-3 1-Methyl-2-ethylbenzene 0.098 0.086 0.041 32.243 100.960 95-63-6 1,2,4-Trimethylbenzene 0.425 0.376 0.178 139.747 103.843 526-73-8 1,2,3-Trimethylbenzene 0.091 0.078 0.038 29.778 106.542 141-93-5 1,3-Diethylbenzene 0.009 0.008 0.003 2.822 106.803 1074-43-7 1-Methyl-3-n-propylbenzene 0.036 0.033 0.014 11.915 107.159 105-05-5 1,4-Diethylbenzene 0.018 0.016 0.007 5.822 107.377 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.025 0.022 0.009 8.046 108.230 1074-17-5 1-Methyl-2-n-propylbenzene 0.007 0.006 0.003 2.314 109.071 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.017 0.015 0.006 5.486 109.234 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.023 0.020 0.009 7.558 109.736 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.029 0.026 0.011 9.449 110.282 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.009 0.008 0.003 2.930 111.411 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.006 0.005 0.002 1.946 112.343 1,2,4,5-Tetramethylbenzene 0.017 0.015 0.006 5.526 112.608 527-53-7 1,2,3,5-Tetramethylbenzene 0.024 0.021 0.009 7.747

Naphthalenes 116.809 91-20-3 Naphthalene 0.016 0.012 0.006 5.344

123.439 91-57-6 2-Methylnaphthalene 0.012 0.009 0.004 4.131 124.304 90-12-0 1-Methylnaphthalene 0.005 0.004 0.002 1.679

Naphtheno/Olefino-Benzs

113.942 874-35-1 5-Methylindan 0.006 0.005 0.002 1.846 114.939 824-63-5 2-Methylindan 0.009 0.008 0.003 2.852

Indenes 105.039 Indan 0.022 0.018 0.009 7.373

105.632 Indene 0.012 0.009 0.005 3.869 114.691 824-22-6 4-Methylindan 0.009 0.007 0.003 2.806

Naphthenes Mono-Naphthenes 27.595 287-92-3 Cyclopentane 0.177 0.184 0.127 55.278

40.654 96-37-7 Methylcyclopentane 0.201 0.208 0.120 62.791 47.541 110-82-7 Cyclohexane 0.067 0.067 0.040 20.976 53.343 1759-58-6 1t,3-Dimethylcyclopentane 0.025 0.026 0.013 7.722 53.929 2532-58-3 1c,3-Dimethylcyclopentane 0.022 0.023 0.011 6.930 54.555 822-50-4 1t,2-Dimethylcyclopentane 0.029 0.030 0.015 9.026 61.501 108-87-2 Methylcyclohexane 0.094 0.095 0.048 29.471 64.168 1640-89-7 Ethylcyclopentane 0.070 0.071 0.036 22.047 66.334 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.009 0.010 0.004 2.959

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 75.602 3c-Ethylmethylcyclopentane 0.005 0.005 0.002 1.493

82.159 1678-91-7 Ethylcyclohexane 0.016 0.016 0.007 5.021

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.621 115-11-7 Isobutene 0.073 0.095 0.065 22.829

9.662 106-98-9 Butene-1 0.055 0.071 0.049 17.123 10.506 624-64-6 t-Butene-2 0.107 0.137 0.096 33.454 11.247 590-18-1 c-Butene-2 0.066 0.082 0.059 20.543 16.723 109-67-1 Pentene-1 0.008 0.010 0.006 2.513 19.225 646-04-8 t-Pentene-2 0.019 0.022 0.013 5.850 20.258 627-20-3 c-Pentene-2 0.010 0.012 0.007 3.111

Iso-Olefins 17.574 563-46-2 2-Methylbutene-1 0.014 0.017 0.010 4.365

20.935 513-35-9 2-Methylbutene-2 0.027 0.032 0.019 8.449 37.397 625-27-4 2-Methylpentene-2 0.009 0.010 0.005 2.835 40.078 3404-73-7 3,3-Dimethylpentene-1 0.009 0.010 0.004 2.745 47.219 3524-73-0 5-Methylhexene-1 0.022 0.024 0.011 6.770 54.670 2-Ethylpentene-1 0.025 0.028 0.013 7.944

Naphtheno-Olefins Di-Olefins Oxygenates 13.405 64-17-5 Ethanol 82.109 80.620 89.603 10578.776

Unidentified 7.476 Unidentified 0.001 0.002 0.001 0.379

63.330 Unidentified 0.196 0.211 0.090 75.213

Plus

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF20.015.010.05.00.0

Unidentified Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane

t-Pentene-2

c-Pentene-2 2-Methylbutene-2

2,2-Dimethylbutane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF45.040.035.030.025.0

Cyclopentane
2,3-Dimethylbutane

2-Methylpentane

3-Methylpentane

n-Hexane

2-Methylpentene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane

Benzene

5-Methylhexene-1 Cyclohexane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF70.065.060.055.050.0 2-Methylhexane

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane 2-Ethylpentene-1 2,2,4-Trimethylpentane

n-Heptane

Methylcyclohexane

2,2-Dimethylhexane Unidentified
Ethylcyclopentane
2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane 3,3-Dimethylhexane

2,3,4-Trimethylpentane Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane

3-Methylheptane 3-Ethylhexane

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane 3c-Ethylmethylcyclopentane

n-Octane

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane

2,5-Dimethylheptane

Ethylbenzene

m-Xylene p-Xylene

4-Methyloctane 2-Methyloctane Heptane, 3-ethyl- 3-Methyloctane o-Xylene C10 - IsoParaffin - 1

n-Nonane

i-Propylbenzene

n-Propylbenzene
1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene

2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF120.0115.0110.0105.0100.0
1,2,4-Trimethylbenzene

n-Decane

1,2,3-Trimethylbenzene

Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene

1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 1,4,Dimethyl-2-ethylbenzene 1,3-Dimethyl-4-ethylbenzene 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene

1,2-Dimethyl-3-ethylbenzene n-Undecane 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene

5-Methylindan
4-Methylindan 2-Methylindan

Naphthalene

2-Methylnaphthalene

1-Methylnaphthalene

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25-Aug-10, 23:27:47 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF Sample: ODDB-91333 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91333 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000015.D\SIG2000015_FID2_B.CDF145.0140.0135.0130.0125.0

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 3.648 4.505 4.628

I-Paraffins 33.536 38.748 34.013

Aromatics 42.295 36.165 32.537 Mono-Aromatics 40.946 35.096 31.657 Naphthalenes 0.185 0.135 0.118 Naphtheno/Olefino-Benzs 0.327 0.274 0.204 Indenes 0.837 0.661 0.557

Naphthenes 1.465 1.456 1.471 Mono-Naphthenes 1.465 1.456 1.471 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.367 8.109 7.962 n-Olefins 3.084 3.481 3.432 Iso-Olefins 3.516 3.888 3.710 Naphtheno-Olefins 0.725 0.696 0.772 Di-Olefins 0.042 0.045 0.048

Oxygenates 10.419 9.834 18.599

Unidentified 1.270 1.182 0.790

Plus 0.000 0.000 0.000

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 10.286 9.710 18.431 C3 0.077 0.072 0.106 C4 2.499 3.184 3.542 C5 17.835 21.096 20.549 C6 23.350 25.952 22.530 C7 14.022 12.449 12.442 C8 12.205 10.510 9.486 C9 12.010 10.266 8.250 C10 4.945 4.214 3.065 C11 1.263 1.163 0.687 C12 0.240 0.202 0.122

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C4 2.216 2.852 3.148 C5 0.832 0.990 0.952 C6 0.415 0.469 0.398 C7 0.091 0.100 0.075 C8 0.020 0.021 0.014 C10 0.039 0.040 0.023 C11 0.034 0.034 0.018

I-Paraffins C4 0.027 0.037 0.039 C5 12.911 15.523 14.772 C6 18.731 21.232 17.943 C7 0.833 0.913 0.687 C8 0.045 0.047 0.032 C10 0.402 0.410 0.231 C11 0.574 0.575 0.303 C12 0.011 0.011 0.005

Mono-Aromatics C6 0.712 0.603 0.752 C7 12.074 10.373 10.817 C8 12.140 10.442 9.440 C9 11.874 10.161 8.155 C10 3.346 2.843 2.058 C11 0.581 0.492 0.323 C12 0.219 0.183 0.111

Naphthalenes C10 0.171 0.124 0.110 C11 0.015 0.011 0.008

Naphtheno/Olefino-Benzs C10 0.327 0.274 0.204

Indenes C9 0.135 0.105 0.095 C10 0.660 0.524 0.439 C11 0.031 0.024 0.018 C12 0.010 0.008 0.006

Mono-Naphthenes C5 0.375 0.374 0.441 C6 0.811 0.805 0.796 C7 0.279 0.277 0.235

n-Olefins C4 0.199 0.243 0.293 C5 1.698 1.950 1.999 C6 1.063 1.158 1.042

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  n-Olefins C7 0.096 0.102 0.081 C11 0.028 0.028 0.016

Iso-Olefins C5 1.782 2.026 2.097 C6 1.102 1.192 1.081 C7 0.632 0.670 0.532

Naphtheno-Olefins C5 0.210 0.203 0.255 C6 0.515 0.493 0.518

Di-Olefins C5 0.027 0.029 0.033 C7 0.015 0.015 0.015

Oxygenates C2 10.286 9.710 18.431 C3 0.077 0.072 0.106 C4 0.056 0.052 0.063

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 22.72 22.20 5% 79.36 79.11 10% 80.61 80.16 15% 81.87 81.20 20% 111.52 88.92 25% 138.02 126.40 30% 139.43 138.13 35% 144.11 139.37 40% 148.77 143.79 45% 172.39 145.53 50% 172.91 170.61 55% 191.00 172.77 60% 223.52 174.24 65% 228.11 222.92 70% 272.95 228.26 75% 281.53 277.87 80% 289.20 281.91 85% 323.48 321.57 90% 335.37 334.25 95% 363.20 359.41 FBP 404.60 404.60

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 8.809 75-28-5 I4 i-Butane 0.027 0.037 0.039 6.805 2 9.623 115-11-7 K4 Isobutene 0.017 0.021 0.024 4.281 3 9.665 106-98-9 K4 Butene-1 0.018 0.023 0.027 4.773 4 10.023 106-97-8 P4 n-Butane 2.216 2.852 3.148 552.220 5 10.510 624-64-6 K4 t-Butene-2 0.075 0.093 0.111 19.435 6 10.638 463-82-1 I5 2,2-Dimethylpropane 0.028 0.035 0.031 6.902 7 11.251 590-18-1 K4 c-Butene-2 0.089 0.107 0.131 22.971 8 13.050 64-17-5 X2 Ethanol 10.286 9.710 18.431 1093.007 9 13.455 563-45-1 C5 3-Methylbutene-1 0.184 0.218 0.216 47.445 10 15.097 78-78-4 I5 i-Pentane 12.884 15.488 14.741 3232.534

11 16.734 109-67-1 K5 Pentene-1 0.345 0.401 0.406 88.991 12 17.587 563-46-2 C5 2-Methylbutene-1 0.524 0.600 0.617 135.298 13 18.116 109-66-0 P5 n-Pentane 0.832 0.990 0.952 208.786 14 18.633 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 2.853 15 19.239 646-04-8 K5 t-Pentene-2 0.874 1.005 1.029 225.599 16 19.882 ? Unidentified 0.006 0.007 0.007 1.934 17 20.268 627-20-3 K5 c-Pentene-2 0.479 0.544 0.564 123.646 18 20.950 513-35-9 C5 2-Methylbutene-2 1.074 1.207 1.264 277.069 19 21.279 2004-70-8 E5 1t,3-Pentadiene 0.016 0.018 0.020 4.276 20 22.540 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.009 1.931

21 23.093 75-83-2 I6 2,2-Dimethylbutane 0.520 0.597 0.498 130.983 22 25.745 142-29-0 B5 Cyclopentene 0.203 0.195 0.246 53.820 23 26.904 71-23-8 X3 n-Propanol 0.077 0.072 0.106 13.895 24 27.005 ? Unidentified 0.062 0.069 0.060 19.450 25 27.607 287-92-3 M5 Cyclopentane 0.375 0.374 0.441 96.657 26 28.353 79-29-8 I6 2,3-Dimethylbutane 1.877 2.113 1.798 472.714 27 28.748 ? Unidentified 0.054 0.054 0.051 17.060 28 29.207 691-38-3 C6 4-Methyl-c-pentene-2 0.046 0.051 0.045 11.836 29 29.474 107-83-5 I6 2-Methylpentane 10.806 12.324 10.351 2721.985 30 29.857 674-76-0 C6 4-Methyl-t-pentene-2 0.134 0.148 0.132 34.623

31 32.101 96-14-0 I6 3-Methylpentane 5.529 6.199 5.296 1392.728 32 33.239 763-29-1 C6 2-Methylpentene-1 0.230 0.250 0.226 59.348 33 33.460 592-41-6 K6 Hexene-1 0.164 0.180 0.161 42.260 34 35.645 760-21-4 C6 2-Ethylbutene-1 0.074 0.080 0.073 19.187 35 35.807 110-54-3 P6 n-Hexane 0.415 0.469 0.398 104.594 36 36.443 13269-52-8 K6 t-Hexene-3 0.269 0.293 0.264 69.349 37 36.921 4050-45-7 K6 t-Hexene-2 0.411 0.449 0.404 106.182 38 37.048 1120-62-3 B6 3-Methylcyclopentene 0.104 0.101 0.104 26.770 39 37.413 625-27-4 C6 2-Methylpentene-2 0.349 0.376 0.342 89.939 40 37.828 922-62-3 C6 3-Methyl-c-pentene-2 0.269 0.287 0.264 69.485

41 38.748 7688-21-3 K6 c-Hexene-2 0.219 0.236 0.215 56.473 42 40.094 3404-73-7 C7 3,3-Dimethylpentene-1 0.316 0.335 0.266 81.530 43 40.674 96-37-7 M6 Methylcyclopentane 0.746 0.743 0.732 192.624

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 42.246 108-08-7 I7 2,4-Dimethylpentane 0.149 0.165 0.123 37.719 45 42.544 594-56-9 C7 2,3,3-Trimethylbutene-1 0.010 0.010 0.008 2.467 46 45.435 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.015 3.958 47 45.645 71-42-3 Q6 Benzene 0.712 0.603 0.752 197.767 48 45.839 693-89-0 B6 1-Methylcyclopentene 0.366 0.350 0.368 96.741 49 46.649 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.013 4.014 50 47.234 3524-73-0 C7 5-Methylhexene-1 0.023 0.024 0.019 5.891 51 47.557 110-82-7 M6 Cyclohexane 0.065 0.062 0.064 16.744 52 48.061 71-36-3 X4 n-Butanol 0.056 0.052 0.063 10.967 53 49.278 15840-60-5 C7 2-Methyl-c-hexene-3 0.041 0.044 0.035 10.648

54 49.626 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.009 2.828 55 50.272 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.052 0.055 0.043 13.320 56 50.665 591-76-4 I7 2-Methylhexane 0.407 0.447 0.335 102.965 57 50.847 ? Unidentified 0.020 0.022 0.017 6.343 58 51.158 110-83-8 B6 Cyclohexene 0.045 0.042 0.046 11.738 59 52.498 589-34-4 I7 3-Methylhexane 0.277 0.300 0.228 70.106 60 53.360 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.096 0.096 0.081 24.869 61 53.946 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.064 0.064 0.054 16.633 62 54.569 822-50-4 M7 1t,2-Dimethylcyclopentane 0.058 0.058 0.049 15.086 63 54.849 C7 C7 - Iso-Olefin - 2 0.023 0.024 0.019 5.866

64 55.475 592-76-7 K7 Heptene-1 0.028 0.030 0.024 7.257 65 56.808 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.625 66 57.338 14686-14-7 K7 t-Heptene-3 0.032 0.034 0.027 8.202 67 57.690 6094-02-6 C7 2-Methylhexene-1 0.056 0.060 0.047 14.491 68 58.060 142-82-5 P7 n-Heptane 0.091 0.100 0.075 23.135 69 58.280 7642-10-6 K7 c-Heptene-3 0.024 0.026 0.020 6.264 70 58.555 2738-19-4 C7 2-Methyl-2-hexene 0.025 0.026 0.021 6.456 71 58.799 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.020 0.016 5.028 72 59.182 14686-13-6 K7 t-Heptene-2 0.012 0.013 0.010 3.067 73 59.657 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 4.736

74 60.080 20710-38-8 C7 3-Methyl-t-hexene-2 0.014 0.015 0.012 3.723 75 60.865 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.326 76 61.506 108-87-2 M7 Methylcyclohexane 0.042 0.040 0.035 10.727 77 63.401 ? Unidentified 0.024 0.025 0.018 7.719 78 69.076 108-88-3 Q7 Toluene 12.074 10.373 10.817 3319.113 79 72.051 592-27-8 I8 2-Methylheptane 0.017 0.018 0.012 4.247 80 72.304 589-53-7 I8 4-Methylheptane 0.009 0.010 0.007 2.396 81 73.365 589-81-1 I8 3-Methylheptane 0.018 0.019 0.013 4.670 82 77.873 111-65-9 P8 n-Octane 0.020 0.021 0.014 4.996 83 84.745 100-41-4 Q8 Ethylbenzene 2.190 1.881 1.703 597.451

84 85.987 108-38-3 Q8 m-Xylene 5.749 4.955 4.470 1568.548 85 86.128 106-42-3 Q8 p-Xylene 2.663 2.304 2.071 726.622 86 88.939 95-47-6 Q8 o-Xylene 1.538 1.301 1.196 419.492

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 93.098 98-82-8 Q9 i-Propylbenzene 0.033 0.028 0.023 8.880 88 95.511 2051-30-1 I10 2,4-Dimethyloctane 0.007 0.007 0.004 1.770 89 96.560 103-65-1 Q9 n-Propylbenzene 0.650 0.562 0.446 176.160 90 97.418 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.697 2.324 1.852 731.111 91 97.648 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.258 1.088 0.864 340.892 92 98.273 108-67-8 Q9 1,3,5-Trimethylbenzene 1.623 1.397 1.115 439.949 93 98.726 15869-85-9 I10 5-Methylnonane 0.011 0.011 0.006 2.827 94 98.915 17301-94-8 I10 4-Methylnonane 0.027 0.027 0.016 6.863 95 99.120 I10 2,2,6-Trimethyloctane 0.253 0.259 0.147 64.384 96 99.353 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.898 0.760 0.617 243.466

97 99.570 5881-17-4 I10 3-Ethyloctane 0.008 0.008 0.005 1.975 98 99.891 5911-04-6 I10 3-Methylnonane 0.042 0.042 0.024 10.561 99 100.356 ? Unidentified 0.016 0.012 0.008 5.086 100 100.489 ? Unidentified 0.048 0.048 0.025 15.084 101 100.702 I11 C11-Isoparaffin-2 0.026 0.026 0.014 6.682 102 101.001 95-63-6 Q9 1,2,4-Trimethylbenzene 4.291 3.649 2.947 1163.089 103 101.167 ? Unidentified 0.034 0.036 0.020 10.723 104 101.288 ? Unidentified 0.019 0.020 0.011 6.145 105 102.339 17302-01-1 I10 3-Ethyl-3-methylheptane 0.055 0.055 0.029 13.971 106 102.628 538-93-2 Q10 i-Butylbenzene 0.085 0.074 0.052 22.871

107 102.806 124-18-5 P10 n-Decane 0.039 0.040 0.023 9.913 108 102.904 ? Unidentified 0.032 0.027 0.019 10.000 109 103.201 ? Unidentified 0.015 0.015 0.008 4.695 110 103.853 526-73-8 Q9 1,2,3-Trimethylbenzene 0.425 0.354 0.292 115.180 111 104.234 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.010 0.009 0.006 2.715 112 104.413 I11 C11 Isoparaffin-4 0.009 0.009 0.005 2.283 113 104.618 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.065 0.057 0.040 17.541 114 105.047 J9 Indan 0.135 0.105 0.095 37.283 115 105.641 J10 Indene 0.368 0.285 0.257 101.478 116 106.356 I11 C11-Isoparaffin-7 0.161 0.162 0.085 41.103

117 106.550 141-93-5 Q10 1,3-Diethylbenzene 0.038 0.033 0.024 10.361 118 106.833 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.590 0.510 0.363 159.044 119 107.166 105-05-5 Q10 1,4-Diethylbenzene 0.245 0.212 0.151 66.072 120 107.385 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.190 0.161 0.117 51.327 121 107.628 135-01-3 Q10 1,2-Diethylbenzene 0.044 0.037 0.027 11.820 122 108.083 ? Unidentified 0.042 0.042 0.022 13.315 123 108.235 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.072 0.062 0.044 19.503 124 108.358 ? Unidentified 0.049 0.049 0.026 15.380 125 108.438 ? Unidentified 0.045 0.045 0.024 14.313 126 108.565 I11 C11- Isoparaffin-11 0.378 0.378 0.200 96.240

127 108.747 ? Unidentified 0.122 0.123 0.065 38.687 128 109.082 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.160 0.136 0.099 43.236 129 109.170 ? Unidentified 0.490 0.416 0.301 154.966

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 109.397 J10 2-Methylindan 0.073 0.057 0.046 20.219 131 109.744 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.471 0.401 0.289 126.903 132 110.288 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.354 0.296 0.218 95.396 133 110.712 ? Unidentified 0.010 0.010 0.006 3.315 134 110.907 693-61-8 K11 2-Undecene, (E)- 0.028 0.028 0.016 7.032 135 111.040 ? Unidentified 0.052 0.052 0.031 16.400 136 111.195 Q11 1-Methyl-4-t-butylbenzene 0.029 0.025 0.016 7.809 137 111.316 ? Unidentified 0.053 0.044 0.030 16.787 138 111.417 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.117 0.098 0.072 31.536 139 111.712 1120-21-4 P11 n-Undecane 0.034 0.034 0.018 8.659

140 111.865 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.045 0.038 0.025 12.199 141 111.975 ? Unidentified 0.024 0.020 0.014 7.681 142 112.351 Q10 1,2,4,5-Tetramethylbenzene 0.379 0.318 0.233 102.212 143 112.617 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.525 0.439 0.323 141.640 144 112.959 ? Unidentified 0.013 0.010 0.007 4.086 145 113.133 I12 C12 - IsoParaffin - 1 0.011 0.011 0.005 2.821 146 113.484 ? Unidentified 0.024 0.024 0.011 7.467 147 113.757 Q11 C11 - Aromatic - 3 0.064 0.054 0.036 17.194 148 113.947 874-35-1 H10 5-Methylindan 0.164 0.138 0.103 44.325 149 114.072 Q12 1,2-Di-i-propylbenzene 0.059 0.050 0.030 15.887

150 114.287 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.084 0.071 0.047 22.642 151 114.443 Q11 C11 - Aromatic - 4 0.048 0.040 0.026 12.772 152 114.697 824-22-6 J10 4-Methylindan 0.218 0.183 0.136 58.850 153 114.848 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.051 0.042 0.028 13.633 154 114.944 824-63-5 H10 2-Methylindan 0.163 0.136 0.101 43.821 155 115.147 ? Unidentified 0.015 0.013 0.009 4.850 156 115.260 538-68-1 Q11 n-Pentylbenzene 0.020 0.017 0.011 5.378 157 115.486 Q11 tert-Pentylbenzene 0.089 0.074 0.049 23.773 158 115.800 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.039 0.033 0.022 10.571 159 115.909 Q11 C11 - Aromatic - 7 0.049 0.043 0.028 13.270

160 116.370 100-18-5 Q12 1,4-Di-i-propylbenzene 0.074 0.062 0.037 19.711 161 116.814 91-20-3 G10 Naphthalene 0.171 0.124 0.110 48.212 162 117.008 J11 4,7-Dimethyl Indane 0.009 0.007 0.005 2.362 163 117.252 J11 1,1-Dimethyl Indane 0.023 0.018 0.013 6.308 164 117.414 J12 Dimethyl Indane - 1 0.010 0.008 0.006 2.783 165 117.594 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.014 0.012 0.007 3.784 166 117.896 Q12 1,3-Di-n-propylbenzene 0.065 0.055 0.033 17.435 167 118.006 Q11 C11 - Aromatic - 11 0.037 0.033 0.021 9.982 168 118.560 Q11 C11 - Aromatic - 12 0.025 0.022 0.014 6.718 169 119.488 102-25-0 Q12 1,3,5-Triethylbenzene 0.007 0.005 0.003 1.752

170 123.441 91-57-6 G11 2-Methylnaphthalene 0.010 0.007 0.005 2.665 171 124.308 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.418

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 10.023 106-97-8 n-Butane 2.216 2.852 3.148 552.220

18.116 109-66-0 n-Pentane 0.832 0.990 0.952 208.786 35.807 110-54-3 n-Hexane 0.415 0.469 0.398 104.594 58.060 142-82-5 n-Heptane 0.091 0.100 0.075 23.135 77.873 111-65-9 n-Octane 0.020 0.021 0.014 4.996 102.806 124-18-5 n-Decane 0.039 0.040 0.023 9.913 111.712 1120-21-4 n-Undecane 0.034 0.034 0.018 8.659

I-Paraffins 8.809 75-28-5 i-Butane 0.027 0.037 0.039 6.805

10.638 463-82-1 2,2-Dimethylpropane 0.028 0.035 0.031 6.902 15.097 78-78-4 i-Pentane 12.884 15.488 14.741 3232.534 23.093 75-83-2 2,2-Dimethylbutane 0.520 0.597 0.498 130.983 28.353 79-29-8 2,3-Dimethylbutane 1.877 2.113 1.798 472.714 29.474 107-83-5 2-Methylpentane 10.806 12.324 10.351 2721.985 32.101 96-14-0 3-Methylpentane 5.529 6.199 5.296 1392.728 42.246 108-08-7 2,4-Dimethylpentane 0.149 0.165 0.123 37.719 50.665 591-76-4 2-Methylhexane 0.407 0.447 0.335 102.965 52.498 589-34-4 3-Methylhexane 0.277 0.300 0.228 70.106 72.051 592-27-8 2-Methylheptane 0.017 0.018 0.012 4.247 72.304 589-53-7 4-Methylheptane 0.009 0.010 0.007 2.396 73.365 589-81-1 3-Methylheptane 0.018 0.019 0.013 4.670 95.511 2051-30-1 2,4-Dimethyloctane 0.007 0.007 0.004 1.770 98.726 15869-85-9 5-Methylnonane 0.011 0.011 0.006 2.827 98.915 17301-94-8 4-Methylnonane 0.027 0.027 0.016 6.863 99.120 2,2,6-Trimethyloctane 0.253 0.259 0.147 64.384 99.570 5881-17-4 3-Ethyloctane 0.008 0.008 0.005 1.975 99.891 5911-04-6 3-Methylnonane 0.042 0.042 0.024 10.561 100.702 C11-Isoparaffin-2 0.026 0.026 0.014 6.682 102.339 17302-01-1 3-Ethyl-3-methylheptane 0.055 0.055 0.029 13.971 104.413 C11 Isoparaffin-4 0.009 0.009 0.005 2.283 106.356 C11-Isoparaffin-7 0.161 0.162 0.085 41.103 108.565 C11- Isoparaffin-11 0.378 0.378 0.200 96.240 113.133 C12 - IsoParaffin - 1 0.011 0.011 0.005 2.821

Aromatics Mono-Aromatics 45.645 71-42-3 Benzene 0.712 0.603 0.752 197.767

69.076 108-88-3 Toluene 12.074 10.373 10.817 3319.113 84.745 100-41-4 Ethylbenzene 2.190 1.881 1.703 597.451 85.987 108-38-3 m-Xylene 5.749 4.955 4.470 1568.548 86.128 106-42-3 p-Xylene 2.663 2.304 2.071 726.622 88.939 95-47-6 o-Xylene 1.538 1.301 1.196 419.492 93.098 98-82-8 i-Propylbenzene 0.033 0.028 0.023 8.880 96.560 103-65-1 n-Propylbenzene 0.650 0.562 0.446 176.160 97.418 620-14-4 1-Methyl-3-ethylbenzene 2.697 2.324 1.852 731.111 97.648 622-96-8 1-Methyl-4-ethylbenzene 1.258 1.088 0.864 340.892 98.273 108-67-8 1,3,5-Trimethylbenzene 1.623 1.397 1.115 439.949 99.353 611-14-3 1-Methyl-2-ethylbenzene 0.898 0.760 0.617 243.466

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 101.001 95-63-6 1,2,4-Trimethylbenzene 4.291 3.649 2.947 1163.089

102.628 538-93-2 i-Butylbenzene 0.085 0.074 0.052 22.871 103.853 526-73-8 1,2,3-Trimethylbenzene 0.425 0.354 0.292 115.180 104.234 535-77-3 1-Methyl-3-i-propylbenzene 0.010 0.009 0.006 2.715 104.618 99-87-6 1-Methyl-4-i-propylbenzene 0.065 0.057 0.040 17.541 106.550 141-93-5 1,3-Diethylbenzene 0.038 0.033 0.024 10.361 106.833 1074-43-7 1-Methyl-3-n-propylbenzene 0.590 0.510 0.363 159.044 107.166 105-05-5 1,4-Diethylbenzene 0.245 0.212 0.151 66.072 107.385 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.190 0.161 0.117 51.327 107.628 135-01-3 1,2-Diethylbenzene 0.044 0.037 0.027 11.820 108.235 1074-17-5 1-Methyl-2-n-propylbenzene 0.072 0.062 0.044 19.503 109.082 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.160 0.136 0.099 43.236 109.744 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.471 0.401 0.289 126.903 110.288 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.354 0.296 0.218 95.396 111.195 1-Methyl-4-t-butylbenzene 0.029 0.025 0.016 7.809 111.417 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.117 0.098 0.072 31.536 111.865 4218-48-8 1-Ethyl-4-i-propylbenzene 0.045 0.038 0.025 12.199 112.351 1,2,4,5-Tetramethylbenzene 0.379 0.318 0.233 102.212 112.617 527-53-7 1,2,3,5-Tetramethylbenzene 0.525 0.439 0.323 141.640 113.757 C11 - Aromatic - 3 0.064 0.054 0.036 17.194 114.072 1,2-Di-i-propylbenzene 0.059 0.050 0.030 15.887 114.287 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.084 0.071 0.047 22.642 114.443 C11 - Aromatic - 4 0.048 0.040 0.026 12.772 114.848 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.051 0.042 0.028 13.633 115.260 538-68-1 n-Pentylbenzene 0.020 0.017 0.011 5.378 115.486 tert-Pentylbenzene 0.089 0.074 0.049 23.773 115.800 577-55-9 1-Methyl-2-n-butylbenzene 0.039 0.033 0.022 10.571 115.909 C11 - Aromatic - 7 0.049 0.043 0.028 13.270 116.370 100-18-5 1,4-Di-i-propylbenzene 0.074 0.062 0.037 19.711 117.594 7364-19-4 1t-Butyl-4-ethylbenzene 0.014 0.012 0.007 3.784 117.896 1,3-Di-n-propylbenzene 0.065 0.055 0.033 17.435 118.006 C11 - Aromatic - 11 0.037 0.033 0.021 9.982 118.560 C11 - Aromatic - 12 0.025 0.022 0.014 6.718 119.488 102-25-0 1,3,5-Triethylbenzene 0.007 0.005 0.003 1.752

Naphthalenes 116.814 91-20-3 Naphthalene 0.171 0.124 0.110 48.212

123.441 91-57-6 2-Methylnaphthalene 0.010 0.007 0.005 2.665 124.308 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.418

Naphtheno/Olefino-Benzs

113.947 874-35-1 5-Methylindan 0.164 0.138 0.103 44.325 114.944 824-63-5 2-Methylindan 0.163 0.136 0.101 43.821

Indenes 105.047 Indan 0.135 0.105 0.095 37.283

105.641 Indene 0.368 0.285 0.257 101.478 109.397 2-Methylindan 0.073 0.057 0.046 20.219 114.697 824-22-6 4-Methylindan 0.218 0.183 0.136 58.850 117.008 4,7-Dimethyl Indane 0.009 0.007 0.005 2.362

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Indenes 117.252 1,1-Dimethyl Indane 0.023 0.018 0.013 6.308

117.414 Dimethyl Indane - 1 0.010 0.008 0.006 2.783

Naphthenes Mono-Naphthenes 27.607 287-92-3 Cyclopentane 0.375 0.374 0.441 96.657

40.674 96-37-7 Methylcyclopentane 0.746 0.743 0.732 192.624 47.557 110-82-7 Cyclohexane 0.065 0.062 0.064 16.744 53.360 1759-58-6 1t,3-Dimethylcyclopentane 0.096 0.096 0.081 24.869 53.946 2532-58-3 1c,3-Dimethylcyclopentane 0.064 0.064 0.054 16.633 54.569 822-50-4 1t,2-Dimethylcyclopentane 0.058 0.058 0.049 15.086 59.657 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.018 0.018 0.015 4.736 61.506 108-87-2 Methylcyclohexane 0.042 0.040 0.035 10.727

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.623 115-11-7 Isobutene 0.017 0.021 0.024 4.281

9.665 106-98-9 Butene-1 0.018 0.023 0.027 4.773 10.510 624-64-6 t-Butene-2 0.075 0.093 0.111 19.435 11.251 590-18-1 c-Butene-2 0.089 0.107 0.131 22.971 16.734 109-67-1 Pentene-1 0.345 0.401 0.406 88.991 19.239 646-04-8 t-Pentene-2 0.874 1.005 1.029 225.599 20.268 627-20-3 c-Pentene-2 0.479 0.544 0.564 123.646 33.460 592-41-6 Hexene-1 0.164 0.180 0.161 42.260 36.443 13269-52-8 t-Hexene-3 0.269 0.293 0.264 69.349 36.921 4050-45-7 t-Hexene-2 0.411 0.449 0.404 106.182 38.748 7688-21-3 c-Hexene-2 0.219 0.236 0.215 56.473 55.475 592-76-7 Heptene-1 0.028 0.030 0.024 7.257 57.338 14686-14-7 t-Heptene-3 0.032 0.034 0.027 8.202 58.280 7642-10-6 c-Heptene-3 0.024 0.026 0.020 6.264 59.182 14686-13-6 t-Heptene-2 0.012 0.013 0.010 3.067 110.907 693-61-8 2-Undecene, (E)- 0.028 0.028 0.016 7.032

Iso-Olefins 13.455 563-45-1 3-Methylbutene-1 0.184 0.218 0.216 47.445

17.587 563-46-2 2-Methylbutene-1 0.524 0.600 0.617 135.298 20.950 513-35-9 2-Methylbutene-2 1.074 1.207 1.264 277.069 29.207 691-38-3 4-Methyl-c-pentene-2 0.046 0.051 0.045 11.836 29.857 674-76-0 4-Methyl-t-pentene-2 0.134 0.148 0.132 34.623 33.239 763-29-1 2-Methylpentene-1 0.230 0.250 0.226 59.348 35.645 760-21-4 2-Ethylbutene-1 0.074 0.080 0.073 19.187 37.413 625-27-4 2-Methylpentene-2 0.349 0.376 0.342 89.939 37.828 922-62-3 3-Methyl-c-pentene-2 0.269 0.287 0.264 69.485 40.094 3404-73-7 3,3-Dimethylpentene-1 0.316 0.335 0.266 81.530 42.544 594-56-9 2,3,3-Trimethylbutene-1 0.010 0.010 0.008 2.467 46.649 3404-61-3 3-Methylhexene-1 0.016 0.017 0.013 4.014 47.234 3524-73-0 5-Methylhexene-1 0.023 0.024 0.019 5.891 49.278 15840-60-5 2-Methyl-c-hexene-3 0.041 0.044 0.035 10.648 49.626 3769-23-1 4-Methylhexene-1 0.011 0.012 0.009 2.828

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Iso-Olefins 50.272 3404-55-5 4-Methyl-t/c-hexene-2 0.052 0.055 0.043 13.320

54.849 C7 - Iso-Olefin - 2 0.023 0.024 0.019 5.866 56.808 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.012 3.625 57.690 6094-02-6 2-Methylhexene-1 0.056 0.060 0.047 14.491 58.555 2738-19-4 2-Methyl-2-hexene 0.025 0.026 0.021 6.456 58.799 10574-36-4 3-Methyl-c-hexene-2 0.019 0.020 0.016 5.028 60.080 20710-38-8 3-Methyl-t-hexene-2 0.014 0.015 0.012 3.723 60.865 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.013 0.011 3.326

Naphtheno-Olefins 22.540 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.009 1.931

25.745 142-29-0 Cyclopentene 0.203 0.195 0.246 53.820 37.048 1120-62-3 3-Methylcyclopentene 0.104 0.101 0.104 26.770 45.839 693-89-0 1-Methylcyclopentene 0.366 0.350 0.368 96.741 51.158 110-83-8 Cyclohexene 0.045 0.042 0.046 11.738

Di-Olefins 18.633 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.013 2.853

21.279 2004-70-8 1t,3-Pentadiene 0.016 0.018 0.020 4.276 45.435 1528-30-9 C6-Diolefin-1 0.015 0.015 0.015 3.958

Oxygenates 13.050 64-17-5 Ethanol 10.286 9.710 18.431 1093.007

26.904 71-23-8 n-Propanol 0.077 0.072 0.106 13.895 48.061 71-36-3 n-Butanol 0.056 0.052 0.063 10.967

Unidentified 19.882 Unidentified 0.006 0.007 0.007 1.934

27.005 Unidentified 0.062 0.069 0.060 19.450 28.748 Unidentified 0.054 0.054 0.051 17.060 50.847 Unidentified 0.020 0.022 0.017 6.343 63.401 Unidentified 0.024 0.025 0.018 7.719 100.356 Unidentified 0.016 0.012 0.008 5.086 100.489 Unidentified 0.048 0.048 0.025 15.084 101.167 Unidentified 0.034 0.036 0.020 10.723 101.288 Unidentified 0.019 0.020 0.011 6.145 102.904 Unidentified 0.032 0.027 0.019 10.000 103.201 Unidentified 0.015 0.015 0.008 4.695 108.083 Unidentified 0.042 0.042 0.022 13.315 108.358 Unidentified 0.049 0.049 0.026 15.380 108.438 Unidentified 0.045 0.045 0.024 14.313 108.747 Unidentified 0.122 0.123 0.065 38.687 109.170 Unidentified 0.490 0.416 0.301 154.966 110.712 Unidentified 0.010 0.010 0.006 3.315 111.040 Unidentified 0.052 0.052 0.031 16.400 111.316 Unidentified 0.053 0.044 0.030 16.787 111.975 Unidentified 0.024 0.020 0.014 7.681 112.959 Unidentified 0.013 0.010 0.007 4.086 113.484 Unidentified 0.024 0.024 0.011 7.467 115.147 Unidentified 0.015 0.013 0.009 4.850

Plus

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF20.015.010.05.00.0

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene
t-Pentene-2
Unidentified c-Pentene-2 2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane

2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1 Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1

C6-Diolefin-1 Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2 2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

Unidentified

Toluene

2-Methylheptane 4-Methylheptane

3-Methylheptane

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF95.090.085.080.075.0

n-Octane

Ethylbenzene

m-Xylene p-Xylene

o-Xylene

i-Propylbenzene

2,4-Dimethyloctane

n-Propylbenzene

1-Methyl-3-ethylbenzene 1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane 1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified

3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified 1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene 1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene Unidentified 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene Unidentified C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 7 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane 1,1-Dimethyl Indane Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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26-Aug-10, 15:36:26 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF Sample: ODDB-91334 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91334 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000019.D\SIG2000019_FID2_B.CDF145.0140.0135.0130.0125.0

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Summary by Group

Recovery = 100.00 **Group %Wgt**  **%Vol %Mol** 

Paraffin 4.688 5.657 4.647

I-Paraffins 19.280 22.413 16.416

Aromatics 42.279 37.515 30.678 Mono-Aromatics 40.739 36.253 29.721 Naphthalenes 0.183 0.138 0.110 Naphtheno/Olefino-Benzs 0.325 0.283 0.191 Indenes 1.031 0.842 0.656

Naphthenes 3.320 3.381 2.938 Mono-Naphthenes 3.320 3.381 2.938 Di/Bicyclo-Naphthenes 0.000 0.000 0.000

Olefins 7.121 8.142 7.242 n-Olefins 2.939 3.445 3.081 Iso-Olefins 3.447 3.961 3.423 Naphtheno-Olefins 0.693 0.691 0.694 Di-Olefins 0.041 0.045 0.044

Oxygenates 21.875 21.438 36.824

Unidentified 1.438 1.453 1.255

Plus 0.000 0.000 0.000

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Summary by Carbon

Recovery = 100.00 

### C# **%Wgt %Vol**  **%Mol** C2 21.748 21.315 36.673 C3 0.075 0.073 0.098 C4 0.867 1.127 1.153 C5 9.339 11.313 10.185 C6 16.286 18.463 14.855 C7 16.039 14.994 13.321 C8 13.867 12.747 10.049 C9 11.815 10.625 7.607 C10 7.003 6.446 4.035 C11 1.266 1.219 0.647 C12 0.257 0.224 0.123

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Paraffin C3 0.002 0.003 0.004 C4 0.597 0.797 0.797 C5 1.763 2.178 1.899 C6 1.573 1.845 1.418 C7 0.376 0.425 0.292 C8 0.201 0.221 0.136 C9 0.110 0.118 0.066 C10 0.040 0.042 0.022 C11 0.027 0.028 0.014

I-Paraffins C4 0.025 0.035 0.034 C5 3.668 4.578 3.949 C6 9.602 11.302 8.656 C7 1.318 1.498 1.022 C8 1.536 1.672 1.044 C9 0.671 0.730 0.406 C10 1.824 1.936 0.988 C11 0.631 0.655 0.313 C12 0.005 0.005 0.002

Mono-Aromatics C6 0.734 0.646 0.730 C7 12.625 11.261 10.644 C8 11.926 10.650 8.727 C9 10.809 9.596 6.987 C10 3.834 3.389 2.219 C11 0.569 0.501 0.298 C12 0.242 0.211 0.116

Naphthalenes C10 0.169 0.128 0.103 C11 0.014 0.011 0.008

Naphtheno/Olefino-Benzs C10 0.325 0.283 0.191

Indenes C9 0.219 0.175 0.144 C10 0.794 0.651 0.503 C11 0.009 0.007 0.005 C12 0.010 0.008 0.005

Mono-Naphthenes C5 0.305 0.316 0.338 C6 1.822 1.858 1.682 C7 0.965 0.980 0.763 C8 0.204 0.204 0.141

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Composite by Carbon

Recovery = 100.00 

### Group **C# %Wgt**  **%Vol %Mol**  Mono-Naphthenes C9 0.007 0.006 0.004 C10 0.018 0.018 0.010

n-Olefins C4 0.191 0.242 0.265 C5 1.616 1.926 1.790 C6 1.017 1.151 0.939 C7 0.099 0.109 0.078 C11 0.017 0.017 0.009

Iso-Olefins C5 1.762 2.084 1.951 C6 1.044 1.172 0.964 C7 0.641 0.706 0.508

Naphtheno-Olefins C5 0.200 0.201 0.228 C6 0.493 0.490 0.466

Di-Olefins C5 0.026 0.030 0.030 C7 0.015 0.015 0.014

Oxygenates C2 21.748 21.315 36.673 C3 0.073 0.070 0.094 C4 0.054 0.053 0.057

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Calculated Boiling Point

Recovery = 100.00 

### %Off **WBP(F) VBP(F)**  IBP 28.34 26.13 5% 83.73 81.27 10% 111.94 97.25 15% 139.18 137.76 20% 145.62 140.07 25% 161.49 152.27 30% 172.44 169.42 35% 172.68 172.46 40% 172.93 172.72 45% 173.18 172.97 50% 196.17 173.22 55% 230.80 201.59 60% 230.94 230.82 65% 231.16 230.98 70% 278.20 257.01 75% 281.80 281.22 80% 318.15 291.63 85% 327.67 323.18 90% 335.83 334.98 95% 363.20 362.49 FBP 404.60 404.60

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 1 7.553 74-98-6 P3 Propane 0.002 0.003 0.004 0.583 2 8.809 75-28-5 I4 i-Butane 0.025 0.035 0.034 6.870 3 9.621 115-11-7 K4 Isobutene 0.016 0.021 0.022 4.502 4 9.662 106-98-9 K4 Butene-1 0.018 0.023 0.024 4.962 5 10.021 106-97-8 P4 n-Butane 0.597 0.797 0.797 162.290 6 10.507 624-64-6 K4 t-Butene-2 0.072 0.092 0.100 20.328 7 10.635 463-82-1 I5 2,2-Dimethylpropane 0.009 0.012 0.010 2.601 8 11.247 590-18-1 K4 c-Butene-2 0.085 0.106 0.118 24.035 9 13.125 64-17-5 X2 Ethanol 21.748 21.315 36.673 2523.196 10 13.445 563-45-1 C5 3-Methylbutene-1 0.245 0.302 0.271 68.928

11 15.073 78-78-4 I5 i-Pentane 3.658 4.566 3.939 1002.166 12 16.725 109-67-1 K5 Pentene-1 0.328 0.396 0.363 92.420 13 17.577 563-46-2 C5 2-Methylbutene-1 0.498 0.592 0.551 140.212 14 18.107 109-66-0 P5 n-Pentane 1.763 2.178 1.899 483.060 15 18.621 78-79-5 E5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 3.164 16 19.228 646-04-8 K5 t-Pentene-2 0.832 0.992 0.921 234.391 17 19.873 ? Unidentified 0.005 0.006 0.006 1.873 18 20.261 627-20-3 K5 c-Pentene-2 0.456 0.538 0.505 128.401 19 20.941 513-35-9 C5 2-Methylbutene-2 1.019 1.190 1.129 287.222 20 21.266 2004-70-8 E5 1t,3-Pentadiene 0.015 0.018 0.018 4.495

21 22.527 1574-41-0 B5 1,3-Cyclopentadiene 0.007 0.008 0.008 1.979 22 23.085 75-83-2 I6 2,2-Dimethylbutane 0.296 0.353 0.267 81.465 23 25.736 142-29-0 B5 Cyclopentene 0.193 0.193 0.220 55.939 24 26.899 71-23-8 X3 n-Propanol 0.073 0.070 0.094 14.306 25 26.983 ? Unidentified 0.059 0.068 0.054 20.285 26 27.596 287-92-3 M5 Cyclopentane 0.305 0.316 0.338 85.857 27 28.336 79-29-8 I6 2,3-Dimethylbutane 1.015 1.187 0.915 279.232 28 28.726 ? Unidentified 0.055 0.057 0.048 18.827 29 29.196 691-38-3 C6 4-Methyl-c-pentene-2 0.044 0.050 0.040 12.346 30 29.429 107-83-5 I6 2-Methylpentane 5.593 6.623 5.042 1538.314

31 29.838 674-76-0 C6 4-Methyl-t-pentene-2 0.128 0.147 0.118 35.957 32 32.074 96-14-0 I6 3-Methylpentane 2.697 3.140 2.431 741.781 33 33.221 763-29-1 C6 2-Methylpentene-1 0.220 0.249 0.203 62.043 34 33.446 592-41-6 K6 Hexene-1 0.158 0.180 0.146 44.508 35 35.633 760-21-4 C6 2-Ethylbutene-1 0.064 0.071 0.059 17.898 36 35.799 110-54-3 P6 n-Hexane 1.573 1.845 1.418 432.616 37 36.435 13269-52-8 K6 t-Hexene-3 0.257 0.291 0.237 72.378 38 36.909 4050-45-7 K6 t-Hexene-2 0.394 0.446 0.363 110.939 39 37.033 1120-62-3 B6 3-Methylcyclopentene 0.098 0.099 0.093 27.611 40 37.401 625-27-4 C6 2-Methylpentene-2 0.333 0.372 0.307 93.747

41 37.815 922-62-3 C6 3-Methyl-c-pentene-2 0.256 0.284 0.237 72.243 42 38.737 7688-21-3 K6 c-Hexene-2 0.209 0.233 0.193 58.832 43 40.080 3404-73-7 C7 3,3-Dimethylpentene-1 0.305 0.336 0.242 86.052

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 44 40.665 96-37-7 M6 Methylcyclopentane 1.205 1.245 1.112 339.547 45 42.235 108-08-7 I7 2,4-Dimethylpentane 0.207 0.238 0.161 57.207 46 42.525 594-56-9 C7 2,3,3-Trimethylbutene-1 0.013 0.015 0.011 3.749 47 42.773 464-06-2 I7 2,2,3-Trimethylbutane 0.020 0.022 0.015 5.432 48 45.422 1528-30-9 E7 C6-Diolefin-1 0.015 0.015 0.014 4.177 49 45.631 71-42-3 Q6 Benzene 0.734 0.646 0.730 222.725 50 45.828 693-89-0 B6 1-Methylcyclopentene 0.351 0.349 0.332 101.379 51 46.634 3404-61-3 C7 3-Methylhexene-1 0.016 0.017 0.012 4.389 52 47.225 3524-73-0 C7 5-Methylhexene-1 0.043 0.048 0.034 12.223 53 47.550 110-82-7 M6 Cyclohexane 0.617 0.613 0.569 173.801

54 48.053 71-36-3 X4 n-Butanol 0.054 0.053 0.057 11.594 55 49.268 15840-60-5 C7 2-Methyl-c-hexene-3 0.040 0.044 0.031 11.166 56 49.614 3769-23-1 C7 4-Methylhexene-1 0.011 0.012 0.009 3.054 57 50.261 3404-55-5 C7 4-Methyl-t/c-hexene-2 0.050 0.055 0.039 14.019 58 50.654 591-76-4 I7 2-Methylhexane 0.651 0.742 0.505 179.828 59 50.835 ? Unidentified 0.041 0.046 0.034 14.321 60 51.147 110-83-8 B6 Cyclohexene 0.044 0.042 0.041 12.323 61 52.488 589-34-4 I7 3-Methylhexane 0.440 0.495 0.341 121.523 62 53.349 1759-58-6 M7 1t,3-Dimethylcyclopentane 0.137 0.141 0.108 38.547 63 53.934 2532-58-3 M7 1c,3-Dimethylcyclopentane 0.102 0.106 0.081 28.707

64 54.556 822-50-4 M7 1t,2-Dimethylcyclopentane 0.131 0.134 0.103 36.801 65 54.838 C7 C7 - Iso-Olefin - 2 0.022 0.024 0.018 6.235 66 55.140 540-84-1 I8 2,2,4-Trimethylpentane 0.054 0.060 0.037 14.924 67 55.464 592-76-7 K7 Heptene-1 0.028 0.031 0.022 7.935 68 56.799 4914-89-0 C7 3-Methyl-c-hexene-3 0.014 0.015 0.011 3.819 69 57.328 14686-14-7 K7 t-Heptene-3 0.031 0.034 0.025 8.787 70 57.679 6094-02-6 C7 2-Methylhexene-1 0.056 0.062 0.044 15.773 71 58.051 142-82-5 P7 n-Heptane 0.376 0.425 0.292 103.846 72 58.270 7642-10-6 K7 c-Heptene-3 0.024 0.027 0.019 6.871 73 58.545 2738-19-4 C7 2-Methyl-2-hexene 0.026 0.028 0.020 7.199

74 58.788 10574-36-4 C7 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.494 75 59.170 14686-13-6 K7 t-Heptene-2 0.015 0.017 0.012 4.257 76 59.646 16491-15-9 M7 Cyclopentene, 1,5-dimethyl- 0.017 0.018 0.014 4.867 77 60.073 20710-38-8 C7 3-Methyl-t-hexene-2 0.014 0.015 0.011 4.032 78 60.857 4914-91-4 C7 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.544 79 61.513 108-87-2 M7 Methylcyclohexane 0.542 0.544 0.428 152.583 80 62.456 4516-69-2 M8 1,1,3-Trimethylcyclopentane 0.015 0.015 0.010 4.114 81 62.845 590-73-8 I8 2,2-Dimethylhexane 0.012 0.014 0.008 3.451 82 63.356 ? Unidentified 0.057 0.062 0.041 19.817 83 64.289 1640-89-7 M7 Ethylcyclopentane 0.036 0.037 0.029 10.269

84 64.942 564-02-3 I8 2,2,3-Trimethylpentane 0.064 0.069 0.043 17.634 85 65.167 592-13-2 I8 2,5-Dimethylhexane 0.133 0.148 0.090 36.796 86 65.503 589-43-5 I8 2,4-Dimethylhexane 0.123 0.136 0.084 34.156

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 87 66.343 4850-28-6 M8 1c,2t,4-Trimethylcyclopentane 0.014 0.014 0.010 3.951 88 67.859 15890-40-1 M8 1t,2c,3-Trimethylcyclopentane 0.012 0.012 0.008 3.360 89 68.478 565-75-3 I8 2,3,4-Trimethylpentane 0.662 0.712 0.450 183.050 90 69.077 108-88-3 Q7 Toluene 12.625 11.261 10.644 3789.205 91 70.790 584-94-1 I8 2,3-Dimethylhexane 0.185 0.201 0.126 51.197 92 72.044 592-27-8 I8 2-Methylheptane 0.105 0.116 0.071 29.018 93 72.303 589-53-7 I8 4-Methylheptane 0.058 0.063 0.039 15.932 94 72.447 ? Unidentified 0.017 0.019 0.012 6.014 95 73.222 M8 1,3-dimethyl-t-cyclohexane 0.070 0.070 0.048 19.722 96 73.358 589-81-1 I8 3-Methylheptane 0.093 0.102 0.063 25.804

97 73.558 619-99-8 I8 3-Ethylhexane 0.047 0.051 0.032 12.962 98 74.457 ? Unidentified 0.011 0.011 0.008 3.870 99 75.247 3522-94-9 I9 2,2,5-Trimethylhexane 0.427 0.467 0.259 118.324 100 76.528 2207-03-6 M8 1t,3-Dimethylcyclohexane 0.031 0.030 0.021 8.620 101 77.868 111-65-9 P8 n-Octane 0.201 0.221 0.136 55.524 102 78.821 M8 C8 - MonoNaph - 3 0.015 0.015 0.010 4.185 103 80.350 1069-53-0 I9 2,3,5-Trimethylhexane 0.077 0.083 0.047 21.429 104 81.519 1071-26-7 I9 2,4-Dimethylheptane 0.018 0.020 0.011 5.059 105 82.172 1678-91-7 M8 Ethylcyclohexane 0.048 0.047 0.033 13.412 106 82.475 1072-05-5 I9 2,6-Dimethylheptane 0.032 0.034 0.019 8.764

107 82.974 ? Unidentified 0.009 0.009 0.006 3.065 108 83.407 I9 2,5-Dimethylheptane 0.049 0.053 0.030 13.705 109 84.740 100-41-4 Q8 Ethylbenzene 2.131 1.901 1.559 634.694 110 85.150 ? Unidentified 0.009 0.009 0.005 3.004 111 85.985 108-38-3 Q8 m-Xylene 5.649 5.055 4.134 1682.769 112 86.126 106-42-3 Q8 p-Xylene 2.623 2.356 1.920 781.401 113 87.275 2216-34-4 I9 4-Methyloctane 0.019 0.020 0.011 5.163 114 87.407 3221-61-2 I9 2-Methyloctane 0.025 0.027 0.015 6.835 115 88.269 2216-33-3 I9 3-Methyloctane 0.024 0.026 0.015 6.708 116 88.745 ? Unidentified 0.031 0.035 0.019 10.638

117 88.935 95-47-6 Q8 o-Xylene 1.523 1.338 1.115 453.684 118 89.320 I10 C10 - IsoParaffin - 1 0.099 0.105 0.054 27.411 119 89.911 M9 trans-1,3-Diethylcyclopentane 0.007 0.006 0.004 1.997 120 90.164 14720-74-2 I10 2,2,4-trimethylheptane 0.073 0.078 0.040 20.361 121 91.730 111-84-2 P9 n-Nonane 0.110 0.118 0.066 30.373 122 93.094 98-82-8 Q9 i-Propylbenzene 0.030 0.027 0.020 8.966 123 93.840 ? Unidentified 0.060 0.064 0.033 20.831 124 94.064 15869-87-1 I10 2,2-Dimethyloctane 0.022 0.023 0.012 6.080 125 94.524 ? Unidentified 0.005 0.004 0.419 1.862 126 94.524 ? Unidentified 0.005 0.006 0.003 1.862

127 94.861 15869-89-3 I10 2,5-Dimethyloctane 0.024 0.025 0.013 6.623 128 95.325 2040-95-1 I10 2,7-Dimethyloctane 0.018 0.019 0.010 5.110 129 95.507 2051-30-1 I10 2,4-Dimethyloctane 0.080 0.085 0.044 22.279

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 130 95.898 I10 2,6-Dimethyloctane 0.025 0.026 0.014 6.909 131 96.556 103-65-1 Q9 n-Propylbenzene 0.549 0.493 0.355 162.621 132 97.413 620-14-4 Q9 1-Methyl-3-ethylbenzene 2.289 2.048 1.480 677.453 133 97.643 622-96-8 Q9 1-Methyl-4-ethylbenzene 1.072 0.963 0.693 317.369 134 98.268 108-67-8 Q9 1,3,5-Trimethylbenzene 1.443 1.290 0.933 427.024 135 98.723 15869-85-9 I10 5-Methylnonane 0.011 0.012 0.006 3.091 136 98.913 17301-94-8 I10 4-Methylnonane 0.027 0.028 0.015 7.394 137 99.121 I10 2,2,6-Trimethyloctane 1.242 1.323 0.678 345.124 138 99.349 611-14-3 Q9 1-Methyl-2-ethylbenzene 0.786 0.690 0.508 232.631 139 99.567 5881-17-4 I10 3-Ethyloctane 0.005 0.005 0.003 1.365

140 99.889 5911-04-6 I10 3-Methylnonane 0.036 0.038 0.019 9.883 141 100.353 ? Unidentified 0.071 0.055 0.035 24.509 142 100.487 ? Unidentified 0.191 0.198 0.095 65.824 143 100.701 I11 C11-Isoparaffin-2 0.102 0.106 0.051 28.437 144 100.999 95-63-6 Q9 1,2,4-Trimethylbenzene 4.057 3.583 2.622 1200.810 145 101.165 ? Unidentified 0.116 0.128 0.064 39.963 146 101.287 ? Unidentified 0.069 0.073 0.038 23.913 147 101.550 1678-98-4 M10 i-Butylcyclohexane 0.018 0.018 0.010 5.091 148 102.193 ? Unidentified 0.007 0.006 0.004 2.278 149 102.337 17302-01-1 I10 3-Ethyl-3-methylheptane 0.162 0.169 0.081 45.156

150 102.643 538-93-2 Q10 i-Butylbenzene 0.194 0.176 0.112 57.190 151 102.798 124-18-5 P10 n-Decane 0.040 0.042 0.022 10.990 152 102.900 ? Unidentified 0.042 0.038 0.025 14.638 153 103.199 ? Unidentified 0.039 0.041 0.020 13.581 154 103.688 ? Unidentified 0.006 0.005 0.004 1.946 155 103.853 526-73-8 Q9 1,2,3-Trimethylbenzene 0.582 0.503 0.376 172.206 156 104.217 535-77-3 Q10 1-Methyl-3-i-propylbenzene 0.028 0.026 0.016 8.359 157 104.410 I11 C11 Isoparaffin-4 0.022 0.023 0.011 6.062 158 104.617 99-87-6 Q10 1-Methyl-4-i-propylbenzene 0.112 0.101 0.065 33.084 159 105.045 J9 Indan 0.219 0.175 0.144 65.778

160 105.640 J10 Indene 0.519 0.416 0.341 156.008 161 106.356 I11 C11-Isoparaffin-7 0.192 0.199 0.095 53.323 162 106.547 141-93-5 Q10 1,3-Diethylbenzene 0.068 0.061 0.040 20.121 163 106.829 1074-43-7 Q10 1-Methyl-3-n-propylbenzene 0.705 0.633 0.408 207.476 164 107.166 105-05-5 Q10 1,4-Diethylbenzene 0.237 0.212 0.137 69.632 165 107.262 104-51-8 Q10 n-Butylbenzene 0.037 0.033 0.022 10.962 166 107.383 934-74-7 Q10 1,3-Dimethyl-5-ethylbenzene 0.222 0.195 0.128 65.332 167 107.625 135-01-3 Q10 1,2-Diethylbenzene 0.045 0.039 0.026 13.226 168 108.081 ? Unidentified 0.039 0.041 0.019 13.531 169 108.234 1074-17-5 Q10 1-Methyl-2-n-propylbenzene 0.077 0.068 0.044 22.563

170 108.355 ? Unidentified 0.042 0.043 0.021 14.353 171 108.435 ? Unidentified 0.038 0.040 0.019 13.148 172 108.563 I11 C11- Isoparaffin-11 0.315 0.327 0.156 87.528

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 173 108.744 ? Unidentified 0.098 0.102 0.049 33.803 174 109.080 1758-88-9 Q10 1,4,Dimethyl-2-ethylbenzene 0.173 0.153 0.100 51.036 175 109.168 ? Unidentified 0.236 0.208 0.137 81.546 176 109.239 874-41-9 Q10 1,3-Dimethyl-4-ethylbenzene 0.187 0.164 0.108 54.928 177 109.395 J10 2-Methylindan 0.057 0.046 0.034 17.206 178 109.743 934-80-5 Q10 1,2-Dimethyl-4-ethylbenzene 0.459 0.406 0.266 135.093 179 110.285 2870-04-4 Q10 1,3-Dimethyl-2-ethylbenzene 0.239 0.208 0.138 70.408 180 110.710 ? Unidentified 0.006 0.006 0.003 2.147 181 110.905 693-61-8 K11 2-Undecene, (E)- 0.017 0.017 0.009 4.613 182 111.039 ? Unidentified 0.023 0.024 0.013 7.855

183 111.195 Q11 1-Methyl-4-t-butylbenzene 0.037 0.034 0.020 10.963 184 111.415 933-98-2 Q10 1,2-Dimethyl-3-ethylbenzene 0.154 0.134 0.089 45.420 185 111.710 1120-21-4 P11 n-Undecane 0.027 0.028 0.014 7.561 186 111.866 4218-48-8 Q11 1-Ethyl-4-i-propylbenzene 0.031 0.027 0.016 9.050 187 111.974 ? Unidentified 0.015 0.013 0.008 5.064 188 112.349 Q10 1,2,4,5-Tetramethylbenzene 0.375 0.327 0.217 110.320 189 112.616 527-53-7 Q10 1,2,3,5-Tetramethylbenzene 0.521 0.452 0.302 153.348 190 113.132 I12 C12 - IsoParaffin - 1 0.005 0.005 0.002 1.451 191 113.483 ? Unidentified 0.020 0.021 0.009 6.737 192 113.755 Q11 C11 - Aromatic - 3 0.059 0.052 0.031 17.430

193 113.946 874-35-1 H10 5-Methylindan 0.163 0.141 0.096 47.931 194 114.071 Q12 1,2-Di-i-propylbenzene 0.059 0.051 0.028 17.265 195 114.286 1595-16-0 Q11 1-methyl-4-(1-methylpropyl)be 0.085 0.074 0.045 24.946 196 114.442 Q11 C11 - Aromatic - 4 0.047 0.041 0.025 13.773 197 114.695 824-22-6 J10 4-Methylindan 0.218 0.189 0.128 64.103 198 114.846 5161-04-6 Q11 Benzene, 1-methyl-4-(2-methylpropyl)- 0.051 0.044 0.027 14.827 199 114.943 824-63-5 H10 2-Methylindan 0.162 0.141 0.095 47.781 200 115.146 ? Unidentified 0.015 0.016 0.007 5.194 201 115.259 538-68-1 Q11 n-Pentylbenzene 0.020 0.017 0.010 5.869 202 115.486 Q11 tert-Pentylbenzene 0.088 0.077 0.046 25.921

203 115.798 577-55-9 Q11 1-Methyl-2-n-butylbenzene 0.039 0.034 0.021 11.513 204 115.908 Q11 C11 - Aromatic - 6 0.049 0.045 0.026 14.427 205 116.369 100-18-5 Q12 1,4-Di-i-propylbenzene 0.073 0.064 0.035 21.437 206 116.813 91-20-3 G10 Naphthalene 0.169 0.128 0.103 52.159 207 117.008 J11 4,7-Dimethyl Indane 0.009 0.007 0.005 2.624 208 117.251 Q12 C12-Aromatic-1 0.023 0.021 0.011 6.871 209 117.414 J12 Dimethyl Indane - 1 0.010 0.008 0.005 3.038 210 117.593 7364-19-4 Q12 1t-Butyl-4-ethylbenzene 0.014 0.013 0.007 4.212 211 117.895 Q12 1,3-Di-n-propylbenzene 0.065 0.057 0.031 19.021 212 118.005 Q11 C11 - Aromatic - 11 0.037 0.034 0.019 10.824

213 118.559 Q11 C11 - Aromatic - 12 0.025 0.023 0.013 7.278 214 119.487 102-25-0 Q12 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.823 215 123.440 91-57-6 G11 2-Methylnaphthalene 0.009 0.007 0.005 2.774

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Component List

Recovery = 100.00 **Pk# Time**  **CASNO Group**  **Component %Wgt**  **%Vol %Mol**  **Area** 216 124.306 90-12-0 G11 1-Methylnaphthalene 0.005 0.004 0.003 1.501

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Paraffin 7.553 74-98-6 Propane 0.002 0.003 0.004 0.583

10.021 106-97-8 n-Butane 0.597 0.797 0.797 162.290 18.107 109-66-0 n-Pentane 1.763 2.178 1.899 483.060 35.799 110-54-3 n-Hexane 1.573 1.845 1.418 432.616 58.051 142-82-5 n-Heptane 0.376 0.425 0.292 103.846 77.868 111-65-9 n-Octane 0.201 0.221 0.136 55.524 91.730 111-84-2 n-Nonane 0.110 0.118 0.066 30.373 102.798 124-18-5 n-Decane 0.040 0.042 0.022 10.990 111.710 1120-21-4 n-Undecane 0.027 0.028 0.014 7.561

I-Paraffins 8.809 75-28-5 i-Butane 0.025 0.035 0.034 6.870

10.635 463-82-1 2,2-Dimethylpropane 0.009 0.012 0.010 2.601 15.073 78-78-4 i-Pentane 3.658 4.566 3.939 1002.166 23.085 75-83-2 2,2-Dimethylbutane 0.296 0.353 0.267 81.465 28.336 79-29-8 2,3-Dimethylbutane 1.015 1.187 0.915 279.232 29.429 107-83-5 2-Methylpentane 5.593 6.623 5.042 1538.314 32.074 96-14-0 3-Methylpentane 2.697 3.140 2.431 741.781 42.235 108-08-7 2,4-Dimethylpentane 0.207 0.238 0.161 57.207 42.773 464-06-2 2,2,3-Trimethylbutane 0.020 0.022 0.015 5.432 50.654 591-76-4 2-Methylhexane 0.651 0.742 0.505 179.828 52.488 589-34-4 3-Methylhexane 0.440 0.495 0.341 121.523 55.140 540-84-1 2,2,4-Trimethylpentane 0.054 0.060 0.037 14.924 62.845 590-73-8 2,2-Dimethylhexane 0.012 0.014 0.008 3.451 64.942 564-02-3 2,2,3-Trimethylpentane 0.064 0.069 0.043 17.634 65.167 592-13-2 2,5-Dimethylhexane 0.133 0.148 0.090 36.796 65.503 589-43-5 2,4-Dimethylhexane 0.123 0.136 0.084 34.156 68.478 565-75-3 2,3,4-Trimethylpentane 0.662 0.712 0.450 183.050 70.790 584-94-1 2,3-Dimethylhexane 0.185 0.201 0.126 51.197 72.044 592-27-8 2-Methylheptane 0.105 0.116 0.071 29.018 72.303 589-53-7 4-Methylheptane 0.058 0.063 0.039 15.932 73.358 589-81-1 3-Methylheptane 0.093 0.102 0.063 25.804 73.558 619-99-8 3-Ethylhexane 0.047 0.051 0.032 12.962 75.247 3522-94-9 2,2,5-Trimethylhexane 0.427 0.467 0.259 118.324 80.350 1069-53-0 2,3,5-Trimethylhexane 0.077 0.083 0.047 21.429 81.519 1071-26-7 2,4-Dimethylheptane 0.018 0.020 0.011 5.059 82.475 1072-05-5 2,6-Dimethylheptane 0.032 0.034 0.019 8.764 83.407 2,5-Dimethylheptane 0.049 0.053 0.030 13.705 87.275 2216-34-4 4-Methyloctane 0.019 0.020 0.011 5.163 87.407 3221-61-2 2-Methyloctane 0.025 0.027 0.015 6.835 88.269 2216-33-3 3-Methyloctane 0.024 0.026 0.015 6.708 89.320 C10 - IsoParaffin - 1 0.099 0.105 0.054 27.411 90.164 14720-74-2 2,2,4-trimethylheptane 0.073 0.078 0.040 20.361 94.064 15869-87-1 2,2-Dimethyloctane 0.022 0.023 0.012 6.080 94.861 15869-89-3 2,5-Dimethyloctane 0.024 0.025 0.013 6.623 95.325 2040-95-1 2,7-Dimethyloctane 0.018 0.019 0.010 5.110 95.507 2051-30-1 2,4-Dimethyloctane 0.080 0.085 0.044 22.279 95.898 2,6-Dimethyloctane 0.025 0.026 0.014 6.909

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  I-Paraffins 98.723 15869-85-9 5-Methylnonane 0.011 0.012 0.006 3.091

98.913 17301-94-8 4-Methylnonane 0.027 0.028 0.015 7.394 99.121 2,2,6-Trimethyloctane 1.242 1.323 0.678 345.124 99.567 5881-17-4 3-Ethyloctane 0.005 0.005 0.003 1.365 99.889 5911-04-6 3-Methylnonane 0.036 0.038 0.019 9.883 100.701 C11-Isoparaffin-2 0.102 0.106 0.051 28.437 102.337 17302-01-1 3-Ethyl-3-methylheptane 0.162 0.169 0.081 45.156 104.410 C11 Isoparaffin-4 0.022 0.023 0.011 6.062 106.356 C11-Isoparaffin-7 0.192 0.199 0.095 53.323 108.563 C11- Isoparaffin-11 0.315 0.327 0.156 87.528 113.132 C12 - IsoParaffin - 1 0.005 0.005 0.002 1.451

Aromatics Mono-Aromatics 45.631 71-42-3 Benzene 0.734 0.646 0.730 222.725

69.077 108-88-3 Toluene 12.625 11.261 10.644 3789.205 84.740 100-41-4 Ethylbenzene 2.131 1.901 1.559 634.694 85.985 108-38-3 m-Xylene 5.649 5.055 4.134 1682.769 86.126 106-42-3 p-Xylene 2.623 2.356 1.920 781.401 88.935 95-47-6 o-Xylene 1.523 1.338 1.115 453.684 93.094 98-82-8 i-Propylbenzene 0.030 0.027 0.020 8.966 96.556 103-65-1 n-Propylbenzene 0.549 0.493 0.355 162.621 97.413 620-14-4 1-Methyl-3-ethylbenzene 2.289 2.048 1.480 677.453 97.643 622-96-8 1-Methyl-4-ethylbenzene 1.072 0.963 0.693 317.369 98.268 108-67-8 1,3,5-Trimethylbenzene 1.443 1.290 0.933 427.024 99.349 611-14-3 1-Methyl-2-ethylbenzene 0.786 0.690 0.508 232.631 100.999 95-63-6 1,2,4-Trimethylbenzene 4.057 3.583 2.622 1200.810 102.643 538-93-2 i-Butylbenzene 0.194 0.176 0.112 57.190 103.853 526-73-8 1,2,3-Trimethylbenzene 0.582 0.503 0.376 172.206 104.217 535-77-3 1-Methyl-3-i-propylbenzene 0.028 0.026 0.016 8.359 104.617 99-87-6 1-Methyl-4-i-propylbenzene 0.112 0.101 0.065 33.084 106.547 141-93-5 1,3-Diethylbenzene 0.068 0.061 0.040 20.121 106.829 1074-43-7 1-Methyl-3-n-propylbenzene 0.705 0.633 0.408 207.476 107.166 105-05-5 1,4-Diethylbenzene 0.237 0.212 0.137 69.632 107.262 104-51-8 n-Butylbenzene 0.037 0.033 0.022 10.962 107.383 934-74-7 1,3-Dimethyl-5-ethylbenzene 0.222 0.195 0.128 65.332 107.625 135-01-3 1,2-Diethylbenzene 0.045 0.039 0.026 13.226 108.234 1074-17-5 1-Methyl-2-n-propylbenzene 0.077 0.068 0.044 22.563 109.080 1758-88-9 1,4,Dimethyl-2-ethylbenzene 0.173 0.153 0.100 51.036 109.239 874-41-9 1,3-Dimethyl-4-ethylbenzene 0.187 0.164 0.108 54.928 109.743 934-80-5 1,2-Dimethyl-4-ethylbenzene 0.459 0.406 0.266 135.093 110.285 2870-04-4 1,3-Dimethyl-2-ethylbenzene 0.239 0.208 0.138 70.408 111.195 1-Methyl-4-t-butylbenzene 0.037 0.034 0.020 10.963 111.415 933-98-2 1,2-Dimethyl-3-ethylbenzene 0.154 0.134 0.089 45.420 111.866 4218-48-8 1-Ethyl-4-i-propylbenzene 0.031 0.027 0.016 9.050 112.349 1,2,4,5-Tetramethylbenzene 0.375 0.327 0.217 110.320 112.616 527-53-7 1,2,3,5-Tetramethylbenzene 0.521 0.452 0.302 153.348 113.755 C11 - Aromatic - 3 0.059 0.052 0.031 17.430

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Aromatics 114.071 1,2-Di-i-propylbenzene 0.059 0.051 0.028 17.265

114.286 1595-16-0 1-methyl-4-(1-methylpropyl)be 0.085 0.074 0.045 24.946 114.442 C11 - Aromatic - 4 0.047 0.041 0.025 13.773 114.846 5161-04-6 Benzene, 1-methyl-4-(2-methylpropyl)- 0.051 0.044 0.027 14.827 115.259 538-68-1 n-Pentylbenzene 0.020 0.017 0.010 5.869 115.486 tert-Pentylbenzene 0.088 0.077 0.046 25.921 115.798 577-55-9 1-Methyl-2-n-butylbenzene 0.039 0.034 0.021 11.513 115.908 C11 - Aromatic - 6 0.049 0.045 0.026 14.427 116.369 100-18-5 1,4-Di-i-propylbenzene 0.073 0.064 0.035 21.437 117.251 C12-Aromatic-1 0.023 0.021 0.011 6.871 117.593 7364-19-4 1t-Butyl-4-ethylbenzene 0.014 0.013 0.007 4.212 117.895 1,3-Di-n-propylbenzene 0.065 0.057 0.031 19.021 118.005 C11 - Aromatic - 11 0.037 0.034 0.019 10.824 118.559 C11 - Aromatic - 12 0.025 0.023 0.013 7.278 119.487 102-25-0 1,3,5-Triethylbenzene 0.006 0.005 0.003 1.823

Naphthalenes 116.813 91-20-3 Naphthalene 0.169 0.128 0.103 52.159

123.440 91-57-6 2-Methylnaphthalene 0.009 0.007 0.005 2.774 124.306 90-12-0 1-Methylnaphthalene 0.005 0.004 0.003 1.501

Naphtheno/Olefino-Benzs

113.946 874-35-1 5-Methylindan 0.163 0.141 0.096 47.931 114.943 824-63-5 2-Methylindan 0.162 0.141 0.095 47.781

Indenes 105.045 Indan 0.219 0.175 0.144 65.778

105.640 Indene 0.519 0.416 0.341 156.008 109.395 2-Methylindan 0.057 0.046 0.034 17.206 114.695 824-22-6 4-Methylindan 0.218 0.189 0.128 64.103 117.008 4,7-Dimethyl Indane 0.009 0.007 0.005 2.624 117.414 Dimethyl Indane - 1 0.010 0.008 0.005 3.038

Naphthenes Mono-Naphthenes 27.596 287-92-3 Cyclopentane 0.305 0.316 0.338 85.857

40.665 96-37-7 Methylcyclopentane 1.205 1.245 1.112 339.547 47.550 110-82-7 Cyclohexane 0.617 0.613 0.569 173.801 53.349 1759-58-6 1t,3-Dimethylcyclopentane 0.137 0.141 0.108 38.547 53.934 2532-58-3 1c,3-Dimethylcyclopentane 0.102 0.106 0.081 28.707 54.556 822-50-4 1t,2-Dimethylcyclopentane 0.131 0.134 0.103 36.801 59.646 16491-15-9 Cyclopentene, 1,5-dimethyl- 0.017 0.018 0.014 4.867 61.513 108-87-2 Methylcyclohexane 0.542 0.544 0.428 152.583 62.456 4516-69-2 1,1,3-Trimethylcyclopentane 0.015 0.015 0.010 4.114 64.289 1640-89-7 Ethylcyclopentane 0.036 0.037 0.029 10.269 66.343 4850-28-6 1c,2t,4-Trimethylcyclopentane 0.014 0.014 0.010 3.951 67.859 15890-40-1 1t,2c,3-Trimethylcyclopentane 0.012 0.012 0.008 3.360 73.222 1,3-dimethyl-t-cyclohexane 0.070 0.070 0.048 19.722 76.528 2207-03-6 1t,3-Dimethylcyclohexane 0.031 0.030 0.021 8.620 78.821 C8 - MonoNaph - 3 0.015 0.015 0.010 4.185 82.172 1678-91-7 Ethylcyclohexane 0.048 0.047 0.033 13.412

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Mono-Naphthenes 89.911 trans-1,3-Diethylcyclopentane 0.007 0.006 0.004 1.997

101.550 1678-98-4 i-Butylcyclohexane 0.018 0.018 0.010 5.091

Di/Bicyclo-Naphthenes Olefins n-Olefins 9.621 115-11-7 Isobutene 0.016 0.021 0.022 4.502

9.662 106-98-9 Butene-1 0.018 0.023 0.024 4.962 10.507 624-64-6 t-Butene-2 0.072 0.092 0.100 20.328 11.247 590-18-1 c-Butene-2 0.085 0.106 0.118 24.035 16.725 109-67-1 Pentene-1 0.328 0.396 0.363 92.420 19.228 646-04-8 t-Pentene-2 0.832 0.992 0.921 234.391 20.261 627-20-3 c-Pentene-2 0.456 0.538 0.505 128.401 33.446 592-41-6 Hexene-1 0.158 0.180 0.146 44.508 36.435 13269-52-8 t-Hexene-3 0.257 0.291 0.237 72.378 36.909 4050-45-7 t-Hexene-2 0.394 0.446 0.363 110.939 38.737 7688-21-3 c-Hexene-2 0.209 0.233 0.193 58.832 55.464 592-76-7 Heptene-1 0.028 0.031 0.022 7.935 57.328 14686-14-7 t-Heptene-3 0.031 0.034 0.025 8.787 58.270 7642-10-6 c-Heptene-3 0.024 0.027 0.019 6.871 59.170 14686-13-6 t-Heptene-2 0.015 0.017 0.012 4.257 110.905 693-61-8 2-Undecene, (E)- 0.017 0.017 0.009 4.613

Iso-Olefins 13.445 563-45-1 3-Methylbutene-1 0.245 0.302 0.271 68.928

17.577 563-46-2 2-Methylbutene-1 0.498 0.592 0.551 140.212 20.941 513-35-9 2-Methylbutene-2 1.019 1.190 1.129 287.222 29.196 691-38-3 4-Methyl-c-pentene-2 0.044 0.050 0.040 12.346 29.838 674-76-0 4-Methyl-t-pentene-2 0.128 0.147 0.118 35.957 33.221 763-29-1 2-Methylpentene-1 0.220 0.249 0.203 62.043 35.633 760-21-4 2-Ethylbutene-1 0.064 0.071 0.059 17.898 37.401 625-27-4 2-Methylpentene-2 0.333 0.372 0.307 93.747 37.815 922-62-3 3-Methyl-c-pentene-2 0.256 0.284 0.237 72.243 40.080 3404-73-7 3,3-Dimethylpentene-1 0.305 0.336 0.242 86.052 42.525 594-56-9 2,3,3-Trimethylbutene-1 0.013 0.015 0.011 3.749 46.634 3404-61-3 3-Methylhexene-1 0.016 0.017 0.012 4.389 47.225 3524-73-0 5-Methylhexene-1 0.043 0.048 0.034 12.223 49.268 15840-60-5 2-Methyl-c-hexene-3 0.040 0.044 0.031 11.166 49.614 3769-23-1 4-Methylhexene-1 0.011 0.012 0.009 3.054 50.261 3404-55-5 4-Methyl-t/c-hexene-2 0.050 0.055 0.039 14.019 54.838 C7 - Iso-Olefin - 2 0.022 0.024 0.018 6.235 56.799 4914-89-0 3-Methyl-c-hexene-3 0.014 0.015 0.011 3.819 57.679 6094-02-6 2-Methylhexene-1 0.056 0.062 0.044 15.773 58.545 2738-19-4 2-Methyl-2-hexene 0.026 0.028 0.020 7.199 58.788 10574-36-4 3-Methyl-c-hexene-2 0.019 0.021 0.015 5.494 60.073 20710-38-8 3-Methyl-t-hexene-2 0.014 0.015 0.011 4.032 60.857 4914-91-4 2-Pentene, 3,4-dimethyl-, (Z)- 0.013 0.014 0.010 3.544

Naphtheno-Olefins 22.527 1574-41-0 1,3-Cyclopentadiene 0.007 0.008 0.008 1.979

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Components by Group

Recovery = 100.00 **Group Time**  **CASNO Component**  **%Wgt %Vol**  **%Mol Area**  Naphtheno-Olefins 25.736 142-29-0 Cyclopentene 0.193 0.193 0.220 55.939

37.033 1120-62-3 3-Methylcyclopentene 0.098 0.099 0.093 27.611 45.828 693-89-0 1-Methylcyclopentene 0.351 0.349 0.332 101.379 51.147 110-83-8 Cyclohexene 0.044 0.042 0.041 12.323

Di-Olefins 18.621 78-79-5 2-Methyl-1,3-Butadiene 0.011 0.012 0.012 3.164

21.266 2004-70-8 1t,3-Pentadiene 0.015 0.018 0.018 4.495 45.422 1528-30-9 C6-Diolefin-1 0.015 0.015 0.014 4.177

Oxygenates 13.125 64-17-5 Ethanol 21.748 21.315 36.673 2523.196

26.899 71-23-8 n-Propanol 0.073 0.070 0.094 14.306 48.053 71-36-3 n-Butanol 0.054 0.053 0.057 11.594

Unidentified 19.873 Unidentified 0.005 0.006 0.006 1.873

26.983 Unidentified 0.059 0.068 0.054 20.285 28.726 Unidentified 0.055 0.057 0.048 18.827 50.835 Unidentified 0.041 0.046 0.034 14.321 63.356 Unidentified 0.057 0.062 0.041 19.817 72.447 Unidentified 0.017 0.019 0.012 6.014 74.457 Unidentified 0.011 0.011 0.008 3.870 82.974 Unidentified 0.009 0.009 0.006 3.065 85.150 Unidentified 0.009 0.009 0.005 3.004 88.745 Unidentified 0.031 0.035 0.019 10.638 93.840 Unidentified 0.060 0.064 0.033 20.831 94.524 Unidentified 0.005 0.004 0.419 1.862 94.524 Unidentified 0.005 0.006 0.003 1.862 100.353 Unidentified 0.071 0.055 0.035 24.509 100.487 Unidentified 0.191 0.198 0.095 65.824 101.165 Unidentified 0.116 0.128 0.064 39.963 101.287 Unidentified 0.069 0.073 0.038 23.913 102.193 Unidentified 0.007 0.006 0.004 2.278 102.900 Unidentified 0.042 0.038 0.025 14.638 103.199 Unidentified 0.039 0.041 0.020 13.581 103.688 Unidentified 0.006 0.005 0.004 1.946 108.081 Unidentified 0.039 0.041 0.019 13.531 108.355 Unidentified 0.042 0.043 0.021 14.353 108.435 Unidentified 0.038 0.040 0.019 13.148 108.744 Unidentified 0.098 0.102 0.049 33.803 109.168 Unidentified 0.236 0.208 0.137 81.546 110.710 Unidentified 0.006 0.006 0.003 2.147 111.039 Unidentified 0.023 0.024 0.013 7.855 111.974 Unidentified 0.015 0.013 0.008 5.064 113.483 Unidentified 0.020 0.021 0.009 6.737 115.146 Unidentified 0.015 0.016 0.007 5.194

Plus

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF20.015.010.05.00.0

Propane

i-Butane

Isobutene Butene-1 n-Butane t-Butene-2 2,2-Dimethylpropane
c-Butene-2

Ethanol 3-Methylbutene-1

i-Pentane

Pentene-1

2-Methylbutene-1 n-Pentane 2-Methyl-1,3-Butadiene

t-Pentene-2
Unidentified c-Pentene-2

2-Methylbutene-2 1t,3-Pentadiene

1,3-Cyclopentadiene 2,2-Dimethylbutane

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF45.040.035.030.025.0 Cyclopentene

n-Propanol Unidentified Cyclopentane
2,3-Dimethylbutane Unidentified 4-Methyl-c-pentene-2 2-Methylpentane 4-Methyl-t-pentene-2

3-Methylpentane

2-Methylpentene-1 Hexene-1

2-Ethylbutene-1 n-Hexane
t-Hexene-3 t-Hexene-2 3-Methylcyclopentene 2-Methylpentene-2 3-Methyl-c-pentene-2

c-Hexene-2

3,3-Dimethylpentene-1

Methylcyclopentane

2,4-Dimethylpentane 2,3,3-Trimethylbutene-1 2,2,3-Trimethylbutane

C6-Diolefin-1

Benzene 1-Methylcyclopentene
3-Methylhexene-1 5-Methylhexene-1 Cyclohexane n-Butanol

2-Methyl-c-hexene-3 4-Methylhexene-1

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF70.065.060.055.050.0 4-Methyl-t/c-hexene-2

2-Methylhexane Unidentified Cyclohexene

3-Methylhexane

1t,3-Dimethylcyclopentane 1c,3-Dimethylcyclopentane 1t,2-Dimethylcyclopentane C7 - Iso-Olefin - 2 2,2,4-Trimethylpentane Heptene-1

3-Methyl-c-hexene-3 t-Heptene-3 2-Methylhexene-1 n-Heptane c-Heptene-3 2-Methyl-2-hexene 3-Methyl-c-hexene-2 t-Heptene-2Cyclopentene, 1,5-dimethyl3-Methyl-t-hexene-2
2-Pentene, 3,4-dimethyl-, (Z)- Methylcyclohexane

1,1,3-Trimethylcyclopentane 2,2-Dimethylhexane Unidentified

Ethylcyclopentane 2,2,3-Trimethylpentane 2,5-Dimethylhexane 2,4-Dimethylhexane
1c,2t,4-Trimethylcyclopentane

1t,2c,3-Trimethylcyclopentane 2,3,4-Trimethylpentane
Toluene

2,3-Dimethylhexane

2-Methylheptane 4-Methylheptane Unidentified
1,3-dimethyl-t-cyclohexane 3-Methylheptane 3-Ethylhexane

Unidentified

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF95.090.085.080.075.0 2,2,5-Trimethylhexane

1t,3-Dimethylcyclohexane

n-Octane

C8 - MonoNaph - 3

2,3,5-Trimethylhexane

2,4-Dimethylheptane Ethylcyclohexane 2,6-Dimethylheptane Unidentified 2,5-Dimethylheptane

Ethylbenzene Unidentified
m-Xylene p-Xylene

4-Methyloctane 2-Methyloctane

3-Methyloctane Unidentified o-Xylene C10 - IsoParaffin - 1 trans-1,3-Diethylcyclopentane 2,2,4-trimethylheptane

n-Nonane

i-Propylbenzene

Unidentified 2,2-Dimethyloctane Unidentified 2,5-Dimethyloctane 2,7-Dimethyloctane 2,4-Dimethyloctane 2,6-Dimethyloctane n-Propylbenzene

1-Methyl-3-ethylbenzene

1-Methyl-4-ethylbenzene 1,3,5-Trimethylbenzene 5-Methylnonane 4-Methylnonane 2,2,6-Trimethyloctane

1-Methyl-2-ethylbenzene 3-Ethyloctane 3-Methylnonane

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF120.0115.0110.0105.0100.0 Unidentified Unidentified C11-Isoparaffin-2 1,2,4-Trimethylbenzene Unidentified i-Butylcyclohexane
Unidentified 3-Ethyl-3-methylheptane i-Butylbenzene n-Decane Unidentified Unidentified Unidentified

1,2,3-Trimethylbenzene 1-Methyl-3-i-propylbenzene C11 Isoparaffin-4 1-Methyl-4-i-propylbenzene Indan
Indene C11-Isoparaffin-7 1,3-Diethylbenzene

1-Methyl-3-n-propylbenzene 1,4-Diethylbenzene n-Butylbenzene 1,3-Dimethyl-5-ethylbenzene 1,2-Diethylbenzene Unidentified 1-Methyl-2-n-propylbenzene C11- Isoparaffin-11 Unidentified 1,4,Dimethyl-2-ethylbenzene Unidentified 1,3-Dimethyl-4-ethylbenzene 2-Methylindan 1,2-Dimethyl-4-ethylbenzene 1,3-Dimethyl-2-ethylbenzene Unidentified 2-Undecene, (E)- Unidentified 1-Methyl-4-t-butylbenzene 1,2-Dimethyl-3-ethylbenzene n-Undecane 1-Ethyl-4-i-propylbenzene Unidentified 1,2,4,5-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene C12 - IsoParaffin - 1 Unidentified C11 - Aromatic - 3 5-Methylindan 1,2-Di-i-propylbenzene 1-methyl-4-(1-methylpropyl)be C11 - Aromatic - 4 4-Methylindan Benzene, 1-methyl-4-(2-methylpropyl)- 2-Methylindan Unidentified n-Pentylbenzene tert-Pentylbenzene 1-Methyl-2-n-butylbenzene C11 - Aromatic - 6 1,4-Di-i-propylbenzene Naphthalene 4,7-Dimethyl Indane C12-Aromatic-1 Dimethyl Indane - 1 1t-Butyl-4-ethylbenzene 1,3-Di-n-propylbenzene C11 - Aromatic - 11 C11 - Aromatic - 12

1,3,5-Triethylbenzene

2-Methylnaphthalene

1-Methylnaphthalene

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26-Aug-10, 10:43:13 File: C:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF Sample: ODDB-91335 Operator: AAD Parameter: C:\Chem32\SeparationSystems\HCE4\ODDB-91335 **LIMS Id:**



# Sample ChromatogramC:\Chem32\1\DATA\8-24-10\TEST_NC 2010-08-24 12-47-46\SIG2000017.D\SIG2000017_FID2_B.CDF145.0140.0135.0130.0125.0

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