## Cover Letter

Dear PMN Reviewer, Our new substance's trade name is CPAR LCCO. To complete this PMN for CPAR LCCO, which is IES name Alkanes, C24-28, chloro, CAS 140-2738-52-6, we have relied on publicly available data for the analog Long-Chain Chlorinated Paraffin (LCCP), primarily C>20, because we do not possess or control test data for CPAR LCCO.

Page 1 NON-CBI SUBMISSION

### 74377735868 258K4BLR CPAR121114109473956 RP3DS3

X X X X X X

X

Page 2 NON-CBI SUBMISSION

### X

Page 3 NON-CBI SUBMISSIONKaren Messana EHS & Regulatory Compliance Mgr Trinity Manufacturing, Inc. PO Box 1519 Hamlet NC 28345 kmessana@trinitymfg.com

Jim MacNeil Product Manager Trinity Manufacturing, Inc. PO Box 1519 Hamlet NC 28345 jmacneil@trinitymfg.com 910-331-4733



## X X X X

Page 4 NON-CBI SUBMISSION

## X

Alkanes, C24-28, chloro

1402738-52-6 

## X 325322 CAS IES CPAR LCCO.pdf 

### CnH2n+2-yCly n=24-28 See Attachment 002 (Structural Formula Diagram CPAR LCCO.docx)

Structural Formula Diagram CPAR LCCO.docx Page 5 NON-CBI SUBMISSIONAlpha Olefins C24-28 CAS 93924-11-9

Chlorine CAS 7782-50-5

The Alpha Olefin C24-28 is treated with chlorine gas. The chlorine replaces hydrogen atoms in a substitution reaction. The chlorine also adds across the olefin functional group. CnH2n+ Cl2------> CnH2n+2-yCly + HCl n=24-28

40 to 52% by weight chlorine

Page 6 NON-CBI SUBMISSIONPage 7 NON-CBI SUBMISSIONPage 8 NON-CBI SUBMISSIONLCCO

Long Chain Chlorinated Olefin

CPAR Expoxidized Soybean Oil 8013-07-8 1.0

Hydrochloric Acid 7647-01-0 Sodium Hypochlorite 7681-52-9

Page 9 NON-CBI SUBMISSION

### 500000 1000000



## X

Flame Retardant in Rubber Products 80 99 0 0 100 0

Extreme Pressure Additive in Lubricants 20 99 0 0 100 0

Page 10 NON-CBI SUBMISSION

## X

20000 24 150 

## 1

CPAR manufacturing process: The alpha olefin feedstock is charged into the chlorination reactor. Chlorine gas is bubbled through the mixture. The chlorine reacts with the alpha olefin to produce the CPAR in a substitution reaction. Unreacted chlorine is captured by a caustic scrubber to make commercial grade bleach. Byproduct HCl gas is captured by water scrubber to make commercial grade hydrochloric acid. No cleanouts are required in between batches. The CPAR will be shipped in bulk by tank truck. New substance entrained in the hydrochloric acid is removed by phase separation, then loaded into one tote per year (estimated), which is then incinerated off-site. The hydrochloric acid is filtered through carbon to remove any residual new substance. The spent carbon is subsequently disposed of in RCRA Class D landfill for non-hazardous waste. Trinity Manufacturing, Inc. PO Box 1519 Hamlet Richmond NC 28345-8821

Page 11 NON-CBI SUBMISSIONSee Attachment 003 (Process Diagram for CPAR LCCO.xlsx)

Process Diagram for CPAR LCCO.xlsx Page 12 NON-CBI SUBMISSIONLoading Trucks Safety glasses, Nitrile gloves Liquid 100% 3 1 100 Filling Totes Safety glasses, Nitrile gloves Liquid 100% 3 1 100 Sampling Safety glasses, Nitrile gloves Liquid 100% 3 0.25 100

Page 13 NON-CBI SUBMISSION1 7.2 kg/batch Off-site Incineration
2 3.0

kg/batch Other: Landfill - RCRA Subtitle D

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### 6

See Attachment 004 (Process Diagram for Lubricant Compounding.xlsx)

Process Diagram for Lubricant Compounding.xlsx CPAR is shipped to customers in cargo trailer tank trucks. Tanks are not cleaned between uses. The customers compound CPAR into lubricants for a wide variety of uses. Used lubricant oils are typically recycled.

Page 15 NON-CBI SUBMISSIONP10SB1(a)(4)1 Part II, Section B, 1(a)(4). Operation Site Locations

Harvey, IL Cleveland, OH Mantua, NJ Crytal Lake, IL Perrysburg, OH Chicago, IL

Page 16 NON-CBI SUBMISSIONA 6 0.5 75 Safety glasses, nitrile gloves Liquid B 6 0.5 75 Safety glasses, Nitrile gloves Liquid C 20 4.0 120 Safety glasses, Nitrile gloves Liquid 99 15

Page 17 NON-CBI SUBMISSION

### 5

See Attachment 005 (Process Diagram for Rubber Compounding.xlsx)

Process Diagram for Rubber Compounding.xlsx CPAR is shipped to customers in cargo trailer tank trucks. Tanks are not cleaned between uses. The customers compound CPAR into rubber for several uses.

Page 18 NON-CBI SUBMISSIONP10SB1(a)(4)2 Part II, Section B, 1(a)(4). Operation Site Locations

Mebane, NC Youngsville, NC Marysville, OH Calhoun, GA St. Mary's, OH

Page 19 NON-CBI SUBMISSIONA 5 0.5 75 Safety glasses, Nitrile gloves Liquid

Page 20 NON-CBI SUBMISSIONProduct Substitution:

LCCO's are a substitute for SCCP's which have a higher toxicity. LCCO's may be a replacement for phthalates in rubber compounding. Phthalates are suspected endocrine disruptors. Automation: The process is highly automated, helping to prevent off spec product thereby reducing the potential for waste generation. Examples include automated temperature control loops, level controls, raw material addtion and inline continuous analytical instrumentation. Loss prevention: Overflow alarms on all vessels activate interlocks through Distributive Control System (DCS) to automatically close inlet valves. Material handling improvements: Product will be shipped in tank truck to minimize packaging waste and release of residue Production Scheduling: Each batch makes one tank truck of product. The result is a reduction in the number of batches required. Safety: All sample points will have closed sample valves reducing worker exposure and sampling waste. Reclamation: All samples including expired retains will be returned to the process/product. The collection container does not need to be cleaned between uses. Process location: The manufacturing equipment is located indoors and in contained dikes. All tank truck loading and raw material unloading activies are conducted in contained areas.

Page 21 NON-CBI SUBMISSION001 CAS IES CPAR LCCO CAS IES CPAR LCCO.pdf Pt.I, Sec.B, 1c. 2 002 Structural Formula Diagram CPAR LCCO Structural Formula Diagram CPAR LCCO.docx Pt.I, Sec.B, 1e. 1 003 Process Diagram for CPAR LCCO Process Diagram for CPAR LCCO.xlsx Pt.2, Sec.A, 1d. 1 004 Process Diagram for Lubricant Compounding Process Diagram for Lubricant Compounding.xlsx Pt.2, Sec.B, 1a. 1 005 Process Diagram for Rubber Compounding Process Diagram for Rubber Compounding.xlsx Pt.2, Sec.B, 1a. (#2) 1 006 CPAR LCCO SDS CPAR LCCO W50AO W40AO Qualice SDS 11-14-12.pdf 0 007 Canadian 2008 Report Chlorinated Paraffins Canadian 2008 Report Chlorinated Paraffins.pdf 78 008 Canadian May 2012 Update on Human Health Assessment of LCCP Canadian May 2012 Update on Human Health Assessment of 10 009 United Kingdom Environmental Risk Assessment LCCP Jan 2009 United Kingdom Environmental Risk Assessment LCCP Jan 360

Page 22 NON-CBI SUBMISSION

## X Measured 9.375771e-7 Estimate 25 1.20 Measured

< 0.000005 Estimate 20

10.3 Estimate

1.2 Measured Specific gravity
Page 23 NON-CBI SUBMISSIONFlash Point > 450 F ( 232 C) Measured Viscosity, Poise @ 77 F 110 Measured

Page 24 NON-CBI SUBMISSION

## ATTACHMENT HEADER SHEET Attachment Number 001 Attachment Name CAS IES CPAR LCCO 

## Associated PMN Section Number

Pt.I, Sec.B, 1c. Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 002 Attachment Name Structural Formula Diagram CPAR LCCO 

## Associated PMN Section Number

Pt.I, Sec.B, 1e. Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 003 Attachment Name Process Diagram for CPAR LCCO 

## Associated PMN Section Number

Pt.2, Sec.A, 1d. Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 004 Attachment Name Process Diagram for Lubricant Compounding 

## Associated PMN Section Number

Pt.2, Sec.B, 1a. Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 005 Attachment Name Process Diagram for Rubber Compounding 

## Associated PMN Section Number

Pt.2, Sec.B, 1a. (#2) Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 006 Attachment Name CPAR LCCO SDS 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 007 Attachment Name Canadian 2008 Report Chlorinated Paraffins 

## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 008 Attachment Name Canadian May 2012 Update on Human Health Assessment of LCCP



## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number CPAR121114109473956

## ATTACHMENT HEADER SHEET Attachment Number 009 Attachment Name United Kingdom Environmental Risk Assessment LCCP Jan 2009



## Associated PMN Section Number

N/A Does not contain CBI 

## Report Number CPAR121114109473956