Palisade EC Page 1

Palisade® EC

For growth management of grasses grown for seed, wheat, triticale, barley, oats, and

sugarcane

Active Ingredient: Trinexapac-eth yl* .......................................................................... 12.0% Other Ingredients: 88.0%
Total: 100.0%

*CAS No. 95266-40-3

Palisade EC is an emulsifiable concentrate containing 1 pound of active ingredient per gallon.

KEEP OUT OF REACH OF CHILDREN.



## WARNING/AVISO

Si usted no entiende la etiqueta, busque a al guien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.)

See additional precautionary statements and directions for use inside booklet.

EPA Reg. No. 100-949

EPA Est. 62171-MS-001

Product of Switzerland
Formulated in the USA

SCP 949A

2.5 Gallons
Net ContentsPalisade EC Page 2

FIRST AID If in eyes • Hold eye open and rinse slowly and gently with water for
15-20 minutes.

• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.

• Call a poison control center or doctor for treatment advice.

If Inhaled • Move person to fresh air.

• If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible.

• Call a poison control center or doctor for further treatment
advice.

If on skin or clothing • Take off contaminated clothing.

• Rinse skin immediately with plenty of water for 15-20
minutes.

• Call a poison control center or doctor for treatment advice.

If swallowed • Call a poison control center or doctor immediately for
treatment advice.

• Have person sip a glass of water if able to swallow.

• Do not induce vomiting unless told to do so by a poison
control center or doctor.

• Do not give anything by mouth to an unconscious person.

NOTE TO PHYSICIAN If ingested, lavage stomach with care to pr event aspiration of stomach contents. An aqueous suspension of activated charcoal can be given to absorb remaining
toxicant. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

HOT LINE NUMBER For 24-Hour Medical Emergency A ssistance (Human or Animal) or

Chemical Emergency Assistance (Spill, Leak, Fire, or Accident),
Call
1-800-888-8372Palisade EC Page 3

PRECAUTIONARY STATEMENTS

Hazards to Humans and Domestic Animals

WARNING/AVISO

Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Wear protective eyewear such as goggles, face sh ield, or safety glasses. Harmful if swallowed, inhaled, or absorbed through skin. Av oid contact with skin, eyes or clothing. Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
Remove and wash contaminat ed clothing before reuse.

Personal Protective Equipment

Some materials that are chemical-resistant to this product are listed below. If you want more options, follow the instructions fo r Category G on an EPA chemical resistance category selection chart.

Applicators and other handlers must wear:

• Long-sleeved shirt and long pants

• Chemical-resistant gloves, such as barrier laminate or Viton®

• Shoes plus socks

• Protective eyewear

Discard clothing and other absorbent mate rials that have been drenched or heavily contaminated with this product’s concent rate. Do not reuse them. Follow manufacturer’s instructions for cleaning/main taining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.

Engineering Control Statements

When handlers use closed systems, enclosed cabs , or aircraft in a manner that meets the requirements listed in the Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced or modified as specified in the WPS.Palisade EC Page 4

User Safety Recommendations

Users should:

• Wash hands before eating, drinking, chewing gum, using tobacco, or using
the toilet.

• Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.

Environmental Hazards

Do not apply directly to water, to areas wher e surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwater or rinsate. Do not appl y when weather conditions favor drift from
treated areas.Palisade EC Page 5

CONDITIONS OF SALE AND LIMITA TION OF WARRANTY AND LIABILITY

NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation of Warranty and Liability before buying or usi ng this product. If the terms are not acceptable, return the product at onc e, unopened, and the purchase price will be
refunded.

The Directions for Use of this product must be followed carefully. It is impossible to eliminate all risks inherently associated wit h the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as manner of use or application, weather or crop conditions, presence of other materials or other influencing factors in the use of the product, which are beyond the control of SYNGENTA CROP PROTECTION, INC. or Se ller. To the extent permitted by applicable law, Buyer and User agree to hold SYNGENTA and Seller harmless for any claims relating to such factors.

SYNGENTA warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated in the Directions for Use, subject to the inherent risks referred to above, when used in accordance with directions under normal use conditions. To the extent permitted by applicable law: (1) this warranty does not extend to the use of the product contrary to label instructions or under conditions not reasonably foreseeable to or beyond the control of Seller or SYNGENTA, and, (2) Buyer and User assume the risk of any such use. TO THE EXTENT PERMITTED BY APPLICABLE LAW, SYNGENTA MAKES NO WARRANTIES OF MERCHANTABILITY
OR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS OR
IMPLIED WARRANTY EXCEPT AS WARRANTED BY THIS LABEL.

To the extent permitted by applicable law, in no event shall SYNGENTA be liable for any incidental, consequential or special damages resulting from the use or handling of this product. TO THE EXTENT PERMITTED BY APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITY OF SYNGENTA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIES OR DAMAGES (INCLUDING CLAIMS BA SED ON BREACH OF WARRANTY, CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE)
RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THE RETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTION OF SYNGENTA OR SELLER, THE REPLACEMENT OF THE PRODUCT.

SYNGENTA and Seller offer this product, and Buyer and User accept it, subject to the foregoing Conditions of Sale and Limitation of Warranty and Liability, which may not be modified except by written agreement signed by a duly authorized representative of
SYNGENTA.Palisade EC Page 6

DIRECTIONS FOR USE

It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. Th is Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination, notificat ion, and emergency assistance. It also contains specific instructions and excepti ons pertaining to the statements on this label about personal protective equipment (PPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Worker Protection Standard.

Do not enter treated areas without footwear until sprays have dried. There is no restricted-entry interval (REI) requirement.

Observe all precautions and limitations on th is label and on the labels of each product used in tank mixture with this product.

GENERAL USE PRECAUTIONS

FAILURE TO FOLLOW THE DIRECTIONS FOR USE AND PRECAUTIONS ON THIS
LABEL MAY RESULT IN POOR PERFO RMANCE, CROP INJURY, OR ILLEGAL
RESIDUES.

GENERAL INFORMATION

All applications should be made according to the use directions that follow.

Palisade EC is a plant growth regulator (PGR) which acts by inhibiting the production of gibberellic acid. It shortens the inter nodes on grasses grown for seed and cereals which results in a reduction in lodging. It also acts as a PGR in sugarcane by shortening the internodes which improves s eed piece production and when used prior toPalisade EC Page 7

harvest, increases and/or maintains the sugar content for an extended harvest window. Palisade EC is rapidly absorbed by the foliage. The PGR effects do not occur through soil uptake.

GENERAL USE INSTRUCTIONS

Application : Thorough coverage is necessary to provide good activity. Make up no more spray solution than is needed for application. Avoid spray overlap, as crop injury

may occur.

Adjuvants: When an adjuvant is to be used with this product, the use of an adjuvant
that meets the standards of the Chemical Producers and Distributors Association (CPDA) adjuvant certificat ion program is recommended.

Efficacy: The activity and performance of Palisade EC is primarily affected by: (1) environmental conditions, (2) crop management and cultural practices that affect crop growth and vigor, (3) fertility level, (4) moistu re availability, (5) plant vigor, and (6) crop growth stage. Palisade EC acts by inhibiting the production of gibberellic acid.

Rotational Crops: There are no rotational crop restrictions.

Crop Tolerance: Plant tolerance has been found acceptable for all crops on the label, however, not all possible tank mix combi nations have been tested under all conditions nor have all varieties been tested under all conditions. When possible, it is
recommended to test the combinations on a small portion of the crop to ensure a phytotoxic response will not occur as a result of application.

Spray Drift Management: To avoid spray drift, do not apply when conditions favor drift beyond the target area. Avoid spray overlap as crop injury may occur. The interaction of many equipment and weather related factor s determine the potential for spray drift.
AVOIDING SPRAY DRIFT AT THE APPLICATION SITE IS THE RESPONSIBILITY OF
THE APPLICATOR AND THE GROWER. Mo re information on managing spray drift can be found on the Syngenta Crop Protec tion website under Stewardship: http://www.syngentacropprotection.com/Env_ Stewardship/driftmanagement/index.aspx? nav=drift_management

MIXING AND APPLICATION METHODS

Spray Equipment

Nozzles

 Equip sprayers with nozzles that prov ide accurate and uniform application.

 Nozzles should be the same size and uniformly spaced across the boom.

 Calibrate sprayer before use.Palisade EC Page 8

 It is suggested that screens be used to prot ect the pump and to prevent nozzles from

clogging.

 Screens placed on suction side of pump should be 16-mesh or coarser

.

 Do not place a screen in the recirculation line.

 Use 50-mesh or coarser screens betw een the pump and boom, and where required,

at the nozzles.

 Check nozzle manufacturer’s recommendations.

Pump

 Use a pump with capacity to: (1) maintain 35-40 psi at nozzles. (2) provide sufficient agitation in tank to keep mixture in suspension - this requires recirculation of 10% of tank volume per minute.

 Use a jet agitator or liquid sparge tube for agitation.

 Do not use air sparge.

For more information on spray equipment and calibration, consult sprayer
manufacturers’ and state recommendations. Fo r specific local directions and spray schedules, consult the current state agricultural recommendations.

Mixing Instructions

 Prepare no more spray mixture than is required for the immediate operation.

 Thoroughly clean spray equipment before using this product.

 Agitate the spray solution bef ore and during application.

 Rinse spray tank thoroughly with clean water after each day’s use and dispose of pesticide rinsate by application to an already treated area.

 Do not allow spray mixture to stand ov ernight or for prolonged periods of time.

Palisade EC Alone (no tank mix):

• Add 1⁄2- 2⁄3 of the required amount of water to the spray or mixing tank.

• With the agitator running, add Palisade EC to the tank.

• Continue agitation while adding the remainder of the water.

• Mix in enough water (10-20 gals/A) to thoroughly and uniformly cover crop.

• Begin application of the spray solution after Palisade EC has completely dispersed
into the mix water.

• Maintain agitation until all of the mixture has been sprayed.

Palisade EC + Tank Mixtures:

• Palisade EC is usually compatible with a ll tank-mix partners listed on this label.

• To determine the physical compatibility of Palisade EC with other products, use a jar test. Using a quart jar, add the proportionat e amounts of the products to 1 qt. of water. Add wettable powders and water di spersible granular products first, then liquid flowables, and emulsifiable concentra tes last. After thoroughly mixing, let
stand for at least 5 minutes. If the comb ination remains mixed or can be remixed readily, it is physically compatible. Once compatibility has been proven, use the same procedure for adding required ingredients to the spray tank.Palisade EC Page 9

• Observe all directions for use, precauti ons, and limitations which appear on tank mix partner label.

Mixing in the Spray Tank

• Add 1⁄2- 2⁄3 of the required amount of water to the spray or mixing tank.

• With the agitator running, add the tank mix par tner(s) into the tank in the same order
as described above.

• Allow the material to completely dissolve and disperse into the mix water. Continue agitation while adding the remainder of the water and Palisade EC to the spray tank.

• Allow Palisade EC to completely disperse.

• Spray the mixture with the agitator running.

Palisade EC + Tilt® Fungicide or Quilt® Fungicide

• Add 1 / 2 – 2 /

3 of the required amount of water to the spray tank.

• While agitating, add Palisade EC followed by Tilt Fungicide or Quilt Fungicide.

• Continue agitation while adding the remainder of the water.

• Maintain agitation until all of the mixture has been applied.

APPLICATION INSTRUCTIONS

Palisade EC may be applied with all types of spray equipment commonly used for making ground and aerial applications. Proper adjustments and calibration of spraying equipment to give good coverage is essentia l for good growth regulator effects.

Ground Application:

 Apply in a minimum of 10 gals. of wate r per acre, unless specified otherwise.

 Do not apply through any ultra-low volume (ULV) spray system.

 Thorough coverage is necessary to provide good disease control.

Aerial Application:

 Thorough coverage is necessary to provide a good, uniform effect.

 A minimum of 2 gallons per acre can be used in grasses grown for seed, cereals, and

sugarcane.

 Avoid application under conditions when uniform coverage cannot be obtained or

when excessive spray drift may occur.

 Do not apply directly to humans or animals.

 Do not apply through any ultra-low volume (ULV) spray system.

Application Through Irrigati on Systems (Chemigation)

• Apply this product only through center pi vot, solid set, hand move, or moving wheel irrigation systems. Do not apply this pr oduct through any other type of irrigation system.Palisade EC Page 10

• Crop injury, lack of effectiveness, or illegal pesticide residues in the crop can result
from non-uniform distribution of treated water.

• Apply in 0.125 - 0.25 inches/A of water. Excessive water ma y reduce efficacy.

• If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers, or other experts.

• Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system , unless the pesticide label-prescribed safety devices for public water systems are in place.

• A person knowledgeable of the chemi gation system and responsible for its operation, or under the supervision of the re sponsible person, shall shut the system down and make necessary adjustments should the need arise.

Note: Do not inject Palisade EC at full strengt h or deterioration of valves and seals may occur. Use a dilution ratio of at least 10 par ts water to 1 part Palisade EC. Palisade EC is corrosive to many seal materials. Leather seals are best. EPDM or silicone rubber seals can be used, but should be replaced onc e a year. Do not use Viton®, Buna-N, Neoprene, or PVC seals.

Operating Instructions

1. The system must contain a functional c heck-valve, vacuum relief valve, and low pressure drain appropriately located on t he irrigation pipeline to prevent watersource contamination from backflow.

2. The pesticide injection pipeline must contain a functional, automatic, quickclosing check-valve to prevent the flow of fluid back toward the injection pump.

3. The pesticide injection pipeline must al so contain a functional, normally closed, solenoid-operated valve located on the in take side of the injection pump and connected to the system interlock to prev ent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut
down.

4. The system must contain functional interl ocking controls to automatically shut off the pesticide injection pump when the water pump motor stops.

5. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to the point where pesticide distribution is adversely affected.

6. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump), effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system
interlock.Palisade EC Page 11

7. Do not apply when wind speed favors drift beyond the area intended for
treatment.

Center Pivot Irrigation Equipment

Notes: (1) Use only with drive systems which provide uniform water distribution. (2) Do not use end guns when chemigating Palisade EC through center pivot systems because of non-uniform application.

• Determine the size of the area to be treated.

• Determine the time required to apply 1⁄8 -1⁄2 inch of water over the area to be treated when the system and injection equipment are operated at normal pressures as recommended by the equipment manufacturer. When applying Palisade EC through irrigation equipment use the lowest obtainable water volume while maintaining uniform distribution. Run the system at 80-95% of the manufacturer’s rated capacity.

• Using water, determine the injecti on pump output when operated at normal line

pressure.

• Determine the amount of Palisade EC requir ed to treat the area covered by the irrigation system.

• Add the required amount of Palisade EC and sufficient water to meet the injection time requirements to the solution tank.

• Make sure the system is fully charged wit h water before starting injection of the Palisade EC solution. Time the injection to la st at least as long as it takes to bring the system to full pressure.

• Maintain constant solution tank agitation during the injection period.

• Continue to operate the system until t he Palisade EC solution has cleared the sprinkler head.

Solid Set, Hand Move, and Moving Wheel Irrigation Equipment

• Determine the acreage covered by the sprinklers.

• Fill injector solution tank with water and adj ust flow rate to use the contents over a 20- to 30-minute interval. When applying Palisade EC through irrigation equipment
use the lowest obtainable water volume while maintaining uniform distribution.

• Determine the amount of Palisade EC requir ed to treat the area covered by the irrigation system.

• Add the required amount of Palisade EC in to the same quantity of water used to calibrate the injection period.

• Operate the system at the same pressure and time interval established during the
calibration.

• Stop injection equipment after treatment is completed. Continue to operate the system until the Palisade EC solution has cleared the last sprinkler head.Palisade EC Page 12

SPECIFIC INSTRUCTIONS FOR PUBLIC WATER SYSTEMS

1. Public water system means a system fo r the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at leas t 25 individuals daily at least 60 days out of the year.

2. Chemigation systems connected to public water systems must contain a functional, reduced-pressure zone, back-fl ow preventer (RPZ) or the functional equivalent in the water supply line ups tream from the point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There shall be a complete physical break (air gap) between the flow outlet end of the fill pipe and the top or overflow rim of the rese rvoir tank of at least twice the inside diameter of the fill pipe.

3. The pesticide injection pipeline must contain a functional, automatic, quickclosing check valve to prevent the flow of fluid back toward the injection pump.

4. The pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve located on the in take side of the injection pump and connected to the system interlock to prev ent fluid from being withdrawn from the supply tank when the irrigation system is either automatically or manually shut
down.

5. The system must contain functional interl ocking controls to automatically shut off the pesticide injection pump when the water pump motor stops, or in cases where there is no water pump, when the wa ter pressure decreases to the point where pesticide distribution is adversely affected.

6. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system
interlock.

Do not apply when wind speed favors drift beyond the area intended for treatment.Palisade EC Page 13

CROP USE DIRECTIONS

Crop Oz/A (Lb a.i./A) Application

For yield protection and lodging prevention in wheat, barley, oats, and triticale.

Cereals

Wheat
Winter Spring
Durum

Barley
Winter Spring

Oats

Triticale 12 – 14.4 (0.09 – 0.11) Apply Palisade EC from Feekes growth stage 5 (leaf sheath strongly erect) to Feekes growth stage 8 (ligule of flag leaf visible). Appl y before the flag leaf sheath extends. On barley, it is recommended to apply
before the third node.

For improved root development, apply 6 – 14.4 oz at Feekes 2-5 (tillers formed to leaf sheath strongly erect).

Use the lower rate when 1) varieties are more lodging tolerant, 2) application timing is earlier, and 3) when applying with a fungicide.

Use the higher rate when 1) varieties are prone to lod g in g , and 2 ) application timin g is late r

.

Split application
6 (0.05) Apply 6 oz at Feekes 4-5 (leaf sheaths lengthening to leaf sheath strongly erect) and then again at Feekes 7 (second node visible).

In barley, apply 6 oz at Feekes 6-7 (1 st to 2 nd nodes visible) and then again at Feekes 8 (flag leaf just visible).

Specific Use Restrictions: 1) For best coverage and uptake, use a minimum of 20 gallons of water/A. 2) Palisade EC may be applied until 45 da ys prior to harvest (45-day PHI). 3) Do not apply more than 14.4 oz (0.11 lb a.i.) Palisade EC/A/season. 4) Do not apply if crop is stressed by drought, disease, or temperatures.Palisade EC Page 14

Crop Oz/A (Lb a.i./A) Application

For yield protection and lodging prevention in grasses grown for seed.

Grasses (grown for seed) 12 - 64 (0.09 – 0.5) Apply as a broadcast, foliar spray to actively growing

grass.

For a single application, appl y before or during stem elongation stage of development (Zadoks 30-37 or Feekes 5-8).

Use the high rate on heavy, lush stands. Use the lower rate range on short varieties, when conditions are less favorable for lodging, or on older stands of

grass.

NOTE: Although this product is effective at any time in this growth stage the BEST timing is early (Zadoks growth stage 32 or Feekes 7) when the second node
on the main stem is detectable.

Split application
6 - 32 (0.05 – 0.25) For a split application, apply the first application before or during stem elongati on stage of development (Zadoks 30-37 or Feekes 5-8) followed by a second application 7-10 days later.

Specific Use Restrictions: (1) Do not apply more than 64 oz (0.5 lb a.i.) Palisade EC/A/season. (2) May be applied up to 35 days before harvest. (3) Do not graze or feed forage 49 days after last application. (4) Other crops may be planted 30 days after the last application.Palisade EC Page 15

Crop Oz/A (Lb a.i./A) Application

For ripening in sugarcane

Sugarcane 22.4 - 40 (0.18 – 0.31) Apply Palisade EC 28-60 days prior to harvest to increase sugar content and/ or extend harvest window.

For internode shortening for seed piece production in sugarcane

Sugarcane 8 – 25.6 (0.06 – 0.2) Make a minimum of two split applications of Palisade EC. Make first application of 8 – 25.6 oz/A when 6 fully developed full size leaves have appeared. Note the bottom leaf should be feeding internodes above the soil surface. Make a second application of 8 – 25.6 oz /A when 6 additional fully developed full size leaves have appeared. The total amount applied per acre/crop/season should not exceed 40 oz.

Specific Use Restrictions: 1) When applied as a ripener, Palisade EC may be applied until 28 days prior to harvest (28-day PHI). 2) Do not apply more than 40 oz (0. 31 lb a.i.) Palisade EC/A/crop/season. 3) Do not apply to cane under stress from lack of water, poor fertilization, abnormal temperatures, or disease. 4) Results may vary according to the variety. 5) Crop tolerance: Palisade EC has been shown to be safe at the rates, timings, and varieties tested. Some varieties may be more sensitive and exhibit symptoms such as stunting. Under normal agricultural c onditions, the affected plants will resume growth.

Conversion Table

Oz/A Lb a.i./A

6 0.05
8 0.06
12 0.09
14.4 0.11
22.4 0.18
25.6 0.2

32 0.25

40 0.31

64 0.5Palisade EC Page 16

Explanation of Growth Stages for Gramineous Crops

Feekes Zadoks Description 2 21 Begin Tillering
3 26 Tillers formed
4 29 Leaf sheaths erect 5 30 Leaf sheaths strongly erect
6 31 First node visible
7 32 Second node visible 8 37 Flag leaf just visible

STORAGE AND DISPOSAL

Do not contaminate water, food, or feed by storage and disposal.

Pesticide Storage

Do not store below 0°F. If crystals do form, store above 70°F, shaking periodically until crystals are dissolved.

Pesticide Disposal

Pesticide wastes are toxic. Improper dis posal of unused pesticide, spray mixture, or
rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, they must be disposed of according to Federal, state, or local procedures. Contact your State Pestic ide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance.

Container Handling

Non-refillable container. Do not reuse or refill this container. Offer for recycling if available. Triple rinse container (or equivalent ) promptly after emptying. Triple rinse as follows: Empty the remaining contents in to application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1⁄4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use and disposal. Dr ain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.

For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to av oid contamination of equipment and facilities during clean up and disposal of wastes. In t he event of a major spill, fire, or other emergency, call 1-800-888-8372, day or night.Palisade EC Page 17

CONTAINER IS NOT SAFE FOR FOOD, FEED, OR DRINKING WATER.

Palisade®, Quilt®, Tilt®, the ALLIANCE FRAME, the SYNGENTA logo, and the
PURPOSE ICON are trademarks of a Syngenta Group Company

Viton® is a trademark of E.I. DuPont de Nemours and Company.

U.S. Patent No. 4,693,745

©2010 Syngenta

For non-emergency (e.g., current product information), call Syngenta Crop Protecti on at 1-800-334-9481.

Manufactured for: Syngenta Crop Protection, Inc.
P.O. Box 18300 Greensboro, North Carolina 27419-8300

SCP 949APalisade EC Page 18

NON-DETACHABLE CONTAINER LABEL

Palisade® EC

For growth management of grasses grown for seed, wheat, triticale, barley, oats, and

sugarcane

Active Ingredient: Trinexapac-eth yl* ......................................................................... 12.0% Other Ingredients: 88.0%
Total: 100.0%

*CAS No. 95266-40-3

Palisade EC is an emulsifiable concentrate containing 1 pound of active ingredient per gallon.

KEEP OUT OF REACH OF CHILDREN.



## WARNING/AVISO

Si usted no entiende la etiqueta, busque a al guien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.)

See additional precautionary statements and directions for use inside booklet.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with it s labeling and with the Worker Protection Standard, 40 CFR part 170. Refer to suppl emental labeling under “Agricultural Use Requirements” in the Directions for Use se ction for information about this standard.

EPA Reg. No. 100-949

EPA Est. 62171-MS-001

Product of Switzerland
Formulated in the USA

2.5 Gallons
Net Contents

SCP 949A L1E 1109Palisade EC Page 19

FIRST AID If in eyes • Hold eye open and rinse slowly and gently with water for
15-20 minutes.

• Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.

• Call a poison control center or doctor for treatment advice.

If Inhaled • Move person to fresh air.

• If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible.

• Call a poison control center or doctor for further treatment
advice.

If on skin or clothing • Take off contaminated clothing.

• Rinse skin immediately with plenty of water for 15-20
minutes.

• Call a poison control center or doctor for treatment advice.

If swallowed • Call a poison control center or doctor immediately for
treatment advice.

• Have person sip a glass of water if able to swallow.

• Do not induce vomiting unless told to do so by a poison
control center or doctor.

• Do not give anything by mouth to an unconscious person.

NOTE TO PHYSICIAN If ingested, lavage stomach with care to pr event aspiration of stomach contents. An aqueous suspension of activated charcoal can be given to absorb remaining
toxicant. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

HOT LINE NUMBER For 24-Hour Medical Emergency A ssistance (Human or Animal) or

Chemical Emergency Assistance (Spill, Leak, Fire, or Accident),
Call
1-800-888-8372

PRECAUTIONARY STATEMENTS

Hazards to Humans and Domestic Animals

WARNING/AVISO

Causes substantial but temporary eye injury. Do not get in eyes or on clothing. Wear protective eyewear such as goggles, face sh ield, or safety glasses. Harmful if swallowed, inhaled, or absorbed through skin. Av oid contact with skin, eyes or clothing.Palisade EC Page 20

Avoid breathing vapor or spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet.
Remove and wash contaminat ed clothing before reuse.

Environmental Hazards

Do not apply directly to water, to areas wher e surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwater or rinsate. Do not appl y when weather conditions favor drift from
treated areas.

STORAGE AND DISPOSAL

Do not contaminate water, food, or feed by storage and disposal.

Pesticide Storage

Do not store below 0°F. If crystals do form, store above 70°F, shaking periodically until crystals are dissolved.

Pesticide Disposal

Pesticide wastes are toxic. Improper dis posal of unused pesticide, spray mixture, or
rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, they must be disposed of according to Federal, state, or local procedures. Contact your State Pestic ide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance.

Container Handling

Non-refillable container. Do not reuse or refill this container. Offer for recycling if available. Triple rinse container (or equivalent ) promptly after emptying. Triple rinse as follows: Empty the remaining contents in to application equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1⁄4 full with water and recap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank or store rinsate for later use and disposal. Dr ain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.

For minor spills, leaks, etc., follow all precautions indicated on this label and clean up immediately. Take special care to av oid contamination of equipment and facilities during clean up and disposal of wastes. In t he event of a major spill, fire, or other emergency, call 1-800-888-8372, day or night.Palisade EC Page 21

CONTAINER IS NOT SAFE FOR FOOD, FEED, OR DRINKING WATER.

Palisade® and the Syngenta logo are tr ademarks of a Syngenta Group Company

U.S. Patent No. 4,693,745

©2010 Syngenta

Manufactured for: Syngenta Crop Protection, Inc.
P.O. Box 18300 Greensboro, North Carolina 27419-8300

SCP 949A

PAL EC 949 APR10 AMEND-B CLEAN – df – 2/3/11 000100-00949.20100401B.PAL_EC-TOLPET-B-CLEAN.PDF