# TSUA NON-CONFIENTIAL BUSINESS INFORMATION DOCUMENT DESCRIPTION DOCUMENT CONTROL NUMBER DATE RECEIVED

-Q 

# la 

# -It--0 

# COMMENTS:DELS



# DO[CS NOT CONTAIN CBI

### ~ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON D.C., 20460 OFFICE OF 

### ~ $~R 

### ~CHEMICAL SAFETY AND POLLUTION PREVENTION 

# Notice of Change inCBI Chemical Identity Status Pre-Manufacture Notice (PMN) P-00-1121 Notice of commencement (NOC) received: 9113/2001 Please be advised thatthe Confidential 

## Business Information (CBI) claimforthe above referenced substance was dropped bythe information submitter inthe NOC. 

## The identified non-confidential chemical name for this substance as provided in the NOC is: MANGANESE STROTIUM OXIDE (MNSR03) The currentTSCA Inventory name is Manganese strontium oxide (MnSrO3) CASRN: 12163-45-0
This notice as submitted tothe NCIC files on 9/1/2011 Name of staffer: Jeffrey Santacroce Position: Asst. NOC Coordinator Branch: RDMB/IMD/OPPT/OCSPP 

# CONTAINS NO CB1SANITARY COPYDaofcp Form Opme. .11B No. 3 W~12- APPro-l14 s 1-1-6 US.ENVRONNMNTAL PROTECTON AGENCY 

## AGENCY USE ONLY

# MWEP NOTICE FOR NEW CHEMICAL SUBSTANCES DOCUMENT CONTROL OFFICERSaize SUBSTANCES, 7407 

## 0

# oMpal Sfltie ~. OFFICEOF POLLUTION PREVENTION AND 

### TOXIC BTNCS 70 U.S. E.P.A. 401M STREET, SW WASHINGTON, D.C. 20460
_______________________________, in the Premanufacture Notice : =:" 'do // /4 

## GENERAL INSTRUCMONS M11 [ -6114"N1

-You must provideamU Information mequested in tfam totheextent that i i known tooemamnably aseainable by you. Makereaonable estiate ifyou do not haveactual data.

. Before you completa this faust, youshould read &henAstartions Manual forPrensanufacture Notification (the Instructions Manual is available fromtheToxic Substanrm ot Act (TSCA) Informaton Serviceby callingZ22554..1404, orfaxing2-SW4S403) - Uf a userfoe hasbeen mittad forthis noticef40C1FR 700.45), indicate in theboxes above.theTS-uee far Idenification sumberyouhave generatd. Remember, youruserfee EDnumber mnua &tooappearonyourcorrsponding fee remittance. which isesentto: EPA, HOAccuntingOpeations Branch (PM.IM), P.O. 360399K,Pittsburgh,PA ISM-639, Afttn TSCA UserFee. PartI- GENERAL INFORMATION TMS DATA AND OTHERDATA You mustprovide the currently correc Chenlcal Abetracts (CA) Name ofthe You anmequiredto submit allteadata in yourpossession ormeoniuli newchemical substance, eoenfyou cila theIdentity anconfidestiaL.Yumay and Soprovideadesciption of allotherdate known toorsreaonably authorizeanother person tosubmit chemical Identityinformation toryan, but astinable by you, Uf thesedata am Meated tothehaltha&d your: submision willnot becomplete and thereview wllnot begin until EPA rnvrouenaefe ofthemanufacture, processm, diatibuttiom receives this information.A letterinsupportofyoursubmission should In cmmentn. Usk ordisposal ofthesaw Chemical substance. Slandeof refemence yourTS usesfee identification number.You mumt submit anoriginal litertue liaioea say beesubmliied fordataIn the open scietific and two copiesof this notieincluding all tes data. Ifyou claimed any litermure. CnnmiitekordatAtyrritten nEgih a s mr. fdt. Informsation ancoidautial asingle saniized copy meum also be submitted. fi- be asutiltad ifthey o at sofLea n hpe Iteatur you should cleerly identity whether testdata is on thesubstane oraen ananalog. Also, Pant U - HUMAN EXPOSURE AND ENVIRONMENTAL pR v"j the cemical compamiot ofthelaseed mateial should bechiudsd. Fa~oelug areexamiples oftat data and otherdata Datashould be Ifthereamnseveral manufacture. pnwmag oruse operationsto bedescribed In submitted accoding tothemquisaumes of9720M ofthe Prmuahum Pant ILsetions Aand l ofthissotice,raipsuduce thesections asueded. NetificationRule (40 CaxPAAt721L Purt IU - LISTOFATTACIMIENTS TeDat~sa (Clickt Belowany included in this notice) Allach additional sheetsit themis not enough space to answersa question fully. Label each continuation sheet with thecorreponding ascion heading. InPant Eswlronminta fatedata e te aa 

## I e 13Llistthese altachmenti, any testdataorother dataandanyoptional Hai fet aays Rs sasnrl information included inthenotice. 13elhefesdt OPTIONAL INFORMATION *Environmental decs data 13 Yes Staudtumuladlvity relationships You may include any Information th" you waste EPA to consideris evaluating *PbyskAI l~em~caPropertie**E yen Test datanot inthe posseio theniew substance. 0 page 12 ofthis form.space has bees provided foryou to orcontrol ofthesulamifter descibepoliltloopruventionandrecycling information you may have regarding Aphscladhe" rorts okbtisoaedntelstag ofthis fogn. So-called "blndlarbarnes amnincluded throughout thinfoam foryou to indicate TYPE OFN07TCE (nieck Only One) yourwillingness to be bound tocta"i tmentsYou maima in thsnotice, such asuse, production volume, protective equipment... Thisoptionis intended to reduce delays that routinely sccompany the developmsent ofcousent ordersor jJPNOeauau oie Significant New Use Rules.ExceptIn thecase ofexemption applications (auck as 1 M rmnfcueNtclC TWEA, LVE, LOREX) wherecertain information provided in such modification is 

# QINTERMEDIATE PMN (submitted insequence with final pmSZct binding on the aubmltterwhes the Agency approves the exemption application, PMN 

### -W checking abinding box in thisnotice do- rniL byItself prohibitthe submitter FM)C- C from later deviating from theInformation (except chemical identity) reported In SNN(infcatNwUeNoie 'T theform. 13 SNN SgnfcatNe seNtie 

## L3 7MEA fraut Marketing Exemption Application) CoN~lDFnA~rrycA~mL 

## 1 LVE (Low Voluame Exemption)040 CM 723j@ (c)9 You may claimany information inthis notice as confidential. To asserta clalm onthe forma, mark 00) the confidential box next to theinformation that you claim LORIX (Low ReleseILnw Expaosure Exemption)O 0 eW asconfidential. To aert aclaim in an attachment,circe orbracketthe LRXMdfct informiation you claim asconfidential. Ifyon ialim infnrmation Inthe antice, ag LVE Modification 1 L RE Mdfcton confidentixl-you muttr alga povide asa.nitized venins of the notice tnduding -arlahinent) Foradditional instructions en claiming Informatdons IS "VSACNOIATDPN 

## f e confidential, readtheInstructios Manual.IT SAO OLD EPM u Ye 

## M

Mark WX Ifayinformation in thisnotice isclaimed asconfidential. 9ofchemicalsanas( ProtcCmuiatn reiedetr9onpg) Realaces previous editions ofEPA Formi 7710-25.Publicreporting burdenfor this oluectionofInformationisestimatedtoaverage 110hoursper response- indludingtime forreviewing intfuctioMs searching existingdata source, gathering and maintainingthedata needed, andcompleting andreviewing thecollection ofinformetiML Send comments regarding theburden estimateor any otheraspectofthiscollection ofinformation including suggestions forreducing thisburden, toGilef,Information PolicyBranch.PM-rn3,U.S. Environmental ProtectionAgency, 401M.SL., S.W., Washington, D.C 20460, andtotheOffice of Manazenient and Buditet, Paperwork Reduction Act (2070-0012). Washington, D.C 2M5(. 

### CERTIFICATION Icertify that tothebestofmyknowledge and beliefL. The companynamed in Part 1, section A, subsection laofthisnotice form intends to manufactureor importfora commercial purpose, otherthan insmallquantities solelyforresearch anddevelopment, the substance identified in Part 1,Section B. 2. All information provided inthis notice iscomplete and truthful as ofthe dateofsubmission. 3. 1am submittingwith this notice alltest data inmypossession orcontroland adescription of all otherdataknown to orreasonably ascertainable byme asrequired by§720.50 ofthePremanufacture Notification Rule. 

### Additional Certification 

### Statements: Ifyouare submitting aPMN, Intermediate PMN, Consolidated PMN, orSNUN, check thefollowinguser feecertification statement that applies: TheCompany namedinPart1,Section Ahasremitted the feeof$2500 specified in40 CFR700.45(b), or 

# O The Companynamed inPart 1,SectionA has remitted the feeofS1000 foranIntermediate PMN (defined @ 40 CPR700.43) in aoracewith 40CFR 700.45(b), or 

# o TheCompany namedin Part I,Section Aisa smallbusiness concern under40 CFR700.43 andhasremitted afee ofS100in acodancewith 40CR700AS(b). Ifyou are submitting a lowvolume exernption-tLVE)-appitonin-aecordAnewith 40 FR723S0 -(c)(1)oraLow .=reeae and low exposure exemption (LoREX) application in accordance with40 CFR723.5 (c (2), checkthe following certification statements:



# OThe manufacturer submittingthisnotice intendsto manufacture orimport thenew chemical substance for

commercial purposes,other than insmallquantities solely forresearch and development, undertheterm of40 CFR723.50. 

# OThemanufacturer isfamiliar with the terms ofthis section andwill complywith thoseterms; and 

# O

Thenew chemical substance forwhich thenoticeis submitted meet all applicable exemption conditions. 

# oIfthis application is foran LVE inaccordance with40CFR723.50 (c)(1), themanufacturer intendsto

### commence

manufacture oftheexempted substance for commercial purposes within I yearofthedateof theexpiration ofthe 30dayreview period.

The aocuracyofthestatements youmakeinthisnotice should reflectyour bestpredictionoftheanticipated facts regardingthechemical

substance describedherein. Anyknowing andwillful misinterpretation issubject tocriminalpenalty pursuant to18USC 1001. Confidenia "g eand title ofA hnz Official (Original Signature Required) Date Signature ofagel~t - (ifapplicable) DateAUG 17 '00 02:07P CERDE CORP P. 2/2 

## pant i -GENERAL 

## INORMATION Section~A - 

### SUB~aMIT iDENTifiCAION Can&i denfiul Mark00 the-raicldatlal"boxnext toanyuaecinyou clim.asconfidential. Name of iaehouized official Positioni

.. Person Suabmitting DAVID SOCCHINI EXECUTIVE VIX M DNA EFR PNCR Notice P= duc2-DECUSSA METALS CATALYSTS CERDECFMDVSO

Mallin6 addzn (anzbe andsweet) 

### City,sSeMPCode WASHINGTON, PA 15301 b. Agent (if Nomeofauthorized official Position applicable) Gompany Mailin addrs 6uamber and uuutP Cit, sa ZI Coe ra Code Number Tatephone
c.Ifyouaresubmitting thisntcaaspartof a joitsubmission. mark00 thisboz. joint Nameofauthoizedoffcat oito Submitter (ifapplicable) Miling address(uamber and swet) city. state,ZIPCO&. ArmCode Number Telephone 2. Technical Name Psto 

# Contact 

# _________________f_______ (nUS) LUCY STEM POUCTu SAM! m AIra dinc2-DEGUSSA IIETALS -CATALYSTS CERDEC CEPEC DISO Mailingaddress(numberand sweet) WEST WYLIE AM EM59AmNme Cky.Sbae. zip demCoe Nib Talephome WASHINGTON, PA 15301 I 724 1223-5990 EXT_ 5933 3.

I youhavehadaprenotom cmmunicaon MPC connig "h~Pode Mark 00 and EPAassigned aPCNumbrto the notie, 11ta thenumber. --- PC 397C. Ifnn 4- Ifyou previously submittedanexemtion application for thechemiol substance covered bythis nocce, entrthe exemption number mmsigsed Mark 00 byEPA. Ifyoupreviously submitted aPMNfor thissubstance enterthIle i PN number assied byEPA "La withdrawn orincomplete). inn 5.I youhave submitted anotice ofBona fideintent totrunufactueor Mar 00

.... > 

## r ,

importfor thechemical substancecovered bythis notice, enterthe ifnoneLZ notice number assigned byEPA. 6. Type ofNotice - Mark00 

# 0 Only Orly 1 . ot 

# Eemingoption 

### Bnipio I L FORM EPA7710.25 (Rev 5-9s) Pag-e3

# 0 0... .... Part I
- 

## GENERAL INFOnMATION
- 

## Continued Section 

### S CHEMICALIDEN =rnINFORMIATON: bO masso nu it osv ne9Mo Cww(~m Amaasaa tCA num. tm m~ Mark00~the -Conficentai' box next to 5.nW item you diaim as confideiaL ComPitte either item I (Class i or2 suostanceso or 2(Polymners) as appropriat. Comiplete ALIother Items. 'd another Person -ill subit chenucai identitv untormamon tor you tfor either item Ior2). maric 00the boxat the n7gh. 

## Lcma ideintvthename. camranv. sno addren ot thatpemsn in acontiuation sheet. 

### t.J dentiai 1. Class Ior 2chemicalrubsances qtordeutin atdaw ana daw~ 2subsmann. see theinsatsanns Mlanual) a. Classoisubstance - Mark00( I 

### [ CAN or 2 

### 0 Clan 2 b. Ciaxucalnamea tCurreily correct Che-mia Abstracts (CM3 Name that &s onsistmt withTSCA Inventory listirn tarsimilar, Aubtan ForCLIO ISubstanfces aCA hIndez Namea ms bevravided.For ClansIsubstances cither aCA Index Name orCA Preferred Nam m XX be provid&c Whichever Isappropriatebasnd anCA 9C3nomeistumW zii andcoiiveitiom)s.

c.Please icentwy whi methodlYouLima to devetop, or ootazn the specuLfed chemucal indetityinformationi sepwr inthisnou (checx onet. ED Method I (CASInventory Expert s1ervucr - acopyoi theIdentasicawo [Method 2 (Other6ource) repotobtaines from tncCAS Inventory Expert Servie must be submitted as an attachment tothis notice) d. M0lecu~ar ormuLa andCAS Rgisry Number (ifanumber alzeady m t for thi subtans) 7P

e. Foriaclass A subsaune.providaa ipieteann correcichenucalstuure disam. F'xaclass2 substance-(1)ULst thue w ia precursor substances withtheirrespective CAS Registry Numbems (2)DeCiabe thenature ofthe reacni orpo (3)Indicatethe XXX range at compotizoon and the typialco. pc~on "n-Wsp proprinie7 (4) Provide a corectrepresative or partiulchemicalI SmtrUCre aiapamU. a~s Com~piete as canbe known, i one Can be rea&XMablV astared..C

a-i on iAt hl box~ ifYou attach a contiuacon sheet.CAS Inventory Expert Service Repo page I of 2

Inetr ExetSevc
Adivision of the American Chemical Society Phone: 800-631 -1884. 614447-3600 (ext. 2308) Fax:614447-3747 E-mail: answers@cas.org

INVENTORY EXPERT SERVICE REPORT

IES-ORDER NUMBER:
REGISTRY NUMBER:.

CA INDEX NAME 

# CONFIDENTIAL

Please print the above CA Index Name on the appropriate page of your PMN.

1fthis 

### box is checked, CAS has made correction(s) marked in red to your IES order. Please make the same correction(s) to your PMN before submitting it to the EPA.



# 000005 2540 Olentangy River Road P0. Box 3343 Columbus. Ohio 43210-0334CAS Inventory Expert Serivce Report page 2 of 2

ANSWRIF.EGSx COPYRIGHT 1999 ACS RNq 

### [ FEGIS=1Y REGI237Y COPYRIGHT 1999 ACS Fq L FI POS T RY

CNl F I (CA IND:!EX- NAME) OTHER NAMES: CN [ 

### I Ir IDR 

### II 

# : COIE 

# T1AL MF 

### [O i

AF 

### I CI TIS



# 0O(OGOG

## Product Structure 

# G6F N IAL



# CONFIDENTIAL 4C000007

### SectionPart 

## I -- 

## GENERAL INFORMATION - 

## Continued ScinB -CHENUICAL 

### IDENTITY INORMATION - 

### Continued :Polymers tFor a definition ofpolymer, see the instructions Manual.) Confidential a. Indicate the number-average weight of the lowest molecular weight compombton of the polymer youintend to manuiacture. Indicate maximum weight percent of low molecular weight speces inot including residual monomers, reactants, or solvents), bel 5 00 and below 1,000 absolute molecular weight ot that composition. Describe the methods of measurement or the basis for Your estimates: GPC 

# C3 Othe(] :(Specify) 0)lowest number average moiecular weight:________ H)maximum weight %below 500molecular weight______ U0l maximum weight %below 1000) molecular weight;________ 

# E Mark WX this box if youattach acontinuation sheet. b. You must make separate confidentiality dlaims for monomer or other reactant identity, composition informatia9(and residual information. Mark (X)the "Confidential" box nextto any item you claim as confidential. (1) - Provide the specific chemical name and CAS Registry Number (if anumber exists) of each monomer other reactant used in the (2) - Mark MX thiscolumn if entry in column (1)is confidential. (3)
- Indicatethe typical weight percent of each monomer or other reactant in the polymer. (4) - Mark WX the identity column if you want amonomer orother reactant used at two weight cent or lessto be listed as part ofthe polymer description on the TSCA Chemical Substance Inventory. (5)
- Mark CX) thiscolumn if entries in columns (3)and (4)are confidential. (6) - Indicate the maximum weight percent of each monomer or other reactant that may be p t as aresiduall in the polymer as manufactured for commercial purposes. (7) - Mark (X thiscolumn if entry in column (6) is confidential. Monomer or other reactant and CAS Registry Number ConfK Typical Identity Confi- Maximum Cof- ()d Icomposition Mark (X) dential residual dential ____________________________________________________(3) (4) (5) (6) (7



# E Mark CX) this box if youattach acontinuation s t c. Please identify which method you usdt=eel or obtain thespecified chemical identity information reported in this notice. (check one). Method'I (CAS Inventory Expert e-i copy of the identification report Method 2 (other source) obtainedfrom CAS lnventoy Expert Service must besubmitted as an attachment to this notige d. The currently correct Chemical Abt ( CA) name for the polymer that is consistent with TSCA Inventory listings for similar polymers.

e. Provide acorrect representativ or partial chemnical structure diagram, as complete as can be known, if one can be reasonably ascertained.

Mark (X)this box if you attach acontinuation sheet. FORM EPA 710-25 (Rev. 5-95) Page 5 0Ao 

## O s

### P.au, I - 

### GENERAL INFORMATION - 

### Continued Section B - CHEMICAL IDENTITY INTORMATION - Continued 3. Impurities

(a)- Identify each impunty thatmay be reasonably anticipated to be present in the chemical substance asmaiutactufed for ewmmeraal purpoeu. Provide the CAS Registry Nuinber it available. If there are unidentified impurities.enter "unidentified." ib) -Estimate the maximum weight %of each Impurity. If there are unidentified impunties, estimate their total weight%5. Impury and CAS Registry Number Ma"mu Confi- (a) percent dentia

% X



# EMark (X)thisbox if youattach acontianuation sheet. 4. Synonyms - Enter any chemical synonyms for the new chemical substance identified in subsection I or 2. ConfiNot Applicable 

# EMark (X)this

### box ifyouattach acontinuation sheet. 5.Trade identification - List tradenames for the new chemical substance identified in subsection I or2. 

# E1 Mark 00 thisbox ifyou attach acontinuationsheet. 6. Generic chemical name - Ifyou claim chemnical identity asconfidential, you must provide ageneric chemical name for your substance that reveals thespecificchemical identityofthe newcheiucalsubstance to the maximum extent possible. Refer to theTSCA Chemical Substance Inventory, 1985 Edition, Appendix Bfor gidcance on developing generic names. Mixed Metal Oxide 

## E Mark 00) thisbox if you attach acontinuation sheet. 7. Byproducts - Descibe any byproducts resulting from the manufacture, proicessing, use, or disposal ofthe new chemical substance. Provide the CAS Registry Number ifavailable. BpoutCAS Registry Number neafl- (2) dential

FORM EPA77iO-25 (Rev. 5-95) Paget) 

## 0(00 9,-

### Part I

-- 

### GENERAL INFORMATION -- 

### Continued Section C - PRODUCTION, IMI'ORT, AND USE INFORMATION: Mark (X)the 'Conndointial- box next toany item you claim asconfidential. 1. Production volume - Estimate the maximum prodiuction volume during the first 12 months of production. Also estimate the maximum produ.:tion volume for any consecutive 12-month penod during the first three years ot production. Estimates should be on 100% new chemical substance basis. ForaLow Volume Exemption application,ifyou choose to have yournotice reviewedat a louw production volumne than 10,000 kg/yr, specify the volume andmark Wxin the binding'box. Ifgranted. you are bound ,to this volume.. Maximum tirst 12-month production (kg/yr) Maximum 12-month production (kg/yr) denfi- OBinn (100% new chemical substance basis) (100% new chemical substance basis) MarkW)

2. Use Information - You must make separate conndentiality claims forthe description ofthe category ofuse, the percent ofproduction volume devoted to each category, the formulation of thenew substance, and other use information. Mark (X)the "Confidential" Box next toayitem you claim as confidential. a. (1)- Describe each intended category of useof thenew chemical substance by function and application. (2)

- Mark (X)th" column ifentry in column (1) isconridential business information (CE!). (3)- Indicate your willingness to have the information provided in column (1)binding. (4)- Estimate the percent oftotal production for the first three years devoted to each category of use. (5)- Mark 0X) this column ifentry in column (4) iscorndential business information (CBI1). (6)- Estimate the percent ofthenew substance as formulated in mnixtures, suspensions, emulsions, solutions, orgels as manufactured for commercial purposes at sites under your control associated with each categoryofuse. (7) - Mark CX) this column ifentry in column (6)isconfidential business information (CBI). (8)- Indicate % of product volume expected forthe listed "use" sectors. Mark morethan onebox ifappropriate. Mark CX) to indicate your willingness to have the usetvpe provided in (8)binding. (9)- Mark (X)this column ifentry~ies) in column (8)is(are) confidential business information (CB!). Categoryof use (1) CBI Binding Produc- CBI %in CBI % of substance expected peruse B (by function andapplication i.e. a dispersive dyefor Option tion %o Form- 

### ~ (8) finishing polyester fibers) MarkW ulation Sit- I~
- Inus Co-Bidn (2) (3) (4) (5) (6) (7) limited sumer trial mercial Option (9) X % X .7. 10 

### X % X 7bX 100~ X %IX X 100~ X % IX %X 100 x -%I X % X I10%,

- *If you have identified a "consumer" use, please provide on a continuation sheet a detailed description of the use(s) ofthis chemical substance in consumer products. In addition include estimates ofthe concentration ofthe new chemical substance as expected in consumer products and describe the chemical reactions by which this substance loses itsidentity in the consumer product. Mark 0)0 this box ifyou attach acontinuation sheet. NO CONSU14ER USE b. Generic Ifyouclaim any category of usedescription in subsection 2a as confidential, entera genericdesciption ofthat use category. Readthe Instructions Manual for examples ofgeneric use descniptions. description Pigment 

# I3 Mark (X)this box ifyou attach a continuation sheet. 3. Hazard Information - Include in thenotice acopy ot reasonable facsuaule ofany hazard warnig statement, label. material safety data sheet, Bin~ding or other unformation which wil beprovided to any person who is reasonably likely to be exposed to this substance regarding protective Optn equipment or pra':tices for the safe handling, transport, use,or disposal of the newIsubstance. List in part Ill hazard information you include. Mr XMark ('X) this box ifyou attach hazard informanon KSDS and Label (see pages 14i'23) FORM EPA 7710-25 (Rev. 5-9S) Page 717,7

### Part hk--- HUMAN EXPOSURE AND ENVIRIONMENTAL RELEASE Section A -INDUSTRIAL 

### SITES CONTROLLED BYTHE 

## SUBM[rITTE Mark0X)the "Confidiential" boxnexttoanyitem you claim as confidential. Complete section Afor each type ofmanufacture, Processing, or use operation involving the new chemical substance atindustrial sites you control Importers donot have to complete this section for operations outside the U.S. ;however, you may stillhave reporting requirements ifthereare furtherindustrial processing or use operations after import. You mustdescribe these operations. See instructions manual. 1. Operation description Cons a. Identity - Enter the identity of the site at which the operation willoccur. et Name

d2- DEGUSSX IETAiT;.CAT*IfIS CERDEC, CERDEC DIVISION Site address (number and street) west Wylie Avenue; P.O. Box M19 City, County, State, ZIP Code Washington, Pennsylvania 15301 Ifthesame operation will occur at more thanone site, enter thenumber ofsites. Identify the 180 m additional siteson acontinuation sheet, and ifany ofthe sites have significantly different production rates or operations, indcle all theinformation requested in thissection for those 1 sitesas attachments.



# []1 Mark (X)this box ifyou attach acontinuation sheet b. Type-

Mark W0 G] Manufacturing 

### 1: Processing El Use c.Amount and Duration - Complete 1or 2asappropriate

d. Process description [3 Mark (X) toindicate your willingness to have your process description binding. 

### xxx (1)Diagram themajor unit operation steps andchemical conversions. Include interim storage and transport containers (specify-e.g. 5gallon pails, 55 gallon drum, railcar, tank truck, etc.). (2)Provide the identity,theapproximate weight (by kg/dayor kg/batch on an 100 newchemical substance basis), andentry pointofall starting materials and feedstocks (includingreactants, solvents, and catalysts,etc),and ofall products, recycle streams, and wastes. Include cleaning chemidcals (notefrequency if notused dailyorper batch.). (3) Identifybynumber thepoints ofrelease, including small orintermittant releases, totheenvironmnenlgite ne-wchemnical substance. See Block Diagrams on pages gas Bb. and Sc.



# (q Mark M this box ifyou attach acontinuation sheet. FORM EPA7710.25 (Rev. 5-95) Pages8

# .0ONFIDENPAL Process Description I PMN Substance Manufacturing Operation for

8a 

# 00O0Of 

# rnwnnm

# Process Description 11 

# CONFDFNIAL PMN Substance Manufacturing Operation for



# mmmflnrlfflTIl 8b 

## 00001s

# Process Description IIILllF 

# J On-Site Processing ofthe PMVN Substance into Glass Enamel Pastes

8_ Bc 

# QCC.Ci4 

# nlm Ri

# flfl R1

### Part 11 - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - 

### Continued SSection A - 

### [NDUSTRIAL SITES CONTROLLED BY THlE SLTBMr[TTER - 

### Continued 2. Occupational Expoaure - You must make separate conindentiality dlaims forthe descrption at worker activity, physicalform ofthe new chemical

substance, number ofworkers exposed. and durationat activity. .Mark (X) the "Confidential"box nextto anv item you claim as confidential. 1)- Describe the activities (e.g. bagdlumping, tote tilling, unloading drums,sampling, dleaning.etc.) in which workers may be exposed tothe substance. (2) - Mark WX this column if entry in column (1) isconndlential businessinformation (CI). (3)- Describe any protectiveequipment and engineering controlsused to protect workers. (4)and (6)- Indicate you willingness to have the intormatlon provided in column (3)or (5)binding. (5)- Indicate the physical form(s) of the new chemical substance te.g. solid: crystal, granule. powder. or dust) and %new chemical substance(if partat amixture) at th timeof exposure. (7)- Mark (X) this column if entry in column (5)is contidlential business information (CBII). (8)- Estimate the maximum number of workers involved in each activity far all sitescombined. (9)- Mark (X this column if entry in column (8)iscontidential business information (CBII). (10) and (11) - Estimate the maximum durationof theactivity for anyworker in hours perday and days per year. (12) - Mark M0this column ifentries in columns (10) and (11) areconfidiential business infor~mation (CIII).

___ Worker activity CI Protective Equipment/ tandini V1hysicali fornital -oo CB *Of CBI Maximum duration CE! (e.g. bag dumping, fillingdrums) Engineenng coUrol apit,, (e.gsoiid.powder) POR Workers -s/aDy/r aMirk s) and %new W Exposed r/aDysr (1) (3) 

### ~~~~~~~substance L .. QL.*fl.. 1) Ventilation XI Respirators, Glasse- X 1-2 1~l2 5-20 X Gloves, Safety Glas X 1 8 5-20 Respirators_______
- -- - - Safety Glasses X Gloves X 1 1 5-20 X Safety Glasses Gloves X1 1 1 5--20 X Safety Glasses Gloves X1 2 1 1 8 15-20 

# I!Mark M0this box ifyou attach acontinuation sheet. See page 9a (for page 8a processing) 3. Environmental Release and Disposal - You must make separate confidentialityclaims for therelease number and the amount ofthe newchemical substance released andother release and disposalinformation. Mark M0 the "Confidential" box nextto eachitem youclaim as confidential. (1) - Enter the number of each release point identified in the processdescription, part 11, section A,subsection ld(3). (2) - Estimate the amountof the new substance released (a)directlytothe environment or (b)into control technology (in kg/dayor kg/batch). (3) - Mark M0 this column ifentries in columns(1)and (2)are confidential business informaion.(CE!). (4) - Identifythe media of release Le.stack air,fugitiveair (optional-see Instruction Manual), surface water, on-siteor off-site land or incineration, P01W, or other(please specify) to which the new substance will be releasedfrom that release point. (5) - a.Describe controltechnology, ifany, ,and controlefficiency that will1be used to Limit the releaseof the new substancetotheenvironment. For releasesdisposedof on land, characterize thedisposal methodand statewhether it isapprovedfor disposalof RCRA hazardouswaste. On acontinuation sheet, for each sitedescribe any additional disposalmethod~s that will be used and whether thewaste is subject to secondary or tertiaryon-ite treatment. b.Estimate theamount released to the environment after control technology (in kg/day). (6) - Mark (X) thiscolum ifentries in columns (4)and (5)are confidential business information (CE!). (7) - Identifythe diestintation(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct dischargers or NPDES numbers of the P01W (Publidly OwnedTreatment Works). Mark 00)11 the P01lW name orNPDES #isconfidentia business information (CB!) Release Amount ofnew substance 0,MdatControl technology and efficiency (you may wish toopitionally attach efficiencydata) CEI Number rele release ( __)_(2a)_ (2b(4)a(kaW (Sb) (6) 1 0.2 kg 20 kg/batch air Pulse Jet Baghouse; 99.9% efficiency 0.02 kg/batch 2 0 20 kg/batch water Onsite Water Pollution Abatement 0.2 kg/batch

- 99.91 efficiency 3 0 10 kg/batch water Onsite Water Pollution Abatement 0.1 kg/batch

________ 99.9% efficiency 4 0.1 kg 10 kg/batchl air Pulse Jet Baghouse: 99.91 efficiency 1 0.01 kg/batch 5 0.2 kg 10 kg/batch air Pulse Jet Baghouse; 99.9% efficiency 0.02 kg/batch (7)Mark WX the [D POTW provide name(s) below: CBI E] Navigable C] other.-specify provide NPDES # CE! destination(s) of Washington-E. Washington waewy releases to waler. JitAhoty(EA PA0026212 

# EMark 00)this box ifyou attach acontinuation sheet. FORM EPA 7710-25 (Rev. 5-95) Page 9 A

## Part 11 - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - 

## Continued1 Section A - 

### ENDUSTRIAL 

### SITES CONTROLLED BYTHE SUBMER= - 

### Continued 2. Occupational Exposure - You must makeseparate cotideniality clains forthe desciption of worker activity, physical form ofthe new chemical substance, number of workers exposed. and duration ofactivity. IMark 0)0 the "Confidential"box next to any item youclaim as confidential. (1)- Descibe theactivities (e.g. bag dumping,tote filling,unloadingdrums, sampling. cleaning.etc.) in which workers may be exposed to the substance. (2)- Mark 00)thiscolumn ifentry incolumn (1)isconfidential business information (CED. (3)- Describe anyprotective equipment and engineering controls used to protect workers. (4)and (6)- Indicate you willingness to have the information provided incolumn (3) or (5)binding. (5)- Indicatethe physicalform(s) of the new chemical substance te.g. solid.crystal, granule, powder, ordust) and%new chemical substance (ifpartof amixture) atthe time of exposure. (7 - Mark 00 thiscolumn ifentryin column (5)isconfidential businessinformation (CBfl. (8)- Estimate the maimum number ofworkers involved in each activity forallsitescombined. (9)- Mark 00 thiscolumn if entryin column (8)isconfidential busiess information (CBI). (10) and (11) - Estimate the maximum duration of the activity for anyworker in hours perdayand days per year. (12) - Mark 00 thiscolumn if entries in columns(10) and (11) are confidential businessinformation (CBfl.

___ Worker activit CE! Prosdive Equipmnt/ Biading k'hysicaitormia) Bidn CB 0of CD! Maximum duration CB1 (e.g. bag dumping, fillingdrums) Engirig Contris Dpiom ea ld-o 

### - Workri/dyDasy M~&(x) and%new ki) Exposed r/aDys-i (1)___________3) substance() *j X Safety Glasses X 1-2 8 5-20 ,Gloves X Ventilation, Gloveq X 2 16 5-20 Safety Glasses, Rew X Ventilation, Gloves X 1 8 5-20

___________________ Safety glasses, Resp. X Ventilation, Gloves X 1 1 5-20

_____________________ afety Glasses, Resp
Mark MXthis box if youattach acontinuation sheet. See page 91b(for page 8b processing) 3. Environmental Release and Disposal - You must make separate confidentialityclaims for the releasenumber and the amount of the newchemical substance released andother releaseand disposal information. Mark

### 00 the "Confidential"boxnext to each item you claimas confidential. (1) - Enter the number ofeach release pointidentified in theprocess description, part ILsection A, subsection ld(3). (2) - Estimate theamount of thenew -substancereleased (a)directly tothe environment or (b)intocontrol technology (in kg/dayorkg/batch). (3) - Mark M0 this column ifentries in columns (1)and (2)are confidential business information (CB!). (4) - Identifythe media ofrelease ie.stack air,fugitive air (optional-see instruction Manual), surface water, on-siteor off-site Landor incineration. P07W. or other (please specify) to which the newsubstance will bereleased from that release point. (5) - a.Describe controltechnology, ifany, ,and control efficiency that will be used to limit therelease ofthe new substanceto theenvironment. For releases disposed of onland. characterize thedisposal method and statewhether itis approved fordisposal of RCRA hazardous waste. Onacontinuation sheet , foreach sitedescibeany additionaldisposal methods that will be used and whether the wasteis subject to secondaryortertiary on-site treatment. b.Estimate the amount released to theenvironment after control technology (in kg/day). (6) - Mark 00)thiscolumn ifentries in columns (4)and (5)are confidential business information (CB!) (7) - Identify thedestination(s) ofreleases to water. Please supply NPDES (National Pollutant Discharge Eimination System) numbers for direct discharger's or NPDES numbers ofthe POTtY (Publidly owned Treatment Works). Mark M011 the P01W name or NPDES #is confidential businessinformation (CE!). Release Amount ofnew substance CB Medao Control technology and efficiency (you may wish tooptionally attach efficiency dta) I Number CDIe release () (2.a) (2b) (3 (4) (54) Kuc W T (6)

(7) Mark MX the 

### ~ 0W de namets) belo-. CBI 

### Navigable 

# [~other -specify provide NPDES # CB! destination(s) of waterway releasesq to water. Mak 00 this box ifyouattach acontinuation sheet. 0O0O91!0 

# G

## Part II- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - 

## Continued Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMrTTE - 

### Continued 2_occupational Exposure - You must make separate confidentiality dhurnsfor thedescription ofworker activity, physical form ofthe newchetnscai substance. number of workers exposed. and duration ofactivity. Mark 00 the "onfidential" box next to anyitem you claim asconfidenbal (1)- Describe the activities (e.g. bagdumping, tote tilling.unloading drums,sampling, cleanung, etc.) in which workers may be exposedtothe substance. (2)- Mark (X)this column ifentryin column (1)is confidential business information (CE!). (3) - Describe any protective equpment and engineering controlsusedto protect worker. (4)and (6)- Indicate you willingnessto have theinformation provided incolumn (3) or (5)binding. (5)- Indicate the physical form(s) of the newchemical substance (e.g. solid.crystal, granule. powder,or dust) and %. newchemical substance (ifpartof amixture) at thetime of exposure. (7 - Mark 0)0 tiscolumn ifentryin column (5) isconfidential business inormation (CM!). (8)- Estimate the maximum number ofworkers involvedin each activity forall sites combined. (9)- Mark 00 thiscolumnn if entryin column (8)isconfidential busines information (CE!) (10) and (11) - Estimate theme-mum duration ofthe activity for any worker inhours perday and days per Year. (12) - Mark 030 this column ifentriesmincolumns (10) and (11) areconfidential business information (CE!). Worker activity CB! Protive.Equipmenti Binding Yhscllrmier BIdbngC *of CB! Maxim uration CEI (e.g. bagdumping, filling drums) EagAnsasag Cosmil OP. (egsaolipd er 'l. irr. (a) and %now Wr~ Exposed Hrs/dy Days/yr substance (8) 

### fy. 12 rVentilation Safety Glasses X 1 10-12 5-20 Safety Glasses X 1 1 5-20 X Ventilation X 1 0.5 5-20

____________________ Safety Classes VentilationI I Safety Glasses

_ ______ - X 1 8-12 5-20 

# EMark W0 thisbox ifyouattach a continuation sheet. 3. Environmental Release and Disposali - You mustmake separate confidentiality claimrs for therelease number andthe amountof thenew chemical substance released and otherrelease and disposal information. Mark 0)0 the "Confidential"box next toeach item you claim as contfidentiaL (1) - Enter thenumber ofeach release point identified in theproces description, part IL,section A, subsection ld(3). (2) - Estimate the amount ofthe new substancereleased (a)directly tothe environment or(b) intocontrol technology (inkg/day or kg/batch). (3) - Mark 00)this-column ifentries incolumns (1)and (2)are confidential businessinformation (CB!). (4) - Identify themedia ofrelease ie.stock air,fugitive air (optional-see Instruction Manual), surface water,on-site or off-siteland orincineration, P01W, or other(please specify) to which thenew substance will be released from that release point. (5) - a.Descrbe control technology, if any, ,and control efficiency that will be used to limit therelease of the newsubstance to theenvironment. For release disposed ofon land.characterize the disposal method and state whether itis approved for disposal ofRCRA hazardous waste. On a continuation sheet,* for each site describe any additional disposal methods that will be usedand whether thewaste is subject to secondary or ternary on-ste treatment. b.Estimate the amount released to theenvironment after control technology (inkg/day). (6) - Mark 00)this colum ifentries in columns (4)and (5)areconfidential business information (CE!) (7) - Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct dischargers or NPDES numbers of theP01W (Publicly OwnedTreatment Works). Mark 00)1i theP01W name or NPDES 11 isconfidential business information (CBM) Release Amount ofnew substance 

### CBI Mediao Control technology and efficiency (youmaywishto optionally attach efficiency data) 

### Cm1 Number ree releaese (1) (2a) (2b) Mark ((A)(6

_______ ______ __ (4) (55a(6 10 0.125 kg 12.5 kg air Pulse Jet Daghouse, 99.9 %.efficiency 0.0125 kg Onsite Water Pollutin Abatement 20 0 12.5 kg water 99.9 %. efficiency 0.0125 kg 30 0.05 kg 5 kg air Pulse Jet Baghouse, 99.9 %. efficiency 0.005 kg Onsite Water Pollution Abatement '#0 0 45_kg water 99.9 %. efficiency 0.045 kg 50 0.125 kg 12.5 kg air jPulse Jet Baghouse, 99.9 efficiency 0.0125 kg (7) Mark (X)the 

# 13 P01rW provide name(s) below. CB! (L-Navigable Other - Specify provide NPDES US CE destination(s) of Washginton-E. Washington waterway 

### reesstae. Joint Authority (WEWJA) 

### PA026120 

# GIo 0 ElMark (X thisboxif youattachacontnuationsheet. ( see page 9c for continuation of ERWD for Schematic page 8b).

,.. . - n 1 :n.OC%

--

## Part 11I- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - 

## Continued Section A- INDUSTRIAL SITES CONTROLLED By THESuBMfTER - 

### Continued 7- Occupational Exposure - You must make separate conridientialitv claims forthe descrition of worker activity, physical form ofthe new chemi substance. number of workers exposed, and duration ofactivity. 'Mark(X)the 'Contidentiaf box next to any item you claim asconfidlential (1)- Describe the activities (e.g. bagdumping, tote filling,unloading drums, sampling, cleanung,etc.) in which workers nmy bee e substance. (2)- Mark M0 thiscolumn ifentry in column (1)is confidential business information (CED. (3)- [)sciibe any protective eqipment and engieering controls used to protect workers. (4)and (6)- indicateyouwdhingnew to havethe information provided in column (3)or (5)binding. (5)- Indicatethe physicalform(s) of the new chemical substance (e.g. solid.crystal. graniule. powder, or dust) .new chenucalsubstance (ifpartof amixture) at the time of exposure. (7 - Mark 00)thiscolumn identry incolumrn (5)is confidential business information (CBI). (8)- Estimate the miaximum number of workers involved ineachi activityfor all sitescombined. (9)- Mark 0X) this column ifentry incolumn (8)isconfidential business information (CBI). (10) and Q11) - Estimate the maximum duration of the activityforany worker in hours y and days peryear. (12) - Mark 00 this column ifentries in columns (10) and(11) are confidential information (CBI).

___ Worker activity CBI ProteciveEquipmentl Binding t icai ormta) =dta Cm of CB1 Maximumduration CB! (e.g. bagdlumptigfilling drums) EngineringCOnaOID a -e-gaoLid:'powder) I t " Workers i/a asy
__0___ 3 r N (8) (10) 

### ~fil (121



# L1i Mark M thisboxifyouattachacontinuationsheet. see page 9d (for page 8c processing) 3. Environmental Release and Disposal - You must makeseparate confidentialityclaimsfor the release number and the amount ofthe newchemical substance released and other release anddisposal information. Mark M0 the "Confidiential" box next toeachitem you claim asconfidential. (1) - Enter the number ofeach releasepoint identified inthe proces desciption. part ILsection A.subsection Ild(3). (2) - Estimate theamount of the newsubstance released (a)directly to theenvironment or (b)intocontrol technology (in kg/dayor kg/batch). (3) - Mark M0 thiscolumn ifentries in columns (1)and (2)areconfidential business information (CBI). (4) - MIdy thie mei ofreleaseie.3ta& -air,fugitive air (optional-see Instruction Manual). surface water, on-siteor off-site land or incineration, P01W. or other (pleasespecify) to which the newsubstance will bereleased from that release point. (5) - a.Describe control technology, ifany, ,and control efficiency thatwill be usedto limitthe releaseofthe new substance to theenvironment. Forrelease disposed ofon land,characterizethedisposal method andstate whether it isapproved fordisposal of RCRA hazardous waste. On acontinuationsheet, for each site describeany additional disposal methods that will be used and whether thewaste is subjectto secondary ortertiaryon-aite treatment. b.Estimate the amount released to theenvironment after control technology (in kg/day). (6) - Mark 00 this column ifentries in columns (4)and (5)are confidential business information (CBI). (7) - Identify the destination(s)ofreleases to water. Pleasesupply NPDES (National Pollutant Discharge Elimination System) numbers for direct dischargers or NPDES numbers of the P01W (Publicly Owned Treatment Works). Mark 00 if the PO'IW name or NPDES 0 isconfidential business inormation (CDI) Release Amount of newsubstance CB Melo Control technology and efficiency (you may wish to optionallyattach efficiency data) CDI Numbe rCDI release

Numbe sac ai hai (1) (2a) (2b) Mar m(x) Badn

_________ _________(3) (4) (5a ar a) (5b) (6) 60 0.125 kg 12.5 kg air Pulse Jet Baghouse, 99.9% efficiency 0.0125 kg 70 0 12.5 kg water Onsite Water Pollution Abatement _______ _______99.9% efficiency 0.0125 kg

- - (7) Mark (X)the PO1W provide namets) belovr. CBI E]Navigable other. Specify provide 

### NPDES CBI destination(s) of WEWJA wtra releases to water. PA0026212 

# E Mark 00 this box ifyou attach acontinuation sheet. 000U)

### ,,art 11 -- 

### !iUMAN 

### EXPOSURE AND ENVIRONMENTAL RELEASE - 

### -'ontmnued ?

### ~ A INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER - o'ntinueu ccu,ationai t-xoiure - 'wu must maKe serarateconnuientialiv-:aims for ilC oesaitnifn of worywr acflvitv rnnv;icii form of tflC new cnemica!

.,tanL': e ::et~v of worl(Crb eXLX)1A. anj uration )t .ivitv 2,lrki t.,oItice onfldennal b'ox next it)ary item youi claim as ,unticntiai. '--lCL trie .tic,tie cU vC Jcumoins! I U~i 1110nn .2,111711:n Ururs. jmplini, nevninc,cwnein wonin workers may txe esooKSea to the

- '.IK trk I this column it entry in columni I is cornfentiaiL'usiness information tI":fI). 4-.ance any protective couipment ana eneinecrintt controls Used to prowect worKers inutO' -- Ildlc.3te Vou willingniess to riave tneffinotration r'rovicied in column 0.) or 6n) binding.

*niicaic the tinvqlcal forintsjof the new c-nemicai suos'tance te sz saud: arvstal. g~ranule. ;xawoer or oustn ana '~new cenmItca substanceuLt partat

mixturel it the time of eroure. %la\t~rk (X) this coljurrn if entryV in column uij is conticiential business information l3) i--

sflmafe the maximum number of worKers involved in vacni activity tor all Sites CornMIed.

- 'IMark tX) this colaun it entry in column to) iscorndential businCSs Information K131). 10) and tIl) - Estimate the maxur duration of the activity for any worker in hours per day and days peryear. 02) -%ldark WX this column it entries in columns t10) and (11) are conndential businesinformation tCBI).I Worker activity CBI Prviecllve Lquipmenu Hifldin, Flhviicat formts) Binding CBI 0of CBI Mximumn duration C1B1 ieg. bagdumping, tilling drums) 

# I tineennit Lontrals Option (e.g.soiid:powder) Opin Wokr substance 'n 1'4)n 

### g~ (2 X Safety Glasses X 1 1 30-100 gloves, VentilX -21-2 3010 Safety Glasses Gloves, Ventilatior X 1-2 1-2 30-10 X Safety Glasses

______________ Gloves X 1-2 2-4 130-120 

# LiMark WX this box if you attach a continuation sheet. 3. Environmental Release and Disposal - You must make separate confidentiality claims for the release numoer and the amount at the newchemical substance released and other release and disposal information. Mark WX the "Confidlential"box next to each item you claim as confidential. (1) - Enter the number of each release point Identified in the process desariptin. part 11, section A. subsection Ld(3). Q)- Estimate'tfieamiiount &fth Knew Nbstance released ta) directly to the enrvironment or tb) into control technology (i kg/day or kg/batch). i- Mark (X)this column Uentries in columns t 1)and (2) are confidential business information tCBI). 1) - Identify the media of release i.e. stack air.lugirive air toptional-see Instruction Manual). surface water, on-site or oti-site land or incineration, ('01W,or othier (please specify) to which the new 'iuostance will be released trom thatreleasen point. a-*

Describe control technology, it any, and control eiliaency that will be used to limit the release ot the new substance to the environment. ror releases isposedi ofon la'nd, characierize the disposal method and state whether it is approved for aisposal of RCRA hazardous waste. On acontinuation sheet, for eacn site olesaribe any additional disposal methods that will be used and whether the waste is sublect to -.acondary or tertiary on-site treatment. b Estimate the amount released to the environment after control technology tin kg/day). fo- Mark tX) this column if entries Ln columns 04) and (5) are confidential business information (CBI).

- Identityv the destina tionts) of releases to water. Please supply NPDES (National Pollutant Discharge t~imination System) numbers for direct

dischargers or NPDES numbers ot the POTW(Publicly Owned Treatment Works). Mark WX ifthe P(YIW name or NPDES ilis confidential business information (C11I). Release

# JAmount of new substanice '.releas ui _"troi techtnology and effticiency tyou may wish to optionally attach efficiency data) CB Number ree *g.Mk1 releae ng 100 0.01 kg 1 kg air Pulse Jet Baghouse, 99.9% efficiency 0.001 kg/batch 200 0 1 kg off sit Approved Methods for Stabilization treat- 1 kg/batch

____ _______________ landfil ment and landfill. off sit Approved Method for Stabilization Treat- 1 kg/batch 300 0 1 kg Ilandfil ment and landfill.

\I try tX1t he 

# E POTW provide namets) bel'ow (-131 C Navigaole ('Ither- ,eivprovide NPDES A ICBII 'Si Ii iflsI )f .aterwav cieKsitowder. '.D

tar&.tX) this oox it you attacti acontinuatmon sneet.000 1J

### Part 11 - HUMA.. EXPOSURE AND ENVIRONMEN--CAL RELEASE - 

### Continued Section B - INDUSTRIAL SITES CONTROLLED BY OTHERS k~cmpiete section 6fortypia rcnugo s prtosivligtenwaeia substance at sites you do not controldlmporters co nothavet complete this section for operations outside the U.S.; however, you must report any processing or useactivities after import. See the Instructions Manual. Camnpiefe aseparatesection Rfor eaci typeortprocessing,or use amration invoimni the newctiurnica substance. Ifthe same operation is periorme at morethan one sitedeseribe the typical operation common to these sites. Identify additional siteson a continuation sheet. 1. Operation Description - To dlaim uruogmation in this section as conndcentiaL. circle or bracket the specinc intorrnation that you claim as contidienial. (1) - Diagram the major unit operation step and chemiucal conversions, including interim storage and transport containers (specify-e.g. 5 gallon paii 55gaLlon drums, rail cars, tank trucks, etc). On the diagram, identity by letter and briefly describe each worker activity. (2) - Provide the identity, the approximate weight (by kg/day or kg/batch. on an 100% new cheical substance basis), and entry point of all feedstocks (including reactants. bolvents and catalysts. etc) and of all products, recycle streams, and wastes. Include cleaning chemiucals (note frequency ifnot used daily or per batch). (3) - Identify by number the points of release, including small or intermiuttent releases, to the environment of the newchiemical substance. (4) Please enter the # of sites ( remember to identi the locations ofthese sites on a continuation sheet): 8

ID Mark00thisboxdifyouattachacontinationsheet. Please see Explanation of Assumptions, pp. 10 a and b. 2. Worker Eposure/Environmental Release (1)
- From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activitydescibed. (2)- Estimate the number of workersexrposed for all sitescombined. (4)- Estimate the typical duration ofexposure per worker in (a)hoursper day and (b) days per year. (6)- Describe physical form ofexposure and %new chemicalsubstance (ifin mixture), and any protective equipment andengineering controlsused toprotect workers. (7 - Estimate the percentof the newsubstance asformulated when packaged orused asafinalproduct. (9)- From theprocessdiagram above, enter the number of each release point. Complete 9-13-foreach release point-identified.- (10)- Estimate the amount ofthe new substance released (a)directly to the environment or (b)intocontrol technology tothe environment (in kg/day orkg/batch). (12) - Describemedia ofrelease i.e.stack air, fugitiveair (optional-see Instructions Manual), surface water, on-siteor off-site landorincineration, POTW, or other (specify) and control technology, if any,that will be used tolimiut the release ofthe new substanceto the environment. (14)- Identify byproducts which may resualt from theoperation. (3), (5), (8), (lb),(13) and(15)- Mark0X) this columnif anyoftheproceeding entries are confidential business information(CBI). Letter #of CBI Duration CBI Protective Equip./ %in CBI Release Amniiit of CBI Mediaof Release CB

of Workers Of Engineering Controls/ Form- Number New &Control Act- Exposed4 Exposure Physical Form and % ulation Substance Tcnlg ivity new substance Released Tdnlg (1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) Q Oa) 1 (lOb) 0V1 (12) (13 1 I A 2-8 0.2-1 11-100 X 1 0-0.01 1 0-10 Air hour !days kg/bat' kg/bal Dust Collection B 2-8 0.2-0.311-100 X Not 0 10 hour days Applicl C 2-8 0.2-1 1-100 X 1 0-0.1 10-10 Air I Dust Collection hour days ___________kg/bat I kg/bal D 2-8 0.2-1 120X 2 0-0.011 0-10 Air 1-00I Dust Collection hour days I _______I___ kg/bai kg/ba

___________ 1 (14) - Byproducts: None Known(1 11 %ark(X)thisbox ifyouattachaontnuationsheet. Please see page 10a for continuation of Partlill, Sect 8.2. FORM EPA7710-25 (Rev. 5-95) Page 1 

# 00 2

### Part 11I- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -- 

### Continlued SSection 83- UNDUSTRIAL SITES CONTROLLED BY OTHERS

,-ormelte section 6itor typical processing or use operations invoiving tne new cjiemicai substance at sites You co not controti1m gersdo nothave to cwmprntc this section tor operations outside the U.S, however. vou must report any processing or use activities after import. 'the lnistrudaions ManuaL. Coinvlete a sepanmtesection 8 for ec tvve or rrpcessing'. or use overation invoiingthe newchernicaisubstance. Ifthe me operation ispertormed atimore than one site describe the typical operanion common to these sites. Identity additional sites on a continuatio t eet. 

### I. Operation L)escnption - To claim iniormation in t-russection as conndcentiai. circle or brac.Ket the specink= anion thatyou clam as coridential. (1) - Diagram the mator unit operation steps and chemticat conversions. including interim storage and tsport containers tspecilv- e.g. 5 gallon padls, 73zallon orums. rail cars, tank trucks. etc). On the adigram. icientitv by letter and bniefly describe e-worker activity. (2) -- Provide the identity, the approximate weight (by kg/day or kg/batch, on an 100% new cnemiual substance beasis), an trY point of all feedstocks (including reactants, 5oivents ana catalysts. etc) and oi all products, recvcle streams, ano wastes, include cleanin ernicals (note trequencv ifnot used daily or per bitch). (3)- Identify by number the points at release, inciuding small or intermittent re es, to the environment or the new chemiucal substance. (4) Please enter the # or sites (remember to identity the locations ot these sites on a ntinuation sheet):

Mark (X)this box ifyou attach a continuation sheet. 2. Worker Exposure/Environmenal Release (1) - From the diagram above, provide the letter foreach worker activity. Complete 2-8 for each worker activity described. (2) - Estimate the number of workers exposed for all sites combined. (4) - Estimate the typical duration ofexposure per worker in (a) hoursper day anid (b)days per year. (6)- Describe physical form ofexposure and %new chemiucal substance (if in mixture), and any protective equipment and engineering controls used to protect workers. (7)- Estimate the percent ofthe new substance as formulated when packaged or used as a final product. (9)- From theprocess diagram above, enter the number ofeach release point. Complete 9-13 for each release point identifiedt. (10) - Estimate the amount ofthenew substance released ta) directly to the environment or (b) into control technology to theenvironent (in kg/day or kg/batch). (12) - Describe mnedia ofrelease i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, P01W, or other (specify) and control technology, Jt any, thatwillbeused tolimit the release ofthe new substance to the environment. (14) - Identjy byproducts which may result from the operation. (3).(5),(8). (1), (13) and (15) - Mark (X)this column ifany oi the vroceeding entries areconfidlential business iformation (CBD. Letter #of CBI Duration CBI Protective Equip. / ill CBI Release Amount or CB Media ofRelease CBl

of Workers of Engineering Controls/ Form- Number New AtControl Act- Exposed Exposure Physical Form and % ulation Substance Technology ivity new substance Released (1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) (1 Oa) 1 0Ob) 0V (12) (13) E 2-8 0.5-1 11-100 X 3Waste Disposal hour days F 1-2 8 1-100 

### XI Waste Disposal hours IdaysI G 0-2 4-8 I1-100 Not I Applic 0 I 0

_______ hoursI days_____________

-- 

### L...

- (14) - Bvproducts: 

# EMark tX) this box ifyou attach acontinuation sneet. FORM EPA 7710-25 (Rev. 5-95) Page 108a 

## 0 0 02

### Part 11, 

### Section B.I., Operation Description7\TI Explanation of Assumptions 

## JJU'I
The Thermoset Organic Coating formulations are proprietary and unknown to the PMN Substance Supplier: however, some assumptions have been made as follows: 1. The PMN Substance concentration in the Premix and/or Mill Stage may be [ 1. Its concentration will be approximately 

### [ I after letdown and at the final package stage. 2. A variety of resin systems are possible, these include: Epoxy Urethane Acrylic Polyester Alkyd Polyester-Silicone Fluoro Polymers (Poly Vinylidene Fluoride - PVDF) 3. Crosslinkers may include: Hydroxy alkyl amides Melamine-formaldehyde Amides Amines Isocyanates Anhydrides 4. Solvents may include: Glycol Ethers Esters Ketones Alcohols Aromatic Hydrocarbons Aliphatic Hydrocarbons Water It should be noted, that the paint or coating systems, which utilize the PMVN substance, are expected to be predominantly solvent based. 5. Catalysts, surfactants, and paint additives are confidential and too numerous to try to enumerate. 6. Milling equipment is typically media mills such as bead, sand, or ball mills. Bead and sand mills may utilize apremix stage but do not require it. Ball mills, typically, will not have apremix stage. High speed disk type dispersers (Cowles) may be utilized and typically will not have any premix stage. Three-roll milling may still be utilized for smaller batches. 3-Roll milling almost always requires premixing ingredients prior to milling. 10 b 0

# 1DIF J

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# 1 NT

# 1AL

!tSCV \V0W RI)i :111[) )(12 0 302

# Part 11, Section B.1. Operation Description Incorporation of PMVN Substance into Thermoset Organic Coatings (1,A)

10 d 

# QAM~fo000P3

# Part 11, Section B.1. Operation DescriptionIncorporation of PMVN Substance into .3LILUP~IALhermoset Organic Coatings (1,B3)

10 

### e 

# Cfl~if~u0OOO'

# Part 11, Section B.1. Operation Description Incorporation ofthe PMN Substance into 

# JON~EIT1~LThermoplastic 

# Materials (1,C)

10f 

# CONF~F;~J~ 0 0072

# Part 11, Section B.1. Operation Description OffSite Use ofThermoset Organic Coatings which contain the PMN Substance (11, A) 

# CONFIDENIIAL



# GONFBENT]AL
LGS.C\HGW\[ 1,1.PRS:S7: 3/30/1999 

### log 

## 0 0 02G

# Part 11, Section B.1. Operation Description Off Site Use ofThermoset Organic Coatings which contain the PMN Substance (11, B) 

# CONFJBEN TI1AL

CDaENTI~l

LGS:G\HGW\[ JO.PRS.S8: 3/30/1999 

### 10 h 

# 00,0027

# Part 11, Section B.1. Operation Description Off Site Use ofThermoset Organic Coatings which contain the PMN Substance (11, C) 

# CONFIDENTIAL

LGS CDHGW\j JO1.PRS:S9; 3/30/1999 10 

# 0000213

# Part 11, Section B.1. Operation Description OffSite use ofGlass Enamels which contain the PMN Substance (11, D)



# CONFIDENTIAL
LGS.CHGW\( j0l.PRS:S1O, 3!'30/1999 10 

### j 

# 000029

# Part 11, Section B.1. Operation Description Off Site Use Thermoplastic Resins which contain the PMN Substance (11, E)

10k LGS.C'HGW\ JO1.PRS.Sl1, 3130/1999 

# f lf G.I 0, 

# 000030

## OPTIONAL POLLUTION PREVENTION INFORMATION Toclaim information in thissection asconfidential circle orbracket the specific informationthat you claim asconfidentiaL 

## In this section you mayprovide information notreported elsewhere inthis form regardingyour efforts to reduce orminimize potential risks associated with activities surrounding manufacturing, processing, use and disposal ofthePMN substance. Pleaseinclude new information pertinent to pollution prevention, including source reduction,recycling activities and saferprocesses orproducts available duetothenew chemical substance. Source reduction includes thereduction inthe amountortoxicity ofchemical wastes bytechnological modification, process and procedure modification, productreformulation, rawmaterials substitution, and/or inventory control. Recycling refers to thereclamation ofuseful chemical components fromwastes that would otherwise be treated orreleased as air emissions orwater discharges, orland disposal. Descriptions ofpollutionprevention, source reduction and recycling should emphasize potential riskreduction subsequent tocompliance with existing regulatory requirements and can beeither quantitative orqualitative. 71he EPAisinterested in this information toassess overall netreductions intoxicityorenvironmental releases and exposures, notthe shifting ofrisks to other environmental media ornon-environmental areas (e.g., occupational or consumer exposure). Inaddition, information ontherelative costor performance characteristics ofthe PMN substance topotential alternatives maybe provided. All information provided inthissection will betakeninto consideration during thereview of this substance. Seethe revised InstructionsManual thatincludes aPollutionPrevention Manual for guidance and examples. Describe theexpected netbenefits, such as (1)an overallreduction inrisktohuman health ortheenvironment, (2Zareduction in thevolume manufactured; (3) areduction inthe generation ofwaste materials through recycling, source reduction orother means. (4) areduction inpotential toxiity orhuman exposure and/or environmental release; 

### (5)ant increasein product performance, adecrease inthecostofproduction and/orimproved operation efficiency ofthenewchemical substancein comparison to eisig chemical substances used in similarapplications; or(6) the extenttowhich thenewchemical substance maybea substitute for anexisting substance thatposes a greateroverall riskto human health or theenvironment.

Please see attached Optional Pollution Prevention Information pp Ila-1ib.



# [Mark (X)this 

### box if

### you attach acontinuauon shoet. FORM EPA 7710-2S CRUV.S-M5 Page 11CO0 

### 3

# CONFIDE[NTIAL Part 11, Section B.2., Worker Exposure/Environmental Release Explanation ofAssumptions for the PMN Substance of

## r,

During the manufacture ofthese organic coatings, the point for worker exposure Is greatest during the addition ofthe PMN substance, in powder form, to the resin, solvents, surfactants mixture at either the Premix or Mill stage. The concentration ofthe PMN substance Is estimated to be roughly in the Premix and/or Mill stage. This concentration Is then lowered to the final level of roughly [ in the Letdown stage. The concentration ofthe PMN substance will be predominantly dependent on its performance In the various coating types and hence is unknown at this time. The number ofworkers exposed, to the PMN substance, Is roughly estimated to be 2to 8 combining the employees ofthe initialfacilities. The dust or inhalation exposure to the PMN substance, In its powder form, will be mitigated by mostly local ventilation and If necessary, by respirators with particulate cartridges. The duration of exposure is difficult to estimate. As many ofthe manufacturing processes are assumed. Roughly five to 20minutes may be required to add the PMN substance to the Premix or Mill stage per batch. This length oftime ofexposure is obviously dependent upon the batch size and the time required to add the PMN substance tothe Premix or Mill materials. And It Is assumed that abatch can be prepared in one day (or an eight hour shift). To totally consume the estimatedkilograms of PMN substance in the firstyear, would require I batches Ifonly jofthe PMN substance were utilized. Because there are so many factors which have not been established as yet, it is very difficult to estimate a-rangeof batches. Hence, a rough range of 1to 5batches will be assumed. Under the Worker ExposurelEnvironmental Fate, Item 10 asks to "estimate the amount of new {PMN) substance released (a)directly to the environment or (b)into control technology to the environment (in kg/day or kg/batch)." Because the manufacturing process and product formulation are proprietary; this aspect is very difficult to estimate. However, due to productivity and cost Issues, loss ofthe PMN substance will be minimized as much as possible. Ifa500 gallon batch is prepared with the PMN substance concentration of [30%] utilized, as aworst case scenario, then cg of PMN substance will be added to the resin mixture at either the Premix or Mill stage. If dust collection equipment, such as Cerdec's Pulse Jet Baghouse Collector, were to be utilized, with a99.9% efficiency, a loss of PMN substance to the control equipment might be roughly a half percent (0.5%). It should be noted that this Is double the loss of PMN substance at any one dust collector spot described In the Process description on pages 8a and 8b. This half percent loss would then translate to approximately kilograms to the control technology. At the 99.9% efficiency, this then translate to a Ikilogram loss per batch ofthe PMN substance to the environment or [' kilograms during a100 batch campaign. These are gross estimates based on a number ofassumptions and limited technical knowledge ofthe coating processes which may to used. This loss of PMN substance will predominantly be released tothe air. There Is some potential for releaseto water, especially If equipment Is cleanedwith water. However, this possibility Is low as most ofthe equipment is expected to be cleaned with solvents. 10 c

LGS:C:\WINWORD\[BIMNJO2.D0C:3/22/1999 

# oeO00~

# CONFIDENTIAL Page 1of 

### 2 

## OPTIONAL POLLUTION PREVENTION INFORMATION for the PMN Substance The use ofthe PMN substances coatings and plastics, will have improved product performance, reduction in risk to both human health and the environment and reduce the generation ofhazardous waste in comparison to the use ofcurrent products such as carbon black (CAS # 1333- 86-4, C.I. Pigment Black 7) chrome iron black (0.1. Pigment Green 17, CAS # 

## 13 17-63-1, or Green 17), and chrome iron nickel black (C.1. Pigment Black 30, CAS # 71631-15-7*, or Black 30). coatings are used in a variety ofindustries such as architectural, automotive, aerospace, marine and military. The various coatings or plastics are used on ships, oil derricks, buildings, homes, storage tanks, airplanes, military field equipment, cars, etc. to reduce the amount will be requi

-- 

## The PMN substances have superior - 

## properties in comparison to the carbon black, Black 30, or Green 17 as evidenced in laboratory testing. The PMN substance will be easier and safer to use for the manufacture ofthe various coatings and-plastics than especially the carbon black. The density of the average carbon black, used in coatings applications, is 1.8 grams per centimeter cubed (g/cm3

### ) 

## while the density ofthe PMN substance is 7.14 g/cm 3

### . 

## Carbon blacks typically used in coatings applications have an average particle size ofroughly 10 to 30 nanometers. The average particle size ofthe PMN substance, as measured, is approximately ons. The carbon black being nearl) times smaller than the PMN substance. The combination ofgreater density and larger average particle size mean that the manufacture coatings will be a lot less dusty when the PMN substance is used in place ofthe carbon black, thereby reducing the inhalation hazard for the manufacture ofthe coatings or plastics. Also, ifoperations are less dusty, there is less product loss. Thereby reducing the loss ofproduct into any engineering controls and ventilation, reducing disposal. The better physical properties ofthe PMN substance will reduce the inhalation hazard to employees and reduce the amount ofmaterial which would have to be disposed.

Twc.cabassnmnpolprev.DOC Page 11lA 

# O,0WO33

# * uJONFIJJENTIIAL Page 2of2 

## OPTIONAL POLLUTION PREVENTION INFORMATION for the PMN Substance [Yttrium,Strontium,Barium,Calcium Manganese Oxides] [PC# 3997C] In addition to the the PMN substance has the advantage ofbeing iron free. In the coloration ofPolyvinyl chloride (PVC) for weatherable applications (such as vinyl siding or window profiles) the use the Green 17 and Black 30 pigments is widely accepted due to the low heat build up properties. However, issues on recycling these materials exist because they contain iron. Ifthe total iron level gets too high, degradation ofthe PVC during processing may occur. The PMN substance would allow for recycling ofthe PVC without concern for iron contamination. Better long term weathering performance for the PMN substance over carbon black would be expected d, o. Coatings and plastics with carbon black tend to crack or delaminate due to its p,- - 

## Therefore, a longer service life should be expected for parts manufactured with the PMN substance instead ofcarbon black and hence reduce potential waste. Chromium compounds and potentially nickel compounds must be carefully handled for disposal. Leachability studies must be run to determine whether or not the waste should be classified as hazardous (inthe case ofno other category or classification for hazard) . Currently, this work would not be necessary as none ofthe components-of the PMN substances-are controlled as hazardous waste. Ifthe materials containing the PMN substance are not otherwise classified as hazardous for disposal, the PMN substance would not need to be disposed ofas a hazardous waste which would reduce hazardous waste in comparison to the products containing Green 17 or Black 30. The PMN substance is expected to out perform carbon black containing coatings and plastics in terms of
- - 

### _7, 

## and weathering durability. Its higher cost can be offset by the extended life and higher performance ofthe ware in which it is use and the energy savings associated with areduction ofcooling costs. Overall, the PMN substance, when used in place ofcarbon black, Green 17, or Black 30, will _- 

## tht ing. Because ofthe high density and lower dusting, its use will reduce employee inhalation exposure during manufacture, and ofgreat importance, it will reduce hazardous waste containing chromium and nickel compounds.

Twc.cabassfrmpolprev.D0C Page 11iB

### 7-art III-- .IST OF ATTACHMENTS ':jcf eoflhtnuanon '.Oect lor %crifonscr Inctorin ano test data and other data (including ph-vNical/chemical properties and nw~turc etivitv intormationt. ana oriionai intormation itter this Page. Ctjrlv identity the attachment ana thetiomnott the torm to * ura it roiatcs. it irprnpriatc. Number coflsx-utiveiv the races otiIhe attacriments. In the column ociow. enter the inclusive page :nwors or ecar attachment. .%.irk tX) the 'Contidennal" box next to any attachment name you claim as contidlential. Read the Instructions Manual tur * :rance on how to ciaim any intormation in in attachment as contidennal. You must include with the sanitized copvot the notice *rm a %liniti7.ed version ot any attachment in wnich You ciaim intormaton ascontidlential. A\ttachment namc Attachment Confi. page number(s) dential 

### NMaterial Safety Data Sheet (MSDS) (Attachment 1) 14-67 Product Label (Attachment 2)687 CAS Inventory Expert Service Report BX Product Structure B4 Process Description 1,PW4 Substance Manufacturing Operation 8a Process Description 11, P191 Substance Manufacturing Operation Sb iProcess Description 111, On Site Processing of the P141 Substance Sc Part 11, HR&ER (cont) Sect A (cont) (for p. 8a processing) 9& Part 11, HIRER (cont) Sect A (cant) (for p. Ob processing) 9b Part 11, HRIER (cont) Sect A (cant) (for p. Sb processing (cont)) 9C Part 11, HRIER (cont) Sect A (cant) (for p. Sc processing) 9d Part II,HR&ER(cont) Sect 8, Part 2 

### ~ ~-10a Part 119 Operation Description, Explanation of Assumptions 101b Part 11, Section B.2., Worker Exposure/Environmental Release Explanation of Assumptions 10c Part 11, Section 6.1., Operation Description (IA) 10d Part 11, Section 5.1., Operation Description (16) 1011 Part 11, Section B.1., Operation Description (IC) lOf Part 119 Section 8.1., Operation Description (IIA) log Part 11, Section B.1., Operation Description (11B) 10h Part 11, Section 6.1., Operation Description (IIC) 10i 

# fPart 11, Section B.l.9 Operation Description (111D) l0j Part 1I, Section 6.1., Operation Description (lIE) 10k Optional Pollution Prevention Information 

### Ila - b Part III, List of Attachments 12 - 12a XX arkX)

hi bo d ouattch cotiuaton het. Enter the attachment name and number. Part III, List of AttacIlents (contl -:R.%EPA 7710-25 (Rev.5-95) Page 12

### Part ill -- 

### KIST OF ATTACHMENTS (continued)

-c ontinuation snits tor wecnons or thetonn ana ti t oa~a ind other data tincluding privsicalchemicai properties and nicture,,.Idivitv intormationi. ana otionaI in iormatin 3:,;L'r ti vacc. keriv identityv the attachment and thest'ction or rte torm to ntcni it rotates. it appropriate. Number cnn-Kxutivo'Iv ino ractn or tne attachments. Iii the cotumn below.onter the inclusivepage iimtx'rs ot eicn attachment. 'Aark t.\ the Conticdential" box next to any attachment name VO~U ciaim as contidential. Reid the Instructions Manual for nliuanceon how to claim any inrormation in in attacriment as contidcnral. You must include with thc sanitized copy cot the notice 'rn a'.jniti?.ed version ot any attachment in wnich vou ciaim intormatbon as conidential. \ttahmet nae Atachment Confi- %ttachmentt naeriz umberts) dential Attachmient 3. Particle Size Measurement 74-76 Attachmnent 4. X-Ray Diffraction Patterns 77-86 Attachment 5, Evaluation of Risk 87-90 Attacmnent 6, Air Monitoring Results 91 Attachment 79 Solubility Data 9-0 Attachment 8, DMC2 Overview of Regulatory Compliance and Capabilities 103-112



# DMark tX) this box ii vou attach acontinuation sheet. Enter th~e attachm~ent name and number. FORM EP.'\710-25 tKev. 5-95) rage 12aU 

### U 3PHYSICAL AND CHEMICAL FROPERTTES WORKSHEET To assist EPA's review of physical and cmical provernesa ata, please complete the tollowine worksheet for data you provide and include it in the nonice. ldentiiv the property measured, the page oi the notice on whi the propmrt appears. the value of the propert. the units in which the property is measured (as necessary), and whether or not the property is clained as confidential. The physical stateof the neat substance sriould be provided. Thes measured properues stiould be tor the neat (10096 pure) chemiical substance. Properties that are measured for mjuxrures or formulations should be so noted (% PMN substance in - ).You are not required to submiut this worksheet: however. EPA strongly recommends that youdo so.as it will stmphfv review and ensure that conndiential information is properly protected. You should submit this worksheet as asupplemnent to your subission of tet data. This worxsheet is not asubstitute for submission of test data. Proprty alueMmajwd CotitPrpryMark (X) if Page Valu dentl (a) provided number 1IW Mak0 (b) (c) Mar 00 Physical state of neat substance Powder x i5s ... L 

### (s) - 

### a)....... W~

__ Vapor presure 20 6C0 E OTempverature TOtS Density/relative density 7.14 g/cmn3 N Solubility

0 Temperature 9 Solvent / Solubiltv in water 0 Tempieraiture OC
Meltinst temoerature 9____

____ C Boilne/subimation temperature tf pressure

____ Spectra X-Ray Diffraction xI See Attachment N X 77-86 Dissociation constant

____ Particle size distribution See Attachmnent 3 

### x 74-76 micror N Octanol/water partition coelficient

___ Henry's Law constant Voitalization from water 0 E Vaitalizationfrom soil 0 E pH 0 concentration

_________________ Flammability

___ Explodabilitv_____ Adsorption /craeffient Other - Specify 

# I I___

### CUSTOMER - 

### US EPA/OPPT/NEW CHEMICALS BRN Page: 1 MATERIAL SAFETY DATA SHEET Prepared: 08/10/00 EMERGENCY PHONE: dmc2 CHEMTREC (800) 424-9300 DegussaMetalsCatalystsCerdec This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Lucy 

### Sten Product Safety Specialist SECTION I - 

### IDENTITY INFORMATION
TRADE NAME CAS NUMBER :Not 

### Available PRODUCT CODE FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: This material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

-Skin, 

### eye and respiratory irritant. SECTION II - 

### HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

PAGE 14 0 -'

### Page: 02 MATERIAL SAFETY DATA SHEET 1)

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products.- Ingredients CAS NUMBER ACGIH - 

### TLV OSHA - 

### PEL GREEN R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. BARIUM COMPOUND

Total Dust TWA 10.0 mg/M3 10.0 mg/M3 RESP 5.0 mg/M3 MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3 STEL 3.0 rng/M3 3.0 mg/M3

SECTION III - 

### PHYSICAL DATA APPEARANCE :Green 

### Powder WEIGHT PER GALLON :N/AV 

### BOILING RANGE N/AP VOC :0 

### 01 (See Note in Section XII -Addendum) 

### VAPOR DENSITY :Non 

### Volatile EVAPORATION RATE Non Volatile SOLUBILITY IN WATER :Insoluble

PACE 15

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA FLASH POINT N/AP FLAMMABILITY CLASS NON-COMBUSTIBLE LOWER EXPLOSION LIMIT N/AP UPPER EXPLOSION LIMIT :N/AP 

### EXTINGUISHING MEDIA: Water.
FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - 

### REACTIVITY DATA STABILITY : 

### Stable HAZARDOUS POLYMERIZATION : 

### Will not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known.

PAGE 16 001'

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION V -REACTIVITY 

### DATA (cont.) HAZARDOUS DECOMPOSITION: Will not occur.
SECTION VI -HEALTH 

### HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: This product contains mixed metal oxide pigment(s) which consist of manganese in combination with other materials. CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence.

page 17 

## 000011

### Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA (cont.)
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention. SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.

PAE 18 

# 001

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VII - 

### TOXICOLOGY INFORMATION (cont.) TOX ICOLOGY INFORMATION
SECTION VIII - 

### SPILL OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal. WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
EYE PROTECTION: Wear safety glasses or goggles to protect against exposure.

PAGE 19 

# (3y94

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION IX - 

### SPECIAL PROTECTION INFORMATION (cont.) RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations. OTHER PROTECTIVE EQUIPMENT: None specified.

SECTION X - 

### SPECIAL PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only.

PAGE 20OG}4Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION
SARA 313 TITLE III - TOXIC CHEMICALS LIST: 1000% Barium Compound .501 Metal As Ba 

### 100% Manganese Compound 40% Metal As Mn 

### PENNSYLVANIA RIGHT-TO-KNOW ACT: Green R&d Pigment Not Available E E =Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical Substance Inventory. Consequently this product is presently available only in quantities necessary for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII - 

### ADDENDUM DEFINITIONS AND ABBREVIATIONS Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number

PAGE 21 

### COO4

### Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - 

### ADDENDUM (Cont.) EPA = 

### Environmental Protection Agency TARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP = 

### Not Applicable N/AV = 

### Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL = 

### Permissible Exposure Limits SARA = 

### Superfund Amendments and Reauthorization Act STEL = 

### Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA = 

### Toxic Substance Control Act TWA = 

### Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PAGE 22

### CUSTOMER -US 

### EPA/OPPT/NEW CHEMICALS BRN Page: 1 MATERIAL SAFETY DATA SHEET Prepared: 08/10/00 EMERGENCY PHONE dmc 2 CHEMTREC (800) 424-9300 DegussaMetalsCatalystsCerdec This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Lucy 

### Sten Product Safety Specialist SECTION I - 

### IDENTITY INFORMATION
TRADE NAME :, 

### CAS NUMBER :Not 

### Available PRODUCT CODE FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

-Skin, 

### eye and respiratory irritant. SECTION II - 

### HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

PAGE 23 

# 0000T7

### Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH - 

### TLV OSHA - 

### PEL BROWN R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. BARIUM COMPOUND

Total Dust TWA 10.0 mg/M3 10.0 mg/M3 RESP 5.0 mg/M3 MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3 STEL 3.0 mg/M3 3.0 mg/M3

SECTION III - 

### PHYSICAL DATA APPEARANCE :Brown Powder WEIGHT PER GALLON :N/AV BOILING RANGE :N/AP 

### VOC :0 0- (See Note in Section XII -Addendum) 

### VAPOR DENSITY :Non 

### Volatile EVAPORATION RATE :Non 

### Volatile SOLUBILITY IN WATER :Insoluble

PAGE 21*

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA
FLASH POINT N/AP FLAMMABILITY CLASS :NON-COMBUSTIBLE 

### LOWER EXPLOSION LIMIT :N/AP 

### UPPER EXPLOSION LIMIT :N/AP EXTINGUISHING MEDIA: Water. FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - 

### REACTIVITY DATA STABILITY : Stable HAZARDOUS POLYMERIZATION : Will not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known.

PAGE 25 

# 000049

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION V -REACTIVITY 

### DATA (cont.) HAZARDOUS DECOMPOSITION: Will not occur.
SECTION VI -HEALTH 

### HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: This product contains mixed metal oxide pigment(s) which consist of manganese in combination with other materials. CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence.

PAGE 26 

# 000050

### Page: 05 MATERIAL SAFETY DATA SHEET R1

SECTION VI - 

### HEALTH HAZARD DATA (cont.) MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention. SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.

PAGE 27 

# 000051

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VII -TOXICOLOGY 

### INFORMATION (cant.) TOXICOLOGY INFORMATION
SECTION VIII -SPILL 

### OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal. WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
EYE PROTECTION: Wear safety glasses or goggles to protect against exposure.

PAGE 28 

# 000052

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION IX - 

### SPECIAL PROTECTION INFORMATION (cont.) RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations. OTHER PROTECTIVE EQUIPMENT: None specified.

SECTION X - 

### SPECIAL PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only.

PACE 29 

# 000053

### Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - 

### REGULATORY INFORMATION SARA 313 TITLE III - 

### TOXIC CHEMICALS LIST: 100% Barium Compound .57% 

### Metal As Ba 100% Manganese Compound .23% 

### Metal As Mn PENNSYLVANIA RIGHT-TO-KNOW ACT: Brown R&d Pigment Not Available E E = 

### Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical Substance Inventory. Consequently this product is presently available only in quantities necessary for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII - 

### ADDENDUM DEFINITIONS AND ABBREVIATIONS: Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number



# 000054 PAGE 30

### Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - 

### ADDENDUM (Cont.) EPA = 

### Environmental Protection Agency IARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP = 

### Not Applicable N/AV = 

### Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL = 

### Permissible Exposure Limits SARA = 

### Superfund Amendments and Reauthorization Act STEL = 

### Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA = 

### Toxic Substance Control Act TWA = 

### Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PAGE 31 

# 000055

### CUSTOMER - 

### US EPA/OPPT/NEW CHEMICALS BRN Page: 1 MATERIAL SAFETY DATA SHEET Prepared: 12/21/99 EMERGENCY PHONE: Cerdec Corporation CHEMTREC (800) 424-9300 Drakenfeld Products This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Jeff 

### Miller Environmental Engineer SECTION I - 

### IDENTITY INFORMATION
TRADE NAME CAS NUMBER :Not 

### Available PRODUCT CODE FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

-Skin, 

### eye and respiratory irritant. SECTION II - 

### HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small 

# 00005G PACE 32

### Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH - 

### TLV OSHA - 

### PEL BROWN R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. MANGANESE COMPOUND



### Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3 STEL 3.0 mg/M3 3.0 mg/M3

SECTION III - 

### PHYSICAL DATA APPEARANCE :Brown 

### Powder WEIGHT PER GALLON : 

### N/AV BOILING RANGE : 

### N/AP VOC : 

### 0 %(See Note in Section XII -Addendum) 

### VAPOR DENSITY :Non Volatile EVAPORATION RATE : Non Volatile SOLUBILITY IN WATER : Insoluble SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA
FLASH POINT : 

### N/AP FLAMMABILITY CLASS : 

### NON-COMBUSTIBLE LOWER EXPLOSION LIMIT :N/AP 

### UPPER EXPLOSION LIMIT :N/AP
PAGE 33 

### 0000517

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA (cont.)
EXTINGUISHING MEDIA: Water.
FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.
SECTION V - 

### REACTIVITY DATA STABILITY : 

### Stable HAZARDOUS POLYMERIZATION : 

### Will not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known. HAZARDOUS DECOMPOSITION: Will not occur.

PAGE 34 

# 000058s

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: This product contains mixed metal oxide pigment(s) which consist of manganese in combination with other materials. CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical

PAGE 35 

# 000059

### Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA (cont.) EYES: attention. SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.
SECTION VIII - 

### SPILL OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal.

PAGE 36 

# 000060O

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - 

### SPILL OR LEAK PROCEDURES (cont.) SPILL PROCEDURES:
WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
EYE PROTECTION: wear safety glasses or goggles to protect against exposure. RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations. OTHER PROTECTIVE EQUIPMENT: None specified.

PAE 37 

# 000061

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - 

### SPECIAL PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: vacuum and dispose in accordance with federal, state and local regulations. For industrial use only. SECTION XI - 

### REGULATORY INFORMATION SARA 313 TITLE III - 

### TOXIC CHEMICALS LIST: 100% Manganese Compound .51% 

### Metal As Mn PENNSYLVANIA RIGHT-TO-KNOW ACT: Brown R&d Pigment Not Available E E = 

### Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical Substance Inventory. Consequently this product is presently available only in quantities necessary 

# 000062 PAGE 38

### Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - 

### REGULATORY INFORMATION (cont.) TOXIC SUBSTANCE CONTROL ACT (TSCA): for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII - 

### ADDENDUM DEFINITIONS AND ABBREVIATIONS Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number EPA = 

### Environmental Protection Agency IARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP = 

### Not Applicable N/AV = 

### Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL = 

### Permissible Exposure Limits SARA = 

### Superfund Amendments and Reauthorization Act STEL = 

### Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA = 

### Toxic Substance Control Act

PAGE 39 

# 0000G3

### Page: 09 MATERIAL SAFETY DATA SHEET RD SECTION XII - 

### ADDENDUM (Cant.) TWA = 

### Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PAGE 40 

# 000064

### CUSTOMER -US 

### EPA/OPPT/NEW CHEMICALS BRN Page: 1 MATERIAL SAFETY DATA SHEET Prepared: 12/21/99 EMERGENCY PHONE: Cerdec Corporation CHEMTREC (800) 424-9300 Drakenfeld Products This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Jeff 

### Miller Environmental Engineer SECTION I - 

### IDENTITY INFORMATION
TRADE NAME CAS NUMBER :Not 

### Available PRODUCT CODE FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CER 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

-Skin, 

### eye and respiratory irritant. SECTION II - 

### HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

PAGE 4*1 

# 000065

### Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH - 

### TLV OSHA - 

### PEL BLACK R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3 STEL 3.0 rng/M3 3.0 mg/M3

SECTION III - 

### PHYSICAL DATA APPEARANCE :Gray 

### Powder WEIGHT PER GALLON :N/AV 

### BOILING RANGE :N/AP 

### VOC :0 %(See Note in Section XII -Addendum) 

### VAPOR DENSITY :Non Volatile EVAPORATION RATE :Non 

### Volatile SOLUBILITY IN WATER :Insoluble SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA
FLASH POINT N/AP FLAMMABILITY CLASS :NON-COMBUSTIBLE 

### LOWER EXPLOSION LIMIT :N/AP 

### UPPER EXPLOSION LIMIT :N/AP

PAGE 42 

# 000066

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA (cont.) EXTINGUISHING MEDIA: Water.
FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - 

### REACTIVITY DATA STABILITY : Stable HAZARDOUS POLYMERIZATION : Will not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known. HAZARDOUS DECOMPOSITION: Will not occur.

PAGE 43 

# 00006?

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention.

PAGE 

### 4400G

### Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA (cant.) SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.
SECTION VIII - 

### SPILL OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal.



# 000069 PAGE 45

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - 

### SPILL OR LEAK PROCEDURES (cont.) WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
EYE PROTECTION: Wear safety glasses or goggles to protect against exposure. RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations.
OTHER PROTECTIVE EQUIPMENT: None specified.



## PAGE 16 

## 0 0 070,

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - 

### SPECIAL PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only. SECTION XI - 

### REGULATORY INFORMATION SARA 313 TITLE III - 

### TOXIC CHEMICALS LIST: 1000i Manganese Compound .29%- 

### Metal As Mn PENNSYLVANIA RIGHT-TO-KNOW ACT: Black R&d Piment Not Available E E = 

### Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical Substance Inventory. Consequently this product is presently available only in quantities necessary PAGE 

### 47 

## 0000,71

### Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - 

### REGULATORY INFORMATION (cont.) TOXIC SUBSTANCE CONTROL ACT (TSCA): for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII -ADDENDUM 

### DEFINITIONS AND ABBREVIATIONS Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number EPA = 

### Environmental Protection Agency IARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP = 

### Not Applicable N/AV = 

### Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL = 

### Permissible Exposure Limits SARA = 

### Superfund Amendments and Reauthorization Act STEL = 

### Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA = 

### Toxic Substance Control Act

PAGE 

## '&8 

# 000017t2

### Page: 09 MATERIAL SAFETY DATA SHEET
SECTION XII - 

### ADDENDUM (Cont.) TWA = 

### Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PAGE 49 

# 0000713CUSTOMER - US EPA/OPPT/NEW CHEMICALS BRN 

### Page: 1 MATERIAL SAFETY DATA SHEET 

### Prepared: 12/21/99 EMERGENCY PHONE: Cerdec Corporation CHEMTREC (800) 424-9300 Drakenfeld Products This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 -gencies 

### involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Jeff 

### Miller Environmental Engineer SECTION I - 

### IDENTITY INFORMATION
TRADE NAME F 

### CAS NUMBER :Not 

### Available PRODUCT CODE7 FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: 

### This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

- 

### Skin, eye and respiratory irritant. SECTION II - HAZARDOUS INGREDIENTS 

### This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

PAGE 50 

# 0000~74

### Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH - 

### TLV OSHA - 

### PEL BLACK R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 rng/M3 STEL 3.0 mg/M3 3.0 mg/M3

SECTION III -PHYSICAL 

### DATA APPEARANCE :Gray Powder WEIGHT PER GALLON :N/AV 

### BOILING RANGE :N/AP 

### VOC :0 

### 0- (See Note in Section XII -Addendum) 

### VAPOR DENSITY :Non Volatile EVAPORATION RATE :Non 

### Volatile SOLUBILITY IN WATER :Insoluble 

### SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA
FLASH POINT :N/AP 

### FLAMMABILITY CLASS :NON-COMBUSTIBLE 

### LOWER EXPLOSION LIMIT :N/AP 

### UPPER EXPLOSION LIMIT :N/AP

PAGE 51 

# 00Y

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA (cont.) EXTINGUISHING MEDIA: Water. FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - 

### REACTIVITY DATA STABILITY :Stable HAZARDOUS POLYMERIZATION :Will 

### not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known. HAZARDOUS DECOMPOSITION: will not occur.



### PAGE 52 

# oooom1(4

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA. PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical attention.

PAGE 53 

# 0000~77

### Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA (cant..) SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.
SECTION VIII - 

### SPILL OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal.

PAGE 54* 

## 000078

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - 

### SPILL OR LEAK PROCEDURES (cont.) WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
EYE PROTECTION: Wear safety glasses or goggles to protect against exposure. RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations. OTHER PROTECTIVE EQUIPMENT: None specified.

PAGE 55 

# 000079

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - 

### SPECIAL PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and 

### respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: Vacuum and dispose in accordance with federal, state and local regulations. For industrial use only. SECTION XI - 

### REGULATORY INFORMATION SARA 313 TITLE III - 

### TOXIC CHEMICALS LIST: 100%0 Manganese Compound .29% 

### Metal As Mn PENNSYLVANIA RIGHT-TO-KNOW ACT: Black R&d Pigment Not Available E E = 

### Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical Substance Inventory. Consequently this product is presently available only in quantities necessary
PAGE 56 

## 000030

### Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - 

### REGULATORY INFORMATION (cont.) TOXIC SUBSTANCE CONTROL ACT (TSCA): for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII - 

### ADDENDUM DEFINITIONS AND ABBREVIATIONS - Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.0. C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number EPA = 

### Environmental Protection Agency IARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP = 

### Not Applicable N/AV = 

### Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL = 

### Permissible Exposure Limits SARA = 

### Superfund Amendments and Reauthorization Act STEL = 

### Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA = 

### Toxic Substance Control Act



### PAGE 57 

# 008

### Page: 09 MATERIAL SAFETY DATA SHEET

- -9) 

### SECTION XII - 

### ADDENDUM (Cont.) TWA =Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### Volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PACE 58 

# 000082

### CUSTOMER - 

### US EPA/OPPT/NEW CHEMICALS ERN Page: 1 MATERIAL SAFETY DATA SHEET Prepared: 08/10/00 EMERGENCY PHONE: dmc 2 CHEMTREC (800) 424-9300 DegussaMetal sCatalystsCerdec This number is to be used only P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak, Information Phone: 724-223-5900 fire, exposure or accident involving chemicals Prepared By :Lucy 

### Sten Product Safety Specialist SECTION I - 

### IDENTITY INFORMATION
TRADE NAME CAS NUMBER :Not 

### Available PRODUCT CODE FAMILY/CHEMICAL NAME: Pigment. PRODUCT TYPE: Mixed Metal Oxide. HAZARD STATEMENT: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous substance under that standard. The key Immediate Hazards are:

- 

### Skin, eye and respiratory irritant. SECTION II - 

### HAZARDOUS INGREDIENTS This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small

PAGE 59

### Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - 

### HAZARDOUS INGREDIENTS (cont.)
HAZARD STATEMENT: percentage of the starting materials may remain in this product and are considered hazardous under OSHA. The pigment and/or frit ingredient(s) do not have exposure limit values. Exposure limit values for the components are listed beneath each ingredient as a guideline for safe use of these products. Ingredients CAS NUMBER ACGIH - 

### TLV OSHA -PEL 

### BLACK R&D PIGMENT Not Availab Carcinogenicity: This product is not listed as a carcinogen by IARC, NTP or OSHA. MANGANESE COMPOUND



### Dust As Mn TWA 0.2 mg/M3 STEL C 5.0 mg/M3 Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3 STEL 3.0 mg/M3 3.0 mg/M3

SECTION III -PHYSICAL 

### DATA APPEARANCE :Black 

### Powder WEIGHT PER GALLON :N/AV 

### BOILING RANGE :N/AP 

### VOC 0 0- (See Note in Section XII -Addendum) 

### VAPOR DENSITY Non Volatile EVAPORATION RATE :Non Volatile SOLUBILITY IN WATER :Insoluble 

### SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA FLASH POINT :N/AP 

### FLAMMABILITY CLASS :NON-COMBUSTIBLE LOWER EXPLOSION LIMIT :N/AP UPPER EXPLOSION LIMIT :N/AP
PAGE 60 

## 0 0084

### Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - 

### FIRE AND EXPLOSIVE HAZARD DATA (cont.) EXTINGUISHING MEDIA: Water.
FIRE FIGHTING PROCEDURES-SPECIAL: Fire-Fighters should wear self-contained breathing apparatus and full protective clothing when fighting chemical fires. Use water spray to cool nearby containers and structures exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product will not burn. Use appropriate techniques to fight surrounding fire.

SECTION V - 

### REACTIVITY DATA STABILITY :Stable 

### HAZARDOUS POLYMERIZATION :Will 

### not occur CONDITIONS TO AVOID: None Known. INCOMPATIBILITY: None known. HAZARDOUS DECOMPOSITION: will not occur.



# PCE61 

# 000085

### Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA This product contains either pigment(s) that belong to the mixed metal oxide pigment class and/or frit which is an amorphous glassy material. These ingredients have been chemically reacted at high temperatures. They consist of metal atoms and oxygen atoms arranged in unique structures; the toxicological properties have not been thoroughly investigated. A small percentage of the starting materials may remain in this product and are considered hazardous under OSHA.
PRIMARY ROUTES OF EXPOSURE: Inhalation, dermal and ingestion. OVEREXPOSURE EFFECTS: This product contains mixed metal oxide pigment(s) which consist of manganese in combination with other materials. CONTAINS MANGANESE COMPOUNDS: Manganese compounds are not considered toxic by ingestion or skin contact. Chronic inhalation of manganese oxide dust during mining or fumes during steel processing can affect the brain. Symptoms may take more than two years to develop and have included apathy, sleepiness, confusion, compulsive behavior, hallucinations, irritability, loss of balanc e difficulty in walking and impotence. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES: EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart to ensure rinsing of the entire eye surface and lids with water. Get immediate medical

PAGE 62 

# 00008G

### Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - 

### HEALTH HAZARD DATA (cont.) EYES: attention. SKIN: For skin contact, wipe away excess material with dry towel. Then wash affected areas with plenty of water, and soap if available, for several minutes. Get medical attention if irritation occurs. INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. INGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention. PHYSICIAN'S NOTE: None specified. SECTION VII - 

### TOXICOLOGY INFORMATION Toxicology data of some components is available upon request. Please contact the Product Safety Specialist at (724) 223-5900.

SECTION VIII - 

### SPILL OR LEAK PROCEDURES SPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Vacuum or shovel material and place in closable container(s) for disposal.

PAGE 63 

# 000087

### Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - 

### SPILL OR LEAK PROCEDURES (cont.) SPILL PROCEDURES:
WASTE DISPOSAL METHODS: Dispose in accordance with Federal, State and Local regulations.

SECTION IX - 

### SPECIAL PROTECTION INFORMATION VENTILATION: Adequate ventilation should be provided to keep dust and vapor concentrations below acceptable Exposure Limits. Discharge from the ventilation system should comply with the applicable air pollution control regulations. Eliminate ignition sources.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure. EYE PROTECTION: Wear safety glasses or goggles to protect against exposure. RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations. OTHER PROTECTIVE EQUIPMENT: None specified.

PAGE 64~008

### Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X -SPECIAL 

### PRECAUTIONS LABELING INFORMATION: WARNING! Skin, eye and respiratory irritant. Keep away from heat and flame. Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep away from food products. Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet facilities. Use with adequate ventilation. Keep container closed when not in use. FIRST AID: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention. IN CASE OF FIRE: Use water, dry chemical or carbon dioxide. IN CASE OF SPILL: vacuum and dispose in accordance with federal, state and local regulations. For industrial use only. SECTION XI - 

### REGULATORY INFORMATION SARA 313 TITLE III - 

### TOXIC CHEMICALS LIST: 1000- Manganese Compound .390- 

### Metal As Mn PENNSYLVANIA RIGHT-TO-KNOW ACT: Black R&d Pigment Not Available E E = 

### Pennsylvania Environmental Hazardous Substance TOXIC SUBSTANCE CONTROL ACT (TSCA): one or more chemical substances in this product are not yet listed on the TSCA Chemical substance Inventory. Consequently this product is presently available only in quantities necessary
PAGE 65 

# 000089

### Page: 08 MATERIAL SAFETY DATA SHEET DR' 

## 2

SECTION XI - 

### REGULATORY INFORMATION (cant.) TOXIC SUBSTANCE CONTROL ACT (TSCA): for research and development purposes as defined by TSCA. The potential health and environmental risks associated with these new chemical substances are not fully characterized. Thus the use of this product is restricted to those technically qualified individuals having the authority to to manage the use, storage, or handling of the product so as to minimize any risks. SECTION XII - 

### ADDENDUM DEFINITIONS AND ABBREVIATIONS: Note: The V.O.C., listed in Section III, Physical Data, is an estimated/calculated value based upon the EPA Method 24 for determining V.O.C. ACGIH = 

### American Conference of Governmental Industrial Hygienists C (Ceil) = 

### The concentration that shall not be exceeded during any part of the working exposure. CAS = 

### Chemical Abstracts Service Registry Number EPA = 

### Environmental Protection Agency IARC = 

### International Agency for Research on Cancer LEL = 

### Lower Explosion Limit N/AP =Not Applicable N/AV =Not Available NIOSH = 

### National Institute for Occupational Safety and Health NTP = 

### National Toxicology Program OSHA = 

### Occupational Safety and Health Administration PEL =Permissible Exposure Limits SARA =Superfund Amendments and Reauthorization Act STEL =Short Term Exposure Limit. Usually a 15 minute time weighted average exposure that should not be exceeded at any time during a work day. TLV = 

### Threshold Limit Values TSCA =Toxic Substance Control Act

PAGE 66 

# 000090

### Page: 09 MATERIAL SAFETY DATA SHEET
SECTION XII - 

### ADDENDUM (Cant.) TWA = 

### Time Weighted Average. Exposure concentration for a normal 8 hour work day and a 40 hour work week. VOC = 

### volatile Organic Content DISCLAIMER The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or implied is made with respect to the information contained herein.

PAGE 67 

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