# Dimethyladamantylamine Revision Date 01/04/2014 Revision Number 1 

# Material Safety Data Sheet Issuing date 26/06/2008 Dimethyladamantylamine Emergency telephone number • 7 0 3 - 5 2 7 - 3 8 8 7 Chemtrec 1-800-424-9300 

### 1. PRODUCT AND COMPANY IDENTIFICATION Recommended Use For research use only, Reserved for industrial and professional use, Chemical intermediate SDS Code(s) 7245 Product Name



### _____________________________________________________________________________________________ Synonyms 1-Adamantyldimethylamine N,N-Dimethyladamantan-1-amine N,N-Dimethyl-tricyclo[3.3.1.13,7]decan-1-amine UN-No


### Page 1 / 10 UN 2735 Manufacturer • S A C H E M E u r o p e B V Van Voordenpark 15 5301 KP Zaltbommel The Netherlands Telephone: 0031-4186-82000 E-mail: msds@sachemeurope.nl Supplier • S A C H E M E u r o p e B V Van Voordenpark 15 5301 KP Zaltbommel The Netherlands Telephone: 0031-4186-82000 E-mail: msds@sachemeurope.nl

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 -

No information available. INGESTION MAY BE HARMFUL IF SWALLOWED. Potential Environmental Effects No information available. Chronic Effects Acute Effects 

### 3. COMPOSITION/INFORMATION ON INGREDIENTS Potential Health Effects Chronic Toxicity No information available Formula C12H21N Eyes Avoid contact with eyes. Causes severe eye damage. Component CAS-No weight-% See Section 11 for additional Toxicological information. 

### 2. HAZARDS IDENTIFICATION

N,N-Dimethyladamantylamine 3717-40-6 >98 Skin. Main Symptoms Effects of breathing high concentrations of vapor may include. Irritation. Headache. Contact causes severe skin irritation and possible burns. Aggravated Medical Conditions No information available. Inhalation May cause respiratory irritation. Principle Routes of Exposure Skin contact, Inhalation, Eye contact. Interactions with Other Chemicals Emergency Overview Causes severe skin burns and eye damage May cause respiratory irritation Combustible liquid and vapor.



### _____________________________________________________________________________________________ DANGER!

Page 2 / 10 Appearance Yellow. Odor Amines Physical state liquid.

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - 

### 5. FIRE-FIGHTING MEASURES 4. FIRST AID MEASURES INGESTION Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Rinse mouth immediately and drink plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Consult a physician if necessary. Flammable Properties Combustible Liquid. Heating can release vapors which can be ignited. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment, Dry powder, Carbon dioxide (CO2), Foam, Water spray Notes to physician Treat symptomatically. General advice
Hazardous Combustion Products Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Inhalation Explosion Data Move to fresh air. If not breathing, give artificial respiration. If symptoms persist, call a physician. Do not get in eyes, on skin, or on clothing Do not breathe vapor or mist If symptoms persist, call a physician



### _____________________________________________________________________________________________ Specific hazards arising from the chemical The product causes irritation of eyes, skin and mucous membranes. Combustible material. As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). 

### Page 3 / 10 Health 2 Recommended NFPA Flammability 2 Instability 1

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - 

### 6. ACCIDENTAL RELEASE MEASURES Other information Storage Keep containers tightly closed in a cool, well-ventilated place Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity) Keep away from direct sunlight Incompatible with strong acids and oxidizing agents Vapour can travel along the ground for considerable distances Methods for containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceus earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Personal precautions Environmental Precautions Prevent further leakage or spillage if safe to do so. Try to prevent the material from entering drains or water courses. Local authorities should be advised if significant spillages cannot be contained. 

### 7. HANDLING AND STORAGE Methods for Clean-up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).



### _____________________________________________________________________________________________ Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Keep people away from and upwind of spill/leak. Use personal protective equipment. Handling


### Page 4 / 10 Ensure adequate ventilation Avoid contact with skin and eyes Do not breathe vapor or mist In case of insufficient ventilation, wear suitable respiratory equipment

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 -

Freezing Point no data available Boiling point 2 1 5 ° C melting point no data available General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands and face before breaks and immediately after handling the product. When using do not eat, drink or smoke. Skin Protection Long sleeved clothing. Do not get in eyes, on skin, or on clothing. P244 - Keep reduction valves free from grease and oil. Personal Protective Equipment 

### 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls

Explosive properties No information available Hand Protection Oxidizing Properties None Rubber gloves. 

### 9. PHYSICAL AND CHEMICAL PROPERTIES Evaporation Rate No information available Ensure adequate ventilation, especially in confined areas Provide controls to prevent exposure to mists and sprays Provide controls to prevent splashing

V a p o r p r e s s u r e @ 2 0 ° C ( k P a ) No information available Vapor Density No information available Density 0.98 g/cc Appearance Yellow. Bulk Density no data available Water Solubility Insoluble Odor Amines Partition coefficient No information available Respiratory protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. In case of insufficient ventilation wear suitable respiratory equipment.
Molecular Weight 179.3 Odor Threshold No information available Eye/face Protection Tightly fitting safety goggles. Physical state liquid pH 11.4 Flash Point 8 8 ° C / 1 9 1 ° F



### _____________________________________________________________________________________________ Protective equipment Ensure that eyewash stations and safety showers are close to the workstation location. Autoignition Temperature no data available 

### Page 5 / 10 Flammability Limit in Air Lower no data available upper no data available

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - Hazardous Reactions Product Information Subchronic Toxicity (28 days). No information available Incomplete toxicological data are available for this product No information available Irritation Incomplete toxicological data are available for this product. Methanol is more toxic to humans and primates than to most experimental animals, due to differences in how it is metabolized. Non-primates do not appear to experience the acidosis or vision effects observed in humans and primates. inhalation of high concentrations can cause unconsciousness and death. Incompatible Materials Strong oxidizing agents. Strong acids.
Corrosivity Causes burns. Chemical Stability Component Information Sensitization No information available. Conditions to Avoid Heat, flames and sparks. To avoid thermal decomposition, do not overheat.

Neurological Effects No information available. 

### 11. TOXICOLOGICAL INFORMATION Component Oral LD50 Dermal LD50 Mutagenic Effects No information available. Inhalation LC50 Hazardous Decomposition Products Thermal decomposition can lead to release of irritating and toxic gases and vapors. Hazardous combustion products. Nitrogen oxides (NOx). Carbon monoxide. N,N-Dimethyladamantylamine Target Organ Effects Eyes, Skin, Respiratory system. - - - 

### Chronic Toxicity Stable under normal conditions. 

### Acute Toxicity Carcinogenicity



### _____________________________________________________________________________________________ There are no known carcinogenic chemicals in this product. 

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### 10. STABILITY AND REACTIVITY

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - Freshwater Algae Bioaccumulation Disposal Considerations Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Dispose of in accordance with local regulations. No information available. Freshwater Fish Microtox Contaminated packaging Triple rinse containers. Treat rinsing as for product disposal. Empty containers should be taken for local recycling, recovery or waste disposal. Residues may cause an explosion hazard; do not puncture, cut or weld uncleaned drums. Crustacea 

### 12. ECOLOGICAL INFORMATION Mobility No information available Waste from residues/unused products Should not be released into the environment. Recover or recycle if possible, otherwise: incineration with wet scrubbing facilities. Treat rinsing as for product disposal. Ecotoxicity Effects N,N-Dimethyladamantylamin e No information available
US EPA Waste Number Would not be considered as a characteristic hazardous waste under RCRA if disposed in the form as shipped from SACHEM No information available N,N-Dimethyladamantylamine No information available No information available Partition coefficient n o d a t a a v a i l a b l e No information available. 

### Ecotoxicity

_____________________________________________________________________________________________ Persistence and degradability No information available.



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### 13. DISPOSAL CONSIDERATIONS Component

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - Proper shipping name UN2735, Amines, Liquid, Corrosive, n.o.s Description IATA UN2735, Amines, Liquid, Corrosive, n.o.s., (Dimethyladamantylamine), 8, PGII IATA: 2735 - Amines or polyamines, liquid, corrosive, n.o.s Proper Technical Name N,N-Dimethyladamantylamine UN-No 2735 Proper Technical Name
Hazard class 8 N,N-Dimethyladamantylamine Packing Group I I 

### 14. TRANSPORT INFORMATION

Description UN2735, Amines, Liquid, Corrosive, n.o.s., (Dimethyladamantylamine), 8, PGII DOT ICAO IMDG/IMO UN-No
IMDG: UN2735, Amines, Liquid, Corrosive, n.o.s. UN 2735
Proper Technical Name N,N-Dimethyladamantylamine ICAO: UN2735, Amines, Liquid, Corrosive, n.o.s. UN-No 2735 Hazard class 8 Proper Technical Name Packing Group I I N,N-Dimethyladamantylamine Description UN2735, Amines, Liquid, Corrosive, n.o.s., (Dimethyladamantylamine), 8, PGII Hazard class UN-No 2735 8 Hazard class 8



### _____________________________________________________________________________________________ Packing Group I I Packing Group I I



### Page 8 / 10 Description UN2735, Amines, Liquid, Corrosive, n.o.s., (Dimethyladamantylamine), 8, PGII

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 -

CERCLA not applicable 

### USA SARA 311/312 Hazardous Categorization Federal Regulations International Regulations Chronic Health Hazard No SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40 of the Code of Federal Regulations, Part 372. 

### International Inventories Acute Health Hazard Yes Component ENCS PICCS DSL TSCA CHINA AICS KECL NDSL EINECS ELINCS EC No. N,N-Dimethyladamantylamin e - - - - - - - - - - 609-335-2 Fire Hazard Yes TSCA • N o t a l l c o m p o n e n t s o f t h i s p r o d u c t a r e l i s t e d o n t h e T S C A C h e m i c a l I n v e n t o r y • T h i s p r o d u c t i s s u p p l i e d s o l e l y f o r r e s e a r c h a n d d e v e l o p m e n t p u r p o s e s b y o r u n d e r t h e supervision of a technically qualified individual as defined in 40CFR720.3(ee). Sudden Release of Pressure Hazard No Component Category Carcinogen Status Exposure limits 

### 15. REGULATORY INFORMATION

N,N-Dimethyladamantylamine 3717-40-6 ( >98 ) - None established Reactive Hazard No Component CAS-No weight-% SARA 313 - Threshold Values 

### Clean Water Act

_____________________________________________________________________________________________ N,N-Dimethyladamantylamine 3717-40-6



### Page 9 / 10 >98 -

### _____________________________________________________________________________________________ Dimethyladamantylamine Revision Date 01/04/2014 - End of Safety Data Sheet 

### 16. OTHER INFORMATION Revision Date SDS sections updated; 2; 3; 9; 11; 14; 16 01/04/2014 Issuing date



### _____________________________________________________________________________________________ 26/06/2008 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. In case of any questions, please refer to the official document in English and contact us in your region.



### Page 10 / 10 Revision Note