STATE OF ARIZONA

STATE IMPLEMENTATION PLAN (SIP) REVISION

APPENDIX 2

1993 RULE-MAKING COMPRISED OF ARTICLES 6,7, & 8

JULY 15, 1998STATEOFARIZONASIPREVISION-JULY15,1998ARTICLE 4.ARTICLE 6. EMISSIONS FROM EXISTING AND NEW NONPOINT

SOURCES R18-2-4016ji1. General

For purposes of this Article, any source of air contaminants which due to lack of an identifiable

emission point or plume cannot be considered a point source, shall be classified as a nonpoint

source. In applying this criteria, such items as air-curtain destructors, heater-planners, and

conveyor transfer points shall be considered to have identifiable plumes. Any affected facility

subject to regulation under Article 2 of this Chapter or A.A.C Title 9, Chapter 3, Article 8,

shall not be subject to regulation under this Article.

R18-2-4O2j. Unlawful open burning No change

R18-2-4O36j. Forestry management No change

R18-2-4046ji4. Open areas, dry washes or riverbeds

A. No person shall cause, suffer, allow, or permit a building or its appurtenances, or a

building or subdivision site, or a driveway, or a parking area, or a vacant lot or sales lot,

or an urban or suburban open area to be constructed, used, altered, repaired, demolished,

cleared, or leveled, or the earth to be moved or excavated, without taking reasonable

precautions to limit excessive amounts of particulate matter from becoming airborne.

Dust and other types of air contaminants shall be kept to a minimum by good modem

practices such as using an approved dust suppressant or adhesive soil stabilizer, paving,

covering, landscaping, continuous wetting, detouring, barring access, or other acceptable

means.

B. No person shall cause, suffer, allow, or permit a vacant lot, or an urban or suburban open

area,

to be driven over or used by motor vehicles, trucks, cars, cycles, bikes, or buggies,

or by animals such as horses, without taking reasonable precautions to limit excessive

amounts of particulates from becoming airborne. Dust shall be kept to a minimum by

using an approved dust suppressant, or adhesive soil stabilizer, or by paving, or by

barring access to the property, or by other acceptable means.

C.

No person shall operate a motor vehicle for recreational purposes in a dry wash, riverbed

or open area in such a way as to cause or contribute to visible dust emissions which then

cross property lines into a residential, recreational, institutional educational, retail sales,

hotel or business premises. For purposes of this subsection “motor vehicles” shall

include, but not be limited to trucks, cars, cycles, bikes, buggies and three-wheelers. Any

person who violates the provisions of this subsection shall be subject to prosecution under

A.R.S. § 49-454. R18-2-4O5. Roadways and streets No change

R18-2-4O6Q. Material handling No change

R18-2-4O-7.Q7. Storage piles No change

R18-2-4O86Ji. Mineral tailings No change

R1824O9. Agricultural practices No change

R18-2-41Gj. Evaluation of nonpoint source emissions

Opacity of an emission from any nonpoint source shall not be greater than 40 percent measured

in accordance with the Arizona Testing Manual, Reference Method 9. Open fires permitted

under Ri 8-2-40 and Ri 8-2-4O3- are exempt from this requirement.

1ARTICLE5ARTICLE7.EXISTINGSTATIONARYPOINTSOURCEPERFORMANCESTANDARDSR18-2-501701.DefinitionsForpurposesofthisArticle:L“Acidmist”meanssulfuricacidmistasmeasuredintheArizonaTestingManualand40CFR60.AppendixA.2“Architecturalcoating”meansacoatingusedcommerciallyorindustriallyforresidential,commercialorindustrialbuildingsandtheirappurtenances:structuralsteel:andotherfabricationssuchasstoragetanics.bridges,beamsandgirders.“Asphaltconcreteplant”meansanyfacilityusedtomanufactureasphaltconcretebyheatinganddryingaggregateandmixingwithasphaltcements.Thisislimitedtofacilities.includingdrumdryerplantsthatintroduceasphaltintothedryer.whichemploytwoormoreofthefollowingprocesses:a.Adryer.Systemsforscreening.handling,storing,andweighinghotaggregate.Systemsforloading.transferring,andstoringmineralfiller.Systemsformixingasphaltconcrete.Theloading.transferring,andstoragesystemsassociatedwithemissioncontrolsystems.“Blackliquor”meanswasteliquorfromthebrownstockwasherandspentcookingliquorwhichhavebeenconcentratedinthemultiple-effectevaporatorsystem.“Calcine”meansthesolidmaterialsproducedbyalimeplant.“Concentrate”meansenrichedcopperorerecoveredfromthefrothflotationprocess.“Concentratedryer”meansanyfacilityinwhichacoppersulfideoreconcentratechargeisheatedinthepresenceofairtoeliminateaportionofthemoisturefromthecharge.providedlessthanfivepercentofthesulfurcontainedinthechargeiseliminatedinthefacility.&“Concentrateroaster”meansanyfacilityinwhichacoppersulfideoreconcentrateisheatedinthepresenceofairtoeliminatefivepercentormoreofthesulfurcontainedinthecharge.“Condensatestrippersystem”meansacolumn,andassociatedcondensers,usedtostrip,withairorsteam.TRScompoundsfromcondensatestreamsofvariousprocesseswithinakraftpulpmill.iQ“Controldevice”meanstheairpollutioncontrolequipmentusedtoremoveparticulatematterorgasesgeneratedbyaprocesssourcefromtheeffluentgasstream.jj“Converter”meansanyvesseltowhichcoppermatteischargedandoxidizedtocopper.i2“Facility”meansanidentifiablepieceofstationaryprocessequipmentalongwithallassociatedairpollutionequipment.3j“Fugitivedust”meansfugitiveemissionsofparticulatematter.ii“Highsulfuroil”meansfueloilcontaining0.90percentormorebyweightof2sulfur.ji“Limekiln”meansaunitusedtocalcinatelimerockorkraftpulpmilllimemudwhich_consistsprimarilyofcalciumcarbonate.intoquicklime,whichiscalciumoxide.ij“Lowsulfuroil”meansfueloilcontaininglessthan0.90percentbyweightofsulfur.ji.“Matte”meansametallicsulfidemadebysmeltingcoppersulfideoreconcentrateortheroastedproductofcoppersulfideores.,

IL“Miscellaneousmetalpartsandproducts”forpurposesofindustrialcoatingincludeallofthefollowing:Largefarmmachinery,suchasharvesting,fertilizingandplantingmachines.tractors,andcombines.Smallfarmmachinery,suchaslawnandgardentractors,lawnmowers,andrototillers.Smallappliances,suchasfans,mixers.blenders,crockpots.dehumidiflers.andvacuumcleaners.Commercialmachinery,suchasofficeequipment.computersandauxiliaryequipment.typewriters,calculators,andvendingmachines.Industrialmachinery,suchaspumps.compressors.conveyorcomponents.fans.blowers,andtransformers.

LFabricatedmetalproductssuchasmetalcovereddoorsandframes.AnyotherindustrialcategorywhichcoatsmetalpartsorproductsundertheCodeinthe“StandardIndustrialClassificationManual.1987”ofMajorGroup33(primarymetalindustries.MajorGroup34(fabricatedmetalproducts).MajorGroup35(non-electricmachinery).MajorGroup36(electricalmachinery).MajorGroup37(transportationequipment).MajorGroup38(miscellaneousinstruments),andMajorGroup39(miscellaneousmanufacturingindustries),exceptallofthefollowing:j,.Automobilesandlight-dutytrucks.ii.,Metalcans.iii.Flatmetalsheetsandstripsintheformofrollsorcoils.iv.Magnetwireforuseinelectricalmachinery.Metalfurniture.yjLargeappliances.ïü.Exteriorofairplanes.-yjji.Automobilerefinishing.

iCustomizedtopcoatingofautomobilesandtrucks,ifproductionislessthan35vehiclesperday.Exteriorofmarinevessels..ii“Multiple-effectevaporatorsystem”meansthemultiple-effectevaporatorsandassociatedcondenserandhotwellusedtoconcentratethespentcookingliquidthatisseparatedfromthepulp.“Neutralsulfitesemichemicalpulping”meansanyoperationinwhichpulpisproducedfromwoodbycookingordigestingwoodchipsinasolutionofsodiumsulfiteandsodiumbicarbonate.followedbymechanicaldefibratingorgrinding.3

# 2.L ‘Petroleum liquids” means petroleum. condensate. and any finished or

intermediate products manufactured in a petroleum refinery, but does not mean Number 2

through Number 6 fuel oils as specified in AS1’M D-396-90a (Specification for Fuel Oils), gas

turbine fuel oils Numbers 2-GT through 4-GT as specified in ASTM D-2880-90a (Specification

for Gas Turbine Fuel Oils) or diesel fuel oils Numbers 2-D and 4-D as specified in ASTM D

Li 975-90.(Specification for Diesel Fuel Oils.

22 “Process source” means the last operation or process which produces an air

contaminant resulting from either:.

The separation of the air contaminants from the process material, or

The

conversion of constituents of the process materials into air contaminants

which is not an air pollution abatement operation.

21 “Process weight” means the total weight of all materials introduced into a process

source,

including fuels. where these contribute to pollution generated by the process.

24

“Process weight rate” means a rate established pursuant to Ri 8-2-5O7O2E.

2. “Recovery furnace” means the unit, including the direct-contact evaporator for a

conventional furnace, used for burning black liquor to recover chemicals consisting primarily of

sodium carbonate and sodium sulfide.

“Reid vapor pressure” means the absolute vapor pressure of volatile crude oil and

volatile

non-viscous petroleum liquids, except liquified petroleum gases. as determined by

ASTM D-323-90(Test Method for Vapor Pressure of Petroleum Products (Reid Method).

22

“Reverberatory smelting furnace” means any vessel in which the smelting of

copper

sulfide ore concentrates or calcines is performed and in which the heat necessary for

smelting is provided primarily by combustion of a fossil fuel.

2.& “Rotary lime kiln” means a unit with an included rotary drum which is used to

j.



# produce a lime product from limestone by calcination.

22 “Slag” means the fused and vitrified matter separated during the reduction of a

metal

from its ore.

3 “Smelt dissolving tank” means a vessel used for dissolving the smelt collected

from

the kraft mill recovery furnace.

31 “Smelter feed” means all materials utilized in the operation of a copper smelter

including

metals or concentrates, fuels and chemical reagents. calculated as the aggregate sulfur

content

of all fuels and other feed materials whose products of combustion and gaseous by

products are emitted to the atmosphere.

31 “Smelting” means processing techniques for the smelting of a copper sulfide ore

concentrate

or calcine charge leading to the formation of separate layers of molten slag, molten

copper. or copper matte.

31 “Smelting furnace” means any vessel in which the smelting of copper sulfide ore

concentrates

or calcines is performed and in which the heat necessary for smelting is provided by

j an electric current, rapid oxidation of a portion of the sulfur contained in the concentrate as it

passes

through an oxidizing atmosphere. or the combustion of a fossil fuel.

34 “Standard conditions” means a temperature of 293K (68°F or 20°C) and a pressure

j of 101.3 kilopascals (29.92 inches Hg or 1013.25 

# mb).

3j “SuDylementary control system” (SCS) means a sYstem by which sulfur dioxide

4.emissionsarecurtailedduringperiodswhenmeteorologicalconditionsconducivetoground-levelconcentrationsinexcessofambientairqualitystandardsforsulfurdioxideeitherexistorareanticipated.3.“Vaporpressure”meansthepressureexertedbythegaseousformofasubstanceinequilibriumwithitsliquidorsolidform.R18-2-5OZ.Visiblecmissions;gcncralGeneralprovisionsA.TheprovisionsofthisArticleshallonlyapplytoexistingsources.A..ExceptasotherwiseprovidedintheseRule3thisArticlerelatingtospecifictypesofsources,theopacityofanyplumeoreffluentLshallShallnotbegreaterthan40percent.and2.aShallbedeterminedbyreferenceMethod9inthcArizonaTestingManual4QCFR60.AppendixA.B.WherethepresenceofuncombinedwateristheonlyreasonfortheexceedanceofanyvisibleemissionsrequirementinthcscRulcathisArticle,suchexceedanceshallnotconstituteaviolationoftheseRules.C.UponwrittenapplicationtotheDircctor,apersonowningoroperatinganairpollutionsourcemayrcgucstthatavisibleemissionsevaluationbeconductedbytheBureauduringaparticulateemissionstestdemonstratingcompliancewithaparticulateemissionstandard.Thevisibleemissionsopacityduringaparticulateemissiontestdemonstratingcomplianceshall,ifgreaterthantheopacitystandardofSubsectionA.,above,andafternoticeandopportunityforpublichearinginaccordancewith40CFR51.4,serveasthevisibleemissionsstandardforthesource.Suchvisibleemissionsstandardshallbeincorporatedasaconditionoftheoperatingpermitfortheairpollutionsource.PApersonowningoroperatinganairpollutionsourcemayasktheDirectorforadeterminationonmeetingtherequirementsoftheapplicableopacitystandard..LTheowneroroperatorshallsubmitthewrittenreportsoftheresultsoftheperformancetests.theopacityobservationresults,andobservercertification.2..IftheDirectorfindsthatthefacilityisincompliancewithallapplicablestandardsfortheperformancetestandstillfailstomeettheapplicableopacitystandard,heshallnotifytheowneroroperatorofthefinding.TheowneroroperatormaypetitiontheDirectorwithintendaysofreceiptofnotification,askingtheDirectortomakeanappropriateadjustmenttotheopacitystandardforthefacility.TheDirectorshallgrantthepetitionafterpublicnoticeandopportunityforpublichearingtakesplace.anduponademonstrationbytheowneroroperatorthat:Theaffectedfacilityandtheassociatedairpollutioncontrolequipmentwereoperatedandmaintainedinamannertominimizetheopacityofemissionsduringtheperformancetest.TheperformancetestswereperformedundertheconditionsestablishedbytheDirector.Theaffectedfacilityandassociatedairpollutioncontrolequipmentwereincapableofbeingadjustedoroperatedtomeettheapplicableopacityrequirement.TheDirectorshallestablishanopacitystandardfortheaffectedfacilitybasedon5the determination made in Paragraph (4) of this Subsection. The opacity standard shall be set at a

level

indicated by the performance and opacity tests. providing that the source will be able to

meet

the mass or concentration standard and the opacity standard at all times. Such opacity

standard shall be incorporated as a condition of the operating permit for the affected facility.

The Director shall publish the opacity standard once in one or more newspapers of

general circulation in the county or counties concerned.

D. Application of A. and B. of this Section shall bc stayed only with regard to

existing copper smelters until the compliance date specified in 1U8-2-515, in a nonferrous

smelter order, in a consent decree, or in a dclaycd compliance ordet

The process weight rate utilized in this Article shall be determined as follows:

.L For continuous or long run, steady-state process sources, the process weight rate

shall be the total process weight for the entire period of continuous operation or for a typical

portion thereof, divided by the number of hours of such period or portion thereof.

Z For cyclical or batch process sources, the process weight rate shall be the total

process weight for a period which covers a complete operation or an integral number of cycles.

divided by the hours of actual process operation during such period.

1U8-2-502. Unclassfflcd sourcca

A. No existing major source which 13 not otherwise covered under any other Section

of these Rules shall cause or permit the cmission of pollutants at rates greater than the following:

1. No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from any unclassified process source in total quantities in

‘r riftl,r. amounts calculated l,y tlir cquations rt fnrfl, 1,rinw

havin 5 rate of 60,000 per hour (30

r hour) orlc, ...iissions shall be determined by‘“‘

equation:Tt-n, 1-srTflU mrnirniimflhIfl”.?JJ1flIUCrY

mc iouowi

where:— 4.1OPO.67

a similar typ,.

of particulate matter.— the maximum allowable particulate emissions rate in pounds-mass per hour.

P— the process weight in tons-mass pcr hour.

b. For process weight ratc greater than 60,000 pounds per hour (30 tons per hour),

the maximum allowable emissions shall be determined by the following equation:— 55.OPO.ll-40

where “E” and “P” arc defined as indicated in A.l.a. above.

2. For purposes of this Rule, the total process weight from all similar units-, nrocc shall be used in determining the maximum allowable emission

3. For reference only the equations in A.l. above arc plotted in Appendix 11, Figure

2. The emission values obtained from the graph are approximately correct for the process weight

rates shown. however, the actual values shall be calculated from the applicable equations and

rounded off to two decimal places.

4. Sulfar dioxide-- 600 parts per million.

5. Nitrogen oxides expressed as N02-- 500 parts per million.

B. No person shall emit gaseous or odorous materials from equipment, operations or :;

6aif-dricd at temperatures up to l94oF (9OoC);

3. 3.5 pounds per gallon (0.42 kilograms per liter) of coating, excluding water,

delivered to a coating applicator that applics extreme pcrformancc coatings-nnd,

4. 3.0 pounds per gallon (0.36 kilograms per litcr) of coating, cxcluding water,

delivered to a coating applicator for all othcr coatings and coating application sy3tcms.

5. If morc than one emission limitation in this Subsection applies to a specific

coating, thcn thc icast stringent emission limitation shall be applicd.

6. All VOC emissions from solvent washings shall be considered in the emission

limitations in this Subsection, unles3 the solvent is directed into containers that prevent•rnrnrntni,iritt11 atmo3oherC.- R18-2-5O3Z! Standards of performance for existing fossil-fuel fired steam generators and

general fuel burning equipment

A. This Section applies to the following:

L installations Installations in which fuel is burned for the primary purpose of

producing power, steam, hot water, hot air or other liquids, gases or solids and in the course of

doing so the products of combustion do not come into direct contact with process materials.

When any products or by-products of a manufacturing process are burned for the same purpose

or

in conjunction with any fuel, the same maximum emission limitation shall apply, except for

wood waste burners as regulated under Section Ri 8-2-O42Q4.

2 All fossil-fuel fired steam generating units or general fuel burning equipment

whichare greater than or equal to 73 megawatts capacity.

B. For purposes of this Seti’on, the heat input shall be the aggregate heat content of

all fuels whose products of eombut(on pass through a stack or other outlet. The heat content of

solid fuel shall be determined in accordance with Rl 8-2-3-l-OU. Compliance tests shall be

conducted during operation at the nominal rated capacity of each unit. The total heat input of all

fuel-burning units on a. plant or premise shall be used for determining the maximum allowable

amount of gaseous or particulate matter which may be emitted.

C. The provisions of this Section arc applicable to all fossil-fuel fired steam

generating units or general fuel burning equipment which arc existing sources or for which

construction, reconstruction or major alteration has commenced prior to the effective date of this

Section, which arc greater than or equal to 73- megawatts capacity.

1. The standard for particulate matter under this cction is:

a No person shall cause, suffer, allow or permit the emission of particulate matter;

caused by combustion of fuel, from any fuel-burning operation subject to the provisions of this

Section in excess of the amounts calculated by one of the following equations presented below:

4 L. For equipment having a heat input rate of 4200 million Btu per hour or less, the

maximum allowable emission 8 ,lll be determined by the following equation:

E=l.02Q

where: E= the maximum allowable particulate emissions rate in pounds-mass per hour.

Q= the heat input in million Btu per hour.

ih 2 For equipment having a heat input rate greater than 4200 million Btulhr, the

maximum allowable emissions shall be determined by the following equation:

8E=17.OQ°432where“E”and“Q”havethesamemeaningasinSubdivisioni.aboveParagraph(1)ofthisSubsection..Forreferencepurposesonly,thetwoequationsinC.i.a.aboveSubsection(C)ofthisSectionareplottedinAppendix11,Figure1.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheheatinputratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.LExceptasprovidedinC.3.below,thestandiirdforsulfurdioxideunderthisScctionisWhenlowsulfuroilisfired:aj.ExistingfuelburningequipmentorsteampowergeneratinginstallationswhichcommencedconstructionoramajoraltcrationmodificationpriortoMay30,1972shallnotemitmorethan1.0poundssulfurdioxidemaximumthreehouraverage,permillionBtu(430nanogramsperjoule)heatinputwhenlowsulfuroilisfired.ExistingfuelburningequipmentorsteampowergeneratinginstallationswhichcommencedconstructionoramajoralterationmodificationafterMay30,1972shallnotemitmorethan0.80poundsofsulfurdioxidemaximumthreehouraveragepermillionBtu(340nanogramsperjoule)heatinputwhenlowsulfuroilisfired.F.WhenhighsulfuroilisfiredAljjexistingsteampowergeneratingandgeneralfuelburninginstallationswhicharesubjecttotheprovisionsofthisSectionshallnotemitmorethan2.2poundsofsulfurdioxidemaximumthree-houraveragepermillionBtu(946nanogramsperjoule)heatinputwhenhighsulfuroilisfired.GWhensolidfuelisfired:j.ExistinggeneralfuelburningequipmentandsteampowergeneratinginstallationswhichcommencedconstructionoramajorahcrationmodificationpriortoMay30,1972shallnotemitmorethan1.0poundsofsulfurdioxidemaximumthree-houraverage,permillionBtu(430nanogramsperjoule)heatinputwhensolidfuelisfired.e2.ExistinggeneralfuelburningequipmentandsteampowergeneratinginstallationswhichcommencedconstructionormajoralterationmodificationafterMay30,1972shallnotemitmorethan0.80pounds,maximumthree-houraverage,permillionBtu(340nanogramsperjoule)heatinputwhensolidfuel13fired.fILAnypermitissuedfortheoperationofanexistingsource,oranyrenewalormodificationofsuchapermit,shallincludeaconditionprohibitingtheuseofhighsulfuroilbythepermittee,unlesstheapplicantdemonstratestothesatisfactionoftheDirectorthatsufficientquantitiesOflowsulfuroilarenotavailableforusebythesourceandthatithasadequatefacilitiesandcontingencyplanstoinsurethatthesulfurdioxideambientairqualitystandardssetforthinSectionRi8-2-202willnotbeviolated.i.Thetermsofthepermitmayauthorizetheuseofhighsulfuroilundersuchconditionsasarejustified.IncaseswherethepermitteeisauthorizedtousehighsulfuroilitshallsubmittotheDepartmentmonthlyreportsdetailingitseffortstoobtainlowsulfuroil.Whentheconditionsjustifyingtheuseofhighsulfuroilnolongerexists,thepermitshallbemodifiedaccordingly.4..NothinginthisSectionshallbeconstruedasallowingtheuseofasupplementary9controlsystemorotherformofdispersiontechnology.g.ForpurposesofthisRulelowsulfuroilmeansfueloilcontaininglessthan0.90percentbyweightofsulfurandhighsulfuroilmeansfueloilcontaining0.90percentormorebywcightofsulfur.3.IntheeventapersonobtainedaninstallationpermitpriortoMay14,1979fortwoormorefuelburningequipmentorsteampowergeneratinginstallationswhichpermittedsuchpersontocomplywiththcsulfurdioxideemissionstandardsspecifiedinC.2.aboveasifsuchequipmentorinstallationsconstitutedoneemissiondischargepoint,suchpersonshallcomplywiththeapplicablesulfurdioxideomissionstandardsinthemannerspecifiedinitsinstallationpermitandsuchomissionstandardsshallbeincorporatedintosuchperson’soperatingpermitasanenforceablepermitcondition.4LExistingsteampowergeneratinginstallationswhichcommencedconstructionoramajoralterationmodificationafterMay30,1972shallnotemitnitrogenoxidesinexcessofthefollowingamounts:a1.0.20poundsofnitrogenoxides,maximumthree-houraverage,calculatedasnitrogendioxide,permillionBtuheatinputwhengaseousfossilfuelisfired.b0.30poundsofnitrogenoxides,maximumthree-houraverage,calculatedasnitrogendioxide,permillionBtuheatinputwhenliquidfossilfuelisfired.e30.70poundsofnitrogenoxides,maximumthree-houraverage,calculatedasnitrogendioxide,permillionBtuheatinputwhensolidfossilfuelisfired.&jEmissionandfuelmonitoringsystems,wheredeemednecessarybytheDirectorforsourcessubjecttotheprovisionsofthisSectionsshallconformtotherequirementsofSectionR18-2-313.&TheapplicablereferencemethodsgivenintheArizonaTestingManualAppendicesto40CFR60shallbeusedtodeterminecompliancewiththestandardsasprescribedinC.l.,C.2.,andC.4.aboveSubsections(C)through(G)and(flofthisSection,orasprescribedinapcr3on’sinstallationpermitasprovidedinC.3.,andnotbycontinuousmonitoring.AlltestsshallberunattheheatinputcalculatedunderSubsection(B)ofthisSection.R18-2-5O4Q4.StandardsofperformanceforincineratorsA.TheprovisionsofthisSectionarcapplicabletoallincineratorswhicharcexisting3Ourecs.4-ANotwithstandingtheprovisionsofSectionRi8-2-501,nopersonshallcause,suffer,alloworpermittobeemittedintotheatmosphere,fromanytypeofincinerator,smoke,fumes,gases,particulatematterorothergas-bornematerialwhichexceeds20percentopacityexceptduringthetimesspecifiedinA.4.belowSubsection(D)ofthisSection.llNopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanyincinerator,inexcessofthefollowinglimits:.jFormultiplechamberincinerators,controlledatmosphereincinerators,fumeincinerators,afterburnersorotherunspecifiedtypesofincinerators,emissionsshallnotexceed0.1grainpercubicfoot,basedondryfluegasatstandardconditions,correctedto12percentcarbondioxide.2Forwoodwasteburnersotherthanaircurtaindestructors,emissionsdischargedfromthestackorburnertopopeningshallnotexceed0.2grainpercubicfoot,basedondryflue10gas at standard conditions, corrected to 12 percent carbon dioxide.

c. For air curtain destructors, emissions discharged from the pit opening shall net

cxcccd 0.5 grain per dry 3tandilrd cubic foot corrected to 12 percent carbon dioxide.

£ Air curtain destructors shall not be used within 500 feet of the nearest dwelling.

3. Thc amount of particulate matter emitted shall be determined by test methods and

procedures as stated in Subsection C. below. Test methods may be modified, adjusted or added

to by the Dircctor to suit spccific 3arnphng conditions or nccd3 and shall be bascd on good

engincering practice, judgment and experience.. Incinerators shall be exempt from the above opacity and emission requirements

described in Subsections (A) and (B) of this Section as follows:

a 1. For multiple chamber incinerators, controlled atmosphere incinerators, fume

incinerators, afterburners or other unspecified types of incinerators, such exemption shall be for

not more than 30 seconds in any 60-minute period.

b 2 Wood waste burners and air curtain dcstructors shall be exempt as follows kh:

For a period once each day for the purpose of building a new fire but not to

exceed 60 minutes. and

iib For an upset of operations not to exceed- three minutes in any 60-minute period.

BL The owner or operator of any incinerator subject to the provisions of this Section

shall record the daily charging rates and hours of operation.

G L The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Testing Manual, 40 CFR 60. Appendix A

shall be used to determine compliance with the standard prescribed in Subsection 4 ) of this

Section as follows:

a. Method 5 for the concentration of particulate matter and the associated moisture

contentt. b. Method 1 for sample and velocity traverses

c. Method 2 for velocity and volumetric flow rate; and

d. Method 3 for gas analysis and calculation of excess air, using the integrated

sampling technique.

2. For Method 5, the sampling time for each run shall be at least 60 minutes and the

minimum sample volume shall be 0.85 dscm (30.0 dscf) except that smaller sampling times or

sample

volumes, when necessitated by process variables or other factors, may be approved by the

Director. R18-2-5O57Q. Standards of performance for existing portland cement plants

A. The provisions of this Section are applicable to the following affected facilities in

portland cement plants: kiln, clinker cooler, raw mill system, finish mill system, raw mill dryer,

raw material storage, clinker storage, finished product storage, conveyor transfer points, bagging

and bulk loading and unloading systems.

B. The provisions of this Section arc applicable to all cement plants under State of

Arizona jurisdiction which arc existing sources.. No person shall cause, suffer, allow or permit the discharge of particulate matter

from any identifiable process source within any existing cement plant subject to the provisions of

this Section which exceeds the amounts allowable under calculated by one of the following

11equations:.L.Forprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P°‘where:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.b2Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.OP0140where“E”and“P”aredefinedasindicatedinB.l.a.abovcParagraph(1)ofthisSubsection.2Noprocesssourcewithinanycxistingportlandcementplantshallexceed20percentopacity.]Nopersonshallcause,suffcr,alloworpermitdischargeintotheatmosphereofanamountinexcessofsixpoundsofsulfuroxides,calculatedassulfurdioxide,pertoncementkilnfeedfromcementplantssubjecttotheprovisionsofthisSection.GTheowneroroperatorofanyportlandcementplantsubjecttotheprovisionsofthisSectionshallrecordthedailyproductionratesandthekilnfeedrates.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsinthcArizonaTc3tingManual40CFR60.AppendixA,exceptasprovidedforinScctionRi8-2-312shallbeusedtodeterminecompliancewiththestandardsprescribedinSubsection(B)ofthisSectionasfollows:a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontent.Vb.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowratc;andd.Method3forgasanalysis.2.ForMethod5,theminimumsamplingtimeandminimumsamplevolumeforeachrunexceptwhenprocessvariablesorotherfactorsjustifyingotherwisetothesatisfactionoftheDirector,shallbeasfollows:a.60minutesand0.85dscm(30.0dscf)forthekiln;.b.60minutesand1.15dscm(40.6dscf)fortheclinkercooler.V3.Totalkilnfeedrate(exceptfuels),expressedinmetrictonsperhouronadrybasis,shallbeboth:dctcrmincdDeterminedduringeachtestingperiodbysuitablemethods;and3hallbcconfirmcdConfirmedbyamaterialbalanceovertheproductionsystem.4.Foreachrun,particulatematteremissions,expresseding/metrictonoflcilnfeed,shallbedeterminedbydividingtheemissionrateing/hrbythekilnfeedrate.Theemissionrateshallbedeterminedbytheequation,g/hr=Q5xc,whereQ-volumetricflowrateofthetotaleffluentindscmThrasdeterminedinaccordancewithD.l.c.abovcParagraph(1).Subparagraph(c)ofthisSubsection,andc=particulateconcentrationingldscmasdeterminedinaccordance12withD.1.a.abovcSubparagraph(l)(a)ofthisSubsection.R18-2-5O62.StandardsofperformanceforexistingnitricacidplantsA.Thestandardfornitrogenoxidesfornitricacidplantswhicharcexistingsources1-A.Nopersonshallcause,suffer,alloworpermitdischargefromanyexistingsourcenitricacidplantproducingweaknitricacid,whichiseither:30to70percentinstrengthbyeithertheincreasedpressureoratmosphericpressureprocess,ormorcMorethan1.5kgoftotaloxidesofnitrogenpermetricton(3.0lbs/ton)ofacidproducedexpressedasnitrogendioxide.2TheopacityofanyplumesubjecttotheprovisionsofthisSectionshallnotexceed1-0tnpercent.B.EmissionsmonitoringrequiredbythisSectionisasfollows:4-.±Acontinuousmonitoringsystemforthemeasurementofnitrogenoxidesshallbeinstalled,calibrated,maintainedandoperatedbytheowneroroperator,inaccordancewithScctionRi8-2-313..ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsinthcArizonaTestingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardprescribedinSubsection(A)abovcc2fthisSectionasfollows:a.Method7fortheconcentrationofNOb.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowratc;andd.Method3forgasanalysis.2.ForMethod7,thesamplesiteshallbeselectedaccordingtoMethodIandthesamplingpointshallbethecentroidofthestackorductoratapointnoclosertothewallsthan1m(3.28ft.).Eachrunshallconsistofatleastfourgrabsamplestakenatapproximately15-minuteintervals.Thearithmeticmeanofthesamplesshallconstitutetherunvalue.Avelocitytraverseshallbeperformedoncepernrn.3.Acidproductionrate,expressedinmetrictonsperhourof100percentnitricacid,shallbeboth:determinedDeterminedduringeachtestingperiodbysuitablemethodsandshallbeconfirmedConfirmedbyamaterialbalaiceovertheproductionsystem.4.Foreachrun,nitrogenoxides,expresseding/metrictonof100percentnitricacid,shallbedeterminedbydividingtheemissionrateing/hrbytheacidproductionrate.Theemissionrateshallbedetenninedbytheequation:Whr=xcwhereQ5=volumetricflowrateoftheeffluentindscmlhr,asdeterminedinaccordancewithC.1.c.aboveSubparagraph(1)(c)ofthisSubsecti,andc=NOxconcentrationingldscm,asdeterminedinaccordancewithC.i.a.aboveSubparagraph(1)(a)ofthisSubsection.R18-2-5077Q2.StandardsofperformanceforexistingsulfuricacidplantsA.Theprovisionsofthi3SectionarcapplicabletoallnonmctallurgicalsulfuricacidplantsunderStateofArizonajurisdictionwhicharcexistingsources.13BANopersonshallcause,suffer,alloworpermitdischargeintotheatmosphereofmorethan2kgofsulfurdioxidepermetricton(4lbs/ton)ofsulfuricacidproduced(calculatedasi00pcrccnt112504),fromfacilitiesFacilitiesthatproducesulfuricacidbythecontactprocessbyburningelementalsulfur,alkylationacid,hydrogensulfide,organicsulfideandmercaptansoracidsludgeshallnotdischargeintotheatmosphere:C.Nopersonshallcause,suffer,alloworpermitdischargeintotheatmosphereofmorethan0.075kgofsulfuricacidmistpermetricton(0.15lbs/ton)ofsulfuricacidproduced(calculatedas100percent112504),expressedas112504,fromfacilitiesthatproducesulfuricacidbythecontactprocessbyburningelementalsulfur,alkylationacid,hydrogensulfide,organicsuffldcsandmercaptansofacidsludge.1.Greaterthan2kgofsulfurdioxidepermetricton(4lbs/ton)ofsulfuricacidproduced(calculatedas100percentH2S04).or2.Greaterthan0.075kgofsulfuricacidmistpermetricton(0.15lbs/ton)ofsulfuricacidproduced(calculatedas100percentE12S04).D.ThisBttleSectionshallnotapplytometallurgicalplantsorotherfacilitieswhereconversiontosulfuricacidisutilizedasameansofcontrollingemissionstotheatmosphereofsulfurdioxideorothersulfurcompounds.IL.EmissionsmonitoringrequiredbythisSectionisasfollows:.Acontinuousmonitoringsystemforthemeasurementofsulfurdioxideshallbeinstalled,calibrated,maintainedandoperatedbytheowneroroperator,inaccordancewithSectionRi8-2-313.F;11ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodsintheArizonaTestingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewithstandardsprescribedinSubsectionsB.andC.above(A)ofthisSectionasfollows:a.Method8forconcentrationofSO2andacidmistb.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowrate;andd.Method3forgasanalysis.2.Themoisturecontenteaniibeconsideredtobezero.ForMethod8thesamplingtimeforeachrunshallbeatleast60minutesandtheminimumsamplevolumeshallbe1.15dscm(40.6dscf)exceptthatsmallersamplingtimesorsamplevolumes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.3.Acidproductionrate,expressedinmetrictonsperhourof100percentH2S04,shallbeboth:determinedDeterminedduringeachtestingperiodbysuitablemethodsandshallbeconfirmedConfirmedbyamaterialbalanceovertheproductionsystem.4.Acidmistandsulfurdioxideemissions,expresseding/metrictonof100percentH7SO4,shallbedeterminedbydividingtheemissionrateing/hrbytheacidproductionrate.Theemissionrateshallbedeterminedbytheequation,g/hr-Qxc,whereQ5=volumetricflowrateoftheeffluentindscmi’hrasdeterminedinaccordancewithF.1.c.aboveSubparagraph(1)(c)ofthisSubsection,andc=acidmistandSO2concentrationsing/dscmasdeterminedinaccordancewithF.l.a.aboveSubparagraph(1)(a)ofthisSubsection.14R18-2-5OWZQ.Standardsofperfonnanceforexistingasphaltconcreteplants-r1—C1__plantisA.rormcpurpo&oiuu.EUOflanasphaltCOilLcomprisedonlyofanycombinationofthcfollowing:Dryer,systemsforscreening,handling,storingandweighinghotaggregate,systemsforloading,transferringandstoringmineralfiller;systemsformixingasphaltconcrete;andtheloading,transferringandstoragesystemsassociatcdwithemissioncontrolsystems.Drumdryerplants,whereinthcasphaltisintroducedintothedryer,arcincludedhcrcundcr.Fixedasphaltconcreteplantsoi’portableasphaltconcreteplantswhicharccxistrngSOUCC3shallmeetthestandardssetforthinthisSection.TheowneroroperatorshallsubmitproofofpriorusctotheDirector.4-Nopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanyexistingasphaltconcreteplantintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowingequations3Ctforthbelow:a.LForprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.l0P°‘where:E=themaximumallowableparticulateemissionrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P°-40where“E”and“P”aredefmedasindicatedinB.l.a.aboveParagraph(1)ofthisSubsection...Forreferencepurposesonly,theequationsgivenaboveareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.3-J2.ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeuse4indeterminingthemaximumallowableemissionofparticulatematter.4.ThestandardforsulfurinfuelunderthisSectionis:aLLiquidfuelcontaininggreaterthan0.9percentsulfurbyweightshallnotbeutilizedforasphaltconcreteplantssubjecttothisSection.Solidfuelcontaininggreaterthan0.5percentsulfurbyweightshallnotbeutilizedforasphaltconcreteplantssubjecttothisSection.G.ThetestmethodsandproceduresrequiredunderthisSectionare:1.ThereferencedmethodsgivenintheArizonaTestingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsection(B)above.a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontent15b.Method1forsampleandvelocitytraversesc.Method2forvelocityandvolumetricflowratc;andLd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.9dscmlhr(0.53dscf7min)exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.3.PercentsulfurinliquidfuelshallbedeterminedbyASTMmethodD-129-649j(TestMethodforSulfurinPetroleumProducts(GeneralBombMethod),andthepercentsulfurinsolidfuelshallbedeterminedbyASTMmethodD-3177-73D-3177-89(TestMethodforTotalSulfurintheAnalysisSampleofCoalandCoke).R18-2-5O92Q.StandardsofperformanceforexistingpetroleumrefineriesA.TheprovisionsofthisSectionareapplicabletothefollowingaffectedfacilitiesinpetroleumrefmeries:fluidcatalyticcrackingunitcatalystregenerators,fluidcatalyticcrackingunitincinerator-wasteheatboilers,andfuelgascombustiondevices.Allpetroleumrefinerieswhicharcexistingsourcesarc3ubjccttothcprovisionsofA.A.C.Title9,Chapter3,Articlc8.ExceptasprovidedinSubsection(G)ofthisSection.allpetroleumrefineriessubjecttothisSectionarealsosubjecttotheprovisionsofRi8-2-801.10901(12)..TheowneroroperatorofapetroleumrefinerycomplexsubjecttothisRuleSectionshalldevelopandconductaleakmonitoringprograminaccordancewithAppendixHoftheEPAPetroleumRefmeryEnforcementmanualManual(EPA340/1-80-008),AppendixIIasamendedasofMarch.1980(andnofutureeditions),whichisincorporatedhereinbyreferenceandonfilewiththeOfficeoftheSecretaryofState.P..Upondetectionofaleakingcomponent,whichhasavolatileorganiccompoundconcentrationexceeding10,000ppmwhentestedinthemannerdescribedinthcArizonaTestingManual40CFR60.AppendixA.theownershallbh:LIncludetheleakingcomponentonawrittenlistofscheduledrepairswithin24hours;and;b2...Repairandretestthecomponentwithin15days.LExceptforsafetypressurereliefvalves,noowneroroperatorofapetroleumrefmeryshallinstallavalveattheendofapipeorlinecontainingvolatileorganiccompoundsunlessthepipeorlineissealedwithasecondvalve,ablindflange,aplug,oracap.Thesealingdevicemayberemovedonlywhenthelineisinuse(ie,whenasampleisbeingtaken).jNoowneroroperatorofapetroleumrefineryshalloperateapipelinevalveorpressurereliefvalveingaseousvolatileorganiccompoundserviceunlessitismarkedinsomemaimerthatwillbereadilyobvioustobothrefinerypersonnelperformingmonitoringandtheDirectorisclearlyvisible.G.Existingpetroleumrefineriesofacapacityof7,000barrelsperdayorlessshallbeexemptfromtheemissionsmonitoringrequirementsof40CFR60.105providedtheowneroroperatorofsucharefinerycomplieswithallofthefollowing:1.Allprocessgasesorfuelgasesshallbetreatedinanafterburner,flareorothercombustiondevicetoinsurecompletecombustionofcarbonmonoxide,hydrogensulfide,andunburnedhydrocarbons.162.AmbientconcentrationsofSO2inthevicinityoftherefineryshallbecalculatedusingasuitablemodelapprovedbytheDirectorandshallnotexceedtheClassIIincrementsmaximumallowableincreasesgiveninSectionRi8-2-217Ri8-2-218.3.AcontinuousSO2ambientairmonitorapprovedbytheDirectorshallbeplacedin alocationselectedbytheDirectorandshallbemaintainedinaccordancewithSectionRi8-2-215,andSO7concentrationsshallnotexceedClassIIincrcmcntamaximumallowableincreases.R18-2-51-921(i.StandardsofperformanceforexistingstoragevesselsforpetroleumliquidsA.StoragevcssclsundcrStateofArizonajurisdictionwhicharcexistingsourcesshallmcctthcfollowingstandards:-hNopersonshallplace,storeorholdinanyreservoir,stationarytankorothercontainerhavingacapacityof40,000(151,400liters)ormoregallonsanypetroleumliquidhavingavaporpressureof1.5poundspersquareinchabsoluteorgreaterunderactualstorageconditions,unlesssuchtank,reservoirorothercontainerisapressuretankmaintainingworkingpressuresufficientatalltimestopreventhydrocarbonvapororgaslosstotheatmosphere.orisequippedwithoneofthefollowingvaporlosscontroldevices,properlyinstalled,ingoodworkingorderandinoperation:a LAfloatingroofconsistingofapontoontypedouble-decktyperoofrestingonthesurfaceoftheliquidcontentsandequippedwithaclosuresealtoclosethespacebetweentheroofeaveandtankwell,wallandavaporballoonorvapordome,designedinaccordancewithacceptedstandardsofthepetroleumindustry.Thecontrolequipmentshallnotbeusedifthepetroleumliquidhasavaporpressureof12poundspersquareinchabsoluteorgreaterunderactualstorageconditions.Alltankgaugingandsamplingdevicesshallbegas-tightexceptwhengaugingorsamplingistakingplace.b.Thereshallbenovisibleholes,tears,orotheropeningsinthesealoranysealfabric.Whereapplicable,allopeningsexceptdrainsshallbeequippedwithacover,seal,orlid.Thecover,seal,orlidshallbeinaclosedpositionatalltimes,exceptwhenthedeviceisinactualuse.Automaticbleederventsshallbeclosedatalltimes,exceptwhentheroofisfloatedofforlandedontherooflegsupports.Rimvents,ifprovided,shallbesettoopenwhentheroofisbeingfloatedofftherooflegsupports,oratthemanufacturer’srecommendedsetting.e2.Otherequipmentproventobeofequalefficiencyforpreventingdischargeofhydrocarbongasesandvaporstotheatmosphere.Anyotherpetroleumliquidstoragetankshallbeequippedwithasubmergedfillingdeviceoracceptableequivalentforthecontrolofhydrocarbonemissions..Allfacilitiesfordockloadingofpetroleumproducts,havingavaporpressureof1.5poundspersquareinchabsoluteorgreateratloadingpressure,shallprovideforsubmergedfillingoracceptableequipmentequivalentforcontrolofhydrocarbonemissions.GPAllpumpsandcompressorswhichhandlevolatileorganiccompoundsshallbeequippedwithmechanicalsealsorotherequipmentofequalefficiencytopreventthereleaseoforganiccontaminantsintotheatmosphere.DLThemonitoringofoperationsrequiredbythisSectionisasfollows:171.TheowneroroperatorofanypetroleumliquidstoragevesseltowhichthisSectionappliesshallforeachsuchstoragevesselmaintainafileofeachtypeofpetroleumliquidstored,ofthetypicalReidvaporpressureofeachtypeofpetroleumliquidstoredandofdatesofstorage.Datesonwhichthestoragevesselisemptyshallbeshown.2.TheowneroroperatorofanypetroleumliquidstoragevesseltowhichthisSectionappliesshallforsuchstoragevesseldetermineandrecordtheaveragemonthlystoragetemperatureandtruevaporpressureofthepetroleumliquidstoredatsuchtemperatureifeither:a.Thepetroleumliquidhasatruevaporpressure,asstored,greaterthan26mmHg(1.5psia0.5psia)butlessthan78mmHg(1.5psia)andisstoredinastoragevesselotherthanoneequippedwithafloatingroof,avaporrecoverysystemortheirequivalents;orb.Thepetroleumliquidhasatruevaporpressureasstored,greaterthan470mmHg•(9.1psia)andisstoredinastoragevesselotherthanoneequippedwithavaporrecoverysystemoritsequivalent.3.Theaveragemonthlystoragetemperatureishallbeanarithmeticaveragecalculatedforeachcalendarmonth,orportionthereof,ifstorageisforlessthanamonth,frombulkliquidstoragetemperaturesdeterminedatleastonceeverysevendays.4.ThetruevaporpressureshallbedeterminedbytheproceduresinAmericanPetroleumInstituteBulletin2517.amendedasofFebruary.1980(andnofutureeditions).whichisincorporatedhereinbyreferenceandonfilewiththeOfficeoftheSecretaryofState.ThisprocedureisdependentupondeterminationofthestoragetemperatureandtheReidvaporpressure,whichrequiressamplingofthepetroleumliquidsinthestoragevessels.UnlesstheDirectorrequiresinspecificcasesthatthestoredpetroleumliquidbesampled,thetruevaporpressuremaybedeterminedbyusingtheaveragemonthlystoragetemperatureandthetypicalReidvaporpressure.ForthoseliquidsforwhichcertifiedspecificationslimitingtheReidvaporpressureexist,theReidporvaporpressuremaybeused.Forotherliquids,supportinganalyticaldatamustbemadeavailableuponrequesttotheDirectorwhentypicalReidvaporpressureisused.E.Casolincvolatilitytcstingandcontrolprogram1.ThisRulestatesthcrcquircdpropcrticsofgasolincatthctimeandplaccofdc1iinbulkinwithA5Th1designation:D-439-7C,.hisRule,.“inbul”oi..,d-pi4t,.toaretailseller.lITmrnn,rn,nIrrfrnru,fr’i-rr2.Automaticvariationbythesellerisprovidcdtomeetthôrequirementsofseasonalchangesintempcraturc,dcpcndinguponthcseasonandthclocalityinwhichthcproductistobcused.Thisisdonebyprovidingfourvolatilitygrades,A.,B.,C.andD.,asdefinedinD-439-70,anddiffcrcntiatingtheuseofthesegradcsaccordingtothemonthsoftheyear.3.TherequirementscnumcratcdinthisRulearebaseduponvaporpressureandshallbcdeterminedbyASTMdesignation:D-323-79.standardmethodoftestforvaporpressureofpetroleumproducts(ReidMethod).Thismethodoftestcoversthedeterminationoftheabsolutenrciircofvolatilecrudeoilandvolatilenonviscuouspetroleumproductsexceptliquiflcdnnr1nnncasoimc.irrmiirrrrflTTI-tsrndnrispecificationfor.•LjJJLrpetroleumgases.4.Theseasonaldistributionofthefourgradesofgasoline(A.,B.,C.andD.)shallconformtothescheduleinTable2ofD439-81asfollows:18MonthjMar.APLMJjjjAug.Nov.DccGradcD/CCC/BBB/AAAAAAIDB/CC/i)ReidPrc3surcororororPSIC.Max11.5..9zQil115.5.Whcrcaltcrnativcgradc3arcpcrmittcd,thcoptionshallbccxcrciscdbythcscllcr.R18-2-5i4fl1.StandardsofperformanceforexistingsecondaryleadsmeltersA;ThisScctionshallbcapplicabictoallsccondaryicadsourccs.4-Nopersonshallcause,suffcr,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanyexistingsecondaryleadsmelterintotalquantitiesinexcessoftheamountscalculatedbyoneofthefollowingequations:actforthbclow.aLForprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.10P°67where:E=themaximum,allowableemissionrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.2Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P°-40where‘E”and“P”aredefmedasindicatedinA.l.a.abovcParagraph(1)ofthisSubsection.2].ForreferencepurposesonlytheequationsinA.1.abovcSubsection(A)ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces..ForpurposesofthisRti4.eSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.ILTheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodssetforthinthcArizonaTcatingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsection(A)abovcofthisSectionasfollows:a.Method5fortheconcentrationofparticulatematterandtheassociatedmoisturecontentb.Method1forsampleandvelocitytraverses“--13.511.511.510.010.09.09.09.09.09.010.011.519c.Method2forvelocityandvolumetricflowratc;andd.Method3forgasanalysis.2.ForMethodS,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.9dscmlhr(0.53dscf7min),exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Particulatesamplingshallbeconductedduringrepresentativeperiodsoffurnaceoperationincludingchargingandtapping.R18-2-51421Z.StandardsofperformanceforexistingsecondarybrassandbronzeingotproductionplantsA.ThcstandardssctforthinthisScctionarcapplicablctoallsccondatybrassandbronzcingotproductionplantswhicharccxistingsourcc3.44Nopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanysecondarybrassorbronzeingotproductionplantintotalquantitiesinexcessoftheamountcalculatedbyoneofthefollowingequationsactforthbclow.n.LForprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.1OPwhere:E=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.b2.LForprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P’’-40where“B”and“P”aredefinedasindicatedinA.l.a.aboveParagraph(1)ofthisSubsection.2Forreferencepurposesonly,theequationsinA.1.abovcSubsection(A)ofthisSectionareplottedinFigure2,Appendix11,Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.3-CForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.TheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodssetforthintheArizonaTcstingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsection(A)abovcofthisSectionasfollows:a.MethodSfortheconcentrationofparticulatematterandtheassociatedmoisturecontentb.Method1forsampleandvelocitytraverses20c.Method2forvelocityandvolumetricflowratc;ancL.d.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast120minutesandthesamplingrateshallbeatleast0.9dscmlhr(0.53dscfYmin)exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Particulatemattersamplingshallbeconductedduringrepresentativeperiodsofchargingandrefming,butnotduringpouringoftheheat.R18-2-51.3m.StandardsofperformanceforexistingironandsteelplantsA.ThestandardsactforthinthisSectionarcapplicabletobasicoxygenprocessrurnaccsunderStateofArizonajurisdictionwhicharcexistingaourccs.

A.Nopersonshallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmosphereinanyonehourfromanybasicoxygenprocessfurnaceintotalquantitiesinexcessoftheamountcalculatedbyoneofthefollowingequations.actforthbelow.a.LForprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.10P°67where:B=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.b2..Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P°14()where“E”and‘P”aredefinedasindicatedinA.l.a.aboveParagraph(1)ofthisSubsection.Forreferencepurposesonly,theequationsinA.1.andA.2.aboveSubsection(A)ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.3-£.ForpurposesofthisRuleSection,thetotalprocessweightfromallsimilarunitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematter.4;.TheopacityofemissionssubjecttotheprovisionsofthisSectionshallnotexceed20percent.B..MonitoringofoperationsunderthisSectionisasfollows:1.Theowneroroperatorofanaffectedfacilityshallmaintaindailyrecordsofthetimeanddurationofeachsteelproductioncycle.2.TheowneroroperatorofanyaffectedfacilitythatusesVenturiscrubberemissioncontrolequipmentshallinstall,calibrate,maintainandcontinuouslyoperatethefollowingmonitoringdevices:a.AmonitoringdeviceforthecontinuousmeasurementofthepressurelossthroughtheVenturiconstructionconstrictionofthecontrolequipment.Themonitoringdeviceis-te hil214becertifiedbythemanufacturertobeaccuratewithin±250pascals(±1inchwater).b.Amonitoringdeviceforthecontinuousmeasurementofthewatersupplypressuretothecontrolequipment.Themonitoringdeviceistobecertifiedbythemanufacturertobeaccuratewithin±5percentofthedesignwatersupplypressure.Thepressuresensorortapmustshallbelocatedclosetothewaterdischargepoint.TheDirectormaybeconsultedforapprovalofaltcrnativclocationsforthcpressuresensorortap.3.AllmonitoringdevicesrequiredinC.2.belowSubsection(F).Paragraph(2)ofthisSectionarctoshallberecalibratedannuallyandatothertimesastheDirectormayrequire,inaccordancewiththeproceduresinAppendix9.GThetestmethodsandproceduresrequiredunderthisSectionareasfollows:1.ThereferencemethodssetforthintheArizonaTestingmanual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsections(A)andB.aboveofthisSectionasfollows:a.Method5forconcentrationofparticulatematterandassociatedmoisturecontentb.Method1forsampleandvelocitytraversesc.Method2forvolumetricflowrate;andLd.Method3forgasanalysis.2.ForMethod5,thesamplingforeachrunshallcontinueforanintegralnumberofcycleswithtotaldurationofatleast60minutes.Thesamplingrateshallbeatleast0.9dscm!hr(0.53dscf7min)exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.Acycleshallstartatthebeginningofeitherthescrappreheatortheoxygenblowandshallterminateimmediatelypriortotapping.R18-2-51-4fl4.StandardsofperformanceforexistingsewagetreatmentplantsA.TheprovisionsofthisSectionarcapplicabletoallmunicipalsewagetreatmentplantsludgeincineratorsofanysizewhicharcexistingsources.4-NotwithstandingtheprovisionsofSectionRi8-2-501,nopersonshallcause,suffer,alloworpermittobeemittedintotheatmosphere;fromanymunicipalsewagetreatmentplantsludgeincinerator.isubjecttotheprovisionsofthisSection,smokeSmoke,fumes,gases,particulatematterorothergas-bornematerialwhichexceeds20percentopacityformorethan30secondsinany60-minuteperiod.2.Nopersonshallcause,suffer,alloworpermittobeemittedintotheatmospherefromanysewagesludgeincineratorsubjecttotheprovisionsofthisSection,particulateParticulatematterinconcentrationsinexcessof0.1grainpercubicfoot,basedondryfluegasatstandardconditions,correctedto12percentcarbondioxide.B.MonitoringofoperationsrequiredbythisSectionisasfollows:4-jTheowneroroperatorofanysludgeincineratorsubjecttotheprovisionsofthisSectionshallmonitoroperationsbydoingallofthefollowing:LInstall,calibrate,maintainandoperateaflowmeasuringdevicewhichcanbeusedtodetermineeitherthemassorvolumeofsludgechargedtotheincinerator.Theflowmeasuringdeviceshallhaveanaccuracyof+1-fivepercentoveritsoperatingrange.b2Provideaccesstothesludgechargedsothatawell-mixedrepresentativegrab22sampleofthesludgecanbeobtained.Install,calibrate,maintainandoperateaweighingdevicefordeterminingthemassofanymunicipalsolidwastechargedtotheincineratorwhensewagesludgeandmunicipalsolidwastesareincineratedtogether.Theweighingdeviceshallhaveanaccuracyof+1-fivepercentoveritsoperatingrange.C.ThetestmethodsandproceduresrequiredbythisSectionareasfollows:1.ThereferencemethodssetforthintheArizonaTestingManual40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinSubsections(A)andB.abovcofthisSectionasfollows:a.Method5forconcentrationofparticulatematterandassociatedmoisturecontentb.Method1forsampleandvelocitytraversesc.Method2forvolumetricflowratc;andd.Method3forgasanalysis.2.ForMethod5,thesamplingtimeforeachrunshallbeatleast60minutesandthesamplingrateshallbeatleast0.015dscmlmin(0.53dscf7rnin),exceptthatshortersamplingtimes,whennecessitatedbyprocessvariablesorotherfactors,maybeapprovedbytheDirector.R18-2-5+52i.Standardsofperformanceforexistingprimarycoppersmelters;SitespecificrequirementsA.TheprovisionsofthisSectionarcapplicabletoallprimarycoppersmelterswiththcStateofArizonawhicharcexistingsources.B.Particulateemissionslimitations:1-A.Noowneroroperatorofanexistingprimarycoppersmelter,fromandafterthecompliancedatespecifiedinSubsectionC.,acompliancedatespecifiedinanonferroussmelterorder,inaconsentdecree,orinadelayedcomplianceorder,shallcause,suffer,alloworpermitthedischargeofparticulatematterintotheatmospherefromanyprocessintotalquantitiesinexcessoftheamountcalculatedbyoneofthequestionsactforthbelowfollowingequations:LForprocesssourceshavingaprocessweightrateof60,000poundsperhour(30tonsperhour)orless,themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=4.1OP°67whereE=themaximumallowableparticulateemissionsrateinpounds-massperhour.P=theprocessweightrateintons-massperhour.b2Forprocesssourceshavingaprocessweightrategreaterthan60,000poundsperhour(30tonsperhour),themaximumallowableemissionsshallbedeterminedbythefollowingequation:E=55.0P0-40where“E”and1ParedefinedasindicatedinB.1.a.aboveParagraph(1)ofthisSubsection.B.Forreferencepurposesonly,theequationsin11.1.aboveSubsection(A)ofthisSectionareplottedinFigure2,Appendix11.Theemissionvaluesobtainedfromthegraphareapproximatelycorrectfortheprocessweightratesshown.However,theactualvaluesshallbecalculatedfromtheapplicableequationsandroundedofftotwodecimalplaces.(±ForpurposesofthisSubsectionSection,thetotalprocessweightfromallsimilar23unitsemployingasimilartypeprocessshallbeusedindeterminingthemaximumallowableemissionofparticulatematterforthatprocess.4ITheopacityofemissionssubjecttotheprovisionsofthisSubsectionSectionshallnotexceed20percent.a.A3OUCCsubjecttothisParagraphmaypctitiontheDirectorforrcvisionofitsvisiblecmissionslimitasprovidedinSubscctionR18-2-501.C.5.Interimopcratingrequirements:a.Duringthcperiodpriortothecompliancedate,thcowneroroperatorofasmeltersubjecttothisSectionshallcomplywiththcfollowingemissionlimitsbyoperatinghisparticulateremovalcguipmcntatitsmaximumfcasiblcefficiency:i.ForthccoppcrsmcltcrofInspirationConsolidatcdCopperCompany,thcparticulatcemissionlimitshallbc141poundsperhour.ii.ForthecoppcrsmclterofKcnnceottCopperCorporation,RayMinesDivision,thcparticulatcemissionlimitshallbc141poundspcrhour.iii.ForthecoppersmelterofMagmaCopperCompany,SanManuelDivision,theparticulateemissionlimitshallbe1830poundsperhour.iv.ForthecoppersmelterofASARCO,Inc.,hayden,theparticulatecmi3sionlimitshallbe800poundsperhour.v.ForthecoppersmelterofPhelpsDodgeCorporation,DouglasReductionWorks,theparticulateemissionlimitshallbe1752poundsperhour.vi.ForthecoppersmelterofPhelpsDodgeCorporation,MorenciBranch,theparticulateemissionlimitshallbe2144poundsperhour.vii.ForthecoppersmelterofPhelpsDodgeCorporation,NewComcliaBranch,theparticulateemissionlimitshallbe568poundsperhour.<hereferencemethodssetforthintheArizonaTestingManualand40CFR60.AppendixAshallbeusedtodeterminecompliancewiththestandardsprescribedinthisSubsectionSectionasfollows:LExceptasdescribedin6.a.i.below,MethodAlorReferenceMethod5forconcentrationofparticulatematterandassociatedmoisturecontent.i.Compliancewiththestandardsprescribedin5.a.i.and5.a.uli.shallbedeterminedusingacombinationofReferenceMethods5and8inwhichaMethod5filterismaintainedat250oFahrenheitandaMethod8impingcrtrainisused.TheparticulatereportedshallincludethecatchfromtheMethod5filter,particulatesfromtheprobewash,andthesulfuricaciddetermininginaccordancewithMethod8.b2ReferenceMethod1forsampleandvelocitytraverseseIReferenceMethod2forvolumetricflowrate,andLd4...Referencemethod3forgasanalysis.GSulfurdioxideemissionslimitations:4LExceptasprovidedinanonferroussmelterorder,aconsentdecreeoradelayedcomplianceorder,noowneroroperatorofanyexistingprimarycoppersmelter,fromandafteradate(hereinaftercalledthe“compliancedate”)threeyearsafterthedateonwhichtheAdministrator,actingpursuanttoSection110oftheAct,approvesthisSubsection,shalldischargeorcausethedischargeofsulfurdioxideintotheatmospherefromanystacksrequired:24tobemonitoredbyParagraph4.bclowRl8-2-l5.0l7l5.O1CK)inexcessofthefollowing:aLForthecoppersmelterofMagmaCopperCompany,SanManuelDivision:Annualaverageemissions,ascalculatedpursuanttoParagraphs2.and3.bclowR18-2-515.01715.Ol(C)throughR18-2-515.01715.OlCfl,shallnotexceed18,275poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphs2.and3.bclowR18-2-515.017l5.0l(C)throughR18-2-515.01715.01(JshallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:E.lb/hr.072,000168,000264,000461,000757,8001254,8002052,0003249,5004847,5006845,500V9443,50013041,200V18039,20024537,200V33035,200435V33,77056032,00071030,20089028,700110027,200134025,700161024,500191023,0002240V21,700ForthecoppersmelterofASARCOInc.,Hayden:Annualaverageemissions,ascalculatedpursuanttoParagraphs2.and3.bclowR18-2-515.01715.01(C)throughR18-2-515.01715.OlCfl,shallnotexceed9,521poundsperhour.iiThenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphs2and3.bclowR18-2-515.01715.0l(C)throughR18-2-515.017l5CflshallnotexceedncumulativeoccuirencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:flE.lb/hr.25038,000136,000234,000432,000730,5001228,8002027,3003226,0004825,0006823,8009422,70013021,50018020,50024519,30033018,50043517,50056016,70071016,00089015,000110014,200134013,500161012,800191012,200224011,500j.ForthecoppersmelterofKcnnccottCoppcrCorporationASARCO.Inc.,RayMinesDivision:Annualaverageemissions,ascalculatedpursuanttoParagraphs2.and3.bclowRi8-2-515.01715.01(C)throughRi8-2-515.01715.01(J,shallnotexceed7,790poundsperhour.bThenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphs2.and3.bclowR18-2-515.01715.01(C)throughR18-2-515.01715.OiCflshallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:nE.lb/hr.V034,0001V32,000230,000428,500726,8001225,3002024,0003222,8004821,700266820,7009419,70013018,70018017,70024516,70033015,70043515,20056014,40071013,50089012,700110012,000134011,200161010,500191010,00022409,500

4.ForthecoppersmelterofInspirationCorisolidatcdCopperCompanyCyprusMiamiMiningCorporation,Miami:Annualaverageemissions,ascalculatedpursuanttoParagraphs2.and3.belowRi8-2-515.01715.01(C)throughR18-2-515.01715.O1J)shallnotexceed3,163poundsperhour.4ii2Thenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphs2.and3.bclowR18-2-515.01715.01(C)throughR18-2-515.01715.01(J’)shallnotexceedncumulativeoccurrencesinexcessofB,theemissionlevel,showninthefollowingtableinanycomplianceperiod:E.lb/hr.016,900115,800214,750413,900713,1001212,2502011,5003210,8004810,250689,750949,2501308,7001808,2002457,6003307,2004356,7505606,3007105,8008905,5002711005,20013404,80016104,50019104,10022403,800ForthecoppersmelterofPhelpsDodgeCorporation,NewComeliaBranch:Annualaverageemissions,ascalculatedpursuanttoParagraphs2.and3.bclowRi8-2-515.01715.01(C)throughR18-2--515.01715.OlCfl,shallnotexceed8,900poundsperhour.Thenumberofthree-houraverageemissionsascalculatedpursuanttoParagraphs2.and3.belowR18-2-515.01715.01(C)throughR18-2-515.01715.01(T)shallnotexceedncumulativeoccurrencesinexcessofE,theemissionlevel,showninthefollowingtableinanycomplianceperiod:EJbfhr.037,000135,000232,500431,000729,0001227,5002026,0003225,0004823,5006822,5009421,50013020,50018019,50024518,50033017,50043517,00056016,00071015,00089014,250110013,500134012,500161012,000191011,000224010,500f.ForthccoppersmcltcrofPhelpsDodgcCorporation,DouglasRcductionWorks:1.Annualaverageemissions,ascalculatedpursumittoParagraphs2.and3.bclow,shallnotexcccd15,675poundspcrhour.ii.Thcnumberofthree-houravcragccmissionsascalculatedpursuanttoParagraphs2.and3.belowshallnotcxeccdncumulativeOccurrencesinexcessofE,theemissionlevel,showninthcfollowingtableinanycomplianceperiod:28E,lb/hr.

0 61,500

4- 58,300 55,000A_____—r 49,500

4-2 47,000

20 44,700

32 42,500 40,500

68 38,800

94 37,000

4-30 35,200

4-80 33,300

24S 31,600

330 30,200 28,800

560 27,300 26,000

890 24,500iirn_____11vJ11Afl______1_,—r’J 1610 20,800

1910 19,800____10L.tV10

For the copper smelter of Phelps Dodge Corporation, Morenci Branch:

Annual average emissions, as calculated pursuant to Paragraphs 2. and 3. bclow

R18-2-515.01715.01(C) through R18-2-515.01715.OlCfl, shall not exceed 10,505 pounds per

hour. The number of three-hour average emissions as calculated pursuant to Paragraphs

2. and 3. bclow R18-2-515.01715.01(C) through R18-2-515.01715.OlCfl shall not exceed n

cumulative occurrences in excess of E, the emissions level, shown in the following table in any

compliance

period: n E,lb/hr.

0 43,500

1 41,000

2 38,200

4 36,200

7 34,500

12 32,500

20 30,500

32 29,500

48 28,000

296827,0009426,00013024,50018023,00024522,00033021,00043519,500.56018,50071017,50089016,500110015,500134015,000161014,000191013,000.224012,000R18-2-515.01715.O1.Standardsofperformanceforexistingprimarycoppersmelters:ComplianceandmonitoringhA.ThecumulativeoccurrenceandemissionlimitsspecifiedinthiaParagraphRi8-2-5-15715(F)shallapplytothesumtotalofsulfurdioxideemissionsfromthesmelterprocessingunitsandsulfurdioxidecontrolandremovalequipment,butnotincludinguncapturedfugitiveemissionsandthoseemissionsduesolelytotheuseoffuelforspaceheatingorsteamgeneration.4Periodsofmalfunction,startup,shutdowna,orotherupsetconditionsshallnotbeexcludedwhendeterminingcompliancewiththecumulativeoccurrenceanorannualaverageemissionlimitsspecifiedinthi3ParagraphR18-2--1-715(F).2.CompliancewiththccumulativeoccurrenceandemissionlimitseontaincdinParagraph1duringtheinitial365daycomplianceperiodwhichthoselimitsareeffectivewithrespecttospecific3mcltcr,shallbedeterminedasfollows:a.CompliancewiththeapplicableannualaveragecmissiohlimitinParagraph1shallbedeterminedonamonthlybasisbyaveragingtheomissionsforallhoursmeasuredfromthecompliancedatethroughthelastdayofthecalendarmonth.Attheendofthefirstmonth,thesmeltershallbedeemedtobeincompliancewiththeapplicablenumericallimitifitsaverageemissionsexceeditsannualaverageemissionlimitbynomorethan11percentofsuchlimit.Attheendofthesecondmonth,thesmeltershallbedeemedtobeincomplianceifitsaverageemissionsexceeditsannualaverageemissionlimitbynomorethan10percentofsuchlimit.Ineachsucceedingmonththepermissiblepercentageabovethelimitshallbedecreasedbyonepercentoftheannualaveragesuchthat,atthcendofthetwelfthmonth,thesmeltershallbeincompliancewithitsannualaveragecmis3ionlimit.b.CompliancewiththcapplicablecumulativeoccurrencelimitsinParagraph1shallbedeterminedonthebasisofallthree-houraveragescalculatedasde3cribcdinParagraph3.Subparagraphb.belowthathavebeenmeasuredfromthecompliancedate.3-.(±CompliancewiththecumulativeoccurrenceandemissionlimitscontainedinParagraph1R18-2--l-&715(F).forallcomplianceperiodssubsequenttotheinitial365-day30

# compliance period spccificd in Paragraph 2 shall be determined

as follows:

L

Annual average emissions shall be calculated at the end of each day by averaging

the emissions for all hours measured during the compliance period ending on that day. An

annual emissions average in excess of the allowable annual average emission limit will be

considered

a violation if either:

The annual

average is larger than the annual average computed for the preceding

day; or 44 h. the Ij annual averages computed for the five preceding days all exceed the

allowable annual average emission limit.

2 Three-hour emissions

averages shall be calculated at the end of each clock hour

by averaging the hourly emissions for the preceding three consecutive hours whenever each such

hour was measured in accordance with the requirements contained in Paragraph 4 Subsection (K.)V 

# of this Section.

. 

# For purposes of this Section. the compliance date, unless otherwise provided in a

consent decree or a delayed compliance order, shall be January 14. 1986.

For purposes of this Paragraph Subsection (C) of this Section, a three-hour

emissions

average in excess of an emission level (E) will be considered to violate the associated

cumulative occurrence limit (n) listed in Paragraph 1 RI 8-2-&r&7I5(F) if hQih:

L The number of all three-hour emissions averages measured during the compliance

period in excess of that emission level exceeds the cumulative

occurrence limit associated with

the emission level; and

ii 2 The average was measured during the last operating day of the compliance period

being reported.

d , 

# A three-hour emissions average can only violate the cumulative

occurrence limit

(n) of an emission level (E) in the day containing the last hour in the average.

e

,. 

# Multiple violations of a cumulative

occurrence limit in the same day and

violations of different cumulative limits in the same day shall constitute a single violation of the

requirements of this Section Rl8-2-14715.

II.. The violation of any cumulative

occurrence limit and an annual average emission

limit in the same day shall constitute only a single violation of the requirements of this Section

Rl 8-2-&15715.

g L Multiple violations of a cumulative

occurrence limit by different three-hour

emissions averages containing

any common hour shall constitute a single violation of the

requirements of this Section Rl8-2--1-7l5.

h J. For purposes of determining compliance with this Paragraph Subsections (C)

through (I) of this Section, the compliance period shall consist of the 365 calendar days

immediately preceding the end of each day of the month being reported unless that period

includes less than 300 operating days. In such case the number of days preceding the last day of

the compliance period shall be increased until the compliance period contains 300 operating

days. Any day in which sulfur containing feed is introduced into the smelting process constitutes

an operating day.

K. For purposes of determining compliance with the cumulative occurrence and

emission limits contained in Paragraph 1 Ri 8-2-4571 (F), the owner or operator of any smelter

31

# subject to such limits shall install, calibrate, maintain, and operate a measurement system for

continuously monitoring sulfur dioxide concentrations and stack gas volumetric flow rates in

each stack which could emit five percent or more of the allowable annual average sulfur dioxide

emissions from the smelter, and for

.1.. Such measurement system shall also continuously monitoring sulfur dioxide

concentrations and stack gas volumetric flow rates in the outlet of each piece of sulfur dioxide

control equipment.

2.. Captured fugitive emissions shall be continuously monitored for sulfur dioxide

concentrations and stack gas volumetric flow rates, and these emissions shall be included

as part

of total plant emissions when determining compliance with the cumulative

occurrence and

emission limits contained in Paragraph 1 R18-2-4-57l5(F).

If the owner or operator can demonstrate to the Director that measurement of

stack gas volumetric flow in the outlet of any particular piece of sulfur dioxide control equipment

would yield inaccurate results or would be technologically infeasible, then the Director may

allow measurement of the flow rate at an alternative sampling point.

4.,. For purposes of this Paragraph Subsection, continuous monitoring means the

taking and recording of at least one measurement of sulfur dioxide concentration and stack gas

flow rate reading from the effluent of each affected stack, outlet or other approved measurement

location in each 1 5-minute period. An hour of smelter emissions wil-l hnii be considered to have.

been continuously monitored if the emissions from all monitored stacks, outlets or other

approved measurement locations are measured for at least 45 minutes of any hour in accordance

with the requirements of this Paragraph Subsection.

5.,. The continuous monitoring system described In this Paragraph Subsection shall

meet all of the following requirements:

a. No later than 18 months prior to the compliance date and at such other times as

the Director may specify, the stack gas volumetric flow rate measurement systems) installed and

operated pursuant to this Section shall be demonstrated to meet the performance specifications

prescribed in 40 CFR 52, 

# Appendix E.

b. No later than 18 months prior to the compliance date and at such other times as

the Director may specify, the sulfur dioxide concentration measurement system(s installed and

operated pursuant to this Section shall be demonstrated to meet the measurement system

performance specifications prescribed in 40 CFR 52, Appendix D, except that “maximum

anticipated concentration” shall be substituted for “emission standard” in “Table I

-- 

# Performance

Specifications”

as containcd in Paragraph 4. of said Appcndix D.

c.

The demonstrations of measurement systems performance required by

Subparagraphs (a) and (b) abovc of this Paragraph shall be conducted in accordance with the

field test procedures prescribed by 40 CFR 52. 

# Appendices D and E to Part 52, Titlc 40, of thc

Codc of Fcdcral Rcgulations. The Director shall be notified at least 30 days in advance of the

start of the field tests.

d. Location of all sampling points 

# for monitoring sulfur dioxide concentrations and

stack gas volumetric flow rates shall be approved in writing by the Director prior to installation

and operation of measurement instruments.

e. The measurement systems) installed and used pursuant to this Paragraph

32Subsection shall be subject to the manufacturer’s recommended zero adjustment and calibration

procedures at least once per 24-hour operating period unless the manufacturer specifies or

recommends

calibration at shorter intervals, in which case specifications .or recommendations

shall be followed. Records of these procedures shall be made which clearly show instrument

readings before and after zero adjustment and calibration.

f L Failure of the owner or operator of a smelter subject to this Section to measure at

least 95 percent of the hours during which emissions occurred in any month shall constitute a

violation

of this Section.

g M Failure of the owner or operator of a smelter subject to this Section to measure

any

12 consecutive hours of emissions in accordance with the requirements of this Paragraph

Subsection (K) of this Section shall constitute a violation of this Section.

The owner or operator of any smelter subject to this Section shall maintain on

hand

and ready for immediate installation sufficient spare parts or duplicate systems for the

continuous monitoring equipment required by this Section to allow for the replacement within

six hours of any monitoring equipment part which fails or malfunctions during operation.

Q. As a means of determining total overall emissions, the owner or operator of any

smelter subject to this Section shall perform material balances for sulfur in accordance with the

procedures prescribed by Appendix 8.

L The owner or operator of any smelter subject to this Section shall maintain a

record

of all average hourly emissions measurements required to be measured by this Section.

The record of such emissions shall be retained for at least two years following the date of

measurement. Mcasurcmcnt rcsults All of the following measurement results shall be expressed

as pounds per hour of sulfur dioxidc. Thc following mcasurcmcnts nci shall be summarized

monthly and submitted to the Director within 14 days after the end of each month:

a. During thc initial 365-day pcriod dcscribcd in Paragraph 2 thc cumulativc

avcragc hourly cmissions as of thc last day of thc month.

L For all subscqucnt periods described in Paragraph 3 Subsection (C) of this

Section, the annual average emissions (expressed in pounds per hour) as calculated at the end of

each day of the month;

b 2 The total number of hourly periods during the month in which measurements

were not taken and of the reason-for loss of measurement for each period;

3 The number of three-hour emissions averages which exceeded each of the

applicable emissions levels listed in Paragraph 1 Ri 8-2--1471 5(F) for the compliance periods

ending on each day of the month being reported;

4. The date(s) on which a cumulative occurrence limit(s) listed in Paragraph 1 Ri 8-

2-447l5(F) was exceeded if such exceedance occurred during the month being reported.

6. Compliancc achcdulcs:

The owner or operator of a smelter subject to this Section shall, within 90 days

from thc datc on which thc Administrator approvcs this Subscction, submit a proposed

compliance schedule to the Director. Thc schcdulc shall which demonstrates that the emission

limits of Paragraph 1 Rl8-2--147151F) will be achieved at the smelter as expeditiously as

practicable,

but no later than the compliance date.

b R,. The schedule submitted pursuant to this Paragraph Subsection (Q) of this Section

33

# shall include increments of progress and the date for achievement of such increments. The

increments of progress shall include all of the following:

i L No later than 30 months prior to the compliance date, submission to the Director

of a final control plan for meeting the emission limits in Paragraph 1 Ri 8-2-414715(F);

4i- No later than 28 months prior to the compliance date, letting of contracts or

issuance of purchase orders for any process 

# aor control equipment necessary to accomplish

the required emission control;

i44 No later than 24 months prior to the compliance date, initiation of any necessary

on-site construction or initiation of any necessary installation of emission control equipment

ant or process modification;

ii 

# 4 No later than 24 months prior to the compliance date, submission of the fugitive

emissions evaluation prescribedin Paragraph 8. of this Section R18-2-515.02715.021B) through

Ri 8-2-515.02715.02(D), including a compliance plan for installation of any additional fugitive

emission control equipment necessary to assure attainment and maintenance of the applicable

ambient air quality standards in the vicinity of the smelter;

5 No later than 18 months prior to the compliance date, the initiation of the

demonstrations of stack gas volumetric flow rate and sulfur dioxide concentration measurement

systems required by subsections (K(5)(a) and (b).

No later than three months prior to the compliance date, completion of any

necessary on-site construction,

or installation of emission control equipment

ant 

# or process

modification; and

vii No later than the compliance date, achievement of compliance with the emission

limits in Paragraph 1 Ri 8-2-414715(F).

e $. The owner or operator shall certif’ to the Director, within 15 days after the

deadline for completion of each increment, whether the required increment of progress has been

met. 7. Intcrim operating rcquircmcnts:

•a. During the pcriod prior to thc complianec date (hcrcafkr called thc “interim

period”), thc owncr or operator of a smeltcr subject to this Scction shall comply with the

following emission limits by opcrating his sulfur removal equipment at its maximum feasible

cfficicncy

i. For the coppcr smeltcr of Inspiration Consolidated Copper Company, the sulfur

emission limit shall bc an avcragc of 85 tons pcr day in any calendar month.

ii. For thc copper smelter of Kcnnecott Copper Corporation, Ray Minc3 Division, thc

sulfur emission limit shall bc an average of 68 tons per clay in any calendar month.

iii. For the coppcr smelter of Magma Coppcr Company, San Manuel Division, the

sulfur cmission limit shall be an average of 448 tons per day in any calendar month.

iv. For the copper smelter of ASARCO Inc., Hayden, the sulfur emission limit shall

be an average of 301 tons per day in any calendar month.

v. For the copper smelter of Phelps Dodge Corporation, Douglas Reduction Works,

the sulfur emission limit shall be an average of 561 tons per day in any calendar month.

vi. For the copper smelter of Phelps Dodge Corporation, Morcnei Branch, the sulfur

emission limit shall be an average of 407 tons per day in any calendar month.V 

# 34

# vii. For the copper smelter of Phelps Dodge Corporation, New Comeia Branch, the

sulfur emission limit shall be an average of 89 tons per day in any calcndar month.

b.

Determination of compliance with the applicable emission limits in Subparagraph

a. during the intcrim pcriodshall bc ubjcct to the following conditions:

i. Thc emission limit shall apply to all process sulfur cmittcd into thc ambient air

from -smelter processing units and sulfur control and removal equipment. The total monthly

amount of sulfur emissions is equal to the weight of the total sulfur introduced into the smelting

process in any calendar month minus the weight of all sulfur removed from the smelter process

streams in that month in any physical form, plus or minus the weight of the sulfur contained in

any

month-to-month decrease or increase necessary to indicate materials in process. Removed

sulfur shall include but not be limited to sulfur contained in slag, blister copper, sulfuric acid,

liquifled sulfur dioxide, elemental sulfur, flue dust, precipitator dust, acid plant sludge, scrubber

effluent and absorption plant purge. All unremovcd sulfur, including fugitive sulfur emissions,

shall be considered as emissions to the ambient air.

ii. Material balances for sulfur described in Subdivision i. above shall be obtained in

accordance with procedures listed in Appendix 8.

iii. Compliance with the average daily emission limits established by Subparagraph a.

is to be determined by dividing the total monthly emissions calculated under Subdivision i.

above

by the number of operating days in the particular month.

iv. Each o’wncr or operator oi a copper smelter subject to sri emission limit under this

paragraph shall report to the Director not later than the fifteenth day of each month, the smelter

material balance or mcamircd sulfur dioxide stack emissions and ambient sulfur dioxide data for

the preceding calendar month as required by the operating permit for the smelter.

I. At each point in the smelter facility where a means exists to bypass the sulfur

removal equipment, such bypass shall be instrumented and monitored to detect and record all

periods that the bypass is in operation. Each owner or operator of a copper smelter shall report to

the Director, not later than the fifteenth day of each month, the information required to be

recorded

by this Paragraph Section. Such report shall include an explanation for the necessity of

the use of the bypass. R18-2-515.02715.02 Standards of performance for existing primary copper

smelters: Fugitive emissions

j For purposes of this Section. the compliance date, unless otherwise provided in a

consent

decree or a delayed compliance order, shall be January 14, 1986.

8. Fugitive emissions evaluation:

a . 

# No later than 24 months before the compliance date the owner or operator of a

smelter

subject to this Section Ri 8-2414715, shall submit to the Director the results of an

evaluation of the fugitive emissions from the smelter. The evaluation results shall contain all of

the following information:

i .j A measurement or accurate estimate of total fugitive emissions from the smelter

during typical operations, including planned start-up and shutdown. The measurement or

estimate

shall contain the amount of both average short-term (24 hours) and average long-term

(monthly) fugitive emissions from the smelter. The evaluation plan shall be approved in advance

by the Bureau Department and shall speciIy the method used to determine the fugitive emission

35

# amounts, including the conditions determined to be “typical operations” for the smelter.

4i2 A measurement or accurate estimate of the relative proportions (expressed

as a

percentage) of total fugitive emissions during typical operations, including planned start-up and

shutdown, produced by any of the following smelter processes:

Roaster or dryer operation;

Calcine or dried concentrate transfer;

Reverberatory furnace operations (including feeding, slag return, matte and slag

tapping); Matte transfer; and Converter operations.

I. The measurement technique

or method of estimation used to fuffill thia th

requirement in Paragraph 2. of this Subsection shall be approved in advance by the Bureau

Department. iii 4. The results of at least a 6-month fugitive emission impact analysis conducted

during that part of the year when fugitive emissions

are expected to have the greatest ambient air

quality impact. The study shall utilize sufficient measurements of fugitive emissions,

meteorological conditions and ambient sulfur dioxide concentrations to associate fugitive

emissions with specific measured ambient concentrations of sulfur dioxide. The study shall

describe in detail the techniques used to make the required determinations. The design of the

study shall be approved in advance by the Burcau Department.

b C. On the basis of the results of the evaluation as well as other data and information

contained in the records of the Burcau Department, the Director shall determine whether fugitive

emissions from a particular smelter have the potential to cause or significantly contribute to

violations of the ambient sulfur dioxide standards in the vicinity of the smelter. If the Director

finds that fugitive emissions from a particular smelter have the potential to cause or significantly

contribute to violations of ambient sulfur dioxide standards in the vicinity of a smelter, then the

Director shall, no later than 18 months before thc compliance date, adopt Rcgulations rules

specifying the emission limits or and undertake other appropriate

measures necessary to maintain

ambient sulfur dioxide standards.

. 

# The requirements of this Paragraph Subsection (B) of this Section shall not apply

to a smelter subject to this Section if the owner or operator of that smelter can demonstrate to the

Director both that:V



# 4 .L Compliance with the applicable cumulative occurrence and emission limits listed

in Paragraph 1 Ri 8-2-715(F). will require the smelter to undergo major modifications to its

physical conliguration nd?or work practices prior to the compliance date, and

ii 2.. That the modification(s) will reduce fugitive emissions to such an extent that such

emissions will not cause or significantly contribute to violations of ambient sulfur dioxide

standards in the vicinity of the smelter.

9 L In order to assess the sufficiency of the cumulative occurrence and emission limits

contained in Paragraph 1. of this Subscction Ri 8-2-715(F) to maintain the ambient air quality

standards for sulfur dioxide set forth in Ri 8-2-202, an owner or operator of a smelter subject to

this Section shall continue to calibrate, maintain and operate any ambient sulfur dioxide

monitoring equipment owned by the smelter owner or operator and in operation within the

36V

# • dcsignatcd liability area of the smelter enclosed by a circle with ten-mile radius as calculated

from a center point which shall be the point of the smelter’s greatest sulfur dioxide emissions,

en

thc cffcctivc datc of this Scction for thc intcrim 

# pcriod and for a period of at least three years

after the compliance date.

Such monitors shall be operated and maintained in accordance with Parts 40 CFR

50 and 58, Titlc 40 of the Codc of Federal Regulations and such other conditions

as the Director

deems necessary.

2 The location of ambient sulfur dioxide monitors and length of time such monitors

remain at a location shall be determined by the Director.

R18-2-51-6Zi. Standards of performance for existing coal preparation

plants

A. The provisions of this Section are applicable to any of the following affected

facilities in coal preparation plants: Thermal thermal dryers, pneumatic coal-cleaning equipment

(air tablca), coal processing and conveying equipment including breakers and crushers, coal

storage systems, and coal transfer and loading systems. This Scction is applicabic to all coal

preparation plants which arc existing sources. For purposes of this Section, the definitions

contained in 40 CFR 60.251 are adopted by reference and incorporated herein.

No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from any existing coal preparation plant locatcd in total

quantities in excess of the amounts calculated by one of the following equations act forth bclow:

a L For process sources having a process weight rate of 60,000 pounds per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E = 

# 4.1OP° 67

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b 2 For process sources having a process weight rate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: E=55.0P°-40

where “E” and “P” are defined as indicated in A.1.a. above Paragraph (1) of this Subsection.

For reference purposes only, the equations in A. 1. above Subsection (B) of this

Section are plotted in Figure 2, Appendix 11. The emission values obtained from the graph are

approximately correct for the process weight rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

..



# For purposes of this Rule Section, the total process weight from all similar units

employing

a similar type process shall be used in determining the maximum allowable emission

of particulate matter.

4. Thc opacity of any emission subject to thc provisions of this Scction shall not

exceed 40 percent.

L Fugitive emissions from coal preparation plants shall be controlled in accordance

with Ri 8-2-4O44 through Ri 8-2-4O7. 37

# B; The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Tcsting Manual 40 CFR 60. Appendix A

are used to determine compliance with standards prescribed in Subsection A. above (B) of this

Section as follows:

a. Method 5 for the concentration of particulate matter and associated moisture

content. b. Method 1 for sample and velocity traverses;,

c.

Method 2 for velocity and volumetric flow rate 5 -an&

d. Method 3 for gas analysis.

2. For MethodS, the sampling time for each run Ia shall be at least 60 minutes and

the minimum sample volume is 0.85 dscm (30 dscf) except that short sampling times or smaller

volumes, when necessitated by process variables or other factors may be approved by the

Director. Sampling Ia hall not to be started until 30 minutes after start-up and Is-to shall be

terminated before shutdown procedures

commence. The owner or operator of the affected facility

shall eliminate cyclonic flow during performance tests in a manner acceptable to the Director.

3. The owner or operator shall construct the facility so that particulate emissions

from thermal dryers or pneumatic coal cleaning equipment can be accurately determined by

applicable test methods and procedures under B.1. above Paragraph (1) of this Subsection.

R18-2-514fl2. Standards of performance for steel plants: existing

electric arc furnaces (EM?)

A. The provisions of t.his Section arc applicable to the following affcctcd facilities in

stccl plants which arc cxisting sources: Electric arc furnaces and dust-handling cquipmcnt.

A No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from electric arc furnaces or dust-handling equipment which

are affected facilities in any steel plant located in total quantities in excess of the amount

calculated by one of the following equations set forth below:

a i For process sources having a process weight rate of 60,000 pounds per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E = 

# 4.1OP° 67

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b For process sources having a process weight rate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: E = 

# 55.0P 0 -40

where “E” and “PH are defined as indicated in A.l.a. above Paragraph (1) of this Subsection.

27 

# For reference

purposes only, the equations given above are plotted in Appendix

11, Figure 2. The emission values obtained from the graph are approximately correct for the

process weight rates shown. However, the actual values shall be calculated from the applicable

equations and rounded off to two decimal places.

For purposes of this Rule Section, the total process weight from all similar units

38

# employing a similar type process shall be used in determining the maximum allowable emission

of particulate matter.

4 ).. An opacity standard of forty 

# 4Q percent shall not be exceeded by existing steel

plant electric arc furnaces and their appurtenances for more than an aggregate of three minutes in

any forty-five 

# 4 minute period.



# L Emission monitoring required by this Scction is as follows: A continuous

monitoring system for the measurement of the opacity of emissions discharged into the

atmosphere from the control devices shall be installed, calibrated, maintained, and operated by

the owner or operator subject to the provisions of this Section.

G 

# L The test methods and procedures required under this Section are as follows:

1. Reference methods in the Arizona Testing manual 40 CFR 60. Appendix A shall

be used to determine compliance with the standards prescribed under Subsection (A) above f

this Section as follows:

a. Method 5 for concentration of particulate matter and associated moisture content.

b. Method 1 for sample and velocity and volumetric flow rate; and

c. Method 2 for velocity and volumetric flow rate; an&

d. Method 3 for gas analysis.

2. For MethodS, the sampling time for each run shall be at least four hours. When a

single EAF is sampled, the sampling time for each run shall also include an integral number of

heats. Shorter sampling times, when necessitated by process variables

or other factors, may be

approved by the Director. The minimum sample volume shall be 4.5 dscm (160 dscf).

Rl8-2-&t&2i. Standards of performance for existing kraft pulp mifis

A. The provisions of this Section

are applicable to the following affected facilities in

efra krafl pulp mills: digester system brown stock washer system, multiple-effect evaporator

system, black liquor oxidation system, recovery furnace, smelt dissolving tank, lime kiln, and

condensate stripper system. In pulp mills in which kraft pulping is combined with neutral sulfite

semichemical pulping, the provisions of this Section are applicable when any portion of the

material charged to an affected facility is produced by the kiafl pulping operation. Thc provisions

of this Section arc applicable only to kraft pulp mills which nrc existing sources.

4

.. 

# No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from any kraft pulp mill process source located in total

quantities in excess of the amounts calculated by one of the following equations set forth below:

L For process sources having a process weight rate of 60,000 pounds per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E 4.1OP° 67

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b 2 For process sources having a process weightrate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: 0 1

E=55.OP



# . 140 39

# where “E” and “P” are defined

as indicated in A.1.a. above Paragraph (1) of this Subsection.

..



# For reference

purposes only, the equations set forth abovc in Subsection (B) of

this Section are plotted in Appendix 11, Figure 2. The emission values obtained from the graph

are approximately correct for the process weight rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.



# fl... For purposes of this Rule Section, the total process weight from all similar units

employing

a similar type process shall be used in determining the maximum allowable emission

of particulate matter.

4. No person shall cause, suffer, allow or permit to be emitted to the atmosphere

from any affcctcd facility undcr this Section, smoke or other emission which exceeds 40 percent

opacity. 5. The standards for total reduced sulfur mcasurcd

as hydrogen 3ulfidc (112S)

utilizing Method II in the Arizona Testing manual

arc:

a

L No person shall cause, suffer, allow or permit the discharge of 112S total reduced

sulfur measured

as hydrogen sulfide (H$.) in excess of the following amounts:



# L From any recovery furnace,

any gases which contain H 2 S in excess of 20 ppm by

volume corrected to eight percent oxygen.

4i 2 From any lime ki1n 

# kiin any gases which contain H 2 S in excess of 40 ppm by

volume corrected to 4G 

# n percent oxygen.

B. Monitoring of emissions and operations required by this Section is as follows:

Any owner or operator subject to the provisions of this Section shall install,

calibrate, maintain, and operate the following continuous monitoring systems:

1. A continuous monitoring system to monitor and record the opacity of the gases

discharged into the atmosphere from any recovery furnace. The span of this system shall be set at

70 percent opacity.

b 2 A continuous monitoring system, to monitor and record the concentration of H 2 S

emissions discharged into the atmosphere from any recovery furnace or lime kiln. The span shall

be set at H 2 S concentration of 50 ppm.

e

3., A continuous monitoring system to monitor and record the percent of oxygen by

volume in the gases discharged from any recovery furnace or lime kiln. The continuous

monitoring system shall be located downstream of the control devices for the recovery furnace

or lime kiln, and all measurements shall be made on a dry basis. The span of this system shall be

set at 20 percent oxygen.

& 4., For any lime kiln or smelter dissolving tank using a scrubber emission control

device: , 

# A monitoring device for the continuous measurement of the pressure loss of the

gas stream through the control equipment. The monitoring device is-ta shall be certified to the

manufacturer to be accurate within a gage pressure of± 500 pascals (Ca. ±2 inches of water gage

pressure). A monitoring device for the continuous measurement of the scrubbing liquid

supply pressure to the control equipment. The monitoring device imte shall be certified by the

manufacturer to be accurate within ± 15 percent of design scrubbing liquid supply pressure. The

pressure sensor or tap is-te shall be located close to the scrubber liquid discharge point,. The

40

# although the Director

may be consulted for approval of alternative locations.

j. The test methOds and procedures required by this Section

are as follows:

1. Reference methods in the Arizona Testing Manual 40 CFR 60. Appendix A

except as provided under Scction Ri 8-2-3127 shall be used to determine compliance with

Subsection A. and B. above this Section

as follows:

a.

Method 5 for the concentration of particulate matter and the associated moisture

content. b. Method 1 for sample and velocity traverses.

c.

Method 3 for gas analysis, and

d. Method 9 for visible emissions.

e. Method 11 for total reduced sulfur as hydrogen sulfide.

2. For Method 5, the sampling time for each run shall be at least 60 minutes and the

sampling rate shall be at least 0.85 dscmlhr (0.53 dscf7min) except that shorter sampling times,

when necessitated by process variables

or other factors, may be approved by the Director. Water

shall be used as the cleanup solvent instead of acetone in the sample recovery procedure outlined

in Method 5. For determination of compliance with this Section, particulate measurements shall

at least be made on the recovery fumaces, smelt dissolving tanks), and lime ki1n(s. all AI

concentrations of particulate matter from the lime kiln and recovery furnace shall be corrected to

4-G volume percent oxygen and B eight volume. percent oxygen, respectively, when the

oxygen concentrations exceed these values.

Ri 8-2-592i. Standards of performance for existing stationary

rotating machinery

A. The provisions of this Section

are applicable to the following affected facilities:

all stationary

gas turbines, oil-fired turbines,

or internal combustion engines which

arc existing

sources. This Section also applies to an installation operated for the purpose of producing electric

or mechanical

power with a resulting discharge of sulfur dioxide in the installation’s effluent

gases. . 

# For purposes of this Section, the heat input shall be the aggregate heat content of

all fuels whose products of combustion

pass through a stack or other outlet. Compliance tests

shall be constructed conducted during operation at the normal rated capacity of each unit. The

total heat input of all operating fuel-burning units on a plant or premises shall be used for

determining the maximum allowable amount of particulate matter which may be emitted.

2. The standards for particulate matter undcr this Section are:

. 

# No person shall cause, suffer, allow or permit the emission of particulate matter,

caused by combustion of fuel, from any stationary rotating machinery in excess of the amounts

calculated by one of the following equations. presented below.

4 L for equipment having

a heat input rate of 4200 million Btu per hour or less,

the maximum allowable emisQjshal1 be determined by the following equation:

E=1.02Q

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.



# Q

= 

# the heat input in million Btu per hour.

447 2 For equipment having

a heat input rate greater than 4200 million Btu/hr., the

41

# maximum allowable emission 8 

# ll be determined by the following equation:

E17.0Q’

where ‘E” and “Q” have the same meaning

as in A.2.a.i. above Paragraph (1) of this Subsection.

j For reference

purposes only, the two equations in A.2.a. abovc Subsection (C) of

this Section are plotted in Appendix 11, Figure 1. The emission values obtained from the graph

are approximately correct for the heat input rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

e Notwithstanding thc provisions of Ri 8-2-501, no person shall cause, suffer,

allow or permit to be emitted into the atmosphere from any stationary rotating machinery, smoke

for any period greater than ten consecutive seconds which exceeds 40 percent opacity. Visible

emissions when starting cold equipment shall be exempt from this requirement for the first ten

minutes. 3. Thc standard for sulfur dioxide undcr this Section is:

a.

This Section applies to an installation opcratcd for thc purpoac of producing

clcctric or mechanical

power with a rcsulting discharge of sulfur dioxide in the installation’s

effluent gases. When low sulfur oil is fired. Stationary rotating machinery installations which

arc existing

sources 

# shall bum fuel which limits the emission of sulfur dioxide to 1.0 pound per

million Btu heat input when low sulfur oil is fired.

When high 

# sulfur oil is fired. Stationary 

# rotating machinery installations which

arc existing sources shall not emit more than 2.2 pounds of sulfur dioxide per million Btu heat

input when high 

# sulfur oil is fired.

j Any permit issued for the operation of an existing

source, or any renewal

or

modification of such a permit, shall include

a condition prohibiting the use of high sulfur oil by

the permittee, unless This condition

may not be included in the permit if the applicant

demonstrates to the satisfaction of the Director ith that sufficient quantities of low sulfur oil are

not available for use by the source; and that it has adequate facilities and contingency plans to

insure that the sulfur dioxide ambient air quality standards set forth in Ri 8-2-202 will not be

violated. L The terms of the permit may authorize the use of high sulfur oil under such

conditions

as are justified.

2 In cases where the permittee is authorized to use high sulfur oil it shall submit to

the Department monthly reports detailing its efforts to obtain low sulfur oil,

3,. When the conditions justifying the use of high sulfur oil no longer exist, the

permit shall be modified accordingly.

Nothing in this Section shall be construed

as allowing the use of a supplementary

control system or other form of dispersion technology.

c. For purposes of this Rule, low sulfur oil means fuel oil containing less than 0.90

percent by weight of sulfur and high sulfur oil means fuel oil containing 0.90 percent or more by

weight of sulfur.

B. Monitoring 

# of operations required by this Section is as follows

1-; L The owner or operator of any stationary rotating machinery subject to the

provisions of this Section shall record daily the sulfur content and lower heating value of the fuel

42

# being fired in the machine.

2 

# L The owner or operator of any stationary rotating machinery subject to the

provisions of this Section shall report to the Director any daily period during which the sulfur

content of the fuel being fired in the machine exceeds 0.8 percent.

€ K. The test methods and procedures required by this Section are as follows:

1. Thc rcfcrcncc methods in the Arizona Testing Manual shall bc used to 12

determine compliance with the standards prescribed in A.2. and A.3. above as follows

Subsections (C) through (H’) of this Section. the following reference methods shall be used:

a.

Reference Method 20 in 40 CFR 60. Appendix A for the concentration of sulfur

dioxide and oxygen.

b. ASTM Method D-2880-71 D-129-91 (Test Method for Sulfur in Petroleum

Products (General Bomb Method) for the sulfur content of liquid ffie1s and

c.

ASTM Method D-l072-090 (Test Method for Total Sulfur in Fuel Gases) of f

the sulfur content of gaseous fuels. Thcsc mcthod3 shall also bc used to comply with B.2. above.

To determine compliance with the standards prescribed in Subsection (J’) of this

Section. the following reference methods in the Arizona Testing Manual shall be used:

a.

ASTM Method D-129-91 (Test Method for Sulfur in Petroleum Products)

(General Bomb Method) for the sulfur content of liquid fuels.V



# ASTM Method D-l 072-90 (Test Method for Total Sulfur in Fuel Gases) for the

sulfur content of gaseous fuels.

R18-2-54Ji2fl. Standards of performance for existing lime manufacturing

plants

A. The provisions of this Section are applicable to the following affected facilities

used in the manufacture of lime: rotary lime kilns, vertical lime kilns, lime hydrators, and

limestone crushing facilities which arc cxisting sourccs. This Section is also applicable to

limestone crushing equipment which exists apart from other lime manufacturing facilities.



# ,

No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from any lime manufacturing of limestone crushing

facility in total quantities in excess of the amounts calculated by one of the following equations

act forth bclow:

a j 4

. For process sources having a process weight rate of 60,000 pounds per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: B = 

# 4.1OP°’ 67

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b 2 For process sources having a process weight rate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: E = 

# 55.OP°’ 1 140

where “B” and “Pa are defined as indicated in A.l.a. above Paragraph (1) of this Subsection..



# For reference purposes only, the equations in A.l. above Subsection (B) of this

43Section are plotted in Appendix 11, Figure 2. The emission values obtained from the graph are

approximately correct for the process weight rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

3-. For purposes of this Rule Section, the total process weight from all similar units

employing a similar type process shall be used in determining the maximum allowable emission

of

particulate matter.

4. Notwithstanding the provisions of Ri 8-2-501, no person shall cause, suffer, allow

or

permit to be emitted into the atmosphere from any lime manufacturing or limestone crushing

facility smoke or dust which exceeds 40 pcrecnt opacity.

& .. Fugitive emissions from lime manufacturing plants shall be controlled in

accordance with Ri 8-2-4O4Q4 through Ri 8-2-40%02.

B. Monitoring of cmissions and operations rcguircd by this Section is as follows:

4-;. 

# L The owner or operator subject to the provisions of this Section shall install,

calibrate, maintain, and operate a continuous monitoring system, except as provided in B2

below

Subsection (G) of this Section, to monitor and record the opacity of the gases discharged

into the atmosphere from any rotary lime kiln. The span of this system shall be set at 70 percent

opacity. The owner or operator of any rotary lime kiln using a wet scrubbing emission

control device subject to the provisions of this Section shall not be required to monitor the

opacity of the gases discharged as required in B.l.abovc Subsection (F) of this Section.

G R± The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Testing Manual 40 CFR 60. Appendix A

shall

be used to determine compliance with Subsections A. and B. above this Section as follows:

a. Method 5 for the measurement of particulate maffer

b. Method 1 for sample and velocity traverses.

c. Method 2 for velocity and volumetric flow rate

d. Method 3 for gas analysis;

e. Method 4 for stack gas moisture, and

f. Method 9 for visible emissions.

2. For Method 5, the sampling time for each run shall be at least 60 minutes and the

sampling rate shall be at least 0.85 dscmlhr (0.53 dscf7min), except that shorter sampling times,

when necessitated by process variables or other factors, may be approved by the Director.

3. Because of the high moisture content (40 to 85 percent by volume) of the exhaust

gases

from the hydrators, in the range of 40 to 85 percent by volume, the Method 5 sample train

may

be modified to include a calibrated orifice immediately following the sample nozzle when

testing

lime hydrators. In this configuration, the sampling rate necessary for maintaining

isokinetic conditions can be directly related to exhaust gas velocity without a correction for

moisture content. Extra care should be exercised when cleaning the sample train with the orifice

in

this position following the test runs.

R18-2-5217i. Standards of performance for existing nonferrous metals

industry sources

A. The provisions of this Section are applicable to the following affected facilities:

mines, mills, concentrators, crushers, screens, material handling facilities, fine ore storage,

44

# dryers, roasters, and loaders which arc existing sourccs.

4- ]j. No person shall cause, suffer, allow or permit the discharge of particulate matter

into the atmosphere in any one hour from any process source subject to the provisions of this

Section in total quantities in excess of the amounts calculated by one of the following equations

3ct forth bclow:

a 

# L For process sources having a process weight rate of 60,000 pounds per hour (30

tons per hour) or less, the maximum allowable emissi6ns shall be determined by the following

equation: E = 

# 4.l0P°

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b 2 For process sources having a process weight greater than 60,000 pounds per hour

(30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: 1



# E

= 

# 55.0P° ‘-40

where

HEll and “F’ are defined as indicated in A. l.a. abovc Paragraph (1) of this Subsection.

,



# For reference

purposes only, the equations in A.l. abovc Subsection (B) of this

Section are plotted in Appendix 11, Figure 2. The emission values obtained from the graph are

approximately correct for the process weight rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

3-:. P.. For purposes of this Rule Section, the total process weight from all similar units

employing

a similar type process shall be used in determining the maximum allowable emission

of particulate matter.

4. No pcrson shall causc, suffer, allow or pcrmit thc discharge of any emissions frorr

any mining property process or nonpoint

sourcc subjcct to thc provisions of this Section, dust or

smoke that exceeds 40 pcrccnt opacity.

B L No person shall cause, suffer, allow or permit to be discharged into the

atmosphere from any dryer or roaster the operating temperature of which exceeds 700° F.,

reduced sulfur, which includes sulfur equivalent from all sulfur cmissions including but not

limited to sulfur dioxide, sulfur trioxidc and sulfuric acid, in excess often percent of the sulfur

entering the process as feed. Reduced sulfur includes sulfur equivalent from all sulfur emissions

including sulfur dioxide, sulfur trioxide. and sulfuric acid.

C. Monitoring of opcrations required by this Section arc:

-1-: 

# L The owner or operator of any mining property subject to the provisions of this

Section shall record the daily process rates and hours of operation of all material handling

facilities. 2- A continuous monitoring system for measuring sulfur dioxide emissions shall be

installed, calibrated, maintained and operated by the owner or operator where dryers or roasters

are not expected to achieve compliance with the standard under Subsection B- (1 of this Section.

D [j The test methods and procedures required by this Section

are as follows:

1. The reference methods in the Arizona Testing Manual 40 CFR 60, Appendix A

shall be used to determine compliance with the standard prescribed in Subsections A. and B.

45

# abovc this Section

as follows:

a. Method 5 for the concentration of particulate matter and the associated moisture

content b. Method I for sample and velocity traverses

c.

Method 2 for velocity and volumetric flow ratc; and

d. Method 3 for gas analysis and calculation of excess air, using the integrated

sample technique.

e. Method 6 for concentration of SO 2

.

2. For Method 5, Method 1 shall be used to select the sampling site and the number

of traverse sampling points. The sampling time for each run shall be at least 60 minutes and the

minimum sampling volume shall be 0.85 dscm (30 dscf) except that smaller sampling times or

volumes, when necessitated by process variables

or other factors, may be approved by the

Director. The probe and filter holder heating systems in the sampling train shall be set to provide

a gas temperature no greater than 1600 C.(320° F.).

3. For Method 6, the sampling site shall be the same as that selected for Method 5.

The sampling point in the duct shall be at the centroid of the cross section

or at a point no closer

to the walls than 1 m (3.28 ft.). For Method 6, the sample shall be extracted at a rate proportional

to the gas velocity a L the sampling point.

4. For Method 6, the minimum sampling time shall be 20 minutes and the minimum

sampling volume 0.02 dscm (0.71 dscf) for each sample. The arithmetic

mean of two samples

shall constitute

one run. Samples shall be taken at approximately 30-minute intervals.

R18-2-s222a2. Standards of performance for existing gravel or crushed

stone processing plants

A. The provisions of this Section are applicable to the following affected facilities:

Primary primary rock crushers, secondary rock crushers, tertiary rock crushers,

screens,

conveyors and conveyor transfer points, stackers, reclaimers, and all gravel or crushed stone

processing plants and rock storage piles which arc cxisting 3ourccs.

4- No person shall cause, suffcr, allow or permit the discharge of particulate matter

into the atmosphere except as fugitive emissions in any one hour from any gravel or crushed

stone processing plant in total quantities in excess of the amounts calculated by one of the

following equations sct forth bclow:

a L For process sources having a process weight rate of 60,000 pounds

per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E=4.l0P° ‘



# where: E the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

2

For process sources having

a process weight rate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: E = 

# 5 S.OP° 140

where “E” and

lip” 

# are defined as indicated in A.l.a. above Paragraph (1) of this Subsection.

46

# For reference

purposes only the equations in A.1. above Subsection (B) of this

Section are plotted in Appendix 11, Figure 2. The emission values obtained from the graph are

approximately correct for the process weight rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

] Notwithstanding the provisions of Section 1U8-2-501,

no person shall cause,

suffcr, allow or permit to be emitted into the atmosphere from any gravel or crushed stone

proccssng plant, smokc or dust that cxcccds 40 pcrccnt opacity. Spray bar pollution controls

shall be utilized in accordance with IEPA Control of Air Emissions From Process Operations In

The Rock Crushing Industry. (EPA 340/1-79-002), Wet Suppression System (pp pages 15-

34). amended

as of January. 1979 (and no future amendments

or editions),

as incorporated herein

by reference and on file with the Office of the Secretary of State, with placement of spray bars

and nozzles as required by the Director to minimize air pollution.

Fugitive emissions from gravel or crushed stone processing plants shall be

controlled in accordance with Sections Ri 8-2-4O44 through Ri 8-2-.4O-72.

B. Monitoring of operations required by this Section is as follows:

+ F. The owner or operator of any affected facility subject to the provisions of this

Section shall install, calibrate, maintain, and operate monitoring devices which can be used to

determine daily the process weight of gravel

or crushed stone produced. The weighing devices

shall have an accuracy of +1- tiy percent over their operating

range.

2 .(j The owner or operator of any affected facility shall maintain

a record of daily

production rates of gravel or crushed stone produced.

C; IL The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Testing Manual 40 CFR 60, Appendix A

shall be used to determine compliance with the standards prescribed in Subsection A. above

Section as follows:

a. Method 5 for concentration of particulate matter and moisture content.

b. Method 1 for sample and velocity traverses;.,

c. Method 2 for velocity and volumetric flow rate, and

d. Method 3 for gas analysis.

2. For Method 5, the sampling time for each run is shall be at least 60 minutes and

the minimum sample volume is 0.85 dscm (30 dscf) except that shorter sampling times or

smaller volumes, when necessitated by process variables

or other factors, may be approved by

the Director. Sampling is shall not to be started until 30 minutes after start-up and is-to shall be

terminated before shutdown procedures

commence. The owner or operator of this thc. affected

facility shall eliminate cyclonic flow during performance tests in a manner acceptable to the

Director. R18-2-5232. Standards of performance for existing concrete batch

plants

A. The provisions of this Scction arc applicable to all concrete batch plants under

State of Arizona jurisdiction which have the capability of emitting more than 100 tons per year of

air contaminants and which arc existing

sources.

B

Fugitive dust emitted from affected concrete batch plants shall be controlled in

accordance with Sections Ri 8-2-4O4.Q4 through Ri 8-2-4OZ. Visible cmis3ions from affected

47

# concrete batch plants shall bc controlled in accordance with Scetion Ri 8-2-501.

R18-2-5242Z4. Standards of performance for fossil-fuel fired

industrial and commercial equipment

A. This Section applies to industrial and commercial installations which are less than

73 megawatts capacity (250 million British thermal units per hour);. but in the aggregate on any

premises are rated at greater than 500,000 British thermal units per hour (0.146 megawatts) and

in which fuel is burned for the primary purpose of producing steam, hot water, hot air or other

liquids, gases or solids and in the course of doing so the products of combustion do not come

into direct contact with process materials. When any products or byproducts of a manufacturing

process are burned for the same purpose or in conjunction with any fuel, the same maximum

emission limitations shall apply.

B. For purposes of this Section, the heat input shall be the aggregate heat content of

all fuels whose products of combustion

pass through a stack or other outlet. The heat content of

solid fuel shall be determined in accordance with Scction Ri 8-2-310. Compliance tests shall be

conducted during operation at the nominal rated capacity of each unit. The total heat input of all

fuel-burning units on a plant or premises shall be used for detennining the maximum allowable

amount of particulate matter which may be emitted.

C. The standards for particulate matter undcr this Scction arc as fo1lows

C No person shall cause, suffer, allow or permit the emission of particulate matter,

caused by combustion of fuel, from any fuel-burning operation in excess of the amounts

calculated by one of the following equations prc3cntcd below:

j For equipment having a heat input rate of 4200 million Btu per hour or less, the

maximum allowable emission 8 ll be determined by the following equation:

E=1.02Q

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

Q

= 

# the heat input in million Btu per hour.

For equipment having a heat input rate greater than 4200 million Btulhr, the

maximum allowable emission 8 9l be determined by the following equation:

E=17.OQ

where “E” and “Q” have the same meanings

as in C.i.a. above Paragraph (1) of this Subsection.

.



# For reference

purposes only, the two equations in C. I. above Subsection (C) of

this Section are plotted in Appendix 11, Figure 1. The emission values obtained from the graph

are approximately correct for the heat input rates shown. However, the actual values shall be

calculated from the applicable equations and rounded off to two decimal places.

D. The standards for sulfur dioxide under this Section arc as follows

L

Fossil-fuel fired industrial and commercial equipment installations which arc

cxi3ting sources shall not emit more than 1.0 pounds of sulfur dioxide per million Btu heat input

when low sulfur oil is fired.

2 ,. 

# Fossil-fuel fired industrial and commercial equipment installations which arc

existing sources shall not emit more than 2.2 pounds of sulfur dioxide per million Btu heat input

when high sulfur oil is fired.

i. Any permit issued for the operation of an existing source, or any renewal or

48

# modification of such a permit, shall include

a condition prohibiting the use of high sulfur oil by

the permittee., unless This condition

may be omitted from the permit if the applicant

demonstrates to the satisfaction of the Director 

# hs.th that sufficient quantities of low 

# sulfur oil are

not available for use by the source; and that it has adequate facilities and contingency plans to

insure that the sulfur dioxide ambient air quality standards set forth in Scction Ri 8-2-202 will

not be violated.

L The terms of the permit may authorize the use of high sulfur oil under such

conditions

as are justified.

2 In cases where the permittee is authorized to use high sulfur oil it shall submit to

the Department monthly reports detailing its efforts to obtain low sulfur oil.

3. When the conditions justifying the use of high sulfur oil no longer exist, the

permit shall be modified accordingly.

Nothing in this Section shall be construed

as allowing the use of a supplementary

control system or other form of dispersion technology.

4. For purposes of this Rule low sulfur oil means fuel oil containing lcss than 0.90

pcrccnt by weight of sulfur and high sulfur oil mcans fuel oil containing 0.90 percent or more by

weight of sulfur.

5 IL When coal is fired. Efossil-fuel fired industrial and commercial equipment

installations which arc cxistmg 3OUCC3 

# shall not emit more than 1.0 pounds of sulfur dioxide per

million Btu heat input when coal is flrcd.

E. Emission monitoring rcquircd by this Scction is as follows:

4- L The owner or operator subject to the provisions of this Section shall install,

calibrate, maintain and operate a continuous monitoring system for measurement of the opacity

of emissions discharged into the atmosphere from the control device(s).

2 J For the purpose of reports required under excess emissions reporting required by

Section Ri 8-2-3443iQ, the owner or operator shall report all six-minuteperiods in which the

opacity of any plume or effluent exceeds 15 percent.

F: The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Testing Manual 40 CFR 60. Appendix A

shall be used to determine compliance with the standards

as prescribed in Subsections C., D., and

E. above this Section.

a. Method 1 for selection of sampling site and sample traverses;

b. Method 3 for gas analysis to be used when applying Reference Methods 5 and 6.

c. Method 5 for concentration of particulate matter and the associated moisture

content. d. Method 6 for concentration of SO 2

.

2. For Method 5, Method 1 shall be used to select the sampling site and the number

of traverse sampling points. The sampling time for each run shall be at least 60 minutes and the

minimum sampling volume shall be 0.85 clscm (30 dscf) except that smaller sampling times or

volumes, when necessitated by process variables

or other factors, may be approved by the

Director. The probe and filter holder heating systems in the sampling train shall be set to provide

a gas temperature no greater than 160° C. (320° F.).

3. For Method 6, the sampling site shall be the same as that selected for Method 5.

49

# The sampling point in the duct shall be at the centroid of the cross section or at a point no closer

to the walls than 1 m (3.28 fI). For Method 6, the sample shall be extracted at a rate proportional

to the gas velocity at the sampling point.

4. For Method 6, the minimum sampling time shall be 20 minutes and the minimum

sampling volume 0.02 dscm (0.71 dscf) for each sample. The arithmetic mean of two samples

shall constitute one run. Samples shall be taken at approximately 30-minute intervals.

5. Gross calorific value shall be determined in accordance with the applicable

ASTM methods. D-2015-66(72)9l (Test for Gross Calorific Value of Solid Fuel by the

Adiabatic Bomb Calorimeter) fr solid fuels), D-240-64(73)87 (Test Method for Heat of

Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter) f liquid fuels), oi 

# D

1826-64(70)88 (Test Method for Calorific Value of Gases in Natural Gas Range by Continuous

Recording Calorimeter) ftr gaseous fuels) as applicable. The rate of fuels burned during each

testing period shall be determined by suitable methods and shall be confirmed by a material

balance over the fossil-fuel fired system.

R18-2-5252. Standards of performance for existing dry cleaning

plants

A. This Scction is applicable to all dry elcaning plants which arc cxisting

sources.



# j. Dry cicaning plants utilizing chlorinated synthetic solvcnts: No person shall

conduct any dry cleaning operation using chlorinated synthetic solvents without minimizing

organic solvent emissions by good modem practices including but not limited to the use of an

adequately sized and properly maintained activated carbon absorber or other equally effective

control device.

( .. 

# Dry cicaning plants utilizing petroleum solvcnts: No person shall operate any dry

cleaning establishment using petroleum solvents other than Stoddard, 140 (safety solution) or

other non-photochemically reactive solvents without reducing solvent emissions by at least 90

percent. For purposes of this Subsection,

a photochemically reactive solvent shall be any solvent

with an aggregate of more than twenty percent of its total volume composed of the chemical

compounds classified in Paragraphs (1) through (3) of this Subsection,

or which exceeds any of

the following percentage composition limitations, referred to the total volume of solvent:

A combination of the following types of compounds having an olefinic or cvclo

olefinic type of unsaturation

-- 

# hydrocarbons, alcohols. aldehydes. esters, ethers. or ketones: five

percent. 2 A combination of aromatic compounds with eight or more carbon atoms to the

molecule except ethylbenzene: eight percent.

A combination of ethvlbenzene. ketones having branched hydrocarbon structures.

trichlorethylene

or toluene: 20 percent.

D C. Where a stack, vent or other outlet is at such a level that fumes, gas mist, odor,

smoke, vapor or any combination thereof constituting air pollutichargcd pollution is discharged

to adjoining property, the Director may require the installation of abatement equipment or the

alteration of such stack, vent, or other outlet by the owner or operator thereof to a degree that will

adequately dilute, reduce or eliminate the discharge of air pollution to th adjoining property.

R18-2-526Z. Standards of performance for Sandblasting operations

No person shall cause or permit sandblasting

or other abrasive blasting without

50

# minimizing dust emissions to the atmosphere by through the use of good modem practices, such

a Examples of good modern practices include wet blasting; the use of effective enclosures

with necessary dust collecting equipment,

or othcr acceptabic

mcans.

R182524t21. Standards of performance for Spray painting operations

A. No person shall conduct any spray paint operation without minimizing organic

solvent emissions by good modern practiccs. Such operations other than architectural coating

and spot paintings shall be conducted in an enclosed area equipped with controls containing no

less than 96 percent of the overspray.

B. No person shall either:

L employ Employ, apply, evaporate or dry any architectural coating containing

photochemically reactive solvents for industrial or commercial purposes, material containing

photoehcmically reactive solvents or

shall thin Thin or dilute any architectural coating with a photochemically reactive

solvent. C. No pcrson shall, during any one day, dispose of a total of more than one and one-

half gallons of any photochcmically reactive solvent in such manner as to permit the evaporation

of the solvent into the atmospherc. For purposes of Subsection (B) of this Section (a)

photochemicallv reactive solvent shall be any solvent with an aggregate of more than twenty

percent of its total volume composed of the chemical compounds classified in Paragraphs (1)

through (3) of this Subsection,

or which exceeds any of the following percentage composition

limitations, referred to the total volume of solvent:

L A combination of the following types of compounds having an olefinic or cyclo

olefinic type of unsaturation

-- 

# hydrocarbons, alcohols, aldehydes. esters, ethers, or ketones: five

percent. A combination of aromatic compounds with eight or more carbon atoms to the

molecule except ethvlbenzene: eight percent.

I A combination of ethylbenzene, ketones having branched hydrocarbon structures.

trichlorethvlene

or toluene: 20 percent.

ji, Whenever

any organic solvent or any constituent of an organic solvent may be

classified from its chemical structure into more than one of the groups or organic compounds

described in Subsection (C). Paragraphs (1) through (3) of this Section. it shall be considered to

be a member of the group having the least allowable percent of the total volume of solvents.

R18-2-52fl. Standards of performance for existing ammonium suffide

manufacturing plants

A. The provisions of this Section are applicable to the following affected facilities in

ammonium sulfide manufacturing plants: Sulfide sulfide unloading facilities, reactor-absorber,

bubble cap scrubbers, an• fume incinerator. This is applicable to all ammonium sulfide

manufacturing plants under State of Arizona jurisdiction which arc existing sources.

B. The standards for particulate matter arc as follows:

4- Notwithstanding the provisions of Section Ri 8-2-501, no person shall cause,

suffer, allow or permit to be emitted into the atmosphere, from any type of incinerator

or other

outlet smoke, fumes, gases, particulate matter or other gas-borne material, the opacity of which

exceeds 20 percent. 51.. 

# No person shall cause, 3uffcr, allow or permit to be emitted into the atmosphere

from any emission point from any incinerator,

or to pass a convenient measuring point near such

emission point, particulate matter of concentrations in excess of 0.1 grain per cubic foot, based

on dry flue gas at standard conditions, corrected to 12 percent carbon dioxide.

j). Thc standard for hydrogcn sulfldc i as follow3: No person shall allow hydrogen

sulfide to be emitted from any location in such manner and amount that the concentration of such

emissions into the ambient air at any occupied place beyond the premises on which the source is

located exceeds 0.03 parts per million by volume for any averaging period of 30 minutes

or

more. Where a stack, vent or other outlet is at such a level that fumes, gas mist, odor,

smoke, vapor or any combination thereof constituting air pollution are discharged to adjoining

property, the Director may require the installation of abatement equipment

or the alteration of

such stack, vent, or other outlet by the owner or operator thereof to a degree that will adequately

dilute, reduce or eliminate the discharge of air pollution to adjoining property.

E. Monitoring of opcrations rcquircd by this Scction is as follows

4-; L The owner or operator of any ammonium sulfide tailgas incinerator subject to the

provisions of this Section shall do both of the following:

a L Install, calibrate, maintain, and operate a flow measuring device which can be

used to determine either the mass or volume of tailgas charged to the incinerator. The flow

measuring device shall have an accuracy of± fiy percent over its operating

range.

I’ 2 Provide access to the tailgas charged so that a well-mixed representative grab

sample can be obtained.

. 

# The test methods and procedures required by this Section are as follows:

1. The reference methods in thc Arizona Tcsting Manual 40 CFR 60.. Appendix A

shall be used to determine compliance with the standard prescribed in Subscctions 13. and C.

abovc this Section as follows:

a. Method 5 for the concentration of particulate matter and the associated moisture

content b. Method 1 for sample and velocity traverse

c.

Method 2 for velocity and volumetric flow rate.

d. Method 3 for gas analysis and calculation of excess air, using the integrated

sample techniquc; and

e. Method 11 shall be used to determine the concentration of H 2 S and Method 6

shall be used to determine the concentration of SO 2

2. For Method 5, the sampling time for each run shall be at least 60 minutes and the

minimum sample volume shall be 0.85 dscm (30.0 dscf) except that shorter sampling times and

smaller sample volumes, when necessitated by process variables

or other factors, may be

approved by the Director.

3. Particulate matter emissions, expressed in gldscm, shall be corrected to 12 percent

CO 2 by using the following formula:

12c %C0 2

where: 52

# C 12

= 

# the concentration of particulate matter corrected to 12 percent CU 2

,

c = 

# the concentration of particulate matter as measured by Method 5, and

%C0 2

= 

# the percentage of CO 2 as measured by Method 3, or when applicable, the

adjusted outlet CO 7 percentage.

4. If Method ii is used, the gases sampled shall be introduced into the sampling

train at approximately atmospheric

pressure. Where fuel gas lines are operating at pressures

substantially above atmosphere, this may be accomplished with a flow control valve. If the line

pressure is high enough to operate the sampling train without a vacuum pump, the pump may be

eliminated from the sampling train. The sample shall be drawn from a point near the centroid of

the fuel gas line. The minimum sampling time shall be 10 minutes and the minimum sampling

volume 0.01 dscm (0.35 dsct) for each sample. The arithmetic average of two samples of equal

sampling time shall constitute

one run. Samples shall be taken at approximately 1-hour intervals.

For most fuel gases, sample times exceeding 20 minutes may result in depletion of the collecting

solution, although fuel gases containing low concentrations of hydrogen sulfide may necessitate

sampling for longer periods of time.

5. If Method 5 is used, Method 1 shall be used for velocity traverses and Method 2

for determining velocity and volumetric flow rate. The sampling site for determining CO 2

concentration by Method 3 shall be the same as for determining volumetric flow rate by Method

2. The sampling point in the duct for determining SO 2 concentration by Method 3 shall be at the

centroid of the cross section if the cross sectional

area is less than 5 m 2 (54 ft2) or at a point no

closer to the walls than 1 m (3.28 feet) if the cross sectional area is 5 m 2 or more and the centroid

is more than one meter from the wall. The sample shall be extracted at a rate proportional to the

gas velocity at the sampling point. The minimum sampling time shall be 10 minutes and the

minimum sampling volume 0.01 dscm (0.36 dscf) for each sample. The arithmetic

average of

two samples of equal sampling time shall constitute

one run. Samples shall be taken at

approximately one-hour intervals.

R18-2-52922. Standards of performance for cotton gins

A. Thc provisions of this Section arc applicabic to all new or cxisting cotton gins in

thc Statc of Arizona.

+ Fugitive dust, lint, bolls, cotton seed or other material emitted from the a cotton

gin or lying loose in the yard shall be collected and disposed of in an efficient manner or shall

be treated in accordance with Sections Ri 8-2-4O44 through Ri 8-2-402.

.



# Cotton gins shall conform to Section Ri 8-2-501, Vi3iblc emissions: general, at

all times. An opacity of 40 percent or less shall exempt the source from mass emissions testing.

In the event that the cotton gin does not comply with the 40 percent opacity standard, the owner

or operator may request the permission of the Director to perform a mass emissions test observed

by a representative of the Bureau of Air Quality Control Department. Successful completion of

this test will result in an adjustment to the simultaneous opacity standard in accordance with

Section R18-2-501.C Ri 8-2-702(D).



# (. No person shall cause, suffer, allow, or permit the discharge of particulate matter

into the atmosphere in any one hour from any cotton gin in total quantities in excess of the

amounts calculated by one of the following equations set forth below.

L

For process sources having a process weight rate of 60,000 pounds per hour (30

53

# tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E = 

# 4.1OP° 67

where: E = 

# the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight rate in tons-mass per hour.

b 2 For process sources having a process weight rate greater than 60,000 pounds per

hour (30 tons per hour), the maximum allowable emissions shall be determined by the following

equation: 1



# E=

55.0P’ 1 -40

where “E” and “P” are defined

as indicated, in A.3.a. above Paragraph (1) of this Subsection.

l. The test methods and procedures required by this Section are as follows:

1. The reference methods in the Arizona Testing Manual and 40 CFR 60. Appendix

. 

# shall be used to determine compliance with Subsection A. above this Section as follows:

a. Method A-2 for the measurement of particulate matter;

b. Method 1 for sample and velocity traverses;V



# c.

Method 2 for velocity and volumetric flow rate.

d. Method 3 for gas analysis;

e. Method 9 for visible emissions.

2. For Method A-2, the sampling time for each run shall be at least 60 minutes and

the sampling rate shall be at least 0.85 dry standard cubic meters per hour (0.53 dry standard

cubic feet per minute), except that shorter sampling times, when necessitated by progress

variables or other factors, may be approved by the Director.

R18-2-5373O. Standards of performance for unclassified

sources

A.

No existing source which is not otherwise subject to standards of performance

under this Article or Article49

or 911 shall cause or permit the emission of pollutants at rates

greater than the following:

L For particulate matter discharged into the atmosphere in any one hour from any

unclassified

process source in total quantities in excess of the amounts calculated by one of the

following equations: For process sàurces having a process weight rate of 60.000 pounds per hour (30

tons per hour) or less, the maximum allowable emissions shall be determined by the following

equation: E = 

# 4.1OP° 67

where:V



# E the maximum allowable particulate emissions rate in pounds-mass

per hour.

P

= 

# the process weight in tons-mass per hour.

For process weight rate greater than 60.000 pounds per hour (30 tons per hour).

the maximum allowable emissions shall be determined by the following equation:

E

= 

# 55.OP° 11 -40

where “E” and “P” are defined as indicated in Subparagraph (a) of this Paragraph.

Sulfur dioxide

-- 

# 600 parts per million,

Nitrogen oxides expressed

as N02

-- 

# 500 parts per million.

# . 

# For purposes of this Section. the total process weight from all similar units

employing a similar type process shall be used in determining the maximum allowable emission

of particulate matter.

L. For reference only the equations in subsection (A)(1) of this Section are plotted in

Appendix 11. Figure 2. The emission values obtained from the graph are approximately correct

for the process weight rates shown. However, the actual values shall be calculated from the

applicable equations and rounded off to two decimal places.

11 No person shall emit gaseous or odorous materials from equipment. operations

or

premises under his control in such quantities or concentrations

as to cause air pollution.

L No person shall operate or use any machine, equipment

or other contrivance for

the treatment or processing of animal or vegetable matter, separately or in combination, unless all

gaseous vapors and gas entrained effluents from such operations. equipment

or contrivance have

been either: Incinerated to destruction.

as indicated by a temperature measuring device, at not

less than l.200.degrees Fahrenheit if constructed

or reconstructed prior to January 1. 1989. or

1600 degrees Fahrenheit with a minimum residence time of 0.5 seconds if constructed

or

reconstructed thereafter: or

2.L Passed through such other device which is designed. installed and maintained to

prevent the emission of odors or other air contaminants and which is approved by the Director.

Materials including solvents

or other volatile compounds. paints, acids. ailcalies.

pesticides. fertilizers and manure shall be processed. stored, used and transported in such a

manner and by such means that they will not evaporate, leak, escape or be otherwise discharged

into the ambient air so as to cause or contribute to air pollution. Where means are available to

reduce effectively the contribution to air pollution from evaporation, leakage or discharge, the

installation and use of such control methods, devices, or equipment shall be mandatory.

Where a stack, vent or other outlet is at such a level that fumes, gas mist, odor.

smoke, vapor or any combination thereof constituting air pollution are discharged to adjoining

property. the Director

may require the installation of abatement equipment or the alteration of

such stack, vent or other outlet by the owner or operator thereof to a degree that will adequately

dilute, reduce or eliminate the discharge of air pollution to adjoining property.

jj No person shall allow hydrogen sulfide to be emitted from any location in such

manner and amount that the concentration of such emissions into the ambient air at any occupied

place beyond the premises on which the source is located exceeds 0.03 parts per million by

volume for any averaging period of 30 minutes or more,

L

No person shall cause, allow or permit discharge from any stationary source

carbon monoxide emissions without the use of complete secondary combustion of waste gases

generated by any process source.



# a. No person shall allow hydrogen cyanide to be emitted from any location in such

manner and amount that the concentration of such emissions into the ambient air at any occupied

place beyond the premises

on which the source is located exceeds 0.3 parts per million by

volume for any averaging period of eight hours.

L No person shall allow sodium cyanide dust or dust from any other solid cyanide to

be emitted from any location in such manner and amount that the concentration of such

55

# emissions into the ambient air at any occupied place beyond the premises

on which the source is

located exceeds 140 micrograms per cubic meter for any averaging period of eight hours.

L No owner or operator of a facility engaged in the surface coating of miscellaneous

metal parts and products may operate a coating application system subject to this Section that

emits volatile organic compounds in excess of any of the following:

L 4.3 pounds per gallon (0.5 kilograms per liter) of coating. excluding water,

delivered to a coating applicator that applies clear coatings.

2 3.5 pounds per gallon (0.42 kilograms per liter) of coating. excluding water

delivered to a coating applicator in a coating application system that is air dried or forced warm

air dried at temperatures up to 194°F (90°C),

3.5 pounds per gallon (0.42 kilograms per liter) of coating. excluding water.

delivered to a coating applicator that applies extreme performance coatings.

3.0 pounds per gallon (0.36 kilograms per liter) of coating. excluding water.

delivered to a coating applicator for all other coatings and coating application systems.

M. If more than one emission limitation in Subsection (L) of this Section applies to a

specific coating. then the least stringent emission limitation shall be applied.

N. All VOC emissions from solvent washings shall be considered in the emission

limitations in Subsection (L) of this Section. unless the solvent is directed into containers that

prevent evaporation into the atmosphere.

ARTICLE 6ARTICLE 8. EMISSIONS FROM MOBILE POINT SOURCES

(NEW AN]) EXISTING)

R18-2-601Sjlj. Ccncral Classification of mobile sources

&

This Article is applicable to mobile sources which either move while emitting air

contaminants

or are frequently moved during the course of their utilization, but are not classified

as motor vehicles, agricultural vehicles,

or agricultural equipment used in normal farm

operations. ft. Unless otherwise specified, no mobile source shall emit smoke or dust the

opacity of which exceeds 40 percent.

R18-2-6OJZ. Off-road machinery

A. Off-road machinery shall include trucks (such as mining trucks), gradcrs, scrapcrs,

rollers, and othcr construction and mining machinery not normally driven on a complctcd public

roadway. 4.. Notwithstanding the provisions of Ri 8-2-601, no N person shall cause, suffer,

allow or permit to be emitted into the atmosphere from any off-road machinery, smoke for any

period greater than ten consecutive seconds, the opacity Qf which exceeds 40 percent. Visible

emissions when starting cold equipment shall be exempt from this requirement for the first ten

minutes. ft Off-road machinery shall include trucks, graders. scrapers. rollers, locomotives

and other construction and mining machinery not normally driven on a completed public

roadway. R18-2-6O3Q.. Heater-planer units 56Nopersonshallcause,suffcr,alloworpermittobeemittedintotheatmospherefromanyheater-planeroperatedforthepurposeofreconstructingasphaltpavements,smoketheopacityofwhichexceeds20percent.However,threeminutes’upsettimeinanyonehourwil-lshallnotconstituteaviolationofthisRuleSection.R18-2-6O44.RoadwayandsitecleaningmachineryA.Nopcrsonshallcausc,suffer,alloworpermitthecleaningofany3itc,roadway,oralleywithouttakingreasonabicprecautionstopreventparticulatematterfrombceomingairborne.Dustandothcrpartieulatcsshallbekepttoaminimumbyemployingdustsuppressants,wettingdown,vacuumdevicesorbyotherreasonablemeans.Earthorothermaterialmayberemovedfrompavedstreet3ontowhichearthorothermaterialhasbeentransportedbytruckingorearthmovingequipment,erosionbywater,orbyothermeans.BA.NotwithstandingthcprovisionsofRi8-2-601,nopersonshallcause,suffer,alloworpermittobeemittedintotheatmospherefromanyroadwayandsitecleaningmachinery,smokeordustforanyperiodgreaterthantenconsecutiveseconds,theopacityofwhichexceeds40percent.Visiblesmokeemissionswhenstartingcoldequipmentshallbeexemptfromthisrequirementforthefirsttenminutes.B.InadditiontocomplyingwithSubsection(A)ofthisSection.nopersonshallcause,alloworpermitthecleaningofanysite,roadway.oralleywithouttakingreasonableprecautionstopreventparticulatematterfrombecomingairborne.Reasonableprecautionsmayincludeapplyingdustsuppressants.Earthorothermaterialshallberemovedfrompavedstreetsontowhichearthorothermaterialhasbeentransportedbytruckingorearthmovingequipment.erosionbywater.orbyothermeans.R18-2-6{)5Q.AsphaltortarkettlesA.Nopersonshallcause,alloworpermittobeemittedintotheatmospherefromanyasphaltortarkettle,smokeforanyperiodgreaterthantenconsecutiveseconds,theopacityofwhichexceeds40percent.li.InadditiontocomplyingwithSubsection(A)ofthisSection.Nepersonshallcause,alloworpermittheoperationofanasphaltortarkettlewithoutminimizingaircontaminantemissionsbyutilizingallreasonablyavailableofthefollowingcontrolmeasuresj,.includingtheflcontroloftemperaturerecommendedbytheasphaltortarmanufacturer;.2theThoperationofthekettlewithlidclosedexceptwhencharging;thepumpingofasphaltfromthekettleorthedrawingofasphaltthroughcockswithnodipping;theThdippingoftarinanapprovedmanner;theIhmaintainingofthekettleinclean,properlyadjusted,andgoodoperatingcondition;theThfiringofthekettlewithliquidpetroleumgasorotherfuelsacceptabletotheDirector.57