Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-404MTM

Page 6 of 6

HESI100813
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-81M ACID INHIBITOR

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-81M ACID INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethyl octynol 5877-42-9 1 - 5% Not applicable Not applicable

Isopropanol 67-63-0 1 - 5% 200 ppm 400 ppm

Kerosene 8008-20-6 1 - 5% 200 mg/m3 Not applicable

Propargyl alcohol 107-19-7 1 - 5% 1 ppm S Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

fatal if swallowed. May cause blindness. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

HAI-81M ACID INHIBITOR

Page 1 of 6

HESI100785
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 58

Flash Point/Range (C): 14Max: < -23

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations. Do not allow runoff to

enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

HAI-81M ACID INHIBITOR

Page 2 of 6

HESI100786
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark red-brown

Odor: Sweet aromatic

pH: 3-5

Specific Gravity @ 20 C (Water=1): 0.9350

Density @ 20 C (lbs./gallon): 7.79

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not DeterminedMax: < -10

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 3.7

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 11

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause moderate eye irritation.

HAI-81M ACID INHIBITOR

Page 3 of 6

HESI100787
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

HAI-81M ACID INHIBITOR

Page 4 of 6

HESI100788
UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Kerosene), 3, II, (14 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol, Kerosene), 3, UN1993, II, (14 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Kerosene), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Methanol, Kerosene Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Kerosene), 3, II, (14 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Propargyl Alcohol//107-19-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2917 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

HAI-81M ACID INHIBITOR

Page 5 of 6

HESI100789
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-81M ACID INHIBITOR

Page 6 of 6

HESI100790
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-85M ACID INHIBITOR

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-85M ACID INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Quaternary ammonium salts 10 - 30% Not applicable Not applicable

Dimethyl formamide 68-12-2 10 - 30% 10 ppm 10 ppm (S)

Propargyl alcohol 107-19-7 5 - 10% 1 ppm S Not applicable

Copper iodide 7681-65-4 1 - 5% 1 mg/m3 1 mg/m3

Ethyl octynol 5877-42-9 1 - 5% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. May cause birth defects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

HAI-85M ACID INHIBITOR

Page 1 of 6

HESI100791
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Contains acetylenic alcohols, no known antidote. Treat symptomatically.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 77

Flash Point/Range (C): 25

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Avoid spraying water directly into

storage containers due to danger of boilover. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

HAI-85M ACID INHIBITOR

Page 2 of 6

HESI100792
Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark black red

Odor: Pungent

pH: 4

Specific Gravity @ 20 C (Water=1): 1.02

Density @ 20 C (lbs./gallon): 8.50

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 181

Boiling Point/Range (C): 82

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 56.87

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 5.1

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation This material is an anesthetic. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

HAI-85M ACID INHIBITOR

Page 3 of 6

HESI100793
Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea. May cause central nervous system depression

including headache, dizziness, drowsiness, muscular weakness, incoordination,

slowed reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Liver and kidney disorders. Central nervous system disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and spleen damage.

Contains dimethylformamide (DMF) which has been shown to cause birth defects

and fetal deaths in laboratory animals. Chronic exposure to DMF may result in liver

and kidney damage. DMF has been classified as a b2 carcinogen by IARC. May

contain ethylene oxide in the headspace of the drum. Ethylene oxide is a cancer and

reproductive hazard. This product contains trace amounts of benzyl chloride, which

has been evaluated by International Agency for Research on Cancer (IARC) and

found to be possibly carcinogenic to humans.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: EC50: 4 ppm (Abra alba)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: E(B)C50: 0.9 mg/l (Skeletonema costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

HAI-85M ACID INHIBITOR

Page 4 of 6

HESI100794
14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Acetylenic Alcohol), 3, (8), III, (25 C)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Acetylenic Alcohol), 3, (8), UN2924, III, (25 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Acetylenic Alcohol), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Isopropanol, Acetylenic Alcohol Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Acetylenic Alcohol), 3, (8), III, (25 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Copper and Compounds//6781-65-4

N,N'-Dimethyl Formamide//68-12-2

Propargyl Alcohol//107-19-7

Isopropanol//67-63-0

HAI-85M ACID INHIBITOR

Page 5 of 6

HESI100795
EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1278 Gallons based on Propargyl alcohol (CAS:

107-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-85M ACID INHIBITOR

Page 6 of 6

HESI100796
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-GE ACID INHIBITOR

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-GE ACID INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 10 - 30% 100 ppm (S) 100 ppm (S)

Propargyl alcohol 107-19-7 5 - 10% 1 ppm S Not applicable

Hexamethylenetetramine 100-97-0 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. May cause allergic skin and respiratory reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Remove contaminated shoes and discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

HAI-GE ACID INHIBITOR

Page 1 of 6

HESI100814
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 100

Flash Point/Range (C): 37

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Fight fire from a safe distance and from a protected location. Avoid spraying

water directly into storage containers due to danger of boilover.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse only competent persons for cleanup. Use appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse. Ground and bond containers when transferring

from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator. In high concentrations, supplied air respirator or a

self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

HAI-GE ACID INHIBITOR

Page 2 of 6

HESI100815
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Acetylenic

pH: 7.2

Specific Gravity @ 20 C (Water=1): 1.027

Density @ 20 C (lbs./gallon): 8.55

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 10

Freezing Point/Range (C): -12

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Avoid contact with acidic, basic or oxidizing agents.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

May cause chemical pneumonia. May cause lungs to fill with fluids. May cause

allergic respiratory reaction.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact Causes severe eye burns.

HAI-GE ACID INHIBITOR

Page 3 of 6

HESI100816
Ingestion Causes burns of the mouth, throat and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and lung effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: LD50: 16 mg/kg (Rabbit) - Propargyl Alcohol

LD50: 9500 mg/kg (Rabbit) - Dipropylene Glycol Monomethyl Ether

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

HAI-GE ACID INHIBITOR

Page 4 of 6

HESI100817
UN1993,Flammable Liquid, N.O.S.(Contains Propargyl Alcohol), 3, III, (37.8 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Propargyl Alcohol), 3, UN1993, III, (37.8 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Propargyl Alcohol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Propargyl Alcohol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Propargyl Alcohol), 3, III, (37.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Fire Hazard

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Propargyl Alcohol//107-19-7

Glycol Ethers//100-97-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1205 Gallons based on Propargyl alcohol (CAS:

107-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

HAI-GE ACID INHIBITOR

Page 5 of 6

HESI100818
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-GE ACID INHIBITOR

Page 6 of 6

HESI100819
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-OS ACID INHIBITOR

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-OS ACID INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Propargyl alcohol 107-19-7 5 - 10% 1 ppm S Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

fatal if swallowed. May cause blindness. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

HAI-OS ACID INHIBITOR

Page 1 of 6

HESI100820
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMax: < 52

Flash Point/Range (C): Not DeterminedMax: < 11

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Decomposition in fire may produce toxic

gases. Use water spray to cool fire exposed surfaces. Closed containers may

explode in fire. Avoid spraying water directly into storage containers due to danger

of boilover. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

HAI-OS ACID INHIBITOR

Page 2 of 6

HESI100821
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Alcohol

pH: 3.15

Specific Gravity @ 20 C (Water=1): 0.89

Density @ 20 C (lbs./gallon): 7.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): >1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with acids. Avoid contact with

oxidizers.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause chemical pneumonia. May cause

central nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May be fatal or cause blindness if swallowed. Causes burns of the mouth, throat and

stomach. May cause central nervous system depression including headache,

dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time,

fatigue blurred vision, slurred speech, giddiness, tremors and convulsions.

HAI-OS ACID INHIBITOR

Page 3 of 6

HESI100822
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 8132 mg/l (Cyprinodon variegatus)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propargyl Alcohol), 3, II, (11.1 C)

NAERG 128

Canadian TDG

HAI-OS ACID INHIBITOR

Page 4 of 6

HESI100823
Flammable Liquid, N.O.S.(Contains Methanol, Propargyl Alcohol), 3, UN1993, II, (11.1 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propargyl Alcohol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Methanol, Propargyl Alcohol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propargyl Alcohol), 3, II, (11.1 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Propargyl Alcohol//107-19-7

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1435 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

HAI-OS ACID INHIBITOR

Page 5 of 6

HESI100824
Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-OS ACID INHIBITOR

Page 6 of 6

HESI100825
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HC-2

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HC-2

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 5 - 10% Not applicable Not applicable

Inner salt of alkyl amines 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HC-2

Page 1 of 5

HESI100826
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 212

Flash Point/Range (C): Not DeterminedMin: > 100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator.

Hand Protection Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Surfactant

pH: 6.5-7.5

HC-2

Page 2 of 5

HESI100827
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.10

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): 32

Freezing Point/Range (C): 0

Vapor Pressure @ 20 C (mmHg): < 17.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: 60-63

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Excessive inhalation causes headache, dizziness, nausea and incoordination.

Skin Contact May cause skin defatting with prolonged exposure. Can dry skin.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

HC-2

Page 3 of 5

HESI100828
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

HC-2

Page 4 of 5

HESI100829
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HC-2

Page 5 of 5

HESI100830
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HII-124B INTENSIFIER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HII-124B INTENSIFIER

Synonyms: None

Chemical Family: Not applicable

Application: Intensifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium iodide 7681-11-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HII-124B INTENSIFIER

Page 1 of 5

HESI100831
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection HEPA Respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 8

Specific Gravity @ 20 C (Water=1): 3.1

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 95

HII-124B INTENSIFIER

Page 2 of 5

HESI100832
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): 2588

Boiling Point/Range (C): 1420

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 140

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 166

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Diazonium salts, diisopropyl peroxydicarbonate, oxidants, bromine, chlorine,

trifluorides, fluorine perchlorate.

Hazardous Decomposition

Products

Iodine. Oxides of iodine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may lead to iodism. Symptoms include skin rash,

running nose, headache and irritation of mucous membranes. Weakness, anemia,

loss of weight and general depression may also occur.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HII-124B INTENSIFIER

Page 3 of 5

HESI100833
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

HII-124B INTENSIFIER

Page 4 of 5

HESI100834
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HII-124B INTENSIFIER

Page 5 of 5

HESI100835
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HII-124C INTENSIFIER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HII-124C INTENSIFIER

Synonyms: None

Chemical Family: Inorganic Salt

Application: Intensifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cuprous chloride 7758-89-6 60 - 100% 1 mg/m3 1 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HII-124C INTENSIFIER

Page 1 of 6

HESI100836
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Light green

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 4.14

HII-124C INTENSIFIER

Page 2 of 6

HESI100837
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 34.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.0062

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 98.99

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Metal oxides. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause damage to nasal and respiratory

passages. May cause Metal Fume Fever (if heated) which is characterized by chills,

fever, aching muscles, dryness and metal taste in mouth and throat, headaches,

sneezing, nausea, and irritation of the nose and trachea.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 265 mg/kg (Rat)

HII-124C INTENSIFIER

Page 3 of 6

HESI100838
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2802,Copper Chloride, 8, III, Marine Pollutant

NAERG 154

Canadian TDG

Copper Chloride, 8, UN2802, III, Marine Pollutant

ADR

UN2802,Copper Chloride, 8, III, Marine Pollutant

Air Transportation

ICAO/IATA

HII-124C INTENSIFIER

Page 4 of 6

HESI100839
UN2802,Copper Chloride, 8, III, Marine Pollutant

Sea Transportation

IMDG

UN2802,Copper Chloride, 8, III

, Marine Pollutant

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

Marine Pollutant

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Copper and Compounds//7758-89-6

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

HII-124C INTENSIFIER

Page 5 of 6

HESI100840
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HII-124C INTENSIFIER

Page 6 of 6

HESI100841
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HII-124F INTENSIFIER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HII-124F INTENSIFIER

Synonyms: None

Chemical Family: Organic acid

Application: Intensifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Formic acid 64-18-6 60 - 100% 5 ppm 5 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HII-124F INTENSIFIER

Page 1 of 6

HESI100842
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 121

Flash Point/Range (C): 49

Flash Point Method: Not Determined

Autoignition Temperature (F): 1114

Autoignition Temperature (C): 601

Flammability Limits in Air - Lower (%): 18

Flammability Limits in Air - Upper (%): 57

Flammability Limits in Air - Upper (oz./ft3): 121

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep container closed when not

in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

HII-124F INTENSIFIER

Page 2 of 6

HESI100843
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear colorless

Odor: Sharp

pH: 1

Specific Gravity @ 20 C (Water=1): 1.2

Density @ 20 C (lbs./gallon): 10.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 215

Boiling Point/Range (C): 101

Freezing Point/Range (F): 50

Freezing Point/Range (C): 10

Vapor Pressure @ 20 C (mmHg): 23

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 46.03

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. Causes severe respiratory burns.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

HII-124F INTENSIFIER

Page 3 of 6

HESI100844
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1779,Formic Acid, 8, (3), II

NAERG 153

Canadian TDG

Formic Acid, 8, (3), UN1779, II

ADR

UN1779,Formic Acid, 8, (3), II

Air Transportation

ICAO/IATA

UN1779,Formic Acid, 8, (3), II

HII-124F INTENSIFIER

Page 4 of 6

HESI100845
Sea Transportation

IMDG

UN1779,Formic Acid, 8, (3), II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Formic Acid//64-18-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 553 Gallons based on Formic acid (CAS: 64-18-6).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

HII-124F INTENSIFIER

Page 5 of 6

HESI100846
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HII-124F INTENSIFIER

Page 6 of 6

HESI100847
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HII-500M CORROSION INHIBITOR INTENSIFIER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HII-500M CORROSION INHIBITOR INTENSIFIER

Synonyms: None

Chemical Family: Blend

Application: Intensifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Antimonate salt 30 - 60% 0.5 mg/m3 0.5 mg/m3

Ethylene glycol 107-21-1 30 - 60% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 1 of 6

HESI100848
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 3.2

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store in a cool, dry location. Keep container closed when not

in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Odorless

pH: 10-11.5

Specific Gravity @ 20 C (Water=1): 1.42

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 2 of 6

HESI100849
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 11.86

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): > 212Min: > 212

Boiling Point/Range (C): >100Min: > 100

Freezing Point/Range (F): 16-19

Freezing Point/Range (C): -7 - -9

Vapor Pressure @ 20 C (mmHg): < 20

Vapor Density (Air=1): >1

Percent Volatiles: 69

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 200 F (93 C).

Incompatibility (Materials to

Avoid)

Strong acids. Prolonged contact with aluminum.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Metal oxides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Vapors given off by heated product may be harmful. May cause central nervous

system depression including headache, dizziness, drowsiness, incoordination,

slowed reaction time, slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Harmful if swallowed. May cause abdominal pain, vomiting, nausea, and diarrhea.

May cause liver and kidney damage. May affect the heart and cardiovascular

system. May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation

and central nervous system depression.

Aggravated Medical Conditions Not determined

Chronic Effects/Carcinogenicity May cause birth defects. Prolonged or repeated exposure may also cause heart and

lung damage. Prolonged or repeated exposure may cause liver, kidney and blood

effects.

Other Information None known.

Toxicity Tests

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 3 of 6

HESI100850
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 4 of 6

HESI100851
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Antimony and Compounds//29638-69-5

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1342 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Toxic characteristics

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 5 of 6

HESI100852
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HII-500M CORROSION INHIBITOR INTENSIFIER

Page 6 of 6

HESI100853
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HMP Con PF

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HMP Con PF

Synonyms: None

Chemical Family: Proprietary Aqueous Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 0 - 1% 2 mg/m3 2 mg/m3

Potassium chloride 7447-40-7 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HMP Con PF

Page 1 of 6

HESI100854
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Store at temperatures between 50 and

100 F (10 and 37.8 C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow to brown

Odor: Odorless

pH: > 13 (1%)

HMP Con PF

Page 2 of 6

HESI100855
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.15

Density @ 20 C (lbs./gallon): 9.6

Bulk Density @ 20 C (lbs/ft3): 71.76

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: ~73

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 25000 @ 25C

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HMP Con PF

Page 3 of 6

HESI100856
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

HMP Con PF

Page 4 of 6

HESI100857
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1000 Pounds based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

HMP Con PF

Page 5 of 6

HESI100858
***END OF MSDS***

HMP Con PF

Page 6 of 6

HESI100859
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HMP DE-LINKER

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HMP DE-LINKER

Synonyms: None

Chemical Family: Anhydride

Application: Delinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

L-Dilactide 4511-42-6 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Remove contaminated shoes and discard.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HMP DE-LINKER

Page 1 of 6

HESI100860
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 275

Flash Point/Range (C): > 135

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Avoid spraying water directly into storage containers due to danger of boilover. Fight

fire from a safe distance and from a protected location. Use water spray to cool fire

exposed surfaces. Closed containers may explode in fire. Decomposition in fire may

produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse only competent persons for cleanup. Use appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep container closed when not

in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

HMP DE-LINKER

Page 2 of 6

HESI100861
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Amber

Odor: Sweet

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.22

Density @ 20 C (lbs./gallon): 10.18

Bulk Density @ 20 C (lbs/ft3): 76.16

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperatures over 302 F (150 C).

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Organic acid vapors. Aldehydes. Ketones. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause irritation of

gastrointestinal tissues resulting in pain, vomiting, abdominal tenderness, nausea,

blood in vomitus, and blood in feces.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

HMP DE-LINKER

Page 3 of 6

HESI100862
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains L-Dilactide), 8, II

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains L-Dilactide), 8, UN3265, II

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains L-Dilactide), 8, II

Air Transportation

HMP DE-LINKER

Page 4 of 6

HESI100863
ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, II

(Contains L-Dilactide Solution)

Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains L-Dilactide), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

HMP DE-LINKER

Page 5 of 6

HESI100864
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HMP DE-LINKER

Page 6 of 6

HESI100865
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HMP LINK

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HMP LINK

Synonyms: None

Chemical Family: Blend

Application: Initiator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

Monoethanolamine 141-43-5 10 - 30% 3 ppm 3 ppm

Boric acid 10043-35-3 30 - 60% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HMP LINK

Page 1 of 6

HESI100866
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark

Odor: Strong offensive

pH: 7.28

HMP LINK

Page 2 of 6

HESI100867
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.22

Density @ 20 C (lbs./gallon): 10.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Dehydrating agents.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause heart, kidney

and brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause liver, heart, blood and brain damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

HMP LINK

Page 3 of 6

HESI100868
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

HMP LINK

Page 4 of 6

HESI100869
Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1674 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

HMP LINK

Page 5 of 6

HESI100870
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HMP LINK

Page 6 of 6

HESI100871
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HpH BREAKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HpH BREAKER

Synonyms: None

Chemical Family: Blend

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HpH BREAKER

Page 1 of 5

HESI100872
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a dry location. Keep from excessive heat. Keep container closed when not in

use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light brown

Odor: Fermentive

pH: 7.5

Specific Gravity @ 20 C (Water=1): 1.1

HpH BREAKER

Page 2 of 5

HESI100873
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 220

Boiling Point/Range (C): 104

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May act as obstruction if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HpH BREAKER

Page 3 of 5

HESI100874
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

HpH BREAKER

Page 4 of 5

HESI100875
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HpH BREAKER

Page 5 of 5

HESI100876
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HpH Foamer

Revision Date: 07-Jul-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HpH Foamer

Synonyms: None

Chemical Family: Not determined

Application: Non-ionic Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Amine 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause eye and skin burns. May

cause respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treatment should be directed at preventing absorption, administering to symptoms

as they occur, and providing supportive therapy.

HpH Foamer

Page 1 of 6

HESI100877
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200Min: > 200

Flash Point/Range (C): > 93Min: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations. Use water spray to cool fire exposed surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store away from acids. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

HpH Foamer

Page 2 of 6

HESI100878
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Pungent

pH: 9 - 10

Specific Gravity @ 20 C (Water=1): 1.055 - 1.085

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.01

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 0.04

Viscosity, Dynamic @ 20 C (centipoise): 150-400

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Do not expose to heat or store at

temperatures above 120 F (49 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes eye irritation.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

HpH Foamer

Page 3 of 6

HESI100879
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

HpH Foamer

Page 4 of 6

HESI100880
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

HpH Foamer

Page 5 of 6

HESI100881
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HpH Foamer

Page 6 of 6

HESI100882
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HPT-1

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HPT-1

Synonyms: None

Chemical Family: Blend

Application: Conformance Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HPT-1

Page 1 of 5

HESI100883
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Amine

pH: 8.5 - 8.9

Specific Gravity @ 20 C (Water=1): 1.0127

Density @ 20 C (lbs./gallon): 8.44

HPT-1

Page 2 of 5

HESI100884
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

HPT-1

Page 3 of 5

HESI100885
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

HPT-1

Page 4 of 5

HESI100886
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HPT-1

Page 5 of 5

HESI100887
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HT BREAKER

Revision Date: 18-Jun-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HT BREAKER

Synonyms: None

Chemical Family: Organic peroxide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

tert-Butyl Hydroperoxide 75-91-2 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May be

harmful if inhaled. May be absorbed through the skin. May cause allergic skin and

respiratory reaction. Organic peroxide.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HT BREAKER

Page 1 of 6

HESI100888
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 109

Flash Point/Range (C): 43

Flash Point Method: TCC

Autoignition Temperature (F): 460

Autoignition Temperature (C): 238

Flammability Limits in Air - Lower (%): 5.7

Flammability Limits in Air - Upper (%): 99.99

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Use water spray to cool fire exposed surfaces.

Closed containers may explode in fire. Decomposition in fire may produce toxic

gases. Vapors are heavier than air and may accumulate in low areas. Vapors may

travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 2

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from combustibles. Keep from heat, sparks, and open flames. Store in a

cool well ventilated area. Keep container closed when not in use. Keep from freezing.

Store away from direct sunlight. Store between 32 F (0 C) and 95 F (35 C). Product

has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

HT BREAKER

Page 2 of 6

HESI100889
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Full Facepiece Respirator with Organic vapor respirator with a dust/mist filter.

Organic vapor respirators have a short service life.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Pungent

pH: 4.3

Specific Gravity @ 20 C (Water=1): 0.93

Density @ 20 C (lbs./gallon): 7.79

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 205

Boiling Point/Range (C): 96

Freezing Point/Range (F): 27

Freezing Point/Range (C): -3

Vapor Pressure @ 20 C (mmHg): 23

Vapor Density (Air=1): 3.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 90.14

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with organic materials.

Incompatibility (Materials to

Avoid)

Organic matter. All flammables, especially petroleum products, asphalt & other

volatile flammables. Reducing agents. Sulfides. Ketones.

Hazardous Decomposition

Products

Oxygen. Carbon monoxide and carbon dioxide.

HT BREAKER

Page 3 of 6

HESI100890
Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause chemical pneumonia. May cause

lungs to fill with fluids. May cause allergic respiratory reaction.

Skin Contact Causes burns. May be absorbed through the skin and produce effects similar to

those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments. Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

HT BREAKER

Page 4 of 6

HESI100891
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3109,Organic Peroxide Type F, Liquid(Contains < 72% tert-Butyl Hydroperoxide), 5.2, (8), II

NAERG 145

Canadian TDG

Organic Peroxide Type F, Liquid(Contains < 72% tert-Butyl Hydroperoxide), 5.2, (8), UN3109, II

ADR

UN3109,Organic Peroxide Type F, Liquid(Contains < 72% tert-Butyl Hydroperoxide), 5.2, (8), II

Air Transportation

ICAO/IATA

UN3109,Organic Peroxide Type F, Liquid, 5.2, (8), II

(Contains < 72% tert-Butyl Hydroperoxide)

Sea Transportation

IMDG

UN3109,Organic Peroxide Type F, Liquid(Contains < 72% tert-Butyl Hydroperoxide), 5.2, (8), II

EmS F-J, S-R

Other Shipping Information

Labels: Organic Peroxide

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

HT BREAKER

Page 5 of 6

HESI100892
EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 19 Gallons based on t-Butyl hydroperoxide (CAS:

75-91-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

C Oxidizing Materials

D2A Very Toxic Materials

D2B Toxic Materials

E Corrosive Material

F Dangerously Reactive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HT BREAKER

Page 6 of 6

HESI100893
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HYDROCHLORIC ACID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HYDROCHLORIC ACID

Synonyms: None

Chemical Family: Inorganic acid

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrochloric acid 7647-01-0 30 - 60% 2 ppm 5 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HYDROCHLORIC ACID

Page 1 of 6

HESI100894
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May form explosive mixtures with strong alkalis. Decomposition in fire may produce

toxic gases. Reaction with steel and certain other metals generates flammable

hydrogen gas. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Physical Hazard 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

HYDROCHLORIC ACID

Page 2 of 6

HESI100895
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear colorless

Odor: Pungent acrid

pH: 0.8

Specific Gravity @ 20 C (Water=1): 1.18

Density @ 20 C (lbs./gallon): 9.82

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 230

Boiling Point/Range (C): 110

Freezing Point/Range (F): -50

Freezing Point/Range (C): -46

Vapor Pressure @ 20 C (mmHg): 26

Vapor Density (Air=1): Not Determined

Percent Volatiles: 35

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 36.5

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Flammable hydrogen gas. Chlorine. Hydrogen sulfide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause skin burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

HYDROCHLORIC ACID

Page 3 of 6

HESI100896
Inhalation Toxicity: LC50: 3124 ppm/1 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1789,Hydrochloric Acid Solution, 8, II

RQ (Hydrochloric Acid - 2273 kg.)

NAERG 157

Canadian TDG

Hydrochloric Acid Solution, 8, UN1789, II

ADR

UN1789,Hydrochloric Acid Solution, 8, II

Air Transportation

ICAO/IATA

UN1789,Hydrochloric Acid Solution, 8, II

HYDROCHLORIC ACID

Page 4 of 6

HESI100897
RQ (Hydrochloric Acid - 2273 kg.)

Sea Transportation

IMDG

UN1789,Hydrochloric Acid Solution, 8, II

RQ (Hydrochloric Acid - 2273 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1592 Gallons based on Hydrochloric acid (CAS:

7647-01-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

HYDROCHLORIC ACID

Page 5 of 6

HESI100898
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HYDROCHLORIC ACID

Page 6 of 6

HESI100899
_--_--_--- _____ ----.-----_-- ------ --------_._--------- ------- ------_--.-_-.l---_ 

-..-.__- ____.____ -------------------_.---- -._- ----_.-._--- -------- --- --._ -------- ..__ - 

HESI100900
-4 

“. 

HESI100901
HESI100902
4 

HESI100903
HESI100904
HESI100905
----------__.---------------------------------------_--------_----------- 

HESI100906
HESI100907
HESI100908
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HYFLO IV M SURFACTANT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HYFLO IV M SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Naphtha, heavy catalytic

reformed

64741-68-0 30 - 60% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

HYFLO IV M SURFACTANT

Page 1 of 6

HESI100909
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 55

Flash Point/Range (C): 12.8

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations. Do not allow runoff to

enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

HYFLO IV M SURFACTANT

Page 2 of 6

HESI100910
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Hydrocarbon

pH: 4-6

Specific Gravity @ 20 C (Water=1): 0.91

Density @ 20 C (lbs./gallon): 7.59

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

HYFLO IV M SURFACTANT

Page 3 of 6

HESI100911
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May produce nervous system effects such as feeling of

weakness, unsteady walk, and dilation of blood vessels. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Contains petroleum

distillates which have been shown to cause skin cancer in laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

HYFLO IV M SURFACTANT

Page 4 of 6

HESI100912
Flammable Liquid, N.O.S., 3, UN1993, II, (12.8 C)

(Contains Isopropanol, Heavy Aromatic Naphtha)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (12.8 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (12.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 165 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

HYFLO IV M SURFACTANT

Page 5 of 6

HESI100913
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HYFLO IV M SURFACTANT

Page 6 of 6

HESI100914
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HYG-3

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HYG-3

Synonyms: None

Chemical Family: Organic acid

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Fumaric acid 110-17-8 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

HYG-3

Page 1 of 6

HESI100915
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 300

Flash Point/Range (C): 148

Flash Point Method: Not Determined

Autoignition Temperature (F): 740

Autoignition Temperature (C): 393

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 3

Flammability Limits in Air - Upper (%): Not Determined

Flammability Limits in Air - Upper (oz./ft3): 40

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection HEPA Respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

HYG-3

Page 2 of 6

HESI100916
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.63

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 50.32

Boiling Point/Range (F): 554

Boiling Point/Range (C): 290

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 116.06

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact None known.

Eye Contact May cause moderate eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 10700 mg/kg (Rat)

Dermal Toxicity: LD50: 20000 mg/kg (Rabbit)

HYG-3

Page 3 of 6

HESI100917
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

HYG-3

Page 4 of 6

HESI100918
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5000 Pounds based on Fumaric acid (CAS: 110-17-

8).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HYG-3

Page 5 of 6

HESI100919
HYG-3

Page 6 of 6

HESI100920
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ISOPROPYL ALCOHOL

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ISOPROPYL ALCOHOL

Synonyms: None

Chemical Family: Alcohol

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 60 - 100% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ISOPROPYL ALCOHOL

Page 1 of 6

HESI100921
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 53

Flash Point/Range (C): 11

Flash Point Method: Not Determined

Autoignition Temperature (F): 750

Autoignition Temperature (C): 398

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 3, Reactivity 0

HMIS Ratings: Health 1, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

ISOPROPYL ALCOHOL

Page 2 of 6

HESI100922
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.8

Density @ 20 C (lbs./gallon): 6.70

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 177

Boiling Point/Range (C): 80

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 34

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

ISOPROPYL ALCOHOL

Page 3 of 6

HESI100923
Ingestion Irritation of the mouth, throat, and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May cause kidney damage.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 5840 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1219,Isopropanol Solution, 3, II, (11.7 C)

ISOPROPYL ALCOHOL

Page 4 of 6

HESI100924
NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (11.7 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (11.7 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

ISOPROPYL ALCOHOL

Page 5 of 6

HESI100925
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ISOPROPYL ALCOHOL

Page 6 of 6

HESI100926
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-34

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-34

Synonyms: None

Chemical Family: Carbonate

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium bicarbonate 144-55-8 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

K-34

Page 1 of 5

HESI100927
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used

in areas without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 8

K-34

Page 2 of 5

HESI100928
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.87

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 41.2

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4220 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

K-34

Page 3 of 5

HESI100929
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

K-34

Page 4 of 5

HESI100930
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-34

Page 5 of 5

HESI100931
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-35

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-35

Synonyms: None

Chemical Family: Carbonate

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium carbonate 497-19-8 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

K-35

Page 1 of 5

HESI100932
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from acids. Store in a cool, dry location. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

pH: 11.4

K-35

Page 2 of 5

HESI100933
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 53.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 105.99

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4220 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

K-35

Page 3 of 5

HESI100934
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 385 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

K-35

Page 4 of 5

HESI100935
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-35

Page 5 of 5

HESI100936
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-38

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-38

Synonyms: None

Chemical Family: Mineral

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Disodium octaborate

tetrahydrate

12008-41-2 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

K-38

Page 1 of 5

HESI100937
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 7.3

Specific Gravity @ 20 C (Water=1): 1.7

K-38

Page 2 of 5

HESI100938
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 25

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 9.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

K-38

Page 3 of 5

HESI100939
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

K-38

Page 4 of 5

HESI100940
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-38

Page 5 of 5

HESI100941
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: K-39

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: K-39

Synonyms: None

Chemical Family: Amine

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Triethanolamine 102-71-6 60 - 100% 5 mg/m3 Not applicable

Diethanolamine 111-42-2 10 - 30% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

K-39

Page 1 of 6

HESI100942
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 382

Flash Point/Range (C): 194

Flash Point Method: Not Determined

Autoignition Temperature (F): 600

Autoignition Temperature (C): 315

Flammability Limits in Air - Lower (%): 1.3

Flammability Limits in Air - Upper (%): 8.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 2

HMIS Ratings: Health 1, Flammability 1, Reactivity 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Water white

Odor: Characteristic

pH: 10.5

K-39

Page 2 of 6

HESI100943
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.11

Density @ 20 C (lbs./gallon): 9.28

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 482

Boiling Point/Range (C): 250

Freezing Point/Range (F): 61

Freezing Point/Range (C): 16

Vapor Pressure @ 20 C (mmHg): 0.01

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Violent, explosive reaction with sulfur trioxide, decaborane, silver

perchlorate, triethenyl aluminum, and hydrogen in presence of nickel catalyst at

temperatures above 200 C.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause severe skin irritation. May cause an allergic skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Amines may form

nitrosamines, a suspect carcinogen, if product is mixed with nitrates, nitrites, nitrogen

oxides or other nitrosamines.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

K-39

Page 3 of 6

HESI100944
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

K-39

Page 4 of 6

HESI100945
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

K-39

Page 5 of 6

HESI100946
K-39

Page 6 of 6

HESI100947
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: KCL POTASSIUM CHLORIDE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: KCL POTASSIUM CHLORIDE

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

KCL POTASSIUM CHLORIDE

Page 1 of 6

HESI100948
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid

breathing vapors.

Storage Information Store in a cool, dry location. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to gray

Odor: Odorless

pH: 9.2

Specific Gravity @ 20 C (Water=1): 1.99

Density @ 20 C (lbs./gallon): Not Determined

KCL POTASSIUM CHLORIDE

Page 2 of 6

HESI100949
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 72.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 25.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 74.55

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

KCL POTASSIUM CHLORIDE

Page 3 of 6

HESI100950
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

KCL POTASSIUM CHLORIDE

Page 4 of 6

HESI100951
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

KCL POTASSIUM CHLORIDE

Page 5 of 6

HESI100952
KCL POTASSIUM CHLORIDE

Page 6 of 6

HESI100953
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-16

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-16

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm 100 ppm

Guar gum derivative 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin. Repeated overexposure may cause liver and kidney effects. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

LGC-16

Page 1 of 6

HESI100966
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 150

Flash Point/Range (C): Not DeterminedMin: > 65

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 14

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-16

Page 2 of 6

HESI100967
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Ether

pH: 5-8.5

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 350

Boiling Point/Range (C): Not DeterminedMin: > 177

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.55

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed. May cause central nervous system depression

including headache, dizziness, drowsiness, muscular weakness, incoordination,

slowed reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders.

LGC-16

Page 3 of 6

HESI100968
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

LGC-16

Page 4 of 6

HESI100969
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-16

Page 5 of 6

HESI100970
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-16

Page 6 of 6

HESI100971
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-17

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-17

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Paraffinic solvent 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-17

Page 1 of 6

HESI100972
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 180

Flash Point/Range (C): 82

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LGC-17

Page 2 of 6

HESI100973
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

LGC-17

Page 3 of 6

HESI100974
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

LGC-17

Page 4 of 6

HESI100975
DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

LGC-17

Page 5 of 6

HESI100976
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-17

Page 6 of 6

HESI100977
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-35

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-35

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

Guar gum 9000-30-0 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-35

Page 1 of 6

HESI100978
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 150

Flash Point/Range (C): 65

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.4

Flammability Limits in Air - Upper (%): 26

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter. In high concentrations, supplied air

respirator or a self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-35

Page 2 of 6

HESI100979
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Gel

Color: Red brown

Odor: Diesel

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): 1.08

Density @ 20 C (lbs./gallon): 9.0

Bulk Density @ 20 C (lbs/ft3): 9.0

Boiling Point/Range (F): 300

Boiling Point/Range (C): 148

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 0.2

Vapor Density (Air=1): > 1

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

LGC-35

Page 3 of 6

HESI100980
Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals. Limited studies on oils that are very active carcinogens have

shown washing the animals' skin with soap and water between applications greatly

decreases the incidence of tumors. In light of these studies, good personal hygiene

is essential with the use of this product.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

LGC-35

Page 4 of 6

HESI100981
Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-35

Page 5 of 6

HESI100982
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-35

Page 6 of 6

HESI100983
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-35 CBM

Revision Date: 22-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-35 CBM

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Paraffinic solvent 30 - 60% Not applicable Not applicable

Polysaccharide 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-35 CBM

Page 1 of 6

HESI100984
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 176

Flash Point/Range (C): 80

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.5

Flammability Limits in Air - Upper (%): 4.9

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-35 CBM

Page 2 of 6

HESI100985
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Odorless

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.034

Density @ 20 C (lbs./gallon): 8.61

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

LGC-35 CBM

Page 3 of 6

HESI100986
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

LGC-35 CBM

Page 4 of 6

HESI100987
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-35 CBM

Page 5 of 6

HESI100988
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-35 CBM

Page 6 of 6

HESI100989
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-35 ZD B

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-35 ZD B

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polysaccharide 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-35 ZD B

Page 1 of 6

HESI100990
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 170

Flash Point/Range (C): 77

Flash Point Method: PMCC

Autoignition Temperature (F): > 475

Autoignition Temperature (C): > 246

Flammability Limits in Air - Lower (%): 1.3

Flammability Limits in Air - Upper (%): 8.1

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Slippery when wet. Ground and

bond containers when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Neoprene gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-35 ZD B

Page 2 of 6

HESI100991
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Green to Beige

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.10

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): 20

Freezing Point/Range (C): -6.7

Vapor Pressure @ 20 C (mmHg): < 0.13

Vapor Density (Air=1): 5.3

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

LGC-35 ZD B

Page 3 of 6

HESI100992
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

LGC-35 ZD B

Page 4 of 6

HESI100993
Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-35 ZD B

Page 5 of 6

HESI100994
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-35 ZD B

Page 6 of 6

HESI100995
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-35CBM+

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-35CBM+

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polysaccharide 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-35CBM+

Page 1 of 6

HESI100996
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): > 475

Autoignition Temperature (C): > 246

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Slippery when wet.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

LGC-35CBM+

Page 2 of 6

HESI100997
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Green to Beige

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): 20

Freezing Point/Range (C): -6.7

Vapor Pressure @ 20 C (mmHg): < 0.13

Vapor Density (Air=1): >1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

LGC-35CBM+

Page 3 of 6

HESI100998
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

LGC-35CBM+

Page 4 of 6

HESI100999
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-35CBM+

Page 5 of 6

HESI101000
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-35CBM+

Page 6 of 6

HESI101001
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-35ZD

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-35ZD

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

30 - 60% 200 mg/m3 Not applicable

Polysaccharide 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-35ZD

Page 1 of 6

HESI101002
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 176-200

Flash Point/Range (C): 80-93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.5

Flammability Limits in Air - Upper (%): 4.9

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-35ZD

Page 2 of 6

HESI101003
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Odorless

pH: 6.5 - 7.5 (1%)

Specific Gravity @ 20 C (Water=1): 1.04

Density @ 20 C (lbs./gallon): 8.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

LGC-35ZD

Page 3 of 6

HESI101004
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

LGC-35ZD

Page 4 of 6

HESI101005
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-35ZD

Page 5 of 6

HESI101006
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-35ZD

Page 6 of 6

HESI101007
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-36 CBM

Revision Date: 22-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-36 CBM

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Paraffinic solvent 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-36 CBM

Page 1 of 6

HESI101008
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 180

Flash Point/Range (C): 82

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-36 CBM

Page 2 of 6

HESI101009
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Slurry

Color: Off white

Odor: Odorless

pH: 6.5 - 7.5 (1%)

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

LGC-36 CBM

Page 3 of 6

HESI101010
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

LGC-36 CBM

Page 4 of 6

HESI101011
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-36 CBM

Page 5 of 6

HESI101012
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-36 CBM

Page 6 of 6

HESI101013
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-36 UC

Revision Date: 24-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-36 UC

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Naphtha, hydrotreated heavy 64742-48-9 30 - 60% Not applicable Not applicable

Polysaccharide 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-36 UC

Page 1 of 6

HESI101014
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 180

Flash Point/Range (C): 82

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LGC-36 UC

Page 2 of 6

HESI101015
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.086

Density @ 20 C (lbs./gallon): 9.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. Causes drying of the skin.

Eye Contact May cause eye irritation.

LGC-36 UC

Page 3 of 6

HESI101016
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

LGC-36 UC

Page 4 of 6

HESI101017
DOT

 Not restricted

DOT (Bulk)

Not restricted in accordance with the terms and conditions of 49 CFR 173.120(b)(3).

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

LGC-36 UC

Page 5 of 6

HESI101018
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-36 UC

Page 6 of 6

HESI101019
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-36P

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-36P

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Proprietary Component 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-36P

Page 1 of 6

HESI101020
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 240

Flash Point/Range (C): > 116

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-36P

Page 2 of 6

HESI101021
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Slurry

Color: Off white

Odor: Odorless

pH: 6.5 - 7.5 (1%)

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

LGC-36P

Page 3 of 6

HESI101022
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

LGC-36P

Page 4 of 6

HESI101023
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

LGC-36P

Page 5 of 6

HESI101024
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-36P

Page 6 of 6

HESI101025
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-4B

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-4B

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycol ether 30 - 60% 100 ppm (S) 100 ppm (S)

Guar gum 9000-30-0 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. May be absorbed through the

skin.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-4B

Page 1 of 6

HESI100954
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 145

Flash Point/Range (C): Not DeterminedMin: > 62

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

LGC-4B

Page 2 of 6

HESI100955
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Tan

Odor: Ether

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 300

Boiling Point/Range (C): Not DeterminedMin: > 148

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

LGC-4B

Page 3 of 6

HESI100956
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S.,Combustible Liquid, NA1993, III

(Contains Heavy Aromatic Naphtha, Dipropylene Glycol Ether)

Canadian TDG

Not restricted

LGC-4B

Page 4 of 6

HESI100957
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-4B

Page 5 of 6

HESI100958
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-4B

Page 6 of 6

HESI100959
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-8

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-8

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 30 - 60% Not applicable Not applicable

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-8

Page 1 of 6

HESI100960
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 152

Flash Point/Range (C): 64Max: < 66Min: > 62

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Gel

Color: Yellowish

LGC-8

Page 2 of 6

HESI100961
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.063

Density @ 20 C (lbs./gallon): 8.62

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 300

Boiling Point/Range (C): 90

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1.6

Vapor Density (Air=1): > 1

Percent Volatiles: 50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

LGC-8

Page 3 of 6

HESI100962
Chronic Effects/Carcinogenicity Prolonged or repeated application of a similar product to the skin of laboratory mice

without washing between applications resulted in increased incidence of skin tumors.

It is suspected that tumors may be due in part to severely irritated conditions from

continous contact with the product. Limited studies on oils that are very active

carcinogens have shown washing the animals' skin with soap and water between

applications greatly decreases the incidence of tumors. In light of these studies,

good personal hygiene is essential with the use of this product.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

LGC-8

Page 4 of 6

HESI100963
DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

LGC-8

Page 5 of 6

HESI100964
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-8

Page 6 of 6

HESI100965
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-V

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-V

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

Guar gum derivative 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if inhaled. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-V

Page 1 of 6

HESI101026
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 150

Flash Point/Range (C): Not DeterminedMin: > 65

Flash Point Method: Not Determined

Autoignition Temperature (F): 495

Autoignition Temperature (C): 257

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellowish

LGC-V

Page 2 of 6

HESI101027
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 300

Boiling Point/Range (C): 148

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Lung disorders.

LGC-V

Page 3 of 6

HESI101028
Chronic Effects/Carcinogenicity Prolonged or repeated application of a similar product to the skin of laboratory mice

without washing between applications resulted in increased incidence of skin tumors.

It is suspected that tumors may be due in part to severely irritated conditions from

continous contact with the product. Limited studies on oils that are very active

carcinogens have shown washing the animals' skin with soap and water between

applications greatly decreases the incidence of tumors. In light of these studies,

good personal hygiene is essential with the use of this product.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

LGC-V

Page 4 of 6

HESI101029
DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

LGC-V

Page 5 of 6

HESI101030
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-V

Page 6 of 6

HESI101031
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-V UC

Revision Date: 22-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-V UC

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 30 - 60% Not applicable Not applicable

Naphtha, hydrotreated heavy 64742-48-9 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause headache, dizziness, and other central nervous system effects. May

cause allergic respiratory reaction. May be harmful if swallowed. May cause eye,

skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-V UC

Page 1 of 6

HESI101032
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 180

Flash Point/Range (C): 82

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LGC-V UC

Page 2 of 6

HESI101033
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.086

Density @ 20 C (lbs./gallon): 9.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. Causes drying of the skin.

Eye Contact May cause eye irritation.

LGC-V UC

Page 3 of 6

HESI101034
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

LGC-V UC

Page 4 of 6

HESI101035
DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

LGC-V UC

Page 5 of 6

HESI101036
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-V UC

Page 6 of 6

HESI101037
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-V ZD

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-V ZD

Synonyms: None

Chemical Family: Guar gum Synthetic Mineral oil Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-V ZD

Page 1 of 6

HESI101038
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185

Flash Point/Range (C): 85

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Launder contaminated clothing before

reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Store at temperatures between 70 and 120 F (21 and 49C)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-V ZD

Page 2 of 6

HESI101039
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Mild hydrocarbon

pH: 9.5 (1%)

Specific Gravity @ 20 C (Water=1): 1.01

Density @ 20 C (lbs./gallon): 8.41

Bulk Density @ 20 C (lbs/ft3): 62.94

Boiling Point/Range (F): > 420

Boiling Point/Range (C): > 216

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: < 55

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

LGC-V ZD

Page 3 of 6

HESI101040
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

LGC-V ZD

Page 4 of 6

HESI101041
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Not applicable

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

LGC-V ZD

Page 5 of 6

HESI101042
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-V ZD

Page 6 of 6

HESI101043
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-VI

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-VI

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

Guar gum derivative 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-VI

Page 1 of 6

HESI101044
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 150

Flash Point/Range (C): 65

Flash Point Method: TCC

Autoignition Temperature (F): 495

Autoignition Temperature (C): 257

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Gel

Color: Light brown

LGC-VI

Page 2 of 6

HESI101045
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 0.2

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

LGC-VI

Page 3 of 6

HESI101046
Chronic Effects/Carcinogenicity Prolonged or repeated application of a similar product to the skin of laboratory mice

without washing between applications resulted in increased incidence of skin tumors.

It is suspected that tumors may be due in part to severely irritated conditions from

continous contact with the product. Limited studies on oils that are very active

carcinogens have shown washing the animals' skin with soap and water between

applications greatly decreases the incidence of tumors. In light of these studies,

good personal hygiene is essential with the use of this product.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

LGC-VI

Page 4 of 6

HESI101047
DOT (Bulk)

Combustible Liquid, N.O.S.,Combustible Liquid, NA1993, III

(Contains Diesel)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

LGC-VI

Page 5 of 6

HESI101048
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-VI

Page 6 of 6

HESI101049
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-VI UC

Revision Date: 22-Sep-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-VI UC

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 30 - 60% Not applicable Not applicable

Naphtha, hydrotreated heavy 64742-48-9 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LGC-VI UC

Page 1 of 6

HESI101050
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 180

Flash Point/Range (C): 82

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LGC-VI UC

Page 2 of 6

HESI101051
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.086

Density @ 20 C (lbs./gallon): 9.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

LGC-VI UC

Page 3 of 6

HESI101052
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

LGC-VI UC

Page 4 of 6

HESI101053
DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

LGC-VI UC

Page 5 of 6

HESI101054
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-VI UC

Page 6 of 6

HESI101055
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-VI ZD

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-VI ZD

Synonyms: None

Chemical Family: Guar gum Synthetic Mineral oil Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum derivative 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-VI ZD

Page 1 of 6

HESI101056
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185

Flash Point/Range (C): 85

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Launder contaminated clothing before

reuse. Material is slippery underfoot.

Storage Information Store at temperatures between 70 and 120 F (21 and 49C) Store away from

oxidizers. Store in a cool well ventilated area. Keep container closed when not in

use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-VI ZD

Page 2 of 6

HESI101057
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Mild hydrocarbon

pH: 9.5 (1%)

Specific Gravity @ 20 C (Water=1): 1.01

Density @ 20 C (lbs./gallon): 8.41

Bulk Density @ 20 C (lbs/ft3): 62.9

Boiling Point/Range (F): > 420

Boiling Point/Range (C): > 216

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: < 55

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

LGC-VI ZD

Page 3 of 6

HESI101058
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

LGC-VI ZD

Page 4 of 6

HESI101059
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Not applicable

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

LGC-VI ZD

Page 5 of 6

HESI101060
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-VI ZD

Page 6 of 6

HESI101061
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LGC-VI ZD B

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LGC-VI ZD B

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 30 - 60% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LGC-VI ZD B

Page 1 of 6

HESI101062
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 170

Flash Point/Range (C): 77

Flash Point Method: PMCC

Autoignition Temperature (F): > 475

Autoignition Temperature (C): > 246

Flammability Limits in Air - Lower (%): 1.3

Flammability Limits in Air - Upper (%): 8.1

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LGC-VI ZD B

Page 2 of 6

HESI101063
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky to pale yellow

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.05 +/-0.02

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): 20

Freezing Point/Range (C): -6.7

Vapor Pressure @ 20 C (mmHg): < 0.13

Vapor Density (Air=1): 5.6

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause chemical pneumonia. If heated: May

cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

LGC-VI ZD B

Page 3 of 6

HESI101064
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

Canadian TDG

LGC-VI ZD B

Page 4 of 6

HESI101065
Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LGC-VI ZD B

Page 5 of 6

HESI101066
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LGC-VI ZD B

Page 6 of 6

HESI101067
HESI101068
HESI101069
HESI101070
HESI101071
HESI101072
HESI101073
HESI101074
HESI101075
HESI101076
HESI101077
HESI101078
HESI101079
HESI101080
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LIQUID HEC

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LIQUID HEC

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Petroleum hydrocarbons 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LIQUID HEC

Page 1 of 6

HESI101081
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185

Flash Point/Range (C): 85

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep container closed when not in use. Product has a

shelf life of 24 months. Keep from heat, sparks, and open flames. Store in a cool well

ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

LIQUID HEC

Page 2 of 6

HESI101082
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Mild hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.94

Density @ 20 C (lbs./gallon): 7.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 442

Boiling Point/Range (C): 227

Freezing Point/Range (F): -45

Freezing Point/Range (C): -43

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause central nervous system

depression including headache, dizziness, drowsiness, incoordination, slowed

reaction time, slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and

central nervous system depression. May cause liver and kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

LIQUID HEC

Page 3 of 6

HESI101083
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Hydrocarbons)

Canadian TDG

Not restricted

LIQUID HEC

Page 4 of 6

HESI101084
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

LIQUID HEC

Page 5 of 6

HESI101085
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LIQUID HEC

Page 6 of 6

HESI101086
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LOSURF-2000LTM

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LOSURF-2000LTM

Synonyms: None

Chemical Family: Sulfonate Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium sulfate 7757-82-6 1 - 5% Not applicable Not applicable

Sulfate 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. Aid in breathing, if necessary, and get immediate medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically.

LOSURF-2000LTM

Page 1 of 5

HESI101099
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: CC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Store at temperatures between 40 and 90 F (5 and 35 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear Yellow

Odor: Mild

pH: 6.5-8.5 (10%)

Specific Gravity @ 20 C (Water=1): 1.126

LOSURF-2000LTM

Page 2 of 5

HESI101100
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.405

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: ~50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperatures over 85 F (29 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen sulfide. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause irritation (upper respiratory) which includes soreness of the nose and

throat, coughing and sneezing.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Large doses may cause nausea, vomiting and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

LOSURF-2000LTM

Page 3 of 5

HESI101101
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

LOSURF-2000LTM

Page 4 of 5

HESI101102
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1330 gallons based on Sodium dodecylbenzene

sulfonate (CAS: 25155-30-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LOSURF-2000LTM

Page 5 of 5

HESI101103
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LOSURF-300 NONIONIC SURFACTANT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LOSURF-300 NONIONIC SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated nonylphenol 5 - 10% Not applicable Not applicable

Light aromatic solvent 64742-95-6 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

LOSURF-300 NONIONIC SURFACTANT

Page 1 of 6

HESI101087
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 65

Flash Point/Range (C): 18

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

LOSURF-300 NONIONIC SURFACTANT

Page 2 of 6

HESI101088
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 7.5

Specific Gravity @ 20 C (Water=1): 0.91

Density @ 20 C (lbs./gallon): 7.59

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 28

Freezing Point/Range (C): -2

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 60-65

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. Can dry skin.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause headache, dizziness, nausea, vomiting,

gastrointestinal irritation and central nervous system depression.

LOSURF-300 NONIONIC SURFACTANT

Page 3 of 6

HESI101089
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Contains petroleum

distillates which have been shown to cause skin cancer in laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II, (17.2 C)

NAERG 128

Canadian TDG

LOSURF-300 NONIONIC SURFACTANT

Page 4 of 6

HESI101090
Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, II, (17.2 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, II, (17.2 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 658 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

LOSURF-300 NONIONIC SURFACTANT

Page 5 of 6

HESI101091
Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LOSURF-300 NONIONIC SURFACTANT

Page 6 of 6

HESI101092
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LOSURF-300MTM

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LOSURF-300MTM

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

1,2,4 Trimethylbenzene 95-63-6 0 - 1% 25 ppm Not applicable

Naphthalene 91-20-3 0 - 1% 10 ppm 10 ppm

Poly(oxy-1,2-ethanediyl),

alpha-(4-nonylphenyl)-

omega-hydroxy-, branched

127087-87-0 5 - 10% Not applicable Not applicable

Heavy aromatic petroleum

naphtha

64742-94-5 10 - 30% 5 mg/m3 5 mg/m3

Ethanol 64-17-5 30 - 60% 1000 ppm 1000 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

LOSURF-300MTM

Page 1 of 6

HESI101093
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 57

Flash Point/Range (C): 14

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 3.3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

Store in a cool well ventilated area. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves. Viton gloves

Skin Protection Rubber apron.

LOSURF-300MTM

Page 2 of 6

HESI101094
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 6 - 9.5

Specific Gravity @ 20 C (Water=1): .918

Density @ 20 C (lbs./gallon): 7.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 173.1

Boiling Point/Range (C): 78.4

Freezing Point/Range (F): -76.9

Freezing Point/Range (C): -60.51

Vapor Pressure @ 20 C (mmHg): 40 (etoh)

Vapor Density (Air=1): > 10

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 3.3

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

LOSURF-300MTM

Page 3 of 6

HESI101095
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity

The International Agency for Research on Cancer (IARC) has evaluated naphthalene

and determined it to be a possible carcinogen to humans (Group 2B, based on

sufficient evidence in experimental animals and inadequate evidence in humans).

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

LOSURF-300MTM

Page 4 of 6

HESI101096
DOT

Flammable Liquid, N.O.S., 3, UN1993, II, (14 C)

(Contains Ethanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Ethanol), 3, UN1993, II, (14 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Ethanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol), 3, II, (14 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

1,2,4-Trimethylbenzene//95-63-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 658 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

LOSURF-300MTM

Page 5 of 6

HESI101097
NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B2 Flammable Liquids

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LOSURF-300MTM

Page 6 of 6

HESI101098
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: LP-65

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: LP-65

Synonyms: None

Chemical Family: Blend

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 5 - 10% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

LP-65

Page 1 of 5

HESI101104
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): Not Determined

Flash Point Method: SFCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

LP-65

Page 2 of 5

HESI101105
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Slight

pH: 6.5-7.5 (100%)

Specific Gravity @ 20 C (Water=1): 1.169-1.181

Density @ 20 C (lbs./gallon): 9.74-9.84

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 0

Freezing Point/Range (C): -17.8

Vapor Pressure @ 20 C (mmHg): 19.3 (21C)

Vapor Density (Air=1): > 1

Percent Volatiles: 59

Evaporation Rate (Butyl Acetate=1): <1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Ammonia. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation In high air concentrations:

May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause slight eye irritation.

Ingestion In large amounts: May be harmful if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

LP-65

Page 3 of 5

HESI101106
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

LP-65

Page 4 of 5

HESI101107
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6294 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

LP-65

Page 5 of 5

HESI101108
MATERIAL SAFETY DATA SHEET 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Identifier : MA-844W 

Chemical Name : Not applicable, a blend 

Chemical Family : Surfactants and Solvent Mixture 

Manufacturer : CESI Chemical (a Flotek Industries, Inc. company) 

: 1004 S. Plainsman Road, Marlow, OK 73055 

Emergency Phone : 1-405-282-8510 

Prepared by : Todd Sanner 

Phone : (580)-658-6608 

Issue Date : 04/03/02 

Revised Date : 11/20/02 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

Ingredient : Isopropanol 

CAS No. : 67-63-0 

Wt. Percent Range : 10-20 

OSHA PEL : 400 ppm TWA 

ACGIH TLV : 400 ppm TWA 

LD50 : Peroral 6.48 ml/kg (rat) Percutaneous 8.0 ml/kg (rabbit) 

LC50 : Fathead Minnow 8,300 mg/l (96 h) Daphnia 7,550 mg/l (48 h) 

Ingredient : Cyclohexenes 

CAS No. : 5989-27-5 

Wt. Percent Range : Proprietary 

OSHA PEL : Not established 

ACGIH TLV : Not established 

LD50 : Dermal >5g/kg (rabbit) Oral >5g/kg (rat) 

LC50 : No data available 

Ingredient : Alcohols 

CAS No. : Proprietary 

Wt. Percent Range : Proprietary 

OSHA PEL : Not established 

ACGIH TLV : Not established 

LD50 : No data available 

LC50 : No data available 

Ingredient : Alkyl Alkoxylate 

CAS No. : Proprietary 

Wt. Percent Range : Proprietary 

OSHA PEL : Not established 

ACGIH TLV : Not established 

LD50 : No data available 

LC50 : No data available 

3. HAZARDS IDENTIFICATION 

Human health hazards 

Acute health hazards : Eye, skin and inhalation irritant. Harmful if swallowed. 

Chronic health hazards : Defatting or dermatitis of the skin. 

Route(s) of entry : Eyes, skin, inhalation, ingestion 

Safety hazards : Flammable liquid 

Environmental hazards : Toxic to aquatic organisms 

HESI101109
4. FIRST AID MEASURES 

Eye : Remove contact lenses at once. Immediately flush with copious amounts of 

water for at least 15 minutes while holding eyelids open. If irritation persists, 

seek medical attention. 

Skin : Wash affected area thoroughly with soap and water. Remove contaminated 

clothing and launder before reuse. If irritation develops, seek medical attention. 

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is 

difficult, give oxygen. Seek prompt medical attention. 

Ingestion : If victim is conscious, give one or two glasses of water. DO NOT induce 

vomiting. If vomiting occurs spontaneously, keep the victim's head below the 

hips to prevent aspiration into the lungs. Never give anything by mouth to an 

unconscious person. Seek immediate medical attention. 

5. FIRE FIGHTING MEASURES 

Flash Point : 770

F (250C) (Closed Cup) 

Lower Explosion Limit : 0.7% (Cyclohexenes) 

Upper Explosion limit : 6.1% (Cyclohexenes) 

Extinguishing Media : carbon dioxide, foam or dry chemical 

Protective equipment : NIOSH/MSHA approved self-contained breathing apparatus (SCBA) and 

turnout gear. 

Hazardous combustion 

products : Carbon monoxide may be evolved if incomplete combustion occurs 

6. ACCIDENTAL RELEASE MEASURES 

Personal precautions : Wear hand, eye, protective clothing and respiratory protective equipment to 

eliminate contact. 

General precautions : Eliminate ignition sources. Evacuate all non-essential personnel. 

Small spills : Soak up residue with an inert absorbent and place into appropriate containers 

for disposal or reclamation. Flush contaminated area thoroughly with water. 

Retain washings as contaminated waste. 

Large spills : If possible stop the flow of chemical. Dike to contain and prevent spreading. 

Remove with vacuum truck or pump to salvage vessels. Treat residue as for 

small spills. 

7. HANDLING AND STORAGE 

Handling : Avoid contact with eyes, skin and clothing. Avoid breathing vapors. Use with 

adequate ventilation. Do not take internally. Wear appropriate protective 

clothing and equipment during handling. Wash thoroughly after handling. 

Remove contaminated clothing and launder before reuse. 

Storage : Store away from heat, sparks and open flames. Keep container closed when 

not in use. Store drums with the bung up. Carefully vent container before 

removing bung. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

Occupational exposure 

standards : Not established for the product. 

Hand protection : Nitrile rubber gloves. 

Eye protection : Chemical splash goggles and face shield if conditions warrant. 

Respiratory protection : Not normally required. 

Engineering control 

measures : General (mechanical) room ventilation is expected to be satisfactory. 

Other : Emergency eye wash fountains and safety showers should be in the immediate 

vicinity of any potential exposure. 

2

HESI101110
9. PHYSICAL AND CHEMCIAL PROPERTIES 

Form : Liquid 

Appearance : Clear to opaque 

Color : Colorless to milky white 

Odor : Citrus 

Specific Gravity : 0.9391 

Bulk Density : 7.837 lbs/gal 

Boiling Point : 3100

 F (154.40 C) 

Freezing Point : < -420 F (< -41.10

 C) 

Solubility in water : 69-79% 

pH : Not determined 

Percent Volatiles : 55-75% weight 

Vapor Pressure : Not determined 

10. STABILITY AND REACTIVITY 

Stability : Stable 

Conditions to avoid : Heat, sparks, open flames 

Hazardous polymerization : Will not occur 

Hazardous decomposition 

products : None 

Incompatibility : Strong oxidizing agents 

11. TOXICOLOGICAL INFORMATION 

Acute Effects 

Eye : Causes moderate to severe irritation. If not removed promptly, permanent injury 

may result. 

Skin : May cause mild to moderate irritation with brief contact. Prolonged contact may 

cause severe irritation, drying, defatting and dermatitis. Contains a potential 

skin sensitizer (Cyclohexenes). 

Inhalation : May cause nose, throat and general upper respiratory tract irritation, coughing 

and headache. 

Ingestion : Product is harmful if swallowed. May cause vomiting, headache, nausea, 

diarrhea, abdominal cramps, drowsiness and dizziness. 

Chronic Effects : No other known chronic effects. 

Carcinogenicity : None of the ingredients are listed in NTP, IARC monographs or OSHA 

regulated. 

12. ECOLOGICAL INFORMATION 

Environmental Fate : No information is available on the product however it is expected to be toxic to 

aquatic organisms. 

13. DISPOSAL CONSIDERATIONS 

Waste disposal : Recycle if possible. Otherwise dispose to licensed disposal contractor. 

Product disposal : Recycle if possible. Otherwise comply with all local, state and federal 

regulations. 

Container disposal : Drain container thoroughly. Triple rinse with water. Send to reclaimer or dispose 

of properly. Comply with all local, state and federal regulations. 

14. TRANSPORT INFORMATION 

United States D.O. T. 

DOT Shipping Name : Flammable liquids, N.O.S. (contains Isopropanol, CAS#67-63-0 and 

Cyclohexenes, CAS# 5989-27-5), 3, UN1993, PGIII 

Label(s) required : Flammable liquid 

Hazard Class : 3 

UN/NA number : UN1993 

Packaging group : PG III 

Emergency Phone : (405) 282-8510 

3

HESI101111
15. REGULATORY INFORMATION 

This document has been prepared in accordance with the MSDS requirements 

of the OSHA Hazard Communication Standard 29 CFR 1910.1200. 

OSHA Classification : Hazardous 

TSCA (USA) : All components listed. 

DSL (Canada) : All components listed. 

SARA Title III 

Section 302 : Extremely Hazardous Substances (40CFR355): This product does not contain 

ingredients listed in Appendix A and B. 

Sections 311/312 

Immediate (acute) health 

hazard 

: YES 

Delayed (chronic) health 

hazard 

: YES 

Fire hazard : YES 

Sudden Release of 

Pressure Hazard 

: NO 

Reactive Hazard : NO 

Section 313 Reportable 

Quantities 

: None 

CERCLA If the reportable quantity of this product is accidentally spilled, the incident is 

subject to the provisions of the Comprehensive Environmental Response, 

Compensation and Liability Act (CERCLA) and must be reported to the National 

Response Center by calling (800) 424-8802. 

Reportable Quantity : Not determined for the product. 

16. OTHER INFORMATION 

NFPA 704 

Health : 2 

Fire : 3 

Reactivity : 0 

Special : None 

HMIS 

Health : 2 

Fire : 3 

Reactivity : 0 

Special : None 

Disclaimer of Liability : The information contained in this MSDS was obtained from sources that we 

believe are reliable. However, the information is without any warranty, express 

or implied, regarding correctness. The methods of handling, storage, use and 

disposal of the product are beyond our control and may be outside the scope of 

our knowledge. For these reasons, we do not assume responsibility and 

expressly disclaim liability for loss, damage or expense arising out of or in any 

way connected with the handling, storage, use or disposal of the product. 

4

HESI101112
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MATRIXFLO II

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MATRIXFLO II

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dimethyl glutarate 1119-40-0 55-65 Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MATRIXFLO II

Page 1 of 5

HESI101113
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 212

Flash Point/Range (C): 100

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool, dry location. Store in a well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Sweet

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.08

MATRIXFLO II

Page 2 of 5

HESI101114
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 196

Boiling Point/Range (C): 91

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.06

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 5.5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 5900 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 1300 ppm/6 hr. (Rat)

MATRIXFLO II

Page 3 of 5

HESI101115
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 18-24 g/l (Pimephales promelas)

Acute Crustaceans Toxicity:TLM48: 3600 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Empty container completely. Transport with all closures in place. Return for reuse or

dispose in a sanitary landfill according to national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

MATRIXFLO II

Page 4 of 5

HESI101116
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MATRIXFLO II

Page 5 of 5

HESI101117
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: METHANOL

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: METHANOL

Synonyms: None

Chemical Family: Alcohol

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Methanol 67-56-1 60 - 100% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

METHANOL

Page 1 of 6

HESI101118
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 54

Flash Point/Range (C): 11

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 3, Reactivity 0

HMIS Ratings: Health 1, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

METHANOL

Page 2 of 6

HESI101119
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.79

Density @ 20 C (lbs./gallon): 6.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 148

Boiling Point/Range (C): 64

Freezing Point/Range (F): -144

Freezing Point/Range (C): -98

Vapor Pressure @ 20 C (mmHg): 97

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 5.9

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 6.58

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 32.01

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation. May be

absorbed through the skin and produce effects similar to those caused by inhalation

and/or ingestion.

Eye Contact May cause moderate eye irritation.

Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May be harmful if swallowed.

METHANOL

Page 3 of 6

HESI101120
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 5628 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Methanol, 3, (6.1), UN1230, II, (11 C)

RQ (Methanol - 2273 kg.)

NAERG 131

Canadian TDG

METHANOL

Page 4 of 6

HESI101121
Methanol, 3, (6.1), UN1230, II, (11 C)

ADR

UN1230,Methanol, 3, (6.1), II

Air Transportation

ICAO/IATA

UN1230,Methanol, 3, (6.1), II

RQ (Methanol - 2273 kg.)

Sea Transportation

IMDG

UN1230,Methanol, 3, (6.1), II, (11 C)

RQ (Methanol - 2273 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 760 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

METHANOL

Page 5 of 6

HESI101122
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

METHANOL

Page 6 of 6

HESI101123
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-67

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-67

Synonyms: None

Chemical Family: Hydroxide

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 10 - 30% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-67

Page 1 of 6

HESI101124
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong acids.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

MO-67

Page 2 of 6

HESI101125
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: 14

Specific Gravity @ 20 C (Water=1): 1.27

Density @ 20 C (lbs./gallon): 10.62

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 234

Boiling Point/Range (C): 112

Freezing Point/Range (F): 7

Freezing Point/Range (C): -14

Vapor Pressure @ 20 C (mmHg): 110

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-67

Page 3 of 6

HESI101126
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Sodium Hydroxide Solution, 8, UN1824, II

NAERG 154

Canadian TDG

Sodium Hydroxide Solution, 8, UN1824, II

ADR

UN1824,Sodium Hydroxide Solution, 8, II

Air Transportation

ICAO/IATA

UN1824,Sodium Hydroxide Solution, 8, II

Sea Transportation

IMDG

MO-67

Page 4 of 6

HESI101127
UN1824,Sodium Hydroxide Solution, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Hydroxide//1310-73-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 376 Gallons based on Sodium hydroxide (CAS:

1310-73-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

MO-67

Page 5 of 6

HESI101128
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-67

Page 6 of 6

HESI101129
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-85

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-85

Synonyms: None

Chemical Family: Organic acid

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Proprietary 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-85

Page 1 of 6

HESI101130
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 329

Flash Point/Range (C): 165

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 1.26

MO-85

Page 2 of 6

HESI101131
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.049

Density @ 20 C (lbs./gallon): 8.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: 1

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Soluble in isopropanol

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 9000

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-85

Page 3 of 6

HESI101132
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

(Contains Phosphate Esters Solution)

MO-85

Page 4 of 6

HESI101133
Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

MO-85

Page 5 of 6

HESI101134
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-85

Page 6 of 6

HESI101135
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-85M

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-85M

Synonyms: None

Chemical Family: Ester

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkyl Esters HMIRC5870 Jan04 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MO-85M

Page 1 of 6

HESI101136
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Alcohol

pH: 2.3 (5%)

MO-85M

Page 2 of 6

HESI101137
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.049

Density @ 20 C (lbs./gallon): 8.76

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): > 1

Percent Volatiles: < 1

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

MO-85M

Page 3 of 6

HESI101138
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

(Contains Phosphate Esters Solution)

Sea Transportation

MO-85M

Page 4 of 6

HESI101139
IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Phosphate Esters), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals Glycol ether

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class To Be Determined

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

MO-85M

Page 5 of 6

HESI101140
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-85M

Page 6 of 6

HESI101141
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MO-IV BREAKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MO-IV BREAKER

Synonyms: None

Chemical Family: Metal oxide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Proprietary component Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

MO-IV BREAKER

Page 1 of 5

HESI101142
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location. Store in a cool well ventilated area. Product has a shelf

life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 10.5

MO-IV BREAKER

Page 2 of 5

HESI101143
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 3.81

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 30

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 40.32

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

MO-IV BREAKER

Page 3 of 5

HESI101144
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

MO-IV BREAKER

Page 4 of 5

HESI101145
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MO-IV BREAKER

Page 5 of 5

HESI101146
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MORFLO III SURFACTANT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MORFLO III SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dodecylbenzene sulfonic acid 27176-87-0 10 - 30% Not applicable Not applicable

1-Methoxy-2-propanol 107-98-2 10 - 30% 100 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause headache, dizziness, and other central

nervous system effects. May cause allergic skin reaction. May be harmful if

swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MORFLO III SURFACTANT

Page 1 of 6

HESI101147
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 138

Flash Point/Range (C): 58

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep from heat, sparks, and

open flames. Keep container closed when not in use. Product has a shelf life of 24

months. Store at temperatures between 50 and 100 F (10 and 37.8 C). Do not

freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MORFLO III SURFACTANT

Page 2 of 6

HESI101148
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark amber

Odor: Solvent

pH: 2

Specific Gravity @ 20 C (Water=1): 1.066

Density @ 20 C (lbs./gallon): 8.88

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 56

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

MORFLO III SURFACTANT

Page 3 of 6

HESI101149
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (58.9 C)

(Contains Dodecylbenzenesulfonic Acid, Methoxypropanol)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Dodecylbenzenesulfonic Acid, Methoxypropanol), 3, (8), UN2924, III, (58.9

C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Dodecylbenzenesulfonic Acid, Methoxypropanol), 3, (8), III

Air Transportation

MORFLO III SURFACTANT

Page 4 of 6

HESI101150
ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Dodecylbenzenesulfonic Acid, Methoxypropanol Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Dodecylbenzenesulfonic Acid, Methoxypropanol), 3, (8), III, (58.9

C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//107-98-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 632 Gallons based on Dodecylbenzene sulfonic

acid (CAS: 27176-87-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

E Corrosive Material

D2B Toxic Materials

MORFLO III SURFACTANT

Page 5 of 6

HESI101151
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MORFLO III SURFACTANT

Page 6 of 6

HESI101152
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MSA-III US

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MSA-III US

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Thioglycolic acid 68-11-1 10 - 30% 1 ppm Not applicable

Ethoxylated alkyl amines 5 - 10% Not applicable Not applicable

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be fatal if

swallowed. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Remove contaminated shoes and discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MSA-III US

Page 1 of 6

HESI101159
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 43

Flash Point/Range (C): 6

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Fight fire from a safe distance and from a protected location.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresEvacuate all persons from the area. Use only competent persons for cleanup. Use

appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas. Prevent contamination of

soil.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Neutralize to pH of 6-8. Contain spill with sand or other inert

materials. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store away from alkalis. Keep from heat, sparks, and

open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator. Positive pressure self-contained breathing

apparatus in enclosed areas.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MSA-III US

Page 2 of 6

HESI101160
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Strong

pH: 2.1-2.3

Specific Gravity @ 20 C (Water=1): 0.934 - 0.946

Density @ 20 C (lbs./gallon): 7.8 - 7.9

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 83.8 - 102.4

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 19-21

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Hydrogen chloride. Carbon monoxide and

carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Massive inhalation immediately dangerous to life and health. Causes severe

respiratory irritation. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact Causes severe eye burns.

Ingestion May be fatal if swallowed. Causes burns of the mouth, throat and stomach. May

cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and central

nervous system depression.

Aggravated Medical Conditions Skin disorders. Lung disorders.

MSA-III US

Page 3 of 6

HESI101161
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Thioglycolic Acid), 3, (8), II, (6 C)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Thioglycolic Acid), 3, (8), UN2924, II, (6 C)

MSA-III US

Page 4 of 6

HESI101162
ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Thioglycolic Acid), 3, (8), II

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), II

(Contains Isopropanol, Thioglycolic Acid Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Thioglycolic Acid), 3, (8), II, (6 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

MSA-III US

Page 5 of 6

HESI101163
Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1B Toxic Materials

D2B Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MSA-III US

Page 6 of 6

HESI101164
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MSA II INHIBITOR

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MSA II INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetone 67-64-1 1-5 500 ppm 1000 ppm

Thiourea 62-56-6 10-30 Not applicable Not applicable

Ethylene glycol 107-21-1 10-30 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects. Potential carcinogen. Combustible. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

MSA II INHIBITOR

Page 1 of 6

HESI101153
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 120

Flash Point/Range (C): 48

Flash Point Method: SFCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Vapors are heavier than air and may accumulate in low areas. Vapors may

travel along the ground to be ignited at distant locations. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 0 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Neoprene gloves. Nitrile gloves. Use Viton or 4H gloves.

Skin Protection Rubber apron. Rubber boots.

MSA II INHIBITOR

Page 2 of 6

HESI101154
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Pungent

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.09

Density @ 20 C (lbs./gallon): 9.08

Bulk Density @ 20 C (lbs/ft3): 68

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -20

Freezing Point/Range (C): -29

Vapor Pressure @ 20 C (mmHg): 16.4

Vapor Density (Air=1): >1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide. Hydrogen

chloride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause moderate skin irritation. May cause an allergic skin reaction.

Eye Contact May cause severe eye irritation. May cause permanent eye damage.

Ingestion Harmful if swallowed. May cause stomach discomfort. May cause kidney damage.

May affect the blood and blood system. May cause thyroid damage.

MSA II INHIBITOR

Page 3 of 6

HESI101155
Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders. Blood disorders. Central nervous

system disorders. Respiratory disorders. Thyroid disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause liver, heart, blood and brain damage. Contains thiourea, a suspected

carcinogen of the liver and thyroid. Chronically high exposures cause bone marrow

depression with anemia, leukopenia and thromboxytopenia. Prolonged or repeated

exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (48.9 C)

MSA II INHIBITOR

Page 4 of 6

HESI101156
(Contains Acetone)

RQ (Thiourea - 4.5 kg.)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Acetone), 3, UN1993, III, (48.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Acetone), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Acetone Solution)

RQ (Thiourea - 4.5 kg.)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Acetone), 3, III, (48.9 C)

RQ (Thiourea - 4.5 kg.)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Thiourea//62-56-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 11 Gallons based on Thiourea (CAS: 62-56-6).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

MSA II INHIBITOR

Page 5 of 6

HESI101157
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B3 Combustible Liquids

D1B Toxic Materials

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MSA II INHIBITOR

Page 6 of 6

HESI101158
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MUSOL A SOLVENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MUSOL A SOLVENT

Synonyms: None

Chemical Family: Blend

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol monobutyl

ether

111-76-2 60 - 100% 20 ppm 50 ppm

Oxylated alcohol 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

MUSOL A SOLVENT

Page 1 of 6

HESI101165
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 152

Flash Point/Range (C): 66

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 10.6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MUSOL A SOLVENT

Page 2 of 6

HESI101166
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Mild

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.55

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 340

Boiling Point/Range (C): 171

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 5

Vapor Density (Air=1): <1

Percent Volatiles: 50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May be absorbed through the skin and contribute to the

symptoms listed under ingestion.

Eye Contact May cause eye burns.

Ingestion May affect the blood and blood system. Coma, shock and death may occur.

Aggravated Medical Conditions Skin disorders. Eye ailments.

MUSOL A SOLVENT

Page 3 of 6

HESI101167
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

Prolonged or repeated exposure may cause kidney, lung and blood effects. May

contain ethylene oxide in the headspace of the drum. Ethylene oxide is a cancer and

reproductive hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

MUSOL A SOLVENT

Page 4 of 6

HESI101168
DOT (Bulk)

NA1993, Combustible Liquid, N.O.S., Combustible Liquid, III

(Contains Ethylene Glycol Monobutyl Ether)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

MUSOL A SOLVENT

Page 5 of 6

HESI101169
WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MUSOL A SOLVENT

Page 6 of 6

HESI101170
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MUSOL E SOLVENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MUSOL E SOLVENT

Synonyms: None

Chemical Family: Glycol Ether

Application: Surfactant Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

1-Methoxy-2-propanol 107-98-2 60 - 100% 100 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MUSOL E SOLVENT

Page 1 of 6

HESI101171
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 89

Flash Point/Range (C): 31

Flash Point Method: Not Determined

Autoignition Temperature (F): 532

Autoignition Temperature (C): 277

Flammability Limits in Air - Lower (%): 3

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. May discolor mild steel. Product has a shelf life of 36

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MUSOL E SOLVENT

Page 2 of 6

HESI101172
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Ether

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 243

Boiling Point/Range (C): 117

Freezing Point/Range (F): -139

Freezing Point/Range (C): -95

Vapor Pressure @ 20 C (mmHg): 10.9

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.01

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May produce nervous

system effects such as feeling of weakness, unsteady walk, and dilation of blood

vessels.

Aggravated Medical Conditions Skin disorders. Eye ailments.

MUSOL E SOLVENT

Page 3 of 6

HESI101173
Chronic Effects/Carcinogenicity May cause testicular toxicity. May cause birth defects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3092,1-Methoxy-2-Propanol Solution, 3, III, (31.7 C)

NAERG 129

Canadian TDG

1-Methoxy-2-Propanol Solution, 3, UN3092, III, (31.7 C)

MUSOL E SOLVENT

Page 4 of 6

HESI101174
ADR

UN3092,1-Methoxy-2-Propanol Solution, 3, III

Air Transportation

ICAO/IATA

UN3092,1-Methoxy-2-Propanol Solution, 3, III

Sea Transportation

IMDG

UN3092,1-Methoxy-2-Propanol Solution, 3, III, (31.7 C)

EmS F-A, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//107-98-2

Glycol Ethers//1589-47-5

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

MUSOL E SOLVENT

Page 5 of 6

HESI101175
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MUSOL E SOLVENT

Page 6 of 6

HESI101176
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: MUSOL SOLVENT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: MUSOL SOLVENT

Synonyms: None

Chemical Family: Glycol Ether

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol monobutyl

ether

111-76-2 60 - 100% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

MUSOL SOLVENT

Page 1 of 6

HESI101177
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 153

Flash Point/Range (C): 67

Flash Point Method: DIN 51758

Autoignition Temperature (F): 446

Autoignition Temperature (C): 230

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 10.6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

MUSOL SOLVENT

Page 2 of 6

HESI101178
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Mild

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.51

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 340

Boiling Point/Range (C): 171

Freezing Point/Range (F): -94

Freezing Point/Range (C): -70

Vapor Pressure @ 20 C (mmHg): 0.76

Vapor Density (Air=1): 4.1

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 0.06

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.8

Molecular Weight (g/mole): 118.2

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Peroxides. Amphoteric metals such as aluminum, magnesium,

lead, tin, or zinc.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May produce nervous

system effects such as feeling of weakness, unsteady walk, and dilation of blood

vessels.

Aggravated Medical Conditions Skin disorders. Eye ailments.

MUSOL SOLVENT

Page 3 of 6

HESI101179
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1480 mg/kg (Rat)

Dermal Toxicity: LD50: 400-500 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 2250 mg/l (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:EC50: 1875 mg/l (Daphnia magna)

Acute Algae Toxicity: EC50: > 500 mg/l (Scenedesmus subspicatus)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Ethylene Glycol Monobutyl Ether)

Canadian TDG

Not restricted

MUSOL SOLVENT

Page 4 of 6

HESI101180
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

MUSOL SOLVENT

Page 5 of 6

HESI101181
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

MUSOL SOLVENT

Page 6 of 6

HESI101182
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: N-Zyme 3

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: N-Zyme 3

Synonyms: None

Chemical Family: Blend

Application: Enzyme

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycerine 56-81-5 30 - 60% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

N-Zyme 3

Page 1 of 5

HESI101189
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Keep container closed when not in use. Keep

refrigerated.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls None known.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Blue

Odor: Odorless

pH: 6

Specific Gravity @ 20 C (Water=1): 1.09

N-Zyme 3

Page 2 of 5

HESI101190
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.08

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

N-Zyme 3

Page 3 of 5

HESI101191
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

N-Zyme 3

Page 4 of 5

HESI101192
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

N-Zyme 3

Page 5 of 5

HESI101193
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: NEA-96M

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: NEA-96M

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hexylene glycol 107-41-5 10 - 30% 25 ppm Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

NEA-96M

Page 1 of 6

HESI101183
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 86

Flash Point/Range (C): 30

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store away from acids. Store in a cool well ventilated

area. Keep from heat, sparks, and open flames. Keep container closed when not in

use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

NEA-96M

Page 2 of 6

HESI101184
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 7-9

Specific Gravity @ 20 C (Water=1): 1.04

Density @ 20 C (lbs./gallon): 8.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

NEA-96M

Page 3 of 6

HESI101185
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (30 C)

(Contains Isopropanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (30 C)

NEA-96M

Page 4 of 6

HESI101186
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (30 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

NEA-96M

Page 5 of 6

HESI101187
WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

NEA-96M

Page 6 of 6

HESI101188
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OPTIFLO-HTE

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OPTIFLO-HTE

Synonyms: None

Chemical Family: Blend

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Walnut hulls Mixture 60 - 100% Not applicable Not applicable

Crystalline silica, quartz 14808-60-7 10 - 30% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation. May cause allergic respiratory reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

OPTIFLO-HTE

Page 1 of 7

HESI101194
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1*, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 24 months.

OPTIFLO-HTE

Page 2 of 7

HESI101195
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark black red

Odor: Fermentive

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated

temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

OPTIFLO-HTE

Page 3 of 7

HESI101196
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

OPTIFLO-HTE

Page 4 of 7

HESI101197
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

OPTIFLO-HTE

Page 5 of 7

HESI101198
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

OPTIFLO-HTE

Page 6 of 7

HESI101199
***END OF MSDS***

OPTIFLO-HTE

Page 7 of 7

HESI101200
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OPTIFLO-III DELAYED RELEASE BREAKER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OPTIFLO-III DELAYED RELEASE BREAKER

Synonyms: None

Chemical Family: Sulfate

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium persulfate 7727-54-0 60 - 100% 0.1 mg/m3 Not applicable

Crystalline silica, quartz 14808-60-7 10 - 30% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May cause allergic skin and

respiratory reaction. May be harmful if swallowed. Oxidizer.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

OPTIFLO-III DELAYED RELEASE BREAKER

Page 1 of 7

HESI101201
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 1

HMIS Ratings: Health 1, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal. Flush area with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet. Wash hands after use. Launder contaminated clothing before

reuse.

Storage Information Store away from reducing agents. Store in a cool, dry location. Product has a shelf

life of 12 months.

OPTIFLO-III DELAYED RELEASE BREAKER

Page 2 of 7

HESI101202
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron. Wear clothing appropriate for the work environment. Dusty clothing

should be laundered before reuse. Use precautionary measures to avoid creating

dust when removing or laundering clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white to tan

Odor: Mild acrid

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.76

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 56.4

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 7.9

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 228.22

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with readily oxidizable materials.

Incompatibility (Materials to

Avoid)

Avoid halogens. Contact with acids. Organic matter. All flammables, especially

petroleum products, asphalt & other volatile flammables. Amphoteric metals such as

aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

Toxic fumes. Ammonia. Sulfuric acid. Amorphous silica may transform at elevated

temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

OPTIFLO-III DELAYED RELEASE BREAKER

Page 3 of 7

HESI101203
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation. Inhaled

crystalline silica in the form of quartz or cristobalite from occupational sources is

carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

OPTIFLO-III DELAYED RELEASE BREAKER

Page 4 of 7

HESI101204
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Ammonium Persulfate, 5.1, UN1444, III

NAERG 140

Canadian TDG

Ammonium Persulfate, 5.1, UN1444, III

ADR

UN1444,Ammonium Persulfate, 5.1, III

Air Transportation

ICAO/IATA

UN1444,Ammonium Persulfate, 5.1, III

Sea Transportation

OPTIFLO-III DELAYED RELEASE BREAKER

Page 5 of 7

HESI101205
IMDG

UN1444,Ammonium Persulfate, 5.1, III

EmS F-A, S-Q

Other Shipping Information

Labels: Oxidizer

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class C Oxidizing Materials

D2B Toxic Materials

D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

OPTIFLO-III DELAYED RELEASE BREAKER

Page 6 of 7

HESI101206
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OPTIFLO-III DELAYED RELEASE BREAKER

Page 7 of 7

HESI101207
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OptiKleen-WFTM

Revision Date: 06-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OptiKleen-WFTM

Synonyms: None

Chemical Family: Not applicable

Application: Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium perborate tetrahydrate 10486-00-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May be harmful if swallowed. May be harmful if inhaled.

Oxidizer. May cause skin and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

OptiKleen-WFTM

Page 1 of 6

HESI101208
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Releases oxygen at high

temperatures.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1 , Oxidizing agent

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from combustibles. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

pH: 10.2 (1%)

Specific Gravity @ 20 C (Water=1): 0.82

OptiKleen-WFTM

Page 2 of 6

HESI101209
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 45

Boiling Point/Range (F): 266

Boiling Point/Range (C): 130

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 6.2

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 3

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 153.86

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with organic materials.

Incompatibility (Materials to

Avoid)

Organic matter. All flammables, especially petroleum products, asphalt & other

volatile flammables. Metal salts such as aluminum chloride. Contact with water.

Hazardous Decomposition

Products

Oxygen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May be absorbed through inhalation contributing

to symptoms listed under ingestion.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue. May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause gastrointestinal effects and muscular

dysfunction.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

OptiKleen-WFTM

Page 3 of 6

HESI101210
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 160-320 mg/l (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

OptiKleen-WFTM

Page 4 of 6

HESI101211
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

C Oxidizing Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

OptiKleen-WFTM

Page 5 of 6

HESI101212
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OptiKleen-WFTM

Page 6 of 6

HESI101213
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OPTIFLO-II DELAYED RELEASE BREAKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OPTIFLO-II DELAYED RELEASE BREAKER

Synonyms: None

Chemical Family: Oxidant

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium persulfate 7727-54-0 60 - 100% 0.1 mg/m3 Not applicable

Crystalline silica, quartz 14808-60-7 5 - 10% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May cause allergic skin and

respiratory reaction. May be harmful if swallowed. Oxidizer.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

OPTIFLO-II DELAYED RELEASE BREAKER

Page 1 of 7

HESI101214
4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 1

HMIS Ratings: Flammability 1, Reactivity 1, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

OPTIFLO-II DELAYED RELEASE BREAKER

Page 2 of 7

HESI101215
Storage Information Store away from reducing agents. Store away from combustibles. Store in a cool, dry

location. Use good housekeeping in storage and work areas to prevent accumulation

of dust. Close container when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron. Wear clothing appropriate for the work environment. Dusty clothing

should be laundered before reuse. Use precautionary measures to avoid creating

dust when removing or laundering clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Orange

Odor: Mild acrid

pH: 5

Specific Gravity @ 20 C (Water=1): 1.98

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 56.04

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 79

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 228.22

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with readily oxidizable materials.

Incompatibility (Materials to

Avoid)

Organic matter. All flammables, especially petroleum products, asphalt & other

volatile flammables. Amphoteric metals such as aluminum, magnesium, lead, tin, or

zinc. Strong acids. Avoid halogens.

OPTIFLO-II DELAYED RELEASE BREAKER

Page 3 of 7

HESI101216
Hazardous Decomposition

Products

Toxic fumes. Ammonia. Sulfuric acid. Amorphous silica may transform at elevated

temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

OPTIFLO-II DELAYED RELEASE BREAKER

Page 4 of 7

HESI101217
Oral Toxicity: LD50: 820 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Ammonium Persulfate, 5.1, UN1444, III

NAERG 140

Canadian TDG

Ammonium Persulfate, 5.1, UN1444, III

ADR

UN1444,Ammonium Persulfate, 5.1, III

Air Transportation

OPTIFLO-II DELAYED RELEASE BREAKER

Page 5 of 7

HESI101218
ICAO/IATA

UN1444,Ammonium Persulfate, 5.1, III

Sea Transportation

IMDG

UN1444,Ammonium Persulfate, 5.1, III

EmS F-A, S-Q

Other Shipping Information

Labels: Oxidizer

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class C Oxidizing Materials

D2B Toxic Materials

D2A Very Toxic Materials

Crystalline silica

OPTIFLO-II DELAYED RELEASE BREAKER

Page 6 of 7

HESI101219
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OPTIFLO-II DELAYED RELEASE BREAKER

Page 7 of 7

HESI101220
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: OXOL II CLEANER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: OXOL II CLEANER

Synonyms: None

Chemical Family: Not applicable

Application: Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium perborate

tetrahydrate

10486-00-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause skin and respiratory irritation. May cause eye burns. May be harmful if

swallowed. May be harmful if inhaled. Oxidizer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

OXOL II CLEANER

Page 1 of 6

HESI101221
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Releases oxygen at high

temperatures.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 1

HMIS Ratings: Health 2, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from combustibles. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 10

Specific Gravity @ 20 C (Water=1): 1.73

Density @ 20 C (lbs./gallon): Not Determined

OXOL II CLEANER

Page 2 of 6

HESI101222
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 43-54

Boiling Point/Range (F): 266

Boiling Point/Range (C): 130

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 6.2

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 153.86

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with organic materials.

Incompatibility (Materials to

Avoid)

Contact with water. Organic matter. All flammables, especially petroleum products,

asphalt & other volatile flammables. Metal salts such as aluminum chloride.

Hazardous Decomposition

Products

Oxygen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May be absorbed through inhalation contributing

to symptoms listed under ingestion.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue. May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions None known. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause gastrointestinal effects and muscular

dysfunction.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

OXOL II CLEANER

Page 3 of 6

HESI101223
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 160-320 mg/l (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

OXOL II CLEANER

Page 4 of 6

HESI101224
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

OXOL II CLEANER

Page 5 of 6

HESI101225
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

OXOL II CLEANER

Page 6 of 6

HESI101226
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PARACHEK 160 PARAFFIN INHIBITOR

Revision Date: 14-Oct-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PARACHEK 160 PARAFFIN INHIBITOR

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Paraffin Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 30 - 60% 5 mg/m3 5 mg/m3

Ethyl benzene 100-41-4 0 - 1% 100 ppm 100 ppm

Naphthalene 91-20-3 5 - 10% 10 ppm 10 ppm

Xylene 1330-20-7 1 - 5% 100 ppm 100 ppm

1,2,4 Trimethylbenzene 95-63-6 1 - 5% 25 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

PARACHEK 160 PARAFFIN INHIBITOR

Page 1 of 6

HESI101227
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 144

Flash Point/Range (C): 62

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Avoid spraying water directly into storage containers due to danger of boilover.

Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PARACHEK 160 PARAFFIN INHIBITOR

Page 2 of 6

HESI101228
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.50

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 268

Boiling Point/Range (C): 131

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 33.97

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

PARACHEK 160 PARAFFIN INHIBITOR

Page 3 of 6

HESI101229
Aggravated Medical Conditions Skin disorders. Central nervous system disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. This product contains

significant amounts of polynuclear aromatic hydrocarbons (PNA). Certain PNAs

have been shown to cause skin cancer in laboratory animals and may also cause

cancer of the lungs and other sites. Contains petroleum distillates which have been

shown to cause skin cancer in laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Napthalenes), 9, III, Marine Pollutant

NAERG 171

PARACHEK 160 PARAFFIN INHIBITOR

Page 4 of 6

HESI101230
DOT (Bulk)

Combustible Liquid, N.O.S. (Contains Naphthalene, 1,2,4-Trimethylbenzene)

Combustible Liquid, NA1993, III, RQ (185 Gallons)

Canadian TDG

Environmentally Hazardous Substance, Liquid, N.O.S.(Napthalenes), 9, UN3082, III, Marine Pollutant

ADR

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Napthalenes), 9, III, Marine Pollutant

Air Transportation

ICAO/IATA

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S., 9, III, Marine Pollutant

Sea Transportation

IMDG

UN3082,Environmentally Hazardous Substance, Liquid, N.O.S.(Napthalenes), III

, Marine Pollutant

EmS F-A, S-F

Other Shipping Information

Labels: Miscellaneous - Class 9

Marine Pollutant

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Xylene//1330-20-7

1,2,4-Trimethylbenzene//95-63-6

Naphthalene//91-20-3

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 444 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

PARACHEK 160 PARAFFIN INHIBITOR

Page 5 of 6

HESI101231
NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PARACHEK 160 PARAFFIN INHIBITOR

Page 6 of 6

HESI101232
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PARAGON 100 E+

Revision Date: 09-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PARAGON 100 E+

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 60 - 100% 5 mg/m3 5 mg/m3

Naphthalene 91-20-3 5 - 10% 10 ppm 10 ppm

1,2,4 Trimethylbenzene 95-63-6 1 - 5% 25 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. May cause lung damage if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

PARAGON 100 E+

Page 1 of 6

HESI101239
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 151

Flash Point/Range (C): 66

Flash Point Method: TCC

Autoignition Temperature (F): 1013

Autoignition Temperature (C): 545

Flammability Limits in Air - Lower (%): 0.8

Flammability Limits in Air - Upper (%): 5.9

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Avoid spraying water directly into storage containers due to danger of boilover.

Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1*, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another. Avoid breathing mist. Material is

slippery underfoot. Open container slowly to release pressure.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames. Product has a

shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

PARAGON 100 E+

Page 2 of 6

HESI101240
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Sweet aromatic

pH: 7

Specific Gravity @ 20 C (Water=1): 0..897

Density @ 20 C (lbs./gallon): 7.49

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 333

Boiling Point/Range (C): 167

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.56

Vapor Density (Air=1): 4.7

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): .99

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

PARAGON 100 E+

Page 3 of 6

HESI101241
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity

The International Agency for Research on Cancer (IARC) has evaluated naphthalene

and determined it to be a possible carcinogen to humans (Group 2B, based on

sufficient evidence in experimental animals and inadequate evidence in humans).

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 71% of COD

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM48: 12 mg/l (Acartia tonsa)

Acute Algae Toxicity: EC50: < 1 mg/l (Skeletonema costatum)

Chemical Fate Information Not determined

PARAGON 100 E+

Page 4 of 6

HESI101242
Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

PARAGON 100 E+

Page 5 of 6

HESI101243
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PARAGON 100 E+

Page 6 of 6

HESI101244
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PARAGON 1 SOLVENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PARAGON 1 SOLVENT

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Terpene hydrocarbon byproducts68956-56-9 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage.

PARAGON 1 SOLVENT

Page 1 of 6

HESI101233
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 117

Flash Point/Range (C): 47

Flash Point Method: CC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep from

excessive heat. Store in a cool, dry location. Store in a well ventilated area. Product

has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Organic vapor respirator with a dust/mist filter.

PARAGON 1 SOLVENT

Page 2 of 6

HESI101234
Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to light straw

Odor: Turpentine

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.85 - 0.87

Density @ 20 C (lbs./gallon): 7.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 315

Boiling Point/Range (C): Not DeterminedMin: > 157

Freezing Point/Range (F): 5

Freezing Point/Range (C): -15

Vapor Pressure @ 20 C (mmHg): .1

Vapor Density (Air=1): Not Determined

Percent Volatiles: 99

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Avoid contact with acids.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Excessive inhalation causes headache, dizziness, nausea and incoordination.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

PARAGON 1 SOLVENT

Page 3 of 6

HESI101235
Ingestion Irritation of the mouth, throat, and stomach. May cause headache, dizziness, nausea,

vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated excessive ingestion may cause central nervous system effects. Prolonged

or repeated exposure may cause liver, kidney and lung effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2319,Terpene Hydrocarbons, N.O.S., 3, III, (47.2 C)

NAERG 128

PARAGON 1 SOLVENT

Page 4 of 6

HESI101236
Canadian TDG

Terpene Hydrocarbons, N.O.S., 3, UN2319, III, (47.2 C)

ADR

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

Air Transportation

ICAO/IATA

UN2319,Terpene Hydrocarbons, N.O.S., 3, III

Sea Transportation

IMDG

UN2319,Terpene Hydrocarbons, N.O.S., 3, III, (47.2 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations

PARAGON 1 SOLVENT

Page 5 of 6

HESI101237
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PARAGON 1 SOLVENT

Page 6 of 6

HESI101238
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PARASPERSE CLEANER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PARASPERSE CLEANER

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Cleaner

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol monobutyl

ether

111-76-2 5 - 10% 20 ppm 50 ppm

Toluene 108-88-3 60 - 100% 20 ppm 200 ppm

Nonylphenol ethoxylate 5 - 10% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause skin and respiratory irritation. May cause eye burns. May be absorbed

through the skin. May cause headache, dizziness, and other central nervous system

effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

PARASPERSE CLEANER

Page 1 of 6

HESI101245
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 44

Flash Point/Range (C): 6

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 10.6

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Avoid spraying water directly into

storage containers due to danger of boilover. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

PARASPERSE CLEANER

Page 2 of 6

HESI101246
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Aromatic hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.89

Density @ 20 C (lbs./gallon): 7.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 237

Boiling Point/Range (C): 113

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 40

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 2.0

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. This material is an anesthetic. May cause central

nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause severe skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

PARASPERSE CLEANER

Page 3 of 6

HESI101247
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and blood effects.

Prolonged or repeated exposure may cause fetal damage and testicular effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

PARASPERSE CLEANER

Page 4 of 6

HESI101248
DOT

UN1294,Toluene Solution, 3, II, (6.67 C)

RQ (Toluene - 454 kg.)

NAERG 129

Canadian TDG

Toluene Solution, 3, UN1294, II, (6.67 C)

ADR

UN1294,Toluene Solution, 3, II

Air Transportation

ICAO/IATA

UN1294,Toluene Solution, 3, II

RQ (Toluene - 454 kg.)

Sea Transportation

IMDG

UN1294,Toluene Solution, 3, II, (6.67 C)

RQ (Toluene - 454 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Toluene//108-88-3

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 169 Gallons based on Toluene (CAS: 108-88-3).

PARASPERSE CLEANER

Page 5 of 6

HESI101249
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PARASPERSE CLEANER

Page 6 of 6

HESI101250
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PEN-5M

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PEN-5M

Synonyms: None

Chemical Family: Blend

Application: Cleaner

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PEN-5M

Page 1 of 6

HESI101251
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 77

Flash Point/Range (C): 25

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store between 40.5 F (4.7 C) and 120.5 F (49 C). Product

has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PEN-5M

Page 2 of 6

HESI101252
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless to Amber

Odor: Alcohol

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 0.96

Density @ 20 C (lbs./gallon): 8.01

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 176

Boiling Point/Range (C): 80

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 33

Vapor Density (Air=1): Not Determined

Percent Volatiles: 58-60

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause headache, dizziness, nausea, vomiting,

gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

PEN-5M

Page 3 of 6

HESI101253
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. May contain ethylene

oxide in the headspace of the drum. Ethylene oxide is a cancer and reproductive

hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1219,Isopropanol Solution, 3, II, (25 C)

NAERG 129

Canadian TDG

PEN-5M

Page 4 of 6

HESI101254
Isopropanol Solution, 3, UN1219, II, (25 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (25 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

PEN-5M

Page 5 of 6

HESI101255
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PEN-5M

Page 6 of 6

HESI101256
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PEN-88 HT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PEN-88 HT

Synonyms: None

Chemical Family: Blend

Application: Cleaner

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol monobutyl

ether

111-76-2 30 - 60% 20 ppm 50 ppm

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

PEN-88 HT

Page 1 of 6

HESI101257
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 175

Flash Point/Range (C): 79

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.5

Flammability Limits in Air - Upper (%): 10.6

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PEN-88 HT

Page 2 of 6

HESI101258
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Sweet

pH: 8

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.68

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 278

Boiling Point/Range (C): 136

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.8

Vapor Density (Air=1): Not Determined

Percent Volatiles: 88

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Amphoteric metals such as aluminum, magnesium,

lead, tin, or zinc.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Harmful if absorbed through the skin. May cause moderate skin irritation.

Eye Contact May cause eye burns. May cause corneal injury.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause liver and

kidney damage. May cause headache, dizziness, nausea, vomiting, gastrointestinal

irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

PEN-88 HT

Page 3 of 6

HESI101259
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and blood effects.

Prolonged or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1,200-4,000 mg/kg (Rat)

Dermal Toxicity: LD50: 1,500 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 350 ppm/5 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

PEN-88 HT

Page 4 of 6

HESI101260
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

PEN-88 HT

Page 5 of 6

HESI101261
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PEN-88 HT

Page 6 of 6

HESI101262
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PEN-88M

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PEN-88M

Synonyms: None

Chemical Family: Blend

Application: Cleaner

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 1 - 5% 100 mg/m3 50 ppm

Ethoxylated nonylphenol 5 - 10% Not applicable Not applicable

Ethylene glycol monobutyl

ether

111-76-2 30 - 60% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PEN-88M

Page 1 of 6

HESI101263
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 156

Flash Point/Range (C): 68

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Avoid breathing

vapors. Do NOT consume food, drink, or tobacco in contaminated areas.

Storage Information Store away from oxidizers. Store in a dry location. Store in a cool well ventilated

area. Keep from heat, sparks, and open flames. Keep container closed when not in

use. Product has a shelf life of 24 months. Store at temperatures between 50 and

100 F (10 and 37.8 C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

PEN-88M

Page 2 of 6

HESI101264
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White, opaque

Odor: Solvent

pH: 5-7

Specific Gravity @ 20 C (Water=1): 0.94

Density @ 20 C (lbs./gallon): 7.90

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 340

Boiling Point/Range (C): 171

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): > 0.76

Vapor Density (Air=1): Not Determined

Percent Volatiles: 57

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin defatting with prolonged exposure. Can dry skin.

Eye Contact May cause eye irritation.

Ingestion May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and

central nervous system depression. May cause liver and kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

PEN-88M

Page 3 of 6

HESI101265
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. May contain ethylene oxide in the

headspace of the drum. Ethylene oxide is a cancer and reproductive hazard.

Prolonged or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Ethylene Glycol Monobutyl Ether)

PEN-88M

Page 4 of 6

HESI101266
Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 62050 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

PEN-88M

Page 5 of 6

HESI101267
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PEN-88M

Page 6 of 6

HESI101268
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: POTASSIUM CHLORIDE SOLUTION (0-10%)

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: POTASSIUM CHLORIDE SOLUTION (0-10%)

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium chloride 7447-40-7 5 - 10% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

POTASSIUM CHLORIDE SOLUTION (0-10%)

Page 1 of 5

HESI101269
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.7

POTASSIUM CHLORIDE SOLUTION (0-10%)

Page 2 of 5

HESI101270
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

POTASSIUM CHLORIDE SOLUTION (0-10%)

Page 3 of 5

HESI101271
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

POTASSIUM CHLORIDE SOLUTION (0-10%)

Page 4 of 5

HESI101272
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

POTASSIUM CHLORIDE SOLUTION (0-10%)

Page 5 of 5

HESI101273
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI101274
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI101275
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI101276
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI101277
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

1/6

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® Black Plus, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: AcFrac® Black Plus, all sizes 

PRODUCT CODE: 306874GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

SOLD UNDER BORDEN U.S. PATENT NUMBERS 4,581,253; 

4,694,905 & 4,722,991 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

14808-60-7 *Quartz (SiO2) 70.0 - 100.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Charcoal, free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

HESI101278
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

2/6

3.2 Potential Health Effects

Immediate Hazards 

INGESTION: Not expected to be harmful under normal conditions of use. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

14808-60-7 Quartz (SiO2)

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an 

increased incidence of significant disease endpoints such as scleroderma (an immune system disorder 

manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also 

reported to increase the risk of tuberculosis. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

HESI101279
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

3/6

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

8.3 Exposure Guidelines 

14808-60-7 Quartz (SiO2) 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction; A2 - 

Suspected Human Carcinogen 

OSHA PEL 8-hr TWA 10/(%SiO2+

2) mg/m3 

respirable dust 

8-hr TWA 30/(%SiO2+

2) mg/m3 

total dust 

Remanded TWA 0.1 mg/m3 respirable dust; 1989 PEL 

remanded, but in effect in some 

HESI101280
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

4/6

states 

NIOSH 8-hr TWA 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

9. Physical and Chemical Properties 

Appearance Charcoal, free flowing granules 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity Approx. 2.53 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities: 

None known to company.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

14808-60-7 Quartz (SiO2) 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined. 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

HESI101281
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

5/6

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

HESI101282
Page 

AcFrac® Black Plus, all sizes Version: 1.1 Current Issue: 11/19/2003 Printed: 01/15/2004 

6/6

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101283
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI101284
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI101285
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI101286
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI101287
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

1/6

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® PR6000, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: AcFrac® PR6000, all sizes 

PRODUCT CODE: 306915GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

SOLD UNDER BORDEN U.S. PATENT NUMBERS 4,581,253 AND 

4,439,489 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

14808-60-7 *Quartz (SiO2) 70.0 - 100.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

HESI101288
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

2/6

3.2 Potential Health Effects

Immediate Hazards 

INGESTION: No hazards known to company. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

Quartz (SiO2) 14808-60-7

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased 

incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested 

by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also reported to 

increase the risk of tuberculosis. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

HESI101289
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

3/6

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

8.3 Exposure Guidelines 

Quartz (SiO2) 14808-60-7 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction; A2 - 

Suspected Human Carcinogen 

OSHA PEL 8-hr TWA 10/(%SiO2+

2) mg/m3 

respirable dust 

8-hr TWA 30/(%SiO2+

2) mg/m3 

total dust 

Remanded TWA 0.1 mg/m3 respirable dust; 1989 PEL 

remanded, but in effect in some 

HESI101290
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

4/6

states 

NIOSH 8-hr TWA 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

9. Physical and Chemical Properties 

Appearance Free flowing granules 

Color Tan 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity Approx. 2.53 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities: 

None known to company.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

Quartz (SiO2) 14808-60-7 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined 

13. Disposal Considerations 

HESI101291
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

5/6

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

HESI101292
Page 

AcFrac® PR6000, all sizes Version: 5 Printed: 01/15/2004 

6/6

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101293
MATERIAL SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® PR4000 12/20 PAGE 1 OF 8

1. Chemical Product and Company Identification

DESCRIPTION: AcFrac® PR4000 12/20

PRODUCT CODE: 74-9XF7.-.

PRODUCT TYPE: Oil/Gas Well Proppant

APPLICATION: Hydraulic Fracturing

Manufacturer/Supplier Information

MSDS Prepared by:

Borden Chemical, Inc. Emergency Phone Number

15730 Park Row Blvd, Suite 400 Poison Control Center

Houston, TX 77084 1-800-228-5635 ext 261

For additional health, safety or regulatory information, call 502-449-6222.

2. Composition, Information on Ingredients

The ingredients listed below have been associated with one or more

immediate and/or delayed(*) health hazards. Risk of damage and effects

depends upon duration and level of exposure. BEFORE USING, HANDLING, OR

EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.

% by weight

14808-60-7 *Quartz (SiO2) >70

3. Hazards Identification

3.1 Emergency Overview

Appearance Free flowing granules

Odor Odorless

CAUTION!

May cause irritation of nose, throat and lungs if allowed to become

airborne.

HMIS Rating

HEALTH = 1 (slight)

FLAMMABILITY = 0 (minimal)

REACTIVITY = 0 (minimal)

CHRONIC = *

067 74-9XF7.-. READ NEXT PAGE

HESI101294
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 2 OF 8

3.2 Potential Health Effects

Immediate Hazards

INGESTION: No hazards known to company.

INHALATION: If allowed to become airborne, may cause irritation of

nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Note: Product has potential to release formaldehyde vapor during

core/mold making and from decomposition during metal pouring. The

amount and level will depend on local conditions of use. Formaldehyde

gas is irritating to the eyes and upper respiratory tract and may

aggravate existing respiratory conditions or allergies. OSHA has

listed formaldehyde as a potential human carcinogen. See the OSHA

formaldehyde standard 29 CFR 1910.1048 for further details.

Product contains traces of hexamethylenetetramine which may cause

allergic skin and respiratory reactions.

Delayed Hazards

Quartz (SiO2) 14808-60-7

CANCER HAZARD. Can cause cancer. Use of this product may

generate silica dust (which may be invisible). Inhaled silica has

been classified by IARC as a human carcinogen.

Inhalation of silica dust may cause delayed lung injury or lung

fibrosis (including silicosis and/or pneumoconiosis) and/or other

diseases which may lead to permanent disability and/or death.

Silicosis is a form of disabling pulmonary fibrosis which can be

progressive. Prolonged exposure to respirable silica may cause

diminished lung capacity with shortness of breath during physical

exertion and may cause fatigue, breathlessness, wheezing, cough, and

sputum production. Pre-existing respiratory disorders may be

aggravated by exposure. Smoking may aggravate the effects of

exposure and may increase the risk of developing respiratory disease

from exposure. Consult with your employer and your doctor for

further information or if you believe you may be developing any

breathing or lung problems.

There is some evidence that breathing respirable crystalline silica

or the disease silicosis is associated with an increased incidence of

significant disease endpoints such as scleroderma (an immune system

disorder manifested by fibrosis of the lungs, skin and other internal

organs) and kidney disease. Silicosis is also reported to increase

067 74-9XF7.-. READ NEXT PAGE

HESI101295
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 3 OF 8

Delayed Hazards

the risk of tuberculosis.

4. First Aid Measures

INGESTION: If accidentally swallowed, dilute by drinking large

quantities of water. Immediately contact poison control

center or hospital emergency room for any other

additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call

a physician if irritation persists.

5. Fire Fighting Measures

Flash point Non-Flammable

Lower explosion limit Not applicable

Upper explosion limit Not applicable

Autoignition temperature Not applicable

Will not burn.

In case of fire, water should be used to keep fire-exposed

containers cool.

6. Accidental Release Measures

Minimize the creation and distribution of dust. Remove to a

chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage

7.1 Handling

Handle in accordance with good industrial hygiene and safety

practices. These practices include avoiding unnecessary exposure and

removal of the material from eyes, skin and clothing.

Wash thoroughly after handling. Always use appropriate Personal

Protective Equipment (PPE).

Minimize the creation and distribution of dust.

INHALATION: Avoid prolonged or repeated breathing of dust or

vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

067 74-9XF7.-. READ NEXT PAGE

HESI101296
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 4 OF 8

7.2 Storage

Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80 F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection

8.1 Exposure Controls

Avoid creating dust. If airborne contaminants are generated when the

material is heated, handled, or transported, appropriate

administrative and engineering controls, including sufficient

ventilation in volume and air flow patterns, should be provided to

keep air contaminant concentration levels below acceptable criteria.

Minimize the collection (build-up) of dust on walls, floors, sills,

ledges, machinery, or equipment. Work clothes should be changed

daily and washed to prevent dust contact. These techniques may not

necessarily address all issues pertaining to your operation. We,

therefore, recommend that you consult with experts of your choice to

determine whether or not your programs are adequate.

Consult OSHA, state/provincial and local laws, and regulations.

Review ASTM E 1132-99, "Standard Practice for Health Requirements

Relating to Occupational Exposure to Respirable Crystalline Silica,"

as well as other guidelines such as NIOSH publications.

8.2 Personal Protection

Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA

approved respiratory protection equipment. Respirators should be

selected based on the form and concentration of contaminants in air

in accordance with OSHA laws and regulations or other applicable

standards or guidelines, including ANSI standards regarding

respiratory protection. Wear impervious gloves as required to prevent

skin contact. Wear safety glasses with sideshields at all times to

prevent eye irritation.

8.3 Exposure Guidelines

Quartz (SiO2) 14808-60-7

ACGIH TLV: 0.05 mg/m3 TWA, respirable fraction, A2 - See Appendix A

OSHA PEL: 10/(%SiO2 + 2) mg/m3 TWA, respirable dust;

30/(%SiO2 + 2) mg/m3 TWA, total dust

REMANDED PEL: 0.1 mg/m3 TWA, respirable dust

OSHA 1989 PEL remanded, but in effect in some states

OTHER: NIOSH has recommended a permissible exposure limit of 50 micrograms

respirable free silica per cubic meter of air (0.05 mg/m3) averaged

over a workshift of up to 10 hours per day, 40 hours per week. NIOSH

067 74-9XF7.-. READ NEXT PAGE

HESI101297
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 5 OF 8

8.3 Exposure Guidelines

publications, including the NIOSH Criteria Document for Crystalline

Silica, should be consulted for more detailed information.

9. Physical and Chemical Properties

Appearance Free flowing granules

Color Tan

Odor Odorless

Odor threshold Not applicable

Specific gravity Approximately 2.53

pH Not applicable

Viscosity, Brookfield Not applicable

Freezing point Not applicable

Solubility in water Very slightly soluble

Octanol/water partition coefficient Not available

Vapor pressure @ 25 C Not applicable

Vapor density (air=1) Not applicable

Evaporation rate (butyl acetate=1) Not applicable

Boiling point, 760 mm Hg Not applicable

10. Stability and Reactivity

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities:

None known to company.

Decomposition products may include:

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen

cyanide, ammonia, particulate matter and other organic compounds

including benzo[a]pyrene.

Hazardous polymerization:

Will not occur.

Other Hazards:

None known to company.

11. Toxicological Information

See Section 3 Hazards Identification information.

Quartz (SiO2) 14808-60-7

LC50: Not available

LD50: Not available

067 74-9XF7.-. READ NEXT PAGE

HESI101298
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 6 OF 8

12. Ecological Information

Not determined.

13. Disposal Considerations

Dispose of according to local, state/provincial, and federal

requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not

be specific to your package size. You will need to apply the

appropriate regulations to properly classify your shipment for

transportation.

Non-Regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Finished Goods

Non-regulated

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazard Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when

reviewed according to the requirements of the Occupational Safety and

Health Administration 29 CFR Part 1910.1200 "Hazard Communication"

Standard.

SARA Title III: Section 311/312

Delayed health hazard

SARA Title III Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the

reporting requirements of Section 313 of Title III of the Superfund

Amendments and Reauthorization Act of 1986, and Subpart C-Supplier

Notification Requirement of 40 CFR Part 372.

None required per SARA TITLE III SECTION 313.

067 74-9XF7.-. READ NEXT PAGE

HESI101299
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 7 OF 8

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory.

We rely on certifications of compliance from our suppliers for

chemical substances not manufactured by us.

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard

criteria of the Controlled Products Regulation (CPR) and the MSDS

contains all the information required by the CPR.

CLASS D, DIV 2A, 2B

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic

Substances List (DSL) or otherwise comply with CEPA new substance

notification requirements.

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the

reporting requirements of the Canadian Environmental Protection Act

(CEPA) subsection 16(1), National Pollutant Release Inventory.

None required.

16. Other Information

User’s Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace

Hazardous Materials Information System (WHMIS) require that the information

contained on these sheets be made available to your workers. Educate and

train your workers regarding OSHA and WHMIS precautions. Instruct your

workers to handle this product properly. Consult with appropriate experts

to guard against hazards associated with use of this product and its

ingredients.

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE

MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product

shall conform to contracted specifications, and that the product does not

infringe any valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the quantity of

product in respect of which damages are claimed. In no event shall Seller

be liable for incidental or consequential damages, whether Buyer’s claim is

067 74-9XF7.-. READ NEXT PAGE

HESI101300
DESCRIPTION: AcFrac® PR4000 12/20 PAGE 8 OF 8

Disclaimer

based on contract, breach of warranty, negligence or otherwise.

CUR ISSUE 05-MAR-02

PREVIOUS ISSUE: 18-SEP-01

067 74-9XF7.-. THIS IS THE LAST PAGE

PRINT DATE: May 28, 2002 02:46 AM

HESI101301
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI101302
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI101303
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI101304
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI101305
MATERIAL SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® PR4000 16/30 PAGE 1 OF 8

1. Chemical Product and Company Identification

DESCRIPTION: AcFrac® PR4000 16/30

PRODUCT CODE: 74-9XF1.-.

PRODUCT TYPE: Oil/Gas Well Proppant

APPLICATION: Hydraulic Fracturing

Manufacturer/Supplier Information

MSDS Prepared by:

Borden Chemical, Inc. Emergency Phone Number

15730 Park Row Blvd, Suite 400 Poison Control Center

Houston, TX 77084 1-800-228-5635 ext 261

For additional health, safety or regulatory information, call 502-449-6222.

2. Composition, Information on Ingredients

The ingredients listed below have been associated with one or more

immediate and/or delayed(*) health hazards. Risk of damage and effects

depends upon duration and level of exposure. BEFORE USING, HANDLING, OR

EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.

% by weight

14808-60-7 *Quartz (SiO2) >70

3. Hazards Identification

3.1 Emergency Overview

Appearance Free flowing granules

Odor Odorless

CAUTION!

May cause irritation of nose, throat and lungs if allowed to become

airborne.

HMIS Rating

HEALTH = 1 (slight)

FLAMMABILITY = 0 (minimal)

REACTIVITY = 0 (minimal)

CHRONIC = *

067 74-9XF1.-. READ NEXT PAGE

HESI101306
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 2 OF 8

3.2 Potential Health Effects

Immediate Hazards

INGESTION: No hazards known to company.

INHALATION: If allowed to become airborne, may cause irritation of

nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Note: Product has potential to release formaldehyde vapor during

core/mold making and from decomposition during metal pouring. The

amount and level will depend on local conditions of use. Formaldehyde

gas is irritating to the eyes and upper respiratory tract and may

aggravate existing respiratory conditions or allergies. OSHA has

listed formaldehyde as a potential human carcinogen. See the OSHA

formaldehyde standard 29 CFR 1910.1048 for further details.

Product contains traces of hexamethylenetetramine which may cause

allergic skin and respiratory reactions.

Delayed Hazards

Quartz (SiO2) 14808-60-7

CANCER HAZARD. Can cause cancer. Use of this product may

generate silica dust (which may be invisible). Inhaled silica has

been classified by IARC as a human carcinogen.

Inhalation of silica dust may cause delayed lung injury or lung

fibrosis (including silicosis and/or pneumoconiosis) and/or other

diseases which may lead to permanent disability and/or death.

Silicosis is a form of disabling pulmonary fibrosis which can be

progressive. Prolonged exposure to respirable silica may cause

diminished lung capacity with shortness of breath during physical

exertion and may cause fatigue, breathlessness, wheezing, cough, and

sputum production. Pre-existing respiratory disorders may be

aggravated by exposure. Smoking may aggravate the effects of

exposure and may increase the risk of developing respiratory disease

from exposure. Consult with your employer and your doctor for

further information or if you believe you may be developing any

breathing or lung problems.

There is some evidence that breathing respirable crystalline silica

or the disease silicosis is associated with an increased incidence of

significant disease endpoints such as scleroderma (an immune system

disorder manifested by fibrosis of the lungs, skin and other internal

organs) and kidney disease. Silicosis is also reported to increase

067 74-9XF1.-. READ NEXT PAGE

HESI101307
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 3 OF 8

Delayed Hazards

the risk of tuberculosis.

4. First Aid Measures

INGESTION: If accidentally swallowed, dilute by drinking large

quantities of water. Immediately contact poison control

center or hospital emergency room for any other

additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call

a physician if irritation persists.

5. Fire Fighting Measures

Flash point Non-Flammable

Lower explosion limit Not applicable

Upper explosion limit Not applicable

Autoignition temperature Not applicable

Will not burn.

In case of fire, water should be used to keep fire-exposed

containers cool.

6. Accidental Release Measures

Minimize the creation and distribution of dust. Remove to a

chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage

7.1 Handling

Handle in accordance with good industrial hygiene and safety

practices. These practices include avoiding unnecessary exposure and

removal of the material from eyes, skin and clothing.

Wash thoroughly after handling. Always use appropriate Personal

Protective Equipment (PPE).

Minimize the creation and distribution of dust.

INHALATION: Avoid prolonged or repeated breathing of dust or

vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

067 74-9XF1.-. READ NEXT PAGE

HESI101308
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 4 OF 8

7.2 Storage

Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80 F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection

8.1 Exposure Controls

Avoid creating dust. If airborne contaminants are generated when the

material is heated, handled, or transported, appropriate

administrative and engineering controls, including sufficient

ventilation in volume and air flow patterns, should be provided to

keep air contaminant concentration levels below acceptable criteria.

Minimize the collection (build-up) of dust on walls, floors, sills,

ledges, machinery, or equipment. Work clothes should be changed

daily and washed to prevent dust contact. These techniques may not

necessarily address all issues pertaining to your operation. We,

therefore, recommend that you consult with experts of your choice to

determine whether or not your programs are adequate.

Consult OSHA, state/provincial and local laws, and regulations.

Review ASTM E 1132-99, "Standard Practice for Health Requirements

Relating to Occupational Exposure to Respirable Crystalline Silica,"

as well as other guidelines such as NIOSH publications.

8.2 Personal Protection

Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA

approved respiratory protection equipment. Respirators should be

selected based on the form and concentration of contaminants in air

in accordance with OSHA laws and regulations or other applicable

standards or guidelines, including ANSI standards regarding

respiratory protection. Wear impervious gloves as required to prevent

skin contact. Wear safety glasses with sideshields at all times to

prevent eye irritation.

8.3 Exposure Guidelines

Quartz (SiO2) 14808-60-7

ACGIH TLV: 0.05 mg/m3 TWA, respirable fraction, A2 - See Appendix A

OSHA PEL: 10/(%SiO2 + 2) mg/m3 TWA, respirable dust;

30/(%SiO2 + 2) mg/m3 TWA, total dust

REMANDED PEL: 0.1 mg/m3 TWA, respirable dust

OSHA 1989 PEL remanded, but in effect in some states

OTHER: NIOSH has recommended a permissible exposure limit of 50 micrograms

respirable free silica per cubic meter of air (0.05 mg/m3) averaged

over a workshift of up to 10 hours per day, 40 hours per week. NIOSH

067 74-9XF1.-. READ NEXT PAGE

HESI101309
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 5 OF 8

8.3 Exposure Guidelines

publications, including the NIOSH Criteria Document for Crystalline

Silica, should be consulted for more detailed information.

9. Physical and Chemical Properties

Appearance Free flowing granules

Color Tan

Odor Odorless

Odor threshold Not applicable

Specific gravity Approximately 2.53

pH Not applicable

Viscosity, Brookfield Not applicable

Freezing point Not applicable

Solubility in water Very slightly soluble

Octanol/water partition coefficient Not available

Vapor pressure @ 25 C Not applicable

Vapor density (air=1) Not applicable

Evaporation rate (butyl acetate=1) Not applicable

Boiling point, 760 mm Hg Not applicable

10. Stability and Reactivity

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities:

None known to company.

Decomposition products may include:

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen

cyanide, ammonia, particulate matter and other organic compounds

including benzo[a]pyrene.

Hazardous polymerization:

Will not occur.

Other Hazards:

None known to company.

11. Toxicological Information

See Section 3 Hazards Identification information.

Quartz (SiO2) 14808-60-7

LC50: Not available

LD50: Not available

067 74-9XF1.-. READ NEXT PAGE

HESI101310
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 6 OF 8

12. Ecological Information

Not determined.

13. Disposal Considerations

Dispose of according to local, state/provincial, and federal

requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not

be specific to your package size. You will need to apply the

appropriate regulations to properly classify your shipment for

transportation.

Non-Regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Finished Goods

Non-regulated

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazard Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when

reviewed according to the requirements of the Occupational Safety and

Health Administration 29 CFR Part 1910.1200 "Hazard Communication"

Standard.

SARA Title III: Section 311/312

Delayed health hazard

SARA Title III Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the

reporting requirements of Section 313 of Title III of the Superfund

Amendments and Reauthorization Act of 1986, and Subpart C-Supplier

Notification Requirement of 40 CFR Part 372.

None required per SARA TITLE III SECTION 313.

067 74-9XF1.-. READ NEXT PAGE

HESI101311
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 7 OF 8

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory.

We rely on certifications of compliance from our suppliers for

chemical substances not manufactured by us.

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard

criteria of the Controlled Products Regulation (CPR) and the MSDS

contains all the information required by the CPR.

CLASS D, DIV 2A, 2B

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic

Substances List (DSL) or otherwise comply with CEPA new substance

notification requirements.

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the

reporting requirements of the Canadian Environmental Protection Act

(CEPA) subsection 16(1), National Pollutant Release Inventory.

None required.

16. Other Information

User’s Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace

Hazardous Materials Information System (WHMIS) require that the information

contained on these sheets be made available to your workers. Educate and

train your workers regarding OSHA and WHMIS precautions. Instruct your

workers to handle this product properly. Consult with appropriate experts

to guard against hazards associated with use of this product and its

ingredients.

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE

MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product

shall conform to contracted specifications, and that the product does not

infringe any valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the quantity of

product in respect of which damages are claimed. In no event shall Seller

be liable for incidental or consequential damages, whether Buyer’s claim is

067 74-9XF1.-. READ NEXT PAGE

HESI101312
DESCRIPTION: AcFrac® PR4000 16/30 PAGE 8 OF 8

Disclaimer

based on contract, breach of warranty, negligence or otherwise.

CUR ISSUE 05-MAR-02

PREVIOUS ISSUE: 18-SEP-01

067 74-9XF1.-. THIS IS THE LAST PAGE

PRINT DATE: May 28, 2002 02:45 AM

HESI101313
MATERIAL SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® PR4000 20/40 PAGE 1 OF 8

1. Chemical Product and Company Identification

DESCRIPTION: AcFrac® PR4000 20/40

PRODUCT CODE: 74-9XF0.-.

PRODUCT TYPE: Oil/Gas Well Proppant

APPLICATION: Hydraulic Fracturing

Manufacturer/Supplier Information

MSDS Prepared by:

Borden Chemical, Inc. Emergency Phone Number

15730 Park Row Blvd, Suite 400 Poison Control Center

Houston, TX 77084 1-800-228-5635 ext 261

For additional health, safety or regulatory information, call 502-449-6222.

2. Composition, Information on Ingredients

The ingredients listed below have been associated with one or more

immediate and/or delayed(*) health hazards. Risk of damage and effects

depends upon duration and level of exposure. BEFORE USING, HANDLING, OR

EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.

% by weight

14808-60-7 *Quartz (SiO2) >70

3. Hazards Identification

3.1 Emergency Overview

Appearance Free flowing granules

Odor Odorless

CAUTION!

May cause irritation of nose, throat and lungs if allowed to become

airborne.

HMIS Rating

HEALTH = 1 (slight)

FLAMMABILITY = 0 (minimal)

REACTIVITY = 0 (minimal)

CHRONIC = *

067 74-9XF0.-. READ NEXT PAGE

HESI101314
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 2 OF 8

3.2 Potential Health Effects

Immediate Hazards

INGESTION: No hazards known to company.

INHALATION: If allowed to become airborne, may cause irritation of

nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Note: Product has potential to release formaldehyde vapor during

core/mold making and from decomposition during metal pouring. The

amount and level will depend on local conditions of use. Formaldehyde

gas is irritating to the eyes and upper respiratory tract and may

aggravate existing respiratory conditions or allergies. OSHA has

listed formaldehyde as a potential human carcinogen. See the OSHA

formaldehyde standard 29 CFR 1910.1048 for further details.

Product contains traces of hexamethylenetetramine which may cause

allergic skin and respiratory reactions.

Delayed Hazards

Quartz (SiO2) 14808-60-7

CANCER HAZARD. Can cause cancer. Use of this product may

generate silica dust (which may be invisible). Inhaled silica has

been classified by IARC as a human carcinogen.

Inhalation of silica dust may cause delayed lung injury or lung

fibrosis (including silicosis and/or pneumoconiosis) and/or other

diseases which may lead to permanent disability and/or death.

Silicosis is a form of disabling pulmonary fibrosis which can be

progressive. Prolonged exposure to respirable silica may cause

diminished lung capacity with shortness of breath during physical

exertion and may cause fatigue, breathlessness, wheezing, cough, and

sputum production. Pre-existing respiratory disorders may be

aggravated by exposure. Smoking may aggravate the effects of

exposure and may increase the risk of developing respiratory disease

from exposure. Consult with your employer and your doctor for

further information or if you believe you may be developing any

breathing or lung problems.

There is some evidence that breathing respirable crystalline silica

or the disease silicosis is associated with an increased incidence of

significant disease endpoints such as scleroderma (an immune system

disorder manifested by fibrosis of the lungs, skin and other internal

organs) and kidney disease. Silicosis is also reported to increase

067 74-9XF0.-. READ NEXT PAGE

HESI101315
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 3 OF 8

Delayed Hazards

the risk of tuberculosis.

4. First Aid Measures

INGESTION: If accidentally swallowed, dilute by drinking large

quantities of water. Immediately contact poison control

center or hospital emergency room for any other

additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call

a physician if irritation persists.

5. Fire Fighting Measures

Flash point Non-Flammable

Lower explosion limit Not applicable

Upper explosion limit Not applicable

Autoignition temperature Not applicable

Will not burn.

In case of fire, water should be used to keep fire-exposed

containers cool.

6. Accidental Release Measures

Minimize the creation and distribution of dust. Remove to a

chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage

7.1 Handling

Handle in accordance with good industrial hygiene and safety

practices. These practices include avoiding unnecessary exposure and

removal of the material from eyes, skin and clothing.

Wash thoroughly after handling. Always use appropriate Personal

Protective Equipment (PPE).

Minimize the creation and distribution of dust.

INHALATION: Avoid prolonged or repeated breathing of dust or

vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

067 74-9XF0.-. READ NEXT PAGE

HESI101316
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 4 OF 8

7.2 Storage

Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80 F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection

8.1 Exposure Controls

Avoid creating dust. If airborne contaminants are generated when the

material is heated, handled, or transported, appropriate

administrative and engineering controls, including sufficient

ventilation in volume and air flow patterns, should be provided to

keep air contaminant concentration levels below acceptable criteria.

Minimize the collection (build-up) of dust on walls, floors, sills,

ledges, machinery, or equipment. Work clothes should be changed

daily and washed to prevent dust contact. These techniques may not

necessarily address all issues pertaining to your operation. We,

therefore, recommend that you consult with experts of your choice to

determine whether or not your programs are adequate.

Consult OSHA, state/provincial and local laws, and regulations.

Review ASTM E 1132-99, "Standard Practice for Health Requirements

Relating to Occupational Exposure to Respirable Crystalline Silica,"

as well as other guidelines such as NIOSH publications.

8.2 Personal Protection

Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA

approved respiratory protection equipment. Respirators should be

selected based on the form and concentration of contaminants in air

in accordance with OSHA laws and regulations or other applicable

standards or guidelines, including ANSI standards regarding

respiratory protection. Wear impervious gloves as required to prevent

skin contact. Wear safety glasses with sideshields at all times to

prevent eye irritation.

8.3 Exposure Guidelines

Quartz (SiO2) 14808-60-7

ACGIH TLV: 0.05 mg/m3 TWA, respirable fraction, A2 - See Appendix A

OSHA PEL: 10/(%SiO2 + 2) mg/m3 TWA, respirable dust;

30/(%SiO2 + 2) mg/m3 TWA, total dust

REMANDED PEL: 0.1 mg/m3 TWA, respirable dust

OSHA 1989 PEL remanded, but in effect in some states

OTHER: NIOSH has recommended a permissible exposure limit of 50 micrograms

respirable free silica per cubic meter of air (0.05 mg/m3) averaged

over a workshift of up to 10 hours per day, 40 hours per week. NIOSH

067 74-9XF0.-. READ NEXT PAGE

HESI101317
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 5 OF 8

8.3 Exposure Guidelines

publications, including the NIOSH Criteria Document for Crystalline

Silica, should be consulted for more detailed information.

9. Physical and Chemical Properties

Appearance Free flowing granules

Color Tan

Odor Odorless

Odor threshold Not applicable

Specific gravity Approximately 2.53

pH Not applicable

Viscosity, Brookfield Not applicable

Freezing point Not applicable

Solubility in water Very slightly soluble

Octanol/water partition coefficient Not available

Vapor pressure @ 25 C Not applicable

Vapor density (air=1) Not applicable

Evaporation rate (butyl acetate=1) Not applicable

Boiling point, 760 mm Hg Not applicable

10. Stability and Reactivity

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities:

None known to company.

Decomposition products may include:

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen

cyanide, ammonia, particulate matter and other organic compounds

including benzo[a]pyrene.

Hazardous polymerization:

Will not occur.

Other Hazards:

None known to company.

11. Toxicological Information

See Section 3 Hazards Identification information.

Quartz (SiO2) 14808-60-7

LC50: Not available

LD50: Not available

067 74-9XF0.-. READ NEXT PAGE

HESI101318
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 6 OF 8

12. Ecological Information

Not determined.

13. Disposal Considerations

Dispose of according to local, state/provincial, and federal

requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not

be specific to your package size. You will need to apply the

appropriate regulations to properly classify your shipment for

transportation.

Non-Regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Finished Goods

Non-regulated

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazard Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when

reviewed according to the requirements of the Occupational Safety and

Health Administration 29 CFR Part 1910.1200 "Hazard Communication"

Standard.

SARA Title III: Section 311/312

Delayed health hazard

SARA Title III Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the

reporting requirements of Section 313 of Title III of the Superfund

Amendments and Reauthorization Act of 1986, and Subpart C-Supplier

Notification Requirement of 40 CFR Part 372.

None required per SARA TITLE III SECTION 313.

067 74-9XF0.-. READ NEXT PAGE

HESI101319
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 7 OF 8

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory.

We rely on certifications of compliance from our suppliers for

chemical substances not manufactured by us.

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard

criteria of the Controlled Products Regulation (CPR) and the MSDS

contains all the information required by the CPR.

CLASS D, DIV 2A, 2B

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic

Substances List (DSL) or otherwise comply with CEPA new substance

notification requirements.

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the

reporting requirements of the Canadian Environmental Protection Act

(CEPA) subsection 16(1), National Pollutant Release Inventory.

None required.

16. Other Information

User’s Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace

Hazardous Materials Information System (WHMIS) require that the information

contained on these sheets be made available to your workers. Educate and

train your workers regarding OSHA and WHMIS precautions. Instruct your

workers to handle this product properly. Consult with appropriate experts

to guard against hazards associated with use of this product and its

ingredients.

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE

MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product

shall conform to contracted specifications, and that the product does not

infringe any valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the quantity of

product in respect of which damages are claimed. In no event shall Seller

be liable for incidental or consequential damages, whether Buyer’s claim is

067 74-9XF0.-. READ NEXT PAGE

HESI101320
DESCRIPTION: AcFrac® PR4000 20/40 PAGE 8 OF 8

Disclaimer

based on contract, breach of warranty, negligence or otherwise.

CUR ISSUE 05-MAR-02

PREVIOUS ISSUE: 18-SEP-01

067 74-9XF0.-. THIS IS THE LAST PAGE

PRINT DATE: May 28, 2002 02:45 AM

HESI101321
MATERIAL SAFETY DATA SHEET HAZARD RATING

4=EXTREME 0 fire

3=HIGH 1 health

4810 INDUSTRIAL DRIVE 2=MODERATE 0 reactivity MSDS NO.: 04

1=SLIGHT special NEW IBERIA, LOUISIANA 70560 protection

PHONE: (337) 367-6151 0=MINIMAL SEE SECTION IX

REVISION DATE: 11/07/01

EMERGENCY TELEPHONE NUMBER: (337) 367-3159 PAGE 1 OF 2

SECTION I: PRODUCT INFORMATION

TRADE NAME: CARBOHSP (All Mesh Sizes)

SYNONYM(S): Ceramic Proppant; Semi-Crystalline Alumina Silicate

CHEMICAL FAMILY: Aluminosilicate

SECTION II: COMPONENT INFORMATION

INGREDIENTS CAS NUMBER % WEIGHT OSHA PEL-TWA ACGIH-TWA TLV

Corundum 1302-74-5 74-76% 15 mg/m3 (total) 10 mg/m3 (total)

5 mg/m3 (resp) 3 mg/m3 (resp)

Mullite 1302-93-8 22-28% 15 mg/m3 (total) 10 mg/m3 (total)

5 mg/m3 (resp) 3 mg/m3 (resp)

SECTION III: PHYSICAL DATA (PUBLISHED OR ESTIMATED VALUES)

BOILING POINT: N/A °F SPECIFIC GRAVITY: 3.57 (H2O=1) pH: N/A

MELTING POINT: 4000 °F BULK DENSITY:: 124 lb/cu.ft

VAPOR PRESSURE: N/A mm Hg % VOLATILE BY WEIGHT: N/A

VAPOR DENSITY: N/A (Air=1) EVAPORATION RATE: N/A (Butyl

Acetate=1)

APPEARANCE/ODOR: Odorless dark-green to grey pellets SOLUBILITY IN WATER: Insoluble

VOLATILE ORGANIC COMPOUNDS (VOC): 0 lbs/gal (EPA Reference Methods 24)

SECTION IV: FIRE AND EXPLOSION HAZARD DATA

ESTIMATED EXPLOSIVE LIMITS (% By volume in air): LEL: N/A UEL: N/A FLASH POINT: N/A

SPECIAL FIRE FIGHTING PROCEDURES: This material does not give a flash point by conventional test methods. Use

extinguishing agent suitable for type of surrounding fire.

UNUSUAL HAZARDS: N/A

SECTION V: HEALTH HAZARD DATA

INHALATION: Product contains little or no particles of respirable size. However, the amount of fines may increase due to attrition

during shipment, use and handling. Dusts may cause respiratory tract irritation. Repeated or prolonged breathing of particles of

respirable size may cause severe respiratory disease.

SECTION VI: REACTIVITY DATA

STABILITY: Stable: X Unstable Conditions to Avoid: N/A

HAZARDOUS POLYMERIZATION: Will Occur: Will Not

Occur:

X Conditions to Avoid: N/A

INCOMPATIBLE MATERIALS: Chlorine Trifluoride

HAZARDOUS DECOMPOSITION PRODUCTS: N/A

SECTION VII: EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Remove affected person from source of exposure. Get medical attention if irritation persists.

INGESTION: No treatment is necessary unless large quantities are ingested. Seek medical advice if large quantities are

ingested.

EYE CONTACT: Immediately flush eyes with large amounts of water. Get medical attention if irritation persists.

SKIN CONTACT: Wash the affected area with soap and water. Get medical attention if irritation persists.

HESI101322
HAZARD RATING

4=EXTREME 0 fire

3=HIGH 1 health

4810 INDUSTRIAL DRIVE 2=MODERATE 0 reactivity MSDS NO.: 04

1=SLIGHT special NEW IBERIA, LOUISIANA 70560 protection

PHONE: (337) 367-6151 0=MINIMAL SEE SECTION IX

REVISION DATE: 11/07/01

EMERGENCY TELEPHONE NUMBER: (337) 367-3159 PAGE 2 OF 2

SECTION VIII: SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No Special procedures are required for clean-up of spills

or leaks of this material. Avoid methods that result in water pollution. Caution should be exercised regarding personal safety and

exposure to the spilled material, the material’s nature could cause reduced traction. Persons should take care so as not to slip.

WASTE DISPOSAL: Disposal must be at an approved waste disposal facility and in accordance with applicable Federal, State and

Local laws and regulations. Contact the district Director of the Environmental Protection Agency and/or state regulatory agency for

appropriate requirements.

SECTION IX: SPECIAL PROTECTION

RESPIRATORY: A NIOSH/MSHA approved respirator should be worn where airborne exposures may exceed

OSHA/ACGIH permissible air concentrations.

EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact lenses

when working with this substance. 

CLOTHING/GLOVES: Gloves are optional to reduce abrasion.

WORK HYGIENE PRACTICES: Handle in accordance with good personal hygiene and safety practices.

VENTILATION: Provide sufficient (general and/or local exhaust) ventilation to maintain exposure below

permissible air concentrations.

SECTION X: SPECIAL PRECAUTIONS

HANDLING/STORAGE: N/A

SECTION XI: ADDITIONAL/REGULATORY INFORMATION

TOXIC SUBSTANCE CONTROL ACT (TSCA) STATUS: All chemicals in this

product are listed, automatically included, or are exempt from listing on

the TSCA Inventory.

SARA TITLE III: Section 302:

Section 312:

Section 313:

None

None

None

CERCLA REPORTABLE QUANTITY: None

CLEAN AIR AMENDMENTS-HAZARDOUS AIR POLLUTANTS (HAPS): None

CALIFORNIA STATE PROPOSITION 65: N/A

MATERIAL SAFETY DATA SHEET

HESI101323
Sintered Bauxite

Material Safety Data Sheet

Norton Proppants, Inc.

11300 North Central Expressway, Suite 402

Dallas, Texas 75243

(214) 233-0661

Fax (214) 233-1409

For Marketing and Technical

5300 Gerber Road Information Contact:

Fort Smith, Arkansas 72904

(501) 782-2001

Fax (501) 782-9984

Proppant Mfg. Facility:

Fort Smith, Arkansas 

Alice, Texas

Fairbanks, Alaska

Red Deer, Alberta, Canada

Rock Springs, Wyoming

Inventory Locations:

1. Chemical Name and Company Identification

1.0 Product Name : Sintered Bauxite (all mesh sizes)

Synonym(s) Ceramic Proppant

Chemical Family: Aluminosilicate

Manufacturer: NORTON PROPPANTS

5300 GERBER ROAD

FORT SMITH, ARKANSAS 72904

24-HOUR EMERGENCY (501)782-2001

2. Component Information 

2.0 Chemical Name Common Name % By Weight (Typical)

Aluminum Silicate Mullite 15-35

Aluminum Oxide Corundum 65-85

3. Hazards Identification 

3.1 Emergency Overview 

HMIS Rating

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

Inhalation: Prolonged exposure to dusts may cause respiratory tract irritation.

Ingestion: No known adverse effects.

Eye Contact: May cause irritation on prolonged or repeated contact.

Skin Contact: May cause irritation on prolonged or repeated contact.

4. First Aid Measures

4.0 Ingestion: Seek medical attention if large quantities are ingested.

Inhalation: Remove to fresh air.

Eye Contact: Immediately flush eyes with large quantities of water, call a physician if irritation persists.

5. Fire Fighting Measure

5.0 Flash Point: Non Flammable 

Lower Explosion Limit: Not Applicable 

Upper Explosion Limit: Not Applicable

Autoignition Temperature: Not Applicable

Use extinguishing agent suitable for type of surrounding fire.

6. Accidental Release Measures

6.0 Spills: No special procedures are required for clean-up of spills or leaks. Spherical shape of spilled pellets can create a slip hazard.

7. Handling and Storage

7.0 Store under dry conditions. Handle with adequate ventilation. Use a niosh/MSHA approved respirator if dust is present.

8. Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creating dust.

8.2 Personal Protection 

HESI101324
Sintered Bauxite

Material Safety Data Sheet

Norton Proppants, Inc.

Use niosh/MHSA approved respiratory protective equipment when airborne concentrations exceed applicable criteria. Wear safety glasses at all times to 

prevent eye irritation.

8.3 Exposure Guidelines 

Ingredient CAS# %/Weight OSHA PEL/TWA ACGIH-TWA TLV

Corundum 1302-44-56 65-85 15mg/m3 (total) 5mg/m3 (respir)

10mg/m3 (total) 3mg/m3 (respir) 

Aluminum Silicate 1302-76-7 15-35 15mg/m3 (total) 5mg/m3 (respir) 

10mg/m3 (total) 3mg/m3 (respir) 

9. Physical and Chemical Properties

9.0 Appearance: Grayish brown to black free flowing granules.

Odor: None

Flash Point: N/A. This material does not give a flashpoint by conventional methods.

Stability: Stable

Specific Gravity: 3.45-3.55

pH: N/A

Vapor Pressure @25°C: N/A 

Viscosity Not Applicable 

Solubility in Water: Non-Soluble

Boiling Point: N/A

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1).

11. Toxicological Information 

See Section 3.

LC50: Not Available 

LD50: Not Available

12. Ecological Information 

Not Determined 

13. Disposal Considerations 

Dispose of according to local, state/provencial requirements.

14. Transportation Information 

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S. Regulatory Information (Selected regulations)

SARA Title III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA): N/A

Cercla Reportable Quantity: None

Clean Air Amendments-Hazardous Air Pollutants: None

California State Proposition 65: N/A

16. OTHER INFORMATION

The OHSA Hazard Communication Standard 29CFR 1910.1200 requires that the information contained on these sheets be made available to your 

workers. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this 

product and its ingredients.

DISCLAIMER

Seller makes no warranty, expressed or implied, concerning the product or the merchantability or fitness thereof for any purpose, except that the product 

conforms to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be 

greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall seller be liable for 

incidental or consequential damages, whether buyer's claim is based on contract, breach of warranty, negligence or otherwise.

ISSUE DATE: 1-MARCH-00

HESI101325
HESI101326
Sintered Bauxite

Material Safety Data Sheet

Norton Proppants, Inc.

11300 North Central Expressway, Suite 402

Dallas, Texas 75243

(214) 233-0661

Fax (214) 233-1409

For Marketing and Technical

5300 Gerber Road Information Contact:

Fort Smith, Arkansas 72904

(501) 782-2001

Fax (501) 782-9984

Proppant Mfg. Facility:

Fort Smith, Arkansas 

Alice, Texas

Fairbanks, Alaska

Red Deer, Alberta, Canada

Rock Springs, Wyoming

Inventory Locations:

1. Chemical Name and Company Identification

1.0 Product Name : Sintered Bauxite (all mesh sizes)

Synonym(s) Ceramic Proppant

Chemical Family: Aluminosilicate

Manufacturer: NORTON PROPPANTS

5300 GERBER ROAD

FORT SMITH, ARKANSAS 72904

24-HOUR EMERGENCY (501)782-2001

2. Component Information 

2.0 Chemical Name Common Name % By Weight (Typical)

Aluminum Silicate Mullite 15-35

Aluminum Oxide Corundum 65-85

3. Hazards Identification 

3.1 Emergency Overview 

HMIS Rating

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

Inhalation: Prolonged exposure to dusts may cause respiratory tract irritation.

Ingestion: No known adverse effects.

Eye Contact: May cause irritation on prolonged or repeated contact.

Skin Contact: May cause irritation on prolonged or repeated contact.

4. First Aid Measures

4.0 Ingestion: Seek medical attention if large quantities are ingested.

Inhalation: Remove to fresh air.

Eye Contact: Immediately flush eyes with large quantities of water, call a physician if irritation persists.

5. Fire Fighting Measure

5.0 Flash Point: Non Flammable 

Lower Explosion Limit: Not Applicable 

Upper Explosion Limit: Not Applicable

Autoignition Temperature: Not Applicable

Use extinguishing agent suitable for type of surrounding fire.

6. Accidental Release Measures

6.0 Spills: No special procedures are required for clean-up of spills or leaks. Spherical shape of spilled pellets can create a slip hazard.

7. Handling and Storage

7.0 Store under dry conditions. Handle with adequate ventilation. Use a niosh/MSHA approved respirator if dust is present.

8. Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creating dust.

8.2 Personal Protection 

HESI101327
Sintered Bauxite

Material Safety Data Sheet

Norton Proppants, Inc.

Use niosh/MHSA approved respiratory protective equipment when airborne concentrations exceed applicable criteria. Wear safety glasses at all times to 

prevent eye irritation.

8.3 Exposure Guidelines 

Ingredient CAS# %/Weight OSHA PEL/TWA ACGIH-TWA TLV

Corundum 1302-44-56 65-85 15mg/m3 (total) 5mg/m3 (respir)

10mg/m3 (total) 3mg/m3 (respir) 

Aluminum Silicate 1302-76-7 15-35 15mg/m3 (total) 5mg/m3 (respir) 

10mg/m3 (total) 3mg/m3 (respir) 

9. Physical and Chemical Properties

9.0 Appearance: Grayish brown to black free flowing granules.

Odor: None

Flash Point: N/A. This material does not give a flashpoint by conventional methods.

Stability: Stable

Specific Gravity: 3.45-3.55

pH: N/A

Vapor Pressure @25°C: N/A 

Viscosity Not Applicable 

Solubility in Water: Non-Soluble

Boiling Point: N/A

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1).

11. Toxicological Information 

See Section 3.

LC50: Not Available 

LD50: Not Available

12. Ecological Information 

Not Determined 

13. Disposal Considerations 

Dispose of according to local, state/provencial requirements.

14. Transportation Information 

14.1 U.S. Department of Transportation

Non-regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated

15. U.S. Regulatory Information (Selected regulations)

SARA Title III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA): N/A

Cercla Reportable Quantity: None

Clean Air Amendments-Hazardous Air Pollutants: None

California State Proposition 65: N/A

16. OTHER INFORMATION

The OHSA Hazard Communication Standard 29CFR 1910.1200 requires that the information contained on these sheets be made available to your 

workers. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this 

product and its ingredients.

DISCLAIMER

Seller makes no warranty, expressed or implied, concerning the product or the merchantability or fitness thereof for any purpose, except that the product 

conforms to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be 

greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall seller be liable for 

incidental or consequential damages, whether buyer's claim is based on contract, breach of warranty, negligence or otherwise.

ISSUE DATE: 1-MARCH-00

HESI101328
HESI101329
MATERIAL SAFETY DATA SHEET HAZARD RATING

4=EXTREME 0 fire

3=HIGH 1 health

4810 INDUSTRIAL DRIVE 2=MODERATE 0 reactivity MSDS NO.: 04

1=SLIGHT special NEW IBERIA, LOUISIANA 70560 protection

PHONE: (337) 367-6151 0=MINIMAL SEE SECTION IX

REVISION DATE: 11/07/01

EMERGENCY TELEPHONE NUMBER: (337) 367-3159 PAGE 1 OF 2

SECTION I: PRODUCT INFORMATION

TRADE NAME: CARBOHSP (All Mesh Sizes)

SYNONYM(S): Ceramic Proppant; Semi-Crystalline Alumina Silicate

CHEMICAL FAMILY: Aluminosilicate

SECTION II: COMPONENT INFORMATION

INGREDIENTS CAS NUMBER % WEIGHT OSHA PEL-TWA ACGIH-TWA TLV

Corundum 1302-74-5 74-76% 15 mg/m3 (total) 10 mg/m3 (total)

5 mg/m3 (resp) 3 mg/m3 (resp)

Mullite 1302-93-8 22-28% 15 mg/m3 (total) 10 mg/m3 (total)

5 mg/m3 (resp) 3 mg/m3 (resp)

SECTION III: PHYSICAL DATA (PUBLISHED OR ESTIMATED VALUES)

BOILING POINT: N/A °F SPECIFIC GRAVITY: 3.57 (H2O=1) pH: N/A

MELTING POINT: 4000 °F BULK DENSITY:: 124 lb/cu.ft

VAPOR PRESSURE: N/A mm Hg % VOLATILE BY WEIGHT: N/A

VAPOR DENSITY: N/A (Air=1) EVAPORATION RATE: N/A (Butyl

Acetate=1)

APPEARANCE/ODOR: Odorless dark-green to grey pellets SOLUBILITY IN WATER: Insoluble

VOLATILE ORGANIC COMPOUNDS (VOC): 0 lbs/gal (EPA Reference Methods 24)

SECTION IV: FIRE AND EXPLOSION HAZARD DATA

ESTIMATED EXPLOSIVE LIMITS (% By volume in air): LEL: N/A UEL: N/A FLASH POINT: N/A

SPECIAL FIRE FIGHTING PROCEDURES: This material does not give a flash point by conventional test methods. Use

extinguishing agent suitable for type of surrounding fire.

UNUSUAL HAZARDS: N/A

SECTION V: HEALTH HAZARD DATA

INHALATION: Product contains little or no particles of respirable size. However, the amount of fines may increase due to attrition

during shipment, use and handling. Dusts may cause respiratory tract irritation. Repeated or prolonged breathing of particles of

respirable size may cause severe respiratory disease.

SECTION VI: REACTIVITY DATA

STABILITY: Stable: X Unstable Conditions to Avoid: N/A

HAZARDOUS POLYMERIZATION: Will Occur: Will Not

Occur:

X Conditions to Avoid: N/A

INCOMPATIBLE MATERIALS: Chlorine Trifluoride

HAZARDOUS DECOMPOSITION PRODUCTS: N/A

SECTION VII: EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Remove affected person from source of exposure. Get medical attention if irritation persists.

INGESTION: No treatment is necessary unless large quantities are ingested. Seek medical advice if large quantities are

ingested.

EYE CONTACT: Immediately flush eyes with large amounts of water. Get medical attention if irritation persists.

SKIN CONTACT: Wash the affected area with soap and water. Get medical attention if irritation persists.

HESI101330
HAZARD RATING

4=EXTREME 0 fire

3=HIGH 1 health

4810 INDUSTRIAL DRIVE 2=MODERATE 0 reactivity MSDS NO.: 04

1=SLIGHT special NEW IBERIA, LOUISIANA 70560 protection

PHONE: (337) 367-6151 0=MINIMAL SEE SECTION IX

REVISION DATE: 11/07/01

EMERGENCY TELEPHONE NUMBER: (337) 367-3159 PAGE 2 OF 2

SECTION VIII: SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No Special procedures are required for clean-up of spills

or leaks of this material. Avoid methods that result in water pollution. Caution should be exercised regarding personal safety and

exposure to the spilled material, the material’s nature could cause reduced traction. Persons should take care so as not to slip.

WASTE DISPOSAL: Disposal must be at an approved waste disposal facility and in accordance with applicable Federal, State and

Local laws and regulations. Contact the district Director of the Environmental Protection Agency and/or state regulatory agency for

appropriate requirements.

SECTION IX: SPECIAL PROTECTION

RESPIRATORY: A NIOSH/MSHA approved respirator should be worn where airborne exposures may exceed

OSHA/ACGIH permissible air concentrations.

EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact lenses

when working with this substance. 

CLOTHING/GLOVES: Gloves are optional to reduce abrasion.

WORK HYGIENE PRACTICES: Handle in accordance with good personal hygiene and safety practices.

VENTILATION: Provide sufficient (general and/or local exhaust) ventilation to maintain exposure below

permissible air concentrations.

SECTION X: SPECIAL PRECAUTIONS

HANDLING/STORAGE: N/A

SECTION XI: ADDITIONAL/REGULATORY INFORMATION

TOXIC SUBSTANCE CONTROL ACT (TSCA) STATUS: All chemicals in this

product are listed, automatically included, or are exempt from listing on

the TSCA Inventory.

SARA TITLE III: Section 302:

Section 312:

Section 313:

None

None

None

CERCLA REPORTABLE QUANTITY: None

CLEAN AIR AMENDMENTS-HAZARDOUS AIR POLLUTANTS (HAPS): None

CALIFORNIA STATE PROPOSITION 65: N/A

MATERIAL SAFETY DATA SHEET

HESI101331
CARBOPROP® (All Mesh Sizes) 

MSDS NO: 03 

REVISION DATE: August 25, 2004 

MATERIAL SAFETY DATA SHEET PAGE 1 OF 3 

1. PRODUCT AND COMPANY IDENTIFICATION 

TRADE NAME: CARBOPROP® (All Mesh Sizes) 

SYNONYM(S): Ceramic Proppant; Semi-Crystalline Alumina Silicate 

CHEMICAL FAMILY: Aluminosilicate 

MANUFACTURER: CARBO Ceramics 

4810 Industrial Drive 

New Iberia, Louisiana 70560 

 Phone: 1-337-367-6151 

EMERGENCY PHONE: 1-337-367-3159 (U.S.A.) 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

INGREDIENTS CAS NUMBER CONCENTRATION CLASSIFICATION R-PHRASES 

Corundum 1302-74-5 40-60% Not Classified Not assigned 

Mullite 1302-93-8 35-60% Not Classified Not assigned 

3. HEALTH HAZARD INFORMATION 

INHALATION: Inhalation of dusts may cause respiratory tract irritation. Repeated or prolonged breathing of particles of respirable 

size may cause severe respiratory disease. However, this product contains few particles of respirable size. The 

amount of dust due to breakdown during shipment and intended use and handling is not expected to exceed 

applicable exposure limits. 

EYE CONTACT: Airborne dust may cause irritation to eyes. 

SKIN CONTACT: Prolonged contact with a skin may cause irritation. 

HMIS RATING: HEALTH 1 (slight) FLAMMABILITY 0 (minimal) REACTIVITY 0 (minimal) SPECIAL PROTECTION: 

(See section 8) 

4. FIRST AID MEASURES 

INHALATION: Remove affected person from source of exposure. Get medical attention if irritation occurs. 

INGESTION: Seek medical attention if large quantities are ingested. 

EYE CONTACT: Immediately flush eyes with large amounts of water, lifting the lower and upper lids occasionally. If irritation is 

present after washing, get medical attention. 

SKIN CONTACT: Wash the affected area with soap and water. Get medical attention if irritation occurs. 

5. FIRE-FIGHTING MEASURES 

ESTIMATED EXPLOSIVE LIMITS (% By volume in air): LEL: N/A UEL: N/A FLASH POINT: N/A 

SPECIAL FIRE FIGHTING PROCEDURES: This material does not give a flash point by conventional test methods. Use 

extinguishing agent suitable for type of surrounding fire. 

UNUSUAL HAZARDS: N/A 

6. SPILL OR LEAK PROCEDURES 

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: No Special procedures are required for clean-up of spills or 

leaks of this material. Caution should be exercised regarding personal safety and exposure to the spilled material, the material’s nature 

could cause reduced traction. Persons should take care so as not to slip. 

HESI101332
CARBOPROP® (All Mesh Sizes) 

MSDS NO: 03 

REVISION DATE: August 25, 2004 

MATERIAL SAFETY DATA SHEET PAGE 2 OF 3 

7. HANDLING AND STORAGE 

HANDLING: Do not create dust. Use personal protective equipment. Refer to section 8 for personal protective equipment. 

STORAGE: Store dry in closed container to reduce dust. 

8. EXPOSURE CONTROLS/PROTECTION DURING USE 

EXPOSURE LIMITS: INGREDIENTS OSHA PEL-TWA ACGIH-TWA TLV 

 Corundum 15 mg/m3 (total) 10 mg/m3 (total) 

 5 mg/m3 (respirable) 3 mg/m3 (resp) 

 Mullite 15 mg/m3

 (total) 

 5 mg/m3

 (respirable) 

10 mg/m3 (total) 

 3 mg/m3

 (resp) 

ENGINEERING CONTROL 

MEASURES: 

Exposure to this material may be controlled in a number of ways. The measures 

appropriate for a particular worksite depend on how the material is used and the potential 

for exposure. Use of the basic principles of industrial hygiene will enable safe handling of 

the material. 

RESPIRATORY: An applicable NIOSH/MSHA or equivalent approved respirator should be worn where 

airborne exposures may exceed OSHA/ACGIH permissible air concentrations. 

EYE PROTECTION: Wear safety glasses or chemical goggles to prevent eye contact. Do not wear contact 

lenses when working with this substance unless protected under full coverage goggles. 

CLOTHING/GLOVES: Gloves are optional to reduce abrasion. 

WORK HYGIENE PRACTICES: Handle in accordance with good personal hygiene and safety practices. 

VENTILATION: Provide sufficient (general and/or local exhaust) ventilation to maintain exposure below 

permissible air concentrations. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

BOILING POINT: N/A °

F SPECIFIC GRAVITY: 3.3 (H2O=1) pH: N/A 

MELTING POINT: 4000 °

F (estimated) BULK DENSITY: 118 lb/cu.ft. 

VAPOR PRESSURE: N/A mm Hg % VOLATILE BY 

WEIGHT: 

N/A 

VAPOR DENSITY: N/A (Air=1) EVAPORATION RATE: N/A (Butyl Acetate=1) 

APPEARANCE/ODOR: Odorless brown to dark green to black 

spheres 

SOLUBILITY IN WATER: Insoluble 

VOLATILE ORGANIC COMPOUNDS (VOC): 0 lbs/gal (EPA Reference Methods 24) 

10. STABILITY AND REACTIVITY 

REACTIVITY: Minimal 

STABILITY: Stable 

INCOMPATIBLE MATERIALS: Chlorine Triflouride. 

11. TOXICOLOGICAL INFORMATION 

ACUTE EFFECTS Coughing and throat irritation are early symptoms of excessive exposure. May be irritating to the 

respiratory system, lungs and skin. May also cause irritation to eyes. 

CHRONIC EFFECTS: Chronic exposure in excess of established human exposure levels can cause severe respiratory disease.

HESI101333
CARBOPROP® (All Mesh Sizes) 

MSDS NO: 03 

REVISION DATE: August 25, 2004 

MATERIAL SAFETY DATA SHEET PAGE 3 OF 3 

12. ECOLOGICAL INFORMATION 

This product poses no significant environmental contamination impact during expected use, handling, and proper disposal. 

13. DISPOSAL CONSIDERATIONS 

WASTE DISPOSAL: Disposal must be at an approved waste disposal facility and in accordance with applicable Federal, State and 

Local laws and regulations. Contact the district Director of the Environmental Protection Agency and/or state regulatory agency for 

appropriate requirements. 

14. TRANSPORTATION INFORMATION 

UN NO. N/A 

ICAO/IATA Not Restricted 

RID/ADR Not Restricted 

DOT SHIPPING DESCRIPTION Not Restricted 

CAN Not Restricted 

IMO Not Restricted 

15. REGULATORY INFORMATION 

TOXIC SUBSTANCE CONTROL ACT (TSCA) STATUS: All chemicals in this product are 

listed, automatically included, or are exempt from listing on the TSCA Inventory.

SARA TITLE III: Section 302: 

Section 312: 

Section 313: 

None 

None 

None 

CERCLA REPORTABLE QUANTITY: None 

CLEAN AIR AMENDMENTS-HAZARDOUS AIR POLLUTANTS (HAPS): None 

CALIFORNIA STATE PROPOSITION 65: n/a 

 

16. OTHER INFORMATION 

HESI101334
Interprop®

Material Safety Data Sheet

Norton Proppants, Inc.

11300 North Central Expressway, Suite 402

Dallas, Texas 75243

(214) 233-0661

Fax (214) 233-1409

For Marketing and Technical

5300 Gerber Road Information Contact:

Fort Smith, Arkansas 72904

(501) 782-2001

Fax (501) 782-9984

Proppant Mfg. Facility:

Fort Smith, Arkansas 

Alice, Texas

Fairbanks, Alaska

Red Deer, Alberta, Canada

Rock Springs, Wyoming

Inventory Locations:

1. Chemical Name and Company Identification

1.0 Product Name : Interprop (all mesh sizes)

Synonym(s): Ceramic Proppant

Chemical Family: Aluminosilicate

Manufacturer: NORTON PROPPANTS

5300 GERBER ROAD

FORT SMITH, ARKANSAS 72904

24-HOUR EMERGENCY (501)782-2001

2. Component Information 

2.0 Chemical Name Common Name % By Weight (Typical)

Aluminum Silicate Mullite 35-65

Aluminum Oxide Corundum 35-65

3. Hazards Identification 

3.1 Emergency Overview 

HMIS Rating

Health: 1. (Slight)

Flammability: 0. (Minimal)

Reactivity: 0. (Minimal)

Chronic: 1. (Slight)

3.2 Potential Health Effects

Inhalation: Prolonged exposure to dusts may cause respiratory tract irritation.

Ingestion: No known adverse effects.

Eye Contact: May cause irritation on prolonged or repeated contact.

Skin Contact: May cause irritation on prolonged or repeated contact.

4. First Aid Measures

4.0 Ingestion: Seek medical attention if large quantities are ingested.

Inhalation: Remove to fresh air.

Eye Contact: Immediately flush eyes with large quantities of water, call a physician if irritation persists.

5. Fire Fighting Measure

5.0 Flash Point: Non Flammable 

Lower Explosion Limit: N/A 

Upper Explosion Limit: N/A

Autoignition Temperature: N/A

Use extinguishing agent suitable for type of surrounding fire.

6. Accidental Release Measures

6.0 Spills: No special procedures are required for clean-up of spills or leaks. Spherical shape of spilled pellets can create a slip hazard.

7. Handling and Storage

7.0 Store under dry conditions. Handle with adequate ventilation. Use a niosh/MSHA approved respirator if dust is present.

8. Exposure Control/Personal Protection

8.1 Exposure Control

Minimize creating dust.

HESI101335
Interprop®

Material Safety Data Sheet

Norton Proppants, Inc.

8.2 Personal Protection 

Use Niosh/MHSA approved respiratory protective equipment when airborne concentrations exceed applicable criteria. Wear safety glasses at all times to 

prevent eye irritation.

8.3 Exposure Guidelines 

Ingredient CAS# %/Weight OSHA PEL/TWA ACGIH-TWA TLV

Corundum 1302-44-56 35-65 15mg/m3 (total) 5mg/m3 (respir)

10mg/m3 (total) 3mg/m3 (respir) 

Aluminum Silicate 1302-76-7 35-65 15mg/m3 (total) 5mg/m3 (respir) 

10mg/m3 (total) 3mg/m3 (respir) 

9. Physical and Chemical Properties

9.0 Appearance: Grayish brown to black free flowing granules.

Odor: None

Flash Point: N/A. This material does not give a flashpoint by conventional methods.

Stability: Stable

Specific Gravity: 3.10-3.20

pH: N/A 

Vapor Pressure @25°C: N/A 

Viscosity: N/A 

Solubility in Water: N/A

Boiling Point: N/A 

10. Stability and Reliability

Normally stable as defined in NFPA 704-12 (4-3.1).

11. Toxicological Information 

See Section 3.

LC50: Not Available 

LD50: Not Available

12. Ecological Information 

Not Determined.

13. Disposal Considerations 

Dispose of according to local, state/provencial requirements.

14. Transportation Information 

14.1 U.S. Department of Transportation

Non-regulated.

14.2 Canadian Transportation of Dangerous Goods (TDG)

Non-regulated.

15. U.S. Regulatory Information (Selected regulations)

SARA Title III

Section 302: None

Section 312: None

Section 313: None

Toxic Substance Control Act (TSCA) N/A

Cercla Reportable Quantity: None

Clean Air Amendments-Hazardous Air Pollutants: None

California State Proposition 65: N/A

16. OTHER INFORMATION

The OHSA Hazard Communication Standard 29CFR 1910.1200 requires that the information contained on these sheets be made available to your 

workers. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of 

this product and its ingredients.

DISCLAIMER

Seller makes no warranty, expressed or implied, concerning the product or the merchantability or fitness thereof for any purpose, except that the product 

conforms to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be 

greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall seller be liable for 

incidental or consequential damages, whether buyer's claim is based on contract, breach of warranty, negligence or otherwise.

ISSUE DATE: 1-MARCH-00 

HESI101336
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PROPYLENE GLYCOL

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PROPYLENE GLYCOL

Synonyms: None

Chemical Family: Glycol

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Propylene glycol 57-55-6 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Repeated overexposure may cause liver and

kidney effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PROPYLENE GLYCOL

Page 1 of 6

HESI101337
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 212

Flash Point/Range (C): 100

Flash Point Method: PMCC

Autoignition Temperature (F): 700

Autoignition Temperature (C): 371

Flammability Limits in Air - Lower (%): 2.6

Flammability Limits in Air - Upper (%): 12.5

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

PROPYLENE GLYCOL

Page 2 of 6

HESI101338
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: 6

Specific Gravity @ 20 C (Water=1): 1.038

Density @ 20 C (lbs./gallon): 8.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 369

Boiling Point/Range (C): 187

Freezing Point/Range (F): -74

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): 0.06

Vapor Density (Air=1): 2.62

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): > 10%

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Hydrocarbons. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and

central nervous system depression. May cause liver and kidney damage.

Aggravated Medical Conditions Liver and kidney disorders. Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

PROPYLENE GLYCOL

Page 3 of 6

HESI101339
Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 3000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

PROPYLENE GLYCOL

Page 4 of 6

HESI101340
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PROPYLENE GLYCOL

Page 5 of 6

HESI101341
PROPYLENE GLYCOL

Page 6 of 6

HESI101342
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: PROTEX-ALL INHIBITOR

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: PROTEX-ALL INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 5 - 10% 100 mg/m3 50 ppm

Quaternary ammonium

compound

1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

PROTEX-ALL INHIBITOR

Page 1 of 6

HESI101343
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >200

Flash Point/Range (C): >93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves. Nitrile gloves. Use Viton or 4H gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear dark red

PROTEX-ALL INHIBITOR

Page 2 of 6

HESI101344
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Amine

pH: 5.5-6.5

Specific Gravity @ 20 C (Water=1): 1.034-1.046

Density @ 20 C (lbs./gallon): 8.61-8.71

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 18.3

Vapor Density (Air=1): >1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause skin defatting with prolonged exposure.

Eye Contact May cause eye irritation.

Ingestion May cause kidney damage. May affect the heart and cardiovascular system. May

cause brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

PROTEX-ALL INHIBITOR

Page 3 of 6

HESI101345
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

PROTEX-ALL INHIBITOR

Page 4 of 6

HESI101346
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 10310 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

PROTEX-ALL INHIBITOR

Page 5 of 6

HESI101347
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

PROTEX-ALL INHIBITOR

Page 6 of 6

HESI101348
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: RC CERAMIC PROP

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: RC CERAMIC PROP

Synonyms: None

Chemical Family: Mineral

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phenol / formaldehyde resin 9003-35-4 1 - 5% Not applicable Not applicable

Crystalline silica, quartz 14808-60-7 10 - 30% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

Mullite 1302-93-8 60 - 100% 5 mg/m3

 (R) 15 mg/m3 (T)

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation. May cause allergic skin and respiratory

reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

RC CERAMIC PROP

Page 1 of 7

HESI101349
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use.

RC CERAMIC PROP

Page 2 of 7

HESI101350
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark green

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.35

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 100

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials. Amorphous silica may

transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

RC CERAMIC PROP

Page 3 of 7

HESI101351
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause a rash and itching of the skin.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

RC CERAMIC PROP

Page 4 of 7

HESI101352
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

RC CERAMIC PROP

Page 5 of 7

HESI101353
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

RC CERAMIC PROP

Page 6 of 7

HESI101354
***END OF MSDS***

RC CERAMIC PROP

Page 7 of 7

HESI101355
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: RC CERAMIC PROP PLUS

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: RC CERAMIC PROP PLUS

Synonyms: None

Chemical Family: Metal oxide

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum oxide 1344-28-1 30 - 60% 10 mg/m3 10 mg/m3

Aluminum silicate 1302-76-7 30 - 60% Not applicable 15 mg/m3

Crystalline silica, quartz 14808-60-7 0 - 1% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye, skin, and respiratory irritation. May cause allergic skin and

respiratory reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

RC CERAMIC PROP PLUS

Page 1 of 7

HESI101356
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

RC CERAMIC PROP PLUS

Page 2 of 7

HESI101357
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark gray

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.53

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials. Amorphous silica may

transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

RC CERAMIC PROP PLUS

Page 3 of 7

HESI101358
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mechanical skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

RC CERAMIC PROP PLUS

Page 4 of 7

HESI101359
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

RC CERAMIC PROP PLUS

Page 5 of 7

HESI101360
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

RC CERAMIC PROP PLUS

Page 6 of 7

HESI101361
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

RC CERAMIC PROP PLUS

Page 7 of 7

HESI101362
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 DynaProp G2

Page 1

Section I

Product Type: 20/40 Ceramic Oil/gas well Proppant

Application: Hydraulic Fracturing or Prepacked screens

Manufacturer's Name Telephone Number

Santrol (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 04/02/03

Section II - Hazardous Ingredients

Hazardous component CAS # OSHA PEL ACGIH TLV OTHER 

Percent

Aluminum Oxide 1344-28-1 0.15 mg/M3 10mg/M316-30%

Aluminum silicate 1304-76-7 15.0 mg/M310.0 mg/M360-74%

Silicon Dioxide 60676-86-0 20 MPPCF 10.0 mg/M3<10%

Iron Oxide 1309-37-1 10 mg/M35.0 mg/M34-11%

Titanium Oxide 13463-67-7 N/A N/A 3-5%

P/F Novolac Resin 9003-35-4 N/K N/K 3-5%

Hexamethylenetetramine 1009-7-0 N/K N/K <1%

Epichlorohydrin 025085-99-8 N/K N/K <0.5%

Hazard Rating Scale: 1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: NONE

Canadian hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS: ClassD, Div 2A, 2B

CEPA: Listed on DSL or otherwise in compliance with CEPA

NPRI: CEPA subsection 16.1 None required

USDOT: Not regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:

CAS# Chemical Name % by Weight

None None

HESI101363
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 DynaProp G2

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: oF N/A Specific Gravity (H2O=1): 2.6 - 3.7

Vapor Pressure (mmHg): at 20oC N/A Melting Point: 3700 - 6000 oF

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin type odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) None

Flammable Limits in air, % : Lower: Upper: None, except dusting conditions.

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable. Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation of dust.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

HESI101364
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 DynaProp G2

Page 3

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or

information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is

believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and

therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular

purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated

herein, and does not relate to its use in combination with any other material or in any other process.

HESI101365
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

1/7

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: CeramaxTM I, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: CeramaxTM I, all sizes 

PRODUCT CODE: 325414GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

SOLD UNDER BORDEN U.S. PATENTS NUMBERS 5,639,806 AND 

6,528,157 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

1302-93-8 Mullite 50.0 - 70.0 

14464-46-1 *Cristobalite 10.0 - 30.0 

7631-86-9 *Silica 10.0 - 30.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Gray, free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HESI101366
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

2/7

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

3.2 Potential Health Effects

Immediate Hazards 

INGESTION: Not expected to be harmful under normal conditions of use. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

7631-86-9 Silica

Can cause lung fibrosis. Pre-existing respiratory disorders may be aggravated by exposure. 

-- See Footnote 

14464-46-1 Cristobalite

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an 

increased incidence of significant disease endpoints such as scleroderma (an immune system disorder 

manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also 

reported to increase the risk of tuberculosis. 

Footnote: As of the date of issuance of this document, this material has not been listed by NTP, 

classified by IARC nor regulated by OSHA as a carcinogen. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

HESI101367
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

3/7

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

HESI101368
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

4/7

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact.

8.3 Exposure Guidelines 

1302-93-8 Mullite 

ACGIH TLV 8-hr TWA 10 mg/m3 inhalable particulate; Particles 

(Insoluble or Poorly Soluble) 

Not Otherwise Specified 

OSHA PEL 8-hr TWA 5 mg/m3 respirable particulate 

8-hr TWA 15 mg/m3 total dust 

VENDOR 

OEL 

8-hr TWA 2 mg/m3 (as Kaolin) 

14464-46-1 Cristobalite 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction 

OSHA PEL 8-hr TWA 5/(%SiO2+2

) mg/m3 

respirable dust; (as Quartz) 

8-hr TWA 15/(%SiO2+

2) mg/m3 

total dust; (as Quartz) 

Remanded TWA 0.05 mg/m3 respirable dust; (as Quartz); 1989 

PEL remanded, but in effect in 

some states 

NIOSH 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

7631-86-9 Silica 

ACGIH TLV 8-hr TWA 10 mg/m3 (as amorphous silica) 

OSHA PEL 8-hr TWA 80/(%SiO2) 

mg/m3 

20 mppcf; (as amorphous silica) 

Remanded TWA 6 mg/m3 (as amorphous silica); 1989 PEL 

remanded, but in effect in some 

states 

9. Physical and Chemical Properties 

Appearance Gray, free flowing granules 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity 2.50 - 2.80 

pH Not applicable 

Viscosity Not applicable 

Freezing point 2,037.8 - 3,315.6 °C (3,700.0 - 6,000.1 °F) 

Solubility in water Negligible 

Octanol/water partition coefficient Not available 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

HESI101369
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

5/7

Incompatibilities: 

Powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

1302-93-8 Mullite 

LC50: Not available

LD50: Not available

14464-46-1 Cristobalite 

LC50: Not available

LD50: Not available

7631-86-9 Silica 

LC50: Not available

LD50: Oral-rat= 3,160 mg/kg (RTECS)

12. Ecological Information 

Not determined 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

HESI101370
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

6/7

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

HESI101371
Page 

CeramaxTM I, all sizes Version: 2.5 Printed: 01/15/2004 

7/7

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101372
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 MagnaProp G2

Page 1

Section I

Product Type: 20/40 Ceramic Oil/gas well Proppant

Application: Hydraulic Fracturing or Prepacked screens

Manufacturer's Name Telephone Number

Santrol (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 04/02/03

Section II - Hazardous Ingredients

Hazardous component CAS # OSHA PEL ACGIH TLV OTHER 

Percent

Aluminum Oxide 1344-28-1 0.15 mg/M3 10mg/M316-30%

Aluminum silicate 1304-76-7 15.0 mg/M310.0 mg/M360-74%

Silicon Dioxide 60676-86-0 20 MPPCF 10.0 mg/M3<10%

Iron Oxide 1309-37-1 10 mg/M35.0 mg/M34-11%

Titanium Oxide 13463-67-7 N/A N/A 3-5%

P/F Novolac Resin 9003-35-4 N/K N/K 3-5%

Hexamethylenetetramine 1009-7-0 N/K N/K <1%

Epichlorohydrin 025085-99-8 N/K N/K <0.5%

Hazard Rating Scale: 1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: NONE

Canadian hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS: ClassD, Div 2A, 2B

CEPA: Listed on DSL or otherwise in compliance with CEPA

NPRI: CEPA subsection 16.1 None required

USDOT: Not regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:

CAS# Chemical Name % by Weight

None None

HESI101373
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 MagnaProp G2

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: oF N/A Specific Gravity (H2O=1): 2.6 - 3.7

Vapor Pressure (mmHg): at 20oC N/A Melting Point: 3700 - 6000 oF

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin type odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) None

Flammable Limits in air, % : Lower: Upper: None, except dusting conditions.

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable. Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation of dust.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

HESI101374
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 MagnaProp G2

Page 3

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or

information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is

believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and

therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular

purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated

herein, and does not relate to its use in combination with any other material or in any other process.

HESI101375
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

1/7

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: CeramaxTM E, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: CeramaxTM E, all sizes 

PRODUCT CODE: 325054GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

1302-93-8 Mullite 70.0 - 100.0 

7631-86-9 *Silica 10.0 - 30.0 

14464-46-1 *Cristobalite 10.0 - 30.0 

100-97-0 *Hexamethylenetetramine 0.1 - 1.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

HESI101376
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

2/7

3.2 Potential Health Effects

Immediate Hazards 

INGESTION: No hazards known to company. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

Silica 7631-86-9

Can cause lung fibrosis. Pre-existing respiratory disorders may be aggravated by exposure. 

-- See Footnote 

Cristobalite 14464-46-1

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased 

incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested 

by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also reported to 

increase the risk of tuberculosis. 

Hexamethylenetetramine 100-97-0

May cause allergic skin and respiratory reactions. 

-- See Footnote 

Footnote: As of the date of issuance of this document, this material has not been listed by NTP, 

classified by IARC nor regulated by OSHA as a carcinogen. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

HESI101377
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

3/7

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

HESI101378
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

4/7

8.3 Exposure Guidelines 

Mullite 1302-93-8 

ACGIH TLV 8-hr TWA 10 mg/m3 inhalable particulate; Particles 

(Insoluble or Poorly Soluble) 

Not Otherwise Specified 

OSHA PEL 8-hr TWA 5 mg/m3 respirable particulate 

8-hr TWA 15 mg/m3 total dust 

VENDOR 

OEL 

8-hr TWA 2 mg/m3 (as Kaolin) 

Silica 7631-86-9 

ACGIH TLV 8-hr TWA 10 mg/m3 (as amorphous silica) 

OSHA PEL 8-hr TWA 80/(%SiO2) 

mg/m3 

20 mppcf; (as amorphous silica) 

Remanded TWA 6 mg/m3 (as amorphous silica); 1989 PEL 

remanded, but in effect in some 

states 

Cristobalite 14464-46-1 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction 

OSHA PEL 8-hr TWA 5/(%SiO2+2

) mg/m3 

respirable dust; (as Quartz) 

8-hr TWA 15/(%SiO2+

2) mg/m3 

total dust; (as Quartz) 

Remanded TWA 0.05 mg/m3 respirable dust; (as Quartz); 1989 

PEL remanded, but in effect in 

some states 

NIOSH 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

Document for Crystalline Silica 

Hexamethylenetetramine 100-97-0 

ACGIH TLV 8-hr TWA 10 mg/m3 inhalable; Particles (Insoluble or 

Poorly Soluble) Not Otherwise 

Specified 

OSHA PEL 8-hr TWA 5 mg/m3 respirable particulate 

8-hr TWA 15 mg/m3 total dust 

9. Physical and Chemical Properties 

Appearance Free flowing granules 

Color Green 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity Approx. 2.53 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not applicable 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

HESI101379
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

5/7

Incompatibilities: 

None known to company.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

Mullite 1302-93-8 

LC50: Not available

LD50: Not available

Silica 7631-86-9 

LC50: Not available

LD50: Oral-rat= 3,160 mg/kg (RTECS)

Cristobalite 14464-46-1 

LC50: Not available

LD50: Not available

Hexamethylenetetramine 100-97-0 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

HESI101380
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

6/7

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

HESI101381
Page 

CeramaxTM E, all sizes Version: 1 Printed: 01/15/2004 

7/7

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101382
MATERIAL SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

DESCRIPTION: CeramaxTM P, all sizes PAGE 1 OF 7

1. Chemical Product and Company Identification

DESCRIPTION: CeramaxTM P, all sizes

PRODUCT CODE: 328052GEN

PRODUCT TYPE: Oil/Gas Well Proppant

APPLICATION: Sold under Borden US Patent Nos. 6,528,157 & 5,639,806

Manufacturer/Supplier Information

MSDS Prepared by:

Borden Chemical, Inc. For Emergency Medical Assistance

15730 Park Row Blvd, Suite 400 Call Health & Safety Information Services

Houston, TX 77084 1-866-303-6949

For additional health, safety or regulatory information, call 502-449-6222.

2. Composition, Information on Ingredients

The ingredients listed below have been associated with one or more

immediate and/or delayed(*) health hazards. Risk of damage and effects

depends upon duration and level of exposure. BEFORE USING, HANDLING, OR

EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.

% by weight

1302-74-5 Corundum (Al203) >70

3. Hazards Identification

3.1 Emergency Overview

Appearance Free flowing granules

Odor Odorless

CAUTION!

May cause irritation of nose, throat and lungs if allowed to become

airborne.

May cause eye irritation.

HMIS Rating

HEALTH = 1 (slight)

FLAMMABILITY = 0 (minimal)

REACTIVITY = 0 (minimal)

067 328052GEN READ NEXT PAGE

HESI101383
DESCRIPTION: CeramaxTM P, all sizes PAGE 2 OF 7

3.2 Potential Health Effects

Immediate Hazards

INGESTION: Not expected to be harmful under normal conditions of

use.

INHALATION: Not expected to be harmful under normal conditions of

use. However, if allowed to become airborne, may cause

irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

This product may release formaldehyde. The amount and level will

depend on local conditions of use. Formaldehyde is irritating to the

eyes and upper respiratory system and may aggravate existing

respiratory conditions or allergies. OSHA has listed formaldehyde as

a potential human carcinogen. See the OSHA formaldehyde standard 29

CFR 1910.1048 for further details.

Delayed Hazards

None of the components present in this product at concentrations equal

to or greater than 0.1% have been listed by NTP, classified by IARC,

nor regulated by OSHA as a carcinogen.

4. First Aid Measures

INGESTION: If accidentally swallowed, dilute by drinking large

quantities of water. Immediately contact poison control

center or hospital emergency room for any other

additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call

a physician if irritation persists.

5. Fire Fighting Measures

Flash point Non-Flammable

Lower explosion limit Not applicable

Upper explosion limit Not applicable

Autoignition temperature Not applicable

Will not burn.

In case of fire, water should be used to keep fire-exposed

067 328052GEN READ NEXT PAGE

HESI101384
DESCRIPTION: CeramaxTM P, all sizes PAGE 3 OF 7

5. Fire Fighting Measures

containers cool.

6. Accidental Release Measures

Sweep (scoop) up and remove to a chemical disposal area. Prevent

entry into natural bodies of water.

7. Handling and Storage

7.1 Handling

Handle in accordance with good industrial hygiene and safety

practices. These practices include avoiding unnecessary exposure and

removal of the material from eyes, skin and clothing. Wash

thoroughly after handling. Always use appropriate Personal Protective

Equipment (PPE).

INHALATION: Avoid prolonged or repeated breathing of dust or

vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage

Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80 F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection

8.1 Exposure Controls

If airborne contaminants are generated when the material is heated or

handled, sufficient ventilation in volume and air flow patterns should

be provided to keep air contaminant concentration levels below

acceptable criteria.

8.2 Personal Protection

Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA

approved respiratory protection equipment. Respirators should be

selected based on the form and concentration of contaminants in air

in accordance with OSHA laws and regulations or other applicable

standards or guidelines, including ANSI standards regarding

respiratory protection. Wear impervious gloves as required to prevent

skin contact. Wear safety glasses with sideshields at all times to

prevent eye irritation.

067 328052GEN READ NEXT PAGE

HESI101385
DESCRIPTION: CeramaxTM P, all sizes PAGE 4 OF 7

8.3 Exposure Guidelines

Corundum (Al203) 1302-74-5

ACGIH TLV: 10 mg/m3 TWA

OSHA PEL: 5 mg/m3 TWA, respirable particulates; 15 mg/m3 TWA

total dust

9. Physical and Chemical Properties

Appearance Free flowing granules

Color Charcoal

Odor Odorless

Odor threshold Not applicable

Specific gravity 3.4-3.6

pH Not applicable

Viscosity, Brookfield Not applicable

Freezing point 3700-6000 F

Solubility in water Negligible

Octanol/water partition coefficient Not available

Vapor pressure @ 25 C Not applicable

Vapor density (air=1) Not applicable

Evaporation rate (butyl acetate=1) Not applicable

Boiling point, 760 mm Hg Not applicable

10. Stability and Reactivity

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities:

Powerful oxidizing agents such as fluorine, chlorine trifluoride,

manganese trioxide.

Decomposition products may include:

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen

cyanide, ammonia, particulate matter and other organic compounds

including benzo[a]pyrene.

Hazardous polymerization:

Will not occur.

Other Hazards:

None known to company.

11. Toxicological Information

See Section 3 Hazards Identification information.

Corundum (Al203) 1302-74-5

LC50: Not available

LD50: Not available

067 328052GEN READ NEXT PAGE

HESI101386
DESCRIPTION: CeramaxTM P, all sizes PAGE 5 OF 7

12. Ecological Information

Not determined.

13. Disposal Considerations

Dispose of according to local, state/provincial, and federal

requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not

be specific to your package size. You will need to apply the

appropriate regulations to properly classify your shipment for

transportation.

Non-Regulated

14.2 Canadian Transportation of Dangerous Goods (TDG)

Not determined.

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazard Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when

reviewed according to the requirements of the Occupational Safety and

Health Administration 29 CFR Part 1910.1200 "Hazard Communication"

Standard.

SARA Title III: Section 311/312

Does not meet any hazard category

SARA Title III Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the

reporting requirements of Section 313 of Title III of the Superfund

Amendments and Reauthorization Act of 1986, and Subpart C-Supplier

Notification Requirement of 40 CFR Part 372.

None required per SARA TITLE III SECTION 313.

067 328052GEN READ NEXT PAGE

HESI101387
DESCRIPTION: CeramaxTM P, all sizes PAGE 6 OF 7

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory.

We rely on certifications of compliance from our suppliers for

chemical substances not manufactured by us.

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard

criteria of the Controlled Products Regulation (CPR) and the MSDS

contains all the information required by the CPR.

Not a controlled product

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic

Substances List (DSL) or otherwise comply with CEPA new substance

notification requirements.

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the

reporting requirements of the Canadian Environmental Protection Act

(CEPA) subsection 16(1), National Pollutant Release Inventory.

None required.

16. Other Information

User’s Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace

Hazardous Materials Information System (WHMIS) require that the information

contained on these sheets be made available to your workers. Educate and

train your workers regarding OSHA and WHMIS precautions. Instruct your

workers to handle this product properly. Consult with appropriate experts

to guard against hazards associated with use of this product and its

ingredients.

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE

MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product

shall conform to contracted specifications, and that the product does not

infringe any valid United States or Canadian patent. No claim of any kind

shall be greater in amount than the purchase price of the quantity of

product in respect of which damages are claimed. In no event shall Seller

be liable for incidental or consequential damages, whether Buyer’s claim is

067 328052GEN READ NEXT PAGE

HESI101388
DESCRIPTION: CeramaxTM P, all sizes PAGE 7 OF 7

Disclaimer

based on contract, breach of warranty, negligence or otherwise.

CUR ISSUE 20-JUN-03

PREVIOUS ISSUE: 19-MAY-03

067 328052GEN THIS IS THE LAST PAGE

HESI101389
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 HyperProp G2

Page 1

Section I

Product Type: 20/40 Ceramic Oil/gas well Proppant

Application: Hydraulic Fracturing or Prepacked screens

Manufacturer's Name Telephone Number

Santrol (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 04/02/03

Section II - Hazardous Ingredients

Hazardous component CAS # OSHA PEL ACGIH TLV OTHER 

Percent

Aluminum Oxide 1344-28-1 0.15 mg/M3 10mg/M355-75%

Aluminum silicate 1304-76-7 15.0 mg/M310.0 mg/M315-35%

Silicon Dioxide 60676-86-0 20 MPPCF 10.0 mg/M3<5%

Iron Oxide 1309-37-1 10 mg/M35.0 mg/M33-5%

Titanium Oxide 13463-67-7 N/A N/A 3%

P/F Novolac Resin 9003-35-4 N/K N/K 3-5%

Hexamethylenetetramine 1009-7-0 N/K N/K <1%

Epichlorohydrin 025085-99-8 N/K N/K <0.5%

Hazard Rating Scale: 1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: NONE

Canadian hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS: ClassD, Div 2A, 2B

CEPA: Listed on DSL or otherwise in compliance with CEPA

NPRI: CEPA subsection 16.1 None required

USDOT: Not regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372:

CAS# Chemical Name % by Weight

None None

HESI101390
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 HyperProp G2

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: oF N/A Specific Gravity (H2O=1): 2.6 - 3.7

Vapor Pressure (mmHg): at 20oC N/A Melting Point: 3700 - 6000 oF

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin type odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) None

Flammable Limits in air, % : Lower: Upper: None, except dusting conditions.

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable. Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation of dust.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

HESI101391
SANTROL Material Safety Data Sheet

RESIN COATED CERAMIC PROPPANTS

 HyperProp G2

Page 3

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions: Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or

information provided herein. All information appearing herein is based upon data obtained from recognized technical sources. While the information is

believed to be accurate, Santrol, Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and

therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular

purposes and they assume all risks of their use of, or reliance upon, information contained herein. This information relates only to the product designated

herein, and does not relate to its use in combination with any other material or in any other process.

HESI101392
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SALT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SALT

Synonyms: None

Chemical Family: Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SALT

Page 1 of 5

HESI101393
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

SALT

Page 2 of 5

HESI101394
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 35.7

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

SALT

Page 3 of 5

HESI101395
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SALT

Page 4 of 5

HESI101396
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SALT

Page 5 of 5

HESI101397
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - COMMON BROWN

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - COMMON BROWN

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - COMMON BROWN

Page 1 of 6

HESI101408
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

SAND - COMMON BROWN

Page 2 of 6

HESI101409
Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63 - 2.67

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - COMMON BROWN

Page 3 of 6

HESI101410
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - COMMON BROWN

Page 4 of 6

HESI101411
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SAND - COMMON BROWN

Page 5 of 6

HESI101412
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - COMMON BROWN

Page 6 of 6

HESI101413
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - COMMON WHITE

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - COMMON WHITE

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - COMMON WHITE

Page 1 of 6

HESI101414
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

SAND - COMMON WHITE

Page 2 of 6

HESI101415
Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63 - 2.67

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - COMMON WHITE

Page 3 of 6

HESI101416
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - COMMON WHITE

Page 4 of 6

HESI101417
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SAND - COMMON WHITE

Page 5 of 6

HESI101418
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - COMMON WHITE

Page 6 of 6

HESI101419
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SAND - RESIEVED

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SAND - RESIEVED

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SAND - RESIEVED

Page 1 of 6

HESI101432
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

SAND - RESIEVED

Page 2 of 6

HESI101433
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Tan

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 100

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 65

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SAND - RESIEVED

Page 3 of 6

HESI101434
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SAND - RESIEVED

Page 4 of 6

HESI101435
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SAND - RESIEVED

Page 5 of 6

HESI101436
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SAND - RESIEVED

Page 6 of 6

HESI101437
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI101398
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI101399
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI101400
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI101401
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

1/6

 

 MATERIAL SAFETY DATA SHEET 

FOR INDUSTRIAL USE ONLY

DESCRIPTION: AcFrac® SB Excel, all sizes

1. Chemical Product and Company Identification 

DESCRIPTION: AcFrac® SB Excel, all sizes 

PRODUCT CODE: 324529GEN 

PRODUCT TYPE: Oil/Gas Well Proppant 

APPLICATION: Hydraulic Fracturing 

Manufacturer/Supplier Information 

MSDS prepared by: 

BORDEN CHEMICAL, INC. 

15730 Park Row Blvd., Suite 400 

Houston, TX 

77084 

For Emergency Medical Assistance

Call Health & Safety Information Services 

1-866-303-6949

For additional health and safety or regulatory information, call (502)449-6201.

2. Composition, Information on Ingredients 

The ingredients listed below have been associated with one or more immediate and/or delayed(*) health 

hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, 

HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE 

MSDS. 

% by weight 

14808-60-7 *Quartz (SiO2) 70.0 - 100.0 

3. Hazards Identification 

3.1 Emergency Overview 

Appearance Light green, free flowing granules 

Odor Odorless 

CAUTION! 

May cause irritation of nose, throat and lungs if allowed to become airborne. 

May cause eye irritation. 

HMIS Rating 

HEALTH = 1 (slight) 

FLAMMABILITY = 0 (minimal) 

REACTIVITY = 0 (minimal) 

CHRONIC = *

3.2 Potential Health Effects

HESI101402
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

2/6

Immediate Hazards 

INGESTION: No hazards known to company. 

INHALATION: Not expected to be harmful under normal conditions of use. However, if 

allowed to become airborne, may cause irritation of nose, throat and lungs.

SKIN: May cause irritation on prolonged or repeated contact.

EYES: May cause irritation on prolonged or repeated contact.

Delayed Hazards 

14808-60-7 Quartz (SiO2)

CANCER HAZARD. Can cause cancer. Use of this product may generate silica dust (which may be 

invisible). Inhaled silica has been classified by IARC as a human carcinogen.

 Inhalation of silica dust may cause delayed lung injury or lung fibrosis (including silicosis and/or 

pneumoconiosis) and/or other diseases which may lead to permanent disability and/or death. Silicosis is 

a form of disabling pulmonary fibrosis which can be progressive. Prolonged exposure to respirable silica 

may cause diminished lung capacity with shortness of breath during physical exertion and may cause 

fatigue, breathlessness, wheezing, cough, and sputum production. Pre-existing respiratory disorders may 

be aggravated by exposure. Smoking may aggravate the effects of exposure and may increase the risk of 

developing respiratory disease from exposure. Consult with your employer and your doctor for further 

information or if you believe you may be developing any breathing or lung problems. There is some 

evidence that breathing respirable crystalline silica or the disease silicosis is associated with an 

increased incidence of significant disease endpoints such as scleroderma (an immune system disorder 

manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Silicosis is also 

reported to increase the risk of tuberculosis. 

4. First Aid Measures 

INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. 

Immediately contact poison control center or hospital emergency room for any 

other additional treatment directions.

INHALATION: Remove to fresh air.

SKIN: In case of irritation, flush with water.

EYES: Immediately flush eyes with plenty of water. Call a physician if irritation 

persists.

5. Fire Fighting Measures 

Flash point Non-flammable 

Lower explosion limit Not applicable 

Upper explosion limit Not applicable 

Autoignition temperature Not applicable 

Will not burn.

In case of fire, water should be used to keep fire-exposed containers cool.

6. Accidental Release Measures 

Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.

HESI101403
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

3/6

7. Handling and Storage 

7.1 Handling 

Handle in accordance with good industrial hygiene and safety practices. These practices include 

avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash 

thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). 

INHALATION: Avoid prolonged or repeated breathing of dust or vapor.

SKIN: Avoid prolonged or repeated contact with skin and clothing.

EYES: Avoid prolonged or repeated contact with eyes.

7.2 Storage Do not expose to direct sunlight for long periods of time.

Keep away from moisture.

Store below 80°F out of direct sunlight in dry location.

Keep away from heat.

Store in cool, dry place to avoid blocking.

Use with adequate ventilation.

8. Exposure Controls/Personal Protection 

8.1 Exposure Controls 

If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in 

volume and air flow patterns should be provided to keep air contaminant concentration levels below 

acceptable criteria.

8.2 Personal Protection 

Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved 

respiratory protection equipment. Respirators should be selected based on the form and concentration of 

contaminants in air in accordance with OSHA laws and regulations or other applicable standards or 

guidelines, including ANSI standards regarding respiratory protection. Wear impervious gloves as 

required to prevent skin contact. Wear safety glasses with sideshields at all times to prevent eye 

irritation.

8.3 Exposure Guidelines 

14808-60-7 Quartz (SiO2) 

ACGIH TLV 8-hr TWA 0.05 mg/m3 respirable fraction; A2 - 

Suspected Human Carcinogen 

OSHA PEL 8-hr TWA 10/(%SiO2+

2) mg/m3 

respirable dust 

8-hr TWA 30/(%SiO2+

2) mg/m3 

total dust 

Remanded TWA 0.1 mg/m3 respirable dust; 1989 PEL 

remanded, but in effect in some 

states 

NIOSH 8-hr TWA 0.05 mg/m3 Respirable; Refer to NIOSH 

publications including Criteria 

HESI101404
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

4/6

Document for Crystalline Silica 

9. Physical and Chemical Properties 

Appearance Light green, free flowing granules 

Odor Odorless 

Odor threshold Not applicable 

Specific gravity Approx. 2.53 

pH Not applicable 

Viscosity Not applicable 

Freezing point Not applicable 

Solubility in water Negligible 

Octanol/water partition coefficient Not applicable 

Vapor pressure Not applicable 

Vapor density Not applicable 

Evaporation rate Not applicable 

Boiling point, 760 mm Hg Not applicable 

10. Stability and Reactivity 

Normally stable as defined in NFPA 704-12(4-3.1).

Incompatibilities: 

None known to company.

Decomposition products may include: 

CO, CO2, aldehydes (including formaldehyde), phenols, hydrogen cyanide, ammonia, particulate 

matter and other organic compounds including benzo[a]pyrene.

Hazardous polymerization: 

Will not occur.

Other Hazards: 

None known to company.

11. Toxicological Information 

See Section 3 Hazards Identification information.

14808-60-7 Quartz (SiO2) 

LC50: Not available

LD50: Not available

12. Ecological Information 

Not determined. 

13. Disposal Considerations 

Dispose of according to local, state/provincial, and federal requirements.

14. Transport Information

HESI101405
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

5/6

14.1 U.S. Department of Transportation (DOT)

The data provided in this section is for information only and may not be specific to your package size. 

You will need to apply the appropriate regulations to properly classify your shipment for transportation.

Regulation: Non regulated 

14.2 Canadian Transportation of Dangerous Goods (TDG)

Regulation: Non regulated 

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

OSHA Hazards Communication Standard 29CFR1910.1200

This material presents possible health hazards as determined when reviewed according to the 

requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard 

Communication" Standard. 

SARA Title III: Section 311/312

Immediate health hazard

Delayed health hazard 

SARA Title III: Section 313 and 40 CFR Part 372

This product contains the following toxic chemical(s) subject to the reporting requirements of Section 

313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart CSupplier Notification Requirement of 40 CFR Part 372. 

None required per SARA TITLE III SECTION 313. 

TSCA Section 8(b) Inventory

All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of 

compliance from our suppliers for chemical substances not manufactured by us. 

15.2 Canadian Regulations

Workplace Hazardous Materials Information System (WHMIS)

This product has been classified in accordance with the hazard criteria of the Controlled Products 

Regulation (CPR) and the MSDS contains all the information required by the CPR. 

Class D2A 

Class D2B 

Canadian Environmental Protection Act (CEPA)

All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise 

comply with CEPA new substance notification requirements. 

HESI101406
Page 

AcFrac® SB Excel, all sizes Version: 1.1 Current Issue: 01/13/2004 Printed: 01/15/2004 

6/6

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the reporting requirements of the Canadian 

Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. 

None required. 

16. Other Information

User's Responsibility

The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous 

Materials Information System (WHMIS) require that the information contained on these sheets be made 

available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. 

Instruct your workers to handle this product properly. Consult with appropriate experts to guard against 

hazards associated with use of this product and its ingredients. 

Disclaimer

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR 

THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product 

shall conform to contracted specifications, and that the product does not infringe any valid United 

States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of 

the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for 

incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, 

negligence or otherwise. 

HESI101407
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandWedge®

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandWedge®

Synonyms: None

Chemical Family: Blend

Application: Conductivity Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

SandWedge®

Page 1 of 6

HESI101438
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 66

Flash Point/Range (C): 18

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SandWedge®

Page 2 of 6

HESI101439
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Bland

pH: 8

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.52

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 35

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal. May cause central nervous

system depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

SandWedge®

Page 3 of 6

HESI101440
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (15.6 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (15.6 C)

SandWedge®

Page 4 of 6

HESI101441
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (15.6 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

SandWedge®

Page 5 of 6

HESI101442
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandWedge®

Page 6 of 6

HESI101443
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandWedge® WF

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandWedge® WF

Synonyms: None

Chemical Family: Blend

Application: Conductivity Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

Methanol 67-56-1 1 - 5% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Repeated overexposure may cause liver and

kidney effects. May be absorbed through the skin. May be harmful if swallowed. May

cause blindness. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

SandWedge® WF

Page 1 of 6

HESI101444
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 66

Flash Point/Range (C): 18

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

SandWedge® WF

Page 2 of 6

HESI101445
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Bland

pH: 7.5-9.8

Specific Gravity @ 20 C (Water=1): 0.903

Density @ 20 C (lbs./gallon): 7.52

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -40

Freezing Point/Range (C): < -40

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

SandWedge® WF

Page 3 of 6

HESI101446
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal. May cause central nervous

system depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May be fatal or cause blindness if swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

SandWedge® WF

Page 4 of 6

HESI101447
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (18.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

SandWedge® WF

Page 5 of 6

HESI101448
NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandWedge® WF

Page 6 of 6

HESI101449
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandWedge® NT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandWedge® NT

Synonyms: None

Chemical Family: Blend

Application: Flow Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm (S) 100 ppm (S)

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

SandWedge® NT

Page 1 of 6

HESI101450
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 143

Flash Point/Range (C): 62

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SandWedge® NT

Page 2 of 6

HESI101451
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Bland

pH: 7.4-8.8

Specific Gravity @ 20 C (Water=1): 0.963

Density @ 20 C (lbs./gallon): 8.02

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

SandWedge® NT

Page 3 of 6

HESI101452
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S.,Combustible Liquid, NA1993, III

(Contains Heavy Aromatic Naphtha, Dipropylene Glycol Ether)

Canadian TDG

Not restricted

SandWedge® NT

Page 4 of 6

HESI101453
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 168 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

SandWedge® NT

Page 5 of 6

HESI101454
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandWedge® NT

Page 6 of 6

HESI101455
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SandWedge® OS

Revision Date: 13-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SandWedge® OS

Synonyms: None

Chemical Family: Blend

Application: Conductivity Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 60 - 100% 100 ppm (S) 100 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

SandWedge® OS

Page 1 of 6

HESI101456
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 170

Flash Point/Range (C): 77

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3.0

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways. Vapors are heavier than air and may accumulate in low areas. Vapors

may travel along the ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SandWedge® OS

Page 2 of 6

HESI101457
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Mild amine

pH: 7.4 - 8.8

Specific Gravity @ 20 C (Water=1): 0.967

Density @ 20 C (lbs./gallon): 8.07

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 300 - 700

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

SandWedge® OS

Page 3 of 6

HESI101458
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

SandWedge® OS

Page 4 of 6

HESI101459
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

SandWedge® OS

Page 5 of 6

HESI101460
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SandWedge® OS

Page 6 of 6

HESI101461
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SCA-130 INHIBITOR

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SCA-130 INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aldol 107-89-1 30 - 60% Not applicable Not applicable

Crotonaldehyde 123-73-9 < 2 Not applicable 2 ppm, 6 mg/m3

Acetaldehyde 75-07-0 <1 25 ppm 200 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SCA-130 INHIBITOR

Page 1 of 6

HESI101462
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 65

Flash Point/Range (C): 18

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SCA-130 INHIBITOR

Page 2 of 6

HESI101463
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless to pale yellow

Odor: Pungent

pH: 5-7

Specific Gravity @ 20 C (Water=1): 1.053

Density @ 20 C (lbs./gallon): 8.77

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -22

Freezing Point/Range (C): -30

Vapor Pressure @ 20 C (mmHg): 0.1

Vapor Density (Air=1): 3.04

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 2-12

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin defatting with prolonged exposure. May cause skin

irritation.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

SCA-130 INHIBITOR

Page 3 of 6

HESI101464
Chronic Effects/Carcinogenicity This product contains a potential carcinogen.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1992,Flammable Liquid, Toxic, N.O.S.(Contains Acetaldehyde, Aldol), 3, (6.1), II, (18.3 C)

NAERG 131

Canadian TDG

Flammable Liquid, Toxic, N.O.S.(Contains Acetaldehyde, Aldol), 3, (6.1), UN1992, II, (18.3 C)

SCA-130 INHIBITOR

Page 4 of 6

HESI101465
ADR

UN1992,Flammable Liquid, Toxic, N.O.S.(Contains Acetaldehyde, Aldol), 3, (6.1), II

Air Transportation

ICAO/IATA

UN1992,Flammable Liquid, Toxic, N.O.S., 3, (6.1), II

(Contains Acetaldehyde, Aldol Solution)

Sea Transportation

IMDG

UN1992,Flammable Liquid, Toxic, N.O.S.(Contains Acetaldehyde, Aldol), 3, (6.1), II, (18.3 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Acetaldehyde//75-07-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 228 Gallons based on Crotonaldehyde (CAS: 123-

73-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

SCA-130 INHIBITOR

Page 5 of 6

HESI101466
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SCA-130 INHIBITOR

Page 6 of 6

HESI101467
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SCALECHEK HT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SCALECHEK HT

Synonyms: None

Chemical Family: Polymer

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic acid salt Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician None known.

SCALECHEK HT

Page 1 of 5

HESI101468
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 230

Flash Point/Range (C): Not DeterminedMin: > 110

Flash Point Method: Not Determined

Autoignition Temperature (F): 899

Autoignition Temperature (C): 481

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Slippery when wet.

Storage Information Store away from acids. Store away from oxidizers. Store in a cool well ventilated

area. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Off white

Odor: Odorless

pH: 8.27

SCALECHEK HT

Page 2 of 5

HESI101469
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 0.7

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 44.1

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 0.095

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2000 mg/kg (Rat)

Dermal Toxicity: LD50: > 3000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

SCALECHEK HT

Page 3 of 5

HESI101470
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

SCALECHEK HT

Page 4 of 5

HESI101471
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SCALECHEK HT

Page 5 of 5

HESI101472
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SCALECHEK LP-55 SCALE INHIBITOR

Revision Date: 13-Feb-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SCALECHEK LP-55 SCALE INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyacrylate 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SCALECHEK LP-55 SCALE INHIBITOR

Page 1 of 5

HESI101473
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 212

Flash Point/Range (C): Not DeterminedMin: > 100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0 , PPE: B

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear dark red

Odor: Characteristic

pH: 3.2 - 4.0

Specific Gravity @ 20 C (Water=1): 1.2

SCALECHEK LP-55 SCALE INHIBITOR

Page 2 of 5

HESI101474
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.99

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): > 212

Boiling Point/Range (C): > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

SCALECHEK LP-55 SCALE INHIBITOR

Page 3 of 5

HESI101475
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: > 1000 mg/l (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM48: > 1000 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

SCALECHEK LP-55 SCALE INHIBITOR

Page 4 of 5

HESI101476
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SCALECHEK LP-55 SCALE INHIBITOR

Page 5 of 5

HESI101477
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SCP-2

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SCP-2

Synonyms: None

Chemical Family: Silicate

Application: Scale Preventer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glassy calcium magnesium

phosphate

65997-17-3 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SCP-2

Page 1 of 5

HESI101478
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Clear

Odor: Odorless

pH: 7-7.5

Specific Gravity @ 20 C (Water=1): Not Determined

SCP-2

Page 2 of 5

HESI101479
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2900 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

SCP-2

Page 3 of 5

HESI101480
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SCP-2

Page 4 of 5

HESI101481
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SCP-2

Page 5 of 5

HESI101482
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SEM-5 EMULSIFIER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SEM-5 EMULSIFIER

Synonyms: None

Chemical Family: Blend

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Quaternary ammonium salts 30 - 60% Not applicable Not applicable

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SEM-5 EMULSIFIER

Page 1 of 6

HESI101483
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 55

Flash Point/Range (C): 13

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SEM-5 EMULSIFIER

Page 2 of 6

HESI101484
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Alcohol

pH: 6.5-9

Specific Gravity @ 20 C (Water=1): 0.93

Density @ 20 C (lbs./gallon): 7.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 200

Boiling Point/Range (C): 93

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 90

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. This product contains ingredients which may produce an

allergic skin reaction. It should be treated as a skin sensitizer.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

SEM-5 EMULSIFIER

Page 3 of 6

HESI101485
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, II, (17.8 C)

(Contains Isopropanol, Quaternary Ammonium Salts)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Quaternary Ammonium Salts), 3, (8), UN2924, II, (17.8 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Quaternary Ammonium Salts), 3, (8), II

SEM-5 EMULSIFIER

Page 4 of 6

HESI101486
Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), II

(Contains Isopropanol, Quaternary Ammonium Salts Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Quaternary Ammonium Salts), 3, (8), II, (17.8 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

SEM-5 EMULSIFIER

Page 5 of 6

HESI101487
WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SEM-5 EMULSIFIER

Page 6 of 6

HESI101488
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SEM-7 EMULSIFIER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SEM-7 EMULSIFIER

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Repeated overexposure may cause liver and

kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SEM-7 EMULSIFIER

Page 1 of 6

HESI101489
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 74

Flash Point/Range (C): 23

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 3, Reactivity 0

HMIS Ratings: Health 1, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SEM-7 EMULSIFIER

Page 2 of 6

HESI101490
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Alcohol

pH: 7-8

Specific Gravity @ 20 C (Water=1): 1.0

Density @ 20 C (lbs./gallon): 8.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 89

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 4.7

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

SEM-7 EMULSIFIER

Page 3 of 6

HESI101491
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Draize Rating (Skin): 2.2/8.0 (Rabbit) Mild

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 10.78% of COD Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM48: > 2000 mg/l (Arcatia tonsa)

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: E(B)C50: 400.7 mg/l (Skeletonema costatum) E(R)C50: 1866.4 mg/l (Skeletonema

costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (23.3 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (23.3 C)

SEM-7 EMULSIFIER

Page 4 of 6

HESI101492
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (23.3 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

SEM-7 EMULSIFIER

Page 5 of 6

HESI101493
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SEM-7 EMULSIFIER

Page 6 of 6

HESI101494
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SGA-1 GELLING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SGA-1 GELLING AGENT

Synonyms: None

Chemical Family: Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 30 - 60% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SGA-1 GELLING AGENT

Page 1 of 6

HESI101495
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 210

Flash Point/Range (C): Not DeterminedMin: > 98

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Butyl rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark red-brown

SGA-1 GELLING AGENT

Page 2 of 6

HESI101496
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Vinegar

pH: 1.9

Specific Gravity @ 20 C (Water=1): 0.99

Density @ 20 C (lbs./gallon): 8.27

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

SGA-1 GELLING AGENT

Page 3 of 6

HESI101497
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2790,Acetic Acid Solution, 8, II

NAERG 153

Canadian TDG

Acetic Acid Solution, 8, UN2790, II

ADR

UN2790,Acetic Acid Solution, 8, II

Air Transportation

ICAO/IATA

UN2790,Acetic Acid Solution, 8, II

SGA-1 GELLING AGENT

Page 4 of 6

HESI101498
Sea Transportation

IMDG

UN2790,Acetic Acid Solution, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1209 Gallons based on Acetic acid (CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

SGA-1 GELLING AGENT

Page 5 of 6

HESI101499
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SGA-1 GELLING AGENT

Page 6 of 6

HESI101500
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SGA-II

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SGA-II

Synonyms: None

Chemical Family: Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

SGA-II

Page 1 of 6

HESI101501
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Decomposition

in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Off white

Odor: Hydrocarbon

pH: 7

SGA-II

Page 2 of 6

HESI101502
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 1.3

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

SGA-II

Page 3 of 6

HESI101503
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

SGA-II

Page 4 of 6

HESI101504
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

SGA-II

Page 5 of 6

HESI101505
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SGA-II

Page 6 of 6

HESI101506
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SGA-III

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SGA-III

Synonyms: None

Chemical Family: Blend

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acrylic polymer 30 - 60% Not applicable Not applicable

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

SGA-III

Page 1 of 6

HESI101507
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: SFCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky

Odor: Hydrocarbon

SGA-III

Page 2 of 6

HESI101508
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.09

Density @ 20 C (lbs./gallon): 9.08

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

SGA-III

Page 3 of 6

HESI101509
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

SGA-III

Page 4 of 6

HESI101510
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

SGA-III

Page 5 of 6

HESI101511
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SGA-III

Page 6 of 6

HESI101512
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SGA-V

Revision Date: 17-Nov-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SGA-V

Synonyms: None

Chemical Family: Blend

Application: Acid gelling polymer

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Modified alkane 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

SGA-V

Page 1 of 6

HESI101513
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: COC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing

mist.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location. Store in a well ventilated area. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Use Viton or 4H gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SGA-V

Page 2 of 6

HESI101514
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White, opaque

Odor: Mild hydrocarbon

pH: 6-8 (5% IPA/water)

Specific Gravity @ 20 C (Water=1): 1.028-1.04

Density @ 20 C (lbs./gallon): 8.56-8.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -20

Freezing Point/Range (C): -28.9

Vapor Pressure @ 20 C (mmHg): 15.7

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 1000-2000

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sodium. Carbon monoxide and carbon dioxide. Oxides of sulfur.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye and skin contact.

Inhalation May cause respiratory irritation. If heated: May cause central nervous system

depression including headache, dizziness, drowsiness, incoordination, slowed

reaction time, slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

SGA-V

Page 3 of 6

HESI101515
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

SGA-V

Page 4 of 6

HESI101516
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

SGA-V

Page 5 of 6

HESI101517
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SGA-V

Page 6 of 6

HESI101518
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SILICA FLOUR - SSA-1

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SILICA FLOUR - SSA-1

Synonyms: None

Chemical Family: Sand

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

SILICA FLOUR - SSA-1

Page 1 of 6

HESI101519
Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

SILICA FLOUR - SSA-1

Page 2 of 6

HESI101520
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.63

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 70

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.09

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SILICA FLOUR - SSA-1

Page 3 of 6

HESI101521
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SILICA FLOUR - SSA-1

Page 4 of 6

HESI101522
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SILICA FLOUR - SSA-1

Page 5 of 6

HESI101523
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SILICA FLOUR - SSA-1

Page 6 of 6

HESI101524
SINTER BLAST

Chemical Characteristic Mineralogical Characteristic

Al2O3 (Aluminum Oxide)........ 76,1% Corundum, alfa-Al2O3

SiO2 (Silicon Dioxide)........... 4,40% Hematite, alfa-Fe2O3

TiO2 (Titanium Dioxide)........ 1,40% Maghemite, Fe2O3

Fe2O3 (Iron Oxide)................ 15,4%

CaO (Calcium Oxide)........... 1,55%

K2O (Potassium Oxide) ......... 0,20%

Sieve Analysis (%)

#8/16 #12/20 #20/40 #30/70 #60/120 #120/180G

#6 0

#8 0,6 0

#12 49,7 0,5

#16 45,6 57,6 0

#20 3,9 39,4 0,5

#30 2,3 58,3 0

#40 39,3 3,3

#50 1,7 0,5

#60 89,9 0,8

#70 5,4 14,8

#80 32,8 0,1

#100 1,1 1,0

#120 46,3

#140 50,2

#170 4,1 33,9

#230 13,2

Finos 0,2 0,2 0,2 0,3 0,7 1,6

Physical Characteristics

Bulk Density (g/cm3) 2,01 2,02 2,07 1,99 1,83 1,70

HESI101525
HESI101526
HESI101527
HESI101528
HESI101529
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Sintered Bauxite

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Sintered Bauxite

Synonyms: None

Chemical Family: Inorganic

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Iron oxide 1332-37-2 3-25 Not applicable 10 mg/m3

Titanium dioxide 13463-67-7 1-3 10 mg/m3 15 mg/m3

Aluminum oxide 1344-28-1 30-75 10 mg/m3 10 mg/m3

Silica, amorphous - fumed 7631-86-9 2-9 2 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

Sintered Bauxite

Page 1 of 5

HESI101530
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Gray

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.35

Density @ 20 C (lbs./gallon): Not Determined

Sintered Bauxite

Page 2 of 5

HESI101531
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): 99.8

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Coughing, chest pains, and breathing difficulty may occur.

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Eye ailments.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure to dust may cause pneumoconiosis, a lung disease

caused by inhaling dust particles less than 0.5 micrometers into the lungs.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Sintered Bauxite

Page 3 of 5

HESI101532
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Sintered Bauxite

Page 4 of 5

HESI101533
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Sintered Bauxite

Page 5 of 5

HESI101534
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SODIUM NITRITE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SODIUM NITRITE

Synonyms: None

Chemical Family: Nitrite

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium nitrite 7632-00-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

effect the blood's ability to carry oxygen. Oxidizer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SODIUM NITRITE

Page 1 of 6

HESI101535
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Explodes when exposed to high temperatures,

cyanides, organic materials or friction. Decomposition in fire may produce toxic

gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 3

HMIS Ratings: Health 2, Flammability 0, Reactivity 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust. Use only

competent persons for cleanup.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Flush area with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Avoid dust

accumulations.

Storage Information Store away from combustibles. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection HEPA Respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to light straw

SODIUM NITRITE

Page 2 of 6

HESI101536
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: 9

Specific Gravity @ 20 C (Water=1): 2.16

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 92.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 46

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 69

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Organic matter. All flammables, especially petroleum products, asphalt & other

volatile flammables. Ammonium compounds. Cyanides.

Hazardous Decomposition

Products

Oxides of nitrogen. Caustic soda. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May reduce the blood's ability to transport oxygen

(methemaglobinemia).

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May reduce the blood's ability to transport oxygen (methemalobinemia).

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 85 mg/kg (Rat)

SODIUM NITRITE

Page 3 of 6

HESI101537
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1500,Sodium Nitrite, 5.1, (6.1), III

RQ (Sodium Nitrite - 45.4 kg.)

NAERG 140

Canadian TDG

Sodium Nitrite, 5.1, (6.1), UN1500, III

ADR

UN1500,Sodium Nitrite, 5.1, (6.1), III

Air Transportation

SODIUM NITRITE

Page 4 of 6

HESI101538
ICAO/IATA

UN1500,Sodium Nitrite, 5.1, (6.1), III

RQ (Sodium Nitrite - 45.4 kg.)

Sea Transportation

IMDG

UN1500,Sodium Nitrite, 5.1, (6.1), III

RQ (Sodium Nitrite - 45.4 kg.)

EmS F-A, S-Q

Other Shipping Information

Labels: Oxidizer

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Sodium Nitrite//7632-00-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 100 Pounds based on Sodium nitrite (CAS: 7632-

00-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

SODIUM NITRITE

Page 5 of 6

HESI101539
WHMIS Hazard Class C Oxidizing Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SODIUM NITRITE

Page 6 of 6

HESI101540
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SP BREAKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SP BREAKER

Synonyms: None

Chemical Family: Oxidant

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium persulfate 7775-27-1 60 - 100% 0.1 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause allergic skin and respiratory reaction. May cause eye irritation. Oxidizer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SP BREAKER

Page 1 of 6

HESI101541
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 1

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust

accumulations.

Storage Information Store away from combustibles. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

SP BREAKER

Page 2 of 6

HESI101542
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 6

Specific Gravity @ 20 C (Water=1): 2.47

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 84.3

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 35

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 238.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with readily oxidizable materials.

Incompatibility (Materials to

Avoid)

Avoid halogens. Contact with acids. Strong alkalis. Combustible materials.

Hazardous Decomposition

Products

Oxides of sulfur. Oxygen. Sulfuric acid.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction.

Skin Contact May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 895 mg/kg (Rat)

Dermal Toxicity: LD50: > 10000 mg/kg (Rabbit)

SP BREAKER

Page 3 of 6

HESI101543
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1505,Sodium Persulfate, 5.1, III

NAERG 140

Canadian TDG

Sodium Persulfate, 5.1, UN1505, III

ADR

UN1505,Sodium Persulfate, 5.1, III

Air Transportation

ICAO/IATA

SP BREAKER

Page 4 of 6

HESI101544
UN1505,Sodium Persulfate, 5.1, III

Sea Transportation

IMDG

UN1505,Sodium Persulfate, 5.1, III

EmS F-A, S-Q

Other Shipping Information

Labels: Oxidizer

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class C Oxidizing Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

SP BREAKER

Page 5 of 6

HESI101545
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SP BREAKER

Page 6 of 6

HESI101546
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SPACER-SPERSE WETTING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SPACER-SPERSE WETTING AGENT

Synonyms: None

Chemical Family: Lignosulfonate

Application: Spacer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Modifed lignosulfonate 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

SPACER-SPERSE WETTING AGENT

Page 1 of 5

HESI101547
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Mild

pH: 9.5-10.5

Specific Gravity @ 20 C (Water=1): 1.25

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 27.1

SPACER-SPERSE WETTING AGENT

Page 2 of 5

HESI101548
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

SPACER-SPERSE WETTING AGENT

Page 3 of 5

HESI101549
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(28 Day): 33.37% of COD Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 160-320 mg/l (Oncorhynchus mykiss) TLM48: 19.8 mg/l (Arcatia tonsa)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: E(B)C50: 1.6 mg/l (Skeletonema costatum) E(R)C50: 2.4 mg/l (Skeletonema

costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

SPACER-SPERSE WETTING AGENT

Page 4 of 5

HESI101550
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SPACER-SPERSE WETTING AGENT

Page 5 of 5

HESI101551
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SPERSE-ALL M

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SPERSE-ALL M

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated nonylphenol 60 - 100% Not applicable Not applicable

Methanol 67-56-1 5 - 10% 200 ppm 200 ppm (S)

Ethylene glycol 107-21-1 5 - 10% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. May cause blindness. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

SPERSE-ALL M

Page 1 of 6

HESI101552
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 134

Flash Point/Range (C): 56

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperatures between 50 and 100 F (10 and 37.8

C). Do not freeze. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SPERSE-ALL M

Page 2 of 6

HESI101553
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Water white

Odor: Bland

pH: 6-8

Specific Gravity @ 20 C (Water=1): 1.04

Density @ 20 C (lbs./gallon): 8.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 23

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause severe skin irritation.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion May be fatal or cause blindness if swallowed. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Lung disorders.

SPERSE-ALL M

Page 3 of 6

HESI101554
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity. May contain ethylene oxide in the headspace of the

drum. Ethylene oxide is a cancer and reproductive hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (34 C)

NAERG 128

SPERSE-ALL M

Page 4 of 6

HESI101555
Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol), 3, UN1993, III, (34 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (34 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethoxylated Nonylphenol (9016-45-9)

Methanol//67-56-1

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 8248 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

SPERSE-ALL M

Page 5 of 6

HESI101556
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SPERSE-ALL M

Page 6 of 6

HESI101557
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SSA-2

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SSA-2

Synonyms: None

Chemical Family: Sand

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 60 - 100% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

SSA-2

Page 1 of 6

HESI101558
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Product has a shelf

life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

SSA-2

Page 2 of 6

HESI101559
Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.65

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 95.2

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

SSA-2

Page 3 of 6

HESI101560
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause mechanical irritation to eye.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

SSA-2

Page 4 of 6

HESI101561
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

SSA-2

Page 5 of 6

HESI101562
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SSA-2

Page 6 of 6

HESI101563
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SSO-21M WINTERIZED

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SSO-21M WINTERIZED

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated nonylphenol 30 - 60% Not applicable Not applicable

Ethylene glycol monobutyl

ether

111-76-2 10 - 30% 20 ppm 50 ppm

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. May cause blindness. May cause damage to internal organs.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

SSO-21M WINTERIZED

Page 1 of 6

HESI101564
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 110

Flash Point/Range (C): 43

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Ground and bond containers when

transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperatures between 50 and 100 F (10 and 37.8

C). Do not freeze. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

SSO-21M WINTERIZED

Page 2 of 6

HESI101565
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Mild

pH: 5 - 7 (10%)

Specific Gravity @ 20 C (Water=1): 0.975 - 0.995

Density @ 20 C (lbs./gallon): 8.12 - 8.29

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause corneal injury. May cause eye burns.

SSO-21M WINTERIZED

Page 3 of 6

HESI101566
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

SSO-21M WINTERIZED

Page 4 of 6

HESI101567
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (33.9 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol), 3, UN1993, III, (33.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (33.9 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethoxylated Nonylphenol (9016-45-9)

Methanol//67-56-1

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 12100 Gallons based on Ethylene glycol (CAS: 107-

21-1). EPA Reportable Spill Quantity is 5790 Gallons based on Methanol (CAS: 67-

56-1)

SSO-21M WINTERIZED

Page 5 of 6

HESI101568
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SSO-21M WINTERIZED

Page 6 of 6

HESI101569
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SUPER HS BAUXITE (20-40 Mesh)

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SUPER HS BAUXITE (20-40 Mesh)

Synonyms: None

Chemical Family: Resin coated bauxite

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phenol / formaldehyde resin 9003-35-4 1 - 5% Not applicable Not applicable

Aluminum silicate 1302-76-7 30 - 60% Not applicable 15 mg/m3

Aluminum oxide 1344-28-1 60 - 100% 10 mg/m3 10 mg/m3

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation. May cause allergic skin and respiratory

reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

SUPER HS BAUXITE (20-40 Mesh)

Page 1 of 7

HESI101570
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use.

SUPER HS BAUXITE (20-40 Mesh)

Page 2 of 7

HESI101571
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Black

Odor: Resin

pH: 7.5

Specific Gravity @ 20 C (Water=1): 3.25

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 119

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials. Amorphous silica may

transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

SUPER HS BAUXITE (20-40 Mesh)

Page 3 of 7

HESI101572
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause a rash and itching of the skin.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

SUPER HS BAUXITE (20-40 Mesh)

Page 4 of 7

HESI101573
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

SUPER HS BAUXITE (20-40 Mesh)

Page 5 of 7

HESI101574
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

SUPER HS BAUXITE (20-40 Mesh)

Page 6 of 7

HESI101575
***END OF MSDS***

SUPER HS BAUXITE (20-40 Mesh)

Page 7 of 7

HESI101576
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SUPERFLO III SURFACTANT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SUPERFLO III SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 1 - 5% 100 mg/m3 50 ppm

Hexylene glycol 107-41-5 10 - 30% 25 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May cause birth defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Ethanol should be given intravenously, as a 5% solution in sodium bicarbonate at a

rate of about 10 ml ethanol per hour to desired therapeutic level of 100 mg/l.

Hemodialysis may be required. The patient should be monitored for metabolic

acidosis.

SUPERFLO III SURFACTANT

Page 1 of 6

HESI101577
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 200

Flash Point/Range (C): 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Slight

SUPERFLO III SURFACTANT

Page 2 of 6

HESI101578
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 5.2

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 212

Boiling Point/Range (C): Not DeterminedMin: > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Slightly soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe skin irritation.

Eye Contact May cause eye burns. May cause permanent eye damage.

Ingestion May cause kidney damage. May affect the heart and cardiovascular system. May

cause brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause reproductive system damage. Prolonged

or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

SUPERFLO III SURFACTANT

Page 3 of 6

HESI101579
Oral Toxicity: LD50: 6135 mg/kg (Rat)

Dermal Toxicity: LD50: 20 ml/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 0.010-0.100 ml/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

SUPERFLO III SURFACTANT

Page 4 of 6

HESI101580
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3924 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

SUPERFLO III SURFACTANT

Page 5 of 6

HESI101581
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SUPERFLO III SURFACTANT

Page 6 of 6

HESI101582
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SUPERSET O

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SUPERSET O

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated nonylphenol 10 - 30% Not applicable Not applicable

Naphtha, heavy catalytic

reformed

64741-68-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Potential carcinogen. May be harmful if

swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SUPERSET O

Page 1 of 6

HESI101583
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 104

Flash Point/Range (C): 40

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1

Flammability Limits in Air - Upper (%): 7

Flammability Limits in Air - Upper (oz./ft3): 7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Avoid spraying water directly into storage containers due to danger of

boilover.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

SUPERSET O

Page 2 of 6

HESI101584
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Straw

Odor: Aromatic hydrocarbon

pH: 8

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.5

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 300

Boiling Point/Range (C): 149

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

SUPERSET O

Page 3 of 6

HESI101585
Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals. May contain ethylene oxide in the headspace of the drum.

Ethylene oxide is a cancer and reproductive hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (40 C)

(Contains Petroleum Naphtha)

NAERG 128

Canadian TDG

SUPERSET O

Page 4 of 6

HESI101586
Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, UN1993, III, (40 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Petroleum Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Petroleum Naphtha), 3, III, (40 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethoxylated Nonylphenol (9016-45-9)

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

SUPERSET O

Page 5 of 6

HESI101587
WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SUPERSET O

Page 6 of 6

HESI101588
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: SUPERSET W

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: SUPERSET W

Synonyms: None

Chemical Family: Blend

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethoxylated nonylphenol 30 - 60% Not applicable Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. May cause blindness. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

SUPERSET W

Page 1 of 6

HESI101589
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 58

Flash Point/Range (C): 14

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 7

Flammability Limits in Air - Upper (%): 36

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Ground and bond containers when

transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

SUPERSET W

Page 2 of 6

HESI101590
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to slightly hazy amber

Odor: Alcohol

pH: 8

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.5

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 149

Boiling Point/Range (C): 65

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 100

Vapor Density (Air=1): > 1

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): < 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause severe skin irritation. May cause a rash and itching of the skin.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May be fatal or cause blindness if swallowed. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Lung disorders.

SUPERSET W

Page 3 of 6

HESI101591
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. May contain ethylene oxide in the

headspace of the drum. Ethylene oxide is a cancer and reproductive hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Methanol Solution, 3, UN1230, II, (14.4 C)

NAERG 131

Canadian TDG

Methanol Solution, 3, UN1230, II, (14.4 C)

SUPERSET W

Page 4 of 6

HESI101592
ADR

UN1230,Methanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1230,Methanol Solution, 3, II

Sea Transportation

IMDG

UN1230,Methanol Solution, 3, II, (14.4 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Ethoxylated Nonylphenol (9016-45-9)

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1319 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

SUPERSET W

Page 5 of 6

HESI101593
WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

SUPERSET W

Page 6 of 6

HESI101594
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: TARGON II ASPHALT SOLVENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TARGON II ASPHALT SOLVENT

Synonyms: None

Chemical Family: Solvent

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

n-Methylpyrrolidone 872-50-4 60 - 100% 10 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

TARGON II ASPHALT SOLVENT

Page 1 of 6

HESI101595
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 199

Flash Point/Range (C): 92

Flash Point Method: Not Determined

Autoignition Temperature (F): 518

Autoignition Temperature (C): 270

Flammability Limits in Air - Lower (%): 1.3

Flammability Limits in Air - Upper (%): 9.5

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store away from reducing agents. Store in a cool well

ventilated area. Keep container closed when not in use. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

TARGON II ASPHALT SOLVENT

Page 2 of 6

HESI101596
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Mild amine

pH: 8.5

Specific Gravity @ 20 C (Water=1): 1.02

Density @ 20 C (lbs./gallon): 8.50

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 395

Boiling Point/Range (C): 201

Freezing Point/Range (F): -75

Freezing Point/Range (C): -60

Vapor Pressure @ 20 C (mmHg): 0.29

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 99

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Reducing agents. Violent, explosive reaction with sulfur trioxide,

decaborane, silver perchlorate, triethenyl aluminum, and hydrogen in presence of

nickel catalyst at temperatures above 200 C.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

TARGON II ASPHALT SOLVENT

Page 3 of 6

HESI101597
Toxicity Tests

Oral Toxicity: LD50: 7000 mg/kg (Rat)

Dermal Toxicity: LD50: 8000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: EC50: 43 ppm (Abra alba) TLM24: 832 mg/l (Lepomis macrochirus) TLM96: 1072

mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

TARGON II ASPHALT SOLVENT

Page 4 of 6

HESI101598
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

n-Methylpyrrolidone//872-50-4

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

TARGON II ASPHALT SOLVENT

Page 5 of 6

HESI101599
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TARGON II ASPHALT SOLVENT

Page 6 of 6

HESI101600
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: TBA-110 BRIDGING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: TBA-110 BRIDGING AGENT

Synonyms: None

Chemical Family: Inorganic Salt

Application: Bridging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

TBA-110 BRIDGING AGENT

Page 1 of 5

HESI101601
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media None - does not burn.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 7

Specific Gravity @ 20 C (Water=1): 2.17

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 92.5

TBA-110 BRIDGING AGENT

Page 2 of 5

HESI101602
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 36

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 58.5

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

TBA-110 BRIDGING AGENT

Page 3 of 5

HESI101603
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

TBA-110 BRIDGING AGENT

Page 4 of 5

HESI101604
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

TBA-110 BRIDGING AGENT

Page 5 of 5

HESI101605
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: THERMAPAC MATERIAL

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: THERMAPAC MATERIAL

Synonyms: None

Chemical Family: Sand

Application: Steam Resistant Gravel

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

Almandite and pyrope garnet 1302-62-1 60 - 100% 10 mg/m3 Not applicable

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

THERMAPAC MATERIAL

Page 1 of 7

HESI101606
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Treat symptomatically.

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use. Do not reuse empty container.

THERMAPAC MATERIAL

Page 2 of 7

HESI101607
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Gray white to green

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.9-4.1

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 168

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

THERMAPAC MATERIAL

Page 3 of 7

HESI101608
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mechanical skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

THERMAPAC MATERIAL

Page 4 of 7

HESI101609
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

THERMAPAC MATERIAL

Page 5 of 7

HESI101610
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

THERMAPAC MATERIAL

Page 6 of 7

HESI101611
THERMAPAC MATERIAL

Page 7 of 7

HESI101612