## Environmental so **lutions delivered uncommonly well** 

# Anadarko Petroleum Corporation

Discoverer Spirit EGOM PSD/Title V Permit Application Addendum

Prepared By:

**TRINITY CONSULTANTS**

301 Main Street, Suite 900 Baton Rouge, LA 70816 (225) 292

- 2661

June 2013

**Project No. 1 31901**  **.00 22** Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants i 

## TABLE OF CONTENTS

1. **INTRODUCTION** 1 **1.1. Discussion of The Proposed Changes**

**................................ ................................**  **................................ .....................**  **1 1.2. Contents of the Application Addendum** 

**................................ ................................**  **................................ .................**  **6**



### 2. **EMISSIONS CALCULATIO NS**  7 **2.1. ‘Equivalency’ Determination**

**................................ ................................**  **................................ ................................**  **..... 7**  **2.2. Emissions Estimation**

**................................ ................................**  **................................ ................................**  **................... 7**  2.2.1. Diesel Fired Well Evaluation Engines on the drillship (DR

- VS

- 01 through DR

- VS

- 05)

................................ .. 7 2.2.2. Diesel Fired Well Evaluation Engines on the support vessel(SB

- VS

- 01 through SB

- VS

- 09)

........................ 9 2.2.3. Welding Operations (DR

- WO

- 01)

................................ ................................ ................................ ................................ ..... 10 2.2.4 Diesel Fired Air Compressor Engines (DR

- AC

- 01 and DR

- AC

- 02)

................................ ................................ ......... 10 2.2.5 Well Completion Wireline Engines (DR

- WC

- 09 and DR

- WC

- 10)

................................ ................................ .......... 10 2.2.6 Painting Operations (DR

- PO

- 01)

................................ ................................ ................................ ................................ ....... 11



### 3. **REGULATORY APPLICABI LITY ANALYSIS**  12 **3.1. New Source Performance Standards (NSPS)**

**................................ ................................**  **................................ ......**  **12** 3.1.1. 40 CFR 60 Subpart A

– General Provisions

................................ ................................ ................................ ................... 12 3.1.2. 40 CFR 60 Subpart IIII

– Stationary Compression Ignition Internal Combustion Engines

........................ 12 3.1.3. 40 CFR 60 Sub part JJJJ

– Stationary Spark Ignition Internal Combustion Engines

................................ ....... 13 **3.2. National Emission Standards for Hazardous Air Pollutants (40 CFR Part 61)** 

**................................ .....**  **14 3.3. National Emission Standards for Hazardous Air Pollutants (40 CFR Part 63)** 

**................................ .....**  **14** 3.3.1. 40 CFR Part 63 Subpart A

– General Provisions

................................ ................................ ................................ ......... 14 3.3.2. 40 CFR 63 Subpart ZZZ Z

- Stationary Reciprocating Internal Combustion Engines

................................ .... 14 3.3.3. 40 CFR 63 Subpart XXXXXX

– Area Source Standards for Nine Metal F abrication and Finishing Source Categories

................................ ................................ ................................ ................................ ................................ ............................. 15



### 4. **BACT ANALYSIS** 17 **4.1. Air Compressor Engines (DR**

**- AC** 

**- 01 and DR** 

**- AC** 

**- 02)** 

**- BACT Analysis** 

**................................ .......................**  **18 4.2. Wire Line Engines (DR** 

**- WC** 

**- 09 and DR** 

**- WC** 

**- 10)** 

**- BACT Analysis** 

**................................ ................................**  **18 4.3. Well Evaluation Engines**  **ON THE DRILLSHIP ( DR** 

**- VS** 

**- 01 through DR** 

**- VS** 

**- 05**  **)**

**- BACT Analysis** 

**....... 19**  4.3.1. NOx BACT Analysis

................................ ................................ ................................ ................................ ................................ . 19 4.3.2. CO BACT Analysis

................................ ................................ ................................ ................................ ................................ .... 23 4.3.3. PM/PM 10 

### /PM 2.5 

### BACT Analysis

................................ ................................ ................................ ................................ .......... 24 4.3.4. VOC BACT Analysis

................................ ................................ ................................ ................................ ................................ . 25 **4.4. BACT Analysis for Welding Operations**

**................................ ................................**  **................................ ...............**  **26 4.5. BACT Analysis for Painting Operations** 

**................................ ................................**  **................................ ...............**  **27 4.6. BACT Analysis for Water Blasting Operations** 

**................................ ................................**  **................................ ..**  **27**



### 5. **AIR DISPERSION MODEL ING ANALYSIS UPDATE**  29 **5.1. Summary of Modeling Updates**

**................................ ................................**  **................................ ...............................**  **29 5.2.**  **Post Modification Modeling Emission Rates**

**– Drilling Scenario** 

**................................ ................................**  **30 5.3.**  **Q/D Analysis**

**................................ ................................**  **................................ ................................**  **................................ ..**  **31 5.4.**  **Updated Modeling Results**

**................................ ................................**  **................................ ................................**  **........ 31**  5.4.1. Class I Area Significance Analysis

................................ ................................ ................................ ................................ .... 31 5.4.2. Deposition

................................ ................................ ................................ ................................ ................................ .................. 32 5.4.3. Visibility

................................ ................................ ................................ ................................ ................................ ...................... 33 **5.5. Conclusion** 

**................................ ................................**  **................................ ................................**  **................................ ......**  **33**Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants ii 

### 6. **PART 71 FORMS** 34

**APPENDIX A**

**– EMISSION CALCULATION**  **S**

**APPENDIX B**

**– RBLC SEARCH RESULTS** 

**APPENDIX C**

**– SPECIFICATION SHEETS** 

**APPENDIX D**

**– AIR DISPERSION MODEL**  **ING**

**APPENDIX E**

**– REVISED RESPONSE TO**  **INCOMPLETENESS DETER MINATION LETTER QUES**  **TION NO. 8**

**APPENDIX F**

**– REVISED DRILLING SC**  **ENARIO**

**APPENDIX G**

**– MATERIAL SAFETY DATA**  **SHEETS**Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants iii 

## LIST OF TABLES

Table 1

- 1 HOS Coral

- Hours of Operation And Fuel Consumption 2

Table 1

- 2 HOS Coral

– Fuel Based Emission Factors for Supply Boats 3

Table 1

- 3 Revised List of Supply Boat Engines (HOS Coral) 3

Table 1

- 4 Addendum Summary of Changes 5

Table 3

- 1 Manufacture Dates for Engines on Drillship 13

T able 4

- 1 Ranks of Technologies Feasible for Diesel Fired Engines 22

Table 4

- 2 Ranks of Technologies Feasible for the Welding Oper ations 27

Table 4

- 3 Proposed BACT Emission Limits for New Sources 28

Table 5

- 1 Modeled Emission Rates Comparison for Well Completions 29

Table 5

- 2 Modeled Emission Rates Comparison for Drilling Operations 30

Table 5

- 3 Updated Drilling Operation PM Speciat ion Summary 30

Table 5

- 4 Q/d Analysis and Results 31

Table 5

- 5 Comparison to Class I Area SILs For Drilling Operations 32

Table 5

- 6 Nitrogen and Sulfur Deposition For Drilling Operations 32

Table 5

- 7 Method 8

- 98th Percentile Extinction Change For Drilling Operations 33Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 1 Trinity Consultants 

## 1. **INTRO DUCTION** 

Anadarko Petroleum Corporation (Anadarko) is proposing to conduct exploratory drilling , completion, and associated maintenance activit ies (the proposed proje c t) on the Outer Continental S hel f (OCS) of the Eastern Gulf of Mexico (EGOM) . The proposed project activity will consist of three phases

– (1) the drilling phase, (2) the well completion phase, and (3) production well maintenance (remedial wellwork) phase. The proposed project will be conducted over a period of two years, with a maximum proposed operation of 208 days per year

. Anadarko submitted an application for a pre

- construction Prevention of Significant Deterioration ( PSD ) and a Title V operation permit in December 2012. This sub mittal constitutes an addendum to that application.



## 1.1. DISCUSSION OF THE PR OPOSED CHANGES

This Section discusses the proposed changes and their impacts on emissions and other aspects of the application. Anadarko is proposing the following changes to the December 2012 application:

1. Add weld ing operations (DR

- WO

- 01) on the drillship

-
Anadarko is proposing to include welding operations as an additional source. The welding operations will be conducted as part of the drillship maintenance activities during the drilling as well as well completion activities

. The addition of welding oper ations will result in increases in total particulate matter (PM), particulate matter with aerodynamic diameter less than 10 microns (PM 10 

### ), particulate matter with aerodynamic diameter less than 2.5 microns (PM 2.5 

### ), and hazardous air pollutants (HAPs) emis sions. This change will impact the drilling as well as the well completion scenario.

2. Add five Detroit 4

- 71 engines (DR

- VS

- 01 to DR

- VS

- 05) for well evaluation activities on the drillship

-
Anadarko is proposing to include five 140 hp diesel fired “well e valuation” engines to support well evaluation activities as additional sources. These engines will be used to support various well evaluation activities during the drilling scenario. The addition of these engines will result in increase in emissions of all criteria pollutants, greenhouse gases (GHGs), and HAPs. This change will not impact the well completion scenario.

3. Remove the operating restrictions on existing water blasting engine and painting operations (DR

- WB

- 01 and DR

- PO

- 01 )

, and allow them to operate simultaneously with the existing remotely operated vehicle (ROV) (SB

- GE

- 04 ) generator on the supply boat

-
The December 2012 application does not allow concurrent operations of ROV generator on the supply boat and painting and water blasting opera tions on the drillship during the drilling scenario. Anadarko proposes to remove this restriction to allow simultaneous operation of these sources. This revision will result in increase in emissions of criteria pollutants, GHGs, and HAPs. This change will not impact the well completion scenario.

4. Increase the existing water blasting engine (DR

- WB

- 01) oper ation limit to 12 hours per day

-Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 2 Trinity Consultants 

### Anadarko is proposing to increase the existing 7 hrs/day operation limit for the water b l a s t ing engine to 12 hrs/day. This revision will result in increase in emissions of all criteria pollutants, GHGs, and HAPs. This change will not impact the well completion scenario.

5. R evise the descriptions and operating hours of existing air compressor diesel engine s (DR

- AC

01 and DR

- AC

- 02)

-

Since these diesel engines will be managed as non

- emergency engines, Anadarko requests to change the names of these sources as DR

- AC

- 01

– Air compressor diesel engine #1 and DR

- AC

02

– Air compressor diesel engine #2. Anadarko also proposes to change the current operating limit of 100 hrs/year for each engine to 1 04 hrs /year for each engine. This revision will result in increase in emissions of criteria pollutants, GHGs, and HAPs.

6. Add two wire line engines (DR

- WC

- 09 and DR

- WC

- 10) to the well completion operation

– Scenario 4

-
Anadarko proposes to add two (2) 275 hp diesel fired wire line engines to the well completion scenario

- Scenario 4. This revision will result in increase in emissions of criteria pollutants, GHGs, and HAPs. This change will not impact drilling operations scenario as well as other well completion operations scenario.

7. Revise the supply boat’s hours based operation limit to a fuel based operation limit

-

Anadarko proposed 30 hrs/day operating limit for the supply boats in the December 2012 application. HOS Coral was considered as the worst case supply boat and emissions were calculated based on the assumption that all listed air em ission sources except for emerge ncy generator (SB

- GE

- 03) on the HOS Coral will operate at 100% load.

Based on the recent changes, Anadarko proposes to revise the hours based operation limit to a fuel based operation limit. As shown in the Table 1

- 1 below, 30 hours of operations at 10 0% load will result in approximately 17,098 gallons of fuel consumption. The proposed change will not result in a change in emissions.

**T ABLE**  

### 1

**- 1**  **HOS C**  **ORAL**


### - **H OURS OF**  

### O **PERATION** 

### A **ND** 

### F **UEL** 

### C **ONSUMPTION**



### Emission **ID Operating**  **Hours (hr**  **s /day)**  **Maximum NO x**  

### Emissions at

**100% load**

**(lb /hr)**  **Maximum Fuel**  **Consumed at** 

**100% load**

**(gal/hr) Maximum**  **Fuel Consumed**  **at**

**100% load (gal/**  **day )**  SB

- ME

- 01 30 35.56 148.31 4,449 SB

- ME

- 02 30 35.56 148.31 4,449 SB

- TE

- 01 30 13.02 54.26 1,628 SB

- TE

- 02 30 13.02 54.26 1,628 SB

- TE

- 03 30 13.02 54.26 1,628 SB

- GE

- 01 30 12.39 50.77 1,523 SB

- GE

- 02 30 12.39 50.77 1,523 SB

- GE

- 04 12 5 .00 22.5 270 Total 139.96 17,098

**B ASED ON THE RECENT C**  **HANGES** 

### , **A NADARKO PROPOSES TO**  **REVISE THE HOURS BAS ED OPERATION LIMIT T**  **O A FUEL**Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 3 Trinity Consultants 

### Table 1

- 2 shows derived emission factors in lbs of pollutant per barrel of fuel.

**T ABLE**  

### 1

**- 2**  **HOS C**  **ORAL**



### – **F UEL**  

### B **ASED** 

### E **MISSION** 

### F **ACTORS FOR**  

### S **UPPLY** 

### B **OATS**



### Emission ID **Maximum Fuel Consumed at 100%**  **load (gal/day) Maximum Fuel**  **Consumed at**

**100% load (bbl/day)**  **Total Emissions (lbs/day)**  **Emission Factor**  **(lbs/bbl)**

PM

17,098 407.1 114.43 0.28 PM 10 

### 94.42 0.23 PM 2.5 

### 91.68 0.22 NO x 

### 4,111.90 10.10 SO 2 

### 3.84 0.01 H 2 

### SO 4 

### 0.12 0.00

CO 2,846.64 6.99 VOC 220.53 0.54

Pb 0.07 0.00 GHG 362,506 889.76

8. Add five Detroit 4

- 71 engines (SB

- VS

- 01 to SB

- VS

- 05) , two Caterpillar 3406C engines (SB

- VS

- 06 and SB

- VS

- 07)

, and two crane engines (SB

- VS

- 08 and SB

- VS

- 09) for well evaluation activities on the supply boat

-
Anadarko proposes to use five Detroit 4

- 71 engines, two Caterpillar 3406C engines
, and two crane engines (John Deere PE 4045D and Cummins B 5.9

- C) for well evaluation activities on the supply boat . Note that Anadarko is not proposing to revise the daily fuel limit requested in item no. 7 and the supply boats will be limited to same daily and annual fuel usage limit after including above mentioned well evalu ation engines. This revision will not result in increase in emissions of criteri a pollutants, GHGs, and HAPs. The manufacturer and capacity of the above listed engines is provided in the Table 1

- 2 below.

**T ABLE**  

### 1

**- 3**  **R EVISED**  

### L **IST OF** 

### S **UPPLY** 

### B **OAT** 

### E **NGINES** 

### (HOS **C ORAL**  

### )

**Unit ID Description**  **Make & Model Rating (HP)** 



### Curren tly Permitted Engines

SB

- ME

- 01 Diesel marine propulsion engine #1 Caterpillar 3516C DITA 3,004

SB

- ME

- 02 Diesel marine propulsion engine #2 Caterpillar 3516C DITA 3,004

SB

- TE

- 01 Diesel marine forward bow thruster engine #1 Caterpillar 3508C DITA 1,100

SB

- TE

- 02 Diesel marine aft bow thruster engine #2 Caterpillar 3508C DITA 1,100

SB

- TE

- 03 Diesel marine stern thruster engine #3 Caterpillar 3508C DITA 1,100

SB

- GE

- 01 Port electrical generator diesel engine #1 Caterpillar C32 DITA 1,047

SB

- GE

- 02 Starboard electrical generator diesel engine #2 Caterpillar C32 DITA 1,047

SB

- GE

- 03 Emergency electrical generator diesel engine #3 Caterpillar C9 DITA 253

SB

- GE

- 0 4 ROV Electrical Generator #4 Cummins QSX15

- G9 NR2 475Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 4 Trinity Consultants 

### Unit ID **Description Make & Model**  **Rating (HP)** 

### Additional Engines

SB

- VS

- 01 Well evaluation engine #1 Detroit 4

- 71 140

SB

- VS

- 02 Well evaluation engine #2 Detroit 4

- 71 140

SB

- VS

- 03 Well evaluation engine #3 Detroit 4

- 71 140

SB

- VS

- 04 Well evaluation engine #4 Detroit 4

- 71 140

SB

- VS

- 05 Well evaluation engine #5 Detroit 4

- 71 140

SB

- VS

- 06 Well evaluation engine # 6 Caterpillar 3406C 360

SB

- VS

- 07 Well evaluation engine # 7 Caterpillar 3406C 360

SB

- VS

- 08 Well evaluation crane engine #1 John Deere PE 4045D 62

SB

- VS

- 09 Well evaluation crane engine #2 Cummins B 5.9

- C 130



### 9. Revise response to Question no. 8 in EPA’s incompleteness determination letter

-

Anadarko responded to EPA’s incompleteness determination le tter in March 2013. Anadarko proposes to revise its response to Question no. 8 with this submittal. The revised response is provided in the Appendix E. The revision primarily includes addition of equipment which were previously restricted to drilling s cenario.

Since emission calculations, regulatory requirements, and Best Available Control Technology (BACT) determinations were already provided to EPA previously, this submittal does not address them again. As shown in Section 5 of this submittal, t his change will have no impact on previously submitted air dispersion modeling for well completion scenario



### .

10. Add Emergency Gen erator (DR

- GE

- 07) engine as a part of Main Engines (DR

- GE

- 01 to DR

- GE

06) fuel based operational limit

-

Anadarko proposes to a dd the Emergency Generator (DR

- GE

- 07) as a part of the fuel limit, which is currently applicable to the main engines (DR

- GE

- 01 to DR

- GE

- 06)

. Anadarko is proposing this limit be applicable to main engines as well as emergency generator. The
emergency gen erator will not be operated for more than 100 hours per year. This change will not result in increase in emissions for the drilling scenario

. A similar fuel limit is requested in Change no. 9 for the well completion scenario.

Since emission calculations, regulatory requirements, and BACT determinations were already provided to EPA previously, this submittal does not address them again. The operating limits and associated emissions for the revised drilling scenario are provide d in Appendix F.

11. Revise Painting Operations (DR

- PO

- 01) emissions due to addition of new paints and thinners

-

Anadarko is proposing to add paints and thinners in the list of paints and thinners previously submitted

. This change will result in increas e in emissions of PM, PM 10 

### , PM 2.5 

### , and HAPs. ThisAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 5 Trinity Consultants 

### change will impact the drilling as well as the well completion scenario. The Material Safety Data Sheets (MSDS) for additional paints and thinners are provided in the Appendix G.

Since the regulatory requirement s and BACT determinations were already provided to EPA previously, this submittal does not address them again.

Table 1

- 3 below, summarizes changes proposed in this addendum, their impacts on total Potential to Emit (PTE) for the p roject, affected pollutants, and affected operating scenario.

**T ABLE**  

### 1

**- 4**  **A DDENDUM**  

### S **UMMARY OF** 

### C **HANGES**



### Emission **ID NEW/**  **MODIFIED**

**Source Increase in Total**  **PTE? Affected Pollutant(s)** * **Affected Operating Scenario** 

DR

- WO

- 01 NEW Yes PM/PM 2.5 

### /PM 10 

### and HAPs Drilling and all Well Completion Scenario DR

- VS

- 01 NEW Yes ALL Drilling Scenario
DR

- VS

- 02 NEW Yes ALL Drilling Scenario
DR

- VS

- 03 NEW Yes ALL Drilling Scenario
DR

- VS

- 04 NEW Yes ALL Drilling Scenario
DR

- VS

- 05 NEW Yes ALL Drilling Scenario SB

- VS

- 01 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 02 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 03 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 04 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 05 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 06 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 07 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 08 NEW No NOT APPLICABLE NOT APPLICABLE SB

- VS

- 09 NEW No NOT APPLICABLE NOT APPLICABLE

DR

- WC

- 09 NEW Yes ALL Well Completion Scenario 4

DR

- WC

- 10 NEW Yes ALL Well Completion Scenario 4

DR

- AC

- 01 MODIFIED Yes ALL Drilling and all Well Completion Scenario

DR

- AC

- 02 MODIFIED Yes ALL Drilling and all Well Completion Scenario DR

- GE

- 07 MODIFIED No NOT APPLICABLE NOT APPLICABLE

DR

- PO

- 01 MODIFIED Yes PM/PM 2.5 

### /PM 10 

### and HAPs Drilling and all Well Completion Scenario

Several

-- Yes ALL All Well Completion Scenario

* ALL = PM/PM 2.5 /PM 10 , NO x , VOC, CO, HAPs, GHGs, P b, SO 2 , H 2 SO 4 , and HAPs **(DR) Drilling operation; (WC) Well CompletionAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 6 Trinity Consultants 

## 1.2. CONTENTS OF THE APPLICATION ADDENDUM

This application addendum includes the following:

Section 2

– Emission Calculations: contains the discussion of emission calculation methodology for all additional sources and operations in this application addendum; Section 3

– Regulatory Applicability Analysis: contains the air regulatory applicability analysis for all additional emission sources related to the proposed well evaluation and welding operations; Section 4

– BACT Analysis: contains the BACT review for all additional emission sources in this application addendum; Section 5

– Air Dispersion Modeling Analysis; Section 6

– Part 71 Forms; and Appendices

• Appendix A

– Emission Calculations

• Appendix B

– RBLC Search R esults

• Appendix C

– Specification Sheets

• Appendix D

– Air Dispersion Modeling

• Appendix E

– Revised response to Question no. 8

• Appendix F

– Drilling Scenario Operations and Emissions

• Appendix G

– Revised Drilling ScenarioAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 7 Trinity Consultants 

## 2. **EMISSIONS CALCULATIO NS** 

This secti on presents a summary of the emissions calculation methodologies, emission factors, and operating parameter assumptions used in developing emissions calculations for the well evaluation engines, wire line engines, and welding activities. The detailed emiss ions calculations are included in Appendix A of this application.



## 2.1. ‘EQUIVALENCY’ DETERM INATION

As discussed in the application submitted in December 2012, Anadarko will operate various emission units for which exact specifications are not available at this time due to scheduling and other contractual agreements that will be completed in the future. Therefore, Anadarko has proposed the worst case emission units to develop the potential emission (PTE) calculations while maintaining sufficient operational flex ibility to provide Anadarko the ability to utilize various, ‘equivalent’ operational equipment. Also, Anadarko proposes the demonstration of ‘equivalency’ based on the following factors:

Equal or lower mass emissions for each criteria, toxic, and other regulated air pollutants on a short

term (e.g., lbs/hr and lbs/day) and a long

- term (e.g., ton/year) basis; Compliance with applicable regulations (e.g., 40 CFR 60, 40 CFR 63); Compliance with applicable certifications (e.g., EPA Tier II, IMO Tier II); an d Compliance with applicable BACT requirements identified for a representative equipment.

A list of equipment for which Anadarko is requesting above

- mentioned flexibility is provided below :

140 HP diesel fired well evaluation engines on the drillship ( DR

- VS

- 01

– DR

- VS

- 05) ; 140 HP diesel fired well evaluation engines on the support vessel (SB

- VS

- 01

– SB

- VS

- 05) 360 HPdiesel fired well evaluation engines (SB

- VS

- 06

- SB

- VS

- 07) ; 62 HP diesel fired crane engine (SB

- VS

- 08) ; 130 HP diesel fired crane engine (SB

- VS

- 09) ; 275 HP wire line engines (DR

- WC

- 09

– DR

- WC

- 10) ; and, Welding activities (DR

- WO

- 01)

.



## 2.2. EMISSIONS ESTIMATION

The emissions sources with regard to this application addendum include diesel fired well evaluation engines; crane motor engines, and welding activities.



## 2.2.1. Diesel Fired Well Evaluation Engines on the drillship (DR

- VS

- 01 through DR

VS

- 0 5 )

The well evaluation operation on the drillship involves five Detroit 4

- 71 140 HP, diesel fired engines

. . The specification s hee t is provided in Appendix C . Emissions are generated as a result of combustion of diesel fuel in the engines.

**Emissions Factors**

– The sources of emission factors used to estimate emissions for the well evaluation operation related diesel engines are sum marized below.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 8 Trinity Consultants 

### AP

**- 42, Section 3.3.**  **Gasoline and Diesel Industrial Engines**

**–** Particulate matter (PM, PM 10 

### , and PM 2.5 

### ) and HAPs emission estimates for the diesel

- fired well evaluation engines are based on AP

- 42, Section 3.3 emission factors. Based on AP

- 42 guidance, all of the particulate matter is assumed to be less than 1 μm. Therefore, it is assumed PM 2.5 

### = PM 10 

### = PM. All of the TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors . An average BSFC of 7,000 Btu/hp

- hr has been used to convert emission factors from lb/MMBtu to lb/hp

- hr. For the large capacity diesel fired engines (Caterpillar 3406C), the NO x 

### , CO, and VOC emissions are also estimated based on AP

- 42, Section 3.3.

**Manufacturer Specifications**

**–** NO x 

### , CO, and VOC emissions estimates for the proposed engines are based on the emission factors from the specification sheet provided by the engine manufactu rer. Please refer to Appendix C of this application.

**EPA Guidance D ocuments** 

**–** Lead emission factor is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds , EPA 454/R

- 98

- 006, May 1998, Section 5.2.2. Emission factor for distillate oil

- fired gas turbines was use d as a surrogate for distillate oil

- fired engines due to lack of emission factors.

**EPA Regulations**

– CO 2 

### , CH 4 

### and N 2 

### O emission factor s are obtained from 40 CFR 98 Subpart C

, Table C

- 1 ( Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel ) and Table C

- 2 (Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel ). Emission factor for CO 2 

### e has been calculated using the global warming potentials (GWPs) obtained from 40 CFR 98 Subpart A.

**Mass Balance**

– Anadarko is proposi ng the use of ultra

- low sulfur diesel (ULSD) fuel for all diesel combustion sources. Therefore, SO 2 

### emissions are calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to sulfuric acid (H 2 

### SO 4 

### ) mist based on Section 4.1.1 of Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines , EPA420

- R

- 03

- 008, April 2003. Emissions of Hydrogen sulfide (H 2 

### S), total reduced sulfur (TRS), and reduced sulfur compounds resulting from sulfur content in the fuel are negligible.

**Operating Parameters**

– The maximum hourly , daily and annual emissions from the well evaluation related engines are calculated based on the foll owing operating parameters.

**Maximum Hourly Emissions**

– Maximum hourly emissions for the well evaluation engines are calculated based on the corresponding engine rating s at 100% load.

**Maximum Daily Emissions**

– Maximum daily emissions for the well evaluation engines are calculated based on 24 hours of operation per day, on the corresponding engine rating s at 100% load.

**Annual Emissions**

– Annual emissions for the well evaluation engines are calculated based on the corresponding engine rating s 100% load , and an annual operatin g time of 1 25 hours per engine.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 9 Trinity Consultants 

## 2.2.2. Diesel Fired Well Evaluation E ngines on the support vessel( SB

- VS

- 01 through SB

- VS

- 09)

Well evaluation on the support vessel involves five Detroit 4

- 71 140 HP, diesel fired engines , two Caterpill ar 3406C 360 HP, diesel fired engines , one 62 HP crane engine , and one 130 HP crane engine

. The specification sheet s are provided in Appendix C. Emissions are generated as a result of combustion of diesel fuel in the engines.

**Emissions Factors**

– The so urces of emission factors used to estimate emissions for the well evaluation operation related diesel engines are summarized below.

**AP**

**- 42, Section 3.3.**  **Gasoline and Diesel Industrial Engines**

**–** Particulate matter (PM, PM 10 

### , and PM 2.5 

### ) and HAPs emission estimates for the diesel

- fired well evaluation compressor engines are based on AP

- 42, Section 3.3 emission factors. Based on AP

- 42 guidance, all of the particulate matter is assumed to be less than 1 μm. Therefore, it is assumed PM 2.5 

### = PM 10 

### = PM. All of the TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. An average BSFC of 7,000 Btu/hp

- hr has been used to convert emission factors from lb/MMBtu to lb/hp

- hr. For the large capacity diesel fired engines (Caterpillar 3406C), the NO x 

### , CO, and VOC emissions are also estimated based on AP

- 42, Section 3.3.

**Manufacturer Specifications**

**–** NO x 

### , CO, and VOC emissions estimates for the proposed engines are based on the emission factors from th e specification sheet provided by the engine manufactu rer. Please refer to Appendix C of this application.

**EPA Guidance Documents**

**–** Lead emission factor is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead an d Lead Compounds , EPA 454/R

- 98

- 006, May 1998, Section 5.2.2. Emission factor for distillate oil

- fired gas turbines was used as a surrogate for distillate oil

- fired engines due to lack of emission factors.

**EPA Regulations**

– CO 2 

### , CH 4 

### and N 2 

### O emission factor s are obtained from 40 CFR 98 Subpart C

, Table C

- 1 (Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel ) and Table C

- 2 (Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel ). Emission factor for CO 2 

### e has been calcul ated using the global warming potentials (GWPs) obtained from 40 CFR 98 Subpart A.

**Mass Balance**

– Anadarko is proposing the use of ultra

- low sulfur diesel (ULSD) fuel for all diesel combustion sources. Therefore, SO 2 

### emissions are calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to sulfuric acid (H 2 

### SO 4 

### ) mist based on Section 4.1.1 of Draft Regulatory Impact Analysis: Con trol of Emissions from Nonroad Diesel Engines , EPA420

- R

- 03

- 008, April 2003. Emissions of Hydrogen sulfide (H 2 

### S), total reduced sulfur (TRS), and reduced sulfur compounds resulting from sulfur content in the fuel are negligible.

**Operating Parameters**

– T he maximum hourly , daily and annual emissions from the well evaluation operation related engines are calculated based on the following operating parameters.

**Maximum Hourly Emissions**

– Maximum hourly emissions for the well evaluation engines and crane engines are calculated based on the corresponding engine rating s at 100% load.

**Maximum Daily Emissions**

– Maximum daily emissions for the well evaluation engines and crane engines are calculated based on 24 hours of operation per day, on the cor responding engine rating sAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 10 Trinity Consultants 

### at 100% load. Although the 130 HP crane engine would only operate for 2 hours during a 24

- hour survey, 24 hour continuous operations is used in the emissions estimation as a conservative approach.

**Annual Emissions**

– Annual emiss ions for the well evaluation engines and crane engines are calculated based on the corresponding engine rating s 100% load , and an annual operatin g time of 1 25 hours per engine.



## 2.2.3. Welding Operations ( DR

- WO

- 01 )

Anadarko proposes to carry out welding operations as part of the maintenance activities on the drillship. The proposed welding activity will use 50 lbs of welding rods per day, and 208 days per year.

**Emissions Factors**

– The source of emission factors used to estimate emissions for the welding operation is summarized below.

**AP**

**- 42, Section**  **12.19 Electric Arc Welding**

– PM 10 

### and HAPs emissions es timates for the proposed welding activity are based on AP

- 42, Section 12.19 emission factors (Table 12.19

- 1). PM and PM 2.5 

### emissions are assumed to be same as PM 10


### .
**Operating Parameters**

– The project emissions from the welding operations are calculated based on the following operating parameters.

**Maximum Hourly Emissions**

– Maximum hourly emissions for the welding operation s are calculated based on the expected operating hours and the daily usage of the welding rods (50 lb/day, and 24 hrs/day)

.

**Maximum Daily**  **Emissions**

– Maximum daily emissions for the welding operations are calculated based on the daily usage of the welding rods

.

**Annual Emissions** 

– Pr oject emissions for the welding operations are calculated based on the daily usage of the welding rods, and annual operational days (208 days/yr).



## 2.2. 4 Diesel Fired Air Compressor Engines (DR

- AC

- 01 and DR

- AC

- 02)

Emission c alcu lation methods shall remain the same as in the Spirit EGOM PSD/Title V Permit Application dated 21 December 2012. T he status of emergency air compressor diesel engines is now updated to nonemergency air compressor diesel engines due to the change in the proposed annual operating hours

.



## 2.2. 5 Well Completion Wire line Engines (DR

- WC

- 0 9 and DR

- W C

- 10 )

Emission c alculation methods shall remain the same as that of DR

- WL

- 01 and DR

- WL

- 02 in the Spirit EGOM PSD/Title V Permit Application dated 21 December 2012.

**Operating Parameters**

– The maximum hourly , daily and annual emissions from the se wire line engines are calculated based on the following operating parameters.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 11 Trinity Consultants 

### Maximum Hourly Emissions

– Maximum hourly emissions are calculated based on the engine operating at 100% load.

**Maximum Daily Emissions**

– Maximum daily emissions for the se engines are calculated based on 24 hours of operation per day and assuming the operation at 100% load.

**Annual Emissions**

– Annual emissions for the se engines are calcula ted based on 1,440 hours of operation per year and assuming the operation at 100% load.



## 2.2.6 Painting Operations (DR

- PO

- 0 1 )

Emission calculation methods as well as material usage shall remain the same as that of DR

- PO

- 01 in the Spirit EGOM PSD/Title V Per mit Application dated 21 December 2012. Anadarko is proposing to add paints and thinners to existing scenario.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 12 Trinity Consultants 

## 3. **REGULATORY APPLICABI LITY ANALYSIS** 

This section of the application provides a review of pertinent federal air quality regulations that potentially apply to the emission sources associated with the proposed project. As the proposed project will be carried out beyond 25 miles of the nearest States’ seaward boundaries, it will be outside of the corresponding state and local regulatory jurisdictions and will not be subject to any state or local regulations. In this section, regulatory applicability analysis is addressed for the new sources wit h regard to this application addendum. Regulatory analyses for other sources are covered in the application submitted in December 2012.



## 3.1. NEW SOURCE PERFORMAN CE STANDARDS (NSPS)

NSPS require new, modified, or reconstructed sources in applicable source categ ories to control emissions to the level achievable by the best

- demonstrated technology as specified in the applicable provisions. A regulatory applicability determination and a summary of potentially applicable NSPS subparts for the equipment associated w ith the proposed EGOM Exploratory Project operations are provided in the following subsections.



## 3.1.1. **40 CFR 60 Subpart A**

**– General Provisions** 
All affected sources subject to an NSPS are also subject to the general provisions of NSPS Subpart A unless specifically excluded by the source

- specific NSPS. NSPS Subpart A requires the following of facilities subject to a source

- specific NSPS:

Initial construction/reconstruction notification Initial startup notification Performance tests Performance test dat e initial notification General monitoring requirements General recordkeeping requirements Semiannual monitoring system and/or excess emission reports General control device and work practice requirements

Source

- specific NSPS provisions can supersede NSPS Subpart A as noted in the relevant NSPS Subpart.



## 3.1.2. **40 CFR 60 Subpart IIII**

**– Stationary Compression Ignition Internal Combustion**  **Engines**
NSPS Subpart IIII, Standards of Performance for Stationary Compression Ignition Internal Combustion Engines , provides stan dards for manufacturers, owners, and operators of stationary compression ignition (CI) internal combustion engines (ICE). This subpart provides standards for owners and operators of stationary CI ICE that commence construction after July 11, 2005 where th e stationary IC engines are:

Manufactured after April 1, 2006 and are not fire pump engines [40 CFR 60.4200(a)(2)(i)]; or Manufactured as a certified National Fire Protection Association NFPA) fire pump engine after July 1, 2006 [40 CFR 60.4200(a)(2)(ii) ].Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 13 Trinity Consultants 

### This subpart is also applicable to owners and operators of stationary CI ICE that modify or reconstruct their stationary CI ICE after July 11, 2005 [40 CFR 60.4200(a)(3)].



### 3.1.2.1. **Well Evaluation Engines**

**– Drillship**  **( DR** 

**- VS** 

**- 01 through DR** 

**- VS** 

**- 05**  **)**
Per 40 CFR 60.4200(a)(2)(i), all the CI engines are not subject to this regulation because the engines were not manufactured after April 1, 2006. Also, these engines were not constructed, modified, or reconstructed after July 11, 2005. However, these eng ines are for representation purposes only, and Anadarko may replace these engines with substitute engines with equal or lesser emissions. Therefore, in cases where the substitute engines are subject to 40 CFR 60 Subpart IIII, Anadarko will comply with all applicable requirements.



### 3.1.2.2. **Well Evaluation Engines**

**- Support Vessels**  **( SB** 

**- VS** 

**- 01 through SB** 

**- VS** 

**- 09**  **)** The well evaluation engines, and crane motor engines on the support vessels will not operate while physically connected to the drill ship. Therefore, these engi nes are not subject to NSPS Subpart IIII regulations.



### 3.1.2.3. **Wire Line Engines**

**– Drillship**  **(DR**

**- W**  **C**

**- 0**  **9 and DR** 

**- W**  **C**

**- 10**  **)**
Per 40 CFR 60.4200(a)(2)(i), all the CI engines are not subject to this regulation because the engines were not manufactured after April 1, 2006. Also, these engines were not constructed, modified, or reconstructed after July 11, 2005. However, these engines are for representation purposes only, and Anadarko may replace these engines with substitute engines with equal or lesser emissions. Therefor e, in cases where the substitute engines are subject to 40 CFR 60 Subpart IIII, Anadarko will comply with all applicable requirements

.



### 3.1.2.4. **Air Compressor Engines**

**– Drillship**  **(DR**

**- AC** 

**- 01 and DR** 

**- AC** 

**- 02)** 
Per 40 CFR 60.4200(a)(2)(i), all the CI engines are not subjec t to this regulation because the engines were not manufactured after April 1, 2006. Also, these engines were not constructed, modified, or reconstructed after July 11, 2005.

**T ABLE**  

### 3

**- 1**  **M ANUFACTURE**  

### D **ATES FOR** 

### E **N GINES ON**  

### D **RILLSHIP**



### Emission ID **Manufacturer and Model Date of Manufacture** 
DR

- VS

- 01 through DR

- VS

- 05 Detroit 4

- 71 Before 2000
DR

- WC

- 09 and DR

- WC

- 10 Cummins C8.3 Unknown*
DR

- AC

- 01 Sperre M

- HL2/140 1997
DR

- AC

- 02 Sperre M

- HL2/140 1997

*For the wire line engines (DR

- WC

- 09 and DR

- WC

- 10), the model years and compliance certificates will be submitted to EPA Region 4 once the specific engines have been determined.



## 3.1.3. **40 CFR 60 Subpart JJJJ**

**– Stationary Spark Ignition Internal Combustion**  **Engines**

NSPS Subpart JJJJ, Standards of Performance for Stationary Spark Ignition Internal Combustion Engines

, provides standards for manufacturers, owners, and operators of stationary spark ignition (SI) ICE. For emergency engines with a maximum power greater than 25 HP, this sub part provides standards for owners and operators of stationary SI ICE that commence construction after June 12, 2006, where theAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 14 Trinity Consultants 

### stationary SI ICE are manufactured on or after July 1, 2009 [40 CFR 60.4230(a)(4)(iv)]. This subpart is also applicable to owne rs and operators of stationary SI ICE that modify or reconstruct their stationary SI ICE after June 12, 2006 [40 CFR 60.4230(a)(5)].

There are no stationary SI engines proposed for this project. Therefore, NSPS Subpart JJJJ does not apply to any source i ncluded in this permit application.



## 3.2. NATIONAL EMISSION ST ANDARDS FOR HAZARDOU S AIR POLLUTANTS (40 CFR PART 61)

Per 40 CFR 55.13(e), 40 CFR Part 61 together with any other provisions promulgated pursuant to section 112 of the Clean Air Act shall apply to OC S sources if rationally related to the attainment and maintenance of federal or state ambient air quality standards or the requirements of part C of title I of the Clean Air Act (PSD). 

### There are no subparts under the 40 CFR Part 61 that applies to the exp loratory drilling operations proposed in this application.



## 3.3. NATIONAL EMISSION ST ANDARDS FOR HAZARDOU S AIR POLLUTANTS (40 CFR PART 63)

Per 40 CFR 55.13(e), 40 CFR Part 61 together with any other provisions promulgated pursuant to section 112 of the Clean Air Act shall apply to OCS sources if rationally related to the attainment and maintenance of federal or state ambient air quality stand ards or the requirements of part C of title I of the Clean Air Act (PSD).

The National Emission Standards for Hazardous Air Pollutants ( NESHAP s) apply to major sources of HAP or specifically designated area sources of HAP. A HAP major source is defined as having potential emissions in excess of 10 tons per year for any individual HAP and/or 25 tons per year for total HAPs. The proposed project r esults in an area source of HAP, because potential HAP emissions are less than the major source thresholds. Potentially applicable NESHAP subparts are discussed below.



## 3.3.1. **40 CFR Part 63 Subpart A**

**– General Provisions** 

All affected sources are subject to the g eneral provisions of Part 63 NESHAP Subpart A unless specifically excluded by the source

- specific NESHAP. These provisions include initial notification and performance testing, recordkeeping, reporting, monitoring, and control device and work practice
sta ndards for all other subparts as applicable.



## 3.3.2. **40 CFR 63 Subpart ZZZZ**

**- Stationary Reciprocating Internal Combustion**  **Engines**

NESHAP Subpart ZZZZ, National Emission Standards for Hazardous Air Pollutants for Stationary Reciprocating Internal Combustion Engi nes , provides emission limitations and operating limitations for HAPs emitted from stationary reciprocating internal combustion engines (RICE) located at major sources and area sources of HAP emissions. Anadarko’s proposed exploratory drilling operations in this application will be an area source for HAPs and therefore potentially subject to applicable requirements of this subpart for area sources.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 15 Trinity Consultants 

### 3.3.2.1. **Engines Located on the Drillship** 

**– (**  **DR**

**- VS** 

**- 01 t**  **hrough DR** 

**- VS** 

**- 05, DR** 

**- WC** 

**- 09 and DR** 

**** **WC**

**- 10, DR** 

**- AC** 

**- 01 and DR** 

**- AC** 

**- 02**  **)**
Per 40 CFR 63.6590(a)( 1 )(iii), stationary RICE located at an area source of HAP emissions would be defined as an existing source under the requirements of this Subpart if the construction of the stationary RICE is commenced before June 12, 2006. Therefore, the five (5) 140 HP well evaluation engines on the drillship are classified as existing non

- emergency stationary CI RICE located at an area source. The two (2) 275 HP wire line engines on the drillship are classified as existing non

- emergency s tationary CI RICE located at an area source. The two (2) 15 HP and 18 HP air compressor engines on the drillship are classified as existing non

- emergency stationary CI RICE located at an area source.

The nine (9 ) engines (DR

- VS

- 01 to DR

- VS

- 05

, DR

- WC

- 09 a nd DR

- WC

- 10, DR

- AC

- 01 and DR

- AC

- 02 ) all have site ratings less than 300 HP. For non

- emergency, non

- black start CI stationar y RICE rated 300 HP or less, t hese engines will be subject to the following requirements:

Operate and maintain the stationary RICE and after

- treatment control device (if any) according to the manufacturer's emission

- related written instructions or develop own maintenance plan which provides to the extent practicable for the maintenance and operation of the engine in a manner consisten t with good air pollution control practice for minimizing emissions [40 CFR 63.6625(e)]. Minimize the engine's time spent at idle during startup and minimize the engine's startup time to a period needed for appropriate and safe loading of the engine, not t o exceed 30 minutes, after which time the non

- startup emission standards apply [40 CFR 63.6625(h)]. Comply with the recordkeeping requirements of 40 CFR 63.6655(e). Comply with the management practices applicable requirements in Table 2d of this Subpart:

• c hange oil and filter every 1,000 hours of operation or annually, whichever comes first;

• inspect air cleaner every 1,000 hours of operation or annually, whichever comes first, and replace as needed; and

• inspect all flexible hoses and belts every 500 hours o f operation or annually, whichever comes first, and replace as needed. Per 40 CFR 63.6660, records of management practices discussed above need to be kept in readily accessible hard or electronic form for at least 5 years following the date of each mainten ance activity. At a minimum, the most recent 2 years of data shall be retained on site and the remaining 3 years of data may be retained off site

.



### 3.3.2.2. **Engines Located on the Supply**  **Boat**

**– (**  **SB**

**- VS** 

**- 01 through**  **SB**

**- VS** 

**- 09)**  The well evaluation engines, and craneengines on the support vessels are not operated while physically connected to the drillship. Therefore, these engines a re not subject to this regulation

.



## 3.3.3. **40 CFR 63 Subpart XXXXXX**

**– Area Source Standards for Nine Metal**  **Fabrication and Finishing Source Categories**
NESHAPs Subpart XXXXXX provides national emission limitations and operating limitations for HAPs emitted from miscellaneous metal fabrication and finishing operations performed at area sources of HAP emissions. Anadarko’s proposed exploratory drilling operations will be an area source for HAPs and therefore this Subpart would be potentially applicable. The welding operation performed on theAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 16 Trinity Consultants 

### drillship is part of the routine maintenance to ensure that the drillsh ip functions in its intended capacity. Therefore, this activity meets the definition of “facility maintenance” provided in 40 CFR 63.11522. Pursuant to 40 CFR 63.11514(f), welding operations , as a facility maintenance function on the drillship,
are not s ubject to the requirements of this regulation.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 17 Trinity Consultants 

## 4. **BACT ANALYSIS**

As required by 40 CFR §52, Best Available Control Technology (BACT) must be applied to reduce or eliminate air emissions from a new or modified facility. PSD BACT is defined 40 CFR §52.21(b)(12) as:

“An emissions limitation (including a visible emission standard) based on the maximum degree of reduction for each pollutant subject to regulation under Act which would be emitted from any proposed major stationary source or major modification which the Administrator, on a case

- by

- case basis, taking into account energy, environmental, and economic impacts and other costs, determines is achievable for such source or modification through application of production processes or available methods, systems, and techniques, including fuel cleaning or treatment or innovative fuel combustion techniques for control of such pollutant. In no event shall application of best available control technology result in emissions of any pollutant, which would exceed the em issions allowed by any applicable standard under 40 CFR parts 60 and 61. If the Administrator determines that technological or economic limitations on the application of measurement methodology to a particular emissions unit would make the imposition of a n emissions standard infeasible, a design, equipment, work practice, operational standard, or combination thereof, may be prescribed instead to satisfy the requirement for the application of best available control technology. Such standard shall, to the d egree possible, set forth the emissions reduction achievable by implementation of such design, equipment, work practice or operation, and shall provide for compliance by means which achieve equivalent results.”

EPA has developed a “top

- down” process that can be used to ensure that a BACT analysis satisfies the applicable legal criteria. Presented below are the five basic steps of a top

- down BACT review as identified by the EPA. 1



### STEP 1

**– IDENTIFY ALL CONTROL**  **TECHNOLOGIES** Step 1 of the top

- down approach r equires that all available control options that are potentially applicable to the proposed source are identified. It is the applicant’s responsibility to identify available control options by consulting the EPA’s Reasonably Available Control Technology ( R ACT ) /BACT/ Least Achievable Emission Rate ( LAER ) clearinghouse (RBLC) , along with other reliable sources. Viable control options are those technologies that have a practical potential for application to the emissions unit and the regulated pollutant under evaluation.

**STEP 2**

**– ELIMINATE TECHNICALL**  **Y INFEASIBLE OPTIONS** Step 2 of the top

- down approach allows for the elimination of control options that are technically infeasible. Also, each technology should be “demonstrated” (previously installed and operated successfully on a similar facility); or if undemonstrated, then the applicant must determine whether the technology is both “available” and “applicable.” Technologies identified in Step 1 that are neither demonstrated nor found to be both available and a pplicable are eliminated under Step 2.

**STEP 3**

**– RANK REMAINING CONTR**  **OL TECHNOLOGIES** Step 3 of the top

- down approach requires ranking of the remaining control technologies based on control effectiveness. If there is only one remaining option or if all of the remaining technologies could achieve equivalent control efficiencies, ranking based on control efficiency is not required.

**STEP 4**

**– EVALUATE MOST EFFECT**  **IVE CONTROLS**

1 U.S. EPA. Draft New Source Review Workshop Manual , Chapter B. Research Triangle Park, North Carolina, October 1990.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 18 Trinity Consultants 

### Step 4 of the top

- down approach allows for the elimination of control options based on collateral impacts. In descending order, the applicant should evaluate and compare the collateral impacts of each control option. The permitting authority (EPA) has di scretion on weighting each area of collateral impact. This step validates the suitability of the top control option identified or provides a clear justification as to why the top option should not be selected as BACT. Costs of installing and operating

co ntrol technologies are estimated and annualized following the methodologies outlined in the U.S. EPA’s OAQPS Control Cost Manual (CCM). 2



### STEP 5

**– SELECT BACT**  Step 5 of the top

- down approach requires selection of BACT for the emissions unit and the regulat ed pollutant under evaluation. The most effective control alternative not eliminated in Step 4 is selected as BACT with a corresponding emission limit established . The selection of BACT in the fifth step involves an evaluation of emission rates achievabl e with the selected control technology. BACT is an emissions limit unless technological or economic limitations of the measurement methodology would make the imposition of an emissions standard infeasible, in which case a work practice or operating standa rd can be imposed. Selected BACT can be no less stringent than an applicable NSPS, MACT, or RACT.

The emissions of NO x 

### , CO, PM, PM 10 

### , PM 2.5 

### , and VOC exceed the applicable SERs. Therefore PSD BACT must be determined for each emission unit at the facility that emits NO x 

### , CO, PM, PM 10 

### , PM 2.5 

### , or VOC when conducting the proposed drilling.

The well evaluation engines, ROV Generator engine on the supply boat, and crane motor engines on the support vessels are not operated while physically connected to the drillship. Therefore, these engines are not subject to BACT review.



## 4.1. AIR COMPRESSOR ENGIN ES (DR

- AC

- 01 AND DR

- AC

- 02)

- BACT ANALYSIS

Air compressor d iesel eng ines (DR

- AC

- 01 and DR

- AC

- 02) BACT analysis can be found in the Discoverer Spirit EGOM PSD/Title V Permit Application submitted in December 2012 and associated responses submitted to EPA in March and April 2013

. The proposed changes in hours from 100 to 1 0 4 result in a negligible increase in emissions. The proposed operating time for this engine is 0.5 hr/day and 104 hrs/year. Given the engine’s minimal operating time, the resulting emissions are minimal. For example, NO x 

### emissions are less than 0.0 4 tpy . Given the minimal operations of this equipment resulting in low emissions, Anadarko believes that replacement of existing emergency engine with the cleanest available engine is cost prohibitive as specified in Anadarko’s response to EPA’s Incom pleteness Determination Letter submitted in April 2013.



## 4.2. WIRE LINE ENGINES (DR

- WC

- 0 9 AND DR

- WC

- 1 0)

- BACT ANALYSIS

Wire line diesel engines (DR

- WL

- 01 and DR

- WL

- 02) BACT analysis can be found in the Discoverer Spirit EGOM PSD/Title V Permit Application submitted in December 2012 and associated responses submitted to EPA in March and April 2013

. Anadarko proposes to use these wire line engines during well completion operating scenario 4. For w ire line engine s , the cleanest available engine was found to be EPA Tier III or Tier IV certified. However, upon further investigation, the vendors noted that EPA Tier III and Tier IV certified engines constitute a small percentage (i.e., approximately less than 20%) of the total inventory.

2 Office of Air Quality Planning and Standards (OAQPS), EPA Air Pollution Control Cost Manual , Sixth Edition, EPA 452

- 02

- 001 (http://www.epa.gov/ttn/catc/products.html#cccinfo), Daniel C. Mussatti & William M. Vatavuk, January 2002.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 19 Trinity Consultants 

### Due to constantly changing schedules during the proposed operations, the availability of these third party engines changes on short notice. Hence, it is difficult to determine which specific engine would be brought onboard on any giv en day. Since availability of the EPA Tier III and Tier IV engines is limited, there is no guarantee that these engines will be available when Anadarko would need them. Restricting these third party engines to EPA Tier III or Tier IV certified engines wi ll significantly impact the operations. Since EPA Tier II certified engines are more readily available for these engine categories, Anadarko proposes the use of EPA Tier II certified engines for the Wire line engines to meet BACT requirements as specified in Anadarko’s response to EPA’s Incompleteness Determination Letter submitted in April 2013.



## 4.3. WELL EVALUATION ENGI NES ON THE DRILLSHIP ( DR

- VS

- 01 THROUGH DR

- VS

- 05 )

- BACT ANALYSIS

4.3.1. **NOx BACT Analysis**

**Step 1**

**– Identify all Control Technologies** 

EPA's RBLC search was used to obtain potential control t echnologies for NO x 

### from smaller diesel eng in es (< 500 hp) and review of the permits recently proposed/issued by U.S. EPA Region 4 and Region 10 (and corresponding permit applications) for similar OCS sources wa s conducted to obtain potential control technologies for NO x 

### from smaller engines. The most recent 10

- year period was used to identify applicable control technologies. The results of the RBLC search are included in Appendix B. The search results for pot ential control technologies for NO x 

### from smaller diesel engines are listed below.

DWI (Direct Water Injection) EGR (Exhaust Gas Recirculation) Derate Engines H/E process (w ater

- in

- fuel Homogenization and Emulsification) Intake Air Humidification/Cooling NO x 

### Adsorber/Scrubber Technology Replacement of Older Engines with Newer Engines CAM Shaft Replacement/ Re

- tooling of Engines LNC (Lean NO x 

### Catalysts) or HC

- SCR (Hydrocarbon Selective Catalytic Reduction) LNE (Low NO x 

### Emissions Engine) design including ( Turbo

- charger with after coolers

, intercoolers, and h igh injection pressure) EPA Tier 2 Standards 4

- Way Catalyst Converter GCP (Good Combustion Practices) ITR (Ignition Timing Retard)



### Step 2

**– Eliminate Technically Infeasible Options** 

**DWI**

– Infeasible. The control technology involves reduction in combustion temperature by mixing steam or water with the air flow. Steam or water acts as a heat sink to reduce peak temperatures, thereby reducing the formation of NO x 

### . NO x 

### reductions of 25

- 35 percent can be ach ieved with water injection. 3

3 Based on Memorandum fr om Tanya Parise, Alpha

- Gamma Technologies, Inc. to Sims Roy, EPA OAQPS ESD Combustion Group, titled NOx Control Technologies for Stationary Diesel ICE

.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 20 Trinity Consultants 

### This technology is in development stages for marine applications. Moreover, this technology is not considered feasible for smaller engines such as well evaluation engines. Ample supply of fresh water is necessary for this NO x 

### reduction technology. Introducing salt water into the engine could result in serious deterioration due to corrosion and fouling. For this reason, implementing this strategy would require either production of fresh water through the use of desalination or distillation system or the storage of fresh water on board. Therefore, either pure water storage tanks would need to be constructed or the alternative of installing a desalination or distillation unit would incur additional costs for the unit. Both al ternatives would also require additional space and would potentially require recertification of the vessel.

Another concern with the use of water in the combustion process is the effect on PM emissions. The water in the cylinder reduces NO x 

### , which is formed at high temperatures, by reducing the temperature in the cylinder during combustion. However, PM oxidation is most efficient at high temperatures. Therefore, while water injection may lead to reduction in NO x 

### emissions, there may be an increase in PM emissions. There is also a potential for engine damage to occur as a result of the water contacting the combustion cylinder surface causing disintegration of lubricating oil film.

**EGR**

– Infeasible. Applying EGR to a stationary diesel RICE can reduce the power that is generated by the engine. This is because the EGR system reduces the specific heat ratio of the combustion gases in the power stroke, which in turn reduces the amount of power or work that can be extracted by the piston.

Applying EGR m ay also reduce the amount of fuel that is completely combusted thereby increasing the PM emission rate. In addition, use of EGR can increase engine oil acidity, which can result in inefficiency and increased engine wear which can reduce power and hinder o peration. This technology is not considered feasible for smaller engines such as well evaluation engines.

**Derate Engines**

– Infeasible

. An engine can be derated by restricting its operation to lower levels of power than normal for the given application. Derating reduces cylinder pressures and temperatures and can lower NO x 

### formation rates. Engine derating is accomplished by changing the injector nozzles with smaller holes to atomize the smaller amount of fuel used and the turbocharger nozzle rings can b e allowed a lower exhaust gas spin the turbocharger faster, thus compressing a greater volume of air for a given volume of gas.

Derating reduces the engine's operating temperature, which can result in higher CO and HC emissions. The primary concern assoc iated with derating the engines is that derating engines would reduce available power, which is required to perform necessary well evaluation operation. Hence derating is technically infeasible.

**H/E process**

– Infeasible

. Diesel and water emulsions were offered as a means of lowering the NO x 

### output from the engines. These emulsion systems have been shown to reduce NO x 

### by 15

- 20% in engines running heavy fuel oil (HFO). Running an engine on fuel

- water emulsions makes it theoretically possible to reduce NO x 

### emissions by up to 50%. 4

4 Based on Non

- Road Diesel Emission Reduction Study”.www.ecy.wa.gov/programs/air/PDFS/NonroadDieselStudy.pdfAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 21 Trinity Consultants 

### This technology would require derating of the engines, and emulsified diesel in marine vessels can cause fuel tank corrosion issues. Additionally, emulsified fuel systems were designed for and installed on slow

- speed engines bu rning heavy fuel oil.

These engines are designed and will be burning medium density fuel (diesel). Several significant engineering hurdles must be overcome in order to install a diesel/water emulsion system. Hence, this technology is considered as tec hnologically infeasible.

**Intake Air Humidification/Cooling**

– Infeasible

. Intake Air Humidification consists of “fogging” and/or saturation of the intake air with water. These motors consist of evaporating water into the relatively hot scavenging air, whi ch flows to the engine through the inlet air manifold. Installation of a Humid Air Motor (HAM) is an alternative to water injection currently being investigated by some diesel engine manufacturers.

H umidification can require additional storage capacity for freshwater that is not available on the drill rig. Quite high volumes of water need to be evaporated to create enough humid air to achieve the reductions sought, and are com parable with the fuel volumes. This technology is not commonly used for small er engines such as well evaluation engines. Therefore, considering the aforementioned reasons, Intake Air Humidification/ Cooling is not technically feasible.

**NO x**  

### Adsorber/Scrubber Technology

– Infeasible

. A NO x 

### adsorber is a catalyst technology used to remove NO x 

### in lean exhaust for diesel and gasoline fired engines. NO x 

### adsorbers consist of ceramic monolith containing parallel channels, coated with precious metal catalysts. During lean operation, NO x 

### is stored in the form of nitrates produced by react ions between the NO x 

### and catalyst. At regular intervals, a momentary reducing condition is produced inside the monolith by injecting reductant, causing the nitrates to decompose to nitrogen.

The technology is currently available for mobile gasoline engin es, but is still in the research and development phase for diesel engines. This technology has been used primarily for on

- road diesel applications or off

- road applications for smaller engines such as backhoes, graders, and wheel loaders, and is in develop ment stages for marine applications. While preliminary testing demonstrates promising results, the exhaust scrubbing and emissions reduction technology is still a technology that is in experimental stages of development. A considerable research and development is required to design a depl oyable system that is safe to operate on a drillship.

**Replacement of Older Engines with Newer Engines**

– Infeasible

. The five well evaluation diesel engines are pre

- 1998 engines and hence no engine certification is available. During one of the well evalua tion activities these five diesel engines will be used to send information to a logging unit powered by the Schlumberger E

- line engines (DR

- EL

- 01 and DR

- EL

- 02) and Wire line eng ines (DR

- WL

- 01 and DR

- WL

- 02). Since all of these engines are used to power di fferent equipment that is performing a single operation they are all leased from the same third party vendor to avoid compatibility issues. The third party vendor Anadarko leases its E

- line and Wireline engines from currently has no EPA Tier certified well evaluation engines in their fleet. Therefore, this is
not considered a viable BACT option.

**CAM Shaft Replacement/ Re** 

**- tooling of Engines** 

– F easible

. Clean Cam Technology Systems (CCTS) offers retrofit cam shaft reengineering kits for some diesel engines. The kits reduce NO x 

### emissions by increasing the volume of the residual exhaust gas that remains in the combustion chamber after the power stroke.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 22 Trinity Consultants 

### CCTS cam shaft retrofit (Re

- tooling) kits are available for Detroit Diesel engines (model series 71 or 92

. ) The “well evaluation” engines proposed in this application are Detroit Diesel engines (model series 71) and hence this technology considered feasible.

**LNC or HC** 

**- SCR** 

– Infeasible

. This technology is not typically not suitable for smaller portable engi nes such as well evaluation engines

. Also, LNC systems operate best at consistent high loads, and are not amenable to long periods of engine idle or load shifts.

**LNE Design**

– Infeasible

. Incorporation of this control technology will involve redesigning the engines, making this technology to be most feasibly installed when the engine is manufactured. Requiring this technology would essentially mean having to replace the existing well evalu ation compressor diesel engines with other air compressor diesel engines that have this technology already installed. This technology is intrinsic to the engine design and retrofitting the air compressor diesel engines is not an option.

**4**

**- Way Catalyst Co**  **nverter**

– Infeasible

. The well evaluation compressor diesel engines will not be able to sustain constant steady state loads/exhaust temperatures for sufficient time periods that are critical for high catalyst performance, resulting in inconsistent emission control. Several non

- combustible chemical elements that may be present in engine lube oils, such as phosphorous, lead and heavy metals, may collect over time and damage the catalyst. In addition, t he technology is in development stages for marine applic ations, and not available for the well evaluation compressor diesel engines

.

**ITR**

– Infeasible

. Changing ignition timing is not an alternative for these engines due to the intrinsic engine design. Alterations of the injection timing can impact value performance. Additionally, use of this technology can reduce engine power and combustion stabili ty that can hinder operations. For these reasons this technology is infeasible for these engines

.



### Step 3

**– Rank Remaining Control Technolog**  **ies by Control Effectiveness**

**T ABLE**  

### 4

**- 1**  **R ANKS OF**  

### T **ECHNOLOGIES** 

### F **EASIBLE FOR** 

### D **IESEL** 

### F **IRED** 

### E **NGINES**



### Technology **Efficiency Rank**  CAM Shaft Replacement/ Retooling of Engines various 1

Good Combustion Practices Baseline N/A

All feasible technologies for the diesel fired engines are listed in Table 4

- 1. Control technologies are ranked by efficiency in a descending order.



### Step 4

**– Evaluate Most Effective Controls and Document Results**  The proposed operating time for these engines is 1 04 hr s /year per engine . Given the engine’s minimal operating time, the resulting emissions are minimal. For example, NO X 

### emissions are less than 1 tpy. Therefore, Anadarko believes that detailed cost infeasibility is not warranted . Given the minimal operations of this equipment resulting in low emissions, Anadarko believes that CAM Shaft Replacement/ Retooling of the engines will be cost prohibitive.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 23 Trinity Consultants 

### Step 5

**- Select BACT** 

Anadarko proposes good combustion practices as NO x 

### BACT for the well evaluation diesel engines

. A summary of the proposed NO x 

### BACT emission limitation for each source associated with this application addendum is provided in Table 4

- 2 at the end of the section.



## 4.3.2. **CO BACT Analysis**

**Step 1**

**– Identify all Control**  **Technologies**
EPA's RBLC search was used to obtain potential control technologies for CO from smaller emergency diesel engines (< 500 hp) and review of the permits recently proposed/issued by U.S. EPA Region 4 and Region 10 (and corresponding permit applica tions) for similar OCS sources was conducted to obtain potential control technologies for CO from smaller engines. The most recent 10

- year period was used to identify applicable control technologies. The results of the RBLC search are included in Appendi x B. The search results for potential control technologies for CO from smaller diesel engines are listed below.

DOC (Diesel Oxidation Catalyst) CDPF (Catalyzed Diesel Particulate Filter) 4

- Way Catalyst Converter Replacement of older engines with new eng ines LNE Design Good combustion practices



### Step 2

**– Eliminate Technically Infeasible Options** 

**DOC**

– Infeasible. This control option is not technically feasible for use on well evaluation operation related diesel engines

, which only operate 104 hours during t he drilling period

. This technology requires constant steady state loads/exhaust temperatures for sufficient time periods that are necessary for high catalyst performance, resulting in limited control. Use of DOCs would also lead to some pressure drop ac ross exhaust flow resulting in back pressure on the engine that could cause plugging of the engine, thus posing safety concerns for the types of offshore operations proposed. Several non

- combustible chemical elements that may be present in engine lube oil s, such as phosphorous, lead and heavy metals, may collect over time and damage the catalyst in the DOC.

**CDPF**

– Infeasible. The catalyst in the CDPF filter reduces emissions of CO and THC by 90 percent but requires sufficient exhaust temperatures to facilitate regeneration by the catalyst. 5 

### CDPFs add backpressure on the engines that could cause plugging of the engine, thus posing safety concerns for the types of offshore operations proposed. The pressure drop will also cause a reduction in fuel econ omy. T he smaller engines such as well evaluation engines cannot typically sustain the high exhaust temperatures necessary for optimal regeneration of the catalyst.

**Replacement of Older Engines with Newer Engines**

– Infeasible

. Refer to the discussion in S ection 4.3.1.

5 Based on Sections 4.3, Alternative Control Techniques Document: Stationary Diesel Engines (Final Report) , Prepared For: Energy Strategies Group U.S. Environmental Protection Agency (EPA) Offi ce of Air Quality Planning and Standards, March 5, 2010.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 24 Trinity Consultants 

### 4

**- Way Catalyst Converter** 

– Infeasible

. Refer to the discussion in Section 4.3.1.

**LNE Design**

– Infeasible

. Refer to the discussion in Section 4.3.1.



### Step 3

**– Rank Remaining Control Technologies by Control Effectiveness** 

Good combustion practi ce s are the only feasible option. Therefore, ranking is not required.



### Step 4

**– Evaluate Most Effective Controls and Document Results** 
Good combustion practices are the only feasible option. Therefore, ranking is not required.



### Step 5

**- Select BACT** 
Anadarko proposes good combustion practices as CO BACT for the well evaluation compressor diesel engine s

.



## 4.3.3. **PM/PM 10**  

## /PM **2.5** 

## BACT Analysis
**Step 1**

**– Identify all Control Technologies**  EPA's RBLC search was used to obtain potential control technologies for PM/PM 10 

### /PM 2.5 

### from smaller emergency diesel engines (< 500 hp) and review of the permits recently proposed/issued by U.S. EPA Region 4 and Region 10 (and corresponding permit applications) for similar OCS sources was conducted to obtain potential control technolo gies for PM/PM 10 

### /PM 2.5 

### from smaller engines. The most recent 10

- year period was used to identify applicable control technologies. The results of the RBLC search are included in Appendix E

- 1. The search results for potential control technologies for PM/P M 10 

### /PM 2.5 

### from smaller diesel engines are listed below.

DOC CDPF PCV (Positive Crankcase Ventilation) 4

- Way Catalyst Converter Replacement of older engines with new engines LNE (Low NO x 

### Emissions Engine) design including ( Turbo

- charger with after coolers

, intercoolers, and h igh injection pressure) U L S D Fuel Good combustion practices



### Step 2

**– Eliminate Technically Infeasible Options** 

**DOC**

– Infeasible Refer to the discussion in Section 4.3.2.

**CDPF**

– Infeasible. Refer to the discussion in Section 4.3 .2.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 25 Trinity Consultants 

### PCV

– Infeasible. Installation of a PCV system involves changes to the design of the engines, making this technology to be most feasibly installed when the engine is manufactured. This technology is intrinsic to the engine design and retrofitting the engines is not an option. Furthermore, engine manufacturers have strict restrictions on installing upgrades to avoid violating warranty. Requiring this technology would essentially mean having to replace the existing engines with other engines that have this technology already installed.

**4**

**- Way Catalyst Converter** 

– Infeasible

. Refer to the discussion in Section 4.31.

**Replacement of Older Engines with Newer Engines**

– Infeasible

. Refer to the discussion in Section 4.31.

**LNE Design**

– Infeasible

. Refer to the discussion in Section 4.31.



### Step 3

**– Rank Remaining Control Technologies by Control Effectiveness** 
ULSD fuel usage is the only feasible option. Therefore, ranking is not required

.



### Step 4

**– Evaluate Most Effective Controls and Document Results** 

ULSD f uel us a ge is the only feasible option. Therefore, ranking is not required

.



### Step 5

**- Select BACT** 
Anadarko proposes ULSD fuel usage along with good combustion practices as PM/PM 10 

### /PM 2.5 

### BACT for the emergency air compressor diesel engine.



## 4.3.4. **VOC BACT Analysis**

**Step 1**

**– Identify all Control Technologies** 

EPA's RBLC search was used to obtain potential control technologies for VOC from smaller emergency diesel engines (< 500 hp) and review of the permits recently proposed/issued by U.S. EPA Region 4 and Region 10 (and corresponding permit applications) for similar OCS sources was conducted to obtain potential control technologies for VOC from smaller engines. The most recent 10

- year period was used to identify applicable control technologies. The results of the R BLC search are included in Appendix E

- 1. The search results for potential control technologies for VOC from smaller diesel engines are listed below.

DOC CDPF PCV 4

- Way Catalyst Converter Replacement of older engines with new enginesAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 26 Trinity Consultants 

### LNE (Low NO x 

### Emissions Engine) design including ( Turbo

- charger with after coolers

, intercoolers, and h igh injection pressure) Good combustion practices



### Step 2

**– Eliminate Technically Infeasible Options** 

**DOC**

– Infeasible. Refer to the discussion in Section 4.3.2.

**CDP F** 

– Infeasible

. Refer to the discussion in Section 4.3.2.

**PCV**

– Infeasible

. Refer to the discussion in Section 4.3.3.

**4**

**- Way Catalyst Converter** 

– Infeasible

. Refer to the discussion in Section 4.3.1.

**Replacement of Older Engines with Newer Engines**

– Infeasible

. Refer to the discussion in Section 4.3.1.

**LNE Design**

– Infeasible

. Refer to the discussion in Section 4.3.2.

**Step 3**

**– Rank Remaining Control Technologies by Control Effectiveness**  Good combustion practices is the only feasible option. Therefo re, ranking is not required.

**Step 4**

**– Evaluate Most Effective Controls and Document Results**  Good combustion practices is the only feasible option. Therefore, ranking is not required.

**Step 5**

**- Select BACT**  Anadarko proposes good combustion practices as VOC BACT for the emergency air compressor diesel engine

.



## 4.4. BACT ANALYSIS FOR WE LDING OPERATIONS

**Step 1**

**– Identify all Control Technologies**  A RBLC search for potential control options for PM/PM 10 

### /PM 2.5 

### from welding operations did not produce many results. Also, a review of the permits recently proposed/issued by U.S. EPA Region 4 and Region 10 for similar OCS sources was performed. The results of the RBLC search are included in Appendix B. However, it should be noted that the control technologies evaluate d in the “top

- down” analysis for these operations were not limited to the controls listed in the RBLC database. The search results for potential control technologies for PM/PM 10 

### /PM 2.5 

### from flares are listed below.

Emission Limit/Welding Rod Usage Limit B est Management Practices Routing to Control Device Body ShopAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 27 Trinity Consultants 

### Step 2

**– Eliminate Technically Infeasible Option** 

**Routing to Control Device**

– Infeasible The welding process results in negligible fugitive emissions, which cannot feasibly be captured and routed to a control device with any significant control efficiency.

**Body Shop**

– Infeasible Due to available space constraints on the drillship , performin g the welding operations in a separate body shop with options to route emissions via control device is technically infeasible.



### Step 3

**– Rank Remaining Control Technologies by Control Effectiveness** 

**T ABLE**  

### 4

**- 2**  **R ANKS OF**  

### T **ECHNOLOGIES** 

### F **EASIBLE FOR THE** 

### W **ELDING** 

### O **PERATIONS**


### Technology **Efficiency Rank**  Emission Limit/Welding Rod s Usage Limit N/A N/A Best Management Practices N/A N/A



### All feasible technologies for the welding operations are listed in Table 4

- 2

. Anadarko is proposing all the feasible options as BACT. Therefore, ranking is not required.



### Step 4

**– Evaluate Most Effective Controls and Document Results**  Since all the identified technologies are being proposed as BACT , a cost analysis is not required.



### Step 5

**- Select BACT** 

Anadarko proposes emission limitation/welding rod s usage limit and best management practices as PM/PM 10 

### /PM 2.5 

### BACT for the welding operations.



## 4.5. BACT ANALYSIS FOR PA INTING OPERATIONS

Painting Operations (DR

- PO

- 01) BACT analysis can be f ound in the Discoverer Spirit EGOM PSD/Title V Permit Application submitted in December 2012 and associated responses submitted to EPA in March and April 2013.



## 4.6. BACT ANALYSIS FOR WATER BLASTING OPERATIONS

Water Blasting Engine (DR

- WB

- 01) BACT analysis can be found in the Discoverer Spirit EGOM PSD/Title V Permit Application submitted in December 2012 and associated responses submitted to EPA in March and April 2013.

A summary of the proposed BACT emission limitation for each new sou rce associated with this application addendum is provided in Table 4

- 3

. The BACT limits for modified sources are unchanged and hence, the BACT limits for modified sources are not provided in the Table 4

- 3.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 28 Trinity Consultants 

### T **ABLE** 

### 4

**- 3**  **P ROPOSED**  

### BACT **E MISSION**  

### L **IMITS FOR**  

### N **EW** 

### S **OURCES**



### Emission Unit **Pollutant BACT**  **Emission Limit**  **Emission Limit Basis**  **BACT Control Technologies** 
Well Evaluation Engines (DR

- VS

- 01 to DR

- VS

- 05) NO x 

### 0.031 lb/hp

hr AP

- 42, Chapter 3, Table 3.3

- 1 Good Combustion Practices

CO 6.68E

- 03 lb/hp

- hr AP

- 42, Chapter 3, Table 3.3

- 1 Good Combustion Practices

PM/PM 10 

### /PM 2.5 

### 2.20E

- 03 lb/hp

- hr AP

- 42, Chapter 3, Table 3.3

- 1 Good Combustion Practices

VOC 2.51E

- 03 lb/hp

- hr AP

- 42, Chapter 3, Table 3.3

- 1 Good Combustion Practices

Wire Line Engines for Well Completion Scenario 4 (DR

- WC

- 09 and DR

- WC

10 ) NO x 

### 6.6 g/kW

- hr EPA Tier II Standards Good Combustion Practices

, and compliance to EPA Tier II standards CO 3.5 g/kW

- hr EPA Tier II Standards Good Combustion Practices
, and compliance to EPA Tier II standards PM/PM 10 

### /PM 2.5 

### 0.20 g/kW

- hr EPA Tier II Standards Good Combustion Practices

, and compliance to EPA Tier II standards VOC 6.6 g/kW

- hr EPA Tier II Standards Good Combustion Practices

, and compliance to EPA Tier II standards Welding Operations (DR

WO

- 01) PM/PM 10 

### /PM 2.5 

### 25.6 lb/10 3 

### lb AP

- 42, Chapter 12, Table 12.19

- 1 Emission Limit and Good Management PracticesAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 29 Trinity Consultants 

## 5. **AIR DISPERSION MODEL ING ANALYSIS**  **UPDATE**

Anadarko conducted an air dispersion modeling analysis as a part of the Discoverer Spirit PSD and Title V Drilling and Well Completion permit application, which was submitted to EPA on December 21, 2012 . This section outlines the updates to the modeling analysis as a result of the changes proposed in this application addendum. Updated modeling files are provided in Appendix D on a disc.



## 5.1. SUMMARY OF MODELING UPDATES

Out of the changes listed in section 1 .1, the following changes will result in increase in emissions and hence, their impact on air dispersion modeling analysis requirement must be assessed:

Add welding operations on the drillship; Add five Detroit 4

- 71 compressor engines for well evaluation a ctivities on the drillship; Remove the restrictions on water blasting/painting operations, and allow them to operate simultaneously with the ROV generator on the supply boat; Revise the water blast engine operation limit to 12 hours per day; Change two air compression diesel engines from emergency to nonemergency status by changing the usage from 100 to 1 04 hours per year; and Add two wire line engines to the well completion scenario

– Scenario 4.

Based on the changes listed above, it is determined that t here will be no impact on the air dispersion modeling analysis result submitted for the well completion operations scenario. The worst case emission rates among the four (4) well completion scenarios were modeled in the application which submitted on Dece mber 21, 2012. The proposed changes resulted in increase in emissions of the Well Completion Scenario 4. As shown in Table 5

- 1, the revised emissions for the Well Completion Scenario 4 are less than the worst case scenario that was modeled. Therefore, the modeling analyses for well completions do not need to be updated.

**Table 5** 

**- 1**  **Modeled Emission Rates Comparison for Well Completions**

**Pollutant Emission Rates (lb/day)** 

**Submitted Modeling**  **Scenario 1 (Upda**  **ted) Scenario 2**  **(Updated) Scenario 3**  **(Updated) Scenario 4**  **(Updated)**

NO x 

### 12,720.00 10,712.00 12,718.00 12,715.00 12,646.00

PM 10 

### 576.00 575.81 575.39 230.15 247.12

SO 2 

### 40.80 39.23 30.54 6.65 8.08



### Modeling updates are only needed for the drilling stage. Details of the modeling me thodology are described in the modeling analysis report in the December 2012 application, and are followed in this updated analysis. The modeling analysis updates are described in the rest of this section.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 30 Trinity Consultants 

## 5.2. POST MODIFICATION MO DELING EMISSION RAT ES

– DRILLING SCENARIO

The proposed changes resulted in increase in emissions of the Drilling Operations Scenario. As sown in Table 5

- 2, the post modification emission rates for PM 10 

### and SO 2 

### are higher than the emission rates modeled in December 2012 appl ication air dispersion modeling analysis. Hence, the revised air dispersion modeling analysis must be performed.

**Table 5** 

**- 2**  **Modeled Emission Rates Comparison**  **for Drilling**  **Operations**

**Pollutant Emission Rates**  **(lb/hr)**

**December 2012**

**Application Modeling Analysis**  **June 2013 Addendum Emission**  **Calculation June 2013**  **Addendum Modeled Emission** * Nitrogen Oxides (NO x 

### ) 574.72 570.98 572.00
Sulfur Dioxide (SO 2 

### ) 0.34 0.35 0.35
Sulfuric Acid (H 2 

### SO 4 

### ) 0.00 0.01 0.01
Particulate Matters (PM 10 

### ) 10.48 12.24 15.00

*Modeled emissions are slightly higher than the updated emission calculation to provide conservative estimates. The total emissions in tons per year will be used in the updated Q/d analysis.



### The air dispersion modeling analysis was performed using the revised emission rates. All other parameters and methodologies used for December 2012 application air dispersion modeling analysis were utilized. Detailed emission calculations are provided in Appendi x A. The particulate matter speciation follows the same percentage as provided by the submitted analysis, an updated speciation calculation is shown in Table 5

- 3.

**Table 5** 

**- 3**  **Updated D rilling Operation PM Speci**  **ation Summary**

**Emissions Speciation*** **Percentage (**  **% of Total PM**  **10** 

### ) **Modeled Emissions (**  **lb/hr )** 

Total PM 10 

### (TPM 10 

### ) 100% 15.00
Condensable portion of TPM 10 

### (CPM) 13.4% 2.0 1
Organic portion of CPM (SOA) 13.4% 2.0 1
Inorganic portion of CPM 0.0% 0.00
Filterable portion of TPM 10 

### (FPM 10 

### ) 86.6% 12.99
Coarse Filterable (PMC) 3.0% 0.45
Fine Filterable (PMF) 83.6% 12.54
Elemental Carbon (EC) 0.0% 0.00

*Values in italics are not modeled directly, but instead are shown for informative purposes.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 31 Trinity Consultants 

## 5.3. Q/D ANALYSIS

The Q/d analysis has been updated to reflect the updated emission rate. The modeled emission rate with some built

- in conservatism is selected as the emission quantity in the Q/d analysis for the drilling scenario.

The Q/d analysis compares the ratio of the sum of proposed annualized maximum 24

- hour emission rates of all visibility impairing pollutants (in tons per year) and the distance to the nearest Class I area (in km) to a threshold value of 10, as determined by the Federal Land Managers ( FLM ) . The “Q” is the combined emissions increase from a source of sulfur dioxide (SO 2 

### ), NO x 

### , particulate matter less than 10 microns (PM 10 

### ), and sulfuric acid mist (H 2 

### SO 4 

### ) in tons per year (tpy) based on annualized 24

- hour maximum allowable emissions . The “d” is the nearest distance to a Class I area in km from the source

. 6 

### Emissions from sources that operate intermittently or seasonally will be adjusted to account for year round operation. Hence, Q is calculated as follows:

Q = (572 lbs/hr + 0.35 lbs/hr + 0.01 lbs/hr + 15 lbs/hr) * 24 hrs/day * 365 days/year

= 2,573 tons/year

Table 5

- 4 below shows the Q/d analysis and results

.

**Table 5** 

**- 4**  **Q/d Analysis and Results**

**Class I Area, State Distance**  **( d,**  **km) Emissions**  **(Q, ton/yr) Q/d** 

Breton National Wildlife Refuge, LA (Breton NWR) 167 2,573 15.41 St. Marks National Wildlife Refuge, FL (St. Marks NWR) 285 9.03 Bradwell Bay Wilderness, FL 281 9.16



### Based on the Q/d results, a Class I area AQRV analysis is required only for the Breton National Wildlife Refuge . Since Q/d values are less than 10 for St. Marks NWR and Bradwell Bay Wilderness, it is inferred that the proposed modifications will have less than significant impact at these Class I areas without further analysis.



## 5.4. UPDATED MODELING RES ULTS

This section summarizes the results of the revised Class I area dispersion modeling analysis, and demonstrates that the proposed project does not cause or contribute to an exceedance of the Class I area PSD Increments, and does not adversely affect any Class I area.



## 5.4.1. **Class I Area Significance Analysis** 

I mpacts were predicted at the Breton NWR receptor locations , and were compared to the Class I area SILs. The hourly emission rates (based on maximum d aily emission rates divided by 24 ) and the methodologies described in the previously submitted air dispersion modeling protocol were utilized for performing the air dispersion modeling analysis. N o puff depletion due to wet or dry

6 U.S. Forest Service

– Air Quality Program, National Park Service

– Air Resources Division, U.S. Fish and Wildlife Service

– Air Quality Branch , Phase I Report of the Federal Land Managers’ Air Qual ity Related Values Workgroup (FLAG)

-- Revised, 2010.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 32 Trinity Consultants 

### deposition was accounted for. Additionally, all NO x 

### emissions were conservatively modeled to represent NO 2 

### emissions. A comparison of the pollutant concentrations with the Class I area SILs for all averaging periods is presented in Table 5

- 5

.

**Table 5** 

**- 5**  **Comparison to Class I Area SILs For Drilling Operations**

**Class I Area Parameter**  **Class I Area Modeling**  **Significance Level (μg/m**  **3** 

### ) **Year**

**2001 (μg/m**  **3** 

### ) **2002 (μg/m**  **3** 

### ) **2003 (μg/m**  **3** 

### )

Breton NWR NO 2 

### - Annual 0.1 0.0150 0.0261 0.0245

PM 2.5 

### - 24 hour 0.07 0.0335 0.0235 0.0375

PM 2.5 

### - Annual 0.06 0.0012 0.0018 0.0023

PM 10 

### - 24 hour 0.32 0.0401 0.0281 0.0448

PM 10 

### - Annual 0.16 0.0014 0.0022 0.0027

Since the p redicted concentrations of NO x 

### , PM 2.5 

### , and PM 10 

### do not exceed the ir respective SILs, it is inferred the proposed modifications will not cause or contribute to an exceedance of the Class I area PSD Increments and will not adversely affect the Class I area. Since St. Marks NWR and Bradwell Bay Wilderness Class I areas are f arther away from the worst case operating location, the proposed modifications will not cause or contribute to an exceedance of the se Class I area PSD Increments, and will not adversely affect these Class I area.



## 5.4.2. **Deposition**
Potential nitrogen and sulfur de position impacts at Breton NWR were calculated using the methodology described in Section 3.2.1 of the December 2012 application modeling report. The results are compared to the deposition assessment threshold s ( DATs ) . Although the sulfur and nitrogen DA Ts are specified based on an annual averaging period, maximum hourly emission rates ( based on maximum daily emission rates divided by 24 ) for the pollutants were modeled to estimate deposition impacts conservatively . The maximum deposition for both nitrog en and sulfur is shown in Table 5

- 6 for the proposed modification

.

**Table 5** 

**- 6**  **Nitrogen and Sulfur Deposition For Drilling Operations**

**Class I Area Parameter**  **Class I DAT Values**  **(Kg/ha/yr) Year** 

**2001 (Kg/ha/yr)**  **2002 (Kg/ha/yr)**  **2003 (Kg/ha/yr)** 

Breton NWR Nitrogen 0.01 0.0032 0.0059 0.0071

Sulfur 0.005 8.81E

- 06 1.74E

- 05 1.82E

- 05Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 33 Trinity Consultants 

### Since the p redicted values did not exceed the respective Nitrogen and Sulfur DAT s, the proposed modifications will not result in adverse impact on this Class I areas.



## 5.4.3. **Visibility**

As discussed in Section 3.2.2 of the December 2012 application modeling report , visibility impacts, in terms of regional haze, were determined for Breton NWR using “Method 8”. Table 5

- 7 shows the 98 th 

### percentile 24

- hour average visibility impact for years 2001 through 2003 based on CALPOST “Method 8” for the updated drilling scenario

.

**Table 5** 

**- 7**  **Method 8**

**- 98th**  **Percentile Extinction Change For Drilling Operations**

**Class I Area Parameter**  **Year**

**2001 2002**  **2003**

Breton NWR Method 8 98th Percentile 24

- hr Average Extinction Change % 4.9 7 % 4.02% 4.09%

No. of Days > 5 % Extinction Change Threshold 0 0 0

No. of Days > 10 % Extinction Change Threshold 0 0 0



## 5.5. CONCLUSION

Based on the updated modeling analysis presented in the section, it can be concluded that the proposed project will not cause adverse impacts to the ambient air quality in Class I areas that are located within 300 kilometers from the project’s worst

- case operation. The modeled concentrations for NO x 

### , PM 2.5 

### , and PM 10 

### were less than their respective SILs. The proposed project will not cause adverse impacts to AQRV in the three Class I areas.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application 34 Trinity Consultants 

## 6. **PAR T 71 FORMS** 

## Page | 2

EPA Form 5900

- 79 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
GENERAL INFORMATION AND SUMMARY (GIS)

A. Mai ling Address and Contact Information

Facility name Anandarko Petroleum Corporation

Mailing address: Street or P.O. Box 1201 Lake Robbins Drive

City The Woodlands State TX ZIP 77380

Contact person: Kathryn Maness Title EHS Manager

Telephone ( 832 ) 636

- 2582 Ext. _________

Facsimile (______) ________

-

___________



## B. Facility Location

Temporary source? X Yes ___No Plant site location Refer to Section 1.1 of the original application submitted in December 2012.

City _______N/A__________ State__N/A___ County_____N/A___________ EPA Region__4__

Is the facility located within:

Indian lands? ___YES _X__ NO OCS waters? _X__YES ___ NO

Non

- attainment area? ___ YES _X__NO If yes, for what air pollutants? ___N/A______

Within 50 miles of affected State? __ YES _X_ NO If yes, What State(s)? __N/A___



## C. Owner

Name Anandarko Petroleum Corporation Street/P.O. Box 1201 Lake Robbins Drive

City The Woodlands St ate TX ZIP 77380

Telephone ( 832 ) 636

- 2582 Ext. _________



## D. Operator

Name Anandarko Petroleum Corporation Street/P.O. Box 1201 Lake Robbins Drive

City The Woodlands State TX ZIP 77380

Telephone ( 832 ) 636

- 2 582 Ext. _________

## Page | 3

EPA Form 5900

- 79 E. Application Type Mark only one permit application type and answer the supplementary question appropriate for the type marked.

X Initial Permit ; Application Addendum ___ Renewal ___ Significant Mod ___ Minor Permit Mod (MPM)

___ Group Processing, MPM ___ Administrative Amendment

For initial permits, when did operations commence? _____ /_____ /_____

For permit renewal, what is the expiration date of current permit? _____/____/_____

F. Applicable Requi rement Summary Mark all types of applicable requirements that apply.

___ SIP ___ FIP/TIP _X_ PSD ___Non

- attainment NSR

___ Minor source NSR _X__ Section 111 ___ Phase I acid rain ___Phase II acid rain

___ Stratospheric ozone _X__ OCS regulations ___ NESHAP _X_ Sec. 112(d) MACT

___ Sec. 112(g) MACT ___ Early reduction of HAP ___ Sec 112(j) MACT ___ RMP [Sec.112(r)]

___ Tank Vessel requirements, sec. 183(f)) ___ Section 129 Standards/Requirement

___ Consumer / comm.. products, ' 183(e) ___ NAAQS, increments or visibility (temp. sources)

Has a risk management plan been registere d? ___YES _X__NO Regulatory agency ____________

Phase II acid rain application submitted? ___YES _X__NO If yes, Permitting authority ____________



## G. Source

- Wide PTE Restrictions and Generic Applicable Requirements

Cite and describe any e missions

- limiting requirements and/or facility

- wide "generic" applicable requirements.

Please see permit application attached herewith.

## Page | 4

EPA Form 5900

- 79 H. Process Description

List processes, products, and SIC codes for the facility.

Process Pro ducts SIC

OCS Exploratory Drilling Operations Petroleum Products 1381

I. Emission Unit Identification



### Assign an emissions unit ID and describe each emissions unit at the facility. Control equipment and/or alternative operating scenarios associated with emissions units should by listed on a separate line. Applicants may exclude from this list any insignificant emissions units or activities.

Emissions Unit ID Description of Unit

DR

- AC

- 01 & DR

- AC

- 02 Air Compressor Engines 1 & 2

DR

- WC

- 09 & DR

- WC

- 10 Well Completion Wireline Diesel Engines 3 & 4

DR

- VS

- 01 through DR

- VS

- 05 Drillship Well Evaluation Engines 1

- 5

SB

- VS

- 01 through SB

- VS

- 05 Supply Boat Well Evaluation Engines 1

- 5

SB

- VS

- 06 & SB

- VS

- 07 Supply Boat Well Evaluation Engines 6 & 7 ( different model than Engines 1

- 5 )

SB

- VS

- 08 & SB

- VS

- 09 Supply Boat Well Evaluation Engine Crane small & large

DR

- WO

- 01 Welding Operations

## P a g e | 5

EPA Form 5900- 79 J. Facility Emissions Summary

Enter potential to emit (PTE) for the facility as a whole for each air pollutant listed below. Enter the name of the single HAP emitted in the greatest amount and its PTE. For all pollutants stipulations to major source status may be indicated by entering "major" in the space for PTE. Indicate the total actual emissions for fee purposes for the facility in the space provided. Applications for permit modifications need not include actual emissions information.

NO x 

### 1,159.60 tons/yr VOC 74.90 tons/yr SO 2 

### 0.7 5 tons /yr

PM 10 

### 23.1 6 tons/yr CO 364.08 tons/yr Lead 0.01 tons/yr

Total HAP 7.81 tons/yr

Single HAP emitted in the greatest amount Xylene PTE 4.65 tons/yr

Total of regulated pollutants (for fee calculation), Sec. F, line 5 of form FEE __ ___ tons/yr



## K. Existing Federally-Enforceable Permits

Permit number(s) _________________ Permit type _____________ Permitting authority _________

Permit number(s) _________________ Permit type _____________ Permitting authori ty _________



## L. Emission Unit(s) Covered by General Permits

Emission unit(s) subject to general permit _______________________________________________

Check one: ___ Application made ___ Coverage granted

General permit identifier ______________________________ Expiration Date ____/____/____



## M. Cross-referenced Information

Does this application cross

- reference information? ___ YES _X_ NO (If yes, see instructions)

## Page | 6

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 0 6 /30/201 5 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION UNIT DESCRIPTION FOR FU E L COMBUSTION SOURCE S (EUD

- 1)

A. General Information

Emissions unit ID DR

- AC

- 01 Description Air C ompressor E ngine #1

SIC Code (4

- digit) 1381 SCC Cod e 20200102

B. Emissions Unit Description

Primary use Air Compressor Engine #1 Temporary Source X Yes No

Manufacturer Sperre Model No. M

- HL2/140

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 18 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___U nderfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______ Diesel ______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 7

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 1.0 gallons 104 gallons



### E. Associated Air Polluti on Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No.______________

_________ Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) ____ 97.113 ______._____ Inside stack diameter (ft) ____ 3.28

_____._____ Stack temp( o 

### F) _____ 523 _____._____ Desig n stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ______ 5414 __.____ Velocity (ft/sec) ____________ 10.66

__

## Page | 8

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- AC

- 0 2 Description Air Com pressor Engine # 2

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Air Compressor Engine # 2 Temporary Source X Yes No

Manufacturer Sperre Model No. M

- HL2/140

Serial Number __ ________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rat ing 1 5 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate

_ __Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe e ach fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 9

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 0.8 gallons 83.2 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_________________________

______________ Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) ____97.113______._____ Inside stack diameter (ft) ____3.28_____._____

Stack temp( o 

### F) _____523_____._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ______5414__.____ Velocity (ft/sec) ____________10.66__

## Page | 10

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit P rogram (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- WC

- 09 Description Well Completion Wireline Engine # 3

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissi ons Unit Description

Primary use Well Completion Wireline Engine # 3 Temporary Source X Yes No

Manufacturer Cummins Model No. C8.3

Serial Number __________________________ Installation Date____/____/_______

Boiler Typ e: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 275 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __ ________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Typ e Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 11

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur die sel N/A 15 gallons 21,600 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer__

_______________________ Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diamete r (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 12

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General I nformation

Emissions unit ID DR

- WC

- 10 Description Well Completion Wireline Engine # 4

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Well Completion Wireline Engine # 4 Temporary Source X Yes N o

Manufacturer Cummins Model No. C8.3

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other ( describe) _____________________________________________

Engine horsepower rating 275 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel typ e(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur d iesel 0.0015 18330 BTU/lb

## Page | 13

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 15 gallons 21,600 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when amb ient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM)

__________.____ Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 14

EPA Form 5900

- 80 OMB No. 2060

- 03 36, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- VS

- 0 1 Description Drillship Well Evaluation Engine # 1

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Drillship Well Evaluation Engine # 1 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number _________________ _________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you e xpected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 15

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency es timation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common)

.

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) _________

_____

## Page | 16

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION UNI T DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- VS

- 0 2 Description Drillship Well Evaluation Engine # 2

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use D rillship Well Evaluation Engine # 2 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ P rocess burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coa l burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Hea t Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. As h Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 17

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gal lons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model N o.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

Thi s information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Sta ck temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 18

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- VS

- 0 3 Description Drillship Well Evaluation Engine # 3

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Drillship Well Evaluation Engine # 3 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) ___________________

__________________________ Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed s toker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Sta ndby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 19

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID___ _________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/__ _______ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an app licable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack f low rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 2 0

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- VS

- 0 4 Description Drillship Well Evaluation Engine # 4

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Drillship Well Evaluation Engine # 4 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date ____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, d ry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 21

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage

Hour ly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled__ _________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method________________

______________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) ________ __._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 22

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTI ON SOURCES (EUD

- 1)

A. General Information

Emissions unit ID DR

- VS

- 0 5 Description Drillship Well Evaluation Engine # 5

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Drillship Well Evaluation Engin e # 5 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fi red ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 23

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ S erial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be complete d by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 24

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 0 1 Description Supp ly Boat Well Evaluation Engine # 1

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine # 1 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) ____________________________________________

_ Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grat e ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)________

_____________ Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 25

EPA Form 5900

- 80 D. Fuel U sage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_

______________________________________ Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control effici ency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for t his emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________. ____ Velocity (ft/sec) ______________

## Page | 26

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 0 2 Description Supply Boat Well Evaluation Engine # 2

SIC Code (4

- digit) 1381 SCC Code 20200102

B. E missions Unit Description

Primary use Supply Boat Well Evaluation Engine # 2 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Bo iler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)________

_______ Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 27

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Ma nufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method_____________________________________

_________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside s tack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 28

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 0 3 Description Supply Boat Well Evaluation Engine # 3

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine # 3 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 29

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air P ollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No.________

_______________ Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary so urces or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 30

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 0 4 Description Supply Boat Well Evalu ation Engine # 4

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine # 4 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Num ber __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepo wer rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

De scribe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 31

EPA Form 5900

- 80 D. Fuel Usage Rates

Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type__________________

_____________________ Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ________

____ Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions uni t (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Veloc ity (ft/sec) ______________

## Page | 32

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 0 5 Description Supply Boat Well Evaluation Engine # 5

SIC Code (4

- digit) 1381 SCC Code 20200102

B. Emissions Unit Des cription

Primary use Supply Boat Well Evaluation Engine # 5 Temporary Source X Yes No

Manufacturer Detroit Model No. 4

- 71

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ I ndustrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 140 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________M M BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. S ulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 33

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A 7.6 gallons 950 gallons



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_______

__________________ Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Amb ient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft ) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 34

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Infor mation

Emissions unit ID SB

- VS

- 06 Description Supply Boat Well Evaluation Engine # 6

SIC Code (4

- digit) ____1381______ SCC Code__20200102______

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine # 6 Temporary Source _X_Yes ___No

Manufacturer Caterpillar Model No. 3406 C

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Ot her (describe) _____________________________________________

Engine horsepower rating 360 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel ______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 35

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A No data No data



### E. Associated Air Pollution Control Equipment

Emissions un it ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/ _____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment i s an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 36

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/3 0/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 07 Description Supply Boat Well Evaluation Engine # 7

SIC Code (4

- digit) ____138 1______ SCC Code__20200102______

B. Emissions Unit Descrip tion

Primary use Supply Boat Well Evaluation Engine # 7 Temporary Source _X_Yes ___No

Manufacturer Caterpillar Model No. 3406 C

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 360 HP Boiler steam fl ow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of th e permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 37

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A No data No data



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled____________ _______ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method__________________________

____________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 38

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 08 Description Supply Boat Well Evaluation Engine Crane

– Small

SIC Code (4

- digit) ____1381______ SCC Code__20200102______

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine Crane

- Small Temporary Source _X_Yes __No

Manufacturer John Deere Model No. PE 4045D

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) _____________________________________________

Engine horsepower rating 62 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)_____________________

Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 39

EPA Form 5900

- 80 D. Fuel Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A No data No data



### E. Associated Air Pollution Control Equipment

Emissions unit ID____________ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.____________________ __ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) ________ __._____ Design stack flow rate (ACFM) __________.____

Actua l stack flow rate (ACFM) ______ __.____ Velocity (ft/sec) ______________

## Page | 40

EPA Form 5900

- 80 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR FUEL COMBUSTION SOURCES (EUD

- 1)

A. General Information

Emissions unit ID SB

- VS

- 09 Description Supply Boat Well Evaluation Engine Crane

– Large

SIC Code (4

- digit) ____1381______ SCC Code__20200102______

B. Emissions Unit Description

Primary use Supply Boat Well Evaluation Engine Crane

- Large Temporary Source _X_Yes __No

Manufactur er Cummins Model No. B 5.9

- C

Serial Number __________________________ Installation Date____/____/_______

Boiler Type: ___ Industrial boiler ___ Process burner ___ Electric utility boiler

Other (describe) ____________________

_________________________ Engine horsepower rating 130 HP Boiler steam flow (lb/hr)_______________

Type of Fuel

- Burning Equipment (coal burning only):

___ Hand fired ___Spreader stoker ___Underfeed stoker ___Overfeed stoker

___ Traveling grate ___Shaking grate ___Pulverized, wet bed ___ Pulverized, dry bed

Actual Heat Input __________MM BTU/hr Max. Design Heat Input __________MM BTU/hr

C. Fuel Data Primary fuel type(s)_______Diesel______ Standby fuel type(s)______

_______________ Describe each fuel you expected to use during the term of the permit.

Fuel Type Max. Sulfur Content (%) Max. Ash Content (%) BTU Value (cf, gal., or lb.)

Ultra low sulfur diesel 0.0015 18330 BTU/lb

## Page | 41

EPA Form 5900

- 80 D. Fue l Usage Rates
Fuel Type Annual Actual Usage Maximum Usage
Hourly Annual

Ultra low sulfur diesel N/A No data No data



### E. Associated Air Pollution Control Equipment

Emissions unit ID___________ _ Device type_______________________________________

Air pollutant(s) Controlled___________________ Manufacturer_________________________

Model No.______________________ Serial No._______________________

Installation date_____/_____/_________ Control efficiency (%) ____________

Efficiency estimation method______________________________________________

F. Ambient Impact Assessment

This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (this is not common).

Stack height (ft) __________._____ Inside stack diameter (ft) _________._____

Stack temp( o 

### F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ________.____ Velocity (ft/sec) ______________

## Page | 42

EPA Form 5900

- 82 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Fed eral Operating Permit Program (40 CFR Part 71)
EMISSION UNIT DESCRIPTION FOR PROCESS SOURCES (EUD

- 3)

A. General Information



### Emissions unit ID DR

- WO

- 01 Description Welding Operations

SIC Code (4

- digit) 1381 SCC Code 30900501

B. Emissio ns Unit Description

Primary use or equipment type Electric Arc Welding

Manufacturer __________________________ Model No. _______________________

Serial No. _____________________________ Installation date _____/_____/_____

Raw materials E308, E310, E316, E6010, E6011, E7018, and E7028

Finished products _________________________________________________________

Temporary source: _No X Yes

C. Activity or Production Rates 

### Activity or Production Rate Amount/Hour Amount/Year

Actual Rate

Maximum rate 1.92 lbs/hr 5.2 tons/year

D. Associated Air Pollution Control Equipment

Emissions unit ID ____________ Device Type___________________________________

Manufacturer _______________________ Model No_______________

_______________ Serial No. ______________________________ Installation date _____/_____/_________

Control efficiency (%) _________.___ Capture efficiency (%) ________.___

Air pollutant(s) controlled ______________ Efficiency estimati on method _______________

## Page | 43

EPA Form 590 0

- 82 E. Ambient Impact Assessment This information must be completed by temporary sources or when ambient impact assessment is an applicable requirement for this emissions unit (This is not common)).

Stack height (ft) ________ __._____ Inside stack diameter (ft) _________._____

Stack temp (F) __________._____ Design stack flow rate (ACFM) __________.____

Actual stack flow rate (ACFM) ____________.____ Velocity (ft/sec) ____________.____

## Page | 44

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted wit h the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- AC

- 01



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed sol ely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Po tential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.02 1.03E

- 03 N/A PM 10 

### N/A 0.02 1.03E

- 03 N/A PM 2.5 

### N/A 0.02 1.03E

- 03 N/A NO X 

### N/A 0.28 1.45E

- 02 N/A S0 2 

### N/A 1.01E

- 04 5.25E

- 06 7446

- 09

- 5 H 2 

### SO 4 

### N/A 3.15E

- 06 1.64E

- 07 7664

- 93

- 9 CO N/A 0.06 3. 13E

- 03 630

- 08

- 0 VOC N/A 0.02 1.18E

- 03 N/A Lead N/A 1.83E

- 06 9.50E

- 08 7439

- 92

- 1 Acetaldehyde N/A 4.83E

- 05 2.51E

- 06 75

- 07

- 0 Acrolein N/A 5.83E

- 06 3.03E

- 07 107

- 02

- 8 Benzene N/A 5.88E

- 05 3.06E

- 06 71

- 43

- 2 Formaldehyde N/A 7.43E

- 05 3.87E

- 06 50

- 00

- 0 Toluen e N/A 2.58E

- 05 1.34E

- 06 108

- 88

- 3 Xylenes N/A 1.80E

- 05 9.34E

- 07 1330

- 20

- 7 1,3 Butadiene N/A 2.46E

- 06 1.28E

- 07 106

- 99

- 0 Total PAH N/A 1.06E

- 05 5.50E

- 07 N/A Naphthalene N/A 5.34E

- 06 2.78E

- 07 91

- 20

- 3 CO 2 

### N/A 10.27 0.53 124

- 38

- 9 CH 4 

### N/A 4.17E

- 04 2.17E

- 05 74

- 82

- 8 N 2 

### O N/A 8.33E

- 05 4.33E

- 06 10024

- 97

- 2 CO 2 

### e N/A 10.31 0.54 N/A

## Page | 45

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/3 0/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating s cenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- AC

- 0 2



## B. Identification and Quantification of Emissions

First, list each air pollu tant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emission s for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 1.65E

- 02 8.58E

- 04 N/A PM 10 

### N/A 1.65E

- 02 8.58E

- 04 N/A PM 2.5 

### N/A 1.65E

- 02 8.58E

- 04 N/A NO X 

### N/A 2.33E

- 0 1 1.21E

- 02 N/A S0 2 

### N/A 8.41E

- 05 4.37E

- 06 7446

- 09

- 5 H 2 

### SO 4 

### N/A 2.63E

- 06 1.37E

- 07 7664

- 93

- 9 CO N/A 5.01E

- 02 2.61E

- 03 630

- 08

- 0 VOC N/A 1.89E

- 02 9.80E

- 04 N/A Lead N/A 1.52E

- 06 7.92E

- 08 7439

- 92

- 1 Acetaldehyde N/A 4.03E

- 05 2.09E

- 06 75

- 07

- 0 Acrolein N/A 4.8 6E

- 06 2.53E

- 07 107

- 02

- 8 Benzene N/A 4.90E

- 05 2.55E

- 06 71

- 43

- 2 Formaldehyde N/A 6.20E

- 05 3.22E

- 06 50

- 00

- 0 Toluene N/A 2.15E

- 05 1.12E

- 06 108

- 88

- 3 Xylenes N/A 1.50E

- 05 7.78E

- 07 1330

- 20

- 7 1,3 Butadiene N/A 2.05E

- 06 1.07E

- 07 106

- 99

- 0 Total PAH N/A 8.82E

- 0 6 4.59E

- 07 N/A Naphthalene N/A 4.45E

- 06 2.32E

- 07 91

- 20

- 3 CO 2 

### N/A 8.56 0.45 124

- 38

- 9 CH 4 

### N/A 3.47E

- 04 1.81E

- 05 74

- 82

- 8 N 2 

### O N/A 6.94E

- 05 3.61E

- 06 10024

- 97

- 2 CO 2 

### e N/A 8.59 0.45 N/A

## Page | 46

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability pu rposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- WC

- 09



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not alrea dy listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr )
PM N/A 0.09 0.07 N/A PM 10 

### N/A 0.09 0.07 N/A PM 2.5 

### N/A 0.09 0.07 N/A NO X 

### N/A 2.98 2.15 N/A S0 2 

### N/A 0.0031 2.22E

- 03 7446

- 09

- 5 H 2 

### SO 4 

### N/A 9.64E

- 05 6.94E

- 05 7664

- 93

- 9 CO N/A 1.58 1.14 630

- 08

- 0 VOC N/A 0.69 0.50 N/A Lead N/A 5.58E

- 05 4.02E

- 05 7439

- 92

- 1 Acetaldehyde N/A 1.48E

- 03 1.06E

- 03 75

- 07

- 0 Acrolein N/A 1.78E

- 04 1.28E

- 04 107

- 02

- 8 Benzene N/A 1.80E

- 03 1.29E

- 03 71

- 43

- 2 Formaldehyde N/A 2.27E

- 03 1.64E

- 03 50

- 00

- 0 Toluene N/A 7.87E

- 04 5.67E

- 04 108

- 88

- 3 Xylenes N/A 5.49E

- 04 3.95E

- 04 1330

- 20

- 7 1,3 Butadiene N/A 7.53E

- 05 5.42E

- 05 106

- 99

- 0 Total PAH N/A 3.23E

- 04 2.33E

- 04 N/A Naphthalene N/A 1.63E

- 04 1.18E

- 04 91

- 20

- 3 CO 2 

### N/A 313.88 225.99 124

- 38

- 9 CH 4 

### N/A 0.013 9.17E

- 03 74

- 82

- 8 N 2 

### O N/A 2.55E

- 03 1.83E

- 03 10024

- 97

- 2 CO 2 

### e N/A 318.61 226.75 N/A

## Page | 47

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION CALCULAT IONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to b e submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- WC

- 10



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, t hen list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pol lutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emiss ions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.09 0.07 N/A PM 10 

### N/A 0.09 0.07 N/A PM 2.5 

### N/A 0.09 0.07 N/A NO X 

### N/A 2.98 2.15 N/A S0 2 

### N/A 0.0031 2.22E

- 03 7446

- 09

- 5 H 2 

### SO 4 

### N/A 9.64E

- 05 6.94E

- 05 7664

- 93

- 9 CO N/A 1.58 1. 14 630

- 08

- 0 VOC N/A 0.69 0.50 N/A Lead N/A 5.58E

- 05 4.02E

- 05 7439

- 92

- 1 Acetaldehyde N/A 1.48E

- 03 1.06E

- 03 75

- 07

- 0 Acrolein N/A 1.78E

- 04 1.28E

- 04 107

- 02

- 8 Benzene N/A 1.80E

- 03 1.29E

- 03 71

- 43

- 2 Formaldehyde N/A 2.27E

- 03 1.64E

- 03 50

- 00

- 0 Toluene N/A 7. 87E

- 04 5.67E

- 04 108

- 88

- 3 Xylenes N/A 5.49E

- 04 3.95E

- 04 1330

- 20

- 7 1,3 Butadiene N/A 7.53E

- 05 5.42E

- 05 106

- 99

- 0 Total PAH N/A 3.23E

- 04 2.33E

- 04 N/A Naphthalene N/A 1.63E

- 04 1.18E

- 04 91

- 20

- 3 CO 2 

### N/A 313.88 225.99 124

- 38

- 9 CH 4 

### N/A 0.013 9.17E

- 03 74

- 82

- 8 N 2 

### O N/A 2.55E

- 03 1.83E

- 03 10024

- 97

- 2 CO 2 

### e N/A 318.61 226.75 N/A

## Page | 48

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/201 5 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenar io identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- VS

- 01



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions fo r fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.8 1E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 49

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- VS

- 02



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, c alculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrol ein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 50

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applica bility purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual em issions.

A. Emissions Unit ID DR

- VS

- 03



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) n ot already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 51

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION CALCU LATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need t o be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- VS

- 04



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air po llutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emis sions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 52

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Fe deral Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario i dentified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID DR

- VS

- 05



## B. Identification and Quantification of Emissions

First, list each air pollutant tha t is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fe e purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Ai r Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 0 5 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 7 1

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 53

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emis sions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 01



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calc ulate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton fo r yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/ A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 54

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicabil ity purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emiss ions.

A. Emissions Unit ID SB

- VS

- 02



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives fo r fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (to ns/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 55

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

EMISSION CALCULAT IONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to b e submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 03



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, the n list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollu tants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissio ns

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0. 14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4. 01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 56

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Feder al Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario iden tified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 04



## B. Identification and Quantification of Emissions

First, list each air pollutant that i s either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee p urposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air P ollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0.31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7 446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 4 3

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.83E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 57

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissio ns unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 05



## B. Identification and Qua ntification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculat e PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for ye arly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.31 0.02 N/A PM 10 

### N/A 0.31 0.02 N/A PM 2.5 

### N/A 0. 31 0.02 N/A NO X 

### N/A 3.42 0.21 N/A S0 2 

### N/A 1.57E

- 03 9.81E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.91E

- 05 3.07E

- 06 7664

- 93

- 9 CO N/A 2.27 0.14 630

- 08

- 0 VOC N/A 0.13 0.01 N/A Lead N/A 2.84E

- 05 1.78E

- 06 7439

- 92

- 1 Acetaldehyde N/A 7.52E

- 04 4.70E

- 05 75

- 07

- 0 Acrolein N/A 9.07E

- 05 5.67E

- 06 107

- 02

- 8 Benzene N/A 9.14E

- 04 5.71E

- 05 71

- 43

- 2 Formaldehyde N/A 1.16E

- 03 7.23E

- 05 50

- 00

- 0 Toluene N/A 4.01E

- 04 2.51E

- 05 108

- 88

- 3 Xylenes N/A 2.79E

- 04 1.75E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.65E

- 04 1.03E

- 05 106

- 99

- 0 Total PAH N/A 3.8 3E

- 05 2.39E

- 06 N/A Naphthalene N/A 8.31E

- 05 5.19E

- 06 91

- 20

- 3 CO 2 

### N/A 160 10 124

- 38

- 9 CH 4 

### N/A 6.48E

- 03 4.05E

- 04 74

- 82

- 8 N 2 

### O N/A 1.30E

- 03 8.10E

- 05 10024

- 97

- 2 CO 2 

### e N/A 160 10 N/A

## Page | 58

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions

.

A. Emissions Unit ID SB

- VS

- 06



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not alr eady listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for f ee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/ yr)
PM N/A 0.79 0.05 N/A PM 10 

### N/A 0.79 0.05 N/A PM 2.5 

### N/A 0.79 0.05 N/A NO X 

### N/A 11.16 0.70 N/A S0 2 

### N/A 4.04E

- 03 2.52E

- 04 7446

- 09

- 5 H 2 

### SO 4 

### N/A 1.26E

- 04 7.88E

- 06 7664

- 93

- 9 CO N/A 2.40 0.15 630

- 08

- 0 VOC N/A 0.90 0.06 N/A Lead N/A 7.31E

- 05 4.57E

- 06 74 39

- 92

- 1 Acetaldehyde N/A 1.93E

- 03 1.21E

- 04 75

- 07

- 0 Acrolein N/A 2.33E

- 04 1.46E

- 05 107

- 02

- 8 Benzene N/A 2.35E

- 03 1.47E

- 04 71

- 43

- 2 Formaldehyde N/A 2.97E

- 03 1.86E

- 04 50

- 00

- 0 Toluene N/A 1.03E

- 03 6.44E

- 05 108

- 88

- 3 Xylenes N/A 7.18E

- 04 4.49E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 4.23E

- 04 2.65E

- 05 106

- 99

- 0 Total PAH N/A 9.85E

- 05 6.16E

- 06 N/A Naphthalene N/A 2.14E

- 04 1.34E

- 05 91

- 20

- 3 CO 2 

### N/A 411 26 124

- 38

- 9 CH 4 

### N/A 1.67E

- 02 1.04E

- 03 74

- 82

- 8 N 2 

### O N/A 3.33E

- 03 2.08E

- 04 10024

- 97

- 2 CO 2 

### e N/A 412 26 N/A

## Page | 59

EPA Form 5900

- 84 Federal Operating Permit Program (40 CFR Part 71)

EMISSION CALCU LATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need t o be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 07



## B. Identification and Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air p ollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emi ssions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.79 0.05 N/A PM 10 

### N/A 0.79 0.05 N/A PM 2.5 

### N/A 0.79 0.05 N/A NO X 

### N/A 11.16 0.70 N/A S0 2 

### N/A 4.04E

- 03 2.52E

- 04 7446

- 09

- 5 H 2 

### SO 4 

### N/A 1.26E

- 04 7.88E

- 06 7664

- 93

- 9 CO N/A 2. 40 0.15 630

- 08

- 0 VOC N/A 0.90 0.06 N/A Lead N/A 7.31E

- 05 4.57E

- 06 7439

- 92

- 1 Acetaldehyde N/A 1.93E

- 03 1.21E

- 04 75

- 07

- 0 Acrolein N/A 2.33E

- 04 1.46E

- 05 107

- 02

- 8 Benzene N/A 2.35E

- 03 1.47E

- 04 71

- 43

- 2 Formaldehyde N/A 2.97E

- 03 1.86E

- 04 50

- 00

- 0 Toluene N /A 1.03E

- 03 6.44E

- 05 108

- 88

- 3 Xylenes N/A 7.18E

- 04 4.49E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 4.23E

- 04 2.65E

- 05 106

- 99

- 0 Total PAH N/A 9.85E

- 05 6.16E

- 06 N/A Naphthalene N/A 2.14E

- 04 1.34E

- 05 91

- 20

- 3 CO 2 

### N/A 411 26 124

- 38

- 9 CH 4 

### N/A 1.67E

- 02 1.04E

- 03 74

- 82

- 8 N 2 

### O N/A 3.33E

- 03 2.08E

- 04 10024

- 97

- 2 CO 2 

### e N/A 412 26 N/A

## Page | 60

EPA Form 5900

- 84 Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each emissions unit, control device, or alternative operating scen ario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 08



## B. Identification and Quantification of Emissions

First, list each air pollut ant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, calculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.14 0.01 N/A PM 10 

### N/A 0.14 0.01 N/A PM 2.5 

### N/A 0.14 0.01 N/A NO X 

### N/A 1.92 0.12 N/A S0 2 

### N/A 6.95E

- 04 4.35E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 2.17E

- 05 1.36E

- 06 7664

- 93

- 9 CO N/A 0.41 0.03 630

- 08

- 0 VOC N/A 0.16 0.01 N/A Lead N/A 1.26E

- 05 7.87E

- 07 7439

- 92

- 1 Acetaldehyde N/A 3.33E

- 04 2.08E

- 05 75

- 07

- 0 Acrolein N/A 4.01E

- 05 2.51E

- 06 107

- 02

- 8 Benzene N/A 4.05E

- 04 2.5 3E

- 05 71

- 43

- 2 Formaldehyde N/A 5.12E

- 04 3.20E

- 05 50

- 00

- 0 Toluene N/A 1.78E

- 04 1.11E

- 05 108

- 88

- 3 Xylenes N/A 1.24E

- 04 7.73E

- 06 1330

- 20

- 7 1,3 Butadiene N/A 7.29E

- 05 4.56E

- 06 106

- 99

- 0 Total PAH N/A 1.70E

- 05 1.06E

- 06 N/A Naphthalene N/A 3.68E

- 05 2.30E

- 06 91

- 20

- 3 CO 2 

### N/A 71 4 124

- 38

- 9 CH 4 

### N/A 2.87E

- 03 1.79E

- 04 74

- 82

- 8 N 2 

### O N/A 5.74E

- 04 3.59E

- 05 10024

- 97

- 2 CO 2 

### e N/A 71 4 N/A

## Page | 61

EPA Form 5900

- 84 OMB No. 2060

- 0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)
EMISSION CALCULATIONS (EMISS)

Calculate potential to emit (PTE) for applicability purposes and actual emissions for fee purposes for each em issions unit, control device, or alternative operating scenario identified in section I of form GIS . If form FEE does not need to be submitted with the application, do not calculate actual emissions.

A. Emissions Unit ID SB

- VS

- 09



## B. Identification a nd Quantification of Emissions

First, list each air pollutant that is either regulated at the unit or present in major amounts, then list any other regulated pollutant (for fee calculation) not already listed. HAP may be simply listed as "HAP." Next, ca lculate PTE for applicability purposes and actual emissions for fee purposes for each pollutant. Do not calculate PTE for air pollutants listed solely for fee purposes. Include all fugitives for fee purposes

. 

### You may round to the nearest tenth of a ton for yearly values or tenth of a pound for hourly values.

Air Pollutants Emission Rates

CAS No. Actual Annual Emissions

(tons/yr) Potential to Emit
Hourly (lb/hr) Annual (tons/yr)
PM N/A 0.29 0.02 N/A PM 10 

### N/A 0.29 0.02 N/A PM 2.5 

### N/A 0.29 0.02 N/A NO X 

### N/A 4.03 0.25 N/A S0 2 

### N/A 1.46E

- 03 9.11E

- 05 7446

- 09

- 5 H 2 

### SO 4 

### N/A 4.55E

- 05 2.85E

- 06 7664

- 93

- 9 CO N/A 0.87 0.05 630

- 08

- 0 VOC N/A 0.33 0.02 N/A Lead N/A 2.64E

- 05 1.65E

- 06 7439

- 92

- 1 Acetaldehyde N/A 6.98E

- 04 4.36E

- 05 75

- 07

- 0 Acrole in N/A 8.42E

- 05 5.26E

- 06 107

- 02

- 8 Benzene N/A 8.49E

- 04 5.31E

- 05 71

- 43

- 2 Formaldehyde N/A 1.07E

- 03 6.71E

- 05 50

- 00

- 0 Toluene N/A 3.72E

- 04 2.33E

- 05 108

- 88

- 3 Xylenes N/A 2.59E

- 04 1.62E

- 05 1330

- 20

- 7 1,3 Butadiene N/A 1.53E

- 04 9.56E

- 06 106

- 99

- 0 Total PAH N /A 3.56E

- 05 2.22E

- 06 N/A Naphthalene N/A 7.72E

- 05 4.82E

- 06 91

- 20

- 3 CO 2 

### N/A 148 9 124

- 38

- 9 CH 4 

### N/A 6.02E

- 03 3.76E

- 04 74

- 82

- 8 N 2 

### O N/A 1.20E

- 03 7.52E

- 05 10024

- 97

- 2 CO 2 

### e N/A 149 9 N/A

## P a g e | 62

EPA Form 5900- 85 OMB No. 2060-0336, Approval Expires 06/30/2015 

## Federal Operating Permit Program (40 CFR Part 71)

POTENTIAL TO EMIT (PTE)

For each unit with emissions that count towards applicability, list the emissions unit ID and the PTE for the air pollutants listed below and sum them up to show totals for the facility. You may find it helpful to complete form EMISS before completing this form. Show other pollutants not listed that are present in major amounts at the facility on attachment in a similar fashion. You may round values to the nearest tenth of a ton. Also report facility totals in section J of form GIS

.

Source Regulated Air Pollutants and Pollutants for which the Source is Major (tons/yr)

PM 10 

### PM 2.5 

### NO x 

### SO 2 

### H 2 

### SO 4 

### CO VOC Pb HAP

Total: Drillship + Support Vessel 23.1 6 22.25 1,159.60 0.7 5 0.02 364.08 61.66 0.01 7.69

Total: Well Completion + Support Vessel 22.50 21.89 1,143.91 0.73 0.0 2 354.36 74.90 0.01 7. 81

Total: Worst case scenario 23.16 22.25 1,159.60 0.7 5 0.02 364.08 74.90 0.01 7.81Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX A

**– EMISSION CALCULATION**  **S**lb/dayton/yr lb/dayton/yr lb/dayton/yrPM 0 0 1.92 0.20 1.92 0.20PM100 0 1.92 0.20 1.92 0.20PM2.50 0 1.92 0.20 1.92 0.20PM 0 0 36.96 0.10 36.96 0.10PM100 0 36.96 0.10 36.96 0.10PM2.50 0 36.96 0.10 36.96 0.10NOx0 0 410.06 1.07 410.06 1.07SO20 0 0.19 4.91E‐04 0.19 4.91E‐04H2SO40 0 0.006 1.53E‐05 0.006 1.53E‐05CO 0 0 272.49 0.71 272.49 0.71VOC 0 0 15.87 0.04 15.87 0.04Pb 0 0 0.003 8.88E‐06 0.003 8.88E‐06CO2e 0 0 19240 50 19240 50PM 2.34 0.19 2.90 0.22 5.24 0.41PM102.34 0.19 2.90 0.22 5.24 0.41PM2.52.34 0.19 2.90 0.22 5.24 0.41NOx59.97 6.24 16.42 1.70 76.39 7.94SO20.016 0.002 0.012 0.001 0.028 0.003H2SO45.1E‐04 5.30E‐05 3.68E‐04 3.83E‐05 8.78E‐04 9.13E‐05CO 32.80 3.41 14.36 1.49 47.16 4.90VOC 145.96 7.78 33.48 1.88 179.44 9.66Pb 3.0E‐04 3.1E‐05 2.1E‐04 2.2E‐05 5.1E‐04 5.3E‐05CO2e 6528 679 2858 297 9386.21098 976PM 0.04 0.002 0 7.55E‐05 0.04 0.002PM100.04 0.002 0 7.55E‐05 0.04 0.002PM2.50.04 0.002 0 7.55E‐05 0.04 0.002NOx0.51 0.03 0 1.06E‐03 0.51 0.03SO21.85E‐04 9.62E‐06 0 3.85E‐07 1.85E‐04 1.00E‐05H2SO45.78E‐06 3.01E‐07 0 1.20E‐08 5.78E‐06 3.13E‐07CO 0.11 0.01 0 2.29E‐04 0.11 0.01VOC 0.04 0.002 0 8.63E‐05 0.04 0.002Pb 3.35E‐06 1.74E‐07 0 6.97E‐09 3.35E‐06 1.81E‐07CO2e 19 0.98 0 3.93E‐02 19 1.02ExistingEmissions Impact	of	Change New	EmissionsSummaryofChanges3/45Add	welding	operations	(DR‐WO‐01)	on	thedrillshipAdd	five	Detroit	4‐71	engines	(DR‐VS‐01	to	DR‐VS‐05)	for	well	evaluation	activities	on	thedrillshipRemove	the	operating	restrictions	on	existingwater	blasting	engine	and	painting	operations(DR‐WB‐01	and	DR‐PO‐01),	and	allow	them	tooperate	simultaneously	with	the	existingremotely	operated	vehicle	(ROV)	(SB‐GE‐04)generator	on	the	supply	boat;	Increase	theexisting	water	blasting	engine	(DR‐WB‐01)operation	limit	to	12	hours	per	dayRevise	the	descriptions	and	operating	hours	ofexisting	air	compressor	diesel	engines	(DR‐AC‐01	and	DR‐AC‐02)No. Changes Pollutant12Anadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit 1 of 40Changes SummaryDate Printed - 6/26/2013PM 0 0 4.34 0.13 4.34 0.13PM100 0 4.34 0.13 4.34 0.13PM2.50 0 4.34 0.13 4.34 0.13NOx0 0 143.23 4.30 143.23 4.30SO20 0 0.15 0.004 0.15 0.004H2SO40 0 4.62E‐03 1.39E‐04 0.00 0.00CO 0 0 75.95 2.28 75.95 2.28VOC 0 0 33.19 1.00 33.19 1.00Pb 0 0 2.68E‐03 8.04E‐05 0.00 0.00CO2e 0 0 15117 454 15117 4547 Revise	the	supply	boat’s	hours	based	operationlimit	to	a	fuel	based	operation	limit8 Add	five	Detroit	4‐71	engines	(SB‐VS‐01	to	SB‐VS‐05),	two	Caterpillar	3406C	engines	(SB‐VS‐06and	SB‐VS‐07),	and	two	crane	engines	(SB‐VS‐08and	SB‐VS‐09)	for	well	evaluation	activities	onthe	supplyboat9 Revise	response	to	Question	no.	8	in	EPA’sincompleteness	determination	letter10 Add	Emergency	Generator	(DR‐GE‐07)	engine	asa	part	of	Main	Engines	(DR‐GE‐01	to	DR‐GE‐06)fuel	based	operational	limit11 Revise	Painting	Operations	(DR‐PO‐01)emissions	due	to	addition	of	new	paints	andthinnersNo	Impact	on	EmissionsNo	Impact	on	EmissionsNo	Impact	on	EmissionsNo	Impact	on	EmissionsNo	Impact	on	Emissions6 Add	two	wire	line	engines	(DR‐WC‐09	and	DR‐WC‐10)	to	the	well	completion	operation	–Scenario	4Anadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit 2 of 40Changes SummaryDate Printed - 6/26/2013Anadarko Petroleum CorporationEmissions Summary - Discoverer Spirit Drillship, Support Vessels & Well CompletionTable 1 - Annual Emissions Summary (tons/year)PMPM10PM2.5NOxSO2H2SO4CO VOC PbCO2eAcetaldehyde Acrolein Benzene Formaldehyde Toluene Xylenes Total PAH 1,3-Butadiene Naphthalene Ethylbenzene ButanoneHexamethylene-diisocyanateDichlorobenzene Hexane Arsenic Beryllium Cadmium Chromium Cobalt Manganese Mercury Nickel Selenium POM Total VOC HAPstons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tons tonstonsDR-GE-01 Main Propulsion Electrical Generator Engine #1A14.128.097.85 509.460.23 0.01 32.0911.564.09E-0323,097.323.56E-031.11E-031.10E-01 1.11E-023.97E-022.72E-022.99E-020 1.84E-020 0 0 0 000000000002.22E-01DR-GE-02 Main Propulsion Electrical Generator Engine #1B14.128.097.85 509.460.23 0.01 32.0911.564.09E-0323,097.323.56E-031.11E-031.10E-01 1.11E-023.97E-022.72E-022.99E-020 1.84E-020 0 0 0 000000000002.22E-01DR-GE-03 Main Propulsion Electrical Generator Engine #1C14.128.097.85 509.460.23 0.01 32.0911.564.09E-0323,097.323.56E-031.11E-031.10E-01 1.11E-023.97E-022.72E-022.99E-020 1.84E-020 0 0 0 000000000002.22E-01DR-GE-04 Main Propulsion Electrical Generator Engine #1D14.128.097.85 509.460.23 0.01 32.0911.564.09E-0323,097.323.56E-031.11E-031.10E-01 1.11E-023.97E-022.72E-022.99E-020 1.84E-020 0 0 0 000000000002.22E-01DR-GE-05 Main Propulsion Electrical Generator Engine #2A9.41 5.395.23 339.640.15 4.71E-0321.397.71 2.73E-0315,398.212.37E-037.42E-047.30E-027.43E-032.64E-021.82E-022.00E-020 1.22E-020 0 0 0 000000000001.48E-01DR-GE-06 Main Propulsion Electrical Generator Engine #2B 9.41 5.39 5.23 339.64 0.15 4.71E-03 21.39 7.71 2.73E-03 15,398.21 2.37E-03 7.42E-047.30E-02 7.43E-03 2.64E-02 1.82E-02 2.00E-02 0 1.22E-02 0 0 0 0000000000001.48E-0119.14 10.97 10.64 690.83 0.31 0.01 43.52 15.68 0.01 31,319.97 4.82E-03 1.51E-03 1.49E-01 1.51E-02 5.38E-02 3.69E-02 4.06E-02 0 2.49E-02 0 0 0 0000000000003.01E-01DR-WO-01 Welding Emissions on Drillship 0.20 0.20 0.20 0.00 0.00 0.00 0.00E+00 0.00 8.42E-040.000 00 0 0 0 0 0 0 0 0 0 0 0 0 0 01.32E-025.20E-061.14E-020 1.02E-030 0 0.00E+00DR-VS-01 Well evaluation engine #10.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04DR-VS-02 Well evaluation engine #20.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04DR-VS-03 Well evaluation engine #30.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04DR-VS-04 Well evaluation engine #40.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04DR-VS-05 Well evaluation engine #5 0.02 0.02 0.02 0.21 9.81E-05 3.07E-06 0.14 0.01 1.78E-06 10.02 4.70E-05 5.67E-06 5.71E-05 7.23E-05 2.51E-05 1.75E-05 1.03E-05 2.39E-06 5.19E-06 0 0 0 0000000000002.37E-04DR-GE-07 Emergency Generator0.000.000.000.000.00E+000.00E+000.000.000.00E+000.000.00E+000.00E+000.00E+000.00E+000.00E+000.00E+000.00E+000 0.00E+000 0 0 0 000000000000.00E+00DR-GE-08 ROV Emergency Generator0.01 0.01 0.01 0.222.38E-047.45E-060.120.05 4.31E-0624.341.14E-041.38E-051.39E-041.76E-046.08E-054.24E-052.50E-055.82E-061.26E-050 0 0 0 000000000005.76E-04DR-AC-01 Air Compressor Diesel Engine #11.03E-031.03E-031.03E-030.01 5.25E-061.64E-073.13E-031.18E-039.50E-080.542.51E-063.03E-073.06E-063.87E-061.34E-069.34E-075.50E-071.28E-072.78E-070 0 0 0 000000000001.27E-05DR-AC-02 Air Compressor Diesel Engine #28.58E-048.58E-048.58E-040.01 4.37E-061.37E-072.61E-039.80E-047.92E-080.45 2.09E-062.53E-072.55E-063.22E-061.12E-067.78E-074.59E-071.07E-072.32E-070 0 0 0 000000000001.06E-05DR-EC-01 Escape Capsule Diesel Engine #1 4.29E-03 4.29E-03 4.29E-03 0.06 2.19E-05 6.83E-07 0.01 4.90E-03 3.96E-07 2.23 1.05E-05 1.26E-06 1.27E-05 1.61E-05 5.58E-06 3.89E-06 2.29E-06 5.34E-07 1.16E-060 0 0 0 000000000005.29E-05DR-EC-02 Escape Capsule Diesel Engine #24.29E-034.29E-034.29E-030.062.19E-056.83E-070.01 4.90E-033.96E-072.23 1.05E-051.26E-061.27E-051.61E-055.58E-063.89E-062.29E-065.34E-071.16E-060 0 0 0 000000000005.29E-05DR-EC-03 Escape Capsule Diesel Engine #34.29E-034.29E-034.29E-030.062.19E-056.83E-070.01 4.90E-033.96E-072.23 1.05E-051.26E-061.27E-051.61E-055.58E-063.89E-062.29E-065.34E-071.16E-060 0 0 0 000000000005.29E-05DR-EC-04 Escape Capsule Diesel Engine #44.29E-034.29E-034.29E-030.062.19E-056.83E-070.01 4.90E-033.96E-072.23 1.05E-051.26E-061.27E-051.61E-055.58E-063.89E-062.29E-065.34E-071.16E-060 0 0 0 000000000005.29E-05DR-EC-05 Escape Capsule Diesel Engine #56.38E-036.38E-036.38E-030.093.25E-051.02E-060.027.29E-032.94E-071.667.79E-069.39E-079.47E-061.20E-054.15E-062.89E-061.71E-063.97E-078.61E-070 0 0 0 000000000003.93E-05DR-EC-06 Escape Capsule Diesel Engine #66.38E-036.38E-036.38E-030.093.25E-051.02E-060.027.29E-032.94E-071.667.79E-069.39E-079.47E-061.20E-054.15E-062.89E-061.71E-063.97E-078.61E-070 0 0 0 000000000003.93E-05DR-FL-01 Diesel Powered Forklift Engine 0.16 0.16 0.16 2.32 8.40E-04 2.62E-05 0.50 0.19 1.52E-05 85.75 4.02E-04 4.85E-05 4.89E-04 6.19E-04 2.14E-04 1.49E-04 8.81E-05 2.05E-05 4.44E-050 0 0 0 000000000002.03E-03DR-WL-01 Wire line Diesel Engine #10.070.070.072.15 2.22E-036.94E-051.140.504.02E-05226.751.06E-031.28E-041.29E-031.64E-035.67E-043.95E-042.33E-045.42E-051.18E-040 0 0 0 000000000005.37E-03DR-WL-02 Wire line Diesel Engine #20.070.070.072.15 2.22E-036.94E-051.140.504.02E-05226.751.06E-031.28E-041.29E-031.64E-035.67E-043.95E-042.33E-045.42E-051.18E-040 0 0 0 000000000005.37E-03DR-EL-01 Electric line Diesel Engine #10.25 0.25 0.25 8.128.40E-032.62E-044.31 1.881.52E-04857.544.02E-034.85E-044.89E-036.19E-032.14E-031.49E-038.81E-042.05E-044.44E-040 0 0 0 000000000002.03E-02DR-EL-02 Electric line Diesel Engine #20.25 0.25 0.25 8.128.40E-032.62E-044.31 1.881.52E-04857.544.02E-034.85E-044.89E-036.19E-032.14E-031.49E-038.81E-042.05E-044.44E-040 0 0 0 000000000002.03E-02DR-CU-01 Casing Unit Diesel Engine #10.15 0.15 0.15 3.35 3.46E-031.08E-042.540.786.26E-05353.31 1.66E-032.00E-042.01E-032.55E-038.83E-046.15E-043.63E-048.44E-051.83E-040 0 0 0 000000000008.37E-03DR-CU-02 Casing Unit Diesel Engine #20.15 0.15 0.15 3.35 3.46E-031.08E-042.540.786.26E-05353.31 1.66E-032.00E-042.01E-032.55E-038.83E-046.15E-043.63E-048.44E-051.83E-040 0 0 0 000000000008.37E-03DR-FR-01 Fast Rescue Craft 7.56E-03 7.56E-03 7.56E-03 0.14 1.29E-04 4.03E-06 0.09 0.03 2.33E-06 13.17 6.17E-05 7.45E-06 7.51E-05 9.50E-05 3.29E-05 2.29E-05 1.35E-05 3.15E-06 6.83E-060 0 0 0 000000000003.12E-04DR-WB-01 Water Blasting Engine 0.09 0.09 0.09 1.71 2.91E-03 9.10E-05 1.49 0.65 5.27E-05 297.28 1.39E-03 1.68E-04 1.70E-03 2.14E-03 7.43E-04 5.18E-04 3.05E-04 7.10E-05 1.54E-04 0 0 0 0000000000007.04E-031.52 1.52 1.52 33.15 3.29E-02 1.03E-03 18.98 7.31 1.44E-03 3,359.08 1.57E-02 1.90E-03 1.92E-02 2.42E-02 8.40E-03 5.85E-03 3.45E-03 8.03E-04 1.74E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 07.95E-02DR-DT-01Forward Fuel Oil Drain Tank(T-21 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-02Aft Fuel Oil Drain Tank(T-24)000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-03Diesel Fuel Overflow Tank(T-28)000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-04Starboard Main Diesel Storage Tank(T-29000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-05Port Main Diesel Storage Tank(T-30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-06Starboard Engine Room Diesel DayTank(T-31000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-07Port Engine Room Diesel DayTank(T-32000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-08Starboard Engine Room Diesel SettlingTank(T-33000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-09Port Engine Room Diesel SettlingTank(T-34000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-FT-01Helicopter Fuel Tank #10 0 0 0 0 0 0 0.13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-FT-02Helicopter Fuel Tank #20 0 0 0 0 0 0 0.13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-FT-03Helicopter Fuel Tank #30 0 0 0 0 0 0 0.13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.71 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DC-01Dust Collector #10.220.220.220 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DC-02Dust Collector #20.220.220.220 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DC-03Dust Collector #30.30 0.30 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0Drill Ship Dust Collectors Emissions0.74 0.74 0.74 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000000000000.00DR-PO-01 Painting Operation 0.13 0.13 0.13 0 0 0 0 9.00 0 0 0 0 0 0 0 4.56 0 0 0 1.10 1.16 0.01 0000000000006.82Drill Ship Painting Emissions0.13 0.13 0.13 0 0 0 0 9.00 0 0 0 0 0 0 0 4.56 0 0 0 1.10 1.16 0.01 0000000000006.82DR-FE-01Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-VG-01Mud Degasser Vent0 0 0 0 0 0 0 5.57 0 282 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 5.57 0 282 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 021.53 13.36 13.03 723.98 0.34 0.01 62.50 38.29 0.01 34,961.27 2.06E-02 3.41E-03 1.68E-01 3.93E-02 6.22E-02 4.60 4.40E-02 8.03E-04 2.66E-02 1.10 1.16 0.01 0000000000007.20Hazardous Air Pollutants (HAPs)Discoverer Spirit TransoceanMain Engines Worst-Case Operating Emissions (Maximum 325 bbls/day of fuel used for allmain engines)TOTAL - Drillship Emission ScenarioDrilling Misc Engines Worst-Case Operating EmissionsDrill Ship Tanks Emissions0.32Emission Unit ID Emission UnitNSR Regulated Air Pollutants & Greenhouse Gas Emissions (CO2e)Drill Ship Fugitive EmissionsDrill Ship Mud Degasser Vent EmissionsAnadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit3 of 40Annual Emission SummaryDate Printed - 6/26/2013SB-ME-01 Diesel Marine Propulsion Engine #13.08 2.53 2.46 110.94 0.11 3.28E-03 77.04 6.01 1.90E-03 9782.24 1.51E-03 4.71E-04 0.05 4.72E-03 0.02 0.01 0.01 0 0.01 0 0 0 0000000000000.09SB-ME-02 Diesel Marine Propulsion Engine #23.08 2.53 2.46 110.94 0.11 3.28E-03 77.04 6.01 1.90E-03 9782.24 1.51E-03 4.71E-04 0.05 4.72E-03 0.02 0.01 0.01 0 0.01 0 0 0 0000000000000.09SB-TE-01 Diesel Marine Forward Bow Thruster Engine #11.13 0.93 0.90 40.62 0.04 1.20E-03 28.21 2.20 6.97E-04 3575.17 5.51E-04 1.72E-04 0.02 1.72E-03 0.01 4.22E-03 4.63E-03 0 2.84E-03 0 0 0 0000000000000.03SB-TE-02 Diesel Marine Aft Bow Thruster Engine #21.13 0.93 0.90 40.62 0.04 1.20E-03 28.21 2.20 6.97E-04 3575.17 5.51E-04 1.72E-04 0.02 1.72E-03 0.01 4.22E-03 4.63E-03 0 2.84E-03 0 0 0 0000000000000.03SB-TE-03 Diesel Marine Stern Thruster Engine #31.13 0.93 0.90 40.62 0.04 1.20E-03 28.21 2.20 6.97E-04 3575.17 5.51E-04 1.72E-04 0.02 1.72E-03 0.01 4.22E-03 4.63E-03 0 2.84E-03 0 0 0 0000000000000.03SB-GE-01 Port Electrical Generator Diesel Engine #11.07 0.88 0.86 38.67 0.04 1.14E-03 26.85 2.10 6.63E-04 3350.90 5.16E-04 1.61E-04 0.02 1.62E-03 0.01 3.95E-03 4.34E-03 0 2.66E-03 0 0 0 0000000000000.03SB-GE-02 Starboard Electrical Generator Diesel Engine #21.07 0.88 0.86 38.67 0.04 1.14E-03 26.85 2.10 6.63E-04 3350.90 5.16E-04 1.61E-04 0.02 1.62E-03 0.01 3.95E-03 4.34E-03 0 2.66E-03 0 0 0 0000000000000.03SB-GE-03 Emergency Electrical Generator Diesel Engine #30 0 0 0 0 0 0 0 0 14 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-GE-04 ROV Electric Generator Diesel Engine #41.95E-01 1.95E-01 1.95E-01 6.24 1.09E-05 3.41E-07 3.41 0.00 1.98E-07 678.89 3.18E-03 3.84E-04 3.87E-03 4.90E-03 1.70E-03 1.18E-03 6.97E-04 1.62E-04 3.52E-04 0 0 0 0000000000001.61E-02SB-VS-01 Well evaluation engine #10.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04SB-VS-02 Well evaluation engine #20.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04SB-VS-03 Well evaluation engine #30.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04SB-VS-04 Well evaluation engine #40.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04SB-VS-05 Well evaluation engine #50.020.020.020.21 9.81E-053.07E-060.140.01 1.78E-0610.024.70E-055.67E-065.71E-057.23E-052.51E-051.75E-051.03E-052.39E-065.19E-060 0 0 0 000000000002.37E-04SB-VS-06 Well evaluation engine #60.05 0.05 0.05 0.702.52E-04 7.88E-060.15 0.064.57E-0625.771.21E-04 1.46E-05 1.47E-04 1.86E-04 6.44E-05 4.49E-05 2.65E-05 6.16E-06 1.34E-050 0 0 0 000000000006.10E-04SB-VS-07 Well evaluation engine #70.05 0.05 0.05 0.702.52E-04 7.88E-060.15 0.064.57E-0625.771.21E-04 1.46E-05 1.47E-04 1.86E-04 6.44E-05 4.49E-05 2.65E-05 6.16E-06 1.34E-050 0 0 0 000000000006.10E-04SB-VS-08 Well evaluation engine crane #10.01 0.01 0.01 0.124.35E-05 1.36E-060.03 0.017.87E-074.442.08E-05 2.51E-06 2.53E-05 3.20E-05 1.11E-05 7.73E-06 4.56E-06 1.06E-06 2.30E-060 0 0 0 000000000001.05E-04SB-VS-09 Well evaluation engine crane #2 0.02 0.02 0.02 0.25 9.11E-05 2.85E-06 0.05 0.02 1.65E-06 9.30 4.36E-05 5.26E-06 5.31E-05 6.71E-05 2.33E-05 1.62E-05 9.56E-06 2.22E-06 4.82E-06 0 0 0 0000000000002.20E-0411.90 9.82 9.53 427.48 0.40 1.25E-02 295.94 22.83 7.22E-03 37,685.09 8.95E-03 2.17E-03 0.18 0.02 0.07 0.04 0.05 1.66E-04 0.03 0 0 0 0000000000000.37SB-DT-01Vessel's Diesel Fuel Storage Tank #1 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-02Vessel's Diesel Fuel Storage Tank #1 Starboar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-03Vessel's Diesel Fuel Storage Tank #2 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-04Vessel's Diesel Fuel Storage Tank #2 Starboar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-05Vessel's Diesel Fuel Storage Tank #3 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-06Vessel's Diesel Fuel Storage Tank #3 Starboar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-07Vessel's Diesel Fuel Storage Tank #4 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-08Vessel's Diesel Fuel Storage Tank #4 Starboar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-09Vessel's Diesel Fuel Storage Tank #5 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-10Vessel's Diesel Fuel Storage Tank #5 Starboar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-11Vessel's Diesel Fuel Storage DayTank #1 Por000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-12Vessel's Diesel Fuel Storage DayTank #1 Starboar000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-13Vessel's Diesel Fuel Stern Thruster DayTank000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-14Vessel's Diesel Fuel Overflow Port Storage Tan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-DT-15Vessel's Diesel Fuel Overflow Stbd Storage Tank000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0.08 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-FE-01Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-ME-01 Diesel Marine Propulsion Engine #113.23 7.58 7.35 453.47 0.21 6.62E-03 103.92 12.12 3.84E-03 21,638.58 3.33E-03 1.04E-03 0.10 0.01 0.04 0.03 0.03 0 0.02 0 0 0 0000000000000.21AB-ME-02 Diesel Marine Propulsion Engine #213.23 7.58 7.35 453.47 0.21 6.62E-03 103.92 12.12 3.84E-03 21,638.58 3.33E-03 1.04E-03 0.10 0.01 0.04 0.03 0.03 0 0.02 0 0 0 0000000000000.21AB-TE-01 Bow Tunnel Thruster Engine2.92 1.68 1.63 100.28 0.05 1.46E-03 22.98 2.68 8.48E-04 4,785.07 7.37E-04 2.30E-04 0.02 2.31E-03 8.22E-03 5.64E-03 6.20E-03 0 3.80E-03 0 0 0 0000000000000.05AB-TE-02 Aft Tunnel Thruster Engine2.92 1.68 1.63 100.28 0.05 1.46E-03 22.98 2.68 8.48E-04 4,785.07 7.37E-04 2.30E-04 0.02 2.31E-03 8.22E-03 5.64E-03 6.20E-03 0 3.80E-03 0 0 0 0000000000000.05AB-TE-03 Bow Drop Down Thruster2.92 1.68 1.63 100.28 0.05 1.46E-03 22.98 2.68 8.48E-04 4,785.07 7.37E-04 2.30E-04 0.02 2.31E-03 8.22E-03 5.64E-03 6.20E-03 0 3.80E-03 0 0 0 0000000000000.05AB-GE-01 Service Generator Engine 11.25 0.72 0.70 42.89 0.02 6.26E-04 9.83 1.15 3.63E-04 2,046.66 3.15E-04 9.86E-05 0.01 9.87E-04 3.52E-03 2.41E-03 2.65E-03 0 1.63E-03 0 0 0 0000000000000.02AB-GE-02 Service Generator Engine 21.25 0.72 0.70 42.89 0.02 6.26E-04 9.83 1.15 3.63E-04 2,046.66 3.15E-04 9.86E-05 0.01 9.87E-04 3.52E-03 2.41E-03 2.65E-03 0 1.63E-03 0 0 0 0000000000000.02AB-GE-03 Service Generator Engine 31.25 0.72 0.70 42.89 0.02 6.26E-04 9.83 1.15 3.63E-04 2,046.66 3.15E-04 9.86E-05 0.01 9.87E-04 3.52E-03 2.41E-03 2.65E-03 0 1.63E-03 0 0 0 0000000000000.02AB-GE-04 Service Generator Engine 42.27 1.30 1.26 77.88 0.04 1.14E-03 17.85 2.08 6.59E-04 3,716.01 5.72E-04 1.79E-04 0.02 1.79E-03 6.38E-03 4.38E-03 4.82E-03 0 2.95E-03 0 0 0 0000000000000.04AB-GE-05 Service Generator Engine 52.27 1.30 1.26 77.88 0.04 1.14E-03 17.85 2.08 6.59E-04 3,716.01 5.72E-04 1.79E-04 0.02 1.79E-03 6.38E-03 4.38E-03 4.82E-03 0 2.95E-03 0 0 0 0000000000000.04AB-GE-06 Emergency Generator0.03 0.03 0.03 0.48 1.72E-04 5.38E-06 0.10 0.04 3.12E-06 17.58 8.24E-05 9.94E-06 1.00E-04 1.27E-04 4.39E-05 3.06E-05 1.81E-05 4.20E-06 9.11E-06 0 00 0 000000000004.16E-04AB-GE-07 Port Winch Hydraulic Engine2.27 1.30 1.26 77.88 0.036 1.14E-03 17.85 2.08 6.59E-04 3,716.01 5.72E-04 1.79E-04 0.02 1.79E-03 6.38E-03 4.38E-03 4.82E-03 0 2.95E-03 0 0 0 0000000000000.04AB-GE-08 Starboard Winch Hydraulic Engine 2.27 1.30 1.26 77.88 0.04 1.14E-03 17.85 2.08 6.59E-04 3,716.01 5.72E-04 1.79E-04 0.02 1.79E-03 6.38E-03 4.38E-03 4.82E-03 0 2.95E-03 0 0 0 0000000000000.0412.17 6.97 6.77 417.20 0.19 0.01 95.61 11.15 3.53E-03 19,907.50 3.07E-03 9.59E-04 0.09 9.60E-03 3.42E-02 2.35E-02 2.58E-02 4.20E-06 0.02 0 0 0 0000000000000.19AB-DT-01 Port Side Double Bottom Diesel Fuel Tank #1000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-02Starboard Side Double Bottom Diesel Fuel Tank #1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-03Center Double Bottom Diesel Fuel Tank #1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-04Port Side Double Bottom Diesel Fuel Tank #2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-05Starboard Side Double Bottom Diesel Fuel Tank #2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-06Port Wing Diesel Fuel Tank #1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-07Starboard Wing Diesel Fuel Tank #1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-08Port Side Double Bottom Diesel Fuel Tank #3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-09Starboard Side Double Bottom Diesel Fuel Tank #3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-10Port Wing Diesel Fuel Tank #2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-11Starboard Side Double Bottom Diesel Fuel Tank #4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-12Starboard Wing Diesel Fuel Tank #2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-13Port Side Double Bottom Diesel Fuel Tank #4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-14Starboard Side Double Bottom Diesel Fuel Tank #5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-15Port Service Diesel Tank 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-16Starboard Service Diesel Tank 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-17Port Diesel Settling Tank 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-18Starboard Diesel Settling Tank 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-19 Diesel Overflow Tank 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-FE-01Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 011.92 9.80 9.51 435.62 0.41 0.01 301.57 23.36 0.01 38401.70 8.95E-03 2.17E-03 0.18 0.02 0.07 0.04 0.05 1.66E-04 0.03 0 0 0 0000000000000.3612.17 6.97 6.77 417.20 0.19 6.09E-03 95.61 11.15 3.53E-03 19,907.50 3.07E-03 9.59E-04 0.09 0.01 0.03 0.02 0.03 4.20E-06 0.02 0 0 0 0000000000000.1912.17 9.80 9.51 435.62 0.41 1.27E-02 301.57 23.36 7.36E-03 38,401.70 8.95E-03 2.17E-03 0.18 0.02 0.07 0.04 0.05 1.66E-04 0.03 0 0 0 0000000000000.36SV-ME-01Stimulation Vessel Main Engine #10.19 0.11 0.10 3.27 2.57E-03 8.02E-05 1.88 0.15 4.65E-05 262.19 4.04E-05 1.26E-05 1.24E-03 1.26E-04 4.50E-04 3.09E-04 3.40E-04 0 2.08E-04 0 0 0 0000000000002.52E-03SV-ME-02Stimulation Vessel Main Engine #20.19 0.11 0.10 3.27 2.57E-03 8.02E-05 1.88 0.15 4.65E-05 262.19 4.04E-05 1.26E-05 1.24E-03 1.26E-04 4.50E-04 3.09E-04 3.40E-04 0 2.08E-04 0 0 0 0000000000002.52E-03SV-BT-01Stimulation Vessel Bow Thruster0.07 0.04 0.04 2.53 1.18E-03 3.70E-05 0.58 0.07 2.14E-05 120.85 1.86E-05 5.82E-06 5.73E-04 5.83E-05 2.08E-04 1.43E-04 1.57E-04 0 9.60E-05 0 0 0 0000000000001.16E-03SV-DD-01Stimulation Vessel Bow Drop-Down0.05 0.03 0.03 1.81 8.48E-04 2.65E-05 0.42 0.05 1.53E-05 86.58 1.33E-05 4.17E-06 4.11E-04 4.18E-05 1.49E-04 1.02E-04 1.12E-04 0 6.88E-05 0 0 0 0000000000008.33E-04SV-ST-01Stimulation Vessel Stern Thruster0.07 0.04 0.04 2.53 1.18E-03 3.70E-05 0.58 0.07 2.14E-05 120.85 1.86E-05 5.82E-06 5.73E-04 5.83E-05 2.08E-04 1.43E-04 1.57E-04 0 9.60E-05 0 0 0 0000000000001.16E-03SV-PE-01 thru SV-PE-08Stimulation Vessel Representative Pumps3.18 1.82 1.77 108.86 0.05 1.59E-03 24.95 2.91 9.21E-04 5194.71 8.00E-04 2.50E-04 2.46E-02 2.51E-03 8.92E-03 6.13E-03 6.73E-03 0 4.13E-03 0 0 0 0000000000000.05SV-GE-01 and SV-GE-02Stimulation Vessel Generators Chouest0.20 0.12 0.11 6.47 6.90E-03 2.15E-04 3.54 0.39 1.25E-04 704.35 1.08E-04 3.39E-05 3.34E-03 3.40E-04 1.21E-03 8.31E-04 9.13E-04 0 5.60E-04 0 0 0 0000000000006.78E-03SV-GE-03 and SV-GE-04 Stimulation Vessel Generators Baker Hughes 0.13 0.08 0.07 4.27 4.55E-03 1.42E-04 2.33 0.26 8.23E-05 464.41 7.15E-05 2.24E-05 2.20E-03 2.24E-04 7.98E-04 5.48E-04 6.02E-04 0 3.69E-04 0 0 0 0000000000004.47E-034.09 2.34 2.27 133.03 7.07E-02 2.21E-03 36.16 4.04 1.28E-03 7,216.12 1.11E-03 3.48E-04 3.42E-02 3.48E-03 1.24E-02 8.51E-03 9.35E-03 0.00E+00 5.73E-03 0 0 0 0000000000006.94E-02DR-WC-01 Tubing Running Unit Engine0.02 0.02 0.03 0.38 3.53E-04 1.10E-05 0.26 0.08 6.39E-06 36.03 1.69E-04 2.04E-05 2.05E-04 2.60E-04 9.01E-05 6.28E-05 3.70E-05 8.61E-06 1.87E-05 0 00 0 000000000008.53E-04DR-WC-02 Fluid Filtration Pump0.02 0.02 0.02 0.55 5.68E-04 1.77E-05 0.42 0.13 1.03E-05 57.95 2.72E-04 3.28E-05 3.30E-04 4.18E-04 1.45E-04 1.01E-04 5.95E-05 1.38E-05 3.00E-05 0 00 0 000000000001.37E-03DR-WC-03 Eline Power Pack0.03 0.03 0.03 0.88 9.08E-04 2.84E-05 0.47 0.20 1.64E-05 92.76 4.35E-04 5.24E-05 5.29E-04 6.69E-04 2.32E-04 1.62E-04 9.53E-05 2.22E-05 4.81E-05 0 00 0 000000000002.20E-03DR-WC-05 Flowback Boiler0.01 0.01 0.01 0.10 8.53E-04 0 0.02 8.01E-04 5.05E-06 91.71 0 0 0 2.44E-04 0 0 0 0 0.00 0 0 0 000000000001.32E-05 1.32E-05DR-WC-06 Boom Flare1.34 1.34 1.34 12.24 0.11 0 66.57 25.19 0 21,052.22 0 0 3.70E-04 0.01 6.00E-04 0 0 0 1.08E-04 0. 0 0 2.12E-04 0.32 3.53E-05 2.12E-06 1.94E-04 2.47E-04 1.48E-05 6.70E-05 4.59E-05 3.70E-04 4.23E-06 1.56E-05 0.33DR-WC-04 Slickline Power Pack0.03 0.03 0.03 0.98 1.02E-03 3.18E-05 0.52 0.23 1.84E-05 103.94 4.87E-04 5.88E-05 5.93E-04 7.50E-04 2.60E-04 1.81E-04 1.07E-04 2.48E-05 5.39E-05 00 0 0 000000000002.46E-03DR-WC-07 CT Power Pack0.07 0.07 0.07 2.27 2.42E-03 7.57E-05 1.24 0.54 4.38E-05 247.37 1.16E-03 1.40E-04 1.41E-03 1.78E-03 6.18E-04 4.31E-04 2.54E-04 5.91E-05 1.28E-04 00 0 0 000000000005.86E-03DR-WC-08 CT Pump0.10 0.06 0.06 3.26 3.47E-03 1.08E-04 1.78 0.20 6.28E-05 354.56 5.46E-05 1.71E-05 1.68E-03 1.71E-04 6.09E-04 4.18E-04 4.59E-04 0 2.82E-04 0 0 0 0000000000003.41E-03DR-WC-09 Wire line Diesel Engine #30.07 0.07 0.07 2.15 2.22E-03 6.94E-05 1.14 0.50 4.02E-05 226.75 1.06E-03 1.28E-04 1.29E-03 1.64E-03 5.67E-04 3.95E-04 2.33E-04 5.42E-05 1.18E-04 00 0 0 000000000005.37E-03DR-WC-10 Wire line Diesel Engine #4 0.07 0.07 0.07 2.15 2.22E-03 6.94E-05 1.14 0.50 4.02E-05 226.75 1.06E-03 1.28E-04 1.29E-03 1.64E-03 5.67E-04 3.95E-04 2.33E-04 5.42E-05 1.18E-04 0 0 0 0000000000005.37E-031.76 1.72 1.72 24.96 0.12 4.12E-04 73.56 27.57 2.44E-04 22,490.05 4.70E-03 5.78E-04 7.71E-03 2.08E-02 3.69E-03 2.15E-03 1.48E-03 2.37E-04 9.03E-04 0 0 0 2.12E-04 0.32 3.53E-05 2.12E-06 1.94E-04 2.47E-04 1.48E-05 6.70E-05 4.59E-05 3.70E-04 4.23E-06 2.88E-05 0.36TB-ME-01 Main Engine #10.39 0.22 0.22 7.15 6.22E-03 1.94E-04 3.05 0.36 1.13E-04 634.91 9.78E-05 3.06E-05 3.01E-03 3.06E-04 1.09E-03 7.49E-04 8.23E-04 0 5.05E-04 0 0 0 0000000000006.11E-03TB-ME-02 Main Engine# 20.39 0.22 0.22 7.15 6.22E-03 1.94E-04 3.05 0.36 1.13E-04 634.91 9.78E-05 3.06E-05 3.01E-03 3.06E-04 1.09E-03 7.49E-04 8.23E-04 0 5.05E-04 0 0 0 0000000000006.11E-03TB-ME-03 Main Engine #30.39 0.22 0.22 7.15 6.22E-03 1.94E-04 3.05 0.36 1.13E-04 634.91 9.78E-05 3.06E-05 3.01E-03 3.06E-04 1.09E-03 7.49E-04 8.23E-04 0 5.05E-04 0 0 0 0000000000006.11E-03TB-GE-01 Generator Engine #10.10 0.10 0.10 1.36 4.93E-04 1.54E-05 0.29 0.11 8.92E-06 50.31 2.36E-04 2.84E-05 2.87E-04 3.63E-04 1.26E-04 8.76E-05 5.17E-05 1.20E-05 2.61E-05 0 00 0 000000000001.19E-03TB-GE-02 Generator Engine #2 0.10 0.10 0.10 1.36 4.93E-04 1.54E-05 0.29 0.11 8.92E-06 50.31 2.36E-04 2.84E-05 2.87E-04 3.63E-04 1.26E-04 8.76E-05 5.17E-05 1.20E-05 2.61E-05 0 0 0 0000000000001.19E-033.10 1.78 1.73 57.24 0.05 1.55E-03 24.39 2.85 9.00E-045,079.277.82E-04 2.45E-04 2.41E-02 2.45E-03 8.72E-03 5.99E-03 6.58E-03 0.00E+00 4.04E-03 0 0 0 0000000000004.89E-02BG-LP-01 Barge Loading Pump Engine #1 0.30 0.30 0.30 4.22 1.53E-03 4.77E-05 0.91 0.34 2.76E-05 155.84 7.31E-04 8.81E-05 8.89E-04 1.12E-03 3.90E-04 2.71E-04 1.60E-04 3.72E-05 8.08E-05 0 0 0 0000000000003.69E-030.30 0.30 0.30 4.22 1.53E-03 4.77E-05 0.91 0.34 2.76E-05 155.84 7.31E-04 8.81E-05 8.89E-04 1.12E-03 3.90E-04 2.71E-04 1.60E-04 3.72E-05 8.08E-05 00 0 0 000000000003.69E-03WC-CT-01 Well Completion Condensate Tank #10 0 0 0 0 0 0 3.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0WC-CT-02 Well Completion Condensate Tank #20 0 0 0 0 0 0 3.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0WC-CT-03 Well Completion Condensate Tank #3 0 0 0 0 0 0 0 3.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 9.26 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 023.59 16.20 15.80 775.20 0.56 0.01 259.82 74.90 0.01 65,989.27 9.74E-03 2.33E-03 1.90E-01 3.80E-02 6.96E-02 4.61 5.14E-02 1.90E-04 3.15E-02 1.10 1.16 1.13E-02 0000000000007.5317.45 11.09 10.84 498.13 0.32 0.01 98.46 62.43 0.01 39,294.31 6.25E-03 1.47E-03 1.19E-01 2.46E-02 4.36E-02 4.59 3.21E-02 2.23E-04 1.97E-02 1.10 1.16 1.13E-02 0000000000007.2822.95 13.79 13.42 765.48 0.35 0.01 78.38 51.32 0.01 36,418.97 6.11E-03 1.52E-03 1.28E-01 1.59E-02 4.66E-02 4.59 3.48E-02 2.28E-04 2.13E-02 1.10 1.16 1.13E-02 0000000000007.0832.84 22.50 21.89 1,143.91 0.73 0.02 354.36 57.68 0.01 71,783.79 1.86E-02 3.92E-03 2.81E-01 4.25E-02 1.03E-01 4.63 7.55E-02 5.03E-04 4.61E-02 1.101.16 1.13E-02 0000000000007.3832.84 22.50 21.89 1,143.91 0.73 2.28E-02 354.36 74.90 1.41E-02 71,783.79 1.86E-02 3.92E-03 2.81E-01 4.25E-02 1.03E-01 4.63 7.55E-02 5.03E-04 4.61E-02 1.10 1.16 1.13E-02 2.12E-04 3.18E-01 3.53E-05 2.12E-06 1.94E-04 1.34E-02 2.00E-05 1.15E-02 4.59E-05 1.39E-03 4.23E-06 2.88E-05 7.5333.70 23.16 22.55 1,159.60 0.75 0.02 364.08 61.66 0.01 73,362.97 2.95E-02 5.58E-03 3.47E-01 6.22E-02 1.27E-01 4.65 9.27E-02 9.68E-04 5.64E-02 1.101.16 1.13E-02 0000000000007.5532.84 22.50 21.89 1,143.91 0.73 0.02 354.36 74.90 0.01 71,783.79 1.86E-02 3.92E-03 2.81E-01 4.25E-02 1.03E-01 4.63 7.55E-02 5.03E-04 4.61E-02 1.101.16 1.13E-02 2.12E-04 0.32 3.53E-05 2.12E-06 1.94E-04 1.34E-02 2.00E-05 1.15E-02 4.59E-05 1.39E-03 4.23E-06 2.88E-05 7.53HOS Coral Work Boat or Similar Supply Boat Tanks EmissionsTOTAL - Supply Boats Scenario (HOS Coral or Similar)TOTAL (Drillship + Support Vessel ) Drilling Operating ScenarioSupply Boat Fugitive Emissions0.08Kirt Chouest Anchor Handling Boat Engines- TOTAL (Max 7500 gpd of fuel usage)0.00Kirt Chouest Anchor Handling Boat Tanks EmissionsAnchor Handling Boat Fugitive EmissionsTOTAL - Anchor Handling Boat Scenario (Kirt Chouest or Similar)TOTAL - Worst-Case Support Vessels ScenarioStimulation Vessel Operation - TOTALWell Completion Misc Operation - TOTALRepresentative Tug Operation - TOTAL (Max 340 bbls per day of fuel usage)Representative Barge Operation - TOTALWell Completion Condensate Tanks - TOTALHOS Coral Work Boat Engines or Similar Supply Boat- TOTALSupport VesselsDiscoverer Spirit Well CompletionTOTAL (Well Completion + Support Vessel ) Completion OperatingScenarioTOTAL - Worst-Case Well Completion ScenarioTOTAL - Worst-Case Gas Well Flowback ScenarioTOTAL - Worst-Case Oil Well Flowback ScenarioTOTAL - Stimulation Vessel Operation ScenarioTOTAL - Third Party Equipment Operation ScenarioAnadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit4 of 40Annual Emission SummaryDate Printed - 6/26/2013Anadarko Petroleum CorporationEmissions Summary - Discoverer Spirit Drillship, Support Vessels & Well CompletionTable 2 - Maximum Daily Emissions Summary (lb/day)PMPM10PM2.5NOxSO2H2SO4CO VOC PbCO2eAcetaldehyde Acrolein Benzene Formaldehyde Toluene Xylenes Total PAH 1,3-Butadiene Naphthalene Ethylbenzene ButanoneHexamethylene-di-isocyanateDichlorobenzene Hexane Arsenic Beryllium Cadmium Chromium Cobalt Manganese Mercury Nickel Selenium POM Total VOC HAPslb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/day lb/dayDR-GE-01 Main Propulsion Electrical Generator Engine #1A 135.75 77.78 75.48 4,898.66 2.18 0.07 308.58 111.18 0.04 222,089.62 3.42E-02 1.07E-02 1.05 1.07E-01 3.81E-01 2.62E-01 2.88E-01 0 1.76E-01 0 0 0 0 0 0 0000000002.14DR-GE-02 Main Propulsion Electrical Generator Engine #1B 135.75 77.78 75.48 4,898.66 2.18 0.07 308.58 111.18 0.04 222,089.62 3.42E-02 1.07E-02 1.05 1.07E-01 3.81E-01 2.62E-01 2.88E-01 0 1.76E-01 0 0 0 0 0 0 0000000002.14DR-GE-03 Main Propulsion Electrical Generator Engine #1C 135.75 77.78 75.48 4,898.66 2.18 0.07 308.58 111.18 0.04 222,089.62 3.42E-02 1.07E-02 1.05 1.07E-01 3.81E-01 2.62E-01 2.88E-01 0 1.76E-01 0 0 0 0 0 0 0000000002.14DR-GE-04 Main Propulsion Electrical Generator Engine #1D 135.75 77.78 75.48 4,898.66 2.18 0.07 308.58 111.18 0.04 222,089.62 3.42E-02 1.07E-02 1.05 1.07E-01 3.81E-01 2.62E-01 2.88E-01 0 1.76E-01 0 0 0 0 0 0 0000000002.14DR-GE-05 Main Propulsion Electrical Generator Engine #2A 90.50 51.86 50.32 3,265.77 1.45 0.05 205.72 74.12 0.03 148,059.75 2.28E-02 7.13E-037.02E-01 7.14E-02 2.54E-01 1.75E-01 1.92E-01 0 1.18E-01 0 0 0 0 0 0 0000000001.42DR-GE-06 Main Propulsion Electrical Generator Engine #2B 90.50 51.86 50.32 3,265.77 1.45 0.05 205.72 74.12 0.03 148,059.75 2.28E-02 7.13E-037.02E-01 7.14E-02 2.54E-01 1.75E-01 1.92E-01 0 1.18E-01 0 0 0 0 0 0 0000000001.42DR-GE-07 Emergency Generator 3.59 2.06 2.00 115.01 5.76E-02 1.80E-03 30.55 2.94 1.04E-03 5,879.98 9.06E-04 2.83E-04 2.79E-02 2.84E-03 1.01E-02 6.94E-03 7.62E-03 0 4.67E-03 0 0 0 0 0 0 0000000005.66E-02240.28 137.68 133.59 8,670.62 3.85 0.12 546.18 196.79 0.07 393,098.64 6.05E-02 1.89E-02 1.86 1.90E-01 6.75E-01 4.64E-01 5.09E-01 0 3.12E-01 0 0 0 0 0 00 0 0.00E+00 0.00E+00 0.00E+00 0 0.00E+00 0 0 3.78DR-WO-01 Welding Emissions on Drillship 1.92 1.92 1.92 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.27E-01 5.00E-05 1.10E-01 0 9.80E-03 0 0 0.00DR-VS-01 Well evaluation engine #17.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.003,847.93 1.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09DR-VS-02 Well evaluation engine #27.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.003,847.93 1.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09DR-VS-03 Well evaluation engine #37.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.003,847.93 1.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09DR-VS-04 Well evaluation engine #47.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.003,847.93 1.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09DR-VS-05 Well evaluation engine #57.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.003,847.93 1.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09DR-GE-08 ROV Emergency Generator 0.14 0.14 0.14 4.47 4.77E-03 1.49E-04 2.45 1.07 8.63E-05 486.72 2.28E-03 2.75E-04 2.78E-03 3.51E-03 1.22E-03 8.48E-04 5.00E-04 1.16E-04 2.52E-04 0 0 0 0 0 0 0000000001.15E-02DR-AC-01 Air Compressor Diesel Engine #1 0.02 0.02 0.02 0.28 1.01E-04 3.15E-06 0.06 0.02 1.83E-06 10.31 4.83E-05 5.83E-06 5.88E-05 7.43E-05 2.58E-05 1.80E-05 1.06E-05 2.46E-06 5.34E-06 0 0 0 0 0 0 0000000002.44E-04DR-AC-02 Air Compressor Diesel Engine #2 0.02 0.02 0.02 0.23 8.41E-05 2.63E-06 0.05 0.02 1.52E-06 8.59 4.03E-05 4.86E-06 4.90E-05 6.20E-05 2.15E-05 1.50E-05 8.82E-06 2.05E-06 4.45E-06 0 0 0 0 0 0 0000000002.03E-04DR-EC-01 Escape Capsule Diesel Engine #1 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0 0 0 0000000005.29E-04DR-EC-02 Escape Capsule Diesel Engine #2 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0 0 0 0000000005.29E-04DR-EC-03 Escape Capsule Diesel Engine #3 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0 0 0 0000000005.29E-04DR-EC-04 Escape Capsule Diesel Engine #4 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0 0 0 0000000005.29E-04DR-EC-05 Escape Capsule Diesel Engine #5 0.03 0.03 0.03 0.45 1.63E-04 5.08E-06 0.10 0.04 2.94E-06 16.61 7.79E-05 9.39E-06 9.47E-05 1.20E-04 4.15E-05 2.89E-05 1.71E-05 3.97E-06 8.61E-06 0 0 0 0 0 0 0000000003.93E-04DR-EC-06 Escape Capsule Diesel Engine #6 0.03 0.03 0.03 0.45 1.63E-04 5.08E-06 0.10 0.04 2.94E-06 16.61 7.79E-05 9.39E-06 9.47E-05 1.20E-04 4.15E-05 2.89E-05 1.71E-05 3.97E-06 8.61E-06 0 0 0 0 0 0 0000000003.93E-04DR-FL-01 Diesel Powered Forklift Engine 1.58 1.58 1.58 22.32 8.08E-03 2.52E-04 4.81 1.81 1.46E-04 824.56 3.87E-03 4.66E-04 4.70E-03 5.95E-03 2.06E-03 1.44E-03 8.47E-04 1.97E-04 4.27E-04 0 0 0 0 0 0 0000000001.95E-02DR-WL-01 Wire line Diesel Engine #1 2.17 2.17 2.17 71.61 7.40E-02 2.31E-03 37.98 16.59 1.34E-03 7,558.44 3.54E-02 4.27E-03 4.31E-02 5.45E-02 1.89E-02 1.32E-02 7.76E-03 1.81E-03 3.92E-03 0 0 0 0 0 0 0000000001.79E-01DR-WL-02 Wire line Diesel Engine #2 2.17 2.17 2.17 71.61 7.40E-02 2.31E-03 37.98 16.59 1.34E-03 7,558.44 3.54E-02 4.27E-03 4.31E-02 5.45E-02 1.89E-02 1.32E-02 7.76E-03 1.81E-03 3.92E-03 0 0 0 0 0 0 0000000001.79E-01DR-EL-01 Electric line Diesel Engine #1 2.37 2.37 2.37 78.12 8.08E-02 2.52E-03 41.43 18.10 1.46E-03 8,245.57 3.87E-02 4.66E-03 4.70E-02 5.95E-02 2.06E-02 1.44E-02 8.47E-03 1.97E-03 4.27E-03 0 0 0 0 0 0 0000000001.95E-01DR-EL-02 Electric line Diesel Engine #2 2.37 2.37 2.37 78.12 8.08E-02 2.52E-03 41.43 18.10 1.46E-03 8,245.57 3.87E-02 4.66E-03 4.70E-02 5.95E-02 2.06E-02 1.44E-02 8.47E-03 1.97E-03 4.27E-03 0 0 0 0 0 0 0000000001.95E-01DR-CU-01 Casing Unit Diesel Engine #1 1.46 1.46 1.46 32.19 3.33E-02 1.04E-03 24.38 7.46 6.02E-04 3,397.18 1.59E-02 1.92E-03 1.94E-02 2.45E-02 8.49E-03 5.92E-03 3.49E-03 8.12E-04 1.76E-03 0 0 0 0 0 0 0000000008.04E-02DR-CU-02 Casing Unit Diesel Engine #2 1.46 1.46 1.46 32.19 3.33E-02 1.04E-03 24.38 7.46 6.02E-04 3,397.18 1.59E-02 1.92E-03 1.94E-02 2.45E-02 8.49E-03 5.92E-03 3.49E-03 8.12E-04 1.76E-03 0 0 0 0 0 0 0000000008.04E-02DR-FR-01 Fast Rescue Craft 0.08 0.08 0.08 1.42 1.29E-03 4.03E-05 0.95 0.29 2.33E-05 131.70 6.17E-04 7.45E-05 7.51E-04 9.50E-04 3.29E-04 2.29E-041.35E-04 3.15E-05 6.83E-05 0 0 0 0 0 0 0000000003.12E-03DR-WB-01 Water Blasting Engine 0.82 0.82 0.82 16.41 2.80E-02 8.75E-04 14.36 6.28 5.07E-04 2,858.47 1.34E-02 1.62E-03 1.63E-02 2.06E-02 7.15E-034.98E-03 2.94E-03 6.83E-04 1.48E-03 0 0 0 0 0 0 0000000006.77E-0251.85 51.85 51.85 822.36 0.61 0.02 503.46 109.93 0.01 62084.93 2.91E-01 3.51E-02 3.54E-01 4.48E-01 1.55E-01 1.08E-01 6.38E-02 1.02E-02 3.22E-02 0 00 0 0 0 0 0 0 0 0 0 0 0 0 1.47DR-DT-01Forward Fuel Oil Drain Tank (T-21)000 0 0 0 00.080 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-02 Aft Fuel Oil Drain Tank (T-24)000 0 0 0 00.080 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-03 Diesel Fuel Overflow Tank (T-28)000 0 0 0 00.080 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-04 Starboard Main Diesel Storage Tank (T-29)000 0 0 0 00.080 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-05 Port Main Diesel Storage Tank (T-30)000 0 0 0 00.090 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-06 Starboard Engine Room Diesel Day Tank (T-31)000 0 0 0 00.090 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-07 Port Engine Room Diesel Day Tank (T-32)000 0 0 0 00.090 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-08 Starboard Engine Room Diesel Settling Tank (T-33)000 0 0 0 00.090 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DT-09 Port Engine Room Diesel Settling Tank (T-34)000 0 0 0 00.010 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-FT-01 Helicopter Fuel Tank #1000 0 0 0 00.010 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-FT-02 Helicopter Fuel Tank #2000 0 0 0 00.010 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-FT-03 Helicopter Fuel Tank #3000 0 0 0 00.020 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000 0 0 0 00.720 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-DC-01 Dust Collector #1 1.20 1.20 1.20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0DR-DC-02 Dust Collector #2 1.20 1.20 1.20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0DR-DC-03 Dust Collector #3 1.65 1.65 1.65 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 04.05 4.05 4.05 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-PO-01 Painting Operation 2.54 2.54 2.54 0 0 0 0 173.14 0 0 0 0 0 0 0 87.73 0 0 0 21.14 22.22 0.22 0 0 0 000000000131.09Drill Ship Painting Emissions 2.54 2.54 2.54 0 0 0 0 173.14 0 0 0 0 0 0 0 87.73 0 0 0 21.14 22.22 0.22 0 0 0 0 0 0 0 0 0 0 0 0 131.09DR-FE-01 Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 0.13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0DR-VG-01 Mud Degasser Vent0 0 0 0 0 0 0 53.56 0 2,713.74 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 53.56 0 2,713.74 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0298.71 196.12 192.03 9,492.99 4.46 0.14 1,049.64 534.27 0.08 457,897.30 3.38E-01 5.24E-02 2.20 6.17E-01 8.23E-0188.305.70E-01 9.56E-03 3.43E-0121.14 22.22 0.22 000000000000136.34SB-ME-01 Diesel Marine Propulsion Engine #1 29.63 24.36 23.64 1,066.74 1.01 0.03 740.79 57.82 0.02 94,060.04 0.01 4.53E-03 0.45 0.05 0.16 0.11 0.12 0 7.47E-02 0 0 0 0 0 0 0000000009.05E-01SB-ME-02 Diesel Marine Propulsion Engine #2 29.63 24.36 23.64 1,066.74 1.01 0.03 740.79 57.82 0.02 94,060.04 0.01 4.53E-03 0.45 0.05 0.16 0.11 0.12 0 7.47E-02 0 0 0 0 0 0 0000000009.05E-01SB-TE-01 Diesel Marine Forward Bow Thruster Engine #1 10.85 8.92 8.66 390.62 0.37 0.01 271.26 21.17 6.70E-03 34,376.63 5.30E-03 1.66E-03 0.160.02 0.06 0.04 0.04 0 2.73E-02 0 0 0 0 0 0 0000000003.31E-01SB-TE-02 Diesel Marine Aft Bow Thruster Engine #2 10.85 8.92 8.66 390.62 0.37 0.01 271.26 21.17 6.70E-03 34,376.63 5.30E-03 1.66E-03 0.16 0.020.06 0.04 0.04 0 2.73E-02 0 0 0 0 0 0 0000000003.31E-01SB-TE-03 Diesel Marine Stern Thruster Engine #3 10.85 8.92 8.66 390.62 0.37 0.01 271.26 21.17 6.70E-03 34,376.63 5.30E-03 1.66E-03 0.16 0.02 0.06 0.04 0.04 0 2.73E-02 0 0 0 0 0 0 0000000003.31E-01SB-GE-01 Port Electrical Generator Diesel Engine #1 10.33 8.49 8.24 371.80 0.35 0.01 258.19 20.15 6.38E-03 32,220.16 4.96E-03 1.55E-03 0.15 0.02 0.06 0.04 0.04 0 2.56E-02 0 0 0 0 0 0 0000000003.10E-01SB-GE-02 Starboard Electrical Generator Diesel Engine #2 10.33 8.49 8.24 371.80 0.35 0.01 258.19 20.15 6.38E-03 32,220.16 4.96E-03 1.55E-030.15 0.02 0.06 0.04 0.04 0 2.56E-02 0 0 0 0 0 0 0000000003.10E-01SB-GE-03 Emergency Electrical Generator Diesel Engine #3 0.08 0.08 0.08 2.99 0.00 0.00 2.08 0.16 0.00 288.16 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-GE-04 ROV Electric Generator Diesel Engine #4 1.87 1.87 1.87 59.97 1.05E-04 3.28E-06 32.80 2.36E-02 1.90E-06 6,527.75 3.06E-02 3.69E-03 3.72E-02 4.71E-02 1.63E-02 1.14E-02 6.70E-03 1.56E-03 3.38E-03 0 0 0 0 0 0 0000000001.55E-01SB-VS-01 Well evaluation engine #17.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.00 3847.931.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09SB-VS-02 Well evaluation engine #27.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.00 3847.931.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09SB-VS-03 Well evaluation engine #37.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.00 3847.931.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09SB-VS-04 Well evaluation engine #47.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.00 3847.931.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09SB-VS-05 Well evaluation engine #57.39 7.39 7.39 82.01 0.04 0.00 54.50 3.17 0.00 3847.931.80E-02 2.18E-03 2.19E-02 2.78E-02 9.62E-03 6.70E-03 3.95E-03 0 1.99E-030.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.09SB-VS-06 Well evaluation engine #619.01 19.01 19.01 267.849.69E-02 3.03E-0357.72 21.701.75E-039894.694.64E-02 5.59E-03 5.64E-02 7.14E-02 2.47E-02 1.72E-02 1.02E-02 2.36E-03 5.13E-03 0 0 0 0 0 0 0000000002.34E-01SB-VS-07 Well evaluation engine #719.01 19.01 19.01 267.849.69E-02 3.03E-0357.72 21.701.75E-039894.694.64E-02 5.59E-03 5.64E-02 7.14E-02 2.47E-02 1.72E-02 1.02E-02 2.36E-03 5.13E-03 0 0 0 0 0 0 0000000002.34E-01SB-VS-08 Well evaluation engine crane #13.27 3.27 3.27 46.131.67E-02 5.21E-049.94 3.743.02E-041704.097.99E-03 9.63E-04 9.72E-03 1.23E-02 4.26E-03 2.97E-03 1.75E-03 4.07E-04 8.83E-04 0 0 0 0 0 0 0000000004.03E-02SB-VS-09 Well evaluation engine crane #26.86 6.86 6.86 96.723.50E-02 1.09E-0320.84 7.846.33E-043573.081.68E-02 2.02E-03 2.04E-02 2.58E-02 8.93E-03 6.22E-03 3.67E-03 8.54E-04 1.85E-03 0 0 0 0 0 0 0000000008.46E-02114.43 94.42 91.68 4,111.90 3.84 0.12 2,846.64219.63 0.07 362,506.22 0.09 0.02 1.73 0.22 0.63 0.43 0.47 1.63E-03 0.29 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.58SB-DT-01 Vessel's Diesel Fuel Storage Tank #1 Port 0 0 0 0 0 0 0 0.08 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-02 Vessel's Diesel Fuel Storage Tank #1 Starboard 0 0 0 0 0 0 0 0.08 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-03 Vessel's Diesel Fuel Storage Tank #2 Port 0 0 0 0 0 0 0 0.08 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-04 Vessel's Diesel Fuel Storage Tank #2 Starboard 0 0 0 0 0 0 0 0.08 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-05 Vessel's Diesel Fuel Storage Tank #3 Port 0 0 0 0 0 0 0 0.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-06 Vessel's Diesel Fuel Storage Tank #3 Starboard 0 0 0 0 0 0 0 0.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-07 Vessel's Diesel Fuel Storage Tank #4 Port 0 0 0 0 0 0 0 0.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-08 Vessel's Diesel Fuel Storage Tank #4 Starboard 0 0 0 0 0 0 0 0.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-09 Vessel's Diesel Fuel Storage Tank #5 Port 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-10 Vessel's Diesel Fuel Storage Tank #5 Starboard 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-11 Vessel's Diesel Fuel Storage Day Tank #1 Port 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-12 Vessel's Diesel Fuel Storage Day Tank #1 Starboard 0 0 0 0 0 0 0 0.02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-13 Vessel's Diesel Fuel Stern Thruster Day Tank 0 0 0 0 0 0 0 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-14 Vessel's Diesel Fuel Overflow Port Storage Tank 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0SB-DT-15 Vessel's Diesel Fuel Overflow Stbd Storage Tank 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 0.74 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0SB-FE-01 Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 0.15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-ME-01 Diesel Marine Propulsion Engine #1 127.18 72.87 70.71 4,360.32 2.04 0.06 999.24 116.56 0.04 208,063.30 0.03 0.01 0.99 0.10 0.36 0.25 0.27 0 0.17 0 0 0 0 0 0 0000000002.00AB-ME-02 Diesel Marine Propulsion Engine #2 127.18 72.87 70.71 4,360.32 2.04 0.06 999.24 116.56 0.04 208,063.30 0.03 0.01 0.99 0.10 0.36 0.25 0.27 0 0.17 0 0 0 0 0 0 0000000002.00AB-TE-01 Bow Tunnel Thruster Engine 28.12 16.11 15.64 964.22 0.45 0.01 220.97 25.77 8.16E-03 46,010.30 7.09E-03 2.22E-03 0.22 0.02 0.08 0.05 0.060 0.04 0 0 0 0 0 0 0000000000.44AB-TE-02 Aft Tunnel Thruster Engine 28.12 16.11 15.64 964.22 0.45 0.01 220.97 25.77 8.16E-03 46,010.30 7.09E-03 2.22E-03 0.22 0.02 0.08 0.05 0.06 0 0.04 0 0 0 0 0 0 0000000000.44AB-TE-03 Bow Drop Down Thruster 28.12 16.11 15.64 964.22 0.45 0.01 220.97 25.77 8.16E-03 46,010.30 7.09E-03 2.22E-03 0.22 0.02 0.08 0.05 0.06 0 0.040 0 0 0 000000000000.44AB-GE-01 Service Generator Engine 1 12.03 6.89 6.69 412.42 0.19 6.02E-03 94.51 11.02 3.49E-03 19,679.44 3.03E-03 9.48E-04 0.09 0.01 0.03 0.02 0.03 0 0.02 0 0 0 0 0 0 0000000000.19AB-GE-02 Service Generator Engine 2 12.03 6.89 6.69 412.42 0.19 6.02E-03 94.51 11.02 3.49E-03 19,679.44 3.03E-03 9.48E-04 0.09 0.01 0.03 0.02 0.03 0 0.02 0 0 0 0 0 0 0000000000.19AB-GE-03 Service Generator Engine 3 12.03 6.89 6.69 412.42 0.19 6.02E-03 94.51 11.02 3.49E-03 19,679.44 3.03E-03 9.48E-04 0.09 0.01 0.03 0.02 0.03 0 0.02 0 0 0 0 0 0 0000000000.19AB-GE-04 Service Generator Engine 4 21.84 12.51 12.14 748.80 0.35 0.01 171.60 20.02 6.33E-03 35,730.82 5.50E-03 1.72E-03 0.17 0.02 0.06 0.04 0.050 0.03 0 0 0 0 0 0 0000000000.34AB-GE-05 Service Generator Engine 5 21.84 12.51 12.14 748.80 0.35 0.01 171.60 20.02 6.33E-03 35,730.82 5.50E-03 1.72E-03 0.17 0.02 0.06 0.04 0.050 0.03 0 0 0 0 0 0 0000000000.34AB-GE-06 Emergency Generator 0.68 0.68 0.68 9.52 3.44E-03 1.08E-04 2.051 0.771 6.23E-05 351.58 1.65E-03 1.99E-04 2.01E-03 2.54E-03 8.79E-04 6.12E-04 3.61E-04 8.40E-05 1.82E-04 0 0 0 0 0 0 0000000008.32E-03AB-GE-07 Port Winch Hydraulic Engine 21.84 12.51 12.14 748.80 0.350 0.01 171.60 20.02 6.33E-03 35,730.82 5.50E-03 1.72E-03 0.17 0.02 0.06 0.04 0.05 0 0.03 0 0 0 0 0 0 0000000000.34AB-GE-08 Starboard Winch Hydraulic Engine 21.84 12.51 12.14 748.80 0.35 0.01 171.60 20.02 6.33E-03 35,730.82 5.50E-03 1.72E-03 0.17 0.02 0.06 0.04 0.05 0 0.03 0 0 0 0 0 0 0000000000.34117.00 67.04 65.05 4,011.49 1.87 0.06 919.30 107.23 0.03 191,418.24 0.03 9.22E-03 0.91 0.09 0.33 0.23 0.25 8.40E-05 0.15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.84Emission Unit ID Emission UnitNSR Regulated Air Pollutants & Greenhouse Gas Emissions (CO2e)Hazardous Air Pollutants (HAPs)Discoverer Spirit TransoceanMain Engines Worst-Case Operating Emissions (Maximum 425 bbls/day of fuel used for allmain engines)Drill Ship Dust Collectors EmissionsDrill Ship Tanks EmissionsTOTAL - Drillship Emissions ScenarioHOS Coral Work Boat Engines or Similar Supply Boat- TOTALDrill Ship Fugitive EmissionsDrill Ship Mud Degasser Vent EmissionsSupport VesselsDrilling Misc Engines Worst-Case Operating EmissionsHOS Coral Work Boat or Similar Supply Boat Tanks EmissionsSupply Boat Fugitive EmissionsKirt Chouest Anchor Handling Boat Engines- TOTAL (Max 7500 gpd of fuel usage)Anadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit5 of 40Max Daily Emission SummaryDate Printed - 6/26/2013AB-DT-01 Port Side Double Bottom Diesel Fuel Tank #1000 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-02Starboard Side Double Bottom Diesel Fuel Tank #1 0 0 0 0 0 0 00.040 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-03Center Double Bottom Diesel Fuel Tank #1 0 0 0 0 0 0 00.040 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-04Port Side Double Bottom Diesel Fuel Tank #2 0 0 0 0 0 0 00.070 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-05Starboard Side Double Bottom Diesel Fuel Tank #2 0 0 0 0 0 0 00.070 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-06Port Wing Diesel Fuel Tank #1 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-07Starboard Wing Diesel Fuel Tank #1 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-08Port Side Double Bottom Diesel Fuel Tank #3 0 0 0 0 0 0 00.060 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-09Starboard Side Double Bottom Diesel Fuel Tank #3 0 0 0 0 0 0 00.060 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-10Port Wing Diesel Fuel Tank #2 0 0 0 0 0 0 00.100 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-11Starboard Side Double Bottom Diesel Fuel Tank #4 0 0 0 0 0 0 00.110 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-12Starboard Wing Diesel Fuel Tank #2 0 0 0 0 0 0 00.090 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-13Port Side Double Bottom Diesel Fuel Tank #4 0 0 0 0 0 0 00.070 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-14Starboard Side Double Bottom Diesel Fuel Tank #5 0 0 0 0 0 0 00.060 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-15Port Service Diesel Tank 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-16Starboard Service Diesel Tank 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-17Port Diesel Settling Tank 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-18Starboard Diesel Settling Tank 0 0 0 0 0 0 00.030 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-DT-19Diesel Overflow Tank 0 0 0 0 0 0 00.010 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000 0 0 0 01.000 0 0 00 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0AB-FE-01Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.23 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 0.23 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0114.65 94.26 91.46 4188.64 3.91 0.12 2899.76 224.63 0.07 369247.10 8.67E-02 2.10E-02 1.73 2.21E-01 6.28E-01 4.31E-01 4.68E-01 1.63E-03 2.86E-01 0 00 0 000000000003.58117.00 67.04 65.05 4011.49 1.87 5.86E-02 919.30 108.47 3.39E-02 191,418.24 2.95E-02 9.22E-03 0.91 0.09 0.33 0.23 0.25 8.40E-05 0.15 0 0 0 0000000000001.84117.00 94.26 91.46 4188.64 3.91 1.22E-01 2899.76 224.63 7.08E-02 369,247.10 8.67E-02 2.10E-02 1.73 0.22 0.63 0.43 0.47 1.63E-03 0.29 0 0 0 0000000000003.58SV-ME-01Stimulation Vessel Main Engine #1 17.92 10.27 9.97 311.870.247.64E-03 179.24 13.99 4.43E-03 24,970.34 3.85E-03 1.20E-030.12 0.01 0.04 0.03 0.0300.020 0 0 0 000000000002.40E-01SV-ME-02Stimulation Vessel Main Engine #2 17.92 10.27 9.97 311.870.247.64E-03 179.24 13.99 4.43E-03 24,970.34 3.85E-03 1.20E-030.12 0.01 0.04 0.03 0.0300.020 0 0 0 000000000002.40E-01SV-BT-01Stimulation Vessel Bow Thruster 7.04 4.03 3.91 241.200.113.52E-03 55.28 6.45 2.04E-03 11,509.45 1.77E-03 5.54E-040.055.55E-030.02 0.01 0.010 9.15E-03 0 0 0 0 0 0 0000000001.11E-01SV-DD-01Stimulation Vessel Bow Drop-Down 5.04 2.89 2.80 172.800.082.52E-03 39.60 4.62 1.46E-03 8,245.57 1.27E-03 3.97E-040.043.98E-030.019.73E-030.010 6.55E-03 0 0 0 0 0 0 0000000007.93E-02SV-ST-01Stimulation Vessel Stern Thruster 7.04 4.03 3.91 241.200.113.52E-03 55.28 6.45 2.04E-03 11,509.45 1.77E-03 5.54E-040.055.55E-030.02 0.01 0.010 9.15E-03 0 0 0 0 0 0 0000000001.11E-01SV-PE-01 thru SV-PE-08Stimulation Vessel Representative Pumps 126.00 72.20 70.06 4,320.00 2.02 0.06 990.00 115.48 3.65E-02 206,139.33 3.18E-02 9.93E-03 0.98 0.10 0.35 0.24 0.27 0 0.16 0 0 0 0 0 0 0000000001.98SV-GE-01 and SV-GE-02Stimulation Vessel Generators Chouest 19.26 11.04 10.71 616.31 0.66 0.02 337.04 37.579 1.19E-02 67,081.04 1.03E-02 3.23E-03 0.32 0.03 0.12 0.08 0.09 0 0.05 0 0 0 0 0 0 0000000006.45E-01SV-GE-03 and SV-GE-04Stimulation Vessel Generators Baker Hughes 12.70 7.276 7.060 406.36 0.43 0.01 222.23 24.78 7.84E-03 44,229.26 6.81E-03 2.13E-03 0.21 0.02 0.080.05 0.06 0 0.04 0 0 0 0 0 0 0000000004.26E-01212.92 122.00 118.38 6,621.61 3.90 0.12 2,057.90 223.33 0.07 398,654.78 6.14E-02 1.92E-02 1.89 1.92E-01 6.85E-01 4.70E-01 5.17E-01 0 3.17E-01 0 0 0 00 0 0 0 0 0 0 0 0 0 0 3.84DR-WC-01 Tubing Running Unit Engine1.44 1.44 1.44 26.98 2.48E-02 7.74E-04 17.99 5.545 4.48E-04 2,528.64 1.19E-02 1.43E-03 1.44E-02 1.82E-02 6.32E-03 4.40E-03 2.60E-03 6.04E-04 1.31E-030 0 0 0 000000000005.99E-02DR-WC-02 Fluid Filtration Pump1.19 1.19 1.19 26.16 2.70E-02 8.44E-04 19.82 6.05 4.89E-04 2,759.52 1.29E-02 1.56E-03 1.57E-02 1.99E-02 6.90E-03 4.81E-03 2.83E-03 6.60E-04 1.43E-030 0 0 0 000000000006.53E-02DR-WC-03 Eline Power Pack1.78 1.78 1.78 58.67 6.06E-02 1.89E-03 31.11 13.576 1.10E-03 6,184.18 2.90E-02 3.50E-03 3.53E-02 4.46E-02 1.55E-02 1.08E-02 6.35E-03 1.48E-03 3.21E-030 0 0 0 000000000001.46E-01DR-WC-04 Slickline Power Pack0.99 0.99 0.99 32.83 3.39E-02 1.06E-03 17.41 7.61 6.14E-04 3,464.630.021.96E-030.02 0.028.66E-03 6.04E-03 3.56E-03 8.28E-04 1.80E-030 0 0 0 000000000008.20E-02DR-WC-05 Flowback Boiler4.40 4.40 4.40 32.03 2.84E-01 0 6.674 2.67E-01 1.68E-03 30,571.44 0 0 0 0 0 0 0 0 0 0 000 00000000004.40E-03 4.40E-03DR-WC-06 Boom Flare446.88 446.88 446.88 4,078.37 35.28 0 22,191.12 8,396.64 0 7,017,407.47 0 00.124.410.2000 00.040 000.07 105.84 0.01 7.06E-04 0.06 0.08 4.94E-03 0.02 0.02 0.12 1.41E-03 5.19E-03 1.11E+02DR-WC-07 CT Power Pack4.73 4.73 4.73 151.51 1.62E-01 5.05E-03 82.859 36.166 2.92E-03 16,491.150.089.32E-030.09 0.12 0.04 0.03 0.023.94E-03 8.55E-03 0 000 000000000003.90E-01DR-WC-08 CT Pump6.79 3.89 3.77 217.17 2.31E-01 7.23E-03 118.76 13.24 4.19E-03 23,637.31 3.64E-03 1.14E-030.11 0.01 0.04 0.03 0.0300.020 000 000000000002.27E-01DR-WC-09 Wire line Diesel Engine #3 2.17 2.17 2.17 71.61 7.40E-02 2.31E-03 37.98 16.59 1.34E-03 7,558.44 3.54E-02 4.27E-03 4.31E-02 5.45E-02 1.89E-02 1.32E-02 7.76E-03 1.81E-03 3.92E-03 0 0 0 0 0 0 0000000001.79E-01DR-WC-10 Wire line Diesel Engine #4 2.17 2.17 2.17 71.61 7.40E-02 2.31E-03 37.98 16.59 1.34E-03 7,558.44 3.54E-02 4.27E-03 4.31E-02 5.45E-02 1.89E-02 1.32E-02 7.76E-03 1.81E-03 3.92E-03 0 0 0 0 0 0 0000000001.79E-01468.21 465.31 465.70 4,623.72 36.10 0.02 22,485.74 8,479.09 0.01 7,103,044.34 0.15 0.02 0.41 4.73 0.32 0.08 0.06 0.01 0.07 0 0 0 0.07 105.84 0.01 7.06E-04 0.06 0.08 0.00 0.02 0.02 0.12 1.41E-03 9.59E-03 111.55TB-ME-01 Main Engine #136.96 21.18 20.55 681.39 0.59 1.85E-02 290.40 33.87 1.07E-02 60,467.54 9.31E-03 2.91E-030.29 0.03 0.10 0.07 0.0800.050 0 0 0 000000000005.82E-01TB-ME-02 Main Engine# 236.96 21.18 20.55 681.39 0.59 1.85E-02 290.40 33.87 1.07E-02 60,467.54 9.31E-03 2.91E-030.29 0.03 0.10 0.07 0.0800.050 0 0 0 000000000005.82E-01TB-ME-03 Main Engine #336.96 21.18 20.55 681.39 0.59 1.85E-02 290.40 33.87 1.07E-02 60,467.54 9.31E-03 2.91E-030.29 0.03 0.10 0.07 0.0800.050 0 0 0 000000000005.82E-01TB-GE-01 Generator Engine #19.20 9.20 9.20 129.70 4.69E-02 1.47E-03 27.95 10.51 8.49E-04 4,791.500.022.71E-030.03 0.03 0.018.35E-03 4.92E-03 1.15E-03 2.48E-03 0 0 0 0 0 0 0000000001.13E-01TB-GE-02 Generator Engine #29.20 9.20 9.20 129.70 4.69E-02 1.47E-03 27.95 10.51 8.49E-04 4,791.500.022.71E-030.03 0.03 0.01 0.014.92E-03 1.15E-03 2.48E-03 0 0 0 0 0 0 0000000001.13E-01295.68 169.42 164.40 5,451.13 4.74 0.15 2,323.20 270.99 0.09 483,740.30 0.07 0.02 2.29 0.23 0.83 0.57 0.63 0.01 0.38 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.65BG-LP-01Barge Loading Pump Engine #128.51 28.51 28.51 401.76 1.45E-01 4.54E-03 86.57 32.55 2.63E-03 14842.036.96E-02 8.39E-03 8.46E-02 1.07E-01 3.71E-02 2.59E-02 1.52E-023.55E-03 7.69E-03 0 0 0 0 0 0 0000000003.51E-0128.51 28.51 28.51 401.76 1.45E-01 4.54E-03 86.57 32.55 2.63E-03 14,842.03 6.96E-02 8.39E-03 8.46E-02 1.07E-01 3.71E-02 2.59E-02 1.52E-02 3.55E-03 7.69E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.51E-01WC-CT-01 Well Completion Condensate Tank #10 0 0 0 0 0 0 22.20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0WC-CT-02 Well Completion Condensate Tank #20 0 0 0 0 0 0 22.20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 0WC-CT-03 Well Completion Condensate Tank #30 0 0 0 0 0 0 22.20 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000 00 0 0 0 0 0 0 66.60 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0643.29 575.81 572.43 10,711.56 39.23 0.11 23,553.23 8,894.14 0.08 7,414,971.79 8.65E-02 1.99E-02 1.69 4.70E+00 7.70E-01 88.11 4.23E-01 1.89E-03 2.95E-01 21.14 22.22 0.22 0 1060000000000244.78749.93 575.39 568.44 12,717.70 30.54 0.21 17,487.73 6,296.86 0.13 5,399,019.93 1.82E-01 4.02E-02 3.10 3.45E+00 1.24E+00 88.49 8.16E-01 1.36E-02 5.22E-01 21.14 22.22 0.22 0 710000000000211.17392.28 230.15 223.70 12,714.65 6.65 0.21 2,480.21 669.87 0.13 681,427.61 1.02E-01 2.80E-02 2.54 2.87E-01 9.20E-01 88.36 6.91E-01 1.06E-03 4.23E-01 21.14 22.22 0.22 000000000000136.29362.15 247.12 241.06 12,646.20 8.08 0.25 3,775.40 753.26 0.15 798,062.45 3.48E-01 5.71E-02 2.75 6.61E-01 1.02E+00 88.41 7.20E-01 1.37E-02 4.35E-01 21.14 22.22 0.22 000000000000137.05749.93 575.81 572.43 12,717.70 39.23 0.25 23,553.23 8,894.14 0.15 7,414,971.79 3.48E-01 5.71E-02 3.10 4.70 1.24 88.49 8.16E-01 1.37E-02 5.22E-01 21.14 22.22 0.22 7.06E-02 105.84 1.18E-02 7.06E-04 6.47E-02 2.09E-01 4.99E-03 1.32E-01 1.53E-02 1.33E-01 1.41E-03 9.59E-03 244.78415.72 290.37 283.49 13,681.63 8.37 0.26 3,949.40 758.90 0.15 827,144.40 0.42 0.07 3.93 0.84 1.45 88.73 1.04 0.01 0.63 21.14 22.22 0.22 000000000000139.92749.93 575.81 572.43 12,717.70 39.23 0.25 23,553.23 8,894.14 0.15 7,414,971.79 0.35 0.06 3.10 4.70 1.24 88.49 0.82 0.01 0.52 21.14 22.22 0.22 7.06E-02 105.84 1.18E-02 7.06E-04 6.47E-02 2.09E-01 4.99E-03 1.32E-01 1.53E-02 0.13 1.41E-03 9.59E-03 244.7817.32 12.10 11.81 570.07 0.35 0.01 164.56 31.62 0.01 34,464.35 1.77E-02 3.06E-03 1.64E-01 3.49E-02 6.05E-02 3.70 4.33E-02 4.66E-04 2.62E-02 8.81E-01 9.26E-01 9.09E-03 0000000000005.8331.25 23.99 23.85 529.90 1.63 0.01 981.38 370.59 0.01 308,957.16 1.45E-02 2.38E-03 1.29E-01 1.96E-01 5.15E-02 3.69 3.40E-02 5.73E-04 2.17E-02 8.81E-01 9.26E-01 9.09E-03 2.94E-03 4.41 4.90E-04 2.94E-05 2.70E-03 8.70E-03 2.08E-04 5.51E-03 6.37E-04 5.55E-03 5.88E-05 4.00E-04 10.204.34TOTAL - Supply Boats Scenario (HOS Coral or Similar)(based on 415 bbls)TOTAL (Drillship + Support Vessel ) Worst-Case Modeling Scenario,lb/hrKirt Chouest Anchor Handling Boat Tanks EmissionsAnchor Handling Boat Fugitive EmissionsTOTAL - Anchor Handling Boat Scenario (Kirt Chouest or Similar)TOTAL - Worst-Case Support Vessels ScenarioDiscoverer Spirit Well CompletionStimulation Vessel Operation - TOTALWell Completion Misc Operation - TOTALRepresentative Tug Operation - TOTAL (Max 340 bbls per day of fuel usage)Representative Barge Operation - TOTALWell Completion Condensate Tanks - TOTALTOTAL (Well Completion + Support Vessel ) Worst-Case ModelingScenario, lb/hrTOTAL (Drillship + Support Vessel ) Worst-Case Operating ScenarioTOTAL - Worst-Case Well Completion ScenarioTOTAL (Well Completion + Support Vessel ) Worst-Case OperatingScenarioTOTAL - Worst-Case Gas Well Flowback ScenarioTOTAL - Worst-Case Oil Well Flowback ScenarioTOTAL - Stimulation Vessel Operation ScenarioTOTAL - Third Party Equipment Operation ScenarioAnadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit6 of 40Max Daily Emission SummaryDate Printed - 6/26/2013Anadarko Petroleum CorporationEmissions Summary - Discoverer Spirit Drillship, Support Vessels & Well CompletionTable 3 - Maximum Hourly Emissions Summary (lb/hr)PMPM10PM2.5NOxSO2H2SO4CO VOC PbCO2eAcetaldehyde Acrolein Benzene Formaldehyde Toluene Xylenes Total PAH 1,3-Butadiene Naphthalene Ethylbenzene ButanoneHexamethylene-di-isocyanateDichlorobenzene Hexane Arsenic Beryllium Cadmium Chromium Cobalt Manganese Mercury Nickel Selenium POM Total VOC HAPslb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hr lb/hrDR-GE-01 Main Propulsion Electrical Generator Engine #1A 5.66 3.24 3.14 204.11 0.09 2.83E-03 12.86 4.63 1.64E-03 9,253.73 1.43E-03 4.46E-04 4.39E-02 4.46E-03 1.59E-02 1.09E-02 1.20E-02 0 7.35E-03 0 0 0 0000000000008.90E-02DR-GE-02 Main Propulsion Electrical Generator Engine #1B 5.66 3.24 3.14 204.11 0.09 2.83E-03 12.86 4.63 1.64E-03 9,253.73 1.43E-03 4.46E-04 4.39E-02 4.46E-03 1.59E-02 1.09E-02 1.20E-02 0 7.35E-03 0 0 0 0000000000008.90E-02DR-GE-03 Main Propulsion Electrical Generator Engine #1C 5.66 3.24 3.14 204.11 0.09 2.83E-03 12.86 4.63 1.64E-03 9,253.73 1.43E-03 4.46E-04 4.39E-02 4.46E-03 1.59E-02 1.09E-02 1.20E-02 0 7.35E-03 0 0 0 0000000000008.90E-02DR-GE-04 Main Propulsion Electrical Generator Engine #1D 5.66 3.24 3.14 204.11 0.09 2.83E-03 12.86 4.63 1.64E-03 9,253.73 1.43E-03 4.46E-04 4.39E-02 4.46E-03 1.59E-02 1.09E-02 1.20E-02 0 7.35E-03 0 0 0 0000000000008.90E-02DR-GE-05 Main Propulsion Electrical Generator Engine #2A 3.77 2.16 2.10 136.07 0.06 1.89E-03 8.57 3.09 1.09E-03 6,169.16 9.50E-04 2.97E-04 2.93E-02 2.98E-03 1.06E-02 7.28E-03 7.99E-03 0 4.90E-03 0 0 0 0000000000005.94E-02DR-GE-06 Main Propulsion Electrical Generator Engine #2B 3.77 2.16 2.10 136.07 0.06 1.89E-03 8.57 3.09 1.09E-03 6,169.16 9.50E-04 2.97E-04 2.93E-02 2.98E-03 1.06E-02 7.28E-03 7.99E-03 0 4.90E-03 0 0 0 0000000000005.94E-0210.01 5.74 5.57 361.28 1.60E-01 5.01E-03 22.76 8.20 2.90E-03 16,379.11 2.52E-03 7.89E-04 7.77E-02 7.90E-03 2.81E-02 1.93E-02 2.12E-02 0 1.30E-02 00 0 0 000000000000.16DR-WO-01 Welding Emissions on Drillship 0.08 0.08 0.08 0.00 0.00 0.00E+00 0.00 0.00 3.38E-04 0.00 0 0 0 0 0 0 0 0 0 0 0 0 000005.27E-03 2.08E-06 4.58E-03 0 4.08E-04 0 0 0.00E+00DR-VS-01 Well evaluation engine #10.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03DR-VS-02 Well evaluation engine #20.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03DR-VS-03 Well evaluation engine #30.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03DR-VS-04 Well evaluation engine #40.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03DR-VS-05 Well evaluation engine #5 0.31 0.31 0.31 3.42 1.57E-03 4.91E-05 2.27 0.13 2.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-042.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03DR-GE-07 Emergency Generator 1.80 1.03 1.00 57.50 2.88E-02 8.99E-04 15.27 1.47 5.21E-04 2,939.99 4.53E-04 1.42E-04 1.39E-02 1.42E-03 5.05E-03 3.47E-03 3.81E-03 0 2.34E-03 0 0 0 0000000000002.83E-02DR-GE-08 ROV Emergency Generator 0.14 0.14 0.14 4.47 4.77E-03 1.49E-04 2.45 1.07 8.63E-05 486.72 2.28E-03 2.75E-04 2.78E-03 3.51E-03 1.22E-03 8.48E-04 5.00E-04 1.16E-04 2.52E-04 0 0 0 0000000000001.15E-02DR-AC-01 Air Compressor Diesel Engine #1 0.02 0.02 0.02 0.28 1.01E-04 3.15E-06 0.06 0.02 1.83E-06 10.31 4.83E-05 5.83E-06 5.88E-05 7.43E-05 2.58E-05 1.80E-05 1.06E-05 2.46E-06 5.34E-06 0 0 0 0000000000002.44E-04DR-AC-02 Air Compressor Diesel Engine #2 0.02 0.02 0.02 0.23 8.41E-05 2.63E-06 0.05 0.02 1.52E-06 8.59 4.03E-05 4.86E-06 4.90E-05 6.20E-05 2.15E-05 1.50E-05 8.82E-06 2.05E-06 4.45E-06 0 0 0 0000000000002.03E-04DR-EC-01 Escape Capsule Diesel Engine #1 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0000000000005.29E-04DR-EC-02 Escape Capsule Diesel Engine #2 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0000000000005.29E-04DR-EC-03 Escape Capsule Diesel Engine #3 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0000000000005.29E-04DR-EC-04 Escape Capsule Diesel Engine #4 0.04 0.04 0.04 0.60 2.19E-04 6.83E-06 0.13 0.05 3.96E-06 22.33 1.05E-04 1.26E-05 1.27E-04 1.61E-04 5.58E-05 3.89E-05 2.29E-05 5.34E-06 1.16E-05 0 0 0 0000000000005.29E-04DR-EC-05 Escape Capsule Diesel Engine #5 0.03 0.03 0.03 0.45 1.63E-04 5.08E-06 0.10 0.04 2.94E-06 16.61 7.79E-05 9.39E-06 9.47E-05 1.20E-04 4.15E-05 2.89E-05 1.71E-05 3.97E-06 8.61E-06 0 0 0 0000000000003.93E-04DR-EC-06 Escape Capsule Diesel Engine #6 0.03 0.03 0.03 0.45 1.63E-04 5.08E-06 0.10 0.04 2.94E-06 16.61 7.79E-05 9.39E-06 9.47E-05 1.20E-04 4.15E-05 2.89E-05 1.71E-05 3.97E-06 8.61E-06 0 0 0 0000000000003.93E-04DR-FL-01 Diesel Powered Forklift Engine 0.07 0.07 0.07 0.93 3.36E-04 1.05E-05 0.20 0.08 6.09E-06 34.36 1.61E-04 1.94E-05 1.96E-04 2.48E-04 8.59E-05 5.99E-05 3.53E-05 8.21E-06 1.78E-05 0 0 0 0000000000008.13E-04DR-WL-01 Wire line Diesel Engine #1 0.09 0.09 0.09 2.98 3.08E-03 9.64E-05 1.58 0.69 5.58E-05 318.61 1.48E-03 1.78E-04 1.80E-03 2.27E-03 7.87E-04 5.49E-04 3.23E-04 7.53E-05 1.63E-04 0 0 0 0000000000007.46E-03DR-WL-02 Wire line Diesel Engine #2 0.09 0.09 0.09 2.98 3.08E-03 9.64E-05 1.58 0.69 5.58E-05 318.61 1.48E-03 1.78E-04 1.80E-03 2.27E-03 7.87E-04 5.49E-04 3.23E-04 7.53E-05 1.63E-04 0 0 0 0000000000007.46E-03DR-EL-01 Electric line Diesel Engine #1 0.10 0.10 0.10 3.26 3.36E-03 1.05E-04 1.73 0.75 6.09E-05 343.57 1.61E-03 1.94E-04 1.96E-03 2.48E-03 8.59E-04 5.99E-04 3.53E-04 8.21E-05 1.78E-04 0 0 0 0000000000008.13E-03DR-EL-02 Electric line Diesel Engine #2 0.10 0.10 0.10 3.26 3.36E-03 1.05E-04 1.73 0.75 6.09E-05 343.57 1.61E-03 1.94E-04 1.96E-03 2.48E-03 8.59E-04 5.99E-04 3.53E-04 8.21E-05 1.78E-04 0 0 0 0000000000008.13E-03DR-CU-01 Casing Unit Diesel Engine #1 0.06 0.06 0.06 1.34 1.39E-03 4.33E-05 1.02 0.31 2.51E-05 141.55 6.64E-04 8.00E-05 8.07E-04 1.02E-03 3.54E-04 2.47E-04 1.45E-04 3.38E-05 7.34E-05 0 0 0 0000000000003.35E-03DR-CU-02 Casing Unit Diesel Engine #2 0.06 0.06 0.06 1.34 1.39E-03 4.33E-05 1.02 0.31 2.51E-05 141.55 6.64E-04 8.00E-05 8.07E-04 1.02E-03 3.54E-04 2.47E-04 1.45E-04 3.38E-05 7.34E-05 0 0 0 0000000000003.35E-03DR-FR-01 Fast Rescue Craft 0.08 0.08 0.08 1.42 1.29E-03 4.03E-05 0.95 0.29 2.33E-05 131.70 6.17E-04 7.45E-05 7.51E-04 9.50E-04 3.29E-04 2.29E-041.35E-04 3.15E-05 6.83E-05 0 0 0 0000000000003.12E-03DR-WB-01 Water Blasting Engine 0.07 0.07 0.07 1.37 2.33E-03 7.29E-05 1.20 0.52 4.22E-05 238.21 1.12E-03 1.35E-04 1.36E-03 1.72E-03 5.96E-04 4.15E-04 2.45E-04 5.69E-05 1.23E-04 0 0 0 0000000000005.64E-034.54 3.77 3.74 101.77 6.24E-02 1.95E-03 40.89 7.91 1.47E-03 6,381.51 1.66E-02 2.08E-03 3.35E-02 2.62E-02 1.36E-02 9.45E-03 7.34E-03 8.21E-04 4.12E-03 0 0 0 0000000000000.11DR-DT-01Forward Fuel Oil Drain Tank(T-210 0 0 0 0 0 0 0.06 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-02 Aft Fuel Oil Drain Tank (T-24) 0 0 0 0 0 0 0 0.19 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-03 Diesel Fuel Overflow Tank (T-28) 0 0 0 0 0 0 0 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-04 Starboard Main Diesel Storage Tank (T-29) 0 0 0 0 0 0 0 0.32 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-05 Port Main Diesel Storage Tank (T-30) 0 0 0 0 0 0 0 0.32 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-06 Starboard Engine Room Diesel Day Tank (T-31) 0 0 0 0 0 0 0 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-07 Port Engine Room Diesel Day Tank (T-32) 0 0 0 0 0 0 0 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-08 Starboard Engine Room Diesel Settling Tank (T-33) 0 0 0 0 0 0 0 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DT-09 Port Engine Room Diesel Settling Tank (T-34) 0 0 0 0 0 0 0 0.30 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-FT-01 Helicopter Fuel Tank #1 0 0 0 0 0 0 0 4.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-FT-02 Helicopter Fuel Tank #2 0 0 0 0 0 0 0 4.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-FT-03 Helicopter Fuel Tank #3 0 0 0 0 0 0 0 4.09 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 14.65 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DC-01 Dust Collector #1 0.05 0.05 0.05 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DC-02 Dust Collector #2 0.05 0.05 0.05 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-DC-03 Dust Collector #3 0.07 0.07 0.07 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00.17 0.17 0.17 0.00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-PO-01 Painting Operation 0.21 0.21 0.21 0 0 0 0 14.43 0 0 0 0 0 0 0 7.31 0 0 0 1.76 1.85 0.02 00000000000010.92Drill Ship Painting Emissions 0.21 0.21 0.21 0.00 0.00 0.00 0.00 14.43 0.00 0.00 0.00 0.00 0.00 0.00 0.00 7.31 0.00 0.00 0.00 1.76 1.85 0.02 00000000000010.92DR-FE-01 Fugitive Emissions From Diesel Fuel Lines 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0DR-VG-01 Mud Degasser Vent 0 0 0 0 0 0 0 2.23 0 113 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 2.23 0 113 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 014.93 9.89 9.69 463.04 0.22 6.96E-03 63.65 47.43 4.37E-03 22,873.70 1.91E-02 2.87E-03 1.11E-01 3.41E-02 4.18E-02 7.34 2.86E-02 8.21E-04 1.71E-02 1.76 1.85 0.02 00000000000011.19Emission Unit ID Emission UnitDrill Ship Tanks EmissionsTOTAL - Drillship Emissions ScenarioDrill Ship Fugitive EmissionsDrill Ship Mud Degasser Vent EmissionsDrill Ship Dust Collectors EmissionsNSR Regulated Air Pollutants & Greenhouse Gas Emissions (CO2e)Hazardous Air Pollutants (HAPs)Discoverer Spirit TransoceanMain Engines Worst-Case Operating Emissions (Maximum 425 bbls/day of fuel used for all mainengines)Drilling Misc Engines Worst-Case Operating EmissionsAnadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit7 of 40Max Hourly Emission SummaryDate Printed - 6/26/2013SB-ME-01 Diesel Marine Propulsion Engine #1 0.99 0.81 0.79 35.56 0.03 1.05E-03 24.69 1.93 6.10E-04 3135.33 4.83E-04 1.51E-04 0.01 1.51E-03 5.39E-03 3.70E-03 4.06E-03 0 2.49E-03 0 0 0 0000000000003.02E-02SB-ME-02 Diesel Marine Propulsion Engine #2 0.99 0.81 0.79 35.56 0.03 1.05E-03 24.69 1.93 6.10E-04 3135.33 4.83E-04 1.51E-04 0.01 1.51E-03 5.39E-03 3.70E-03 4.06E-03 0 2.49E-03 0 0 0 0000000000003.02E-02SB-TE-01 Diesel Marine Forward Bow Thruster Engine #1 0.36 0.30 0.29 13.02 0.01 3.85E-04 9.04 0.71 2.23E-04 1145.89 1.77E-04 5.53E-05 5.44E-03 5.53E-04 1.97E-03 1.35E-03 1.49E-03 0 9.12E-04 0 0 0 0000000000001.10E-02SB-TE-02 Diesel Marine Aft Bow Thruster Engine #2 0.36 0.30 0.29 13.02 0.01 3.85E-04 9.04 0.71 2.23E-04 1145.89 1.77E-04 5.52E-05 5.44E-03 5.53E-04 1.97E-03 1.35E-03 1.48E-03 0 9.11E-04 0 0 0 0000000000001.10E-02SB-TE-03 Diesel Marine Stern Thruster Engine #3 0.36 0.30 0.29 13.02 0.01 3.85E-04 9.04 0.71 2.23E-04 1145.89 1.77E-04 5.52E-05 5.44E-03 5.53E-04 1.97E-03 1.35E-03 1.48E-03 0 9.11E-04 0 0 0 0000000000001.10E-02SB-GE-01 Port Electrical Generator Diesel Engine #1 0.34 0.28 0.27 12.39 0.01 3.67E-04 8.61 0.67 2.13E-04 1074.01 1.65E-04 5.17E-05 5.09E-035.18E-04 1.84E-03 1.27E-03 1.39E-03 0 8.53E-04 0 0 0 0000000000001.03E-02SB-GE-02 Starboard Electrical Generator Diesel Engine #2 0.34 0.28 0.27 12.39 0.01 3.67E-04 8.61 0.67 2.13E-04 1074.01 1.65E-04 5.17E-05 5.09E-03 5.18E-04 1.84E-03 1.27E-03 1.39E-03 0 8.53E-04 0 0 0 0000000000001.03E-02SB-GE-03 Emergency Electrical Generator Diesel Engine #3 0 0 0 3 0 0 2 0 0 288 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-GE-04 ROV Electric Generator Diesel Engine #4 0.16 0.16 0.16 5.00 8.76E-06 2.74E-07 2.73 0.00 1.59E-07 543.98 2.55E-03 3.08E-04 3.10E-03 3.92E-03 1.36E-03 9.48E-04 5.59E-04 1.30E-04 2.82E-04 0 0 0 0000000000001.29E-02SB-VS-01 Well evaluation engine #10.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03SB-VS-02 Well evaluation engine #20.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03SB-VS-03 Well evaluation engine #30.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03SB-VS-04 Well evaluation engine #40.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03SB-VS-05 Well evaluation engine #50.31 0.31 0.31 3.421.57E-03 4.91E-052.270.132.84E-05 160.33 7.52E-04 9.07E-05 9.14E-04 1.16E-03 4.01E-04 2.79E-04 1.65E-04 3.83E-05 8.31E-05 0 0 0 0000000000003.80E-03SB-VS-06 Well evaluation engine #60.790.790.7911.164.04E-03 1.26E-042.400.907.31E-05412.281.93E-03 2.33E-04 2.35E-03 2.97E-03 1.03E-03 7.18E-04 4.23E-04 9.85E-05 2.14E-04 0 0 0 0000000000009.76E-03SB-VS-07 Well evaluation engine #70.790.790.7911.164.04E-03 1.26E-042.400.907.31E-05412.281.93E-03 2.33E-04 2.35E-03 2.97E-03 1.03E-03 7.18E-04 4.23E-04 9.85E-05 2.14E-04 0 0 0 0000000000009.76E-03SB-VS-08 Well evaluation engine crane #10.140.140.141.926.95E-04 2.17E-050.41 0.161.26E-0571.003.33E-04 4.01E-05 4.05E-04 5.12E-04 1.78E-04 1.24E-04 7.29E-05 1.70E-05 3.68E-05 0 0 0 0000000000001.68E-03SB-VS-09 Well evaluation engine crane #2 0.29 0.29 0.29 4.03 1.46E-03 4.55E-05 0.87 0.33 2.64E-05 148.88 6.98E-04 8.42E-05 8.49E-04 1.07E-03 3.72E-04 2.59E-04 1.53E-04 3.56E-05 7.72E-05 0 0 0 0000000000003.52E-033.99 3.32 3.23 142.96 0.13 4.08E-03 98.54 7.48 2.37E-03 12,688.49 5.73E-03 1.04E-03 6.10E-02 1.17E-02 2.24E-02 1.54E-02 1.62E-02 1.99E-04 9.85E-030 0 0 0 000000000001.34E-01SB-DT-01 Vessel's Diesel Fuel Storage Tank #1 Port 0 0 0 0 0 0 0 3.32E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-02 Vessel's Diesel Fuel Storage Tank #1 Starboard 0 0 0 0 0 0 0 3.32E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-03 Vessel's Diesel Fuel Storage Tank #2 Port 0 0 0 0 0 0 0 3.38E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-04 Vessel's Diesel Fuel Storage Tank #2 Starboard 0 0 0 0 0 0 0 3.38E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-05 Vessel's Diesel Fuel Storage Tank #3 Port 0 0 0 0 0 0 0 3.57E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-06 Vessel's Diesel Fuel Storage Tank #3 Starboard 0 0 0 0 0 0 0 3.57E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-07 Vessel's Diesel Fuel Storage Tank #4 Port 0 0 0 0 0 0 0 3.57E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-08 Vessel's Diesel Fuel Storage Tank #4 Starboard 0 0 0 0 0 0 0 3.57E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-09 Vessel's Diesel Fuel Storage Tank #5 Port 0 0 0 0 0 0 0 5.63E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-10 Vessel's Diesel Fuel Storage Tank #5 Starboard 0 0 0 0 0 0 0 6.14E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-11 Vessel's Diesel Fuel Storage Day Tank #1 Port 0 0 0 0 0 0 0 4.85E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-12 Vessel's Diesel Fuel Storage Day Tank #1 Starboard 0 0 0 0 0 0 0 7.53E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-13 Vessel's Diesel Fuel Stern Thruster Day Tank 0 0 0 0 0 0 0 1.18E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-14 Vessel's Diesel Fuel Overflow Port Storage Tank 0 0 0 0 0 0 0 3.44E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-DT-15 Vessel's Diesel Fuel Overflow Stbd Storage Tank 0 0 0 0 0 0 0 3.44E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 3.09E-02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0SB-FE-01 Fugitive Emissions From Diesel Fuel Lines 0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-ME-01 Diesel Marine Propulsion Engine #1 5.30 3.04 2.95 181.68 8.49E-02 2.65E-03 41.64 4.86 1.54E-03 8,669.30 1.34E-03 4.18E-04 0.04 4.18E-03 0.01 0.01 0.01 0 6.89E-03 0 0 0 0000000000008.34E-02AB-ME-02 Diesel Marine Propulsion Engine #2 5.30 3.04 2.95 181.68 8.49E-02 2.65E-03 41.64 4.86 1.54E-03 8,669.30 1.34E-03 4.18E-04 4.11E-02 4.18E-03 0.01 0.01 0.01 0 6.89E-03 0 0 0 0000000000008.34E-02AB-TE-01 Bow Tunnel Thruster Engine 1.17 0.67 0.65 40.18 1.88E-02 5.87E-04 9.21 1.07 3.40E-04 1,917.10 2.95E-04 9.23E-05 9.09E-03 9.25E-04 3.29E-03 2.26E-03 2.48E-03 0 1.52E-03 0 0 0 0000000000001.84E-02AB-TE-02 Aft Tunnel Thruster Engine 1.17 0.67 0.65 40.18 1.88E-02 5.87E-04 9.21 1.07 3.40E-04 1,917.10 2.95E-04 9.23E-05 9.09E-03 9.25E-04 3.29E-03 2.26E-03 2.48E-03 0 1.52E-03 0 0 0 0000000000001.84E-02AB-TE-03 Bow Drop Down Thruster 1.17 0.67 0.65 40.18 1.88E-02 5.87E-04 9.21 1.07 3.40E-04 1,917.10 2.95E-04 9.23E-05 9.09E-03 9.25E-04 3.29E-032.26E-03 2.48E-03 0 1.52E-03 0 0 0 0000000000001.84E-02AB-GE-01 Service Generator Engine 1 0.50 0.29 0.28 17.18 8.03E-03 2.51E-04 3.94 0.46 1.45E-04 819.98 1.26E-04 3.95E-05 3.89E-03 3.95E-04 1.41E-03 9.67E-04 1.06E-03 0 6.52E-04 0 0 0 0000000000007.89E-03AB-GE-02 Service Generator Engine 2 0.50 0.29 0.28 17.18 8.03E-03 2.51E-04 3.94 0.46 1.45E-04 819.98 1.26E-04 3.95E-05 3.89E-03 3.95E-04 1.41E-03 9.67E-04 1.06E-03 0 6.52E-04 0 0 0 0000000000007.89E-03AB-GE-03 Service Generator Engine 3 0.50 0.29 0.28 17.18 8.03E-03 2.51E-04 3.94 0.46 1.45E-04 819.98 1.26E-04 3.95E-05 3.89E-03 3.95E-04 1.41E-03 9.67E-04 1.06E-03 0 6.52E-04 0 0 0 0000000000007.89E-03AB-GE-04 Service Generator Engine 4 0.91 0.52 0.51 31.20 1.46E-02 4.55E-04 7.15 0.83 2.64E-04 1,488.78 2.29E-04 7.17E-05 7.06E-03 7.18E-04 2.56E-03 1.76E-03 1.93E-03 0 1.18E-03 0 0 0 0000000000001.43E-02AB-GE-05 Service Generator Engine 5 0.91 0.52 0.51 31.20 1.46E-02 4.55E-04 7.15 0.83 2.64E-04 1,488.78 2.29E-04 7.17E-05 7.06E-03 7.18E-04 2.56E-03 1.76E-03 1.93E-03 0 1.18E-03 0 0 0 0000000000001.43E-02AB-GE-06 Emergency Generator 0.68 0.68 0.68 9.52 3.44E-03 1.08E-04 2.05 0.77 6.23E-05 351.58 1.65E-03 1.99E-04 2.01E-03 2.54E-03 8.79E-04 6.12E-04 3.61E-04 8.40E-05 1.82E-04 0 0 0 0000000000008.32E-03AB-GE-07 Port Winch Hydraulic Engine 0.91 0.52 0.51 31.20 1.46E-02 4.55E-04 7.15 0.83 2.64E-04 1,488.78 2.29E-04 7.17E-05 7.06E-03 7.18E-04 2.56E-03 1.76E-03 1.93E-03 0 1.18E-03 0 0 0 0000000000001.43E-02AB-GE-08 Starboard Winch Hydraulic Engine 0.91 0.52 0.51 31.20 1.46E-02 4.55E-04 7.15 0.83 2.64E-04 1,488.78 2.29E-04 7.17E-05 7.06E-03 7.18E-04 2.56E-03 1.76E-03 1.93E-03 0 1.18E-03 0 0 0 0000000000001.43E-024.88 2.79 2.71 167.15 7.81E-02 2.44E-03 38.30 4.47 1.41E-03 7,975.76 1.23E-03 3.84E-04 3.78E-02 3.85E-03 1.37E-02 9.41E-03 1.03E-02 8.40E-05 6.34E-03 0 0 0 0000000000007.67E-02AB-DT-01 Port Side Double Bottom Diesel Fuel Tank #1 0 0 0 0 0 0 0 1.17E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-02Starboard Side Double Bottom Diesel Fuel Tank #10 0 0 0 0 0 0 1.17E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-03Center Double Bottom Diesel Fuel Tank #10 0 0 0 0 0 0 1.78E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-04Port Side Double Bottom Diesel Fuel Tank #20 0 0 0 0 0 0 3.12E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-05Starboard Side Double Bottom Diesel Fuel Tank #20 0 0 0 0 0 0 3.12E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-06Port Wing Diesel Fuel Tank #10 0 0 0 0 0 0 1.31E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-07Starboard Wing Diesel Fuel Tank #10 0 0 0 0 0 0 1.31E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-08Port Side Double Bottom Diesel Fuel Tank #30 0 0 0 0 0 0 2.35E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-09Starboard Side Double Bottom Diesel Fuel Tank #30 0 0 0 0 0 0 2.35E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-10Port Wing Diesel Fuel Tank #20 0 0 0 0 0 0 4.17E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-11Starboard Side Double Bottom Diesel Fuel Tank #40 0 0 0 0 0 0 4.77E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-12Starboard Wing Diesel Fuel Tank #20 0 0 0 0 0 0 3.68E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-13Port Side Double Bottom Diesel Fuel Tank #40 0 0 0 0 0 0 2.89E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-14Starboard Side Double Bottom Diesel Fuel Tank #50 0 0 0 0 0 0 2.30E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-15Port Service Diesel Tank0 0 0 0 0 0 0 1.07E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-16Starboard Service Diesel Tank0 0 0 0 0 0 0 1.07E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-17Port Diesel Settling Tank0 0 0 0 0 0 0 1.08E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-18Starboard Diesel Settling Tank0 0 0 0 0 0 0 1.08E-03 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-DT-19 Diesel Overflow Tank 0 0 0 0 0 0 0 3.96E-04 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 4.12E-02 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0AB-FE-01Fugitive Emissions From Diesel Fuel Lines0 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 0.01 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 03.99 3.32 3.23 142.96 0.13 4.08E-03 98.54 7.52 2.37E-03 12,688.49 5.73E-03 1.04E-03 6.10E-02 1.17E-02 2.24E-02 1.54E-02 1.62E-02 1.99E-04 9.85E-030 0 0 0 0 0 0 0 0 0 0 0 0 0 00.134.88 2.79 2.71 167.15 0.08 2.44E-03 38.30 4.52 1.41E-03 7,975.76 1.23E-03 3.84E-04 3.78E-02 3.85E-03 1.37E-02 9.41E-03 1.03E-02 8.40E-05 6.34E-030 0 0 0 000000000000.084.88 3.32 3.23 167.15 0.13 4.08E-03 98.54 7.52 2.37E-03 12,688.49 5.73E-03 1.04E-03 6.10E-02 1.17E-02 2.24E-02 1.54E-02 1.62E-02 1.99E-04 9.85E-030 0 0 0 0 0 0 0 0 0 0 0 0 0 00.13SV-ME-01Stimulation Vessel Main Engine #1 0.75 0.43 0.42 12.99 0.01 3.18E-04 7.47 0.58 1.84E-04 1,040.43 1.60E-04 5.01E-05 4.93E-03 5.02E-04 1.79E-03 1.23E-03 1.35E-03 0 8.27E-04 0 0 0 0000000000000.01SV-ME-02Stimulation Vessel Main Engine #2 0.75 0.43 0.42 12.99 0.01 3.18E-04 7.47 0.58 1.84E-04 1,040.43 1.60E-04 5.01E-05 4.93E-03 5.02E-04 1.79E-03 1.23E-03 1.35E-03 0 8.27E-04 0 0 0 0000000000000.01SV-BT-01Stimulation Vessel Bow Thruster 0.29 0.17 0.16 10.05 4.70E-03 1.47E-04 2.30 0.27 8.50E-05 479.56 7.39E-05 2.31E-05 2.27E-03 2.31E-04 8.24E-04 5.66E-04 6.21E-04 0 3.81E-04 0 0 0 0000000000004.61E-03SV-DD-01Stimulation Vessel Bow Drop-Down 0.21 0.12 0.12 7.20 3.36E-03 1.05E-04 1.65 0.19 6.09E-05 343.57 5.29E-05 1.65E-05 1.63E-03 1.66E-04 5.90E-04 4.05E-04 4.45E-04 0 2.73E-04 0 0 0 0000000000003.31E-03SV-ST-01Stimulation Vessel Stern Thruster 0.29 0.17 0.16 10.05 4.70E-03 1.47E-04 2.30 0.27 8.50E-05 479.56 7.39E-05 2.31E-05 2.27E-03 2.31E-04 8.24E-04 5.66E-04 6.21E-04 0 3.81E-04 0 0 0 0000000000004.61E-03SV-PE-01 thru SV-PE-08Stimulation Vessel Representative Pumps 12.60 7.22 7.01 432.00 0.20 6.31E-03 99.00 11.55 3.65E-03 20,613.93 3.18E-03 9.93E-04 9.78E-02 9.94E-03 3.54E-02 2.43E-02 2.67E-02 0 1.64E-02 0 0 0 0000000000000.20SV-GE-01 and SV-GE-02Stimulation Vessel Generators Chouest 0.80 0.46 0.45 25.68 0.03 8.55E-04 14.04 1.57 4.95E-04 2,795.04 4.31E-04 1.35E-04 1.33E-02 1.35E-03 4.80E-03 3.30E-03 3.62E-03 0 2.22E-03 0 0 0 0000000000000.03SV-GE-03 and SV-GE-04 Stimulation Vessel Generators Baker Hughes 0.53 0.30 0.29 16.93 0.02 5.64E-04 9.26 1.03 3.27E-04 1,842.89 2.84E-04 8.88E-05 8.74E-03 8.89E-04 3.17E-03 2.17E-03 2.39E-03 0 1.46E-03 0 0 0 0000000000000.0216.22 9.29 9.02 527.90 0.28 0.01 143.50 16.04 5.08E-03 28,635.41 4.41E-03 1.38E-03 1.36E-01 1.38E-02 4.92E-02 3.38E-02 3.71E-02 0 2.28E-02 0 0 0 0 0 0 0000000000.28DR-WC-01 Tubing Running Unit Engine0.06 0.06 0.08 1.12 1.03E-03 3.22E-05 0.75 0.231 1.87E-05 105.36 4.94E-04 5.96E-05 6.01E-04 7.60E-04 2.63E-04 1.84E-04 1.08E-04 2.52E-05 5.46E-050 0 0 0 000000000002.49E-03DR-WC-02 Fluid Filtration Pump0.05 0.05 0.05 1.09 1.13E-03 3.52E-05 0.83 0.252 2.04E-05 114.98 5.39E-04 6.50E-05 6.56E-04 8.29E-04 2.87E-04 2.00E-04 1.18E-04 2.75E-05 5.96E-050 0 0 0 000000000002.72E-03DR-WC-03 Eline Power Pack0.07 0.07 0.07 2.44 2.52E-03 7.88E-05 1.30 0.566 4.57E-05 257.67 1.21E-03 1.46E-04 1.47E-03 1.86E-03 6.44E-04 4.49E-04 2.65E-04 6.16E-05 1.34E-040 0 0 0 000000000006.10E-03DR-WC-04 Slickline Power Pack0.04 0.04 0.04 1.37 1.41E-03 4.42E-05 0.73 0.317 2.56E-05 144.36 6.77E-04 8.16E-05 8.23E-04 1.04E-03 3.61E-04 2.51E-04 1.48E-04 3.45E-05 7.48E-050 0 0 0 000000000003.42E-03DR-WC-05 Flowback Boiler0.18 0.18 0.18 1.330.010 0.28 1.11E-02 7.01E-05 1,273.81 0 0 0 0 0 0 0 0 0 0 000 00000000001.84E-04 1.84E-04DR-WC-06 Boom Flare18.62 18.62 18.62 169.93 1.47 0 924.63 349.86 0.00 292,391.98 0 0 5.15E-03 1.84E-01 8.33E-03 0 0 0 1.49E-03 0 002.94E-03 4.41 4.90E-04 2.94E-05 2.70E-03 3.43E-03 2.06E-04 9.31E-04 6.37E-04 5.15E-03 5.88E-05 2.16E-04 4.61DR-WC-07 CT Power Pack0.20 0.20 0.20 6.31 6.73E-03 2.10E-04 3.452 1.507 1.22E-04 687.13 3.22E-03 3.89E-04 3.92E-03 4.96E-03 1.72E-03 1.20E-03 7.06E-04 1.64E-04 3.56E-040 0 0 0 000000000001.63E-02DR-WC-08 CT Pump0.28 0.16 0.16 9.05 9.65E-03 3.01E-04 4.95 0.55 1.75E-04 984.89 1.52E-04 4.74E-05 4.67E-03 4.75E-04 1.69E-03 1.16E-03 1.28E-03 0 7.83E-040 0 0 0 000000000009.48E-03DR-WC-09 Wire line Diesel Engine #3 0.09 0.09 0.09 2.98 3.08E-03 9.64E-05 1.58 0.69 5.58E-05 318.61 1.48E-03 1.78E-04 1.80E-03 2.27E-03 7.87E-04 5.49E-04 3.23E-04 7.53E-05 1.63E-04 0 0 0 0000000000007.46E-03DR-WC-10 Wire line Diesel Engine #4 0.09 0.09 0.09 2.98 3.08E-03 9.64E-05 1.58 0.69 5.58E-05 318.61 1.48E-03 1.78E-04 1.80E-03 2.27E-03 7.87E-04 5.49E-04 3.23E-04 7.53E-05 1.63E-04 0 0 0 0000000000007.46E-0319.51 19.39 19.40 192.65 1.50 7.02E-04 936.91353.30 4.77E-04 295,960.18 6.29E-03 7.88E-04 1.73E-02 1.94E-01 1.33E-02 3.44E-03 2.62E-03 3.13E-04 2.96E-03 0 0 0 2.94E-03 4.41 4.90E-04 2.94E-05 2.70E-03 3.43E-03 2.06E-04 9.31E-04 6.37E-04 5.15E-03 5.88E-05 4.00E-04 4.65TB-ME-01 Main Engine #11.54 0.88 0.86 28.390.027.71E-04 12.10 1.41 4.47E-04 2,519.48 3.88E-04 1.21E-04 1.20E-02 1.22E-03 4.33E-03 2.97E-03 3.26E-03 0 2.00E-03 0 0 0 0000000000000.02TB-ME-02 Main Engine# 21.54 0.88 0.86 28.390.027.71E-04 12.10 1.41 4.47E-04 2,519.48 3.88E-04 1.21E-04 1.20E-02 1.22E-03 4.33E-03 2.97E-03 3.26E-03 0 2.00E-03 0 0 0 0000000000000.02TB-ME-03 Main Engine #31.54 0.88 0.86 28.390.027.71E-04 12.10 1.41 4.47E-04 2,519.48 3.88E-04 1.21E-04 1.20E-02 1.22E-03 4.33E-03 2.97E-03 3.26E-03 0 2.00E-03 0 0 0 0000000000000.02TB-GE-01 Generator Engine #10.38 0.38 0.38 5.40 1.96E-03 6.11E-05 1.16 0.44 3.54E-05 199.65 9.36E-04 1.13E-04 1.14E-03 1.44E-03 4.99E-04 3.48E-04 2.05E-04 4.77E-05 1.03E-04 00 0 0 000000000004.73E-03TB-GE-02 Generator Engine #2 0.38 0.38 0.38 5.40 1.96E-03 6.11E-05 1.16 0.44 3.54E-05 199.65 9.36E-04 1.13E-04 1.14E-03 1.44E-03 4.99E-04 3.48E-04 2.05E-04 4.77E-05 1.03E-04 0 0 0 0000000000004.73E-0312.32 7.06 6.85 227.13 1.97E-01 6.17E-03 96.80 11.29 3.57E-03 20,155.85 3.10E-03 9.71E-04 9.56E-02 9.72E-03 3.46E-02 2.38E-02 2.61E-02 3.82E-04 1.60E-02 0 0 0 0000000000000.19BG-LP-01 Barge Loading Pump Engine #1 1.19 1.19 1.19 16.74 6.06E-03 1.89E-04 3.61 1.36 1.10E-04 618.42 2.90E-03 3.50E-04 3.53E-03 4.46E-03 1.55E-03 1.08E-03 6.35E-04 1.48E-04 3.21E-04 0 0 0 0000000000000.011.19 1.19 1.19 16.74 6.06E-03 1.89E-04 3.61 1.36 1.10E-04 618.42 2.90E-03 3.50E-04 3.53E-03 4.46E-03 1.55E-03 1.08E-03 6.35E-04 1.48E-04 3.21E-040 0 0 0 000000000000.01WC-CT-01 Well Completion Condensate Tank #10 0 0 0 0 0 0 0.92 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0WC-CT-02 Well Completion Condensate Tank #20 0 0 0 0 0 0 0.92 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 0WC-CT-03 Well Completion Condensate Tank #3 0 0 0 0 0 0 0 0.92 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 00 0 0 0 0 0 0 2.77 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000 026.46 24.09 23.96 427.94 1.64 4.80E-03 992.67 391.44 3.19E-03 309,132.60 8.36E-03 1.42E-03 7.92E-02 2.00E-01 3.57E-02 7.33 1.95E-02 3.16E-04 1.33E-02 1.76 1.85 0.02 04000000000015.6831.84 24.57 24.28 540.52 1.28 9.03E-03 733.43 283.55 5.64E-03 225,829.36 1.20E-02 2.28E-03 1.45E-01 1.48E-01 5.75E-02 7.35 3.78E-02 7.76E-04 2.40E-02 1.76 1.85 0.02 03000000000014.3021.96 13.02 12.66 709.93 0.37 1.14E-02 159.82 53.69 6.96E-03 37,488.71 1.04E-02 2.33E-03 1.78E-01 2.50E-02 6.50E-02 7.36 4.82E-02 2.47E-04 2.94E-02 1.76 1.85 0.02 00000000000011.308.54 6.05 5.94 284.03 0.18 5.70E-03 82.93 43.60 3.64E-03 18,398.43 1.76E-02 2.57E-03 8.98E-02 3.08E-02 3.39E-02 7.33 2.28E-02 7.80E-04 1.36E-02 1.76 1.85 0.02 00000000000011.1331.84 24.57 24.28 709.93 1.64 1.14E-02 992.67 391.44 6.96E-03 309,132.60 1.76E-02 2.57E-03 1.78E-01 2.00E-01 6.50E-02 7.36 4.82E-02 7.80E-04 2.94E-02 1.76 1.85 0.02 2.94E-03 4.41 4.90E-04 2.94E-05 2.70E-03 8.70E-03 2.08E-04 5.51E-03 6.37E-04 5.55E-03 5.88E-05 4.00E-04 15.6819.81 13.21 12.92 630.19 0.35 0.01 162.19 54.95 6.74E-03 35,562.18 0.02 3.91E-03 0.17 0.05 0.06 7.36 0.04 1.02E-03 0.03 1.76 1.85 0.02 00000000000011.3231.84 24.57 24.28 709.93 1.64 0.01 992.67 391.44 6.96E-03 309,132.60 0.02 2.57E-03 0.18 0.20 0.07 7.36 0.05 7.80E-04 0.03 1.76 1.85 0.02 04000000000015.68TOTAL - Supply Boats Scenario (HOS Coral or Similar)TOTAL (Drillship + Support Vessel ) Worst-Case Operating ScenarioSupport VesselsSupply Boat Fugitive EmissionsHOS Coral Work Boat Engines or Similar Supply Boat- TOTALKirt Chouest Anchor Handling Boat Engines- TOTAL (Max 7500 gpd of fuel usage)Kirt Chouest Anchor Handling Boat Tanks EmissionsAnchor Handling Boat Fugitive EmissionsHOS Coral Work Boat or Similar Supply Boat Tanks EmissionsTOTAL - Anchor Handling Boat Scenario (Kirt Chouest or Similar)TOTAL - Worst-Case Support Vessels ScenarioDiscoverer Spirit Well CompletionStimulation Vessel Operation - TOTALWell Completion Misc Operation - TOTALTOTAL - Worst-Case Well Completion ScenarioTOTAL (Well Completion + Support Vessel ) Worst-Case OperatingScenarioRepresentative Tug Operation - TOTAL (Max 340 bbls per day of fuel usage)Representative Barge Operation - TOTALWell Completion Condensate Tanks - TOTALTOTAL - Worst-Case Gas Well Flowback ScenarioTOTAL - Worst-Case Oil Well Flowback ScenarioTOTAL - Stimulation Vessel Operation ScenarioTOTAL - Third Party Equipment Operation ScenarioAnadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit8 of 40Max Hourly Emission SummaryDate Printed - 6/26/2013

### Engine Rating [1] 18 HP Operating Time [2] = 0.5 hr/day 104.0 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [4],[5] 2.20E-03 lb/hp-hr 0.02 0.02 1.03E-03
PM 10 

### AP-42 [4],[5] 2.20E-03 lb/hp-hr 0.02 0.02 1.03E-03
PM 2.5 

### AP-42 [4],[5] 2.20E-03 lb/hp-hr 0.02 0.02 1.03E-03
NO x 

### AP-42 [4] 0.031 lb/hp-hr 0.28 0.28 1.45E-02
SO 2 

### Fuel S Content [3] 1.12E-05 lb/hp-hr 1.01E-04 1.01E-04 5.25E-06 CO AP-42 [4] 6.68E-03 lb/hp-hr 0.06 0.06 3.13E-03 VOC AP-42 [4],[7] 2.51E-03 lb/hp-hr 0.02 0.02 1.18E-03

Pb EPA [6] 2.03E-07 lb/hp-hr 1.83E-06 1.83E-06 9.50E-08 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/hp-hr 3.15E-06 3.15E-06 1.64E-07

[1] [2]

[3]

[4]

[5]

[6]

[7] All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #1 EPN: DR-AC-01 Criteria Pollutants and Sulfuric Acid

Pollutant Emission Factor Basis Emission Factor

Lead emission factor (2.9x10 -5 

### lb/MMBtu) is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines is used as a surrogate for distillate oil-fired engines due to lack of emissionfactors. An average brake-specific fuel consumption (Brake Specific Fuel Consumption (BFSC)) of 7,000 Btu/hphr is used to convert from lb/MMBtu to lb/hp-hr. Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppmw in diesel fuel assuming that 98 wt.% of sulfur in the fuel is oxidized to SO 2 

### and 2 wt.% of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on AP-42 Appendix A, table 3.4.1 footnote e and Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, all PM is assumed to be < 1 μ m. Therefore, it is assumed PM 2.5 

### = PM 10 

### = PM.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 9 of 40 Gen AC-01 - Criteria Date Printed - 6/26/2013

### Engine Rating [1] 18 HP Operating Time [2] = 0.5 hr/day 104.0 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [4],[5] 7.67E-04 lb/MMBtu 4.83E-05 4.83E-05 2.51E-06

Acrolein AP-42 [4],[5] 9.25E-05 lb/MMBtu 5.83E-06 5.83E-06 3.03E-07 Benzene AP-42 [4],[5] 9.33E-04 lb/MMBtu 5.88E-05 5.88E-05 3.06E-06 Formaldehyde AP-42 [4],[5] 1.18E-03 lb/MMBtu 7.43E-05 7.43E-05 3.87E-06 Toluene AP-42 [4],[5] 4.09E-04 lb/MMBtu 2.58E-05 2.58E-05 1.34E-06 Xylenes AP-42 [4],[5] 2.85E-04 lb/MMBtu 1.80E-05 1.80E-05 9.34E-07 1,3-Butadiene AP-42 [4],[5] 3.91E-05 lb/MMBtu 2.46E-06 2.46E-06 1.28E-07

Total PAH AP-42 [4],[5] 1.68E-04 lb/MMBtu 1.06E-05 1.06E-05 5.50E-07 Naphthalene AP-42 [4],[5] 8.48E-05 lb/MMBtu 5.34E-06 5.34E-06 2.78E-07 2.44E-04 2.44E-04 1.27E-05

[1] [2]

[3] [4]

[5] 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #1 EPN: DR-AC-01 Hazardous Air Pollutants

Pollutant Emission Factor Basis Emission Factor

Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition.

Emission factors are based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Total VOC HAPs

Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 10 of 40 Gen AC-01 - HAP Date Printed - 6/26/2013

### Engine Rating [1] 18 HP Operating Time [2] = 0.5 hrs/day 104.0 hrs/yr Operating load [2] = 100% CO 2 

### 1 Fuel Type [3] = ULSD CH 4 

### 21
N 2 

### O 310

Maximum

Hourly
Emissions [7] 

### Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr)

CO 2 

### 40 CFR 98 Subpart C [4] 73.96 kg/MMBtu 10.27 10.27 0.53

CH 4 

### 40 CFR 98 Subpart C [5] 3.00E-03 kg/MMBtu 4.17E-04 4.17E-04 2.17E-05

N 2 

### O 40 CFR 98 Subpart C [5] 6.00E-04 kg/MMBtu 8.33E-05 8.33E-05 4.33E-06

CO 2 

### e 40 CFR 98 Subpart C [6] -- -- 10.31 10.31 0.54

[1]
[2]

[3] [4]

[5]

[6]

[7] An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Emission factor is based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 is used to calculate

Global warming potentials (GWP) for CH 4 

### , CO 2 

### and N 2 

### O are used to calculate CO 2 

### equivalent (CO 2 

### e). The GWPs are obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #1 EPN: DR-AC-01 Greenhouse Gases

Pollutant Emission Factor Basis Emission Factor

Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion

Emission factors are based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) is used to calculate Chemicals Global Warming Potential (100 yr.)

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 11 of 40 Gen AC-01 - GHG Date Printed - 6/26/2013

### Engine Rating [1] 15 HP Operating Time [2] = 0.5 hrs/day 104.0 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [4],[5] 2.20E-03 lb/hp-hr 1.65E-02 1.65E-02 8.58E-04
PM 10 

### AP-42 [4],[5] 2.20E-03 lb/hp-hr 1.65E-02 1.65E-02 8.58E-04
PM 2.5 

### AP-42 [4],[5] 2.20E-03 lb/hp-hr 1.65E-02 1.65E-02 8.58E-04
NO x 

### AP-42 [4] 0.031 lb/hp-hr 2.33E-01 2.33E-01 1.21E-02
SO 2 

### Fuel S Content [3] 1.12E-05 lb/hp-hr 8.41E-05 8.41E-05 4.37E-06 CO AP-42 [4] 6.68E-03 lb/hp-hr 5.01E-02 5.01E-02 2.61E-03 VOC AP-42 [4],[7] 2.51E-03 lb/hp-hr 1.89E-02 1.89E-02 9.80E-04

Pb EPA [6] 2.03E-07 lb/hp-hr 1.52E-06 1.52E-06 7.92E-08 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/hp-hr 2.63E-06 2.63E-06 1.37E-07

[1] [2]

[3]

[4]

[5]

[6]

[7] All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. Lead emission factor (2.9x10 -5 

### lb/MMBtu) is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines is used as a surrogate for distillate oil-fired engines due to lack of emission factors. An average brake-specific fuel consumption (Brake Specific Fuel Consumption (BFSC)) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hp-hr. 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #2 EPN: DR-AC-02 Criteria Pollutants and Sulfuric Acid

Pollutant Emission Factor Basis Emission Factor

Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppmw in diesel fuel assuming that 98 wt.% of sulfur in the fuel is oxidized to SO 2 

### and 2 wt.% of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on AP-42 Appendix A, table 3.4.1 footnote e and Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, all PM is assumed to be < 1 μ m. Therefore, it is assumed PM 2.5 

### = PM 10 

### = PM.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 12 of 40 Gen AC-02 - Criteria Date Printed - 6/26/2013

### Engine Rating [1] 15 HP Operating Time [2] = 0.5 hrs/day 104.0 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [4],[5] 7.67E-04 lb/MMBtu 4.03E-05 4.03E-05 2.09E-06

Acrolein AP-42 [4],[5] 9.25E-05 lb/MMBtu 4.86E-06 4.86E-06 2.53E-07 Benzene AP-42 [4],[5] 9.33E-04 lb/MMBtu 4.90E-05 4.90E-05 2.55E-06 Formaldehyde AP-42 [4],[5] 1.18E-03 lb/MMBtu 6.20E-05 6.20E-05 3.22E-06 Toluene AP-42 [4],[5] 4.09E-04 lb/MMBtu 2.15E-05 2.15E-05 1.12E-06 Xylenes AP-42 [4],[5] 2.85E-04 lb/MMBtu 1.50E-05 1.50E-05 7.78E-07 1,3-Butadiene AP-42 [4],[5] 3.91E-05 lb/MMBtu 2.05E-06 2.05E-06 1.07E-07

Total PAH AP-42 [4],[5] 1.68E-04 lb/MMBtu 8.82E-06 8.82E-06 4.59E-07 Naphthalene AP-42 [4],[5] 8.48E-05 lb/MMBtu 4.45E-06 4.45E-06 2.32E-07 2.03E-04 2.03E-04 1.06E-05

[1] [2]

[3] [4]

[5] An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #2 EPN: DR-AC-02 Hazardous Air Pollutants

Pollutant Emission Factor Basis Emission Factor

Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion Emission factors based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). Total VOC HAPs

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 13 of 40 Gen AC-02 - HAP Date Printed - 6/26/2013

### Engine Rating [1] 15 HP Operating Time [2] = 0.5 hrs/day 104.0 hrs/yr Operating load [2] = 100% CO 2 

### 1 Fuel Type [3] = ULSD CH 4 

### 21
N 2 

### O 310

Maximum

Hourly
Emissions [7] 

### Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr)

CO 2 

### 40 CFR 98 Subpart C [4] 73.96 kg/MMBtu 8.56 8.56 0.45

CH 4 

### 40 CFR 98 Subpart C [5] 3.00E-03 kg/MMBtu 3.47E-04 3.47E-04 1.81E-05

N 2 

### O 40 CFR 98 Subpart C [5] 6.00E-04 kg/MMBtu 6.94E-05 6.94E-05 3.61E-06

CO 2 

### e 40 CFR 98 Subpart C [6] -- -- 8.59 8.59 0.45

[1]
[2]

[3] [4]

[5]

[6]

[7] Global Warming Potential (100 yr.)

An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Global warming potentials (GWP) for CH 4 

### , CO 2 

### and N 2 

### O are used to calculate CO 2 

### equivalent (CO 2 

### e). The GWPs are obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon). 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Air Compressor Engine #2 EPN: DR-AC-02 Greenhouse Gases

Pollutant Emission Factor Basis Emission Factor

Based on EPA Region 4 Permit No. OCS-EPA-R4005-M1. Operating time for this engine is conservatively assumed to be 0.5 hrs/day, 104.0 hr/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion sources. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate emissions. Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate emissions. Chemicals

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 14 of 40 Gen AC-02 - GHG Date Printed - 6/26/2013Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
PM 10 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
PM 2.5 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
NO x 40 CFR 89.112 [6] 6.6 g/kW-hr 2.98 71.61 2.15
SO 2 Fuel S Content [3] 1.12E-05 lb/hp-hr 0.0031 7.40E-02 2.22E-03 CO 40 CFR 89.112 [6] 3.5 g/kW-hr 1.58 37.98 1.14 VOC AP-42 [8] 2.51E-03 lb/hp-hr 0.69 16.59 0.50

Pb EPA [7] 2.03E-07 lb/hp-hr 5.58E-05 1.34E-03 4.02E-05 H 2 SO 4 Fuel S Content [3] 3.50E-07 lb/hp-hr 9.64E-05 2.31E-03 6.94E-05

[1]

[2]
[3]

[4] [5]

[6]

[7]

[8] Rating is based on the Cummins C8.3 engine specification sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppmw in diesel fuel assuming that 98 wt.% of sulfur in the fuel is oxidized to SO 2 and 2 wt.% of sulfur in the fuel is oxidized to H 2 SO 4 based on AP-42 Appendix A, table 3.4.1 footnote e and Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel En g ines, EPA420-R-03-008, A p ril 2003. 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #3 EPN: DR-WC-09 Criteria Pollutants and Sulfuric Acid

Pollutant Emission Factor Basis Emission Factor

Factor is based on AP-42, Table 3.3-1. All TOC is assumed to be VOC. TOC emission factor is calculated as the sum of exhaust and crankcase emission factors. Lead emission factor (2.9x10 -5 lb/MMBtu) is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines is used as a surrogate for distillate oil-fired engines due to lack of specific emission factors for distillate oil-fired engines. According to Cummin's Specification Sheet, this engine is EPA Tier 2 certified. The NOx+NMHC emission factor is 6.6 g/kW-hr. Factor for NOx+NMHC can also be found in 40 CFR, Part 89.112 Table 1. From the same reference, CO emission factor is 3.5 g/kW-hr. According to Cummins C8.3 engine Specification Sheet, this engine is EPA Tier 2 certified. The PM emission Based on footnote b of AP-42 Chapter 3, Table 3.3-1, all PM is assumed to be < 1 μ m, therefore, assumed PM 2.5 = PM 10 = PM.

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 15 of 40 DR-WC-09- Crit Date Printed - 6/26/2013Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [4],[5] 7.67E-04 lb/MMBtu 1.48E-03 3.54E-02 1.06E-03

Acrolein AP-42 [4],[5] 9.25E-05 lb/MMBtu 1.78E-04 4.27E-03 1.28E-04 Benzene AP-42 [4],[5] 9.33E-04 lb/MMBtu 1.80E-03 4.31E-02 1.29E-03 Formaldehyde AP-42 [4],[5] 1.18E-03 lb/MMBtu 2.27E-03 5.45E-02 1.64E-03

Toluene AP-42 [4],[5] 4.09E-04 lb/MMBtu 7.87E-04 1.89E-02 5.67E-04 Xylenes AP-42 [4],[5] 2.85E-04 lb/MMBtu 5.49E-04 1.32E-02 3.95E-04 1,3-Butadiene AP-42 [4],[5] 3.91E-05 lb/MMBtu 7.53E-05 1.81E-03 5.42E-05

Total PAH AP-42 [4],[5] 1.68E-04 lb/MMBtu 3.23E-04 7.76E-03 2.33E-04 Naphthalene AP-42 [4],[5] 8.48E-05 lb/MMBtu 1.63E-04 3.92E-03 1.18E-04 7.46E-03 1.79E-01 5.37E-03

[1] [2]

[3] [4]

[5] Total VOC HAPs 

### Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #3 EPN: DR-WC-09 Hazardous Air Pollutants

Pollutant Emission Factor Basis Emission Factor

An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Rating is based on the Cummins C8.3 engine specification sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion sources. Emission factors are based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996).

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 16 of 40 DR-WC-09- HAP Date Printed - 6/26/2013

### Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr CO 2 

### 1 Operating load [2] = 100% CH 4 

### 21 Fuel Type [3] = ULSD N 2 

### O 310

Maximum

Hourly
Emissions [7] 

### Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr)

CO 2 

### 40 CFR 98 Subpart C [4] 73.96 kg/MMBtu 313.88 7533.08 225.99

CH 4 

### 40 CFR 98 Subpart C [5] 3.00E-03 kg/MMBtu 0.013 0.31 9.17E-03

N 2 

### O 40 CFR 98 Subpart C [5] 6.00E-04 kg/MMBtu 2.55E-03 0.06 1.83E-03

CO 2 

### e 40 CFR 98 Subpart C [6] -- -- 318.61 7558.44 226.75

[1] [2]

[3] [4]

[5]

[6]

[7] An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hphr to calculate emissions. Global warming potentials (GWP) for CH 4 

### , CO 2 

### and N 2 

### O are used to calculate CO 2 

### equivalent (CO 2 

### e). The GWPs are obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon). 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #3 EPN: DR-WC-09 Greenhouse Gases

Pollutant Emission Factor Basis Emission Factor

Rating is based on the Cummins C8.3 engine specification sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion sources. Emission factor is based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 is used to calculate emissions.

Emission factor is based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) is used to calculate emissions. Chemicals Global Warming Potential ( 100 y r. )

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 17 of 40 DR-WC-09- GHG Date Printed - 6/26/2013

### Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
PM 10 

### 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
PM 2.5 

### 40 CFR 89.112, AP-42 [4],[5] 0.2 g/kW-hr 0.09 2.17 0.07
NO x 

### 40 CFR 89.112 [6] 6.6 g/kW-hr 2.98 71.61 2.15
SO 2 

### Fuel S Content [3] 1.12E-05 lb/hp-hr 0.003 7.40E-02 2.22E-03 CO 40 CFR 89.112 [6] 3.5 g/kW-hr 1.58 37.98 1.14 VOC AP-42 [8] 2.51E-03 lb/hp-hr 0.69 16.59 0.50

Pb EPA [7] 2.03E-07 lb/hp-hr 5.58E-05 1.34E-03 4.02E-05 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/hp-hr 9.64E-05 2.31E-03 6.94E-05

[1]

[2]
[3]

[4]

[5]

[6]

[7]

[8] Rating is based on the Cummins C8.3 engine Specification Sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppmw in diesel fuel assuming that 98 wt.% of sulfur in the fuel is oxidized to SO 2 

### and 2 wt.% of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on AP-42 Appendix A, table 3.4.1 footnote e and Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #4 EPN: DR-WC-10 Criteria Pollutants and Sufuric Acid

Pollutant Emission Factor Basis Emission Factor

Factor is based on AP-42, Table 3.3-1. All TOC is assumed to be VOC. TOC emission factor is calculated as the sum of exhaust and crankcase emission factors. Lead emission factor (2.9x10 -5 

### lb/MMBtu) is obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines is used as a surrogate for distillate oil-fired engines due to lack of specific emission factors for distillate oil-fired engines. According to Cummin's Specification Sheet, this engine is EPA Tier 2 certified. The NOx+NMHC emission factor is 6.6 g/kW-hr. Factor for NOx+NMHC can also be found in 40 CFR, Part 89.112 Table 1. From the same reference, CO emission factor is 3.5 g/kW-hr. According to Cummins C8.3 engine Specification Sheet, this engine is EPA Tier 2 certified. The PM emission factor is 0.2 g/kW-hr. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, all PM is assumed to be < 1 μ m, therefore, assumed PM 2.5 

### = PM 10 

### = PM.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 18 of 40 DR-WC-10- Crit Date Printed - 6/26/2013

### Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr Operating load [2] = 100% Fuel Type [3] = ULSD

Maximum Hourly Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [4],[5] 7.67E-04 lb/MMBtu 1.48E-03 3.54E-02 1.06E-03

Acrolein AP-42 [4],[5] 9.25E-05 lb/MMBtu 1.78E-04 4.27E-03 1.28E-04 Benzene AP-42 [4],[5] 9.33E-04 lb/MMBtu 1.80E-03 4.31E-02 1.29E-03 Formaldehyde AP-42 [4],[5] 1.18E-03 lb/MMBtu 2.27E-03 5.45E-02 1.64E-03 Toluene AP-42 [4],[5] 4.09E-04 lb/MMBtu 7.87E-04 1.89E-02 5.67E-04 Xylenes AP-42 [4],[5] 2.85E-04 lb/MMBtu 5.49E-04 1.32E-02 3.95E-04 1,3-Butadiene AP-42 [4],[5] 3.91E-05 lb/MMBtu 7.53E-05 1.81E-03 5.42E-05

Total PAH AP-42 [4],[5] 1.68E-04 lb/MMBtu 3.23E-04 7.76E-03 2.33E-04 Naphthalene AP-42 [4],[5] 8.48E-05 lb/MMBtu 1.63E-04 3.92E-03 1.18E-04 7.46E-03 1.79E-01 5.37E-03

[1] [2]

[3] [4]

[5] Total VOC HAPs 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #4 EPN: DR-WC-10 Hazardous Air Pollutants

Pollutant 

### Emission Factor Basis Emission Factor

An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Rating is based on the Cummins C8.3 engine Specification Sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion Emission factors are based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996).

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 19 of 40 DR-WC-10 HAP Date Printed - 6/26/2013

### Engine Rating [1] = 205 kW 275 HP Operating Time [2] = 24 hrs/day 1,440 hrs/yr CO 2 

### 1 Operating load [2] = 100% CH 4 

### 21 Fuel Type [3] = ULSD N 2 

### O 310

Maximum

Hourly
Emissions [7] 

### Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr)

CO 2 

### 40 CFR 98 Subpart C [4] 73.96 kg/MMBtu 313.88 7533.08 225.99

CH 4 

### 40 CFR 98 Subpart C [5] 3.00E-03 kg/MMBtu 1.27E-02 3.06E-01 9.17E-03

N 2 

### O 40 CFR 98 Subpart C [5] 6.00E-04 kg/MMBtu 2.55E-03 0.06 1.83E-03

CO 2 

### e 40 CFR 98 Subpart C [6] -- -- 318.61 7558.44 226.75

[1] [2]

[3] [4]

[5]

[6]

[7] An average Brake Specific Fuel Consumption (BFSC) of 7,000 Btu/hp-hr is used to convert from lb/MMBtu to lb/hphr to calculate emissions. Global warming potentials (GWP) for CH 4 

### , CO 2 

### and N 2 

### O are used to calculate CO 2 

### equivalent (CO 2 

### e). The GWPs are obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon). 

## Anadarko Petroleum Corporation Emission Calculations

Drillship Wire Line Engine #4 EPN: DR-WC-10 Greenhouse Gases

Pollutant Emission Factor Basis Emission Factor

Rating is based on the Cummins C8.3 engine Specification Sheet. Operating time for this engine is conservatively assumed to be 24 hrs/day, 1,440 hrs/year. Operating Load is assumed to be 100% based on expected operating condition. Per 40 CFR 80.510(b), Anadarko proposes the use of Ultra Low Sulfur Diesel for all diesel combustion sources. Emission factor is based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 is used to calculate emissions. Emission factor is based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) is used to calculate emissions. Chemicals Global Warming Potential ( 100 y r. )

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 20 of 40 DR-WC-10 GHG Date Printed - 6/26/2013Engine Rating [1],[4] = 155 kW 208 HP Operating Time [2] = 12 hrs/day 2496 hrs/year Fuel Type [3] = ULSD Operating load [2] = 100%

Maximum Emissions M ax i mum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) tpy PM 40 CFR 89.112, AP-42 [4] 3.29E-04 lb/hp-hr 0.07 0.82 0.09
PM 10 40 CFR 89.112, AP-42 [5] 3.29E-04 lb/hp-hr 0.07 0.82 0.09
PM 2.5 40 CFR 89.112, AP-42 [5] 3.29E-04 lb/hp-hr 0.07 0.82 0.09
NO x 40 CFR 89.112 [4] 6.58E-03 lb/hp-hr 1.37 16.41 1.71
SO 2 Fuel S Content [3] 1.12E-05 lb/hp-hr 2.33E-03 0.03 2.91E-03
H 2 SO 4 Fuel S Content [3] 3.50E-07 lb/hp-hr 7.29E-05 0.00 9.10E-05

CO 40 CFR 89.112 [4] 5.75E-03 lb/hp-hr 1.20 14.36 1.49 VOC AP-42 [6],[7] 2.51E-03 lb/hp-h r 0.52 6.28 0.65

Pb EPA [8] 2.90E-05 lb/Mmbt u 4.22E-05 0.00 5.27E-05

[1] [2]

[3]

[4] [5]

[6]

[ 7 ] [8] Lead emission factor (2.9x10 -5 lb/MMBtu) is obtained from EPA guidance document: Locating and Estimating Air Emissionsfrom Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oilfired gas turbines is used as a surrogate for distillate oil-fired engines due to lack of specific emission factors for distill ate oilfired engines. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, all PM is assumed to be < 1 μ m. Therefore, it is assumed PM 2.5 = PM 10 = PM. Data from engine specification sheet provided by Ms. Sara Carlson (Anadarko) via email to Mr. Raghu Soule (Trinity) Water blasting will occur for 12 hours a day and 2,496 hrs/yr. This information is provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on May 30, 2013. Operating Load is assumed to be 100% to represent the worst case operating conditions. Per NSPS IIII, the Water Blasting Engine is required to use ULSD beginning June 1, 2010. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppmw in diesel fuel assuming that 98 wt.% of sulfur in the fuel is oxidized to SO 2 and 2 wt.% of sulfur in the fuel is oxidized to H 2 SO 4 based on Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Based on Engine Specification sheet for Deutz BF6M2012C , this engine is non-road Tier 3, 40 CFR 89.112.

Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used. All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission 

## Anadarko Petroleum Corporation Emission Calculations

Deutz BF6M2012C (Water Blasting Engine) EPN: DR-WB-01 Criteria Pollutants and Sulfuric Acid

Pollutant Emission Factor Basis Emission Factor

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 21 of 40 Water Blasting Engine- Criteria Date Printed - 6/26/2013

### Engine Rating [1] = 155 kW 208 HP Operating Time [2] = 12 hrs/day 2496 hrs/year Fuel Type [6] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) tpy Acetaldehyde AP-42 [3],[5] 7.67E-04 lb/MMBtu 1.12E-03 1.34E-02 1.39E-03

Acrolein AP-42 [3],[5] 9.25E-05 lb/MMBtu 1.35E-04 1.62E-03 1.68E-04 Benzene AP-42 [3],[5] 9.33E-04 lb/MMBtu 1.36E-03 1.63E-02 1.70E-03 Formaldehyde AP-42 [3],[5] 1.18E-03 lb/MMBtu 1.72E-03 2.06E-02 2.14E-03 Toluene AP-42 [3],[5] 4.09E-04 lb/MMBtu 5.96E-04 7.15E-03 7.43E-04 Xylenes AP-42 [3],[5] 2.85E-04 lb/MMBtu 4.15E-04 4.98E-03 5.18E-04 1,3-Butadiene AP-42 [3],[5] 3.91E-05 lb/MMBtu 5.69E-05 6.83E-04 7.10E-05

Total PAH AP-42 [3],[5] 1.68E-04 lb/MMBtu 2.45E-04 2.94E-03 3.05E-04 Naphthalene AP-42 [3],[5] 8.48E-05 lb/MMBtu 1.23E-04 1.48E-03 1.54E-04 Total VOC HAPs 5.64E-03 6.77E-02 7.04E-03

[1]

[2]

[3]

[5] [6] Data from engine specification sheet provided by Ms. Sara Carlson (Anadarko) via email to Mr. Raghu Soule (Trinity) 11/27/12. Water blasting will occur for 12 hours a day and 2,496 hrs/yr. This information is provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on May 30, 2013. Operating Load is assumed to be 100% to represent the worst case operating conditions. Emission factors based on AP-42, Chapter 3, Table 3.3-2, Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions. Per NSPS IIII, the Water Blasting Engine is required to use ULSD beginning June 1, 2010 

## Anadarko Petroleum Corporation Emission Calculations

Deutz BF6M2012C (Water Blasting Engine) EPN: DR-WB-01 Hazardous Air Pollutants

Pollutant Emission Factor Basis Emission Factor

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 22 of 40 Water Blasting Engine - HAP Date Printed - 6/26/2013

### Engine Rating [1],[4] = 155 kW 208 HP Operating Time [2] = 12 hrs/day 2496 hrs/year Fuel Type [7] = ULSD CO 2 

### 1 Operating load [2] = 100% CH 4 

### 21
N 2 

### O 310

Average Emissions [5] Average Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) tpy

CO 2 

### 40 CFR 98 Subpart C [3] 7.40E+01 kg/MMBtu 237.41 2848.87 296.28

CH 4 

### 40 CFR 98 Subpart C [4] 3.00E-03 kg/MMBtu 9.63E-03 1.16E-01 1.20E-02

N 2 

### O 40 CFR 98 Subpart C [4] 6.00E-04 kg/MMBtu 1.93E-03 2.31E-02 2.40E-03

CO 2 

### e 40 CFR 98 Subpart C [6] -- -- 238.21 2858.47 297.28

[1]

[2]

[3]

[4]

[5] [6]

[7] Per NSPS IIII, the Water Blasting Engine is required to use ULSD beginning June 1, 2010 Global warming potentials (GWP) for CH 4 

### , CO 2 

### and N 2 

### O are used to calculate CO 2 

### equivalent (CO 2 

### e). The GWPs are obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time 

## Anadarko Petroleum Corporation Emission Calculations

Deutz BF6M2012C (Water Blasting Engine) EPN: DR-WB-01 Greenhouse Gases

Chemicals Global Warming Potential ( 100 y r. )

Pollutant Emission Factor Basis Emission Factor

Data from engine specification sheet provided by Ms. Sara Carlson (Anadarko) via email to Mr. Raghu Soule (Trinity) 11/27/12. Water blasting will occur for 12 hours a day and 2,496 hrs/yr. This information is provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on May 30, 2013. Operating Load is assumed to be 100% to represent the worst case operating conditions. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate i i Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 23 of 40 Water Blasting Engine - GHG Date Printed - 6/26/2013

### Engine Rating [1],[4] = 104 kW 140 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [3] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.31 7.39 0.02
PM 10 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.31 7.39 0.02
PM 2.5 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.31 7.39 0.02
NO x 

### Engine Specs [8] 1.55E+03 g/hr 3.42 82.01 0.21
SO 2 

### Fuel S Content [3] 1.12E-05 lb/HP-hr 1.57E-03 3.77E-02 9.81E-05 CO Engine Specs [8] 1.03E+03 g/hr 2.27 54.50 0.14 VOC Engine Specs [8] 6.00E+01 g/hr 0.13 3.17 0.01

Pb EPA [7] 2.03E-07 lb/HP-hr 2.84E-05 6.82E-04 1.78E-06 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/HP-hr 4.91E-05 1.18E-03 3.07E-06

[1]

[2]

[3]

[4] [5]

[6]

[7]

[8] 

## Anadarko Petroleum Corporation Emission Calculations

Drillship and Supply Boat Well Evaluation Engines

DR-VS-01 to DR-VS-05, SB-VS-01 to SB-VS-05 Criteria Pollutants

Pollutant Emission Factor Basis Emission Factor

Lead emission factor was obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines was used as a surrogate for distillate oil-fired engines due to lack of emission factors. Anaverage brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hphr. Emission rates for CO, NOx, and VOC are based on engine spec sheet provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013. Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Note that the well evaluation engines will be subjected to the 17,500 gal of diesel per day cap of all engines if located on supply boats.

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Engine generator efficiency is assumed to be 100% to represent the worst case scenario. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Per footnote b of Table 3.3-1, all PM is assumed to be < 1 um, therefore, assumed PM 2.5 

### = PM 10 

### = PM. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 24 of 40 Detroit 4-71 - Criteria Date Printed - 6/26/2013

### Engine Rating [1] = 104 kW 140 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [5] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [3],[4] 7.67E-04 lb/MMBtu 7.52E-04 1.80E-02 4.70E-05

Acrolein AP-42 [3],[4] 9.25E-05 lb/MMBtu 9.07E-05 2.18E-03 5.67E-06 Benzene AP-42 [3],[4] 9.33E-04 lb/MMBtu 9.14E-04 2.19E-02 5.71E-05 Formaldehyde AP-42 [3],[4] 1.18E-03 lb/MMBtu 1.16E-03 2.78E-02 7.23E-05 Toluene AP-42 [3],[4] 4.09E-04 lb/MMBtu 4.01E-04 9.62E-03 2.51E-05 Xylenes AP-42 [3],[4] 2.85E-04 lb/MMBtu 2.79E-04 6.70E-03 1.75E-05 Total PAH AP-42 [3],[4] 1.68E-04 lb/MMBtu 1.65E-04 3.95E-03 1.03E-05 1,3-Butadiene AP-42 [3],[4] 3.91E-05 lb/MMBtu 3.83E-05 9.20E-04 2.39E-06 Naphthalene AP-42 [3],[4] 8.48E-05 lb/MMBtu 8.31E-05 1.99E-03 5.19E-06 Total VOC HAPs 3.80E-03 9.11E-02 2.37E-04

[1]

[2]

[3]

[4]

[5] 

## Anadarko Petroleum Corporation Emission Calculations

Drillship and Supply Boat Well Evaluation Engines

DR-VS-01 to DR-VS-05, SB-VS-01 to SB-VS-05 Hazardous Air Pollutants (HAPs)

Pollutant Emission Factor Basis Emission Factor

Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013.

Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Note that the well evaluation engines will be subjected to the 17,500 gal of diesel per day cap of all engines if located on supply boats. Emission factors based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 25 of 40 Detroit 4-71 - HAP Date Printed - 6/26/2013

### Engine Rating [1] = 104 kW 140 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [7] = ULSD Operating load [2] = 100%

Average Emissions [5] Average Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) CO 2 

### EPA [3] 7.40E+01 kg/MMBtu 160 3,835 10
CH 4 

### EPA [4] 3.00E-03 kg/MMBtu 6.48E-03 1.56E-01 4.05E-04
N 2 

### O EPA [4] 6.00E-04 kg/MMBtu 1.30E-03 3.11E-02 8.10E-05 CO 2 

### e EPA [6] -- -- 160 3,848 10

[1]

[2]

[3]

[4]

[5]

[6]

[7] 

## Anadarko Petroleum Corporation Emission Calculations

Drillship and Supply Boat Well Evaluation Engines

DR-VS-01 to DR-VS-05, SB-VS-01 to SB-VS-05 Greenhouse Gases (GHGs)

Pollutant Emission Factor Basis Emission Factor

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013.

Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Note that the well evaluation engines will be subjected to the 17,500 gal of diesel per day cap of all engines if located on supply boats. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate emissions. Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate emissions. An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

CH 4 

### , CO 2 

### and N 2 

### O are included in the emissions of CO 2 

### equivalent (CO 2 

### e), weighted according to their global warming potential (GWP). The GWP was obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon).

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 26 of 40 Detroit 4-71 - GHG Date Printed - 6/26/2013

### Engine Rating [1],[4] = 268 kW 360 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [3] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.79 19.01 0.05
PM 10 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.79 19.01 0.05
PM 2.5 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.79 19.01 0.05
NO x 

### AP-42 [6] 3.10E-02 lb/HP-hr 11.16 267.84 0.70
SO 2 

### Fuel S Content [3] 1.12E-05 lb/HP-hr 4.04E-03 9.69E-02 2.52E-04 CO AP-42 [6] 6.68E-03 lb/HP-hr 2.40 57.72 0.15 VOC AP-42 [6],[8] 2.51E-03 lb/HP-hr 0.90 21.70 0.06

Pb EPA [7] 2.03E-07 lb/HP-hr 7.31E-05 1.75E-03 4.57E-06 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/HP-hr 1.26E-04 3.03E-03 7.88E-06

[1]

[2] [3]

[4]
[5]

[6]

[7]

[8] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine SB-VS-06 and SB-VS-07 Criteria Pollutants

Pollutant Emission Factor Basis Emission Factor

Lead emission factor was obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines was used as a surrogate for distillate oil-fired engines due to lack of emission factors. Anaverage brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hphr.
All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Engine generator efficiency is assumed to be 100% to represent the worst case scenario. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Per footnote b of Table 3.3-1, all PM is assumed to be < 1 um, therefore, assumed PM 2.5 

### = PM 10 

### = PM. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 27 of 40 Cat 3406C - Criteria Date Printed - 6/26/2013

### Engine Rating [1] = 268 kW 360 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [5] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [3],[4] 7.67E-04 lb/MMBtu 1.93E-03 4.64E-02 1.21E-04

Acrolein AP-42 [3],[4] 9.25E-05 lb/MMBtu 2.33E-04 5.59E-03 1.46E-05 Benzene AP-42 [3],[4] 9.33E-04 lb/MMBtu 2.35E-03 5.64E-02 1.47E-04 Formaldehyde AP-42 [3],[4] 1.18E-03 lb/MMBtu 2.97E-03 7.14E-02 1.86E-04 Toluene AP-42 [3],[4] 4.09E-04 lb/MMBtu 1.03E-03 2.47E-02 6.44E-05 Xylenes AP-42 [3],[4] 2.85E-04 lb/MMBtu 7.18E-04 1.72E-02 4.49E-05 Total PAH AP-42 [3],[4] 1.68E-04 lb/MMBtu 4.23E-04 1.02E-02 2.65E-05 1,3-Butadiene AP-42 [3],[4] 3.91E-05 lb/MMBtu 9.85E-05 2.36E-03 6.16E-06 Naphthalene AP-42 [3],[4] 8.48E-05 lb/MMBtu 2.14E-04 5.13E-03 1.34E-05 Total VOC HAPs 9.76E-03 2.34E-01 6.10E-04

[1]

[2] [3]

[4]

[5] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine SB-VS-06 and SB-VS-07 Hazardous Air Pollutants (HAPs)

Pollutant Emission Factor Basis Emission Factor

Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013.

Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factors based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 28 of 40 Cat 3406C - HAP Date Printed - 6/26/2013

### Engine Rating [1] = 268 kW 360 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [7] = ULSD Operating load [2] = 100%

Average Emissions [5] Average Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) CO 2 

### EPA [3] 7.40E+01 kg/MMBtu 411 9,861 26
CH 4 

### EPA [4] 3.00E-03 kg/MMBtu 1.67E-02 4.00E-01 1.04E-03
N 2 

### O EPA [4] 6.00E-04 kg/MMBtu 3.33E-03 8.00E-02 2.08E-04 CO 2 

### e EPA [6] -- -- 412 9,895 26

[1]

[2] [3]

[4]

[5]

[6]

[7] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine SB-VS-06 and SB-VS-07 Greenhouse Gases (GHGs)

Pollutant Emission Factor Basis Emission Factor

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Representative standard capacity compressor to be used for well evaluation activities. Engine specification provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on May 22, 2013.

Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate emissions. Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate emissions. An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

CH 4 

### , CO 2 

### and N 2 

### O are included in the emissions of CO 2 

### equivalent (CO 2 

### e), weighted according to their global warming potential (GWP). The GWP was obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon).

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 29 of 40 Cat 3406C - GHG Date Printed - 6/26/2013

### Engine Rating [1],[4] = 46 kW 62 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [3] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.14 3.27 0.01
PM 10 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.14 3.27 0.01
PM 2.5 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.14 3.27 0.01
NO x 

### AP-42 [6] 3.10E-02 lb/HP-hr 1.92 46.13 0.12
SO 2 

### Fuel S Content [3] 1.12E-05 lb/HP-hr 6.95E-04 1.67E-02 4.35E-05 CO AP-42 [6] 6.68E-03 lb/HP-hr 0.41 9.94 0.03 VOC AP-42 [6],[8] 2.51E-03 lb/HP-hr 0.16 3.74 0.01

Pb EPA [7] 2.03E-07 lb/HP-hr 1.26E-05 3.02E-04 7.87E-07 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/HP-hr 2.17E-05 5.21E-04 1.36E-06

[1]

[2] [3]

[4]
[5]

[6]

[7]

[8] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Small SB-VS-08 Criteria Pollutants

Pollutant Emission Factor Basis Emission Factor

Lead emission factor was obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines was used as a surrogate for distillate oil-fired engines due to lack of emission factors. Anaverage brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hphr.
All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Engine generator efficiency is assumed to be 100% to represent the worst case scenario. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Per footnote b of Table 3.3-1, all PM is assumed to be < 1 um, therefore, assumed PM 2.5 

### = PM 10 

### = PM. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 30 of 40 EngCrane 62 - Criteria Date Printed - 6/26/2013

### Engine Rating [1] = 46 kW 62 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [5] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [3],[4] 7.67E-04 lb/MMBtu 3.33E-04 7.99E-03 2.08E-05

Acrolein AP-42 [3],[4] 9.25E-05 lb/MMBtu 4.01E-05 9.63E-04 2.51E-06 Benzene AP-42 [3],[4] 9.33E-04 lb/MMBtu 4.05E-04 9.72E-03 2.53E-05 Formaldehyde AP-42 [3],[4] 1.18E-03 lb/MMBtu 5.12E-04 1.23E-02 3.20E-05 Toluene AP-42 [3],[4] 4.09E-04 lb/MMBtu 1.78E-04 4.26E-03 1.11E-05 Xylenes AP-42 [3],[4] 2.85E-04 lb/MMBtu 1.24E-04 2.97E-03 7.73E-06 Total PAH AP-42 [3],[4] 1.68E-04 lb/MMBtu 7.29E-05 1.75E-03 4.56E-06 1,3-Butadiene AP-42 [3],[4] 3.91E-05 lb/MMBtu 1.70E-05 4.07E-04 1.06E-06 Naphthalene AP-42 [3],[4] 8.48E-05 lb/MMBtu 3.68E-05 8.83E-04 2.30E-06 Total VOC HAPs 1.68E-03 4.03E-02 1.05E-04

[1]

[2] [3]

[4]

[5] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Small SB-VS-08 Hazardous Air Pollutants (HAPs)

Pollutant Emission Factor Basis Emission Factor

Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factors based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 31 of 40 EngCrane 62 - HAP Date Printed - 6/26/2013

### Engine Rating [1] = 46 kW 62 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [7] = ULSD Operating load [2] = 100%

Average Emissions [5] Average Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) CO 2 

### EPA [3] 7.40E+01 kg/MMBtu 71 1,698 4
CH 4 

### EPA [4] 3.00E-03 kg/MMBtu 2.87E-03 6.89E-02 1.79E-04
N 2 

### O EPA [4] 6.00E-04 kg/MMBtu 5.74E-04 1.38E-02 3.59E-05 CO 2 

### e EPA [6] -- -- 71 1,704 4

[1]

[2] [3]

[4]

[5]

[6]

[7] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Small SB-VS-08 Greenhouse Gases (GHGs)

Pollutant Emission Factor Basis Emission Factor

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate emissions. Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate emissions. An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

CH 4 

### , CO 2 

### and N 2 

### O are included in the emissions of CO 2 

### equivalent (CO 2 

### e), weighted according to their global warming potential (GWP). The GWP was obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon).

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 32 of 40 EngCrane 62 - GHG Date Printed - 6/26/2013

### Engine Rating [1],[4] = 97 kW 130 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [3] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) PM AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.29 6.86 0.02
PM 10 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.29 6.86 0.02
PM 2.5 

### AP-42 [6],[5] 2.20E-03 lb/HP-hr 0.29 6.86 0.02
NO x 

### AP-42 [6] 3.10E-02 lb/HP-hr 4.03 96.72 0.25
SO 2 

### Fuel S Content [3] 1.12E-05 lb/HP-hr 1.46E-03 3.50E-02 9.11E-05 CO AP-42 [6] 6.68E-03 lb/HP-hr 0.87 20.84 0.05 VOC AP-42 [6],[8] 2.51E-03 lb/HP-hr 0.33 7.84 0.02

Pb EPA [7] 2.03E-07 lb/HP-hr 2.64E-05 6.33E-04 1.65E-06 H 2 

### SO 4 

### Fuel S Content [3] 3.50E-07 lb/HP-hr 4.55E-05 1.09E-03 2.85E-06

[1]

[2] [3]

[4]
[5]

[6]

[7]

[8] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Large SB-VS-09 Criteria Pollutants

Pollutant Emission Factor Basis Emission Factor

Lead emission factor was obtained from EPA guidance document: Locating and Estimating Air Emissions from Sources of Lead and Lead Compounds, EPA 454/R-98-006, May 1998, Section 5.2.2. Emission factor for distillate oil-fired gas turbines was used as a surrogate for distillate oil-fired engines due to lack of emission factors. Anaverage brake-specific fuel consumption (BSFC) of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hphr.
All TOC is assumed to be VOC. TOC emission factor has been calculated as the sum of exhaust and crankcase emission factors. Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Therefore, emissions have been calculated based on a maximum sulfur content of 15 ppm in diesel fuel assuming that 98 percent of sulfur in the fuel is oxidized to SO 2 

### and 2 percent of sulfur in the fuel is oxidized to H 2 

### SO 4 

### based on Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines, EPA420-R-03-008, April 2003. Engine generator efficiency is assumed to be 100% to represent the worst case scenario. Based on footnote b of AP-42 Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Per footnote b of Table 3.3-1, all PM is assumed to be < 1 um, therefore, assumed PM 2.5 

### = PM 10 

### = PM. Emission factors are based on AP-42, Chapter 3, Table 3.3-1, Emission Factors for Uncontrolled Gasoline and Diesel Industrial Engines (October 1996). Emission factors for diesel fuel are used.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 33 of 40 EngCrane 130 - Criteria Date Printed - 6/26/2013

### Engine Rating [1] = 97 kW 130 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [5] = ULSD Operating load [2] = 100%

Maximum Emissions Maximum Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) Acetaldehyde AP-42 [3],[4] 7.67E-04 lb/MMBtu 6.98E-04 1.68E-02 4.36E-05

Acrolein AP-42 [3],[4] 9.25E-05 lb/MMBtu 8.42E-05 2.02E-03 5.26E-06 Benzene AP-42 [3],[4] 9.33E-04 lb/MMBtu 8.49E-04 2.04E-02 5.31E-05 Formaldehyde AP-42 [3],[4] 1.18E-03 lb/MMBtu 1.07E-03 2.58E-02 6.71E-05 Toluene AP-42 [3],[4] 4.09E-04 lb/MMBtu 3.72E-04 8.93E-03 2.33E-05 Xylenes AP-42 [3],[4] 2.85E-04 lb/MMBtu 2.59E-04 6.22E-03 1.62E-05 Total PAH AP-42 [3],[4] 1.68E-04 lb/MMBtu 1.53E-04 3.67E-03 9.56E-06 1,3-Butadiene AP-42 [3],[4] 3.91E-05 lb/MMBtu 3.56E-05 8.54E-04 2.22E-06 Naphthalene AP-42 [3],[4] 8.48E-05 lb/MMBtu 7.72E-05 1.85E-03 4.82E-06 Total VOC HAPs 3.52E-03 8.46E-02 2.20E-04

[1]

[2] [3]

[4]

[5] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Large SB-VS-09 Hazardous Air Pollutants (HAPs)

Pollutant Emission Factor Basis Emission Factor

Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factors based on AP-42, Chapter 3, Table 3.3-2 Speciated Organic Compound Emission Factors for Uncontrolled Diesel Engines (October 1996). An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources.

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 34 of 40 EngCrane 130 - HAP Date Printed - 6/26/2013

### Engine Rating [1] = 97 kW 130 HP Operating Time [2] = 24 hrs/day [2] 125 hrs/yr Fuel Type [7] = ULSD Operating load [2] = 100%

Average Emissions [5] Average Daily Emissions Annual Emissions Value Units (lb/hr) (lb/day) (tons/yr) CO 2 

### EPA [3] 7.40E+01 kg/MMBtu 148 3,561 9
CH 4 

### EPA [4] 3.00E-03 kg/MMBtu 6.02E-03 1.44E-01 3.76E-04
N 2 

### O EPA [4] 6.00E-04 kg/MMBtu 1.20E-03 2.89E-02 7.52E-05 CO 2 

### e EPA [6] -- -- 149 3,573 9

[1]

[2] [3]

[4]

[5]

[6]

[7] 

## Anadarko Petroleum Corporation Emission Calculations

Supply Boat Well Evaluation Engine Crane - Large SB-VS-09 Greenhouse Gases (GHGs)

Pollutant Emission Factor Basis Emission Factor

Anadarko is proposing the use of Ultra Low Sulfur Diesel (ULSD) for all diesel combustion sources. Representative engine crane to be used for VSP activities. Information provided by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) via email on April 18, 2013. Assumptions: Max operating time of 24 hr/day, 100% Operating Load, and 125 hrs/yr. Emission factor based on 40 CFR 98 Subpart C, Table C-1 Default CO 2 

### Emission Factors and High Heat Values for Various Types of Fuel. The emission factor for Distillate Fuel Oil No. 2 was used to calculate emissions. Emission factors based on 40 CFR 98 Subpart C, Table C-2 Default CH 4 

### and N 2 

### O Emission Factors for Various Types of Fuel. The emission factor for petroleum (All types in table C-1) was used to calculate emissions. An average BSFC of 7,000 Btu/hp-hr was used to convert from lb/MMBtu to lb/hp-hr to calculate emissions.

CH 4 

### , CO 2 

### and N 2 

### O are included in the emissions of CO 2 

### equivalent (CO 2 

### e), weighted according to their global warming potential (GWP). The GWP was obtained from 40 CFR 98, Subpart A, Table A-1 Global Warming Potentials (100-year Time Horizon).

A nadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 35 of 40 EngCrane 130 - GHG Date Printed - 6/26/2013Operating Data:Operating Hours 4992 hrs/yr208 days/year24 hrs/dayWelding Rod Consumption [1]: 50 lbs/dayTypes of Welding Rod Amount (lbs)E308, E310, E316, E6010,E6011, E7018, E7028, orequivalent10,400Emission Factors[4]E308, E310, E316, E6010,E6011, E7018, E7028, orequivalentPM10AP-42 [2],[5] 38.4lb/ 103lb8.00E-02 1.92E+00 399.36 2.00E-01Cr AP-42 [3] 25.310-1lb/ 103lb5.27E-03 1.27E-01 26.312 1.32E-02Cr(VI) AP-42 [3] 18.810-1lb/ 103lb3.92E-03 9.40E-02 19.552 9.78E-03Co AP-42 [3] 0.0110-1lb/ 103lb2.08E-06 5.00E-05 0.0104 5.20E-06Mn AP-42 [3] 22.010-1lb/ 103lb4.58E-03 1.10E-01 22.88 1.14E-02Ni AP-42 [3] 1.9610-1lb/ 103lb4.08E-04 9.80E-03 2.0384 1.02E-03Pb AP-42 [3] 1.6210-1lb/ 103lb3.38E-04 8.10E-03 1.6848 8.42E-04[1] Data provided by Sara Carlson (Anadarko) to Rahul Pendse (Trinity) via phone on February 25, 2013.[2] Emission factors based on AP-42 Chapter 12 Section 12.19 Electric Arc Welding (1/95),Table 12.19-1 - PM-10 EMISSION FACTORS FOR WELDING OPERATIONS, for SMAW, page 12.19-4.[3] Emission factors based on AP-42 Chapter 12 Section 12.19 Electric Arc Welding (1/95),Table 12.19-2 - HAP EMISSION FACTORS FOR WELDING OPERATIONS, for SMAW, page 12.19-6.HAP Emission factors represent the worst case emission factor for each pollutant available in the Tables referenced above.[4] Worst case emission factor is used for each pollutant among the emission factors availablefor the proposed types of welding rods to be used for conducting the welding operations.[5] PM10emissions are conservatively assumed equal to PM2.5and total PM emissions (i.e., PM = PM10= PM2.5)AnnualEmissions(tpy)Anadarko Petroleum CorporationEmission CalculationsWelding OperationsEPN: DR-WO-01PollutantEmission FactorBasisUnitMaximumEmissions(lb/hr)Max. DailyEmissions(lb/day)AnnualEmissions(lb/yr)Anadarko Petroleum CorporationEGOM Exploratory Project - Discoverer Spirit36 of 40WeldingDate Printed - 6/26/2013Operating Data [1] Average Thinner Usage = 24 gallons/week = 1 gallons/hour Average Primer Usage = 57 gallons/week = 1 gallons/hour Air Assisted Spray Transfer Efficiency 4 = 50%
Fall out Factor 5 = 98.56% Operating Hours = 12 hrs/day = 208 days/year

VOC PTE Calculations- Paint Coatings, and Thinners

Product Code Name 1 Product Description Code 1 New or Existing Paint Density 1 (lb/gal) VOC
Content 1 (wt %) Maximum Daily Usage 2

(gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy) Jotun Thinner No. 26 Thinner MM00000557 Existing 7.34 88% 10 1049 65.13 3.39 Jotun Thinner No. 17 Thinner MM00000553 Existing 7.18 40% 10 1049 28.96 1.51 Jotun Thinner No. 7 Thinner MM00000561 Existing 7.26 100% 10 1049 73.21 3.81
Amercoat 10 - Thinner Thinner AT10/05 New 7.01 100.0% 10 1049 70.69 3.68
Amercoat 65 - Thinner Thinner AT765/05 New 7.26 100.0% 10 1049 73.21 3.81 Worst Emitting Thinner Thinner AT765/05 New 7.26 100.0% 10 1049 73.21 3.81 Hardtop Flexi - Comp A Primer MM00001531 Existing 9.76 30.8% 19 2014 58.28 3.03 Hardtop Flexi - Comp B Primer MM00001533 Existing 9.01 24.8% 5 503 10.82 0.56 Jotacote Universal - Comp A Primer MM00000478 Existing 12.18 16.3% 18 1888 36.04 1.87 Jotacote Universal - Comp B Primer MM00000479 Existing 8.01 33.6% 6 629 16.28 0.85

Barrier AV - Comp A Primer MM00001131 Existing 18.36 14.7% 19 2014 52.25 2.72 Barrier AV - Comp B Primer MM00001132 Existing 12.52 24.5% 5 503 14.85 0.77 Dimetcote 9 - Liquid Base DI9-A/05 New 8.51 60.7% 19 2014 99.93 5.20
Dimetcote 9 - Powder Hardener DI9-P New 59.50 0.0% 5 503 0.00 0.00
Amercoat 450H - Yellow Base AT45H813 New 10.18 23.3% 19 2014 45.90 2.39 Amercoat 450H - Gray Base AT45H251 New 10.85 22.1% 19 2014 46.36 2.41
Amercoat 450H - Cure Hardener AT45H-B New 8.68 38.4% 5 503 16.14 0.84 Amercoat 240 - Gray Base AT45H20 New 10.85 22.1% 19 2014 46.36 2.41
Amercoat 240 - Cure Hardener AT240-B New 8.10 9.1% 5 503 3.57 0.19 Amercoat 235 - Buff Base JDAT235-1(F1) New 11.85 20.3% 19 2014 46.60 2.42
Amercoat 235 - Cure Hardener AT235-B/55 New 8.01 35.0% 5 503 13.57 0.71
Base DI9-A/05 New 8.51 60.7% 19 2014 99.93 5.20
Hardener DI9-P New 59.5 0.0% 5 503 0.00 0.00
Worst Case VOC 173.14 9.00

PM/PM 10 /PM 2.5 Emissions from Coatings Applied via Spray Gun

Product Product Description Application Method New or Existing Paint Densit y Based on Mixing Ratio (lb/gal) Solids
Content 3

(%) Maximum Daily Usage 2

(gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy) Hardtop Flexi - Comp A Primer spray gun Existing 9.76 66.0% 19 2014 0.90 0.05 Hardtop Flexi - Comp B Primer spray gun Existing 9.01 66.0% 5 503 0.21 0.01 Jotacote Universal - Comp A Primer spray gun Existing 12.18 74.0% 18 1888 1.18 0.06 Jotacote Universal - Comp B Primer spray gun Existing 8.01 74.0% 6 629 0.26 0.01

Barrier AV - Comp A Primer spray gun Existing 18.36 62.0% 19 2014 1.59 0.08 Barrier AV - Comp B Primer spray gun Existing 12.52 62.0% 5 503 0.27 0.01 Dimetcote 9 - Liquid Base spray gun New 8.51 39.4% 19 2014 0.47 0.02 Dimetcote 9 - Powder Hardener spray gun New 59.50 100.0% 5 503 2.07 0.11 Amercoat 450H - Yellow Base spray gun New 10.18 76.7% 19 2014 1.09 0.06 Amercoat 450H - Gray Base spray gun New 10.85 77.9% 19 2014 1.18 0.06 Amercoat 450H - Cure Hardener spray gun New 8.68 61.6% 5 503 0.19 0.01 Amercoat 240 - Gray Base spray gun New 10.85 77.9% 19 2014 1.18 0.06 Amercoat 240 - Cure Hardener spray gun New 8.10 90.9% 5 503 0.26 0.01 Amercoat 235 - Buff Base spray gun New 11.85 79.7% 19 2014 1.32 0.07 Amercoat 235 - Cure Hardener spray gun New 8.01 65.0% 5 503 0.18 0.01 Base spray gun New 8.51 39.4% 19 2014 0.47 0.02 Hardener spray gun New 59.50 100.0% 5 503 2.07 0.11 Worst Case PM/PM 10 /PM 2.5 2.54 0.13

[1] [2]

[3] Solids content obtained from technical data sheets obtained from Jotun Paints, Inc website. [4] Air assited spray transfer efficiency obtained from Coating Operations Instruction for Emission Calculation Spreadsheet - Mi nnesoata Pollution Control Agency. [5] Fax Transmittal Correspondence from Ms. Alyssa Aston (TCEQ) to Mr. Glen Muenchow (Aggregate Plant Production Company) regard ing Permit Number: 48092. Anadarko Petroleum Corporation Emission Calculations

Painting Operations (Aternate Operating Scenario) EPN: DR-PO-01 Criteria Pollutants

Data provided in emails by Ms. Sara Carlson (Anadarko) on 11/28/2012, and 6/24/2013.
Maximum daily usage determined based on phone conversation between Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 12/03/2012. Primer usage is based on the mixing ratio provided in the technical data sheet. Worst Emitting Paint

Worst Emitting Paint

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 37 of 40 Painting Emissions - Criteria Date Printed - 6/26/2013Operating Data [1] Average Thinner Usage = 25 gallons/week = 1 gallons/hour Average Primer Usage = 60 gallons/week = 1 gallons/hour Air Assisted Spray Transfer Efficiency 4 = 30%
Fall out Factor 5 = 98.56% Operating Hours = 12 hrs/day = 208 days/year

VOC PTE Calculations- Paint Coatings, and Thinners

Product Code Name 1 Product Description Code 1 New or Existing Paint Density 1 (lb/gal) VOC
Content 1 (wt %) Maximum Daily Usage 2

(gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy)
Jotun Thinner No. 26 Thinne r MM00000557 Existing 7.34 88% 7 743 46.14 2.40 Jotun Thinner No. 17 Thinne r MM00000553 Existing 7.18 40% 7 743 20.51 1.07 Jotun Thinner No. 7 Thinne r MM00000561 Existing 7.26 100% 7 743 51.86 2.70 Amercoat 10 - Thinner Thinner AT10/05 New 7.01 100.0% 7 743 50.07 2.60
Amercoat 65 - Thinner Thinner AT765/05 New 7.26 100.0% 7 743 51.86 2.70 Worst Emitting Thinner Thinner AT765/05 New 7.26 100.0% 7 743 51.86 2.70 Hardtop Flexi - Comp A Prime r MM00001531 Existing 9.76 30.8% 14 1426 41.28 2.15 Hardtop Flexi - Comp B Prime r MM00001533 Existing 9.01 24.8% 3 357 7.66 0.40 Jotacote Universal - Comp A Prime r MM00000478 Existing 12.18 16.3% 13 1337 25.53 1.33 Jotacote Universal - Comp B Prime r MM00000479 Existing 8.01 33.6% 4 446 11.53 0.60

Barrier AV - Comp A Prime r MM00001131 Existing 18.36 14.7% 14 1426 37.01 1.92 Barrier AV - Comp B Prime r MM00001132 Existing 12.52 24.5% 3 357 10.52 0.55 Dimetcote 9 - Liquid Base DI9-A/05 New 8.51 60.7% 14 1426 70.78 3.68
Dimetcote 9 - Powder Hardener DI9-P New 59.50 0.0% 3 357 0.00 0.00
Amercoat 450H - Yellow Base AT45H813 New 10.18 23.3% 14 1426 32.52 1.69 Amercoat 450H - Gray Base AT45H251 New 10.85 22.1% 14 1426 32.84 1.71
Amercoat 450H - Cure Hardener AT45H-B New 8.68 38.4% 3 357 11.43 0.59 Amercoat 240 - Gray Base AT45H20 New 10.85 22.1% 14 1426 32.84 1.71
Amercoat 240 - Cure Hardener AT240-B New 8.10 9.1% 3 357 2.53 0.13 Amercoat 235 - Buff Base JDAT235-1(F1) New 11.85 20.3% 14 1426 33.01 1.72
Amercoat 235 - Cure Hardener AT235-B/55 New 8.01 35.0% 3 357 9.61 0.50
Base DI9-A/05 New 8.51 60.7% 14 1426 70.78 3.68
Hardener DI9-P New 59.5 0.0% 3 357 0.00 0.00
Worst Case VOC 122.64 6.38

PM/PM 10 /PM 2.5 Emissions from Coatings Applied via Spray Gun

Product Product Description Application Method New or Existing Paint Density Based on Mixing Ratio

(lb/gal) Solids
Content 3

(%) Maximum Daily Usage 2

(gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy) Hardtop Flexi - Comp A Primer spray gun Existing 9.76 66.0% 14 1426 0.89 0.05 Hardtop Flexi - Comp B Primer spray gun Existing 9.01 66.0% 3 357 0.21 0.01 Jotacote Universal - Comp A Primer spray gun Existing 12.18 74.0% 13 1337 1.17 0.06 Jotacote Universal - Comp B Primer spray gun Existing 8.01 74.0% 4 446 0.26 0.01

Barrier AV - Comp A Primer spray gun Existing 18.36 62.0% 14 1426 1.57 0.08 Barrier AV - Comp B Primer spray gun Existing 12.52 62.0% 3 357 0.27 0.01 Dimetcote 9 - Liquid Base spray gun New 8.51 39.4% 14 1426 0.46 0.02 Dimetcote 9 - Powder Hardener spray gun New 59.50 100.0% 3 357 2.06 0.11 Amercoat 450H - Yellow Base spray gun New 10.18 76.7% 14 1426 1.08 0.06 Amercoat 450H - Gray Base spray gun New 10.85 77.9% 14 1426 1.17 0.06 Amercoat 450H - Cure Hardener spray gun New 8.68 61.6% 3 357 0.18 0.01 Amercoat 240 - Gray Base spray gun New 10.85 77.9% 14 1426 1.17 0.06 Amercoat 240 - Cure Hardener spray gun New 8.10 90.9% 3 357 0.25 0.01 Amercoat 235 - Buff Base spray gun New 11.85 79.7% 14 1426 1.31 0.07 Amercoat 235 - Cure Hardener spray gun New 8.01 65.0% 3 357 0.18 0.01 Base spray gun New 8.51 39.4% 14 1426 0.46 0.02 Hardener spray gun New 59.5 100.0% 3 357 2.06 0.11
Worst Case PM/PM 10 /PM 2.5 2.52 0.13

[1] [2]

[3] Solids content obtained from technical data sheets obtained from Jotun Paints, Inc website. [4] Air assited spray transfer efficiency obtained from Coating Operations Instruction for Emission Calculation Spreadsheet - Mi nnesoata Pollution Control Agency. [5] Fax Transmittal Correspondence from Ms. Alyssa Aston (TCEQ) to Mr. Glen Muenchow (Aggregate Plant Production Company) regard ing Permit Number: 48092. [6] Total emissions based on the sum of the worst-case primer (Hardtop Flexi) and thinner (Jotun Thinner No.7) components. [7] Total emissions based on the worst-case primer (Barrier AV) components. Anadarko Petroleum Corporation Emission Calculations

Painting Operations EPN: DR-PO-01 (ALT)

Criteria Pollutants

Data provided in an email by Ms. Sara Carlson (Anadarko) on 11/28/2012. Maximum daily usage determined based on phone conversation between Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 12/03/2012. Primer usage is based on the mixing ratio provided in the technical data sheet. Worst Emitting Paint

Worst Emitting Paint

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 38 of 40 Painting Emissions - Crit ALT Date Printed - 6/26/2013Operating Data [1] Operating Hours = 12 hrs/day = 208 days/year

HAP PTE Calculations- Paint Coatings, and Thinners

Product Description Pollutant Weight % 3 Highest Emitting HAP by Product Density 3 (lb/gal) Maximum Daily Usage 2 (gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy) Xylenes 100.00% Amercoat 65 - Thinne r 7.26 10 1049 73.2 3.81 Ethylbenzene 30.00% Amercoat 65 - Thinne r 7.26 10 1049 22.0 1.14

Tolene 1.00% Amercoat 65 - Thinne r 7.26 10 1049 0.7 0.04 Hexone 60.00% Amercoat 10 - Thinne r 7.01 10 1049 42.4 2.21 Xylenes 1.25% Amercoat 450H - Yello w 10.18 19 2014 2.5 0.13 Ethylbenzene 1.25% Amercoat 450H - Yello w 10.18 19 2014 2.5 0.13 Naphtalene 1.00% Amercoat 450H - Yello w 10.18 19 2014 2.0 0.10

Cumene 0.00% Amercoat 450H - Yello w 10.18 19 2014 0.0 0.00 Xylenes 1.00% Amercoat 235 - Cure 8.01 5 503 0.4 0.02 Ethylbenzene 0.00% Amercoat 235 - Cure 8.01 5 503 0.0 0.00 Naphtalene 0.00% Amercoat 235 - Cure 8.01 5 503 0.0 0.00

Cumene 1.00% Amercoat 235 - Cure 8.01 5 503 0.4 0.02 Worst Case VOC HAPs 145.99 7.59

[1] [2]

[3] Data provided in an email by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 11/28/2012 and 6/24/2013. Maximum daily usage determined based on phone conversation between Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 12/03/2012. Primer usage is based on the mixing ratio provided in the technical data sheet. Based on MSDS provided in emails by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 6/24/2013. Maximum wt% have be en used when VOC HAP exceeded corresponding VOC emissions. 

### Anadarko Petroleum Corporation Emission Calculations

Painting Operations

EPN: DR-PO-01 Hazardous Air Pollutants

Thinner

Base

Hardener

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 39 of 40 Painting Emissions - HAPs Date Printed - 6/26/2013Operating Data [1] Operating Hours = 12 hrs/day = 208 days/year

HAP PTE Calculations- Paint Coatings, and Thinners

Product Description Pollutant Weight % 3 Highest Emitting HAP by Product Density 3 (lb/gal) Maximum Daily Usage 2 (gal/day) Annual Usage 2 (gal/year) Maximum Daily Emissions (lb/day) Annual Emissions

(tpy) Xylenes 100.00% Amercoat 65 - Thinner 7.26 7 743 51.86 2.70 Ethylbenzene 30.00% Amercoat 65 - Thinner 7.26 7 743 15.56 0.81

Tolene 1.00% Amercoat 65 - Thinner 7.26 7 743 0.52 0.03 Hexone 60.00% Amercoat 10 - Thinner 7.01 7 743 30.04 1.56 Xylenes 1.25% Amercoat 450H - Yellow 10.18 14 1426 1.75 0.09 Ethylbenzene 1.25% Amercoat 450H - Yellow 10.18 14 1426 1.75 0.09 Naphtalene 1.00% Amercoat 450H - Yellow 10.18 14 1426 1.40 0.07

Cumene 0.00% Amercoat 450H - Yellow 10.18 14 1426 0.00 0.00 Xylenes 1.00% Amercoat 235 - Cure 8.01 3 357 0.27 0.01 Ethylbenzene 0.00% Amercoat 235 - Cure 8.01 3 357 0.00 0.00 Naphtalene 0.00% Amercoat 235 - Cure 8.01 3 357 0.00 0.00

Cumene 1.00% Amercoat 235 - Cure 8.01 3 357 0.27 0.01 Worst Case VOC HAPs 103.41 5.38

[1] [2] [3] Data provided in an email by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 11/28/2012 and 6/24/2013. Maximum daily usage determined based on phone conversation between Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 12/03/2012. Primer Based on MSDS provided in emails by Ms. Sara Carlson (Anadarko) to Mr. Rahul Pendse (Trinity) on 6/24/2013. Maximum wt% have be en used when VOC HAP exceeded corresponding VOC emissions. 

### Anadarko Petroleum Corporation Emission Calculations

Painting Operations EPN: DR-PO-01 (ALT) Hazardous Air Pollutants

Thinner

Base

Hardener

Anadarko Petroleum Corporation EGOM Exploratory Project - Discoverer Spirit 40 of 40 Painting Emissions - HAPs ALT Date Printed - 6/26/2013Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPEND **IX B**

**– RBLC SEARCH RESULTS** 

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT** 

AK-0059 9/29/2003 IC ENGINES DIESEL Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES 0

AK-0059 9/29/2003 IC ENGINES, FIREWATER PUMP, DIESEL, (2) DIESEL Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES 0

AR-0076 2/17/2004 IC ENGINE, EMERGENCY GENERATOR SN-PBCDF-12 DIESEL FUEL 250 KW Nitrogen Oxides (NOx) OPERATING HOURS LIMIT: < 1200 COMBINED H/YR FOR SN-PBCDF-09 & SN-PBCDF-10, < 500 H/YR FOR SN-PBCDF-12. 4.7 LB/H

AR-0094 11/5/2008 EMERGENCY GENERATOR AND FIRE PUMP ENGINE Nitrogen Oxides (NOx) GOOD COMBUSTION 6.4 G/KW-H

CA-0998 1/7/2003 IC ENGINE DIESEL FUEL 415 HP Nitrogen Oxides (NOx) EPA CERTIFIED ENGINE 6.9 G/B-HP-H

*CA-1191 3/11/2010 EMERGENCY FIREWATER PUMP ENGINE DIESEL 135 KW Nitrogen Oxides (NOx) OPERATIONAL RESTRICTION OF 50 HR/YR, OPERATE AS REQUIRED FOR FIRE SAFETY TESTING 3.8 G/KW-HR

*CA-1192 6/21/2011 EMERGENCY FIREWATER PUMP ENGINE DIESEL 288 HP Nitrogen Oxides (NOx) EQUIPPED W/ A TURBOCHARGER AND AN INTERCOOLER/AFTERCOOLER 3.4 G/HP-H

*CA-1212 10/18/2011 EMERGENCY IC ENGINE DIESEL 182 HP Nitrogen Oxides (NOx) 4 G/KW-HR

*CA-1213 4/21/2006 EMERGENCY FIRE IC ENGINE DIESEL 375 BHP Nitrogen Oxides (NOx) 0

*CA-1217 8/23/2012 Internal Combustion Engine - 450 bhp diesel 450 bhp Nitrogen Oxides (NOx) Tier 4 interim certified 1.8 G/KW-HR

FL-0324 12/23/2010 Two emergency diesel firewater pump engines 250 HP Nitrogen Oxides (NOx) demonstrate compliance in accordance with the procedures given in 40 CFR 60, Subpart IIII 3 G/HP-H

FL-0324 12/23/2010 250 Kw Emergency Generator ULSD 0 Nitrogen Oxides (NOx) Use of inherently clean ultra low sulfur distillate (ULSD) fuel oil and GCP 4 G/KW-H

FL-0327 6/13/2011 Main Propulsion Engines Diesel 0 Nitrogen Oxides (NOx) Use of good combustion and maintenance practices, Power Management System, and NOx Concentration Maintenance System as described in the OCS permit application. 12.7 G/KW-H

FL-0327 6/13/2011 Emergency Engine Diesel 0 Nitrogen Oxides (NOx) Limited use of 24 hours/week and recordkeeping of operation. 9.4 TONS PER PROJECT

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Nitrogen Oxides (NOx) Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 12.7 G/KW-H

*FL-0328 10/27/2011 Crane Engines (units 1 and 2) Diesel 0 Nitrogen Oxides (NOx) Use of certified EPA Tier 1 engines and good combustion practices based on the current manufacturer's specifications for this engine. 9.5 TONS PER YEAR

*FL-0328 10/27/2011 Crane Engines (units 3 and 4) Diesel 0 Nitrogen Oxides (NOx) Use of good combustion practices, based on the current manufacturer's specifications for this engine 9.7 T/YR

*FL-0328 10/27/2011 Emergency Engine Diesel 0 Nitrogen Oxides (NOx) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.4 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Fire Pump Engine Diesel 0 Nitrogen Oxides (NOx) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.02 TONS PER YEAR

*FL-0328 10/27/2011 Boiler Diesel 9.6 mmBTU/h Nitrogen Oxides (NOx) Use of good combustion and maintenance practices, based on the current manufacturer's specifications for this boiler. 0.49 TONS PER YEAR

*FL-0329 11/28/2011 Main Generator Engines - Deepwater Nautilus Diesel 0 Nitrogen Oxides (NOx) use of Low NOx engine design and engine performance management system 12.7 G/KW-H

*FL-0329 11/28/2011 Standby Generator - Deepwater Nautilus Diesel 0 Nitrogen Oxides (NOx) use of turbo charger/after cooler, intake air cooling and good combustion practices 0.15 T/YR

*FL-0329 11/28/2011 Cementing Units Diesel 0 Nitrogen Oxides (NOx) Use of EPA Tier 1 engine and good combustion practices 4.86 T/YR

*FL-0329 11/28/2011 Crane Engines (units 1 and 2) Diesel 0 Nitrogen Oxides (NOx) use of EPA Tier 1 engines w/Low NOx Engine design and good combustion practices. 15.65 T/YR

*FL-0329 11/28/2011 Main Generator Engines - Bully Diesel 0 Nitrogen Oxides (NOx) use of EPA Tier 2 with Low NOx engine design and good combustion practices. 5.5 G/KW-H

*FL-0329 11/28/2011 Emergency Generator - Bully Diesel 0 Nitrogen Oxides (NOx) Use of EPA Tier 2 engines w/Low NOx engine design and good combustion practices 0.15 T/YR

IA-0064 1/31/2003 710 HP DIESEL STARTING ENGINE DIESEL 38.4 GAL/H Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES 3.1 LB/MMBTU

IA-0095 9/19/2008 GLUTEN MEAL DRYER AND NON-CONDENSABLE VENT SYSTEM Nitrogen Oxides (NOx) 0.04 LB/MMBTU

ID-0018 6/25/2010 FIRE PUMP ENGINE DIESEL 235 KW Nitrogen Oxides (NOx) TIER 3 ENGINE-BASED GOOD COMBUSTION PRACTICES (GCP) 4 G/KW-H 

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) NO **X**

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT**  

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) NO **X**



### LA-0194 11/24/2004 FIREWATER BOOSTER PUMP DIESEL ENGINES (2) DIESEL 300 HP EACH Nitrogen Oxides (NOx) GOOD ENGINE DESIGN & PROPER OPERATING PRACTICES 3.44 LB/H

LA-0204 2/27/2009 SMALL EMERGENCY ENGINES DIESEL Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 4.41 LB/MMBTU

LA-0204 2/27/2009 LARGE EMERGENCY ENGINES DIESEL Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 3.2 LB/MMBTU

LA-0204 2/27/2009 BOILERS A & B (U-1 & U-2) 250 MMBTU/H Nitrogen Oxides (NOx) LOW NOX BURNERS AND FLUE GAS RECIRCULATION 0.04 LB/MMBTU

LA-0204 2/27/2009 BOILERS C & D (U-3 & U-4) 250 MMBTU/H Nitrogen Oxides (NOx) LOW NOX BURNERS AND FLUE GAS RECIRCULATION 0.012 LB/MMBTU

LA-0204 2/27/2009 CRACKING FURNACES A-D 90 MMBTU/H EA. Nitrogen Oxides (NOx) LOW NOX BURNERS AND SELECTIVE CATALYTIC REDUCTION (SCR) 0.009 LB/MMBTU

LA-0251 4/26/2011 Large Generator Engines (17 units) Diesel 0 Nitrogen Oxides (NOx) 6.32 LB/H

LA-0251 4/26/2011 Small Generator Engine diesel 193 hp Nitrogen Oxides (NOx) 1.28 LB/H

LA-0251 4/26/2011 Fire Pump Engines - 2 units diesel 444 hp Nitrogen Oxides (NOx) 5.82 LB/H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY FIRE WATER PUMP DIESEL 300 HP Nitrogen Oxides (NOx) 3 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Nitrogen Oxides (NOx) 4.8 G/HP-H

MN-0053 7/15/2004 IC ENGINE, SMALL, FUEL OIL (1) DIESEL 250 HP Nitrogen Dioxide (NO2) GOOD COMBUSTION. 4.41 LB/MMBTU

MN-0053 7/15/2004 BOILER, DISTILLATE OIL (1) #2 FUEL OIL 40 MMBTU/H Nitrogen Dioxide (NO2) LOW NOX BURNER AND FGR. 0.058 LB/MMBTU

MN-0054 12/4/2003 INTERNAL COMBUSTION ENGINE, SMALL DIESEL FUEL 290 HP Nitrogen Oxides (NOx) GOOD COMBUSTION 5.7 G/B-HP-H

MO-0067 12/29/2004 IC ENGINE, EMERGENCY DIESEL FIRE PUMP DIESEL 0.47 mmbtu/h Nitrogen Oxides (NOx) IGNITION TIMING RETARD (ITR) 0

MT-0022 7/21/2003 BOILER, AUXILIARY, # 1 & #2 FUEL OIL 117 MMBTU/H Nitrogen Oxides (NOx) LOW NOX BURNERS, HOURLY OPERATION LIMIT 19.8 LB/H

MT-0022 7/21/2003 IC ENGINE, EMERGENCY GENERATOR NO. 2 FUEL OIL 15.3 MMBTU/H Nitrogen Oxides (NOx) LIMITED HOURS OF OPERATION TO 200 H/YR 97.7 % REDUCTION

NC-0074 1/24/2003 IC ENGINE, DIESEL GENERATOR, (2) DIESEL 15.7 MMBTU/H Nitrogen Oxides (NOx) IGNITION TIMING RETARD 43.76 LB/H

NC-0074 1/24/2003 IC ENGINES, AIR COMPRESSORS, DIESEL, (5) DIESEL 4.46 MMBTU/H Nitrogen Oxides (NOx) IGNITION TIMING RETARD 7.8 LB/H

NJ-0073 3/8/2008 DUAL FUEL ENGINES ON 100 % DISTILLATE FUEL OIL DISTILLATE FUEL OIL 1 MMGAL/YR Nitrogen Oxides (NOx) 12 G/B-HP-H

NV-0045 12/11/2006 LARGE INTERNAL COMBUSTION ENGINE DIESEL OIL 12 GAL/H Nitrogen Oxides (NOx) N/A 0.058 LB/T

NV-0047 2/26/2008 LARGE INTERNAL COMBUSTION ENGINES (> 500 HP) DIESEL OIL Nitrogen Oxides (NOx) TURBOCHARGER AND AFTERCOOLER 7.58 G/B-HP-H

NV-0047 2/26/2008 SMALL INTERNAL COMBUSTION ENGINES (<= 500 HP) DIESEL OIL Nitrogen Oxides (NOx) TURBOCHARGER AND AFTERCOOLER 3.88 G/B-HP-H

NV-0050 11/30/2009 SMALL INTERNAL COMBUSTION ENGINE - UNIT EX012 AT EXCALIBUR DIESEL OIL 350 HP Nitrogen Oxides (NOx) TURBOCHARGER AND AFTERCOOLER 0.031 LB/HP-H

OH-0281 6/10/2004 PORTABLE ENGINE 0.58 MMBTU/H FUEL OIL #2 0.58 MMBTU/H Nitrogen Oxides (NOx) 2.55 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 4.68 MMBTU/H FUEL OIL #2 4.68 MMBTU/H Nitrogen Oxides (NOx) 14.99 LB/H

OH-0317 11/20/2008 FIRE PUMP ENGINES (2) DIESEL FUEL OIL 300 HP Nitrogen Oxides (NOx) GOOD COMBUSTION PRACTICES, GOOD ENGINE DESIGN, IGNITION TIMING RETARD, TURBOCHARGER, AND LOW-TEMPERATURE AFTERCOOLER 4.89 LB/H

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT** 

AK-0059 9/29/2003 IC ENGINES, FIREWATER PUMP, DIESEL, (2) DIESEL Carbon Monoxide GOOD COMBUSTION PRACTICES 0

AR-0094 11/5/2008 EMERGENCY GENERATOR AND FIRE PUMP ENGINE Carbon Monoxide 3.5 G/KW-H

CA-0998 1/7/2003 IC ENGINE DIESEL FUEL 415 HP Carbon Monoxide EPA CERTIFIED ENGINE 8.5 G/B-HP-H

*CA-1191 3/11/2010 EMERGENCY FIREWATER PUMP ENGINE DIESEL 135 KW Carbon Monoxide OPERATIONAL RESTRICTION OF 50 HR/YR, OPERATE AS REQUIRED FOR FIRE SAFETY TESTING 3.5 G/KW-HR

*CA-1192 6/21/2011 EMERGENCY FIREWATER PUMP ENGINE DIESEL 288 HP Carbon Monoxide EQUIPPED W/ A TURBOCHARGER AND AN INTERCOOLER/AFTERCOOLER 0.447 G/HP-H

*CA-1212 10/18/2011 EMERGENCY IC ENGINE DIESEL 182 HP Carbon Monoxide 3.5 G/KW-HR

FL-0324 12/23/2010 Two emergency diesel firewater pump engines 250 HP Carbon Monoxide demonstrate compliance in accordance with the procedures given in 40 CFR 60, Subpart IIII 2.6 G/HP-H

FL-0324 12/23/2010 250 Kw Emergency Generator ULSD 0 Carbon Monoxide Use of inherently clean ultra low sulfur distillate (ULSD) fuel oil and GCP 3.5 G/KW-H

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Carbon Monoxide Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 3.3 G/KW-H

*FL-0328 10/27/2011 Crane Engines (units 1 and 2) Diesel 0 Carbon Monoxide Use of certified EPA Tier 1 engines and good combustion practices based on the current manufacturer's specifications for this engine. 11.8 TONS PER YEAR

*FL-0328 10/27/2011 Crane Engines (units 3 and 4) Diesel 0 Carbon Monoxide Use of good combustion practices, based on the current manufacturer's specifications for this engine 4 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Engine Diesel 0 Carbon Monoxide Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.09 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Fire Pump Engine Diesel 0 Carbon Monoxide Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.005 TONS PER YEAR

IA-0084 11/30/2006 FIRE PUMP ENGINE DIESEL FUEL 460 HP Carbon Monoxide GOOD COMBUSTION PRACTICES 2.6 G/B-HP-H

ID-0018 6/25/2010 FIRE PUMP ENGINE DIESEL 235 KW Carbon Monoxide TIER 3 ENGINE-BASED, GOOD COMBUSTION PRACTICES (GCP) 0

LA-0194 11/24/2004 FIREWATER BOOSTER PUMP DIESEL ENGINES (2) DIESEL 300 HP EACH Carbon Monoxide GOOD ENGINE DESIGN & PROPER OPERATING PRACTICES 0.18 LB/H

LA-0204 2/27/2009 SMALL EMERGENCY ENGINES DIESEL Carbon Monoxide GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 0.95 LB/MMBTU

LA-0204 2/27/2009 LARGE EMERGENCY ENGINES DIESEL Carbon Monoxide GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 0.85 LB/MMBTU

LA-0229 7/10/2008 EQT115, 116, 121, 129 - EMERGENCY IC ENGINES Carbon Monoxide MAINTAIN WRITTEN OPERATING AND MAINTENANCE PROCEDURES; PROPERLY TRAINED OPERATING PERSONNEL; MAINTAINING APPROPRIATE FUEL-TO AIR RATIO; AND PROPER DESIGN, FUEL HANDLING, SIZING, AND COMBUSTION AIR AND FUEL DISTRIBUTION 0.0067 LB/HP-H

LA-0251 4/26/2011 Large Generator Engines (17 units) Diesel 0 Carbon Monoxide no additional control 0.03 LB/H

LA-0251 4/26/2011 Small Generator Engine diesel 193 hp Carbon Monoxide 0.16 LB/H

LA-0251 4/26/2011 Fire Pump Engines - 2 units diesel 444 hp Carbon Monoxide good equipment design and proper combustion practices 0.65 LB/H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY FIRE WATER PUMP DIESEL 300 HP Carbon Monoxide 2.6 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Carbon Monoxide 2.6 G/HP-H

MN-0053 7/15/2004 IC ENGINE, SMALL, FUEL OIL (1) DIESEL 250 HP Carbon Monoxide GOOD COMBUSTION. 0.95 LB/MMBTU

MN-0054 12/4/2003 INTERNAL COMBUSTION ENGINE, SMALL DIESEL FUEL 290 HP Carbon Monoxide GOOD COMBUSTION 0.25 G/B-HP-H

MT-0022 7/21/2003 IC ENGINE, EMERGENCY GENERATOR NO. 2 FUEL OIL 15.3 MMBTU/H Carbon Monoxide LIMITED TO 200 HOURS OF OPERATION PER YEAR 97.7 % REDUCTION

NV-0045 12/11/2006 ASPHALT CONCRETE MANUFACTURING N/A 450 T/H Carbon Monoxide N/A 0.1 LB/T

NV-0045 12/11/2006 LARGE INTERNAL COMBUSTION ENGINE DIESEL OIL 12 GAL/H Carbon Monoxide OPERATING ACCORDING TO THE MANUFACTURER'S SPECIFICATION 0.1 LB/T

NV-0047 2/26/2008 BOILERS/HEATERS - DIESEL OILFIRED DIESEL OIL Carbon Monoxide GOOD COMBUSTION PRACTICE 0.038 LB/MMBTU

NV-0047 2/26/2008 LARGE INTERNAL COMBUSTION ENGINES (> 500 HP) DIESEL OIL Carbon Monoxide TURBOCHARGER AND AFTERCOOLER 0.22 G/B-HP-H

NV-0047 2/26/2008 SMALL INTERNAL COMBUSTION ENGINES (<= 500 HP) DIESEL OIL Carbon Monoxide TURBOCHARGER AND AFTERCOOLER 0.5 G/B-HP-H

NV-0050 11/30/2009 SMALL INTERNAL COMBUSTION ENGINE - UNIT EX012 AT EXCALIBUR DIESEL OIL 350 HP Carbon Monoxide TURBOCHARGER AND GOOD COMBUSTION PRACTICES 0.0067 LB/HP-H

OH-0254 8/14/2003 EMERGENCY DIESEL FIRE PUMP ENGINE DIESEL 400 HP Carbon Monoxide LOW SULFUR FUEL, COMBUSTION CONTROL 2.76 LB/H

OH-0281 6/10/2004 FUGITIVE EMISSIONS FROM LANDFILL AND GAS COLLECTION SYSTEM Carbon Monoxide 34.18 T/YR

OH-0281 6/10/2004 PORTABLE ENGINE 0.58 MMBTU/H FUEL OIL #2 0.58 MMBTU/H Carbon Monoxide 0.55 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 4.68 MMBTU/H FUEL OIL #2 4.68 MMBTU/H Carbon Monoxide 3.98 LB/H

OH-0317 11/20/2008 FIRE PUMP ENGINES (2) DIESEL FUEL OIL 300 HP Carbon Monoxide GOOD COMBUSTION PRACTICES AND GOOD ENGINE DESIGN 1.72 LB/H 

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) CO

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT** 

AK-0060 10/10/2003 BOILER, FUEL OIL, (2) DISTILLATE OIL 29.3 MMBTU/H Particulate matter, filterable; 10 μ (FPM10) GOOD COMBUSTION MANAGEMENT, OPACITY LIMIT 0

AR-0076 2/17/2004 IC ENGINE, EMERGENCYGENERATOR SNPBCDF-12 DIESEL FUEL 250 KW Particulate matter, filterable; 10 μ (FPM10) OPERATING HOURS LIMIT: < 500 H/YR 0.4 LB/H

AR-0094 11/5/2008 EMERGENCY GENERATOR AND FIRE PUMP ENGINE Particulate Matter (PM) 0.2 G/KW-H

CA-0998 1/7/2003 IC ENGINE DIESEL FUEL 415 HP Particulate matter, filterable; 10 μ (FPM10) EPA CERTIFIED ENGINE 0.1 G/B-HP-H

*CA-1191 3/11/2010 EMERGENCY FIREWATER PUMP ENGINE DIESEL 135 KW Particulate matter, total (TPM) OPERATIONAL RESTRICTION OF 50 HR/YR, OPERATE AS REQUIRED FOR FIRE SAFETY TESTING 0.2 G/KW-HR

*CA-1191 3/11/2010 EMERGENCY FIREWATER PUMP ENGINE DIESEL 135 KW Particulate matter, total; 2.5 μ (TPM2.5) OPERATIONAL RESTRICTION OF 50 HR/YR, OPERATE AS REQUIRED FOR FIRE SAFETY TESTING 0.2 G/KW-HR

*CA-1192 6/21/2011 EMERGENCY FIREWATER PUMP ENGINE DIESEL 288 HP Particulate matter, total (TPM) USE ULTRA LOW SULFUR FUELNOT TO EXCEED 15 PPMVD FUEL SULFUR, OPERATIONAL LIMIT OF 50 HRS/YR 0

*CA-1192 6/21/2011 EMERGENCY FIREWATER PUMP ENGINE DIESEL 288 HP Particulate matter, total; 10 μ (TPM10) USE ULTRA LOW SULFUR FUEL NOT TO EXCEED 15 PPMVD FUEL SULFUR, OPERATIONAL LIMIT OF 50 HRS/YR 0

*CA-1212 10/18/2011 EMERGENCY IC ENGINE DIESEL 182 HP Particulate matter, total (TPM) USE ULTRA LOW SULFUR FUEL 0.2 G/KW-HR

*CA-1212 10/18/2011 EMERGENCY IC ENGINE DIESEL 182 HP Particulate matter, total; 10 μ (TPM10) USE ULTRA LOW SULFUR FUEL 0.2 G/KW-HR

*CA-1212 10/18/2011 EMERGENCY IC ENGINE DIESEL 182 HP Particulate matter, total; 2.5 μ (TPM2.5) USE ULTRA LOW SULFUR FUEL 0.2 G/KW-HR

FL-0324 12/23/2010 Two emergency diesel firewater pump engines 250 HP Particulate matter, total (TPM) demonstrate compliance in accordance with the procedures given in 40 CFR 60, Subpart IIII 0.15 G/HP-H

FL-0324 12/23/2010 250 Kw Emergency Generator ULSD 0 Particulate matter, total (TPM) Use of inherently clean ultra low sulfur distillate (ULSD) fuel oil and GCP & demonstrate compliance in accordance with the procedures given in 40 CFR 60, Subpart IIII 0.2 G/KW-H

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Particulate matter, filterable (FPM) Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 0.43 G/KW-H

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Particulate matter, total; 10 μ (TPM10) Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 0.24 G/KW-H

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Particulate matter, total; 2.5 μ (TPM2.5) Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 0.24 G/KW-H

*FL-0328 10/27/2011 Crane Engines (units 1 and 2) Diesel 0 Particulate matter, total (TPM) Use of certified EPA Tier 1 engines and good combustion practices based on the current manufacturer's specifications for this engine. 0.6 TONS PER YEAR

*FL-0328 10/27/2011 Crane Engines (units 3 and 4) Diesel 0 Particulate matter, total (TPM) Use of good combustion practices, based on the current manufacturer's specifications for this engine 1.3 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Engine Diesel 0 Particulate matter, total (TPM) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.03 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Fire Pump Engine Diesel 0 Particulate matter, total (TPM) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.002 TONS PER YEAR

IA-0064 1/31/2003 710 HP DIESEL STARTING ENGINE DIESEL 38.4 GAL/H Particulate Matter (PM) LOW ASH FUEL, GOOD COMBUSTION PRACTICES. 0.069 LB/MMBTU

ID-0018 6/25/2010 FIRE PUMP ENGINE DIESEL 235 KW Particulate Matter (PM) TIER 3 ENGINE-BASED, GOOD COMBUSTION PRACTICES (GCP) 0.2 G/KW-H

LA-0194 11/24/2004 FIREWATER BOOSTER PUMP DIESEL ENGINES (2) DIESEL 300 HP EACH Particulate matter, filterable; 10 μ (FPM10) GOOD ENGINE DESIGN, PROPER OPERATING PRACTICES, AND USE OF LOW SULFUR DIESEL 0.06 LB/H

LA-0204 2/27/2009 SMALL EMERGENCY ENGINES DIESEL Particulate matter, total; 10 μ (TPM10) GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 0.31 LB/MMBTU

LA-0204 2/27/2009 LARGE EMERGENCY ENGINES DIESEL Particulate matter, total; 10 μ (TPM10) GOOD COMBUSTION PRACTICES AND GASEOUS FUEL BURNING 0.1 LB/MMBTU 

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) PM/PM **10** 

# /PM **2.5**

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT**  

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) PM/PM **10** 

# /PM **2.5**



### LA-0229 7/10/2008 EQT115, 116, 121, 129 - EMERGENCY IC ENGINES Particulate matter, total; 10 μ (TPM10) MAINTAIN WRITTEN OPERATING AND MAINTENANCE PROCEDURES; PROPERLY TRAINED OPERATING PERSONNEL; MAINTAINING APPROPRIATE FUEL-TO AIR RATIO; AND PROPER DESIGN, FUEL HANDLING, SIZING, AND COMBUSTION AIR AND FUEL DISTRIBUTION 0.0022 LB/HP-H

LA-0251 4/26/2011 Large Generator Engines (17 units) Diesel 0 Particulate matter, filterable; 10 μ (FPM10) 0.01 LB/H

LA-0251 4/26/2011 Small Generator Engine diesel 193 hp Particulate matter, filterable; 10 μ (FPM10) 0.01 LB/H

LA-0251 4/26/2011 Fire Pump Engines - 2 units diesel 444 hp Particulate matter, filterable; 10 μ (FPM10) 0.01 LB/H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY FIRE WATER PUMP DIESEL 300 HP Particulate Matter (PM) 0.15 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY FIRE WATER PUMP DIESEL 300 HP Particulate matter, filterable; 10 μ (FPM10) 0.15 GR-HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY FIRE WATER PUMP DIESEL 300 HP Particulate matter, filterable; 2.5 μ (FPM2.5) 0.15 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Particulate Matter (PM) 0.15 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Particulate matter, filterable; 10 μ (FPM10) 0.15 G/HP-H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Particulate matter, filterable; 2.5 μ (FPM2.5) 0.15 G/HP-H

MN-0053 7/15/2004 IC ENGINE, SMALL, FUEL OIL (1) DIESEL 250 HP Particulate Matter (PM) CLEAN FUEL AND GOOD COMBUSTION. 0.31 LB/MMBTU

MN-0053 7/15/2004 BOILER, DISTILLATE OIL (1) #2 FUEL OIL 40 MMBTU/H Particulate Matter (PM) CLEAN FUEL AND GOOD COMBUSTION. 0.024 LB/MMBTU

MN-0054 12/4/2003 INTERNAL COMBUSTION ENGINE, SMALL DIESEL FUEL 290 HP Particulate Matter (PM) GOOD COMBUSTION 0.07 G/B-HP-H

MN-0054 12/4/2003 INTERNAL COMBUSTION ENGINE, SMALL DIESEL FUEL 290 HP Particulate matter, filterable; 10 μ (FPM10) GOOD COMBUSTION 0.07 G/B-HP-H

NH-0018 7/26/2010 EU03 FIRE PUMP ENGINE DIESEL FUEL 2.27 MMBTU/H Particulate matter, filterable (FPM) 0.3 E-5 LB/MMBTU

NV-0045 12/11/2006 LARGE INTERNAL COMBUSTION ENGINE DIESEL OIL 12 GAL/H Particulate matter, filterable; 10 μ (FPM10) USE OF LOW-SULFUR DIESEL OIL 0.0049 LB/T

NV-0047 2/26/2008 BOILERS/HEATERS - DIESEL OIL-FIRED DIESEL OIL Particulate matter, filterable; 10 μ (FPM10) GOOD COMBUSTION PRACTICE 0.019 LB/MMBTU

NV-0047 2/26/2008 LARGE INTERNAL COMBUSTION ENGINES (>500 HP) DIESEL OIL Particulate matter, filterable; 10 μ (FPM10) TURBOCHARGER AND AFTERCOOLER 0.084 G/B-HP-H

NV-0047 2/26/2008 SMALL INTERNAL COMBUSTION ENGINES (<= 500 HP) DIESEL OIL Particulate matter, filterable; 10 μ (FPM10) TURBOCHARGER AND AFTERCOOLER 0.14 G/B-HP-H

NV-0050 11/30/2009 SMALL INTERNAL COMBUSTION ENGINE - UNIT EX012 AT EXCALIBUR DIESEL OIL 350 HP Particulate matter, filterable; 10 μ (FPM10) TURBOCHARGER AND GOOD COMBUSTION PRACTICE 0.0022 LB/HP-H

OH-0254 8/14/2003 EMERGENCY DIESEL FIRE PUMP ENGINE DIESEL 400 HP Particulate Matter (PM) LOW SULFUR FUEL, COMBUSTION CONTROL 0.88 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 0.58 MMBTU/H FUEL OIL #2 0.58 MMBTU/H Particulate matter, filterable; 10 μ (FPM10) 0.18 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 0.58 MMBTU/H FUEL OIL #2 0.58 MMBTU/H Particulate Matter (PM) 0.18 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 4.68 MMBTU/H FUEL OIL #2 4.68 MMBTU/H Particulate matter, filterable; 10 μ (FPM10) 0.27 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 4.68 MMBTU/H FUEL OIL #2 4.68 MMBTU/H Particulate Matter (PM) 0.29 LB/H

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT**  

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) PM/PM **10** 

# /PM **2.5**



### OH-0317 11/20/2008 FIRE PUMP ENGINES (2) DIESEL FUEL OIL 300 HP Particulate matter, filterable; 10 μ (FPM10) GOOD COMBUSTION PRACTICES AND GOOD ENGINE DESIGN 0.27 LB/H

### RBLCID **ISSUANCE PROCESS**  **FUEL THROUGHPUT**  **UNIT POLLUTANT**  **CONTROL METHOD EMISSION**  **LIMIT UNIT** 

AR-0094 11/5/2008 EMERGENCY GENERATOR AND FIRE PUMP ENGINE Volatile Organic Compounds (VOC) GOOD COMBUSTION 6.4 G/KW-H

CA-0998 1/7/2003 IC ENGINE DIESEL FUEL 415 HP Volatile Organic Compounds (VOC) EPA CERTIFIED ENGINE 1 G/B-HPH

*FL-0328 10/27/2011 Main Propulsion Engines Diesel 0 Volatile Organic Compounds (VOC) Use of good combustion practices based on the current manufacturer's specifications for these engines, and additional enhanced work practice standards including an engine performance management system and the Diesel Engines with Turbochargers (DEWT) measurement system. 0.39 G/KW-H

*FL-0328 10/27/2011 Crane Engines (units 1 and 2) Diesel 0 Volatile Organic Compounds (VOC) Use of certified EPA Tier 1 engines and good combustion practices based on the current manufacturer's specifications for this engine. 1.3 TONS PER YEAR

*FL-0328 10/27/2011 Crane Engines (units 3 and 4) Diesel 0 Volatile Organic Compounds (VOC) Use of good combustion practices, based on the current manufacturer's specifications for this engine 1.5 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Engine Diesel 0 Volatile Organic Compounds (VOC) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.03 TONS PER YEAR

*FL-0328 10/27/2011 Emergency Fire Pump Engine Diesel 0 Volatile Organic Compounds (VOC) Use of good combustion practices, based on the current manufacturer's specifications for this engine 0.002 TONS PER YEAR

*FL-0328 10/27/2011 Boiler Diesel 9.6 mmBTU/h Volatile Organic Compounds (VOC) Use of good combustion and maintenance practices, based on the current manufacturer's specifications for this boiler. 0.005 TONS PER YEAR

IA-0084 11/30/2006 POLYMER POWDER CONVEYING 5 T/H Volatile Organic Compounds (VOC) 80 T/YR

IA-0084 11/30/2006 EXTRUDER VACUUM PUMP 300 ACFM Volatile Organic Compounds (VOC) 0.03 LB/H

IA-0084 11/30/2006 PELLETIZER & DRYER 3.15 T/H Volatile Organic Compounds (VOC) 80 T/YR

IA-0084 11/30/2006 FIRE PUMP ENGINE DIESEL FUEL 460 HP Volatile Organic Compounds (VOC) GOOD COMBUSTION PRACTICES 3 G/B-HPH

IA-0084 11/30/2006 EMERGENCY GENERATOR DIESEL FUEL 74.3 GAL/H Volatile Organic Compounds (VOC) GOOD COMBUSTION PRACTICES 4.8 GAL/BHP-H

ID-0018 6/25/2010 FIRE PUMP ENGINE DIESEL 235 KW Volatile Organic Compounds (VOC) TIER 3 ENGINE-BASED, GOOD COMBUSTION PRACTICES (GCP) 4 G/KW-H

LA-0194 11/24/2004 FIREWATER BOOSTER PUMP DIESEL ENGINES (2) DIESEL 300 HP EACH Volatile Organic Compounds (VOC) GOOD ENGINE DESIGN & PROPER OPERATING PRACTICES 0.1 LB/H

LA-0219 8/15/2007 FUGITIVE EMISSIONS Volatile Organic Compounds (VOC) 0.62 LB/H

MD-0040 11/12/2008 INTERNAL COMBUSTION ENGINE - EMERGENCY GENERATOR DIESEL Volatile Organic Compounds (VOC) 4.8 G/HP-H

MN-0053 7/15/2004 IC ENGINE, SMALL, FUEL OIL (1) DIESEL 250 HP Volatile Organic Compounds (VOC) GOOD COMBUSTION. 0.36 LB/MMB TU

MN-0053 7/15/2004 BOILER, DISTILLATE OIL (1) #2 FUEL OIL 40 MMBTU/H Volatile Organic Compounds (VOC) GOOD COMBUSTION. 0.003 LB/MMB TU

MN-0054 12/4/2003 INTERNAL COMBUSTION ENGINE, SMALL DIESEL FUEL 290 HP Volatile Organic Compounds (VOC) GOOD COMBUSTION 0.08 G/B-HPH

NV-0045 12/11/2006 LARGE INTERNAL COMBUSTION ENGINE DIESEL OIL 12 GAL/H Volatile Organic Compounds (VOC) N/A 0.032 LB/T

NV-0047 2/26/2008 BOILERS/HEATERS - DIESEL OIL-FIRED DIESEL OIL Volatile Organic Compounds (VOC) GOOD COMBUSTION PRACTICE 0.0094 LB/MMB TU

NV-0047 2/26/2008 LARGE INTERNAL COMBUSTION ENGINES (> 500 HP) DIESEL OIL Volatile Organic Compounds (VOC) TURBOCHARGER AND AFTERCOOLER 0.2 G/B-HPH

NV-0047 2/26/2008 SMALL INTERNAL COMBUSTION ENGINES (<= 500 HP) DIESEL OIL Volatile Organic Compounds (VOC) TURBOCHARGER AND AFTERCOOLER 0.14 G/B-HPH

NV-0050 11/30/2009 SMALL INTERNAL COMBUSTION ENGINE - UNIT EX012 AT EXCALIBUR DIESEL OIL 350 HP Volatile Organic Compounds (VOC) TURBOCHARGER AND GOOD COMBUSTION PRACTICE 0.0025 LB/HP-H

OH-0281 6/10/2004 PORTABLE ENGINE 0.58 MMBTU/H FUEL OIL #2 0.58 MMBTU/H Volatile Organic Compounds (VOC) 0.2 LB/H

OH-0281 6/10/2004 PORTABLE ENGINE 4.68 MMBTU/H FUEL OIL #2 4.68 MMBTU/H Volatile Organic Compounds (VOC) 0.42 LB/H

OH-0317 11/20/2008 FIRE PUMP ENGINES (2) DIESEL FUEL OIL 300 HP Volatile Organic Compounds (VOC) GOOD COMBUSTION PRACTICES AND GOOD ENGINE DESIGN 0.26 LB/H 

# RBLC SEARCH - SMALL DIESEL ENGINES (< 500 HP) VOCAnadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX C

**– NEW**  **ENGINE SPECIFICATION SHEETS** 

# FOR OFF-HIGHWAY APPLICATIONS 

# C SERIES EVER Y JOB

.

### From excavators to cranes to threshers and knuckleboom loaders, the C8.3 is one of the most versatile engines in every kind of equipment for construction, agriculture, logging and more. It’s also one of the most successful, with millions of C Series engines in use around the globe. Over the decades, Cummins C8.3-powered equipment has earned the trust and repeat business of customers who appreciate its simplicity, durability and no-nonsense work ethic. Cummins C8.3 engine meets all current Tier 2/Stage II standards.



# Features And Benefits.

Cummins C8.3 engines have been proven durable and

r eliable in some of the most remote locations and harshest working environments in the world. A robust in-line rotary fuel pump delivers more power while making it possible to use lighter weight fuels such as Jet A and kerosene, when diesel fuel is not available. Other design
features include:

■ Dual Ni-Resist Piston Inserts – Reduce friction and oil

consumption, increase piston life.

■ Plateau-Honed Cylinder Liners – Virtually eliminate oil

consumption.

■ Mid-Stop Cylinder Liners – Reduce cavitation and improve rebuildability.

■ Holset HX40 Turbo – Wastegated design optimizes

r esponse across the torque curve.

■ Edge-Molded Gaskets – Prevents oil leaks.

■ Helical Gear Train – For smoother and quieter operation. 

# Ratings

E NGINE A DVERTISED P EAK P EAK M ODEL H ORSEPOWER H ORSEPOWER T ORQUE

C8.3-260 260 @ 2200 RPM 275 @ 2000 RPM 889 LB

- FT @ 1500 RPM

C8.3-250 250 @ 2200 RPM 265 @ 2000 RPM 853 LB

- FT @ 1500 RPM

C8.3-240 240 @ 2200 RPM 257 @ 2000 RPM 824 LB

- FT @ 1500 RPM

C8.3-230 230 @ 2200 RPM 249 @ 2000 RPM 804 LB

- FT @ 1500 RPM

C8.3-215 215 @ 2200 RPM 225 @ 2000 RPM 719 LB

- FT @ 1500 RPM

C8.3-205* 205 @ 2200 RPM 216 @ 2000 RPM 715 LB

- FT @ 1500 RPM

C8.3-190* 190 @ 2000 RPM 194 @ 1800 RPM 638 LB

- FT @ 1500 RPM

C8.3-185* 185 @ 2200 RPM 193 @ 2000 RPM 631 LB

- FT @ 1500 RPM

* Ratings with an asterisk are continuous/water management. All other ratings are intermittent unless noted. Additional ratings may be available. Check with your Cummins distributor or dealer. 

# Specifications

A DVERTISED H ORSEPOWER 185-260 BHP 138-194 K W

P EAK T ORQUE 631-889 LB

- FT 856-1205 N• M

N UMBER OF C YLINDERS 6

O IL S YSTEM C APACITY 21 U.S. QT 19.9 LITERS

L ENGTH 44.4 IN 1128 MM

W IDTH 29.5 IN 749 MM

H EIGHT 43.1 IN 1096 MM

N ET W EIGHT ( WET ) 1,360 LB 617 KG 

# FOR OFF-HIGHWAY APPLICATIONS.

# Options.

The C8.3 is adaptable to a wide variety of equipment, operating everywhere around the world. For colder climates, we offer Resistive Grid Heating that preheats intake air electrically for improved starting. For high-traffic areas where noise is a concern, we offer a choice of noise

r eduction packages, lowering noise output by as much as 3 dBA. There are literally hundreds of options to choose from when spec’ing every C8.3, including:

■ Flywheels

■ Flywheel housings

■ Starters

■ Oil fill options

■ Alternators

■ Oil pans

■ Air-handling options

■ Cooling system options

■ Accessory drive mounting options

■ Fan drive options

■ And more


# Cummins Advisor.

Getting every installation right – the first time – is
what Cummins Advisor is
all about. Advisor
software builds a virtual model to make sure every system (air, intake, exhaust, cooling, etc.) is integrated for optimum performance. It takes into account everything from load factors to operating climates to duty cycles – then identifies systems or components that could negatively impact reliability – listing alternatives that deliver the performance you expect the first time – every time. 

# Maintenance Intervals.

The C8.3 is designed to run up to 500 hours between oil changes with the optional high-capacity oil pan, with little or no top-off needed. Plateau-honed cylinder liners, an innovative ring pack design and edge-molded gaskets all help to reduce oil consumption.


# Base Warranty.

Cummins C Series engines come with a full 2-year/2,000- hour warranty that
covers all Cummins branded components, including electrics such
as starters and alternators. Major components coverage continues into the third year, up to 3,000 hours of operation from the time your C8.3 engine goes in service.

Three simple steps explain everything you need to know:

Step One: Full coverage on all Cummins industrial engines and branded components with unlimited hours during the first year of operation. This includes Cummins branded electrics such as alternators, starters, etc.

Step Two: Full coverage is extended for the second year, up to 2,000 hours of operation. Total hours are cumulative from the time the engine goes in service.

Step Three: Major components coverage including block, crankshaft, camshaft and rods on all products for the third year or up to 3,000 hours of operation.
T

otal hours are cumulative from the time the engine goes in service.

# Extended Coverage.

Unlike plans offered by other diesel manufacturers, Encompass gives you a choice of hourly or unlimited plans and options that include parts only, parts and service, or parts, service and travel coverage. You can get up to seven years of additional coverage for your C8.3 engine with Encompass, including your choice of plans for up to five years of coverage with unlimited hours. No matter where your Cummins-powered equipment is going to be used, Cummins Encompass has you covered, around the clock and around the globe. For additional details, please
ask to see Cummins Bulletin 3624570. 

# Cummins QuickServe ®



# .
Cummins QuickServe is an entire system dedicated to performing fast, accurate maintenance and repair services – using quality
Cummins and Cummins
ReCon ® 

### parts – to minimize downtime and maximize productivity. Our distributors’ service record is so reliable, we offer an
exclusive QuickServe Guarantee* to customers in the majority of our industrial markets.

Cummins distributors guarantee that engine service performed in their shop with a standard repair time of four hours or less will be completed that same day – or you’ll

r eceive a $75 credit toward future Cummins parts or
service work.

If your equipment is down and you can’t bring it to one of our locations, we’ll come to yours. A Cummins QuickServe truck and certified service technician will be dispatched within four hours of your call, or you’ll receive a $75 credit toward future Cummins parts or service work.

*$75 credit applies only to service in the U.S. and Canada. The QuickServe Guarantee varies by country. Please contact your local Cummins distributor for details. 

### To schedule or request service, call your local Cummins distributor today. For additional details or to learn more about the QuickServe Guarantee, see our web site at www.everytime.cummins.com. 

# QuickServe ® 

# Online.

QuickServe Online (http://quickserve.cummins.com) gives you easy access to parts and service information. While there are over eight million engines and literally billions of part numbers indexed in the QuickServe Online database, you can find the information you need in seconds with our high-speed search function and your engine’s serial number. 

# Every Question, Answered.

Service Network – Cummins engines are backed by the strength of Cummins global network of over 5,500 service locations worldwide.

Customer Assistance Center – For technical assistance, service locations and product literature, call 1-800-DIESELS (1-800-343-7357).

Cummins PowerMaster – E-mail the experts for timely answers to Cummins-related questions at powermaster@cummins.com.

Cummins Online Registration – Register all your Cummins engines quickly and easily at www.everytime.cummins.com to ensure quality parts and service for your engine.

# TORQUE AND POWER CURVES.

240 HP/824@1500 FR 90886

250 HP/853@1500 FR 90883Power (hp) Torque (lb-ft)Power (hp) Torque (lb-ft)Power (hp) Torque (lb-ft)



## 260 HP/889@1500 FR 91194 215 HP/719@1500 FR 90892Power (hp) Torque (lb-ft)Power (hp) Torque (lb-ft) 

## 205 HP/715@1500 FR 90895Power (hp) Torque (lb-ft)



## 230 HP/804@1500 FR 90887Power (hp) Torque (lb-ft) 

## 190 HP/638@1500 FR 91003Power (hp) Torque (lb-ft) 

## 185 HP/631@1500 FR 91002

Cummins is a pioneer in product improvement. Thus specifications may change without notice. Illustrations may include optional equipment.Cummins Inc. Box 3005 Columbus, IN 47202-3005 U.S.A.
Phone: 1-800-DIESELS (1-800-343-7357) Fax: 1-800-232-6393 E-Mail: powermaster@cummins.com Internet: www.everytime.cummins.com

Bulletin 4087027 Printed in U.S.A. 8/04 ©2004 Cummins Inc.

# 3406 C Industrial Engine

Non-Certified 269 bkW/360 bhp @ 1800 rpm

Image shown may not reflect actual engine 

## CAT® ENGINE SPECIFICATIONS

I-6, 4-Stroke-Cycle Diesel Bore

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137.2 mm (5.4 in) Stroke

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165.1 mm (6.5 in) Displacement

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14.64 L (893.39 in 3 

### ) Aspiration

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . Turbocharged / Aftercooled Compression Ratio

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15.9:1 Rotation (from flywheel end)

. . . . . . . . . . . . . . Counterclockwise Capacity for Liquids Cooling System

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20.8 L (5.5 gal) Lube Oil System (refill)

. . . . . . . . . . . . . . . . . . . . . . . . . . . 38.0 L (10.0 gal) Engine Weight, Net Dry (approximate)

. . 1,512 kg (3,333 lb)



## FEATURES

Emissions Non-certified rating. Meets emission levels for Tier 1 / Stage I standards.

Single Source Supplier Caterpillar

- Casts engine blocks, heads, cylinder liners, and flywheel housings

- Machines critical components

- Assembles complete engine Ownership of these manufacturing processes enables Caterpillar to produce high quality, dependable product.
Factory-designed systems built at Caterpillar ISO certified facilities.

Testing Prototype testing on every model:

- proves computer design

- verifies system torsional stability

- functionality tests every model
Every Caterpillar engine is dynamometer tested under full load to ensure proper engine performance. Full Range of Attachments Wide range of bolt-on system expansion attachments, factory designed and tested

Unmatched Product Support Offered Through Worldwide Caterpillar Dealer Network More than 1,500 dealer outlets. Caterpillar factory-trained dealer technicians service every aspect of your industrial engine. 99.7% of parts orders filled within 24 hours worldwide. Caterpillar parts and labor warranty. Preventive maintenance agreements available for repair before failure options.

Scheduled Oil Sampling program matches your oil sample against Caterpillar set standards to determine:

- internal engine component condition

- presence of unwanted fluids

- presence of combustion by-products

Web Site For all your industrial power requirements, visit www.cat-industrial.com.

13 April 2012 9:33 AM

## 3406 C Industrial Engine
Non-Certified 269 bkW/360 bhp @ 1800 rpm 

## STANDARD ENGINE EQUIPMENT

Air Inlet System Air cleaner, Regular duty, dry, panel type with service indicators, turbocharger, jacket water aftercooled

Control System Governor, Hydra-mechanical

Cooling System Thermostats and housing, Jacket water pump, gear driven, centrifugal, RH

Exhaust System Exhaust manifold, dry, front exhaust Exhaust elbow, dry, 152 mm (6 in), 4 bolt flange 127 mm (5 in) on 406DO12

Flywheels and Flywheel Housings Flywheel, SAE No. 1 Flywheel housing, SAE No. 1, SAE standard rotation

Fuel Systems Fuel Filter, LH Fuel transfer pump Fuel priming pump Instrumentation Instrument Panel, LH Engine oil pressure gauge Fuel pressure gauge Water temperature gauge Service meter

Lube System Crankcase breather Oil cooler, RH Oil filter, RH Oil filler in valve cover and dipstick, both RH Rear sump oil pan

Mounting System Supports

General Paint, Caterpillar Yellow Vibration damper and guard Lifting eyes

2 13 April 2012 9:33 AM

## 3406 C Industrial Engine
Non-Certified 269 bkW/360 bhp @ 1800 rpm 

## PERFORMANCE CURVES

IND

- C (Intermittent)

- DM2169-01

Torque N•m

Engine Power kW

BSFC g/kW-hr

Engine Speed

- rpm Metric

Engine Speed rpm Engine Power

kW Torque N•m BSFC g/kW-hr Fuel Rate L/hr

1800 269 1424 206.6 66.1 1750 268 1460 206.2 65.7 1700 266 1494 205.8 65.1 1650 264 1527 205.4 64.4 1600 261 1559 205.1 63.6 1550 258 1587 204.8 62.6 1500 253 1612 204.6 61.6 1450 249 1637 204.7 60.5 1400 243 1659 205.2 59.4 1350 237 1678 206.4 58.3 1300 231 1694 208.5 57.2 1250 223 1705 211.8 56.1 1200 215 1709 216.5 55.1 1150 205 1705 222.8 54.3 1100 195 1694 230.7 53.7



### 3 13 April 2012 9:33 AM

## 3406 C Industrial Engine
Non-Certified 269 bkW/360 bhp @ 1800 rpm 

## PERFORMANCE CURVES

IND

- C (Intermittent)

- DM2169-01

Engine Torque lb•ft

Engine Power bhp

BSFC lb/bhp-hr

Engine Speed rpm English

Engine Speed rpm Engine Power

bhp Engine Torque

lb•ft BSFC lb/bhp-hr Fuel Rate gal/hr
1800 360 1050 .340 17.5 1750 359 1077 .339 17.4 1700 357 1102 .338 17.2 1650 354 1126 .338 17.0 1600 350 1150 .337 16.8 1550 345 1171 .337 16.5 1500 340 1189 .336 16.3 1450 333 1207 .337 16.0 1400 326 1224 .337 15.7 1350 318 1238 .339 15.4 1300 309 1249 .343 15.1 1250 299 1258 .348 14.8 1200 288 1260 .356 14.6 1150 275 1258 .366 14.3 1100 262 1249 .379 14.2



### 4 13 April 2012 9:33 AM

## 3406 C Industrial Engine
Non-Certified 269 bkW/360 bhp @ 1800 rpm 

## RATINGS AND CONDITIONS

IND

- C (Intermittent) Intermittent service where maximum power and/or speed are cyclic. The power and speed capability of the engine can be utilized for one uninterrupted hour followed by one hour of operation at or below IND

- A. Time at full load is not to exceed 50% of the duty cycle. Typical service examples are: agricultural tractors, harvesters and combines, off highway trucks, fire pump application power, blast hole drills, rock crushers and wood chippers with high torque rise, and oil field hosting. Engine Performance Engine performance is corrected to inlet air standard conditions of 99 KPA (29.31 IN HG) dry barometer and 25 deg C (77 deg F) temperature. These values correspond to the standard atmospheric pressure and temperature as shown in SAE J1995.

Performance measured using a standard fuel with fuel gravity of 35 degrees API having a lower heating value of 42,780 KJ/KG (18,390 BTU/LB) when used at 29 DEG (84.2 DEG F) where the density is 838.9 G/L (7.001 LB/US GAL).

The corrected performance values shown for Caterpillar engines will approximate the values obtained when the observed performance data is corrected to SAE J1995, ISO 3046-2 and 8665 and 2288 and 9249 and 1585, EEC 80/1269 and DIN 70020 standard reference conditions.



## Engine Dimensions
(1) Length 1660.1 mm (65.36 in) (2) Width 905.7 mm (35.66 in) (3) Height 1335.0 mm (52.56 in) Note: Do not use for installation design. See general dimension drawings for detail (Drawing # 1324895 ).

Performance Number: DM2169-01

Feature Code: 406DI04 Arr. Number: 1266205

Materials and specifications are subject to change without notice.

16282541 © 2012 Caterpillar

All rights reserved.

The International System of Units (SI) is used in this publication.
CAT, CATERPILLAR, their respective logos, "Caterpillar Yellow," the "Power Edge" trade dress, as well as corporate and product identity used herein, are trademarks of Caterpillar and may not be used without permission.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX D

**– AIR DISPERSION MODEL**  **ING**

**List of FLM Class I AQRV Modeling Files on Disc**

**– Drilling Operations** 

The disc included with this appendix contains all of the input and output data files used to generate the results from the FLM Class I AQRV analysis presented in this report. The following section provides a description of the contents of each folder included in the attached disc.



## Breton NWR Files

1. CALPUFF Input and Output Files

BR01 C

. INP

– Input file for year 2001. BR01C.LST

– Output file for year 2001. BR02C.INP

– Input file for year 2002. BR02C.LST

– Output file for year 2002. BR03C.INP

– Input file for year 2003. BR03C.LST

– Output file for year 2003.



### 2. POSTUTIL Input and Output Files

BR01NSC.INP

– Input file for 2001 to combine wet and dry fluxes for N and S deposition. BR01NSC.LST

– Output file for 2001 to combine wet and dry fluxes for N and S deposition. BR02NSC.INP

– Input file for 2002 to combine wet and dry fluxes for N and S deposition. BR02NSC.LST

– Output file for 2002 to combine wet and dry fluxes for N and S deposition. BR03NSC.INP

– Input file for 2003 to combine wet and dry f luxes for N and S deposition. BR03NSC.LST

– Output file for 2003 to combine wet and dry fluxes for N and S deposition.



### 3. CALPOST Input and Output Files

BR01NC.INP

– Input file for 2001 to calculate nitrogen deposition. BR01NC.LST

– Output file for 2001 to calculate nitrogen deposition. BR02NC.INP

– Input file for 2002 to calculate nitrogen deposition. BR0 2 N C.LST

– Output file for 2002 to calculate nitrogen deposition. BR03NC.INP

– Input file for 2003 to calculate nitrogen depositi on. BR03NC.LST

– Output file for 2003 to calculate nitrogen deposition. BR01SC.INP

– Input file for 2001 to calculate sulfur deposition. BR01SC.LST

– Output file for 2001 to calculate sulfur deposition. BR02SC.INP

– Input file for 2002 to calculate sulfur deposition. BR02SC.LST

– Output file for 2002 to calculate sulfur deposition. BR03SC.INP

– Input file for 2003 to calculate sulfur deposition. BR03SC.LST

– Output file for 2003 to calculate sulfur deposition. BR01V8C.INP

– Input file for 2001 to calculate Method 8 visibility. BR01V8C.LST

– Output file for 2001 to calculate Method 8 visibility. BR02V8C.INP

– Input file for 2002 to calculate Method 8 visibility. BR02V8C.LST

– Output file for 2002 to calculate Method 8 visib ility. BR03V8C.INP

– Input file for 2003 to calculate Method 8 visibility. BR03V8C.LST

– Output file for 2003 to calculate Method 8 visibility.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

### List of Class I PSD **Significance Modeling Files on DVD** 

**– Drilling Operations** 

The disc included with this appen dix contains all of the input and output data files used to generate the results from the Class I PSD Increment analysis presented in this report. The following section provides a description of the contents of each folder included in the attached disc

.



## Breton NWR Files

1. CALPUFF Input and Output Files

BR01 D

. INP

– Input file for year 2001. BR01D.LST

– Output file for year 2001. BR02D.INP

– Input file for year 2002. BR02D.LST

– Output file for year 2002. BR03D.INP

– Input file for year 2003. BR03D.LST

– Output file for year 2003.



### 2. POSTUTIL Input and Output Files

BR01PMD.INP

– Input file for 2001 to combine speciated PM components into PM 10


### . BR01PMD.LST

– Output file for 2001 to combine speciated PM components into PM 10


### . BR02PMD.INP

– Input file for 2002 to combine speciated PM components into PM 10


### . BR02PMD.LST

– Output file for 2002 to combine speciated PM components into PM 10


### . BR03PMD.INP

– Input file for 2003 to combine speciated PM components into PM 10


### . BR03PMD.LST

– Output file for 2003 to combine speciated PM components into PM 10


### . BR01ALMD.INP

– Input file for 2001 to repartition nitrate mass using ALM method. BR01ALMD.LST

– Output file for 2001 to repartition nitrate mass using ALM method. BR02ALMD.INP

– Input file for 2002 to repartition nitrate mass using ALM method. BR02ALMD.LST

– Output file for 2002 to repartition nitrate mass using ALM method. BR03ALMD.INP

– Input file for 2003 to repartition nitrate mass using ALM method. BR03ALMD.LST

– Output file for 2003 to repartition nitrate mass using ALM method.



### 3. CALPOST Input and Output File

BR01P1D.INP

– Input file for 2001 to calculate PM 10 

### concentration. BR01P1D.LST

– Output file for 2001 to calculate PM 10 

### concentration. BR02P1D.INP

– Input file for 2002 to calculate PM 10 

### concentr ation. BR02P1D.LST

– Output file for 2002 to calculate PM 10 

### concentration. BR03P1D.INP

– Input file for 2003 to calculate PM 10 

### concentration. BR03P1D.LST

– Output file for 2003 to calculate PM 10 

### concentration. BR01P2D.INP

– Input file for 2001 to calculate PM 2.5 

### concentration. BR01P2D.LST

– Output file for 2001 to calculate PM 2.5 

### concentration. BR02P2D.INP

– Input file for 2002 to calculate PM 2.5 

### concentration. BR02P2D.LST

– Output file for 2002 to calculate PM 2.5 

### concentr ation. BR03P2D.INP

– Input file for 2003 to calculate PM 2.5 

### concentration. BR03P2D.LST

– Output file for 2003 to calculate PM 2.5 

### concentration. BR01NO2D.INP

– Input file for 2001 to calculate NO 2 

### concentration. BR01NO2D.LST

– Output file for 2001 to calcul ate NO 2 

### concentration. BR02NO2D.INP

– Input file for 2002 to calculate NO 2 

### concentration. BR02NO2D.LST

– Output file for 2002 to calculate NO 2 

### concentration. BR03NO2D.INP

– Input file for 2003 to calculate NO 2 

### concentration. BR03NO2D.LST

– Output file for 2003 to calculate NO 2 

### concentration.Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX E

**– REVISED RESPONSE TO**  **INCOMPLETENESS DETER MINATION**  **LETTER QUESTION NO. 8** 8. It is unclear how the total worst

- case well completion emissions were calculated. Each well completion scenario will use both the emission units listed in Table 1 on page 4 of Appendix B and emission units on the drillship and support vessels. For example, each of the four well completion scenarios will use the Main Engines, listed as DR

- ME

- 01 through DR

- ME

- 06, (it is assumed that these engines are the same as the drillship engines listed in the first part of the emission calculations, DR

- GE

- 01 through DR

- GE

- 06). Yet, this results in a discontinuity. The total emissions from each well completion scenario, listed at the bottom of Table 1 on page 4, do not result from a summation of the emission units listed on this page. The application
indicat es that additional units will be used during a given well completion scenario, but the information provided does not clearly show how many hours these emissions units will operate. Please provide an additional chart that provides all emission units and ca lculations
for the worst

- case well completion scenarios, so that the total emission equal the emissions for each unit presented.

**Anadarko Response** : Anadarko confirms tha t the same main engines (i.e., DR

- GE

- 01 through DR

- GE

06) on the drillship will be used during the well completion activities. However, the requested fuel restriction during well completion scenario is lower than that of drilling scenario. Tables 3 throu gh 1 3 provide details regarding operations and emissions for each well completion scenario.Table3.WellCompletionScenario–EmissionSourceSummaryNOTE:However,oilwellcompletionscenariorequiressupplyboattoperformapreliminaryworkbeforetheboomflarecouldoperate.Hence,bothsupplyboatsaswellasboomflarewillberequiredtooperateduringtheoilwellcompletionscenario;however,theywillnotoperatesimultaneously.Sincetheboomflarerepresentstheworstcaseemissionscenariobetweenthesetwosourcesofairpollution,emissionsarecalculatedfortheboomflareoperations.AnadarkoproposestoretainflexibilitytooperatethesupplyboatsortheboomflareoranycombinationofthemduringtheoilwellcompletionscenarioaslongasthetotalemissionsforeachpollutantareequalorlessthantheemissionsfortheboomflarespecifiedinTables4through13.AirEmissionSourcesUnitScenario1Scenario2Scenario3Scenario4EPN(s)Gas	Well	Completion	 Oil	Well	Completion	 Stimulation	Vessel	 Third	Party	Equipmentper	day	 per	year	 per	day	 per	year	 per	day	 per	year	 per	day	 peryearDR‐WC‐01Tubing	Running	Pumpshours ‐‐‐‐‐‐24684DR‐WC‐02Fluid	Filtration	Packhours ‐‐‐‐241,008241,008DR‐WC‐03E‐Line	Power	Packhours ‐‐‐‐‐‐24720DR‐WC‐07CT	Power	Packhours ‐‐‐‐‐‐24720DR‐WC‐08CT	Pumphours ‐‐‐‐‐‐24720All	sources	with	EPN	starting	with	TBTugbbls	 ‐‐3407,140‐‐‐‐BG‐LP‐01Bargehours ‐‐24504‐‐‐‐DR‐WC‐05Flowback	BoilerMMbtu 1921,1521921,152‐‐‐‐DR‐WC‐06Boom	FlareMMscf 6036040160‐‐‐‐DR‐WC‐04Slickline	Power	Packhours ‐‐‐‐‐‐241,440All	sources	starts	with	SVStimulation	Vessel	Engineshours ‐‐‐‐24960‐‐DR‐GE‐01	through	DR‐GE‐07	 Drillship	Main	Engines	and	EmergencyGenerator	 bbls	 250	 52,000	 200	 41,600	 295	 61,360	 380	 67,600All	sources	with	EPN	starting	with		SB	 Supply	Boats	 bbls	 145	 45,136	 See	Note	Below	 ‐	 ‐	 415	 86,320DR‐PO‐01Painting	(paint	+	thinner)gals	 34‐34‐34‐34‐DR‐WC‐09,	DR‐WC‐10Wire	Line	Engines	no.	3	and	4	 hours ‐‐‐‐‐‐241,440DR‐GE‐08ROV	Emergency	Generatorhours 1100110011001100DR‐AC‐01Air	Compressor	Diesel	Engine	#1	 hours 0.51040.51040.51040.5104DR‐AC‐02Air	Compressor	Diesel	Engine	#2	 hours 0.51040.51040.51040.5104DR‐EC‐01	through	DR‐EC‐06Escape	Capsule	Diesel	Engine	no.	1	to6	 hours 0.51000.51000.51000.5100DR‐FL‐01Diesel	Powered	Forklift	Engine	 hours 122,49681,664244,992244,992DR‐FR‐01Fast	Rescue	Crafthours 0.51000.51000.51000.5100DR‐WB‐01Water	Blasting	Enginehours 122,496122,496122,496122,496DR‐DC‐01	through	DR‐DC‐03Dust	Collectors	no.	1	to	3hours 244,992244,992244,992244,992DR‐WO‐01Weldinglbs	 5010,4005010,4005010,4005010,400DR‐DT‐01	through	DR‐DT‐09Nine	Drill	Ship	Diesel	Storage	Tankshours 244,992244,992244,992244,992DR‐FT‐01	through	DR‐FT‐03Three	Drill	Ship	Jet	Fuel	Storage	Tanks	 hours 244,992244,992244,992244,992DR‐FE‐01Drillship	Fugitive	Emissionshours 244,992244,992244,992244,992DR‐VG‐01Mud	Degasser	Venthours 244,992244,992244,992244,992WC‐CT‐01	through	WC‐CT‐03Well	Completion	Condensate	Tanks	1	to3hours ‐‐244,992‐‐‐‐**T able**  **4**

**. Well Completion Scenario** 

**– PM Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day t py lb/day t py lb/day t py lb/day t py
DR

- WC

- 01 Tubing Running Pumps

- - - - - - 1.44 0.02

DR

- WC

- 02 Fluid Filtration Pack

- - - - 1.19 0.02 1.19 0.02

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 1.78 0.03

DR

- WC

- 07 CT Power Pack

- - - - - - 4.73 0.07

DR

- WC

- 08 CT Pump

- - - - - - 6.79 0.1 All sources with EPN starting with TB Tug

- - 295.68 3.10

- - - -
BG

- LP

- 01 Barge

- - 28.51 0.30

- - - -
DR

- WC

- 05 Flowback Boiler 4.40 0.01 4.40 0.01

- - - -
DR

- WC

- 06 Boom Flare 446.88 1.34 297.93 0.90

- - - -
DR

- WC

- 04 Slickline Power Pack

- - - - - - 0.99 0.03

All sources starts with SV Stimulation Vessel Engines

- - - - 212.92 4.09

- -
DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 141.34 14.73 113. 07 11.78 166.78 17.38 214.83 19.14 All sources with EPN starting with SB Supply Boats 40.06 6.23

- - - - 114.65 11.92

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.1 3 2.54 0.1 3 2.54 0.1 3 2.54 0.1 3

DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.007 0.14 0.007 0.14 0.007 0.14 0.007

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0. 24 0.03 0.235 0.03 0.235 0.03 0.235 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 0.79 0.83 0.528 0.055 1.584 0.16 5 1.584 0.16 5

DR

- FR

- 01 Fast Rescue Craft 0.08 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09 0.82 0.09 0.82 0.09 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.05 0.738 4.05 0.738 4.05 0.738 4.05 0.738

DR

- WO

- 01 Welding 1.92 0.20 1.92 0.20 1.92 0.20 1.92 0.20

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - -
DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - -
WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 643.29 23.60 749.93 17.45 392.28 22.95 362.15 32.84**Table 5. Well Completion Scenario** 

**– PM**  **10 Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 1.44 0.02

DR

- WC

- 02 Fluid Filtration Pack

- - - - 1.19 0.02 1.19 0.02

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 1.78 0.03

DR

- WC

- 07 CT Power Pack

- - - - - - 4.73 0.07

DR

- WC

- 08 CT Pump

- - - - - - 3.89 0.06 All sources with EPN starting with TB Tug

- - 169.42 1.78

- - - - BG

- LP

- 01 Barge

- - 28.51 0.30

- - - - DR

- WC

- 05 Flowback Boiler 4.40 0.01 4.40 0.01

- - - - DR

- WC

- 06 Boom Flare 446.88 1.34 297.93 0.90

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 0.99 0.03
All sources starts with SV Stimulation Vessel Engines

- - - - 122.00 2.34

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 80.99 8.44 64.79 6.75 95.56 9.96 123.10 10.97 All sources with EPN starting with SB Supply Boa ts 32.93 5.13

- - - - 94.26 9.8

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.13 2.54 0.13 2.54 0.13 2.54 0.13

DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.007 0.14 0.007 0.14 0.007 0.14 0.007

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.235 0.03 0.235 0.03 0.235 0.03 0.235 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 0.79 0.83 0.528 0.055 1.584 0.165 1.584 0.165

DR

- FR

- 01 Fast Rescue Craft 0.076 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09 0.82 0.09 0.82 0.09 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.046 0.738 4.046 0.738 4.046 0.738 4.046 0.738

DR

- WO

- 01 Welding 1.92 0.20 1.92 0.20 1.92 0.20 1.92 0.20

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 575.81 16.20 575.39 11.09 230.15 13.79 247.12 22.50**Table 6. Well Completion Scenario** 

**– PM**  **2.5 Emissions** 

**Air Emission Sources**  **Scenario 1 Scenario 2**  **Scenario 3 Scenario 4**  **EPN(s)** Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 1.44 0.03

DR

- WC

- 02 Fluid Filtration Pack

- - - - 1.19 0.02 1.19 0.02

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 1.78 0.03

DR

- WC

- 07 CT Power Pack

- - - - - - 4.73 0.07

DR

- WC

- 08 CT Pump

- - - - - - 3.77 0.06 All sources with EPN starting with TB Tug

- - 164.40 1.73

- - - - BG

- LP

- 01 Barge

- - 28.51 0.30

- - - - DR

- WC

- 05 Flowback Boiler 4.40 0.01 4.40 0.01

- - - - DR

- WC

- 06 Boom Flare 446.88 1.34 297.93 0.90

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 0.99 0.03
All sources starts with SV Stimulation Vessel Engines

- - - - 118.38 2.27

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 78.58 8.19 62.87 6.55 92.73 9.66 119.45 10.64 All sources with EPN starting with SB Supply Boa ts 31.96 4.97

- - - - 91.46 9.51

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.13 2.54 0.13 2.54 0.13 2.54 0.13

DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.007 0.14 0.007 0.14 0.007 0.14 0.007

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.0165 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04 0.0165 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.235 0.03 0.235 0.03 0.235 0.03 0.235 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 0.79 0.83 0.528 0.055 1.584 0.165 1.584 0.165

DR

- FR

- 01 Fast Rescue Craft 0.076 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03 0.076 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09 0.82 0.09 0.82 0.09 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.046 0.738 4.046 0.738 4.046 0.738 4.046 0.738

DR

- WO

- 01 Welding 1.92 0.20 1.92 0.20 1.92 0.20 1.92 0.20

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 572.43 15.80 568.44 10.84 223.70 13.42 241.06 21.89**Table 7. Well Completion Scenario** 

**– NO**  **X Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 26.98 0.38

DR

- WC

- 02 Fluid Filtration Pack

- - - - 26.16 0.55 26.16 0.55

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 58.67 0.88

DR

- WC

- 07 CT Power Pack

- - - - - - 151.51 2.27

DR

- WC

- 08 CT Pump

- - - - - - 217.17 3.26 All sources with EPN starting with TB Tug

- - 5451.13 57.24

- - - - BG

- LP

- 01 Barge

- - 401.76 4.22

- - - - DR

- WC

- 05 Flowback Boiler 32.03 0.10 32.03 0.10

- - - - DR

- WC

- 06 Boom Flare 4078.37 12.24 2718.91 8.16

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 32.83 0.98
All sources starts with SV Stimulation Vessel Engines

- - - - 6621.61 133.03

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 5,100.37 531.41 4080.29 425.12 6,018.43 627.06 7,752.56 690.83 All sources with EPN starting wi th SB Supply Boats 1464 227.78

- - - - 4189 435.62

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 143.23 4.3

DR

- GE

- 08 ROV Emergency Generator 4.47 2 0.22 4 4.47 2 0.22 4 4.47 2 0.22 4 4.47 2 0.22 4

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.28 0.01 45 0.28 0.01 45 0.28 0.01 45 0.28 0.01 45

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.23 3 0.01 21 0.23 3 0.01 21 0.23 3 0.01 21 0.23 3 0.01 21

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 3.317 0.422 3.317 0.422 3.317 0.422 3.317 0.422

DR

- FL

- 01 Diesel Powered Forklift Engine 11.16 1.16 7.44 0.774 22.32 2.32 1 22.32 2.32 1

DR

- FR

- 01 Fast Rescue Craft 1.4 18 0.14 2 1.418 0.14 2 1.418 0.14 2 1.418 0.14 2

DR

- WB

- 01 Water Blasting Engine 16.41 4 1.7 07 16.41 4 1.707 16.41 4 1.707 16.41 4 1.707

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 10,712 775 12,718 498 12,715 765 12,646 1,144**Table 8** 

**. Well Completion Scenario** 

**– SO**  **2 Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 2.48E

- 02 3.53E

- 04

DR

- WC

- 02 Fluid Filtration Pack

- - - - 2.70E

- 02 5.68E

- 04 2.70E

- 02 5.68E

- 04

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 6.06E

- 02 9.08E

- 04

DR

- WC

- 07 CT Power Pack

- - - - - - 1.62E

- 01 2.42E

- 03

DR

- WC

- 08 CT Pump

- - - - - - 2.31E

- 01 3.47E

- 03 All sources with EPN starting with TB Tug

- - 4.74 0.05

- - - - BG

- LP

- 01 Barge

- - 1.45E

- 01 1.53E

- 03

- - - - DR

- WC

- 05 Flowback Boiler 2.84E

- 01 8.53E

- 04 2.84E

- 01 8.53E

- 04

- - - - DR

- WC

- 06 Boom Flare 35.2 8 0.11 23.52 0.07

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 3.39E

- 02 1.02E

- 03
All sources starts with SV Stimulation Vessel Engines

- - - - 3.90 7.07E

- 02

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 2.26 0.24 1.81 0.19 2.67 0.28 3.44 0.31 All sources with EPN starting with SB Sup ply Boats 1.37 0.21

- - - - 3.91 0.41

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 0.15 4.44 E

- 03

DR

- GE

- 08 ROV Emergency Generator 4.77E

- 03 2.38E

- 04 4.77E

- 03 2.38E

- 04 4.77E

- 03 2.38E

- 04 4.77E

- 03 2.38E

- 04

DR

- AC

- 01 Air Compressor Diesel Engine #1 1.01E

- 04 5.25E

- 06 1.01E

- 04 5.25E

- 06 1.01E

- 04 5.25E

- 06 1.01E

- 04 5.25E

- 06

DR

- AC

- 02 Air Compressor Diesel Engine #2 8.41E

- 05 4.37E

- 06 8.41E

- 05 4.37E

- 06 8.41E

- 05 4.37E

- 06 8.41E

- 05 4.37E

- 06

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 1.20E

- 03 1.525 E

- 0 4 1.20E

- 03 1.525E

- 04 1.20E

- 03 1.525E

- 04 1.20E

- 03 1.525E

- 04

DR

- FL

- 01 Diesel Powered Forklift Engine 4 .0 4 E

- 03 4

. 2 0E

- 04 2.69E

- 03 2.80E

- 04 8.08E

- 03 8.40E

- 04 8.08E

- 03 8.40E

- 04

DR

- FR

- 01 Fast Rescue Craft 1.29E

- 03 1.29E

- 04 1.29E

- 03 1.29E

- 04 1.29E

- 03 1.29E

- 04 1.29E

- 03 1.29E

- 04

DR

- WB

- 01 Water Blasting Engine 2.80E

- 02 2.91E

- 03 2.80E

- 02 2.91E

- 03 2.80E

- 02 2.91E

- 0 3 2.80E

- 02 2.91E

- 03

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 39.23 0.56 30.54 0.32 6.65 0.35 8.08 0.73**Table 9** 

**. Well Completion Scenario** 

**– H**  **2 SO**  **4 Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 7.74E

- 04 1.10E

- 05

DR

- WC

- 02 Fluid Filtration Pack

- - - - 8.44E

- 04 1.77E

- 05 8.44E

- 04 1.77E

- 05

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 1.89E

- 03 2.84E

- 05

DR

- WC

- 07 CT Power Pack

- - - - - - 5.05E

- 03 7.57E

- 05

DR

- WC

- 08 CT Pump

- - - - - - 7.23E

- 03 1.08E

- 04 All sources with EPN starting with TB Tug

- - 0.15 1.55E

- 03

- - - - BG

- LP

- 01 Barge

- - 4.54E

- 03 4.77E

- 05

- - - - DR

- WC

- 05 Flowback Boiler

- - - - - - - - DR

- WC

- 06 Boom Flare

- - - - - - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 1.06E

- 03 3.18E

- 05

All sources starts with SV Stimulation Vessel Engines

- - - - 0.12 2.21E

- 03

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 7.07 E

- 02 7.37 E

- 03 5.66E

- 02 5.90E

- 03 8.35 E

- 02 8.7 0E

- 03 1.08E

- 01 9.58 E

- 03
All sources with EPN st arting with SB Supply Boats 4.27 E

- 02 6.64 E

- 03

- - - - 1.22 E

- 01 1.27E

- 02

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 4.63 E

- 03 1.39 E

- 04

DR

- GE

- 08 ROV Emergency Generator 1.49E

- 04 7.45E

- 06 1.49E

- 04 7.45E

- 06 1.49E

- 04 7.45E

- 06 1.49E

- 04 7.45E

- 06

DR

- AC

- 01 Air Compressor Diesel Engine #1 3.15E

- 06 1.64E

- 07 3.15E

- 06 1.64E

- 07 3.15E

- 06 1.64E

- 07 3.15E

- 06 1.64E

- 07

DR

- AC

- 02 Air Compressor Diesel Engine #2 2.63E

- 06 1.37E

- 07 2.63E

- 06 1.37E

- 07 2.63E

- 06 1.37E

- 07 2.63E

- 06 1.37E

- 07

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 3.75E

- 05 4.76E

- 06 3.75E

- 05 4.76E

- 06 3.75E

- 05 4.76E

- 06 3.75E

- 05 4.76E

- 06

DR

- FL

- 01 Diesel Powered Forklift Engine 1

. 26 E

- 04 1.31 E

- 05 8.40E

- 05 8.73E

- 06 2.52E

- 04 2.62E

- 05 2.52E

- 04 2.62E

- 05

DR

- FR

- 01 Fast Rescue Craft 4.03E

- 05 4.03E

- 06 4.03E

- 05 4.03E

- 06 4.03E

- 05 4.03E

- 06 4.03E

- 05 4.03E

- 06

DR

- WB

- 01 Water Blasting Engine 8.75E

- 04 9.10E

- 05 8.75E

- 04 9.10E

- 05 8.75E

- 04 9.10E

- 05 8.75E

- 04 9.10E

- 05

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 1.15E

- 01 1.41 E

- 02 2.10E

- 01 7.61E

- 03 2.08E

- 01 1.11E

- 02 2.53E

- 01 2.28E

- 02**Table 10** 

**. Well Completion Scenario** 

**– CO Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 17.99 0.26

DR

- WC

- 02 Fluid Filtration Pack

- - - - 19.82 0.42 19.82 0.42

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 31.11 0.47

DR

- WC

- 07 CT Power Pack

- - - - - - 82.86 1.24

DR

- WC

- 08 CT Pump

- - - - - - 118.76 1.78 All sources with EPN starting with TB Tug

- - 2323.20 24.39

- - - - BG

- LP

- 01 Barge

- - 86.57 0.91

- - - - DR

- WC

- 05 Flowback Boiler 6.67 0.02 6.67 0.02

- - - - DR

- WC

- 06 Boom Flare 22191.12 66.57 14794.08 44.38

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 17.41 0.52

All sources starts with SV Stimulation Vessel Engines

- - - - 2057.90 36.16

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 321.28 33.47 257.03 26.78 379.11 39.50 488.35 43.52 All sources with EPN starting with SB Supp ly Boats 1013 157.69

- - - - 2900 301.57

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 75.95 2.28

DR

- GE

- 08 ROV Emergency Generator 2.45 0.12 2.45 0.12 2.45 0.12 2.45 0.12

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.06 3.13E

- 03 0.06 3.13E

- 03 0.06 3.13E

- 03 0.06 3.13E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.05 2.61E

- 03 0.05 2.61E

- 03 0.05 2.61E

- 03 0.05 2.61E

- 03

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.715 0.091 0.715 0.091 0.715 0.091 0.715 0.091

DR

- FL

- 01 Diesel Powered Forklift Engine 2

. 41 0. 25 1.60 3 0.167 4.81 0.50 4.81 0.50

DR

- FR

- 01 Fast Rescue Craft 0.95 0.09 0.95 0.09 0.95 0.09 0.95 0.09

DR

- WB

- 01 Water Blasting Engine 14.36 1.49 14.36 1.49 14.36 1.49 14.36 1.49

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 23,553 259.82 17,488 98.46 2,480 78.38 3,775 354.36**Table 11** 

**. Well Completion Scenario** 

**– VOC Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 5.545 0.08

DR

- WC

- 02 Fluid Filtration Pack

- - - - 6.05 0.13 6.05 0.13

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 13.576 0.20

DR

- WC

- 07 CT Power Pack

- - - - - - 36.166 0.54

DR

- WC

- 08 CT Pump

- - - - - - 13.24 0.20 All sources with EPN starting with TB Tug

- - 270.99 2.85

- - - - BG

- LP

- 01 Barge

- - 32.55 0.34

- - - - DR

- WC

- 05 Flowback Boiler 2.67E

- 01 8.01E

- 04 2.67E

- 01 8.01E

- 04

- - - - DR

- WC

- 06 Boom Flare 8396.64 25.19 5597.76 16.79

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 7.61 0.23
All sources starts with SV Stimulation Vessel Engines

- - - - 223.33 4.04

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 115.76 12.06 92.61 9.65 136.59 14.23 175.95 15.68 All sources with EPN starting with SB Supply Boats 78.49 12. 22

- - - - 224.63 23.36

DR

- PO

- 01 Painting (paint + thinner) 173.14 9.00 173.14 9.00 173.14 9.00 173.14 9.00

DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 33.19 1.00

DR

- GE

- 08 ROV Emergency Generator 1.07 0.05 1.07 0.05 1.07 0.05 1.07 0.05

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.18E

- 03 0.02 1.18E

- 03 0.02 1.18E

- 03 0.02 1.18E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 9.80E

- 04 0.02 9.80E

- 04 0.02 9.80E

- 04 0.02 9.80E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.27 3.42E

- 02 0.27 3.42E

- 02 0.27 3.42E

- 02 0.27 3.42E

- 02

DR

- FL

- 01 Diesel Powered Forklift Engine 0.91 0.10 0.60 6.27E

- 02 1.81 0.19 1.81 0.19

DR

- FR

- 01 Fast Rescue Craft 0.29 0.03 0.29 0.03 0.29 0.03 0.29 0.03

DR

- WB

- 01 Water Blasting Engine 6.28 0.65 6.28 0.65 6.28 0.65 6.28 0.65

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks 0.678 0.322 0.678 0.322 0.678 0.322 0.678 0.322

DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks 0.044 0.384 0.044 0.384 0.044 0.384 0.044 0.384

DR

- FE

- 01 Drillship Fugitive Emissions 0.13 0.02 0.13 0.02 0.13 0.02 0.13 0.02

DR

- VG

- 01 Mud Degasser Vent 53.556 5.57 53.556 5.57 53.556 5.57 53.556 5.57

WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - 66.60 9.26

- - - -
**Total Emissions** 8,894 74.89 6,297 62.43 669.87 51.32 753.26 57.68**Table 12. Well Completion Scenario**

**– Pb Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 4.48E

- 04 6.39E

- 06

DR

- WC

- 02 Fluid Filtration Pack

- - - - 4.89E

- 04 1.03E

- 05 4.89E

- 04 1.03E

- 05

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 1.10E

- 03 1.64E

- 05

DR

- WC

- 07 CT Power Pack

- - - - - - 2.92E

- 03 4.38E

- 05

DR

- WC

- 08 CT Pump

- - - - - - 4.19E

- 03 6.28E

- 05 All sources with EPN starting with TB Tug

- - 0.09 9.00E

- 04

- - - - BG

- LP

- 01 Barge

- - 2.63E

- 03 2.76E

- 05

- - - - DR

- WC

- 05 Flowback Boiler 1.68E

- 03 5.05E

- 06 1.68E

- 03 5.05E

- 06

- - - - DR

- WC

- 06 Boom Flare

- - - - - - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 6.14E

- 04 1.84E

- 05

All sources starts with SV Stimulation Vessel Engines

- - - - 0.07 1.28E

- 03

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 4.10 E

- 02 4.27 E

- 03 3.28E

- 02 3.42E

- 03 4.84 E

- 02 5.04 E

- 03 6.23 E

- 02 5.55 E

- 03
All sources with EPN st arting with SB Supply Boats 2.47 E

- 02 3.85E

- 03

- - - - 7.08 E

- 01 7.36 E

- 03

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 2.68 E

- 03 8.04 E

- 05

DR

- GE

- 08 ROV Emergency Generator 8.63E

- 05 4.31E

- 06 8.63E

- 05 4.31E

- 06 8.63E

- 05 4.31E

- 06 8.63E

- 05 4.31E

- 06

DR

- AC

- 01 Air Compressor Diesel Engine #1 1.83E

- 06 9.50E

- 08 1.83E

- 06 9.50E

- 08 1.83E

- 06 9.50E

- 08 1.83E

- 06 9.50E

- 08

DR

- AC

- 02 Air Compressor Diesel Engine #2 1.52E

- 06 7.92E

- 08 1.52E

- 06 7.92E

- 08 1.52E

- 06 7.92E

- 08 1.52E

- 06 7.92E

- 08

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 2.17E

- 05 2.17E

- 06 2.17E

- 05 2.17E

- 06 2.17E

- 05 2.17E

- 06 2.17E

- 05 2.17E

- 06

DR

- FL

- 01 Diesel Powered Forklift Engine 7.30 E

- 05 0.76 E

- 05 4.87E

- 05 5.07E

- 06 1.46E

- 04 1.52E

- 05 1.46E

- 04 1.52E

- 05

DR

- FR

- 01 Fast Rescue Craft 2.33E

- 05 2.33E

- 06 2.33E

- 05 2.33E

- 06 2.33E

- 05 2.33E

- 06 2.33E

- 05 2.33E

- 06

DR

- WB

- 01 Water Blasting Engine 5.07E

- 04 5.27E

- 05 5.07E

- 04 5.27E

- 05 5.07E

- 04 5.27E

- 05 5.07E

- 04 5.27E

- 05

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding 8.10E

- 03 8.42E

- 04 8.10E

- 03 8.42E

- 04 8.10E

- 03 8.42E

- 04 8.10E

- 03 8.42E

- 04

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent

- - - - - - - - WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 7.62E

- 02 9.04E

- 03 1.32E

- 01 5.26E

- 03 1.28E

- 01 7.25E

- 03 1.54E

- 01 1.41E

- 02**Table 13. Well Completion Scenario**

**– GHG Emissions** 

**Air Emission Sources Scenario 1**  **Scenario 2 Scenario 3**  **Scenario 4 EPN(s)**  Gas Well Completion Oil Well Completion Stimulation Vessel Third Party Equipment lb/day tpy lb/day tpy lb/day tpy lb/day tpy

DR

- WC

- 01 Tubing Running Pumps

- - - - - - 2,529 36 .03

DR

- WC

- 02 Fluid Filtration Pack

- - - - 2,760 57.95 2,760 57.95

DR

- WC

- 03 E

- Line Power Pack

- - - - - - 6,184 92.76

DR

- WC

- 07 CT Power Pack

- - - - - - 16,491 247 .37

DR

- WC

- 08 CT Pump

- - - - - - 23,637 354.56 All sources with EPN starting with TB Tug

- - 483,740 5,079

- - - - BG

- LP

- 01 Barge

- - 14,842 155.84

- - - - DR

- WC

- 05 Flowback Boiler 30,571 91.71 30,571 91.71

- - - - DR

- WC

- 06 Boom Flare 7,017,407 21,052 4,678,272 14,035

- - - - DR

- WC

- 04 Slickline Power Pack

- - - - - - 3,465 103.94
All sources starts with SV Stimulation Vessel Engines

- - - - 398,655 7,216

- - DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 231,234 24,092 184,988 19,274 272,857 28,429 351,476 31,320
All sources with EPN star ting with SB Supply Boats 129,014 20,080

- - - - 369,247 38,402

DR

- PO

- 01 Painting (paint + thinner)

- - - - - - - - DR

- WC

- 09, DR

- WC

- 10 Wire Line Engines no. 3 and 4

- - - - - - 15,117 453.51

DR

- GE

- 08 ROV Emergency Generator 486.72 24.336 486.72 24.336 486.72 24.336 486.72 24.336

DR

- AC

- 01 Air Compressor Diesel Engine #1 10.31 0.54 10.31 0.54 10.31 0.54 10.31 0.54

DR

- AC

- 02 Air Compressor Diesel Engine #2 8.59 0.45 8.59 0.45 8.59 0.45 8.59 0.45

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 122.538 12.254 122.538 12.254 122.538 12.254 122.538 12.25

DR

- FL

- 01 Diesel Powered Forklift Engine 412.28 42.88 274.853 28.583 824.56 85.75 824.56 85.75

DR

- FR

- 01 Fast Rescue Craft 131.70 13.17 131.70 13.17 131.70 13.17 131.70 13.17

DR

- WB

- 01 Water Blasting Engine 2,858.47 297.28 2,858.47 297.28 2,858.47 297.28 2,858.47 297.28

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- - - - - - - -
DR

- WO

- 01 Welding

- - - - - - - - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- - - - - - - -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - - - - - - - DR

- FE

- 01 Drillship Fugitive Emissions

- - - - - - - -
DR

- VG

- 01 Mud Degasser Vent 2,713 282 .229 2,713 282.229 2,713 282.229 2,713 282.229

WC

- CT

- 01 through WC

- CT

- 03 Well Completion Condensate Tanks 1 to 3

- - - - - - - -
**Total Emissions** 7,414,972 65,989 5,399,020 39,294 681,428 36,419 798,062 71,784Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX F

**– REVISED DRILLING SCE**  **NARIO Table 3** 

**. Drilling**  **Scenario**

**– Emission Source Summary** 

**Air Emission Sources Unit**  **Drilling Scenario EPN(s)**  per day per year
DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator bbls 425 67,600
All sources with EPN starting with SB Supply Boats bbls 415 86,320

DR

- PO

- 01 Painting (paint + thinner) gals 34

-
DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 hours 24 1,440

DR

- GE

- 08 ROV Emergency Generator hours 1 100

DR

- AC

- 01 Air Compressor Diesel Engine #1 hours 0.5 104

DR

- AC

- 02 Air Compressor Diesel Engine #2 hours 0.5 104

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 hours 0.5 100

DR

- FL

- 01 Diesel Powered Forklift Engine hours 24 4,992

DR

- FR

- 01 Fast Rescue Craft hours 0.5 100

DR

- WB

- 01 Water Blasting Engine hours 12 2,496

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 hours 24 4,992

DR

- WO

- 01 Welding lbs 50 10,400

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks hours 24 4,992

DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks hours 24 4,992

DR

- FE

- 01 Drillship Fugitive Emissions hours 24 4,992

DR

- VG

- 01 Mud Degasser Vent hours 24 4,992

DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 hours 24 4,992

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 hours 24 4,992

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 hours 24 125**T able**  **4**

**. Drilling**  **Scenario**

**– PM Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 240.28 19.14 All sources with EPN starting with SB Supply Boats 114.65 11.92

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.13

DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.01

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.24 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 1.58 0.17

DR

- FR

- 01 Fast Rescue Craft 0.08 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.05 0.74

DR

- WO

- 01 Welding 1.92 0.2 0

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 2.93 0.30

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 4.73 0.49

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 36.96 0.10
**Total Emissions** 415.72 33.70**Table 5. Drilling**  **Scenario**

**– PM**  **10 Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 137.68 10.97 All sources with EPN starting with SB Supply Boats 94.26 9.8

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.13

DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.01

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.24 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 1.58 0.17

DR

- FR

- 01 Fast Rescue Craft 0.08 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.05 0.74

DR

- WO

- 01 Welding 1.92 0.2 0

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 2.93 0.30

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 4.73 0.49

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 36.96 0.10

**Total Emissions** 290.37 23.16**Table 6. Drilling**  **Scenario**

**– PM**  **2.5 Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 133.59 10.64 All sources with EPN starting with SB Supply Boats 91.46 9.51

DR

- PO

- 01 Painting (paint + thinner) 2.54 0.13

DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 4.34 0.13

DR

- GE

- 08 ROV Emergency Generator 0.14 0.01

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.03E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 8.58E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.24 0.03

DR

- FL

- 01 Diesel Powered Forklift Engine 1.58 0.1 7

DR

- FR

- 01 Fast Rescue Craft 0.08 7.56E

- 03

DR

- WB

- 01 Water Blasting Engine 0.82 0.09

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3 4.05 0.74

DR

- WO

- 01 Welding 1.92 0.2 0

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 2.93 0.30

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 4.73 0.49

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 36.96 0.10

**Total Emissions** 283.49 22.55**Table 7. Drilling**  **Scenario**

**– NO**  **X Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 8,670 690.83 All sources with EPN starting with SB Supply Boats 4189 435.62

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 143.23 4.3 0

DR

- GE

- 08 ROV Emergency Generator 4 .47 0.22

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.28 0.01

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.23 0.01

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 3.32 0.42

DR

- FL

- 01 Diesel Powered Forklift Engine 22.32 2.32

DR

- FR

- 01 Fast Rescue Craft 1.42 0.14

DR

- WB

- 01 Water Blasting Engine 16.41 1.71

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 64.37 6.69

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 156.25 16.25

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 410.06 1.07

**Total Emissions** 13,682 1,160**Table 8** 

**. Drilling**  **Scenario**

**– SO**  **2 Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 3.85 0.31 All sources with EPN starting with SB Supply Boats 3.91 0.41

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 0.15 4.44E

- 03

DR

- GE

- 08 ROV Emergency Generator 4.77E

- 03 2.38E

- 04

DR

- AC

- 01 Air Compressor Diesel Engine #1 1.01E

- 04 5.25E

- 06

DR

- AC

- 02 Air Compressor Diesel Engine #2 8.41E

- 05 4.37E

- 06

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 1.20E

- 03 1.53E

- 04

DR

- FL

- 01 Diesel Powered Forklift Engine 8.08E

- 03 8.40E

- 04

DR

- FR

- 01 Fast Rescue Craft 1.29E

- 03 1.29E

- 04

DR

- WB

- 01 Water Blasting Engine 2.80E

- 02 2.91E

- 03

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 6.65E

- 02 6.92E

- 03

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 1.62E

- 01 1.68E

- 02

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 1.88E

- 01 4.91E

- 04

**Total Emissions** 8.37 0.75**Table 9** 

**. Drilling**  **Scenario**

**– H**  **2 SO**  **4 Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 1.20E

- 01 9.58E

- 03 All sources with EPN starting with SB Supply Boats 1.22E

- 01 1.27E

- 02

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 4.63E

- 03 1.39E

- 04

DR

- GE

- 08 ROV Emergency Generator 1.49E

- 04 7.45E

- 06

DR

- AC

- 01 Air Compressor Diesel Engine #1 3.15E

- 06 1.64E

- 07

DR

- AC

- 02 Air Compressor Diesel Engine #2 2.63E

- 06 1.37E

- 07

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 3.75E

- 05 4.76E

- 06

DR

- FL

- 01 Diesel Powered Forklift Engine 2.52E

- 04 2.62E

- 05

DR

- FR

- 01 Fast Rescue Craft 4.03E

- 05 4.03E

- 06

DR

- WB

- 01 Water Blasting Engine 8.75E

- 04 9.10E

- 05

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 2.08E

- 03 2.16E

- 04

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 5.05E

- 03 5.25E

- 04

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 5.89E

- 03 1.53E

- 05

**Total Emissions** 2.61E

- 01 2.33 E

- 02**Table 10** 

**. Drilling**  **Scenario**

**– CO Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 546.18 43.52 All sources with EPN starting with SB Supply Boats 2
, 900 301.57

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 75.95 2.28

DR

- GE

- 08 ROV Emergency Generator 2.45 0.12

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.06 3.13E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.05 2.61E

- 03

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.72 0.09

DR

- FL

- 01 Diesel Powered Forklift Engine 4.81 0.5

DR

- FR

- 01 Fast Rescue Craft 0.95 0.09

DR

- WB

- 01 Water Blasting Engine 14.36 1.49

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 48.77 5.07

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 82.86 8.62

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 272.49 0.71

**Total Emissions** 3,949 364.08**Table 11** 

**. Drilling**  **Scenario**

**– VOC Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 196.79 15.68 All sources with EPN starting with SB Supply Boats 224.63 23.36

DR

- PO

- 01 Painting (paint + thinner) 173.14 9 .00

DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 33.19 1 .00

DR

- GE

- 08 ROV Emergency Generator 1.07 0.05

DR

- AC

- 01 Air Compressor Diesel Engine #1 0.02 1.18E

- 03

DR

- AC

- 02 Air Compressor Diesel Engine #2 0.02 9.80E

- 04

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 0.27 3.42E

- 02

DR

- FL

- 01 Diesel Powered Forklift Engine 1.81 0.19

DR

- FR

- 01 Fast Rescue Craft 0.29 0.03

DR

- WB

- 01 Water Blasting Engine 6.28 0.65

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks 0.68 0.32

DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks 0.04 0.38

DR

- FE

- 01 Drillship Fugitive Emissions 0.13 0.02

DR

- VG

- 01 Mud Degasser Vent 53.56 5.57

DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 14.92 1.55

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 36.20 3.77

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 15.87 0.04

**Total Emissions** 758.90 61.66**Table 12. Drilling**  **Scenario**

**– Pb Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 6.97E

- 02 5.55E

- 03 All sources with EPN starting with SB Supply Boats 7.08E

- 01 7.36E

- 03

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 2.68E

- 03 8.04E

- 05

DR

- GE

- 08 ROV Emergency Generator 8.63E

- 05 4.31E

- 06

DR

- AC

- 01 Air Compressor Diesel Engine #1 1.83E

- 06 9.50E

- 08

DR

- AC

- 02 Air Compressor Diesel Engine #2 1.52E

- 06 7.92E

- 08

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 2.17E

- 05 2.17E

- 06

DR

- FL

- 01 Diesel Powered Forklift Engine 1.46E

- 04 1.52E

- 05

DR

- FR

- 01 Fast Rescue Craft 2.33E

- 05 2.33E

- 06

DR

- WB

- 01 Water Blasting Engine 5.07E

- 04 5.27E

- 05

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding 8.10E

- 03 8.42E

- 04

DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent

- - DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 1.20E

- 03 1.25E

- 04

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 2.92E

- 03 3.04E

- 04

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 3.41E

- 03 8.88E

- 06

**Total Emissions** 1.51E

- 01 1.44 E

- 02**Table 13. Drilling**  **Scenario**

**– GHG Emissions** 

**Air Emission Sources Drilling Scenario**  **EPN(s)** lb/day tpy

DR

- GE

- 01 through DR

- GE

- 07 Drillship Main Engines and Emergency Generator 393,098 31,320 All sources with EPN starting with SB Supply Boats 369,247 38,402

DR

- PO

- 01 Painting (paint + thinner)

- - DR

- WC

- 01, DR

- WC

- 02 Wire Line Engines no. 1 and 2 15,117 453.51

DR

- GE

- 08 ROV Emergency Generator 486.72 24.34

DR

- AC

- 01 Air Compressor Diesel Engine #1 10.31 0.54

DR

- AC

- 02 Air Compressor Diesel Engine #2 8.59 0.45

DR

- EC

- 01 through DR

- EC

- 06 Escape Capsule Diesel Engine no. 1 to 6 122.54 12.25

DR

- FL

- 01 Diesel Powered Forklift Engine 824.56 85.75

DR

- FR

- 01 Fast Rescue Craft 131.7 13.17

DR

- WB

- 01 Water Blasting Engine 2,854 297.28

DR

- DC

- 01 through DR

- DC

- 03 Dust Collectors no. 1 to 3

- -
DR

- WO

- 01 Welding

- - DR

- DT

- 01 through DR

- DT

- 09 Nine Drill Ship Diesel Storage Tanks

- -
DR

- FT

- 01 through DR

- FT

- 03 Three Drill Ship Jet Fuel Storage Tanks

- - DR

- FE

- 01 Drillship Fugitive Emissions

- -
DR

- VG

- 01 Mud Degasser Vent 2,713 282.23
DR

- CU

- 01, DR

- CU

- 02 Drilling Casing Units 1 and 2 6,794 706.61

DR

- EL

- 01, DR

- EL

- 02 Electric line diesel 1 and 2 16,491 1,715

DR

- VS

- 01 through DR

- VS

- 05 Well Evaluation Engines No. 1 to 5 19,240 50.10

**Total Emissions** 827,144 73,363Anadarko Petroleum Corporation | Discoverer Spirit EGOM PSD/Title V Permit Application Trinity Consultants 

## APPENDIX **G**

**– MATERIAL SAFETY DATA**  **SHEETS**AMERCOAT 10 THINNER Product name 

# Product and company identification

: 

# 1 .

AT10/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 22 December 2012
Version 5

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8

United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. toluene 108-88-3 30 - 60 4-methylpentan-2-one 108-10-1 30 - 60 ethanol 64-17-5 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 

# 6 .

Page: 2/8

United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# Accidental release measures 6 .

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 4-methylpentan-2-one TWA 20 ppm 100 ppm 50 ppm 50 ppm Not established STEL 75 ppm Not established 75 ppm 75 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethanol TWA Not

established 1000 ppm Not established 1000 ppm Not established STEL 1000 ppm Not established 1000 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/8 United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

= Threshold Limit Value TLV TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z STEL = =

Short term Exposure limit values

Liquid.

Not available. Not available. 

# Physical and chemical properties

Physical state

Odor Color :

:

: Flash point : Closed cup: 2.22°C (36°F) Explosion limits : Lower: 1.1% 

# 9 .

Yes. : Material supports combustion.

Page: 4/8

United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# Physical and chemical properties 9 .

>37.78°C (>100°F)

100% (v/v), 100% (w/w) Not available.

Not available.
0.84

Not available. 2.6 kPa (19.5 mm Hg) [room temperature] Boiling/condensation point Melting/freezing point

2.09 (butyl acetate = 1) pH

Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate :

:

:

:

:

:

:

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 0 Density ( lbs / gal ) : 7.01

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids, strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, the nervous system, the reproductive system, liver, heart, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. toluene LD50 Oral Rat 636 mg/kg

-

LD50 Dermal Rabbit 8.39 g/kg

- LC50 Inhalation Rat 49 g/m3 4 hours 4-methylpentan-2-one LD50 Oral Rat 2.08 g/kg

-

LC50 Inhalation Vapor Rat 32772 mg/m3 4 hours

ethanol LD50 Oral Rat 7 g/kg

-

LC50 Inhalation Rat 124700 mg/m3 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Product/ingredient name toluene A4 3

- - 4-methylpentan-2-one A3 2B

- -

ACGIH NTP OSHA IARC

Page: 5/8 United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# 11 . Toxicological information

Teratogenicity Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair female fertility, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: -



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 4-methylpentan-2-one Acute LC50 505000 to 514000 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 4 days

_________________________________ ________________________________ __________ Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

Page: 6/8 United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT RELATED MATERIAL 3 II Additional information

- IMDG 1263 PAINT RELATED MATERIAL 3

-

II

DOT Reportable quantity

1706. 6 lbs / 774.8 kg [244.37 gal / 925.03 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT RELATED MATERIAL II

CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: 4-methylpentan-2-one: 5000 lbs. (2270 kg); toluene: 1000 lbs. (454 kg);

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : 4-methylpentan-2-one; toluene

Supplier notification : toluene 108-88-3 30 - 60 4-methylpentan-2-one 108-10-1 30 - 60 SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

toluene 108-88-3 Y Y Y N N 4-methylpentan-2-one 108-10-1 Y Y Y N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N

Chemical name

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada

Page: 7/8

United States - Canada - Mexico

### AMERCOAT 10 THINNER Product name 5 Product code Date of issue Version 

### AT10/05 22 December 2012



# 15 . Regulatory information

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). :

Mexico

3 2 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 7/30/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 8/8

United States - Canada - MexicoAMERCOAT 65 THINNER Product name 

# Product and company identification

: 

# 1 .

AT765/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 22 December 2012
Version 7

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not swallow. Avoid breathing vapor or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY BE HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. Harmful in contact with skin. Irritating to skin.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. xylene 1330-20-7 60 - 100 ethylbenzene 100-41-4 10 - 30 toluene 108-88-3 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 

# 6 .

Page: 2/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# Accidental release measures 6 .

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not established STEL 150 ppm Not established 150 ppm 150 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not established STEL Not established Not established 125 ppm 125 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/8 United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

= Threshold Limit Value TLV TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z STEL = =

Short term Exposure limit values

Liquid.

Not available. Not available. 

# Physical and chemical properties

Physical state

Odor Color :

:

: Flash point : Closed cup: 27.22°C (81°F) Explosion limits : Lower: 1% 

# 9 .

Yes. : Material supports combustion.

Page: 4/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# Physical and chemical properties 9 .

>37.78°C (>100°F)

100% (v/v), 100% (w/w) Not available.

Not available.
0.87

Not available. 0.85 kPa (6.4 mm Hg) [room temperature] Boiling/condensation point Melting/freezing point

0.63 (butyl acetate = 1) pH

Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate :

:

:

:

:

:

:

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 0 Density ( lbs / gal ) : 7.26

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids, strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, liver, gastrointestinal tract, cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. xylene LD50 Oral Rat 4.3 g/kg

-

LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours

ethylbenzene LD50 Oral Rat 3.5 g/kg

-

LD50 Dermal Rabbit >5000 mg/kg

- LC50 Inhalation Vapor Rat 4000 ppm 4 hours

toluene LD50 Oral Rat 636 mg/kg

-

LD50 Dermal Rabbit 8.39 g/kg

- LC50 Inhalation Rat 49 g/m3 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 5/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# 11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair female fertility, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - Product/ingredient name xylene A4 3

- - ethylbenzene A3 2B

- - toluene A4 3

- -

ACGIH NTP OSHA IARC



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute LC50 5100 to 5700 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Acute EC50 2930 to 4400 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or Waste disposal 

# Disposal considerations

: 

# 13 .

Page: 6/8

United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# Disposal considerations 13 .

explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1307 XYLENES 3 III Additional information

-
IMDG 1307 XYLENES 3

-

III

DOT Reportable quantity

118. 22 lbs / 53.674 kg [16. 389 gal / 62.04 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1307 3 XYLENES III

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45. 4 kg);

CAS number Concentration SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : ethylbenzene; xylene

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

xylene 1330-20-7 Y N Y N N ethylbenzene 100-41-4 Y Y Y N N toluene 108-88-3 Y Y Y N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N

Chemical name

Page: 7/8 United States - Canada - Mexico

### AMERCOAT 65 THINNER Product name 7 Product code Date of issue Version 

### AT765/05 22 December 2012



# 15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification : xylene 1330-20-7 60 - 100 ethylbenzene 100-41-4 10 - 30

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 2 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 5/18/2011. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 8/8

United States - Canada - MexicoDIMETCOTE 9 LIQUID Product name 

# Product and company identification

: 

# 1 .

DI9-A/05 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 23 January 2013
Version 6.01

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.

Harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes, nose, mouth and throat.

Irritating to eyes. May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. propan-2-ol 67-63-0 15 - 40 Silicic acid, ethyl ester 11099-06-2 10 - 30 Kaolin 1332-58-7 7 - 13 1-methoxy-2-propanol 107-98-2 5 - 10 tetraethyl silicate 78-10-4 5 - 10 toluene 108-88-3 1 - 5 Mica-group minerals 12001-26-2 1 - 5 ethanol 64-17-5 0.1 - 1 zinc chloride 7646-85-7 0.1 - 1 Quartz (SiO2) (<10 microns) 14808-60-7 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product :

Page: 2/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Consult local authorities for acceptable exposure limits. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value

TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z propan-2-ol TWA 200 ppm 400 ppm 200 ppm 400 ppm Not established STEL 400 ppm Not established 400 ppm 500 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Kaolin TWA 2 mg/m3 R 5 mg/m3 R

15 mg/m3 TD 2 mg/m3 R 10 mg/m3 Not

established STEL Not established Not established Not established 20 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1-methoxy-2-propanol TWA 100 ppm Not

established 100 ppm Not established Not established STEL 150 ppm Not established 150 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ tetraethyl silicate TWA 10 ppm 100 ppm 10 ppm 10 ppm Not established STEL Not established Not established Not established 30 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not established STEL Not established 500 ppm Z A 300 ppm Z C Not established Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Mica-group minerals TWA 3 mg/m3 R 20 mppcf Z 3 mg/m3 R 3 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethanol TWA Not

established 1000 ppm Not established 1000 ppm Not established STEL 1000 ppm Not established 1000 ppm Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ zinc chloride TWA 1 mg/m3 F 1 mg/m3 F 1 mg/m3 F 1 mg/m3 Not established STEL 2 mg/m3 F Not established 2 mg/m3 F 2 mg/m3 Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Quartz (SiO2) (<10 microns) TWA 0.025 mg/m3

R 10 mg/m3 R Z 30 mg/m3 TD Z 250 mppcf R Z 0.1 mg/m3 R 0.1 mg/m3 R Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL = =

Short term Exposure limit values

Page: 4/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# Exposure controls/personal protection 8 .

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Gloves : For prolonged or repeated handling, use the following type of gloves:

Recommended: nitrile rubber Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

76% (v/v), 60.65% (w/w) Not available.

Not available.
1.02

Not available. 4 kPa (30.3 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point

2.54 (butyl acetate = 1) 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate Odor Color :

:

:

:

:

:

:

:

:

:

: Flash point : Closed cup: 15.56°C (60°F) Explosion limits : Lower: 1.8% 

# 9 .

Density ( lbs / gal ) : 8.51 Yes. : Material supports combustion.

Page: 5/9

United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# Physical and chemical properties 9 .

Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 39.35

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,water,acids,oxidizing materials, strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid increased storage temperature. Pressure hazard 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :
:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, lungs, the reproductive system, liver, heart, spleen, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea, stomach, testes. propan-2-ol LD50 Oral Rat 4.396 g/kg

-

LD50 Dermal Rabbit 12800 mg/kg

- LC50 Inhalation Vapor Rat 72600 mg/m3 4 hours

Kaolin LD50 Oral Rat >5000 mg/kg

- 1-methoxy-2-propanol LD50 Oral Rat 5.2 g/kg

-

LD50 Dermal Rabbit 13 g/kg

- tetraethyl silicate LD50 Oral Rat 6.27 g/kg

-

LD50 Dermal Rabbit 5.878 g/kg

- toluene LD50 Oral Rat 636 mg/kg

-

LD50 Dermal Rabbit 8.39 g/kg

- LC50 Inhalation Rat 49 g/m3 4 hours ethanol LD50 Oral Rat 7 g/kg

-

LC50 Inhalation Rat 124700 mg/m3 4 hours zinc chloride LD50 Oral Rat 0.35 g/kg

- Product/ingredient name Result Species Dose Exposure Acute toxicity

Product/ingredient name propan-2-ol A4 3

- - Kaolin A4

- - - toluene A4 3

- - Quartz (SiO2) (<10 microns) A2 1 Proven.

-

ACGIH NTP OSHA IARC

Page: 6/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# 11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair male fertility, based on animal data. Contains material which may impair female fertility, based on animal data. Teratogenicity : Contains material which may cause birth defects, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: -



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

propan-2-ol Acute LC50 >1400000 ug/L Fish - Bluegill - Lepomis macrochirus 96 hours

______________________ _________________________________ ________________________________ __________ toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 4 days

_________________________________ ________________________________ __________ Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

Page: 7/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 II Additional information

- IMDG 1263 PAINT 3

-

II

DOT Reportable quantity

25002. 6 lbs / 11351.2 kg [2930 gal / 11091.2 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT II

CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

Substance Use Restricted All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) :

Philippines inventory (PICCS) :

:

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: toluene: 1000 lbs. (454 kg); zinc chloride: 1000 lbs. (454 kg);

CAS number Concentration SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : 1-methoxy-2-propanol; Kaolin; Mica-group minerals; propan-2-ol; toluene; tetraethyl silicate

Supplier notification : propan-2-ol 67-63-0 15 - 40 toluene 108-88-3 1 - 5 SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

propan-2-ol 67-63-0 Y N Y N N Silicic acid, ethyl ester 11099-06-2 Y N N N N Kaolin 1332-58-7 Y N N N N 1-methoxy-2-propanol 107-98-2 Y N Y N N tetraethyl silicate 78-10-4 Y N Y Y N toluene 108-88-3 Y Y Y N N Mica-group minerals 12001-26-2 N N N N N zinc chloride 7646-85-7 Y Y N Y N Quartz (SiO2) (<10 microns) 14808-60-7 N Y N N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y Y N

Chemical name

Page: 8/9 United States - Canada - Mexico

### DIMETCOTE 9 LIQUID Product name 6.01 Product code Date of issue Version 

### DI9-A/05 23 January 2013



# 15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative.

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 3 1 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

3

1 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 12/22/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 3 *

3 1 ( * ) - Chronic effects

Page: 9/9

United States - Canada - MexicoDIMETCOTE 9/D9VOC/D9H POWDER Product name 

# Product and company identification

: 

# 1 .

DI9-P PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 26 May 2013
Version 19

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes Skin Inhalation Ingestion

See toxicological information (Section 11) WARNING! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms

Ingestion : Skin : Eyes : Inhalation : Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

May be harmful if inhaled.

No known significant effects or critical hazards. No known significant effects or critical hazards.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200). No specific data. No specific data. No specific data. No specific data.



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100 zinc oxide 1314-13-2 1 - 5 Name CAS number %

Page: 1/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use an extinguishing agent suitable for the surrounding fire. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. No specific fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : None known. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: metal oxide/oxides Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions :

Large spill : 

# 6 .

Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill :

Page: 2/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Safety glasses with side shields. Personal protection Eyes Consult local authorities for acceptable exposure limits.

: Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value

TLV TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z zinc oxide TWA 2 mg/m3 R 5 mg/m3 F

5 mg/m3 R 15 mg/m3 TD 2 mg/m3 R 10 mg/m3 5 mg/m3 Not established

STEL 10 mg/m3 R Not established 10 mg/m3 R 10 mg/m3 Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico IPEL

STEL = =

Short term Exposure limit values

Page: 3/7 United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013



# Exposure controls/personal protection 8 .

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Skin Respiratory

: :

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Not available. Solid.

0% (v/v), 0% (w/w) Not available.

Not available.
7.13

Not available. 0 kPa (0 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point

0 (butyl acetate = 1) 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate Odor Color :

:

:

:

:

:

:

:

:

:

: Flash point : Closed cup: Not applicable. [Product does not sustain combustion.] 

# 9 .

Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 100 Density ( lbs / gal ) : 59.5

The product may not be stable under certain conditions of storage or use.

Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Evolves hydrogen on contact with water. Avoid increased storage temperature. Pressure hazard 

# Stability and reactivity

Stability Conditions to avoid Materials to avoid

Hazardous decomposition products Hazardous polymerization :
:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Target organs : Contains material which may cause damage to the following organs: lungs. Acute toxicity

Page: 4/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013



# Ecological information

Environmental effects : Water polluting material. May be harmful to the environment if released in large quantities. 

# 12 .

Aquatic ecotoxicity

Zinc powder - zinc dust (stabilized) Acute LC50 0.41 mg/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide) 9 III Additional information

-

IMDG 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide). Marine pollutant (Zinc powder - zinc dust (stabilized), zinc oxide) 9

-

III

DOT Reportable quantity

1041. 7 lbs / 472.92 kg Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 3077 9 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc powder - zinc dust (stabilized), zinc oxide) III

CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg); Reportable quantity RQ : PG* : Packing group

Page: 5/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: zinc oxide; Zinc powder - zinc dust (stabilized): 1000 lbs. (454 kg);

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SARA 302/304 : No products were found.

Supplier notification : Zinc powder - zinc dust (stabilized) 7440-66-6 60 - 100 zinc oxide 1314-13-2 1 - 5 SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification:

zinc oxide 1314-13-2 N N N N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : N N N Y N

Chemical name

WHMIS (Canada) None identified. : Canada

Mexico

0 1 1 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

0

1 0 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer Date of previous issue 12/22/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 1

1 1 ( * ) - Chronic effects

Page: 6/7

United States - Canada - Mexico

### DIMETCOTE 9/D9VOC/D9H POWDER Product name 19 Product code Date of issue Version 

### DI9-P 26 May 2013



# Other information 16 .

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Page: 7/7

United States - Canada - MexicoAMERCOAT 450H YELLOW RAL 1023 RESIN Product name 

# Product and company identification

: 

# 1 .

AT45H813 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 25 August 2012
Version 17

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) WARNING! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. SKIN CONTACT TO ISOCYANATE MONOMER MAY LEAD TO ALLERGIC LUNG REACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Irritating to eyes. Moderately irritating to the skin.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. n-butyl acetate 123-86-4 10 - 30 Wollastonite (Ca(SiO3)) 13983-17-0 5 - 10 Nepheline syenite 37244-96-5 5 - 10 2-methoxy-1-methylethyl acetate 108-65-6 3 - 7 titanium dioxide 13463-67-7 1 - 5 Solvent naphtha (petroleum), light arom. 64742-95-6 0.5 - 1.5 xylene 1330-20-7 0.1 - 1 1,2,4-trimethylbenzene 95-63-6 0.1 - 1 4-isocyanatosulphonyltoluene 4083-64-1 0.1 - 1 naphthalene 91-20-3 0.1 - 1 ethylbenzene 100-41-4 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide/oxides Flammability of the product :

Page: 2/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Special provisions : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Place in a suitable container. The contaminated area should be cleaned immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts) and water (95 parts). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container. Once this stage is reached, close container and dispose of according to local regulations (see section 13). Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling : 

# 7 .

Page: 3/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# Handling and storage 7 .
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Precautions should be taken to minimize exposure to atmospheric humidity or water. CO2 will be formed, which, in closed containers, could result in pressurization. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Storage :



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Consult local authorities for acceptable exposure limits. = Threshold Limit Value

TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not

established STEL 200 ppm Not established 200 ppm 200 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Nepheline syenite TWA Not established Not established 10 mg/m3 TD Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 2-methoxy-1-methylethyl acetate TWA Not established Not established 50 ppm Not established 50 ppm

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ titanium dioxide TWA 10 mg/m3 15 mg/m3 TD 10 mg/m3 TD 10 mg/m3

(as Ti) Not established STEL Not established Not established Not established 20 mg/m3 (as Ti) Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not

established STEL 150 ppm Not established 150 ppm 150 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1,2,4-trimethylbenzene TWA 25 ppm Not established 25 ppm 25 ppm Not established STEL Not established Not established Not established 35 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ naphthalene TWA 10 ppm 10 ppm 10 ppm 10 ppm Not

established STEL 15 ppm Not established 15 ppm 15 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not

established STEL Not established Not established 125 ppm 125 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

STEL = =

Short term Exposure limit values

Page: 4/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# Exposure controls/personal protection 8 .

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : butyl rubber Gloves : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

Not available.

Not available.
1.22

Not available. 1.9 kPa (13.9 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Odor Color :

:

:

:

:

:

:

:

: Flash point : Closed cup: 36.11°C (97°F) Explosion limits : Lower: 1.3% 

# 9 .

Density ( lbs / gal ) : 10.18

Page: 5/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# Physical and chemical properties 9 .

32% (v/v), 23.29% (w/w) 0.83 (butyl acetate = 1) Volatility Evaporation rate :

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 76.71

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water, resulting in the production of carbon dioxide. In closed containers, pressure buildup could result in distortion, expansion and, in extreme cases, bursting of the container. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS). Contains material which may cause damage to the following organs: kidneys, lungs, upper respiratory tract, skin, eye, lens or cornea. n-butyl acetate LD50 Oral Rat 10.768 g/kg

- LD50 Dermal Rabbit >17600 mg/kg

- LC50 Inhalation Rat >21.1 mg/l 4 hours 2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg

- LD50 Dermal Rabbit >5 g/kg

- titanium dioxide LD50 Oral Rat >10 g/kg

- Solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg

- LD50 Dermal Rabbit 3.48 g/kg

- xylene LD50 Oral Rat 4.3 g/kg

- LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours

1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg

- LC50 Inhalation Rat 18000 mg/m3 4 hours 4-isocyanatosulphonyltoluene LD50 Oral Rat >0.5 g/kg

- naphthalene LD50 Oral Rat 490 mg/kg

- LD50 Dermal Rabbit >20 g/kg

- ethylbenzene LD50 Oral Rat 3.5 g/kg

- LD50 Dermal Rabbit >5000 mg/kg

- LC50 Inhalation Vapor Rat 4000 ppm 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 6/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# 11 . Toxicological information

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer. Risk of cancer depends on duration and level of exposure.

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5 IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - Product/ingredient name titanium dioxide A4 2B

- - naphthalene A4 2B Possible

- ethylbenzene A3 2B

- - ACGIH NTP OSHA IARC



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

n-butyl acetate Acute LC50 18000 to 19000 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ 1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ naphthalene Acute EC50 1.96 mg/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 600 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute LC50 5100 to 5700 ug/L Marine water Fish - Atlantic silverside - Menidia menidia 96 hours

_________________________________ ________________________________ __________ Acute EC50 2930 to 4400 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia menidia 96 hours

_________________________________ ________________________________ __________ Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been Waste disposal 

# Disposal considerations

: 

# 13 .

Page: 7/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# Disposal considerations 13 .

cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 III Additional information

-
IMDG 1263 PAINT 3

-

III

DOT Reportable quantity

17858 lbs / 8107.5 kg [1752.2 gal / 6632.7 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT III

CERCLA: Hazardous substances.: xylene: 100 lbs. (45.4 kg); n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); naphthalene: 100 lbs. (45.4 kg); acetone: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

At least one component is not listed. All components are listed or exempted. At least one component is not listed.

Not determined.

Substance Use Restricted At least one component is not listed. At least one component is not listed. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) :

Philippines inventory (PICCS) : :

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

United States U.S. Federal regulations :

CERCLA: Hazardous substances.: xylene: 100 lbs. (45.4 kg); n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); naphthalene: 100 lbs. (45.4 kg); acetone: 5000 lbs. (2270 kg); SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : 2-methoxy-1-methylethyl acetate; n-butyl acetate; titanium dioxide

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification: Chemical name CAS # Acute Chronic Fire Reactive Pressure

Page: 8/9 United States - Canada - Mexico

### AMERCOAT 450H YELLOW RAL 1023 RESIN Product name 17 Product code Date of issue Version 

### AT45H813 25 August 2012



# 15 . Regulatory information

SARA 313 CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification : naphthalene 91-20-3 0.1 - 1 ethylbenzene 100-41-4 0.1 - 1 n-butyl acetate 123-86-4 Y N Y N N 2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N titanium dioxide 13463-67-7 N Y N N N Solvent naphtha (petroleum), light

arom. 64742-95-6 Y N Y N N

4-isocyanatosulphonyltoluene 4083-64-1 Y N N Y N naphthalene 91-20-3 Y Y N Y N ethylbenzene 100-41-4 Y Y Y N N Product as-supplied : Y Y Y N N

Chemical name

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 2 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)
3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 6/6/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 9/9 United States - Canada - MexicoAMERCOAT 450H GRAY RAL 7037 RESIN Product name 

# Product and company identification

: 

# 1 .

AT45H251 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 20 May 2013
Version 17

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) WARNING! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. SKIN CONTACT TO ISOCYANATE MONOMER MAY LEAD TO ALLERGIC LUNG REACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation.

Irritating to eyes. May cause skin dryness and irritation.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. n-butyl acetate 123-86-4 10 - 30 Nepheline syenite 37244-96-5 7 - 13 Wollastonite (Ca(SiO3)) 13983-17-0 7 - 13 titanium dioxide 13463-67-7 3 - 7 2-methoxy-1-methylethyl acetate 108-65-6 1 - 5 xylene 1330-20-7 0.1 - 1 1,2,4-trimethylbenzene 95-63-6 0.1 - 1 carbon black respirable 1333-86-4 0.1 - 1 4-isocyanatosulphonyltoluene 4083-64-1 0.1 - 1 ethylbenzene 100-41-4 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product :

Page: 2/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Special provisions : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Place in a suitable container. The contaminated area should be cleaned immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts) and water (95 parts). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container. Once this stage is reached, close container and dispose of according to local regulations (see section 13). Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling : 

# 7 .

Page: 3/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# Handling and storage 7 .

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Precautions should be taken to minimize exposure to atmospheric humidity or water. CO2 will be formed, which, in closed containers, could result in pressurization. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Storage :



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Consult local authorities for acceptable exposure limits. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not established STEL 200 ppm Not established 200 ppm 200 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Nepheline syenite TWA Not

established Not established 10 mg/m3 TD Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ titanium dioxide TWA 10 mg/m3 15 mg/m3 TD 10 mg/m3 TD 10 mg/m3 (as Ti) Not established STEL Not established Not established Not established 20 mg/m3 (as Ti) Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 2-methoxy-1-methylethyl acetate TWA Not

established Not established 50 ppm Not established 50 ppm

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not established STEL 150 ppm Not established 150 ppm 150 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1,2,4-trimethylbenzene TWA 25 ppm Not

established 25 ppm 25 ppm Not

established STEL Not established Not established Not established 35 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ carbon black respirable TWA 3 mg/m3 3.5 mg/m3 3.5 mg/m3 3.5 mg/m3 Not established STEL Not established Not established Not established 7 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not established STEL Not established Not established 125 ppm 125 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico IPEL

STEL = =

Short term Exposure limit values

Page: 4/9 United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# Exposure controls/personal protection 8 .

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : butyl rubber Gloves : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

Not available.

Not available. 1.3

Not available. 1.9 kPa (14.1 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Odor Color :

:

:

:

:

:

:

:

: Flash point : Closed cup: 36.11°C (97°F) Explosion limits : Lower: 1.4% 

# 9 .

Density ( lbs / gal ) : 10.85

Page: 5/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# Physical and chemical properties 9 .

32% (v/v), 22.07% (w/w) 0.87 (butyl acetate = 1) Volatility Evaporation rate :

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 77.93

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water, resulting in the production of carbon dioxide. In closed containers, pressure buildup could result in distortion, expansion and, in extreme cases, bursting of the container. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: kidneys, lungs, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. n-butyl acetate LD50 Oral Rat 10.768 g/kg

-

LD50 Dermal Rabbit >17600 mg/kg

- LC50 Inhalation Rat >21.1 mg/l 4 hours titanium dioxide LD50 Oral Rat >10 g/kg

- 2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg

-

LD50 Dermal Rabbit >5 g/kg

- xylene LD50 Oral Rat 4.3 g/kg

-

LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours

1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg

-

LC50 Inhalation Rat 18000 mg/m3 4 hours carbon black respirable LD50 Oral Rat >15400 mg/kg

-

LD50 Dermal Rabbit >3 g/kg

- 4-isocyanatosulphonyltoluene LD50 Oral Rat >0.5 g/kg

- ethylbenzene LD50 Oral Rat 3.5 g/kg

-

LD50 Dermal Rabbit >5000 mg/kg

- LC50 Inhalation Vapor Rat 4000 ppm 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 6/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# 11 . Toxicological information

Classification

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - Product/ingredient name titanium dioxide A4 2B

- - carbon black respirable A3 2B

- - ethylbenzene A3 2B

- -

ACGIH NTP OSHA IARC



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

n-butyl acetate Acute LC50 18000 to 19000 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ 1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute LC50 5100 to 5700 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Acute EC50 2930 to 4400 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Page: 7/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# Disposal considerations 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 III Additional information

- IMDG 1263 PAINT 3

-

III

DOT Reportable quantity

19466. 4 lbs / 8837.7 kg [1792. 9 gal / 6787 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT III

CERCLA: Hazardous substances.: n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); acetone: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

At least one component is not listed. All components are listed or exempted. All components are listed or exempted.

At least one component is not listed.

Substance Use Restricted At least one component is not listed. At least one component is not listed. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) :

Philippines inventory (PICCS) :

:

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); acetone: 5000 lbs. (2270 kg);

CAS number Concentration SARA 302/304 : 1,4-dihydroxybenzene

SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification:

n-butyl acetate 123-86-4 Y N Y N N titanium dioxide 13463-67-7 N Y N N N 2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N carbon black respirable 1333-86-4 N Y N N N 4-isocyanatosulphonyltoluene 4083-64-1 Y N N Y N ethylbenzene 100-41-4 Y Y Y N N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y Y Y N N

Chemical name United States - TSCA 5(a)2 - Final significant new use rules: mercury Listed United States - TSCA 5(a)2 - Proposed significant new use rules: mercury Listed

Page: 8/9

United States - Canada - Mexico

### AMERCOAT 450H GRAY RAL 7037 RESIN Product name 17 Product code Date of issue Version 

### AT45H251 20 May 2013



# 15 . Regulatory information

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification : ethylbenzene 100-41-4 0.1 - 1

California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 2 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 9/18/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 9/9

United States - Canada - MexicoAMERCOAT 450H CURE Product name 

# Product and company identification

: 

# 1 .

AT45H-B PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. EST 

# Material Safety Data Sheet

Date of issue 8 June 2010 Version 7

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes Skin Inhalation

Ingestion

See toxicological information (section 11) WARNING! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory and skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Based on the properties of the isocyanate components and considering toxicological data on similar preparations, this preparation may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION. SKIN CONTACT TO ISOCYANATE MONOMER MAY LEAD TO ALLERGIC LUNG REACTION. MAY BE HARMFUL IF SWALLOWED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

Harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Severely irritating to eyes. Risk of serious damage to eyes. Moderately irritating to the skin. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Isocyanic acid, hexamethylene ester, polymers 28182-81-2 40 - 70 n-butyl acetate 123-86-4 15 - 40 Solvent naphtha (petroleum), light arom. 64742-95-6 1 - 5 1,2,4-trimethylbenzene 95-63-6 0.5 - 1.5 xylene 1330-20-7 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Use dry chemical, CO 2 , water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides Hydrogen cyanide (HCN). Cyanate and isocyanate. Flammability of the product :

Page: 2/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Special provisions : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Place in a suitable container. The contaminated area should be cleaned immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts) and water (95 parts). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container. Once this stage is reached, close container and dispose of according to local regulations (see section 13). Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling : 

# 7 .

Page: 3/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Handling and storage 7 .
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Precautions should be taken to minimize exposure to atmospheric humidity or water. CO

2 will be formed, which, in closed containers, could result in pressurization. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Storage :



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit = Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS TD = Total dust Key to abbreviations

Personal protection Consult local authorities for acceptable exposure limits.

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous

Substances = Z Isocyanic acid, hexamethylene ester, polymers TWA Not established Not established Not established Not established 0.5 mg/m3

STEL Not established Not established Not established Not established 1 mg/m3

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not

established STEL 200 ppm Not established 200 ppm 200 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1,2,4-trimethylbenzene TWA 25 ppm Not established 25 ppm 25 ppm Not established STEL Not established Not established Not established 35 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not

established STEL 150 ppm Not established 150 ppm 150 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

Page: 4/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Exposure controls/personal protection 8 .

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Eyes

Skin Respiratory :

: : butyl rubber Gloves :

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

>37.78°C (>100°F) Liquid.

45% (v/v), 38.42% (w/w) Not available.

Not available.
1.04

Not available. 0.99 kPa (7.4 mm Hg)

Not available. Not available. Not available.

Boiling/condensation point Melting/freezing point

93 (butyl acetate = 1) 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Volatility Odor threshold Evaporation rate Odor Color :

:

:

:

:

:

:

:

:

:

:

: Flash point : Closed cup: 33.33°C (92°F) Explosion limits : Lower: 1.6% 

# 9 .

Octanol/water partition coefficient : Not available.

% Solid. (w/w) : 61.58 Density ( lbs / gal ) : 8.68

The product may not be stable under certain conditions of storage or use. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water, resulting in the production of carbon dioxide. In closed containers, pressure buildup could result in distortion, expansion and, in extreme cases, bursting of the container. Avoid increased storage temperature. Pressure hazard 

# Stability and reactivity

Stability Conditions to avoid :

: 

# 10 .

Page: 5/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Stability and reactivity 10 .
Reactive or incompatible with the following materials:,oxidizing materials,strong acids,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Cyanate and isocyanate. Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

: 

# Toxicological information 11 .

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Mutagenicity

Teratogenicity

Reproductive toxicity Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS). Contains material which may cause damage to the following organs: blood, upper respiratory tract, skin, eyes. Isocyanic acid, hexamethylene ester, polymers LC50 Inhalation Rat 18500 mg/m3 1 hours

n-butyl acetate LD50 Oral Rat 10.768 g/kg

- LD50 Dermal Rabbit >17600 mg/kg

- LC50 Inhalation Vapor Rat 390 ppm 4 hours

Solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg

- LD50 Dermal Rabbit 3.48 g/kg

- 1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg

- LC50 Inhalation Rat 18000 mg/m3 4 hours xylene LD50 Oral Rat 4.3 g/kg

- LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity Product/ingredient

name Species Result Exposure

Page: 6/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Ecological information 12 .

Other adverse effects : No known significant effects or critical hazards. n-butyl acetate Acute LC50 18000 to 19000 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ 1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________

The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via alicensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and

sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 Paint. 3 III Additional information

- IMDG 1263 Paint. 3

-

III

DOT

- 1263 3 Paint. III

CERCLA: Hazardous substances.: xylene: 100 lbs. (45.4 kg); butan-1-ol: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group



# Regulatory information

U.S. Federal regulations : United States 

# 15 .

TSCA 12(b) annual export notification : No products were found. TSCA 12(b) one-time export : No products were found. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) : :

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

Page: 7/8 United States - Canada - Mexico

### AMERCOAT 450H CURE Product name 7 Product code Date of issue Version 

### AT45H-B 8 June 2010



# Regulatory information 15 .

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : 1,2,4-trimethylbenzene; n-butyl acetate SARA 311/312 MSDS distribution - chemical inventory - hazard identification : 1,2,4- trimethylbenzene: Fire hazard, Delayed (chronic) health hazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard

: SARA 313

Canada

Mexico

3 3 1 Health Flammability Reactivity Classification CERCLA: Hazardous substances.: xylene: 100 lbs. (45.4 kg); butan-1-ol: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg);

: : : Product name CAS number Concentration 1,2,4-trimethylbenzene 95-63-6 0.5 - 1.5 Form R - Reporting requirements :

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative.



# Other information

Hazardous Material Information System (U.S.A.)
3

1 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue No previous validation. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 3 *

3 1 ( * ) - Chronic effects

Page: 8/8 United States - Canada - MexicoAMERCOAT 450H HAZE GRAY F/S 26270 R Product name 

# Product and company identification

: 

# 1 .

AT45H20 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 15 April 2013
Version 26

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) WARNING! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT AND EYE IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. SKIN CONTACT TO ISOCYANATE MONOMER MAY LEAD TO ALLERGIC LUNG REACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation.

Irritating to eyes. Moderately irritating to the skin.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. n-butyl acetate 123-86-4 10 - 30 titanium dioxide 13463-67-7 7 - 13 Wollastonite (Ca(SiO3)) 13983-17-0 7 - 13 Nepheline syenite 37244-96-5 5 - 10 2-methoxy-1-methylethyl acetate 108-65-6 1 - 5 Solvent naphtha (petroleum), light aromatic 64742-95-6 0.5 - 1.5 1,2,4-trimethylbenzene 95-63-6 0.1 - 1 xylene 1330-20-7 0.1 - 1 carbon black respirable 1333-86-4 0.1 - 1 4-isocyanatosulphonyltoluene 4083-64-1 0.1 - 1 ethylbenzene 100-41-4 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides Flammability of the product :

Page: 2/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Special provisions : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Place in a suitable container. The contaminated area should be cleaned immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts) and concentrated (d: 0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts) and water (95 parts). Add the same decontaminant to the remnants and let stand for several days until no further reaction in an unsealed container. Once this stage is reached, close container and dispose of according to local regulations (see section 13). Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling : 

# 7 .

Page: 3/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# Handling and storage 7 .

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Precautions should be taken to minimize exposure to atmospheric humidity or water. CO2 will be formed, which, in closed containers, could result in pressurization. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Storage :



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Consult local authorities for acceptable exposure limits. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z n-butyl acetate TWA 150 ppm 150 ppm 150 ppm 150 ppm Not established STEL 200 ppm Not established 200 ppm 200 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ titanium dioxide TWA 10 mg/m3 15 mg/m3 TD 10 mg/m3 TD 10 mg/m3 (as Ti) Not established STEL Not established Not established Not established 20 mg/m3 (as Ti) Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Nepheline syenite TWA Not

established Not established 10 mg/m3 TD Not established Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 2-methoxy-1-methylethyl acetate TWA Not

established Not established 50 ppm Not established 50 ppm

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1,2,4-trimethylbenzene TWA 25 ppm Not

established 25 ppm 25 ppm Not

established STEL Not established Not established Not established 35 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not established STEL 150 ppm Not established 150 ppm 150 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ carbon black respirable TWA 3 mg/m3 3.5 mg/m3 3.5 mg/m3 3.5 mg/m3 Not established STEL Not established Not established Not established 7 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylbenzene TWA 20 ppm 100 ppm 100 ppm 100 ppm Not established STEL Not established Not established 125 ppm 125 ppm Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico IPEL

STEL = =

Short term Exposure limit values

Page: 4/9 United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# Exposure controls/personal protection 8 .

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : butyl rubber Gloves : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

Not available.

Not available. 1.32

Not available. 1.9 kPa (13.9 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Odor Color :

:

:

:

:

:

:

:

: Flash point : Closed cup: 36.11°C (97°F) Explosion limits : Lower: 1.3% 

# 9 .

Density ( lbs / gal ) : 11.02

Page: 5/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# Physical and chemical properties 9 .

32% (v/v), 21.77% (w/w) 0.88 (butyl acetate = 1) Volatility Evaporation rate :

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 78.23

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,acids,oxidizing materials,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water, resulting in the production of carbon dioxide. In closed containers, pressure buildup could result in distortion, expansion and, in extreme cases, bursting of the container. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. n-butyl acetate LD50 Oral Rat 10.768 g/kg

-

LD50 Dermal Rabbit >17600 mg/kg

- LC50 Inhalation Rat >21.1 mg/l 4 hours titanium dioxide LD50 Oral Rat >10 g/kg

- 2-methoxy-1-methylethyl acetate LD50 Oral Rat 8532 mg/kg

-

LD50 Dermal Rabbit >5 g/kg

- Solvent naphtha (petroleum), light aromatic LD50 Oral Rat 8400 mg/kg

-

LD50 Dermal Rabbit 3.48 g/kg

- 1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg

-

LC50 Inhalation Rat 18000 mg/m3 4 hours xylene LD50 Oral Rat 4.3 g/kg

-

LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours

carbon black respirable LD50 Oral Rat >15400 mg/kg

-

LD50 Dermal Rabbit >3 g/kg

- 4-isocyanatosulphonyltoluene LD50 Oral Rat >0.5 g/kg

- ethylbenzene LD50 Oral Rat 3.5 g/kg

-

LD50 Dermal Rabbit >5000 mg/kg

- LC50 Inhalation Vapor Rat 4000 ppm 4 hours Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 6/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# 11 . Toxicological information

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS). Contains material which may cause damage to the following organs: kidneys, lungs, upper respiratory tract, skin, eye, lens or cornea.

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - Product/ingredient name titanium dioxide A4 2B

- - carbon black respirable A3 2B

- - ethylbenzene A3 2B

- -

ACGIH NTP OSHA IARC



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

n-butyl acetate Acute LC50 18000 to 19000 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ 1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

______________________ _________________________________ ________________________________ __________ xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ ethylbenzene Acute LC50 4200 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute LC50 5100 to 5700 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Acute EC50 2930 to 4400 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

_________________________________ ________________________________ __________ Chronic NOEC 3300 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia 96 hours

_________________________________ ________________________________ __________ Chronic NOEC 6800 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only Waste disposal 

# Disposal considerations

: 

# 13 .

Page: 7/9

United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# Disposal considerations 13 .

be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 III Additional information

- IMDG 1263 PAINT 3

-

III

DOT Reportable quantity

19603. 5 lbs / 8900 kg [1778.7 gal / 6733.2 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT III

CERCLA: Hazardous substances.: acetone: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

At least one component is not listed. All components are listed or exempted. All components are listed or exempted.

Not determined.

Substance Use Restricted At least one component is not listed. At least one component is not listed. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) :

Philippines inventory (PICCS) :

:

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :
CERCLA: Hazardous substances.: acetone: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg); ethylbenzene: 1000 lbs. (454 kg); xylene: 100 lbs. (45.4 kg); SARA 302/304 : 1,4-dihydroxybenzene

SARA 311/312 SDS Distribution - Chemical Inventory - Hazard Identification: Chemical name CAS # Acute Chronic Fire Reactive Pressure

Page: 8/9 United States - Canada - Mexico

### AMERCOAT 450H HAZE GRAY F/S 26270 R Product name 26 Product code Date of issue Version 

### AT45H20 15 April 2013



# 15 . Regulatory information

SARA 313 CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification : ethylbenzene 100-41-4 0.1 - 1 n-butyl acetate 123-86-4 Y N Y N N titanium dioxide 13463-67-7 N Y N N N 2-methoxy-1-methylethyl acetate 108-65-6 Y N Y N N Solvent naphtha (petroleum), light aromatic 64742-95-6 Y N Y N N

carbon black respirable 1333-86-4 N Y N N N 4-isocyanatosulphonyltoluene 4083-64-1 Y N N Y N ethylbenzene 100-41-4 Y Y Y N N Product as-supplied : Y Y Y N N

Chemical name

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 2 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 12/15/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

: : : : : : 2 *

2 0 ( * ) - Chronic effects

Page: 9/9

United States - Canada - MexicoAMERCOAT 240 CURE Product name 

# Product and company identification

: 

# 1 .

AT240-B PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 22 December 2012
Version 21

Emergency overview 

# Hazards identification

Potential acute health effects

Harmful or fatal if swallowed. May cause burns to mouth, throat and stomach.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory and skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. 1-component mixtures: formaldehyde is released during curing. Formaldehyde may cause irreversible effects, is irritating to the mucous membranes and may cause skin sensitization. Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. COMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. CAUSES EYE AND SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF INHALED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Corrosive to eyes. Causes burns. Corrosive to the skin. Causes burns. Toxic in contact with skin. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8

United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. butan-1-ol 71-36-3 5 - 10 ethylenediamine 107-15-3 1 - 5 2,2'-iminodiethylamine 111-40-0 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides Formaldehyde. Flammability of the product :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Personal precautions : 

# 6 .

Page: 2/8

United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Accidental release measures 6 .

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Exposure controls/personal protection 8 .

butan-1-ol TWA 20 ppm 100 ppm 20 ppm Not established Not established STEL Not established Not established Not established 50 ppm S C Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylenediamine TWA 10 ppm S 10 ppm 10 ppm S 10 ppm S Not established STEL Not established Not established Not established 3 mg/m3 S Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 2,2'-iminodiethylamine TWA 1 ppm S Not

established 1 ppm S 1 ppm S Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/8 United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical splash goggles and face shield.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : nitrile, neoprene Gloves : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

= Threshold Limit Value TLV TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z STEL = =

Short term Exposure limit values

>37.78°C (>100°F) Liquid.

Not available. Not available. Clear.

Boiling/condensation point 

# Physical and chemical properties

Physical state

pH Odor Color :

:

:

:

: Flash point : Closed cup: 58.89°C (138°F) Explosion limits : Lower: 1.5% 

# 9 .

Page: 4/8

United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Physical and chemical properties 9 .

11% (v/v), 9.1% (w/w) Not available.
0.97

Not available. 0.59 kPa (4.4 mm Hg) [room temperature] Melting/freezing point

0.46 (butyl acetate = 1) Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate :

:

:

:

:

:Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 90.9 Density ( lbs / gal ) : 8.1

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids, strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Formaldehyde. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :
:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity Classification Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain. Contains material which may cause damage to the following organs: blood, kidneys, lungs, liver, mucous membranes, upper respiratory tract, skin, central nervous system (CNS), ears, eye, lens or cornea. butan-1-ol LD50 Oral Rat 0.79 g/kg

-

LD50 Dermal Rabbit 3400 mg/kg

- LC50 Inhalation Vapor Rat 8000 ppm 4 hours

ethylenediamine LD50 Oral Rat 0.5 g/kg

-

LD50 Dermal Rabbit 0.73 g/kg

- 2,2'-iminodiethylamine LD50 Oral Rat 1080 mg/kg

-

LD50 Dermal Rabbit 1090 mg/kg

- Product/ingredient name Result Species Dose Exposure Acute toxicity

Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5

IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: - Product/ingredient name ethylenediamine A4

- - -

ACGIH NTP OSHA IARC

Page: 5/8 United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Ecological information

Environmental effects : No known significant effects or critical hazards. 

# 12 .

Aquatic ecotoxicity

butan-1-ol Acute LC50 100 to 500 mg/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________ Acute EC50 1983000 to 2072000 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ ethylenediamine Acute LC50 115700 to 131600 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas 96 hours

_________________________________ ________________________________ __________ Acute LC50 26500 to 34400 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ 2,2'-iminodiethylamine Acute LC50 1014000 ug/L Fresh water Fish - Guppy - Poecilia reticulata 96 hours

_________________________________ ________________________________ __________ Acute LC50 53500 ug/L Fresh water Daphnia - Water flea - Daphnia

magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 3469 PAINT, FLAMMABLE, CORROSIVE 3 (8) III Additional information

- IMDG 3469 PAINT, FLAMMABLE, CORROSIVE 3 (8)

-

III

DOT

- 3469 3 (8) PAINT, FLAMMABLE, CORROSIVE III

CERCLA: Hazardous substances.: ethylenediamine: 5000 lbs. (2270 kg); butan-1-ol: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group

Page: 6/8

United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this

material.

United States U.S. Federal regulations :

SARA 313 CERCLA: Hazardous substances.: ethylenediamine: 5000 lbs. (2270 kg); butan-1-ol: 5000 lbs. (2270 kg);

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. SARA 302/304/311/312 extremely hazardous substances : ethylenediamine SARA 302/304 emergency planning and notification : ethylenediamine SARA 302/304/311/312 hazardous chemicals : ethylenediamine; butan-1-ol

Supplier notification : butan-1-ol 71-36-3 5 - 10 SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

butan-1-ol 71-36-3 Y N Y N N ethylenediamine 107-15-3 Y N Y Y N 2,2'-iminodiethylamine 111-40-0 Y N N Y N Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y N Y N N

Chemical name

WHMIS (Canada) Class E: Corrosive liquid. Class B-3: Combustible liquid with a flash point between 37. 8°C (100°F) and 93.3°C (200°F). Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

2 3 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)

2

0 2 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Date of previous issue 12/29/2011. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

: : : : : : 3 *

3 0 ( * ) - Chronic effects

Page: 7/8

United States - Canada - Mexico

### AMERCOAT 240 CURE Product name 21 Product code Date of issue Version 

### AT240-B 22 December 2012



# Other information 16 .

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS

Page: 8/8

United States - Canada - MexicoAMERCOAT 235 BUFF 235B1642 RESIN Product name 

# Product and company identification

: 

# 1 .

JDAT235-1 (F1) PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : 888-977-4762 

# Material Safety Data Sheet

Date of issue 24 September 2012
Version 5

Emergency overview 

# Hazards identification

Potential acute health effects

May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.

Eyes Skin Inhalation

Ingestion

See toxicological information (Section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Keep away from flames, such as a pilot light, and any object that sparks, such as an electric motor. Keep away from heat. Do not smoke. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF INHALED OR SWALLOWED. SANDING AND GRINDING DUSTS MAY BE HARMFUL IF INHALED. ASPIRATION HAZARD. CAN ENTER LUNGS AND CAUSE DAMAGE. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes, nose, mouth and throat.

Severely irritating to eyes. Risk of serious damage to eyes. Irritating to skin. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Talc , not containing asbestiform fibres 14807-96-6 10 - 30 Epoxy resin (MW < 700) 25068-38-6 10 - 30 Mica-group minerals 12001-26-2 7 - 13 Petroleum resins 64742-16-1 7 - 13 Solvent naphtha (petroleum), light arom. 64742-95-6 5 - 10 butan-1-ol 71-36-3 3 - 7 titanium dioxide 13463-67-7 3 - 7 Polyisocyanate, Alkyl Phenol Blocked Not available. 1 - 5 1,2,4-trimethylbenzene 95-63-6 1 - 5 Epoxy Resin (MW<=700) 67924-34-9 1 - 5 heptan-2-one 110-43-0 1 - 5 xylene 1330-20-7 0.1 - 1

cumene 98-82-8 0.1 - 1 4-nonylphenol, branched 84852-15-3 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Use dry chemical, CO2, water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides halogenated compounds metal oxide/oxides Hydrogen cyanide (HCN). Cyanate and isocyanate. Flammability of the product :

Page: 2/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Fire-fighting measures 5 .
Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. :

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Page: 3/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS

TD = Total dust Key to abbreviations

Consult local authorities for acceptable exposure limits.

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. = Threshold Limit Value TLV TWA = Time Weighted Average Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances = Z Talc , not containing asbestiform fibres TWA 2 mg/m3 R 20 mppcf Z 2 mg/m3 R 2 mg/m3 R Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Mica-group minerals TWA 3 mg/m3 R 20 mppcf Z 3 mg/m3 R 3 mg/m3 Not

established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ butan-1-ol TWA 20 ppm 100 ppm 20 ppm Not

established Not established STEL Not established Not established Not established 50 ppm S C Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ titanium dioxide TWA 10 mg/m3 15 mg/m3 TD 10 mg/m3 TD 10 mg/m3

(as Ti) Not established STEL Not established Not established Not established 20 mg/m3 (as Ti) Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ 1,2,4-trimethylbenzene TWA 25 ppm Not established 25 ppm 25 ppm Not established STEL Not established Not established Not established 35 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ heptan-2-one TWA 50 ppm 100 ppm 25 ppm 50 ppm Not

established STEL Not established Not established Not established 100 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ xylene TWA 100 ppm 100 ppm 100 ppm 100 ppm Not

established STEL 150 ppm Not established 150 ppm 150 ppm Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ cumene TWA 50 ppm 50 ppm S 50 ppm S 50 ppm S Not

established STEL Not established Not established Not established 75 ppm S Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

STEL = =

Short term Exposure limit values

Page: 4/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Exposure controls/personal protection 8 .

If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical splash goggles.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Personal protection Eyes

Skin Respiratory :

: : butyl rubber Gloves : Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Restrictions on use : Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

>37.78°C (>100°F) Liquid.

34% (v/v), 20.31% (w/w) Not available.

Not available.
1.42

Not available. 0.6 kPa (4.5 mm Hg) [room temperature] Not available. Not available.

Boiling/condensation point Melting/freezing point

35 (butyl acetate = 1) 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Volatility Evaporation rate Odor Color :

:

:

:

:

:

:

:

:

:

: Flash point : Closed cup: 36.67°C (98°F) Explosion limits : Lower: 1.1% 

# 9 .

Partition coefficient: noctanol/water : Not available.

% Solid. (w/w) : 79.69 Density ( lbs / gal ) : 11.85

Page: 5/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012

Stable under recommended storage and handling conditions (see Section 7).

Reactive or incompatible with the following materials:,water,acids,oxidizing materials, strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Cyanate and isocyanate. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :
:

:

:

: 

# 10 .

11 . Toxicological information

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available.

Carcinogenicity

Classification Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Defatting irritant : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS). Contains material which may cause damage to the following organs: blood, kidneys, lungs, liver, mucous membranes, peripheral nervous system, upper respiratory tract, skin, ears, eye, lens or cornea, nose/sinuses, testes, throat. Epoxy resin (MW < 700) LD50 Oral Rat >2 g/kg

- LD50 Dermal Rabbit >2 g/kg

- Solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg

- LD50 Dermal Rabbit 3.48 g/kg

- butan-1-ol LD50 Oral Rat 0.79 g/kg

- LD50 Dermal Rabbit 3400 mg/kg

- LC50 Inhalation Vapor Rat 8000 ppm 4 hours

titanium dioxide LD50 Oral Rat >10 g/kg

- 1,2,4-trimethylbenzene LD50 Oral Rat 5 g/kg

- LC50 Inhalation Rat 18000 mg/m3 4 hours heptan-2-one LD50 Oral Rat 1.6 g/kg

- LD50 Dermal Rabbit 10.206 g/kg

- xylene LD50 Oral Rat 4.3 g/kg

- LD50 Dermal Rabbit >1.7 g/kg

- LC50 Inhalation Vapor Rat 5000 ppm 4 hours

cumene LD50 Oral Rat 1.4 g/kg

- LD50 Dermal Rabbit 12.3 g/kg

- LC50 Inhalation Rat 39000 mg/m3 4 hours 4-nonylphenol, branched LD50 Oral Rat 0.58 g/kg

- LD50 Dermal Rabbit 2.14 g/kg

- Product/ingredient name Result Species Dose Exposure Acute toxicity

Product/ingredient name titanium dioxide A4 2B

- - cumene

- 2B

- - ACGIH NTP OSHA IARC

Page: 6/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# 11 . Toxicological information

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data. Fertility effects : Contains material which may impair male fertility, based on animal data. Contains material which may impair female fertility, based on animal data. Carcinogen Classification code: ACGIH: A1, A2, A3, A4, A5 IARC: 1, 2A, 2B, 3, 4 NTP: Proven, Possible OSHA: + Not listed or regulated as a carcinogen: -



# Ecological information

Environmental effects : Water polluting material. May be harmful to the environment if released in large quantities. 

# 12 .

Aquatic ecotoxicity

butan-1-ol Acute LC50 100 to 500 mg/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________ Acute EC50 1983000 to 2072000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ 1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ heptan-2-one Acute LC50 131000 to 137000 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

______________________ _________________________________ ________________________________ __________ xylene Acute LC50 3300 to 4093 ug/L Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 96 hours

______________________ _________________________________ ________________________________ __________ cumene Acute LC50 2700 ug/L Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 96 hours

_________________________________ ________________________________ __________ Acute EC50 10600 to 14100 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ 4-nonylphenol, branched Acute LC50 135.1 ug/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________ Acute LC50 142 ug/L Marine water Fish - Sheepshead minnow - Cyprinodon variegatus 96 hours

_________________________________ ________________________________ __________ Chronic NOEC 23 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 4 days

_________________________________ ________________________________ __________ Chronic NOEC 0.24 to 0.26 mg/L Marine water Fish - Sheepshead minnow - Cyprinodon variegatus 96 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Waste disposal 

# Disposal considerations

: 

# 13 .

Page: 7/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Disposal considerations 13 .
Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures 

# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 PAINT 3 III Additional information

-
IMDG 1263 PAINT. Marine pollutant (Solvent naphtha (petroleum), light arom.) 3

- III

DOT Reportable quantity

26127 lbs / 11861.7 kg [2210. 5 gal / 8367.7 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. 1263 3 PAINT III

CERCLA: Hazardous substances.: butan-1-ol: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg); xylene: 100 lbs. (45.4 kg); cumene: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group



# 15 . Regulatory information

All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

Not determined.

Substance Use Restricted All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

New Zealand ( NZIoC ) United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) :

Philippines inventory (PICCS) : :

: Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

United States

CERCLA: Hazardous substances.: butan-1-ol: 5000 lbs. (2270 kg); n-butyl acetate: 5000 lbs. (2270 kg); xylene: 100 lbs. (45.4 kg); cumene: 5000 lbs. (2270 kg); SARA 302/304/311/312 extremely hazardous substances : No products were found. SARA 302/304 emergency planning and notification : No products were found. SARA 302/304/311/312 hazardous chemicals : butan-1-ol; Talc , not containing asbestiform fibres; Mica-group minerals; titanium dioxide; heptan-2-one; 1,2,4-trimethylbenzene

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification: Chemical name CAS # Acute Chronic Fire Reactive Pressure

Page: 8/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# 15 . Regulatory information

SARA 313 CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Supplier notification butan-1-ol 71-36-3 3 - 7 1,2,4-trimethylbenzene 95-63-6 1 - 5 Talc , not containing asbestiform fibres 14807-96-6 Y N N N N

Epoxy resin (MW < 700) 25068-38-6 Y N N N N Mica-group minerals 12001-26-2 N N N N N Petroleum resins 64742-16-1 N N N N N Solvent naphtha (petroleum), light

arom. 64742-95-6 Y N Y N N

butan-1-ol 71-36-3 Y N Y N N titanium dioxide 13463-67-7 N Y N N N Polyisocyanate, Alkyl Phenol Blocked Not available. Y N N N N

1,2,4-trimethylbenzene 95-63-6 Y N Y N N Epoxy Resin (MW<=700) 67924-34-9 Y N N N N heptan-2-one 110-43-0 Y N Y N N

cumene 98-82-8 Y Y Y N N 4-nonylphenol, branched 84852-15-3 Y Y N N N Product as-supplied : Y Y Y N N

Chemical name

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). : Canada

Mexico

3 3 0 Health Flammability Reactivity Classification

: : : 

# Other information

Hazardous Material Information System (U.S.A.)
3

0 3 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer Date of previous issue 7/8/2012. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 3 *

3 0 ( * ) - Chronic effects

Page: 9/10 United States - Canada - Mexico

### AMERCOAT 235 BUFF 235B1642 RESIN Product name 5 Product code Date of issue Version 

### JDAT235-1 (F1) 24 September 2012



# Other information 16 .

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Page: 10/10 United States - Canada - MexicoAMERCOAT 235 CLEAR CURE Product name 

# Product and company identification

: 

# 1 .

AT235-B/55 PPG Industries, Inc. One PPG Place Pittsburgh, PA 15272 (412) 434-4515 (U.S.) (514) 645-1320 (Canada) 01-800-00-21-400 (Mexico) Supplier Code

Emergency telephone number :

: :

Technical Phone Number : (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. EST 

# Material Safety Data Sheet

Date of issue 3 June 2010 Version 2

Emergency overview 

# Hazards identification

Potential acute health effects

Harmful or fatal if swallowed. May cause burns to mouth, throat and stomach.

Eyes Skin Inhalation

Ingestion

See toxicological information (section 11) DANGER! :

: : :

:

Medical conditionsaggravated by overexposure Pre-existing respiratory and skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. : 

# 2 .

Over-exposure signs/symptoms Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. COMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. CAUSES EYE AND SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN. CAUSES RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF INHALED. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.

May be harmful if inhaled. Irritating to respiratory system. Can irritate eyes, nose, mouth and throat. May cause sensitization by inhalation. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

Corrosive to eyes. Causes burns. Corrosive to the skin. Causes burns. Toxic in contact with skin. May cause an allergic skin reaction.

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous Materials Information System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Page: 1/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010



# Composition/information on ingredients 3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Alkylated phenolic polyamine Proprietary 40 - 70 Solvent naphtha (petroleum), light arom. 64742-95-6 10 - 30 butan-1-ol 71-36-3 3 - 7 ethylenediamine 107-15-3 0.1 - 1 Name CAS number %



# First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Notes to physician :

:

:

:

: 

# 4 .

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting. 

### If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Material Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Use dry chemical, CO 2 , water spray (fog) or foam. 

# Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. : 

# 5 .

Special exposure hazards : Do not use water jet. Suitable : Not suitable :

Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides Flammability of the product :

Page: 2/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Use spark-proof tools and explosion-proof equipment. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Environmental precautions 

# Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Personal precautions :

Large spill : 

# 6 .

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill :

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Do not store above the following temperature: 120F / 49C. Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skin or clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Vapors are heavier than air and may spread along floors. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. 

# Handling and storage

Handling

Storage :

: 

# 7 .

Page: 3/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010



# Exposure controls/personal protection 8 .

Acceptable Maximum Peak A = ACGIH = American Conference of Governmental Industrial Hygienists. C = Ceiling Limit = Potential skin absorption

S SR = Respiratory sensitization

= Skin sensitization SS TD = Total dust Key to abbreviations

By spraying: air-fed respirator. By other operations than spraying, in well ventilated areas, air-fed respirators could be replaced by a combination charcoal filter and particulate filter mask. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical splash goggles and face shield.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Personal protection Eyes

Skin Respiratory Consult local authorities for acceptable exposure limits.

:

: : nitrile, neoprene Gloves : Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. = Threshold Limit Value TLV TWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Fume = F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration. OSHA R = Respirable OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous

Substances = Z butan-1-ol TWA 20 ppm 100 ppm 20 ppm Not

established Not established STEL Not established Not established Not established 50 ppm C Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ ethylenediamine TWA 10 ppm 10 ppm 10 ppm 10 ppm Not

established STEL Not established Not established Not established 3 mg/m3 Not established

____________________________ ___________ ___________ ___________ ___________ ___________ ___________ Name Result ACGIH OSHA Ontario Mexico PPG

Page: 4/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010

>37.78°C (>100°F) Liquid.

38% (v/v), 35% (w/w) Not available.

Not available. 0.96

Not available. 0.43 kPa (3.2 mm Hg)

Not available. Not available. Not available.

Boiling/condensation point Melting/freezing point

28 (butyl acetate = 1) 

# Physical and chemical properties

Physical state

pH

Specific gravity

Vapor pressure Vapor density Volatility Odor threshold Evaporation rate Odor Color :

:

:

:

:

:

:

:

:

:

:

: Flash point : Closed cup: 40°C (104°F) Explosion limits : Lower: 1% 

# 9 .

Octanol/water partition coefficient : Not available.

% Solid. (w/w) : 65 Density ( lbs / gal ) : 8.01

Stable under recommended storage and handling conditions (see section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strong acids,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. 

# Stability and reactivity

Stability Conditions to avoid

Materials to avoid

Hazardous decomposition products Hazardous polymerization :

:

:

:

: 

# 10 .

Toxicological information 11 .

Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis. Solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg

- LD50 Dermal Rabbit 3.48 g/kg

- butan-1-ol LD50 Oral Rat 0.79 g/kg

- LD50 Dermal Rabbit 3400 mg/kg

- LC50 Inhalation Vapor Rat 8000 ppm 4 hours

ethylenediamine LD50 Oral Rat 0.5 g/kg

- LD50 Dermal Rabbit 0.73 g/kg

- Product/ingredient name Result Species Dose Exposure Acute toxicity

Page: 5/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010



# Toxicological information 11 .

Carcinogenicity

Mutagenicity

Teratogenicity

Reproductive toxicity Classification

ethylenediamine A4

- - - - - Product/ingredient name ACGIH EPA NIOSH NTP IARC OSHA Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS), ears. Contains material which may cause damage to the following organs: blood, kidneys, lungs, liver, mucous membranes, upper respiratory tract, skin, eyes.



# Ecological information

Environmental effects : Water polluting material. May be harmful to the environment if released in large quantities. 

# 12 .

Aquatic ecotoxicity

butan-1-ol Acute LC50 100 to 500 mg/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________ Acute EC50 1983000 to 2072000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ ethylenediamine Acute LC50 115700 to 131600 ug/L Fresh water Fish - Fathead minnow - Pimephales promelas 96 hours

_________________________________ ________________________________ __________ Acute LC50 26500 to 34400 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________ Product/ingredient

name Species Result Exposure

The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via alicensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and

sewers. Waste disposal 

# Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. : 

# 13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

Page: 6/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010



# Transport information 14 .

Regulation UN number Proper shipping name Classes PG*
UN 1263 Paint. 3 III Additional information

- IMDG 1263 Paint.. Marine pollutant (Solvent naphtha (petroleum), light arom.) 3 Marine pollutant III

DOT Remarks

USA Only: Can be reclassifiedas Combustible Liquid. NonBulk highway shipments (Less than or Equal to 450Liters) can be shipped as non-regulated. 1263 3 Paint. III

CERCLA: Hazardous substances.: ethylenediamine: 5000 lbs. (2270 kg); butan-1-ol: 5000 lbs. (2270 kg); Reportable quantity RQ : PG* : Packing group



# Regulatory information

U.S. Federal regulations

WHMIS (Canada) Class E: Corrosive liquid. Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). SARA 302/304/311/312 extremely hazardous substances : ethylenediamine SARA 302/304 emergency planning and notification : ethylenediamine SARA 302/304/311/312 hazardous chemicals : ethylenediamine; butan-1-ol SARA 311/312 MSDS distribution - chemical inventory - hazard identification : ethylenediamine: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; butan-1-ol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard :

: SARA 313

Canada United States

Mexico 

# 15 .

Classification TSCA 12(b) annual export notification : No products were found. TSCA 12(b) one-time export : No products were found.

CERCLA: Hazardous substances.: ethylenediamine: 5000 lbs. (2270 kg); butan-1-ol: 5000 lbs. (2270 kg); All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.
Not determined. All components are listed or exempted. All components are listed or exempted.

Product name CAS number Concentration butan-1-ol 71-36-3 3 - 7 Form R - Reporting requirements : United States inventory (TSCA 8b) : Australia inventory (AICS) Canada inventory ( DSL ) : China inventory (IECSC) :

Japan inventory (ENCS) : Korea inventory (KECI) : New Zealand ( NZIoC ) : Philippines inventory (PICCS) : :

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative. Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

Page: 7/8 United States - Canada - Mexico

### AMERCOAT 235 CLEAR CURE Product name 2 Product code Date of issue Version 

### AT235-B/55 3 June 2010



# Regulatory information 15 .

2 3 0 Health Flammability Reactivity : : : 

# Other information

Hazardous Material Information System (U.S.A.)
2

0 2 National Fire Protection Association (U.S.A.)
Health Instability Flammability Health Flammability Physical hazards

Disclaimer The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products. Date of previous issue 2/25/2010. : 

# 16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version. Organization that prepared the MSDS : EHS : : : : : : 3 *

3 0 ( * ) - Chronic effects

Page: 8/8 United States - Canada - Mexico