Belle River Power Plant Unit 2 

Emissions Test Report 

Prepared for: 

DTE Energy Belle River Power Plant 

East China Township, Michigan 

DTE Energy 

Belle River Power Plant 

4505 King Road 

East China Township, Michigan 49460 

Project No. 10-3991.00 

August 31, 2010 

BT Environmental Consulting, Inc. 

2615 Wolcott Street 

Ferndale, Michigan 48220 

(248) 548-8070 
Executive Summary

BT Environmental Consulting, Inc. (BTEC) was retained by DTE Energy (DTE) to evaluate air 

pollutant emissions rates from Belle River Power Plant Unit 2 (BRPP Unit 2) located in East 

China, Michigan. The test project consisted of (1) measurement of exhaust gas flowrates and 

moisture content, (2) measurement of exhaust gas oxygen (O2) and carbon dioxide (CO2) 

concentrations, (3) measurement of exhaust gas sulfur dioxide (SO2), carbon monoxide (CO), 

and total hydrocarbons (THC) concentrations, (4) measurement of exhaust gas methane (CH4) 

concentrations, (5) measurement of exhaust gas formaldehyde concentrations, and (6) 

measurement of exhaust gas volatile and semi-volatile organic hazardous air pollutant (HAP) 

concentrations. Testing for this project was completed June 22, 2010. The emissions test program 

was requested in a letter sent to DTE by the United States Environmental Protection Agency 

(U.S. EPA) pursuant to U.S. EPA authority under Section 114 of the Clean Air Act. 

Testing of Unit 2 consisted of triplicate 120-minute test runs for each compound. Sampling was 

performed utilizing United States Environmental Protection Agency (USEPA) methods. The 

average results of the testing are highlighted in the following table: 

Table 1 

Overall Emission Summary 

Pollutant Emission Rate 

lb/MMBtu 

Emission Rate 

ppmvd 

@ 7%O2

Emission Rate 

ug/dscm 

@7% O2

Concentration

% 

Formaldehyde 0.000117 0.10 

CO 0.0182 17.3 

SO2 0.55 228.4 

THC1 0.00225 1.4 

CH4 <0.00156 <2.6 

Speciated Volatile 

Organic HAPs2

<0.000032 <35.4 

Speciated Semi-Volatile 

Organic HAPs3

<0.00078 <864 

Oxygen (O2) 8.79 

Carbon Dioxide (CO2) 10.80 

1: THC ppm as propane 

2: See Tables 3 and 4 for individual Volatile Organic HAP emissions 

3: See Tables 5 and 6 for individual Semi Volatile Organic HAP

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

i
DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

ii

TABLE OF CONTENTS

1.0 INTRODUCTION............................................................................................................... 1

2.0 PROCESS DESCRIPTION ............................................................................................... 1

3.0 SAMPLING AND ANALYTICAL METHODOLOGIES.............................................. 1

3.1 EXHAUST GAS VELOCITY AND MOISTURE CONTENT ......................................................... 2 

3.2 OXYGEN AND CARBON DIOXIDE (USEPA METHOD 3A).................................................... 2 

3.3 SULFUR DIOXIDE (USEPA METHOD 6C) ........................................................................... 3 

3.4 CARBON MONOXIDE (USEPA METHOD 10)....................................................................... 3 

3.5 FORMALDEHYDE (METHOD 0011)...................................................................................... 3 

3.6 TOTAL HYDROCARBONS (USEPA METHOD 25A).............................................................. 4 

3.7 METHANE (USEPA METHOD 18)....................................................................................... 4 

3.8 SEMI VOLATILE ORGANIC HAPS (METHOD 0010) ............................................................. 5 

3.9 VOLATILE ORGANIC HAPS (METHOD 0031)...................................................................... 5 

4.0 TEST RESULTS ................................................................................................................. 6

TABLES

Table 1 – Overall Emissions Summary 

Table 2 – Unit 2 Formaldehyde, CO, SO2, THC, and CH4 Emission Rates

Table 3 – Unit 2 Volatile Organic HAP Laboratory Results Summary 

Table 4 – Unit 2 Volatile Organic HAP Emission Test Results Summary 

Table 5 – Unit 2 Semi Volatile Organic HAP Laboratory Results Summary 

Table 6 – Unit 2 Semi Volatile Organic HAP Emission Test Results Summary 

FIGURES

Figure 1 – Boilers 1 & 2 Exhaust Stack Traverse Point Diagram 

Figure 2 – USEPA Method 3A/6C/10 Sampling Train Diagram 

Figure 3 – USEPA Method 25A Sampling Train Diagram 

Figure 4 – USEPA Method 0010 Sampling Train Diagram 

Figure 5 – USEPA Method 0011 Sampling Train Diagram 

Figure 6 – USEPA Method 0031 Sampling Train Diagram 

APPENDICES

Appendix A – Field and Computer Generated Raw Data and Field Notes 

Appendix B – Calibration Data 

Appendix C – Raw CEM Data 

Appendix D – Laboratory Analytical Results 

Appendix E – Example Calculations 

Appendix F – Production Data 
1.0 Introduction

BT Environmental Consulting, Inc. (BTEC) was retained by DTE Energy (DTE) to evaluate air 

pollutant emissions rates from Belle River Power Plant Unit 2 (BRPP Unit 2) located in East 

China, Michigan. The test project consisted of (1) measurement of exhaust gas flowrates and 

moisture content, (2) measurement of exhaust gas oxygen (O2) and carbon dioxide (CO2) 

concentrations, (3) measurement of exhaust gas sulfur dioxide (SO2), carbon monoxide (CO), 

and total hydrocarbons (THC) concentrations, (4) measurement of exhaust gas methane (CH4) 

concentrations, (5) measurement of exhaust gas formaldehyde concentrations, and (6) 

measurement of exhaust gas volatile and semi-volatile organic hazardous air pollutant (HAP) 

concentrations. Testing for this project was completed June 22, 2010. The emissions test program 

was requested in a letter sent to DTE by the United States Environmental Protection Agency 

(U.S. EPA) pursuant to U.S. EPA authority under Section 114 of the Clean Air Act. 

The following BTEC professionals participated in conducting this study: Todd Wessel and Jim 

Sharp, Senior Project Managers; Thom Snyder, Project Manager; Jeff Peitzsch, Staff 

Environmental Engineer; and Matthew Smith, Environmental Technician. Mr. Mark Grigereit 

with DTE provided on-site coordination for this project. 

2.0 Process Description

Belle River Power Plant employs the use of two (2) Babcock and Wilcox coal-fired boilers 

(Units 1 & 2) each designed to produce nominally 4,550,000 pounds per hour of steam. Each 

Unit has a Siemens Power Corporation turbine generator with a rated capability of 635 (Unit 1) 

and 645 (Unit 2) gross megawatts (GMW). The typical coal blend for Unit 2 is a 70% low-sulfur 

western (LSW) / 30% midsulfur eastern (MSE). Full load conditions for the Unit will be 

nominally 600-645 MW, but may be lower during the testing period due to unit-specific issues. 

Testing will occur on Unit 2 as close to full load conditions as possible, but not less than 90% of 

full load. 

3.0 Sampling and Analytical Methodologies

Sampling and analytical methodologies for the emissions test program can be separated into nine 

categories as follows: 

(1) Measurement of exhaust gas velocity, molecular weight, and moisture content; 

(2) Measurement of exhaust gas oxygen (O2) and carbon dioxide (CO2) concentrations using 

the procedures of U.S. EPA Method 3A; 

(3) Measurement of exhaust gas sulfur dioxide (SO2) concentrations and emission rates 

using U.S. EPA Method 6C; 

(4) Measurement of exhaust gas carbon monoxide (CO) concentrations and emission rates 

using U.S. EPA Method 10; 

(5) Measurement of exhaust gas formaldehyde concentrations and emission rates using 

Method 0011; 

(6) Measurement of exhaust gas total hydrocarbons (THC) concentrations and emission rates 

using U.S. EPA Method 25A; 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

1
(7) Measurement of exhaust gas methane concentrations and emission rates using U.S. EPA 

Method 18; 

(8) Measurement of exhaust gas semi volatile organic HAPs concentrations and emission 

rates using Method 0010; and 

(9) Measurement of exhaust gas speciated volatile organic HAPs concentrations and 

emission rates using Method 0031. 

Descriptions of sampling and analytical methodologies by category are summarized by Sections 

3.1 through 3.9, respectively. 

3.1 Exhaust Gas Velocity and Moisture Content 

Measurement of exhaust gas velocity and moisture content were conducted using the following 

reference test methods codified at Title 40, Part 60, Appendix A of the Code of Federal 

Regulations (40 CFR 60, Appendix A): 

• Method 1 -“Sample and Velocity Traverses for Stationary Sources” 

• Method 2 -“Determination of Stack Gas Velocity and Volumetric Flowrate” 

• Method 4 -“Determination of Moisture Content in Stack Gases”

Stack gas velocity traverses were conducted in accordance with the procedures outlined in 

Methods 1 and 2 (see Figure 1 for an exhaust stack traverse point diagram). An S-type pitot tube 

with a thermocouple assembly, calibrated in accordance with Method 2, Section 4.1.1, was used 

to measure exhaust gas velocity pressures (using a manometer) and temperatures during testing. 

The S-type pitot tube dimensions were within specified limits, therefore, a baseline pitot tube 

coefficient of 0.84 (dimensionless) was assigned. 

A cyclonic flow check was performed at the sampling location. The existence of cyclonic flow 

is determined by measuring the flow angle at each sample point. The flow angle is the angle 

between the direction of flow and the axis of the stack. If the average of the absolute values of 

the flow angles is greater than 20 degrees, cyclonic flow exists. The null angle was determined 

to be less than 20 degrees at each sampling point. 

Exhaust gas moisture content was evaluated using Method 4. Exhaust gas was extracted as part 

of the Method 0010, 0011, and 0031 sampling trains (see Figures 4, 54, and 6 for schematics of 

the sampling trains). Exhaust gas moisture content was then determined gravimetrically. 

3.2 Oxygen and Carbon Dioxide (USEPA Method 3A) 

Exhaust gas O2 and CO2 concentrations were measured using the procedures of 40 CFR 60, 

Appendix A, Method 3A, “Determination of Oxygen and Carbon Dioxide Concentrations in 

Emissions from Stationary Sources”. The O2 content of the gas stream was measured using a 

Teledyne paramagnetic O2 gas analyzer. The CO2 content of the gas stream was measured using 

a Teledyne infrared CO2 gas analyzer. The gas stream was drawn through a stainless-steel probe 

with a heated in-line filter to remove any particulate, a heated Teflon® sample line, through a 

refrigerated Teflon® sample conditioner to remove the moisture from the sample before it 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

2
entered the analyzers. Data was recorded on a PC equipped with data acquisition software. 

Recorded concentrations were averaged and reported for the duration of each 120-minute test (as 

drift corrected per Method 7E). A drawing of the sampling train used for the testing program is 

presented as Figure 2. 

In accordance with Method 7E, a 3-point (zero, mid, and high) bias check and calibration check 

was performed on the analyzers prior to initiating the test program. Following each test run, a 2-

point (zero and high) calibration drift check was performed. 

3.3 Sulfur Dioxide (USEPA Method 6C) 

The sulfur dioxide content of the gas stream was evaluated according to procedures outlined in 

Title 40, Part 60, Appendix A, Method 6C. The SO2 content of the gas stream was measured 

using a Western Research SO2 gas analyzer (see Figure 2 for a schematic of the sampling train). 

A sample of the gas stream was drawn through an insulated stainless-steel probe with an in-line 

glass fiber filter to remove any particulate, a heated Teflon® sample line, through a refrigerated 

sample conditioner with a peristaltic pump to remove the moisture from the sample before it 

entered the analyzer. Data was recorded at 4-second intervals on a PC equipped with Labview®

II data acquisition software. Recorded SO2 concentrations were averaged over the course of 

each 120-minute test. The analyzer was calibrated for a range of 0 to 500 ppm. 

A three-point (zero, mid, and high) calibration check was performed on the SO2 analyzer. 

Calibration drift checks were performed at the completion of each run. 

3.4 Carbon Monoxide (USEPA Method 10) 

The CO content of the exhaust gas was evaluated according to procedures outlined in 40 CFR 

60, Appendix A, Method 10. The CO content of the gas stream was measured using a TECO 48 

CO gas analyzer. The gas stream was drawn through a stainless-steel probe with a heated in-line 

filter to remove any particulate, a heated Teflon® sample line, through a refrigerated sample 

conditioner with a peristaltic pump to remove the moisture from the sample before it entered the 

analyzer. Data was recorded on a PC equipped with Labview® II data acquisition software. 

Recorded CO concentrations were averaged and reported for the duration of each 120-minute 

test (as drift corrected per Method 7E). The analyzer was calibrated for a range of 0 to 200 ppm. 

In accordance with Method 10, a 3-point (zero, mid, and high) calibration check was performed 

on the CO analyzer. Calibration drift checks were performed at the completion of each run. 

3.5 Formaldehyde (Method 0011) 

Exhaust gas formaldehyde concentrations were measured using the procedures of Method 0011, 

“Sampling For Selected Aldehyde and Ketone Emissions from Stationary Sources”. The Method 

0011 sampling train consisted of: (1) a borosilicate or quartz nozzle, (2) a heated borosilicate or 

quartz probe liner; (3) a set of five Greensburg-Smith (GS) impingers with first containing 200 

ml of DNPH, (4) the second and third impingers each containing 100 mL DNPH, (5) a fourth 

empty impinger, (6) a modified GS impinger containing a known weight of silica gel desiccant; 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

3
(7) a length of sample line, and (6) a Nutech control case equipped with a pump, dry gas meter, 

and calibrated orifice. Figure 5 provides an illustration of the Method 0011 sample train. 

After completion of the final leak test for each test run, the impinger train was carefully 

disassembled. The nozzle and probe line were brushed and rinsed with methylene chloride 

(MeCl2) which was collected in a pre-cleaned sample container. The liquid volume of each 

impinger was measured gravimetrically and any mass increase was noted on field sheets. The 

impinger catch solution was then added to the probe rinse sample container. The impingers were 

then triple rinsed with MeCl2 and the rinses added to the sample container. A final rinse with 

MeCl2 and deionized water (DI H2O) was performed on the nozzle, probe liner, and impingers. 

BTEC labeled each container with the test number, test location, and test date, and marked the 

level of liquid on the outside of the container. In addition, blank samples of the DI H2O and 

MeCl2 were collected. Samples were couriered by Maxxam Analytics, Ltd. (Maxxam) personnel 

to the Maxxam laboratory for analysis. 

3.6 Total Hydrocarbons (USEPA Method 25A) 

Total hydrocarbons (THC) concentrations were measured according to 40 CFR 60, Appendix A, 

Method 25A. A sample of the gas stream was drawn through a stainless steel probe with an inline glass fiber filter to remove any particulate, and a heated Teflon® sample line to prevent the 

condensation of any moisture from the sample before it enters the analyzer. Data was recorded 

at 4-second intervals on a PC equipped with Labview® II data acquisition software. BTEC used 

a VIG Model 20 THC hydrocarbon analyzer to determine the THC concentration. 

The VIG THC hydrocarbon analyzer channels a fraction of the gas sample through a capillary 

tube that directs the sample to the flame ionization detector (FID), where the hydrocarbons 

present in the sample are ionized into carbon. The carbon concentration is then determined by 

the detector in parts per million (ppm). This concentration is transmitted to the data acquisition 

system (DAS) at 4-second intervals in the form of an analog signal, specifically voltage, to 

produce data that can be averaged over the duration of the testing program. This data is then 

used to determine the average ppm for total hydrocarbons (THC) using the equivalent units of 

propane (calibration gas). The analyzer was calibrated for a range of 0 to 50 ppm. 

In accordance with Method 25A, a 3-point (zero, mid, and high) calibration check was 

performed on the THC analyzer. Calibration drift checks were performed at the completion of 

each run. 

3.7 Methane (USEPA Method 18) 

Methane concentrations were measured according to 40 CFR 60, Appendix A, Method 18. A 

tedlar bag was placed inside an integrated bag sampling lung. A sample of the gas was drawn 

into the tedlar bag by keep the lung under negative pressure using a pump. Sample extraction 

was done in conjunction with Method 25A. Integrated bag samples were shipped via fed-ex to 

Enthalpy Laboratories for Methane analysis. 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

4
3.8 Semi Volatile Organic HAPs (Method 0010) 

Method 0010, was used to evaluate semi volatile organic HAP’s concentrations. The Method 

0010 sampling train consisted of: (1) a stainless steel or borosilicate glass nozzle, (2) a heated 

borosilicate or quartz probe liner; (2) a heated borosilicate or quartz glass filter holder containing 

a pre-weighed 90-mm quartz filter with Teflon filter support; (3) a vertical condenser, (4) a 

sorbant trap, (5) an empty pot bellied impinger, (6) two Greenburg-Smith (GS) impingers each 

containing 100 ml of DI H2O, (7) an empy GS impinger, (8) a modified GS impinger containing 

a known weight of silica gel desiccant; (9) a length of sample line, and (10) a Nutech control 

case equipped with a pump, dry gas meter, and calibrated orifice. Figure 4 provides an 

illustration of the Method 0010 sample train. 

After completion of the final leak test for each test run, the impinger train was carefully 

disassembled. The nozzle, probe, and front half of the filter housing were brushed and rinsed 

with a solvent mixture (1:1 v/v methanol/methylene chloride) and collected in a pre-cleaned 

glass sample container. The filter was recovered and placed in its original Petri dish. The 

sorbant trap was removed and capped with parafilm. The liquid volume of the pot bellied 

impinger was measured gravimetrically and transferred to a glass sample container. The back 

half of the filter housing, the condenser, and pot bellied impinger were rinsed with the solvent 

mixture and the rinse was collected in a separate glass sample container. The remaining 

impingers were gravimetrically analyzed for moisture gain and the liquid was discarded. 

BTEC labeled each container with the test number, test location, and test date, and marked the 

level of liquid on the outside of the container. In addition, blank samples of the solvent mixture, 

filter, and sorbant trap were collected. Samples were couriered by Maxxam personnel to the 

Maxxam laboratory for analysis. 

3.9 Volatile Organic HAPs (Method 0031) 

Exhaust gas volatile organic HAPs concentrations were measured using the procedures of 

Method 0031, “Sampling Method For Volatile Organic Compounds (SMVOC)”. The Method 

0031 sampling train consisted of: (1) a heated borosilicate or quartz probe liner; (2) a three way 

glass/Teflon isolation valve, (3) a vertical condenser, (4) two Tenax-GC sorbent traps in series, 

(5) a condensate trap, (6) another vertical condenser, (7) an Anasorb-747 sorbent trap, (8) a small 

impinger containing a known weight of silica gel desiccant; (9) a length of sample line, and (10) 

a Nutech control case equipped with a pump, dry gas meter, and calibrated orifice. Figure 5 

provides an illustration of the Method 0031 sample train. 

The probe was placed at the center of the stack for non-isokinetic sampling. The sample train 

was run for 40 minutes at a rate of 0.5 L/min at which point all the sorbent traps were recovered 

and replaced with new traps. A total of three sets of sorbent traps were used for each test for a 

total sample time of 120 minutes per test. The mass of liquid condensed in the condensate trap 

and silica gel impingers were measured gravimetrically for moisture analysis. 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

5
BTEC labeled each trap with the test number, test location, and test date. In addition, blank 

samples of the sorbent traps were collected. Samples were couriered by Maxxam personnel to 

the Maxxam laboratory for analysis. 

4.0 Test Results

The results of the emissions test program are summarized by Table 1. 

Table 1 

Overall Emission Summary 

Pollutant Emission Rate 

lb/MMBtu 

Emission Rate 

ppmvd 

@ 7%O2

Emission Rate 

ug/dscm 

@7% O2

Concentration

% 

Formaldehyde 0.000117 0.10 

CO 0.0182 17.3 

SO2 0.55 228.4 

THC1 0.00225 1.4 

CH4 <0.00156 <2.6 

Speciated Volatile 

Organic HAPs2

<0.000032 <35.4 

Speciated Semi-Volatile 

Organic HAPs3

<0.00078 <864 

Oxygen (O2) 8.79 

Carbon Dioxide (CO2) 10.80 

1: THC ppm as propane 

2: See Tables 3 and 4 for individual Volatile Organic HAP emissions 

3: See Tables 5 and 6 for individual Semi Volatile Organic HAP

Field and computer generated data for each test run are available in Appendix A, as well as all 

other applicable field data. Equipment calibration and span gas documentation is presented in 

Appendix B. Raw CEMs data is presented in Appendix C. Laboratory analysis is available in 

Appendix D. Example calculations are available in Appendix E. Production data is available in 

Appendix F. 

DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

6
DTE Belle River Power Plant BTEC Project No. 10-3991.00 

Unit 2 Emissions Test Report 8/31/2010 

 

7

Limitations

The information and opinions rendered in this report are exclusively for use by DTE Energy. 

BTEC will not distribute or publish this report without consent granted by DTE Energy except as 

required by law or court order. BTEC accepts responsibility for the competent performance of 

its duties in executing the assignment and preparing reports in accordance with the normal 

standards of the profession, but disclaims any responsibility for consequential damages. 

This report was prepared by: 

Brandon V. Chase 

Staff Environmental Engineer 

This report was reviewed by: 

Barry P. Boulianne 

Senior Project Manager 
Tables 
Table 2

Unit 2 Formaldehyde, CO, SO2, THC, and Methane Emission Rates (Methods 0011, 10, 6C, 25A, 18)

Plant Job #

Location 

Copyright by Walter Smith

Run Number M0011-R1 M0011-R2 M0011-R3 Average

Date Test Date 6/22/2010 6/22/2010 6/22/2010

Start Run Start Time 8:27:00 11:57:00 15:29:00

Run Finish Time 11:04:00 14:33:00 17:47:00

Net Traversing Points 24 24 24

Θ Net Run Time, minutes 120 120 120 120

DN Nozzle Dianeter, inches 0.180 0.180 0.180 0.180

Cp Pitot Tube Coeficient 0.84 0.84 0.84 0.84

Y Dry Gas Meter Calibration Factor 0.996 0.996 0.996 0.996

PBr Barometric Pressure, inches of Mercury 29.93 29.93 29.93 29.93

ΔH Average orifice meter Differential, inches H2O 1.31 1.38 1.38 1.36

Vm Dry Gas Meter Volume Sampled, cubic feet 79.502 81.728 81.621 80.950

tm Average Dry Gas Meter Temperature, °F 90.98 93.94 97.60 94.17

Vmstd Dry Gas Meter Volume Sampled, dscf 76.152 77.878 77.266 77.099

Vlc Total Moisture Liquid collected, ml 196 204 196 198.7

Vwstd Volume of Water Vapor, standard cubic feet 9.23 9.60 9.23 9.35

% H2O Moisture Content of Stack Gas, % 10.8 11.0 10.7 10.8

% H2Osat Moisture Saturation at Stack Gas Temperature, % 100.0 100.0 100.0 100

Mfd Dry Mole Fraction 0.892 0.890 0.893 0.892

%CO2 Carbon Dioxide, % 10.79 10.82 10.8 10.80

%O2 Oxygen, % 8.9 8.46 9.02 8.79

% CO+ N2 Carbon Monoxide & Nitrogen, % 80.33 80.72 80.18 80.4

Fo Fuel Factor 1.11 1.15 1.10 1.12

Md Dry Molecular Weight, lb/lb-Mole 30.08 30.07 30.09 30.08

Ms Wet Molecular weight, lb/lb-Mole 28.78 28.74 28.80 28.77

Pg Flue Gas Static Pressure, inches of H2O -1.90 -1.90 -1.90 -1.90

Ps Absolute Flue Gas Pressure, inches of Mercury 29.79 29.79 29.79 29.79

ts Average Stack Gas Temperature, °F 317 318 321 319

ΔPavg Average Velocity Head, inches of H2O 2.077 2.147 2.219 2.148

vs Average Stack Gas Velocity, feet/second 98.5 100.3 102.1 100.3

As Stack Crossectional Area, square feet 510.7 510.7 510.7 510.7

Qsd Dry Volumetric Flow Rate, dry scfm 1,848,721 1,822,014 1,880,328 1,850,354

Qaw Actual Wet Volumetric Flue Gas Flow Rate, acfm 3,072,930 3,019,180 3,127,971 3,073,360

%I Percent Isokinetic of Sampling Rate, % 100.7 101.5 99.0 100.4

% EA Percent Excess Air, % 72 66 74 71

Fd F-Factor, dscfm/MMBtu @ 0%O2 9657 9657 9657 9657

W Formaldehyde Catch Weight, ug 250.0 300.0 190.0 246.7

Cppm,@7%O2 Formaldehyde Concentration, ppm @ 7%O2 0.11 0.12 0.08 0.10

Elb/MMBtu Formaldehyde Emission Rate, lb/mmbtu 1.22E-04 1.38E-04 9.21E-05 1.17E-04

CO ppm Carbon Monoxide Concentration, ppmd 3.9 29.0 12.8 15.2

CO ppm@7%O2 Carbon Monoxide Concentration, ppmd @ 7% O2 4.5 32.4 15.0 17.3

CO lb/mmbtu Carbon Monoxide Emission Rate, lb/mmbtu 4.72E-03 3.41E-02 1.58E-02 1.82E-02

SO2 ppm Sulfur Dioxide Concentration, ppmd 227.0 188.1 181.6 198.9

SO2 ppm@7%O2 Sulfur Dioxide Concentration, ppmd @ 7% O2 262.5 210.2 212.5 228.4

SO2 lb/mmbtu Sulfur Dioxide Emission Rate, lb/mmbtu 6.32E-01 5.06E-01 5.11E-01 5.50E-01

THC ppm Total Hydrocarbon Concentration, ppmw as propane 1.2 1.0 1.0 1.1

THC ppm@7%O2 Total Hydrocarbon Concentration, ppmd @ 7% O2 1.6 1.2 1.3 1.4

THC lb/mmbtu Total Hydrocarbon Emission Rate, lb/mmbtu 2.60E-03 2.04E-03 2.10E-03 2.25E-03

Methaneppm Methane Concentration, ppmw 2.0 2.0 2.0 2.0

Methane ppm@7%O2 Methane Concentration, ppmd @ 7% O2 2.6 2.5 2.6 2.6

Methane lb/mmbtu Methane Emission Rate, lb/mmbtu 1.56E-03 1.53E-03 1.58E-03 1.56E-03

Copyright by Walter Smith

DTE Belle River 10-3991.00

Unit 2 Exhaust

Address East China, MI

Personnel TS
Table 3

Unit 2 Volatile Organic HAP Laboratory Results Summary

DTE Energy Belle River Power Plant

East China, Michigan

BTEC Project No. 10-3991.00

Sampling Date: June 22, 2010

 

Parameter Run 1 Run 2 Run 3 Average

Test Run Date 6/22/2010 6/22/2010 6/22/2010

Test Run Time 8:28-11:35 12:09-15:22 16:00-18:54

Exhaust Gas Flowrate (dscfm) 1,879,744 1,839,548 1,877,667 1,865,653

Sample Volume, Vmstd (dscf) 61.3 53.5 53.2 56.0

O2 Concentration (%, Corrected as per Method 7E) 8.9 8.5 9.0 8.8

CO2 Concentration (%, Corrected as per Method 7E) 10.8 10.8 10.8 10.8

Moisture % 0.15 0.09 0.00 0.08

Fd 9,657 9,657 9,657 9,657

Laboratory Result (ug)

Dichlorodifluoromethane (FREON 12) 0.7425 1.5225 0.9225 1.1

Chloromethane 1.165 1.545 1.245 1.3

Vinyl Chloride 0.339 1.029 0.429 0.6

Bromomethane 1.4875 1.8675 1.5675 1.6

Chloroethane 0.5115 0.9225 0.5925 0.7

Trichlorofluoromethane (FREON 11) 0.855 1.245 0.945 1.0

Acetone (2-Propanone) 4.285 5.925 4.725 5.0

1,1-Dichloroethylene 0.5325 0.9225 0.6225 0.7

Iodomethane 0.6135 1.0935 0.7935 0.8

Carbon Disulfide 0.7977 1.6677 1.0677 1.2

Methylene Chloride(Dichloromethane) 3.602 3.565 3.6315 3.6

1,1-Dichloroethane 0.339 0.729 0.429 0.5

trans-1,2-Dichloroethylene 0.5325 0.9225 0.6225 0.7

cis-1,2-Dichloroethylene 0.5325 0.9225 0.6225 0.7

Chloroform 0.339 0.772 2.622 1.2

1,2-Dichloroethane 0.3147 0.4677 0.3777 0.4

Methyl Ethyl Ketone (2-Butanone) 4.065 5.325 4.425 4.6

1,1,1-Trichloroethane 0.3777 1.0677 0.4677 0.6

Carbon Tetrachloride 0.5877 1.0677 0.7677 0.8

Benzene 0.3597 0.7677 0.4377 0.5

1,1,2-Trichloroethane 0.5877 1.0677 0.7677 0.8

1,2-Dichloropropane 0.3777 0.7677 0.4677 0.5

Trichloroethylene 0.3777 0.7677 0.4677 0.5

Dibromomethane 0.3777 0.7677 0.4677 0.5

Bromodichloromethane 0.339 0.729 0.429 0.5

cis-1,3-Dichloropropene 0.339 0.729 0.429 0.5

trans-1,3-Dichloropropene 0.3405 0.4935 0.4035 0.4

Dibromochloromethane 0.318 0.729 0.399 0.5

Methyl Isobutyl Ketone 2.097 2.877 2.277 2.4

Methyl Butyl Ketone (2-Hexanone) 2.307 3.477 2.577 2.8

Toluene 0.3777 1.0677 0.4677 0.6

Ethylene Dibromide 0.3777 0.7677 0.4677 0.5

Tetrachloroethylene 0.5877 1.3677 0.7677 0.9

Chlorobenzene 0.3777 0.7677 0.4677 0.5

1,1,1,2-Tetrachloroethane 0.3777 0.7677 0.4677 0.5

Ethylbenzene 0.3777 1.0677 0.4677 0.6

m / p-Xylene 0.5877 1.0677 0.7892 0.8

Styrene 0.3777 0.7677 0.4677 0.5

o-Xylene 0.5877 1.0677 0.7677 0.8

Bromoform 0.339 1.029 0.429 0.6

1,1,2,2-Tetrachloroethane 0.855 1.545 0.945 1.1

1,2,3-Trichloropropane 0.6135 1.0935 0.7935 0.8

1,3-Dichlorobenzene 0.5877 1.3677 0.7677 0.9

1,4-Dichlorobenzene 0.5877 1.3677 0.7677 0.9

1,2-Dichlorobenzene 0.5877 1.3677 0.7677 0.9

dscfm = dry standard cubic feet per minute

dscf = dry standard cubic feet

ng/dscm @ 7%O2 = nanograms per dry standard cubic meter corrected to 7% Oxygen

lb/mmbtu = pounds per million btu

31.31 = Ft^3 per m^3

453.6 = grams per pound

All results not in bold are flagged as BDL. DL used for calculations 

All results in bold are flagged detection level limited (DLL). Fractions with results below DL use DL for calculations.

No results flagged as ADL.

equations:

lb/mmbtu = concentration(ug)/(10^6) *Fd/Vmstd * 1/453.6 * 20.9/(20.9-O2)

ug/dscm @ 7%O2 = mass(ug) * (35.31/Vmstd) * (20.9-7)/(20.9-O2)
Table 4

Unit 2 Volatile Organic HAP Emission Test Results Summary

DTE Energy Belle River Power Plant

East China, Michigan

BTEC Project No. 10-3991.00

Sampling Date: June 22, 2010

Run 1 Run 2 Run 3 Average Compound Run 1 Run 2 Run 3 Average

4.5E-07 1.0E-06 6.5E-07 7.1E-07 Dichlorodifluoromethane (FREON 12) 0.49 1.12 0.72 0.78

7.0E-07 1.0E-06 8.8E-07 8.7E-07 Chloromethane 0.78 1.14 0.97 0.96

2.0E-07 6.9E-07 3.0E-07 4.0E-07 Vinyl Chloride 0.23 0.76 0.33 0.44

9.0E-07 1.2E-06 1.1E-06 1.1E-06 Bromomethane 0.99 1.38 1.22 1.19

3.1E-07 6.2E-07 4.2E-07 4.5E-07 Chloroethane 0.34 0.68 0.46 0.49

5.2E-07 8.3E-07 6.7E-07 6.7E-07 Trichlorofluoromethane (FREON 11) 0.57 0.92 0.73 0.74

2.6E-06 4.0E-06 3.3E-06 3.3E-06 Acetone (2-Propanone) 2.85 4.37 3.67 3.63

3.2E-07 6.2E-07 4.4E-07 4.6E-07 1,1-Dichloroethylene 0.35 0.68 0.48 0.51

3.7E-07 7.3E-07 5.6E-07 5.5E-07 Iodomethane 0.41 0.81 0.62 0.61

4.8E-07 1.1E-06 7.5E-07 7.8E-07 Carbon Disulfide 0.53 1.23 0.83 0.86

2.2E-06 2.4E-06 2.6E-06 2.4E-06 Methylene Chloride(Dichloromethane) 2.40 2.63 2.82 2.62

2.0E-07 4.9E-07 3.0E-07 3.3E-07 1,1-Dichloroethane 0.23 0.54 0.33 0.37

3.2E-07 6.2E-07 4.4E-07 4.6E-07 trans-1,2-Dichloroethylene 0.35 0.68 0.48 0.51

3.2E-07 6.2E-07 4.4E-07 4.6E-07 cis-1,2-Dichloroethylene 0.35 0.68 0.48 0.51

2.0E-07 5.2E-07 1.8E-06 8.6E-07 Chloroform 0.23 0.57 2.04 0.94

1.9E-07 3.1E-07 2.7E-07 2.6E-07 1,2-Dichloroethane 0.21 0.34 0.29 0.28

2.5E-06 3.6E-06 3.1E-06 3.0E-06 Methyl Ethyl Ketone (2-Butanone) 2.71 3.93 3.44 3.36

2.3E-07 7.1E-07 3.3E-07 4.2E-07 1,1,1-Trichloroethane 0.25 0.79 0.36 0.47

3.5E-07 7.1E-07 5.4E-07 5.4E-07 Carbon Tetrachloride 0.39 0.79 0.60 0.59

2.2E-07 5.1E-07 3.1E-07 3.5E-07 Benzene 0.24 0.57 0.34 0.38

3.5E-07 7.1E-07 5.4E-07 5.4E-07 1,1,2-Trichloroethane 0.39 0.79 0.60 0.59

2.3E-07 5.1E-07 3.3E-07 3.6E-07 1,2-Dichloropropane 0.25 0.57 0.36 0.39

2.3E-07 5.1E-07 3.3E-07 3.6E-07 Trichloroethylene 0.25 0.57 0.36 0.39

2.3E-07 5.1E-07 3.3E-07 3.6E-07 Dibromomethane 0.25 0.57 0.36 0.39

2.0E-07 4.9E-07 3.0E-07 3.3E-07 Bromodichloromethane 0.23 0.54 0.33 0.37

2.0E-07 4.9E-07 3.0E-07 3.3E-07 cis-1,3-Dichloropropene 0.23 0.54 0.33 0.37

2.1E-07 3.3E-07 2.8E-07 2.7E-07 trans-1,3-Dichloropropene 0.23 0.36 0.31 0.30

1.9E-07 4.9E-07 2.8E-07 3.2E-07 Dibromochloromethane 0.21 0.54 0.31 0.35

1.3E-06 1.9E-06 1.6E-06 1.6E-06 Methyl Isobutyl Ketone 1.40 2.12 1.77 1.76

1.4E-06 2.3E-06 1.8E-06 1.8E-06 Methyl Butyl Ketone (2-Hexanone) 1.54 2.56 2.00 2.03

2.3E-07 7.1E-07 3.3E-07 4.2E-07 Toluene 0.25 0.79 0.36 0.47

2.3E-07 5.1E-07 3.3E-07 3.6E-07 Ethylene Dibromide 0.25 0.57 0.36 0.39

3.5E-07 9.1E-07 5.4E-07 6.0E-07 Tetrachloroethylene 0.39 1.01 0.60 0.67

2.3E-07 5.1E-07 3.3E-07 3.6E-07 Chlorobenzene 0.25 0.57 0.36 0.39

2.3E-07 5.1E-07 3.3E-07 3.6E-07 1,1,1,2-Tetrachloroethane 0.25 0.57 0.36 0.39

2.3E-07 7.1E-07 3.3E-07 4.2E-07 Ethylbenzene 0.25 0.79 0.36 0.47

3.5E-07 7.1E-07 5.6E-07 5.4E-07 m / p-Xylene 0.39 0.79 0.61 0.60

2.3E-07 5.1E-07 3.3E-07 3.6E-07 Styrene 0.25 0.57 0.36 0.39

3.5E-07 7.1E-07 5.4E-07 5.4E-07 o-Xylene 0.39 0.79 0.60 0.59

2.0E-07 6.9E-07 3.0E-07 4.0E-07 Bromoform 0.23 0.76 0.33 0.44

5.2E-07 1.0E-06 6.7E-07 7.4E-07 1,1,2,2-Tetrachloroethane 0.57 1.14 0.73 0.81

3.7E-07 7.3E-07 5.6E-07 5.5E-07 1,2,3-Trichloropropane 0.41 0.81 0.62 0.61

3.5E-07 9.1E-07 5.4E-07 6.0E-07 1,3-Dichlorobenzene 0.39 1.01 0.60 0.67

3.5E-07 9.1E-07 5.4E-07 6.0E-07 1,4-Dichlorobenzene 0.39 1.01 0.60 0.67

3.5E-07 9.1E-07 5.4E-07 6.0E-07 1,2-Dichlorobenzene 0.39 1.01 0.60 0.67

2.3E-05 4.2E-05 3.2E-05 3.2E-05 Total Volatile Organic HAPs: 24.9 45.9 35.4 35.4

dscfm = dry standard cubic feet per minute

dscf = dry standard cubic feet

ng/dscm @ 7%O2 = nanograms per dry standard cubic meter corrected to 7% Oxygen

lb/mmbtu = pounds per million btu

31.31 = Ft^3 per m^3

453.6 = grams per pound

All results not in bold are flagged as BDL. DL used for calculations 

All results in bold are flagged detection level limited (DLL). Fractions with results below DL use DL for calculations.

No results flagged as ADL.

equations:

lb/mmbtu = concentration(ug)/(10^6) *Fd/Vmstd * 1/453.6 * 20.9/(20.9-O2)

ug/dscm @ 7%O2 = mass(ug) * (35.31/Vmstd) * (20.9-7)/(20.9-O2)

Emissions (lb/mmbtu) Concentrations (ug/dscm @7% O2)
Table 5

Unit 2 Semi Volatile Organic HAP Laboratory Results Summary

DTE Energy Belle River Power Plant

East China, Michigan

BTEC Project No. 10-3991.00

Sampling Date: June 22, 2010

Parameter Run 1 Run 2 Run 3 Average

Test Run Date 6/22/2010 6/22/2010 6/22/2010

Test Run Time 8:39-11:04 11:57-14:22 15:29-17:47

Exhaust Gas Flowrate (dscfm) 1,879,744 1,839,548 1,877,667 1,865,653

Sample Volume, Vmstd (dscf) 78.6 76.8 77.5 77.6

O2 Concentration (%, Corrected as per Method 7E) 8.9 8.5 9.0 8.8

CO2 Concentration (%, Corrected as per Method 7E) 10.8 10.8 10.8 10.8

Moisture % 11.05 11.08 10.85 10.99

Fd 9,657 9,657 9,657 9,657

Laboratory Result (ug)

1,2,4-Trichlorobenzene 18 18 18 18

1,2-Dichlorobenzene 18 18 18 18

1,3-Dichlorobenzene 18 18 18 18

1,4-Dichlorobenzene 18 18 18 18

1-Chloronaphthalene 18 18 18 18

1-Methylnaphthalene 0.9 0.9 0.9 0.9

1-Methylphenanthrene 0.9 0.9 0.9 0.9

2,4,5-Trichlorophenol 18 18 18 18

2,4,6-Trichlorophenol 15 15 15 15

2,4-Dichlorophenol 12 12 12 12

2,4-Dimethylphenol 18 18 18 18

2,4-Dinitrophenol 30 30 30 30

2,4-Dinitrotoluene 6666

2,6-Dinitrotoluene 9999

2-Chloronaphthalene 0.9 3.6 0.9 1.8

2-Chlorophenol 24 24 24 24

2-Methylanthracene 0.9 0.9 0.9 0.9

2-Methylnaphthalene 0.45 5.3 5.3 3.7

2-Methylphenol 27 27 27 27

2-Nitroaniline 60 60 60 60

2-Nitrophenol 15 15 15 15

3 & 4-methylphenol 30 30 30 30

3,3'-Dichlorobenzidine 24 24 24 24

3-Methylcholanthrene 1.8 1.8 1.8 1.8

3-Nitroaniline 60 60 60 60

4,6-Dinitro-2-methylphenol 30 30 30 30

4-Bromophenyl phenyl ether 6666

4-Chloro-3-Methylphenol 15 15 15 15

4-Chloroaniline 60 60 60 60

4-Chlorophenyl phenyl ether 9999

4-Nitroaniline 60 60 60 60

4-Nitrophenol 30 30 30 30

7,12-Dimethylbenzo(a)anthracene 1.8 1.8 1.8 1.8

9,10-Dimethylanthracene 1.8 1.8 1.8 1.8

Acenaphthene 0.45 2.3 4.15 2.3

Acenaphthylene 0.45 2.3 0.45 1.1

Aniline 60 60 60 60

Anthracene 0.45 1.3 2.15 1.3

Benzidine 180 180 180 180

Benzo(a)anthracene 0.45 1.3 2.15 1.3

Benzo(a)fluorene 1.8 1.8 1.8 1.8

Benzo(a)pyrene 2.3 2.3 0.45 1.7

Benzo(b)fluoranthene 0.45 2.15 2.15 1.6

Benzo(b)fluorene 0.9 0.9 0.9 0.9

Benzo(e)pyrene 0.9 0.9 0.9 0.9

Benzo(g,h,i)perylene 3333

Benzo(k)fluoranthene 2.3 2.3 2.3 2.3

Benzoic Acid 100 149 125 125

Benzyl Alcohol 18 18 18 18

Benzyl butyl phthalate 6666

Biphenyl 0.9 6.6 12.3 6.6

Bis(2-chloroethoxy)methane 12 12 12 12

Bis(2-chloroethyl)ether 15 15 15 15

Bis(2-chloroisopropyl)ether 15 15 15 15

Bis(2-ethylhexyl)phthalate 66 58 43 56

Carbazole 60 60 60 60

Chrysene 0.45 2.15 1.3 1.3

Coronene 1.8 1.8 1.8 1.8

Dibenz(a,h)anthracene 0.45 3 2.15 1.87

Dibenzo(a,e)pyrene 1.8 1.8 1.8 1.8

Dibenzofuran 60 60 60 60

Diethyl phthalate 9999

Dimethyl phthalate 9999

Di-N-butyl phthalate 9 999

Di-N-octyl phthalate 9999

Fluoranthene 1.8 2.54 2.15 2.2

Fluorene 0.45 0.45 0.45 0.45

Hexachlorobenzene 18 18 18 18

Hexachlorobutadiene 18 18 18 18

Hexachlorocyclopentadiene 18 18 18 18

Hexachloroethane 18 18 18 18

Indeno(1,2,3-cd)pyrene 0.45 2.3 0.45 1.07

Isophorone 30 30 30 30

m-Terphenyl 0.9 0.9 0.9 0.9

Naphthalene 1.32 6 2.6 3.3

Nitrobenzene 18 18 18 18

N-Nitrosodimethylamine 90 90 90 90

N-Nitroso-di-n-propylamine 18 18 18 18

N-Nitrosodiphenylamine 18 18 18 18

o-Terphenyl 0.94 0.91 0.9 0.92

Pentachlorophenol 27 27 27 27

Perylene 1.8 1.8 1.8 1.8

Phenanthrene 0.81 1.55 0.45 0.94

Phenol 15 48 15 26

p-Terphenyl 0.9 0.9 0.9 0.9

Pyrene 5.83 6.15 4.15 5.38

Quinoline 1.8 1.8 1.8 1.8

Tetralin 0.9 0.9 0.9 0.9

dscfm = dry standard cubic feet per minute

dscf = dry standard cubic feet

All results not in bold are flagged as BDL. DL used for calculations

All results in bold are flagged detection level limited (DLL). Fractions with results below DL use DL for calculation

No results flagged as ADL.
Table 6

Unit 2 Semi Volatile Organic HAP Emission Test Results Summary

DTE Energy Belle River Power Plant

East China, Michigan

BTEC Project No. 10-3991.00

Sampling Date: June 22, 2010

Run 1 Run 2 Run 3 Average Compound Run 1 Run 2 Run 3 Average

8.5E-06 8.4E-06 8.7E-06 8.5E-06 1,2,4-Trichlorobenzene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 1,2-Dichlorobenzene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 1,3-Dichlorobenzene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 1,4-Dichlorobenzene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 1-Chloronaphthalene 9.3 9.2 9.6 9.4

4.2E-07 4.2E-07 4.4E-07 4.3E-07 1-Methylnaphthalene 0.5 0.5 0.5 0.5

4.2E-07 4.2E-07 4.4E-07 4.3E-07 1-Methylphenanthrene 0.5 0.5 0.5 0.5

8.5E-06 8.4E-06 8.7E-06 8.5E-06 2,4,5-Trichlorophenol 9.3 9.2 9.6 9.4

7.1E-06 7.0E-06 7.3E-06 7.1E-06 2,4,6-Trichlorophenol 7.8 7.7 8.0 7.8

5.7E-06 5.6E-06 5.8E-06 5.7E-06 2,4-Dichlorophenol 6.2 6.2 6.4 6.3

8.5E-06 8.4E-06 8.7E-06 8.5E-06 2,4-Dimethylphenol 9.3 9.2 9.6 9.4

1.4E-05 1.4E-05 1.5E-05 1.4E-05 2,4-Dinitrophenol 15.6 15.4 16.0 15.7

2.8E-06 2.8E-06 2.9E-06 2.8E-06 2,4-Dinitrotoluene 3.1 3.1 3.2 3.1

4.2E-06 4.2E-06 4.4E-06 4.3E-06 2,6-Dinitrotoluene 4.7 4.6 4.8 4.7

4.2E-07 1.7E-06 4.4E-07 8.4E-07 2-Chloronaphthalene 0.5 1.8 0.5 0.9

1.1E-05 1.1E-05 1.2E-05 1.1E-05 2-Chlorophenol 12.5 12.3 12.8 12.5

4.2E-07 4.2E-07 4.4E-07 4.3E-07 2-Methylanthracene 0.5 0.5 0.5 0.5

2.1E-07 2.5E-06 2.6E-06 1.7E-06 2-Methylnaphthalene 0.2 2.7 2.8 1.9

1.3E-05 1.3E-05 1.3E-05 1.3E-05 2-Methylphenol 14.0 13.9 14.4 14.1

2.8E-05 2.8E-05 2.9E-05 2.8E-05 2-Nitroaniline 31.2 30.8 32.0 31.3

7.1E-06 7.0E-06 7.3E-06 7.1E-06 2-Nitrophenol 7.8 7.7 8.0 7.8

1.4E-05 1.4E-05 1.5E-05 1.4E-05 3 & 4-methylphenol 15.6 15.4 16.0 15.7

1.1E-05 1.1E-05 1.2E-05 1.1E-05 3,3'-Dichlorobenzidine 12.5 12.3 12.8 12.5

8.5E-07 8.4E-07 8.7E-07 8.5E-07 3-Methylcholanthrene 0.9 0.9 1.0 0.9

2.8E-05 2.8E-05 2.9E-05 2.8E-05 3-Nitroaniline 31.2 30.8 32.0 31.3

1.4E-05 1.4E-05 1.5E-05 1.4E-05 4,6-Dinitro-2-methylphenol 15.6 15.4 16.0 15.7

2.8E-06 2.8E-06 2.9E-06 2.8E-06 4-Bromophenyl phenyl ether 3.1 3.1 3.2 3.1

7.1E-06 7.0E-06 7.3E-06 7.1E-06 4-Chloro-3-Methylphenol 7.8 7.7 8.0 7.8

2.8E-05 2.8E-05 2.9E-05 2.8E-05 4-Chloroaniline 31.2 30.8 32.0 31.3

4.2E-06 4.2E-06 4.4E-06 4.3E-06 4-Chlorophenyl phenyl ether 4.7 4.6 4.8 4.7

2.8E-05 2.8E-05 2.9E-05 2.8E-05 4-Nitroaniline 31.2 30.8 32.0 31.3

1.4E-05 1.4E-05 1.5E-05 1.4E-05 4-Nitrophenol 15.6 15.4 16.0 15.7

8.5E-07 8.4E-07 8.7E-07 8.5E-07 7,12-Dimethylbenzo(a)anthracene 0.9 0.9 1.0 0.9

8.5E-07 8.4E-07 8.7E-07 8.5E-07 9,10-Dimethylanthracene 0.9 0.9 1.0 0.9

2.1E-07 1.1E-06 2.0E-06 1.1E-06 Acenaphthene 0.2 1.2 2.2 1.2

2.1E-07 1.1E-06 2.2E-07 5.0E-07 Acenaphthylene 0.2 1.2 0.2 0.6

2.8E-05 2.8E-05 2.9E-05 2.8E-05 Aniline 31.2 30.8 32.0 31.3

2.1E-07 6.1E-07 1.0E-06 6.2E-07 Anthracene 0.2 0.7 1.1 0.7

8.5E-05 8.4E-05 8.7E-05 8.5E-05 Benzidine 93.5 92.4 96.0 94.0

2.1E-07 6.1E-07 1.0E-06 6.2E-07 Benzo(a)anthracene 0.2 0.7 1.1 0.7

8.5E-07 8.4E-07 8.7E-07 8.5E-07 Benzo(a)fluorene 0.9 0.9 1.0 0.9

1.1E-06 1.1E-06 2.2E-07 7.9E-07 Benzo(a)pyrene 1.2 1.2 0.2 0.9

2.1E-07 1.0E-06 1.0E-06 7.5E-07 Benzo(b)fluoranthene 0.2 1.1 1.1 0.8

4.2E-07 4.2E-07 4.4E-07 4.3E-07 Benzo(b)fluorene 0.5 0.5 0.5 0.5

4.2E-07 4.2E-07 4.4E-07 4.3E-07 Benzo(e)pyrene 0.5 0.5 0.5 0.5

1.4E-06 1.4E-06 1.5E-06 1.4E-06 Benzo(g,h,i)perylene 1.6 1.5 1.6 1.6

1.1E-06 1.1E-06 1.1E-06 1.1E-06 Benzo(k)fluoranthene 1.2 1.2 1.2 1.2

4.7E-05 6.9E-05 6.0E-05 5.9E-05 Benzoic Acid 51.9 76.5 66.7 65.0

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Benzyl Alcohol 9.3 9.2 9.6 9.4

2.8E-06 2.8E-06 2.9E-06 2.8E-06 Benzyl butyl phthalate 3.1 3.1 3.2 3.1

4.2E-07 3.1E-06 5.9E-06 3.1E-06 Biphenyl 0.5 3.4 6.6 3.5

5.7E-06 5.6E-06 5.8E-06 5.7E-06 Bis(2-chloroethoxy)methane 6.2 6.2 6.4 6.3

7.1E-06 7.0E-06 7.3E-06 7.1E-06 Bis(2-chloroethyl)ether 7.8 7.7 8.0 7.8

7.1E-06 7.0E-06 7.3E-06 7.1E-06 Bis(2-chloroisopropyl)ether 7.8 7.7 8.0 7.8

3.1E-05 2.7E-05 2.1E-05 2.6E-05 Bis(2-ethylhexyl)phthalate 34.3 29.8 22.9 29.0

2.8E-05 2.8E-05 2.9E-05 2.8E-05 Carbazole 31.2 30.8 32.0 31.3

2.1E-07 1.0E-06 6.3E-07 6.1E-07 Chrysene 0.2 1.1 0.7 0.7

8.5E-07 8.4E-07 8.7E-07 8.5E-07 Coronene 0.9 0.9 1.0 0.9

2.1E-07 1.4E-06 1.0E-06 8.8E-07 Dibenz(a,h)anthracene 0.2 1.5 1.1 1.0

8.5E-07 8.4E-07 8.7E-07 8.5E-07 Dibenzo(a,e)pyrene 0.9 0.9 1.0 0.9

2.8E-05 2.8E-05 2.9E-05 2.8E-05 Dibenzofuran 31.2 30.8 32.0 31.3

4.2E-06 4.2E-06 4.4E-06 4.3E-06 Diethyl phthalate 4.7 4.6 4.8 4.7

4.2E-06 4.2E-06 4.4E-06 4.3E-06 Dimethyl phthalate 4.7 4.6 4.8 4.7

4.2E-06 4.2E-06 4.4E-06 4.3E-06 Di-N-butyl phthalate 4.7 4.6 4.8 4.7

4.2E-06 4.2E-06 4.4E-06 4.3E-06 Di-N-octyl phthalate 4.7 4.6 4.8 4.7

8.5E-07 1.2E-06 1.0E-06 1.0E-06 Fluoranthene 0.9 1.3 1.1 1.1

2.1E-07 2.1E-07 2.2E-07 2.1E-07 Fluorene 0.2 0.2 0.2 0.2

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Hexachlorobenzene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Hexachlorobutadiene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Hexachlorocyclopentadiene 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Hexachloroethane 9.3 9.2 9.6 9.4

2.1E-07 1.1E-06 2.2E-07 5.0E-07 Indeno(1,2,3-cd)pyrene 0.2 1.2 0.2 0.6

1.4E-05 1.4E-05 1.5E-05 1.4E-05 Isophorone 15.6 15.4 16.0 15.7

4.2E-07 4.2E-07 4.4E-07 4.3E-07 m-Terphenyl 0.5 0.5 0.5 0.5

6.2E-07 2.8E-06 1.3E-06 1.6E-06 Naphthalene 0.7 3.1 1.4 1.7

8.5E-06 8.4E-06 8.7E-06 8.5E-06 Nitrobenzene 9.3 9.2 9.6 9.4

4.2E-05 4.2E-05 4.4E-05 4.3E-05 N-Nitrosodimethylamine 46.7 46.2 48.0 47.0

8.5E-06 8.4E-06 8.7E-06 8.5E-06 N-Nitroso-di-n-propylamine 9.3 9.2 9.6 9.4

8.5E-06 8.4E-06 8.7E-06 8.5E-06 N-Nitrosodiphenylamine 9.3 9.2 9.6 9.4

4.4E-07 4.2E-07 4.4E-07 4.3E-07 o-Terphenyl 0.5 0.5 0.5 0.5

1.3E-05 1.3E-05 1.3E-05 1.3E-05 Pentachlorophenol 14.0 13.9 14.4 14.1

8.5E-07 8.4E-07 8.7E-07 8.5E-07 Perylene 0.9 0.9 1.0 0.9

3.8E-07 7.2E-07 2.2E-07 4.4E-07 Phenanthrene 0.4 0.8 0.2 0.5

7.1E-06 2.2E-05 7.3E-06 1.2E-05 Phenol 7.8 24.6 8.0 13.5

4.2E-07 4.2E-07 4.4E-07 4.3E-07 p-Terphenyl 0.5 0.5 0.5 0.5

2.7E-06 2.9E-06 2.0E-06 2.5E-06 Pyrene 3.0 3.2 2.2 2.8

8.5E-07 8.4E-07 8.7E-07 8.5E-07 Quinoline 0.9 0.9 1.0 0.9

4.2E-07 4.2E-07 4.4E-07 4.3E-07 Tetralin 0.5 0.5 0.5 0.5

7.6E-04 8.0E-04 7.9E-04 7.8E-04 Semi Organic Volatile HAPs Totals 836 882 873 864

dscfm = dry standard cubic feet per minute

dscf = dry standard cubic feet

ng/dscm @ 7%O2 = nanograms per dry standard cubic meter corrected to 7% Oxygen

lb/mmbtu = pounds per million btu

31.31 = Ft^3 per m^3

453.6 = grams per pound

All results not in bold are flagged as BDL. DL used for calculations 

All results in bold are flagged detection level limited (DLL). Fractions with results below DL use DL for calculations.

No results flagged as ADL.

equations:

lb/mmbtu = concentration(ug)/(10^6) *Fd/Vmstd * 1/453.6 * 20.9/(20.9-O2)

ug/dscm @ 7%O2 = mass(ug) * (35.31/Vmstd) * (13.9)/(20.9-O2)

Emissions (lb/mmbtu) Concentrations (ug/dscm @7% O2)
Figures 
diameter = 306"

Points Distance "

12 6.4

11 20.5

10 36.1

9 54.2

8 76.5

7 108.9

6 197.1

5 229.5

4 251.8

3 269.9

2 285.5

1 299.6

Figure 1

Site: Sampling Dates:

DTE Energy

Belle River Power Plant

Unit 2 Exhaust

BT Environmental Consulting, 

Inc.

2615 Wolcott Street

Ferndale, Michigan

June 22, 2010

Not to Scale

>2 diameters

>8 diameters
Figure No. 2

Site: Sampling Date:

USEPA Method 3A, 6C, and 10 June 22, 2010

DTE Belle River Power Plant

Unit 2

BT Environmental Consulting Inc. 

2615 Wolcott 

Ferndale MI 48220

Heated Sample Line

Flow Controller

Pump

Moisture Removal System

 Vent

Data Acquisition System, Laptop 

PC, & Pdaq Software

Calibration Line

Teledyne paramagnetic O2 gas 

analyzer

Calibration Gas

Mid High Zero

TECO 48 CO gas analyzer

 Western Research

 SO2 Analyzer

Teledyne infrared CO2 gas 

analyzer
Figure No. 3

Site: Sampling Date:

USEPA Method 25A

DTE Belle River Power Plant

Unit 2

BT Environmental Consulting, Inc.

2615 Wolcott Street

Ferndale, Michigan

June 22, 2010

Data Acquisition System

Heated Sample Line

Calibration Gases 

(Fed to Probe Tip)

Calibration Lines

VIG Model 20

Total Hydrocarbon Analyzer
Figure No. 4

Site: Sampling Date:USEPA Method 0010DTE Belle River Power PlantUnit 2

BT Environmental Consult

2615 Wolcott Michigan

June 22, 2010

Silic

Heated Filter Box

S-Type Pitot w/ Thermocouple

Heated Probe w/ Glass Liner & Glass or SS Nozzle

Meter Rig

Temp.

ProbeFilter

On

Off

-

+

00:00

1 2 3 4 5

Verticle Condenser Sorbent Trap

Pot Bellied Impinger 100 mL DI H2O Empty
Figure No. 5

Site: Sampling Date:USEPA Method 0011 Sampling TrainDTE Belle River Power PlantUnit 2

BT Environmental Cons2615 Wolcott Michigan

June 22, 2010

Heated Filter Box

S-type pitot w/ thermocouple

Heated probe with glass liner & nozzle

Meter Rig

Temp.

ProbeFilter

On

Off

-

+

00:00

1 2 3 4 5

200 mL DNPH 100 mL DNPHl E
Figure No. 6

Site: Sampling Date:USEPA Method 0031DTE Belle River Power PlantUnit 2

BT Environmental Cons2615 Wolcott Michigan

June 22, 2010

Sampling Module

Heated probe with glass liner

Meter Rig

Temp.

ProbeFilter

On

Off

-

+

00:00

1 2 3 4 5

Charcoal Trap

Condensers

Tenax-GC Sorbent Traps

Anasorb-747 

Sorbent Trap

Condensate Trap

Silica Gel

Three Way Glass/Teflon 

Isolation Valve

Glass Wool Filter
Appendix A 

Field and Computer Generated Raw Data and Field Notes 
Plant Run No.M

_

0011-R1 Date Job # 

Address Checks 

Location Reag. Box ______ Samp. box _____ As foot2 510.71 Vacuum _____ Personnel Umbical

______

Meter box MB-4 Y 0.996 Init DGM

_____ 

% Moisture 10.8 Meas Stack TC

______

TC Readout

_____

ΔH@ 1.3125 1.680 Final DGM _____ 

PBr in “Hg 29.93 Tedlar Bag ______ Pitot 10' Cp 0.840 Leak rate _____ P static in H2O -1.90 Orsat Pump ______ Nozzle _____ DN in inches 0.180 Pitot _____ K factor 0.6 Est. Moisture 6.4 gm H2O 196.0 Analyzer 10.8 %CO2 Nozzle _____ 

Filter # ____NA ___________ ___________ Bwmeas 10.8 8.9 %O2 Stack TC _____ Filter Wt. _________ ___________ ___________ Bwsat 100.0 Fo= 1.114 Fd= 9657 Ms 

Copyright by Walter Smith - used with permission

Traverse Elapsed Time Clock Gas Velocity Stack Orifice Pressure Probe Filter Imping. PPoint In Minutes Time Meter Temp. ΔH in H2O Temp. Temp. Temp. 

No. Begin End 24 hr Reading ΔP °F inlet Outlet Desired Actual °F °F °F 

C3 0.0 5.0 8:27 870.056 2.300 317 87 87 1.42 1.44 251 252 63 

C3 5.0 10.0 8:32 873.680 2.300 318 88 87 1.42 1.44 252 253 61 

C2 10.0 15.0 8:37 877.110 2.400 318 88 87 1.48 1.50 250 252 60 

C2 15.0 20.0 8:42 880.700 2.400 318 89 87 1.48 1.50 253 248 60 

C1 20.0 25.0 8:47 884.190 2.400 318 91 87 1.48 1.51 250 249 58 

C1 25.0 30.0 8:52 887.750 2.400 317 92 87 1.48 1.51 247 250 57 

B3 30.0 35.0 9:19 891.340 2.000 316 87 86 1.23 1.25 242 248 62 

B3 35.0 40.0 9:24 894.680 2.000 316 90 87 1.23 1.25 254 260 60 

B2 40.0 45.0 9:29 897.920 2.200 316 92 88 1.36 1.39 259 253 62 

B2 45.0 50.0 9:34 901.380 2.200 317 93 88 1.36 1.39 251 250 62 

B1 50.0 55.0 9:39 904.850 2.200 317 95 89 1.36 1.39 245 250 60 

B1 55.0 60.0 9:44 908.320 2.200 317 95 90 1.36 1.39 245 248 60 

A3 60.0 65.0 9:56 911.690 1.600 317 91 90 0.99 1.01 248 250 62 

A3 65.0 70.0 10:01 914.620 1.600 317 94 90 0.99 1.01 255 252 61 

A2 70.0 75.0 10:06 917.550 2.100 317 95 90 1.29 1.33 252 250 62 

A2 75.0 80.0 10:11 920.820 2.100 317 96 90 1.29 1.33 248 249 60 

A1 80.0 85.0 10:16 924.170 1.900 317 96 90 1.17 1.20 250 251 58 

A1 85.0 90.0 10:21 927.430 1.900 317 97 91 1.17 1.20 249 250 62 

D3 90.0 95.0 10:34 930.580 1.900 316 91 91 1.17 1.20 249 251 61 

D3 95.0 100.0 10:39 933.850 1.900 317 94 91 1.17 1.20 250 253 58 

D2 100.0 105.0 10:44 937.100 1.900 317 96 91 1.17 1.20 252 251 58 

D2 105.0 110.0 10:49 940.280 1.900 317 97 91 1.17 1.20 250 250 59 

D1 110.0 115.0 10:54 943.440 2.100 317 97 91 1.29 1.33 249 250 59 

D1 115.0 120.0 10:59 946.850 2.100 317 98 92 1.29 1.33 248 249 60 

11:04 950.200

Final changed-> 11:04 950.200 0.463 1.180 6.911 3.679 0.287

Sum or avg 120.0 79.502 2.077 317.0 93 89 1.313 Max 

DTE Belle RiverUnit 2 ExhaustTSEast China, MI Equipment ID

6/22/2010

Cal Constants

Dry Gas Meter

Temperature
Plant Run No.M

_

0011-R2 Date Job # 

Address Checks Pre 

Location Reag. Box ______ Samp. box _____ As foot2 510.71 Vacuum _____ Personnel Umbical

______

Meter box MB-4 Y 0.996 Init DGM

_____

% Moisture 11.0 Meas Stack TC

______

TC Readout

_____

ΔH@ 1.37666667 1.680 Final DGM _____ 

PBr in “Hg 29.93 Tedlar Bag ______ Pitot 10' Cp 0.840 Leak rate _____ P static in H2O -1.90 Orsat Pump ______ Nozzle _____ DN in inches 0.180 Pitot _____ K factor 0.62 Est. Moisture 6.4 gm H2O 204.0 Orsat 10.8 %CO2 Nozzle _____ 

Filter # ____NA ___________ ___________ Bwmeas 11.0 8.5 %O2 Stack TC _____ Filter Wt. _________ ___________ ___________ Bwsat 100.0 Fo= 1.14972274 Fd= 9657 Ms 28.

Copyright by Walter Smith

Traverse Elapsed Time Clock Gas Velocity Stack Orifice Pressure Probe Filter Imping. PumPoint In Minutes Time Meter Temp. ΔH in H2O Temp. Temp. Temp. Vac

No. Begin End 24 hr Reading ΔP °F inlet Outlet Desired Actual °F °F °F Hg

D3 0.0 5.0 11:57 951.602 1.800 318 89 89 1.11 1.13 257 259 60 3D3 5.0 10.0 12:02 954.890 1.800 317 89 89 1.11 1.13 252 249 60 3D2 10.0 15.0 12:07 958.120 2.100 317 89 89 1.30 1.32 250 252 59 3D2 15.0 20.0 12:12 961.470 2.100 317 93 89 1.30 1.32 250 250 60 3D1 20.0 25.0 12:17 964.830 2.300 317 95 90 1.42 1.46 247 250 62 3D1 25.0 30.0 12:22 968.320 2.300 317 96 90 1.42 1.46 248 248 61 3

A3 30.0 35.0 12:33 971.810 2.100 317 91 90 1.30 1.51 250 250 62 3A3 35.0 40.0 12:38 975.480 2.100 317 96 91 1.30 1.51 250 247 62 3A2 40.0 45.0 12:43 979.180 2.200 317 97 91 1.36 1.40 251 250 62 3A2 45.0 50.0 12:48 982.690 2.200 317 98 92 1.36 1.40 248 249 60 3A1 50.0 55.0 12:53 986.080 2.300 318 98 92 1.42 1.46 249 250 61 3A1 55.0 60.0 12:58 989.570 2.300 317 99 92 1.42 1.46 250 250 60 3

B3 60.0 65.0 13:15 992.980 1.900 318 98 91 1.17 1.20 250 248 62 3B3 65.0 70.0 13:20 996.320 1.900 318 96 94 1.17 1.20 258 253 62 3B2 70.0 75.0 13:25 999.560 2.100 318 97 93 1.30 1.33 250 248 60 3B2 75.0 80.0 13:30 1002.950 2.100 318 98 93 1.30 1.33 248 250 61 3

B1 80.0 85.0 13:35 1006.340 2.200 318 99 92 1.36 1.40 251 251 62 3

B1 85.0 90.0 13:40 1009.450 2.200 318 99 93 1.36 1.40 247 249 65 3

C3 90.0 95.0 13:52 1012.830 2.100 318 94 93 1.30 1.33 252 252 63 3

C3 95.0 100.0 13:57 1016.120 2.100 319 98 94 1.30 1.33 251 257 62 3

C2 100.0 105.0 14:02 1019.440 2.300 319 98 94 1.42 1.46 251 249 63 3

C2 105.0 110.0 14:07 1022.900 2.300 320 99 94 1.42 1.46 248 250 63 3C1 110.0 115.0 14:12 1026.320 2.400 320 100 94 1.48 1.52 250 251 62 3C1 115.0 120.0 14:17 1029.800 2.400 320 100 94 1.48 1.52 257 250 63 3

120.0 14:33 1033.330

Final changed-> 14:33 1033.330 0.339 2.036 6.976 3.682 0.236

Sum or avg 120.0 81.73 2.147 317.9 96 92 1.377 Max 3

DTE Belle RiverEast China, MIUnit 2 ExhaustTS

Equipment ID

6/22/2010

Cal Constants

Dry Gas Meter

Temperature 
Plant Run No.M

_

0011-R3 Date Job # 

Address Checks Pre 

Location Reag. Box ______ Samp. box _____ As foot2 510.71 Vacuum _____ Personnel Umbical

______

Meter box MB-4 Y 0.996 Init DGM

_____

% Moisture 10.7 Meas Stack TC

______

TC Readout

_____

ΔH@ 1.38333333 1.680 Final DGM _____ 

PBr in “Hg 29.93 Tedlar Bag ______ Pitot 10' Cp 0.840 Leak rate _____ P static in H2O -1.90 Orsat Pump ______ Nozzle _____ DN in inches 0.180 Pitot _____ K factor 0.62 Est. Moisture 6.4 gm H2O 196.0 Orsat 10.8 %CO2 Nozzle _____ 

Filter # ____NA ___________ ___________ Bwmeas 10.7 9.0 %O2 Stack TC _____ Filter Wt. _________ ___________ ___________ Bwsat 100.0 Fo= 1.1 Fd= 9657 Ms 28

Copyright by Walter Smith

Traverse Elapsed Time Clock Gas Velocity Stack Orifice Pressure Probe Filter Imping. Pum

Point In Minutes Time Meter Temp. ΔH in H2O Temp. Temp. Temp. Vac

No. Begin End 24 hr Reading ΔP °F inlet Outlet Desired Actual °F °F °F Hg

C3 0.0 5.0 15:29 34.841 2.400 321 93 92 1.49 1.48 253 250 60 2

C3 5.0 10.0 15:34 38.420 2.400 322 96 92 1.49 1.48 253 250 61 2C2 10.0 15.0 15:39 42.010 2.300 322 98 93 1.43 1.43 251 249 62 2C2 15.0 20.0 15:44 45.510 2.300 322 99 93 1.43 1.43 247 249 63 2C1 20.0 25.0 15:49 48.950 2.300 322 100 93 1.43 1.43 248 249 62 3C1 25.0 30.0 15:54 52.420 2.300 320 101 94 1.43 1.43 249 250 61 3B3 30.0 35.0 16:05 55.860 2.200 317 96 95 1.37 1.37 249 249 60 3B3 35.0 40.0 16:10 59.210 2.200 320 99 95 1.37 1.37 251 249 58 3B2 40.0 45.0 16:15 62.500 2.500 322 100 95 1.55 1.56 253 251 58 3B2 45.0 50.0 16:20 65.720 2.500 322 101 95 1.55 1.56 249 250 60 3B1 50.0 55.0 16:25 69.650 2.100 322 101 95 1.31 1.27 244 249 61 3B1 55.0 60.0 16:30 73.040 2.100 321 101 96 1.31 1.27 245 249 60 3

A3 60.0 65.0 16:41 76.130 2.500 319 98 96 1.55 1.56 249 250 62 3A3 65.0 70.0 16:46 79.960 2.500 321 101 96 1.55 1.56 259 252 60 3A2 70.0 75.0 16:51 83.600 2.300 321 102 96 1.43 1.44 253 250 62 3A2 75.0 80.0 16:56 87.230 2.300 321 102 96 1.43 1.44 249 250 61 3A1 80.0 85.0 17:01 90.780 1.700 322 102 96 1.06 1.06 250 249 62 3A1 85.0 90.0 17:06 93.930 1.700 320 103 97 1.06 1.06 251 250 61 3

D3 90.0 95.0 17:17 96.920 2.200 321 97 97 1.37 1.37 246 252 61 3D3 95.0 100.0 17:22 99.870 2.200 322 101 97 1.37 1.37 255 250 60 3D2 100.0 105.0 17:27 103.730 2.300 322 101 97 1.43 1.44 260 245 61 3

D2 105.0 110.0 17:32 107.290 2.300 322 102 97 1.43 1.44 249 250 60 3

D1 110.0 115.0 17:37 110.680 1.900 323 102 97 1.18 1.19 250 250 60 3

D1 115.0 120.0 17:42 114.090 1.900 323 102 97 1.18 1.19 250 250 62 3

120.0 17:47 117.090

Final 17:47 117.090 0.458 2.654 4.931 3.309 0.288

Sum or avg 120.0 81.621 2.219 321.3 99.9 95.3 1.383 Max 3

Cal Constants

Temperature

DTE Belle River

6/22/2010

East China, MIUnit 2 ExhaustTS

Dry Gas Meter

Equipment ID
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 10Test Number Run #1 M-0010 Condensate Volume (Vlc) 183Operator MS/JP Silica Gel Weight Gain (Vlc) 24

Filter Number NA Nozzle Diameter (in.) 0.18Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.01@12"Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.01@12"Stack Dimensions (in.) 306 Traverse points 3x4Pitot Tube Number 9ft Pitot Corr. Factor (Cp) 0.84Meter Number MB-3 Meter Corr. Factor (Y) 1.012Meter Isokinetic Factor (Kiso) - Orsat Results (%)Delta ∆H@ 1.56 CO2 10.79

 O2 8.88

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

6 0 8:39 9 321 2.30 1.34 391.31 91 89 65 251 250 575 5 10 321 2.30 1.34 92 90 65 251 250 574 10 10 321 2.40 1.40 93 90 64 255 250 523 15 10 321 2.40 1.40 95 90 64 256 251 512 20 9 320 2.20 1.29 95 90 62 250 250 511 25 9 320 2.20 1.29 96 91 60 247 251 51

STOP 30 - - - - - - - - - -

6 30 9:19 10 320 2.40 1.40 90 91 62 249 245 565 35 10 320 2.40 1.40 93 91 61 252 250 524 40 10 320 2.40 1.40 94 91 57 251 250 503 45 10 320 2.40 1.40 96 91 56 251 250 502 50 10 320 2.20 1.29 97 91 56 249 250 501 55 10 320 2.20 1.29 98 91 57 248 250 51

STOP 60 - - - - - - - - - -

6 60 9:56 10 321 2.30 1.34 93 92 60 245 250 525 65 10 321 2.30 1.34 96 92 59 251 250 514 70 10 321 2.20 1.29 97 92 58 254 250 523 75 10 321 2.20 1.29 98 92 58 253 250 522 80 10 321 2.00 1.18 98 93 60 251 249 531 85 10 321 2.00 1.18 100 93 61 251 251 54

STOP 90 - - - - - - - - - -

6 90 10:34 10 320 2.10 1.23 94 93 65 250 253 615 95 10 321 2.10 1.23 97 93 65 252 252 604 100 10 321 2.20 1.29 98 93 64 251 251 603 105 10 321 2.20 1.29 99 94 64 250 249 602 110 10 321 1.90 1.12 100 94 64 252 251 611 115 10 321 1.90 1.12 101 94 64 250 249 60

END 120 11:04 - - - - 472.185 - - - - - -

Average 120 320.6 2.2 1.3 80.9 95.9 91.7 61.3 250.8 250.1 54.3

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

93.79
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 10Test Number Run #2 M-0010 Condensate Volume (Vlc) 183Operator MS/JP Silica Gel Weight Gain (Vlc) 20

Filter Number NA Nozzle Diameter (in.) 0.18Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.01@14"Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.005@14"Stack Dimensions (in.) 306 Traverse points 3x4Pitot Tube Number 9ft Pitot Corr. Factor (Cp) 0.84Meter Number MB-3 Meter Corr. Factor (Y) 1.012Meter Isokinetic Factor (Kiso) - Orsat Results (%)Delta ∆H@ 1.56 CO2 10.82

 O2 8.46

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

6 0 11:57 7 320 2.10 1.23 472.452 91 91 66 250 249 645 5 8 321 2.10 1.23 92 91 66 247 249 594 10 8 321 2.20 1.28 93 91 65 252 250 533 15 8 321 2.20 1.28 95 91 65 249 250 522 20 8 321 2.00 1.17 97 91 64 251 250 541 25 8 321 2.00 1.17 97 92 64 250 250 54

STOP 30 - - - - - - - - - -

6 30 12:33 9 321 2.20 1.29 93 92 64 248 251 555 35 9 322 2.20 1.29 97 92 64 251 250 544 40 9 322 2.20 1.29 99 93 63 255 250 553 45 8 322 2.20 1.29 100 93 64 252 250 552 50 8 322 2.00 1.18 101 94 64 249 250 541 55 8 322 2.00 1.18 102 95 64 250 250 54

STOP 60 - - - - - - - - - -

6 60 13:15 9 322 2.10 1.23 96 94 66 250 248 545 65 8 322 2.10 1.23 98 94 66 249 250 544 70 8 322 2.20 1.29 99 95 64 252 250 533 75 8 322 2.20 1.29 100 95 64 250 250 542 80 8 322 1.90 1.12 102 95 64 251 250 551 85 8 321 1.90 1.12 102 95 65 250 250 59

STOP 90 - - - - - - - - - -

6 90 13:52 8 321 2.20 1.30 97 96 65 248 249 545 95 8 322 2.20 1.30 99 96 64 250 251 554 100 8.5 322 2.30 1.36 100 96 64 248 247 553 105 8.5 322 2.30 1.36 102 96 64 249 249 552 110 8.5 323 2.10 1.24 103 96 63 251 247 551 115 9 323 2.10 1.24 104 96 64 246 249 56

END 120 14:22 - - - - 551.840 - - - - - -

Average 120 321.7 2.13 1.25 79.388 98 94 64 250 250 55

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

96.02
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 11.2Test Number Run #3 M-0010 Condensate Volume (Vlc) 168Operator MS/JP Silica Gel Weight Gain (Vlc) 32

Filter Number NA Nozzle Diameter (in.) 0.18Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.01@14"Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.01@14"Stack Dimensions (in.) 306 Traverse points 3x4Pitot Tube Number 9ft Pitot Corr. Factor (Cp) 0.84Meter Number MB-3 Meter Corr. Factor (Y) 1.012Meter Isokinetic Factor (Kiso) - Orsat Results (%)Delta ∆H@ 1.56 CO2 10.8

 O2 9.02

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

6 0 15:29 6 325 2.30 1.32 553.081 94 93 65 252 250 605 5 6.5 325 2.30 1.32 97 94 65 250 250 604 10 7 325 2.40 1.38 99 94 65 254 248 603 15 7 326 2.40 1.38 101 95 64 254 250 592 20 7 326 2.10 1.21 102 95 64 250 250 591 25 6 326 2.10 1.21 103 96 64 250 249 60

STOP 30 15:59 - - - - - - - - - -

6 30 16:05 7 325 2.30 1.32 98 96 63 248 249 605 35 7 325 2.30 1.32 102 97 63 256 251 604 40 7 325 2.20 1.27 104 97 63 251 252 593 45 7 325 2.20 1.27 104 97 63 250 250 592 50 7 325 2.00 1.16 105 98 63 251 249 601 55 7 325 2 1.16 105 98 63 250 250 60

STOP 60 16:35 - - - - - - - - - -

6 60 16:41 7 325 2.30 1.33 99 98 62 252 250 605 65 7 325 2.30 1.33 103 98 63 251 251 604 70 7 325 2.30 1.33 104 98 63 250 250 573 75 7 325 2.30 1.33 105 98 64 250 250 582 80 7 324 2.00 1.16 105 98 62 252 250 601 85 7 326 2.00 1.16 108 99 62 250 251 60

STOP 90 17:11 - - - - - - - - - -

6 90 17:17 7 325 2.20 1.27 100 99 63 250 250 625 95 7 325 2.20 1.27 103 99 63 252 249 614 100 8 326 2.30 1.33 105 99 64 251 250 603 105 8 326 2.30 1.33 106 99 63 250 250 602 110 8 326 2.20 1.28 106 99 62 249 250 611 115 8 326 2.20 1.28 107 100 62 249 251 60

END 120 17:47 - - - - 633.681 - - - - - -

Average 120 325.3 2.2 1.3 80.600 102.7 97.3 63.3 250.9 250.0 59.8

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

99.98
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 10

Test Number Run #1 M-0031 Condensate Volume (Vlc) 1

Operator TW Silica Gel Weight Gain (Vlc) 1

Filter Number NA Nozzle Diameter (in.) NA

Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.02@25"

Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.01@12"

Stack Dimensions (in.) 306 Traverse points 1

Pitot Tube Number NA Pitot Corr. Factor (Cp) NA

Meter Number VOS Meter Corr. Factor (Y) 0.98

Meter Isokinetic Factor (Kiso) - Orsat Results (%)

Delta ∆H@ 0.93 CO2 10.79

 O2 8.88

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

0 8:28 18 NA NA NA 1009.00 89 89 66 249 NA NA

10 8:38 22 NA NA NA 1015.00 89 89 58 245 NA NA20 8:48 22 NA NA NA 1023.00 91 91 58 244 NA NA30 8:58 22 NA NA NA 1030.00 92 92 59 245 NA NA40 - - - - - - - - - - NA NA

END 9:12 15 NA NA NA 1036.00 92 92 59 245 - -

0 9:41 20 NA NA NA 1040.00 93 93 69 243 NA NA

10 9:51 17 NA NA NA 1046.50 93 93 66 247 NA NA20 10:01 17 NA NA NA 1050.10 94 94 66 246 NA NA30 10:11 16 NA NA NA 1056.10 96 95 66 248 NA NA40 10:21 15 NA NA NA 1061.15 96 95 66 247 NA NA

END - - - - - - - - - - - -

0 10:55 14 NA NA NA 1064.17 93 93 67 245 NA NA

10 11:05 14 NA NA NA 1070.00 93 93 64 248 NA NA20 11:15 14 NA NA NA 1074.90 92 96 64 249 NA NA30 11:25 14 NA NA NA 1079.00 93 93 63 247 NA NA

11:35 15 NA NA NA 1083.51 93 94 63 249 NA NA

Average 40 #DIV/0! #DIV/0! #DIV/0! 65.49 92.6 92.8 63.6 246.5 #DIV/0! #DIV/0!

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

92.70
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 10

Test Number Run #2 M-0031 Condensate Volume (Vlc) 1

Operator TW Silica Gel Weight Gain (Vlc) 0

Filter Number NA Nozzle Diameter (in.) NA

Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.006@24"

Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.002@17"

Stack Dimensions (in.) 306 Traverse points 1

Pitot Tube Number NA Pitot Corr. Factor (Cp) NA

Meter Number VOS Meter Corr. Factor (Y) 0.98

Meter Isokinetic Factor (Kiso) - Orsat Results (%)

Delta ∆H@ 0.93 CO2 10.82

 O2 8.46

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

0 12:09 13 NA NA NA 1086.37 92 92 68 246 NA NA

10 13 NA NA NA 1091.00 92 93 65 250 NA NA20 13 NA NA NA 1095.30 92 93 65 246 NA NA30 15 NA NA NA 1100.00 93 94 65 249 NA NA40 15 NA NA NA 1105.71 NA NA

- - - - - - - -- - - - -

0 13:34 14 NA NA NA 1112.85 93 93 68 248 NA NA

10 13:44 10 NA NA NA 1118.40 94 96 66 249 NA NA20 13:53 NA NA NA 1123.20 94 96 67 249 NA NA30 14:04 NA NA NA 1127.00 96 98 65 251 NA NA40 14:14 NA NA NA 1131.18 NA NA

- - - - - - - -- - - - -

0 14:42 14 NA NA NA 1139.50 96 97 68 249 NA NA

10 10 NA NA NA 1144.70 97 99 66 250 NA NA20 9 NA NA NA 1152.00 99 100 65 248 NA NA30 9 NA NA NA 155.35 100 101 64 247 NA NA40 15:22 9 NA NA NA 1159.23

Average 40 #DIV/0! #DIV/0! #DIV/0! 57.40 95 96 66 249 #DIV/0! #DIV/0!

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

95.42
Company DTE Belle River

Source Designation Unit 2 BoilerTest Date 6/22/2010 Assumed Moisture (Bws) 10

Test Number Run #3 M-0031 Condensate Volume (Vlc) 0

Operator TW Silica Gel Weight Gain (Vlc) 0

Filter Number NA Nozzle Diameter (in.) NA

Barometric Pressure (Pb) 29.93 Leak Rate Initial 0.000@24"

Stack Static Pressure (Ps) -1.9 Leak Rate Final 0.01@14"

Stack Dimensions (in.) 306 Traverse points 1

Pitot Tube Number NA Pitot Corr. Factor (Cp) NA

Meter Number VOS Meter Corr. Factor (Y) 0.98

Meter Isokinetic Factor (Kiso) - Orsat Results (%)

Delta ∆H@ 0.93 CO2 10.8

 O2 9.02

Traverse Sampling Time Sampling Stack Temp.Velocity Pres Orifice Sample Volume Dry Gas Meter Temp. Last Impinger Probe Filter Box Filter Box Exit

Point (Minutes) Clock Time Train Vac. (F) ("H2O) Differential (cubic feet) Inlet Outlet Temperature Temperature Temperature Temperature

Number ø (24 hour) ("Hg) Ts ∆Ps ("H2O) ∆H Vm (F) Tm (F) Tm (F) (F) (F) (F)

0 16:00 8 NA NA NA 1161.40 98 99 68 250 NA NA

10 16:10 8 NA NA NA 1166.65 98 100 67 251 NA NA20 8 NA NA NA 1171.60 99 101 66 249 NA NA30 8 NA NA NA 1176.50 100 102 66 251 NA NA40 16:40 8 NA NA NA 1180.09 101 103 66 250 NA NA

- - - - - - - -- - - - -

0 17:08 10 NA NA NA 1183.17 100 99 68 248 NA NA

10 10 NA NA NA 1189.00 101 99 65 251 NA NA20 17:28 11 NA NA NA 1193.50 100 101 66 250 NA NA30 11 NA NA NA 1197.00 101 103 66 249 NA NA40 17:48 17 NA NA NA 1202.73 102 102 66 249 NA NA

- - - - - - - -- - - - -

0 18:14 8 NA NA NA 1209.50 102 102 68 251 NA NA

10 8 NA NA NA 1214.50 102 103 65 247 NA NA20 8 NA NA NA 1220.50 102 105 64 246 NA NA30 8 NA NA NA 1224.50 104 103 63 249 NA NA40 8 NA NA NA 1228.90 - - - - - -

Average 40 #DIV/0! #DIV/0! #DIV/0! 57.65 100.7 101.6 66.0 249.4 #DIV/0! #DIV/0!

∆H = Kiso * (Cp)2 * (1-wv/100)2 * (MWm/MWs) * (Ps/Pm) * (Tm/Ts) * ∆Ps * D4

101.14


























Appendix B 

Calibration Data 
ANALYZER CALIBRATION ERROR CHECK DATA

Test Date: 6/22/2010 Analyzer: Teledyne 300E

Client: DTE Belle River Power Plant Serial #: 288

Unit: Unit 2 Span: 22.40

Sample Location: Exhaust Recorder Range: -5 to 95% FS

Calibration Gas: O2 Concentration: 22.4, 10.0

Cylinder #: EB0013835 Units: %

Zero Gas: Nitrogen

Cylinder Analyzer Absolute Difference

Value Response Difference (% of Span)

ppm ppm ppm *

Zero Gas 0.00 0.07 0.07 0.31

Mid Gas 10.00 10.16 0.16 0.71

High Gas 22.40 22.45 0.05 0.22

ANALYZER CALIBRATION ERROR CHECK DATA

Test Date: 6/22/2010 Analyzer: Teledyne Model 300 E

Client: DTE Belle River Power Plant Serial #: 56872602

Unit: Unit 2 Span: 199.7

Sample Location: Exhaust Recorder Range: -5 to 95% FS

Calibration Gas: CO Concentration: 99.9, 199.7

Cylinder #: CC28908, CC56451 Units: ppm

Zero Gas: Nitrogen

Cylinder Analyzer Absolute Difference

Value Response Difference (% of Span)

ppm ppm ppm *

Zero Gas 0.00 0.92 0.92 0.46

Mid Gas 99.90 99.85 0.05 0.03

High Gas 199.70 198.69 1.01 0.51

* Eq. 7E-1

(Cdir - Cv)

ACE = CS x 100

Where:

ACE = Analyzer calibratoin error, % of span

Cdir = Measured concentration of a cal gas when introduced in direct cal mode

Cv = Manufacturer cirtified concentration of cal gas

CS = Calibration Span
ANALYZER CALIBRATION ERROR CHECK DATA

Test Date: 6/22/2010 Analyzer: Teledyne Infrared

Client: DTE Belle River Power Plant Serial #:

Unit: Unit 2 Span: 18.10

Sample Location: Exhaust Recorder Range: -5 to 95% FS

Calibration Gas: CO2 Concentration: 10.08, 18.1

Cylinder #: CC28908 Units: %

Zero Gas: Nitrogen

Cylinder Analyzer Absolute Difference

Value Response Difference (% of Span)

ppm ppm ppm *

Zero Gas 0.00 0.00 0.00 0.00

Mid Gas 10.08 10.22 0.14 0.77

High Gas 18.10 18.01 0.09 0.50

ANALYZER CALIBRATION ERROR CHECK DATA

Test Date: 6/22/2010 Analyzer: Western Research Model 92

Client: DTE Belle River Power Plant Serial #: AB-921W-9202-1

Unit: Unit 2 Span: 499.90

Sample Location: Exhaust Recorder Range: -5 to 95% FS

Calibration Gas: SO2 Concentration: 89.43, 50.7

Cylinder #: XCO26999B Units: PPM

Zero Gas: Nitrogen

Cylinder Analyzer Absolute Difference

Value Response Difference (% of Span)

ppm ppm ppm *

Zero Gas 0.00 1.52 1.52 0.30

Mid Gas 249.70 250.21 0.51 0.10

High Gas 499.90 502.19 2.29 0.46

* Eq. 7E-1

(Cdir - Cv)

ACE = CS x 100

Where:

ACE = Analyzer calibratoin error, % of span

Cdir = Measured concentration of a cal gas when introduced in direct cal mode

Cv = Manufacturer cirtified concentration of cal gas

CS = Calibration Span
CEMS DRIFT CALCULATION SPREAD SHEET

Client: DTE Belle River Power Plant

Source: Unit 2

Date: 6/22/2010

Span: 22.40 199.70 18.10 499.90 49.99 22.4 199.7 18.1 499.9

O2 CO CO2 SO2 VOC O2 CO CO2 SO2

Calibration Gas Value = 10.00 99.90 10.08 249.70 9.91 10 99.9 10.08 249.7

Run #1 Initial Zero Bias Value = 0.06 1.19 0.06 2.25 0.01 analyzer 0.07 0.92 0.00 1.52

Run #1 Initial System Bias Value = 9.81 99.76 10.22 247.09 10.06 system 0.02 0.97 0.00 2.88

Run #1 Average = 8.69 4.87 10.95 229.25 1.20 RUN 1

Run #1 Final Zero Bias Value = 0.02 0.97 0 2.88 -0.04 analyzer 10.16 99.85 10.22 250.21

Run #1 Final System Bias Value = 9.76 97.47 10.25 256.75 9.81 system 9.76 97.47 10.25 256.75

Run #1 Total Drift Corrected = 8.88 3.88 10.79 227.00 1.21 F Factor = 8710

zero calibration drift = 3% -0.18 -0.11 -0.33 0.13 -0.10 zero bias -0.22 0.03 0.00 0.27 5% allowed

calibration drift = -0.22 -1.15 0.17 1.93 -0.50 span bias -1.79 -1.19 0.17 1.31

Run #2 Initial Zero Bias Value = 0.02 0.97 0.00 2.88 -0.04 analyzer 0.07 0.92 0 1.52

Run #2 Initial System Bias Value = 9.76 97.47 10.25 256.75 9.81 system 0.05 1.14 0.00 3.05

Run #2 Average = 8.39 29.23 10.85 191.67 0.94 RUN 2

Run #2 Final Zero Bias Value = 0.05 1.14 0 3.05 -0.04 analyzer 10.16 99.85 10.22 250.21

Run #2 Final System Bias Value = 10.07 98.56 9.96 250.17 9.85 system 10.07 98.56 9.96 250.17

Run #2 Total Drift Corrected = 8.46 29.03 10.82 188.11 0.98 F Factor = 8710

zero calibration drift = 0.13 0.09 0.00 0.03 0.00 zero bias -0.09 0.11 0.00 0.31

calibration drift = 1.38 0.55 -1.60 -1.32 0.08 span bias -0.40 -0.65 -1.44 -0.01

Run #3 Initial Zero Bias Value = 0.05 1.14 0 3.05 -0.04 analyzer 0.07 0.92 0 1.52

Run #3 Initial System Bias Value = 10.07 98.56 9.96 250.17 9.85 system 0.23 1.06 0.01 4.19

Run #3 Average = 9.14 13.53 10.75 183.71 0.94 RUN 3

Run #3 Final Zero Bias Value = 0.23 1.06 0.01 4.19 0.02 analyzer 10.16 99.85 10.22 250.21

Run #3 Final System Bias Value = 10.17 97.33 10.1 252.29 9.55 system 10.17 97.33 10.1 252.29

Run #3 Total Drift Corrected = 9.02 12.82 10.80 181.61 0.97 F Factor = 8710

zero calibration drift = 0.80 -0.04 0.06 0.23 0.12 zero bias 0.71 0.07 0.06 0.53

calibration drift = 0.45 -0.62 0.77 0.42 -0.60 span bias 0.04 -1.26 -0.66 0.42

Drift Correction calculation

Where:

Cgas =effluent gas concentration, dry basis, ppm

C = avg. gas concentration indicated by analyzer, dry basis, ppm

Co = avg. of initial and final system calibration bias check for the zero gas

Cm = avg. of initial and final system calibration bias check for the upscale calibration gas

Cma = actual concentration of the upscale calibration gas, ppm

m o

ma

gas o C C

C C C C − = ( − )
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record data and information in the GREEN cells, YELLOW cells are calculated.

INITIAL FINAL AVG (Pbar)

DATE: 4/13/2010 METER SERIAL #: C-5000 BAROMETRIC PRESSURE (in Hg): 30.44 30.52 30.48 

METER PART #: MB3 CRITICAL ORIFICE SET SERIAL #: 1447 

K' TESTED TEMPERATURES °F ELAPSED

FACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGM ΔH (1) 

ORIFICE # RUN # (AVG) (in Hg) INITIAL FINAL NET (Vm) INITIAL FINAL INITIAL FINAL AVG θ (in H2O) Vm (STD) Vcr 

1 0.8778 16 286.30 293.140 6.840 60 64 64 65 64 64.25 6.00 4.5 7.0954 7.2 0.8778 16 293.140 299.930 6.790 60 64 67 64 65 65 6.00 4.5 7.0335 7.3 0.8778 16 299.930 306.706 6.776 60 67 69 65 65 66.5 6.00 4.5 6.9990 7.1 0.5057 16 306.706 312.557 5.851 60 67 70 66 67 67.5 9.00 1.4 5.9874 6.2 0.5057 16 312.557 318.402 5.845 60 70 71 67 68 69 9.00 1.4 5.9643 6.3 0.5057 16 318.402 324.235 5.833 60 71 73 68 69 70.25 9.00 1.4 5.9380 6.1 0.3367 16 324.235 329.556 5.321 60 69 71 69 69 69.5 12.00 0.63 5.4145 5.2 0.3367 16 329.556 334.864 5.308 60 71 72 69 70 70.5 12.00 0.63 5.3910 5.3 0.3367 16 334.864 340.183 5.319 60 72 73 70 70 71.25 12.00 0.63 5.3946 5.

AVERAGE DRY GAS METER CALIBRATION FACT

AVERAG

(1) = Net volume of gas sample passed through DGM, corrected to standard conditions

K1 = 17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)

Tm = Absolute DGM avg. temperature (oR - English, oK - Metric) ΔH@ = 0.

Vcr

(2) = Volume of gas sample passed through the critical orifice, corrected to standard conditions

Tamb = Absolute ambient temperature (oR - English, oK - Metric)

K' = Average K' factor from Critical Orifice Calibration

(3) = DGM calibration factor

321812

ENVIRONMENTAL 

USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical 

orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.

(

Tm

Pbar

H Vm std

K Vm ( /13.6) ( ) 1

+ Δ = ∗ ∗

Tamb

Pbar Vcr std

K ∗ Θ ( ) = '∗

( )

( )

std

std

Vm

Vcr

Y =
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record data and information in the GREEN cells, YELLOW cells are calculated.

INITIAL FINAL AVG (Pbar)

DATE: 7/6/2010 METER SERIAL #: C-5000 BAROMETRIC PRESSURE (in Hg): 30.07 30.09 30.08 

METER PART #: MB3 CRITICAL ORIFICE SET SERIAL #: 1447 

K' TESTED TEMPERATURES °F ELAPSED

FACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGM ΔH (1) 

ORIFICE # RUN # (AVG) (in Hg) INITIAL FINAL NET (Vm) INITIAL FINAL INITIAL FINAL AVG θ (in H2O) Vm (STD) Vcr 

1 0.8778 16 721.888 728.80 6.912 81 88 90 85 86 87.25 6.00 4.45 6.7786 6.2 0.8778 16 728.80 735.708 6.908 81 90 92 86 86 88.5 6.00 4.45 6.7592 6.3 0.8778 16 735.708 742.642 6.934 81 92 92 86 87 89.25 6.00 4.45 6.7754 6.1 0.5057 16 704.027 709.974 5.947 81 83 85 83 84 83.75 9.00 1.4 5.8265 5.2 0.5057 16 709.974 715.935 5.961 81 85 86 84 85 85 9.00 1.4 5.8268 5.3 0.5057 16 715.935 721.888 5.953 81 86 88 85 85 86 9.00 1.4 5.8083 5.1 0.3367 16 742.642 748.048 5.406 81 92 91 87 88 89.5 12.00 0.62 5.2310 5.2 0.3367 16 748.048 753.450 5.402 81 91 91 88 88 89.5 12.00 0.62 5.2272 5.3 0.3367 16 753.450 758.850 5.40 81 91 91 88 89 89.75 12.00 0.62 5.2229 5.

AVERAGE DRY GAS METER CALIBRATION FACT

AVERAG

(1) = Net volume of gas sample passed through DGM, corrected to standard conditions

K1 = 17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)

Tm = Absolute DGM avg. temperature (oR - English, oK - Metric) ΔH@ = 0.

Vcr

(2) = Volume of gas sample passed through the critical orifice, corrected to standard conditions

Tamb = Absolute ambient temperature (oR - English, oK - Metric)

K' = Average K' factor from Critical Orifice Calibration

(3) = DGM calibration factor

321812

ENVIRONMENTAL 

USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical 

orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.

(

Tm

Pbar

H Vm std

K Vm ( /13.6) ( ) 1

+ Δ = ∗ ∗

Tamb

Pbar Vcr std

K ∗ Θ ( ) = '∗

( )

( )

std

std

Vm

Vcr

Y =
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICE

S

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record data and information in the GREEN cells, YELLOW cells are calculated.

INITIAL FINAL AVG (Pbar)

DATE: 6/18/2010 METER SERIAL #: CA 4 BAROMETRIC PRESSURE (in Hg): 30.08 30.02 30.05 

METER PART #: MB4 CRITICAL ORIFICE SET SERIAL #: 1447 

K' TESTED TEMPERATURES °F ELAPSED

FACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGM ΔH (1) 

ORIFICE # RUN # (AVG) (in Hg) INITIAL FINAL NET (Vm) INITIAL FINAL INITIAL FINAL AVG θ (in H2O) Vm (STD) Vc

1 0.6665 15 816.80 822.943 6.143 77 76 78 76 77 76.75 7.00 2.25 6.1036 62 0.6665 15 822.943 829.088 6.145 77 78 79 77 78 78 7.00 2.25 6.0914 63 0.6665 15 829.088 835.250 6.162 77 79 81 78 78 79 7.00 2.25 6.0969 61 0.5057 16 835.250 841.205 5.955 77 81 81 78 79 79.75 9.00 1.25 5.8696 52 0.5057 16 841.205 847.155 5.950 77 81 82 79 79 80.25 9.00 1.25 5.8592 53 0.5057 16 847.155 853.10 5.945 77 82 83 79 80 81 9.00 1.25 5.8462 51 0.3367 16 853.10 858.495 5.395 77 83 83 80 80 81.5 12.00 0.61 5.2922 52 0.3367 16 858.495 863.910 5.415 77 83 83 80 80 81.5 12.00 0.61 5.3118 53 0.3367 16 863.910 869.315 5.405 77 83 83 80 81 81.75 12.00 0.61 5.2995 5

AVERAGE DRY GAS METER CALIBRATION FAC

AVERAG

(1) = Net volume of gas sample passed through DGM, corrected to standard conditions

K1 = 17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)

Tm = Absolute DGM avg. temperature (oR - English, oK - Metric) ΔH@ = 0

Vc

(2) = Volume of gas sample passed through the critical orifice, corrected to standard conditions

Tamb = Absolute ambient temperature (oR - English, oK - Metric)

K' = Average K' factor from Critical Orifice Calibration

(3) = DGM calibration factor

241812

ENVIRONMENTAL 

USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical 

orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.

(

Tm

Pbar

H Vm std

K Vm ( /13.6) ( ) 1

+ Δ = ∗ ∗

Tamb

Pbar Vcr std

K ∗ Θ ( ) = '∗

( )

( )

std

std

Vm

Vcr

Y =
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICE

S

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record data and information in the GREEN cells, YELLOW cells are calculated.

INITIAL FINAL AVG (Pbar)

DATE: 7/6/2010 METER SERIAL #: CA 4 BAROMETRIC PRESSURE (in Hg): 30.07 30.09 30.08 

METER PART #: MB4 CRITICAL ORIFICE SET SERIAL #: 1447 

K' TESTED TEMPERATURES °F ELAPSED

FACTOR VACUUM DGM READINGS (FT3) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGM ΔH (1) 

ORIFICE # RUN # (AVG) (in Hg) INITIAL FINAL NET (Vm) INITIAL FINAL INITIAL FINAL AVG θ (in H2O) Vm (STD) Vc

1 0.6665 15 135.080 141.267 6.187 81 86 88 84 85 85.75 7.00 2.25 6.0519 62 0.6665 15 141.267 147.460 6.193 81 88 89 85 85 86.75 7.00 2.25 6.0467 63 0.6665 15 147.460 153.675 6.215 81 89 89 85 86 87.25 7.00 2.25 6.0626 61 0.5057 16 117.182 123.132 5.950 81 83 84 82 83 83 9.00 1.25 5.8353 52 0.5057 16 123.132 129.10 5.968 81 84 85 83 84 84 9.00 1.25 5.8422 53 0.5057 16 129.10 135.080 5.980 81 85 86 84 84 84.75 9.00 1.25 5.8459 51 0.3367 16 153.675 159.088 5.413 81 86 87 85 86 86 12.00 0.61 5.2713 52 0.3367 16 159.088 164.535 5.447 81 87 88 86 86 86.75 12.00 0.61 5.2971 53 0.3367 16 164.535 169.960 5.425 81 88 88 86 86 87 12.00 0.61 5.2733 5

AVERAGE DRY GAS METER CALIBRATION FAC

AVERAG

(1) = Net volume of gas sample passed through DGM, corrected to standard conditions

K1 = 17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)

Tm = Absolute DGM avg. temperature (oR - English, oK - Metric) ΔH@ = 0

Vc

(2) = Volume of gas sample passed through the critical orifice, corrected to standard conditions

Tamb = Absolute ambient temperature (oR - English, oK - Metric)

K' = Average K' factor from Critical Orifice Calibration

(3) = DGM calibration factor

241812

ENVIRONMENTAL 

USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical 

orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.

(

Tm

Pbar

H Vm std

K Vm ( /13.6) ( ) 1

+ Δ = ∗ ∗

Tamb

Pbar Vcr std

K ∗ Θ ( ) = '∗

( )

( )

std

std

Vm

Vcr

Y =
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICE

S

1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.2) Record barometric pressure before and after calibration procedure.3) Run at tested vacuum (from Orifice Calibration Report), for a period of time

necessary to achieve a minimum total volume of 5 cubic feet.

4) Record data and information in the GREEN cells, YELLOW cells are calculated.

INITIAL FINAL AVG (Pbar)

DATE: 6/15/2010 METER SERIAL #: VOS BAROMETRIC PRESSURE (in Hg): 30.05 30.05 30.05 

METER PART #: CRITICAL ORIFICE SET SERIAL #: 2662 

K' TESTED TEMPERATURES °F ELAPSED

FACTOR VACUUM DGM READINGS (L) AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN) DGM ΔH (1) 

ORIFICE # RUN # (AVG) (in Hg) INITIAL FINAL NET (Vm) INITIAL FINAL INITIAL FINAL AVG θ (in H2O) Vm (STD) Vc

1 0.4551 15 794.250 800.310 6.060 79 78 79 78 79 78.5 10.00 1 5.9833 52 0.4551 15 800.310 806.540 6.230 79 79 80 79 81 79.75 10.00 1 6.1369 53 0.4551 15 806.540 812.730 6.190 79 80 82 81 83 81.5 10.00 1 6.0778 51 0.8249 15 812.730 823.730 11.000 80 82 83 83 84 83 10.00 1.5 10.7839 12 0.8249 15 823.730 834.780 11.050 80 83 84 84 85 84 10.00 1.5 10.8130 13 0.8249 15 834.780 845.860 11.080 78 84 85 85 86 85 10.00 1.6 10.8251 11 1.2954 15 845.860 863.30 17.440 79 86 86 86 87 86.25 10.00 2.4 17.0329 12 1.2954 15 863.30 880.850 17.550 79 86 86 87 87 86.5 10.00 2.4 17.1324 13 1.2954 15 880.850 898.420 17.570 79 86 86 87 87 86.5 10.00 2.4 17.1520 1

AVERAGE DRY GAS METER CALIBRATION FAC

AVERAG

(1) = Net volume of gas sample passed through DGM, corrected to standard conditions

K1 = 17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)

Tm = Absolute DGM avg. temperature (oR - English, oK - Metric) ΔH@ = 0

Vc

(2) = Volume of gas sample passed through the critical orifice, corrected to standard conditions

Tamb = Absolute ambient temperature (oR - English, oK - Metric)

K' = Average K' factor from Critical Orifice Calibration

(3) = DGM calibration factor

123

ENVIRONMENTAL 

USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical 

orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.

(

Tm

Pbar

H Vm std

K Vm ( /13.6) ( ) 1

+ Δ = ∗ ∗

Tamb

Pbar Vcr std

K ∗ Θ ( ) = '∗

( )

( )

std

std

Vm

Vcr

Y =


















Appendix C 

RAW CEM Data 
Appendix D 

Laboratory Analytical Results 
BT Environmental 

Consulting, Inc. 

2615 Wolcott St. 

Ferndale, MI 48220

DTE - Belle River 

St. Clair, MI 

Project # 10-3991.00 

Analytical Report 

(0610-115)

EPA Method 18 Bags

Methane

Enthalpy Analytical, Inc. 

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 

2202 Ellis Road Durham, NC 27703 - 5518 
I certify that to the best of my knowledge all analytical data presented in this report: 

Have been checked for completeness 

Are accurate, error-free, and legible 

Have been conducted in accordance with approved protocol, and that all deviations and analytical 

problems are summarized in the appropriate narrative(s) 

This analytical report was prepared in Portable Document Format (.PDF) and contains 129 pages. 
Summary of Results
Compound Sample ID / Adjusted Concentration (ppm)

Run 1 Run 2 Run 3

Methane 0.719 J 2.03 E 1.10 J

Company

Analyst

Parameters

# Samples

BT Environmental

KAM / CJT

EPA Method 18 Bags

3 Runs, 1 S&R

Client #

Job #

PO #

Report Date

10-3991.00

0610-115

Verbal

6/30/2010

0610-115 res 7/8/2010
Results

v 2.12 Validated by MSS 7/21/09

% Recovery = (T - U) / S x 100

T = after spike concentration U = before spike concentration S = theoretical spike concentration

Methane

MW 16.04 MW 0.000 MW

What was the conc of the Inj 1 Inj 2 Inj 3 Inj 3Inj 1 Inj 2 Inj 3 Inj 1 I

bag before spiking? (ppm) (ppm) (ppm) (pp (ppm) (ppm) (ppm) (ppm) (

U' (before spiking) 0.761 0.721 0.754 0.00 0.00 0.00 0.00

Avg ppm 0.745 Avg ppm 0.00 Avg ppm

What was added to the bag?

Conc. ppm Pbar (inHg) T (F) T (FConc. ppm Pbar (inHg) T (F) Conc. ppm T

Gas Spike #1 99.8 29.71 69.8 0 29.71 69.8 0

Volume Added (mL) 150 Total ug 9.9 150 Total ug 0.0 150

Total Vol (mL) vaporized 0.0 0.0 0.0

Total Vol (mL) added as gas 150 150 150

Other volume (mL) Added 0 0 0

Volume (mL) used in analysis 0 0 0

What volume was in the Sampled 6/22/10 8:27 AM Hours

bag before spiking? Wedge Volume 2.167 (L) Delta 27:32:50

Analyzed 6/23/10 11:59 AM

Spiked 6/24/10 11:30 AM Hours

Delta 28:17:00

Spike Analyzed 6/25/10 3:47 PM

Total Vol. After Spiking 2,317 (mL) Spike hold equal to or greater than original hold YES

Ending Volume in Bag (mL) 2,317

Original volume in the bag (mL) 2,167 2,167

Total volume added (mL) 150 150

Dilution Factor caused by addition 1.07 1.07

Dilution Adjusted Base Conc (ppm) "U" 0.70 0.00

Theoretical Spike Conc (ppm) "S" 6.39 #DIV/0!

What was the conc of the Inj 1 Inj 2 Inj 3 Inj 3Inj 1 Inj 2 Inj 3 Inj 1 I

bag after spiking? (ppm) (ppm) (ppm) (pp (ppm) (ppm) (ppm) (ppm) (

7.41 7.28 7.30 0.00 0.00 0.00 0.00

Final Concentration (ppm) "T" Avg ppm 7.33 Avg ppm 0.00 Avg ppm

RECOVERY % 104 % % #DIV/0! % %

Company

Analyst

Parameters

Unspiked Sample ID

BT Environmental

KAM / CJT

Bag Spike & Recovery

Run 1

Client #

Job #

PO #

Report Date

10-3991.00

0610-115

Verbal

6/30/2010

7/8/2010 9:57 AM 0610-115 res % Recovery
Narrative Summary
Enthalpy Analytical Narrative Summary 

Company BT Environmental 

Consulting

Client # 10-3991.00

Analyst KAM Job # 0610-115

Parameters EPA Method 18 Bags PO # Verbal

# Samples 3 Runs, 1 S&R Report Date June 30, 2010 

Custody Heather Tarjeft received the samples on 6/23/10 after being relinquished 

by BT Environmental Consulting, Inc. The samples were received at 

ambient temperature. The sample, Run 2 had a very low sample 

volume upon receipt. Prior to, during, and after analysis, the samples 

were kept under lock with access only to authorized personnel by 

Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for methane using the analytical procedures 

in EPA Method 18, Measurement of Gaseous Organic Compound 

Emissions by Gas Chromatography (40 CFR Part 60, Appendix A). 

The standards and samples were analyzed following the procedures 

specified in section 8.2.1, Integrated Bag Sampling and Analysis. 

All samples and standards were introduced directly to the column using 

an automated 6-port Valco gas sampling valve equipped with a stainless 

steel loop. Methane was referenced to certified gas phase standards. 

The Agilent Technologies Model 6890, Gas Chromatograph ("Gummo" 

S/N US00028451) was equipped with a Flame Ionization Detector and a 

Restek Rtx-624, 30 m x 0.32 mm column (S/N 926828). 

Calibration The calibration curves are located in the back of this report and 

referenced in the Analysis Method column on the Detailed Results page. 

For each calibration curve used, the first page of the curve contains all 

method specific parameters (i.e., curve type, origin, weight, etc.) used to 

quantify the samples. The calibration curve section also includes a table 

with the Retention Time (RetTime), Level (Lvl), Amount 

(corresponding units), Area, Response Factor (Amt/Area) and the 

analyte Name. The calibration table is used to identify (by retention 

time) and quantify each target compound. 

Chromatographic

Conditions

The acquisition method gc114p103.m is included in the Calibration 

Curve Chromatograms section of this report. 
Enthalpy Analytical Narrative Summary 

(continued)

QC Notes As required by section 8.4.2, Recovery Study for Bag Sampling, a 

recovery study is performed on a bag sample. The bag sample Run 1

was spiked at 11:30 AM on 6/24/10. The recovery efficiency value met 

the method-required limit of between 70 and 130%. The recovery 

efficiency value is used to adjust the results following equation 18-7 

from section 12.8. 

A Laboratory Control Sample (LCS) bag was analyzed with the 

samples. The recovery value was 89.2%. 

All sample preparation and analytical holding times specified in the 

method were met. 

Reporting Notes The results presented in this report are representative of the samples as 

provided to the laboratory. 

These analytical results are reported on a wet basis. The user of this 

report should determine the % moisture in the sample and correct the 

reported value to ppmvd as appropriate. 

There was only one injection made for Run 2 as there was not enough 

volume for any more injections. 

Enthalpy Analytical, Inc. is accredited to perform this method for 

compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 
General Reporting Notes 

The following are general reporting notes that are applicable to all Enthalpy Analytical, Inc. data 

reports, unless specifically noted otherwise.

The acronym MDL represents the Minimum Detection Limit. Below this value the laboratory cannot 

determine the presence of the analyte of interest reliably. 

The acronym LOQ represents the Limit of Quantification. Below this value the laboratory cannot 

quantitate the analyte of interest within the criteria of the method. 

The acronym ND following a value indicates a non-detect or analytical result below the MDL. 

The letter J following a value indicates an analytical result between the MDL and the LOQ. A J flag 

indicates that the laboratory can positively identify the analyte of interest as present, but the value 

should be considered an estimate. 

The letter E following a value indicates an analytical result exceeding 100% of the highest calibration 

point. The associated value should be considered as an estimate. 

The acronym DF represents Dilution Factor. This number represents dilution of the sample during the 

preparation and/or analysis process. The analytical result taken from a laboratory instrument is 

multiplied by the DF to determine the final undiluted sample results. 

The addition of MS to the Sample ID represents a Matrix Spike. An aliquot of an actual sample is 

spiked with a known amount of analyte so that a percent recovery value can be determined. This shows 

what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample 

matrix interferes with the analysis of the analyte(s). 

The addition of MSD to the Sample ID represents a Matrix Spike Duplicate. Prepared in the same 

manner as an MS, the use of duplicate matrix spikes allows further confirmation of laboratory quality 

by showing the consistency of results gained by performing the same steps multiple times. 

The addition of LD to the Sample ID represents a Laboratory Duplicate. The analyst prepares an 

additional aliquot of sample for testing and the results of the duplicate analysis are compared to the 

initial result. The result should have a difference value of within 10% of the initial result (if the results 

of the original analysis are greater than the LOQ). 

The addition of AD to the Sample ID represents an Alternate Dilution. The analyst prepares an 

additional aliquot at a different dilution factor (usually double the initial factor). This analysis helps 

confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of 

interest, as they would have a different response/absorbance than the analyte of interest. 

The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample 

matrix, prepared and analyzed by the laboratory using the same reagents, spiking standards and 

procedures used for the client samples. The LCS is used to assess the control of the laboratory’s 

analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. 

The extras (randomly chosen) are labeled with the associated project number and kept in-house at the 

appropriate temperature conditions. When the project samples are received for analysis, the LCSs are 

analyzed to confirm that the analyte could be recovered from the media, separate from the samples 

which were used on the project and which may have been affected by source matrix, sample collection 

and/or sample transport. 
General Reporting Notes 

(continued)

Significant Figures: Where the reported value is much greater than unity (1.00) in the units expressed, 

the number is rounded to a whole number of units, rather than to 3 significant figures. For example, a 

value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits displayed, but no 

confidence should be placed on more than two significant digits. 

Manual Integration: The data systems used for processing will flag manually integrated peaks with 

an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified 

by the following two letter designations. The peak was not integrated by the software “NI”, the peak 

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software 

“WP”. These codes will accompany the analyst’s manual integration stamp placed next to the 

compound name. 
Sample Custody

Your Project #: 10-3991.00 

Site: DTE-BELLE RIVER

Your C.O.C. #: F05, F01, F02, F03

Attention: James K. Sharp

BT Environmental Consulting

2615 Wolcott St.

Ferndale, MI

USA 48220

Report Date: 2010/07/08

CERTIFICATE OF ANALYSIS

MAXXAM JOB #: B082562

Received: 2010/06/24, 12:00

Sample Matrix: AIR

# Samples Received: 4

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

Aldehydes + Ketones in Air 4 2010/06/29 2010/07/02 BRL SOP-00229 EPA 8315mod (M0011)

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

Encryption Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

LINA BARRETO, Project Manager

Email: Lina.Barreto@maxxamanalytics.com

Phone# (905) 817-5700

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section

5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 1

Page 1 of 5
BT Environmental Consulting

Maxxam Job #: B082562 Client Project #: 10-3991.00

Report Date: 2010/07/08 Project name: DTE-BELLE RIVER

CARBONYL COMPOUNDS BY HPLC (AIR)

Maxxam ID G H 3 1 6 8 G H 3 1 6 9 G H 3 1 7 0 G H 3 1 7 1 G H 3 1 7 1

Sampling Date 2010/06/22 2010/06/22 2010/06/22 2010/06/22 2010/06/22

COC Number F05 F01 F02 F03 F03

 U n i t s BLANK-M0011 RDL RUN RDL RUN RDL RUN RUN RDL QC Batch

1- M0011 2- M0011 3- M0011 3- M0011

Lab-Dup

Formaldehyde (Methanal) ug/Tot. 860 20 250 2 300 4 190 190 2 2192533

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 2 of 5
BT Environmental Consulting

Maxxam Job #: B082562 Client Project #: 10-3991.00

Report Date: 2010/07/08 Project name: DTE-BELLE RIVER

Test Summary

Maxxam ID GH3168 Collected 2010/06/22

Sample ID BLANK-M0011 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

Aldehydes + Ketones in Air LC/UV 2192533 2010/06/29 2010/07/02 SPS

Maxxam ID GH3169 Collected 2010/06/22

Sample ID RUN 1- M0011 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

Aldehydes + Ketones in Air LC/UV 2192533 2010/06/29 2010/07/02 SPS

Maxxam ID GH3170 Collected 2010/06/22

Sample ID RUN 2- M0011 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

Aldehydes + Ketones in Air LC/UV 2192533 2010/06/29 2010/07/02 SPS

Maxxam ID GH3171 Collected 2010/06/22

Sample ID RUN 3- M0011 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

Aldehydes + Ketones in Air LC/UV 2192533 2010/06/29 2010/07/02 SPS

Maxxam ID GH3171 D u p Collected 2010/06/22

Sample ID RUN 3- M0011 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

Aldehydes + Ketones in Air LC/UV 2192533 2010/07/07 2010/07/02 SPS

Page 3 of 5
BT Environmental Consulting

Maxxam Job #: B082562 Client Project #: 10-3991.00

Report Date: 2010/07/08 Project name: DTE-BELLE RIVER

GENERAL COMMENTS

Sample GH3168-01: The sample was diluted 10x. MDL adjusted accordingly.

Sample GH3170-01: The sample was diluted 2x. MDL adjusted accordingly.

Samples have been corrected for desorption efficiencies if average percent recoveries are less than 80% (does not apply to gravimetric and

inorganic analysis).

Results relate only to the items tested.

Page 4 of 5
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report

Maxxam Job Number: GB082562

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2192533 SPS Spiked Blank Formaldehyde (Methanal) 2010/07/02 111 % N/A

Spiked Blank DUP Formaldehyde (Methanal) 2010/07/02 117 % N/A

RPD Formaldehyde (Methanal) 2010/07/02 5.2 % 30

Method Blank Formaldehyde (Methanal) 2010/07/02 2.3, RDL=0.2 ug/Tot.

RPD -

Sample/Sample

Dup Formaldehyde (Methanal) 2010/07/02 0.2 % 30

Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.

Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery.

Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.

Page 5 of 5
Your Project #: 10-3991.00 

Site: DTE-BELLE RIVER

Your C.O.C. #: 001/003, N/A, 006/008, 007/009,

011/013, 012/014, 015

Attention: James K. Sharp

BT Environmental Consulting

2615 Wolcott St.

Ferndale, MI

USA 48220

Report Date: 2010/08/13

CERTIFICATE OF ANALYSIS

MAXXAM JOB #: B082851

Received: 2010/06/24, 12:00

Sample Matrix: Stack Sampling Train

# Samples Received: 12

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

SVOCs in MM5 SamplingTrain (EPA0010) (1 ) 9 2010/06/30 2010/08/10 BRL SOP-00200 EPA 8270D mod(M0010)

SVOCs in MM5 SamplingTrain (EPA0010) (1 ) 3 2010/07/05 2010/08/11 BRL SOP-00200 EPA 8270D mod(M0010)

PAH's in MM5 SamplingTrains (CARB429mod) (1 ) 9 2010/06/30 2010/08/10 BRL SOP-00201 CARB429(ARBM1,M2)mod

PAH's in MM5 SamplingTrains (CARB429mod) (1 ) 3 2010/07/05 2010/08/11 BRL SOP-00201 CARB429(ARBM1,M2)mod

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

(1) This test was performed in Maxxam Mississauga under Maxxam Burlington SCC Accreditation

Encryption Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

LINA BARRETO, Project Manager

Email: Lina.Barreto@maxxamanalytics.com

Phone# (905) 817-5700

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section

5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 1

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 1 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 3 G H 4 6 5 6

Sampling Date 2010/06/22 2010/06/22

COC Number 001/003 006/008

 U n i t s BLK-DTE-M0010-FILT RDL QC Batch FB-DTE-M0010 RDL QC Batch

1,2,4-Trichlorobenzene ug ND 6 2194806 ND 6 2194806

1,2-Dichlorobenzene ug ND 6 2194806 ND 6 2194806

1,3-Dichlorobenzene ug ND 6 2194806 ND 6 2194806

1,4-Dichlorobenzene ug ND 6 2194806 ND 6 2194806

1-Chloronaphthalene ug ND 6 2194806 ND 6 2194806

1-Methylnaphthalene ug ND 0.30 2194814 ND 0.30 2194814

1-Methylphenanthrene ug ND 0.30 2194814 ND 0.30 2194814

2,4,5-Trichlorophenol ug ND 6 2194806 ND 6 2194806

2,4,6-Trichlorophenol ug ND 5 2194806 ND 5 2194806

2,4-Dichlorophenol ug ND 4 2194806 ND 4 2194806

2,4-Dimethylphenol ug ND 6 2194806 ND 6 2194806

2,4-Dinitrophenol ug ND 10 2194806 ND 10 2194806

2,4-Dinitrotoluene ug ND 2 2194806 ND 2 2194806

2,6-Dinitrotoluene ug ND 3 2194806 ND 3 2194806

2-Chloronaphthalene ug ND 3 2194806 ND 0.30 2194814

2-Chlorophenol ug ND 8 2194806 ND 8 2194806

2-Methylanthracene ug ND 0.30 2194814 ND 0.30 2194814

2-Methylnaphthalene ug ND 5 2194806 ND 0.15 2194814

2-Methylphenol ug ND 9 2194806 ND 9 2194806

2-Nitroaniline ug ND 20 2194806 ND 20 2194806

2-Nitrophenol ug ND 5 2194806 ND 5 2194806

3 & 4-methylphenol ug ND 10 2194806 ND 10 2194806

3,3'-Dichlorobenzidine ug ND 8 2194806 ND 8 2194806

3-Methylcholanthrene ug ND 0.60 2194814 ND 0.60 2194814

3-Nitroaniline ug ND 20 2194806 ND 20 2194806

4,6-Dinitro-2-methylphenol ug ND 10 2194806 ND 10 2194806

4-Bromophenyl phenyl ether ug ND 2 2194806 ND 2 2194806

4-Chloro-3-Methylphenol ug ND 5 2194806 ND 5 2194806

4-Chloroaniline ug ND 20 2194806 ND 20 2194806

4-Chlorophenyl phenyl ether ug ND 3 2194806 ND 3 2194806

4-Nitroaniline ug ND 20 2194806 ND 20 2194806

4-Nitrophenol ug ND 10 2194806 ND 10 2194806

7,12-Dimethylbenzo(a)anthracene ug ND 0.60 2194814 ND 0.60 2194814

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 2 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 3 G H 4 6 5 6

Sampling Date 2010/06/22 2010/06/22

COC Number 001/003 006/008

 U n i t s BLK-DTE-M0010-FILT RDL QC Batch FB-DTE-M0010 RDL QC Batch

9,10-Dimethylanthracene ug ND 0.60 2194814 ND 0.60 2194814

Acenaphthene ug ND 2 2194806 ND 2 2194806

Acenaphthylene ug ND 0.15 2194814 ND 0.15 2194814

Aniline ug ND 20 2194806 ND 20 2194806

Anthracene ug ND 1 2194806 ND 1 2194806

Benzidine ug ND 60 2194806 ND 60 2194806

Benzo(a)anthracene ug ND 1 2194806 ND 1 2194806

Benzo(a)fluorene ug ND 0.60 2194814 ND 0.60 2194814

Benzo(a)pyrene ug ND 2 2194806 ND 0.15 2194814

Benzo(b)fluoranthene ug ND 0.15 2194814 ND 1 2194806

Benzo(b)fluorene ug ND 0.30 2194814 ND 0.30 2194814

Benzo(e)pyrene ug ND 0.30 2194814 ND 0.30 2194814

Benzo(g,h,i)perylene ug ND 1 2194806 ND 1 2194806

Benzo(k)fluoranthene ug ND 0.15 2194814 ND 2 2194806

Benzoic Acid ug ND 10 2194806 ND 10 2194806

Benzyl Alcohol ug ND 6 2194806 ND 6 2194806

Benzyl butyl phthalate ug ND 2 2194806 ND 2 2194806

Biphenyl ug ND 6 2194806 ND 6 2194806

Bis(2-chloroethoxy)methane ug ND 4 2194806 ND 4 2194806

Bis(2-chloroethyl)ether ug ND 5 2194806 ND 5 2194806

Bis(2-chloroisopropyl)ether ug ND 5 2194806 ND 5 2194806

Bis(2-ethylhexyl)phthalate ug ND 8 2194806 ND 8 2194806

Carbazole ug ND 20 2194806 ND 20 2194806

Chrysene ug ND 1 2194806 ND 0.15 2194814

Coronene ug ND 0.60 2194814 ND 0.60 2194814

Dibenz(a,h)anthracene ug ND 1 2194806 ND 1 2194806

Dibenzo(a,e)pyrene ug ND 0.60 2194814 ND 0.60 2194814

Dibenzofuran ug ND 20 2194806 ND 20 2194806

Diethyl phthalate ug ND 3 2194806 ND 3 2194806

Dimethyl phthalate ug ND 3 2194806 ND 3 2194806

Di-N-butyl phthalate ug ND 3 2194806 ND 3 2194806

Di-N-octyl phthalate ug ND 3 2194806 ND 3 2194806

Fluoranthene ug ND 1 2194806 ND 1 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 3 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 3 G H 4 6 5 6

Sampling Date 2010/06/22 2010/06/22

COC Number 001/003 006/008

 U n i t s BLK-DTE-M0010-FILT RDL QC Batch FB-DTE-M0010 RDL QC Batch

Fluorene ug ND 0.15 2194814 ND 0.15 2194814

Hexachlorobenzene ug ND 6 2194806 ND 6 2194806

Hexachlorobutadiene ug ND 6 2194806 ND 6 2194806

Hexachlorocyclopentadiene ug ND 6 2194806 ND 6 2194806

Hexachloroethane ug ND 6 2194806 ND 6 2194806

Indeno(1,2,3-cd)pyrene ug ND 2 2194806 ND 0.15 2194814

Isophorone ug ND 10 2194806 ND 10 2194806

m-Terphenyl ug ND 0.30 2194814 ND 0.30 2194814

Naphthalene ug ND 2 2194806 ND 0.30 2194814

Nitrobenzene ug ND 6 2194806 ND 6 2194806

N-Nitrosodimethylamine ug ND 30 2194806 ND 30 2194806

N-Nitroso-di-n-propylamine ug ND 6 2194806 ND 6 2194806

N-Nitrosodiphenylamine ug ND 6 2194806 ND 6 2194806

o-Terphenyl ug ND 0.30 2194814 ND 0.30 2194814

Pentachlorophenol ug ND 9 2194806 ND 9 2194806

Perylene ug ND 0.60 2194814 ND 0.60 2194814

Phenanthrene ug ND 1 2194806 ND 0.15 2194814

Phenol ug ND 5 2194806 ND 5 2194806

p-Terphenyl ug ND 0.30 2194814 ND 0.30 2194814

Pyrene ug ND 2 2194806 ND 0.15 2194814

Quinoline ug ND 0.60 2194814 ND 0.60 2194814

Tetralin ug ND 0.30 2194814 ND 0.30 2194814

Surrogate Recovery (%)

2,4,6-Tribromophenol % 71 2194806 75 2194806

2-Fluorobiphenyl % 80 2194806 75 2194806

2-Fluorophenol % 76 2194806 71 2194806

D5-Nitrobenzene % 83 2194806 73 2194806

D5-Phenol % 78 2194806 74 2194806

D10-2-Methylnaphthalene % 80 2194814 72 2194814

D10-Anthracene % 84 2194814

D10-Fluoranthene % 90 2194814 100 2194814

D10-Phenanthrene % 92 2194814 94 2194814

D12-Benzo(a)anthracene % 146 2194814 134 2194814

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 4 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 3 G H 4 6 5 6

Sampling Date 2010/06/22 2010/06/22

COC Number 001/003 006/008

 U n i t s BLK-DTE-M0010-FILT RDL QC Batch FB-DTE-M0010 RDL QC Batch

D12-Benzo(a)pyrene % 98 2194814 110 2194814

D12-Benzo(b)fluoranthene % 108 2194814 114 2194814

D12-Benzo(ghi)perylene % 96 2194814 94 2194814

D12-Benzo(k)fluoranthene % 92 2194814 98 2194814

D12-Chrysene % 100 2194814 90 2194814

D12-Indeno(1,2,3-cd)pyrene % 100 2194814 100 2194814

D12-Perylene % 90 2194814 96 2194814

D14-Dibenzo(a,h)anthracene % 94 2194814 94 2194814

D8-Acenaphthylene % 120 2194814 112 2194814

D8-Naphthalene % 88 2194814 80 2194814

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 5 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 7 G H 4 6 5 9 G H 4 6 6 0

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 007/009 011/013 012/014

 U n i t s FB-DTE-M0010 RDL QC Batch RUN1 RDL QC Batch RUN1 RDL QC Batch

-DTE-M0010 -DTE-M0010

1,2,4-Trichlorobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

1,2-Dichlorobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

1,3-Dichlorobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

1,4-Dichlorobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

1-Chloronaphthalene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

1-Methylnaphthalene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

1-Methylphenanthrene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

2,4,5-Trichlorophenol ug ND 6 2194806 ND 6 2194806 ND 6 2194806

2,4,6-Trichlorophenol ug ND 5 2194806 ND 5 2194806 ND 5 2194806

2,4-Dichlorophenol ug ND 4 2194806 ND 4 2194806 ND 4 2194806

2,4-Dimethylphenol ug ND 6 2194806 ND 6 2194806 ND 6 2194806

2,4-Dinitrophenol ug ND 10 2194806 ND 10 2194806 ND 10 2194806

2,4-Dinitrotoluene ug ND 2 2194806 ND 2 2194806 ND 2 2194806

2,6-Dinitrotoluene ug ND 3 2194806 ND 3 2194806 ND 3 2194806

2-Chloronaphthalene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

2-Chlorophenol ug ND 8 2194806 ND 8 2194806 ND 8 2194806

2-Methylanthracene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

2-Methylnaphthalene ug ND 5 2194806 ND 0.15 2194814 0.15 0.15 2194814

2-Methylphenol ug ND 9 2194806 ND 9 2194806 ND 9 2194806

2-Nitroaniline ug ND 20 2194806 ND 20 2194806 ND 20 2194806

2-Nitrophenol ug ND 5 2194806 ND 5 2194806 ND 5 2194806

3 & 4-methylphenol ug ND 10 2194806 ND 10 2194806 ND 10 2194806

3,3'-Dichlorobenzidine ug ND 8 2194806 ND 8 2194806 ND 8 2194806

3-Methylcholanthrene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

3-Nitroaniline ug ND 20 2194806 ND 20 2194806 ND 20 2194806

4,6-Dinitro-2-methylphenol ug ND 10 2194806 ND 10 2194806 ND 10 2194806

4-Bromophenyl phenyl ether ug ND 2 2194806 ND 2 2194806 ND 2 2194806

4-Chloro-3-Methylphenol ug ND 5 2194806 ND 5 2194806 ND 5 2194806

4-Chloroaniline ug ND 20 2194806 ND 20 2194806 ND 20 2194806

4-Chlorophenyl phenyl ether ug ND 3 2194806 ND 3 2194806 ND 3 2194806

4-Nitroaniline ug ND 20 2194806 ND 20 2194806 ND 20 2194806

4-Nitrophenol ug ND 10 2194806 ND 10 2194806 ND 10 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 6 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 7 G H 4 6 5 9 G H 4 6 6 0

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 007/009 011/013 012/014

 U n i t s FB-DTE-M0010 RDL QC Batch RUN1 RDL QC Batch RUN1 RDL QC Batch

-DTE-M0010 -DTE-M0010

7,12-Dimethylbenzo(a)anthracene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

9,10-Dimethylanthracene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Acenaphthene ug ND 2 2194806 ND 0.15 2194814 ND 0.15 2194814

Acenaphthylene ug ND 0.15 2194814 ND 0.15 2194814 ND 0.15 2194814

Aniline ug ND 20 2194806 ND 20 2194806 ND 20 2194806

Anthracene ug ND 1 2194806 ND 0.15 2194814 ND 0.15 2194814

Benzidine ug ND 60 2194806 ND 60 2194806 ND 60 2194806

Benzo(a)anthracene ug ND 1 2194806 ND 0.15 2194814 ND 0.15 2194814

Benzo(a)fluorene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Benzo(a)pyrene ug ND 0.15 2194814 ND 0.15 2194814 ND 0.15 2194814

Benzo(b)fluoranthene ug ND 1 2194806 ND 0.15 2194814 ND 0.15 2194814

Benzo(b)fluorene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

Benzo(e)pyrene ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

Benzo(g,h,i)perylene ug ND 1 2194806 ND 1 2194806 ND 1 2194806

Benzo(k)fluoranthene ug ND 0.15 2194814 ND 0.15 2194814 ND 0.15 2194814

Benzoic Acid ug ND 10 2194806 ND 10 2194806 80 10 2194806

Benzyl Alcohol ug ND 6 2194806 ND 6 2194806 ND 6 2194806

Benzyl butyl phthalate ug ND 2 2194806 ND 2 2194806 ND 2 2194806

Biphenyl ug ND 6 2194806 ND 0.30 2194814 ND 0.30 2194814

Bis(2-chloroethoxy)methane ug ND 4 2194806 ND 4 2194806 ND 4 2194806

Bis(2-chloroethyl)ether ug ND 5 2194806 ND 5 2194806 ND 5 2194806

Bis(2-chloroisopropyl)ether ug ND 5 2194806 ND 5 2194806 ND 5 2194806

Bis(2-ethylhexyl)phthalate ug ND 8 2194806 ND 8 2194806 50 8 2194806

Carbazole ug ND 20 2194806 ND 20 2194806 ND 20 2194806

Chrysene ug ND 1 2194806 ND 0.15 2194814 ND 0.15 2194814

Coronene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Dibenz(a,h)anthracene ug ND 1 2194806 ND 0.15 2194814 ND 0.15 2194814

Dibenzo(a,e)pyrene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Dibenzofuran ug ND 20 2194806 ND 20 2194806 ND 20 2194806

Diethyl phthalate ug ND 3 2194806 ND 3 2194806 ND 3 2194806

Dimethyl phthalate ug ND 3 2194806 ND 3 2194806 ND 3 2194806

Di-N-butyl phthalate ug ND 3 2194806 ND 3 2194806 3 3 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 7 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 7 G H 4 6 5 9 G H 4 6 6 0

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 007/009 011/013 012/014

 U n i t s FB-DTE-M0010 RDL QC Batch RUN1 RDL QC Batch RUN1 RDL QC Batch

-DTE-M0010 -DTE-M0010

Di-N-octyl phthalate ug ND 3 2194806 ND 3 2194806 ND 3 2194806

Fluoranthene ug ND 1 2194806 ND 0.15 2194814 ND ( 1 ) 1.5 2194814

Fluorene ug ND 0.15 2194814 ND 0.15 2194814 ND 0.15 2194814

Hexachlorobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

Hexachlorobutadiene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

Hexachlorocyclopentadiene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

Hexachloroethane ug ND 6 2194806 ND 6 2194806 ND 6 2194806

Indeno(1,2,3-cd)pyrene ug ND 0.15 2194814 ND 0.15 2194814 ND 0.15 2194814

Isophorone ug ND 10 2194806 ND 10 2194806 ND 10 2194806

m-Terphenyl ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

Naphthalene ug ND 2 2194806 ND 0.30 2194814 0.72 0.30 2194814

Nitrobenzene ug ND 6 2194806 ND 6 2194806 ND 6 2194806

N-Nitrosodimethylamine ug ND 30 2194806 ND 30 2194806 ND 30 2194806

N-Nitroso-di-n-propylamine ug ND 6 2194806 ND 6 2194806 ND 6 2194806

N-Nitrosodiphenylamine ug ND 6 2194806 ND 6 2194806 ND 6 2194806

o-Terphenyl ug ND 0.30 2194814 0.34 0.30 2194814 ND 0.30 2194814

Pentachlorophenol ug ND 9 2194806 ND 9 2194806 ND 9 2194806

Perylene ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Phenanthrene ug ND 0.15 2194814 ND 0.15 2194814 0.51 0.15 2194814

Phenol ug ND 5 2194806 ND 5 2194806 5 5 2194806

p-Terphenyl ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

Pyrene ug ND 2 2194806 ND 2 2194806 3.68 0.15 2194814

Quinoline ug ND 0.60 2194814 ND 0.60 2194814 ND 0.60 2194814

Tetralin ug ND 0.30 2194814 ND 0.30 2194814 ND 0.30 2194814

Surrogate Recovery (%)

2,4,6-Tribromophenol % 0.00 ( 2 ) 2194806 77 2194806 84 2194806

2,6-Dibromo-4-fluorophenol (FS) % 0.74 ( 2 ) 2194806 56 2194806

2-Fluorobiphenyl % 81 2194806 75 2194806 74 2194806

2-Fluorophenol % 47 2194806 70 2194806 71 2194806

D5-Nitrobenzene % 77 2194806 75 2194806 68 2194806

D5-Phenol % 67 2194806 73 2194806 73 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

( 1 ) Confirming ion does not meet criteria

( 2 ) Recovery or RPD for this parameter is outside control limits. The overall quality control for this analysis meets acceptability criteria.

Page 8 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 5 7 G H 4 6 5 9 G H 4 6 6 0

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 007/009 011/013 012/014

 U n i t s FB-DTE-M0010 RDL QC Batch RUN1 RDL QC Batch RUN1 RDL QC Batch

-DTE-M0010 -DTE-M0010

D10-2-Methylnaphthalene % 60 2194814 72 2194814 60 2194814

D10-Anthracene % 76 2194814 70 2194814 86 2194814

D10-Fluoranthene % 74 2194814 78 2194814 96 2194814

D10-Fluorene (FS) % 92 2194814 78 2194814

D10-Phenanthrene % 76 2194814 76 2194814 88 2194814

D12-Benzo(a)anthracene % 112 2194814 126 2194814 140 2194814

D12-Benzo(a)pyrene % 68 2194814 94 2194814 104 2194814

D12-Benzo(b)fluoranthene % 96 2194814 108 2194814 102 2194814

D12-Benzo(ghi)perylene % 84 2194814 88 2194814 96 2194814

D12-Benzo(k)fluoranthene % 84 2194814 96 2194814 94 2194814

D12-Chrysene % 84 2194814 92 2194814 84 2194814

D12-Indeno(1,2,3-cd)pyrene % 86 2194814 92 2194814 104 2194814

D12-Perylene % 66 2194814 84 2194814 92 2194814

D14-Dibenzo(a,h)anthracene % 80 2194814 84 2194814 96 2194814

D14-Terphenyl (FS) % 86 2194814 86 2194814

D8-Acenaphthylene % 86 2194814 106 2194814 98 2194814

D8-Naphthalene % 66 2194814 82 2194814 64 2194814

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 9 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 6 1 G H 4 6 6 2 G H 4 6 6 3

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 015 001/003 001/003

 U n i t s RUN1 RDL QC Batch RUN2 RDL QC Batch RUN2 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

1,2,4-Trichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,2-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,3-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,4-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1-Chloronaphthalene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1-Methylnaphthalene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

1-Methylphenanthrene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

2,4,5-Trichlorophenol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

2,4,6-Trichlorophenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

2,4-Dichlorophenol ug ND 4 2198768 ND 4 2194806 ND 4 2194806

2,4-Dimethylphenol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

2,4-Dinitrophenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

2,4-Dinitrotoluene ug ND 2 2198768 ND 2 2194806 ND 2 2194806

2,6-Dinitrotoluene ug ND 3 2198768 ND 3 2194806 ND 3 2194806

2-Chloronaphthalene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

2-Chlorophenol ug ND 8 2198768 ND 8 2194806 ND 8 2194806

2-Methylanthracene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

2-Methylnaphthalene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

2-Methylphenol ug ND 9 2198768 ND 9 2194806 ND 9 2194806

2-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

2-Nitrophenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

3 & 4-methylphenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

3,3'-Dichlorobenzidine ug ND 8 2198768 ND 8 2194806 ND 8 2194806

3-Methylcholanthrene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

3-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4,6-Dinitro-2-methylphenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

4-Bromophenyl phenyl ether ug ND 2 2198768 ND 2 2194806 ND 2 2194806

4-Chloro-3-Methylphenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

4-Chloroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4-Chlorophenyl phenyl ether ug ND 3 2198768 ND 3 2194806 ND 3 2194806

4-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4-Nitrophenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 10 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 6 1 G H 4 6 6 2 G H 4 6 6 3

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 015 001/003 001/003

 U n i t s RUN1 RDL QC Batch RUN2 RDL QC Batch RUN2 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

7,12-Dimethylbenzo(a)anthracene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

9,10-Dimethylanthracene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Acenaphthene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Acenaphthylene ug ND 0.15 2198767 ND 0.15 2194814 ND 2 2194806

Aniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Anthracene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Benzidine ug ND 60 2198768 ND 60 2194806 ND 60 2194806

Benzo(a)anthracene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Benzo(a)fluorene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Benzo(a)pyrene ug ND 2 2198768 ND 0.15 2194814 ND 0.15 2194814

Benzo(b)fluoranthene ug ND 0.15 2198767 ND 1 2194806 ND 1 2194806

Benzo(b)fluorene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Benzo(e)pyrene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Benzo(g,h,i)perylene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Benzo(k)fluoranthene ug ND 2 2198768 ND 0.15 2194814 ND 2 2194806

Benzoic Acid ug ND 10 2198768 ND 10 2194806 129 20 2194806

Benzyl Alcohol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Benzyl butyl phthalate ug ND 2 2198768 ND 2 2194806 ND 2 2194806

Biphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Bis(2-chloroethoxy)methane ug ND 4 2198768 ND 4 2194806 ND 4 2194806

Bis(2-chloroethyl)ether ug ND 5 2198768 ND 5 2194806 ND 5 2194806

Bis(2-chloroisopropyl)ether ug ND 5 2198768 ND 5 2194806 ND 5 2194806

Bis(2-ethylhexyl)phthalate ug ND 8 2198768 9 8 2194806 41 8 2194806

Carbazole ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Chrysene ug ND 0.15 2198767 ND 1 2194806 ND 0.15 2194814

Coronene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Dibenz(a,h)anthracene ug ND 0.15 2198767 ND 1 2194806 ND 1 2194806

Dibenzo(a,e)pyrene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Dibenzofuran ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Diethyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Dimethyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Di-N-butyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 11 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 6 1 G H 4 6 6 2 G H 4 6 6 3

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 015 001/003 001/003

 U n i t s RUN1 RDL QC Batch RUN2 RDL QC Batch RUN2 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

Di-N-octyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Fluoranthene ug ND 0.15 2198767 ND 0.15 2194814 1.39 0.15 2194814

Fluorene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Hexachlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachlorobutadiene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachlorocyclopentadiene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachloroethane ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Indeno(1,2,3-cd)pyrene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Isophorone ug ND 10 2198768 ND 10 2194806 ND 10 2194806

m-Terphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Naphthalene ug ND 0.30 2198767 ND 2 2194806 ND 2 2194806

Nitrobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

N-Nitrosodimethylamine ug ND 30 2198768 ND 30 2194806 ND 30 2194806

N-Nitroso-di-n-propylamine ug ND 6 2198768 ND 6 2194806 ND 6 2194806

N-Nitrosodiphenylamine ug ND 6 2198768 ND 6 2194806 ND 6 2194806

o-Terphenyl ug ND 0.30 2198767 0.31 0.30 2194814 ND 0.30 2194814

Pentachlorophenol ug ND 9 2198768 ND 9 2194806 ND 9 2194806

Perylene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Phenanthrene ug ND 0.15 2198767 ND 0.15 2194814 0.40 0.15 2194814

Phenol ug 5 5 2198768 ND 5 2194806 13 5 2194806

p-Terphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Pyrene ug ND 0.15 2198767 ND 0.15 2194814 4 2 2194806

Quinoline ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Tetralin ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Surrogate Recovery (%)

2,4,6-Tribromophenol % 81 2198768 84 2194806 75 2194806

2,6-Dibromo-4-fluorophenol (FS) % 52 2194806

2-Fluorobiphenyl % 80 2198768 85 2194806 78 2194806

2-Fluorophenol % 72 2198768 85 2194806 73 2194806

D5-Nitrobenzene % 82 2198768 83 2194806 73 2194806

D5-Phenol % 83 2198768 88 2194806 79 2194806

D10-2-Methylnaphthalene % 58 2198767 66 2194814 58 2194814

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 12 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 6 1 G H 4 6 6 2 G H 4 6 6 3

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 015 001/003 001/003

 U n i t s RUN1 RDL QC Batch RUN2 RDL QC Batch RUN2 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

D10-Anthracene % 76 2194814 90 2194814

D10-Fluoranthene % 90 2198767 84 2194814 90 2194814

D10-Fluorene (FS) % 78 2194814

D10-Phenanthrene % 90 2198767 78 2194814 82 2194814

D12-Benzo(a)anthracene % 118 2198767 122 2194814 132 2194814

D12-Benzo(a)pyrene % 88 2198767 94 2194814 96 2194814

D12-Benzo(b)fluoranthene % 114 2198767 100 2194814 96 2194814

D12-Benzo(ghi)perylene % 92 2198767 86 2194814 90 2194814

D12-Benzo(k)fluoranthene % 94 2198767 86 2194814 88 2194814

D12-Chrysene % 92 2198767 82 2194814 80 2194814

D12-Indeno(1,2,3-cd)pyrene % 98 2198767 92 2194814 98 2194814

D12-Perylene % 88 2198767 84 2194814 84 2194814

D14-Dibenzo(a,h)anthracene % 92 2198767 86 2194814 90 2194814

D14-Terphenyl (FS) % 81 2194814

D8-Acenaphthylene % 60 2198767 100 2194814 92 2194814

D8-Naphthalene % 68 2198767 74 2194814 62 2194814

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 13 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 0 G H 4 6 7 1 G H 4 6 7 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 001/003 001/003 001/003

 U n i t s RUN2 RDL QC Batch RUN3 RDL QC Batch RUN3 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

1,2,4-Trichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,2-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,3-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1,4-Dichlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1-Chloronaphthalene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

1-Methylnaphthalene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

1-Methylphenanthrene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

2,4,5-Trichlorophenol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

2,4,6-Trichlorophenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

2,4-Dichlorophenol ug ND 4 2198768 ND 4 2194806 ND 4 2194806

2,4-Dimethylphenol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

2,4-Dinitrophenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

2,4-Dinitrotoluene ug ND 2 2198768 ND 2 2194806 ND 2 2194806

2,6-Dinitrotoluene ug ND 3 2198768 ND 3 2194806 ND 3 2194806

2-Chloronaphthalene ug ND 3 2198768 ND 0.30 2194814 ND 0.30 2194814

2-Chlorophenol ug ND 8 2198768 ND 8 2194806 ND 8 2194806

2-Methylanthracene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

2-Methylnaphthalene ug ND 5 2198768 ND 0.15 2194814 ND 5 2194806

2-Methylphenol ug ND 9 2198768 ND 9 2194806 ND 9 2194806

2-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

2-Nitrophenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

3 & 4-methylphenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

3,3'-Dichlorobenzidine ug ND 8 2198768 ND 8 2194806 ND 8 2194806

3-Methylcholanthrene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

3-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4,6-Dinitro-2-methylphenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

4-Bromophenyl phenyl ether ug ND 2 2198768 ND 2 2194806 ND 2 2194806

4-Chloro-3-Methylphenol ug ND 5 2198768 ND 5 2194806 ND 5 2194806

4-Chloroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4-Chlorophenyl phenyl ether ug ND 3 2198768 ND 3 2194806 ND 3 2194806

4-Nitroaniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

4-Nitrophenol ug ND 10 2198768 ND 10 2194806 ND 10 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 14 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 0 G H 4 6 7 1 G H 4 6 7 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 001/003 001/003 001/003

 U n i t s RUN2 RDL QC Batch RUN3 RDL QC Batch RUN3 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

7,12-Dimethylbenzo(a)anthracene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

9,10-Dimethylanthracene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Acenaphthene ug ND 2 2198768 ND 2 2194806 ND 2 2194806

Acenaphthylene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Aniline ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Anthracene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Benzidine ug ND 60 2198768 ND 60 2194806 ND 60 2194806

Benzo(a)anthracene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Benzo(a)fluorene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Benzo(a)pyrene ug ND 2 2198768 ND 0.15 2194814 ND 0.15 2194814

Benzo(b)fluoranthene ug ND 0.15 2198767 ND 1 2194806 ND 1 2194806

Benzo(b)fluorene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Benzo(e)pyrene ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Benzo(g,h,i)perylene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Benzo(k)fluoranthene ug ND 0.15 2198767 ND 2 2194806 ND 0.15 2194814

Benzoic Acid ug ND 10 2198768 ND 10 2194806 105 10 2194806

Benzyl Alcohol ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Benzyl butyl phthalate ug ND 2 2198768 ND 2 2194806 ND 2 2194806

Biphenyl ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Bis(2-chloroethoxy)methane ug ND 4 2198768 ND 4 2194806 ND 4 2194806

Bis(2-chloroethyl)ether ug ND 5 2198768 ND 5 2194806 ND 5 2194806

Bis(2-chloroisopropyl)ether ug ND 5 2198768 ND 5 2194806 ND 5 2194806

Bis(2-ethylhexyl)phthalate ug ND 8 2198768 10 8 2194806 25 8 2194806

Carbazole ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Chrysene ug ND 1 2198768 ND 0.15 2194814 ND 1 2194806

Coronene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Dibenz(a,h)anthracene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Dibenzo(a,e)pyrene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Dibenzofuran ug ND 20 2198768 ND 20 2194806 ND 20 2194806

Diethyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Dimethyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Di-N-butyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 15 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 0 G H 4 6 7 1 G H 4 6 7 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 001/003 001/003 001/003

 U n i t s RUN2 RDL QC Batch RUN3 RDL QC Batch RUN3 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

Di-N-octyl phthalate ug ND 3 2198768 ND 3 2194806 ND 3 2194806

Fluoranthene ug ND 1 2198768 ND 1 2194806 ND 1 2194806

Fluorene ug ND 0.15 2198767 ND 0.15 2194814 ND 0.15 2194814

Hexachlorobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachlorobutadiene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachlorocyclopentadiene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Hexachloroethane ug ND 6 2198768 ND 6 2194806 ND 6 2194806

Indeno(1,2,3-cd)pyrene ug ND 2 2198768 ND 0.15 2194814 ND 0.15 2194814

Isophorone ug ND 10 2198768 ND 10 2194806 ND 10 2194806

m-Terphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Naphthalene ug ND 2 2198768 ND 0.30 2194814 ND 2 2194806

Nitrobenzene ug ND 6 2198768 ND 6 2194806 ND 6 2194806

N-Nitrosodimethylamine ug ND 30 2198768 ND 30 2194806 ND 30 2194806

N-Nitroso-di-n-propylamine ug ND 6 2198768 ND 6 2194806 ND 6 2194806

N-Nitrosodiphenylamine ug ND 6 2198768 ND 6 2194806 ND 6 2194806

o-Terphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Pentachlorophenol ug ND 9 2198768 ND 9 2194806 ND 9 2194806

Perylene ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Phenanthrene ug ND 1 2198768 ND 0.15 2194814 0.15 0.15 2194814

Phenol ug 30 5 2198768 ND 5 2194806 ND 5 2194806

p-Terphenyl ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Pyrene ug ND 2 2198768 ND 0.15 2194814 2 2 2194806

Quinoline ug ND 0.60 2198767 ND 0.60 2194814 ND 0.60 2194814

Tetralin ug ND 0.30 2198767 ND 0.30 2194814 ND 0.30 2194814

Surrogate Recovery (%)

2,4,6-Tribromophenol % 92 2198768 79 2194806 68 2194806

2,6-Dibromo-4-fluorophenol (FS) % 47 2194806

2-Fluorobiphenyl % 86 2198768 76 2194806 77 2194806

2-Fluorophenol % 93 2198768 71 2194806 66 2194806

D5-Nitrobenzene % 91 2198768 79 2194806 72 2194806

D5-Phenol % 98 2198768 78 2194806 78 2194806

D10-2-Methylnaphthalene % 56 2198767 60 2194814 56 2194814

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 16 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 0 G H 4 6 7 1 G H 4 6 7 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number 001/003 001/003 001/003

 U n i t s RUN2 RDL QC Batch RUN3 RDL QC Batch RUN3 RDL QC Batch

-DTE-M0010 -DTE-M0010 -DTE-M0010

D10-Anthracene % 78 2194814 84 2194814

D10-Fluoranthene % 82 2198767 80 2194814 82 2194814

D10-Fluorene (FS) % 81 2194814

D10-Phenanthrene % 84 2198767 74 2194814 78 2194814

D12-Benzo(a)anthracene % 112 2198767 116 2194814 126 2194814

D12-Benzo(a)pyrene % 86 2198767 90 2194814 90 2194814

D12-Benzo(b)fluoranthene % 108 2198767 96 2194814 98 2194814

D12-Benzo(ghi)perylene % 88 2198767 84 2194814 86 2194814

D12-Benzo(k)fluoranthene % 90 2198767 86 2194814 86 2194814

D12-Chrysene % 88 2198767 82 2194814 80 2194814

D12-Indeno(1,2,3-cd)pyrene % 92 2198767 88 2194814 92 2194814

D12-Perylene % 82 2198767 80 2194814 82 2194814

D14-Dibenzo(a,h)anthracene % 88 2198767 82 2194814 82 2194814

D14-Terphenyl (FS) % 82 2194814

D8-Acenaphthylene % 102 2198767 92 2194814 88 2194814

D8-Naphthalene % 62 2198767 64 2194814 60 2194814

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 17 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 3

Sampling Date 2010/06/22

COC Number 001/003

 U n i t s RUN3 RDL QC Batch

-DTE-M0010

1,2,4-Trichlorobenzene ug ND 6 2198768

1,2-Dichlorobenzene ug ND 6 2198768

1,3-Dichlorobenzene ug ND 6 2198768

1,4-Dichlorobenzene ug ND 6 2198768

1-Chloronaphthalene ug ND 6 2198768

1-Methylnaphthalene ug ND 0.30 2198767

1-Methylphenanthrene ug ND 0.30 2198767

2,4,5-Trichlorophenol ug ND 6 2198768

2,4,6-Trichlorophenol ug ND 5 2198768

2,4-Dichlorophenol ug ND 4 2198768

2,4-Dimethylphenol ug ND 6 2198768

2,4-Dinitrophenol ug ND 10 2198768

2,4-Dinitrotoluene ug ND 2 2198768

2,6-Dinitrotoluene ug ND 3 2198768

2-Chloronaphthalene ug ND 0.30 2198767

2-Chlorophenol ug ND 8 2198768

2-Methylanthracene ug ND 0.30 2198767

2-Methylnaphthalene ug ND 0.15 2198767

2-Methylphenol ug ND 9 2198768

2-Nitroaniline ug ND 20 2198768

2-Nitrophenol ug ND 5 2198768

3 & 4-methylphenol ug ND 10 2198768

3,3'-Dichlorobenzidine ug ND 8 2198768

3-Methylcholanthrene ug ND 0.60 2198767

3-Nitroaniline ug ND 20 2198768

4,6-Dinitro-2-methylphenol ug ND 10 2198768

4-Bromophenyl phenyl ether ug ND 2 2198768

4-Chloro-3-Methylphenol ug ND 5 2198768

4-Chloroaniline ug ND 20 2198768

4-Chlorophenyl phenyl ether ug ND 3 2198768

4-Nitroaniline ug ND 20 2198768

4-Nitrophenol ug ND 10 2198768

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 18 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 3

Sampling Date 2010/06/22

COC Number 001/003

 U n i t s RUN3 RDL QC Batch

-DTE-M0010

7,12-Dimethylbenzo(a)anthracene ug ND 0.60 2198767

9,10-Dimethylanthracene ug ND 0.60 2198767

Acenaphthene ug ND 0.15 2198767

Acenaphthylene ug ND 0.15 2198767

Aniline ug ND 20 2198768

Anthracene ug ND 0.15 2198767

Benzidine ug ND 60 2198768

Benzo(a)anthracene ug ND 0.15 2198767

Benzo(a)fluorene ug ND 0.60 2198767

Benzo(a)pyrene ug ND 0.15 2198767

Benzo(b)fluoranthene ug ND 0.15 2198767

Benzo(b)fluorene ug ND 0.30 2198767

Benzo(e)pyrene ug ND 0.30 2198767

Benzo(g,h,i)perylene ug ND 1 2198768

Benzo(k)fluoranthene ug ND 0.15 2198767

Benzoic Acid ug ND 10 2198768

Benzyl Alcohol ug ND 6 2198768

Benzyl butyl phthalate ug ND 2 2198768

Biphenyl ug ND 0.30 2198767

Bis(2-chloroethoxy)methane ug ND 4 2198768

Bis(2-chloroethyl)ether ug ND 5 2198768

Bis(2-chloroisopropyl)ether ug ND 5 2198768

Bis(2-ethylhexyl)phthalate ug ND 8 2198768

Carbazole ug ND 20 2198768

Chrysene ug ND 0.15 2198767

Coronene ug ND 0.60 2198767

Dibenz(a,h)anthracene ug ND 0.15 2198767

Dibenzo(a,e)pyrene ug ND 0.60 2198767

Dibenzofuran ug ND 20 2198768

Diethyl phthalate ug ND 3 2198768

Dimethyl phthalate ug ND 3 2198768

Di-N-butyl phthalate ug ND 3 2198768

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 19 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 3

Sampling Date 2010/06/22

COC Number 001/003

 U n i t s RUN3 RDL QC Batch

-DTE-M0010

Di-N-octyl phthalate ug ND 3 2198768

Fluoranthene ug ND 0.15 2198767

Fluorene ug ND 0.15 2198767

Hexachlorobenzene ug ND 6 2198768

Hexachlorobutadiene ug ND 6 2198768

Hexachlorocyclopentadiene ug ND 6 2198768

Hexachloroethane ug ND 6 2198768

Indeno(1,2,3-cd)pyrene ug ND 0.15 2198767

Isophorone ug ND 10 2198768

m-Terphenyl ug ND 0.30 2198767

Naphthalene ug ND 0.30 2198767

Nitrobenzene ug ND 6 2198768

N-Nitrosodimethylamine ug ND 30 2198768

N-Nitroso-di-n-propylamine ug ND 6 2198768

N-Nitrosodiphenylamine ug ND 6 2198768

o-Terphenyl ug ND 0.30 2198767

Pentachlorophenol ug ND 9 2198768

Perylene ug ND 0.60 2198767

Phenanthrene ug ND 0.15 2198767

Phenol ug ND 5 2198768

p-Terphenyl ug ND 0.30 2198767

Pyrene ug ND 2 2198768

Quinoline ug ND 0.60 2198767

Tetralin ug ND 0.30 2198767

Surrogate Recovery (%)

2,4,6-Tribromophenol % 85 2198768

2-Fluorobiphenyl % 82 2198768

2-Fluorophenol % 83 2198768

D5-Nitrobenzene % 83 2198768

D5-Phenol % 87 2198768

D10-2-Methylnaphthalene % 54 2198767

D10-Fluoranthene % 86 2198767

ND = Not detected

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 20 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

SEMI-VOLATILE ORGANICS BY GC-MS (STACK SAMPLING TRAIN)

Maxxam ID G H 4 6 7 3

Sampling Date 2010/06/22

COC Number 001/003

 U n i t s RUN3 RDL QC Batch

-DTE-M0010

D10-Phenanthrene % 86 2198767

D12-Benzo(a)anthracene % 118 2198767

D12-Benzo(a)pyrene % 92 2198767

D12-Benzo(b)fluoranthene % 108 2198767

D12-Benzo(ghi)perylene % 90 2198767

D12-Benzo(k)fluoranthene % 90 2198767

D12-Chrysene % 90 2198767

D12-Indeno(1,2,3-cd)pyrene % 96 2198767

D12-Perylene % 86 2198767

D14-Dibenzo(a,h)anthracene % 90 2198767

D8-Acenaphthylene % 106 2198767

D8-Naphthalene % 64 2198767

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 21 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

Test Summary

Maxxam ID GH4653 Collected 2010/06/22

Sample ID BLK-DTE-M0010-FILT Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4656 Collected 2010/06/22

Sample ID FB-DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4657 Collected 2010/06/22

Sample ID FB-DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4659 Collected 2010/06/22

Sample ID RUN1 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4660 Collected 2010/06/22

Sample ID RUN1 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4661 Collected 2010/06/22

Sample ID RUN1 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2198768 2010/07/05 2010/08/11 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2198767 2010/07/05 2010/08/11 WZ

Page 22 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

Test Summary

Maxxam ID GH4662 Collected 2010/06/22

Sample ID RUN2 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4663 Collected 2010/06/22

Sample ID RUN2 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4670 Collected 2010/06/22

Sample ID RUN2 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2198768 2010/07/05 2010/08/11 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2198767 2010/07/05 2010/08/11 WZ

Maxxam ID GH4671 Collected 2010/06/22

Sample ID RUN3 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4672 Collected 2010/06/22

Sample ID RUN3 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2194806 2010/06/30 2010/08/10 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2194814 2010/06/30 2010/08/10 WZ

Maxxam ID GH4673 Collected 2010/06/22

Sample ID RUN3 -DTE-M0010 Shipped

Matrix Stack Sampling Train Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

SVOCs in MM5 SamplingTrain (EPA0010) GC/MS 2198768 2010/07/05 2010/08/11 JIW

PAH's in MM5 SamplingTrains (CARB429m GC/MS 2198767 2010/07/05 2010/08/11 WZ

Page 23 of 33
BT Environmental Consulting

Maxxam Job #: B082851 Client Project #: 10-3991.00

Report Date: 2010/08/13 Project name: DTE-BELLE RIVER

GENERAL COMMENTS

ABNMM5-TR

Benzoic acid and Benzidine are above 20% RSD in initial calibration.

Benzidine is above 30% RSD in 8270 Reference Standard.

PAHMM5-TR

7,12-Dimethylbenzo(a)anthracene is above 25% RSD in initial calibation and D8-Acenaphthylene is above 25% RSD in continuing . No positive

found for this compound.

Not calibrated for Benzo(b)Anthracene, Picene, Dibenzo(a,c) anthracene or Triphenylene. An estimated mdl for each of these compounds is

0.15ug.

Since Dibenzo(a,c) anthracene co-elutes with Dibenzo(a,h) anthracene and Triphenylene with Chrysene each would have a value below estimated

mdl.

Benzo(b)Anthracene elutes after Benzo(a)Anthracene and Chysene. Picene elutes after Dibenzo(a,h) anthracene. Searched for ions specific to

these 2 compounds in the appropriate retention time range with no possible positives detected

Sample GH4657-01: ABNMM5-TR

Low recovery of 2,6-Dibromo-4-fluorophenol and 2,4,6-Tribromophenol in this sample.

Sample GH4660-01: ABNMM5-TR

Internal Std area response criteria was low in this sample. The sample was rerun with similar result. Original run reported.

Sample GH4663-01: ABNMM5-TR

Sample was rerun at a 2x dilution for Benzoic acid due to exceedence of linear range.

Mdl was raised accordingly.

Results relate only to the items tested.

Page 24 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2194806 JIW Spiked Blank 2,4,6-Tribromophenol 2010/08/10 93 % 24 - 121

Spiked Blank DUP 2,4,6-Tribromophenol 2010/08/10 82 % 24 - 121

Spiked Blank 2-Fluorobiphenyl 2010/08/10 96 % 30 - 115

Spiked Blank DUP 2-Fluorobiphenyl 2010/08/10 90 % 30 - 115

Spiked Blank 2-Fluorophenol 2010/08/10 91 % 30 - 130

Spiked Blank DUP 2-Fluorophenol 2010/08/10 86 % 30 - 130

Spiked Blank D5-Nitrobenzene 2010/08/10 101 % 23 - 120

Spiked Blank DUP D5-Nitrobenzene 2010/08/10 91 % 23 - 120

Spiked Blank D5-Phenol 2010/08/10 94 % 24 - 113

Spiked Blank DUP D5-Phenol 2010/08/10 90 % 24 - 113

Spiked Blank 1,2,4-Trichlorobenzene 2010/08/10 97 % 40 - 125

Spiked Blank DUP 1,2,4-Trichlorobenzene 2010/08/10 88 % 40 - 125

RPD 1,2,4-Trichlorobenzene 2010/08/10 9.7 % 50

Spiked Blank 1,4-Dichlorobenzene 2010/08/10 93 % 40 - 125

Spiked Blank DUP 1,4-Dichlorobenzene 2010/08/10 89 % 40 - 125

RPD 1,4-Dichlorobenzene 2010/08/10 4.4 % 50

Spiked Blank 2,4-Dinitrotoluene 2010/08/10 98 % 40 - 125

Spiked Blank DUP 2,4-Dinitrotoluene 2010/08/10 86 % 40 - 125

RPD 2,4-Dinitrotoluene 2010/08/10 12.8 % 50

Spiked Blank 2-Chlorophenol 2010/08/10 96 % 10 - 125

Spiked Blank DUP 2-Chlorophenol 2010/08/10 90 % 10 - 125

RPD 2-Chlorophenol 2010/08/10 6.4 % 50

Spiked Blank 4-Chloro-3-Methylphenol 2010/08/10 108 % 10 - 125

Spiked Blank DUP 4-Chloro-3-Methylphenol 2010/08/10 96 % 10 - 125

RPD 4-Chloro-3-Methylphenol 2010/08/10 11.2 % 50

Spiked Blank 4-Nitrophenol 2010/08/10 103 % 10 - 125

Spiked Blank DUP 4-Nitrophenol 2010/08/10 90 % 10 - 125

RPD 4-Nitrophenol 2010/08/10 13.1 % 50

Spiked Blank Acenaphthene 2010/08/10 95 % 40 - 125

Spiked Blank DUP Acenaphthene 2010/08/10 90 % 40 - 125

RPD Acenaphthene 2010/08/10 6.2 % 50

Spiked Blank N-Nitroso-di-n-propylamine 2010/08/10 108 % 40 - 125

Spiked Blank DUP N-Nitroso-di-n-propylamine 2010/08/10 101 % 40 - 125

RPD N-Nitroso-di-n-propylamine 2010/08/10 7.5 % 50

Spiked Blank Pentachlorophenol 2010/08/10 69 % 10 - 125

Spiked Blank DUP Pentachlorophenol 2010/08/10 54 % 10 - 125

RPD Pentachlorophenol 2010/08/10 24.4 % 50

Spiked Blank Phenol 2010/08/10 91 % 10 - 125

Spiked Blank DUP Phenol 2010/08/10 86 % 10 - 125

RPD Phenol 2010/08/10 5.0 % 50

Spiked Blank Pyrene 2010/08/10 101 % 40 - 125

Spiked Blank DUP Pyrene 2010/08/10 94 % 40 - 125

RPD Pyrene 2010/08/10 7.1 % 50

Method Blank 2,4,6-Tribromophenol 2010/08/10 26 % 24 - 121

2-Fluorobiphenyl 2010/08/10 86 % 30 - 115

2-Fluorophenol 2010/08/10 80 % 30 - 130

D5-Nitrobenzene 2010/08/10 86 % 23 - 120

D5-Phenol 2010/08/10 84 % 24 - 113

1,2,4-Trichlorobenzene 2010/08/10 ND, RDL=6 ug

1,2-Dichlorobenzene 2010/08/10 ND, RDL=6 ug

1,3-Dichlorobenzene 2010/08/10 ND, RDL=6 ug

1,4-Dichlorobenzene 2010/08/10 ND, RDL=6 ug

1-Chloronaphthalene 2010/08/10 ND, RDL=6 ug

1-Methylnaphthalene 2010/08/10 ND, RDL=9 ug

2,4,5-Trichlorophenol 2010/08/10 ND, RDL=6 ug

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 25 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2194806 JIW Method Blank 2,4,6-Trichlorophenol 2010/08/10 ND, RDL=5 ug

2,4-Dichlorophenol 2010/08/10 ND, RDL=4 ug

2,4-Dimethylphenol 2010/08/10 ND, RDL=6 ug

2,4-Dinitrophenol 2010/08/10 ND, RDL=10 ug

2,4-Dinitrotoluene 2010/08/10 ND, RDL=2 ug

2,6-Dinitrotoluene 2010/08/10 ND, RDL=3 ug

2-Chloronaphthalene 2010/08/10 ND, RDL=3 ug

2-Chlorophenol 2010/08/10 ND, RDL=8 ug

2-Methylnaphthalene 2010/08/10 ND, RDL=5 ug

2-Methylphenol 2010/08/10 ND, RDL=9 ug

2-Nitroaniline 2010/08/10 ND, RDL=20 ug

2-Nitrophenol 2010/08/10 ND, RDL=5 ug

3 & 4-methylphenol 2010/08/10 ND, RDL=10 ug

3,3'-Dichlorobenzidine 2010/08/10 ND, RDL=8 ug

3-Nitroaniline 2010/08/10 ND, RDL=20 ug

4,6-Dinitro-2-methylphenol 2010/08/10 ND, RDL=10 ug

4-Bromophenyl phenyl ether 2010/08/10 ND, RDL=2 ug

4-Chloro-3-Methylphenol 2010/08/10 ND, RDL=5 ug

4-Chloroaniline 2010/08/10 ND, RDL=20 ug

4-Chlorophenyl phenyl ether 2010/08/10 ND, RDL=3 ug

4-Nitroaniline 2010/08/10 ND, RDL=20 ug

4-Nitrophenol 2010/08/10 ND, RDL=10 ug

Acenaphthene 2010/08/10 ND, RDL=2 ug

Acenaphthylene 2010/08/10 ND, RDL=2 ug

Aniline 2010/08/10 ND, RDL=20 ug

Anthracene 2010/08/10 ND, RDL=1 ug

Benzidine 2010/08/10 ND, RDL=60 ug

Benzo(a)anthracene 2010/08/10 ND, RDL=1 ug

Benzo(a)pyrene 2010/08/10 ND, RDL=2 ug

Benzo(b)fluoranthene 2010/08/10 ND, RDL=1 ug

Benzo(g,h,i)perylene 2010/08/10 ND, RDL=1 ug

Benzo(k)fluoranthene 2010/08/10 ND, RDL=2 ug

Benzoic Acid 2010/08/10 ND, RDL=10 ug

Benzyl Alcohol 2010/08/10 ND, RDL=6 ug

Benzyl butyl phthalate 2010/08/10 ND, RDL=2 ug

Biphenyl 2010/08/10 ND, RDL=6 ug

Bis(2-chloroethoxy)methane 2010/08/10 ND, RDL=4 ug

Bis(2-chloroethyl)ether 2010/08/10 ND, RDL=5 ug

Bis(2-chloroisopropyl)ether 2010/08/10 ND, RDL=5 ug

Bis(2-ethylhexyl)phthalate 2010/08/10 33, RDL=8 ug

Carbazole 2010/08/10 ND, RDL=20 ug

Chrysene 2010/08/10 ND, RDL=1 ug

Dibenz(a,h)anthracene 2010/08/10 ND, RDL=1 ug

Dibenzofuran 2010/08/10 ND, RDL=20 ug

Diethyl phthalate 2010/08/10 ND, RDL=3 ug

Dimethyl phthalate 2010/08/10 ND, RDL=3 ug

Di-N-butyl phthalate 2010/08/10 ND, RDL=3 ug

Di-N-octyl phthalate 2010/08/10 ND, RDL=3 ug

Fluoranthene 2010/08/10 ND, RDL=1 ug

Fluorene 2010/08/10 ND, RDL=1 ug

Hexachlorobenzene 2010/08/10 ND, RDL=6 ug

Hexachlorobutadiene 2010/08/10 ND, RDL=6 ug

Hexachlorocyclopentadiene 2010/08/10 ND, RDL=6 ug

Hexachloroethane 2010/08/10 ND, RDL=6 ug

Indeno(1,2,3-cd)pyrene 2010/08/10 ND, RDL=2 ug

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 26 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2194806 JIW Method Blank Isophorone 2010/08/10 ND, RDL=10 ug

Naphthalene 2010/08/10 ND, RDL=2 ug

Nitrobenzene 2010/08/10 ND, RDL=6 ug

N-Nitrosodimethylamine 2010/08/10 ND, RDL=30 ug

N-Nitroso-di-n-propylamine 2010/08/10 ND, RDL=6 ug

N-Nitrosodiphenylamine 2010/08/10 ND, RDL=6 ug

Pentachlorophenol 2010/08/10 ND, RDL=9 ug

Phenanthrene 2010/08/10 ND, RDL=1 ug

Phenol 2010/08/10 ND, RDL=5 ug

Pyrene 2010/08/10 ND, RDL=2 ug

2194814 WZ Spiked Blank D10-2-Methylnaphthalene 2010/08/09 80 % 50 - 150

Spiked Blank DUP D10-2-Methylnaphthalene 2010/08/09 64 % 50 - 150

Spiked Blank D10-Fluoranthene 2010/08/09 100 % 50 - 150

Spiked Blank DUP D10-Fluoranthene 2010/08/09 82 % 50 - 150

Spiked Blank D10-Phenanthrene 2010/08/09 88 % 50 - 150

Spiked Blank DUP D10-Phenanthrene 2010/08/09 80 % 50 - 150

Spiked Blank D12-Benzo(a)anthracene 2010/08/09 106 % 50 - 150

Spiked Blank DUP D12-Benzo(a)anthracene 2010/08/09 88 % 50 - 150

Spiked Blank D12-Benzo(a)pyrene 2010/08/09 92 % 50 - 150

Spiked Blank DUP D12-Benzo(a)pyrene 2010/08/09 70 % 50 - 150

Spiked Blank D12-Benzo(b)fluoranthene 2010/08/09 100 % 50 - 150

Spiked Blank DUP D12-Benzo(b)fluoranthene 2010/08/09 76 % 50 - 150

Spiked Blank D12-Benzo(ghi)perylene 2010/08/09 104 % 50 - 150

Spiked Blank DUP D12-Benzo(ghi)perylene 2010/08/09 86 % 50 - 150

Spiked Blank D12-Benzo(k)fluoranthene 2010/08/09 108 % 50 - 150

Spiked Blank DUP D12-Benzo(k)fluoranthene 2010/08/09 98 % 50 - 150

Spiked Blank D12-Chrysene 2010/08/09 116 % 50 - 150

Spiked Blank DUP D12-Chrysene 2010/08/09 98 % 50 - 150

Spiked Blank D12-Indeno(1,2,3-cd)pyrene 2010/08/09 102 % 50 - 150

Spiked Blank DUP D12-Indeno(1,2,3-cd)pyrene 2010/08/09 86 % 50 - 150

Spiked Blank D12-Perylene 2010/08/09 98 % 50 - 150

Spiked Blank DUP D12-Perylene 2010/08/09 76 % 50 - 150

Spiked Blank D14-Dibenzo(a,h)anthracene 2010/08/09 94 % 50 - 150

Spiked Blank DUP D14-Dibenzo(a,h)anthracene 2010/08/09 78 % 50 - 150

Spiked Blank D8-Acenaphthylene 2010/08/09 100 % 50 - 150

Spiked Blank DUP D8-Acenaphthylene 2010/08/09 82 % 50 - 150

Spiked Blank D8-Naphthalene 2010/08/09 92 % 50 - 150

Spiked Blank DUP D8-Naphthalene 2010/08/09 74 % 50 - 150

Spiked Blank Acenaphthene 2010/08/09 89 % 60 - 130

Spiked Blank DUP Acenaphthene 2010/08/09 71 % 60 - 130

RPD Acenaphthene 2010/08/09 22.2 % 50

Spiked Blank Acenaphthylene 2010/08/09 100 % 60 - 130

Spiked Blank DUP Acenaphthylene 2010/08/09 80 % 60 - 130

RPD Acenaphthylene 2010/08/09 21.7 % 50

Spiked Blank Anthracene 2010/08/09 87 % 60 - 130

Spiked Blank DUP Anthracene 2010/08/09 65 % 60 - 130

RPD Anthracene 2010/08/09 28.7 % 50

Spiked Blank Benzo(a)anthracene 2010/08/09 89 % 60 - 130

Spiked Blank DUP Benzo(a)anthracene 2010/08/09 73 % 60 - 130

RPD Benzo(a)anthracene 2010/08/09 19.5 % 50

Spiked Blank Benzo(a)pyrene 2010/08/09 81 % 60 - 130

Spiked Blank DUP Benzo(a)pyrene 2010/08/09 60 % 60 - 130

RPD Benzo(a)pyrene 2010/08/09 28.8 % 50

Spiked Blank Benzo(b)fluoranthene 2010/08/09 75 % 60 - 130

Spiked Blank DUP Benzo(b)fluoranthene 2010/08/09 64 % 60 - 130

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 27 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2194814 WZ RPD Benzo(b)fluoranthene 2010/08/09 16.5 % 50

Spiked Blank Benzo(k)fluoranthene 2010/08/09 111 % 60 - 130

Spiked Blank DUP Benzo(k)fluoranthene 2010/08/09 94 % 60 - 130

RPD Benzo(k)fluoranthene 2010/08/09 16.7 % 50

Spiked Blank Chrysene 2010/08/09 113 % 60 - 130

Spiked Blank DUP Chrysene 2010/08/09 96 % 60 - 130

RPD Chrysene 2010/08/09 16.1 % 50

Spiked Blank Dibenz(a,h)anthracene 2010/08/09 92 % 60 - 130

Spiked Blank DUP Dibenz(a,h)anthracene 2010/08/09 75 % 60 - 130

RPD Dibenz(a,h)anthracene 2010/08/09 20.2 % 50

Spiked Blank Fluoranthene 2010/08/09 95 % 60 - 130

Spiked Blank DUP Fluoranthene 2010/08/09 79 % 60 - 130

RPD Fluoranthene 2010/08/09 18.5 % 50

Spiked Blank Fluorene 2010/08/09 87 % 60 - 130

Spiked Blank DUP Fluorene 2010/08/09 70 % 60 - 130

RPD Fluorene 2010/08/09 22.3 % 50

Spiked Blank Indeno(1,2,3-cd)pyrene 2010/08/09 88 % 60 - 130

Spiked Blank DUP Indeno(1,2,3-cd)pyrene 2010/08/09 75 % 60 - 130

RPD Indeno(1,2,3-cd)pyrene 2010/08/09 16.6 % 50

Spiked Blank Naphthalene 2010/08/09 94 % 60 - 130

Spiked Blank DUP Naphthalene 2010/08/09 69 % 60 - 130

RPD Naphthalene 2010/08/09 30.2 % 50

Spiked Blank Phenanthrene 2010/08/09 77 % 60 - 130

Spiked Blank DUP Phenanthrene 2010/08/09 62 % 60 - 130

RPD Phenanthrene 2010/08/09 21.5 % 50

Spiked Blank Pyrene 2010/08/09 88 % 60 - 130

Spiked Blank DUP Pyrene 2010/08/09 74 % 60 - 130

RPD Pyrene 2010/08/09 17.3 % 50

Method Blank D10-2-Methylnaphthalene 2010/08/09 78 % 50 - 150

D10-Fluoranthene 2010/08/09 82 % 50 - 150

D10-Phenanthrene 2010/08/09 82 % 50 - 150

D12-Benzo(a)anthracene 2010/08/09 80 % 50 - 150

D12-Benzo(a)pyrene 2010/08/09 84 % 50 - 150

D12-Benzo(b)fluoranthene 2010/08/09 80 % 50 - 150

D12-Benzo(ghi)perylene 2010/08/09 86 % 50 - 150

D12-Benzo(k)fluoranthene 2010/08/09 104 % 50 - 150

D12-Chrysene 2010/08/09 124 % 50 - 150

D12-Indeno(1,2,3-cd)pyrene 2010/08/09 84 % 50 - 150

D12-Perylene 2010/08/09 94 % 50 - 150

D14-Dibenzo(a,h)anthracene 2010/08/09 76 % 50 - 150

D8-Acenaphthylene 2010/08/09 94 % 50 - 150

D8-Naphthalene 2010/08/09 88 % 50 - 150

1-Methylnaphthalene 2010/08/09 ND, RDL=0.30 ug

1-Methylphenanthrene 2010/08/09 ND, RDL=0.30 ug

2-Chloronaphthalene 2010/08/09 ND, RDL=0.30 ug

2-Methylanthracene 2010/08/09 ND, RDL=0.30 ug

2-Methylnaphthalene 2010/08/09 ND, RDL=0.15 ug

3-Methylcholanthrene 2010/08/09 ND, RDL=0.60 ug

7,12-Dimethylbenzo(a)anthracene 2010/08/09 ND, RDL=0.60 ug

9,10-Dimethylanthracene 2010/08/09 ND, RDL=0.60 ug

Acenaphthene 2010/08/09 ND, RDL=0.15 ug

Acenaphthylene 2010/08/09 ND, RDL=0.15 ug

Anthracene 2010/08/09 ND, RDL=0.15 ug

Benzo(a)anthracene 2010/08/09 ND, RDL=0.15 ug

Benzo(a)fluorene 2010/08/09 ND, RDL=0.60 ug

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 28 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2194814 WZ Method Blank Benzo(a)pyrene 2010/08/09 ND, RDL=0.15 ug

Benzo(b)fluoranthene 2010/08/09 ND, RDL=0.15 ug

Benzo(b)fluorene 2010/08/09 ND, RDL=0.30 ug

Benzo(e)pyrene 2010/08/09 ND, RDL=0.30 ug

Benzo(k)fluoranthene 2010/08/09 ND, RDL=0.15 ug

Biphenyl 2010/08/09 ND, RDL=0.30 ug

Chrysene 2010/08/09 ND, RDL=0.15 ug

Coronene 2010/08/09 ND, RDL=0.60 ug

Dibenz(a,h)anthracene 2010/08/09 ND, RDL=0.15 ug

Dibenzo(a,e)pyrene 2010/08/09 ND, RDL=0.60 ug

Fluoranthene 2010/08/09 ND, RDL=0.15 ug

Fluorene 2010/08/09 ND, RDL=0.15 ug

Indeno(1,2,3-cd)pyrene 2010/08/09 ND, RDL=0.15 ug

m-Terphenyl 2010/08/09 ND, RDL=0.30 ug

Naphthalene 2010/08/09 ND, RDL=0.30 ug

o-Terphenyl 2010/08/09 ND, RDL=0.30 ug

Perylene 2010/08/09 ND, RDL=0.60 ug

Phenanthrene 2010/08/09 ND, RDL=0.15 ug

p-Terphenyl 2010/08/09 ND, RDL=0.30 ug

Pyrene 2010/08/09 ND, RDL=0.15 ug

Quinoline 2010/08/09 ND, RDL=0.60 ug

Tetralin 2010/08/09 ND, RDL=0.30 ug

2198767 WZ Spiked Blank D10-2-Methylnaphthalene 2010/08/10 60 % 50 - 150

Spiked Blank DUP D10-2-Methylnaphthalene 2010/08/10 60 % 50 - 150

Spiked Blank D10-Fluoranthene 2010/08/10 70 % 50 - 150

Spiked Blank DUP D10-Fluoranthene 2010/08/10 72 % 50 - 150

Spiked Blank D10-Phenanthrene 2010/08/10 78 % 50 - 150

Spiked Blank DUP D10-Phenanthrene 2010/08/10 78 % 50 - 150

Spiked Blank D12-Benzo(a)anthracene 2010/08/10 120 % 50 - 150

Spiked Blank DUP D12-Benzo(a)anthracene 2010/08/10 116 % 50 - 150

Spiked Blank D12-Benzo(a)pyrene 2010/08/10 86 % 50 - 150

Spiked Blank DUP D12-Benzo(a)pyrene 2010/08/10 86 % 50 - 150

Spiked Blank D12-Benzo(b)fluoranthene 2010/08/10 94 % 50 - 150

Spiked Blank DUP D12-Benzo(b)fluoranthene 2010/08/10 90 % 50 - 150

Spiked Blank D12-Benzo(ghi)perylene 2010/08/10 88 % 50 - 150

Spiked Blank DUP D12-Benzo(ghi)perylene 2010/08/10 90 % 50 - 150

Spiked Blank D12-Benzo(k)fluoranthene 2010/08/10 90 % 50 - 150

Spiked Blank DUP D12-Benzo(k)fluoranthene 2010/08/10 88 % 50 - 150

Spiked Blank D12-Chrysene 2010/08/10 96 % 50 - 150

Spiked Blank DUP D12-Chrysene 2010/08/10 96 % 50 - 150

Spiked Blank D12-Indeno(1,2,3-cd)pyrene 2010/08/10 92 % 50 - 150

Spiked Blank DUP D12-Indeno(1,2,3-cd)pyrene 2010/08/10 92 % 50 - 150

Spiked Blank D12-Perylene 2010/08/10 84 % 50 - 150

Spiked Blank DUP D12-Perylene 2010/08/10 82 % 50 - 150

Spiked Blank D14-Dibenzo(a,h)anthracene 2010/08/10 84 % 50 - 150

Spiked Blank DUP D14-Dibenzo(a,h)anthracene 2010/08/10 86 % 50 - 150

Spiked Blank D8-Acenaphthylene 2010/08/10 106 % 50 - 150

Spiked Blank DUP D8-Acenaphthylene 2010/08/10 106 % 50 - 150

Spiked Blank D8-Naphthalene 2010/08/10 70 % 50 - 150

Spiked Blank DUP D8-Naphthalene 2010/08/10 68 % 50 - 150

Spiked Blank Acenaphthene 2010/08/10 82 % 60 - 130

Spiked Blank DUP Acenaphthene 2010/08/10 84 % 60 - 130

RPD Acenaphthene 2010/08/10 2.4 % 50

Spiked Blank Acenaphthylene 2010/08/10 106 % 60 - 130

Spiked Blank DUP Acenaphthylene 2010/08/10 110 % 60 - 130

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 29 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2198767 WZ RPD Acenaphthylene 2010/08/10 3.7 % 50

Spiked Blank Anthracene 2010/08/10 75 % 60 - 130

Spiked Blank DUP Anthracene 2010/08/10 80 % 60 - 130

RPD Anthracene 2010/08/10 6.5 % 50

Spiked Blank Benzo(a)anthracene 2010/08/10 90 % 60 - 130

Spiked Blank DUP Benzo(a)anthracene 2010/08/10 92 % 60 - 130

RPD Benzo(a)anthracene 2010/08/10 2.5 % 50

Spiked Blank Benzo(a)pyrene 2010/08/10 72 % 60 - 130

Spiked Blank DUP Benzo(a)pyrene 2010/08/10 74 % 60 - 130

RPD Benzo(a)pyrene 2010/08/10 2.7 % 50

Spiked Blank Benzo(b)fluoranthene 2010/08/10 81 % 60 - 130

Spiked Blank DUP Benzo(b)fluoranthene 2010/08/10 82 % 60 - 130

RPD Benzo(b)fluoranthene 2010/08/10 0.9 % 50

Spiked Blank Benzo(k)fluoranthene 2010/08/10 81 % 60 - 130

Spiked Blank DUP Benzo(k)fluoranthene 2010/08/10 82 % 60 - 130

RPD Benzo(k)fluoranthene 2010/08/10 1.8 % 50

Spiked Blank Chrysene 2010/08/10 92 % 60 - 130

Spiked Blank DUP Chrysene 2010/08/10 96 % 60 - 130

RPD Chrysene 2010/08/10 3.7 % 50

Spiked Blank Dibenz(a,h)anthracene 2010/08/10 73 % 60 - 130

Spiked Blank DUP Dibenz(a,h)anthracene 2010/08/10 75 % 60 - 130

RPD Dibenz(a,h)anthracene 2010/08/10 2.7 % 50

Spiked Blank Fluoranthene 2010/08/10 68 % 60 - 130

Spiked Blank DUP Fluoranthene 2010/08/10 70 % 60 - 130

RPD Fluoranthene 2010/08/10 2.9 % 50

Spiked Blank Fluorene 2010/08/10 80 % 60 - 130

Spiked Blank DUP Fluorene 2010/08/10 81 % 60 - 130

RPD Fluorene 2010/08/10 2.2 % 50

Spiked Blank Indeno(1,2,3-cd)pyrene 2010/08/10 73 % 60 - 130

Spiked Blank DUP Indeno(1,2,3-cd)pyrene 2010/08/10 78 % 60 - 130

RPD Indeno(1,2,3-cd)pyrene 2010/08/10 6.6 % 50

Spiked Blank Naphthalene 2010/08/10 83 % 60 - 130

Spiked Blank DUP Naphthalene 2010/08/10 86 % 60 - 130

RPD Naphthalene 2010/08/10 3.6 % 50

Spiked Blank Phenanthrene 2010/08/10 72 % 60 - 130

Spiked Blank DUP Phenanthrene 2010/08/10 74 % 60 - 130

RPD Phenanthrene 2010/08/10 2.4 % 50

Spiked Blank Pyrene 2010/08/10 61 % 60 - 130

Spiked Blank DUP Pyrene 2010/08/10 64 % 60 - 130

RPD Pyrene 2010/08/10 4.8 % 50

Method Blank D10-2-Methylnaphthalene 2010/08/10 58 % 50 - 150

D10-Fluoranthene 2010/08/10 76 % 50 - 150

D10-Phenanthrene 2010/08/10 78 % 50 - 150

D12-Benzo(a)anthracene 2010/08/10 106 % 50 - 150

D12-Benzo(a)pyrene 2010/08/10 80 % 50 - 150

D12-Benzo(b)fluoranthene 2010/08/10 86 % 50 - 150

D12-Benzo(ghi)perylene 2010/08/10 82 % 50 - 150

D12-Benzo(k)fluoranthene 2010/08/10 76 % 50 - 150

D12-Chrysene 2010/08/10 82 % 50 - 150

D12-Indeno(1,2,3-cd)pyrene 2010/08/10 86 % 50 - 150

D12-Perylene 2010/08/10 74 % 50 - 150

D14-Dibenzo(a,h)anthracene 2010/08/10 82 % 50 - 150

D8-Acenaphthylene 2010/08/10 100 % 50 - 150

D8-Naphthalene 2010/08/10 64 % 50 - 150

1-Methylnaphthalene 2010/08/10 ND, RDL=0.30 ug

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 30 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2198767 WZ Method Blank 1-Methylphenanthrene 2010/08/10 ND, RDL=0.30 ug

2-Chloronaphthalene 2010/08/10 ND, RDL=0.30 ug

2-Methylanthracene 2010/08/10 ND, RDL=0.30 ug

2-Methylnaphthalene 2010/08/10 ND, RDL=0.15 ug

3-Methylcholanthrene 2010/08/10 ND, RDL=0.60 ug

7,12-Dimethylbenzo(a)anthracene 2010/08/10 ND, RDL=0.60 ug

9,10-Dimethylanthracene 2010/08/10 ND, RDL=0.60 ug

Acenaphthene 2010/08/10 ND, RDL=0.15 ug

Acenaphthylene 2010/08/10 ND, RDL=0.15 ug

Anthracene 2010/08/10 ND, RDL=0.15 ug

Benzo(a)anthracene 2010/08/10 ND, RDL=0.15 ug

Benzo(a)fluorene 2010/08/10 ND, RDL=0.60 ug

Benzo(a)pyrene 2010/08/10 ND, RDL=0.15 ug

Benzo(b)fluoranthene 2010/08/10 ND, RDL=0.15 ug

Benzo(b)fluorene 2010/08/10 ND, RDL=0.30 ug

Benzo(e)pyrene 2010/08/10 ND, RDL=0.30 ug

Benzo(k)fluoranthene 2010/08/10 ND, RDL=0.15 ug

Biphenyl 2010/08/10 ND, RDL=0.30 ug

Chrysene 2010/08/10 ND, RDL=0.15 ug

Coronene 2010/08/10 ND, RDL=0.60 ug

Dibenz(a,h)anthracene 2010/08/10 ND, RDL=0.15 ug

Dibenzo(a,e)pyrene 2010/08/10 ND, RDL=0.60 ug

Fluoranthene 2010/08/10 ND, RDL=0.15 ug

Fluorene 2010/08/10 ND, RDL=0.15 ug

Indeno(1,2,3-cd)pyrene 2010/08/10 ND, RDL=0.15 ug

m-Terphenyl 2010/08/10 ND, RDL=0.30 ug

Naphthalene 2010/08/10 ND, RDL=0.30 ug

o-Terphenyl 2010/08/10 ND, RDL=0.30 ug

Perylene 2010/08/10 ND, RDL=0.60 ug

Phenanthrene 2010/08/10 ND, RDL=0.15 ug

p-Terphenyl 2010/08/10 ND, RDL=0.30 ug

Pyrene 2010/08/10 ND, RDL=0.15 ug

Quinoline 2010/08/10 ND, RDL=0.60 ug

Tetralin 2010/08/10 ND, RDL=0.30 ug

2198768 JIW Spiked Blank 2,4,6-Tribromophenol 2010/08/11 92 % 24 - 121

Spiked Blank DUP 2,4,6-Tribromophenol 2010/08/11 92 % 24 - 121

Spiked Blank 2-Fluorobiphenyl 2010/08/11 70 % 30 - 115

Spiked Blank DUP 2-Fluorobiphenyl 2010/08/11 70 % 30 - 115

Spiked Blank 2-Fluorophenol 2010/08/11 90 % 30 - 130

Spiked Blank DUP 2-Fluorophenol 2010/08/11 94 % 30 - 130

Spiked Blank D5-Nitrobenzene 2010/08/11 93 % 23 - 120

Spiked Blank DUP D5-Nitrobenzene 2010/08/11 93 % 23 - 120

Spiked Blank D5-Phenol 2010/08/11 87 % 24 - 113

Spiked Blank DUP D5-Phenol 2010/08/11 92 % 24 - 113

Spiked Blank 1,2,4-Trichlorobenzene 2010/08/11 61 % 40 - 125

Spiked Blank DUP 1,2,4-Trichlorobenzene 2010/08/11 63 % 40 - 125

RPD 1,2,4-Trichlorobenzene 2010/08/11 3.9 % 50

Spiked Blank 1,4-Dichlorobenzene 2010/08/11 55 % 40 - 125

Spiked Blank DUP 1,4-Dichlorobenzene 2010/08/11 62 % 40 - 125

RPD 1,4-Dichlorobenzene 2010/08/11 10.9 % 50

Spiked Blank 2,4-Dinitrotoluene 2010/08/11 92 % 40 - 125

Spiked Blank DUP 2,4-Dinitrotoluene 2010/08/11 90 % 40 - 125

RPD 2,4-Dinitrotoluene 2010/08/11 2.1 % 50

Spiked Blank 2-Chlorophenol 2010/08/11 94 % 10 - 125

Spiked Blank DUP 2-Chlorophenol 2010/08/11 97 % 10 - 125

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 31 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2198768 JIW RPD 2-Chlorophenol 2010/08/11 2.5 % 50

Spiked Blank 4-Chloro-3-Methylphenol 2010/08/11 92 % 10 - 125

Spiked Blank DUP 4-Chloro-3-Methylphenol 2010/08/11 96 % 10 - 125

RPD 4-Chloro-3-Methylphenol 2010/08/11 3.8 % 50

Spiked Blank 4-Nitrophenol 2010/08/11 79 % 10 - 125

Spiked Blank DUP 4-Nitrophenol 2010/08/11 78 % 10 - 125

RPD 4-Nitrophenol 2010/08/11 1.0 % 50

Spiked Blank Acenaphthene 2010/08/11 87 % 40 - 125

Spiked Blank DUP Acenaphthene 2010/08/11 87 % 40 - 125

RPD Acenaphthene 2010/08/11 0.3 % 50

Spiked Blank N-Nitroso-di-n-propylamine 2010/08/11 105 % 40 - 125

Spiked Blank DUP N-Nitroso-di-n-propylamine 2010/08/11 107 % 40 - 125

RPD N-Nitroso-di-n-propylamine 2010/08/11 1.9 % 50

Spiked Blank Pentachlorophenol 2010/08/11 84 % 10 - 125

Spiked Blank DUP Pentachlorophenol 2010/08/11 88 % 10 - 125

RPD Pentachlorophenol 2010/08/11 3.7 % 50

Spiked Blank Phenol 2010/08/11 82 % 10 - 125

Spiked Blank DUP Phenol 2010/08/11 86 % 10 - 125

RPD Phenol 2010/08/11 4.6 % 50

Spiked Blank Pyrene 2010/08/11 102 % 40 - 125

Spiked Blank DUP Pyrene 2010/08/11 102 % 40 - 125

RPD Pyrene 2010/08/11 0.2 % 50

Method Blank 2,4,6-Tribromophenol 2010/08/11 80 % 24 - 121

2-Fluorobiphenyl 2010/08/11 80 % 30 - 115

2-Fluorophenol 2010/08/11 85 % 30 - 130

D5-Nitrobenzene 2010/08/11 83 % 23 - 120

D5-Phenol 2010/08/11 86 % 24 - 113

1,2,4-Trichlorobenzene 2010/08/11 ND, RDL=6 ug

1,2-Dichlorobenzene 2010/08/11 ND, RDL=6 ug

1,3-Dichlorobenzene 2010/08/11 ND, RDL=6 ug

1,4-Dichlorobenzene 2010/08/11 ND, RDL=6 ug

1-Chloronaphthalene 2010/08/11 ND, RDL=6 ug

1-Methylnaphthalene 2010/08/11 ND, RDL=9 ug

2,4,5-Trichlorophenol 2010/08/11 ND, RDL=6 ug

2,4,6-Trichlorophenol 2010/08/11 ND, RDL=5 ug

2,4-Dichlorophenol 2010/08/11 ND, RDL=4 ug

2,4-Dimethylphenol 2010/08/11 ND, RDL=6 ug

2,4-Dinitrophenol 2010/08/11 ND, RDL=10 ug

2,4-Dinitrotoluene 2010/08/11 ND, RDL=2 ug

2,6-Dinitrotoluene 2010/08/11 ND, RDL=3 ug

2-Chloronaphthalene 2010/08/11 ND, RDL=3 ug

2-Chlorophenol 2010/08/11 ND, RDL=8 ug

2-Methylnaphthalene 2010/08/11 ND, RDL=5 ug

2-Methylphenol 2010/08/11 ND, RDL=9 ug

2-Nitroaniline 2010/08/11 ND, RDL=20 ug

2-Nitrophenol 2010/08/11 ND, RDL=5 ug

3 & 4-methylphenol 2010/08/11 ND, RDL=10 ug

3,3'-Dichlorobenzidine 2010/08/11 ND, RDL=8 ug

3-Nitroaniline 2010/08/11 ND, RDL=20 ug

4,6-Dinitro-2-methylphenol 2010/08/11 ND, RDL=10 ug

4-Bromophenyl phenyl ether 2010/08/11 ND, RDL=2 ug

4-Chloro-3-Methylphenol 2010/08/11 ND, RDL=5 ug

4-Chloroaniline 2010/08/11 ND, RDL=20 ug

4-Chlorophenyl phenyl ether 2010/08/11 ND, RDL=3 ug

4-Nitroaniline 2010/08/11 ND, RDL=20 ug

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 32 of 33
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE-BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082851

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2198768 JIW Method Blank 4-Nitrophenol 2010/08/11 ND, RDL=10 ug

Acenaphthene 2010/08/11 ND, RDL=2 ug

Acenaphthylene 2010/08/11 ND, RDL=2 ug

Aniline 2010/08/11 ND, RDL=20 ug

Anthracene 2010/08/11 ND, RDL=1 ug

Benzidine 2010/08/11 ND, RDL=60 ug

Benzo(a)anthracene 2010/08/11 ND, RDL=1 ug

Benzo(a)pyrene 2010/08/11 ND, RDL=2 ug

Benzo(b)fluoranthene 2010/08/11 ND, RDL=1 ug

Benzo(g,h,i)perylene 2010/08/11 ND, RDL=1 ug

Benzo(k)fluoranthene 2010/08/11 ND, RDL=2 ug

Benzoic Acid 2010/08/11 ND, RDL=10 ug

Benzyl Alcohol 2010/08/11 ND, RDL=6 ug

Benzyl butyl phthalate 2010/08/11 ND, RDL=2 ug

Biphenyl 2010/08/11 ND, RDL=6 ug

Bis(2-chloroethoxy)methane 2010/08/11 ND, RDL=4 ug

Bis(2-chloroethyl)ether 2010/08/11 ND, RDL=5 ug

Bis(2-chloroisopropyl)ether 2010/08/11 ND, RDL=5 ug

Bis(2-ethylhexyl)phthalate 2010/08/11 ND, RDL=8 ug

Carbazole 2010/08/11 ND, RDL=20 ug

Chrysene 2010/08/11 ND, RDL=1 ug

Dibenz(a,h)anthracene 2010/08/11 ND, RDL=1 ug

Dibenzofuran 2010/08/11 ND, RDL=20 ug

Diethyl phthalate 2010/08/11 ND, RDL=3 ug

Dimethyl phthalate 2010/08/11 ND, RDL=3 ug

Di-N-butyl phthalate 2010/08/11 ND, RDL=3 ug

Di-N-octyl phthalate 2010/08/11 ND, RDL=3 ug

Fluoranthene 2010/08/11 ND, RDL=1 ug

Fluorene 2010/08/11 ND, RDL=1 ug

Hexachlorobenzene 2010/08/11 ND, RDL=6 ug

Hexachlorobutadiene 2010/08/11 ND, RDL=6 ug

Hexachlorocyclopentadiene 2010/08/11 ND, RDL=6 ug

Hexachloroethane 2010/08/11 ND, RDL=6 ug

Indeno(1,2,3-cd)pyrene 2010/08/11 ND, RDL=2 ug

Isophorone 2010/08/11 ND, RDL=10 ug

Naphthalene 2010/08/11 ND, RDL=2 ug

Nitrobenzene 2010/08/11 ND, RDL=6 ug

N-Nitrosodimethylamine 2010/08/11 ND, RDL=30 ug

N-Nitroso-di-n-propylamine 2010/08/11 ND, RDL=6 ug

N-Nitrosodiphenylamine 2010/08/11 ND, RDL=6 ug

Pentachlorophenol 2010/08/11 ND, RDL=9 ug

Phenanthrene 2010/08/11 ND, RDL=1 ug

Phenol 2010/08/11 ND, RDL=5 ug

Pyrene 2010/08/11 ND, RDL=2 ug

Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.

Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery.

Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.

Surrogate: A pure or isotopically labeled compound whose behavior mirrors the analytes of interest. Used to evaluate extraction efficiency.

Maxxam Analytics International Corporation o/a Maxxam Analytics Burlington:5555 North Service Road, Burlington, Ontario L7L 5H7 Telephone(905) 332-8788 Fax(905) 332-9169

Page 33 of 33
Your Project #: 10-3991.00 

Site: DTE- BELLE RIVER

Your C.O.C. #: N/A

Attention: James K. Sharp

BT Environmental Consulting

2615 Wolcott St.

Ferndale, MI

USA 48220

Report Date: 2010/07/07

CERTIFICATE OF ANALYSIS

MAXXAM JOB #: B082809

Received: 2010/06/24, 12:00

Sample Matrix: AIR

# Samples Received: 11

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

VOST Analysis (5041mod) 5 N/A 2010/06/28 BRL SOP-00302 EPA 5041mod(M0030) 

VOST Analysis (5041mod) 6 N/A 2010/06/29 BRL SOP-00302 EPA 5041mod(M0030) 

Sample Matrix: Water

# Samples Received: 10

Date Date Method

Analyses Quantity Extracted Analyzed Laboratory Method Reference

VOST Condensate (8260Cmod) 10 N/A 2010/07/06 BRL SOP-00305 EPA 8260Cmod(M0030)

* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.

Encryption Key

Please direct all questions regarding this Certificate of Analysis to your Project Manager.

LINA BARRETO, Project Manager

Email: Lina.Barreto@maxxamanalytics.com

Phone# (905) 817-5700

====================================================================

Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section

5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.

Total cover pages: 1

Page 1 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 0 8 G H 4 4 0 9 G H 4 4 1 0 G H 4 4 1 1

Sampling Date 2010/06/22 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A N/A

 U n i t s TRIP BLANK TRAIN RUN1-SET1-M0031 RDL RUN1-SET2-M0031 RDL QC Batch

-M0031 BLANK

-M0031

Dichlorodifluoromethane (FREON 12) ug ND ND ND 0.02 ND 0.2 2192425

Chloromethane ug ND 0.06 ND 0.02 0.3 0.2 2192425

Vinyl Chloride ug ND ND ND 0.01 ND 0.1 2192425

Bromomethane ug ND 0.18 0.12 0.02 ND 0.2 2192425

Chloroethane ug ND ND ND 0.009 ND 0.09 2192425

Trichlorofluoromethane (FREON 11) ug ND ND ND 0.01 ND 0.1 2192425

Acetone (2-Propanone) ug ND 0.09 0.06 0.05 ND 0.5 2192425

1,1-Dichloroethylene ug ND ND ND 0.01 ND 0.1 2192425

Iodomethane ug ND ND ND 0.02 ND 0.2 2192425

Carbon Disulfide ug ND ND ND 0.03 ND 0.3 2192425

Methylene Chloride(Dichloromethane) ug ND 0.15 0.02 0.02 ND 0.2 2192425

1,1-Dichloroethane ug ND ND ND 0.01 ND 0.1 2192425

trans-1,2-Dichloroethylene ug ND ND ND 0.01 ND 0.1 2192425

cis-1,2-Dichloroethylene ug ND ND ND 0.01 ND 0.1 2192425

Chloroform ug ND ND ND 0.01 ND 0.1 2192425

1,2-Dichloroethane ug ND ND ND 0.007 ND 0.07 2192425

Methyl Ethyl Ketone (2-Butanone) ug ND ND ND 0.04 ND 0.4 2192425

1,1,1-Trichloroethane ug ND ND ND 0.01 ND 0.1 2192425

Carbon Tetrachloride ug ND ND ND 0.02 ND 0.2 2192425

Benzene ug ND ND 0.012 0.009 ND 0.09 2192425

1,1,2-Trichloroethane ug ND ND ND 0.02 ND 0.2 2192425

1,2-Dichloropropane ug ND ND ND 0.01 ND 0.1 2192425

Trichloroethylene ug ND ND ND 0.01 ND 0.1 2192425

Dibromomethane ug ND ND ND 0.01 ND 0.1 2192425

Bromodichloromethane ug ND ND ND 0.01 ND 0.1 2192425

cis-1,3-Dichloropropene ug ND ND ND 0.01 ND 0.1 2192425

trans-1,3-Dichloropropene ug ND ND ND 0.007 ND 0.07 2192425

Dibromochloromethane ug ND ND ND 0.009 ND 0.09 2192425

Methyl Isobutyl Ketone ug ND ND ND 0.02 ND 0.2 2192425

Methyl Butyl Ketone (2-Hexanone) ug ND ND ND 0.03 ND 0.3 2192425

Toluene ug ND ND 0.01 0.01 ND 0.1 2192425

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 2 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 0 8 G H 4 4 0 9 G H 4 4 1 0 G H 4 4 1 1

Sampling Date 2010/06/22 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A N/A

 U n i t s TRIP BLANK TRAIN RUN1-SET1-M0031 RDL RUN1-SET2-M0031 RDL QC Batch

-M0031 BLANK

-M0031

Ethylene Dibromide ug ND ND ND 0.01 ND 0.1 2192425

Tetrachloroethylene ug ND ND ND 0.02 ND 0.2 2192425

Chlorobenzene ug ND ND ND 0.01 ND 0.1 2192425

1,1,1,2-Tetrachloroethane ug ND ND ND 0.01 ND 0.1 2192425

Ethylbenzene ug ND ND ND 0.01 ND 0.1 2192425

m / p-Xylene ug ND ND ND 0.02 ND 0.2 2192425

Styrene ug ND ND ND 0.01 ND 0.1 2192425

o-Xylene ug ND ND ND 0.02 ND 0.2 2192425

Bromoform ug ND ND ND 0.01 ND 0.1 2192425

1,1,2,2-Tetrachloroethane ug ND ND ND 0.01 ND 0.1 2192425

1,2,3-Trichloropropane ug ND ND ND 0.02 ND 0.2 2192425

1,3-Dichlorobenzene ug ND ND ND 0.02 ND 0.2 2192425

1,4-Dichlorobenzene ug ND ND ND 0.02 ND 0.2 2192425

1,2-Dichlorobenzene ug ND ND ND 0.02 ND 0.2 2192425

Surrogate Recovery (%)

Bromofluorobenzene % 84 90 103 81 2192425

D10-Ethylbenzene (FS) % 108 101 108 96 2192425

D4-1,2-Dichloroethane % 96 97 96 100 2192425

D8-Toluene % 101 99 85 98 2192425

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 3 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 1 2 G H 4 4 1 3 G H 4 4 1 4

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN1-SET3-M0031 RDL QC Batch RUN2-SET1-M0031 RUN2-SET2-M0031 RDL QC Batch

Dichlorodifluoromethane (FREON 12) ug ND 0.2 2192425 ND ND 0.4 2192993

Chloromethane ug ND 0.2 2192425 ND ND 0.3 2192993

Vinyl Chloride ug ND 0.1 2192425 ND ND 0.3 2192993

Bromomethane ug ND 0.2 2192425 ND ND 0.3 2192993

Chloroethane ug ND 0.09 2192425 ND ND 0.2 2192993

Trichlorofluoromethane (FREON 11) ug ND 0.1 2192425 ND ND 0.2 2192993

Acetone (2-Propanone) ug ND 0.5 2192425 ND ND 0.9 2192993

1,1-Dichloroethylene ug ND 0.1 2192425 ND ND 0.2 2192993

Iodomethane ug ND 0.2 2192425 ND ND 0.3 2192993

Carbon Disulfide ug ND 0.3 2192425 ND ND 0.5 2192993

Methylene Chloride(Dichloromethane) ug ND 0.2 2192425 ND ND 0.4 2192993

1,1-Dichloroethane ug ND 0.1 2192425 ND ND 0.2 2192993

trans-1,2-Dichloroethylene ug ND 0.1 2192425 ND ND 0.2 2192993

cis-1,2-Dichloroethylene ug ND 0.1 2192425 ND ND 0.2 2192993

Chloroform ug ND 0.1 2192425 ND ND 0.2 2192993

1,2-Dichloroethane ug ND 0.07 2192425 ND ND 0.1 2192993

Methyl Ethyl Ketone (2-Butanone) ug ND 0.4 2192425 ND ND 0.7 2192993

1,1,1-Trichloroethane ug ND 0.1 2192425 ND ND 0.3 2192993

Carbon Tetrachloride ug ND 0.2 2192425 ND ND 0.3 2192993

Benzene ug ND 0.09 2192425 ND ND 0.2 2192993

1,1,2-Trichloroethane ug ND 0.2 2192425 ND ND 0.3 2192993

1,2-Dichloropropane ug ND 0.1 2192425 ND ND 0.2 2192993

Trichloroethylene ug ND 0.1 2192425 ND ND 0.2 2192993

Dibromomethane ug ND 0.1 2192425 ND ND 0.2 2192993

Bromodichloromethane ug ND 0.1 2192425 ND ND 0.2 2192993

cis-1,3-Dichloropropene ug ND 0.1 2192425 ND ND 0.2 2192993

trans-1,3-Dichloropropene ug ND 0.07 2192425 ND ND 0.1 2192993

Dibromochloromethane ug ND 0.09 2192425 ND ND 0.2 2192993

Methyl Isobutyl Ketone ug ND 0.2 2192425 ND ND 0.4 2192993

Methyl Butyl Ketone (2-Hexanone) ug ND 0.3 2192425 ND ND 0.6 2192993

Toluene ug ND 0.1 2192425 ND ND 0.3 2192993

Ethylene Dibromide ug ND 0.1 2192425 ND ND 0.2 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 4 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 1 2 G H 4 4 1 3 G H 4 4 1 4

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN1-SET3-M0031 RDL QC Batch RUN2-SET1-M0031 RUN2-SET2-M0031 RDL QC Batch

Tetrachloroethylene ug ND 0.2 2192425 ND ND 0.4 2192993

Chlorobenzene ug ND 0.1 2192425 ND ND 0.2 2192993

1,1,1,2-Tetrachloroethane ug ND 0.1 2192425 ND ND 0.2 2192993

Ethylbenzene ug ND 0.1 2192425 ND ND 0.3 2192993

m / p-Xylene ug ND 0.2 2192425 ND ND 0.3 2192993

Styrene ug ND 0.1 2192425 ND ND 0.2 2192993

o-Xylene ug ND 0.2 2192425 ND ND 0.3 2192993

Bromoform ug ND 0.1 2192425 ND ND 0.3 2192993

1,1,2,2-Tetrachloroethane ug ND 0.1 2192425 ND ND 0.3 2192993

1,2,3-Trichloropropane ug ND 0.2 2192425 ND ND 0.3 2192993

1,3-Dichlorobenzene ug ND 0.2 2192425 ND ND 0.4 2192993

1,4-Dichlorobenzene ug ND 0.2 2192425 ND ND 0.4 2192993

1,2-Dichlorobenzene ug ND 0.2 2192425 ND ND 0.4 2192993

Surrogate Recovery (%)

Bromofluorobenzene % 74 2192425 58 65 2192993

D10-Ethylbenzene (FS) % 91 2192425 84 87 2192993

D4-1,2-Dichloroethane % 87 2192425 83 90 2192993

D8-Toluene % 82 2192425 85 92 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 5 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 1 5 G H 4 4 1 6 G H 4 4 1 7

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN2-SET3-M0031 RDL RUN3-SET1-M0031 RUN3-SET2-M0031 RDL QC Batch

Dichlorodifluoromethane (FREON 12) ug ND 0.4 ND ND 0.2 2192993

Chloromethane ug ND 0.3 ND ND 0.2 2192993

Vinyl Chloride ug ND 0.3 ND ND 0.1 2192993

Bromomethane ug ND 0.3 ND ND 0.2 2192993

Chloroethane ug ND 0.2 ND ND 0.09 2192993

Trichlorofluoromethane (FREON 11) ug ND 0.2 ND ND 0.1 2192993

Acetone (2-Propanone) ug ND 0.9 ND ND 0.5 2192993

1,1-Dichloroethylene ug ND 0.2 ND ND 0.1 2192993

Iodomethane ug ND 0.3 ND ND 0.2 2192993

Carbon Disulfide ug ND 0.5 ND ND 0.3 2192993

Methylene Chloride(Dichloromethane) ug ND 0.4 0.9 ND 0.2 2192993

1,1-Dichloroethane ug ND 0.2 ND ND 0.1 2192993

trans-1,2-Dichloroethylene ug ND 0.2 ND ND 0.1 2192993

cis-1,2-Dichloroethylene ug ND 0.2 ND ND 0.1 2192993

Chloroform ug ND 0.2 ND ND 0.1 2192993

1,2-Dichloroethane ug ND 0.1 ND ND 0.07 2192993

Methyl Ethyl Ketone (2-Butanone) ug ND 0.7 ND ND 0.4 2192993

1,1,1-Trichloroethane ug ND 0.3 ND ND 0.1 2192993

Carbon Tetrachloride ug ND 0.3 ND ND 0.2 2192993

Benzene ug ND 0.2 ND ND 0.09 2192993

1,1,2-Trichloroethane ug ND 0.3 ND ND 0.2 2192993

1,2-Dichloropropane ug ND 0.2 ND ND 0.1 2192993

Trichloroethylene ug ND 0.2 ND ND 0.1 2192993

Dibromomethane ug ND 0.2 ND ND 0.1 2192993

Bromodichloromethane ug ND 0.2 ND ND 0.1 2192993

cis-1,3-Dichloropropene ug ND 0.2 ND ND 0.1 2192993

trans-1,3-Dichloropropene ug ND 0.1 ND ND 0.07 2192993

Dibromochloromethane ug ND 0.2 ND ND 0.09 2192993

Methyl Isobutyl Ketone ug ND 0.4 ND ND 0.2 2192993

Methyl Butyl Ketone (2-Hexanone) ug ND 0.6 ND ND 0.3 2192993

Toluene ug ND 0.3 ND ND 0.1 2192993

Ethylene Dibromide ug ND 0.2 ND ND 0.1 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 6 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 1 5 G H 4 4 1 6 G H 4 4 1 7

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN2-SET3-M0031 RDL RUN3-SET1-M0031 RUN3-SET2-M0031 RDL QC Batch

Tetrachloroethylene ug ND 0.4 ND ND 0.2 2192993

Chlorobenzene ug ND 0.2 ND ND 0.1 2192993

1,1,1,2-Tetrachloroethane ug ND 0.2 ND ND 0.1 2192993

Ethylbenzene ug ND 0.3 ND ND 0.1 2192993

m / p-Xylene ug ND 0.3 ND ND 0.2 2192993

Styrene ug ND 0.2 ND ND 0.1 2192993

o-Xylene ug ND 0.3 ND ND 0.2 2192993

Bromoform ug ND 0.3 ND ND 0.1 2192993

1,1,2,2-Tetrachloroethane ug ND 0.3 ND ND 0.1 2192993

1,2,3-Trichloropropane ug ND 0.3 ND ND 0.2 2192993

1,3-Dichlorobenzene ug ND 0.4 ND ND 0.2 2192993

1,4-Dichlorobenzene ug ND 0.4 ND ND 0.2 2192993

1,2-Dichlorobenzene ug ND 0.4 ND ND 0.2 2192993

Surrogate Recovery (%)

Bromofluorobenzene % 68 62 68 2192993

D10-Ethylbenzene (FS) % 86 87 79 2192993

D4-1,2-Dichloroethane % 97 98 96 2192993

D8-Toluene % 97 96 92 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 7 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 2 3

Sampling Date 2010/06/22

COC Number N/A

 U n i t s RUN3-SET3-M0031 RDL QC Batch

Dichlorodifluoromethane (FREON 12) ug ND 0.2 2192993

Chloromethane ug ND 0.2 2192993

Vinyl Chloride ug ND 0.1 2192993

Bromomethane ug ND 0.2 2192993

Chloroethane ug ND 0.09 2192993

Trichlorofluoromethane (FREON 11) ug ND 0.1 2192993

Acetone (2-Propanone) ug ND 0.5 2192993

1,1-Dichloroethylene ug ND 0.1 2192993

Iodomethane ug ND 0.2 2192993

Carbon Disulfide ug ND 0.3 2192993

Methylene Chloride(Dichloromethane) ug 0.2 0.2 2192993

1,1-Dichloroethane ug ND 0.1 2192993

trans-1,2-Dichloroethylene ug ND 0.1 2192993

cis-1,2-Dichloroethylene ug ND 0.1 2192993

Chloroform ug 0.1 0.1 2192993

1,2-Dichloroethane ug ND 0.07 2192993

Methyl Ethyl Ketone (2-Butanone) ug ND 0.4 2192993

1,1,1-Trichloroethane ug ND 0.1 2192993

Carbon Tetrachloride ug ND 0.2 2192993

Benzene ug ND 0.09 2192993

1,1,2-Trichloroethane ug ND 0.2 2192993

1,2-Dichloropropane ug ND 0.1 2192993

Trichloroethylene ug ND 0.1 2192993

Dibromomethane ug ND 0.1 2192993

Bromodichloromethane ug ND 0.1 2192993

cis-1,3-Dichloropropene ug ND 0.1 2192993

trans-1,3-Dichloropropene ug ND 0.07 2192993

Dibromochloromethane ug ND 0.09 2192993

Methyl Isobutyl Ketone ug ND 0.2 2192993

Methyl Butyl Ketone (2-Hexanone) ug ND 0.3 2192993

Toluene ug ND 0.1 2192993

Ethylene Dibromide ug ND 0.1 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 8 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (AIR)

Maxxam ID G H 4 4 2 3

Sampling Date 2010/06/22

COC Number N/A

 U n i t s RUN3-SET3-M0031 RDL QC Batch

Tetrachloroethylene ug ND 0.2 2192993

Chlorobenzene ug ND 0.1 2192993

1,1,1,2-Tetrachloroethane ug ND 0.1 2192993

Ethylbenzene ug ND 0.1 2192993

m / p-Xylene ug ND 0.2 2192993

Styrene ug ND 0.1 2192993

o-Xylene ug ND 0.2 2192993

Bromoform ug ND 0.1 2192993

1,1,2,2-Tetrachloroethane ug ND 0.1 2192993

1,2,3-Trichloropropane ug ND 0.2 2192993

1,3-Dichlorobenzene ug ND 0.2 2192993

1,4-Dichlorobenzene ug ND 0.2 2192993

1,2-Dichlorobenzene ug ND 0.2 2192993

Surrogate Recovery (%)

Bromofluorobenzene % 69 2192993

D10-Ethylbenzene (FS) % 77 2192993

D4-1,2-Dichloroethane % 94 2192993

D8-Toluene % 85 2192993

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 9 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 2 7 G H 4 4 2 8 G H 4 4 2 9

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s TRAIN RUN1 RUN1 RDL QC Batch

BLANK-M0031-COND SET1-M0031-COND SET2-M0031-COND

Dichlorodifluoromethane (FREON 12) ug/L ND ND ND 2.5 2193350

Chloromethane ug/L ND ND ND 5.0 2193350

Vinyl Chloride ug/L ND ND ND 1.0 2193350

Bromomethane ug/L ND ND ND 7.5 2193350

Chloroethane ug/L ND ND ND 2.5 2193350

Trichlorofluoromethane (FREON 11) ug/L ND ND ND 5.0 2193350

Acetone (2-Propanone) ug/L ND ND ND 25 2193350

1,1-Dichloroethylene ug/L ND ND ND 2.5 2193350

Iodomethane ug/L ND ND ND 1.5 2193350

Carbon Disulfide ug/L ND ND ND 1.3 2193350

Methylene Chloride(Dichloromethane) ug/L 24 26 25 2.5 2193350

1,1-Dichloroethane ug/L ND ND ND 1.0 2193350

trans-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

cis-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

Chloroform ug/L ND ND ND 1.0 2193350

1,2-Dichloroethane ug/L ND ND ND 1.3 2193350

Methyl Ethyl Ketone (2-Butanone) ug/L ND ND ND 25 2193350

1,1,1-Trichloroethane ug/L ND ND ND 1.3 2193350

Carbon Tetrachloride ug/L ND ND ND 1.3 2193350

Benzene ug/L ND ND ND 1.3 2193350

1,1,2-Trichloroethane ug/L ND ND ND 1.3 2193350

1,2-Dichloropropane ug/L ND ND ND 1.3 2193350

Trichloroethylene ug/L ND ND ND 1.3 2193350

Dibromomethane ug/L ND ND ND 1.3 2193350

Bromodichloromethane ug/L ND ND ND 1.0 2193350

cis-1,3-Dichloropropene ug/L ND ND ND 1.0 2193350

trans-1,3-Dichloropropene ug/L ND ND ND 1.5 2193350

Dibromochloromethane ug/L ND ND ND 1.0 2193350

Methyl Isobutyl Ketone ug/L ND ND ND 13 2193350

Methyl Butyl Ketone (2-Hexanone) ug/L ND ND ND 13 2193350

Toluene ug/L ND ND ND 1.3 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 10 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 2 7 G H 4 4 2 8 G H 4 4 2 9

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s TRAIN RUN1 RUN1 RDL QC Batch

BLANK-M0031-COND SET1-M0031-COND SET2-M0031-COND

Ethylene Dibromide ug/L ND ND ND 1.3 2193350

Tetrachloroethylene ug/L ND ND ND 1.3 2193350

Chlorobenzene ug/L ND ND ND 1.3 2193350

1,1,1,2-Tetrachloroethane ug/L ND ND ND 1.3 2193350

Ethylbenzene ug/L ND ND ND 1.3 2193350

p+m-Xylene ug/L ND ND ND 1.3 2193350

Styrene ug/L ND ND ND 1.3 2193350

o-Xylene ug/L ND ND ND 1.3 2193350

Bromoform ug/L ND ND ND 1.0 2193350

1,1,2,2-Tetrachloroethane ug/L ND ND ND 5.0 2193350

1,2,3-Trichloropropane ug/L ND ND ND 1.5 2193350

1,3-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,4-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,2-Dichlorobenzene ug/L ND ND ND 1.3 2193350

Surrogate Recovery (%)

4-Bromofluorobenzene % 95 93 95 2193350

D4-1,2-Dichloroethane % 92 90 93 2193350

D8-Toluene % 106 107 107 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 11 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 3 0 G H 4 4 3 1 G H 4 4 3 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN1 RUN2 RUN2 RDL QC Batch

SET3-M0031-COND SET1-M0031-COND SET2-M0031-COND

Dichlorodifluoromethane (FREON 12) ug/L ND ND ND 2.5 2193350

Chloromethane ug/L ND ND ND 5.0 2193350

Vinyl Chloride ug/L ND ND ND 1.0 2193350

Bromomethane ug/L ND ND ND 7.5 2193350

Chloroethane ug/L ND ND ND 2.5 2193350

Trichlorofluoromethane (FREON 11) ug/L ND ND ND 5.0 2193350

Acetone (2-Propanone) ug/L ND ND ND 25 2193350

1,1-Dichloroethylene ug/L ND ND ND 2.5 2193350

Iodomethane ug/L ND ND ND 1.5 2193350

Carbon Disulfide ug/L ND ND ND 1.3 2193350

Methylene Chloride(Dichloromethane) ug/L 23 21 20 2.5 2193350

1,1-Dichloroethane ug/L ND ND ND 1.0 2193350

trans-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

cis-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

Chloroform ug/L ND ND ND 1.0 2193350

1,2-Dichloroethane ug/L ND ND ND 1.3 2193350

Methyl Ethyl Ketone (2-Butanone) ug/L ND ND ND 25 2193350

1,1,1-Trichloroethane ug/L ND ND ND 1.3 2193350

Carbon Tetrachloride ug/L ND ND ND 1.3 2193350

Benzene ug/L ND ND ND 1.3 2193350

1,1,2-Trichloroethane ug/L ND ND ND 1.3 2193350

1,2-Dichloropropane ug/L ND ND ND 1.3 2193350

Trichloroethylene ug/L ND ND ND 1.3 2193350

Dibromomethane ug/L ND ND ND 1.3 2193350

Bromodichloromethane ug/L ND ND ND 1.0 2193350

cis-1,3-Dichloropropene ug/L ND ND ND 1.0 2193350

trans-1,3-Dichloropropene ug/L ND ND ND 1.5 2193350

Dibromochloromethane ug/L ND ND ND 1.0 2193350

Methyl Isobutyl Ketone ug/L ND ND ND 13 2193350

Methyl Butyl Ketone (2-Hexanone) ug/L ND ND ND 13 2193350

Toluene ug/L ND ND ND 1.3 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 12 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 3 0 G H 4 4 3 1 G H 4 4 3 2

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN1 RUN2 RUN2 RDL QC Batch

SET3-M0031-COND SET1-M0031-COND SET2-M0031-COND

Ethylene Dibromide ug/L ND ND ND 1.3 2193350

Tetrachloroethylene ug/L ND ND ND 1.3 2193350

Chlorobenzene ug/L ND ND ND 1.3 2193350

1,1,1,2-Tetrachloroethane ug/L ND ND ND 1.3 2193350

Ethylbenzene ug/L ND ND ND 1.3 2193350

p+m-Xylene ug/L ND ND ND 1.3 2193350

Styrene ug/L ND ND ND 1.3 2193350

o-Xylene ug/L ND ND ND 1.3 2193350

Bromoform ug/L ND ND ND 1.0 2193350

1,1,2,2-Tetrachloroethane ug/L ND ND ND 5.0 2193350

1,2,3-Trichloropropane ug/L ND ND ND 1.5 2193350

1,3-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,4-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,2-Dichlorobenzene ug/L ND ND ND 1.3 2193350

Surrogate Recovery (%)

4-Bromofluorobenzene % 94 94 94 2193350

D4-1,2-Dichloroethane % 90 91 92 2193350

D8-Toluene % 108 107 106 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 13 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 3 3 G H 4 4 7 5 G H 4 4 7 6

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN2 RUN3 RUN3 RDL QC Batch

SET3-M0031-COND SET1-M0031-COND SET2-M0031-COND

Dichlorodifluoromethane (FREON 12) ug/L ND ND ND 2.5 2193350

Chloromethane ug/L ND ND ND 5.0 2193350

Vinyl Chloride ug/L ND ND ND 1.0 2193350

Bromomethane ug/L ND ND ND 7.5 2193350

Chloroethane ug/L ND ND ND 2.5 2193350

Trichlorofluoromethane (FREON 11) ug/L ND ND ND 5.0 2193350

Acetone (2-Propanone) ug/L ND ND ND 25 2193350

1,1-Dichloroethylene ug/L ND ND ND 2.5 2193350

Iodomethane ug/L ND ND ND 1.5 2193350

Carbon Disulfide ug/L ND ND ND 1.3 2193350

Methylene Chloride(Dichloromethane) ug/L 14 4.6 58 2.5 2193350

1,1-Dichloroethane ug/L ND ND ND 1.0 2193350

trans-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

cis-1,2-Dichloroethylene ug/L ND ND ND 2.5 2193350

Chloroform ug/L 2.0 20 19 1.0 2193350

1,2-Dichloroethane ug/L ND ND ND 1.3 2193350

Methyl Ethyl Ketone (2-Butanone) ug/L ND ND ND 25 2193350

1,1,1-Trichloroethane ug/L ND ND ND 1.3 2193350

Carbon Tetrachloride ug/L ND ND ND 1.3 2193350

Benzene ug/L ND ND ND 1.3 2193350

1,1,2-Trichloroethane ug/L ND ND ND 1.3 2193350

1,2-Dichloropropane ug/L ND ND ND 1.3 2193350

Trichloroethylene ug/L ND ND ND 1.3 2193350

Dibromomethane ug/L ND ND ND 1.3 2193350

Bromodichloromethane ug/L ND ND ND 1.0 2193350

cis-1,3-Dichloropropene ug/L ND ND ND 1.0 2193350

trans-1,3-Dichloropropene ug/L ND ND ND 1.5 2193350

Dibromochloromethane ug/L ND ND ND 1.0 2193350

Methyl Isobutyl Ketone ug/L ND ND ND 13 2193350

Methyl Butyl Ketone (2-Hexanone) ug/L ND ND ND 13 2193350

Toluene ug/L ND 2.1 ND 1.3 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 14 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 3 3 G H 4 4 7 5 G H 4 4 7 6

Sampling Date 2010/06/22 2010/06/22 2010/06/22

COC Number N/A N/A N/A

 U n i t s RUN2 RUN3 RUN3 RDL QC Batch

SET3-M0031-COND SET1-M0031-COND SET2-M0031-COND

Ethylene Dibromide ug/L ND ND ND 1.3 2193350

Tetrachloroethylene ug/L ND ND ND 1.3 2193350

Chlorobenzene ug/L ND ND ND 1.3 2193350

1,1,1,2-Tetrachloroethane ug/L ND ND ND 1.3 2193350

Ethylbenzene ug/L ND ND ND 1.3 2193350

p+m-Xylene ug/L ND 1.8 ND 1.3 2193350

Styrene ug/L ND ND ND 1.3 2193350

o-Xylene ug/L ND ND ND 1.3 2193350

Bromoform ug/L ND ND ND 1.0 2193350

1,1,2,2-Tetrachloroethane ug/L ND ND ND 5.0 2193350

1,2,3-Trichloropropane ug/L ND ND ND 1.5 2193350

1,3-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,4-Dichlorobenzene ug/L ND ND ND 1.3 2193350

1,2-Dichlorobenzene ug/L ND ND ND 1.3 2193350

Surrogate Recovery (%)

4-Bromofluorobenzene % 95 94 95 2193350

D4-1,2-Dichloroethane % 93 92 94 2193350

D8-Toluene % 108 108 106 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 15 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 7 7

Sampling Date 2010/06/22

COC Number N/A

 U n i t s RUN3 RDL QC Batch

SET3-M0031-COND

Dichlorodifluoromethane (FREON 12) ug/L ND 2.5 2193350

Chloromethane ug/L ND 5.0 2193350

Vinyl Chloride ug/L ND 1.0 2193350

Bromomethane ug/L ND 7.5 2193350

Chloroethane ug/L ND 2.5 2193350

Trichlorofluoromethane (FREON 11) ug/L ND 5.0 2193350

Acetone (2-Propanone) ug/L ND 25 2193350

1,1-Dichloroethylene ug/L ND 2.5 2193350

Iodomethane ug/L ND 1.5 2193350

Carbon Disulfide ug/L ND 1.3 2193350

Methylene Chloride(Dichloromethane) ug/L 7.9 2.5 2193350

1,1-Dichloroethane ug/L ND 1.0 2193350

trans-1,2-Dichloroethylene ug/L ND 2.5 2193350

cis-1,2-Dichloroethylene ug/L ND 2.5 2193350

Chloroform ug/L 15 1.0 2193350

1,2-Dichloroethane ug/L ND 1.3 2193350

Methyl Ethyl Ketone (2-Butanone) ug/L ND 25 2193350

1,1,1-Trichloroethane ug/L ND 1.3 2193350

Carbon Tetrachloride ug/L ND 1.3 2193350

Benzene ug/L ND 1.3 2193350

1,1,2-Trichloroethane ug/L ND 1.3 2193350

1,2-Dichloropropane ug/L ND 1.3 2193350

Trichloroethylene ug/L ND 1.3 2193350

Dibromomethane ug/L ND 1.3 2193350

Bromodichloromethane ug/L ND 1.0 2193350

cis-1,3-Dichloropropene ug/L ND 1.0 2193350

trans-1,3-Dichloropropene ug/L ND 1.5 2193350

Dibromochloromethane ug/L ND 1.0 2193350

Methyl Isobutyl Ketone ug/L ND 13 2193350

Methyl Butyl Ketone (2-Hexanone) ug/L ND 13 2193350

Toluene ug/L ND 1.3 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 16 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

VOLATILE ORGANICS BY GC/MS (WATER)

Maxxam ID G H 4 4 7 7

Sampling Date 2010/06/22

COC Number N/A

 U n i t s RUN3 RDL QC Batch

SET3-M0031-COND

Ethylene Dibromide ug/L ND 1.3 2193350

Tetrachloroethylene ug/L ND 1.3 2193350

Chlorobenzene ug/L ND 1.3 2193350

1,1,1,2-Tetrachloroethane ug/L ND 1.3 2193350

Ethylbenzene ug/L ND 1.3 2193350

p+m-Xylene ug/L ND 1.3 2193350

Styrene ug/L ND 1.3 2193350

o-Xylene ug/L ND 1.3 2193350

Bromoform ug/L ND 1.0 2193350

1,1,2,2-Tetrachloroethane ug/L ND 5.0 2193350

1,2,3-Trichloropropane ug/L ND 1.5 2193350

1,3-Dichlorobenzene ug/L ND 1.3 2193350

1,4-Dichlorobenzene ug/L ND 1.3 2193350

1,2-Dichlorobenzene ug/L ND 1.3 2193350

Surrogate Recovery (%)

4-Bromofluorobenzene % 94 2193350

D4-1,2-Dichloroethane % 94 2193350

D8-Toluene % 107 2193350

ND = Not detected

N/A = Not Applicable

RDL = Reportable Detection Limit

QC Batch = Quality Control Batch

Page 17 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

Test Summary

Maxxam ID GH4408 Collected 2010/06/22

Sample ID TRIP BLANK -M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192425 N/A 2010/06/28 YYA

Maxxam ID GH4409 Collected 2010/06/22

Sample ID TRAIN BLANK -M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192425 N/A 2010/06/28 YYA

Maxxam ID GH4410 Collected 2010/06/22

Sample ID RUN1-SET1-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192425 N/A 2010/06/28 YYA

Maxxam ID GH4411 Collected 2010/06/22

Sample ID RUN1-SET2-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192425 N/A 2010/06/28 YYA

Maxxam ID GH4412 Collected 2010/06/22

Sample ID RUN1-SET3-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192425 N/A 2010/06/28 YYA

Maxxam ID GH4413 Collected 2010/06/22

Sample ID RUN2-SET1-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Maxxam ID GH4414 Collected 2010/06/22

Sample ID RUN2-SET2-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Page 18 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

Test Summary

Maxxam ID GH4415 Collected 2010/06/22

Sample ID RUN2-SET3-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Maxxam ID GH4416 Collected 2010/06/22

Sample ID RUN3-SET1-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Maxxam ID GH4417 Collected 2010/06/22

Sample ID RUN3-SET2-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Maxxam ID GH4423 Collected 2010/06/22

Sample ID RUN3-SET3-M0031 Shipped

Matrix AIR Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Analysis (5041mod) GC/MS 2192993 N/A 2010/06/29 YYA

Maxxam ID GH4427 Collected 2010/06/22

Sample ID TRAIN BLANK-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4428 Collected 2010/06/22

Sample ID RUN1 SET1-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4429 Collected 2010/06/22

Sample ID RUN1 SET2-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Page 19 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

Test Summary

Maxxam ID GH4430 Collected 2010/06/22

Sample ID RUN1 SET3-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4431 Collected 2010/06/22

Sample ID RUN2 SET1-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4432 Collected 2010/06/22

Sample ID RUN2 SET2-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4433 Collected 2010/06/22

Sample ID RUN2 SET3-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4475 Collected 2010/06/22

Sample ID RUN3 SET1-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4476 Collected 2010/06/22

Sample ID RUN3 SET2-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Maxxam ID GH4477 Collected 2010/06/22

Sample ID RUN3 SET3-M0031-COND Shipped

Matrix Water Received 2010/06/24

Test Description Instrumentation Batch Extracted Analyzed Analyst

VOST Condensate (8260Cmod) P&T/MS 2193350 N/A 2010/07/06 AH

Page 20 of 27
BT Environmental Consulting

Maxxam Job #: B082809 Client Project #: 10-3991.00

Report Date: 2010/07/07 Project name: DTE- BELLE RIVER

GENERAL COMMENTS

WS# 2192425

In continuing calibration std., iodomethane exceed the acceptance limit of 20%.

VOC Analysis: Due to high concentrations of target analytes and/or insufficient sample volumes, the samples required dilution. Detection limits

were adjusted accordingly.

Sample GH4411-01: Sample analyzed at 10X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4412-01: Sample analyzed at 10X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4413-01: Sample analyzed at 20X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4414-01: Sample analyzed at 20X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4415-01: Sample analyzed at 20X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4416-01: Sample analyzed at 10X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

D4-1,4-dichlorobenzene internal recovery exceed acceptance limit of 50-200%.

Sample GH4417-01: Sample analyzed at 10X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Sample GH4423-01: Sample analyzed at 10X dilution due to high concentration of non-target analytes. The DL's were adjusted accordingly.

Results relate only to the items tested.

Page 21 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2192425 YYA Spiked Blank Bromofluorobenzene 2010/06/28 104 % 36 - 141

D10-Ethylbenzene (FS) 2010/06/28 95 % 54 - 152

D4-1,2-Dichloroethane 2010/06/28 101 % 74 - 122

D8-Toluene 2010/06/28 99 % 80 - 114

Dichlorodifluoromethane (FREON 12) 2010/06/28 90 % 50 - 150

Chloromethane 2010/06/28 84 % 50 - 150

Vinyl Chloride 2010/06/28 99 % 50 - 150

Bromomethane 2010/06/28 91 % 50 - 150

Chloroethane 2010/06/28 88 % 50 - 150

Trichlorofluoromethane (FREON 11) 2010/06/28 83 % 50 - 150

Acetone (2-Propanone) 2010/06/28 58 % 50 - 150

1,1-Dichloroethylene 2010/06/28 94 % 50 - 150

Iodomethane 2010/06/28 63 % N/A

Carbon Disulfide 2010/06/28 102 % 50 - 150

Methylene Chloride(Dichloromethane) 2010/06/28 102 % 50 - 150

1,1-Dichloroethane 2010/06/28 101 % 50 - 150

trans-1,2-Dichloroethylene 2010/06/28 101 % 50 - 150

cis-1,2-Dichloroethylene 2010/06/28 98 % 50 - 150

Chloroform 2010/06/28 106 % 50 - 150

1,2-Dichloroethane 2010/06/28 99 % 50 - 150

Methyl Ethyl Ketone (2-Butanone) 2010/06/28 89 % 50 - 150

1,1,1-Trichloroethane 2010/06/28 102 % 50 - 150

Carbon Tetrachloride 2010/06/28 106 % 50 - 150

Benzene 2010/06/28 98 % 50 - 150

1,1,2-Trichloroethane 2010/06/28 101 % 50 - 150

1,2-Dichloropropane 2010/06/28 98 % 50 - 150

Trichloroethylene 2010/06/28 101 % 50 - 150

Dibromomethane 2010/06/28 102 % 50 - 150

Bromodichloromethane 2010/06/28 103 % 50 - 150

cis-1,3-Dichloropropene 2010/06/28 106 % 50 - 150

trans-1,3-Dichloropropene 2010/06/28 117 % 50 - 150

Dibromochloromethane 2010/06/28 107 % 50 - 150

Methyl Isobutyl Ketone 2010/06/28 113 % 50 - 150

Methyl Butyl Ketone (2-Hexanone) 2010/06/28 112 % 50 - 150

Toluene 2010/06/28 100 % 50 - 150

Ethylene Dibromide 2010/06/28 105 % 50 - 150

Tetrachloroethylene 2010/06/28 100 % 50 - 150

Chlorobenzene 2010/06/28 98 % 50 - 150

1,1,1,2-Tetrachloroethane 2010/06/28 100 % 50 - 150

Ethylbenzene 2010/06/28 100 % 50 - 150

m / p-Xylene 2010/06/28 102 % 50 - 150

Styrene 2010/06/28 98 % 50 - 150

o-Xylene 2010/06/28 100 % 50 - 150

Bromoform 2010/06/28 111 % 50 - 150

1,1,2,2-Tetrachloroethane 2010/06/28 107 % 50 - 150

1,2,3-Trichloropropane 2010/06/28 97 % 50 - 150

1,3-Dichlorobenzene 2010/06/28 101 % 50 - 150

1,4-Dichlorobenzene 2010/06/28 99 % 50 - 150

1,2-Dichlorobenzene 2010/06/28 100 % 50 - 150

Method Blank Bromofluorobenzene 2010/06/28 82 % 36 - 141

D10-Ethylbenzene (FS) 2010/06/28 78 % 54 - 152

D4-1,2-Dichloroethane 2010/06/28 104 % 74 - 122

D8-Toluene 2010/06/28 104 % 80 - 114

Dichlorodifluoromethane (FREON 12) 2010/06/28 ND, RDL=0.02 ug

Chloromethane 2010/06/28 ND, RDL=0.02 ug

Page 22 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2192425 YYA Method Blank Vinyl Chloride 2010/06/28 ND, RDL=0.01 ug

Bromomethane 2010/06/28 ND, RDL=0.02 ug

Chloroethane 2010/06/28 ND, RDL=0.009 ug

Trichlorofluoromethane (FREON 11) 2010/06/28 ND, RDL=0.01 ug

Acetone (2-Propanone) 2010/06/28 ND, RDL=0.05 ug

1,1-Dichloroethylene 2010/06/28 ND, RDL=0.01 ug

Iodomethane 2010/06/28 ND, RDL=0.02 ug

Carbon Disulfide 2010/06/28 ND, RDL=0.03 ug

Methylene Chloride(Dichloromethane) 2010/06/28 ND, RDL=0.02 ug

1,1-Dichloroethane 2010/06/28 ND, RDL=0.01 ug

trans-1,2-Dichloroethylene 2010/06/28 ND, RDL=0.01 ug

cis-1,2-Dichloroethylene 2010/06/28 ND, RDL=0.01 ug

Chloroform 2010/06/28 ND, RDL=0.01 ug

1,2-Dichloroethane 2010/06/28 ND, RDL=0.007 ug

Methyl Ethyl Ketone (2-Butanone) 2010/06/28 ND, RDL=0.04 ug

1,1,1-Trichloroethane 2010/06/28 ND, RDL=0.01 ug

Carbon Tetrachloride 2010/06/28 ND, RDL=0.02 ug

Benzene 2010/06/28 ND, RDL=0.009 ug

1,1,2-Trichloroethane 2010/06/28 ND, RDL=0.02 ug

1,2-Dichloropropane 2010/06/28 ND, RDL=0.01 ug

Trichloroethylene 2010/06/28 ND, RDL=0.01 ug

Dibromomethane 2010/06/28 ND, RDL=0.01 ug

Bromodichloromethane 2010/06/28 ND, RDL=0.01 ug

cis-1,3-Dichloropropene 2010/06/28 ND, RDL=0.01 ug

trans-1,3-Dichloropropene 2010/06/28 ND, RDL=0.007 ug

Dibromochloromethane 2010/06/28 ND, RDL=0.009 ug

Methyl Isobutyl Ketone 2010/06/28 ND, RDL=0.02 ug

Methyl Butyl Ketone (2-Hexanone) 2010/06/28 ND, RDL=0.03 ug

Toluene 2010/06/28 ND, RDL=0.01 ug

Ethylene Dibromide 2010/06/28 ND, RDL=0.01 ug

Tetrachloroethylene 2010/06/28 ND, RDL=0.02 ug

Chlorobenzene 2010/06/28 ND, RDL=0.01 ug

1,1,1,2-Tetrachloroethane 2010/06/28 ND, RDL=0.01 ug

Ethylbenzene 2010/06/28 ND, RDL=0.01 ug

m / p-Xylene 2010/06/28 ND, RDL=0.02 ug

Styrene 2010/06/28 ND, RDL=0.01 ug

o-Xylene 2010/06/28 ND, RDL=0.02 ug

Bromoform 2010/06/28 ND, RDL=0.01 ug

1,1,2,2-Tetrachloroethane 2010/06/28 ND, RDL=0.01 ug

1,2,3-Trichloropropane 2010/06/28 ND, RDL=0.02 ug

1,3-Dichlorobenzene 2010/06/28 ND, RDL=0.02 ug

1,4-Dichlorobenzene 2010/06/28 ND, RDL=0.02 ug

1,2-Dichlorobenzene 2010/06/28 ND, RDL=0.02 ug

2192993 YYA Spiked Blank Bromofluorobenzene 2010/06/29 108 % 36 - 141

D10-Ethylbenzene (FS) 2010/06/29 108 % 54 - 152

D4-1,2-Dichloroethane 2010/06/29 98 % 74 - 122

D8-Toluene 2010/06/29 100 % 80 - 114

Dichlorodifluoromethane (FREON 12) 2010/06/29 93 % 50 - 150

Chloromethane 2010/06/29 88 % 50 - 150

Vinyl Chloride 2010/06/29 99 % 50 - 150

Bromomethane 2010/06/29 101 % 50 - 150

Chloroethane 2010/06/29 87 % 50 - 150

Trichlorofluoromethane (FREON 11) 2010/06/29 84 % 50 - 150

Acetone (2-Propanone) 2010/06/29 61 % 50 - 150

1,1-Dichloroethylene 2010/06/29 89 % 50 - 150

Page 23 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2192993 YYA Spiked Blank Iodomethane 2010/06/29 66 % N/A

Carbon Disulfide 2010/06/29 95 % 50 - 150

Methylene Chloride(Dichloromethane) 2010/06/29 96 % 50 - 150

1,1-Dichloroethane 2010/06/29 95 % 50 - 150

trans-1,2-Dichloroethylene 2010/06/29 96 % 50 - 150

cis-1,2-Dichloroethylene 2010/06/29 94 % 50 - 150

Chloroform 2010/06/29 101 % 50 - 150

1,2-Dichloroethane 2010/06/29 94 % 50 - 150

Methyl Ethyl Ketone (2-Butanone) 2010/06/29 97 % 50 - 150

1,1,1-Trichloroethane 2010/06/29 98 % 50 - 150

Carbon Tetrachloride 2010/06/29 101 % 50 - 150

Benzene 2010/06/29 95 % 50 - 150

1,1,2-Trichloroethane 2010/06/29 99 % 50 - 150

1,2-Dichloropropane 2010/06/29 94 % 50 - 150

Trichloroethylene 2010/06/29 103 % 50 - 150

Dibromomethane 2010/06/29 103 % 50 - 150

Bromodichloromethane 2010/06/29 99 % 50 - 150

cis-1,3-Dichloropropene 2010/06/29 102 % 50 - 150

trans-1,3-Dichloropropene 2010/06/29 111 % 50 - 150

Dibromochloromethane 2010/06/29 106 % 50 - 150

Methyl Isobutyl Ketone 2010/06/29 129 % 50 - 150

Methyl Butyl Ketone (2-Hexanone) 2010/06/29 132 % 50 - 150

Toluene 2010/06/29 98 % 50 - 150

Ethylene Dibromide 2010/06/29 104 % 50 - 150

Tetrachloroethylene 2010/06/29 99 % 50 - 150

Chlorobenzene 2010/06/29 97 % 50 - 150

1,1,1,2-Tetrachloroethane 2010/06/29 97 % 50 - 150

Ethylbenzene 2010/06/29 97 % 50 - 150

m / p-Xylene 2010/06/29 105 % 50 - 150

Styrene 2010/06/29 100 % 50 - 150

o-Xylene 2010/06/29 101 % 50 - 150

Bromoform 2010/06/29 106 % 50 - 150

1,1,2,2-Tetrachloroethane 2010/06/29 96 % 50 - 150

1,2,3-Trichloropropane 2010/06/29 96 % 50 - 150

1,3-Dichlorobenzene 2010/06/29 100 % 50 - 150

1,4-Dichlorobenzene 2010/06/29 100 % 50 - 150

1,2-Dichlorobenzene 2010/06/29 102 % 50 - 150

Method Blank Bromofluorobenzene 2010/06/29 85 % 36 - 141

D10-Ethylbenzene (FS) 2010/06/29 99 % 54 - 152

D4-1,2-Dichloroethane 2010/06/29 98 % 74 - 122

D8-Toluene 2010/06/29 104 % 80 - 114

Dichlorodifluoromethane (FREON 12) 2010/06/29 ND, RDL=0.02 ug

Chloromethane 2010/06/29 ND, RDL=0.02 ug

Vinyl Chloride 2010/06/29 ND, RDL=0.01 ug

Bromomethane 2010/06/29 ND, RDL=0.02 ug

Chloroethane 2010/06/29 ND, RDL=0.009 ug

Trichlorofluoromethane (FREON 11) 2010/06/29 ND, RDL=0.01 ug

Acetone (2-Propanone) 2010/06/29 ND, RDL=0.05 ug

1,1-Dichloroethylene 2010/06/29 ND, RDL=0.01 ug

Iodomethane 2010/06/29 ND, RDL=0.02 ug

Carbon Disulfide 2010/06/29 ND, RDL=0.03 ug

Methylene Chloride(Dichloromethane) 2010/06/29 ND, RDL=0.02 ug

1,1-Dichloroethane 2010/06/29 ND, RDL=0.01 ug

trans-1,2-Dichloroethylene 2010/06/29 ND, RDL=0.01 ug

cis-1,2-Dichloroethylene 2010/06/29 ND, RDL=0.01 ug

Page 24 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2192993 YYA Method Blank Chloroform 2010/06/29 ND, RDL=0.01 ug

1,2-Dichloroethane 2010/06/29 ND, RDL=0.007 ug

Methyl Ethyl Ketone (2-Butanone) 2010/06/29 ND, RDL=0.04 ug

1,1,1-Trichloroethane 2010/06/29 ND, RDL=0.01 ug

Carbon Tetrachloride 2010/06/29 ND, RDL=0.02 ug

Benzene 2010/06/29 ND, RDL=0.009 ug

1,1,2-Trichloroethane 2010/06/29 ND, RDL=0.02 ug

1,2-Dichloropropane 2010/06/29 ND, RDL=0.01 ug

Trichloroethylene 2010/06/29 ND, RDL=0.01 ug

Dibromomethane 2010/06/29 ND, RDL=0.01 ug

Bromodichloromethane 2010/06/29 ND, RDL=0.01 ug

cis-1,3-Dichloropropene 2010/06/29 ND, RDL=0.01 ug

trans-1,3-Dichloropropene 2010/06/29 ND, RDL=0.007 ug

Dibromochloromethane 2010/06/29 ND, RDL=0.009 ug

Methyl Isobutyl Ketone 2010/06/29 ND, RDL=0.02 ug

Methyl Butyl Ketone (2-Hexanone) 2010/06/29 ND, RDL=0.03 ug

Toluene 2010/06/29 ND, RDL=0.01 ug

Ethylene Dibromide 2010/06/29 ND, RDL=0.01 ug

Tetrachloroethylene 2010/06/29 ND, RDL=0.02 ug

Chlorobenzene 2010/06/29 ND, RDL=0.01 ug

1,1,1,2-Tetrachloroethane 2010/06/29 ND, RDL=0.01 ug

Ethylbenzene 2010/06/29 ND, RDL=0.01 ug

m / p-Xylene 2010/06/29 ND, RDL=0.02 ug

Styrene 2010/06/29 ND, RDL=0.01 ug

o-Xylene 2010/06/29 ND, RDL=0.02 ug

Bromoform 2010/06/29 ND, RDL=0.01 ug

1,1,2,2-Tetrachloroethane 2010/06/29 ND, RDL=0.01 ug

1,2,3-Trichloropropane 2010/06/29 ND, RDL=0.02 ug

1,3-Dichlorobenzene 2010/06/29 ND, RDL=0.02 ug

1,4-Dichlorobenzene 2010/06/29 ND, RDL=0.02 ug

1,2-Dichlorobenzene 2010/06/29 ND, RDL=0.02 ug

2193350 AH Spiked Blank 4-Bromofluorobenzene 2010/07/06 97 % 76 - 120

D4-1,2-Dichloroethane 2010/07/06 91 % 67 - 122

D8-Toluene 2010/07/06 104 % 75 - 114

Dichlorodifluoromethane (FREON 12) 2010/07/06 107 % 60 - 140

Chloromethane 2010/07/06 106 % 60 - 140

Vinyl Chloride 2010/07/06 103 % 70 - 130

Bromomethane 2010/07/06 97 % 60 - 140

Chloroethane 2010/07/06 95 % 70 - 130

Trichlorofluoromethane (FREON 11) 2010/07/06 95 % 70 - 130

Acetone (2-Propanone) 2010/07/06 78 % 60 - 140

1,1-Dichloroethylene 2010/07/06 92 % 70 - 130

Iodomethane 2010/07/06 123 % N/A

Carbon Disulfide 2010/07/06 116 % N/A

Methylene Chloride(Dichloromethane) 2010/07/06 98 % 70 - 130

1,1-Dichloroethane 2010/07/06 95 % 70 - 130

trans-1,2-Dichloroethylene 2010/07/06 95 % 70 - 130

cis-1,2-Dichloroethylene 2010/07/06 92 % 70 - 130

Chloroform 2010/07/06 91 % 70 - 130

1,2-Dichloroethane 2010/07/06 89 % 70 - 130

Methyl Ethyl Ketone (2-Butanone) 2010/07/06 79 % 60 - 140

1,1,1-Trichloroethane 2010/07/06 98 % 70 - 130

Carbon Tetrachloride 2010/07/06 103 % 70 - 130

Benzene 2010/07/06 97 % 70 - 130

1,1,2-Trichloroethane 2010/07/06 84 % 70 - 130

Page 25 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2193350 AH Spiked Blank 1,2-Dichloropropane 2010/07/06 93 % 70 - 130

Trichloroethylene 2010/07/06 91 % 70 - 130

Dibromomethane 2010/07/06 84 % N/A

Bromodichloromethane 2010/07/06 88 % 70 - 130

cis-1,3-Dichloropropene 2010/07/06 94 % 70 - 130

trans-1,3-Dichloropropene 2010/07/06 72 % 70 - 130

Dibromochloromethane 2010/07/06 99 % 70 - 130

Methyl Isobutyl Ketone 2010/07/06 80 % 70 - 130

Methyl Butyl Ketone (2-Hexanone) 2010/07/06 83 % N/A

Toluene 2010/07/06 101 % 70 - 130

Ethylene Dibromide 2010/07/06 91 % 70 - 130

Tetrachloroethylene 2010/07/06 100 % 70 - 130

Chlorobenzene 2010/07/06 97 % 70 - 130

1,1,1,2-Tetrachloroethane 2010/07/06 94 % 70 - 130

Ethylbenzene 2010/07/06 102 % 70 - 130

p+m-Xylene 2010/07/06 103 % 70 - 130

Styrene 2010/07/06 105 % 70 - 130

o-Xylene 2010/07/06 98 % 70 - 130

Bromoform 2010/07/06 95 % 70 - 130

1,1,2,2-Tetrachloroethane 2010/07/06 79 % 70 - 130

1,2,3-Trichloropropane 2010/07/06 77 % N/A

1,3-Dichlorobenzene 2010/07/06 100 % 70 - 130

1,4-Dichlorobenzene 2010/07/06 98 % 70 - 130

1,2-Dichlorobenzene 2010/07/06 94 % 70 - 130

Method Blank 4-Bromofluorobenzene 2010/07/06 95 % 76 - 120

D4-1,2-Dichloroethane 2010/07/06 90 % 67 - 122

D8-Toluene 2010/07/06 106 % 75 - 114

Dichlorodifluoromethane (FREON 12) 2010/07/06 ND, RDL=1.0 ug/L

Chloromethane 2010/07/06 ND, RDL=2.0 ug/L

Vinyl Chloride 2010/07/06 ND, RDL=0.40 ug/L

Bromomethane 2010/07/06 ND, RDL=3.0 ug/L

Chloroethane 2010/07/06 ND, RDL=1.0 ug/L

Trichlorofluoromethane (FREON 11) 2010/07/06 ND, RDL=2.0 ug/L

Acetone (2-Propanone) 2010/07/06 ND, RDL=10 ug/L

1,1-Dichloroethylene 2010/07/06 ND, RDL=1.0 ug/L

Iodomethane 2010/07/06 ND, RDL=0.60 ug/L

Carbon Disulfide 2010/07/06 ND, RDL=0.50 ug/L

Methylene Chloride(Dichloromethane) 2010/07/06 ND, RDL=1.0 ug/L

1,1-Dichloroethane 2010/07/06 ND, RDL=0.40 ug/L

trans-1,2-Dichloroethylene 2010/07/06 ND, RDL=1.0 ug/L

cis-1,2-Dichloroethylene 2010/07/06 ND, RDL=1.0 ug/L

Chloroform 2010/07/06 ND, RDL=0.40 ug/L

1,2-Dichloroethane 2010/07/06 ND, RDL=0.50 ug/L

Methyl Ethyl Ketone (2-Butanone) 2010/07/06 ND, RDL=10 ug/L

1,1,1-Trichloroethane 2010/07/06 ND, RDL=0.50 ug/L

Carbon Tetrachloride 2010/07/06 ND, RDL=0.50 ug/L

Benzene 2010/07/06 ND, RDL=0.50 ug/L

1,1,2-Trichloroethane 2010/07/06 ND, RDL=0.50 ug/L

1,2-Dichloropropane 2010/07/06 ND, RDL=0.50 ug/L

Trichloroethylene 2010/07/06 ND, RDL=0.50 ug/L

Dibromomethane 2010/07/06 ND, RDL=0.50 ug/L

Bromodichloromethane 2010/07/06 ND, RDL=0.40 ug/L

cis-1,3-Dichloropropene 2010/07/06 ND, RDL=0.40 ug/L

trans-1,3-Dichloropropene 2010/07/06 ND, RDL=0.60 ug/L

Dibromochloromethane 2010/07/06 ND, RDL=0.40 ug/L

Page 26 of 27
BT Environmental Consulting

Attention: James K. Sharp 

Client Project #: 10-3991.00

P.O. #:

Project name: DTE- BELLE RIVER

Quality Assurance Report (Continued)

Maxxam Job Number: GB082809

QA/QC Date

Batch Analyzed

Num Init QC Type Parameter yyyy/mm/dd Value %Recovery Units QC Limits

2193350 AH Method Blank Methyl Isobutyl Ketone 2010/07/06 ND, RDL=5.0 ug/L

Methyl Butyl Ketone (2-Hexanone) 2010/07/06 ND, RDL=5.0 ug/L

Toluene 2010/07/06 ND, RDL=0.50 ug/L

Ethylene Dibromide 2010/07/06 ND, RDL=0.50 ug/L

Tetrachloroethylene 2010/07/06 ND, RDL=0.50 ug/L

Chlorobenzene 2010/07/06 ND, RDL=0.50 ug/L

1,1,1,2-Tetrachloroethane 2010/07/06 ND, RDL=0.50 ug/L

Ethylbenzene 2010/07/06 ND, RDL=0.50 ug/L

p+m-Xylene 2010/07/06 ND, RDL=0.50 ug/L

Styrene 2010/07/06 ND, RDL=0.50 ug/L

o-Xylene 2010/07/06 ND, RDL=0.50 ug/L

Bromoform 2010/07/06 ND, RDL=0.40 ug/L

1,1,2,2-Tetrachloroethane 2010/07/06 ND, RDL=2.0 ug/L

1,2,3-Trichloropropane 2010/07/06 ND, RDL=0.60 ug/L

1,3-Dichlorobenzene 2010/07/06 ND, RDL=0.50 ug/L

1,4-Dichlorobenzene 2010/07/06 ND, RDL=0.50 ug/L

1,2-Dichlorobenzene 2010/07/06 ND, RDL=0.50 ug/L

Spiked Blank: A blank matrix to which a known amount of the analyte has been added. Used to evaluate analyte recovery.

Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.

Surrogate: A pure or isotopically labeled compound whose behavior mirrors the analytes of interest. Used to evaluate extraction efficiency.

Page 27 of 27







Appendix E 

Example Calculations 
EXAMPLE CALCULATIONS

Method 1-4

Moisture Content

wc VKV 11 ⋅=

wsg VKV 22 ⋅=

Where: Vwc = volume of water vapor condensed in impingers at standard conditions (ft3

) 

 K1 = 0.04715 ft3

/g water 

 V1 = mass of water collected in impingers (g) 

Vwsg = volume of water vapor collected in silica gel at standard conditions (ft3

) 

K2 = 0.04715 ft3/g water 

V2 = mass of water collected by silica gel (g) 

Gas Volume Standardization

⎟

⎟

⎟

⎟

⎠

⎞

⎜

⎜

⎜

⎜

⎝

⎛ Δ

+

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛ =

m

b

std

std

mmstd T

H P

P

T YVV 6.13

Where: Vstd = volume of gas sampled at standard conditions 

Vm = volume of gas measured by dry gas meter (ft3

) 

 Ym = dry gas meter correction factor (dimensionless) 

 Tstd = standard temperature (o

R = 460 + oF) 

 Pstd = standard pressure (“Hg) 

 Pb = barometric pressure (“Hg) 

 ΔH = average orifice differential pressure (“H2O) 

 Tm = average meter temperature (o

R) 

Moisture Fraction

wc wsg std

wc wsg

ws VVV

VV

B

++

+ =

Where: Bws = exhaust gas moisture content 
Absolute Stack Gas Temperature, Ts (o

R)

s s 460 += tT

Where: ts = Measured stack gas temperature (o

F) 

Absolute Stack Gas Pressure, Ps (in. Hg)

⎟

⎠

⎞ ⎜

⎝

⎛ +=

6.13

stat

bars

P

PP

Where: Pbar = Barometric pressure at test site (in. Hg) 

 Pstat = Stack static pressure (in. Hg) 

Stack Gas Molecular Weight, Dry Basis (lb/lb mole)

M d = CO2 + O2 + 2 + CON )%(%28.0)(%32.0)(%44.0

Stack Gas Molecular Weight, Wet Basis (lb/lb mole)

⎟

⎠

⎞ ⎜

⎝

⎛ ⎟ +

⎠

⎞ ⎜

⎝

⎛ −= 100

18

100

1 ws ws

ds

BB MM

Stack Gas Velocity, Vs (fpm)

ss

s

s pp MP

T V ⎟ ΔPCK⎠

⎞ ⎜

⎝

⎛ = min

sec 60

Where: Kp = Pitot tube constant equal to 85.49 

).)((

).)(/(

sec 2OHinR

Hginmolelblbft

o

⋅

Cp = Pitot tube coefficient, dimensionless 

ΔP = The average square root of the velocity head of stack gas (in. H2O) 

Ms = Molecular weight of the stack gas, wet basis (lb/lb mole) 

Average Stack Gas Volumetric Flowrate, Qs (cfm)

ss ⋅= AVQ

Where: Vs = Stack gas velocity (fpm) 

A = Cross-sectional area of stack (ft2

) 
Standard Stack Gas Volumetric Flowrate, Qstd (scfm)

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛ = Hgin

P

T

R QQ s

s

o

sstd .92.29

530

Where: Ts = Absolute stack gas temperature (o

R) 

Ps = Absolute stack gas pressure (in. Hg) 

Dry Standard Stack Gas Volumetric Flowrate, Qstd,dry (dscfm)

( ) ,drystd std 1−= BQQ ws

Method 0010, 0011, 0031, 18, 25A, 10, 6C 

Concentration, C1 (lb/ft3, dry basis)

Vt

m C

000,600,453 1 =

Where: m = mass of pollutant (ug). 

Vt = total volume of gas sampled (ft3

). 

 453,600,000 = conversion factor, micrograms to pounds. 

Mass Emission Rate (lb/hr)

⎟

⎠

⎞ ⎜

⎝

⎛ = hr QC drystd

min Emission Rate ,1 60

Method 7E 

Analyzer Drift Correction

( ) ⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛

− −=

om

ma

o CC

C CCC

Where: C = Effluent gas concentration, dry basis (ppm or %). 

C = Average gas concentration indicated by gas analyzer, dry basis (ppm 

or %). 

= Average of initial and final system calibration bias check responses 

for the zero gas (ppm or %). 

Co
 = Actual concentration of the upscale calibration gas (ppm or %). Cma

= Average of initial and final system calibration bias check responses 

for the upscale calibration gas (ppm or %). 

Cm

Method 6C, 10 - Mass Flowrate (lb/hr)

⎟

⎠

⎞ ⎜

⎝

⎛

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛ = ft hr

m

g

lb

mg

g CQM drystd

min 60

31.35

1

6.453

1

000,1

1

3

3

,

Where: C = Pollutant concentration (mg/dscm) 

 MW = molecular weight lb/lb mol 

Emission Rate as lb/mmbtu

⎟

⎠

⎞ ⎜

⎝

⎛ = hrmmbt

M

M hrlb

mmbtulb /

/

/

Where: Mlb/hr = Pollutant Emission Rate (lb/hr) 

 Mmbtu/hr = million BTUs per hour 

ug/dscm

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛ = Vmstd

CC 31.35

2

Where: C = Pollutant Catch (ug) 

 35.31 = Ft^3 per m^3 

 Vmstd = Sample volume corrected to standard conditions (ft^3) 

 

Correction to 7% O2

⎟

⎟

⎠

⎞

⎜

⎜

⎝

⎛

−

− =

2

2

2%7 %9.20

%79.20

O

O

O MM

Where: M = Pollutant Emission Rate or Concentration 

 %O2 = Measured %O2 value for run 
Appendix F 

Production Data