AlllDS bDOTEfi

I OH

NBS I '^'S^

Publi- PUBLJGATIONS

cations

QC

LL5753

CHNICAL NOTE

270-4

Selected Values of Chemical

Thermodynamic Properties

Tables for Elements 35 Through 53 in the

Standard Order of Arrangement

*<"?£AU of *^

U.S. DEPARTMENT OF COMMERCE

National Bureau of Standards
k
UNITED STATES DEPARTMENT OF COMMERCE

Maurice H. Stans, Secretary NATIONAL BUREAU OF STANDARDS • A. V. Astin, Director

NBS TECHNICAL NOTE 270-4

ISSUED MAY 1969

Nat. Bur. Stand. (U.S.), Tech. Note 270-4, 152 pages (May 1969) CODEN: NBTNA

Selected Values of Chemical Thermodynamic Properties

Tables for Elements 35 Through 53 in the Standard Order of Arrangement

D. D. Wagman, W. H. Evans, V. B. Parker,

I. Halow, S. M. Bailey, and R. H. Schumm

Institute for Materials Research

National Bureau of Standards

Washington, D.C. 20234

NBS Technical Notes are designed to supplement the Bureau's regular publications program. They provide a means for making available scientific data that are of transient or limited interest. Technical Notes may be

listed or referred to in the open literature.

For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C, 20402

Price $1.25 cents.
PREFACE

Technical Note 270-4 is the fourth part of a series of Notes

containing the tables of material prepared as a revision of Series I of National Bureau of Standards Circular 500, Selected Values of Chemical Thermodynamic Properties, by F. D. Rossini, D. D. Wagman,

W. H. Evans, S. Levine and I. Jaffe. This Note contains data for compounds of nineteen elements, numbered 35 through 53 in the Standard Order of Arrangement. In addition the Appendix contains

a list of corrections for errors and nnisprints which have been

detected in the previous summary Note TN 270-3. Data for compounds

of elements numbered 1 through 34 are contained in TN 270-3.
CONTENTS

Preface ii Intr oduc tion v Standard Order of Arrangement x

Table 35 Mercury 1 Table 36 Copper 13 Table 37 Silver 29 Table 38 Gold 39 Table 39 Nickel 43 Table 40 Cobalt 54 Table 41 Iron 74 Table 42 Palladium 90 Table 43 Rhodium 93 Table 44 Ruthenium 94 Table 45 Platinum 96 Table 46 Iridium 103 Table 47 Osmium 104 Table 48 Manganese ^06

Table 49 Technetium 116 Table 50 Rhenium 117 Table 51 Chromium 120 Table 52 Molybdenum 129 Table 53 Tungsten 134

Appendix 139 Index 140

SELECTED VALUES OF CHEMICAL THERMODYNAMIC PROPERTIES

by

Donald D. Wagman, William H. Evans, Vivian B. Parker,

Iva Halow, Sylvia M. Bailey, and Richard H„ Schiomm

INTRODUCTION

Substances and Properties Included in the Tables

The tables contain values where known of the enthalpy and Gibbs

energy of formation, enthalpy, entropy and heat capacity at 298.15°K

(2 5°C), and the enthalpy of formation at 0*^K, for all inorganic substances

and organic molecules containing not more than two carbon atoms. In some instances such as metal -organic compounds, data are given for substances in which each organic radical contains one or two carbon

atoms. No values are given in these tables for metal alloys or other

solid solutions, fused salts, or for substances of \indefined chemical

composition.

Physical States The physical state of each substance is indicated in the column

headed "State" as crystalline solid (c), liquid (liq), glassy or amorphous

(amorp), or gaseous (g). Solutions in water are listed as aqueous (aq).

For non -aqueous systems the physical state is that normal for the indicated solvent at 298ol5°K,

Definition of Symbols

The symbols used in these tables are defined as follows: P = pressure; V = volume; T = absolute temperature; E = intrinsic or

internal energy; S = entropy; H = E + PV = enthalpy (heat content);

G = H - TS = Gibbs energy (formerly the free energy); Cp = (dH/dT)p = heat capacity at constant pressure.
Conventions Regarding Pure Substances

The values of the thermodynamic properties of the pure substances

given in these tables are for the substances in their standard states (indicated by the superscript " on the thermodynamic symbol). These

standard states are defined as follows: For a pure solid or liquid, the standard state is the substance

in the condensed phase under a pressure of one atmosphere.

For a gas the standard state is the hypothetical ideal gas at unit fugacity, in which state the enthalpy is that of the real gas at the same

temperature and at zero pressure. The values of A Hf and AGf* given in the tables represent the change

in the appropriate thermodynajnic quantity when one gram -formula

weight of the substance in its standard state is formed, isothermally at the indicated temperature, from the elements, each in its appropriate

standard reference state. The standard reference state at Z5"C for each element except phosphorus has been chosen to be the standard

state that is thermodynamically stable at 25 "C and at one atmosphere

pressure. For phosphorus the standard reference state is the crystalline

white form; the more stable forms have not been well characterized

thermochemically. The same reference states have been maintained for

the elements at "K except for the liquid elements bromine and mercury,

for which the reference states have been chosen as the stable crystalline

forms. The standard reference states are indicated in the tables by the

fact that the values of A Hf " and A Gf ° are exactly zero. The values of H^q^. -Hq represent the enthalpy difference for the given substance between 298.15*K and CK. If the indicated standard

state at 25 "C is the gas, the corresponding state at "K is the hypothetical ideal gas; if the state at 25 °C is solid or liqiiid, the corres- ponding state at "K is the thermodynamically "stable^crystalline

solid, unless otherwise specifically indicated. The values of S " represent the virtual or "thermal" entropy of the substance in the standard state at 298.15°K, omitting contributions from

nuclear spins. Isotope mixing effects, etc. , are also excluded except

in the case of the hydrogen -deuterixim ( H-^H) system. Where data have

been available only for a particular isotope, they have been corrected

when possible to the normal isotopic composition.

The values of the enthalpies of formation of gaseous ionic species are computed on the convention that the value of AHf " for the electron

is zero. Conversions between and 298.15°K are calculated using

the value of H298 H, 1.481 kcal per mole of electrons, and assximing

that the values of H|Qg-H5 for the ionized and un-ionized moleciiles are

the same.
Conventions Regarding Solutions

Solutions in water are designated as aqueous (aq); other solvents are designated by name or chemical formula. The concentration of the solution is expressed in terms of the number of moles of solvent associated with one mole of the solute. If no concentration is indicated, the solution is assumed to be "dilute". The standard state for a solute in aqueous solution is taken as the hypothetical ideal solution of unit molality (indicated as "std. state, m = 1"). In this state the partial molal enthalpy and heat capacity of the solute are the same as in the infinitely dilute real solution. For non- aqueous solutions the standard state of the solute is the hypothetical

ideal solution of unit mole fraction of solute ("std. state, X2 = 1"). The value of A Hf " given in the tables for a solute in its standard

state is the apparent molal enthalpy of formation of the substance in the infinitely dilute real solution. At this dilution the partial molal

enthalpy is equal to the apparent molal quantity. At concentrations

other than the standard state, the value of A Hf ° represents the apparent

enthalpy of the reaction of formation of the solution from the elements

connprising the solute, each in its standard reference state, and the appropriate total number of moles of solvent. In this representation

the value of A Hf " for the solvent is not required. The experimental value

for a heat of dilution is obtained directly as the difference between the two values of A Hf " at the corresponding concentrations.

The values of the thermodynamic properties tabulated for the individual ions in aqueous solution are based on the usual convention

that the values of AHf% AGt", S" and Cp* for H"*" (aq, std. state, m = 1) are zero. The properties of a neutral electrolyte in aqueous solution

in the standard state are equal to the algebraic sum of these values for

the appropriate kin^s and number of individual ions assumed to constitute

the molecule of the given electrolyte. When the undissociated species,

rather than the s\im of the ions, is meant, the notation "undissociated"

or "un-Ionized" is used. For an ionic species the properties tabulated refer to thatxindissociated ion. By adopting the above convention with

respect to aqueous H , it follows that the thermodynamic relation A Gf * = A Hi" - T A Sf " will not hold for an individual ionic species. However

no problem arises when neutral chemical systems are considered.
Unit of Energy and Fundamental Constants

All of the energy values given in these tables are expressed in terms

of the thermochemical calorie. This unit, defined as equal to 4.1840

joules, is generally accepted for the presentation of chemical thermodynamic data. Values reported in other units have been converted to calories by means of the conversion factors for molecular energy given

in Table A. The following values of the fundamental physical constants have

been used in these calculations: R = gas constant = 8.3143 + 0.0012 J/deg mol = 1.98717 ± 0.00029

cal/deg nnol F = Faraday constant = 96487. + 1.6 coulombs /mol

= 23060.9 ±0.4 cal/volt equivalent

Z = Nhc = 11. 96258 + 0. 00107 J/cm"^ mol = 2. 85912 -k 0. 00026 cal/cm"^ mol

C2 = second radiation constant = hc/k = 1.43879 ± 0.00015 cm deg

0»C = 273.15*K

These constants are consistent with those given in the Table of General

Physical Constants, recommended by the National Academy of Sciences - National Research Council . The formula weights in the tables have

been calculated for the molecular formula given in the Formula and

Description column using the 1961 Table of Relative Atomic Weights based

on the atomic mass of ^ C = 12 exactly . Internal Consistency of the Tables

All of the values given in these tables have been calculated from

the original articles, using consistent values for all subsidiary and

auxiliary quantities. The original data were corrected where possible

for differences in energy units, molecular weights, tennperature scales,

etc. Thus w^e have sought to maintain a uniform scale of energies for

all the substances in the tables. In addition the tabulated values of the properties of a substance satisfy all the known physical and thermodynamic

relationships annong these properties. The quantities A Hf ", A Gf, and

S° at 298. 15 "K satisfy the relation: A Gf° = A Hf° - T ASf.

NBS Technical News Bulletin, October 1963.

'A. E. Cameron and E. Wichers, J. Am. Chem, Soc. 84, 4192 (1962).
Furthermore the calculated value of any thermodynamic quantity for a reaction is independent of the path chosen for the evaluation.

In some cases newer data may have become available on certain

substances after the values were selected for these tables. Because

of the need to maintain the internal consistency of the tables, it is not always possible to incorporate these newer data into the tables without

a detailed analysis of the effect of such a change. Unless great care is used, relatively significant errors in calculated values of A H" or A G"

for specific reactions may result from the introduction of such data. Uncertainties

The uncertainty in any value in the tables depends on the vmcertainties of all the determinations in the total chain of reactions used to establish the value. A discussion of the uncertainties will be included in the final publication of these tables in the National Standard Reference Data System. However we have followed certain rules with respect to significant figures to indicate these uncertainties. Values are tabulated

in general such that the overall uncertainty lies between 2 and 20 units

of the last figure. On the other hand, values are given so that the experimental data from which they are derived may be recovered with an accuracy equal to that of the original quantities. Thus the number

of significant figures for any one value in the tables need not represent

the absolute accuracy of that value. For solutions of varying composition

values are frequently tabulated to more figures to make possible the recovery of enthalpies of solution and dilution. Similarly values of A HfQ and AHf^og ir may be given to different niombers of significant

figures. In this instance the quantity with the lesser number of figures

is used to represent the uncertainty estimate. The larger number of figures is used for the other quantity to retain the significance of the temperature correction term. Arrangement of the Tables

The compounds in the tables are entered according to the Standard

Order of Arrangement, (see Figure 1), by the principle of latest position.

In this scheme, a compoimd is listed under the element occurring latest

in the list; water of hydration is neglected. Within a given elementtable will be found all of the compounds of that element with elements

occurring earlier in the order; the arrangement within a table follows

the same ordering. An exception occurs in the carbon tables (Table 23), which is divided into subgroups consisting of all compounds with one carbon atom, then all with two carbon atoms, etc.
(mC^ /o^ /°^ f^^^ {of^ /oM \(D<nJ 1 2 o»y\oo>yl to o>) 1 0Do>/~\a: oy

«HO -P

-+Ja

(1) H rH

(0 • r- H ^ a) J5 -P ^1 ^ ^ ?n O •H «H Cm l^ O

0)

fH rH

Q) riJ01

f^ Eh "

CD T) ^ •

fM -P (D 1

•H •H

4^ t:! h4

L') a) -p fl) eri o o

o i.Q H Of ® <n a ^

1

E <D ^••^ oo g fjgHi SH^iHSqVu?
O>

in

<=> s

CD X

COO

in -2CD "

CO X

CO

<1<

,-. O o X

ino o

CO

CO

in S22 X

CM*

CSl o

oi X

CO

CSl - OOJso 5 2

COCO

^2

CO

CO

CD O

^- 1]! c- X

00

00

CO

CDo"o

CO

CD O

03 -

CO

in

COo

00 a

CO

(M

05

05

C^d

CD

00

CSl

<| X in

CO

CO

'^

in -

05

CSl

in* o

CO O ^ X

I>

CSl

CD -2

CO X

CD

00

CO o S X

00

CS) - 1 _, o 5 X

cd'

CD ^2

?^ X

CO

CO*

CO

05 O

CD

CSl s

006o

CSl CD

03

05

CM

OS

CM5^ - S X

in

CO

in

in

02

c^'

CSl

CDo

oo'

CS] in

COCM

in

C35

CO -

CO o S X

cvi

(M

CD00

t~ o

CO —

05 s,; in '^ in

in

CSl 05

in00

co'

055 d

CDo

COCO s - i

CO o

in

C^3 Od ooo

o"o

CD

CO* oo

CD

COCO

CSl

00

in

C<1 CD

C35 o

c-' 00

CD05

'oao

-3S

COBo H-3 H'os1 Hos

's oo>

(U is Si

TABLES OF SELECTED VALUES OF PROPERTIES

SERIES I

Enthalpy of Formation at CK

Enthalpy of Formation at 298. 15°K

Gibbs Energy of Formation at 298. IS^K

Enthalpy at 298. 15°K

Entropy at 298. 15 "K

Heat Capacity at 298. 15°K

Hg-Hg(OH)

35

O O VD r-<

C M

CM CM CM

S 8
HgF

35

VD 00 u a

vO e

00 00 Q

c ^ 00 o>

-; o Ov O

C w (J t»i r4 CM 00 -* rJ O o vo o^ I-< ,-( vD CO CO <!• * -*

ic

to O

00 US

cs

cm"

1:^ OCM ^

X

00

p. n) (VJ O • -* in I-< o CO r^ <t cr> 00 CO I-l vO CM

4^ 8

oJ CJ^ -* in i-H C<4 ^ CO vo o CM vo ^'

n) o ^ <)• t^ o CO

(U 1 1 I-l 1 I ' -0c £

n) ^

^

"rt -< •* %

o 00 i-i in ^O r^ CO ^^ o <y. vj- CO in 00 <!• CM I-l O

c

J>i ^ r^ o <*

• ^ <f CO r~. CM* ^ d 00 i-I rH n 1 ? 7

in in vo o 2vo <t CO -* -* W

c

rt oo i^ . E P ^ o CM o i

d 00 r- "pT" ^ ON "TT~VD~~"^

~oo~ >

r~ <!• (3^ <t o 00 (j\ o

"? -5, to <-< o -* •* O -* >*

>H £ .?? o^ <jC vC ^ VO CM CM CO o U u <u CO CO CD o- oo 1 ^^ CM -d- CM CO 5 CO a 60 «r o 60 D" o cr T o* (J a* (J cr

rt o O <3 a « o a

T3 w

C

rta

^ ^ £ C ^ •\ c u 0) CD u O. JJ "d c CO 01

rt c

n)C u

(0 J3 a> ^ ^

•a ^ 1 ^ u

3 D

m z 01 (U <u s <u OJ 0) c 5

8" S I fs a s g g

s„

ra 01 CO X 01 m CO X

3 m X cs

<i "s u o o c/^ o "O a "O •o T3 £ c c c u u u C c c

Ci 01 01 3 •H T-l •r^ 01 01 m 3

CO fc

"rtc 1 ii + <t 1-4 + 2

.13 + fa i-l I-l o U u

fa fa

C>0 % ^ % S, & 60

pq60PQ60 X w X P5 E PC K a 33 X a
Hgl.

VD as o

ON vo ao £

<f -*

I-l

73

in vo

rt CO

CO CNJ <t C-J ^ o r-T 0^ CO o CM

VO ^ -* vo -* o- O

00

in

CO 1

00CO

>- .jS ^ a CX5 a O^ 00 ^ U o o r~- CM r-~ -* in CO CO o

4^ a

cJ 00 CO 00 r^ CjC <r <) 00

(T) X

VD 00 t

CO CO <-< I-l ^ ' ' ' ' ' ' 1 ^

13

a- 5 1

r-l 9 -d- OO VO CM CO in CO CM vo r-i o CO CM X O CO • • 00 CM in * * o * vi- <t <Ti CO o -* ^ CO ^ <f CM 1 T i-l rH 1 1 1 1 ' ' ' o o CM vo OO W £ 1

4^ <A cl ^ o * 1

!:: S

rt r^ VO 00 r~. r- VO KO CM <f 0^ ^ CJ> (Ti 00 in cr. '3 ;c CO °i "i "^

I-l r-- CJN -* £.5? o o vo CO d vo sd-

(U Ii 4) <f CM I-. c^ tH CM in c ^°^ ^ in in r- O CM CO <f W

(U tr c o O O o o 60 cr 00 o* o y 00 D"

rt ca 0) as a) CS

T3 W C

ni>- r-lh C u V i & 4J c n

ni 1- XI

<i I 1 h g s 3 m z W m

<u <u (U 0) XI JJ 4J u in c cs <<) a <a o a: o

rt 4-) 4J •M g O o o n) m B o O 3 TJ T) •o -o TJ "O £

4-) 4J

ii a c c B

CO ra (0 CO >. 3 1-1 1-1 tnCO fc o ^ ISCO <J- V

CO >3 J^ 3 "g P9 M ^ u u +M CM

(4 ra CQ « M M M n M H H

OO 00 ^" 60 60 W PS ^ ^

60 1^ ^ ig'
Hgl,

-* ^ «*

in In in

<f

r-( i-i CO

01

1) TJ ^ VO

00 in 00

nJ to o u

•^ 00 mm ^ S

VD c^ r-l o

-*

?f

5:^ r^ CO

00 ^

CO CM

>. ?r

ur,

n) 00

S. o^ O . in ^ m

00 r. ^. ^ CM ^ -^ O VO in

rt §

in o vi> o vD o ^ ^ CVJ ^ o Q o> n n r-~ vO D 1 1 1 1 ;S I O ' •o

n) ^

>- 1

rt o a CJ o o o -k:

•J2 VO <T. in 00 CO cm' CJ^ ^ CO n in CV4 CO CM r-< cUc 1 1 1 1 I-I r-4 CM ' ' ' h

OO ^ 1 o 2 ^ 1

"o

rt ^

0^ 00 0^ r^ „ ~ ^ CM -* 00 CM CM O > 3 X O o 00

ON ^. o?i ?i

in

;::; 12 ^.

CO ^ E

.2= ^ 00 ^ ^ sT ^ 5

VO C7\ c

I. V 00 o in VD o vO VO ^^ m r-- vo 00 •* VO CM CM <!• r^ ^

J3 o* o M cr cr cr u 00 cr U cr o o Q CO <s <o <a <a a

XI w c

(fl a

"(3 ^ ^ ,-1 k i h 1 c ^ ^ ^

_0

(U <u (0

Id 0. 4J C OS <a

rt y -I 1

IS

01 ^ 1 3 4J i ^ ^ g

•a

CO n SI w c

(U <u <u (U (U 01 u u

<0 m s o a) n) Id CD cj

rt u o 4J u o

rt (0 CO CO CO CO

01 CO ^ ra "5 ^ s S ? i

•o •o s J

•o 1

;*, o eo 3 3 CO m CO 2 ^ m 3 mCO [l< , 1 CM , _« 1 "^ CO P "^H •^ 3 M CM M u m pq CM ^ O >* n * H o a

CM CO CM o C/3 O^

n) i-i M CVJ R H w M CO CM CO H :g> ;§' ^ :§> 00 00 00 §> 00 ^ _^ 1. p"
( Hg^N) ^O. 4H2O

a. E

4) •0

00 nt^ M

ni CO oC

VO VO <f

•sP in ^. in

00 ^

Cvj CM ^ t?

in

00

ni <f U-I •-I -*

rt §

vO r- ^ ^

00 X "o

nJ ^

^

^ 1

ri

r-l "*. °°. 00 in <!• CM CTv CTv ^ ^ 00 cj 00 en 00 r-^ o> ^* <f f^

^< ,-t in t^ r^

1 rH 1 1 CM

' '

1 1

00

r^

OS !: ^

or ^ *. ^ m T a\ s

n

<^ CM CO r~- ~i~ js; 3 ^

o>

u-i 3

00

r-i CM r-~ en

in .-^ in VO «d- 00 D r^ CM CM CM n CM VD r~. <(• VO

<n ^^ CM CM ?! -* 00 CO m in 1^ 00 00 a^ 5

4) cr y 00 00 D" y D- y u y y B

cd CS 6 w

C

ni;^ ^

a II e

rt X c

c u W

C

CO

c

j5

ai

CD

i 3^8 1 °.i

u^ 3

E 1 •H ^ °cMo a

u-i s"- g ^ CN w- en

(l^ CO

CM HIM

CM 'cm ^"'>'^CMO

CM °CM

ni i ^

^

^ CM CM 60 %

^

«" H ^ ^ &

/* ;§> ^" ^ ^ ^ ^ rS' 5 £ £
35 6 u Q 6/ c ^ c • rt

tn' co' d -* VD 00 £

It U 1 Im

CO X

>. •=? h

rt 00 a o

n! rvj U >« "". «^. -* ,

rt K ^

cs V

Csj vO _ ' '

a!c ^o 1

•* 00 vo o^ ov in i-i CM c^ r^ in o ^ 00 ON ^ cJ 1

P^ in vD ON <t d r-! .* CO <f ri d vD

VO <N ^ r^ t-i CM m c ' . ^ CM CM . ^ CM . . £

>* OO « ^ O

U4 1

"o

(4 ^ CM c^ in o m O r^ CN 00 m f-H r^ OO O r-4 >

or 00 OO O r^ m m >a- 00 in 2 ;2 ^_ P| ^^ O O '-<•-' CO E .5?

y£> 00 o^en r- 00 in r~. CM

c-4 in r-! en d CJ t. (U In n r^ 00 o o on cW ^^ CM CTN O^ ,-1 CM CO ^ v3- CO in in VO ON CTN

XI

X3 a cr IT cr (J o o u o o o o o o o o o

rt o o 0

T3 W C

rt:^a

rt x: C cU lU •^ « o.

"d C

fl) 'C 1

XI3W y

IS<u 1 1 1 w -0 i

uT a c

nl CD O4-1 CD 3 a •

"s •o "O •o C-J

4-1 O I-H CO

vO O B o o «-% - ^ ;zrg

(Q m X <N K CO O CO O- 2 S cn fc A^ *<^ fffl g

pe g S ^^cM

rH 1-4 C11)0 CM 00 ON « ^'^ «" Ct" o O O 4h 'cm .^ o o •^ s g CM CM CM 'cm *cm 'cm *cm CM O rH O C-4 CM ^ 1 5 f III! 1
a. "o o

a/ ^

• rt ^ CJ^ in CO

VD VO 2

•* U

1

in

00 ^ >- .j5 h

00* mO M-l CO >-< Ov O OV 00 "

a

^' r-^ ^ in i-J in p-I ^ rt •* CO 00 a\ <-< <f

lU « •* o- CM 1-4 l-l DC O

1 1

' '

' T3

ni ^

rt ^ 1

o l~- O CN r-l O VD VO 00 o rH CO

i^ in .-I <f in 00 VO in CO ^ 1-^ vO CM CM

CM ON <f r^ <t VO 00 cW

c

I 1 CM *? i-< 1 1

' ' ' '

' o OO W

1 O

^ 1

"o VO 0^ t-l <^ ^ CO «^ a\ VO O CO CO >-i S

° TO o

cm

0\ CT\ ^

KD CO

CO o\ O vO 00 CM CO o

°. in r-. <f O O ^

a.

CO -*

00 00 VO r-I o%

IH <U s ^ ?;

<:^ 0> 00 1^ OV TO [-- VO C ^^ -* <r m r-~ CO -* -* in in m CM CO .<j- <!•

r-( CM

J3 a o O O O o o O o o o o O" o* o cr o u

n) ffl CD 6

T3 C^ C

<i>-a

13S C

cW u

G a

to 11 1

*J *J •u c Id <d at

rt u u 4J

rt ca CO a

'5 CM CM a TS ts £ U U 4J 4J 4J r^ pq m U CO « a

00 bO n

in W W w c^r-.

en fc en CO <J aj* f O CM <r K K K „co 1 CM CM 'u ^ ^ S S ^

CO K CM P4 S r~ /-^ '^ «d- u m M • n CO si- VO o ffi <i- O CO o

m CM W M o CM O O CM o fi Cv s *CM ^ ^ CM O O o

n) 60 CQ oT M hf y-T H

1^ 5 H ^" g & B ^

M PC W 2; g rg" 00 ^ ^ a i"
HgCH,

35 w2wa nj H u

OJ „ M <D O E

ai •u CU a QS

ai <« M h I ^ H fa J v« <U > s

^1 u c X U oo

J3J3 w O u T3 oa

lU <

>- > J2 p ^ u c. H U a ^

H^ ii W -o

CM ^iT ^
HgC^H^I

35 ra "o o

n) . o

in

00

in

>- ?l^

n) 00 a o

rt fM

i~^ O ?H w

rt ^ *? X "o 1

nJ ^

rt

. &. 1

o VO rH in <r m in CM o^ c^ cv r^ n 0^ ^ en 00 cn O <f

• " ^ O O ir in en O

1 CM 1 1-4 CM I CN T-i C

1 -< 1 1

CO W

1 o

2

>-

611

rt ^ ^ S ^ VO O in '3 5 in in in in m in S.^f r^ CO in o^ c^ VD

<U u « O o ^

W

to ^^ CM en CM en ^

^

s

rt O o o O M O M O M O M W

c

n! o

>^ u ^ a t4^ "

rt

a) Pu 1

J

•H ^ o ^

^

S §« So,

S S3 S3 g

s

PS

r-4 Jj u u m o

C

J2 O t o si s- if

en g

m B

c c c

'5 o nH o\ E

1^ s g

l-l Mm H

_4) CM m

ffT

l-lCO m 3 ^ W <N

nJ ^ s

"

"T *& % X P3 sc m w w "
HgCN

35 a

o

H

61 •0^ CM CO •*

• o o r,! r^ ^ o m m "^ 3

U

•p? in

00 ^ >. C7\

ir^ 00 a a~

<fl <J\ Ov O in u IW vO <r o vj- CD r-^ CO o

rt a

in 3

CO in CO -* 00 DX "o

T3C £

(U ^

p. 1

(«

(T.^ O m CTv 00 ^ MD r-l ,-1 O- o ^ Cn CO r-I vo ^ in <t <J> 00 CO VD

• in vo ch vO Ov vO m •-' t-i I I CM

'

s o

"o 00 ^

:J

CM >* in 00 VO O o o 0^ r^ >

or O CM VC CM VO 5

O C7V in ^ C7V 3 X

KD Cvl 00 oC CM CD

vo r- ^ 0C3 O

ocj o

« CM in o r- 01 c Ki ^

(^^

>* 0^ CO 5 i cr o 50 cr cr cr u u o O" cr o- a" cr cr cr H

a CO ca CO 0) a aJ o w

c

II t^ E

Jtt. 1 s <u X

1 ^ ^ ^ ^ s ^ ^ 1 1 ^ ,_, C

ID ^

(U

<d I e J

e ^ ^ h

O a. 4J 3

c <u <u <u <u « -0 0) u

rt ^ «j w u 4J o (d cd Kl CJ * <a « m «

-o 4J U •H u 4J •u J3 CO 4J ltd ;4 g> 01 l» .. in in C^ D

a \ . pu

XI •V T3 u •o o •O o •<3 •o

•u 1 u ->-> in JJ u

c <n o in m <n n 01 0) o •H

iS CO A 1 o

3

£

•s

CM + CM rH 3 + '^ ^ o "§> + CM CM 8 § , CO U^ M X '-^ E o o CM

CM en CM ^

X > ^

x'^B O "cn o 2 CO K 3 ff

1 jg* 1 § 1 bO s

»" O g H

tJO ^

60 X t>0 X ^ ^ rg' ^ _i_ K
a 'o o

g

4)

•X}

(i m O

o

-* ^ o o

•^

Ci

CO t>^ >- •Ji ^

s. 00

It o

rvj -* o CM -^ in CO <f

ti 00 d in CM d CO 00 <f

rt ^

i CTV 00 CO vo cjv in VX "o "§

13 ^

^

1

rn r^^ r~- in r-l vD 00 1-^ CM a^ o

2 ^ iri <r cn VD d CO 00 C3^ r^ vo 00 G m vo CO 00 CO 1^ VD t

*

u

c

H 1

CO ^ 1

o

g

"o

rt i-< CTN CO vo CO CO (Jv 00 CO o^ ~^ n3- ~ 00 vt

>- '3 O CM •* Ov o 00 O r~ Ov CN m CO r-l ^ ^ t-1 ^ iri m in O ^ r- r- 00 (Jv CO u S.^ r-^ 0^ vo ^ d 00 00 d •* vo vo •* CM r-^ S

l< D vo t-l o\ CO m i-i CO CO n-< CM PI CO CO CO CO ^ "* CO CO CO ^ in 1

1) D* O D* o 2* cr o o o o D- cr cr o- o

rt a a CO CO CO 55

t-i .

(4 1 1 ^ «

•V 0) 4J 4J

ri CO « a

4J

10 U tH i-i a n •o 11 11 O II II B e e e 4J e e

rt a

u •V o « 0) o 0) XI 4J •p ^ 4J ^ D

c

(0 4J

cn 1

2

(0 o 5

S 5

rt O "O a

"H

•o "O

iJ O 4J 4J 4J u rt n CN 0) o o 3 m CO 's K CM CM nl^ + X ^ ffr* g

CM CM • CM ^\-f + -^ s >j K CM CM <^ O g H ffi cn lO g-^r c

'^p K*S 1 , ci CM =r-<.

«* *!„ w CN ' CO -^'-^ w o CI *CM O *CM CM /-\

4) O ^-s CM o CO 3 :::: 6

o J^ ^

z i > i *CM g g O § s It] O V-' O 1 1

s^ PQ si- 1-1 V^ CM H ^ ^ A _i_ !§> ^ A^ _i A.Z. ^ r^
Q. "o O £

6/

11 a , nj O

°=? in

00 u: ^^ # in o

IT) CO a on5 <! CSI U U-l oJ

rt g

'-* DX

"oE

rt ^ a ^ o lA CTN CO OO <f -^^ ^ x in C<I in o vo 00 rJ

vo r~- on CM OO c t

in "-^ -* ' 1 p

OO ^ ^ o § ^ 1

"o

n)

CSI m ^ in ""c^ t^ o > s

00 ON Cs

"a ^ o £ .?f in <f 00 ^* 1^ -a- ^ 00 in

IH 4) O o\ p~- r^ cU

to t.°^

in ^ CO ^"^ OO -* in o

J3 s cr V Q> o CJ o o o o

rt a a 6 W c

rt h ^

>-a . •

<0 0)

rt 4J w ^ c « «

4J u c n o U oc

XI 1 a o o X ra 10 c «

rt •o o o •o CN o o o

rt c 3= x^ CM 3 r- 3S^ w

?? E + 'cm

CM CO OO -* U

CJ ? u M CO e S 00 fc s "cN ^ ^

NJ Na S s O cq r

CM eg

4J m" CO CM s z ^-N 2 2 z I-H o o s 1 O 3 v-' 3 o H u

rt H

in fcO 00 <-' 5 ^ CM

00 ;^ « s ^ ^K
rn o 00^ ^ ra l^ '-' CM

P- in <f 00 d in o E ^ o C\l <t CM ^ CT\ kD

']^ en F^ LO c^ 00 1^ •-' CN C3N • n) " o> • Q^ co" ^" o CNj' 00 ^ m o u 7 '^ 1

in ^o

<) o

00 ^ • ^ ' t o^ in a

00

vD * o § o

CO O

'^. ^ o

CO -:r 5

o^

1-^

CM* 13

<u

r-^

'"' '"' o "7 -* X

T3

rt ^ VD in CO

CO CO 00 CN ^

>- rt 00 ON <r 00 I-~- vO i-i -*

a. 1 ^ o 'o ^* CJ r^" CJ^ in d lA d in O

^" * C^ o^

00 ^ CM .-1 00 -I <f o vO CM c

.-1 1 1 W

rt ^ e^ es

CO W s ^

ON ^ r- ^ o o §

00 ^' ^

in ^ g

'^

'o

rt ^ ^ ON en 00 ^ ~ 00 ^

>- 9 ^

-* 00 CO -* In

^<

<uG o

ON

'^ O

CO VO

in ^"

"^ < CT. as o h^ "'

XI^ w o 60 cr O- 60 60 o D" o O 6 CJ o* cr o

a) K) CD Id (d C

rt;^a

<i X c E cW a

60 1 ^ ^ ^ ^ ^

rt 11 II II II II ^

10 <U e e E e B 3 D

X)c t

eg a 5

4-1 St «

rt 60 X , . 3 •o o o o o c 4J u m

,_^ u

In CO , , <N « X 3 + + ;)^ CM o cf °CM ffi O o +^ PlT*

rt 3 3 3 3 3 3 3 3 3 H o O o O O o o <J o K O O o
in ^ CM

CN CO O CM

3 X.

cr o- cr a*

.. o I riT

CM CM CM CM CM CM
-

• «i. u E^ CM

( fl) d en

CO O

o •* \D

•^ S

00 u:

>- '^ i

00

(M

oo -* d

<f

rt in -1 vX "og

nJ

];;::^ oocn,-iQOr-~.-i-iooooo <t

>- g m p^ r-~O-<r^00Or-<(M^^f0 CM n 0^ O o

a. IH ^ d in ^" .o vo .o r^ r-^ r~^ r-! r-* vo

* VJD s i i

CJN vD ,-d- in <t 1 >-i vJ- c

1

li P5 oo W

E 1 ^

s

1 o

(fl r^ vO o> CS ^ CO m <t ^

>-. -* ON <^ <t CO 00 ^

cW d

3

oo d

<i; d CO pi ^' u <u r^ vD C«1 <f ^ IM CO oj CO 5

w

cr ccr'crcr'crD'cr'cr'CT'cr o D* CT D" cr o o o o o

-0 tatscacdcoojcamtaS « CI) of

c

nJ>^aH

5 c

c _0 W o

u o

.-i -

II pT KECffiWPCPCpSffipCffi E E g

lU oooooooooo o S D

m lAinmrninintrjiounm W CM W ffi ffi W WffiKffiKK <u OJ k"^ m 1 UOUOOOUOOU CNJCMCMOMCMCMCMCMCMCN 4J

s) n) (4 o 4J jj

It ffi mr^-omOioOOOO

a .-l.-ICMCMCnu-lOO ^ CM E

T3 o

c JJ o

CO M CM ffT

en o

CnI f O

IM 3 6 ^ O o en '^ <f CM CO CO o o O -1 . a 5 8^^ 3 o O

o o O ii CM O o nl 3 3 3 3 3 3 3 3 H " o O O o O 6 6 6 o
" ^ 1 CM CO -* o °i

-* ON •c"^ g

'-' -^ '-' ^ <^ o

ON 00 ON CJN o

<< 00 ON oc> o^ w

p" o CM vO CO CM CM

•pP Ci s

oo :<: CM

>^ 0^ ^ O

00

CM ^ ON CM CN4 vO m o o CO NO o CM c^ ^

'a o <t ^o VO VD o d CM

CM o v£> vO CO 1 n ^ I 1 .-1 .-H 1 1 •-I .-1 _ ' ' ' ' ' ' ' •oc E a vO -*

>. 1

rt O (TV in o •* o CO 00 o j^ C^ oo" NO d IS

CnI <r. -*

CM 7 t ^ ?;CTv '^ 00 o c ' ' ' I Uco vO If

•o

J^ o

(X•o

<« u-i CTv 00 CT% CM OS :J

U1 ,_( CJN s

~t CM CM

4)CU

01 m 5 m ^ <t o 11 CO O O 5_

CO

CO

vO NOON CO CJN U V -* ON s

r-l O o^ in ^S' > c^ CM m vO <! <r ^ "

J3 i! J3 O O cr cr o o cr tr cr

rt ca CO « 0) td a 5

•o

«5 c ^

>-

II O. e

rt ^

.c c «r

lU S) a c

nl II II <D u o to e E E ^ D 3 O W <u CM <u 1

3: jj

0) D) s) o o o

(t III o

rt

<1- 3= "5 •o O •C3 X o' o •o u c O^ c

00 3 « n ra 3

,-^ 1 ^ o

-* o x^ 1 I

(b O CN 3 'cm n X O f

CO Qo X O CO CO CO

0) o + O o o ^ 3 u ^^ U u >J pa M i-i I-I M O^ O

CM m PQ CQ ta pa w

(4 3 3 3 3 3 3 3 3 3 3 3 H O O o O O u o O U U o o o O o
36

£ S

•p?

O l> O vo ON (Ti O OOOOOOOO CMC-JC-4CMCMCJC^4CMCM

3 ^

CM <M CM CM CM CM eg CM OOOOOOOO OOOOOOOO
CuSO,

' P. "o oj o^ o^ d •<!• vD

•o

n) ^" d

CO u >/. " 00 O

!? ^

00 U^

>- a. i

u

n) 00 a

n! O

^ in :S

o

<r ^_ m -* f^; vt *". U-, <c §

-* <N a^ oj ^00 X

<3- cn <t

CM en <t on ' en <! -*

__

' ' ' ' ' ' ' o

a)c ^ o <t

vt O -d- -* fM > W

n) vO 1- r-_ a. U-, 00 O -<t a ^ .-H .-( .-1 <T> c^ <t d

^*

C3^ en <t

?1 o O O O ii-1 o 3-

•* in ^ S s

c

1 1 1 1 1 1 ' 1 1 ' ' '

E a oo

S^ o

s o

rt „ r^ 00 00 ^ ^ <f r^ CM CM r-l r-4 VO ,-1 <t o < <f <t <r ^ v£) 00

or 3 j; O vO s

ci pi en (j\ <r o 0- o o en in

j3 tS^

^ cs CM en OJ en CM c-j en <t <t B o- cr a* cr o o o cr CJ cr o- cr y o o o (J B 0] 3) 0) 0) s) <d 15 w

c

(fl >,a

nJ tS c Cw 0)u

c

3 1

o

O O O

=:"' :!:"' :i:^ E

'"'

E W o aT 0? c o

0) K) o o o 4-1 0)

(S o o o u 5

O u

rt

(U

,-1 o atT* DO "a

4-1 o c

c CM C p CM a) ^ a) XI K k"

VD o O S

o o

)g [t< o sT in <t 3 3 3

CO s^ m s

\C CM

<" P- ^ 3 O ?

V •^ -a *<r <i O o"" O^ O o 6^ " ^-* vj- -<f "2 o o O O . O o O w CO m ai CO CO (N O CO CO CO

n) 3 3 3 3 3 3 s" 3 ^

o o U o u O o O U 6 o d d
Cu(NO

36 3>Z

" 0. "o <N o

4)

CM

•o

to U

n) d <f ^

1

in

00 ^ ^

0^

in t

00

nj u ?H

INI ri

•""I <t '^.

rt ^

00 r^ s n

4) X

•a g

n! ;i7 in VD ^o -* ^ 00 00 CO

>. rt ^. ". "^ <M CO r~ ON O 00 *. '°, a 1

^ o^ ' d <f ^ <t r-^ VO in d <t CO r^' CM CO cJ CO CO CO o r-J M3 a- -2; ^ 00 00 00 00

-I ^

c

1 1 ' <

rt 1

OO ^

1 o

o

b

'S

(D 00 00 ~i- O O r~- o

>. "^ r O VD <f Ov

in >i- o <^

CS -J VD d

Ov OO VO 00 CM m

<^ Ind

^

-*

in in ^

rt< 4) ^ CM O 0^ o O 3^ O 00 ^ r-) <N

J3^ o o o o D- o cr o o CJ D" O t> o cr a- u- V utd 0) s> S) 0] D) 0) 6 W

c

13>-a

"rt j: £

cU u ^ ^ ^

•j:

,1 II „ u

e O

E S O O O O w oT K i i w ffi a K^

d at u o 4J o CM in in

rt o m S

1^ '3 TS a O c jj u c

E

Bl •w CO 1^ 5- O m

CM •(-T* <^ -^ CO

.2 CM dJ O o o u + '^ o

X) <S J§ "^CM<S

8) (U ^CM

co^ cn s ^; s OT CO S S ^ CO

(4 3 3 ;3 3 d 3 d 3 d 3 3 H o o o o o u O o o o o o
CulNO^)

36

" ^

°Cl. "o o S

til 4) •o

<J\ vO r~. <r <f

«

"(3 CM VO r» in in O

CM •* so a^

•^ vT,

CO Ui l- #

oin00 a o^

^3 o

<^_ <f ^, '^. §

CO •£>

4)

' T* 7o

CO X o 1

E^ CN in r^ 00 <) o 1

(D 00 r~ r-~ O -J- ^. '^. O o in 00 00 a ^ <^ en ~:r -* CO CD o- <T~ -*" 00 CO 00 s

<!• 00 00 00 CO 00 00 c^ o CO 00 <^ 00 12

•-I <r c

rt <=^ OO ^

% o

jfl ^ ^D CM ^ ^ CM CM CO CM <f <f (^ > 'o X.

<7^ o c^ CO

'^. o

o ^

oo"

'^. o

o

-*

<T CO S; CO -*

CM '"' CM <r '"' '"' ^ 01 ^ o" cr a- cr cr o cr cr cr cr o* o u 6

XI

B) « « ca 0) a a! td ffl <d a) td

c

<i>-0.

rt X C CU

c

to a

^ IIB

11EII g O o o o

CM CM CN oCM oCM

<u J 0? 01 c? o

K 3= P3 K p: td Id 01 Id 4J o O o o o O 01

rt o o o o r-l CM -d- 00

1

•a T3 a •o X S

i

c

•H o o

+

+

CM + +

0) + i

c: o

CO -* <t 'cm '"n '~\r Qo ^ '^ '"co '"co '"co CO CO CO

4; o o K X K p: S as o 3 g Z^ 2^ Z z 2^ <-- 2 o o 3 3 3 ^ 3 3 3 H u o o O U O O o o o o o
.-1 o eg .-I o^

CM CN W CM

O .-i CM CM O CM

<7\ <n i-l s ^

so -* m o CM <n

r^ •* O 00 m CO

in a. oo o CM «\

CM r-l CM « CO ?>

CO CO _j* -d- CM CM CM CM g s s

CM Ip CM CM CM !S ev O P O U O 3 O 3 O 3 p 3 O p o o o o o
Cul- 1/2NH,

T

CM O O

cr o tr

;=""

<=> 3: a

CO W (Z)
o*^ Qc z 2 , rt CM

ON

ON UO C CO -<f '7* CO

Ic 1 •^

hH •^ in « CO ^

_^

in00 w 0^ H §

INJ d

'^ d CO

'^. '^. 1 '^. O4

4) ON in i? ^

<! ^ en CM '-' "-I CO s K1 B n^CU «5 ^

>- m <f au \ ^ <f m ^ ^ s s i

00

'I'' 7

2* d r c ' ' 7 ?Q

'£ ^ 001 « £ " b

<J "0

n) ^ .-1 00 3?

CM m CM 00 3

bn

-3 Z C 60 ^.

CTv 00

ON ON

>d- 00 ^. S * 00

00 en

ON U 1 ^ V CO VD CM in s ND <! u-i CO g ^^ c^ "^ PJ CM * CO ^ 5

T3

ii " u u U CJ §" " " §- u U

S*

5*

s* U3 s

IIe <> 1(4 Q X c «r U c

4J S 10 U u p. ^ 2

ra ^ 3 01 1

ID s e

IIe B nIIB w 3W a a « (U 0 s 3 s g" a

rt m m CO s

rt ^g

"O •0 T3

ra •0 •0 u 4J C u § ^U

CM ra CO ra a « i-i CM CM 1

)S

(x CM en en X cnw'^ en tif

<n ^ Vj- g a S FI4 CO W ^ c 0^ PM M K PL4 ^ n Sf 0^ « (U 1^ CM CO ^ J3 CM

*5 3 %1 ^ ^ H H Z i. "c^en cT l4 3 3 3 3 3 3 3 s 3 3 3 3 3 3 H U
o. "o o 6^ vO r~- to O

n) d 1^ :$ d

1

in^ >- •J5

in1

6

CM en

e

Ov -; ^_ «J ^

vO §

o d in CO

rt ;q 7 r-l CM

' X "o

' ' ' ' a

a

c ^

-* <!

>. rt a^ 00 o CI •0

a. 1 ^ vo" r^" 00 <^ VO vd' i

•^ 00 rH o m r>

00 00 00 VO r-l CTN o. in <»> CM CM

•o- en €4 1 c

1 1 1 1 1 1 1 I 1 1 1 1

11

OO ^

§ o

"

U<"o a CO VO ^ in o U-, ON 3

m r^ <r > in CO 00 ^ m

Of X. § S*

VO in

CO i

VO l^ '^ c>< CN

j2 V ^ xr u c cr D* (T cr

ti « * « « ) nt « m 6 to C -1 ^ U a e

«) ^ c •

1)o

c1 I

c

B e OB g O o

CO s~

«" u ^iT i

«r T M ^ 2

s

« o s s g o O 1-1 01

rt m n o CO w CQ o O J=

jfl

-J- B -* «s o O •o •o "0 o o J5 S

£

c O c c

en n 1-1 c-l a B 3 aT C^J S cl ^'^S o H

^1 fa + CN § § € . 5 "ICN ^

8

o § § 1 5

5 s>

4{ g g

O

:r bT S^'^tT' 'en

en ^

o CJ O o o o O O

,"* 3 3 3 3 3 3 3 3 H O o O O O o O O CM O. CM 24
Cu(NH2CH2COO)

"^

6 "o d

2

c

IS

, o o "^ r4 00 OO o •* r^ r^ CM CM •51

O

•^

Ci

oo ^

(4 •J=

00 a CT^

<i (M o >»-< So n CM vO VO m * CO

rt ^ ^ .^ VD VD ^ \D •n ^

0) ro CM 0^ en

a:

"o ' T*

,-t ' §

rt ^

^

o sf 08 ^ f^ ^ o fO VO CO 00 s ^ VO O^ 00 CM rn o CM

lO vD r^ o o o fO .* 1 1

' ' ' ' ' c

13B

en oo ^O _

'o

It] > 00 <r CJV a\ 3 5 00 00 00 u-l r>. CJN CO u E .S? O m u-i vD 1^ in >n lO ^ "^ ^

f^ ^

4) h (U ri 00 vO n CO Ox 1^ CO r^ C ^^ tN o\ 00 vD o 00

(0

(N CM CO t-t ^ '"' '-' ^

^

2 o o o o cr o O" U" cr o o* o" tr

n! ca « (0 CO 0) <fl q) 6

T3 W

C

n!>s0,

r-l (U

rt 4J

ueIIe e J

c

•H

IIE U

o e E n o Pu o 1

c (U 3

nJ a: •o

St IS <e CD to to o 4J u d

J3 D

o 3 C 3 vO O

rt W u >>

(fl •o o a x: 73

TJ d u 3 u

"S c

rt +

+ CM s

rt S

(4 3 ^ "^ ^ £ a: CM ^CM +

S K o a: ^M n O o X 33 8

(l4 CM r- sP

aT O o O O VO X X CO 3 M CN O o u O 1 CM sT' sT' sT" 1

O ^1 u-i CO >* o o o

4> X CM CM

.5 i4 i d" o

o"

CM g 1 1 I

2: H O 3 3 3 3 3 3 3 3

fn O o o O o o O O O O o O
Cu(HCOO) 2" 2NH,

36

CM CM fn CM to PO

CM tS CM CM

CJ O O O
"p. O 61

OT U u i * i

•pP Ci

00 Ui

>s .|1 h I

00

<fl rsl o O ro <f

U-l r^ i-H ^O OS O

rt ^ <f <r <> <r CO m u-( 00 X "o 1 E

<ta c

rt c^j- o o ^ ? o vn vO o n ^ CN (>. CM CM •j-i CM 00 ^ < J^ O U1 cWc

•m? ^

<r 1 o 2 o

b.

Vh

tlfl u

rt vn VA P^ r^ c^ <f 1^ 3 £ vl- vn CM o vD £ .^

•J-1 "^

•=t ^. 00 CM CO

ti m <r <t en C3> CM O^

fi o :>

3> 00 <f 00 o "^ CN CM CO '"' "• eg —1 CO

J3

(4 436

XI

(J (J (J y y cr o- cr cr 0< M O w a cd a <8 c

<i>.a.

ti X g a c B B B ^ E E W oc a 2 3 4J ^2 ca

CI) CO ! o T3 •V 4J U 4J c U c CO CO 3

«i

,_;m

•zCM z Xz

CM \•X. 3 o o E s o s 3= m o "cm O o s h o X o nT' 1 ^ z z m ro g"

CM € o CM >* + CM 'cm *PM z Z s ^ kl o o C M ^ O o 03 M tn 3 3 3 3 3 3 3 3 3 O O CJ O o o o O O O

27
° (X "o cT g

T)

to

nl

•3?

rsl 1

00

n) rg U y-i rt ^ X "oE^ 10 a °^

00 r^ in 00 OJ <n CN U-, 0^ 0^ .0 VO vO 5 S ?

cW

cn

t? ^

^ "

fc

"o

nS ^ ^ ^

> II

c^ VO 00 <r 00

en

in in vo in in oj

r^ <r r- <J- -1 m <r

-^ as -^ in r-j ^ 00 -;t- VO tS^

-I OJ <t

XI s X> rj 00000 000

W

c

nj>.a

rt c C

cU u

c

[0 XJ

0.uV

c

'5 ^ £

vO

^-'

Ci< ^ o-^:,. V CM 1-1 TS 3

(3 1 1

u >>>u ra ^ <c."c.

3 3 3 ^J 000

CQ ci
Ag-AgF

37

a^ -DVin ^ ^ o CT\ CM r- CO CO " (X O 6 • <t LO OO ^ d d "-1 CM c^ V ' ' ^ i~- J^ r^ en o ^ '^ CO <J- o CM -^ to

rt o ^ r-! ^ r-l o^ 00 <t <t VO -*

-* '"' 1 VO CM ri O

•^P CO ^ ^_0^ ' n -* o- CO

n)

CO

00

""• '"' CM CO a o^

<i n O ^

r^ <f '^ r^ VO VO O -; o '^. '^. '^. a o 00 o- o^ o^ cm" oo" 00

«i VO o- -*

0! X

nJ ^ ^ vo o ^

13 m CO in 1 o o

on '^ o> -* d

ON O; 00 00 O^

ON

00 "^ eg ^- u <r VO <f o^ CM -tf1 c

OO ^ o

ON oo OO ^ en o s o o r-- cs in vC 00 p^

MD -3-

'"'

01) <J- ""oo" CM <r ^ ^ o o o. 00 00 -* 11

r^ <) CO CO CO cm 00 1^ r~~ 00 00 00

0) n -<] C 1* o <! ^ CM <f CM W

'"' CM c^

0) ^

55 o M M a" M o* 00 60 o (J cr o" w o a* cr zr ir

13

a) a 0) at td Id m «i <>> ^ C

<fl

II

11 -I

>v e

11 a e e 1 1

ft

S' u 2

03

ra i3 c

.-H .

r-l r-l r-l rt ^

!l 3 II •o 11 . g 1

01 p E e at e s e 3

aT 1

aT .- a naT o o -0 4-1 2

Bt 8 s

g" <d pT X m n 00 ON

nt m 3 •o •a "S •o T3 •o E c C 4J C c ^ o CO ^ n 3 a

v^ b r^CO

4) ^-s

CS CO ffi 1 + iJi + CM CM o O o 3 bO 60 M) ao 60 « 60 60 60 60 a,

<! <S <; <; <! < < < <i < _± -^
AgF

o- ^ u-l <t 00 °r,^ oE ^ d CN 00 r^' d o en •-I «N

tx ' ^ 00 o ;c ON 00 <n

vO

lo • s ^ 3

(O 00 o vO in oi ^ w <t CM in en <n m CO -* O

S" in CO t 1 in

Ol*

00

a. O

o- 1

?^

<f '^. <t '^. -; m % o <r 00

nt -I ci 1 I 1 1 X ' ' T3C E o a X s ^^ s_ s_ s s o k

•* 00 <n ~^ end <t

<f

00 CN

en

0^ m m en 7r< 1c 1 1 1 1 1 1 1 .-1 m 1 •-< > " ' '

rf OS CO ^ 11 o

i-< £ "

"o

rt ^ ^ 00 00 00 00 >

%o "3 ^ ON vO ^ ts r~. CM

bf 00 a\ <n <n

tl t< (U <N 00 VO <n CO lO c ts^

-* ^-*

00 ^ ^ "^ ^

XI V

XI

rt cr cr o- o- cr a- cr cr o o o CT- o 00 cr cr o- o o- w

Id (d 0) a 0) St <a a 0) 0) a M c

ni •-> S- II a g

x; c cU (U a 3 C

R) ^

ID J2 E 4J E E 3 O O O O O O o o (U a « 0) XIc X^ 3f W*^ W^ w^ s'^ O tn u-i O O o o ^ o 3 «

n! rH ,-( CM m o o o^ "s •o •o E c c3 ^v^ fc en o o

5C^ 33 CM

-d- o

XIH M

fl

t>0 60 % ^ ^ < *^ <C <: < < < <

30
Agl

37 C 00

,-, m r~- in 00 "o*^ H

cJ S

CO 7"

•o ^ CVJ o\ ^ r-l m <t VO

CO O

rt ^ d ^ m

yo S ^ :l

•^ in

00 ^ ^ sF

in00

nJ (M CM u 3

><-i ^o '^. "-; <f c^ 04 O o 00 •? -d- *^ ^

r^ yD CO 0(3 d VO C-J nJ t o

0) K "o ' ' a

rt ^ k

^o !3 :J s ^ o- 0^CO

00

^o -.vf s uc« as OO ^ ^ O w

U<"o

n] CM vO C-J CM -*

>^ o 00 o <!• 3 X CM 00 ON CO in g .5? m n ^ ^ o '^. o ^ V U (U ^ <f <f c > O o <J- CO CO

to

'"' ^ Csj CO CM CO CM ^ « ^ nl o tr O o* u- cr o D- Cf c cr u cr cr cr O cr cr m B) to at td at cd Cd Id at c

rt

'-' '-' >. II II a e E

'is X a <u <u c Z U u 1 S

at c

,-< r-( ,-1 ID ,-1 r-l ,-1 ,-{ ,-( ^ 0] s um

II II II II II II CO •o T) o 2' e J-) E a ^ B

•o s'g •u c S

Id g' <d 2 3

at 8 ° 5

en a m 0)

nl CO '3

•o c "= •o o •a •O a -o a E

4J c c D m 0] ^ b r-~ _<f , u

'^

CO ^ n <t o CO OQ p o O CO o ^

(^

tj n M U U ^ ^ DO

PQ60 M "& "^

<« <! < <! < < < < < <:
Agl, o 0^ o ^ -* CM <f ^ ° o. <f OO o o s

<t CO «a

4) o

in r^ r-~ 5^ o 00 00 a; ^. M

rt d S <»

O^ S' S CO ^ ^ <r CO O

SP in 2

>- •1 in -*

00 6

C-J CO o

<4-l 00o

00 d

-* 7r^ -* m I; oo" cr. ^•

CO ^• X 7 7 7 '^ • ' o S

c^ -* ^ _ ' ' ' '

-? E

n) ^ 0\ CO o UO

>- rt a^ r, o <t o 1 ^ n o ^ OO r^ '^ d I-" r-~' ^ ^ m

IH CM CT^ o -< o CO

CO .-1 c

»o

In

OO C4

"o 11 o ^0 <f CM -*

00 n CM en o- <r > CO OO o CM O o M ^ «• ^*

'". ^ ^ cw

^o S s <t <t o CO Ov m <> CM -* '"' CO CM CO CO

XI a XI 5

u- o- o CT* o o D- cr o- O cr cr o u01 « 0) <a 0) w c

rt ^ ^ II a B

rt £ J. 4) c iJ W uc a ^ ^ ^ ^ ^ ^ ^ ^ u

II " II II o 11 II II •o

II 1 (i e E ^ ^ 1 e a a E

(U (U OJ O <u (U <u <u TJ 4-1 4-) IJ w

0) o Id o eg

n) u j-i iJ o u

CO 0) m CO tn uo 3 D •o a •o •a £ c ^

CO CO CO o

cs

is aa en C^ ^ m 3 m o CO ^ ^ X O 0- ^ O

<r CM O o 3 en <f o M s: en O o^ en cn"^ HI 00 CM cs 00 tlO 00 ^

00 CO 00 00 M 00 00 < * "* *° < < < ^ < < < <
AgNO^

37 n <» ^ <f

in o\ -1 -' CM m

r",'=^ £

<T. d o^ 00 CM in o pj CM I-' ' '

•o O o <t r^ o as CM 5 a\

00

-* • u

VO in 00 o\ r-J pj -* en d d en CM

to CO m en in -* CO <f CO m o 1

in

<f

CM

00 « -* -* ^ cp in00 a ani IM o 00 00 u e ^ '^ in o> VO en ON vO in in CD r- § d CM ^ o^ 00 d c;^ r^ <f o^ CO OC) r-~ i

'^' "? VO o X

"o

n!c ^

ej\ ^ VO en en iQ en IS 1

PI

oC r~- ^ o

^'

ON 00

en o

'°. d d

OV

o^

en CTV VO <t h oo oo o CTV <7> 5 1 Cvl, CJ eg CM CM

jj 00 cli

oo1 o 0^ o K

"o ^ "7^^ ~"in~ ""ctT" >

00 O o ^ o> o c:^ * Ov r~. or oo S en 00

(U -* 00 o^ f^* en oC W

•* ^ ^

-* S "

JD^ o o o D* o a- o o D- o o O" cr CJ cr cr cr cr cr 6 « 0) cd « CD etf a Id a cd C

'-' >- ,-1 II a e

rt ^ c e

<u cM Vo3 o e

11 - e s

to

(d

•a D ^ ^ 1

CO o o o a <u aT 4) O

c- T tiT sTsT' s

at 0) at ed X

iJ u o o o to o u o

ni o cd -* Ij •H 'S •o •o o •a o £

4J c c; c

CO m 3 o

r~ C-J en vO <f V o o*^ d^

zfT* « <u u <u C-J c^ 2

ft CO CO CO H en s o O

CM CM a a 2 60 U) 60 60 60 M M 60 <! <: <! < <! <J <; <: <
AgNO^

37

a "o o

a; T3

—f \C vC ^

M O

nj in s on

°:? in

00 ?^ ^ # IT,

(4 oo a o^

nS U VM •*

vO ^ r^ ^

rt a CM f^ ^ O ^

1 CO m

X

' ' 1

6

~~~ ON CM 00 ^ ON i-H oo a

r^vor>ii-(0<-i.-ifn O o 1

M

o in -^ O vO

vO o

vO !^ m

>-i CM * 00 1^ o

1 c

o11 o

"

fe"o

rt o CM ^ OJ -4 r<. lO >

SO lO CO

"a ^ 00 n en v£> u £ .S? 00 f^; "1 °l *^ o\ n

V U <J <A •* n o O

c ^^ a\ f^ <t o CM vA

(0 "

a trcrcrcrcrD-trcr tr o cr cr cr y cr o o

<c a as « « 6

T3 w

C

nJ^a

"rt ^ c cU

c

(4 a.u §

" II

'"'

II O m B E B s m s

XI ^ oooooooo o « 3 OJ CS <N tS CN tS «M CM V 0) (U « W BCXXXSSBXa OU 4J *J 4J O CS t: o o o o o o o „ O " W

c o o o o o o o 3 • 00 0)

rt sj- m o^ o^ o o^ o^

, _

rt r-T ri in o* o*

""* •« •o •o o

"5 e i-i m C 4J u ^ t4 id C

>« cn

fc o O r^ 1 + z Z PI + cs en CO 1

v O ^ CI c- n 2

i4 £ 1

2^ 1 I I

H < s i ^ ^ _!. ^ i
AgPO^

37

» a

o

CK

1) t3 ^ ^ ^ 00 <r r- CO -*

CO U

nJ i

pj ^

S :j

00 S"

1 ^

Ciw

>- 1

o

n) 00 — a. o^

(NJ r~- U M-l OO <r O '°. ON "1 ON CM o

^

CO u-\ 00 o M <A in

n) CO CO CO CO CM CO CM C4 CO v • • ' ' ' 1 1 1 • a:

"o

nJ ^

lO in CO

>- <fl in' o CO -* O r- -* vo o in in in^ o ^

<r %

^ -* VO i-T r-^ i-T ^o in m 00 2 VD ^ ON vo in 00 1^ <! in m 00 M, CO o w CM C

rt B! OO ^

.^^ o £«

^ rt ^

ON j^ 00 00 ^ ^o ON CM 00 CM r~- O vD ^ O -* r^ CM * O o •* r-- 1-1 CM

>- OO .-1 CM -* l-~ CM CO O ON 3

i

Ml 00 CO •* en ^ 5 s 1

CO 00CM

00 m CM 00 -* m

00i

s

00 ^ CM CM C^ CM CM m CM CM CM

XI a J3 u 5* 2* O D* O O" o o C CT" O o O O o O

s* 6

T3 4 « « tt « «

c^

-1 i-l >. D a a e E

rt 1

iS^ s U U

B. 3 3

c

t-i « 1-1 to 5

u D . II , o o

3 £

B a oB • pT sf «r

"0 4J c 3 8 o o s i

« m

a

T^ 3 a •O o o 4J C c c u c « 3 3 P

fa a'' r» 2* ^ p^r n 1

CM ^^ s o o "c^ %

z pq PB C4 CM en CO CM CM 1o ^^ ^

e

^

X •^ o CM CO f r i ^1 COu ? w ^ s

CN « o« <

60 < 5 1

s.< 100 <1 J_ f :- :- ^s 5

35
AgPO^- l/3H^O

37

on 6 E

00 r^ 6c

T3^ c-i o 00 ,-1 60 , rt c>i o d ^ 00 c t/3 u •-> n n CO

'£

ID U

?P

ci

00 X

>- h

fl) oo' a an) rg o o ^

""^ <f ^. '^. '^. °°. °°. O CJN ^ d i o a^ c^

Id c^ r^ •s> in in VI o ' ' ' ' c 6

rt ^

>• o

n) ^ QS In 00 o a^ >o en CTv ^ a 1 ^ <o' ^ 00 o en d d VO in d d u (^ en 00 <J^ m cc

o< <t < "-• -" ' o

nl cd oo « s 1 1 o ^

CO

"o

n) -' «* <t n CM CO <f a\ CM O o o CO

>.

r~- i-l m cr> ^a- O "-1 11

<!• 00 r-~ vO •* CM S 00 or 00 u-i ~* ^ ". r- '^ 0^ ON r- o

4> £«

in CM c^ irv n vO n CTv -1 o vO to o 00 U

<-< -* CM •* CM ^ '^ CN

XI 2 Si 5 O O o cr u O" CT CT cr

T3 « •)) (d 01 Id 0) C

n) '^

>. II a g

"ifl ^ g .«r c

T3U

(4 U oc I ^ __, ^

B)

,-1 ,-1 rt om n II II •O

II II XI "^

01 a s

CO Tl u u

"o c 2

0) 01 8 S 5 m 01 3

rt H . (4 "s o •O o •O t3 V £

•u c ^ p a 00 3 O I + n 00

hi f cn y-N CM ^

CO

CM O o o ^ r- Pu ^ <f + o*^ o o O CO

60 <; V • ^-^o O d^ <t o CO 3= en O O X PC o "2 O (H (^ < o O tj^ C^^ X B ^ O

(4 PLI C' •<*• 1-1 en CM CM CM o o z

60 60 60 60 60 60 60 60 60 60 60 60 60 <! < < < < < < < < <! < < <

36
AglNH^CH^COO)

37

ino\

"o

D. B m

O >-i

, a ^ ON

O

U

CJ -

OS C3S

•^ in i

1

in

aCO

aO in VO o OS o OS f^^ ^

a

pj on" ci CO ON oo" CO

• X

nJ ^

rt ^ 1

,-1 r^ r-- <t O CN CM CM VD 00 OS OS ^ O r~- -H r-( r-^ <f ^ ^ vd- CM CM l~J d

s

C

en ^ in C^ rH e^i VO in VO -* 7

<t

<f "

CO en

d^

rt ^ r~~ r-l CT< CM oo VO r~. CM CM in <f SD CM ^ r-~ ^ r~- <! 00 in OS

"3 ,S ^ CO .-1 VO S 00 OS O 00 CO 00 CM E.^ 00 in CO m CO 00 00 C3^ 00 ^ OS OS O 00

<U CV4 <t O^ r-I r-I CO pj on" C^ o^ d <T~ 00 d ^ C (^^

csi r^ O in ON CO ^ ^ o in ^ OS in VD <! -I ^ •* ^ "^ '-' 5

<u O O o o o (J cr o cr o o (J o cr cr D*

rt eg o CO CO a 6 cJ^ c

nl:^ ^ ^ ^ ^ ^

a <u (U T3 II II T3

n) CO 0) ^ E e e E E CO C §

"g s „ ^ ^ e M D aT « (U CO <u lU a- >> 3 >s u 4-1 <D C 18 CD o

nJ X 4J J-1 O

ll CO M CO s m 01 0) <U gj m ^

<^

?• ? p> 13 o "O W U •r^ 4-J u

-o

to 0) CO m CO CO CO 3

c

rt

rt '3 ^ g _* +

o- o + 6" O M CO X o

fc u M m CM o z o CO tJO M M CM M s CM CM < 60 <0 M < 60 coir pT • <: CM < . < ^^ o 4> 00 X W O CN CM CM O 4 2; ffi o 5 K ? tlT' "cN g

o. g g

o^ g 3 e

H < bT M M <! 00 60 60 60 60 <N <! < < CM <: < < < <: <: < < < <! <

37
AgCl-CH^NH^-AgCu

37

U1 u a "o o E

-* -* Q

<u 1

•o

&o rt in CO <j; c CO o ^ 5 ^

m U

!P 5:] 00 :»i >- 0^ ^

n) 00 a CT-

(VJ O <} <o 00

t-l 00 CM in -1 -* CJv r^

1) ^ d s ^

d J^ c^ ;:^ CO

<7^ _

' '

rt ^

> 1

n vo o •* 00 a o CO o in VO CM o Ov O vO o ^ 00 ^ eo vO S

0(5 ^ c^ in r~- <t CM vr O o in p~ o

c

1 CM W '

' o

H 1

OO ^

in 00

jj §

O

i

O

fc<

rt ^ r^ I^ OO r~. VO <t (O in in o

"3 X

O O CO r^ o 00 o

or 00 CO o. ^o o 00 S .* rH

t. £ -^ '^. 00 c^ o 1-1 <N m ^ ^ CTN <t ^

-* 00 in ~* CM d vD vo vo" •* rH CO r-i (^^ vC CM 00 ^

00 U -' CN <o CM CM -* I^ o> I^ ^ a^ JD o cr cr 60 o 00 S

a a a a CO a o w

c

rt ^

a

^ II

rt S X c n c V W <u ^ a

C a

tj

rt t< 1

J33 J

II e 2II gII e

c a T cT s

<u u

<c o o CO

rt 09 s o CO m 3 m o

rt "3£

CM

4) o V •o •o c +

3 2

<a = "^ o <n M 1

j::^ t, i" g , CM CO Qn -T OO U

U pq CO 1 CO

P2 CM <»• O rH < o iJ O o S" Z < < S 1

3 5:^ CO s ^

COO c "m tl =1 == o CQ CO CO o H ao 60 60 00 60 60 60 60 60 60 60 M < < < < < < < < _^_ <; <; <i ^ 1
Au-AuCl • 2H O

38 "* ^

OO 00

"o XO vO a o ON ON o E vO ^ 00 vD

11 •o in ^

rH ~*

, rt ". '^

u

o ^ >* d *

•pP Ci -*

00

00

00 Ui

• ^

* ' >- h

rt 00 a o

6

c^ o

o

00

<r n

O CNI P-. r^ d

rt '^ ^ rN u-i r-. IS CO X1 s

0) ^

>, J

rt n o

a I

O ON m OO CJN ^

o r^ J vO m d ^ d OO 1^ 00 CM d

o o 00 -* en r^ c n r^ W

' '

vO o

OO «

o

>* d o

fO d r>. o 00 O r^ •»

ti o t»i t,"o a ~Tr o ~ CM

>• "3 ^

~* in t-l ON o NO r^

CiT vO n 00 00 vO m

Ov <3\ ON ON ON ON ON ON •* OO en en

(0

U V vO e«i 3

r- lA \o r^ n CM t^ en CJ^ ON ON ON <t vO o en

'-* <n * SI f-j CM en

J3 V ^ rt O ao 00 00 00 o* M c O" o tr o u 60 V u O* tJ

T3 W « a) a ed a <d C

'-<

«1 B a •N <0 c

c

r-l i-< i-i OJ i-< W

c

ni .5*

II II II aII u

E E E 4-1 03 E O

Ji3

o . OJ CM

CO <u <u (U *J D ac

flj 4J 4J a *J D « « eg 4J o CS W o 4J -0c

00 ra m o. s

a ON

•H

•o •o S T3 •o

nl u d 4J c

to to to a 3

"5E ^

s

fc o

a: « m ^ 2

PI roo EC CNI CO en 1 + tn O 3 O n ^

+ Si as 3 < ^ Cb o O u H 3 3 3 3 3 ^

_!. < <. <_ < < _<- =

CM <

3

*^3 _<.

3 ^

3 ^ -< 1 39
6 " > E 00 Q 6( co

T3

00 00 m ^ en 1

to

rt VO CO

En § O XCD u

?P in -*

>»

00 u: pj ^ h

(fl CO a o

n) U t-l

'^. ^ -*. O t^ St

»£) vO f>. o tD

n) u-i u-i ~a- <r

0) X "o •ac 6

n) ^ a '?

(1) O CV4 o cn cr. r^ 1^ ro 00 OtJ r^ 1^ r~. CT> r^

I-. r^ n r^ vf in ro O tN o^ in in CO o o o^ lO tD <n r-t 1 -* -* 0^ -a- vD CO vO c

rj. «

fn Wc 1 '

n) S? ^ H 1 1 o o

U.'o

rt -*

or r^ IT) 00 vO in o- en 00 r^ 1-1 t-i r~ n. 9 2 00 en 00 a< o vO in 00 o fn

k< (U

r~- >o t-. 00 00 00 r>. vo »o VO VO 00 ,n 5 ^r <^. <7V

a> oo vO C7N o ^ v£> lO so vO f^ p^ en vr ON vO t^ CD c ^°^ ri o n o\ r>. in m o tN ^ vO ON W

fn vO CO r-l * (N U-, m en en

j2 0; j2

rt tr 00 cr o (J y cr o cr a- o" Q fj 60 O O O u w

eu to c^a

rt c ^ ^ ^ ^ rt W

1) II II II II ,1 CL t3 C E e e E u rt T3 u

HI <u ^ 4J u c 3 « at « to

rt 4J u

in W •c "o c

•o •o •o au

•o 3 j5 0) (0 to to to (4 "5

4)U E 3 t- CQ

00 O O o n X X X*^

cd m -* n X f X C X z X 2

CJ vO -* *-^ '-* 1 *<r ^ CN <- <f u 3 CJ U U CQ oa (U r-H ,H U

(d n) u cs 00 03 « 3 3 i-i H o o pa m 2 H 3 3 ^ 3 3 <: < 3 3 3 3 3 3

<: < X X < < < <: X X < <: < < < <

40
Au{SCN)

38

o. "o o 6

4) T) w O

o l-J

•nP ci

00 i<j >- "^ ^

00* m (M O • CO CM CM <f m

rt ^

00vO OVO 2

in r^

i-i X O

-%n ^

>• ^

rt a. a ,i<! 00 r- <N c-j 00 in o 00 VO VO OS ^ 0> 00 VO vD in in r-I CO OS CM r-! c

r^ o> CO CM <!• vo CM 1 m 1 1 r-4 1 1 1 T-l 1 W

B g 1

O

t4"o

rt O vO CM ^ ^

>- •zi -y OO 00 o CM CM CO in in OS r^ CO <^ VD 00 3 ^ VD CT\ vO O CO VO VO o CO OS r-~ u £ .5? OS C^ O <T^ OS ON o 00 00 -* o <f

4J ^< (U ^' i ^*

CO ?S CO O r^ <P VD VO r-^ o OS CO OS r~- in

to J3

> ^ s J^

CM 5 ^ ^

<f

CO 5!

00 s

aj J3

n) o o o o o o „ bO U o cr" v w D" D*

X) W

ta CS rt C3 Cd c

(fl ^a

rt ^ C

cW (U '^ II 11 II II II c

IX E e e e e

ni 'i^ m 10 C) 0) (U Q) (U ^ 4J 4J u U 4J 3 cd n) C8 nJ n) W 4J

to ai O m CO , , , , ,

rt S s 3 w

13

rt a CO m CQ 01 3 g

E

tH oo O

CO fc 1 CO CO CO

CO f f ;r CO CM

1 '^ CM in

CO

VO

Jj ll Jj f ."? ^ i 1 i S 1

(4 M n n ^ ^ ^^ H CM H CO H M ^ ^ _i. ^ ^ ^ 4 s ^ ^ ^

s o
AuSn-AgAuF

vX) o o

c>< u

(U 2 ^

^'

•o

CM <t 0^

n)

U

CO <>I o^

CM fO in CO o\

en

?P in

00 Ui ^ # Ll-l 00 a t>

>u in r~. »* -J O 3 ^. 5 S^ " ^ 7 T f

oC <t VO

a>

' ' ' a:

"o •? E

nJ ^

D. 3 00 ^ in 00 VO -* ^

J.! CM .-• CM in in oo o CM <f 00 m

r^ o CJN* r4 c> O 00 O^ <f VD CO 1

1 •-< 1 1 m

1 o oo1 o

t<"o

rt VO

r- r-~ r~- r-~ ~a- r- r^ r^ o 3 X in sr f^

vO PI 1^ ^ CM 00 o oS rH I-. VO

VO O 00 en

^< E .2? n in in oo

a; £ S 3 ^* ?f

i-H i-I 1-4 vo (3^ Q r-^ o C ^°^ •-I O .-< CM O VO oo oo

CO -d- \D vo vo n ^ n CM en en

XI 0/ ^ rt o o o O CJ t) o o o o o 6 w

cm

>-a

rt X C

cU

C

a.

XI

j5 5 E

oon fc

_aj ^

3 c c<^c* xTg fl c"* S S J-^ :i Kl CO CO PM CM H M H 3 3 3 "3 t, < < < ^ ^ ^ ^ < < < <

42
39 n s O. ^ en

a. ^ CN in CO "-• o g

or

kD in d in ^

<»

OS

«) <f '^ in 00 o ON in <f CO • n)

P,' (<-) o ON 1^" ^ in f^' r-J CO w O ^ CO '^ 7 7

?? ^ ^ VO a-

>3- 00 Ui ^ __J ^ CnJ CO

>- .^ h

<i 00 — a. a- 00

rsl 6 § o

^. d d NO NO -* 00 "^

13 a> o OS ^ ;* CO X "o ' ' ' ' 1

nJ ^

rt <f est NO

ON ON O oo NO oo ON in ON a a ^ o cJ O d oj d r-" in r" oo NO d in* d CnI o o NO c .-H 1 1 1 1 1 1 1 n in ^ li

«o ^ J^

r^ o ^

00 O s O o eg 00 ^"

oo" d -^"

1/^ in CO u o o o in r^

t:; vo fe ^ •-' ' "o

n! ON 00 r- ~ CM ^ 00 NO 3 X. O rg n o NO ar 1^ -* -* f~~ r-~ NO CW

00

00 r-! -* in in CNJ ON NO 00 ON

r~~ r~- ON o ON NO

'"' '"' '"' ^ « ^

in o 60 60 60 60 60 30 o o o* c o o 6 " CS « to SI ~ C

«)>-a

nl X c cW V

II EIIE

•s E

°cs

oT a; 4J oT K c

4J 0) u

<S s) cd 3 o iJ u 4-1 o 0) a

rt O

'9 •o XI (U U u ^ m to u. m ^

?;

fc Ol o^ + ^

o'^ +« § I

CN CNI r-T* + s CN o O fe S O H •z Z ^ ^ 2 Z ^ is "^ s Z Z la 43
39

??

£ S

^ O O O I S sT* fls*^ sT*

3 O O O O O O

C Cij K S K S S o o o o o

o o o

o o o o

o o o o

o o o o o

en iri o o o
"" ^

o.

P. "o 00 o " o •-o '^ CO CM ^ -d- ^ o

to U

rt V* s s ^

00 ' in ' CO 1

in

00 UJ

>-o

n) •^ in00 a o^

ni <r o § J

CM in o

in d ^- o00 o

^-

00 o VO

CM ^ 1 1 1 1 1 X ' ' '

n) ^ ^

>- rt 00 -J ^o <t o o r~. a 1

J^ <N d CN* <t CO <t o-

^' o -I ~;f ^

^•

o^ 00 00 in u vD o r~ :-- ri 00 <f O T 5^ CO -* c 1 1 1 1 1 1

rt iJ OO t>i 1 °

l-l U* ^ ^ ^ OO ^ en 00 <f ON m -d- 00 o ^ <^ o o m 00

^f' ^ ^O ^

00 "^ '^. 00 d

CM in d CM 1

in o o -* -' ^ OJ CM CO CM CM CO <f ^ ii ^ u- o o o D- cr o- cr o tr o cr o o o O CJ 6

T3

s) n> « <0 td «J C

<i>-a

rt X C cW 1

a- -i .-1

II

.-1

0) 00 £?C O E O ° °c- E ^ 1

0)

0) nf^ XA m cs) o o o

jfl o 3 •a XI •o <u £ d 4J c o ;^ •H a

w^

J3 o o o ^ o

ON CM O. CM

CO

CN4 vO o^ o^

ffi ">! £ CM o CM ir

cd o o_ u u o CJ u CQ CO CO \D

tA •H H 2 S •z. z "Z, s Z z S 2 s a z
39

•^

.^

0\ 0^ 0^ <y^

£ S

3 X

CM CM CM o o o o o o o 4-1 o o o o o o
~

VO <t a. in ^ ^

CO in C3N '-' •* ° p. oo" rJ CM CM 00 d o

4) t3

CO " "

'"'

sj- ^ T 4? ^ ON m oo o • ifl ON d ON d oo 00 w O o o> <) eg eg <f

•.p Ci oJ i i i ^^

oo ^ CN ^ CM CO ^

>- en OJ.

00 — a CT-

(i 00 ON O '^ -* "^.

rt ^ m

00 00 m

in in m CO Xa ^

rt eg <t o in O <t ^ vo ^ >• O .-1 .-1 CN ON CN <j- <f 00 C3N t 1 X o d. d d CN 00 ^"

o^ ^"

<f ^ i<r

c^ en 00 CO o ^ CO C3N 00 CO

-u CM CM O-J ^ r-- CM c f Mc

r-. o

CO ^ g ON -* s O CO

s^ CO ?" S .o ^

U.

"o

n! ^ CO ~ ~

-d- VO ^ <f ~^

>- "3 £ <f --I <T^ eg MlUVC

00

00 00 00d

00

00

CJS CM in ^ ^ oo o

vo" ON ^. egd s 00 00 CO CO o eg 00 -d- CO CM ^ ^ CO in

a.

XI

Xi

rt cr D- c o* o o CT- o o o o o o CJ o o o 60

rt (d nj B) tS E w rt c

<t! >^a

"rt X c c c u oC

n) O O O o s 3

CM CM CM CM

to W W fC W i-T s o o s

•o 00 to o

rt o o o o o o C b

(ti -1 csi m (U os o 3B

eT ax CM ^-v o s p<

in o g S o o o o CM N-' ^

ON CM CN K •^ S uT'

CO ffi'^ X X ^ z 5 CM -* VD 00 . JS -* _-* "o- _<f X* °

°CM ^* ° d^ CN. Cl a O o o o O en (U 0) (u a <u H CO CO H E-t H ^ 3 •r-l a 2 IS 2; s Z Z CO ^ Z Z Z Z Z
Ni(N,

39 —

u a "o ^" Q

o £ -

g

•o

C^l * 00 M , "ifl o\ d

• c CO u CO CM so

•Jj<D1« U

•s? Ci

00 X

>- 1? h

cfl 00 a CTn) -vj U

CM ON vO CM <^

rt ?

id d -* d

X o

c E

rt ^

a

rt CO CM

C<J O u-i <r -* ^o r-- O O as OS ^

^ in o

cr. 2 i^ ::i id :1 :i :::: S S d .-1 CO in c 1 1 1 I 1 1

rt "J eo «

ki u s O

"-I Ui ^

"o

nS vO r~- o vD CM in ^ ^ CM VC

>-Ofu d d yo d d s

§

CO

00 ^

«* C

vO a^ CO CJv ^ ^ ^

J2 m ^

w

o o cr cr o* cr o o cr o* tr cr cr 6

a O <o qj m <a <a <a <s

C

li>-a

rt ^ c

cU J) 0) 13 C a r^ ,-1 ,-1 r-( r-l r-" 1 J3 s B

IIE e e g g

i2 3 D oT o O O O o V <u 01 lU <U to CM iJ u

>« c a X W^ X^ X^ X

s s 2 3

09

0) o o o o o

3 o o o o -1 CM <r o^

rt 3 o o o 4> £ u c AJ u o o 0) n n m

3

oT o

5C CO VO + S A. A A^

rt "cm 'cm CM ^-^ -* ^ /-N Vl ^

1

4) CO '"co^ X CO a CO o o o CM K C-. X 2 Z: Z Z S Z Z Z z z

(tf v-- CO 2 •r^ Z Z ^ z z ^ Z Z Z z
Ni(NH3)^l2

39

•^

o n n

vo 00 en

CM eg n

E £

Cv| CM M r-l ! O O ' v, •— 3^ '^ 3^ CM Cs^ S • pH

49
39 o u E

OH

CO•* ^'

•a'^ in OV CO OV 1-1 • " ^ CJV o- >* 00 -* 1 r- OV 1 u

•P1

u^ -*S

CO u: I«» >- OCM ^

n! 00 a CT- VO 1 o

^' °i <f

c^ r^ VO o o

o^ o

00d i c^ >* ^ ;3 ! "-• in <t CO i-1 "^ •^ I-l j ^ „ ' ' 1 XIc E

(V ^ o > a eg ON 00 00 OV CO rH -d- a ^ o o ^ S

VO

r-1 1 s s m $ 1 m r-4 I-l 1 c 1 1 1 Idc

re iJ OO ^

S5 ^ O ^ w 53

ul ^ 1

"o J2. ^ "^ 00 CO ~ CO ^ 00 ^ OV o ~ \o > o CJ^ VO r^ VO vO VO <!• S CO m ^ 6/ o r^ in CM CO O

CO o 00 00 >o o 00 O CO o> CO OO 00 T-* <J- »* W d CM CO CO <! r-t i-l r^ "^ ^ 1 ^

rt o o cr o o tr O o CJ o o a- cr- cr 00 o

n) nJ t4 6 w

'-'

n)>ac c

II II

1-4 r-li W C £ eu e

<0 8 a 3 H s s 3 C m to n

•a

4J 4J u OJ CO m 09 n n .«S d* CB CO n w

o\ U. n •o CM n '^ c!, _r-- ^ r^ d* c3 «^ CM

P5 r~ O O O ^ ^ o

_ij CM CM O CM (U CM c^ d^ 6" 5 g

!U fu tn fU O jQ O o o 3 m cu' CM CO X CO CO O iT'

<fl •H Ti •H ^r^ •H H a S a 3 a 3 S3 K B s a z z z
39 1 ° e>< "o o'^ E

4) XI

rt M U o i in S j 1

in«

>-

CTN in

nJ 00 a CTIT) M u ^ ^, '^. r-~ ^ 00 vO ^

r~- CM VO

rt o 00 X 1 ' ' XIc E >a 1

in

CO in

C3

i-i °:

in d 0<3

I-. <)• CO in CO ^ CM * 1 1 >-l Wc '

rt ^

CO ^ u ^ 1 O H

U< Z

"o

rt ''J un o CO VD r-l 1

CTN c:n 00 O

'a ^ in o 00 ^ CO o o E .S'

f"; r-. 00 ON ° O u r- d d 00 Ov in c ^^ r-- VO o- 1^ CO <f

'"' rH <f '"' i-l r-t ^ "^ X <L ^ <r D< Cf o o a" cr c c CT* tr

T3 w

CD rt eS n! ca CD C8 a C

nJ S a •H ^ i-l __^ ^ ^ 1 ^ c XJ c 11 II II II II cu

II W

a. B e e

XI e e e 1 (4 (U >. u

<u (U <u 4J <u <u x: (U 4J •p tfl cd ta ts C3 cS <u cfl « 4J u 4J u 4J D 01 OJ CO .5*

CO CO

<u " 1 X) o ,2 , 1 c X) XI X) 0) X) XI o XI

AJ p ^ 4J •H + + u CO to CO a CQ CQ * « s Sj m CM CO p 8 g^ CM f +

ON + CM

CO

CO g ffT" s"- nf CM ^ fc •H 0-) o o

d^ d^ -H g 1 CM w"" W^ ffT s'^ o o 3 ?

st <> o o G B 3

(4 •H i •HS" 1^ 1 1•rl i•H r•H r•H r•H H a s s s s S 13 S s s
NilNH^CH^COO).

39 ° P. u 6

ex XI

to u

rt 1

•=? Ci

00 1^

>- ^

.t; ^ —. 1 rt oc a 1 org 1 u ^ 1 Q ? j - 1 =^

in in <n

rt o- O r^ O ON ON <!• VO CM 00 1 ^ y ; 1 ^ o 00 in in CO CM en in in o ^ en 00 .-H O

C-J 1 CM .-1 i-l c 1 —

re hJ E g

oo

-• o C M

U, z

"c

rt a^ ^ -* in >^ r~- r~- 00 > o

^. s <t cr>

in I-l 00 00 00 U f^^

CM CM en 0-) -* <!• in

a, "^ O O o cr o o o- o o c o n CU c9 CD O w ^ (U |:

td i c <u

(U TD

(U a 1 <u a « c u o ">.

n) >. >. ^

"m (1) <u O O ^ 1 1 Z 3 cmII € O c

•§

•s

i-l -H J3 >-i vj U CM CM

rt o c o o (S « H H £

cs. CM € ? r r.r g^

o" 1- 8 '^ =r i^ jf- ;=r »r sT' O z o o o o o o

0^ U. ar o^ a «<^ .r =r ^ «- o H^^ o o o o o o 3 f s^

CM 1 r c§CM

rt •H •H •H --I ^ H a a IS !3 a a a S I
39 r ' ON 00 00

"r-P- 'oG O vO 00 o

01 ^

(/5 U

In

•pP Ci

00 t<i >- !^ X I

00

<i (M U tj o CO 1^ ^

ON r^ CO

«s CO VO X 1 1 1 £ a 1

in 00

00 ol O CO <f inCM r^ OO m 00 r-J u 1^ CO c 1 1 I 1 1 CO 7 :? Wc

"^

rf OO ^ 1 O

t^> a CM <f NO VO NO <N O .-1 CM O

"s X ON O CO 00 CO ON ON r^

or E .2? ^ 00 r- u-i 00 in o o 1. '^. VO VO u vo -d- vD in •* fO VO O C t s ^^ r-l r- 00 V* ON r^ 00 o- 00 r- ^ ,-. CM St O '-I .-1 CM l-H X v ^ rt cr o o o O CJ O CJ CJ CJ o o 6 W

ca c

<{>

0.

<i X G c ^ U

1)cm

to W

COV

n! ims

ra o ^

w" cP

CO M

CO

Oi CM *CM K

CO fc

C-4 H H CM ^^ *CN| -* + to CNl ^^ o

Ji g i C C 'cm 'cm

•rl W M M H H g g iH rH % CO <N fl -H

flt •H -H ^ ^ H -rl ;a 13 ^ -H :3 ^ H s s s a S B CM CM a a a a
Co

40 O o a "o a\ u-i in o

61 ^ in* 2

o^

XI

oo o- ^D ^ fo 00 vO in w O "

<! 7

r- s * 3 1

?p ID s o

00 Ui "^

>. .ll •in " "

nl oo a CT- vD o rt O o <J- NO o >t-l o O o m r~ oo o a

OV m T o O O 00 o

01 ' ' ^ Xc £ a

~-- 00

<^ r^

Q. i

CO ON 00 o 00 X o O __J s* ^ * vD en as • h o « m CSJ VD in CNl CN)

<)• cc? H

CO ^

-, 00 ^

ro £ 3 ^ o o o S t~~ 0(3 n S O-l vo '"' In o

"o <N 1

vo CM o On >

r- o r^ 3 X CO ON <f -* £.??

o> 00 ON ^

ON ON V 00 o c t^

<! ON CTN

(0 ^ c-J ^X

ij o o 00 00 00 cr 00 ^ 00 (J (J cr o o o cr cr 5 m CO CU CO 6

X) w c ^ rt>•

11 a •o S

(fl 00

il c

_o T3 •o

CD T3 %

Cl 4) 0) (U CO C « JJ

rt II II n) to o u JJ o g E e •H •H S

J3 a a. O. CO 3 D a 3 •H W c (U O o o 0) 4J u 4J 0) (U <u 4J "? 00 n) n ^ S Q) c <s p o. o. Q.

nJ X . CO to » m S tn '5

J= •o •o "O s3 •s*^ ^G •o

4J iH •H •H ^ E b CD. CO CO m •^ D, O. m 3

^1 o Ck -*^ , o 3 + + O^

CM s

<e + cj; o h o o '^O o o o o o o o o U o g o
-d- VD

c< "o <f u^

t3

vO 2

0^ CA ^ u-i O

• U

o> vO o

•=? ^

00 ^

00 ^

0^ CO

>- 0^ c^ CO

.^ o^ „

rt 00 a a-

«) ^j U >4-( r~ in r~.

d) ^

-* 5 r^

4) r-l I 1 I "o

' 13C E

' nj ^

>• ,

nl vDOOCOvOvoO\DO<rr^ a 1

^

f^ <r -* 00 r^ 00 oooocnvi>ocn<i-vor-oo

r-I in ^ CO <) CO CJN<D.-<r4tN<N<N<N(NCN

1^ r^ G0<^>O^O^O^O^CJ^CJ^O^O^

c 1 1 1 1 1 1 1 1 1 1

c

' '

' ' 11

CO « 2 S. %

o

s

o

U."o

1

rt ^ n o <! CM 3 ^

E .5P

lH o 00 CT^

tjr m CO CO a< o^ a\ 00 cW § ^' >-i s

r-( '-'

j:^ rt o o o o O-Cr'D'crD'crD'D'D'CT'

cfl n) tanjcfltdajtacscanjcd

(5 W

c>a

rt X C W (Uu

c

a.uo

1-1

XI IP 'O o 3 e oooooooooo D (U CM CM CM CM CM CM CM CM CM CM C<l W

« w 4J

Q) fCWWISWKPdWKW

4J >-icjcjco<fu-i^t-oin inoinoooomoo

& to .-1 1-) n) •H CM

E s c 4J C

a, 01 •H

CV4 O U. •*

CO V3 g c CO ^^ ^ ^ % % g

o o " _£^
CoCl.

- ^

° e. "o o E

4) T3

to U

m * 00 —

?.P 0^

00 ^

>- a< °^ ^ 3: -

n 00 a o-^ U •^ 00 ~* 1-4

rt ^ i

pj

fi -f

•^

"o ^ £

0! ^

> e x

-* O vo CO 00 <!• VO

Q. S :^^ S ^, S ?<yi i-H r-l n CO U-l VD 00

CO

lO

t~~ O in in C^ CTN C^ CTN CT^ (J^ cr. 0^ CTl <t CN O

C ^

U ' ' 1

'^ s .O ^

1

1

o

o

U,

"o

"3 ^ ^ s ^ s 00 00 (^ 00 c 5

u-i CO K* S 3 a* cr cr cr o* o" cr rr C7* o U t) w tr cr tr o* o* 6

a m ta ra m rt ni <0 CO CD CD (8 w

n)>-a

0) ^ c

cW

c

a. r-l

II o o o o o o o o o o o o o o (£ CM 6 ^- „- a- «- «- <U 33 PC W PS 33 SzT" BS*^ 33 C o o o o o o o 8 a VO c c o o o o o o .Hg

cd r~! o n o o r-( CM in i-H ^ CM n

rt a . "5E c e

TS a

1-1 T*

COO fc O O «* o c 'Jl" V o 3

*cs *c-j o

"g ^ 'i? ? o o _i2--£2- "

,

-iL. 56
Co{lO^)^'ZU^O

40

" (X

1

1 o

u s 0^

T3

• rt CM VO o <f

(/I CO VO u

•^ in

00 ^ >- 0°"

pr* 00 U ^.

C-J o

% S

7

OV X "o

1

c 4

> rt o o o o

a. o r~~ r^ r^ r-~ i^ o VO 00 OS VO sg in in in in in r- CM I-~ c^I rH O a> OS 00

c» r-4 00 CM vd- CO t-l in c

1 1 1 1 1 * 1 1 1 <t 1 1 r^ ~"~

1 1 ' '

a OO X

i s

o o

U."o

_rt ^ <f eg CM O ^ ,-1 vO

6f 3 ^ CM in <(• <f VO E .?? °i

r^ 00 r~ f^

1) 00 VO c>I »* £^ VO rM 3- W « CM CO CT) •* 3

^^ o- tr cr* D" D- o o D" C O V a" 2* o

nJ m 0) (8 ni CD d c8 tS CD 6 CO c

nJ>-a

nJ J= C

cu

o o o o o

IL oII O

l-l

c^J c-j CM eg CM E c e e

J3 4) K W tC W ffi W w

3W D o o o o 8 0) (U 0) u XI c8 nS ca c 4J u

rt m M to

rt , , , u Tl 13 B Jj c JJ ^ E

•r) O

eg

to ra •H to o ^ X eg VO W o t( o CVJ * CM

<i- f

eg

t) O^ O

iH CM *CM O ^O

Ji o o U U CM H H ^ o n H v_/ o O O o o _iL o O O o
Cos

40 ° a <! CO u E

4) i i

•o vo m CO o

rt

t/3 O U 00 7

i-T r^ c^

00 a. <r

\P ^ s s

00 .S

CO m >^ ^

•-< r-l S

00 a

rt (NJ in vo U ^ o o CO CM 00 m ^ 00 CT% i i i oX ' ' I 1 1 1 V ^ >a \

<D 00 Cvj en CM OO CO <!• m CM ^ S CM vo in

0^ in CN PH o> o o o r-4 i-< CM CM -* >0 r-j r-^ r-I r> CO CM CO CO fo <t r-i OS

v2> r~- in

r-l vo CO r^ o c ' ' ' 1 1 1 ' I I

r> r~ li

OO ^ a ^. s o O ON t ° CO OS o vo vo U>

0/

rt ^ CM <r 00 00 CM vo

"3 ^ o\

CO ^ s s s

CO S S 8 S c O o O r-< 00 00 "i '^. 'I

'^

CO r4 CO t~! ^ ^ * 2 U3

in VO 00 CO CO

CM '-' CM CM ^

rt ^ „ ^ c o* cr cr cr O" O O O o o o o o W

ttf « n) to 0) cd c

rt>a

rt .^ C CU 4)c

'C

.5* rH O O O O o

nJ CN y

II K ffi K K w

to

<u •o e

p; C (U

(U CO o o o 8

XI CD o o o

rt D.

jt •H

(U o E U C

a. 1-1 N o o og o

CM <f :£':ra a

VO r^ CO

01 f

*-* *-* *-* ^

ai O O O W OT CO Si <3! ^ ^cn^in H o ^ O O O ^ r^ r<^ r^ r°. 58
rCo(NH2)^]N3

• a 00 o o

V

n) W U

O en 3

??

Ci

00 u:: >. 1^ h

m 00 a o

u ,

fsj CM -^ in ^_ CO

°i ^

VO CM CD 00 in 00 ^

rt VD CM f

CO -.•t 0)

' ' ' ' X

E

n) ^ ^ a\

>- n) in o o 00 o

a 1

^ d ci CM <M ^ vD c:^ 00 o <f r~. O i-< f-l ^ r-l OO C^J CO

i; r-l rH 1-4 ^ CM CO en lA •-I .-1 1 cW

c

8 f o

h

'o O I-- o <r o CM 00 ~* o vO o\ o

> ll

CO c^ <j- m s ^ og

inm 5 CO

Ofc

01

^

5; ^ 8 S

00 vD m >-< ^

°i od

o '2 o ^ ,-J CO IT, o^ CO CS VO o

U,^ i-l '"' '"' CM

J3 Oj J3 5

u cr cr cr o o cj o cr cr w cr cr cr

•rj n) n) t8 CO -0 W

c

njt ^ ^ ^ ^ ^ ^ ^

<i II II II ^ c g O °c. E B e E e e

C w W U o l

01 o o oT oT oT oT oT a

4J CM o 4J o 03 <f n) s

CO S 3

CO to J3 4) . . . S D T) TS •o o T3 w U U u JJ XI m

c

fli m ^

"5 °CM °CM °CM °CM + + + + + ? ? ^ ?

+ CM CM S^ o U. '~vo

CM

'~kl CO <t ""^D ^

'cm *C^J *OJ *CM CM ^ ^~rl Qo '^

JS^ s

o o

a g^o o

B s

o g 1 E. E E E

O O o o o O o

o ^ "o^ ^ "o o O o tJ o _o CJ o u o o u

59
[Co(NH3)3(N3)3]

O (1, o U E1

M U

'=? h

00 ^ 1:^ 0°" in

.;; 5: U

00

0- o~

rt u ^

rt ^

<u X j -a

rtc ^

k

rt i^

OO o o o d

OS CO 3

SD o 00 r-< r~-

ct! ON ON u-1 m S o lo in in

i-i i-i •-{ c

ll

OO o

o

U. o

"o

rt o ON vD CN ro OS so »d- ~~tri~ so

VO VO in > 3 ^

E .5? 00 -2 00 [^ o <t- SD

Of o •^ "i o o rH o o O

VO CO d m r^ CN r- 00 O^ cW ^^ ^

r- 00 ^ o r^ <! J S J3

n) o o o o o cr cr D- cr o D- cr o- 6

T3 W

ra rt « ca n) « a) C

(fl >,a

rt :£ C c _0 O

W

3

Oi O

s

CO 0) tS CO (d u C -H M T3 •H O -U C + rt (.

rt en C-J A_ \ , +

C

"3£ z

^cn S^ fo '~csi pc'^ O CO t, ^'^ ^ ^ r-- H <N O o O o o 2 o

S S

z £ 5 P3^ e B B -* ro <f '"'vD ^-C* * CM en -*

'"en '^ ^ '"V) ^m ^ '^ '^ '^ '^ 3 1 § i g

PC We rt "o ^ V "o^ "o "o O o o H o _o o_ _o tJ o o u o o " 60
[Co(NH3)5H^O](N03)3

" o. "o o

•o

, u

(A CO CO w -* oo r-l O

100 ^ >, oS Lfl

.ti X

(4 oo' o o

J Ol o m

^

C3\ o sj- t 1 g T

X "o

'

1 -0 ^ — rt>r g

rt VO oo CM 00 CO <N r- CO VD o^ CM r^ r^ cr. oo -Cl- a 1

^ VO o oC -* <? CM og 00 tn O in VO rH in' o

u <i- O OO 1-4 i-H O o rH O VO O- 1- VO

ri CM ?^ ?\ c 1 1 1 V 1 1 1 1 t 1 I 1 W

c CO ^

s

o

5

(X4 U

nl 00 O o CO >

rH <-( <J- in •-I in VO 11

r-~ 00 o o oru O o "i o O o "l

0) l-i i) o VD 00 -* o 00 c £* (T, O 1^ a\ 00 CO 1-1 CO <f

CO CO CO CO V

s> *i CT* D* cr o O" o o a" cr o tr o D* O D" t) D" 6

T3 a

fl) n) ni n) <d tfl t« CS CD nt C

nl

to :^ c C a to (S to «

•r4 ^J •H u

n) 11 II O 4J o n ^ c E B s

C O o o o o u CM cs CNJ CM

p. <u <o aa W PC W 0) ffi C ^j

(4 c n) d o nj O

o u o 4J O m o in o ^ VO 3 CM r-l W "O T3 -a

_c c c Qn C c B ra M •1-1 O Tt ra c

tt <i- o" B CM CM CO

rt la o CO CO "5 CM o o O

^^ *. A_ + §

""cm w_ B B B

00 "^

'^

v-* CM ""en CM O CM CO o 5 §

o e s o

13 «"• m u-i ""vD ^ ^ m in m

CO en i i" i

CO i tt o o o '~<f o o o o o H o o o

g o o o o o
40 6

s Q w

c

•0 M a rt CM in c •-< <t

i-( r-l XCD

•3?

00 i^ oS

•in

.t; S

00 a o- u U-l 00 rrt ^

VD 00 X "o "? £ > ,

n) ^ in innoor-n<Noo CM VO CM VO • r~ -* ^

O ^

j<; vD 00 ^^^^oocor^ CO CM r^ CO VD r-~ r^ ^* © 00 m .-< n CO .- in r-l .-1 CO OV

1 CO -* <f vD vO -* <f c 1 7 1 1 1 1 1 1 1 1 1 1 1 1 1 W

c 00 «

1 5

U, o

rt vO 00 .-1 .-H VO VO 00 00 00 -* r-- (TV > 11

VO 00 00 CVJ VO CJV or "1 000 ^. CM 00 °l

CT^ u 1- 0) 1^ f-! VO VO :?

CM CD 0^ VO ^

Ov OV CTv <T^ <r -cf VO Ov K

-*<)••* ri c^ CM r-< ^ <v JD w

a" oooocro-ocr CI" u tr

13 a So) 0) a) <d C

rt to m

>- c c a 0) 0) n td •H (4 -H P

rt -u j: c g

cU u •^ ^ <f u a (U c u Cvl R) ^ CO •*

i! 1

4J 5 CM .-f

"O ^ CM -* c ^ ". «- ^^ d^ "vD i

to V 01 -Is^ e "^^ e^ 0^ u

"o3

(«

4)9

(t VO '^

"9 00.—. w ^^ g_ CM 5 "^ ^"^

'S^' h s 000 <N

(Q O x^^ B ^

~a- b^ s z K r W

•3 VD m VO o- in vO CO P3 X z z

a n n CO CO CO CO CO g s ^4 i Eli 1 f

1 5 ^ S H

^'^ ^"^

<g —u..^2.
[Co(NH3)4(H20)2]Cl3

40

» a r- VO o 10

TJ

, rt r-I 1-^ 00 c<^ w u 00 00 CM 00

•3? Ci S

'00 ^

>. oS °^ K

00* a arvj 00 n m

rt s 2' 3' 1-! CO

VO CO

s:

1 I '

C g ;

Oi ;;:::;• >, J

rt r~ m m o^ r- in rH rH 1-1 i^ r- vo 00 a

o 1

^ ON 00 00 ON r4 00 <! 00 00 o\

<r> ro CO CM en in 0- n CO 00 CO vo in i i

«^^ OJ CM .-1 eg CM CN CO CO c 1 1 I 1

rt 5H t? ^ S

H 1^ ^ a

5

fe o 1

rt ^

VO

<l- <N CM o\ in 1 a S in

>- s

3

-* S 5. in IJ 5.

rn 0^ vo CM r-! ON cU ^^ a^ r^ m ON CO vo VD ^ CM

J3 4> ^ D* c W D- COD* D- cr c O' 6

n) «f <s ta n) 01 C8 cs nJ (fl

c

rta i-l r-< <-< 1-4

"tS II II n 11 ^ g s s c E B B B

c m (3 01 n! en (4 W 1) •rf M •H n •^ S .J^

D. u 4J <D <0 CM <U 0) M

c 4-1 -I-l 33 4-1 4-1 Oj 0) rt ca 4J -U 4J !-> la 01 01 S i i C i i C

"D m m m 01 1-1 c

nJ .4^

n) "3 fi 01 o £ +_^ *-. S

S CM CO SCM o ^ ^ 000 w

-* u< '~C0 CO '~vd'~vd ""vo CO CO CO

-22 § i" 000

H 000
[Co(NH^)^H20]CL

c^

" o< in E

•0

VD

VO

, n» C^l CM rH m

I-I rH

U-l

?P i 0^

00 :>:; '^

>- cji h

n) 00" a 0- U

^

vt 10 CO

rt 2 ? t r-l I

'

' T3

n)c ^

>

"(3 00 •Si m CM i-i r^ r-l U-l CM r-~ * CO lA CM CM a ^

^ CM CO en CM VO v£> IS 3

d CO r^ CM M3 0> CjC

<J\ CT^ CO CM <!• CO vO -a- -*

C^ CM CM CM CM CM CM CM CM c 1 1 1 1 1 1 t 1 I 1 1 1 1

co

? a

00 ^ ct! 'P 1 o> o

' vO vO 00 CV, r- C^ 00 <7» >

or "3 ,£ 00 .*

0^

ON ON

00 CJN ^. cW

VO iri v^ 1^ U.^ CN CO 5 CO

J3 s X3 w

cr cr c cr D- cr cr cr cr M 0) to « ca 0) «

Cm

>-a r-l 13 II 4; c s s B Q

c m CD en CD U

•H p •H ^ CM u 0. -u u

s s W

«

ID

<J «"'«"• CO n §

J3 I •0 •0 S

c

T) n 01 c

fll i-i c c C<1- CM

Id CO ^ CO 3 fi r-l '~<t E

<^

rH CM B Vi ^ CM ^ [I4 X* a S B z -* n Cp n -T" CO £

^ g E 1.

rt ^

H t3 u
[Co(NH2)5N02]Br2

» p< 00 o

tJ

r-

• "rt CJN l~^ (3> M U

o CO r- ON

•^P i 00

00 ^

eg

>, oS in

.ti PS OO a a^ O « ^

in 00 <(• s O C7\ CO

0) " ? ?

X "o 1 13

n) ^

>- k

rt ^

01 rH O CO r-l CJ% CM r^ -* r-. o r-l 00 CO r-- vO LO in vo -< ^ ^ (j^ i-I vo <3N r-! 00 00 ^'

t. i

CTi ^ <^ r-4 CJ> c t t

00

|-i r-

.-1 CM M I^ CM CM CM CM CM

1 I

ch

OO o

CMm

tM h o ' "o 11

^ 00 <^ 00 CM (N as a\ cs VO OO

>. CM

r-- 00 5^ <f CT> .-1 in <[• CO

CM c^ <f

00 §

r^ 00 00 CT. 00 O CJN 00 o>

^14) co 00 CO r-H O O

c £* en (N OO * e:^ 9 O ^ W

r~- CM <N CM CM CO CM CO <! -*

x> 0) .a

rt o tr o o o O* O CT" C O O CT- o o< o w 6

XI

in

ta CD n) ta ca Oj cfl

c

n)>-a 1-4 <-< 13 II II ,c G S B

c O O

W

c a CNl nT'

4J -P «"

Rl ^. td td '"<] jj -p m CO ^

B o <u w s s a s s i:l T3 h •H OJ 0) •H C ,_^

rt ji g. CO CM ^^ "B CM n a S E o it S S CM CO

fq M

H H H O § (2

r-l O cow-* ^ ^

pq pq pq w"' g > ir If

in m ""vD '~VD ""vo in in

,,-\ /-^

0) 3 & 5 iTi" i i"

l4 o n n m o o o o o o o H o o ^ o o o o o o o o

" " "
[Co(NH3)5Cl]Br2

40 6 E S S* 6c 1 o

BID • "ifl .-1 00 C s ^ ;il fo O 1

LH

CO itf >• ON

in Gt

00 1 n) U ^ '^. vo 0^ ^

Oi 00 u-i

n) •* r^

<D 1 1 X ' -a

(T! c ^ >a • u

OJ <N <N O r-l CJN 00 >* o\ en CM O CO <r o <N CM '^. o J^ 04 00 en cr> m ON .* CTi 00 OO m iH C^J O 00 <n CM r-| r-j vo 00 r- O 00 <r cUc

CM VO lO 00 2 ^ I-l t-l CM 1 I 1 1 1 1 1 1 ' ' . . "" \%

OO ^ ^ o

u. §

"o r. CM <N -* en r- .-1 00 o VO o g >

r- n cjN .-1 in o -* 3 X O CT\ CM CN en .-1

(jT E.2>

fy 00 r- O CJN 00 00 as °l °l ° u u as vD <» 00 ^ r-l as c (^^ m ^ S 00 3 <f m CN <f in s ^ t

U1

?^

1) ^ n) O D* O* o o cr o o o< o o* o o o- o cr o v o

T3 W

<8 ta CO ffl n) CO CD cd C

<i> m m a C C

(0 CO ta

iS II II II t4 P ;j ^ Ca U 4J 4J c

lU g o B B O

T3 c iJ « k> 0) o rt ca 1

4J o (0 (B O o in 01 XI c 3 g D

(U M

12 CO •o ^

"O -o to

JJ c c c

in Xi "o3 r2 l-l CM

(43

^_^ "3 to M

CM Hen '"cm H

CM H

CM >o

pq H CM C-J CO o" o'^ ""cm '"en s

03 o ^ ^ hH M H CM & O O ^ b O K Z Z M

rt m CO in vo vo ^o <i- m K

.2 3 i" 3 iiii E^ i c

en

rt i« o H o o o o o o o o Z H o O o o o o o o u o o 1
CoHPO,

4 40

O. o

T3

« rt ^ M u

u VO

'.P Ci

00 ^

.^

CO a o^

n) IN) u

§

CO in X o

1 T3a

C ^

a. o U-1 r-l lA CO in CT. .-i r~ CM -I in r^ vD r^ s ^ VO CM VO CTi r^ 00 r^ vo CM ^ CO c^ o o in g ^ o> r- a% <!• CO CM <N ^ ^

-* n 00 lO "? in in c 1 1 1 1 1 I

ll

OO o

rt ^

VO o 00 00 m <y\ <N CM ^ VD

>• S ro CO r^ CM 00 o- ^ "^ ^

or S S, S :3

(y. O

-f <t <-i So 1-^ ON

00

u-i

r-~ OO vrJ <f 1

to £^ ^ 3

in ^ ^ CM

VD ;S J^ 2

o

XI O O CT" D* w o o* CJ< O O cr cj* O Cf o o o

T3

nJ flj ctf CD n! oj ni tS

C

rt>-a i-< 1 C B s

to c O O ra 0] 01 c3 o

W

0) CM •H H CM C

o. tiT pa cu "o " O -P w

td ni

ra XI <u ^ [;;:; a

W

T3C 5

+ ^

a a

d*

c

<j- CM CM d^

+__ + ^ ^ H

pili i-( h-l vl- O —

o '~<f _•* o o _•* o i^ ,-i CM cr o w s

O

U^ H U M CO CO CO mm m vO ^ m CM

i^-S n CO '^ CO CO ^ t^ _-* i E i s i

i« o o o o o o o H o o o o o o o o

t*? e^ 5

67
CoAs

40

• Ck o O E

ex •o o

(« vO w O

r-t CM

•^ i

CO Ul ^ .|; h

(« 00 a a- U

^.

^

*.

-* o

00

rt s

00 ^

X

"o

' ' V

5 ^

>a

o 1

r^ r^ m CO .* O f ;S T a s s

o en NO o o

u-1 ^ u-1 o 5 2

F-H r^ o O r^ so

1 1 1 ^ U-. c

1 1 W

cli

»o ^

? o

S

U, o

"o

rt ^

00 <1- O C^J 00 CM Q o ^£> ^ o iON :? 2> oo ^ csi c^

uS r^ 00 o ~a- o

00 r^ r~- vo ^o m

r-~ CM en m

> 3 X

£.2?

00 en 00 r- -*

or vO vo ^ ,-< 00 a\ ctI S O ON 3 "^ -^

r-l tN r-l C?) fO <J- IS O CM <t

OO O CM ^ 2 i -* -< en <r ^ '-I CM

XI

J3 to o a o o o o o (J o o o o o er 2* a- cr u a

a 0) CD <d

c

(fl a rH ^ s

rt II II i

cW u

c1

co1uu

B BiCO

i

I 2

•o §

•vc

n) r

0) o ^

3 01 •n E ^ , h -o o c

(b CM 3 evj en CM^v ^

en CM CM o^

_<! s-o; 8oo

CM <n tn in CO no CM O

J3 5 ^ iM is in in

a o o o o o o o 1 f

4 o o o o o o " u o o _o_o._££.___ P" "
40

» p. o

4) VO

rt o

o in

•^

Ci

00 ^

>- tr h

CX3

nJ (VJ u «-l rt ^ X "o 1 £ m ^

^

(4 CO O O CM 1-1 VD VO CM CM 00 r-l in o VO o 1

X 00 c^ 0^ o r-! r^ oC o> CM i-I J^* <f VO CM ^ t-l 0^ iH CO ON 00 VD CT. CO m

<N CM .* r-l i-l CM CM CO t

1 1 1 1 1

o OO ^ ^1 3 O

S

U, 8

"o ^. CM 00 O .-1 CM O 00 O I^ CO r- I^ r-4 VD

00 t^ vD vO O CTv CJV OO o O r~ CM CM i-l or "3 j: S; S S

t-l OO vO

CO ov 00 >n m 00 CO 00 0^ ON

C^J O <N VO <f S J^ ^ i^ §

s

<f VO o OV s

CO CO

0\ C3S cW ^^ i s s

r^ CO

r-t CM «

XI o o o o o u o u c D* O w D" tr CT* 6

XI w

CS <B ta nj CD t8

c

nJ>^a

rt X

g S m

cW u

Gi

XI

ft

c

n) "3 CM CM

d

(3

s » if

S_ *. -^ *^

""cm ""oo '~c^

'"^ O

^

s g 5 g E

3"

CM i iii S S 5^

CO CM «* < < <

3 > > > CM CM CM CM CM u B a C s s s

^ 11§ o o "o *§ "o "o o o 5 3 8 8

_Si_- " " '-' 69
[Co(NH3)5C03]^

o o. "o o E

0) ^

( rt in C3 o

O

CO m

1

in

u: t

0^

o-i X

00afSl

1) § (JN CO

0^

1 -<

' I

IT) c ^

> rt t-i ^ O >-< r- <! 00 vO CM a

o '^ ^ en iA CM PI O -* o^ vo <N r-^ r^ go" CM O CO .-1 CM CTi .-( CO CM CO in CO :$ c

C^ CM 7 t 7 7

rH CM CO CO CO

1 1 1 1 1 .-1 CO 7

CM W

c

5 H

•o ?^ c ^ 1 o

U. o

"o

"3 X

vD CS u-l 00 O o^ CO in en 00 ^ r-- > s s 8 2 ;3i CT\ CM r^ vo r^ rH in

or O r-l (J^ O O O O -4 o

E .5?

<u 3 S

vO ^ CO

\0 S> •-! CM CO in .-I <f 00 1^o

U

CM J-4 CN CM CO .-1 CM CM CM CM CM ^ <h ^ u" tr O" CJ CJ D- tr a- cr o cr cr cr 5

T3

0) R) d n) n CO to CO to to C

Rlk i-i ^ M

n II II II X c e B 6

c O O o

w 4) CM CM U o. w w 4) X <u c u u

m kl o o la o n) <a o o

m n o 01 01 n

3 -S CM c T3 •— O •o c c 4J <f C Z T3 •r< -H ra I d^ -H 01 c O CM -'^o- < S £ ^ J + cPd^B O CM O o

"s CM+ O

£ + —

r—. CM

la S " +^ -iThtS 7b^

o

l-c o-S o o o 5 O d^ CM O O o CO ^ o o-

^o^ § "S <f b m lo O O PS ^N ^S ^-N S ^m <1-^-. i

3 3

Id iio o

CO CO CO oEC CO o ^

^ o H o o tJ o o

<S s S g o o o

-ii.
[ColC^H^lNH^P^Cl^ C1,]C1-NH,

' o« "o o

01 ^

, rt

O

?? in

00 ^ >- 0°" in X

n)

00* a ort U M-l rt ^ X1 4

>- g

rt o^ CO in m en 00 o in VO ^ 0<D CTV VO -* 00 a

o 1

j<; s' 2 S

VD r-l CO CJV e3N o o in CO eg en VD VO a

m H CJV 00

<y. 1-1 iM r-l i-< VO r^ M

c V 1 1 1 1 1 1 1 1 1 1 W

•f ^

^ o

o 5

Ui o

"o fH O CO 00 t- <^ r-J ^ i-i r^ >

00 00 S Sis CT. o m

^

ri rH CM <t

Otj cr. e^ o C3 eg c t^ ro 00 >-< in 00 CO o

cvj en * u-i .-1 CM C^ <f 00 ^ CL XI

rt cr o o- o tr o O O (J* w tJ o D" cr O tj o 6

to ca ta rt ca tS W

c

>^a s

(4 tS £ c s s s a s

C CO to m CO CtJ CO td CO <« CO Cfl W i) •H -H t4 •r) J^ •H !-l O T^ M

"a o. o o o o •" O 4J o «"• " "

m to o

+ 13 > ©

pf

vO

CO o CO if CM ""cm O XI ^ ^ O 'lo o + O S 8

c O VO CO

(Ti O^ Q«^ 2

1—. c

CM CM

n) s^e^ c < o '^ u o 3 5

CO -H .— E CM CM CM "3 cT' ^-s g /-^ <N CM '^ CM CM Cvl o '-N <h^-.

CM '^ o <N tC eg CM IN C^ 5 ii i isi fi •* >* <r y^ -*^^ —~* ^<f nJ* er--* pr 33 w CO re CO w w PC pH J)

CM r>j CM M OJ eg CM 3

O g O *cvi o O S B

H s s o ^^ i-l V-' ^^ O ^ o y o O o

o o o o o o o o o o — —
[Co(C2H^(NH2)2)2Cl2^Cl- 2NH^

40

o ci. o

C-'' c

Tl—

1

.^ O

rt

•^ lii

00 X. > # ir>

.T) 00 a oas O L

rt H

4) X "o

X)c ^

tl

rt 1— o m O CO -d- VO rH CM in 00 a Ji! CO 00 vO ^ \o v£> r^ o\ CJN ol CM CO ^ CM VO i-I ^, o in .* in in r^ vo 00 * ::! £j i-l n St

ev» OJ <n r-i y-i I-l r-4 i-i 1-1 CM C>1 c 1 1 1 1 1 1 1 I 1 1

co

£

E- OO ?• 5 ^

o

o c"

rt ^ n ^D 00 vO CM O <f vO <}• 00 o

CO <r CT> CO CO ON § 1

CO o^

>

Ofc

"3 ic inON 5

CO o

S 3 u-1 3

oj

00 !c ^ ON ON rH

en CO CO CS CO in CO <! VO :$ ^

J3

rt o o o o- O o o CT- o tr

<4 n) a w

c

rt•^a. X c g s

c 01 ta CO to I \ U

•H p u U U

o a o j-i u o lA U

C O O o

CO CM CM CM 1 g g g

W ffi w

« ^ VD o O o

D CO o o o

o o * o

X O o o S in O ^

c CS r-, ,-< i-T* c o U CM CO

i-< o n 1-1 M c: c o o o O -H •rl C' ^ CM CO ^ CM 3 O /-s H

o\ E ^ ^ -T" ^ O '-^ "^ '^ CM C-J '"cm

r-j o. '^ CM C-J O o ffi E s„C w w E O

-* fc 5 g. o E g. e 5 E in ^ <J- <)• O-'-N -* o- <i- * <t ^CM K K CO K w w S K '^

_4j

Csl CM ffi CM <N CM CM O o o u ^ O o o O O

43 vi- O v-' v-' <—' v-' o o ^ ^ o o "o o o o o

C3 o o o o o o o s s o

I
- ^

CM CO n r-~

CM CM eg * o

o\ in i-i cvi o t-i O o^ in in

«d- vo OS n

g e n^ -H CO w

OT M W QUO ^ ^ ^ o- " " " "
Fe

41 ~~ o - ^ CM CO o o E

4) " H.

en

T3 CM 2 <f On ^ in •-< CT^ in 00 o

rt ^0 ri fsj in en d in ,^' i ^

CO " <r *? en ' CM u

I?

Ci o

-3- s

On «

00 ^ ^ ^ CN cn in

>. .a ^ ." X —. a

CO O o 00

00CO J oo" 00

oo"

"*. CM vD

00 m CO d nd" i

00 ' in o ;:: -* X ' ' ' ' c E

n) ^ vC s* > r-< 00 ON s o o n vO ^ o a "^ o ON <o r- ^ m ^ «n

^•

C3N NO ON

ON 00 in vo VO lO oi NO CO CO PI c 1 1 1 Wcou

oo ^ ^. 2 <>. 00 00 ^ o

oo 1 o o 00 ^ -;t d m in in

c^ 00 in vO ON lO

vC U,

"^ ' ' "o

(d ^ ^ "s" oo "^ vO "¥";:;:; > 11 ^ 00 <r i

ON U~l lO 00

u-i 00

oo vD

CJ^ in 00 00Otj 00

O^ c " en X ii ^ CO 00 00 o- 00 cr cr Oa

ffl <o a CO td c

nJJ^a

nJ X. c cw

TIu

CO D

t3

II E

2~

IIE

9?

0) E

4? a

IIB

4J a) c

(« a) <a 0) O al V <d w

4) 4J 4-) 4-1 -r^ m 4J CO a.

CJ H I

c: 3 T3 tj 01 •o 00 •a <u •O 0) e s m i m s u m a ^ R ^ (fc -* o ^ CNJ ii 5 + X

ON CN( m <t + o

J3 + + O o X X o o + CO d o O*^ cs n o O o^ " £ ""S £ £

<u s fc! lU £ s £ i £ I
FeCl00 OJ o ^ M n

o. o vo oc> o 6

T3 <7> ^ ^ in in -* '-' 0^ • nj iri in a^ d a\ in iri r^ 00 in

CO OJ ? 7 7

'^^ 00 7

OJ O 1 k

CT^ CT^

>- 0^

in CO ro

00 1 d fSI c» en a> O § ' VD ^ o o " d O -*

-* 7

<i vD <} O en

<u

'-' '-' '-' -1 -1 1 •-I -1 CNJ 1 1 1 X ' '

<ic ^

>- ^

rt r-^ C-, ^ ^ en ~d- C3^ ^ ^ S u-1 CM

0- 1 ^ VO ^' 00 o d oo" CO -i ^

^1 en ^ 00 ^ 00 s in ^ <) 00 1 o c 1 1 1 1 1 1 1

OO ^

'^ 1 o s 1

U<

n)

.-1 s ro

<f s "^ ^ en >cW 11 00 o5 i^

<f 5

:•

in h^ '"' ^ '^

•j x 4, ^ s

c- cr o- D- cr cr o J- cr cr cr 50 cr 1 (0 m cd TJ CO 10 CO

T3 W

CO 1 C

n!

II S^a E

rt X c S^

fe 1 c o W c3 o - V -

II II II -II - oo+ - - « e D m s s E e e e e °CM E E W C a? m Q) (U cu" (U <U w cu <u c O

CO 4-1 " td CO CO 2

CO CO o CO cd o 4-1 4-1 o 4-1 4-1 CL, CO r-. rt o

"p o 01 •o 13 ID T3 p c 4-1 4-1 c E

to & m m CO CO CO CO CO CO

<t + ^ > ~* +

EC -1- V X ffi O + + 3 o O O CN CN fa fa fa fa O O rt <u (1) 0) cu cu <U cu H ptH ^ fc fa fa ^ fa fa
2 c QO 'i ^ rt U b XH t! J

<:u > 2

^1 uX M o to ?! 5 w O U X) S rt J< j^ > Jh p ,c uH W U (0 i3 s W 'O « !s CN CM CM o o o o o o o o o o o o o o
•d. "o o 1 -1 w o S :^

oo ^ >-I

00

nj rM r^ o • '^. <js ^

cm" -* CM

n) r~- CM

<u X "oa^ o

rt ^

'-; '^. 00 0^ -* OS so <! <r CTs r-< in '^. -^, '-; 51 u-l u <i o o o <N CM CM -1 00 CO in CJS 00 ' c

"^ 1 1 1 1 1 1 1 1 1 ' 1 t 1 o

rt oo W ^ § ^ O ^ h

rt <J- so

>- 00 so csl a\ 00 II

CJs .-1 <!

Wi PJ in o- ^ ^

r^ V CO <f 1^ 10 <J- cWm f^^

in CM in in

CM CM c<1 '"' ^ V 3 " bO M "

ta

CT" a) c

nJ

'"' ^ II a CM

rt o o o o U U

J= c X P3 ffi m ffi W K X W X ^ C u^ w u p. o o ir, o to in 00 <f CD C

en CXJ C-J 00 in J-> "H -d- tn <n CN csi .-H

II II ro to + + + + + + + + + + + 3 o o o o W e e D CM CM to W uT uT rtT 3/^ X X W^ EE^ sT' 05^ X - u c o o o <J- OS 01 o o o m .-1 in in X

CM •r^ en 3 0 •a g c c

•H •H -H 0] _,

;£,

-a- P3^ + ^ S _<f Ji -* U o <U CM 8

OJ Ctt UJ 0) (U (U H iS f>^ c- fe fe fa fa
° p. "o u

61 ^ U-, -* " O

o ^

vO >D

1

in^

5- •1 in

00 a

(i vO 0t5 7

X "o

X3c ^

> J n r- O -< <f v£) r. <r -a- 00 c^ ^ ^ 00 CO r^ O (O a. 1

X c^j c^ tn ^" <! 0\ r4 cr. d o^ 00 5 S00 CO CM CJ^ CO •** 00 00 00 ON CO r- 00 CTv CJ^ .CJ^ 00 VO

t t 1 <t c

OS OO o

"o

rt ^ o \D m <t O 00 > 3 ^

-d- CO <!

00

u-1 in" in

CO

VO CO o\ CO

CSI <* U1

J: i J3 5

cr o- tr o o- O 00 cr cr cr cr cr cr cr 00

XI

ffl a to <s m « <a 0) <a B) m

c

nJ^a

n! j: c

cW Hic

II ^

i-i

a> E E O o e o o o

^ O O O ,? ^" «" ^ x'^:^x^

c

CM eg cs( •u O O i-H U o o o X X X 01 a) in O CJ fl o o o m E u o o o o o o n - ^ ^

j5 o o o r-l Z o o o CN m o -H S . ^ <N O- 3 D o 73 E

C ,-1 o U J-. c; e u c H W -H ^

1/^ vO "^

fc CM *CS ^ CM •* -* « o o^ + vO

e»i u k E s u M CQ (S

PQ O

(U <u (U lU fa H Ct, fc fe fa fa fa 78
° p- "o

C) £

TJ^ 00 CO n

m

6" i

d •* ^^

1

LO

00 ^ >- in

n) 00 a CTnJ fM u IW ^ o s ^

rt ^ 00 \0 c<i 00 V w -* r> X

' ' 1 E

<i ;:::;• a 1

<f vO O -H m rn 00 o in r^ o . '^ . fO o m ^ t^ CM ^ •*

op rj -H CS r-l -* * r-i m

c

1 i-i 'T T' T" V

"7* ' ' ' ' W

c

_0

ri t? ^

£ § ^ o

t -

_rt ^

O- CO CM vO >

.^ U-, O -H o S

?1 CM ST E§ vO rC ^o

t< <u vD <N <^ vo a> > O 2

° CO .-H v3- vO 00 ^

XI

tS o o" o" cr cr tr o* cr o M 2" 60 cr 60 oo 6 OT

<9 « «) <s a CO 01 « CO

Ga>a

"(3 X

g

cu UJ X! c

a. ^ ^ ^

rt 'i:; 1 o o o o

°CM 1 ^ ^ m aT* X X 33 ac X3 <o

ID o o o o <u <u ^ oT o o o o o u t

CDm

o^ o o o^ o «l 2 a u

O* iX" o o* o CO z 00 a ,-< ^ CS <f CM

^

<i •o •o •o •o c

4J c

"B m ca OH •rl CO ^ g

vO

,_l Ch *

XI ^ *M hT CO M-* M^

ea

4) V v <u u h h h h h h u. 79
"1.000^

41 ' oo vO o -* 00 o 00 o ei

o. o -

-*

s5

>* i

T5

00

CO O

n) ~» 2 5 ^ S S sf 1

in § S ^

00 « r-l t 0^ in

00 a CTrt fNJ u § o ON On CN oo r-^ <7N St

li ^ ON 00 nD ^o J (7N >*

0) PO ON ON 00 ON VO X ' ' ' ul CO c ' ' a

t. 1 u

ON ^ o O o> ^ '^ OO r^ CN ON O

J.; ri cs r-. <o ^ i i

r^ CM r^ 00 d -a- cs m CM ON o cWc 1 1 -I CM CM r^ ' ' ' ' ' ' ' ' ' li

•O ^ o rv nO o -»7

-» 5 -' '^ ho jti ^ ^ CJN O o CM > en o yO O "a ^ <t CM Pv r^ E.2?

ON ON ^

ON ON O c^ V u o r^ ON ON (A 00 r» c ° ^ oo NO CM r^ •* W ^ -o "^ a o (J u u u O- or u- a- u o (_, ^

rt TO S) to « <s 6

XI (^ c

(fl >-a. t

rt 2 X c

01

4) 4J 4Jo

o. o c J= 1^ II nJ n kl ai u o. E E B O o XI a -n . CN 3 D

<U X X (V V W X iJ 4J u 1 o B) O o m A

4J o w u "u u «1 CM O a

<i c s 3 o • ,

fl) o o <f 73 •o '5 k i 3

li 5 a

4J

10 P

.2 p^ U, o O *

CO O CM X CN i< + ^ 3

00 <r -* '-a- '-* '•* o o o o o o

«i VI w CO H 41 <a a> OJ u a <u b t»- &u 0. b h. fr. b
o o in

-* VO VO r^ vO

a. o

e

ri in r^ tn

i-< m o

-0

in * r^ <t "J

rv ^

00 r^ o\ CM to o vO o !>. VO VO A ^

o CM VO -* U

?P

r» t^ 00 00 VO

rsj in Ov c^ 00 cn CM C3N o en CM 00 ^ ^ T

in d oo' a o^

(i IM O ^

rt ^ 5

K "o "?

nJ ^

1 1

O (M o

to ^

>X1 _ LO

e<i o\ r-I vO o

oo !^ o

t-i r^ s m u-1 vo VO <r

vO vO IS vO 1" VO vO VO vD ' ' 1 ~

.2 o

fe § o vO in « s

5 ?

en 1-1

vO CO

ON o 00 en en

VO VO

5

> <Ti n 00 00 -1 00

cn " "^ CvJ '"' O r-i cn '"'

rt

tx ^ o cr c U" c o" tr D* u o CJ o o

T3 a a <d « ca td <s E w CD C

rt^a

"(3 ^ c

c _0 w O

c oD 1

o O o^ o ^ ^-^ _

91 Cv eg o o o

•u

CD B X EC == e3 "ex"*

X) 4J o O o a: a s

c o o o o

5

ni si- o O 25 Z O

M ^ iTl VO

(U •o o. o. "5 u

<0 •Hc

•r<SOBTi V a

£

00 h f> en (U ,2 f ^ CO-* >a- 00 H o ii (U 3 9) 9) CO r^ H H

4) w OJ 0) « (U (U <u 01 H h [t. b [b tb Bl, (b tu fa
o. "o o

E

4) ^ 00

nJ . O

?

r-

"? a>

1

in

00 ^ > <7> in 1

CO*

(« u ^ m a> 00 __ o\

rt ^ in o O^ o^ o

4) r» 00 I '

njc ^

1 1

vO "^

CN n r-1 O

'^ O^

00 ^ in cn OO

'I '^.

>> v£> vO 00 OO -* <^ rH O S CM C

c

•-I

. 7

CM CO

' ' ' ' ' ' '

l'^

OO ^

% o

b

"o ^ r~ ^ o> r^ OO ^ ^ CM r^ r» -< vO CM >

r-1 CTv Oi n ^ vo <^ o> m lo 3 X vC o a^ m 00 i-i ro CO <n CJ\ CM

tf E .S? 00 m OO OO OO 0^ !>. 00 o» CO o NO r>.

lU Ih <u f~. r~ in rx ^ O <o ri O OO >» 1^ CM ON c ^°^ r-i <T O m <r lO CM vO 0> CO ^

CM '^ .a- '"' -^ CM CM CM CM CM

J3

1; sr o — cr cr cr u cr o (J (J o o o o 5

CD « 6 w

C

n!

J,, a

n! c ^ .- ,-, ^

u o 1

" 1 " " c E e E e

rt o a> <u <u J2 B

D « « « a W go <a -ac

rt •v a T3 V

rt "5E o

a CO

fc S m f CO X

+ X X X z CO X

J- + CM o^ X z z Z O

z CM >0 i S

4> + ro

c5 o O cT O

g

"cm '(N CM CM 3 c z^ z S z.

R) 2 -a- o o o o o oa 03 H

QJ a) OJ 01 o <u

fc- b [b tb (b b b b fc, (X. b. U. b (b
° o. "o o

T3

to U

n)

?f h

00 ^ ^ !?

in

nJ 00 a ort o ^

rt ^

D

rn ^

> nJ 00 - .-< ""i

'^. 00 <f rn -* O in ^ s

^ 00 r-! CN en iX CO c^ r-- 04 ON CD VO

-I o^ o> ON in 00 o m I-- CO <f n CJ I 1 c

' ' ' ' 1 1 1 1 1 W

c

rt OO W

2 % o

fe

-'

1^ r-~ o m CM 00 <! O n

ON ON O i-H CM

00 VO

>• CO r- i^- o> vj o <i- 3 X ^ ^

^ CO vD o n ON CN ON

*' g.??

r- 00 ON ON e^ o CD o

<u IH m r~ r^ CO t-l 00 iri CO o <f VO r-I c ^

h

•<) '-' CO VD 00 O CM m 00 .-1 W en m m <f ,-1 rH CM CN4 CM I-H ^ 4) ^ n! o o o o ^ o o o o o o o 6 W

tfl C

rt>^a

n) £ C

CU o 1u

c

<« "3 o E

d^ m fo

"d- O* g-f fc CM fCO f-^f fVD u CSl v£> o *-* "-**-* -* *

3 h u IZ o o o o o

(4 « PQ H 1-1 w CO CO CO CO pj a^ H HI <U 0) <u a) (U a) (1) 0) fe fe P:. P^ |4 PH PH fe P4 [X. ft. fe
lO n CO NO in ao E

0^ 1^

sj- CM >n

0/ T)3

CTN o CM 00 V*

CO O oJ irl CM o NO

-* <N CNJ CM 00 s U

•pP in O

00 ^

vO

>- T

inCO a <r

ifl u t- C^4 OO •fi, NO

inNO

01 ^•3 • vO >* ON 00 NO

0; ON u-1 NO NO X

(-1 ' ' ' ' o

rt ^ § 1 ^ tn -<r lo o ri o >» ^ a^ o\ o ^ o <>j ro NO r^ ^ in n CI r^ oo r*. c ' ' n t 1 en Wc ' ' ' 1 H §g

COs o

00

[x, "o a oo 00 ^ ^ vD CM vT lO 00 r« 2

ON r^ r>. -O

Of "S X. vO <• m O^ vt U-N S; E .?

vO m 00 00 in n U-1 OO 00 00 V t. (U N CO o vC tN r^ o^ o^ in cr. in c ^> ^

ON oo VO r^ ON 1^ ^

rv ON

J2 B " " ^ y " o y J o o o- M

(5 w ^ c

nj:

_a

rt j= c C _0 U c

a) XI3 a

00

-ac

0) c

rt i »4

<u 0) o •o

4J •H

la b £ o

fc O «N

•a- X^ ^ in

_a) s? -* <t (/) CM m o O 3 Qw CU £

(U 2

01 XI ^ o O (N o H

0) a) ^ S £ <u ^ "i <u

i:^ b< b. fa fa fa fa fa fa fa
Fe(CN)^

41

•(X "o o B

01 T3 , rt m -* VO

OT

6"

00 <A 5 1

IT,

(NJ w

>. 1 oin

00 a ON

It IM o

rt

U-l u-i

u-i o CO v VO ^ X o * CM

njc ^ - ^ 1

CO OO VO ^ CM o\ ^ vD OV Cvl f„ CO cWc

A!

<f -< O O CM • ° o * • • <?

-H rH .Q. vO in m m 0^ 00 s vO VO vO en 00 n on i-l ' • .1 ' 1 1 ' ' ' ' '

.2 t?^ o

fe

rt r>. VO o CM Q ,_, >

or

1-1 "a 5 j;^ s

Cvl 00

1^O « s 6 M r» o^ o^ rv VO 0\

J! u 'v in <N c^ r> ^ ^ c ^^ r^ CM PI

<0

en n en «* CM ^^

Si cr <r D* o* cr cr* O" w u D* o c rt at tg cd 19 (0 <8 cs «8 « « W c

nJ>.a

rt ,C c Cw 1

0.

10 1 1 °CM 1 ^ B r ° o O o

°cs

3='^ 3 a> CM 0) CM CM CM u W ^ SB JJ X K O 4J

ID 0) Rl "O U O 4J O r^ c 00 o OQ o

(t en VO "^ o_ f-T

rt •X3 o

'B u c u a C

<a -H IB •H •H to ^ £

CO

PLI cT) m h

<r ?* °^ o M M CO tn «* * VC v ^^ ^

as ^o

CM 1 1 i <i H ^ £

(U fa ?

«) ?
Fe(CN)^

41 - >

"(X o

T)

r^ M 6 o C^ <r

cs

?? h

00 u:

>- tr i;

(4 oO a o

It no o o • o <* 1

rt ^ i d r^

i) X

"o -o

nJc ^

>- ,

"ifl o- ^ r-. a. On CTn ON >c og GO ON o a 1

J^ 00 OO vO o^ O^ 00 00 u^ 00 d d <r d vO O 00 -3- CO o o CO O ^ -1, .-H cn <t 1 <r cc

rt OO « £ 1 s O b

"o

n)

•-' en 00 ~00~ m ^ o o o <f in 00

<r o en o 00 CO o ^ >- 9 X U-, ^ CTv -* s o o in

6f OS eg °'. (T. °'. '^ °^ "^. t S ^ CT\ n o>" li^ CO <r i ^

<r >

to

<M 00 CN eg '"' eg CM OJ CM eg

J3 a; J3 a- V cr a- cr o cr cr o cr 6

3) a o <a o a cd

>-a

rt X c cU <uc a ^ ^ ,_l ^ ^ ^

rt

11 II D D II -Q

[0 B e e s E c ^ <u dT ^ (U oT qT (U "V u c « a y a) 0) o 10

(« iJ 4-1 u

en + z o 0) R) s

x^ 3 •o •o E u X c

^_^ 01 n ra Z -H 0) m 0) vD "vD 0) vo X z z eg Ch > z" "cm VO NC ^ o s s

>» "* s Z X ^ -'-V ^ 4) z z o O z z" z" S fc- fc. u £t

y-^ V o. z" o CJ " s <r <f ^ § ^ o^ g 1 o

<u 4> Oj u v3- >* oo ^ <r o (U fe fc fc< § 1

<u a (u 4) V « fc, jn en o- H b Ci, (K tl. »x X ^ X X s I
as CN o so _,

<f vD in r^ "P. 6 ^ u-i r-^ 00 P^ ^" o -1 >-i x-l eg <t CO

0) •o^ o CO VO 00 -1 I-~ o M

,_; r-i CO so <!" d ?^" c^ '"' '"' p

'^

IM

ctI 5 £ ;2 S

>- 00 ^

'^

^'

CvJ og <|^ 00

nS o

00 s

(SJ o ^.

^- -* cs o^ CMd i

"^ ^ '7 V 7

CMCO-* X "o 1 £

(fl ^ o

nJ CO M3 VD <f -cr r^ so 1 ^ vo" r^ \o u-i

1^' o" O^ csj co" CO ^ -* ~* ^ CM o , c 1 1 1 s 1

eo w IS 2

CO in O m ^ o r-- ON S CM

i-" 1 fe^

J2 ^

r^ r^ o CO CM VO

eg O ^D CO en o o ^ CO 00 CM CTs CO r^ CO or 0^

in

a^ Og

0^ a> o CM ^

1-1 in -* cs I^ d o 00 t-l Csj OS 2 CO o S CM <N ""* '"' 2

JD 2 ^ rt V o o cj O

(8 ID 0) a W c

«j>~a

a) X c c .2 W oc3 o

11 11

OJ D

oT w <u •H XIc a S u

<a S 0)

(0 >,

n) V <a <u o tH 'a •o °(M

a" >. o

!c a ? m ^

'^^ " oa b M-l ^so

(l4 "S S" + o O o cii CO 2:

•a- o^ O^ o^ z

CO

CO C0O-* PM o V u u o CJ O -H 01 3

01 01 OJ w •H CO W H CO fa fa fa fa 0> (4 c^ n 0) 0) a 01 OJ ta OJ 0) fa H aT X K fa fa fa fa fa fa fa CM PM
FeAl

41 „ n in —1 «n o^<X "oE

o^ -* o> •

tvi n n

0/

>* o 5Q CM r^ to

"<< U1 o vO ^ <n

<N tn cs CI U 1

in oJ

00 >i

>-

CTv in00 a cr

n) r\> o t, ^ m CV4 O vO r»

VO

n) ^ rvj ^ vD >* Ov •* • <» u-1 lO <n ON o X ^ "^ CM '^ c E >a °^ ^ o

00 00 O -

o^ >A 1^ VOo r~ ir\ (^ cc 1 ' ' ^ —

•-< ' ' ' ' ' o

a: ti -'

rt ^ o u-1 vO >

00 o <r m (SI vO "3 X On O VO VO OS vO s m or E .2? "^ oo ^ 'I o r~ O oo

<u vO n vO CO 00 Ov c c°^"

00 o n vO ^ r^ CO vO u-l 2

'^ '^ "" <r o n <N S " - u " ^~ o o o o o o w c

rt>a

rt X c ^ cW oc o 1e sw

•^ 3 s ^

>s c

(t :s g

•H

rt to &

"a O °~ O 3 3

In E

s"'

CN E-^

tn VO VO

-a- VO Z z' 1

S" o * o "* O O o O O <1) O (M J3 h 1) Pb oT* 4) -5 t 1 ^

fe ^<1- c"* % 1 Uu Ck U. Cb H E-i N N o O o
fo o o> CN •* o -* CO ^

-• CO CO 1^ m cr> U-, H1

;^ ;^

COCO s en CO ^ J^

^2; <N r, w o> VO CO o C-J W 6 ^ fO ^ CO i ^ i PI

??

-* <t m o CO i-H St t^ ^

SJ

(M C-4 VO r~ vO 1 in in in in m in m

00 ^

'^

00

(X CTn! (M u <4-l o O vO 00

rt ^ VO c^ cvj X

r^ 2 c3 -*

'%

(i ^ a 1

rt ^

-3- 00

in

CM *^ CM c 1 Wa

OO

rt « *^ m ^ i O a d M 1 h * o 00

>- O ;^ o ^ S 5 g Si

or S o

VD

-*^ 1

ON o CO

?^

VO

CN m VO CM CM CM CM 1 rt o o O " " " o o O " 6

XI W c

rt>a

"rt ^ C cU

CO

XIc

"s * O 0-* O w

CM < < < vO in <U <1) lU (U 'vO U. h fa u. ^ C^j vO ey. oo r^ VO

>* <U S d d d d b. o o -* c c c ^ .* o N_^ N N N O^ o^ il r^ 1) CM CO ^ 3 d ^CVJ ^ o o o o o aT"

(« 3 3^

iP g! •H •w o ^ O CJ < S z z z z fa o
— 00

i-l vO CM 0^, • CL vO <} r~- o E

6/ •o 00 O ^ ON ON to

5"

rt °° ?i CM n 1 S

CM

VD 13

•pP in

CO ^

r-4 t-4 >^ OCN ai

3= V

oo* a S U .

<N '^. ON -* o\ 00 o VO 00 ^ O •-' CM r-~ in o^ d VO O^ CM

rt oo •* n VO c^ O oX

•a

n)c ^

;:; > a »3- <) ~* r~- O O o a 1 u o d ^ CO d <t d CO ^ cr. -* <r CO in

ON 00 en <r C7\ CM 00 1 00 <f CM •*

CM r^ -* c

rt i

oo <N| <t in ^ ^ ? o d CM d d • 3 Ov 00 CO a <!

l! s;

"o

(« II o vO CO <r 00 -*

CO d

-*^

00

'I, r- 2 S d o r-l ^ .* in

'^ ^ ^ ^ CM ^ CO CM ^ &> j: o to 60 00 O" 00 O 00 o o o cr o cr cr tr O" o*

10 to a « « 08 ^ ,-1 r-l c u O

II 33 K > 5 Z 3

nl a) c c

X. c

4-1 0)

1-1 ^ C o U U c

o.

11 7 B i-i

II II

<-l

nJ a E 2 e e E m •o •o to ^ 1

(U <u 3 9) <u <u <u U <d Ul 4J u

0) OJ <a 8

<a s

tS X n^ •u 4J c (» o. a (» CO m 0]

CS 1-1 1-1u

Si •o 2 « •6 c "O •o •o M c 4J 4-> 4J 'a m p. a 3 to 01 m ^ B

-* U. St <J- 3 + A ^ « § 1

+^ r-T" C <t VO O 1 1-1 <-l "O 1 (d O CMV-- o O O O O Pk H •c •o >o "O "O •O 13 •o "O o •o •o "O CM 1 fil a (S ft pL, O. A. FM Ci< Ph _£j._Si..£l. 90 I
n CO ^

^ CM CO

• (X o s

1) d s

•o CM in

rt <f w d s

r-I oC CO

.-4 i-l <J- S

^' u _

•^

Ci o i

'co ^

CM <f

>- o\

«J 00 a CT- a (M O t-l CD o "i o o I^. 00 ^. , ^

vD o in O 00

•d- r-~ oo ^

(U 1 1 t 1 1 1 1 1 1 1 X

XI B

nj ^

a

o %

U

-* 00 in 00 o> vo

CM

' c

E 1 O

tj

fe !^ v« "^

n) > "a ,c CM CO s

in ,-1 CM CO VD CO VO o o CM CM

bf £ .2? <^ CM O 00 <h m vD o KO -* "^

<u M V d <? 00 C3 r-! g

l-I C3 c ^ £^ vO <e CO r^ in VD a\

05

CO -* in CO v£) 00 r-) 1-1 ^ CO '"' ^ V

U3

rt O tr o* c o D- 2* u u c; o O c 2* 6

T3 w

tij « 0) CS « at (0

C

ni>.

a.

nJ s c

Cu Pu

II II ^

II

.-1 "^ r-l

II 5 S e g B e e s n (S ^

<s 3 0) 0) <u (U 9) <u <o W 4J jj u

XI

cd cd s H s 2

c in oa m « ca m

. . . m "O 13 "O TS •o a 4J +j jj "5

CO m (D m m

^,^ E

Ci M

-*

1 -* 1

^^ Li "'vf > CM '^.f '^.o <N m <0 CM S m m 1-1 H M ra CO <h H H ? t

H 2 _2_.2. s .^_§_ s s s s _s._S-_s. s
•^

o o o cr O <7" O D"

O 4J 4J

SI m to

CM CM en • CM -d- ^

fe 6 g

si- OT

CO G

_&L.^

92
^ (- 6 P<

(j> o OO Q

CJ

«>

"^ ^ •* 1

no n 00

ec » rt c-l c OT o

t^ 5 1 o ^

•pP in S

CO

>- s ^ ^

IT

in00

S. o^

oj (M O M-l rt ^' l-l

aj o X

CM XI e

nl ^ a 1

<« ^ ^ vO O CO U-l O 00 u o (*1 vo in fn <N 00 ~^ vO cs d rH VO CM VO O CSJ >* ON O -* -1 00 CO r-. 1-1 o vO c c^ r^ <t- CO ^ ' '

rt OO W 0^ °. « H I ^ o o S ^ d ?^

CO r- -*

di'o * 00 CM CM

>. "3 ^ g s s § H! 3 CM

t>n s g§ °l * 00 CM

lU >4 tl CO ^ s

CO 0^ lA CM c £* o r^ O 1^ W

-t rH CM ^ CM CO •* ^ ii 6

XI o tSO 00 60 60 60 60 60 60 O 60 O •* Z " c

«)^a

(d ^ c c o U DO a C

ni

4-> ^S

CO XI -3a

Rl rt 3 m Vp3 in 1

CO + CO CM C ^

<£

CO'co

i4 3 + t ^ o+o

CM^ CMO 2 S S 5 S S S is S 5
Ru

44

<t Sf

r-l a "o o u-i m 2

;o o

CM iTl , <« 00 m O 00 o _ OT o

u ^ i

in f^ o^ -^ m ^ vo "^

•pP Ci o o

vo

00 ^

ts. >- en .^ i;

g.

CO*

It (M o •

<J- fO ^ ^ >* <M r~ vD

rt ^ O tN i i i i :^ i ^ i V t II

X "o

T3 E

n! ^

>-a

o

<4 vO 0^ O <> ^

r^ csi vo O «n

>H O ro sT f^ O 00 r-! <r -* r-! rH 00 c

li-l C<J ^ r>. r». -^

jr O

rt '-' CO ^

ci o >o o

1 O ° s jd s i t

rH ro r^ ri

"o

01 ON 00 oo U-I OJ

vO VO ^ 00 »o 3 x: O o o o § o

so

JJ

ti 4) O r-i 5 2 m OS

(0 ^^ '"' '^ ^ i a

J3 u cr

rt O 00 OO 00 oo o ooo-< ooo-CT-o-o- U 00 w

e ^ 0) CO <o a

c

rt>~a

R) ^ c

cU u

c

XI3 1uo

a

e 6 e e

01 U 01 0) W u u u u

•a M <s « 0) "d « 4J w u u

c 4J « (0 n n

(« 2 . . . .

n) •S -O t) T3 "O '5 >, 4J 4J 4J U ^ «.«<»»

^ g

~a- b -3- A

V 1 /-T* ^ 1 cs X

nl + 1: * O^ o o o o ^^ uT H 3 3 3 3 3 3 3 3 3 3 3

05 OS o: OS Btf CH Oi o: OS OS OS
o. "o o ^

•co U s

?? in

00 w ^ t?

in

00 a <y~

n) U t-1

r-.

rt ^ s (U X "o ' -a

(Un ^

>- J

ti 1 ^ en <^ 1^ u o^ d oj en in 1^ .-I d Wc

-* " " <f

12 cvj •2g

OO ^ 1 s o H

u. §

rt >

oru

'^ ^ OS 00 * "-1 3 ^ CM 00 ^

ON ON ON .-1 H .^ * 00 r^ f^^ ON ^

<u u d) CM r^ in G ^^ o <f 00 ^o W

to <M CM <N en -a- ^ 1^

J2

rt o 00 00 o o O o o o 6

XI w c

n)a

--

II rd ,£ c e C ^ W 3

4-1 2 W JJ B

J3 CO C

(«

rt ^-T' '5 OT M <N

cs

«-N in 5

u. g

CM O T 'en ^ -d- in en ^ '-' 9

nt CJ M M O 3 H s <s _J_ ^ 3

ptS ^ 3 Pi
Pt

45

00 o m«n u o £

vO vO 9. Q 6/ c

T3 in S ri

CT> 0^ CO CM 2" « ON m vO « c w m 00

'£

ID ^ O

?f r-1 ul

00 1 — • ^ • in

00 itf « ^ •^ oi00 a cr

(« u §

<r ^_ ^ CO pH

(4 o -^r -* d

0) <r s i I "o

'" ' ' T3

rtC ^ >a °^

rt ^ O m n

ON o

ON vj o^ NO

NO ^ 5 n oo 1 ~» cC jr

-- r-> r^ 1 1 < y

t?^ o o ° 2

o^

u,"o

rt ^ ON 00 U-, O <0 NO c^

On 00 vO o 00 -» ON -»

1^ E .2? o t»j '^ o in «»>

<u r^ o^ ON o^ d in £* ON CM (S. O to NO o W

eg NO CN fO CN4 CM to X a; j=

rt o 00 00 00 o- 00 (_, O O 00 o u cr tr o

T3

iji a « a C

n!> 1 a

rt V C s u 0) •^ (0 c a

00 1

•o ^ 'J C ^ « «

iS W C 4J w 1

*J u O

<« . 4J . 45 3

«j •o JO e •() "5 ao t; § V E 3

CQ

(4 ? 1 C CM .2 3

t^

CN < i NO -H „~ „" 1 rt 4- o ^ fa o O o z H ei! s iJ sT i: £ £ u £

96
° P. "o o g^ VO vO

(D M

6" O -* Si in

s? iri

00 w

>. # in

'S 00

(X o^

rt U U-{ vO ^ CM in m 00 CO ^ :^ 00 ;^

r^ 0- jn

CO o ^ X ' ^ 7* ^ "T" ^

rt ^

rt m (N CTv CO n ^ 1

i^ vO VO O^ O ^ • ^ ^o M in kO VO cW 1 "^ ^ —

CM i-i s

ii s i g

OO ^ 1 1 o

fc. "o

CM OS CM OO ^ ^ VD ^ OS r^ VO <)• > O r^ o o OS CM vO

tun ^so\ ON CJ\ 00 00 o O o <t

i-i •J2 kO ^ r^ OS O^ ^ o CM 00 OS c (S^

fn O o o o O o

to d <t m <r •* m en CO CO CO ^ a; ^ cr u- u cr cr D" cr cr C cr 6

T3

CB C8 « a re re re re C

rt>.a

rt ^ C " 1' O II

II " C E E B B W

(U m e c

ft ^ ^ rt rt lU oT oT oT

II JL " 4J • (U s e E E re re o -u re re

CO re 4J ^3 « (U (U (U oT

CO CO CO 4-1 CO CO W D « (9 re CO "O T3 •o o

T3 4J 4J u C ,

n) •a o •o •a , 4J 4J 4-1 u 3 m E CM °oj ,_, , , O o o

fc O CM 33 o O

-* = s

'^ g I

£^ ^ >.o s V *-* ^ VO u o 1 o o o o o o o O o U o AJ *J u 4J s

4J

4J u 4J 4J u a< CM pj Oi Oi CLi Eh a, IX eu IX X w 3 -^
PtBr

45

° (X "o ?5 IC o E

4) T3

;2

vO u-i , rt —1 00

t/5 U

u -

rv

'

1

li^ 5 00 00 X

-i Cn] >- OCM iT. X

s. 0-

n) u ^

t ^ 00

00

CO

CM ^ ' 1 £

ri> ,

rt a ^

-H o> >o ^ -i fn 00 00 0^ <f r^ ^ _; ON >r) c —1 r~

c

'

'

'

.2 1 m

rt 2 »o « r^ CO C H 5^ 00 u-v = 5

• CM

U, °'

1 "o

rt ^

> "a .S

CM 00 r^ vo <r 00 00 <C CM <r 00

Of 0\ -1 <N ^ vO ON NTl £ .2? o> a> CO r>~ m in vD r- u-i \n ^ CM c

I. u ^ c^ S i ;j

vc 00 CN vo 00 r^ o\ (2> r~ <o m 'j-i U tN ro J- u-^ vD vo 00 <^ ON CM CM 2 cr cr tr cr o- oOJ OJ <B m IS w

c>

a. 1 c

cW 4)c

to 1

c

V

cm

^^ I-. m

Uh ?"

•a-

, , vO -o V ki i^ M CO s* <J- vO 3 u u ^ vD iJ CM

t« m m m a an Du a, M Ou H

4J 4J U U 4J 4J C-) CM XJ eg u

eu 0. a, fc a, 0- s s 0. a, X a, 98
[Pt(NH3)2Cl2l

CO iH

0^ CO in th " P- . " 

u s

00 in in ^ - O

rt -* d d 1^

«3-

°P? in i o

oo X M •* w

0^

in

o^

n) U §

.-1 in 00 1^ CM CO CM X

r-4 fn d d 00 CO <r

00 CJS o B 1 1 1 T3 ' m ^ >- n) o a u

A! r-^ t^ ON fl

.00 c ' ' ' • 1 1

oo ^ 1 o £g

rt >K '3 £

vD ^ o r^ or vo r- 00 CM DO in E .?f ^ CN -1 OJ CM * CO O s

^1 (U CVJ d VD en s s

in 1^ 1^ 00 0^ Q c (2^

in <t VO w CI •* CM OJ CM CM CO 00 CO CO

XI «

Xi

rt o o cr cr S* °" cr- cr u cr cr o o 6

XI 55 o a OJ o CO CO G O >-l ^ nJ u II II >.

<n B a ^ ^

Xic

0)

II II 4J u II e s ^

CO g E U m aT «r ta t-i (U o ex ^ 1 "O

4J jj c CS CO -o

rt •u C 4J y 3 ^ M to -

<" X a S D

TS 13 m eg ra o o CO CO w 4J •H n C

CO la US] u o CO CO o u

rt >K^ + ni cs o" 3 CM CM 6 m ^ + + '"cm S" o

CM S o^ '^ '^ ""cm «^ CVJ s w O s

in

fc PC v_^ o ^3

"to ^ S eg CM <f <r o u

sf 5 > f

^^ i §

'In 1

'~co '"co

<i H H U 4J u u jj 4J JJ H PM pi

PM ^Ph_ ^ p^ h

PLi £ £l p^
[Pt(NH3) ^Cl 3] r ^ «, 00 <r * 0. "o J vD ro ro E

01

4)

<f in <r U1

•0

to u

(4 s

"~ •^

Ci

00 :^

>- '^ ii '5

00 a 0-

(4 INl U %-i ^ -; vir ^ m 00

I4 g >/^ <r >n 00 to V 00 00 m >f> -» X "o

' ' ' ' c E

n) ;;::; a ^

u d

-O

•* r^ ^

2

u iQ 0\ 00 T ;2

r^ vo -3- ol C t t 1 1 1 1 1 1 U

c

' if3

»o

Ui "^ "o

Jfl ^ ~ f-i <yv vn 00 ^ 00 3- 00 ON

>• fn 00 ro at>r ^ ON S; vO U-l .-H '-; ^ £* g ^ 00 —> ^ ^ S^ ;^ In S CN ri t^ t»1 n

^ 9; J3 cr o* tr tr tr O- (J CT- cr 6

4 <s a <s a « <S (S a

c

nJ •0 T3

>- 0 M a

rt j; •-II II c

C u B 0) B E « E e E Q W a

« m

. c 00 0) T3 «J a (U-O oT lU (3 •^ iJ C 4J 13 « 3 <* •0 « 3 <d « Q <9 m C *J *-• C w _^ u u

3 1

3 01 - to C C

to " " W <n « la « a •0 •0 -c -tH ^ u

c

to

rtnl °cs +

E +

+

h -3- ro i-i ^ >-i -d- -H

Ci^ -H t— £

CM ^/-5

*"<»• ^^ <f ^ 4J g c- rl a- ro en ro CO "^ 1

£ II i§ i Z, >

£

i^ S i"" £ £ pu bJ £ ^ a H i_j ^ l_ I-i •-^ '—

Ol.
45

i~- o -^ o^

o

VD p; !o o o ^

, (« , M o

:S

I (M 00 W

>. .JS

•in00 m M O <*4 r- o o in vo m vo <JN CO

rt <f VD «j r^ «* VD 00 a\ o\ r^ i~- CO CM CM iH VX o

' 1

m ^

^ 1

<7> <f -* 00 i^ >*

j<i <? a^ CO r-! 00 0(3 ?:l ?? J^ 2

CO CM

r-l r-< W III 1 ' 1 c

5 2

OO W

s o

^

^

'V. « <t St CM CM <N s

o m o O r-l ^

^ *; .-1 r^ r^ <!• CM 00 VD

:3 .c ^ ^ ^ o VO vo o o o\ o

s.? CM

i> O o o o 00 00 00 ^^" VD ^ a^ c^ <r) CM CO O- <t m

1

s O o o o o D* tr C tr cr u D" D" tr O D*

rt d 0) cS CD nj cd ni cd m

X) W

TJ •o c • u nJ 13 to 13 n ^

iJ 4J

<u to r-t -"T-l r-l (X •V 4J

"(3 •: II o II II s s

II •: " §

" 11 ^ c o B ra g e ca to p 8^S^ B

c 01' • (D •>«-< ^ U u a, ^S'HS i^ ."^ S

"^ s ^S-HS <u 4J C •a (S 3 n) nl •o II n II C8 •o m 3 cs t8

nl C -U JJ jj u 4-) S CO '^ m n S •> S to 3 CO ^ to a

J3 0) § . s . . s . s

3 1

en CM 01 c8 "O (S n) •o CD CD "O OT o r^ n-; -rl M •H )^ ^ •rl M 4J u O CO O 4J n O JJ CO CJ 4J CO "? X rH .-.

c: PI O •*

It ^ S CO O r— +_^ +_^ ^ t g S e

CM © o* +

o £ O ,12. CM © CM r-l CVI +

£

i-. w cj K

^ £ o '^ S

s r— S r-n "^ 2

O —• O 1-1 o o ^ > ;:i > h> <) n O- CO o o CO ^ CM ^^ 3

^

''^ CO CO CO 'In CO fO Q^Qo

E IEEE 1 § E e" 1 EE

It s ^ ^ s ^ £l £i s ^ S

4-> 4J P4 S H

,"

101
[Pt(NH3)4]SO^-Ag2PtBr^

45 u «^

E D

<v c

•o 5

to

rt c u

X,a

cd u ^

*:F Ci

00 X

>• h '5

00 a CT-

<t <VJ U IM o^ CO r- ^ r^ ^ ^

4> a vO d -<

;^ ^

<sl -* I "o

' ' c £

n) ^

> ^

rt (7> m ^

O

u

J«! § S' s

c

"-*

co X

R) B •o X

£ §

1 O

(x

611 3 ^

E .5?

-* -I vD Zl

•3- O ^ V ki 41 S 2 oo CO c iS^

in ov ON

00 m <N CM ^ 3 ^ K ^ m ST ^ cp cr cr O" tr (T "

T3 w

eg 0) a m <a a cd C

i« E • ^ «i a • w

4> « 1 c

^ u u

at 00

00

•

'^ s'^ SI f1

O II c « •> U m <u •O H 00 « •o u CO V •n aT

ID o o. u C 4J C "

13 C n T3 00 B •o a :? a •V C8 3 0)

tn n) 4J C 4J u C iJ 1

". - C s

3 0) c . c 3 o en « dT-o -o 0) -o CO T3

rt CO •H kl •H U ki -u k( 4-1 W n

CO O U o CO u a o m

<H C o <« 3

"5 +_ r-. 3 ^ £ 0-* o o

""cmCN (Q W 1 k'^ X

CZ

z

en

•z. u<

p-i
CO o VO

g —

<

o t-~. S

o

O

G

VO ^ CO oo'

•o o

o- to

6"

n) o- S s

1

in I

OO C\ ^

s

Ui ^ in •^ in00

nJ «* O M-l

f~-. CO ^ o o o

a •* VX

' ' a a m ^

o in o^ s ^ r- i-l ^

»4 ^ o 0\ iri in r-i 00 oo" d <> 00 oo" o^ m ^ iri in r^ VD 1^ CO CO in «* CO cM ' ' ' ' c

00

)4 Q

oo5 o

o 00 e^ o

M

fe g ^

>

Ml

01 o o a^ m ^ CM ^ C^ CM 11

CM CM CM vo r^ oo' §

'I d"I O li 4) CM .* o tyi in ^ M

no > " CM CM CO ^ CM * CM <f in ^ v

rt y oo M O 60 60 ^ 6B y y cr cr o u o W 10 C

«i >.a

H

M C

c O

Ui y

« 'Cu

1

wm

\o £ S-

>* ^ CO CO

_« + CO CO *C0 CM CO cn VC CM

Vj +^ O O O fe ^

o go CO ^«^ ?

H M M M H M H M I-l I-l

1
Os

47 s

u" E

^- Dg

"O §

BO ,

"^ 00 o <t -1 CN vo C M u r- vo

•^ i d -* X

-* <f O ^

!f u^ s o

00 « • • > ON

inoo

(4 vO <r o V o OO <N cvj od oj «N c>i oo" o V

-I I 1 1 1 1 rH -I i-i X "o ' ' ' •o

rtc ^

>- rt ^ aou ^ ^ O O^ r-I iX

"? . •* <^l d d

O^ CTs 00 a> C t-i cn r^ Wc

rt S CO itf

It-I o o o

u."o m o ^ o __, en > "a ^ '^ CM CM eg CM eg

IH E .? d 00 <t ^ CM co" ox on U1 1^" " " " CM 2 a ^ o tc or. ti Zl M a cr O" w to « <0 <0 c

nl

'-' '-' >. II ^ II a e 1, E

(4 ^ X c 4) 4) c

(0

n) w C

n) ay «

II 73 e C

iS 3

0) 2 m

Vi XIc

g" ^

10 g g 4, B C8 2

10 o CO

i-l 4-1 •H o 3 « S

•g c 2 ? u >. 9 3 3 an r^•* 1

•*

(4 + t, + d* +d* CO d^

<5 § z § § s 8 3 <s 5 O

:c^ i
^ ^

CO

a. o o

E

00

:o

, * 00 in

to U

u S S

•^ in

0^

00 Ui

'^. •|! irv

It 00 a o

<a O Vl H ^

VX

n) ^

>^ rt ? 1

J^

in ON ON

>4 in" d o^ c

•^ ^ ^ ^

ii

OOs

Ui

Itf ON VO -H CO

61) "3 X 3

in o

ON to :^

00 ^^ CO <N CO cs ^ (U 6

•a s O M o o OO "

c

K

>.a

"3X C

cU u

C

.2

u•S1

sE ^ ^ Ex

-3- ^ CO <J- ^ u u w^ 5 5 8 5

105
u

Q

1

6

0^

ctJ dood i-H

en

in ". o 5

co

T3

in CM in ^ ^ 00 <n ^

M) , rt vo CM t-~ -* vD <^ r^

, <t •^ o -* C V. o r^ oo St ^ VD cvj vt -' '-' <!• en in

"b

' U

•=? s s

CM oo

i-i 5 s

>• ^ ^ ^ •-4 .- —

.

00 a r ;3i <t 00

i4 o vo U • O • ^ vo ^ vo CJ^ d vo §

in O o

m 1 '-' <-< C-J ^~

"o 1 T3

rtC ^

^ vO 1^ Ov > rt Ol O o <t a 1

J^ o

r~ d CM CM ^ CTv •* d (A vo 0^ ^

u vo jdj o in <yv CM CM en

vo 1 1 cW

c

D M cn

CO ^. o

rt g

oo ?^ o

•": °°.

. 00 £ 1

o

oo S

vo o^

Ul ^

"

"o

nl o

00 <t s in <i- "S" o

vO CM > "3 X en en <« m

Of o\ C7V "i °i

00 eyv <JV •^ d 00 r^ 00 in' vo c

09 ^^" in 00 ^ IQ CM

.n in

Cl, X o M ^ ll o S£ 00 cr CO Ul o cr* o o 60 00 d E CO T3 u5 eO C

rt:*a

rt ^ c

cU o J

Ul ca

O

.a3

CO

a

u

.-1

IIB

•- •O B 6 « 4J oT M c

4J CD 0} 4J

cd •« u •H 4J a. <a ra 3

rt o

rt "s •o S

S £

4J p

Ih a ax ?-. 01 en 3 5 1.° 1

3

*i

4: i o o"- O^ O^ CM en 1

It H i 1 S ;! S 1 1 ^ _l 1
VO ^ ^

CT> o <J- e

ai

1-4 00 m

13

in ^

<fl o CO w O o * CM c4 CO o\

•^ h ^ 00 s

>- 00 ^ co- c- CO I

oo" ON O o> co ^ '^. u M vo r^ r~. vD m ^ ^

o> -* r^ csi 00 o

n) •-4 1 1-4 VX "o

n)c ^ a

rt CO VD CO <f O vo r^ « f~; <^ <^ 1^ -; o o VO <!; eg VD O .-) CM ^ o in CO CM O r-I .-^ CM CM CM ^ o i-i ' O rH VD

t-i CO CO CO CO CO Wc ' ' ' ' 1 T" 1 1 I w • M <)•

rt §

OO

U-l o o

CO ? o 3

(2 i 1

"o

<i <f r-~ ~^I] <j- 00 o o

in CN o S <! 3 ^ <t- ^o oo CO ON ^ E .?

ON o> CO °°.

01 m CO OJ o in

Si

J2

^^" '~~ 00 s

t-- ON

ni 60 cr

a. cr M C O tr bO a" o M D- cr 2* 5* 2* 2* 2*

CO E (D ni cs tfl C8 oi m CD (8 ca W 5 c

rt>aaX C cw Vuc1

II eII e 6 3 D ^ <u ^ o ^ o o o o o o

-D

(U 4J (U w"-

0) pT „- ^C ^C ^CM ^.N c 0) 0)

(4 4J 4J o o & CO o CO o0) "3 o

"d 0) a o ^ g ra y.

4J

to G 4-1 CO c

00

(I. ' CO V g1 1 1 § + CM ^ t. ^"' 3H 1 1 1 III 1 s s
• a o u E

^o , rt vD t-i in O

-* - r-~ 3

•p? in

00 ^ >. 0^

Ln ^ p: n oo' a an! VD vT CN en CM •* o t- r~- vO in d 00 St ^ ^ r-l ^ ^ 3 3

11 1 1 1 1 1 1 X

"o anc ^ I .

"ifl ". ^. 00 o en ^_ o c^ in -- in ^_ -^ ?; % ^ 00 cr. oj d 00 d in ;^* d o ^o oo O vO

r-l -< cc w

ra S '° ?^ OO r. ^ o d in 5 b §

rt ^

en <f o o o vt •* 00 ^ m r- r-- 1^ CM vO si- 00 > "9 2 o a> 3 «

o- o *

r^

00 0\ CM ^• 1^- d

r-. 00 <f00 1^ ^^" <)• Ov ^ 00 00 o ^ o

'"' rH -H '^ CM 04 en <!

J3 Oy ^ rO cr cr cr o o o o- M o cr o o M D- o o o o W

ca td c

rt>.a

n) II C c e U O a <0 c

rt (d

II II J3 V

<o e e E 3 a o o -o ^ ^ ^

04 CM il <u <u (U •V S S CO •u jj c <d cS « o 8 •- m 0}

jfl o o

"5 in o o •o C m «

en m

00 ? o o O

«d- b. 3 O O »r* O o

w'^ X

rf ?

s-^sT CM •*

cv CM CM CO O

r-4 i-l iH Lj ;j M ^ o o o (^ n (5 M H M H 5 1 1 j_ 1 ;g 1 J_ 1 1 1 1 i 1 1
MnSO,

<f CM 0^ o

o 0, 6

T3

i-I ^'

, n) r~- OO

O

s

vO

?p ITI

'oo W

>- OtM in K

rt 00 a o Ol

rt 00 in O ^ eg" 00

n) ^ 1 c^ CM VX

T3

n! ^

rt ^ o oocMoococTioj-inr- <f vo o CO 00 r-~ >• 1

CM

*

1-1 1-1 in o 1-4 en <i- S oo o 1-4 M <f in vo t~- ^ ^ <? o r-^oooooooooooocJ^ <Ti <Ti <Ti <T> CTi 0^

in VDVCVOVOVDVOOVD vD vO VO vO VO O

CM CM <N CM <N (N c 1 1 1 1 1 1 1 1 1 1 W

c w

rt §

oo ^

1

o

3

"o O VD > O (TV 6r o 0^o

CW

J3 p2^

00 S a

^ rt o o D* U-U'U-U'O'O'U'O' cr< D- D* cr a" O" 6

B rt ctfrtnjnicSctfnjnJ n) tfl ca ta n) es W (8 c

rt>-0- 13^ c

c .2 w o. 1

^

rt ^' o. II oooooooo o o o o o o

ffl •a" g s" «^ Pf* «" ffl"' «" w" w" oooooooo W^ K- s- s"" «"' «"

S (Nc^inooooo

"S

tS 4J o o o o o o

c

iJ

cS r-T cm" co" in" cs" o" o" cT

p< .-1 CM in o

n) •Ho

a <u (U -o 3 ^1 u

60 a< a

•i-i oo* fc

ii d* ^

n) ^ _i
MnSO^

48

00 o 0^ ^ CM <* u ° p. o E

00 r^ d rH

C3? Q a/

'

c

00

T)

r-- ,^ r- vf c 00 ^

X

o O >

•^

> s tn

rj 00 a ovo r- CO U o

u-i vD r;

rt ^ « CM o

I

(fl c ^ en > "ifl --1 t^ O tN r- CN CO O in Csl OO \n a 1

i^ O vO CTi CM O^ O CD CM OO ^ r-~ n-4 r- vo CM CSI C7^ O- en in

cn ro S 5 r- r-. 1 c 1

c« u 'O ^

£ § ^ o t. 2i

"o

i 1

rt ^

0^ o en o ^ vl- s ^

-* 00 ^ vc r- ^ 00 00 r- 1^ > "3 X ;h .o r- O CJN in <» n 1^ o -d- u o O O -< O r-i 00 u-1 o^ r- 13 00 c

CM <t r^ CM cn s n o ^

(°^ ^ CS] S CM CM -I en -* "^ X

J3 § ^

o o o u o o CJ O " O <J " " §*

c

j^ ^

a

n) ^ c

E

CU V ;J OJ T31

i2 3

a

c

O="1

3

0)

II B

Cfl 8 S

4J "S n! OJ u

o c CO 3

(S o m s

00 <)• 3

iri

"5 a ca o O

i 1 ta 03 » p o

o o o

-< cs X

<N K

CM X

CM u:"

eg f (4 w ^ tn r- I JS d* •* d* d* d* O^

CM a <u vo z'^ Z^ i

1

^^ 1 1 ill 1 s llV £ HO
• eu "o o 6

TJ • rt w u

?p in

00 ^ >> oS iTl

.ti X

(Tj 00 a

n) u tj

nt ^

<U

1 I "o

1

1 T3

rt ^

rt ono\n,-tooc.jooinvovDO^.-ivooo O 1^ o 1

cnCT>u-ivo oo<^oooo<tooo^OO© 0^ C-J cjcOin^r^OOO>dor4rHr^C^C^cj cJ vO t-^ -d--*-*<f-cl--d--*"-iinjnininini£jirj vo in 'T''T'V'T''VV'T''i'i iT'i'Vi I 1 W

CO t^

r* ^ o

g

or

00s

V ti <u i:^ ^^ 00

a, J <u U D". ^ crcrO'CT'D'cro'CT'D'D'D'D'Cr'tT'D' 5* O -rl 6

a w rtoJrtrtrtrtrtrtnJrtrtrtojnJrt rt § '^ c

Rt>-a

n) ^ C

CU

C

rt a

(D u OOOOOOOOOOOOOOO O

a

^r liT m"' w"- pT «" pT w"* w"' sT w"^ pf ffi"- pT hT bT ^ c.-cvi<f.nvoooo;n^og§|go o %

60

rt "a vo £ •H o

•*

00 f b *CM

X) f

0^

rt H 1 1
':?

3 X. ^ ^ CM ^ -a-

§ g 5

rc fUPH cope < cnK W rt J^ T112
-* o

G

4) 3 ^

, rt iri i-i

u

O vO in 00 <r CM

•pP ai

00 U:

>- o\

LTl

Oo' a an) INI CM o CM ^

U ^ i i

VO* i

^

ctI ON

rt CT) CO

a) 1 I

T3

n! ^

G. 1

rto

r^ -•-; o\ 00

eg O <f o o d r^ r^ iH vD 5 ;S'

CM <f VO

CO ^ vD

CO u <-i in <f o\ m sf o 00 a^ t^ 00 in CU

c

<N CM CM e^ T t t t 7

CM C>4 CO CM CM in

' ' •2S

OO o

5

^ J-. <f cn vD o> 00 in n 00 moo r^ CO > '3 X. »* 00 o r^ 00 s s s

bT

. o> 0^ ON o a^ o

<d- 00 r^ O CT^ <f r-4 CO CO > ri ;3 ;:; S S ^ ^ ^ S lU ::;

XI 4) X) ts o O " §• O O D" O 60 %

O XT " S* " ^

"

73 W

C

nJ t-l >- II a

6 n

X d (iT c ti u p. S -^

II Rt *n m

y

•o E e

J3 I

XI o

rt s"5

rt

rt '&. o

to

eo to O

J2"5 3

CO •H •o o 3

00 E a 3 O O 1 €: CM •*

*CM

00 CM CMCM

(l, WW <N O

CM CO /-s t-l /-T* ^^^o"- ^ •^•<fd*© >°"' ^^^ ^ d""^ d^ d^ <N o m W <M <M .^ o"^ 1

-1 rrir i

B S S

III 1
s 3

E

es

en o ^

. n in O

O

O i-i ?i

1

ir. «

> in

.T) CO a

(T! rg U ^

00 o "^ •^ ^

VO o

<« >-) ON ON

1 1 CM m CO X O

1 1 ' •o £

rt ^

>a %

r- r- -3- OO CO 00 in en in

'^. en

r^ t^ ON 00 o o

cW

c

>-• »-< 1 1 .-1 en en ~* w

rt g OO X

£ a ?^ O

<i;

"o ^ j^ ^ in ^ o "^ in S 3

CM ^

u-l o CTS OS 3 X CM 3

o m CO CM <»• £ .SP 00 ON ON o o o "i "". CM h V r~ ox .-1 CD en r-4 in in <f en c ^^ in OO CM vO r- en o ri o

CO

r-l ,-< CM CM CM "^ F-t '^ r^ CM "^ <N -I on

rl o o o O CT* cr a- c cr cr o

o.

CJ o v W

03 ctj (0 0) CO 1

<o c

nJ •-* > II a

rt g

j: c

•« c _0 2 U u

C O

m

c

II e

s

(0 u

ra

CO A *.*„

IIB

^^ i

•H ^z r ? o i e « g g

O CO en g

m 3 bT •"^ pf' m

GO o —"^ o o o ^ fc K'^g g

S O CM en o

•*

VO

CM pfu opT o

:ir'

<J- /-T•d- ^<t 3 fff 1

+^ 1 r a o

CO 1

O

;g _t 1 1 1 1 i l" £

c
6

o*^ Q bl

J" T3

rt c CO y x<D

(4 U ^ 1

in

00 ^

in

oo' a a- O IM 00

'S ^ i X

XI

n)c ^

>• IS ^ ^ en c ~~'

.2 g

nJ H t? ^ ^ o 5 h f

"o

rt ^

vo rH >

Oi OCO e:§'

VD 00

<u M <u O W ^^ CO S X V a s o o o w c

n!>a

rt ^ c cU

lU 0) <J ft 73

tl 1 53 1

w5 "?

rt 3 ^

J!3

o" 3

ffl 00 vo * Ui ^ 13 _<!• o c O «

ja <u

<0 p[4 M2 3 1 i
Tc-HTcO

49 —

^ 6

o

<! Q ai c

T3

rt "^ c w o <r X O ^

1 is

<r

5^ 1

o a 1

O t-i o

rt ^ X o

•? 6

>. rt! a i^ ^ O rJ -< ^ r-' on 71 VO f^ vO xo ri;

r-l CO c

1 1 R 11

oo O O

S

"o -sn) VOo o

^

3 X

£.2f o 00 °'. s

U V c^ o

<0 ^^ "

X t. ^ O M oo " O r. w

c

n)>a

rt ^ c

CU <u ^

0) a o c "*

XI3 1

VW c

n! su

o

3

flj 3

j9

CQ 3

n! <]• C

ii cT (S^ 1

XI + o ^ ^ ^ B g
On

00 ^ ON CM 1^ CM u^ E

vo" -* 7 S'CO

1

c ^ ^ 00 '-* i-i in 00 "-I 2° e 00 in in 00" o\ 00 ^ OtJ c <f in -* o- vj- U ^

'3? tn g

00 1 1 -* W

rH* r4 1--" ^ 1

\r,

n) 00* a an! O

1

CM o- 00 VO °i

rt fO 00 CM 00 vD -j r-! vO VO

0) X

00 VO in CO VO

__

•-' i-l CM CM r-l

rtc ^

rt

. 5 •* -* * >- r-< vD CM <J- ^ ^ ,M r^

O.o y ^ <h t-~ ^ <f 00 vo n CM OV 00 00 00 00 0!3 ^ ^ 3 ^

•-I S 500 CJN VO 00 in s00 00 00 00 c

rH CM CM

T* T* 1 1 1 1

a

00 ?^ 00 in 00

2: § s s

CO

fa

Pi

r-l P-I evj

rt ^

> <n r-l V

cU

00

CM CM <N 2 S

fl

<N CM ^ CJ

ii ^ rt 00 M o" D* cr 00 00 O" o" cr cr cr

T3

5) <0 CO CO CO a CO CO W

c

n!>.a

rt j: c

c

CO U u

c

n!

0) | 1: II II II •V u5

g g e E 0^

(fl ^ ^ ^ ^ nT* ffi K w

c

<u 0)

CO Q) s 0000 D s 3 il 4-1 u 0000 W T5 (0 a. "3 c

n! <u 'O -a CM CO in 3

(4

(4 u ^J 4J c

'a6

en 03 CU CO CO •H V

U ^

3n s [fa rt 1

PS ii

•1 "t^ t^ '-•* d*

rt + 1 cT CM s Z ^ ^ J__!. 5 5 ^ S .. g
00o

C (1. CM O E

OJ ^ vO

( n) 0^ o in O

<M vD

1 2

i<: <f

>. 0^

ir> ." 0^

00

Ifl O t- CM ^

• ^ lO

-4- ;3 3

I O

1 T3n

C ^ ^

> J

rt 12 M o CO a ij j<: 00 oo m CT> v£> CM r-^ CM o o^ vo ri r^ ^ o

T^. 00 00 vD 00 r- 00 CO U1 ^ VD <r o

1 ,-t c

c

rt t?? o

Z

u. g v_ pi JS „ > "3 X vo r^ CO 00 <}• CO in 3

vo

CTV

c

in <t CT^ ^ O

CO r~ O

CM00 o vo

VOvO

o^ r- CO cM r^ VD m ov CO

CM n n oo CO -* ^

CM CM in CO in J

^ cr to o O 60 o o 6

CO Q m

C

nl^a

«) X c

cu

c

OS3 C

X

c

O O O 8 §

c

II BfOJ i

m' £ o

1 si- _<J- « O

<f CO in vo rH O CO U 5

^i^ 3 o 5 "co^ U « CM W C/3 « CO <J- CO CM < S ^ «- ^ <§ .J_l. S ^

.
AgReO, * o< "o o

6/ T)^ ^

CO U

;i i 1 S

00 X ^ # in

00* 0- CTni U ^ o\

rt ^ lO ^ X

lO lO t 1 •o

n)>- g

"rt a %

ji; s

vO

"? c 1 c

rt S OO W

'" s s °

l2 1

tJT E .5? 3 o V M S CO 00 cWm &

fe ^ s CO ^^ rt o o 5a W c

<fl ;>, Q.

nJ ^ c CU c3

0uoc

01 E o

CM M PS o CM m (h 3 f d* S

119
Cr

51

u^ u o °i H

in -* Q

4> co

•o

OO CO

60c

"(3 vo

on o

in ^

!c •* a o

•=? k o s

-*

>• 00 ^ o

.^ ii G

s.

00*

n! INI O ^

-^

15 ^ o 5 Ic E

<n ]^

rt ON r~- NO r^ CO

SI?1

j^ 00 C-) en C7N CM ^ ^ NO 00 o ^ C-4 J^' <f O in CnI CO r4

CO m On 00 r- ON

CO O CM- CM CM CNJ CnJ c

ON <t <J- ON -*<!•<}•«*

NO 1 CO O- i-H CM ON r-l r^ r-4 r-l r-l W .-1 <N <! NO ON ' ' 1 1 1 1 o

rt 2 s o o <r o o in CO <t <f o CO* -*

CTN in CO ^ M 1^ ^ « in l2 g

NO

r-< CJ <t vo ON

(4 <f 00 CM >

Of <f <f

"s £ CTN s ON ON E .?f On V I- o r~- CO ON c

00 £^ in NO ON

ja

rt XI o yj to to a- CO M CO M 60 CO O CO O 00 D* O- O* C

T3 W

CO 03 td (0 (9 Cm^a

rt X C cU 4) ft U a 0uC c1 s

iS o o o o W •w x^ aT* x^ x^ c ra "o rt CM CO ,» in 3Vu

rt "O

"s 00 5 ^ £ 3 Ih CQ m k,

Rlc

_0 ii

rt 3 + A * 4f A i ^ o a'^ o" Z P ^u p p^w K p p u u u o o o o o o o o o o o
HCrO,

00 o

CO °p. o^ EV

OO ^

o (t» o <t o M o

cJ ON CM i

U

1

in

00 Ui

>~ ON

00 o t-l

(SI VO o OO

rt a

CO eg pjl CM

r-^ in 00

4) X

6

I V 7

r^

ca ^

1

<f CM CO O 00 00 o

•^ ON .H CM ^ in ^ r~- '°. i; . . CM 00 CJN u eg CO en CO CO CO CO <3 CM C3 i-I c:n vo vo CO ON cW

O- <f -* >3- <f -* <)• r-t 1^ vo ^ CM CM CO 5

.-1 m vo O ,-1 ,-1 ^ ^ ^ ^

1 1 1 1 1 1 1 "?

1 I V

o

H g

OO o

fe §

1 a 00 vo ON VO 3 X

CO o m o VO r^ m r^ 1-1 CO 00 00 o

f_, s .^ ON ON o o o CJN ON ON o

S J.

4) lA r^ O CO VD in CJN in r^ £^ .-1 in r^ 00 o -) r-l vo w r^ ,-( M .H CO '-'

JD S ^ s

D* D* c tr C D* c D" CJ O O y o- o y cr" w

C8 (S CS n) CS CD c3 Ctf ni nj c

n)>.a

rt ^ c

cW o a-

«-• •-• iH c II II n) iH u

y g a n ^ <u o o o o o o

g°CN

"« •N S

c

(fl

<u <u W sT* Si Si X X X a: % % rt vD 00 O u^ m O o 4-1 4J

r-( -1 CM in 00 01 ra m

m TS •a •o "s c 4J 4J ^ ^ to 10 m s

£ m fo =.:- °c. w

W CM CO

4) CM CO CO C" 1^ <!• <f 3 o- O O O o O O^ W O^

(6 o Cr CM CM CN CSI CO H !^ M U H H ^T" U U u o O o o o o o o o o w
- ^

CT\ OO CT\ m vO

I OO lii

E 2r

ooooooooo

e

B '&n S * w ^ IP <t vC 5^5^ i'i' £

u u M o o O
1 C r-l <f

00 o o\

o. o s

r^ o D

TD

to O n u-l CM o

CO

00

00

•^ in

CO s s ^.

00 ^ >. o CO •* *

nl 00

Q. o

<i rvj o U-l . "i

CM -"1 ON ^ O VO eg ON

nj VD 00 t-l CM X

"o 1 1 1 1 1 £

rt ;^

>- ,

nJ 1 ^

CM r^ in 1^ eg M °i -* o m VD

r-^ 00 * CO «* o -* r-! 00 ^ CO CM rH 00 00

r~ <y\ •-< «* 0\ CO .-1 CO O CO CO O CO CM c CM CM r- o^ CO CO Wc

.2 I 1 ' ' I 1 1 1 1 1 1CM CO VO 00

rt OO ^

CM CT\ ov VO 1 O ;s s( 2* r^ 1 1 1 h 2

"o o rt ^

CM v« £S ^ r^ 1 2oo~

1-1 » CO CM CM CM 00 <!• >• 3 X Oi 00 00 <=> O CO m o O § Cw

a. o> o -[ "i

ON

00

en (»\ CO

00

00CO00 a. O CM in c\ -* in

i-l rH CM O" ^ ^ 1-1 1-1 i-< 1-H CM iH

•2 O O D* a" o ao w o o o o 60 00 •S* BO

rt « c8 t« 1-1 a w

rd>a

rt c c _0 w 1)C

a.y

'J Oc

(T) c

CO 11

si 5

^"1 o o o

U^ CM CM sa^ i-f CM ^CS e £

*CM *cg CO >* 1-1 O

CO <! I

c^ J3 a ^ H S

•g "2 il <g ? •2 H o o " o " o O
lCr(H^O)^Cir

(X "c o

"Jo~

c

00

5" t? LO

00 ^ >,

CTx in

.•;:; e^

r) oc a c^

rg O ^

rt ^

D

::: "o c ^

>- p n

a iJ X '^. o <r CM 00 ^. . VO r- VO St 00

1- <] -* in t-J CO CN r-4 r^ * so r- CM r-- sf r^ VO CM O 1

3^ ON r-l St •* m t t ? ? t

CO VO CM 00 ON r-^ 1-4 00 00 1-1 m in cW

c ^

in ? 7

in in 7 t

m m

1 1

rt "^ ^

£ B o

2 ^1 r-^ :;? ^ :S 5

o

"I"

TT" o St -d; o o

t-~ si- 00 m C3- in m

>. <N vo 00 -1 o 3

^0

r-~ 00 or p M

(-. in (7» CTx <»• ri ^ oC O

in

oo

sl- 00

00 VO 00 rCO CO00 00 S

" ON a. CM CO VD CO si- VO 00 VO CTv C7V [J > '"' n CM St CM CO CO CO ^ " D* cr D* O" O o- cr O 60 cr cr o o

rt ca rt cd a rt rt (S « cd o tJ} 5>a

rt c W V

c s

no a ^

2" c d <U (U C c C r-l 4) c V 4) (U (U S u

i-M 3 (U "o o (U 0) O

r^ S •H -H ^ M > > a a, a I > ^ 'J w S+ C^

o O

n

o

u

1 + CMCM i-l O o o "t, s

M

in E M

6 r-f K .4

^-^ O O o

O nrH '~cs ""cm <M U

CJ u u u to lO o o o O m m M r-. t. in <! si- m SI- <t «:t St <f St VO S" S' s: 6" 6" 6" S" o o o o S" S" « £ e'e'e'e' £ £ € € ^

CM

CO ^e ^£ 1 3 p ^4 vi vi ^ ^ s U u u P u 1 rj o o o o o o o o o o. H H o o

H

o
[Cr(H20)^]2(^°4^'^"2°

in

D. "o U IS <N

T)

e n)

C/3 O

u

00

>- ^

?:

'rt oc a o

n rsl U U-l rt ^ X

"o •o

! t

• ^-.

>, ^

rt a

o s

J^

in r-l O <n in m I-- in in o .-1 CO r^ r^ -* O 0^ O O 0^ a^ C^I c:^ CO in CM CM I-? O

c

en <N VD -* a^ o r~ r~ o .-1 vo O " « ra ctI W

c

1 M n 2 ;3 S

1 1 1 I 1 • III

.2

u H

, o

1 <h <f vo CJV CM vo

R) s

o\ ^ 00 vo f-J O O r-l t^ in vo <T. ^ •?„ CO

'~i "*, CO -* -* -*

Ih £ -^ c^ a\ 00 <N O CO vo vo eg 00 5 vO 00 Ov

VO VO VO VD

0) o n <f CO a^ r-J O CO o > en -* M CO CO t^ m in in in vo a O M c o cr o o o o D* o CT- D- a" o o o o

n) n> (tf nj IS ts a w

.^a.

rtc .2 g

U <D g! 4J C .£" 0) o S

j^ 5 li O ^ "J w a o o o o o

CM CM CM CM CM

-o w _-*y-v P3 !fi W W

9 ^^ CM CO ^ in

rt ^Pl'^r- "cmE ^" *co *co *co *C0 3 O * ^-^

^-N<! —<!• 'lit O X^C?*^^ o o o o 2 E W o o O O CO CO CO CO CO OO CO CO CO CO v-'

r-l

1-, vo vc

^-' O CM CM CM CM CM

in CO *co •Cv .Cv '^ '~vo'~vo'~vO ""vD o o o o ^-, ^^ -* CM CM CM CM O S" S" 6" 6~

<u S^a^

s §

£ 5

CM CM a £ sCM CM ^' d'&d'd'

3 H^ h' M U h ^4 h !-l I-l !-l M " .s <s 5 5 5

o o O O O O O O O
vO

u-i o en

o. u E o .* o

-0 X K + *' +

vO ON !o U

OO Oo -I VO \

s? in

CM

ON

00 ^

00 u: • >.

VD <y. 2

nl oo a o

rt M O U tw

00 ov Ov ^

00 O r-4 ? o OJ CN >-

"c ^ —

0. 1

00 .n VO O ^^ .n 00 in <f

CTi o r^ 0\ CO CO o O O CJv 0\ ov

en V* r~ r- CM CM CM rH .-1 .-1 c5 _^ 1 1 csl <N CM CM t t t ^ ^ ^ ^ ^

rt oo ^ - 5 ?; o s ^ i n

r- 00 o 00 o > -3 X S .2? ^. ". * i

Oi \ S o § o ^ VD \n VO o in c^ CM

00 o CO in U

<!• NO O ^ -a- CM S rt

'J " " o u o

s- " S" S" O % s* % X % % % W 5>X ^

t5 c1

•H i-H

II n

1-1a o o o o o o

«r aT O aT Cv 3 D

4J 4J 3C X X X X X w (0 m ae n) -o

4J 4-1 4J o o 00 in ;c 8 § 8 8 o -^ CM CO .*

rt CO

rt •O T3 •o

4J 4J c U C a a H n £ o

CM w ru-l O

<^ -* VO b CM O

JJ S S g 2 Es a -> ^ 3

s- i fi" _|^ s" €t

126
??

c^ -* -*

lo a> en

ON CTN ON o\ r^ vo <jt-l i-l t-l i-l r-l t-4 00 •*-*>*•* <f sf m

CO •* a.

CM CM CM CM CM

..f

i ss r

W CO CO r^ CM h h h M l-i u u u o u

127
o <r

CM r^ n o^ o

o. o E

°^* d 2 ^* ^' ^

•V ~^ e r! lo o oo eJ^ OT o

^'

vo m 5 o

!=? ^^

00 ^ >. .|; in o

oc a art rvl o a\ U • ON <)• o esi ^ u in en r-! ^ in <J o u-i en o V 1 1 X "o ' •o

rtc ^ a 1 u

.a: -* -* in r~. ^ 00 S -<

r-^ O in en o <t (N r-I ot in ^ CD in m ,* -1 CN <n ^ CN <f vc CM r- ^ ?

CS CN CM r-l n 1 1 1 7 1 1 1 s

oo

04 ^ ^ n H 5 o <n ^ g

rt _^ ^ VO

CT^ <N 00 o- 00 <! 00 -* S Sen NO > 00 vD r^ fO 00 o m <i) D/ o O .-1 O OJ r-~ t-~ CTx 00 i s s 1 i i

en CM lo CM r^ CM S' S 1

CM w m O r-( m en

t; — rt O M o o o o o o o o o a- to o W

rt>a

•^ c U c

a.u

'Jc o

r-l

II e

CT\ g

«"•

CO i " o

vO si" <a- _•* 1

<o <f CM CM o o o

S" «M -H ^ u u u •H ^ CO w U 'cm *CM o o 3 u"

XI v-' CO M n ir> U M H e fi e

<; O ^u

ti u u H o o o o pTi* o S
00 m vo

r-- ON ON o^ a

4>

in <r d

r-

"O

vo OO

rt 00 ^ o

CO ^ tn ^ 00 •* '"' O CN •^ iTl 00 -1

00 W

>. ? oin 1

00

rt O tu > -* 5 s

rt ^ O yD r^ ON o ^ CN X ^

T* X)

nJ ^ ^ 1

13 CO in m OO CN ?^

NO § in r« O r^" <nI ^o oi in r-J oo' 00 O ^ O CO 00 CO CN

(^ ^ Si (Jv CO O <t c

-I n CN 00 W "^ a

Ih oS

OO3 o O vD d c<i o ON

ON ON r- 00

in <N ON 00 ON vO VO 00 <o 00

00 U< ^

nl CN ON ON 3 .C CO CO CO B .?P S^

ON <JN ON

lU U 4) CO C > CN <f

to

o\ I-l I-l

fi^ at o 00 00 60 00 60 60 60 60 60 60 o 00 o 60 cr 1 W « C

n)>~a

nl X C cw o 1 rt u

-S <u 3 DcE

I-l <N

iJs^ + s ^ i + + ^ i o o*^ O^ 1 i i 1 _£_j_ "l 1 1 1 1 s

129
MoO,

OO CN4 °o. "o u^ 00 u E

1) O 00

T3

NO U-N , 15

u~i O «-; CO U

vD CM CO

•^ 1/-N o <j- CM r^

00 X O >n

>. OC.4 \r\ u

rt 00 a a-

. ^

0^

00 00 O 00 ^ OS

0^ m to X

•V 1c

n ^

> a u-i On

a.c ^

X

O U-, v£> o oo ON CM

00 00 o^ -< -< oo <n O oi o >n 00 <M

in fn n r~ u-i ^ oo <!• <N

-( tN -. CM <r >£) r~ CM rl ro ro

.1 §

' ' ' '

'

CO 00

:^ s •o Ui

CO o

r- O U

^ o S ^

i

*

' ' "o

rt >

0. II1-. 4) s ?; ;s :q c;^ s;; ^ i

ON

o>

oi

ON ON oo oo r^ vc o\

o^ u^ r<l -H lo ON ^ c U°^

NO r^ o

U r- !^ CM J' !o i^ X a- X o- cr o- 60 00 00 00 o ao o- o tA 00

n! « o a «J

-a W

S>

a.n~ c II c

c a

u

3 1

to

0) 1

•o

t;c m » =^

n) 3

E

^^

[IH O

?!

CM <^ ^ ^

X^

•* "*

CM ^ ^ "^ ^ O o

X) r ff 1 1 1

f
CO " p. "o "

4>

00 ^

n)

5" o 1

in

00 ^ >• in I

00

<« o ti H ^

i) X

it ^ t %

<to

•* in 00 o -* ^ -* •* o sf 00 ^ o> o ^ r-! eg >* o VO C^ ^ i-i O m CO CM NO O vo u ^ ^ ON 2 2

r~~ in ON ^ in X) s s c ' ' T' ' r* T* T* 'i' T* ' • t-l rH U2 1 1 1

OO S

Ui

«! ^ vO ^ <N m in o <-* 00 VD ^ 3 X "* ON O -d- r^ in U E

.^^ 00 CM '^ 00 00 i^ r^ V h 4) vo 00 ^" CO in C > ^ o cn ON 00

'"' OJ CM CM CM CM CM •*

XI <u XI

rt o o O Ml O 00 o OO cr o o o (J O o- w

CO s

>.

ex

nl ^ c CW 0)o

XI uV

XIc

ItIt '5EK n O

fc

CM V

i-H ^ m * o <N

•J* n 3 "cm U 1 1 1 1

PC
Mol

Ov o ro ^

ON ^_

o. in r^ ON cnI 00 o E

4)

'^ m <t OJ o

CT> 05 U

u * ^*

;q en

•=? ^ 00

in •*

00 ^

eg o»

>. ON

ir\ .^ ^ -

rt oc a o

It IM U • o oo >£> -*.

rt 8 i s 3

en

CM ^ ' "? E

n) o

Q. 1

<N m ^ '^ '^ o J- ^ CM vo r-! ON CN d <r 00 oo CO 00 in ^ -i o^ m in 00 1 ^ m l-l tN CM VO C

'

'

'

' ^ 'V

1 1 1 ^' '

' U

§ ?

~ i oo o

m

00

OS 00 r-4 1^ -^ ,-. r-i CN vO 00 00 .-1 -J >

rt ^ vO r^ 00 in ON o rH o in CM m ON

"3 .£ O O 00 ON CO o r-1 ON ON >* r^ VO E .?? O^ O 00 m r-~ m vt CNj in CO <3 ;^ NO CM u u ^ o O O S in .-1 NO vO NO o o

C ^°^ o 2 S .-< ri in U

S

00 W

n!>a

nJ x; c

c 1 U

oC

a

c

E

i

;*S

y^ n -*

CNJ CM oT" Z o 8 •rJ CO CO 5 m

PQ CM 1 1 i" s S i^ 1 ££ l" CU g ^
MnMoO. — ^

CO °o. s o H

CO <3^ • H i-H rH w 6 u in o-

?p h

oo id

>^ sP h

00

li rg O • 00

(i §

00 CO S VX ' ' '

nJ ^

>s rt cTi a.o a .K u^* 00 I-! cn' <f

c^g 00 in 00

CM t-< c 1 1 1 1 1 1 ° 5

nt cd «o w e g ^1 bH 1 O 3 ^ ^

00 CO m r~- vO * -w

I-. r-~ 00 r~ 3 X <f vo 00

en in in -J <t m

CM m CM

J2% S

nl

<-> ^ u 6

X) t^ c

n)^a

rt

,-1 ,c C II cw o a.u

<a3

2. ^° CO

-*

~d- d* * 5

<)• 3 1 bO i "oT ^ H " < b p^ ^
'

ro O ON tn ^ 00 O <f vO ° (X ' * ^ o E

Of

1)

'~* •"^

•o Ov 1 o <r 00 <* , "rt 00 in o

oo O " 5 2

00 1 1 ^ "1 <t § S

00 i<C ^* ^ (N <N > 0<N iT X o

a) X ' 1 a CT- i 1^ § ° ^

tN 00

"^ o V E ^ ^ <r in > ^s

(fl O VO Ov vl- in NO a O CO 00 00 O r-j in vo --1 .-H c^ r- 00 ON O ON in 1 k. s s o -* -( 00 ON O r^ ^

r-- vo -J

rg <t 2)

r^ CNj ON c 1 1 1 > I 1 1 ' 1 •-I U o o vO o

•o ^

r-. 00 r^ O <si ^ ON o ^ O O 00 o S

U, R

n) Ov CTV -J 00 00 5 ^. 3

r-^ d -<

00 vo in CO

o^

in >

Of •3 X

£.5?

u-1 oo

CO 3 3

ON in 3 s s ^,

CO in r^ sd 5. u «; 00 (^ -. <f so ON <vj -d- -* u t^^

CN CS CVJ O- NO ON -*

60 O 00 u o o oe o- 00 60 00 O 60 cr 5 « w

rt>a ,_i c e U c3 ww

(?

T3CE Sni

f-. y^ ^ <T> 00

fc O O 00 o m S 3^ in

•C- C- CNJ CO ^

<r CM

U3 00 o '~m ^cn ^m o o

<t O O O 3 >o

:. +^ g § S S g" X e o e X g
WOCl

1 LO

" ^ "o 00 o

4) T)

CTv i , rt

•-1 <f

6" g S

1

1

^

in

1

>- 0<N L^ X

oc a CTn) S ^

O

S

a> o

1

rt 00 a\ 1 ^

"o

t: £ ^ ^ 1

(Tl r~ in ^O 00 O 00 <N r~

1 ?- ^ t-I rH* .H Cvj CO OO C5 <f CM o r-~ -* r-I d

vD .-1 r^ -I O <!• CM 00 vo VO <f

: c t t

rH ,-1 7

r-l r-(

c _

11

eo1 O o

c 5

U, EH "c

nJ o VO C-J in 00 o in r-< >

-* in vD VD in "3 "S ,S 00 I-. vo <-* t^ i^ vO

>^ I-! I^" s

^ VD CN vO .-1 %

^ (U 00 <! £^ <N CO CO 3 s S OB O O 00 O 00 O 00 00 O 00 O 60 w

c>a

nJ X

g

cU

C

OS a.uP

C b

CVl" o

Jn

tx. o <N

*; 1-4 <f 2 CM <f in VD o

vO o CM o Rj g O O o O O o H S S S: :s s s S
3

E

00 V

to U

3

1 i

00 :.s

a-i 3:

rt oc a a0! fSl u IMU

nJ

_!; ^

"o c ^

> 1

rt i in in en

ON

r-I 00 ^

CO r-. 2 CN ON

c"- z

1

00 it: d K

§ t t

k s

m 3

CM 00 t-- 00 00 3 ;£ 0^ vO 00 CM en .-<

S;

vo <r CTv 00 r-- m ON

ON XO .-I

CNJ 00 r- --1 ^ -* NO

u^ ^ (N S "^ro CO m <!• CO 3 rt 00 to 00 00 u o W

nj>a

rt j: C

cW

C

T3C

"3

en

ti- in

CM VO « u <t <f 0"^

<f -*

VD ta u S 3 3 eg pa 0, 3 CN 3 :s

PQ PQ M CM w C C H s 3 U 3 3 3 3 3 3 CO C/5 CU M
' " 0^ ^ rH r-4 f^

r-P" 0> 0\ r4 r-- r~. CJN u E

r^ CM

'V

, n in

U

u S "

•^

!^ 00 ^

>- cS ^

3:

rt 00 a o^ u

10 §

r^ s

•^

T3c ^

>a I

<N vo °i

vo' ON in

ON <f 00 ,-j VO on o>

VO <N <f r- 1 r-~ 00 in

CVJ <f 1 eg CM <f en c

1 1

'

' ' 1 1 ' —

oz

^

rt S

.0 ^

u ^ 1 °

p h ^ ^ n) 00 00 00 00 .-) ON in r-J VO

00 .H 00 oi in in 00 <N ON ^ vo 00

fo -a- vo in vD r~- vo r-. rt. £ .S' .-1 t-~ (ri CO vo vo ^ s [;^ ON <N

1^ a -I <f vo .-H vo ON c ^^ CO cJl <f <t n en CO ;5 CO en ^

^ rt " S 0000 000 " " w

C

rt>a

rt II c e W

C a

c

si

°cM

en

. u. d^ W

en <f ^

«d- <f «* <f ^ o- <t 3, •* 3 ^ g S g ^ g g 3 <N -* 3 m 3 r-~ s 3 M v-( -H 0) <J s la (S iS (S py ^

Errata for Te chnical Note 270-3

Page 22 HF(liq) AH^°gg = -71.65 kcal/mol

Page 32 HBr(g) AH^ = -6.826 kcal/mol

Page 43 s(g) AGf = 56.951 kcal/mol

S° = 40.084 cal/deg mol

Page 48 H2S+(g^ AHfQ = 237.0 kcal/mol

Page 56 Se(g) H° - H° = 1.4815 kcal/mol

S° = 42.21 cal/deg/mol

Cp° = 4.978 cal/deg/mol

Page 61 N(g) AG£° = 108.886 kcal/mol

S° = 36.613 cal/deg mol

Page 86 H2PO4" (aq) AGf ° = -270.17 kcal/mol

Page 231 Tlzl 5603)3 instead of Te (8603)3

TlzSe formula weight = 487.70

Page 234 ZnFzCc) AGf° = -170.5 kcal/mol

139
INDEX OF CONTENTS

Chemical

Symbol

Ag

AlAr

As

AtAuB

BiBrC

Cd

CICo

Cr

CuF

Fe

Ga

GeH

He

HgIIn

IrKr

MnN

Ne

NiO

OsP

Pb

Pd

Po

PtRe

Element

Silver

Aluminunn

Argon

Arsenic

Astatine

Gold

Boron

Bismut h

Bromine

Carbon

Cadmium

Chlorine

Cobalt

Chromium

Copper

Fluorine

Iron Gallium

Germanium

Hydrogen

Helium

Mercury

Iodine

Indium

Iridium

Krypton

Manganese

Nitrogen

Neon

Nickel

Oxygen

Osmium

Phosphorus

Lead

Palladiiim

Polonium

Platinum

Rhenium

Table VolumeNumber Page Number

37 4- 29

29 3-207 5 3- 17 20 3- 95

13 3- 42

38 4- 39

28 3-196

ZZ 3-103

11 3- 31 23 3-106

34 3-248

10 3- 24 40 4- 54

51 4-120

36 4- 13 9 3- 21

41 4- 74 30 3-218

25 3-177 2 3- 12 3 3- 15 35 4- 1 12 3- 36

31 3-223

46 4-103 6 3- 18 48 4-106

18 3- 61 4 3- 16 39 4- 43 1 3- 11 47 4-104

19 3- 84

27 3-187

42 4- 90

17 3- 60

45 4- 96 50 4-117

140
Chemical

Symbol

Rh

Rn

Ru

SSbSe

SiSnTc

Te

TlW

Xe

Zn

Element Table Volume - Number Page Number

Rhodium 43 4- 93 Radon 8 3- 20 Ruthenium 44 4- 94

Sulfur 14 3- 43 Antimony 21 3- 99 Selenium 15 3- 56

Silicon 24 3-171

Tin 26 3-181

Technetium 49 4-116

Telluriunn 16 3- 58 Thallium 32 3-227

Tungsten 53 4-134

Xenon 7 3- 19 Zinc 33 3-233

Compounds are located in the Table for the element (in the compound)

having the highest Table number.

U.S. GOVERNMENT PRINTING OFFICE : 1 969 —3**! -026/1 Tit

141

Announcement of New Technical Notes on

Selected Values of Chemical Thermiodynamic Properties

Superintendent of Documents

Government Printing Office

Washington, D, C. 20402

Dear Sir

Please add my name to the announcement list of new

publications to be issued in the series: NBS Technical Note 270 - Selected Values of Chemical Thermodynamic

Properties.

Name

Company

Address

City State Zip Code

(Notification key 341)



NBS TECHNICAL PUBLICATIONS

PERIODICALS NONPERIODICALS JOURNAL OF RESEARCH reports National Bureau of Standards research and development in physics, mathematics, chemistry, and engineering. Comprehensive scientific papers give complete details of the work, including laboratory data, experimental

procedures, and theoretical and mathematical analyses. Illustrated with photographs, drawings, and

charts. Published in three sections, available separately: • Physics and Chemistry

Papers of interest primarily to scientists working in these fields. This section covers a broad range of physical and chemical research, with major emphasis on standards of physical measurement, fundamental

constants, and properties of matter. Issued six times

a year. Annual subscription: Domestic, $6.00; for- eign, $7.25*. • Mathematical Sciences

Studies and compilations designed mainly for the mathematician and theoretical physicist. Topics in mathematical statistics, theory of experiment design, numerical analysis, theoretical physics and chemistry, logical design and programming of computers and computer systems. Short numerical tables. Issued quarterly. Annual subscription: Domestic,

$2.25; foreign, $2.75*. • Engineering and Instrumentation

Reporting results of interest chiefly to the engineer and the applied scientist. This section includes many

of the new developments in instrumentation resulting from the Bureau's work in physical measurement,

data processing, and development of test methods.

It will also cover some of the work in acoustics, applied mechanics, building research, and cryogenic

engineering. Issued quarterly. Annual subscription: Domestic, $2.75; foreign, $3.50*. TECHNICAL NEWS BULLETIN

The best single source of information concerning

the Bureau's research, developmental, cooperative and publication activities, this monthly publication

is designed for the industry-oriented individual whose

daily work involves intimate contact with science and technology

for engineers, chemists, physicists, research managers, product-development managers, and company executives. Annual subscription: Domestic,

$3.00; foreign, $4.00*.

Applied Mathematics Series. Mathematical

tables, manuals, and studies. Building Science Series. Research results, test methods, and performance criteria of building materials, components, systems, and structures. Handbooks. Recommended codes of engineering and industrial practice (including safety codes) de- veloped in cooperation with interested industries, professional organizations, and regulatory bodies. Special Publications. Proceedings of NBS conferences, bibliographies, annual reports, wall charts, pamphlets, etc. Monographs. Major contributions to the technical literature on various subjects related to the Bureau's scientific and technical activities. National Standard Reference Data Series. NSRDS provides quantitative data on the physical and chemical properties of materials, compiled from

the world's literature and critically evaluated. Product Standards. Provide requirements for

sizes, types, quality and methods for testing various

industrial products. These standards are developed

cooperatively with interested Government and in- dustry groups and provide the basis for common

understanding of product characteristics for both

buyers and sellers. Their use is voluntary. Technical Notes. This series consists of communications and reports (covering both other agency and NBS-sponsored work) of Umited or transitory

interest. Federal Information Processing Standards

Publications. This series is the official publication within the Federal Government for information on

standards adopted and promulgated under the Public Law 89-306, and Bureau of the Budget Circular A-86 entitled, Standardization of Data Elements and Codes in Data Systems.

CLEARINGHOUSE The Clearinghouse for Federal Scientific and

Technical Information, operated by NBS, supplies

unclassified information related to Governmentgenerated science and technology in defense, space, atomic energy, and other national programs. For

further information on Clearinghouse services, write: Clearinghouse

U.S. Department of Commerce

Springfield, Virginia 22151

•Difference in price is due to extra cost'of foreign mailing. Order NBS publications from: Superintendent of Documents

Government Printing Office Washington, D.C. 20402
U.S. DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20230 POSTAGE AND FEES PAID

U.S. DEPARTMENT OF COMMERCE OFFICIAL BUSINESS