each attached sheet as Fonn 26R, reference the Item number and identify the date prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revi8ed 219/11 

c. Phytslcal Appearance 

Company 

County 

Indiana 

Address Une 2 

Number of Solid or Uquid Phases of Separation 

Ext 

No 

Describe each phase of separatlon • .=s.:=----------------1 

- 1 -
c. 

a. 

b. 

c. 

d. 

b. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Facility 

Title 

Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

Phone 

Indiana 

(check one) 

Oton (check one) 

-2-
_and has not changed. 

Form Submitted: D Fonn 26R 

D Other (specify) 

Date Submitted: 

D I certify the Information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

_and has not changed. 

Form Submitted: D Form26R 

D other (specify) 

Date Submitted: 

D I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department 

for the year_ and has not changed. 

Form Submitted: D Fonn 26R 

D Other (specify) 

Date Submitted: 

Name of Respo_pslble Official 

Date 2-28-11 

-3-
Form 26R: Section B 1 e 

GENERATOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and Mure testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the com posited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
y 

Form 26R: Section 83a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.·D.#.(various) 

~~~ 

'\/ ~ -)V,-

/1' 

* COUNTY A 

I \ I 

\ / Well I. D.# (various) 

\ I :::b/ 

\ I /II' 

\ I / 

\ I // 

\ I // 

. \ I / 

Well I. D.# (various) \ I // 

- COUNTYB 

'-\/ / \ I / 

-0.- / ~ / ...,...-_ ' . 

u "I of!~....\..~;~ Mobile Tank Truck 

'fr-oc\h.-\ 10" Ocu 1\\i..~-\ \OA~S :! ( 

U S brine ('TYP.) 

Note: . Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedures. 

-----Landfill orTru.J~v.+ 'P\Wlt . 

() 

~ UJ 

:I: 

() 

CJ) 

z 

0 

~ 

~ 0 

0.. 

CJ) 

z 

~ 1-

~II If. ~~~- j 

... ~ ~ 

i I § I ~ 

~~ ~ 

h-llll " ~ 

I

t: i i~ 

.I U 

g i I 

il 
RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: Order No.: 01101912 . 

Geochemical Testing received I sample(s) on 1/28/2011 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 

.. ,.., 
No problems were encountered during analysis of this workorder, except if noted in this report. 

The ethylene gycol analysis was subcontracted to Free Col Labs. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. 

J - Indicates an estimated value. 

U -The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit 

B - Analyte detected in the associated Method Blank 

Q- Qualifier QL -Quantitation Limit DF - Dilution Factor 

R - RPD outside accepted recovery limits 

E - Value above quantitation range 

••- Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL - Contaminant Limit 

I. D. 56-00306 PA DEP 
Project: 

Lab ID: 

Matrix: 

Analyses 

26R Analysis 

Gli01912-00I 

AQUEOUS 

INORGANIC NON-METALS 

Acidity to pH 8.2 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 

PHYSICAL TESTS 

Specific Conductance 

PH BY SM 4500 H+B 

lab pH 

INORGANIC NON-METALS 

Total dissolved solids 

PHYSICAL TESTS 

Total suspended solids 

INDICATOR ORGANIC PARAMETERS 

Result 

-38 

150 

111000 

6.52 

97500 

545 

BOD 5-day 1350 

Finish Date/Time 212/2011 18:10 

REACTIVE CYANIDE 

Reactive cyanide 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 

INORGANIC NON-METALS 

Bromide 

Chloride 

Sulfate 

INORGANIC NON-METALS 

MBAS 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 

INORGANIC NON-METALS 

Nitrate - Nitrite 

INDICATOR ORGANIC PARAMETERS 

Phenolics 

REACTIVE SULFIDE 

Reactive sulfide 

INORGANIC NON-METALS 

< 0.25 

5800 

461 

57100 

< 100 

< 0.25 

69.1 

0.53 

< 100 

0.50 

Sampled By: Client 

Collection Date: 1/28/2011 1:10:00 PM 

Received Date: 1/28/2011 7:08:50 PM 

QL Q Units DF Date Analyzed 

SM·2310B(4A) Analyst: LNW 

0 mg!LCaC03 2/412011 9:44:00 AM 

SM 18 23208 Analyst: LNW 

5 mgll.CaC03 2/312011 4:50:00 PM 

EPA 120.1 Analyst: LNW ~hos/an 21312011 4:50:00 PM 

SM4500-H+B Analyst: LNW 

0 su 2/3/2011 4:50:00 PM 

SM 2540C Analyst:· KLS 

100 mg/L 5 1/3112011 7:10:00 AM 

SM 2540D Analyst: KLS 

25 mg!L 5 113112011 7:17:04 AM 

SM 5210 B Analyst: SAG 

300 mg/l 300 112812011 6:50:00 PM 

0 mgll. 300 112812011 6:50:00 PM 

SW846 CH.7 Analyst: SAG 

0.25 mg/Kg 0.99 219/2011 4:58:00 .PM 

HACH 8000 Analyst: MGV 

50 mg/L 5 2/112011 

EPA300.0 Analyst: CAS 

10.0 mg/L 50 1/3112011 2:51 :00 PM 

50 mg/L 50 113112011 2:51:00 PM 

100 mgll 50 1/31/2011 2:51 :00 PM 

SM 5540C Analyst: CAS 

0.25 H mgll as LAS 5 2/2/2011 2:30:00 PM 

EPA 350.1 Analyst: SLY 

. 5.00 mg/L as N 50 2/10/2011 12:51 :01 PM 

EPA 353.2 Analyst: SLY 

0.05 mgll as N 2/1/2011 10:14:21 AM 

EPA420.1 Analyst: KMW 

100 IJ9/L ·s 2/4/20111 :05:00 PM 

SW846 CH.7 Analyst: SLY 

0.25 mg/Kg 0.99 2/3/2011 2:50:00 PM 

EPA 351.2 Analyst: SLY 

-·------ ---------·-···- -· . . ·--- ~ ~ .. u ... * " 
y

Sampled By: Client 

Lab ID: 01101912-00t Collection Date: l/28120 11 1:10:00 PM 

Matrix: AQUEOUS Received Date: 1/2812011 7:08:50 PM • • •• • - - ' oo o n- • • • ••• ••• •• •••--•• 

Analyses Result QL Q Units DF Date Anal_yzed 

INORGANIC NON-METALS EPA 351.2 Analyst: SLY Total Kjeldahl Nitrogen 61.4 20.0 mg/L as N 2.0 2/1/2011 2:35:48 PM 

INORGANIC METALS EPA200.7 Analyst: MS 

. Iron, dissolved 10.5 0.05 !l19'l 2/1/2011 12:26:00 PM 

INORGANIC METALS SM 31128 Analyst: JEK Mercury <0.20 0.20 IJg/1,. 2/1/201112:53:33 PM 

TCLP METALS EPA 7470 Analyst: JEK Mercury <0.0002 0.0002 mgll 1 2/1/2011 12:49:15 PM 

TCLP METALS EPA6010 Analyst: MS Arsenic < 0.020 0.020 mgll 1 2/1/201112:18:00PM 

Barium 3190 150 ** mg/L 500 21312011 10:31:00 AM 

Cadmium <0.002 0.002 mg/L 2/1/2011 12:18:00 PM 

Chromium < 0.010 0.010 mg/L 2/1/2011 12:18:00 PM 

Lead < 0.020 0.020 mg/L 2/1/201112:18:00 PM 

Selenium < 0.020 0.020 mgll 1 2/1/201112:18:00 PM 

Silver <0.005 0.005 mg/L 1 2/1/201112:18:00 PM 

INORGANIC METALS EPA200.7 Analyst: MS 

Aluminum < 1.0 1.0 mg/L 10 2/1/201112:22:00 PM 

Arsenic <0.20 0.20 mg/L 10 2/1/2011 12:22:00 PM 

Barium 2850 5.00 mgiL 500 21312011 10:35:00 AM 

Beryllium < 0.010 0.010 mg/L 10 2/1/2011 12:22:00 PM 

Boron 2.58 0.50 mg/L 10 2/1/2011 12:22:00 PM 

Cadmium < 0.020 0.020 mg/L 10 2/1/2011 12:22:00 PM 

Calcium 7470 25.0 mgll 250 213/2011 10:38:00 AM 

Chromium < 0.10 0.10 mgll 10 2/1/201112:22:00 PM 

Cobalt 0.544 0.050 mg/L 10 2/112011 12:22:00 PM 

Copper < 0.10 0.10 mg/L 10 2/112011 12:22:00 PM 

Iron 46.9 0.50 mgll 10 2/1/2011 12:22:00 PM 

Lead <0.20 0.20 mg/l 10 2/1/2011 12:22:00 PM 

Lithium 60.3 5.00 mg/L 500 2/3/2011 7:41:00 PM 

Magnesium 638 1.0 mgll 10 2/1/2011 12:22:00 PM 

Manganese 3.47 0.10 mg/L 10 2/1/2011 12:22:00 PM 

Molybdenum <0.20 0.20 mg/L 10 2/1/2011 12:22:00 PM 

Nickel < 0.10 0.10 mg/l 10 2/1/2011 12:22:00 PM 

Selenium < 0.20 0.20 mg/L 10 2/1/201112:22:00 PM 

Silver < 0.050 0.050 mg/L 10 2/1/2011 12:22:00 PM 

Sodium 1510 100 mg/L 500 2/3/2011 7:41 :00 PM 

Strontium 1350 2.50 mgll 250 2/3/2011 10:38:00 AM 

Zinc < 0.10 0.10 mg/L 10 2/1/2011 12:22:00 PM 

--

---~- - ·---·-·-·----- -- ...... - - --·· -···· - -

. ···---···---------- ----- ·····------------------------·-···--·----------- ---· -------- -··· -· -- -

.:;> 

~ 

.. 

<.o ~ * 

- " -
: AQUEOUS 

Analyses 

INORGANIC METALS 

Hardness (SM 23408) 

INORGANIC METALS 

Thorium 

· Uranium 

TCLP HERBICIDES 

2,4,5-T 

2,4-0 

Silvex 

Surr: 2,4-Dichlorophenyt acetic acid 

TCLP PESTICIDES 

Chlordane 

Endrin 

Lindane 

Methoxychlor 

Toxaphene 

Heptachlor (and its epoxide) 

Surr: Decachlorobiphenyt 

Surr: Tetrachloro-m-xytene 

SEMI-VOLATILE COMPOUNDS: TCLP 

2-Methylphenol 

2,4-0initrotoluene 

Hexachlorobenzene 

Hexachlorobutadiene 

Hexachloroethane 

Nitrobenzene 

Pentachlorophenol 

Pyridine 

2,4,5-Trichlorophenol 

2,4,6-Trichlorophenol 

3.4-Methytphenol 

Surr: 2,4,6-Tribromophenol 

Surr: 2-Fiuorobiphenyt 

Surr: 2-Fiuorophenol 

Surr: Nitrobenzene-d5 

Surr: Phenol-d6 

Surr: p-Terphenyl-d14 

VOLATILE ORGANIC COMPOUNDS 

Benzene 

Result 

18500 

<200 

<200 

< 0.0050 

< 0.020 

<0.0050 

74.9 

< 0.010 

<0.00050 

< 0.00050 

< 0.00050 

< 0.020 

< 0.0010 

96.3 

64.3 

< 100 

< 100 

< 100 

< 100 

< 100 

< 100 

< 500 

<200 

< 100 

< 100 

< 100 

101 

49.3 

60.4 

86.7 

51 .7 

38.8 

< 1.0 

Received Date: 1128/2011 7:08:50 PM 

QL Q Units DF Date Analyzed 

EPA200.7 Analyst: MS 

10.0 mgJLCaC03 10 211/201112:?2:00 PM 

EPA200.8 Analyst: JEK 

. 200 IJg/L 200 21812011 3:03:00 PM 

200 IJg/L 200 21812011 3:03:00 PM 

EPA 8151 Analyst.: NPT 

0.0050 mgll 100 213/2011 10:39:30 PM 

0.020 mg/L 100 213/201110:39:30 PM 

0.0050 mg/L 100 213/2011 10:39:30 PM 

28.5-130 %REC 100 213/2011 10:39:30 PM 

EPA8081 Analyst: NPT 

0.010 mgll 10 21212011 7:07:46 PM 

0.00050 mgll 10 2!212011 7:07:46 PM 

0.00050 mg/L 10 21212011 7:07:46 PM 

0.00050 mg/L 10 21212011 7:07:46 PM 

0.020 mgll 10 21212011 7:07:46 PM 

0.0010 mg/L 10 21212011 7:07:46 PM 

5-156 %REC 10 21212011 7:07:46 PM 

15.9-102 %REC 10 21212011 7:07:46 PM 

EPA8270 Analyst: JB 

100 IJg/L 10 214/2011 6:48:00 /lN. 

100 IJg/L 10 214/2011 6:48:00 /lN. 

100 IJQ/L 10 214/2011 6:48:00 /lN. 

100 IJg/L 10 214/2011 6:48:00 /lN. 

100 IIQIL 10 214/2011 6:48:00 AM 

100 1J91L 10 214/2011 6:48:00 AM 

500 IJg/L 10 214/2011 6:48:00 /lN. 

200 IJQIL 10 214/2011 6:48:00.AM 

100 IJQ/L 10 214/2011 6:48:00 AM 

100 IJg/L 10 214/2011 6:48:00 AM 

100 119/L 10 214/2011 6:4.8:00 AM 

5-137 %REC 10 214/2011 6:48:00 AM 

27.7-95.1 %REC 10 2/4/2011 6:48:00 AM 

5-104 %REC 10 214/2011 6:48:00 AM 

16-101 o/oREC 10 214/2011 6:48:00 AM 

5-106 %REC 10 214/2011 6:48:00 AM 

25.4-133 %REC 10 2/4/2011 6:48:00 AM 

EPA8260 Analyst: SJM 

1.0 119/L . 1/31/2011 7:02:00 PM 

--------

------------------··---------------·------------

.. 

~ 

... « ~ " ~ < " ~ ~ 1.0. 56-00306 PA DEP 

Paae 5 of 7 
Matrix: AQUEOUS Received Date: 1/28/20ll 7:08:50 PM 

-------·---------··--·----- ----------·-----------------------------

-

. 

--· Analyses 

VOLA TILE ORGANIC COMPOUNDS 

Toluene 

Surr: 1,2-Dichloroethane--d4 

Surr: 4-Bromofluorobenzene 

Surr: Toluene-d8 

Result 

1.1 

10S 

102 

95.3 

VOLATILE ORGANIC COMPOUNDS: TCLP 

~nz~ <00 

Carbon Tetrachloride < 00 

Chlorobenzene < 00 

1,1-Dichloroethene < 50 

1,2-Dichloroethane < 50 

1,4-Dichlorobenzene < 00 

Trichloromethane < 50 

Methyl Ethyl Ketone < 250 

Tetrachloroethene < 00 

Trichloroethene < 50 

Vinyl Chloride < 50 

surr: 1,2-Dichloroethane-<14 90.7 

Surr: 4-Bromofluorobenzene 99.7 

Surr: Dibromofluoromethane 92.0 

Surr: Toluene-d8 97.0 

INDICATOR ORGANIC PARAMETERS 

Oil & Grease 436 

NOTES: 

QL Q 

EPA 8260 

1.0 

70-130 

70-130 

70-130 

EPA8260 

50 

50 

50 

50 

50 

50 

50 

250 

50 

50 

50 

70-130 

70-130 

70-130 

70-130 

EPA 1664 

5 

Units 

ll91L 

%REC 

%REC 

%REC 

J.I9IL 

J.191l 

J.lg/L 

J.lg/L 

ll91L 

J.19IL 

J.191l 

J.191l 

J.IQIL 

J.I9IL 

J.I9IL 

%REC 

%REC 

%REC 

%REC 

mgll 

DF Date Analyzed 

Analyst: SJM 

113112011 7:02:00 PM 

113112011 7:02:00 PM 

113112011 7:02:00 PM 

1/3112011 7:02:00 PM 

Analyst: JAW 

50 2/312011 4:31 :00 AM 

50 2/3120114:31:00AM 

50 21312011 4:31:00 AM 

50 21312011 4:31 :00 AM 

50 213120114:31:00AM 

50 2/3/2011 4:31:00 AM 

50 2/312011 4:31 :00 AM 

50 213/20114:31 :00AM 

50 2/3/20114:31:00AM 

50 213120114:31 :00AM 

50 21312011 4:31:00 AM 

50 213120114:31:00AM 

50 21312011 4:31 :00 AM 

50 21312011 4:31 :00 AM 

50 213/2011 4:31:00 AM 

Analyst: DSZ 

1.08 21112011 8:48:00 AM 

J- Unable to obtain a stable weight within specified limits due to sample matrix. Value is estimated. 

VOLA TILE ORGANIC COMPOUNDS 

Ethylene Glycol < 550 

RADIOLOGICAL TESTING 

Gross Alpha 7229 +- 1675 

Gross Beta 1048 +-- 748 

RADIOLOGICAL PARAMETERS 

Radium 226 1638 +- 307 

RADIOLOGICAL PARAMETERS 

Radium 228 199 +- 39.2 

INORGANICS NON-METALS 

Corrosivity Characteristic 6.55 

FLASH POINT 

EPA8015 

550 

EPA 900.0 

3.00 

4.00 

EPA 903.1 

1.00 

EPA 904.0 

1.00 

EPA 9040 

1.00 

EPA 1010 

P~nA R nf7 

mgll 

pCVL 

pCill 

pCill 

pCill 

su 

Analyst: SUB 

217/2011 

Analyst: SUB 

2110/2011 

2110/2011 

Analyst: SUB 

211812011 

Analyst: SUB 

2/1812011 

Analyst: RLL 

1131/2011 

Analyst: RLL 

1.0. 56-00306 PA DEP 
Matrix: AQUEOUS Received Date: 1/2812011 7:08:50 PM 

--

·~~ --- -- -- --- -·----·· ··-··· --------- ··-------------------- ---· .. - · . --- ---·-- ----------------- ------- --------- -- ----

... . . 

-- Analyses 

FLASH POINT 

Flashpoint 

TCLP ZHE EXTRACTION 

TCLP,ZHE 

TCLP EXTRACTION 

Extraction Fluid Used 

Final pH. 

Initial pH 

pH with HCI 

pH with water 

TCLP, non-volatile 

TCLP, ZHE 

Result QL Q 

EPA 1010 

>200 10.0 

EPA 1311 

RL 1.0 

EPA 1311 

NA 0 

3.1 1.0 

NA 1.0 

NA 1.0 

NA 1:0 

NA 0 

NA 0 

Units 

•f 

DF Date Analyzed 

Analyst: RLL 

2/212011 

Analyst: RLL 

1/3112011 

Analyst: RLL 

1 . 1/3112011 

1 . 1/31/2011 

1/3112011 

1/3112011 

1 1/3112011 

1 1131/2011 

1/31/2011 

• •• •• ·· - - •• -· -····-·- · ---

-- · --·-··. - -- -- -- --- ·-· - --·- -· - --·- - 0 • • - -

. 

I. D. 56-00306 PA DEP 

Pace 7 of 7