Secretariat of Transport and Communications

Transport Transports

Canada Canada

Safety and Security

THIS DOCUMENT SHOULD NOT BE USED TO

DETERMINE COMPLIANCE WITH THE

DANGEROUS GOODS REGULATIONS

OR TO CREATE WORKER SAFETY DOCUMENTS

FOR SPECIFIC CHEMICALS

U.S. Department of Transportation

Research and Special Programs Administration 

NOT FOR SALE

This document is distributed free of charge to Public Safety Organizations

and may not be resold.
EMERGENCY CONTACT

1-000-000-0000

NO. & TYPE

OF PACKAGES QUANTITY DESCRIPTION OFARTICLES

1 TANK TRUCK ISOPROPANOL 3 UN1219 II 3,000 LITERS

EXAMPLE OF EMERGENCY

RESPONSE TELEPHONE NUMBER

HAZARD CLASS

OR DIVISION NO.

SHIPPING NAME ID NUMBER PACKING GROUP

SHIPPING DOCUMENTS (PAPERS)*

The shipping document provides vital information when responding to a

hazardous materials/dangerous goods** incident. The shipping document

contains information needed to identify the materials involved. Use this

information to initiate protective actions for your own safety and the safety

of the public. The shipping document contains the proper shipping name

(see blue-bordered pages), the hazard class or division of the material(s),

ID number (see yellow-bordered pages), and, where appropriate, the

Packing Group. In addition, there must be information available that

describes the hazards of the material which can be used in the mitigation

of an incident. The information must be entered on or be with the shipping

document. This requirement may be satisfied by attaching a guide from the

ERG2004 to the shipping document, or by having the entire guidebook

available for ready reference. Shipping documents are required for most

dangerous goods in transportation. Shipping documents are kept in

• the cab of the motor vehicle,

• the possession of the train crew member,

• a holder on the bridge of a vessel, or

• an aircraft pilot’s possession.

The 4-digit ID Number may be shown on the diamond-shaped placard or on

an adjacent orange panel displayed on the ends and sides of a cargo tank,

vehicle or rail car.

* For the purposes of this book, the terms shipping document/shipping paper are synonymous.

** For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous.

EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER

A Numbered or

Placard

A Placard 

and an 

Orange Panel

1219

1219 FLAMMABLE
Page 1

RESIST RUSHING IN !

APPROACH INCIDENT FROM UPWIND

STAY CLEAR OF ALL SPILLS, VAPORS, FUMES AND SMOKE

HOW TO USE THIS GUIDEBOOK DURING AN INCIDENT INVOLVING

DANGEROUS GOODS

 ON E IDENTIFY THE MATERIAL BY FINDING ANY ONE OF THE FOLLOWING:

THE 4-DIGIT ID NUMBER ON A PLACARD OR ORANGE PANEL

THE 4-DIGIT ID NUMBER (after UN/NA) ON A SHIPPING DOCUMENT OR PACKAGE

THE NAME OF THE MATERIAL ON A SHIPPING DOCUMENT, PLACARD OR PACKAGE

IF AN ID NUMBER OR THE NAME OF THE MATERIAL CANNOT BE FOUND, SKIP

TO THE NOTES BELOW.

T WO LOOK UP THE MATERIAL’S 3-DIGIT GUIDE NUMBER IN EITHER:

THE ID NUMBER INDEX..(the yellow-bordered pages of the guidebook)

THE NAME OF MATERIAL INDEX..(the blue-bordered pages of the guidebook)

If the guide number is supplemented with the letter “P”, it indicates that the material may

undergo violent polymerization if subjected to heat or contamination.

If the index entry is highlighted (in either yellow or blue), it is a TIH (Toxic Inhalation Hazard) material,

a chemical warfare agent or a Dangerous Water Reactive Material (produces toxic gas upon contact

with water). LOOK FOR THE ID NUMBER AND NAME OF THE MATERIAL IN THE TABLE

OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (the green-bordered pages).

Then, if necessary, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions on

page 298). If protective action is not required, use the information jointly with the 3-digit guide.

USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT FOR EXPLOSIVES 1.4

(EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CONSULTED.

THREE TURN TO THE NUMBERED GUIDE (the orange-bordered pages) AND READ CAREFULLY.

NOTES IF A NUMBERED GUIDE CANNOT BE OBTAINED BY FOLLOWING THE ABOVE

STEPS, AND A PLACARD CAN BE SEEN, LOCATE THE PLACARD IN THE TABLE

OF PLACARDS (pages 16-17), THEN GO TO THE 3-DIGIT GUIDE SHOWN NEXT TO

THE SAMPLE PLACARD.

IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO

INVOLVE DANGEROUS GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL

INFORMATION BECOMES AVAILABLE. If the shipping document lists an emergency response

telephone number, call that number. If the shipping document is not available, or no emergency response

telephone number is listed, IMMEDIATELY CALL the appropriate emergency response agency listed

on the inside back cover of this guidebook. Provide as much information as possible, such as the

name of the carrier (trucking company or railroad) and vehicle number. AS A LAST RESORT, CONSULT

THE TABLE OF RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages 18-19). IF THE

CONTAINER CAN BE IDENTIFIED, REMEMBER THAT THE INFORMATION ASSOCIATED

WITH THESE CONTAINERS IS FOR THE WORST CASE POSSIBLE.
Page 2

ERG2004 USER’S GUIDE

The 2004 Emergency Response Guidebook (ERG2004) was developed jointly by Transport

Canada (TC), the U.S. Department of Transportation (DOT), the Secretariat of Transport and

Communications of Mexico (SCT) and with the collaboration of CIQUIME (Centro de Información

Química para Emergencias) of Argentina, for use by fire fighters, police, and other emergency

services personnel who may be the first to arrive at the scene of a transportation incident

involving dangerous goods. It is primarily a guide to aid first responders in quickly

identifying the specific or generic hazards of the material(s) involved in the incident,

and protecting themselves and the general public during the initial response phase

of the incident. For the purposes of this guidebook, the “initial response phase” is that period

following arrival at the scene of an incident during which the presence and/or identification of

dangerous goods is confirmed, protective actions and area securement are initiated, and

assistance of qualified personnel is requested. It is not intended to provide information on the

physical or chemical properties of dangerous goods.

This guidebook will assist responders in making initial decisions upon arriving at the scene of a

dangerous goods incident. It should not be considered as a substitute for emergency response

training, knowledge or sound judgment. ERG2004 does not address all possible circumstances

that may be associated with a dangerous goods incident. It is primarily designed for use at a

dangerous goods incident occurring on a highway or railroad. Be mindful that there may be

limited value in its application at fixed facility locations.

ERG2004 incorporates dangerous goods lists from the most recent United Nations

Recommendations as well as from other international and national regulations. Explosives are

not listed individually by either proper shipping name or ID Number. They do, however,

appear under the general heading “Explosives” on the first page of the ID Number index

(yellow-bordered pages) and alphabetically in the Name of Material index (blue-bordered

pages). Also, the letter “P” following the guide number in the yellow-bordered and bluebordered pages identifies those materials which present a polymerization hazard under certain

conditions, for example: Acrolein, stabilized 131P.

First responders at the scene of a dangerous goods incident should seek additional specific

information about any material in question as soon as possible. The information received by

contacting the appropriate emergency response agency, the emergency response number on

the shipping document, or by consulting the information on or accompanying the shipping

document, may be more specific and accurate than this guidebook in providing guidance for the

materials involved.

BECOME FAMILIAR WITH THIS GUIDEBOOK BEFORE USING IT DURING AN

EMERGENCY! In the U.S., according to the requirements of the U.S. Department of Labor’s

Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations

issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders

must be trained regarding the use of this guidebook.
Page 3

GUIDEBOOK CONTENTS

1-Yellow-bordered pages: Index list of dangerous goods in numerical order of ID number.

This section quickly identifies the guide to be consulted from the ID Number of the material

involved. This list displays the 4-digit ID number of the material followed by its assigned

emergency response guide and the material name.

For example: ID No. GUIDE No. Name of Material

1090 127 Acetone

2-Blue-bordered pages: Index list of dangerous goods in alphabetical order of material

name. This section quickly identifies the guide to be consulted from the name of the material

involved. This list displays the name of the material followed by its assigned emergency

response guide and 4-digit ID number.

For example: Name of Material GUIDE No. ID No.

Sulfuric acid 137 1830

3-Orange-bordered pages: This section is the most important section of the guidebook

because it is where all safety recommendations are provided. It comprises a total of 62 individual

guides, presented in a two-page format. Each guide provides safety recommendations and

emergency response information to protect yourself and the public. The left hand page provides

safety related information whereas the right hand page provides emergency response guidance

and activities for fire situations, spill or leak incidents and first aid. Each guide is designed to

cover a group of materials which possess similar chemical and toxicological characteristics.

The guide title identifies the general hazards of the dangerous goods covered.

For example: GUIDE 124 - Gases-Toxic and/or Corrosive-Oxidizing.

Each guide is divided into three main sections: the first section describes potential hazards

that the material may display in terms of fire/explosion and health effects upon exposure. The

highest potential is listed first. The emergency responder should consult this section first. This

allows the responder to make decisions regarding the protection of the emergency response

team as well as the surrounding population.

The second section outlines suggested public safety measures based on the situation at hand. It

provides general information regarding immediate isolation of the incident site, recommended type of

protective clothing and respiratory protection. Suggested evacuation distances are listed for small

and large spills and for fire situations (fragmentation hazard). It also directs the reader to consult the

tables listing Toxic Inhalation Hazard materials (TIH), chemical warfare agents and water-reactive

materials (green-bordered pages) when the material name is highlighted in the yellow-bordered and

blue-bordered pages.

The third section covers emergency response actions, including first aid. It outlines special

precautions for incidents which involve fire, spill or chemical exposure. Several recommendations

are listed under each part which will further assist in the decision making process. The information

on first aid is general guidance prior to seeking medical care.
Page 4

4-Green-bordered pages: This section contains a table which lists, by ID number, TIH

materials, including certain chemical warfare agents, and water-reactive materials which produce

toxic gases upon contact with water. The table provides two different types of recommended

safe distances which are “Initial isolation distances” and “Protective action distances.” The

materials are highlighted for easy identification in both numeric (yellow-bordered pages) and

alphabetic (blue-bordered pages) lists of the guidebook. The table provides distances for both

small (approximately 200 liters or less) and large spills (more than 200 liters) for all highlighted

materials. The list is further subdivided into daytime and nighttime situations. This is necessary

due to varying atmospheric conditions which greatly affect the size of the hazardous area. The

distances change from daytime to nighttime due to different mixing and dispersion conditions in

the air. During the night, the air is generally calmer and this causes the chemical to disperse less

and therefore create a toxicity zone which is greater than would usually occur during the day.

During the day, the chemical is generally dispersed by a more active atmosphere. The chemical

will be present in a larger area; however, the actual area where toxic levels are reached will be

smaller (due to increased dispersion). It is the quantity or concentration of the chemical vapor

that poses problems not its mere presence.

The “Initial Isolation Distance” is a distance within which all persons should be considered for

evacuation in all directions from the actual spill/leak source. It is a distance (radius) which

defines a circle (Initial Isolation Zone) within which persons may be exposed to dangerous

concentrations upwind of the source and may be exposed to life threatening concentrations

downwind of the source. For example, in the case of Compressed gas, toxic, n.o.s., ID No.

1955, Inhalation Hazard Zone A, the isolation distance for small spills is 600 meters, therefore,

representing an evacuation circle of 1200 meters in diameter.

For the same material, the “Protective Action Distance” is 5.9 kilometers for a daytime incident

and 11.0+ kilometers for a nighttime incident, these distances represent a downwind distance

from the spill/leak source within which Protective Actions could be implemented. Protective

Actions are those steps taken to preserve the health and safety of emergency responders and

the public. People in this area could be evacuated and/or sheltered in-place. For more

information, consult the INTRODUCTION TO THE TABLE OF INITIAL ISOLATION AND

PROTECTIVE ACTION DISTANCES (pages 295-296).

What is a TIH?

It is a gas or volatile liquid which is known to be so toxic to humans as to pose a hazard to health

during transportation, or in the absence of adequate data on human toxicity, is presumed to be toxic

to humans because when tested on laboratory animals it has an LC50 value of not more than 5000

ppm.

It is important to note that even though the term zone is used, the hazard zones do not represent

any actual area or distance. The assignment of the zones is strictly a function of their Lethal

Concentration 50 (LC50); for example, TIH Zone A is more toxic than Zone D. All distances

which are listed in the green-bordered pages are calculated by the use of mathematical models

for each TIH material.
Page 5

Assignment of hazard zones:

HAZARD ZONE A: Gases: LC50 of less than or equal to 200 ppm,

 Liquids: V equal to or greater than 500 LC50 and LC50 less than or

 equal to 200 ppm,

HAZARD ZONE B: Gases: LC50 greater than 200 ppm and less than or equal to 1000 ppm,

 Liquids: V equal to or greater than 10 LC50; LC50 less than or equal to

 1000 ppm and criteria for Hazard Zone A are not met,

HAZARD ZONE C: LC50 greater than 1000 ppm and less than or equal to 3000 ppm,

HAZARD ZONE D: LC50 greater than 3000 ppm and less than or equal to 5000 ppm.

ISOLATION AND EVACUATION DISTANCES

Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the

Table of Initial Isolation and Protective Action Distances (green-bordered pages). This may

confuse users not thoroughly familiar with ERG2004.

It is important to note that some guides refer only to non-TIH materials (36 guides), some refer

to both TIH and non-TIH materials (21 guides) and some (5 guides) refer only to TIH or Waterreactive materials (WRM). A guide refers to both TIH and non-TIH materials (for example see

GUIDE 131) when the following sentence appears under the title EVACUATION-Spill: “See the

Table of Initial Isolation and Protective Action Distances for highlighted substances. For nonhighlighted substances, increase, in the downwind direction, as necessary, the isolation distance

shown under ‘PUBLIC SAFETY.’” A guide refers only to TIH or WRM materials (for example

see GUIDE 124) when the following sentence appears under the title EVACUATION-Spill:

“See the Table of Initial Isolation and Protective Action Distances”. If the previous sentences do

not appear in a guide, then this particular guide refers only to non-TIH materials (for example

see GUIDE 128).

In order to identify appropriate isolation and protective action distances, use the following:

If you are dealing with a TIH/WRM/Chemical warfare material (highlighted entries in the index

lists), the isolation and evacuation distances are found directly in the green-bordered pages.

The guides (orange-bordered pages) also remind the user to refer to the green-bordered

pages for evacuation specific information involving highlighted materials.

If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH

materials, an immediate isolation distance is provided under the heading PUBLIC SAFETY as

a precautionary measure to prevent injuries. It applies to the non-TIH materials only. In

addition, for evacuation purposes, the guide informs the user under the title EVACUATION-Spill

to increase, for non-highlighted substances, in the downwind direction, if necessary, the immediate

isolation distance listed under “PUBLIC SAFETY”. For example, GUIDE 131 – Flammable

Liquids-Toxic, instructs the user to: "As an immediate precautionary measure, isolate spill or

leak area for at least 50 meters (150 feet) in all directions." In case of a large spill, the isolation

area could be expanded from 50 meters to a distance deemed as safe by the On-scenecommander and emergency responders.

If you are dealing with a non-TIH material and the guide refers only to non-TIH materials,

the immediate isolation and evacuation distances are specified as actual distances in the guide

(orange-bordered pages) and are not referenced in the green-bordered pages.
Page 6

SAFETY PRECAUTIONS

APPROACH CAUTIOUSLY FROM UPWIND. Resist the urge to rush in; others cannot be

helped until the situation has been fully assessed.

SECURE THE SCENE. Without entering the immediate hazard area, isolate the area and

assure the safety of people and the environment, keep people away from the scene and outside

the safety perimeter. Allow enough room to move and remove your own equipment.

IDENTIFY THE HAZARDS. Placards, container labels, shipping documents, material safety

data sheets, Rail Car and Road Trailer Identification Charts, and/or knowledgeable persons on

the scene are valuable information sources. Evaluate all available information and consult the

recommended guide to reduce immediate risks. Additional information, provided by the

shipper or obtained from another authoritative source, may change some of the

emphasis or details found in the guide. Remember, the guide provides only the most

important and worst case scenario information for the initial response in relation to a family or

class of dangerous goods. As more material-specific information becomes available, the response

should be tailored to the situation.

ASSESS THE SITUATION. Consider the following:

- Is there a fire, a spill or a leak?

- What are the weather conditions?

- What is the terrain like?

- Who/what is at risk: people, property or the environment?

- What actions should be taken: Is an evacuation necessary? Is diking

necessary? What resources (human and equipment) are required and

are readily available?

- What can be done immediately?

OBTAIN HELP. Advise your headquarters to notify responsible agencies and call for assistance

from qualified personnel.

DECIDE ON SITE ENTRY. Any efforts made to rescue persons, protect property or the

environment must be weighed against the possibility that you could become part of the problem.

Enter the area only when wearing appropriate protective gear (see PROTECTIVE CLOTHING,

page 350).

RESPOND. Respond in an appropriate manner. Establish a command post and lines of

communication. Rescue casualties where possible and evacuate if necessary. Maintain control

of the site. Continually reassess the situation and modify the response accordingly. The first

duty is to consider the safety of people in the immediate area, including your own.

ABOVE ALL — Do not walk into or touch spilled material. Avoid inhalation of fumes, smoke and

vapors, even if no dangerous goods are known to be involved. Do not assume that gases or

vapors are harmless because of lack of a smell—odorless gases or vapors may be harmful.

Use CAUTION when handling empty containers because they may still present hazards until

they are cleaned and purged of all residues.
Page 7

WHO TO CALL FOR ASSISTANCE

Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous

goods, protect oneself and the public, secure the area, and call for the assistance of trained

personnel as soon as conditions permit. Follow the steps outlined in your organization’s

standard operating procedures and/or local emergency response plan for obtaining qualified

assistance. Generally, the notification sequence and requests for technical information beyond

what is available in this guidebook should occur in the following order:

1. ORGANIZATION/AGENCY

Notify your organization/agency. This will set in motion a series of events based upon the

information provided. Actions may range from dispatching additional trained personnel to the

scene to activating the local emergency response plan. Ensure that local fire and police

departments have been notified.

2. EMERGENCY RESPONSE TELEPHONE NUMBER

Locate and call the telephone number listed on the shipping document. The person answering

the phone at the listed emergency response number must be knowledgeable of the materials

and mitigation actions to be taken, or must have immediate access to a person who has the

required knowledge.

3. NATIONAL ASSISTANCE

Contact the appropriate emergency response agency listed on the inside back cover of this

guidebook when the emergency response telephone number is not available. Upon receipt of

a call describing the nature of the incident, the agency will provide immediate advice on handling

the early stages of the incident. The agency will also contact the shipper or manufacturer of the

material for more detailed information and request on-scene assistance when necessary.

Collect and provide as much of the following information as can safely be obtained to your chain-ofcommand and specialists contacted for technical guidance:

Your name, call back telephone number, FAX number

Location and nature of problem (spill, fire, etc.)

Name and identification number of material(s) involved

Shipper/consignee/point of origin

Carrier name, rail car or truck number

Container type and size

Quantity of material transported/released

Local conditions (weather, terrain, proximity to schools, hospitals, waterways, etc.)

Injuries and exposures

Local emergency services that have been notified
Page 8

CANADA

1. CANUTEC

CANUTEC is the Canadian Transport Emergency Centre operated by the Transport Dangerous

Goods Directorate of Transport Canada.

CANUTEC provides a national bilingual (French and English) advisory service and is staffed by

professional scientists experienced and trained in interpreting technical information and providing

emergency response advice.

In an emergency, CANUTEC may be called collect at 613-996-6666 (24 hours) *666 cellular (Press Star 666, Canada only)

In a non-emergency situation, please call the information line at 613-992-4624 (24 hours).

2. PROVINCIAL AGENCIES

Although technical information and emergency response assistance can be obtained from CANUTEC,

there are federal and provincial regulations requiring the reporting of dangerous goods incidents to

certain authorities.

The following list of provincial agencies is supplied for your convenience.

Province Emergency Authority and/or

Telephone Number

Alberta ......................................... Local Police and Provincial Authorities

1-800-272-9600* or 780-422-9600

British Columbia .......................... Local Police and Provincial Authorities

 1-800-663-3456

Manitoba ..................................... Provincial Authority 204-945-4888 and

 Local Police or fire brigade, as

appropriate

New Brunswick ........................... Local Police or 1-800-565-1633** or

902-426-6030

Newfoundland ............................ Local Police and 709-772-2083

Northwest Territories .................. 867-920-8130

Nova Scotia ................................ Local Police or 1-800-565-1633** or

902-426-6030

Nunavut Territory ....................... Local Police and 1-800-693-1666 or

 867-979-6262

Ontario ......................................... Local Police

Prince Edward Island ................. Local Police or 1-800-565-1633** or

902-426-6030

Quebec ........................................ Local Police

Saskatchewan ............................ Local Police or 1-800-667-7525

Yukon Territory ........................... 867-667-7244

* This number is not accessible from outside Alberta.

** This number is not accessible from outside of New Brunswick, Nova Scotia or Prince Edward Island.
Page 9

NOTE:

1. The appropriate federal agency must be notified in the case of rail, air or marine incidents.

2. The nearest police department must be notified in the case of lost, stolen or misplaced explosives,

radioactive materials or infectious substances.

3. CANUTEC must be notified in the case of:

a. lost, stolen or misplaced infectious substances;

b. an incident involving infectious substances;

c. an accidental release from a cylinder that has suffered a catastrophic failure;

d. an incident where the shipping documents display CANUTEC’s telephone number 613-996-

6666 as the emergency telephone number; or

e. a dangerous goods incident in which a railway vehicle, a ship, an aircraft, an aerodrome or

an air cargo facility is involved.
Page 10

UNITED STATES

1. CHEMTREC®, a 24-hour emergency response communication service, can be reached as follows:

CALL CHEMTREC® (24 hours)

1-800-424-9300

(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)

For calls originating elsewhere:

703-527-3887 (Collect calls are accepted)

or

2. CHEM-TEL, INC., a 24-hour emergency response communication service, can be reached as follows:

CALL CHEM-TEL, INC. (24 hours)

1-800-255-3924

(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)

For calls originating elsewhere:

813-248-0585 (Collect calls are accepted)

or

3. INFOTRAC, a 24-hour emergency response communication service, can be reached as follows:

CALL INFOTRAC (24 hours)

1-800-535-5053

(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)

For calls originating elsewhere:

352-323-3500 (Collect calls are accepted)

or

4. 3E COMPANY, a 24-hour emergency response communication service, can be reached as follows:

CALL 3E COMPANY (24 hours)

1-800-451-8346

(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)

For calls originating elsewhere:

760-602-8703 (Collect calls are accepted)

The emergency response information services shown above have requested to be listed as providers of

emergency response information and have agreed to provide emergency response information to all

callers. They maintain periodically updated lists of state and Federal radiation authorities who provide

information and technical assistance on handling incidents involving radioactive materials.
Page 11

5. NATIONAL RESPONSE CENTER (NRC)

The NRC, which is operated by the U.S. Coast Guard, receives reports required when dangerous

goods and hazardous substances are spilled. After receiving notification of an incident, the NRC will

immediately notify the appropriate Federal On-Scene Coordinator and concerned Federal agencies.

Federal law requires that anyone who releases into the environment a reportable quantity of a

hazardous substance (including oil when water is, or may be affected) or a material identified as a

marine pollutant, must immediately notify the NRC. When in doubt as to whether the amount

released equals the required reporting levels for these materials, the NRC should be notified.

CALL NRC (24 hours)

1-800-424-8802

(Toll-free in the U.S., Canada, and the U.S. Virgin Islands)

202-267-2675 in the District of Columbia

Calling the emergency response telephone number, CHEMTREC®, CHEM-TEL, INC., INFOTRAC

or 3E COMPANY, does not constitute compliance with regulatory requirements to call the NRC.

6. MILITARY SHIPMENTS

For assistance at incidents involving materials being shipped by, for, or to the Department of Defense

(DOD), call one of the following numbers (24 hours):

703-697-0218 (call collect) (U.S. Army Operations Center) for incidents involving explosives and

ammunition.

1-800-851-8061 (toll-free in the U.S.) (Defense Logistics Agency) for incidents involving dangerous

goods other than explosives and ammunition.

7. NATIONWIDE POISON CONTROL CENTER (United States Only)

Emergency and information calls are answered by the nearest Poison Center (24 hours):

1-800-222-1222 (toll-free in the U.S.).

The above numbers are for emergencies only.
Page 12

MEXICO

1. SETIQ (Emergency Transportation System for the Chemical Industry), a service of the National

Association of Chemical Industries (ANIQ), can be reached as follows:

CALL SETIQ (24 hours)

01-800-00-214-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan Area

5559-1588

For calls originating elsewhere, call

011-52-555-559-1588

2. CENACOM, the National Center for Communications of the Civil Protection Agency, can be reached

as follows:

CALL CENACOM (24 hours)

01-800-00-413-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan Area

5550-1496, 5550-1552, 5550-1485, or 5550-4885

For calls originating elsewhere, call

011-52-555-550-1496, or 011-52-555-550-1552

011-52-555-550-1485, or 011-52-555-550-4885

ARGENTINA

1. CIQUIME (Information Center for Chemical Emergencies) a 24-hour emergency response information

service, can be reached as follows:

CALL CIQUIME (24 hours)

0-800-222-2933 in the Republic of Argentina

For calls originating elsewhere, call

+54-11-4613-1100

BRAZIL

1. PRÓ-QUÍMICA a 24-hour emergency response information service, can be reached as follows:

CALL PRO-QUÍMICA (24 hours)

0-800-118270 in the Federal Republic of Brazil

For calls originating elsewhere, call

+55-11-232-1144
Page 13

COLOMBIA

1. CISPROQUIM a 24-hour emergency response information service, can be reached as follows:

CALL CISPROQUIM (24 hours)

01-800-091-6012 in Colombia

For calls originating in Bogotá, Colombia call

288-6012

For calls originating elsewhere, call

011-57-1-288-6012
Page 14

HAZARD CLASSIFICATION SYSTEM

The hazard class of dangerous goods is indicated either by its class (or division) number or name. For a

placard corresponding to the primary hazard class of a material, the hazard class or division number must

be displayed in the lower corner of the placard. However, no hazard class or division number may be

displayed on a placard representing the subsidiary hazard of a material. For other than Class 7 or the

OXYGEN placard, text indicating a hazard (for example, “CORROSIVE”) is not required. Text is shown

only in the U.S. The hazard class or division number must appear on the shipping document after each

shipping name.

Class 1 - Explosives

Division 1.1 Explosives with a mass explosion hazard

Division 1.2 Explosives with a projection hazard

Division 1.3 Explosives with predominantly a fire hazard

Division 1.4 Explosives with no significant blast hazard

Division 1.5 Very insensitive explosives with a mass explosion hazard

Division 1.6 Extremely insensitive articles

Class 2 - Gases

Division 2.1 Flammable gases

Division 2.2 Non-flammable, non-toxic* gases

Division 2.3 Toxic* gases

Class 3 - Flammable liquids (and Combustible liquids [U.S.])

Class 4 - Flammable solids; Spontaneously combustible materials; and Dangerous when wet

materials/Water-reactive substances

Division 4.1 Flammable solids

Division 4.2 Spontaneously combustible materials

Division 4.3 Water-reactive substances/Dangerous when wet materials

Class 5 - Oxidizing substances and Organic peroxides

Division 5.1 Oxidizing substances

Division 5.2 Organic peroxides

Class 6 - Toxic* substances and Infectious substances

Division 6.1 Toxic*substances

Division 6.2 Infectious substances

Class 7 - Radioactive materials

Class 8 - Corrosive substances

Class 9 - Miscellaneous hazardous materials/Products, Substances or Organisms

* The words “poison” or “poisonous” are synonymous with the word “toxic”.
Page 15

INTRODUCTION TO THE TABLE OF PLACARDS

USE THIS TABLE ONLY IF YOU HAVE NOT BEEN ABLE TO IDENTIFY

THE MATERIAL(S) IN TRANSPORT BY ID NUMBER OR NAME

The next two pages display the placards used on transport vehicles carrying

dangerous goods. As you approach a reported or suspected dangerous goods

incident involving a placarded vehicle:

1. Approach the incident cautiously from upwind to a point from which you

can safely identify and/or read the placard or orange panel information. If

wind direction allows, consider approaching the incident from uphill. Use

binoculars, if available.

2. Match the vehicle placard(s) with one of the placards displayed on the

following pages.

3. Consult the numbered guide associated with the sample placard. Use

that information for now. For example, a FLAMMABLE (Class 3) placard

leads to GUIDE 127. A CORROSIVE (Class 8) placard leads to GUIDE 153. If

multiple placards point to more than one guide, initially use the most

conservative guide (i.e., the guide requiring the greatest degree of protective

actions).

4. Remember that the guides associated with the placards provide the most

significant risk and/or hazard information.

5. When specific information, such as ID number or shipping name, becomes

available, the more specific guide recommended for that material must

be consulted.

6. If GUIDE 111 is being used because only the DANGER/DANGEROUS

placard is displayed or the nature of the spilled, leaking, or burning material

is not known, as soon as possible, get more specific information

concerning the material(s) involved.

7. Asterisks (*) on orange placards represent explosives “Compatibility

Group” letters; refer to the Glossary (page 359).

8. Double asterisks (**) on orange placards represent the division of the

explosive.
Page 16

TABLE OF PLACARDS AND INITIAL

USE THIS TABLE ONLY IF MATERIALS CANNOT BE SPECIFICALLY IDENTIFIED BY
Page 17

RESPONSE GUIDE TO USE ON-SCENE

USING THE SHIPPING DOCUMENT, NUMBERED PLACARD, OR ORANGE PANEL NUMBER
Page 18

CAUTION: Emergency response personnel must be aware that rail tank cars vary widely in

construction, fittings and purpose. Tank cars could transport products that may be solids, liquids

or gases. The products may be under pressure. It is essential that products be identified by

consulting shipping documents or train consist or contacting dispatch centers before emergency

response is initiated.

The information stenciled on the sides or ends of tank cars, as illustrated above, may be used to

identify the product utilizing:

a. the commodity name shown; or

b. the other information shown, especially reporting marks and car number which,

when supplied to a dispatch center, will facilitate the identification of the product.

* The recommended guides should be considered as last resort if product

cannot be identified by any other means.

RAIL CAR IDENTIFICATION CHART*
Page 19

CAUTION: This chart depicts only the most general shapes of road trailers. Emergency

response personnel must be aware that there are many variations of road trailers, not illustrated

above, that are used for shipping chemical products. The suggested guides are for the most

hazardous products that may be transported in these trailer types.

* The recommended guides should be considered as last resort if product

cannot be identified by any other means.

ROAD TRAILER IDENTIFICATION CHART*
Page 20

HAZARD IDENTIFICATION CODES

DISPLAYED ON SOME INTERMODAL CONTAINERS

Hazard identification codes, referred to as “hazard identification numbers” under European and some

South American regulations, may be found in the top half of an orange panel on some intermodal bulk

containers. The 4-digit identification number is in the bottom half of the orange panel.

The hazard identification code in the top half of the orange panel consists of two or three digits.

In general, the digits indicate the following hazards:

2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL REACTION

3 - FLAMMABILITY OF LIQUIDS (VAPORS) AND GASES OR SELF-HEATING LIQUID

4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID

5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT

6 - TOXICITY OR RISK OF INFECTION

7 - RADIOACTIVITY

8 - CORROSIVITY

9 - MISCELLANEOUS DANGEROUS SUBSTANCE

• Doubling of a digit indicates an intensification of that particular hazard (i.e. 33, 66, 88).

• Where the hazard associated with a material can be adequately indicated by a single

digit, the digit is followed by a zero (i.e. 30, 40, 50).

• A hazard identification code prefixed by the letter “X” indicates that the material will

react dangerously with water (i.e. X88).

• When 9 appears as a 2nd or 3rd digit, this may present a risk of spontaneous violent

reaction.

33

1203
Page 21

The hazard identification codes listed below have the following meanings:

20 Inert gas

22 Refrigerated gas

223 Refrigerated gas, flammable

225 Refrigerated gas, oxidizing (fire-intensifying)

23 Flammable gas

236 Flammable gas, toxic

239 Flammable gas which can spontaneously lead to violent reaction

25 Oxidizing (fire-intensifying) gas

26 Toxic gas

263 Toxic gas, flammable

265 Toxic gas, oxidizing (fire-intensifying)

266 Highly toxic gas

268 Toxic gas, corrosive

30 Flammable liquid

323 Flammable liquid which reacts with water, emitting flammable gas

X323 Flammable liquid which reacts dangerously with water, emitting flammable gas

33 Highly flammable liquid

333 Pyrophoric liquid

X333 Pyrophoric liquid which reacts dangerously with water

336 Highly flammable liquid, toxic

338 Highly flammable liquid, corrosive

X338 Highly flammable liquid, corrosive, which reacts dangerously with water

339 Highly flammable liquid which can spontaneously lead to violent reaction

36 Flammable liquid, toxic, or self-heating liquid, toxic

362 Flammable liquid, toxic, which reacts with water, emitting flammable gas

X362 Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas

368 Flammable liquid, toxic, corrosive

38 Flammable liquid, corrosive

382 Flammable liquid, corrosive, which reacts with water, emitting flammable gas

X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gas

39 Flammable liquid which can spontaneously lead to violent reaction

40 Flammable solid, or self-reactive material, or self-heating material

423 Solid which reacts with water, emitting flammable gas

HAZARD IDENTIFICATION CODES

DISPLAYED ON SOME INTERMODAL CONTAINERS
Page 22

X423 Flammable solid which reacts dangerously with water, emitting flammable gas

43 Spontaneously flammable (pyrophoric) solid

44 Flammable solid, in the molten state at an elevated temperature

446 Flammable solid, toxic, in the molten state at an elevated temperature

46 Flammable solid, toxic, or self-heating solid, toxic

462 Toxic solid which reacts with water, emitting flammable gas

X462 Solid which reacts dangerously with water, emitting toxic gas

48 Flammable or self-heating solid, corrosive

482 Corrosive solid which reacts with water, emitting flammable gas

X482 Solid which reacts dangerously with water, emitting corrosive gas

50 Oxidizing (fire-intensifying) substance

539 Flammable organic peroxide

55 Strongly oxidizing (fire-intensifying) substance

556 Strongly oxidizing (fire-intensifying) substance, toxic

558 Strongly oxidizing (fire-intensifying) substance, corrosive

559 Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to

violent reaction

56 Oxidizing (fire-intensifying) substance, toxic

568 Oxidizing (fire-intensifying) substance, toxic, corrosive

58 Oxidizing (fire-intensifying) substance, corrosive

59 Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction

60 Toxic material

606 Infectious substance

623 Toxic liquid which reacts with water, emitting flammable gas

63 Toxic liquid, flammable

638 Toxic liquid, flammable, corrosive

639 Toxic liquid, flammable, which can spontaneously lead to violent reaction

64 Toxic solid, flammable or self-heating

642 Toxic solid which reacts with water, emitting flammable gas

65 Toxic material, oxidizing (fire-intensifying)

66 Highly toxic material

663 Highly toxic liquid, flammable

664 Highly toxic solid, flammable or self-heating

665 Highly toxic material, oxidizing (fire-intensifying)

668 Highly toxic material, corrosive

HAZARD IDENTIFICATION CODES

DISPLAYED ON SOME INTERMODAL CONTAINERS
Page 23

669 Highly toxic material which can spontaneously lead to violent reaction

68 Toxic material, corrosive

69 Toxic material which can spontaneously lead to violent reaction

70 Radioactive material

72 Radioactive gas

723 Radioactive gas, flammable

73 Radioactive liquid, flammable

74 Radioactive solid, flammable

75 Radioactive material, oxidizing (fire-intensifying)

76 Radioactive material, toxic

78 Radioactive material, corrosive

80 Corrosive material

X80 Corrosive material which reacts dangerously with water

823 Corrosive liquid which reacts with water, emitting flammable gas

83 Corrosive liquid, flammable

X83 Corrosive liquid, flammable, which reacts dangerously with water

839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction

X839 Corrosive liquid, flammable, which can spontaneously lead to violent reaction

and which reacts dangerously with water

84 Corrosive solid, flammable or self-heating

842 Corrosive solid which reacts with water, emitting flammable gas

85 Corrosive material, oxidizing (fire-intensifying)

856 Corrosive material, oxidizing and toxic

86 Corrosive material, toxic

88 Highly corrosive material

X88 Highly corrosive material which reacts dangerously with water

883 Highly corrosive liquid, flammable

884 Highly corrosive solid, flammable or self-heating

885 Highly corrosive material, oxidizing (fire-intensifying)

886 Highly corrosive material, toxic

X886 Highly corrosive material, toxic, which reacts dangerously with water

89 Corrosive material which can spontaneously lead to violent reaction

90 Miscellaneous dangerous substance; environmentally hazardous substance

99 Miscellaneous dangerous substance transported at elevated temperature

HAZARD IDENTIFICATION CODES

DISPLAYED ON SOME INTERMODAL CONTAINERS
Page 24

Note: If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND

THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective

Action Distances (green-bordered pages) and look up the ID number and name of

material to obtain initial isolation and protective action distances. IF THERE IS A

FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide (orangebordered pages) and use the evacuation information shown under PUBLIC SAFETY.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 25

—— 112 Ammonium nitrate-fuel oil

mixtures

—— 158 Biological agents

—— 112 Blasting agent, n.o.s.

—— 112 Explosive A

—— 112 Explosive B

—— 114 Explosive C

—— 112 Explosives, division 1.1, 1.2,

1.3, 1.5 or 1.6

—— 114 Explosives, division 1.4

—— 153 Toxins

1001 116 Acetylene

1001 116 Acetylene, dissolved

1002 122 Air, compressed

1003 122 Air, refrigerated liquid

(cryogenic liquid)

1003 122 Air, refrigerated liquid

(cryogenic liquid), nonpressurized

1005 125 Ammonia, anhydrous

1005 125 Ammonia, anhydrous, liquefied

1005 125 Ammonia solution, with more

than 50% Ammonia

1005 125 Anhydrous ammonia

1005 125 Anhydrous ammonia, liquefied

1006 121 Argon

1006 121 Argon, compressed

1008 125 Boron trifluoride

1008 125 Boron trifluoride, compressed

1009 126 Bromotrifluoromethane

1009 126 Refrigerant gas R-13B1

1010 116P Butadienes, inhibited

1010 116P Butadienes, stabilized

1010 116P Butadienes and hydrocarbon

mixture, stabilized

1011 115 Butane

1011 115 Butane mixture

1012 115 Butylene

1013 120 Carbon dioxide

1013 120 Carbon dioxide, compressed

1014 122 Carbon dioxide and Oxygen mixture

1014 122 Carbon dioxide and Oxygen

mixture, compressed

1014 122 Oxygen and Carbon dioxide

mixture

1014 122 Oxygen and Carbon dioxide

mixture, compressed

1015 126 Carbon dioxide and Nitrous

oxide mixture

1015 126 Nitrous oxide and Carbon

dioxide mixture

1016 119 Carbon monoxide

1016 119 Carbon monoxide, compressed

1017 124 Chlorine

1018 126 Chlorodifluoromethane

1018 126 Refrigerant gas R-22

1020 126 Chloropentafluoroethane

1020 126 Refrigerant gas R-115

1021 126 1-Chloro-1,2,2,2-

tetrafluoroethane

1021 126 Chlorotetrafluoroethane

1021 126 Refrigerant gas R-124

1022 126 Chlorotrifluoromethane

1022 126 Refrigerant gas R-13

1023 119 Coal gas

1023 119 Coal gas, compressed

1026 119 Cyanogen

1026 119 Cyanogen, liquefied

1026 119 Cyanogen gas
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 26

1043 125 Fertilizer, ammoniating solution,

with free Ammonia

1044 126 Fire extinguishers with

compressed gas

1044 126 Fire extinguishers with

liquefied gas

1045 124 Fluorine

1045 124 Fluorine, compressed

1046 121 Helium

1046 121 Helium, compressed

1048 125 Hydrogen bromide, anhydrous

1049 115 Hydrogen

1049 115 Hydrogen, compressed

1050 125 Hydrogen chloride, anhydrous

1051 117 AC

1051 117 Hydrocyanic acid, aqueous

solutions, with more than

20% Hydrogen cyanide

1051 117 Hydrocyanic acid, liquefied

1051 117 Hydrogen cyanide, anhydrous,

stabilized

1051 117 Hydrogen cyanide, stabilized

1052 125 Hydrogen fluoride, anhydrous

1053 117 Hydrogen sulfide

1053 117 Hydrogen sulfide, liquefied

1053 117 Hydrogen sulphide

1053 117 Hydrogen sulphide, liquefied

1055 115 Isobutylene

1056 121 Krypton

1056 121 Krypton, compressed

1057 115 Lighter refills (cigarettes)

(flammable gas)

1057 115 Lighters (cigarettes)

(flammable gas)

1058 120 Liquefied gas (nonflammable)

1027 115 Cyclopropane

1027 115 Cyclopropane, liquefied

1028 126 Dichlorodifluoromethane

1028 126 Refrigerant gas R-12

1029 126 Dichlorofluoromethane

1029 126 Refrigerant gas R-21

1030 115 1,1-Difluoroethane

1030 115 Difluoroethane

1030 115 Refrigerant gas R-152a

1032 118 Dimethylamine, anhydrous

1033 115 Dimethyl ether

1035 115 Ethane

1035 115 Ethane, compressed

1036 118 Ethylamine

1037 115 Ethyl chloride

1038 115 Ethylene, refrigerated liquid

(cryogenic liquid)

1039 115 Ethyl methyl ether

1039 115 Methyl ethyl ether

1040 119P Ethylene oxide

1040 119P Ethylene oxide with Nitrogen

1041 115 Carbon dioxide and Ethylene

oxide mixture, with more than

9% but not more than 87%

Ethylene oxide

1041 115 Carbon dioxide and Ethylene

oxide mixtures, with more

than 6% Ethylene oxide

1041 115 Ethylene oxide and Carbon

dioxide mixture, with more

than 9% but not more than

87% Ethylene oxide

1041 115 Ethylene oxide and Carbon

dioxide mixtures, with more

than 6 % Ethylene oxide
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 27

1058 120 Liquefied gases, non-flammable,

charged with Nitrogen, Carbon

dioxide or Air

1060 116P Methylacetylene and Propadiene

mixture, stabilized

1060 116P Propadiene and Methylacetylene

mixture, stabilized

1061 118 Methylamine, anhydrous

1062 123 Methyl bromide

1063 115 Methyl chloride

1063 115 Refrigerant gas R-40

1064 117 Methyl mercaptan

1065 121 Neon

1065 121 Neon, compressed

1066 121 Nitrogen

1066 121 Nitrogen, compressed

1067 124 Dinitrogen tetroxide

1067 124 Dinitrogen tetroxide, liquefied

1067 124 Nitrogen dioxide

1067 124 Nitrogen dioxide, liquefied

1069 125 Nitrosyl chloride

1070 122 Nitrous oxide

1070 122 Nitrous oxide, compressed

1071 119 Oil gas

1071 119 Oil gas, compressed

1072 122 Oxygen

1072 122 Oxygen, compressed

1073 122 Oxygen, refrigerated liquid

(cryogenic liquid)

1075 115 Butane

1075 115 Butane mixture

1075 115 Butylene

1075 115 Isobutane

1075 115 Isobutane mixture

1075 115 Isobutylene

1075 115 Liquefied petroleum gas

1075 115 LPG

1075 115 Petroleum gases, liquefied

1075 115 Propane

1075 115 Propane mixture

1075 115 Propylene

1076 125 CG

1076 125 Diphosgene

1076 125 DP

1076 125 Phosgene

1077 115 Propylene

1078 126 Dispersant gas, n.o.s.

1078 126 Refrigerant gas, n.o.s.

1079 125 Sulfur dioxide

1079 125 Sulfur dioxide, liquefied

1079 125 Sulphur dioxide

1079 125 Sulphur dioxide, liquefied

1080 126 Sulfur hexafluoride

1080 126 Sulphur hexafluoride

1081 116P Tetrafluoroethylene, inhibited

1081 116P Tetrafluoroethylene, stabilized

1082 119P Trifluorochloroethylene

1082 119P Trifluorochloroethylene,

inhibited

1082 119P Trifluorochloroethylene,

stabilized

1083 118 Trimethylamine, anhydrous

1085 116P Vinyl bromide, inhibited

1085 116P Vinyl bromide, stabilized

1086 116P Vinyl chloride, inhibited

1086 116P Vinyl chloride, stabilized

1087 116P Vinyl methyl ether
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 28

1087 116P Vinyl methyl ether, inhibited

1087 116P Vinyl methyl ether, stabilized

1088 127 Acetal

1089 129 Acetaldehyde

1090 127 Acetone

1091 127 Acetone oils

1092 131P Acrolein, inhibited

1092 131P Acrolein, stabilized

1093 131P Acrylonitrile, inhibited

1093 131P Acrylonitrile, stabilized

1098 131 Allyl alcohol

1099 131 Allyl bromide

1100 131 Allyl chloride

1104 129 Amyl acetates

1105 129 Amyl alcohols

1105 129 Pentanols

1106 132 Amylamines

1107 129 Amyl chloride

1108 128 n-Amylene

1108 128 1-Pentene

1109 129 Amyl formates

1110 127 n-Amyl methyl ketone

1110 127 Amyl methyl ketone

1110 127 Methyl amyl ketone

1111 130 Amyl mercaptan

1112 140 Amyl nitrate

1113 129 Amyl nitrite

1114 130 Benzene

1120 129 Butanols

1123 129 Butyl acetates

1125 132 n-Butylamine

1126 130 1-Bromobutane

1126 130 n-Butyl bromide

1127 130 Butyl chloride

1127 130 Chlorobutanes

1128 129 n-Butyl formate

1129 129 Butyraldehyde

1130 128 Camphor oil

1131 131 Carbon bisulfide

1131 131 Carbon bisulphide

1131 131 Carbon disulfide

1131 131 Carbon disulphide

1133 128 Adhesives (flammable)

1134 130 Chlorobenzene

1135 131 Ethylene chlorohydrin

1136 128 Coal tar distillates, flammable

1139 127 Coating solution

1143 131P Crotonaldehyde, inhibited

1143 131P Crotonaldehyde, stabilized

1144 128 Crotonylene

1145 128 Cyclohexane

1146 128 Cyclopentane

1147 130 Decahydronaphthalene

1148 129 Diacetone alcohol

1149 128 Butyl ethers

1149 128 Dibutyl ethers

1150 130P 1,2-Dichloroethylene

1150 130P Dichloroethylene

1152 130 Dichloropentanes

1153 127 Ethylene glycol diethyl ether

1154 132 Diethylamine

1155 127 Diethyl ether

1155 127 Ethyl ether

1156 127 Diethyl ketone

1157 128 Diisobutyl ketone

1158 132 Diisopropylamine
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 29

1159 127 Diisopropyl ether

1160 132 Dimethylamine, aqueous solution

1160 132 Dimethylamine, solution

1161 129 Dimethyl carbonate

1162 155 Dimethyldichlorosilane

1163 131 1,1-Dimethylhydrazine

1163 131 Dimethylhydrazine,

unsymmetrical

1164 130 Dimethyl sulfide

1164 130 Dimethyl sulphide

1165 127 Dioxane

1166 127 Dioxolane

1167 128P Divinyl ether, inhibited

1167 128P Divinyl ether, stabilized

1169 127 Extracts, aromatic, liquid

1170 127 Ethanol

1170 127 Ethanol, solution

1170 127 Ethyl alcohol

1170 127 Ethyl alcohol, solution

1171 127 Ethylene glycol monoethyl ether

1172 129 Ethylene glycol monoethyl ether

acetate

1173 129 Ethyl acetate

1175 130 Ethylbenzene

1176 129 Ethyl borate

1177 130 2-Ethylbutyl acetate

1177 130 Ethylbutyl acetate

1178 130 2-Ethylbutyraldehyde

1179 127 Ethyl butyl ether

1180 130 Ethyl butyrate

1181 155 Ethyl chloroacetate

1182 155 Ethyl chloroformate

1183 139 Ethyldichlorosilane

1184 131 Ethylene dichloride

1185 131P Ethyleneimine, inhibited

1185 131P Ethyleneimine, stabilized

1188 127 Ethylene glycol monomethyl

ether

1189 129 Ethylene glycol monomethyl

ether acetate

1190 129 Ethyl formate

1191 129 Ethylhexaldehydes

1191 129 Octyl aldehydes

1192 129 Ethyl lactate

1193 127 Ethyl methyl ketone

1193 127 Methyl ethyl ketone

1194 131 Ethyl nitrite, solution

1195 129 Ethyl propionate

1196 155 Ethyltrichlorosilane

1197 127 Extracts, flavoring, liquid

1197 127 Extracts, flavouring, liquid

1198 132 Formaldehyde, solution,

flammable

1198 132 Formaldehyde, solutions

(Formalin)

1199 132P Furaldehydes

1199 132P Furfural

1199 132P Furfuraldehydes

1201 127 Fusel oil

1202 128 Diesel fuel

1202 128 Fuel oil

1202 128 Fuel oil, no. 1,2,4,5,6

1202 128 Gas oil

1202 128 Heating oil, light

1203 128 Gasohol

1203 128 Gasoline

1203 128 Motor spirit
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 30

1203 128 Petrol

1204 127 Nitroglycerin, solution in alcohol,

with not more than 1%

Nitroglycerin

1206 128 Heptanes

1207 130 Hexaldehyde

1208 128 Hexanes

1208 128 Neohexane

1210 129 Ink, printer’s, flammable

1210 129 Printing ink, flammable

1210 129 Printing ink related material

1212 129 Isobutanol

1212 129 Isobutyl alcohol

1213 129 Isobutyl acetate

1214 132 Isobutylamine

1216 128 Isooctenes

1218 130P Isoprene, inhibited

1218 130P Isoprene, stabilized

1219 129 Isopropanol

1219 129 Isopropyl alcohol

1220 129 Isopropyl acetate

1221 132 Isopropylamine

1222 130 Isopropyl nitrate

1223 128 Kerosene

1224 127 Ketones, liquid, n.o.s.

1226 128 Lighters for cigars, cigarettes

(flammable liquid)

1228 131 Mercaptan mixture, liquid,

flammable, poisonous, n.o.s.

1228 131 Mercaptan mixture, liquid,

flammable, toxic, n.o.s.

1228 131 Mercaptan mixtures, liquid,

n.o.s.

1228 131 Mercaptans, liquid, flammable,

poisonous, n.o.s.

1228 131 Mercaptans, liquid, flammable,

toxic, n.o.s.

1229 129 Mesityl oxide

1230 131 Methanol

1230 131 Methyl alcohol

1231 129 Methyl acetate

1233 130 Methylamyl acetate

1234 127 Methylal

1235 132 Methylamine, aqueous solution

1237 129 Methyl butyrate

1238 155 Methyl chloroformate

1239 131 Methyl chloromethyl ether

1242 139 Methyldichlorosilane

1243 129 Methyl formate

1244 131 Methylhydrazine

1245 127 Methyl isobutyl ketone

1246 127P Methyl isopropenyl ketone,

inhibited

1246 127P Methyl isopropenyl ketone,

stabilized

1247 129P Methyl methacrylate monomer,

inhibited

1247 129P Methyl methacrylate monomer,

stabilized

1248 129 Methyl propionate

1249 127 Methyl propyl ketone

1250 155 Methyltrichlorosilane

1251 131P Methyl vinyl ketone

1251 131P Methyl vinyl ketone, stabilized

1259 131 Nickel carbonyl

1261 129 Nitromethane

1262 128 Isooctane

1262 128 Octanes

1263 128 Paint (flammable)
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 31

1263 128 Paint related material (flammable)

1264 129 Paraldehyde

1265 128 Isopentane

1265 128 n-Pentane

1265 128 Pentanes

1266 127 Perfumery products, with

flammable solvents

1267 128 Petroleum crude oil

1268 128 Petroleum distillates, n.o.s.

1268 128 Petroleum products, n.o.s.

1270 128 Oil, petroleum

1270 128 Petroleum oil

1272 129 Pine oil

1274 129 n-Propanol

1274 129 normal Propyl alcohol

1274 129 Propyl alcohol, normal

1275 129 Propionaldehyde

1276 129 n-Propyl acetate

1277 132 Monopropylamine

1277 132 Propylamine

1278 129 1-Chloropropane

1278 129 Propyl chloride

1279 130 1,2-Dichloropropane

1279 130 Dichloropropane

1279 130 Propylene dichloride

1280 127P Propylene oxide

1281 129 Propyl formates

1282 129 Pyridine

1286 127 Rosin oil

1287 127 Rubber solution

1288 128 Shale oil

1289 132 Sodium methylate, solution in

alcohol

1292 129 Ethyl silicate

1292 129 Tetraethyl silicate

1293 127 Tinctures, medicinal

1294 130 Toluene

1295 139 Trichlorosilane

1296 132 Triethylamine

1297 132 Trimethylamine, aqueous solution

1298 155 Trimethylchlorosilane

1299 128 Turpentine

1300 128 Turpentine substitute

1301 129P Vinyl acetate

1301 129P Vinyl acetate, inhibited

1301 129P Vinyl acetate, stabilized

1302 127P Vinyl ethyl ether

1302 127P Vinyl ethyl ether, inhibited

1302 127P Vinyl ethyl ether, stabilized

1303 130P Vinylidene chloride, inhibited

1303 130P Vinylidene chloride, stabilized

1304 127P Vinyl isobutyl ether

1304 127P Vinyl isobutyl ether, inhibited

1304 127P Vinyl isobutyl ether, stabilized

1305 155P Vinyltrichlorosilane

1305 155P Vinyltrichlorosilane, inhibited

1305 155P Vinyltrichlorosilane, stabilized

1306 129 Wood preservatives, liquid

1307 130 Xylenes

1308 170 Zirconium metal, liquid

suspension

1308 170 Zirconium suspended in a

flammable liquid

1308 170 Zirconium suspended in a liquid

(flammable)

1309 170 Aluminum powder, coated
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 32

1310 113 Ammonium picrate, wetted with

not less than 10% water

1312 133 Borneol

1313 133 Calcium resinate

1314 133 Calcium resinate, fused

1318 133 Cobalt resinate, precipitated

1320 113 Dinitrophenol, wetted with not

less than 15% water

1321 113 Dinitrophenolates, wetted with

not less than 15% water

1322 113 Dinitroresorcinol, wetted with

not less than 15% water

1323 170 Ferrocerium

1324 133 Films, nitrocellulose base

1325 133 Flammable solid, n.o.s.

1325 133 Flammable solid, organic, n.o.s.

1325 133 Fusee (rail or highway)

1325 133 Medicines, flammable, solid,

n.o.s.

1326 170 Hafnium powder, wetted with

not less than 25% water

1327 133 Bhusa, wet, damp or

contaminated with oil

1327 133 Hay, wet, damp or contaminated

with oil

1327 133 Straw, wet, damp or

contaminated with oil

1328 133 Hexamethylenetetramine

1328 133 Hexamine

1330 133 Manganese resinate

1331 133 Matches, “strike anywhere”

1332 133 Metaldehyde

1333 170 Cerium, slabs, ingots or rods

1334 133 Naphthalene, crude

1334 133 Naphthalene, refined

1336 113 Nitroguanidine (Picrite), wetted

with not less than 20% water

1336 113 Nitroguanidine, wetted with not

less than 20% water

1336 113 Picrite, wetted

1337 113 Nitrostarch, wetted with not less

than 20% water

1337 113 Nitrostarch, wetted with not less

than 30% solvent

1338 133 Phosphorus, amorphous

1338 133 Phosphorus, amorphous, red

1338 133 Red phosphorus

1338 133 Red phosphorus, amorphous

1339 139 Phosphorus heptasulfide, free

from yellow and white

Phosphorus

1339 139 Phosphorus heptasulphide, free

from yellow and white

Phosphorus

1340 139 Phosphorus pentasulfide, free

from yellow and white

Phosphorus

1340 139 Phosphorus pentasulphide, free

from yellow and white

Phosphorus

1341 139 Phosphorus sesquisulfide, free

from yellow and white

Phosphorus

1341 139 Phosphorus sesquisulphide,

free from yellow and white

Phosphorus

1343 139 Phosphorus trisulfide, free from

yellow and white Phosphorus

1343 139 Phosphorus trisulphide, free from

yellow and white Phosphorus

1344 113 Picric acid, wet, with not less

than 10% water
ID Guide Name of Material

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Page 33

1344 113 Trinitrophenol, wetted with not

less than 30% water

1345 133 Rubber scrap, powdered or

granulated

1345 133 Rubber shoddy, powdered or

granulated

1346 170 Silicon powder, amorphous

1347 113 Silver picrate, wetted with not

less than 30% water

1348 113 Sodium dinitro-o-cresolate,

wetted with not less than 15%

water

1348 113 Sodium dinitro-ortho-cresolate,

wetted

1349 113 Sodium picramate, wetted with

not less than 20% water

1350 133 Sulfur

1350 133 Sulphur

1352 170 Titanium powder, wetted with

not less than 25% water

1353 133 Fabrics impregnated with

weakly nitrated

Nitrocellulose, n.o.s.

1353 133 Fibers impregnated with weakly

nitrated Nitrocellulose, n.o.s.

1353 133 Fibres impregnated with weakly

nitrated Nitrocellulose, n.o.s.

1353 133 Toe puffs, nitrocellulose base

1354 113 Trinitrobenzene, wetted with not

less than 30% water

1355 113 Trinitrobenzoic acid, wetted with

not less than 30% water

1356 113 TNT, wetted with not less than

30% water

1356 113 Trinitrotoluene, wetted with not

less than 30% water

1357 113 Urea nitrate, wetted with not

less than 20% water

1358 170 Zirconium metal, powder, wet

1358 170 Zirconium powder, wetted with

not less than 25% water

1360 139 Calcium phosphide

1361 133 Carbon, animal or vegetable

origin

1361 133 Charcoal

1362 133 Carbon, activated

1363 135 Copra

1364 133 Cotton waste, oily

1365 133 Cotton

1365 133 Cotton, wet

1366 135 Diethylzinc

1369 135 p-Nitrosodimethylaniline

1370 135 Dimethylzinc

1372 133 Fiber, animal or vegetable,

n.o.s., burnt, wet or damp

1372 133 Fibers, animal or vegetable,

burnt, wet or damp

1372 133 Fibres, animal or vegetable,

burnt, wet or damp

1373 133 Fabrics, animal or vegetable or

synthetic, n.o.s. with oil

1373 133 Fibers, animal or vegetable or

synthetic, n.o.s. with oil

1373 133 Fibres, animal or vegetable or

synthetic, n.o.s. with oil

1374 133 Fish meal, unstabilized

1374 133 Fish scrap, unstabilized

1376 135 Iron oxide, spent

1376 135 Iron sponge, spent

1378 170 Metal catalyst, wetted

1379 133 Paper, unsaturated oil treated

1380 135 Pentaborane
ID Guide Name of Material

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Page 34

1381 136 Phosphorus, white, dry or under

water or in solution

1381 136 Phosphorus, yellow, dry or

under water or in solution

1381 136 White phosphorus, dry

1381 136 White phosphorus, in solution

1381 136 White phosphorus, under water

1381 136 Yellow phosphorus, dry

1381 136 Yellow phosphorus, in solution

1381 136 Yellow phosphorus, under water

1382 135 Potassium sulfide, anhydrous

1382 135 Potassium sulfide, with less

than 30% water of

crystallization

1382 135 Potassium sulfide, with less

than 30% water of hydration

1382 135 Potassium sulphide, anhydrous

1382 135 Potassium sulphide, with less

than 30% water of

crystallization

1382 135 Potassium sulphide, with less

than 30% water of hydration

1383 135 Aluminum powder, pyrophoric

1383 135 Pyrophoric alloy, n.o.s.

1383 135 Pyrophoric metal, n.o.s.

1384 135 Sodium dithionite

1384 135 Sodium hydrosulfite

1384 135 Sodium hydrosulphite

1385 135 Sodium sulfide, anhydrous

1385 135 Sodium sulfide, with less than

30% water of crystallization

1385 135 Sodium sulphide, anhydrous

1385 135 Sodium sulphide, with less than

30% water of crystallization

1386 135 Seed cake, with more than 1.5%

oil and not more than 11%

moisture

1387 133 Wool waste, wet

1389 138 Alkali metal amalgam

1389 138 Alkali metal amalgam, liquid

1389 138 Alkali metal amalgam, solid

1390 139 Alkali metal amides

1391 138 Alkali metal dispersion

1391 138 Alkaline earth metal dispersion

1392 138 Alkaline earth metal amalgam

1392 138 Alkaline earth metal amalgam,

liquid

1393 138 Alkaline earth metal alloy,

n.o.s.

1394 138 Aluminum carbide

1395 139 Aluminum ferrosilicon powder

1396 138 Aluminum powder, uncoated

1397 139 Aluminum phosphide

1398 138 Aluminum silicon powder,

uncoated

1400 138 Barium

1401 138 Calcium

1402 138 Calcium carbide

1403 138 Calcium cyanamide, with more

than 0.1% Calcium carbide

1404 138 Calcium hydride

1405 138 Calcium silicide

1406 138 Calcium silicon

1407 138 Caesium

1407 138 Cesium

1408 139 Ferrosilicon

1409 1388 Hydrides, metal, n.o.s.

1409 138 Metal hydrides, water-reactive,

n.o.s.
ID Guide Name of Material

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Page 35

1410 138 Lithium aluminum hydride

1411 138 Lithium aluminum hydride,

ethereal

1412 139 Lithium amide

1413 138 Lithium borohydride

1414 138 Lithium hydride

1415 138 Lithium

1417 138 Lithium silicon

1418 138 Magnesium alloys powder

1418 138 Magnesium powder

1419 139 Magnesium aluminum phosphide

1420 138 Potassium, metal alloys

1420 138 Potassium, metal alloys, liquid

1421 138 Alkali metal alloy, liquid, n.o.s.

1422 138 Potassium sodium alloys

1422 138 Potassium sodium alloys, liquid

1422 138 Sodium potassium alloys

1422 138 Sodium potassium alloys, liquid

1423 138 Rubidium

1423 138 Rubidium metal

1426 138 Sodium borohydride

1427 138 Sodium hydride

1428 138 Sodium

1431 138 Sodium methylate

1431 138 Sodium methylate, dry

1432 139 Sodium phosphide

1433 139 Stannic phosphides

1435 138 Zinc ashes

1435 138 Zinc dross

1435 138 Zinc residue

1435 138 Zinc skimmings

1436 138 Zinc dust

1436 138 Zinc powder

1437 138 Zirconium hydride

1438 140 Aluminum nitrate

1439 141 Ammonium dichromate

1442 143 Ammonium perchlorate

1444 140 Ammonium persulfate

1444 140 Ammonium persulphate

1445 141 Barium chlorate

1445 141 Barium chlorate, solid

1446 141 Barium nitrate

1447 141 Barium perchlorate

1447 141 Barium perchlorate, solid

1448 141 Barium permanganate

1449 141 Barium peroxide

1450 141 Bromates, inorganic, n.o.s.

1451 140 Caesium nitrate

1451 140 Cesium nitrate

1452 140 Calcium chlorate

1453 140 Calcium chlorite

1454 140 Calcium nitrate

1455 140 Calcium perchlorate

1456 140 Calcium permanganate

1457 140 Calcium peroxide

1458 140 Borate and Chlorate mixtures

1458 140 Chlorate and Borate mixtures

1459 140 Chlorate and Magnesium chloride

mixture

1459 140 Chlorate and Magnesium chloride

mixture, solid

1459 140 Magnesium chloride and Chlorate

mixture

1459 140 Magnesium chloride and Chlorate

mixture, solid

1461 140 Chlorates, inorganic, n.o.s.

1462 143 Chlorites, inorganic, n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 36

1463 141 Chromic acid, solid

1463 141 Chromium trioxide, anhydrous

1465 140 Didymium nitrate

1466 140 Ferric nitrate

1467 143 Guanidine nitrate

1469 141 Lead nitrate

1470 141 Lead perchlorate

1470 141 Lead perchlorate, solid

1470 141 Lead perchlorate, solution

1471 140 Lithium hypochlorite, dry

1471 140 Lithium hypochlorite mixture

1471 140 Lithium hypochlorite mixtures,

dry

1472 143 Lithium peroxide

1473 140 Magnesium bromate

1474 140 Magnesium nitrate

1475 140 Magnesium perchlorate

1476 140 Magnesium peroxide

1477 140 Nitrates, inorganic, n.o.s.

1479 140 Medicines, oxidizing

substances, solid, n.o.s.

1479 140 Oxidizing solid, n.o.s.

1479 140 Oxidizing substances, solid,

n.o.s.

1481 140 Perchlorates, inorganic, n.o.s.

1482 140 Permanganates, inorganic,

n.o.s.

1483 140 Peroxides, inorganic, n.o.s.

1484 140 Potassium bromate

1485 140 Potassium chlorate

1486 140 Potassium nitrate

1487 140 Potassium nitrate and Sodium

nitrite mixture

1487 140 Sodium nitrite and Potassium

nitrate mixture

1488 140 Potassium nitrite

1489 140 Potassium perchlorate

1490 140 Potassium permanganate

1491 144 Potassium peroxide

1492 140 Potassium persulfate

1492 140 Potassium persulphate

1493 140 Silver nitrate

1494 141 Sodium bromate

1495 140 Sodium chlorate

1496 143 Sodium chlorite

1498 140 Sodium nitrate

1499 140 Potassium nitrate and Sodium

nitrate mixture

1499 140 Sodium nitrate and Potassium

nitrate mixture

1500 140 Sodium nitrite

1502 140 Sodium perchlorate

1503 140 Sodium permanganate

1504 144 Sodium peroxide

1505 140 Sodium persulfate

1505 140 Sodium persulphate

1506 143 Strontium chlorate

1506 143 Strontium chlorate, solid

1506 143 Strontium chlorate, solution

1507 140 Strontium nitrate

1508 140 Strontium perchlorate

1509 143 Strontium peroxide

1510 143 Tetranitromethane

1511 140 Urea hydrogen peroxide

1512 140 Zinc ammonium nitrite

1513 140 Zinc chlorate

1514 140 Zinc nitrate

1515 140 Zinc permanganate
ID Guide Name of Material

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Page 37

1516 143 Zinc peroxide

1517 113 Zirconium picramate, wetted with

not less than 20% water

1541 155 Acetone cyanohydrin, stabilized

1544 151 Alkaloids, solid, n.o.s.

(poisonous)

1544 151 Alkaloid salts, solid, n.o.s.

(poisonous)

1545 155 Allyl isothiocyanate, inhibited

1545 155 Allyl isothiocyanate, stabilized

1546 151 Ammonium arsenate

1547 153 Aniline

1548 153 Aniline hydrochloride

1549 157 Antimony compound, inorganic,

n.o.s.

1549 157 Antimony compound, inorganic,

solid, n.o.s.

1549 157 Antimony tribromide, solid

1549 157 Antimony tribromide, solution

1549 157 Antimony trifluoride, solid

1549 157 Antimony trifluoride, solution

1550 151 Antimony lactate

1551 151 Antimony potassium tartrate

1553 154 Arsenic acid, liquid

1554 154 Arsenic acid, solid

1555 151 Arsenic bromide

1556 152 Arsenic compound, liquid, n.o.s.

1556 152 Arsenic compound, liquid, n.o.s.,

inorganic

1556 152 MD

1556 152 Methyldichloroarsine

1556 152 PD

1557 152 Arsenic compound, solid, n.o.s.

1557 152 Arsenic compound, solid, n.o.s.,

inorganic

1557 152 Arsenic sulfide

1557 152 Arsenic sulphide

1557 152 Arsenic trisulfide

1557 152 Arsenic trisulphide

1558 152 Arsenic

1559 151 Arsenic pentoxide

1560 157 Arsenic chloride

1560 157 Arsenic trichloride

1561 151 Arsenic trioxide

1562 152 Arsenical dust

1564 154 Barium compound, n.o.s.

1565 157 Barium cyanide

1566 154 Beryllium compound, n.o.s.

1567 134 Beryllium powder

1569 131 Bromoacetone

1570 152 Brucine

1571 113 Barium azide, wetted with not

less than 50% water

1572 151 Cacodylic acid

1573 151 Calcium arsenate

1574 151 Calcium arsenate and Calcium

arsenite mixture, solid

1574 151 Calcium arsenite, solid

1574 151 Calcium arsenite and Calcium

arsenate mixture, solid

1575 157 Calcium cyanide

1577 153 Chlorodinitrobenzenes

1577 153 Chlorodinitrobenzenes, liquid

1577 153 Chlorodinitrobenzenes, solid

1577 153 Dinitrochlorobenzenes

1578 152 Chloronitrobenzenes

1578 152 Chloronitrobenzenes, liquid

1578 152 Chloronitrobenzenes, solid
ID Guide Name of Material

No. No.

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Page 38

1579 153 4-Chloro-o-toluidine

hydrochloride

1579 153 4-Chloro-o-toluidine

hydrochloride, solid

1580 154 Chloropicrin

1581 123 Chloropicrin and Methyl

bromide mixture

1581 123 Methyl bromide and

Chloropicrin mixture

1582 119 Chloropicrin and Methyl

chloride mixture

1582 119 Methyl chloride and

Chloropicrin mixture

1583 154 Chloropicrin mixture, n.o.s.

1585 151 Copper acetoarsenite

1586 151 Copper arsenite

1587 151 Copper cyanide

1588 157 Cyanides, inorganic, n.o.s.

1588 157 Cyanides, inorganic, solid,

n.o.s.

1589 125 CK

1589 125 Cyanogen chloride, inhibited

1589 125 Cyanogen chloride, stabilized

1590 153 Dichloroanilines

1590 153 Dichloroanilines, liquid

1590 153 Dichloroanilines, solid

1591 152 o-Dichlorobenzene

1593 160 Dichloromethane

1593 160 Methylene chloride

1594 152 Diethyl sulfate

1594 152 Diethyl sulphate

1595 156 Dimethyl sulfate

1595 156 Dimethyl sulphate

1596 153 Dinitroanilines

1597 152 Dinitrobenzenes

1597 152 Dinitrobenzenes, liquid

1597 152 Dinitrobenzenes, solid

1598 153 Dinitro-o-cresol

1599 153 Dinitrophenol, solution

1600 152 Dinitrotoluenes, molten

1601 151 Disinfectant, solid, poisonous,

n.o.s.

1601 151 Disinfectant, solid, toxic, n.o.s.

1601 151 Disinfectants, solid, n.o.s.

(poisonous)

1602 151 Dye, liquid, poisonous, n.o.s.

1602 151 Dye, liquid, toxic, n.o.s.

1602 151 Dye intermediate, liquid,

poisonous, n.o.s.

1602 151 Dye intermediate, liquid, toxic,

n.o.s.

1603 155 Ethyl bromoacetate

1604 132 Ethylenediamine

1605 154 Ethylene dibromide

1606 151 Ferric arsenate

1607 151 Ferric arsenite

1608 151 Ferrous arsenate

1610 159 Halogenated irritating liquid, n.o.s.

1611 151 Hexaethyl tetraphosphate

1611 151 Hexaethyl tetraphosphate,

liquid

1611 151 Hexaethyl tetraphosphate, solid

1612 123 Hexaethyl tetraphosphate and

compressed gas mixture

1613 154 Hydrocyanic acid, aqueous

solution, with less than 5%

Hydrogen cyanide

1613 154 Hydrocyanic acid, aqueous

solution, with not more than

20% Hydrogen cyanide
ID Guide Name of Material

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Page 39

1613 154 Hydrogen cyanide, aqueous

solution, with not more than

20% Hydrogen cyanide

1614 152 Hydrogen cyanide, anhydrous,

stabilized (absorbed)

1614 152 Hydrogen cyanide, stabilized

(absorbed)

1616 151 Lead acetate

1617 151 Lead arsenates

1618 151 Lead arsenites

1620 151 Lead cyanide

1621 151 London purple

1622 151 Magnesium arsenate

1623 151 Mercuric arsenate

1624 154 Mercuric chloride

1625 141 Mercuric nitrate

1626 157 Mercuric potassium cyanide

1627 141 Mercurous nitrate

1629 151 Mercury acetate

1630 151 Mercury ammonium chloride

1631 154 Mercury benzoate

1634 154 Mercuric bromide

1634 154 Mercurous bromide

1634 154 Mercury bromides

1636 154 Mercuric cyanide

1636 154 Mercury cyanide

1637 151 Mercury gluconate

1638 151 Mercury iodide

1639 151 Mercury nucleate

1640 151 Mercury oleate

1641 151 Mercury oxide

1642 151 Mercuric oxycyanide

1642 151 Mercury oxycyanide,

desensitized

1643 151 Mercury potassium iodide

1644 151 Mercury salicylate

1645 151 Mercuric sulfate

1645 151 Mercuric sulphate

1645 151 Mercury sulfate

1645 151 Mercury sulphate

1646 151 Mercury thiocyanate

1647 151 Ethylene dibromide and Methyl

bromide mixture, liquid

1647 151 Methyl bromide and Ethylene

dibromide mixture, liquid

1648 127 Acetonitrile

1648 127 Methyl cyanide

1649 131 Motor fuel anti-knock mixture

1649 131 Tetraethyl lead, liquid

1650 153 beta-Naphthylamine

1650 153 beta-Naphthylamine, solid

1650 153 Naphthylamine (beta)

1650 153 Naphthylamine (beta), solid

1651 153 Naphthylthiourea

1652 153 Naphthylurea

1653 151 Nickel cyanide

1654 151 Nicotine

1655 151 Nicotine compound, solid, n.o.s.

1655 151 Nicotine preparation, solid, n.o.s.

1656 151 Nicotine hydrochloride

1656 151 Nicotine hydrochloride, liquid

1656 151 Nicotine hydrochloride, solid

1656 151 Nicotine hydrochloride, solution

1657 151 Nicotine salicylate

1658 151 Nicotine sulfate, solid

1658 151 Nicotine sulfate, solution

1658 151 Nicotine sulphate, solid
ID Guide Name of Material

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Page 40

1658 151 Nicotine sulphate, solution

1659 151 Nicotine tartrate

1660 124 Nitric oxide

1660 124 Nitric oxide, compressed

1661 153 Nitroanilines

1662 152 Nitrobenzene

1663 153 Nitrophenols

1664 152 Nitrotoluenes

1664 152 Nitrotoluenes, liquid

1664 152 Nitrotoluenes, solid

1665 152 Nitroxylenes

1665 152 Nitroxylenes, liquid

1665 152 Nitroxylenes, solid

1669 151 Pentachloroethane

1670 157 Perchloromethyl mercaptan

1671 153 Phenol, solid

1672 151 Phenylcarbylamine chloride

1673 153 Phenylenediamines

1674 151 Phenylmercuric acetate

1677 151 Potassium arsenate

1678 154 Potassium arsenite

1679 157 Potassium cuprocyanide

1680 157 Potassium cyanide

1680 157 Potassium cyanide, solid

1683 151 Silver arsenite

1684 151 Silver cyanide

1685 151 Sodium arsenate

1686 154 Sodium arsenite, aqueous

solution

1687 153 Sodium azide

1688 152 Sodium cacodylate

1689 157 Sodium cyanide

1689 157 Sodium cyanide, solid

1690 154 Sodium fluoride

1690 154 Sodium fluoride, solid

1691 151 Strontium arsenite

1692 151 Strychnine

1692 151 Strychnine salts

1693 159 Tear gas devices

1693 159 Tear gas substance, liquid,

n.o.s.

1693 159 Tear gas substance, solid,

n.o.s.

1694 159 Bromobenzyl cyanides

1694 159 Bromobenzyl cyanides, liquid

1694 159 Bromobenzyl cyanides, solid

1694 159 CA

1695 131 Chloroacetone, stabilized

1697 153 Chloroacetophenone

1697 153 Chloroacetophenone, liquid

1697 153 Chloroacetophenone, solid

1697 153 CN

1698 154 Adamsite

1698 154 Diphenylamine chloroarsine

1698 154 D M

1699 151 D A

1699 151 Diphenylchloroarsine

1699 151 Diphenylchloroarsine, liquid

1699 151 Diphenylchloroarsine, solid

1700 159 Tear gas candles

1700 159 Tear gas grenades

1701 152 Xylyl bromide

1701 152 Xylyl bromide, liquid

1702 151 1,1,2,2-Tetrachloroethane

1702 151 Tetrachloroethane

1704 153 Tetraethyl dithiopyrophosphate
ID Guide Name of Material

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Page 41

1704 153 Tetraethyl dithiopyrophosphate,

mixture, dry or liquid

1707 151 Thallium compound, n.o.s.

1707 151 Thallium sulfate, solid

1707 151 Thallium sulphate, solid

1708 153 Toluidines

1708 153 Toluidines, liquid

1708 153 Toluidines, solid

1709 151 2,4-Toluenediamine

1709 151 2,4-Toluylenediamine

1709 151 2,4-Toluylenediamine, solid

1710 160 Trichloroethylene

1711 153 Xylidines

1711 153 Xylidines, liquid

1711 153 Xylidines, solid

1712 151 Zinc arsenate

1712 151 Zinc arsenate and Zinc arsenite

mixture

1712 151 Zinc arsenite

1712 151 Zinc arsenite and Zinc arsenate

mixture

1713 151 Zinc cyanide

1714 139 Zinc phosphide

1715 137 Acetic anhydride

1716 156 Acetyl bromide

1717 155 Acetyl chloride

1718 153 Acid butyl phosphate

1718 153 Butyl acid phosphate

1719 154 Caustic alkali liquid, n.o.s.

1722 155 Allyl chlorocarbonate

1722 155 Allyl chloroformate

1723 132 Allyl iodide

1724 155 Allyltrichlorosilane, stabilized

1725 137 Aluminum bromide, anhydrous

1726 137 Aluminum chloride, anhydrous

1727 154 Ammonium bifluoride, solid

1727 154 Ammonium hydrogendifluoride,

solid

1727 154 Ammonium hydrogen fluoride,

solid

1728 155 Amyltrichlorosilane

1729 156 Anisoyl chloride

1730 157 Antimony pentachloride, liquid

1731 157 Antimony pentachloride,

solution

1732 157 Antimony pentafluoride

1733 157 Antimony trichloride

1733 157 Antimony trichloride, liquid

1733 157 Antimony trichloride, solid

1733 157 Antimony trichloride, solution

1736 137 Benzoyl chloride

1737 156 Benzyl bromide

1738 156 Benzyl chloride

1739 137 Benzyl chloroformate

1740 154 Hydrogendifluorides, n.o.s.

1741 125 Boron trichloride

1742 157 Boron trifluoride acetic acid

complex

1742 157 Boron trifluoride acetic acid

complex, liquid

1743 157 Boron trifluoride propionic acid

complex

1743 157 Boron trifluoride propionic acid

complex, liquid

1744 154 Bromine

1744 154 Bromine, solution

1745 144 Bromine pentafluoride
ID Guide Name of Material

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Page 42

1746 144 Bromine trifluoride

1747 155 Butyltrichlorosilane

1748 140 Calcium hypochlorite, dry

1748 140 Calcium hypochlorite mixture,

dry, with more than 39%

available Chlorine (8.8%

available Oxygen)

1749 124 Chlorine trifluoride

1750 153 Chloroacetic acid, liquid

1750 153 Chloroacetic acid, solution

1751 153 Chloroacetic acid, solid

1752 156 Chloroacetyl chloride

1753 156 Chlorophenyltrichlorosilane

1754 137 Chlorosulfonic acid

1754 137 Chlorosulfonic acid and Sulfur

trioxide mixture

1754 137 Chlorosulphonic acid

1754 137 Chlorosulphonic acid and

Sulphur trioxide mixture

1754 137 Sulfur trioxide and

Chlorosulfonic acid mixture

1754 137 Sulphur trioxide and

Chlorosulphonic acid mixture

1755 154 Chromic acid, solution

1756 154 Chromic fluoride, solid

1757 154 Chromic fluoride, solution

1758 137 Chromium oxychloride

1759 154 Corrosive solid, n.o.s.

1759 154 Ferrous chloride, solid

1759 154 Medicines, corrosive, solid,

n.o.s.

1760 154 Chemical kit

1760 154 Compound, cleaning liquid

(corrosive)

1760 154 Compound, tree or weed killing,

liquid (corrosive)

1760 154 Corrosive liquid, n.o.s.

1760 154 Ferrous chloride, solution

1760 154 Medicines, corrosive, liquid, n.o.s.

1760 154 Titanium sulfate, solution

1760 154 Titanium sulphate, solution

1761 154 Cupriethylenediamine, solution

1762 156 Cyclohexenyltrichlorosilane

1763 156 Cyclohexyltrichlorosilane

1764 153 Dichloroacetic acid

1765 156 Dichloroacetyl chloride

1766 156 Dichlorophenyltrichlorosilane

1767 155 Diethyldichlorosilane

1768 154 Difluorophosphoric acid,

anhydrous

1769 156 Diphenyldichlorosilane

1770 153 Diphenylmethyl bromide

1771 156 Dodecyltrichlorosilane

1773 157 Ferric chloride

1773 157 Ferric chloride, anhydrous

1774 154 Fire extinguisher charges,

corrosive liquid

1775 154 Fluoboric acid

1775 154 Fluoroboric acid

1776 154 Fluorophosphoric acid,

anhydrous

1777 137 Fluorosulfonic acid

1777 137 Fluorosulphonic acid

1778 154 Fluorosilicic acid

1778 154 Fluosilicic acid

1778 154 Hydrofluorosilicic acid

1779 153 Formic acid

1780 156 Fumaryl chloride
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Page 43

1781 156 Hexadecyltrichlorosilane

1782 154 Hexafluorophosphoric acid

1783 153 Hexamethylenediamine, solution

1784 156 Hexyltrichlorosilane

1786 157 Hydrofluoric acid and Sulfuric

acid mixture

1786 157 Hydrofluoric acid and Sulphuric

acid mixture

1786 157 Sulfuric acid and Hydrofluoric

acid mixture

1786 157 Sulphuric acid and Hydrofluoric

acid mixture

1787 154 Hydriodic acid

1787 154 Hydriodic acid, solution

1788 154 Hydrobromic acid

1788 154 Hydrobromic acid, solution

1789 157 Hydrochloric acid

1789 157 Hydrochloric acid, solution

1789 157 Muriatic acid

1790 157 Hydrofluoric acid

1790 157 Hydrofluoric acid, solution

1791 154 Hypochlorite solution

1791 154 Hypochlorite solution, with more

than 5% available Chlorine

1792 157 Iodine monochloride

1793 153 Isopropyl acid phosphate

1794 154 Lead sulfate, with more than 3%

free acid

1794 154 Lead sulphate, with more than

3% free acid

1796 157 Nitrating acid mixture

1798 157 Aqua regia

1798 157 Nitrohydrochloric acid

1799 156 Nonyltrichlorosilane

1800 156 Octadecyltrichlorosilane

1801 156 Octyltrichlorosilane

1802 140 Perchloric acid, with not more

than 50% acid

1803 153 Phenolsulfonic acid, liquid

1803 153 Phenolsulphonic acid, liquid

1804 156 Phenyltrichlorosilane

1805 154 Phosphoric acid

1805 154 Phosphoric acid, liquid

1805 154 Phosphoric acid, solid

1805 154 Phosphoric acid, solution

1806 137 Phosphorus pentachloride

1807 137 Phosphorus pentoxide

1808 137 Phosphorus tribromide

1809 137 Phosphorus trichloride

1810 137 Phosphorus oxychloride

1811 154 Potassium hydrogendifluoride

1811 154 Potassium hydrogen difluoride,

solid

1812 154 Potassium fluoride

1812 154 Potassium fluoride, solid

1813 154 Caustic potash, dry, solid

1813 154 Potassium hydroxide, dry, solid

1813 154 Potassium hydroxide, flake

1813 154 Potassium hydroxide, solid

1814 154 Caustic potash, liquid

1814 154 Caustic potash, solution

1814 154 Potassium hydroxide, solution

1815 132 Propionyl chloride

1816 155 Propyltrichlorosilane

1817 137 Pyrosulfuryl chloride

1817 137 Pyrosulphuryl chloride

1818 157 Silicon tetrachloride

1819 154 Sodium aluminate, solution
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1823 154 Caustic soda, bead

1823 154 Caustic soda, flake

1823 154 Caustic soda, granular

1823 154 Caustic soda, solid

1823 154 Sodium hydroxide, bead

1823 154 Sodium hydroxide, dry

1823 154 Sodium hydroxide, flake

1823 154 Sodium hydroxide, granular

1823 154 Sodium hydroxide, solid

1824 154 Caustic soda, solution

1824 154 Sodium hydroxide, solution

1825 157 Sodium monoxide

1826 157 Nitrating acid mixture, spent

1827 137 Stannic chloride, anhydrous

1827 137 Tin tetrachloride

1828 137 Sulfur chlorides

1828 137 Sulphur chlorides

1829 137 Sulfur trioxide

1829 137 Sulfur trioxide, inhibited

1829 137 Sulfur trioxide, stabilized

1829 137 Sulfur trioxide, uninhibited

1829 137 Sulphur trioxide

1829 137 Sulphur trioxide, inhibited

1829 137 Sulphur trioxide, stabilized

1829 137 Sulphur trioxide, uninhibited

1830 137 Sulfuric acid

1830 137 Sulfuric acid, with more than

51% acid

1830 137 Sulphuric acid

1830 137 Sulphuric acid, with more than

51% acid

1831 137 Sulfuric acid, fuming

1831 137 Sulfuric acid, fuming, with less

than 30% free Sulfur trioxide

1831 137 Sulfuric acid, fuming, with not

less than 30% free Sulfur

trioxide

1831 137 Sulphuric acid, fuming

1831 137 Sulphuric acid, fuming, with

less than 30% free Sulphur

trioxide

1831 137 Sulphuric acid, fuming, with not

less than 30% free Sulphur

trioxide

1832 137 Sulfuric acid, spent

1832 137 Sulphuric acid, spent

1833 154 Sulfurous acid

1833 154 Sulphurous acid

1834 137 Sulfuryl chloride

1834 137 Sulphuryl chloride

1835 153 Tetramethylammonium

hydroxide

1835 153 Tetramethylammonium

hydroxide, solution

1836 137 Thionyl chloride

1837 157 Thiophosphoryl chloride

1838 137 Titanium tetrachloride

1839 153 Trichloroacetic acid

1840 154 Zinc chloride, solution

1841 171 Acetaldehyde ammonia

1843 141 Ammonium dinitro-o-cresolate

1843 141 Ammonium dinitro-o-cresolate,

solid

1845 120 Carbon dioxide, solid

1845 120 Dry ice

1846 151 Carbon tetrachloride
ID Guide Name of Material

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Page 45

1847 153 Potassium sulfide, hydrated, with

not less than 30% water of

crystallization

1847 153 Potassium sulfide, hydrated, with

not less than 30% water of

hydration

1847 153 Potassium sulphide, hydrated,

with not less than 30% water

of crystallization

1847 153 Potassium sulphide, hydrated,

with not less than 30% water

of hydration

1848 132 Propionic acid

1849 153 Sodium sulfide, hydrated, with

not less than 30% water

1849 153 Sodium sulphide, hydrated, with

not less than 30% water

1851 151 Medicine, liquid, poisonous,

n.o.s.

1851 151 Medicine, liquid, toxic, n.o.s.

1854 135 Barium alloys, pyrophoric

1855 135 Calcium, metal and alloys,

pyrophoric

1855 135 Calcium, pyrophoric

1855 135 Calcium alloys, pyrophoric

1856 133 Rags, oily

1857 133 Textile waste, wet

1858 126 Hexafluoropropylene

1858 126 Refrigerant gas R-1216

1859 125 Silicon tetrafluoride

1859 125 Silicon tetrafluoride, compressed

1860 116P Vinyl fluoride, inhibited

1860 116P Vinyl fluoride, stabilized

1862 130 Ethyl crotonate

1863 128 Fuel, aviation, turbine engine

1865 131 n-Propyl nitrate

1866 127 Resin solution

1868 134 Decaborane

1869 138 Magnesium

1869 138 Magnesium, in pellets, turnings

or ribbons

1869 138 Magnesium alloys, with more

than 50% Magnesium, in

pellets, turnings or ribbons

1870 138 Potassium borohydride

1871 170 Titanium hydride

1872 141 Lead dioxide

1873 143 Perchloric acid, with more than

50% but not more than 72%

acid

1884 157 Barium oxide

1885 153 Benzidine

1886 156 Benzylidene chloride

1887 160 Bromochloromethane

1888 151 Chloroform

1889 157 Cyanogen bromide

1891 131 Ethyl bromide

1892 151 ED

1892 151 Ethyldichloroarsine

1894 151 Phenylmercuric hydroxide

1895 151 Phenylmercuric nitrate

1897 160 Perchloroethylene

1897 160 Tetrachloroethylene

1898 156 Acetyl iodide

1902 153 Diisooctyl acid phosphate

1903 153 Disinfectant, liquid, corrosive,

n.o.s.

1903 153 Disinfectants, corrosive, liquid,

n.o.s.

1905 154 Selenic acid

1906 153 Acid, sludge
ID Guide Name of Material

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Page 46

1906 153 Sludge acid

1907 154 Soda lime, with more than 4%

Sodium hydroxide

1908 154 Chlorite solution

1908 154 Chlorite solution, with more

than 5% available Chlorine

1908 154 Sodium chlorite, solution, with

more than 5% available

Chlorine

1910 157 Calcium oxide

1911 119 Diborane

1911 119 Diborane, compressed

1911 119 Diborane mixtures

1912 115 Methyl chloride and Methylene

chloride mixture

1912 115 Methylene chloride and Methyl

chloride mixture

1913 120 Neon, refrigerated liquid

(cryogenic liquid)

1914 130 Butyl propionates

1915 127 Cyclohexanone

1916 152 2,2'-Dichlorodiethyl ether

1916 152 Dichloroethyl ether

1917 129P Ethyl acrylate, inhibited

1917 129P Ethyl acrylate, stabilized

1918 130 Cumene

1918 130 Isopropylbenzene

1919 129P Methyl acrylate, inhibited

1919 129P Methyl acrylate, stabilized

1920 128 Nonanes

1921 131P Propyleneimine, inhibited

1921 131P Propyleneimine, stabilized

1922 132 Pyrrolidine

1923 135 Calcium dithionite

1923 135 Calcium hydrosulfite

1923 135 Calcium hydrosulphite

1928 135 Methyl magnesium bromide in

Ethyl ether

1929 135 Potassium dithionite

1929 135 Potassium hydrosulfite

1929 135 Potassium hydrosulphite

1931 171 Zinc dithionite

1931 171 Zinc hydrosulfite

1931 171 Zinc hydrosulphite

1932 135 Zirconium scrap

1935 157 Cyanide solution, n.o.s.

1938 156 Bromoacetic acid

1938 156 Bromoacetic acid, solution

1939 137 Phosphorus oxybromide

1939 137 Phosphorus oxybromide, solid

1940 153 Thioglycolic acid

1941 171 Dibromodifluoromethane

1942 140 Ammonium nitrate, with not

more than 0.2% combustible

substances

1944 133 Matches, safety

1945 133 Matches, wax “vesta”

1950 126 Aerosol dispensers

1950 126 Aerosols

1951 120 Argon, refrigerated liquid

(cryogenic liquid)

1952 126 Carbon dioxide and Ethylene

oxide mixtures, with not more

than 6% Ethylene oxide

1952 126 Carbon dioxide and Ethylene

oxide mixtures, with not more

than 9% Ethylene oxide

1952 126 Ethylene oxide and Carbon

dioxide mixtures, with not

more than 6% Ethylene oxide
ID Guide Name of Material

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Page 47

1952 126 Ethylene oxide and Carbon

dioxide mixtures, with not

more than 9% Ethylene oxide

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Compressed gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Compressed gas, flammable,

toxic, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Compressed gas, flammable,

toxic, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Compressed gas, flammable,

toxic, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Compressed gas, flammable,

toxic, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Compressed gas, poisonous,

flammable, n.o.s.

1953 119 Compressed gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Compressed gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Compressed gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Compressed gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Compressed gas, toxic,

flammable, n.o.s.

1953 119 Compressed gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Compressed gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Compressed gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Compressed gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Liquefied gas, flammable,

poisonous, n.o.s.

1953 119 Liquefied gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone A)

1953 119 Liquefied gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone B)

1953 119 Liquefied gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone C)

1953 119 Liquefied gas, flammable,

poisonous, n.o.s. (Inhalation

Hazard Zone D)

1953 119 Liquefied gas, flammable, toxic,

n.o.s.

1953 119 Liquefied gas, flammable, toxic,

n.o.s. (Inhalation Hazard

Zone A)

1953 119 Liquefied gas, flammable, toxic,

n.o.s. (Inhalation Hazard

Zone B)
ID Guide Name of Material

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ID Guide Name of Material

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Page 48

1953 119 Liquefied gas, flammable, toxic,

n.o.s. (Inhalation Hazard

Zone C)

1953 119 Liquefied gas, flammable, toxic,

n.o.s. (Inhalation Hazard

Zone D)

1954 115 Compressed gas, flammable,

n.o.s.

1954 115 Dispersant gas, n.o.s.

(flammable)

1954 115 Insecticide gas, flammable,

n.o.s.

1954 115 Liquefied gas, flammable, n.o.s.

1954 115 Refrigerant gas, n.o.s.

(flammable)

1954 115 Refrigerating machines,

containing flammable, nonpoisonous, non-corrosive,

liquefied gas

1955 123 Compressed gas, poisonous,

n.o.s.

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone A)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone B)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone C)

1955 123 Compressed gas, poisonous,

n.o.s. (Inhalation Hazard

Zone D)

1955 123 Compressed gas, toxic, n.o.s.

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone A)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone B)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone C)

1955 123 Compressed gas, toxic, n.o.s.

(Inhalation Hazard Zone D)

1955 123 Liquefied gas, poisonous, n.o.s.

1955 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone A)

1955 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone B)

1955 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone C)

1955 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone D)

1955 123 Liquefied gas, toxic, n.o.s.

1955 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone A)

1955 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone B)

1955 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone C)

1955 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone D)

1955 123 Organic phosphate compound

mixed with compressed gas

1955 123 Organic phosphate mixed with

compressed gas

1955 123 Organic phosphorus compound

mixed with compressed gas

1956 126 Accumulators, pressurized,

pneumatic or hydraulic

1956 126 Compressed gas, n.o.s.

1956 126 Hexafluoropropylene oxide

1956 126 Liquefied gas, n.o.s.

1957 115 Deuterium

1957 115 Deuterium, compressed

1958 126 1,2-Dichloro-1,1,2,2-

tetrafluoroethane
ID Guide Name of Material

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Page 49

1958 126 Dichlorotetrafluoroethane

1958 126 Refrigerant gas R-114

1959 116P 1,1-Difluoroethylene

1959 116P Refrigerant gas R-1132a

1960 115 Engine starting fluid

1961 115 Ethane, refrigerated liquid

1961 115 Ethane-Propane mixture,

refrigerated liquid

1961 115 Propane-Ethane mixture,

refrigerated liquid

1962 116P Ethylene

1962 116P Ethylene, compressed

1963 120 Helium, refrigerated liquid

(cryogenic liquid)

1964 115 Hydrocarbon gas, compressed,

n.o.s.

1964 115 Hydrocarbon gas mixture,

compressed, n.o.s.

1965 115 Hydrocarbon gas, liquefied, n.o.s.

1965 115 Hydrocarbon gas mixture,

liquefied, n.o.s.

1966 115 Hydrogen, refrigerated liquid

(cryogenic liquid)

1967 123 Insecticide gas, poisonous,

n.o.s.

1967 123 Insecticide gas, toxic, n.o.s.

1967 123 Parathion and compressed gas

mixture

1968 126 Insecticide gas, n.o.s.

1969 115 Isobutane

1969 115 Isobutane mixture

1970 120 Krypton, refrigerated liquid

(cryogenic liquid)

1971 115 Methane

1971 115 Methane, compressed

1971 115 Natural gas, compressed

1972 115 Liquefied natural gas (cryogenic

liquid)

1972 115 LNG (cryogenic liquid)

1972 115 Methane, refrigerated liquid

(cryogenic liquid)

1972 115 Natural gas, refrigerated liquid

(cryogenic liquid)

1973 126 Chlorodifluoromethane and

Chloropentafluoroethane

mixture

1973 126 Chloropentafluoroethane and

Chlorodifluoromethane

mixture

1973 126 Refrigerant gas R-502

1974 126 Bromochlorodifluoromethane

1974 126 Chlorodifluorobromomethane

1974 126 Refrigerant gas R-12B1

1975 124 Dinitrogen tetroxide and Nitric

oxide mixture

1975 124 Nitric oxide and Dinitrogen

tetroxide mixture

1975 124 Nitric oxide and Nitrogen

dioxide mixture

1975 124 Nitric oxide and Nitrogen

tetroxide mixture

1975 124 Nitrogen dioxide and Nitric oxide

mixture

1975 124 Nitrogen tetroxide and Nitric

oxide mixture

1976 126 Octafluorocyclobutane

1976 126 Refrigerant gas RC-318

1977 120 Nitrogen, refrigerated liquid

(cryogenic liquid)

1978 115 Propane

1978 115 Propane mixture
ID Guide Name of Material

No. No.

ID Guide Name of Material

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Page 50

1979 121 Rare gases mixture

1979 121 Rare gases mixture, compressed

1980 121 Oxygen and Rare gases mixture

1980 121 Oxygen and Rare gases mixture,

compressed

1980 121 Rare gases and Oxygen mixture

1980 121 Rare gases and Oxygen mixture,

compressed

1981 121 Nitrogen and Rare gases mixture

1981 121 Nitrogen and Rare gases

mixture, compressed

1981 121 Rare gases and Nitrogen

mixture

1981 121 Rare gases and Nitrogen

mixture, compressed

1982 126 Refrigerant gas R-14

1982 126 Refrigerant gas R-14,

compressed

1982 126 Tetrafluoromethane

1982 126 Tetrafluoromethane,

compressed

1983 126 1-Chloro-2,2,2-trifluoroethane

1983 126 Chlorotrifluoroethane

1983 126 Refrigerant gas R-133a

1984 126 Refrigerant gas R-23

1984 126 Trifluoromethane

1986 131 Alcohols, flammable, poisonous,

n.o.s.

1986 131 Alcohols, flammable, toxic, n.o.s.

1986 131 Alcohols, poisonous, n.o.s.

1986 131 Alcohols, toxic, n.o.s.

1986 131 Denatured alcohol (toxic)

1986 131 Propargyl alcohol

1987 127 Alcohols, n.o.s.

1987 127 Denatured alcohol

1988 131 Aldehydes, flammable,

poisonous, n.o.s.

1988 131 Aldehydes, flammable, toxic,

n.o.s.

1988 131 Aldehydes, poisonous, n.o.s.

1988 131 Aldehydes, toxic, n.o.s.

1989 129 Aldehydes, n.o.s.

1990 129 Benzaldehyde

1991 131P Chloroprene, inhibited

1991 131P Chloroprene, stabilized

1992 131 Flammable liquid, poisonous,

n.o.s.

1992 131 Flammable liquid, toxic, n.o.s.

1993 128 Combustible liquid, n.o.s.

1993 128 Compound, cleaning liquid

(flammable)

1993 128 Compound, tree or weed killing,

liquid (flammable)

1993 128 Diesel fuel

1993 128 Flammable liquid, n.o.s.

1993 128 Fuel oil

1993 128 Medicines, flammable, liquid,

n.o.s.

1993 128 Refrigerating machine

1994 131 Iron pentacarbonyl

1999 130 Asphalt

1999 130 Tars, liquid

2000 133 Celluloid, in blocks, rods, rolls,

sheets, tubes, etc., except

scrap

2001 133 Cobalt naphthenates, powder

2002 135 Celluloid, scrap

2003 135 Metal alkyls, n.o.s.

2003 135 Metal alkyls, water-reactive,

n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 51

2003 135 Metal aryls, n.o.s

2003 135 Metal aryls, water-reactive,

n.o.s.

2004 135 Magnesium diamide

2005 135 Magnesium diphenyl

2006 135 Plastic, nitrocellulose-based,

spontaneously combustible,

n.o.s.

2006 135 Plastics, nitrocellulose-based,

self-heating, n.o.s.

2008 135 Zirconium powder, dry

2009 135 Zirconium, dry, finished sheets,

strips or coiled wire

2010 138 Magnesium hydride

2011 139 Magnesium phosphide

2012 139 Potassium phosphide

2013 139 Strontium phosphide

2014 140 Hydrogen peroxide, aqueous

solution, with not less than

20% but not more than 60%

Hydrogen peroxide

(stabilized as necessary)

2015 143 Hydrogen peroxide, aqueous

solution, stabilized, with

more than 60% Hydrogen

peroxide

2015 143 Hydrogen peroxide, stabilized

2016 151 Ammunition, poisonous,

non-explosive

2016 151 Ammunition, toxic,

non-explosive

2017 159 Ammunition, tear-producing,

non-explosive

2018 152 Chloroanilines, solid

2019 152 Chloroanilines, liquid

2020 153 Chlorophenols, solid

2021 153 Chlorophenols, liquid

2022 153 Cresylic acid

2023 131P 1-Chloro-2,3-epoxypropane

2023 131P Epichlorohydrin

2024 151 Mercury compound, liquid,

n.o.s.

2025 151 Mercury compound, solid, n.o.s.

2026 151 Phenylmercuric compound,

n.o.s.

2027 151 Sodium arsenite, solid

2028 153 Bombs, smoke, non-explosive,

with corrosive liquid, without

initiating device

2029 132 Hydrazine, anhydrous

2029 132 Hydrazine, aqueous solutions,

with more than 64%

Hydrazine

2030 153 Hydrazine, aqueous solution,

with more than 37%

Hydrazine

2030 153 Hydrazine, aqueous solution,

with not less than 37% but not

more than 64% Hydrazine

2030 153 Hydrazine hydrate

2031 157 Nitric acid, other than red

fuming

2032 157 Nitric acid, fuming

2032 157 Nitric acid, red fuming

2033 154 Potassium monoxide

2034 115 Hydrogen and Methane mixture,

compressed

2034 115 Methane and Hydrogen mixture,

compressed

2035 115 Refrigerant gas R-143a

2035 115 1,1,1-Trifluoroethane

2035 115 Trifluoroethane, compressed

2036 121 Xenon
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 52

2036 121 Xenon, compressed

2037 115 Gas cartridges

2037 115 Receptacles, small, containing

gas

2038 152 Dinitrotoluenes

2038 152 Dinitrotoluenes, liquid

2038 152 Dinitrotoluenes, solid

2044 115 2,2-Dimethylpropane

2045 130 Isobutyl aldehyde

2045 130 Isobutyraldehyde

2046 130 Cymenes

2047 129 Dichloropropenes

2048 130 Dicyclopentadiene

2049 130 Diethylbenzene

2050 128 Diisobutylene, isomeric

compounds

2051 132 2-Dimethylaminoethanol

2051 132 Dimethylethanolamine

2052 128 Dipentene

2053 129 Methylamyl alcohol

2053 129 Methyl isobutyl carbinol

2053 129 M.I.B.C.

2054 132 Morpholine

2055 128P Styrene monomer, inhibited

2055 128P Styrene monomer, stabilized

2056 127 Tetrahydrofuran

2057 128 Tripropylene

2058 129 Valeraldehyde

2059 127 Nitrocellulose, solution,

flammable

2059 127 Nitrocellulose, solution, in a

flammable liquid

2067 140 Ammonium nitrate fertilizers

2068 140 Ammonium nitrate fertilizers, with

Calcium carbonate

2069 140 Ammonium nitrate fertilizers, with

Ammonium sulfate

2069 140 Ammonium nitrate fertilizers, with

Ammonium sulphate

2069 140 Ammonium nitrate mixed

fertilizers

2070 143 Ammonium nitrate fertilizers,

with Phosphate or Potash

2071 140 Ammonium nitrate fertilizer,

with not more than 0.4%

combustible material

2071 140 Ammonium nitrate fertilizers

2072 140 Ammonium nitrate fertilizer, n.o.s.

2072 140 Ammonium nitrate fertilizers

2073 125 Ammonia, solution, with more

than 35% but not more than

50% Ammonia

2074 153P Acrylamide

2074 153P Acrylamide, solid

2075 153 Chloral, anhydrous, inhibited

2075 153 Chloral, anhydrous, stabilized

2076 153 Cresols

2076 153 Cresols, liquid

2076 153 Cresols, solid

2077 153 alpha-Naphthylamine

2077 153 Naphthylamine (alpha)

2078 156 Toluene diisocyanate

2079 154 Diethylenetriamine

2186 125 Hydrogen chloride, refrigerated

liquid

2187 120 Carbon dioxide, refrigerated

liquid

2188 119 Arsine

2188 119 SA
ID Guide Name of Material

No. No.

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Page 53

2189 119 Dichlorosilane

2190 124 Oxygen difluoride

2190 124 Oxygen difluoride, compressed

2191 123 Sulfuryl fluoride

2191 123 Sulphuryl fluoride

2192 119 Germane

2193 126 Hexafluoroethane

2193 126 Hexafluoroethane, compressed

2193 126 Refrigerant gas R-116

2193 126 Refrigerant gas R-116,

compressed

2194 125 Selenium hexafluoride

2195 125 Tellurium hexafluoride

2196 125 Tungsten hexafluoride

2197 125 Hydrogen iodide, anhydrous

2198 125 Phosphorus pentafluoride

2198 125 Phosphorus pentafluoride,

compressed

2199 119 Phosphine

2200 116P Propadiene, inhibited

2200 116P Propadiene, stabilized

2201 122 Nitrous oxide, refrigerated

liquid

2202 117 Hydrogen selenide, anhydrous

2203 116 Silane

2203 116 Silane, compressed

2204 119 Carbonyl sulfide

2204 119 Carbonyl sulphide

2205 153 Adiponitrile

2206 155 Isocyanate solution, poisonous,

n.o.s.

2206 155 Isocyanate solution, toxic,

n.o.s.

2206 155 Isocyanate solutions, n.o.s.

2206 155 Isocyanates, n.o.s.

2206 155 Isocyanates, poisonous, n.o.s.

2206 155 Isocyanates, toxic, n.o.s.

2208 140 Bleaching powder

2208 140 Calcium hypochlorite mixture,

dry, with more than 10% but

not more than 39% available

Chlorine

2209 132 Formaldehyde, solutions

(Formalin) (corrosive)

2210 135 Maneb

2210 135 Maneb preparation, with not

less than 60% Maneb

2211 133 Polymeric beads, expandable

2211 133 Polystyrene beads, expandable

2212 171 Asbestos

2212 171 Asbestos, blue

2212 171 Asbestos, brown

2212 171 Blue asbestos

2212 171 Brown asbestos

2213 133 Paraformaldehyde

2214 156 Phthalic anhydride

2215 156 Maleic acid

2215 156 Maleic anhydride

2215 156 Maleic anhydride, molten

2216 171 Fish meal, stabilized

2216 171 Fish scrap, stabilized

2217 135 Seed cake, with not more than

1.5% oil and not more than

11% moisture

2218 132P Acrylic acid, inhibited

2218 132P Acrylic acid, stabilized

2219 129 Allyl glycidyl ether

2222 128 Anisole

2224 152 Benzonitrile
ID Guide Name of Material

No. No.

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Page 54

2225 156 Benzenesulfonyl chloride

2225 156 Benzenesulphonyl chloride

2226 156 Benzotrichloride

2227 130P n-Butyl methacrylate

2227 130P n-Butyl methacrylate, inhibited

2227 130P n-Butyl methacrylate, stabilized

2232 153 Chloroacetaldehyde

2232 153 2-Chloroethanal

2233 152 Chloroanisidines

2234 130 Chlorobenzotrifluorides

2235 153 Chlorobenzyl chlorides

2235 153 Chlorobenzyl chlorides, liquid

2236 156 3-Chloro-4-methylphenyl

isocyanate

2236 156 3-Chloro-4-methylphenyl

isocyanate, liquid

2237 153 Chloronitroanilines

2238 129 Chlorotoluenes

2239 153 Chlorotoluidines

2239 153 Chlorotoluidines, liquid

2239 153 Chlorotoluidines, solid

2240 154 Chromosulfuric acid

2240 154 Chromosulphuric acid

2241 128 Cycloheptane

2242 128 Cycloheptene

2243 130 Cyclohexyl acetate

2244 129 Cyclopentanol

2245 128 Cyclopentanone

2246 128 Cyclopentene

2247 128 n-Decane

2248 132 Di-n-butylamine

2249 131 Dichlorodimethyl ether,

symmetrical

2250 156 Dichlorophenyl isocyanates

2251 128P Bicyclo[2.2.1]hepta-2,5-diene

2251 128P Bicyclo[2.2.1]hepta-2,5-diene,

inhibited

2251 128P Bicyclo[2.2.1]hepta-2,5-diene,

stabilized

2251 128P Dicycloheptadiene

2251 128P 2,5-Norbornadiene

2251 128P 2,5-Norbornadiene, inhibited

2251 128P 2,5-Norbornadiene, stabilized

2252 127 1,2-Dimethoxyethane

2253 153 N,N-Dimethylaniline

2254 133 Matches, fusee

2256 130 Cyclohexene

2257 138 Potassium

2257 138 Potassium, metal

2258 132 1,2-Propylenediamine

2258 132 1,3-Propylenediamine

2259 153 Triethylenetetramine

2260 132 Tripropylamine

2261 153 Xylenols

2261 153 Xylenols, solid

2262 156 Dimethylcarbamoyl chloride

2263 128 Dimethylcyclohexanes

2264 132 N,N-Dimethylcyclohexylamine

2264 132 Dimethylcyclohexylamine

2265 129 N,N-Dimethylformamide

2266 132 Dimethyl-N-propylamine

2267 156 Dimethyl thiophosphoryl chloride

2269 153 3,3'-Iminodipropylamine

2270 132 Ethylamine, aqueous solution,

with not less than 50% but not

more than 70% Ethylamine

2271 128 Ethyl amyl ketone

2272 153 N-Ethylaniline
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Page 55

2273 153 2-Ethylaniline

2274 153 N-Ethyl-N-benzylaniline

2275 129 2-Ethylbutanol

2276 132 2-Ethylhexylamine

2277 130P Ethyl methacrylate

2277 130P Ethyl methacrylate, inhibited

2277 130P Ethyl methacrylate, stabilized

2278 128 n-Heptene

2279 151 Hexachlorobutadiene

2280 153 Hexamethylenediamine, solid

2281 156 Hexamethylene diisocyanate

2282 129 Hexanols

2283 130P Isobutyl methacrylate

2283 130P Isobutyl methacrylate, inhibited

2283 130P Isobutyl methacrylate, stabilized

2284 131 Isobutyronitrile

2285 156 Isocyanatobenzotrifluorides

2286 128 Pentamethylheptane

2287 128 Isoheptenes

2288 128 Isohexenes

2289 153 Isophoronediamine

2290 156 IPDI

2290 156 Isophorone diisocyanate

2291 151 Lead compound, soluble, n.o.s.

2293 128 4-Methoxy-4-methylpentan-2-

one

2294 153 N-Methylaniline

2295 155 Methyl chloroacetate

2296 128 Methylcyclohexane

2297 128 Methylcyclohexanone

2298 128 Methylcyclopentane

2299 155 Methyl dichloroacetate

2300 153 2-Methyl-5-ethylpyridine

2301 128 2-Methylfuran

2302 127 5-Methylhexan-2-one

2303 128 Isopropenylbenzene

2304 133 Naphthalene, molten

2305 153 Nitrobenzenesulfonic acid

2305 153 Nitrobenzenesulphonic acid

2306 152 Nitrobenzotrifluorides

2306 152 Nitrobenzotrifluorides, liquid

2307 152 3-Nitro-4-chlorobenzotrifluoride

2308 157 Nitrosylsulfuric acid

2308 157 Nitrosylsulfuric acid, liquid

2308 157 Nitrosylsulfuric acid, solid

2308 157 Nitrosylsulphuric acid

2308 157 Nitrosylsulphuric acid, liquid

2308 157 Nitrosylsulphuric acid, solid

2309 128P Octadiene

2310 131 Pentan-2,4-dione

2310 131 2,4-Pentanedione

2310 131 Pentane-2,4-dione

2311 153 Phenetidines

2312 153 Phenol, molten

2313 129 Picolines

2315 171 Articles containing Polychlorinated

biphenyls (PCB)

2315 171 PCB

2315 171 Polychlorinated biphenyls

2315 171 Polychlorinated biphenyls, liquid

2315 171 Polychlorinated biphenyls, solid

2316 157 Sodium cuprocyanide, solid

2317 157 Sodium cuprocyanide, solution

2318 135 Sodium hydrosulfide, solid, with

less than 25% water of

crystallization
ID Guide Name of Material

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Page 56

2318 135 Sodium hydrosulfide, with less

than 25% water of

crystallization

2318 135 Sodium hydrosulphide, solid,

with less than 25% water of

crystallization

2318 135 Sodium hydrosulphide, with

less than 25% water of

crystallization

2319 128 Terpene hydrocarbons, n.o.s.

2320 153 Tetraethylenepentamine

2321 153 Trichlorobenzenes, liquid

2322 152 Trichlorobutene

2323 130 Triethyl phosphite

2324 128 Triisobutylene

2325 129 1,3,5-Trimethylbenzene

2326 153 Trimethylcyclohexylamine

2327 153 Trimethylhexamethylenediamines

2328 156 Trimethylhexamethylene

diisocyanate

2329 130 Trimethyl phosphite

2330 128 Undecane

2331 154 Zinc chloride, anhydrous

2332 129 Acetaldehyde oxime

2333 131 Allyl acetate

2334 131 Allylamine

2335 131 Allyl ethyl ether

2336 131 Allyl formate

2337 131 Phenyl mercaptan

2338 127 Benzotrifluoride

2339 130 2-Bromobutane

2340 130 2-Bromoethyl ethyl ether

2341 130 1-Bromo-3-methylbutane

2342 130 Bromomethylpropanes

2343 130 2-Bromopentane

2344 129 2-Bromopropane

2344 129 Bromopropanes

2345 130 3-Bromopropyne

2346 127 Butanedione

2346 127 Diacetyl

2347 130 Butyl mercaptan

2348 130P Butyl acrylate

2348 130P Butyl acrylates, inhibited

2348 130P Butyl acrylates, stabilized

2350 127 Butyl methyl ether

2351 129 Butyl nitrites

2352 127P Butyl vinyl ether, inhibited

2352 127P Butyl vinyl ether, stabilized

2353 132 Butyryl chloride

2354 131 Chloromethyl ethyl ether

2356 129 2-Chloropropane

2357 132 Cyclohexylamine

2358 128P Cyclooctatetraene

2359 132 Diallylamine

2360 131P Diallyl ether

2361 132 Diisobutylamine

2362 130 1,1-Dichloroethane

2363 129 Ethyl mercaptan

2364 128 n-Propyl benzene

2366 128 Diethyl carbonate

2367 130 alpha-Methylvaleraldehyde

2367 130 Methyl valeraldehyde (alpha)

2368 128 alpha-Pinene

2368 128 Pinene (alpha)

2369 152 Ethylene glycol monobutyl ether

2370 128 1-Hexene

2371 128 Isopentenes

2372 129 1,2-Di-(dimethylamino)ethane
ID Guide Name of Material

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Page 57

2373 127 Diethoxymethane

2374 127 3,3-Diethoxypropene

2375 129 Diethyl sulfide

2375 129 Diethyl sulphide

2376 127 2,3-Dihydropyran

2377 127 1,1-Dimethoxyethane

2378 131 2-Dimethylaminoacetonitrile

2379 132 1,3-Dimethylbutylamine

2380 127 Dimethyldiethoxysilane

2381 130 Dimethyl disulfide

2381 130 Dimethyl disulphide

2382 131 1,2-Dimethylhydrazine

2382 131 Dimethylhydrazine, symmetrical

2383 132 Dipropylamine

2384 127 Di-n-propyl ether

2384 127 Dipropyl ether

2385 129 Ethyl isobutyrate

2386 132 1-Ethylpiperidine

2387 130 Fluorobenzene

2388 130 Fluorotoluenes

2389 128 Furan

2390 129 2-Iodobutane

2391 129 Iodomethylpropanes

2392 129 Iodopropanes

2393 129 Isobutyl formate

2394 129 Isobutyl propionate

2395 132 Isobutyryl chloride

2396 131P Methacrylaldehyde

2396 131P Methacrylaldehyde, inhibited

2396 131P Methacrylaldehyde, stabilized

2397 127 3-Methylbutan-2-one

2398 127 Methyl tert-butyl ether

2399 132 1-Methylpiperidine

2400 130 Methyl isovalerate

2401 132 Piperidine

2402 130 Propanethiols

2403 129P Isopropenyl acetate

2404 131 Propionitrile

2405 129 Isopropyl butyrate

2406 127 Isopropyl isobutyrate

2407 155 Isopropyl chloroformate

2409 129 Isopropyl propionate

2410 129 1,2,3,6-Tetrahydropyridine

2410 129 1,2,5,6-Tetrahydropyridine

2411 131 Butyronitrile

2412 130 Tetrahydrothiophene

2413 128 Tetrapropyl orthotitanate

2414 130 Thiophene

2416 129 Trimethyl borate

2417 125 Carbonyl fluoride

2417 125 Carbonyl fluoride, compressed

2418 125 Sulfur tetrafluoride

2418 125 Sulphur tetrafluoride

2419 116 Bromotrifluoroethylene

2420 125 Hexafluoroacetone

2421 124 Nitrogen trioxide

2422 126 Octafluorobut-2-ene

2422 126 Refrigerant gas R-1318

2424 126 Octafluoropropane

2424 126 Refrigerant gas R-218

2426 140 Ammonium nitrate, liquid (hot

concentrated solution)

2427 140 Potassium chlorate, aqueous

solution

2427 140 Potassium chlorate, solution

2428 140 Sodium chlorate, aqueous

solution
ID Guide Name of Material

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Page 58

2429 140 Calcium chlorate, aqueous

solution

2429 140 Calcium chlorate, solution

2430 153 Alkyl phenols, solid, n.o.s.

(including C2-C12

homologues)

2431 153 Anisidines

2431 153 Anisidines, liquid

2431 153 Anisidines, solid

2432 153 N,N-Diethylaniline

2433 152 Chloronitrotoluenes

2433 152 Chloronitrotoluenes, liquid

2433 152 Chloronitrotoluenes, solid

2434 156 Dibenzyldichlorosilane

2435 156 Ethylphenyldichlorosilane

2436 129 Thioacetic acid

2437 156 Methylphenyldichlorosilane

2438 132 Trimethylacetyl chloride

2439 154 Sodium hydrogendifluoride

2440 154 Stannic chloride, pentahydrate

2440 154 Tin tetrachloride, pentahydrate

2441 135 Titanium trichloride, pyrophoric

2441 135 Titanium trichloride mixture,

pyrophoric

2442 156 Trichloroacetyl chloride

2443 137 Vanadium oxytrichloride

2444 137 Vanadium tetrachloride

2445 135 Lithium alkyls

2445 135 Lithium alkyls, liquid

2446 153 Nitrocresols

2446 153 Nitrocresols, solid

2447 136 Phosphorus, white, molten

2447 136 White phosphorus, molten

2447 136 Yellow phosphorus, molten

2448 133 Sulfur, molten

2448 133 Sulphur, molten

2451 122 Nitrogen trifluoride

2451 122 Nitrogen trifluoride, compressed

2452 116P Ethylacetylene, inhibited

2452 116P Ethylacetylene, stabilized

2453 115 Ethyl fluoride

2453 115 Refrigerant gas R-161

2454 115 Methyl fluoride

2454 115 Refrigerant gas R-41

2455 116 Methyl nitrite

2456 130P 2-Chloropropene

2457 128 2,3-Dimethylbutane

2458 130 Hexadiene

2459 128 2-Methyl-1-butene

2460 128 2-Methyl-2-butene

2461 128 Methylpentadiene

2463 138 Aluminum hydride

2464 141 Beryllium nitrate

2465 140 Dichloroisocyanuric acid, dry

2465 140 Dichloroisocyanuric acid salts

2465 140 Sodium dichloroisocyanurate

2465 140 Sodium dichloro-s-triazinetrione

2466 143 Potassium superoxide

2467 140 Sodium percarbonates

2468 140 Trichloroisocyanuric acid, dry

2468 140 (mono)-(Trichloro)-tetra-

(monopotassium dichloro)-

penta-s-triazinetrione, dry

2469 140 Zinc bromate

2470 152 Phenylacetonitrile, liquid

2471 154 Osmium tetroxide

2473 154 Sodium arsanilate
ID Guide Name of Material

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Page 59

2474 157 Thiophosgene

2475 157 Vanadium trichloride

2477 131 Methyl isothiocyanate

2478 155 Isocyanate solution, flammable,

poisonous, n.o.s.

2478 155 Isocyanate solution, flammable,

toxic, n.o.s.

2478 155 Isocyanate solutions, n.o.s.

2478 155 Isocyanates, flammable,

poisonous, n.o.s.

2478 155 Isocyanates, flammable, toxic,

n.o.s.

2478 155 Isocyanates, n.o.s.

2480 155 Methyl isocyanate

2481 155 Ethyl isocyanate

2482 155 n-Propyl isocyanate

2483 155 Isopropyl isocyanate

2484 155 tert-Butyl isocyanate

2485 155 n-Butyl isocyanate

2486 155 Isobutyl isocyanate

2487 155 Phenyl isocyanate

2488 155 Cyclohexyl isocyanate

2490 153 Dichloroisopropyl ether

2491 153 Ethanolamine

2491 153 Ethanolamine, solution

2491 153 Monoethanolamine

2493 132 Hexamethyleneimine

2495 144 Iodine pentafluoride

2496 156 Propionic anhydride

2498 129 1,2,3,6-Tetrahydrobenzaldehyde

2501 152 1-Aziridinyl phosphine oxide

(Tris)

2501 152 Tri-(1-aziridinyl)phosphine

oxide, solution

2501 152 Tris-(1-aziridinyl)phosphine

oxide, solution

2502 132 Valeryl chloride

2503 137 Zirconium tetrachloride

2504 159 Acetylene tetrabromide

2504 159 Tetrabromoethane

2505 154 Ammonium fluoride

2506 154 Ammonium hydrogen sulfate

2506 154 Ammonium hydrogen sulphate

2507 154 Chloroplatinic acid, solid

2508 156 Molybdenum pentachloride

2509 154 Potassium hydrogen sulfate

2509 154 Potassium hydrogen sulphate

2511 153 2-Chloropropionic acid

2511 153 2-Chloropropionic acid, solid

2511 153 2-Chloropropionic acid, solution

2512 152 Aminophenols

2513 156 Bromoacetyl bromide

2514 130 Bromobenzene

2515 159 Bromoform

2516 151 Carbon tetrabromide

2517 115 1-Chloro-1,1-difluoroethane

2517 115 Chlorodifluoroethanes

2517 115 Difluorochloroethanes

2517 115 Refrigerant gas R-142b

2518 153 1,5,9-Cyclododecatriene

2520 130P Cyclooctadienes

2521 131P Diketene, inhibited

2521 131P Diketene, stabilized

2522 153P 2-Dimethylaminoethyl

methacrylate

2522 153P Dimethylaminoethyl methacrylate

2524 129 Ethyl orthoformate
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Page 60

2525 156 Ethyl oxalate

2526 132 Furfurylamine

2527 130P Isobutyl acrylate

2527 130P Isobutyl acrylate, inhibited

2527 130P Isobutyl acrylate, stabilized

2528 130 Isobutyl isobutyrate

2529 132 Isobutyric acid

2530 132 Isobutyric anhydride

2531 153P Methacrylic acid, inhibited

2531 153P Methacrylic acid, stabilized

2533 156 Methyl trichloroacetate

2534 119 Methylchlorosilane

2535 132 4-Methylmorpholine

2535 132 N-Methylmorpholine

2535 132 Methylmorpholine

2536 127 Methyltetrahydrofuran

2538 133 Nitronaphthalene

2541 128 Terpinolene

2542 153 Tributylamine

2545 135 Hafnium powder, dry

2546 135 Titanium powder, dry

2547 143 Sodium superoxide

2548 124 Chlorine pentafluoride

2552 151 Hexafluoroacetone hydrate

2552 151 Hexafluoroacetone hydrate,

liquid

2554 130P Methylallyl chloride

2555 113 Nitrocellulose with water, not

less than 25% water

2556 113 Nitrocellulose with alcohol

2556 113 Nitrocellulose with not less than

25% alcohol

2557 133 Nitrocellulose mixture, without

plasticizer, without pigment

2557 133 Nitrocellulose mixture, without

plasticizer, with pigment

2557 133 Nitrocellulose mixture, with

plasticizer, without pigment

2557 133 Nitrocellulose mixture, with

plasticizer, with pigment

2557 133 Nitrocellulose with plasticizing

substance

2558 131 Epibromohydrin

2560 129 2-Methylpentan-2-ol

2561 128 3-Methyl-1-butene

2564 153 Trichloroacetic acid, solution

2565 153 Dicyclohexylamine

2567 154 Sodium pentachlorophenate

2570 154 Cadmium compound

2571 156 Alkylsulfuric acids

2571 156 Alkylsulphuric acids

2571 156 Ethylsulfuric acid

2571 156 Ethylsulphuric acid

2572 153 Phenylhydrazine

2573 141 Thallium chlorate

2574 151 Tricresyl phosphate

2576 137 Phosphorus oxybromide,

molten

2577 156 Phenylacetyl chloride

2578 157 Phosphorus trioxide

2579 153 Piperazine

2580 154 Aluminum bromide, solution

2581 154 Aluminum chloride, solution

2582 154 Ferric chloride, solution

2583 153 Alkyl sulfonic acids, solid, with

more than 5% free Sulfuric

acid
ID Guide Name of Material

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Page 61

2583 153 Alkyl sulphonic acids, solid, with

more than 5% free Sulphuric

acid

2583 153 Aryl sulfonic acids, solid, with

more than 5% free Sulfuric

acid

2583 153 Aryl sulphonic acids, solid, with

more than 5% free Sulphuric

acid

2583 153 Toluene sulfonic acid, solid,

with more than 5% free

Sulfuric acid

2583 153 Toluene sulphonic acid, solid,

with more than 5% free

Sulphuric acid

2584 153 Alkyl sulfonic acids, liquid, with

more than 5% free Sulfuric acid

2584 153 Alkyl sulphonic acids, liquid,

with more than 5% free

Sulphuric acid

2584 153 Aryl sulfonic acids, liquid, with

more than 5% free Sulfuric

acid

2584 153 Aryl sulphonic acids, liquid,

with more than 5% free

Sulphuric acid

2584 153 Dodecylbenzenesulfonic acid

2584 153 Dodecylbenzenesulphonic acid

2584 153 Toluene sulfonic acid, liquid, with

more than 5% free Sulfuric

acid

2584 153 Toluene sulphonic acid, liquid,

with more than 5% free

Sulphuric acid

2585 153 Alkyl sulfonic acids, solid, with

not more than 5% free

Sulfuric acid

2585 153 Alkyl sulphonic acids, solid, with

not more than 5% free

Sulphuric acid

2585 153 Aryl sulfonic acids, solid, with

not more than 5% free

Sulfuric acid

2585 153 Aryl sulphonic acids, solid, with

not more than 5% free

Sulphuric acid

2585 153 Toluene sulfonic acid, solid,

with not more than 5% free

Sulfuric acid

2585 153 Toluene sulphonic acid, solid,

with not more than 5% free

Sulphuric acid

2586 153 Alkyl sulfonic acids, liquid, with

not more than 5% free Sulfuric

acid

2586 153 Alkyl sulphonic acids, liquid,

with not more than 5% free

Sulphuric acid

2586 153 Aryl sulfonic acids, liquid, with

not more than 5% free

Sulfuric acid

2586 153 Aryl sulphonic acids, liquid,

with not more than 5% free

Sulphuric acid

2586 153 Toluene sulfonic acid, liquid,

with not more than 5% free

Sulfuric acid

2586 153 Toluene sulphonic acid, liquid,

with not more than 5% free

Sulphuric acid

2587 153 Benzoquinone

2588 151 Pesticide, solid, poisonous

2588 151 Pesticide, solid, poisonous,

n.o.s.

2588 151 Pesticide, solid, toxic, n.o.s.

2589 155 Vinyl chloroacetate

2590 171 Asbestos, white

2590 171 White asbestos
ID Guide Name of Material

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Page 62

2591 120 Xenon, refrigerated liquid

(cryogenic liquid)

2599 126 Chlorotrifluoromethane and

Trifluoromethane azeotropic

mixture with approximately

60% Chlorotrifluoromethane

2599 126 Refrigerant gas R-13 and

Refrigerant gas R-23

azeotropic mixture with 60%

Refrigerant gas R-13

2599 126 Refrigerant gas R-23 and

Refrigerant gas R-13

azeotropic mixture with 60%

Refrigerant gas R-13

2599 126 Refrigerant gas R-503

(azeotropic mixture of

Refrigerant gas R-13 and

Refrigerant gas R-23 with

approximately 60%

Refrigerant gas R-13)

2599 126 Trifluoromethane and

Chlorotrifluoromethane

azeotropic mixture with

approximately 60%

Chlorotrifluoromethane

2600 119 Carbon monoxide and Hydrogen

mixture

2600 119 Carbon monoxide and Hydrogen

mixture, compressed

2600 119 Hydrogen and Carbon monoxide

mixture

2600 119 Hydrogen and Carbon monoxide

mixture, compressed

2601 115 Cyclobutane

2602 126 Dichlorodifluoromethane and

Difluoroethane azeotropic

mixture with approximately

74% Dichlorodifluoromethane

2602 126 Difluoroethane and

Dichlorodifluoromethane

azeotropic mixture with

approximately 74%

Dichlorodifluoromethane

2602 126 Refrigerant gas R-12 and

Refrigerant gas R-152a

azeotropic mixture with 74%

Refrigerant gas R-12

2602 126 Refrigerant gas R-152a and

Refrigerant gas R-12

azeotropic mixture with 74%

Refrigerant gas R-12

2602 126 Refrigerant gas R-500

(azeotropic mixture of

Refrigerant gas R-12 and

Refrigerant gas R-152a with

approximately 74%

Refrigerant gas R-12)

2603 131 Cycloheptatriene

2604 132 Boron trifluoride diethyl etherate

2605 155 Methoxymethyl isocyanate

2606 155 Methyl orthosilicate

2607 129P Acrolein dimer, stabilized

2608 129 Nitropropanes

2609 156 Triallyl borate

2610 132 Triallylamine

2611 131 Propylene chlorohydrin

2612 127 Methyl propyl ether

2614 129 Methallyl alcohol

2615 127 Ethyl propyl ether

2616 129 Triisopropyl borate

2617 129 Methylcyclohexanols

2618 130P Vinyltoluenes, inhibited

2618 130P Vinyltoluenes, stabilized

2619 132 Benzyldimethylamine

2620 130 Amyl butyrates
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2621 127 Acetyl methyl carbinol

2622 131P Glycidaldehyde

2623 133 Firelighters, solid, with

flammable liquid

2624 138 Magnesium silicide

2626 140 Chloric acid, aqueous solution,

with not more than 10%

Chloric acid

2627 140 Nitrites, inorganic, n.o.s.

2628 151 Potassium fluoroacetate

2629 151 Sodium fluoroacetate

2630 151 Selenates

2630 151 Selenites

2630 151 Sodium selenite

2642 154 Fluoroacetic acid

2643 155 Methyl bromoacetate

2644 151 Methyl iodide

2645 153 Phenacyl bromide

2646 151 Hexachlorocyclopentadiene

2647 153 Malononitrile

2648 154 1,2-Dibromobutan-3-one

2649 153 1,3-Dichloroacetone

2650 153 1,1-Dichloro-1-nitroethane

2651 153 4,4'-Diaminodiphenylmethane

2653 156 Benzyl iodide

2655 151 Potassium fluorosilicate

2655 151 Potassium silicofluoride

2656 154 Quinoline

2657 153 Selenium disulfide

2657 153 Selenium disulphide

2658 152 Selenium powder

2659 151 Sodium chloroacetate

2660 153 Mononitrotoluidines

2660 153 Nitrotoluidines (mono)

2661 153 Hexachloroacetone

2662 153 Hydroquinone

2662 153 Hydroquinone, solid

2664 160 Dibromomethane

2666 156 Ethyl cyanoacetate

2667 152 Butyltoluenes

2668 131 Chloroacetonitrile

2669 152 Chlorocresols

2669 152 Chlorocresols, liquid

2669 152 Chlorocresols, solid

2669 152 Chlorocresols, solution

2670 157 Cyanuric chloride

2671 153 Aminopyridines

2672 154 Ammonia, solution, with more

than 10% but not more than

35% Ammonia

2672 154 Ammonium hydroxide

2672 154 Ammonium hydroxide, with

more than 10% but not more

than 35% Ammonia

2673 151 2-Amino-4-chlorophenol

2674 154 Sodium fluorosilicate

2674 154 Sodium silicofluoride

2676 119 Stibine

2677 154 Rubidium hydroxide, solution

2678 154 Rubidium hydroxide

2678 154 Rubidium hydroxide, solid

2679 154 Lithium hydroxide, solution

2680 154 Lithium hydroxide

2680 154 Lithium hydroxide, monohydrate

2680 154 Lithium hydroxide, solid

2681 154 Caesium hydroxide, solution

2681 154 Cesium hydroxide, solution

2682 157 Caesium hydroxide
ID Guide Name of Material

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2682 157 Cesium hydroxide

2683 132 Ammonium sulfide, solution

2683 132 Ammonium sulphide, solution

2684 132 3-Diethylaminopropylamine

2684 132 Diethylaminopropylamine

2685 132 N,N-Diethylethylenediamine

2686 132 2-Diethylaminoethanol

2686 132 Diethylaminoethanol

2687 133 Dicyclohexylammonium nitrite

2688 159 1-Bromo-3-chloropropane

2688 159 1-Chloro-3-bromopropane

2689 153 Glycerol alpha-monochlorohydrin

2690 152 N,n-Butylimidazole

2691 137 Phosphorus pentabromide

2692 157 Boron tribromide

2693 154 Bisulfites, aqueous solution,

n.o.s.

2693 154 Bisulfites, inorganic, aqueous

solution, n.o.s.

2693 154 Bisulphites, aqueous solution,

n.o.s.

2693 154 Bisulphites, inorganic, aqueous

solution, n.o.s.

2698 156 Tetrahydrophthalic anhydrides

2699 154 Trifluoroacetic acid

2705 153P 1-Pentol

2707 127 Dimethyldioxanes

2708 127 Butoxyl

2709 128 Butylbenzenes

2710 128 Dipropyl ketone

2711 129 Dibromobenzene

2713 153 Acridine

2714 133 Zinc resinate

2715 133 Aluminum resinate

2716 153 1,4-Butynediol

2717 133 Camphor

2717 133 Camphor, synthetic

2719 141 Barium bromate

2720 141 Chromium nitrate

2721 141 Copper chlorate

2722 140 Lithium nitrate

2723 140 Magnesium chlorate

2724 140 Manganese nitrate

2725 140 Nickel nitrate

2726 140 Nickel nitrite

2727 141 Thallium nitrate

2728 140 Zirconium nitrate

2729 152 Hexachlorobenzene

2730 152 Nitroanisoles

2730 152 Nitroanisoles, liquid

2730 152 Nitroanisoles, solid

2732 152 Nitrobromobenzenes

2732 152 Nitrobromobenzenes, liquid

2732 152 Nitrobromobenzenes, solid

2733 132 Alkylamines, n.o.s.

2733 132 Amines, flammable, corrosive,

n.o.s.

2733 132 Polyalkylamines, n.o.s.

2733 132 Polyamines, flammable,

corrosive, n.o.s.

2734 132 Alkylamines, n.o.s.

2734 132 Amines, liquid, corrosive,

flammable, n.o.s.

2734 132 Polyalkylamines, n.o.s.

2734 132 Polyamines, liquid, corrosive,

flammable, n.o.s.

2735 153 Alkylamines, n.o.s.

2735 153 Amines, liquid, corrosive, n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 65

2735 153 Polyalkylamines, n.o.s.

2735 153 Polyamines, liquid, corrosive,

n.o.s.

2738 153 N-Butylaniline

2739 156 Butyric anhydride

2740 155 n-Propyl chloroformate

2741 141 Barium hypochlorite, with more

than 22% available Chlorine

2742 155 sec-Butyl chloroformate

2742 155 Chloroformates, n.o.s.

2742 155 Chloroformates, poisonous,

corrosive, flammable, n.o.s.

2742 155 Chloroformates, toxic,

corrosive, flammable, n.o.s.

2742 155 Isobutyl chloroformate

2743 155 n-Butyl chloroformate

2744 155 Cyclobutyl chloroformate

2745 157 Chloromethyl chloroformate

2746 156 Phenyl chloroformate

2747 156 tert-Butylcyclohexyl

chloroformate

2748 156 2-Ethylhexyl chloroformate

2749 130 Tetramethylsilane

2750 153 1,3-Dichloropropanol-2

2751 155 Diethylthiophosphoryl chloride

2752 127 1,2-Epoxy-3-ethoxypropane

2753 153 N-Ethylbenzyltoluidines

2753 153 N-Ethylbenzyltoluidines, liquid

2753 153 N-Ethylbenzyltoluidines, solid

2754 153 N-Ethyltoluidines

2757 151 Carbamate pesticide, solid,

poisonous

2757 151 Carbamate pesticide, solid,

toxic

2758 131 Carbamate pesticide, liquid,

flammable, poisonous

2758 131 Carbamate pesticide, liquid,

flammable, toxic

2759 151 Arsenical pesticide, solid,

poisonous

2759 151 Arsenical pesticide, solid, toxic

2760 131 Arsenical pesticide, liquid,

flammable, poisonous

2760 131 Arsenical pesticide, liquid,

flammable, toxic

2761 151 Aldrin, solid

2761 151 Dieldrin

2761 151 Organochlorine pesticide, solid,

poisonous

2761 151 Organochlorine pesticide, solid,

toxic

2762 131 Aldrin, liquid

2762 131 Organochlorine pesticide,

liquid, flammable, poisonous

2762 131 Organochlorine pesticide,

liquid, flammable, toxic

2763 151 Triazine pesticide, solid,

poisonous

2763 151 Triazine pesticide, solid, toxic

2764 131 Triazine pesticide, liquid,

flammable, poisonous

2764 131 Triazine pesticide, liquid,

flammable, toxic

2765 152 Phenoxy pesticide, solid,

poisonous

2765 152 Phenoxy pesticide, solid, toxic

2766 131 Phenoxy pesticide, liquid,

flammable, poisonous

2766 131 Phenoxy pesticide, liquid,

flammable, toxic
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 66

2767 151 Phenyl urea pesticide, solid,

poisonous

2767 151 Phenyl urea pesticide, solid,

toxic

2768 131 Phenyl urea pesticide, liquid,

flammable, poisonous

2768 131 Phenyl urea pesticide, liquid,

flammable, toxic

2769 151 Benzoic derivative pesticide,

solid, poisonous

2769 151 Benzoic derivative pesticide,

solid, toxic

2770 131 Benzoic derivative pesticide,

liquid, flammable, poisonous

2770 131 Benzoic derivative pesticide,

liquid, flammable, toxic

2771 151 Dithiocarbamate pesticide, solid,

poisonous

2771 151 Dithiocarbamate pesticide, solid,

toxic

2771 151 Thiocarbamate pesticide, solid,

poisonous

2771 151 Thiocarbamate pesticide, solid,

toxic

2772 131 Dithiocarbamate pesticide, liquid,

flammable, poisonous

2772 131 Dithiocarbamate pesticide, liquid,

flammable, toxic

2772 131 Thiocarbamate pesticide, liquid,

flammable, poisonous

2772 131 Thiocarbamate pesticide, liquid,

flammable, toxic

2773 151 Phthalimide derivative pesticide,

solid, poisonous

2773 151 Phthalimide derivative pesticide,

solid, toxic

2774 131 Phthalimide derivative pesticide,

liquid, flammable, poisonous

2774 131 Phthalimide derivative pesticide,

liquid, flammable, toxic

2775 151 Copper based pesticide, solid,

poisonous

2775 151 Copper based pesticide, solid,

toxic

2776 131 Copper based pesticide, liquid,

flammable, poisonous

2776 131 Copper based pesticide, liquid,

flammable, toxic

2777 151 Mercury based pesticide, solid,

poisonous

2777 151 Mercury based pesticide, solid,

toxic

2778 131 Mercury based pesticide, liquid,

flammable, poisonous

2778 131 Mercury based pesticide, liquid,

flammable, toxic

2779 153 Substituted nitrophenol

pesticide, solid, poisonous

2779 153 Substituted nitrophenol

pesticide, solid, toxic

2780 131 Substituted nitrophenol

pesticide, liquid, flammable,

poisonous

2780 131 Substituted nitrophenol pesticide,

liquid, flammable, toxic

2781 151 Bipyridilium pesticide, solid,

poisonous

2781 151 Bipyridilium pesticide, solid,

toxic

2782 131 Bipyridilium pesticide, liquid,

flammable, poisonous

2782 131 Bipyridilium pesticide, liquid,

flammable, toxic

2783 152 Methyl parathion, solid

2783 152 Organophosphorus pesticide,

solid, poisonous
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 67

2783 152 Organophosphorus pesticide,

solid, toxic

2783 152 Parathion

2783 152 Tetraethyl pyrophosphate, solid

2784 131 Organophosphorus pesticide,

liquid, flammable, poisonous

2784 131 Organophosphorus pesticide,

liquid, flammable, toxic

2785 152 4-Thiapentanal

2785 152 Thia-4-pentanal

2786 153 Organotin pesticide, solid,

poisonous

2786 153 Organotin pesticide, solid, toxic

2787 131 Organotin pesticide, liquid,

flammable, poisonous

2787 131 Organotin pesticide, liquid,

flammable, toxic

2788 153 Organotin compound, liquid, n.o.s.

2789 132 Acetic acid, glacial

2789 132 Acetic acid, solution, more than

80% acid

2790 153 Acetic acid, solution, more than

10% but not more than 80%

acid

2793 170 Ferrous metal borings,

shavings, turnings or cuttings

2794 154 Batteries, wet, filled with acid

2795 154 Batteries, wet, filled with alkali

2796 157 Battery fluid, acid

2796 157 Sulfuric acid, with not more than

51% acid

2796 157 Sulphuric acid, with not more

than 51% acid

2797 154 Battery fluid, alkali

2797 154 Battery fluid, alkali, with battery

2797 154 Battery fluid, alkali, with

electronic equipment or

actuating device

2798 137 Benzene phosphorus dichloride

2798 137 Phenylphosphorus dichloride

2799 137 Benzene phosphorus

thiodichloride

2799 137 Phenylphosphorus

thiodichloride

2800 154 Batteries, wet, non-spillable

2801 154 Dye, liquid, corrosive, n.o.s.

2801 154 Dye intermediate, liquid,

corrosive, n.o.s.

2802 154 Copper chloride

2803 172 Gallium

2805 138 Lithium hydride, fused solid

2806 138 Lithium nitride

2807 171 Magnetized material

2809 172 Mercury

2809 172 Mercury metal

2810 153 Buzz

2810 153 BZ

2810 153 Compound, tree or weed killing,

liquid (toxic)

2810 153 CS

2810 153 DC

2810 153 GA

2810 153 GB

2810 153 GD

2810 153 GF

2810 153 H

2810 153 HD

2810 153 HL

2810 153 HN-1
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 68

2810 153 HN-2

2810 153 HN-3

2810 153 L (Lewisite)

2810 153 Lewisite

2810 153 Mustard

2810 153 Mustard Lewisite

2810 153 Poison B, liquid, n.o.s.

2810 153 Poisonous liquid, n.o.s.

2810 153 Poisonous liquid, n.o.s.

(Inhalation Hazard Zone A)

2810 153 Poisonous liquid, n.o.s.

(Inhalation Hazard Zone B)

2810 153 Poisonous liquid, organic,

n.o.s.

2810 153 Poisonous liquid, organic,

n.o.s. (Inhalation Hazard

Zone A)

2810 153 Poisonous liquid, organic,

n.o.s. (Inhalation Hazard

Zone B)

2810 153 Sarin

2810 153 Soman

2810 153 Tabun

2810 153 Thickened GD

2810 153 Toxic liquid, n.o.s.

2810 153 Toxic liquid, n.o.s. (Inhalation

Hazard Zone A)

2810 153 Toxic liquid, n.o.s. (Inhalation

Hazard Zone B)

2810 153 Toxic liquid, organic, n.o.s.

2810 153 Toxic liquid, organic, n.o.s.

(Inhalation Hazard Zone A)

2810 153 Toxic liquid, organic, n.o.s.

(Inhalation Hazard Zone B)

2810 153 VX

2811 154 CX

2811 154 Poisonous solid, organic, n.o.s.

2811 154 Selenium oxide

2811 154 Toxic solid, organic, n.o.s.

2812 154 Sodium aluminate, solid

2813 138 Substances, which in contact

with water emit flammable

gases, solid, n.o.s.

2813 138 Water-reactive solid, n.o.s.

2813 138 Water-reactive substances,

solid, n.o.s.

2814 158 Infectious substance, affecting

humans

2815 153 N-Aminoethylpiperazine

2817 154 Ammonium bifluoride, solution

2817 154 Ammonium hydrogendifluoride,

solution

2817 154 Ammonium hydrogen fluoride,

solution

2818 154 Ammonium polysulfide, solution

2818 154 Ammonium polysulphide,

solution

2819 153 Amyl acid phosphate

2820 153 Butyric acid

2821 153 Phenol solution

2822 153 2-Chloropyridine

2823 153 Crotonic acid

2823 153 Crotonic acid, liquid

2823 153 Crotonic acid, solid

2826 155 Ethyl chlorothioformate

2829 153 Caproic acid

2829 153 Hexanoic acid

2830 139 Lithium ferrosilicon

2831 160 1,1,1-Trichloroethane

2834 154 Phosphorous acid

2834 154 Phosphorous acid, ortho
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 69

2835 138 Sodium aluminum hydride

2837 154 Bisulfates, aqueous solution

2837 154 Bisulphates, aqueous solution

2837 154 Sodium bisulfate, solution

2837 154 Sodium bisulphate, solution

2837 154 Sodium hydrogen sulfate,

solution

2837 154 Sodium hydrogen sulphate,

solution

2838 129P Vinyl butyrate, inhibited

2838 129P Vinyl butyrate, stabilized

2839 153 Aldol

2840 129 Butyraldoxime

2841 131 Di-n-amylamine

2842 129 Nitroethane

2844 138 Calcium manganese silicon

2845 135 Ethyl phosphonous dichloride,

anhydrous

2845 135 Methyl phosphonous dichloride

2845 135 Pyrophoric liquid, n.o.s.

2845 135 Pyrophoric liquid, organic, n.o.s.

2846 135 Pyrophoric solid, n.o.s.

2846 135 Pyrophoric solid, organic, n.o.s.

2849 153 3-Chloropropanol-1

2850 128 Propylene tetramer

2851 157 Boron trifluoride, dihydrate

2852 113 Dipicryl sulfide, wetted with not

less than 10% water

2852 113 Dipicryl sulphide, wetted with

not less than 10% water

2853 151 Magnesium fluorosilicate

2853 151 Magnesium silicofluoride

2854 151 Ammonium fluorosilicate

2854 151 Ammonium silicofluoride

2855 151 Zinc fluorosilicate

2855 151 Zinc silicofluoride

2856 151 Fluorosilicates, n.o.s.

2856 151 Silicofluorides, n.o.s.

2857 126 Refrigerating machines,

containing Ammonia

solutions (UN2073)

2857 126 Refrigerating machines,

containing Ammonia solutions

(UN2672)

2857 126 Refrigerating machines,

containing non-flammable,

liquefied gas

2857 126 Refrigerating machines,

containing non-flammable,

non-poisonous gases

2857 126 Refrigerating machines,

containing non-flammable,

non-poisonous, liquefied gas

2857 126 Refrigerating machines,

containing non-flammable,

non-poisonous, noncorrosive, liquefied gas

2857 126 Refrigerating machines,

containing non-flammable,

non-toxic gases

2857 126 Refrigerating machines,

containing non-flammable,

non-toxic, liquefied gas

2857 126 Refrigerating machines,

containing non-flammable,

non-toxic, non-corrosive,

liquefied gas

2858 170 Zirconium, dry, coiled wire,

finished metal sheets or

strips

2859 154 Ammonium metavanadate

2861 151 Ammonium polyvanadate

2862 151 Vanadium pentoxide
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 70

2863 154 Sodium ammonium vanadate

2864 151 Potassium metavanadate

2865 154 Hydroxylamine sulfate

2865 154 Hydroxylamine sulphate

2869 157 Titanium trichloride mixture

2870 135 Aluminum borohydride

2870 135 Aluminum borohydride in devices

2871 170 Antimony powder

2872 159 Dibromochloropropanes

2873 153 Dibutylaminoethanol

2874 153 Furfuryl alcohol

2875 151 Hexachlorophene

2876 153 Resorcinol

2878 170 Titanium sponge granules

2878 170 Titanium sponge powders

2879 157 Selenium oxychloride

2880 140 Calcium hypochlorite, hydrated,

with not less than 5.5% but

not more than 16% water

2880 140 Calcium hypochlorite, hydrated

mixture, with not less than

5.5% but not more than 16%

water

2881 135 Metal catalyst, dry

2881 135 Nickel catalyst, dry

2900 158 Infectious substance, affecting

animals only

2901 124 Bromine chloride

2902 151 Pesticide, liquid, poisonous,

n.o.s.

2902 151 Pesticide, liquid, toxic, n.o.s.

2903 131 Pesticide, liquid, poisonous,

flammable, n.o.s.

2903 131 Pesticide, liquid, toxic,

flammable, n.o.s.

2904 154 Chlorophenates, liquid

2904 154 Chlorophenolates, liquid

2904 154 Phenolates, liquid

2905 154 Chlorophenates, solid

2905 154 Chlorophenolates, solid

2905 154 Phenolates, solid

2907 133 Isosorbide dinitrate mixture

2908 161 Radioactive material, empty

packages

2908 161 Radioactive material, excepted

package, empty packaging

2909 161 Radioactive material, articles

manufactured from depleted

Uranium

2909 161 Radioactive material, articles

manufactured from natural

Thorium

2909 161 Radioactive material, articles

manufactured from natural

Uranium

2909 161 Radioactive material, excepted

package, articles

manufactured from depleted

Uranium

2909 161 Radioactive material, excepted

package, articles

manufactured from natural

Thorium

2909 161 Radioactive material, excepted

package, articles

manufactured from natural

Uranium

2910 161 Radioactive material, excepted

package, articles

manufactured from depleted

Uranium

2910 161 Radioactive material, excepted

package, articles manufactured

from natural Thorium
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 71

2910 161 Radioactive material, excepted

package, articles

manufactured from natural

Uranium

2910 161 Radioactive material, excepted

package, empty packaging

2910 161 Radioactive material, excepted

package, instruments or

articles

2910 161 Radioactive material, excepted

package, limited quantity of

material

2910 161 Radioactive material, limited

quantity, n.o.s.

2911 161 Radioactive material, excepted

package, instruments or

articles

2911 161 Radioactive material, instruments

or articles

2912 162 Radioactive material, low

specific activity (LSA), n.o.s.

2912 162 Radioactive material, low

specific activity (LSA-I)

2913 162 Radioactive material, surface

contaminated objects (SCO)

2913 162 Radioactive material, surface

contaminated objects (SCO-I)

2913 162 Radioactive material, surface

contaminated objects (SCO-II)

2915 163 Radioactive material, Type A

package

2916 163 Radioactive material, Type B(U)

package

2917 163 Radioactive material, Type

B(M) package

2918 165 Radioactive material, fissile,

n.o.s.

2919 163 Radioactive material, transported

under special arrangement

2920 132 Corrosive liquid, flammable, n.o.s.

2920 132 Dichlorobutene

2921 134 Corrosive solid, flammable, n.o.s.

2922 154 Corrosive liquid, poisonous, n.o.s.

2922 154 Corrosive liquid, toxic, n.o.s.

2922 154 Sodium hydrosulfide, solution

2922 154 Sodium hydrosulphide, solution

2923 154 Corrosive solid, poisonous, n.o.s.

2923 154 Corrosive solid, toxic, n.o.s.

2924 132 Flammable liquid, corrosive, n.o.s

2925 134 Flammable solid, corrosive, n.o.s.

2925 134 Flammable solid, corrosive,

organic, n.o.s.

2926 134 Flammable solid, poisonous,

n.o.s.

2926 134 Flammable solid, poisonous,

organic, n.o.s.

2926 134 Flammable solid, toxic, organic,

n.o.s.

2927 154 Ethyl phosphonothioic

dichloride, anhydrous

2927 154 Ethyl phosphorodichloridate

2927 154 Poisonous liquid, corrosive,

n.o.s.

2927 154 Poisonous liquid, corrosive,

n.o.s. (Inhalation Hazard

Zone A)

2927 154 Poisonous liquid, corrosive,

n.o.s. (Inhalation Hazard

Zone B)

2927 154 Toxic liquid, corrosive, organic,

n.o.s.

2927 154 Toxic liquid, corrosive, organic,

n.o.s. (Inhalation Hazard

Zone A)
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 72

2927 154 Toxic liquid, corrosive, organic,

n.o.s. (Inhalation Hazard

Zone B)

2928 154 Poisonous solid, corrosive, n.o.s.

2928 154 Toxic solid, corrosive, organic,

n.o.s.

2929 131 Poisonous liquid, flammable,

n.o.s.

2929 131 Poisonous liquid, flammable,

n.o.s. (Inhalation Hazard

Zone A)

2929 131 Poisonous liquid, flammable,

n.o.s. (Inhalation Hazard

Zone B)

2929 131 Poisonous liquid, flammable,

organic, n.o.s.

2929 131 Poisonous liquid, flammable,

organic, n.o.s. (Inhalation

Hazard Zone A)

2929 131 Poisonous liquid, flammable,

organic, n.o.s. (Inhalation

Hazard Zone B)

2929 131 Toxic liquid, flammable, n.o.s.

2929 131 Toxic liquid, flammable, n.o.s.

(Inhalation Hazard Zone A)

2929 131 Toxic liquid, flammable, n.o.s.

(Inhalation Hazard Zone B)

2929 131 Toxic liquid, flammable,

organic, n.o.s.

2929 131 Toxic liquid, flammable, organic,

n.o.s. (Inhalation Hazard

Zone A)

2929 131 Toxic liquid, flammable, organic,

n.o.s. (Inhalation Hazard

Zone B)

2930 134 Poisonous solid, flammable, n.o.s.

2930 134 Poisonous solid, flammable,

organic, n.o.s.

2930 134 Toxic solid, flammable, n.o.s.

2930 134 Toxic solid, flammable, organic,

n.o.s.

2931 151 Vanadyl sulfate

2931 151 Vanadyl sulphate

2933 129 Methyl 2-chloropropionate

2934 129 Isopropyl 2-chloropropionate

2935 129 Ethyl 2-chloropropionate

2936 153 Thiolactic acid

2937 153 alpha-Methylbenzyl alcohol

2937 153 alpha-Methylbenzyl alcohol,

liquid

2937 153 Methylbenzyl alcohol (alpha)

2938 152 Methyl benzoate

2940 135 Cyclooctadiene phosphines

2940 135 9-Phosphabicyclononanes

2941 153 Fluoroanilines

2942 153 2-Trifluoromethylaniline

2943 129 Tetrahydrofurfurylamine

2945 132 N-Methylbutylamine

2946 153 2-Amino-5-diethylaminopentane

2947 155 Isopropyl chloroacetate

2948 153 3-Trifluoromethylaniline

2949 154 Sodium hydrosulfide, with not

less than 25% water of

crystallization

2949 154 Sodium hydrosulphide, with not

less than 25% water of

crystallization

2950 138 Magnesium granules, coated

2956 149 5-tert-Butyl-2,4,6-trinitrom-xylene

2956 149 Musk xylene

2965 139 Boron trifluoride dimethyl

etherate
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 73

2966 153 Thioglycol

2967 154 Sulfamic acid

2967 154 Sulphamic acid

2968 135 Maneb, stabilized

2968 135 Maneb preparation, stabilized

2969 171 Castor beans, meal, pomace or

flake

2974 164 Radioactive material, special

form, n.o.s.

2975 162 Thorium metal, pyrophoric

2976 162 Thorium nitrate, solid

2977 166 Radioactive material, Uranium

hexafluoride, fissile

2977 166 Uranium hexafluoride, fissile

containing more than 1%

Uranium-235

2978 166 Radioactive material, Uranium

hexafluoride

2978 166 Radioactive material, Uranium

hexafluoride, non-fissile or

fissile-excepted

2978 166 Uranium hexafluoride

2978 166 Uranium hexafluoride, fissileexcepted

2978 166 Uranium hexafluoride, low

specific activity

2978 166 Uranium hexafluoride,

non-fissile

2979 162 Uranium metal, pyrophoric

2980 162 Uranium nitrate, hexahydrate,

solution

2980 162 Uranyl nitrate, hexahydrate,

solution

2981 162 Uranyl nitrate, solid

2982 163 Radioactive material, n.o.s.

2983 129P Ethylene oxide and Propylene

oxide mixture, with not more

than 30% Ethylene oxide

2983 129P Propylene oxide and Ethylene

oxide mixture, with not more

than 30% Ethylene oxide

2984 140 Hydrogen peroxide, aqueous

solution, with not less than

8% but less than 20%

Hydrogen peroxide

2985 155 Chlorosilanes, flammable,

corrosive, n.o.s.

2985 155 Chlorosilanes, n.o.s.

2986 155 Chlorosilanes, corrosive,

flammable, n.o.s.

2986 155 Chlorosilanes, n.o.s.

2987 156 Chlorosilanes, corrosive, n.o.s.

2987 156 Chlorosilanes, n.o.s.

2988 139 Chlorosilanes, n.o.s.

2988 139 Chlorosilanes, water-reactive,

flammable, corrosive, n.o.s.

2989 133 Lead phosphite, dibasic

2990 171 Life-saving appliances, selfinflating

2991 131 Carbamate pesticide, liquid,

poisonous, flammable

2991 131 Carbamate pesticide, liquid,

toxic, flammable

2992 151 Carbamate pesticide, liquid,

poisonous

2992 151 Carbamate pesticide, liquid,

toxic

2993 131 Arsenical pesticide, liquid,

poisonous, flammable

2993 131 Arsenical pesticide, liquid, toxic,

flammable
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 74

2994 151 Arsenical pesticide, liquid,

poisonous

2994 151 Arsenical pesticide, liquid, toxic

2995 131 Organochlorine pesticide, liquid,

poisonous, flammable

2995 131 Organochlorine pesticide, liquid,

toxic, flammable

2996 151 Organochlorine pesticide, liquid,

poisonous

2996 151 Organochlorine pesticide, liquid,

toxic

2997 131 Triazine pesticide, liquid,

poisonous, flammable

2997 131 Triazine pesticide, liquid, toxic,

flammable

2998 151 Triazine pesticide, liquid,

poisonous

2998 151 Triazine pesticide, liquid, toxic

2999 131 Phenoxy pesticide, liquid,

poisonous, flammable

2999 131 Phenoxy pesticide, liquid, toxic,

flammable

3000 152 Phenoxy pesticide, liquid,

poisonous

3000 152 Phenoxy pesticide, liquid, toxic

3001 131 Phenyl urea pesticide, liquid,

poisonous, flammable

3001 131 Phenyl urea pesticide, liquid,

toxic, flammable

3002 151 Phenyl urea pesticide, liquid,

poisonous

3002 151 Phenyl urea pesticide, liquid,

toxic

3003 131 Benzoic derivative pesticide,

liquid, poisonous, flammable

3003 131 Benzoic derivative pesticide,

liquid, toxic, flammable

3004 151 Benzoic derivative pesticide,

liquid, poisonous

3004 151 Benzoic derivative pesticide,

liquid, toxic

3005 131 Dithiocarbamate pesticide,

liquid, poisonous, flammable

3005 131 Dithiocarbamate pesticide,

liquid, toxic, flammable

3005 131 Thiocarbamate pesticide,

liquid, poisonous, flammable

3005 131 Thiocarbamate pesticide,

liquid, toxic, flammable

3006 151 Dithiocarbamate pesticide, liquid,

poisonous

3006 151 Dithiocarbamate pesticide, liquid,

toxic

3006 151 Thiocarbamate pesticide, liquid,

poisonous

3006 151 Thiocarbamate pesticide, liquid,

toxic

3007 131 Phthalimide derivative pesticide,

liquid, poisonous, flammable

3007 131 Phthalimide derivative pesticide,

liquid, toxic, flammable

3008 151 Phthalimide derivative pesticide,

liquid, poisonous

3008 151 Phthalimide derivative pesticide,

liquid, toxic

3009 131 Copper based pesticide, liquid,

poisonous, flammable

3009 131 Copper based pesticide, liquid,

toxic, flammable

3010 151 Copper based pesticide, liquid,

poisonous

3010 151 Copper based pesticide, liquid,

toxic

3011 131 Mercury based pesticide, liquid,

poisonous, flammable
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 75

3011 131 Mercury based pesticide, liquid,

toxic, flammable

3012 151 Mercury based pesticide, liquid,

poisonous

3012 151 Mercury based pesticide, liquid,

toxic

3013 131 Substituted nitrophenol

pesticide, liquid, poisonous,

flammable

3013 131 Substituted nitrophenol

pesticide, liquid, toxic,

flammable

3014 153 Substituted nitrophenol pesticide,

liquid, poisonous

3014 153 Substituted nitrophenol pesticide,

liquid, toxic

3015 131 Bipyridilium pesticide, liquid,

poisonous, flammable

3015 131 Bipyridilium pesticide, liquid,

toxic, flammable

3016 151 Bipyridilium pesticide, liquid,

poisonous

3016 151 Bipyridilium pesticide, liquid,

toxic

3017 131 Organophosphorus pesticide,

liquid, poisonous, flammable

3017 131 Organophosphorus pesticide,

liquid, toxic, flammable

3018 152 Methyl parathion, liquid

3018 152 Organophosphorus pesticide,

liquid, poisonous

3018 152 Organophosphorus pesticide,

liquid, toxic

3018 152 Tetraethyl pyrophosphate, liquid

3019 131 Organotin pesticide, liquid,

poisonous, flammable

3019 131 Organotin pesticide, liquid,

toxic, flammable

3020 153 Organotin pesticide, liquid,

poisonous

3020 153 Organotin pesticide, liquid, toxic

3021 131 Pesticide, liquid, flammable,

poisonous, n.o.s.

3021 131 Pesticide, liquid, flammable,

toxic, n.o.s.

3022 127P 1,2-Butylene oxide, stabilized

3023 131 2-Methyl-2-hepthanethiol

3023 131 tert-Octyl mercaptan

3024 131 Coumarin derivative pesticide,

liquid, flammable, poisonous

3024 131 Coumarin derivative pesticide,

liquid, flammable, toxic

3025 131 Coumarin derivative pesticide,

liquid, poisonous, flammable

3025 131 Coumarin derivative pesticide,

liquid, toxic, flammable

3026 151 Coumarin derivative pesticide,

liquid, poisonous

3026 151 Coumarin derivative pesticide,

liquid, toxic

3027 151 Coumarin derivative pesticide,

solid, poisonous

3027 151 Coumarin derivative pesticide,

solid, toxic

3028 154 Batteries, dry, containing

Potassium hydroxide solid

3048 157 Aluminum phosphide pesticide

3049 138 Metal alkyl halides, n.o.s.

3049 138 Metal alkyl halides, waterreactive, n.o.s.

3049 138 Metal aryl halides, n.o.s.

3049 138 Metal aryl halides, waterreactive, n.o.s.

3050 138 Metal alkyl hydrides, n.o.s.
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3050 138 Metal alkyl hydrides, waterreactive, n.o.s.

3050 138 Metal aryl hydrides, n.o.s.

3050 138 Metal aryl hydrides, waterreactive, n.o.s.

3051 135 Aluminum alkyls

3052 135 Aluminum alkyl halides

3052 135 Aluminum alkyl halides, liquid

3052 135 Aluminum alkyl halides, solid

3053 135 Magnesium alkyls

3054 129 Cyclohexanethiol

3054 129 Cyclohexyl mercaptan

3055 154 2-(2-Aminoethoxy)ethanol

3056 129 n-Heptaldehyde

3057 125 Trifluoroacetyl chloride

3064 127 Nitroglycerin, solution in alcohol,

with more than 1% but not

more than 5% Nitroglycerin

3065 127 Alcoholic beverages

3066 153 Paint (corrosive)

3066 153 Paint related material (corrosive)

3070 126 Dichlorodifluoromethane and

Ethylene oxide mixture, with

not more than 12.5%

Ethylene oxide

3070 126 Dichlorodifluoromethane and

Ethylene oxide mixtures, with

not more than 12% Ethylene

oxide

3070 126 Ethylene oxide and

Dichlorodifluoromethane

mixture, with not more than

12.5% Ethylene oxide

3070 126 Ethylene oxide and

Dichlorodifluoromethane

mixtures, with not more than

12% Ethylene oxide

3071 131 Mercaptan mixture, liquid,

poisonous, flammable, n.o.s.

3071 131 Mercaptan mixture, liquid, toxic,

flammable, n.o.s.

3071 131 Mercaptan mixtures, liquid,

n.o.s.

3071 131 Mercaptans, liquid, n.o.s.

3071 131 Mercaptans, liquid, poisonous,

flammable, n.o.s.

3071 131 Mercaptans, liquid, toxic,

flammable, n.o.s.

3072 171 Life-saving appliances, not selfinflating

3073 131P Vinylpyridines, inhibited

3073 131P Vinylpyridines, stabilized

3076 138 Aluminum alkyl hydrides

3077 171 Environmentally hazardous

substances, solid, n.o.s.

3077 171 Hazardous waste, solid, n.o.s.

3077 171 Other regulated substances,

solid, n.o.s.

3078 138 Cerium, turnings or gritty

powder

3079 131P Methacrylonitrile, inhibited

3079 131P Methacrylonitrile, stabilized

3080 155 Isocyanate solution, poisonous,

flammable, n.o.s.

3080 155 Isocyanate solution, toxic,

flammable, n.o.s.

3080 155 Isocyanate solutions, n.o.s.

3080 155 Isocyanates, n.o.s.

3080 155 Isocyanates, poisonous,

flammable, n.o.s.

3080 155 Isocyanates, toxic, flammable,

n.o.s.

3082 171 Environmentally hazardous

substances, liquid, n.o.s.
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3082 171 Hazardous waste, liquid, n.o.s.

3082 171 Other regulated substances,

liquid, n.o.s.

3083 124 Perchloryl fluoride

3084 140 Corrosive solid, oxidizing, n.o.s.

3085 140 Oxidizing solid, corrosive, n.o.s.

3085 140 Oxidizing substances, solid,

corrosive, n.o.s.

3086 141 Poisonous solid, oxidizing,

n.o.s.

3086 141 Toxic solid, oxidizing, n.o.s.

3087 141 Oxidizing solid, poisonous, n.o.s.

3087 141 Oxidizing solid, toxic, n.o.s.

3087 141 Oxidizing substances, solid,

poisonous, n.o.s.

3087 141 Oxidizing substances, solid,

toxic, n.o.s.

3088 135 Self-heating solid, organic,

n.o.s.

3088 135 Self-heating substances, solid,

n.o.s.

3089 170 Metal powder, flammable, n.o.s.

3090 138 Lithium batteries

3090 138 Lithium batteries, liquid or solid

cathode

3091 138 Lithium batteries contained in

equipment

3091 138 Lithium batteries packed with

equipment

3092 129 1-Methoxy-2-propanol

3093 140 Corrosive liquid, oxidizing,

n.o.s.

3094 138 Corrosive liquid, water-reactive,

n.o.s.

3094 138 Corrosive liquid, which in

contact with water emits

flammable gases, n.o.s.

3095 136 Corrosive solid, self-heating,

n.o.s.

3096 138 Corrosive solid, water-reactive,

n.o.s.

3096 138 Corrosive solid, which in contact

with water emits flammable

gases, n.o.s.

3097 140 Flammable solid, oxidizing, n.o.s.

3098 140 Oxidizing liquid, corrosive, n.o.s.

3098 140 Oxidizing substances, liquid,

corrosive, n.o.s.

3099 142 Oxidizing liquid, poisonous, n.o.s.

3099 142 Oxidizing liquid, toxic, n.o.s.

3099 142 Oxidizing substances, liquid,

poisonous, n.o.s.

3099 142 Oxidizing substances, liquid,

toxic, n.o.s.

3100 135 Oxidizing solid, self-heating,

n.o.s.

3100 135 Oxidizing substances, selfheating, n.o.s.

3100 135 Oxidizing substances, solid,

self-heating, n.o.s.

3101 146 Organic peroxide type B, liquid

3102 146 Organic peroxide type B, solid

3103 146 Organic peroxide type C, liquid

3104 146 Organic peroxide type C, solid

3105 145 Organic peroxide type D, liquid

3106 145 Organic peroxide type D, solid

3107 145 Organic peroxide type E, liquid

3108 145 Organic peroxide type E, solid

3109 145 Organic peroxide type F, liquid

3110 145 Organic peroxide type F, solid

3111 148 Organic peroxide type B, liquid,

temperature controlled
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3112 148 Organic peroxide type B, solid,

temperature controlled

3113 148 Organic peroxide type C, liquid,

temperature controlled

3114 148 Organic peroxide type C, solid,

temperature controlled

3115 148 Organic peroxide type D, liquid,

temperature controlled

3116 148 Organic peroxide type D, solid,

temperature controlled

3117 148 Organic peroxide type E, liquid,

temperature controlled

3118 148 Organic peroxide type E, solid,

temperature controlled

3119 148 Organic peroxide type F, liquid,

temperature controlled

3120 148 Organic peroxide type F, solid,

temperature controlled

3121 144 Oxidizing solid, water-reactive,

n.o.s.

3121 144 Oxidizing substances, solid,

which in contact with water

emit flammable gases, n.o.s.

3122 142 Poisonous liquid, oxidizing,

n.o.s.

3122 142 Poisonous liquid, oxidizing,

n.o.s. (Inhalation Hazard

Zone A)

3122 142 Poisonous liquid, oxidizing,

n.o.s. (Inhalation Hazard

Zone B)

3122 142 Toxic liquid, oxidizing, n.o.s.

3122 142 Toxic liquid, oxidizing, n.o.s.

(Inhalation Hazard Zone A)

3122 142 Toxic liquid, oxidizing, n.o.s.

(Inhalation Hazard Zone B)

3123 139 Poisonous liquid, waterreactive, n.o.s.

3123 139 Poisonous liquid, water-reactive,

n.o.s. (Inhalation Hazard

Zone A)

3123 139 Poisonous liquid, water-reactive,

n.o.s. (Inhalation Hazard

Zone B)

3123 139 Poisonous liquid, which in

contact with water emits

flammable gases, n.o.s.

3123 139 Poisonous liquid, which in

contact with water emits

flammable gases, n.o.s.

(Inhalation Hazard Zone A)

3123 139 Poisonous liquid, which in

contact with water emits

flammable gases, n.o.s.

(Inhalation Hazard Zone B)

3123 139 Toxic liquid, water-reactive,

n.o.s.

3123 139 Toxic liquid, water-reactive,

n.o.s. (Inhalation Hazard

Zone A)

3123 139 Toxic liquid, water-reactive,

n.o.s. (Inhalation Hazard

Zone B)

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s.

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone A)

3123 139 Toxic liquid, which in contact

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone B)

3124 136 Poisonous solid, self-heating,

n.o.s.

3124 136 Toxic solid, self-heating, n.o.s.
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3125 139 Poisonous solid, water-reactive,

n.o.s.

3125 139 Poisonous solid, which in contact

with water emits flammable

gases, n.o.s.

3125 139 Toxic solid, water-reactive,

n.o.s.

3125 139 Toxic solid, which in contact

with water emits flammable

gases, n.o.s.

3126 136 Self-heating solid, corrosive,

organic, n.o.s.

3126 136 Self-heating substance, solid,

corrosive, n.o.s.

3127 135 Self-heating solid, oxidizing,

n.o.s.

3127 135 Self-heating substances, solid,

oxidizing, n.o.s.

3128 136 Self-heating solid, organic,

poisonous, n.o.s.

3128 136 Self-heating solid, organic,

toxic, n.o.s.

3128 136 Self-heating solid, poisonous,

organic, n.o.s.

3128 136 Self-heating solid, toxic,

organic, n.o.s.

3128 136 Self-heating substances, solid,

poisonous, n.o.s.

3128 136 Self-heating substances, solid,

toxic, n.o.s.

3129 138 Substances, which in contact

with water emit flammable

gases, liquid, corrosive,

n.o.s.

3129 138 Water-reactive liquid,

corrosive, n.o.s.

3129 138 Water-reactive substances,

liquid, corrosive, n.o.s.

3130 139 Substances, which in contact

with water emit flammable

gases, liquid, poisonous,

n.o.s.

3130 139 Substances, which in contact

with water emit flammable

gases, liquid, toxic, n.o.s.

3130 139 Water-reactive liquid,

poisonous, n.o.s.

3130 139 Water-reactive liquid, toxic,

n.o.s.

3130 139 Water-reactive substances,

liquid, poisonous, n.o.s.

3130 139 Water-reactive substances,

liquid, toxic, n.o.s.

3131 138 Substances, which in contact

with water emit flammable

gases, solid, corrosive, n.o.s.

3131 138 Water-reactive solid, corrosive,

n.o.s.

3131 138 Water-reactive substances,

solid, corrosive, n.o.s.

3132 138 Substances, which in contact

with water emit flammable

gases, solid, flammable,

n.o.s.

3132 138 Water-reactive solid, flammable,

n.o.s.

3132 138 Water-reactive substances,

solid, flammable, n.o.s.

3133 138 Substances, which in contact

with water emit flammable

gases, solid, oxidizing, n.o.s.

3133 138 Water-reactive solid, oxidizing,

n.o.s.

3133 138 Water-reactive substances,

solid, oxidizing, n.o.s.
ID Guide Name of Material

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Page 80

3134 139 Substances, which in contact

with water emit flammable

gases, solid, poisonous, n.o.s.

3134 139 Substances, which in contact

with water emit flammable

gases, solid, toxic, n.o.s.

3134 139 Water-reactive solid,

poisonous, n.o.s.

3134 139 Water-reactive solid, toxic, n.o.s.

3134 139 Water-reactive substances,

solid, poisonous, n.o.s.

3134 139 Water-reactive substances,

solid, toxic, n.o.s.

3135 138 Substances, which in contact with

water emit flammable gases,

solid, self-heating, n.o.s.

3135 138 Water-reactive solid, selfheating, n.o.s.

3135 138 Water-reactive substances,

solid, self-heating, n.o.s.

3136 120 Trifluoromethane, refrigerated

liquid

3137 140 Oxidizing solid, flammable,

n.o.s.

3137 140 Oxidizing substances, solid,

flammable, n.o.s.

3138 115 Acetylene, Ethylene and

Propylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

3138 115 Ethylene, Acetylene and

Propylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

3138 115 Propylene, Ethylene and

Acetylene in mixture,

refrigerated liquid containing at

least 71.5% Ethylene with not

more than 22.5% Acetylene

and not more than 6%

Propylene

3139 140 Oxidizing liquid, n.o.s.

3139 140 Oxidizing substances, liquid,

n.o.s.

3140 151 Alkaloids, liquid, n.o.s.

(poisonous)

3140 151 Alkaloid salts, liquid, n.o.s.

(poisonous)

3141 157 Antimony compound, inorganic,

liquid, n.o.s.

3142 151 Disinfectant, liquid, poisonous,

n.o.s.

3142 151 Disinfectant, liquid, toxic, n.o.s.

3142 151 Disinfectants, liquid, n.o.s.

(poisonous)

3143 151 Dye, solid, poisonous, n.o.s.

3143 151 Dye, solid, toxic, n.o.s.

3143 151 Dye intermediate, solid,

poisonous, n.o.s.

3143 151 Dye intermediate, solid, toxic,

n.o.s.

3144 151 Nicotine compound, liquid, n.o.s.

3144 151 Nicotine preparation, liquid,

n.o.s.

3145 153 Alkyl phenols, liquid, n.o.s.

(including C2-C12

homologues)

3146 153 Organotin compound, solid,

n.o.s.

3147 154 Dye, solid, corrosive, n.o.s.

3147 154 Dye intermediate, solid,

corrosive, n.o.s.
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Page 81

3148 138 Substances, which in contact

with water emit flammable

gases, liquid, n.o.s.

3148 138 Water-reactive liquid, n.o.s.

3148 138 Water-reactive substances,

liquid, n.o.s.

3149 140 Hydrogen peroxide and

Peroxyacetic acid mixture,

with acid(s), water and not

more than 5% Peroxyacetic

acid, stabilized

3150 115 Devices, small, hydrocarbon

gas powered, with release

device

3150 115 Hydrocarbon gas refills for

small devices, with release

device

3151 171 Polyhalogenated biphenyls,

liquid

3151 171 Polyhalogenated terphenyls,

liquid

3152 171 Polyhalogenated biphenyls,

solid

3152 171 Polyhalogenated terphenyls,

solid

3153 115 Perfluoromethyl vinyl ether

3153 115 Perfluoro(methyl vinyl ether)

3154 115 Perfluoroethyl vinyl ether

3154 115 Perfluoro(ethyl vinyl ether)

3155 154 Pentachlorophenol

3156 122 Compressed gas, oxidizing,

n.o.s.

3157 122 Liquefied gas, oxidizing, n.o.s.

3158 120 Gas, refrigerated liquid, n.o.s.

3159 126 Refrigerant gas R-134a

3159 126 1,1,1,2-Tetrafluoroethane

3160 119 Liquefied gas, poisonous,

flammable, n.o.s.

3160 119 Liquefied gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone A)

3160 119 Liquefied gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone B)

3160 119 Liquefied gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone C)

3160 119 Liquefied gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone D)

3160 119 Liquefied gas, toxic, flammable,

n.o.s.

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone A)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone B)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone C)

3160 119 Liquefied gas, toxic, flammable,

n.o.s. (Inhalation Hazard

Zone D)

3161 115 Liquefied gas, flammable, n.o.s.

3162 123 Liquefied gas, poisonous, n.o.s.

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone A)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone B)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone C)

3162 123 Liquefied gas, poisonous, n.o.s.

(Inhalation Hazard Zone D)
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Page 82

3162 123 Liquefied gas, toxic, n.o.s.

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone A)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone B)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone C)

3162 123 Liquefied gas, toxic, n.o.s.

(Inhalation Hazard Zone D)

3163 126 Liquefied gas, n.o.s.

3164 126 Articles, pressurized, hydraulic

(containing non-flammable

gas)

3164 126 Articles, pressurized,

pneumatic (containing nonflammable gas)

3165 131 Aircraft hydraulic power unit

fuel tank

3166 128 Engines, internal combustion,

flammable gas powered

3166 128 Engines, internal combustion,

flammable liquid powered

3166 128 Engines, internal combustion,

including when fitted in

machinery or vehicles

3166 128 Vehicle, flammable gas powered

3166 128 Vehicle, flammable liquid

powered

3167 115 Gas sample, non-pressurized,

flammable, n.o.s., not

refrigerated liquid

3168 119 Gas sample, non-pressurized,

poisonous, flammable, n.o.s.,

not refrigerated liquid

3168 119 Gas sample, non-pressurized,

toxic, flammable, n.o.s., not

refrigerated liquid

3169 123 Gas sample, non-pressurized,

poisonous, n.o.s., not

refrigerated liquid

3169 123 Gas sample, non-pressurized,

toxic, n.o.s., not refrigerated

liquid

3170 138 Aluminum dross

3170 138 Aluminum processing

by-products

3170 138 Aluminum remelting byproducts

3170 138 Aluminum smelting by-products

3171 154 Battery-powered equipment

(wet battery)

3171 154 Battery-powered vehicle (wet

battery)

3171 154 Wheelchair, electric, with

batteries

3172 153 Toxins, extracted from living

sources, liquid, n.o.s.

3172 153 Toxins, extracted from living

sources, n.o.s.

3172 153 Toxins, extracted from living

sources, solid, n.o.s.

3174 135 Titanium disulfide

3174 135 Titanium disulphide

3175 133 Solids containing flammable

liquid, n.o.s.

3176 133 Flammable solid, organic,

molten, n.o.s.

3178 133 Flammable solid, inorganic, n.o.s.

3178 133 Smokeless powder for small

arms

3179 134 Flammable solid, poisonous,

inorganic, n.o.s.

3179 134 Flammable solid, toxic,

inorganic, n.o.s.
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3180 134 Flammable solid, corrosive,

inorganic, n.o.s.

3180 134 Flammable solid, inorganic,

corrosive, n.o.s.

3181 133 Metal salts of organic

compounds, flammable,

n.o.s.

3182 170 Metal hydrides, flammable,

n.o.s.

3183 135 Self-heating liquid, organic,

n.o.s.

3184 136 Self-heating liquid, poisonous,

organic, n.o.s.

3184 136 Self-heating liquid, toxic,

organic, n.o.s.

3185 136 Self-heating liquid, corrosive,

organic, n.o.s.

3186 135 Self-heating liquid, inorganic,

n.o.s.

3187 136 Self-heating liquid, poisonous,

inorganic, n.o.s.

3187 136 Self-heating liquid, toxic,

inorganic, n.o.s.

3188 136 Self-heating liquid, corrosive,

inorganic, n.o.s.

3189 135 Metal powder, self-heating, n.o.s.

3189 135 Self-heating metal powders, n.o.s.

3190 135 Self-heating solid, inorganic,

n.o.s.

3191 136 Self-heating solid, inorganic,

poisonous, n.o.s.

3191 136 Self-heating solid, inorganic,

toxic, n.o.s.

3191 136 Self-heating solid, poisonous,

inorganic, n.o.s.

3191 136 Self-heating solid, toxic,

inorganic, n.o.s.

3192 136 Self-heating solid, corrosive,

inorganic, n.o.s.

3194 135 Pyrophoric liquid, inorganic, n.o.s.

3200 135 Pyrophoric solid, inorganic, n.o.s.

3203 135 Pyrophoric organometallic

compound, n.o.s.

3203 135 Pyrophoric organometallic

compound, water-reactive,

n.o.s.

3205 135 Alkaline earth metal alcoholates,

n.o.s.

3206 136 Alkali metal alcoholates, selfheating, corrosive, n.o.s.

3207 138 Organometallic compound,

water-reactive, flammable,

n.o.s.

3207 138 Organometallic compound

dispersion, water-reactive,

flammable, n.o.s.

3207 138 Organometallic compound

solution, water-reactive,

flammable, n.o.s.

3208 138 Metallic substance, waterreactive, n.o.s.

3209 138 Metallic substance, waterreactive, self-heating, n.o.s.

3210 140 Chlorates, inorganic, aqueous

solution, n.o.s.

3211 140 Perchlorates, inorganic, aqueous

solution, n.o.s.

3212 140 Hypochlorites, inorganic, n.o.s.

3213 140 Bromates, inorganic, aqueous

solution, n.o.s.

3214 140 Permanganates, inorganic,

aqueous solution, n.o.s.

3215 140 Persulfates, inorganic, n.o.s.

3215 140 Persulphates, inorganic, n.o.s.
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3216 140 Persulfates, inorganic, aqueous

solution, n.o.s.

3216 140 Persulphates, inorganic, aqueous

solution, n.o.s.

3217 140 Percarbonates, inorganic, n.o.s.

3218 140 Nitrates, inorganic, aqueous

solution, n.o.s.

3219 140 Nitrites, inorganic, aqueous

solution, n.o.s.

3220 126 Pentafluoroethane

3220 126 Refrigerant gas R-125

3221 149 Self-reactive liquid type B

3222 149 Self-reactive solid type B

3223 149 Self-reactive liquid type C

3224 149 Self-reactive solid type C

3225 149 Self-reactive liquid type D

3226 149 Self-reactive solid type D

3227 149 Self-reactive liquid type E

3228 149 Self-reactive solid type E

3229 149 Self-reactive liquid type F

3230 149 Self-reactive solid type F

3231 150 Self-reactive liquid type B,

temperature controlled

3232 150 Self-reactive solid type B,

temperature controlled

3233 150 Self-reactive liquid type C,

temperature controlled

3234 150 Self-reactive solid type C,

temperature controlled

3235 150 Self-reactive liquid type D,

temperature controlled

3236 150 Self-reactive solid type D,

temperature controlled

3237 150 Self-reactive liquid type E,

temperature controlled

3238 150 Self-reactive solid type E,

temperature controlled

3239 150 Self-reactive liquid type F,

temperature controlled

3240 150 Self-reactive solid type F,

temperature controlled

3241 133 2-Bromo-2-nitropropane-1,3-

diol

3242 149 Azodicarbonamide

3243 151 Solids containing poisonous

liquid, n.o.s.

3243 151 Solids containing toxic liquid,

n.o.s.

3244 154 Solids containing corrosive

liquid, n.o.s.

3245 171 Genetically modified microorganisms

3246 156 Methanesulfonyl chloride

3246 156 Methanesulphonyl chloride

3247 140 Sodium peroxoborate,

anhydrous

3248 131 Medicine, liquid, flammable,

poisonous, n.o.s.

3248 131 Medicine, liquid, flammable,

toxic, n.o.s.

3249 151 Medicine, solid, poisonous, n.o.s.

3249 151 Medicine, solid, toxic, n.o.s.

3250 153 Chloroacetic acid, molten

3251 133 Isosorbide-5-mononitrate

3252 115 Difluoromethane

3252 115 Refrigerant gas R-32

3253 154 Disodium trioxosilicate

3253 154 Disodium trioxosilicate,

pentahydrate

3254 135 Tributylphosphane

3254 135 Tributylphosphine
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3255 135 tert-Butyl hypochlorite

3256 128 Elevated temperature liquid,

flammable, n.o.s., with flash

point above 37.8°C (100°F),

at or above its flash point

3256 128 Elevated temperature liquid,

flammable, n.o.s., with flash

point above 60.5°C (141°F),

at or above its flash point

3257 128 Elevated temperature liquid,

n.o.s., at or above 100°C

(212°F), and below its flash

point

3258 171 Elevated temperature solid,

n.o.s., at or above 240°C

(464°F)

3259 154 Amines, solid, corrosive, n.o.s.

3259 154 Polyamines, solid, corrosive,

n.o.s.

3260 154 Corrosive solid, acidic,

inorganic, n.o.s.

3261 154 Corrosive solid, acidic, organic,

n.o.s.

3262 154 Corrosive solid, basic,

inorganic, n.o.s.

3263 154 Corrosive solid, basic, organic,

n.o.s.

3264 154 Corrosive liquid, acidic,

inorganic, n.o.s.

3265 153 Corrosive liquid, acidic, organic,

n.o.s.

3266 154 Corrosive liquid, basic,

inorganic, n.o.s.

3267 153 Corrosive liquid, basic, organic,

n.o.s.

3268 171 Air bag inflators

3268 171 Air bag inflators, pyrotechnic

3268 171 Air bag modules

3268 171 Air bag modules, pyrotechnic

3268 171 Seat-belt modules

3268 171 Seat-belt pre-tensioners

3268 171 Seat-belt pre-tensioners,

pyrotechnic

3269 128 Polyester resin kit

3270 133 Nitrocellulose membrane filters

3271 127 Ethers, n.o.s.

3272 127 Esters, n.o.s.

3273 131 Nitriles, flammable, poisonous,

n.o.s.

3273 131 Nitriles, flammable, toxic, n.o.s.

3274 132 Alcoholates solution, n.o.s., in

alcohol

3275 131 Nitriles, poisonous, flammable,

n.o.s.

3275 131 Nitriles, toxic, flammable, n.o.s.

3276 151 Nitriles, poisonous, liquid,

n.o.s.

3276 151 Nitriles, poisonous, n.o.s.

3276 151 Nitriles, toxic, liquid, n.o.s

3276 151 Nitriles, toxic, n.o.s.

3277 154 Chloroformates, poisonous,

corrosive, n.o.s.

3277 154 Chloroformates, toxic, corrosive,

n.o.s.

3278 151 Organophosphorus compound,

poisonous, liquid, n.o.s.

3278 151 Organophosphorus compound,

poisonous, n.o.s.

3278 151 Organophosphorus compound,

toxic, liquid, n.o.s.

3278 151 Organophosphorus compound,

toxic, n.o.s.

3279 131 Organophosphorus compound,

poisonous, flammable, n.o.s.
ID Guide Name of Material

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Page 86

3279 131 Organophosphorus compound,

toxic, flammable, n.o.s.

3280 151 Organoarsenic compound,

liquid, n.o.s.

3280 151 Organoarsenic compound, n.o.s.

3281 151 Metal carbonyls, liquid, n.o.s.

3281 151 Metal carbonyls, n.o.s.

3282 151 Organometallic compound,

poisonous, liquid, n.o.s.

3282 151 Organometallic compound,

poisonous, n.o.s.

3282 151 Organometallic compound,

toxic, liquid, n.o.s.

3282 151 Organometallic compound,

toxic, n.o.s.

3283 151 Selenium compound, n.o.s.

3283 151 Selenium compound, solid,

n.o.s.

3284 151 Tellurium compound, n.o.s.

3285 151 Vanadium compound, n.o.s.

3286 131 Flammable liquid, poisonous,

corrosive, n.o.s.

3286 131 Flammable liquid, toxic,

corrosive, n.o.s.

3287 151 Poisonous liquid, inorganic,

n.o.s.

3287 151 Poisonous liquid, inorganic,

n.o.s. (Inhalation Hazard

Zone A)

3287 151 Poisonous liquid, inorganic,

n.o.s. (Inhalation Hazard

Zone B)

3287 151 Toxic liquid, inorganic, n.o.s.

3287 151 Toxic liquid, inorganic, n.o.s.

(Inhalation Hazard Zone A)

3287 151 Toxic liquid, inorganic, n.o.s.

(Inhalation Hazard Zone B)

3288 151 Poisonous solid, inorganic,

n.o.s.

3288 151 Toxic solid, inorganic, n.o.s.

3289 154 Poisonous liquid, corrosive,

inorganic, n.o.s.

3289 154 Poisonous liquid, corrosive,

inorganic, n.o.s. (Inhalation

Hazard Zone A)

3289 154 Poisonous liquid, corrosive,

inorganic, n.o.s. (Inhalation

Hazard Zone B)

3289 154 Toxic liquid, corrosive,

inorganic, n.o.s.

3289 154 Toxic liquid, corrosive,

inorganic, n.o.s. (Inhalation

Hazard Zone A)

3289 154 Toxic liquid, corrosive,

inorganic, n.o.s. (Inhalation

Hazard Zone B)

3290 154 Poisonous solid, corrosive,

inorganic, n.o.s.

3290 154 Toxic solid, corrosive,

inorganic, n.o.s.

3291 158 (Bio)Medical waste, n.o.s.

3291 158 Clinical waste, unspecified,

n.o.s.

3291 158 Medical waste, n.o.s.

3291 158 Regulated medical waste, n.o.s.

3292 138 Batteries, containing Sodium

3292 138 Cells, containing Sodium

3293 152 Hydrazine, aqueous solution,

with not more than 37%

Hydrazine

3294 131 Hydrogen cyanide, solution in

alcohol, with not more than

45% Hydrogen cyanide

3295 128 Hydrocarbons, liquid, n.o.s.
ID Guide Name of Material

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Page 87

3296 126 Heptafluoropropane

3296 126 Refrigerant gas R-227

3297 126 Chlorotetrafluoroethane and

Ethylene oxide mixture, with

not more than 8.8% Ethylene

oxide

3297 126 Ethylene oxide and

Chlorotetrafluoroethane

mixture, with not more than

8.8% Ethylene oxide

3298 126 Ethylene oxide and

Pentafluoroethane mixture,

with not more than 7.9%

Ethylene oxide

3298 126 Pentafluoroethane and

Ethylene oxide mixture, with

not more than 7.9% Ethylene

oxide

3299 126 Ethylene oxide and

Tetrafluoroethane mixture,

with not more than 5.6%

Ethylene oxide

3299 126 Tetrafluoroethane and Ethylene

oxide mixture, with not more

than 5.6% Ethylene oxide

3300 119P Carbon dioxide and Ethylene

oxide mixture, with more than

87% Ethylene oxide

3300 119P Ethylene oxide and Carbon

dioxide mixture, with more

than 87% Ethylene oxide

3301 136 Corrosive liquid, self-heating,

n.o.s.

3302 152 2-Dimethylaminoethyl acrylate

3303 124 Compressed gas, poisonous,

oxidizing, n.o.s.

3303 124 Compressed gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3303 124 Compressed gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3303 124 Compressed gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3303 124 Compressed gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3303 124 Compressed gas, toxic,

oxidizing, n.o.s.

3303 124 Compressed gas, toxic,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3303 124 Compressed gas, toxic,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3303 124 Compressed gas, toxic,

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3303 124 Compressed gas, toxic,

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s.

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 123 Compressed gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3304 123 Compressed gas, toxic,

corrosive, n.o.s.
ID Guide Name of Material

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Page 88

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 123 Compressed gas, toxic,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3305 119 Compressed gas, poisonous,

flammable, corrosive, n.o.s.

3305 119 Compressed gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3305 119 Compressed gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3305 119 Compressed gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3305 119 Compressed gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3305 119 Compressed gas, toxic,

flammable, corrosive, n.o.s.

3305 119 Compressed gas, toxic,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3305 119 Compressed gas, toxic,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3305 119 Compressed gas, toxic,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3305 119 Compressed gas, toxic,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3306 124 Compressed gas, poisonous,

oxidizing, corrosive, n.o.s.

3306 124 Compressed gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3306 124 Compressed gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3306 124 Compressed gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3306 124 Compressed gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3306 124 Compressed gas, toxic,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s.

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone C)
ID Guide Name of Material

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Page 89

3307 124 Liquefied gas, poisonous,

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s.

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone A)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone B)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone C)

3307 124 Liquefied gas, toxic, oxidizing,

n.o.s. (Inhalation Hazard

Zone D)

3308 123 Liquefied gas, poisonous,

corrosive, n.o.s.

3308 123 Liquefied gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3308 123 Liquefied gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3308 123 Liquefied gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3308 123 Liquefied gas, poisonous,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3308 123 Liquefied gas, toxic, corrosive,

n.o.s.

3308 123 Liquefied gas, toxic, corrosive,

n.o.s. (Inhalation Hazard

Zone A)

3308 123 Liquefied gas, toxic, corrosive,

n.o.s. (Inhalation Hazard

Zone B)

3308 123 Liquefied gas, toxic, corrosive,

n.o.s. (Inhalation Hazard

Zone C)

3308 123 Liquefied gas, toxic, corrosive,

n.o.s. (Inhalation Hazard

Zone D)

3309 119 Liquefied gas, poisonous,

flammable, corrosive, n.o.s.

3309 119 Liquefied gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

3309 119 Liquefied gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3309 119 Liquefied gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3309 119 Liquefied gas, poisonous,

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s.

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3309 119 Liquefied gas, toxic, flammable,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)
ID Guide Name of Material

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Page 90

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3310 124 Liquefied gas, poisonous,

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s.

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3310 124 Liquefied gas, toxic, oxidizing,

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3311 122 Gas, refrigerated liquid,

oxidizing, n.o.s.

3312 115 Gas, refrigerated liquid,

flammable, n.o.s.

3313 135 Organic pigments, self-heating

3314 171 Plastic molding compound

3314 171 Plastics moulding compound

3315 151 Chemical sample, poisonous

3315 151 Chemical sample, poisonous

liquid

3315 151 Chemical sample, poisonous

solid

3315 151 Chemical sample, toxic

3315 151 Chemical sample, toxic liquid

3315 151 Chemical sample, toxic solid

3316 171 Chemical kit

3316 171 First aid kit

3317 113 2-Amino-4,6-dinitrophenol,

wetted with not less than 20%

water

3318 125 Ammonia solution, with more

than 50% Ammonia

3319 113 Nitroglycerin mixture,

desensitized, solid, n.o.s.,

with more than 2% but not

more than 10% Nitroglycerin

3319 113 Nitroglycerin mixture with more

than 2% but not more than

10% Nitroglycerin,

desensitized

3320 157 Sodium borohydride and

Sodium hydroxide solution,

with not more than 12%

Sodium borohydride and not

more than 40% Sodium

hydroxide

3321 162 Radioactive material, low

specific activity (LSA-II)

3322 162 Radioactive material, low

specific activity (LSA-III)

3323 163 Radioactive material, Type C

package

3324 165 Radioactive material, low specific

activity (LSA-II), fissile

3325 165 Radioactive material, low specific

activity (LSA-III), fissile

3326 165 Radioactive material, surface

contaminated objects (SCO-I),

fissile

3326 165 Radioactive material, surface

contaminated objects (SCO-II),

fissile

3327 165 Radioactive material, Type A

package, fissile
ID Guide Name of Material

No. No.

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No. No.

Page 91

3328 165 Radioactive material, Type B(U)

package, fissile

3329 165 Radioactive material, Type

B(M) package, fissile

3330 165 Radioactive material, Type C

package, fissile

3331 165 Radioactive material, transported

under special arrangement,

fissile

3332 164 Radioactive material, Type A

package, special form

3333 165 Radioactive material, Type A

package, special form, fissile

3334 171 Aviation regulated liquid, n.o.s.

3334 171 Self-defense spray, nonpressurized

3335 171 Aviation regulated solid, n.o.s.

3336 130 Mercaptan mixture, liquid,

flammable, n.o.s.

3336 130 Mercaptans, liquid, flammable,

n.o.s.

3337 126 Refrigerant gas R-404A

3338 126 Refrigerant gas R-407A

3339 126 Refrigerant gas R-407B

3340 126 Refrigerant gas R-407C

3341 135 Thiourea dioxide

3342 135 Xanthates

3343 113 Nitroglycerin mixture,

desensitized, liquid,

flammable, n.o.s., with not

more than 30% Nitroglycerin

3344 113 Pentaerythrite tetranitrate

mixture, desensitized, solid,

n.o.s., with more than 10%

but not more than 20% PETN

3345 153 Phenoxyacetic acid derivative

pesticide, solid, poisonous

3345 153 Phenoxyacetic acid derivative

pesticide, solid, toxic

3346 131 Phenoxyacetic acid derivative

pesticide, liquid, flammable,

poisonous

3346 131 Phenoxyacetic acid derivative

pesticide, liquid, flammable,

toxic

3347 131 Phenoxyacetic acid derivative

pesticide, liquid, poisonous,

flammable

3347 131 Phenoxyacetic acid derivative

pesticide, liquid, toxic,

flammable

3348 153 Phenoxyacetic acid derivative

pesticide, liquid, poisonous

3348 153 Phenoxyacetic acid derivative

pesticide, liquid, toxic

3349 151 Pyrethroid pesticide, solid,

poisonous

3349 151 Pyrethroid pesticide, solid,

toxic

3350 131 Pyrethroid pesticide, liquid,

flammable, poisonous

3350 131 Pyrethroid pesticide, liquid,

flammable, toxic

3351 131 Pyrethroid pesticide, liquid,

poisonous, flammable

3351 131 Pyrethroid pesticide, liquid,

toxic, flammable

3352 151 Pyrethroid pesticide, liquid,

poisonous

3352 151 Pyrethroid pesticide, liquid, toxic

3353 126 Air bag inflators, compressed gas

3353 126 Air bag modules, compressed gas

3353 126 Seat-belt pre-tensioners,

compressed gas

3354 115 Insecticide gas, flammable, n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 92

3355 119 Insecticide gas, poisonous,

flammable, n.o.s.

3355 119 Insecticide gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone A)

3355 119 Insecticide gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone B)

3355 119 Insecticide gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone C)

3355 119 Insecticide gas, poisonous,

flammable, n.o.s. (Inhalation

Hazard Zone D)

3355 119 Insecticide gas, toxic,

flammable, n.o.s.

3355 119 Insecticide gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone A)

3355 119 Insecticide gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone B)

3355 119 Insecticide gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone C)

3355 119 Insecticide gas, toxic,

flammable, n.o.s. (Inhalation

Hazard Zone D)

3356 140 Oxygen generator, chemical

3356 140 Oxygen generator, chemical,

spent

3357 113 Nitroglycerin mixture,

desensitized, liquid, n.o.s.,

with not more than 30%

Nitroglycerin

3358 115 Refrigerating machines,

containing flammable, nontoxic, liquefied gas

3359 171 Fumigated unit

3360 133 Fibers, vegetable, dry

3360 133 Fibres, vegetable, dry

3361 156 Chlorosilanes, poisonous,

corrosive, n.o.s.

3361 156 Chlorosilanes, toxic, corrosive,

n.o.s.

3362 155 Chlorosilanes, poisonous,

corrosive, flammable, n.o.s.

3362 155 Chlorosilanes, toxic, corrosive,

flammable, n.o.s.

3363 171 Dangerous goods in apparatus

3363 171 Dangerous goods in machinery

3364 113 Picric acid, wetted with not less

than 10% water

3364 113 Trinitrophenol, wetted with not

less than 10% water

3365 113 Picryl chloride, wetted with not

less than 10% water

3365 113 Trinitrochlorobenzene, wetted

with not less than 10% water

3366 113 TNT, wetted with not less than

10% water

3366 113 Trinitrotoluene, wetted with not

less than 10% water

3367 113 Trinitrobenzene, wetted with not

less than 10% water

3368 113 Trinitrobenzoic acid, wetted

with not less than 10% water

3369 113 Sodium dinitro-o-cresolate,

wetted with not less than 10%

water

3370 113 Urea nitrate, wetted with not

less than 10% water

3371 129 2-Methylbutanal

3372 138 Organometallic compound,

solid, water-reactive,

flammable, n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 93

3373 158 Clinical specimens

3373 158 Diagnostic specimens

3374 116 Acetylene, solvent free

3375 140 Ammonium nitrate emulsion

3375 140 Ammonium nitrate gel

3375 140 Ammonium nitrate suspension

3376 113 4-Nitrophenylhydrazine, with not

less than 30% water

3377 140 Sodium perborate monohydrate

3378 140 Sodium carbonate peroxyhydrate

3379 128 Desensitized explosive, liquid,

n.o.s.

3380 133 Desensitized explosive, solid,

n.o.s.

3381 151 Poisonous by inhalation liquid,

n.o.s. (Inhalation Hazard

Zone A)

3381 151 Toxic by inhalation liquid, n.o.s.

(Inhalation Hazard Zone A)

3382 151 Poisonous by inhalation liquid,

n.o.s. (Inhalation Hazard

Zone B)

3382 151 Toxic by inhalation liquid, n.o.s.

(Inhalation Hazard Zone B)

3383 131 Poisonous by inhalation liquid,

flammable, n.o.s. (Inhalation

Hazard Zone A)

3383 131 Toxic by inhalation liquid,

flammable, n.o.s. (Inhalation

Hazard Zone A)

3384 131 Poisonous by inhalation liquid,

flammable, n.o.s. (Inhalation

Hazard Zone B)

3384 131 Toxic by inhalation liquid,

flammable, n.o.s. (Inhalation

Hazard Zone B)

3385 139 Poisonous by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone A)

3385 139 Toxic by inhalation liquid, waterreactive, n.o.s. (Inhalation

Hazard Zone A)

3386 139 Poisonous by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

3386 139 Toxic by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

3387 142 Poisonous by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3387 142 Toxic by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

3388 142 Poisonous by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3388 142 Toxic by inhalation liquid,

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3389 154 Poisonous by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3389 154 Toxic by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone A)

3390 154 Poisonous by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3390 154 Toxic by inhalation liquid,

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3391 135 Organometallic substance,

solid, pyrophoric

3392 135 Organometallic substance,

liquid, pyrophoric
ID Guide Name of Material

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ID Guide Name of Material

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Page 94

3393 135 Organometallic substance, solid,

pyrophoric, water-reactive

3394 135 Organometallic substance, liquid,

pyrophoric, water-reactive

3395 135 Organometallic substance, solid,

water-reactive

3396 138 Organometallic substance, solid,

water-reactive, flammable

3397 138 Organometallic substance, solid,

water-reactive, self-heating

3398 135 Organometallic substance, liquid,

water-reactive

3399 138 Organometallic substance, liquid,

water-reactive, flammable

3400 138 Organometallic substance, solid,

self-heating

3401 138 Alkali metal amalgam, solid

3402 138 Alkaline earth metal amalgam,

solid

3403 138 Potassium, metal alloys, solid

3404 138 Potassium sodium alloys, solid

3404 138 Sodium potassium alloys, solid

3405 141 Barium chlorate, solution

3406 141 Barium perchlorate, solution

3407 140 Chlorate and Magnesium chloride

mixture, solution

3407 140 Magnesium chloride and Chlorate

mixture, solution

3408 141 Lead perchlorate, solution

3409 152 Chloronitrobenzenes, liquid

3410 153 4-Chloro-o-toluidine

hydrochloride, solution

3411 153 beta-Naphthylamine, solution

3411 153 Naphthylamine (beta), solution

3413 157 Potassium cyanide, solution

3414 157 Sodium cyanide, solution

3415 154 Sodium fluoride, solution

3416 153 Chloroacetophenone, liquid

3417 152 Xylyl bromide, solid

3418 151 2,4-Toluylenediamine, solution

3419 157 Boron trifluoride acetic acid

complex, solid

3420 157 Boron trifluoride propionic acid

complex, solid

3421 154 Potassium hydrogen difluoride,

solution

3422 154 Potassium fluoride, solution

3423 153 Tetramethylammonium

hydroxide, solid

3424 141 Ammonium dinitro-o-cresolate,

solution

3425 156 Bromoacetic acid, solid

3426 153P Acrylamide, solution

3427 153 Chlorobenzyl chlorides, solid

3428 156 3-Chloro-4-methylphenyl

isocyanate, solid

3429 153 Chlorotoluidines, liquid

3430 153 Xylenols, liquid

3431 152 Nitrobenzotrifluorides, solid

3432 171 Polychlorinated biphenyls, solid

3433 135 Lithium alkyls, solid

3434 153 Nitrocresols, liquid

3435 153 Hydroquinone, solution

3436 151 Hexafluoroacetone hydrate, solid

3437 152 Chlorocresols, solid

3438 153 alpha-Methylbenzyl alcohol,

solid

3439 151 Nitriles, poisonous, solid, n.o.s.

3439 151 Nitriles, toxic, solid, n.o.s.

3440 151 Selenium compound, liquid,

n.o.s.
ID Guide Name of Material

No. No.

ID Guide Name of Material

No. No.

Page 95

3441 153 Chlorodinitrobenzenes, solid

3442 153 Dichloroanilines, solid

3443 152 Dinitrobenzenes, solid

3444 151 Nicotine hydrochloride, solid

3445 151 Nicotine sulfate, solid

3445 151 Nicotine sulphate, solid

3446 152 Nitrotoluenes, solid

3447 152 Nitroxylenes, solid

3448 159 Tear gas substance, solid, n.o.s.

3449 159 Bromobenzyl cyanides, solid

3450 151 Diphenylchloroarsine, solid

3451 153 Toluidines, solid

3452 153 Xylidines, solid

3453 154 Phosphoric acid, solid

3454 152 Dinitrotoluenes, solid

3455 153 Cresols, solid

3456 157 Nitrosylsulfuric acid, solid

3456 157 Nitrosylsulphuric acid, solid

3457 152 Chloronitrotoluenes, solid

3458 152 Nitroanisoles, solid

3459 152 Nitrobromobenzenes, solid

3460 153 N-Ethylbenzyltoluidines, solid

3461 135 Aluminum alkyl halides, solid

3462 153 Toxins, extracted from living

sources, solid, n.o.s.

3464 151 Organophosphorus compound,

poisonous, solid, n.o.s.

3464 151 Organophosphorus compound,

toxic, solid, n.o.s.

3465 151 Organoarsenic compound,

solid, n.o.s.

3466 151 Metal carbonyls, solid, n.o.s.

3467 151 Organometallic compound,

poisonous, solid, n.o.s.

3467 151 Organometallic compound, toxic,

solid, n.o.s.

3468 115 Hydrogen, in a metal hydride

storage system

8000 171 Consumer commodity

8013 171 Gas generator assemblies

8038 171 Heat producing article

9035 123 Gas identification set

9163 171 Zirconium sulfate

9163 171 Zirconium sulphate

9191 143 Chlorine dioxide, hydrate,

frozen

9192 167 Fluorine, refrigerated liquid

(cryogenic liquid)

9195 135 Metal alkyl, solution, n.o.s.

9202 168 Carbon monoxide, refrigerated

liquid (cryogenic liquid)

9206 137 Methyl phosphonic dichloride

9260 169 Aluminum, molten

9263 156 Chloropivaloyl chloride

9264 151 3,5-Dichloro-2,4,6-

trifluoropyridine

9269 132 Trimethoxysilane

9275 158 Regulated medical waste

9279 115 Hydrogen, absorbed in metal

hydride
Note: If an entry is highlighted in either the yellow-bordered or blue-bordered pages AND THERE

IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances

(green-bordered pages) and look up the ID number and name of material to obtain initial

isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED,

go directly to the appropriate guide (orange-bordered pages) and use the evacuation

information shown under PUBLIC SAFETY.
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 97

AC 117 1051

Accumulators, pressurized, 126 1956

pneumatic or hydraulic

Acetal 127 1088

Acetaldehyde 129 1089

Acetaldehyde ammonia 171 1841

Acetaldehyde oxime 129 2332

Acetic acid, glacial 132 2789

Acetic acid, solution, more than 153 2790

10% but not more than 80%

acid

Acetic acid, solution, more than 132 2789

80% acid

Acetic anhydride 137 1715

Acetone 127 1090

Acetone cyanohydrin, stabilized 155 1541

Acetone oils 127 1091

Acetonitrile 127 1648

Acetyl bromide 156 1716

Acetyl chloride 155 1717

Acetylene 116 1001

Acetylene, dissolved 116 1001

Acetylene, solvent free 116 3374

Acetylene, Ethylene and 115 3138

Propylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

Acetylene tetrabromide 159 2504

Acetyl iodide 156 1898

Acetyl methyl carbinol 127 2621

Acid, sludge 153 1906

Acid butyl phosphate 153 1718

Acridine 153 2713

Acrolein, inhibited 131P 1092

Acrolein, stabilized 131P 1092

Acrolein dimer, stabilized 129P 2607

Acrylamide 153P 2074

Acrylamide, solid 153P 2074

Acrylamide, solution 153P 3426

Acrylic acid, inhibited 132P 2218

Acrylic acid, stabilized 132P 2218

Acrylonitrile, inhibited 131P 1093

Acrylonitrile, stabilized 131P 1093

Adamsite 154 1698

Adhesives (flammable) 128 1133

Adiponitrile 153 2205

Aerosol dispensers 126 1950

Aerosols 126 1950

Air, compressed 122 1002

Air, refrigerated liquid 122 1003

(cryogenic liquid)

Air, refrigerated liquid 122 1003

(cryogenic liquid), nonpressurized

Air bag inflators 171 3268

Air bag inflators, compressed gas 126 3353

Air bag inflators, pyrotechnic 171 3268

Air bag modules 171 3268

Air bag modules, compressed gas 126 3353

Air bag modules, pyrotechnic 171 3268

Aircraft hydraulic power unit fuel 131 3165

tank

Alcoholates solution, n.o.s., in 132 3274

alcohol

Alcoholic beverages 127 3065

Alcohols, flammable, poisonous, 131 1986

n.o.s.

Alcohols, flammable, toxic, 131 1986

n.o.s.

Alcohols, n.o.s. 127 1987

Alcohols, poisonous, n.o.s. 131 1986
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 98

Alcohols, toxic, n.o.s. 131 1986

Aldehydes, flammable, 131 1988

poisonous, n.o.s.

Aldehydes, flammable, toxic, 131 1988

n.o.s.

Aldehydes, n.o.s. 129 1989

Aldehydes, poisonous, n.o.s. 131 1988

Aldehydes, toxic, n.o.s. 131 1988

Aldol 153 2839

Aldrin, liquid 131 2762

Aldrin, solid 151 2761

Alkali metal alcoholates, self- 136 3206

heating, corrosive, n.o.s.

Alkali metal alloy, liquid, n.o.s. 138 1421

Alkali metal amalgam 138 1389

Alkali metal amalgam, liquid 138 1389

Alkali metal amalgam, solid 138 1389

Alkali metal amalgam, solid 138 3401

Alkali metal amides 139 1390

Alkali metal dispersion 138 1391

Alkaline earth metal 135 3205

alcoholates, n.o.s.

Alkaline earth metal alloy, n.o.s. 138 1393

Alkaline earth metal amalgam 138 1392

Alkaline earth metal amalgam, 138 1392

liquid

Alkaline earth metal amalgam, 138 3402

solid

Alkaline earth metal dispersion 138 1391

Alkaloids, liquid, n.o.s. 151 3140

(poisonous)

Alkaloids, solid, n.o.s. 151 1544

(poisonous)

Alkaloid salts, liquid, n.o.s. 151 3140

(poisonous)

Alkaloid salts, solid, n.o.s. 151 1544

(poisonous)

Alkylamines, n.o.s. 132 2733

Alkylamines, n.o.s. 132 2734

Alkylamines, n.o.s. 153 2735

Alkyl phenols, liquid, n.o.s. 153 3145

(including C2-C12

homologues)

Alkyl phenols, solid, n.o.s. 153 2430

(including C2-C12

homologues)

Alkyl sulfonic acids, liquid, with 153 2584

more than 5% free Sulfuric

acid

Alkyl sulfonic acids, liquid, with 153 2586

not more than 5% free Sulfuric

acid

Alkyl sulfonic acids, solid, with 153 2583

more than 5% free Sulfuric

acid

Alkyl sulfonic acids, solid, with 153 2585

not more than 5% free Sulfuric

acid

Alkylsulfuric acids 156 2571

Alkyl sulphonic acids, liquid, 153 2584

with more than 5% free

Sulphuric acid

Alkyl sulphonic acids, liquid, 153 2586

with not more than 5% free

Sulphuric acid

Alkyl sulphonic acids, solid, with 153 2583

more than 5% free Sulphuric

acid

Alkyl sulphonic acids, solid, with 153 2585

not more than 5% free

Sulphuric acid

Alkylsulphuric acids 156 2571

Allyl acetate 131 2333
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 99

Allyl alcohol 131 1098

Allylamine 131 2334

Allyl bromide 131 1099

Allyl chloride 131 1100

Allyl chlorocarbonate 155 1722

Allyl chloroformate 155 1722

Allyl ethyl ether 131 2335

Allyl formate 131 2336

Allyl glycidyl ether 129 2219

Allyl iodide 132 1723

Allyl isothiocyanate, inhibited 155 1545

Allyl isothiocyanate, stabilized 155 1545

Allyltrichlorosilane, stabilized 155 1724

Aluminum, molten 169 9260

Aluminum alkyl halides 135 3052

Aluminum alkyl halides, liquid 135 3052

Aluminum alkyl halides, solid 135 3052

Aluminum alkyl halides, solid 135 3461

Aluminum alkyl hydrides 138 3076

Aluminum alkyls 135 3051

Aluminum borohydride 135 2870

Aluminum borohydride in 135 2870

devices

Aluminum bromide, anhydrous 137 1725

Aluminum bromide, solution 154 2580

Aluminum carbide 138 1394

Aluminum chloride, anhydrous 137 1726

Aluminum chloride, solution 154 2581

Aluminum dross 138 3170

Aluminum ferrosilicon powder 139 1395

Aluminum hydride 138 2463

Aluminum nitrate 140 1438

Aluminum phosphide 139 1397

Aluminum phosphide pesticide 157 3048

Aluminum powder, coated 170 1309

Aluminum powder, pyrophoric 135 1383

Aluminum powder, uncoated 138 1396

Aluminum processing 138 3170

by-products

Aluminum remelting by-products 138 3170

Aluminum resinate 133 2715

Aluminum silicon powder, 138 1398

uncoated

Aluminum smelting by-products 138 3170

Amines, flammable, corrosive, 132 2733

n.o.s.

Amines, liquid, corrosive, 132 2734

flammable, n.o.s.

Amines, liquid, corrosive, n.o.s. 153 2735

Amines, solid, corrosive, n.o.s. 154 3259

2-Amino-4-chlorophenol 151 2673

2-Amino-5-diethylaminopentane 153 2946

2-Amino-4,6-dinitrophenol, 113 3317

wetted with not less than 20%

water

2-(2-Aminoethoxy)ethanol 154 3055

N-Aminoethylpiperazine 153 2815

Aminophenols 152 2512

Aminopyridines 153 2671

Ammonia, anhydrous 125 1005

Ammonia, anhydrous, liquefied 125 1005

Ammonia, solution, with more 154 2672

than 10% but not more than

35% Ammonia

Ammonia, solution, with more 125 2073

than 35% but not more than

50% Ammonia

Ammonia solution, with more 125 1005

than 50% Ammonia
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 100

Ammonia solution, with more 125 3318

than 50% Ammonia

Ammonium arsenate 151 1546

Ammonium bifluoride, solid 154 1727

Ammonium bifluoride, solution 154 2817

Ammonium dichromate 141 1439

Ammonium dinitro-o-cresolate 141 1843

Ammonium dinitro-o-cresolate, 141 1843

solid

Ammonium dinitro-o-cresolate, 141 3424

solution

Ammonium fluoride 154 2505

Ammonium fluorosilicate 151 2854

Ammonium hydrogendifluoride, 154 1727

solid

Ammonium hydrogendifluoride, 154 2817

solution

Ammonium hydrogen fluoride, 154 1727

solid

Ammonium hydrogen fluoride, 154 2817

solution

Ammonium hydrogen sulfate 154 2506

Ammonium hydrogen sulphate 154 2506

Ammonium hydroxide 154 2672

Ammonium hydroxide, with more 154 2672

than 10% but not more than

35% Ammonia

Ammonium metavanadate 154 2859

Ammonium nitrate, liquid (hot 140 2426

concentrated solution)

Ammonium nitrate, with not more 140 1942

than 0.2% combustible

substances

Ammonium nitrate emulsion 140 3375

Ammonium nitrate fertilizer, 140 2072

n.o.s.

Ammonium nitrate fertilizer, with 140 2071

not more than 0.4%

combustible material

Ammonium nitrate fertilizers 140 2067

Ammonium nitrate fertilizers 140 2071

Ammonium nitrate fertilizers 140 2072

Ammonium nitrate fertilizers, 140 2069

with Ammonium sulfate

Ammonium nitrate fertilizers, 140 2069

with Ammonium sulphate

Ammonium nitrate fertilizers, 140 2068

with Calcium carbonate

Ammonium nitrate fertilizers, 143 2070

with Phosphate or Potash

Ammonium nitrate-fuel oil 112 ——

mixtures

Ammonium nitrate gel 140 3375

Ammonium nitrate mixed 140 2069

fertilizers

Ammonium nitrate suspension 140 3375

Ammonium perchlorate 143 1442

Ammonium persulfate 140 1444

Ammonium persulphate 140 1444

Ammonium picrate, wetted with 113 1310

not less than 10% water

Ammonium polysulfide, solution 154 2818

Ammonium polysulphide, 154 2818

solution

Ammonium polyvanadate 151 2861

Ammonium silicofluoride 151 2854

Ammonium sulfide, solution 132 2683

Ammonium sulphide, solution 132 2683

Ammunition, poisonous, 151 2016

non-explosive

Ammunition, tear-producing, 159 2017

non-explosive
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 101

Ammunition, toxic, 151 2016

non-explosive

Amyl acetates 129 1104

Amyl acid phosphate 153 2819

Amyl alcohols 129 1105

Amylamines 132 1106

Amyl butyrates 130 2620

Amyl chloride 129 1107

n-Amylene 128 1108

Amyl formates 129 1109

Amyl mercaptan 130 1111

n-Amyl methyl ketone 127 1110

Amyl methyl ketone 127 1110

Amyl nitrate 140 1112

Amyl nitrite 129 1113

Amyltrichlorosilane 155 1728

Anhydrous ammonia 125 1005

Anhydrous ammonia, liquefied 125 1005

Aniline 153 1547

Aniline hydrochloride 153 1548

Anisidines 153 2431

Anisidines, liquid 153 2431

Anisidines, solid 153 2431

Anisole 128 2222

Anisoyl chloride 156 1729

Antimony compound, inorganic, 157 3141

liquid, n.o.s.

Antimony compound, inorganic, 157 1549

n.o.s.

Antimony compound, inorganic, 157 1549

solid, n.o.s.

Antimony lactate 151 1550

Antimony pentachloride, liquid 157 1730

Antimony pentachloride, 157 1731

solution

Antimony pentafluoride 157 1732

Antimony potassium tartrate 151 1551

Antimony powder 170 2871

Antimony tribromide, solid 157 1549

Antimony tribromide, solution 157 1549

Antimony trichloride 157 1733

Antimony trichloride, liquid 157 1733

Antimony trichloride, solid 157 1733

Antimony trichloride, solution 157 1733

Antimony trifluoride, solid 157 1549

Antimony trifluoride, solution 157 1549

Aqua regia 157 1798

Argon 121 1006

Argon, compressed 121 1006

Argon, refrigerated liquid 120 1951

(cryogenic liquid)

Arsenic 152 1558

Arsenic acid, liquid 154 1553

Arsenic acid, solid 154 1554

Arsenical dust 152 1562

Arsenical pesticide, liquid, 131 2760

flammable, poisonous

Arsenical pesticide, liquid, 131 2760

flammable, toxic

Arsenical pesticide, liquid, 151 2994

poisonous

Arsenical pesticide, liquid, 131 2993

poisonous, flammable

Arsenical pesticide, liquid, toxic 151 2994

Arsenical pesticide, liquid, toxic, 131 2993

flammable

Arsenical pesticide, solid, 151 2759

poisonous
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 102

Arsenical pesticide, solid, toxic 151 2759

Arsenic bromide 151 1555

Arsenic chloride 157 1560

Arsenic compound, liquid, n.o.s. 152 1556

Arsenic compound, liquid, 152 1556

n.o.s., inorganic

Arsenic compound, solid, n.o.s. 152 1557

Arsenic compound, solid, n.o.s., 152 1557

inorganic

Arsenic pentoxide 151 1559

Arsenic sulfide 152 1557

Arsenic sulphide 152 1557

Arsenic trichloride 157 1560

Arsenic trioxide 151 1561

Arsenic trisulfide 152 1557

Arsenic trisulphide 152 1557

Arsine 119 2188

Articles containing 171 2315

Polychlorinated biphenyls

(PCB)

Articles, pressurized, hydraulic 126 3164

(containing non-flammable

gas)

Articles, pressurized, pneumatic 126 3164

(containing non-flammable

gas)

Aryl sulfonic acids, liquid, with 153 2584

more than 5% free Sulfuric

acid

Aryl sulfonic acids, liquid, with 153 2586

not more than 5% free Sulfuric

acid

Aryl sulfonic acids, solid, with 153 2583

more than 5% free Sulfuric

acid

Aryl sulfonic acids, solid, with 153 2585

not more than 5% free Sulfuric

acid

Aryl sulphonic acids, liquid, with 153 2584

more than 5% free Sulphuric

acid

Aryl sulphonic acids, liquid, with 153 2586

not more than 5% free

Sulphuric acid

Aryl sulphonic acids, solid, with 153 2583

more than 5% free Sulphuric

acid

Aryl sulphonic acids, solid, with 153 2585

not more than 5% free

Sulphuric acid

Asbestos 171 2212

Asbestos, blue 171 2212

Asbestos, brown 171 2212

Asbestos, white 171 2590

Asphalt 130 1999

Aviation regulated liquid, n.o.s. 171 3334

Aviation regulated solid, n.o.s. 171 3335

1-Aziridinyl phosphine oxide 152 2501

(Tris)

Azodicarbonamide 149 3242

Barium 138 1400

Barium alloys, pyrophoric 135 1854

Barium azide, wetted with not 113 1571

less than 50% water

Barium bromate 141 2719

Barium chlorate 141 1445

Barium chlorate, solid 141 1445

Barium chlorate, solution 141 3405

Barium compound, n.o.s. 154 1564

Barium cyanide 157 1565

Barium hypochlorite, with more 141 2741

than 22% available Chlorine

Barium nitrate 141 1446

Barium oxide 157 1884
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 103

Barium perchlorate 141 1447

Barium perchlorate, solid 141 1447

Barium perchlorate, solution 141 3406

Barium permanganate 141 1448

Barium peroxide 141 1449

Batteries, containing Sodium 138 3292

Batteries, dry, containing 154 3028

Potassium hydroxide solid

Batteries, wet, filled with acid 154 2794

Batteries, wet, filled with alkali 154 2795

Batteries, wet, non-spillable 154 2800

Battery fluid, acid 157 2796

Battery fluid, alkali 154 2797

Battery fluid, alkali, with battery 154 2797

Battery fluid, alkali, with 154 2797

electronic equipment or

actuating device

Battery-powered equipment (wet 154 3171

battery)

Battery-powered vehicle (wet 154 3171

battery)

Benzaldehyde 129 1990

Benzene 130 1114

Benzene phosphorus dichloride 137 2798

Benzene phosphorus 137 2799

thiodichloride

Benzenesulfonyl chloride 156 2225

Benzenesulphonyl chloride 156 2225

Benzidine 153 1885

Benzoic derivative pesticide, 131 2770

liquid, flammable, poisonous

Benzoic derivative pesticide, 131 2770

liquid, flammable, toxic

Benzoic derivative pesticide, 151 3004

liquid, poisonous

Benzoic derivative pesticide, 131 3003

liquid, poisonous, flammable

Benzoic derivative pesticide, 151 3004

liquid, toxic

Benzoic derivative pesticide, 131 3003

liquid, toxic, flammable

Benzoic derivative pesticide, 151 2769

solid, poisonous

Benzoic derivative pesticide, 151 2769

solid, toxic

Benzonitrile 152 2224

Benzoquinone 153 2587

Benzotrichloride 156 2226

Benzotrifluoride 127 2338

Benzoyl chloride 137 1736

Benzyl bromide 156 1737

Benzyl chloride 156 1738

Benzyl chloroformate 137 1739

Benzyldimethylamine 132 2619

Benzylidene chloride 156 1886

Benzyl iodide 156 2653

Beryllium compound, n.o.s. 154 1566

Beryllium nitrate 141 2464

Beryllium powder 134 1567

Bhusa, wet, damp or 133 1327

contaminated with oil

Bicyclo[2.2.1]hepta-2,5-diene 128P 2251

Bicyclo[2.2.1]hepta-2,5-diene, 128P 2251

inhibited

Bicyclo[2.2.1]hepta-2,5-diene, 128P 2251

stabilized

Biological agents 158 ——

(Bio)Medical waste, n.o.s. 158 3291

Bipyridilium pesticide, liquid, 131 2782

flammable, poisonous
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 104

Bipyridilium pesticide, liquid, 131 2782

flammable, toxic

Bipyridilium pesticide, liquid, 151 3016

poisonous

Bipyridilium pesticide, liquid, 131 3015

poisonous, flammable

Bipyridilium pesticide, liquid, 151 3016

toxic

Bipyridilium pesticide, liquid, 131 3015

toxic, flammable

Bipyridilium pesticide, solid, 151 2781

poisonous

Bipyridilium pesticide, solid, 151 2781

toxic

Bisulfates, aqueous solution 154 2837

Bisulfites, aqueous solution, 154 2693

n.o.s.

Bisulfites, inorganic, aqueous 154 2693

solution, n.o.s.

Bisulphates, aqueous solution 154 2837

Bisulphites, aqueous solution, 154 2693

n.o.s.

Bisulphites, inorganic, aqueous 154 2693

solution, n.o.s.

Blasting agent, n.o.s. 112 ——

Bleaching powder 140 2208

Blue asbestos 171 2212

Bombs, smoke, non-explosive, 153 2028

with corrosive liquid, without

initiating device

Borate and Chlorate mixtures 140 1458

Borneol 133 1312

Boron tribromide 157 2692

Boron trichloride 125 1741

Boron trifluoride 125 1008

Boron trifluoride, compressed 125 1008

Boron trifluoride, dihydrate 157 2851

Boron trifluoride acetic acid 157 1742

complex

Boron trifluoride acetic acid 157 1742

complex, liquid

Boron trifluoride acetic acid 157 3419

complex, solid

Boron trifluoride diethyl etherate 132 2604

Boron trifluoride dimethyl 139 2965

etherate

Boron trifluoride propionic acid 157 1743

complex

Boron trifluoride propionic acid 157 1743

complex, liquid

Boron trifluoride propionic acid 157 3420

complex, solid

Bromates, inorganic, aqueous 140 3213

solution, n.o.s.

Bromates, inorganic, n.o.s. 141 1450

Bromine 154 1744

Bromine, solution 154 1744

Bromine chloride 124 2901

Bromine pentafluoride 144 1745

Bromine trifluoride 144 1746

Bromoacetic acid 156 1938

Bromoacetic acid, solid 156 3425

Bromoacetic acid, solution 156 1938

Bromoacetone 131 1569

Bromoacetyl bromide 156 2513

Bromobenzene 130 2514

Bromobenzyl cyanides 159 1694

Bromobenzyl cyanides, liquid 159 1694

Bromobenzyl cyanides, solid 159 1694

Bromobenzyl cyanides, solid 159 3449

1-Bromobutane 130 1126
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 105

2-Bromobutane 130 2339

Bromochlorodifluoromethane 126 1974

Bromochloromethane 160 1887

1-Bromo-3-chloropropane 159 2688

2-Bromoethyl ethyl ether 130 2340

Bromoform 159 2515

1-Bromo-3-methylbutane 130 2341

Bromomethylpropanes 130 2342

2-Bromo-2-nitropropane-1,3-diol 133 3241

2-Bromopentane 130 2343

2-Bromopropane 129 2344

Bromopropanes 129 2344

3-Bromopropyne 130 2345

Bromotrifluoroethylene 116 2419

Bromotrifluoromethane 126 1009

Brown asbestos 171 2212

Brucine 152 1570

Butadienes, inhibited 116P 1010

Butadienes, stabilized 116P 1010

Butadienes and hydrocarbon 116P 1010

mixture, stabilized

Butane 115 1011

Butane 115 1075

Butanedione 127 2346

Butane mixture 115 1011

Butane mixture 115 1075

Butanols 129 1120

Butoxyl 127 2708

Butyl acetates 129 1123

Butyl acid phosphate 153 1718

Butyl acrylate 130P 2348

Butyl acrylates, inhibited 130P 2348

Butyl acrylates, stabilized 130P 2348

n-Butylamine 132 1125

N-Butylaniline 153 2738

Butylbenzenes 128 2709

n-Butyl bromide 130 1126

Butyl chloride 130 1127

n-Butyl chloroformate 155 2743

sec-Butyl chloroformate 155 2742

tert-Butylcyclohexyl 156 2747

chloroformate

Butylene 115 1012

Butylene 115 1075

1,2-Butylene oxide, stabilized 127P 3022

Butyl ethers 128 1149

n-Butyl formate 129 1128

tert-Butyl hypochlorite 135 3255

N,n-Butylimidazole 152 2690

n-Butyl isocyanate 155 2485

tert-Butyl isocyanate 155 2484

Butyl mercaptan 130 2347

n-Butyl methacrylate 130P 2227

n-Butyl methacrylate, inhibited 130P 2227

n-Butyl methacrylate, stabilized 130P 2227

Butyl methyl ether 127 2350

Butyl nitrites 129 2351

Butyl propionates 130 1914

Butyltoluenes 152 2667

Butyltrichlorosilane 155 1747

5-tert-Butyl-2,4,6-trinitro- 149 2956

m-xylene

Butyl vinyl ether, inhibited 127P 2352

Butyl vinyl ether, stabilized 127P 2352

1,4-Butynediol 153 2716

Butyraldehyde 129 1129
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 106

Butyraldoxime 129 2840

Butyric acid 153 2820

Butyric anhydride 156 2739

Butyronitrile 131 2411

Butyryl chloride 132 2353

Buzz 153 2810

BZ 153 2810

C A 159 1694

Cacodylic acid 151 1572

Cadmium compound 154 2570

Caesium 138 1407

Caesium hydroxide 157 2682

Caesium hydroxide, solution 154 2681

Caesium nitrate 140 1451

Calcium 138 1401

Calcium, metal and alloys, 135 1855

pyrophoric

Calcium, pyrophoric 135 1855

Calcium alloys, pyrophoric 135 1855

Calcium arsenate 151 1573

Calcium arsenate and Calcium 151 1574

arsenite mixture, solid

Calcium arsenite, solid 151 1574

Calcium arsenite and Calcium 151 1574

arsenate mixture, solid

Calcium carbide 138 1402

Calcium chlorate 140 1452

Calcium chlorate, aqueous 140 2429

solution

Calcium chlorate, solution 140 2429

Calcium chlorite 140 1453

Calcium cyanamide, with more 138 1403

than 0.1% Calcium carbide

Calcium cyanide 157 1575

Calcium dithionite 135 1923

Calcium hydride 138 1404

Calcium hydrosulfite 135 1923

Calcium hydrosulphite 135 1923

Calcium hypochlorite, dry 140 1748

Calcium hypochlorite, hydrated, 140 2880

with not less than 5.5% but not

more than 16% water

Calcium hypochlorite, hydrated 140 2880

mixture, with not less than

5.5% but not more than 16%

water

Calcium hypochlorite mixture, 140 2208

dry, with more than 10% but

not more than 39% available

Chlorine

Calcium hypochlorite mixture, 140 1748

dry, with more than 39%

available Chlorine (8.8%

available Oxygen)

Calcium manganese silicon 138 2844

Calcium nitrate 140 1454

Calcium oxide 157 1910

Calcium perchlorate 140 1455

Calcium permanganate 140 1456

Calcium peroxide 140 1457

Calcium phosphide 139 1360

Calcium resinate 133 1313

Calcium resinate, fused 133 1314

Calcium silicide 138 1405

Calcium silicon 138 1406

Camphor 133 2717

Camphor, synthetic 133 2717

Camphor oil 128 1130

Caproic acid 153 2829
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 107

Carbamate pesticide, liquid, 131 2758

flammable, poisonous

Carbamate pesticide, liquid, 131 2758

flammable, toxic

Carbamate pesticide, liquid, 151 2992

poisonous

Carbamate pesticide, liquid, 131 2991

poisonous, flammable

Carbamate pesticide, liquid, 151 2992

toxic

Carbamate pesticide, liquid, 131 2991

toxic, flammable

Carbamate pesticide, solid, 151 2757

poisonous

Carbamate pesticide, solid, 151 2757

toxic

Carbon, activated 133 1362

Carbon, animal or vegetable 133 1361

origin

Carbon bisulfide 131 1131

Carbon bisulphide 131 1131

Carbon dioxide 120 1013

Carbon dioxide, compressed 120 1013

Carbon dioxide, refrigerated 120 2187

liquid

Carbon dioxide, solid 120 1845

Carbon dioxide and Ethylene 115 1041

oxide mixture, with more than

9% but not more than 87%

Ethylene oxide

Carbon dioxide and Ethylene 119P 3300

oxide mixture, with more than

87% Ethylene oxide

Carbon dioxide and Ethylene 115 1041

oxide mixtures, with more

than 6% Ethylene oxide

Carbon dioxide and Ethylene 126 1952

oxide mixtures, with not more

than 6% Ethylene oxide

Carbon dioxide and Ethylene 126 1952

oxide mixtures, with not more

than 9% Ethylene oxide

Carbon dioxide and Nitrous 126 1015

oxide mixture

Carbon dioxide and Oxygen 122 1014

mixture

Carbon dioxide and Oxygen 122 1014

mixture, compressed

Carbon disulfide 131 1131

Carbon disulphide 131 1131

Carbon monoxide 119 1016

Carbon monoxide, compressed 119 1016

Carbon monoxide, refrigerated 168 9202

liquid (cryogenic liquid)

Carbon monoxide and Hydrogen 119 2600

 mixture

Carbon monoxide and Hydrogen 119 2600

 mixture, compressed

Carbon tetrabromide 151 2516

Carbon tetrachloride 151 1846

Carbonyl fluoride 125 2417

Carbonyl fluoride, compressed 125 2417

Carbonyl sulfide 119 2204

Carbonyl sulphide 119 2204

Castor beans, meal, pomace or 171 2969

flake

Caustic alkali liquid, n.o.s. 154 1719

Caustic potash, dry, solid 154 1813

Caustic potash, liquid 154 1814

Caustic potash, solution 154 1814

Caustic soda, bead 154 1823

Caustic soda, flake 154 1823
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 108

Caustic soda, granular 154 1823

Caustic soda, solid 154 1823

Caustic soda, solution 154 1824

Cells, containing Sodium 138 3292

Celluloid, in blocks, rods, rolls, 133 2000

sheets, tubes, etc., except

scrap

Celluloid, scrap 135 2002

Cerium, slabs, ingots or rods 170 1333

Cerium, turnings or gritty powder 138 3078

Cesium 138 1407

Cesium hydroxide 157 2682

Cesium hydroxide, solution 154 2681

Cesium nitrate 140 1451

CG 125 1076

Charcoal 133 1361

Chemical kit 154 1760

Chemical kit 171 3316

Chemical sample, poisonous 151 3315

Chemical sample, poisonous 151 3315

liquid

Chemical sample, poisonous 151 3315

solid

Chemical sample, toxic 151 3315

Chemical sample, toxic liquid 151 3315

Chemical sample, toxic solid 151 3315

Chloral, anhydrous, inhibited 153 2075

Chloral, anhydrous, stabilized 153 2075

Chlorate and Borate mixtures 140 1458

Chlorate and Magnesium 140 1459

chloride mixture

Chlorate and Magnesium 140 1459

chloride mixture, solid

Chlorate and Magnesium 140 3407

chloride mixture, solution

Chlorates, inorganic, aqueous 140 3210

solution, n.o.s.

Chlorates, inorganic, n.o.s. 140 1461

Chloric acid, aqueous solution, 140 2626

with not more than 10%

Chloric acid

Chlorine 124 1017

Chlorine dioxide, hydrate, frozen 143 9191

Chlorine pentafluoride 124 2548

Chlorine trifluoride 124 1749

Chlorite solution 154 1908

Chlorite solution, with more than 154 1908

5% available Chlorine

Chlorites, inorganic, n.o.s. 143 1462

Chloroacetaldehyde 153 2232

Chloroacetic acid, liquid 153 1750

Chloroacetic acid, molten 153 3250

Chloroacetic acid, solid 153 1751

Chloroacetic acid, solution 153 1750

Chloroacetone, stabilized 131 1695

Chloroacetonitrile 131 2668

Chloroacetophenone 153 1697

Chloroacetophenone, liquid 153 1697

Chloroacetophenone, liquid 153 3416

Chloroacetophenone, solid 153 1697

Chloroacetyl chloride 156 1752

Chloroanilines, liquid 152 2019

Chloroanilines, solid 152 2018

Chloroanisidines 152 2233

Chlorobenzene 130 1134

Chlorobenzotrifluorides 130 2234

Chlorobenzyl chlorides 153 2235

Chlorobenzyl chlorides, liquid 153 2235

Chlorobenzyl chlorides, solid 153 3427
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 109

1-Chloro-3-bromopropane 159 2688

Chlorobutanes 130 1127

Chlorocresols 152 2669

Chlorocresols, liquid 152 2669

Chlorocresols, solid 152 2669

Chlorocresols, solid 152 3437

Chlorocresols, solution 152 2669

Chlorodifluorobromomethane 126 1974

1-Chloro-1,1-difluoroethane 115 2517

Chlorodifluoroethanes 115 2517

Chlorodifluoromethane 126 1018

Chlorodifluoromethane and 126 1973

Chloropentafluoroethane mixture

Chlorodinitrobenzenes 153 1577

Chlorodinitrobenzenes, liquid 153 1577

Chlorodinitrobenzenes, solid 153 1577

Chlorodinitrobenzenes, solid 153 3441

1-Chloro-2,3-epoxypropane 131P 2023

2-Chloroethanal 153 2232

Chloroform 151 1888

Chloroformates, n.o.s. 155 2742

Chloroformates, poisonous, 155 2742

corrosive, flammable, n.o.s.

Chloroformates, poisonous, 154 3277

corrosive, n.o.s.

Chloroformates, toxic, 155 2742

corrosive, flammable, n.o.s.

Chloroformates, toxic, 154 3277

corrosive, n.o.s.

Chloromethyl chloroformate 157 2745

Chloromethyl ethyl ether 131 2354

3-Chloro-4-methylphenyl 156 2236

isocyanate

3-Chloro-4-methylphenyl 156 2236

isocyanate, liquid

3-Chloro-4-methylphenyl 156 3428

isocyanate, solid

Chloronitroanilines 153 2237

Chloronitrobenzenes 152 1578

Chloronitrobenzenes, liquid 152 1578

Chloronitrobenzenes, liquid 152 3409

Chloronitrobenzenes, solid 152 1578

Chloronitrotoluenes 152 2433

Chloronitrotoluenes, liquid 152 2433

Chloronitrotoluenes, solid 152 2433

Chloronitrotoluenes, solid 152 3457

Chloropentafluoroethane 126 1020

Chloropentafluoroethane and 126 1973

Chlorodifluoromethane

mixture

Chlorophenates, liquid 154 2904

Chlorophenates, solid 154 2905

Chlorophenolates, liquid 154 2904

Chlorophenolates, solid 154 2905

Chlorophenols, liquid 153 2021

Chlorophenols, solid 153 2020

Chlorophenyltrichlorosilane 156 1753

Chloropicrin 154 1580

Chloropicrin and Methyl bromide 123 1581

mixture

Chloropicrin and Methyl chloride 119 1582

mixture

Chloropicrin mixture, n.o.s. 154 1583

Chloropivaloyl chloride 156 9263

Chloroplatinic acid, solid 154 2507

Chloroprene, inhibited 131P 1991

Chloroprene, stabilized 131P 1991

1-Chloropropane 129 1278

2-Chloropropane 129 2356
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 110

3-Chloropropanol-1 153 2849

2-Chloropropene 130P 2456

2-Chloropropionic acid 153 2511

2-Chloropropionic acid, solid 153 2511

2-Chloropropionic acid, solution 153 2511

2-Chloropyridine 153 2822

Chlorosilanes, corrosive, 155 2986

flammable, n.o.s.

Chlorosilanes, corrosive, n.o.s. 156 2987

Chlorosilanes, flammable, 155 2985

corrosive, n.o.s.

Chlorosilanes, n.o.s. 155 2985

Chlorosilanes, n.o.s. 155 2986

Chlorosilanes, n.o.s. 156 2987

Chlorosilanes, n.o.s. 139 2988

Chlorosilanes, poisonous, 155 3362

corrosive, flammable, n.o.s.

Chlorosilanes, poisonous, 156 3361

corrosive, n.o.s.

Chlorosilanes, toxic, corrosive 155 3362

flammable, n.o.s.

Chlorosilanes, toxic, corrosive, 156 3361

n.o.s.

Chlorosilanes, water-reactive, 139 2988

flammable, corrosive, n.o.s.

Chlorosulfonic acid 137 1754

Chlorosulfonic acid and Sulfur 137 1754

trioxide mixture

Chlorosulphonic acid 137 1754

Chlorosulphonic acid and 137 1754

Sulphur trioxide mixture

1-Chloro-1,2,2,2- 126 1021

tetrafluoroethane

Chlorotetrafluoroethane 126 1021

Chlorotetrafluoroethane and 126 3297

Ethylene oxide mixture, with

not more than 8.8% Ethylene

oxide

Chlorotoluenes 129 2238

4-Chloro-o-toluidine 153 1579

hydrochloride

4-Chloro-o-toluidine 153 1579

hydrochloride, solid

4-Chloro-o-toluidine 153 3410

hydrochloride, solution

Chlorotoluidines 153 2239

Chlorotoluidines, liquid 153 2239

Chlorotoluidines, liquid 153 3429

Chlorotoluidines, solid 153 2239

1-Chloro-2,2,2-trifluoroethane 126 1983

Chlorotrifluoroethane 126 1983

Chlorotrifluoromethane 126 1022

Chlorotrifluoromethane and 126 2599

Trifluoromethane azeotropic

mixture with approximately

60% Chlorotrifluoromethane

Chromic acid, solid 141 1463

Chromic acid, solution 154 1755

Chromic fluoride, solid 154 1756

Chromic fluoride, solution 154 1757

Chromium nitrate 141 2720

Chromium oxychloride 137 1758

Chromium trioxide, anhydrous 141 1463

Chromosulfuric acid 154 2240

Chromosulphuric acid 154 2240

C K 125 1589

Clinical specimens 158 3373

Clinical waste, unspecified, 158 3291

n.o.s.
Name of Material Guide ID

No. No.

Name of Material Guide ID

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Page 111

C N 153 1697

Coal gas 119 1023

Coal gas, compressed 119 1023

Coal tar distillates, flammable 128 1136

Coating solution 127 1139

Cobalt naphthenates, powder 133 2001

Cobalt resinate, precipitated 133 1318

Combustible liquid, n.o.s. 128 1993

Compound, cleaning liquid 154 1760

(corrosive)

Compound, cleaning liquid 128 1993

(flammable)

Compound, tree or weed killing, 154 1760

liquid (corrosive)

Compound, tree or weed killing, 128 1993

liquid (flammable)

Compound, tree or weed killing, 153 2810

liquid (toxic)

Compressed gas, flammable, 115 1954

n.o.s.

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, flammable, 119 1953

toxic, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, n.o.s. 126 1956

Compressed gas, oxidizing, 122 3156

n.o.s.

Compressed gas, poisonous, 123 3304

corrosive, n.o.s.

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, poisonous, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, poisonous, 119 3305

flammable, corrosive, n.o.s.

Compressed gas, poisonous, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, poisonous, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, poisonous, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Compressed gas, poisonous, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, poisonous, 119 1953

flammable, n.o.s.
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 112

Compressed gas, poisonous, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, poisonous, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, poisonous, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, poisonous, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, poisonous, 123 1955

n.o.s.

Compressed gas, poisonous, 123 1955

n.o.s. (Inhalation Hazard

Zone A)

Compressed gas, poisonous, 123 1955

n.o.s. (Inhalation Hazard

Zone B)

Compressed gas, poisonous, 123 1955

n.o.s. (Inhalation Hazard

Zone C)

Compressed gas, poisonous, 123 1955

n.o.s. (Inhalation Hazard

Zone D)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Compressed gas, poisonous, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s.

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, poisonous, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, toxic, 123 3304

corrosive, n.o.s.

Compressed gas, toxic, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, toxic, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, toxic, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, toxic, 123 3304

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, toxic, 119 3305

flammable, corrosive, n.o.s.

Compressed gas, toxic, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, toxic, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, toxic, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 113

Compressed gas, toxic, 119 3305

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, toxic, 119 1953

flammable, n.o.s.

Compressed gas, toxic, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, toxic, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, toxic, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, toxic, 119 1953

flammable, n.o.s. (Inhalation

Hazard Zone D)

Compressed gas, toxic, n.o.s. 123 1955

Compressed gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone A)

Compressed gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone B)

Compressed gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone C)

Compressed gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone D)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Compressed gas, toxic, 124 3306

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s.

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

Compressed gas, toxic, 124 3303

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

Consumer commodity 171 8000

Copper acetoarsenite 151 1585

Copper arsenite 151 1586

Copper based pesticide, liquid, 131 2776

flammable, poisonous

Copper based pesticide, liquid, 131 2776

flammable, toxic

Copper based pesticide, liquid, 151 3010

poisonous

Copper based pesticide, liquid, 131 3009

poisonous, flammable

Copper based pesticide, liquid, 151 3010

toxic

Copper based pesticide, liquid, 131 3009

toxic, flammable

Copper based pesticide, solid, 151 2775

poisonous

Copper based pesticide, solid, 151 2775

toxic

Copper chlorate 141 2721

Copper chloride 154 2802
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 114

Copper cyanide 151 1587

Copra 135 1363

Corrosive liquid, acidic, 154 3264

inorganic, n.o.s.

Corrosive liquid, acidic, organic, 153 3265

n.o.s.

Corrosive liquid, basic, 154 3266

inorganic, n.o.s.

Corrosive liquid, basic, organic, 153 3267

n.o.s.

Corrosive liquid, flammable, 132 2920

n.o.s.

Corrosive liquid, n.o.s. 154 1760

Corrosive liquid, oxidizing, 140 3093

n.o.s.

Corrosive liquid, poisonous, 154 2922

n.o.s.

Corrosive liquid, self-heating, 136 3301

n.o.s.

Corrosive liquid, toxic, n.o.s. 154 2922

Corrosive liquid, water-reactive, 138 3094

n.o.s.

Corrosive liquid, which in 138 3094

contact with water emits

flammable gases, n.o.s.

Corrosive solid, acidic, 154 3260

inorganic, n.o.s.

Corrosive solid, acidic, organic, 154 3261

n.o.s.

Corrosive solid, basic, 154 3262

inorganic, n.o.s.

Corrosive solid, basic, organic, 154 3263

n.o.s.

Corrosive solid, flammable, n.o.s. 134 2921

Corrosive solid, n.o.s. 154 1759

Corrosive solid, oxidizing, n.o.s. 140 3084

Corrosive solid, poisonous, 154 2923

n.o.s.

Corrosive solid, self-heating, 136 3095

n.o.s.

Corrosive solid, toxic, n.o.s. 154 2923

Corrosive solid, water-reactive, 138 3096

n.o.s.

Corrosive solid, which in contact 138 3096

with water emits flammable

gases, n.o.s.

Cotton 133 1365

Cotton, wet 133 1365

Cotton waste, oily 133 1364

Coumarin derivative pesticide, 131 3024

liquid, flammable, poisonous

Coumarin derivative pesticide, 131 3024

liquid, flammable, toxic

Coumarin derivative pesticide, 151 3026

liquid, poisonous

Coumarin derivative pesticide, 131 3025

liquid, poisonous, flammable

Coumarin derivative pesticide, 151 3026

liquid, toxic

Coumarin derivative pesticide, 131 3025

liquid, toxic, flammable

Coumarin derivative pesticide, 151 3027

solid, poisonous

Coumarin derivative pesticide, 151 3027

solid, toxic

Cresols 153 2076

Cresols, liquid 153 2076

Cresols, solid 153 2076

Cresols, solid 153 3455

Cresylic acid 153 2022

Crotonaldehyde, inhibited 131P 1143

Crotonaldehyde, stabilized 131P 1143
Name of Material Guide ID

No. No.

Name of Material Guide ID

No. No.

Page 115

Crotonic acid 153 2823

Crotonic acid, liquid 153 2823

Crotonic acid, solid 153 2823

Crotonylene 128 1144

C S 153 2810

Cumene 130 1918

Cupriethylenediamine, solution 154 1761

C X 154 2811

Cyanide solution, n.o.s. 157 1935

Cyanides, inorganic, n.o.s. 157 1588

Cyanides, inorganic, solid, 157 1588

n.o.s.

Cyanogen 119 1026

Cyanogen, liquefied 119 1026

Cyanogen bromide 157 1889

Cyanogen chloride, inhibited 125 1589

Cyanogen chloride, stabilized 125 1589

Cyanogen gas 119 1026

Cyanuric chloride 157 2670

Cyclobutane 115 2601

Cyclobutyl chloroformate 155 2744

1,5,9-Cyclododecatriene 153 2518

Cycloheptane 128 2241

Cycloheptatriene 131 2603

Cycloheptene 128 2242

Cyclohexane 128 1145

Cyclohexanethiol 129 3054

Cyclohexanone 127 1915

Cyclohexene 130 2256

Cyclohexenyltrichlorosilane 156 1762

Cyclohexyl acetate 130 2243

Cyclohexylamine 132 2357

Cyclohexyl isocyanate 155 2488

Cyclohexyl mercaptan 129 3054

Cyclohexyltrichlorosilane 156 1763

Cyclooctadiene phosphines 135 2940

Cyclooctadienes 130P 2520

Cyclooctatetraene 128P 2358

Cyclopentane 128 1146

Cyclopentanol 129 2244

Cyclopentanone 128 2245

Cyclopentene 128 2246

Cyclopropane 115 1027

Cyclopropane, liquefied 115 1027

Cymenes 130 2046

D A 151 1699

Dangerous goods in apparatus 171 3363

Dangerous goods in machinery 171 3363

D C 153 2810

Decaborane 134 1868

Decahydronaphthalene 130 1147

n-Decane 128 2247

Denatured alcohol 127 1987

Denatured alcohol (toxic) 131 1986

Desensitized explosive, 128 3379

liquid, n.o.s.

Desensitized explosive, 133 3380

solid, n.o.s.

Deuterium 115 1957

Deuterium, compressed 115 1957

Devices, small, hydrocarbon gas 115 3150

powered, with release device

Diacetone alcohol 129 1148

Diacetyl 127 2346

Diagnostic specimens 158 3373

Diallylamine 132 2359

Diallyl ether 131P 2360
Name of Material Guide ID

No. No.

Name of Material Guide ID

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Page 116

4,4'-Diaminodiphenylmethane 153 2651

Di-n-amylamine 131 2841

Dibenzyldichlorosilane 156 2434

Diborane 119 1911

Diborane, compressed 119 1911

Diborane mixtures 119 1911

Dibromobenzene 129 2711

1,2-Dibromobutan-3-one 154 2648

Dibromochloropropanes 159 2872

Dibromodifluoromethane 171 1941

Dibromomethane 160 2664

Di-n-butylamine 132 2248

Dibutylaminoethanol 153 2873

Dibutyl ethers 128 1149

Dichloroacetic acid 153 1764

1,3-Dichloroacetone 153 2649

Dichloroacetyl chloride 156 1765

Dichloroanilines 153 1590

Dichloroanilines, liquid 153 1590

Dichloroanilines, solid 153 1590

Dichloroanilines, solid 153 3442

o-Dichlorobenzene 152 1591

Dichlorobutene 132 2920

2,2'-Dichlorodiethyl ether 152 1916

Dichlorodifluoromethane 126 1028

Dichlorodifluoromethane and 126 2602

Difluoroethane azeotropic

mixture with approximately

74% Dichlorodifluoromethane

Dichlorodifluoromethane and 126 3070

Ethylene oxide mixture, with

not more than 12.5% Ethylene

oxide

Dichlorodifluoromethane and 126 3070

Ethylene oxide mixtures, with

not more than 12% Ethylene

oxide

Dichlorodimethyl ether, 131 2249

symmetrical

1,1-Dichloroethane 130 2362

1,2-Dichloroethylene 130P 1150

Dichloroethylene 130P 1150

Dichloroethyl ether 152 1916

Dichlorofluoromethane 126 1029

Dichloroisocyanuric acid, dry 140 2465

Dichloroisocyanuric acid salts 140 2465

Dichloroisopropyl ether 153 2490

Dichloromethane 160 1593

1,1-Dichloro-1-nitroethane 153 2650

Dichloropentanes 130 1152

Dichlorophenyl isocyanates 156 2250

Dichlorophenyltrichlorosilane 156 1766

1,2-Dichloropropane 130 1279

Dichloropropane 130 1279

1,3-Dichloropropanol-2 153 2750

Dichloropropenes 129 2047

Dichlorosilane 119 2189

1,2-Dichloro-1,1,2,2- 126 1958

tetrafluoroethane

Dichlorotetrafluoroethane 126 1958

3,5-Dichloro-2,4,6- 151 9264

trifluoropyridine

Dicycloheptadiene 128P 2251

Dicyclohexylamine 153 2565

Dicyclohexylammonium nitrite 133 2687

Dicyclopentadiene 130 2048

1,2-Di-(dimethylamino)ethane 129 2372
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Didymium nitrate 140 1465

Dieldrin 151 2761

Diesel fuel 128 1202

Diesel fuel 128 1993

Diethoxymethane 127 2373

3,3-Diethoxypropene 127 2374

Diethylamine 132 1154

2-Diethylaminoethanol 132 2686

Diethylaminoethanol 132 2686

3-Diethylaminopropylamine 132 2684

Diethylaminopropylamine 132 2684

N,N-Diethylaniline 153 2432

Diethylbenzene 130 2049

Diethyl carbonate 128 2366

Diethyldichlorosilane 155 1767

Diethylenetriamine 154 2079

Diethyl ether 127 1155

N,N-Diethylethylenediamine 132 2685

Diethyl ketone 127 1156

Diethyl sulfate 152 1594

Diethyl sulfide 129 2375

Diethyl sulphate 152 1594

Diethyl sulphide 129 2375

Diethylthiophosphoryl chloride 155 2751

Diethylzinc 135 1366

Difluorochloroethanes 115 2517

1,1-Difluoroethane 115 1030

Difluoroethane 115 1030

Difluoroethane and 126 2602

Dichlorodifluoromethane

azeotropic mixture with

approximately 74%

Dichlorodifluoromethane

1,1-Difluoroethylene 116P 1959

Difluoromethane 115 3252

Difluorophosphoric acid, 154 1768

anhydrous

2,3-Dihydropyran 127 2376

Diisobutylamine 132 2361

Diisobutylene, isomeric 128 2050

compounds

Diisobutyl ketone 128 1157

Diisooctyl acid phosphate 153 1902

Diisopropylamine 132 1158

Diisopropyl ether 127 1159

Diketene, inhibited 131P 2521

Diketene, stabilized 131P 2521

1,1-Dimethoxyethane 127 2377

1,2-Dimethoxyethane 127 2252

Dimethylamine, anhydrous 118 1032

Dimethylamine, aqueous 132 1160

solution

Dimethylamine, solution 132 1160

2-Dimethylaminoacetonitrile 131 2378

2-Dimethylaminoethanol 132 2051

2-Dimethylaminoethyl acrylate 152 3302

2-Dimethylaminoethyl 153P 2522

methacrylate

Dimethylaminoethyl 153P 2522

methacrylate

N,N-Dimethylaniline 153 2253

2,3-Dimethylbutane 128 2457

1,3-Dimethylbutylamine 132 2379

Dimethylcarbamoyl chloride 156 2262

Dimethyl carbonate 129 1161

Dimethylcyclohexanes 128 2263

N,N-Dimethylcyclohexylamine 132 2264

Dimethylcyclohexylamine 132 2264
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Dimethyldichlorosilane 155 1162

Dimethyldiethoxysilane 127 2380

Dimethyldioxanes 127 2707

Dimethyl disulfide 130 2381

Dimethyl disulphide 130 2381

Dimethylethanolamine 132 2051

Dimethyl ether 115 1033

N,N-Dimethylformamide 129 2265

1,1-Dimethylhydrazine 131 1163

1,2-Dimethylhydrazine 131 2382

Dimethylhydrazine, symmetrical 131 2382

Dimethylhydrazine, 131 1163

unsymmetrical

2,2-Dimethylpropane 115 2044

Dimethyl-N-propylamine 132 2266

Dimethyl sulfate 156 1595

Dimethyl sulfide 130 1164

Dimethyl sulphate 156 1595

Dimethyl sulphide 130 1164

Dimethyl thiophosphoryl chloride 156 2267

Dimethylzinc 135 1370

Dinitroanilines 153 1596

Dinitrobenzenes 152 1597

Dinitrobenzenes, liquid 152 1597

Dinitrobenzenes, solid 152 1597

Dinitrobenzenes, solid 152 3443

Dinitrochlorobenzenes 153 1577

Dinitro-o-cresol 153 1598

Dinitrogen tetroxide 124 1067

Dinitrogen tetroxide, liquefied 124 1067

Dinitrogen tetroxide and Nitric 124 1975

oxide mixture

Dinitrophenol, solution 153 1599

Dinitrophenol, wetted with not 113 1320

less than 15% water

Dinitrophenolates, wetted with 113 1321

not less than 15% water

Dinitroresorcinol, wetted with 113 1322

not less than 15% water

Dinitrotoluenes 152 2038

Dinitrotoluenes, liquid 152 2038

Dinitrotoluenes, molten 152 1600

Dinitrotoluenes, solid 152 2038

Dinitrotoluenes, solid 152 3454

Dioxane 127 1165

Dioxolane 127 1166

Dipentene 128 2052

Diphenylamine chloroarsine 154 1698

Diphenylchloroarsine 151 1699

Diphenylchloroarsine, liquid 151 1699

Diphenylchloroarsine, solid 151 1699

Diphenylchloroarsine, solid 151 3450

Diphenyldichlorosilane 156 1769

Diphenylmethyl bromide 153 1770

Diphosgene 125 1076

Dipicryl sulfide, wetted with not 113 2852

less than 10% water

Dipicryl sulphide, wetted with 113 2852

not less than 10% water

Dipropylamine 132 2383

Di-n-propyl ether 127 2384

Dipropyl ether 127 2384

Dipropyl ketone 128 2710

Disinfectant, liquid, corrosive, 153 1903

n.o.s.

Disinfectant, liquid, poisonous, 151 3142

n.o.s.

Disinfectant, liquid, toxic, n.o.s. 151 3142
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Disinfectant, solid, poisonous, n.o.s. 151 1601

Disinfectant, solid, toxic, n.o.s. 151 1601

Disinfectants, corrosive, liquid, 153 1903

n.o.s.

Disinfectants, liquid, n.o.s. 151 3142

(poisonous)

Disinfectants, solid, n.o.s. 151 1601

(poisonous)

Disodium trioxosilicate 154 3253

Disodium trioxosilicate, 154 3253

pentahydrate

Dispersant gas, n.o.s. 126 1078

Dispersant gas, n.o.s. 115 1954

(flammable)

Dithiocarbamate pesticide, 131 2772

liquid, flammable, poisonous

Dithiocarbamate pesticide, 131 2772

liquid, flammable, toxic

Dithiocarbamate pesticide, 151 3006

liquid, poisonous

Dithiocarbamate pesticide, 131 3005

liquid, poisonous, flammable

Dithiocarbamate pesticide, 151 3006

liquid, toxic

Dithiocarbamate pesticide, 131 3005

liquid, toxic, flammable

Dithiocarbamate pesticide, 151 2771

solid, poisonous

Dithiocarbamate pesticide, 151 2771

solid, toxic

Divinyl ether, inhibited 128P 1167

Divinyl ether, stabilized 128P 1167

D M 154 1698

Dodecylbenzenesulfonic acid 153 2584

Dodecylbenzenesulphonic acid 153 2584

Dodecyltrichlorosilane 156 1771

DP 125 1076

Dry ice 120 1845

Dye, liquid, corrosive, n.o.s. 154 2801

Dye, liquid, poisonous, n.o.s. 151 1602

Dye, liquid, toxic, n.o.s. 151 1602

Dye, solid, corrosive, n.o.s. 154 3147

Dye, solid, poisonous, n.o.s. 151 3143

Dye, solid, toxic, n.o.s. 151 3143

Dye intermediate, liquid, 154 2801

corrosive, n.o.s.

Dye intermediate, liquid, 151 1602

poisonous, n.o.s.

Dye intermediate, liquid, toxic, 151 1602

n.o.s.

Dye intermediate, solid, 154 3147

corrosive, n.o.s.

Dye intermediate, solid, 151 3143

poisonous, n.o.s.

Dye intermediate, solid, toxic, 151 3143

n.o.s.

E D 151 1892

Elevated temperature liquid, 128 3256

flammable, n.o.s., with flash

point above 37.8°C (100°F),

at or above its flash point

Elevated temperature liquid, 128 3256

flammable, n.o.s., with flash

point above 60.5°C (141°F),

at or above its flash point

Elevated temperature liquid, 128 3257

n.o.s., at or above 100°C

(212°F), and below its flash

point

Elevated temperature solid, 171 3258

n.o.s., at or above 240°C

(464°F)

Engine starting fluid 115 1960
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Engines, internal combustion, 128 3166

flammable gas powered

Engines, internal combustion, 128 3166

flammable liquid powered

Engines, internal combustion, 128 3166

including when fitted in

machinery or vehicles

Environmentally hazardous 171 3082

substances, liquid, n.o.s.

Environmentally hazardous 171 3077

substances, solid, n.o.s.

Epibromohydrin 131 2558

Epichlorohydrin 131P 2023

1,2-Epoxy-3-ethoxypropane 127 2752

Esters, n.o.s. 127 3272

Ethane 115 1035

Ethane, compressed 115 1035

Ethane, refrigerated liquid 115 1961

Ethane-Propane mixture, 115 1961

refrigerated liquid

Ethanol 127 1170

Ethanol, solution 127 1170

Ethanolamine 153 2491

Ethanolamine, solution 153 2491

Ethers, n.o.s. 127 3271

Ethyl acetate 129 1173

Ethylacetylene, inhibited 116P 2452

Ethylacetylene, stabilized 116P 2452

Ethyl acrylate, inhibited 129P 1917

Ethyl acrylate, stabilized 129P 1917

Ethyl alcohol 127 1170

Ethyl alcohol, solution 127 1170

Ethylamine 118 1036

Ethylamine, aqueous solution, 132 2270

with not less than 50% but not

more than 70% Ethylamine

Ethyl amyl ketone 128 2271

2-Ethylaniline 153 2273

N-Ethylaniline 153 2272

Ethylbenzene 130 1175

N-Ethyl-N-benzylaniline 153 2274

N-Ethylbenzyltoluidines 153 2753

N-Ethylbenzyltoluidines, liquid 153 2753

N-Ethylbenzyltoluidines, solid 153 2753

N-Ethylbenzyltoluidines, solid 153 3460

Ethyl borate 129 1176

Ethyl bromide 131 1891

Ethyl bromoacetate 155 1603

2-Ethylbutanol 129 2275

2-Ethylbutyl acetate 130 1177

Ethylbutyl acetate 130 1177

Ethyl butyl ether 127 1179

2-Ethylbutyraldehyde 130 1178

Ethyl butyrate 130 1180

Ethyl chloride 115 1037

Ethyl chloroacetate 155 1181

Ethyl chloroformate 155 1182

Ethyl 2-chloropropionate 129 2935

Ethyl chlorothioformate 155 2826

Ethyl crotonate 130 1862

Ethyl cyanoacetate 156 2666

Ethyldichloroarsine 151 1892

Ethyldichlorosilane 139 1183

Ethylene 116P 1962
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Ethylene, Acetylene and 115 3138

Propylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

Ethylene, compressed 116P 1962

Ethylene, refrigerated liquid 115 1038

(cryogenic liquid)

Ethylene chlorohydrin 131 1135

Ethylenediamine 132 1604

Ethylene dibromide 154 1605

Ethylene dibromide and Methyl 151 1647

bromide mixture, liquid

Ethylene dichloride 131 1184

Ethylene glycol diethyl ether 127 1153

Ethylene glycol monobutyl ether 152 2369

Ethylene glycol monoethyl ether 127 1171

Ethylene glycol monoethyl ether 129 1172

acetate

Ethylene glycol monomethyl ether 127 1188

Ethylene glycol monomethyl 129 1189

ether acetate

Ethyleneimine, inhibited 131P 1185

Ethyleneimine, stabilized 131P 1185

Ethylene oxide 119P 1040

Ethylene oxide and Carbon 115 1041

dioxide mixture, with more

than 9% but not more than

87% Ethylene oxide

Ethylene oxide and Carbon 119P 3300

dioxide mixture, with more

than 87% Ethylene oxide

Ethylene oxide and Carbon 115 1041

dioxide mixtures, with more

than 6 % Ethylene oxide

Ethylene oxide and Carbon 126 1952

dioxide mixtures, with not

more than 6% Ethylene oxide

Ethylene oxide and Carbon 126 1952

dioxide mixtures, with not

more than 9% Ethylene oxide

Ethylene oxide and 126 3297

Chlorotetrafluoroethane

mixture, with not more than

8.8% Ethylene oxide

Ethylene oxide and 126 3070

Dichlorodifluoromethane

mixture, with not more than

12.5% Ethylene oxide

Ethylene oxide and 126 3070

Dichlorodifluoromethane

mixtures, with not more than

12% Ethylene oxide

Ethylene oxide and 126 3298

Pentafluoroethane mixture,

with not more than 7.9%

Ethylene oxide

Ethylene oxide and Propylene 129P 2983

oxide mixture, with not more

than 30% Ethylene oxide

Ethylene oxide and 126 3299

Tetrafluoroethane mixture,

with not more than 5.6%

Ethylene oxide

Ethylene oxide with Nitrogen 119P 1040

Ethyl ether 127 1155

Ethyl fluoride 115 2453

Ethyl formate 129 1190

Ethylhexaldehydes 129 1191

2-Ethylhexylamine 132 2276

2-Ethylhexyl chloroformate 156 2748

Ethyl isobutyrate 129 2385

Ethyl isocyanate 155 2481
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Ethyl lactate 129 1192

Ethyl mercaptan 129 2363

Ethyl methacrylate 130P 2277

Ethyl methacrylate, inhibited 130P 2277

Ethyl methacrylate, stabilized 130P 2277

Ethyl methyl ether 115 1039

Ethyl methyl ketone 127 1193

Ethyl nitrite, solution 131 1194

Ethyl orthoformate 129 2524

Ethyl oxalate 156 2525

Ethylphenyldichlorosilane 156 2435

Ethyl phosphonothioic 154 2927

dichloride, anhydrous

Ethyl phosphonous dichloride, 135 2845

anhydrous

Ethyl phosphorodichloridate 154 2927

1-Ethylpiperidine 132 2386

Ethyl propionate 129 1195

Ethyl propyl ether 127 2615

Ethyl silicate 129 1292

Ethylsulfuric acid 156 2571

Ethylsulphuric acid 156 2571

N-Ethyltoluidines 153 2754

Ethyltrichlorosilane 155 1196

Explosive A 112 ——

Explosive B 112 ——

Explosive C 114 ——

Explosives, division 1.1, 1.2, 112 ——

1.3, 1.5 or 1.6

Explosives, division 1.4 114 ——

Extracts, aromatic, liquid 127 1169

Extracts, flavoring, liquid 127 1197

Extracts, flavouring, liquid 127 1197

Fabrics, animal or vegetable 133 1373

or synthetic, n.o.s. with oil

Fabrics impregnated with weakly 133 1353

nitrated Nitrocellulose, n.o.s.

Ferric arsenate 151 1606

Ferric arsenite 151 1607

Ferric chloride 157 1773

Ferric chloride, anhydrous 157 1773

Ferric chloride, solution 154 2582

Ferric nitrate 140 1466

Ferrocerium 170 1323

Ferrosilicon 139 1408

Ferrous arsenate 151 1608

Ferrous chloride, solid 154 1759

Ferrous chloride, solution 154 1760

Ferrous metal borings, 170 2793

shavings, turnings or cuttings

Fertilizer, ammoniating solution, 125 1043

with free Ammonia

Fiber, animal or vegetable, 133 1372

n.o.s., burnt, wet or damp

Fibers, animal or vegetable 133 1373

or synthetic, n.o.s. with oil

Fibers, animal or vegetable, 133 1372

burnt, wet or damp

Fibers, vegetable, dry 133 3360

Fibers impregnated with weakly 133 1353

nitrated Nitrocellulose, n.o.s.

Fibres, animal or vegetable, 133 1372

burnt, wet or damp

Fibres, animal or vegetable 133 1373

or synthetic, n.o.s. with oil

Fibres, vegetable, dry 133 3360

Fibres impregnated with weakly 133 1353

nitrated Nitrocellulose, n.o.s.

Films, nitrocellulose base 133 1324
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Fire extinguisher charges, 154 1774

corrosive liquid

Fire extinguishers with 126 1044

compressed gas

Fire extinguishers with 126 1044

liquefied gas

Firelighters, solid, with 133 2623

flammable liquid

First aid kit 171 3316

Fish meal, stabilized 171 2216

Fish meal, unstabilized 133 1374

Fish scrap, stabilized 171 2216

Fish scrap, unstabilized 133 1374

Flammable liquid, corrosive, 132 2924

n.o.s

Flammable liquid, n.o.s. 128 1993

Flammable liquid, poisonous, 131 3286

corrosive, n.o.s.

Flammable liquid, poisonous, 131 1992

n.o.s.

Flammable liquid, toxic, 131 3286

corrosive, n.o.s.

Flammable liquid, toxic, n.o.s. 131 1992

Flammable solid, corrosive, 134 3180

inorganic, n.o.s.

Flammable solid, corrosive, 134 2925

n.o.s.

Flammable solid, corrosive, 134 2925

organic, n.o.s.

Flammable solid, inorganic, 134 3180

corrosive, n.o.s.

Flammable solid, inorganic, 133 3178

n.o.s.

Flammable solid, n.o.s. 133 1325

Flammable solid, organic, 133 3176

molten, n.o.s.

Flammable solid, organic, n.o.s. 133 1325

Flammable solid, oxidizing, 140 3097

n.o.s.

Flammable solid, poisonous, 134 3179

inorganic, n.o.s.

Flammable solid, poisonous, 134 2926

n.o.s.

Flammable solid, poisonous, 134 2926

organic, n.o.s.

Flammable solid, toxic, 134 3179

inorganic, n.o.s.

Flammable solid, toxic, organic, 134 2926

n.o.s.

Fluoboric acid 154 1775

Fluorine 124 1045

Fluorine, compressed 124 1045

Fluorine, refrigerated liquid 167 9192

(cryogenic liquid)

Fluoroacetic acid 154 2642

Fluoroanilines 153 2941

Fluorobenzene 130 2387

Fluoroboric acid 154 1775

Fluorophosphoric acid, 154 1776

anhydrous

Fluorosilicates, n.o.s. 151 2856

Fluorosilicic acid 154 1778

Fluorosulfonic acid 137 1777

Fluorosulphonic acid 137 1777

Fluorotoluenes 130 2388

Fluosilicic acid 154 1778

Formaldehyde, solution, 132 1198

flammable

Formaldehyde, solutions 132 1198

(Formalin)

Formaldehyde, solutions 132 2209

(Formalin) (corrosive)

Formic acid 153 1779
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Fuel, aviation, turbine engine 128 1863

Fuel oil 128 1202

Fuel oil 128 1993

Fuel oil, no. 1,2,4,5,6 128 1202

Fumaryl chloride 156 1780

Fumigated unit 171 3359

Furaldehydes 132P 1199

Furan 128 2389

Furfural 132P 1199

Furfuraldehydes 132P 1199

Furfuryl alcohol 153 2874

Furfurylamine 132 2526

Fusee (rail or highway) 133 1325

Fusel oil 127 1201

GA 153 2810

Gallium 172 2803

Gas, refrigerated liquid, 115 3312

flammable, n.o.s.

Gas, refrigerated liquid, n.o.s. 120 3158

Gas, refrigerated liquid, 122 3311

oxidizing, n.o.s.

Gas cartridges 115 2037

Gas generator assemblies 171 8013

Gas identification set 123 9035

Gasohol 128 1203

Gas oil 128 1202

Gasoline 128 1203

Gas sample, non-pressurized, 115 3167

flammable, n.o.s., not

refrigerated liquid

Gas sample, non-pressurized, 119 3168

poisonous, flammable, n.o.s.,

not refrigerated liquid

Gas sample, non-pressurized, 123 3169

poisonous, n.o.s., not

refrigerated liquid

Gas sample, non-pressurized, 119 3168

toxic, flammable, n.o.s., not

refrigerated liquid

Gas sample, non-pressurized, 123 3169

toxic, n.o.s., not refrigerated

liquid

GB 153 2810

GD 153 2810

Genetically modified micro- 171 3245

organisms

Germane 119 2192

G F 153 2810

Glycerol alpha- 153 2689

monochlorohydrin

Glycidaldehyde 131P 2622

Guanidine nitrate 143 1467

H 153 2810

Hafnium powder, dry 135 2545

Hafnium powder, wetted with not 170 1326

less than 25% water

Halogenated irritating liquid, 159 1610

n.o.s.

Hay, wet, damp or contaminated 133 1327

with oil

Hazardous waste, liquid, n.o.s. 171 3082

Hazardous waste, solid, n.o.s. 171 3077

H D 153 2810

Heating oil, light 128 1202

Heat producing article 171 8038

Helium 121 1046

Helium, compressed 121 1046

Helium, refrigerated liquid 120 1963

(cryogenic liquid)
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Heptafluoropropane 126 3296

n-Heptaldehyde 129 3056

Heptanes 128 1206

n-Heptene 128 2278

Hexachloroacetone 153 2661

Hexachlorobenzene 152 2729

Hexachlorobutadiene 151 2279

Hexachlorocyclopentadiene 151 2646

Hexachlorophene 151 2875

Hexadecyltrichlorosilane 156 1781

Hexadiene 130 2458

Hexaethyl tetraphosphate 151 1611

Hexaethyl tetraphosphate, liquid 151 1611

Hexaethyl tetraphosphate, solid 151 1611

Hexaethyl tetraphosphate and 123 1612

compressed gas mixture

Hexafluoroacetone 125 2420

Hexafluoroacetone hydrate 151 2552

Hexafluoroacetone hydrate, 151 2552

liquid

Hexafluoroacetone hydrate, 151 3436

solid

Hexafluoroethane 126 2193

Hexafluoroethane, compressed 126 2193

Hexafluorophosphoric acid 154 1782

Hexafluoropropylene 126 1858

Hexafluoropropylene oxide 126 1956

Hexaldehyde 130 1207

Hexamethylenediamine, solid 153 2280

Hexamethylenediamine, 153 1783

solution

Hexamethylene diisocyanate 156 2281

Hexamethyleneimine 132 2493

Hexamethylenetetramine 133 1328

Hexamine 133 1328

Hexanes 128 1208

Hexanoic acid 153 2829

Hexanols 129 2282

1-Hexene 128 2370

Hexyltrichlorosilane 156 1784

HL 153 2810

HN-1 153 2810

HN-2 153 2810

HN-3 153 2810

Hydrazine, anhydrous 132 2029

Hydrazine, aqueous solution, 153 2030

with more than 37%

Hydrazine

Hydrazine, aqueous solution, 153 2030

with not less than 37% but not

more than 64% Hydrazine

Hydrazine, aqueous solution, 152 3293

with not more than 37%

Hydrazine

Hydrazine, aqueous solutions, 132 2029

with more than 64% Hydrazine

Hydrazine hydrate 153 2030

Hydrides, metal, n.o.s. 138 1409

Hydriodic acid 154 1787

Hydriodic acid, solution 154 1787

Hydrobromic acid 154 1788

Hydrobromic acid, solution 154 1788

Hydrocarbon gas, compressed, 115 1964

n.o.s.

Hydrocarbon gas, liquefied, 115 1965

n.o.s.

Hydrocarbon gas mixture, 115 1964

compressed, n.o.s.

Hydrocarbon gas mixture, 115 1965

liquefied, n.o.s.
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Hydrocarbon gas refills for small 115 3150

devices, with release device

Hydrocarbons, liquid, n.o.s. 128 3295

Hydrochloric acid 157 1789

Hydrochloric acid, solution 157 1789

Hydrocyanic acid, aqueous 154 1613

solution, with less than 5%

Hydrogen cyanide

Hydrocyanic acid, aqueous 154 1613

solution, with not more than

20% Hydrogen cyanide

Hydrocyanic acid, aqueous 117 1051

solutions, with more than 20%

Hydrogen cyanide

Hydrocyanic acid, liquefied 117 1051

Hydrofluoric acid 157 1790

Hydrofluoric acid, solution 157 1790

Hydrofluoric acid and Sulfuric 157 1786

acid mixture

Hydrofluoric acid and Sulphuric 157 1786

acid mixture

Hydrofluorosilicic acid 154 1778

Hydrogen 115 1049

Hydrogen, absorbed in metal 115 9279

hydride

Hydrogen, compressed 115 1049

Hydrogen, in a metal hydride 115 3468

storage system

Hydrogen, refrigerated liquid 115 1966

(cryogenic liquid)

Hydrogen and Carbon monoxide 119 2600

mixture

Hydrogen and Carbon monoxide 119 2600

mixture, compressed

Hydrogen and Methane mixture, 115 2034

compressed

Hydrogen bromide, anhydrous 125 1048

Hydrogen chloride, anhydrous 125 1050

Hydrogen chloride, refrigerated 125 2186

liquid

Hydrogen cyanide, anhydrous, 117 1051

stabilized

Hydrogen cyanide, anhydrous, 152 1614

stabilized (absorbed)

Hydrogen cyanide, aqueous 154 1613

solution, with not more than

20% Hydrogen cyanide

Hydrogen cyanide, solution in 131 3294

alcohol, with not more than

45% Hydrogen cyanide

Hydrogen cyanide, stabilized 117 1051

Hydrogen cyanide, stabilized 152 1614

(absorbed)

Hydrogendifluorides, n.o.s. 154 1740

Hydrogen fluoride, anhydrous 125 1052

Hydrogen iodide, anhydrous 125 2197

Hydrogen peroxide, aqueous 143 2015

solution, stabilized, with more

than 60% Hydrogen peroxide

Hydrogen peroxide, aqueous 140 2984

solution, with not less than 8%

but less than 20% Hydrogen

peroxide

Hydrogen peroxide, aqueous 140 2014

solution, with not less than

20% but not more than 60%

Hydrogen peroxide (stabilized

as necessary)

Hydrogen peroxide, stabilized 143 2015

Hydrogen peroxide and 140 3149

Peroxyacetic acid mixture,

with acid(s), water and not

more than 5% Peroxyacetic

acid, stabilized

Hydrogen selenide, anhydrous 117 2202

Hydrogen sulfide 117 1053
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Page 127

Hydrogen sulfide, liquefied 117 1053

Hydrogen sulphide 117 1053

Hydrogen sulphide, liquefied 117 1053

Hydroquinone 153 2662

Hydroquinone, solid 153 2662

Hydroquinone, solution 153 3435

Hydroxylamine sulfate 154 2865

Hydroxylamine sulphate 154 2865

Hypochlorite solution 154 1791

Hypochlorite solution, with more 154 1791

than 5% available Chlorine

Hypochlorites, inorganic, n.o.s. 140 3212

3,3'-Iminodipropylamine 153 2269

Infectious substance, affecting 158 2900

animals only

Infectious substance, affecting 158 2814

humans

Ink, printer’s, flammable 129 1210

Insecticide gas, flammable, n.o.s. 115 1954

Insecticide gas, flammable, n.o.s. 115 3354

Insecticide gas, n.o.s. 126 1968

Insecticide gas, poisonous, 119 3355

flammable, n.o.s.

Insecticide gas, poisonous, 119 3355

 flammable, n.o.s.

(Inhalation Hazard Zone A)

Insecticide gas, poisonous, 119 3355

 flammable, n.o.s.

(Inhalation Hazard Zone B)

Insecticide gas, poisonous, 119 3355

 flammable, n.o.s.

(Inhalation Hazard Zone C)

Insecticide gas, poisonous, 119 3355

flammable, n.o.s.

(Inhalation Hazard Zone D)

Insecticide gas, poisonous, 123 1967

n.o.s.

Insecticide gas, toxic, flammable, 119 3355

 n.o.s.

Insecticide gas, toxic, flammable, 119 3355

 n.o.s.

(Inhalation Hazard Zone A)

Insecticide gas, toxic, flammable, 119 3355

 n.o.s.

(Inhalation Hazard Zone B)

Insecticide gas, toxic, flammable, 119 3355

 n.o.s.

(Inhalation Hazard Zone C)

Insecticide gas, toxic, flammable, 119 3355

 n.o.s.

(Inhalation Hazard Zone D)

Insecticide gas, toxic, n.o.s. 123 1967

Iodine monochloride 157 1792

Iodine pentafluoride 144 2495

2-Iodobutane 129 2390

Iodomethylpropanes 129 2391

Iodopropanes 129 2392

IPDI 156 2290

Iron oxide, spent 135 1376

Iron pentacarbonyl 131 1994

Iron sponge, spent 135 1376

Isobutane 115 1075

Isobutane 115 1969

Isobutane mixture 115 1075

Isobutane mixture 115 1969

Isobutanol 129 1212

Isobutyl acetate 129 1213

Isobutyl acrylate 130P 2527

Isobutyl acrylate, inhibited 130P 2527

Isobutyl acrylate, stabilized 130P 2527

Isobutyl alcohol 129 1212

Isobutyl aldehyde 130 2045
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Isobutylamine 132 1214

Isobutyl chloroformate 155 2742

Isobutylene 115 1055

Isobutylene 115 1075

Isobutyl formate 129 2393

Isobutyl isobutyrate 130 2528

Isobutyl isocyanate 155 2486

Isobutyl methacrylate 130P 2283

Isobutyl methacrylate, inhibited 130P 2283

Isobutyl methacrylate, stabilized 130P 2283

Isobutyl propionate 129 2394

Isobutyraldehyde 130 2045

Isobutyric acid 132 2529

Isobutyric anhydride 132 2530

Isobutyronitrile 131 2284

Isobutyryl chloride 132 2395

Isocyanate solution, flammable, 155 2478

poisonous, n.o.s.

Isocyanate solution, flammable, 155 2478

toxic, n.o.s.

Isocyanate solution, poisonous, 155 3080

flammable, n.o.s.

Isocyanate solution, poisonous, 155 2206

n.o.s.

Isocyanate solution, toxic, 155 3080

flammable, n.o.s.

Isocyanate solution, toxic, n.o.s. 155 2206

Isocyanate solutions, n.o.s. 155 2206

Isocyanate solutions, n.o.s. 155 2478

Isocyanate solutions, n.o.s. 155 3080

Isocyanates, flammable, 155 2478

poisonous, n.o.s.

Isocyanates, flammable, toxic, 155 2478

n.o.s.

Isocyanates, n.o.s. 155 2206

Isocyanates, n.o.s. 155 2478

Isocyanates, n.o.s. 155 3080

Isocyanates, poisonous, 155 3080

flammable, n.o.s.

Isocyanates, poisonous, n.o.s. 155 2206

Isocyanates, toxic, flammable, 155 3080

n.o.s.

Isocyanates, toxic, n.o.s. 155 2206

Isocyanatobenzotrifluorides 156 2285

Isoheptenes 128 2287

Isohexenes 128 2288

Isooctane 128 1262

Isooctenes 128 1216

Isopentane 128 1265

Isopentenes 128 2371

Isophoronediamine 153 2289

Isophorone diisocyanate 156 2290

Isoprene, inhibited 130P 1218

Isoprene, stabilized 130P 1218

Isopropanol 129 1219

Isopropenyl acetate 129P 2403

Isopropenylbenzene 128 2303

Isopropyl acetate 129 1220

Isopropyl acid phosphate 153 1793

Isopropyl alcohol 129 1219

Isopropylamine 132 1221

Isopropylbenzene 130 1918

Isopropyl butyrate 129 2405

Isopropyl chloroacetate 155 2947

Isopropyl chloroformate 155 2407

Isopropyl 2-chloropropionate 129 2934

Isopropyl isobutyrate 127 2406

Isopropyl isocyanate 155 2483
Name of Material Guide ID

No. No.

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Page 129

Isopropyl nitrate 130 1222

Isopropyl propionate 129 2409

Isosorbide dinitrate mixture 133 2907

Isosorbide-5-mononitrate 133 3251

Kerosene 128 1223

Ketones, liquid, n.o.s. 127 1224

Krypton 121 1056

Krypton, compressed 121 1056

Krypton, refrigerated liquid 120 1970

(cryogenic liquid)

L (Lewisite) 153 2810

Lead acetate 151 1616

Lead arsenates 151 1617

Lead arsenites 151 1618

Lead compound, soluble, n.o.s. 151 2291

Lead cyanide 151 1620

Lead dioxide 141 1872

Lead nitrate 141 1469

Lead perchlorate 141 1470

Lead perchlorate, solid 141 1470

Lead perchlorate, solution 141 1470

Lead perchlorate, solution 141 3408

Lead phosphite, dibasic 133 2989

Lead sulfate, with more than 3% 154 1794

free acid

Lead sulphate, with more than 154 1794

3% free acid

Lewisite 153 2810

Life-saving appliances, not self- 171 3072

inflating

Life-saving appliances, self- 171 2990

inflating

Lighter refills (cigarettes) 115 1057

(flammable gas)

Lighters (cigarettes) 115 1057

(flammable gas)

Lighters for cigars, cigarettes 128 1226

(flammable liquid)

Liquefied gas (nonflammable) 120 1058

Liquefied gas, flammable, n.o.s. 115 1954

Liquefied gas, flammable, n.o.s. 115 3161

Liquefied gas, flammable, 119 1953

poisonous, n.o.s.

Liquefied gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, flammable, 119 1953

poisonous, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, flammable, toxic, 119 1953

n.o.s.

Liquefied gas, flammable, toxic, 119 1953

n.o.s. (Inhalation Hazard

Zone A)

Liquefied gas, flammable, toxic, 119 1953

n.o.s. (Inhalation Hazard

Zone B)

Liquefied gas, flammable, toxic, 119 1953

n.o.s. (Inhalation Hazard

Zone C)

Liquefied gas, flammable, toxic, 119 1953

n.o.s. (Inhalation Hazard

Zone D)

Liquefied gas, n.o.s. 126 1956

Liquefied gas, n.o.s. 126 3163

Liquefied gas, oxidizing, n.o.s. 122 3157
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Liquefied gas, poisonous, 123 3308

corrosive, n.o.s.

Liquefied gas, poisonous, 123 3308

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, poisonous, 123 3308

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, poisonous, 123 3308

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, poisonous, 123 3308

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Liquefied gas, poisonous, 119 3309

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s.

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, poisonous, 119 3160

flammable, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, poisonous, n.o.s. 123 1955

Liquefied gas, poisonous, n.o.s. 123 3162

Liquefied gas, poisonous, n.o.s. 123 1955

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, n.o.s. 123 1955

(Inhalation Hazard Zone B)

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone B)

Liquefied gas, poisonous, n.o.s. 123 1955

(Inhalation Hazard Zone C)

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone C)

Liquefied gas, poisonous, n.o.s. 123 1955

(Inhalation Hazard Zone D)

Liquefied gas, poisonous, n.o.s. 123 3162

(Inhalation Hazard Zone D)

Liquefied gas, poisonous, 124 3310

oxidizing, corrosive, n.o.s.

Liquefied gas, poisonous, 124 3310

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone A)

Liquefied gas, poisonous, 124 3310

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

Liquefied gas, poisonous, 124 3310

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

Liquefied gas, poisonous, 124 3310

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

Liquefied gas, poisonous, 124 3307

oxidizing, n.o.s.
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Liquefied gas, poisonous, 124 3307

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, poisonous, 124 3307

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, poisonous, 124 3307

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, poisonous, 124 3307

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, toxic, corrosive, 123 3308

n.o.s.

Liquefied gas, toxic, corrosive, 123 3308

n.o.s. (Inhalation Hazard

Zone A)

Liquefied gas, toxic, corrosive, 123 3308

n.o.s. (Inhalation Hazard

Zone B)

Liquefied gas, toxic, corrosive, 123 3308

n.o.s. (Inhalation Hazard

Zone C)

Liquefied gas, toxic, corrosive, 123 3308

n.o.s. (Inhalation Hazard

Zone D)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s.

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, toxic, flammable, 119 3309

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, toxic, flammable, 119 3160

n.o.s.

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone A)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone B)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone C)

Liquefied gas, toxic, flammable, 119 3160

n.o.s. (Inhalation Hazard

Zone D)

Liquefied gas, toxic, n.o.s. 123 1955

Liquefied gas, toxic, n.o.s. 123 3162

Liquefied gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone A)

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone A)

Liquefied gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone B)

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone B)

Liquefied gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone C)

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone C)

Liquefied gas, toxic, n.o.s. 123 1955

(Inhalation Hazard Zone D)

Liquefied gas, toxic, n.o.s. 123 3162

(Inhalation Hazard Zone D)

Liquefied gas, toxic, oxidizing, 124 3310

corrosive, n.o.s.

Liquefied gas, toxic, oxidizing, 124 3310

corrosive, n.o.s. (Inhalation

Hazard Zone A)
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Liquefied gas, toxic, oxidizing, 124 3310

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Liquefied gas, toxic, oxidizing, 124 3310

corrosive, n.o.s. (Inhalation

Hazard Zone C)

Liquefied gas, toxic, oxidizing, 124 3310

corrosive, n.o.s. (Inhalation

Hazard Zone D)

Liquefied gas, toxic, oxidizing, 124 3307

n.o.s.

Liquefied gas, toxic, oxidizing, 124 3307

n.o.s. (Inhalation Hazard

Zone A)

Liquefied gas, toxic, oxidizing, 124 3307

n.o.s. (Inhalation Hazard

Zone B)

Liquefied gas, toxic, oxidizing, 124 3307

n.o.s. (Inhalation Hazard

Zone C)

Liquefied gas, toxic, oxidizing, 124 3307

n.o.s. (Inhalation Hazard

Zone D)

Liquefied gases, non-flammable, 120 1058

charged with Nitrogen,

Carbon dioxide or Air

Liquefied natural gas (cryogenic 115 1972

liquid)

Liquefied petroleum gas 115 1075

Lithium 138 1415

Lithium alkyls 135 2445

Lithium alkyls, liquid 135 2445

Lithium alkyls, solid 135 3433

Lithium aluminum hydride 138 1410

Lithium aluminum hydride, 138 1411

ethereal

Lithium amide 139 1412

Lithium batteries 138 3090

Lithium batteries, liquid or solid 138 3090

cathode

Lithium batteries contained in 138 3091

equipment

Lithium batteries packed with 138 3091

equipment

Lithium borohydride 138 1413

Lithium ferrosilicon 139 2830

Lithium hydride 138 1414

Lithium hydride, fused solid 138 2805

Lithium hydroxide 154 2680

Lithium hydroxide, monohydrate 154 2680

Lithium hydroxide, solid 154 2680

Lithium hydroxide, solution 154 2679

Lithium hypochlorite, dry 140 1471

Lithium hypochlorite mixture 140 1471

Lithium hypochlorite mixtures, 140 1471

dry

Lithium nitrate 140 2722

Lithium nitride 138 2806

Lithium peroxide 143 1472

Lithium silicon 138 1417

LNG (cryogenic liquid) 115 1972

London purple 151 1621

LPG 115 1075

Magnesium 138 1869

Magnesium, in pellets, turnings 138 1869

or ribbons

Magnesium alkyls 135 3053

Magnesium alloys, with more 138 1869

than 50% Magnesium, in

pellets, turnings or ribbons

Magnesium alloys powder 138 1418

Magnesium aluminum phosphide 139 1419

Magnesium arsenate 151 1622
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No. No.

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Magnesium bromate 140 1473

Magnesium chlorate 140 2723

Magnesium chloride and 140 1459

Chlorate mixture

Magnesium chloride and 140 1459

Chlorate mixture, solid

Magnesium chloride and 140 3407

Chlorate mixture, solution

Magnesium diamide 135 2004

Magnesium diphenyl 135 2005

Magnesium fluorosilicate 151 2853

Magnesium granules, coated 138 2950

Magnesium hydride 138 2010

Magnesium nitrate 140 1474

Magnesium perchlorate 140 1475

Magnesium peroxide 140 1476

Magnesium phosphide 139 2011

Magnesium powder 138 1418

Magnesium silicide 138 2624

Magnesium silicofluoride 151 2853

Magnetized material 171 2807

Maleic acid 156 2215

Maleic anhydride 156 2215

Maleic anhydride, molten 156 2215

Malononitrile 153 2647

Maneb 135 2210

Maneb, stabilized 135 2968

Maneb preparation, stabilized 135 2968

Maneb preparation, with not less 135 2210

than 60% Maneb

Manganese nitrate 140 2724

Manganese resinate 133 1330

Matches, fusee 133 2254

Matches, safety 133 1944

Matches, “strike anywhere” 133 1331

Matches, wax “vesta” 133 1945

MD 152 1556

Medical waste, n.o.s. 158 3291

Medicine, liquid, flammable, 131 3248

poisonous, n.o.s.

Medicine, liquid, flammable, 131 3248

toxic, n.o.s.

Medicine, liquid, poisonous, 151 1851

n.o.s.

Medicine, liquid, toxic, n.o.s. 151 1851

Medicine, solid, poisonous, 151 3249

n.o.s.

Medicine, solid, toxic, n.o.s. 151 3249

Medicines, corrosive, liquid, 154 1760

n.o.s.

Medicines, corrosive, solid, 154 1759

n.o.s.

Medicines, flammable, liquid, 128 1993

n.o.s.

Medicines, flammable, solid, 133 1325

n.o.s.

Medicines, oxidizing 140 1479

substances, solid, n.o.s.

Mercaptan mixture, liquid, 130 3336

flammable, n.o.s.

Mercaptan mixture, liquid, 131 1228

flammable, poisonous, n.o.s.

Mercaptan mixture, liquid, 131 1228

flammable, toxic, n.o.s.

Mercaptan mixture, liquid, 131 3071

poisonous, flammable, n.o.s.

Mercaptan mixture, liquid, toxic, 131 3071

flammable, n.o.s.

Mercaptan mixtures, liquid, 131 1228

n.o.s.
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Page 134

Mercaptan mixtures, liquid, 131 3071

n.o.s.

Mercaptans, liquid, flammable, 130 3336

n.o.s.

Mercaptans, liquid, flammable, 131 1228

poisonous, n.o.s.

Mercaptans, liquid, flammable, 131 1228

toxic, n.o.s.

Mercaptans, liquid, n.o.s. 131 3071

Mercaptans, liquid, poisonous, 131 3071

flammable, n.o.s.

Mercaptans, liquid, toxic, 131 3071

flammable, n.o.s.

Mercuric arsenate 151 1623

Mercuric bromide 154 1634

Mercuric chloride 154 1624

Mercuric cyanide 154 1636

Mercuric nitrate 141 1625

Mercuric oxycyanide 151 1642

Mercuric potassium cyanide 157 1626

Mercuric sulfate 151 1645

Mercuric sulphate 151 1645

Mercurous bromide 154 1634

Mercurous nitrate 141 1627

Mercury 172 2809

Mercury acetate 151 1629

Mercury ammonium chloride 151 1630

Mercury based pesticide, liquid, 131 2778

flammable, poisonous

Mercury based pesticide, liquid, 131 2778

flammable, toxic

Mercury based pesticide, liquid, 151 3012

poisonous

Mercury based pesticide, liquid, 131 3011

poisonous, flammable

Mercury based pesticide, liquid, 151 3012

toxic

Mercury based pesticide, liquid, 131 3011

toxic, flammable

Mercury based pesticide, solid, 151 2777

poisonous

Mercury based pesticide, solid, 151 2777

toxic

Mercury benzoate 154 1631

Mercury bromides 154 1634

Mercury compound, liquid, n.o.s. 151 2024

Mercury compound, solid, n.o.s. 151 2025

Mercury cyanide 154 1636

Mercury gluconate 151 1637

Mercury iodide 151 1638

Mercury metal 172 2809

Mercury nucleate 151 1639

Mercury oleate 151 1640

Mercury oxide 151 1641

Mercury oxycyanide, 151 1642

desensitized

Mercury potassium iodide 151 1643

Mercury salicylate 151 1644

Mercury sulfate 151 1645

Mercury sulphate 151 1645

Mercury thiocyanate 151 1646

Mesityl oxide 129 1229

Metal alkyl, solution, n.o.s. 135 9195

Metal alkyl halides, n.o.s. 138 3049

Metal alkyl halides, water- 138 3049

reactive, n.o.s.

Metal alkyl hydrides, n.o.s. 138 3050

Metal alkyl hydrides, water- 138 3050

reactive, n.o.s.

Metal alkyls, n.o.s. 135 2003
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No. No.

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No. No.

Page 135

Metal alkyls, water-reactive, 135 2003

n.o.s.

Metal aryl halides, n.o.s. 138 3049

Metal aryl halides, water- 138 3049

reactive, n.o.s.

Metal aryl hydrides, n.o.s. 138 3050

Metal aryl hydrides, water- 138 3050

reactive, n.o.s.

Metal aryls, n.o.s 135 2003

Metal aryls, water-reactive, 135 2003

n.o.s.

Metal carbonyls, liquid, n.o.s. 151 3281

Metal carbonyls, n.o.s. 151 3281

Metal carbonyls, solid, n.o.s. 151 3466

Metal catalyst, dry 135 2881

Metal catalyst, wetted 170 1378

Metaldehyde 133 1332

Metal hydrides, flammable, n.o.s. 170 3182

Metal hydrides, water-reactive, 138 1409

n.o.s.

Metallic substance, water- 138 3208

reactive, n.o.s.

Metallic substance, water- 138 3209

reactive, self-heating, n.o.s.

Metal powder, flammable, n.o.s. 170 3089

Metal powder, self-heating, n.o.s. 135 3189

Metal salts of organic 133 3181

compounds, flammable, n.o.s.

Methacrylaldehyde 131P 2396

Methacrylaldehyde, inhibited 131P 2396

Methacrylaldehyde, stabilized 131P 2396

Methacrylic acid, inhibited 153P 2531

Methacrylic acid, stabilized 153P 2531

Methacrylonitrile, inhibited 131P 3079

Methacrylonitrile, stabilized 131P 3079

Methallyl alcohol 129 2614

Methane 115 1971

Methane, compressed 115 1971

Methane, refrigerated liquid 115 1972

(cryogenic liquid)

Methane and Hydrogen mixture, 115 2034

compressed

Methanesulfonyl chloride 156 3246

Methanesulphonyl chloride 156 3246

Methanol 131 1230

Methoxymethyl isocyanate 155 2605

4-Methoxy-4-methyl- 128 2293

pentan-2-one

1-Methoxy-2-propanol 129 3092

Methyl acetate 129 1231

Methylacetylene and 116P 1060

Propadiene mixture,

stabilized

Methyl acrylate, inhibited 129P 1919

Methyl acrylate, stabilized 129P 1919

Methylal 127 1234

Methyl alcohol 131 1230

Methylallyl chloride 130P 2554

Methylamine, anhydrous 118 1061

Methylamine, aqueous solution 132 1235

Methylamyl acetate 130 1233

Methylamyl alcohol 129 2053

Methyl amyl ketone 127 1110

N-Methylaniline 153 2294

Methyl benzoate 152 2938

alpha-Methylbenzyl alcohol 153 2937

alpha-Methylbenzyl alcohol, 153 2937

liquid

alpha-Methylbenzyl alcohol, 153 3438

solid
Name of Material Guide ID

No. No.

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No. No.

Page 136

Methylbenzyl alcohol (alpha) 153 2937

Methyl bromide 123 1062

Methyl bromide and Chloropicrin 123 1581

mixture

Methyl bromide and Ethylene 151 1647

dibromide mixture, liquid

Methyl bromoacetate 155 2643

2-Methylbutanal 129 3371

3-Methylbutan-2-one 127 2397

2-Methyl-1-butene 128 2459

2-Methyl-2-butene 128 2460

3-Methyl-1-butene 128 2561

N-Methylbutylamine 132 2945

Methyl tert-butyl ether 127 2398

Methyl butyrate 129 1237

Methyl chloride 115 1063

Methyl chloride and Chloropicrin 119 1582

mixture

Methyl chloride and Methylene 115 1912

chloride mixture

Methyl chloroacetate 155 2295

Methyl chloroformate 155 1238

Methyl chloromethyl ether 131 1239

Methyl 2-chloropropionate 129 2933

Methylchlorosilane 119 2534

Methyl cyanide 127 1648

Methylcyclohexane 128 2296

Methylcyclohexanols 129 2617

Methylcyclohexanone 128 2297

Methylcyclopentane 128 2298

Methyl dichloroacetate 155 2299

Methyldichloroarsine 152 1556

Methyldichlorosilane 139 1242

Methylene chloride 160 1593

Methylene chloride and Methyl 115 1912

chloride mixture

Methyl ethyl ether 115 1039

Methyl ethyl ketone 127 1193

2-Methyl-5-ethylpyridine 153 2300

Methyl fluoride 115 2454

Methyl formate 129 1243

2-Methylfuran 128 2301

2-Methyl-2-hepthanethiol 131 3023

5-Methylhexan-2-one 127 2302

Methylhydrazine 131 1244

Methyl iodide 151 2644

Methyl isobutyl carbinol 129 2053

Methyl isobutyl ketone 127 1245

Methyl isocyanate 155 2480

Methyl isopropenyl ketone, 127P 1246

inhibited

Methyl isopropenyl ketone, 127P 1246

stabilized

Methyl isothiocyanate 131 2477

Methyl isovalerate 130 2400

Methyl magnesium bromide in 135 1928

Ethyl ether

Methyl mercaptan 117 1064

Methyl methacrylate monomer, 129P 1247

inhibited

Methyl methacrylate monomer, 129P 1247

stabilized

4-Methylmorpholine 132 2535

N-Methylmorpholine 132 2535

Methylmorpholine 132 2535

Methyl nitrite 116 2455

Methyl orthosilicate 155 2606

Methyl parathion, liquid 152 3018
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Methyl parathion, solid 152 2783

Methylpentadiene 128 2461

2-Methylpentan-2-ol 129 2560

Methylphenyldichlorosilane 156 2437

Methyl phosphonic dichloride 137 9206

Methyl phosphonous dichloride 135 2845

1-Methylpiperidine 132 2399

Methyl propionate 129 1248

Methyl propyl ether 127 2612

Methyl propyl ketone 127 1249

Methyltetrahydrofuran 127 2536

Methyl trichloroacetate 156 2533

Methyltrichlorosilane 155 1250

alpha-Methylvaleraldehyde 130 2367

Methyl valeraldehyde (alpha) 130 2367

Methyl vinyl ketone 131P 1251

Methyl vinyl ketone, stabilized 131P 1251

M.I.B.C. 129 2053

Molybdenum pentachloride 156 2508

Monoethanolamine 153 2491

Mononitrotoluidines 153 2660

Monopropylamine 132 1277

Morpholine 132 2054

Motor fuel anti-knock mixture 131 1649

Motor spirit 128 1203

Muriatic acid 157 1789

Musk xylene 149 2956

Mustard 153 2810

Mustard Lewisite 153 2810

Naphthalene, crude 133 1334

Naphthalene, molten 133 2304

Naphthalene, refined 133 1334

alpha-Naphthylamine 153 2077

Naphthylamine (alpha) 153 2077

beta-Naphthylamine 153 1650

beta-Naphthylamine, solid 153 1650

beta-Naphthylamine, solution 153 3411

Naphthylamine (beta) 153 1650

Naphthylamine (beta), solid 153 1650

Naphthylamine (beta), solution 153 3411

Naphthylthiourea 153 1651

Naphthylurea 153 1652

Natural gas, compressed 115 1971

Natural gas, refrigerated liquid 115 1972

(cryogenic liquid)

Neohexane 128 1208

Neon 121 1065

Neon, compressed 121 1065

Neon, refrigerated liquid 120 1913

(cryogenic liquid)

Nickel carbonyl 131 1259

Nickel catalyst, dry 135 2881

Nickel cyanide 151 1653

Nickel nitrate 140 2725

Nickel nitrite 140 2726

Nicotine 151 1654

Nicotine compound, liquid, 151 3144

n.o.s.

Nicotine compound, solid, n.o.s. 151 1655

Nicotine hydrochloride 151 1656

Nicotine hydrochloride, liquid 151 1656

Nicotine hydrochloride, solid 151 1656

Nicotine hydrochloride, solid 151 3444

Nicotine hydrochloride, solution 151 1656

Nicotine preparation, liquid, 151 3144

n.o.s.
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Nicotine preparation, solid, 151 1655

n.o.s.

Nicotine salicylate 151 1657

Nicotine sulfate, solid 151 1658

Nicotine sulfate, solid 151 3445

Nicotine sulfate, solution 151 1658

Nicotine sulphate, solid 151 1658

Nicotine sulphate, solid 151 3445

Nicotine sulphate, solution 151 1658

Nicotine tartrate 151 1659

Nitrates, inorganic, aqueous 140 3218

solution, n.o.s.

Nitrates, inorganic, n.o.s. 140 1477

Nitrating acid mixture 157 1796

Nitrating acid mixture, spent 157 1826

Nitric acid, fuming 157 2032

Nitric acid, other than red fuming 157 2031

Nitric acid, red fuming 157 2032

Nitric oxide 124 1660

Nitric oxide, compressed 124 1660

Nitric oxide and Dinitrogen 124 1975

tetroxide mixture

Nitric oxide and Nitrogen dioxide 124 1975

mixture

Nitric oxide and Nitrogen 124 1975

tetroxide mixture

Nitriles, flammable, poisonous, 131 3273

n.o.s.

Nitriles, flammable, toxic, n.o.s. 131 3273

Nitriles, poisonous, flammable, 131 3275

n.o.s.

Nitriles, poisonous, liquid, n.o.s. 151 3276

Nitriles, poisonous, n.o.s. 151 3276

Nitriles, poisonous, solid, n.o.s. 151 3439

Nitriles, toxic, flammable, n.o.s. 131 3275

Nitriles, toxic, liquid, n.o.s. 151 3276

Nitriles, toxic, n.o.s. 151 3276

Nitriles, toxic, solid, n.o.s. 151 3439

Nitrites, inorganic, aqueous 140 3219

solution, n.o.s.

Nitrites, inorganic, n.o.s. 140 2627

Nitroanilines 153 1661

Nitroanisoles 152 2730

Nitroanisoles, liquid 152 2730

Nitroanisoles, solid 152 2730

Nitroanisoles, solid 152 3458

Nitrobenzene 152 1662

Nitrobenzenesulfonic acid 153 2305

Nitrobenzenesulphonic acid 153 2305

Nitrobenzotrifluorides 152 2306

Nitrobenzotrifluorides, liquid 152 2306

Nitrobenzotrifluorides, solid 152 3431

Nitrobromobenzenes 152 2732

Nitrobromobenzenes, liquid 152 2732

Nitrobromobenzenes, solid 152 2732

Nitrobromobenzenes, solid 152 3459

Nitrocellulose, solution, 127 2059

flammable

Nitrocellulose, solution, in a 127 2059

flammable liquid

Nitrocellulose membrane filters 133 3270

Nitrocellulose mixture, without 133 2557

plasticizer, without pigment

Nitrocellulose mixture, without 133 2557

plasticizer, with pigment

Nitrocellulose mixture, with 133 2557

plasticizer, without pigment

Nitrocellulose mixture, with 133 2557

plasticizer, with pigment

Nitrocellulose with alcohol 113 2556
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Nitrocellulose with not less than 113 2556

25% alcohol

Nitrocellulose with plasticizing 133 2557

substance

Nitrocellulose with water, not 113 2555

less than 25% water

3-Nitro-4-chlorobenzotrifluoride 152 2307

Nitrocresols 153 2446

Nitrocresols, liquid 153 3434

Nitrocresols, solid 153 2446

Nitroethane 129 2842

Nitrogen 121 1066

Nitrogen, compressed 121 1066

Nitrogen, refrigerated liquid 120 1977

(cryogenic liquid)

Nitrogen and Rare gases mixture 121 1981

Nitrogen and Rare gases 121 1981

mixture, compressed

Nitrogen dioxide 124 1067

Nitrogen dioxide, liquefied 124 1067

Nitrogen dioxide and Nitric oxide 124 1975

mixture

Nitrogen tetroxide and Nitric 124 1975

oxide mixture

Nitrogen trifluoride 122 2451

Nitrogen trifluoride, compressed 122 2451

Nitrogen trioxide 124 2421

Nitroglycerin, solution in 127 3064

alcohol, with more than 1%

but not more than 5%

Nitroglycerin

Nitroglycerin, solution in 127 1204

alcohol, with not more than

1% Nitroglycerin

Nitroglycerin mixture, 113 3343

desensitized, liquid, flammable,

n.o.s., with not more than 30%

Nitroglycerin

Nitroglycerin mixture, 113 3357

desensitized, liquid, n.o.s.,

with not more than 30%

Nitroglycerin

Nitroglycerin mixture, 113 3319

desensitized, solid, n.o.s.,

with more than 2% but not more

than 10% Nitroglycerin

Nitroglycerin mixture with more 113 3319

than 2% but not more than 10%

Nitroglycerin, desensitized

Nitroguanidine (Picrite), wetted 113 1336

with not less than 20% water

Nitroguanidine, wetted with not 113 1336

less than 20% water

Nitrohydrochloric acid 157 1798

Nitromethane 129 1261

Nitronaphthalene 133 2538

Nitrophenols 153 1663

4-Nitrophenylhydrazine, with not 113 3376

less than 30% water

Nitropropanes 129 2608

p-Nitrosodimethylaniline 135 1369

Nitrostarch, wetted with not less 113 1337

than 20% water

Nitrostarch, wetted with not less 113 1337

than 30% solvent

Nitrosyl chloride 125 1069

Nitrosylsulfuric acid 157 2308

Nitrosylsulfuric acid, liquid 157 2308

Nitrosylsulfuric acid, solid 157 2308

Nitrosylsulfuric acid, solid 157 3456

Nitrosylsulphuric acid 157 2308
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Nitrosylsulphuric acid, liquid 157 2308

Nitrosylsulphuric acid, solid 157 2308

Nitrosylsulphuric acid, solid 157 3456

Nitrotoluenes 152 1664

Nitrotoluenes, liquid 152 1664

Nitrotoluenes, solid 152 1664

Nitrotoluenes, solid 152 3446

Nitrotoluidines (mono) 153 2660

Nitrous oxide 122 1070

Nitrous oxide, compressed 122 1070

Nitrous oxide, refrigerated liquid 122 2201

Nitrous oxide and Carbon 126 1015

dioxide mixture

Nitroxylenes 152 1665

Nitroxylenes, liquid 152 1665

Nitroxylenes, solid 152 1665

Nitroxylenes, solid 152 3447

Nonanes 128 1920

Nonyltrichlorosilane 156 1799

2,5-Norbornadiene 128P 2251

2,5-Norbornadiene, inhibited 128P 2251

2,5-Norbornadiene, stabilized 128P 2251

Octadecyltrichlorosilane 156 1800

Octadiene 128P 2309

Octafluorobut-2-ene 126 2422

Octafluorocyclobutane 126 1976

Octafluoropropane 126 2424

Octanes 128 1262

Octyl aldehydes 129 1191

tert-Octyl mercaptan 131 3023

Octyltrichlorosilane 156 1801

Oil, petroleum 128 1270

Oil gas 119 1071

Oil gas, compressed 119 1071

Organic peroxide type B, liquid 146 3101

Organic peroxide type B, liquid, 148 3111

temperature controlled

Organic peroxide type B, solid 146 3102

Organic peroxide type B, solid, 148 3112

temperature controlled

Organic peroxide type C, liquid 146 3103

Organic peroxide type C, liquid, 148 3113

temperature controlled

Organic peroxide type C, solid 146 3104

Organic peroxide type C, solid, 148 3114

temperature controlled

Organic peroxide type D, liquid 145 3105

Organic peroxide type D, liquid, 148 3115

temperature controlled

Organic peroxide type D, solid 145 3106

Organic peroxide type D, solid, 148 3116

temperature controlled

Organic peroxide type E, liquid 145 3107

Organic peroxide type E, liquid, 148 3117

temperature controlled

Organic peroxide type E, solid 145 3108

Organic peroxide type E, solid, 148 3118

temperature controlled

Organic peroxide type F, liquid 145 3109

Organic peroxide type F, liquid, 148 3119

temperature controlled

Organic peroxide type F, solid 145 3110

Organic peroxide type F, solid, 148 3120

temperature controlled

Organic phosphate compound 123 1955

mixed with compressed gas

Organic phosphate mixed with 123 1955

compressed gas
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Organic phosphorus compound 123 1955

mixed with compressed gas

Organic pigments, self-heating 135 3313

Organoarsenic compound, 151 3280

liquid, n.o.s.

Organoarsenic compound, n.o.s. 151 3280

Organoarsenic compound, 151 3465

solid, n.o.s.

Organochlorine pesticide, liquid, 131 2762

flammable, poisonous

Organochlorine pesticide, liquid, 131 2762

flammable, toxic

Organochlorine pesticide, liquid, 151 2996

poisonous

Organochlorine pesticide, liquid, 131 2995

poisonous, flammable

Organochlorine pesticide, liquid, 151 2996

toxic

Organochlorine pesticide, liquid, 131 2995

toxic, flammable

Organochlorine pesticide, solid, 151 2761

poisonous

Organochlorine pesticide, solid, 151 2761

toxic

Organometallic compound, 151 3282

poisonous, liquid, n.o.s.

Organometallic compound, 151 3282

poisonous, n.o.s.

Organometallic compound, 151 3467

poisonous, solid, n.o.s.

Organometallic compound, solid 138 3372

water-reactive, flammable, n.o.s.

Organometallic compound, 151 3282

toxic, liquid, n.o.s.

Organometallic compound, 151 3282

toxic, n.o.s.

Organometallic compound, 151 3467

toxic, solid, n.o.s.

Organometallic compound, 138 3207

water-reactive, flammable, n.o.s.

Organometallic compound 138 3207

dispersion, water-reactive,

flammable, n.o.s.

Organometallic compound 138 3207

solution, water-reactive,

flammable, n.o.s.

Organometallic substance, 135 3392

liquid, pyrophoric

Organometallic substance, 135 3394

liquid, pyrophoric,

water-reactive

Organometallic substance, 135 3398

liquid, water-reactive

Organometallic substance, 138 3399

liquid, water-reactive,

flammable

Organometallic substance, 135 3391

solid, pyrophoric

Organometallic substance, 135 3393

solid, pyrophoric,

water-reactive

Organometallic substance, 138 3400

solid, self-heating

Organometallic substance, 135 3395

solid, water-reactive

Organometallic substance, 138 3396

solid, water-reactive,

flammable

Organometallic substance, 138 3397

solid, water-reactive,

self-heating

Organophosphorus compound, 131 3279

poisonous, flammable, n.o.s.

Organophosphorus compound, 151 3278

poisonous, liquid, n.o.s.

Organophosphorus compound, 151 3278

poisonous, n.o.s.
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Organophosphorus compound, 151 3464

poisonous, solid, n.o.s.

Organophosphorus compound, 131 3279

toxic, flammable, n.o.s.

Organophosphorus compound, 151 3278

toxic, liquid, n.o.s.

Organophosphorus compound, 151 3278

toxic, n.o.s.

Organophosphorus compound, 151 3464

toxic, solid, n.o.s.

Organophosphorus pesticide, 131 2784

liquid, flammable, poisonous

Organophosphorus pesticide, 131 2784

liquid, flammable, toxic

Organophosphorus pesticide, 152 3018

liquid, poisonous

Organophosphorus pesticide, 131 3017

liquid, poisonous, flammable

Organophosphorus pesticide, 152 3018

liquid, toxic

Organophosphorus pesticide, 131 3017

liquid, toxic, flammable

Organophosphorus pesticide, 152 2783

solid, poisonous

Organophosphorus pesticide, 152 2783

solid, toxic

Organotin compound, liquid, 153 2788

n.o.s.

Organotin compound, solid, 153 3146

n.o.s.

Organotin pesticide, liquid, 131 2787

flammable, poisonous

Organotin pesticide, liquid, 131 2787

flammable, toxic

Organotin pesticide, liquid, 153 3020

poisonous

Organotin pesticide, liquid, 131 3019

poisonous, flammable

Organotin pesticide, liquid, toxic 153 3020

Organotin pesticide, liquid, 131 3019

toxic, flammable

Organotin pesticide, solid, 153 2786

poisonous

Organotin pesticide, solid, toxic 153 2786

Osmium tetroxide 154 2471

Other regulated substances, 171 3082

liquid, n.o.s.

Other regulated substances, 171 3077

solid, n.o.s.

Oxidizing liquid, corrosive, 140 3098

n.o.s.

Oxidizing liquid, n.o.s. 140 3139

Oxidizing liquid, poisonous, n.o.s. 142 3099

Oxidizing liquid, toxic, n.o.s. 142 3099

Oxidizing solid, corrosive, n.o.s. 140 3085

Oxidizing solid, flammable, 140 3137

n.o.s.

Oxidizing solid, n.o.s. 140 1479

Oxidizing solid, poisonous, 141 3087

n.o.s.

Oxidizing solid, self-heating, 135 3100

n.o.s.

Oxidizing solid, toxic, n.o.s. 141 3087

Oxidizing solid, water-reactive, 144 3121

n.o.s.

Oxidizing substances, liquid, 140 3098

corrosive, n.o.s.

Oxidizing substances, liquid, 140 3139

n.o.s.

Oxidizing substances, liquid, 142 3099

poisonous, n.o.s.

Oxidizing substances, liquid, 142 3099

toxic, n.o.s.

Oxidizing substances, self- 135 3100

heating, n.o.s.
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Oxidizing substances, solid, 140 3085

corrosive, n.o.s.

Oxidizing substances, solid, 140 3137

flammable, n.o.s.

Oxidizing substances, solid, 140 1479

n.o.s.

Oxidizing substances, solid, 141 3087

poisonous, n.o.s.

Oxidizing substances, solid, 135 3100

self-heating, n.o.s.

Oxidizing substances, solid, 141 3087

toxic, n.o.s.

Oxidizing substances, solid, 144 3121

which in contact with water

emit flammable gases, n.o.s.

Oxygen 122 1072

Oxygen, compressed 122 1072

Oxygen, refrigerated liquid 122 1073

(cryogenic liquid)

Oxygen and Carbon dioxide 122 1014

mixture

Oxygen and Carbon dioxide 122 1014

mixture, compressed

Oxygen and Rare gases mixture 121 1980

Oxygen and Rare gases mixture, 121 1980

compressed

Oxygen difluoride 124 2190

Oxygen difluoride, compressed 124 2190

Oxygen generator, chemical 140 3356

Oxygen generator, chemical, 140 3356

spent

Paint (corrosive) 153 3066

Paint (flammable) 128 1263

Paint related material 153 3066

(corrosive)

Paint related material 128 1263

(flammable)

Paper, unsaturated oil treated 133 1379

Paraformaldehyde 133 2213

Paraldehyde 129 1264

Parathion 152 2783

Parathion and compressed gas 123 1967

mixture

PCB 171 2315

P D 152 1556

Pentaborane 135 1380

Pentachloroethane 151 1669

Pentachlorophenol 154 3155

Pentaerythrite tetranitrate 113 3344

mixture,desensitized, solid,

n.o.s., with more than 10%

but not more than 20% PETN

Pentafluoroethane 126 3220

Pentafluoroethane and Ethylene 126 3298

oxide mixture, with not more

than 7.9% Ethylene oxide

Pentamethylheptane 128 2286

Pentan-2,4-dione 131 2310

n-Pentane 128 1265

2,4-Pentanedione 131 2310

Pentane-2,4-dione 131 2310

Pentanes 128 1265

Pentanols 129 1105

1-Pentene 128 1108

1-Pentol 153P 2705

Percarbonates, inorganic, n.o.s. 140 3217

Perchlorates, inorganic, 140 3211

aqueous solution, n.o.s.

Perchlorates, inorganic, n.o.s. 140 1481

Perchloric acid, with more than 143 1873

50% but not more than 72%

acid
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Perchloric acid, with not more 140 1802

than 50% acid

Perchloroethylene 160 1897

Perchloromethyl mercaptan 157 1670

Perchloryl fluoride 124 3083

Perfluoroethyl vinyl ether 115 3154

Perfluoro(ethyl vinyl ether) 115 3154

Perfluoromethyl vinyl ether 115 3153

Perfluoro(methyl vinyl ether) 115 3153

Perfumery products, with 127 1266

flammable solvents

Permanganates, inorganic, 140 3214

aqueous solution, n.o.s.

Permanganates, inorganic, 140 1482

n.o.s.

Peroxides, inorganic, n.o.s. 140 1483

Persulfates, inorganic, aqueous 140 3216

solution, n.o.s.

Persulfates, inorganic, n.o.s. 140 3215

Persulphates, inorganic, 140 3216

aqueous solution, n.o.s.

Persulphates, inorganic, n.o.s. 140 3215

Pesticide, liquid, flammable, 131 3021

poisonous, n.o.s.

Pesticide, liquid, flammable, 131 3021

toxic, n.o.s.

Pesticide, liquid, poisonous, 131 2903

flammable, n.o.s.

Pesticide, liquid, poisonous, 151 2902

n.o.s.

Pesticide, liquid, toxic, 131 2903

flammable, n.o.s.

Pesticide, liquid, toxic, n.o.s. 151 2902

Pesticide, solid, poisonous 151 2588

Pesticide, solid, poisonous, 151 2588

n.o.s.

Pesticide, solid, toxic, n.o.s. 151 2588

Petrol 128 1203

Petroleum crude oil 128 1267

Petroleum distillates, n.o.s. 128 1268

Petroleum gases, liquefied 115 1075

Petroleum oil 128 1270

Petroleum products, n.o.s. 128 1268

Phenacyl bromide 153 2645

Phenetidines 153 2311

Phenol, molten 153 2312

Phenol, solid 153 1671

Phenol solution 153 2821

Phenolates, liquid 154 2904

Phenolates, solid 154 2905

Phenolsulfonic acid, liquid 153 1803

Phenolsulphonic acid, liquid 153 1803

Phenoxyacetic acid derivative 131 3346

pesticide, liquid, flammable,

poisonous

Phenoxyacetic acid derivative 131 3346

pesticide, liquid, flammable,

toxic

Phenoxyacetic acid derivative 153 3348

pesticide, liquid, poisonous

Phenoxyacetic acid derivative 131 3347

pesticide, liquid, poisonous,

flammable

Phenoxyacetic acid derivative 153 3348

pesticide, liquid, toxic

Phenoxyacetic acid derivative 131 3347

pesticide, liquid, toxic,

flammable

Phenoxyacetic acid derivative 153 3345

pesticide, solid, poisonous

Phenoxyacetic acid derivative 153 3345

pesticide, solid, toxic
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Phenoxy pesticide, liquid, 131 2766

flammable, poisonous

Phenoxy pesticide, liquid, 131 2766

flammable, toxic

Phenoxy pesticide, liquid, 152 3000

poisonous

Phenoxy pesticide, liquid, 131 2999

poisonous, flammable

Phenoxy pesticide, liquid, toxic 152 3000

Phenoxy pesticide, liquid, toxic, 131 2999

flammable

Phenoxy pesticide, solid, 152 2765

poisonous

Phenoxy pesticide, solid, toxic 152 2765

Phenylacetonitrile, liquid 152 2470

Phenylacetyl chloride 156 2577

Phenylcarbylamine chloride 151 1672

Phenyl chloroformate 156 2746

Phenylenediamines 153 1673

Phenylhydrazine 153 2572

Phenyl isocyanate 155 2487

Phenyl mercaptan 131 2337

Phenylmercuric acetate 151 1674

Phenylmercuric compound, 151 2026

n.o.s.

Phenylmercuric hydroxide 151 1894

Phenylmercuric nitrate 151 1895

Phenylphosphorus dichloride 137 2798

Phenylphosphorus 137 2799

thiodichloride

Phenyltrichlorosilane 156 1804

Phenyl urea pesticide, liquid, 131 2768

flammable, poisonous

Phenyl urea pesticide, liquid, 131 2768

flammable, toxic

Phenyl urea pesticide, liquid, 151 3002

poisonous

Phenyl urea pesticide, liquid, 131 3001

poisonous, flammable

Phenyl urea pesticide, liquid, 151 3002

toxic

Phenyl urea pesticide, liquid, 131 3001

toxic, flammable

Phenyl urea pesticide, solid, 151 2767

poisonous

Phenyl urea pesticide, solid, 151 2767

toxic

Phosgene 125 1076

9-Phosphabicyclononanes 135 2940

Phosphine 119 2199

Phosphoric acid 154 1805

Phosphoric acid, liquid 154 1805

Phosphoric acid, solid 154 1805

Phosphoric acid, solid 154 3453

Phosphoric acid, solution 154 1805

Phosphorous acid 154 2834

Phosphorous acid, ortho 154 2834

Phosphorus, amorphous 133 1338

Phosphorus, amorphous, red 133 1338

Phosphorus, white, dry or under 136 1381

water or in solution

Phosphorus, white, molten 136 2447

Phosphorus, yellow, dry or under 136 1381

water or in solution

Phosphorus heptasulfide, free 139 1339

from yellow and white

Phosphorus

Phosphorus heptasulphide, free 139 1339

from yellow and white

Phosphorus

Phosphorus oxybromide 137 1939
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Phosphorus oxybromide, molten 137 2576

Phosphorus oxybromide, solid 137 1939

Phosphorus oxychloride 137 1810

Phosphorus pentabromide 137 2691

Phosphorus pentachloride 137 1806

Phosphorus pentafluoride 125 2198

Phosphorus pentafluoride, 125 2198

compressed

Phosphorus pentasulfide, free 139 1340

from yellow and white

Phosphorus

Phosphorus pentasulphide, free 139 1340

from yellow and white

Phosphorus

Phosphorus pentoxide 137 1807

Phosphorus sesquisulfide, free 139 1341

from yellow and white

Phosphorus

Phosphorus sesquisulphide, 139 1341

free from yellow and white

Phosphorus

Phosphorus tribromide 137 1808

Phosphorus trichloride 137 1809

Phosphorus trioxide 157 2578

Phosphorus trisulfide, free from 139 1343

yellow and white Phosphorus

Phosphorus trisulphide, free 139 1343

from yellow and white

Phosphorus

Phthalic anhydride 156 2214

Phthalimide derivative 131 2774

pesticide, liquid, flammable,

poisonous

Phthalimide derivative 131 2774

pesticide, liquid, flammable,

toxic

Phthalimide derivative 151 3008

pesticide, liquid, poisonous

Phthalimide derivative 131 3007

pesticide, liquid, poisonous,

flammable

Phthalimide derivative 151 3008

pesticide, liquid, toxic

Phthalimide derivative 131 3007

pesticide, liquid, toxic,

flammable

Phthalimide derivative 151 2773

pesticide, solid, poisonous

Phthalimide derivative 151 2773

pesticide, solid, toxic

Picolines 129 2313

Picric acid, wet, with not less 113 1344

than 10% water

Picric acid, wetted with not less 113 3364

than 10% water

Picrite, wetted 113 1336

Picryl chloride, wetted with not 113 3365

less than 10% water

alpha-Pinene 128 2368

Pinene (alpha) 128 2368

Pine oil 129 1272

Piperazine 153 2579

Piperidine 132 2401

Plastic molding compound 171 3314

Plastic, nitrocellulose-based, 135 2006

spontaneously combustible,

n.o.s.

Plastics moulding compound 171 3314

Plastics, nitrocellulose-based, 135 2006

self-heating, n.o.s.

Poison B, liquid, n.o.s. 153 2810

Poisonous by inhalation liquid, 154 3389

corrosive, n.o.s. (Inhalation

Hazard Zone A)
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Poisonous by inhalation liquid, 154 3390

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Poisonous by inhalation liquid, 131 3383

flammable, n.o.s. (Inhalation

Hazard Zone A)

Poisonous by inhalation liquid, 131 3384

flammable, n.o.s. (Inhalation

Hazard Zone B)

Poisonous by inhalation liquid, 151 3381

n.o.s. (Inhalation Hazard

Zone A)

Poisonous by inhalation liquid, 151 3382

n.o.s. (Inhalation Hazard

Zone B)

Poisonous by inhalation liquid, 142 3387

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Poisonous by inhalation liquid, 142 3388

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Poisonous by inhalation liquid, 139 3385

water-reactive, n.o.s.

(Inhalation Hazard Zone A)

Poisonous by inhalation liquid, 139 3386

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

Poisonous liquid, corrosive, 154 3289

inorganic, n.o.s.

Poisonous liquid, corrosive, 154 3289

inorganic, n.o.s. (Inhalation

Hazard Zone A)

Poisonous liquid, corrosive, 154 3289

inorganic, n.o.s. (Inhalation

Hazard Zone B)

Poisonous liquid, corrosive, 154 2927

n.o.s.

Poisonous liquid, corrosive, 154 2927

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, corrosive, 154 2927

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, flammable, 131 2929

n.o.s.

Poisonous liquid, flammable, 131 2929

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, flammable, 131 2929

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, flammable, 131 2929

organic, n.o.s.

Poisonous liquid, flammable, 131 2929

organic, n.o.s. (Inhalation

Hazard Zone A)

Poisonous liquid, flammable, 131 2929

organic, n.o.s. (Inhalation

Hazard Zone B)

Poisonous liquid, inorganic, 151 3287

n.o.s.

Poisonous liquid, inorganic, 151 3287

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, inorganic, 151 3287

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, n.o.s. 153 2810

Poisonous liquid, n.o.s. 153 2810

(Inhalation Hazard Zone A)

Poisonous liquid, n.o.s. 153 2810

(Inhalation Hazard Zone B)

Poisonous liquid, organic, n.o.s. 153 2810

Poisonous liquid, organic, n.o.s. 153 2810

(Inhalation Hazard Zone A)

Poisonous liquid, organic, n.o.s. 153 2810

(Inhalation Hazard Zone B)

Poisonous liquid, oxidizing, 142 3122

n.o.s.
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Poisonous liquid, oxidizing, 142 3122

n.o.s. (Inhalation Hazard

Zone A)

Poisonous liquid, oxidizing, 142 3122

n.o.s. (Inhalation Hazard

Zone B)

Poisonous liquid, water- 139 3123

reactive, n.o.s.

Poisonous liquid, water- 139 3123

reactive, n.o.s. (Inhalation

Hazard Zone A)

Poisonous liquid, water- 139 3123

reactive, n.o.s. (Inhalation

Hazard Zone B)

Poisonous liquid, which in 139 3123

contact with water emits

flammable gases, n.o.s.

Poisonous liquid, which in 139 3123

contact with water emits

flammable gases, n.o.s.

(Inhalation Hazard Zone A)

Poisonous liquid, which in 139 3123

contact with water emits

flammable gases, n.o.s.

(Inhalation Hazard Zone B)

Poisonous solid, corrosive, 154 3290

inorganic, n.o.s.

Poisonous solid, corrosive, 154 2928

n.o.s.

Poisonous solid, flammable, 134 2930

n.o.s.

Poisonous solid, flammable, 134 2930

organic, n.o.s.

Poisonous solid, inorganic, 151 3288

n.o.s.

Poisonous solid, organic, n.o.s. 154 2811

Poisonous solid, oxidizing, 141 3086

n.o.s.

Poisonous solid, self-heating, 136 3124

n.o.s.

Poisonous solid, water-reactive, 139 3125

n.o.s.

Poisonous solid, which in 139 3125

contact with water emits

flammable gases, n.o.s.

Polyalkylamines, n.o.s. 132 2733

Polyalkylamines, n.o.s. 132 2734

Polyalkylamines, n.o.s. 153 2735

Polyamines, flammable, 132 2733

corrosive, n.o.s.

Polyamines, liquid, corrosive, 132 2734

flammable, n.o.s.

Polyamines, liquid, corrosive, 153 2735

n.o.s.

Polyamines, solid, corrosive, 154 3259

n.o.s.

Polychlorinated biphenyls 171 2315

Polychlorinated biphenyls, liquid 171 2315

Polychlorinated biphenyls, solid 171 2315

Polychlorinated biphenyls, solid 171 3432

Polyester resin kit 128 3269

Polyhalogenated biphenyls, 171 3151

liquid

Polyhalogenated biphenyls, 171 3152

solid

Polyhalogenated terphenyls, 171 3151

liquid

Polyhalogenated terphenyls, 171 3152

solid

Polymeric beads, expandable 133 2211

Polystyrene beads, expandable 133 2211

Potassium 138 2257

Potassium, metal 138 2257

Potassium, metal alloys 138 1420

Potassium, metal alloys, liquid 138 1420

Potassium, metal alloys, solid 138 3403
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Potassium arsenate 151 1677

Potassium arsenite 154 1678

Potassium borohydride 138 1870

Potassium bromate 140 1484

Potassium chlorate 140 1485

Potassium chlorate, aqueous 140 2427

solution

Potassium chlorate, solution 140 2427

Potassium cuprocyanide 157 1679

Potassium cyanide 157 1680

Potassium cyanide, solid 157 1680

Potassium cyanide, solution 157 3413

Potassium dithionite 135 1929

Potassium fluoride 154 1812

Potassium fluoride, solid 154 1812

Potassium fluoride, solution 154 3422

Potassium fluoroacetate 151 2628

Potassium fluorosilicate 151 2655

Potassium hydrogendifluoride 154 1811

Potassium hydrogen difluoride, 154 1811

solid

Potassium hydrogen difluoride, 154 3421

solution

Potassium hydrogen sulfate 154 2509

Potassium hydrogen sulphate 154 2509

Potassium hydrosulfite 135 1929

Potassium hydrosulphite 135 1929

Potassium hydroxide, dry, solid 154 1813

Potassium hydroxide, flake 154 1813

Potassium hydroxide, solid 154 1813

Potassium hydroxide, solution 154 1814

Potassium metavanadate 151 2864

Potassium monoxide 154 2033

Potassium nitrate 140 1486

Potassium nitrate and Sodium 140 1499

nitrate mixture

Potassium nitrate and Sodium 140 1487

nitrite mixture

Potassium nitrite 140 1488

Potassium perchlorate 140 1489

Potassium permanganate 140 1490

Potassium peroxide 144 1491

Potassium persulfate 140 1492

Potassium persulphate 140 1492

Potassium phosphide 139 2012

Potassium silicofluoride 151 2655

Potassium sodium alloys 138 1422

Potassium sodium alloys, liquid 138 1422

Potassium sodium alloys, solid 138 3404

Potassium sulfide, anhydrous 135 1382

Potassium sulfide, hydrated, 153 1847

with not less than 30% water

of crystallization

Potassium sulfide, hydrated, 153 1847

with not less than 30% water

of hydration

Potassium sulfide, with less than 135 1382

30% water of crystallization

Potassium sulfide, with less than 135 1382

30% water of hydration

Potassium sulphide, anhydrous 135 1382

Potassium sulphide, hydrated, 153 1847

with not less than 30% water

of crystallization

Potassium sulphide, hydrated, 153 1847

with not less than 30% water

of hydration

Potassium sulphide, with less 135 1382

than 30% water of

crystallization
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Potassium sulphide, with less 135 1382

than 30% water of hydration

Potassium superoxide 143 2466

Printing ink, flammable 129 1210

Printing ink related material 129 1210

Propadiene, inhibited 116P 2200

Propadiene, stabilized 116P 2200

Propadiene and 116P 1060

Methylacetylene mixture,

stabilized

Propane 115 1075

Propane 115 1978

Propane-Ethane mixture, 115 1961

refrigerated liquid

Propane mixture 115 1075

Propane mixture 115 1978

Propanethiols 130 2402

n-Propanol 129 1274

Propargyl alcohol 131 1986

Propionaldehyde 129 1275

Propionic acid 132 1848

Propionic anhydride 156 2496

Propionitrile 131 2404

Propionyl chloride 132 1815

n-Propyl acetate 129 1276

normal Propyl alcohol 129 1274

Propyl alcohol, normal 129 1274

Propylamine 132 1277

n-Propyl benzene 128 2364

Propyl chloride 129 1278

n-Propyl chloroformate 155 2740

Propylene 115 1075

Propylene 115 1077

Propylene, Ethylene and 115 3138

Acetylene in mixture,

refrigerated liquid containing

at least 71.5% Ethylene with

not more than 22.5%

Acetylene and not more than

6% Propylene

Propylene chlorohydrin 131 2611

1,2-Propylenediamine 132 2258

1,3-Propylenediamine 132 2258

Propylene dichloride 130 1279

Propyleneimine, inhibited 131P 1921

Propyleneimine, stabilized 131P 1921

Propylene oxide 127P 1280

Propylene oxide and Ethylene 129P 2983

oxide mixture, with not more

than 30% Ethylene oxide

Propylene tetramer 128 2850

Propyl formates 129 1281

n-Propyl isocyanate 155 2482

n-Propyl nitrate 131 1865

Propyltrichlorosilane 155 1816

Pyrethroid pesticide, liquid, 131 3350

flammable, poisonous

Pyrethroid pesticide, liquid, 131 3350

flammable, toxic

Pyrethroid pesticide, liquid, 151 3352

 poisonous

Pyrethroid pesticide, liquid, 131 3351

poisonous, flammable

Pyrethroid pesticide, liquid, toxic 151 3352

Pyrethroid pesticide, liquid, toxic, 131 3351

 flammable

Pyrethroid pesticide, solid, 151 3349

 poisonous

Pyrethroid pesticide, solid, toxic 151 3349

Pyridine 129 1282
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Pyrophoric alloy, n.o.s. 135 1383

Pyrophoric liquid, inorganic, 135 3194

n.o.s.

Pyrophoric liquid, n.o.s. 135 2845

Pyrophoric liquid, organic, n.o.s. 135 2845

Pyrophoric metal, n.o.s. 135 1383

Pyrophoric organometallic 135 3203

compound, n.o.s.

Pyrophoric organometallic 135 3203

compound, water-reactive,

n.o.s.

Pyrophoric solid, inorganic, 135 3200

n.o.s.

Pyrophoric solid, n.o.s. 135 2846

Pyrophoric solid, organic, n.o.s. 135 2846

Pyrosulfuryl chloride 137 1817

Pyrosulphuryl chloride 137 1817

Pyrrolidine 132 1922

Quinoline 154 2656

Radioactive material, articles 161 2909

manufactured from depleted

Uranium

Radioactive material, articles 161 2909

manufactured from natural

Thorium

Radioactive material, articles 161 2909

manufactured from natural

Uranium

Radioactive material, empty 161 2908

packages

Radioactive material, excepted 161 2909

package, articles manufactured

from depleted Uranium

Radioactive material, excepted 161 2910

package, articles manufactured

from depleted Uranium

Radioactive material, excepted 161 2909

package, articles manufactured

from natural Thorium

Radioactive material, excepted 161 2910

package, articles manufactured

from natural Thorium

Radioactive material, excepted 161 2909

package, articles manufactured

from natural Uranium

Radioactive material, excepted 161 2910

package, articles manufactured

from natural Uranium

Radioactive material, excepted 161 2908

package, empty packaging

Radioactive material, excepted 161 2910

package, empty packaging

Radioactive material, excepted 161 2910

package, instruments or

articles

Radioactive material, excepted 161 2911

package, instruments or

articles

Radioactive material, excepted 161 2910

package, limited quantity of

material

Radioactive material, fissile, 165 2918

n.o.s.

Radioactive material, 161 2911

instruments or articles

Radioactive material, limited 161 2910

quantity, n.o.s.

Radioactive material, low 162 2912

specific activity (LSA), n.o.s.

Radioactive material, low 162 2912

specific activity (LSA-I)

Radioactive material, low 162 3321

specific activity (LSA-II)
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Radioactive material, low 165 3324

specific activity (LSA-II),

fissile

Radioactive material, low 162 3322

specific activity (LSA-III)

Radioactive material, low 165 3325

specific activity (LSA-III),

fissile

Radioactive material, n.o.s. 163 2982

Radioactive material, special 164 2974

form, n.o.s.

Radioactive material, surface 162 2913

contaminated objects (SCO)

Radioactive material, surface 162 2913

contaminated objects (SCO-I)

Radioactive material, surface 165 3326

contaminated objects

(SCO-I), fissile

Radioactive material, surface 162 2913

contaminated objects (SCO-II)

Radioactive material, surface 165 3326

contaminated objects

(SCO-II), fissile

Radioactive material, transported 163 2919

under special arrangement

Radioactive material, transported 165 3331

under special arrangement,

fissile

Radioactive material, Type A 163 2915

 package

Radioactive material, Type A 165 3327

 package, fissile

Radioactive material, Type A 164 3332

package, special form

Radioactive material, Type A 165 3333

package, special form, fissile

Radioactive material, Type B(M) 163 2917

 package

Radioactive material, Type B(M) 165 3329

package, fissile

Radioactive material, Type B(U) 163 2916

package

Radioactive material, Type B(U) 165 3328

package, fissile

Radioactive material, Type C 163 3323

package

Radioactive material, Type C 165 3330

package, fissile

Radioactive material, Uranium 166 2977

hexafluoride, fissile

Radioactive material, Uranium 166 2978

hexafluoride

Radioactive material, Uranium 166 2978

hexafluoride, non-fissile or

fissile-excepted

Rags, oily 133 1856

Rare gases and Nitrogen mixture 121 1981

Rare gases and Nitrogen 121 1981

mixture, compressed

Rare gases and Oxygen mixture 121 1980

Rare gases and Oxygen mixture, 121 1980

compressed

Rare gases mixture 121 1979

Rare gases mixture, compressed 121 1979

Receptacles, small, containing 115 2037

gas

Red phosphorus 133 1338

Red phosphorus, amorphous 133 1338

Refrigerant gas, n.o.s. 126 1078

Refrigerant gas, n.o.s. 115 1954

(flammable)

Refrigerant gas R-12 126 1028

Refrigerant gas R-12 and 126 2602

Refrigerant gas R-152a

azeotropic mixture with 74%

Refrigerant gas R-12
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Refrigerant gas R-12B1 126 1974

Refrigerant gas R-13 126 1022

Refrigerant gas R-13 and 126 2599

Refrigerant gas R-23

azeotropic mixture with 60%

Refrigerant gas R-13

Refrigerant gas R-13B1 126 1009

Refrigerant gas R-14 126 1982

Refrigerant gas R-14, 126 1982

compressed

Refrigerant gas R-21 126 1029

Refrigerant gas R-22 126 1018

Refrigerant gas R-23 126 1984

Refrigerant gas R-23 and 126 2599

Refrigerant gas R-13

azeotropic mixture with 60%

Refrigerant gas R-13

Refrigerant gas R-32 115 3252

Refrigerant gas R-40 115 1063

Refrigerant gas R-41 115 2454

Refrigerant gas R-114 126 1958

Refrigerant gas R-115 126 1020

Refrigerant gas R-116 126 2193

Refrigerant gas R-116, 126 2193

compressed

Refrigerant gas R-124 126 1021

Refrigerant gas R-125 126 3220

Refrigerant gas R-133a 126 1983

Refrigerant gas R-134a 126 3159

Refrigerant gas R-143a 115 2035

Refrigerant gas R-142b 115 2517

Refrigerant gas R-152a 115 1030

Refrigerant gas R-152a and 126 2602

Refrigerant gas R-12

azeotropic mixture with 74%

Refrigerant gas R-12

Refrigerant gas R-161 115 2453

Refrigerant gas R-218 126 2424

Refrigerant gas R-227 126 3296

Refrigerant gas R-404A 126 3337

Refrigerant gas R-407A 126 3338

Refrigerant gas R-407B 126 3339

Refrigerant gas R-407C 126 3340

Refrigerant gas R-500 126 2602

(azeotropic mixture of

Refrigerant gas R-12 and

Refrigerant gas R-152a with

approximately 74%

Refrigerant gas R-12)

Refrigerant gas R-502 126 1973

Refrigerant gas R-503 126 2599

(azeotropic mixture of

Refrigerant gas R-13 and

Refrigerant gas R-23 with

approximately 60%

Refrigerant gas R-13)

Refrigerant gas R-1132a 116P 1959

Refrigerant gas R-1216 126 1858

Refrigerant gas R-1318 126 2422

Refrigerant gas RC-318 126 1976

Refrigerating machine 128 1993

Refrigerating machines, 126 2857

containing Ammonia solutions

(UN2073)

Refrigerating machines, 126 2857

containing Ammonia solutions

(UN2672)

Refrigerating machines, 115 1954

containing flammable,

non-poisonous, noncorrosive, liquefied gas

Refrigerating machines, containing 115 3358

flammable, non-toxic, liquefied

gas
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Refrigerating machines, 126 2857

containing non-flammable,

liquefied gas

Refrigerating machines, 126 2857

containing non-flammable,

non-poisonous gases

Refrigerating machines, 126 2857

containing non-flammable,

non-poisonous, liquefied gas

Refrigerating machines, 126 2857

containing non-flammable,

non-poisonous, non-corrosive,

liquefied gas

Refrigerating machines, 126 2857

containing non-flammable,

non-toxic gases

Refrigerating machines, 126 2857

containing non-flammable,

non-toxic, liquefied gas

Refrigerating machines, 126 2857

containing non-flammable,

non-toxic, non-corrosive,

liquefied gas

Regulated medical waste, n.o.s. 158 3291

Regulated medical waste 158 9275

Resin solution 127 1866

Resorcinol 153 2876

Rosin oil 127 1286

Rubber scrap, powdered or 133 1345

granulated

Rubber shoddy, powdered or 133 1345

granulated

Rubber solution 127 1287

Rubidium 138 1423

Rubidium hydroxide 154 2678

Rubidium hydroxide, solid 154 2678

Rubidium hydroxide, solution 154 2677

Rubidium metal 138 1423

SA 119 2188

Sarin 153 2810

Seat-belt modules 171 3268

Seat-belt pre-tensioners 171 3268

Seat-belt pre-tensioners, 126 3353

compressed gas

Seat-belt pre-tensioners, 171 3268

pyrotechnic

Seed cake, with more than 1.5% 135 1386

oil and not more than 11%

moisture

Seed cake, with not more than 135 2217

1.5% oil and not more than

11% moisture

Selenates 151 2630

Selenic acid 154 1905

Selenites 151 2630

Selenium compound, liquid, 151 3440

n.o.s.

Selenium compound, n.o.s. 151 3283

Selenium compound, solid, 151 3283

n.o.s.

Selenium disulfide 153 2657

Selenium disulphide 153 2657

Selenium hexafluoride 125 2194

Selenium oxide 154 2811

Selenium oxychloride 157 2879

Selenium powder 152 2658

Self-defense spray, non- 171 3334

pressurized

Self-heating liquid, corrosive, 136 3188

inorganic, n.o.s.

Self-heating liquid, corrosive, 136 3185

organic, n.o.s.

Self-heating liquid, inorganic, 135 3186

n.o.s.
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Self-heating liquid, organic, 135 3183

n.o.s.

Self-heating liquid, poisonous, 136 3187

inorganic, n.o.s.

Self-heating liquid, poisonous, 136 3184

organic, n.o.s.

Self-heating liquid, toxic, 136 3187

inorganic, n.o.s.

Self-heating liquid, toxic, 136 3184

organic, n.o.s.

Self-heating metal powders, 135 3189

n.o.s.

Self-heating solid, corrosive, 136 3192

inorganic, n.o.s.

Self-heating solid, corrosive, 136 3126

organic, n.o.s.

Self-heating solid, inorganic, 135 3190

n.o.s.

Self-heating solid, inorganic, 136 3191

poisonous, n.o.s.

Self-heating solid, inorganic, 136 3191

toxic, n.o.s.

Self-heating solid, organic, 135 3088

n.o.s.

Self-heating solid, organic, 136 3128

poisonous, n.o.s.

Self-heating solid, organic, 136 3128

toxic, n.o.s.

Self-heating solid, oxidizing, 135 3127

n.o.s.

Self-heating solid, poisonous, 136 3191

inorganic, n.o.s.

Self-heating solid, poisonous, 136 3128

organic, n.o.s.

Self-heating solid, toxic, 136 3191

inorganic, n.o.s.

Self-heating solid, toxic, 136 3128

organic, n.o.s.

Self-heating substance, solid, 136 3126

corrosive, n.o.s.

Self-heating substances, solid, 135 3088

n.o.s.

Self-heating substances, solid, 135 3127

oxidizing, n.o.s.

Self-heating substances, solid, 136 3128

poisonous, n.o.s.

Self-heating substances, solid, 136 3128

toxic, n.o.s.

Self-reactive liquid type B 149 3221

Self-reactive liquid type B, 150 3231

temperature controlled

Self-reactive liquid type C 149 3223

Self-reactive liquid type C, 150 3233

temperature controlled

Self-reactive liquid type D 149 3225

Self-reactive liquid type D, 150 3235

temperature controlled

Self-reactive liquid type E 149 3227

Self-reactive liquid type E, 150 3237

temperature controlled

Self-reactive liquid type F 149 3229

Self-reactive liquid type F, 150 3239

temperature controlled

Self-reactive solid type B 149 3222

Self-reactive solid type B, 150 3232

temperature controlled

Self-reactive solid type C 149 3224

Self-reactive solid type C, 150 3234

temperature controlled

Self-reactive solid type D 149 3226

Self-reactive solid type D, 150 3236

temperature controlled

Self-reactive solid type E 149 3228

Self-reactive solid type E, 150 3238

temperature controlled
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Self-reactive solid type F 149 3230

Self-reactive solid type F, 150 3240

temperature controlled

Shale oil 128 1288

Silane 116 2203

Silicofluorides, n.o.s. 151 2856

Silane, compressed 116 2203

Silicon powder, amorphous 170 1346

Silicon tetrachloride 157 1818

Silicon tetrafluoride 125 1859

Silicon tetrafluoride, 125 1859

compressed

Silver arsenite 151 1683

Silver cyanide 151 1684

Silver nitrate 140 1493

Silver picrate, wetted with not 113 1347

less than 30% water

Sludge acid 153 1906

Smokeless powder for small 133 3178

arms

Soda lime, with more than 4% 154 1907

Sodium hydroxide

Sodium 138 1428

Sodium aluminate, solid 154 2812

Sodium aluminate, solution 154 1819

Sodium aluminum hydride 138 2835

Sodium ammonium vanadate 154 2863

Sodium arsanilate 154 2473

Sodium arsenate 151 1685

Sodium arsenite, aqueous 154 1686

solution

Sodium arsenite, solid 151 2027

Sodium azide 153 1687

Sodium bisulfate, solution 154 2837

Sodium bisulphate, solution 154 2837

Sodium borohydride 138 1426

Sodium borohydride and Sodium 157 3320

hydroxide solution, with not

more than 12% Sodium

borohydride and not more

than 40% Sodium hydroxide

Sodium bromate 141 1494

Sodium cacodylate 152 1688

Sodium carbonate peroxyhydrate 140 3378

Sodium chlorate 140 1495

Sodium chlorate, aqueous 140 2428

solution

Sodium chlorite 143 1496

Sodium chlorite, solution, with 154 1908

more than 5% available

Chlorine

Sodium chloroacetate 151 2659

Sodium cuprocyanide, solid 157 2316

Sodium cuprocyanide, solution 157 2317

Sodium cyanide 157 1689

Sodium cyanide, solid 157 1689

Sodium cyanide, solution 157 3414

Sodium dichloroisocyanurate 140 2465

Sodium dichloro-s-triazinetrione 140 2465

Sodium dinitro-o-cresolate, 113 3369

wetted with not less than 10%

water

Sodium dinitro-o-cresolate, 113 1348

wetted with not less than 15%

water

Sodium dinitro-ortho-cresolate, 113 1348

wetted

Sodium dithionite 135 1384

Sodium fluoride 154 1690

Sodium fluoride, solid 154 1690
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Sodium fluoride, solution 154 3415

Sodium fluoroacetate 151 2629

Sodium fluorosilicate 154 2674

Sodium hydride 138 1427

Sodium hydrogendifluoride 154 2439

Sodium hydrogen sulfate, 154 2837

solution

Sodium hydrogen sulphate, 154 2837

solution

Sodium hydrosulfide, solid, 135 2318

with less than 25% water of

crystallization

Sodium hydrosulfide, solution 154 2922

Sodium hydrosulfide, with less 135 2318

than 25% water of

crystallization

Sodium hydrosulfide, with not 154 2949

less than 25% water of

crystallization

Sodium hydrosulfite 135 1384

Sodium hydrosulphide, solid, 135 2318

with less than 25% water of

crystallization

Sodium hydrosulphide, solution 154 2922

Sodium hydrosulphide, with less 135 2318

than 25% water of

crystallization

Sodium hydrosulphide, with not 154 2949

less than 25% water of

crystallization

Sodium hydrosulphite 135 1384

Sodium hydroxide, bead 154 1823

Sodium hydroxide, dry 154 1823

Sodium hydroxide, flake 154 1823

Sodium hydroxide, granular 154 1823

Sodium hydroxide, solid 154 1823

Sodium hydroxide, solution 154 1824

Sodium methylate 138 1431

Sodium methylate, dry 138 1431

Sodium methylate, solution in 132 1289

alcohol

Sodium monoxide 157 1825

Sodium nitrate 140 1498

Sodium nitrate and Potassium 140 1499

nitrate mixture

Sodium nitrite 140 1500

Sodium nitrite and Potassium 140 1487

nitrate mixture

Sodium pentachlorophenate 154 2567

Sodium perborate 140 3377

monohydrate

Sodium percarbonates 140 2467

Sodium perchlorate 140 1502

Sodium permanganate 140 1503

Sodium peroxide 144 1504

Sodium peroxoborate, 140 3247

anhydrous

Sodium persulfate 140 1505

Sodium persulphate 140 1505

Sodium phosphide 139 1432

Sodium picramate, wetted with 113 1349

not less than 20% water

Sodium potassium alloys 138 1422

Sodium potassium alloys, liquid 138 1422

Sodium potassium alloys, solid 138 3404

Sodium selenite 151 2630

Sodium silicofluoride 154 2674

Sodium sulfide, anhydrous 135 1385

Sodium sulfide, hydrated, with 153 1849

not less than 30% water
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Sodium sulfide, with less than 135 1385

30% water of crystallization

Sodium sulphide, anhydrous 135 1385

Sodium sulphide, hydrated, with 153 1849

not less than 30% water

Sodium sulphide, with less than 135 1385

30% water of crystallization

Sodium superoxide 143 2547

Solids containing corrosive 154 3244

liquid, n.o.s.

Solids containing flammable 133 3175

liquid, n.o.s.

Solids containing poisonous 151 3243

liquid, n.o.s.

Solids containing toxic liquid, 151 3243

n.o.s.

Soman 153 2810

Stannic chloride, anhydrous 137 1827

Stannic chloride, pentahydrate 154 2440

Stannic phosphides 139 1433

Stibine 119 2676

Straw, wet, damp or 133 1327

contaminated with oil

Strontium arsenite 151 1691

Strontium chlorate 143 1506

Strontium chlorate, solid 143 1506

Strontium chlorate, solution 143 1506

Strontium nitrate 140 1507

Strontium perchlorate 140 1508

Strontium peroxide 143 1509

Strontium phosphide 139 2013

Strychnine 151 1692

Strychnine salts 151 1692

Styrene monomer, inhibited 128P 2055

Styrene monomer, stabilized 128P 2055

Substances, which in contact 138 3129

with water emit flammable

gases, liquid, corrosive, n.o.s.

Substances, which in contact 138 3148

with water emit flammable

gases, liquid, n.o.s.

Substances, which in contact 139 3130

with water emit flammable

gases, liquid, poisonous,

n.o.s.

Substances, which in contact 139 3130

with water emit flammable

gases, liquid, toxic, n.o.s.

Substances, which in contact 138 3131

with water emit flammable

gases, solid, corrosive, n.o.s.

Substances, which in contact 138 3132

with water emit flammable

gases, solid, flammable, n.o.s.

Substances, which in contact 138 2813

with water emit flammable

gases, solid, n.o.s.

Substances, which in contact 138 3133

with water emit flammable

gases, solid, oxidizing, n.o.s.

Substances, which in contact 139 3134

with water emit flammable

gases, solid, poisonous,

n.o.s.

Substances, which in contact 138 3135

with water emit flammable

gases, solid, self-heating,

n.o.s.

Substances, which in contact 139 3134

with water emit flammable

gases, solid, toxic, n.o.s.

Substituted nitrophenol 131 2780

pesticide, liquid, flammable,

poisonous
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Substituted nitrophenol 131 2780

pesticide, liquid, flammable,

toxic

Substituted nitrophenol 153 3014

pesticide, liquid, poisonous

Substituted nitrophenol 131 3013

pesticide, liquid, poisonous,

flammable

Substituted nitrophenol 153 3014

pesticide, liquid, toxic

Substituted nitrophenol 131 3013

pesticide, liquid, toxic,

flammable

Substituted nitrophenol 153 2779

pesticide, solid, poisonous

Substituted nitrophenol 153 2779

pesticide, solid, toxic

Sulfamic acid 154 2967

Sulfur 133 1350

Sulfur, molten 133 2448

Sulfur chlorides 137 1828

Sulfur dioxide 125 1079

Sulfur dioxide, liquefied 125 1079

Sulfur hexafluoride 126 1080

Sulfuric acid 137 1830

Sulfuric acid, fuming 137 1831

Sulfuric acid, fuming, with less 137 1831

than 30% free Sulfur trioxide

Sulfuric acid, fuming, with not 137 1831

less than 30% free Sulfur

trioxide

Sulfuric acid, spent 137 1832

Sulfuric acid, with more than 137 1830

51% acid

Sulfuric acid, with not more than 157 2796

51% acid

Sulfuric acid and Hydrofluoric 157 1786

acid mixture

Sulfurous acid 154 1833

Sulfur tetrafluoride 125 2418

Sulfur trioxide 137 1829

Sulfur trioxide, inhibited 137 1829

Sulfur trioxide, stabilized 137 1829

Sulfur trioxide, uninhibited 137 1829

Sulfur trioxide and 137 1754

Chlorosulfonic acid mixture

Sulfuryl chloride 137 1834

Sulfuryl fluoride 123 2191

Sulphamic acid 154 2967

Sulphur 133 1350

Sulphur, molten 133 2448

Sulphur chlorides 137 1828

Sulphur dioxide 125 1079

Sulphur dioxide, liquefied 125 1079

Sulphur hexafluoride 126 1080

Sulphuric acid 137 1830

Sulphuric acid, fuming 137 1831

Sulphuric acid, fuming, with less 137 1831

than 30% free Sulphur trioxide

Sulphuric acid, fuming, with not 137 1831

less than 30% free Sulphur

trioxide

Sulphuric acid, spent 137 1832

Sulphuric acid, with more than 137 1830

51% acid

Sulphuric acid, with not more 157 2796

than 51% acid

Sulphuric acid and Hydrofluoric 157 1786

acid mixture

Sulphurous acid 154 1833

Sulphur tetrafluoride 125 2418
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Sulphur trioxide 137 1829

Sulphur trioxide, inhibited 137 1829

Sulphur trioxide, stabilized 137 1829

Sulphur trioxide, uninhibited 137 1829

Sulphur trioxide and 137 1754

Chlorosulphonic acid mixture

Sulphuryl chloride 137 1834

Sulphuryl fluoride 123 2191

Tabun 153 2810

Tars, liquid 130 1999

Tear gas candles 159 1700

Tear gas devices 159 1693

Tear gas grenades 159 1700

Tear gas substance, liquid, 159 1693

n.o.s.

Tear gas substance, solid, n.o.s. 159 1693

Tear gas substance, solid, n.o.s. 159 3448

Tellurium compound, n.o.s. 151 3284

Tellurium hexafluoride 125 2195

Terpene hydrocarbons, n.o.s. 128 2319

Terpinolene 128 2541

Tetrabromoethane 159 2504

1,1,2,2-Tetrachloroethane 151 1702

Tetrachloroethane 151 1702

Tetrachloroethylene 160 1897

Tetraethyl dithiopyrophosphate 153 1704

Tetraethyl dithiopyrophosphate, 153 1704

mixture, dry or liquid

Tetraethylenepentamine 153 2320

Tetraethyl lead, liquid 131 1649

Tetraethyl pyrophosphate, liquid 152 3018

Tetraethyl pyrophosphate, solid 152 2783

Tetraethyl silicate 129 1292

1,1,1,2-Tetrafluoroethane 126 3159

Tetrafluoroethane and Ethylene 126 3299

oxide mixture, with not more

than 5.6% Ethylene oxide

Tetrafluoroethylene, inhibited 116P 1081

Tetrafluoroethylene, stabilized 116P 1081

Tetrafluoromethane 126 1982

Tetrafluoromethane, 126 1982

compressed

1,2,3,6-Tetrahydro- 129 2498

benzaldehyde

Tetrahydrofuran 127 2056

Tetrahydrofurfurylamine 129 2943

Tetrahydrophthalic anhydrides 156 2698

1,2,3,6-Tetrahydropyridine 129 2410

1,2,5,6-Tetrahydropyridine 129 2410

Tetrahydrothiophene 130 2412

Tetramethylammonium 153 1835

hydroxide

Tetramethylammonium 153 3423

hydroxide, solid

Tetramethylammonium 153 1835

hydroxide, solution

Tetramethylsilane 130 2749

Tetranitromethane 143 1510

Tetrapropyl orthotitanate 128 2413

Textile waste, wet 133 1857

Thallium chlorate 141 2573

Thallium compound, n.o.s. 151 1707

Thallium nitrate 141 2727

Thallium sulfate, solid 151 1707

Thallium sulphate, solid 151 1707

4-Thiapentanal 152 2785

Thia-4-pentanal 152 2785

Thickened GD 153 2810

Thioacetic acid 129 2436
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Thiocarbamate pesticide, liquid, 131 2772

flammable, poisonous

Thiocarbamate pesticide, liquid, 131 2772

flammable, toxic

Thiocarbamate pesticide, liquid, 151 3006

 poisonous

Thiocarbamate pesticide, liquid, 131 3005

poisonous, flammable

Thiocarbamate pesticide, liquid, 151 3006

toxic

Thiocarbamate pesticide, liquid, 131 3005

toxic, flammable

Thiocarbamate pesticide, solid, 151 2771

poisonous

Thiocarbamate pesticide, solid, 151 2771

toxic

Thioglycol 153 2966

Thioglycolic acid 153 1940

Thiolactic acid 153 2936

Thionyl chloride 137 1836

Thiophene 130 2414

Thiophosgene 157 2474

Thiophosphoryl chloride 157 1837

Thiourea dioxide 135 3341

Thorium metal, pyrophoric 162 2975

Thorium nitrate, solid 162 2976

Tinctures, medicinal 127 1293

Tin tetrachloride 137 1827

Tin tetrachloride, pentahydrate 154 2440

Titanium disulfide 135 3174

Titanium disulphide 135 3174

Titanium hydride 170 1871

Titanium powder, dry 135 2546

Titanium powder, wetted with 170 1352

not less than 25% water

Titanium sponge granules 170 2878

Titanium sponge powders 170 2878

Titanium sulfate, solution 154 1760

Titanium sulphate, solution 154 1760

Titanium tetrachloride 137 1838

Titanium trichloride, pyrophoric 135 2441

Titanium trichloride mixture 157 2869

Titanium trichloride mixture, 135 2441

pyrophoric

TNT, wetted with not less than 113 3366

10% water

TNT, wetted with not less than 113 1356

30% water

Toe puffs, nitrocellulose base 133 1353

Toluene 130 1294

2,4-Toluenediamine 151 1709

Toluene diisocyanate 156 2078

Toluene sulfonic acid, liquid, 153 2584

with more than 5% free

Sulfuric acid

Toluene sulfonic acid, liquid, 153 2586

with not more than 5% free

Sulfuric acid

Toluene sulfonic acid, solid, with 153 2583

more than 5% free Sulfuric

acid

Toluene sulfonic acid, solid, with 153 2585

not more than 5% free Sulfuric

acid

Toluene sulphonic acid, liquid, 153 2584

with more than 5% free

Sulphuric acid

Toluene sulphonic acid, liquid, 153 2586

with not more than 5% free

Sulphuric acid
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Toluene sulphonic acid, solid, 153 2583

with more than 5% free

Sulphuric acid

Toluene sulphonic acid, solid, 153 2585

with not more than 5% free

Sulphuric acid

Toluidines 153 1708

Toluidines, liquid 153 1708

Toluidines, solid 153 1708

Toluidines, solid 153 3451

2,4-Toluylenediamine 151 1709

2,4-Toluylenediamine, solid 151 1709

2,4-Toluylenediamine, solution 151 3418

Toxic by inhalation liquid, 154 3389

corrosive, n.o.s. (Inhalation

Hazard Zone A)

Toxic by inhalation liquid, 154 3390

corrosive, n.o.s. (Inhalation

Hazard Zone B)

Toxic by inhalation liquid, 131 3383

flammable, n.o.s. (Inhalation

Hazard Zone A)

Toxic by inhalation liquid, 131 3384

flammable, n.o.s. (Inhalation

Hazard Zone B)

Toxic by inhalation liquid, 151 3381

n.o.s. (Inhalation Hazard

Zone A)

Toxic by inhalation liquid, 151 3382

n.o.s. (Inhalation Hazard

Zone B)

Toxic by inhalation liquid, 142 3387

oxidizing, n.o.s. (Inhalation

Hazard Zone A)

Toxic by inhalation liquid, 142 3388

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

Toxic by inhalation liquid, 139 3385

water-reactive, n.o.s.

(Inhalation Hazard Zone A)

Toxic by inhalation liquid, 139 3386

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

Toxic liquid, corrosive, 154 3289

inorganic, n.o.s.

Toxic liquid, corrosive, 154 3289

inorganic, n.o.s. (Inhalation

Hazard Zone A)

Toxic liquid, corrosive, 154 3289

inorganic, n.o.s. (Inhalation

Hazard Zone B)

Toxic liquid, corrosive, organic, 154 2927

n.o.s.

Toxic liquid, corrosive, organic, 154 2927

n.o.s. (Inhalation Hazard

Zone A)

Toxic liquid, corrosive, organic, 154 2927

n.o.s. (Inhalation Hazard

Zone B)

Toxic liquid, flammable, n.o.s. 131 2929

Toxic liquid, flammable, n.o.s. 131 2929

(Inhalation Hazard Zone A)

Toxic liquid, flammable, n.o.s. 131 2929

(Inhalation Hazard Zone B)

Toxic liquid, flammable, organic, 131 2929

n.o.s.

Toxic liquid, flammable, organic, 131 2929

n.o.s. (Inhalation Hazard

Zone A)

Toxic liquid, flammable, organic, 131 2929

n.o.s. (Inhalation Hazard

Zone B)

Toxic liquid, inorganic, n.o.s. 151 3287

Toxic liquid, inorganic, n.o.s. 151 3287

(Inhalation Hazard Zone A)
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Toxic liquid, inorganic, n.o.s. 151 3287

(Inhalation Hazard Zone B)

Toxic liquid, n.o.s. 153 2810

Toxic liquid, n.o.s. (Inhalation 153 2810

Hazard Zone A)

Toxic liquid, n.o.s. (Inhalation 153 2810

Hazard Zone B)

Toxic liquid, organic, n.o.s. 153 2810

Toxic liquid, organic, n.o.s. 153 2810

(Inhalation Hazard Zone A)

Toxic liquid, organic, n.o.s. 153 2810

(Inhalation Hazard Zone B)

Toxic liquid, oxidizing, n.o.s. 142 3122

Toxic liquid, oxidizing, n.o.s. 142 3122

(Inhalation Hazard Zone A)

Toxic liquid, oxidizing, n.o.s. 142 3122

(Inhalation Hazard Zone B)

Toxic liquid, water-reactive, 139 3123

n.o.s.

Toxic liquid, water-reactive, 139 3123

n.o.s. (Inhalation Hazard

Zone A)

Toxic liquid, water-reactive, 139 3123

n.o.s. (Inhalation Hazard

Zone B)

Toxic liquid, which in contact 139 3123

with water emits flammable

gases, n.o.s.

Toxic liquid, which in contact 139 3123

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone A)

Toxic liquid, which in contact 139 3123

with water emits flammable

gases, n.o.s. (Inhalation

Hazard Zone B)

Toxic solid, corrosive, inorganic, 154 3290

n.o.s.

Toxic solid, corrosive, organic, 154 2928

n.o.s.

Toxic solid, flammable, n.o.s. 134 2930

Toxic solid, flammable, organic, 134 2930

n.o.s.

Toxic solid, inorganic, n.o.s. 151 3288

Toxic solid, organic, n.o.s. 154 2811

Toxic solid, oxidizing, n.o.s. 141 3086

Toxic solid, self-heating, n.o.s. 136 3124

Toxic solid, water-reactive, 139 3125

n.o.s.

Toxic solid, which in contact with 139 3125

water emits flammable gases,

n.o.s.

Toxins 153 ——

Toxins, extracted from living 153 3172

sources, liquid, n.o.s.

Toxins, extracted from living 153 3172

sources, n.o.s.

Toxins, extracted from living 153 3172

sources, solid, n.o.s.

Toxins, extracted from living 153 3462

sources, solid, n.o.s.

Triallylamine 132 2610

Triallyl borate 156 2609

Triazine pesticide, liquid, 131 2764

flammable, poisonous

Triazine pesticide, liquid, 131 2764

flammable, toxic

Triazine pesticide, liquid, 151 2998

poisonous

Triazine pesticide, liquid, 131 2997

poisonous, flammable

Triazine pesticide, liquid, toxic 151 2998

Triazine pesticide, liquid, toxic, 131 2997

flammable
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Triazine pesticide, solid, 151 2763

poisonous

Triazine pesticide, solid, toxic 151 2763

Tri-(1-aziridinyl)phosphine 152 2501

oxide, solution

Tributylamine 153 2542

Tributylphosphane 135 3254

Tributylphosphine 135 3254

Trichloroacetic acid 153 1839

Trichloroacetic acid, solution 153 2564

Trichloroacetyl chloride 156 2442

Trichlorobenzenes, liquid 153 2321

Trichlorobutene 152 2322

1,1,1-Trichloroethane 160 2831

Trichloroethylene 160 1710

Trichloroisocyanuric acid, dry 140 2468

Trichlorosilane 139 1295

(mono)-(Trichloro)-tetra- 140 2468

(monopotassium dichloro)-

penta-s-triazinetrione, dry

Tricresyl phosphate 151 2574

Triethylamine 132 1296

Triethylenetetramine 153 2259

Triethyl phosphite 130 2323

Trifluoroacetic acid 154 2699

Trifluoroacetyl chloride 125 3057

Trifluorochloroethylene 119P 1082

Trifluorochloroethylene, 119P 1082

inhibited

Trifluorochloroethylene, 119P 1082

stabilized

1,1,1-Trifluoroethane 115 2035

Trifluoroethane, compressed 115 2035

Trifluoromethane 126 1984

Trifluoromethane, refrigerated 120 3136

liquid

Trifluoromethane and 126 2599

Chlorotrifluoromethane

azeotropic mixture with

approximately 60%

Chlorotrifluoromethane

2-Trifluoromethylaniline 153 2942

3-Trifluoromethylaniline 153 2948

Triisobutylene 128 2324

Triisopropyl borate 129 2616

Trimethoxysilane 132 9269

Trimethylacetyl chloride 132 2438

Trimethylamine, anhydrous 118 1083

Trimethylamine, aqueous 132 1297

solution

1,3,5-Trimethylbenzene 129 2325

Trimethyl borate 129 2416

Trimethylchlorosilane 155 1298

Trimethylcyclohexylamine 153 2326

Trimethylhexamethylenediamines 153 2327

Trimethylhexamethylene 156 2328

diisocyanate

Trimethyl phosphite 130 2329

Trinitrobenzene, wetted with not 113 3367

less than 10% water

Trinitrobenzene, wetted with not 113 1354

less than 30% water

Trinitrobenzoic acid, wetted with 113 3368

not less than 10% water

Trinitrobenzoic acid, wetted with 113 1355

not less than 30% water

Trinitrochlorobenzene, wetted 113 3365

with not less than 10% water

Trinitrophenol, wetted with not 113 3364

less than 10% water
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Trinitrophenol, wetted with not 113 1344

less than 30% water

Trinitrotoluene, wetted with not 113 3366

less than 10% water

Trinitrotoluene, wetted with not 113 1356

less than 30% water

Tripropylamine 132 2260

Tripropylene 128 2057

Tris-(1-aziridinyl)phosphine 152 2501

oxide, solution

Tungsten hexafluoride 125 2196

Turpentine 128 1299

Turpentine substitute 128 1300

Undecane 128 2330

Uranium hexafluoride 166 2978

Uranium hexafluoride, fissile 166 2977

containing more than 1%

Uranium-235

Uranium hexafluoride, fissile- 166 2978

excepted

Uranium hexafluoride, low 166 2978

specific activity

Uranium hexafluoride, non- 166 2978

fissile

Uranium metal, pyrophoric 162 2979

Uranium nitrate, hexahydrate, 162 2980

solution

Uranyl nitrate, hexahydrate, 162 2980

solution

Uranyl nitrate, solid 162 2981

Urea hydrogen peroxide 140 1511

Urea nitrate, wetted with not less 113 3370

than 10% water

Urea nitrate, wetted with not less 113 1357

than 20% water

Valeraldehyde 129 2058

Valeryl chloride 132 2502

Vanadium compound, n.o.s. 151 3285

Vanadium oxytrichloride 137 2443

Vanadium pentoxide 151 2862

Vanadium tetrachloride 137 2444

Vanadium trichloride 157 2475

Vanadyl sulfate 151 2931

Vanadyl sulphate 151 2931

Vehicle, flammable gas powered 128 3166

Vehicle, flammable liquid 128 3166

powered

Vinyl acetate 129P 1301

Vinyl acetate, inhibited 129P 1301

Vinyl acetate, stabilized 129P 1301

Vinyl bromide, inhibited 116P 1085

Vinyl bromide, stabilized 116P 1085

Vinyl butyrate, inhibited 129P 2838

Vinyl butyrate, stabilized 129P 2838

Vinyl chloride, inhibited 116P 1086

Vinyl chloride, stabilized 116P 1086

Vinyl chloroacetate 155 2589

Vinyl ethyl ether 127P 1302

Vinyl ethyl ether, inhibited 127P 1302

Vinyl ethyl ether, stabilized 127P 1302

Vinyl fluoride, inhibited 116P 1860

Vinyl fluoride, stabilized 116P 1860

Vinylidene chloride, inhibited 130P 1303

Vinylidene chloride, stabilized 130P 1303

Vinyl isobutyl ether 127P 1304

Vinyl isobutyl ether, inhibited 127P 1304

Vinyl isobutyl ether, stabilized 127P 1304

Vinyl methyl ether 116P 1087

Vinyl methyl ether, inhibited 116P 1087
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Vinyl methyl ether, stabilized 116P 1087

Vinylpyridines, inhibited 131P 3073

Vinylpyridines, stabilized 131P 3073

Vinyltoluenes, inhibited 130P 2618

Vinyltoluenes, stabilized 130P 2618

Vinyltrichlorosilane 155P 1305

Vinyltrichlorosilane, inhibited 155P 1305

Vinyltrichlorosilane, stabilized 155P 1305

VX 153 2810

Water-reactive liquid, corrosive, 138 3129

n.o.s.

Water-reactive liquid, n.o.s. 138 3148

Water-reactive liquid, 139 3130

poisonous, n.o.s.

Water-reactive liquid, toxic, 139 3130

n.o.s.

Water-reactive solid, corrosive, 138 3131

n.o.s.

Water-reactive solid, flammable, 138 3132

n.o.s.

Water-reactive solid, n.o.s. 138 2813

Water-reactive solid, oxidizing, 138 3133

n.o.s.

Water-reactive solid, poisonous, 139 3134

n.o.s.

Water-reactive solid, self- 138 3135

heating, n.o.s.

Water-reactive solid, toxic, n.o.s. 139 3134

Water-reactive substances, 138 3129

liquid, corrosive, n.o.s.

Water-reactive substances, 138 3148

liquid, n.o.s.

Water-reactive substances, 139 3130

liquid, poisonous, n.o.s.

Water-reactive substances, 139 3130

liquid, toxic, n.o.s.

Water-reactive substances, 138 3131

solid, corrosive, n.o.s.

Water-reactive substances, 138 3132

solid, flammable, n.o.s.

Water-reactive substances, 138 2813

solid, n.o.s.

Water-reactive substances, 138 3133

solid, oxidizing, n.o.s.

Water-reactive substances, 139 3134

solid, poisonous, n.o.s.

Water-reactive substances, 138 3135

solid, self-heating, n.o.s.

Water-reactive substances, 139 3134

solid, toxic, n.o.s.

Wheelchair, electric, with 154 3171

batteries

White asbestos 171 2590

White phosphorus, dry 136 1381

White phosphorus, in solution 136 1381

White phosphorus, molten 136 2447

White phosphorus, under water 136 1381

Wood preservatives, liquid 129 1306

Wool waste, wet 133 1387

Xanthates 135 3342

Xenon 121 2036

Xenon, compressed 121 2036

Xenon, refrigerated liquid 120 2591

(cryogenic liquid)

Xylenes 130 1307

Xylenols 153 2261

Xylenols, liquid 153 3430

Xylenols, solid 153 2261

Xylidines 153 1711

Xylidines, liquid 153 1711

Xylidines, solid 153 1711
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Xylidines, solid 153 3452

Xylyl bromide 152 1701

Xylyl bromide, liquid 152 1701

Xylyl bromide, solid 152 3417

Yellow phosphorus, dry 136 1381

Yellow phosphorus, in solution 136 1381

Yellow phosphorus, molten 136 2447

Yellow phosphorus, under water 136 1381

Zinc ammonium nitrite 140 1512

Zinc arsenate 151 1712

Zinc arsenate and Zinc arsenite 151 1712

mixture

Zinc arsenite 151 1712

Zinc arsenite and Zinc arsenate 151 1712

mixture

Zinc ashes 138 1435

Zinc bromate 140 2469

Zinc chlorate 140 1513

Zinc chloride, anhydrous 154 2331

Zinc chloride, solution 154 1840

Zinc cyanide 151 1713

Zinc dithionite 171 1931

Zinc dross 138 1435

Zinc dust 138 1436

Zinc fluorosilicate 151 2855

Zinc hydrosulfite 171 1931

Zinc hydrosulphite 171 1931

Zinc nitrate 140 1514

Zinc permanganate 140 1515

Zinc peroxide 143 1516

Zinc phosphide 139 1714

Zinc powder 138 1436

Zinc residue 138 1435

Zinc resinate 133 2714

Zinc silicofluoride 151 2855

Zinc skimmings 138 1435

Zirconium, dry, coiled wire, 170 2858

finished metal sheets or strips

Zirconium, dry, finished sheets, 135 2009

strips or coiled wire

Zirconium hydride 138 1437

Zirconium metal, liquid 170 1308

suspension

Zirconium metal, powder, wet 170 1358

Zirconium nitrate 140 2728

Zirconium picramate, wetted 113 1517

with not less than 20% water

Zirconium powder, dry 135 2008

Zirconium powder, wetted with 170 1358

not less than 25% water

Zirconium scrap 135 1932

Zirconium sulfate 171 9163

Zirconium sulphate 171 9163

Zirconium suspended in a 170 1308

flammable liquid

Zirconium suspended in a liquid 170 1308

(flammable)

Zirconium tetrachloride 137 2503
NOTES
ERG2004 GUIDE

Page 169

GUIDES
GU ERG2004 IDE

Page 170

MIXED LOAD/UNIDENTIFIED CARGO

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May explode from heat, shock, friction or contamination.

• May react violently or explosively on contact with air, water or foam.

• May be ignited by heat, sparks or flames.

• Vapors may travel to source of ignition and flash back.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Inhalation, ingestion or contact with substance may cause severe injury, infection,

disease or death.

• High concentration of gas may cause asphyxiation without warning.

• Contact may cause burns to skin and eyes.

• Fire or contact with water may produce irritating, toxic and/or corrosive gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it may not be effective in spill situations.

EVACUATION

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

111
ERG2004 GUIDE

Page 171

MIXED LOAD/UNIDENTIFIED CARGO

EMERGENCY RESPONSE

FIRE

CAUTION: Material may react with extinguishing agent.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Cool containers with flooding quantities of water until well after fire is out.

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Prevent entry into waterways, sewers, basements or confined areas.

Small Spills • Take up with sand or other non-combustible absorbent material and place

into containers for later disposal.

Large Spills • Dike far ahead of liquid spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Shower and wash with soap and water.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

111
GU ERG2004 IDE

Page 172

EXPLOSIVES* - DIVISION 1.1, 1.2, 1.3, 1.5 OR

1.6; CLASS A OR B

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE

REACHES CARGO.

• For information on “Compatibility Group” letters, refer to Glossary section.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions.

• Move people out of line of sight of the scene and away from windows.

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for 800 meters (1/2 mile) in all directions.

Fire

• If rail car or trailer is involved in a fire and heavily encased explosives such as bombs or

artillery projectiles are suspected, ISOLATE for 1600 m (1 mile) in all directions; also,

initiate evacuation including emergency responders for 1600 m (1 mile) in all directions.

• When heavily encased explosives are not involved, evacuate the area for 800 meters

(1/2 mile) in all directions.

112

* For information on "Compatibility Group" letters, refer to the Glossary section.
ERG2004 GUIDE

Page 173

EXPLOSIVES* - DIVISION 1.1, 1.2, 1.3, 1.5 OR

1.6; CLASS A OR B

EMERGENCY RESPONSE

FIRE

CARGO Fires

• DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!

• Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let

burn.

• Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE or VEHICLE Fires

• Use plenty of water - FLOOD it! If water is not available, use CO2

, dry chemical or dirt.

• If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC

DETONATORS.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

112

* For information on "Compatibility Group" letters, refer to the Glossary section.
GU ERG2004 IDE

Page 174

 FLAMMABLE SOLIDS - TOXIC

(WET/DESENSITIZED EXPLOSIVE)

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Flammable/combustible material.

• May be ignited by heat, sparks or flames.

• DRIED OUT material may explode if exposed to heat, flame, friction or shock;

Treat as an explosive (GUIDE 112).

• Keep material wet with water or treat as an explosive (GUIDE 112).

• Runoff to sewer may create fire or explosion hazard.

HEALTH

• Some are toxic and may be fatal if inhaled, swallowed or absorbed through skin.

• Contact may cause burns to skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for 500 meters (1/3 mile) in all directions.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

113
ERG2004 GUIDE

Page 175

 FLAMMABLE SOLIDS - TOXIC

(WET/DESENSITIZED EXPLOSIVE)

EMERGENCY RESPONSE

FIRE

CARGO Fires

• DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!

• Stop all traffic and clear the area for at least 800 meters (1/2 mile) in all directions and let

burn.

• Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE or VEHICLE Fires

• Use plenty of water - FLOOD it! If water is not available, use CO2

, dry chemical or dirt.

• If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

Small Spills

• Flush area with flooding quantities of water.

Large Spills

• Wet down with water and dike for later disposal.

• KEEP “WETTED” PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF

WATER.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

113
GU ERG2004 IDE

Page 176

 POTENTIAL HAZARDS

FIRE OR EXPLOSION

• MAY EXPLODE AND THROW FRAGMENTS 500 meters (1/3 MILE) OR MORE IF FIRE

REACHES CARGO.

• For information on “Compatibility Group” letters, refer to Glossary section.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.

• Move people out of line of sight of the scene and away from windows.

• Keep unauthorized personnel away.

• Stay upwind.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for 250 meters (800 feet) in all directions.

Fire

• If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile) in all directions;

also initiate evacuation including emergency responders for 500 meters (1/3 mile) in all

directions.

EXPLOSIVES* - DIVISION 1.4; CLASS C

114

* For information on "Compatibility Group" letters, refer to the Glossary section.
ERG2004 GUIDE

Page 177

EMERGENCY RESPONSE

FIRE

CARGO Fires

• DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!

• Stop all traffic and clear the area for at least 500 meters (1/3 mile) in all directions and let

burn.

• Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE or VEHICLE Fires

• Use plenty of water - FLOOD it! If water is not available, use CO2

, dry chemical or dirt.

• If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from

maximum distance to prevent fire from spreading to cargo area.

• Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC

DETONATORS.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUPPLEMENTAL INFORMATION

• Packages bearing the 1.4S label or packages containing material classified as 1.4S are

designed or packaged in such a manner that when involved in a fire, may burn vigorously

with localized detonations and projection of fragments.

• Effects are usually confined to immediate vicinity of packages.

• If fire threatens cargo area containing packages bearing the 1.4S label or packages

containing material classified as 1.4S, consider isolating at least 15 meters (50 feet) in all

directions. Fight fire with normal precautions from a reasonable distance.

EXPLOSIVES* - DIVISION 1.4; CLASS C

114

* For information on "Compatibility Group" letters, refer to the Glossary section.
GU ERG2004 IDE

Page 178

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• EXTREMELY FLAMMABLE.

• Will be easily ignited by heat, sparks or flames.

• Will form explosive mixtures with air.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

CAUTION: Hydrogen (UN1049), Deuterium (UN1957) and Methane (UN1971) are

lighter than air and will rise. Hydrogen and Deuterium fires are difficult to

detect since they burn with an invisible flame. Use an alternate method of

detection (thermal camera, broom handle, etc.)

• Vapors may travel to source of ignition and flash back.

• Cylinders exposed to fire may vent and release flammable gas through pressure relief

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Some may be irritating if inhaled at high concentrations.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mile).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

GASES - FLAMMABLE

(INCLUDING REFRIGERATED LIQUIDS) 115
ERG2004 GUIDE

Page 179

EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

CAUTION: Hydrogen (UN1049) and Deuterium (UN1957) burn with an invisible

flame.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray or fog.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Do not direct water at spill or source of leak.

• Prevent spreading of vapors through sewers, ventilation systems and confined areas.

• Isolate area until gas has dispersed.

CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become

brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Clothing frozen to the skin should be thawed before being removed.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin. • Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - FLAMMABLE

(INCLUDING REFRIGERATED LIQUIDS) 115
GU ERG2004 IDE

Page 180

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• EXTREMELY FLAMMABLE.

• Will be easily ignited by heat, sparks or flames.

• Will form explosive mixtures with air.

• Silane will ignite spontaneously in air.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Vapors may travel to source of ignition and flash back.

• Cylinders exposed to fire may vent and release flammable gas through pressure relief

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Some may be toxic if inhaled at high concentrations.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mile).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

GASES - FLAMMABLE (UNSTABLE)

116
ERG2004 GUIDE

Page 181

EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray or fog.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Stop leak if you can do it without risk.

• Do not touch or walk through spilled material.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - FLAMMABLE (UNSTABLE)

116
GU ERG2004 IDE

Page 182

POTENTIAL HAZARDS

HEALTH

• TOXIC; Extremely Hazardous.

• May be fatal if inhaled or absorbed through skin.

• Initial odor may be irritating or foul and may deaden your sense of smell.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• These materials are extremely flammable.

• May form explosive mixtures with air.

• May be ignited by heat, sparks or flames.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Vapors may travel to source of ignition and flash back.

• Runoff may create fire or explosion hazard.

• Cylinders exposed to fire may vent and release toxic and flammable gas through

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

GASES - TOXIC - FLAMMABLE (EXTREME HAZARD)

117
ERG2004 GUIDE

Page 183

EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with

no fire. • Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material. • Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

• Consider igniting spill or leak to eliminate toxic gas concerns.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - TOXIC - FLAMMABLE (EXTREME HAZARD)

117
GU ERG2004 IDE

Page 184

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• EXTREMELY FLAMMABLE.

• May be ignited by heat, sparks or flames.

• May form explosive mixtures with air.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Vapors may travel to source of ignition and flash back.

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release flammable gas through pressure relief

devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• May cause toxic effects if inhaled.

• Vapors are extremely irritating.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas. • Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 800 meters (1/2 mile).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

 GASES - FLAMMABLE - CORROSIVE

118
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EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Do not direct water at spill or source of leak.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 GASES - FLAMMABLE - CORROSIVE

118
GU ERG2004 IDE

Page 186

POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled or absorbed through skin.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• Flammable; may be ignited by heat, sparks or flames.

• May form explosive mixtures with air.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Vapors may travel to source of ignition and flash back.

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release toxic and flammable gas through

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

• Runoff may create fire or explosion hazard.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away. • Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas. • Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

GASES - TOXIC - FLAMMABLE

119
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EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fires

• Dry chemical, CO2

, water spray or alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium

expansion foam. • Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank. • ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce

vapors.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - TOXIC - FLAMMABLE

119
GU ERG2004 IDE

Page 188

POTENTIAL HAZARDS

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

FIRE OR EXPLOSION

• Non-flammable gases.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids or

solids.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - INERT

120 (INCLUDING REFRIGERATED LIQUIDS)
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EMERGENCY RESPONSE

FIRE

• Use extinguishing agent suitable for type of surrounding fire.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Allow substance to evaporate.

• Ventilate the area.

CAUTION: When in contact with refrigerated/cryogenic liquids, many materials

become brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being removed.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - INERT

(INCLUDING REFRIGERATED LIQUIDS) 120
GU ERG2004 IDE

Page 190

POTENTIAL HAZARDS

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

FIRE OR EXPLOSION

• Non-flammable gases.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - INERT

121
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EMERGENCY RESPONSE

FIRE

• Use extinguishing agent suitable for type of surrounding fire.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Allow substance to evaporate.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - INERT

121
GU ERG2004 IDE

Page 192

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Substance does not burn but will support combustion.

• Some may react explosively with fuels.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Runoff may create fire or explosion hazard.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 500 meters (1/3 mile).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - OXIDIZING

122 (INCLUDING REFRIGERATED LIQUIDS)
ERG2004 GUIDE

Page 193

EMERGENCY RESPONSE

FIRE

• Use extinguishing agent suitable for type of surrounding fire.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined areas.

• Allow substance to evaporate.

• Isolate area until gas has dispersed.

CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become

brittle and are likely to break without warning.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Clothing frozen to the skin should be thawed before being removed.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - OXIDIZING

(INCLUDING REFRIGERATED LIQUIDS) 122
GU ERG2004 IDE

Page 194

POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled or absorbed through skin.

• Vapors may be irritating.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• Some may burn, but none ignite readily.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - TOXIC AND/OR CORROSIVE

123
ERG2004 GUIDE

Page 195

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Do not get water inside containers.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Do not direct water at spill or source of leak.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - TOXIC AND/OR CORROSIVE

123
GU ERG2004 IDE

Page 196

POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled or absorbed through skin.

• Fire will produce irritating, corrosive and/or toxic gases.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• Substance does not burn but will support combustion.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• These are strong oxidizers and will react vigorously or explosively with many materials

including fuels.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Some will react violently with air, moist air and/or water.

• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - TOXIC AND/OR CORROSIVE - OXIDIZING

124
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EMERGENCY RESPONSE

FIRE

Small Fires: Water only; no dry chemical, CO2 or Halon ® .

• Contain fire and let burn. If fire must be fought, water spray or fog is recommended.

• Do not get water inside containers.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no

fire.

• Do not touch or walk through spilled material.

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being removed.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - TOXIC AND/OR CORROSIVE - OXIDIZING

124
GU ERG2004 IDE

Page 198

POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.

• Vapors are extremely irritating and corrosive.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• Some may burn, but none ignite readily.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Some of these materials may react violently with water.

• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through

pressure relief devices.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

GASES - CORROSIVE

125
ERG2004 GUIDE

Page 199

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Do not get water inside containers.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank. • ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material. • Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• In case of contact with Hydrogen fluoride, anhydrous (UN1052), flush skin and

eyes with water for 5 minutes; then, for skin exposures rub on a calcium/jelly

combination; for eyes flush with a water/calcium solution for 15 minutes.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - CORROSIVE

125
GU ERG2004 IDE

Page 200

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Some may burn, but none ignite readily.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

HEALTH

• Vapors may cause dizziness or asphyxiation without warning.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Fire may produce irritating, corrosive and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 500 meters (1/3 mile).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

GASES - COMPRESSED OR LIQUEFIED

126 (INCLUDING REFRIGERANT GASES)
ERG2004 GUIDE

Page 201

EMERGENCY RESPONSE

FIRE

• Use extinguishing agent suitable for type of surrounding fire.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Damaged cylinders should be handled only by specialists.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• Some of these materials, if spilled, may evaporate leaving a flammable residue.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Do not direct water at spill or source of leak.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Allow substance to evaporate.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

GASES - COMPRESSED OR LIQUEFIED

(INCLUDING REFRIGERANT GASES) 126
GU ERG2004 IDE

Page 202

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

FLAMMABLE LIQUIDS

127 (POLAR/WATER-MISCIBLE)
ERG2004 GUIDE

Page 203

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray when

fighting fire may be inefficient.

Small Fires

• Dry chemical, CO2

, water spray or alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes. • Wash skin with soap and water.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 FLAMMABLE LIQUIDS

(POLAR/WATER-MISCIBLE) 127
GU ERG2004 IDE

Page 204

 POTENTIAL HAZARDS

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

• Substance may be transported hot.

• If molten aluminum is involved, refer to GUIDE 169.

HEALTH

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire may produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

FLAMMABLE LIQUIDS

128 (NON-POLAR/WATER-IMMISCIBLE)
ERG2004 GUIDE

Page 205

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray when

fighting fire may be inefficient.

CAUTION: For mixtures containing a high percentage of an alcohol or polar

solvent, alcohol-resistant foam may be more effective.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers. • Use clean non-sparking tools to collect absorbed material.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Wash skin with soap and water. • Keep victim warm and quiet.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

FLAMMABLE LIQUIDS

(NON-POLAR/WATER-IMMISCIBLE) 128
GU ERG2004 IDE

Page 206

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or absorbed through skin.

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 FLAMMABLE LIQUIDS

129 (POLAR/WATER-MISCIBLE/NOXIOUS)
ERG2004 GUIDE

Page 207

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray when

fighting fire may be inefficient.

Small Fires • Dry chemical, CO2

, water spray or alcohol-resistant foam.

• Do not use dry chemical extinguishers to control fires involving nitromethane or

nitroethane.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• Do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spills • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Wash skin with soap and water. • Keep victim warm and quiet.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 FLAMMABLE LIQUIDS

(POLAR/WATER-MISCIBLE/NOXIOUS) 129
GU ERG2004 IDE

Page 208

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or absorbed through skin.

• Inhalation or contact with material may irritate or burn skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 300 meters (1000 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

FLAMMABLE LIQUIDS

130 (NON-POLAR/WATER-IMMISCIBLE/NOXIOUS)
ERG2004 GUIDE

Page 209

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray when

fighting fire may be inefficient.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Do not use straight streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• Use clean non-sparking tools to collect absorbed material.

Large Spills • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Wash skin with soap and water. • Keep victim warm and quiet.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

FLAMMABLE LIQUIDS

(NON-POLAR/WATER-IMMISCIBLE/NOXIOUS) 130
GU ERG2004 IDE

Page 210

POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.

• Inhalation or contact with some of these materials will irritate or burn skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under "PUBLIC SAFETY".

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 FLAMMABLE LIQUIDS - TOXIC

131
ERG2004 GUIDE

Page 211

EMERGENCY RESPONSE

FIRE

CAUTION: All these products have a very low flash point: Use of water spray when

fighting fire may be inefficient.

Small Fires • Dry chemical, CO2

, water spray or alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no

fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

Small Spills • Absorb with earth, sand or other non-combustible material and

transfer to containers for later disposal.

• Use clean non-sparking tools to collect absorbed material.

Large Spills • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Wash skin with soap and water. • Keep victim warm and quiet.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 FLAMMABLE LIQUIDS - TOXIC

131
GU ERG2004 IDE

Page 212

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Flammable/combustible materials.

• May be ignited by heat, sparks or flames.

• Vapors may form explosive mixtures with air.

• Vapors may travel to source of ignition and flash back.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapor explosion hazard indoors, outdoors or in sewers.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Runoff to sewer may create fire or explosion hazard.

• Containers may explode when heated.

• Many liquids are lighter than water.

HEALTH

• May cause toxic effects if inhaled or ingested/swallowed.

• Contact with substance may cause severe burns to skin and eyes.

• Fire will produce irritating, corrosive and/or toxic gases.

• Vapors may cause dizziness or suffocation.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 FLAMMABLE LIQUIDS - CORROSIVE

132
ERG2004 GUIDE

Page 213

EMERGENCY RESPONSE

FIRE

• Some of these materials may react violently with water.

Small Fires • Dry chemical, CO2

, water spray or alcohol-resistant foam.

Large Fires • Water spray, fog or alcohol-resistant foam.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

• Do not get water inside containers.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no

fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch or walk through spilled material. • Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• A vapor suppressing foam may be used to reduce vapors.

• Absorb with earth, sand or other non-combustible material and transfer to

containers (except for Hydrazine).

• Use clean non-sparking tools to collect absorbed material.

Large Spills • Dike far ahead of liquid spill for later disposal.

• Water spray may reduce vapor; but may not prevent ignition in closed spaces.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• In case of burns, immediately cool affected skin for as long as possible with cold water.

Do not remove clothing if adhering to skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 FLAMMABLE LIQUIDS - CORROSIVE

132
GU ERG2004 IDE

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Flammable/combustible material.

• May be ignited by friction, heat, sparks or flames.

• Some may burn rapidly with flare burning effect.

• Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with

explosive violence.

• Substance may be transported in a molten form at a temperature that may be above its

flash point.

• May re-ignite after fire is extinguished.

HEALTH

• Fire may produce irritating and/or toxic gases.

• Contact may cause burns to skin and eyes.

• Contact with molten substance may cause severe burns to skin and eyes.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

FLAMMABLE SOLIDS

133
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EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

, sand, earth, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Cool containers with flooding quantities of water until well after fire is out.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

Small Dry Spills

• With clean shovel place material into clean, dry container and cover loosely; move

containers from spill area.

Large Spills

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Removal of solidified molten material from skin requires medical assistance.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

FLAMMABLE SOLIDS

133
GU ERG2004 IDE

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Flammable/combustible material.

• May be ignited by heat, sparks or flames.

• When heated, vapors may form explosive mixtures with air: indoors, outdoors and

sewers explosion hazards.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated.

HEALTH

• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or

death.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause

pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 FLAMMABLE SOLIDS - TOXIC AND/OR CORROSIVE

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EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

, water spray or alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

• Do not get water inside containers.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Stop leak if you can do it without risk.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Prevent entry into waterways, sewers, basements or confined areas.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 FLAMMABLE SOLIDS - TOXIC AND/OR CORROSIVE

134
GU ERG2004 IDE

Page 218

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Flammable/combustible material.

• May ignite on contact with moist air or moisture.

• May burn rapidly with flare-burning effect.

• Some react vigorously or explosively on contact with water.

• Some may decompose explosively when heated or involved in a fire.

• May re-ignite after fire is extinguished.

• Runoff may create fire or explosion hazard.

• Containers may explode when heated.

HEALTH

• Fire will produce irritating, corrosive and/or toxic gases.

• Inhalation of decomposition products may cause severe injury or death.

• Contact with substance may cause severe burns to skin and eyes.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE

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EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER, CO2 OR FOAM ON MATERIAL ITSELF.

• Some of these materials may react violently with water.

EXCEPTION: For Xanthates, UN3342 and for Dithionite (Hydrosulfite/

Hydrosulphite) UN1384, UN1923 and UN1929, USE FLOODING AMOUNTS OF

WATER for SMALL AND LARGE fires to stop the reaction. Smothering will not

work for these materials, they do not need air to burn.

Small Fires

• Dry chemical, soda ash, lime or DRY sand, EXCEPT for UN1384, UN1923 and UN1929.

Large Fires

• DRY sand, dry chemical, soda ash or lime, EXCEPT for UN1384, UN1923 and UN1929,

or withdraw from area and let fire burn.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers or in contact with substance.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leak with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material. • Stop leak if you can do it without risk.

Small Spills

EXCEPTION: For spills of Xanthates, UN3342 and for Dithionite (Hydrosulfite/

Hydrosulphite), UN1384, UN1923 and UN1929, dissolve in 5 parts water and

collect for proper disposal.

• Cover with DRY earth, DRY sand or other non-combustible material followed with plastic

sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes. • Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE

135
GU ERG2004 IDE

Page 220

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Extremely flammable; will ignite itself if exposed to air.

• Burns rapidly, releasing dense, white, irritating fumes.

• Substance may be transported in a molten form.

• May re-ignite after fire is extinguished.

• Corrosive substances in contact with metals may produce flammable hydrogen gas.

• Containers may explode when heated.

HEALTH

• Fire will produce irritating, corrosive and/or toxic gases.

• TOXIC; ingestion of substance or inhalation of decomposition products will cause severe

injury or death.

• Contact with substance may cause severe burns to skin and eyes.

• Some effects may be experienced due to skin absorption.

• Runoff from fire control may be corrosive and/or toxic and cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Stay upwind.

• Keep unauthorized personnel away.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

• For Phosphorus (UN1381): Special aluminized protective clothing should be

worn when direct contact with the substance is possible.

EVACUATION

Spill

• Consider initial downwind evacuation for at least 300 meters (1000 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE -

136 TOXIC AND/OR CORROSIVE (AIR-REACTIVE)
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EMERGENCY RESPONSE

FIRE

Small Fires

• Water spray, wet sand or wet earth.

Large Fires

• Water spray or fog.

• Do not scatter spilled material with high pressure water streams.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Do not touch damaged containers or spilled material unless wearing appropriate

protective clothing.

• Stop leak if you can do it without risk.

Small Spills

• Cover with water, sand or earth. Shovel into metal container and keep material under

water.

Large Spills

• Dike for later disposal and cover with wet sand or earth.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, keep exposed skin areas immersed in water or

covered with wet bandages until medical attention is received.

• Removal of solidified molten material from skin requires medical assistance.

• Remove and isolate contaminated clothing and shoes at the site and place in metal

container filled with water. Fire hazard if allowed to dry.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE -

TOXIC AND/OR CORROSIVE (AIR-REACTIVE) 136
GU ERG2004 IDE

Page 222

POTENTIAL HAZARDS

HEALTH

• CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors,

dusts or substance may cause severe injury, burns or death.

• Fire will produce irritating, corrosive and/or toxic gases.

• Reaction with water may generate much heat which will increase the concentration of

fumes in the air.

• Contact with molten substance may cause severe burns to skin and eyes.

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these

materials may burn, but none ignite readily.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Substance will react with water (some violently), releasing corrosive and/or toxic

gases.

• Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/

tank cars etc.)

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES - WATER-REACTIVE - CORROSIVE

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EMERGENCY RESPONSE

FIRE

• When material is not involved in fire: do not use water on material itself.

Small Fires

• Dry chemical or CO2.

• Move containers from fire area if you can do it without risk.

Large Fires

• Flood fire area with large quantities of water, while knocking down vapors with water

fog. If insufficient water supply: knock down vapors only.

Fire involving Tanks or Car/Trailer Loads

• Cool containers with flooding quantities of water until well after fire is out.

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.

• Do not touch damaged containers or spilled material unless wearing appropriate

protective clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors; do not put water directly on leak, spill area or inside

container.

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Removal of solidified molten material from skin requires medical assistance.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES - WATER-REACTIVE - CORROSIVE

137
GU ERG2004 IDE

Page 224

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Produce flammable gases on contact with water.

• May ignite on contact with water or moist air.

• Some react vigorously or explosively on contact with water.

• May be ignited by heat, sparks or flames.

• May re-ignite after fire is extinguished.

• Some are transported in highly flammable liquids.

• Runoff may create fire or explosion hazard.

HEALTH

• Inhalation or contact with vapors, substance or decomposition products may cause

severe injury or death.

• May produce corrosive solutions on contact with water.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate the area before entry.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under "PUBLIC SAFETY".

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - WATER-REACTIVE

138 (EMITTING FLAMMABLE GASES)
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EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER OR FOAM.

Small Fires

• Dry chemical, soda ash, lime or sand.

Large Fires

• DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.

• Move containers from fire area if you can do it without risk.

Magnesium Fires

• DRY sand, sodium chloride powder, graphite powder or Met-L-X® powder.

Lithium Fires

• DRY sand, sodium chloride powder, graphite powder, copper powder or Lith-X® powder.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• DO NOT GET WATER on spilled substance or inside containers.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Dike for later disposal; do not apply water unless directed to do so.

Powder Spills • Cover powder spill with plastic sheet or tarp to minimize

spreading and keep powder dry.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, wipe from skin immediately; flush skin or eyes with

running water for at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - WATER-REACTIVE

(EMITTING FLAMMABLE GASES) 138
GU ERG2004 IDE

Page 226

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Produce flammable and toxic gases on contact with water.

• May ignite on contact with water or moist air.

• Some react vigorously or explosively on contact with water.

• May be ignited by heat, sparks or flames.

• May re-ignite after fire is extinguished.

• Some are transported in highly flammable liquids.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Highly toxic: contact with water produces toxic gas, may be fatal if inhaled.

• Inhalation or contact with vapors, substance or decomposition products may cause

severe injury or death.

• May produce corrosive solutions on contact with water.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate the area before entry.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - WATER-REACTIVE

139 (EMITTING FLAMMABLE AND TOXIC GASES)
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EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER OR FOAM. (FOAM MAY BE USED FOR CHLOROSILANES, SEE BELOW)

Small Fires

• Dry chemical, soda ash, lime or sand.

Large Fires

• DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.

• FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium

expansion foam; DO NOT USE dry chemicals, soda ash or lime on chlorosilane fires

(large or small) as they may release large quantities of hydrogen gas that may explode.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not get water inside containers.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• DO NOT GET WATER on spilled substance or inside containers.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce

vapors.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Dike for later disposal; do not apply water unless directed to do so.

Powder Spills • Cover powder spill with plastic sheet or tarp to minimize

spreading and keep powder dry.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, wipe from skin immediately; flush skin or eyes with

running water for at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take precautions

to protect themselves.

SUBSTANCES - WATER-REACTIVE

(EMITTING FLAMMABLE AND TOXIC GASES) 139
GU ERG2004 IDE

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• These substances will accelerate burning when involved in a fire.

• Some may decompose explosively when heated or involved in a fire.

• May explode from heat or contamination.

• Some will react explosively with hydrocarbons (fuels).

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe

injury, burns or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

OXIDIZERS

140
ERG2004 GUIDE

Page 229

EMERGENCY RESPONSE

FIRE

Small Fires

• Use water. Do not use dry chemicals or foams. CO2

 or Halon® may provide limited

control.

Large Fires

• Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Do not get water inside containers.

Small Dry Spills

• With clean shovel place material into clean, dry container and cover loosely; move

containers from spill area.

Small Liquid Spills

• Use a non-combustible material like vermiculite or sand to soak up the product and place

into a container for later disposal.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Following product recovery, flush area with water.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

OXIDIZERS

140
GU ERG2004 IDE

Page 230

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• These substances will accelerate burning when involved in a fire.

• May explode from heat or contamination.

• Some may burn rapidly.

• Some will react explosively with hydrocarbons (fuels).

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Toxic by ingestion.

• Inhalation of dust is toxic.

• Fire may produce irritating, corrosive and/or toxic gases.

• Contact with substance may cause severe burns to skin and eyes.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

OXIDIZERS - TOXIC

141
ERG2004 GUIDE

Page 231

EMERGENCY RESPONSE

FIRE

Small Fires

• Use water. Do not use dry chemicals or foams. CO2

 or Halon® may provide limited

control.

Large Fires

• Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

Small Dry Spills

• With clean shovel place material into clean, dry container and cover loosely; move

containers from spill area.

Large Spills

• Dike far ahead of spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

OXIDIZERS - TOXIC

141
GU ERG2004 IDE

Page 232

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• These substances will accelerate burning when involved in a fire.

• May explode from heat or contamination.

• Some will react explosively with hydrocarbons (fuels).

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors or substance may

cause severe injury, burns or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Toxic/flammable fumes may accumulate in confined areas (basement, tanks, tank cars,

etc.).

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

OXIDIZERS - TOXIC (LIQUID)

142
ERG2004 GUIDE

Page 233

EMERGENCY RESPONSE

FIRE

Small Fires

• Use water. Do not use dry chemicals or foams. CO2

 or Halon® may provide limited

control.

Large Fires

• Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Fully encapsulating, vapor protective clothing should be worn for spills and

leaks with no fire.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift.

• Do not get water inside containers.

Small Liquid Spills

• Use a non-combustible material like vermiculite or sand to soak up the product and place

into a container for later disposal.

Large Spills

• Dike far ahead of liquid spill for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

OXIDIZERS - TOXIC (LIQUID)

142
GU ERG2004 IDE

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May explode from friction, heat or contamination.

• These substances will accelerate burning when involved in a fire.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Some will react explosively with hydrocarbons (fuels).

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance

may cause severe injury, burns or death.

• Fire may produce irritating and/or toxic gases.

• Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank

cars, etc.).

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

OXIDIZERS (UNSTABLE)

143
ERG2004 GUIDE

Page 235

EMERGENCY RESPONSE

FIRE

Small Fires

• Use water. Do not use dry chemicals or foams. CO2

 or Halon® may provide limited

control.

Large Fires

• Flood fire area with water from a distance.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Move containers from fire area if you can do it without risk.

• Do not get water inside containers: a violent reaction may occur.

• Cool containers with flooding quantities of water until well after fire is out.

• Dike fire-control water for later disposal.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Use water spray to reduce vapors or divert vapor cloud drift.

• Prevent entry into waterways, sewers, basements or confined areas.

Small Spills

• Flush area with flooding quantities of water.

Large Spills

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

OXIDIZERS (UNSTABLE)

143
GU ERG2004 IDE

Page 236

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• React vigorously and/or explosively with water.

• Produce toxic and/or corrosive substances on contact with water.

• Flammable/toxic gases may accumulate in tanks and hopper cars.

• Some may produce flammable hydrogen gas upon contact with metals.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• TOXIC; inhalation or contact with vapor, substance, or decomposition products may

cause severe injury or death.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 OXIDIZERS (WATER-REACTIVE)

144
ERG2004 GUIDE

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EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER OR FOAM.

Small Fires

• Dry chemical, soda ash or lime.

Large Fires

• DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• DO NOT GET WATER on spilled substance or inside containers.

Small Spills

• Cover with DRY earth, DRY sand or other non-combustible material followed with plastic

sheet to minimize spreading or contact with rain.

Large Spills

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 OXIDIZERS (WATER-REACTIVE)

144
GU ERG2004 IDE

Page 238

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May explode from heat or contamination.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• May be ignited by heat, sparks or flames.

• May burn rapidly with flare-burning effect.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injury or burns.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

ORGANIC PEROXIDES

145 (HEAT AND CONTAMINATION SENSITIVE)
ERG2004 GUIDE

Page 239

EMERGENCY RESPONSE

FIRE

Small Fires

• Water spray or fog is preferred; if water not available use dry chemical, CO2

 or regular

foam.

Large Fires

• Flood fire area with water from a distance.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Keep substance wet using water spray.

• Stop leak if you can do it without risk.

Small Spills

• Take up with inert, damp, non-combustible material using clean non-sparking tools and

place into loosely covered plastic containers for later disposal.

Large Spills

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

ORGANIC PEROXIDES

(HEAT AND CONTAMINATION SENSITIVE) 145
GU ERG2004 IDE

Page 240

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May explode from heat, shock, friction or contamination.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• May be ignited by heat, sparks or flames.

• May burn rapidly with flare-burning effect.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injury or burns.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

ORGANIC PEROXIDES (HEAT, CONTAMINATION

146 AND FRICTION SENSITIVE)
ERG2004 GUIDE

Page 241

EMERGENCY RESPONSE

FIRE

Small Fires

• Water spray or fog is preferred; if water not available use dry chemical, CO2

 or regular

foam.

Large Fires

• Flood fire area with water from a distance.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Keep substance wet using water spray.

• Stop leak if you can do it without risk.

Small Spills

• Take up with inert, damp, non-combustible material using clean non-sparking tools and

place into loosely covered plastic containers for later disposal.

Large Spills

• Wet down with water and dike for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

ORGANIC PEROXIDES (HEAT, CONTAMINATION AND

FRICTION SENSITIVE) 146
GU ERG2004 IDE

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147

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ERG2004 GUIDE

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Page 244

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May explode from heat, contamination or loss of temperature control.

• These materials are particularly sensitive to temperature rises. Above a given “Control

Temperature” they decompose violently and catch fire.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• May ignite spontaneously if exposed to air.

• May be ignited by heat, sparks or flames.

• May burn rapidly with flare-burning effect.

• Containers may explode when heated.

• Runoff may create fire or explosion hazard.

HEALTH

• Fire may produce irritating, corrosive and/or toxic gases.

• Ingestion or contact (skin, eyes) with substance may cause severe injury or burns.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• DO NOT allow the substance to warm up. Obtain liquid nitrogen, dry ice or ice for

cooling. If none can be obtained, evacuate the area immediately.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

ORGANIC PEROXIDES (HEAT AND CONTAMINATION

148 SENSITIVE/TEMPERATURE CONTROLLED)
ERG2004 GUIDE

Page 245

EMERGENCY RESPONSE

FIRE

• The temperature of the substance must be maintained at or below the “Control

Temperature” at all times.

Small Fires

• Water spray or fog is preferred; if water not available use dry chemical, CO2

 or regular foam.

Large Fires

• Flood fire area with water from a distance.

• Use water spray or fog; do not use straight streams.

• Move containers from fire area if you can do it without risk.

• Do not move cargo or vehicle if cargo has been exposed to heat.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spills

• Take up with inert, damp, non-combustible material using clean non-sparking tools and

place into loosely covered plastic containers for later disposal.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• Contaminated clothing may be a fire risk when dry.

• Remove material from skin immediately.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

ORGANIC PEROXIDES (HEAT AND CONTAMINATION

SENSITIVE/TEMPERATURE CONTROLLED) 148
GU ERG2004 IDE

Page 246

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Self-decomposition or self-ignition may be triggered by heat, chemical reaction,

friction or impact.

• May be ignited by heat, sparks or flames.

• Some may decompose explosively when heated or involved in a fire.

• May burn violently. Decomposition may be self-accelerating and produce

large amounts of gases.

• Vapors or dust may form explosive mixtures with air.

HEALTH

• Inhalation or contact with vapors, substance or decomposition products may cause

severe injury or death.

• May produce irritating, toxic and/or corrosive gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES (SELF-REACTIVE)

149
ERG2004 GUIDE

Page 247

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spills

• Take up with inert, damp, non-combustible material using clean non-sparking tools and

place into loosely covered plastic containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES (SELF-REACTIVE)

149
GU ERG2004 IDE

Page 248

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Self-decomposition or self-ignition may be triggered by heat, chemical reaction,

friction or impact.

• Self-accelerating decomposition may occur if the specific control temperature is not

maintained.

• These materials are particularly sensitive to temperature rises. Above a given “Control

Temperature” they decompose violently and catch fire.

• May be ignited by heat, sparks or flames.

• Some may decompose explosively when heated or involved in a fire.

• May burn violently. Decomposition may be self-accelerating and produce

large amounts of gases.

• Vapors or dust may form explosive mixtures with air.

HEALTH

• Inhalation or contact with vapors, substance or decomposition products may cause

severe injury or death.

• May produce irritating, toxic and/or corrosive gases.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• DO NOT allow the substance to warm up. Obtain liquid nitrogen, dry ice or ice for

cooling. If none can be obtained, evacuate the area immediately.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 250 meters (800 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES (SELF-REACTIVE/

150 TEMPERATURE CONTROLLED)
ERG2004 GUIDE

Page 249

EMERGENCY RESPONSE

FIRE

• The temperature of the substance must be maintained at or below the “Control

Temperature” at all times.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Flood fire area with water from a distance.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• BEWARE OF POSSIBLE CONTAINER EXPLOSION.

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

Small Spills

• Take up with inert, damp, non-combustible material using clean non-sparking tools and

place into loosely covered plastic containers for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES (SELF-REACTIVE/

TEMPERATURE CONTROLLED) 150
GU ERG2004 IDE

Page 250

POTENTIAL HAZARDS

HEALTH

• Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin.

• Avoid any skin contact.

• Effects of contact or inhalation may be delayed.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause

pollution.

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose upon heating to

produce corrosive and/or toxic fumes.

• Containers may explode when heated.

• Runoff may pollute waterways.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - TOXIC (NON-COMBUSTIBLE)

151
ERG2004 GUIDE

Page 251

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• Cover with plastic sheet to prevent spreading.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - TOXIC (NON-COMBUSTIBLE)

151
GU ERG2004 IDE

Page 252

POTENTIAL HAZARDS

HEALTH

• Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin.

• Contact with molten substance may cause severe burns to skin and eyes.

• Avoid any skin contact.

• Effects of contact or inhalation may be delayed.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause

pollution.

FIRE OR EXPLOSION

• Combustible material: may burn but does not ignite readily.

• Containers may explode when heated.

• Runoff may pollute waterways.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - TOXIC (COMBUSTIBLE)

152
ERG2004 GUIDE

Page 253

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch damaged containers or spilled material unless wearing appropriate

protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• Cover with plastic sheet to prevent spreading.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - TOXIC (COMBUSTIBLE)

152
GU ERG2004 IDE

Page 254

POTENTIAL HAZARDS

HEALTH

• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or

death.

• Contact with molten substance may cause severe burns to skin and eyes.

• Avoid any skin contact.

• Effects of contact or inhalation may be delayed.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause

pollution.

FIRE OR EXPLOSION

• Combustible material: may burn but does not ignite readily.

• When heated, vapors may form explosive mixtures with air: indoors, outdoors and

sewers explosion hazards.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated.

• Runoff may pollute waterways.

• Substance may be transported in a molten form.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES - TOXIC AND/OR CORROSIVE

153 (COMBUSTIBLE)
ERG2004 GUIDE

Page 255

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Dry chemical, CO2

, alcohol-resistant foam or water spray.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES - TOXIC AND/OR CORROSIVE

(COMBUSTIBLE) 153
GU ERG2004 IDE

Page 256

POTENTIAL HAZARDS

HEALTH

• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or

death.

• Contact with molten substance may cause severe burns to skin and eyes.

• Avoid any skin contact.

• Effects of contact or inhalation may be delayed.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause

pollution.

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose upon heating to

produce corrosive and/or toxic fumes.

• Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.).

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

154 (NON-COMBUSTIBLE)
ERG2004 GUIDE

Page 257

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Dry chemical, CO2

, alcohol-resistant foam or water spray.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• Absorb or cover with dry earth, sand or other non-combustible material and

transfer to containers.

• DO NOT GET WATER INSIDE CONTAINERS.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

(NON-COMBUSTIBLE) 154
GU ERG2004 IDE

Page 258

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

• Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapors may travel to source of ignition and flash back.

• Those substances designated with a "P" may polymerize explosively when heated or

involved in a fire.

• Substance will react with water (some violently) releasing flammable, toxic or corrosive

gases and runoff.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance

may cause severe injury, burns or death.

• Bromoacetates and chloroacetates are extremely irritating/lachrymators.

• Reaction with water or moist air will release toxic, corrosive or flammable gases.

• Reaction with water may generate much heat which will increase the concentration of

fumes in the air.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

155 (FLAMMABLE/WATER-SENSITIVE)
ERG2004 GUIDE

Page 259

EMERGENCY RESPONSE

FIRE

• Note: Most foams will react with the material and release corrosive/toxic gases.

CAUTION: For Acetyl chloride (UN1717), use CO2

 or dry chemical only.

Small Fires • CO2

, dry chemical, dry sand, alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium

expansion foam.

• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to

reduce vapors.

• DO NOT GET WATER on spilled substance or inside containers.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Prevent entry into waterways, sewers, basements or confined areas.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

(FLAMMABLE/WATER-SENSITIVE) 155
GU ERG2004 IDE

Page 260

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Combustible material: may burn but does not ignite readily.

• Substance will react with water (some violently) releasing flammable, toxic or corrosive

gases and runoff.

• When heated, vapors may form explosive mixtures with air: indoors, outdoors and

sewers explosion hazards.

• Most vapors are heavier than air. They will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Vapors may travel to source of ignition and flash back.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance

may cause severe injury, burns or death.

• Contact with molten substance may cause severe burns to skin and eyes.

• Reaction with water or moist air will release toxic, corrosive or flammable gases.

• Reaction with water may generate much heat which will increase the concentration of

fumes in the air.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind. • Keep out of low areas. • Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

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EMERGENCY RESPONSE

FIRE

• Note: Most foams will react with the material and release corrosive/toxic gases.

Small Fires • CO2

, dry chemical, dry sand, alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium

expansion foam.

• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to

reduce vapors.

• DO NOT GET WATER on spilled substance or inside containers.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• Prevent entry into waterways, sewers, basements or confined areas.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

(COMBUSTIBLE/WATER-SENSITIVE) 156
GU ERG2004 IDE

Page 262

POTENTIAL HAZARDS

HEALTH

• TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance

may cause severe injury, burns or death.

• Reaction with water or moist air will release toxic, corrosive or flammable gases.

• Reaction with water may generate much heat that will increase the concentration of

fumes in the air.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may decompose upon heating to

produce corrosive and/or toxic fumes.

• Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.).

• Substance will react with water (some violently), releasing corrosive and/or toxic

gases.

• Contact with metals may evolve flammable hydrogen gas.

• Containers may explode when heated or if contaminated with water.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate enclosed areas.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

157 (NON-COMBUSTIBLE/WATER-SENSITIVE)
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EMERGENCY RESPONSE

FIRE

• Note: Most foams will react with the material and release corrosive/toxic gases.

Small Fires • CO2

 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam.

Large Fires

• Water spray, fog or alcohol-resistant foam.

• Move containers from fire area if you can do it without risk.

• Use water spray or fog; do not use straight streams.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• A vapor suppressing foam may be used to reduce vapors.

• DO NOT GET WATER INSIDE CONTAINERS.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Prevent entry into waterways, sewers, basements or confined areas.

Small Spills • Cover with DRY earth, DRY sand or other non-combustible material

followed with plastic sheet to minimize spreading or contact with rain.

• Use clean non-sparking tools to collect material and place it into loosely covered plastic

containers for later disposal.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES - TOXIC AND/OR CORROSIVE

(NON-COMBUSTIBLE/WATER-SENSITIVE) 157
GU ERG2004 IDE

Page 264

POTENTIAL HAZARDS

HEALTH

• Inhalation or contact with substance may cause infection, disease or death.

• Runoff from fire control may cause pollution.

• Note: Damaged packages containing solid CO2

 as a refrigerant may produce

water or frost from condensation of air. Do not touch this liquid as it could be

contaminated by the contents of the parcel.

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Some may be transported in flammable liquids.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Obtain identity of substance involved.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

INFECTIOUS SUBSTANCES

158
ERG2004 GUIDE

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EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, soda ash, lime or sand.

Large Fires

• Use extinguishing agent suitable for type of surrounding fire.

• Move containers from fire area if you can do it without risk.

• Do not scatter spilled material with high pressure water streams.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Absorb with earth, sand or other non-combustible material.

• Cover damaged package or spilled material with damp towel or rag and keep

wet with liquid bleach or other disinfectant.

• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A

SPECIALIST.

FIRST AID

• Move victim to a safe isolated area.

CAUTION: Victim may be a source of contamination.

• Call 911 or emergency medical service.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for at

least 20 minutes.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• For further assistance, contact your local Poison Control Center.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

INFECTIOUS SUBSTANCES

158
GU ERG2004 IDE

Page 266

POTENTIAL HAZARDS

HEALTH

• Inhalation of vapors or dust is extremely irritating.

• May cause burning of eyes and flow of tears.

• May cause coughing, difficult breathing and nausea.

• Brief exposure effects last only a few minutes.

• Exposure in an enclosed area may be very harmful.

• Fire will produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Containers may explode when heated.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under "PUBLIC SAFETY".

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

SUBSTANCES (IRRITATING)

159
ERG2004 GUIDE

Page 267

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Do not get water inside containers.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.

Small Spills

• Take up with sand or other non-combustible absorbent material and place into

containers for later disposal.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Do not use mouth-to-mouth method if victim ingested or inhaled the substance;

give artificial respiration with the aid of a pocket mask equipped with a one-way

valve or other proper respiratory medical device.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Keep victim warm and quiet.

• Effects should disappear after individual has been exposed to fresh air for

approximately 10 minutes.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

SUBSTANCES (IRRITATING)

159
GU ERG2004 IDE

Page 268

POTENTIAL HAZARDS

HEALTH

• Toxic by ingestion.

• Vapors may cause dizziness or suffocation.

• Exposure in an enclosed area may be very harmful.

• Contact may irritate or burn skin and eyes.

• Fire may produce irritating and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but none ignite readily.

• Most vapors are heavier than air.

• Air/vapor mixtures may explode when ignited.

• Container may explode in heat of fire.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

HALOGENATED SOLVENTS

160
ERG2004 GUIDE

Page 269

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Dry chemical, CO2

, alcohol-resistant foam or water spray.

• Move containers from fire area if you can do it without risk.

• Dike fire control water for later disposal; do not scatter the material.

Fire involving Tanks or Car/Trailer Loads

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Stop leak if you can do it without risk.

Small Liquid Spills

• Take up with sand, earth or other non-combustible absorbent material.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• For minor skin contact, avoid spreading material on unaffected skin.

• Wash skin with soap and water.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

HALOGENATED SOLVENTS

160
GU ERG2004 IDE

Page 270

POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel

and the public during transportation accidents. Packaging durability increases as

potential hazard of radioactive content increases.

• Very low levels of contained radioactive materials and low radiation levels outside

packages result in low risks to people. Damaged packages may release measurable

amounts of radioactive material, but the resulting risks are expected to be low.

• Some radioactive materials cannot be detected by commonly available instruments.

• Packages do not have RADIOACTIVE I, II, or III labels. Some may have EMPTY labels or

may have the word “Radioactive” in the package marking.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Many have cardboard outer packaging; content (physically large or small) can be of many

different physical forms.

• Radioactivity does not change flammability or other properties of materials.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually

responsible for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay

decontamination and cleanup until instructions are received from Radiation Authority.

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’

protective clothing will provide adequate protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initial

evacuation distance of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS

161 (LOW LEVEL RADIATION)
ERG2004 GUIDE

Page 271

EMERGENCY RESPONSE

FIRE

• Presence of radioactive material will not influence the fire control processes and should

not influence selection of techniques.

• Move containers from fire area if you can do it without risk.

• Do not move damaged packages; move undamaged packages out of fire zone.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Cover liquid spill with sand, earth or other non-combustible absorbent material.

• Cover powder spill with plastic sheet or tarp to minimize spreading.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Injured persons contaminated by contact with released material are not a serious hazard

to health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to

protect themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS

(LOW LEVEL RADIATION) 161
GU ERG2004 IDE

Page 272

POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel

and the public during transportation accidents. Packaging durability increases as

potential hazard of radioactive content increases.

• Undamaged packages are safe. Contents of damaged packages may cause higher external

radiation exposure, or both external and internal radiation exposure if contents are released.

• Low radiation hazard when material is inside container. If material is released from package or

bulk container, hazard will vary from low to moderate. Level of hazard will depend on the

type and amount of radioactivity, the kind of material it is in, and/or the surfaces it is on.

• Some material may be released from packages during accidents of moderate severity but

risks to people are not great.

• Released radioactive materials or contaminated objects usually will be visible if packaging fails.

• Some exclusive use shipments of bulk and packaged materials will not have “RADIOACTIVE”

labels. Placards, markings and shipping papers provide identification.

• Some packages may have a “RADIOACTIVE” label and a second hazard label. The

second hazard is usually greater than the radiation hazard; so follow this GUIDE as well

as the response GUIDE for the second hazard class label.

• Some radioactive materials cannot be detected by commonly available instruments.

• Runoff from control of cargo fire may cause low-level pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Uranium and Thorium metal cuttings may ignite spontaneously if exposed to air (see

GUIDE 136).

• Nitrates are oxidizers and may ignite other combustibles (see GUIDE 141).

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually

responsible for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay

decontamination and cleanup until instructions are received from Radiation Authority.

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’

protective clothing will provide adequate protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initial

evacuation distance of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS

162 (LOW TO MODERATE LEVEL RADIATION)
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Page 273

EMERGENCY RESPONSE

FIRE

• Presence of radioactive material will not influence the fire control processes and should

not influence selection of techniques.

• Move containers from fire area if you can do it without risk.

• Do not move damaged packages; move undamaged packages out of fire zone.

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog (flooding amounts).

• Dike fire-control water for later disposal.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Cover liquid spill with sand, earth or other non-combustible absorbent material.

• Dike to collect large liquid spills.

• Cover powder spill with plastic sheet or tarp to minimize spreading.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, wipe from skin immediately; flush skin or eyes with

running water for at least 20 minutes.

• Injured persons contaminated by contact with released material are not a serious hazard to

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to

protect themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS

(LOW TO MODERATE LEVEL RADIATION) 162
GU ERG2004 IDE

Page 274

POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel and the public

during transportation accidents. Packaging durability increases as potential hazard of radioactive

content increases.

• Undamaged packages are safe. Contents of damaged packages may cause higher external radiation exposure,

or both external and internal radiation exposure if contents are released.

• Type A packages (cartons, boxes, drums, articles, etc.) identified as “Type A” by marking on packages or

by shipping papers contain non-life endangering amounts. Partial releases might be expected if “Type A”

packages are damaged in moderately severe accidents.

• Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain the

most hazardous amounts. They can be identified by package markings or by shipping papers. Life threatening

conditions may exist only if contents are released or package shielding fails. Because of design,

evaluation and testing of packages, these conditions would be expected only for accidents of utmost

severity.

• The rarely occurring "Special Arrangement" shipments may be of Type A, Type B or Type C packages. Package

type will be marked on packages, and shipment details will be on shipping papers.

• Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are very

low (less than 0.005 mSv/h (0.5 mrem/h)).

• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport index

(TI) on the label identifies the maximum radiation level in mrem/h one meter from a single, isolated, undamaged

package.

• Some radioactive materials cannot be detected by commonly available instruments.

• Water from cargo fire control may cause pollution.

FIRE OR EXPLOSION

• Some of these materials may burn, but most do not ignite readily.

• Radioactivity does not change flammability or other properties of materials.

• Type B packages are designed and evaluated to withstand total engulfment in flames at

temperatures of 800°C (1475°F) for a period of 30 minutes.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper

not available or no answer, refer to appropriate telephone number listed on the inside back

cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually

responsible for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay

decontamination and cleanup until instructions are received from Radiation Authority.

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’

protective clothing will provide adequate protection against internal radiation exposure, but not

external radiation exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initial evacuation

distance of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS

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EMERGENCY RESPONSE

FIRE

• Presence of radioactive material will not influence the fire control processes and should

not influence selection of techniques.

• Move containers from fire area if you can do it without risk.

• Do not move damaged packages; move undamaged packages out of fire zone.

Small Fires

• Dry chemical, CO2, water spray or regular foam.

Large Fires

• Water spray, fog (flooding amounts).

• Dike fire-control water for later disposal.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seldom an indication of

packaging failure. Most packaging for liquid content have inner containers and/or inner

absorbent materials.

• Cover liquid spill with sand, earth or other non-combustible absorbent material.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with running water for at least 20

minutes.

• Injured persons contaminated by contact with released material are not a serious hazard to health

care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to protect

themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS

(LOW TO HIGH LEVEL RADIATION) 163
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POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel and the

public during transportation accidents. Packaging durability increases as potential hazard of

radioactive content increases.

• Undamaged packages are safe; contents of damaged packages may cause external radiation

exposure, and much higher external exposure if contents (source capsules) are released.

• Contamination and internal radiation hazards are not expected, but not impossible.

• Type A packages (cartons, boxes, drums, articles, etc.) identified as “Type A” by marking on packages

or by shipping papers contain non-life endangering amounts. Radioactive sources may be released if

“Type A” packages are damaged in moderately severe accidents.

• Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain

the most hazardous amounts. They can be identified by package markings or by shipping papers. Life

threatening conditions may exist only if contents are released or package shielding fails. Because of

design, evaluation and testing of packages, these conditions would be expected only for

accidents of utmost severity.

• Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are

very low (less than 0.005 mSv/h (0.5 mrem/h)).

• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport

index (TI) on the label identifies the maximum radiation level in mrem/h one meter from a single,

isolated, undamaged package.

• Radiation from the package contents, usually in durable metal capsules, can be detected by most

radiation instruments.

• Water from cargo fire control is not expected to cause pollution.

FIRE OR EXPLOSION

• Packagings can burn completely without risk of content loss from sealed source capsule.

• Radioactivity does not change flammability or other properties of materials.

• Radioactive source capsules and Type B packages are designed and evaluated to withstand total

engulfment in flames at temperatures of 800°C (1475°F).

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not

available or no answer, refer to appropriate telephone number listed on the inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher

than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible

for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75

feet) in all directions.

• Stay upwind. • Keep unauthorized personnel away.

• Delay final cleanup until instructions or advice is received from Radiation Authority.

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’ protective

clothing will provide adequate protection against internal radiation exposure, but not external radiation

exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initial evacuation distance

of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS (SPECIAL FORM / LOW TO

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EMERGENCY RESPONSE

FIRE

• Presence of radioactive material will not influence the fire control processes and should

not influence selection of techniques.

• Move containers from fire area if you can do it without risk.

• Do not move damaged packages; move undamaged packages out of fire zone.

Small Fires

• Dry chemical, CO2, water spray or regular foam.

Large Fires

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seldom an indication of

packaging failure. Contents are seldom liquid. Content is usually a metal capsule, easily seen if

released from package.

• If source capsule is identified as being out of package, DO NOT TOUCH. Stay away and await

advice from Radiation Authority.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Persons exposed to special form sources are not likely to be contaminated with radioactive

material.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Injured persons contaminated by contact with released material are not a serious hazard to

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to protect

themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS (SPECIAL FORM/LOW TO

HIGH LEVEL EXTERNAL RADIATION) 164
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POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel and the

public during transportation accidents. Packaging durability increases as potential radiation

and criticality hazards of the content increase.

• Undamaged packages are safe. Contents of damaged packages may cause higher external radiation

exposure, or both external and internal radiation exposure if contents are released.

• Type AF or IF packages, identified by package markings, do not contain life-threatening amounts of

material. External radiation levels are low and packages are designed, evaluated and tested

to control releases and to prevent a fission chain reaction under severe transport conditions.

• Type B(U)F, B(M)F and CF packages (identified by markings on packages or shipping papers) contain

potentially life endangering amounts. Because of design, evaluation and testing of packages,

fission chain reactions are prevented and releases are not expected to be life endangering for

all accidents except those of utmost severity.

• The rarely occurring "Special Arrangement" shipments may be of Type AF, BF or CF packages.

Package type will be marked on packages, and shipment details will be on shipping papers.

• The transport index (TI) shown on labels or a shipping paper might not indicate the radiation

level at one meter from a single, isolated, undamaged package; instead, it might relate to

controls needed during transport because of the fissile properties of the materials.

Alternatively, the fissile nature of the contents may be indicated by a criticality safety index

(CSI) on a special FISSILE label or on the shipping paper.

• Some radioactive materials cannot be detected by commonly available instruments.

• Water from cargo fire control is not expected to cause pollution.

FIRE OR EXPLOSION

• These materials are seldom flammable. Packages are designed to withstand fires without

damage to contents.

• Radioactivity does not change flammability or other properties of materials.

• Type AF, IF, B(U)F, B(M)F and CF packages are designed and evaluated to withstand total

engulfment in flames at temperatures of 800°C (1475°F) for a period of 30 minutes.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper

not available or no answer, refer to appropriate telephone number listed on the inside back

cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually

responsible for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay

decontamination and cleanup until instructions are received from Radiation Authority.

PROTECTIVE CLOTHING

• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’

protective clothing will provide adequate protection against internal radiation exposure, but not

external radiation exposure.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When a large quantity of this material is involved in a major fire, consider an initial

evacuation distance of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS

165 (FISSILE/LOW TO HIGH LEVEL RADIATION)
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EMERGENCY RESPONSE

FIRE

• Presence of radioactive material will not influence the fire control processes and should

not influence selection of techniques.

• Move containers from fire area if you can do it without risk.

• Do not move damaged packages; move undamaged packages out of fire zone.

Small Fires

• Dry chemical, CO2, water spray or regular foam.

Large Fires

• Water spray, fog (flooding amounts).

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Damp surfaces on undamaged or slightly damaged packages are seldom an indication of

packaging failure. Most packaging for liquid content have inner containers and/or inner

absorbent materials.

Liquid Spills

• Package contents are seldom liquid. If any radioactive contamination resulting from a liquid

release is present, it probably will be low-level.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with running water for at least

20 minutes.

• Injured persons contaminated by contact with released material are not a serious hazard to

health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to protect

themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS

(FISSILE/LOW TO HIGH LEVEL RADIATION) 165
GU ERG2004 IDE

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POTENTIAL HAZARDS

HEALTH

• Radiation presents minimal risk to transport workers, emergency response personnel and the

public during transportation accidents. Packaging durability increases as potential radiation

and criticality hazards of the content increase.

• Chemical hazard greatly exceeds radiation hazard.

• Substance reacts with water and water vapor in air to form toxic and corrosive hydrogen

fluoride gas and an extremely irritating and corrosive, white-colored, water-soluble residue.

• If inhaled, may be fatal.

• Direct contact causes burns to skin, eyes, and respiratory tract.

• Low-level radioactive material; very low radiation hazard to people.

• Runoff from control of cargo fire may cause low-level pollution.

FIRE OR EXPLOSION

• Substance does not burn. • The material may react violently with fuels.

• Containers in protective overpacks (horizontal cylindrical shape with short legs for tiedowns), are identified with "AF", "B(U)F" or "H(U)" on shipping papers or by markings on

the overpacks. They are designed and evaluated to withstand severe conditions

including total engulfment in flames at temperatures of 800°C (1475°F).

• Bare filled cylinders, identified with UN2978 as part of the marking (may also be marked

H(U) or H(M)), may rupture in heat of engulfing fire; bare empty (except for residue)

cylinders will not rupture in fires.

• Radioactivity does not change flammability or other properties of materials.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• Priorities for rescue, life-saving, first aid, fire control and other hazards are

higher than the priority for measuring radiation levels.

• Radiation Authority must be notified of accident conditions. Radiation Authority is usually

responsible for decisions about radiological consequences and closure of emergencies.

• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters

(75 feet) in all directions. • Stay upwind. • Keep unauthorized personnel away.

• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay

decontamination and cleanup until instructions are received from Radiation Authority.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

EVACUATION

Large Spill

• See the Table of Initial Isolation and Protective Action Distances.

Fire

• When a large quantity of this material is involved in a major fire, consider an initial

evacuation distance of 300 meters (1000 feet) in all directions.

RADIOACTIVE MATERIALS - CORROSIVE

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EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER OR FOAM ON MATERIAL ITSELF.

• Move containers from fire area if you can do it without risk.

Small Fires

• Dry chemical or CO2

.

Large Fires

• Water spray, fog or regular foam.

• Cool containers with flooding quantities of water until well after fire is out.

• If this is impossible, withdraw from area and let fire burn.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch damaged packages or spilled material.

• Without fire or smoke, leak will be evident by visible and irritating vapors and residue

forming at the point of release.

• Use fine water spray to reduce vapors; do not put water directly on point of material release

from container.

• Residue buildup may self-seal small leaks.

• Dike far ahead of spill to collect runoff water.

FIRST AID

• Medical problems take priority over radiological concerns.

• Use first aid treatment according to the nature of the injury.

• Do not delay care and transport of a seriously injured person.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

• Injured persons contaminated by contact with released material are not a serious hazard

to health care personnel, equipment or facilities.

• Ensure that medical personnel are aware of the material(s) involved, take precautions to

protect themselves and prevent spread of contamination.

RADIOACTIVE MATERIALS - CORROSIVE

(URANIUM HEXAFLUORIDE/WATER-SENSITIVE) 166
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POTENTIAL HAZARDS

HEALTH

• TOXIC; may be fatal if inhaled.

• Vapors are extremely irritating.

• Contact with gas or liquefied gas will cause burns, severe injury and/or frostbite.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

• Substance does not burn but will support combustion.

• This is a strong oxidizer and will react vigorously or explosively with many materials

including fuels.

• May ignite combustibles (wood, paper, oil, clothing, etc.).

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Containers may explode when heated.

• Ruptured cylinders may rocket.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all

directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.

FLUORINE (REFRIGERATED LIQUID)

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EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, soda ash, lime or sand.

Large Fires

• Water spray, fog (flooding amounts).

• Do not get water inside containers.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,

withdraw from area and let fire burn.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• If you have not donned special protective clothing approved for this material, do not expose

yourself to any risk of this material touching you.

• Do not direct water at spill or source of leak.

• A fine water spray remotely directed to the edge of the spill pool can be used to direct and

maintain a hot flare fire which will burn the spilled material in a controlled manner.

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to

contact spilled material.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

• Ventilate the area.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Clothing frozen to the skin should be thawed before being removed.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

FLUORINE (REFRIGERATED LIQUID)

167
GU ERG2004 IDE

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POTENTIAL HAZARDS

HEALTH

• TOXIC; Extremely Hazardous.

• Inhalation extremely dangerous; may be fatal.

• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.

• Odorless, will not be detected by sense of smell.

FIRE OR EXPLOSION

• EXTREMELY FLAMMABLE.

• May be ignited by heat, sparks or flames.

• Flame may be invisible.

• Containers may explode when heated.

• Vapor explosion and poison hazard indoors, outdoors or in sewers.

• Vapors from liquefied gas are initially heavier than air and spread along ground.

• Vapors may travel to source of ignition and flash back.

• Runoff may create fire or explosion hazard.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters

(330 feet) in all directions.

• Keep unauthorized personnel away.

• Stay upwind.

• Many gases are heavier than air and will spread along ground and collect in low or

confined areas (sewers, basements, tanks).

• Keep out of low areas.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear chemical protective clothing that is specifically recommended by the manufacturer.

It may provide little or no thermal protection.

• Structural firefighters' protective clothing provides limited protection in fire situations

ONLY; it is not effective in spill situations where direct contact with the substance is

possible.

• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

CARBON MONOXIDE (REFRIGERATED LIQUID)

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EMERGENCY RESPONSE

FIRE

• DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fires

• Dry chemical, CO2

 or water spray.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks

• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

• Cool containers with flooding quantities of water until well after fire is out.

• Do not direct water at source of leak or safety devices; icing may occur.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• All equipment used when handling the product must be grounded.

• Fully encapsulating, vapor protective clothing should be worn for spills and leaks with

no fire.

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff

to contact spilled material.

• Do not direct water at spill or source of leak.

• If possible, turn leaking containers so that gas escapes rather than liquid.

• Prevent entry into waterways, sewers, basements or confined areas.

• Isolate area until gas has dispersed.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• In case of contact with liquefied gas, thaw frosted parts with lukewarm water.

• Keep victim warm and quiet. • Keep victim under observation.

• Effects of contact or inhalation may be delayed.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

CARBON MONOXIDE (REFRIGERATED LIQUID)

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Substance is transported in molten form at a temperature above 705°C (1300°F).

• Violent reaction with water; contact may cause an explosion or may produce a

flammable gas.

• Will ignite combustible materials (wood, paper, oil, debris, etc.).

• Contact with nitrates or other oxidizers may cause an explosion.

• Contact with containers or other materials, including cold, wet or dirty tools, may cause

an explosion.

• Contact with concrete will cause spalling and small pops.

HEALTH

• Contact causes severe burns to skin and eyes.

• Fire may produce irritating and/or toxic gases.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Keep unauthorized personnel away.

• Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Wear flame retardant structural firefighters’ protective clothing, including faceshield,

helmet and gloves, this will provide limited thermal protection.

ALUMINUM (MOLTEN)

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EMERGENCY RESPONSE

FIRE

• Do Not Use Water, except in life threatening situations and then only in a fine

spray.

• Do not use halogenated extinguishing agents or foam.

• Move combustibles out of path of advancing pool if you can do so without risk.

• Extinguish fires started by molten material by using appropriate method for the burning

material; keep water, halogenated extinguishing agents and foam away from the molten

material.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Do not attempt to stop leak, due to danger of explosion.

• Keep combustibles (wood, paper, oil, etc.) away from spilled material.

• Substance is very fluid, spreads quickly, and may splash. Do not try to stop it with

shovels or other objects.

• Dike far ahead of spill; use dry sand to contain the flow of material.

• Where possible allow molten material to solidify naturally.

• Avoid contact even after material solidifies. Molten, heated and cold aluminum

look alike; do not touch unless you know it is cold.

• Clean up under the supervision of an expert after material has solidified.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• For severe burns, immediate medical attention is required.

• Removal of solidified molten material from skin requires medical assistance.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

ALUMINUM (MOLTEN)

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POTENTIAL HAZARDS

FIRE OR EXPLOSION

• May react violently or explosively on contact with water.

• Some are transported in flammable liquids.

• May be ignited by friction, heat, sparks or flames.

• Some of these materials will burn with intense heat.

• Dusts or fumes may form explosive mixtures in air.

• Containers may explode when heated.

• May re-ignite after fire is extinguished.

HEALTH

• Oxides from metallic fires are a severe health hazard.

• Inhalation or contact with substance or decomposition products may cause

severe injury or death.

• Fire may produce irritating, corrosive and/or toxic gases.

• Runoff from fire control or dilution water may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Stay upwind.

• Keep unauthorized personnel away.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 50 meters (160 feet).

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

METALS (POWDERS, DUSTS, SHAVINGS, BORINGS,

170 TURNINGS, OR CUTTINGS, ETC.)
ERG2004 GUIDE

Page 289

EMERGENCY RESPONSE

FIRE

• DO NOT USE WATER, FOAM OR CO2.

• Dousing metallic fires with water may generate hydrogen gas, an extremely dangerous

explosion hazard, particularly if fire is in a confined environment (i.e., building, cargo hold,

etc.).

• Use DRY sand, graphite powder, dry sodium chloride based extinguishers,

G-1® or Met-L-X® powder.

• Confining and smothering metal fires is preferable rather than applying water.

• Move containers from fire area if you can do it without risk.

Fire involving Tanks or Car/Trailer Loads

• If impossible to extinguish, protect surroundings and allow fire to burn itself out.

SPILL OR LEAK

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

METALS (POWDERS, DUSTS, SHAVINGS, BORINGS,

TURNINGS, OR CUTTINGS, ETC.) 170
GU ERG2004 IDE

Page 290

POTENTIAL HAZARDS

FIRE OR EXPLOSION

• Some may burn but none ignite readily.

• Containers may explode when heated.

• Some may be transported hot.

HEALTH

• Inhalation of material may be harmful.

• Contact may cause burns to skin and eyes.

• Inhalation of Asbestos dust may have a damaging effect on the lungs.

• Fire may produce irritating, corrosive and/or toxic gases.

• Some liquids produce vapors that may cause dizziness or suffocation.

• Runoff from fire control may cause pollution.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If

Shipping Paper not available or no answer, refer to appropriate telephone

number listed on the inside back cover.

• As an immediate precautionary measure, isolate spill or leak area in all directions for at

least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

• Keep unauthorized personnel away.

• Stay upwind.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Spill

• See the Table of Initial Isolation and Protective Action Distances for highlighted

substances. For non-highlighted substances, increase, in the downwind direction, as

necessary, the isolation distance shown under “PUBLIC SAFETY”.

Fire

• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all

directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

 SUBSTANCES (LOW TO MODERATE HAZARD)

171
ERG2004 GUIDE

Page 291

EMERGENCY RESPONSE

FIRE

Small Fires

• Dry chemical, CO2

, water spray or regular foam.

Large Fires

• Water spray, fog or regular foam.

• Move containers from fire area if you can do it without risk.

• Do not scatter spilled material with high pressure water streams.

• Dike fire-control water for later disposal.

Fire involving Tanks

• Cool containers with flooding quantities of water until well after fire is out.

• Withdraw immediately in case of rising sound from venting safety devices or

discoloration of tank.

• ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Stop leak if you can do it without risk.

• Prevent dust cloud.

• Avoid inhalation of asbestos dust.

Small Dry Spills

• With clean shovel place material into clean, dry container and cover loosely; move

containers from spill area.

Small Spills

• Take up with sand or other non-combustible absorbent material and place

into containers for later disposal.

Large Spills

• Dike far ahead of liquid spill for later disposal.

• Cover powder spill with plastic sheet or tarp to minimize spreading.

• Prevent entry into waterways, sewers, basements or confined areas.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.

 SUBSTANCES (LOW TO MODERATE HAZARD)

171
GU ERG2004 IDE

Page 292

POTENTIAL HAZARDS

HEALTH

• Inhalation of vapors or contact with substance will result in contamination and potential

harmful effects.

• Fire will produce irritating, corrosive and/or toxic gases.

FIRE OR EXPLOSION

• Non-combustible, substance itself does not burn but may react upon heating to produce

corrosive and/or toxic fumes.

• Runoff may pollute waterways.

PUBLIC SAFETY

• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping

Paper not available or no answer, refer to appropriate telephone number listed on the

inside back cover.

• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters

(150 feet) in all directions.

• Stay upwind.

• Keep unauthorized personnel away.

PROTECTIVE CLOTHING

• Wear positive pressure self-contained breathing apparatus (SCBA).

• Structural firefighters’ protective clothing will only provide limited protection.

EVACUATION

Large Spill

• Consider initial downwind evacuation for at least 100 meters (330 feet).

Fire

• When any large container is involved in a fire, consider initial evacuation for 500 meters

(1/3 mile) in all directions.

GALLIUM AND MERCURY

172
ERG2004 GUIDE

Page 293

GALLIUM AND MERCURY

172

EMERGENCY RESPONSE

FIRE

• Use extinguishing agent suitable for type of surrounding fire.

• Do not direct water at the heated metal.

SPILL OR LEAK

• Do not touch or walk through spilled material.

• Do not touch damaged containers or spilled material unless wearing

appropriate protective clothing.

• Stop leak if you can do it without risk.

• Prevent entry into waterways, sewers, basements or confined areas.

• Do not use steel or aluminum tools or equipment.

• Cover with earth, sand or other non-combustible material followed with plastic sheet to

minimize spreading or contact with rain.

• For mercury, use a mercury spill kit.

• Mercury spill areas may be subsequently treated with calcium sulphide/calcium sulfide or

with sodium thiosulphate/sodium thiosulfate wash to neutralize any residual mercury.

FIRST AID

• Move victim to fresh air. • Call 911 or emergency medical service.

• Give artificial respiration if victim is not breathing.

• Administer oxygen if breathing is difficult.

• Remove and isolate contaminated clothing and shoes.

• In case of contact with substance, immediately flush skin or eyes with running water for

at least 20 minutes.

• Keep victim warm and quiet.

• Ensure that medical personnel are aware of the material(s) involved and take

precautions to protect themselves.
Page 294

NOTES
Page 295

INTRODUCTION TO THE TABLE OF INITIAL ISOLATION

AND PROTECTIVE ACTION DISTANCES

The Table of Initial Isolation and Protective Action Distances suggests distances useful to protect

people from vapors resulting from spills involving dangerous goods which are considered toxic

by inhalation (TIH), including certain chemical warfare agents, or which produce toxic gases

upon contact with water. The Table provides first responders with initial guidance until technically

qualified emergency response personnel are available. Distances show areas likely to be

affected during the first 30 minutes after materials are spilled and could increase

with time.

The Initial Isolation Zone defines an area SURROUNDING the incident in which persons

may be exposed to dangerous (upwind) and life threatening (downwind) concentrations of

material. The Protective Action Zone defines an area DOWNWIND from the incident in

which persons may become incapacitated and unable to take protective action and/or incur

serious or irreversible health effects. The Table provides specific guidance for small and

large spills occurring day or night.

Adjusting distances for a specific incident involves many interdependent variables and should

be made only by personnel technically qualified to make such adjustments. For this reason,

no precise guidance can be provided in this document to aid in adjusting the table distances;

however, general guidance follows.

Factors That May Change the Protective Action Distances

The guide for a material (orange-bordered pages) clearly indicates under the section

EVACUATION – Fire, the evacuation distance required to protect against fragmentation hazard

of a large container. If the material becomes involved in a FIRE, the toxic hazard may become

less important than the fire or explosion hazard.

If more than one tank car, cargo tank, portable tank, or large cylinder involved in the incident is

leaking, LARGE SPILL distances may need to be increased.

For a material with a protective action distance of 11.0+ km (7.0+ miles), the actual distance can

be larger in certain atmospheric conditions. If the dangerous goods vapor plume is channeled

in a valley or between many tall buildings, distances may be larger than shown in the Table due

to less mixing of the plume with the atmosphere. Daytime spills in regions with known strong

inversions or snow cover, or occurring near sunset, accompanied by a steady wind, may

require an increase in protective action distance. When these conditions are present, airborne

contaminants mix and disperse more slowly and may travel much farther downwind. In addition,

protective action distances may be larger for liquid spills when either the material or outdoor

temperature exceeds 30°C (86°F).

Materials which react with water to produce large amounts of toxic gases are included in the

Table of Initial Isolation and Protective Action Distances. Note that some water-reactive materials
Page 296

(WRM) which are also TIH (e.g., Bromine trifluoride (1746), Thionyl chloride (1836), etc.)

produce additional TIH materials when spilled in water. For these materials, two entries are

provided in the Table of Initial Isolation and Protective Action Distances (i.e., for spills on land

and for spills in water). If it is not clear whether the spill is on land or in water, or in cases where

the spill occurs both on land and in water, choose the larger Protective Action Distance. Following

the Table of Initial Isolation and Protective Action Distances is a table that lists the materials which,

when spilled in water, produce toxic gases. The toxic gases that these water-reactive materials

(WRM) produce are also included in the Table.

When a water-reactive TIH producing material is spilled into a river or stream, the source of the

toxic gas may move with the current and stretch from the spill point downstream for a substantial

distance.

Certain chemical warfare agents have been added to the Table of Initial Isolation and Protective

Action Distances. The distances shown were calculated using worst case scenarios for these

agents when used as a weapon.

Initial isolation and protective action distances in this guidebook are derived from historical data

on transportation incidents and the use of statistical models. For worst case scenarios involving

the instantaneous release of the entire contents of a package (e.g., as a result of terrorism,

sabotage or catastrophic accident) the distances may increase. The increase can be estimated

by multiplying the distances by a factor of two (2).
Page 297

PROTECTIVE ACTION DECISION FACTORS TO CONSIDER

The choice of protective actions for a given situation depends on a number of factors. For some

cases, evacuation may be the best option; in others, sheltering in-place may be the best course.

Sometimes, these two actions may be used in combination. In any emergency, officials need to

quickly give the public instructions. The public will need continuing information and instructions

while being evacuated or sheltered in-place.

Proper evaluation of the factors listed below will determine the effectiveness of evacuation or inplace protection. The importance of these factors can vary with emergency conditions. In

specific emergencies, other factors may need to be identified and considered as well. This list

indicates what kind of information may be needed to make the initial decision.

The Dangerous Goods

· Degree of health hazard

· Chemical and physical properties

· Amount involved

· Containment/control of release

· Rate of vapor movement

The Population Threatened

· Location

· Number of people

· Time available to evacuate or shelter in-place

· Ability to control evacuation or shelter in-place

· Building types and availability

· Special institutions or populations, e.g., nursing homes, hospitals,

prisons

Weather Conditions

· Effect on vapor and cloud movement

· Potential for change

· Effect on evacuation or protection in-place
Page 298

PROTECTIVE ACTIONS

Protective Actions are those steps taken to preserve the health and safety of emergency

responders and the public during an incident involving releases of dangerous goods. The

Table of Initial Isolation and Protective Action Distances (green-bordered pages) predicts

the size of downwind areas which could be affected by a cloud of toxic gas. People in this

area should be evacuated and/or sheltered in-place inside buildings.

Isolate Hazard Area and Deny Entry means keep everybody away from the area if they

are not directly involved in emergency response operations. Unprotected emergency responders should not be allowed to enter the isolation zone. This “isolation” task is done first

to establish control over the area of operations. This is the first step for any protective

actions that may follow. See the Table of Isolation and Protective Action Distances (greenbordered pages) for more detailed information on specific materials.

Evacuate means move all people from a threatened area to a safer place. To perform an

evacuation, there must be enough time for people to be warned, to get ready, and to leave

an area. If there is enough time, evacuation is the best protective action. Begin evacuating

people nearby and those outdoors in direct view of the scene. When additional help arrives, expand the area to be evacuated downwind and crosswind to at least the extent

recommended in this guidebook. Even after people move to the distances recommended,

they may not be completely safe from harm. They should not be permitted to congregate at

such distances. Send evacuees to a definite place, by a specific route, far enough away so

they will not have to be moved again if the wind shifts.

Shelter In-Place means people should seek shelter inside a building and remain inside

until the danger passes. Sheltering in-place is used when evacuating the public would

cause greater risk than staying where they are, or when an evacuation cannot be

performed. Direct the people inside to close all doors and windows and to shut off all

ventilating, heating and cooling systems. In-place protection may not be the best option if (a) the vapors are flammable; (b) if it will take a long time for the gas to clear the area;

or (c) if buildings cannot be closed tightly. Vehicles can offer some protection for a short

period if the windows are closed and the ventilating systems are shut off. Vehicles are not

as effective as buildings for in-place protection.

It is vital to maintain communications with competent persons inside the building so

that they are advised about changing conditions. Persons protected-in-place should be

warned to stay far from windows because of the danger from glass and projected metal

fragments in a fire and/or explosion.

Every dangerous goods incident is different. Each will have special problems and concerns. Action to protect the public must be selected carefully. These pages can help with

initial decisions on how to protect the public. Officials must continue to gather information

and monitor the situation until the threat is removed.
Page 299

BACKGROUND ON THE INITIAL ISOLATION

AND PROTECTIVE ACTION DISTANCE TABLE

Initial Isolation and Protective Action Distances in this guidebook were determined for small

and large spills occurring during day or night. The overall analysis was statistical in nature

and utilized state-of-the-art emission rate and dispersion models; statistical release data

from the U.S. DOT HMIS (Hazardous Materials Incident Reporting System) database; 5

years of meteorological observations from over 120 locations in United States, Canada and

Mexico; and the most current toxicological exposure guidelines.

For each chemical, thousands of hypothetical releases were modeled to account for the

statistical variation in both release amount and atmospheric conditions. Based on this statistical

sample, the 90% percentile Protective Action Distance for each chemical and category was

selected to appear in the Table. A brief description of the analysis is provided below. A

detailed report outlining the methodology and data used in the generation of the Initial Isolation

and Protective Action Distances may be obtained from the U.S. Department of Transportation,

Research and Special Programs Administration.

Release amounts and emission rates into the atmosphere were statistically modeled based on

(1) data from the U.S. DOT HMIS database; (2) container types and sizes authorized for transport

as specified in 49 CFR §172.101 and Part 173; (3) physical properties of the materials involved, and

(4) atmospheric data from a historical database. The emission model calculated the release of

vapor due to evaporation of pools on the ground, direct release of vapors from the container, or a

combination of both, as would occur for liquefied gases which can flash to form both a vapor/

aerosol mixture and an evaporating pool. In addition, the emission model also calculated the

emission of toxic vapor by-products generated from spilling water-reactive chemicals in water. Spills

that involve releases of approximately 200 liters or less are considered Small Spills, while spills that

involve quantities greater than 200 liters are considered Large Spills.

Downwind dispersion of the vapor was estimated for each case modeled. Atmospheric

parameters affecting the dispersion, and the emission rate, were selected in a statistical

fashion from a database containing hourly meteorological data from 120 cities in United

States, Canada and Mexico. The dispersion calculation accounted for the time dependent

emission rate from the source as well as the density of the vapor plume (i.e., heavy gas

effects). Since atmospheric mixing is less effective at dispersing vapor plumes during

nighttime, day and night were separated in the analysis. In the Table, “Day” refers to time

periods after sunrise and before sunset, while “Night” includes all hours between sunset and

sunrise.

Toxicological short-term exposure guidelines for the chemicals were applied to determine

the downwind distance to which persons may become incapacitated and unable to take

protective action or may incur serious health effects. Toxicological exposure guidelines were

chosen from (1) emergency response guidelines, (2) occupational health guidelines, or (3)

lethal concentrations determined from animal studies, as recommended by an independent

panel of toxicological experts from industry and academia.
Page 300

HOW TO USE THE TABLE OF INITIAL ISOLATION AND

PROTECTIVE ACTION DISTANCES

(1) The responder should already have:

• Identified the material by its ID Number and Name; (if an ID Number cannot be

found, use the Name of Material index in the blue-bordered pages to locate that

number.) • Found the three-digit guide for that material in order to consult the emergency

actions recommended jointly with this table;

• Noted the wind direction.

(2) Look in this Table (the green-bordered pages) for the ID Number and Name of the

Material involved in the incident. Some ID Numbers have more than one shipping

name listed—look for the specific name of the material. (If the shipping name is not

known and the Table lists more than one name for the same ID Number, use the entry

with the largest protective action distances.)

(3) Determine if the incident involves a SMALL or LARGE spill and if DAY or NIGHT.

Generally, a SMALL SPILL is one which involves a single, small package (e.g., a drum

containing up to approximately 200 liters), a small cylinder, or a small leak from a large

package. A LARGE SPILL is one which involves a spill from a large package, or

multiple spills from many small packages. DAY is any time after sunrise and before

sunset. NIGHT is any time between sunset and sunrise.

(4) Look up the initial ISOLATION distance.

Direct all persons to move, in a crosswind

direction, away from the spill to the

distance specified—in meters and feet.

(5) Look up the initial PROTECTIVE ACTION DISTANCE shown in the Table. For a given

material, spill size, and whether day or night, the Table gives the downwind distance—in

kilometers and miles— for which protective actions should be considered. For practical

purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful

exposure) is a square, whose length and width are the same as the downwind distance

shown in the Table.

Initial Isolation

Zone

Initial Isolation

Distance

Spill
Page 301

(6) Initiate Protective Actions to the extent possible, beginning with those closest to the

spill site and working away from the site in the downwind direction. When a waterreactive TIH producing material is spilled into a river or stream, the source of the toxic

gas may move with the current or stretch from the spill point downstream for a substantial

distance.

The shape of the area in which protective actions should be taken (the Protective

Action Zone) is shown in this figure. The spill is located at the center of the small

circle. The larger circle represents the INITIAL ISOLATION zone around the spill.

NOTE: See “Introduction To The Table Of Initial Isolation And Protective Action

Distances” for factors which may increase or decrease Protective Action

Distances.

Call the emergency response telephone number listed on the shipping paper, or the

appropriate response agency as soon as possible for additional information on the material,

safety precautions, and mitigation procedures.

Protective

Action Zone

Initial

Isolation

Zone

1/2 Downwind

Distance

Wind Direction

1/2 Downwind

Distance

Spill

Downwind Distance
Page 302

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1005 Ammonia, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

1005 Ammonia, anhydrous, liquefied

1005 Ammonia, solution, with more

 than 50% Ammonia

1005 Anhydrous ammonia

1005 Anhydrous ammonia, liquefied

1008 Boron trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi)

1008 Boron trifluoride, compressed

1016 Carbon monoxide 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)

1016 Carbon monoxide, compressed

1017 Chlorine 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi)

1023 Coal gas 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)

1023 Coal gas, compressed

1026 Cyanogen 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 120 m (400 ft) 1.1 km (0.7 mi) 4.3 km (2.7 mi)

1026 Cyanogen, liquefied

1026 Cyanogen gas

1040 Ethylene oxide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

1040 Ethylene oxide with Nitrogen

1045 Fluorine 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi)

1045 Fluorine, compressed

1048 Hydrogen bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.7 km (3.6 mi)

1050 Hydrogen chloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi)

1051 AC (when used as a weapon) 60 m (200 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 500 m (1500 ft) 1.7 km (1.0 mi) 3.9 km (2.4 mi)
"+" means distance can be larger in certain atmospheric conditions

Page 303

1051 Hydrocyanic acid, aqueous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi)

solutions, with more than 20%

Hydrogen cyanide

1051 Hydrocyanic acid, liquefied

1051 Hydrogen cyanide, anhydrous,

 stabilized

1051 Hydrogen cyanide, stabilized

1052 Hydrogen fluoride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 210 m (700 ft) 1.9 km (1.2 mi) 4.3 km (2.7 mi)

1053 Hydrogen sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 210 m (700 ft) 2.1 km (1.3 mi) 6.2 km (3.9 mi)

1053 Hydrogen sulfide, liquefied

1053 Hydrogen sulphide

1053 Hydrogen sulphide, liquefied

1062 Methyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.2 km (1.4 mi)

1064 Methyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.5 km (2.8 mi)

1067 Dinitrogen tetroxide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.6 km (1.0 mi) 4.1 km (2.5 mi)

1067 Dinitrogen tetroxide, liquefied

1067 Nitrogen dioxide

1067 Nitrogen dioxide, liquefied

1069 Nitrosyl chloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 450 m (1500 ft) 4.3 km (2.7 mi) 11.0 km (6.9 mi)

1071 Oil gas 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)

1071 Oil gas, compressed

1076 CG (when used as a weapon) 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.0 mi) 800 m (2500 ft) 7.3 km (4.5 mi) 11.0+ km (7.0+ mi)

1076 Diphosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1 km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+ km (7.0+ mi)

1076 DP (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 180 m (600 ft) 1.7 km (1.0 mi) 4.6 km (2.8 mi)

1076 Phosgene 90 m (300 ft) 0.9 km (0.6 mi) 4.1 km (2.6 mi) 800 m (2500 ft) 6.6 km (4.1 mi) 11.0+ km (7.0+ mi)

1079 Sulfur dioxide 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 210 m (700 ft) 2.0 km (1.3 mi) 6.3 km (3.9 mi)

1079 Sulfur dioxide, liquefied

1079 Sulphur dioxide

1079 Sulphur dioxide, liquefied
Page 304

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1082 Trifluorochloroethylene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)

1082 Trifluorochloroethylene, inhibited

1082 Trifluorochloroethylene, stabilized

1092 Acrolein, inhibited 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.8 km (3.0 mi) 10.2 km (6.3 mi)

1092 Acrolein, stabilized

1098 Allyl alcohol 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)

1135 Ethylene chlorohydrin 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.5 km (1.0 mi)

1143 Crotonaldehyde, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)

1143 Crotonaldehyde, stabilized

1162 Dimethyldichlorosilane 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi)

(when spilled in water)

1163 1,1-Dimethylhydrazine 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.2 km (0.8 mi)

1163 Dimethylhydrazine, unsymmetrical

1182 Ethyl chloroformate 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi)

1185 Ethyleneimine, inhibited 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 4.0 km (2.5 mi)

1185 Ethyleneimine, stabilized

1196 Ethyltrichlorosilane 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi)

(when spilled in water)

1238 Methyl chloroformate 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 180 m (600 ft) 1.8 km (1.1 mi) 3.9 km (2.4 mi)

1239 Methyl chloromethyl ether 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

1242 Methyldichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi)

(when spilled in water)

1244 Methylhydrazine 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.9 km (1.8 mi)
"+" means distance can be larger in certain atmospheric conditions

Page 305

1250 Methyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 4.0 km (2.5 mi)

(when spilled in water)

1251 Methyl vinyl ketone 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

1251 Methyl vinyl ketone, stabilized

1259 Nickel carbonyl 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi)

1295 Trichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 6.5 km (4.1 mi)

(when spilled in water)

1298 Trimethylchlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi)

(when spilled in water)

1305 Vinyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.0 km (3.1 mi)

(when spilled in water)

1305 Vinyltrichlorosilane, inhibited

(when spilled in water)

1305 Vinyltrichlorosilane, stabilized

(when spilled in water)

1340 Phosphorus pentasulfide, free 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi)

from yellow or white Phosphorus

(when spilled in water)

1340 Phosphorus pentasulphide, free

 from yellow or white Phosphorus

(when spilled in water)

1360 Calcium phosphide 60 m (200 ft) 0.5 km (0.3 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.3 km (3.9 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

1380 Pentaborane 90 m (300 ft) 0.9 km (0.6 mi) 3.3 km (2.1 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)

1384 Sodium dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

(when spilled in water)

1384 Sodium hydrosulfite

(when spilled in water)

1384 Sodium hydrosulphite

(when spilled in water)

1397 Aluminum phosphide 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)

(when spilled in water)
Page 306

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1412 Lithium amide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi)

(when spilled in water)

1419 Magnesium aluminum phosphide 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 7.9 km (4.9 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

1432 Sodium phosphide 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

1510 Tetranitromethane 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)

1541 Acetone cyanohydrin, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 240 m (800 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)

(when spilled in water)

1556 MD (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.1 km (0.7 mi)

1556 Methyldichloroarsine 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.6 km (2.2 mi)

1556 PD (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi)

1560 Arsenic chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.8 km (1.1 mi)

1560 Arsenic trichloride

1569 Bromoacetone 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.3 km (1.5 mi)

1580 Chloropicrin 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)

1581 Chloropicrin and Methyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.9 km (3.7 mi)

mixture

1581 Methyl bromide and Chloropicrin

 mixture

1582 Chloropicrin and Methyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi)

mixture

1582 Methyl chloride and Chloropicrin

 mixture

1583 Chloropicrin mixture, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)
"+" means distance can be larger in certain atmospheric conditions

Page 307

1589 CK (when used as a weapon) 60 m (200 ft) 0.7 km (0.4 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1 km (2.5 mi) 8.1 km (5.0 mi)

1589 Cyanogen chloride, inhibited 60 m (200 ft) 0.6 km (0.4 mi) 2.8 km (1.8 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 10.1 km (6.3 mi)

1589 Cyanogen chloride, stabilized

1595 Dimethyl sulfate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

1595 Dimethyl sulphate

1605 Ethylene dibromide 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi)

1612 Hexaethyl tetraphosphate and 90 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.1 km (5.1 mi)

compressed gas mixture

1613 Hydrocyanic acid, aqueous 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 120 m (400 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi)

solution, with not more than

20% Hydrogen cyanide

1613 Hydrogen cyanide, aqueous

 solution, with not more than

 20% Hydrogen cyanide

1614 Hydrogen cyanide, anhydrous, 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.7 km (1.1 mi)

stabilized (absorbed)

1614 Hydrogen cyanide, stabilized

 (absorbed)

1647 Ethylene dibromide and Methyl 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi)

bromide mixture, liquid

1647 Methyl bromide and Ethylene

 dibromide mixture, liquid

1660 Nitric oxide 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi)

1660 Nitric oxide, compressed

1670 Perchloromethyl mercaptan 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.8 mi)

1680 Potassium cyanide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.0 km (0.6 mi) 3.9 km (2.4 mi)

(when spilled in water)

1680 Potassium cyanide, solid

(when spilled in water)
Page 308

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1689 Sodium cyanide 60 m (200 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 390 m (1300 ft) 1.3 km (0.8 mi) 4.9 km (3.0 mi)

(when spilled in water)

1689 Sodium cyanide, solid

(when spilled in water)

1694 CA (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.7 km (1.0 mi) 4.2 km (2.6 mi)

1695 Chloroacetone, stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)

1697 CN (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.2 km (0.7 mi) 3.3 km (2.0 mi)

1698 Adamsite (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)

1698 DM (when used as a weapon)

1699 DA (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 180 m (600 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)

1716 Acetyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.3 km (1.4 mi)

(when spilled in water)

1717 Acetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 3.5 km (2.2 mi)

(when spilled in water)

1722 Allyl chlorocarbonate 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 2.0 km (1.2 mi) 3.8 km (2.4 mi)

1722 Allyl chloroformate

1724 Allyltrichlorosilane, stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 180 m (600 ft) 1.8 km (1.2 mi) 5.4 km (3.4 mi)

(when spilled in water)

1725 Aluminum bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.6 km (1.6 mi)

(when spilled in water)

1726 Aluminum chloride, anhydrous 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 120 m (400 ft) 1.2 km (0.7 mi) 4.5 km (2.8 mi)

(when spilled in water)

1728 Amyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi)

(when spilled in water)
"+" means distance can be larger in certain atmospheric conditions

Page 309

1732 Antimony pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 180 m (600 ft) 1.9 km (1.2 mi) 5.4 km (3.4 mi)

(when spilled in water)

1741 Boron trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.7 km (1.1 mi)

1744 Bromine 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

1744 Bromine, solution

1745 Bromine pentafluoride 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)

(when spilled on land)

1745 Bromine pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.6 km (4.1 mi)

(when spilled in water)

1746 Bromine trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.8 km (1.1 mi) 4.8 km (3.0 mi)

(when spilled on land)

1746 Bromine trifluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.8 km (3.6 mi)

(when spilled in water)

1747 Butyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)

(when spilled in water)

1749 Chlorine trifluoride 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 8.1 km (5.1 mi)

1752 Chloroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 2.6 km (1.6 mi)

(when spilled on land)

1752 Chloroacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.5 km (1.0 mi)

(when spilled in water)

1754 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)

(when spilled on land)

1754 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

(when spilled in water)

1754 Chlorosulfonic acid and Sulfur 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

trioxide mixture

(when spilled on land)

1754 Chlorosulfonic acid and Sulfur 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

 trioxide mixture

(when spilled in water)
Page 310

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1754 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)

(when spilled on land)

1754 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

(when spilled in water)

1754 Chlorosulphonic acid and 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

Sulphur trioxide mixture

(when spilled on land)

1754 Chlorosulphonic acid and 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

 Sulphur trioxide mixture

(when spilled in water)

1754 Sulfur trioxide and Chlorosulfonic 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

 acid mixture (when spilled on land)

1754 Sulfur trioxide and Chlorosulfonic 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

acid mixture (when spilled in water)

1754 Sulphur trioxide and 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

Chlorosulphonic acid mixture

(when spilled on land)

1754 Sulphur trioxide and 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.8 km (1.7 mi)

Chlorosulphonic acid mixture

(when spilled in water)

1758 Chromium oxychloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)

(when spilled in water)

1763 Cyclohexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)

(when spilled in water)

1766 Dichlorophenyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.7 km (3.6 mi)

(when spilled in water)
"+" means distance can be larger in certain atmospheric conditions

Page 311

1767 Diethlydichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

(when spilled in water)

1769 Diphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)

(when spilled in water)

1771 Dodecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.2 mi)

(when spilled in water)

1777 Fluorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.4 km (2.1 mi)

(when spilled in water)

1777 Fluorosulphonic acid

(when spilled in water)

1784 Hexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 3.8 km (2.4 mi)

(when spilled in water)

1799 Nonyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi)

(when spilled in water)

1800 Octadecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)

(when spilled in water)

1801 Octyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi)

(when spilled in water)

1804 Phenyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.2 km (1.4 mi) 6.4 km (4.0 mi)

(when spilled in water)

1806 Phosphorus pentachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.1 km (1.9 mi)

(when spilled in water)

1809 Phosphorus trichloride 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 150 m (500 ft) 1.5 km (1.0 mi) 3.5 km (2.2 mi)

(when spilled on land)

1809 Phosphorus trichloride 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.8 km (3.0 mi)

(when spilled in water)

1810 Phosphorus oxychloride 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.0 km (0.7 mi) 2.2 km (1.4 mi)

(when spilled on land)

1810 Phosphorus oxychloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 240 m (800 ft) 2.3 km (1.5 mi) 6.3 km (3.9 mi)

(when spilled in water)
Page 312

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1816 Propyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.3 km (0.8 mi) 4.1 km (2.6 mi)

(when spilled in water)

1818 Silicon tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.5 km (1.0 mi) 4.6 km (2.9 mi)

(when spilled in water)

1828 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi)

(when spilled on land)

1828 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi)

(when spilled in water)

1828 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.7 km (1.1 mi)

(when spilled on land)

1828 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.4 km (0.9 mi) 4.9 km (3.0 mi)

(when spilled in water)

1829 Sulfur trioxide 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

1829 Sulfur trioxide, inhibited

1829 Sulfur trioxide, stabilized

1829 Sulfur trioxide, uninhibited

1829 Sulphur trioxide

1829 Sulphur trioxide, inhibited

1829 Sulphur trioxide, stabilized

1829 Sulphur trioxide, uninhibited

1831 Sulfuric acid, fuming 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 330 m (1000 ft) 2.5 km (1.5 mi) 6.5 km (4.0 mi)

1831 Sulfuric acid, fuming, with not

 less than 30% free Sulfur trioxide

1831 Sulphuric acid, fuming

1831 Sulphuric acid, fuming, with not

 less than 30% free Sulphur trioxide
"+" means distance can be larger in certain atmospheric conditions

Page 313

1834 Sulfuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi)

(when spilled on land)

1834 Sulfuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)

(when spilled in water)

1834 Sulphuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi)

(when spilled on land)

1834 Sulphuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.9 km (1.8 mi)

(when spilled in water)

1836 Thionyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 90 m (300 ft) 1.0 km (0.6 mi) 2.2 km (1.4 mi)

(when spilled on land)

1836 Thionyl chloride 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 450 m (1500 ft) 4.5 km (2.8 mi) 10.5 km (6.5 mi)

(when spilled in water)

1838 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

(when spilled on land)

1838 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 3.7 km (2.3 mi)

(when spilled in water)

1859 Silicon tetrafluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

1859 Silicon tetrafluoride, compressed

1892 ED (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 120 m (400 ft) 1.3 km (0.8 mi) 2.6 km (1.6 mi)

1892 Ethyldichloroarsine 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)

1898 Acetyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.8 km (1.1 mi)

(when spilled in water)

1911 Diborane 60 m (200 ft) 0.4 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.8 km (1.1 mi) 5.4 km (3.4 mi)

1911 Diborane, compressed

1923 Calcium dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

(when spilled in water)

1923 Calcium hydrosulfite

(when spilled in water)

1923 Calcium hydrosulphite

(when spilled in water)
Page 314

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1931 Zinc dithionite 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)

 (when spilled in water)

1931 Zinc hydrosulfite

(when spilled in water)

1931 Zinc hydrosulphite

(when spilled in water)

1953 Compressed gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

poisonous, n.o.s. (Inhalation

Hazard Zone A)

1953 Compressed gas, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone B)

1953 Compressed gas, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone C)

1953 Compressed gas, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone D)

1953 Compressed gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

toxic, n.o.s. (Inhalation

Hazard Zone A)

1953 Compressed gas, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

toxic, n.o.s. (Inhalation

Hazard Zone B)

1953 Compressed gas, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

toxic, n.o.s. (Inhalation

Hazard Zone C)
"+" means distance can be larger in certain atmospheric conditions

Page 315

1953 Compressed gas, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

toxic, n.o.s. (Inhalation

Hazard Zone D)

1953 Compressed gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

flammable, n.o.s.

1953 Compressed gas, poisonous,

 flammable, n.o.s. (Inhalation

 Hazard Zone A)

1953 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, n.o.s. (Inhalation

Hazard Zone B)

1953 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, n.o.s. (Inhalation

Hazard Zone C)

1953 Compressed gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, n.o.s. (Inhalation

Hazard Zone D)

1953 Compressed gas, toxic, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

flammable, n.o.s.

1953 Compressed gas, toxic,

 flammable, n.o.s. (Inhalation

 Hazard Zone A)

1953 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, n.o.s. (Inhalation

Hazard Zone B)

1953 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, n.o.s. (Inhalation

Hazard Zone C)

1953 Compressed gas, toxic, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, n.o.s. (Inhalation

Hazard Zone D)
Page 316

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1953 Liquefied gas, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

poisonous, n.o.s.

1953 Liquefied gas, flammable,

 poisonous, n.o.s. (Inhalation

 Hazard Zone A)

1953 Liquefied gas, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone B)

1953 Liquefied gas, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone C)

1953 Liquefied gas, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

poisonous, n.o.s. (Inhalation

Hazard Zone D)

1953 Liquefied gas, flammable, toxic, n.o.s. 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

1953 Liquefied gas, flammable, toxic, n.o.s.

(Inhalation Hazard Zone A)

1953 Liquefied gas, flammable, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

(Inhalation Hazard Zone B)

1953 Liquefied gas, flammable, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

1953 Liquefied gas, flammable, toxic, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

(Inhalation Hazard Zone D)

1955 Compressed gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

1955 Compressed gas, poisonous, n.o.s.

(Inhalation Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 317

1955 Compressed gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)

1955 Compressed gas, poisonous, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

1955 Compressed gas, poisonous, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

1955 Compressed gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

1955 Compressed gas, toxic, n.o.s.

 (Inhalation Hazard Zone A)

1955 Compressed gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)

1955 Compressed gas, toxic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

1955 Compressed gas, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

1955 Liquefied gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

1955 Liquefied gas, poisonous, n.o.s.

 (Inhalation Hazard Zone A)

1955 Liquefied gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)

1955 Liquefied gas, poisonous, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

1955 Liquefied gas, poisonous, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

1955 Liquefied gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

1955 Liquefied gas, toxic, n.o.s.

 (Inhalation Hazard Zone A)

1955 Liquefied gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)
Page 318

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

1955 Liquefied gas, toxic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

1955 Liquefied gas, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

1955 Organic phosphate compound 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi)

mixed with compressed gas

1955 Organic phosphate mixed with

 compressed gas

1955 Organic phosphorus compound

 mixed with compressed gas

1967 Insecticide gas, poisonous, n.o.s. 120 m (400 ft) 1.0 km (0.7 mi) 3.4 km (2.1 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.6 km (6.0 mi)

1967 Insecticide gas, toxic, n.o.s.

1967 Parathion and compressed gas

mixture

1975 Dinitrogen tetroxide and Nitric 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi)

oxide mixture

1975 Nitric oxide and Dinitrogen

 tetroxide mixture

1975 Nitric oxide and Nitrogen dioxide

 mixture

1975 Nitric oxide and Nitrogen

 tetroxide mixture

1975 Nitrogen dioxide and Nitric oxide

 mixture

1975 Nitrogen tetroxide and Nitric

 oxide mixture

1994 Iron pentacarbonyl 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 3.0 km (1.9 mi)

2004 Magnesium diamide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.9 km (1.8 mi)

(when spilled in water)
"+" means distance can be larger in certain atmospheric conditions

Page 319

2011 Magnesium phosphide 60 m (200 ft) 0.5 km (0.4 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 7.5 km (4.7 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

2012 Potassium phosphide 60 m (200 ft) 0.4 km (0.3 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

2013 Strontium phosphide 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 500 m (1600 ft) 4.6 km (2.9 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

2032 Nitric acid, fuming 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi)

2032 Nitric acid, red fuming

2186 Hydrogen chloride, refrigerated liquid 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 360 m (1200 ft) 3.6 km (2.2 mi) 10.4 km (6.5 mi)

2188 Arsine 60 m (200 ft) 0.6 km (0.4 mi) 3.0 km (1.9 mi) 420 m (1400 ft) 4.1 km (2.6 mi) 9.5 km (5.9 mi)

2188 SA (when used as a weapon) 60 m (200 ft) 0.9 km (0.5 mi) 2.5 km (1.5 mi) 420 m (1300 ft) 4.1 km (2.5 mi) 8.1 km (5.0 mi)

2189 Dichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

2190 Oxygen difluoride 600 m (2000ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2190 Oxygen difluoride, compressed

2191 Sulfuryl fluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

2191 Sulphuryl fluoride

2192 Germane 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.0 km (1.9 mi)

2194 Selenium hexafluoride 90 m (300 ft) 0.7 km (0.5 mi) 3.2 km (2.0 mi) 450 m (1500 ft) 4.4 km (2.7 mi) 9.0 km (5.6 mi)

2195 Tellurium hexafluoride 90 m (300 ft) 1.0 km (0.6 mi) 4.0 km (2.5 mi) 600 m (2000 ft) 6.0 km (3.7 mi) 11.0+ km (7.0+ mi)

2196 Tungsten hexafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.1 km (0.7 mi) 120 m (400 ft) 1.0 km (0.6 mi) 3.7 km (2.3 mi)

2197 Hydrogen iodide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 120 m (400 ft) 1.3 km (0.8 mi) 3.7 km (2.3 mi)

2198 Phosphorus pentafluoride 30 m (100 ft) 0.3 km (0.2 mi) 1.6 km (1.0 mi) 180 m (600 ft) 1.6 km (1.0 mi) 4.6 km (2.9 mi)

2198 Phosphorus pentafluoride,

 compressed

2199 Phosphine 60 m (200 ft) 0.7 km (0.4 mi) 3.1 km (1.9 mi) 450 m (1400 ft) 4.3 km (2.7 mi) 9.6 km (6.0 mi)

2202 Hydrogen selenide, anhydrous 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)
Page 320

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

2204 Carbonyl sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 3.0 km (1.9 mi) 8.1 km (5.0 mi)

2204 Carbonyl sulphide

2232 Chloroacetaldehyde 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)

2232 2-Chloroethanal

2334 Allylamine 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 2.5 km (1.5 mi)

2337 Phenyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)

2382 1,2-Dimethylhydrazine 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi)

2382 Dimethylhydrazine, symmetrical

2407 Isopropyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)

2417 Carbonyl fluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.1 km (0.7 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.6 km (2.3 mi)

2417 Carbonyl fluoride, compressed

2418 Sulfur tetrafluoride 60 m (200 ft) 0.7 km (0.4 mi) 3.2 km (2.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 10.6 km (6.6 mi)

2418 Sulphur tetrafluoride

2420 Hexafluoroacetone 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)

2421 Nitrogen trioxide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.9 km (1.2 mi)

2437 Methylphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi)

(when spilled in water)

2438 Trimethylacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

2442 Trichloroacetyl chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi) 120 m (400 ft) 1.2 km (0.8 mi) 2.2 km (1.4 mi)

2474 Thiophosgene 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 360 m (1200 ft) 3.6 km (2.3 mi) 6.8 km (4.2 mi)

2477 Methyl isothiocyanate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.7 mi)

2480 Methyl isocyanate 60 m (200 ft) 0.5 km (0.3 mi) 1.9 km (1.2 mi) 600 m (1800 ft) 5.4 km (3.3 mi) 11.0+ km (7.0+ mi)
"+" means distance can be larger in certain atmospheric conditions

Page 321

2481 Ethyl isocyanate 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)

2482 n-Propyl isocyanate 120 m (400 ft) 1.0 km (0.7 mi) 2.5 km (1.6 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)

2483 Isopropyl isocyanate 120 m (400 ft) 1.1 km (0.7 mi) 2.8 km (1.8 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2484 tert-Butyl isocyanate 90 m (300 ft) 1.0 km (0.6 mi) 2.4 km (1.5 mi) 1000 m (3000 ft) 8.4 km (5.2 mi) 11.0+ km (7.0+ mi)

2485 n-Butyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 8.0 km (5.0 mi)

2486 Isobutyl isocyanate 90 m (300 ft) 0.7 km (0.5 mi) 1.6 km (1.0 mi) 500 m (1600 ft) 4.7 km (3.0 mi) 7.8 km (4.8 mi)

2487 Phenyl isocyanate 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi)

2488 Cyclohexyl isocyanate 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.9 km (0.6 mi) 1.6 km (1.0 mi)

2495 Iodine pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 210 m (700 ft) 1.9 km (1.2 mi) 5.7 km (3.6 mi)

(when spilled in water)

2521 Diketene, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

2521 Diketene, stabilized

2534 Methylchlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

2548 Chlorine pentafluoride 30 m (100 ft) 0.3 km (0.2 mi) 1.7 km (1.1 mi) 240 m (800 ft) 2.4 km (1.5 mi) 7.4 km (4.6 mi)

2600 Carbon monoxide and Hydrogen 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)

mixture

2600 Carbon monoxide and Hydrogen

 mixture, compressed

2600 Hydrogen and Carbon monoxide

 mixture

2600 Hydrogen and Carbon monoxide

 mixture, compressed

2605 Methoxymethyl isocyanate 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi)

2606 Methyl orthosilicate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)

2644 Methyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi)

2646 Hexachlorocyclopentadiene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.5 km (0.3 mi)

2668 Chloroacetonitrile 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
Page 322

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

2676 Stibine 60 m (200 ft) 0.4 km (0.3 mi) 2.2 km (1.4 mi) 270 m (900 ft) 2.8 km (1.7 mi) 7.5 km (4.7 mi)

2691 Phosphorus pentabromide 30 m (100 ft) 0.1 km (0.1 mi) 0.7 km (0.4 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.8 km (1.7 mi)

(when spilled in water)

2692 Boron tribromide 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.3 km (0.8 mi)

(when spilled on land)

2692 Boron tribromide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.7 km (0.5 mi) 2.6 km (1.6 mi)

(when spilled in water)

2740 n-Propyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.7 km (0.5 mi) 1.5 km (0.9 mi)

2742 sec-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi)

2742 Isobutyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

2743 n-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)

2806 Lithium nitride 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.6 km (1.6 mi)

(when spilled in water)

2810 Buzz (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.0 km (1.2 mi)

2810 BZ (when used as a weapon)

2810 CS (when used as a weapon) 60 m (200 ft) 0.4 km (0.2 mi) 1.2 km (0.7 mi) 240 m (800 ft) 2.6 km (1.6 mi) 5.7 km (3.5 mi)

2810 DC (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.9 km (0.5 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.4 km (3.3 mi)

2810 GA (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1 km (1.9 mi)

2810 GB (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 GD (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)

2810 GF (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 240 m (800 ft) 2.3 km (1.4 mi) 5.2 km (3.2 mi)
"+" means distance can be larger in certain atmospheric conditions

Page 323

2810 H (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.2 km (0.7 mi)

2810 HD (when used as a weapon)

2810 HL (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)

2810 HN-1 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.3 km (0.8 mi)

2810 HN-2 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.2 km (0.7 mi)

2810 HN-3 (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi)

2810 L (Lewisite) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)

(when used as a weapon)

2810 Lewisite (when used as a weapon)

2810 Mustard (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi)

2810 Mustard Lewisite 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 90 m (300 ft) 1.0 km (0.6 mi) 1.8 km (1.1 mi)

(when used as a weapon)

2810 Poisonous liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 Poisonous liquid, n.o.s.

 (Inhalation Hazard Zone A)

2810 Poisonous liquid, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

(Inhalation Hazard Zone B)

2810 Poisonous liquid, organic, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 Poisonous liquid, organic, n.o.s.

 (Inhalation Hazard Zone A)

2810 Poisonous liquid, organic, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

(Inhalation Hazard Zone B)

2810 Sarin (when used as a weapon) 150 m (500 ft) 1.7 km (1.0 mi) 3.4 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 Soman (when used as a weapon) 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)

2810 Tabun (when used as a weapon) 30 m (100 ft) 0.4 km (0.2 mi) 0.7 km (0.4 mi) 150 m (500 ft) 1.7 km (1.0 mi) 3.1 km (1.9 mi)

2810 Thickened GD 90 m (300 ft) 0.9 km (0.5 mi) 1.8 km (1.1 mi) 800 m (2500 ft) 6.8 km (4.2 mi) 10.5 km (6.5 mi)

(when used as a weapon)
Page 324

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

2810 Toxic liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 Toxic liquid, n.o.s. (Inhalation

 Hazard Zone A)

2810 Toxic liquid, n.o.s. (Inhalation 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

Hazard Zone B)

2810 Toxic liquid, organic, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2810 Toxic liquid, organic, n.o.s.

 (Inhalation Hazard Zone A)

2810 Toxic liquid, organic, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

(Inhalation Hazard Zone B)

2810 VX (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.7 km (0.4 mi) 1.0 km (0.6 mi)

2811 CX (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 1.0 km (0.6 mi) 3.1 km (1.9 mi)

2826 Ethyl chlorothioformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.0 km (0.6 mi)

2845 Ethyl phosphonous dichloride, 30 m (100 ft) 0.4 km (0.2 mi) 0.8 km (0.5 mi) 210 m (700 ft) 1.9 km (1.2 mi) 3.6 km (2.2 mi)

anhydrous

2845 Methyl phosphonous dichloride 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)

2901 Bromine chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.3 km (3.9 mi)

2927 Ethyl phosphonothioic 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi)

dichloride, anhydrous

2927 Ethyl phosphorodichloridate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi)

2927 Poisonous liquid, corrosive, 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)

n.o.s.

2927 Poisonous liquid, corrosive, n.o.s.

(Inhalation Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 325

2927 Poisonous liquid, corrosive, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

(Inhalation Hazard Zone B)

2927 Toxic liquid, corrosive, organic, 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)

n.o.s.

2927 Toxic liquid, corrosive, organic,

n.o.s. (Inhalation Hazard Zone A)

2927 Toxic liquid, corrosive, organic, 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 180 m (600 ft) 1.6 km (1.0 mi) 2.9 km (1.8 mi)

n.o.s. (Inhalation Hazard Zone B)

2929 Poisonous liquid, flammable, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

2929 Poisonous liquid, flammable, n.o.s.

(Inhalation Hazard Zone A)

2929 Poisonous liquid, flammable, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

(Inhalation Hazard Zone B)

2929 Poisonous liquid, flammable, 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

organic, n.o.s.

2929 Poisonous liquid, flammable,

 organic, n.o.s. (Inhalation

 Hazard Zone A)

2929 Poisonous liquid, flammable, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

organic, n.o.s. (Inhalation

Hazard Zone B)

2929 Toxic liquid, flammable, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

2929 Toxic liquid, flammable, n.o.s.

(Inhalation Hazard Zone A)

2929 Toxic liquid, flammable, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

(Inhalation Hazard Zone B)

2929 Toxic liquid, flammable, organic, 150 m (500 ft) 1.3 km (0.8 mi) 3.3 km (2.1 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

2929 Toxic liquid, flammable, organic,

 n.o.s. (Inhalation Hazard Zone A)
Page 326

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

2929 Toxic liquid, flammable, organic, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

n.o.s. (Inhalation Hazard Zone B)

2977 Radioactive material, Uranium 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi)

hexafluoride, fissile

(when spilled in water)

2977 Uranium hexafluoride, fissile

containing more than 1%

Uranium-235

 (when spilled in water)

2978 Radioactive material, Uranium 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 90 m (300 ft) 0.7 km (0.5 mi) 3.3 km (2.1 mi)

hexafluoride

(when spilled in water)

2978 Radioactive material, Uranium

hexafluoride, non-fissile or

fissile-excepted

(when spilled in water)

2978 Uranium hexafluoride

(when spilled in water)

2978 Uranium hexafluoride, fissile-excepted

(when spilled in water)

2978 Uranium hexafluoride, low

specific activity

(when spilled in water)

2978 Uranium hexafluoride, non-fissile

(when spilled in water)

2985 Chlorosilanes, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)

corrosive, n.o.s.

(when spilled in water)

2985 Chlorosilanes, n.o.s.

(when spilled in water)
"+" means distance can be larger in certain atmospheric conditions

Page 327

2986 Chlorosilanes, corrosive, 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)

flammable, n.o.s.

(when spilled in water)

2986 Chlorosilanes, n.o.s.

(when spilled in water)

2987 Chlorosilanes, corrosive, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)

(when spilled in water)

2987 Chlorosilanes, n.o.s.

(when spilled in water)

2988 Chlorosilanes, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.3 km (0.8 mi) 3.9 km (2.4 mi)

(when spilled in water)

2988 Chlorosilanes, water-reactive,

flammable, corrosive, n.o.s.

(when spilled in water)

3023 2-Methyl-2-hepthanethiol 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)

3023 tert-Octyl mercaptan

3048 Aluminum phosphide pesticide 90 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 1000 m (3000 ft) 9.0 km (5.6 mi) 11.0+ km (7.0+ mi)

(when spilled in water)

3049 Metal alkyl halides, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)

(when spilled in water)

3049 Metal alkyl halides, water-reactive,

n.o.s. (when spilled in water)

3049 Metal aryl halides, n.o.s.

(when spilled in water)

3049 Metal aryl halides, water-reactive,

n.o.s. (when spilled in water)

3052 Aluminum alkyl halides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)

(when spilled in water)

3052 Aluminum alkyl halides, liquid

(when spilled in water)

3052 Aluminum alkyl halides, solid

(when spilled in water)

3057 Trifluoroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
Page 328

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3079 Methacrylonitrile, inhibited 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (02 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)

3079 Methacrylonitrile, stabilized

3083 Perchloryl fluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

3122 Poisonous liquid, oxidizing, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

3122 Poisonous liquid, oxidizing, n.o.s.

(Inhalation Hazard Zone A)

3122 Poisonous liquid, oxidizing, n.o.s. 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)

(Inhalation Hazard Zone B)

3122 Toxic liquid, oxidizing, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

3122 Toxic liquid, oxidizing, n.o.s.

(Inhalation Hazard Zone A)

3122 Toxic liquid, oxidizing, n.o.s. 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)

(Inhalation Hazard Zone B)

3123 Poisonous liquid, water-reactive, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

3123 Poisonous liquid, water-reactive,

n.o.s. (Inhalation Hazard Zone A)

3123 Poisonous liquid, water-reactive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

n.o.s. (Inhalation Hazard Zone B)

3123 Poisonous liquid, which in 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

contact with water emits

flammable gases, n.o.s.

3123 Poisonous liquid, which in contact

with water emits flammable gases,

n.o.s. (Inhalation Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 329

3123 Poisonous liquid, which in contact 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

with water emits flammable gases,

n.o.s. (Inhalation Hazard Zone B)

3123 Toxic liquid, water-reactive, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

3123 Toxic liquid, water-reactive,

n.o.s. (Inhalation Hazard Zone A)

3123 Toxic liquid, water-reactive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

n.o.s. (Inhalation Hazard Zone B)

3123 Toxic liquid, which in contact 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

with water emits flammable

gases, n.o.s.

3123 Toxic liquid, which in contact with

water emits flammable gases,

n.o.s. (Inhalation Hazard Zone A)

3123 Toxic liquid, which in contact with 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

water emits flammable gases,

n.o.s. (Inhalation Hazard Zone B)

3160 Liquefied gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

flammable, n.o.s.

3160 Liquefied gas, poisonous,

 flammable, n.o.s. (Inhalation

 Hazard Zone A)

3160 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, n.o.s. (Inhalation

Hazard Zone B)

3160 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, n.o.s. (Inhalation

Hazard Zone C)

3160 Liquefied gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, n.o.s. (Inhalation

Hazard Zone D)
Page 330

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3160 Liquefied gas, toxic, flammable, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

n.o.s.

3160 Liquefied gas, toxic, flammable,

 n.o.s. (Inhalation Hazard Zone A)

3160 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

n.o.s. (Inhalation Hazard Zone B)

3160 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

n.o.s. (Inhalation Hazard Zone C)

3160 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

n.o.s. (Inhalation Hazard Zone D)

3162 Liquefied gas, poisonous, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

3162 Liquefied gas, poisonous, n.o.s.

 (Inhalation Hazard Zone A)

3162 Liquefied gas, poisonous, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)

3162 Liquefied gas, poisonous, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)

3162 Liquefied gas, poisonous, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

3162 Liquefied gas, toxic, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

3162 Liquefied gas, toxic, n.o.s.

 (Inhalation Hazard Zone A)

3162 Liquefied gas, toxic, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone B)

3162 Liquefied gas, toxic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

(Inhalation Hazard Zone C)
"+" means distance can be larger in certain atmospheric conditions

Page 331

3162 Liquefied gas, toxic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

(Inhalation Hazard Zone D)

3246 Methanesulfonyl chloride 60 m (200 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 150 m (500 ft) 1.6 km (1.0 mi) 2.6 km (1.6 mi)

3246 Methanesulphonyl chloride

3275 Nitriles, poisonous, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)

n.o.s.

3275 Nitriles, toxic, flammable, n.o.s.

3276 Nitriles, poisonous, liquid, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 90 m (300 ft) 0.8 km (0.5 mi) 1.6 km (1.0 mi)

3276 Nitriles, poisonous, n.o.s.

3276 Nitriles, toxic, liquid, n.o.s.

3276 Nitriles, toxic, n.o.s.

3278 Organophosphorus compound, 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)

poisonous, liquid, n.o.s.

3278 Organophosphorus compound,

 poisonous, n.o.s.

3278 Organophosphorus compound,

 toxic, liquid, n.o.s.

3278 Organophosphorus compound,

 toxic, n.o.s.

3279 Organophosphorus compound, 60 m (200 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 330 m (1000 ft) 3.1 km (1.9 mi) 5.9 km (3.7 mi)

poisonous, flammable, n.o.s.

3279 Organophosphorus compound,

 toxic, flammable, n.o.s.

3280 Organoarsenic compound, liquid, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 210 m (700 ft) 2.1 km (1.3 mi) 5.1 km (3.2 mi)

3280 Organoarsenic compound, n.o.s.

3281 Metal carbonyls, liquid, n.o.s. 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi) 500 m (1600 ft) 4.7 km (2.9 mi) 9.8 km (6.1 mi)

3281 Metal carbonyls, n.o.s.

3287 Poisonous liquid, inorganic, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)

n.o.s.

3287 Poisonous liquid, inorganic,

 n.o.s. (Inhalation Hazard Zone A)

3287 Poisonous liquid, inorganic, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

n.o.s. (Inhalation Hazard Zone B)
Page 332

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3287 Toxic liquid, inorganic, n.o.s. 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)

3287 Toxic liquid, inorganic, n.o.s.

 (Inhalation Hazard Zone A)

3287 Toxic liquid, inorganic, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

(Inhalation Hazard Zone B)

3289 Poisonous liquid, corrosive, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)

inorganic, n.o.s.

3289 Poisonous liquid, corrosive,

 inorganic, n.o.s. (Inhalation

 Hazard Zone A)

3289 Poisonous liquid, corrosive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

inorganic, n.o.s. (Inhalation

Hazard Zone B)

3289 Toxic liquid, corrosive, 90 m (300 ft) 0.9 km (0.6 mi) 3.5 km (2.2 mi) 600 m (1800 ft) 5.3 km (3.3 mi) 11.0 km (6.9 mi)

inorganic, n.o.s.

3289 Toxic liquid, corrosive,

 inorganic, n.o.s. (Inhalation

 Hazard Zone A)

3289 Toxic liquid, corrosive, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

inorganic, n.o.s. (Inhalation

Hazard Zone B)

3294 Hydrogen cyanide, solution in 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 210 m (700 ft) 0.7 km (0.4 mi) 2.1 km (1.3 mi)

alcohol, with not more than

45% Hydrogen cyanide
"+" means distance can be larger in certain atmospheric conditions

Page 333

3300 Carbon dioxide and Ethylene 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

oxide mixture, with more than

87% Ethylene oxide

3300 Ethylene oxide and Carbon

 dioxide mixture, with more

 than 87% Ethylene oxide

3303 Compressed gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, n.o.s.

3303 Compressed gas, poisonous,

 oxidizing, n.o.s. (Inhalation

 Hazard Zone A)

3303 Compressed gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3303 Compressed gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3303 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3303 Compressed gas, toxic, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, n.o.s.

3303 Compressed gas, toxic,

 oxidizing, n.o.s. (Inhalation

 Hazard Zone A)

3303 Compressed gas, toxic, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3303 Compressed gas, toxic, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3303 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone D)
Page 334

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3304 Compressed gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

3304 Compressed gas, poisonous,

 corrosive, n.o.s. (Inhalation

 Hazard Zone A)

3304 Compressed gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 Compressed gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3304 Compressed gas, toxic, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

3304 Compressed gas, toxic,

 corrosive, n.o.s. (Inhalation

 Hazard Zone A)

3304 Compressed gas, toxic, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3304 Compressed gas, toxic, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3304 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone D)
"+" means distance can be larger in certain atmospheric conditions

Page 335

3305 Compressed gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

flammable, corrosive, n.o.s.

3305 Compressed gas, poisonous,

 flammable, corrosive, n.o.s.

 (Inhalation Hazard Zone A)

3305 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3305 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3305 Compressed gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3305 Compressed gas, toxic, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

flammable, corrosive, n.o.s.

3305 Compressed gas, toxic,

 flammable, corrosive, n.o.s.

 (Inhalation Hazard Zone A)

3305 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3305 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3305 Compressed gas, toxic, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3306 Compressed gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, corrosive, n.o.s.

3306 Compressed gas, poisonous,

 oxidizing, corrosive, n.o.s.

 (Inhalation Hazard Zone A)
Page 336

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3306 Compressed gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3306 Compressed gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3306 Compressed gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3306 Compressed gas, toxic, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, corrosive, n.o.s.

3306 Compressed gas, toxic,

 oxidizing, corrosive, n.o.s.

 (Inhalation Hazard Zone A)

3306 Compressed gas, toxic, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3306 Compressed gas, toxic, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3306 Compressed gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3307 Liquefied gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, n.o.s.

3307 Liquefied gas, poisonous,

 oxidizing, n.o.s. (Inhalation

 Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 337

3307 Liquefied gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone B)

3307 Liquefied gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone C)

3307 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

oxidizing, n.o.s. (Inhalation

Hazard Zone D)

3307 Liquefied gas, toxic, oxidizing, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

n.o.s.

3307 Liquefied gas, toxic, oxidizing,

 n.o.s. (Inhalation Hazard Zone A)

3307 Liquefied gas, toxic, oxidizing, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

n.o.s. (Inhalation Hazard Zone B)

3307 Liquefied gas, toxic, oxidizing, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

n.o.s. (Inhalation Hazard Zone C)

3307 Liquefied gas, toxic, oxidizing, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 120 m (400 ft) 1.2 km (0.8 mi) 3.8 km (2.4 mi)

n.o.s. (Inhalation Hazard Zone D)

3308 Liquefied gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

3308 Liquefied gas, poisonous,

 corrosive, n.o.s. (Inhalation

 Hazard Zone A)

3308 Liquefied gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3308 Liquefied gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3308 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone D)
Page 338

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3308 Liquefied gas, toxic, corrosive, n.o.s. 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

3308 Liquefied gas, toxic, corrosive,

 n.o.s. (Inhalation Hazard Zone A)

3308 Liquefied gas, toxic, corrosive, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 800 m (2500 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)

n.o.s. (Inhalation Hazard Zone B)

3308 Liquefied gas, toxic, corrosive, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

n.o.s. (Inhalation Hazard Zone C)

3308 Liquefied gas, toxic, corrosive, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

n.o.s. (Inhalation Hazard Zone D)

3309 Liquefied gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

flammable, corrosive, n.o.s.

3309 Liquefied gas, poisonous,

 flammable, corrosive, n.o.s.

 (Inhalation Hazard Zone A)

3309 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3309 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3309 Liquefied gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3309 Liquefied gas, toxic, flammable, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

3309 Liquefied gas, toxic, flammable,

 corrosive, n.o.s. (Inhalation

 Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 339

3309 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone B)

3309 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3309 Liquefied gas, toxic, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3310 Liquefied gas, poisonous, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, corrosive, n.o.s.

3310 Liquefied gas, poisonous,

 oxidizing, corrosive, n.o.s.

 (Inhalation Hazard Zone A)

3310 Liquefied gas, poisonous, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone B)

3310 Liquefied gas, poisonous, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone C)

3310 Liquefied gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

oxidizing, corrosive, n.o.s.

(Inhalation Hazard Zone D)

3310 Liquefied gas, toxic, oxidizing, 600 m (2000 ft) 5.9 km (3.7 mi) 11.0+ km (7.0+ mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

3310 Liquefied gas, toxic, oxidizing,

 corrosive, n.o.s. (Inhalation

 Hazard Zone A)

3310 Liquefied gas, toxic, oxidizing, 60 m (200 ft) 0.4 km (0.3 mi) 2.0 km (1.3 mi) 360 m (1200 ft) 3.5 km (2.2 mi) 8.8 km (5.5 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone B)
Page 340

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3310 Liquefied gas, toxic, oxidizing, 30 m (100 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone C)

3310 Liquefied gas, toxic, oxidizing, 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

corrosive, n.o.s. (Inhalation

Hazard Zone D)

3318 Ammonia solution, with more 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)

than 50% Ammonia

3355 Insecticide gas, poisonous, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

flammable, n.o.s

3355 Insecticide gas, poisonous,

flammable, n.o.s.

(Inhalation Hazard Zone A)

3355 Insecticide gas, poisonous, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, n.o.s.

(Inhalation Hazard Zone B)

3355 Insecticide gas, poisonous, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, n.o.s.

(Inhalation Hazard Zone C)

3355 Insecticide gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, n.o.s.

(Inhalation Hazard Zone D)

3355 Insecticide gas, toxic, 120 m (400 ft) 1.2 km (0.8 mi) 5.1 km (3.2 mi) 1000 m (3000 ft) 8.7 km (5.4 mi) 11.0+ km (7.0+ mi)

flammable, n.o.s

3355 Insecticide gas, toxic,

flammable, n.o.s.

(Inhalation Hazard Zone A)
"+" means distance can be larger in certain atmospheric conditions

Page 341

3355 Insecticide gas, toxic, 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.8 mi) 420 m (1400 ft) 4.0 km (2.5 mi) 10.8 km (6.7 mi)

flammable, n.o.s.

(Inhalation Hazard Zone B)

3355 Insecticide gas, toxic, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 240 m (800 ft) 2.4 km (1.5 mi) 6.4 km (4.0 mi)

flammable, n.o.s.

(Inhalation Hazard Zone C)

3355 Insecticide gas, toxic, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi)

flammable, n.o.s.

(Inhalation Hazard Zone D)

3381 Poisonous by inhalation liquid, n.o.s. 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

(Inhalation Hazard Zone A)

3381 Toxic by inhalation liquid, n.o.s.

 (Inhalation Hazard Zone A)

3382 Poisonous by inhalation liquid, n.o.s. 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

(Inhalation Hazard Zone B)

3382 Toxic by inhalation liquid, n.o.s.

 (Inhalation Hazard Zone B)

3383 Poisonous by inhalation liquid, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

flammable, n.o.s.

(Inhalation Hazard Zone A)

3383 Toxic by inhalation liquid,

flammable, n.o.s.

(Inhalation Hazard Zone A)

3384 Poisonous by inhalation liquid, 60 m (200 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi) 270 m (900 ft) 2.5 km (1.6 mi) 5.6 km (3.5 mi)

flammable, n.o.s.

(Inhalation Hazard Zone B)

3384 Toxic by inhalation liquid,

flammable, n.o.s.

(Inhalation Hazard Zone B)

3385 Poisonous by inhalation liquid, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

water-reactive, n.o.s.

(Inhalation Hazard Zone A)

3385 Toxic by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone A)
Page 342

TABLE OF INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES

SMALL SPILLS LARGE SPILLS

(From a small package or small leak from a large package) (From a large package or from many small packages)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringNIGHT

Kilometers (Miles)

DAY NAME OF MATERIAL Kilometers (Miles)

First

ISOLATE

in all Directions

Meters (Feet)

Then

PROTECT

persons Downwind duringDAY

Kilometers (Miles)

NIGHT

Kilometers (Miles)

ID

No.

3386 Poisonous by inhalation liquid, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

3386 Toxic by inhalation liquid,

water-reactive, n.o.s.

(Inhalation Hazard Zone B)

3387 Poisonous by inhalation liquid, 150 m (500 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)

oxidizing, n.o.s.

(Inhalation Hazard Zone A)

3387 Toxic by inhalation liquid,

oxidizing, n.o.s.

(Inhalation Hazard Zone A)

3388 Poisonous by inhalation liquid, 30 m (100 ft) 0.4 km (0.2mi) 1.4 km (0.9 mi) 270 m (900 ft) 2.7 km (1.7 mi) 6.9 km (4.3 mi)

oxidizing, n.o.s.

(Inhalation Hazard Zone B)

3388 Toxic by inhalation liquid,

oxidizing, n.o.s.

(Inhalation Hazard Zone B)

3389 Poisonous by inhalation liquid, 90 m (300 ft) 0.8 km (0.5 mi) 2.4 km (1.5 mi) 800 m (2500 ft) 6.2 km (3.9 mi) 11.0+ km (7.0+ mi)

corrosive, n.o.s.

(Inhalation Hazard Zone A)

3389 Toxic by inhalation liquid,

corrosive, n.o.s.

(Inhalation Hazard Zone A)

3390 Poisonous by inhalation liquid, 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi) 330 m (1100 ft) 3.3 km (2.1 mi) 7.3 km (4.6 mi)

corrosive, n.o.s.

(Inhalation Hazard Zone B)

3390 Toxic by inhalation liquid,

corrosive, n.o.s.

(Inhalation Hazard Zone B)
"+" means distance can be larger in certain atmospheric conditions

Page 343

See Next Page for Table of Water-Reactive Materials Which Produce Toxic Gases

3461 Aluminum alkyl halides, solid 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)

(when spilled in water)

9191 Chlorine dioxide, hydrate, frozen 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi)

(when spilled in water)

9192 Fluorine, refrigerated liquid 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 90 m (300 ft) 0.8 km (0.5 mi) 3.5 km (2.2 mi)

(cryogenic liquid)

9202 Carbon monoxide, refrigerated 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 90 m (300 ft) 0.7 km (0.4 mi) 2.4 km (1.5 mi)

liquid (cryogenic liquid)

9206 Methyl phosphonic dichloride 30 m (100 ft) 0.1km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)

9263 Chloropivaloyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)

9264 3,5-Dichloro-2,4,6- 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)

trifluoropyridine

9269 Trimethoxysilane 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.3 mi) 120 m (400 ft) 1.1 km (0.7 mi) 2.2 km (1.4 mi)
Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Page 344 Use this list only when material is spilled in water.

1162 155 Dimethyldichlorosilane HCl

1196 155 Ethyltrichlorosilane HCl

1242 139 Methyldichlorosilane HCl

1250 155 Methyltrichlorosilane HCl

1295 139 Trichlorosilane HCl

1298 155 Trimethylchlorosilane HCl

1305 155P Vinyltrichlorosilane HCl

1305 155P Vinyltrichlorosilane, inhibited HCl

1305 155P Vinyltrichlorosilane, stabilized HCl

1340 139 Phosphorus pentasulfide, free from yellow and white Phosphorus H2

S

1340 139 Phosphorus pentasulphide, free from yellow and white Phosphorus H2

S

1360 139 Calcium phosphide PH3

1384 135 Sodium dithionite H2S SO2

1384 135 Sodium hydrosulfite H2S SO2

1384 135 Sodium hydrosulphite H2S SO2

1397 139 Aluminum phosphide PH3

1412 139 Lithium amide NH3

1419 139 Magnesium aluminum phosphide PH3

1432 139 Sodium phosphide PH3

1541 155 Acetone cyanohydrin, stabilized HCN

1680 157 Potassium cyanide HCN

1680 157 Potassium cyanide, solid HCN

1689 157 Sodium cyanide HCN

1689 157 Sodium cyanide, solid HCN
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Use this list only when material is spilled in water. Page 345

1716 156 Acetyl bromide HBr

1717 155 Acetyl chloride HCl

1724 155 Allyltrichlorosilane, stabilized HCl

1725 137 Aluminum bromide, anhydrous HBr

1726 137 Aluminum chloride, anhydrous HCl

1728 155 Amyltrichlorosilane HCl

1732 157 Antimony pentafluoride HF

1745 144 Bromine pentafluoride HF Br2

1746 144 Bromine trifluoride HF Br2

1747 155 Butyltrichlorosilane HCl

1752 156 Chloroacetyl chloride HCl

1754 137 Chlorosulfonic acid HCl

1754 137 Chlorosulfonic acid and Sulfur trioxide mixture HCl

1754 137 Chlorosulphonic acid HCl

1754 137 Chlorosulphonic acid and Sulphur trioxide mixture HCl

1754 137 Sulfur trioxide and Chlorosulfonic acid HCl

1754 137 Sulphur trioxide and Chlorosulphonic acid HCl

1758 137 Chromium oxychloride HCl

1763 156 Cyclohexyltrichlorosilane HCl

1766 156 Dichlorophenyltrichlorosilane HCl

1767 155 Diethyldichlorosilane HCl

1769 156 Diphenyldichlorosilane HCl

1771 156 Dodecyltrichlorosilane HCl

1777 137 Fluorosulfonic acid HF
Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Page 346 Use this list only when material is spilled in water.

1777 137 Fluorosulphonic acid HF

1784 156 Hexyltrichlorosilane HCl

1799 156 Nonyltrichlorosilane HCl

1800 156 Octadecyltrichlorosilane HCl

1801 156 Octyltrichlorosilane HCl

1804 156 Phenyltrichlorosilane HCl

1806 137 Phosphorus pentachloride HCl

1809 137 Phosphorus trichloride HCl

1810 137 Phosphorus oxychloride HCl

1816 155 Propyltrichlorosilane HCl

1818 157 Silicon tetrachloride HCl

1828 137 Sulfur chlorides HCl SO2 H2

S

1828 137 Sulphur chlorides HCl SO2 H2

S

1834 137 Sulfuryl chloride HCl SO3

1834 137 Sulphuryl chloride HCl SO3

1836 137 Thionyl chloride HCl SO2

1838 137 Titanium tetrachloride HCl

1898 156 Acetyl iodide HI

1923 135 Calcium dithionite H2

S SO2

1923 135 Calcium hydrosulfite H2S SO2

1923 135 Calcium hydrosulphite H2S SO2

1931 171 Zinc dithionite H2S SO2

1931 171 Zinc hydrosulfite H2S SO2

1931 171 Zinc hydrosulphite H2S SO2
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Use this list only when material is spilled in water. Page 347

2004 135 Magnesium diamide NH3

2011 139 Magnesium phosphide PH3

2012 139 Potassium phosphide PH3

2013 139 Strontium phosphide PH3

2437 156 Methylphenyldichlorosilane HCI

2495 144 Iodine pentafluoride HF

2691 137 Phosphorus pentabromide HBr

2692 157 Boron tribromide HBr

2806 138 Lithium nitride NH3

2977 166 Radioactive material, Uranium hexafluoride, fissile HF

2977 166 Uranium hexafluoride, fissile containing more than 1% HF

Uranium-235

2978 166 Radioactive material, Uranium hexafluoride HF

2978 166 Radioactive material, Uranium hexafluoride, non-fissile or HF

fissile-excepted

2978 166 Uranium hexafluoride HF

2978 166 Uranium hexafluoride, fissile-excepted HF

2978 166 Uranium hexafluoride, low specific activity HF

2978 166 Uranium hexafluoride, non-fissile HF

2985 155 Chlorosilanes, flammable, corrosive, n.o.s. HCl

2985 155 Chlorosilanes, n.o.s. HCl

2986 155 Chlorosilanes, corrosive, flammable, n.o.s. HCl

2986 155 Chlorosilanes, n.o.s. HCl

2987 156 Chlorosilanes, corrosive, n.o.s. HCl

2987 156 Chlorosilanes, n.o.s. HCl
Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Page 348 Use this list only when material is spilled in water.

2988 139 Chlorosilanes, n.o.s. HCl

2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. HCl

3048 157 Aluminum phosphide pesticide PH3

3049 138 Metal alkyl halides, n.o.s. HCl

3049 138 Metal alkyl halides, water-reactive, n.o.s. HCl

3049 138 Metal aryl halides, n.o.s. HCl

3049 138 Metal aryl halides, water-reactive, n.o.s. HCl

3052 135 Aluminum alkyl halides HCl

3052 135 Aluminum alkyl halides, liquid HCl

3052 135 Aluminum alkyl halides, solid HCl

3461 135 Aluminum alkyl halides, solid HCl

9191 143 Chlorine dioxide, hydrate, frozen Cl2
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water

Chemical Symbols for TIH Gases:

Br 2 Bromine

C l 2 Chlorine

HBr Hydrogen bromide

HCl Hydrogen chloride

HCN Hydrogen cyanide

HF Hydrogen fluoride

HI Hydrogen iodide

H2

S Hydrogen sulfide

H2

S Hydrogen sulphide

N H3 Ammonia

PH3 Phosphine

S O2 Sulfur dioxide

S O2 Sulphur dioxide

S O3 Sulfur trioxide

S O3 Sulphur trioxide

ID Guide TIH Gas(es)

No. No. Name of Material Produced

TABLE OF WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES

Use this list only when material is spilled in water. Page 349

Page Intentionally Left Blank
Page 350

PROTECTIVE CLOTHING

Street Clothing and Work Uniforms. These garments, such as uniforms worn by police and

emergency medical services personnel, provide almost no protection from the harmful effects of

dangerous goods.

Structural Fire Fighters’ Protective Clothing (SFPC). This category of clothing, often

called turnout or bunker gear, means the protective clothing normally worn by fire fighters

during structural fire fighting operations. It includes a helmet, coat, pants, boots, gloves and

a hood to cover parts of the head not protected by the helmet and facepiece. This clothing

must be used with full-facepiece positive pressure self-contained breathing apparatus (SCBA).

This protective clothing should, at a minimum, meet the OSHA Fire Brigades Standard (29

CFR 1910.156). Structural fire fighters’ protective clothing provides limited protection from

heat and cold, but may not provide adequate protection from the harmful vapors or liquids

that are encountered during dangerous goods incidents. Each guide includes a statement

about the use of SFPC in incidents involving those materials referenced by that guide. Some

guides state that SFPC provides limited protection. In those cases, the responder wearing

SFPC and SCBA may be able to perform an expedient, that is quick “in-and-out”, operation.

However, this type of operation can place the responder at risk of exposure, injury or death.

The incident commander makes the decision to perform this operation only if an overriding

benefit can be gained (i.e., perform an immediate rescue, turn off a valve to control a leak,

etc.). The coverall-type protective clothing customarily worn to fight fires in forests or wildlands

is not SFPC and is not recommended nor referred to elsewhere in this guidebook.

Positive Pressure Self-Contained Breathing Apparatus (SCBA). This apparatus provides

a constant, positive pressure flow of air within the facepiece, even if one inhales deeply while

doing heavy work. Use apparatus certified by NIOSH and the Department of Labor/Mine

Safety and Health Administration in accordance with 42 CFR Part 84. Use it in accordance

with the requirements for respiratory protection specified in OSHA 29 CFR 1910.134

(Respiratory Protection) and/or 29 CFR 1910.156 (f) (Fire Brigades Standard). Chemicalcartridge respirators or other filtering masks are not acceptable substitutes for positive pressure

self-contained breathing apparatus. Demand-type SCBA does not meet the OSHA 29 CFR

1910.156 (f)(1)(i) of the Fire Brigades Standard.

Chemical Protective Clothing and Equipment. Safe use of this type of protective clothing

and equipment requires specific skills developed through training and experience. It is

generally not available to, or used by, first responders. This type of special clothing may

protect against one chemical, yet be readily permeated by chemicals for which it was not

designed. Therefore, protective clothing should not be used unless it is compatible with the

released material. This type of special clothing offers little or no protection against heat and/

or cold. Examples of this type of equipment have been described as (1) Vapor Protective Suits

(NFPA 1991), also known as Totally-Encapsulating Chemical Protective (TECP) Suits or Level

A* protection (OSHA 29 CFR 1910.120, Appendix A & B), and (2) Liquid-Splash Protective Suits

(NFPA 1992 & 1993), also known as Level B* or C* protection (OSHA 29 CFR 1910.120,
Page 351

Appendix A & B) or suits for chemical/biological terrorism incidents (NFPA 1994), class 1, 2 or 3

Ensembles. No single protective clothing material will protect you from all dangerous goods. Do

not assume any protective clothing is resistant to cold and/or heat or flame exposure unless it is

so certified by the manufacturer. (NFPA 1991 5-3 Flammability Resistance Test and 5-6 Cold

Temperature Performance Test)

* Consult glossary for additional protection levels under the heading “Protective Clothing”.
Page 352

FIRE AND SPILL CONTROL

FIRE CONTROL

Water is the most common and generally most available fire extinguishing agent. Exercise

caution in selecting a fire extinguishing method since there are many factors to be considered

in an incident. Water may be ineffective in fighting fires involving some materials; its

effectiveness depends greatly on the method of application.

Spill fires involving flammable liquids are generally controlled by applying a fire fighting foam

to the surface of the burning material. Fighting flammable liquid fires requires foam concentrate

which is chemically compatible with the burning material, correct mixing of the foam concentrate

with water and air, and careful application and maintenance of the foam blanket. There are

two general types of fire fighting foam: regular and alcohol-resistant. Examples of regular

foam are protein-base, fluoroprotein, and aqueous film forming foam (AFFF). Some flammable

liquids, including many petroleum products, can be controlled by applying regular foam.

Other flammable liquids, including polar solvents (flammable liquids which are water soluble)

such as alcohols and ketones, have different chemical properties. A fire involving these

materials cannot be easily controlled with regular foam and requires application of

alcohol-resistant foam. Polar-solvent fires may be difficult to control and require a higher

foam application rate than other flammable liquid fires (see NFPA/ANSI Standards 11 and

11A for further information). Refer to the appropriate guide to determine which type of foam

is recommended. Although it is impossible to make specific recommendations for flammable

liquids which have subsidiary corrosive or toxic hazards, alcohol-resistant foam may be

effective for many of these materials. The emergency response telephone number on the

shipping document, or the appropriate emergency response agency, should be contacted as

soon as possible for guidance on the proper fire extinguishing agent to use. The final selection

of the agent and method depends on many factors such as incident location, exposure hazards,

size of the fire, environmental concerns, as well as the availability of extinguishing agents

and equipment at the scene.

WATER REACTIVE MATERIALS

Water is sometimes used to flush spills and to reduce or direct vapors in spill situations.

Some of the materials covered by the guidebook can react violently or even explosively with

water. In these cases, consider letting the fire burn or leaving the spill alone (except to

prevent its spreading by diking) until additional technical advice can be obtained. The

applicable guides clearly warn you of these potentially dangerous reactions. These materials

require technical advice since

(1) water getting inside a ruptured or leaking container may cause an explosion;

(2) water may be needed to cool adjoining containers to prevent their rupturing

(exploding) or further spread of the fires;

(3) water may be effective in mitigating an incident involving a water-reactive material

only if it can be applied at a sufficient flooding rate for an extended period; and
Page 353

(4) the products from the reaction with water may be more toxic, corrosive, or

otherwise more undesirable than the product of the fire without water applied.

When responding to an incident involving water-reactive chemicals, take into account the

existing conditions such as wind, precipitation, location and accessibility to the incident, as

well as the availability of the agents to control the fire or spill. Because there are variables to

consider, the decision to use water on fires or spills involving water-reactive materials should

be based on information from an authoritative source; for example, a producer of the material,

who can be contacted through the emergency response telephone number or the appropriate

emergency response agency.

VAPOR CONTROL

Limiting the amount of vapor released from a pool of flammable or corrosive liquids is an

operational concern. It requires the use of proper protective clothing, specialized equipment,

appropriate chemical agents, and skilled personnel. Before engaging in vapor control, get

advice from an authoritative source as to the proper tactics.

There are several ways to minimize the amount of vapors escaping from pools of spilled

liquids, such as special foams, adsorbing agents, absorbing agents, and neutralizing agents.

To be effective, these vapor control methods must be selected for the specific material involved

and performed in a manner that will mitigate, not worsen, the incident.

Where specific materials are known, such as at manufacturing or storage facilities, it is

desirable for the dangerous goods response team to prearrange with the facility operators to

select and stockpile these control agents in advance of a spill. In the field, first responders

may not have the most effective vapor control agent for the material available. They are

likely to have only water and only one type of fire fighting foam on their vehicles. If the

available foam is inappropriate for use, they are likely to use water spray. Because the water

is being used to form a vapor seal, care must be taken not to churn or further spread the spill

during application. Vapors that do not react with water may be directed away from the site

using the air currents surrounding the water spray. Before using water spray or other methods

to safely control vapor emission or to suppress ignition, obtain technical advice, based on

specific chemical name identification.
Page 354

CRIMINAL/TERRORIST USE OF CHEMICAL/BIOLOGICAL/RADIOLOGICAL AGENTS

The following is intended to supply information to first responders for use in making a preliminary

assessment of a situation that they suspect involves criminal/terrorist use of chemical, biological

(CB) agents and/or radioactive materials. To aid in the assessment, a list of observable indicators

of the use and/or presence of a CB agent or radioactive material is provided in the following

paragraphs.

DIFFERENCES BETWEEN A CHEMICAL, BIOLOGICAL AND RADIOLOGICAL AGENT

Chemical and biological agents as well as radioactive materials can be dispersed in the air we

breathe, the water we drink, or on surfaces we physically contact. Dispersion methods may be

as simple as opening a container, using conventional (garden) spray devices, or as elaborate as

detonating an improvised explosive device.

Chemical Incidents are characterized by the rapid onset of medical symptoms (minutes to

hours) and easily observed signatures (colored residue, dead foliage, pungent odor, dead

insects and animals).

Biological Incidents are characterized by the onset of symptoms in hours to days. Typically,

there will be no characteristic signatures because biological agents are usually odorless and

colorless. Because of the delayed onset of symptoms in a biological incident, the area

affected may be greater due to the movement of infected individuals.

Radiological Incidents are characterized by the onset of symptoms, if any, in days to weeks or

longer. Typically, there will be no characteristic signatures because radioactive materials are

usually odorless and colorless. Specialized equipment is required to determine the size of the

affected area, and whether the level of radioactivity presents an immediate or long-term health

hazard. Because radioactivity is not detectable without special equipment, the affected area may

be greater due to the migration of contaminated individuals.

 At the levels created by most probable sources, not enough radiation would be generated to kill

people or cause severe illness. In a radiological incident generated by a “dirty bomb”, or

Radiological Dispersal Device (RDD), in which a conventional explosive is detonated to spread

radioactive contamination, the primary hazard is from the explosion. However, certain radioactive

materials dispersed in the air could contaminate up to several city blocks, creating fear and

possibly panic, and requiring potentially costly cleanup.

INDICATORS OF A POSSIBLE CHEMICAL INCIDENT

Dead animals/birds/fish Not just an occasional road kill, but numerous animals (wild

and domestic, small and large), birds, and fish in the same

area.
Page 355

INDICATORS OF A POSSIBLE CHEMICAL INCIDENT (Continued)

Lack of insect life If normal insect activity (ground, air, and/or water) is missing,

check the ground/water surface/shore line for dead insects.

If near water, check for dead fish/aquatic birds.

Unexplained odors Smells may range from fruity to flowery to sharp/pungent to

garlic/ horseradish-like to bitter almonds/peach kernels to

new mown hay. It is important to note that the particular odor

is completely out of character with its surroundings.

Unusual numbers of dying or Health problems including nausea, disorientation, difficulty

sick people (mass casualties) in breathing, convulsions, localized sweating, conjunctivitis

(reddening of eyes/nerve agent symptoms), erythema

(reddening of skin/vesicant symptoms) and death.

Pattern of casualties Casualties will likely be distributed downwind, or if indoors,

by the air ventilation system.

Blisters/rashes Numerous individuals experiencing unexplained water-like

blisters, weals (like bee stings), and/or rashes.

Illness in confined area Different casualty rates for people working indoors versus

outdoors dependent on where the agent was released.

Unusual liquid droplets Numerous surfaces exhibit oily droplets/film; numerous water

surfaces have an oily film. (No recent rain.)

Different looking areas Not just a patch of dead weeds, but trees, shrubs, bushes,

food crops, and/or lawns that are dead, discolored, or

withered. (No current drought.)

Low-lying clouds Low-lying cloud/fog-like condition that is not consistent with

its surroundings.

Unusual metal debris Unexplained bomb/munitions-like material, especially if it

contains a liquid.

INDICATORS OF A POSSIBLE BIOLOGICAL INCIDENT

Unusual numbers of sick or Any number of symptoms may occur. Casualties may

dying people or animals occur hours to days after an incident has occurred. The

time required before symptoms are observed is dependent

on the agent used.

Unscheduled and unusual Especially if outdoors during periods of darkness.

spray being disseminated

Abandoned spray devices Devices may not have distinct odors.
Page 356

INDICATORS OF A POSSIBLE RADIOLOGICAL INCIDENT

Radiation Symbols Containers may display a “propeller” radiation symbol.

Unusual metal debris Unexplained bomb/munitions-like material.

Heat-emitting material Material that is hot or seems to emit heat without any sign of

an external heat source.

Glowing material Strongly radioactive material may emit or cause

radioluminescence.

Sick people/animals In very improbable scenarios there may be unusual numbers

of sick or dying people or animals. Casualties may occur

hours to days or weeks after an incident has occurred. The

time required before symptoms are observed is dependent

on the radioactive material used, and the dose received.

Possible symptoms include skin reddening or vomiting.

PERSONAL SAFETY CONSIDERATIONS

When approaching a scene that may involve CB agents or radioactive materials, the most critical

consideration is the safety of oneself and other responders. Protective clothing and respiratory

protection of appropriate level of safety must be used. Be aware that the presence and identification

of CB or radioactive materials may not be verifiable, especially in the case of biological or

radiological agents. The following actions/measures to be considered are applicable to either a

chemical, biological or radiological incident. The guidance is general in nature, not all

encompassing, and its applicability should be evaluated on a case-by-case basis.

Approach and response strategies. Protect yourself and use a safe approach (minimize any

exposure time, maximize the distance between you and the item that is likely to harm you, use

cover as protection and wear appropriate personal protective equipment and respiratory

protection). Identify and estimate the hazard by using indicators as provided above. Isolate the

area and secure the scene; potentially contaminated people should be isolated and decontaminated

as soon as possible. To the extent possible, take measures to limit the spread of contamination.

In the event of a chemical incident, the fading of chemical odors is not necessarily an indication of

reduced vapor concentrations. Some chemicals deaden the senses giving the false perception

that the chemical is no longer present.

If there is any indication that an area may be contaminated with radioactive materials, including the

site of any non-accidental explosion, responder personnel should be equipped with radiation

detection equipment that would alert them if they are entering a radiologically compromised

environment, and should have received adequate training in its use. This equipment should be

designed in such a way that it can also alert the responders when an unacceptable ambient dose

rate or ambient dose has been reached.
Page 357

Decontamination measures. Emergency responders should follow standard decontamination

procedures (flush-strip-flush). Mass casualty decontamination should begin as soon as possible

by stripping (all clothing) and flushing (soap and water). If biological agents are involved or

suspected, careful washing and use of a brush are more effective. If chemical agents are

suspected, the most important and effective decontamination will be that done within the first one or

two minutes. If possible, further decontamination should be performed using a 0.5% hypochlorite

solution (1 part household bleach mixed with 9 parts water). If biological agents are suspected,

a contact time of 10 to 15 minutes should be allowed before rinsing. The solution can be used on

soft tissue wounds, but must not be used in eyes or open wounds of the abdomen, chest, brain,

or spine. For further information contact the agencies listed in this guidebook.

For persons contaminated with radioactive material, remove them to a low radiation area if

necessary. Remove their clothing and place it in a clearly marked sealed receptacle, such as a

plastic bag, for later testing. Use decontamination methods described above, but avoid breaking

the skin, e.g., from shaving, or overly vigorous brushing. External radiological contamination on

intact skin surface rarely causes a high enough dose to be a hazard to either the contaminated

person or the first responders. For this reason, except in very unusual circumstances, an injured

person who is also radiologically contaminated should be medically stabilized, taking care to

minimize the spread of the contamination to the extent possible, before decontamination measures

are initiated.

NOTE: The above information was developed in part by the Department of National Defence

(Canada) and the U.S. Department of the Army, Edgewood Arsenal.
Page 358

Glossary

Alcohol resistant foam A foam that is resistant to “polar” chemicals such as ketones and

esters which may break down other types of foam.

Biological agents Living organisms that cause disease, sickness and mortality in

humans. Anthrax and Ebola are examples of biological agents.

Refer to GUIDE 158.

Blister agents (vesicants) Substances that cause blistering of the skin. Exposure is through

liquid or vapor contact with any exposed tissue (eyes, skin, lungs).

Mustard (H), Distilled Mustard (HD), Nitrogen Mustard (HN) and

Lewisite (L) are blister agents.

Symptoms: Red eyes, skin irritation, burning of skin, blisters,

upper respiratory damage, cough, hoarseness.

Blood agents Substances that injure a person by interfering with cell respiration

(the exchange of oxygen and carbon dioxide between blood and

tissues). Hydrogen cyanide (AC) and Cyanogen chloride (CK)

are blood agents.

Symptoms: Respiratory distress, headache, unresponsiveness,

seizures, coma.

Burn Refers to either a chemical or thermal burn, the former may be

caused by corrosive substances and the latter by liquefied

cryogenic gases, hot molten substances, or flames.

Choking agents Substances that cause physical injury to the lungs. Exposure is

through inhalation. In extreme cases, membranes swell and lungs

become filled with liquid (pulmonary edema). Death results from

lack of oxygen; hence, the victim is “choked”. Phosgene (CG) is

a choking agent.

Symptoms: irritation to eyes/nose/throat, respiratory distress,

nausea and vomiting, burning of exposed skin.

CO2 Carbon dioxide gas.

Cold zone Area where the command post and support functions that are

necessary to control the incident are located. This is also referred

to as the clean zone, green zone or support zone in other documents.

(EPA Standard Operating Safety Guidelines, OSHA 29 CFR

1910.120, NFPA 472)
Page 359

Glossary

Combustible liquid Liquids which have a flash point greater than 60.5oC (141oF) and

below 93oC (200oF). U.S. regulations permit a flammable liquid

with a flash point between 38o

C (100oF) and 60.5oC (141oF) to be

reclassed as a combustible liquid.

Compatibility Group Letters identify explosives that are deemed to be compatible. Class

1 materials are considered to be “compatible” if they can be

transported together without significantly increasing either the

probability of an incident or, for a given quantity, the magnitude

of the effects of such an incident.

A Substances which are expected to mass detonate very

soon after fire reaches them.

B Articles which are expected to mass detonate very soon

after fire reaches them.

C Substances or articles which may be readily ignited and

burn violently without necessarily exploding.

D Substances or articles which may mass detonate (with

blast and/or fragment hazard) when exposed to fire.

E&F Articles which may mass detonate in a fire.

G Substances and articles which may mass explode and

give off smoke or toxic gases.

H Articles which in a fire may eject hazardous projectiles and

dense white smoke.

J Articles which may mass explode.

K Articles which in a fire may eject hazardous projectiles and

toxic gases.

L Substances and articles which present a special risk and

could be activated by exposure to air or water.

N Articles which contain only extremely insensitive

detonating substances and demonstrate a negligible

probability of accidental ignition or propagation.

S Packaged substances or articles which, if accidentally

initiated, produce effects that are usually confined to the

immediate vicinity.
Page 360

Glossary

Control zones Designated areas at dangerous goods incidents, based on safety

and the degree of hazard. Many terms are used to describe control

zones; however, in this guidebook, these zones are defined as the

hot/exclusion/restricted zone, warm/contamination reduction/limited

access zone, and cold/support/clean zone. (EPA Standard

Operating Safety Guidelines, OSHA 29 CFR 1910.120, NFPA 472)

Cryogenic liquid A refrigerated, liquefied gas that has a boiling point colder than

-90o

C (-130oF) at atmospheric pressure.

Dangerous Water Produces significant toxic gas when it comes in contact with water.

Reactive Material

Decomposition products Products of a chemical or thermal break-down of a substance.

Decontamination The removal of dangerous goods from personnel and equipment to

the extent necessary to prevent potential adverse health effects.

Always avoid direct or indirect contact with dangerous goods;

however, if contact occurs, personnel should be decontaminated as

soon as possible. Since the methods used to decontaminate personnel

and equipment differ from one chemical to another, contact the

chemical manufacturer, through the agencies listed on the inside

back cover, to determine the appropriate procedure. Contaminated

clothing and equipment should be removed after use and stored in

a controlled area (warm/contamination reduction/limited access zone)

until cleanup procedures can be initiated. In some cases, protective

clothing and equipment cannot be decontaminated and must be

disposed of in a proper manner.

Dry chemical A preparation designed for fighting fires involving flammable liquids,

pyrophoric substances and electrical equipment. Common types

contain sodium bicarbonate or potassium bicarbonate.

Edema The accumulation of an excessive amount of watery fluid in cells and

tissues. Pulmonary edema is an excessive buildup of water in the

lungs, for instance, after inhalation of a gas that is corrosive to lung

tissue.

ERPG(s) Emergency Response Planning Guideline(s). Values intended

to provide estimates of concentration ranges above which one

could reasonably anticipate observing adverse health effects;

see ERPG-1, ERPG-2 and ERPG-3.
Page 361

Glossary

ERPG-1 The maximum airborne concentration below which it is believed

nearly all individuals could be exposed for up to 1 hour without

experiencing more than mild, transient adverse health effects or

without perceiving a clearly defined objectionable odor.

ERPG-2 The maximum airborne concentration below which it is believed

nearly all individuals could be exposed for up to 1 hour without

experiencing or developing irreversible or other serious health

effects or symptoms that could impair an individual’s ability to take

protective action.

ERPG-3 The maximum airborne concentration below which it is believed

nearly all individuals could be exposed for up to 1 hour without

experiencing or developing life-threatening health effects.

Flammable liquid A liquid that has a flash point of 60.5oC (141oF) or lower.

Flash point Lowest temperature at which a liquid or solid gives off vapor in such

a concentration that, when the vapor combines with air near the

surface of the liquid or solid, a flammable mixture is formed. Hence,

the lower the flash point, the more flammable the material.

Hazard zones (Inhalation HAZARD ZONE A: Gases: LC50 of less than or equal to 200

Hazard Zones) ppm,

 Liquids: V equal to or greater than 500

 LC50 and LC50 less than or equal to 200

 ppm,

HAZARD ZONE B: Gases: LC50 greater than 200 ppm and

 less than or equal to 1000 ppm,

 Liquids: V equal to or greater than 10

 LC50; LC50 less than or equal to 1000 ppm

 and criteria for Hazard Zone A are not met.

HAZARD ZONE C: LC50 greater than 1000 ppm and less than or

 equal to 3000 ppm,

HAZARD ZONE D: LC50 greater than 3000 ppm and less than or

 equal to 5000 ppm.

Hot zone Area immediately surrounding a dangerous goods incident which

extends far enough to prevent adverse effects from released

dangerous goods to personnel outside the zone. This zone is also

referred to as exclusion zone, red zone or restricted zone in other

documents. (EPA Standard Operating Safety Guidelines, OSHA 29

CFR 1910.120, NFPA 472)
Page 362

Glossary

Immiscible In this guidebook, means that a material does not mix readily with water.

LC50 Lethal concentration 50. The concentration of a material administered

by inhalation that is expected to cause the death of 50% of an

experimental animal population within a specified time.

(Concentration is reported in either ppm or mg/m3)

Mass explosion Explosion which affects almost the entire load virtually

instantaneously.

mg/m3 Milligrams of a material per cubic meter of air.

Miscible In this guidebook, means that a material mixes readily with water.

mL/m3 Milliliters of a material per cubic meter of air. (1 mL/m3

 equals 1

ppm)

Nerve agents Substances that interfere with the central nervous system. Exposure

is primarily through contact with the liquid (via skin and eyes) and

secondarily through inhalation of the vapor. Tabun (GA), Sarin

(GB), Soman (GD) and VX are nerve agents.

Symptoms: Pinpoint pupils, extreme headache, severe tightness in

the chest, dyspnea, runny nose, coughing, salivation, unresponsiveness,

seizures.

Non-polar See “Immiscible”.

n.o.s. These letters refer to not otherwise specified. The entries which use

this description are generic names such as “Corrosive liquid, n.o.s.”

This means that the actual chemical name for that corrosive liquid is

not listed in the regulations; therefore, a generic name must be used

to describe it on shipping papers.

Noxious In this guidebook, means that a material may be harmful or injurious

to health or physical well-being.

Oxidizer A chemical which supplies its own oxygen and which helps other

combustible material burn more readily.
Page 363

P The letter “P” following a guide number in the yellow-bordered and

blue-bordered pages identifies a material which may polymerize

violently under high temperature conditions or contamination with

other products. This polymerization will produce heat and high

pressure buildup in containers which may explode or rupture. (See

polymerization below.)

pH pH is a value that represents the acidity or alkalinity of a water solution.

Pure water has a pH of 7. A pH value below 7 indicates an acid solution

(a pH of 1 is extremely acidic). A pH above 7 indicates an alkaline

solution (a pH of 14 is extremely alkaline). Acids and alkalies (bases)

are commonly referred to as corrosive materials.

PIH Poison Inhalation Hazard. Term used to describe gases and volatile

liquids that are toxic when inhaled. (Same as TIH)

Polar See “Miscible”.

Polymerization This term describes a chemical reaction which is generally associated

with the production of plastic substances. Basically, the individual

molecules of the chemical (liquid or gas) react with each other to

produce what can be described as a long chain. These chains can

be formed in many useful applications. A well known example is the

styrofoam (polystyrene) coffee cup which is formed when liquid

molecules of styrene react with each other or polymerize forming a

solid, therefore changing the name from styrene to polystyrene

(poly means many).

ppm Parts per million. (1 ppm equals 1 mL/m3)

Protective clothing Includes both respiratory and physical protection. One cannot assign

a level of protection to clothing or respiratory devices separately.

These levels were accepted and defined by response organizations

such as U.S. Coast Guard, NIOSH, and U.S. EPA.

Level A: SCBA plus totally encapsulating chemical resistant clothing

(permeation resistant).

Level B: SCBA plus hooded chemical resistant clothing (splash suit).

Level C: Full or half-face respirator plus hooded chemical resistant

clothing (splash suit).

Level D: Coverall with no respiratory protection.

Pyrophoric A material which ignites spontaneously upon exposure to air (or oxygen).

Glossary
Page 364

Glossary

Radioactivity The property of some substances to emit invisible and potentially

harmful radiation.

Radiation Authority As referred to in GUIDES 161 through 166 for radioactive materials,

the Radiation Authority is either a Federal, state/provincial agency

or state/province designated official. The responsibilities of this

authority include evaluating radiological hazard conditions during

normal operations and during emergencies. If the identity and

telephone number of the authority are not known by emergency

responders, or included in the local response plan, the information

can be obtained from the agencies listed on the inside back cover.

They maintain a periodically updated list of radiation authorities.

Refrigerated liquid See “Cryogenic liquid”.

Straight (solid) stream Method used to apply or distribute water from the end of a hose.

The water is delivered under pressure for penetration. In an efficient

straight (solid) stream, approximately 90% of the water passes

through an imaginary circle 38 cm (15 inches) in diameter at the

breaking point. Hose (solid or straight) streams are frequently used

to cool tanks and other equipment exposed to flammable liquid fires,

or for washing burning spills away from danger points. However,

straight streams will cause a spill fire to spread if improperly used or

when directed into open containers of flammable and combustible

liquids.

TIH Toxic Inhalation Hazard. Term used to describe gases and volatile

liquids that are toxic when inhaled. (Same as PIH)

V Saturated vapor concentration in air of a material in mL/m3 (volatility)

at 20o

C and standard atmospheric pressure.

Vapor density Weight of a volume of pure vapor or gas (with no air present)

compared to the weight of an equal volume of dry air at the same

temperature and pressure. A vapor density less than 1 (one) indicates

that the vapor is lighter than air and will tend to rise. A vapor density

greater than 1 (one) indicates that the vapor is heavier than air and

may travel along the ground.

Vapor pressure Pressure at which a liquid and its vapor are in equilibrium at a given

temperature. Liquids with high vapor pressures evaporate rapidly.
Page 365

Glossary

Viscosity Measure of a liquid’s internal resistance to flow. This property is

important because it indicates how fast a material will leak out through

holes in containers or tanks.

Warm zone Area between Hot and Cold zones where personnel and equipment

decontamination and hot zone support take place. It includes control

points for the access corridor and thus assists in reducing the spread

of contamination. Also referred to as the contamination reduction

corridor (CRC), contamination reduction zone (CRZ), yellow zone

or limited access zone in other documents. (EPA Standard Operating

Safety Guidelines, OSHA 29 CFR 1910.120, NFPA 472)

Water-sensitive Substances which may produce flammable and/or toxic

decomposition products upon contact with water.

Water spray (fog) Method or way to apply or distribute water. The water is finely

divided to provide for high heat absorption. Water spray patterns

can range from about 10 to 90 degrees. Water spray streams

can be used to extinguish or control the burning of a fire or to

provide exposure protection for personnel, equipment, buildings,

etc. (This method can be used to absorb vapors, knockdown vapors or disperse vapors. Direct a water spray (fog),

rather than a straight (solid) stream, into the vapor cloud to

accomplish any of the above).

Water spray is particularly effective on fires of flammable liquids and

volatile solids having flash points above 37.8o

C (100oF).

Regardless of the above, water spray can be used successfully on

flammable liquids with low flash points. The effectiveness depends

particularly on the method of application. With proper nozzles, even

gasoline spill fires of some types have been extinguished when

coordinated hose lines were used to sweep the flames off the surface

of the liquid. Furthermore, water spray carefully applied has frequently

been used with success in extinguishing fires involving flammable

liquids with high flash points (or any viscous liquids) by causing frothing

to occur only on the surface, and this foaming action blankets and

extinguishes the fire.
Page 366

PUBLICATION DATA

The 2004 Emergency Response Guidebook (ERG2004) was prepared by the staff of Transport

Canada, the U.S. Department of Transportation, and the Secretariat of Communications and

Transport of Mexico with the assistance of many interested parties from government and industry

including the collaboration of CIQUIME of Argentina. The principal authors of the ERG since its

inception have been Transport Canada's Michel Cloutier and U.S. DOT's George Cushmac.

ERG2004 is based on earlier Transport Canada, U.S. DOT, and Secretariat of Communications

and Transport emergency response guidebooks. ERG2004 is published in three languages:

English, French and Spanish. The Emergency Response Guidebook has been translated and

printed in other languages, including Chinese, German, Hebrew, Japanese, Portuguese, Korean,

Hungarian, Polish, Turkish and Thai.

We encourage countries that wish to participate in future editions of the Guidebook to provide their

emergency response center information for inclusion. Please contact any of the websites or

telephone numbers in the paragraph below.

DISTRIBUTION OF THIS GUIDEBOOK

The primary objective is to place one copy of the ERG2004 in each emergency service vehicle

through distribution to Federal, state, provincial and local public safety authorities. The distribution

of this guidebook is being accomplished through the voluntary cooperation of a network of key

agencies. Emergency service organizations that have not yet received copies of ERG2004

should contact the respective distribution center in their country, state or province. In the U.S.,

information about the distribution center for your location may be obtained from the Office of

Hazardous Materials Safety web site at http://hazmat.dot.gov or call 202-366-4900. In Canada,

contact CANUTEC at 613-992-4624 or via the web site at http://www.canutec.gc.ca for information.

In Mexico, call SCT at 52-555-684-1275 or 684-0188 or via email at iflores@sct.gob.mx. In

Argentina, call CIQUIME at 011-4613-1100, or via the web site at http://www.ciquime.org.ar, or

via email at erg2004@ciquime.org.ar

REPRODUCTION and RESALE

Copies of this document which are provided free of charge to fire, police and other emergency

services may not be resold. ERG2004 (RSPA P 5800.9) may be reproduced without further

permission subject to the following:

The names and the seals of the participating governments may not be

reproduced on a copy of this document unless that copy accurately reproduces

the entire content (text, format, and coloration) of this document without

modification. In addition, the publisher’s full name and address must be

displayed on the outside back cover of each copy, replacing the wording

placed on the center of the back cover.
Page 367

Constructive comments concerning ERG2004 are solicited; in particular, comments concerning its

use in handling incidents involving dangerous goods. Comments should be addressed to:

In Canada:

Director, CANUTEC

Transport Dangerous Goods

Transport Canada

Ottawa, Ontario

Canada K1A 0N5

Phone: 613-992-4624 (information)

FAX: 613-954-5101

Email: canutec@tc.gc.ca

In the U.S.:

U. S. Department of Transportation

Research and Special Programs Administration

Office of Hazardous Materials Initiatives and Training (DHM-50)

Washington, DC 20590-0001

Phone: 202-366-4900

FAX: 202-366-7342

Email: welisten@rspa.dot.gov

In Mexico:

Secretariat for Communications and Transport

Land Transport Directorate

Hazardous Materials and Wastes Directorate

Calz. de las Bombas No. 411-9 piso

Col. San Bartolo Coapa

Coyoacan 04800, D.F.

Mexico

Phone and FAX: 52-555-684-1275 and 684-0188

In Argentina:

Information Center for Chemical Emergencies (CIQUIME)

Juan Bautista Alberdi 2986

C1406GSS Buenos Aires, Argentina

Tel. (011) 4613-1100 Fax (011) 4613-3707

Email: erg2004@ciquime.org.ar
Page 368

NOTES
Page 369

The Emergency Response Guidebook is normally revised and reissued every four years.

However, in the event of a significant mistake, omission or change in the state of knowledge,

special instructions to change the guidebook (in pen-and-ink, with paste-over stickers, or

with a supplement) may be issued.

Users of this guidebook should check periodically (about every 6 months) to make sure their

version is current. Changes should be annotated below. Contact:

DOT/RSPA

http://hazmat.dot.gov/gydebook.htm

TRANSPORT CANADA

http://www.tc.gc.ca/canutec/en/guide/guide.htm

CIQUIME

http://www.ciquime.org.ar

This guidebook incorporates changes dated:
Page 370

EMERGENCY RESPONSE TELEPHONE NUMBERS

MEXICO

1. SETIQ

01-800-00-214-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan Area

5559-1588

For calls originating elsewhere, call

011-52-555-559-1588

2. CENACOM

01-800-00-413-00 in the Mexican Republic

For calls originating in Mexico City and the Metropolitan Area

5550-1496, 5550-1552. 5550-1485 or 5550-4885

For calls originating elsewhere, call

011-52-555-550-1496, or 011-52-555-550-1552

011-52-555-550-1485, or 011-52-555-550-4885

ARGENTINA

1. CIQUIME

0-800-222-2933 in the Republic of Argentina

For calls originating elsewhere, call

+54-11-4613-1100

BRAZIL

1. PRÓ-QUÍMICA

0-800-118270

(Toll-free in Brazil)

For calls originating elsewhere, call

+55-11-232-1144

(Collect calls are accepted)

COLOMBIA

1. CISPROQUIM

01-800-091-6012 in Colombia

For calls originating in Bogotá, Colombia call

288-6012

For calls originating elsewhere call

011-57-1-288-6012

For additional details see the section entiitled "WHO TO CALL FOR ASSISTANCE."
EMERGENCY CONTACT

1-000-000-0000

NO. & TYPE

OF PACKAGES QUANTITY DESCRIPTION OFARTICLES

1 TANK TRUCK ISOPROPANOL 3 UN1219 II 3,000 LITERS

EXAMPLE OF EMERGENCY

RESPONSE TELEPHONE NUMBER

HAZARD CLASS

OR DIVISION NO.

SHIPPING NAME ID NUMBER PACKING GROUP

SHIPPING DOCUMENTS (PAPERS)*

The shipping document provides vital information when responding to a

hazardous materials/dangerous goods** incident. The shipping document

contains information needed to identify the materials involved. Use this

information to initiate protective actions for your own safety and the safety

of the public. The shipping document contains the proper shipping name

(see blue-bordered pages), the hazard class or division of the material(s),

ID number (see yellow-bordered pages), and, where appropriate, the

Packing Group. In addition, there must be information available that

describes the hazards of the material which can be used in the mitigation

of an incident. The information must be entered on or be with the shipping

document. This requirement may be satisfied by attaching a guide from the

ERG2004 to the shipping document, or by having the entire guidebook

available for ready reference. Shipping documents are required for most

dangerous goods in transportation. Shipping documents are kept in

• the cab of the motor vehicle,

• the possession of the train crew member,

• a holder on the bridge of a vessel, or

• an aircraft pilot’s possession.

The 4-digit ID Number may be shown on the diamond-shaped placard or on

an adjacent orange panel displayed on the ends and sides of a cargo tank,

vehicle or rail car.

* For the purposes of this book, the terms shipping document/shipping paper are synonymous.

** For the purposes of this book, the terms hazardous materials/dangerous goods are synonymous.

EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER

A Numbered or

Placard

A Placard 

and an 

Orange Panel

1219

1219 FLAMMABLE
Secretariat of Transport and Communications

Transport Transports

Canada Canada

Safety and Security

THIS DOCUMENT SHOULD NOT BE USED TO

DETERMINE COMPLIANCE WITH THE

DANGEROUS GOODS REGULATIONS

OR TO CREATE WORKER SAFETY DOCUMENTS

FOR SPECIFIC CHEMICALS

U.S. Department of Transportation

Research and Special Programs Administration 

NOT FOR SALE

This document is distributed free of charge to Public Safety Organizations

and may not be resold.