### Name: David M. Fraley, Ph.D.

Title: Director - Environmental Affairs Company: City Utilities of Springfield Sign Date: 9/30/2010 Name: Mike Taylor Title: President Company:Catalyst Air Management Sign Date: 9/29/2010 Permitted Facility Representative / Date Testing Company Representative / Date 

## MO2161 James River 5 Final Test Report for

/ / Based on information and belief formed after reasonable inquiry, I certify that the statements and information in this test report are true, accurate, and complete. I have reviewed all testing details and results in this test report and hereby certify that the test report is authentic and accurate.

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### MO2161 James River 5 9/30/2010 Facility Information: MO2161 James River 5 5701 South Kissick Rd

Springfield MO65804 Contact:Daniel Hedrick Phone:417-831-8916 Fax: Email: daniel.hedrick@cityutilities.net Testing Company: Catalyst Air Management 2505 ByingRdton-Solway

Knoxville TN37931 Contact:Mike Taylor Phone:865-531-0075 Fax: 865-531-0750 Email: mike.taylor@catalystair.com

Air Permit Number: 2161 Permitted Source ID/Name: City Utilities of Springfield James River Station 5 Permitted Maximum Process Rate:Max. Normal Operation Process Rate: Target Process Test Rate

Description of the source (including control equipment). Please see the attachments for source or process flow diagram: Industry/SCC/NAIS221112

Sampling Location Information:

Test Parameter Information: AFS #: FRS #:

SCC / Description10100222 External Combustion Boilers - Electric Generation - Bituminous/Subbituminous Coal - Pulverized Coal: Dry Bottom (Subbituminous Coal)
The following state and federal regulations that apply to the proposed testing:

Location Round

Duct Diam. Distance from upstream dist. Distance from

downstream dist. Number of

Traverse Ports Equiv. Diam Min.Travers Points Rect. Duct Length /Width MO2161 JR5 123 0 0 4 0 16 0 0

Target Parameter Test Method Number of

Test Runs Test Run

Duration Sample

Points Comments Location Total PM2.5 OTM - 27/28 3 362 0 MO2161 JR5Organic Condensible

Particulate OTM - 27/28 3 362 0 MO2161 JR5Inorganic (Aqueous)

Condensible Part. OTM - 27/28 3 362 0 MO2161 JR5
Filterable PM2.5 OTM - 27/28 3 362 0 MO2161 JR5Lead Method 29 3 240 0 MO2161 JR5Selenium Method 29 3 240 0 MO2161 JR5 

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### MO2161 James River 5 9/30/2010

The following describes any modifications and/or deviations to the applicable test methods. If alternative methods were requested, see the attachments for documentation of request AND approval, including dates.

Nickel Method 29 3 240 0 MO2161 JR5Manganese Method 29 3 240 0 MO2161 JR5Cadmium Method 29 3 240 0 MO2161 JR5Antimony Method 29 3 240 0 MO2161 JR5Filterable Particulate Method 29 3 240 0 MO2161 JR5Arsenic Method 29 3 240 0 MO2161 JR5Cobalt Method 29 3 240 0 MO2161 JR5Chromium Method 29 3 240 0 MO2161 JR5Beryllium Method 29 3 240 0 MO2161 JR5Mercury Method 29 3 240 0 MO2161 JR5



### Saturday, January 29, 2011 Page 3 of 10

### MO2161 James River 5 9/30/2010 Sampling / Stack Data Results Summary 

### Location MO2161 JR5 - Method 29 Average Run Number M29-1 M29-2 M29-3 Test Date 4/26/2010 4/27/2010 4/27/2010 Run Start Time 10:00:00 AM 6:06:00 AM10:30:00 AM

Run Finish Time 2:15:00 PM 10:17:00 AM 2:45:00 PM
Net Run Time, minutes 240 240 240 Dry Gas Meter Volume Sampled, dscf 179.572 180.325 179.605 179.834 Moisture Content of Stack Gas, % 9.62 10.61 10.47 10.233 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 11.6 11.7 11.5 11.600 Oxygen, % 7.3 7.8 7.7 7.600 Average Stack Gas Temperature, °F 339.06 336.13 343.06 339.417 Dry Volumetric Flow Rate, dry scfm 261,438.1 260,142.9 258,965.3 260,182.100 Actual Wet Volumetric Flue Gas Flow Rate, acfm 462,172.1 462,617.7 463,805.9 462,865.233 Percent Isokinetic of Sampling Rate, % 93.7 94.5 94.6 94.267 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000 Fw 10640 10640 10640 10,640.000 Fc 1800 1800 1800 1,800.000



### Saturday, January 29, 2011 Page 4 of 10

### MO2161 James River 5 9/30/2010 Location MO2161 JR5 - OTM - 27/28 Average Run Number OTM27-1 OTM27-2 OTM27-3 Test Date 4/26/2010 4/27/2010 4/27/2010 Run Start Time 10:00:00 AM 6:06:00 AM 1:07:00 PM

Run Finish Time 4:12:00 PM 12:19:00 PM 7:16:00 PM
Net Run Time, minutes 360.75 360.75 360.75 Dry Gas Meter Volume Sampled, dscf 118.329 123.955 127.549 123.278 Moisture Content of Stack Gas, % 9.10 10.18 10.26 9.847 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 11.8 11.6 12.9 12.100 Oxygen, % 7.3 8 6.3 7.200 Average Stack Gas Temperature, °F 338.58 334.67 338.17 337.140 Dry Volumetric Flow Rate, dry scfm 262,339.3 260,613.3 259,267.3 260,739.967 Actual Wet Volumetric Flue Gas Flow Rate, acfm 460,835.4 460,389.8 460,439.3 460,554.833 Percent Isokinetic of Sampling Rate, % 84.1 88.7 91.7 88.167 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000 Fw 10640 10640 10640 10,640.000 Fc 1800 1800 1800 1,800.000



### Saturday, January 29, 2011 Page 5 of 10

### MO2161 James River 5 9/30/2010 Emissions Summary 

### Location: MO2161 JR5 - Method 29 Compound: Antimony Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.006 0.006 0.006 0.006 lb/mmBtuO2 1.11E-06 1.14E-06 1.14E-06 0.000 

### Compound: Arsenic Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.0181 0.0145 0.0088 0.014 lb/mmBtuO2 3.34E-06 2.77E-06 1.67E-06 0.000 

### Compound: Beryllium Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.0015 0.00166 0.00151 0.002 lb/mmBtuO2 2.77E-07 3.17E-07 2.87E-07 0.000 

### Compound: Cadmium Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.01024 0.0049 0.00354 0.006 lb/mmBtuO2 1.89E-06 9.35E-07 6.73E-07 0.000 

### Compound: Chromium Average RunNumber M29-1 M29-2 M29-3 Mass_mg 7.74255 4.59685 1.04465 4.461 lb/mmBtuO2 1.43E-03 8.77E-04 1.99E-04 0.001 

### Compound: Cobalt Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.09883 0.05594 0.01629 0.057 lb/mmBtuO2 1.82E-05 1.07E-05 3.10E-06 0.000 

### Compound: Filterable Particulate Average RunNumber M29-1 M29-2 M29-3 Mass_mg 96.4 80.6 103.9 93.633 lb/mmBtuO2 1.78E-02 1.54E-02 1.97E-02 0.018 

### Compound: Lead Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.083 0.0462 0.1705 0.100 lb/mmBtuO2 1.53E-05 8.81E-06 3.24E-05 0.000 

### Compound: Manganese Average


### Saturday, January 29, 2011 Page 6 of 10

### MO2161 James River 5 9/30/2010

Process Run Data RunNumber M29-1 M29-2 M29-3 Mass_mg 0.70826 0.44316 0.11926 0.424 lb/mmBtuO2 1.31E-04 8.45E-05 2.27E-05 0.000 

### Compound: Mercury Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.01148 0.01398 0.00944 0.012 lb/mmBtuO2 2.12E-06 2.67E-06 1.79E-06 0.000 

### Compound: Nickel Average RunNumber M29-1 M29-2 M29-3 Mass_mg 4.85212 3.17692 0.70162 2.910 lb/mmBtuO2 8.95E-04 6.06E-04 1.33E-04 0.001 

### Compound: Selenium Average RunNumber M29-1 M29-2 M29-3 Mass_mg 0.1955 0.1422 0.034 0.124 lb/mmBtuO2 3.61E-05 2.71E-05 6.46E-06 0.000


### Location: MO2161 JR5 - OTM - 27/28 

### Compound: Filterable PM2.5 Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 80.36 75.06 94.66 83.360 lb/mmBtuO2 2.25E-02 2.12E-02 2.29E-02 0.022 

### Compound: Inorganic (Aqueous) Condensible Pa Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 330 53 36 139.667 lb/mmBtuO2 9.24E-02 1.49E-02 8.71E-03 0.039 

### Compound: Organic Condensible Particulate Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 2.7 2.1 2.2 2.333 lb/mmBtuO2 7.56E-04 5.92E-04 5.32E-04 0.001 

### Compound: Total PM2.5 Average RunNumber OTM27-1 OTM27-2 OTM27-3 Mass_mg 413.06 130.16 132.86 225.360 lb/mmBtuO2 1.16E-01 3.67E-02 3.22E-02 0.062



### Saturday, January 29, 2011 Page 7 of 10

### MO2161 James River 5 9/30/2010 Process Run Data

APCD Run Data

Process Lab Run Data 

### Run Name Value UOM Comments Target Value 1 Heat Input 944.1 Million Btus/million BTU using O2Daily Average (4- 26-10) 0



### 1 Unit Load 91.6 MW Daily Average (4- 26-10) 0

1 Steam Rate 604.6 1000 lbs/hr Daily Average (4- 26-10) 0



### 1 Fuel Rate 53.6 tons/hr Daily Average (4- 26-10) 0

2 Heat Input 1012 Million Btus/million BTU using O2Daily Average (4- 27-10) 0

2 Unit Load 97.7 MW Daily Average (4- 27-10) 0



### 2 Steam Rate 646.8 1000 lbs/hr Daily Average (4- 27-10) 0

2 Fuel Rate 57.5 tons/hr Daily Average (4- 27-10) 0



### 3 Heat Input 1036.3 Million Btus/million BTU using O2Daily Average (4- 28-10) 0

3 Unit Load 99.5 MW Daily Average (4- 28-10) 0



### 3 Steam Rate 662.7 1000 lbs/hr Daily Average (4- 28-10) 0

3 Fuel Rate 59.2 tons/hr Daily Average (4- 28-10) 0

Run Name Value UOM Comments Target Value 

### 1 OVERFIRE AIR 0 0 1 NSCR (NON-SELECTIVE CATALYTIC REDUCTION) 0 0



### 1 ELECTROSTATIC PRECIPITATOR 0 0

Saturday, January 29, 2011 Page 8 of 10

### MO2161 James River 5 9/30/2010 Sampling / Stack Data Results Detail 

### Location MO2161 JR5 - Method 29 Average Run Number M29-1 M29-2 M29-3 Test Date 4/26/2010 4/27/2010 4/27/2010 Run Start Time 10:00:00 AM6:06:00 AM10:30:00 AM Run Finish Time 2:15:00 PM10:17:00 AM 2:45:00 PM Net Traversing Points 16 16 16 Net Run Time, minutes 240 240 240 Nozzle Diameter, inches 0.215 0.215 0.215 0.215 Pitot Tube Coefficient 0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor 1.01 1.01 1.01 1.010 Barometric Pressure, inches of Mercury 28.15 28.2 28.2 28.183 Average Orifice Meter Differential, inches H2O 1.93 1.94 1.91 1.927 Dry Gas Meter Volume Sampled, cubic feet 190.119 187.751 190.394 189.421 Average Dry Gas Meter Temperature, °F 73.88 65.97 75.47 71.773 Dry Gas Meter Volume Sampled, dscf 179.572 180.325 179.605 179.834 Total Moisture Liquid collected, g 406.3 454.6 446.3 435.733 Volume of Water Vapor, standard cubic feet 19.12 21.40 21.01 20.510 Moisture Content of Stack Gas, % 9.62 10.61 10.47 10.233 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.9038 0.8939 0.8953 0.898 Carbon Dioxide, % 11.6 11.7 11.5 11.600 Oxygen, % 7.3 7.8 7.7 7.600 Carbon Monoxide & Nitrogen, % 81.1 80.5 80.8 80.800 Fuel Factor 1.17 1.12 1.15 Dry Molecular Weight, lb/lb-Mole 30.15 30.18 30.15 30.160 Wet Molecular weight, lb/lb-Mole 28.98 28.89 28.88 28.917 Flue Gas Static Pressure, inches of H2O 2.6 2.5 2.5 2.533 Absolute Flue Gas Pressure, inches of Mercury 28.34 28.38 28.38 28.367 Average Stack Gas Temperature, °F 339.06 336.13 343.06 339.417 Average Velocity Head, inches of H2O 1.7368812540 2741.743729401

593081.736881254

0274 1.739 Average Stack Gas Velocity, feet/second 93.35 93.44 93.68 93.490 Stack Cross-Sectional Area, square feet 82.516 82.516 82.516 82.516 Dry Volumetric Flow Rate, dry scfm 261,438.1 260,142.9 258,965.3260,182.100 Actual Wet Volumetric Flue Gas Flow Rate, acfm 462,172.1 462,617.7 463,805.9462,865.233 Percent Isokinetic of Sampling Rate, % 93.7 94.5 94.6 94.267 Percent Excess Air, % 51.7 58.0 56.5 55.400 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000 Round Duct Diameter, inches 123 123 123 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10640 10640 1064010,640.000 Fc 1800 1800 1800 1,800.000



### Saturday, January 29, 2011 Page 9 of 10

### MO2161 James River 5 9/30/2010 Location MO2161 JR5 - OTM - 27/28 Average Run Number OTM27-1 OTM27-2 OTM27-3 Test Date 4/26/2010 4/27/2010 4/27/2010 Run Start Time 10:00:00 AM6:06:00 AM 1:07:00 PM Run Finish Time 4:12:00 PM12:19:00 PM 7:16:00 PM Net Traversing Points 12 12 12 Net Run Time, minutes 360.75 360.75 360.75 Nozzle Diameter, inches 0.15 0.15 0.15 0.150 Pitot Tube Coefficient 0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor 1.02 1.02 1.02 1.020 Barometric Pressure, inches of Mercury 28.15 28.2 28.2 28.183 Average Orifice Meter Differential, inches H2O 0.38 0.38 0.40 0.387 Dry Gas Meter Volume Sampled, cubic feet 123.074 125.840 132.306 127.073 Average Dry Gas Meter Temperature, °F 67.54 55.83 67.08 63.483 Dry Gas Meter Volume Sampled, dscf 118.329 123.955 127.549 123.278 Total Moisture Liquid collected, g 251.7 298.4 309.8 286.633 Volume of Water Vapor, standard cubic feet 11.85 14.05 14.58 13.493 Moisture Content of Stack Gas, % 9.10 10.18 10.26 9.847 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.909 0.8982 0.8974 0.902 Carbon Dioxide, % 11.8 11.6 12.9 12.100 Oxygen, % 7.3 8 6.3 7.200 Carbon Monoxide & Nitrogen, % 80.9 80.4 80.8 80.700 Fuel Factor 1.15 1.11 1.13 Dry Molecular Weight, lb/lb-Mole 30.18 30.18 30.32 30.227 Wet Molecular weight, lb/lb-Mole 29.07 28.94 29.06 29.023 Flue Gas Static Pressure, inches of H2O 2.6 2.5 2.5 2.533 Absolute Flue Gas Pressure, inches of Mercury 28.34 28.38 28.38 28.367 Average Stack Gas Temperature, °F 338.58 334.67 338.17 337.140 Average Velocity Head, inches of H2O 1.7331128591 42951.733112859

142951.733112859

14295 1.733 Average Stack Gas Velocity, feet/second 93.08 92.99 93.00 93.023 Stack Cross-Sectional Area, square feet 82.516 82.516 82.516 82.516 Dry Volumetric Flow Rate, dry scfm 262,339.3 260,613.3 259,267.3260,739.967 Actual Wet Volumetric Flue Gas Flow Rate, acfm 460,835.4 460,389.8 460,439.3460,554.833 Percent Isokinetic of Sampling Rate, % 84.1 88.7 91.7 88.167 Percent Excess Air, % 51.9 60.5 41.9 51.433 F-Factor, dscfm/MMBtu @ %O2 9780 9780 9780 9,780.000 Round Duct Diameter, inches 123 123 123 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10640 10640 1064010,640.000 Fc 1800 1800 1800 1,800.000



### Saturday, January 29, 2011 Page 10 of 10