p.1 

RCRA Box 1883 

Prepped by Ollie Stewart 

Document Number: 

90) ll-B-252 

Docket Number: 

A-90-19 

Printed 12/3/200810:42:16 AM Sheet 90 of 171 
P.2 

A-90-19 

ll-B-252 

TO: Docket /}- cYC-/ ci 

FROM: Bennett King 

DATE: January 17, 1992 

SUBJECT: Product Process Summary Form Discrepancies 

The purpose of this memo is to provide dbcumentation of 

discrepancies to the PPS (Product-Process Summary) forms found as 

part of an internal quality assurance audit. The printout enclosed 

as Attachment 1 should be used when reading the PPS forms. 

Attachment 1 gives correct values for reaction types and process 

vents flags. A stamp on the PPS forms refers readers to this ..memo. 

m_i_ijjLi iL,irtcc: Valerie Everette 

Project File 6.6 

Docket A-90-19 

(M. Haley) 

Jli; S0> 4BK 

EPA AIR DOCKET | 
P.3 

ATTACHMENT 1 
P.4 

. Page No. 1 

. 01/15/92 ' 

Descriptive Name 

4,4-METHYLENEDIANILINE VIA 

CONDENSATION OF ANILINE WITH 

FORMALDEHYDE 

ACETAL VIA CONDENSATION OF 

ETHANOL AND ACETALDEHYD 

ACETALDEHYDE VIA AIR OXIDATION 

OF ETHYLENE 

ACETAMIDE VIA OISTILLATION OF 

AMMONIUM ACETATE 

ACETIC ACID VIA CARBONYLATION 

OF METHANOL 

ACETIC ACID VIA OXIDATION OF 

ACETALDEHYDE WITH CATALYST 

ACETIC ANHYDRIDE VIA AIR 

OXIDATION OF ACETALDEHYDE 

ACROLEIN VIA OXIDATION OF 

PROPYLENE 

ACRYLAMIDE VIA HYDROLYSIS OF 

ACRYLONITRILE 

ACRYLIC ACID VIA OXIDATION OF 

ACROLEIN, ACROLEIN FROM 

OXIDATION OF PROPYLEN 

ACRYLONITRILE VIA AIR 

OXIDATION OF PROPYLENE 

ADIPONITRILE VIA ADDITION OF 

HYDROGEN CYANID TO BUTADIENE 

ADIPONITRILE VIA 

ELECTROHYDRODIMERIZATION OF 

ACRYLONITRILE 

ALLYL ALCOHOL VIA HYDROLYSIS 

OF ALLYL CHLORIDE 

ALLYL ALCOHOL VIA 

ISOMERIZATION OF PROPENE OXIDE 

ALLYL CHLORIDE VIA 

HALOGENATION OF PROPENE 

AMINOPHENOL (P-) VIA 

HYDROGENATION OF NITROPHENOL 

• AMMONIUN THIOCYANATE VIA 

PYROYSIS OF AMMONIUM 

. DITHIOCARBONATE 

ANILINE HYDROC. VIA 

AMMONOLYSIS OF CHLOROBENZENE 

ANILINE VIA AMINOLYSIS OF 

PHENOL 

ANILINE VIA HYDROGENATION OF 

NITROBENZENE 

ANISIDINE (0-) VIA 

HYDROGENATION OF NITROANISOLE 

ANTHRAQUINONE VIA CONDENSATION 

OF NAPHTHAQUINONE AND 

BUTADIENE 

Product 

Process 

101779A 

105577A 

75070A 

60355A 

64197A 

64197B 

108247A 

107028A 

79061A 

79107A 

107131A 

111693B 

111693C 

107186A 

107186B 

107051A 

123308A 

1762954A 

142041A 

62533B 

62533A 

92159A 

84651B 

Process Vent 

Chemical Name 

METHYLENE DIANILINE 

- 4,4 (MDA) 

ACETAL 

ACETALDEHYDE 

ACETAMIDE 

ACETIC ACID 

ACETIC ACID 

ACETIC ANHYDRIDE 

ACROLEIN 

ACRYLAMIDE 

ACRYLIC ACID 

ACRYLONITRILE 

ADIPONITRILE 

ADIPONITRILE 

ALLYL ALCOHOL 

ALLYL ALCOHOL 

ALLYL CHLORIDE 

AMINOPHENOL - P 

Flags 

Category 

(A or 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

AMMONIUM THIOCYANATE A 

ANILINE 

HYDROCHLORIDE 

ANILINE 

ANILINE 

ANISIDINE - 0 

ANTHRAQUINONE 

B 

A 

A 

B 

A 

B) 

PVENT RXTJ/ENTS DIST.VENTS AROX.VE 

.T. . .T. .T. .F. 

.T. .T. .F. .F. 

.T. .F. .F. .T. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .F. .F. .T. 

.T. .F. .F. .T. 

.T. .T. .T. .F. 

.T. .F. .F. .T. 

.T. .F. .F. .T. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .F. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

.T. .T. .T. .F. 

<TS DIST_VAC DIST.NVAC 

.F. .T. 

.F. .F. 

.F. .F. 

.F. .T. 

.F. ,T. 

.F. .T. 

.F. ,F. 

.F. .F. 

.F. .T. 

.F. .F. 

.F. .F. 

.T. .F. 

.T. ,F. 

,F. .T. 

.F. .T. 

.F. .T. 

.F. .F. 

.F. .T. 

.F. .T. 

.F. .T. 

.T. .F. 

.F. ,T. 

.F. .T. 
P.5 

v Page No. 

01/15/92' 

Descriptive Name 

Process Vent Flags 

Product Chemical Name Category PVENT RXTJ/ENTS DISTJ/ENTS AROX.VENTS DISTJ/AC DIST_NVAC 

Process (A or B) 

ANTHRAQUINONE VIA DEHYDROLYSIS 84651A 

OF BENZOYLBENZOIC ACID 

ANTHRAQUINONE VIA 84651C 

HYDRODIMERIZATION OF STYRENE 

BENZENE DISULFONIC ACID VIA 98486A 

SULFONATION OF BENZENE 

BENZENE SULFONIC ACID VIA 98113A 

CONTINUOUS SULFONATION W/ 

OLEUM 

BENZENE SULFONIC ACID VIA 98113B 

SULFONATION & CONTINUOUS 

EXTRACTION 

BENZENE SULFONIC ACID VIA 98U3C 

SULFONATION & REMOVAL OF ISO 

BENZENE VIA CATALYTIC 71432A 

REFORMING.OF NAPHTHA 

BENZENE VIA 71432B 

HYDRODEALKYLATION/TRANSALKYLAT 

ION OF TOLUENE 

BENZENE VIA HYDROGENATION OF 71432C 

PYROLYSIS GAS 

BENZIL VIA CARBONYLATION OF 134816A 

CHLOROBENZENE 

BENZOIC ACID VIA OXIDATION OF 65850A 

TOLUENE 

BENZOIN VIA ESTERIFICATION OF 119539A 

BENZALDEHYDE 

BENZONITRILE VIA ADDITION OF 100470A 

POTASSIUM CY. TO BENZ. DIAZ. 

BENZOPHENONE VIA ACYLATION OF 119619A 

BENZENE & BENZOYL CHLORID 

BENZOYL CHLORIDE VIA REACTION 98884A 

OF BENZOIC ACID AND 

BENZOTRICHLORIDE 

BENZYL ALCOHOL VIA HYDROLYSIS 100516A 

OF BENZYL CHLORIDE 

BENZYL BENZOATE VIA 120514A 

ESTERIFICATION OF BENZYL ALCOH 

8ENZYL CHLORIDE VIA 100447A 

CHLORINATION OF TOLUENE 

BIPHENYL VIA DEHYDROGENATION 925248 

OF BENZENE 

BIS(CHLOROMETHYL)ETHER VIA 542881A 

HALOGENATION OF 

PARAFORMALDEHYDE 

BISPHENOL A VIA CONDENSATION 80057A 

OF PHENOL AND ACETONE 

8R0M0F0RM VIA RXN OF 75252A 

TRIBROMOACETAMIDE AND KOH 

ANTHRAQUINONE A 

ANTHRAQUINONE A 

BENZENE DISULFONIC B 

ACID 

BENZENE SULFONIC A 

ACID 

BENZENE SULFONIC A 

ACID 

BENZENE SULFONIC A 

ACID 

BENZENE (INCLUDING A 

BENZENE FROM 

GASOLINE) 

BENZENE (INCLUDING A 

BENZENE FROM 

GASOLINE) 

BENZENE (INCLUDING A 

BENZENE FROM 

GASOLINE) 

BENZIL 

BENZOIC ACID 

BENZOIN 

BENZONITRILE 

BENZOPHENONE 

BENZOYL CHLORIDE 

BENZYL ALCOHOL A 

BENZYL BENZOATE A 

BENZYL CHLORIDE A 

BIPHENYL A 

BIS(CHLOROMETHYL)ETH B 

ER 

BISPHENOL A A 

BROMOFORM B 

.T. .T. 

.T. .T. 

.T. .T. 

.T. .T. 

.T. .T. 

.T. .T. 

.T. .T. 

T. .T 

T. .F 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

T. .T 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.F. 

.F. 

.F. 

.T. 

.F. 

.T. 

.T. 

.F. 

.T. 

.F. 

.T. 

.T. 

.T. .F. 
• Page No.. 3 

01/15/92 

P.6 

Process Vent Flags 

Descriptive Name 

BROMONAPHTHALENE VIA 

HALOGENATION OF NAPHTHALENE 

BUTADIENE VIA CATALYTIC 

REFORMATION OF C4 STREAMS 

BUTADIENE VIA DEHYDROGENATION 

OF C4 COMPOUNDS 

BUTYL ACRYLATE (N-ISOMER) VIA 

ESTERIFICATION OF ACRYLIC ACID 

BUTYLENE GLYCOL (1,3-) VIA 

HYDROGENATION OF ACETALDOL 

CAPROLACTAM PRODUCTION VIA 

REARRANGEMENT OF CYCLOHEXANONE 

CARBARYL VIA CONDENSATION OF 

M. ISOCYANATE AND NAPHTHOL 

CARBON DISULFIDE VIA 

SULFONATION OF METHANE 

CARBON TETRABROMIOE VIA 

HALOGENATION OF CARBON 

DISULFIDE 

CARBON TETRACHLORIDE VIA 

CHLORINATION OF CARBON 

DISULFIDE 

CARBON TETRACHLORIDE VIA 

CHLORINATION OF HYDROCARBONS 

CFC VIA LIQUID PHASE CATALYTIC 

REACTION 

CFC-142 VIA HALOGENATION OF 

CHLORO COMPOUNOS 

CFC-22 VIA HALOGENATION OF 

CHLOROFORM 

CHLOROACETIC ACID VIA 

HALOGENATION OF ACETIC ACID 

CHLOROACETIC ACID VIA 

HYDROLYSIS OF CHLOROACETYL 

CHLORIDE 

CHLOROANILINE (0-) VIA 

HYDROGENATION OF 

2-CHL0R0NITR0BENZENE 

CHLOROANILINE (P-) VIA 

HALOGENATION OF ANILINE 

CHLOROBENZENE VIA HALOGENATION 

OF BENZENE 

CHLOROFORM VIA HALOGENATION OF 

METHANE 

CHLOROFORM VIA HALOGENATION OF 

METHYL CHLORIDE 

CHLORONAPHTHALENE VIA 

HALOGENATION OF NAPHTHALENE 

CHLORONITROBENZENE (P-ISOMER) 

VIA NITRATION OF CHLOROBENZENE 

Product 

Process 

27497514A 

106990A 

106990B 

141322A 

107880A 

105602A 

63252A 

75150A 

558134A 

Chemical Name 

BROMONAPHTHALENE 

BUTADIENE-1.3 

BUTADIENE-1,3 

BUTYL ACRYLATE - N 

BUTYLENE GLYCOL -

1,3 

CAPROLACTAM 

CARBARYL 

CARBON DISULFIDE 

CARBON TETRABROMIDE 

Category 

(A 

A 

A 

A 

A 

A 

A 

B 

A 

B 

or B) 

PVENT 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

RXTJ/ENTS D 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

56235A CARBON TETRACHLORIDE A 

95512A CHLOROANILINE-0 4,4 B 

METHYLENE 

BIS(2-CHL0R0ANILINE) 

.T. 

56235B 

75694A 

75456A 

25497294A 

79118A 

79118B 

CARBON TETRACHLORIDE A 

TRICHLOROFLUOROMETHA A 

NE 

CHLORODIFLUOROETHANE A 

CHLORODIFLUOROMETHAN A 

E 

CHLOROACETIC ACID A 

CHLOROACETIC ACID A 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.F. . . 

.T. 

.T. 

.T. .T. 

106478A 

108907A 

67663B 

67663A 

25586430A 

100005A 

CHLOROANILINE - P 

CHLOROBENZENE 

CHLOROFORM 

CHLOROFORM 

CHLORONAPHTHALENE 

CHLORONITROBENZENE 

P 

B 

A 

A 

A 

B 

- A 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.F. 

.F. 

.T. 

.F. 

.F. 

.T. 

.F. 

.F. 

.F. 

.T. 

.F. 

.F. 

.F. 

,F. 

.F. 

.F. 

.F. 

.T. 

.T. 

.T. 

.F. 

.F. 
P.7 

"' Page No.'. 4 

• 01/15/92 

Descriptive Name 

CHLOROPHENOLS VIA HYDROLYSIS 

OF CHLOROBENZENE • 

CHLOROPRENE VIA 

0EHYDROHALOGENATION OF 

3,4-DICHLORO-l-BUTENE 

CHLOROTOLUENE (0-) VIA 

HALOGENATION OF TOLUENE 

CHLOROTRIFLUOROMETHANE VIA 

FLUORINATION OF CHLORO 

COMPOUNDS 

CRESOLS/CRESYLIC ACIDS (MIX) 

VIA RECOVERY FROM SPENT 

REFINERY CAUSTICS 

CRESOLS/CRESYLIC ACIDS 

(P-ISOMER) VIA ALKALI FUSION 

OF TOLUENE SULFONATES 

CROTONALDEHYDE VIA DEHYDRATION 

OF ACETALDOL 

CUMENE HYDROPEROXIDE VIA 

OXIDATION OF CUMENE 

CUMENE VIA ALKYLATION OF 

BENZENE WITH PROPYLENE 

CYCLOHEXANE VIA HYDROGENATION 

OF BENZENE 

CYCLOHEXANONE VIA 

HYDROGENATION OF PHENOL 

CYCLOHEXYLAMINE VIA 

HYDROGENATION OF ANILINE 

DICHLOROETHYL ETHER VIA 

HALOGENATION OF ETHYL ETHER 

DIETHEYLENE GLYCOL MONOBUTYL 

ETHER ACETATE VIA 

ESTERIFICATION 

DIETHYLAMINE VIA ETHYLATION OF 

AMMONIA 

DIETHYLENE GLYCOL DIBUTYL 

ETHER VIA HYDROGENATION OF DEG 

M8 ETHER 

DIETHYLENE GLYCOL DIETHYL 

ETHER VIA HYDROGENATION OF DEG 

ME ETHER 

DIETHYLENE GLYCOL DIMETHYL 

ETHER VIA HYDROGENATION OF 

DEGMM ETHER 

DIETHYLENE GLYCOL MONOETHYL 

ETHER ACETATE VIA 

ESTERIFICATION OF OEG 

DIISODECYL PHTHALATE VIA 

ESTERIFICATION W/PHTHALIC 

ANHYDRIDE AND DECANOL 

Product 

Process 

25167800A 

126998A 

95498A 

75729A 

1319773A 

106445B 

123739A 

80159A 

98828A 

110877A 

108941A 

108918A 

111444A 

124177A 

109897A 

112732A 

112367A 

111966A 

112152A 

26761400A 

Proces 

Chemical Name 

CHLOROPHENOLS 

CHLOROPRENE 

(2-CHLORO-1.3-BUTADI 

ENE) 

CHLOROTOLUENE - 0 

--.. 

s Vent Flags 

Category 

(A or B) 

A 

A 

A 

CHLOROTRIFLUOROMETHA A 

NE 

CRESOLS/CRESYLIC 

ACID (ISOMERS & 

MIX),MIX 

CRESOLS/CRESYLIC 

ACID (ISOMERS & 

MIX),PCROTONALDEHYDE 

CUMENE HYDROPEROXIDE 

CUMENE (ISOPROPYL 

BENZENE) 

CYCLOHEXANE 

CYCLOHEXANONE 

CYCLOHEXYLAMINE 

DICHLOROETHYL ETHER 

(BIS(2-CHLOROETHYL)E 

THER) 

DIETHYLENE GLYCOL 

MONOBUTYL ETHER 

ACETATE 

DIETHYLAMINE 

DIETHYLENE GLYCOL 

DIBUTYL ETHER 

DIETHYLENE GLYCOL 

DIETHYL ETHER 

DIETHYLENE GLYCOL 

DIMETHYL ETHER 

DIETHYLENE GLYCOL 

MONOETHYL ETHER 

ACETATE 

A 

A 

B 

A 

A 

A 

A 

A 

B 

B 

A 

B 

B 

A 

B 

DIISODECYL PHTHALATE A 

PVENT RXT.VENTS DISTJ/ENTS 

.T. .T. .T. 

.T. .T. .F. 

.T. .T. .F. 

.T. .T. .T. 

.T. .F. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .F. .F. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

.T. .T. .T. 

i 

AROX_VENTS DIST_VAC DIST_NVAC 
Page No. ' 5 

01/15/92 

P.8 

Process Vent Flags 

Descriptive Name 

DIIS00CTYL PHTHALATE VIA 

ESTERIFICATION W/ PHTHALIC 

ANHYDRIDE & OCTYL ALCOH 

DIMETHYL ETHER (N.N-) VIA 

CATALYTIC DEHYDRATION OF 

METHANOL 

Product Chemical Name Category PVENT RXT.VENTS DIST.VENTS AROX.VENTS OIST.VAC 0 

Process (A or B) 

27554263A 0IIS00CTYL PHTHALATE A 

115106A DIMETHYL ETHER - N,N A 

.T. 

.T. 

DIMETHYL FORMAMIDE VIA 

AMINOLYSIS OF METHYL FORMATE 

DIMETHYL FORMAMIDE VIA 

CARBONYLATION OF DIMETHYLAMINE 

DIMETHYL SULFATE VIA 

ESTERIFICATION OF METHYLC.S. & 

DI-M.S. 

DIMETHYL TEREPHTHALATE VIA 

ESTERIFICATION OF TPA 

DIMETHYLANILINE VIA ALKYLATION 

OF ANILINE 

DINITROPHENOL (2,4-) VIA 

HYDROLYSIS OF 

2,4-DINITROCHLOROBENZENE 

DINITROTOLUENE (2,4-) VIA 

NITRATION OF NITROTOLUENE 

MIXTURE 

DINITROTOLUENE (2,4-) VIA 

NITRATION OF NITROTOLUENE(P-) 

DIOXANE (1,4-) VIA CYCLIC 

DEHYDRATION OF DIGLYCOL 

OIOXANE (1,4-) VIA 

DEHYDROHALOGENATION OF 

CHLOROHYDRIN 

DIOXANE (1,4-) VIA ETHYLENE 

OXIDE HYDRODIMERIZATION 

DIOXOLANE VIA CONDENSATION OF 

GLYCOL AND FORMALDEHYDE 

DIPHENYL OXIDE VIA HYDROLYSIS 

OF CHLOROBENZENE 

EPICHLOROHYDRIN VIA 

CHLOROHYDRATION OF ALLYL 

CHLORIDE 

ETHANOLAMINE VIA AMMONOLYSIS 

OF ETHYLENE OXIDE 

ETHYL ACRYLATE VIA 

ESTERIFICATION OF ACRYLIC ACID 

BY ETHYL ALCOHOL 

ETHYL CELLULOSE VIA ETHYLATION 

OF CELLULOSE 

ETHYL CHLORIDE VIA 

HYDROCHLORINATION OF EHTYLENE 

681228 

68122A 

77781A 

120616A 

121697A 

51285A 

121142A 

121142B 

123911A 

123911C 

123911B 

646060A 

101848A 

106898A 

141435A 

140885A 

9004573A 

75003A 

DIMETHYL FORMAMIDE 

(DMF) 

DIMETHYL FORMAMIDE 

(DMF) 

DIMETHYL SULFATE 

DIMETHYL 

TEREPHTHALATE 

DIMETHYLANILINE -

N.N (N.N 

DIETHYLANILINE) 

DINITROPHENOL - 2,4 

DINITROTOLUENE - 2,4 

(DNT) 

DINITROTOLUENE - 2,4 

(DNT) 

DIOXANE - 1,4 

(1.4-DIETHYLENE0XI0E 

1 

) 

DIOXANE - 1,4 

(1,4-DIETHYLENEOXIDE 

) 

DIOXANE - 1,4 

(1,4-DIETHYLENEOXIDE 

J 

DIOXOLANE 

DIPHENYL OXIDE 

EPICHL0R0HYDRIN(1-CH 

L0R0-2.3-EP0XYPR0PAN 

E) 

ETHANOLAMINES + ALL 

ISOMERS 

ETHYL ACRYLATE 

ETHYLCELLULOSE 

ETHYL CHLORIDE 

(CHLOROETHANE) 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

ST.NVAC 
Page No. 

01/15/92 

P.9 

Process Vent Flags 

Descriptive Name Product Chemical Name Category PVENT RXT_VENTS DISTJ/ENTS AROXJ/ENTS OISTJ/AC OIST.NVAC 

Process (A or B) 

ETHYL CHLORIDE VIA 

HYDROCHLORINATION OF ETHANOL 

ETHYLBENZENE VIA ALKYLATION OF 

BENZENE WITH ETHYLENE 

ETHYLENE DIBROMIDE VIA 

HALOGENATION OF ETHYLENE 

ETHYLENE DICHLORIDE VIA 

CHLORINATION/OXYCHLORINATION 

OF ETHYLENE 

ETHYLENE GLYCOL DIETHYL ETHER 

VIA HYDROGENATION OF EHTYLENE 

GLYCO 

ETHYLENE GLYCOL OIMETHYL ETHER 

VIA HYDROGENATION OF E.G. 

MONO-M 

ETHYLENE GLYCOL MONOB. ETHER 

VIA ALCOHOLYSIS OF ETHYLENE 

OXIDE BY BUTANOL 

ETHYLENE GLYCOL MONOBUTYL 

ETHER ACETATE VIA 

ESTERIFICATION OF E.G.MB.ETHER 

ETHYLENE GLYCOL MONOETH. ETHER 

VIA ALCOHOLYSIS OF ETHYLENE 

OXIDE BY ETHANOL 

ETHYLENE GLYCOL MONOETHYL 

ETHER ACETATE VIA 

ESTERIFICATION OF 

E.G.MONOE.E.A 

ETHYLENE GLYCOL MONOETHYL 

ETHER ACETATE VIA 

ESTERIFICATION OF 

E.G.MONOE.ETH 

ETHYLENE GLYCOL MONOMETH. 

ETHER VIA ALCOHOLYSIS OF 

ETHYLENE OXIDE BY METHA. 

ETHYLENE GLYCOL MONOPHENYL 

ETHER VIA ALCOHOLYSIS OF 

E.OXIDE BY-P 

ETHYLENE GLYCOL MONOPROPYL 

ETHER VIA ALCOHOLYSIS OF 

ETHYLENE OXIDE 

ETHYLENE GLYCOL VIA HYDROLYSIS 

OF ETHYLENE OXIDE 

ETHYLENE OXIDE VIA AIR 

OXIDATION OF ETHYLENE 

ETHYLENEDIAMINE VIA 

DEHYDROHALOGENATION OF 

ETHYLENE DICHLORIDE 

FORMADIDE VIA AMMONOLYSIS OF 

METHYL FORMATE 

75003B 

100414A 

106934A 

107062A 

629141A 

110714A 

111762A 

112072A 

110805A 

111159A 

110496A 

109864A 

122996A 

2807309A 

* 

107211A 

75218A 

107153A 

75127B 

ETHYL CHLORIDE 

(CHLOROETHANE) 

ETHYL BENZENE 

ETHYLENE DIBROMIDE 

(DIBROMOETHANE) 

(EDB) 

DICHLOROETHANE - 1 

(EDC) 

ETHYLENE GLYCOL 

DIETHYL ETHER 

ETHYLENE GLYCOL 

DIMETHYL ETHER 

ETHYLENE GLYCOL 

MONOBUTYL ETHER 

ETHYLENE GLYCOL 

MONOBUTYL ETHER 

ACETATE 

ETHYLENE GLYCOL 

MONOETHYL ETHER 

ETHYLENE GLYCOL 

MONOETHYL ETHER 

ACETATE 

ETHYLENE GLYCOL 

MONOMETHYL ETHER 

ACETATE 

ETHYLENE GLYCOL 

MONOMETHYL ETHER 

ETHYLENE GLYCOL 

MONOPHENYL ETHER 

ETHYLENE GLYCOL 

MONOPROPYL ETHER 

ETHYLENE GLYCOL 

ETHYLENE OXIDE 

ETHYLENEDIAMINE 

FORMAMIDE 

A 

A 

B 

2 A 

B 

B 

A 

A 

A 

B 

' B 

A 

B 

B 

A 

A 

A 

A 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T-. 

.T. 

.T. 

.T. 

.T. 

.F. 

.T. 

.T. 

.F. .F. 

.T. .F. 

.T. .F. 

.T. .F. 

.T.' .F. 

.T. .F. 

.T. .F. 

.T. .F. 

. 

.T. .F. 

.T. .F. 

.T. .F. 

.T. .F. 

.T. .F. 

.T. .F. 

.T. .F. 

.F. .T. 

.T. .F. 

.T. .F. 

.F. .F 

.F. .T 

.F. ,T 

.F. .T 

.F. .T 

.F. .T 

.T. .F 

.F. .T 

.F. .T 

.F. .T 

.F. .T 

.F. .T 

.F. .T 

.F. ,T 

.T. .F 

.F. .F 

.F. .T 

.F. .T 
Page No. " 7 

01/15/92 

P.10 

Process Vent Flags 

Descriptive Name 

FORMALDEHYDE FROM 

DEHYDROGENATION OF METHANOL 

FORMALOEHYDE VIA AIR OXIDATION 

OF METHANOL 

FUMARIC ACID VIA HYDRATION OF 

MALEIC ANHYDRIDE 

GLYCEROL VIA HYDROLYSIS OF 

EPICHLOROHYDRIN 

GLYCINE VIA AMMONOLYSIS OF 

CHLOROACETIC ACID 

GLYOXAL VIA AIR OXIDATION OF 

ETHYLENE GLYCOL 

HEXACHLOROBUTADIENE VIA 

HALOGENATION OF BUTADIENE 

HEXACHLOROBUTADIENE VIA 

HALOGENATION OF CARBON 

DISULFIDE 

HEXACHLOROBUTADIENE VIA 

HALOGENATION OF CHLOROPREN 

HEXACHLOROETHANE VIA 

HALOGENATION OF 

TETRACHLOROETHYLENE 

HEXAMETHYLENETETRAMINE VIA 

ADDITION OF AMMONIA TO 

FORMALDEHYDE 

HYDROFORMYLATION OF ETHYLENE 

THEN HYDROGENATION OF 

PROPIONALDEHYDE/OXO PROC 

HYDROQUINONE VIA 

DIISOPROPYL-BENZENE 

HYDROPEROXIDE CLEAVAGE 

HYDROQUINONE VIA QUINONE 

REDUCTION 

ISOBUTYLENE VIA CRACKING OF 

MTBE 

ISOPHERONE VIA LIQUID PHASE 

CONDENSATION OF ACETON 

ISOPHTHALIC ACID VIA AIR 

OXIDATION OF M-XYLENE 

ISOPROPYL PHENOL VIA 

ALKYLATION OF PHENOL 

LINEAR ALKYLBENZENE VIA 

ALKYLATION OF 

N-CHLOROPARAFFINS 

MALEIC ANHYDRIDE VIA AIR 

OXIDATION OF BUTENES 

MDI VIA REACTING 4,4 

METHYLENEDIANILINE WITH 

PHOSGENE 

MESITYL OXIDE VIA DEHYDRATION 

OF DIACETONE AND HYDROGENATION 

OF DOUBLE BOND 

Product 

Process 

50000A 

50000B 

110178A 

56815C 

56406A 

107222A 

87683B 

87683C 

87683A 

67721A 

100970A 

71238A 

123319B 

123319A 

115117B 

78591A 

121915A 

25168063A 

123013A 

108316B 

101688A 

108101A 

Chemical Name 

FORMALDEHYDE 

FORMALDEHYDE 

FUMARIC ACID 

GLYCEROL 

GLYCINE 

GLYOXAL 

HEXACHLOROBUTADIENE 

HEXACHLOROBUTADIENE 

HEXACHLOROBUTADIENE 

HEXACHLOROETHANE 

HEXAMETHYLENETETRAMI 

NE 

PROPYL ALCOHOL - N 

HYDROQUINONE 

HYDROQUINONE 

ISOBUTYLENE 

ISOPHORONE 

ISOPHTHALIC ACID 

ISOPROPYLPHENOL 

LINEAR ALKYLBENZENE 

(LINEAR 

DODECYLBENZENE) 

MALEIC ANHYDRIDE 

METHYLENE OIPHENYL 

DIISOCYANATE (MDI) 

METHYL ISOBUTYL 

KETONE (HEXONE) 

Category PVENT RXTJ/ENTS DISTJ/ENTS ARC 

(A or B) 

A 

A 

A 

A 

A 

A 

B 

B 

B 

B 

A 

A 

A 

A 

A 

B 

A 

B 

A 

A 

A 

A 

.T. 

.T. 

. T . • 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.F. 

.T. 

.T. 

.T. 

.F. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.F. 

.T. 

.T. 

.F. 

.T. 

.T. 

.T. .F 

.F. .T 

.T. .F 

.T. .F 

.T. .F 

•• 

.F. .T 

.T. .F 

.T. .F 

.T. .F 

.T. .F 

.F. .F 

.T. .F 

.F. .F 

.F. .F 

.T. .F 

.T. .F 

.F. .T 

.T. .F 

.T. .F 

.F. .T 

.T. .F 

.T. .F 
P.11 

Page No. 

01/15/92 

Descriptive Name 

Process Vent Flags 

Product Chemical Name Category PVENT RXTJ/ENTS DISTJ/ENTS AR0XJ/ENTS DIST_VAC DIST.NVAC 

Process (A or B) 

METHANOL VIA HYDROGENATION OF 67561A 

CARBON MONOXIDE 

METHYL ACETATE VIA HYDROLYSIS 79209A 

OF POLYVINYL ACETATE BY 

METHANOL 

METHYL BROMIDE VIA 74839A 

HALOGENATION OF METHANOL 

METHYL CHLORIDE VIA 74873A 

HYDROHALOGENATION OF METHANOL 

METHYL ETHYL KETONE VIA 78933A 

DEHYDROGENATION OF S-BUTYL 

ALCOHOL 

METHYL ISOCYANATE VIA 624839A 

PHOSGENATION OF METHYLAMINE 

METHYL METHACRYLATE VIA 80626A 

HYDROLYSIS AND ALKYLATION OF 

ACETONE CYANOHYDRIN 

METHYL TERT BUTYL ETHER VIA 1634044A 

ETHERIFICATION OF ISOBUTYLENE 

AND METHANOL 

METHYL TERT BUTYL ETHER VIA 1634044C 

ISOMERIZATION OF BUTANE 

METHYLAMINES VIA METHYLATION 74895A 

OF AMMONIA 

NAPHTHALENE FROM COAL TAR 91203B 

DISTILLATION 

NAPHTHALENE SULFONIC ACID (A-) 85472A 

VIA SULFONATION OF N. @ 600C 

NAPHTHALENE SULFONIC ACID (B-) 120183A 

VIA SULFONATION OF NAPTHALENE 

NAPHTHOL (B-ISOMER) VIA 135193A 

OXIDATION CLEAVAGE OF 

ISOPROPYL NAPHTHALENE 

NAPTHALENE FROM PETROLEUM 91203A 

DEALKYLATION 

NITROBENZENE VIA NITRATION OF 98953A 

BENZENE 

NITROTOLUENE VIA NITRATION OF 1321126A 

TOLUENE 

NONYLPHENOL VIA ALKYLATION OF 25154523A 

PHENOL 

PENTACHLOROPHENOL VIA 87865A 

HALOGENATION OF PHENOL 

PENTAERYTHRITOL VIA ADDITION 115775A 

OF FORMALDEHYDE TO 

ACETALDEHYDE 

PERCHLOROETHYLENE VIA 127184A 

CHLORINATION OF ETHYLENE 

DICHLORIDE 

PERCHLOROETHYLENE VIA 127184B 

OXYCHLORINATION OF ETHYLENE 

DICHLORIDE 

METHANOL 

METHYL ACETATE 

METHYL BROMIDE A 

(BROMOMETHANE) 

METHYL CHLORIDE A 

(CHLOROMETHANE) 

METHYL ETHYL KETONE A 

(2-BUTANONE) 

METHYL ISOCYANATE A 

METHYL METHACRYLATE A 

METHYL TERT BUTYL A 

ETHER (MTBE) 

METHYL TERT BUTYL A 

ETHER (MTBE) 

METHYLAMINE A 

NAPHTHALENE A 

NAPHTHALENE SULFONIC B 

ACID - A 

NAPHTHALENE SULFONIC B 

ACID - B 

NAPHTHOL - B A 

NAPHTHALENE A 

NITROBENZENE A 

NITROTOLUENE B 

NONYLPHENOL A 

PENTACHLOROPHENOL A 

PENTAERYTHRITOL A 

PERCHLOROETHYLENE(TE A 

TRACHLOROETHYLENE) 

PERCHLOROETHYLENE(TE A 

TRACHLOROETHYLENE) 
Page No. • 

01/15/92 

P.12 

Process Vent Flags 

Descriptive Name 

PERCHLOROMETHYL MERCAPTAN VIA 

HALOGENATION OF CARBON 

DISULFIDE 

PHENOL VIA ACID CLEAVAGE OF 

CUMENE HYDROPEROXIDE 

PHENYLENEDIAMINE (P-) VIA 

HYDROGENATION OF NITROANILINE 

PHOSGENE VIA HALOGENATION OF 

CARBON MONOXIDE 

PHTHALIC ANHYDRIDE VIA AIR 

OXIDATION OF NAPHTHALENE 

PHTHALIC ANHYDRIDE VIA AIR 

OXIDATION OF O-XYLENE 

POLYETHYLENE GLYCOL VIA 

POLYMERIZATION OF ETHYLENE 

GLYCOL & ETHYLENE OXIDE 

POLYPROPYLENE GLYCOL VIA 

POLYMER OF PROPYLENE OXIDE AND 

PROPYLENE GLYCOL 

PROPIOLACTONE (B-) VIA 

CONDENSATION OF KETENE AND 

FORMALDEHYDE 

PROPIONIC ACIO VIA AIR 

OXIDATION OF PROPIONALDEHYDE 

PROPYLENE GLYCOL MONOMETHYL 

ETHER VIA ALCOHOLY. PROPYLENE 

OXIDE BY METHANOL 

PROPYLENE GLYCOL VIA 

HYDROLYSIS OF PROPYLENE OXIDE 

PROPYLENE OXIDE VIA 

DEHYDROHALOGENATION OF 

PROPYLENE CHLOROHYDRIN 

PROPYLENE OXIDE VIA 

EPOXIDATION OF T-BUTYL 

HYDROPEROXIDE 

PYRIDINE VIA CONDENSATION OF 

ACETALDEHYDE AND FORMALDEHYDE 

RESORCINOL VIA SULFONATE 

FUSION PROCESS 

SALICYLIC ACID VIA 

HYDROFORMYLATION OF SODIUM 

PHENATE 

STYRENE PRODUCTION VIA 

DEHYDROGENATION OF 

ETHYLBENZENE 

STYRENE VIA DEHYDRATION OF 

METHYL BENZYL ALCOHOL 

SUCCINIC ACID VIA HYDROLYSIS 

OF ETHYLENE DICYANIDE 

SULFOLANE VIA ADDITION OF 

SULFUR DIOXIDE TO BUTADIENE 

Product 

Process 

594423A 

108952A 

106503A 

75445A . 

85449B 

85449A 

25322683A 

25322694A 

Chemical Name 

PERCHLOROMETHYL 

MERCAPTAN 

PHENOL 

PHENYLENEDIAMINE -P 

PHOSGENE 

PHTHALIC ANHYDRIDE 

PHTHALIC ANHYDRIDE 

POLYETHYLENE GLYCOL 

Category 

(A or B) 

A 

A 

B 

A 

A 

A 

A 

POLYPROPYLENE GLYCOL A 

PV 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

Category PVENT RXT.VENTS DIST_VENTS AROX.VENTS DISTJ/AC OIST.NVAC 

57578A PROPIOLACTONE (B-) B 

79094B 

107982A 

57556A 

75569A 

75569B 

110861A 

108463A 

69727A 

PROPIONIC ACID 

PROPYLENE GLYCOL 

MONOMETHYL ETHER 

PROPYLENE GLYCOL 

PROPYLENE OXIDE 

PROPYLENE OXIDE 

PYRIDINE 

RESORCINOL 

SALICYLIC ACID 

A 

A 

A 

A 

A 

A 

A 

A 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

100425A STYRENE .T. 

100425B 

1101568 

126330A 

STYRENE 

SUCCINIC ACID 

SULFOLANE 

A 

A 

A 

.T 

.T 

.T 
Page No. 

01/15/92 

10 

P.13 

Process Vent Flags 

Descriptive Name 

TEREPHTHALIC ACIO VIA 

HYDROLYSIS OF DNT 

TEREPHTHALIC ACID VIA 

OXIDATION OF P-XYLENE 

TETRACHLOROETHANE (1,1,2,2-) 

VIA HALOGENATION OF ACETYLENE 

TETRACHLOROETHANE (1,1,2,2-) 

VIA HALOGENATION OF ETHYLENE 

TETRACHLOROPHTHALIC ANHYDRIDE 

VIA HALOGENATION OF PHTHALIC 

ANHYDRIDE 

TETRAETHYL LEAO VIA ADDITION 

OF ETHYL CHLORIDE TO 

LEAD-SODIUM ALLOY 

TOLUENE DIISOCYANATES VIA 

DINITRATION OF TOLUENE WITH 

PHOSEGENATION 

TOLUENE SULFONYL CHLORIDE VIA 

REACTION OF TOLUENE W/ 

CHLOROSULFONIC ACID 

TRICHLOROETHANE (1.1,1-) VIA 

HALOGENATION OF ETHANE 

TRICHLOROETHANE (1,1,1-) VIA 

HYDROHALOGENATION OF VINYL 

CHLORIDE 

TRICHLOROETHANE (1.1,2-) VIA 

HALOGENATION OF ETHYLENE 

TRICHLOROETHANE (1,1.2-) VIA 

HALOGENATION OF VINYL CHLORIDE 

TRICHLOROETHYLENE VIA 

CHLORINATION OF ETHYLENE 

DICHLORIDE 

TRICHLOROTRIFLUOROETHANE VIA 

HALOGENATION OF 

PERCHLOROETHYLENE 

TRIETHYLENE GLYCOL DIMETHYL 

ETHER VIA HYDROGENATION OF 

TRI-E.G.MONO-M E. 

TRIMETHYLPENTANE (2,2,4-) (M-) 

VIA ALKYLATION OF ISOBUTYLENE 

AND ISO-BUTANE 

VINYL ACETATE VIA 

OXYACETYLATION OF ETHYLENE 

VINYL CHLORIDE VIA 

DEHYDROHALOGENATION OF 

ETHYLENE DICHLORIDE BY THERMAL 

CRACKING 

VINYL CHLORIDE VIA 

HYDROHALOGENATION OF ACETYLENE 

Product 

Process 

100210B 

100210A 

79345A 

79345B 

117088A 

78002A 

26471625A 

98599A 

71556B 

71556A 

79005B 

79005A 

79016B 

Chemical Name 

TEREPHTHALIC ACID 

TEREPHTHALIC ACID 

TETRACHLOROETHANE -

1,1,2,2 

TETRACHLOROETHANE -

1,1.2.2 

TETRACHLOROPHTHALIC 

ANHYDRIDE 

TETRAETHYL LEAD 

TOLUENE 

DIISOCYANATES(MIXTUR 

E) 

TOLUENESULFONYL-P 

CHLORIDE 

TRICHLOROETHANE 

(1,1,1-) 

TRICHLOROETHANE 

(1,1.1-) 

TRICHLOROETHANE 

(1,1,2-) (VINYL 

TRICHLORIDE) 

TRICHLOROETHANE 

(1,1,2-) (VINYL 

TRICHLORIDE) 

TRICHLOROETHYLENE 

Category 

(A or B) 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

A 

PVENT 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

.T. 

RX 

.T 

.F 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

.T 

76131A TRICHLOROTRIFLUOROET A .T. .T. 

HANE-1,2,2 -1,1,2 

112492A TRIETHYLENE GLYCOL B .T. .T. 

DIMETHYL ETHER 

540841A 

108054A 

75014A 

TRIMETHYLPENTANE 

(2,2,4-) 

VINYL ACETATE 

VINYL CHLORIDE 

(CHLORO ETHYLENE) 

A 

A 

A 

.T. 

.T. 

.T. 

.T 

.T 

.T 

75014B VINYL CHLORIDE A 

(CHLORO ETHYLENE) 

.T. .T. .F. .F. 
1

 • * 

Page No. 11 

01/15/92 

P.14 

Process Vent Flags 

Descriptive Name 

VINYL TOLUENE VIA CATALYTIC 

DEHYDROGENATION OF 

ETHYLTOLUENE 

VINYLIDENE CHLORIDE VIA 

DEHYDROCHLORINATION OF 

1,1,2-TRICHLOROETHANE 

XYLENE (0-) VIA FRACTIONAL 

DISTILLATION OF MIXED XYLENE 

XYLENE (P-) VIA PURIFICATION 

OF MIXED XYLENE 

Product 

Process 

25013154A 

75354A 

95476A 

106423A 

Chemical Name Category PVENT 

(A 

VINYL TOLUENE B 

VINYLIDENE CHLORIDE A 

(1,1-DICHLOROETHYLEN 

E) 

XYLENES (ISOMERS AND A 

MIXTURE)-0 

XYLENES (ISOMERS AND A 

MIXTURE)-P 

or B) 

.T. 

.T. 

.T. 

.T. 

RXT_VEri 

.T. 

.T. 

.F. 

.F. 

TS DIST_VENTS 

.T. 

.T. 

.T. 

.T. 

AROX.VENTS 

.F. 

.F. 

.F. 

.F. 

DIST.VAC 

.F. 

.F. 

.F. 

.F. 

DI 

.T 

.T 

.T 

.T