METHOD 321 TEST RESULTS FOR PORTLAND CEMENT MANUFACTURING

AUGUST 6, 2010
Method 321 Test Results for HCl, ppmvd@7%O2

Company National Cement Capitol Cement Capitol Cement* Lafarge Ash Grove

Plant Ragland, AL San Antonio, TX San Antonio, TX Harleyville, SC Louisville, NE

Kiln PH/PC Wet PH/PC PH/PC PH or PC

Runs (ppmwet)

1 8.12 1.03 0.34 12.63 15.90

2 5.73 1.72 0.34 13.27 14.70

3 5.19 1.72 0.34 2.37 12.40

4 14.73 0.34 29.78

5 4.27 0.34 6.76

6 0.34 19.09

7

8

9

AVG 7.61 1.49 0.34 13.98 14.33

STDEV 4.23 0.40 0.00 9.64 1.78

Rank 8 3 1 10 11

*NOTES:

Capitol Cement, wet kiln ‐ Run results were ppmwet. To calculate HCl, ppmvd@7%O2, moisture and O2 co

Capitol Cement, PH/PC kiln ‐ All runs were nondetects; detection limit  was 0.2 ppmwet. To calculate HCl,p

Lone Star ‐ Kiln 1 & 2 exhausts through common stack

Holcim, Ste Genevieve ‐ Runs 1 ‐ 3 reported as below detection limit.
o

p

Illinois Cement Alamo Cement Lone Star Lone Star* Holcim Holcim

La Salle, IL San Antonio, TX Pryor, OK Pryor, OK Ada, OK Devils Slide, UT

PH PH or PC Dry, kiln3 Dry, kiln 1&2 Wet PH/PC

18.48 0.54 12.96 18.50 1.66 2.81

14.49 0.66 11.55 16.10 1.34 4.11

14.33 0.78 10.12 16.50 1.25 2.73

1.36 0.25 20.30 7.59

1.54 0.25 23.60 8.22

1.46 0.27 11.90 5.44

8.61 0.46 15.07 17.03 1.42 5.15

7.98 0.23 5.50 1.29 0.22 2.36

9 2 13 15 4 7

ncentration were estimated.

pmvd@7%O2, moisture and O2 were estimated.
Holcim* Lafarge Lafarge Lehigh Lehigh Lehigh

Ste Genevieve,MO Alpena, MI Ravena,NY Tehachapi, CA Leeds, AL Redding, CA

PH/PC Dry, K23 Wet, K1 PH/PC PH PH

0.23 32.99 26.2 5.24 9.14 4.24

0.21 31.43 23.4 3.52 4.94 2.29

0.23 27.91 29.1 1.36 4.57 2.39

2.38 1.53 20.09 42.05

4.14 1.13 24.16 19.69

3.62 27.81 18.53

0.78

1.12

1.24

1.55 30.78 26.23 2.56 15.12 14.87

1.49 2.61 2.85 1.78 10.18 15.51

5 17 16 6 14 12
n

3

HCl Test Results, Major Sources, Using M321

Plant Location Kiln Type Test Date

Major/area

source (per

NEI) Mill Status Run

HCl

ppmwet moisture %

HCl

ppmdry

O2%

actual

HCl ppmd

at 7%O2 Notes

National Cement Ragland, AL PH/PC 5/21/2002 Major On 1 5.42 14.92 6.37 10 8.12 Sanders Engineering and Analytical Services, Hydrogen Chloride

5/21/2002 On 2 3.79 15.67 4.49 10 5.73 Emission Test Report (V 1), National Cement, Koppers

5/21/2002 On 3 3.44 15.48 4.07 10 5.19 Main Stack, Ragland Alabama, May 21 ‐ 24, 2002.

5/24/2002 Off 1 10.81 14.29 12.61 9 14.73

5/24/2002 Off 2 3.31 16.45 3.96 8 4.27

Capitol Cement San Antonio, TX Wet 5/9/2002 Major NA 1 0.60 26 0.81 10 1.03 Emission Monitoring Inc, NESHAP Applicability Testing

5/9/2002 NA 2 1.00 26 1.35 10 1.72 at Capitol Cement Co., 2002.

5/9/2002 NA 3 1.00 26 1.35 10 1.72

Alkali bypass 5/9/2002 NA 1 0.20 26 0.27 10 0.34 All nondetect; detection limit 0.2 ppmvwet

5/9/2002 NA 2 0.20 26 0.27 10 0.34 Moisture and O2 estimated

5/9/2002 NA 3 0.20 26 0.27 10 0.34

PH/PC 5/10/2002 On 1 0.20 26 0.27 10 0.34 All nondetect; detection limit 0.2 ppmvwet

5/10/2002 On 2 0.20 26 0.27 10 0.34 Moisture and O2 estimated

5/10/2002 On 3 0.20 26 0.27 10 0.345/10/2002 Off 1 0.20 26 0.27 10 0.34

5/10/2002 Off 2 0.20 26 0.27 10 0.34

5/10/2002 Off 3 0.20 26 0.27 10 0.34

Lafarge Harleyville, SC PH/PC 10/26/2004 Major On 1 7.73 15 9.09 10.89 12.63 O2 conc. estimated

10/26/2004 On 2 8.19 14.3 9.56 10.89 13.27 URS, Compliance Test Report, Lafarge Building Materials, Inc10/26/2004 On 3 1.44 15.6 1.71 10.89 2.37 Harleyville, SC, October 25 ‐ Nov. 1, 2004.

10/25/2004 Off 1 24.41 16.2 29.13 7.3 29.78 O2 conc. estimated

11/1/2004 Off 2 5.51 16.7 6.61 7.3 6.76

11/1/2004 Off 3 15.58 16.6 18.68 7.3 19.09

Ash Grove Louisville, NE PH or PC? 5/25/2005 Major 1 15.90 Prism Analytical Technologies, Inc., Ash Grove Cement Co,

5/26/2005 2 14.70 Louisville, Nebraska, Gaseous Hydrogen Chloride Testing,

5/26/2005 3 12.40 May 25 and 26, 2005.

Illinois Cement La Salle, IL PH 1/8/2002 Major* Off 1 12.90 6.69 13.82 10.5 18.48 The cover letter to the 2002 report states they are an area source.

1/8/2002 Off 2 11.20 7.37 12.09 9.3 14.49 Emission Monitoring Inc, NESHAP Applicability Testing for the Portland

1/8/2002 Off 3 12.40 7.45 13.40 7.9 14.33 Cement NESHAP, Illinois Cement Co., LaSalle, IL, February 17, 2002.

1/9/2002 On 4 1.00 10.57 1.12 9.5 1.36

1/9/2002 On 5 1.10 11.55 1.24 9.7 1.54

1/9/2002 On 6 1.20 11.45 1.36 8 1.46

Alamo Cement San Antonio, TX PH/PC 4/10/2001 Major Off 1 0.50 17.99 0.61 5.3 0.54 Clean Air Engineering, Report on Hydrogen Chloride Testing. Performed

4/10/2001 Off 2 0.60 18.92 0.74 5.3 0.66 for: Alamo Cement Co. Kiln Stack, San Antonio Cement Plant, May 24, 20014/10/2001 Off 3 0.70 19.96 0.87 5.4 0.78

4/11/2001 On 1 0.20 15.22 0.24 7.8 0.25

4/11/2001 On 2 0.20 15.43 0.24 7.8 0.25

4/11/2001 On 3 0.20 16.36 0.24 8.7 0.27

Lone Star Industries I Pryor, OK Dry, kiln 3 2/24/2010 Major NA 1 7.80 4.9 8.20 12.1 12.96 Received on 3/21/2010

2/24/2010 NA 2 6.50 4.6 6.81 12.7 11.552/24/2010 NA 3 5.90 4.7 6.19 12.4 10.12

Dry, kiln 1&2 9/28/1999 NA 1 18.50 Kiln 1 & 2 exhaust through common stack

9/28/1999 NA 2 16.109/28/1999 NA 3 16.50

Dry, kiln 3 9/30/1999 NA 1 20.30

9/30/1999 NA 2 23.609/30/1999 NA 3 11.90

Holcim Ada, OK Wet 3/12/2010 Major NA 1 1.66

3/12/2010 NA 2 1.343/12/2010 NA 3 1.25

Holcim Devils Slide, UT PH/PC 2/24/2010 Major On 1 2.81

2/24/2010 On 2 4.112/24/2010 On 3 2.732/25/2010 Off 1 7.592/25/2010 Off 2 8.22

2/25/2010 Off 3 5 4.4

Holcim Ste Genevieve,MO PH/PC 2/14/2010 Major BothOn 1 [<0.23] below detection limit

2/14/2010 BothOn 2 [<0.21] below detection limit2/14/2010 BothOn 3 [<0.23] below detection limit2/15/2010 BothOff 1 2.38

2/15/2010 BothOff 2 4.142/15/2010 BothOff 3 3.622/15/2010 1On/1Off 1 0.782/15/2010 1On/1Off 2 1.122/15/2010 1On/1Off 3 1.24

Lafarge Alpena, MI Dry, K23 3/25/2010 Major NA 1 32.99

3/25/2010 NA 2 31.433/25/2010 NA 3 27.91

Lafarge Ravena,NY Wet, Kiln 1 3/12/2010 NA 1

26.2

2 kilns exhaust to 1 stack; one kiln was operating during testing; tests in kiln breaching

3/12/2010 NA 2 23.4

3/12/2010 NA 3 29.1

Lehigh Tehachapi, CA PH/PC 3/25/2010 Major On 1 5.24

3/27/2010 On 2 3.523/27/2010 On 3 1.363/25/2010 Off 1 1.533/25/2010 Off 2 1.13

Lehigh Leeds, AL PH 3/17/2010 Major On 1 9.14

3/17/2010 On 2 4.943/17/2010 On 3 4.573/18/2010 Off 1 20.09

3/18/2010 Off 2 24.163/18/2010 Off 3 27.81

Lehigh Redding, CA PH 3/16/2010 Major On 1 4.24

3/16/2010 On 2 2.293/16/2010 On 3 2.393/17/2010 Off 1 42.053/17/2010 Off 2 19.693/17/2010 Off 3 18.53

*Cover letter to test report says they are not major.NA=not applicablend=nondetectable

February 22, 2010
1

3612342

______ ) 9 )

6967

State Contact Phone # Plants Locations M321 test Test date Alabama Scanlan, Katrina

334‐271‐786

334‐279‐3044 (fax) Cemex Demopolis Yes? ? 

National Cement Ragland Yes May‐0

Florida Linero, Al 850‐921‐952 FL Rock Newberry No ‐ Not req'd

Rinker Materials BrooksvilleRinker MiamiSuwannee American BranfordTitan America Medley

Illinois Asselmyer, David (Buzz) 217‐524‐763 Eagle Materials (Illinois Cement) LaSalle Yes ‐ Illinois, LaSalle 200

Pilapil, Ray 217‐782‐581 St. Mary's Cement Dixon no test data

Missouri Yronwode, Peter 573‐526‐678 Buzzi Unicem Festus (Selma) No ‐ Not req'd

New York DeSantis, Steve 518‐402‐840 St. Lawrence Catskill Not req'd (will ck)

Pennsylvania Kohli, ______ 717‐772‐397 Buzzi Stockertown No

Cemex Wampum NoKeystone NoGiant Cement Bath No (M26A test done)

Texas Hamilton, Randy 512‐239‐151 Capitol Aggregates (reg 13) San Antonio Yes (major source) 

______, Christine (Reg 11) 512‐339‐292 Cemex(Reg 13) New Braunfels M26A

McGrath, Carol (Reg 13) 210‐490‐309 Cemex (Reg 7) Odessa M26AMclean, Vickie (Reg 7) 432‐570‐135 Texas‐Lehigh (Reg 11) Buda M26

Seiler, Jeffrey 210‐490‐309 Alamo Cement San Antonio Yes (major source) 

Seiler, Jeffrey 210‐490‐309 TXI Hunter Yes (area source) 
0/09
States Contacted Plant Location M321 HCl Data

Major/Area

source

Alabama Cemex Demopolis ?

National Cement Ragland Yes Major

Florida Florida Rock Newberry No

Rinker Brooksville No

Rinker Miami No

Suwannee Branford No

Titan Medley No

Illinois Eagle Materials (Illinois Cement) LaSalle Yes Major (Area based on 2002 tests)

St Mary's Cement Dixon No

Missouri Buzzi Unicem Festus (Selma) No

New York St Lawrence Catskill No

Pennsylvania Buzzi Unicem Stockertown No

Cemex Wampum No

Giant Bath No

Texas Capitol Aggregates San Antonio Yes (all nd) Major

Cemex New Braunfels No (M26)

Cemex Odessa No (M26)

Texas‐Lehigh Buda No (M26)

Alamo Cement San Antonio Yes Major

TXI Hunter Yes Area

Other

South Carolina Lafarge Harleyville Yes Major

Nebraska Ash Grove Louisville Yes Major