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## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008

DR 

### 1 Identification of the substance/mixture and of the company/undertaking

· Product identifier · Trade name: EPICLON HP-4700 · CAS Number:

146876-45-1 · Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation Epoxy resin · Details of the supplier of the safety data sheet · Manufacturer/Supplier:

DIC Corporation Functional Polymers Division DIC Blg, 7-20, Nihonbashi 3-chome, Chuo-ku, Tokyo 103-8233, Japan · Information department:

Functional Polymers Technical Department Phone: +81-436-41-4142 FAX: +81-436-43-1947 · Emergency telephone number: Phone: +81-3-5203-7636 Fax: +81-3-5203-7850 Sales Dept. 

### 2 Composition/information on ingredients

· Chemical characterization: Substances · CAS No. Description

146876-45-1 2,7-Naphthalenediol, polymer with (chloromethyl) oxirane and formaldehyde · Identification number(s) 

### 3 Hazards identification

· Classification of the substance or mixture

The substance is not classified according to the Globally Harmonized System (GHS). · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. · Information concerning particular hazards for human and environment: Not applicable. · Label elements · Labelling according to EU guidelines:

Observe the general safety regulations when handling chemicals. The substance is not subject to classification according to the sources of literature known to us. · Classification system: · NFPA ratings (scale 0 - 4) 

## 0 0 0 Health = 0 Fire = 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)

HEALTH FIRE REACTIVITY 0 0 0 Health = 0 Fire = 0 Reactivity = 0
· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. USA (Contd. on page 2)Page 2/6 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008 Trade name: EPICLON HP-4700 (Contd. of page 1)

DR 

### 4 First aid measures

· Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. ·After skin contact: Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed

No further relevant information available. 

### 5 Firefighting measures

· Extinguishing media · Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. ·Advice for firefighters · Protective equipment: No special measures required. 

### 6Accidental release measures

· Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Pick up mechanically. · Reference to other sections

No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 

### 7Handling and storage

· Handling: · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available. 

### 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: Not required. · Additional information: The lists that were valid during the creation were used as basis. (Contd. on page 3) USAPage 3/6 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008 Trade name: EPICLON HP-4700 (Contd. of page 2)

DR · Exposure controls · Personal protective equipment: · General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands:

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Not required. 

### 9 Physical and chemical properties

· Information on basic physical and chemical properties · General Information · Appearance: Form: Solid Color: Brown · Odor: Characteristic · Odour threshold: Not determined. ·pH-value: Not applicable. · Change in condition Melting point/Melting range: 90°C (194°F) Boiling point/Boiling range: Undetermined. · Flash point: Not applicable. · Flammability (solid, gaseous): Product is not flammable. · Ignition temperature: Decomposition temperature: Not determined. · Auto igniting: Not determined. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure: Not applicable. · Density at 25°C (77°F): 1.2 g/cm3 (10.014 lbs/gal) · Relative density Not determined. · Vapour density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Insoluble. · Segregation coefficient (n-octonol/water): Not determined. (Contd. on page 4) USAPage 4/6 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008 Trade name: EPICLON HP-4700 (Contd. of page 3)

DR · Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. Solids content: 100 % · Other information No further relevant information available. 

### 10 Stability and reactivity

· Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. 

### 11 Toxicological information

· Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information:

When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. The substance is not subject to classification. 

### 12 Ecological information

· Toxicity · Acquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. ·Additional ecological information: · General notes:

Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. 

### 13 Disposal considerations

· Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. (Contd. on page 5) USAPage 5/6 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008 Trade name: EPICLON HP-4700 (Contd. of page 4)

DR · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. 

### 14 Transport information

· Land transport ADR/RID (cross-border): · ADR/RID class: - · Maritime transport IMDG: · Marine pollutant: No · UN "Model Regulation": - · Special precautions for user Not applicable. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 

### 15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances):

Substance is not listed. · Section 313 (Specific toxic chemical listings):

Substance is not listed. · TSCA (Toxic Substances Control Act):

Substance is not listed. · Proposition 65 · Chemicals known to cause cancer:

Substance is not listed. · Chemicals known to cause reproductive toxicity for females:

Substance is not listed. · Chemicals known to cause reproductive toxicity for males:

Substance is not listed. · Chemicals known to cause developmental toxicity:

Substance is not listed.
· Cancerogenity categories · EPA (Environmental Protection Agency)

146876-45-1 2,7-Naphthalenediol, polymer with (chloromethyl) oxirane and formaldehyde LVE by DIC international (USA)

· IARC (International Agency for Research on Cancer)

Substance is not listed. · NTP (National Toxicology Program)

Substance is not listed. · TLV (Threshold Limit Value established by ACGIH)

Substance is not listed. · NIOSH-Ca (National Institute for Occupational Safety and Health)

Substance is not listed. · OSHA-Ca (Occupational Safety & Health Administration)

Substance is not listed.
· Product related hazard informations:

Observe the general safety regulations when handling chemicals. (Contd. on page 6) USAPage 6/6 

## Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 04/22/2011 Reviewed on 04/04/2008 Trade name: EPICLON HP-4700 (Contd. of page 5)

DR The substance is not subject to classification according to the sources of literature known to us. · National regulations: · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 

### 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Functional Polymers Technical Department · Contact: · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) USA