TSUA NON-CONFIENTIAL BUSINESS INFORMATION

DOCUMENT DESCRIPTION DOCUMENT CONTROL NUMBER DATE RECEIVED

-Q la - It--0

COMMENTS:DELS

DO[CS NOT CONTAIN CBI
~ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON D.C., 20460

OFFICE OF

~ $~R ~CHEMICAL SAFETY AND

POLLUTION PREVENTION

Notice of Change in CBI Chemical Identity Status

Pre-Manufacture Notice (PMN) P-00-1121

Notice of commencement (NOC) received: 9113/2001

Please be advised that the Confidential Business Information (CBI) claim for the

above referenced substance was dropped by the information submitter in the

NOC.

The identified non-confidential chemical name for this substance as provided in

the NOC is:

MANGANESE STROTIUM OXIDE (MNSR03)

The current TSCA Inventory name is

Manganese strontium oxide (MnSrO3)

CASRN: 12163-45-0

This notice as submitted to the NCIC files on 9/1/201 1

Name of staffer: Jeffrey Santacroce

Position: Asst. NOC Coordinator

Branch: RDMB/IMD/OPPT/OCSPP

CONTAINS NO CB1
SANITARY COPYDaofcp

Form Opme. .11B No. 3 W~12- APPro-l14 s 1-1-6

US.ENVRONNMNTAL PROTECTON AGENCY AGENCY USE ONLYMWEP NOTICE

FOR NEW CHEMICAL SUBSTANCES

DOCUMENT CONTROL OFFICERSaize

SUBSTANCES, 7407 0oMpal Sfltie ~. OFFICE OF POLLUTION PREVENTION

AND TOXIC BTNCS 70

U.S. E.P.A. 401 M STREET, SW

WASHINGTON, D.C. 20460 _______________________________,

in the Premanufacture Notice : =:" 'do // /4

GENERAL INSTRUCMONS M11 [ -6114"N1

- You must provide amU Information mequested in tfam to the extent that i i known to o emamnably aseainable by you. Make reaonable estiate if you do

not have actual data. . Before you completa this faust, you should read &he nAstartions Manual for Prensanufacture Notification (the Instructions Manual is available from the Toxic

Substanrm ot Act (TSCA) Informaton Service by calling Z22554..1404, or faxing 2-SW4S403)

- Uf a user foe has been mittad for this notice f40 C1FR 700.45), indicate in the boxes above. the TS-uee far Idenification sumber you have generatd.

Remember, your user fee ED number mnua &too appear on your corrsponding fee remittance. which isesent to: EPA, HO Accunting Opeations Branch (PM.IM), P.O. 360399K, Pittsburgh, PA ISM-639, Afttn TSCA UserFee.

Part I- GENERAL INFORMATION TMS DATA AND OTHER DATA

You must provide the currently correc Chenlcal Abetracts (CA) Name of the You an mequired to submit all tea data in your possession ormeoniuli

new chemical substance, eoen fyou cila the Identity an confidestiaL.Yumay and So provide adesciption of all other date known to orsreaonably

authorize another person to submit chemical Identity information toryan, but astinable by you, Uf these data am Meated to the halth a&d

your: submision will not be complete and the review wll not begin until EPA rnvrouenaefe of the manufacture, processm, diatibuttiom

receives this information.A letter in support of your submission should In cmmentn. Usk ordisposal of the saw Chemical substance. Slandeof

refemence your TS uses fee identification number. You mumt submit an original litertue liaioea say beesubmliied for data In the open scietific

and two copies of this notie including all tes data. If you claimed any litermure. CnnmiitekordatAtyrritten nEgih a s mr. fdt.

Informsation an coidautial a single saniized copy meum also be submitted. fi- be asutiltad if they o at sofLea n hpe Iteatur you should

cleerly identity whether test data is on the substane oraen an analog. Also,

Pant U - HUMAN EXPOSURE AND ENVIRONMENTAL pR v"j the cemical compamiot of the laseed mateial should be chiudsd.

Fa~oelug are examiples of tat data and other data Data should be

If there amn several manufacture. pnwmag or use operations to be described In submitted accoding to the mquisaumes of 9720M of the Prmuahum

Pant IL setions A and l of this sotice, raipsuduce the sections as ueded. Netification Rule (40 Cax PAAt 721L

Purt IU - LIST OF ATTACIMIENTS TeDat~sa (Clickt Below any included in this notice)

Allach additional sheets it them is not enough space to answersa question fully.

Label each continuation sheet with the correponding ascion heading. In Pant Eswlronminta fate data e te aa I e

13L list these altachmenti, any test data or other data and any optional Hai fet aays Rs sasnrl

information included in the notice. 13elhefesdt

OPTIONAL INFORMATION *Environmental decs data 13 Yes Staudtumuladlvity relationships

You may include any Information th" you waste EPA to consider is evaluating *PbyskAI l~em~caPropertie**E yen Test data not in the posseio

the niew substance. 0 page 12 of this form. space has bees provided for you to or control of the sulamifter

descibe poliltloo pruvention and recycling information you may have regarding Aphscladhe" rorts okbtisoaedntelstag

of this fogn.

So-called "blndlar barnes amn included throughout thin foam for you to indicate TYPE OF N07TCE (nieck Only One)

your willingness to be bound to cta"i tments You maima in thsnotice, such

as use, production volume, protective equipment... This option is intended to

reduce delays that routinely sccompany the developmsent of cousent orders or jJPNOeauau oie

Significant New Use Rules. Except In the case of exemption applications (auck as 1 M rmnfcueNtclC

TWEA, LVE, LOREX) where certain information provided in such modification is QINTERMEDIATE PMN (submitted in sequence with final pmSZct

binding on the aubmltterwhes the Agency approves the exemption application, PMN -W

checking a binding box in this notice do- rniL by Itself prohibit the submitter FM)C- C

from later deviating from the Information (except chemical identity) reported In SNN(infcatNwUeNoie 'T

the form. 13 SNN SgnfcatNe seNtie

L3 7MEA fraut Marketing Exemption Application)

CoN~lDFnA~rrycA~mL 1 LVE (Low Voluame Exemption) 040 CM 723j@ (c)9

You may claim any information in this notice as confidential. To assert a clalm

on the forma, mark 00) the confidential box next to the information that you claim LORIX (Low ReleseILnw Expaosure Exemption)O 0 eW

as confidential. To aert a claim in an attachment, circe or bracket the LRXMdfct

informiation you claim as confidential. If yon ialim infnrmation In the antice, ag LVE Modification 1 L RE Mdfcton

confidentixl- you muttr alga povide a sa.nitized venins of the notice tnduding

-arlahinent) For additional instructions en claiming Informatdons IS "VSACNOIATDPN f e

confidential, read the Instructios Manual.IT SAO OLD EPM u Ye

M Mark WX If ayinformation in this notice is claimed asconfidential. 9of ProtcCmuiatn chemicalsanas( reiedetr9onpg)

Realaces previous editions of EPA Formi 7710-25.
Public reporting burden for this oluection of Information is estimated to average 110 hours per response- indluding time for reviewing intfuctioMs

searching existing data source, gathering and maintaining the data needed, and completing and reviewing the collection of informetiML Send

comments regarding the burden estimate or any other aspect of this collection of information including suggestions for reducing this burden,

to Gilef, Information Policy Branch. PM-rn3, U.S. Environmental Protection Agency, 401 M. SL., S.W., Washington, D.C 20460, and to the Office of

Manazenient and Buditet, Paperwork Reduction Act (2070-0012). Washington, D.C 2M5(.

CERTIFICATION

I certify that to the best of my knowledge and beliefL. The company named in Part 1, section A, subsection la of this notice form intends to manufacture or import for a

commercial purpose, other than in small quantities solely for research and development, the substance identified in

Part 1, Section B.

2. All information provided in this notice is complete and truthful as of the date of submission.

3. 1 am submitting with this notice all test data in my possession or control and a description of all other data known to

or reasonably ascertainable by me as required by §720.50 of the Premanufacture Notification Rule.

Additional Certification Statements:

If you are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following user fee certification

statement that applies:

The Company named in Part 1, Section A has remitted the fee of $2500 specified in 40 CFR 700.45 (b), or

O The Company named in Part 1, Section A has remitted the fee of S1000 for an Intermediate PMN (defined @ 40 CPR 700.43) in

aoracewith 40 CFR 700.45(b), or

o The Company named in Part I, Section A is a small business concern under 40 CFR 700.43 and has remitted

a fee of S100in acodancewith 40 CR700AS (b).

If you are submitting a low volume exernption-tLVE)-appitonin-aecordAnewith 40 FR723S0 -(c) (1) or a Low

.=reeae and low exposure exemption (LoREX) application in accordance with 40 CFR 723.5 (c (2), check the following

certification statements:

OThe manufacturer submitting this notice intends to manufacture or import the new chemical substance for

commercial purposes, other than in small quantities solely for research and development, under the term

of 40 CFR 723.50.

OThe manufacturer is familiar with the terms of this section and will comply with those terms; and

O The new chemical substance for which the notice is submitted meet all applicable exemption conditions.

oIf this application is for an LVE in accordance with 40 CFR 723.50 (c)(1), the manufacturer intends to commence

manufacture of the exempted substance for commercial purposes within I year of the date of the expiration of the

30 day review period.

The aocuracy of the statements you make in this notice should reflect your best prediction of the anticipated facts regarding the chemical

substance described herein. Any knowing and willful misinterpretation is subject to criminal penalty pursuant to 18 USC 1001. Confidenia

"g eand title of A hnz Official (Original Signature Required) Date

Signature of agel~t - (if applicable) Date
AUG 17 '00 02:07P CERDE CORP P. 2/2

pant i -GENERAL INORMATION

Section~ A - SUB~aMIT iDENTifiCAION Can&i

denfiul

Mark 00 the -raicldatlal" box next to any uaecinyou clim. as confidential.

Name of iaehouized official Positioni .. Person

Suabmitting DAVID SOCCHINI EXECUTIVE VIX M DNA EFR PNCR

Notice P=

duc2-DECUSSA METALS CATALYSTS CERDECFMDVSO

Mallin 6 addzn (anzbe and sweet)

City,sSeMPCode

WASHINGTON, PA 15301

b. Agent (if Nome of authorized official Position

applicable)

Gompany

Mailin addrs 6uamber and uuutP

Cit, sa ZI Coe ra Code Number

Tatephone

c. If you are submitting this ntca aspart of a joit submission. mark 00 this boz.

joint Name of authoized offcat oito

Submitter

(if applicable)

Miling address (uamber and swet)

city. state, ZIP CO&. Arm Code Number

Telephone

2. Technical Name Psto Contact _________________f_______ (nUS) LUCY STEM POUCTu SAM! m A Ira

dinc2-DEGUSSA IIETALS -CATALYSTS CERDEC CEPEC DISO

Mailing address (number and sweet)

WEST WYLIE AM EM59AmNme

Cky. Sbae. zip demCoe Nib

Talephome

WASHINGTON, PA 15301 I 724 1223-5990 EXT_ 5933

3. I you have had a prenotom cmmunicaon MPC connig "h~ Pode Mark 00

and EPA assigned a PC Numbr to the notie, 11ta the number. --- PC 397C. Ifnn

4- If you previously submitted an exemtion application for the chemiol

substance covered by this nocce, entr the exemption number mmsigsed Mark 00

by EPA. If you previously submitted a PMN for this substance enterthIle i

PN number assied by EPA "La withdrawn or incomplete). inn

5.I you have submitted a notice of Bona fide intent to trunufactue or Mar 00 .... > r , import for the chemical substance covered by this notice, enter the if noneLZ

notice number assigned by EPA.

6. Type of Notice - Mark 00 0 Only Orly 1 . ot

E emingoption Bnipio I L

FORM EPA 7710.25 (Rev 5-9s) Pag-e 3
0 .... 0... 

Part I - GENERAL INFOnMATION - Continued

Section S CHEMICAL IDEN =rn INFORMIATON: bO masso nu it osv ne 9Mo Cww(~m Amaasaa tCA num. tm m~

Mark 00~ the -Conficentai' box next to 5.nW item you diaim as confideiaL

ComPitte either item I (Class i or 2 suostanceso or 2 (Polymners) as appropriat. Comiplete ALI other Items.

'd another Person -ill subit chenucai identitv untormamon tor you tfor either item I or 2). maric 00 the box at the n7gh. Lcma

ideintv the name. camranv. sno addren ot that pemsn in a contiuation sheet. t.J dentiai

1. Class I or 2 chemical rubsances qtor deutin at daw ana daw~ 2 subsmann. see the insatsanns Mlanual)

a. Class oi substance - Mark 00( I [ CAN or 2 0 Clan 2

b. Ciaxucal namea tCurreily correct Che-mia Abstracts (CM3 Name that &s onsistmt with TSCA Inventory listirn tar similar, Aubtan

For CLIO I Substanfces a CA hIndez Namea ms be vravided. For Clans I substances cither a CA Index Name or CA Preferred Nam m XX

be provid&c Whichever Is appropriate basnd an CA 9C3 nomeistumW zii and coiiveitiom)s.

c. Please icentwy whi methodl You Lima to devetop, or ootazn the specuLfed chemucal indetity informationi sepwr in this nou (checx onet.

ED Method I (CAS Inventory Expert s1ervucr - a copy oi the Identasicawo [Method 2 (Other 6ource)

repot obtaines from tnc CAS Inventory Expert Servie must be

submitted as an attachment to this notice)

d. M0lecu~ar ormuLa and CAS Rgisry Number (if a number alzeady m t for thi subtans) 7P 

e. Foria class A subsaune.providaa ipieteann correcichenucalstuure disam. F'x aclass2 substance-(1)ULst thue w ia

precursor substances with their respective CAS Registry Numbems (2) DeCiabe the nature of the reacni or po (3) Indicate the XXX

range at compotizoon and the typial co. pc~on "n-Wsp proprinie7 (4) Provide a corect represative or partiul chemicalI SmtrUCre aiapamU. a~s Com~piete as can be known, i one Can be rea&XMablV astared..C

a-i on iAt hl box~ if You attach a contiuacon sheet.
CAS Inventory Expert Service Repo

page I of 2

Inetr ExetSevc

Adivision of the American Chemical Society Phone: 800-631 -1884. 61 4447-3600 (ext. 2308)

Fax: 61 4447-3747 E-mail: answers@cas.org

INVENTORY EXPERT SERVICE REPORT

IES-ORDER NUMBER:

REGISTRY NUMBER:.

CA INDEX NAME CONFIDENTIAL

Please print the above CA Index Name on the appropriate page of your PMN.

1fthis box is checked, CAS has made correction(s) marked in red to

your IES order. Please make the same correction(s) to your PMN before

submitting it to the EPA.

000005

2540 Olentangy River Road P0. Box 3343 Columbus. Ohio 43210-0334
CAS Inventory Expert Serivce Report

page 2 of 2

ANSWRIF.EGSx COPYRIGHT 1999 ACS

RNq [ FEGIS=1Y REG I 237Y COPYRIGHT 1999 ACS

Fq L F I POS T RY

CNl F I (CA IND:!EX- NAME)

OTHER NAMES:

CN [ I Ir

IDR II : COI E T1AL

MF [O 

AF I

CI TIS

0O(OGOG
Product Structure G6F N I AL

CON FIDENTIAL 4C000007
SectionPart I -- GENERAL INFORMATION - Continued

ScinB -CHENUICAL IDENTITY INORMATION - Continued

:Polymers tFor a definition of polymer, see the instructions Manual.) Confidential

a. Indicate the number-average weight of the lowest molecular weight compombton of the polymer you intend to manuiacture.

Indicate maximum weight percent of low molecular weight speces inot including residual monomers, reactants, or solvents), bel

5 00 and below 1,000 absolute molecular weight ot that composition.

Describe the methods of measurement or the basis for Your estimates: GPC C3 Othe(] :(Specify)

0) lowest number average moiecular weight:________

H) maximum weight % below 500 molecular weight______

U0l maximum weight % below 1000) molecular weight;________ E Mark WX this box if you attach a continuation sheet.

b. You must make separate confidentiality dlaims for monomer or other reactant identity, composition informatia 9(and residual information.

Mark (X) the "Confidential" box next to any item you claim as confidential.

(1) - Provide the specific chemical name and CAS Registry Number (if a number exists) of each monomer other reactant used in the

(2) - Mark MX this column if entry in column (1) is confidential.

(3) - Indicate the typical weight percent of each monomer or other reactant in the polymer. (4) -

polymer 

Mark WX 

description 

the identity 

on 

column 

the TSCA 

if you 

Chemical 

want a monomer 

Substance or Inventory.

other reactant used at two weight cent or less to be listed as part of the

(5) - Mark CX) this column if entries in columns (3) and (4) are confidential.

(6) - Indicate the maximum weight percent of each monomer or other reactant that may be p t as a residuall in the polymer as

manufactured for commercial purposes.

(7) - Mark (X this column if entry in column (6) is confidential.

Monomer or other reactant and CAS Registry Number ConfK Typical Identity Confi- Maximum Cof-

()d Icomposition Mark (X) dential residual dential

____________________________________________________(3) (4) (5) (6) (7

E Mark CX) this box if you attach a continuation s t

c. Please identify which method you usdt=eel or obtain the specified chemical identity information reported in this notice. (check one).

Method'I (CAS Inventory Expert e-i copy of the identification report Method 2 (other source)

obtained from CAS lnventoy Expert Service must be submitted as

an attachment to this notige

d. The curr ently corr ect Chemical Abt ( CA) name for the polymer that is consistent with TSCA Inventory listings for similar polymers.

e. Provide a correct representativ or partial chemnical structure diagram, as complete as can be known, if one can be reasonably ascertained.

Mark (X) this box if you attach a continuation sheet.

FORM EPA 710-25 (Rev. 5-95) Page 5 0Ao O s
P.au, I - GENERAL INFORMATION - Continued

Section B - CHEMICAL IDENTITY INTORMATION - Continued

3. Impurities

(a) - Identify each impunty that may be reasonably anticipated to be present in the chemical substance asmaiutactufed for ewmmeraal purpoeu.

Provide the CAS Registry Nuinber it available. If there are unidentified impurities. enter "unidentified."

ib) -Estimate the maximum weight % of each Impurity. If there are unidentified impunties, estimate their total weight%5.

Impury and CAS Registry Number Ma"mu Confi-

(a) percent dentia

% X

EMark (X) this box if you attach a contianuation sheet.

4. Synonyms - Enter any chemical synonyms for the new chemical substance identified in subsection I or 2. ConfiNot Applicable

EMark (X) this box if you attach a continuation sheet.

5. Trade identification - List trade names for the new chemical substance identified in subsection I or 2.

E1 Mark 00 this box if you attach a continuation sheet.

6. Generic chemical name - If you claim chemnical identity as confidential, you must provide a generic chemical name for your substance

that reveals the specific chemical identity of the new cheiucal substance to the maximum extent possible.

Refer to the TSCA Chemical Substance Inventory, 1985 Edition, Appendix B for gidcance on developing

generic names.

Mixed Metal Oxide

E Mark 00) this box if you attach a continuation sheet.

7. Byproducts - Descibe any byproducts resulting from the manufacture, proicessing, use, or disposal of the new chemical substance. Provide the CAS

Registry Number if available.

BpoutCAS Registry Number neafl-

(2) dential

FORM EPA 77 iO-25 (Rev. 5-95) Page t) 0(00 9,-
Part I -- GENERAL INFORMATION -- Continued

Section C - PRODUCTION, IMI'ORT, AND USE INFORMATION:

Mark (X) the 'Conndointial- box next to any item you claim as confidential.

1. Production volume - Estimate the maximum prodiuction volume during the first 12 months of production. Also estimate the

maximum produ.:tion volume for any consecutive 12-month penod during the first three years ot production. Estimates should be on

100% new chemical substance basis. For a Low Volume Exemption application, if you choose to have your notice reviewed at a louw production

volumne than 10,000 kg/yr, specify the volume and mark Wx in the binding' box. If granted. you are bound ,to this volume..

Maximum tirst 12-month production (kg/yr) Maximum 12-month production (kg/yr) denfi- OBinn

(100% new chemical substance basis) (100% new chemical substance basis) Mark W)

2. Use Information - You must make separate con ndentiality claims for the description of the category of use, the percent of production volume

devoted to each category, the formulation of the new substance, and other use information. Mark (X) the "Confidential" Box next to ay item you

claim as confidential. a. (1) - Describe each intended category of use of the new chemical substance by function and application.

(2) - Mark (X) th" column if entry in column (1) is conridential business information (CE!).

(3) - Indicate your willingness to have the information provided in column (1) binding.

(4) - Estimate the percent of total production for the first three years devoted to each category of use. (5) - Mark 0X) this column if entry in column (4) is corndential business information (CBI1).

(6) - Estimate the percent of the new substance as formulated in mnixtures, suspensions, emulsions, solutions, or gels as manufactured for commercial purposes at sites under your control associated with each category of use. (7) - Mark CX) this column if entry in column (6) is confidential business information (CBI).

(8) - Indicate % of product volume expected for the listed "use" sectors. Mark more than one box if appropriate. Mark

CX) to indicate your willingness to have the use tvpe provided in (8) binding.

(9) - Mark (X) this column if entry~ies) in column (8) is (are) confidential business information (CB!).

Category of use (1) CBI Binding Produc- CBI % in CBI % of substance expected per use B

(by function and application i.e. a dispersive dye for Option tion %o Form- ~ (8)

finishing polyester fibers) Mark W ulation Sit- I~ - Inus Co-Bidn

(2) (3) (4) (5) (6) (7) limited sumer trial mercial Option (9)

X % X .7. 10

X % X 7bX 100~

X %IX X 100~

X % IX % X 100

x -%I X % X I 10%, -

*If you have identified a "consumer" use, please provide on a continuation sheet a detailed description of the use(s) of this chemical

substance in consumer products. In addition include estimates of the concentration of the new chemical substance as expected in

consumer products and describe the chemical reactions by which this substance loses its identity in the consumer product.

Mark 0)0 this box if you attach a continuation sheet. NO CONSU14ER USE

b. Generic If you claim any category of use description in subsection 2a as confidential, enter a generic desciption of that use category. Read the Instructions Manual for examples of generic use descniptions.

description

Pigment

I3 Mark (X) this box if you attach a continuation sheet.

3. Hazard Information - Include in the notice a copy ot reasonable facsuaule of any hazard warnig statement, label. material safety data sheet, Bin~ding

or other unformation which wil be provided to any person who is reasonably likely to be exposed to this substance regarding protective Optn

equipment or pra':tices for the safe handling, trans port, use, or disposal of th e new Isubstance. List in part Ill hazard information you include. Mr

XMa rk ('X) this box if you attach h azard in form a non KSDS and Label (see pages 14i'23)

FORM EPA 7710-25 (Rev. 5-9S) Page 717,7
Part hk--- HUMAN EXPOSURE AND ENVIRIONMENTAL RELEASE

Section A -INDUSTRIAL SITES CONTROLLED BY THE SUBM[rITTE Mark 0X) the "Confidiential" box next to any item you

claim as confidential.

Complete section A for each type of manufacture, Processing, or use operation involving the new chemical substance at industrial sites you control

Importers do not have to complete this section for operations outside the U.S. ; however, you may still have reporting requirements if there are further industrial processing or use operations after import. You must describe these operations. See instructions manual.

1. Operation description Cons

a. Identity - Enter the identity of the site at which the operation will occur. et

Name

d2- DEGUSSX IETAiT;.CAT*IfIS CERDEC, CERDEC DIVI SION

Site address (number and street)

west Wylie Avenue; P.O. Box M19

City, County, State, ZIP Code

Washington, Pennsylvania 15301

If the same operation will occur at more than one site, enter the number of sites. Identify the 180 m

additional sites on a continuation sheet, and if any of the sites have significantly different

production rates or operations, indcle all the information requested in this section for those 1

sites as attachments.

[]1 Mark (X) this box if you attach a continuation sheet

b. Type -

Mark W0 G] Manufacturing 1: Processing El Use

c. Amount and Duration - Complete 1 or 2 as appropriate

d. Process description [3 Mark (X) to indicate your willingness to have your process description binding. xxx

(1) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specify-e.g. 5 gallon pails, 55

gallon drum, rail car, tank truck, etc.).

(2) Provide the identity, the approximate weight (by kg/day or kg/batch on an 100 new chemical substance basis), and entry point of all starting materials and feedstocks (including reactants, solvents, and catalysts, etc), and of all products, recycle streams, and wastes. Include cleaning

chemidcals (note frequency if not used daily or per batch.).

(3) Identify by number the points of release, including small or intermittant releases, to the environmnenlgite ne-w chemnical substance.

See Block Diagrams on pages gas Bb. and Sc.

(q Mark M this box if you attach a continuation sheet.

FORM EPA 7710.25 (Rev. 5-95) Pages8
.0ONFIDENPAL

Process Description I

PMN Substance Manufacturing Operation for

8a 0 0O0 Of

rnwnnm
Process Description 11 CONFDFNIAL

PMN Substance Manufacturing Operation for

mmmflnrlfflTIl 8b 00001s
Process Description IIILllF J

On-Site Processing of the PMVN Substance

into Glass Enamel Pastes

8_ Bc QCC.Ci4 nlm Ri flfl R1
Part 11 - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued

SSection A - [NDUSTRIAL SITES CONTROLLED BY THlE SLTBMr[TTER - Continued

2. Occupational Expoaure - You must make separate conindentiality dlaims for the descrption at worker activity, physical form of the new chemical

substance, number of workers exposed. and duration at activity. .Mark (X) the "Confidential" box next to anv item you claim as confidential.

1) - Describe the activities (e.g. bag dlumping, tote tilling, unloading drums, sampling, dleaning. etc.) in which workers may be exposed to the

substance.

(2) - Mark WX this column if entry in column (1) is conndlential business information (CI).

(3) - Describe any protective equipment and engineering controls used to protect workers.

(4) and (6) - Indicate you willingness to have the intormatlon provided in column (3) or (5) binding.

(5) - Indicate the physical form(s) of the new chemical substance te.g. solid: crystal, granule. powder. or dust) and % new chemical substance (if part at

a mixture) at th time of exposure.

(7) - Mark (X) this column if entry in column (5) is contidlential business information (CBII).

(8) - Estimate the maximum number of workers involved in each activity far all sites combined.

(9) - Mark (X this column if entry in column (8) is contidential business information (CBII).

(10) and (11) - Estimate the maximum duration of the activity for any worker in hours per day and days per year.

(12) - Mark M0 this column if entries in columns (10) and (11) are confidiential business infor~mation (CIII). ___

Worker activity CI Protective Equipment/ tandini V1hysicali fornital -oo CB *Of CBI Maximum duration CE!

(e.g. bag dumping, filling drums) Engineenng coUrol apit,, (e.gsoiid.powder) POR Workers -s/aDy/r aMirks) and % new W Exposed r/aDysr

(1) (3) ~~~~~~~substance L .. QL.*fl.. 1)

Ventilation

XI Respirators, Glasse- X 1-2 1~l2 5-20

X Gloves, Safety Glas X 1 8 5-20

Respirators_______ - -- - -

Safety Glasses

X Gloves X 1 1 5-20

X Safety Glasses

Gloves X 1 1 1 5--20

X Safety Glasses

Gloves X1 2 1 1 8 15-20

I!Mark M0 this box if you attach a continuation sheet. See page 9a (for page 8a processing)

3. Environmental Release and Disposal - You must make separate confidentiality claims for the release number and the amount of the new chemical

substance released and other release and disposal information. Mark M0 the "Confidential" box next to each item you claim as confidential.

(1) - Enter the number of each release point identified in the process description, part 11, section A, subsection ld(3).

(2) - Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch).

(3) - Mark M0 this column if entries in columns (1) and (2) are confidential business informaion. (CE!).

(4) - Identify the media of release Le. stack air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration,

P01W, or other (please specify) to which the new substance will be released from that release point.

(5) - a. Describe control technology, if any, ,and control efficiency that will1 be used to Limit the release of the new substance to the environment.

For releases disposed of on land, characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste.

On a continuation sheet, for each site describe any additional disposal method~s that will be used and whether the waste is subject to

secondary or tertiary on-ite treatment. b. Estimate the amount released to the environment after control technology (in kg/day).

(6) - Mark (X) this colum if entries in columns (4) and (5) are confidential business information (CE!).

(7) - Identify the diestintation(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct

dischargers or NPDES numbers of the P01W (Publidly Owned Treatment Works). Mark 00)11 the P01lW name or NPDES # is confidentia

business information (CB!)

Release Amount of new substance 0,MdatControl technology and efficiency (you may wish to opitionally attach efficiency data) CEI

Number rele release

( __)_(2a)_ (2b(4)a(kaW (Sb) (6)

1 0.2 kg 20 kg/batch air Pulse Jet Baghouse; 99.9% efficiency 0.02 kg/batch

2 0 20 kg/batch water Onsite Water Pollution Abatement 0.2 kg/batch

- 99.91 efficiency

3 0 10 kg/batch water Onsite Water Pollution Abatement 0.1 kg/batch

________ 99.9% efficiency

4 0.1 kg 10 kg/batchl air Pulse Jet Baghouse: 99.91 efficiency 1 0.01 kg/batch

5 0.2 kg 10 kg/batch air Pulse Jet Baghouse; 99.9% efficiency 0.02 kg/batch

(7) Mark WX the [D POTW provide name(s) below: CBI E] Navigable C] other. -specify provide NPDES # CE!

destination(s) of Washington-E. Washington waewy

releases to waler. JitAhoty(EA PA0026212

EMark 00) this box if you attach a continuation sheet.

FORM EPA 7710-25 (Rev. 5-95) Page 9 A
Part 11 - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued1

Section A - ENDUSTRIAL SITES CONTROLLED BY THE SUBMER= - Continued

2. Occupational Exposure - You must make separate cotideniality clains for the desciption of worker activity, physical form of the new chemical

substance, number of workers exposed. and duration of activity. IMark 0)0 the "Confidential" box next to any item you claim as confidential.

(1) - Descibe the activities (e.g. bag dumping, tote filling, unloading drums, sampling. cleaning. etc.) in which workers may be exposed to the

substance.

(2) - Mark 00) this column if entry in column (1) is confidential business information (CED.

(3) - Describe any protective equipment and engineering controls used to protect workers.

(4) and (6) - Indicate you willingness to have the information provided in column (3) or (5) binding. (5) - Indicate the physical form(s) of the new chemical substance te.g. solid. crystal, granule, powder, or dust) and % new chemical substance (if part of

a mixture) at the time of exposure.

(7 - Mark 00 this column if entry in column (5) is confidential business information (CBfl.

(8) - Estimate the maimum number of workers involved in each activity for all sites combined.

(9) - Mark 00 this column if entry in column (8) is confidential busiess information (CBI).

(10) and (11) - Estimate the maximum duration of the activity for any worker in hours per day and days per year.

(12) - Mark 00 this column if entries in columns (10) and (11) are confidential business information (CBfl. ___

Worker activit CE! Prosdive Equipmnt/ Biading k'hysicai tormia) Bidn CB 0of CD! Maximum duration CB1

(e.g. bag dumping, filling drums) Engirig Contris Dpiom ea ld-o - Workri/dyDasy M~&(x) and %new ki) Exposed r/aDys-i (1)___________3) substance() *j

X Safety Glasses X 1-2 8 5-20

,Gloves

X Ventilation, Gloveq X 2 16 5-20

Safety Glasses, Rew

X Ventilation, Gloves X 1 8 5-20

___________________ Safety glasses, Resp.

X Ventilation, Gloves X 1 1 5-20

_____________________ afety Glasses, Resp

Mark MX this box if you attach a continuation sheet. See page 91b (for page 8b processing)

3. Environmental Release and Disposal - You must make separate confidentiality claims for the release number and the amount of the new chemical

substance released and other release and disposal information. Mark 00 the "Confidential" box next to each item you claim as confidential.

(1) - Enter the number of each release point identified in the process description, part IL section A, subsection ld(3).

(2) - Estimate the amount of the new -substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch).

(3) - Mark M0 this column if entries in columns (1) and (2) are confidential business information (CB!).

(4) - Identify the media of release ie. stack air, fugitive air (optional-see instruction Manual), surface water, on-site or off-site Land or incineration.

P07W. or other (please specify) to which the new substance will be released from that release point.

(5) - a. Describe control technology, if any, ,and control efficiency that will be used to limit the release of the new substance to the environment.

For releases disposed of on land. characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste.

On a continuation sheet , for each site descibe any additional disposal methods that will be used and whether the waste is subject to

secondary or tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day).

(6) - Mark 00) this column if entries in columns (4) and (5) are confidential business information (CB!)

(7) - Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Eimination System) numbers for direct

discharger's or NPDES numbers of the POTtY (Publidly owned Treatment Works). Mark M011 the P01W name or NPDES # is confidential

business information (CE!).

Release Amount of new substance CB Medao Control technology and efficiency (you may wish to optionally attach efficiency dta) I

Number CDIe release

() (2.a) (2b) (3 (4) (54) Kuc W T (6)

(7) Mark MX the ~ 0W de namets) belo-. CBI Navigable [~other -specify provide NPDES # CB!

destination(s) of waterway

releasesq to water.

Mak 00 this box if you attach a continuation sheet. 0O0O91!0 G
Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued

Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMrTTE - Continued

2_ occupational Exposure - You must make separate confidentiality dhurns for the description of worker activity, physical form of the new chetnscai

substance. number of workers exposed. and duration of activity. Mark 00 the "onfidential" box next to any item you claim as confidenbal

(1) - Describe the activities (e.g. bag dumping, tote tilling. unloading drums, sampling, cleanung, etc.) in which workers may be exposed to the

substance.

(2) - Mark (X) this column if entry in column (1) is confidential business information (CE!).

(3) - Describe any protective equpment and engineering controls used to protect worker.

(4) and (6) - Indicate you willingness to have the information provided in column (3) or (5) binding.

(5) - Indicate the physical form(s) of the new chemical substance (e.g. solid. crystal, granule. powder, or dust) and %. new chemical substance (if part of

a mixture) at the time of exposure.

(7 - Mark 0)0 tis column if entry in column (5) is confidential business inormation (CM!).

(8) - Estimate the maximum number of workers involved in each activity for all sites combined.

(9) - Mark 00 this columnn if entry in column (8) is confidential busines information (CE!)

(10) and (11) - Estimate the me-mum duration of the activity for any worker in hours per day and days per Year.

(12) - Mark 030 this column if entriesmincolumns (10) and (11) are confidential business information (CE!).

Worker activity CB! Protive.Equipmenti Binding Yhscllrmier BIdbngC *of CB! Maxim uration CEI

(e.g. bag dumping, filling drums) EagAnsasag Cosmil OP. (egsaolipd er 'l. irr.

(a) and % now Wr~ Exposed Hrs/dy Days/yr substance (8) fy. 12

rVentilation

Safety Glasses X 1 10-12 5-20

Safety Glasses X 1 1 5-20

X Ventilation X 1 0.5 5-20

____________________ Safety Classes

VentilationI

I Safety Glasses _ ______ - X 1 8-12 5-20

EMark W0 this box if you attach a continuation sheet.

3. Environmental Release and Disposali - You must make separate confidentiality claimrs for the release number and the amount of the new chemical

substance released and other release and disposal information. Mark 0)0 the "Confidential" box next to each item you claim as contfidentiaL

(1) - Enter the number of each release point identified in the proces description, part IL, section A, subsection ld(3).

(2) - Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch).

(3) - Mark 00) this-column if entries in columns (1) and (2) are confidential business information (CB!).

(4) - Identify the media of release ie. stock air, fugitive air (optional-see Instruction Manual), surface water, on-site or off-site land or incineration,

P01W, or other (please specify) to which the new substance will be released from that release point.

(5) - a. Descrbe control technology, if any, ,and control efficiency that will be used to limit the release of the new substance to the environment.

For release disposed of on land. characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste.

On a continuation sheet,* for each site describe any additional disposal methods that will be used and whether the waste is subject to

secondary or ternary on-ste treatment. b. Estimate the amount released to the environment after control technology (in kg/day).

(6) - Mark 00) this colum if entries in columns (4) and (5) are confidential business information (CE!)

(7) - Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct

dischargers or NPDES numbers of the P01W (Publicly Owned Treatment Works). Mark 00)1i the P01W name or NPDES 11 is confidential

business information (CBM)

Release Amount of new substance CBI Mediao Control technology and efficiency (you may wish to optionally attach efficiency data) Cm1

Number ree releaese

(1) (2a) (2b) Mark ((A)(6 _______ ______ __ (4) (55a(6

10 0.125 kg 12.5 kg air Pulse Jet Daghouse, 99.9 %. efficiency 0.0125 kg

Onsite Water Pollutin Abatement

20 0 12.5 kg water 99.9 %. efficiency 0.0125 kg

30 0.05 kg 5 kg air Pulse Jet Baghouse, 99.9 %. efficiency 0.005 kg

Onsite Water Pollution Abatement

'#0 0 45_kg water 99.9 %. efficiency 0.045 kg

50 0.125 kg 12.5 kg air jPulse Jet Baghouse, 99.9 efficiency 0.0125 kg

(7) Mark (X) the 13 P01rW provide name(s) below. CB! (L-Navigable Other - Specif y provide NPDES US CE

destination(s) of Washginton-E. Washington waterway

reesst ae. Joint Authority (WEWJA) PA026120 GIo 0

ElMark (X this box if you attach acontnuation sheet. ( see page 9c for continuation of ERWD for Schematic page 8b).

,. . . - n 1 :n. OC% --
Part 11I- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued

Section A- INDUSTRIAL SITES CONTROLLED By THE SuBMfTER - Continued

7- Occupational Exposure - You must make separate conridientialitv claims for the descrition of worker activity, physical form of the new chemi

substance. number of workers exposed, and duration of activity. 'Mark (X) the 'Contidentiaf box next to any item you claim as confidlential

(1) - Describe the activities (e.g. bag dumping, tote filling, unloading drums, sampling, cleanung, etc.) in which workers nmy be e e

substance.

(2) - Mark M0 this column if entry in column (1) is confidential business information (CED.

(3) - [)sciibe any protective eqipment and engieering controls used to protect workers.

(4) and (6) - indicate you wdhingnew to have the information provided in column (3) or (5) binding. (5) - Indicate the physical form(s) of the new chemical substance (e.g. solid. crystal. graniule. powder, or dust) .new chenucal substance (if part of

a mixture) at the time of exposure.

(7 - Mark 00) this column id entry in columrn (5) is confidential business information (CBI).

(8) - Estimate the miaximum number of workers involved in eachi activity for all sites combined.

(9) - Mark 0X) this column if entry in column (8) is confidential business information (CBI).

(10) and Q11) - Estimate the maximum duration of the activity for any worker in hours y and days per year.

(12) - Mark 00 this column if entries in columns (10) and (11) are confidential information (CBI). ___

Worker activity CBI Protecive Equipmentl Binding t icai ormta) =dta Cm of CB1 Maximumduration CB!

(e.g. bag dlumptigfilling drums) Enginering COnaOID a -e-gaoLid:'powder) I t " Workers i/a asy

__0___ 3 r N (8) (10) ~fil (121

L1i Mark M this box if you attach acontinuation sheet. see page 9d (for page 8c processing)

3. Environmental Release and Disposal - You must make separate confidentiality claims for the release number and the amount of the new chemical

substance released and other release and disposal information. Mark M0 the "Confidiential" box next to each item you claim as confidential.

(1) - Enter the number of each release point identified in the proces desciption. part IL section A. subsection Ild(3).

(2) - Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology (in kg/day or kg/batch).

(3) - Mark M0 this column if entries in columns (1) and (2) are confidential business information (CBI).

(4) - MIdy thie mei of release ie. 3ta& -air, fugi tive air (optional-see Instruction Manual). surface water, on-site or off-site land or incineration,

P0 1W. or other (please specify) to which the new substance will be released from that release point.

(5) - a. Describe control technology, if any, ,and control efficiency that will be used to limit the release of the new substance to the environment.

For release disposed of on land, characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste.

On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to

secondary or tertiary on-aite treatment. b. Estimate the amount released to the environment after control technology (in kg/day).

(6) - Mark 00 this column if entries in columns (4) and (5) are confidential business information (CBI).

(7) - Identify the destination(s) of releases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct

dischargers or NPDES numbers of the P01W (Publicly Owned Treatment Works). Mark 00 if the PO'IW name or NPDES 0 is confidential

business inormation (CDI)

Release Amount of new substance CB Melo Control technology and efficiency (you may wish to optionally attach efficiency data) CDI

Numbe rCDI release

Numbe sac ai hai

(1) (2a) (2b) m(x) Mar Badn

_________ _________(3) (4) (5a a) ar (5b) (6)

60 0.125 kg 12.5 kg air Pulse Jet Baghouse, 99.9% efficiency 0.0125 kg

70 0 12.5 kg water Onsite Water Pollution Abatement

_______ _______99.9% efficiency 0.0125 kg

- -

(7) Mark (X) the PO1W provide namets) belovr. CBI E]Navigable other. Specify provide NPDES CBI

destination(s) of WEWJA wtra

releases to water. PA002621 2

E Mark 00 this box if you attach a continuation sheet. 000U)
,,art 11 -- !iUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - -'ontmnued

? ~ A INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER - o'ntinueu

ccu,ationai t-xoiure - 'wu must maKe serarateconnuientialiv-:aims for ilC oesaitnifn of worywr acflvitv rnnv;icii form of tflC new cnemica!

.,tanL': e ::et~v of worl(Crb eXLX)1A. anj uration )t .ivitv 2,lrki t.,oI tice onfldennal b'ox next it) ary item youi claim as ,unticntiai.

'--lCL trie .tic,tie cU vC Jcum oins! I U~i 1110nn .2,111711:n Ururs. jmplini, nevninc, cwne in wonin workers may txe esooKSea to the

- '.IK trk I this column it entry in columni I is cornfentiaiL'usiness information tI":fI).

4-.ance any protective couipment ana eneinecrintt controls Used to prowect worKers

inutO' -- Ildlc.3te Vou willingniess to riave tne ffinotration r'rovicied in column 0.) or 6n) binding.

* niicaic the tinvqlcal forintsjof the new c-nemicai suos'tance te sz saud: arvstal. g~ranule. ;xawoer or oustn ana '~new cenmItca substanceuLt part at

mixturel it the time of eroure.

%la\t~rk (X) this coljurrn if entryV in column uij is conticiential business information l3)

i-- sflmafe the maximum number of worKers involved in vacni activity tor all Sites CornMIed.

- 'I Mark tX) this colaun it entry in column to) is corndential businCSs Information K131).

10) and tIl) - Estimate the maxur duration of the activity for any worker in hours per day and days per year.

02) -%ldark WX this column it entries in columns t 10) and (11) are conndential businesinformation tCBI).I

Worker activity CBI Prviecllve Lquipmenu Hifldin, Flhviicat formts) Binding CBI 0 of CBI Mximumn duration C1B1

ieg. bag dumping, tilling drums) I tineennit Lontrals Option (e.g.soiid:powder) Opin Wokr

substance 'n 1'4)n g~ (2

X Safety Glasses X 1 1 30-100

gloves, VentilX -21-2 3010

Safety Glasses

Gloves, Ventilatior X 1-2 1-2 30-10

X Safety Glasses

______________ Gloves X 1-2 2-4 130-120

LiMark WX this box if you attach a continuation sheet.

3. Environmental Release and Disposal - You must make separate confidentiality claims for the release numoer and the amount at the new chemical

substance released and other release and disposal information. Mark WX the "Confidlential" box next to each item you claim as confidential.

(1) - Enter the number of each release point Identified in the process desariptin. part 11, section A. subsection Ld(3).

Q)- Estimate'tfieamiiount &f th Knew Nbst ance released ta) directly to the enrvironment or tb) into control technology (i kg/day or kg/batch).

i- Mark (X) this column U entries in columns t 1) and (2) are confidential business information tCBI).

1) - Identify the media of release i.e. stack air. lugirive air toptional-see Instruction Manual). surf ace water, on-site or oti-site land or incineration,

('01W, or othier (please specify) to which the new 'iuostance will be released trom that releasen point.

a-* Describe control technology, it any, and control ei liaency that will be used to limit the release ot the new substance to the environment.

ror releases isposedi of on la'nd, characierize the disposal method and state whether it is approved for aisposal of RCRA hazardous waste.

On a continuation sheet, for eacn site olesaribe any additional disposal methods that will be used and whether the waste is sublect to

-.acondary or tertiary on-site treatment. b Estimate the amount released to the environment after control technology tin kg/day).

fo- Mark tX) this column if entries Ln columns 04) and (5) are confidential business information (CBI).

- Iden tityv the destina tionts) of releases to water. Please supply NPDES (National Pollutant Discharge t~imination System) numbers for direct

dischargers or NPDES numbers ot the POTW (Publicly Owned Treatment Works). Mark WX if the P(YIW name or NPDES il is confidential

business information (C11I).

Release JAmount of new substanice '. releas ui _"troi techtnology and effticiency tyou may wish to optionally attach efficiency data) CB

Number ree *g.Mk1 releae ng

100 0.01 kg 1 kg air Pulse Jet Baghouse, 99.9% efficiency 0.001 kg/batch

200 0 1 kg off sit Approved Methods for Stabilization treat- 1 kg/batch

____ _______________ landfil ment and landfill.

off sit Approved Method for Stabilization Treat- 1 kg/batch

300 0 1 kg Ilandfil ment and landfill.

\I try tX1t he E POTW provide namets) bel'ow (-131 C Navigaole ('Ither- ,eivprovide NPDES A ICBII

'Si Ii iflsI )f .aterwav

cieKsitowder.

'.D tar&. tX) this oox it you attacti a continuatmon sneet.000 1J
Part 11 - HUMA.. EXPOSURE AND ENVIRONMEN--CAL RELEASE - Continued

Section B - INDUSTRIAL SITES CONTROLLED BY OTHERS

k~cmpiete section 6 for typia rcnugo s prtosivligtenwaeia substance at sites you do not controldlmporters co not havet

complete this section for operations outside the U.S.; however, you must report any processing or use activities after import. See the Instructions

Manual. Camnpiefe a separate section R for eaci type ort processing, or use amrat ion invoimni the new ctiurnica substance. If the same operation is periorme

at more than one site deseribe the typical operation common to these sites. Identify additional sites on a continuation sheet.

1. Operation Description - To dlaim uruogmation in this section as conndcentiaL. circle or bracket the specinc intorrnation that you claim as contidienial.

(1) - Diagram the major unit operation step and chemiucal conversions, including interim storage and transport containers (specify- e.g. 5 gallon paii

55gaLlon drums, rail cars, tank trucks, etc). On the diagram, identity by letter and briefly describe each worker activity. (2) - Provide the identity,

the approximate weight (by kg/day or kg/batch. on an 100% new cheical substance basis), and entry point of all feedstocks (including reactants.

bolvents and catalysts. etc) and of all products, recycle streams, and wastes. Include cleaning chemiucals (note frequency if not used daily or per

batch). (3) - Identify by number the points of release, including small or intermiuttent releases, to the environment of the new chiemical substance.

(4) Please enter the # of sites ( remember to identi the locations of these sites on a continuation sheet):

8

ID Mark 00 this boxdifyou attach acontination sheet. Please see Explanation of Assumptions, pp. 10 a and b.

2. Worker Eposure/Environmental Release

(1) - From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity descibed.

(2) - Estimate the number of workers exrposed for all sites combined.

(4) - Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. (6) - Describe physical form of exposure and % new chemical substance (if in mixture), and any protective equipment and engineering controls used

to protect workers.

(7 - Estimate the percent of the new substance as formulated when packaged or used as a final product. (9) - From the process diagram above, enter the number of each release point. Complete 9-13-for each release point-identified.- (10) - Estimate the amount of the new substance released (a) directly to the environment or (b) into control technology to the environment

(in kg/ day or kg/ batch). (12) - Describe media of release i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration,

POTW, or other (specify) and control technology, if any, that will be used to limiut the release of the new substance to the environment.

(14) - Identify byproducts which may resualt from the operation. (3), (5), (8), (lb), (13) and (15) - Mark 0X) this column if any of the proceeding entries are confidential business information (CBI).

Letter # of CBI Duration CBI Protective Equip. / % in CBI Release Amniiit of CBI Media of Release CB

of Workers Of Engineering Controls/ Form- Number New & Control

Act- Exposed4 Exposure Physical Form and % ulation Substance Tcnlg

ivity new substance Released Tdnlg

(1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) Q Oa) 1 (lOb) 0V1 (12) (13

1 I A 2-8 0.2-1 11-100 X 1 0-0.01 1 0-10 Air

hour !days kg/bat' kg/bal Dust Collection

B 2-8 0.2-0.311-100 X Not 0 10

hour days Applicl

C 2-8 0.2-1 1-100 X 1 0-0.1 10-10 Air

I Dust Collection

hour days ___________kg/bat I kg/bal

D 2-8 0.2-1 120X 2 0-0.011 0-10 Air

1-00I Dust Collection

hour days I _______I___ kg/bai kg/ba ___________ 1

(14) - Byproducts: None Known(1

11 %ark (X) this box ifyou attach a ontnuation sheet. Please see page 10a for continuation of Partlill, Sect 8.2.

FORM EPA 7710-25 (Rev. 5-95) Page 1 00 2
Part 11I- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE -- Continlued

SSection 83 - UNDUSTRIAL SITES CONTROLLED BY OTHERS

,-ormelte section 6i tor typical processing or use operations invoiving tne new cjiemicai substance at sites You co not controti1m gers do not have to

cwmprntc this section tor operations outside the U.S, however. vou must report any processing or use activities after import. 'the lnistrudaions

ManuaL. Coinvlete a sepanmte section 8 for ec tvve or rrpcessing'. or use overation invoiing the new chernicai substance. If th e me operation is pertormed ati more than one site describe the typical operanion common to these sites. Identity additional sites on a continuatio t eet.

I. Operation L)escnption - To claim iniormation in t-rus section as conndcentiai. circle or brac.Ket the spec ink= anion that you clam as coridential.

(1) - Diagram the mator unit operation steps and chemticat conversions. including interim storage and tsport containers tspecilv- e.g. 5 gallon padls, 73zallon orums. rail cars, tank trucks. etc). On the adigram. icientitv by letter and bniefly describe e -worker activity. (2) -- Provide the identity, the approximate weight (by kg/day or kg/batch, on an 100% new cnemiual substance beasis), an trY point of all feedstocks (including reactants,

5oivents ana catalysts. etc) and oi all products, recvcle streams, ano wastes, include cleanin ernicals (note trequencv if not used daily or per bitch). (3) - Identify by number the points at release, inciuding small or intermittent re es, to the environment or the new chemiucal substance.

(4) Please enter the # or sites ( remember to identity the locations ot these sites on a ntinuation sheet):

Mark (X) this box if you attach a continuation sheet.

2. Worker Exposure/Environmenal Release

(1) - From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described.

(2) - Estimate the number of workers exposed for all sites combined.

(4) - Estimate the typical duration of exposure per worker in (a) hours per day anid (b) days per year. (6) - Describe physical form of exposure and % new chemiucal substance (if in mixture), and any protective equipment and engineering controls used

to protect workers.

(7) - Estimate the percent of the new substance as formulated when packaged or used as a final product. (9) - From the process diagram above, enter the number of each release point. Complete 9-13 for each release point identifiedt.

(10) - Estimate the amount of the new substance released ta) directly to the environment or (b) into control technology to the environent

(in kg/day or kg/batch).

(12) - Describe mnedia of release i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, P01W, or other (specify) and control technology, Jt any, that will be used to limit the release of the new substance to the environment.

(14) - Identjy byproducts which may result from the operation. (3). (5), (8). (1), (13) and (15) - Mark (X) this column if any oi the vroceeding entries are confidlential business iformation (CBD.

Letter # of CBI Duration CBI Protective Equip. / ill CBI Release Amount or CB Media of Release CBl

of Workers of Engineering Controls/ Form- Number New At Control

Act- Exposed Exposure Physical Form and % ulation Substance Technology ivity new substance Released

(1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) (1 Oa) 1 0 Ob) 0 V (12) (13)

E 2-8 0.5-1 11-100 X 3Waste Disposal

hour days

F 1-2 8 1-100 XI Waste Disposal

hours IdaysI

G 0-2 4-8 I1-100 Not I

Applic 0 I 0 _______ hours I days_____________ -- L... -

(14) - Bvproducts:

EMark tX) this box if you attach a continuation sneet.

FORM EPA 7710-25 (Rev. 5-95) Page 108a 0 0 02
Part 11, Section B.I., Operation Description7\TI

Explanation of Assumptions JJU'I

The Thermoset Organic Coating formulations are proprietary and unknown to the PMN

Substance Supplier: however, some assumptions have been made as follows:

1. The PMN Substance concentration in the Premix and/or Mill Stage may be [ 1. Its

concentration will be approximately [ I after letdown and at the final package stage.

2. A variety of resin systems are possible, these include:

Epoxy

Urethane

Acrylic

Polyester

Alkyd

Polyester-Silicone

Fluoro Polymers (Poly Vinylidene Fluoride - PVDF)

3. Crosslinkers may include:

Hydroxy alkyl amides

Melamine-formaldehyde

Amides

Amines

Isocyanates

Anhydrides

4. Solvents may include:

Glycol Ethers

Esters

Ketones

Alcohols

Aromatic Hydrocarbons

Aliphatic Hydrocarbons

Water

It should be noted, that the paint or coating systems, which utilize the PMVN substance, are

expected to be predominantly solvent based.

5. Catalysts, surfactants, and paint additives are confidential and too numerous to try to

enumerate.

6. Milling equipment is typically media mills such as bead, sand, or ball mills. Bead and sand

mills may utilize a premix stage but do not require it. Ball mills, typically, will not have a premix

stage. High speed disk type dispersers (Cowles) may be utilized and typically will not have any

premix stage. Three-roll milling may still be utilized for smaller batches. 3-Roll milling almost

always requires premix ing ingredients prior to milling.

10 b

0 1DIF J D E NT 1 1AL

!tSCV \V0W RI)i :111[) )(12 302 0 
Part 11, Section B.1. Operation Description

Incorporation of PMVN Substance into

Thermoset Organic Coatings (1,A)

10 d

QAM~fo000P3
Part 11, Section B.1. Operation DescriptionIncorporation of PMVN Substance into

.3LILUP~IALhermoset Organic Coatings (1,B3)

10 e

Cfl~if~u0 OOO'
Part 11, Section B.1. Operation Description

Incorporation of the PMN Substance into

JON~EIT 1~LThermoplastic Materials (1,C)

10f

CONF~F;~J~ 0 0 072
Part 11, Section B.1. Operation Description

Off Site Use of Thermoset Organic Coatings

which contain the PMN Substance (11, A)

CON FIDENIIAL

GONF BENT] AL

LGS.C\HGW\[ 1,1.PRS:S7: 3/30/1999 log 0 0 02 G
Part 11, Section B.1. Operation Description

Off Site Use of The rmoset Organic Coatings

which contain the PMN Substance (11, B)

CONFJBEN TI1AL

CDaENTI~l

LGS:G\HGW\[ JO.PRS.S8: 3/30/1999 10 h

00,0027
Part 11, Section B.1. Operation Description

Off Site Use of Thermoset Organic Coatings

which contain the PMN Substance (11, C)

CON FIDENTIAL

LGS CDHGW\j JO1.PRS:S9; 3/30/1999 10

0000213
Part 11, Section B.1. Operation Description

Off Site use of Glass Enamels

which contain the PMN Substance (11, D)

CONFIDENTIAL

LGS.CHGW\( j0l.PRS:S1O, 3!'30/1999 10 j

000029
Part 11, Section B.1. Operation Description

Off Site Use Thermoplastic Resins

which contain the PMN Substance (11, E)

10k

LGS.C'HGW\ JO1.PRS.Sl1, 3130/1999

f lf 000030 G.I 0, 
OPTIONAL POLLUTION PREVENTION INFORMATION

To claim information in this section as confidential circle or bracket the specific information that you claim as confidentiaL

In this section you may provide information not reported elsewhere in this form regarding your efforts to reduce or minimize potential risks associated with activities surrounding

manufacturing, processing, use and disposal of the PMN substance. Please include new

information pertinent to pollution prevention, including source reduction, recycling activities

and safer processes or products available due to the new chemical substance. Source reduction

includes the reduction in the amount or toxicity of chemical wastes by technological modification, process and procedure modification, product reformulation, raw materials

substitution, and/or inventory control. Recycling refers to the reclamation of useful chemical

components from wastes that would otherwise be treated or released as air emissions or water

discharges, or land disposal. Descriptions of pollution prevention, source reduction and

recycling should emphasize potential risk reduction subsequent to compliance with existing regulatory requirements and can be either quantitative or qualitative. 71he EPA is interested in

this information to assess overall net reductions in toxicity or environmental releases and

exposures, not the shifting of risks to other environmental media or non-environmental areas

(e.g., occupational or consumer exposure). In addition, information on the relative cost or

performance characteristics of the PMN substance to potential alternatives may be provided. All information provided in this section will be taken into consideration during the review

of this substance. See the revised Instructions Manual that includes a Pollution Prevention

Manual for guidance and examples.

Describe the expected net benefits, such as (1) an overall reduction in risk to human health or the environment, (2Z a reduction in

the volume manufactured; (3) a reduction in the generation of waste materials through recycling, source reduction or other

means. (4) a reduction in potential toxiity or human exposure and/or environmental release; (5) ant increase in product performance, a decrease in the cost of production and /or improved operation efficiency of the new chemical substance in

comparison to eisig chemical substances used in similar applications; or (6) the extent to which the new chemical substance

may be a substitute for an existing substance that poses a greater overall risk to human health or the environment.

Please see attached Optional Pollution Prevention Information pp Ila-1ib.

[Mark (X) this box if you attach a continuauon shoet.

FORM EPA 7710-2S CRUV.S-M5 Page 11CO0 3
CONFIDE[NTIAL

Part 11, Section B.2., Worker Exposure/Environmental Release

Explanation of Assumptions

for the PMN Substance of r,

During the manufacture of these organic coatings, the point for worker exposure Is greatest

during the addition of the PMN substance, in powder form, to the resin, solvents, surfactants

mixture at either the Premix or Mill stage. The concentration of the PMN substance Is estimated

to be roughly in the Premix and/or Mill stage. This concentration Is then lowered to

the final level of roughly [ in the Letdown stage. The concentration of the PMN

substance will be predominantly dependent on its performance In the various coating types and

hence is unknown at this time.

The number of workers exposed, to the PMN substance, Is roughly estimated to be 2 to 8

combining the employees of the initial facilities. The dust or inhalation exposure to the PMN

substance, In its powder form, will be mitigated by mostly local ventilation and If necessary, by

respirators with particulate cartridges.

The duration of exposure is difficult to estimate. As many of the manufacturing processes are

assumed. Roughly five to 20minutes may be required to add the PMN substance to the Premix

or Mill stage per batch. This length of time of exposure is obviously dependent upon the batch

size and the time required to add the PMN substance to the Premix or Mill materials. And It Is

assumed that a batch can be prepared in one day (or an eight hour shift). To totally consume

the estimatedkilograms of PMN substance in the first year, would require I batches If only

jof the PMN substance were utilized.

Because there are so many factors which have not been established as yet, it is very difficult to

estimate a -range of batches. Hence, a rough range of 1 to 5 batches will be assumed.

Under the Worker Exposu relEnviron mental Fate, Item 10 asks to "estimate the amount of new

{PMN) substance released (a) directly to the environment or (b) into control technology to the

environment (in kg/day or kg/batch)." Because the manufacturing process and product

formulation are proprietary; this aspect is very difficult to estimate. However, due to

productivity and cost Issues, loss of the PMN substance will be minimized as much as

possible. If a 500 gallon batch is prepared with the PMN substance concentration of [30%]

utilized, as a worst case scenario, then cg of PMN substance will be added to the resin

mixture at either the Premix or Mill stage. If dust collection equipment, such as Cerdec's Pulse

Jet Baghouse Collector, were to be utilized, with a 99.9% efficiency, a loss of PMN substance to

the control equipment might be roughly a half percent (0.5%). It should be noted that this Is

double the loss of PMN substance at any one dust collector spot described In the Process

description on pages 8a and 8b. This half percent loss would then translate to approximately

kilograms to the control technology. At the 99.9% efficiency, this then translate to a

Ikilogram loss per batch of the PMN substance to the environment or [' kilograms

during a 100 batch campaign. These are gross estimates based on a number of assumptions

and limited technical knowledge of the coating processes which may to used.

This loss of PMN substance will predominantly be released to the air. There Is some potential

for release to water, especially If equipment Is cleaned with water. However, this possibility Is

low as most of the equipment is expected to be cleaned with solvents.

10 c

LGS:C:\WINWORD\[BIMNJO2.D0C:3/22/1999 oeO00~
CON FIDENTIAL

Page 1 of 2 OPTIONAL POLLUTION PREVENTION INFORMATION

for the PMN Substance

The use of the PMN substances coatings and plastics, will

have improved product performance, reduction in risk to both human health

and the environment and reduce the generation of hazardous waste in

comparison to the use of current products such as carbon black (CAS # 1333-

86-4, C.I. Pigment Black 7) chrome iron black (0.1. Pigment Green 17, CAS #

13 17-63- 1, or Green 17), and chrome iron nickel black (C.1. Pigment Black 30,

CAS # 71631-15-7*, or Black 30).

coatings are used in a variety of industries such as architectural,

automotive, aerospace, marine and military. The various coatings or plastics

are used on ships, oil derricks, buildings, homes, storage tanks, airplanes,

military field equipment, cars, etc. to reduce the amount

will be requi --

The PMN substances have superior - properties in comparison to the

carbon black, Black 30, or Green 17 as evidenced in laboratory testing.

The PMN substance will be easier and safer to use for the manufacture of the

various coatings and- plastics than especially the carbon black. The density of

the average carbon black, used in coatings applications, is 1.8 grams per

centimeter cubed (g/cm3) while the density of the PMN substance is 7.14

g/cm 3 . Carbon blacks typically used in coatings applications have an average

particle size of roughly 10 to 30 nanometers. The average particle size of the

PMN substance, as measured, is approximately ons. The carbon

black being nearl) times smaller than the PMN substance. The

combination of greater density and larger average particle size mean that the

manufacture coatings will be a lot less dusty when the PMN

substance is used in place of the carbon black, thereby reducing the inhalation

hazard for the manufacture of the coatings or plastics. Also, if operations are

less dusty, there is less product loss. Thereby reducing the loss of product into

any engineering controls and ventilation, reducing disposal. The better

physical properties of the PMN substance will reduce the inhalation hazard to

employees and reduce the amount of material which would have to be disposed.

Twc.cabassnmnpolprev.DOC Page 11lA

O,0WO33
* uJONFIJJENTIIAL

Page 2 of 2 OPTIONAL POLLUTION PREVENTION INFORMATION

for the PMN Substance [Yttrium,Strontium,Barium,Calcium Manganese

Oxides]

[PC# 3997C]

In addition to the the PMN substance has the

advantage of being iron free. In the coloration of Polyvinyl chloride (PVC) for

weatherable applications (such as vinyl siding or window profiles) the use the

Green 17 and Black 30 pigments is widely accepted due to the low heat build

up properties. However, issues on recycling these materials exist because they

contain iron. If the total iron level gets too high, degradation of the PVC during

processing may occur. The PMN substance would allow for recycling of the

PVC without concern for iron contamination.

Better long term weathering performance for the PMN substance over carbon

black would be expected d, o. Coatings and plastics

with carbon black tend to crack or delaminate due to its p,- -

Therefore, a longer service life should be expected for parts manufactured with

the PMN substance instead of carbon black and hence reduce potential waste.

Chromium compounds and potentially nickel compounds must be carefully

handled for disposal. Leachability studies must be run to determine whether

or not the waste should be classified as hazardous (in the case of no other

category or classification for hazard) . Currently, this work would not be

necessary as none of the components-of the PMN substances-are controlled as

hazardous waste. If the materials containing the PMN substance are not

otherwise classified as hazardous for disposal, the PMN substance would not

need to be disposed of as a hazardous waste which would reduce hazardous

waste in comparison to the products containing Green 17 or Black 30.

The PMN substance is expected to out perform carbon black containing

coatings and plastics in terms of - - _7, and weathering

durability. Its higher cost can be offset by the extended life and higher

performance of the ware in which it is use and the energy savings associated

with a reduction of cooling costs. Overall, the PMN substance, when used in

place of carbon black, Green 17, or Black 30, will _-

tht ing. Because of the high

density and lower dusting, its use will reduce employee inhalation exposure

during manufacture, and of great importance, it will reduce hazardous waste

containing chromium and nickel compounds.

Twc.cabassfrmpolprev.D0C Page 11iB
7-art III -- .IST OF ATTACHMENTS

':jcf eoflhtnuanon '.Oect lor %crifons cr Inc torin ano test data and other data (including ph-vNical/chemical properties and

nw~turc etivitv intormationt. ana oriionai intormation itter this Page. Ctjrlv identity the attachment ana the tiomnott the torm to

* ura it roiatcs. it irprnpriatc. Number coflsx-utiveiv the races o tiIhe attacriments. In the column ociow. enter the inclusive page

:nwors or ecar attachment.

.%.irk tX) the 'Contidennal" box next to any attachment name you claim as contidlential. Read the Instructions Manual tur

* :rance on how to ciaim any intormation in in attachment as contidennal. You must include with the sanitized copv ot the notice

*rm a %liniti7.ed version ot any attachment in wnich You ciaim intormaton as contidlential.

A\ttachment namc Attachment Confi.

page number(s) dential

NMaterial Safety Data Sheet (MSDS) (Attachment 1) 14-67

Product Label (Attachment 2)687

CAS Inventory Expert Service Report BX

Product Structure B4

Process Description 1, PW4 Substance Manufacturing Operation 8a

Process Description 11, P191 Substance Manufacturing Operation Sb

iProcess Description 111, On Site Processing of the P141 Substance Sc

Part 11, HR&ER (cont) Sect A (cont) (for p. 8a processing) 9&

Part 11, HIRER (cont) Sect A (cant) (for p. Ob processing) 9b

Part 11, HRIER (cont) Sect A (cant) (for p. Sb processing (cont)) 9C

Part 11, HRIER (cont) Sect A (cant) (for p. Sc processing) 9d

Part I I,HR&ER(cont) Sect 8, Part 2 ~ ~-10a

Part 119 Operation Description, Explanation of Assumptions 101b

Part 11, Section B.2., Worker Exposure/Environmental Release Explanation of Assumptions 10c

Part 11, Section 6.1., Operation Description (IA) 10d

Part 11, Section 5.1., Operation Description (16) 1011

Part 11, Section B.1., Operation Description (IC) lOf

Part 119 Section 8.1., Operation Description (IIA) log

Part 11, Section B.1., Operation Description (11B) 10h

Part 11, Section 6.1., Operation Description (IIC) 10i fPart 11, Section B.l.9 Operation Description (111D) l0j

Part 1I, Section 6.1., Operation Description (lIE) 10k

Optional Pollution Prevention Information Ila - b

Part III, List of Attachments 12 - 12a

XX arkX) hi bo d ouattch cotiuaton het. Enter the attachment name and number. Part III, List of AttacIlents (contl

-:R.%EPA 7710-25 (Rev.5-95) Page 12
Part ill -- KIST OF ATTACHMENTS (continued)

-c ontinuation snits tor wecnons or the tonn ana ti t oa~a ind other data tincluding privsicalchemicai properties and

nict ure,,.Idivitv intormationi. ana otiona I in iormatin 3:,;L'r ti va cc. k eriv iden tityv the attachment and the st'ction or rte torm to

ntcni it rotates. it appropriate. Number cnn-Kxutivo'Iv ino ractn or tne attachments. Iii the cotumn below. onter the inclusive page

iimtx'rs ot eicn attachment.

'Aark t.\ the Conticdential" box next to any attachment name VO~U ciaim as contidential. Reid the Instructions Manual for

nliuance on how to claim any inrormation in in attacriment as contidcnral. You must include with thc sanitized copy cot the notice

'rn a '.jniti?.ed version ot any attachment in wnich vou ciaim intormatbon as conidential.

\ttahmet nae Atachment Confi-

%ttachmentt naeriz umberts) dential

Attachmient 3. Particle Size Measurement 74-76

Attachmnent 4. X-Ray Diffraction Patterns 77-86

Attachment 5, Evaluation of Risk 87-90

Attacmnent 6, Air Monitoring Results 91

Attachment 79 Solubility Data 9-0

Attachment 8, DMC2 Overview of Regulatory Compliance and Capabilities 103-112

D Mark tX) this box ii vou attach a continuation sheet. Enter th~e attachm~ent name and number.

FORM EP.'\710-25 tKev. 5-95) rage 12aU U 3
PHYSICAL AND CHEMICAL FROPERTTES WORKSHEET

To assist EPA's review of physical and cmical provernesa ata, please complete the tollowine worksheet for data you provide

and include it in the nonice. ldentiiv the property measured, the page oi the notice on whi the propmrt appears. the value

of the propert. the units in which the property is measured (as necessary), and whether or not the property is clained as

confidential. The physical state of the neat substance sriould be provided. Thes measured properues stiould be tor the neat (10096

pure) chemiical substance. Properties that are measured for mjuxrures or formulations should be so noted (% PMN substance in - ).You

are not required to submiut this worksheet: however. EPA strongly recommends that you do so. as it will stmphfv review and ensure

that conndiential information is properly protected. You should submit this worksheet as a supplemnent to your subission of tet

data. This worxsheet is not a substitute for submission of test data.

Proprty alueMmajwd CotitPrpryMark (X) if Page Valu dentl

(a) provided number 1IW Mak0

(b) (c) Mar 00

Physical state of neat substance Powder x i5s ... L (s) - a)....... W~ __

Vapor presure 20 6C0 E

O Tempverature TOtS

Densi ty/relative density 7.14 g/cmn3 N

Solubility

0 Temperature 9

Solvent /

Solubiltv in water 0 Tempieraiture OC

Meltinst temoerature ____ 9____ C

Boilne /subimation temperature tf pressure ____

Spectra X-Ray Diffraction xI See Attachment N X

77-86

Dissociation constant ____

Particle size distribution See Attachmnent 3 x 74-76 micror N

Octanol /water partition coelficient ___

Henry's Law constant

Voitalization from water 0 E

Vait alization from soil 0 E

pH 0 concentration _________________

Flammability ___

Explodabilitv_____

Adsorption /craeffient

Other - Specify

I I___
CUSTOMER - US EPA/OPPT/NEW CHEMICALS BRN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 08/10/00

EMERGENCY PHONE:

dmc2 CHEMTREC (800) 424-9300

DegussaMetalsCatalystsCerdec This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Lucy Sten

Product Safety Specialist

SECTION I - IDENTITY INFORMATION

TRADE NAME

CAS NUMBER :Not Available

PRODUCT CODE

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CFR 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

-Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

PAGE 14 0 -'
Page: 02 MATERIAL SAFETY DATA SHEET

1)

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.-

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

GREEN R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

BARIUM COMPOUND

Total Dust TWA 10.0 mg/M3 10.0 mg/M3

RESP 5.0 mg/M3

MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3

STEL 3.0 rng/M3 3.0 mg/M3

SECTION III - PHYSICAL DATA

APPEARANCE :Green Powder

WEIGHT PER GALLON :N/AV

BOILING RANGE N/AP

VOC :0 01 (See Note in Section XII -Addendum)

VAPOR DENSITY :Non Volatile

EVAPORATION RATE Non Volatile

SOLUBILITY IN WATER :Insoluble

PACE 15
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT N/AP

FLAMMABILITY CLASS NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT N/AP

UPPER EXPLOSION LIMIT :N/AP

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY : Stable

HAZARDOUS POLYMERIZATION : Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

PAGE 16 001'
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION V -REACTIVITY DATA (cont.)

HAZARDOUS DECOMPOSITION:

Will not occur.

SECTION VI -HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

This product contains mixed metal oxide pigment(s) which

consist of manganese in combination with other materials.

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

page 17 000011
Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA (cont.)

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

attention.

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

PAE 18 001
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VII - TOXICOLOGY INFORMATION (cont.)

TOX ICOLOGY INFORMATION

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

Wear safety glasses or goggles to protect against exposure.

PAGE 19 (3y94
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION IX - SPECIAL PROTECTION INFORMATION (cont.)

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

SECTION X - SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

Vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

PAGE 20OG}4
Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

1000% Barium Compound .501 Metal As Ba

100% Manganese Compound 40% Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Green R&d Pigment Not Available E

E =Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical Substance Inventory. Consequently

this product is presently available only in quantities necessary

for research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.O.C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

PAGE 21 COO4
Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - ADDENDUM (Cont.)

EPA = Environmental Protection Agency

TARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP = Not Applicable

N/AV = Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL = Permissible Exposure Limits

SARA = Superfund Amendments and Reauthorization Act

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA = Toxic Substance Control Act

TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = Volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PAGE 22
CUSTOMER -US EPA/OPPT/NEW CHEMICALS BRN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 08/10/00

EMERGENCY PHONE

dmc 2 CHEMTREC (800) 424-9300

DegussaMetalsCatalystsCerdec This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Lucy Sten

Product Safety Specialist

SECTION I - IDENTITY INFORMATION

TRADE NAME :,

CAS NUMBER :Not Available

PRODUCT CODE

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This Material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CFR 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

-Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

PAGE 23 0000T7
Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

BROWN R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

BARIUM COMPOUND

Total Dust TWA 10.0 mg/M3 10.0 mg/M3

RESP 5.0 mg/M3

MANGANE SE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3

STEL 3.0 mg/M3 3.0 mg/M3

SECTION III - PHYSICAL DATA

APPEARANCE :Brown Powder

WEIGHT PER GALLON :N/AV

BOILING RANGE :N/AP

VOC :0 0- (See Note in Section XII -Addendum)

VAPOR DENSITY :Non Volatile

EVAPORATION RATE :Non Volatile

SOLUBILITY IN WATER :Insoluble

PAGE 21*
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT N/AP

FLAMMABILITY CLASS :NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT :N/AP

UPPER EXPLOSION LIMIT :N/AP

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY : Stable

HAZARDOUS POLYMERIZATION : Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

PAGE 25 000049
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION V -REACTIVITY DATA (cont.)

HAZARDOUS DECOMPOSITION:

Will not occur.

SECTION VI -HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

This product contains mixed metal oxide pigment(s) which

consist of manganese in combination with other materials.

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

PAGE 26 000050
Page: 05 MATERIAL SAFETY DATA SHEET

R1

SECTION VI - HEALTH HAZARD DATA (cont.)

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

attention.

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

PAGE 27 000051
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VII -TOXICOLOGY INFORMATION (cant.)

TOXI COLOGY INFORMATION

SECTION VIII -SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

Wear safety glasses or goggles to protect against exposure.

PAGE 28 000052
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION IX - SPECIAL PROTECTION INFORMATION (cont.)

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

SECTION X - SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

Vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

PACE 29 000053
Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

100% Barium Compound .57% Metal As Ba

100% Manganese Compound .23% Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Brown R&d Pigment Not Available E

E = Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical Substance Inventory. Consequently

this product is presently available only in quantities necessary

for research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS:

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.O.C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

000054

PAGE 30
Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - ADDENDUM (Cont.)

EPA = Environmental Protection Agency

IARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP = Not Applicable

N/AV = Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL = Permissible Exposure Limits

SARA = Superfund Amendments and Reauthorization Act

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA = Toxic Substance Control Act

TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = Volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PAGE 31 000055
CUSTOMER - US EPA/OPPT/NEW CHEMICALS BRN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 12/21/99

EMERGENCY PHONE:

Cerdec Corporation CHEMTREC (800) 424-9300

Drakenfeld Products This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Jeff Miller

Environmental Engineer

SECTION I - IDENTITY INFORMATION

TRADE NAME

CAS NUMBER :Not Available

PRODUCT CODE

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This Material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CFR 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

-Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

00005G

PACE 32
Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

BROWN R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3

STEL 3.0 mg/M3 3.0 mg/M3

SECTION III - PHYSICAL DATA

APPEARANCE :Brown Powder

WEIGHT PER GALLON : N/AV

BOILING RANGE : N/AP

VOC : 0 %(See Note in Section XII -Addendum)

VAPOR DENSITY :Non Volatile

EVAPORATION RATE : Non Volatile

SOLUBILITY IN WATER : Insoluble

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT : N/AP

FLAMMABILITY CLASS : NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT :N/AP

UPPER EXPLOSION LIMIT :N/AP

PAGE 33 0000517
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA (cont.)

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY : Stable

HAZARDOUS POLYMERIZATION : Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

HAZARDOUS DECOMPOSITION:

Will not occur.

PAGE 34 000058s
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

This product contains mixed metal oxide pigment(s) which

consist of manganese in combination with other materials.

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

PAGE 35 000059
Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA (cont.)

EYES:

attention.

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

PAGE 36

000060O
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - SPILL OR LEAK PROCEDURES (cont.)

SPILL PROCEDURES:

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

PAE 37 000061
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

100% Manganese Compound .51% Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Brown R&d Pigment Not Available E

E = Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical Substance Inventory. Consequently

this product is presently available only in quantities necessary

000062

PAGE 38
Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION (cont.)

TOXIC SUBSTANCE CONTROL ACT (TSCA):

for research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.O.C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

EPA = Environmental Protection Agency

IARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP = Not Applicable

N/AV = Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL = Permissible Exposure Limits

SARA = Superfund Amendments and Reauthorization Act

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA = Toxic Substance Control Act

PAGE 39 0000G3
Page: 09 MATERIAL SAFETY DATA SHEET

RD

SECTION XII - ADDENDUM (Cant.)

TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = Volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PAGE 40 000064
CUSTOMER -US EPA/OPPT/NEW CHEMICALS BRN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 12/21/99

EMERGENCY PHONE:

Cerdec Corporation CHEMTREC (800) 424-9300

Drakenfeld Products This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Jeff Miller

Environmental Engineer

SECTION I - IDENTITY INFORMATION

TRADE NAME

CAS NUMBER :Not Available

PRODUCT CODE

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This Material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CER 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

-Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

PAGE 4*1 000065
Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

BLACK R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

MANGANE SE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3

STEL 3.0 rng/M3 3.0 mg/M3

SECTION III - PHYSICAL DATA

APPEARANCE :Gray Powder

WEIGHT PER GALLON :N/AV

BOILING RANGE :N/AP

VOC :0 %(See Note in Section XII -Addendum)

VAPOR DENSITY :Non Volatile

EVAPORATION RATE :Non Volatile

SOLUBILITY IN WATER :Insoluble

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT N/AP

FLAMMABILITY CLASS :NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT :N/AP

UPPER EXPLOSION LIMIT :N/AP

PAGE 42 000066
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA (cont.)

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY : Stable

HAZARDOUS POLYMERIZATION : Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

HAZARDOUS DECOMPOSITION:

Will not occur.

PAGE 43 00006?
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

attention.

PAGE 4400G
Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA (cant.)

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

000069

PAGE 45
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - SPILL OR LEAK PROCEDURES (cont.)

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

Wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

PAGE 16 0 0 070,
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

Vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

1000i Manganese Compound .29%- Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Black R&d Piment Not Available E

E = Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical Substance Inventory. Consequently

this product is presently available only in quantities necessary

PAGE 47 0000,71
Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION (cont.)

TOXIC SUBSTANCE CONTROL ACT (TSCA):

f or research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII -ADDENDUM

DEFINITIONS AND ABBREVIATIONS

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.O.C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

EPA = Environmental Protection Agency

IARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP = Not Applicable

N/AV = Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL = Permissible Exposure Limits

SARA = Superfund Amendments and Reauthorization Act

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA = Toxic Substance Control Act

PAGE '&8 000017t2
Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - ADDENDUM (Cont.)

TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = Volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PAGE 49 0000713
CUSTOMER - US EPA/OPPT/NEW CHEMICALS BRN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 12/21/99

EMERGENCY PHONE:

Cerdec Corporation CHEMTREC (800) 424-9300

Drakenfeld Products This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 -gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Jeff Miller

Environmental Engineer

SECTION I - IDENTITY INFORMATION

TRADE NAME F

CAS NUMBER :Not Available

PRODUCT CODE7

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This Material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CFR 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

- Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

PAGE 50 0000~74
Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.

Ingredients CAS NUMBER ACGIH - TLV OSHA - PEL

BLACK R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 rng/M3

STEL 3.0 mg/M3 3.0 mg/M3

SECTION III -PHYSICAL DATA

APPEARANCE :Gray Powder

WEIGHT PER GALLON :N/AV

BOILING RANGE :N/AP

VOC :0 0- (See Note in Section XII -Addendum)

VAPOR DENSITY :Non Volatile

EVAPORATION RATE :Non Volatile

SOLUBILITY IN WATER :Insoluble

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT :N/AP

FLAMMABILITY CLASS :NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT :N/AP

UPPER EXPLOSION LIMIT :N/AP

PAGE 51 00Y
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA (cont.)

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY :Stable

HAZARDOUS POLYMERIZATION :Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

HAZARDOUS DECOMPOSITION:

will not occur.

PAGE 52 oooom1(4
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

attention.

PAGE 53 0000~77
Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA (cant..)

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

PAGE 54* 000078
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - SPILL OR LEAK PROCEDURES (cont.)

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

Wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

PAGE 55 000079
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X - SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

Vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

100%0 Manganese Compound .29% Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Black R&d Pigment Not Available E

E = Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical Substance Inventory. Consequently

this product is presently available only in quantities necessary

PAGE 56 000030
Page: 08 MATERIAL SAFETY DATA SHEET

SECTION XI - REGULATORY INFORMATION (cont.)

TOXIC SUBSTANCE CONTROL ACT (TSCA):

for research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS -

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.0. C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

EPA = Environmental Protection Agency

IARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP = Not Applicable

N/AV = Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL = Permissible Exposure Limits

SARA = Superfund Amendments and Reauthorization Act

STEL = Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA = Toxic Substance Control Act

PAGE 57 008
Page: 09 MATERIAL SAFETY DATA SHEET - -9)

SECTION XII - ADDENDUM (Cont.)

TWA =Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = Volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PACE 58 000082
CUSTOMER - US EPA/OPPT/NEW CHEMICALS ERN

Page: 1 MATERIAL SAFETY DATA SHEET

Prepared: 08/10/00

EMERGENCY PHONE:

dmc 2 CHEMTREC (800) 424-9300

DegussaMetal sCatalystsCerdec This number is to be used only

P.O. Box 519 in the event of chemical emerWashington PA 15301 gencies involving a spill, leak,

Information Phone: 724-223-5900 fire, exposure or accident

involving chemicals

Prepared By :Lucy Sten

Product Safety Specialist

SECTION I - IDENTITY INFORMATION

TRADE NAME

CAS NUMBER :Not Available

PRODUCT CODE

FAMILY/CHEMICAL NAME:

Pigment.

PRODUCT TYPE:

Mixed Metal Oxide.

HAZARD STATEMENT:

This Material Safety Data Sheet (MSDS) has been prepared in

compliance with the Federal OSHA Hazard Communication Standard

29 CFR 1910.1200.

This product is considered to be a hazardous substance under

that standard.

The key Immediate Hazards are:

- Skin, eye and respiratory irritant.

SECTION II - HAZARDOUS INGREDIENTS

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

PAGE 59
Page: 02 MATERIAL SAFETY DATA SHEET

SECTION II - HAZARDOUS INGREDIENTS (cont.)

HAZARD STATEMENT:

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

The pigment and/or frit ingredient(s) do not have exposure limit

values. Exposure limit values for the components are listed

beneath each ingredient as a guideline for safe use of these

products.

Ingredients CAS NUMBER ACGIH - TLV OSHA -PEL

BLACK R&D PIGMENT Not Availab

Carcinogenicity:

This product is not listed as a

carcinogen by IARC, NTP or OSHA.

MANGANESE COMPOUND

Dust As Mn TWA 0.2 mg/M3

STEL C 5.0 mg/M3

Fume As Mn TWA 0.2 mg/M3 1.0 mg/M3

STEL 3.0 mg/M3 3.0 mg/M3

SECTION III -PHYSICAL DATA

APPEARANCE :Black Powder

WEIGHT PER GALLON :N/AV

BOILING RANGE :N/AP

VOC 0 0- (See Note in Section XII -Addendum)

VAPOR DENSITY Non Volatile

EVAPORATION RATE :Non Volatile

SOLUBILITY IN WATER :Insoluble

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA

FLASH POINT :N/AP

FLAMMABILITY CLASS :NON-COMBUSTIBLE

LOWER EXPLOSION LIMIT :N/AP

UPPER EXPLOSION LIMIT :N/AP

PAGE 60 0 0084
Page: 03 MATERIAL SAFETY DATA SHEET

SECTION IV - FIRE AND EXPLOSIVE HAZARD DATA (cont.)

EXTINGUISHING MEDIA:

Water.

FIRE FIGHTING PROCEDURES-SPECIAL:

Fire-Fighters should wear self-contained breathing apparatus and

full protective clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed

to fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

This product will not burn. Use appropriate techniques to fight

surrounding fire.

SECTION V - REACTIVITY DATA

STABILITY :Stable

HAZARDOUS POLYMERIZATION :Will not occur

CONDITIONS TO AVOID:

None Known.

INCOMPATIBILITY:

None known.

HAZARDOUS DECOMPOSITION:

will not occur.

PCE61 000085
Page: 04 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA

This product contains either pigment(s) that belong to the mixed

metal oxide pigment class and/or frit which is an amorphous

glassy material. These ingredients have been chemically reacted

at high temperatures. They consist of metal atoms and oxygen

atoms arranged in unique structures; the toxicological

properties have not been thoroughly investigated. A small

percentage of the starting materials may remain in this product

and are considered hazardous under OSHA.

PRIMARY ROUTES OF EXPOSURE:

Inhalation, dermal and ingestion.

OVEREXPOSURE EFFECTS:

This product contains mixed metal oxide pigment(s) which

consist of manganese in combination with other materials.

CONTAINS MANGANESE COMPOUNDS:

Manganese compounds are not considered toxic by ingestion or

skin contact. Chronic inhalation of manganese oxide dust

during mining or fumes during steel processing can affect

the brain. Symptoms may take more than two years to develop

and have included apathy, sleepiness, confusion, compulsive

behavior, hallucinations, irritability, loss of balanc e

difficulty in walking and impotence.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

Respiratory conditions.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:

For eye contact, immediately flush eyes for at least 15 minutes

with running water. Hold eyelids apart to ensure rinsing of the

entire eye surface and lids with water. Get immediate medical

PAGE 62

00008G
Page: 05 MATERIAL SAFETY DATA SHEET

SECTION VI - HEALTH HAZARD DATA (cont.)

EYES:

attention.

SKIN:

For skin contact, wipe away excess material with dry towel.

Then wash affected areas with plenty of water, and soap if

available, for several minutes. Get medical attention if

irritation occurs.

INHALATION:

If inhaled, remove from area to fresh air. Get medical

attention if respiratory irritation develops or if breathing

becomes difficult.

INGESTION:

If swallowed, give at least 3-4 glasses of water, but do not

induce vomiting. Do not give anything by mouth to an

unconscious or convulsing person. Get medical attention.

PHYSICIAN'S NOTE:

None specified.

SECTION VII - TOXICOLOGY INFORMATION

Toxicology data of some components is available upon request.

Please contact the Product Safety Specialist at (724) 223-5900.

SECTION VIII - SPILL OR LEAK PROCEDURES

SPILL PROCEDURES:

Wear appropriate protective equipment. Avoid the generation of

dust. Vacuum or shovel material and place in closable

container(s) for disposal.

PAGE 63

000087
Page: 06 MATERIAL SAFETY DATA SHEET

SECTION VIII - SPILL OR LEAK PROCEDURES (cont.)

SPILL PROCEDURES:

WASTE DISPOSAL METHODS:

Dispose in accordance with Federal, State and Local regulations.

SECTION IX - SPECIAL PROTECTION INFORMATION

VENTILATION:

Adequate ventilation should be provided to keep dust and vapor

concentrations below acceptable Exposure Limits. Discharge from

the ventilation system should comply with the applicable air

pollution control regulations. Eliminate ignition sources.

PROTECTIVE GLOVES:

Use gloves as a standard industrial handling procedure.

EYE PROTECTION:

Wear safety glasses or goggles to protect against exposure.

RESPIRATORY PROTECTION:

Appropriate respiratory protection is required when exposure to

airborne contaminant is likely to exceed acceptable limits.

Respirators should be selected and used in accordance with OSHA

Subpart I (29 CFR 1910.134) and manufacturer's recommendations.

OTHER PROTECTIVE EQUIPMENT:

None specified.

PAGE 64~008
Page: 07 MATERIAL SAFETY DATA SHEET

SECTION X -SPECIAL PRECAUTIONS

LABELING INFORMATION:

WARNING!

Skin, eye and respiratory irritant.

Keep away from heat and flame.

Avoid contact with eyes, skin and clothing.

Avoid breathing dust.

Keep away from food products.

Wash thoroughly after handling and before eating, drinking or

using cosmetic or tobacco products or toilet facilities.

Use with adequate ventilation.

Keep container closed when not in use.

FIRST AID:

If inhaled, remove to fresh air. If not breathing, give

artificial respiration. If breathing is difficult, give

oxygen. In case of contact, immediately flush eyes or skin

with plenty of water. Remove contaminated clothing. Get

medical attention.

IN CASE OF FIRE:

Use water, dry chemical or carbon dioxide.

IN CASE OF SPILL:

vacuum and dispose in accordance with federal, state and

local regulations.

For industrial use only.

SECTION XI - REGULATORY INFORMATION

SARA 313 TITLE III - TOXIC CHEMICALS LIST:

1000- Manganese Compound .390- Metal As Mn

PENNSYLVANIA RIGHT-TO-KNOW ACT:

Black R&d Pigment Not Available E

E = Pennsylvania Environmental Hazardous Substance

TOXIC SUBSTANCE CONTROL ACT (TSCA):

one or more chemical substances in this product are not yet

listed on the TSCA Chemical substance Inventory. Consequently

this product is presently available only in quantities necessary

PAGE 65 000089
Page: 08 MATERIAL SAFETY DATA SHEET

DR' 2

SECTION XI - REGULATORY INFORMATION (cant.)

TOXIC SUBSTANCE CONTROL ACT (TSCA):

f or research and development purposes as defined by TSCA. The

potential health and environmental risks associated with

these new chemical substances are not fully characterized.

Thus the use of this product is restricted to those

technically qualified individuals having the authority to

to manage the use, storage, or handling of the product so as

to minimize any risks.

SECTION XII - ADDENDUM

DEFINITIONS AND ABBREVIATIONS:

Note: The V.O.C., listed in Section III, Physical Data, is an

estimated/calculated value based upon the EPA Method 24 for

determining V.O.C.

ACGIH = American Conference of Governmental Industrial Hygienists

C (Ceil) = The concentration that shall not be exceeded during any part of

the working exposure.

CAS = Chemical Abstracts Service Registry Number

EPA = Environmental Protection Agency

IARC = International Agency for Research on Cancer

LEL = Lower Explosion Limit

N/AP =Not Applicable

N/AV =Not Available

NIOSH = National Institute for Occupational Safety and Health

NTP = National Toxicology Program

OSHA = Occupational Safety and Health Administration

PEL =Permissible Exposure Limits

SARA =Superfund Amendments and Reauthorization Act

STEL =Short Term Exposure Limit. Usually a 15 minute time weighted

average exposure that should not be exceeded at any time during

a work day.

TLV = Threshold Limit Values

TSCA =Toxic Substance Control Act

PAGE 66 000090
Page: 09 MATERIAL SAFETY DATA SHEET

SECTION XII - ADDENDUM (Cant.)

TWA = Time Weighted Average. Exposure concentration for a normal

8 hour work day and a 40 hour work week.

VOC = volatile Organic Content

DISCLAIMER

The information and recommendations contained herein are based upon data

believed to be correct. However, no guarantee or warranty of any kind

expressed or implied is made with respect to the information contained herein.

PAGE 67 000091
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