## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **1** of 

### 9 **1. IDENTIFICA** 

**TION** Material N ame : Long Chain Chlorinated Paraffin (LCCP) 

### Revision Date : 09
- 01
- 12 W - 40 43 % chlorine (Cl) by weight W - 50 48 % chlorine (Cl) by weight 

### Chemical D escription : Alkanes, C 19
- 28 – branched and linear, chloro C19
- 28, Long Chain Chlorinated Paraffin (LCCP) 

### CAS #: 1392825
- 28
- 3 

### Product Use: Lubri cant Additive, Flame Retardant 

### Manufacturer I nformation : Trinity Manufacturing, Inc. 11 EV Hogan Drive Hamlet, NC, 28345, USA 910
- 419
- 6566 CHEMTREC (U.S. and Canada) 1
- 800
- 424
- 9300 (For emergencies occurring while in transportation) CHEMTREC (Outside the U.S.) 1
- 703
- 527
- 0585 

### 2. **HA ZA**  **RDS IDENTIFICATION** GHS Classification These two products do not have health or physical hazards that meet the classification criteria under the OSHA Hazard Communication GHS scheme
. The se two products do not have health, physical, or environmental hazards that meet the classification criteria under the United Nations (UN) GHS scheme . However, these products may have potential to persist in the aquatic environment, therefore the Hazard Statement and Precautionary Statements proscribed by the UN GHS for classification under Category 4 of Hazardous to the Aquatic Environment

– Long - Term Hazard, are included below
. 

### Signal W ord None GHS Hazard Statement  H413

– May cause long lasting harmful effects to aquatic life GHS Precautionary Statements  P273

– Avoid release to the environment
.  P501

– Dispose of contents/container in accordance with government regulations

and in accordance with manufacturer instructions in Section 13 of this SDS. 

### 3. **COMPOSITION / INFORMA TION ON INGREDIENTS**  **Components Sy**  **nonyms CA** **S Number % by**  **Weight** Alkanes , C 19
- 28 – branched and linear, chloro 43% chlorine by weight 48% chlorine by weight 1392825
- 28
- 3 99 Epoxidized Soybean Oil (Stabilizer) 8013
- 07
- 8 1 * The stabilizer does not contribute to the classification of this product
.

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **2** of **9** 

### 4. **FIRST A ID MEA** **SURES** Inhalation Move to fresh air. Get medical attention, if needed. 

### Eye Contact Hold eyelids apart and flush eyes with plenty of water for at least 1 5 minutes. If irritation persists get medical attention. 

### Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists. 

### Ingestion Have victim rinse mouth thoroughly with water. Do not induce vomiting without medical advice. If ingestion of a large amount does occur, seek medical attention. 

### Most Important Symptoms/Effects, Acute and Delayed Repeated or prolonged exposure may cause slight irritation of eyes and skin of susceptible persons. Inhalation of vapors in high concentration may cause irritation of the respiratory system. 

### Indication of Immediate Medical Attention or Special Treatment These two products do not have health hazards that require special first aid measures . If you feel unwell, seek medical advice (show the label or SDS where possible). 

### Notes to Physi ci an Treat symptomatically
. 

### 5. **FIRE FIGHTING MEASURES**  Suitable Extinguishing Media Water Fog. Dry Chemical, Foam 

### Unsuitable Extinguishing Media Water. High volume water jet. If use water jet as an extinguisher, this will spread the fire 

### Specific Hazards Arising From the Chemical Irritating and toxic gases or fumes may be released during a fire. Containers may explode when heated. May burn, but does not ignite readily. 

### Hazardous Combustion Products Hydrogen chloride , carbon oxides, phosgene, chlorine 

### Protective Equipment and Precautions for Firefighters In event of fire, wear self
- contained pressure - demand breathing apparatus with full protective gear
. 

### Fire Fighting Equipment/Instructions Use water spray to cool unopened containers. Move containers from fire area, if you can do so wi thout risk. 

### 6. **ACCIDENTA L RELEA** **SE ME AS**  **URES** Personal Precautions Keep unnecessary personnel away. Ensure adequate ventilation. Use personal protective equipment. Avoid touching spilled materials. 

### Methods for Containment ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so w ithout risk. Dike the spilled material, where this is possible. Prevent t

his material from contaminating soil or from entering sewage and drainage systems that lead to waterways. 

### Methods for Cleaning Up Spills Wear appropriate protective equipment and clothing during clean
-up . Should not be released into the environment. 

### Large Spills Stop the flow of material, if safe to do so. Dike the spilled material, if possible. Dike far ahead of liquid spill for later disposal. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Absorb with earth, sand or other non
- com bustible material and transfer to containers for later disposal. Following product recovery, use oil absorbent to collect any residual material.

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **3** of **9** Small Spills Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. 

### Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Do not contaminate water. 

### Other Information Never return spills in original containers for re
-use. For waste disposal, see Section 13. 

### 7. **HA NDLING AND STORA** **GE**
Precautions for Safe Handling DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid prolonged or repeated skin contact with this material. Wash hands after handling and before eating. Avoid breathing va pors or mists of this product. Wear personal protective equipment. Avoid release to the environment. Handle and open container with care. 

### Conditions for Safe Storage , including incompatibilities Keep away from heat, sparks, and flame. Store in a cool dry place. Keep container closed when not in use. 

### 8. **EXPOSURE CONTROLS / PERSONA L PROTECTION**  Exposure G uidelines : Exposure Limits for this product have not been established. Avoid repeated or prolonged exposure to vapor or mist without appropriate respiratory protection. 

### Engineering Controls : Under normal conditions of use, natural ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this product. 

### Personal P rotective E quipment : Eye / Face Protection W ear safety glasses with side
- shields
. If splashes are likely to occur, we ar a face shield with safety glasses. 

### Skin Protection Normal work clothing (long sleeved shirts and long pants) is recommended. If splashes are likely to occur, use apron or impervious suit, such as a Tyvek coverall. If liquid contact is likely to occur, manufacturer recommends nitrile gloves (ex: N
- DEX Nitrile). 

### Respiratory Protection No personal respiratory protective equipment normally required. If mist is ge nerated (heating, spraying) and engineering controls are not sufficient, w ear NIOSH
- approved organic vapor respirator w ith (R or P) particulate filter for oil mist. 

### Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 

### 9. **PHYSICA L & CHEMICA**  **L PROPERTIES** Appearanc e: Clear, yellow to dark yellow Physical S tate: Liquid Odor : S light Odor T hreshold : Not available pH : Not applicable Melting / Freezing Point: Not applicable Boiling Point: > 4 00 °C Boiling Point Range Not available

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **4** of **9** Flash Point: W - 40 > 4 50 °F (232 °C) Cleveland Open Cup W - 5 0 > 450 °F (232 °C) Cleveland Open Cup Evaporation Rate: Not available Flammability Will decompose if involved in fire conditions Flammability limits in Air, Not available Lo wer and Upper % by Volume: Auto
- I gnition T em

perature : Not available. Vapor P ressure : Very low
. Not available for these two products, but representative value provided: C >20 with 42% Cl or 48% Cl =
- 2.5 x 10 - 5 Pa @ 25 °C ( 9.375771e
- 7 torr) Vapor D ensity : Not available Volatility: (% Loss, 25 hours) 0.8 @ 10 0 °C Specific Gravity W - 40 1. 1 7 g/cm3 W - 50 1. 2 3 g/cm3 Relative Density (lbs/gal): W - 40 9. 7 W - 5 0 10. 2 Solubility ( in water) : Very low
. <0.000005 g/l @ 20 °C Partition Coefficient : n - octanol/water: See Section 12. Decomposition Temperature: Not available Viscosity SUS @ 210 °F W - 40 140 W - 50 230 Viscosity Poises @ 77 °F W - 40 27 W - 50 110 Stability: W - 40 0.4 W - 50 0.5 Saturated Vapor Concentration: Not available Molecular F ormula : 

### C n

### H 2n+2
-y

### Cl y 

### n = 19
- 28 Molecular Structure: CH 3 (CH 2 CHCl) 7 CH 2 CH 2 CH 2 CH 2 CH 2 CH 3 (representative) Flash P oint C lass : 

### Class IIIB Combustible (NFPA) Oxidiz ing P roperties : None



### 10. **CHEMICA L STA**  **BILITY & REA CTIVITY INFORMA**  **TION** Reactivity Not reactive.

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **5** of **9** Chemical Stability Stable at normal conditions
. 

### Pos sibility of Hazardous Reactions Will not occur. 

### Conditions to Avoid: High temperatures. 

### Incompatible Materials: Strong oxidizing agents, reducing agents. 

### H azardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapors
- carbon oxides, hydrogen chloride, phosgene, chlorine. 

### 11. **TOXICOLOGICA L INFORMA**  **TION** Likely Routes of Exposure Skin contact, eye contact, inhalation, ingestion (skin is predominant route of exposure in workplace) 

### Signs and Symptoms of Exposure Repeated or prolonged exposure may cause irritation of eyes and skin in sensitive persons . Inhalation of vapors in high concentration may cause irritation of respiratory system. 

### Acute or Delayed Effects: Eyes Contact with eyes may cause slight irritation. 

### Skin Prolonged and/or repeated skin contact may result in mild irritation or redness
. 

### Inhalation May cause slight irritation of respiratory tract. Avoid breathing vapors or mists of this product
. 

### Ingestion Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury. 

### Chronic Effects From Short and Long Term Exposure : Specific Target Organ Toxicity  No data available for repeated skin exposure
.  Liver (inflammatory/necrotic) is predominant target in animal studies.  Kidney, lymphatic system also identified as possible targets 

### Respiratory or Sk in Sensitization  Available data is inconclusive 

### Mutagenicity (germ cell)  No data available for these products , but it is predicted that LCCPs are not mutagenic 

### Reproductive Effects  No ef fects on fertility is expected.  Slight increase in implantation loss at 5,000 mg/kg/day, rabbit for C22

–26, 43% Cl 

### Endocrine Disruption  No data available 

### Toxicology Studies: Acute Toxicity Low acute toxicity has been observed for inhalation or dermal routes. Oral studies on representative products are listed below: LOAEL, Rat, oral, 90 day 100 mg/kg/day , for repeated dose toxicity (liver) for LCCP, 43% Cl 

### NOAEL, Rat, oral, 14 day 3,000 mg/kg/day , for repeated dose toxicity (liver) 

### NOAEL, Mouse, oral, 2 year 5,000 mg/kg/day

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **6** of **9** Carcinogenicity This product is not listed by or considered to be a carcinogen by IARC, NTP, OSHA , or ACGIH
. An increased incidence of malignant lymphoma in male mice wa s reported at the highest dose tested (5,000 mg/kg/day) for C 23 avg, 43% Cl 

### 12. **ECOLOGICA L INFORMA**  **TION** There is no specific ecological information for the W40 or W50 product or for the C19
- 28 range. Information provided below is representative of the carbon chain range and percent of chlorination in the two products. 

### Ecotoxicity: E cologically significant impacts may have potential to occur if released to w ater and sediment. Although there is no established acute aquatic toxicity for these products , they may cause long lasting harmful effects to aquatic life due to studies that they do not readily biodegrade and may therefore p ersist in the environment
.


### Aquatic Toxicity:  C22
- 26, 42% wt. Cl , 96h LC50 >5,000 mg/l , Bleak fish species , No effects seen at solubility.  C18
- 26, 49% wt. Cl , 91
- day LC0 >3,400 mg/kg , Bleak, No effects seen at solubility. Bleak  C>20, 48

–54% wt. C , l 96h LC50 >300 mg/l, Bluegill Sunfish , No effects seen at solubility.  C20
- 30, 42% wt. Cl , 96h LC50 >770 mg/l Rainbow Trout , No effects seen at solubility.  C>20, 43% wt. Cl , No adverse eff ects seen over 48 hours, daphnia magna (does not meet Marine toxicity criteria) 

### Terrestrial Toxicity No data available. 

### Persistence and Degradability: (Environmental Fate)  Unlikely to be readily or inherently biodegradable
. Assumed to be potentially persistent, as a result.  No data available on degradation in soil or fate in atmosphere.  Atmospheric half

- life is estimated 20 to 25 hours 

### Bioaccumulative Potential: Not considered to be bioaccumulative
. 

### Mobility in Soil: No data available. 

### Other Adverse Effects: Ozone Depletion Potential

– not determined 

### Partition Coefficient (n - octanol/water) Log Kow = 10.3 is representative value Koc = 2.77 × 10 8 l/kg is representative value 

### BCF: BCF for LCCPs is considered to be <2,000 l/kg. Thus it is concluded that LCCPs are unlikely to meet the bioaccumulative criteria
. 

### 13. **DISPOS AL** **CONSIDERA TIONS**  Waste C odes Waste codes should be assigned by the user based on the application for which the product wa s used. Disposal Instructions Collect and reclaim or dispose in sealed containers at licensed wa ste disposal site. Do not allow this material to drain into sewers/water supplies. This product, in its present state, when discarded or disposed of, is not a hazardous wa ste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous wa ste. Dispose in accordance with all applicable regulations.

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **7** of **9** Waste from Residues and Dispose of in accordance with local regulations. Unused Products Contaminated P ackaging Do not re -use empty containers for other substances
. Em pty containers should be taken to an approved wa ste handling site for recycling or disp osal or returned to the manufacturer. 

### 14. **TRA NSPORT INFORMA**  **TION DOT**  **(United States)** Not regulated as hazardous material. **TDG (Canada)**  Not regulated as dangerous goods. **IM DG**  **(Water)** Not regulated as dangerous goods. **IATA (Air)**  Not regulated as dangerous goods. 

### 15. **REGULA**

**TORY INFORMATION** US FEDERAL REGULATIONS : OSHA : This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200 DEA : Not regulated under any of the 4 DEA regulations below
. List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) DEA Essential Chemical Code Number Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) DEA Exempt Chemical Mixtures Code Number CERCLA Reportable Quantity (RQ) : None SARA EPCRA 312/313 : Not applicable Immediate Hazard

– No Delayed Hazard
- No Fire Hazard

– No Pressure Hazard

– No Reactivity Hazard
- No Section 302
- Extremely H azardous No S ubstance Section 311
- H azardous Chemical No EPA High Production Volume List No Inventory S tatus for : Alkanes, C 19
- 28 – branched and linear, chloro * "Yes" indicates that all components of this pr oduct comply with the inventory, requirements administered by the governing country(s). Country or Region Inventory N ame On Inventory * United States & Puerto Rico
...... Toxic Substances Control Act (TSCA) Inventory 8(b)
............. No, PMN submitted Canada
................................ ....... Domestic Substances List (DSL)
................................ ................................ ......... No

................................ ................... ................................ ........... Yes for CAS 85535
- 86
- 0 For Alkanes, C18
- 28, chloro Canada
................................ ....... Non- Domestic Substances List (NDSL)
................................ ............................. No Mexico
................................ ....... No Established List
................................ ................................ ........... Not Applicable

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **8** of **9** STATE REGULATIONS: California This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm
. CANADA: CEPA Schedule 1 List No for these two products. Yes, for Chloroalkanes C 10 – C 20 WHMIS Not controlled 

### 16. **OTHER INFORMA TION**  HMIS® Rating : HMIS® is a registered trade and service mark of the American Coatings Association Health: 1 Flammability: 1 Physical hazard: 0 Personal protection: B NFPA Rating: Health: 1 Flammability: 1 Instability: 0 

### ACRONYMS : ACGIH American Conference of Governmental Industrial Hygien ist s BCF Bioconcentration Factor CAS Chemical Abstracts Service CEPA Canadian Environmental Protection Act CERCLA Comprehensive Environmental Response, Compensation, and Liability Act (Superfund) CFR Code of Federal Regulations CHEMTREC Chemical Transportation Emergency Center DOT United States Dep artment of Transportation EPCRA Emergency Planning and Community Right
-to -Know GHS Globally Harmonized System IARC International Agency for Research on Cancer IMDG International Maritime Dangerous Goods Koc 

### The value of Koc indicates where a chemical is likely to end up
- surface water or ground

water. For example, a chemical with large Koc values tend to adsorb onto soil and has potential for contaminating surface water
. LC 50 

### Lethal Concentration
- median dose at which 50% of test animals die from inhalation LOAEL Lowest Observed Adverse Effect Level Log K ow 

### Octanol
-Water Partition Coefficient
. The higher the number, the mo re bioavailable

(prefer s partitioning into soil organic matter rather than water). NFPA National Fire Protection Association NOAEL No Observed Adverse Effect Level NTP Normal Temperature and Pressure: 760 mmHg and 20oC or 1 atm and 68o F NTP National Toxicology Program OSHA Occupational Health and Safety Administration RCRA Resource Conservation and Recovery Act

## SAFETY DATA SHEET 

# CP **AR –**  **LCCP** Page **9** of **9** SARA US EPA Superfund Amendments and Reauthorization Act SDS Safety Data Sheet (formerly known as MSDS

– Material Safety Data Sheet) TDG Transport of Dangerous Goods (Canada) TSCA Toxic Substances Control Act US United States USA United States of America WHMIS Workplace Hazardous Materials Identification System (Canada) Disclaimer: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the dat e of its publication. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information given is designed only as guidance for safe handling, use, processing , storage, transportation, disposal and release. The information in the sheet was w ritten based on the best knowledge and experience currently available. Issue Date: 09
- 01
- 12 Version: North America Changes: Not appli c able as this is original version