# METHOD 321 TEST RESULTS FOR PORTLAND CEMENT MANUFACTURING

AUGUST 6, 2010

# Method 321 Test Results for HCl, ppmvd@7%O2

Company National Cement Capitol Cement Capitol Cement* Lafarge Ash Grove

Plant Ragland, A L San Antonio, TX San Antonio, TX Harleyville, SC Louisville, NE

Kiln PH/PC Wet PH/PC PH/PC PH or PC

Runs (ppmwet)

1 8.12 1.03 0.34 12.63 15.90

2 5.73 1.72 0.34 13.27 14.70

3 5.19 1.72 0.34 2.37 12.40

4 14.73 0.34 29.78

5 4.27 0.34 6.76

6 0.34 19.09

7

8

9

AVG 7.61 1.49 0.34 13.98 14.33

STDEV 4.23 0.40 0.00 9.64 1.78

Rank 8 3 1 10 11

*NOTES:

Capitol Cement, wet kiln

‐ Run results were ppmwet. To calculate HCl, ppmvd@7%O2, moisture and O2 c o

Capitol Cement, PH/PC kiln

‐ All runs were nondetects; detection limit was 0.2 ppmwet. To calculate HCl, p

Lone Star

‐ Kiln 1 & 2 exhausts through common stack

Holcim, Ste Genevieve

‐ Runs 1

‐ 3 reported as below detection limit.

# o

p Illinois Cement Alamo Cement Lone Sta r Lone Star* Holcim Holcim

La Salle, IL San Antonio, TX Pryor, OK Pryor, OK Ada, OK Devils Slide, UT

PH PH or PC Dry, kiln3 Dry, kiln 1&2 Wet PH/PC

18.48 0.54 12.96 18.50 1.66 2.81

14.49 0.66 11.55 16.10 1.34 4.11

14.33 0.78 10.12 16.50 1.25 2.73

1.36 0.25 20.30 7.59

1.54 0.25 23.60 8.22

1.46 0.27 11.90 5.44

8.61 0.46 15.07 17.03 1.42 5.15

7.98 0.23 5.50 1.29 0.22 2.36

9 2 13 15 4 7

ncentration were estimated.

pmvd@7%O2, moisture and O2 were estimated.

# Holcim* Lafarge Lafarge Lehigh Lehigh Lehigh

Ste Genevieve,MO Alpena, MI Ravena,NY Tehachapi, CA Leeds, AL Redding, CA

PH/PC Dry, K23 Wet, K1 PH/PC PH PH

0.23 32.99 26.2 5.24 9.14 

# 4.24

0.21 31.43 23.4 3.52 4.94 

# 2.29

0.23 27.91 29.1 1.36 4.57 

# 2.39

2.38 1.53 20.09 

# 42.05

4.14 1.13 24.16 

# 19.69

3.62 27.81 18.53

0.78

1.12

1.24

1.55 30.78 26.23 2.56 15.12 14.87

1.49 2.61 2.85 1.78 10.18 15.51

5 17 16 6 14 12n3HClTestResults,MajorSources,UsingM321PlantLocationKilnTypeTestDateMajor/areasource(perNEI)MillStatusRunHClppmwetmoisture%HClppmdryO2%actualHClppmdat7%O2NotesNationalCementRagland,ALPH/PC5/21/2002MajorOn15.4214.926.37108.12SandersEngineeringandAnalyticalServices,HydrogenChloride5/21/2002On23.7915.674.49105.73EmissionTestReport(V1),NationalCement,Koppers5/21/2002On33.4415.484.07105.19MainStack,RaglandAlabama,May21‐24,2002.5/24/2002Off110.8114.2912.61914.735/24/2002Off23.3116.453.9684.27CapitolCementSanAntonio,TXWet5/9/2002MajorNA10.60260.81101.03EmissionMonitoringInc,NESHAPApplicabilityTesting5/9/2002NA21.00261.35101.72atCapitolCementCo.,2002.5/9/2002NA31.00261.35101.72Alkalibypass5/9/2002NA10.20260.27100.34Allnondetect;detectionlimit0.2ppmvwet5/9/2002NA20.20260.27100.34MoistureandO2estimated5/9/2002NA30.20260.27100.34PH/PC5/10/2002On10.20260.27100.34Allnondetect;detectionlimit0.2ppmvwet5/10/2002On20.20260.27100.34MoistureandO2estimated5/10/2002On30.20260.27100.345/10/2002Off10.20260.27100.345/10/2002Off20.20260.27100.345/10/2002Off30.20260.27100.34LafargeHarleyville,SCPH/PC10/26/2004MajorOn17.73159.0910.8912.63O2conc.estimated10/26/2004On28.1914.39.5610.8913.27URS,ComplianceTestReport,LafargeBuildingMaterials,Inc10/26/2004On31.4415.61.7110.892.37Harleyville,SC,October25‐Nov.1,2004.10/25/2004Off124.4116.229.137.329.78O2conc.estimated11/1/2004Off25.5116.76.617.36.7611/1/2004Off315.5816.618.687.319.09AshGroveLouisville,NEPHorPC?5/25/2005Major115.90PrismAnalyticalTechnologies,Inc.,AshGroveCementCo,5/26/2005214.70Louisville,Nebraska,GaseousHydrogenChlorideTesting,5/26/2005312.40May25and26,2005.IllinoisCementLaSalle,ILPH1/8/2002Major*Off112.906.6913.8210.518.48Thecoverlettertothe2002reportstatestheyareanareasource.1/8/2002Off211.207.3712.099.314.49EmissionMonitoringInc,NESHAPApplicabilityTestingforthePortland1/8/2002Off312.407.4513.407.914.33CementNESHAP,IllinoisCementCo.,LaSalle,IL,February17,2002.1/9/2002On41.0010.571.129.51.361/9/2002On51.1011.551.249.71.541/9/2002On61.2011.451.3681.46AlamoCementSanAntonio,TXPH/PC4/10/2001MajorOff10.5017.990.615.30.54CleanAirEngineering,ReportonHydrogenChlorideTesting.Performed4/10/2001Off20.6018.920.745.30.66for:AlamoCementCo.KilnStack,SanAntonioCementPlant,May24,20014/10/2001Off30.7019.960.875.40.784/11/2001On10.2015.220.247.80.254/11/2001On20.2015.430.247.80.254/11/2001On30.2016.360.248.70.27LoneStarIndustriesIPryor,OKDry,kiln32/24/2010MajorNA17.804.98.2012.112.96Receivedon3/21/20102/24/2010NA26.504.66.8112.711.552/24/2010NA35.904.76.1912.410.12Dry,kiln1&29/28/1999NA118.50Kiln1&2exhaustthroughcommonstack9/28/1999NA216.109/28/1999NA316.50Dry,kiln39/30/1999NA120.309/30/1999NA223.609/30/1999NA311.90HolcimAda,OKWet3/12/2010MajorNA11.663/12/2010NA21.343/12/2010NA31.25HolcimDevilsSlide,UTPH/PC2/24/2010MajorOn12.812/24/2010On24.112/24/2010On32.732/25/2010Off17.592/25/2010Off28.222/25/2010Off35 4.4HolcimSteGenevieve,MOPH/PC2/14/2010MajorBothOn1[<0.23]belowdetectionlimit2/14/2010BothOn2[<0.21]belowdetectionlimit2/14/2010BothOn3[<0.23]belowdetectionlimit2/15/2010BothOff12.382/15/2010BothOff24.142/15/2010BothOff33.622/15/20101On/1Off10.782/15/20101On/1Off21.122/15/20101On/1Off31.24LafargeAlpena,MIDry,K233/25/2010MajorNA132.993/25/2010NA231.433/25/2010NA327.91LafargeRavena,NYWet,Kiln13/12/2010NA126.22kilnsexhaustto1stack;onekilnwasoperatingduringtesting;testsinkilnbreaching3/12/2010NA223.43/12/2010NA329.1LehighTehachapi,CAPH/PC3/25/2010MajorOn15.243/27/2010On23.523/27/2010On31.363/25/2010Off11.533/25/2010Off21.13LehighLeeds,ALPH3/17/2010MajorOn19.143/17/2010On24.943/17/2010On34.573/18/2010Off120.093/18/2010Off224.163/18/2010Off327.81LehighRedding,CAPH3/16/2010MajorOn14.243/16/2010On22.293/16/2010On32.393/17/2010Off142.053/17/2010Off219.693/17/2010Off318.53*Coverlettertotestreportsaystheyarenotmajor.NA=notapplicablend=nondetectableFebruary22,2010136123429______))6967StateContactPhone#PlantsLocationsM321testTestdate DatareceivedAlabamaScanlan,Katrina334‐271‐786334‐279‐3044(fax)CemexDemopolisYes?? Informationrequestsubmittedon12/30NationalCementRaglandYesMay‐02 Yes‐summaryFloridaLinero,Al850‐921‐952FLRockNewberryNo‐Notreq'dRinkerMaterialsBrooksvilleRinkerMiamiSuwanneeAmericanBranfordTitanAmericaMedleyIllinoisAsselmyer,David(Buzz) 217‐524‐763EagleMaterials(IllinoisCement) LaSalleYes‐Illinois,LaSalle2002 12/21/2009AreaSourcePilapil,Ray217‐782‐581St.Mary'sCementDixonnotestdataMissouriYronwode,Peter573‐526‐678BuzziUnicemFestus(Selma)No‐Notreq'dNewYorkDeSantis,Steve518‐402‐840St.LawrenceCatskillNotreq'd(willck)PennsylvaniaKohli,______717‐772‐397BuzziStockertownNoCemexWampumNoKeystoneNoGiantCementBathNo(M26Atestdone)TexasHamilton,Randy512‐239‐151CapitolAggregates(reg13) SanAntonioYes(majorsource)Requestingentire2002testreport______,Christine(Reg11)512‐339‐292Cemex(Reg13)NewBraunfelsM26AMcGrath,Carol(Reg13)210‐490‐309Cemex(Reg7)OdessaM26AMclean,Vickie(Reg7)432‐570‐135Texas‐Lehigh(Reg11)BudaM26Seiler,Jeffrey210‐490‐309AlamoCementSanAntonioYes(majorsource)Rec'd2/22/10Seiler,Jeffrey210‐490‐309TXIHunterYes(areasource)Rec'd2/22/110/09

# States Contacted Plant Location M321 HCl Data Major/Area

source

Alabama Cemex Demopolis ?

National Cement Ragland Yes Major

Florida Florida Roc k Newberry No

Rinker Brooksville No

Rinker Miami No

Suwannee Branford No

Titan Medley No

Illinois Eagle Materials (Illinois Cement) LaSalle Yes Major (Area based on 2002 tests)

St Mary's Cement Dixon No

Missouri Buzzi Unicem Festus (Selma) No

New York St Lawrence Catskill No

Pennsylvania Buzzi Unicem Stockertown No

Cemex Wampum No

Giant Bath No

Texas Capitol Aggregates San Antonio Yes (all nd) Major

Cemex New Braunfels No (M26)

Cemex Odessa No (M26)

Texas

‐ Lehigh Buda No (M26)

Alamo Cement San Antonio Yes Major

TXI Hunter Yes Area

Other

South Carolina Lafarge Harleyville Yes Major

Nebraska Ash Grove Louisville Yes Major