Appendix 7 

Acute Impacts Refined Analysis Figures 
Refined Acute Modeling Approach 

 Initial acute screening risk calculations were performed with the HEM-3 model. 

HEM-3 estimates acute (1-hour) impacts at both polar and census block receptors. It is 

assumed for this short period of time that an exposed individual could be located at any 

off-site location. The lack of readily available detailed property boundary information 

for many of the facilities evaluated made it difficult to determine whether receptors were 

on- or off-site. In the absence of such information, the first ring of polar receptors was 

placed 100 meters from the plant center for many facilities. However, these polar rings 

often transected on-site locations, restricting public access to exposures at these levels 

and thereby overestimating exposures. 

 The screening approach used by HEM-3 to estimate maximum 1-hour exposures 

also likely overestimates. To estimate maximum 1-hour concentrations at each receptor, 

HEM-3 sums the maximum concentrations attributed to each source, regardless of 

whether those maximum concentrations occurred during the same hour. In other words, 

HEM-3 assumes that the maximum impact from each source at each receptor occurs at 

the same time. In actuality, maximum impacts from different sources may occur at 

different times. 

 This appendix includes the results of refined acute assessments performed for 

facilities that exceeded short-term health benchmarks using the HEM-3 approach. The 

refinements can address both areas of conservatism described above. The simplest 

refinement is to plot the HEM-3 polar grid results on aerial photographs of the facilities; 

This allows the assessment of off-site locations that may be accessible to the public (e.g.,

roadways and public buildings.). In cases where this refinement results in lower acute 

risks no further refinement was conducted. However, if acute risk still remain at or near 

levels of concern a further refinement is conducted. This second refinement includes 

remodeling with the AERMOD model directly (instead of using HEM) to estimate 

maximum 1-hour concentrations at each receptor by pairing individual source impacts in 

time and space. The AERMOD results are then plotted on aerial photographs as noted 

above to determine off-site impacts. Modeling with AERMOD also allows the 

estimation of the frequency of higher impacts at or above the health levels of concern. 

The attached figures present the estimated hazard quotient values (the modeled 1-hour 

concentration of a pollutant divided by its short-term health benchmark) at the polar 

receptors near the facilities. Each set of figures is prefaced with a description of the 

maximum off-site hazard quotient value and where that value occurs. 
Printing and Publishing F

(all HQs are for tolue

• Figure 1 – NEI10987; maximum offsite acute HQ 

of facility

• Figure 2 – NEI11092; maximum offsite acute HQ 

of facility

• Figure 3 – NEI13250; maximum offsite acute HQ 

of facility

• Figure 4 – NEI25071; maximum offsite acute HQ 

of facility

• Figure 5 – NEI8115; maximum offsite acute HQ o

northeast of facility

• Figure 6 – NEI9433; maximum offsite acute HQ o

northwest of facility

• Figure 7 – NEITNT$4767; maximum offsite acute 

north of facility
Figure 1 – NEI10987 Acute Toluene HQ (RE
Figure 2 – NEI11092 Acute Toluene HQ (RE
Figure 3 – NEI13250 Acute Toluene HQ (RE
Figure 4 – NEI25071 Acute Toluene HQ (RE
Figure 5 – NEI8115 Acute Toluene HQ (REL
Figure 6 – NEI9433 Acute Toluene HQ (REL
Figure 7 – NEITNT$4767 Acute Toluene HQ 
Marine Tank Vessel Loading 

Operations

• Figure 1 - NEI7687 ; maximum offsite 

acute HQ for glycol ethers of 0.6 to the 

east of facility

• Figure 2 - NEITX20191; maximum offsite 

acute HQ for benzene of 1.49 to the north 

of facility on a roadway
Figure 1 – NEI7687 Acute Glycol Ethers HQ (REL)
Figure 2 – NEITX20191 Acute Benzene HQ (REL)
Pharmaceutical Facil

• Figure 1 - NEI34261; maximum offsite ac

chloroform of 2.18 to the west of facility

• Figure 2 - NEI34769; maximum offsite ac

methanol of 0.91 to the north of facility

• Figure 3 - NEI46520; maximum offsite ac

methylene chloride of 1.25 to the north of 

• Figure 4 - NEI46520; maximum offsite ac

acetonitrile of 0.47 to the north of facility

• Figure 5 - NEIIL0918580; maximum offsit

glycol ethers of 1.93 to the southwest of f
Figure 1 – NEI34261 Acute Chloroform HQ (
Figure 2 – NEI34769 Acute Methanol HQ (R
Figure 3 – NEI46520 Acute Methylene Chloride 
Figure 4 – NEI46520 Acute Acetonitrile HQ (A
2.00

1.93

1.58

1.85

0.58

Figure 5 – NEIIL0918580 Acute Glycol Ethers HQ 
Polybutadiene Rubb

Production Facilitie

• Figure 1 - NEI32876; maximum 

acute HQ for toluene of 1.40 to southeast of facility
Figure 1 – NEI32876 Acute Toluene HQ (RE
Styrene Butadiene Rubb

Latex Production Faci

• Figure 1 - NEI13230; maximum 

acute HQ for styrene of 0.35 to southeast of facility
Figure 1 – NEI13230 Acute Styrene HQ (RE