NATX INST. OF 5TAND & TECH NIST

REFERENCE

NBSIR 77-1300

A Computer-Assisted Evaluation

of the Thermochemical Data of

the Compounds of Thorium

D. D. Wagman, R. H. Schumm and V. B. Parker

Physical Chemistry Division

Institute for Materials Research

National Bureau of Standards

Washington, D.C. 20234

August 1 977

r> ^rati for Qd, 3nal Atomic Energy Agency

f Standard Reference Data, NBS

/f77

NBSIR 77-1300

A COMPUTER-ASSISTED EVALUATION

OF THE THERMOCHEMICAL DATA OF

THE COMPOUNDS OF THORIUM

D. D. Wagman, R. H. Schumm and V. B. Parker

Physical Chemistry Division

Institute for Materials Research

National Bureau of Standards

Washington, D.C. 20234

August 1977

Prepared for International Atomic Energy Agency

and

Office of Standard Reference Data, NBS

U.S. DEPARTMENT OF COMMERCE, Juanita M. Kreps, Secretary

Dr. Sidney Harman, Under Secretary

Jordan J. Baruch, Assistant Secretary for Science and Technology

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting Director

TABLE OF CONTENTS

I. General Description

1. Introduction 2

2. Explanation of the Contents of Tables 3

3. Unit of Energy and Fundamental Constants 8

4. Internal Consistency of the Tables 9

5. Arrangement of the Tables 11

II. Tables of Values for AHf% A3f° and S° at 298.15 K for

the Compounds of Thorium and the Reaction Catalog

III. Bibliography

IV. Appendix: Thermal Functions for Thorium Compounds A-1

Th(c,l) A-6

Th(g) ' A-7

ThO(g) A-8

ThO^Cc) A-9

Th02(g) A-10

ThF(g) A-11

ThF^Cg) A-12

ThF^(g) A-13

ThF^(c,l) A- 14

ThF^(g) A-15

ThCl(g) A- 16

ThCl2(g) A-17
ThCl^Cg) A-18

ThCl^ (c,l) A-19

ThCl^(g) A-20

ThBr(g) A-21

ThBr2(g) A-22

ThBr^Cg) A-23

ThBr^(c,l) k-lu,

ThBr^(g) A-25

Thl(g) ' \ A-26

Thl^Cg) A-27

ThIgCg) A-28

Thl^(c,l) A-29
A Computer-Assisted Evaluation of the Thermochemica 1 Data

of the Compounds of Thorium

by D. Wagman, R. Schumm, and V. B. Parker

Abstract

Selected values are given for the thermochemica 1 properties of

the compounds of thorium. They are obtained from a computer-assisted

least sums-least squares approach to the evaluation of thermodynamic

data networks. The properties given, where data are available, are

enthalpy of formation, Gibbs energy of formation, and entropy at

298.15 K (AHf°(298), AGf°(298), and S°(298)). The values are consistent

with the CODATA Key Values for Thermodynamics. The reaction catalog

from which this self consistent set of values is generated is given

with a statistical analysis. Some thermal functions are also given,

as well as detailed comments when necessary.

Kej^ords : Data evaluation; enthalpyj entropy; Gibbs energy; thermochemical data networks; thermochemica 1 tables; thorium

compounds.

1
I. General Description

1, Introduction

This report presents a computer-assisted comprehensive evaluation

of the thermocheraical properties of compounds of thorium at 298 K that

is consistent with the CODATA Key Values for Thermodynamics [75COD] .

A combined least sums-least squares technique previously described by

Garvin et al [76GAR/PAR] has been used. This computer-based evaluation

is an extension of the CATCH program developed by J. B. Pedley^ University of Sussex v7ho used linear least squares analysis on enthalpy

measurements [69GUE/PED]

Thorium represents the first complete analysis of an element and

its compounds to be done by this least sums-least squares approach to

the evaluation of thermodynamic data networks. A self consistent set

of values for Zfflf°, A?f°^ and S° is generated from the given reaction

catalog. A detailed analysis of the values leads us to believe that

they are as good as and as reliable as those which would be obtained

in the traditional sequential method. Comparisons of the performance

of the computer-assisted method used here versus the traditional

method are given in [76GAR/PAR],

A major advantage of this method is the rapid updating that is

possible when new data become available or if the interpretation of

the existing data must be revised. Another advantage of this method

is that a translation from one scale of auxiliary values (CODATA here)

to the NBS Technical Note 270 Scale or some other scale can be made

readily.

cL References are given in a chronologically ordered bibliography at the

end of the report. They are cited in the text in coded form indicating

year of publication and the first two authors.
This report provides the following data: the final selceted values

for /:^>Hf°, AGf" and S" for the compounds considered and their predicted

reliabilities, the values used for auxiliary compounds, a catalog of

the measurements upon which the solution is based, some newly developed

thermal functions and, where, needed, comments on the interpretation of

the data.

The values for properties of auxiliary compounds are either

CODATA selections [75COD] or compatible with them [75PAR/WAG].

The reaction catalog (following the selected values), from which

the solution is derived, contains the set of experimental enthalpy,

Gibbs energy and entropy changes at 298 K as well as entropies at

298 K from low temperature Cp measurements or statistical calculations.

It also contains for each reaction the initial assigned uncertainty,

the final weighting factor, the residual (i.e., the observed minus the

predicted value), the standard deviation of the predicted value (95 per

cent confidence level), a coded citation to the Bibliography, and,

occasionally, brief comments on corrections made to or interpretation

of individual measurements.

User^ of th'^ tables and reaction catalog are invited to comment

on the selections, correct errors and bring new measurements to our

attention.

2. Explanation of the Contents of the Tables

The following material provides definitions and conventions used

in the tables.

3
2.1 Chemical Formulae and Physical States

The tables were reproduced from computer printout in which only

capital (upper case) letters are available. Normal one-line chemical

formulae are used^ with the following modifications:

Subscripts (counts of atoms) and superscripts (charge) are printed on line: TH'CL'4 = ThCl^; TH'CL'+3 = ThCl^

The apostrophe ' appears after each letter in a chemical

sjmibol that would normally be written in lower case: TH'N = ThN

The centered dot^ used in hydrates and minerals^ is shown as

a colon: TH'F4:2.5H20 = ThF, •2.5H^O

4 2

The physical state of the substance is appended to the chemical

formula in parentheses: TH'CL'4(C) = ThCl^, crystalline

Conventions with respect to physical state are given in Table A.

2.2 Definition of S3mibols for Thermochemical Properties

The headings used in the tabulated Thermochemical Values have the

following meanings

DELTA HF = zXEIf", standard enthalpy of formation at 298.15 K;

DELTA GF = Z^f°, standard Gibbs energy (formerly free energy), G,

of formation at 298.15 K;

+/- SIGMA = Predicted reliability, "one sigma" (see paragraph 4.1)

In the reaction catalog the heading, PROP. MEAS. refers to

A3, and Z^S at 298 K for the process given; the S3mibols used are H, G,

and S; the symbol S means S°2gg when it refers to a "process" written

without reactants:

= TH'CL'4(C) S = 45.5 (standard entropy of cryst. ThCl,)

4
All H and G relationships are in kcal/mol; all S relationships in

cal/(mol'K).

All values refer to one mole of substance for the formula given.

2 . 3 Conventions Regarding Pure Substances

The values of the thermodynamic properties of the pure substances

given in these tables are for the substances in their standard states.

These standard states are defined as follows:

For a pure solid or liquid, the standard state at any temperature

is the substance in the condensed phase under a pressure of one atmosphere.

For a gas the standard state at any temperature is the hypothetical

ideal gas at unit fugacity, in which state the enthalpy is that of the

real gas at the same temperature and at zero pressure.

The phase of a substance is indicated in parentheses at the end

of the chemical formula. See Table A.

The values of AHf° and ASf given in the tables represent the

change in the appropriate thermodynamic quantity when one mole of

the substance in its standard state is formed, isothermally at the

indicated temperature, from the elements, each in its appropriate

standard reference state. The standard reference state at 298 K for

each element except phosphorus has been chosen to be the standard state

that is thermodynamically stable at 298 K and at one atmosphere pressure.

For phosphorus the standard reference state is the crystalline white

form; the more stable forms have not been well characterized thermochemically. The same reference states have been maintained for the

5
elements at 0 K except for the liquid elements bromine and mercury

for which the reference states have been chosen as the stable

crystalline forms. The standard reference states for the elements

are indicated in the tables by the fact that the values of /SHf° and

Zfif° are exactly zero.

The values of S° represent the virtual or "thermal" entropy of

the substance in the standard state at 298.15 omitting contributions from nuclear spins and isotopic mixing. Where data have been

available only for a particular isotope^ they have been corrected

when possible to the normal isotopic composition.

2 .4 Convention Regarding Solutions

For all dissolved substances the composition of the solvent is

indicated in parentheses following the chemical formula. Except in

special cases ^ discussed below, the number of moles of the solvent

associated with one mole of solute is stated explicitly. See Table A

for the conventions used^

In some cases the concentration of the solute can not be specified.

These are indicated as "AU" (aqueous, unspecified) for water solutions

and by "U" for non-aqueous and mixed media. In all these cases the

solution may be assumed to be "dilute".

The standard state for a non-dissociated solute in aqueous solution

is taken as the hypothetical ideal solution of unit molality, which

has been designated as "std. state, m = 1", For strong electrolytes

in aqueous solution the conventional standard state is the ideal

/)

6
solution of unit activity (unit mean molality). The designation "A"

is used for strong electrolytes in the standard state and "AO" for

undissociated species in water solution. In non-aqueous media two

standard states are commonly used. For the mole fraction scale,

"std. state, = I", x is added to the formula of the solvent. For

the molal scale, "std, state, m = 1", either s or M is appended to

the formula.

The value of Z\Hf° for a solute in its standard state is equal to

the apparent molal enthalpy of formation of the substance in the

infinitely dilute real solution, since the enthalpy of dilution of an

ideal solution is zero. At this dilution the partial molal enthalpy

is equal to the apparent molal quantity. At concentrations other

than the standard state, the value of AHf° represents the apparent

enthalpy of the reaction of formation of the solution from the

elements comprising the solute, each in its standard reference state,

and the appropriate total number of moles of solvent. In this representation the value of AHf° for the solvent is not required. The

experimental value for a heat of dilution is obtained directly as the

difference between the two values of AHf° at the corresponding concentrations. At finite concentrations the partial molal enthalpy of

formation differs from the apparent enthalpy.

The values of the thermodynamic properties tabulated for the

individual ions in aqueous solution are based on the usual convention

7
that the values of AHf°, AGf", S" and Cp" for H*" (aq, std. state,

m = 1) are zero. The properties of a neutral electrolyte in aqueous

solution in the standard state are equal to the algebraic sum of

these values for the appropriate kinds and numbers of individual ions

assumed to constitute the molecule of the given electrolyte. For an

ionic aqueous species e.g., y ^^'^ properties tabulated refer to

that undissociated ion, i.e. they are not equal to the sum of those

for its constituent ions. By adopting the above convention with

respect to aqueous H^, it follows that the thermodynamic relation

^f° = ^*'-T(^f° + n-0.5S''(H2)) holds for individual ionic species,

with n equal to the algebraic value of the charge. For neutral

electrolytes the normal consistency relationship applies. See

section 4.

3. Unit of Energy and Fundamental Constants

All of the energy values given in these tables are expressed in

terms of the thermochemical calorie. This unit, defined as equal to

4.184 joules exactly, is generally accepted for the presentation of

chemical thermodynamic data. Values reported in other units have

been converted to calories by means of the conversion factors for

molecular energy given in Table B,

Values in this report are consistent with the CQDATA Fundamental

Constants [73COD].

The formula weights in the tables have been calculated from the

molecular formula using the 1969 Table of Atomic Weights [70IUP].

8
Values are given to four decimal places for convenience in the

computer processing.

4 . Internal Consistency of the Tables

The processes given in the reaction catalog have been obtained

from the original articles^ using consistent values for all subsidiary

and auxiliary quantities. The original data were corrected V7here

possible for differences in energy units, molecular V7eights, temperature scales, etc. Thus we have sought to maintain a uniform scale of

energies for all processes in the tables and catalog. In addition

the final tabulated values of the properties of a substance satisfy

all the known physical and thermodynamic relationships among these

properties. The quantities AHf°, -AGf% and S° at 298.15 K satisfy

the relation:

AGf° = AHf ° -TZ^f

to the precision given. The special case of solutions is discussed

in section 2.4. Furthermore the calculated value of any thennodynamic

quantity for a reaction is independent of the path chosen for the

evaluation.

4 . 1 Uncertainties

The uncertainty reported for a selected value is "one sigma" as

developed in the final least squares solution of the reaction data

base. The magnitude of the uncertainty reflects the overall fit of

the data in the entire network. It is not an estimate made by the

data analyst based on how well various small sections of the network

fit together.
These uncertainties, when used in the usual "square root of sum

of squares" formula overestimate the uncertainty of a process. This

is because the selected values (answers) are highly correlated. Better

estimates for processes that are in the data network are provided in

the listing of the reaction catalog. These estimates allow for the

correlations among values.

Since the selected values are computer generated, more places are

given than may be warranted by the uncertainty. Although these extra

figures in the absolute sense are not significant, the retention and

use of these figures ensures that the experimental data from which

these values are derived may be recovered with an accuracy equal to

that of the original quantities. This is particularly important for

enthalpies of solution, dilution and transition.

4.2 Relationship to Other Tables of Thermodynamic Properties

The chemical thermodynamic properties in the present table may

be combined with those published by CODATA in order to calculate the

change in a property for a process. However, we recommend against

these values being combined with those in any other tabulation or

with a property reported in an original research paper. In particular, we warn against indiscriminate combination with the NBS Technical

Note 270 Series. A conversion to the NBS Technical Note 270 Scale

will be made and included in that series.

There are several reasons for avoiding the combination of thermochemical data from more than one table. The most important is that

different large-scale tables use different thermochemical propei cies

.10

- i

I
of formation for substances that are ubiquitous in thermochemical

measurements. Outstanding examples are in the common inorganic acids

and their ions. Another reason is that the groups preparing different

tables may have relied on different measurements as the basis for

selecting property values.

It is difficult to predict a priori how a change in one selected

formation property would affect values assigned to other substances

because of the way these are linked by complex networks. In general^

it may be expected that the advantage of internal consistency of a

table will be lost if values frcm several sources are combined and

the experimental measurements may be reproduced poorly.

No general, simple algorithm can be suggested for overcoming

this problem. If it becomes necessary to extend a table of data to

substances other than those tabulated, the user is advised to consult

the group that prepared the table about the procedure that he plans

to use.

5 . Arrangement of the Tables

The compounds in the tables are entered according to the Standard

Order of Arrangement, (see Figure 1), by the principle of latest

position. In this scheme, a compound is listed under the element

occurring latest in the list; water of hydration is neglected. Within

a given element^table will be found all of the compounds of that element

with elements occurring earlier in the order; the arrangement within

a table follows the same ordering.

11
STANDARD ORDER OF ARRANGEMENT

12
TABLE A ; Physical State Conventions

The following conventions are used to designate the physical

state of a substance. These apply to the attached table and to the

NBS Thennochemica 1 Data Bank, This information appears in a

parenthetical expression appended to the molecular formula. Some of

the explanations imply a thermochemica 1 value^ particularly those

for solutions. These normally are used in describing enthalpy

measurements

.

Basic Symbols Explanation

(G)

(GS)

Gaseous, e.g., HCL' (G) for HCJ^(g)

Gaseous reference standard state for an element,

(L)

(LS)

(C)

(CS)

e.g., 02 (GS) for O^Cg)

Crystalline, e.g., NH4CL' (C) for m^C^(c)

Crystalline reference standard state for an

element, e.g., RB'(CS) for Rb(c)

Liquid, e.g., H20(L) for H20(i)

Liquid reference standard state for an element.

e.g., BR'2(LS) for Br2('^)

(AM)

(GL)

(A)

Amorphous

Glassy

Hypothetical standard state of the ideal aqueous

solution at unit activity. For a neutral

electrolyte the value of a property is equal to

the algebraic sum of the values for the ions

assumed to constitute the molecule of the

electrolyte, e.g. HCL' (A) = ffl-(A) + CL'-(A). For

an ionic species this notation is commonly used to

refer to the undissociated ion as written,

e.g. HSOi-(A)

13
Symbol Explanation

(AO) Hypothetical standard state of the ideal aqueous

solution at unit activity of the undissociated

(non-ionized) species, e.g. HF(AO), HF2-(A0).

May also be used whenever the designation (A)

could be ambiguous. Note that the descriptions

HS04-(A) and HSOi-(AO) are equivalent, but that

HF(A) and HF(AO) are not.

Aqueous solution of undefined, but usually

dilute, concentration, e.g. XE'03(AU).

(AU)

The sjnnbols used above occasionally are modified by numbers to

distinguish two substances in the same state that have the same molecular

weight, as for isomers: (AU2) , (C3). They are also used in combination

with descriptive material, e.g. (C:HE'), (C:AL') etc. to mean "crystalline,

hexagonal", "crystalline, alpha form" etc.

Special notations for substances in solutions

The notations for the "state" of a substance in solution may combine

a definition of the system, e.g. HC-^ in 220 moles of water, and a

specification of the thermochemical property associated with it.

Usually the thermochemical property is the apparent integral enthalpy

or free energy of formation or an absolute entropy, i.e. the formation

properties of the solvent are not included. If a partial molal property

is tabulated the notation D: ("D" for "differential") occurs as the

first term in the state bracket. The notations given below illustrate

the differences for integral and differential (partial molal) properties,

and extrapolated values. Examples are given for aqueous, mixed, and

non-aqueous solvents.

14
Symbol

HCL' (200H2O)

HCL' (D:2 00H2O) and

H2O(D:HCL'+200H2O)

UCL'4(HCL'O^+50H20)

UCL'4(HCL'04+

50H20:AU)

Explanat ion

An aqueous solution of specified composition,

e.g. one mole of HCjJ in 200 moles H2O. The

value of AHf represents the apparent integral

enthalpy of formation.

These represent the partial molal (enthalpy) of

formation of the substance in a solution of

specified concentration, e.g. the partial molal

enthalpy of formation of HC^ and respectively,

in a solution consisting of 1 mole HCj^ and 200

moles H2O.

This describes a solute dissolved in a mixed

solvent, e.g. one mole of VC£^ in a mixture of

1 mole of HCiO, and 50 moles H-0. The value of

4 2

Atlf represents the apparent integral enthalpy of

formation of the substance, UCi^, in the medium.

This represents a solute at an unspecified but

usually dilute concentration in a solvent mixture

of fixed composition.

15
PQ

Pi

i=» IHM

COHOBH

CO 3O

(U

t-lo>oeIoe

vO1 _ _ \^

ty^ <• 1 1 1 VD

<}•

XX

X

vO vO 0

CO CO in CO O CO 0• I—

<^ 1—

CO

CO

U) t T—

CO 1 [ 1ur\1 CO ON X r

X X On

LO ON •s <! 0 • 00 CO 00 CO

inI I /—

\^

in r-H in 1—

X 00 0 OS

r-l CO

<f CNJ CM

00CO

00

CM

o>

CM

4J

O

00

VO

CM

a\ o .—I t-i VD X

inCO

00

CMm

CMOCO

invOo

00o

00 1 CM 1 I-l 00 0 CvJ 00 '0 0 CM l-l in 1-1 X CM X <f X

1^ vO r-l

r-l 00 % • CM 1—1 CM I vO CMI

CM

CO

COo o6u

CO o 3uM

II

(U

i-i3o

(U

I-lo>

01 c

•Hc

•I-l i

<uu

COiJ

CO x:

00

•H

?> •HU

(U

CO CO > a,

•r-4 CO CM 0 00 CM 0 t-i JC

CM 00 I-l

m vO CO CO CO CJN CM CM X in 0 CM 4-1 G

vO ON

m c 0

00 CM I-l in • 00 CM •rl • CM I-l in i U

1—1 CO CM I—

OS CO CO TD I-l G 0) 3 >-i

l-t CM «-l (U 1 1 1 d) ^ 1-4 r» 0 0 in I—

CO I-l I—

r~ I—

u 0 X X CM CM X 1-1 • 00 0 I-l I-l as CTi 0 4J fi

I-l a\ CM in

m vO

C 'H

CO CO 0 in 00 0 0) >. 0 • • \£> • CO CO 1—1 CM .00 in CM CM 0 Oi u a.

CU CO r-t 0)

ir\ SOu >^ CM 0 0 vC in XI

I-l CO 0 0 vO CO 0 <1- I-l 0 vO CM <f U 'V e r-t 00 0 •> CM 00 Q) (U

1-1 0 CO <!•

x c • • 0 • • so e -H 0 vO

•> CM I-l I-l

<ys 2 "5 3

X3o

(U3

CO

>-i o

(U

u

x: CO H (4-1

•H

I-l 0 so 0 CO 0 II I-l I—

as r-l 1—1 I-l (U I—

X CM X 0 X CO 1-1 so CM 00 3 1-1 CO G • • • CO vO CO CM <u
II. Tables of Values for AHf°, and S" at 298.15 K for

the Compounds of Thorium and the Reaction Catalog

M p) CM

N in (\j o o> eg 0> o m « r)

CVi PS ' ^ P) in in f< o in CO n n rj D n m n o in « <o CO CO X) <0 m CM o n (M

COm •* •* tn in * <0

N IS (0 in CO o>

ro

n r) rj

n r)

in o o <t in « o in o CD

N in

m CM fO tn « CM « z CM <* <t U) tn in in (0 0> tn Ifl o n m r) PO n n P) M cS (8 a to 1- o o 0^ « in <o o n CO rti o (0 o in CO >o CD c^ n (S n o m <t (0 CM n IT" CM N « o « u CM ru * 0- < in <o in in •o in <0 t- N N m in a (S to m < n n r) 10 p4 n «4 p) « o o o w M «4 W 1 o t 1 1 111 s • +

»- + — tf) I 1 <o CM

15 -1

N

M o • • z CM in m V) •< o o o in o o I I+ o o Q in O P)

UJ P"

(D o lO CM * * UJ *

in

Q * 1 Atx If) V 11 1 1 Z UJ + + 1

f-i t o U o o \J o o z Z * * •

UJ < \L CM < Q m O u. -1 < z 1 O o UJ 1 VI o u o M zo ^ ^ z in z < o o p) CM v» o < o z o o O CM o z o N M < 19 o CM UJ CM

H- z * * • * • * * o • 3 < in •4 o o

-1

J 1 z < O 0, s 1 1 1 1 1 1 s 1

1/)

X + + + + + + u UJ +

UJ 1 o o CM (M CM CM o z o N

N u. o o o h"

N

N z o o O in

O in z O

u: z • • • • • • * • S O < • CM n o CM PI <

CM IL * to inN o u 1 s J < CM in O « N < UJ 1 z o UJ UJ < w u I z < O u

»-< > • UJ • in Q IZ CO 03 03 03 <D 0) 05 I CM N < P) n PI P) PI P» PJ • o in o in o o O o o 1- O < _J • N • N • • • • • a • o CM CM CM CM CM CM CM • < a X z PI P) P) P3 PI P3 a * Z D CM CM CM CM CM CM CM • CM

lU < u. • z > > in

\J U. • o a a z z z

oc o < < O u z a a H a z M H z

t- UJ UJ UJ o > > o u X M 3 -1 *- Q o < < Z z s UJ < < 2 z o Z Z z UJ UJ • in D >- S O • z

IL UJ

a < < a UJ

O z U) z O

U. o < < O < \s UJ < u in a O O J 19 o

in o o CM P) <»• Ul UJ u u + + + O < UJ z I r r I z Z z < o • t- »- 1- t- t- u z oz o O P) « w u o CM CM CM p) oz

CM CM CM CM CM CM (M

N

toO

O o CM < o P) P) P) o in o o o • • • • • 1+ 1 I + 1 1 o- o o o o o N

in

N o • 0 • • • O CM P) (M

*4 <0 ff«

O1 uO CO O in CM < (0 o 0-

CO o (M • • • • 14- 1+ 1 1+ 1 O N in 03

in P3 o CM

PI

N « CM • • • • • o O CM

CM CM P> CM1 T 1 1 CM1 w * o CM <o O

p)

N 0> oo • • • • • t •

P41+ 1+ 1+ 1+ 1+ 1+ 1

P) o o o o o in

CM (M rm o o o P) <0 CM • • • • • t • m P) CO P) CM (0 «

PI 03 P) CM «4 1 (M < O U < 19 w O w

CM

O CM o u o z z

19 <•

m•

CM CM P) O Z Z z z z

CD «

P3 *

CM CM CM

N

O * m

CM CM o « O

O

O P) o IS CM O K o « • • • • •

•4 CM f4 P) ro ii 1+ 1 1+ o in o N CM o o o

in o in • • • • • o n « N N 10

P3 PJ

N * (M « CM o CO P) O (M CM • • • • • •

(M 1+ + 1 i 1 O * O o «

in

N in CM • • • • « •

CM CM N * in CM »

CM CM

n PI

o« - *

0> CM

03 • • • • •

CM CM 1+ 1+ 1 1 1 o O o

in 03 o « in n M o • • • • •

in

n

N

in * 03 eg

CM P) CM « I I

in » o 0. .it tn o o in in 0" <^ PJ PJ « « O tn CM <0 lO <* PJ P»

p) p) p) P3 10 in 0« PJ PJ PJ PJ

n PJ o o m o o o o o o o o o o o o • • ^> t • • • • • • • « • • • •

0) « o> * tn 03 o o

<• « — « o PJ PJ « m in

NN 03 09 CM (M w CM CM CM CM CM CM < CM CM CM CM CM CM < < «

CM CM <

CM < < Z 19 N 19 Z o 19 PJ o + CM CM PJ PJ

CM U. U. U. U. U. U. z Z Z z Z Z z z H 1- (- H K H

<J> 03 * O 0> CM 03 UJ <0 N O » O

CM CM CM CM CM CM (M CM c»
m <o o •-4 o <0

n

n o N 0» o CO 10 o o in CM <c n in N 0> in r) in in <c <0 n) ro !) ro

oo 0» o CM in

m in o (0 in 10 10 in

N « CO in o (0 in O <0 w tC (M ro m CO in p) < in lO <o

r) o f)

mmri fn ro 10

V) o N <0

m o «-«

N CD <»• o> « <t « Ifl in CO * « <0 CM z o in o o « (\j N (\J < (0 oo n <0 in < in in N

N o n m m »-i ^ ft CM *^ <^ D ro »-< n K in N m in CO o in *H CM <0 ro N o oo <^ O n CO <t in ro •* N 00 o to ^ (0 CM O « u o m o m <0 eg <M N \0 (M ro n < in N N in n O <o in in in in in <0 < n v4 (0 n *-» fO *^ Vi4 CM ro 10

d 5

(A

in I I ^ s •tos

tf) •

-J< o 10

O o CO

O o o N O o o o

in CM o o O o o • • • • • * •

CM CM CMN 1+ 1+ \ X 1 1 o O o o (0 o • . o o «^ o o ro o. . o N o o e • • • • • • •

in (M Ift CO (M CM 0) 9

10NO•Ni«o•I O

CM

in

(M

Ul < Ifl in 0< in <o lO e o <0 CM fO J z CD m n CM 10 * o 9- 10 N o

IS in ro in CM * S o in lO oo • • • t • • * * * • • • • •

1- in (M (M CM < 1 N 1 i 1 1 1 1 1 i 1 t 1 z + " + + + f + o 1 in N U) to O o N 10 o o o o

U. _l

N in (> (M o CM

N 0> oo o o (0 N N CM CM N « . •* - < z • • • • • • • • • • • • • • < CO 00 O CM — n 10 10 o « < t- _l N o CM « O 10 <0 <0 01 » 0> CM o J < < « ro CM CM CM CM N CM CM « CM CM o lU u 1 1 1 1 1 1 III t 1 1 1 1 1 u o ^ z < in <o s CM n (0 * • <0 <o <o <o oo <0 <0 0> 10 o Z CO CM N CM OO (0 o o <^ 0> N N CM

CM 10 o < <0 0" < <0 o

\- • • • • • • • • • • • • » • • t • 3 ••4 CM CM N o J • o s 1 1 1 1 1 1 X X 1 ; 1 1 1 1 1 — + + + + + + + + + 1 ro (^ o O in 10 CM CM CM CM CM 10 ro N o

U. _i * o o ro 10

n

O * <0

m 10 « CO 10

N I o < m CM <o

N in

O 00 in o o ro S z • • • • • • • 

• • • • • • • • • • t N < • CO CM 10 10 • o 10 <0 CD o

CM 1- -1

O o (0

N CO

n ro OO o N «^ CM •* \ _) < in m <a ro CM CM ro in (0 CO ro 10 ro CM CM N Ul u o ^ 1 1 1 \ 1 1 7 1 1 1 1 1 1 1 1 1 <Q

-I<WMX

UlXuo

'ZsX

ftoX

»-

ILooo

:^<<

U)oz • N

N CM ro •4 « Oi

N <^ 10 «4 10 in in o * * s o O o o o r*. ro o o o a> ro

10 ro ro 10 0« 10 in in in 00 in

N in in in <D s • o o o O o ro o a CO IS 03 oo oo CO J • • • • • • • • • • • t • * • • • • • • • •

00 o (0 10N CM (0 10n ro ro 0> in 10 ro 10 in CO z o o o in oo <0 O 10 N N N O o> N 1^ N CM 10 •0 ro ro CM CM 10 ro 10 n ro ro •» < <• in ro ro ro ro ro • • • < < <

•f o O o

CM CM CM X X X

CMo • • • U (J o o in •o + + o o o o o » <

CM ro CM CM (M -1 X < w < O X I I X (J u u 10

u • in CM U < < CM N OO X X X + o • u ro + « (0 CM o (9 < CM CM ro « * * < O • • t CM • - _l « IL -i J J J J -1 J -1 J -1 -1 u. u. u. O <J VJ (J (J u U u U u u — (J y — u o • • • • • w X I X X X X I I X X X I X I I I X I X X X

(-

K tH (- t- t- l- t- »- tK

«^

O ro « (> CM (0 o o 10 « o tn o * N o O O •4 •4 CM CM CM ro 10 * m in <0 lO <0

fO ro ro 10 10 10 ro P) ro 10 ro 10 10 ro ro 10 ro 10 ro (0 ro <o — > « J • u a

OO » » X X o ro

10 ro
W CM -WJ ro CM

111 s w

O V* CM

fk,.

w ^ m fO

n 10

</> <o o m in CM Z CO !>. 0^ 00 t o n '* n ro M

U) fhV' ^ (VI ''I lO* ' ^w to 10 (D CM *^ tD CM wr» msu m*JU Ow p" V* CO *o (7^ (7^ r^

fO ^ *^ ^ *^

M ^ ^ ro ^ ro ^ ro CM

ill UJ 1 Aw ID III 10 PI lw

Ql 00 flO o 3 * •

*• CM

_o 1 1 1 1 UJ \ 4. + ^ O 10 CM ro 10 1 <D o Ifl CM o O %

111 (0 CM

V) • o n J<

III III < ff) iO 10 10 o m to 1 Q 30 «i4 «4 ^ m(U 10 fO tf) tn ^ (0 CM 10 *

*4 CM CM fO 1 I f 1 1 1 1 1 1 1 \ ^ ^ ^ o 1 in o o ^ o O 1^ O o

IL -J (0

N CD ^ <o CM ro o O o n N 0) CD N a» 10 * • * • •

ro ^ N 10

oo ^ to CM o ro ro

u CM CM CM CM O III f 1 III 111 1 1 1 11 11 z fO f) CM O V*

w o u fO Oi CM ro O o w 10 o o o to CD 10 to * * ^ *

«I *

(0 p4 1 1 o 1 1 I 1 1 1 1 1 I 1 1 ^ -f i 1 1 I 1 ID to 10 CM CD O

P" IL -J IX) <D 10 P) I o CM •i^ (0 10 r^ ^ (0 \ z • • • • • • • • • • ^ • ^ lO O D\ ^

CM CO 10 ro ^ 0^ m CM AV" 11 UJ o 1 1 I 1 «4 1 I1 11 11 1^ ro ^ CD 10 CM o ^ w (AW ^%^7 AJ %F\ t0 O kC ro

10 10 S o fO ^ ^ lO lO sr ^ Ol Ok (A t/^ \W V 1^ CD CO

J # « • * •

|Sk 1^ ^ v iD *4 z lO \f\ V in fn MM Ul IV D ro to to o o

10 ^ fO ^ ^ ^ to to

© CM

III W%

III « ft W w ^ ^ O

01 CM Q Q w^ nu O ^ CM I O CM CM D ^ *T ^ Al»M CM o X o (M A N 10 ro Q z W W ro o o ^ * • ro 10 <5 • fr oe ^ ro CM Q Q I u o a IX tr cr a (D (0 « w o ^ J (D (D (D (D M o < • • • • X X i X XXII z I i i X i i < • K 1- H H H H 1- K U oz O CM 10 ® N O •0 CM to

U)

N CO flO (0 c^ Ok o o o o ^ CM 0 1*) ro fo n * z

p)

Q o !«.

n o )».

N (\i (\J 10 ro fO CM

ro

m in o 00O

p. 04 CM CM fO ro >0

ro (0

N ro ro ro (M CM fO CM CM CM CM

ro

m in < in « c CO

N 00 in

O <0 10 o N N o o «-« CM CM CM CM ro ro <0

Oi 10 ro

N 10 ro Oi CM 10 CM CM CM CM

N (M

00 rom CO o ro (M r>- 00 >0 ro «t ^.

O 0' CM ro 10 ^

1^ CM CM CM CM CM ro ro ro

<\i ro ro (\i ro

N ro (VJ CM ro C\i ro CM CM CM ro CM CM CM CM CM CM

(0 10 10 o o>

<D CMO

N

10 10 ro CM o o • • # « •

CO Oj CM CM i 1 1 + 1+ 1+ 1 O in in ro O+ ouo o (0 O <o o O (D o ro in 10 O « 9 • • •

ro 10 oo CMn

O Ql

N « 101 n CM1

OO P)

10 »0

m 10 in * o> in 0> o o in o ro O N CM CM o o ro (M ID *4 c 10 N

CM 10 (0 «i4 »4 CM 1+ 1 1+ 1+ 1+ 1+ 1+ 1 I 1 . ro in 00 CM CM CM 00 o O e

'0 ID in CO gt CM «

CM M> s in in

N ro ro 10 • • • • • « • • •

ID 10 CM <c in CO in to ro CO CM

CM ro in inN CO CM CM 1 1 g 1 1 1 1 1 1 1 1

CM o ro (0 CO in CO o *4 o ro tO o o CM S o N o N • • • • • • • • • •

CM ro CO CM (M 1 1+ 1+ 1 1+ 1+ 14- 1 1 O o o o o CO o O O

(M o o o ro ro <0 N o ro CM o o CM • • • • • • • • • • < CO N N 10 CM

in in ID 0> o O' CO

CM * 0> ro 1 to ro 1 1 1 1 1 » f 1 1

«4 CM ro

N

N ro ro in CO o 0>

N

N

IS <0 <0 in ro fO o CO < ro S N

N

in tn ro CO <j> in in -• <o <• in 10

CM in (> o -4 CM CM o o o o o • • • • « • • • • * • • • • •

<o o o to o <o

m « o o

<0 CM o CM CM CM CM - in tn CO o

CM in

O o n in « CM

N CM

n

<M < < < O< CM CM

U < < 1 1 < + u ' CM CM 10 CM

u CM

U

u CM + t * ro ro ro

ro fO

O o o U 10 o o o

CM (A tn

O Vt «n

w

w z o z z z

(0 CM roN z ro z • • w • • • z z z r z z z z z z z z z z z

»- »-

K t- ^-

K tK

N

O ro o CM in (0 s o n «

CM CM (0 ro 10 * in in in « <0 « « <
in

lU3 O CM N n

!«) (0 CO o CV) CM CO r* z to CO CO (0 ID CD 0" O o (M tn c\» w CM CM CM n CM r)

CM V4

O

O

O 0> 0 N •* S CM

m •* If) <0 (0 c^ o CM

N 0> o CM 1/)

N o n

U <0 <0 < •* CD

N

NN CD 00 00 (S CO <^ CO c^ o < N CM CM (M CM CM 01 CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM CM r*) CM CM CM fO 8 n

Ul z

V)os <s

V) I i ^ \ •

»•Ioz m « oI ona•

CM

Oo

CMIoo

-JID< t Q. \ Z 4- « O I U U. J o o < z H < < »- J O J < O UJ w> u o ^ ooI+N

•A

in10I

0>

O

O «^ 01 CM in 0> t-t «-« m* o in n in (M 9 • • • • • •

CM P) 1 1 1 1 1 1 + + + + + o o CM o O * « oo (D o o

(D o 00 o • • • • • « • * O o CM in < «

CM *^ N 1 n in CO <o 1 1 • 1 1 1 z < •4 «4 <o <o *4 N m m v4 in «^ «-4 O o CM o in in CM CM CM CM CM CM CM CM NO oo CO in 00 in o o CO m N N N N o o o n o o CM tn CM • • • • • • • • • • • • • • • • • • • • • • • • • • • t

tf>

—

•14

m

O 1 1 1 r i 1 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 i 1 w > + + + + + 1 + + + + + + + + + + + + + + + + + 1 « O in O <D CO •* 'D CM fNJ eg CM CM CO CM CM in o OO N u. _l in N N (0 in N o s (M CM in <0 >0 CM CM o o CM O in CO » 00 X o 00 CO m O « in in in N in CD v4 nO n s z • • • • • • • • • • • • * • • • • • • • 9 • • • • • • •

h- < 9 o OO CM CM CM CM CM CM CM CM o N CD ID in o m

CM <D 00 CD CO

O 00 00 00 <0

N

N

O in OO CM CO

n 0* <*• (0

N CM CM « S < D « N r) r> r) n n P) n n < * in in <o •O 1 CM 1 N 1 1 • 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 o 1 < • N N N s N N <s in tn o o in in N N c^ in in o * r<4

N > o N < N N N N N (M CM * in in CO OO CM CM c^ in CM W O N s 9> <0 in —* n in in in in m in in in o vO r4 o O o CM to <0 in N lO C^ • o •« o o o o o o o o c^ o o o o CM CM o o o o o n o o O o < • • t • • • • • • • * • • • • • • • • • • • • • • t • • • • • • • • o o CM o o o o o o o o o N o to n CD (D o o o CJ> in to o CO to « z 00 in OO 00 CD CO OO 00 00 OO CM N s r- CD CD o CM CM CM in in CM o •-< 0) z in » « * •« •* in in « to CM CO n <• CM CM CM D 10 <

III Xuoz

aelUo o X 2

»- 3O

Ul

a o zo o u o

-I<< • u oz

enm u. z X o u

u

CM

w

X o o O CM CM in X I n 4' in ^* * «• n t») r) o o o z z z ooo

inooX oo

<0*ouX

GOo ooo

«4o

-IuX

OO •« »< in o

CMXo U «• CM w . — O - _J U J o — « U * P> • * I X -I I z z o Z CM <•

P) ~ n o ro o ro O O O CM O CM O Z CM Z X Z X Z I O O X o n o n 10 CM O CM O O X Z X z o z O w o " CM

— * 0 —

CM ro o •* * in 1 O CM - - • X O Z I J J J z O w o u u w —

m tn X X z z

CM -»

m

..

y .. <t • It - m •

-J I -I u z u N

CMUmXz

CM * m • I J z « X

_j z U w - I-J z — < w CM n + + CM« o « <M _ o o — s, a a — 01 O < CM CM CJ • »» a X X —

ia

m ^ w (J

u

w o

CM CM o u - o • CM < O I — < <0 CM < - •• I w CM CM n

CM « * * * o o o

CM CM 01 U O U I X X X I X X X X X X I X X X I X X X X X X I X X X I X X X I X X X

t- 1- fK 1-

H 1-

K >- t- »-

H tH 1- »- ^- t- t- 1- V- *- tK 1-K 1- 1-

n <0 Ot 01 tf) 00 «-«

N o <o Ot Ol

m CD o m «0 0« OJ oo <t

O tO Ot CM 10 CO « o» Ot o o N in m <0 <o tO N N 00 CO CO o Ot Ot o o o CM CM 01 s in n 10 n m in m m in in in m in in m in in tn in in <o tO •o <0 o <0 « to
<<<z

UJzuoz

atlUzKOZ

ILoo

-I<<

IDZ

in in a« in to 0>

(\j CM < n to to n to 10 to to to to to

10 in o <o CD

a * o o (0 •-4 IS

N

00 CO to 00 (M (0 10 < CO to <»> to

ro (0 to to to to to ro

n to 10 ro ton o n tn 0> « N o> to o a OO in 1^ 01 V) z o oo CO CM 00 05 10 <^ to 00 ro <J> to z o ro 10 to n to to ro to to to to QM

fa o in o ro in >o vO o o CM o « <D o 1- o o o «^ rvj CD CM CO (0 ro CO c^ n <a ro (^ < r) tn (0 n n m n n n 10 to 10 fO to ro to to n ro to to to to to to to <

UJ Uia

0> «^ <0 ^ O CO o e < in (\J in N < o o o z in in in in co in 10 z o o o 3 • • • M <«• to

V) (A 1 1 1 1 1 1 1 1 1 1 1 1 1 1 s • + + + S • + +

tM in in (M o + in o 1 O O o 10 IS 0> 1 o o o

10 < (M

J o o o • • f • • • • • o • • • z c o 10 in in CM (M z mm

(A • OJ ro to to to o (0 « to < <u < o o CO * o N o CM o o < o o o z N w * C^ N o « z o o o O « <0 N o CO o n o o o • • • • «

in • « t w *4 tn CM U) 1 V 1 1 1 1 1 1 1 1 r 1 1 1 1 Js 1 1 1 + + + •f + + + * 1 o o o o (0 « CO in CO o o o

IL

J a> oo <B (\J to « * * ro -1 o o o o in o o o 10 o eg CO o o o o o z • • • • • • • • • • • • • z • • • < o in o o o o o o <

-J lt> <VI o eo 10 in (M to o <0

-1 < t-1 I 1 • 1 1 1 1 1 -1 <

UJ 1 1 1 1 1 UJo < o o o o o o o o o o o CO o (M 0) <0 o *M < o o o z o o o o o o o o o o N o « N in o z o o o

V9 o o o o o o o o o o « o N oo o 10 (9 o o o • • • • • t • • • • • • • • • • • • • • • 10Is+ -I U. -I X oz < * H J J <

UJu

O iC o

•4o o o

<o o I i o oo

to o • • «I o o o o M in <o o O O " o - in - CM in •« I I I I I I I t I I I + + + + + + + + + + oooooooooo^ UOoOOOOoOOtM oinr^Noo'OoinoN

OiC>*00>OOIO'0^iOO

(MIO>0-»-^<MtOCM*NrO t I I -• I I I I I I I

in

U.

J z oz < •

»- -J J <

UJ

u

a ^ +o o o o o o I I o o

in 0 o o

lO m* ^ S) 1 in I N

inm o>m 10

r»N

N

Oi o> 9 o • 0« OO m CM 0> to ro fH 10 m to CM 10 mm <o <0 • oo o o < in (- (M in to »-* CO * o •0 CO CO (0 * •* < IS IS <8 o 00 oo m • in • UJ CO

00 c <t CM ID CM o o in IS

O o c^ o o 0> • o CM 10 CM CM in <0 00 CM o « in 0" « o • o o J o o -1

-J • • t • • • • • • t • • • • • • • • • • • • -J • < • • < • < • < • < • < o o CO o 05 CM * t^ (S in (M O « in mm z CM z r>- z 00 z > (0 z z o> <t o o (D in n o * <0 < in <t CM « 0« CM O z 10 l—i CM CM 10 « CM CM N (D to ro « N o

«4

to in (M in o *

v4

O

•4 z

U. u. IL U, UJ>

U. < < • w V < o

lO CM

w <

CM •» CM 10

U - u

u - y - w w ^ (J >r orO'>'~~u<'CMinu^'<'^cMinw —

10 z z z I z o u uCM

w

N ^ • w CM to • • CM

_ - UJ UJ UJ • (MUco(n(/)M>->(/)i/)iuujuJoooM yU)wwwl/)i/)[OIOOUUtOfOIOZ

in

X

X I r

H I- IH IIXXIXIIXIIX

t-Ht-t-l-l-HI-l-Ht-K

•"4NOtOiOOiCMinO>-«*l>-OIOcM

ioroto<t*-*-*inininiO'0'OSNoo 3

-io

1/1 o

UIM

O 3 Z <

Ia < z o a

<J >

a.<J • M O X z 3< Ik oz

Ulzzo

UJa< • a

(/) o

CMo > < < z t- o < < y - O - Q

•« I/)

a < < O U o — «- I + <M I X I o

I/) z<Qz

UJzzoy

UJa<< — o

-i«.

y o

(Mz <ooyzoo

UJw<

15 < < u o . z z

UJ UJ z z z z o o y y

UJ UJ a s < < o • o • o «n o < y v9 y o n <o 9 M ^ M M CM
o o o <0 o

U) o o o o o o o • • • • • • 1 1+ 1+ 1 1+ 1 1+ o o o o o

0>

N

m o o s (g

Nn

n

N • • • • • • • n « N N 10 in in m (Vi 10 « n o o o o

01z o o o o o <0 o o o © (VI o o in o o o o o 0> o o o o o o 10 o o o o o o o «i4 • • « • • • • • • • • t • •z 1 1 1 0. 1 1 1 1 1 1 1 1 I

<«> * + 4> UI I + i + + f 4- 4- (g o o o o (A o o o o o o o o O t

<t) o o o o o o o in « o in o 0 I e * o o o o m e « » • o • • • • • • • t • z 1 J u o o <0

rjn

K o (M in 1 in 1 u. 1 1 o a

as 1 1 a

o>

M IQ Q z a • o o «^ O o in o o o o o o o o o o o o o o eg CD o o o O o

(M o (M o o u. o o •4 o N o o o o 10 (0 o « O o O o o o o o o o o CVJ o o o o o o 1 o ••4 -1 o < • c • • • • • • « • V) • • • • • • t « • • • • •- • t • o t • • Z o M h- M (g I

u. 1 1 1 1 1 1 1 1 1 UJ 1 1 1 ni 1 1 1 1 1 t 1 1 1 1 1 1 1 1 1 1 a ? + + 4- + N 4' i- + 4- 1 + + + (VJ ¥ f + + + 4 z + +

rt o o (A < m « N o o IS o CVI in CO o o in in (\l o o o c^ o o o O 1- o m o (g

10 o in o (D CO 1 CO 1 o < in ro 1 o m <n o m o <o 1 eg o tH ro o o ro \0 0) * z 10 2 o (D CVJ z in <n in o > in in OJ CVJ o CVJ in eg eg o (^ in z (^ < 10 o • • • • 1 • m • • m « • • • CD • • • t ) • • CO • • • • • • • • o • • • o in z CO z o CO CO z in in 10 z in o eg o: o in n f) o n n s O CM CVJ (VJ Q o *^ CD 10 N u. o ro < 1 1 1 in 1 1 in 1 1 1 m 1 ct r 1 a 1 1 in 1 2 1 eg 1 1 1 1 1 o m Q o • Q in in o 1 in u. o z in in z a a: in a z in z cc in in in in X in lU N in in N in in a N N c^ N o ^ eg I 0> _j z z 0> z z • z (X Ov r-4 9 o z 1 •4 o -1 in • z o o o o o o o o fvj o ° z o m (VJ o in 1 in z in z o o 00 ^0 vO in 1^ 1^ o u e vO » X o 1 o CO 00 N <\) o CVJ o 1 (^ • CVJ CVI CVJ w o (\j o o CO » in UI ro in a o !0 o til ID o 10 <0 a in in o UJ o in o o I •4 z eg in in <o o o o 10 * in o o < cf Q CD D -1 ff" Q in CD CO a o o o in -I o -J o in o -I o _l o o a o J o CD « < • < • • • N • 01 t Z • III • • < • • t LU • < * z • < • • • • OJ • • s • < • < t < • < • • • < • z • o < in Z o z o in N in o z o o in o CD •V z * N <Jv N K in o eg (^ z Z 0 <? > CO Z eg z z o (0 N 1- * ro < m in < o in t\J S) CO < CVJ in in t-4 CVJ (0 (VJ eg < eg Ol ro o Ov eg UJ (0 1 < u. u. • oo o m u. o a o (VJ u. • •H CD in u. U. UJ U. 10 o o a OQ cc < > z o o + in I in CD > > o z

in in -1 z J in

a z in z in in (0 (n z z < u z m a z 1- z z < z z o o I z X o X o z o IX »-( a o t- o te o < M < a u. o < X < < Z »4 o M o u. a a. UJ u. < < o N Q CM < (VI N o < < < < »- < < o N o O u -1 UJ a o -1 -1 u O O eg eg UJ a o UJ o o Q o z z • in z eg CVJ in z o -J -1 > z z > < z Z U

u. UJ

u

Q < O UJ

X o X

a

O < 01

OO UI UJ UI UJ z z < Z a z X z <0 z CVJ o X CVI o eg o z z < X • X + X z < < X • < < X X X z I z < z z < O X J X o o O Oil o o * • * (VJ < < '0 < K o t- o o J X u <J CM 1 CM 1 u in 1 CO 1 • u • Z u u Z o u u z z lU u o o X X -J o X -> u o -+ a cr •* UJ 1 • 1 UJ UJ Ol UJ UJ O UJ o a (X w tvj CM + <u u a (D IS in a: I in 1- ir a z IZ cc eg in r X fO • X X -1 -1 + o •• u o < X UJ o < < o in n < in < • < < o u < w < < < o o CVJ < < < < < < < t- < o z

u. 1- < o in o in 03 < 1- < o X I -1 o I -1 -1 1-

m *- o < 1- 10 o < "l o • < < < in < o < < u < < I • o u < o < z < < < < < < 01 < o < CD

Ui < Q V5

a

T o o o o O

O o -1 o 1 o o o I o o < 10 o X

X o o u o o o in o < o o 10

X

O UJ

O o n o o o o n o o in

a • o o o X o o 13 o <\l o 1 < in o o u 13 o a o < in T U tw u o 1 u o o <\j u o o u o u u o 1 in 1 o u o u tn cc u o VJ u 1 u * o u 1 u z o u

-I

J

J -1 -1 o:a IT ro

u eg <t o eg ro

n

_j

JJ

u

uu o U

u

a crm

mm 1 CM

O

M eg

O

O in eg o O

X

X

X

X

uu I z I X

XX o (D

X

X

X

XXXX in in in 10

X z z Z z z z

lf> o n c N in (0

N o K) lO ^^ (U in CO «4 o 10 <0 C^ eg in 0) t-*

<\J

W

n * in in in <0 <0

N CO 00 CO o o o o o (g
o o o o o o o o o o

4- + + * o O O O O o "in * CO n O o in o O • • • • • • • o N N N (VI n

<0 o

r4 o o o o

»« o I I o o o oo o o o o o o o o o

ill

N« o

o> o — o

*^ •

to I+o o o o e o> o in ^ N S + • + O NO o o o • o • < • <O o o o o •4 «4 O O o o O o o o o o O • o o N o * 10 o o o o o o o o o o z o w 10 o o o o 0> o (M o ffl o 10 o UJ o • • • • • • 9 • 9 • « • • • • • X • Ui «4

lU • V) 1 1 1 1 1 1 1 1 1 1 1 1 1 ^ 1 1 + + + + + + + + + + + + + + o O o o o o o O o o o o o o o

en o 10 o o o CM ID o o o 0> o o • o z <o 10 o o o ID N 01 o CO o o OJ z o o 9 • • • • • • • • • • • • • • • 0 • M 10 « N 10 N m 10 o N 10 N o 01 ID 10 <0 10 • < 1 1 I eg (0 10 o 1 1 r 1 a J 10 10 10 10 10 10 10 10 < < h- N N N o > 0> 0> 9> » ID tu

CO « o ID CD (S

N o o <t (0 <D o o in

N o ID I nj > n in • O • Ci •* (\) N • » in (J< » o o • * <0 o <0 ro

0.

N c o <* in CO CO 00 CO 0> ID

N

O • n o in in o -J O -1 o o O o O o o -1 o o O J in CO J (^ in N •

ex • N • N • • < • < • < • • • • • < • < • t • < • • < • < • N • • I •

1- o o> z oo z z oo (71 o CO z OO z o z eg o z Z n CO • IS z (0 <M <* CO 10 <M CVJ « o Ol CO in UJ 10

UJ u. u. u. u. u. u. U. • w a u > > > UI

(0 (0 v> in

w V) « in z z z z z z z z z 1- z o ir o o a o o o a a X UJ < < M M 1^ M M« < > a a a. UJ < < < < < < < < < o

111 UJ o o o o o o u z < > > z z z z z z z z z > < Q UJ UJ UI o UI UJ UJ UI UJ > O t- z z X z z N z z z U < < z z z z z z z z < m

1- o o UJ o o a o o H 9 z z z u <J <J 1- < ^J u Z UI o UI UJ UI UJ UI < UI UI UI UJ UJ UJ •

cr

a

a z a ir

O

K

a a. to

u. < < < < < < < < > < < < < < < 1- z t- < < 1-

lU < < < < < < 1 < < uX < < < u < w

M

Q o o o CM

a < in

Q o Q.

Q tf)

O V) o a in o < O o o o 1 o ro I u O o Q CM _J O o u o 10 o u w o

tu o U

O in

uuu •* r) I T

H

U

U o «t u. VJuu u. o u. o:

a

u I N z » o •

10 o (\t

U

y UI -1

J o a a X u (J <J (J I (/) (0 v> tn (0 w U) CO < < z z o * o fO « o (M 10 CO •14 •* N o 10 o CM 10 o <

(M ro to 10 * * 10 in 10 <0 <0 « K

N (D CD (0

O Ol

O

O

O o o O -4 o o o o o O 0 0 0*^0 u I o + in o • 0 z « UJ • I « • 1 ->

in

»^JJ o •-

COX oKo o — o o • • 10 O" o <g

.4 I

in

Q • z

in <

1010 ^

q:<

oiioinoio 00 o *

ininin<*in o id OOOOO-^O — CO'^N o>o>o>oiiointoinoino

C0*c0**(^c^l0lO0l0>

(00(ou)fU'^vo»»-*»<in

N

01•

Ol10

-i<zo

19<X

UJ 10 I u • eg < o I • a< O

0> <a

UJ - > to

CO

N

5; J. « ID

in

Mos

V)z < a. H ID Z >

UJ

IV5 O w _|

UJ <f <

_J - u

t-D t10

0>

-» 15

W

O •»O

VS

wO

U

w . o . w o < < o

>• >• -I -I z < < < K I- K U < < — < — O - Q O Q

eg o o o - o

iL o y u.

u

X - a o

egX0 <

inH

U) < w o 1 o a u <z o m om <

in »- ^ < • Q J O u u <z 0 o> eg m o> eg

(^ 01 o o o - - eg eg r» rcgN
UI

to UI

(0 UJ

Q i l. It Ui o w

(A o 1 UJ

(iJ o III UI < 1 o *

UJ Pv AT -J O >o (/) o

UJ UJ

a.

Q UJ III Ui f A < -X. X 2

UJ < ^ Q

ES

(/) UJ 1* >

CO t-K

w 2 Q tw1 UJ

u <

UI

K UJ

w

A

aJ 111

III UJ

a (/) (/) tx. o UJ

f*

K • J o a LL 1 -at UJ w

Ui (/)

W

J

Q

w >. UJ UJ (0 Pi (0 Ui

1-

J

J 14 > UJ < (/)

J

1- <^

UJ < </) o Ui z UJ IL 01 UI

UJ 1 O o (0 - 1- X ^J •1 u. LL Of t- o t/) uJ

a Ul

a UJ

a o to o

lit tf)a ^ q; 2 3 UJ UI

U)

a -J UJ \- 01 z <

"\ It

X

Q UJ * Z 1 UJ (Y 2 o UJ o o Q < to u. UJ z II

II Z z 1 IX en UJ *^ UJ (L Q

EM •J UJX Z 01UJ

HE ot U

(0 (0 UJ O u. X z z UJ 2 u. D 1 u < < X UJ (0 X t/) UJ o • 1 I- a u

III Ui

u < UJ (0 (/)

O V) o X v/ *M y z 1 1 

w

UJ I u. 2 Q 3 UJ ^

cc s o UJ

Q U) PI fY ^ Ui Q Q)

UJ o a.Q II 

UJ

Q »- u>

X z UJ

O 2 o UJ 1 to UJ < o LJ UJ 1 mj < UI 01 UJ fVLL.

ii UJ Q. UJ -1 ^ mw w cr O to 01 o

o» < o (J > U. «J q: Ui to

UJ a: UJ z Z o U) GL o Q. < C£ * UJ X u. O dm

*-»

a o X QD tl> 01 H- < z t CO o * z o o < UJ CO o UJ UJ o Z J a 1- X X z to UJ Ui O z (/) Z o to to

V) o UJ

_o U. o o UJ

IT" o UJ UJ III

111 < J

w)a I X UJ

iT z o X tj

0* z K III o X.

O 1" lU z

CVI

O o

-T- y- (D Ui

UJ

w o w 11II

w

Q 1* »- UJ Z lit LU to < AIX *^

uj liw < tO (A

_U 01 •J I z V* • UI u « -J IL z U) •J o ow o > u O o X

UJ I a. lU I.I UJ o o lift 3 o X zl _z X 111 o o to o O o < 01 * Z u UJ w (0 < (X, w Z > to z d.

III UJ o o UJ (0 *«•

M

w o

-p

H II to o s z UJ UJ to o UJ z Z o o (- to 01 o o

UJ

Q < a. < X 1 1 * 2 II < to

UJ t/l o UJ

U < (/) * • z _z 01 UI o UJ UJ • X < UJ X fY a. a. to K X

III UJ

UJ

A < X

X 3 UJ V)X

Q UJ

K Z O Ui 2 m I If) z o a UJ »i4 to z cr t- a UJ o • • • UJ o < z IT > X O o < II to UI s < X cr < < CM J to < D

UJ • aD

u

XD < o UiX -1

UJ (/)

a

M It Z z u <

UJ z X UJ o II o a o 1- o >- > o X 3 o I UJ X o to o UJ 01 to z W u z u < < CVJ u. z a UJ < u 0) O K • B O

ON 4) 41

4) tM > «

VI

B 1-1

O

O

X

CM 00

u

cn

10 CM «M 41 e

0) 4J 1 ONM

O

a o '0> CMa

b

a s CM

to

M - 4J

r-l 3 rH

•t ON XI

a

N CM o

«M - j<

<S SS CM * •o O 01 NO 41

O

J5 J3 CMK • H 4J n o

•O U.4 CM

— >N

B

M CO « «* m

iHCM

O6 u • • iH • 01

00 CM • 41

O < 4) 1 U B w 3 CM rH ca iH CM + « CM * > H w h

ON CM 4) • « I-l O 04 ^ X £ >w O -H • H —' «M •> NO •O

rH NO •o

*• I-l

B «

00 r-l eg o • B B * •rl ^ 60 O * 'Si W •>H •A NO /-V » • DO 4J <s r-l U (0 U iH Sm^ OD w <g d 1 ^ «l

41 CNJ CM o H 41 Id CM NO X a U i-l r-l H « A cd eo u o B * * • a

•rl CO •H cn rH /-s .fl Si 4) » o> CM O 3 » O O rH w 00 B iH «. B a T-4 m H «

t4 4J

O 00 o 00

IS <M o h 41 09 .a r-l O X B s 41 «<-< U O 0) SI 00

•H Ki ON 00

M

U 4) CO 41

O

CO 10 e CM 3 <M 3 4) •H 00 » c j: CO a 00

4) 4J 00

41 CO > 413 B 4> iH 4) rH o m U3 1 NO -B 01 •H 3 a r-l •* r-l CO v> >

«J CD tM r» rH O U 1 CO

B

B

19 4) Id o\ • 1 •a- 4) -rl 4) A > f-l <r\ r~. CO X U \D o 1 » a •

4) 00 •> 1 ro <N

4» rH 0) t-l VC CO •a rH <H A A f-4 V© 4) 3 .a

4J CO

u 1 ITl

B 00 «

4J 00 - o rH 4) 4J

U « CO (M

a

u

O

B

a vO 1 u •

<M 1-1

a vO 1 r~ JO «-H

X.a 1 On 0> NOO « 43

00u (M <r CM CNl 41 4J •o B rH

4)

B r-l o X e

JS •r^ 9 •rl

a -rl

B

O 3 T3 » < u

a

u "9

B 4) rHd 4)

u >. o CM

O > 4J

41 00 41 + o 00 00 J3 -H JB Si d tI H iH U H H 4 d rH

tlo

4>o
2 < O Z

•1 < O «A

t- UI

(U I- > « < U. O >

t- UI V) o

2^

UI I a oo 3

-iO

V)NN<<OJ<

a.X

UI

tr

u.

(AzoMu<

UIK

Uiz

tn o o z o s< • • u a in ^ o < a lu a s z Si

UJzuoza

UJz

t-z3M

(Xoz

u.oooJ<<u

(A

CDZ

(A

UJoz

UJ zo

»-<

UJ

cr oo

CM

<oN

a

N <o

J • a <

(VJ

m

UJ

II u.

(0 •»z

UJ

cr15^-

-Iz

>-

IDQ

UJ

I-u

UJ-I

UI

V)

(/) < - vO o < <0 N Z •< O a I CM J Q I < o> o

(\J « • o > o> in

UJ CO

-I I -

<£)

n - O K I <0 eg O ^ K

tn o HO* M O M

U. o o o o

U) o • n o o Z • -f o o o J • o o w +

<0 < -

II z Z - I q: s£

UJ

Q ^ X o> <

»-

N t- • UJ

K < ID I Z - Z 0. X O _l « < X «.z ^

UJzw • X — < oz< — a

(M UJ < > • UJ

Ifl -I

Ifl O

q:

u.

U)a

z->

ID^oooo

t-z o a K

UJ - Z J O I- < w N • O IS Z Z lO H <

IL

in o n

Ifl e z o z o o Ifl < • < • aK

V) V) z z o - o o e u • • 1 1 o o o • • o «mn -

•4

mz

Jl > Z (0<oa

o> -I « o

<Vi (0 I » - z • o z «

Iw3

u.

11 • z

(A UJo • 3 z z • U * <

UJ oo ozo

(VI o

CMo

(VI

-> z O I- • a Z UI K >o

II •

VJ

— UJ • a

(A

W

u • w (A • (A (A X < o

I- z z oV4u

UJ

(Io

01

II • — UJ • Q. (A (A U

«» lA • (A I <

I- Z Oot . o <

in• o o z

(A

in9

Ifl

M Z o

(VI Ia<>

II UJ

ir

«A 3

tl Z tA •» V3 UJ • z > z < « I 1 o a 3 o 0 < z < a V s s

UI 2 o

UJ (A < 3 > o QC < V) z r) • ? N

<0o • • • 1 1 o (0 . • • •

(VI

lO lO

00 9 • • 9 o • o (VI (M o o z v4 •4 0) n -1 <0 Ifl 9 z • < • • •

(M o 1 1 (VI «4 H 1 1 z (A o Z o o o o (VI • • V • • • < 1 z 1 ao o z Ifl o e • # • • •

Ifl o (VI

N so

ILO

UJ o Ifl

N • 1- • • • • o (0 n o N

r) < n

-I V4 «4 o

UIKu<s

»-

ID3

U)>a

UIz

UJ o <u z

10

II « « X

(A < O J • a X z

»- (V)

O

II UJ - u 0 UJ — _l • UJ 1 lA

II Z ^

«DOv

(U

103->O<o

(0>

UI•o

«>0*< X a K Z H ZO » a » U • UJ X J H UI o>

UI

(Vom<z<X3

*• «

«9

U

w UI + a • <fl XK Z

It •Z 3 d w a • IK

Q

X o (^ H U (VI
u

a 3 a ID 3 tc

u

M Ui

O < 3 Z u < 3 z z X UJ Z N < a Z

UJ UJ Z' s s s N a a z M o o o

V)

-i 3 3 J < UJ o z o o o u. u UJ < •4

U.

M «A z z z UJ CD < z z a < X

O UJ o o o o Z < a « « N • • N

N • % • 00 m o o

V)

O <A o o o o o

»- UJ • • • • 1 1 1 • •4 « o o

UJ

K - •4

N o in > « • • • • • ^ Ik CM Z9 • • CO o <D o o

(A o > CM CM CM •4 f4 K Ul • • • • • o (A O «4 *4

UJ

H-Z • ^ • eo « o o o O

H o n

n o O

O • O -t o V (S > o o o •o Z o z CM CM tO o O O >• M < •o N sJ o o o O M o o 00 o o o CM J

111 (A

U • z t Z • • • • < • < • • • • • • z X UJ 1 o O K a 1 p4 CM CM o a o N ft

1- 1 1 o z z W <A z o o z Z o • o o M o o o o o o e m o O M K • 1- • • • • • u • u • • • • • • 1-

UJ

B • < < o •4 •4 <

-1 -J 1 z 1 z 1 1 1 1 1 •4 1 z o O a a (X t z o o o

<J

w u. ILm u. < Z N CD z z CM o o o (M o tf> o z a J • • M • • • • • • • t • • • »4 s < o o o o O CM n CM in o 1 u a a u + o o » o a Ul U. CM < • o O O O o in • o a o < > (0 Ui < UJ 10 in in o n o 00 •* Ul o (0 o • K »- • • • • • • X • • • CM • • • • i£ H o o z ^ (A U) • V> w o UJ CM CM 1- 9> O (A u o s N « <0 in z n p4 o •4 < * S2 n » M

-1 (M 4- lO t- UJ 1 K •4 ^ 3 CM

J < O o in (A -> z • • < 0» «4 O o o o a V) M N II H 11 u II QC II II < II II (0 11 < o < z o Z Z Z z u in • z z z z c^ z z H a UJ O >• O CM o • 3 a z K lA ->

-1 « U -1 o O 9 J < • <

V) • V)

aO

Ml 3 t- Ul 1- o

Ul lA • z (A >• 3 «4 < -1 -> f4

N > •* z o + o N tti o Ul • o < S 1- 1- > • N M < « lA o UJ •4 « Ul in + • • ]^ z (0 (A N4 •4 > < e • UJ cr o (A •4 • UJ

III o o CM • (A z UJ • UJ CO

O CM < 10 o a 3 1- (A < 3 * M • O o + N (M + a. oo -1 • f4 . Q . ' • > 1- < • -1 > O o a (M lA > O < UJ o 1- < < lA CC + •

(J »- z V + O •4

X

w z J o z u. < > • X o • J < < + UJ -1 Ul -1 UJ M o < • w X o • H • X K «» u z N < • (A • o CM Z u <. in N o q: z a • »- H o N • in w • V) o »- O a Z z M in * z z z w K Z • •4 N -1 (M »- CM 1- •4 • a

UJ

O •• UJ • II 3 II • —

a

X

M Z w (/> UJ

O < o o a

1- o l*> < < N

O It z w < w a.

O UJ

N • • > o o < + < z z • • w * o o X z o o • o • o + < + < z o z o Z UJ >- < • • o • • o - u « u. • N Z o 1- z »- z m -1 (A < z z < z a X a • a K Z (T z t- z •* <o z « 3 J o »- Q. K >- o 1- 3 Z Ul UJ UJ z o u Z z Z I < «n o Ul 11 > II > + u. 1- a •» UJ M a a

»- UJ l-l

II > < < «^ o < n + X + «A II 11

K 11 h> e n UJ II < X X t- < z u u U.

IK Ul

X • w

w + a U. o —

aa

O o o O -1 -1 z O (X

O (A

O (A U) o a O < o CM o n o u Ul UJ < o UJ w U. + o + o + 0> z > > 15 o K o z o o O CO O «A 3 o a> a o • «4 H UJ UJ a • < Ul • (A • «A -1 z o o I I n I n J J Q 2 X X I UJ X J X < I < < H Z W » t- «i4 »- CM >- CM K 1- z t- UJ t- z K Z >

»- II <u •o N in « S o c^

O •4 CM 10

00 z •4 «4 v4 V4 «4 «4 «4 v4 CM CM CM CM CM
UJ

U

Ui ^ w UJ

V)

a » - X CD

til UJ s N

V

aa

M (D . (D

K

a - ut (/) D u 3 IL X O ui CM Al

V)

a 10 U) ro o

(- • t OW (AVI J K Ui

(A Af I •

UJ

H < IL z

(J f\a ^7 H UI - oIII X * ^ o * O H

O o * o o >• O Z O 2 CM ^ CM > ^ < •J O O P" -J

UJ </}

u Z • ^ • ^

UJ 1 o o o

CC CD

K o _z t/) (/)

_z o Z o w o O w o o o o * » 1 1 • u * ^ J T1 1 B V 11 00 o (£ *

r—1 O

u u» CM rl U. iL z o O CO o z o TP lL —> * * o o CM CM o 1 01 U w O w

tL (L IL

Q

O (^ "JQ

Q > UJ to O Ul UJ o o • H" • • • • o CD Z </) lO CO <A o CO *^ c^ (D »^

«4 CMw

J CM < 1 1 z • • o a (/) 11 u n 11 II M o < X X X

cr UJ

(L Z Ju

(0N^ - N

<M - \ - <

(L < • O Q **** • UJ u < 10 H w u O U CM CM ^

%0 UJ

O

O Z * (/) UJ • O UJ X X UJ

"y

jL J"

O

U o o (C z • II II z

tt UJ o

UJ o • z X tf) o * * O

u + UJ z Z QC 01 o • O X z CM CNJ 01

*^

M

X IL o O ou o u «• z X

2l

u o + *

UJ II UJ

u >•

II cc

w ^ • OJ w H * * W 19 * o Ok ^? w CM UJ 1 A O X O CC CL O • • M Z J

*•

TTO * un <u •

(A o ID

K (0 Ok

O Z «^ <M CM z

11 : 3 - t¥ w . ^ i - 5 - Z z Ot I V X X V

UJJ <

CD

O

XX

(0 <^ p# N - N o N •1 1

r*

MW CM

N • • • •

10 lAin (0 1

to

mv 10 III • * lf) 10 fO ^

I'l

n

J 1 O * * * * * O CM o CM U Ol 1 1 1 1 o _ Q Q

10 CD 10 * * * t z 11 g1 X

01 CC

Q LJQ li O o o O 2 o *

CM CM CM At CM CM

01o Q

w

Ik ll CM

<A

O

u

u

w

CM z UJ UJ

A

w

_ III * o l~ • * • 9 * *

(/) CD CJ* CM CM to r)

O 1 N *^ N N CO 0* o 1 CM CM CM CM CM CM QC - ull

II II „n W X X it

X

X\ J, w <D X

CMQ

K

X

W CO « O 00 Ul 1 Ak W u a CM CM X o UJ X N iO w u w X CO • z > • 0* o

CM UJ

_O

O CM

Ql CO

LC

_

X * 01 1*1 w w r~i w w w w u W Q Cj Q Q 1 •J z 1 1 o X X X 3 u ^ W • *!* ll X 1 • CM UJ CM CM "J CM Al 1 o 01 (0 X in II

II II 11 II * II ffi 0) o O W z UJ

tf)

W UJ (/)w 10W (0 o W

w

01 UJ III UJ UJ

w

m

CM tL CM o CM LJ CM

Q (\J CM ttl o O O O O o o LJ U

01 CC * -J •JJ

u • ^ X u. X O X X X z -i X A d K Z z < 1 < *^ u (0

UJ

U + + a. Z o * W III Ul

UJ • u < -J • -1 • UJ • UJ U to (0 tn < <0 01 CM u UJ u u o u J IJ ^ o 01 01 01 01

01 u. 01 o < X CL. w Q X X X z T III K (M H- Z O CM U) «

10 10 10 •0 ro
uu

V) z

UJ tu

OE

a < UJ tf) u. CD

UJ

(Aa • • • •

<A o w J UJa I •

UI> M < Ik Z • • o >

¥• UI o V> o

UiX • o o o J o M M < o

lii (A

u *

UJ 1 IX IDO • o K

lU • 1 CD w • z U < z N HI

CL * Z o o r• so o < > N o (/) o • o o w o s « < • * a V) II o <

1-

a UJ a X 3

J5<<o<uMz

UIXuossX

u.oo<

I-<.• u

<n

(Dz

I-z<K

IU)zo u

UJa

ID<

ILO<O

X.o

a.

u.oz — >• O CD

(M

O 0 • • U 1 J< 5 i w z •J

III UJ o < < < M Ui Z XJL 1 1 B z f A z V V \ V g

*^ o O z $

lii

W ^ < X < u. X IL z a ID n N N K N CM in CM m V r* tf) N tf) in o O w O CM • t • • • • •1 1 1 N O o - o CM

lA tf) o U) • • • • • •

01 CM

W Cr I* CM CM * * * * • * * O —o o O O O * W W O w V CM

IT) tf) o o o o o o o o o CO o tf) -J o o

4_ o o o o UI o * * * * * * 11 tf) w QW w 1 1 1 11 w

*—

— w

O

PI

_ o w

w o V * * * * *

CM 1 11 11 1 1 11 nw w O ii ll% IL P) (*) Q

Ww

mm ^ Z w o o w lA o

*^ *H *

ff) tf) CM (T tc. Of O o o

IL u. IL O o O («i «^ o * in (M tf) ttJ UJ UJ O U) tf) • • • • >- • • 1- • • • • • • • •

tn o o CM U) CM CD (0 tf) ni

M to tf) tf) U)

N o CO o CO tf)

M I*) «i« CM «i4 -J CM mm CM 1 • 1 1 oooNao

u.<u

N UJ O O • 3 X _lz w <

<M

J

O• O I z oo n <o X N

a.o

IL<

UJo3

-Iuz w — ~t<

01 o 0 H 1 «

II

-»

v>w > N UJ Om ^ X I* I- eo

CO0)No

ItU)3a< - o- O « • • X - H >

UJ

V • N O O « * N X •

IO o»NO

»-

Iin3<o

I19 -««

CM • O M X

Si o o a o

(03

-> « O 0 < + o O1 CO I- «

V9 >

UJ niO Q> • • X o e

in

N •• X <M - X X tt K N

CC •

IIO

U. • in o>

tf) < o 0 <^ «r d •H (MOW X J -

UJ

N o o + • • in -» X » • < CM

W) _l U

«- o • z 1 CM

(9

UI

-I<

CMI

UJz X o

I- UJz3 H M

V) «» <

!)> > o o

<M ^ I O

in om o• z 0 oa • u. - o u UJ •» K

CM (/) 1 3 • -) X o K < < N w 4^• X OI f >

CD < Q

in

T

4'

Q ~ < Xo in V • . O XK a

Itf)

II zo o <

(MX -o + in < tf) w cr * o f I • I- X 3

\~ < XH oa " *:z < u X I- o <Q

u.

-'

a < o w a « ui

<t' a. X tf) »- < wzo n M o

I-<

Al

10 < « w a. * o X X

»-3< w X n s<a X V o « »X z K O

QCU.

H

10a

J o

*•

X o t (M 3 X <> * ID < y • J « < o o * UJ • X a o

I- I
tu

O o J

V UJ 3 o O

V) z z V)

X

X

hi UJ s S s a a Ui IT X ID UJ < < < UJ < UJ U) < s 3 tL ID ID z X O UJ If) 1* <M CO

(/)

a NO « tf) in • • • u> o (D 1*) Vi N P) V

-iH Ui • • • • • •

(A

a 1 1 • CO 10 CM

UJK CO

V

N > « • • • • • • ^ lb zo • V* V •A

(/) 2 SiCM CM CM

K III * * • • * * D (A O

UJX o CO o O J o N <0 CM N M o CM CM

UJ (0 o • • • • • • V Ui 1(D 1 O * o ID o CD CD * * • • *

III * CM

ml 1 (D o M • z O o O

OO o < z N o O 10 lO o o

Q. • • • * * * • Z O o o 1 UJ u + KO • o z o CM o tf) < > 10

I/) o • UJ • • • * * •

CO z inX P) o s «4 K 1 1 < O H z • • Z </) o II iL H II H 11

u

*^ o < X u> o

(X UJ

y

M 3 ^ IL o O OZ H < < W N UI CD o + < O U. • < 1*) < < X

u. o • • • ID •

CM + K UJ t o O + CM z < X 1 1 X X * 1*) •# > • O + < o > O 1 • • + 1- to + 03 (D + t "f o < < N O > < 1 O • O O > to < < < < • < • < (D < <M > O a < Q + CD o o Q TO • CM _i UJ -1 + < + < + • + o

<-

X o If)

O

X • X 1- I X • X 10 X X O X o "1 o s o o o o o * o o o z < * o * *

Ul

a • (E o • • n • X

X £ a ^ X

X

X

K

X

X CE

u. <t */) (Z o 10 Z V) (/) z o Z (/) (A 11 Z s II M M II z II o II z H Z o

Ui o o o M X J 1- < < < -J < J I- w 1- < O < z z o < < 1 (D o < 1 o < o < CM 3 o O X 60 (M X CM <M X

*^

X >• o • X o o X eo

X

O 10

(K H- o u. • N CM • O U • t • o X + 1 r* 10

UJ UJ • 1 > z • » • • • < w U </> < < < V) < w tf) o <r J cc C£ a

UJ < o o O o o + Q U I + I + X X I + X o UJ • • 1- • • • H- * t- X X X 3 X X X 3 X 3 H < < < < < < <u •

(fl o N r> * lO S co m z U) lA 10 10 tf) 10 10 z > o 1 UJ UJ ^ z z V) UJ V S s X

Ul Ui UJ

X

a \ < ^ tf) LU ID UJ X (D ^

U) 10 CO CMN CD

<0 <0 ^• NO U) in

nO

c^ o CM 1

nO ID o O • • • 9 • 1 1

ID CD CM r) N 1*) • * • • * • . * z z o o

tAV

f) t*) * * * * wJ 1 o o III Ul tf)

tAV z O o O to 10 *^ *^ 10 o c^ ID o • • * * Ui * 1 1 o

Ul

O lib l*> % * * * * * CD

CM CM JJ 1 1

f-» u

— o W o O iL o O ID to

W (D * • * *

*^ * O O QW

UJ • X o W z K UJ III o _ CM o O or ID o N 10 CM lAv o tf) Q z ID • o z • • • • * tu z o

</) CD tn

_w

X ID Z 1 Z o o u X z Z u < . II H A

II IL

II „ o It

X h" < Id

XX b>r* IL

O

w (/)

w U)

10 z 10 lO

0* o 0> o • CC o o z < 1w1 z u.

ii o «< o X + (/) + + CO o X X X X CO CM CM o >- CM •^ o D * • X u

Ui CM

X OJ <^ CM o 1-

u < iL • 1 • < u.

IL + + o u. ^ 1 < Ul < (D • < UJ

CM in 1- < * < • < > < + Q nO < •» O (D o CM * X + a u

CM U) CM o CM CM • o -J CM 10 CM

O + CM + X + Q + X u a CM

CM CM \ CM CM o X

X ^ X

UJX

r-< X <

[I

X

Q

X < • in

X z o UJX < 2 < o o o o X J* CM 1- CM

•J o z O * 10 * II

_z 4b z o X

X o X

X

X o c o o X ^ ft

K z II h* IZ

a

IL o tf) u. <

or Z ^

II

II (A II IL II z II tf) < o o «J tf) o z »« CM s

IZ

O U) (/) o X o ID 1 M X X X

>- IL

O o Hi IL

O t- U.

W o O o X o < O • o CM 3 O

CM < CM CM CM < X < X X < X X o X + ^ < CD

(0 ID CM > CM ^

CM CD < CM CM • CM < CD < o * < + X «A + O CD • + •4 1 u X O

UJ * UJ • • > z * + z > Z < tf) < < w tf) tf) tf) tu u

q: -1 t cr (£

X

a « o

UJ < < o o O o z + Ul < I o U 1 + I + X X o a • »-

UJ UJ ha

X UJ

X 3 X (0 X (E X.

TM» tf)

a ^ <

H- < (D < < < 1- <

CM CM

OO CM 10 «

10 <0 «
Ui > u Ul > >

(A z z Ul Ul UJ Ul z z a a J Ul Ul < Ul M < UJ Ul

u. z (D z < <

Ui in CD

a o K « in in <o « •

*- • • CD V) O V) o CD

_J

K Ul • • •

(A

a » 1 g • N

Ul

K CO (D > • • • • • z z Z o o M 0 • • N M »-

«/) o > 3 3

t- Ul • 9 • J

J o V) a O o

111 (A (A tI e O O z z O J « <0 M

UJ tf>u • • • H- »- 2 Ul 1 1 1 O o

a. ID Z z o

UJ UJ • o o • • • • to • o

Ul S « wm 4 < <

-i -1 1 1 a o a

a

•>« • z < <

1- o o O > o > < z s in in in m in a 3 • • • • • z < wm • • • o 1 u Q > o >- u + UJ J -1 a a z z < • o o o o o

in

a Z in < < > J n N o z N z o v> o • • • • UJ » o • o o a z in in m N z n o in a. J < 1- < < o a z (A Z z » • z H IT z K o u u II H < lA O O M o < O o o z Z IL It K Ul O Z z 3 a z in

o> < o < < < < u. ir <

lA o o o * + z u. Z z z z < z • u in V M CM CO o UJ CO CM in m in IL (M + •f U. + * s • • • < Ul (A o a < 1 < 1 < 1 < < < o » u z < >• > < in t- + ID + (D + o o (M 3 < CM 10 o < O O O o IX z • z z z < z • o o -> o -> o UJ o < o o o z J z < 01 < CM < t- O • m z • z z • z • z • z z s z in

UJ

n 1-

n o < 1- z (Z IZ z u BC a a u. o o II k- II K II II < II a s (A tn « in u. a z z Z

Ul -1 o _J

J o u.

J (A z M z o w a o o o o t- a o

(\J CM CM CM 3 < (M z X z z < z < z < z < z 1- 3 o < 3

«^

M (VI (M CO > O CO < K o O O • • * • u. > Z < o o ID

Ul Ul

a. < < * < • < > z < • CO U. w Q o <- q: a a a U •

•+ o o o UJ < -1 CM z z z o u < 1 O z 1- z Z t- z Ul z (J H 3 »- 3 t- 3 (A ir UJ >- < < < < < IT (D K (M CM CM

<«U »

V) o N CO 0>

O o z <0 <0 N z - O 3 O M 1 w a < w S \ \ s o 3 - >. o a 3

Ul (0 < < o Ml < o O o o N 9 z z o o 5 e • in in fo «

0"

O

N CO (M n • • • • •

f41 1 1 1

<0 <0 o o n

(M 4' in • • • • • • Zo N N 3 •< J • • • • • O

(Az o o M o z in CM in o o CM o K * • • • • • • O a 1 1 1 1 z ^•

(A

UJ Z o -1 o o o o • CD t u • • • • • • < CM CM CM 11 1 1 a< o > N O o o o o o O o o o 10 • • • • • • • •

CM •> e o •4 o

-1z a o o o u. » 0> CM o z mm N CD o CM • o • u. • • • • • •

in

CM 1 «4 ( 1 1 1 < i*> 1 z s a

1]

a II IL IIu o II II

H Z

«A S o z •

in <A < a t- UJ o (A

U. Z • *- z o o N u Ul > n

N s

CO z • • » • 3 »- o • • •

CO

u <A < u 1 < O < O < o • UJ <A < 1 1 1 •

(M

J < > o < 1 o z > o z >• I > z >

UJ _l o (0 ID

CO > 1- o

(D z < + z + Q o o U)

CD o UJ -> z O (A o -» o z » u. < < < O < o < a M o -J < a < < < O ^ Z 0. < < a < o o + < o in + in in w o o M a. ro • u. • • u. • P) IL z in lA UJ + o o o

1- «4 z a u.

a z z z U.

Q

oe t- < t- (- c 1-

a

K s • • o z «A 1- K Z 1 H «A tA (- Z lA <A (A z • II o II Z II Z II Z < o • U z o o a M (A (A UJ H U

1-

tO z ' • o o \J 1 o UJ o 1- o 1- o . - z

(M < z • < QJ < < < < < < < < z 3 X 3 CM

U.a u. <A 1 O u. CM u. IL 1 Ui o N < z < u. • z z o z IL 3 • • z UJ • • • J

00

X 1 X <o <

CM

a • 1 4- 1 1 1 * >

UJ 1- » < • z o (A «A • •

(A »-

a < a < < v> < «A < «A < • +

(tO

u.

U o1 oz ao ao ao ao ;* so z z z t- z z + z + z z z t- < o * 3 »- t- K • H

t- 3 z < z 3 z 3 z 3 z 3 Z 3 < a I- < 1- < < t- < K < « N

(M V) « o 0> N N N N N
UJ 1 J 5 J o 5

(/) (A tt

X

111u s s s V a >• c o o 3 3 o o < UJ (/) o < o J UJ < < (D < < o o Q o O (A X CD o o g u z IM O o o IS N O o c>

(/)

a • o Ift Ift Z O

N • %

1- • • «4 o N CM

n

n

M

O (A CO (D

nN

J

H UJ • • • • • • • • 1 1 1 1 1 1 o> <0 CM o «

UJK eg 10 CM

n 10 > *^ • • # • • • • < IL z z z o o o a 0 # o

in

O > CM CM CM (M 3 3 CM CM CM

H- UJ

J • • • • • J

J • • • Q (A O Q' o o

Ul til v> V) I • o z CM o CM o z z o s N z Ift CM o o M o s o M < o O o in o o CM

111 If)

u • < »- • • • • • • hK • • • • X UJ f o 1 1 1 1 1 o o 1 t 1 S (D z z z Q lAZ UJ UJ Ul • o o o J N o O o o o J o J o o • • ID • • • • • • • (D 9 o • • • •

lU • < CM CM «4 < •-t < l*> J J 1 1 1 1 1 1 (D o tt tt • X < < < u > O o O o

in > > o e < z o o lA o in in o in in Ift a J t • • • • • 9 • • • • • • • z < • o o o o • CM • o o o o o 1 {J UJ > > > y < z z z < • o o > o o

V) rn

m o o o y < > _J in z o CO 0> < z z CO 4- CM Q o • < o • • • % • o • o • • • o o z o z CM o CO Ul o CM CM Q >^ p4 1 1 1 1 ID z !«. 1 1 1 m

|f) < 1 1 UJ < < 1 (A o z UJ tt tt o Ql to II 11 Q II II II H n II II Q 11 o n N R n M O < (A i It & V9 X (A IL £ IL X is V9

(£ UJ z z z 3 a, z • • M

(J (0

y (A

O (0 a( III (A tt tt Ul

tfS o Q

M o o o • M 1 1- 1 IL u.

N • M e o • o X < > n X 9 CM CM > • < • • • • < • < < o 1- o o < o w o

ni I I t 1 X i 1 1 I o 1 'f 1 y s 1 X # 1 • X I

CM > CM CM > • o y . >

)- (D (D > o IB ID ID

n > Q Q tt < q; Q Q ^ O o o 1 2 (A 1 (A • z < UJ z z < - ^ UJ 5 o o Q M o Q o < tt CM < CM CM < CM < < < < (9 < < < < < J

;3 QJ CM in CM Ift (VI CM in CM oc CM fV1^ tt It Ift tt IL o IL < ij • Q o n Q IL < M oc o • o CM IL CM # tt IL IL IL • X « z o X X o X UJ X IL IL o o o o I Ul Ul u. a l. h- Q IL X o I tt I < I X n ^- K tt tt < u u. (A (A Up ^ n o z z II (A II (A n z (0 X I Q lA (A u (0 X - o z o < z ^ H- II < II 2 z a lf) PI z *^ n II Q fO o • o z

Ul l>.

M UJ l_

M

N Z o UJ z 3E Q o < o < < o z

t- < < < < UJ < < < z < iL r) z < UJ < w < O CA IL 1 1 < It < tt s z CM IL II IL CO 1 IL IL X IL o t I CM X X (A X IL UJ 1^^ CO • X UJ X (A M <A CO 3 CA O 3 OJ o < a |. CM o CM UJ CM • n UJ o (0 n < (0 CA UJ CM z < z • 4 1 1 > 1 Z O II tt > 1 1 UJ o o a o < < < « a _ o ^ < (A < (A (0 y o UJ (A (0 V) <A

u. o UJ < (A (A q; < (A V9

Q CM (M CM tt < tt o U. • UJ o (K q; o a: tt I*) a: IL • tt tt o o

(9 • o z «J

O + O I + O o u z o CMO OJ CM z z

1^

Q |j_^

X ij^ 1^XX UJ Uj IL It It

X IL o J (A »- -J ^ m IT • 3 o V) X X X •rX J- k X o ^ X X X

X < z < < < < |_ < < < z t- IL < i~ <

AT

H

N

U •

(A o o CM

m in CO (J> o CM

n

Oz z CO o (0 e coO o o O c> 0> »
UJ o < < < a V V) o < 3

in z o UJ UJ

a UIa

lU

uN

V s s N,

a

a z ? UJ > < U) o UJ UI UJ UJ

u. z z V) z Q

O UJ NO r) <0 o

v>

a U) <o « •

»- • • N (M

N

(/)OM o O

O

-1H UJ • • • • • 1 f 1 1 I • <0 U) (M CO n

UJH o o n > -> • • • • • < IL n * < CM zws • • _ O

v>

a > o

h- UJ • • • • • O «/) o CM

Ui»-z o to P) o O -1 o z N 10 w < o o CM o

UJ U)

u • < • • • • • X UJ 1 a 1 1 (X o 1 o «AZ • o o • u • • • • •

Ui

m

-1 1 (0 o • z o w o o O o < z N, o o O U) CM a J • • • • • • X < o N CD o 1 us < • o n • m Ifl ^^ < > -J • (VI CO Ifl o o • • • o • • o o z a o o o N y o s, 00 oo o 10 O • o » 10 < Z w z • • o a (/) II • U. IL 11 11 < II M o < Z z z z Z z

(X 01

O

K > 3 a z a> CM

-1

n

wO

O •< z u o

«0 • 1 > n u

u o U. I «^

N (0 > • «J CM CM N o z u. u. • U. N ' ' 

< m • in • N a \ z z o z N (M Z z

1-

O CM • N • S "I D < O H *• + < CO O U • • < O < in Z o O > UJ u • • o in • o a in in •

-> o • u

u • in < tn • z z in IS a t- « • u UJ • M 1 z z z -1 > z CM Z UJ D »- < U. UI t- H 13 z O 1 H CM u «M Z II n Z n o O O < • + X o « • a • z in • 1 < •

UI o u (A in o > (0 • z »- u K u to + in * • u D • • 0. z z N -> < z • o • O z z • UJ z z

Ot < a <M UI CM o O + Z z < II H < o II »- UI u a w a. Q V)

u.U UJ

u

u < U o U. V) w o -1 • • D U. <

V9 z O « u. -1

Q U. u. o »- tf) z * o Z •

in < k- z z <M z z < UI B 1- 1- H n <u •

V) o tn

N CO o m z o> <^ z < z 2

UJ UI

a »-V

a Ui cr 10

M

a<

(/) ID V)

Q o m o z O « K • <o 10 10

Ot o#

Q>

n • #N o in U) N CM # • •

00 OD • o o • n

n o o o z lO (0 1 0 J n # • • 2 • < t z • • Q Q 1*) o 1 Q

ro1 z CO z o o z o o M o f-l o o 10 • • • • • • •

4{ < ^ 1 1 Z 1 1 X a (U O o Q

1^ u. IL o 2 o z 10 z o • • • • • • #

CM CM

fY

Q o Q • IL li. g o • Q Q o

in UJ ^0 • UJ to CM UI «^ m o CM «^ in CM

ro

ALL 00 (0 0 11 1 CM • T 1 X ^

11

n l» II II

H

J II

n

X (0 • in \j

XX

UJ

X

Ui OC • I CM UI o gt z V) CM M 2 z m 2 o o> • M 1 CM

CM o o . ^ |»c 10

ill < (0 111 10 1 1 UI o * |» QJ 10 Q > Q tf) CM

CM 2 <

GO

(0

N CO 0>

X

g

Q

CM 10 (L

Q o O < ( 

w O a.

•J CM CM z o > o Q O < X |_ • X < • O f» > z X z 10 UI

h- C9 z (A

CO

O o II UI

Q

H

*^ o < CD to

II

n o z z

UI (0 z I u )- 2 IL

y •

(J c> z Q

OJ CM < CM z o O 1— UJ IL Q IL

M

ro UI < CO CO » IL X > I X

1^ o tD z ^ #

CM CM * • y CM z 1 10 Q UJ 1 O n UJ ID II <

(/)

Q in

Q

u cr

U 3 O UI

q: o o a u.

U

a to < < Q X <• o UJ UJ I »- z u. z z a u. U.

»- >- ta » o X I < z 3 X in o X it < •< n < z t- f> K CM o CM n lA <0 o o O o O o O V4 V4 V4 «4 •4
lUu

V) z

lU UJ a a < UJ o 3 IL z O Ul N

(0

a o • • •

V)

O (A

J 1- UJ

10 at 1 •

Ul

K >< U. o >

I- Ul

v> o O J

•-• <

in

u

UJ I a (Do

ID ID Z Z OD N N Z O O N N h- O 3ZS S

V) o < < M J

w

O o o ID Z o o z Z M N • • « ZoM

»-3JO

in zoo

(Aoz ooo ooo zo

»-3JO

10 eoo ooo Z

Ul Ul Ul o o • o J O J o o o o O O O o o o • ID • ID • • • ID • • • t • • 1- 9

Ul • •« < < 0» fi4 < < 0* J 1 M 1 1 1 1 1 1 1 1 1 Z 1 z 1 o o K a a OJ z < < Q o > > o > e o u. o u. o V o If) m in 2 o Z o a 3 J • • t t • • • • • • M • M 9 z < 10 • 01 01 01 o 01 01 o 0* o 1 N > ({ J J Q a a z z iL < • o o o o

OJ «4 0>

N > P4 0 2 10 UJ UJ

(A o • O • o • o • • • 9 o (0 z O 1^ lA M Q Q ID lA i lA w n 1f 11 If) 10 1*) <0 < U) < n < 1 J < z z z • « Of (t oc o Q. tA 2 II o H II H n o n n n II II H n O < I C I ii_ I X I II i & in & O

OL UJ Z 2

(L Z M

J <A o Ul

u>

Q

Q o g 1^ |w 01

in • 9 9 o 9 01 01

01 01 (9 e 1 + s U. • (A < n o > 1- I It (D o J 2

eg < < o •4 0m < I K o X (A 9 n 9

«A in 1 o TO 0* < + Z « Z U. u U. u. O - o o OJ 3 n • R + • < X O o o Z ID tr 1- K < < a < U. < + H K

u. U. 3 o o a 0* • (A 9 (A •

U. « • I 3 z 11 Z z 01 < U. U. u. U. o t- < II O o o o o

Ul u.

u • a (A cc OJ 01

M <M z

01 < I - i a 3 X

X < X

u •f »- 1 »- 11

O + (0 in + »- in \r in o o (A V9 z • « < 9 + < • z o R < z O X o 01 X OJ X 01 s n n 11 o -1 •t t- J •t 01 1- < < ro z o (9 •* o o z a. cr u a

1- 01 < z < 01 < II < o II o -1 ^ o

u. u. u. < X U. u.

V u. z Z • • • U. 1 7 z UJ o 0m o o 3 o Z z • m X U. U) o in o u 3 o in o u 01 N O M M X • 3 01 • a -» o 9 o X • O c »- X _J • X 01 u. o < o o ID o 10 O o • < in 01 > N OJ to s 01 in M N z < H a II • H It > 1 + o UJ X UJ X 9 lU

t- Ul

a U) 01 o UJ in * in 01 • • a UJ — o UJ < <A < <A Ul *m • (A o 9 «A o 9 lA o

U. V9

O V9 Ul o • * tu < 01 cr ot (X l>- 01 + a

N o a u. < Z »t in *• O in t« o « o o o P) o m o • z < M < X X < -» X o u. u. o u. U. X u. X I « u. »- U. UJ u. H UJ u. • K Ul o • e < * a • H- t- • (A 3 UJ -1 3 UJ O 3 Ul z o 1 1- u < z I 3 I 3 lA I UJ X < in X < (A X < < (A < K U. 1- < u 1- U, H < t- < UJ K H o 1- o

01

R 01 OJ U. < X z Z

(A •o (0 o o •4 01

n

n <0 • CO Z o o o v4 0* *4 0* 0* z «4 «4 •< v4 •4 •4 0* »4 0* ozo
Ui 'J' (X o o o o y Q Q o I* J

vt Z - S z < X V) (A < (0 <

tuV

V N, N. s s

a.

a o a < CD < > o o m o < lU o < < I UJ § < < UJ < lU < < (A

u. o Q o o N o N

B

N s > O

O lU 0*

O o 0) o o CM t-i <M Vi4 z

to (X « <0 in <o to 10 10 10 o • O V)

u)

a

UJ »- > •-« < It. O J

»- <

V)

u

tr IDo

UJ

B o

Iy < z a 3 zO I < > O (D U O § a M O K C 3 a

.JowN<o

-1<Mz

UJzuoz

'Zz3

»-* I s<uao

_1ozs

-i< • o

(0 ^ <

UIz

u.oo<<w

IDz oIe o

in in <0 « o N

O • • •

fi4 • • • • «4 o > N N M K UJ • • • • • • • — oz

(\J z

UJ

tUJ

IDO

UJz3

U)

«n<

v>zoa o o N

u. zw

-)

a o a < u. N o N O • o o s

UJ + J

(O o I N o in - o - U Oi

«- z o

eg 10 o z • *» in (M 9>X UJ

in u) - >• o

u.• O

J o z < o z K « W <

u.z ooo

oo • M

—

10

x

u

N I w oo «

11 •* z < Noz O Iin

u. • z o w Z N UJ

U. (X o z t- o oz a < <Q V) o

<o u.o

u.o •

»- « w

I- UJ z

Ui z 3

(/) UJ < Ul UJ tr z o< o o in

N o o o o in O o *4 (g o o eg o O o o •1 •1 • • • •1 • • •1 •1 o (M o 6 CO o o o • • • • • • • • • • 1

eg 1

10 o o e o o o o o N o o in o in o o • • • • • • • • • • m O eg o eg eg • e * o o M o « o M o <g in < eg • • • • • • • • • • M o o O o O 1 7 1 1 1 1 V>

3^o

<g

I? - * I Ul» 0> z o

eg z O UJ • z Z UJ »- a3

V)

H <

UJz u

eg

B

u. < o -I z o

»- z

eg eg z

.1 2 o <O

»-Ja

»-K

in - a < o - z + 3 • <

-Iu o z

»- cra

IIKa

-» Ul w K I Z • Ul

-I o u d

Ula + o <w z

<» V9 + >- • (A Z W)< o

«l

nI

>• <w O n •

-> - o J < •z

ha

t-v>

H ZO <I < J in V -•o + I < U) w a « o + z • I- Z 3 K < oI >o < • — -» n o + <

-I in

<j • - o z

I- cr

(0

II za I < K

»-

(AZo < wa

•* oz • t- Z 3 K < n •

eg

II < ~ in < h-J I 3 • «n

-I UJ u a

u. + o• < z « -Ia . a z K

eg

eg ~ I <w >

eg CD

eg o J -) u o • < z

I- *a

II Iin - z < o

HI I - H J < u

in eg ru

10

— o < •

eg+ >

rtj CD L O U • . -> z o K <

eg

II ce — I- < in w z I

-I < + N + - < - < in «- a * o

•• z - t- Z 3

»- < m • • in • a J o V z • H Z 3 H <

eg < —

eg >

eg CO J Q o - • -> z o

t- < < en w z I o m M J+ O • t < »• m - + tn . q: J o o z

t- Z 3 I o•NI

>•ID

«» o < < + eg u• a z K H «nzo

II

M < < •u oI + •o — eg < • w o

eg+ •

eM Ui m a Jo z • t- Z 3

I- <

eg • ^ >.

in

J • z

in ozo 0 « • K

»i < 1 zao 0 z

U) • ao

>- U. Ja o a Ul • < K

co tn

to

H

H

eg o -J 1 z

II v> Z UJoou

UJgu

y >•

"« * oc dg• z Z M

t- •

in » •a - o - z

in t- u 3 V <

eg* • u z

eg IDz

4-

OU • H

in

u

U Ul

cr z o O Z o• <c

1-

inz o o • y I uz«JuaN < a Z K H «0

Ul
III 11W

(/) UJ Ui

(£ cr

III (0

tL (D

w III lAJ

(/) • •

V)

U VI 1 H UJ

inVI fvu 1 •

UJ

H ^ ulb z

jiw

(A

u ^ K UJ

Q (0 o

UJ o

UJ (0 o * X UJ 1 S COo• •

UJ •o M • X < z a 3 zO I o + z • o a M O H a 3 a

-IoMN

5:NSO<uMz

UIzuoza

UJX <uao

-Ioz

-i<o <

UJz a Ku z <

h- UJa

U.o

(9o

-J<

I-<u • a z z u< Z H O U) a z - D Z ° n s w UI

in z»^ IL

P)

O

O

(M

N

01

M

w ^ ON •Z • o

UI

w >• o o

«^•) o

UI • M

tf> IL O M

UJ o K O

U. Z 0 _i a w < o • « a z . o s

-i UJ < n

vj I a • • < ^ H 1 a n J H I- N 3

UJ z oo z 0 « • < 1 aK

(0z o o • u w < J o Z X

II) z<o

CVJ < o • X

-I

X • D X < K

B

UJ i o o I n o UI UI z < s Z M o

»M UJ z 3 UJ

M u. u. UJ

U. >- tf> >• CO UI UJ IM

0* P) z o o « « •o • • • U) o o o • O o o o > o « -1 • • • z •

in o

•4

NO o o o o • • • 1- • «4 < t 1 1

FORM o o o z o • • • • ca in CM

in

<o •

(/) z

II o X «

I-oz3

u.

_l<z

(XUJXo<« — o

>» I • « • N

_» 0> u• I- X <n H o>

in

cro

u.o

(0 UI • (-

r> (A m • « z

It o X «3

u.

-I<za

UJX

^•o X < N M O 0 -« w I • n • in J o> • t- 1 <

CM

n

M

in

u •

(/) a • o

-J I U K • 3 X < H

O< ~ in O CO w I « P) • N

-J <0 u• K X <

11m

u - — w

•*

a • o J X u- 3 X < EO

U.o

UJ • 1- (M V>

\0 • J

in

II z

u) ouz3

U.z

ceUIX

in

u • w (0 « ce • o

-I

X

U

K • 3 X < «

in o t o • o O

K o o > o o z o z o

in -1 -J o « o • z • z • • < • o o 1 K 1 «4 K z z U) M o o z Z O o o o o o o o t 1- • 1- • 1 u • u •

r* < < «4 •4 1 z 1 z 1 1 1 a d o o

U. u. o z o z o • • • • '• •

(VJ V4 o e

cro

u.a

<0 UJ • 1-

in (0

in •

-I

toz

II o w >-> 3

U.<za

UJX

t-

>•oo<

in '* o 0 -

•*

n • in J 9 y• H 1 < H

II in w - — V) < a • o J X o• 3 X < Ia

t-MZO

M

M

O•

u.o - «ga <

«n (M O o z •

u.o z I K > H J « U Zo « •-•

4' • — > <- zo • M • K

_

X < K H -) X O UI a H <

irH

y

X

w UJ • a J < U UJ • z X •-

cr •«

1- o w • z ^ U _l M UX •> — — zJ

N • o • Z V) (\J H «» ^0 -I I I a ( a

u. «A O UI> a UJ (A < 3

UI _| _| z < u « > X M O _l > • <

cc -»J 3 £3 O U < Z

CM

4' <Umz

»-

niom a. z »-o H «a < o

<» tt. I- H d UIze

(03 - Q < <• ZH I
UJ o o < CD V) (A u o a X O UJ UJ

V) z cr (D ha

X s

Ui UJ s s s s s

a. a. V)

M «A

aa < Ill < UI X UJ > >

u. z s IL tf> UJ UJ

Ou P) o o

U) a. S « in 10 oa

ISso

U.N <Xu

\- • •

1/1 lA o J Ut

(A Of 1 1 •

UJ> • • < It

jr o J 3 • • o >

ui

J • o o a

UJ </) • z o < o

UI (/>

u •

UJ I o 1 cr OD z O

UI • o o

t- o •

UI • < o

-1

J

Q o a M • z <> o zoM3NN

niN<<O<

UJXooza

UlX.q > _i

U)

Q

O Z o s

-I< • • u a (A ^ a < a UJ a z •o »-z

UJoz

ro UJ

o>

a • UJ

<t o m z I o N in N in •1 • • • • N

1*1 (M P) • • •e • • • •N e in * o n • • • • • r O• n « o o o in O

in • • • • • O o O o o

in o o o «4 t • • • • < ID 1 1 1 1 1

IIu It I z I Z KUz 3 < 3 <

U. •t

O

(M • N Z z Z w <0 o -1 • • • in oo » -J

-J < •

-1

UJ o z o < z »- z o < « < o

-J • u u. o u • z z z J o z

UJo

II 11 • J II UJ u o z

VJ z U

UJz • * z *

-1 (J -1

u

u z z • J • z z UJ z

1- o 1-

inN

«4 v4 • -I 3 < < <J

.. ^ O

(M

m z • « o

»^ ^• «

oo U. + " m in J N

<J < Z Z • J • <

-1J o o • z z in H OO•

II

ao u u. * Q m » J a u a • o z u 3<owz • «• z

CO UJ + > • J J o U V) z• u • z

-I I U O • < z

I- z

v>uaz3<zM

(A3 • <

l»)

J • u o z -

u.M

V)N<z< • O V) z z

in • O (T O (K • o

cro >• ^ u. »- • «

(A

Q

a

15 • 3 w a a N q: z X o « N Qz

+,Q <

•«

U Z • _J • 3 < a < (J <

UJ > o q: UI o

in

m

J q: Z UJo — 00 + •

(A - O t- . w <

(A (M U Z • w (D - <M O Z (X H Q. N

in 3O

(AOZ

UI

-Jo<a<>>Jzozo

1-<zao

u.zao

u.

(M o•1 •1 »

Cll # • • •o o o o o l») o •1 •1 • o in o • • • o 1 o o o • • • o O o oNzNO• «. in • + 3 J < U

•• Z O

(VJ • • • z

_l I- U UI • Q zH ZO

II I-z — lU V zz « o • u U UJ - UJ z w

Nm • o N a

in so

(\j zNo ~ in - + 3 _J < <J

•• Z O «-

<\J z o < >- • z«

in+ * • -I J y o z Z K • • • z J K U UJ • O z

I- zo H HZ — UJ u z V za ooo ooo

t- o z •

Ul • o N z z

AJ UJ 1 a

UJ -1u

II z z Z 1-

(X

CM o z d u. z • <

>•

in

K < + h« o

-1< u -J < z O -J z * z z M L o (A u

UJ z O UJ

»- z lA 3

u.

u • •z •3 -1 o < z o -1

(VJ

u o z z t

(VI o o • • o

in < 1- + z J -1 uz <• z

-1uz • J z y uz z 3 z < < O

in

in

«4

(VI X

in+ o

(M

J z z • ^ 10 U (A> z

I- (Vl o

II in - u 3 I <

.. < O J

(M

U z z

<0

H

-1 I- ^ 5 w ZXo

-I (J u -» . > Ul Z 3 UJ K < *A

10O

J

(VI

V z o

(VI

N

•• Z «> z J « u• z z o3

11J

-8

u. o o

(VI Z (A

UJ

(VJ

M

Q.J< - z y I- - z « UJ d§> (T Z U.
Ui

UIa

lU

u.UJa

(AS

>•<o iX<

<0

NJDXS<z oa

(99

ILn

K • •

«AO (A

-IH lU

V)

a Iz

ino

UIzM

UJs o > K UI O J<

UJ I a oo n

n • n 9m N M 10 o O > « • • • • •

«4

NN ft

Ooo ooo ooo e

U) o •

10 > N _l • z - ozo

>-

-Izozo n (M o O 1-

N

m in o z • N o o fm O • • • • < • 1 1 M a 1 W o W w — o M Q) w g * * * • »- * * w

UJ * • in 1 I 1• 1 1 1f I 1f (D K a * z W o O tL w in < IP 1 O o o — ni

&. 3 •J • • • • • * • M * * • Z o o o o CM CM CM CM CM CM

O o 1 O UI s u z o o K *^ IL U. * U _J O o O o m < > J o 01 z • UJ UJ tf) <D o u) o • • • • • M - • • • • 1- • t • • z • (/) o flQ Z o CM CM 3 o to in (A in (^ D o u O N ro 1 fO a • in >-> in O a 1 Z 1 1 1 1 A :j 1 -1 1 #4 IL o < X w a II z • • u o 1- u a t < o Q. (n n n 11 II a. }l z n 1 SL II 11 i iL »^ o < z z X X Q (/) UJ (A z z w It z z <

(X UI ' z • IIu o 3 OL Z z o • (L u. A 1 Z o U _Z o (D o in t- -J CM J ri (0 u UJ V) UI UJ + o u UJ o + o CM Z VJ >- ' N <

*^

m > o o & o • u • • w a

N o U. • o w CM

M

n •

\J • • • 1 UJ o UJ 111

w o — O

d iS o o •J o < o UJ < o o o CM • * u Z (/) < OD o ffi CM X ^ X

fiIj

X o X KJ 1*) CM o < • a

»- CVJ

N (U 00

WQ OJ o X o V o X

O • • M < I X «• X ro o m t- o -1 o t- UI o o -> z X u V o u -> y II X z Z * Z Q I 1^ K u. » • o o K J -1 M -1 < K 3 o X X X < II X < 00 H < u u u O 1 1 1- K in o u. u • z z Z >• z • CM o z o X o X o X • H X 3 o o o « » z »- M »- »- o o tf) + o (M o J i z

Ui

H

a o X o 3 • o z 3 3 3 a Q UI o «i« Z M

II -1 II II -1 II 1- ^ > o uu »- 1 in 1 in ift o o O U (A O X < < (/> m «^ 0> o UJ t* < z m (0 U) Z N 1 -1 o «>J -J CM «4 CM K o z a J < o X 1- O N in o CO O CO <

UI u. u. u.

M » CO • O • 1- o z o o o o o o 1 I X z X • I • X CM X V) lA o z

•-

N (\j (M I*) t- »- K- UI »- « f- 1- < < X »- < a

V CM o z V) X v> X «0 o < to N z UJ a z X z z UJ UJ UJ • < n a z 3 o M CO -1 z H It II • » H (0 CM H U. 3 • z a a a w < o O • • O o

(T »- -1 • <n

N UJ UI o • a in

a

Ou < < < o o u

O

U <0 o U * o u. z < z I X 1 z 1- «^ «^ <M w < *

1- UJ (J

U

K * o OJ <^ (M z OJ < a: • u

J o a Z Z Z O V * X * u. U. «n o • o u Ui

u. < UI UJ < UJ < «n • »- UJ

J UJ -i CE in -1

a tr UJ o X z o NT a -1 < V) ce (X U o in u a o X z «• -1 z Ij z -1 z o u o U. X -1 o X < < a: o < o u o u o X < o < < H u h- I a. 01 o a IT (T • »- » o UJ X X 1- X X 3 Ii X 3 K K m • • a

-1 z u.

X U.

X U.

X 3 X

X t- tn < < 1- < X 1- < UJ

X

a o < 1- < »- J o o t- • 1- •- o u N 01 cg < (M II X <u Z z

(A •o O

O

N V)

N o Ok e o z m <0 « « « <0 « z P4 «4 *4 «4 «4 •i4
Ui o o o O

*J

a tt

B

u

V) z o ID CD (9 «A (A

til UJ s V \ s S a a o v> < < < < > > < UJ 3 p 3 M (A z z z X < < tn o u. U. u. IL IL CD yj u u u z o CD a UJ n n 9 Z «^ u S o z

v>a

NN

W • 0m lO 10 • •

1- • • W O (A c J H UJ • •

V)

a 1 1 e !•» UJ H o > M • • • < U. z z

.1 oM o • • n K, ID

«/>

Q > N 3 10

h- UI .•

J • o tn Q O

Ui

H- (A Z • ^ • • O K o h- O e O o z e o CM

15O

J > o z o Z e o O o o o iO

»M

M < tf) -J o -1 o •- o o o O o o o CM

UJ (A

U • z • • z • < • < • • • • • • • s UI 1 1 o 1 o cc (E 1 1 o 1 1 a (0 t- z o z z (A lA o o z Z Ui 9 O o o o o o o o o o e o o o

1- 9 • • • u • • • • • • o • • •

111

X • < o < «1 0m 0m

-J 1 z N 1 Z 1 1 1 1 t t 1 M f 1 03 o d CE « • z O o < V o u. o tf) Ik > o o < z CM z CM z o O U) If) 10 e o a • • t • t • • • * • • • • z < o UI o o UJ (M CM o o o o • 0m 0m CM • o 1 u a a a tc

Ul o m

p • • • CE

K z u. V) z u. z O < • O 9 9 u u u o z O o Ul o o -1 Ot UJ o «4 tf) < > J V) UJ < (A UJ n * CM o CM z O N < o o • J H • lA • -J I- • • • • a: • a • cc • • • • a o CD z If) uj in o N Ul lA U) o o o wm (D ID CM IE CM CM CM V u O s 10 Z <0 M in N * z Z f z ID 1- 1 1 -< n J 1 < J 1 o 1 4' J r 1 1- 1 1- T t- 1 Z < < -1 m z z • • y < 9

tr IX q: * (E o a (/)

.. I

11 z 11 11 Z II • n •I

H P il o II o II » + II II II o M o < z 1- z < z z lA z z u. z u. z u. Z CM u. O V) a a UJ o o a II z u. 3 a z < Ui < < < ID M J o a * z lA a K 1- o O ID _J ID U < < < z K

10 • z o • z Ul o o O s O

(A

J o U. • !•)

N <J Ui lA «A (A U. z z 1- U. Z I- v> » • » o »-

O S u O U U • + « U) • N UJ UJ • u z CM • < • N • a • K • a *• 13 -1 o o

-1 < -i

M

O Z o z o z CM o z < 1 CM 1 N a Ul Q o o <M 11 CM •1 (A • • z * O tA Z (A z CA + H n > CM > • z UJ z Z UJ 2 CM 3 O 3 CM 3 u. CM + CO

1- > 1-

a > a z 0m o am

»-

M

M

N • • • • • ID o o o • < O V9 UJ o 1.9 " O « O O (A o • « • Q II N II z U CM « CM • nj • CM CM Ul Z • -> CE O CM Z O z O - Z (Z Z Z • CE o ID -» <0 1- « s ID (D CC a CM ID < < < o o U. o • CM CD Z • z • z ID J • U (M • • CM o CM • «i • z •-• z < X • 10 Z tf) M z «) H z z o Z 1- • z _l Z • • • X VJ z U UJ »- z Z z z H UJ o o

lU • < o • • < 1 • M o o o 1- Z a X • J UJ • J UJ u. II •-'

II UJa II IE

u oo

u

a <J

a < •1 II

H Ul II

H tN o Z «t < •• X u 3 ^ 3 3 II lA -1 (A (A z a s o z o t a, < < UJ J -1 J -1 -J CD z < Z K O UJ o UJ • »- • a .1 O X 9 o a < < o o

Ui " z • ID • z ce lA U)

w (A o «I o (A

J o »1 1 « • z - J H -1 o Z • t- m y ID O (M CM w z a 1 l») v> 1- u a o u (M a u o • a • Z CM U. I U. Z U. o n O K o z o z z z z ID z z u z o z o O CM 3 o < • < Ul z z z < z < »- — o CM z < • IE a o <r z < »- - > 0* > < a O ID tf) U. z • o z o < a a a Z z (D 0m CM

ce

K + + ffl

a + u o>

n oc. * -I * -1 »^ 3 9 N • » a U + 11 u. M t < < < •4 z < * s z «> z — z z O It O •f 1 <f 1 -» <

UJ

u o u » UJw »-

U 1-

U

u CM U. 1- U> CE

q: - Q Ul • o • o w Z — z z Z M • ^ » w

O

U. Z> UlX z UJ

J IT z « UJ « Ul UJ o o <A < (A < CA < Ul o < z • t < z a o o a (E w (£ M I o Q w z Z o z < Q ^ O

ID

O ID e CO

b o ID

a z ID

m ID

ma ID 1 o Ul z * z Z (E o • (M Z • • 10 • CM z * o • a • a • a. • a -1 • • H

•J Z Z O z o z Z o z z Z z z u. z u. z U. z • u. z 3 Z 3 Ui

<o

u 1- ID

u

a < K <

1- z • N o H <u • Z •o •4 N w « 10 « o O CM fO

(0 z N

N

N

N

N s OO « O CO z «4 »4 *4 w* «>4 #4 »4 «4 0m
u

a o o o u < a a Of z o ID ID ID Ui s N. s s a a z < ai < (A 3 3 3 3 u. CD U. u. u. O UJ o Z n ro p>

(A

a « • i«-

N •

I- • • 9

tf)

O (0

_i h- Ul • • •

(A

a 1 « o eo

a

UJ

H

N > M • • • < u. zJo • • « o e « o > in rn

1- U) • • • o (A Q

lUz • »» o in o> •

V9

O

J o o to in > in 1 < o in J <g

(A

U • » • • z • > UJ 1 1 1 1 o a (0o zo • o eg o o • • • • • • (M e <

-i 1 1 z

(D o a • z o H o o % O < z N o z n

a. 3 J • • • • s < l») O o o o 1 V UJ a u a o

tt in Ul u.

m < • o »- z ^ »- Q 9 O -1 < > -1 CO < U UJ < o <A o • • • lA • •A K • lA o (D z CO » « J (A o O N, < <0 Z N Ul •- CM Z J 1 1 o 1 -1 1 o < z • • u < J < o a (A II n « II u 11 M o < z w z < z z z < H a UJ O •- O 3 Q. z 1 Z • z O J .J w o in z o

(A + K lA

N 4- •

U. U. \ O U O U z Ul u N a t- \ < < • UJ * o • UJ z z • u Ul u < • a • > • a z z •m z ¥m < UJ »- o K UJ O z z o 1- H n II < U. o u. u o <VI • M O o Z H o z N z eg « u CM z

Ul Z o z • < Z o z w •* « UJ u • »- • in a 1- o < • < z • in z in • tr z a 1-4 J UJ Ul u o o o w z o ID X o z Z 1- z K o • o • .. o • o

oo

J o z «^

u S z • 1 u o u «» < u o 3 o z o Z eg z z X eg z M o z o z z z o

oe * cr « a o u • u. u. z < u • + B * •

Ui in o + CO o a < UJ o + UJ

u.

u • z <« UJ • z o w w - z -1

4- o • u < * 3 « u <

(9 z z »- »^ < ID

X

O • t- • o m •• z • ffi J X Z z o o Z o o z Q O < »- N U

II mm z < z z U •

«n o « in « N

O o z CO CO 10 CO e z v4 •4 o a

tt

a < 3 < < - o 3 o o o s H S N

V9 s z < Z z 3 < < < < «A

lb 1 1 , W 1 (A t 1 go

ro IAO in o o z

in « <o <0 « •

<o

e^ o> o o • • • 1 1 N P) m • • • • zo

1- • • • o

(A

9> • z in in • o O > 10 in to > o n -J eg o o » z • • • • z • 1 o o 1 o z 1 mm z z o Ul o o ¥m o -J N o O o • • ID • • • • • < < eg < mm 1 z 1 1 z 1 s a o < o o u. > !k z o eg o O z • • • • • • • • rm mm • •

UJa > eg eg

a

a o _i

g o

UJ u. z Z X u. X o « B O o

UJ UJ z CO mm o O + Ul • (A H • o • • • • 1- •

in aJ iA ul

O eg IA

<o Ul

M i>- in eg in « •1 1 < r mm mm -1 Z t- u y 11 ceo u II II II II H

N z z u. z z (A (0 z eg eg 1 M O O

mm *^ mm • M K • o K

GO

X

O

1- U. (A eg • Z

_l 1-

Q + • • o u M l-t mm mm

M

X UJ 1-

K z X

a

u

u

1-4 z • o 3 • • + U. • • (A (A Ul IA a oe > _l d UJ O U o z • < • B z w I

1- o 3 z z N eg eg 1- < X O 3 O 3 o hi > < • < eg

11

O z Ul z z M o eg »- II o U. U. o

eg • X in o • o z 1- > cg <g X

eg

u • ID

O z Z z z < eg o II o n o « • Ul in O z a mm M eg • a • in U. K • + in D < (0 < N

CO • a o • t z U

Ul

u < o o Ul Ul ^ • o u X X u mm eg a eg a -u eg z • K a a. O a * O <t o -1 U * a • a eg o o z u < Ul mm UJ O X < o • z o Ul • H X X eg z 1 eg a Z Z I z X »- X »- o z M mm K W

1- • Ul Ul M • + a oc U. B II II + O

in

X

U •*

u •* o + < u 3 B B •» Ul

Ul

u V9 o < eg < CM < O

K • z -1 eg <\J eg w < < 3 *-* u < • mm I Z o o « Z < m z »-( O • O • o M — • z •» m • z z z z • K z o o X o z 1 z in B »- eg »- eg X «

eg

u tH UJ z eg eg « X » e eg p> « M o c» o> •< mm mm mm
ID ow

Q P

CD «J

U tK U) § UJ Ul

u 5 2 U) tn 1/) o z s * s N

UJ UJ s s S s V N, s S s a < < >• >- >- o Z o O a < o o < X z < < < -1 o a cr > UJ a a

u.

u

u o o o u. < < < UJ o < < lA

a o o N

m o N « a in in N in (0 in n <0 O V) ^ UJ

(A

a z

2^

«)a

UJ

I-r

19

UJoMNNSNMN<

I-O<uM

-X

UizuoXa

UlX

UJ

K > w < u. o > H Ul

V)

O

O

J

"« <

in

u

UJ I It too Zs

-I<uaoJ< • u

V) ^ <

UJz

CE (- 0 U 1 <

u.aO<< ooo

UJ3

-I

•<> N • o o o o o o o o e o • o O • e

>- o o o o o o o o o o > o « > o J o o o o o o o o o o _l o O J o • z • • • • . • • • • • • z • • z • o 1 1 i 1 o 1 (M N 1 f z z z o o o o o o o o o o o o o o O M o • 1- • • • • • • • • t • • • 1- • < -4 mm < -• < 1 z 1 1 1 1 1 1 1 1 1 z 1 1 z 1 a a IT o o o O

u. o o o s o m u. u. o e z o o o in o o o z o o z o • M • • • • • • • • • • • • M • o o n in N

at o o

u. u. e

in o . •* n m e o o N

UJ ee

n « in o I*) o UJ r- UJ • 1- • • • • • • • • • • K • • »- •

in (0 00

N

n <0

W in lO (A

n 1 1 *4 CVI 1 in r)

M 1 CM

M I -J 1 1 T CM1

(M1-1 1 -1

H II II II

n II

n II II IIN Z O (A z V) w z (A Z

(AUBSC>

in 3 • 1 1 n >• o U. • >• < >- 10 • O m (0 <

-J -1 o o (M o lA

uU z

(M

Q + Q + z o O o z z < (M n -» D ?)

(M o -> -> o (A (AKu o U I z o z o O m < K CM CM u o o + < < o O < ro (A «0 O z in U. z z in UJ (0 • • (M z o m in • 1- CM d CM Z z «0 o »^ • • • o Z 1- o 1- + z z o z o z lA o • z z z o »- z .1- K O 1- 1- n Ul n f o

1-4 o 3 a IT

K z 1-

H II

J • (0 o K N J K H (A »- u II o II

n

—

n

CM 3 Z o (A II lA II Z < II (AH o u z -1 o w II Z Z o UJ U U a (A lA »- ^ a o o o o o It a u CM u o CM U o 10 -1 o u. < M < CM CM -J O z z (A _l o o < w z •-4 rH UJ (A (A K r? Ul in . Ill U. o 1- 1 1 < (A lA o U z U 10 (A z o a N V) 1 < m < (A a K t- w* u. CM < CM

(J Z J Ul o o inU U. UJ «A (A o • UJ z >• o n Z z z z Z z <o z o a z a. in • V) lA K 3 n to z a 3 N u + -i • • ID (A o u n <A + z < w < m Z (A X < o z (M z 1 1 >f < »- + + > Q «A u z O z o w • UJ * 3 w •

UJ z UJ < (A < (A < «A %^ * CM (A Z (A (D

NB

N 1- o a q:

a (A

m (A <A (A < U •My Z (A (A lA < M z z <• o o u U U -J to o y O n J o z o d o CM o z + z z Z V) Z w z u w « o a. o (£ 1- -> 1- Q Z o z » z o z u. u. r o U. z 3 z 3 z 3 z o Z z Z H u H > z z H Z

1-

K 1- < < t- < < CM ID 1- < t- CM z z H H CM (M CM

»-

<0

N o O e N r)n <0 r» co o O

0> 0» 0> Oi o O

O o O o O o o o •i* p4 CM CM CM CM CM CM CM CM CM CM (M
u o Ul V u M e V) z z o u

Ul

ct a: o UJ Ul (S UJ > > < UJ UJ < < 3 u. < N < N N N z z o UJ 1*) S o

iO <0 in tf) in ^ K • • o m (D o> in

(/> o v> in J K Ui • • • • *

*A

a 1 1 • CO

m

UlK o <> > M • • • • * < IL Z

>>o • • m in Ul

_

(0 o > H UJ • • • • • o (A O

UltX • O

O in in tn

w vi o O -J o o in o IS 'O o

»- < o o lo o o

UJ (0

U • • • • • * • X UJ 1 CM a o 1 o• o o 0} CO o

1- • • • t • • • •

Ul *

—1 •J 1 1 > OD o

¥M • s o o o o o o o z o o in in m N • • • • * * * • Z < o o o o 1 u + s < • o a CO •* in o < > _l in in in o 0) o (/> • • • • • • • • o ID z o o o 1") CM O s o 1 1 1 1 J 1 < z • • o y 11 II n A A n II II *^ O < z z w X a Ul 3 a z O

(0 • • (0 < < • < • • o NN 1 f 10 CM CM CM <M ^t z P) Z • CM O • O O • • o • N in • < in X + r 1 1 o • N CM < >• > > 1 to + < in < ID < ID < O CM ID < O • z O 01 CM U. CM O CM 10 o CM < + • • • O O O > J •« • U) to < N o Q O o z O • V) < 10 < < • CM • z • • < • • < to z z X o X CM z CM CM + z

111

H 1- 1- II < u I z cr o: (T O _l u n o < o H II a 11 (0 II 10 < to u. z «^ u. z z z CM o CM

a:

u o 1 o O

O

Ul < < (/) < < • (/) • z OJ «• oc o z Z < CM 1 1 to 1- to »-

N • X 1 X < •* < z < > lf> Z z z • < 1- o O 3 o D to O CM II < II «4 U 1/) < z o z O + IS z 1 (Z • t • < O U (T D n u z < < 1- O 1 1 < 1 * O

UJ Ul CM < CM C7« X ~ • (A • CM to -1 «»

U. • *^ < o • < (0 + • 1 X o 10 q: — u o: •* (Z o o o < Iw1 Q Q w w Q Q (0 oc to _l Z Z 10 z o • < • u 1- t- - 1- o z X o X UJ z z X < 3 X z CK < 1- 1- CE < < 1- «^ < 1- 10 < z u • M o N tf) <0 CO O z «^ z N CM CM CM CM (M CM o o o > o to u V u O cc 3 < z z z z < N s s s N \ S

UJ ID -1 -1 -1 z 3 o

to UJ -1 -1 < Ul cc

ID

N

N < < < Q I < Z 10 10 10 CM • in m <0 <0 N 10 <0

in CM « CM o

10 o o o o • • • • • n 1 in 10 N N

(0 in • • • • •

Al 10

o> o e o

lO in • • •

CM CM

10 e CM (D o o O o ro o o o 10 o o o o n n o « o o o o m • 0 * • • * • • * 1 1 o fO o o o o N • t • • • • • • •

10 1 1 1 1 o o o o o

CM in o o o CM o Ul * * • • * • • *

CM to o O 10 oz3

Q. <^ CM Z CO o • o • • • • • • • • z o tj o 10 CM 10 • m M 1 0* 1 <o 10 (0 z 1 D 3 1 o m

It z SL

H

u

n II II o 1 If to < X V) O o to o X I * K CM o 3 1 Z o

h- 9O • o X CM to • •

CM • < < zo 10 CM CM CM

to + • 1 1 Z \ • UJ 10 O a • CM • o CM fO o < < 1 o N < o CM o a < < 10 z CM > in to to < 10 o CM ID CM • tf) u. • • U v) • 1 O O X X «^ O o to O • o 1 CM o # z • to to < • O CM (X CM < X O »- tO • Z *0 • < • < n o II N X O X X o CM < o o K CM s CM • * o H z < < O (0 o o z K o to O < +

1- 11 11 tr (M z CM • It 10

Ul < 10 It 1 o 1 O 10 z z * • < < to O o • • o

to

Xa to to 10 to fO • 1 CM o • 10

1- 1 X ^ * N

UJ o < * H to CM z z • to O 3 a O X to < o II < y 1- • N • I 10 to 1 z < CM • CM > o Q. o 10

CM < a. (D < 3 CM II z

1- < 1 CM

01 Ul CM 10 Ul

O UJ z - • Q > u to

u

a

to CO < U ID ^ 3 (/)

w < o q: J o Z

to

Q

Q ^ to to o • z X u i o 10 fO z a

t- to 1 < UJ ->

K <0

H

UJ

X <• tJ

X < 3 X

a 1 O I J

X z to

»- o K < K < 1- < < Ul

n 10u z z

o> o «4 CM 10 « in « s

CM

N CM CM CM CM CM (M

CM CM CM CM CM CM

N CM CM
UJ o 1- o a.

u

u z J o o o o u

(/) z < (/) z < UJ Ul

uX

UJ UJ

N s S 2 z z \

a.

a V) o > < o M

M s < Ul UJ X UJ 10 tf) u. IL IL M o

u.N

a o N (D

M UJ UJ UJ

a c a

a

a z O UJ o CO z z o o u. u. u. u. IL (0 a N in in <0 in • o t • • o> 9> o> 0« o> N n 01 01 CM 01 01 • • • O o>

(/) o J I- Ul t • • •

V)

d 1 1 1 • <o p»

.1,

UJ yn

N CO • • • • • • • • • < u. o z z z z z z z o o o o o o

ft

M o • • 9i 01 01 01 o > in o CO flO D < < < < < H UJ • • • • 3 3 D 3 o V) Q N O o O o o a

UJ UJ UJ UJ Ul UJ X • ^ N o o o o o z O 1- o z z z z z o

vs

O

J <0 01 <0 o o o z o z o Z M

M o < in o o O o o e

UJ V)

u • • • • • • t < • < • < UJ UJ UJ Ul UJ • » UJ » 1 1 1 O a a 1 s _J _J J _i K O 1 z ID o o (D o o in If) (A < < < < <

Ul z z Z • CM in o o O -1 o o o o o o o a o a. o a: o s o a o • • • • • • • o • u • u • u • < • < • < • < • < •

UJ • »H < « > > > > •4 > J ( t 1 M 1 1 1 1 1 1 1 1 1 CD o K IT a a • z < O O o

in o o o u o o o > in u. in U. in u. u. in u. f« < z V o o o o o o o o o o e a J • • • • • • • • • • • z • z • z • z . 2 • z < n 01 n o o o o o o o o o o o o o o 1 >> *-i M M M u J a 2 3 3 3 3 5 < • o • t • o _l -1 _l J J e N (0 nj O in O o O o o in o s < > J o « <o z o O (0 «o (0 V) o m o a • • • • • <0 • • • o • • t • • • o (D z t (M o .H II M o o o o O o o o o mm o CM O o

(J o V

n 1 T o 1 CO 1 z 1 z 1 z 1 1 2 J >- 1 « < • » < ID z z • • m (•) a o a to 2 II ^ II n II CO n It II o o II n n II H II n II

n o < X O o o (!» 9 V) X z u. I ± £ t I i t

QC UJ 0> • z

0. z (\i o I 1 1- o o • ct •« a. o • o o o OJ w < • • o X o o * t V * o « • CM h> «^

(4 < o o a

O (A

n s • 1 < n UJ Ul o • a z

to 1 >• < CM o

OD • 1 (A ID - CM o o o Q

01 < < < I 01 CM CM CM I o O o o w o I X X X

v> < < < • 01 CD z 1 r 1 o o o o Q Q -» 3 CM T to to 10 in o o o

l«5

Q r) o O

O o o o w in

m in in

w o f -> < tt o • z < z z z < z tr ro O n z O 4'

Q. o < o in

Q 1/) •4 to o

If)

a z z • z z < o to to to to CM s • < 01 o o I CO z o o a o I

UJ o I X

X

K (0 z z z z o I K H- K Ul m w o u 4 < tt J U 1 < < < X o o O (/) < II K H> I X X I o o II z II Z u (A o N 0> 4' 1- o a u • o o in z (VI O (0 «4

hi

w (\J < o I * w • • • H

X z n < < < • in I I X I R

n

H

n

1- »- o 1 )- «^ o X 3 1 < 1 < 1 1 »- W O * X z K < (•) 10 o UJ ^. CM o o o o J o J o o OJ o • z I H • II II n X 01 CM CM CM n 1 z z z o o X X X X X a o • • o N ft o m o o o II z o o • • z u < < < in (M CM ti4 I < (M 4 1 1 o o w UJ a « a u • ^ ^ o It u. < w < (/» < If) < z n < to to 10 to to to to to 10 o cr a a o O J o o o o o o o o o o Z O * •* o o z z z z z z z z z z n I I I I 4^ I I h- o • h- t- »- «0 - z • J I 3 I X I 3 I 3 UJ I OJ I I I I X X I I < 1- < t- < 1- < < < f- w 1- 1-

AT II U •

«/> o O

O o 01 to in « N 10 » O *4 CM 10 o z CM (M m n n m to 10 to 10 to z N 01 01 01 01 OJ OJ 01 01 01 01 01 01 01 01 01
UI

u

uu

u

u o u

u

uu

V) z z z z z z z z

UJ UJN

V s "V s a s a. a cx a a. IX a < UJ o o o o o o o 2 u. z z z z z z z o UJ « lO <0 « <0 <0 <o a h- N N •K • • lAJ >- 111 (A a 1 •

UJ

K > »- < u. ZJ0 • •

U)

Q >

\- UJ o

Uit- • ^ z • ^ o o o O o o o O J o o o o o o o M •-' < o o o o o o e

UJ V)u « • • • • • • K UI 1 a IDo • o o o o o • • • • • • • u > • J i 1 1 1 1 1 1 o o • z o o o o o o o O < z >k o o o o o o o

a. 3 • • « • • t • z < o o o o o o o o 1 u u a < • o o o < m o O o n fO •4 n < > in m in O (/) o • • • • • • • o 03 z o o o o o o o u O \< z • • o n n 1 II H 1 o < z z z X z X z

tC UI

a. z JO

(0 < < < < < < N <

fli o * P) ro z o o o o m z z z z o • o z • X z • • • • < z X z I • • H p z < z O > »- N « 1! II n < o N ^ U N O o O M Z (M CM CM CM o Z o o Z z Z X CM UI o (M o o o O X z o Z o o o o o u o o o o o o o o o o o N « o z + o + + in K o + * U o in o o z o • • o • < • • • • • -1 • • • • u o -J <J u Z z z • u u X < X < o 3 O J a Z o z O « QO o X o M M • -1 u -i -1 o CM -1 o -1 J E 1- u z u • u • u • U • u • u O z u> z in z z I I o X Z < K UI < z z z * z Z z * z

q: *^

IL o n o r) o n o o to o P) o O o • o • o • o • o • o • o • z o z o z o z o z o z o z o o • z z • z • z • z • z • z z z z z X X X < »- 1- H < •o N e O o z < * « in Z CM «\J CM CM CM CM

u UJ UJ UI Ul M M M M M z z z z Z s s s z z z < ^ < <

-1

J

N

N

N

N

10

n 10 10 • • • • • O o o o oM

!• 3 3 D

-1 -1

J

O o O o

CO

M (0 CO z z Z z z M M M M

h- fc O o O O b Z z z Z z

UJ UJ UI UJu o -1 o o o -J o • ID • 10 • ID • o • o < < < < 1 1 1 *^ 1 1 (X K IX K o < o < o •X o < o <

in > in > in > in > m > o o o o O- • • » 0 • • o • o • O • o • > > > > > • • • -J • -1 • Z z z z z z o o z z o z o in z o

CO o a * o CM o o Z z P) M z •* *^ z z • 1- o • o • o • o • o o < o < o < o < M o < M 1 -1 1 J 1 -1 K 1 -J K 1 J o < o < O < o < o < a Z Q. z Q. Z a. Z & z < < < IX < a < s

IL a. tl ir 11 q: o 11 cr o 11 o X t- Ik X u. X 1- U. X K u. X Ik X Z X z X z X Z X z

UI UJ UJ Ui UJ o X X o o o • a o • s o t (X o 4 a o • s

C9

X

a o X o o X o o X o X o o 1 u. o 1 u. o 1 u. o 1 u. o 1 U. o • o • o • o • o •

CM o o o o CM o o o o CM o CM o CM o H »- <

P)

a o Z Z z 0 Z PJ Z z ct PJ C£ p> a. z a o a o o O o o o z a m u. z u. z u. • u. U. I z z z X Z V z o • o * o o X o u X u X y u 1- u

1-

II 1- t II t a o o o II o z II z II z ^ z z

PJ PJ O U) « in o tfj P) z UI P) UJ p) UJ z UJ o UI X o o s a X o z o o a z o z a o o X o X X • • t (^ • • • • o + ± * o

CM p)nQ PI o PJ + P)

X o CM

a CM o CM o o o o z X z X z X z CM z o z o z o X o z X z o o o o o o o -1 o J o -1 o o < o < o < o < o < o o o J o J o J o in m 0 o in 3 z z z z z n < PJ a ^ «^ 0^ •4 O PJ

P) z o p) p) o p) p) o p> z o PJ o o o X o o o o o a o X o o z o z • z z • z z • z lO • z i • n I z PJ • + z • z • <0 z • + z • PJ z X o X p) X PJ X o X

CM 1- + CM o X o o X CM o (M CM o X

eg

n 10

in in in 10

CM CM CM 01
u

UI Ui

V) z M <

lU UJ \ V < z K

u. < < < UJ

O UJ

JJ U. in N N <0

tf) ID 10 10 • •

V)J

K UJ •

Ui

H > ^ • • z z 2 o o o I iiit M 5 • » l_

(AO > < K UJ ' J J J

Q (/)

Q

Q o o o

lii in (A UI X • z z z

V3

O

J

M

(-• <

lii (/)

u 1- UJ

UI

r o b o z z 10 O <

UJ UJ UJ • o _J O _J o o cc • • ID • (D • <

UJ • < < < > J 1 1 1 1 (D o Of tr o < o o u > U) > in > IL < z s o o o • • • • 2 X < o • o • o Q 1 > > *^ # J • «J • 2 2 < o tn Z O o z o J o 2 P) o Q

*^ z O Z M 2 o • H O # 1-1 o • Q

Q (D < M < M o

(J 1 J ^ 1 1 1*) 2 O < J < < < 0. X O Z

Q. CC < o CL to 11 tt O II < O II ft o 11 O < X U. I q: u. X H- IL i

f. (X UI

X Z K 2 X z

Q.

X UJ 1-4

X

M UJ »*• o o UJ o o o • o q; o • K

Iff

Q I O • O o Q 1 u. o I (L ^ IL 1^ Q Q 1 Q Q Q OJ .'N Q o

CVI

Q

m CO O Qz Q QJ Q 2 Q Q ll J» 1^ ^ ' ^ 1" 2 Q ow Q {Wt CNJ {J X J II II o < o II o o «^ 2 o 2 tf) ro n 2 CM 2 Q (/> Q |V) (/) UJ z (A o UJ ^ X X UJ z Q 8 <0 Q X 3 o (*) o Oi Q s • Q 2

QC o

UJ

D (T)

Q o ^ o Q Q O Q X 2 2 Q 2 X X X X X Q o X

Q o o J o II M Q < o Q -1

Q

Q

wQ

O < z

UJ <f a o o

ll o PJ 2 o O ro 5 o Q Q X z o o 2 2 2 X

(9 ' o 2 ^ 2 n z 3 I o X o X

X < 

N K w 1- o H Z X CM < o o z u •

(A o 0 0*

CO z n lA 10 tf) z 01 N ni M

1)w

u < < u u u < z \ s N V s

or CC QL

g

GC /yi£ UJ Ui UI r\w V) UJ

1^

J CD 1^

tf) « <0 2 U)

tf) tf)

N • tf)

r) • • • 1

tf>

tf) CM o • • •*

1-

Q tf) % 2 Q f) V) o o f) W * * * * • Z 1 1 1 w

tf) 2 2 Q o o o o u

CM fOQ 1 1 1 1 CM 1 (J O LJ w o _w ll

tf) CM o tf) *^ tf) * * o to W

W

llIk 2

tf) tf)

Ik, 1*)

wU

u« UJ * * • O * •

V* CM CM tf) f) tf) 1 1 1 t W Ik 1 9 O O

II II II

w < IL II II (0 X U) w ll X 4X * UJ 1 

O *k V

UJ UJ X o o ^ O M

UJ ^• 1 •J CL

tf) 2 o f)

O tf) CM CM CM CM CM X X X X X

U.

_

— z o o tf) U) w tf) tf) tf) CM CM O UJ ^ X X tf) X X X o 8

—J

tf)

X

f*)

m 4 o ^

r) UJ r*) r# O O X Q ro UI o UI ^ O

O z Z Z 2 z

rtIk z y • CD n z ^ * n XJL X IW M^ ^V X XX

(X

O ^ tf) ^

IL tf) *0 ^ w CM

H

H ll

II

II II «J 1 H

n1

tf) </l ll

Q

(£ IXw

X tf)

w

w

w

O

w ^ III UJ 1 

w - 

<M ^ X w O o X

X

U.a

O ^•

UIJ ^ o ^O

tf) CM CM CM 3 IL CM ro ^ O CM CM X X X X 4 UJ X II CD X

if) tf) tf)

O tf) • O

O HI lA ^ tt N ^ (D ^ 1 «o tf «J v ^ _ Ow ^V V^ Q mr/ tf) UJ r# o o o O • H o • a O o 2 2 2 2 u o 2 X IL ^ 2 r J s O Ui f*) <( tf) /V O 1^ LL w * X X w o X ll Ll X X o o H CM N X z O N r) tf) <0 N CM CM CM CM CM CM
Ulo

V) z

Ui Ui X a < lU <

ILa

a Ul

V)a s •

1- • •

(0

-1K Ui

in

a • o o a o a o cr o o o o o o o • < • < 9 < • < • t • • • • •

Ul • > > > > J J 1 1 1 1 > 1 1 1 1 1 ID o a (T a • I Q o o o o U. u. IL < z N o in o in m in in in in in

Q.

D

J • z • z 9 z • z • • • • • • • < o o o *^ o (VI o o o o o o o o 1 M

(J 1- 1-5 5 < • o J _i Q o o o o o > 10 (/) n (/) o q: (0 (VI •o o •o 10 1^

(/) o • • Q Ul • • • Q ID jr CM o o (VI o • Q N o Ov ro o (S CO Q >^ 1 1 o z (VI 2 (VI in

in II (A 1 10 10 10 10 «^ 10 1 Ui 10 < 1 1 1 1 1 1 1 1 1 1 f) n Q o o o Q. (1) ^ II n n o II o II ro II II II II 11 s II < II N o < I a I 2 i 2 I o t (VI X (VI ± (VI t CVI Z (VI ± > X (VI a Ul z 4' 2 3 a z « Z Z <f Z • z • z • z • z 0 10 z • J I Z (V> Z (VI Z K h- 1- 1 O 2 Z Z Z U o

to z in Z in z o 13 (Vi 15 o (VI V9 z (M (VI (VI (VI (VI z <t z z u Z * z M (J Z N 1 1 1 -1 J -I J M

J

N 1 o * * in o in

u

w

u 10 (0 o w

y z fO in

u o <» (\i 3 z 3 z 3 z z 3 z 3 z 1- z 3 z N CM z m (0 ro 10 10 »- (VI 1- (- z 1- • z 1- N I in o o o a o * (Vi 15 10 »

in o (M z z z z z o O cc <r o cr a. o o q: Z O

X z (VI o (VI o (Vi o (VI o w (VI o II (VI o z z z 10 z U. Z u. 10 z u. Z u. n I u. in ? z u. • * z H z H z 1- z in -1 m z in _l in z in 3 -1 Ifl < n »- »- z in Ul o in Ui z in Ui in Ui z in Ul -1 u in Ul n a Z Z z 3 * 3 o 3 < 3 N •• 3 » z 3 < o Z z (U in (VI (VI -1 -1 J -1 Ij -i •• _i J o O J J Q z (M •* u < 10 o < <t < 10 o < < u < (VJ (VI 10 u < z II z n z z > z z > z > z z > . z > z z cr z z > Z z li z z -1 o z < I -1 -1 <J z z u z in z in u z o z u. z U H o u o o o » • * o eg o (\J o (VI z z u z u z y z Ui z u s <M II z o z o <V1 z 1- z 1- z 1- z z • I- z + z 3 (- z •

Ul II z (VI Z (M z in o o a o a o a o o C3 -1 o o z (0 z ^ z (VI z >^ z z z u z < z u u in in 11 < II 1- < 11 1- < II 1- < II K < o > II H < o U z z z CVI (VI z 3 3 3 3 10 3 3 3 10 2 a _l J -1 J -1 -i -1 z ~ _l U -1 in -1 z a o J o (M o 10 o n + IS o o o a o o o z 13 O J a 15 o a z

Ul (VI in Z in o in o in in < in < in < (/) < (Vi

w in < u o in < 10 z z O (S z z 10 10 ro (0 ro (VI ro »- (V (- z » o 1- •* o z u. -I z IL -1 • z Ul -1 X U. * z u. J z X u. o z u. J

10 z < m < z (VI < <st < z u z o u * z O

u z o u -I z u z o z z o u z z o Ul o o Ul z z Ul i X Ul z Z J z z z < z u 3 o z z z z o z o Z > < > u >• > < N > (VI > > * M * + « + ro 10 Q. + a + * a + a 4' a + a a. a l- z z -1 -i J -I 10 + -1 + J + n o z u. z u. 10 U. 10 U. < < (0 < < z < u < < I < o u. o u. o o u. Z ID z 13 Z z o z 15 z - z 13 * z J z 13 i H UJ CM » w ro z 10 z u 1- 1- *' z u 1- u ^- u X u »- z o z a o « a o •* o z 10 z 10 — z ro z 10 z w 2 10 z z < z 10 X

U. o n o z z z z •* Ul z Ul z z Ul z Ui z 1- <f Ul z <t (VI UlX ? Ul z o o P) Ul o n Ul z Ui z Ui z z z z z z z

IS z z z z • z z L z -1 z z -i z II

L z _l •* z z H

n 3 z 3 z 3 u cr

V o a

u o K

u o q:

u o C£

u o a o o m 1- (/) 1- (0 a. a O (VI a o a (VI • q: o J a. O cr o (VI z z in z z m in 1/) m + <n z IL U. I \L u. u z u. U. z \L u z u. u. z u IL u. z u. u. U < K < »- * < w < < H 1- H z z z <u z z o o

(0 •o CO o Al 10 Ifl <0 « o z « ^• N N N z (M (VI N (VI (VI (VI (VI (VI (VI
Ill y

V) z

ui

u < < < < < Ul X X X X z

u.

u

u CJ

w

O UJ • • • O V) o o H Ul * • . • n1 10 1 * ^^ w

Ul r- in > * * ^^ IIIk z

I* in

CO 2 ?i

II) r- UJ • # • o (A O

UJX * ^ O o m O J w o Ul

»—^ ^ lA o - n

Ul * * * •

111B Ul > 11 1 W o . 1^ * *

uJ *

aJ 1 CD w • z - U < z V in in _ _

ID

J * • V o o O PI' o 1 u +

(t < • o < > -1

N nl o • t • • • o OD z in <M u o s 10 J r) CM 10 CM CM rl < 1 1 t 1 1 1 1 1 z t • u O o o O o Q, V) II N 41 II K 11 N

*^ < X

W

X

X

X CM

1— tt Ui 3 (L Z z • z * Z • _Z •

•J

N o u CM Ci/ U

i/)

w ^ U Cd

_

CJ? >r CJ Z •* z * Z 1*) z N —1 n J -1 X

J r) o X CO (J CO CJ z CO VJ X

VX z 3 X 3 X CM 3 X Z N u K

«M • * CJ S n q: o a o a O N X C\J o • w o X ca o • CM o fO z X u. _1 X u. z X u. J X Up X

ID

u \D GO IT) o m z < Ul m Ul in UJ Ul CM

1- •* 3 3 3 *** < -1 _1 n -1 -1 X -J 1*) -1 -1 10 OD O • u < I u < z • u < I (J < X CM -1 X z X > X > z X > _l z 1 u u CM O < z I/) • z C/) z * z CO U) u X • X • X *^ • X • CM M U H- u 10 z z z X z z X • z

UJ o o z o a o o z X II z II z *^ 11 Z 11 z u o 1- < < X < < X • iL o 3 3 3 3 X z -J C3 -1 K (/) a. >rf a X o ^ a X UJ Ml n 1/) < n V) < Ul n CO < 1*) CO < Ul cr X X X J X X *^ _l 11 3

I— z U. -1 z U. -1 0. z u.

J Z IL

J Q. CO o u u z u u z CO z z X (>J X CD X CD X o u UJ 3 o > u >• w (£ d. Q. + + CL + 10 tL

(T + + -i o + + -1

X

O < < z < < z z X X < X X X C3 X C9 oo

UJ

U

H 1- z U 1- z a

(Z

w Z z z Z r) ** z z <

IL <t Ul

X

u

X < U!

X UJ

X < > O z * z z • z • 1 •J II •J z 11 .J (9 V o q: u o IX u O (X u o cr o o O a o a o N (T o a o CM a

-i X. u. u.

X u. u.

u

X U. u.X u. u.

U I u. ^< 1- (- 1-< «i« u •

vt o 0>

O CM 10 s z N 0) o CO «0 z (M N (M (M

Os •J < < s < z z CD z UJ u M M 19 N o

<^ « 10 o w o • * o o

U) o z z CM CM o oM o _o o o J * *

-^ o o w o o o o o o o o o o o * * * * o 1 z

UJ UJ

w o 1 • • ID (D * < 1 I1 1 K 01<> o

10 o o o o to * * * * *

10 • m * in > I 

z z -

\/ o

in *

(M o _z CM

U o u z o • * UJ • CO o • UJ fO J o • • ^ *

CM o CM CM Q. t Cli o o 1 o CM U) ro f .Sn ( 1 • < 1 1 J < 1 1 10

Ul z */) z z O ex I/) (£ UJ

II

NG II < z • O II II o n 1 X CM U. X £ It X X O z CM z o

UJ • U *^ UJ

CM

c^

Ul z _ w (^ 1 o Z UJ o VI

tL CM IL < to X _X

CJ

O + z O o • • z o * (D z to

CO o v) < U 01 • 1 # o (0 to O X • o X z z II 1 + 1 z X *^ o II u CI) UL 01 (L (L > X ID < CJ o CD • o < • • to J -J Q. CM X > z u Ul CJ UJ CM O u X cc > GD 01 z o X * • o (D UJ < (X X z u. * X a o • Q * o Z 1— 10 UJ X Ul X

UJ Z z ^* z J* z * • • X 3 3 CM

II o -J Vi < o CM CO 4 V) < o K CO CO

n Ob > u U CI (0 II <

"D CL Z • UJ 1 II to J CO D X < z > X * Z * o < U. h* X u O 1- o

-J CO

w

T 1 v7 1 t o o j£

IL

Q

Q 2 11 01 CM

a r*

X

O Z o OC ro fO

a

O 10 10 o z < ro UJ ^ O • N d • X CI u) 10 X ^ PI

_

CL

X o X • K »<

X + h- a <D »- O • < • CM z 1- CM X • O • • o + <

CJ II !« CO (£ Z ^ CO o <t z li. UJ X UJ Ul UJ o u > Z in Z a o o: e

CO Ul 01

-J z CL

u o o a a o z CM o (0 CO <- z X

cc o * CDX • o CD • X LL u. X CO X r- UJ Z X (Z 0» X • K tl* CM < m z

in « N CO »

CO CO OD CO CD CO

CVI CM CM CM CM CM
u -1 z -1

a >• o (/) > IS in in o y J o < o < a o (/) in a o in in z

V) z < z (0 t- z o a UJ UJ o a Ul UJ <

UJ v. s S ? s s s \ s. s a tr m o a «A UJ > in en UJ > in in o < UJ UJ 3 o UJ 3 < z a a o o a IZ o o D u. N Z Z z z IS ID z z r" O UJ CO in O « o o N o O s f- (M

CE U) « o « c^

\0

N o N « <0

N •

t- • t o e N o <0

</)

O V) o o CM p)

J 1- UJ • • • • • • • •

in

a 1

«41

»4 1

•41 1 • O n o> « o tn o

UJ 1-

N o (0 > >- • • • • • • • • • z O J »4 5 • • 00 o 1- CM CM CM

(/> o > CM 3 m in in in

t- UJ • • -1 • • • • • • o U) o O

lU in KI • o N a> O K o o z CM CM o s p) o o O O J o O o z o o CO CO «4 o o> o o O

•-' < o (\J CM o •- o o o N v4 o o o

UJ V)

u • • • • < • • • • • • • • • • • X UJ 1 1 r a o 1 v4 1 X o z 1 o Mz UJ • o o o o o o o -J o N in o o o • • • • u • • • o • • • • • • • • •

UJ • M *4 < «4 CM ** f4 J -1 1 1 1 1 t 1 1 1 to o a • z <

(J o o o o o > < z s in O CM o o in in o O o o o o o a 3 • • • • • • • « « • • • • • • • z < o in • •4 «4 o «4 • f4 •4 «4 o 1 u > •

-1

N <o

K z • • • < • o o •4 • z

l- in CO o CO v4 1- CM < > in -J At CM n N CM z <0 1 o (0 J f4 1 o •4 o a • • • • • • • o • • • 1 • • a • « • • o o z O tfl (M CM - CM (Z in UJ in CM o 1 in •4 CM « in UJ CM CM t- CM > P) p) 1 -i CM * 1 < 1 K 1 1 > 1 1 1 1 < 1 1 Z o tr z • • a z cz • UJ o a (/) II It II • M II II 11 II 1- 11 II UJ II II in II o .'i .'i R o < o z z in z z z Ik O 3 IS o IS IS a IS

in 0 O

a UJ II z < o 3 a z Q. M (A z a. -i U U. (Z t- o O < K o O 3 z

«n

O z < y- + • U. 3 o z 3 • < K • UJ < < \ < • V) z • N UJ H CM Ct (M <* 10 (A CM • • n • o 1 < o o > 3 • o o 1 • * • < o • OJ «. o -i CM < • < < O CM • o o o u <• O 1 > 1 CM 1 1 P> •4 • 1 u u o z < < < < CM 1 CM CM U P) + 1 < O > • CM o >- >• > CM

1-

am CM -> CM (Z CM

m CM CM 10 > o CO rvi ID

O > < CM •f a • U. + m + O o • o O P) ID a z a * < z » z < Q CM CM -> CM o CM O Z m y- z o o • O U a U • U * CM O

-J « u

— ^ 1-

w in CM CM CM -> • < -> ->

U • < I o u 3 y a U U O * -> • • o < O • u t- < N * n • -) • t- • • • < Z O Z in X < z < z o M o u (^ II z O z m Z z < • »- < Z • • «4 < t- z »- • t- f4 o •4 p4 Ul II z z • o • (Z • f4 X (Z 1- 1- 1 (A • CM o 1- II (E 11 IZ II a Z 11 a H u 1- in II II « II (- 1- 1- <J> 1- H »- a o • U) o u H o 1 (A V) «/) w in z o z u u in CM O - z Z < z < Z N < z < z < (A

IT < o O < o (/) < o < o o • a II o Z

lU II— 1-

Q CM Ii4 CM

M CM CM CM 4 1 o X • • < « CM J CM CM 1 1 CM 1 1 CM M Q c^ o CM a 1 • UJ 1 U. 1 1- l- K 1 <t 1- U «• O

Q. < o u < t • Uu < z M * o < < O < O < o < P) s z n CM o • J o t- > O CM CM in CM o CM Z < 3 o z <3 Z UJ (M J CM 1- CM CM U CM o U o CM U «4 CM M o • + in (3 y a U O y • • • -1 • Z • U

(t OJ • n « u

a • Ul CM CM CM CM CM « P) *4 • O o U. (M CM CM M CM P» •4 I < r + CM u + Ul + X + u. + 1 + 1 1 > f 1 CM + 1 + 1 UJ + w z K Ul

IZ • M • • <• 3 «>» • »- • • • a *^ • • m

u. < <J

w

W < IT) in < K < in < m < W 1- < in < < in o a V a • • V) (/) ^ a z — U a. a (Z y> IT CM IZ IZ Q CM O u ^ Q ^ UJ Q Q o z Q o + z Z z z •f -1 + z + z + z o I z + z • ~ t- • - t- • IS • • UJ - H • o • »- • • 1- >-" • »- • t- •

-i z < 3 z Z 3 z z z V) Z 3 I UJ z 3 Z 3 Z 3 X 3 X o z 3 Z 3 < < >- CM t- 3 h- < < H Z < K < < o ^- < CM < < + H o z

CA z u « •o O CM m in <0

O

O V4 CM P) in o z o o 0" 0" o O O O O O o z OJ CM CM CM CM CM CM CM P) to PJ m P) p)
UJ

O 3 3 3 ccKK s (X

K

u »-

O

O

O o O

O o o o O

if) z 10 u. IL

u

uUU tw1 UJ UJ V s N N 1^ \ s. N, s s s \ a a 3 ViJ U u u V u

<, UJ UJ < < _l

J -J •J

J IL </) _J < ^ < o Ul p o «4 «4 «

to to

N

N r*

V *0 ^ <0 HI • • O

t/) o

-iK UJ • •

(A

a 1 1 • <»

UJ

K > *" * * z < IL * * CM iO «O >III o O• Q (A O tX t A o * O o O o o e o o o o o O J o> >- O o o o o e o o o o o

*^ o O o o o o o o o o o o e

UJ tou • z t • • • • • • • • • • • • 3 UJ 1 o 1 1 1 1 QC (D 1 O _o • o _ o o o — w o W • • f • • * • • • • • •

UJ * CM

_J 1 1 1 1 1 1 t 1 1 1 o o • o u o o o o * z o o in ifi o O o o o

-1 • • • • • • • • • • * * 9 • z < n n n 1*> o 1 K

X o u o >; >

IL

J -J Ul < • o •J S IB

l- o o <0 oo I*) CO < < < < UJ < > -1 s UJ r) CM (M o o 3 N 3 3 3 O 3 > O o I/) o • • • • • • • • • • • • • K • O H o ID z (/> (M o tj CO U O U a s 1 1 1 1 1 1 CM < fO < < < CM < P) < CM ^ z 1 1 T «^ 1 1 1 1 19 UJ < z Z 1 z z z Z z • • o o a o o o UJ < a tf> A n II II 11 II n II II II H r_ II 15 h- o < o z X Z z X 1" Z Z

(T UJ tJ Z &

0. z < < < o w

UJ Ul Ul Ul UJ UJ (t ( K. DC oc ot K K IL vl •

Ul Ul Ul Ul UJ Ul <A

K

N > > > K

O

N

MM ? {S* V9 \9 15 • u X & N < In o <^ u) CM ni • CM r- 1- 3 < s O IS • • • • O O O o O o < K N + 1 • CM < z z z z z z < o 1 < 1 1 • 1 >• Q o > 1 < o o o o o o (D < o o >• CM > > < > o o o o o -> o a H z > IS + ID + m ID u (M in < <\J o < CD < (VJ (A • to to to <^ CO ^ Ul Q u • o Q o O a CM K IX a CM q: • o z • O • Z • Z z • o • O (0 to • o • o UJ z o + • + u w u • z Z ro tn z z UJ z UJ z V9 < z z o 1/) O O O ¥- • " t- UJ 1- V5 K ID t- P) v4 Z u o o < < < • 3 z z 3 3 * 3 • 3 o

u) • • « < X < < < Z < z < z 1 s z II • • • z 1*) X z z X IL

III o X z 1- 1- • • • O X 1- a a tr a O O II O II o o O O ^ • u • (£ s II M II II II II II II II II U o o (0 II (/) II (0 II W II Q, 0. (L 0. II (L H Q. •4 P) X < (0 n

(/) II z Z z z U *** • • t^

UV ~ U

a z z o o o -J • J 10

J 10 -1 • J • -1 • • tA

OJ o < < < M • Ul UJ

u Ul Ul • UJ to UJ to UJ to 3k UJ z o < < o u o o o o tj Q o o u 1 1 1 • o w z 1 < z < z < z < Ul • UJ UJ UJ UJ • UJ • Ul * c X z (M < z < z u u u • z z 10 z to z • z UJ z Ul z UJ O UJ o U u u w v> oo 3 (0 3 3 3 UJ 3 19 3 19 3 z o M *^ X (0 in o in o </> (A CM to m to to to 10 CM

q: • • CM • "J • • U) 10 to (0 to CM to

m to

w tA o u CM CM < < + < < < < < + 0 z < 1 + 1 + 1 1 \ + 1 + + + + + o z

UJ • • • • • • UJ IT • • • • • • • • a • > t»

IL < I/) < V) < < < (/) < • o O (0 o 10 o o o » o to

M til o a (X a a (£ a. in o • to o • o o u o • (0 o • to o • to o • u cr 19

<* o O <• o o O o CO o u

Q 00 00 o uQ

O o u -< o Ul P) z + X + z + X + Z + z ^ 1/) in • 10 to to to • o z • • • t- K • • • z X < * • < • z J" X < X X X X 3 z D z UJ X UJ K 1- UJ X UJ z UJ Z 1- UJ

J* 1" ro

m P) < • X

(A o « CO o (M

n

m CO <^ o z o o o o *^ *-« z n r) m m D n tn n n
UJ

a

a

LJ o u u < <

Ui UJ s z s a cr u u s N < UJ -J .1 z u UJ o U. < < ^ o UJ «n «A

q; <0 <0 o O • « N N • •

V)O (A

t- Ui 1

(A

a•

Ui h- > M • • • < u. z z z z o a o g3 • • »- »-

lA o > 3 3 3

H> UiJ -1 -i

Q (A

O o O o

ID (A (A <A

1-Z • M o o z Z z O J o o M < o o

(A

U • • »- »- s UI 1 o o O a ID z Z z o

UI UI Ui • o o -1 O O

1- • • • ID • ID • ID

UJ » • < f-t < <

_l

J 1 1 1 1 1 ID o s a

a 9 z < < < > > > < z o o in in a 3 J t • • • • z < in • CM • N • o 1 u y > u > > _i J s z Z z < • o J o o o o < < o < > _J t m z in z CO z o 10 o • 1- • 1- • • o • o • o o ID z S U U CO UJ C\J o M

(J

O \ < < K < ••4a

N

n

_l

T 1 (A • < < < < z z 1 Z Z S z • • u o o (A 1 a IT a. o a (A II II (i^ II (A z o II O 11 o o < i t- I K z < u u, Z \L th u. a UJ (J Z 2 2 z a z < < o

-1 UI UJ UJ

n o a a -1 « a IX

K

(A o o O u UJ z o u. u. O U. > > z o M (A II V 19 H z Q. N o • a (J

>k

O

O lA

u S z z s _i _l o UI UJ • u o (J o z z o O < " o o 3

CM 3 U. UJ UJ < > (A (A o < z z Q UI tr UJ a • 3 3

U) o a > z z (A z (A

-1

n I m z m

a (A V> < • K • UJ z < z < U I 3 z z M K < t- < z X • OJ (M

UI • » _J • >• (0 03 z II O II O < O II (\J II tM u II 00 1- <J o — a a • (A _J ^ X • u • u z UJ a t u 1 a (A _J (A _j < K

iu

U U! UI

J z _i <VI lO CM o X w Q a 1 Z

t- • II o

UJ UJ UJ UJ

a • z z „ z z o z o z a IL U. 3 o 3 (3 H X s I M (M (A in (A >^ (J UJ UI a »- (A (A m o UJ o 'f < < 00 J Ui UJ I < • CM UJ + K * tUJ ^ • • a 1- < <. a • o < • 1- I»

U. (AO inO UJ • • lA » (A o tj in • (J o • o Q (A (A >^ * a o t- O O

(A » V)

a o <A «A o I < z < < o - J • -1

»- 1- UJ 1- ill z 1- UJ z z o Z o < < z < z t- < z < I- lA 1- n n <u •

(fl o o fM

n * o z CM CM N z to ro o 19 < < < < < < z z z z Z z < < s s s N V s z z

UJ UJ UJ UJ UJ UJ N. ^ ^ UJ Ui

(A lA (A V) (A ^ o o O o o (A (A s N o O • • z z o o M M

»- < 5 3 3 O O

UI Ui o o o o o o z z o o o o o o M M o o o o o o • • • • • • Ui UI i _l J D 10 < <

•-4 o o o o o O o a • • • • • e • < • 1 > > 1 1 1 r 1 1 a I a o o

u. u.

m in o o o o • • • • • • • z • z N in in N o o o o m r>

»-3

-1o

in in (A

N Si • • • • • • 9 • e (M CO cu O O O o

CM «4 1 z z 1 1 1 1

II

n II II II z V) z z (A o • o o O o o e O

II

N

II II

H II II

N

a

UU

a Ui a.

a

a Q.

a a.

y

V o in

u in

U

u

u

J -i

U -J

U -1 -1

J

J

UI >^ UJ tu UJ UJ UJ

U UI

U Ui

(\J o CM o N o N

a z o Z o o w o

10 10

UJ UJ UI UJ

X UI I UI UJ . Ill z z z z z 1- z K z s-« 3 3 z 3 z § 3 3 Z zS z (A z (A (M lA CM (A N (A ^ (A (A N «A K lA 1- W (A (A lA •4 (A (A • «n < < Z < z < < < z < z <

in in t- 1- II II »-

«t •«

II II •-4 «4 11 II »-* (J

u II (M (7> «4 o •M u *4 o O s •>« «^ r-< • *4 r-t -4

u

in 1 in 1 (A 1 (A 1 1 1 1 ^ 1 ro 1^ U <t U o o . «

<0 in in z ro z 10

M z o> z • o> (^ (M (M <7> z z 0> • z •fl z z •f z •» Z Z «* z •t z «

H- U. »- u. u. u. u. »- U.

H U. s z z N z z z z z

UI CM UJ UJ UJ in UI in UI 10 Ui 10 Ui + UJ + UJ + UJ + UJ UJ + UJ + UJ * Ui

1- 1- 1- »- < < < < < < !5

1- 1- • 1- »- • 1-

(A (A (A lA tf) (A (A (A (A V) lA (A lA lA lA U U u U U o o Q o O o O O iio Z _l Z _l z J Z -1 z J X -J z -i Z -i o 1- O o 1- o 1- O 1- O 1- o

lA (A (A «A CA (A (A (A

M co CM CMN

N

in <0 <D

O

O CM

(M CM CM

N CM 10

l») ro 10 ro 10 10 10
Ui Viz

w - (9

u < < < < < z Z z z z z Z

tu UJ \ s s s

OL UJ Ui UJ UJ UJ UJ UJ UJ ^

(L

w (0 V) V) V)

LU •«« N N

N

|t» •

W) o VsUJ

*/)

UJ>

Ik

u

UJ

U) o

UJX * o o o o o o o -J o o o o o o o o o o o o

UJ 1w1 • • • • • • •

UJ 1 1 1 a (D o o o o o o o * * * • • •

UJ1 •J 1 1 11 11 1 \ 1 to w

*^ • Z 1, < z o o • * * • • • *

CM ou

csw o < > o

10 • • • • • • • o CD z to u O s >o f N n 1 1 1 1 1 n < 9 1 • Q a II y 11 R H 11 H o < ± X 10 £ Z

oc UJ 3 Ql z JO

(/J ^ o O o o o o o N IIn II n II 11 11 II

CM (L. IL (L

d Q. (L ^ U (J U O u U in

-Ju -1

u

J • -1

UJ UJ

N UJ UJ *^ UJ

w UJ o UI • o o • o • o o N o u o • O O • O UJ O UI UJ UJ • UJ • UJ X UJ < u z z z z O z o z z • • 3 u 3 3 X to X V) z (0 Z w V) w

to 10 1- • V) • (/) (0 < < < X < X < < N N in tn »- II «• *•

II II II II UJ ID in II o II o U

N

D o o 00 VJ <Vl w o u o o o *^ >^ • » N 1 1 1 1 Mi 1 tf) 1 • 1 • * • o • o U *^ O o

UJ

O

O

O CD

O CO

w

m

U

X

Uu • • fVI CM CM • o • • • Z X u X X IL X >- u. IL u. u. 3 o z z z z N z z z

UJ UJ UJ UJ UJ U) in UJ

K h- O UI + Uj + UJ UJ + UJ UJ + UI Z < 1- »-

UJ < < < < < < * • • • • • •

u. (0 10 tO

W 10 V) V) to

Q

uu

u

u

U

Q

O

_o o o » e o X X X J X X -1 X J X -1 O o o o o o

«0 (0 tn to

If) lf) C>J

w < «O U) CO m «) n Z m m m

m

(9< < < Z z z \ s, s

UJ UJ UJ

in lA in in in in in lA

«*• *4 19 19 19 o 19

h.N

N z XXX z X o O O o 1- o 1- o t- o « t- « 1- o o O o z o z o z o z in z o z o o o o o c o • » « • < • < < • < • < • <

txam ITa

H- «4 »-

in in lA in 10 z z Z z z z o o o o o o o o o o o o o o • • • • u • u • • u • u • 1 i

«41 1

*41

•41

«41

•41 1 o o o o o o o o o o o o o o o o o • • • • • • • • • o o o o o o o o o o o lO o o o in o o o o o> • • • • • • • • O in o o o i> 1 T

II

n

H II II

n

n

H H, (0 X lA V u ISw 0< o o O u H II CM w a. Q. a z

in

u

U o o • J J J Itw n V o UJ u UI U UJ m o a ^ o in z • n N • H z UJ • UJ . UI * 10 z o z ° ? 3 u 3 U 3 X n w l>- tf) S lA • CM w • V) • in o 19 u X O < z < z < m »- •

II

K z M CM in 10

«• tO

X • 19 • • H o O II It * z X CM o (0 ID n K- O N o *4 am «4

in 1 1 w 1 • H u 19 • O o « • 01 in 10 U «• o o (^ o CM o

0>

u • • X * • « OJ in CM 10 Z •» z z o V9 19 in X 19

1- u, U. 1- u. ^ 1 z z in N CM oo in CM

in UI

n UJ

n UJ • O

X » • X o o + UI UJ * UI + + -» + < < — < < • • 1-

V)

w in V) in in • » m

m

n • u (0 in in in m

a

a

u

u

u « U

M

w •»

X z -1 z _i Z -I * > o «

IO o H

O z z I X I «» z

(A (A in 1- 1-

K • 1-

N

X

1-

O U)

N o * *

p) 1^
t- Ui

V)

a z

(A (A in O o o Z z z z(A (A (A V) «A (A in O o O Z z Z z " Z z z < U. o >

lAO z

(Ao

UIz • -»

lU tf)

U S UI I a ao

tuX

-Io

»-

u < z a 3 sa I o + < • < > a (A o o u o z • o a w o K a 3 a

-to

(A <SoJozV<

(A<

UIz

UJo< o a • < I a o o O IL o• z o oMK

(M -J ^ O

0> (A zao

tti

UI

-Jo< o cr • < ^ > I a o o o u. o• z o o3

c3 5! zoM<O

lU o <0 »- o t- t H z <M 1- o 1- o t- o 1- o 1- o (- o 1- ^0 1- o »- o z in z o z O Z m z o Z o Z o z o z o z o z in z o z o o vO — o o o o o o O M • < • < • < • < UJ • < • < • < • < • < • < t < • < • < n a a a J a a a a a a D a

(- tK tm

K

K 1- (A «A <A (A < <A <A «A (A lA lA (A <A (A Z Z Z Z Z Z z z z z z z z o o o o o o o o o o o o o o o o o a o o o o a o o • u • u • • u • < • u * • • u • (J • u • • u • w 1 1 1 1 1 > » 1 1 1 1 1 1 1 I o o o o o

OR o o o o o o o o o o o o o o IL o o o o o o o o o o o o o o o o o o o o o o o • • • • • Z • • • • • • • • • o o o o o o o o o o o o o o o N

CO«zo ooo 3 o Si •o oz N o o o o o o <o o

in o o o o o o in o o o o o o o o • • • • • • • • • o o o o o o n o H II II n II II n II U u V V u u u u o 10 o

ni • (M • s X • z •z K 1- < • K fO < II u n (9 < < n 19 • • n < + o (A * u -1 < 19 U) »

u. 19 u. U. o z < (0 * • • » • CM « U z z N z z u. U. z u. Z CM z M O t- tt. U. t- • • O »- z 01 * z z z in H u o z Z K »- • in z H u 1- II a II CM • H u * U • o II N II + — (A z • • H R m • • o + O • a • (A lA lA iO — CM (A UJ • (0 O (9 19 « * iD • Z CM 19 z in • ^ (A (A (A (0 in • •

1-

NM lA lA (MN 19 19 (9 V9 • CM

CM U. a. 19 19 U. U. * w CM • z z N Z «3 CM CM CM 3 o Z in in (M N m in U. U. u U. U. « CM 10 M M « • « U. U. • • U. U. • S o o (M CM CM CM CM > o N z < + + K f

UJa • *

u. tf) • • • • * * • • « • • o u u (A in ifi lA lA (A (A lA (A (0 lA tf) u u u U U U U U u U u u U u o • w w w w • o z z * • » • • • (A * • • K - z z z z z Z z Z z Z z o z z Z < 1- »- 1- h- I- 1- K 1- ^ K M * < CM < O u •

U) o » o N

m

m « o » O CM « o z in in in m in in in in in in « <o z n 10 m n P)
ifi Ula<O

V)

tf) v> <A V) «n V) (0 V) V) (A «A (A o o o o o V9 V9 X X X X X X X X 1^ X X X X X X

O (A K 111 (0 a o«azou

UJ

K > « < u. o >

V)

Q I • o o K o 1- o o o 1- o o o o o 1- o o »- o 1- Q o Z o Z o z o z o z o z o Z o Z o z o Z o z o z o z o z o Z o z < o o o o r> o 1-4 o o o o o o O '-' o O M

Ul

U • < • < • < • < • < • < * < • < t < • < • < • < • < • < • < • < > tu 1 a a a a cr a (1 a a a a a

00 t- t- i- 1- »-K 1- 1- o Vt (0 w (/) vt lA (A (A lA «A (A lA (A V) z z z z z z Z Z z z Z z Z Z Z Z • o o o o o o o o o o o o o o o o o o o o o o o O O • • • V • o • o • u • u • u • (J • • • u • • u • u • u S • «4 *-< 9^ v*4 f-1 «4 «4 V4 •4 < a < > O (A O 00 w o z • a a. It o 3 a o

(A

1^N<<<uzuoXa

UlX oX\J<

txooss

-I< <

Ulz o & X < H Ula

U.oo3<<

<A

(0z o o o o o o o o o o O o o o o o o o o o o o o o o o O o o o o o o o o o o o o o o o o o o o o o * * * * * * * * * * • * * w o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o e o o o o o o o o o o o o o o o o * • • • 9 • • • • • • • t • • • o o o o o o o o o o o o e o o n II II n A n H II II II H n n n u w u w u umo u < U

Ol

N

n

M 01 o d + o o z » OT w

X' o •

OT • X

H

X

X »- I »- < u H K * u a « «A II H o • • • (M u n

-1

a o (A *4 • u IS u OT n « z V) • O • » N OT • OT OT X X X 01 N 01 OT v> (9 i

10

K « o w - (0

X o 19

w 1- 01 • X I w X 01 01 o

»- 1- in

XK 01 o o

II II

N • X o n o n U H II 01 • • • N •f •

(A • (A (A II + OT O -1 • • (9 * W «A (A • VI OT • • OT

(M 01

u

U (A (A

u

w (A

N

01 * * U (0

U

u OT

u

u z J • a K c3 >^ u OT 01

<J -1 o O <M (A

N OT OT 10 z

«A in

w • N 01 01 o + + + + + + + * A f « u • • w * • • • • OT OT • * * m •

in

WN (A (0 (A

W

U

uw to OT (0 OT

u

V • U

u

u

u

u

U ^ u

uU

J * • U • * • X X « « • X X O i X I X X X X t- H X X X X

X

H

H • 1-

H

K t- »-

X

N 01

1-

in <0 s O o 01

n 10 « N o O « <o « N N N N N a m m m n fO D m r) m n m
Uiz u UJ a a

UJ

]^ (A

liJ If) (0•

''J

u (0

f" UJ

gr 1 1 d •

UJ o

UJI • o o O -1 o < o

Ui tf)

u • X LU 1o • •

lU • J 1 o o

Iu < z a 3 zO i < • < > a in o o u o § a w O

IX 3 a

-IoMN

(VI <OJ<UMz

111 XuozK

U)IZ3M

oco

-i< • o <

UJz

(A •«

(U

O

O <XX o »- o z O xi • <a

V)z o»Ooo o »- o z O <' « <

cr

»-

(/) z o o • w Iooo

UJ

-I

ID< I a o o O U. o• z o 3 O -I o o o o o oz o za

I-inz o a • u I ooo e r o <- • <az o o • u I ooo

UJo< o a • <

-« > I a: o o o u. o• z o o3 O -I oO (/> o oz

(/) in V5 u X X

O

H o z • <a

t-(AZ o o • o I ooo O Z o » • <

a.MZ o• u Iooo

OKO tO I- o z o z o z • <ana• < • <

>n in z z 0 o o o • U • <J 1 r

(Az o o • u I ooo H H II u II II + II m H

in

m - ro in • u (A (A • o <j (A « (A u U tA

in z U (A • (A

U

U

V

U » Z o

OJ

X z u o Z K z Z N o u • z w N CM UI 10 n • (A « • (A (A (A •

in «9 lA (A «A (A

U

U

U v>

Uw

U

U

U

w « • o X X

X * X X X X X K (- X

X

H

H

K • N N M N n m « N 0) » O

CO CO CO 0) CO oo

O CO o

P)

n

n ro

n l»)

(A

-J • •

(A Z

UJO

U

X Z •-' t- H3 Z Z -I o o o M (A

(A

H

UJ

U IH < < O UJ X z a t-

(A<

UJJ • < (A U Z

(A

UJH I U < <

lA UJa

UJX u. H O Z O 0 o

-I z <

UIK 1 < K U K UI 3 I a H o w

t- z O I- o z O M

•H

a

s.a

UJ

>•

a

CO

U.

O UJ

UJ

ma

ui>z

UIaz

UJ

UJ

IS

(A«XaoH<

u.

inM • X X H O

-I • UJ

in

m z

10 13

•- Z

UJ lA

UJ in a 3

u.

u

(A o •-• Z Q < o > in

a. -I

-I < <IK U) Z Ui

Hi (A

(AZ

UJz

UJa3

(A<

UJz

UI (A

_l UJ o •-• Z K M (T (A UJa

UJ o a a < a

(A UJ z a w o < z Xu ao

UJQ o W KZ • UJ O UJ

UJ s Z I- M UJ Z (0 a

UJ (A

I- z

UJoa

U)>o <amz

_l o

-t

u <z •

fi in < UJ Z H o a U Ula

in^ a a a

t- <

UJ 3 Z o>

inz oz « > Z U.

UJ UJz
UJ V) o z m o X

1- Fl »- • u w tz <

UJ

IT

UJX

t~

UJO< o

UJ

(A < >- UJ z Ul O a UJ X I

(-

a I <

(A UJ ft z z tr ft Ul a z

UJ o o to o o u u. Ul z

UJ (3

1-

a UJ z 3 o a >- z s o

u. u.

M o X < J K (0

•M

a < o u 1 z (J < UJ < (0 UJ o UJ X w < (J a: or »- > z a K UJ z o -1 O UJ u X z < UJ 1- o UJ < I K u. o M < Ul u. UJ • Z z 111 o (0

UJ 1—

z 3 a o V5 > • o M 2 t- H- 3 to o z X

t- o > UJ < < J z ft UJ 1 UJ < H- a a. X Z < X V) Ul < UJ UJ UJ z ce • X LU z X < 10 »- 3 »-

1- o z UJ to < Ul o u. t- Ul UJ Q UJ o < X u < _l UJ z

UJm > a. Ul I < J »- a. 3 < u o z Ul J I M <0 UJ UJ I u. > t- _J < (/) z m a o < W a UJ a Ul UJ o z < 1- UJ 10 X z >

UJ o X

u z UJ o 13 z o I

1- UJ 3 a ft

K > u Ul t- o UJ o < < X UJ u u. 3 1-

UJ I < <

Q. a. UJ tr UJ ft < X > o > W a. o u. U. X

l-i o 03 o ^- o

u. < z ft Ul Z

Ul ft « ' UJ

UJ o o < < Z u »- < > Ul o o X o Q Ul

1- Z ^ a tn UJ a z q; UJ

(/) (X

K t-« o -1 Q. I

Ul Od

a

>• EC

IJ so

UJ

aw o a

X o z w »- ft U. X o UJ < a ft z UJ X UJ a. 1-

UJ • ^- < 3 o a I UJ _l J u. UJ 3 X Q. o < < u

f- > a > z X o • »- Q Ul

Ui z ft _l -1 < O o (/) < < UJ o

_l z Z K < UJ a o C3 V o

a.

U (0 Ul

X Z 1^ > 3 o < z UJ o Ul J

Ul o (0 < 3 UJ o u K < M M O a z

UJ Ul UJ a. o

(/) UJ Q£

u

X (0

a

x < 1 < Ul K Q UJ < o o cr o Ul ft Z UJ z < z q: 10 O u. > < < o t\J o a <

u. Z a U) • UJ V) • o o UJ UJ (- lO < z t- a 1- t-» (0 10 CD *-« O o I o K < a O z Z Z II > < UJ ft u. II ft < UJ o < -1 > < > X o < Ul ft UJ a z UJ a I o o _l

UJ II UJU

K ft • < O z u UJ 10 o X

m 1- I z < z a u. Ul 3 o u < 3 in o a. < • ft

11. Q (A s UlJ

CO< «

11. o "> <>

UJ o

QC

M

ft tA 5

(0 UJ < tr Ul a •

Ul o cr o z X < 2

%^ o UJ (0 UJ 2 2 2 o X

Ul •

CD

X h- z tA Z »- 3 2 (A o 2 tA o >

(J Q.J

u.

U 1- < Ul tj Z

ot < <

(0 > Q. Ul J ft 9s o: <

Ul 1-

1- Ul U. < < u. a O O z Ul

ft O;

X ft Ul

CM

X o X o I s o o 2

(ra z y II o < a < UJ IL > 2 o lA

Ul

Q 5 2

Ul o

(0 Ul 2 a |_ < iL IJ > Ul 3

II Ul IL

a o < o

(M tf) V) ft X to 2

Ul

Q 2 s UJ ^

(0 < <A Ul < (0 X u y- Q r o UJ

Ul Ul

J 2 tt o < o Ul •

iL

Ul < Ul 2 |b

to

V

Q

UJ 2 2 UJ a. < UJ

tA 2 _l

Q

to UJ 2 > o Q o J

1*B o Q • V) 1- tA

OJ ft UJ 5 III o (0 UJ > > o w Of (J o z < < J • z J < tA < 2

(J o Ul Ul 2 0^ UJ < J 10 tA 1) > 2 Q Ul Q V)

Ul 3 2 ^ U) to (0 Q

tj ft II UJ 2

UJ (/) o 3 ^ Ul X 2 3

Ul < 3 o UJ

(0 UJ

X tA lA

J

Ul o X ^ 111 q; 2 to < to to (A Ul

(/) to < < tA

J

Ul Ul Ul <

II

y -1

J -1

u z ft w tA

UJ «0 ft ft

X z

UJ UJ to to o

U. (0 q: 3 Ul UJ o M J ct IT CD »-

ft

w ft < ft ft tj

UJ z o > o o a. < > o t- K o Ul < VJ (A < 10 lA u. a
III. BIBLIOGRAPHY'

.N3S EVALUATED DATA (SEE COMMENT ON REACTION)

09«AK VON WARTENBERG. He.; Z. ELEKTROCHEM. 15. 866 ( 1909)

30mS MISCIATELLI. P.; GAZZ. CHIM, ITAL. 60. 882 ( 1930)

325DT/BEC ROTH. W.A,; BECKER. G.; Z. PHYSIK. CHEM, A 159. I (1932)

34NEU/<R0 NEUMANN. Bo ; KROGER. C«; KUNZ. H.; Z. ANORG. ALLGEM. CHEM.

218. 379 (1934)

39FIS/GEW FISCHER. W«; GEwEHR, R.; WINGCHEN. H. ; Z. ANIDR3. ALLGEM. CHEM,

242. 161 (1939)

40B!RA BRASEI-ITEN. C,; COMPT. REND. 211. 326 (1940)

41STR/ZUM STROTZER. E.F.; ZUMBUSCH. M,; Z. ANORG. ALLGEM, CHEM, 247.

415 (1941)

46GJG GUGGENHEIMER . K.M,; PROC . PHYS. SOC. LONDON 58. 456 (1946)

4eRDB/LEV ROBINSON. R,A.; LEVIEN, B.; TRANS. ROY. SOC, N,Z. 76. 295

( 1946)

49D0D/R0L DODGEN. H.W.; ROLLEFSON. G,K.; J, AM, CHEM, SOC. 71. 2600

( 1949)

49WES/R0B WESTRUM, E.F.. JR.; ROBINSON, H.D.; THE TRASURANIUM ELEMENTS.

NATL, NUCLEAR ENERGY SERIES. VOL 14B, PT 2. 887

(MCGRAW-HILL. NEW YORK. 1969)

50DAY/STO DAY. R.A.. JR.; STOUGHTON, R.W.; J. AM, CHEM, SOC, 72. 5662

( 1950)

50EYR/WES EYRING. L. ; WESTRUM, E.F,, JR.; J. AM. CHEM, SDC , 72. 5555

(1950)

50WAG/STO WAGGENER. W.C.; STOUGHTON. R.W.; U.S. AEC REPORT DRNL 795(1950)

51MAL/CAM MALLETT. M.W.; CAMPBELL. I.E.; J. AM, CHEM. SOC, 73. 4850

( 1951

)

51ZEB/ALT ZEBROSKI. E.L,; ALTER, H,W.; HEUMANN. F.K.; J. AM, CHEM, SOC.

73. 5646 (1951)

52M0T/WIL NOTTORF, R.W.; WILSON. A.S.; RUNDLE. R.E,; NEWTON. A,S-;

POWELL. J.E.; IN KATZIN, L,I,; U.S, AEC REPORT TID-5223.

350 (1952)

52WAG/ST0 WAGGENER. W.C.; STOUGHTON. R,W.; J. PHYS. CHEM, 56. 1 (1952)

53EYR/WES EYRING. L.; WESTRUM, E-F,. JR.; J. AM. CHEM^ SOC. 75. 4802

(1953)

53GRI/SK0 GRIFFEL, M. ; SKOCHDOPLE, R.E.; J. AM. CHEM. SOC. 75. 5250

( 1953)

533SB/WES OSBORNE. D. W. ; WESTRUM. E.F. .JR.; J. CHEM. PHYS. 21. 1884 (1953)

54L0H/0SB LOHR. H.R.; OSBORNE. D.W.; WESTRUM, E.F.. JR.; J, AM, CHEM.

SOC, 76. 3837 (1954)

54<RA/H0L KRAUS, K.A.; HOLMBERG. R,W,; J, PHYS, CHEM. 58. 325 (1954)

55FER/KAT FERRARO. J.R.; KATZIN. L,I,; QUOTED BY GILBREATH. ET AL. IN

U.S. AEC REPORT ANL 5451. 89 PP, (1955)

55PAN/MSE PAN. K. ; HSEU. T.M.; BULL. CHEM. SOC. JAPAN 28. 162 ( 1955)

5SFER/ICAT FERRARO, J.R.; KATZIN. L.I.; GIBSON. G. ; J. INORG, NUCL. CHEM,

2, lie (1956)

57D»E/B00 D'EYE, R,W.M.; BOOTH, G,W.; J. INORG. NUCL, CHEM, 4. 13 (1957)

57LAN/MIE LANGE. E.: MIEDERER. W.: Z. ELEKTROCHEM. 61. 407 (1957)

58BEA/MCT BEAR. J.; MCTAGGART, F.K.; AUSTRALIAN J. CHEM. 11. 458 (1958)

58DAR/KEN DARNELL, A.J.; KENESHEA. F.J., JR.; J. PHYS, CHEM, 62, 1143

( 1958)

596AG/MAS GAGARINSKII, YU. V. ; MASHIREV, V.P. ; ZHUR. NEORG. KHIM, 4, 1246

( 1959)

59ICIN/WEL KING, E.G.; WELLER, W.W.; U.S. BUR. MINES. REPT. INVEST. 5485

5 PP. (1959)
5 9V 1 T

5 9Z 1 E 50DAR 12

6 OD AR/ MCC

60L AM/DAR

60MAY/DWE

60WAL

61 BUC/3ER

61DAK/MCC

51H0C/J0H

6 1 I DN/MIT

ei V 1 C/DOU

52N I K/LUK

53ACK/R AJ

63ALL/MCD

63YEN/L

64J AC/BAR

64NAB/<UD

653AE/ME

65EDV/SEL

65L I N

65SCA/TUR

65WE S/T AK

66ALC/C0R

66AR0/AUS

66CHI /G AR

66G1 N/ARO

66HEU/EGA

66LEV

66SU/N0V

6 7AR0

6 7BER

57M0S/ESS

67ILI/RUT

67WEE/M0R

N'lT'KlNA, E.A.; AT. ENERG. (RUS5.) 7. 163 ( 1959); SOV. AT.

ENERG. (ENGL.) 7, 669, (1959)

ZIELEN, A.J.; J. AM. CHEM. SOC . 81, 5022 CI959)

DARNELL, A. J.; U.S. AEC NAA-SR 5045. 13 PP. (1960)

DARNELL, A.J.; J. INORG. NUCL. CHEM. 15, 359 (1960)

DARNELL, A. J. J MCCOLLUM, W.A.; MILNE, T.A.; J. PHYS. CHEM. 64.

341 (1960)

LANDIS. A.L. ; DARNELL, A.J.; U.S. AEC REPORT NAA-SR-5394, 15 PP

( 1960)

MAYER, S.W. ; OWENS, B.B.; RUTHERFORD, T.H.; SERRINO, R.B.;

J. PHYS. CHEM. 64, 911 (1960)

WALLACE, D.C.; PHYS. REV. 120,84 (1960)

BUCHLER,A.; BERKOW I T Z-M ATTUCK , J • B . ; DUGRE.D.H.; J. CHEM.

PHYS. 34, 2202 (1961)

DARNELL. A.J.; MCCOLLUM. W.A.; AEC REPORT NAA-SR-6498, 14 PP.,

(1961

)

HOCH.M.; JOHNSTON. H.L.; J. PHYS. CHEM. 65, 1164 (1961)

I0N3V. V.I.; MITTSEV. M.A.; SOV. PHYS. JETP 13. 516 (1961),

VICTOR. A.C.; DOUGLAS. T.B.; J. RESEARCH NAT. BUR. STAND.

65A, 105 ( 1961

)

NIKOLAEV. N.S.; LUKYANYCHEV. YU. A,; SOV. J. AT. ENERGY (USSR)

12. 334 (1962)

ACKERMANN, R.J.; RAUH, E.G.; THORN, R.J.; CANNON, M.C.; J.

PHYS. CHEM. 67, 762 (1963)

ALLEN, K.A.; MCDOWELL, W.J.; J. PHYS. CHEM. 67, 1138 (1963)

YEN, K.-F«: LI, S.-C; NOVIKOV, G. I.; RUSS. J .INORG. CHEM.

6, 44 (1963)

GINGERICH, K.A.; U.S. AEC REPORT NY02541-1 (1964)

JACKSON, D.D.; BARTON, G.W., JR.; KRIKORIAN, O.H.; NEWBURY,

R.S.; J. PHYS. CHEM. 68. 1516 (1964)

NABIVANETS, B.I.; KUDRITSKAYA. L.N.; UKR . <HIM. ZH. 30,

891 (1964)

BAES. C.F.. JR.; MEYER. N.J.; ROBERTS, C.E.; J. INORG. CHEM.

4, 518 (1965)

EDVINSSON, G.; SELIN, L.E.; ASLUND, N.; ARKIV FYSIK. 30,

283 (1965)

LINEVSKY. M.; CHEM. PROPULSION INFORM. AGENCY THERMDCHEM.

PROCEEDINGS 1, 71 (1965)

SCAIFE, O.E.; TURNBULL, A.G.; WYLIE, A.W.; J. CHEM. SOC.

(LONDON) 1965, 1432

WESTRUM, E.F., JR.; TAKAHASHI, Y.; STOUT, N.D.; J. PHYS. CHEM.

69, 1520 (1965)

ALCOCK, C.B.; CORNISH, J.B.; GRIEVESON, P.; 'THERMODYNAMICS*

VOL I, P. 211 (INT. AT. ENERGY AGENCY, VIENNA, 1966)

ARONSON. S. ; AUSKERN. A.B.; J. PHYS. CHEM. 70. 3937 (1966)

CHIOTTI. P.; GARTNER. G.J . ; STE VENS . E . R . ; SAITO.Y.; J. CHEM.

ENG. DATA 11. 571 (1966)

GINGERICH. K.A.; ARONSON. S.; J. PHYS. CHEM. 70, 2517 (1966)

HEUS. R.J.; EGAN. J.J.; Z. PHYSIK. CHEM. ( NF ) »9. 38 (1966)

LEVINSON. L.S.; J. NUCL. MATER. 19, 50 (1966)

SU. M.T.; NOVIKOV. G. I • ; ZHUR. NEORG. KHIM. 11. 498 (1966)

ARONSON, S.; J. INORG. NUCL. CHEM. 29, 1611 (1967)

BERAN, M.; COLL. CZECH, CHEM. COMMUN. 32, 1368 (1967)

MOSKVIN, A. I.; ESSEN, L«N.; ZHUR. NEORG. KHIM. 12. 636 C1967)

ILINA. G.G.; PUTGAIZER. YU • S. : SEMENOV, G.A.;

PRIBORY I TEKHNIK EKSPER. 1. 151 (1967)

WEED. H.C.; MORROW. R.J.; U.S. AEC REPORT UCRL-70245. 26 PP.

( 1967)
fc fc H 1 E / 5 1 L

t 3HUE/ ^0L

68DHA/MDR

66ZAL

69GI N

69GJE/PED

69L0R/5CH

69MUC/5MI

69SMI/HER

69SMI /THA

7CBAJ

70SRy/R0G

7CDEV/R JD

7 OGRE/BR

701 JP

70MDO

7CRDS

70SEI/AST

70SKE/MAG

70ZMB

7 IFLO/OSB

7KL0/MUK

71KUS/I MO

71L AU/r DU

71MIL

71SKE/MAG

72ACt<./'R AU

72ADE/HUB

72DAN/NDV

72<NA/MUL1

72<SA/MUL2

72TED/AN0

HlETANEN, S. ; SILLEN, L.G.; ACTA. CHF.M. SCAND. 2.2, 265 ( 1968)

HUBER. E.J,. JR.; HDLLEY. C.E.. JR.; KRlKOPIAN, N.H.; J. CHEM.

ENG. DATA 13. 253 <196B»

OHASHI . H.; MOROZUMl. T.; NIPPON GENSHIPYOKU GAKKAI 10.

2A4 (1968)

ZALUBAS. R.I J- OPT. SOC. AMER. 58. 1195 (196e»

GIN6ERICH. K-A.; HIGH TEMP. SCI. 1. 258 (1969»

GUEST. M. F.; PEDLEY, J. B.; AND HORN, M.; J. CHEM.

THERMODYNAMICS 1. 345 (1969).

LORENZ. K,; SCHERFF. H.G.; TOUISSANT. N.T.; J. INORG. NUCL.

CHEM. 31. 2381 (1969)

MUCKEN. K.; SMITH, G.S.; JOHNSON, Q, ; ELSON, R. C . ; ACTA CRYST.

825. 236 (1969)

SMITH. D.H.; HERTEL, G.R.; J. CHEM. PHYS. 51, 3 105 (1969)

SMITH, B.C.; THAKUR, L«; WASSEF, M.A.; INDIAN J. CHEM. 7. 1154

( 1969)

BAUMANN. E-W.; J. INORG. NJCL. CHEM. 32. 3823 (1970)

BRYZGALOVA, R.V.; ROGOZIN, YU. M. ; CHERNI TSK A YA . I.V.;

RADIOKHIMIYA 12, 286 (1970)

VAN DEVENTER, E.H.: RUDZITIS, E.; HUBBARD, W.N.; J. INORG.

NUCL. CHEM. 32, 3233 (1970)

GREBENSHCHI KOVA, V.I.; BRYZGALOVA, R. V. ; ROGOZIN, YU. M.

RADIOKHIMIYA 12, 279 (197C)

COMMISSION ON ATOMIC WEIGHTS OF lUPAC, PURE APPL. CHEM21. 91 (1970).

MOORE, C.E.; IONIZATION POTENTIALS AND IONIZATION LIMITS

DERIVED FROM THE ANALYSES OF OPTICAL SPECTRA, NSRDS-NBS34

6 PP. (SEPT. 1970)

ROSEN. B.; SPECTROSCOPIC DATA RELATIVE TO DIATOMIC MOLECULES,

(PERGAMON PRESS. ELMSFORD. N.Y,. 1970)

SEIGEEV, G.M.; ASTRASHKOVA, L.G.; YAGODI NSKA YA , N.N.;

RADIOKHIMIYA 12, 392 (1970)

SKELTON, W.H.; MAGNANI, N.J.; SMITH, J.F.; MET. TRANS. 1.

1833 (1970)

ZMBOV, K.F. ; J. INORG, NUCL. CHEM. 32. 1378 (1970)

FLOTOW. H.E.; OSBORNE, D.W.; WALTERS, R.R.; J. CHEM. PHYS.

55. 880 (1971)

KLOTZ. P.; MUKHERJI, A.; FELDBERG, S.; NEWMAN, L. ; INORG.

CHEM. 10, 740 (1971)

KUSAKABE. T.; IMOTO. S.; NIPPON KINZOKU GAKKAISHI 35, 1115

(1971)

LAUBSCHER, A.E.; FOUCHE. K.F.; J. INORG. NUCL. CHEM. 33.

3521 (1971)

MILIC. N.B.; ACTA CHEM. SCAND. 25. 2487 (1971)

SKELTON, W.H.; MAGNANI. N.J.; SMITH, J.F.; MET. TRANS. 2.

473 (1971)

ACKERMANN, R.J.; RAUH, E.G.; J. CHEM. THERMODYNAMICS 4,

521 (1972)

ADER, M.; HUBBARD. W.N.; O'HARE, P.A.; U.S. AEC REPORT

ANL7e76-l. 33 PP. (1972)

DANAN, J.; D5 NOVION. C.H.; DALLAPORTA, H.; SOLID STATE COMMUN,

10. 775 (1972)

KNACKE, O.; MULLER, F.; VAN RENSEN, E.; Z. PHYSIK. CHEM. ( NF

80, 82 (1972)

KNACKE, O.; MULLER, F.; VAN RENSEN. E.; Z. PHYSIK. CHEM, ( NF

80, 91 (1972)

TEDESCO, P.H.; ANON. M.C.; J. INORG. NUCL. CHEM. 34, 2271

(1972)
721JSH/SKD USHERENKO. L.N.; SKORIK, N.A.; RUSS. J. INORG. CHEM. I7t

1533 (1972)

72WEN/SPI WENTINK, T.« JR.; SPINDLER, R.J.; J, QUANT. SPECTROSC.

RADIAT. TRANSFER 12. 1569 (1972)

73ACK/RAU ACKERMANN. R.J.; RAUH, E.G.; HIGH TEMP. SCI. 5. 463 (1973)

73APE/AZ0 Af^ELBLAT, A.; AZOULAY, D.; SAHAR , A.; J. CHEM. SOC . FARADAY

TRANS. I. 1973. 1618

73CDD CODATA TASK GROUP ON FUNDAMENTAL CONSTANTS. CODATA BULLETIN

NO. 11 (DECEMBER 1973).

73HUL/DES HULTGREN. R.; DESAI. P.D.; HAWKINS. D.T.; GLEISER. M.;

KELLEY. K.K.; WAGMAN. D.D.; 'SELECTED VALUES THERMODYN. PROP.

ELEMENTS* (1973) PUBL. BY AM. SOC. METALS

73<RA/M0R KRASNOV. K.S.; MOROZOV. E.V.; FILLIPENKO. N.V.; GIRICHEVA.

N.I.; IZV. VYSSH. UCHEB. ZAVED. KHIM. I KHIM. TEKHNDL. 16.

1500 ( 1973)

73SKE/PAT SKELTON, W.H.; PATTERSON, J.W.; J. LESS COMMON METALS 31. 47

(1973)

735JG SUGAR, J.; J. CHEM. PHYS. 59. 766 (1973)

7430H/<RA BOHKES. E.W.; KRASSER. W.K.; SCHENK, H.J.; SCHWOCHAU. K.

J. INORG. NUCL. CHEM. 36. 669 (1974)

74GAB/^EE GAB ELN I CK . S . D . ; REEDY. G.T.; CH A SAN 0 V , M . G . ; J. CHEM. PHYS.

60. 1167 (1974)

74HIL/MUR HILDENBRAND. D.L.; MURAD. E.; J. CHEM. PHYS. 61. 1232 (1974)

74NEU/ZMB NEUBERT. A.; ZMBOV. K.F.; HIGH TEMP. SCI. 6. 303 (1974)

74:?AU/ACK RAUH, E.G.; ACKERMANN. R.J,; J. CHEM. PHYS. 60. 1396 (i974)

75C0D CODATA RECOMMENDED KEY VALUES FOR THERMODYNAMICS 1975.

CODATA BULL. NO. 17 (JAN. 1976). AND CODATA SPECIAL REPORT

NO. 3 (SEPT. 1975). CODATA, PARIS.

75PAR/WAG PARKER. V. B; WAGMAN. D. D. ; AND GARVIN. D.

NAT. BUR. STAND. (U.S.) NBSIR 75-968. 34 PP. (1976)

75RAN RAND. M.; AT. ENERGY REV. SPECIAL ISSUE NO. 5.

IAEA. VIENNA (1975).

76CHE/WES CHEDA, J . A.R . ; WESTRUM . E .F . . JR . ; J . CHEM .THER MD DYN AM I C S 6. 25

( 1976)

76GAR/PAR GARVIN. D.; PARKER. V. B.; WAGMAN. D. D.; AND EVANS. W. H.

NAT. BUR. STAND. (U.S.). NBSIR 76-1147. 37 PP. (1976)

76M0R/MCC MORSS. L.R.; MCCUE. M.C.; J. CHEM. ENGR. DATA 21. 337 (1976)

77FLC FLOTOW.H.. ARGONNE NATL. LAB., PRIVATE COMMUNICATION. MARCH 1977
IV. APPENDIX

Thermal Functions for Thorium Compounds

In reducing high-temperature equilibrium measurements to

values at 298 K we have made use of the thermal functions S°,

(H^-H" (298)), and G" -H" (298) /T for a number of thorium compounds.

This section of the Report contains tables of values of the

functions that have been used and gives sources of data from which

the tables are derived.

Th(c) The high -temperature enthalpy measurements of Levinson

[66 LEV] from 1260-2100 K were fitted empirically to the following

equations, which also reproduce the value of Cp at 298 K:

Th(c,a): Cp = 6.267 ± 0.000664 T + 7.02 x lO'^T^ cal/mol-K (298-1660)

Transition (0,0-) = (c,p): AH = 870 cal/mol at 1653 K

Th(c,P): Cp = 3.72 + 0.00288T cal/mol-K

Fusion (c,P) = (1): AH = 3300 cal/mol at 2023 K

Th(l): Cp = 11.0 cal/mol-K

The above equations for Th(c,Q') yield Cp values significantly

lower than those reported by Wallace [60WAL] and Mitkina [59MIT]

and reproduce the values of Levinson on Th(c,a) more closely than

the equation given by Rand [75RAN],

Th(g) Calculated from the 75 energy levels to 20,000 cm ^ given

by Zalubas [68ZAL]. Up to 2500 K these values are essentially the same as those given by Rand [75RAN].

ThO(g) Calculated from the molecular constants given by Rosen

[70ROS], using a non-rigid rotator, anharmonic oscillator approximation

and including contributions from the higher electronic levels.

This analysis of the higher levels is different from that used by

Rand [75RAN], and consequently our values of S* are lower than

Rand's by 0.01, 0.03, and 0.54 cal'K" 'mol" at 298, 1000, and 2000 K,

respectively.

A-1
Th02(c) The entropy and enthalpy content at 298 K are based on

the measurements of Osborne and Westrum [53 OSB/WES]. The high

temperature enthalpy data of Victor and Douglas [61 VIC/DOU]

(273-1173 K) and Hoch and Johnston [61 HOC/JOH] (1450-2750 K) are well represented by the equation given by Victor and Douglas.

The data of Hoch and Johnston show considerable scatter with

respect to any simple analytical function in T. The equation

used to calculate the thermal functions is:

Cp(cal-K"''"-mol"^) = 17.060 + 0.001806 T - -^^i^^

T

Th02(g) The molecular constants are taken fran Gabelnick et al.

[74 gab/REE] who demonstrated by isotopic substitution that the

gaseous molecule is bent with an apex angle of 122°. The low

lying frequency is taken as 120 cm"-'-, based on an estimate by

Linevsky [65 LIN].

The available vapor pressure data on Th02 are not easily

reconciled with the available thermal functions but do satisfy

functions for Th02(g) as a linear molecule.

ThXn(g) (X = F, CI, Br, I, n = 1, 2, 3) The values of uj^ for

ThX(g) were estimated using the Guggenheimer equation [46 GUG]

we have estimated the anharmonicity constant (JUgXg. The degeneracy

of the ground state is taken = 4. Values of r^ are taken from

Krasnov et al [73 KRA/MOR] , who also give values for uUg.

For ThX2(g) and ThK^ig) we have used the molecular constants

and frequencies estimated by Krasnov et al. [73 KRA/MCHl] for a rigid-rotator-harmonic oscillator. As the ground state of ThO(g) was shown to be ^T., we have taken the degeneracy of the ground

state of the dihalides to be unity, whereas we have estimated the

degeneracy as 6 for the trihalides ThX2(g).

ThF^(c) Values of S° and H-H(O) at 298 K are based on the measurements of Lohr et al. [54 LOH/OSB]. Preliminary unpublished high

temperature enthalpy measurements by Dworkin [74 DWG] from 1200 K - 1420 K were used to obtain approximate values of the enthalpy of

fusion and heat capacities. The equations used are:

Cp(c) = 29.2 + 0.002 T - 300000/t2 cal/mol-K

AH(fusion) = 10000 cal/mol at 1383 K

Cp(l) = 32. cal/mol«K

A-2
T^F^(g) Molecular constants have been estimated by Krasnov et al.

[73 KRA/MOR] and by Rand [75 RAN], Calculations using both sets

of frequencies have been made with the vaporization data of Darnell

and Keneshea [58 DAR/KEN]. A better fit (Second Law and Third

Law] is obtained with Rand's function so these are adopted here.

ThCl4(c) There are no good low temperature heat capacity data

for ThCl4(c). The measurements by Chauvenet [11 CHA] near room

temperature are unreasonable. We have estimated S*'(298 K) = 45.5 cal'K"l»mol"l based on comparisons with HfCl4(c), ZrCl4(c),

UCl4(c), and the UF4(c) -ThF4(c) difference. We have accepted

Rand's heat capacity equation [75 RAN].

The enthalpy and temperature of transition and fusion were

determined by Chiotti et al. [66 CHI /GAR],

The equations used are:

Cp(c) = 28.75 + 0.005561 T - 147000/T^ cal/mol-K [298-1042 K]

AH (transition) = 1200 cal/mol at 679 K

AH(fusion) = 14690 cal/mol at 1042 K

Cp(l) = 40 cal/mol-K

ThCl4(g) The thermal functions for ThCl4(g) are calculated

assuming a tetrahedral molecule (symmetry = 12), ground state

degeneracy = 1, and the Th-Cl bond distance = 2.58 X. The frequencies

and degeneracies are taken to be 300(1), 70(2), 335(3), 75(3).

The frequency at 335 cm"l has been observed by Buchler et al.

[61 BUC/BER] . The enthalpy and entropy of vaporization data

computed from the measurements of Knacke et al. [72 KNA/MULl]

are consistent with the functions given here. The data of

Fischer et al. [39 FIS/GEW] on the vapor pressure of ThCl4(l) and

(c) are not very consistent with the selected functions.

A-3
ThBr^Cc) The heat capacity of the solid and liquid is based on estimated constants given by Rand [75 RAN], The enthalpy of

fusion is calculated from the vapor pressure data of Fischer et al.

[39 FIS/GEW]. The entropy is estimated. The equations used are:

Cp(c) = 30.5 + 0.0036 + - 147000/T^ cal/mol-K [298-952 K]

AH (trans it ion) = 1000 cal/mol at 693 K

AH (fusion) = 7000 cal/mol at 952 K

Cp(l) = 41 cal/mol'K

ThBr^(g) The functions are calculated for a tetrahedral molecule

with Th-Br distance = 2.72^ and frequencies 205(1), 58(2), 220(3),

72(3), as estimated by Rand [75 RAN]. The vapor pressure data

of Fischer et al.[39 FIS/GEW] are consistent with these functions

for both solid and liquid.

Thl^(c) The thermal functions for the solid and liquid were

calculated from the estimated heat capacity and enthalpy of fusion

data given by Rand. The vapor pressure of the solid has been

reported by Landis and Darnell [60 LAN/DAR; equation only]; data

for the liquid are given by Fischer et al. [39 FIS/GEW]. The

two sets of data do not agree at the triple point, and do not yield

similar values for the heat of sublimation at 298 K. If it is

assumed that the Landis and Darnell equation, log P(atm) = 10.32 - 10700/T

should be log P(atm) = 10.32-10300/T (misprint in the report?),

both sets of data yield consistent values and indicate that S°(298)

= 61 cal'K'mol"-'-.

The equations used are:

Cp(c) = 31.0 + 0.0031 T - 147000/T^ cal/mol'K [298-839 K]

AH(fusion) = 11500 cal/mol at 839 K

Cp(l) = 42 cal/mol-K

A-4
^I4^s) The functions are calculated from the molecular constants

and frequencies given by Krasnov et al. [73 KRA/MOR] . These

frequencies satisfied the relations given by Herzberg [45 HER]

better than did those given by Rand [75 RAN].

A-5
Th (c,l)

CP H-H298 S CG-H298)/T

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

7 o 0 • J 0 v . 1 P . 7 A

OK' c/ I c . I c • 010 A7 1 » 1 •*^ .. AO07

500 6. 77 1 342. 1 6.19 -13.51

ov \o OCT 0 <^ If. _ 1 A CI A

700 7.08 2726. 1 8 . 52 -1 4.62

800 7.25 3442. 19. 47 -15.17

900 7.43 41 76. 20.34 -1 5.70

t CA rX flL / . 0 J 47 C 7 . 0111 •—10. 1 A dvOCT

1 \ nn 1 1 tdl^ / . 0 J

^ "7 01 0 e: 1 . 0 / _ 1 A AS

1 am 0 47 7 . eid • 00 — 1 / . 1 4

1 f J 1 <5 • d. J» dti —— 11 7f . ^0J7

1 0 "7 0 1 0^ . J • 0 4

•— 1 a CT 1

1 0 . W I

1 bl^ld 0 . 0 4 ya 33 • OA A A d 4. 44 _ « n >*o

1 600 9.13 9931 . 25.02 -18.81

1 653 9.28 10419. 25.32 -1 9.02

= 870 CAL/MOL ST= .52632 CAL/MOL.K AT 1

1 653 8. 48 1 1289. 25.85 -19.02

1 700 8. 62 1 1 691 . 26.09 -19.21

1 800 8.90 12567. 2 6. 59 -19.61

1 900 9.19 13472. 27.08 -19.99

2000 9. 48 1 440 5. 27. 56 -20.35

2023 9.55 1 4624. 27.66 -20 . 44

HT= 3300 CAL/MOL ST= 1.6312 CAL/MOL.K AT 2023 K

2023 1 1 .00 17924. 29.30 -20.44

2100 1 1 .00 18771

29.71 -20. 77

2200 1 1 .00 19871. 30.22 -21.19

2300 1 1 .00 20971. 30.71 -21 .59

2 400 11.00 22071. 31 .18 -21 .98

2 500 1 1 .00 231 71

31 .62 -22.36

2600 11.00 2427132.06 -22.72

2700 1 1 .00 25371

32. 47 -23.07

2800 11.00 2647132.87 -23. 42

A-6
Th (g)

CP H-HC0) S (6-H298)/T

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

298 4.969 1 48 1 . 2 45. 42 4 -45. 42 4

300 4.9 69 1 490 . 4 45. 454 -45. 425

400 4.982 1987.7 46.885 -45. 620

500 5.039 2488.2 48 .002 -45.988

600 5. 1 71 2998 .0 48 . 9 3

- 46. 404

700 5. 388 3525.3 49 . 743 - 46.824

800 5. 679 40 78. 1 50 . 48 1 -47.236

900 6.024 4662.9 51 . 1 69 -47. 635

1000 6. 398 528 3.9 51 .823 -48.021

1 100 6. 780 59 42.8 52. 451 -48. 39 6

1200 7. 1 54 6639 .

53.057 -48. 759

1 300 7. 509 7373.0 53. 644 -49. 1 12

1 400 7.837 8 1 40 . 5 54.212 -49.457

1 500 8. 1 38 8939.

54. 763 -49. 792

1 600 8. 409 9767.

55.297 -50. 120

1 700 8. 653 10620.

55.81

-50. 440

1800 8.870 1 1 49 6.8 56.31-50. 752

1900 9.063 12393.

56.800 -51 .058

2000 9.235 1 3308.8 5 7.2 70 -51 .357

2100 9.388 1 42 40 . 1 57. 724 -51 . 649

2200 9. 523 1 5185.

58.1 64 -51 .936

2300 9. 642 1 61 44.0 58.590 -52.21

2400 9. 7 46 17113.5 59.003 -52. 490

2 500 9.837 18092.8 59.402 -52. 759

2600 9.915 19080. 5 59. 790 -53.022

2700 9.980 20075.3 60. 1 65 -53.279

2800 10.034 21076.60.529 -53.532

2900 10.077 22081 .8 60.882 -53. 779

3000 10. 109 23091 .2 61.224 -54.022

A-7
ThO (g)

T CP H-H< 0

)

S ( G-H298

CAL/MOL .K CAL/MOL CAL/MOL .K CAL/MOL

298 7.473 2109.0 C '7 '3 C t -57« 351

300 7 . 48 1 21 22.8 d7 • 39 f -57.351

40 0 7.864 2890.8 59 . 60 4 - 57 . 649

500 8 . 1 50 3692 •

61 .391 -58 .225

600 8.353 4518.0 62 • 8 9 6 - 58.88

700 8 . 50 1 5361 .

64*19 5 - 59 . 5 50

800 8 . 621 621 7 . 3 65. 339 - 60 . 20 3

900 8. 732 7085.0 66.361 -60.8 32

1000 8.845 7963.8 67.28 6 - 61 .431

1 1 00 8.966 8854.

68 . 1 3 5 - 62 .003

1200 9.099 9757.

68 .921 -62. 547

1300 9.243 10674.

69. 655 -63.066

1 400 9.395 1 1 606.2 70.345 -63. 561

I 500 9. 552 12553.

70.999 -64.035

1 600 9.712 13516.7 71 • 620 - 64. 490

1700 9.873 1 4496.0 72.21

-64.927

1800 10.031 15491.2 72. 782 -65.348

1900 10.187 16502.2 73.329 -65.754

2000 10.339 1 7 528.

73.855 -66. 1 46

2100 1 0 . 48 7 18569.9 74.363 -66. 525

2200 10.630 19 62 5.

74.855 -66.892

2300 10.767 20695.

75.330 -67.249

2400 10.901 21 779. 1 75.791 -67. 595

2500 1 1 .029 22875.

76.239 -67.932

MOLECULAR WEIGHT= 248.04

MOLECULAR CONSTANTS ARE LISTED AS:

LES/EL# WE*X£WE' YEWE*BE*ALPHAE* DE# MULTIPL I C I TV* V00

1 895. 77 2. 39 0 .33264 1.3020E-3 1.8330E- 7 1 0

2 864. 1 2. 31 0 .32641 .00123 1.8630E-7 2 5305

3 846. 4 2.4 0 .32304 1 .2940E-3 1 .3660E-7 1 1 0 60 1 . 4 8 42. 8 2.18 0 .32497 1.2990E-3 1.9400E-7 2 11129.

5 835. 1 2.39 0 .32246 .00128 1.9310E-7 2 1 4490

6 8 39. 2 2.5 0 .32155 .0013 1.8500E-7 2 1 5946.

7 829. 26 2.3 0 .32309 1.3030E-3 1.9900E-7 1 16320.

8 81 6. 2 2.26 0 .31817 .00124 1.9300E-7 2 1 7998

9 816. 2 2.4 0 .3214 .00124 2.0420E-7 1 18338.

A-8
Th02 (c)

T CP H-H298 S (G-H29(

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOl

298 14.77 0. 1 5.59 -1 5.59

300 1 4.81 27. 1 5.68 -1 5. 59

400 1 6.21 1 58 7. 20. 1 6 -1 6. 19

500 16.96 32 48. 23.86 -1 7.37

600 1 7. 44 49 70. 27.00 -18. 72

700 17.81 6733. 29. 72 -20.10

800 18.11 8 530. 32. 12 -21 . 45

900 18.37 10354. 34.26 -22. 76

1000 18.61 12204. 36.21 -24.01

1 100 18.84 1 40 7 7 . 38.00 -25.20

1200 19.05 1 59 7 1 . 39.65 -26.34

1 300 19.26 1 7887. 41 .18 -27.42

1 400 19. 46 19823. 42. 61 -28 .45

1 500 19. 66 21 779. 43.96 -29. 44

1 600 19.85 23754. 45.24 -30.39

1 700 20.0 4 25749. 46. 45 -31 .30

1800 20.23 27763. 47. 60 -32. 1

1900 20. 42 29796. 48.70 -33.02

2000 20. 61 31847. 49. 75 -33.83

2100 20.80 3391 7. 50. 76 -34. 61

2200 20.98 36006. 51 . 73 -35.37

2300 21.17 381 1 4. 52.67 -36.10

2 400 21 .35 40239. 53.57 -36.81

2 500 21 .53 4238 4. 54. 45 -3 7.49

2600 21 . 72 44546. 55.30 -38. 1

2700 21 .90 46727. 56.12 -38.81

2800 22.08 48927. 56.92 -39.45

A-9
Th02 (g)

T CP H-H(0)

CAL/MOL.K CAL/MOL

298 , 11.317 2921.2

300 11.334 2942.2

400 12.110 4116.9

500 12.621 5355.3

600 12.955 6635.3

700 13.180 7942.7

800 13.336 9268.9

900 13.448 10608.4

1000 13.531 11957.5

1 100 1 3. 59 3 1 331 3.9

1200 1 3. 642 1 4675.

1300 13.680 16041.9

1 400 13.71 1 1 741 1 . 5

1 500 1 3. 736 18783.9

1600 13.757 20158.6

1700 13.774 21535.1

1800 13.788 22913.2

1900 13.801 2 4292.7

2000 13.811 25673.3

2100 13.820 27054.8

2200 1 3.828 28437.

2300 13.835 29820.4

2400 1 3.841 31204.2

2500 13.846 32588.6

2600 13.851 33973.5

2700 13.855 35358.8

2800 13.859 36744.6

2900 13.863 38130.6

3000 13.866 39517.1

FREQ 787 CM-l MULT 1 FREQ 120 CM-l MULT 1 FREQ 735 CM-l MULT 1 MOLECULAR WEIGHT 264.037

SYMMETRY 2

MOMENTS 23.486 88.795 112.281 IN AMU A2

GROUND STATE DEGENERACY 1

S (G-H298)/T

CAL/MOL.K CAL/MOL.K

68 . 701 - 68 . 70 1 68 . 7 7

-68. 701

72. 1 45 -69.1 56

74.906 -70 .0 38

77.239 -71 .0 49

79 .254 -72.080

81 .025 -73.090

82 . 602 - 74.0 61

%J W V w - 74.98 7 85.316 - 7 5.8 68

8 6 . 50

-76. 706

8 7. 59 5 -77. 502

88 . 61

-78 .2 60

89.557 -78.981

ODl . AAA - 79 • 670

91 .278 -80 . 329

92 .0 66 -80 . 9 59

92.812 -81 . 564

93. 520 -82. 1 44

94.194 -82. 702

94.837 -83.239

9 5.452 -83. 757

96.041 -84.256

96. 606 -84.739

9 7 . 1 49 -85.206

97.672 -85.658

98. 1 76 -86.096

98. 662 -86.521

99. 1 32 -86.934

A-10
ThF (g)

CP H-H(0) S (G-H298)/T

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

298 8.28 5 2226.8 61 .471 -61 . 471

300 8.292 2242.

61 .523 -61 . 472

400 8. 573 3086.7 63.951 -61 .80

500 8. 735 3952.8 65.882 -62. 430

600 8.839 48 3 1 . 8 67. 48 5 -63. 1 43

700 8.912 5719.5 68.853 -63.863

800 8.9 68 661 3.

70.047 -64. 563

900 9.01 4 7512.9 71 . 105 -65.232

1000 9.054 841 6. 3 72.057 -65.868

1 100 9.090 9323.

72.922 -66. 470

1200 9. 123 10234.2 73.714 -67.041

1 300 9.155 1 1 1 48 . 1 74. 445 -67. 582

1 400 9.185 12065.

75.124 -68.097

1 500 9.21 5 12985.

75. 758 -68.58 6

1 600 ' 9.244 13908.0 76.353 -69.053

1 700 9.273 1 4833.8 76.91

-69. 498

1800 9.302 1 5762.6 77. 445 -69.925

1900 9. 331 1 6694.2 77.9 48 -70.333

2000 9.361 1 7 628.8 78. 426 -70. 72 5

2100 9. 390 18566.

78.883 -71 .102

2200 9.420 19 506.9 79.320 -71 .465

2300 9. 450 20450.

79.738 -71 .81

2400 9. 481 21397.0 80 . 1 40 -72.1 53

2500 9. 512 22346.

80 .527 -72. 479

MOLECULAR WEIGHT= 251.04

ALPHAE APPROXIMATED AS 2.0386E-3 STATE 1 DE APPROXIMATED AS 4( BE) t 3/ ( WE ) t 2 1.9931E-7 STATE 1 MOLECULAR CONSTANTS ARE LISTED AS

LEVEL* WE*XEWE* YEWE* BE* ALPHAE* DE* MULTIPLI CI TY* V00

I 489 4 0 .2284 2.0386E-3 1 .9931E-7 4 0

A-11
ThF2 (g)

TV CP H-H(0) S (G-H298)/T

i CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

298 12.527 , 31 1 1 . 7 70. 533 -70. 533

300 12. 541 31 34.9 70. 61-70.534

400 13.064 4418.0 74.299 -71 .033

500 13.343 5739.77.247 -71.991

600 13.50 6 7082.9 79.69 5 -73.077

700 13.609 8 439.0 81 .78 5 -74.1 75

800 13.677 9803.8 3.60 7 -75.243

900 13.725 11173.7 85.221 -76.263

1000 13.7 59 12548.0 86.669 -77.233

1100 13.785 13925.3 87.982 -78.1 51

1200 13.805 15304.8 89. 182 -79.021

1300 1 3.820 1 6686.90.288 -79.846

1 400 1 3.832 18068.

91 .312 -80.629

1 500 1 3 . 8 42 19452.5 92.267 -81 .373

1 600 1 3.8 50 20837.

93.1 61 -82.082

1 700 13.857 22222.5 94.001 -82.759

1800 1 3.863 23608.94. 793 -83. 406

1900 13.8 68 24995.1 9 5. 542 -84.025

2000 13.872 26382.0 96.254 -84.619

2100 13.875 27769.4 96.931 -85.189

2200 13.878 29157.1 97.576 -85.737

2300 1 3.881 30545.

98.193 -86.266

2400 13.884 31933.3 98.784 -86.775

2500 1 3.886 33321 .8 99.351 -87.267

FREQ 447 CM-1 MULT 1 FREQ 130 CM- I MULT 1 FREQ 483 CM-1 MULT 1 MOLECULAR WEIGHT 270.04

SYMMETRY 2

MOMENTS 137.64 25.717 163.36 IN AMU A2

GROUND STATE DEGENERACY 1

A-12
ThF3 (g)

T CP H-H(0)

CAL/MOL.K CAL/MOL

298 17.519 4025.6

300 17.542 40 58.0

400 18.431 58 61 .6

500 18.906 7730.8

600 19.184 9636.5

700 19.358 11564.2

800 19. 475 1 3506.2

900 19.556 15458.0

1000 19.614 17416.6

1100 19.658 19380.3

1200 19.692 21347.9

1300 19.718 23318.5

1400 19.739 25291.4

1500 19.756 27266.1

1600 19.770 29242.5

1700 19.781 31220.0

1800 19.791 33198.7

1900 19.799 35178.2

2000 19.806 37158.5

2100 19.812 39139.4

2200 19.818 41120.9

2300 19.822 43102.9

2400 19.826 45085.4

2500 19.830 47068.2

FREQ 480 CM-1 MULT 1 FREQ 140 CM-1 MULT 1 FREQ 484 CM-1 MULT 2

FREQ 1 56 CM- 1 MULT 2

MOLECULAR WEIGHT 289.033

SYMMETRY 3

MOMENTS 133.691 133.691 224.87 IN

GROUND STATE DEGENERACY 6

S (G-H298)/T

CAL/MOL.K CAL/MOL

81 .072 -81 .072

81.181 -81 .072

86.363 -81 . 773

90.532 -83.122

94.006 -84.654

96.977 -86.208

99.570 -87. 71 9

101 .8 69 -89. 1 66

103.932 -90.541

105.804 -91 .845

107.51

-93.081

1 09.093 -94.253

1 10. 555 -95.365

111.918 -96. 424

1 13.193 -97. 433

1 1 4.392 -98.395

1 1 5.523 -99.31

1 1 6. 593 -100. 1 97

1 1 7.609 -101 .043

1 18. 576 -101 .855

1 1 9 . 49 7 -102.636

1 20.378 -103.388

121 .222 -104.1 1

122.032 -104.81

AMU A2

A-13
ThF. (c,]

CP

CAL/MOL .K

H-H298

CAL/MOL CAL/MOL .K

(G-H298)/T

CAL/MOL.

298

300

Aa0

500

600

700

800

900

1000

I 100

1 200

1 300

1 38 3

26.42

26. 47

28. 1 3

29.00

29. 57

29.99

30.33

30. 63

30.90

31 . 1 5

31 .39

31 . 62

31 .81

0.

49.

2789.

5649.

8579.

1 1 557.

1 4574.

1 7 622.

20699.

23802.

26929.

30080.

32712.

33.95

34. 1 1 41 .98

48. 3 6

5 3. 70

58.29

62.32

65.91

69. 1 5

72.1 1 74.83

77.35

79.32

-33.95

-33.95

-35.01

-37.07

-39. 41

-41 . 78

-44. 10

-46.33

-48.45

-50.47

-52.39

-54.21

-55.66

HT= 10000 CAL/MOL

1 383

1 400

1 500

32.00

32.00

32.00

ST= 7.2307 CAL/MOL.

42712.

43256.

46456.

86. 55

86.94

89. 1 4

AT 138 3 K

-55.66

-56.04

-58. 1

A- 14
ThF4 (g)

T CP H-H(0) S CG-H298

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL

298 22.235 4901 .

81 .667 -81 . 667

300 22.269 49 42 . 6 81 .805 -81 . 668

400 23. 598 7243.0 88 . 41

-82.560

500 24. 324 9642.

93. 765 -84.283

600 24. 753 12098.0 98 .2 40 -86.246

700 25.025 14587.9 102.078 -88.240

800 25.207 1 7100.0 105. 432 -90.184

900 25. 334 19627.4 108.409 -92.047

1000 25. 426 221 65.

1 1 1 .083 -93.819

1 100 25. 496 24712.0 113.510 -95.500

1 200 25. 548 27264.1 1 5. 731 -97.095

1 300 25. 590 29821 .3 1 1 7.777 -98.608

1 400 25. 623 32382.0 119. 675 -100.046

1 500 25. 650 34945.

121 .444 -101 . 41

1 600 25.672 3751 1 .8 123.100 -102.719

1 700 25.690 400 79.9 124.657 -103.964

1800 25. 705 42649.7 126.126 -105. 1 55

1900 25. 718 45220.9 127.51

-106.295

2000 25. 730 47793.3 1 28 .835 -107.390

2100 25. 739 50366.8 1 30.091 -108.441

2200 25. 747 529 41 . 1 1 31 .289 -109.452

2300 25. 755 5551 6.2 1 32.433 -1 10.427

2400 25. 761 58092.0 1 33. 530 -111 .367

2500 25. 767 60 6 68 . 4 1 34.581 -1 12.274

FREQ 555 CM-1 MULT 1 FHEQ 145 CM-1 MULT 2

FREQ 51 5 CM-1 MULT 3

FREQ 155 CM-1 MULT 3

MOLECULAR WEIGHT 308.0 3

SYMMETRY 12

MOMENTS 232.01 232.01 232.01 IN AMU A2

GROUND STATE DEGENERACY 1

A-15
ThCl (g)

t

T1 CP c3 V 13 n ^ 7 o

wrni^^ iJL/w *r\

RCJ • 7f 1 £P oT *i3 ^1 . 01 . 10 O M . O ^- J — A Z . "JP O • CIO p T la - t A^ . 179 — A ^ . "JP ^ o • O O *J TP ^Oi . (A A A . 9 1 01 — f^A. O M . O AO07

O * 7 •J 1 ^ 1 >l 1 P AROO .. RO 9R7 o — A^ . IP "i 6f)0 U C 97 .• MK/ 1 P^ 701 . ST> - AO AO .. 01ft/ S9J 7

7 • «/ O 1 J7 *U . C 7r 1 -• 9PR 7 & O — A A . R^C^

O V C/ 9 . 1 PI ^ OO D i . O - A7 . R

7 • 1 H M 7 7 01 f r O M • W 7 id . P 1 S OO • C 1l/ J

I VK/ XJ 97 .• 1I RO OT RO AROI OO - >i K/ * 1 7S . 1 RPI OO . O J J

9 . PPCI 9 AOIOI - 7 A . 01 A _ OCO7 .. ^MOOAR

1200 • & C/ 9 • ? 5R 1 01 'iP ^. ^ 7 A . R S9 » 701 . 01 SI

11 O'^00 ft/ K/ 97 .• P9^ 7 SJ 1 1 ^SP . 01 7 7 , A0 1 • f * OIL/ I - 70 . 60P

1 MIL/ IL/ 7 • J J J 1 P "^R 1 • ^ 7Rf O .. P9C1 & 7 C/ 9 . T7P 7R .

f O . 7 o J

1 u t> 7 • *4 1 1

1 ^P 7 . R - 7Pf ^ .. 11 00ft/ ft/ 7 • 1 J 1

i ^oaa

1 J^vY) . Q7 ROi Oc/ .. 1 1 01 1 1 10 - 7P . SST

7 • ^7<i lot 4o • I ROI A ^ 1 olo . OJM — 70 OR 7

1 900 9. 534 1 7099.

81 . 1 64 -73. 403

2000 9.577 18054.9 81 . 653 -73.802

2100 9. 620 1901 4.

82.1 19 -74.186

2200 9 . 665 19979.0 82. 566 -74. 555

2300 9.710 20947.

82.995 -74.91 1 2400 9. 757 21 921 .

83. 408 -75.255

2500 9.804 22899.

83.805 -75.587

MOLECULAR WEIGHT= 267.49

ALPHAE APPROXIMATED AS 6.0992E-4 STATE 1 DE APPROXIMATED AS 4( BE) t 3/ ( WE ) » 2 3.3206E-8 STATE 1 MOLECULAR CONSTANTS ARE LISTED AS

LEVEL* WE. XEWE» YEWE* BE* ALPHAE* DE* MUL TIPL I CI TY* V00

1 292 2 0 .08912 6.0992E-4 3.3206E-8 4 0

A-16
ThCl^ (g)

T CP H-H(0) S (G-H298

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL

298 13.212 3359.9 75. 766 -75. 766

300 1 3.220 3384.

7 5 . 8 48 -75.766

400 1 3 . 50 4 4722.

79.695 -76.289

500 1 3. 645 6080.

82.725 -77.284

600 13. 724 7 449.85.220 -78.40 5

700 13. 772 8824.87.340 -79.534

800 1 3.804 10203.2 89.181 -80. 627

900 1 3.826 1 1 584.8 90.808 -81 . 669

1000 13.842 12968.2 92.266 -82.658

1 100 1 3.854 1 4353.0 93.586 -83. 592

1200 1 3.863 1 5738.9 94.792 -84. 476

1 300 1 3.870 1 7125.

95.901 -85.312

1 AQfd 13.875 18512.7 96.929 -86.106

1 500 1 3.880 19900.

97.887 -86.860

1 600 1 3.883 21288.6 98. 783 -87.577

1 700 13.886 22677.1 99.625 -88.262

1800 13.889 24065.9 100.418 -88.91

1900 1 3.891 25454.9 101 . 1 69 -89.540

2000 13.893 26844.

101 .882 -90. 1 40

2100 13.895 28233.

102.560 -90. 71

2200 13.896 29623.0 103.206 -91 .268

2300 13.897 31012.

103.824 -91 .801

2400 13.898 32 402.5 104.41

-92.31

2500 1 3.899 33792.3 104.983 -92.810

FREQ 308 CM-1 MULT 1 FREQ 84 CM-1 MULT 1 FREQ 31 5 CM-1 MULT 1 MOLECULAR WEIGHT 302.944

SYMMETRY 2

MOMENTS 372.8 62.09 434.89 IN AMU A2

GROUND STATE DEGENERACY 1

A-17
T11C13 (g)

CP H-H ( 0

)

S C G-H298

CAL /MOL CAL/MOL CAL/MOL .K CAL/MOL

298 18*643 4466 .

88 . 331 -88.331

300 IB • 656 450 1.2 88 . 447 -88 . 332

400 1 9 • 1 bb 639 4.

93.891 -89.070

500 1 9 • 40 3 8324.

98.195 -90 . 480

600 1 9 • 542 102 11 .9 101 .746 -92.0 fv

700 19* 628 1 2230 .

% A. —IXC 104.765 - V 3 . 6 / 4

800 1 9 • 63 4 1419 6.5 10 7. 390

900 1 9 • 723 16166.9 109.71

— 76. / 1 W

M r% Hk nt 1 000 1 Q TCI 1 7 • f 51 1 8 1 40 . 7

4 t 4 *T n /I 111.790 — Vb . 1 I 0

1 1 00 1 9 • 7 72 20 116.9 113.674 -99 . 446

• r\ 1 200 1 9 • 78 7 2209 4.9 1 1 5 . 395 -100. 70 5

1 300 1 9 • 8 0 0 2 40 7 4 » 2 1 1 6 . 9 79 -101.896

1 400 19.810 260 54.

1 18.447 -103.027

1 500 1 9 • 8 1 8 28036 .119.814 -10 4.101

1 600 19.824 30018.2 121 .093 -105. 123

I 700 19.8 30 32000.9 1 22.295 -106.098

1800 19.834 33984.

123.429 -107.0 33

1900 19.8 38 35967.

124.501 -107.922

2000 19.841 37951 .

125.519 -108. 776

2100 19.844 39936.0 126.487 -109.597

2200 19.847 41920.

127. 410 -1 10.38 6

2300 1 9 . 8 49 43905.3 128.292 -1 1 1 . 1 45

2 400 19.851 45890.2 129.1 37 -1 1 1 .877

2500 19.8 52 47875.4 129.9 48 -1 12.584

FREQ 320 CM-1 MULT 1 FREQ 100 CM-1 MULT 1 FREQ 333 CM-1 MULT 2

FREQ 105 CM-1 MULT 2

MOLECULAR WEIGHT 338.397

SYMMETRY 3

MOMENTS 353.677 353.677 609.06 IN AMU A2

GROUND STATE DEGENERACY 6

A- 18
ThCl^ (c,l)

T CP H-H298 S (G-H298)/T

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

298 28.75 0. 45.50 -45.50

300 28.78 53. 45.68 -45.50

400 30.06 3000. 54.15 -46.65

500 30.9 4 60 52. 60.95 -48.8 5

600 31.68 9184. 66.66 -51.36

679 32.21 11708. 70.61 -53.37

riT= 1200 CAL/MOL ST= 1.7673 CAL/MOL.K AT 679 K

679 32.21 12908. 72.38 -53.37

700 32.34 13585. 73.36 -53.96

800 32.97 16851. 77.72 -56.66

900 33.57 20179. 81.64 -59.22

1000 34.16 23565. 85.21 -61.64

1042 34.41 25006. 86.62 -62.62

HT= 14690 CAL/MOL ST= 14.098 CAL/MOL.K AT 1 0 42 K

1042 40.00 39696. 100.72 -62.62

1100 40.00 42016. 102.88 -64.69

1200 40.00 46016. 106.36 -68.02

1300 40.00 50016. 109.57 -71.09

1400 40.00 54016. 112.53 -73.95

1500 40.00 58016. 115.29 -76.61

A-19
ThCl^ (g)

298

300

400

500

600

700

800

900

1000

1 100

1200

1 300

1 400

1 500

1 600

1 700

1800

1900

2000

2100

2200

2300

2 400

2500

CP H-H C 0

)

S C 6-H298

CAL /MOL • K CAL /^MOL CAL /MOL .K CAL/MOL

24» 273 58 1 6. 7 95.000

24» 290 CO ^ % £. 58 6 1 . 6

o c ten 9 5 . 1 50 -9 5. 00

24« 922 8 326.2 102.236 -95.963

2 5*237 10835.8 10 7.835 -97.797

25* 41 4 1 3369 .

112. 453 -99 .866

2 5. 523 1 59 1 6. 3 1 1 6. 380 101 .952

25.59 4 18A72»A 119. 793 1 03.9 73

25. 644 21034.5 122.810 105. 902

2 5.679 23600 •125.51

107. 730

25.706 26170.0 1 27.963 109 • 460

25.726 r 28741 . 7 1 30 .201 1 1 1 .096

25. 7 42 31 31 5. 1 1 32.260 1 12. 646

25. 754 33889.9 1 34. 1 69 1 1 4. 1 1 6

25.764 36465.9 1 35.946 115.513

25.773 39042.8 1 3 7. 609 1 1 6.843

25.780 41 620.

1 39. 1 72 1 18. M 1 25.78 5 . 441 98.

1 40 • 645 1 19.322

25. 790 46777.4 1 42.039 120. 481

25. 794 49 356.

1 43.362 121 .592

25. 798 51936.3 1 44.621 122. 659

25.801 5451 6.3 1 45.821 123.685

25.804 57096.1 46.9 68 124.673

25.806 59677.

1 48 .067 125.625

25.808 62257.8 1 49 . 1 20 126.544

FREQ 300 CM-1 MULT 1 FREQ 70 CM-1 MULT 2

FREQ 335 CM-1 MULT 3

FREQ 75 CM-1 MULT 3

MOLECULAR WEIGHT 373.85

SYMMETRY 12

MOMENTS 629.31 629.31

GROUND STATE DEGENERACY

629.31

1 IN AMU A2

A-20
ThBr (g)

T CP H-H(0 ) s ( G-H298

CAL/MOL.K CAL/MOL CAL/MOL .K CAL/MOL

298 8.9 52 2452.9 67 . 1 53 -67.153

300 8.955 2469 .67 .209 -67. I 53

400 9.0 72 3371 .2 69 .801 -67. 506

500 9. 1 64 428 3.

71 .835 -68 . 1 75

600 9.2 49 520 3.8 73.513 -68.928

700 9. 332 61 32.8 74.943 -69. 686

800 9. 41 6 7070.2 76.1 93 -70. 421

900 9 . 50 4 801 6.2 77. 305 -71 . 1 24

1 000 9 . 59 5 8971 .1 78.308 -71 . 790

1 1 00 9. 691 9935.

79.224 -72. 422

1 200 9. 790 10909.

80 .069 - 73.021

1 300 9.894 1 1893.

80.852 -73. 590

1 400 10.003 12888.

81 . 585 -74. 1 31

1 500 10.116 1 3894. 4 82.274 -74. 647

1 600 10.234 1 49 1 1 • 9 82.926 -75. 1 39

1 700 10.357 1 5941 . 4 83. 544 -75. 609

1800 1 0 . 48 5 1 6983.

84. 1 33 -76.060

1900 10.6118038.

84.696 -7 6. 49 3

2000 10. 754 19107.0 85.237 -76.910

2100 10.895 20189.4 85.757 -77.31

2200 1 1 . 0 42 21 286.

8 6.2 58 -7 7. 69 7 2300 1 1 . 193 22398.0 86. 743 -78.0 71

2 400 1 1 . 349 23525.87.212 -78. 432

2500 1 1 . 510 24668 .0 87.668 -78. 782

MOLECULAR WEIGHT= 311.94

ALPHAE APPROXIMATED AS 3.0458E-4 STATE 1 DE APPROXIMATED AS 4( BE) t 3/ ( WE) t 2 7.0029E-9 STATE 1 MOLECULAR CONSTANTS ARE LISTED AS:

LEVEL. WE#XEWE* YEWE#BE* ALPHAE* DE* MULTIPLI CI TY* V00

1 194 2 0 .04039 3.0458E-4 7.0029E-9 4 0

A-21
T - CP H-H ( 0

)

S C G-H298

C AL /MOL •CAL /MOL CAL /MOL .

CAL /MOL

O f!> C7 IT Q Q 1 J • J D 7 T 5^ Cl /: T J J D O . / 81 .00 9 -8 1. 009

O .'H 1 J • J O J

T R O 1 D 81 .09 3

11 "7 11 47 4 O . D 8 b .0 1 8 -8 1. 543

IT TCI 1 J • / O 1 ^ T O 1 A o Jci 1.4 88 .08 5 -82

DD6

to a o f5i T T ni 1 ^ 90 .602 -o 3 •

1 J • o 44 y io tt 4 . 9 •o 4« o 3 / lH O k5 IT D 1 Ic3 4 / 0 • I 9 4. 58 4 •o t> • 9 42

Q iT* iT* y o fc3 IT o n Oi

1 1 o 3 6 . 6 9 6.21 / o z one

1 ukJ k3 1 3 • o 7 7 1 32 44.0 9 7 . 6 78 -87.991

1 1 e)0 1 3 • 8 8 3 1 4632 .

99.00 1 •OD 933

1200 1 3 • 88 7 1 6020 . 6 100.210 _ O Q O O O

1 300 1 3*891 1 7 43 9 . 5 101.321 - Q Z Z C y fe^ • 6ob

1 400 1 3» 89 3 18 798.7 102.351 -9 1. 464

1 50 0 1 3 • 8 9 6 20188.1 1 0 3 . 309 - 92 . 222

1 600 1 3 • 8 9 7 21 577.8 10 4.206 -92.9 43

1 700 1 3*899 229 67 . 6 1 0 5 .0 49 -93. 631

1800 13*900 24357 .

1 0 5 . 8 43 -94.28

19 0 0 13.901 257 47.6 10 6.595 -94.91

2000 13.902 27137.8 107.308 -95.51

21 00 13.903 28528 .0 107.986 -96.095

2200 13.903 2991 8 . 3 108.633 -96. 650

2 300 13.90 4 31308.7 109.251 -97. 185

2 400 13.904 32699.1 109.843 -97. 700

2500 13.905 34089 .

1 10.410 -98. 1 97

FREQ 196 CM-1 MULT 1 FREQ 61 CM-1 MJLT 1 FREQ 232 CM-1 MULT 1

' MOLECULAR WEIGHT 391.856

SYMMETRY 2

MOMENTS 123.221 956.989 1080.21 IN AMU A2

GROUND STATE DEGENERACY 1

A-22
ThBr3 (g)

T CP H-H(0) S (G-H298

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL

298 19.311 4888. 1 96.829 -96.829

300 19. 31

4923.9 9 6 . 9 49 -96.830

400 19. 553 68 69.0 102.543 -97.591

500 19. 666 8830.1 06.920 -99.035

600 19. 728 10800.1 10.51

-100.657

700 19. 766 12775.

1 1 3.555 -102.288

800 19. 790 1 4753.

1 1 6.196 -103.865

900 19.807 16733.2 1 18. 528 -105.367

1000 19.820 18714.

120.61

-106. 789

1 100 19.829 20697.0 122.505 -108. 1 34

1200 19.835 22680.2 124.231 - 109 . 40 4

1 300 19.841 24664.

125.819 - 1 1 0 . 60 7

1 400 19.845 26648 .1 27.289 -111 .746

1 500 1 9 . 8 48 28633.0 1 28. 659 -1 12.829

1 600 19.851 30618.0 129.9 40 -1 1 3.859

1 700 19.854 32 60 3. 3 1 31 . 1 43 - 1 1 4 . 8 40

1800 19.856 34588.1 32.278 -1 1 5. 778

1900 19.857 36574.

1 33.352 -1 1 6.675

2000 19.8 59 38 560.2 1 34.370 -1 1 7.534

2100 19.8 60 40546.

1 35.339 -1 18.359

2200 19.861 42 532.1 36.263 -1 19.1 52

2300 19.8 62 44518.3 1 37. 1 46 -119.915

2 400 19.863 46504.5 1 37.991 -120.651

2 500 19.863 48 490 .8 1 38 .802 -121 .361

FREQ 200 CM-1 MULT 1 FREQ 68 CM-1 MULT 1 FREQ 223 CM-1 MULT 2

FREQ 66 CM-1 MULT 2

MOLECULAR WEIGHT 471.765

SYMMETRY 3

MOMENTS 872.26 872.26 1563.51 IN AMU A2

GROUND STATE DEGENERACY 6

A-23
ThBr^ (c,l)

CP H-H298 S (G-H298)/T

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL.K

298 29.92 0. 54.50 -54.50

300 29.95 55. 54.69 -54.50

400 31.02 3109. 63.46 -55.69

500 31.71 6247. 70.46 -57.97

600 32.25 9446. 76.29 -60.55

693 32.69 12466. 80.97 -62.98

HT= 1000 CAL/MOL ST= 1 . 443 CAL/MOL .K AT 693 K

69 3

700

800

900

9 52

32. 69

32.72

33. 1 5

33. 56

33. 77

1 3466.

1 3695.

1 6989

20325.

22075.

82. 42

82. 74

87.14

91.07

92.96

62.98

63. 1 8

65.91

68. 49

69. 77

HT= 7000 CAL/MOL ST= 7.3529 CAL/MOL.K AT 952 K

9 52

1 000

1 100

1200

1 300

1 400

1 500

41

41

41

41

41

41

41

00

00

00

00

.00

'00

>00

29075.

31 043.

351 43.

39243.

43343.

47443.

51 543.

100.

102.

106.

109.

1 1 3.

1 1 6. 118.

31

33

24

81

09

1 3

95

69. 77

71 .29

74.29

•77.10

•79.75

•82.24

•84. 59

A-24
ThBr^ (g)

T CP H-H ( 0

)

S < G-H298

CAL/MOL •K CAL/MOL CAL /MOL .K CAL/MOL

298 / r\ rj fx b2.2.^ .0 1 02 . 720 • 1 13 2 • 720

300 o c m 1 62 1 A* A 1 02 .8 75 -102. 720

400 2d» 39 6 8800 .0 1 1 0 . 1 39 - 1 0 3 . 709

c fM n

1 1 3 48 . 2 1 1 5.824 - 1 0 5 . 58 4

600 25* 636 1 3908 . 0 1 20 . 49 1 - 1 0 7 • 69 1 700 2 5« 688 1 6474.

124. 447 -109. 809

800 2 5. 722 1 90 45.0 12 7.879 - 1 1 1 . 8 bo

900 25. 745 21618.4 1 30 .91

- 1 1 3.8 1

I 000 2 5.7 62 241 93.1 33 . 62 4 - 1 1 5. 658

1 1 00 25.774 26770.1 36.080 - 1 1 7 • 40 5

1 200 25. 783 29348 .

1 38 . 323 - 1 19.0 56

1 300 25. 791 31927.2 1 40 . 38 7 - 1 20 . 61

1 400 25. 797 34506.

1 42 .298 - 1 22 .099

1 500 25.801 37086.5 1 44.078 - 1 2 3 . 50 6

1 600 25.805 39666.8 1 45. 744 -124.844

1 700 25.808 42247.

147.308 -126. 120

1800 25.81 1 44828 .

1 48. 78 3 -127.339

1900 25.813 47 409. 7 1 50.1 79 -128.50 4

2000 25.81

49991 . 1 1 51 .503 -129.622

2100 25.8152572.1 52. 763 -130.69 4

2200 25.818 551 54.5 1 53.964 -131 .72 4

2300 25.820 57736.1 55.1 1

-1 32. 71

2400 25.821 60318.1 56.210 -1 33. 673

2500 25.822 62900. 6 1 57.264 -1 34.595

FREQ 205 CM-1 MULT 1 FREQ 58 CM-1 MULT 2

FREQ 220 CM-1 MULT 3

FREQ 72 CM-1 MULT 3

MOLECULAR WEIGHT 551.654

SYMMETRY 12

MOMENTS 1576.4 1576.4 1576.4 IN AMU A2

GROUND STATE DEGENERACY I

A-25
Thl (g)

T CP H-H(0) S ( G-H298:

CAL/MOL .K CAL/MOL CAL/MOL .K CAL/MOL.

298 8.980 249 4.2 68 . 9 50 - 68 . 9 50

300 8.982 2510.8 69 .006 -68 .950

400 9.066 341 3.

71 . 602 -69. 303

500 9.135 4323.5 73. 632 -69.973

600 9. 199 5240.2 75. 302 - 70 . 72 5

700 9.2 62 61 63.2 76.724 -71 .482

800 9.327 7092. 7 77.963 -72.21

900 9.39 4 8028. 7 79.064 -72.91

1000 9.464 8971 .80.056 - 73. 578

1 100 9. 536 9921 . 5 80.959 -74.207

1200 9.611 108 78.9 81 . 789 - 74.802

1300 9. 690 11843.9 82.559 -75.367

1 400 9.772 12817.0 83.277 -75.904

1 500 9.856 13798.3 83.951 -76. 41

1 600 9. 944 14788.3 84.586 -76.902

1 700 10.036 1 5787.3 85.188 -77.368

1800 10.130 1 6795.85.760 -77o81

1900 10.228 17813.4 8 6.30 5 -78.242

2000 10. 329 18841 .2 86.827 -78. 654

2100 10. 433 19879.

87.328 -79.050

2200 10.541 20927.9 87.810 -79.431

2300 10. 651 21 987.88 .275 -79. 799

2 400 10. 765 230 58. 3 88. 724 -80. 1 55

2500 10.883 241 40. 7 89.158 -80. 500

MOLECULAR WEIGHT= 358.94

ALPHAE APPROXIMATED AS 1.3447E-4 STATE 1 DE APPROXIMATED AS 4( BE) t 3/( WE) t2 2.8410E-9 STATE 1 MOLECULAR CONSTANTS ARE LISTED AS:

LEVEL* WE#XEWE* YEWE* BE* ALPHAE* DE* MULTIPLI CI TY* V00

1 1 51 1 0 .0253 1 .3447E-4 2.8410E-9 4 0

A-26
Thl2 (g)

T CP H-H(0> S ( G-H298

CAL/MOL.K CAL/MOL CAL/MOL.K CAL/MOL

298 13.713 3691 •

84.960 -84.960

300 13.716 371 6.

85.045 -84.961

^00 1 3. 799 5092.8 89.004 -85.500

500 1 3.839 6475.0 92.088 -86. 520

600 1 3.860 7860.0 94. 61 3 -87. 665

700 13.874 9246.8 96. 751 -88.81

800 13.882 10634.

98 . 60 4 -89.925

900 13.888 12023.

100.239 -90.982

1000 1 3.892 1 3412.101 . 703 -91 .982

1 100 1 3.895 1 4801 .5 103.027 -92.927

1200 1 3.898 16191 .2 104.236 -93.820

1 300 1 3.900 1 7581 .0 105.349 -94. 664

1 400 1 3.901 18971 .1 106.379 -95.465

1 500 1 3.902 20361 .2 107.338 -96.225

1 600 1 3.903 21 751 .

108.235 -96.948

1 700 1 3.904 231 41 .9 109.078 -97. 637

1800 13.905 24532.3 109.873 -98.295

1900 1 3.905 25922.8 1 10.62 5 -98.924

2000 1 3.906 2731 3.3 1 1 1 .338 -99.527

2100 13.906 28703.9 112.016 -100. 106

2200 13.906 30094.5 1 12. 663 -100. 662

2300 1 3.907 31 485.2 1 1 3.282 -101.197

2400 13.907 32875.9 1 1 3.873 -101.713

2500 1 3.907 34266.

1 1 4. 441 -102.21

FREQ 140 CM-1 MULT 1 FREQ 45 CM-1 MULT 1 FREQ 176 CM-1 MULT 1 MOLECULAR WEIGHT 48 5.847

SYMMETRY 2

MOMENTS 182.08 1753.3 1935.38 IN AMU A2

GROUND STATE DEGENERACY 1

A-27
Thl3 (g)

T CP H-H( 0

)

CAL /MOL •

CAL/MOL

298 1 9 • 550 5117.7

300 1 9 • 553 51 53.

400 1 9 • 690 7117.0

500 1 9 • 7 55 9089 .

600 1 9 • 790 110 67.1

700 19.812 1 30 47 .

O nt n 800 1 9 •826 1 5029 •

Q CM nk 900 19.835 1 701 2.

1 000 1 9 . 8 42 18996.2

1100 19.8 47 20980 .

1 200 19.8 51 229 65.7

1 300 19.854 2 49 51 .0

1 400 19.857 26936.

1 500 1 9 .8 59 28922 .

I 600 19.8 60 30908.2

1 700 19.862 32894. 3

1800 19.863 34880.

1900 19.864 36866.8

2000 19.864 38853.2

2100 19.865 40839.

2200 19.866 42826.2

2300 19.866 44812.8

2400 19.867 46799.

2 500 19.867 48786. 1 FREQ 144 CM-1 MULT 1 FREQ 53 CM-1 MULT 1 FREQ 1 70 CM-1 MULT 2

FREQ 48 CM-1 MULT 2

MOLECULAR WEIGHT 612.751

SYMMETRY 3

MOMENTS 1559.54 1559.94 2864.51 IN AMU A2

GROUND STATE DEGENERACY 6

S (G-H298)/T

CAL/MOL.K CAL/MOL.K

102.733 - 1 02 • 733

102.8 54 -102. 734

1 08 . 501 - 1 03. 50 3

1 1 2 .902 - 104.959

1 1 6. 508 - 1 06. 592

1 1 9 . 5 60 -108.232

1 22 .20 7 -109.81

1 24. 542 - 1 I 1 . 326

126. 633 -1 12.754

1 28 . 52 4 -114.103

1 30.251 -1 1 5.378

1 3 1 . 8 40 -11 6.584

1 33.312 -1 1 7.727

1 34. 682 -118.812

1 35.963 -1 1 9.844

1 37. 1 67 -120.828

1 38.30 3 -121 . 768

1 39.377 -122.667

1 40.39 6 -123.528

1 41 .365 -124.354

1 42.289 -125. 1 49

1 43. 1 72 -125.91

1 44.01

-126.650

1 44.828 -127.361

A-28
Thl^ (c,l)

CP

CAU/MOL.K

H-H298

CAL/MOL CAU/MOL.K

(G-H298)/T

CAL/MOL.

298

300

400

500

600

700

800

839

30.2 7 30. 30

31

31

32

96

32. 45

32.8 7 33.25

33. 39

0.

56.

31 42.

6308.

9530.

12796.

1 6102.

1 7 402.

61 .00

61.19

70.06

77.12

82.99

88.03

92. 44

94.03

61 .00

61 .00

62.20

64.50

67. 1 1 69. 75

72.31

73.29

= 1 1 500 CAL/MOL ST= 13.707 CAL/MOL.

AT 839

839 42.00 28902. 107.73 -73.29

900 42.00 31 464. 1 1 0 . 68 -75. 72

1000 42.00 35664. 1 1 5. 11 - 79 . 44

1 100 42.00 39864. 119.11 -82.87

1200 42.00 44064. 122. 76 -86.04

1 300 42.00 48264. 126. 1

-89.00

1 400 42.00 52464. 1 29.24 -91 . 76

1 500 42.00 56664. 1 32. 1

-94.36

A-29
NBS-IMA (REV. 7.711

U.S. DtPT. OF COMM. BIBLIOGRAPHIC DATA

SHEET

1. I'llHMCA l lON OK Kl-.l'OK 1 NO. NBSIR 77-1300

2. Gov't Accession

No.

3. Recipient's Accession No.

4. Til I.I-; AND SUM 1 I I I. 1. A COMPUTER-ASSISTED EVALUATION OF THE THERMOCHEMICAL

DATA OF THE COMPOUNDS OF THORIUM

5. Publication Date

6. Performing Organization Code

7. AUTHOR(S)

D. D. Wagman, R. H. Schumm and V. B. Parker

8. Performing Organ. Report No.

9. PERFORMING ORGANIZATION NAME AND ADDRESS

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

10. Project/Task/Work Unit No.

11. Contract/Grant No.

12. Sponsoring Organization Name and Complete Address (Street, City, Stale, ZIP) 13. Type of Report & Period Covered

14. Sponsoring Agency Code

15. SUPPLEMENTARY NOTES

16. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bibliograpfiy or literature survey, mention it tiere.)

Selected values are given for the thermochemical properties of the compounds

of thorium. They are obtained from a computer-assisted least sums-least squares

approach to the evaluation of thermodynamic data networks. The properties given,

where data are available, are enthalpy of formation, Gibbs energy of formation,

and entropy at 298.15 K (AHf°(298), AGf°(298), and S°(298)). The values are consistent with the CODATA Key Values for Thermodynamics. The reaction catalog

from which this self consistent set of values is generated is given with a statistical analysis. Some thermal functions are also given, as well as detailed comments when necessary.

17. KEY WORDS (six to twelve entries; alphabetical order;. capUalize only the first tetter of the first key word unless a proper nmme; separated by semicolons) u3.ta evaiuatloA,

gj^j-j^^j^py . entropy; Gibbs energy;

thermochemical data networks; thermochemical tables; thorium compounds

18. /AVAILABILITY

^ Unlimited

1 1 For Official Distribution. Do Not Release to NTIS

1 1 Order From Sup. of Doc, U.S. Government Printing Office Washineton. D.C. 20402. SD Cat. No. Cn

1 Order From National Technical Information Service (NTIS)

Springfield, Virginia 22IS1

19. SECURITY CLASS

(THIS REPORT)

UNCL ASSIFIED

21. NO. OF PAGES

93

20. SECURITY CLASS

(THIS PAGE)

UNCLASSIFIED

22. Price

$6.00

USCOMM.DC 2S042-P74