Conforms to Regulation (EC) No. 1907/2006 (REACH),

_**A,nnex~rr :·** **unitep** Kin '**dom":~~ ~)**  ' )

..l

..·. . . 

### ,--_ii::-; 

## SAFETY DATA SHEET

. . ... .**~; --** **~** 

## . -, _ J,**-Jl.....:.;.~**
.**··>r,<~-;;v** 

## Jotun Thinner No. 17 SECTION 1: Identification ofthe substance/mixture and of the company/undertaking 1.1 Product Identifier

Product name Product code Product description Product type Jotun Thinner No. 17 553 Coatings: Solvent-borne. Liquid. Other means of Identification Not available

.


### 1.2 Relevant Identified uses ofthe substance or mixture and uses advised against

Uses in Coatings
- Industrial use Uses in Coatings • Professional use Identified uses

See Annex to the Safety data sheet for additional Information In the Exposure Scenario(s). 

### 1.3 Details ofthe supplier ofthe safety data sheet Jotun Paints (Europe) ltd. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +4417 24 40 

## oo oo Fax: +44 17 24 40 01 00 SDSJotun@jotun.com
1.4 Emergency telephone number

Contact National Poison Centre via Hospital or Registered Medical Practitioner 

# I SECTION 2: Hazards identification 2.1 Classification ofthe substance or mixture

Product definition : Mixture Classification according to Directive 1999/45/EC [DPDJ

The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification R10 Xn; R20/21, R65 XI; 

### R41, R37/38 N; R51/53 Physical/chemical hazards Flammable

. Human health hazards Harmful by Inhalation and in contact with skin. Harmful: may cause lung damage if swallowed. Risk of serious damage to eyes. Irritating to respiratory system and skin

. Environmental hazards Toxic 

### to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for 

### the full text ofthe R phrases or H statements declared above. See Section 

### 11 for more detailed information on health effects and symptoms

. 

### 2.2 Label elements ' 

## ....



# I Date of Issue 

### 17.1 0.2012. 

### 1/141Conforms to Regulation (EC) No. 1907/2006{REACH), Annex II
- United Kingdom (UK) Jotun ThinnerNo. 17 

## SECTION 2: Hazards identification

Hazard symbol orsymbols :

Indication ofdanger Risk phrases --- 

# . i

I I I ' 

### ! ' Harmful, Dangerous for the environment R10- Flammable. R20/21- Harmful by Inhalation and in contact with skin

. R65- Harmful: may cause lung damage ifswallowed

. R41- Risk ofserious damage to eyes. R37/38- Irritating to respiratory system and skin. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases S2- Keep out of the reach of children

. S23- Do not breathe vapour 

### I spray. S26- In case of contact with eyes, rinse immediately with plenty ofwater and seek medical advice

. S29- Do not empty Into drains. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection

. S46- Ifswallowed, seek medical advice Immediately and show this container or label

. S51- Use only in well-ventilated areas. Hazardous Ingredients Solvent naphtha (petroleum), light arom. Supplemental label elements


### 2.3 Other hazards xylene Not applicable.

Other hazards which do not Not available. result In classification 

# I SECTION 3: Composition/information on ingredients Substance/mixture : Mixture Classification Product/ingredient Identifiers % 67/548/EEC Regulation {EC) No. name 1272/2008 [CLP] Solvent naphtha REACH#: 01- 50-75 R10 Flam. Llq

. 3, H226 (petroleum), light 2119455851-35 arom. EC: 265·199-0 Xn;R20,R65 Acute Tox. 4, H332 CAS: 64742-95-6 Xi;R37 STOT SE 3, H335 Index: 649-356-00-4 R66 Asp.Tox

. 1,H304 N; R51/53 Aquatic Chronic 

### 2, H411 xylene REACH#: 01
- 20-25 R10 Flam

. Liq. 3, H22E? 2119488216-32 EC: 215-535-7 Xn; R20/21 Acute Tox

. 4 , H312 CAS: 1330-20-7 Xi;R38 Acute Tox

. 4, H332 Index: 601-022-{)0-9 Skin lrrit. 2, H315 butan-1-ol REACH#: 01- 15-20 R10 Flam

. Liq. 3, H226 2119484630-38 EC: 200-751-6 Xn ; R22 Acute Tox. 4, H302 CAS: 71
-36-3 

### Xi; R41, R37/38 Skin lrrit. 2, H315 Index: 603-004-00-6 R67 Eye Dam. 1, H318 STOT SE 3, H335 and H336 ethylbenzene REACH#: 01- 

### 3-7 

### F; R11 Flam. Llq

. 2, H225 2119489370-35 EC : 202-849-4 Xn ; R20 Acut e Tox

. 4, H33 2 CAS: 100-41-4 Index: 601-023-00-4 

# I Date of Issue 17

.10

.2012

. Type Notes [1 ) [2] 

### H·P

[1] [2] 

## c

[1] [2] 

# -

[1] [2] 

# - 

# I IConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II -United Kingdom {UK) Jotun Thinner No. 17 

## SECTION 3: Composition/information on ingredients See Section 16for See Section 16 for the full text ofthe R- the full text ofthe H phrases declared statements declared above. above

. There are no additional ingredients present which, within the current knowledge ofthe suppl ier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs orvPvBs or have been assigned a workplace exposure limit and hence require reporting In this section.**~** [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No

. 1907/2006, Annex XIII Occupational exposure limits, if available, are listed in Section 8. 

# I SECTION 4: First aid measures 4.1 Description offirst aid measures

General

Inhalation

Skin contact Eye contact Ingestion Protection offirst-alders In all cases of doubt, orwhen symptoms persist, seek medical attention. Nevergive anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. Remove to fresh air. Keep person warm and at rest. If not breathing, If breathing is Irregular or if respiratory arrestoccurs, provide artificial respiration or oxygen by trained personnel. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents orthinners. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention

. Ifswallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting

. No action shall be taken Involving any personal risk orwithout suitable train ing. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most Important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact Inhalation Skin contact Ingestion Severely Irritating to eyes. Risk ofserious damage to eyes. Harmful by inhalation

. Irritating to respiratory system

. Harmful in contact with skin. Irritating to skin

. Aspiration hazard ifswallowed. Can enter lungs and cause damage. Irritating to mouth, throat and stomach

. Over-exposure signs/symptoms

Eye contact Adverse symptoms may Include the following: pain or Irritation watering redness Inhalation Adverse symptoms may incl ude the following : respiratory tract Irritation Skin contact Ingestion coughing Adverse symptoms may include the following: irritation redness Adverse symptoms may include the following : nausea orvomiting
4.3 Indication ofany Immediate medical attention and special treatment needed

Notes to physician Treat symptomatically

. Contact poison treatment specialist immediately iflarge quantities have been ingested or Inhaled. Specific treatments No speclflc treatment. 

# I



# I Date of Issue : 17.10.2012

. 

### 31141Conforms to Regulation (EC) No

. 1907/2006 (REACH), Annex II
- United Kingdom (UK) Jotun Thinner No. 17 

# J SECTION 4: First aid measures 

# I SECTION 5: Firefighting measures 5.1 Extinguishing media

Suitable extinguishing media Unsuitable extinguishing media Recommended: alcohol-resistant foam , CO 2, powders, water spray.
Do not use waterjet

5

.2 Special hazards arising from the substance or mixture

Hazards from the Flammable liquid. In a fire or if heated, a pressure increase will occur and the substance or mixture container may burst, with the risk of a subsequent explosion

. Runoffto sewer may Hazardous thermal decomposition products

5.3 Advice forfirefighters

Special protective actions for fire-fighters

Special protective equipment forfire-fighters create fire or explosion hazard. Decomposition products may include the followi ng materials: carbon dioxide carbon monoxide
Promptly Isolate the scene by removing all persons from the vicinity ofthe Incident if there is a fire

. No action shall be taken involving any personal risk orwithout suitable training

. Move containers from fire area Ifthis can be done without risk. Use water spray to keep fire-exposed containers cool. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or d r ain. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. 

# I SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency No action shall be taken Involving any personal risk or without suitable training. personnel Evacuate surround ing areas. Keep unnecessary and unprotected personnel from entering

. Do nottouch orwalk through spilt material. Shut off all ignition sources. No flares, smoking orflames In hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is Inadequate

. Put on appropriate personal protective equipment. For emergency responders Ifspecialised clothing is required to deal with the spillage, take note ofany information in Section 8 on suitable and unsuitable materials

. See also Section 8 for additional Information on hygiene measures. 6.2 Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities ifthe product has caused environmental pollution (sewers, waterways, soil or ai r)

. Water polluting material. May be harmful to the environment if released In large quantities

. 6.3 Methods and materials for containmentand cleaning up

Small spill Stop leak ifwithout risk. Move containers from spill area. Dilute with water and mop up ifwater-soluble

. Alternatively, or Ifwater-insoluble, absorb with an inertdry material and place In an appropriate waste disposal container

. Use spark-proof tools and explosion-proof equipment. Dispose ofvia a licensed waste disposal contractor

.



# I Date of issue 

### 17

. 10

.2012. 

# IConfonns to Regulation (EC) No. 1907/2006 (REACH), Annex II
- United Kingdom (UK) Jotun ThinnerNo. 17 

## SECTION 6: 

## Accidental release measures

Large spill

6.4 Reference to other sections Stop leak ifwithout risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages Into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, verm iculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information

. 

## jsECTION 7: 

## Handling and storage The information in this section contains generic advice and gu idance

. The list of Identified Uses In Section 1 should be consulted for any available use-specific Information provided In the Exposure Scenarlo(s). 7.1 Precautions for safe handling Prevent the creation of flammable or explosive concentrations of vapours In air and avoid vapour concentrations higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded

. Electrical equipment should be protected to the appropriate standard. To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators should wear antistatic footwear and clothing and floors should be ofthe conducting type. Keep away from heat, sparks and flame. No sparking tools should be used. Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this preparation. Avoid inhalation ofdust from sanding. Eating, drinking and smoking should be prohibited In areas where this material Is handled, stored and processed

. Put on appropriate personal protective equipment (see Section 8)

. Never use pressure to empty

. Container is not a pressure vessel. Always keep in containers made from the same material as the original one. Comply with the health and safety at work laws. Information on fire and explosion protection Vapours are heavier than air and may spread along floors

.Vapours may form explosive mixtures with air. When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits

. 7.2 Conditions for safe storage, Including any incompatibilities Store in accordance with local regulations. Notes on jointstorage Keep away from: oxidising agents , strong alkalis, strong acids

. Additional information on storage conditions Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away from sources of ignition

. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)

Recommendations Industrial sector specific solutions



# I Date of Issue Not available

. Not available

.

17

.10

.2012. 

## I

# IJotun ThinnerNo. 17 

# I SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for 

### any available use-specific information provided in the Exposure Scenario(s)

. 8.1 Control parameters

Occupational exposure limits ProducUingredient name Exposure limitvalues Solvent naphtha (petroleum}, light arom . EH40·WEL (United Kingdom (UK}, 12/2011). Absorbed through
xylene

butan-1-ol
ethyfbenzene

Recommended monitoring procedures

Derived effect levels

No DELs available

. Predicted effect concentrations

No PECs available

.
8.2 Exposure controls

Appropriate engineering controls

Individual protection measures skin. TWA: 200 mg/m" 8 hour(s). Form: All forms TWA: 40 ppm 8 hour(s}. Form: All forms EH40/2005 WELs (United Kingdom (UK), 8/2007)

. Absorbed through skin.

STEL: 441 mglm2 15 minute(s)

. STEL: 100 ppm 15 minute(s)

. TWA: 220 mg/m 3 8 hour(s). TWA: 50 ppm 

### 8 hour(s}. EH40/2005 WELs (United Kingdom (UK), 8/2007)

. Absorbed through skin

.

STEL: 154 mg/m" 15 mfnute(s). STEL: 50 ppm 15 minute(s). EH40/2005 WELs (United Kingdom (UK), 8/2007)

. Absorbed through skin.

STEL: 552 mg/m" 15 mlnute(s). STEL: 125 ppm 15 minute(s}. TWA: 100 ppm 8 hour(s). TWA: 

### 441 mglm" 

### 8 hour(s)

. 

### If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness ofthe ventilation or other control measures and/or the necessity to use respiratory protective equipment Reference should be made to European Standard EN 

### 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination ofhazardous substances

.

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended orstatutory limits

. The engi neering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits

. Use explosion-proofventilation equipment. Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and atthe end ofthe working period

. Appropriate techniques should be used to remove potentially contaminated clothing

. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location

. Eye/face protection

Skin protection

Hand protection 

# I Data of Issue Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts.
For prolonged or repeated handling , use the following type ofgloves: gloves: polyvinyl alcohol or nitrile. Barrier creams may help to protect the exposed areas ofthe skin but should not be applied once exposure has occurred

.

: 17.10.2012

.Conforms to Regulation (EC) No.1907/2006 (REACH), Annex II- United Klngdom_iUK) Jotun ThinnerNo. 

### 17 

## SECTION 8: Exposure controls/personal protection

Body protection
Other skin protection Respiratory protection

Environmental exposure controls For prolonged or repeated handling, use the following type of gloves: Recommended, gloves(breakthrough time)> 8 hours: 4H, Teflon, nitrile rubber 

### May be used, gloves(breakthrough time} 

### 4- 8 hours: neoprene, butyl rubber, Viton®, Barricade, CPF 3, Responder, PVC, polyvinyl alcohol (PVA} Not recommended, gloves(breakthrough time) < 

### 1 hour: PE For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier ofchemical resistant gloves

. The user must check that the final choice of type ofglove selected for handling this product is the most appropriate and takes into account the particular conditions of use, as included In the user's risk assessment. Personal protective equipment for the body should be selected based on the task being performed and the risks Involved and should be approved by 

### a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Ifworkers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air orfresh-air respiratory equipment. When use of roller or brush, consider use ofcharcoalfilter. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

J

## SECTION 9: Physical and chemical properties 9

. 1 Information on basic physical and chemical properties

Appearance

Physical state Colour Odour Odour threshold 

### pH Melting point/freezing point Initial boiling point and bolllng range Flash point Evaporation rate Flammability (solid, gas)

Bumlngtlme Burning rate Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density Solublllty(les) Partition coefficient: noctanollwater Auto-ignition temperature Decomposition temperature VIscosity Explosive properties 

# I Date of Issue Liquid. Clear. Characteristic

. Not available

. Not available

. Not available. Not available. Closed cup: 2s•c Not available

. Not available

. Not applicable

. Not applicable. 

### 1.1 -11.3% Not available. Not available. 

### 0.86 g/cm' Insoluble in the following materials: cold water and hot water

. Not available

. Not available. Not available. Not available

. Not available. 17.10.2012

. 

### 71141

# IConforms to Regulat ion (EC) No

. 1907/2006 (REACH), Annex II ·United Kingdom (UK) Jotun ThinnerNo. 17 

## SECTION 9: Physical and chemical properties

Oxidising properties : Not available

. 9.2 Other i nformation

No additional information

. 

# I SECTION 10: Stability and reactivity 10.1 Reactivity 10

.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10

. 5 Incompatible materials 10.6 Hazardous decomposition products No specific test data related to reactivity available for this product or its ingredients. The product is stable

. Under normal conditions of storage and use, hazardous reactions will not occur. Avoid a ll possible sou rces ofignition (spark orflame)

. Do not pressurise, cut, weld , braze, solder, drill, grind or expose containers to heat orsources of Ignition

. Reactive or incompatible with the following materials: oxidizing materials Under normal conditions of storage and use, hazardous decomposition products should not be produced

. 

# I SECTION 11: Toxicological information 11.1 Information on toxicological effects There are no data available on the preparation itself. The preparation has been assessed following the conventional method ofthe Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly

. See sections 2 and 15 for details. Exposure to component solvent vapour concentrations in excess ofthe stated occupational exposure limit may result In adverse health effects such as mucous membrane and resp iratory system irritation and adverse effects on the kidneys, liver and central nervous system

. Solvents may cause some of the above effects by absorption through the skin

. Symptoms and signs Include headache, dizziness, fatigue, muscularweakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact w ith the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin

. Ifsplashed i n the eyes, the liquid may cause Irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-Intestinal irritation and chemical pneumonia. Aspiration hazard if swallowed. Can enter lungs and cause damage

. Risk ofserious damage to eyes. Product/ingredient name Result Species Dose Exposure xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours**butan 1-ol**  LC50 Inhalation Gas. Rat 8000ppm 4 hours LC50 Inhalation Vapour Rat 24000 mglm3 4 hours LD50 Dermal Rabbit 3400 mg/kg 

# - LD50 Oral Rat 790 mglkg 

# - ethylbenzene LD50 Oral Rat 3500 mglkg 

# - 

# I SECTION 12: Ecological information 12

. 1 Toxicity

Product/Ingredient name Result Species Exposure Solvent naphtha (petroleum), Acute EC50 <1 0 mg/L Daphnia 48 hours lightar om. Acute IC50 <10 mgll Algae 72 hours Acute LC50 <1 0 mg!L Fish 

### 96 hours ethylbenzene Acute EC50 7,2 mgll Algae 48 hours Acute EC50 2 ,93 mg/L Daphnia 48 hours Acute LC50 4 ,2 mgll Fish 

### 96 hours Conclusion/Summary Water polluting material. May be harmful to the environment If released in large quantities

. This material is toxicto aquatic life with long lasting 

### effects

. 12

.2 Persistence and degradablllty 

# I Date of Issue : 17

. 10.2012. 

# IConfonns to Regulation (EC) No. 1907/2006 (REACH), Annex II
- United Kingdom (UK) Jotun ThinnerNo. 17 

## SECTION 12: Ecological information

Conclusion/Summary : Not available. Product/Ingredient name Aquatic half·life Solvent naphtha (petroleum},
- light arom . xylene 

# - ethylbenzene


## -

12

.3 Bloaccumulative potential

Product/ingredient name xylene butan-1-ol
12.4 Mobility In soil

Soli/water partition coefficient (Koc) Mobility LogPow 

### 3,12 0,88

Not available. Not available.
12

.5 Results of PBT and vPvB assessment

PBT Not applicable. vPvB Not applicable. Photolysis



# -

-

-

BCF



# -

-

12.6 Other adverse effects No known significant effects or critical hazards. 

# I SECTION 13: Disposal considerations Biodegradability Not readily Readily Readily

Potential high low

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific Information provided in the Exposure Scenario{s)

. 13.1 Waste treatment methods Do not allow to enter drains 

### orwatercourses. Material and/or container must be disposed of as hazardous waste. European waste catalogue 

### 08 01 11

### * Waste paint and varnish containing organic solvents or other dangerous 

# J

(EWC) substances

. Ifthis product Is mixed with other wastes, this code may no longer apply. If mixed with other wastes, the appropriate code should be assigned. For further information, contact your local waste authority. 

## !sECTION 14: Transport information

Transport within user's premises: always transport In closed containers that are upright and secure. Ensure that persons transporting the product know what to do In the event ofan accident or spillage. Transport In accordance with ADRIRID, IMDG/IMO and ICAO/IATA and national regulation . International transport regulations 14.1 UN number 1263 14.2 UN proper shipping Paint related material. Marine pollutant (Solvent naphtha (petroleum}, light aromatic) name 14.3 Transport hazard 3 class{es)

Marking The environmental hazardous 

### I marine pollutant mark is only applicable for packages containing more than 511tres for liquids and 5 kg for solids. 14.4 Packing group Ill 14.5 Environmental hazards Yes

. 

# I Date of Issue : 17

. 10

.2012. 

### 9/141 

# IConfonns to Regulation (EC) No. 1907/2006 (REACH}, Annex II -United Kingdom{UK) Jotun ThinnerNo. 

### 17 

## SECTION 14: Transport information 14.6 Special precautions for user Additional Information ADR/RID
IMDG

14.7 Transport In bulk according to Annex 

### II of MARPOL 73/78 and the IBC Code : Not available.

Tunnel restriction code: (0/E) Hazard identification number: 30 Special provisions: 

### 640E Emergency schedules (EmS) 

### F-E, S-E Not available.


## jsECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation fEC) No.1907/2006 CREACH) Annex XIV
- List 

### of**s~:~bstances** subjectto authorisation

Substances ofverv high concern

None ofthe components are listed. Annex XVII
- Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations

Europe Inventory Black List Chemicals Priority List Chemicals Integrated pollution prevention and control list (IPPC} -Air Integrated pollution prevention and control list (IPPC}
- Water lntematjonal regulations

Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule Ill Chemicals All components are listed or exempted

. Not listed Listed Not listed

Not listed

Not listed

Not listed

Not listed

15.2 Chemical Safety Assessment This product contains substances for which Chemical Safety Assessments are still required.

[Date of Issue 17

. 10

.2012. 

### 101141

# IJotun ThinnerNo. 17 

### j

## SECTION 

## 16; Other information

,.. Indicates information that has changed from previously issued vers ion . Abbreviations and acronyms : ATE= Acute Toxicity Estimate CLP = Classification , Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008) DNEL 

### = Derived No Effect Level EUH statement 

### =CLP-specific Hazard statement PNEC 

# = Predicted No Effect Concentration RRN 

# =REACH Registration Number Classification according to Regulation (ECl No. 1272/2008 £CLP/GHSJ Flam. Liq. 3, H226 Acute Tox. 4, H332 Skin lrrit. 2, H315 Eye Dam

. 1 , H318 STOT SE 3 , H335 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Procedure used to derive the classification accordina to Reaulation (ECl No 1272/2008 rCLP/GHSl 

# . Classification Justification Flam. Uq

. 3 , H226 Acute Tox. 4, H332 Skin lrrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Asp

. Tox

. 1, H304 Aquatic Chronic 2, H411 Full text ofabbreviated H statements

Full text ofclassifications [CLP/GHS] H225 H226 H302 H304 H312 H315 H318 H332 H335 H335 and H336 On basis oftest data Calculation method Calculation method Calculation method Calculation method Expertjudgment Calculation method Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful ifswallowed

. May be fatal 

### ifswallowed and enters airways. Harmful In contact with skin

. Causes skin i rritation. Causes serious eye damage

. Harmful if inhaled

. May cause respiratory irritation . . May cause respiratory Irritation

. May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects. Acute Tox

. 4, H302 ACUTE TOXICITY: ORAL- Category 4 Acute Tax

. 4 , H312 ACUTE TOXICITY: SKIN- Category 4 Acute Tax

. 4 , H332 ACUTE TOXICITY: INHALATION- Category 4 Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC)- Category 2 Asp. To x. 1 , H304 ASPIRATION HAZARD- Category 1 Eye Dam.1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION- Category 

### 1

Full text ofabbreviated R phrases



# I Date of Issue Flam. Liq. 2, H225 FLAMMABLE LIQUIDS
- Category 2 Flam. Llq. 3, H226 FLAMMABLE LIQUIDS
- Category 3 Skin lrrit. 

### 2, H315 SKIN CORROSION/IRRITATION- Category 

### 2 STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Respiratory tract irritation]
- Category 3 STOT SE 3, H335 and SPECIFIC TARGET ORGAN TOXICITY (SINGLE H336 EXPOSURE) [Respiratory tract irritation and Narcotic effects)
- Category 3 R11- H ighly flammable. R1D- Flammable. R20
- Harmful by inhalation. R22
- Harmful Ifswallowed

. R20/21- Harmful by inhalation and in contact with skin

. R65- Harmful: may cause lung damage ifswallowed. R41- Risk ofserious damage to eyes. R37
- Irritating to respiratory system

. R38- Irritating to skin. R37/38-lrritating to respiratory system and skin

. R66- Repeated exposure may cause skin dryness or cracking.
: 17.10.2012

. 

### 111141Conforms to Regulation (EC} No. 1907/2006 (REACH}, Annex If -United Kingdom (UK) Jotun ThinnerNo

. 17 

## SECTION 16: Other information

Full text of classifications (DSD/DPD]
Date of printing Date of issue/ Date of revision Date of previous Issue Version Notice to reader R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. F
- Highly flammable 

### Xn- Harmful 

### Xi

- Irritant N
- Dangerous for the environment 

### 17.10

.2012. 17.10.2012. No previous validation. 

### 2 To the best of our knowledge, the Information contained herein is accurate. However, neitherthe above-named supplier, nor any of Its subsidiaries, assumes any liability whatsoever for the accuracy or completeness ofthe Information contained herein

. Final determination ofsuitability of any material Is the sole responsibility ofthe user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist

.



# I Date of Issue 

### 17

. 10.2012. 

### 12114, 

# I

# .., ..**~-r-** 

# - ·- ''"

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### '... 

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### ..**~** ·" 11..-/ ' ,, ...... ' 

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# r**~** 

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## Jotun Thinner No. 17 Exposure Scenario: Uses In Coatings
- Sector of Use Process Category Environmental Release categories : Industrial use : PROCOS PROC08a : ERC4 

### Industrial use**!~**

.**~~:!**

## ' .. :· i**L**



### ,. 

# . · .

Covers the use In coaUngs (paints, inks, adhesives, etc) Including exposures during use (includ ing product transfer and preparation, application by brush, spray by hand orsimilar methods) and equipment cleaning. 

### Operational conditions and risk management measures 

### Control ofworker exposure : Covers daily exposures up to 8 hours (unless stated differenUy)

. Frequency and duration of use General -Operational condiUons : Assumes use at not more than 

### 2o•c above ambient temperature (unless stated differently). Assumes a good basic standard ofoccupational hygiene Is Implemented. General
- Risk Management Measures : Wear chemical-resistant gloves (tested to EN374) In combination with 'basic' employee training. Wear suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for Information on appropriate personal protecllve equipment. 

### Type of activity or process Risk Management Measures Preparation of material for applfcallon : Provide extract ventilation to points where emissions occur. 

### Control of environmental exposure Organisational measures to preventlllmlt : Prevent environmental discharge consistent with regulatOIY requirements. release from site Conditions and measures related to external : External treatment and disposal ofwaste should comply with appficable local and/or natlonal regulations treatment ofwaste for disposal See Sectlon 13 for additional waste treatment Information. Conditions and measures related to external : External recovery and recycling orwaste should comply with applicable local andfornational regulations recovery orwaste 

### Additional information The exposure scenario rorthe mixture Is based on the following substances: REACH#: 01·2119455851-35 REACH#: 01-2119488216-32



### Page: 131141

## Jotun Thinner No. 17 Exposure Scenario: Uses in Coatings
- Professional use Sector of Use Process Category Environmental Release Categories : Professional use : PROC05 PROCOBa : ERC8a ERC8d Covers the use in coatings (paints, inks , adhesives, etc) including exposures during usa (Including product transfer and preparation, applicaUon by brush, spray by hand or similar methods) and equipment cleaning. 

### Operational conditions and risk management measures 

### Control ofworker exposure Frequency and duration of use General- Operational conditions General
- Risk Management Measures 

### Type of activity or process Preparation of material for application
- Indoor

.
Preparation ofmaterial for application
- Outdoor. : Covers daily exposures up to 8 hours (unless stated differently). : Assumes use at not mora than 20"C above ambient temperatura (unless stated differently). Assumes a

good basic standard ofoccupational hygiene Is implemented. : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear

suitable coveralls to prevent exposure tothe skin. Use suitable eye protection

. See Section 8 for information on appropriate personal Pfotectlve equipment. 

### Risk Management Measures : Provide a good standard ofcontrolled ventllallon (10 to 15 air changes per hour). Avoid carrying out

activities involving exposure for more than 1 hour

. or Provide a good standard ofcontrolled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to EN140 with Type AJP2 filter or better. : Ensure operation is undertaken outdoors. Avoid canying out activities invoMng exposure for more than

1 hour. or Provide a good standard ofcontrolled ventilation (10 to 15air changes per hour)

. Wear a respirator conforming to EN140 wilh Type AJP2 filter or bolter. 

### Control of environmental exposure Organisational measures to prevantnlmit : Prevent environmental discharge consistent with regulatory requir ements. release from site Conditions and measures related to external : External treatment and disposal ofwaste should comply with applicable local and/or national regulations treatment ofwaste for disposal See Section 13 for additional waste treabnent Information. Conditions and measures related to external ; External recovery and recycling ofwaste should comply with applicable local and/or national regulations recovery ofwaste 

### Additional information The exposure scenario for the mixture is based on the following substances: REACH#: 01-2119455851-35 REACH#: 01-2119488216-32

Page: 

### 141141Jotun Thinner No. 23 MM00000555 Coatings: Solvent-borne.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Jotun Thinner No. 23

:

: :

: : 

# 1 .

Hazards identification

No known significant effects or critical hazards. May cause eye irritation.

Harmful if swallowed. Harmful in contact with skin. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Flammable liquid. May be harmful if absorbed through skin or if swallowed. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not ingest. Do not get in eyes. Avoid contact with skin and clothing. Contains material that may cause target organ damage, based on animal data. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. :

: : : : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Classified A3 (Proven for animals.) by ACGIH [cyclohexanone]. Classified 3 (Not classifiable for humans.) by IARC [cyclohexanone]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). xylene 1330-20-7 50 - 100 butan-1-ol 71-36-3 10 - 25 ethylbenzene 100-41-4 10 - 25 cyclohexanone 108-94-1 2.5 - 10 1-methoxy-2-propanol 107-98-2 2.5 - 10 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Continued on next page

### Jotun Thinner No. 23 Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact

Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

May be combustible at high temperature. Decomposition products may include the following materials: carbon dioxide carbon monoxide Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Continued on next page

### Jotun Thinner No. 23 Page: 3/8

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

xylene ACGIH TLV (United States, 1/2009). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). butan-1-ol ACGIH TLV (United States, 2/2010). TWA: 20 ppm 8 hour(s). NIOSH REL (United States, 6/2009). Absorbed through skin. CEIL: 150 mg/m3 CEIL: 50 ppm OSHA PEL (United States, 6/2010). TWA: 300 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. CEIL: 150 mg/m3 CEIL: 50 ppm ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2008). TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 11/2006). 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

Continued on next page

### Jotun Thinner No. 23 Page: 4/8 

# Exposure controls/personal protection 8 . TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2008). Notes: K TWA: 100 ppm 8 hour(s). Form: STEL: 125 ppm 15 minute(s). Form: cyclohexanone ACGIH TLV (United States, 2/2010). Absorbed through skin. TWA: 20 ppm 8 hour(s). STEL: 50 ppm 15 minute(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 25 ppm 8 hour(s). TWA: 100 mg/m3 8 hour(s). NIOSH REL (United States, 6/2009). Absorbed through skin. TWA: 25 ppm 10 hour(s). TWA: 100 mg/m3 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 50 ppm 8 hour(s). TWA: 200 mg/m3 8 hour(s). 1-methoxy-2-propanol ACGIH TLV (United States, 2/2010). STEL: 553 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 369 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). NIOSH REL (United States, 6/2009). STEL: 540 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 360 mg/m3 10 hour(s). TWA: 100 ppm 10 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 540 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 360 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s).

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.



### Continued on next page

### Jotun Thinner No. 23 Page: 5/8

Liquid.

0.87 g/cm 3 Insoluble in the following materials: cold water and hot water. Characteristic. Clear. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
866 % (w/w) VOC :

: : : : : Flash point : Closed cup: 24°C (75,2°F) 

# 9 .

7.26 pounds/gallon

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects Contains material that may cause target organ damage, based on animal data. Contains material which may cause damage to the following organs: kidneys, lungs, liver, mucous membranes, spleen, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. Target organs Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Classified A3 (Proven for animals.) by ACGIH [cyclohexanone]. Classified 3 (Not classifiable for humans.) by IARC [cyclohexanone]. Contains material which may cause damage to the following organs: kidneys, lungs, liver, mucous membranes, spleen, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. Chronic effects on humans

Other toxic effects on humans :

:

:

: : : : 

# 11 .

Ecological information Ecotoxicity data xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l butan-1-ol Daphnia magna (EC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 1983 mg/l 100 mg/l 1730 mg/l Species Period Result Product/ingredient name 

# 12 .

Continued on next page

### Jotun Thinner No. 23 Page: 6/8 

# Ecological information 12 .

Products of degradation: carbon oxides (CO, CO2) and water. Products of degradation Pimephales promelas (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 1910 mg/l 1940 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l cyclohexanone Pimephales promelas (LC50) Pimephales promelas (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 527 mg/l 630 mg/l 732 mg/l

: Environmental precautions : No known significant effects or critical hazards.

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

Transport information

3 - DOT Classification

TDG Classification 3 Paint related material III

1263 Paint related material III

ADR/RID Class Paint related material 3 III Regulatory information UN number Proper shipping name Class PG* Label Additional information

1263 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E 1263

- 

# 14 .

Continued on next page

### Jotun Thinner No. 23 Page: 7/8 

# Transport information 14 .

- IMDG Class Paint related material 3 III

Paint related material 1263 IATA-DGR Class 3 III 1263 Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

-
PG* : Packing group

Flammable liquid Carcinogen Target organ effects HCS Classification 

# Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances : The following components are listed: XYLENE; ethylbenzene; N-BUTYL ALCOHOL; PROPYLENE GLYCOL METHYL ETHER; CYCLOHEXANONE Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances : The following components are listed: XYLENES; BENZENE, DIMETHYL-; ethylbenzene; n-BUTYL ALCOHOL; 1-BUTANOL; PROPYLENE GLYCOL MONOMETHYL ETHER; 1-METHOXY-2-PROPANOL; CYCLOHEXANONE New Jersey Spill: None of the components are listed. TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: butan-1-ol; ethylbenzene; xylene; 1- methoxy-2-propanol; cyclohexanone SARA 311/312 MSDS distribution - chemical inventory - hazard identification: butan-1-ol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; cyclohexanone: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

: SARA 313 :

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 

# 15 .

xylene 1330-20-7 50 - 100 butan-1-ol 71-36-3 10 - 25 ethylbenzene 100-41-4 10 - 25 xylene 1330-20-7 50 - 100 butan-1-ol 71-36-3 10 - 25 ethylbenzene 100-41-4 10 - 25 Form R - Reporting requirements Supplier notification :

:



### Continued on next page

### Jotun Thinner No. 23 Page: 8/8 

# Regulatory information 15 . New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Xylene (mixed); Ethylbenzene; 1-Butanol; Cyclohexanone New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENE, DIMETHYL-; ethylbenzene; 1-BUTANOL; 2-PROPANOL, 1-METHOXY-; CYCLOHEXANONE Rhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer.

ethylbenzene Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

S23- Do not breathe vapor / spray. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S38- In case of insufficient ventilation, wear suitable respiratory equipment. R10- Flammable. R20/21- Harmful by inhalation and in contact with skin. R41- Risk of serious damage to eyes. R37/38- Irritating to respiratory system and skin. Risk phrases EU regulations

Safety phrases :

: Hazard symbol or symbols :

Harmful



# Other information

Hazardous Material Information System (U.S.A.)

0 3 1 National Fire Protection Association (U.S.A.) Health Special Instability Flammability FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 17.10.2012. 1.01 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards C PERSONAL PROTECTION 2 3 0 Health

### AMERCOAT 10 THINNER Product name 

# Product and company identification
: 

# 1 .

AT10/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 22 December 2012 Version 5

Emergency overview 

# Hazards identification

Potential acute health effects May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Eyes Skin Inhalation Ingestion

See toxicological information (Section 11) DANGER! :

: : :
:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8

United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. toluene 108-88-3 30 - 60 4-methylpentan-2-one 108-10-1 30 - 60 ethanol 64-17-5 0.1 - 1 Name CAS number %



# First aid measures

Eye contact
Skin contact Inhalation Ingestion Notes to physician :

:
:

:
: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2,water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 

# 6 .

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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# Accidental release measures 6 . Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### 4-methylpentan-2-one TWA 20 ppm 100 ppm 50 ppm 50 ppm Not established STEL 75 ppm Not established 75 ppm 75 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### ethanol TWA Not

established 1000 ppm Not established 1000 ppm Not established STEL 1000 ppm Not established 1000 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Name Result ACGIH OSHA Ontario Mexico PPG

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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# Exposure controls/personal protection 8 .
Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations



### If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

= Threshold Limit Value TLV TWA = Time Weighted Average



### Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit = Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z STEL = = Short term Exposure limit values



### Liquid.

Not available. Not available. 

# Physical and chemical properties Physical state

Odor Color :

: : Flash point : Closed cup: 2.22°C (36°F) Explosion limits : Lower: 1.1% 

# 9 .

Yes. : Material supports combustion.

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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# Physical and chemical properties 9 . >37.78°C (>100°F)

100% (v/v), 100% (w/w) Not available. Not available. 0.84

Not available. 2.6 kPa (19.5 mm Hg) [room temperature] Boiling/condensation point Melting/freezing point

2.09 (butyl acetate = 1) pH
Specific gravity Vapor pressure Vapor density Volatility Evaporation rate : : : :

: : : :Partition coefficient: noctanol/water : Not available. % Solid. (w/w) : 0 Density ( lbs / gal ) : 7.01

Stable under recommended storage and handling conditions (see Section 7). Reactive or incompatible with the following materials:,oxidizing materials,strong acids, strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : :
:
:
: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, the nervous system, the reproductive system, liver, heart, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. toluene LD50 Oral Rat 636 mg/kg
-

LD50 Dermal Rabbit 8.39 g/kg
- LC50 Inhalation Rat 49 g/m3 4 hours 4-methylpentan-2-one LD50 Oral Rat 2.08 g/kg
-

LC50 Inhalation Vapor Rat 32772 mg/m3 4 hours ethanol LD50 Oral Rat 7 g/kg
-

LC50 Inhalation Rat 124700 mg/m3 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Product/ingredient name toluene A4 3
- - 4-methylpentan-2-one A3 2B
- -

ACGIH NTP OSHA IARC

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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# 11 . Toxicological information

Teratogenicity Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair female fertility, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: -



# Ecological information Environmental effects : No known significant effects or critical hazards. 

# 12 .
Aquatic ecotoxicity

toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ 

### Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### 4-methylpentan-2-one Acute LC50 505000 to 514000 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ 

### ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 4 days

_________________________________ ________________________________ __________ 

### Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### Product/ingredient name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# Transport information 14 . Regulation UN number Proper shipping name Classes PG* UN 1263 PAINT RELATED MATERIAL 3 II Additional information

- IMDG 1263 PAINT RELATED MATERIAL 3
-

II DOT Reportable quantity

1706.6 lbs / 774.8 kg [244.37 gal / 925.03 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT RELATED MATERIAL II

CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group 

# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.
All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :
Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:
Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 lbs. (454 kg);

CAS number Concentration
Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SARA 302/304/311/312 extremely hazardous substances:No products were found. SARA 302/304 emergency planning and notification:No products were found. SARA 302/304/311/312 hazardous chemicals:4-methylpentan-2-one; toluene

Supplier notification : toluene 108-88-3 30 - 60 4-methylpentan-2-one 108-10-1 30 - 60 SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification: toluene 108-88-3 Y Y Y N N 4-methylpentan-2-one 108-10-1 Y Y Y N N Chemical name CAS # Acute Chronic Fire Reactive Pressure
Product as-supplied : Y Y Y N N Chemical name

California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada
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### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012 

# 15 . Regulatory information WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). :
Mexico 3 2 0 Health Flammability Reactivity Classification : : : 

# Other information Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.) Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 7/30/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

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United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 

# Product and company identification
: 

# 1 .

AT765/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 22 December 2012 Version 7

Emergency overview 

# Hazards identification

Potential acute health effects May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Eyes Skin Inhalation Ingestion

See toxicological information (Section 11) DANGER! :

: : :
:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. Harmful in contact with skin. Irritating to skin.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

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United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. xylene 1330-20-7 60 - 100 ethylbenzene 100-41-4 10 - 30 toluene 108-88-3 0.1 - 1 Name CAS number %



# First aid measures

Eye contact
Skin contact Inhalation Ingestion Notes to physician :

:
:

:
: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2,water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 

# 6 .

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### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# Accidental release measures 6 . Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not established STEL 150 ppm Not established 150 ppm 150 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not established STEL Not established Not established 125 ppm 125 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Name Result ACGIH OSHA Ontario Mexico PPG

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### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# Exposure controls/personal protection 8 .
Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations



### If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

= Threshold Limit Value TLV TWA = Time Weighted Average



### Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit = Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z STEL = = Short term Exposure limit values



### Liquid.

Not available. Not available. 

# Physical and chemical properties Physical state

Odor Color :

: : Flash point : Closed cup: 27.22°C (81°F) Explosion limits : Lower: 1% 

# 9 .

Yes. : Material supports combustion.

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### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# Physical and chemical properties 9 . >37.78°C (>100°F)

100% (v/v), 100% (w/w) Not available. Not available. 0.87

Not available. 0.85 kPa (6.4 mm Hg) [room temperature] Boiling/condensation point Melting/freezing point

0.63 (butyl acetate = 1) pH
Specific gravity Vapor pressure Vapor density Volatility Evaporation rate : : : :

: : : :Partition coefficient: noctanol/water : Not available. % Solid. (w/w) : 0 Density ( lbs / gal ) : 7.26

Stable under recommended storage and handling conditions (see Section 7). Reactive or incompatible with the following materials:,oxidizing materials,strong acids, strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : :
:
:
: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, liver, gastrointestinal tract, cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. xylene LD50 Oral Rat 4.3 g/kg
-

LD50 Dermal Rabbit >1.7 g/kg
- LC50 Inhalation Vapor Rat 5000 ppm 4 hours ethylbenzene LD50 Oral Rat 3.5 g/kg
-

LD50 Dermal Rabbit >5000 mg/kg
- LC50 Inhalation Vapor Rat 4000 ppm 4 hours toluene LD50 Oral Rat 636 mg/kg
-

LD50 Dermal Rabbit 8.39 g/kg
- LC50 Inhalation Rat 49 g/m3 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 5/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# 11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair female fertility, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - 

### Product/ingredient name xylene A4 3
- - ethylbenzene A3 2B
- - toluene A4 3
- -

ACGIH NTP OSHA IARC



# Ecological information Environmental effects : No known significant effects or critical hazards. 

# 12 .
Aquatic ecotoxicity
xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ 

### ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ 

### Acute LC50 5100 to 5700 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ 

### Acute EC50 2930 to 4400 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ 

### Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### Product/ingredient name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or Waste disposal 

# Disposal considerations
: 

# 13 .

Page: 6/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# Disposal considerations 13 . explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 . Regulation UN number Proper shipping name Classes PG* UN 1307 XYLENES 3 III Additional information

- IMDG 1307 XYLENES 3
-

III DOT Reportable quantity

118.22 lbs / 53.674 kg [16. 389 gal / 62.04 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1307 3 XYLENES III

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); Reportable quantity RQ : PG* : Packing group 

# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.
All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :
Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:
Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45. 4 kg);

CAS number Concentration SARA 302/304/311/312 extremely hazardous substances:No products were found. SARA 302/304 emergency planning and notification:No products were found. SARA 302/304/311/312 hazardous chemicals:ethylbenzene; xylene SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification: xylene 1330-20-7 Y N Y N N ethylbenzene 100-41-4 Y Y Y N N toluene 108-88-3 Y Y Y N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N Chemical name
Page: 7/8 United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012 

# 15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification : xylene 1330-20-7 60 - 100 ethylbenzene 100-41-4 10 - 30

California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico 3 2 0 Health Flammability Reactivity Classification : : : 

# Other information Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.) Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 5/18/2011. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 8/8

United States - Canada - MexicoHardtop XP - Comp. A MM00003140 Coatings: Solvent-borne.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Hardtop XP - Comp. A

:

: :

: : 

# 1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. May cause eye irritation.

No known significant effects or critical hazards. Harmful in contact with skin. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Flammable liquid. May be harmful if absorbed through skin. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. :

: : :
: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure None known. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). xylene 1330-20-7 10 - 25 n-butyl acetate 123-86-4 2.5 - 10 ethylbenzene 100-41-4 2.5 - 10 Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 2.5 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Continued on next page

### Hardtop XP - Comp. A Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact

Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

Flammable. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds metal oxide/oxides Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

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### Hardtop XP - Comp. A Page: 3/8

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

xylene ACGIH TLV (United States, 1/2009). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). n-butyl acetate ACGIH TLV (United States, 1/2009). STEL: 200 ppm 15 minute(s). TWA: 150 ppm 8 hour(s). NIOSH REL (United States, 6/2009). STEL: 950 mg/m3 15 minute(s). STEL: 200 ppm 15 minute(s). TWA: 710 mg/m3 10 hour(s). TWA: 150 ppm 10 hour(s). OSHA PEL (United States, 11/2006). TWA: 710 mg/m3 8 hour(s). TWA: 150 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 950 mg/m3 15 minute(s). STEL: 200 ppm 15 minute(s). TWA: 710 mg/m3 8 hour(s). TWA: 150 ppm 8 hour(s). ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2008). 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

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### Hardtop XP - Comp. A Page: 4/8 

# Exposure controls/personal protection 8 . TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2008). Notes: K TWA: 100 ppm 8 hour(s). Form: STEL: 125 ppm 15 minute(s). Form: Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001). TWA: 125 mg/m3 10 hour(s). Form: All forms TWA: 25 ppm 10 hour(s). Form: All forms ACGIH TLV (United States, 1/2005). TWA: 123 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989). TWA: 125 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Liquid.

1.2 to 1.4 g/cm3 Insoluble in the following materials: cold water and hot water. Characteristic. Various colors. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
384 % (w/w) [ISO % 11890-2] VOC :

: : : : : Flash point : Closed cup: 32°C (89,6°F) 

# 9 .

10.01 to 11.68 pounds/gallon 3.2 pounds/gallon (US)



### Continued on next page

### Hardtop XP - Comp. A Page: 5/8

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects No known significant effects or critical hazards. Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. Contains bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate. May produce an allergic reaction. CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Chronic effects on humans

Other toxic effects on humans :

:

:

: : : 

# 11 .

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2 etc.), halogenated compounds. Some metallic oxides. 

# Ecological information

Products of degradation Ecotoxicity data xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l n-butyl acetate Pimephales promelas (EC50) Pimephales promelas (LC50) Lepomis macrochirus (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 19 mg/l 18 mg/l 100 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l Solvent naphtha (petroleum), light aromatic Fish (LC50) Daphnia (EC50) Algae (IC50) 96 hour(s) 48 hour(s) 72 hour(s) <10 mg/l <10 mg/l <10 mg/l Species Period Result Product/ingredient name

: Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

# 12 .

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### Hardtop XP - Comp. A Page: 6/8

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

- 

# Transport information

3 - DOT Classification

TDG Classification 3 Paint III

1263 Paint III

ADR/RID Class Paint 3 III

IMDG Class Paint 3 III

Paint 1263 IATA-DGR Class 3 Regulatory information UN number Proper shipping name Class PG* Label Additional information

III 1263

1263 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

- 1263

-

PG* : Packing group ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity). 

# 14 .

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### Hardtop XP - Comp. A Page: 7/8

Flammable liquid Carcinogen HCS Classification 

# Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances : The following components are listed: XYLENE; ethylbenzene; n-butyl acetate Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances : The following components are listed: XYLENES; BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetate New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Xylene (mixed); Ethylbenzene; Butyl acetate New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetate Rhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer. TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Water Act (CWA) 307: c.i. pigment brown 24 Clean Water Act (CWA) 311 : formaldehyde Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: ethylbenzene; n-butyl acetate; xylene SARA 311/312 MSDS distribution - chemical inventory - hazard identification: ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

: SARA 313 :

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

ethylbenzene Yes. No. No. No. silica, crystalline - quartz Yes. No. No. No. formaldehyde Yes. No. Yes. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

EU regulations 

# 15 .

xylene 1330-20-7 10 - 25 ethylbenzene 100-41-4 2.5 - 10 xylene 1330-20-7 10 - 25 ethylbenzene 100-41-4 2.5 - 10 Form R - Reporting requirements Supplier notification :

:



### Continued on next page

### Hardtop XP - Comp. A Page: 8/8 

# Regulatory information 15 .

S23- Do not breathe vapor / spray. S36/37- Wear suitable protective clothing and gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. R10- Flammable. R20/21- Harmful by inhalation and in contact with skin. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases

Safety phrases :

: Hazard symbol or symbols :

Harmful



# Other information

Hazardous Material Information System (U.S.A.)

0 3 1 National Fire Protection Association (U.S.A.) Health Special Instability Flammability FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 24.10.2012. 1.02 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards G PERSONAL PROTECTION 2 3 1 HealthHardtop XP - Comp. B MM00003240

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Manufacturer Code

In case of emergency 

# Product and company identification 

# Hardtop XP - Comp. B

:

: :

: 

# 1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. May cause eye irritation.

No known significant effects or critical hazards. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) CAUTION! COMBUSTIBLE LIQUID AND VAPOR. Combustible liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin and clothing. Use only with adequate ventilation. :

: : :
: CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure None known. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). n-butyl acetate 123-86-4 2.5 - 10 Solvent naphtha (petroleum), light aromatic 64742-95-6 2.5 - 10 hexamethylene-di-isocyanate 822-06-0 0 - 1 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact

Inhalation

Ingestion :

:

:

: 

# 4 .

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### Hardtop XP - Comp. B Page: 2/7 

# First aid measures 4 . Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Flammable. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling : 

# 7 .

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### Hardtop XP - Comp. B Page: 3/7 

# Handling and storage 7 . Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Storage :

n-butyl acetate ACGIH TLV (United States, 1/2009). STEL: 200 ppm 15 minute(s). TWA: 150 ppm 8 hour(s). NIOSH REL (United States, 6/2009). STEL: 950 mg/m3 15 minute(s). STEL: 200 ppm 15 minute(s). TWA: 710 mg/m3 10 hour(s). TWA: 150 ppm 10 hour(s). OSHA PEL (United States, 11/2006). TWA: 710 mg/m3 8 hour(s). TWA: 150 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 950 mg/m3 15 minute(s). STEL: 200 ppm 15 minute(s). TWA: 710 mg/m3 8 hour(s). TWA: 150 ppm 8 hour(s). Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001). TWA: 125 mg/m3 10 hour(s). Form: All forms TWA: 25 ppm 10 hour(s). Form: All forms ACGIH TLV (United States, 1/2005). TWA: 123 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989). TWA: 125 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms hexamethylene-di-isocyanate ACGIH TLV (United States, 2/2010). TWA: 0,01 ppm 8 hour(s). TWA: 0,03 mg/m3 8 hour(s). NIOSH REL (United States, 6/2009). TWA: 0,005 ppm 10 hour(s). TWA: 35 μg/m3 10 hour(s). CEIL: 0,02 ppm 10 minute(s). CEIL: 140 μg/m3 10 minute(s). 

# Exposure controls/personal protection Product name Exposure limits

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : 

# 8 .

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.



### Continued on next page

### Hardtop XP - Comp. B Page: 4/7 

# Exposure controls/personal protection 8 . Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Liquid.

1.13 g/cm 3 Insoluble in the following materials: cold water and hot water. Characteristic. Yellowish-brown. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
113 % (w/w) [ISO % 11890-2] VOC :

: : : : : Flash point : Closed cup: 47°C (116,6°F) 

# 9 .

9.43 pounds/gallon 0.94 pounds/gallon (US)

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects No known significant effects or critical hazards. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects No known significant effects or critical hazards. Based on the properties of the isocyanate components and considering toxicological data on similar preparations, this preparation may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Repeated or prolonged contact with irritants may cause dermatitis. If splashed in the eyes, the liquid may cause irritation and reversible damage. Contains Hexamethylene diisocyanate, oligomers, hexamethylene-di-isocyanate. May produce an allergic reaction. Other toxic effects on humans :

: : : : 

# 11 .

Ecological information Ecotoxicity data Species Period Result Product/ingredient name 

# 12 .

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### Hardtop XP - Comp. B Page: 5/7 

# Ecological information 12 .

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2 etc.). Products of degradation n-butyl acetate Pimephales promelas (EC50) Pimephales promelas (LC50) Lepomis macrochirus (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 19 mg/l 18 mg/l 100 mg/l Solvent naphtha (petroleum), light aromatic Fish (LC50) Daphnia (EC50) Algae (IC50) 96 hour(s) 48 hour(s) 72 hour(s) <10 mg/l <10 mg/l <10 mg/l

: Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

Transport information

- - DOT Classification TDG Classification
- - - Not regulated. - - ADR/RID Class Paint 3 III

IMDG Class Paint 3 III Regulatory information UN number Proper shipping name Class PG* Label Additional information

1263

1263 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E Emergency schedules (EmS): F-E, S-E Marine pollutant: No. Not regulated.

- 

# 14 .

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# Transport information 14 .

- Paint 1263 IATA-DGR Class 3 III
-
PG* : Packing group ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity).

Combustible liquid HCS Classification 

# Regulatory information U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances : The following components are listed: n-butyl acetate Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances : The following components are listed: n-butyl acetate New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Butyl acetate New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: nbutyl acetate Rhode Island Hazardous Substances: None of the components are listed. TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. TSCA 8(c) calls for record of SAR: hexamethylene-di-isocyanate TSCA 8(d) H and S data reporting: hexane, 1,6-diisocyanato-, homopolymer

Clean Air Act (CAA) 112 accidental release prevention: No products were found. State regulations SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: n-butyl acetate SARA 311/312 MSDS distribution - chemical inventory - hazard identification: nbutyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

: :

R10- Flammable.

R42/43- May cause sensitization by inhalation and skin contact. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases EU regulations

:

Hazard symbol or symbols :

Harmful 

# 15 .

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### Hardtop XP - Comp. B Page: 7/7 

# Regulatory information 15 . S23- Do not breathe vapor / spray. S24- Avoid contact with skin. S37- Wear suitable gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Safety phrases :



# Other information
Hazardous Material Information System (U.S.A.)

0 3 0 National Fire Protection Association (U.S.A.) Health Special Instability Flammability COMBUSTIBLE LIQUID AND VAPOR. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 24.10.2012. 6.01 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards G PERSONAL PROTECTION 1 2 0 Health

# Hardtop Flexi
- Comp. A j1

. Product and company identification**------------------------------------~** 

### Trade name Code Materia! uses Manufacturer

In case of emergency Hardtop Flexi
- Camp. A MM00001531 Coatings: Solvent-borne. Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.no 1-800-424-9300 

# j2. Hazards identification Physical slate Odor OSHA/HCS status

Skin inhalation Ingestion Potential chronic health effects

Medical conditions aggravated by**over~** exposure Liquid. Characteristic. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). CAUTION! FLAMMABLE LIQUID AND VAPOR MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD- CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Flammable liquid. Harmful in contact with skin. Keep away from heat, sparks and flame. Avoid exposure- obtain special instructions before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing. Contains material that can cause target organ damage. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. May cause eye irritation. Harmful in contact with skin. May cause skin irritation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. No known significant effects or critical hazards. CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Pre-existing skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product See toxicological information (section 11) 

# [f Composition/information on ingredients Name Xylene n-butyl acetate ethylbenzene CAS number 1330-20-7 123-86-4 100-41-4 1 % bv weight 10- 25 2.5 -10 2.5- 10 Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard).



# IContinued on nextpage

# I Hardtop Flexi
- Comp. A Page: 2/8 

## rsection4. First aid

# mea~u~~s Eye contact

Skin contact

inhalation

Ingestion

Protection of first-aiders Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water_ Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop ifthe exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personneL If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated cloth"1ng thoroughly with water before remov'mg or wear gloves. 

# 15 Fire-fighting measures Flammability of the product Products of combustion

Suitable No! suitable Special exposure hazards

Speda! protective equipment for**fire~fighters** Flammable. Decomposition products may include the following materials: carbon oxides nitrogen oxides phosphorus oxides metal oxide/oxides Use dry chemical, 

## co,, water spray (fog) or foam. Do not use water jet. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 

# ISection 6. Accidental

# ~~lease**measu~~s** L____

______ Personal precautions

Environmental precautions


# I Continued on next page No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

### /Hardtop Flexi -::_amp. A

# ---~~---~---**-----~-** Page: 

### 318

# [se~tion 6. Accidental release measures
_ Methods for cleaning up Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent materia! e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. 

## /section 7. Handling and storage 

# l

Handling

Storage Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 

## Exposure controls/personal protection L___

__ __:__ 

# Is I • Product name Xylene

n-butyl acetate



### /Continued on nextpage Exposure limits ACGIH TLV (United States, 1/2005). Notes: 1996 Adoption Substances for which there is a Biological Exposure Index or Indices Refers to Appendix A-- Carcinogens.

STEL: 651 mg/m' 15 minute(s). Form: All forms STEL: 150 ppm 15 minute(s). Form: All forms TWA: 434 mg/m' 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms OSHA PEL (United States, 8/1997).

TWA: 435 mg/m' 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989).

STEL: 655 mg/m' 15 minute(s). Form: All forms STEL: 150 ppm 15 minute(s). Form: All forms TWA: 435 mg/m' 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms ACGIH TLV (United States, 1/2005). Notes: 1998 Adoption.

STEL: 200 ppm 15 minute(s). Form: All forms TWA: 150 ppm 8 hour(s). Form: All forms NIOSH REL (United States, 12/2001).

STEL: 950 mg/m' 15 minute(s). Form: All forms STEL: 200 ppm 15 minute(s). Form: All forms TWA: 710 mg/m' 10 hour(s). Form: All forms TWA: 150 ppm 10 hour(s). Form: All forms OSHA PEL (United States, 8/1997).

TWA: 710 mg/m' 8 hour(s). Form: All forms

### Hardtop Flexi
- Comp. A Page: 4/8 

# /a

. Exposure controls/personal protection

ethylbenzene

Engineering measures



### Eyes

Skin
Respiratory

Hands
Hygiene measures TWA: 150 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989).

STEL: 950 mg/m' 15 minute(s). Form: All forms STEL: 200 ppm 15 minute(s). Form: All forms TWA: 710 mg/m' 8 hour(s). Form: All forms TWA: 150 ppm 

### 8 hour(s). Form: All forms ACGIH TLV (United States, 1/2005). Notes: 2002 Adoption. Substances for which there is a Biological Exposure Index or Indices

STEL: 125 ppm 15 minute(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms NIOSH REL (United States, 12/2001).

STEL: 545 mg/m' 15 minute(s). Form: All forms STEL: 125 ppm 15 minute(s). Form: All forms TWA: 435 

### mglm' 10 hour(s). Form: All forms TWA: 100 ppm 10 hour(s). Form: All forms OSHA PEL (United States, 811997).

TWA: 435 mg/m' 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989).

STEL: 545 

### mglm' 15 minute(s). Form: All forms STEL: 125 ppm 15 minute(s). Form: All forms TWA: 435 

### mg!m' 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 

# '/9-.---P-h-ys_i_c_a_l_a-nd

__ c_h_e_m_i_c_a_lproperties ------------------------. Physical 

### stale Flash point Color Odor Re!ative density 

## voc Solubility


# IContinued on next page Liquid. Closed cup: 25'C (77'F) Various colors. Characteristic. 1.19 g/cm' 3.01 pounds/gallon (US) 9.76 pounds/gallon 361 (g/1). Insoluble in the following materials: cold water and hot water.

# I Hardtop Flexi
- Comp. A Page: 518

# ~ion10.St~bil_it~y_a_n_d_r_e_a_ct_iv_i~ty_·**------------------------~~** StabHity and reactivity Hazardous decomposition products

Chronic effects on humans

Other toxic effects on humans

Carcinogenic effects Mutagenic effects Reproduction toxicity Chronic effects The product is stable. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by !ARC [ethylbenzene]. Contains material which causes damage to the following organs: blood, kidneys, liver, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. No specific information is available in our database regarding the other toxic effects of this material to humans.
Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. No known significant effects or critical hazards. No known significant effects or critical hazards. Contains material that can cause target organ damage. Target organs Contains material which causes damage to the following organs: blood, kidneys, liver, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.

## ~-Ec~l-ogical 

## information
------- Ecotoxidty data Product/ingredient name Xylene

n-butyl acetate ethylbenzene

Environmental precautions Products of degradation Soedes Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) Pimephales promelas (EC50) Pimephales promelas (LC50) Lepomis macrochirus (LC50) Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) Period 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) Result 3.3 mg/1 8.2 mg/1 8.6 mg/1 12 mg/1 13.3 mg/1 13.4 mg/1 19 mg/1 18 mg/1 100 mg/1 2.93 mg/1 2.97 mg/1 7.2 mg/1 4.2 mg/1 9.09 mg/1 9.6 mg/1 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Products of degradation: carbon oxides (CO, CO,) and water, nitrogen oxides (NO, NO, etc.), phosphates. Sorne metallic oxides. 

# [13

. Disposal considera!ions

____________ _ Waste disposal



# I Continued on next page The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

### \Hardtop Flexi • Comp. A Page: 

### 618 

# [13 _:

# Disposal~onside~ations .

# ·~~-__j Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

# l.~-~~~~()l'l_14. Transport information Regulatory UN number Proper shipping Class PG"Ilabel information name information DOT Classification 1263 Paint 3 Ill

TDG Classification 1263 Paint 

### 3 Ill

ADR/RID Class 1263 Paint 3 Ill Hazard identification number: 30

iMDG Class 1263 Paint 3 Ill Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

lA

TA-DGR Class 1263 Paint ,3 Ill

PG' : Packing group 

# /15

. Regulatory information

HCS Classification

U.S. Federal regulations



# I Continued on nextpage Flammable liquid Carcinogen Target organ effects TSCA 4(a) final test rules: n-butyl acetate TSCA B(a) PAIR: 2-methoxy-1-methylethyl acetate United States inventory (TSCA Bb): Not determined. TSCA 12(b) one-time export n-butyl acetate SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals ethylbenzene; Xylene; n-butyl acetate; titanium dioxide SARA 311/312 MSDS distribution- chemical inventory- hazard identification: ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; Xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; titanium dioxide: Immediate (acute) health hazard Clean Water Act (CWA) 307: ethylbenzene; trizinc bis(orthophosphate) Clean Water Act (CWA) 311: ethylbenzene; Xylene; n-butyl acetate Clean Air Act (CAA) 112 accidental release prevenliorr No products were found.

# I Hardtop Flexi
- Comp. A Page: 7/8 

# r . j15

. Regulatory**information~:-:-:-:-;-:-::---:-:~~--:-:--**

# --;-;---~~__j Clean Air Act (CAA) 112 regulated flammable substances No products were found.
SARA 313

Form R. Reporting
Supplier notification Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
Product name Xylene ethylbenzene trizinc bis(orthophosphate) Xylene ethylbenzene trizinc bis(orthophosphate) CAS number 1330-20-7 100-41-4 7779-90-0 1330-20-7 100-41-4 7779-90-0 Concentration 10- 

### 25 2.5. 10 

### 2.5- 10 10- 

### 25 2.5. 10 

### 2.5- 10 SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations

Ingredient name
ethylbenzene EU regulations

Hazard symbol or symbols

Risk phrases

Safety phrases


# IContinued on nextpage Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill: None of the components are listed. Massachusetts Substances: The following components are listed: Xylene; n-butyl acetate; ethylbenzene;titanium dioxide Michigan Critical Material: None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances: The following components are listed: Xylene; nbutyl acetate; ethylbenzene; trizinc bis(orthophosphate);titanium dioxide New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: None of the components are listed. New York Toxic Chemical Release Reporting: None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: Xylene; n-butyl acetate; ethylbenzene; trizinc bis(orthophosphate);titanium dioxide Rhode Island Hazardous Substances: None of the components are listed.
WARNING: This product contains a chemical known to the State of California to cause cancer.

Yes.

Harmful R10- Flammable. 

### Reproductive

No.

Dangerous for the

environment. No significant risk !eve!
No.

R20/21- Harmful by inhalation and in contact with skin. R38- Irritating to skin. Maximum 

### acceptable dosage !eve! No.

R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23· Do not breathe vapor I spray. S36137· Wear suitable protective clothing and gloves. 838- In case of insufficient ventilation, wear suitable respiratory equipment. 861- Avoid release to the environment. Refer to special instructions/safety data sheet.

# I Hardtop Flexi • Comp. A Page: 8/8

# ~ 6

. Other

# info~;tion Label requirements

Hazardous Materia! Information System (U.S.A.)



### National Fire Protection Association (U.S.A.)

Date of issue Version Notice to reader FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD- CONTAINS MATERIAL WHICH MAY CAUSE CANCER. BASED ON ANIMAL DATA 

# -

:

l**~P~e,~r's'~o n,~a~l** **~p-ro_t_e-ct_i_o_n_ ~** 

# j

Health

28.09.2007. 3 Flammability lnstabilily 

### Special

To the best of our knowledge, the information contained herein is accurate. However, neither the**above~named** supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the · information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.



### fi7' Indicates information that has changed from previously issued version.Hardtop Flexi Standard - Comp. B MM00001533 Coatings: Solvent-borne.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Hardtop Flexi Standard - Comp. B

:

: :

: : 

# 1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. May cause eye irritation.

No known significant effects or critical hazards. Harmful in contact with skin. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) CAUTION! COMBUSTIBLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Combustible liquid. May be harmful if absorbed through skin. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Wash thoroughly after handling. :

: : :
: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure None known. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). 2-methoxy-1-methylethyl acetate 108-65-6 10 - 25 xylene 1330-20-7 10 - 25 ethylbenzene 100-41-4 1 - 2.5 hexamethylene-di-isocyanate 822-06-0 0 - 1 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact

Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

Flammable. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 3/8

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

2-methoxy-1-methylethyl acetate AIHA WEEL (United States, 5/2010). TWA: 50 ppm 8 hour(s). xylene ACGIH TLV (United States, 1/2009). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2008). TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2008). Notes: K TWA: 100 ppm 8 hour(s). Form: STEL: 125 ppm 15 minute(s). Form: hexamethylene-di-isocyanate ACGIH TLV (United States, 2/2010). TWA: 0,01 ppm 8 hour(s). TWA: 0,03 mg/m3 8 hour(s). NIOSH REL (United States, 6/2009). 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 4/8 

# Exposure controls/personal protection 8 . TWA: 0,005 ppm 10 hour(s). TWA: 35 μg/m3 10 hour(s). CEIL: 0,02 ppm 10 minute(s). CEIL: 140 μg/m3 10 minute(s).

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Liquid.

1.08 g/cm 3 Insoluble in the following materials: cold water and hot water. Characteristic. Various colors. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
24,8 % (w/w) [ISO 11890-1] VOC :

: : : : : Flash point : Closed cup: 38°C (100,4°F) 

# 9 .

9.01 pounds/gallon 2.24 pounds/gallon (US)

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Based on the properties of the isocyanate components and considering toxicological data on similar preparations, this preparation may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Chronic effects on humans

Other toxic effects on humans :

: 

# 11 .

Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 5/8 

# Toxicological information 11 .

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects No known significant effects or critical hazards. fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Repeated or prolonged contact with irritants may cause dermatitis. If splashed in the eyes, the liquid may cause irritation and reversible damage. Contains Hexamethylene diisocyanate, oligomers, hexamethylene-di-isocyanate. May produce an allergic reaction.

:

: : :

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2

etc.). 

# Ecological information

Products of degradation Ecotoxicity data xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l Species Period Result Product/ingredient name

: Environmental precautions : No known significant effects or critical hazards. 

# 12 .

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION : 

# 13 .

Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 6/8 

# Disposal considerations 13 . for additional handling information and protection of employees.

- 

# Transport information

- - DOT Classification TDG Classification
- - - Not regulated. - - ADR/RID Class Resin solution 3 III

IMDG Class Resin solution 3 III

Resin solution 1866 IATA-DGR Class 3 Regulatory information UN number Proper shipping name Class PG* Label Additional information

III 1866

1866 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

- Not regulated.

-

PG* : Packing group ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity). 

# 14 .

Combustible liquid Carcinogen HCS Classification 

# Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): All components are listed or exempted. TSCA 8(c) calls for record of SAR: hexamethylene-di-isocyanate TSCA 8(d) H and S data reporting: hexane, 1,6-diisocyanato-, homopolymer

Clean Air Act (CAA) 112 accidental release prevention: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: ethylbenzene; 2-methoxy-1-methylethyl acetate; xylene SARA 311/312 MSDS distribution - chemical inventory - hazard identification: ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; 2-methoxy-1-methylethyl acetate: Fire hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

SARA 313 :

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 

# 15 .

xylene 1330-20-7 10 - 25 ethylbenzene 100-41-4 1 - 2.5 xylene 1330-20-7 10 - 25 ethylbenzene 100-41-4 1 - 2.5 Form R - Reporting requirements Supplier notification :

:



### Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 7/8 

# Regulatory information 15 . Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances : The following components are listed: XYLENE; ethylbenzene Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances : The following components are listed: XYLENES; BENZENE, DIMETHYL-; ethylbenzene New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Xylene (mixed); Ethylbenzene New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENE, DIMETHYL-; ethylbenzene Rhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer. State regulations :

ethylbenzene Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

S23- Do not breathe vapor / spray. S24- Avoid contact with skin. S37- Wear suitable gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). R10- Flammable. R20- Harmful by inhalation. R42/43- May cause sensitization by inhalation and skin contact. Risk phrases EU regulations

Safety phrases :

: Hazard symbol or symbols :

Harmful



# Other information

Hazardous Material Information System (U.S.A.) COMBUSTIBLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Label requirements :

: 

# 16 .

Health Flammability Physical hazards G PERSONAL PROTECTION 1 2 0 Health



### Continued on next page

### Hardtop Flexi Standard - Comp. B Page: 8/8 

# Other information 16 .

0 3 0 National Fire Protection Association (U.S.A.) Health Special Instability Flammability

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 24.10.2012. 6.02 : : :

Indicates information that has changed from previously issued version.

### Resist 78 AV - Comp. A MM00001151 Coatings: Solvent-borne.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Resist 78 AV - Comp. A

:

: :

: : 

# 1 .

Hazards identification

No known significant effects or critical hazards. May cause eye irritation.
No known significant effects or critical hazards. Harmful in contact with skin. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Flammable liquid. May be harmful if absorbed through skin. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing. Contains material that may cause target organ damage, based on animal data. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. :

: : : : CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol].

Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for animals.) by ACGIH [2-butoxyethanol]. Classified 3 (Not classifiable for humans.) by IARC [2-butoxyethanol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Continued on next page

## Resist 78 AV - Comp. A Page: 2/10

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). ethanol 64-17-5 10 - 25 1-methoxy-2-propanol 107-98-2 10 - 25 tetraethyl silicate 78-10-4 10 - 25 2-butoxyethanol 111-76-2 2.5 - 10 mica 12001-26-2 2.5 - 10 silica, amorphous, diatomaceous earth 61790-53-2 2.5 - 10 butanone 78-93-3 2.5 - 10 xylene 1330-20-7 1 - 2.5 ethylbenzene 100-41-4 0 - 1 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact
Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

May be combustible at high temperature. Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Use dry chemical, CO2

### , water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :



## Continued on next page

## Resist 78 AV - Comp. A Page: 3/10

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

ethanol ACGIH TLV (United States, 2/2010). STEL: 1000 ppm 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 1900 mg/m3 10 hour(s). TWA: 1000 ppm 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 1900 mg/m3 8 hour(s). TWA: 1000 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m3 8 hour(s). 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

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## Resist 78 AV - Comp. A Page: 4/10 

# Exposure controls/personal protection 8 . TWA: 1000 ppm 8 hour(s). 1-methoxy-2-propanol ACGIH TLV (United States, 2/2010). STEL: 553 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 369 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). NIOSH REL (United States, 6/2009). STEL: 540 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 360 mg/m3 10 hour(s). TWA: 100 ppm 10 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 540 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 360 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). tetraethyl silicate ACGIH TLV (United States, 2/2010). TWA: 85 mg/m3 8 hour(s). TWA: 10 ppm 8 hour(s). NIOSH REL (United States, 6/2009). TWA: 85 mg/m3 10 hour(s). TWA: 10 ppm 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 850 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 85 mg/m3 8 hour(s). TWA: 10 ppm 8 hour(s). 2-butoxyethanol OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 25 ppm 8 hour(s). TWA: 120 mg/m3 8 hour(s). NIOSH REL (United States, 6/2009). Absorbed through skin. TWA: 5 ppm 10 hour(s). TWA: 24 mg/m3 10 hour(s). ACGIH TLV (United States, 2/2010). TWA: 20 ppm 8 hour(s). OSHA PEL (United States, 6/2010). Absorbed through skin. TWA: 50 ppm 8 hour(s). TWA: 240 mg/m3 8 hour(s). mica OSHA PEL 1989 (United States, 3/1989). TWA: 3 mg/m3 8 hour(s). Form: Respirable dust ACGIH TLV (United States, 2/2010). TWA: 3 mg/m3 8 hour(s). Form: Respirable fraction NIOSH REL (United States, 6/2009). TWA: 3 mg/m3 10 hour(s). Form: Respirable fraction OSHA PEL Z3 (United States, 9/2005). TWA: 20 mppcf 8 hour(s). silica, amorphous, diatomaceous earth OSHA PEL 1989 (United States, 3/1989). TWA: 6 mg/m3 8 hour(s). OSHA PEL Z3 (United States, 9/2005). TWA: 80 mg/m3 8 hour(s). TWA: 20 mppcf 8 hour(s). butanone OSHA PEL 1989 (United States, 3/1989). TWA: 200 ppm 8 hour(s). TWA: 590 mg/m3 8 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). ACGIH TLV (United States, 2/2010). TWA: 200 ppm 8 hour(s). 

## Continued on next page

## Resist 78 AV - Comp. A Page: 5/10 

# Exposure controls/personal protection 8 . TWA: 590 mg/m3 8 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 200 ppm 10 hour(s). TWA: 590 mg/m3 10 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). OSHA PEL (United States, 6/2010). TWA: 200 ppm 8 hour(s). TWA: 590 mg/m3 8 hour(s). xylene ACGIH TLV (United States, 1/2009). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2008). TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2008). Notes: K TWA: 100 ppm 8 hour(s). Form: STEL: 125 ppm 15 minute(s). Form:

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.



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## Resist 78 AV - Comp. A Page: 6/10 

# Exposure controls/personal protection 8 . Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Liquid.

1.1 g/cm 3 

### Insoluble in the following materials: cold water and hot water. Characteristic. Various colors. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
103,6 % (w/w) [ISO 11890-1] VOC :

: : : : : Flash point : Closed cup: 15°C (59°F) 

# 9 .

9.18 pounds/gallon 9.51 pounds/gallon (US)

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects Contains material that may cause target organ damage, based on animal data. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, the reproductive system, liver, lymphatic system, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, testes. Target organs Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for animals.) by ACGIH [2-butoxyethanol]. Classified 3 (Not classifiable for humans.) by IARC [2-butoxyethanol]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, the reproductive system, liver, lymphatic system, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, testes. Chronic effects on humans

Other toxic effects on humans :

:

:
: : : : 

# 11 .

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## Resist 78 AV - Comp. A Page: 7/10

Products of degradation: carbon oxides (CO, CO2

### ) and water. Some metallic oxides. 

# Ecological information

Products of degradation Ecotoxicity data ethanol Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (LC50) Pimephales promelas (LC50) Oncorhynchus mykiss (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2 mg/l 9.3 mg/l >100 mg/l >100 mg/l >100 mg/l 13000 mg/l 2-butoxyethanol Lepomis macrochirus (LC50) 96 hour(s) 1490 mg/l butanone Daphnia magna (EC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 5091 mg/l 3220 mg/l xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l Species Period Result Product/ingredient name

: Environmental precautions : No known significant effects or critical hazards. 

# 12 .

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

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## Resist 78 AV - Comp. A Page: 8/10

- 

# Transport information

3 - DOT Classification

TDG Classification 3 Paint II

1263 Paint II

ADR/RID Class Paint 3 II

IMDG Class Paint 3 II

Paint 1263 IATA-DGR Class 3 Regulatory information UN number Proper shipping name Class PG* Label Additional information

II 1263

1263 Tunnel restriction code: (D/E) Hazard identification number: 33 Special provisions: 640D Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

- 1263

-

PG* : Packing group 

# 14 .

Flammable liquid Carcinogen Target organ effects HCS Classification 

# Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: tetraethyl silicate TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: xylene; 1-methoxy-2-propanol; butanone; mica; 2-butoxyethanol; tetraethyl silicate; ethanol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; butanone: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; mica: Immediate (acute) health hazard; 2-butoxyethanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; tetraethyl silicate: Fire hazard, Immediate (acute) health hazard; ethanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

SARA 313 :

Product name CAS number Concentration 

# 15 .

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## Resist 78 AV - Comp. A Page: 9/10 

# Regulatory information 15 .

Connecticut Carcinogen Reporting : None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting : None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances: The following components are listed: ETHYL ALCOHOL; tetraethyl silicate; 2-BUTOXYETHANOL; PROPYLENE GLYCOL METHYL ETHER; MICA DUST; METHYL ETHYL KETONE (MEK); XYLENE Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances : None of the components are listed. New Jersey Hazardous Substances: The following components are listed: ETHYL ALCOHOL; ALCOHOL; tetraethyl silicate; 2-BUTOXY ETHANOL; BUTYL CELLOSOLVE; PROPYLENE GLYCOL MONOMETHYL ETHER; 1-METHOXY-2- PROPANOL; silica, amorphous, diatomaceous earth; MICA; METHYL ETHYL KETONE; 2-BUTANONE; XYLENES; BENZENE, DIMETHYL-; ethylbenzene New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: 2- Butanone; Xylene (mixed); Ethylbenzene New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: SILICIC ACID, ETHYL ESTER; DENATURED ALCOHOL; tetraethyl silicate; ETHANOL, 2-BUTOXY-; 2-PROPANOL, 1-METHOXY-; 2-BUTANONE; BENZENE, DIMETHYL-; ethylbenzene Rhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer. State regulations :

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

ethanol Yes. No. No. No. ethylbenzene Yes. No. No. No. carbon black Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

EU regulations

Hazard symbol or symbols :

Highly flammable Harmful 

### 2-butoxyethanol 111-76-2 2.5 - 10 butanone 78-93-3 2.5 - 10 xylene 1330-20-7 1 - 2.5 ethylbenzene 100-41-4 0 - 1 2-butoxyethanol 111-76-2 2.5 - 10 butanone 78-93-3 2.5 - 10 xylene 1330-20-7 1 - 2.5 ethylbenzene 100-41-4 0 - 1 Form R - Reporting requirements Supplier notification :

:



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## Resist 78 AV - Comp. A Page: 10/10 

# Regulatory information 15 .

S23- Do not breathe vapor / spray. S38- In case of insufficient ventilation, wear suitable respiratory equipment. R11- Highly flammable. R20- Harmful by inhalation. R36/37- Irritating to eyes and respiratory system. Risk phrases Safety phrases :

: 

# Other information

Hazardous Material Information System (U.S.A.)

0 4 2 National Fire Protection Association (U.S.A.) Health Special Instability Flammability FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 06.11.2012. 2.04 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards G PERSONAL PROTECTION 

### 1 4 0 Health

### Jotamastic 80 - Comp. A 5580

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Manufacturer Code

In case of emergency 

# Product and company identification 

# Jotamastic 80 - Comp. A

:

: :

: 

# 1 .

Hazards identification

No known significant effects or critical hazards. May cause eye irritation.
No known significant effects or critical hazards. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Flammable liquid. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Avoid contact with skin and clothing. Contains material that may cause target organ damage, based on animal data. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. :

: : : : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). xylene 1330-20-7 2.5 - 10 2-methylpropan-1-ol 78-83-1 2.5 - 10 benzyl alcohol 100-51-6 1 - 2.5 ethylbenzene 100-41-4 1 - 2.5 Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 2.5 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

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## Jotamastic 80 - Comp. A Page: 2/9

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact
Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. 

# 4 .

Flammable. Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds metal oxide/oxides Use dry chemical, CO2

### , water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Continued on next page

## Jotamastic 80 - Comp. A Page: 3/9

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

xylene ACGIH TLV (United States, 1/2011). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 6/2010). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). 2-methylpropan-1-ol ACGIH TLV (United States, 1/2011). TWA: 152 mg/m3 8 hour(s). TWA: 50 ppm 8 hour(s). NIOSH REL (United States, 6/2009). TWA: 150 mg/m3 10 hour(s). TWA: 50 ppm 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 300 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 150 mg/m3 8 hour(s). TWA: 50 ppm 8 hour(s). benzyl alcohol AIHA WEEL (United States, 10/2011). TWA: 10 ppm 8 hour(s). ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

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## Jotamastic 80 - Comp. A Page: 4/9 

# Exposure controls/personal protection 8 . STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 6/2010). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2011). Notes: K TWA: 20 ppm 8 hour(s). Form: Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001). TWA: 125 mg/m3 10 hour(s). Form: All forms TWA: 25 ppm 10 hour(s). Form: All forms ACGIH TLV (United States, 1/2005). TWA: 123 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms OSHA PEL 1989 (United States, 3/1989). TWA: 125 mg/m3 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Liquid.

1.6 g/cm 3 

### Insoluble in the following materials: cold water and hot water. Characteristic. Various 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
207 % (w/w) [ISO % 11890-2] VOC :

: : : : : Flash point : Closed cup: 35°C (95°F) 

# 9 .

13.35 pounds/gallon 1.73 pounds/gallon (US)



## Continued on next page

## Jotamastic 80 - Comp. A Page: 5/9

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects Contains material that may cause target organ damage, based on animal data. Contains material which may cause damage to the following organs: skin, eyes. Target organs Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, this preparation may be a skin sensitizer and an irritant. It contains low-molecular weight epoxy constituents which are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead to irritation and to sensitization, possibly with cross-sensitization to other epoxies. Skin contact with the preparation and exposure to spray, mist and vapors should be avoided. Contains reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average molecular weight ≤700), hydrocarbons, c9-unsatd., polymd., epoxy resin (MW 700-1200). May produce an allergic reaction. CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Contains material which may cause damage to the following organs: skin, eyes. Chronic effects on humans

Other toxic effects on humans :

:

:
: : : : 

# 11 .

Ecological information Ecotoxicity data xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l 2-methylpropan-1-ol Scenedesmus subspicatus (EC50) Daphnia pulex (EC50) Scenedesmus subspicatus (EC50) Oncorhynchus mykiss (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 230 mg/l 1100 mg/l 1250 mg/l 1330 mg/l Species Period Result Product/ingredient name 

# 12 .

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## Jotamastic 80 - Comp. A Page: 6/9 

# Ecological information 12 .

Products of degradation: carbon oxides (CO, CO2

### ) and water, halogenated compounds. Some metallic oxides. Products of degradation Pimephales promelas (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 1430 mg/l 1510 mg/l benzyl alcohol Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 10 mg/l 460 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l Solvent naphtha (petroleum), light aromatic Fish (LC50) Daphnia (EC50) Algae (IC50) 96 hour(s) 48 hour(s) 72 hour(s) <10 mg/l <10 mg/l <10 mg/l

: Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

Transport information

3 - DOT Classification Paint III Regulatory information UN number Proper shipping name Class PG* Label Additional information 1263 

# 14 .

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## Jotamastic 80 - Comp. A Page: 7/9 

# Transport information 14 .

- 

### TDG Classification 3 1263 Paint III

ADR/RID Class Paint 3 III

IMDG Class Paint 3 III

Paint 1263 IATA-DGR Class 3 III 1263

1263 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E Emergency schedules (EmS): F-E, S-E Marine pollutant: No.

- -

PG* : Packing group ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity)



### Flammable liquid Carcinogen Target organ effects HCS Classification 

# Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: ethylbenzene; xylene; reaction product: bisphenol-A-(epichlorhydrin); epoxy resin; 2-methylpropan-1-ol; benzyl alcohol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; reaction product: bisphenol-A-(epichlorhydrin); epoxy resin: Immediate (acute) health hazard; 2-methylpropan-1-ol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; benzyl alcohol: Immediate (acute) health hazard, Delayed (chronic) health hazard :

SARA 313 :

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 

# 15 .

xylene 1330-20-7 2.5 - 10 ethylbenzene 100-41-4 1 - 2.5 xylene 1330-20-7 2.5 - 10 ethylbenzene 100-41-4 1 - 2.5 Form R - Reporting requirements Supplier notification :

:



## Continued on next page

## Jotamastic 80 - Comp. A Page: 8/9 

# Regulatory information 15 . Connecticut Carcinogen Reporting : None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting : None of the components are listed. Louisiana Spill : None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances: The following components are listed: XYLENE; ethylbenzene; BENZYL ALCOHOL; ISOBUTYL ALCOHOL Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances : None of the components are listed. New Jersey Hazardous Substances: The following components are listed: XYLENES; BENZENE, DIMETHYL-; ethylbenzene; ISOBUTYL ALCOHOL; 1-PROPANOL, 2-METHYLNew Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Xylene (mixed); Ethylbenzene; Isobutanol New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENE, DIMETHYL-; ethylbenzene; BENZENEMETHANOL; 1-PROPANOL, 2-METHYLRhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer. State regulations :

ethylbenzene Yes. No. No. No. carbon black Yes. No. No. No. Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

S23- Do not breathe vapor / spray. S24- Avoid contact with skin. S37- Wear suitable gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. R10- Flammable. R36/38- Irritating to eyes and skin. R43- May cause sensitization by skin contact. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases EU regulations

Safety phrases :

: Hazard symbol or symbols :

Irritant



## Continued on next page

## Jotamastic 80 - Comp. A Page: 9/9 

# Other information

Hazardous Material Information System (U.S.A.)

0 3 1 National Fire Protection Association (U.S.A.) Health Special Instability Flammability FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 20.02.2013. 1.02 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards G PERSONAL PROTECTION 

### 2 3 1 Health

### DIMETCOTE 9 LIQUID Product name 

# Product and company identification
: 

# 1 .

DI9-A/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 23 January 2013 Version 6.01

Emergency overview 

# Hazards identification

Potential acute health effects May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Eyes Skin Inhalation Ingestion

See toxicological information (Section 11) DANGER! :

: : :
:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.

Harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. propan-2-ol 67-63-0 15 - 40 Silicic acid, ethyl ester 11099-06-2 10 - 30 Kaolin 1332-58-7 7 - 13 1-methoxy-2-propanol 107-98-2 5 - 10 tetraethyl silicate 78-10-4 5 - 10 toluene 108-88-3 1 - 5 Mica-group minerals 12001-26-2 1 - 5 ethanol 64-17-5 0.1 - 1 zinc chloride 7646-85-7 0.1 - 1 Quartz (SiO2) (<10 microns) 14808-60-7 0.1 - 1 Name CAS number %



# First aid measures

Eye contact
Skin contact Inhalation Ingestion Notes to physician :

:
:

:
: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2,water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product :

Page: 2/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 . Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations



### Consult local authorities for acceptable exposure limits. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value

TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit = Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z 

### propan-2-ol TWA 200 ppm 400 ppm 200 ppm 400 ppm Not established STEL 400 ppm Not established 400 ppm 500 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Kaolin TWA 2 mg/m3 R 5 mg/m3 R

15 mg/m3 TD 2 mg/m3 R 10 mg/m3 Not

established STEL Not established Not established Not established 20 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### 1-methoxy-2-propanol TWA 100 ppm Not

established 100 ppm Not established Not established STEL 150 ppm Not established 150 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### tetraethyl silicate TWA 10 ppm 100 ppm 10 ppm 10 ppm Not established STEL Not established Not established Not established 30 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Mica-group minerals TWA 3 mg/m3 R 20 mppcf Z 3 mg/m3 R 3 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### ethanol TWA Not

established 1000 ppm Not established 1000 ppm Not established STEL 1000 ppm Not established 1000 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### zinc chloride TWA 1 mg/m3 F 1 mg/m3 F 1 mg/m3 F 1 mg/m3 Not established STEL 2 mg/m3 F Not established 2 mg/m3 F 2 mg/m3 Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Quartz (SiO2) (<10 microns) TWA 0.025 mg/m3

R 10 mg/m3 R Z 30 mg/m3 TD Z 250 mppcf R Z 0.1 mg/m3 R 0.1 mg/m3 R Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL = = Short term Exposure limit values



### Page: 4/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# Exposure controls/personal protection 8 .

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Gloves : For prolonged or repeated handling, use the following type of gloves: Recommended: nitrile rubber Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

76% (v/v), 60.65% (w/w) Not available. Not available. 1.02

Not available. 4 kPa (30.3 mm Hg) [room temperature] Not available. Not available.
Boiling/condensation point Melting/freezing point

2.54 (butyl acetate = 1) 

# Physical and chemical properties Physical state

pH
Specific gravity Vapor pressure Vapor density Volatility Evaporation rate Odor Color :

: : : : : :

: : : : Flash point : Closed cup: 15.56°C (60°F) Explosion limits : Lower: 1.8% 

# 9 .

Density ( lbs / gal ) : 8.51 Yes. : Material supports combustion.

Page: 5/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# Physical and chemical properties 9 .Partition coefficient: noctanol/water : Not available. % Solid. (w/w) : 39.35

The product may not be stable under certain conditions of storage or use.
Reactive or incompatible with the following materials:,water,acids,oxidizing materials, strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid increased storage temperature. Pressure hazard 

# Stability and reactivity Stability Conditions to avoid
Materials to avoid Hazardous decomposition products Hazardous polymerization : :

:
:
: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the reproductive system, liver, heart, spleen, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, stomach, testes. propan-2-ol LD50 Oral Rat 4.396 g/kg
-

LD50 Dermal Rabbit 12800 mg/kg
- LC50 Inhalation Vapor Rat 72600 mg/m3 4 hours Kaolin LD50 Oral Rat >5000 mg/kg
- 1-methoxy-2-propanol LD50 Oral Rat 5.2 g/kg
-

LD50 Dermal Rabbit 13 g/kg
- tetraethyl silicate LD50 Oral Rat 6.27 g/kg
-

LD50 Dermal Rabbit 5.878 g/kg
- toluene LD50 Oral Rat 636 mg/kg
-

LD50 Dermal Rabbit 8.39 g/kg
- LC50 Inhalation Rat 49 g/m3 4 hours ethanol LD50 Oral Rat 7 g/kg
-

LC50 Inhalation Rat 124700 mg/m3 4 hours zinc chloride LD50 Oral Rat 0.35 g/kg
- Product/ingredient name Result Species Dose Exposure Acute toxicity

Product/ingredient name propan-2-ol A4 3
- - Kaolin A4
- - - toluene A4 3
- - Quartz (SiO2) (<10 microns) A2 1 Proven.
-

ACGIH NTP OSHA IARC

Page: 6/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# 11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair male fertility, based on animal data. Contains material which may impair female fertility, based on animal data. Teratogenicity : Contains material which may cause birth defects, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: -



# Ecological information Environmental effects : No known significant effects or critical hazards. 

# 12 .
Aquatic ecotoxicity
propan-2-ol Acute LC50 >1400000 ug/L Fish - Bluegill - Lepomis macrochirus 96 hours

______________________ _________________________________ ________________________________ __________ 

### toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ 

### Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 4 days

_________________________________ ________________________________ __________ 

### Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ 

### Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 

### Product/ingredient name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

Page: 7/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# Transport information 14 . Regulation UN number Proper shipping name Classes PG* UN 1263 PAINT 3 II Additional information

- IMDG 1263 PAINT 3
-

II DOT Reportable quantity

25002.6 lbs / 11351.2 kg [2930 gal / 11091.2 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT II

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group 

# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.
All components are listed or exempted. Substance Use Restricted All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :
Japan inventory (ENCS) : Korea inventory (KECI) : Philippines inventory (PICCS) :

:

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 kg);

CAS number Concentration SARA 302/304/311/312 extremely hazardous substances:No products were found. SARA 302/304 emergency planning and notification:No products were found. SARA 302/304/311/312 hazardous chemicals:1-methoxy-2-propanol; Kaolin; Mica-group minerals; propan-2-ol; toluene; tetraethyl silicate

Supplier notification : propan-2-ol 67-63-0 15 - 40 toluene 108-88-3 1 - 5 SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification: propan-2-ol 67-63-0 Y N Y N N Silicic acid, ethyl ester 11099-06-2 Y N N N N Kaolin 1332-58-7 Y N N N N 1-methoxy-2-propanol 107-98-2 Y N Y N N tetraethyl silicate 78-10-4 Y N Y Y N toluene 108-88-3 Y Y Y N N Mica-group minerals 12001-26-2 N N N N N zinc chloride 7646-85-7 Y Y N Y N Quartz (SiO2) (<10 microns) 14808-60-7 N Y N N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y Y N Chemical name

Page: 8/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013 

# 15 . Regulatory information Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico 3 3 1 Health Flammability Reactivity Classification : : : 

# Other information Hazardous Material Information System (U.S.A.)

3

1 3 National Fire Protection Association (U.S.A.) Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 12/22/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 3 *

3 1 ( * ) - Chronic effects

Page: 9/9

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 

# Product and company identification
: 

# 1 .

DI9-P PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 26 May 2013 Version 19

Emergency overview 

# Hazards identification

Potential acute health effects May be harmful if swallowed. Eyes Skin Inhalation Ingestion

See toxicological information (Section 11) WARNING! :

: : : :

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Ingestion : Skin : Eyes : Inhalation : Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

May be harmful if inhaled.
No known significant effects or critical hazards. No known significant effects or critical hazards.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200). No specific data. No specific data. No specific data. No specific data.



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100 zinc oxide 1314-13-2 1 - 5 Name CAS number %

Page: 1/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013 

# First aid measures

Eye contact
Skin contact Inhalation Ingestion Notes to physician :

:
:

:
: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use an extinguishing agent suitable for the surrounding fire. 

# Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. No specific fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : None known. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: metal oxide/oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions :

Large spill : 

# 6 .

Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill :

Page: 2/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization = Skin sensitization SS TD = Total dust Key to abbreviations



### Safety glasses with side shields. Personal protection Eyes Consult local authorities for acceptable exposure limits.

: Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value

TLV TWA = Time Weighted Average



### Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit = Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z 

### zinc oxide TWA 2 mg/m3 R 5 mg/m3 F

5 mg/m3 R 15 mg/m3 TD 2 mg/m3 R 10 mg/m3 5 mg/m3 Not established STEL 10 mg/m3 R Not established 10 mg/m3 R 10 mg/m3 Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 

### Name Result ACGIH OSHA Ontario Mexico IPEL

STEL = = Short term Exposure limit values



### Page: 3/7 United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013 

# Exposure controls/personal protection 8 . If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Skin Respiratory

: :

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Not available. Solid.

0% (v/v), 0% (w/w) Not available. Not available. 7.13

Not available. 0 kPa (0 mm Hg) [room temperature] Not available. Not available.
Boiling/condensation point Melting/freezing point

0 (butyl acetate = 1) 

# Physical and chemical properties Physical state

pH
Specific gravity Vapor pressure Vapor density Volatility Evaporation rate Odor Color :

: : : : : :

: : : : Flash point : Closed cup: Not applicable. [Product does not sustain combustion.] 

# 9 .

Partition coefficient: noctanol/water : Not available. % Solid. (w/w) : 100 Density ( lbs / gal ) : 59.5

The product may not be stable under certain conditions of storage or use. Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis Under normal conditions of storage and use, hazardous polymerization will not occur. Evolves hydrogen on contact with water. Avoid increased storage temperature. Pressure hazard 

# Stability and reactivity Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization : : :
:
: 

# 10 .

11 . Toxicological information
Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Target organs : Contains material which may cause damage to the following organs: lungs. Acute toxicity

Page: 4/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013 

# Ecological information Environmental effects : Water polluting material. May be harmful to the environment if released in large quantities. 

# 12 .

Aquatic ecotoxicity
Zinc powder - zinc dust (stabilized) Acute LC50 0.41 mg/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ 

### Product/ingredient name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 . Regulation UN number Proper shipping name Classes PG* UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide) 9 III Additional information

-

IMDG 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide). Marine pollutant (Zinc powder - zinc dust (stabilized), zinc oxide) 9
-

III

DOT Reportable quantity

1041.7 lbs / 472.92 kg Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 3077 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide) III

CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group

Page: 5/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013 

# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.
All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :
Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:
Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg);

CAS number Concentration
Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SARA 302/304:No products were found.

Supplier notification : Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100 zinc oxide 1314-13-2 1 - 5 SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification: zinc oxide 1314-13-2 N N N N N Chemical name CAS # Acute Chronic Fire Reactive Pressure Product as-supplied : N N N Y N Chemical name

WHMIS (Canada) None identified. : Canada Mexico 0 1 1 Health Flammability Reactivity Classification : : : 

# Other information Hazardous Material Information System (U.S.A.)

0

1 0 National Fire Protection Association (U.S.A.) Health Instability Flammability Health Flammability Physical hazards

Disclaimer Date of previous issue 12/22/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 1

1 1 ( * ) - Chronic effects

Page: 6/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013 

# Other information 16 . The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Page: 7/7

United States - Canada - Mexico

### Jotamastic 80 Std Comp B 5660 Coatings: Hardener for resins.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Jotamastic 80 Std Comp B

:

: :

: : 

# 1 .

Hazards identification

May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. May cause eye irritation.

May cause burns to mouth, throat and stomach. Corrosive to the skin. Causes burns. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) DANGER! COMBUSTIBLE LIQUID AND VAPOR. CAUSES SKIN BURNS. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Combustible liquid. Corrosive to the skin. Causes burns. Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not get in eyes or on skin or clothing. Contains material that may cause target organ damage, based on animal data. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use

. Wash thoroughly after handling. :

: : :

: CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). benzyl alcohol 100-51-6 25 - 50 3-aminomethyl-3,5,5-trimethylcyclohexylamine 2855-13-2 10 - 25 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Continued on next page

## Jotamastic 80 Std Comp B Page: 2/7

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact
Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

May be combustible at high temperature. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Use dry chemical, CO2

### , water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Methods for cleaning up : 

# 6 .

Continued on next page

## Jotamastic 80 Std Comp B Page: 3/7

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

benzyl alcohol AIHA WEEL (United States, 10/2011). TWA: 10 ppm 8 hour(s). 

# Exposure controls/personal protection Product name Exposure limits

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : 

# 8 .

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.



## Continued on next page

## Jotamastic 80 Std Comp B Page: 4/7

Liquid.

1.04 g/cm 3 

### Insoluble in the following materials: cold water and hot water. Characteristic. Yellowish-brown. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
0 % (w/w) [ISO % 11890-2] VOC :

: : : : : Flash point : Closed cup: 80°C (176°F) 

# 9 .

8.68 pounds/gallon 2.28 pounds/gallon (US)

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects No known significant effects or critical hazards. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects Contains material that may cause target organ damage, based on animal data. Contains material which may cause damage to the following organs: skin, eyes. Target organs Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. Contains aminepoxyadduct, 3-aminomethyl-3,5,5-trimethylcyclohexylamine. May produce an allergic reaction. Contains material which may cause damage to the following organs: skin, eyes. Chronic effects on humans Other toxic effects on humans : :

: : : : : 

# 11 .

Products of degradation: carbon oxides (CO, CO2

### ) and water, nitrogen oxides (NO, NO2 

### etc.). 

# Ecological information

Products of degradation Ecotoxicity data benzyl alcohol Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 10 mg/l 460 mg/l 3-aminomethyl-3,5,5- trimethylcyclohexylamine Daphnia magna (EC50) Daphnia (EC50) Algae (IC50) 48 hour(s) 24 hour(s) 72 hour(s) 17.4 mg/l 44 mg/l 37 mg/l Species Period Result Product/ingredient name

: Environmental precautions : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 

# 12 .

Continued on next page

## Jotamastic 80 Std Comp B Page: 5/7

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. : 

# 13 .

Transport information

8 - DOT Classification

TDG Classification 8 Polyamines, liquid, corrosive, n.o.s. (3- aminomethyl-3,5,5- trimethylcyclohexylamine) 

### III

2735 Polyamines, liquid, corrosive, n.o.s. (3- aminomethyl-3,5,5- trimethylcyclohexylamine) 

### III

ADR/RID Class Polyamines, liquid, corrosive, n.o.s. (3- aminomethyl-3,5,5- trimethylcyclohexylamine) 

### 8 III

IMDG Class Polyamines, liquid, corrosive, n.o.s. (3- aminomethyl-3,5,5- trimethylcyclohexylamine). 

### Marine pollutant (aminepoxyadduct) 8 III Regulatory information UN number Proper shipping name Class PG* Label Additional information

2735

2735 Tunnel restriction code: (E) Hazard identification number: 80

Emergency schedules (EmS): F-A, S-B Marine pollutant: Yes. 2735

- 

# 14 .

Continued on next page

## Jotamastic 80 Std Comp B Page: 6/7 

# Transport information 14 .

- 

### Polyamines, liquid, corrosive, n.o.s. (3- aminomethyl-3,5,5- trimethylcyclohexylamine) 

### 2735 IATA-DGR Class 8 III
-

PG* : Packing group The environmental hazardous / marine pollutant mark is only applicable for packages containing more than 5 litres for liquids and 5 kg for solids. Marking :

Combustible liquid Corrosive material Target organ effects HCS Classification 

# Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting : None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting : None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances: The following components are listed: BENZYL ALCOHOL Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances : None of the components are listed. New Jersey Hazardous Substances: The following components are listed: ISOPHORONEDIAMINE; CYCLOHEXANEMETHANAMINE, 5-AMINO-1,3,3-TRIMETHYLNew Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: None of the components are listed. New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENEMETHANOL Rhode Island Hazardous Substances: None of the components are listed. TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found. State regulations SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: 3-aminomethyl-3,5,5- trimethylcyclohexylamine; benzyl alcohol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: 3- aminomethyl-3,5,5-trimethylcyclohexylamine: Immediate (acute) health hazard; benzyl alcohol: Immediate (acute) health hazard, Delayed (chronic) health hazard :

: :

EU regulations 

# 15 .

Continued on next page

## Jotamastic 80 Std Comp B Page: 7/7 

# Regulatory information 15 .

S23- Do not breathe vapor / spray. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S38- In case of insufficient ventilation, wear suitable respiratory equipment. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to special instructions/safety data sheet. R20/22- Harmful by inhalation and if swallowed. R34- Causes burns. R43- May cause sensitization by skin contact. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases

Safety phrases :

: Hazard symbol or symbols :

Corrosive Dangerous for the environment



# Other information

Hazardous Material Information System (U.S.A.)

0 0 3 National Fire Protection Association (U.S.A.) Health Special Instability Flammability COMBUSTIBLE LIQUID AND VAPOR. CAUSES SKIN BURNS. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Label requirements :

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 20.02.2013. 4.04 : : :

: 

# 16 .

Indicates information that has changed from previously issued version. Health Flammability Physical hazards G PERSONAL PROTECTION 

### 3 2 0 Health

### Barrier AV - Comp. A MM00001131 Coatings: Solvent-borne.

1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 SDSJotun@jotun.com 

# Material Safety Data Sheet

Trade name Material uses Manufacturer Code

In case of emergency 

# Product and company identification 

# Barrier AV - Comp. A

:

: :

: : 

# 1 .

Hazards identification

No known significant effects or critical hazards. May cause eye irritation.

Harmful if swallowed. Harmful in contact with skin. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid.

See toxicological information (Section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Flammable liquid. May be harmful if absorbed through skin or if swallowed. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not ingest. Do not get in eyes. Avoid contact with skin and clothing. Contains material that may cause target organ damage, based on animal data. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. :

: : : : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [zinc oxide]. Classified 1 (Proven for humans.) by IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [propan-2-ol]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects :

: Odor : Characteristic. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 

# 2 .

Continued on next page

## Barrier AV - Comp. A Page: 2/11

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). barium sulfate 7727-43-7 10 - 25 heptan-2-one 110-43-0 2.5 - 10 xylene 1330-20-7 2.5 - 10 butanone 78-93-3 2.5 - 10 zinc oxide 1314-13-2 1 - 2.5 ethanol 64-17-5 1 - 2.5 ethylbenzene 100-41-4 0 - 1 

# Composition/information on ingredients Name CAS number % by weight 

# 3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. 

# First aid measures Eye contact
Skin contact
Inhalation

Ingestion :

:

:

:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 

# 4 .

May be combustible at high temperature. Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides metal oxide/oxides Use dry chemical, CO2

### , water spray (fog) or foam. 

# Fire-fighting measures Flammability of the product Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : :

: 

# 5 .

Special exposure hazards : Do not use water jet.

Suitable : Not suitable :



## Continued on next page

## Barrier AV - Comp. A Page: 3/11

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions :

Methods for cleaning up : 

# 6 .

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Avoid exposure - obtain special instructions before use. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage Handling

Storage :

: 

# 7 .

barium sulfate ACGIH TLV (United States, 2/2010). TWA: 10 mg/m3 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction TWA: 10 mg/m3 8 hour(s). Form: Total dust NIOSH REL (United States, 6/2009). TWA: 5 mg/m3 10 hour(s). Form: Respirable fraction TWA: 10 mg/m3 10 hour(s). Form: Total 

# Exposure controls/personal protection Product name Exposure limits 

# 8 .

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## Barrier AV - Comp. A Page: 4/11 

# Exposure controls/personal protection 8 . OSHA PEL (United States, 6/2010). TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction TWA: 15 mg/m3 8 hour(s). Form: Total dust heptan-2-one ACGIH TLV (United States, 2/2010). TWA: 50 ppm 8 hour(s). TWA: 233 mg/m3 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 465 mg/m3 8 hour(s). NIOSH REL (United States, 6/2009). TWA: 100 ppm 10 hour(s). TWA: 465 mg/m3 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 100 ppm 8 hour(s). TWA: 465 mg/m3 8 hour(s). xylene ACGIH TLV (United States, 1/2009). STEL: 651 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 434 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL (United States, 11/2006). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m3 15 minute(s). STEL: 150 ppm 15 minute(s). TWA: 435 mg/m3 8 hour(s). TWA: 100 ppm 8 hour(s). butanone OSHA PEL 1989 (United States, 3/1989). TWA: 200 ppm 8 hour(s). TWA: 590 mg/m3 8 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). ACGIH TLV (United States, 2/2010). TWA: 200 ppm 8 hour(s). TWA: 590 mg/m3 8 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 200 ppm 10 hour(s). TWA: 590 mg/m3 10 hour(s). STEL: 300 ppm 15 minute(s). STEL: 885 mg/m3 15 minute(s). OSHA PEL (United States, 6/2010). TWA: 200 ppm 8 hour(s). TWA: 590 mg/m3 8 hour(s). zinc oxide NIOSH REL (United States, 6/2009). CEIL: 15 mg/m3 Form: Dust TWA: 5 mg/m3 10 hour(s). Form: Dust and fumes STEL: 10 mg/m3 15 minute(s). Form: Fume OSHA PEL (United States, 6/2010). TWA: 5 mg/m3 8 hour(s). Form: Fume TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction TWA: 15 mg/m3 8 hour(s). Form: Total dust OSHA PEL 1989 (United States, 3/1989). STEL: 10 mg/m3 15 minute(s). Form: Fume TWA: 5 mg/m3 8 hour(s). Form: Fume TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction TWA: 10 mg/m3 8 hour(s). Form: Total dust ACGIH TLV (United States, 2/2010). 

## Continued on next page

## Barrier AV - Comp. A Page: 5/11 

# Exposure controls/personal protection 8 . STEL: 10 mg/m3 15 minute(s). Form: Respirable fraction TWA: 2 mg/m3 8 hour(s). Form: Respirable fraction ethanol ACGIH TLV (United States, 2/2010). STEL: 1000 ppm 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 1900 mg/m3 10 hour(s). TWA: 1000 ppm 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 1900 mg/m3 8 hour(s). TWA: 1000 ppm 8 hour(s). OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m3 8 hour(s). TWA: 1000 ppm 8 hour(s). ethylbenzene OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). NIOSH REL (United States, 6/2008). TWA: 100 ppm 10 hour(s). TWA: 435 mg/m3 10 hour(s). STEL: 125 ppm 15 minute(s). STEL: 545 mg/m3 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 100 ppm 8 hour(s). TWA: 435 mg/m3 8 hour(s). ACGIH TLV (United States, 1/2008). Notes: K TWA: 100 ppm 8 hour(s). Form: STEL: 125 ppm 15 minute(s). Form:

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes
Skin Respiratory :

:

:
Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Hands : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.



## Continued on next page

## Barrier AV - Comp. A Page: 6/11

Liquid.

2.2 g/cm 3 

### Insoluble in the following materials: cold water and hot water. Characteristic. Various colors. 

# Physical and chemical properties Physical state

Relative density Solubility Odor Color
14,7 % (w/w) [ISO 11890-1] VOC :

: : : : : Flash point : Closed cup: 30°C (86°F) 

# 9 .

18.36 pounds/gallon 2.7 pounds/gallon (US)

The product is stable.
Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

# Stability and reactivity Stability and reactivity Hazardous decomposition products Hazardous polymerization : :

: 

# 10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Mutagenic effects No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. Chronic effects Contains material that may cause target organ damage, based on animal data. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, the reproductive system, liver, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, nose/sinuses, throat. Target organs Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia. Contains epoxy resin (MW 700-1200), Phenol, methylstyrenated, hydrocarbons, c9- unsatd., polymd.. May produce an allergic reaction. CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [zinc oxide]. Classified 1 (Proven for humans.) by IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC [propan-2-ol]. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, the reproductive system, liver, peripheral nervous system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, nose/sinuses, throat. Chronic effects on humans

Other toxic effects on humans :

:

:
: : : : 

# 11 .

Continued on next page

## Barrier AV - Comp. A Page: 7/11

Products of degradation: carbon oxides (CO, CO2

### ) and water, sulfur oxides (SO2

### , SO3 

### etc.). Some metallic oxides. 

# Ecological information

Products of degradation Ecotoxicity data barium sulfate Daphnia magna (EC50) 48 hour(s) 32 mg/l heptan-2-one Pimephales promelas (LC50) 96 hour(s) 131 mg/l xylene Oncorhynchus mykiss (LC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 3.3 mg/l 8.2 mg/l 8.6 mg/l 12 mg/l 13.3 mg/l 13.4 mg/l butanone Daphnia magna (EC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 5091 mg/l 3220 mg/l zinc oxide Daphnia magna (EC50) Oncorhynchus mykiss (LC50) Lepomis macrochirus (LC50) Pimephales promelas (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) >1000 mg/l 1.1 mg/l >320 mg/l 2246 mg/l ethanol Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (LC50) Pimephales promelas (LC50) Oncorhynchus mykiss (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2 mg/l 9.3 mg/l >100 mg/l >100 mg/l >100 mg/l 13000 mg/l ethylbenzene Daphnia magna (EC50) Daphnia magna (EC50) Selenastrum capricornutum (EC50) Oncorhynchus mykiss (LC50) Pimephales promelas (LC50) Poecilia reticulata (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2.93 mg/l 2.97 mg/l 7.2 mg/l 4.2 mg/l 9.09 mg/l 9.6 mg/l Species Period Result Product/ingredient name

: Environmental precautions : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Water polluting material. May be harmful to the environment if released in large quantities. 

# 12 .

The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. : 

# 13 .

Continued on next page

## Barrier AV - Comp. A Page: 8/11 

# Disposal considerations 13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

- 

# Transport information

3 - DOT Classification

TDG Classification 3 Paint. Marine pollutant (barium sulfate) III

1263 Paint III

ADR/RID Class Paint 3 III

IMDG Class Paint. Marine pollutant (zinc) 3 III

Paint 1263 IATA-DGR Class 3 Regulatory information UN number Proper shipping name Class PG* Label Additional information

III 1263

1263 Tunnel restriction code: (D/E) Hazard identification number: 30 Special provisions: 640E Emergency schedules (EmS): F-E, S-E Marine pollutant: Yes.

- 1263

-

PG* : Packing group The environmental hazardous / marine pollutant mark is only applicable for packages containing more than 5 litres for liquids and 5 kg for solids. Marking : 

# 14 .

Continued on next page

## Barrier AV - Comp. A Page: 9/11

Flammable liquid Carcinogen Target organ effects HCS Classification 

# Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting : None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting : None of the components are listed. Louisiana Spill : None of the components are listed. Massachusetts Spill : None of the components are listed. Massachusetts Substances: The following components are listed: ETHYL ALCOHOL; ZINC OXIDE FUME; ZINC; BARIUM SULFATE; METHYL ETHYL KETONE (MEK); XYLENE; METHYL (N-AMYL) KETONE Michigan Critical Material : None of the components are listed. Minnesota Hazardous Substances : None of the components are listed. New Jersey Hazardous Substances: The following components are listed: ETHYL ALCOHOL; ALCOHOL; ZINC OXIDE; ZINC; barium sulfate; METHYL ETHYL KETONE; 2-BUTANONE; XYLENES; BENZENE, DIMETHYL-; ethylbenzene; METHYL n-AMYL KETONE; 2-HEPTANONE New Jersey Spill: None of the components are listed. TSCA 4(a) final test rules: 4-methylpentan-2-one TSCA 6 proposed risk management: lead TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined.

Clean Water Act (CWA) 307: zinc oxide; zinc; lead; cadmium Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: xylene; heptan-2-one; butanone; barium sulfate; zinc; zinc oxide; ethanol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; heptan-2-one: Fire hazard, Immediate (acute) health hazard; butanone: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; barium sulfate: Immediate (acute) health hazard; zinc: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; zinc oxide: Immediate (acute) health hazard, Delayed (chronic) health hazard; ethanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

: SARA 313 :

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 

# 15 .

zinc 7440-66-6 25 - 50 xylene 1330-20-7 2.5 - 10 butanone 78-93-3 2.5 - 10 zinc oxide 1314-13-2 1 - 2.5 ethylbenzene 100-41-4 0 - 1 propan-2-ol 67-63-0 0 - 1 lead 7439-92-1 0 - 1 zinc 7440-66-6 25 - 50 xylene 1330-20-7 2.5 - 10 butanone 78-93-3 2.5 - 10 zinc oxide 1314-13-2 1 - 2.5 ethylbenzene 100-41-4 0 - 1 Form R - Reporting requirements

Supplier notification :

:



## Continued on next page

## Barrier AV - Comp. A Page: 10/11 

# Regulatory information 15 . New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Zinc; 2-Butanone; Xylene (mixed); Ethylbenzene New York Toxic Chemical Release Reporting : None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: DENATURED ALCOHOL; ZINC OXIDE (ZNO); ZINC; BARIUM SULFATE; 2- BUTANONE; BENZENE, DIMETHYL-; ethylbenzene; 2-HEPTANONE Rhode Island Hazardous Substances: None of the components are listed. WARNING:This product contains a chemical known to the State of California to cause cancer. WARNING:This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.

ethanol Yes. No. No. No. ethylbenzene Yes. No. No. No. lead Yes. Yes. 15 μg/day (ingestion) Yes. silica, crystalline - quartz Yes. No. No. No. cadmium Yes. Yes. 0.05 μg/day (inhalation) 4.1 μg/day (ingestion) Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level

S23- Do not breathe vapor / spray. S24- Avoid contact with skin. S37- Wear suitable gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. S61- Avoid release to the environment. Refer to special instructions/safety data sheet. R10- Flammable. R43- May cause sensitization by skin contact. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Risk phrases EU regulations

Safety phrases :

: Hazard symbol or symbols :

Irritant Dangerous for the environment



# Other information

Hazardous Material Information System (U.S.A.)

0 3 1 National Fire Protection Association (U.S.A.) Health Special Instability Flammability FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Label requirements :

:

: 

# 16 .

Health Flammability Physical hazards G PERSONAL PROTECTION 

### 0 0 0 Health



## Continued on next page

## Barrier AV - Comp. A Page: 11/11 

# Other information 16 .

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue Version 06.11.2012. 2.01 : :

Indicates information that has changed from previously issued version.Confonns to Regulation (EC) No

. 1907/2006 (REACH), Annex II- United Kingdom (UK) 

# SAFETY DATA SHEET Jotun Anti-skid SECTION 1: Identification of the substance/mixture and ofthe company/undertaking 1.1 Product identifier

Product name EC number CAS number Product code Product description Product type Other means of Identification Jotun Anti-skid 215-691-6 1344-28-1 545 Coatings: Powder. Solid

. Not available

.

1.2 Relevant Identified uses ofthe substance or mixture and uses advised against

Notapplicable. 

### 1.3 Details ofthe supplier ofthe safety data sheet Jotun Paints (Europe) Ltd

. Stather Road Flixborough, Scunthorpe North Lincolnshire DN15 8RR England Tel: +44 17 24 40 00 00 Fax: +44 17 24 40 01 00 SDSJotun@jotun

.com
1.4 Emergency telephone number

Contact National Poison Centre via Hospital or Registered Medical Practitioner 

# I SECTION 2: Hazards identification 2.1 Classification ofthe substance or mixture

Product definition : Mono-constituent substance Classjficatjon according to Regulation lEC) No. 1272/2008 rCLPJGHSl Not classified. Classification according to D!rectjye 6V548/EEC 

## rpsrn

Not classified

. Sea Section 

### 16 for the full text ofthe R phrases or 

### H statements declared above. See Section 11 for more detaUed Information on health effects and symptoms

. 

### 2.2 Label elements

Hazard plctograms Signalword Hazard statements Precautlonarv statements

Prevention Response Storage Disposal Supplemental label elements 

## jDate of issue No signal word. No known significant effects or critical hazards. Do not breathe dust. Notapplicable

. Not applicable. Not applicable. Notapplicable.

20

.05.2011

.

## SECTION 2: Hazards Identification 2

.3 Other hazards

Substance meets the No. criteria for PBT according P: Not available. B: Not available. T: No

. to Regulation (EC) No. 1907/2006, Annex XIII Substance meets the Not available. c::rlteria for vPvB according to Regulation (EC} No

. 1907/2006, Annex XIII Other hazards which do not Not available

. result In classification 

# I SECTION 3: Composition/information on ingredients Substance/mixture : Mono-constituent substance Classjficatjon Product/Ingredient Identifiers 

### o/o 67/548/EEC Regulation (EC) No. Type Notes name 1272/2008 [CLP) alumina REACH#: 01- 50- Not classified. Not classified. (A) 2119529248-35 100 EC: 215-691-6 CAS: 1344-28-1 There are no additional ingredients present which , within the current knowledge ofthe supplier, are classified and contribute to the classification of the substance and hence require reporting In this section. 

### Uwl [A] Constituent [B) Impurity [C) Stabllfsing additive Occupational exposure limits, ifavailable, are listed in Section 8. 

# I SECTION 4: First aid measures 4.1 Description offirst aid measures 

### .

General In all cases ofdoubt, orwhen symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person . If unconscious, place in recovery position and seek medical advice

. Inhalation Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing Is
Skin contact Eye contact Ingestion Protection offirst-alders irregular or if respiratory arrest occurs , provide artlflclal respiration or oxygen by trained personnel. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents orthinners

. Check for and remove anycontact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate med ical attention. Ifswallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do notinduce vomiting. No action shall be taken Involving any personal rlsk or without suitable training

. 4

.2 Most importantsymptoms and effects, both acute and delayed

Potgntjal acute heaHh gfftcts

Eye contact Inhalation Skin contact Ingestion No known significant effects or critical hazards

. No known significant effects or critical hazards. No known signfflcant effects or critical hazards. No kno wn significant effects or critical hazards. Over-excosure sjgns/symotoms

Eye contact No specific data. Inhalation : No specific data. 

# I Date of Issue : 20.05.2011

. 

# 2/91Conforms to Regulation (EC) No

. 1907/2006 (REACH), Annex D• United Kingdom (UK) Jotun Anti-skid(MM·WCS) 

## SECTION 4: First aid measures

Skin contact Ingestion No specific data

. : No specific data.
4.3 Indication ofany Immediate medical attention and special treatment needed

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately 

### if farge quantities have been ingested or Inhaled. Specific treatments No specific treatment. 

# jSECTION 5: Firefighting measures 5

.1 Extinguishing media

Suitable extinguishing media Unsuitable extinguishing media Recommended : alcohol-resistant foam, C02blanket, water spray or mist.
Do not use waterjet. Do not use inert gas under high pressure (e

.g. C02}.


### 5.2 Special hazards arising from the substance or mixture

Hazards from the substance or mixture Hazardous thermal decomposition products


### 5.3 Advice for firefighters

Special protective actions forfire-fighters Special protective equipment for fire-fighters No specific fire or explosion hazard

. Decomposition products may Include the following materials: metal oxide/oxides
PrompOy isolate the scene by removing all persons from the vicinity ofthe incident if there 

### is a fire

. No action shalf be taken involving any personal risk orwithout suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus {SCBA) with a 

### tuff face-piece operated in positive pressure mode

. Clothing for fire-fJQhters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical Incidents. 

# I SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency No action shall be taken involving any personal risk orwithout suitable training

. personnel Evacuate surrounding areas . Keep unnecessary and unprotected personnel from entering

. Do nottouch or walk through spilt material. Put on appropriate personal protective equipment. For emergency responders If specialised clothing is required to deal with the spillage, take note ofany information in Section 8 on suitable and unsuitable materials. See also the information In "For non-emergency personnel"

. 6.2 Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if 

### the product has caused environmental pollution {sewers, waterways, soil or air)

. 

### 6.3 Methods and materials for containment and cleaning up

Small spill Move containers from spnl area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose ofvia a licensed waste disposal contractor. Large spill 

# I Date of Issue Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place In a designated, labelled waste container

. Dispose ofvia a licensed waste disposal contractor. Note: see section 1 for emergencycontact information and section 13 for waste disposal.

: 20.05

.2011. 

### I

# IConforms to Regulatlon_(EC) No. 1907/2006 {REACH), Annex 

### U

- United Kll!gdom (UK) Jotun Anti-skid(MM-WCS) 

## SECTION 6: Accidental release measures
6

.4 Reference to other sections See Section 1 for emergency contact information

. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment Information. 

# I SECTION 7: Handling and storage The Information In this section contains generic advice and guidance. The Jist of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenarlo(s)

. 

### 7.1 Precautions for safe handling Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational exposure limits. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact 

### with hot surfaces, sparks or other ignition sources. To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators should wear antistatic footwear and cloth ing and floors should be ofthe conducting type

. Keep awayfrom heat, sparks and flame. Avoid contact with skin and eyes. Avoid the Inhalation of dust, particulates, spray or mist arising from the application of this preparation

. Avoid inhalation of dust from sanding

. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed

. Put on appropriate personal protective equipment (see Section 

### 8). Always keep in containers made from the seme material asthe original one. Comply with the health and safety at work laws. 

### 7.2 Conditions for safe storage, Including any Incompatibilities Store in accordance with local regulations. Additional Information on storage conditions Observe label precautions

. Store in a dry, cool and well-ventilated area. Keep awayfrom heat and direct sunlight. Keep container tightly closed

. Keep awayfrom sources of ignition

. No smoking. Prevent unauthorised access . Containers that have been opened must be carefully resealed and kept upright to prevent leakage

. 

### 7.3 Specific end use(s)

Recommendations Industrial sector specific solutions Not available. Notavailable

. 

# I SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 

### 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 

### 8.1 Control parameters

Occuoatlonal exoosure limits Product/ingredient name Exposure limitvalues alumina Recommended monitoring procedures

oer!yed effect layels

No DEls available. EH40/2005 WELs (United Kingdom (UK), 8/2007). 

### TWA: 10 mg/m 5 

### 8 hour(s). Form: inhalable dust If this product contains ingredients 

### with exposure 

### limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness ofthe ventilation orother control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 

### 689 for methods for the assessment of exposure by Inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Predicted effect cgncentratlgns

No PECs available. 

# I Date of Issue 20.05.2011. 

# I

# IConforms to Regulation (EC) No

. 1907/2006 (REACH), Annex II- United Kingdom (UK) Jotun Anti-skid (MM·WCS) 

# I SECTION 8: Exposure controls/personal protection
8

.2 Exposure controls

Appropriate engineering controls

lndlyldua! protection measures No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants

. Ifthis product contains Ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls 

### to keep worker exposure below any recommended 

### or statutory limits

. Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period

. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothi ng before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location. Eye/face protection Safetyeyewear complying with an approved standard should be used when a risk

. assessment indicates !his is necessary to avoid exposure to liqu id splashes, mists, gases or dusts. Skin protection

Hand protection

Body protection

Other skin protection
Respiratory protection

Environmental exposure controls For prolonged or repeated handling, use the following type ofgloves: gloves: nitrile

. Barrier creams may help to protect the exposed areas ofthe skin but should not be applied once exposure has occurred. For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the supplier of chemical resistant gloves. The user mustcheck that the final choice oftype of glove selected for handling this product is lhe most appropriate and takes Into account the particular conditions of use, as included in the user's risk assessment. Personal protective equipmentfor the body should 

### be selected based on the task being performed and lhe risks involved and should be approved by a specialist before handling this product. Appropriate footw ear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. 

### Ifworkers are exposed to concentrations above the exposure lim it, they must use appropriate, certified respirators. Ifdust is generated and ventilation is inadequate, use respirator that will protect against dust/mist. {FFP2/ N95). Emissions from ventilation orwork process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment 

### will be necessary to reduce emissions to acceptable levels

. 

# I SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties

Appearance

Physical state Colour Odour Odour threshold pH Mehlng point/freezing point Initial bolllng point and bolllng range Flash point Evaporation rate Flammability {solid, gas)

Burning time Bumlngrate 

# I Date of issue Solid

. [Powder

.] White. Characteristic

. Not available

. Notavailable

. Not available. Notavailable. Not available

. Not available. Notavailable. Notavailable

. Not available.


### 20

.05.2011. 

# 5/91Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II -United Ki ngdom (UK) JotunAnti-skid (MM·WCS) 

## SECTION 9: Physical and chemical properties

Upper/lowerflammability or explosive limits Vapour pressure Vapour density Relative density Solublllty(les) Partition coefficient: n· octanol/water Auto-ignHion temperature Decomposition temperature VIscosity Explosive properties Oxidising properties
9

.2 Other Information

No additional Information

. Not available. Notavailable

. Not available. Insoluble 

### in the following materials: cold water and hot water

. Not available. Not available. Notavailable

. Notavailable

. Not available

. Not available.



## !sECTION 10: Stability and reactivity 1 0.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.51ncompatlble materials 10

.6 Hazardous decomposHion products No specific test data related to reactivity available for this product or its ingredients. The product is stable. Under normal conditions of storage and use, hazardous reactions wlfl not occur. No specific data

. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 

## jsECTION 11: Toxicological information

11.1 Information on toxicological effects Coating powders can cause localised skin irritation In folds of the skin or under tight clothing. Handling and/or processing ofthis material may generate a dustwhich can cause mechanical irritation ofthe eyes, skin, nose and throat. Repeated inhalation of dust can produce varying degrees of respiratory irritation or lung damage. Swallowing may cause nausea, diarrhoea, vomiting and gastro-intestinal Irritation

.

Acute toxlcltv Specific 

### taraet oraan tox!cltv lslng!e uposurel Not available. Specifictarget organ toxicltv (repeatgd exposure) Notavailable. AsPiration hazard Notavailable.


## !sECTION 12: Ecological information 12.1 Toxicity

Conclusion/Summary : Notavailable.
12.2 Persistence and degradability Conclusion/Summary Notavailable

. 12.3 Bloaccumulatlve potential 

# I Date 

### of Issue 

### 20.05

.2011

.Conformsto Regulation (EC) No

. 1907/2006 (REACH}, Annex H- United Kingdom (UK) Jotun Anti-skid(MM-WCS) 

## SECTION 12: Ecological information

Not available.


### 12.4 Mobility in soli Soli/water partition coefficient (Koe) Mobility Notavailable

. Not available

. 

### 12.5 Results of PBT and vPvB assessment

PBT No

. P: Notavailable. B: Not available

. T: No

. vPvB Notavailable

. 

### vP: Not available

. vB: Not available

. 

### 12.6 Other adverse effects No known significant effects or critical hazards

. 

# I SECTION 13: Disposal considerations The information in this section contains generic advice and gu idance

. The list of Identified Uses In Section 

### 1 should be consulted forany available use-specific Information provided in the Exposure Scenario(s)

. 

### 13.1 Waste treatment methods Within the present knowledge ofthe supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC

. European waste catalogue (EWC) waste paint and varnish other than those mentioned in 08 01 11

. Ifthis product is mixed with otherwastes, this code may no longer apply. If mixed with other wastes, the appropriate code should be assigned

. For further information, contact your local waste authority

. 

## !sECTION 14: Transport information

Transport within user's premises: always transport i n closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage

. This preparation is not classified as dangerous according to international transport regulations (ADRIRID, IMDG or ICAO/IA TA)

. 

### 14.1 UN number 

### 14.2 UN proper shipping name 

### 14

.3 Transport hazard class(es) 

### 14.4 Packing group Not regulated

.



### 14

.5 Environmental hazards No. 

### 14

.6 Special precautions Not available. for user Additional Information ADR/RID 

### 14

.7 Transport 

### In bulk Notavailable

. according to Annex 

### II of MARPOL73/78 and the IBC Code



# I Date ofissue 20

.05.2011. J

# I

# I SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation lECl No. 190V2006 CREACH) Annex XIV

- List ofsybstances subject to authorisation

Substances ofyery high concern

None of the components are listed. Annex

### XVII· Restrictions : Not applicable. on the manufacture, placing on the market and use ofcertain dangerous substances, mixtures and articles Other EU regylatlons

Europe Inventory Black list Chemicals Priority List Chemicals Integrated pollution prevention and control list (IPPC) -Air Integrated pollution prevention and control list (IPPC)
- Water lnternat!opal regulations

Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule Ill Chemicals
15.2 Chemical Safety Assessment All components are listed or exempted

. Not listed Not listed Not listed

Not listed

Not listed

Not listed

Not listed

This product contains substances forwhich Chemical Safety Assessments are still requ ired. 

# I SECTION 16: Other information J' Indicates information that has changed from previously Issued version

. Abbreviations and acronyms : ATE= Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation (Regulation (EC} No. 

### 1272/2008) DNEL 

# =Derived No Effect Level EUH statement= CLP-specific Hazard statement PNEC 

### = Predicted No Effect Concentration RBN 

# = REACH Registration Number Procedure used 

### to derive the classification according 

### to Regulatjop tECl No

. 1272/2008 lCLPIGHS] Classification Justification Not classified

. Full text ofabbreviated H statements Full text of classifications [CLP/GHS] Full text ofabbreviated R 

### phrases Full text of classifications (DSDIDPD] 

# I Date of Issue Not applicable. Not applicable. Not applicable

. Notapplicable

.



### 20

.05

.2011

.

# I SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation lECl No. 190V2006 CREACH) Annex XIV

- List ofsybstances subject to authorisation

Substances ofyery high concern

None of the components are listed. Annex

### XVII· Restrictions : Not applicable. on the manufacture, placing on the market and use ofcertain dangerous substances, mixtures and articles Other EU regylatlons

Europe Inventory Black list Chemicals Priority List Chemicals Integrated pollution prevention and control list (IPPC) -Air Integrated pollution prevention and control list (IPPC)
- Water lnternat!opal regulations

Chemical Weapons Convention List Schedule I Chemicals Chemical Weapons Convention List Schedule II Chemicals Chemical Weapons Convention List Schedule Ill Chemicals
15.2 Chemical Safety Assessment All components are listed or exempted

. Not listed Not listed Not listed

Not listed

Not listed

Not listed

Not listed

This product contains substances forwhich Chemical Safety Assessments are still requ ired. 

# I SECTION 16: Other information J' Indicates information that has changed from previously Issued version

. Abbreviations and acronyms : ATE= Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation (Regulation (EC} No. 

### 1272/2008) DNEL 

# =Derived No Effect Level EUH statement= CLP-specific Hazard statement PNEC 

### = Predicted No Effect Concentration RBN 

# = REACH Registration Number Procedure used 

### to derive the classification according 

### to Regulatjop tECl No

. 1272/2008 lCLPIGHS] Classification Justification Not classified

. Full text ofabbreviated H statements Full text of classifications [CLP/GHS] Full text ofabbreviated R 

### phrases Full text of classifications (DSDIDPD] 

# I Date of Issue Not applicable. Not applicable. Not applicable

. Notapplicable

.



### 20

.05

.2011

.Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II ·United Kingdom (UK) Jotun Anti-skid (MM-WCS) 

## SECTION 

## 16: Other information Date of printing Date of Issue/ Date of revision Date of previous issue Version Notice to reader 

### 20.05.2011. 20.05.2011. No previous validation. 

### 1.01 To the best ofour knowledge, the information contained herein Is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness ofthe information contained herein. Final determination ofsuitability ofany material Is the sole responsibility ofthe user. All materials may present unknown hazards and should be used with caution. Al1hough certain hazards are described herein, we cannot guarantee thatthese are the only hazards that exist.



# I Date of issue 

### 20.05.2011

. 

# IConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II ·United Kingdom (UK) Jotun Anti-skid (MM-WCS) 

## SECTION 

## 16: Other information Date of printing Date of Issue/ Date of revision Date of previous issue Version Notice to reader 

### 20.05.2011. 20.05.2011. No previous validation. 

### 1.01 To the best ofour knowledge, the information contained herein Is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness ofthe information contained herein. Final determination ofsuitability ofany material Is the sole responsibility ofthe user. All materials may present unknown hazards and should be used with caution. Al1hough certain hazards are described herein, we cannot guarantee thatthese are the only hazards that exist.



# I Date of issue 

### 20.05.2011

. 

# I