Conforms to Regulation (EC) No. 1907/2006 (REACH),_ A,nnex~rr:· unitep Kin' dom":~~ ~) 

' ) .. l .. ·. . . ,--_ii::-; 

SAFETY DATA SHEET . . ... . ~; --~ . -, _ 

J, -Jl.....:.;.~ . ··>r,<~-;;v 

Jotun Thinner No. 17 

SECTION 1: Identification of the substance/mixture and of the 

company/undertaking 

1.1 Product Identifier 

Product name 

Product code 

Product description 

Product type 

Jotun Thinner No. 17 

553 

Coatings: Solvent-borne. 

Liquid. 

Other means of 

Identification 

Not available. 

1.2 Relevant Identified uses of the substance or mixture and uses advised against 

Uses in Coatings - Industrial use 

Uses in Coatings • Professional use 

Identified uses 

See Annex to the Safety data sheet for additional Information In the Exposure Scenario(s). 

1.3 Details of the supplier of the safety data sheet 

Jotun Paints (Europe) ltd. 

Stather Road 

Flixborough, Scunthorpe 

North Lincolnshire 

DN15 8RR 

England 

Tel: +4417 24 40 oo oo 

Fax: +44 17 24 40 01 00 

SDSJotun@jotun.com 

1.4 Emergency telephone number 

Contact National Poison Centre via Hospital or Registered Medical Practitioner 

I SECTION 2: Hazards identification 

2.1 Classification of the substance or mixture 

Product definition : Mixture 

Classification according to Directive 1999/45/EC [DPDJ 

The product is classified as dangerous according to Directive 1999/45/EC and its amendments. 

Classification R10 

Xn; R20/21, R65 

XI; R41, R37/38 

N; R51/53 

Physical/chemical hazards Flammable. 

Human health hazards Harmful by Inhalation and in contact with skin. Harmful: may cause lung damage if 

swallowed. Risk of serious damage to eyes. Irritating to respiratory system and skin. 

Environmental hazards Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 

environment. 

See Section 16 for the full text of the R phrases or H statements declared above. 

See Section 11 for more detailed information on health effects and symptoms. 

2.2 Label elements 

.... ' 

I Date of Issue 17.1 0.2012. 1/141 
Conforms to Regulation (EC) No. 1907/2006{REACH), Annex II - United Kingdom (UK) 

Jotun Thinner No. 17 

SECTION 2: Hazards identification 

Hazard symbol or symbols : 

Indication of danger 

Risk phrases 

---

. i I I 

I 

' ! 

' 

Harmful, Dangerous for the environment 

R10- Flammable. 

R20/21- Harmful by Inhalation and in contact with skin. 

R65- Harmful: may cause lung damage if swallowed. 

R41- Risk of serious damage to eyes. 

R37/38- Irritating to respiratory system and skin. 

R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the 

aquatic environment. 

Safety phrases S2- Keep out of the reach of children. 

S23- Do not breathe vapour I spray. 

S26- In case of contact with eyes, rinse immediately with plenty of water and seek 

medical advice. 

S29- Do not empty Into drains. 

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. 

S46- If swallowed, seek medical advice Immediately and show this container or label. 

S51- Use only in well-ventilated areas. 

Hazardous Ingredients Solvent naphtha (petroleum), light arom. 

Supplemental label 

elements 

2.3 Other hazards 

xylene 

Not applicable. 

Other hazards which do not Not available. 

result In classification 

I SECTION 3: Composition/information on ingredients 

Substance/mixture : Mixture 

Classification 

Product/ingredient Identifiers % 67/548/EEC Regulation {EC) No. 

name 1272/2008 [CLP] 

Solvent naphtha REACH#: 01- 50-75 R10 Flam. Llq. 3, H226 

(petroleum), light 2119455851-35 

arom. EC: 265·199-0 Xn;R20,R65 Acute Tox. 4, H332 

CAS: 64742-95-6 Xi;R37 STOT SE 3, H335 

Index: 649-356-00-4 R66 Asp.Tox. 1,H304 

N; R51/53 Aquatic Chronic 2, 

H411 

xylene REACH#: 01- 20-25 R10 Flam. Liq. 3, H22E? 

2119488216-32 

EC: 215-535-7 Xn; R20/21 Acute Tox. 4, H312 

CAS: 1330-20-7 Xi;R38 Acute Tox. 4, H332 

Index: 601-022-{)0-9 Skin lrrit. 2, H315 

butan-1-ol REACH#: 01- 15-20 R10 Flam. Liq. 3, H226 

2119484630-38 

EC: 200-751-6 Xn; R22 Acute Tox. 4, H302 

CAS: 71-36-3 Xi; R41, R37/38 Skin lrrit. 2, H315 

Index: 603-004-00-6 R67 Eye Dam. 1, H318 

STOT SE 3, H335 and 

H336 

ethylbenzene REACH#: 01- 3-7 F; R11 Flam. Llq. 2, H225 

2119489370-35 

EC: 202-849-4 Xn; R20 Acute Tox. 4, H332 

CAS: 100-41-4 

Index: 601-023-00-4 

I Date of Issue 17.10.2012. 

Type Notes 

[1) [2] H·P 

[1] [2] c 

[1] [2] -

[1] [2] -

I 

I 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II -United Kingdom {UK) 

Jotun Thinner No. 17 

SECTION 3: Composition/information on ingredients 

See Section 16 for See Section 16 for 

the full text of the R- the full text of the H 

phrases declared statements declared 

above. above. 

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations 

applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a 

workplace exposure limit and hence require reporting In this section. 

~ 

[1] Substance classified with a health or environmental hazard 

[2] Substance with a workplace exposure limit 

[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII 

[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII 

Occupational exposure limits, if available, are listed in Section 8. 

I SECTION 4: First aid measures 

4.1 Description of first aid measures 

General 

Inhalation 

Skin contact 

Eye contact 

Ingestion 

Protection of first-alders 

In all cases of doubt, or when symptoms persist, seek medical attention. Never give 

anything by mouth to an unconscious person. If unconscious, place in recovery 

position and seek medical advice. 

Remove to fresh air. Keep person warm and at rest. If not breathing, If breathing is 

Irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by 

trained personnel. 

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water 

or use recognised skin cleanser. Do NOT use solvents or thinners. 

Check for and remove any contact lenses. Immediately flush eyes with running water 

for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. 

If swallowed, seek medical advice immediately and show the container or label. Keep 

person warm and at rest. Do not induce vomiting. 

No action shall be taken Involving any personal risk or without suitable training. It may 

be dangerous to the person providing aid to give mouth-to-mouth resuscitation. 

4.2 Most Important symptoms and effects, both acute and delayed 

Potential acute health effects 

Eye contact 

Inhalation 

Skin contact 

Ingestion 

Severely Irritating to eyes. Risk of serious damage to eyes. 

Harmful by inhalation. Irritating to respiratory system. 

Harmful in contact with skin. Irritating to skin. 

Aspiration hazard if swallowed. Can enter lungs and cause damage. Irritating to 

mouth, throat and stomach. 

Over-exposure signs/symptoms 

Eye contact Adverse symptoms may Include the following: 

pain or Irritation 

watering 

redness 

Inhalation Adverse symptoms may include the following: 

respiratory tract Irritation 

Skin contact 

Ingestion 

coughing 

Adverse symptoms may include the following: 

irritation 

redness 

Adverse symptoms may include the following: 

nausea or vomiting 

4.3 Indication of any Immediate medical attention and special treatment needed 

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large 

quantities have been ingested or Inhaled. 

Specific treatments No speclflc treatment. 

I 

I Date of Issue : 17.10.2012. 31141 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) 

Jotun Thinner No. 17 J 

SECTION 4: First aid measures 

I SECTION 5: Firefighting measures 

5.1 Extinguishing media 

Suitable extinguishing 

media 

Unsuitable extinguishing 

media 

Recommended: alcohol-resistant foam, CO 2, powders, water spray. 

Do not use water jet 

5.2 Special hazards arising from the substance or mixture 

Hazards from the Flammable liquid. In a fire or if heated, a pressure increase will occur and the 

substance or mixture container may burst, with the risk of a subsequent explosion. Runoff to sewer may 

Hazardous thermal 

decomposition products 

5.3 Advice for firefighters 

Special protective actions 

for fire-fighters 

Special protective 

equipment for fire-fighters 

create fire or explosion hazard. 

Decomposition products may include the following materials: 

carbon dioxide 

carbon monoxide 

Promptly Isolate the scene by removing all persons from the vicinity of the Incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Move containers from fire area If this can be done without risk. Use water 

spray to keep fire-exposed containers cool. This material is toxic to aquatic 

organisms. Fire water contaminated with this material must be contained and 

prevented from being discharged to any waterway, sewer or drain. 

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus (SCBA) with a full face-piece operated in positive pressure 

mode. Clothing for fire-fighters (including helmets, protective boots and gloves) 

conforming to European standard EN 469 will provide a basic level of protection for 

chemical incidents. 

I SECTION 6: Accidental release measures 

6.1 Personal precautions, protective equipment and emergency procedures 

For non-emergency No action shall be taken Involving any personal risk or without suitable training. 

personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilt material. Shut off all ignition sources. No 

flares, smoking or flames In hazard area. Avoid breathing vapour or mist. Provide 

adequate ventilation. Wear appropriate respirator when ventilation is Inadequate. Put 

on appropriate personal protective equipment. 

For emergency responders If specialised clothing is required to deal with the spillage, take note of any information 

in Section 8 on suitable and unsuitable materials. See also Section 8 for additional 

Information on hygiene measures. 

6.2 Environmental 

precautions 

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to 

the environment if released In large quantities. 

6.3 Methods and materials for containment and cleaning up 

Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop 

up if water-soluble. Alternatively, or If water-insoluble, absorb with an inert dry 

material and place In an appropriate waste disposal container. Use spark-proof tools 

and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. 

I Date of issue 17.10.2012. 

I 
Confonns to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) 

Jotun Thinner No. 17 

SECTION 6: Accidental release measures 

Large spill 

6.4 Reference to other 

sections 

Stop leak if without risk. Move containers from spill area. Approach the release from 

upwind. Prevent entry into sewers, water courses, basements or confined areas. 

Wash spillages Into an effluent treatment plant or proceed as follows. Contain and 

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite 

or diatomaceous earth and place in container for disposal according to local 

regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a 

licensed waste disposal contractor. Contaminated absorbent material may pose the 

same hazard as the spilt product. 

See Section 1 for emergency contact information. 

See Section 8 for information on appropriate personal protective equipment. 

See Section 13 for additional waste treatment information. 

jsECTION 7: Handling and storage 

The information in this section contains generic advice and guidance. The list of Identified Uses In Section 1 should be 

consulted for any available use-specific Information provided In the Exposure Scenarlo(s). 

7.1 Precautions for safe handling 

Prevent the creation of flammable or explosive concentrations of vapours In air and avoid vapour concentrations higher 

than the occupational exposure limits. 

In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been 

excluded. Electrical equipment should be protected to the appropriate standard. 

To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators 

should wear antistatic footwear and clothing and floors should be of the conducting type. 

Keep away from heat, sparks and flame. No sparking tools should be used. 

Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of 

this preparation. Avoid inhalation of dust from sanding. 

Eating, drinking and smoking should be prohibited In areas where this material Is handled, stored and processed. 

Put on appropriate personal protective equipment (see Section 8). 

Never use pressure to empty. Container is not a pressure vessel. 

Always keep in containers made from the same material as the original one. 

Comply with the health and safety at work laws. 

Information on fire and explosion protection 

Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. 

When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to 

control particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed 

respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen 

below the exposure limits. 

7.2 Conditions for safe storage, Including any incompatibilities 

Store in accordance with local regulations. 

Notes on joint storage 

Keep away from: oxidising agents, strong alkalis, strong acids. 

Additional information on storage conditions 

Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep 

away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be 

carefully resealed and kept upright to prevent leakage. 

7.3 Specific end use(s) 

Recommendations 

Industrial sector specific 

solutions 

I Date of Issue 

Not available. 

Not available. 

17.10.2012. 

I 

I 
Jotun Thinner No. 17 

I SECTION 8: Exposure controls/personal protection 

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be 

consulted for any available use-specific information provided in the Exposure Scenario(s). 

8.1 Control parameters 

Occupational exposure limits 

ProducUingredient name Exposure limit values 

Solvent naphtha (petroleum}, light arom. EH40·WEL (United Kingdom (UK}, 12/2011). Absorbed through 

xylene 

butan-1-ol 

ethyfbenzene 

Recommended monitoring 

procedures 

Derived effect levels 

No DELs available. 

Predicted effect concentrations 

No PECs available. 

8.2 Exposure controls 

Appropriate engineering 

controls 

Individual protection measures 

skin. 

TWA: 200 mg/m" 8 hour(s). Form: All forms 

TWA: 40 ppm 8 hour(s}. Form: All forms 

EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed 

through skin. 

STEL: 441 mglm2 15 minute(s). 

STEL: 100 ppm 15 minute(s). 

TWA: 220 mg/m3 8 hour(s). 

TWA: 50 ppm 8 hour(s}. 

EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed 

through skin. 

STEL: 154 mg/m" 15 mfnute(s). 

STEL: 50 ppm 15 minute(s). 

EH40/2005 WELs (United Kingdom (UK), 8/2007). Absorbed 

through skin. 

STEL: 552 mg/m" 15 mlnute(s). 

STEL: 125 ppm 15 minute(s}. 

TWA: 100 ppm 8 hour(s). 

TWA: 441 mglm" 8 hour(s). 

If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness 

of the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment Reference should be made to European Standard EN 689 for 

methods for the assessment of exposure by inhalation to chemical agents and 

national guidance documents for methods for the determination of hazardous 

substances. 

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation 

or other engineering controls to keep worker exposure to airborne contaminants 

below any recommended or statutory limits. The engineering controls also need to 

keep gas, vapour or dust concentrations below any lower explosive limits. Use 

explosion-proof ventilation equipment. 

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period. 

Appropriate techniques should be used to remove potentially contaminated clothing. 

Wash contaminated clothing before reusing. Ensure that eyewash stations and 

safety showers are close to the workstation location. 

Eye/face protection 

Skin protection 

Hand protection 

I Data of Issue 

Safety eyewear complying with an approved standard should be used when a risk 

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or 

dusts. 

For prolonged or repeated handling, use the following type of gloves: gloves: 

polyvinyl alcohol or nitrile. 

Barrier creams may help to protect the exposed areas of the skin but should not be 

applied once exposure has occurred. 

: 17.10.2012. 
Conforms to Regulation (EC) No.1907/2006 (REACH), Annex II- United Klngdom_iUK) 

Jotun Thinner No. 17 

SECTION 8: Exposure controls/personal protection 

Body protection 

Other skin protection 

Respiratory protection 

Environmental exposure 

controls 

For prolonged or repeated handling, use the following type of gloves: 

Recommended, gloves(breakthrough time)> 8 hours: 4H, Teflon, nitrile rubber 

May be used, gloves(breakthrough time} 4- 8 hours: neoprene, butyl rubber, Viton®, 

Barricade, CPF 3, Responder, PVC, polyvinyl alcohol (PVA} 

Not recommended, gloves(breakthrough time) < 1 hour: PE 

For right choice of glove materials, with focus on chemical resistance and time of 

penetration, seek advice by the supplier of chemical resistant gloves. 

The user must check that the final choice of type of glove selected for handling this 

product is the most appropriate and takes into account the particular conditions of 

use, as included In the user's risk assessment. 

Personal protective equipment for the body should be selected based on the task 

being performed and the risks Involved and should be approved by a specialist 

before handling this product. 

Appropriate footwear and any additional skin protection measures should be selected 

based on the task being performed and the risks involved and should be approved by 

a specialist before handling this product. 

If workers are exposed to concentrations above the exposure limit, they must use 

appropriate, certified respirators. Use respiratory mask with charcoal and dust filter 

when spraying this product.( as filter combination A2-P2). In confined spaces, use 

compressed-air or fresh-air respiratory equipment. When use of roller or brush, 

consider use of charcoalfilter. 

Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels. 

J SECTION 9: Physical and chemical properties 

9.1 Information on basic physical and chemical properties 

Appearance 

Physical state 

Colour 

Odour 

Odour threshold 

pH 

Melting point/freezing point 

Initial boiling point and bolllng 

range 

Flash point 

Evaporation rate 

Flammability (solid, gas) 

Bumlngtlme 

Burning rate 

Upper/lower flammability or 

explosive limits 

Vapour pressure 

Vapour density 

Relative density 

Solublllty(les) 

Partition coefficient: noctanollwater 

Auto-ignition temperature 

Decomposition temperature 

VIscosity 

Explosive properties 

I Date of Issue 

Liquid. 

Clear. 

Characteristic. 

Not available. 

Not available. 

Not available. 

Not available. 

Closed cup: 2s•c 

Not available. 

Not available. 

Not applicable. 

Not applicable. 

1.1 -11.3% 

Not available. 

Not available. 

0.86 g/cm' 

Insoluble in the following materials: cold water and hot water. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

17.10.2012. 71141 

I 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II ·United Kingdom (UK) 

Jotun Thinner No. 17 

SECTION 9: Physical and chemical properties 

Oxidising properties : Not available. 

9.2 Other information 

No additional information. 

I SECTION 10: Stability and reactivity 

10.1 Reactivity 

10.2 Chemical stability 

10.3 Possibility of hazardous 

reactions 

10.4 Conditions to avoid 

10.5 Incompatible materials 

10.6 Hazardous 

decomposition products 

No specific test data related to reactivity available for this product or its ingredients. 

The product is stable. 

Under normal conditions of storage and use, hazardous reactions will not occur. 

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, 

braze, solder, drill, grind or expose containers to heat or sources of Ignition. 

Reactive or incompatible with the following materials: 

oxidizing materials 

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced. 

I SECTION 11: Toxicological information 

11.1 Information on toxicological effects 

There are no data available on the preparation itself. The preparation has been assessed following the conventional 

method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See 

sections 2 and 15 for details. 

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result In 

adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, 

liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin. 

Symptoms and signs Include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss 

of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, 

resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause 

Irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-Intestinal irritation and 

chemical pneumonia. Aspiration hazard if swallowed. Can enter lungs and cause damage. 

Risk of serious damage to eyes. 

Product/ingredient name Result Species Dose Exposure 

xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours 

butan 1-ol LC50 Inhalation Gas. Rat 8000ppm 4 hours 

LC50 Inhalation Vapour Rat 24000 mglm3 4 hours 

LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mglkg - ethylbenzene LD50 Oral Rat 3500 mglkg -

I SECTION 12: Ecological information 

12.1 Toxicity 

Product/Ingredient name Result Species Exposure 

Solvent naphtha (petroleum), Acute EC50 <1 0 mg/L Daphnia 48 hours 

lightarom. 

Acute IC50 <10 mgll Algae 72 hours 

Acute LC50 <1 0 mg!L Fish 96 hours 

ethylbenzene Acute EC50 7,2 mgll Algae 48 hours 

Acute EC50 2,93 mg/L Daphnia 48 hours 

Acute LC50 4,2 mgll Fish 96 hours 

Conclusion/Summary Water polluting material. May be harmful to the environment If released in large 

quantities. This material is toxic to aquatic life with long lasting effects. 

12.2 Persistence and degradablllty 

I Date of Issue : 17.10.2012. 

I 
Confonns to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) 

Jotun Thinner No. 17 

SECTION 12: Ecological information 

Conclusion/Summary : Not available. 

Product/Ingredient name Aquatic half·life 

Solvent naphtha (petroleum}, -

light arom. 

xylene - ethyl benzene -

12.3 Bloaccumulative potential 

Product/ingredient name 

xylene 

butan-1-ol 

12.4 Mobility In soil 

Soli/water partition 

coefficient (Koc) 

Mobility 

Log Pow 

3,12 

0,88 

Not available. 

Not available. 

12.5 Results of PBT and vPvB assessment 

PBT Not applicable. 

vPvB Not applicable. 

Photolysis 

-

-

-

BCF 

-

-

12.6 Other adverse effects No known significant effects or critical hazards. 

I SECTION 13: Disposal considerations 

Biodegradability 

Not readily 

Readily 

Readily 

Potential 

high 

low 

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be 

consulted for any available use-specific Information provided in the Exposure Scenario{s). 

13.1 Waste treatment methods 

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste. 

European waste catalogue 08 01 11 * Waste paint and varnish containing organic solvents or other dangerous 

J 

(EWC) substances. If this product Is mixed with other wastes, this code may no longer apply. If 

mixed with other wastes, the appropriate code should be assigned. For further 

information, contact your local waste authority. 

!sECTION 14: Transport information 

Transport within user's premises: always transport In closed containers that are upright and secure. Ensure that 

persons transporting the product know what to do In the event of an accident or spillage. 

Transport In accordance with ADRIRID, IMDG/IMO and ICAO/IATA and national regulation. 

International transport regulations 

14.1 UN number 1263 

14.2 UN proper shipping Paint related material. Marine pollutant (Solvent naphtha (petroleum}, light aromatic) 

name 

14.3 Transport hazard 3 

class{es) 

Marking The environmental hazardous I marine pollutant mark is only applicable for packages 

containing more than 511tres for liquids and 5 kg for solids. 

14.4 Packing group Ill 

14.5 Environmental hazards Yes. 

I Date of Issue : 17.10.2012. 9/141 

I 
Confonns to Regulation (EC) No. 1907/2006 (REACH}, Annex II -United Kingdom{UK) 

Jotun Thinner No. 17 

SECTION 14: Transport information 

14.6 Special precautions 

for user 

Additional Information 

ADR/RID 

IMDG 

14.7 Transport In bulk 

according to Annex II of 

MARPOL 73/78 and the IBC 

Code 

: Not available. 

Tunnel restriction code: (0/E) 

Hazard identification number: 30 

Special provisions: 640E 

Emergency schedules (EmS) 

F-E, S-E 

Not available. 

jsECTION 15: Regulatory information 

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 

EU Regulation fEC) No.1907/2006 CREACH) 

Annex XIV - List of s~:~bstances subject to authorisation 

Substances of verv high concern 

None of the components are listed. 

Annex XVII - Restrictions : Not applicable. 

on the manufacture, 

placing on the market and 

use of certain dangerous 

substances, mixtures and 

articles 

Other EU regulations 

Europe Inventory 

Black List Chemicals 

Priority List Chemicals 

Integrated pollution 

prevention and control list 

(IPPC} -Air 

Integrated pollution 

prevention and control list 

(IPPC} - Water 

lntematjonal regulations 

Chemical Weapons 

Convention List Schedule I 

Chemicals 

Chemical Weapons 

Convention List Schedule II 

Chemicals 

Chemical Weapons 

Convention List Schedule Ill 

Chemicals 

All components are listed or exempted. 

Not listed 

Listed 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

15.2 Chemical Safety 

Assessment 

This product contains substances for which Chemical Safety Assessments are still 

required. 

[Date of Issue 17.10.2012. 101141 

I 
Jotun Thinner No. 17 

j SECTION 16; Other information 

,.. Indicates information that has changed from previously issued version. 

Abbreviations and acronyms : ATE= Acute Toxicity Estimate 

CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 

1272/2008) 

DNEL = Derived No Effect Level 

EUH statement = CLP-specific Hazard statement 

PNEC = Predicted No Effect Concentration 

RRN = REACH Registration Number 

Classification according to Regulation (ECl No. 1272/2008 £CLP/GHSJ 

Flam. Liq. 3, H226 

Acute Tox. 4, H332 

Skin lrrit. 2, H315 

Eye Dam. 1, H318 

STOT SE 3, H335 

Asp. Tox. 1, H304 

Aquatic Chronic 2, H411 

Procedure used to derive the classification accordina to Reaulation (ECl No . 1272/2008 rCLP/GHSl 

Classification Justification 

Flam. Uq. 3, H226 

Acute Tox. 4, H332 

Skin lrrit. 2, H315 

Eye Dam. 1, H318 

STOT SE 3, H335 

Asp. Tox. 1, H304 

Aquatic Chronic 2, H411 

Full text of abbreviated H 

statements 

Full text of classifications 

[CLP/GHS] 

H225 

H226 

H302 

H304 

H312 

H315 

H318 

H332 

H335 

H335 

and 

H336 

On basis of test data 

Calculation method 

Calculation method 

Calculation method 

Calculation method 

Expert judgment 

Calculation method 

Highly flammable liquid and vapour. 

Flammable liquid and vapour. 

Harmful if swallowed. 

May be fatal if swallowed and enters airways. 

Harmful In contact with skin. 

Causes skin irritation. 

Causes serious eye damage. 

Harmful if inhaled. 

May cause respiratory irritation. . 

May cause respiratory Irritation. May cause drowsiness or dizziness. 

H411 Toxic to aquatic life with long lasting effects. 

Acute Tox. 4, H302 ACUTE TOXICITY: ORAL- Category 4 

Acute Tax. 4, H312 ACUTE TOXICITY: SKIN- Category 4 

Acute Tax. 4, H332 ACUTE TOXICITY: INHALATION- Category 4 

Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC)- Category 2 

Asp. Tox. 1, H304 ASPIRATION HAZARD- Category 1 

Eye Dam.1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION- Category 1 

Full text of abbreviated R 

phrases 

I Date of Issue 

Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2 

Flam. Llq. 3, H226 FLAMMABLE LIQUIDS - Category 3 

Skin lrrit. 2, H315 SKIN CORROSION/IRRITATION- Category 2 

STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE 

EXPOSURE) [Respiratory tract irritation] - Category 3 

STOT SE 3, H335 and SPECIFIC TARGET ORGAN TOXICITY (SINGLE 

H336 EXPOSURE) [Respiratory tract irritation and Narcotic 

effects) - Category 3 

R11- Highly flammable. 

R1D- Flammable. 

R20- Harmful by inhalation. 

R22- Harmful If swallowed. 

R20/21- Harmful by inhalation and in contact with skin. 

R65- Harmful: may cause lung damage if swallowed. 

R41- Risk of serious damage to eyes. 

R37- Irritating to respiratory system. 

R38- Irritating to skin. 

R37/38-lrritating to respiratory system and skin. 

R66- Repeated exposure may cause skin dryness or cracking. 

: 17.10.2012. 111141 
Conforms to Regulation (EC} No. 1907/2006 (REACH}, Annex If -United Kingdom (UK) 

Jotun Thinner No. 17 

SECTION 16: Other information 

Full text of classifications 

(DSD/DPD] 

Date of printing 

Date of issue/ Date of 

revision 

Date of previous Issue 

Version 

Notice to reader 

R67- Vapours may cause drowsiness and dizziness. 

R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the 

aquatic environment. 

F - Highly flammable 

Xn- Harmful 

Xi - Irritant 

N - Dangerous for the environment 

17.10.2012. 

17.10.2012. 

No previous validation. 

2 

To the best of our knowledge, the Information contained herein is accurate. However, neither the above-named 

supplier, nor any of Its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the 

Information contained herein. 

Final determination of suitability of any material Is the sole responsibility of the user. All materials may present 

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot 

guarantee that these are the only hazards that exist. 

I Date of Issue 17.10.2012. 12114, 

I 
.. , .. ~-r- -·- ''" . \. '... , ..,.- ' ~~~ .. ~ 

·" 11..-/ ' ,, ...... ' 

Annex , :....~... ...-.3 ~-0 , __ ....,. ....... r ~ ,. ~' 

Jotun Thinner No. 17 

Exposure Scenario: Uses In Coatings -

Sector of Use 

Process Category 

Environmental Release categories 

: Industrial use 

: PROCOS PROC08a 

: ERC4 

Industrial use 

!~ 

. ~~:! 

.. ' :·i 

L 

,. 

.· . 

Covers the use In coaUngs (paints, inks, adhesives, etc) Including exposures during use (including product transfer and preparation, application by brush, 

spray by hand or similar methods) and equipment cleaning. 

Operational conditions and risk management measures 

Control of worker exposure 

Frequency and duration of use : Covers daily exposures up to 8 hours (unless stated differenUy). 

General -Operational condiUons : Assumes use at not more than 2o•c above ambient temperature (unless stated differently). Assumes a 

good basic standard of occupational hygiene Is Implemented. 

General - Risk Management Measures : Wear chemical-resistant gloves (tested to EN374) In combination with 'basic' employee training. Wear 

suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for 

Information on appropriate personal protecllve equipment. 

Type of activity or process Risk Management Measures 

Preparation of material for applfcallon : Provide extract ventilation to points where emissions occur. 

Control of environmental exposure 

Organisational measures to preventlllmlt : Prevent environmental discharge consistent with regulatOIY requirements. 

release from site 

Conditions and measures related to external : External treatment and disposal of waste should comply with appficable local and/or natlonal regulations 

treatment of waste for disposal See Sectlon 13 for additional waste treatment Information. 

Conditions and measures related to external : External recovery and recycling or waste should comply with applicable local andfor national regulations 

recovery or waste 

Additional information 

The exposure scenario ror the mixture Is based on the following substances: 

REACH#: 01·2119455851-35 

REACH#: 01-2119488216-32 

Page: 131141 
Jotun Thinner No. 17 

Exposure Scenario: Uses in Coatings - Professional use 

Sector of Use 

Process Category 

Environmental Release Categories 

: Professional use 

: PROC05 PROCOBa 

: ERC8a ERC8d 

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during usa (Including product transfer and preparation, applicaUon by brush, 

spray by hand or similar methods) and equipment cleaning. 

Operational conditions and risk management measures 

Control of worker exposure 

Frequency and duration of use 

General- Operational conditions 

General - Risk Management Measures 

Type of activity or process 

Preparation of material for application -

Indoor. 

Preparation of material for application -

Outdoor. 

: Covers daily exposures up to 8 hours (unless stated differently). 

: Assumes use at not mora than 20"C above ambient temperatura (unless stated differently). Assumes a 

good basic standard of occupational hygiene Is implemented. 

: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear 

suitable coveralls to prevent exposure to the skin. Use suitable eye protection. See Section 8 for 

information on appropriate personal Pfotectlve equipment. 

Risk Management Measures 

: Provide a good standard of controlled ventllallon (10 to 15 air changes per hour). Avoid carrying out 

activities involving exposure for more than 1 hour. 

or 

Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator 

conforming to EN140 with Type AJP2 filter or better. 

: Ensure operation is undertaken outdoors. Avoid canying out activities invoMng exposure for more than 

1 hour. 

or 

Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator 

conforming to EN140 wilh Type AJP2 filter or bolter. 

Control of environmental exposure 

Organisational measures to prevantnlmit : Prevent environmental discharge consistent with regulatory requirements. 

release from site 

Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations 

treatment of waste for disposal See Section 13 for additional waste treabnent Information. 

Conditions and measures related to external ; External recovery and recycling of waste should comply with applicable local and/or national regulations 

recovery of waste 

Additional information 

The exposure scenario for the mixture is based on the following substances: 

REACH#: 01-2119455851-35 

REACH#: 01-2119488216-32 

Page: 141141 
Jotun Thinner No. 23

MM00000555

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Jotun Thinner No. 23

:

:

:

:

:

1 .

Hazards identification

No known significant effects or critical hazards.

May cause eye irritation.

Harmful if swallowed.

Harmful in contact with skin. May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

WARNING!

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET

ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD -

CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.

Flammable liquid. May be harmful if absorbed through skin or if swallowed. Keep away

from heat, sparks and flame. Avoid exposure - obtain special instructions before use.

Do not breathe vapor or mist. Do not ingest. Do not get in eyes. Avoid contact with skin

and clothing. Contains material that may cause target organ damage, based on animal

data. Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure. Use only with adequate ventilation. Keep

container tightly closed and sealed until ready for use. Wash thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene]. Classified

A3 (Proven for animals.) by ACGIH [cyclohexanone]. Classified 3 (Not classifiable for

humans.) by IARC [cyclohexanone].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at

risk may be aggravated by over-exposure to this product.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

xylene 1330-20-7 50 - 100

butan-1-ol 71-36-3 10 - 25

ethylbenzene 100-41-4 10 - 25

cyclohexanone 108-94-1 2.5 - 10

1-methoxy-2-propanol 107-98-2 2.5 - 10

Composition/information on ingredients

Name CAS number % by weight

3 .

Continued on next page
Jotun Thinner No. 23 Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Wash contaminated clothing thoroughly with water before removing it, or wear

gloves.

4 .

May be combustible at high temperature.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or

explosion hazard.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Continued on next page
Jotun Thinner No. 23 Page: 3/8

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid

breathing vapor or mist. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

xylene ACGIH TLV (United States, 1/2009).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

butan-1-ol ACGIH TLV (United States, 2/2010).

 TWA: 20 ppm 8 hour(s).

NIOSH REL (United States, 6/2009). Absorbed through skin.

 CEIL: 150 mg/m3

 CEIL: 50 ppm

OSHA PEL (United States, 6/2010).

 TWA: 300 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.

 CEIL: 150 mg/m3

 CEIL: 50 ppm

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2008).

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 11/2006).

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Jotun Thinner No. 23 Page: 4/8

8 . Exposure controls/personal protection

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2008). Notes: K

 TWA: 100 ppm 8 hour(s). Form:

 STEL: 125 ppm 15 minute(s). Form:

cyclohexanone ACGIH TLV (United States, 2/2010). Absorbed through skin.

 TWA: 20 ppm 8 hour(s).

 STEL: 50 ppm 15 minute(s).

OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.

 TWA: 25 ppm 8 hour(s).

 TWA: 100 mg/m3 8 hour(s).

NIOSH REL (United States, 6/2009). Absorbed through skin.

 TWA: 25 ppm 10 hour(s).

 TWA: 100 mg/m3 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 50 ppm 8 hour(s).

 TWA: 200 mg/m3 8 hour(s).

1-methoxy-2-propanol ACGIH TLV (United States, 2/2010).

 STEL: 553 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 369 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 STEL: 540 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 360 mg/m3 10 hour(s).

 TWA: 100 ppm 10 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 540 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 360 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Continued on next page
Jotun Thinner No. 23 Page: 5/8

Liquid.

0.87 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Clear.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 866 % (w/w)

:

:

:

:

:

:

Flash point : Closed cup: 24°C (75,2°F)

9 .

7.26 pounds/gallon

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects Contains material that may cause target organ damage, based on animal data.

Contains material which may cause damage to the following organs: kidneys, lungs,

liver, mucous membranes, spleen, upper respiratory tract, skin, central nervous

system (CNS), ears, eye, lens or cornea.

Target organs

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)

by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven

for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Classified A3 (Proven for animals.) by ACGIH [cyclohexanone]. Classified 3 (Not

classifiable for humans.) by IARC [cyclohexanone].

Contains material which may cause damage to the following organs: kidneys, lungs,

liver, mucous membranes, spleen, upper respiratory tract, skin, central nervous

system (CNS), ears, eye, lens or cornea.

Chronic effects on humans

Other toxic effects on

humans

:

:

:

:

:

:

:

11 .

Ecological information

Ecotoxicity data

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

butan-1-ol Daphnia magna (EC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

48 hour(s)

96 hour(s)

96 hour(s)

1983 mg/l

100 mg/l

1730 mg/l

Product/ingredient name Species Period Result

12 .

Continued on next page
Jotun Thinner No. 23 Page: 6/8

12 . Ecological information

Products of degradation Products of degradation: carbon oxides (CO, CO2) and water.

Pimephales promelas (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

1910 mg/l

1940 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

cyclohexanone Pimephales promelas (LC50)

Pimephales promelas (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

527 mg/l

630 mg/l

732 mg/l

:

Environmental precautions : No known significant effects or critical hazards.

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

Transport information

DOT Classification 3 -

TDG Classification 3

Paint related material III

1263 Paint related material III

ADR/RID Class Paint related material 3 III

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

1263 Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

1263

-

14 .

Continued on next page
Jotun Thinner No. 23 Page: 7/8

14 . Transport information

-

IMDG Class Paint related material 3 III

IATA-DGR Class 1263 Paint related material 3 III

1263 Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

-

PG* : Packing group

Flammable liquid

Carcinogen

Target organ effects

HCS Classification

Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: XYLENE;

ethylbenzene; N-BUTYL ALCOHOL; PROPYLENE GLYCOL METHYL ETHER;

CYCLOHEXANONE

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: XYLENES;

BENZENE, DIMETHYL-; ethylbenzene; n-BUTYL ALCOHOL; 1-BUTANOL;

PROPYLENE GLYCOL MONOMETHYL ETHER; 1-METHOXY-2-PROPANOL;

CYCLOHEXANONE

New Jersey Spill: None of the components are listed.

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: butan-1-ol; ethylbenzene; xylene; 1-

methoxy-2-propanol; cyclohexanone

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

butan-1-ol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard; ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)

health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)

health hazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard,

Delayed (chronic) health hazard; cyclohexanone: Fire hazard, Immediate (acute) health

hazard, Delayed (chronic) health hazard

:

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

15 .

xylene 1330-20-7 50 - 100

butan-1-ol 71-36-3 10 - 25

ethylbenzene 100-41-4 10 - 25

xylene 1330-20-7 50 - 100

butan-1-ol 71-36-3 10 - 25

ethylbenzene 100-41-4 10 - 25

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Jotun Thinner No. 23 Page: 8/8

15 . Regulatory information

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed:

Xylene (mixed); Ethylbenzene; 1-Butanol; Cyclohexanone

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

BENZENE, DIMETHYL-; ethylbenzene; 1-BUTANOL; 2-PROPANOL, 1-METHOXY-;

CYCLOHEXANONE

Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

ethylbenzene Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

S23- Do not breathe vapor / spray.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

R10- Flammable.

R20/21- Harmful by inhalation and in contact with skin.

R41- Risk of serious damage to eyes.

R37/38- Irritating to respiratory system and skin.

Risk phrases

EU regulations

Safety phrases

:

:

Hazard symbol or symbols :

Harmful

Other information

Hazardous Material

Information System (U.S.A.)

0

3

1

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET

ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD -

CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.

Label requirements :

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

17.10.2012.

: 1.01

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION C

2

3

0

Health
Product name AMERCOAT 10 THINNER

Product and company identification

:

1 .

AT10/05

PPG Industries, Inc.

One PPG Place

Pittsburgh, PA 15272

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada)

01-800-00-21-400 (Mexico)

Supplier

Code

Emergency telephone 

number

:

:

:

Technical Phone Number : 888-977-4762

Material Safety Data Sheet

Date of issue 22 December 2012

Version 5

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and 

cause damage.

Eyes

Skin

Inhalation

Ingestion

See toxicological information (Section 11)

: DANGER!

:

:

:

:

Medical conditions 

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at 

risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptoms

Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and 

nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes 

headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated 

exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than 

expected from exposure to noise alone.

Keep away from flames, such as a pilot light, and any object that sparks, such as an 

electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid 

breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with 

adequate ventilation. Keep container tightly closed and sealed until ready for use.

Wash thoroughly after handling.

FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE 

IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. ASPIRATION 

HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR 

REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS 

MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose,

mouth and throat.

Irritating to eyes.

May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials 

Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

United States - Canada - Mexico Page: 1/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

3 . Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the 

concentrations applicable, are classified as hazardous to health or the environment and hence require reporting 

in this section.

toluene 108-88-3 30 - 60

4-methylpentan-2-one 108-10-1 30 - 60

ethanol 64-17-5 0.1 - 1

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running 

water for at least 15 minutes, keeping eyelids open. Seek immediate medical 

attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and 

water or use recognized skin cleanser. Do NOT use solvents or thinners.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is 

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by 

trained personnel.

If swallowed, seek medical advice immediately and show this container or label.

Keep person warm and at rest. Do NOT induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this 

product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material 

Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist 

immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Move containers from fire area if this can be done without risk. Use water 

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the 

container may burst, with the risk of a subsequent explosion. Vapors may accumulate 

in low or confined areas or travel a considerable distance to a source of ignition and 

flash back. Runoff to sewer may create fire or explosion hazard.

Special protective 

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Hazardous combustion 

products

: Decomposition products may include the following materials:

carbon oxides

Flammability of the product :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide 

adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put 

on appropriate personal protective equipment (see Section 8).

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air).

Personal precautions :

6 .

United States - Canada - Mexico Page: 2/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

6 . Accidental release measures

Stop leak if without risk. Move containers from spill area. Approach release from 

upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into 

sewers, water courses, basements or confined areas. Wash spillages into an effluent 

treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth 

and place in container for disposal according to local regulations (see Section 13).

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material 

may pose the same hazard as the spilled product. Note: see Section 1 for emergency 

contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and 

explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb 

with an inert dry material and place in an appropriate waste disposal container.

Dispose of via a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink.

Eliminate all ignition sources. Separate from oxidizing materials. Keep container 

tightly closed and sealed until ready for use. Containers that have been opened must 

be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled 

containers. Use appropriate containment to avoid environmental contamination. Do 

not store above the following temperature: 120F / 49C.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking 

and smoking should be prohibited in areas where this material is handled, stored and 

processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing 

vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when 

ventilation is inadequate. Do not enter storage areas and confined spaces unless 

adequately ventilated. Keep in the original container or an approved alternative made 

from a compatible material, kept tightly closed when not in use. Store and use away 

from heat, sparks, open flame or any other ignition source. Use explosion-proof 

electrical (ventilating, lighting and material handling) equipment. Use non-sparking 

tools. Take precautionary measures against electrostatic discharges. Vapors are 

heavier than air and may spread along floors. To avoid fire or explosion, dissipate 

static electricity during transfer by grounding and bonding containers and equipment 

before transferring material. Empty containers retain product residue and can be 

hazardous. Do not reuse container. If this material is part of a multiple component 

system, read the Material Safety Data Sheet(s) for the other component or 

components before blending as the resulting mixture may have the hazards of all of its 

parts.

Handling and storage

Handling

Storage

:

:

7 .

8 . Exposure controls/personal protection

toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not 

established

STEL Not 

established

500 ppm Z A

300 ppm Z C

Not 

established

Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 4-methylpentan-2-one TWA 20 ppm 100 ppm 50 ppm 50 ppm Not 

established

STEL 75 ppm Not 

established

75 ppm 75 ppm Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethanol TWA Not 

established

1000 ppm Not 

established

1000 ppm Not 

established

STEL 1000 ppm Not 

established

1000 ppm Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

Name Result ACGIH OSHA Ontario Mexico PPG

United States - Canada - Mexico Page: 3/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

8 . Exposure controls/personal protection

A = Acceptable Maximum Peak

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

S Potential skin absorption

SR = Respiratory sensitization

SS = Skin sensitization

TD = Total dust

Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must use 

appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator 

complying with an approved standard if a risk assessment indicates this is necessary.

Respirator selection must be based on known or anticipated exposure levels, the 

hazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task 

being performed and the risks involved and should be approved by a specialist before 

handling this product.

When there is a risk of ignition from static electricity, wear anti-static protective clothing.

For the greatest protection from static discharges, clothing should include anti-static 

overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation 

or other engineering controls to keep worker exposure to airborne contaminants below 

any recommended or statutory limits. The engineering controls also need to keep gas,

vapor or dust concentrations below any lower explosive limits. Use explosion-proof 

ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety 

showers are close to the workstation location.

Recommended monitoring 

procedures

: If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness of 

the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment. Reference should be made to appropriate monitoring standards.

Reference to national guidance documents for methods for the determination of 

hazardous substances will also be required.

Environmental exposure 

controls

: Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels.

TLV = Threshold Limit Value

TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. Considering the parameters specified by the glove manufacturer, check 

during use that the gloves are still retaining their protective properties. It should be 

noted that the time to breakthrough for any glove material may be different for different 

glove manufacturers. In the case of mixtures, consisting of several substances, the 

protection time of the gloves cannot be accurately estimated.

F = Fume

IPEL = Internal Permissible Exposure Limit

OSHA = Occupational Safety and Health Administration.

R = Respirable

Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances

STEL =

=

Short term Exposure limit values

Liquid.

Not available.

Not available.

Physical and chemical properties

Physical state

Odor

Color

:

:

:

Flash point : Closed cup: 2.22°C (36°F)

Explosion limits : Lower: 1.1%

9 .

Material supports : Yes.

combustion.

United States - Canada - Mexico Page: 4/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

9 . Physical and chemical properties

>37.78°C (>100°F)

100% (v/v), 100% (w/w)

Not available.

Not available.

0.84

Not available.

2.6 kPa (19.5 mm Hg) [room temperature]

Boiling/condensation point

Melting/freezing point

2.09 (butyl acetate = 1)

pH

Specific gravity

Vapor pressure

Vapor density

Volatility

Evaporation rate

:

:

:

:

:

:

:

:

Partition coefficient: noctanol/water: Not available.

% Solid. (w/w) : 0

Density ( lbs / gal ) : 7.01

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids,

strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,

braze, solder, drill, grind or expose containers to heat or sources of ignition.

Stability and reactivity

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition 

products

Hazardous polymerization

:

:

:

:

:

10 .

11 . Toxicological information

Conclusion/Summary : Not available.

Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Classification

Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer 

depends on duration and level of exposure.

Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or 

dermatitis.

Target organs : Contains material which causes damage to the following organs: brain.

Contains material which may cause damage to the following organs: blood, kidneys,

the nervous system, the reproductive system, liver, heart, upper respiratory tract, skin,

central nervous system (CNS), eye, lens or cornea.

toluene LD50 Oral Rat 636 mg/kg - LD50 Dermal Rabbit 8.39 g/kg - LC50 Inhalation Rat 49 g/m3 4 hours

4-methylpentan-2-one LD50 Oral Rat 2.08 g/kg - LC50 Inhalation 

Vapor

Rat 32772 mg/m3 4 hours

ethanol LD50 Oral Rat 7 g/kg - LC50 Inhalation Rat 124700 mg/m3 4 hours

Product/ingredient name Result Species Dose Exposure

Acute toxicity

Product/ingredient name

toluene A4 3 - - 4-methylpentan-2-one A3 2B - -

ACGIH IARC NTP OSHA

United States - Canada - Mexico Page: 5/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

11 . Toxicological information

Teratogenicity

Developmental effects : Contains material which may cause developmental abnormalities, based on animal 

data.

Fertility effects : Contains material which may impair female fertility, based on animal data.

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4

NTP: Proven, Possible

OSHA: +

Not listed or regulated as a carcinogen: -

Ecological information

Environmental effects : No known significant effects or critical hazards.

12 .

Aquatic ecotoxicity

toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________ 4-methylpentan-2-one Acute LC50 505000 to 514000 ug/L 

Fresh water

Fish - Fathead minnow - Pimephales 

promelas

96 hours

______________________ _________________________________ ________________________________ __________ ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

4 days

_________________________________ ________________________________ __________ Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________

Product/ingredient 

name

Result Species Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal 

of this product, solutions and any by-products should at all times comply with the 

requirements of environmental protection and waste disposal legislation and any 

regional local authority requirements. Dispose of surplus and non-recyclable products 

via a licensed waste disposal contractor. Waste should not be disposed of untreated 

to the sewer unless fully compliant with the requirements of all authorities with 

jurisdiction. Waste packaging should be recycled. Incineration or landfill should only 

be considered when recycling is not feasible. This material and its container must be 

disposed of in a safe way. Care should be taken when handling emptied containers 

that have not been cleaned or rinsed out. Empty containers or liners may retain some 

product residues. Vapor from product residues may create a highly flammable or 

explosive atmosphere inside the container. Do not cut, weld or grind used containers 

unless they have been cleaned thoroughly internally. Avoid dispersal of spilled 

material and runoff and contact with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

for additional handling information and protection of employees. Section 6. Accidental release measures

United States - Canada - Mexico Page: 6/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

14 . Transport information

Regulation UN number Proper shipping name Classes PG*

UN 1263 PAINT RELATED MATERIAL 3 II

Additional information

-

IMDG 1263 PAINT RELATED MATERIAL 3 II - DOT Reportable quantity

1706.6 lbs / 774.8 kg [244.37 

gal / 925.03 L]

Package sizes shipped in 

quantities less than the 

product reportable quantity 

are not subject to the RQ 

(reportable quantity)

transportation requirements.

1263 PAINT RELATED MATERIAL 3 II

CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 

lbs. (454 kg);

Reportable quantity RQ :

PG* : Packing group

15 . Regulatory information

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

United States inventory (TSCA 8b) : All components are listed or exempted.

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

New Zealand ( NZIoC ) :

Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this 

material.

United States

U.S. Federal regulations :

SARA 313

CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 lbs. (454 kg);

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which 

can be obtained from your PPG representative.

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: 4-methylpentan-2-one; toluene

Supplier notification : toluene 108-88-3 30 - 60

4-methylpentan-2-one 108-10-1 30 - 60

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

toluene 108-88-3 Y Y Y N N

4-methylpentan-2-one 108-10-1 Y Y Y N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N

Chemical name

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or 

other reproductive harm.

Canada

United States - Canada - Mexico Page: 7/8
Product name AMERCOAT 10 THINNER

Product code AT10/05 Date of issue 22 December 2012 Version 5

15 . Regulatory information

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A:

Material causing other toxic effects (Very toxic). Class D-2B: Material causing other 

toxic effects (Toxic).

:

Mexico

Flammability 3 Health 2 Reactivity 0

Classification

: : :

Other information

Hazardous Material Information System (U.S.A.)

3

3 0

National Fire Protection Association (U.S.A.)

Health Flammability Instability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this 

information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to 

recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in 

respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary 

measures described in this data sheet or for any misuse of the products.

Date of previous issue : 7/30/2012.

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 

representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.

1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® 

program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may 

be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that prepared 

the MSDS

: EHS

: : :

: 2 * : :

2

0

( * ) - Chronic 

effects

United States - Canada - Mexico Page: 8/8
Product name AMERCOAT 65 THINNER

Product and company identification

:

1 .

AT765/05

PPG Industries, Inc.

One PPG Place

Pittsburgh, PA 15272

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada)

01-800-00-21-400 (Mexico)

Supplier

Code

Emergency telephone 

number

:

:

:

Technical Phone Number : 888-977-4762

Material Safety Data Sheet

Date of issue 22 December 2012

Version 7

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and 

cause damage.

Eyes

Skin

Inhalation

Ingestion

See toxicological information (Section 11)

: DANGER!

:

:

:

:

Medical conditions 

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at 

risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptoms

Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and 

nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes 

headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated 

exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than 

expected from exposure to noise alone.

Keep away from flames, such as a pilot light, and any object that sparks, such as an 

electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid 

breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with 

adequate ventilation. Keep container tightly closed and sealed until ready for use.

Wash thoroughly after handling.

FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND 

SKIN IRRITATION. MAY BE HARMFUL IF INHALED, ABSORBED THROUGH SKIN 

OR SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE 

DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE 

IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose,

mouth and throat.

Irritating to eyes.

Harmful in contact with skin. Irritating to skin.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials 

Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

United States - Canada - Mexico Page: 1/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

3 . Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the 

concentrations applicable, are classified as hazardous to health or the environment and hence require reporting 

in this section.

xylene 1330-20-7 60 - 100

ethylbenzene 100-41-4 10 - 30

toluene 108-88-3 0.1 - 1

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running 

water for at least 15 minutes, keeping eyelids open. Seek immediate medical 

attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and 

water or use recognized skin cleanser. Do NOT use solvents or thinners.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is 

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by 

trained personnel.

If swallowed, seek medical advice immediately and show this container or label.

Keep person warm and at rest. Do NOT induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this 

product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material 

Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist 

immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Move containers from fire area if this can be done without risk. Use water 

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the 

container may burst, with the risk of a subsequent explosion. Vapors may accumulate 

in low or confined areas or travel a considerable distance to a source of ignition and 

flash back. Runoff to sewer may create fire or explosion hazard.

Special protective 

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Hazardous combustion 

products

: Decomposition products may include the following materials:

carbon oxides

Flammability of the product :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide 

adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put 

on appropriate personal protective equipment (see Section 8).

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air).

Personal precautions :

6 .

United States - Canada - Mexico Page: 2/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

6 . Accidental release measures

Stop leak if without risk. Move containers from spill area. Approach release from 

upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into 

sewers, water courses, basements or confined areas. Wash spillages into an effluent 

treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth 

and place in container for disposal according to local regulations (see Section 13).

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material 

may pose the same hazard as the spilled product. Note: see Section 1 for emergency 

contact information and Section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and 

explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb 

with an inert dry material and place in an appropriate waste disposal container.

Dispose of via a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink.

Eliminate all ignition sources. Separate from oxidizing materials. Keep container 

tightly closed and sealed until ready for use. Containers that have been opened must 

be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled 

containers. Use appropriate containment to avoid environmental contamination. Do 

not store above the following temperature: 120F / 49C.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking 

and smoking should be prohibited in areas where this material is handled, stored and 

processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing 

vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when 

ventilation is inadequate. Do not enter storage areas and confined spaces unless 

adequately ventilated. Keep in the original container or an approved alternative made 

from a compatible material, kept tightly closed when not in use. Store and use away 

from heat, sparks, open flame or any other ignition source. Use explosion-proof 

electrical (ventilating, lighting and material handling) equipment. Use non-sparking 

tools. Take precautionary measures against electrostatic discharges. Vapors are 

heavier than air and may spread along floors. To avoid fire or explosion, dissipate 

static electricity during transfer by grounding and bonding containers and equipment 

before transferring material. Empty containers retain product residue and can be 

hazardous. Do not reuse container. If this material is part of a multiple component 

system, read the Material Safety Data Sheet(s) for the other component or 

components before blending as the resulting mixture may have the hazards of all of its 

parts.

Handling and storage

Handling

Storage

:

:

7 .

8 . Exposure controls/personal protection

xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not 

established

STEL 150 ppm Not 

established

150 ppm 150 ppm Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not 

established

STEL Not 

established

Not 

established

125 ppm 125 ppm Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not 

established

STEL Not 

established

500 ppm Z A

300 ppm Z C

Not 

established

Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

Name Result ACGIH OSHA Ontario Mexico PPG

United States - Canada - Mexico Page: 3/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

8 . Exposure controls/personal protection

A = Acceptable Maximum Peak

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

S Potential skin absorption

SR = Respiratory sensitization

SS = Skin sensitization

TD = Total dust

Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must use 

appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator 

complying with an approved standard if a risk assessment indicates this is necessary.

Respirator selection must be based on known or anticipated exposure levels, the 

hazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task 

being performed and the risks involved and should be approved by a specialist before 

handling this product.

When there is a risk of ignition from static electricity, wear anti-static protective clothing.

For the greatest protection from static discharges, clothing should include anti-static 

overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation 

or other engineering controls to keep worker exposure to airborne contaminants below 

any recommended or statutory limits. The engineering controls also need to keep gas,

vapor or dust concentrations below any lower explosive limits. Use explosion-proof 

ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety 

showers are close to the workstation location.

Recommended monitoring 

procedures

: If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness of 

the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment. Reference should be made to appropriate monitoring standards.

Reference to national guidance documents for methods for the determination of 

hazardous substances will also be required.

Environmental exposure 

controls

: Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels.

TLV = Threshold Limit Value

TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. Considering the parameters specified by the glove manufacturer, check 

during use that the gloves are still retaining their protective properties. It should be 

noted that the time to breakthrough for any glove material may be different for different 

glove manufacturers. In the case of mixtures, consisting of several substances, the 

protection time of the gloves cannot be accurately estimated.

F = Fume

IPEL = Internal Permissible Exposure Limit

OSHA = Occupational Safety and Health Administration.

R = Respirable

Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances

STEL =

=

Short term Exposure limit values

Liquid.

Not available.

Not available.

Physical and chemical properties

Physical state

Odor

Color

:

:

:

Flash point : Closed cup: 27.22°C (81°F)

Explosion limits : Lower: 1%

9 .

Material supports : Yes.

combustion.

United States - Canada - Mexico Page: 4/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

9 . Physical and chemical properties

>37.78°C (>100°F)

100% (v/v), 100% (w/w)

Not available.

Not available.

0.87

Not available.

0.85 kPa (6.4 mm Hg) [room temperature]

Boiling/condensation point

Melting/freezing point

0.63 (butyl acetate = 1)

pH

Specific gravity

Vapor pressure

Vapor density

Volatility

Evaporation rate

:

:

:

:

:

:

:

:

Partition coefficient: noctanol/water: Not available.

% Solid. (w/w) : 0

Density ( lbs / gal ) : 7.26

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids,

strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,

braze, solder, drill, grind or expose containers to heat or sources of ignition.

Stability and reactivity

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition 

products

Hazardous polymerization

:

:

:

:

:

10 .

11 . Toxicological information

Conclusion/Summary : Not available.

Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Classification

Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer 

depends on duration and level of exposure.

Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or 

dermatitis.

Target organs : Contains material which causes damage to the following organs: brain.

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the nervous system, liver, gastrointestinal tract, cardiovascular system, upper 

respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea.

xylene LD50 Oral Rat 4.3 g/kg - LD50 Dermal Rabbit >1.7 g/kg - LC50 Inhalation 

Vapor

Rat 5000 ppm 4 hours

ethylbenzene LD50 Oral Rat 3.5 g/kg - LD50 Dermal Rabbit >5000 mg/kg - LC50 Inhalation 

Vapor

Rat 4000 ppm 4 hours

toluene LD50 Oral Rat 636 mg/kg - LD50 Dermal Rabbit 8.39 g/kg - LC50 Inhalation Rat 49 g/m3 4 hours

Product/ingredient name Result Species Dose Exposure

Acute toxicity

United States - Canada - Mexico Page: 5/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal 

data.

Fertility effects : Contains material which may impair female fertility, based on animal data.

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4

NTP: Proven, Possible

OSHA: +

Not listed or regulated as a carcinogen: -

Product/ingredient name

xylene A4 3 - - ethylbenzene A3 2B - -

toluene A4 3 - -

ACGIH IARC NTP OSHA

Ecological information

Environmental effects : No known significant effects or critical hazards.

12 .

Aquatic ecotoxicity

xylene Acute LC50 3300 to 4093 ug/L Fresh 

water

Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

______________________ _________________________________ ________________________________ __________ ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

_________________________________ ________________________________ __________ Acute LC50 5100 to 5700 ug/L Marine 

water

Fish - Atlantic silverside - Menidia 

menidia

96 hours

_________________________________ ________________________________ __________ Acute EC50 2930 to 4400 ug/L Fresh 

water

Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia 

menidia

96 hours

_________________________________ ________________________________ __________ Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________

toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________

Product/ingredient 

name

Result Species Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal 

of this product, solutions and any by-products should at all times comply with the 

requirements of environmental protection and waste disposal legislation and any 

regional local authority requirements. Dispose of surplus and non-recyclable products 

via a licensed waste disposal contractor. Waste should not be disposed of untreated 

to the sewer unless fully compliant with the requirements of all authorities with 

jurisdiction. Waste packaging should be recycled. Incineration or landfill should only 

be considered when recycling is not feasible. This material and its container must be 

disposed of in a safe way. Care should be taken when handling emptied containers 

that have not been cleaned or rinsed out. Empty containers or liners may retain some 

product residues. Vapor from product residues may create a highly flammable or 

Waste disposal

Disposal considerations

:

13 .

United States - Canada - Mexico Page: 6/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

13 . Disposal considerations

explosive atmosphere inside the container. Do not cut, weld or grind used containers 

unless they have been cleaned thoroughly internally. Avoid dispersal of spilled 

material and runoff and contact with soil, waterways, drains and sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

for additional handling information and protection of employees. Section 6. Accidental release measures

14 . Transport information

Regulation UN number Proper shipping name Classes PG*

UN 1307 XYLENES 3 III

Additional information

-

IMDG 1307 XYLENES 3 III - DOT Reportable quantity

118.22 lbs / 53.674 kg [16.

389 gal / 62.04 L]

Package sizes shipped in 

quantities less than the 

product reportable quantity 

are not subject to the RQ 

(reportable quantity)

transportation requirements.

1307 XYLENES 3 III

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 

kg); xylene: 100 lbs. (45.4 kg);

Reportable quantity RQ :

PG* : Packing group

15 . Regulatory information

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

United States inventory (TSCA 8b) : All components are listed or exempted.

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

New Zealand ( NZIoC ) :

Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this 

material.

United States

U.S. Federal regulations :

SARA 313

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.

4 kg);

CAS number Concentration

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: ethylbenzene; xylene

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

xylene 1330-20-7 Y N Y N N

ethylbenzene 100-41-4 Y Y Y N N

toluene 108-88-3 Y Y Y N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N

Chemical name

United States - Canada - Mexico Page: 7/8
Product name AMERCOAT 65 THINNER

Product code AT765/05 Date of issue 22 December 2012 Version 7

15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which 

can be obtained from your PPG representative.

Supplier notification : xylene 1330-20-7 60 - 100

ethylbenzene 100-41-4 10 - 30

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or 

other reproductive harm.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A:

Material causing other toxic effects (Very toxic). Class D-2B: Material causing other 

toxic effects (Toxic).

:

Canada

Mexico

Flammability 3 Health 2 Reactivity 0

Classification

: : :

Other information

Hazardous Material Information System (U.S.A.)

3

3 0

National Fire Protection Association (U.S.A.)

Health Flammability Instability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this 

information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to 

recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in 

respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary 

measures described in this data sheet or for any misuse of the products.

Date of previous issue : 5/18/2011.

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 

representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.

1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® 

program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may 

be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that prepared 

the MSDS

: EHS

: : :

: 2 * : :

2

0

( * ) - Chronic 

effects

United States - Canada - Mexico Page: 8/8
Hardtop XP - Comp. A

MM00003140

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Hardtop XP - Comp. A

:

:

:

:

:

1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may

be delayed following exposure.

May cause eye irritation.

No known significant effects or critical hazards.

Harmful in contact with skin. May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

WARNING!

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE

CANCER, BASED ON ANIMAL DATA.

Flammable liquid. May be harmful if absorbed through skin. Keep away from heat,

sparks and flame. Avoid exposure - obtain special instructions before use. Do not

breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.

Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure. Use only with adequate ventilation. Keep

container tightly closed and sealed until ready for use. Wash thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

None known.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

xylene 1330-20-7 10 - 25

n-butyl acetate 123-86-4 2.5 - 10

ethylbenzene 100-41-4 2.5 - 10

Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 2.5

Composition/information on ingredients

Name CAS number % by weight

3 .

Continued on next page
Hardtop XP - Comp. A Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Wash contaminated clothing thoroughly with water before removing it, or wear

gloves.

4 .

Flammable.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

nitrogen oxides

halogenated compounds

metal oxide/oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or

explosion hazard.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Continued on next page
Hardtop XP - Comp. A Page: 3/8

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid

breathing vapor or mist. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

xylene ACGIH TLV (United States, 1/2009).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

n-butyl acetate ACGIH TLV (United States, 1/2009).

 STEL: 200 ppm 15 minute(s).

 TWA: 150 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 STEL: 950 mg/m3 15 minute(s).

 STEL: 200 ppm 15 minute(s).

 TWA: 710 mg/m3 10 hour(s).

 TWA: 150 ppm 10 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 710 mg/m3 8 hour(s).

 TWA: 150 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 950 mg/m3 15 minute(s).

 STEL: 200 ppm 15 minute(s).

 TWA: 710 mg/m3 8 hour(s).

 TWA: 150 ppm 8 hour(s).

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2008).

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Hardtop XP - Comp. A Page: 4/8

8 . Exposure controls/personal protection

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 11/2006).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2008). Notes: K

 TWA: 100 ppm 8 hour(s). Form:

 STEL: 125 ppm 15 minute(s). Form:

Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001).

 TWA: 125 mg/m3 10 hour(s). Form: All forms

 TWA: 25 ppm 10 hour(s). Form: All forms

ACGIH TLV (United States, 1/2005).

 TWA: 123 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

OSHA PEL 1989 (United States, 3/1989).

 TWA: 125 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Liquid.

1.2 to 1.4 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Various colors.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 384 % (w/w) [ISO % 11890-2]

:

:

:

:

:

:

Flash point : Closed cup: 32°C (89,6°F)

9 .

10.01 to 11.68 pounds/gallon

3.2 pounds/gallon (US)

Continued on next page
Hardtop XP - Comp. A Page: 5/8

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects No known significant effects or critical hazards.

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

Contains bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate. May produce an allergic

reaction.

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)

by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven

for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Chronic effects on humans

Other toxic effects on

humans

:

:

:

:

:

:

11 .

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2

etc.), halogenated compounds. Some metallic oxides.

Ecological information

Products of degradation

Ecotoxicity data

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

n-butyl acetate Pimephales promelas (EC50)

Pimephales promelas (LC50)

Lepomis macrochirus (LC50)

48 hour(s)

96 hour(s)

96 hour(s)

19 mg/l

18 mg/l

100 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

Solvent naphtha (petroleum), light

aromatic

Fish (LC50)

Daphnia (EC50)

Algae (IC50)

96 hour(s)

48 hour(s)

72 hour(s)

<10 mg/l

<10 mg/l

<10 mg/l

Product/ingredient name Species Period Result

:

Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

12 .

Continued on next page
Hardtop XP - Comp. A Page: 6/8

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

-

Transport information

DOT Classification 3 -

TDG Classification 3

Paint III

1263 Paint III

ADR/RID Class Paint 3 III

IMDG Class Paint 3 III

IATA-DGR Class 1263 Paint 3

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

III

1263

1263

Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

-

1263

-

PG* : Packing group

ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity).

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre

capacity).

14 .

Continued on next page
Hardtop XP - Comp. A Page: 7/8

Flammable liquid

Carcinogen

HCS Classification

Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: XYLENE;

ethylbenzene; n-butyl acetate

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: XYLENES;

BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetate

New Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed:

Xylene (mixed); Ethylbenzene; Butyl acetate

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetate

Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Water Act (CWA) 307: c.i. pigment brown 24

Clean Water Act (CWA) 311: formaldehyde

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: ethylbenzene; n-butyl acetate; xylene

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)

health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)

health hazard

:

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

ethylbenzene Yes. No. No. No.

silica, crystalline - quartz Yes. No. No. No.

formaldehyde Yes. No. Yes. No.

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

EU regulations

15 .

xylene 1330-20-7 10 - 25

ethylbenzene 100-41-4 2.5 - 10

xylene 1330-20-7 10 - 25

ethylbenzene 100-41-4 2.5 - 10

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Hardtop XP - Comp. A Page: 8/8

15 . Regulatory information

S23- Do not breathe vapor / spray.

S36/37- Wear suitable protective clothing and gloves.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

R10- Flammable.

R20/21- Harmful by inhalation and in contact with skin.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Risk phrases

Safety phrases

:

:

Hazard symbol or symbols :

Harmful

Other information

Hazardous Material

Information System (U.S.A.)

0

3

1

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE

CANCER, BASED ON ANIMAL DATA.

Label requirements :

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

24.10.2012.

: 1.02

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

2

3

1

Health
Hardtop XP - Comp. B

MM00003240

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Manufacturer

Code

In case of emergency

Product and company identification

Hardtop XP - Comp. B

:

:

:

:

1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may

be delayed following exposure.

May cause eye irritation.

No known significant effects or critical hazards.

May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

CAUTION!

COMBUSTIBLE LIQUID AND VAPOR.

Combustible liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or

mist. Avoid contact with skin and clothing. Use only with adequate ventilation.

:

:

:

:

:

CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

None known.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

n-butyl acetate 123-86-4 2.5 - 10

Solvent naphtha (petroleum), light aromatic 64742-95-6 2.5 - 10

hexamethylene-di-isocyanate 822-06-0 0 - 1

Composition/information on ingredients

Name CAS number % by weight

3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

4 .

Continued on next page
Hardtop XP - Comp. B Page: 2/7

4 . First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Flammable.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

nitrogen oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Combustible liquid. In a fire or if heated, a pressure increase will occur and the

container may burst, with the risk of a subsequent explosion.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid

breathing vapor or mist. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling :

7 .

Continued on next page
Hardtop XP - Comp. B Page: 3/7

7 . Handling and storage

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Storage :

n-butyl acetate ACGIH TLV (United States, 1/2009).

 STEL: 200 ppm 15 minute(s).

 TWA: 150 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 STEL: 950 mg/m3 15 minute(s).

 STEL: 200 ppm 15 minute(s).

 TWA: 710 mg/m3 10 hour(s).

 TWA: 150 ppm 10 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 710 mg/m3 8 hour(s).

 TWA: 150 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 950 mg/m3 15 minute(s).

 STEL: 200 ppm 15 minute(s).

 TWA: 710 mg/m3 8 hour(s).

 TWA: 150 ppm 8 hour(s).

Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001).

 TWA: 125 mg/m3 10 hour(s). Form: All forms

 TWA: 25 ppm 10 hour(s). Form: All forms

ACGIH TLV (United States, 1/2005).

 TWA: 123 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

OSHA PEL 1989 (United States, 3/1989).

 TWA: 125 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

hexamethylene-di-isocyanate ACGIH TLV (United States, 2/2010).

 TWA: 0,01 ppm 8 hour(s).

 TWA: 0,03 mg/m3 8 hour(s).

NIOSH REL (United States, 6/2009).

 TWA: 0,005 ppm 10 hour(s).

 TWA: 35 μg/m3 10 hour(s).

 CEIL: 0,02 ppm 10 minute(s).

 CEIL: 140 μg/m3 10 minute(s).

Exposure controls/personal protection

Product name Exposure limits

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

8 .

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Continued on next page
Hardtop XP - Comp. B Page: 4/7

8 . Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Liquid.

1.13 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Yellowish-brown.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 113 % (w/w) [ISO % 11890-2]

:

:

:

:

:

:

Flash point : Closed cup: 47°C (116,6°F)

9 .

9.43 pounds/gallon

0.94 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects No known significant effects or critical hazards.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects No known significant effects or critical hazards.

Based on the properties of the isocyanate components and considering toxicological

data on similar preparations, this preparation may cause acute irritation and/or

sensitization of the respiratory system, leading to an asthmatic condition, wheezing

and tightness of the chest. Sensitized persons may subsequently show asthmatic

symptoms when exposed to atmospheric concentrations well below the OEL.

Repeated exposure may lead to permanent respiratory disability.

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat

from the skin, resulting in non-allergic contact dermatitis and absorption through the

skin. Repeated or prolonged contact with irritants may cause dermatitis. If splashed

in the eyes, the liquid may cause irritation and reversible damage.

Contains Hexamethylene diisocyanate, oligomers, hexamethylene-di-isocyanate.

May produce an allergic reaction.

Other toxic effects on

humans

:

:

:

:

:

11 .

Ecological information

Ecotoxicity data

Product/ingredient name Species Period Result

12 .

Continued on next page
Hardtop XP - Comp. B Page: 5/7

12 . Ecological information

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2

etc.).

Products of degradation

n-butyl acetate Pimephales promelas (EC50)

Pimephales promelas (LC50)

Lepomis macrochirus (LC50)

48 hour(s)

96 hour(s)

96 hour(s)

19 mg/l

18 mg/l

100 mg/l

Solvent naphtha (petroleum), light

aromatic

Fish (LC50)

Daphnia (EC50)

Algae (IC50)

96 hour(s)

48 hour(s)

72 hour(s)

<10 mg/l

<10 mg/l

<10 mg/l

:

Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

Transport information

DOT Classification - -

TDG Classification -

- -

Not

regulated.

- -

ADR/RID Class Paint 3 III

IMDG Class Paint 3 III

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

1263

1263

Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

Not

regulated.

-

14 .

Continued on next page
Hardtop XP - Comp. B Page: 6/7

14 . Transport information

-

IATA-DGR Class 1263 Paint 3 III -

PG* : Packing group

ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity).

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre

capacity).

HCS Classification Combustible liquid

Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: n-butyl acetate

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: n-butyl

acetate

New Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed: Butyl

acetate

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed: nbutyl acetate

Rhode Island Hazardous Substances: None of the components are listed.

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

TSCA 8(c) calls for record of SAR: hexamethylene-di-isocyanate

TSCA 8(d) H and S data reporting: hexane, 1,6-diisocyanato-, homopolymer

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: n-butyl acetate

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: nbutyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard

:

:

:

R10- Flammable.

R42/43- May cause sensitization by inhalation and skin contact.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Risk phrases

EU regulations

:

Hazard symbol or symbols :

Harmful

15 .

Continued on next page
Hardtop XP - Comp. B Page: 7/7

15 . Regulatory information

S23- Do not breathe vapor / spray.

S24- Avoid contact with skin.

S37- Wear suitable gloves.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show

the label where possible).

Safety phrases :

Other information

Hazardous Material

Information System (U.S.A.)

0

3

0

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

Label requirements : COMBUSTIBLE LIQUID AND VAPOR.

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

24.10.2012.

: 6.01

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

1

2

0

Health
Hardtop Flexi - Comp. A 

j1 . Product and company identification ------------------------------------~ 

Trade name 

Code 

Materia! uses 

Manufacturer 

In case of emergency 

Hardtop Flexi - Camp. A 

MM00001531 

Coatings: Solvent-borne. 

Jotun Paints, Inc. 

9203 Highway 23 

Belle Chasse, LA 70037 

Telephone: (800) 229-3538 or 

(504) 394-3538 

SDSJotun@jotun.no 

1-800-424-9300 

j2. Hazards identification 

Physical slate 

Odor 

OSHA/HCS status 

Skin 

inhalation 

Ingestion 

Potential chronic health 

effects 

Medical conditions 

aggravated by over~ 

exposure 

Liquid. 

Characteristic. 

This material is considered hazardous by the OSHA Hazard Communication Standard 

(29 CFR 1910.1200). 

CAUTION! 

FLAMMABLE LIQUID AND VAPOR MAY BE HARMFUL IF ABSORBED THROUGH 

SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. 

POSSIBLE CANCER HAZARD- CONTAINS MATERIAL WHICH MAY CAUSE 

CANCER, BASED ON ANIMAL DATA. 

Flammable liquid. Harmful in contact with skin. Keep away from heat, sparks and flame. 

Avoid exposure- obtain special instructions before use. Do not breathe vapor or mist. 

Do not get in eyes. Avoid contact with skin and clothing. Contains material that can 

cause target organ damage. Contains material which may cause cancer, based on 

animal data. Risk of cancer depends on duration and level of exposure. Use only with 

adequate ventilation. Keep container tightly closed and sealed until ready for use. 

Wash thoroughly after handling. 

May cause eye irritation. 

Harmful in contact with skin. May cause skin irritation. 

Exposure to decomposition products may cause a health hazard. Serious effects may 

be delayed following exposure. 

No known significant effects or critical hazards. 

CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH, 2B 

(Possible for humans.) by IARC [ethylbenzene]. 

MUTAGENIC EFFECTS: Not available. 

TERATOGENIC EFFECTS: Not available. 

Pre-existing skin disorders and disorders involving any other target organs mentioned in 

this MSDS as being at risk may be aggravated by over-exposure to this product 

See toxicological information (section 11) 

[f Composition/information on ingredients 

Name 

Xylene 

n-butyl acetate 

ethyl benzene 

CAS number 

1330-20-7 

123-86-4 

100-41-4 

1

% bv weight 

10- 25 

2.5 -10 

2.5- 10 

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication 

Standard). 

I Continued on next page 
I Hardtop Flexi - Comp. A Page: 2/8 

rsection4. First aid mea~u~~s 

Eye contact 

Skin contact 

inhalation 

Ingestion 

Protection of first-aiders 

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower 

eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 

minutes. Get medical attention. 

Flush contaminated skin with plenty of water_ Remove contaminated clothing and 

shoes. Wash contaminated clothing thoroughly with water before removing or wear 

gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash 

clothing before reuse. Clean shoes thoroughly before reuse. 

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if 

breathing is irregular or if respiratory arrest occurs, provide artificial respiration or 

oxygen by trained personnel. It may be dangerous to the person providing aid to 

give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in 

recovery position and get medical attention immediately. Maintain an open airway. 

Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of 

decomposition products in a fire, symptoms may be delayed. The exposed person 

may need to be kept under medical surveillance for 48 hours. 

Wash out mouth with water. Remove dentures if any. Move exposed person to 

fresh air. Keep person warm and at rest. If material has been swallowed and the 

exposed person is conscious, give small quantities of water to drink. Stop if the 

exposed person feels sick as vomiting may be dangerous. Do not induce vomiting 

unless directed to do so by medical personneL If vomiting occurs, the head should 

be kept low so that vomit does not enter the lungs. Get medical attention. Never 

give anything by mouth to an unconscious person. If unconscious, place in recovery 

position and get medical attention immediately. Maintain an open airway. Loosen 

tight clothing such as a collar, tie, belt or waistband. 

No action shall be taken involving any personal risk or without suitable training. It 

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. 

Wash contaminated cloth"1ng thoroughly with water before remov'mg or wear gloves. 

15 Fire-fighting measures 

Flammability of the product 

Products of combustion 

Suitable 

No! suitable 

Special exposure hazards 

Speda! protective 

equipment for fire~fighters 

Flammable. 

Decomposition products may include the following materials: 

carbon oxides 

nitrogen oxides 

phosphorus oxides 

metal oxide/oxides 

Use dry chemical, co,, water spray (fog) or foam. 

Do not use water jet. 

Promptly isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Move containers from fire area if this can be done without risk. Use water 

spray to keep fire-exposed containers cool. 

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container 

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or 

explosion hazard. 

Fire-fighters should wear appropriate protective equipment and self-contained breathing 

apparatus (SCBA) with a full face-piece operated in positive pressure mode. 

I L____ Section _____ _ 6. Accidental ~~lease measu~~s 

Personal precautions 

Environmental precautions 

I Continued on next page 

No action shall be taken involving any personal risk or without suitable training. 

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilled material. Shut off all ignition sources. 

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide 

adequate ventilation. Wear appropriate respirator when ventilation is inadequate. 

Put on appropriate personal protective equipment (see section 8). 

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air). 
/Hardtop Flexi -::_amp. A ---~~---~--- -----~- Page: 318 

[se~tion 6. Accidental release measures _ 

Methods for cleaning up Stop leak if without risk. Move containers from spill area. Approach release from 

upwind. Prevent entry into sewers, water courses, basements or confined areas. 

Wash spillages into an effluent treatment plant or proceed as follows. Contain and 

collect spillage with non-combustible, absorbent materia! e.g. sand, earth, vermiculite 

or diatomaceous earth and place in container for disposal according to local 

regulations (see section 13). Use spark-proof tools and explosion-proof equipment 

Dispose of via a licensed waste disposal contractor. Contaminated absorbent 

material may pose the same hazard as the spilled product. Note: see section 1 for 

emergency contact information and section 13 for waste disposal. 

/section 7. Handling and storage l 

Handling 

Storage 

Put on appropriate personal protective equipment (see section 8). Eating, drinking 

and smoking should be prohibited in areas where this material is handled, stored and 

processed. Workers should wash hands and face before eating, drinking and 

smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. 

Do not ingest. Use only with adequate ventilation. Wear appropriate respirator 

when ventilation is inadequate. Do not enter storage areas and confined spaces 

unless adequately ventilated. Keep in the original container or an approved 

alternative made from a compatible material, kept tightly closed when not in use. 

Store and use away from heat, sparks, open flame or any other ignition source. Use 

explosion-proof electrical (ventilating, lighting and material handling) equipment. 

Use non-sparking tools. Take precautionary measures against electrostatic 

discharges. To avoid fire or explosion, dissipate static electricity during transfer by 

grounding and bonding containers and equipment before transferring material. 

Empty containers retain product residue and can be hazardous. Do not reuse 

container. 

Store in accordance with local regulations. Store in a segregated and approved 

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and 

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep 

container tightly closed and sealed until ready for use. Containers that have been 

opened must be carefully resealed and kept upright to prevent leakage. Do not store 

in unlabeled containers. Use appropriate containment to avoid environmental 

contamination. 

Exposure controls/personal protection L___ __ __:__ 

Is I • 

Product name 

Xylene 

n-butyl acetate 

/Continued on next page 

Exposure limits 

ACGIH TLV (United States, 1/2005). Notes: 1996 Adoption 

Substances for which there is a Biological Exposure Index or 

Indices Refers to Appendix A-- Carcinogens. 

STEL: 651 mg/m' 15 minute(s). Form: All forms 

STEL: 150 ppm 15 minute(s). Form: All forms 

TWA: 434 mg/m' 8 hour(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

OSHA PEL (United States, 8/1997). 

TWA: 435 mg/m' 8 hour(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

OSHA PEL 1989 (United States, 3/1989). 

STEL: 655 mg/m' 15 minute(s). Form: All forms 

STEL: 150 ppm 15 minute(s). Form: All forms 

TWA: 435 mg/m' 8 hour(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

ACGIH TLV (United States, 1/2005). Notes: 1998 Adoption. 

STEL: 200 ppm 15 minute(s). Form: All forms 

TWA: 150 ppm 8 hour(s). Form: All forms 

NIOSH REL (United States, 12/2001). 

STEL: 950 mg/m' 15 minute(s). Form: All forms 

STEL: 200 ppm 15 minute(s). Form: All forms 

TWA: 710 mg/m' 10 hour(s). Form: All forms 

TWA: 150 ppm 10 hour(s). Form: All forms 

OSHA PEL (United States, 8/1997). 

TWA: 710 mg/m' 8 hour(s). Form: All forms 
Hardtop Flexi - Comp. A Page: 4/8 

/a . Exposure controls/personal protection 

ethyl benzene 

Engineering measures 

Eyes 

Skin 

Respiratory 

Hands 

Hygiene measures 

TWA: 150 ppm 8 hour(s). Form: All forms 

OSHA PEL 1989 (United States, 3/1989). 

STEL: 950 mg/m' 15 minute(s). Form: All forms 

STEL: 200 ppm 15 minute(s). Form: All forms 

TWA: 710 mg/m' 8 hour(s). Form: All forms 

TWA: 150 ppm 8 hour(s). Form: All forms 

ACGIH TLV (United States, 1/2005). Notes: 2002 Adoption. 

Substances for which there is a Biological Exposure Index or 

Indices 

STEL: 125 ppm 15 minute(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

NIOSH REL (United States, 12/2001). 

STEL: 545 mg/m' 15 minute(s). Form: All forms 

STEL: 125 ppm 15 minute(s). Form: All forms 

TWA: 435 mglm' 10 hour(s). Form: All forms 

TWA: 100 ppm 10 hour(s). Form: All forms 

OSHA PEL (United States, 811997). 

TWA: 435 mg/m' 8 hour(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

OSHA PEL 1989 (United States, 3/1989). 

STEL: 545 mglm' 15 minute(s). Form: All forms 

STEL: 125 ppm 15 minute(s). Form: All forms 

TWA: 435 mg!m' 8 hour(s). Form: All forms 

TWA: 100 ppm 8 hour(s). Form: All forms 

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or 

other engineering controls to keep worker exposure to airborne contaminants below any 

recommended or statutory limits. The engineering controls also need to keep gas, vapor 

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation 

equipment. 

Safety eyewear complying with an approved standard should be used when a risk 

assessment indicates this is necessary to avoid exposure to liquid splashes, mists, 

gases or dusts. 

Personal protective equipment for the body should be selected based on the task being 

performed and the risks involved and should be approved by a specialist before handling 

this product. 

Use a properly fitted, air-purifying or air-fed respirator complying with an approved 

standard if a risk assessment indicates this is necessary. Respirator selection must be 

based on known or anticipated exposure levels, the hazards of the product and the safe 

working limits of the selected respirator. 

Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. 

Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period. Appropriate 

techniques should be used to remove potentially contaminated clothing. Wash 

contaminated clothing before reusing. Ensure that eyewash stations and safety showers 

are close to the workstation location. 

'/9-.---P-h-ys_i_c_a_l_a-nd __ c_h_e_m_i_c_a_lproperties ------------------------. 

Physical stale 

Flash point 

Color 

Odor 

Re!ative density 

voc 

Solubility 

I Continued on next page 

Liquid. 

Closed cup: 25'C (77'F) 

Various colors. 

Characteristic. 

1.19 g/cm' 

3.01 pounds/gallon (US) 

9.76 pounds/gallon 

361 (g/1). 

Insoluble in the following materials: cold water and hot water. 
I Hardtop Flexi - Comp. A Page: 518 

~ion10.St~bil_it~y_a_n_d_r_e_a_ct_iv_i~ty_· ------------------------~~ StabHity and reactivity 

Hazardous decomposition 

products 

Chronic effects on humans 

Other toxic effects on 

humans 

Carcinogenic effects 

Mutagenic effects 

Reproduction toxicity 

Chronic effects 

The product is stable. 

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced. 

CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH, 2B 

(Possible for humans.) by !ARC [ethylbenzene]. 

Contains material which causes damage to the following organs: blood, kidneys, 

liver, gastrointestinal tract, upper respiratory tract, skin, central nervous system 

(CNS), eye, lens or cornea. 

No specific information is available in our database regarding the other toxic effects 

of this material to humans. 

Contains material which may cause cancer, based on animal data. Risk of cancer 

depends on duration and level of exposure. 

No known significant effects or critical hazards. 

No known significant effects or critical hazards. 

Contains material that can cause target organ damage. 

Target organs Contains material which causes damage to the following organs: blood, kidneys, 

liver, gastrointestinal tract, upper respiratory tract, skin, central nervous system 

(CNS), eye, lens or cornea. 

~-Ec~l-ogical information -------

Ecotoxidty data 

Product/ingredient name 

Xylene 

n-butyl acetate 

ethylbenzene 

Environmental precautions 

Products of degradation 

Soedes 

Oncorhynchus mykiss (LC50) 

Oncorhynchus mykiss (LC50) 

Lepomis macrochirus (LC50) 

Lepomis macrochirus (LC50) 

Lepomis macrochirus (LC50) 

Pimephales promelas (LC50) 

Pimephales promelas (EC50) 

Pimephales promelas (LC50) 

Lepomis macrochirus (LC50) 

Daphnia magna (EC50) 

Daphnia magna (EC50) 

Selenastrum capricornutum 

(EC50) 

Oncorhynchus mykiss (LC50) 

Pimephales promelas (LC50) 

Poecilia reticulata (LC50) 

Period 

96 hour(s) 

96 hour(s) 

96 hour(s) 

96 hour(s) 

96 hour(s) 

96 hour(s) 

48 hour(s) 

96 hour(s) 

96 hour(s) 

48 hour(s) 

48 hour(s) 

48 hour(s) 

96 hour(s) 

96 hour(s) 

96 hour(s) 

Result 

3.3 mg/1 

8.2 mg/1 

8.6 mg/1 

12 mg/1 

13.3 mg/1 

13.4 mg/1 

19 mg/1 

18 mg/1 

100 mg/1 

2.93 mg/1 

2.97 mg/1 

7.2 mg/1 

4.2 mg/1 

9.09 mg/1 

9.6 mg/1 

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 

environment. 

Products of degradation: carbon oxides (CO, CO,) and water, nitrogen oxides (NO, NO, 

etc.), phosphates. Sorne metallic oxides. 

[13 . Disposal considera!ions ____________ _ 

Waste disposal 

I Continued on next page 

The generation of waste should be avoided or minimized wherever possible. Dispose of 

surplus and non-recyclable products via a licensed waste disposal contractor. Disposal 

of this product, solutions and any by-products should at all times comply with the 

requirements of environmental protection and waste disposal legislation and any 

regional local authority requirements. Avoid dispersal of spilled material and runoff and 

contact with soil, waterways, drains and sewers. 
\Hardtop Flexi • Comp. A Page: 618 

[13 _: Disposal~onside~ations . ·~~-__j Disposal should be in accordance with applicable regional, national and local laws and regulations. Local 

regulations may be more stringent than regional or national requirements. 

The information presented below only applies to the material as supplied. The identification based on 

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the 

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to 

determine the proper waste identification and disposal methods in compliance with applicable regulations. 

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

for additional handling information and protection of employees. 

l.~-~~~~()l'l_14. Transport information 

Regulatory UN number Proper shipping Class PG"Ilabel 

information name information 

DOT Classification 1263 Paint 3 Ill 

TDG Classification 1263 Paint 3 Ill 

ADR/RID Class 1263 Paint 3 Ill Hazard identification 

number: 30 

iMDG Class 1263 Paint 3 Ill Emergency schedules 

(EmS): F-E, S-E 

Marine pollutant: No. 

lA TA-DGR Class 1263 Paint ,3 Ill 

PG' : Packing group 

/15 . Regulatory information 

HCS Classification 

U.S. Federal regulations 

I Continued on next page 

Flammable liquid 

Carcinogen 

Target organ effects 

TSCA 4(a) final test rules: n-butyl acetate 

TSCA B(a) PAIR: 2-methoxy-1-methylethyl acetate 

United States inventory (TSCA Bb): Not determined. 

TSCA 12(b) one-time export n-butyl acetate 

SARA 302/304/311/312 extremely hazardous substances: No products were found. 

SARA 302/304 emergency planning and notification: No products were found. 

SARA 302/304/311/312 hazardous chemicals ethylbenzene; Xylene; n-butyl acetate; 

titanium dioxide 

SARA 311/312 MSDS distribution- chemical inventory- hazard identification: 

ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health 

hazard; Xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health 

hazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) 

health hazard; titanium dioxide: Immediate (acute) health hazard 

Clean Water Act (CWA) 307: ethylbenzene; trizinc bis(orthophosphate) 

Clean Water Act (CWA) 311: ethylbenzene; Xylene; n-butyl acetate 

Clean Air Act (CAA) 112 accidental release prevenliorr No products were found. 
I Hardtop Flexi - Comp. A Page: 7/8 

r . j15 . Regulatory information~:-:-:-:-;-:-::---:-:~~--:-:-- --;-;---~~__j Clean Air Act (CAA) 112 regulated flammable substances No products were found. 

SARA 313 

Form R. Reporting 

Supplier notification 

Clean Air Act (CAA) 112 regulated toxic substances: No products were found. 

Product name 

Xylene 

ethylbenzene 

trizinc bis(orthophosphate) 

Xylene 

ethyl benzene 

trizinc bis(orthophosphate) 

CAS number 

1330-20-7 

100-41-4 

7779-90-0 

1330-20-7 

100-41-4 

7779-90-0 

Concentration 

10- 25 

2.5. 10 

2.5- 10 

10- 25 

2.5. 10 

2.5- 10 

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall 

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. 

State regulations 

Ingredient name 

ethylbenzene 

EU regulations 

Hazard symbol or symbols 

Risk phrases 

Safety phrases 

I Continued on next page 

Connecticut Carcinogen Reporting: None of the components are listed. 

Connecticut Hazardous Material Survey: None of the components are listed. 

Florida substances: None of the components are listed. 

Illinois Chemical Safety Act None of the components are listed. 

Illinois Toxic Substances Disclosure to Employee Act: None of the components are 

listed. 

Louisiana Reporting: None of the components are listed. 

Louisiana Spill: None of the components are listed. 

Massachusetts Spill: None of the components are listed. 

Massachusetts Substances: The following components are listed: Xylene; n-butyl 

acetate; ethylbenzene;titanium dioxide 

Michigan Critical Material: None of the components are listed. 

Minnesota Hazardous Substances: None of the components are listed. 

New Jersey Hazardous Substances: The following components are listed: Xylene; nbutyl acetate; ethylbenzene; trizinc bis(orthophosphate);titanium dioxide 

New Jersey Spill: None of the components are listed. 

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. 

New York Acutely Hazardous Substances: None of the components are listed. 

New York Toxic Chemical Release Reporting: None of the components are listed. 

Pennsylvania RTK Hazardous Substances: The following components are listed: 

Xylene; n-butyl acetate; ethylbenzene; trizinc bis(orthophosphate);titanium dioxide 

Rhode Island Hazardous Substances: None of the components are listed. 

WARNING: This product contains a chemical known to the State of California to cause 

cancer. 

Yes. 

Harmful 

R10- Flammable. 

Reproductive 

No. 

Dangerous for the 

environment. 

No significant risk 

!eve! 

No. 

R20/21- Harmful by inhalation and in contact with skin. 

R38- Irritating to skin. 

Maximum 

acceptable dosage 

!eve! 

No. 

R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the 

aquatic environment. 

S23· Do not breathe vapor I spray. 

S36137 · Wear suitable protective clothing and gloves. 

838- In case of insufficient ventilation, wear suitable respiratory equipment. 

861- Avoid release to the environment. Refer to special instructions/safety data sheet. 
I Hardtop Flexi • Comp. A Page: 8/8 

~ 6 . Other info~;tion Label requirements 

Hazardous Materia! 

Information System (U.S.A.) 

National Fire Protection 

Association (U.S.A.) 

Date of issue 

Version 

Notice to reader 

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH 

SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. 

POSSIBLE CANCER HAZARD- CONTAINS MATERIAL WHICH MAY CAUSE 

CANCER. BASED ON ANIMAL DATA 

-: l ~P~e,~r's'~o n,~a~l ~p-ro_t_e-ct_i_o_n_ ~ j 

Health 

28.09.2007. 

3 

Flammability 

lnstabilily 

Special 

To the best of our knowledge, the information contained herein is accurate. However, neither the above~named 

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the · 

information contained herein. 

Final determination of suitability of any material is the sole responsibility of the user. All materials may present 

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot 

guarantee that these are the only hazards that exist. 

fi7' Indicates information that has changed from previously issued version. 
Hardtop Flexi Standard - Comp. B

MM00001533

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Hardtop Flexi Standard - Comp. B

:

:

:

:

:

1 .

Hazards identification

Exposure to decomposition products may cause a health hazard. Serious effects may

be delayed following exposure.

May cause eye irritation.

No known significant effects or critical hazards.

Harmful in contact with skin. May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

CAUTION!

COMBUSTIBLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE

CANCER, BASED ON ANIMAL DATA.

Combustible liquid. May be harmful if absorbed through skin. Keep away from heat,

sparks and flame. Avoid exposure - obtain special instructions before use. Do not

breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.

Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure. Use only with adequate ventilation. Wash

thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

None known.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

2-methoxy-1-methylethyl acetate 108-65-6 10 - 25

xylene 1330-20-7 10 - 25

ethylbenzene 100-41-4 1 - 2.5

hexamethylene-di-isocyanate 822-06-0 0 - 1

Composition/information on ingredients

Name CAS number % by weight

3 .

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 2/8

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Wash contaminated clothing thoroughly with water before removing it, or wear

gloves.

4 .

Flammable.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

nitrogen oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Combustible liquid. In a fire or if heated, a pressure increase will occur and the

container may burst, with the risk of a subsequent explosion.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 3/8

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid

breathing vapor or mist. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

2-methoxy-1-methylethyl acetate AIHA WEEL (United States, 5/2010).

 TWA: 50 ppm 8 hour(s).

xylene ACGIH TLV (United States, 1/2009).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2008).

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 11/2006).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2008). Notes: K

 TWA: 100 ppm 8 hour(s). Form:

 STEL: 125 ppm 15 minute(s). Form:

hexamethylene-di-isocyanate ACGIH TLV (United States, 2/2010).

 TWA: 0,01 ppm 8 hour(s).

 TWA: 0,03 mg/m3 8 hour(s).

NIOSH REL (United States, 6/2009).

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 4/8

8 . Exposure controls/personal protection

 TWA: 0,005 ppm 10 hour(s).

 TWA: 35 μg/m3 10 hour(s).

 CEIL: 0,02 ppm 10 minute(s).

 CEIL: 140 μg/m3 10 minute(s).

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Liquid.

1.08 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Various colors.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 24,8 % (w/w) [ISO 11890-1]

:

:

:

:

:

:

Flash point : Closed cup: 38°C (100,4°F)

9 .

9.01 pounds/gallon

2.24 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Based on the properties of the isocyanate components and considering toxicological

data on similar preparations, this preparation may cause acute irritation and/or

sensitization of the respiratory system, leading to an asthmatic condition, wheezing

and tightness of the chest. Sensitized persons may subsequently show asthmatic

symptoms when exposed to atmospheric concentrations well below the OEL.

Repeated exposure may lead to permanent respiratory disability.

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Symptoms and signs include headache, dizziness,

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)

by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven

for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Chronic effects on humans

Other toxic effects on

humans

:

:

11 .

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 5/8

11 . Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects No known significant effects or critical hazards.

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat

from the skin, resulting in non-allergic contact dermatitis and absorption through the

skin. Repeated or prolonged contact with irritants may cause dermatitis. If splashed

in the eyes, the liquid may cause irritation and reversible damage.

Contains Hexamethylene diisocyanate, oligomers, hexamethylene-di-isocyanate.

May produce an allergic reaction.

:

:

:

:

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2

etc.).

Ecological information

Products of degradation

Ecotoxicity data

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

Product/ingredient name Species Period Result

:

Environmental precautions : No known significant effects or critical hazards.

12 .

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

:

13 .

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 6/8

13 . Disposal considerations

for additional handling information and protection of employees.

-

Transport information

DOT Classification - -

TDG Classification -

- -

Not

regulated.

- -

ADR/RID Class Resin solution 3 III

IMDG Class Resin solution 3 III

IATA-DGR Class 1866 Resin solution 3

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

III

1866

1866

Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

-

Not

regulated.

-

PG* : Packing group

ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity).

IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre

capacity).

14 .

Combustible liquid

Carcinogen

HCS Classification

Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

TSCA 8(c) calls for record of SAR: hexamethylene-di-isocyanate

TSCA 8(d) H and S data reporting: hexane, 1,6-diisocyanato-, homopolymer

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: ethylbenzene; 2-methoxy-1-methylethyl

acetate; xylene

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard; 2-methoxy-1-methylethyl acetate: Fire hazard; xylene: Fire hazard, Immediate

(acute) health hazard, Delayed (chronic) health hazard

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

15 .

xylene 1330-20-7 10 - 25

ethylbenzene 100-41-4 1 - 2.5

xylene 1330-20-7 10 - 25

ethylbenzene 100-41-4 1 - 2.5

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 7/8

15 . Regulatory information

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: XYLENE;

ethylbenzene

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: XYLENES;

BENZENE, DIMETHYL-; ethylbenzene

New Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed:

Xylene (mixed); Ethylbenzene

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

BENZENE, DIMETHYL-; ethylbenzene

Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

State regulations :

ethylbenzene Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

S23- Do not breathe vapor / spray.

S24- Avoid contact with skin.

S37- Wear suitable gloves.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show

the label where possible).

R10- Flammable.

R20- Harmful by inhalation.

R42/43- May cause sensitization by inhalation and skin contact.

Risk phrases

EU regulations

Safety phrases

:

:

Hazard symbol or symbols :

Harmful

Other information

Hazardous Material

Information System (U.S.A.)

COMBUSTIBLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE

CANCER, BASED ON ANIMAL DATA.

Label requirements :

:

16 .

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

1

2

0

Health

Continued on next page
Hardtop Flexi Standard - Comp. B Page: 8/8

16 . Other information

0

3

0

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

24.10.2012.

: 6.02

:

:

Indicates information that has changed from previously issued version.
Resist 78 AV - Comp. A

MM00001151

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Resist 78 AV - Comp. A

:

:

:

:

:

1 .

Hazards identification

No known significant effects or critical hazards.

May cause eye irritation.

No known significant effects or critical hazards.

Harmful in contact with skin. May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

WARNING!

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE,

BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN

CAUSE CANCER.

Flammable liquid. May be harmful if absorbed through skin. Keep away from heat,

sparks and flame. Avoid exposure - obtain special instructions before use. Do not

breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.

Contains material that may cause target organ damage, based on animal data.

Contains material which can cause cancer. Risk of cancer depends on duration and

level of exposure. Use only with adequate ventilation. Keep container tightly closed and

sealed until ready for use. Wash thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol].

Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for

animals.) by ACGIH [2-butoxyethanol]. Classified 3 (Not classifiable for humans.) by

IARC [2-butoxyethanol]. Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at

risk may be aggravated by over-exposure to this product.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Continued on next page
Resist 78 AV - Comp. A Page: 2/10

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

ethanol 64-17-5 10 - 25

1-methoxy-2-propanol 107-98-2 10 - 25

tetraethyl silicate 78-10-4 10 - 25

2-butoxyethanol 111-76-2 2.5 - 10

mica 12001-26-2 2.5 - 10

silica, amorphous, diatomaceous earth 61790-53-2 2.5 - 10

butanone 78-93-3 2.5 - 10

xylene 1330-20-7 1 - 2.5

ethylbenzene 100-41-4 0 - 1

Composition/information on ingredients

Name CAS number % by weight

3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it

is suspected that fumes are still present, the rescuer should wear an appropriate

mask or self-contained breathing apparatus. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing

thoroughly with water before removing it, or wear gloves.

4 .

May be combustible at high temperature.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

metal oxide/oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or

explosion hazard.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Continued on next page
Resist 78 AV - Comp. A Page: 3/10

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Avoid exposure - obtain special instructions before use. Do not get in

eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only

with adequate ventilation. Wear appropriate respirator when ventilation is

inadequate. Do not enter storage areas and confined spaces unless adequately

ventilated. Keep in the original container or an approved alternative made from a

compatible material, kept tightly closed when not in use. Store and use away from

heat, sparks, open flame or any other ignition source. Use explosion-proof electrical

(ventilating, lighting and material handling) equipment. Use non-sparking tools.

Take precautionary measures against electrostatic discharges. To avoid fire or

explosion, dissipate static electricity during transfer by grounding and bonding

containers and equipment before transferring material. Empty containers retain

product residue and can be hazardous. Do not reuse container.

Handling and storage

Handling

Storage

:

:

7 .

ethanol ACGIH TLV (United States, 2/2010).

 STEL: 1000 ppm 15 minute(s).

NIOSH REL (United States, 6/2009).

 TWA: 1900 mg/m3 10 hour(s).

 TWA: 1000 ppm 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 1900 mg/m3 8 hour(s).

 TWA: 1000 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 1900 mg/m3 8 hour(s).

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Resist 78 AV - Comp. A Page: 4/10

8 . Exposure controls/personal protection

 TWA: 1000 ppm 8 hour(s).

1-methoxy-2-propanol ACGIH TLV (United States, 2/2010).

 STEL: 553 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 369 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 STEL: 540 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 360 mg/m3 10 hour(s).

 TWA: 100 ppm 10 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 540 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 360 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

tetraethyl silicate ACGIH TLV (United States, 2/2010).

 TWA: 85 mg/m3 8 hour(s).

 TWA: 10 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 TWA: 85 mg/m3 10 hour(s).

 TWA: 10 ppm 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 850 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 85 mg/m3 8 hour(s).

 TWA: 10 ppm 8 hour(s).

2-butoxyethanol OSHA PEL 1989 (United States, 3/1989). Absorbed through skin.

 TWA: 25 ppm 8 hour(s).

 TWA: 120 mg/m3 8 hour(s).

NIOSH REL (United States, 6/2009). Absorbed through skin.

 TWA: 5 ppm 10 hour(s).

 TWA: 24 mg/m3 10 hour(s).

ACGIH TLV (United States, 2/2010).

 TWA: 20 ppm 8 hour(s).

OSHA PEL (United States, 6/2010). Absorbed through skin.

 TWA: 50 ppm 8 hour(s).

 TWA: 240 mg/m3 8 hour(s).

mica OSHA PEL 1989 (United States, 3/1989).

 TWA: 3 mg/m3 8 hour(s). Form: Respirable dust

ACGIH TLV (United States, 2/2010).

 TWA: 3 mg/m3 8 hour(s). Form: Respirable fraction

NIOSH REL (United States, 6/2009).

 TWA: 3 mg/m3 10 hour(s). Form: Respirable fraction

OSHA PEL Z3 (United States, 9/2005).

 TWA: 20 mppcf 8 hour(s).

silica, amorphous, diatomaceous earth OSHA PEL 1989 (United States, 3/1989).

 TWA: 6 mg/m3 8 hour(s).

OSHA PEL Z3 (United States, 9/2005).

 TWA: 80 mg/m3 8 hour(s).

 TWA: 20 mppcf 8 hour(s).

butanone OSHA PEL 1989 (United States, 3/1989).

 TWA: 200 ppm 8 hour(s).

 TWA: 590 mg/m3 8 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

ACGIH TLV (United States, 2/2010).

 TWA: 200 ppm 8 hour(s).

Continued on next page
Resist 78 AV - Comp. A Page: 5/10

8 . Exposure controls/personal protection

 TWA: 590 mg/m3 8 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2009).

 TWA: 200 ppm 10 hour(s).

 TWA: 590 mg/m3 10 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

OSHA PEL (United States, 6/2010).

 TWA: 200 ppm 8 hour(s).

 TWA: 590 mg/m3 8 hour(s).

xylene ACGIH TLV (United States, 1/2009).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2008).

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 11/2006).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2008). Notes: K

 TWA: 100 ppm 8 hour(s). Form:

 STEL: 125 ppm 15 minute(s). Form:

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Continued on next page
Resist 78 AV - Comp. A Page: 6/10

8 . Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Liquid.

1.1 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Various colors.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 103,6 % (w/w) [ISO 11890-1]

:

:

:

:

:

:

Flash point : Closed cup: 15°C (59°F)

9 .

9.18 pounds/gallon

9.51 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which can cause cancer. Risk of cancer depends on duration and

level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects Contains material that may cause target organ damage, based on animal data.

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the nervous system, the reproductive system, liver, lymphatic system,

peripheral nervous system, upper respiratory tract, skin, central nervous system

(CNS), eye, lens or cornea, testes.

Target organs

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol].

Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified A3 (Proven for

animals.) by ACGIH [2-butoxyethanol]. Classified 3 (Not classifiable for humans.) by

IARC [2-butoxyethanol]. Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the nervous system, the reproductive system, liver, lymphatic system,

peripheral nervous system, upper respiratory tract, skin, central nervous system

(CNS), eye, lens or cornea, testes.

Chronic effects on humans

Other toxic effects on

humans

:

:

:

:

:

:

:

11 .

Continued on next page
Resist 78 AV - Comp. A Page: 7/10

Products of degradation: carbon oxides (CO, CO2) and water. Some metallic oxides.

Ecological information

Products of degradation

Ecotoxicity data

ethanol Daphnia magna (EC50)

Daphnia magna (EC50)

Daphnia magna (EC50)

Daphnia magna (LC50)

Pimephales promelas (LC50)

Oncorhynchus mykiss (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2 mg/l

9.3 mg/l

>100 mg/l

>100 mg/l

>100 mg/l

13000 mg/l

2-butoxyethanol Lepomis macrochirus (LC50) 96 hour(s) 1490 mg/l

butanone Daphnia magna (EC50)

Pimephales promelas (LC50)

48 hour(s)

96 hour(s)

5091 mg/l

3220 mg/l

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

Product/ingredient name Species Period Result

:

Environmental precautions : No known significant effects or critical hazards.

12 .

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

Continued on next page
Resist 78 AV - Comp. A Page: 8/10

-

Transport information

DOT Classification 3 -

TDG Classification 3

Paint II

1263 Paint II

ADR/RID Class Paint 3 II

IMDG Class Paint 3 II

IATA-DGR Class 1263 Paint 3

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

II

1263

1263

Tunnel restriction

code: (D/E)

Hazard identification

number: 33

Special provisions:

640D

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

-

1263

-

PG* : Packing group

14 .

Flammable liquid

Carcinogen

Target organ effects

HCS Classification

Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: tetraethyl silicate

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: xylene; 1-methoxy-2-propanol;

butanone; mica; 2-butoxyethanol; tetraethyl silicate; ethanol

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;

1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)

health hazard; butanone: Fire hazard, Immediate (acute) health hazard, Delayed

(chronic) health hazard; mica: Immediate (acute) health hazard; 2-butoxyethanol: Fire

hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; tetraethyl

silicate: Fire hazard, Immediate (acute) health hazard; ethanol: Fire hazard, Immediate

(acute) health hazard, Delayed (chronic) health hazard

:

SARA 313

:

Product name CAS number Concentration

15 .

Continued on next page
Resist 78 AV - Comp. A Page: 9/10

15 . Regulatory information

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: ETHYL ALCOHOL;

tetraethyl silicate; 2-BUTOXYETHANOL; PROPYLENE GLYCOL METHYL ETHER;

MICA DUST; METHYL ETHYL KETONE (MEK); XYLENE

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: ETHYL

ALCOHOL; ALCOHOL; tetraethyl silicate; 2-BUTOXY ETHANOL; BUTYL

CELLOSOLVE; PROPYLENE GLYCOL MONOMETHYL ETHER; 1-METHOXY-2-

PROPANOL; silica, amorphous, diatomaceous earth; MICA; METHYL ETHYL KETONE;

2-BUTANONE; XYLENES; BENZENE, DIMETHYL-; ethylbenzene

New Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed: 2-

Butanone; Xylene (mixed); Ethylbenzene

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

SILICIC ACID, ETHYL ESTER; DENATURED ALCOHOL; tetraethyl silicate; ETHANOL,

2-BUTOXY-; 2-PROPANOL, 1-METHOXY-; 2-BUTANONE; BENZENE, DIMETHYL-;

ethylbenzene

Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

State regulations :

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

ethanol Yes. No. No. No.

ethylbenzene Yes. No. No. No.

carbon black Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

EU regulations

Hazard symbol or symbols :

Highly flammable Harmful

2-butoxyethanol 111-76-2 2.5 - 10

butanone 78-93-3 2.5 - 10

xylene 1330-20-7 1 - 2.5

ethylbenzene 100-41-4 0 - 1

2-butoxyethanol 111-76-2 2.5 - 10

butanone 78-93-3 2.5 - 10

xylene 1330-20-7 1 - 2.5

ethylbenzene 100-41-4 0 - 1

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Resist 78 AV - Comp. A Page: 10/10

15 . Regulatory information

S23- Do not breathe vapor / spray.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

R11- Highly flammable.

R20- Harmful by inhalation.

R36/37- Irritating to eyes and respiratory system.

Risk phrases

Safety phrases

:

:

Other information

Hazardous Material

Information System (U.S.A.)

0

4

2

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED

ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE

CANCER.

Label requirements :

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

06.11.2012.

: 2.04

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

1

4

0

Health
Jotamastic 80 - Comp. A

5580

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Manufacturer

Code

In case of emergency

Product and company identification

Jotamastic 80 - Comp. A

:

:

:

:

1 .

Hazards identification

No known significant effects or critical hazards.

May cause eye irritation.

No known significant effects or critical hazards.

May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

WARNING!

FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSE

TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER

HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON

ANIMAL DATA.

Flammable liquid. Keep away from heat, sparks and flame. Avoid exposure - obtain

special instructions before use. Do not breathe vapor or mist. Avoid contact with skin

and clothing. Contains material that may cause target organ damage, based on animal

data. Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure. Use only with adequate ventilation. Keep

container tightly closed and sealed until ready for use.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven for

animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at

risk may be aggravated by over-exposure to this product.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

xylene 1330-20-7 2.5 - 10

2-methylpropan-1-ol 78-83-1 2.5 - 10

benzyl alcohol 100-51-6 1 - 2.5

ethylbenzene 100-41-4 1 - 2.5

Solvent naphtha (petroleum), light aromatic 64742-95-6 1 - 2.5

Composition/information on ingredients

Name CAS number % by weight

3 .

Continued on next page
Jotamastic 80 - Comp. A Page: 2/9

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It

may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4 .

Flammable.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

halogenated compounds

metal oxide/oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or

explosion hazard.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Continued on next page
Jotamastic 80 - Comp. A Page: 3/9

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid

breathing vapor or mist. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

xylene ACGIH TLV (United States, 1/2011).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

2-methylpropan-1-ol ACGIH TLV (United States, 1/2011).

 TWA: 152 mg/m3 8 hour(s).

 TWA: 50 ppm 8 hour(s).

NIOSH REL (United States, 6/2009).

 TWA: 150 mg/m3 10 hour(s).

 TWA: 50 ppm 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 300 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 150 mg/m3 8 hour(s).

 TWA: 50 ppm 8 hour(s).

benzyl alcohol AIHA WEEL (United States, 10/2011).

 TWA: 10 ppm 8 hour(s).

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Jotamastic 80 - Comp. A Page: 4/9

8 . Exposure controls/personal protection

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2009).

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 6/2010).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2011). Notes: K

 TWA: 20 ppm 8 hour(s). Form:

Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001).

 TWA: 125 mg/m3 10 hour(s). Form: All forms

 TWA: 25 ppm 10 hour(s). Form: All forms

ACGIH TLV (United States, 1/2005).

 TWA: 123 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

OSHA PEL 1989 (United States, 3/1989).

 TWA: 125 mg/m3 8 hour(s). Form: All forms

 TWA: 25 ppm 8 hour(s). Form: All forms

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Liquid.

1.6 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Various

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 207 % (w/w) [ISO % 11890-2]

:

:

:

:

:

:

Flash point : Closed cup: 35°C (95°F)

9 .

13.35 pounds/gallon

1.73 pounds/gallon (US)

Continued on next page
Jotamastic 80 - Comp. A Page: 5/9

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancer

depends on duration and level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects Contains material that may cause target organ damage, based on animal data.

Target organs Contains material which may cause damage to the following organs: skin, eyes.

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

Based on the properties of the epoxy constituent(s) and considering toxicological

data on similar preparations, this preparation may be a skin sensitizer and an irritant.

It contains low-molecular weight epoxy constituents which are irritating to eyes,

mucous membranes and skin. Repeated skin contact may lead to irritation and to

sensitization, possibly with cross-sensitization to other epoxies. Skin contact with the

preparation and exposure to spray, mist and vapors should be avoided.

Contains reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number

average molecular weight ≤ 700), hydrocarbons, c9-unsatd., polymd., epoxy resin

(MW 700-1200). May produce an allergic reaction.

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)

by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven

for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Contains material which may cause damage to the following organs: skin, eyes.

Chronic effects on humans

Other toxic effects on

humans

:

:

:

:

:

:

:

11 .

Ecological information

Ecotoxicity data

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

2-methylpropan-1-ol Scenedesmus subspicatus

(EC50)

Daphnia pulex (EC50)

Scenedesmus subspicatus

(EC50)

Oncorhynchus mykiss (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

230 mg/l

1100 mg/l

1250 mg/l

1330 mg/l

Product/ingredient name Species Period Result

12 .

Continued on next page
Jotamastic 80 - Comp. A Page: 6/9

12 . Ecological information

Products of degradation: carbon oxides (CO, CO2) and water, halogenated compounds.

Some metallic oxides.

Products of degradation

Pimephales promelas (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

1430 mg/l

1510 mg/l

benzyl alcohol Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

10 mg/l

460 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

Solvent naphtha (petroleum), light

aromatic

Fish (LC50)

Daphnia (EC50)

Algae (IC50)

96 hour(s)

48 hour(s)

72 hour(s)

<10 mg/l

<10 mg/l

<10 mg/l

:

Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

Transport information

DOT Classification Paint III 3 -

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

1263

14 .

Continued on next page
Jotamastic 80 - Comp. A Page: 7/9

14 . Transport information

-

TDG Classification 1263 Paint III 3

ADR/RID Class Paint 3 III

IMDG Class Paint 3 III

IATA-DGR Class 1263 Paint 3 III

1263

1263

Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: No.

-

-

PG* : Packing group

ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity). IMDG

Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litre capacity)

Flammable liquid

Carcinogen

Target organ effects

HCS Classification

Regulatory information

U.S. Federal regulations TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: ethylbenzene; xylene; reaction product:

bisphenol-A-(epichlorhydrin); epoxy resin; 2-methylpropan-1-ol; benzyl alcohol

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health

hazard; reaction product: bisphenol-A-(epichlorhydrin); epoxy resin: Immediate (acute)

health hazard; 2-methylpropan-1-ol: Fire hazard, Immediate (acute) health hazard,

Delayed (chronic) health hazard; benzyl alcohol: Immediate (acute) health hazard,

Delayed (chronic) health hazard

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

15 .

xylene 1330-20-7 2.5 - 10

ethylbenzene 100-41-4 1 - 2.5

xylene 1330-20-7 2.5 - 10

ethylbenzene 100-41-4 1 - 2.5

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Jotamastic 80 - Comp. A Page: 8/9

15 . Regulatory information

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: XYLENE;

ethylbenzene; BENZYL ALCOHOL; ISOBUTYL ALCOHOL

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: XYLENES;

BENZENE, DIMETHYL-; ethylbenzene; ISOBUTYL ALCOHOL; 1-PROPANOL, 2-

METHYLNew Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed:

Xylene (mixed); Ethylbenzene; Isobutanol

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

BENZENE, DIMETHYL-; ethylbenzene; BENZENEMETHANOL; 1-PROPANOL, 2-

METHYLRhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

State regulations :

ethylbenzene Yes. No. No. No.

carbon black Yes. No. No. No.

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

S23- Do not breathe vapor / spray.

S24- Avoid contact with skin.

S37- Wear suitable gloves.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

R10- Flammable.

R36/38- Irritating to eyes and skin.

R43- May cause sensitization by skin contact.

R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Risk phrases

EU regulations

Safety phrases

:

:

Hazard symbol or symbols :

Irritant

Continued on next page
Jotamastic 80 - Comp. A Page: 9/9

Other information

Hazardous Material

Information System (U.S.A.)

0

3

1

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSE

TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER

HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL

DATA.

Label requirements :

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

20.02.2013.

: 1.02

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

2

3

1

Health
Product name DIMETCOTE 9 LIQUID

Product and company identification

:

1 .

DI9-A/05

PPG Industries, Inc.

One PPG Place

Pittsburgh, PA 15272

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada)

01-800-00-21-400 (Mexico)

Supplier

Code

Emergency telephone 

number

:

:

:

Technical Phone Number : 888-977-4762

Material Safety Data Sheet

Date of issue 23 January 2013

Version 6.01

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and 

cause damage.

Eyes

Skin

Inhalation

Ingestion

See toxicological information (Section 11)

: DANGER!

:

:

:

:

Medical conditions 

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at 

risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptoms

Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and 

nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes 

headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated 

exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than 

expected from exposure to noise alone. This product contains crystalline silica which can cause lung cancer or silicosis.

The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray 

applications.

Keep away from flames, such as a pilot light, and any object that sparks, such as an 

electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist.

Do not swallow. Avoid contact with eyes, skin and clothing. Use only with adequate 

ventilation. Keep container tightly closed and sealed until ready for use. Wash 

thoroughly after handling.

FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES 

RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED.

SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. ASPIRATION 

HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR 

REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS 

MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD -

CONTAINS MATERIAL WHICH CAN CAUSE CANCER.

Harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes, nose,

mouth and throat.

Irritating to eyes.

May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials 

Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

United States - Canada - Mexico Page: 1/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

3 . Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the 

concentrations applicable, are classified as hazardous to health or the environment and hence require reporting 

in this section.

propan-2-ol 67-63-0 15 - 40

Silicic acid, ethyl ester 11099-06-2 10 - 30

Kaolin 1332-58-7 7 - 13

1-methoxy-2-propanol 107-98-2 5 - 10

tetraethyl silicate 78-10-4 5 - 10

toluene 108-88-3 1 - 5

Mica-group minerals 12001-26-2 1 - 5

ethanol 64-17-5 0.1 - 1

zinc chloride 7646-85-7 0.1 - 1

Quartz (SiO2) (<10 microns) 14808-60-7 0.1 - 1

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running 

water for at least 15 minutes, keeping eyelids open. Seek immediate medical 

attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and 

water or use recognized skin cleanser. Do NOT use solvents or thinners.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is 

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by 

trained personnel.

If swallowed, seek medical advice immediately and show this container or label.

Keep person warm and at rest. Do NOT induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this 

product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material 

Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist 

immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Move containers from fire area if this can be done without risk. Use water 

spray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the 

container may burst, with the risk of a subsequent explosion. Vapors may accumulate 

in low or confined areas or travel a considerable distance to a source of ignition and 

flash back. Runoff to sewer may create fire or explosion hazard.

Special protective 

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Hazardous combustion 

products

: Decomposition products may include the following materials:

carbon oxides

metal oxide/oxides

Flammability of the product :

United States - Canada - Mexico Page: 2/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide 

adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put 

on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from 

upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into 

sewers, water courses, basements or confined areas. Wash spillages into an effluent 

treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth 

and place in container for disposal according to local regulations (see Section 13).

Dispose of via a licensed waste disposal contractor. Contaminated absorbent material 

may pose the same hazard as the spilled product. Note: see Section 1 for emergency 

contact information and Section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air).

Personal precautions :

Large spill :

6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and 

explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb 

with an inert dry material and place in an appropriate waste disposal container.

Dispose of via a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink.

Eliminate all ignition sources. Separate from oxidizing materials. Keep container 

tightly closed and sealed until ready for use. Containers that have been opened must 

be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled 

containers. Use appropriate containment to avoid environmental contamination. Do 

not store above the following temperature: 120F / 49C.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking 

and smoking should be prohibited in areas where this material is handled, stored and 

processed. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on 

skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when 

ventilation is inadequate. Do not enter storage areas and confined spaces unless 

adequately ventilated. Keep in the original container or an approved alternative made 

from a compatible material, kept tightly closed when not in use. Store and use away 

from heat, sparks, open flame or any other ignition source. Use explosion-proof 

electrical (ventilating, lighting and material handling) equipment. Use non-sparking 

tools. Take precautionary measures against electrostatic discharges. Vapors are 

heavier than air and may spread along floors. To avoid fire or explosion, dissipate 

static electricity during transfer by grounding and bonding containers and equipment 

before transferring material. Empty containers retain product residue and can be 

hazardous. Do not reuse container. If this material is part of a multiple component 

system, read the Material Safety Data Sheet(s) for the other component or 

components before blending as the resulting mixture may have the hazards of all of its 

parts.

Handling and storage

Handling

Storage

:

:

7 .

8 . Exposure controls/personal protection

Name Result ACGIH OSHA Ontario Mexico PPG

United States - Canada - Mexico Page: 3/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

8 . Exposure controls/personal protection

A = Acceptable Maximum Peak

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

S Potential skin absorption

SR = Respiratory sensitization

SS = Skin sensitization

TD = Total dust

Key to abbreviations

Consult local authorities for acceptable exposure limits.

Recommended monitoring 

procedures

: If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness of 

the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment. Reference should be made to appropriate monitoring standards.

Reference to national guidance documents for methods for the determination of 

hazardous substances will also be required.

TLV = Threshold Limit Value

TWA = Time Weighted Average

F = Fume

IPEL = Internal Permissible Exposure Limit

OSHA = Occupational Safety and Health Administration.

R = Respirable

Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances

propan-2-ol TWA 200 ppm 400 ppm 200 ppm 400 ppm Not 

established

STEL 400 ppm Not 

established

400 ppm 500 ppm Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Kaolin TWA 2 mg/m3 R 5 mg/m3 R

15 mg/m3 TD

2 mg/m3 R 10 mg/m3 Not 

established

STEL Not 

established

Not 

established

Not 

established

20 mg/m3 Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1-methoxy-2-propanol TWA 100 ppm Not 

established

100 ppm Not 

established

Not 

established

STEL 150 ppm Not 

established

150 ppm Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

tetraethyl silicate TWA 10 ppm 100 ppm 10 ppm 10 ppm Not 

established

STEL Not 

established

Not 

established

Not 

established

30 ppm Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not 

established

STEL Not 

established

500 ppm Z A

300 ppm Z C

Not 

established

Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Mica-group minerals TWA 3 mg/m3 R 20 mppcf Z 3 mg/m3 R 3 mg/m3 Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethanol TWA Not 

established

1000 ppm Not 

established

1000 ppm Not 

established

STEL 1000 ppm Not 

established

1000 ppm Not 

established

Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

zinc chloride TWA 1 mg/m3 F 1 mg/m3 F 1 mg/m3 F 1 mg/m3 Not 

established

STEL 2 mg/m3 F Not 

established

2 mg/m3 F 2 mg/m3 Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Quartz (SiO2) (<10 microns) TWA 0.025 mg/m3 

R

10 mg/m3 R 

Z

30 mg/m3 

TD Z

250 mppcf 

R Z

0.1 mg/m3 R 0.1 mg/m3 R Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL =

=

Short term Exposure limit values

United States - Canada - Mexico Page: 4/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

8 . Exposure controls/personal protection

If workers are exposed to concentrations above the exposure limit, they must use 

appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator 

complying with an approved standard if a risk assessment indicates this is necessary.

Respirator selection must be based on known or anticipated exposure levels, the 

hazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task 

being performed and the risks involved and should be approved by a specialist before 

handling this product.

When there is a risk of ignition from static electricity, wear anti-static protective clothing.

For the greatest protection from static discharges, clothing should include anti-static 

overalls, boots and gloves.

Personal protection

Eyes

Skin

Respiratory

:

:

:

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation 

or other engineering controls to keep worker exposure to airborne contaminants below 

any recommended or statutory limits. The engineering controls also need to keep gas,

vapor or dust concentrations below any lower explosive limits. Use explosion-proof 

ventilation equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety 

showers are close to the workstation location.

Environmental exposure 

controls

: Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels.

Gloves : For prolonged or repeated handling, use the following type of gloves:

Recommended: nitrile rubber

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. Considering the parameters specified by the glove manufacturer, check 

during use that the gloves are still retaining their protective properties. It should be 

noted that the time to breakthrough for any glove material may be different for different 

glove manufacturers. In the case of mixtures, consisting of several substances, the 

protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F)

Liquid.

76% (v/v), 60.65% (w/w)

Not available.

Not available.

1.02

Not available.

4 kPa (30.3 mm Hg) [room temperature]

Not available.

Not available.

Boiling/condensation point

Melting/freezing point

2.54 (butyl acetate = 1)

Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure

Vapor density

Volatility

Evaporation rate

Odor

Color

:

:

:

:

:

:

:

:

:

:

:

Flash point : Closed cup: 15.56°C (60°F)

Explosion limits : Lower: 1.8%

9 .

Density ( lbs / gal ) : 8.51

Material supports : Yes.

combustion.

United States - Canada - Mexico Page: 5/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

9 . Physical and chemical properties

Partition coefficient: noctanol/water: Not available.

% Solid. (w/w) : 39.35

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,water,acids,oxidizing materials,

strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,

braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid 

increased storage temperature. Pressure hazard

Stability and reactivity

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition 

products

Hazardous polymerization

:

:

:

:

:

10 .

11 . Toxicological information

Conclusion/Summary : Not available.

Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Classification

Carcinogenicity : Contains material which can cause cancer. Risk of cancer depends on duration and 

level of exposure.

Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or 

dermatitis.

Target organs : Contains material which causes damage to the following organs: brain.

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the reproductive system, liver, heart, spleen, upper respiratory tract, skin, central 

nervous system (CNS), eye, lens or cornea, stomach, testes.

propan-2-ol LD50 Oral Rat 4.396 g/kg - LD50 Dermal Rabbit 12800 mg/kg - LC50 Inhalation 

Vapor

Rat 72600 mg/m3 4 hours

Kaolin LD50 Oral Rat >5000 mg/kg - 1-methoxy-2-propanol LD50 Oral Rat 5.2 g/kg - LD50 Dermal Rabbit 13 g/kg -

tetraethyl silicate LD50 Oral Rat 6.27 g/kg - LD50 Dermal Rabbit 5.878 g/kg -

toluene LD50 Oral Rat 636 mg/kg - LD50 Dermal Rabbit 8.39 g/kg - LC50 Inhalation Rat 49 g/m3 4 hours

ethanol LD50 Oral Rat 7 g/kg - LC50 Inhalation Rat 124700 mg/m3 4 hours

zinc chloride LD50 Oral Rat 0.35 g/kg -

Product/ingredient name Result Species Dose Exposure

Acute toxicity

Product/ingredient name

propan-2-ol A4 3 - - Kaolin A4 - - -

toluene A4 3 - - Quartz (SiO2) (<10 microns) A2 1 Proven. -

ACGIH IARC NTP OSHA

United States - Canada - Mexico Page: 6/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal 

data.

Fertility effects : Contains material which may impair male fertility, based on animal data. Contains 

material which may impair female fertility, based on animal data.

Teratogenicity : Contains material which may cause birth defects, based on animal data.

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4

NTP: Proven, Possible

OSHA: +

Not listed or regulated as a carcinogen: -

Ecological information

Environmental effects : No known significant effects or critical hazards.

12 .

Aquatic ecotoxicity

propan-2-ol Acute LC50 >1400000 ug/L Fish - Bluegill - Lepomis macrochirus 96 hours ______________________ _________________________________ ________________________________ __________

toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________ ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

4 days

_________________________________ ________________________________ __________ Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

_________________________________ ________________________________ __________ Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia 

magna

48 hours

______________________ _________________________________ ________________________________ __________

Product/ingredient 

name

Result Species Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal 

of this product, solutions and any by-products should at all times comply with the 

requirements of environmental protection and waste disposal legislation and any 

regional local authority requirements. Dispose of surplus and non-recyclable products 

via a licensed waste disposal contractor. Waste should not be disposed of untreated 

to the sewer unless fully compliant with the requirements of all authorities with 

jurisdiction. Waste packaging should be recycled. Incineration or landfill should only 

be considered when recycling is not feasible. This material and its container must be 

disposed of in a safe way. Care should be taken when handling emptied containers 

that have not been cleaned or rinsed out. Empty containers or liners may retain some 

product residues. Vapor from product residues may create a highly flammable or 

explosive atmosphere inside the container. Do not cut, weld or grind used containers 

unless they have been cleaned thoroughly internally. Avoid dispersal of spilled 

material and runoff and contact with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

for additional handling information and protection of employees. Section 6. Accidental release measures

United States - Canada - Mexico Page: 7/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

14 . Transport information

Regulation UN number Proper shipping name Classes PG*

UN 1263 PAINT 3 II

Additional information

-

IMDG 1263 PAINT 3 II - DOT Reportable quantity

25002.6 lbs / 11351.2 kg 

[2930 gal / 11091.2 L]

Package sizes shipped in 

quantities less than the 

product reportable quantity 

are not subject to the RQ 

(reportable quantity)

transportation requirements.

1263 PAINT 3 II

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 

kg);

Reportable quantity RQ :

PG* : Packing group

15 . Regulatory information

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

Substance Use Restricted

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

New Zealand ( NZIoC )

United States inventory (TSCA 8b) :

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

Philippines inventory (PICCS) :

:

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this 

material.

United States

U.S. Federal regulations :

SARA 313

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 kg);

CAS number Concentration

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: 1-methoxy-2-propanol; Kaolin; Mica-group minerals; propan-2-ol;

toluene; tetraethyl silicate

Supplier notification : propan-2-ol 67-63-0 15 - 40

toluene 108-88-3 1 - 5

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

propan-2-ol 67-63-0 Y N Y N N

Silicic acid, ethyl ester 11099-06-2 Y N N N N

Kaolin 1332-58-7 Y N N N N

1-methoxy-2-propanol 107-98-2 Y N Y N N

tetraethyl silicate 78-10-4 Y N Y Y N

toluene 108-88-3 Y Y Y N N

Mica-group minerals 12001-26-2 N N N N N

zinc chloride 7646-85-7 Y Y N Y N

Quartz (SiO2) (<10 microns) 14808-60-7 N Y N N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y Y N

Chemical name

United States - Canada - Mexico Page: 8/9
Product name DIMETCOTE 9 LIQUID

Product code DI9-A/05 Date of issue 23 January 2013 Version 6.01

15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which 

can be obtained from your PPG representative.

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or 

other reproductive harm.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B:

Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material 

causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic 

effects (Toxic).

:

Canada

Mexico

Flammability 3 Health 3 Reactivity 1

Classification

: : :

Other information

Hazardous Material Information System (U.S.A.)

3

3 1

National Fire Protection Association (U.S.A.)

Health Flammability Instability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this 

information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to 

recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in 

respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary 

measures described in this data sheet or for any misuse of the products.

Date of previous issue : 12/22/2012.

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 

representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.

1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® 

program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may 

be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that prepared 

the MSDS

: EHS

: : :

: 3 * : :

3

1

( * ) - Chronic 

effects

United States - Canada - Mexico Page: 9/9
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product and company identification

:

1 .

DI9-P

PPG Industries, Inc.

One PPG Place

Pittsburgh, PA 15272

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada)

01-800-00-21-400 (Mexico)

Supplier

Code

Emergency telephone 

number

:

:

:

Technical Phone Number : 888-977-4762

Material Safety Data Sheet

Date of issue 26 May 2013

Version 19

Emergency overview

Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes

Skin

Inhalation

Ingestion

See toxicological information (Section 11)

: WARNING!

:

:

:

:

Medical conditions 

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at 

risk may be aggravated by over-exposure to this product.

:

2 .

Over-exposure signs/symptoms

Ingestion :

Skin :

Eyes :

Inhalation :

Use only with adequate ventilation. Keep container tightly closed and sealed until 

ready for use. Wash thoroughly after handling.

MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING 

DUSTS MAY BE HARMFUL IF INHALED. CONTAINS MATERIAL THAT MAY CAUSE 

TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

May be harmful if inhaled.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials 

Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

No specific data.

No specific data.

No specific data.

No specific data.

3 . Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the 

concentrations applicable, are classified as hazardous to health or the environment and hence require reporting 

in this section.

Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100

zinc oxide 1314-13-2 1 - 5

Name CAS number %

United States - Canada - Mexico Page: 1/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running 

water for at least 15 minutes, keeping eyelids open. Seek immediate medical 

attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and 

water or use recognized skin cleanser. Do NOT use solvents or thinners.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is 

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by 

trained personnel.

If swallowed, seek medical advice immediately and show this container or label.

Keep person warm and at rest. Do NOT induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this 

product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material 

Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist 

immediately if large quantities have been ingested or inhaled.

Use an extinguishing agent suitable for the surrounding fire.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shall be taken involving any personal risk or without suitable 

training. Fire water contaminated with this material must be contained and prevented 

from being discharged to any waterway, sewer or drain.

No specific fire or explosion hazard.

Special protective 

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

None known.

Suitable :

Not suitable :

Hazardous combustion 

products

: Decomposition products may include the following materials:

metal oxide/oxides

Flammability of the product :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilled material. Provide adequate ventilation.

Wear appropriate respirator when ventilation is inadequate. Put on appropriate 

personal protective equipment (see Section 8).

Move containers from spill area. Approach release from upwind. Prevent entry into 

sewers, water courses, basements or confined areas. Vacuum or sweep up material 

and place in a designated, labeled waste container. Dispose of via a licensed waste 

disposal contractor. Note: see Section 1 for emergency contact information and 

Section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to 

the environment if released in large quantities.

Personal precautions :

Large spill :

6 .

Move containers from spill area. Vacuum or sweep up material and place in a 

designated, labeled waste container. Dispose of via a licensed waste disposal 

contractor.

Small spill :

United States - Canada - Mexico Page: 2/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

Store in accordance with local regulations. Store in original container protected from 

direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials 

(see Section 10) and food and drink. Keep container tightly closed and sealed until 

ready for use. Containers that have been opened must be carefully resealed and kept 

upright to prevent leakage. Do not store in unlabeled containers. Use appropriate 

containment to avoid environmental contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking 

and smoking should be prohibited in areas where this material is handled, stored and 

processed. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid release 

to the environment. Keep in the original container or an approved alternative made 

from a compatible material, kept tightly closed when not in use. Empty containers 

retain product residue and can be hazardous. Do not reuse container.

Handling and storage

Handling

Storage

:

:

7 .

8 . Exposure controls/personal protection

A = Acceptable Maximum Peak

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

S Potential skin absorption

SR = Respiratory sensitization

SS = Skin sensitization

TD = Total dust

Key to abbreviations

Safety glasses with side shields.

Personal protection

Eyes

Consult local authorities for acceptable exposure limits.

:

Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to 

control worker exposure to airborne contaminants. If this product contains ingredients 

with exposure limits, use process enclosures, local exhaust ventilation or other 

engineering controls to keep worker exposure below any recommended or statutory 

limits.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety 

showers are close to the workstation location.

Recommended monitoring 

procedures

: If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness of 

the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment. Reference should be made to appropriate monitoring standards.

Reference to national guidance documents for methods for the determination of 

hazardous substances will also be required.

TLV = Threshold Limit Value

TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be 

worn at all times when handling chemical products if a risk assessment indicates this is 

necessary. Considering the parameters specified by the glove manufacturer, check 

during use that the gloves are still retaining their protective properties. It should be 

noted that the time to breakthrough for any glove material may be different for different 

glove manufacturers. In the case of mixtures, consisting of several substances, the 

protection time of the gloves cannot be accurately estimated.

F = Fume

IPEL = Internal Permissible Exposure Limit

OSHA = Occupational Safety and Health Administration.

R = Respirable

Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances

zinc oxide TWA 2 mg/m3 R 5 mg/m3 F

5 mg/m3 R

15 mg/m3 TD

2 mg/m3 R 10 mg/m3

5 mg/m3

Not 

established

STEL 10 mg/m3 R Not 

established

10 mg/m3 R 10 mg/m3 Not 

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

Name Result ACGIH OSHA Ontario Mexico IPEL

STEL =

=

Short term Exposure limit values

United States - Canada - Mexico Page: 3/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

8 . Exposure controls/personal protection

If workers are exposed to concentrations above the exposure limit, they must use 

appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator 

complying with an approved standard if a risk assessment indicates this is necessary.

Respirator selection must be based on known or anticipated exposure levels, the 

hazards of the product and the safe working limits of the selected respirator.

Personal protective equipment for the body should be selected based on the task 

being performed and the risks involved and should be approved by a specialist before 

handling this product.

Skin

Respiratory

:

:

Environmental exposure 

controls

: Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels.

Not available.

Solid.

0% (v/v), 0% (w/w)

Not available.

Not available.

7.13

Not available.

0 kPa (0 mm Hg) [room temperature]

Not available.

Not available.

Boiling/condensation point

Melting/freezing point

0 (butyl acetate = 1)

Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure

Vapor density

Volatility

Evaporation rate

Odor

Color

:

:

:

:

:

:

:

:

:

:

:

Flash point : Closed cup: Not applicable. [Product does not sustain combustion.]

9 .

Partition coefficient: noctanol/water: Not available.

% Solid. (w/w) : 100

Density ( lbs / gal ) : 59.5

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,acids,oxidizing materials,strong 

alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Evolves hydrogen on contact with water.

Avoid increased storage temperature. Pressure hazard

Stability and reactivity

Stability

Conditions to avoid

Materials to avoid

Hazardous decomposition 

products

Hazardous polymerization

:

:

:

:

:

10 .

11 . Toxicological information

Conclusion/Summary : Not available.

Chronic toxicity

Conclusion/Summary : Not available.

Target organs : Contains material which may cause damage to the following organs: lungs.

Acute toxicity

United States - Canada - Mexico Page: 4/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

Ecological information

Environmental effects : Water polluting material. May be harmful to the environment if released in large 

quantities.

12 .

Aquatic ecotoxicity

Zinc powder - zinc dust 

(stabilized)

Acute LC50 0.41 mg/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss

96 hours

______________________ _________________________________ ________________________________ __________

Product/ingredient 

name

Result Species Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal 

of this product, solutions and any by-products should at all times comply with the 

requirements of environmental protection and waste disposal legislation and any 

regional local authority requirements. Dispose of surplus and non-recyclable products 

via a licensed waste disposal contractor. Waste should not be disposed of untreated 

to the sewer unless fully compliant with the requirements of all authorities with 

jurisdiction. Waste packaging should be recycled. Incineration or landfill should only 

be considered when recycling is not feasible. This material and its container must be 

disposed of in a safe way. Care should be taken when handling emptied containers 

that have not been cleaned or rinsed out. Empty containers or liners may retain some 

product residues. Avoid dispersal of spilled material and runoff and contact with soil,

waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 

for additional handling information and protection of employees. Section 6. Accidental release measures

14 . Transport information

Regulation UN number Proper shipping name Classes PG*

UN 3077 ENVIRONMENTALLY HAZARDOUS 

SUBSTANCE, SOLID, N.O.S. (Zinc 

powder - zinc dust (stabilized), zinc 

oxide)

9 III

Additional information

-

IMDG 3077 ENVIRONMENTALLY HAZARDOUS 

SUBSTANCE, SOLID, N.O.S. (Zinc 

powder - zinc dust (stabilized), zinc 

oxide). Marine pollutant (Zinc 

powder - zinc dust (stabilized), zinc 

oxide)

9 III -

DOT Reportable quantity

1041.7 lbs / 472.92 kg

Package sizes shipped in 

quantities less than the 

product reportable quantity 

are not subject to the RQ 

(reportable quantity)

transportation requirements.

3077 ENVIRONMENTALLY HAZARDOUS 9

SUBSTANCE, SOLID, N.O.S. (Zinc 

powder - zinc dust (stabilized), zinc 

oxide)

III

CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs.

(454 kg);

Reportable quantity RQ :

PG* : Packing group

United States - Canada - Mexico Page: 5/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

15 . Regulatory information

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.

United States inventory (TSCA 8b) : All components are listed or exempted.

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

New Zealand ( NZIoC ) :

Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this 

material.

United States

U.S. Federal regulations :

SARA 313

CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg);

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which 

can be obtained from your PPG representative.

SARA 302/304: No products were found.

Supplier notification : Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100

zinc oxide 1314-13-2 1 - 5

SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification:

zinc oxide 1314-13-2 N N N N N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : N N N Y N

Chemical name

WHMIS (Canada) : None identified.

Canada

Mexico

Flammability 0 Health 1 Reactivity 1

Classification

: : :

Other information

Hazardous Material Information System (U.S.A.)

0

0 1

National Fire Protection Association (U.S.A.)

Health Flammability Instability

Health Flammability Physical hazards

Disclaimer

Date of previous issue : 12/22/2012.

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 

representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.

1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® 

program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may 

be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that prepared 

the MSDS

: EHS

: : :

: 1 : :

1

1

( * ) - Chronic 

effects

United States - Canada - Mexico Page: 6/7
Product name DIMETCOTE 9/D9VOC/D9H POWDER

Product code DI9-P Date of issue 26 May 2013 Version 19

16 . Other information

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this 

information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to 

recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in 

respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary 

measures described in this data sheet or for any misuse of the products.

United States - Canada - Mexico Page: 7/7
Jotamastic 80 Std Comp B

5660

Coatings: Hardener for resins.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Jotamastic 80 Std Comp B

:

:

:

:

:

1 .

Hazards identification

May give off gas, vapor or dust that is very irritating or corrosive to the respiratory

system. Exposure to decomposition products may cause a health hazard. Serious

effects may be delayed following exposure.

May cause eye irritation.

May cause burns to mouth, throat and stomach.

Corrosive to the skin. Causes burns.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

DANGER!

COMBUSTIBLE LIQUID AND VAPOR. CAUSES SKIN BURNS. CONTAINS

MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL

DATA.

Combustible liquid. Corrosive to the skin. Causes burns. Keep away from heat, sparks

and flame. Do not breathe vapor or mist. Do not get in eyes or on skin or clothing.

Contains material that may cause target organ damage, based on animal data. Use only

with adequate ventilation. Keep container tightly closed and sealed until ready for use.

Wash thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at

risk may be aggravated by over-exposure to this product.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

benzyl alcohol 100-51-6 25 - 50

3-aminomethyl-3,5,5-trimethylcyclohexylamine 2855-13-2 10 - 25

Composition/information on ingredients

Name CAS number % by weight

3 .

Continued on next page
Jotamastic 80 Std Comp B Page: 2/7

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it

is suspected that fumes are still present, the rescuer should wear an appropriate

mask or self-contained breathing apparatus. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing

thoroughly with water before removing it, or wear gloves.

4 .

May be combustible at high temperature.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

nitrogen oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool.

Combustible liquid. In a fire or if heated, a pressure increase will occur and the

container may burst, with the risk of a subsequent explosion.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air).

Personal precautions :

Methods for cleaning up :

6 .

Continued on next page
Jotamastic 80 Std Comp B Page: 3/7

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapor or

mist. Do not ingest. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

benzyl alcohol AIHA WEEL (United States, 10/2011).

 TWA: 10 ppm 8 hour(s).

Exposure controls/personal protection

Product name Exposure limits

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

8 .

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Continued on next page
Jotamastic 80 Std Comp B Page: 4/7

Liquid.

1.04 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Yellowish-brown.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 0 % (w/w) [ISO % 11890-2]

:

:

:

:

:

:

Flash point : Closed cup: 80°C (176°F)

9 .

8.68 pounds/gallon

2.28 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects No known significant effects or critical hazards.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects Contains material that may cause target organ damage, based on animal data.

Target organs Contains material which may cause damage to the following organs: skin, eyes.

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

Contains aminepoxyadduct, 3-aminomethyl-3,5,5-trimethylcyclohexylamine. May

produce an allergic reaction.

Chronic effects on humans Contains material which may cause damage to the following organs: skin, eyes.

Other toxic effects on

humans

:

:

:

:

:

:

:

11 .

Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2

etc.).

Ecological information

Products of degradation

Ecotoxicity data

benzyl alcohol Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

10 mg/l

460 mg/l

3-aminomethyl-3,5,5-

trimethylcyclohexylamine

Daphnia magna (EC50)

Daphnia (EC50)

Algae (IC50)

48 hour(s)

24 hour(s)

72 hour(s)

17.4 mg/l

44 mg/l

37 mg/l

Product/ingredient name Species Period Result

:

Environmental precautions : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

12 .

Continued on next page
Jotamastic 80 Std Comp B Page: 5/7

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

:

13 .

Transport information

DOT Classification 8 -

TDG Classification 8

Polyamines, liquid,

corrosive, n.o.s. (3-

aminomethyl-3,5,5-

trimethylcyclohexylamine)

III

2735 Polyamines, liquid,

corrosive, n.o.s. (3-

aminomethyl-3,5,5-

trimethylcyclohexylamine)

III

ADR/RID Class Polyamines, liquid,

corrosive, n.o.s. (3-

aminomethyl-3,5,5-

trimethylcyclohexylamine)

8 III

 

IMDG Class Polyamines, liquid,

corrosive, n.o.s. (3-

aminomethyl-3,5,5-

trimethylcyclohexylamine).

Marine pollutant

(aminepoxyadduct)

8 III

 

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

2735

2735

Tunnel restriction

code: (E)

Hazard identification

number: 80

Emergency schedules

(EmS): F-A, S-B

Marine pollutant: Yes.

2735

-

 

14 .

Continued on next page
Jotamastic 80 Std Comp B Page: 6/7

14 . Transport information

-

Polyamines, liquid,

corrosive, n.o.s. (3-

aminomethyl-3,5,5-

trimethylcyclohexylamine)

IATA-DGR Class 2735

 

8 III -

PG* : Packing group

The environmental hazardous / marine pollutant mark is only applicable for

packages containing more than 5 litres for liquids and 5 kg for solids.

Marking :

Combustible liquid

Corrosive material

Target organ effects

HCS Classification

Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: BENZYL ALCOHOL

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed:

ISOPHORONEDIAMINE; CYCLOHEXANEMETHANAMINE, 5-AMINO-1,3,3-

TRIMETHYLNew Jersey Spill: None of the components are listed.

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: None of the components are listed.

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

BENZENEMETHANOL

Rhode Island Hazardous Substances: None of the components are listed.

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: 3-aminomethyl-3,5,5-

trimethylcyclohexylamine; benzyl alcohol

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: 3-

aminomethyl-3,5,5-trimethylcyclohexylamine: Immediate (acute) health hazard; benzyl

alcohol: Immediate (acute) health hazard, Delayed (chronic) health hazard

:

:

:

EU regulations

15 .

Continued on next page
Jotamastic 80 Std Comp B Page: 7/7

15 . Regulatory information

S23- Do not breathe vapor / spray.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show

the label where possible).

S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

R20/22- Harmful by inhalation and if swallowed.

R34- Causes burns.

R43- May cause sensitization by skin contact.

R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Risk phrases

Safety phrases

:

:

Hazard symbol or symbols :

Corrosive Dangerous for the

environment

Other information

Hazardous Material

Information System (U.S.A.)

0

0

3

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

COMBUSTIBLE LIQUID AND VAPOR. CAUSES SKIN BURNS. CONTAINS MATERIAL

THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

Label requirements :

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

20.02.2013.

: 4.04

:

:

:

16 .

Indicates information that has changed from previously issued version.

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

3

2

0

Health
Barrier AV - Comp. A

MM00001131

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.

9203 Highway 23

Belle Chasse, LA 70037

Telephone: (800) 229-3538 or

(504) 394-3538

SDSJotun@jotun.com

Material Safety Data Sheet

Trade name

Material uses

Manufacturer

Code

In case of emergency

Product and company identification

Barrier AV - Comp. A

:

:

:

:

:

1 .

Hazards identification

No known significant effects or critical hazards.

May cause eye irritation.

Harmful if swallowed.

Harmful in contact with skin. May cause skin irritation.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (Section 11)

WARNING!

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET

ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS

MATERIAL WHICH CAN CAUSE CANCER.

Flammable liquid. May be harmful if absorbed through skin or if swallowed. Keep away

from heat, sparks and flame. Avoid exposure - obtain special instructions before use.

Do not breathe vapor or mist. Do not ingest. Do not get in eyes. Avoid contact with skin

and clothing. Contains material that may cause target organ damage, based on animal

data. Contains material which can cause cancer. Risk of cancer depends on duration

and level of exposure. Use only with adequate ventilation. Keep container tightly closed

and sealed until ready for use. Wash thoroughly after handling.

:

:

:

:

:

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A4 (Not classifiable

for humans or animals.) by ACGIH [zinc oxide]. Classified 1 (Proven for humans.) by

IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified

A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].

Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for

humans.) by IARC [propan-2-ol].

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

Medical conditions

aggravated by overexposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being at

risk may be aggravated by over-exposure to this product.

Potential chronic health

effects

:

:

Odor : Characteristic.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

2 .

Continued on next page
Barrier AV - Comp. A Page: 2/11

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication

Standard).

barium sulfate 7727-43-7 10 - 25

heptan-2-one 110-43-0 2.5 - 10

xylene 1330-20-7 2.5 - 10

butanone 78-93-3 2.5 - 10

zinc oxide 1314-13-2 1 - 2.5

ethanol 64-17-5 1 - 2.5

ethylbenzene 100-41-4 0 - 1

Composition/information on ingredients

Name CAS number % by weight

3 .

Wash out mouth with water. Do not induce vomiting unless directed to do so by

medical personnel. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of

water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get

medical attention immediately.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes

while removing contaminated clothing and shoes. Wash clothing before reuse.

Clean shoes thoroughly before reuse. Get medical attention immediately.

Move exposed person to fresh air. If not breathing, if breathing is irregular or if

respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention

immediately.

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it

is suspected that fumes are still present, the rescuer should wear an appropriate

mask or self-contained breathing apparatus. It may be dangerous to the person

providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing

thoroughly with water before removing it, or wear gloves.

4 .

May be combustible at high temperature.

Decomposition products may include the following materials:

carbon dioxide

carbon monoxide

sulfur oxides

metal oxide/oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Flammability of the product

Products of combustion

Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. No action shall be taken involving any personal risk or without suitable

training. Move containers from fire area if this can be done without risk. Use water

spray to keep fire-exposed containers cool. Fire water contaminated with this material

must be contained and prevented from being discharged to any waterway, sewer or

drain.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the container

may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or

explosion hazard.

Special protective

equipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

:

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Continued on next page
Barrier AV - Comp. A Page: 3/11

No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide

adequate ventilation. Wear appropriate respirator when ventilation is inadequate.

Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from

upwind. Prevent entry into sewers, water courses, basements or confined areas.

Wash spillages into an effluent treatment plant or proceed as follows. Contain and

collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite

or diatomaceous earth and place in container for disposal according to local

regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

Dispose of via a licensed waste disposal contractor. Contaminated absorbent

material may pose the same hazard as the spilled product. Note: see section 1 for

emergency contact information and section 13 for waste disposal.

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental

pollution (sewers, waterways, soil or air). Water polluting material. May be harmful

to the environment if released in large quantities.

Personal precautions :

Methods for cleaning up :

6 .

Store in accordance with local regulations. Store in a segregated and approved

area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and

drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep

container tightly closed and sealed until ready for use. Containers that have been

opened must be carefully resealed and kept upright to prevent leakage. Do not store

in unlabeled containers. Use appropriate containment to avoid environmental

contamination.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking

and smoking should be prohibited in areas where this material is handled, stored and

processed. Workers should wash hands and face before eating, drinking and

smoking. Remove contaminated clothing and protective equipment before entering

eating areas. Avoid exposure - obtain special instructions before use. Do not get in

eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid

release to the environment. Use only with adequate ventilation. Wear appropriate

respirator when ventilation is inadequate. Do not enter storage areas and confined

spaces unless adequately ventilated. Keep in the original container or an approved

alternative made from a compatible material, kept tightly closed when not in use.

Store and use away from heat, sparks, open flame or any other ignition source. Use

explosion-proof electrical (ventilating, lighting and material handling) equipment.

Use non-sparking tools. Take precautionary measures against electrostatic

discharges. To avoid fire or explosion, dissipate static electricity during transfer by

grounding and bonding containers and equipment before transferring material.

Empty containers retain product residue and can be hazardous. Do not reuse

container.

Handling and storage

Handling

Storage

:

:

7 .

barium sulfate ACGIH TLV (United States, 2/2010).

 TWA: 10 mg/m3 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction

 TWA: 10 mg/m3 8 hour(s). Form: Total dust

NIOSH REL (United States, 6/2009).

 TWA: 5 mg/m3 10 hour(s). Form: Respirable fraction

 TWA: 10 mg/m3 10 hour(s). Form: Total

Exposure controls/personal protection

Product name Exposure limits

8 .

Continued on next page
Barrier AV - Comp. A Page: 4/11

8 . Exposure controls/personal protection

OSHA PEL (United States, 6/2010).

 TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction

 TWA: 15 mg/m3 8 hour(s). Form: Total dust

heptan-2-one ACGIH TLV (United States, 2/2010).

 TWA: 50 ppm 8 hour(s).

 TWA: 233 mg/m3 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 465 mg/m3 8 hour(s).

NIOSH REL (United States, 6/2009).

 TWA: 100 ppm 10 hour(s).

 TWA: 465 mg/m3 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 100 ppm 8 hour(s).

 TWA: 465 mg/m3 8 hour(s).

xylene ACGIH TLV (United States, 1/2009).

 STEL: 651 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 434 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL (United States, 11/2006).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 STEL: 655 mg/m3 15 minute(s).

 STEL: 150 ppm 15 minute(s).

 TWA: 435 mg/m3 8 hour(s).

 TWA: 100 ppm 8 hour(s).

butanone OSHA PEL 1989 (United States, 3/1989).

 TWA: 200 ppm 8 hour(s).

 TWA: 590 mg/m3 8 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

ACGIH TLV (United States, 2/2010).

 TWA: 200 ppm 8 hour(s).

 TWA: 590 mg/m3 8 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2009).

 TWA: 200 ppm 10 hour(s).

 TWA: 590 mg/m3 10 hour(s).

 STEL: 300 ppm 15 minute(s).

 STEL: 885 mg/m3 15 minute(s).

OSHA PEL (United States, 6/2010).

 TWA: 200 ppm 8 hour(s).

 TWA: 590 mg/m3 8 hour(s).

zinc oxide NIOSH REL (United States, 6/2009).

 CEIL: 15 mg/m3 Form: Dust

 TWA: 5 mg/m3 10 hour(s). Form: Dust and fumes

 STEL: 10 mg/m3 15 minute(s). Form: Fume

OSHA PEL (United States, 6/2010).

 TWA: 5 mg/m3 8 hour(s). Form: Fume

 TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction

 TWA: 15 mg/m3 8 hour(s). Form: Total dust

OSHA PEL 1989 (United States, 3/1989).

 STEL: 10 mg/m3 15 minute(s). Form: Fume

 TWA: 5 mg/m3 8 hour(s). Form: Fume

 TWA: 5 mg/m3 8 hour(s). Form: Respirable fraction

 TWA: 10 mg/m3 8 hour(s). Form: Total dust

ACGIH TLV (United States, 2/2010).

Continued on next page
Barrier AV - Comp. A Page: 5/11

8 . Exposure controls/personal protection

 STEL: 10 mg/m3 15 minute(s). Form: Respirable fraction

 TWA: 2 mg/m3 8 hour(s). Form: Respirable fraction

ethanol ACGIH TLV (United States, 2/2010).

 STEL: 1000 ppm 15 minute(s).

NIOSH REL (United States, 6/2009).

 TWA: 1900 mg/m3 10 hour(s).

 TWA: 1000 ppm 10 hour(s).

OSHA PEL (United States, 6/2010).

 TWA: 1900 mg/m3 8 hour(s).

 TWA: 1000 ppm 8 hour(s).

OSHA PEL 1989 (United States, 3/1989).

 TWA: 1900 mg/m3 8 hour(s).

 TWA: 1000 ppm 8 hour(s).

ethylbenzene OSHA PEL 1989 (United States, 3/1989).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

NIOSH REL (United States, 6/2008).

 TWA: 100 ppm 10 hour(s).

 TWA: 435 mg/m3 10 hour(s).

 STEL: 125 ppm 15 minute(s).

 STEL: 545 mg/m3 15 minute(s).

OSHA PEL (United States, 11/2006).

 TWA: 100 ppm 8 hour(s).

 TWA: 435 mg/m3 8 hour(s).

ACGIH TLV (United States, 1/2008). Notes: K

 TWA: 100 ppm 8 hour(s). Form:

 STEL: 125 ppm 15 minute(s). Form:

Use a properly fitted, air-purifying or air-fed respirator complying with an approved

standard if a risk assessment indicates this is necessary. Respirator selection must be

based on known or anticipated exposure levels, the hazards of the product and the safe

working limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a risk

assessment indicates this is necessary to avoid exposure to liquid splashes, mists or

dusts.

Personal protective equipment for the body should be selected based on the task being

performed and the risks involved and should be approved by a specialist before handling

this product.

Eyes

Skin

Respiratory

:

:

:

Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is

necessary.

Hands :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or

other engineering controls to keep worker exposure to airborne contaminants below any

recommended or statutory limits. The engineering controls also need to keep gas, vapor

or dust concentrations below any lower explosive limits. Use explosion-proof ventilation

equipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before

eating, smoking and using the lavatory and at the end of the working period. Appropriate

techniques should be used to remove potentially contaminated clothing. Wash

contaminated clothing before reusing. Ensure that eyewash stations and safety showers

are close to the workstation location.

Continued on next page
Barrier AV - Comp. A Page: 6/11

Liquid.

2.2 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.

Various colors.

Physical and chemical properties

Physical state

Relative density

Solubility

Odor

Color

VOC 14,7 % (w/w) [ISO 11890-1]

:

:

:

:

:

:

Flash point : Closed cup: 30°C (86°F)

9 .

18.36 pounds/gallon

2.7 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not

occur.

Under normal conditions of storage and use, hazardous decomposition products

should not be produced.

Stability and reactivity

Stability and reactivity

Hazardous decomposition

products

Hazardous polymerization

:

:

:

10 .

Toxicological information

Specific effects

Carcinogenic effects Contains material which can cause cancer. Risk of cancer depends on duration and

level of exposure.

Mutagenic effects No known significant effects or critical hazards.

Reproduction toxicity No known significant effects or critical hazards.

Chronic effects Contains material that may cause target organ damage, based on animal data.

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the nervous system, the reproductive system, liver, peripheral nervous

system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or

cornea, nose/sinuses, throat.

Target organs

Exposure to component solvent vapor concentrations in excess of the stated

occupational exposure limit may result in adverse health effects such as mucous

membrane and respiratory system irritation and adverse effects on the kidneys, liver

and central nervous system. Solvents may cause some of the above effects by

absorption through the skin. Symptoms and signs include headache, dizziness,

fatigue, muscular weakness, drowsiness and, in extreme cases, loss of

consciousness. Repeated or prolonged contact with the preparation may cause

removal of natural fat from the skin, resulting in non-allergic contact dermatitis and

absorption through the skin. If splashed in the eyes, the liquid may cause irritation

and reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastrointestinal irritation and chemical pneumonia.

Contains epoxy resin (MW 700-1200), Phenol, methylstyrenated, hydrocarbons, c9-

unsatd., polymd.. May produce an allergic reaction.

CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)

by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A4 (Not

classifiable for humans or animals.) by ACGIH [zinc oxide]. Classified 1 (Proven for

humans.) by IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH

[ethanol]. Classified A3 (Proven for animals.) by ACGIH, 2B (Possible for humans.)

by IARC [ethylbenzene]. Classified A4 (Not classifiable for humans or animals.) by

ACGIH, 3 (Not classifiable for humans.) by IARC [propan-2-ol].

Contains material which may cause damage to the following organs: blood, kidneys,

lungs, the nervous system, the reproductive system, liver, peripheral nervous

system, upper respiratory tract, skin, central nervous system (CNS), eye, lens or

cornea, nose/sinuses, throat.

Chronic effects on humans

Other toxic effects on

humans

:

:

:

:

:

:

:

11 .

Continued on next page
Barrier AV - Comp. A Page: 7/11

Products of degradation: carbon oxides (CO, CO2) and water, sulfur oxides (SO2, SO3

etc.). Some metallic oxides.

Ecological information

Products of degradation

Ecotoxicity data

barium sulfate Daphnia magna (EC50) 48 hour(s) 32 mg/l

heptan-2-one Pimephales promelas (LC50) 96 hour(s) 131 mg/l

xylene Oncorhynchus mykiss (LC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

3.3 mg/l

8.2 mg/l

8.6 mg/l

12 mg/l

13.3 mg/l

13.4 mg/l

butanone Daphnia magna (EC50)

Pimephales promelas (LC50)

48 hour(s)

96 hour(s)

5091 mg/l

3220 mg/l

zinc oxide Daphnia magna (EC50)

Oncorhynchus mykiss (LC50)

Lepomis macrochirus (LC50)

Pimephales promelas (LC50)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

>1000 mg/l

1.1 mg/l

>320 mg/l

2246 mg/l

ethanol Daphnia magna (EC50)

Daphnia magna (EC50)

Daphnia magna (EC50)

Daphnia magna (LC50)

Pimephales promelas (LC50)

Oncorhynchus mykiss (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2 mg/l

9.3 mg/l

>100 mg/l

>100 mg/l

>100 mg/l

13000 mg/l

ethylbenzene Daphnia magna (EC50)

Daphnia magna (EC50)

Selenastrum capricornutum

(EC50)

Oncorhynchus mykiss (LC50)

Pimephales promelas (LC50)

Poecilia reticulata (LC50)

48 hour(s)

48 hour(s)

48 hour(s)

96 hour(s)

96 hour(s)

96 hour(s)

2.93 mg/l

2.97 mg/l

7.2 mg/l

4.2 mg/l

9.09 mg/l

9.6 mg/l

Product/ingredient name Species Period Result

:

Environmental precautions : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Water polluting material. May be harmful to the environment if released in

large quantities.

12 .

The generation of waste should be avoided or minimized wherever possible. Significant

quantities of waste product residues should not be disposed of via the foul sewer but

processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Disposal of this product, solutions

and any by-products should at all times comply with the requirements of environmental

protection and waste disposal legislation and any regional local authority requirements.

Waste packaging should be recycled. Incineration or landfill should only be considered

when recycling is not feasible. This material and its container must be disposed of in a

safe way. Care should be taken when handling emptied containers that have not been

cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

inside the container. Do not cut, weld or grind used containers unless they have been

cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact

with soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local

regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on

characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the

responsibility of the waste generator to determine the toxicity and physical properties of the material generated to

determine the proper waste identification and disposal methods in compliance with applicable regulations.

:

13 .

Continued on next page
Barrier AV - Comp. A Page: 8/11

13 . Disposal considerations

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

for additional handling information and protection of employees.

-

Transport information

3 -

 

DOT Classification

TDG Classification 3

Paint. Marine

pollutant (barium

sulfate)

III

1263 Paint III

ADR/RID Class Paint 3 III

 

IMDG Class Paint. Marine

pollutant (zinc)

3 III

 

IATA-DGR Class 1263 Paint

 

3

Regulatory

information

UN number Proper shipping

name

Class PG* Label Additional

information

III

1263

1263

Tunnel restriction

code: (D/E)

Hazard identification

number: 30

Special provisions:

640E

Emergency schedules

(EmS): F-E, S-E

Marine pollutant: Yes.

-

1263

-

PG* : Packing group

 

The environmental hazardous / marine pollutant mark is only applicable for

packages containing more than 5 litres for liquids and 5 kg for solids.

Marking :

14 .

Continued on next page
Barrier AV - Comp. A Page: 9/11

Flammable liquid

Carcinogen

Target organ effects

HCS Classification

Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: None of the components are listed.

Connecticut Hazardous Material Survey: None of the components are listed.

Florida substances: None of the components are listed.

Illinois Chemical Safety Act: None of the components are listed.

Illinois Toxic Substances Disclosure to Employee Act: None of the components are

listed.

Louisiana Reporting: None of the components are listed.

Louisiana Spill: None of the components are listed.

Massachusetts Spill: None of the components are listed.

Massachusetts Substances: The following components are listed: ETHYL ALCOHOL;

ZINC OXIDE FUME; ZINC; BARIUM SULFATE; METHYL ETHYL KETONE (MEK);

XYLENE; METHYL (N-AMYL) KETONE

Michigan Critical Material: None of the components are listed.

Minnesota Hazardous Substances: None of the components are listed.

New Jersey Hazardous Substances: The following components are listed: ETHYL

ALCOHOL; ALCOHOL; ZINC OXIDE; ZINC; barium sulfate; METHYL ETHYL KETONE;

2-BUTANONE; XYLENES; BENZENE, DIMETHYL-; ethylbenzene; METHYL n-AMYL

KETONE; 2-HEPTANONE

New Jersey Spill: None of the components are listed.

TSCA 4(a) final test rules: 4-methylpentan-2-one

TSCA 6 proposed risk management: lead

TSCA 8(a) IUR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): Not determined.

Clean Water Act (CWA) 307: zinc oxide; zinc; lead; cadmium

Clean Air Act (CAA) 112 accidental release prevention: No products were found.

State regulations

SARA 302/304/311/312 extremely hazardous substances: No products were found.

SARA 302/304 emergency planning and notification: No products were found.

SARA 302/304/311/312 hazardous chemicals: xylene; heptan-2-one; butanone; barium

sulfate; zinc; zinc oxide; ethanol

SARA 311/312 MSDS distribution - chemical inventory - hazard identification:

xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;

heptan-2-one: Fire hazard, Immediate (acute) health hazard; butanone: Fire hazard,

Immediate (acute) health hazard, Delayed (chronic) health hazard; barium sulfate:

Immediate (acute) health hazard; zinc: Fire hazard, Immediate (acute) health hazard,

Delayed (chronic) health hazard; zinc oxide: Immediate (acute) health hazard, Delayed

(chronic) health hazard; ethanol: Fire hazard, Immediate (acute) health hazard, Delayed

(chronic) health hazard

:

:

SARA 313

:

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

15 .

zinc 7440-66-6 25 - 50

xylene 1330-20-7 2.5 - 10

butanone 78-93-3 2.5 - 10

zinc oxide 1314-13-2 1 - 2.5

ethylbenzene 100-41-4 0 - 1

propan-2-ol 67-63-0 0 - 1

lead 7439-92-1 0 - 1

zinc 7440-66-6 25 - 50

xylene 1330-20-7 2.5 - 10

butanone 78-93-3 2.5 - 10

zinc oxide 1314-13-2 1 - 2.5

ethylbenzene 100-41-4 0 - 1

Form R - Reporting

requirements

Supplier notification

:

:

Continued on next page
Barrier AV - Comp. A Page: 10/11

15 . Regulatory information

New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.

New York Acutely Hazardous Substances: The following components are listed: Zinc;

2-Butanone; Xylene (mixed); Ethylbenzene

New York Toxic Chemical Release Reporting: None of the components are listed.

Pennsylvania RTK Hazardous Substances: The following components are listed:

DENATURED ALCOHOL; ZINC OXIDE (ZNO); ZINC; BARIUM SULFATE; 2-

BUTANONE; BENZENE, DIMETHYL-; ethylbenzene; 2-HEPTANONE

Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause

cancer.

WARNING: This product contains less than 1% of a chemical known to the State of

California to cause birth defects or other reproductive harm.

ethanol Yes. No. No. No.

ethylbenzene Yes. No. No. No.

lead Yes. Yes. 15 μg/day (ingestion) Yes.

silica, crystalline - quartz Yes. No. No. No.

cadmium Yes. Yes. 0.05 μg/day

(inhalation)

4.1 μg/day (ingestion)

Ingredient name Cancer Reproductive No significant risk

level

Maximum

acceptable dosage

level

S23- Do not breathe vapor / spray.

S24- Avoid contact with skin.

S37- Wear suitable gloves.

S38- In case of insufficient ventilation, wear suitable respiratory equipment.

S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

R10- Flammable.

R43- May cause sensitization by skin contact.

R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Risk phrases

EU regulations

Safety phrases

:

:

Hazard symbol or symbols :

Irritant Dangerous for the

environment

Other information

Hazardous Material

Information System (U.S.A.)

0

3

1

National Fire Protection

Association (U.S.A.)

Health

Special

Instability

Flammability

FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH

SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET

ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS

MATERIAL WHICH CAN CAUSE CANCER.

Label requirements :

:

:

16 .

Health

Flammability

Physical hazards

PERSONAL PROTECTION G

0

0

0

Health

Continued on next page
Barrier AV - Comp. A Page: 11/11

16 . Other information

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the

information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present

unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot

guarantee that these are the only hazards that exist.

Date of issue

Version

06.11.2012.

: 2.01

:

Indicates information that has changed from previously issued version.
Confonns to Regulation (EC) No. 1907/2006 (REACH), Annex II- United Kingdom (UK) 

SAFETY DATA SHEET 

Jotun Anti-skid 

SECTION 1: Identification of the substance/mixture and of the 

company/undertaking 

1.1 Product identifier 

Product name 

EC number 

CAS number 

Product code 

Product description 

Product type 

Other means of 

Identification 

Jotun Anti-skid 

215-691-6 

1344-28-1 

545 

Coatings: Powder. 

Solid. 

Not available. 

1.2 Relevant Identified uses of the substance or mixture and uses advised against 

Not applicable. 

1.3 Details of the supplier of the safety data sheet 

Jotun Paints (Europe) Ltd. 

Stather Road 

Flixborough, Scunthorpe 

North Lincolnshire 

DN15 8RR 

England 

Tel: +44 17 24 40 00 00 

Fax: +44 17 24 40 01 00 

SDSJotun@jotun.com 

1.4 Emergency telephone number 

Contact National Poison Centre via Hospital or Registered Medical Practitioner 

I SECTION 2: Hazards identification 

2.1 Classification of the substance or mixture 

Product definition : Mono-constituent substance 

Classjficatjon according to Regulation lEC) No. 1272/2008 rCLPJGHSl 

Not classified. 

Classification according to D!rectjye 6V548/EEC rpsrn 

Not classified. 

Sea Section 16 for the full text of the R phrases or H statements declared above. 

See Section 11 for more detaUed Information on health effects and symptoms. 

2.2 Label elements 

Hazard plctograms 

Signal word 

Hazard statements 

Precautlonarv statements 

Prevention 

Response 

Storage 

Disposal 

Supplemental label 

elements 

j Date of issue 

No signal word. 

No known significant effects or critical hazards. 

Do not breathe dust. 

Not applicable. 

Not applicable. 

Not applicable. 

Not applicable. 

20.05.2011 . 
SECTION 2: Hazards Identification 

2.3 Other hazards 

Substance meets the No. 

criteria for PBT according P: Not available. B: Not available. T: No. to Regulation (EC) No. 

1907/2006, Annex XIII 

Substance meets the Not available. 

c::rlteria for vPvB according 

to Regulation (EC} No. 

1907/2006, Annex XIII 

Other hazards which do not Not available. 

result In classification 

I SECTION 3: Composition/information on ingredients 

Substance/mixture : Mono-constituent substance 

Classjficatjon 

Product/Ingredient Identifiers o/o 67/548/EEC Regulation (EC) No. Type Notes 

name 1272/2008 [CLP) 

alumina REACH#: 01- 50- Not classified. Not classified. (A) 

2119529248-35 100 

EC: 215-691-6 

CAS: 1344-28-1 

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and 

contribute to the classification of the substance and hence require reporting In this section. 

Uwl 

[A] Constituent 

[B) Impurity 

[C) Stabllfsing additive 

Occupational exposure limits, if available, are listed in Section 8. 

I SECTION 4: First aid measures 

4.1 Description of first aid measures 

. 

General In all cases of doubt, or when symptoms persist, seek medical attention. Never give 

anything by mouth to an unconscious person. If unconscious, place in recovery 

position and seek medical advice. 

Inhalation Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing Is 

Skin contact 

Eye contact 

Ingestion 

Protection of first-alders 

irregular or if respiratory arrest occurs, provide artlflclal respiration or oxygen by 

trained personnel. 

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water 

or use recognised skin cleanser. Do NOT use solvents or thinners. 

Check for and remove any contact lenses. Immediately flush eyes with running water 

for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. 

If swallowed, seek medical advice immediately and show the container or label. Keep 

person warm and at rest. Do notinduce vomiting. 

No action shall be taken Involving any personal rlsk or without suitable training. 

4.2 Most important symptoms and effects, both acute and delayed 

Potgntjal acute heaHh gfftcts 

Eye contact 

Inhalation 

Skin contact 

Ingestion 

No known significant effects or critical hazards. 

No known significant effects or critical hazards. 

No known signfflcant effects or critical hazards. 

No known significant effects or critical hazards. 

Over-excosure sjgns/symotoms 

Eye contact No specific data. 

Inhalation : No specific data. 

I Date of Issue : 20.05.2011 . 2/91 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex D • United Kingdom (UK) 

Jotun Anti-skid (MM·WCS) 

SECTION 4: First aid measures 

Skin contact 

Ingestion 

No specific data. 

: No specific data. 

4.3 Indication of any Immediate medical attention and special treatment needed 

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if farge 

quantities have been ingested or Inhaled. 

Specific treatments No specific treatment. 

j SECTION 5: Firefighting measures 

5.1 Extinguishing media 

Suitable extinguishing 

media 

Unsuitable extinguishing 

media 

Recommended: alcohol-resistant foam, C02 blanket, water spray or mist. 

Do not use water jet. 

Do not use inert gas under high pressure (e.g. C02}. 

5.2 Special hazards arising from the substance or mixture 

Hazards from the 

substance or mixture 

Hazardous thermal 

decomposition products 

5.3 Advice for firefighters 

Special protective actions 

for fire-fighters 

Special protective 

equipment for fire-fighters 

No specific fire or explosion hazard. 

Decomposition products may Include the following materials: 

metal oxide/oxides 

PrompOy isolate the scene by removing all persons from the vicinity of the incident if 

there is a fire. No action shalf be taken involving any personal risk or without suitable 

training. 

Fire-fighters should wear appropriate protective equipment and self-contained 

breathing apparatus {SCBA) with a tuff face-piece operated in positive pressure 

mode. Clothing for fire-fJQhters (including helmets, protective boots and gloves) 

conforming to European standard EN 469 will provide a basic level of protection for 

chemical Incidents. 

I SECTION 6: Accidental release measures 

6.1 Personal precautions, protective equipment and emergency procedures 

For non-emergency No action shall be taken involving any personal risk or without suitable training. 

personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from 

entering. Do not touch or walk through spilt material. Put on appropriate personal 

protective equipment. 

For emergency responders If specialised clothing is required to deal with the spillage, take note of any information 

in Section 8 on suitable and unsuitable materials. See also the information In "For 

non-emergency personnel". 

6.2 Environmental 

precautions 

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains 

and sewers. Inform the relevant authorities if the product has caused environmental 

pollution {sewers, waterways, soil or air). 

6.3 Methods and materials for containment and cleaning up 

Small spill Move containers from spnl area. Vacuum or sweep up material and place in a 

designated, labelled waste container. Dispose of via a licensed waste disposal 

contractor. 

Large spill 

I Date of Issue 

Move containers from spill area. Prevent entry into sewers, water courses, 

basements or confined areas. Vacuum or sweep up material and place In a 

designated, labelled waste container. Dispose of via a licensed waste disposal 

contractor. Note: see section 1 for emergency contact information and section 13 for 

waste disposal. 

: 20.05.2011. 

I 

I 
Conforms to Regulatlon_(EC) No. 1907/2006 {REACH), Annex U - United Kll!gdom (UK) 

Jotun Anti-skid (MM-WCS) 

SECTION 6: Accidental release measures 

6.4 Reference to other 

sections 

See Section 1 for emergency contact information. 

See Section 8 for information on appropriate personal protective equipment. 

See Section 13 for additional waste treatment Information. 

I SECTION 7: Handling and storage 

The Information In this section contains generic advice and guidance. The Jist of Identified Uses in Section 1 should be 

consulted for any available use-specific information provided in the Exposure Scenarlo(s). 

7.1 Precautions for safe handling 

Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or 

occupational exposure limits. 

Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with 

hot surfaces, sparks or other ignition sources. 

To dissipate static electricity during transfer, earth drum and connect to receiving container with bonding strap. Operators 

should wear antistatic footwear and clothing and floors should be of the conducting type. 

Keep away from heat, sparks and flame. 

Avoid contact with skin and eyes. Avoid the Inhalation of dust, particulates, spray or mist arising from the application of 

this preparation. Avoid inhalation of dust from sanding. 

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. 

Put on appropriate personal protective equipment (see Section 8). 

Always keep in containers made from the seme material as the original one. 

Comply with the health and safety at work laws. 

7.2 Conditions for safe storage, Including any Incompatibilities 

Store in accordance with local regulations. 

Additional Information on storage conditions 

Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. 

Keep container tightly closed. 

Keep away from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must 

be carefully resealed and kept upright to prevent leakage. 

7.3 Specific end use(s) 

Recommendations 

Industrial sector specific 

solutions 

Not available. 

Not available. 

I SECTION 8: Exposure controls/personal protection 

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be 

consulted for any available use-specific information provided in the Exposure Scenario(s). 

8.1 Control parameters 

Occuoatlonal exoosure limits 

Product/ingredient name Exposure limit values 

alumina 

Recommended monitoring 

procedures 

oer!yed effect layels 

No DEls available. 

EH40/2005 WELs (United Kingdom (UK), 8/2007). 

TWA: 10 mg/m5 8 hour(s). Form: inhalable dust 

If this product contains ingredients with exposure limits, personal, workplace 

atmosphere or biological monitoring may be required to determine the effectiveness 

of the ventilation or other control measures and/or the necessity to use respiratory 

protective equipment. Reference should be made to European Standard EN 689 for 

methods for the assessment of exposure by Inhalation to chemical agents and 

national guidance documents for methods for the determination of hazardous 

substances. 

Predicted effect cgncentratlgns 

No PECs available. 

I Date of Issue 20.05.2011. 

I 

I 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II- United Kingdom (UK) 

Jotun Anti-skid (MM·WCS) I 

SECTION 8: Exposure controls/personal protection 

8.2 Exposure controls 

Appropriate engineering 

controls 

lndlyldua! protection measures 

No special ventilation requirements. Good general ventilation should be sufficient to 

control worker exposure to airborne contaminants. If this product contains 

Ingredients with exposure limits, use process enclosures, local exhaust ventilation or 

other engineering controls to keep worker exposure below any recommended or 

statutory limits. 

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before 

eating, smoking and using the lavatory and at the end of the working period. 

Appropriate techniques should be used to remove potentially contaminated clothing. 

Wash contaminated clothing before reusing. Ensure that eyewash stations and 

safety showers are close to the workstation location. 

Eye/face protection Safety eyewear complying with an approved standard should be used when a risk. 

assessment indicates !his is necessary to avoid exposure to liquid splashes, mists, 

gases or dusts. 

Skin protection 

Hand protection 

Body protection 

Other skin protection 

Respiratory protection 

Environmental exposure 

controls 

For prolonged or repeated handling, use the following type of gloves: gloves: nitrile. 

Barrier creams may help to protect the exposed areas of the skin but should not be 

applied once exposure has occurred. 

For right choice of glove materials, with focus on chemical resistance and time of 

penetration, seek advice by the supplier of chemical resistant gloves. 

The user must check that the final choice of type of glove selected for handling this 

product is lhe most appropriate and takes Into account the particular conditions of 

use, as included in the user's risk assessment. 

Personal protective equipment for the body should be selected based on the task 

being performed and lhe risks involved and should be approved by a specialist 

before handling this product. 

Appropriate footwear and any additional skin protection measures should be selected 

based on the task being performed and the risks involved and should be approved by 

a specialist before handling this product. 

If workers are exposed to concentrations above the exposure lim it, they must use 

appropriate, certified respirators. If dust is generated and ventilation is inadequate, 

use respirator that will protect against dust/mist. {FFP2/ N95). 

Emissions from ventilation or work process equipment should be checked to ensure 

they comply with the requirements of environmental protection legislation. In some 

cases, fume scrubbers, filters or engineering modifications to the process equipment 

will be necessary to reduce emissions to acceptable levels. 

I SECTION 9: Physical and chemical properties 

9.1 Information on basic physical and chemical properties 

Appearance 

Physical state 

Colour 

Odour 

Odour threshold 

pH 

Mehlng point/freezing point 

Initial bolllng point and bolllng 

range 

Flash point 

Evaporation rate 

Flammability {solid, gas) 

Burning time 

Bumlngrate 

I Date of issue 

Solid. [Powder.] 

White. 

Characteristic. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

20.05.2011. 5/91 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II -United Kingdom (UK) 

Jotun Anti-skid (MM·WCS) 

SECTION 9: Physical and chemical properties 

Upper/lower flammability or 

explosive limits 

Vapour pressure 

Vapour density 

Relative density 

Solublllty(les) 

Partition coefficient: n· 

octanol/water 

Auto-ignHion temperature 

Decomposition temperature 

VIscosity 

Explosive properties 

Oxidising properties 

9.2 Other Information 

No additional Information. 

Not available. 

Not available. 

Not available. 

Insoluble in the following materials: cold water and hot water. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

Not available. 

!sECTION 10: Stability and reactivity 

1 0.1 Reactivity 

10.2 Chemical stability 

10.3 Possibility of hazardous 

reactions 

10.4 Conditions to avoid 

10.51ncompatlble materials 

10.6 Hazardous 

decomposHion products 

No specific test data related to reactivity available for this product or its ingredients. 

The product is stable. 

Under normal conditions of storage and use, hazardous reactions wlfl not occur. 

No specific data. 

No specific data. 

Under normal conditions of storage and use, hazardous decomposition products 

should not be produced. 

jsECTION 11: Toxicological information 

11.1 Information on toxicological effects 

Coating powders can cause localised skin irritation In folds of the skin or under tight clothing. Handling and/or processing 

of this material may generate a dust which can cause mechanical irritation of the eyes, skin, nose and throat. Repeated 

inhalation of dust can produce varying degrees of respiratory irritation or lung damage. Swallowing may cause nausea, 

diarrhoea, vomiting and gastro-intestinal Irritation. 

Acute toxlcltv 

Specific taraet oraan tox!cltv lslng!e uposurel 

Not available. 

Specific target organ toxicltv (repeatgd exposure) 

Not available. 

AsPiration hazard 

Not available. 

!sECTION 12: Ecological information 

12.1 Toxicity 

Conclusion/Summary : Not available. 

12.2 Persistence and degradability 

Conclusion/Summary Not available. 

12.3 Bloaccumulatlve potential 

I Date of Issue 20.05.2011. 
Conforms to Regulation (EC) No. 1907/2006 (REACH}, Annex H- United Kingdom (UK) 

Jotun Anti-skid (MM-WCS) 

SECTION 12: Ecological information 

Not available. 

12.4 Mobility in soli 

Soli/water partition 

coefficient (Koe) 

Mobility 

Not available. 

Not available. 

12.5 Results of PBT and vPvB assessment 

PBT No. 

P: Not available. B: Not available. T: No. 

vPvB Not available. 

vP: Not available. vB: Not available. 

12.6 Other adverse effects No known significant effects or critical hazards. 

I SECTION 13: Disposal considerations 

The information in this section contains generic advice and guidance. The list of Identified Uses In Section 1 should be 

consulted for any available use-specific Information provided in the Exposure Scenario(s). 

13.1 Waste treatment methods 

Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU 

Directive 91/689/EEC. 

European waste catalogue 

(EWC) 

waste paint and varnish other than those mentioned in 08 01 11 . If this product is 

mixed with other wastes, this code may no longer apply. If mixed with other wastes, the 

appropriate code should be assigned. For further information, contact your local waste 

authority. 

!sECTION 14: Transport information 

Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that 

persons transporting the product know what to do in the event of an accident or spillage. 

This preparation is not classified as dangerous according to international transport regulations (ADRIRID, IMDG or 

ICAO/IA TA). 

14.1 UN number 

14.2 UN proper shipping 

name 

14.3 Transport hazard 

class(es) 

14.4 Packing group 

Not regulated. 

14.5 Environmental hazards No. 

14.6 Special precautions Not available. 

for user 

Additional Information 

ADR/RID 

14.7 Transport In bulk Not available. 

according to Annex II of 

MARPOL 73/78 and the IBC 

Code 

I Date of issue 20.05.2011. 

J 

I 
I SECTION 15: Regulatory information 

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 

EU Regulation lECl No. 190V2006 CREACH) 

Annex XIV - List of sybstances subject to authorisation 

Substances of yery high concern 

None of the components are listed. 

Annex XVII· Restrictions : Not applicable. 

on the manufacture, 

placing on the market and 

use of certain dangerous 

substances, mixtures and 

articles 

Other EU regylatlons 

Europe Inventory 

Black list Chemicals 

Priority List Chemicals 

Integrated pollution 

prevention and control list 

(IPPC) -Air 

Integrated pollution 

prevention and control list 

(IPPC) - Water 

lnternat!opal regulations 

Chemical Weapons 

Convention List Schedule I 

Chemicals 

Chemical Weapons 

Convention List Schedule II 

Chemicals 

Chemical Weapons 

Convention List Schedule Ill 

Chemicals 

15.2 Chemical Safety 

Assessment 

All components are listed or exempted. 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

This product contains substances for which Chemical Safety Assessments are still 

required. 

I SECTION 16: Other information 

J' Indicates information that has changed from previously Issued version. 

Abbreviations and acronyms : ATE= Acute Toxicity Estimate 

CLP = Classification, Labelling and Packaging Regulation (Regulation (EC} No. 

1272/2008) 

DNEL = Derived No Effect Level 

EUH statement= CLP-specific Hazard statement 

PNEC = Predicted No Effect Concentration 

RBN = REACH Registration Number 

Procedure used to derive the classification according to Regulatjop tECl No. 1272/2008 lCLPIGHS] 

Classification Justification 

Not classified. 

Full text of abbreviated H 

statements 

Full text of classifications 

[CLP/GHS] 

Full text of abbreviated R 

phrases 

Full text of classifications 

(DSDIDPD] 

I Date of Issue 

Not applicable. 

Not applicable. 

Not applicable. 

Not applicable. 

20.05.2011. 
I SECTION 15: Regulatory information 

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 

EU Regulation lECl No. 190V2006 CREACH) 

Annex XIV - List of sybstances subject to authorisation 

Substances of yery high concern 

None of the components are listed. 

Annex XVII· Restrictions : Not applicable. 

on the manufacture, 

placing on the market and 

use of certain dangerous 

substances, mixtures and 

articles 

Other EU regylatlons 

Europe Inventory 

Black list Chemicals 

Priority List Chemicals 

Integrated pollution 

prevention and control list 

(IPPC) -Air 

Integrated pollution 

prevention and control list 

(IPPC) - Water 

lnternat!opal regulations 

Chemical Weapons 

Convention List Schedule I 

Chemicals 

Chemical Weapons 

Convention List Schedule II 

Chemicals 

Chemical Weapons 

Convention List Schedule Ill 

Chemicals 

15.2 Chemical Safety 

Assessment 

All components are listed or exempted. 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

Not listed 

This product contains substances for which Chemical Safety Assessments are still 

required. 

I SECTION 16: Other information 

J' Indicates information that has changed from previously Issued version. 

Abbreviations and acronyms : ATE= Acute Toxicity Estimate 

CLP = Classification, Labelling and Packaging Regulation (Regulation (EC} No. 

1272/2008) 

DNEL = Derived No Effect Level 

EUH statement= CLP-specific Hazard statement 

PNEC = Predicted No Effect Concentration 

RBN = REACH Registration Number 

Procedure used to derive the classification according to Regulatjop tECl No. 1272/2008 lCLPIGHS] 

Classification Justification 

Not classified. 

Full text of abbreviated H 

statements 

Full text of classifications 

[CLP/GHS] 

Full text of abbreviated R 

phrases 

Full text of classifications 

(DSDIDPD] 

I Date of Issue 

Not applicable. 

Not applicable. 

Not applicable. 

Not applicable. 

20.05.2011. 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II ·United Kingdom (UK) 

Jotun Anti-skid (MM-WCS) 

SECTION 16: Other information 

Date of printing 

Date of Issue/ Date of 

revision 

Date of previous issue 

Version 

Notice to reader 

20.05.2011. 

20.05.2011. 

No previous validation. 

1.01 

To the best of our knowledge, the information contained herein Is accurate. However, neither the above-named 

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the 

information contained herein. 

Final determination of suitability of any material Is the sole responsibility of the user. All materials may present 

unknown hazards and should be used with caution. Al1hough certain hazards are described herein, we cannot 

guarantee that these are the only hazards that exist. 

I Date of issue 20.05.2011. 

I 
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II ·United Kingdom (UK) 

Jotun Anti-skid (MM-WCS) 

SECTION 16: Other information 

Date of printing 

Date of Issue/ Date of 

revision 

Date of previous issue 

Version 

Notice to reader 

20.05.2011. 

20.05.2011. 

No previous validation. 

1.01 

To the best of our knowledge, the information contained herein Is accurate. However, neither the above-named 

supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the 

information contained herein. 

Final determination of suitability of any material Is the sole responsibility of the user. All materials may present 

unknown hazards and should be used with caution. Al1hough certain hazards are described herein, we cannot 

guarantee that these are the only hazards that exist. 

I Date of issue 20.05.2011. 

I