# Polyvinyl Chloride and Copolymers (PVC) Production

**GACT Analysis**

**February 7, 2012**

**Worksheet Name** 

# GACT Existing Source Summary GACT New Source Summary All EP Record Keeping and Rep. B. PVC-Only PV Smmry B. PV-PVC Only-Limits B. PV-PVCO Redux B. PVCO Condenser Cost B. PV-PVCO Testing Costs C. PVC-Com PV Smmry C. PV-PVCC Limits PV-PVCComb-Baseline Ems C. THAP Emission Rate for OVDP C. PV-PVCC Testing Costs D. Resins - Summary D. Suspension-VC-Existing D. Suspension-HAP Existing D. Dispersion-VC GACT D. Dispersion-HAP GACT D. Resins - Testing Costs D. CTLC Resin Emission Est. E. WW Summary E. WW - Limits E. WW - Opt 2 Base&Redux (Ex) E. WW - Opt 2 Base&Redux (New) E. WW Steam Stripper Cost E. WW Hard pipe Costing E. WW Testing Cost F.HEX - Baseline, Costs, Reduxs G. EQLeaks Summary G. EQLeaks Emissions G. EQLeaks SubpartV Cost G. EQLeaks P Option 1 G. EQLeaks V Option 1 G. EQLeaks C Option 1 H. OES Summary H. OES - Reactor Openings H. OES - Gas Holders

# J. Storage - Baseline

# Polyvinyl Chloride and Copolymers (PVC) Production

**Description**

Control option summary for existing area sources Control option summary for new area sources Recordkeeping and reporting costs from Burden Estimates for area sources Process Vents: PVC-Only summary

for area sources Process Vents: PVC-Only limit calculations for VC, CDD/CDF, TOHAP, and THC Process Vents: PVC-Only reductions for existing PVC-only area source meeting major source requirements Process Vents: PVC-Only cost of condenser for existing PVC-only area source meeting major source requirements Process Vents: PVC-Only major testing costs for area sources Process Vents: PVC-Combined summary for area sources Process Vents: PVC-Combined limit calculations for VC, CDD/CDF, TOHAP, and THC Process Vents: PVC-Combined emissions Process Vents: PVC-Combined - TOHAP emission rate calculation for existing area sources Process Vents: PVC-Combined major testing costs for area sources 

# Resins: Summary of limits and costs for existing area sources Resins: Vinyl chloride limit calculations for suspension resin at existing area sources Resins: Total non-VC organic HAP limit calculations for suspension resin at existing area sources Resins: Vinyl chloride limit calculations for dispersion resin at existing area sources Resins: Total non-VC organic HAP limit calculations for dispersion resin at existing area sources Resins: Cost of major source testing requirements at existing area sources Resins: Emission estimates for CTLC from stripped resins Wastewater: Summary of wastewater limits and costs for existing area sources Wastewater: Limits calculations Wastewater: Costs and emission reductions of existing area sources complying with new major source requirements Wastewater: Costs and emission reductions of new area sources complying with new major source requirements Wastewater: Costs of new wastewater steam stripper Wastewater: Costs of hard piping to control previously uncontrolled streams Wastewater: Costs of major source testing requirements at existing area sources Heat exchanger analysis for area sources Equipment Leaks: Summary of analysis for area sources Equipment leaks: Estimate of emissions from equipment leaks at existing area sources Equipment leaks: Estimate of subpart V cost for existing area sources Equipment Leaks: Estimate of Subpart UU cost for pumps at existing area sources Equipment Leaks: Estimate of Subpart UU cost for valves at existing area sources Equipment Leaks: Estimate of Subpart UU cost for connectors at existing area sources Other Emission Sources: Summary of analysis for existing area sources Other Emission Sources: Summary of reactor opening emissions from existing area sources Other Emission Sources: Summary of gas holder analysis for existing area sources

# Storage Vessels: Estimate of emissions from storage vessels at existing area sources

# Wastewater: Costs and emission reductions of existing area sources complying with new major source requirements

# Existing Source GACT Analysis Summary

**VC D/F (g/yr)**  **Total HAP**

**Baseline**(Current Performance) 0.058 1.20E-04 1.07
**Option 1**(Existing Major Source Testing and Monitoring) 48,161[3] 10,890[4]

- - - - **Option 2 [5]** 

### (Existing Major Source Emission Limits) 350,711 180,245 0.0140[6] 2.87E-05 0.2568275 701,814

**Baseline**(Current Performance) 0.279 7.64E-03 4.61
**Option 1**(Existing Major Source Testing and Monitoring) 48,161[3] 10,890[4]

- - - - **Option 2 [5]** 

### (Existing Major Source Emission Limits) 48,161[3] 10,890[4]

- - - -
**Baseline**(Current Performance) 0.903

- 13.148
**Option 1 [7]** 

### (Major Source Testing and Monitoring) 7,429 19,777

- - - - **Option 2 [7]** 

### (Existing Major Source Concentration Limits and Work Practices) 7,429 19,777

- - - - **Option 3 [8** 

### (New Major Source Concentration Limits and Work Practices ) 12,370,537 2,996,390 8.55E-03

- 12.20 245,516

**Baseline**(Current Level of Control - Subpart F/V) 19.99100
**Option 1 [10]** 

### (Existing Major Source Requirements) 359,970 72,525

- - 9.29 7,807

**Baseline**(LDAR - 5000 ppb and monthly monitoring) 17.80

- 17.80 **Option 1**(LDAR - Major Source 50 ppb and quarterly monitoring ) 7,425 25,529 15.10

- 15.10 1,691

**Baseline**(Current Level of Control - Subpart F) 0.23

- 0.23
**Option 1**(Existing Major Source Requirements and Work Practices) 2,204 3,108

- - - -
**Baseline**(Current Level of Control - No Control) 0.34

- 0.49
**Option 1**(Existing Major Source Requirements) 2,204 3,108

- - - 2,000-12,000[12] **Heat Exchangers [11]** 



### Other Emission **Sources**

**Storage Vessels Process Vents (PVC**  **Only)**

**Process Vents (PVC Combined)** 

**Wastewater**

**Equipment Leaks [9]**  

### Emission Point **Control Option [1]**  

### Total Initial Cost ($) **Total Annual Cost ($/yr)**  **Baseline Emission and Reductions [2]**  

### (Tons/yr) **Cost Effectiveness ($/ton, Total HAP basis)** 

# Existing Source GACT Summary - Stripped Resins

**VC Total HAP** **[3]**



### Baseline(Current Performance) 0.93850 6.51
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 0.23809 3.57
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 1.17 1.32
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - - **Baseline**(Current Performance) 0.03428 0.17475
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 0.79125 2.75 **Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - - [1] – For dispersion, suspension blending, and copolymer resins, baseline for existing area sources was determined to be the level of control of the least controlled major source in the applicable stripped resin subcategory. Option 1 is equivalent to baseline with the addition of major source testing and monitoring requirements. Option 2 consists of the existing major concentration limits in each resin subcategory.
[2] – Emission reductions are presented for Option 2 where applicable. Emissions reductions are not applicable to Option 1 as there are no emission reductions associated with testing and monitoring only. [3] – Total HAP baseline and reductions include vinyl chloride. **Copolymer Bulk** 

**Suspension**

**Dispersion**

**Suspension Blending Cost Effectiveness ($/ton,**  **Total HAP basis) Resin Type**  **Control Option [1]**  

### Total Initial **Cost ($) Total Annual** 

**Cost ($/yr) Baseline Emission and** 

**Reductions [2]**  

### (tons/yr)

# New Source GACT Analysis Summary

**VC D/F (g/yr)**  **Total HAP**

**Baseline**(Current Performance CertainTeed - Lake Charles) 0.058 1.20E-04 1.07
**Option 1**(Existing Major Source Testing and Monitoring) 48,161[3] 10,890[4]

- - - - **Option 2 [5]** 

### (Existing Major Source Emission Limits) 350,711 180,245 0.0140[6] 2.87E-05 0.26 701,814

**Baseline**(Current Performance OxyVinyls - Deer Park) 0.279 7.64E-03 4.61
**Option 1**(Existing Major Source Testing and Monitoring) 48,161[3] 10,890[4]

- - - - **Option 2 [5]** 

### (Existing Major Source Emission Limits) 48,161[3] 10,890[4]

- - - -
**Baseline**(Current Performance - OxyVinyls - Deer Park) 0.634

- 9.443
**Option 1 [7]** 

### (Major Source Testing and Monitoring) 3,715 9,888

- - - **Option 2 [7]** 

### (Existing Major Source Concentration Limits and Work Practices) 3,715 9,888

- - - - **Option 3 [8** 

### (New Major Source Concentration Limits and Work Practices ) 8,054,327 1,988,368 1.31E-01

- 8.91 223,169

**Baseline**(Current Level of Control - Subpart F/V - OxyVinyls Deer Park) 10
**Option 1 [10]** 

### (Existing Major Source Requirements) 179,985 36,263

- - 4.64 7,807

**Baseline**(LDAR - 5000 ppb and monthly monitoring - OxyVinyls - Deer Park) 1.25E+01

- 12.48 **Option 1**(LDAR - Major Source 50 ppb and quarterly monitoring )

- 8,600 1.14E+01

- 1.14E+01 752

**Baseline**(Current Level of Control - Subpart F - OxyVinyls Deer Park) 1.08

- 1.08
**Option 1**(Existing Major Source Requirements and Work Practices) 6,102 3,032 0.616

- 0.616 4,922

**Baseline**(Current Level of Control - No Control - OxyVinyls - Deer Park) 0.336

- 0.492
**Option 1**(Existing Major Source Requirements) 1,102 1,554

- - - 2,000-12,000[12] **Heat Exchangers [11]** 



### Other Emission **Sources**

**Storage Vessels Process Vents (PVC**  **Only)**

**Process Vents (PVC Combined)** 

**Wastewater**

**Equipment Leaks [9]**  

### Emission Point **Control Option [1]**  

### Total Initial Cost ($) **Total Annual Cost ($/yr)**  **Baseline Emission and Reductions [2]**  

### (Tons/yr) **Cost Effectiveness ($/ton, Total HAP basis)** 

# New Source GACT Summary - Stripped Resins

**VC Total HAP** **[3]**



### Baseline(Current Performance) 0.94 6.51
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 0.24 3.57
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 1.17 1.32
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - - **Baseline**(Current Performance) 0.03 0.17
**Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - -
**Baseline**(Current Performance) 0.79 2.75 **Option 1 [4]** 

### (Major Source Testing and Monitoring) 4,319 10,615

- - - **Option 2 [4]** 

### (Existing Source Concentration Limits) 4,319 10,615

- - - [1] – For dispersion, suspension blending, and copolymer resins, baseline for existing area sources was determined to be the level of control of the least controlled major source in the applicable stripped resin subcategory. Option 1 is equivalent to baseline with the addition of major source testing and monitoring requirements. Option 2 consists of the existing major concentration limits in each resin subcategory.
[2] – Emission reductions are presented for Option 2 where applicable. Emissions reductions are not applicable to Option 1 as there are no emission reductions associated with testing and monitoring only. [3] – Total HAP baseline and reductions include vinyl chloride. **Copolymer Bulk** 

**Suspension**

**Dispersion**

**Suspension Blending Cost Effectiveness ($/ton,**  **Total HAP basis) Resin Type**  **Control Option [1]**  

### Total Initial **Cost ($) Total Annual** 

**Cost ($/yr) Baseline Emission and** 

**Reductions [2]**  

### (tons/yr)

# ATTACHMENT I: RECORDKEEPING AND REPORTING COST ESTIMATION FOR AREA SOURCES

02/09/12

Yr 1 Yr 2 Yr 3 Resins $2,639a,b,d $2,393 $6,806.13 $6,806.13e,f,g
Process Vents $9,927a,b,c,d $0 $4,500.12 $4,500.12e,f,g
Wastewater $3,074a,b,d $2,393 $7,023.67 $7,023.67e,f,g Equipment Leaks $2,639a,b,d $2,611 $8,981.60 $8,981.60e,f,g,h Storage Vessels $2,204a,d $0 $3,107.82 $3,107.82e,f,g Heat Exchange Systems $2,204a,b,d $5,221 $8,328.96 $8,328.96e,f,g Other Sources $2,204a,d $0 $3,107.82 $3,107.82e,f,g **Total $24,892**  **$12,617.75 $41,856.12**  **$41,856.12**

a Labor/Non Labor Costs to "Read/Understand Rule Requirements" divided by 7 emission points b Initial Performance Test/Sampling/Report

c Establishment of operating parameters and monitoring plan d Report preparation for item 3.E.1-6 divided by 7 emission points

e Periodic sampling/testing/and monitoring (not applicable for process vents in year 1) f Years 2 and 3 include items 3.E.5 and 3.E.6 divided by 7 emission points

g In year 2 and 3, recordkeeping items under 4.D are included h includes annual labor cost for PRD monitoring system Record Keeping and Reporting Burden By Emission Point

Emission Point Initial Cost ($) Initial Notes Annual Cost ($/yr) Annual Notes

h includes annual labor cost for PRD monitoring system

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012



# GACT Analysis Process Vents Summary
**PVC ONLY**
**Calculated GACT Limits for Process Vents - PVC Only**

**Calculated Limits Area Source Current Level of**  **Performance (CTLC Averages)**  **Existing Source - Current Level of Control Calculted Limits**  **(CTLC w/ Variability) New Source Current Level of**  **Performance New Source**  **(Least Controlled MACT Source w/ Variability)**  **Vinyl Chloride (ppmv)** 5.24E+00 5.30E+00 5.24E+00 5.30E+00 **Dioxins/Furans (TEQ - ng/dscm)** 3.11E-02 1.30E-01 3.11E-02 1.30E-01 **Total Organic HAP (ppmv)**  7.37E+01 1.40E+02 7.37E+01 1.40E+02 **THC (ppmvd as propane)** 1.66E+01 4.53E+01 1.66E+01 4.53E+01



## Existing Source GACT Summary for Process Vents - PVC Only

**Pollutant Area Source Current Level of**  **Performance (CTLC Averages)**  **Option 1 Limit (Major Source Requirement)**  **Baseline Emissions - Based on CTLC Average Concentration (TPY)**  **Emission Reductions as a Result of Complying w/ Major Source** 

**Reqs (TPY)** Vinyl Chloride (ppmv) 5.24E+00 6.00E+00 5.84E-02 1.40E-02 Dioxins/Furans (TEQ - ng/dscm) 3.11E-02 3.80E-02 1.32E-10 3.17E-11
Total Organic HAP(ppm

v) 7.37E+01 5.60E+01 1.07E+00 2.57E-01



## New Source GACT Summary for Process Vents - PVC Only

**Pollutant New Area Source Current**  **Level of Performance (Model new Source Avg.**  **Concentrations) Option 1 Limit**  **(Existing Source MACT) Baseline Emissions - Based on CTLC**  **Average Concentration (TPY) Emission Reductions as a Result**  **of Complying w/ Major Source**

**Reqs (TPY)**
Vinyl Chloride (ppmv) 5.24E+00 6.00E+00 5.84E-02 1.40E-02 Dioxins/Furans (TEQ - ng/dscm) 3.11E-02 3.80E-02 1.32E-10 3.17E-11
Total Organic HAP(ppm

v) 7.37E+01 5.60E+01 1.07E+00 2.57E-01



## Existing and New Source GACT Costs for Compliance with Major Source Requirements**1**

## - PVC Only

**Compliance with Major Source Requirements Cost Summary**



## Initial Costs

Control Equipment Capital Cost 3.03E+05 Process Vent Emissions Testing 4.32E+04 Record Keeping and Reporting 4.96E+03 **Total Initial Costs 3.51E+05**  **Annual Costs** Annualized Capital Cost 2.86E+04 Annual Control Equipment Cost 1.41E+05 Annualized Initial Testing and Monitoring Cost2 

## 0.00E+00 Annual Testing and Monitoring Cost 8.64E+03 Annual Record Keeping and Reporting Cost 2.25E+03 **Total Annual Cost 1.80E+05**  1 - Both existing and new source facilities are based on CTLC, therefore, costs are equivalent.

2 - Annual testing cost = Initial testing cost, therefore, initial testing cost was not amortized.

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC ONLY - New and Existing Limit Calculations

**New and Existing GACT VC Floor (CertainTeed Lake Charles) New and Existing GACT CDD/CDF on a TEQ Basis (CertainTeed Lake Charles)** 

**Facility Run**  **Conc (PPMV @ 3% O2)**  **LN Conc (PPMV @ 3% O2)**  **DL average**

**run value DL for Max** 

**Sorting** 

### Facility **Run TEQ Conc (ng/dscm**  **@ 3% O2)**  **LN(TEQ)**



## CTLC 1 5.23E+00 1.65E+00 0.00E+00 0.00E+00 CTLC 1 5.09E-02 -2.98E+00
CTLC 2 5.25E+00 1.66E+00 0.00E+00 0.00E+00 CTLC 2 2.29E-02 -3.78E+00
CTLC 3 5.24E+00 1.66E+00 0.00E+00 0.00E+00 CTLC 3 1.94E-02 -3.94E+00

**Normal LN**  **Normal LN**  

### Sample Size **3.00E+00 3.00E+00**  **Sample Size 3.00E+00**  **3.00E+00**
**Non-Detects 0.00E+00**  **0.00E+00 Average**  **3.11E-02 -3.56E+00**  **Average 5.24E+00**  **1.66E+00 Median**  **2.29E-02 -3.78E+00** 
**Median 5.24E+00**  **1.66E+00 Standard Deviation**  **1.73E-02 5.15E-01**  **Standard Deviation 1.00E-02**  **1.91E-03 Minimum**  **1.94E-02 -3.94E+00** 
**Minimum 5.23E+00**  **1.65E+00 Maximum**  **5.09E-02 -2.98E+00** 
**Maximum 5.25E+00**  **1.66E+00 Skewness**  **1.65E+00 1.53E+00**  **Skewness 0.00E+00**  **-2.86E-03 SE Skewness**  **1.41E+00 1.41E+00**  **SE Skewness 1.41E+00**  **1.41E+00 Skewness Test**  **Normal Normal**  **Skewness Test Normal**  **Normal Kurtosis**  **Kurtosis SE Kurtosis**  **2.83E+00 2.83E+00**  **SE Kurtosis 2.83E+00**  **2.83E+00 Kurtosis Test**  **Kurtosis Test 99.0%**  **t-statistic for UPL 6.96E+00**  **6.96E+00 99.0%**  **t-statistic for UPL 6.96E+00**  **6.96E+00 99.0%**  **UPL 1.29E-01**  **5.30E-01 99.0%**  **UPL 5.30E+00**  **5.30E+00**
average in variability analysis 3.11E-02

### ng/dscm @ 3% O2
average in variability analysis 5.24E+00

### PPMVD @ 3% O2 RDL 

## 1.25E-02ng/dscm @ 3% O2

RDL 1.84E-01

### PPMVD @ 3% O2 3 x RDL 

## 3.74E-02ng/dscm @ 3% O2

3 x RDL 5.52E-01

### PPMVD @ 3% O2 

### 99.0% **UPL** 1.29E-01ng/dscm @ 3% O2 

### 99.0% **UPL** 5.30E+00PPMVD @ 3% O2 **Area Source w/ Variability 1.30E-01** 

### ng/dscm @ 3% O2 **Area Source w/ Variability 5.30E+00** 

### PPMVD @ 3% O2



## 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC ONLY - New and Existing Limit Calculations

**New and Existing Source GACT Floor for Total Organic HAP (CertainTeed Lake Charles)**

**Facility Run**  **Conc (PPMV @ 3% O2) LN Conc (PPMV @ 3%**  **O2) DL average** 

**run value DL for Max** 

**Sorting** 

## CTLC 1 75.5 4.32 5.33E-09 5.33E-09
CTLC 2 62.2 4.13 3.06E-09 3.06E-09
CTLC 3 83.4 4.42 182 0.00E+00

**Normal LN**  

### Sample Size **3.00E+00 3.00E+00** 
**Non-Detects 3.00E+00**  **3.00E+00 Average**  **7.37E+01 4.29E+00** 
**Median 7.55E+01**  **4.32E+00 Standard Deviation**  **1.07E+01 1.49E-01** 
**Minimum 6.22E+01**  **4.13E+00**
**Maximum 8.34E+01**  **4.42E+00 Skewness**  **-7.36E-01 -9.07E-01**  **SE Skewness 1.41E+00**  **1.41E+00 Skewness Test**  **Normal Normal**  **Kurtosis SE Kurtosis**  **2.83E+00 2.83E+00** 
**Kurtosis Test 99.0%**  **t-statistic for UPL 6.96E+00**  **6.96E+00 99.0%**  **UPL 1.35E+02**  **1.71E+02**

average in variability analysis 7.37E+01

### ppmvd @ 3% O2

RDL 1.84E-01

### ppmvd @ 3% O2

3 x RDL 5.52E-01

### ppmvd @ 3% O2 

### 99.0% **UPL** 1.35E+02ppmvd @ 3% O2 **Area Source w/ Variability 1.40E+02** 

### ppmvd @ 3% O2



## 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC ONLY - New and Existing Limit Calculations

**THC - PVC Only - Existing Area Source**

**Company Facility**  **Compound_Std Method**  **Run Date**  **Value Ln Value** 
CertainTeed Lake Charles THC EPA Method 25A 1 1/26/2010 15.28 2.726544784 CertainTeed Lake Charles THC EPA Method 25A 2 1/26/2010 12.36 2.514465452 CertainTeed Lake Charles THC EPA Method 25A 3 1/26/2010 22.19 3.099641737 Average **16.61**

**Normal LN**  Sample Size 3 3 Compliance Avg 3 3 Average 16.6100 2.7802
Median 15.28 2.727 Standard Deviation 5.05 0.296
Minimum 12.36 2.514
Maximum 22.19 3.100 Skewness 1.10 0.79 SE Skewness 1.41 1.41 Skewness Test Normal Normal Kurtosis * * SE Kurtosis 2.83 2.83
Kurtosis Test * * 99.0% t-statistic for UL 4.54 4.54 99.0% UL 39.53 61.895 99.0% t-statistic for UPL 6.96 6.96 99.0% UPL 45.32 86.912
RDL 0.85PPMVD @ 3% O2 3x RDL 2.535PPMVD @ 3% O2 99.0% UL 39.5PPMVD @ 3% O2 **99.0% UPL**  **45.3 PPMVD @ 3%**  **O2** * Cannot perform Kurtosis test.

**THC Variability Analysis - PVC ONLY (Existing) ppmvd @ 3%**  **O2** ppmvd @ 3% O2 ppmvd @ 3% O2 ppmvd @ 3% O2

**Units**

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012

**Process Vents - PVC ONLY - Costs and Emissions Reductions for New and Existing Area Sources**

**Major Source Requirements (Existing PVC Only MACT Floor)**
VC Area Source 6.00ppmvd @ 3% O2 HCl Area Source ppmvd @ 3% O2 CDD/CDF Area Source 0.038ng/dscm @ 3% O2
TOHAP Area Source 56ppmvd @ 3% O2

**Outlet Max Flow Rate (DSCMM)**  **Average O2 (%)**  **Avg.**

**Temp (C)**  **Vinyl Chloride**

**(ppmvd @ 3%O2) HCl** 

**(ppmvd @ 3%O2) CDD/CDF** 

**(ng/dscm @ 3%O2)**  **TotalHAP**

**(ppmvd @ 3%O2)**  **Inlet Max Flow**

**Rate (DSCMM) Average O2**  **(%) Avg. Temp** 

**(C) Vinyl** 

**Chloride (ppmvd @**  **3%O2) CE Redux** 

**Effy Vinyl** 

**Chloride (lbs/hr)**  **VC**

Baseline (lbs/hr) **HCl**

Baseline (lbs/hr) **CDD/CDF**

Baseline (lbs/hr) **TOHAP**

Baseline (lbs/hr) **VC**Baseline

(Tons/Yr) **HCl**

Baseline (Tons/Yr) **CDD/CDF**

**(TEQ)** Baseline (Tons/Yr) **TOHAP**

Baseline (Tons/Yr) **VC -**%

Redux to
MeetConc.
Limit **HCl**- %

Redux to
Meet Conc.
Limit **CDD/CDF**-

% Redux to
Meet Conc.
Limit **TOHAP -**%

Redux to
Meet Conc.
Limit **VC HCl**  **CDD/CDF TOHAP** 

CertainTeed Lake Charles Area Source 3.43E+01 1.69E+01 5.71E+01 5.24E+00 3.11E-02 7.37E+01 5.65E+00 3.33E-02 6.47E+01 9.59E+04 1.00E+02 2.20E+02 1.39E-02 0.00E+00 3.14E-11 2.55E-01 5.84E-02 0.00E+00 1.32E-10 1.07E+00 2.40E+01 1.40E-02 0.00E+00 3.17E-11 2.57E-01

2.87E-05g/yr (CDD/CDF) **Facility Classification**  **Outlet Conditions Inlet Conditions**  **Reductions (Tons/yr) Baseline Emissions Estimates**  Percent Reductions Needed to Meet Floors

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012

**Total Reductions** 

**Tons/yr**

2.57E-01

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012

**Refrigerated Condenser Package for PVC-Only Process Vents**

**Certain Teed Lake Charles PVC-Only** 
-- Inlet stream flowrate (DSCMM): 

### 5.65E+00 -- Inlet stream flowrate (scfm): (Qin) =DSCMM/35.31 

### 2.00E+02
-- Inlet stream temperature (oC): 

### 6.47E+01 -- Inlet stream temperature (oF): (Tin) =oC*1.8+32 

### 1.48E+02

-- VOC to be condensed: 

### Vinyl chloride
-- VOC inlet volume fraction:(Yvoc,in) =ppm/1E6 

### 9.59E-02 -- Required VOC removal (fraction): (n) 

### 2.40E-01 -- Antoine equation constants for VOC: [4]

A: 

### 6.50E+00

B: 

### 7.83E+02

C: 

### 2.30E+02
-- VOC heat of condensation (BTU/lb-mole): (ΔHvoc,r) 

### 1.01E+04
-- VOC heat capacity (BTU/lb-mole-oF): (Cp,voc) 

### 1.17E+01
-- Coolant specific heat (BTU/lb-oF): Cp,cool 

### 6.50E-01
-- VOC boiling point (oF): (Tboil) 

### 6.53E+00
-- VOC critical temperature (oR): (Tc) 

### 7.73E+02
-- VOC molecular weight (lb/lb-mole): (MWvoc) 

### 6.25E+01
-- VOC condensate density (lb/gal): 

### 8.15E+00
-- Air heat capacity (BTU/lb-mole-oF): (Cp,air) 

### 6.95E+00

DESIGN PARAMETERS: -- Outlet VOC partial pressure (mm Hg): (Pvoc) =760*(Yvoc,in*(1-n)/(1-Yvoc,in*n)) 

### 5.67E+01
-- Condensation temperature, Tc (oF): (Tcon) =(B/(A-log10(Pvoc))-C)*1.8+32 

### -8.48E+01
(oR):=Tcon+460 

### 3.75E+02
-- VOC flowrate in (lb-moles/hr): (Mvoc,in) =Qin*Yvoc,in*60/392 

### 2.93E+00
-- VOC flowrate out (lb-moles/hr): (Mvoc,out) =Mvoc,in*(1-n) 

### 2.23E+00
-- VOC condensed (lb-moles/hr): (Mvoc,con) =Mvoc,in-Mvoc,out 

### 7.03E-01
(lb/hr): (Lb/hrvoc,con) =Mwvoc*Mvoc,con 

### 4.40E+01
-- VOC heat of condensation @ Tc (BTU/lb-mole): (ΔHvoc) =(ΔHvoc,r)*[(1-Tcon/Tc)/(1-Tboil/Tc)]^0.38 

### 1.11E+04
-- Enthalpy change, condensed VOC (BTU/hr): (ΔHcon) =Mvoc,con[ΔHvoc+Cp,voc(Tin-Tcon) 

### 9.74E+03
-- Enthalpy change, uncondensed VOC (BTU/hr):(ΔHuncon) =Mvoc,out*Cp,voc*(Tin-Tcon) 

### 6.05E+03
-- Enthalpy change, air (BTU/hr): (ΔHnoncon) =Cp,air*(Tin-Tcon)*(Qin*60/392-Mvoc,in) 

### 4.48E+04
-- Condenser heat load (BTU/hr): (Hload) =ΔHcon+Δhuncon+ΔHnoncon 

### 6.06E+04
-- Heat transfer coefficient, U (BTU/hr-ft2-oF): Estimate from OAQPS Manual 

### 2.00E+01
-- Log-mean temperature difference (oF): Tlm =(Tin-Tcon-25)/ln((Tin-Tcon-10)/15) 

### 7.71E+01
-- Condenser surface area (ft2): (Acon) =Hload/U*Tlm 

### 3.93E+01
-- Coolant flowrate (lb/hr): =Hload/(Cp,cool*(Tcon-15+25)-(Tcon-15)) 

### 3.73E+03
-- Refrigeration capacity (tons): (R) =Hload/1200 

### 5.05E+00
-- Electricity requirement (kW/ton) [6]: (kW) =-9E-06(Tcon)^3 - 0.0004(Tcon)2 - 0.0331(Tcon) + 3.560 

### 8.97E+00

CAPITAL COSTS Equipment Costs ($):
-- Refrigeration unit/single-stage (< 10 tons): (Rss<10) =exp(9.83-0.014Tcon+0.340lnR) 

### 1.06E+05
-- Refrigeration unit/single-stage (> 10 tons): (Rss>10) =exp(9.26-0.007Tcon+0.627lnR) 

### 0.00E+00
-- Multistage refrigeration unit: (Mru) exp(9.73-0.012Tcon+0.584lnR) 

### 1.20E+05 Total equipment cost ($)--base: (ECp) =1.25*MAX(Rss<10,Rss>10,Mru) 

### 1.50E+05

Cost Index a. 2010 CE Equip (Feb Final) CE Equipment index (Feb 2010 Final) 

### 6.41E+02
b. 1990 CE Equip (Oct Final) CE Equipment index (Oct 1990 Final) 

### 3.94E+02
' ' ' ' --escalated: (ECpe) =(ECp)*(FebFinal/OctFinal) 

### 2.44E+05 Purchased Equipment Cost ($): (PECp) =ECpe*1.08 

### 2.63E+05 Total Capital Investment ($): (TCI) =PECp*1.15 

### 3.03E+05 INPUT PARAMETERS: **Equation**

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012

**Refrigerated Condenser Package for PVC-Only Process Vents**

ANNUAL COST INPUTS: Operating factor (hr/yr): (OF) 

### 8.40E+03 Operating labor rate ($/hr): (LR) 

### 3.46E+01 Maintenance labor rate ($/hr): (MR) 

### 3.81E+01
Operating labor factor (hr/sh): (OLF) 1/2 hour per 8 hour shift 

### 5.00E-01
Maintenance labor factor (hr/sh): (MLF) 1/2 hour per 8 hour shift 

### 5.00E-01 Electricity price ($/kWhr): (EP) 

### 7.00E-02 Recovered VOC value ($/lb)[5]: (Rvoc) 

### 0.00E+00
Annual interest rate (fraction): (Int) 

### 7.00E-02
Control system life (years): (EL) 

### 2.00E+01
Capital recovery factor: (CRF) =Int*(1+Int)^EL/((1+Int)^EL-1) 

### 9.44E-02
Taxes, insurance, admin. factor: (TaxF) 

### 4.00E-02

ANNUAL COSTS:

Item 

### Cost ($/yr)

Operating labor =OF/8*OLF*LR 

### 1.82E+04
Supervisory labor =.15*Operating Labor 

### 2.72E+03

Maintenance labor =OF/8*MLF*MR 

### 2.00E+04

Maintenance materials 100% of maintenance labor 

### 2.00E+04
Electricity =EP*OF*kW*R/0.85 

### 3.13E+04

Overhead =.60*(Operating Labor+Supervisory Labor+Maint Labor+Maint Materials) 

### 3.65E+04
Taxes, insurance, administrative =TaxF*TCI 

### 1.21E+04
Capital recovery =CRF*TCI 

### 2.86E+04

Total Annual Cost (without credits) (TACwoc) =sum of all annual costs 

### 1.69E+05
Recovery credits (RC) =-Rvoc*OF*Lb/hrvoc,con 

### 0.00E+00
Total Annual Cost (with credits) =TACwoc+RC 

### 1.69E+05



## NOTES:

---------- 1. Base equipment costs reflect Third Quart 1990

3. Electricity cost: Energy Information Administration. Average Industrial Retail Price of Electricity: October 2009. 4. Antoine constants listed in OAQPS Manual 5. ICIS, http://www.icis.com/v2/chemicals/9076567/vinyl-chloride/pricing.html, October 20, 2010. (Avg. $690/tonne = $0.313/lb) 6. Polynomial of best fit based on Table 2.5 OAQPS Control Cost Manual Section 3.1 Chapter 2. 2. Operating labor rate: Bureau of Labor Statistics, Occupational Employment Statistics, May 2008 National Industry-Specific Occupational Employment and Wage Estimates

# ATTACHMENT B - PVC ONLY PROCESS VENTS ANALYSIS

02/09/2012

**Process Vents Emission Testing Costs**

**Parameters/Costs Equation**  **Values Testing Freq.** * **Annual Cost of Test Annualized Cost of Initial**  **Test TA** **C of Testing**

A. Parameters
1. CE Plant Cost index a. 2010 (Feb 10 Final CE Index) 539.1 b. 2009 (Annual CE Index) 521.9 c. 1992 (Annual CE Index) 358.2

B. Testing Costs, $
1. Method 1 or 1A Included as part of M 23

- $ 

## 5

- $

-

$

- $ 2. Method 26 (HCl) = $5,000 x (539.1/358.2) 3. Method 23 (CDD/CDF) = $21,000 x (539.1/358.2) - $5,000 $27,000 

## 5 5,400 $ 5,400 $ 4. Method 25A (THC) =$6,000x(539.1/521.9) $6,198 

## 5 1,240 $ 1,240 $ 5. Method 18 (Assumed cost equal to 0031) $10,000 

## 5 2,000 $ 2,000 $

C. CRF (20 yr, 7%): (0.07*(1+0.07)^20)/((1+0.07)^20-1) 0.09439

D. Facility Totals 1.TOH, &VC 

### 3,240 **$**

2. CDD/CDF 

### 5,400 **$ 3. Facility Total**  **$ 43,197.74** 

### 8,640 **$**

* Number of Years Between Tests

Note:

3. E-mail from Jason Dewees, EPA, to Mary Johnson, EPA. August 20, 2008. Re: Monitoring Options for SNCR & Test Cost Questions. 4. Conversation with Ray Merrill, ERG - 11/5/2010.

5. Email from Peter Westlin, EPA 4/8/2011 to ERG: Method 18 Costs 1. Initial testing costs to be annualized over 20 years at 7% interest.

2. Testing costs have been rounded to the nearest $1,000 to be consistent with level of rounding in original costs; costs also adjusted based on additional information from EPA.

Sources:

1. Memorandum from R. Segall, EPA/EMB, to R. Copland, EPA/SDB. October 14, 1992. Medical Waste Incinerator Study: Emission Measurement and Continuous Monitoring. (II-B-89)
2. E-mail from Jason Dewees, EPA, to Peter Westlin, EPA. August 20, 2008. Monitoring Options for SNCR & Test Cost Questions.

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012



# PVC Combined

Calculated GACT Limits for Process Vents - PVC Combined

**Calculated Limits Area Source Current**  **Level of Performance (OVDP Averages)**  **Existing Source - Current Level of**  **Control Calculted Limits (OVDP w/**  **Variability) New Source Current** 

**Level of Performance New Source**  **Current Level of Control**

**Vinyl Chloride (ppmv)** 1.93E-01 5.60E-01 1.93E-01 5.60E-01 **Dioxins/Furans (TEQ - ng/dscm)** 1.53E-02 7.60E-02 1.53E-02 7.60E-02 **Total Organic HAP (ppmv) - Based on WLG since OVDP**  **did not test for TOHAP 2nd round 114)** 4.02E+00 2.90E+01 4.02E+00 2.90E+01

**THC (ppmvd as propane)** 1.10E-01 2.30E+00 1.10E-01 2.30E+00



# Existing Source GACT Summary for Process Vents - PVC Combined

**Pollutant Area Source Current**  **Level of Performance (OVDP Averages)**  **Option 1 Limit (Major Source**  **Requirements) Baseline Emissions -**  **Based on OVDP Average Concentrations**  **(TPY) Emission Reductions as a** 

**Result of Complying w/ Major Source Requirements** 

**(TPY)** Vinyl Chloride (ppmv) 1.93E-01 1.10E+00 2.79E-01

- Dioxins/Furans (TEQ - ng/dscm) 1.53E-02 5.10E-02 8.42E-09

- Total Organic HAP(ppm

v) 4.02E+00 9.80E+00 4.61E+00

-



# New Source GACT Summary for Process Vents - PVC Combined

**Pollutant New Area Source**  **Current Level of Performance (Model new**  **Source Avg. Concentrations)**  **Option 1 Limit (Major Source**  **Requirements) Baseline Emissions -** 

**Based on Model New Source Average**  **Concentrations (TPY) Emission Reductions as a**  **Result of Complying w/ Major Source Requirements** 

**(TPY)** Vinyl Chloride (ppmv) 1.93E-01 1.10E+00 2.79E-01

- Dioxins/Furans (TEQ - ng/dscm) 1.53E-02 5.10E-02 8.42E-09

- Total Organic HAP(ppm

v) 4.02E+00 9.80E+00 4.61E+00

-



# Existing and New Source GACT Costs for Compliance with Major Source Requirements1

# - PVC Combined

**Initial Costs** Control Equipment Capital Cost

- Process Vent Emissions Testing 4.32E+04 Record Keeping and Reporting 4.96E+03 **Total Initial Costs 4.82E+04**  **Annual Costs** Annualized Capital Cost

- Annual Control Equipment Cost

- Annualized Initial Testing and Monitoring Cost2



# - Annual Testing and Monitoring Cost 8.64E+03 Annual Record Keeping and Reporting Cost 2.25E+03 **Total Annual Cost 1.09E+04**  **MACT Floor Cost Summary**



# 1 - Both existing and new source facilities are based on CTLC, therefore, costs are 2 - Annual testing cost = Initial testing cost, therefore, initial testing cost was not

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC Combined - Existing Area Source Limit Calculations

**PVC Process Vents - GACT Analysis - Vinyl Chloride - PVC Combined**

**Facility Run**  **Conc (PPMV @ 3% O2)**  **LN Conc (PPMV**

**@ 3% O2) DL** 

**average run value**  **DL for Max**

**Sorting Facility**  **Run TEQ Conc**  **(ng/dscm @ 3% O2)**  **LN(TEQ)**



## OVLADP 1 1.93E-01 -1.65E+00 1.00E+00 1.93E-01 OVLADP 1 2.74E-02 -3.60E+00
OVLADP 2 1.93E-01 -1.65E+00 1.00E+00 1.93E-01 OVLADP 2 1.07E-02 -4.54E+00
OVLADP 3 1.93E-01 -1.65E+00 1.00E+00 1.93E-01 OVLADP 3 7.89E-03 -4.84E+00

**Normal LN**  **Normal LN**  

## Sample Size **3.00 3.00**  **Sample Size 3.00E+00**  **3.00E+00**
**Non-Detects 3.00**  **3.00 Average**  **1.53E-02 -4.33E+00**  **Average 1.93E-01**  **-1.65 Median**  **1.07E-02 -4.54E+00** 
**Median 1.93E-01**  **-1.65 Standard Deviation**  **1.06E-02 6.50E-01**  **Standard Deviation 3.40E-17**  **0 Minimum**  **7.89E-03 -4.84E+00** 
**Minimum 1.93E-01**  **-1.65 Maximum**  **2.74E-02 -3.60E+00** 
**Maximum 1.93E-01**  **-1.65 Skewness**  **1.60E+00 1.32E+00**  **Skewness SE Skewness**  **1.41E+00 1.41E+00**  **SE Skewness 1.41**  **1.41 Skewness Test**  **Normal Normal**  **Skewness Test Normal**  **Normal Kurtosis** 
**Kurtosis SE Kurtosis**  **2.83E+00 2.83E+00**  **SE Kurtosis 2.83**  **2.83 Kurtosis Test**  **Normal Normal** 
**Kurtosis Test Normal**  **Normal 99.0% t-statistic for UPL**  **6.96E+00 6.96E+00**  **99.0% t-statistic for UPL 6.96**  **6.96 99.0% UPL**  **7.55E-02 5.34E-01**  **99.0% UPL 1.93E-01**  **1.93E-01**
average in variability analysis 

## 1.53E-02
average in variability analysis 

## 1.93E-01 3x RDL 

## 3.35E-02

RDL 1.84E-01 

## 99.0% UPL 7.55E-02

3 x RDL 5.52E-01 

### New Source GACT Limit 

## 7.60E-02**ng/dscm @ 3% O2** 

## 99.0% UPL 1.93E-01 **New Source GA CT Limit**  **5.60E-01 PPMVD @ 3% O2**  

## 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability **PVC Process Vents - GACT Analysis -CDD/CDF (TEQ) - PVC Combined**

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC Combined - Existing Area Source Limit Calculations

**PVC Process Vents - GACT Analysis -TOHAP - PVC Combined**

**Facility Run**  **Conc (PPMV @ 3% O2)**  **LN Conc (PPMV @**

**3% O2) DL average** 

**run value DL for Max** 

**Sorting** 

## WLG 1 1.17E+00 1.58E-01 2.56E+00 2.56E+00
WLG 2 8.94E+00 2.19E+00 2.49E+00 2.49E+00
WLG 3 1.93E+00 6.59E-01 2.69E+00 2.69E+00

**Normal LN**  

## Sample Size **3.00E+00 3.00E+00** 
**Non-Detects 3.00E+00**  **3.00E+00 Average**  **4.02E+00 1.00E+00** 
**Median 1.93E+00**  **6.59E-01 Standard Deviation**  **4.28E+00 1.06E+00** 
**Minimum 1.17E+00**  **1.58E-01**
**Maximum 8.94E+00**  **2.19E+00 Skewness**  **1.67E+00 1.31E+00**  **SE Skewness 1.41E+00**  **1.41E+00 Skewness Test**  **Normal Normal** 
**Kurtosis SE Kurtosis**  **2.83E+00 2.83E+00** 
**Kurtosis Test Normal**  **Normal 99.0% t-statistic for UPL**  **6.96E+00 6.96E+00**  **99.0% UPL 2.84E+01**  **1.13E+03**

average in variability analysis 4.02E+00

RDL 1.81E+00

3 x RDL 5.42E+00 

## 99.0% UPL 2.84E+01
**New Source GACT Limit 2.90E+01** 

### ppmvd @ 3% O2 

## 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012



# Process Vents - PVC Combined - Existing Area Source Limit Calculations

**THC PVC Combined - Existing Area Source**

**Company Facility**  **Compound_Std Method**  **Run Date**  **Value Ln Value**  OxyVinyls Deer Park THC EPA Method 25A 1 8/31/2011 1.10E-01 -2.21E+00 OxyVinyls Deer Park THC EPA Method 25A 2 8/31/2011 1.10E-01 -2.21E+00 OxyVinyls Deer Park THC EPA Method 25A 3 8/31/2011 1.10E-01 -2.21E+00 Average **1.10E-01** Note: All Values Reported as ND

**Normal LN**  Sample Size 3.00E+00 3.00E+00 Compliance Avg 3.00E+00 3.00E+00 Average 1.10E-01 -2.21E+00
Median 1.10E-01 -2.21E+00 Standard Deviation 0.00E+00 0.00E+00
Minimum 1.10E-01 -2.21E+00
Maximum 1.10E-01 -2.21E+00 Skewness SE Skewness 1.41E+00 1.41E+00 Skewness Test
Kurtosis SE Kurtosis 2.83E+00 2.83E+00
Kurtosis Test 99.0% t-statistic for UL 4.54E+00 4.54E+00 99.0% UL 1.10E-01 1.10E-01 99.0% t-statistic for UPL 6.96E+00 6.96E+00 99.0% UPL 1.10E-01 1.10E-01

average in variability analysis 1.10E-01

RDL 7.58E-01

3x RDL 2.27E+00 

## 99.0% UPL 1.10E-01 **Existing Source Level of Control 2.30E+00** 

### ppmvd @ 3% O2 

## * Cannot perform Skewness or Kurtosis test. 

## 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability **THC Variability Analysis - PVC Combined (Existing) ppmvd @ 3% O2**  ppmvd @ 3% O2 ppmvd @ 3% O2 ppmvd @ 3% O2 **Units**

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012

**Process Vents - PVC Combined - Costs and Emissions Reductions for New and Existing Area Sources**

**Major Source Requirements (Existing PVC Combined MACT Floor)**
VC Area Source 1.10ppmvd @ 3% O2 HCl Area Source ppmvd @ 3% O2 CDD/CDF Area Source 0.051ng/dscm @ 3% O2
TOHAP Area Source 9.8ppmvd @ 3% O2

**Outlet Max Flow Rate**  **(DSCMM) Average O2**  **(%) Avg.** 

**Temp (C)**  **Vinyl Chloride**

**(ppmvd @ 3%O2) HCl** 

**(ppmvd @ 3%O2) CDD/CDF** 

**(ng/dscm @ 3%O2)**  **TotalHAP**

**(ppmvd @ 3%O2)**  **Inlet Max**

**Flow Rate (DSCMM)**  **Average O2**

**(%) Avg. Temp** 

**(C) Vinyl** 

**Chloride (ppmvd @**  **3%O2) CE Redux Effy**  **Vinyl Chloride**  **(lbs/hr) VC** 

Baseline (lbs/hr) **HCl**

Baseline (lbs/hr) **CDD/CDF**

Baseline (lbs/hr) **TOHAP**

Baseline (lbs/hr) **VC**

Baseline (Tons/Yr) **HCl**

Baseline (Tons/Yr) **CDD/CDF**

**(TEQ)** Baseline (Tons/Yr) **TOHAP**

Baseline (Tons/Yr) **VC -**%

Redux to
Meet Conc. Limit **HCl**- %

Redux to
Meet Conc. Limit**CDD/CDF**-

% Redux to
Meet Conc. Limit**TOHAP -**%

Redux to
Meet Conc. Limit **VC HCl**  **CDD/CDF TOHAP** 

OVDP Area Source 1.05E+03 4.07E+00 5.50E+01 1.93E-01 1.53E-02 4.02E+00 2.33E+01 2.43E+00 1.89E+01 1.93E+04 1.00E+02 1.61E+02 6.64E-02 2.01E-09 1.10E+00 2.79E-01 8.42E-09 4.61E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00

0.00E+00g/yr (CDD/CDF)

Average of PVC Combined Facilities

Estimated by calculating average factor of TOHAP (TPY)/Outlet Flow Rate Calculated using Inlet flow, O2, and VC Concentration estimates

Average of All Facilities Estimated by calculating average Reduction Effy for VC for All PVC facilties and applying to outlet concentration

Based on Average Factor (Inlet Flow Rate/Outlet Flow Rate) of PVC Combined Facilities **Facility Classification**  **Outlet Conditions Inlet Conditions**  **Reductions (Tons/yr) Baseline Emissions Estimates**  Percent Reductions Needed to Meet Floors

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012

**Total Reductions** 

**Tons/yr**

0.00E+00

g/yr (CDD/CDF)

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012

**Total Organic HAP Emission Rate Estimate for OVDP**

Notes: Current level of performance for OVDP is based on WLG since OVDP was not required to, and did not, perform testing for any HAP other than VC and CDD/CDF in response to the March 16 section 114.

Baseline emission estimate is calculated using OVDP stack conditions (flow, temperature, etc) during the March 16 section 114 testing: concentration information from WLG.

**lb/hr Tons/yr** 

**OVDP Stack Conditions. 1.10E+00**  **4.61E+00**

**Flow Rate (DSCMM)** 1.05E+03 **Average O2%** 4.07E+00 **Average Temp** 5.50E+01

**Westlake Geismar Concentration Information**
HAP Avg. MW Weight Concentration (ppmvd @ 3% O2) Emission Rate (Lb/hr) Emission Rate (Tons/yr) 1,2,3,4,6,7,8-Heptachlorodibenzofuran 4.09E+02 8.38E-09 1.89E-08 7.93E-08 1,2,3,4,6,7,8-Heptachlorodibenzo-p-Dioxin 4.25E+02 8.77E-10 2.05E-09 8.61E-09 1,2,3,4,7,8,9-Heptachlorodibenzofuran 3.18E+02 2.02E-09 3.54E-09 1.49E-08 1,2,3,4,7,8-Hexachlorodibenzofuran 3.75E+02 3.27E-09 6.74E-09 2.83E-08 1,2,3,4,7,8-Hexachlorodibenzo-p-Dioxin 3.91E+02 2.85E-10 6.13E-10 2.58E-09 1,2,3,6,7,8-Hexachlorodibenzofuran 3.75E+02 2.30E-09 4.74E-09 1.99E-08 1,2,3,6,7,8-Hexachlorodibenzo-p-Dioxin 3.91E+02 2.17E-10 4.66E-10 1.96E-09 1,2,3,7,8,9-Hexachlorodibenzofuran 3.75E+02 7.30E-10 1.51E-09 6.32E-09 1,2,3,7,8,9-Hexachlorodibenzo-p-Dioxin 3.91E+02 2.27E-10 4.89E-10 2.05E-09 1,2,3,7,8-Pentachlorodibenzofuran 3.40E+02 1.46E-09 2.73E-09 1.15E-08 1,2,3,7,8-Pentachlorodibenzo-p-Dioxin 3.56E+02 1.70E-10 3.32E-10 1.40E-09 2,3,3',4,4',5,5'-Heptachlorobiphenyl (PCB 189) 3.95E+02 1.08E-09 2.36E-09 9.89E-09 2,3,3',4,4',5-Hexachlorobiphenyl (PCB 156) 3.61E+02 1.98E-09 3.93E-09 1.65E-08 2,3,3',4,4',5'-Hexachlorobiphenyl (PCB 157) 3.61E+02 2.25E-09 4.46E-09 1.87E-08 2,3,3',4,4'-Pentachlorobiphenyl (PCB 105) 3.26E+02 2.81E-09 5.04E-09 2.12E-08 2,3',4,4',5,5'-Hexachlorobiphenyl (PCB 167) 3.61E+02 2.06E-09 4.10E-09 1.72E-08 2,3,4,4',5-Pentachlorobiphenyl (PCB 114) 3.26E+02 3.15E-09 5.66E-09 2.38E-08 2,3',4,4',5-Pentachlorobiphenyl (PCB 118) 3.26E+02 1.06E-08 1.91E-08 8.03E-08 2,3,4,6,7,8-Hexachlorodibenzofuran 3.75E+02 1.35E-09 2.79E-09 1.17E-08 2,3,4,7,8-Pentachlorodibenzofuran 3.40E+02 1.82E-09 3.41E-09 1.43E-08 2,3,7,8-Tetrachlorodibenzofuran 3.06E+02 5.29E-10 8.90E-10 3.74E-09 2,3,7,8-Tetrachlorodibenzo-p-Dioxin 3.22E+02 1.92E-10 3.40E-10 1.43E-09 2-Methylnaphthalene 1.42E+02 1.06E-05 8.31E-06 3.49E-05 3,3',4,4',5,5'-Hexachlorobiphenyl (PCB 169) 3.61E+02 2.36E-09 4.69E-09 1.97E-08 3,3',4,4',5-Pentachlorobiphenyl (PCB 126) 3.26E+02 3.41E-09 6.12E-09 2.57E-08 3,3',4,4'-Tetrachlorobiphenyl (PCB 77) 2.92E+02 5.14E-09 8.25E-09 3.47E-08 Acetaldehyde 4.41E+01 3.35E+00 8.12E-01 3.41E+00 Benzo[e]Pyrene 2.52E+02 8.40E-07 1.17E-06 4.90E-06 Benzo[g,h,i,]Perylene 2.76E+02 7.67E-07 1.17E-06 4.90E-06 Ethyl Chloride 6.45E+01 6.42E-04 2.28E-04 9.56E-04 Ethylene Dichloride 9.90E+01 5.76E-02 3.14E-02 1.32E-01 Fluoranthene 2.02E+02 1.05E-06 1.17E-06 4.90E-06 Formaldehyde 3.00E+01 2.89E-01 4.77E-02 2.00E-01 Methanol 3.20E+01 2.89E-01 5.09E-02 2.14E-01 Methyl Chloride 5.05E+01 1.12E-02 3.11E-03 1.31E-02 Methylene Chloride 8.49E+01 5.73E-03 2.68E-03 1.12E-02 Naphthalene 1.28E+02 2.39E-05 1.69E-05 7.08E-05 Octachlorodibenzofuran 4.44E+02 7.93E-09 1.94E-08 8.13E-08 Octachlorodibenzo-p-Dioxin 4.60E+02 2.71E-09 6.85E-09 2.88E-08 Perylene 2.52E+02 8.40E-07 1.17E-06 4.90E-06 Phenanthrene 1.78E+02 1.04E-05 1.02E-05 4.27E-05 Phenol 9.41E+01 2.89E-01 1.49E-01 6.28E-01 Pyrene 2.02E+02 1.05E-06 1.17E-06 4.90E-06 Toluene 9.21E+01 6.70E-04 3.40E-04 1.43E-03 Vinyl Chloride 6.25E+01 7.31E-04 2.51E-04 1.06E-03 **TOHAP Emission**
**Rate**

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012

# ATTACHMENT C - PVC Combined PROCESS VENTS ANALYSIS

02/09/2012

**Process Vents Emission Testing Costs Parameters/Costs**  **Equation Values**  **Testing Freq.*** **An nual Cost of Test**  **An nual Cost of Initial Test**  **TAC of Testing**

A. Parameters
1. CE Plant Cost index a. 2010 (Feb 10 Final CE Index) 539.1 b. 2009 (Annual CE Index) 521.9 c. 1992 (Annual CE Index) 358.2

B. Testing Costs, $
1. Method 1 or 1A Included as part of M 23

- $ 

## 5

- $

-

$

- $ 2. Method 26 (HCl) = $5,000 x (539.1/358.2) 

## 5

- $

- $ 3. Method 23 (CDD/CDF) = $21,000 x (539.1/358.2) - $5,000 $27,000 

## 5 5,400 $ 5,400 $ 4. Method 25A (THC) =$6,000x(539.1/521.9) $6,198 

## 5 1,240 $ 1,240 $ 5. Method 18 (Assumed cost equal to 0031) $10,000 

## 5 2,000 $ 2,000 $

C. CRF (20 yr, 7%): (0.07*(1+0.07)^20)/((1+0.07)^20-1) 0.09439

D. Facility Totals 1.TOH, &VC 

## 3,240 **$**

2. CDD/CDF 

## 5,400 **$ 3. Facility Total**  **$ 43,197.74** 

## 8,640 **$**

* Number of Years Between Tests

Note:

3. E-mail from Jason Dew ees, EPA, to Mary Johnson, EPA. August 20, 2008. Re: Monitoring Options for SNCR & Test Cost Questions.

4. Conversation with Ray Merrill, ERG - 11/5/2010.
5. Email from Peter Westlin, EPA 4/8/2011 to ERG: Method 18 Costs 1. Initial testing costs to be annualized over 20 years at 7% interest.

2. Testing costs have been rounded to the nearest $1,000 to be consistent with level of rounding in original costs; costs also adjusted based on additional information from EPA.

Sources:

1. Memorandum from R. Segall, EPA/EMB, to R. Copland, EPA/SDB. October 14, 1992. Medical Waste Incinerator Study: Emission Measurement and Continuous Monitoring. (IIB-89)

2. E-mail from Jason Dew ees, EPA, to Peter Westlin, EPA. August 20, 2008. Monitoring Options for SNCR & Test Cost Questions.

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins Summary

**4.47E+08**(lbs/yr)

**5.51E+08**

## (lbs/yr)
**4.38E+06**

## (lbs/yr) **New and Existing Source GACT Summary for Stripped Resins** 1 - VI 009 Submission - 2006 Capacity Data

**Resin Type Pollutant**  **Area Source Current Level of Performance**  **(Avg. Concentrations) Area Source Current**  **Level of Performance (With Variability)**  **(ppmw) Option 1 Concentration** 

**(Existing Source Requirements)**  **(ppmw) Current Level of** 

**Performance Emissions**  **(Tons/yr) Existing Source** 

**Requirements Emissions (Tons/yr)**  **Emissions Reduction for**  **Option 1 (Tons/yr)**



## VC 7.10 7.10 7.10 0.94 0.94 0.00 Total Non-VC HAP 160.20 170.00 170.00 5.57 5.57 0.00
VC 0.86 36.00 37.00 0.24 10.20 0.00 Total Non-VC HAP 12.11 36.00 670.00 3.34 184.64 0.00
VC 533.50 1500.00 1300.00 1.17 2.85 0.00 Total Non-VC HAP 67.60 320.00 240.00 0.15 0.53 0.00
VC 15.66 140.00 140.00 0.03 0.31 0.00 Total Non-VC HAP 64.16 500.00 500.00 0.14 1.09 0.00
VC 361.44 790.00 790.00 0.79 1.73 0.00 Total Non-VC HAP 892.77 1900.00 1900.00 1.95 4.16 0.00 Note - OVDP is better controlled than the least controlled MACT Source, therefore, new = exisitng. CTLC is only bulk source, therefore new=existing. All other categories = least controlled MACT source. Total HAP Disp. 2.34E+01TPY Total HAP SB 2.23E+01TPY Total HAP CP 2.48E+01TPY

**GACT Analysis - Resins -New and Existing Source Costs to Meet Exisitng Major Source Requirements**

**Cost Component Bulk**  **Suspension Dispersion**  **Suspension Blending Copolymer** 



## Initial Costs Control Equipment Capital Cost 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Initial Resin Testing 1.80E+03 1.80E+03 1.80E+03 1.80E+03 1.80E+03 Initial Record Keeping and Reporting Cost 2.52E+03 2.52E+03 2.52E+03 2.52E+03 2.52E+03 **Total Initial Costs 4.32E+03**  **4.32E+03 4.32E+03**  **4.32E+03 4.32E+03**  **Annual Costs** Annualized Capital Cost 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Annual Control Equipment Cost 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Annualized Initial Testing and Monitoring Cost 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Annual Testing and Monitoring Cost 7.21E+03 7.21E+03 7.21E+03 7.21E+03 7.21E+03 Annual Record Keeping and Reporting Cost 3.40E+03 3.40E+03 3.40E+03 3.40E+03 3.40E+03 **Total Annual Cost 1.06E+04**  **1.06E+04 1.06E+04**  **1.06E+04 1.06E+04**  1 - Initial Testing Cost less than annual; therefore, no amortization of initial testing cost Suspension Blending

Copolymer Cretain Teed Resin Production

OVDP Resin Production1


## Model Resin Production

CTLC - Bulk

OVDP-Suspension

Dispersion

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**

Resin Type Suspension Percentile: 9.99E+01 **GACT Limit (ppmw) 3.52E+01**  Average of Vinyl Chloride Concentration (ppmw) Facility Date Total Vinyl Chloride (ppmw) 

# OxyVinyls - Deer Park 1/1/2007#DIV/0! 1/2/2007 9.20E-02 9.20E-02 1/3/2007 3.19E-01 3.19E-01 1/4/2007 2.39E-01 2.39E-01 1/5/2007 2.06E-01 2.06E-01 1/6/2007 3.18E-01 3.18E-01 1/7/2007 3.01E-01 3.01E-01 1/8/2007 3.05E-01 3.05E-01 1/9/2007 1.88E-01 1.88E-01 1/10/2007 1.51E-01 1.51E-01 1/11/2007 1.58E-01 1.58E-01 1/12/2007 4.09E-01 4.09E-01 1/13/2007 3.15E-01 3.15E-01 1/14/2007 3.25E-01 3.25E-01 1/15/2007 1.73E-01 1.73E-01 1/16/2007 4.96E-01 4.96E-01 1/17/2007 2.42E-01 2.42E-01 1/18/20071.13E+00 1.13E+00 1/19/20071.99E+00 1.99E+00 1/20/20071.72E+00 1.72E+00 1/21/20071.47E+00 1.47E+00 1/22/20071.39E+00 1.39E+00 1/23/20071.87E+00 1.87E+00 1/24/20078.97E+00 8.97E+00 1/25/20072.27E+00 2.27E+00 1/26/20072.64E+00 2.64E+00 1/27/20073.41E+00 3.41E+00 1/28/20071.84E+00 1.84E+00 1/29/2007 5.68E-01 5.68E-01 1/30/2007 1.51E-01 1.51E-01 1/31/2007 2.23E-01 2.23E-01 2/1/2007 4.01E-01 4.01E-01 2/2/2007 8.78E-01 8.78E-01 2/3/2007 3.54E-01 3.54E-01 2/4/2007 7.01E-01 7.01E-01 2/5/2007 4.11E-01 4.11E-01 2/6/2007 2.92E-01 2.92E-01 2/7/2007 2.76E-01 2.76E-01 2/8/2007 7.47E-01 7.47E-01 2/9/2007 9.83E-01 9.83E-01 2/10/2007 6.69E-01 6.69E-01 2/11/2007 6.37E-01 6.37E-01 2/12/2007 5.37E-01 5.37E-01 2/13/2007 2.50E-02 2.50E-02 2/14/2007 1.04E-01 1.04E-01 2/15/2007 2.09E-01 2.09E-01 2/16/2007 3.25E-01 3.25E-01 2/17/2007 3.96E-01 3.96E-01 2/18/2007 2.15E-01 2.15E-01 2/19/2007 2.21E-01 2.21E-01 2/20/2007 7.90E-02 7.90E-02 2/21/20071.96E+00 1.96E+00 2/22/20073.25E+00 3.25E+00 2/23/20073.55E+00 3.55E+00 2/24/2007 4.55E-01 4.55E-01 2/25/20072.10E+00 2.10E+00 2/26/20074.30E+00 4.30E+00 2/27/2007 9.76E-01 9.76E-01 2/28/2007 6.35E-01 6.35E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
3/1/20071.80E+00 1.80E+00 3/2/20073.30E+00 3.30E+00 3/3/2007 8.81E-01 8.81E-01 3/4/2007 6.19E-01 6.19E-01 3/5/20071.32E+00 1.32E+00 3/6/2007 6.35E-01 6.35E-01 3/7/2007 7.14E-01 7.14E-01 3/8/2007 7.08E-01 7.08E-01 3/9/20071.31E+00 1.31E+00 3/10/2007 9.45E-01 9.45E-01 3/11/20071.10E+00 1.10E+00 3/12/2007 6.79E-01 6.79E-01 3/13/2007 1.60E-01 1.60E-01 3/14/2007 2.00E-01 2.00E-01 3/15/2007 2.28E-01 2.28E-01 3/16/2007 2.49E-01 2.49E-01 3/17/2007 1.24E-01 1.24E-01 3/18/2007 2.13E-01 2.13E-01 3/19/2007 2.64E-01 2.64E-01 3/20/2007#DIV/0! 3/21/20071.07E+00 1.07E+00 3/22/2007 1.97E-01 1.97E-01 3/23/2007 1.77E-01 1.77E-01 3/24/2007 6.32E-01 6.32E-01 3/25/2007 3.96E-01 3.96E-01 3/26/2007 4.24E-01 4.24E-01 3/27/20074.20E+00 4.20E+00 3/28/2007 2.11E-01 2.11E-01 3/29/2007 3.25E-01 3.25E-01 3/30/2007 1.99E-01 1.99E-01 3/31/2007 6.34E-01 6.34E-01 4/1/2007 2.69E-01 2.69E-01 4/2/2007 1.10E-01 1.10E-01 4/3/2007 2.95E-01 2.95E-01 4/4/2007 6.68E-01 6.68E-01 4/5/2007 5.70E-01 5.70E-01 4/6/2007 6.58E-01 6.58E-01 4/7/2007 5.38E-01 5.38E-01 4/8/2007 5.68E-01 5.68E-01 4/9/2007 8.46E-01 8.46E-01 4/10/20071.05E+00 1.05E+00 4/11/20071.33E+00 1.33E+00 4/12/20071.48E+00 1.48E+00 4/13/20071.32E+00 1.32E+00 4/14/20071.17E+00 1.17E+00 4/15/20071.21E+00 1.21E+00 4/16/2007 5.49E-01 5.49E-01 4/17/2007 2.74E-01 2.74E-01 4/18/2007 1.58E-01 1.58E-01 4/19/2007 4.62E-01 4.62E-01 4/20/2007 2.53E-01 2.53E-01 4/21/2007 1.81E-01 1.81E-01 4/22/2007 1.62E-01 1.62E-01 4/23/2007 2.15E-01 2.15E-01 4/24/2007 3.00E-01 3.00E-01 4/25/20071.46E+00 1.46E+00 4/26/2007 2.39E-01 2.39E-01 4/27/2007 3.51E-01 3.51E-01 4/28/2007 7.99E-01 7.99E-01 4/29/2007 2.75E-01 2.75E-01 4/30/2007 2.19E-01 2.19E-01 5/1/2007 1.69E-01 1.69E-01 5/2/2007 1.81E-01 1.81E-01 5/3/2007#DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
5/4/20073.88E+00 3.88E+00 5/5/2007#DIV/0! 5/6/2007#DIV/0! 5/7/2007#DIV/0! 5/8/2007#DIV/0! 5/9/2007#DIV/0! 5/10/2007 7.20E-02 7.20E-02 5/11/2007 1.00E-02 1.00E-02 5/12/2007#DIV/0! 5/13/2007#DIV/0! 5/14/2007 4.50E-02 4.50E-02 5/15/2007 2.20E-01 2.20E-01 5/16/2007 2.43E-01 2.43E-01 5/17/2007 2.60E-01 2.60E-01 5/18/2007 1.92E-01 1.92E-01 5/19/2007 2.03E-01 2.03E-01 5/20/2007 3.62E-01 3.62E-01 5/21/2007 2.41E-01 2.41E-01 5/22/2007 3.22E-01 3.22E-01 5/23/2007 6.49E-01 6.49E-01 5/24/20071.06E+00 1.06E+00 5/25/20071.94E+00 1.94E+00 5/26/20072.19E+00 2.19E+00 5/27/20072.29E+00 2.29E+00 5/28/20073.34E+00 3.34E+00 5/29/20071.34E+00 1.34E+00 5/30/2007 8.06E-01 8.06E-01 5/31/20072.03E+00 2.03E+00 6/1/2007 3.77E-01 3.77E-01 6/2/2007 2.39E-01 2.39E-01 6/3/2007 4.42E-01 4.42E-01 6/4/2007 5.86E-01 5.86E-01 6/5/20071.03E+00 1.03E+00 6/6/2007 9.92E-01 9.92E-01 6/7/20073.44E+00 3.44E+00 6/8/20073.39E+00 3.39E+00 6/9/20072.77E+00 2.77E+00 6/10/20072.69E+00 2.69E+00 6/11/2007 7.61E-01 7.61E-01 6/12/20071.19E+00 1.19E+00 6/13/2007 3.09E-01 3.09E-01 6/14/2007 7.40E-01 7.40E-01 6/15/2007 7.78E-01 7.78E-01 6/16/20071.14E+00 1.14E+00 6/17/20071.15E+00 1.15E+00 6/18/2007 9.96E-01 9.96E-01 6/19/2007 6.52E-01 6.52E-01 6/20/2007 5.09E-01 5.09E-01 6/21/2007 6.38E-01 6.38E-01 6/22/2007 6.40E-01 6.40E-01 6/23/2007 4.48E-01 4.48E-01 6/24/2007 4.82E-01 4.82E-01 6/25/20076.59E+00 6.59E+00 6/26/2007 3.33E-01 3.33E-01 6/27/2007 6.13E-01 6.13E-01 6/28/2007 5.88E-01 5.88E-01 6/29/2007 3.06E-01 3.06E-01 6/30/2007 2.05E-01 2.05E-01 7/1/2007 2.88E-01 2.88E-01 7/2/2007 1.95E-01 1.95E-01 7/3/2007 1.57E-01 1.57E-01 7/4/2007 5.31E-01 5.31E-01 7/5/2007 1.56E-01 1.56E-01 7/6/2007 3.60E-01 3.60E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
7/7/2007 2.99E-01 2.99E-01 7/8/2007 4.04E-01 4.04E-01 7/9/2007 3.85E-01 3.85E-01 7/10/2007 2.91E-01 2.91E-01 7/11/2007 5.27E-01 5.27E-01 7/12/2007 4.30E-01 4.30E-01 7/13/2007 4.83E-01 4.83E-01 7/14/2007 9.49E-01 9.49E-01 7/15/2007 4.79E-01 4.79E-01 7/16/2007 3.88E-01 3.88E-01 7/17/2007 6.29E-01 6.29E-01 7/18/2007 6.03E-01 6.03E-01 7/19/2007 5.51E-01 5.51E-01 7/20/2007 5.75E-01 5.75E-01 7/21/2007 3.39E-01 3.39E-01 7/22/2007 2.83E-01 2.83E-01 7/23/2007 3.77E-01 3.77E-01 7/24/2007 2.76E-01 2.76E-01 7/25/2007 4.27E-01 4.27E-01 7/26/20072.03E+00 2.03E+00 7/27/20071.37E+00 1.37E+00 7/28/2007 7.21E-01 7.21E-01 7/29/2007 4.05E-01 4.05E-01 7/30/2007 5.63E-01 5.63E-01 7/31/2007 2.50E-01 2.50E-01 8/1/2007 5.47E-01 5.47E-01 8/2/2007 5.77E-01 5.77E-01 8/3/20071.09E+00 1.09E+00 8/4/20072.27E+00 2.27E+00 8/5/20071.30E+00 1.30E+00 8/6/2007 4.66E-01 4.66E-01 8/7/2007 6.14E-01 6.14E-01 8/8/20071.20E+00 1.20E+00 8/9/2007 2.67E-01 2.67E-01 8/10/2007 1.56E-01 1.56E-01 8/11/2007 2.05E-01 2.05E-01 8/12/2007 1.53E-01 1.53E-01 8/13/2007 1.82E-01 1.82E-01 8/14/2007 9.20E-02 9.20E-02 8/15/2007 3.31E-01 3.31E-01 8/16/20071.42E+00 1.42E+00 8/17/2007 6.46E-01 6.46E-01 8/18/2007 7.05E-01 7.05E-01 8/19/2007 6.54E-01 6.54E-01 8/20/2007 5.83E-01 5.83E-01 8/21/2007 6.69E-01 6.69E-01 8/22/2007 6.76E-01 6.76E-01 8/23/2007 5.89E-01 5.89E-01 8/24/20073.88E+01 3.88E+01 8/25/2007 6.10E-01 6.10E-01 8/26/2007 3.35E-01 3.35E-01 8/27/2007 3.68E-01 3.68E-01 8/28/2007 3.03E-01 3.03E-01 8/29/2007 4.86E-01 4.86E-01 8/30/2007 7.88E-01 7.88E-01 8/31/2007 5.29E-01 5.29E-01 9/1/2007 3.76E-01 3.76E-01 9/2/2007 3.57E-01 3.57E-01 9/3/2007 7.41E-01 7.41E-01 9/4/2007 4.26E-01 4.26E-01 9/5/2007 4.46E-01 4.46E-01 9/6/2007 3.58E-01 3.58E-01 9/7/2007 4.92E-01 4.92E-01 9/8/2007 8.48E-01 8.48E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
9/9/2007 3.93E-01 3.93E-01 9/10/2007 5.02E-01 5.02E-01 9/11/2007 4.73E-01 4.73E-01 9/12/2007 2.68E-01 2.68E-01 9/13/2007 2.10E-01 2.10E-01 9/14/2007 2.68E-01 2.68E-01 9/15/2007 3.92E-01 3.92E-01 9/16/2007 4.89E-01 4.89E-01 9/17/2007 2.81E-01 2.81E-01 9/18/2007 3.50E-01 3.50E-01 9/19/2007 2.89E-01 2.89E-01 9/20/2007 3.32E-01 3.32E-01 9/21/2007#DIV/0! 9/22/2007#DIV/0! 9/23/2007#DIV/0! 9/24/2007 2.00E-02 2.00E-02 9/25/2007#DIV/0! 9/26/2007 5.87E-01 5.87E-01 9/27/2007 8.02E-01 8.02E-01 9/28/2007 9.96E-01 9.96E-01 9/29/20071.27E+00 1.27E+00 9/30/20071.23E+00 1.23E+00 10/1/20071.12E+00 1.12E+00 10/2/2007 6.80E-01 6.80E-01 10/3/2007 2.18E-01 2.18E-01 10/4/2007 5.15E-01 5.15E-01 10/5/2007 1.69E-01 1.69E-01 10/6/2007 2.87E-01 2.87E-01 10/7/2007 3.95E-01 3.95E-01 10/8/2007 4.66E-01 4.66E-01 10/9/2007 8.42E-01 8.42E-01 10/10/2007 5.63E-01 5.63E-01 10/11/2007 7.33E-01 7.33E-01 10/12/2007#DIV/0! 10/13/2007#DIV/0! 10/14/2007#DIV/0! 10/15/2007#DIV/0! 10/16/2007#DIV/0! 10/17/2007#DIV/0! 10/18/2007#DIV/0! 10/19/2007#DIV/0! 10/20/2007#DIV/0! 10/21/2007#DIV/0! 10/22/2007 1.60E-02 1.60E-02 10/23/2007 8.60E-02 8.60E-02 10/24/2007 4.75E-01 4.75E-01 10/25/2007 3.80E-01 3.80E-01 10/26/2007 3.77E-01 3.77E-01 10/27/2007 3.04E-01 3.04E-01 10/28/2007 3.69E-01 3.69E-01 10/29/2007 2.47E-01 2.47E-01 10/30/2007 3.61E-01 3.61E-01 10/31/2007 3.69E-01 3.69E-01 11/1/2007 8.82E-01 8.82E-01 11/2/2007 8.43E-01 8.43E-01 11/3/2007 9.11E-01 9.11E-01 11/4/20076.57E+00 6.57E+00 11/5/2007 8.06E-01 8.06E-01 11/6/2007 5.83E-01 5.83E-01 11/7/2007 5.08E-01 5.08E-01 11/8/2007 6.70E-01 6.70E-01 11/9/2007 6.24E-01 6.24E-01 11/10/2007 6.13E-01 6.13E-01 11/11/2007 3.67E-01 3.67E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
11/12/2007 3.38E-01 3.38E-01 11/13/2007 3.33E-01 3.33E-01 11/14/2007 2.56E-01 2.56E-01 11/15/2007 3.23E-01 3.23E-01 11/16/2007 1.82E-01 1.82E-01 11/17/2007 3.12E-01 3.12E-01 11/18/2007 3.05E-01 3.05E-01 11/19/2007 4.62E-01 4.62E-01 11/20/2007 5.22E-01 5.22E-01 11/21/2007 1.00E-02 1.00E-02 11/22/20075.04E+00 5.04E+00 11/23/2007 3.84E-01 3.84E-01 11/24/2007 5.62E-01 5.62E-01 11/25/20071.09E+00 1.09E+00 11/26/20073.35E+00 3.35E+00 11/27/20075.99E+00 5.99E+00 11/28/20072.72E+00 2.72E+00 11/29/20071.81E+00 1.81E+00 11/30/20073.26E+00 3.26E+00 12/1/20071.24E+00 1.24E+00 12/2/20074.03E+00 4.03E+00 12/3/20071.68E+00 1.68E+00 12/4/20071.39E+00 1.39E+00 12/5/20071.69E+00 1.69E+00 12/6/20072.18E+00 2.18E+00 12/7/20074.63E+00 4.63E+00 12/8/20072.15E+00 2.15E+00 12/9/20071.94E+00 1.94E+00 12/10/20074.25E+00 4.25E+00 12/11/20073.45E+00 3.45E+00 12/12/2007 7.34E-01 7.34E-01 12/13/2007 1.39E-01 1.39E-01 12/14/2007 1.58E-01 1.58E-01 12/15/2007 3.54E-01 3.54E-01 12/16/2007 9.91E-01 9.91E-01 12/17/2007 6.00E-02 6.00E-02 12/18/2007#DIV/0! 12/19/2007#DIV/0! 12/20/2007#DIV/0! 12/21/2007 1.26E-01 1.26E-01 12/22/2007 3.23E-01 3.23E-01 12/23/2007 6.30E-02 6.30E-02 12/24/2007 2.33E-01 2.33E-01 12/25/2007 2.30E-01 2.30E-01 12/26/2007 2.66E-01 2.66E-01 12/27/2007 1.29E-01 1.29E-01 12/28/2007 3.55E-01 3.55E-01 12/29/2007 8.54E-01 8.54E-01 12/30/2007 3.80E-01 3.80E-01 12/31/2007 6.34E-01 6.34E-01 1/1/2008 6.32E-01 6.32E-01 1/2/2008 6.56E-01 6.56E-01 1/3/20081.03E+00 1.03E+00 1/4/20081.05E+00 1.05E+00 1/5/20081.69E+00 1.69E+00 1/6/20081.72E+00 1.72E+00 1/7/20082.45E+00 2.45E+00 1/8/2008 6.45E-01 6.45E-01 1/9/2008 3.66E-01 3.66E-01 1/10/2008 2.74E-01 2.74E-01 1/11/2008 3.05E-01 3.05E-01 1/12/2008 2.39E-01 2.39E-01 1/13/2008 2.45E-01 2.45E-01 1/14/2008 2.47E-01 2.47E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
1/15/2008 3.14E-01 3.14E-01 1/16/2008 1.84E-01 1.84E-01 1/17/2008 2.30E-01 2.30E-01 1/18/2008 1.27E-01 1.27E-01 1/19/2008 7.52E-01 7.52E-01 1/20/2008 1.44E-01 1.44E-01 1/21/2008 2.36E-01 2.36E-01 1/22/2008 2.30E-01 2.30E-01 1/23/2008 9.25E-01 9.25E-01 1/24/2008 1.67E-01 1.67E-01 1/25/2008 1.81E-01 1.81E-01 1/26/2008 4.03E-01 4.03E-01 1/27/2008 2.53E-01 2.53E-01 1/28/2008 3.25E-01 3.25E-01 1/29/2008 3.24E-01 3.24E-01 1/30/20081.09E+00 1.09E+00 1/31/2008 3.70E-01 3.70E-01 2/1/2008 4.61E-01 4.61E-01 2/2/2008 4.26E-01 4.26E-01 2/3/2008 4.22E-01 4.22E-01 2/4/2008 4.45E-01 4.45E-01 2/5/2008 3.74E-01 3.74E-01 2/6/2008 1.22E-01 1.22E-01 2/7/2008 5.91E-01 5.91E-01 2/8/2008 2.77E-01 2.77E-01 2/9/2008 1.82E-01 1.82E-01 2/10/2008 3.28E-01 3.28E-01 2/11/2008 2.53E-01 2.53E-01 2/12/2008 2.01E-01 2.01E-01 2/13/2008 1.88E-01 1.88E-01 2/14/2008 4.44E-01 4.44E-01 2/15/2008 3.91E-01 3.91E-01 2/16/2008 1.96E-01 1.96E-01 2/17/2008 2.94E-01 2.94E-01 2/18/2008 3.16E-01 3.16E-01 2/19/2008 2.45E-01 2.45E-01 2/20/2008 4.04E-01 4.04E-01 2/21/2008 1.23E-01 1.23E-01 2/22/2008 4.90E-01 4.90E-01 2/23/2008 6.52E-01 6.52E-01 2/24/2008 8.16E-01 8.16E-01 2/25/20081.06E+00 1.06E+00 2/26/2008#DIV/0! 2/27/2008#DIV/0! 2/28/2008#DIV/0! 2/29/2008#DIV/0! 3/1/2008#DIV/0! 3/2/2008#DIV/0! 3/3/2008 2.52E-01 2.52E-01 3/4/20081.62E+00 1.62E+00 3/5/2008 2.51E-01 2.51E-01 3/6/2008 3.00E-01 3.00E-01 3/7/2008 7.30E-01 7.30E-01 3/8/2008 5.57E-01 5.57E-01 3/9/2008 5.03E-01 5.03E-01 3/10/2008 2.51E-01 2.51E-01 3/11/2008 2.89E-01 2.89E-01 3/12/2008 2.84E-01 2.84E-01 3/13/2008 2.16E-01 2.16E-01 3/14/2008 3.12E-01 3.12E-01 3/15/2008 1.23E-01 1.23E-01 3/16/2008 1.86E-01 1.86E-01 3/17/2008 8.14E-01 8.14E-01 3/18/20082.08E+00 2.08E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
3/19/20081.08E+00 1.08E+00 3/20/20081.29E+00 1.29E+00 3/21/20081.20E+00 1.20E+00 3/22/2008 7.96E-01 7.96E-01 3/23/20081.88E+00 1.88E+00 3/24/2008 9.26E-01 9.26E-01 3/25/2008#DIV/0! 3/26/2008#DIV/0! 3/27/2008#DIV/0! 3/28/2008#DIV/0! 3/29/2008 1.00E-02 1.00E-02 3/30/2008#DIV/0! 3/31/2008 1.60E-02 1.60E-02 4/1/2008#DIV/0! 4/2/2008 7.20E-01 7.20E-01 4/3/2008 1.96E-01 1.96E-01 4/4/2008 3.17E-01 3.17E-01 4/5/2008 3.56E-01 3.56E-01 4/6/2008 3.71E-01 3.71E-01 4/7/2008 6.12E-01 6.12E-01 4/8/2008 2.36E-01 2.36E-01 4/9/2008 2.34E-01 2.34E-01 4/10/2008 2.22E-01 2.22E-01 4/11/2008 3.90E-01 3.90E-01 4/12/2008 3.76E-01 3.76E-01 4/13/2008 7.72E-01 7.72E-01 4/14/2008 6.00E-01 6.00E-01 4/15/2008 6.63E-01 6.63E-01 4/16/20081.50E+00 1.50E+00 4/17/20081.44E+00 1.44E+00 4/18/2008 7.93E-01 7.93E-01 4/19/2008#DIV/0! 4/20/2008#DIV/0! 4/21/2008#DIV/0! 4/22/2008#DIV/0! 4/23/2008#DIV/0! 4/24/2008#DIV/0! 4/25/2008#DIV/0! 4/26/2008#DIV/0! 4/27/2008#DIV/0! 4/28/2008#DIV/0! 4/29/2008#DIV/0! 4/30/2008#DIV/0! 5/1/2008 1.59E-01 1.59E-01 5/2/2008 1.43E-01 1.43E-01 5/3/2008 3.70E-01 3.70E-01 5/4/20088.39E+00 8.39E+00 5/5/2008 3.31E-01 3.31E-01 5/6/2008 2.53E-01 2.53E-01 5/7/2008 2.21E-01 2.21E-01 5/8/2008 6.46E-01 6.46E-01 5/9/2008 5.35E-01 5.35E-01 5/10/20081.36E+00 1.36E+00 5/11/20081.37E+00 1.37E+00 5/12/20081.37E+00 1.37E+00 5/13/20081.18E+00 1.18E+00 5/14/20082.87E+00 2.87E+00 5/15/2008 2.46E-01 2.46E-01 5/16/2008 3.74E-01 3.74E-01 5/17/2008 7.01E-01 7.01E-01 5/18/2008 2.37E-01 2.37E-01 5/19/2008 2.81E-01 2.81E-01 5/20/2008 2.14E-01 2.14E-01 5/21/2008 4.62E-01 4.62E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
5/22/2008 3.83E-01 3.83E-01 5/23/2008 3.87E-01 3.87E-01 5/24/2008 2.60E-01 2.60E-01 5/25/2008 3.52E-01 3.52E-01 5/26/2008 4.23E-01 4.23E-01 5/27/2008 3.95E-01 3.95E-01 5/28/2008 4.50E-01 4.50E-01 5/29/20081.11E+00 1.11E+00 5/30/2008 6.12E-01 6.12E-01 5/31/2008 7.79E-01 7.79E-01 6/1/2008 7.14E-01 7.14E-01 6/2/2008 7.57E-01 7.57E-01 6/3/2008 5.67E-01 5.67E-01 6/4/2008 4.90E-01 4.90E-01 6/5/2008 6.23E-01 6.23E-01 6/6/2008 2.44E-01 2.44E-01 6/7/2008 2.88E-01 2.88E-01 6/8/2008 2.83E-01 2.83E-01 6/9/2008 2.79E-01 2.79E-01 6/10/2008 9.33E-01 9.33E-01 6/11/2008 8.18E-01 8.18E-01 6/12/2008 6.26E-01 6.26E-01 6/13/2008 9.00E-01 9.00E-01 6/14/2008 9.05E-01 9.05E-01 6/15/2008 4.90E-01 4.90E-01 6/16/2008 6.47E-01 6.47E-01 6/17/2008 9.51E-01 9.51E-01 6/18/2008 3.18E-01 3.18E-01 6/19/2008 5.83E-01 5.83E-01 6/20/2008 5.17E-01 5.17E-01 6/21/2008 3.83E-01 3.83E-01 6/22/2008 3.66E-01 3.66E-01 6/23/2008 4.24E-01 4.24E-01 6/24/2008 3.28E-01 3.28E-01 6/25/2008 1.02E-01 1.02E-01 6/26/2008 9.43E-01 9.43E-01 6/27/2008 5.39E-01 5.39E-01 6/28/2008 1.58E-01 1.58E-01 6/29/20082.94E+00 2.94E+00 6/30/2008 2.34E-01 2.34E-01 7/1/2008 2.04E-01 2.04E-01 7/2/2008 3.83E-01 3.83E-01 7/3/2008 1.88E-01 1.88E-01 7/4/2008 2.62E-01 2.62E-01 7/5/2008 3.68E-01 3.68E-01 7/6/2008 2.86E-01 2.86E-01 7/7/2008 3.08E-01 3.08E-01 7/8/20082.28E+00 2.28E+00 7/9/2008 3.80E-01 3.80E-01 7/10/2008 5.48E-01 5.48E-01 7/11/2008 7.72E-01 7.72E-01 7/12/20081.14E+00 1.14E+00 7/13/2008 3.38E-01 3.38E-01 7/14/2008 4.24E-01 4.24E-01 7/15/2008 3.45E-01 3.45E-01 7/16/2008 6.93E-01 6.93E-01 7/17/2008 6.18E-01 6.18E-01 7/18/20081.50E+00 1.50E+00 7/19/20082.01E+00 2.01E+00 7/20/2008 3.88E-01 3.88E-01 7/21/2008 4.48E-01 4.48E-01 7/22/2008 5.93E-01 5.93E-01 7/23/20081.38E+00 1.38E+00 7/24/2008 5.59E-01 5.59E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
7/25/2008 4.02E-01 4.02E-01 7/26/2008 6.26E-01 6.26E-01 7/27/2008 4.42E-01 4.42E-01 7/28/20081.73E+00 1.73E+00 7/29/20081.51E+00 1.51E+00 7/30/2008 3.82E-01 3.82E-01 7/31/2008 3.65E-01 3.65E-01 8/1/2008 3.13E-01 3.13E-01 8/2/2008 4.77E-01 4.77E-01 8/3/2008 4.82E-01 4.82E-01 8/4/2008 4.95E-01 4.95E-01 8/5/2008 7.43E-01 7.43E-01 8/6/2008 4.69E-01 4.69E-01 8/7/2008 8.93E-01 8.93E-01 8/8/2008 5.50E-01 5.50E-01 8/9/2008 8.13E-01 8.13E-01 8/10/2008 5.58E-01 5.58E-01 8/11/2008 6.02E-01 6.02E-01 8/12/2008 7.29E-01 7.29E-01 8/13/2008 5.12E-01 5.12E-01 8/14/2008 5.17E-01 5.17E-01 8/15/20081.03E+00 1.03E+00 8/16/2008 3.74E-01 3.74E-01 8/17/2008 6.10E-01 6.10E-01 8/18/2008 4.70E-01 4.70E-01 8/19/2008 3.25E-01 3.25E-01 8/20/2008 4.56E-01 4.56E-01 8/21/2008 3.46E-01 3.46E-01 8/22/2008 5.89E-01 5.89E-01 8/23/2008 6.73E-01 6.73E-01 8/24/20081.49E+00 1.49E+00 8/25/2008 5.53E-01 5.53E-01 8/26/2008 6.89E-01 6.89E-01 8/27/2008 3.36E-01 3.36E-01 8/28/2008 3.97E-01 3.97E-01 8/29/20081.12E+00 1.12E+00 8/30/2008 7.06E-01 7.06E-01 8/31/20081.12E+00 1.12E+00 9/1/2008 2.94E-01 2.94E-01 9/2/2008 6.33E-01 6.33E-01 9/3/2008 1.89E-01 1.89E-01 9/4/2008 4.40E-01 4.40E-01 9/5/2008 4.56E-01 4.56E-01 9/6/2008 5.88E-01 5.88E-01 9/7/2008 2.71E-01 2.71E-01 9/8/2008 1.68E-01 1.68E-01 9/9/2008 4.35E-01 4.35E-01 9/10/2008 3.00E-01 3.00E-01 9/11/2008 1.54E-01 1.54E-01 9/12/2008#DIV/0! 9/13/2008#DIV/0! 9/14/2008#DIV/0! 9/15/2008#DIV/0! 9/16/2008#DIV/0! 9/17/2008#DIV/0! 9/18/2008#DIV/0! 9/19/2008 5.40E-02 5.40E-02 9/20/2008 1.00E-02 1.00E-02 9/21/2008 5.44E-01 5.44E-01 9/22/20083.05E+00 3.05E+00 9/23/20081.28E+00 1.28E+00 9/24/20081.47E+00 1.47E+00 9/25/20082.39E+00 2.39E+00 9/26/20081.39E+00 1.39E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
9/27/20081.57E+00 1.57E+00 9/28/2008 6.11E-01 6.11E-01 9/29/2008 4.52E-01 4.52E-01 9/30/2008 4.25E-01 4.25E-01 10/1/2008 3.35E-01 3.35E-01 10/2/2008 2.50E-01 2.50E-01 10/3/2008 3.73E-01 3.73E-01 10/4/2008 3.76E-01 3.76E-01 10/5/2008 3.05E-01 3.05E-01 10/6/2008 2.12E-01 2.12E-01 10/7/2008 4.09E-01 4.09E-01 10/8/2008 2.16E-01 2.16E-01 10/9/2008 4.81E-01 4.81E-01 10/10/2008 4.97E-01 4.97E-01 10/11/2008 6.57E-01 6.57E-01 10/12/2008 4.02E-01 4.02E-01 10/13/2008 2.39E-01 2.39E-01 10/14/2008 6.33E-01 6.33E-01 10/15/20081.32E+00 1.32E+00 10/16/20082.89E+00 2.89E+00 10/17/20087.22E+00 7.22E+00 10/18/20085.17E+00 5.17E+00 10/19/20082.45E+00 2.45E+00 10/20/20082.35E+00 2.35E+00 10/21/2008 9.27E-01 9.27E-01 10/22/2008 8.02E-01 8.02E-01 10/23/2008 3.93E-01 3.93E-01 10/24/2008 5.85E-01 5.85E-01 10/25/2008 5.80E-01 5.80E-01 10/26/2008 4.41E-01 4.41E-01 10/27/2008 4.30E-01 4.30E-01 10/28/2008 2.46E-01 2.46E-01 10/29/2008 1.02E-01 1.02E-01 10/30/2008 2.38E-01 2.38E-01 10/31/2008 4.20E-01 4.20E-01 11/1/2008 2.23E-01 2.23E-01 11/2/2008 1.90E-01 1.90E-01 11/3/2008 3.43E-01 3.43E-01 11/4/2008 1.95E-01 1.95E-01 11/5/2008 8.50E-02 8.50E-02 11/6/2008 9.80E-02 9.80E-02 11/7/2008 1.47E-01 1.47E-01 11/8/2008 1.06E-01 1.06E-01 11/9/2008 1.18E-01 1.18E-01 11/10/2008 1.88E-01 1.88E-01 11/11/2008 4.73E-01 4.73E-01 11/12/2008 2.06E-01 2.06E-01 11/13/2008 2.83E-01 2.83E-01 11/14/2008 2.25E-01 2.25E-01 11/15/2008 2.78E-01 2.78E-01 11/16/2008 2.29E-01 2.29E-01 11/17/20081.24E+00 1.24E+00 11/18/2008 3.72E-01 3.72E-01 11/19/2008 3.94E-01 3.94E-01 11/20/2008 3.69E-01 3.69E-01 11/21/2008 3.76E-01 3.76E-01 11/22/2008 5.34E-01 5.34E-01 11/23/2008#DIV/0! 11/24/2008#DIV/0! 11/25/2008 1.00E-02 1.00E-02 11/26/2008 1.00E-02 1.00E-02 11/27/2008#DIV/0! 11/28/2008#DIV/0! 11/29/2008#DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
11/30/2008#DIV/0! 12/1/2008#DIV/0! 12/2/2008#DIV/0! 12/3/20081.59E+01 1.59E+01 12/4/2008 9.40E-02 9.40E-02 12/5/2008 2.45E-01 2.45E-01 12/6/2008 1.35E-01 1.35E-01 12/7/2008 2.29E-01 2.29E-01 12/8/2008 2.50E-01 2.50E-01 12/9/2008 1.13E-01 1.13E-01 12/10/2008 1.28E-01 1.28E-01 12/11/2008 7.00E-02 7.00E-02 12/12/2008 2.40E-02 2.40E-02 12/13/2008 1.72E-01 1.72E-01 12/14/2008 1.64E-01 1.64E-01 12/15/2008 3.12E-01 3.12E-01 12/16/2008 1.71E-01 1.71E-01 12/17/2008 1.24E-01 1.24E-01 12/18/2008 1.98E-01 1.98E-01 12/19/2008 2.33E-01 2.33E-01 12/20/20083.79E+00 3.79E+00 12/21/2008#DIV/0! 12/22/2008#DIV/0! 12/23/2008#DIV/0! 12/24/2008#DIV/0! 12/25/2008#DIV/0! 12/26/2008#DIV/0! 12/27/2008#DIV/0! 12/28/2008#DIV/0! 12/29/2008 2.40E-02 2.40E-02 12/30/2008 5.13E-01 5.13E-01 12/31/2008 1.30E-01 1.30E-01 1/1/2009 1.09E-01 1.09E-01 1/2/2009 2.92E-01 2.92E-01 1/3/2009 2.32E-01 2.32E-01 1/4/2009 1.28E-01 1.28E-01 1/5/2009 1.46E-01 1.46E-01 1/6/2009#DIV/0! 1/7/2009#DIV/0! 1/8/2009 1.04E-01 1.04E-01 1/9/2009 1.00E-01 1.00E-01 1/10/2009 4.21E-01 4.21E-01 1/11/2009 1.49E-01 1.49E-01 1/12/2009 1.53E-01 1.53E-01 1/13/2009 1.78E-01 1.78E-01 1/14/2009 9.30E-02 9.30E-02 1/15/2009 1.90E-01 1.90E-01 1/16/2009 4.22E-01 4.22E-01 1/17/2009 3.87E-01 3.87E-01 1/18/2009 5.36E-01 5.36E-01 1/19/2009 8.14E-01 8.14E-01 1/20/20091.11E+00 1.11E+00 1/21/2009 6.00E-01 6.00E-01 1/22/2009 1.83E-01 1.83E-01 1/23/2009 1.88E-01 1.88E-01 1/24/2009 2.09E-01 2.09E-01 1/25/2009 2.40E-01 2.40E-01 1/26/2009 1.40E-01 1.40E-01 1/27/2009 7.96E-01 7.96E-01 1/28/2009 4.51E-01 4.51E-01 1/29/2009 6.33E-01 6.33E-01 1/30/20094.36E+00 4.36E+00 1/31/2009#DIV/0! 2/1/20091.05E+00 1.05E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
2/2/20092.18E+00 2.18E+00 2/3/2009 6.39E-01 6.39E-01 2/4/20091.01E+00 1.01E+00 2/5/2009 2.60E-01 2.60E-01 2/6/2009 8.88E-01 8.88E-01 2/7/2009 5.71E-01 5.71E-01 2/8/20091.06E+00 1.06E+00 2/9/2009#DIV/0! 2/10/2009#DIV/0! 2/11/2009#DIV/0! 2/12/2009#DIV/0! 2/13/2009 1.50E-02 1.50E-02 2/14/20092.17E+00 2.17E+00 2/15/2009 9.18E-01 9.18E-01 2/16/2009 2.14E-01 2.14E-01 2/17/2009 3.69E-01 3.69E-01 2/18/2009 5.62E-01 5.62E-01 2/19/2009 7.09E-01 7.09E-01 2/20/2009 8.47E-01 8.47E-01 2/21/2009 6.93E-01 6.93E-01 2/22/20092.82E+00 2.82E+00 2/23/2009 2.70E-01 2.70E-01 2/24/2009 2.00E-01 2.00E-01 2/25/20093.33E+00 3.33E+00 2/26/20091.43E+00 1.43E+00 2/27/20091.66E+00 1.66E+00 2/28/20091.62E+00 1.62E+00 3/1/2009 4.95E-01 4.95E-01 3/2/2009 4.80E-01 4.80E-01 3/3/2009 5.07E-01 5.07E-01 3/4/20091.19E+00 1.19E+00 3/5/2009 4.28E-01 4.28E-01 3/6/2009 5.61E-01 5.61E-01 3/7/2009 4.81E-01 4.81E-01 3/8/20091.02E+00 1.02E+00 3/9/2009 5.57E-01 5.57E-01 3/10/20091.58E+00 1.58E+00 3/11/2009 5.88E-01 5.88E-01 3/12/2009 3.03E-01 3.03E-01 3/13/2009 2.68E-01 2.68E-01 3/14/2009 5.80E-02 5.80E-02 3/15/2009 4.01E-01 4.01E-01 3/16/2009 1.56E-01 1.56E-01 3/17/20093.95E+00 3.95E+00 3/18/2009 9.55E-01 9.55E-01 3/19/20092.89E+00 2.89E+00 3/20/20091.22E+00 1.22E+00 3/21/2009 7.01E-01 7.01E-01 3/22/2009 5.01E-01 5.01E-01 3/23/2009#DIV/0! 3/24/2009#DIV/0! 3/25/2009#DIV/0! 3/26/2009#DIV/0! 3/27/2009#DIV/0! 3/28/2009#DIV/0! 3/29/2009#DIV/0! 3/30/2009#DIV/0! 3/31/2009#DIV/0! 4/1/2009#DIV/0! 4/2/2009 2.70E-02 2.70E-02 4/3/2009 9.64E-01 9.64E-01 4/4/2009 3.44E-01 3.44E-01 4/5/2009 1.25E-01 1.25E-01 4/6/2009 2.50E-01 2.50E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
4/7/2009 1.75E-01 1.75E-01 4/8/2009 1.72E-01 1.72E-01 4/9/2009 6.78E-01 6.78E-01 4/10/2009 6.00E-02 6.00E-02 4/11/2009 6.12E-01 6.12E-01 4/12/2009 1.59E-01 1.59E-01 4/13/2009 3.86E-01 3.86E-01 4/14/20091.14E+00 1.14E+00 4/15/20091.32E+00 1.32E+00 4/16/20091.22E+00 1.22E+00 4/17/20092.22E+00 2.22E+00 4/18/20091.29E+00 1.29E+00 4/19/2009 6.90E-01 6.90E-01 4/20/2009#DIV/0! 4/21/2009#DIV/0! 4/22/2009#DIV/0! 4/23/2009#DIV/0! 4/24/2009#DIV/0! 4/25/2009 2.60E-02 2.60E-02 4/26/20091.22E+00 1.22E+00 4/27/20091.21E+00 1.21E+00 4/28/20091.11E+00 1.11E+00 4/29/2009 9.70E-01 9.70E-01 4/30/20091.35E+00 1.35E+00 5/1/20093.34E+00 3.34E+00 5/2/20095.30E+00 5.30E+00 5/3/20093.65E+00 3.65E+00 5/4/2009 3.67E-01 3.67E-01 5/5/2009 1.45E-01 1.45E-01 5/6/20091.80E+00 1.80E+00 5/7/20093.51E+00 3.51E+00 5/8/20091.93E+00 1.93E+00 5/9/2009 3.34E-01 3.34E-01 5/10/2009 2.60E-01 2.60E-01 5/11/20091.04E+00 1.04E+00 5/12/2009 2.57E-01 2.57E-01 5/13/2009 4.44E-01 4.44E-01 5/14/2009 5.60E-01 5.60E-01 5/15/2009 3.25E-01 3.25E-01 5/16/2009 2.83E-01 2.83E-01 5/17/2009 4.55E-01 4.55E-01 5/18/2009 3.05E-01 3.05E-01 5/19/2009 4.77E-01 4.77E-01 5/20/2009 4.86E-01 4.86E-01 5/21/2009 3.81E-01 3.81E-01 5/22/2009 2.25E-01 2.25E-01 5/23/2009 5.63E-01 5.63E-01 5/24/20091.40E+00 1.40E+00 5/25/2009 6.95E-01 6.95E-01 5/26/2009 5.01E-01 5.01E-01 5/27/2009 3.97E-01 3.97E-01 5/28/2009 5.07E-01 5.07E-01 5/29/2009 7.11E-01 7.11E-01 5/30/2009 6.21E-01 6.21E-01 5/31/2009 4.91E-01 4.91E-01 6/1/20091.25E+00 1.25E+00 6/2/20092.75E+00 2.75E+00 6/3/2009 7.97E-01 7.97E-01 6/4/2009 2.37E-01 2.37E-01 6/5/2009 4.61E-01 4.61E-01 6/6/2009 3.34E-01 3.34E-01 6/7/2009 5.29E-01 5.29E-01 6/8/2009 2.11E-01 2.11E-01 6/9/2009 2.02E-01 2.02E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
6/10/2009 4.71E-01 4.71E-01 6/11/2009 6.38E-01 6.38E-01 6/12/2009 2.97E-01 2.97E-01 6/13/2009 2.00E-01 2.00E-01 6/14/2009 2.82E-01 2.82E-01 6/15/2009 3.00E-01 3.00E-01 6/16/2009#DIV/0! 6/17/2009#DIV/0! 6/18/2009#DIV/0! 6/19/2009#DIV/0! 6/20/2009#DIV/0! 6/21/2009#DIV/0! 6/22/2009#DIV/0! 6/23/2009#DIV/0! 6/24/2009#DIV/0! 6/25/2009 4.20E-01 4.20E-01 6/26/2009 1.73E-01 1.73E-01 6/27/2009 5.33E-01 5.33E-01 6/28/2009 5.36E-01 5.36E-01 6/29/2009 1.92E-01 1.92E-01 6/30/20091.20E+00 1.20E+00 7/1/2009 1.59E-01 1.59E-01 7/2/2009 2.53E-01 2.53E-01 7/3/2009 2.04E-01 2.04E-01 7/4/2009 1.67E-01 1.67E-01 7/5/2009 6.44E-01 6.44E-01 7/6/2009 5.30E-02 5.30E-02 7/7/2009 2.13E-01 2.13E-01 7/8/2009 2.73E-01 2.73E-01 7/9/2009 2.27E-01 2.27E-01 7/10/2009 4.26E-01 4.26E-01 7/11/2009 3.25E-01 3.25E-01 7/12/2009 2.40E-01 2.40E-01 7/13/2009 2.61E-01 2.61E-01 7/14/2009 2.53E-01 2.53E-01 7/15/2009 1.35E-01 1.35E-01 7/16/2009 1.38E-01 1.38E-01 7/17/2009 8.47E-01 8.47E-01 7/18/2009 2.58E-01 2.58E-01 7/19/2009 2.48E-01 2.48E-01 7/20/2009 3.76E-01 3.76E-01 7/21/2009 2.91E-01 2.91E-01 7/22/2009 2.75E-01 2.75E-01 7/23/2009 3.66E-01 3.66E-01 7/24/2009 2.94E-01 2.94E-01 7/25/2009 7.62E-01 7.62E-01 7/26/2009 3.72E-01 3.72E-01 7/27/2009 5.22E-01 5.22E-01 7/28/2009 4.11E-01 4.11E-01 7/29/2009 5.53E-01 5.53E-01 7/30/2009 5.82E-01 5.82E-01 7/31/20091.04E+00 1.04E+00 8/1/2009 6.04E-01 6.04E-01 8/2/2009 3.56E-01 3.56E-01 8/3/2009 2.94E-01 2.94E-01 8/4/2009 3.50E-01 3.50E-01 8/5/2009 5.78E-01 5.78E-01 8/6/20092.71E+01 2.71E+01 8/7/20094.58E+00 4.58E+00 8/8/2009 7.17E-01 7.17E-01 8/9/20096.26E+00 6.26E+00 8/10/2009 9.42E-01 9.42E-01 8/11/2009#DIV/0! 8/12/2009#DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
8/13/2009#DIV/0! 8/14/2009 1.73E-01 1.73E-01 8/15/2009 7.38E-01 7.38E-01 8/16/20098.98E+00 8.98E+00 8/17/20091.54E+00 1.54E+00 8/18/20091.63E+00 1.63E+00 8/19/20093.35E+00 3.35E+00 8/20/20091.15E+00 1.15E+00 8/21/2009 9.48E-01 9.48E-01 8/22/20091.14E+00 1.14E+00 8/23/20091.51E+00 1.51E+00 8/24/20091.67E+00 1.67E+00 8/25/20091.05E+01 1.05E+01 8/26/20096.37E+00 6.37E+00 8/27/20091.39E+00 1.39E+00 8/28/2009 3.23E-01 3.23E-01 8/29/2009 2.90E-01 2.90E-01 8/30/2009 3.96E-01 3.96E-01 8/31/2009 3.82E-01 3.82E-01 9/1/2009 6.90E-01 6.90E-01 9/2/2009 4.66E-01 4.66E-01 9/3/20091.93E+00 1.93E+00 9/4/20091.79E+00 1.79E+00 9/5/2009 6.20E-01 6.20E-01 9/6/20092.50E+00 2.50E+00 9/7/2009 5.25E-01 5.25E-01 9/8/20091.39E+00 1.39E+00 9/9/20091.25E+00 1.25E+00 9/10/20091.01E+00 1.01E+00 9/11/2009 5.11E-01 5.11E-01 9/12/2009 3.21E-01 3.21E-01 9/13/2009 2.93E-01 2.93E-01 9/14/2009 6.02E-01 6.02E-01 9/15/2009 4.21E-01 4.21E-01 9/16/2009 5.76E-01 5.76E-01 9/17/2009 5.49E-01 5.49E-01 9/18/2009 4.25E-01 4.25E-01 9/19/2009 1.83E-01 1.83E-01 9/20/2009 3.81E-01 3.81E-01 9/21/2009#DIV/0! 9/22/2009 1.00E-02 1.00E-02 9/23/2009 1.00E-02 1.00E-02 9/24/2009#DIV/0! 9/25/2009 8.80E-02 8.80E-02 9/26/2009 1.45E-01 1.45E-01 9/27/2009 1.60E-01 1.60E-01 9/28/20091.37E+00 1.37E+00 9/29/2009 2.90E-01 2.90E-01 9/30/2009 1.51E-01 1.51E-01 10/1/20099.80E+00 9.80E+00 10/2/2009 7.40E-01 7.40E-01 10/3/20091.34E+00 1.34E+00 10/4/20093.76E+00 3.76E+00 10/5/2009 2.42E-01 2.42E-01 10/6/2009 3.22E-01 3.22E-01 10/7/2009 5.25E-01 5.25E-01 10/8/2009 6.93E-01 6.93E-01 10/9/2009 6.32E-01 6.32E-01 10/10/2009 2.47E-01 2.47E-01 10/11/2009 9.24E-01 9.24E-01 10/12/2009 2.33E-01 2.33E-01 10/13/2009 1.91E-01 1.91E-01 10/14/2009 2.60E-01 2.60E-01 10/15/2009 2.53E-01 2.53E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
10/16/2009 2.49E-01 2.49E-01 10/17/2009 7.69E-01 7.69E-01 10/18/2009 2.43E-01 2.43E-01 10/19/2009 2.94E-01 2.94E-01 10/20/2009 2.35E-01 2.35E-01 10/21/2009 9.70E-01 9.70E-01 10/22/20091.22E+00 1.22E+00 10/23/2009 5.48E-01 5.48E-01 10/24/2009 7.19E-01 7.19E-01 10/25/20091.45E+00 1.45E+00 10/26/2009 5.62E-01 5.62E-01 10/27/2009 3.85E-01 3.85E-01 10/28/2009 3.69E-01 3.69E-01 10/29/2009 8.70E-02 8.70E-02 10/30/2009 6.24E-01 6.24E-01 10/31/2009#DIV/0! 11/1/2009#DIV/0! 11/2/2009#DIV/0! 11/3/2009#DIV/0! 11/4/2009#DIV/0! 11/5/2009#DIV/0! 11/6/2009#DIV/0! 11/7/2009#DIV/0! 11/8/2009#DIV/0! 11/9/2009#DIV/0! 11/10/2009#DIV/0! 11/11/2009#DIV/0! 11/12/2009#DIV/0! 11/13/2009#DIV/0! 11/14/2009#DIV/0! 11/15/2009#DIV/0! 11/16/2009 1.00E-02 1.00E-02 11/17/2009 2.90E-02 2.90E-02 11/18/2009 1.27E-01 1.27E-01 11/19/2009 8.60E-02 8.60E-02 11/20/2009 1.17E-01 1.17E-01 11/21/2009 2.82E-01 2.82E-01 11/22/2009 2.19E-01 2.19E-01 11/23/2009 2.66E-01 2.66E-01 11/24/2009 1.44E-01 1.44E-01 11/25/2009 1.96E-01 1.96E-01 11/26/2009 1.38E-01 1.38E-01 11/27/2009 1.39E-01 1.39E-01 11/28/2009 1.60E-01 1.60E-01 11/29/2009 3.34E-01 3.34E-01 11/30/2009 1.24E-01 1.24E-01 12/1/2009 1.50E-01 1.50E-01 12/2/2009 1.13E-01 1.13E-01 12/3/2009 1.76E-01 1.76E-01 12/4/2009 5.20E-01 5.20E-01 12/5/20091.40E+00 1.40E+00 12/6/2009 1.78E-01 1.78E-01 12/7/2009 2.35E-01 2.35E-01 12/8/2009 5.90E-01 5.90E-01 12/9/20091.76E+00 1.76E+00 12/10/20091.01E+00 1.01E+00 12/11/2009 1.29E-01 1.29E-01 12/12/20091.36E+00 1.36E+00 12/13/2009 2.94E-01 2.94E-01 12/14/20092.70E+00 2.70E+00 12/15/2009 3.04E-01 3.04E-01 12/16/2009 6.04E-01 6.04E-01 12/17/20091.87E+00 1.87E+00 12/18/20091.18E+00 1.18E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
12/19/20091.63E+00 1.63E+00 12/20/2009#DIV/0! 12/21/2009#DIV/0! 12/22/2009#DIV/0! 12/23/2009#DIV/0! 12/24/2009#DIV/0! 12/25/2009#DIV/0! 12/26/2009#DIV/0! 12/27/2009#DIV/0! 12/28/2009#DIV/0! 12/29/2009#DIV/0! 12/30/2009#DIV/0! 12/31/2009#DIV/0! 1/1/2010#DIV/0! 1/2/2010#DIV/0! 1/3/2010#DIV/0! 1/4/2010#DIV/0! 1/5/2010 6.80E-02 6.80E-02 1/6/2010 2.51E-01 2.51E-01 1/7/2010 8.80E-02 8.80E-02 1/8/2010 6.70E-02 6.70E-02 1/9/2010 1.10E-02 1.10E-02 1/10/2010 1.00E-02 1.00E-02 1/11/2010 1.00E-02 1.00E-02 1/12/2010 1.00E-02 1.00E-02 1/13/2010 1.00E-02 1.00E-02 1/14/2010 1.55E-01 1.55E-01 1/15/2010 1.11E-01 1.11E-01 1/16/2010 1.05E-01 1.05E-01 1/17/2010 2.13E-01 2.13E-01 1/18/2010 1.69E-01 1.69E-01 1/19/2010 9.70E-02 9.70E-02 1/20/2010 1.92E-01 1.92E-01 1/21/2010 2.87E-01 2.87E-01 1/22/2010 3.45E-01 3.45E-01 1/23/2010 3.22E-01 3.22E-01 1/24/2010 3.24E-01 3.24E-01 1/25/2010 2.12E-01 2.12E-01 1/26/2010 7.00E-02 7.00E-02 1/27/2010 2.18E-01 2.18E-01 1/28/2010 2.64E-01 2.64E-01 1/29/2010 3.07E-01 3.07E-01 1/30/20104.93E+01 4.93E+01 1/31/2010 3.92E-01 3.92E-01 2/1/2010 1.41E-01 1.41E-01 2/2/2010 4.68E-01 4.68E-01 2/3/2010 1.86E-01 1.86E-01 2/4/2010 5.66E-01 5.66E-01 2/5/20101.01E+00 1.01E+00 2/6/2010 6.79E-01 6.79E-01 2/7/2010 8.98E-01 8.98E-01 2/8/20103.18E+00 3.18E+00 2/9/20101.60E+00 1.60E+00 2/10/2010 1.76E-01 1.76E-01 2/11/2010 2.45E-01 2.45E-01 2/12/2010 2.26E-01 2.26E-01 2/13/2010 3.22E-01 3.22E-01 2/14/2010 3.69E-01 3.69E-01 2/15/2010 4.83E-01 4.83E-01 2/16/2010 4.16E-01 4.16E-01 2/17/2010 4.23E-01 4.23E-01 2/18/2010 1.52E-01 1.52E-01 2/19/2010 8.30E-02 8.30E-02 2/20/2010 1.32E-01 1.32E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
2/21/2010 1.56E-01 1.56E-01 2/22/2010 2.38E-01 2.38E-01 2/23/2010 6.49E-01 6.49E-01 2/24/2010 1.29E-01 1.29E-01 2/25/2010 1.00E-01 1.00E-01 2/26/2010 9.10E-02 9.10E-02 2/27/2010 1.19E-01 1.19E-01 2/28/2010 1.33E-01 1.33E-01 3/1/2010 1.80E-01 1.80E-01 3/2/2010 1.76E-01 1.76E-01 3/3/2010 4.48E-01 4.48E-01 3/4/20101.24E+00 1.24E+00 3/5/20101.13E+00 1.13E+00 3/6/20101.25E+00 1.25E+00 3/7/20101.52E+00 1.52E+00 3/8/2010 3.47E-01 3.47E-01 3/9/2010 1.06E-01 1.06E-01 3/10/2010 2.78E-01 2.78E-01 3/11/2010 1.32E-01 1.32E-01 3/12/20107.74E+00 7.74E+00 3/13/20101.57E+01 1.57E+01 3/14/2010 8.28E-01 8.28E-01 3/15/2010 4.52E-01 4.52E-01 3/16/2010 1.12E-01 1.12E-01 3/17/2010 4.09E-01 4.09E-01 3/18/2010 1.70E-01 1.70E-01 3/19/2010 1.56E-01 1.56E-01 3/20/2010 2.54E-01 2.54E-01 3/21/2010 1.36E-01 1.36E-01 3/22/2010 1.12E-01 1.12E-01 3/23/2010 7.90E-02 7.90E-02 3/24/2010 1.72E-01 1.72E-01 3/25/2010 2.46E-01 2.46E-01 3/26/2010 5.21E-01 5.21E-01 3/27/2010 1.46E-01 1.46E-01 3/28/2010 1.96E-01 1.96E-01 3/29/2010 3.10E-01 3.10E-01 3/30/2010 4.49E-01 4.49E-01 3/31/2010 3.54E-01 3.54E-01 4/1/2010 5.07E-01 5.07E-01 4/2/2010 5.13E-01 5.13E-01 4/3/2010 7.02E-01 7.02E-01 4/4/2010 5.11E-01 5.11E-01 4/5/2010 4.27E-01 4.27E-01 4/6/2010 1.53E-01 1.53E-01 4/7/2010 1.36E-01 1.36E-01 4/8/2010 1.91E-01 1.91E-01 4/9/2010 2.19E-01 2.19E-01 4/10/2010 3.05E-01 3.05E-01 4/11/2010 2.32E-01 2.32E-01 4/12/2010 3.38E-01 3.38E-01 4/13/2010 1.35E-01 1.35E-01 4/14/2010 2.02E-01 2.02E-01 4/15/2010 1.18E-01 1.18E-01 4/16/2010 1.87E-01 1.87E-01 4/17/2010 2.30E-01 2.30E-01 4/18/2010 2.07E-01 2.07E-01 4/19/2010 1.58E-01 1.58E-01 4/20/2010 1.77E-01 1.77E-01 4/21/2010 1.17E-01 1.17E-01 4/22/2010 2.25E-01 2.25E-01 4/23/20101.21E+00 1.21E+00 4/24/20102.07E+00 2.07E+00 4/25/20102.20E+00 2.20E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
4/26/2010#DIV/0! 4/27/2010#DIV/0! 4/28/2010#DIV/0! 4/29/2010#DIV/0! 4/30/2010#DIV/0! 5/1/2010 1.68E-01 1.68E-01 5/2/2010 4.09E-01 4.09E-01 5/3/2010 3.72E-01 3.72E-01 5/4/2010 3.32E-01 3.32E-01 5/5/2010 2.05E-01 2.05E-01 5/6/2010 1.99E-01 1.99E-01 5/7/2010 2.10E-01 2.10E-01 5/8/2010 8.20E-02 8.20E-02 5/9/2010 1.71E-01 1.71E-01 5/10/2010 1.27E-01 1.27E-01 5/11/2010 1.91E-01 1.91E-01 5/12/2010 1.01E-01 1.01E-01 5/13/2010 8.40E-02 8.40E-02 5/14/2010 8.30E-02 8.30E-02 5/15/2010 1.07E-01 1.07E-01 5/16/2010 1.42E-01 1.42E-01 5/17/2010 1.94E-01 1.94E-01 5/18/2010 4.01E-01 4.01E-01 5/19/2010 1.82E-01 1.82E-01 5/20/2010 5.35E-01 5.35E-01 5/21/2010 7.28E-01 7.28E-01 5/22/2010 3.74E-01 3.74E-01 5/23/2010 6.14E-01 6.14E-01 5/24/2010 6.73E-01 6.73E-01 5/25/20101.79E+01 1.79E+01 5/26/2010 2.11E-01 2.11E-01 5/27/2010 2.64E-01 2.64E-01 5/28/2010 2.17E-01 2.17E-01 5/29/2010 6.46E-01 6.46E-01 5/30/2010 1.23E-01 1.23E-01 5/31/2010 1.48E-01 1.48E-01 6/1/2010 1.54E-01 1.54E-01 6/2/2010 8.10E-02 8.10E-02 6/3/2010 1.66E-01 1.66E-01 6/4/2010 3.73E-01 3.73E-01 6/5/2010 5.09E-01 5.09E-01 6/6/2010 1.27E-01 1.27E-01 6/7/2010 1.52E-01 1.52E-01 6/8/2010 1.45E-01 1.45E-01 6/9/2010 5.20E-02 5.20E-02 6/10/2010 1.14E-01 1.14E-01 6/11/2010 1.18E-01 1.18E-01 6/12/2010 8.50E-02 8.50E-02 6/13/2010 1.20E-01 1.20E-01 6/14/2010 1.01E-01 1.01E-01 6/15/2010 1.26E-01 1.26E-01 6/16/2010 1.60E-01 1.60E-01 6/17/2010 3.57E-01 3.57E-01 6/18/2010 6.35E-01 6.35E-01 6/19/2010 8.70E-01 8.70E-01 6/20/20103.10E+00 3.10E+00 6/21/20101.76E+00 1.76E+00 6/22/2010 4.21E-01 4.21E-01 6/23/2010 3.05E-01 3.05E-01 6/24/2010 3.03E-01 3.03E-01 6/25/2010 6.08E-01 6.08E-01 6/26/2010 9.32E-01 9.32E-01 6/27/20101.51E+00 1.51E+00 6/28/2010 1.33E-01 1.33E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
6/29/2010 1.01E-01 1.01E-01 6/30/2010 1.13E-01 1.13E-01 7/1/2010 2.03E-01 2.03E-01 7/2/2010 5.40E-02 5.40E-02 7/3/2010 6.90E-02 6.90E-02 7/4/2010 8.60E-02 8.60E-02 7/5/2010 1.18E-01 1.18E-01 7/6/2010 3.74E-01 3.74E-01 7/7/2010 1.20E-01 1.20E-01 7/8/2010 2.98E-01 2.98E-01 7/9/2010 1.28E-01 1.28E-01 7/10/2010 1.84E-01 1.84E-01 7/11/2010 1.37E-01 1.37E-01 7/12/2010 2.69E-01 2.69E-01 7/13/2010 2.37E-01 2.37E-01 7/14/2010 2.82E-01 2.82E-01 7/15/2010 3.47E-01 3.47E-01 7/16/2010 3.76E-01 3.76E-01 7/17/2010 3.34E-01 3.34E-01 7/18/2010 3.01E-01 3.01E-01 7/19/2010 2.98E-01 2.98E-01 7/20/2010 1.36E-01 1.36E-01 7/21/2010 1.20E-01 1.20E-01 7/22/2010 2.17E-01 2.17E-01 7/23/2010 2.29E-01 2.29E-01 7/24/2010 2.10E-01 2.10E-01 7/25/2010 2.28E-01 2.28E-01 7/26/20102.98E+00 2.98E+00 7/27/2010 2.42E-01 2.42E-01 7/28/2010 2.57E-01 2.57E-01 7/29/2010 2.29E-01 2.29E-01 7/30/2010 2.73E-01 2.73E-01 7/31/2010 2.79E-01 2.79E-01 8/1/2010 3.41E-01 3.41E-01 8/2/2010 2.95E-01 2.95E-01 8/3/20101.36E+00 1.36E+00 8/4/2010 9.56E-01 9.56E-01 8/5/2010 4.10E-01 4.10E-01 8/6/2010 7.03E-01 7.03E-01 8/7/2010 3.81E-01 3.81E-01 8/8/2010 6.37E-01 6.37E-01 8/9/2010 2.99E-01 2.99E-01 8/10/2010 9.75E-01 9.75E-01 8/11/2010 6.21E-01 6.21E-01 8/12/20101.12E+00 1.12E+00 8/13/20101.13E+00 1.13E+00 8/14/20101.40E+00 1.40E+00 8/15/2010 6.61E-01 6.61E-01 8/16/2010 3.02E-01 3.02E-01 8/17/2010 4.63E-01 4.63E-01 8/18/2010 1.45E-01 1.45E-01 8/19/2010 1.59E-01 1.59E-01 8/20/2010 7.38E-01 7.38E-01 8/21/2010 5.85E-01 5.85E-01 8/22/20101.04E+00 1.04E+00 8/23/20102.11E+00 2.11E+00 8/24/20101.39E+00 1.39E+00 8/25/20101.98E+00 1.98E+00 8/26/20103.03E+00 3.03E+00 8/27/20101.27E+00 1.27E+00 8/28/20101.05E+00 1.05E+00 8/29/20102.28E+00 2.28E+00 8/30/2010 3.46E-01 3.46E-01 8/31/2010 8.00E-01 8.00E-01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
9/1/2010 2.53E-01 2.53E-01 9/2/2010 2.70E-01 2.70E-01 9/3/2010 2.11E-01 2.11E-01 9/4/2010 2.20E-01 2.20E-01 9/5/2010 2.52E-01 2.52E-01 9/6/2010 5.02E-01 5.02E-01 9/7/20101.31E+00 1.31E+00 9/8/20106.00E+00 6.00E+00 9/9/20101.66E+00 1.66E+00 9/10/20101.09E+00 1.09E+00 9/11/20101.90E+00 1.90E+00 9/12/20101.80E+00 1.80E+00 9/13/20101.96E+00 1.96E+00 9/14/20104.05E+00 4.05E+00 9/15/20103.31E+00 3.31E+00 9/16/2010 2.75E-01 2.75E-01 9/17/2010 3.15E-01 3.15E-01 9/18/2010 2.41E-01 2.41E-01 9/19/2010 2.64E-01 2.64E-01 9/20/2010 2.00E-01 2.00E-01 9/21/2010 6.49E-01 6.49E-01 9/22/2010 4.30E-01 4.30E-01 9/23/2010 2.49E-01 2.49E-01 9/24/2010 2.90E-01 2.90E-01 9/25/2010 5.73E-01 5.73E-01 9/26/2010 5.71E-01 5.71E-01 9/27/2010 4.71E-01 4.71E-01 9/28/2010 2.38E-01 2.38E-01 9/29/2010 2.14E-01 2.14E-01 9/30/2010 2.71E-01 2.71E-01 10/1/2010 8.00E-02 8.00E-02 10/2/2010 9.30E-02 9.30E-02 10/3/2010 9.40E-02 9.40E-02 10/4/2010 1.82E-01 1.82E-01 10/5/2010 1.33E-01 1.33E-01 10/6/2010 3.36E-01 3.36E-01 10/7/2010 8.52E-01 8.52E-01 10/8/2010 3.37E-01 3.37E-01 10/9/2010 4.02E-01 4.02E-01 10/10/20101.07E+00 1.07E+00 10/11/2010 5.01E-01 5.01E-01 10/12/2010 2.43E-01 2.43E-01 10/13/2010 2.55E-01 2.55E-01 10/14/2010 3.53E-01 3.53E-01 10/15/2010 1.98E-01 1.98E-01 10/16/2010 3.43E-01 3.43E-01 10/17/2010 3.16E-01 3.16E-01 10/18/2010 8.30E-02 8.30E-02 10/19/2010 8.24E-01 8.24E-01 10/20/2010 6.29E-01 6.29E-01 10/21/2010 4.69E-01 4.69E-01 10/22/20101.29E+00 1.29E+00 10/23/2010 5.89E-01 5.89E-01 10/24/2010 9.68E-01 9.68E-01 10/25/2010 9.11E-01 9.11E-01 10/26/20103.30E+00 3.30E+00 10/27/20101.27E+01 1.27E+01 10/28/20101.97E+00 1.97E+00 10/29/20108.30E+00 8.30E+00 10/30/2010 2.97E-01 2.97E-01 10/31/2010 3.12E-01 3.12E-01 11/1/2010 2.68E-01 2.68E-01 11/2/2010 3.45E-01 3.45E-01 11/3/20101.52E+00 1.52E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# Resins - Suspension - Existing A**rea Sources - VC**
11/4/2010 2.38E-01 2.38E-01 11/5/20101.59E+00 1.59E+00 11/6/20102.08E+00 2.08E+00 11/7/20101.24E+00 1.24E+00 11/8/20101.21E+00 1.21E+00 11/9/2010 2.86E-01 2.86E-01 11/10/20101.47E+00 1.47E+00 11/11/2010 6.62E-01 6.62E-01 11/12/2010 9.34E-01 9.34E-01 11/13/2010 8.46E-01 8.46E-01 11/14/20101.81E+00 1.81E+00 11/15/2010#DIV/0! 11/16/2010 1.33E-01 1.33E-01 11/17/20101.31E+00 1.31E+00 11/18/2010 4.23E-01 4.23E-01 11/19/2010 8.12E-01 8.12E-01 11/20/2010 3.85E-01 3.85E-01 11/21/20102.44E+00 2.44E+00 11/22/2010 5.77E-01 5.77E-01 11/23/2010 2.38E-01 2.38E-01 11/24/2010 1.76E-01 1.76E-01 11/25/2010 2.65E-01 2.65E-01 11/26/2010 2.44E-01 2.44E-01 11/27/2010 4.05E-01 4.05E-01 11/28/2010 6.76E-01 6.76E-01 11/29/20101.04E+00 1.04E+00 11/30/2010 2.54E-01 2.54E-01 12/1/2010 3.77E-01 3.77E-01 12/2/2010 1.83E-01 1.83E-01 12/3/2010 1.76E-01 1.76E-01 12/4/2010 2.79E-01 2.79E-01 12/5/2010 3.62E-01 3.62E-01 12/6/2010 7.81E-01 7.81E-01 12/7/2010 5.89E-01 5.89E-01 12/8/2010 8.79E-01 8.79E-01 12/9/20101.17E+00 1.17E+00 12/10/20102.25E+00 2.25E+00 12/11/2010 4.16E-01 4.16E-01 12/12/2010 3.62E-01 3.62E-01 12/13/2010 3.20E-01 3.20E-01 12/14/2010#DIV/0! 12/15/2010#DIV/0! 12/16/20102.44E+00 2.44E+00 12/17/2010 5.16E-01 5.16E-01 12/18/20101.33E+00 1.33E+00 12/19/2010 1.09E-01 1.09E-01 12/20/2010 1.45E-01 1.45E-01 12/21/2010 2.13E-01 2.13E-01 12/22/2010 2.02E-01 2.02E-01 12/23/2010 3.10E-01 3.10E-01 12/24/2010 3.55E-01 3.55E-01 12/25/2010#DIV/0! 12/26/2010#DIV/0! 12/27/2010#DIV/0! 12/28/2010#DIV/0! 12/29/2010#DIV/0! 12/30/2010 1.50E-02 1.50E-02 12/31/2010#DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**New**

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Suspension - Existing Area Sources - Total Non-VC HAP**

Method Method 8260B Resin Type Suspension HAP (0=no, 1=yes) 1

Average of Wet Resin from Stripper Bottoms, ppm Analyte_Std
Reporting Plant Sample Date BDL (0=no, 1=yes) 2,2,4- Trimethylpentane Acetaldehyde Acetophenone Benzene Chloroform Cumene Ethyl Chloride Ethylene Dichloride Ethylidene

Dichloride Formaldehyde Hydroquinone Methanol Methyl Chloride Toluene Vinylidene Chloride Xylenes (Mixed

Isomers) Oxy DP 12/1/2009 0 2.99E+00 1.16E+00
1 1.15E-01 3.60E-01 5.00E-02 4.70E-02 7.60E-02 1.45E-01 5.10E-02 2.05E-02 2.35E-01 4.45E+00 9.70E-02 2.45E-02 4.30E-02 9.75E-02 6.90E-02 12/1/2009 Total 1.15E-01 2.99E+00 3.60E-01 5.00E-02 4.70E-02 7.60E-02 1.45E-01 5.10E-02 2.05E-02 2.35E-01 4.45E+00 6.29E-01 2.45E-02 4.30E-02 9.75E-02 6.90E-02 12/2/2009 0 2.33E+00 5.99E-01
1 1.15E-01 3.05E-01 4.90E-02 4.55E-02 7.45E-02 1.40E-01 4.95E-02 2.00E-02 2.00E-01 3.75E+00 2.40E-02 4.20E-02 9.55E-02 6.75E-02 12/2/2009 Total 1.15E-01 2.33E+00 3.05E-01 4.90E-02 4.55E-02 7.45E-02 1.40E-01 4.95E-02 2.00E-02 2.00E-01 3.75E+00 5.99E-01 2.40E-02 4.20E-02 9.55E-02 6.75E-02 12/3/2009 0 7.77E-01 7.35E-01 1.25E+00
1 1.20E-01 2.85E-01 5.15E-02 4.85E-02 7.85E-02 1.50E-01 5.20E-02 2.10E-02 1.90E-01 3.50E+00 1.00E-01 2.50E-02 4.45E-02 1.03E-01 7.10E-02 12/3/2009 Total 1.20E-01 7.77E-01 2.85E-01 5.15E-02 4.85E-02 7.85E-02 1.50E-01 5.20E-02 2.10E-02 4.63E-01 3.50E+00 6.75E-01 2.50E-02 4.45E-02 1.03E-01 7.10E-02 12/4/2009 0 2.97E-01 5.76E+00 5.34E-01 1.08E-01 9.35E-02
1 1.10E-01 2.70E-01 4.85E-02 4.55E-02 7.35E-02 1.40E-01 4.90E-02 2.00E-02 1.75E-01 3.30E+00 9.05E-02 2.35E-02 4.15E-02 9.45E-02 6.65E-02 12/4/2009 Total 1.10E-01 2.97E-01 3.02E+00 4.85E-02 4.55E-02 7.35E-02 3.37E-01 7.85E-02 5.68E-02 1.75E-01 3.30E+00 9.05E-02 2.35E-02 4.15E-02 9.45E-02 6.65E-02 12/5/2009 0 6.69E-01 5.01E+00 6.27E-02 1.67E+00 2.71E-01 2.52E-01 4.45E-01 6.73E-01
1 1.05E-01 2.70E-01 4.65E-02 4.50E-02 7.05E-02 1.40E-01 4.90E-02 1.90E-02 3.15E+00 8.90E-02 2.25E-02 3.95E-02 9.00E-02 6.35E-02 12/5/2009 Total 1.05E-01 6.69E-01 2.64E+00 4.65E-02 5.39E-02 7.05E-02 9.05E-01 1.60E-01 1.36E-01 4.45E-01 3.15E+00 3.81E-01 2.25E-02 3.95E-02 9.00E-02 6.35E-02 12/6/2009 0 5.47E-01 4.08E+00 2.58E-01 1.04E-01 8.66E-02 4.05E-01 4.26E-01
1 1.10E-01 2.70E-01 4.70E-02 4.40E-02 7.20E-02 1.50E-01 5.20E-02 2.10E-02 3.05E+00 9.90E-02 2.30E-02 4.05E-02 9.20E-02 6.55E-02 12/6/2009 Total 1.10E-01 5.47E-01 2.18E+00 4.70E-02 4.40E-02 7.20E-02 2.04E-01 7.80E-02 5.38E-02 4.05E-01 3.05E+00 2.63E-01 2.30E-02 4.05E-02 9.20E-02 6.55E-02 12/7/2009 0 2.14E-01 5.11E+00 1.53E-01 5.32E-02 5.65E-02 3.15E-01
1 1.10E-01 2.60E-01 4.70E-02 4.40E-02 7.15E-02 1.40E-01 5.00E-02 2.00E-02 3.05E+00 9.20E-02 2.30E-02 4.00E-02 9.15E-02 6.50E-02 12/7/2009 Total 1.10E-01 2.14E-01 2.69E+00 4.70E-02 4.40E-02 7.15E-02 1.47E-01 5.16E-02 3.83E-02 3.15E-01 3.05E+00 9.20E-02 2.30E-02 4.00E-02 9.15E-02 6.50E-02 12/8/2009 0 2.71E-01 4.63E+00 3.99E-01 1.31E-01 9.69E-02 3.87E-01 7.91E-01
1 1.10E-01 2.80E-01 4.75E-02 4.45E-02 7.25E-02 1.50E-01 5.20E-02 2.10E-02 1.80E-01 3.15E+00 9.30E-02 2.30E-02 4.10E-02 9.25E-02 6.55E-02 12/8/2009 Total 1.10E-01 2.71E-01 2.46E+00 4.75E-02 4.45E-02 7.25E-02 2.75E-01 9.15E-02 5.90E-02 2.84E-01 3.15E+00 4.42E-01 2.30E-02 4.10E-02 9.25E-02 6.55E-02 12/9/2009 0 2.85E-01 4.21E+00 3.46E-01 6.85E-02 3.54E-02 3.80E-01 1.07E+00 1 1.04E-01 2.60E-01 4.40E-02 4.10E-02 6.65E-02 1.30E-01 4.60E-02 1.90E-02 3.05E+00 8.60E-02 2.10E-02 3.75E-02 8.50E-02 6.00E-02 12/9/2009 Total 1.04E-01 2.85E-01 2.24E+00 4.40E-02 4.10E-02 6.65E-02 2.38E-01 5.73E-02 2.72E-02 3.80E-01 3.05E+00 5.78E-01 2.10E-02 3.75E-02 8.50E-02 6.00E-02 12/10/2009 0 3.72E+00 3.97E-01 8.22E-01
1 1.00E-01 6.30E-02 2.40E-01 4.45E-02 4.15E-02 6.70E-02 1.30E-01 4.45E-02 1.80E-02 1.55E-01 2.85E+00 2.15E-02 3.75E-02 8.60E-02 6.10E-02 12/10/2009 Total 1.00E-01 6.30E-02 1.98E+00 4.45E-02 4.15E-02 6.70E-02 2.64E-01 4.45E-02 1.80E-02 1.55E-01 2.85E+00 8.22E-01 2.15E-02 3.75E-02 8.60E-02 6.10E-02 12/11/2009 0 6.13E+00 6.41E-01 5.23E-01 1.79E-01 3.09E+00 1.08E+00 1.01E+00
1 2.65E-01 6.60E-02 2.50E-01 1.14E-01 1.07E-01 1.71E-01 1.40E-01 4.80E-02 1.90E-02 1.60E-01 3.00E+00 5.50E-02 4.00E-02 2.21E-01 6.50E-02 12/11/2009 Total 2.65E-01 6.60E-02 3.19E+00 1.14E-01 1.07E-01 1.71E-01 3.91E-01 2.86E-01 9.90E-02 1.60E-01 3.00E+00 3.09E+00 5.50E-02 5.60E-01 2.21E-01 5.38E-01 12/12/2009 0 1.04E+00 5.63E+00 8.04E-02 2.54E-02 1.00E+00
1 9.90E-02 2.70E-01 4.30E-02 4.00E-02 6.55E-02 1.25E-01 4.30E-02 1.70E-02 1.65E-01 3.10E+00 2.05E-02 3.70E-02 8.40E-02 5.95E-02 12/12/2009 Total 9.90E-02 1.04E+00 2.95E+00 4.30E-02 4.00E-02 6.55E-02 1.25E-01 6.17E-02 2.12E-02 1.65E-01 3.10E+00 1.00E+00 2.05E-02 3.70E-02 8.40E-02 5.95E-02 12/13/2009 0 4.34E-01 5.62E+00 9.26E-02 8.29E-01
1 9.90E-02 2.40E-01 4.25E-02 3.95E-02 6.45E-02 1.25E-01 4.30E-02 1.70E-02 1.55E-01 2.90E+00 2.05E-02 3.65E-02 8.20E-02 5.85E-02 12/13/2009 Total 9.90E-02 4.34E-01 2.93E+00 4.25E-02 3.95E-02 6.45E-02 1.25E-01 6.78E-02 1.70E-02 1.55E-01 2.90E+00 8.29E-01 2.05E-02 3.65E-02 8.20E-02 5.85E-02 12/14/2009 0 3.78E-01 4.51E+00 1.36E+00
1 1.10E-01 2.40E-01 4.65E-02 4.35E-02 7.05E-02 1.35E-01 4.70E-02 1.90E-02 1.55E-01 2.90E+00 8.70E-02 2.25E-02 3.95E-02 9.05E-02 6.40E-02 12/14/2009 Total 1.10E-01 3.78E-01 2.38E+00 4.65E-02 4.35E-02 7.05E-02 1.35E-01 4.70E-02 1.90E-02 1.55E-01 2.90E+00 7.24E-01 2.25E-02 3.95E-02 9.05E-02 6.40E-02 12/15/2009 0 3.66E-01 5.51E+00 4.02E-01 1.73E-01 3.18E-02 1.29E+00
1 1.05E-01 2.50E-01 4.65E-02 4.35E-02 7.05E-02 1.40E-01 5.00E-02 2.00E-02 1.70E-01 3.20E+00 2.25E-02 3.95E-02 9.05E-02 6.40E-02 12/15/2009 Total 1.05E-01 3.66E-01 2.88E+00 4.65E-02 4.35E-02 7.05E-02 2.71E-01 1.12E-01 2.59E-02 1.70E-01 3.20E+00 1.29E+00 2.25E-02 3.95E-02 9.05E-02 6.40E-02 12/16/2009 0 3.98E-01 1.07E+01 2.74E-02 1.36E-01 4.12E-02 1.71E+00 5.61E-02
1 6.75E-02 2.50E-01 2.60E-02 2.60E-02 2.60E-02 1.40E-01 2.70E-02 1.90E-02 1.60E-01 3.00E+00 2.60E-02 2.60E-02 2.60E-02 12/16/2009 Total 6.75E-02 3.98E-01 5.48E+00 2.60E-02 2.60E-02 2.60E-02 8.37E-02 8.15E-02 3.01E-02 1.60E-01 3.00E+00 1.71E+00 5.61E-02 2.60E-02 2.60E-02 2.60E-02 12/17/2009 0 5.65E-01 1.40E+01 4.96E-01 1.43E-01 2.27E-02 1.54E+00
1 1.10E-01 2.50E-01 2.75E-02 2.75E-02 2.75E-02 1.50E-01 3.00E-02 2.10E-02 1.60E-01 2.95E+00 2.30E-02 2.75E-02 6.25E-02 2.75E-02 12/17/2009 Total 1.10E-01 5.65E-01 7.13E+00 2.75E-02 2.75E-02 2.75E-02 3.23E-01 8.65E-02 2.19E-02 1.60E-01 2.95E+00 1.54E+00 2.30E-02 2.75E-02 6.25E-02 2.75E-02 12/18/2009 0 6.25E-01 1.17E+01 9.71E-02 9.57E-02 1.71E+00 1.16E-02
1 1.05E-01 2.70E-01 2.65E-02 2.65E-02 2.65E-02 1.40E-01 2.80E-02 1.80E-02 1.65E-01 3.10E+00 2.20E-02 2.80E-02 2.65E-02 2.65E-02 12/18/2009 Total 1.05E-01 6.25E-01 5.99E+00 2.65E-02 2.65E-02 2.65E-02 1.19E-01 6.19E-02 1.80E-02 1.65E-01 3.10E+00 1.71E+00 2.20E-02 1.98E-02 2.65E-02 2.65E-02 12/19/2009 0 5.66E-01 1.26E+01 3.22E-02 6.16E-01 2.40E-01 7.03E-02 1.66E+00
1 2.50E-02 2.50E-02 2.50E-02 1.60E-01 2.90E+00 2.00E-02 2.50E-02 2.50E-02 2.50E-02 12/19/2009 Total 2.50E-02 5.66E-01 1.26E+01 2.50E-02 3.22E-02 2.50E-02 6.16E-01 2.40E-01 7.03E-02 1.60E-01 2.90E+00 1.66E+00 2.00E-02 2.50E-02 2.50E-02 2.50E-02 1/7/2010 0 2.03E+00 1.36E-02 1.73E+00 5.01E+00
1 2.60E-02 7.70E-02 2.75E-01 2.60E-02 2.60E-02 2.60E-02 2.90E-02 2.60E-02 2.60E-02 3.35E+00 9.50E-02 2.60E-02 2.60E-02 2.60E-02 2.60E-02 1/7/2010 Total 2.60E-02 1.05E+00 2.75E-01 2.60E-02 2.60E-02 2.60E-02 2.13E-02 2.60E-02 2.60E-02 1.73E+00 3.35E+00 2.55E+00 2.60E-02 2.60E-02 2.60E-02 2.60E-02 1/8/2010 0 1.67E-02 7.30E-01 4.25E-02 2.50E-03 8.41E-01 1.08E+00 8.46E-02 4.70E-03
1 2.90E-02 2.80E-01 2.90E-02 2.90E-02 2.90E-02 2.90E-02 2.90E-02 3.45E+00 1.90E-01 2.90E-02 2.90E-02 2.90E-02 2.90E-02 1/8/2010 Total 2.29E-02 7.30E-01 2.80E-01 2.90E-02 2.90E-02 2.90E-02 4.25E-02 2.90E-02 1.58E-02 8.41E-01 3.45E+00 6.35E-01 5.68E-02 1.69E-02 2.90E-02 2.90E-02 1/26/2010 0 2.37E-02 1.56E+01 5.87E-02 6.02E-02 3.19E-02 1.11E+00 2.04E-02
1 7.20E-02 2.90E-02 2.90E-02 2.90E-02 1.70E-01 3.00E+00 2.40E-02 2.90E-02 2.90E-02 1/26/2010 Total 2.37E-02 7.20E-02 1.56E+01 2.90E-02 2.90E-02 5.87E-02 6.02E-02 2.90E-02 3.19E-02 1.70E-01 3.00E+00 1.11E+00 2.40E-02 2.90E-02 2.90E-02 2.04E-02 1/27/2010 0 1.83E-02 2.51E-01 1.66E+01 7.39E-02 3.16E-02 2.13E-02 9.68E-01 2.31E-02
1 2.70E-02 2.70E-02 2.70E-02 3.00E+00 1.70E-01 2.20E-02 2.70E-02 2.70E-02 1/27/2010 Total 1.83E-02 2.51E-01 1.66E+01 2.70E-02 2.70E-02 7.39E-02 3.16E-02 2.70E-02 2.13E-02 9.68E-01 3.00E+00 1.70E-01 2.20E-02 2.70E-02 2.70E-02 2.31E-02 1/28/2010 0 1.43E-02 1.22E+00 1.47E+01 6.08E-02 2.27E-02 1.26E-02 1.44E+00
1 2.60E-02 2.60E-02 2.60E-02 3.20E+00 1.70E-01 2.60E-02 2.60E-02 2.60E-02 2.60E-02 1/28/2010 Total 1.43E-02 1.22E+00 1.47E+01 2.60E-02 2.60E-02 6.08E-02 2.27E-02 2.60E-02 1.26E-02 1.44E+00 3.20E+00 1.70E-01 2.60E-02 2.60E-02 2.60E-02 2.60E-02 1/30/2010 0 7.02E-01 1.90E+01 2.51E-02 7.80E-03 1.34E+00
1 2.70E-02 2.70E-02 2.70E-02 2.70E-02 2.70E-02 3.30E+00 1.80E-01 2.70E-02 2.70E-02 2.70E-02 2.70E-02 1/30/2010 Total 2.70E-02 7.02E-01 1.90E+01 2.70E-02 2.70E-02 2.51E-02 2.70E-02 2.70E-02 7.80E-03 1.34E+00 3.30E+00 1.80E-01 2.70E-02 2.70E-02 2.70E-02 2.70E-02 1/31/2010 0 2.46E-02 7.14E-01 1.73E+01 5.25E-02 1.09E-01 2.11E-02 1.54E+00 1.09E+00 3.61E-02 3.60E-02
1 3.10E-02 3.10E-02 3.10E-02 3.00E+00 3.10E-02 3.10E-02 1/31/2010 Total 2.46E-02 7.14E-01 1.73E+01 3.10E-02 3.10E-02 5.25E-02 1.09E-01 3.10E-02 2.11E-02 1.54E+00 3.00E+00 1.09E+00 3.10E-02 3.61E-02 3.10E-02 3.60E-02 2/1/2010 0 1.50E-02 1.05E+00 1.61E+01 4.27E-02 1.09E-01 1.49E-02 1.40E+00 1.38E+00
1 2.70E-02 2.70E-02 2.70E-02 2.60E+00 2.70E-02 2.70E-02 2.70E-02 2.70E-02 2/1/2010 Total 1.50E-02 1.05E+00 1.61E+01 2.70E-02 2.70E-02 4.27E-02 1.09E-01 2.70E-02 1.49E-02 1.40E+00 2.60E+00 1.38E+00 2.70E-02 2.70E-02 2.70E-02 2.70E-02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Suspension - Existing Area Sources - Total Non-VC HAP Resins - Suspension - Existing Area Sources - Total Non-VC HAP** 

**Detection Limit A nalysis** 

Facility HAP Sum Daily HAP Sum ln Total HAP
Oxy DP 4.15E+00 **Normal Lognormal**  Oxy DP 5.88E+00 n 2.70E+01 2.70E+01 Oxy DP 9.40E+00 9.40E+00 2.24E+00 m 1.00E+00 1.00E+00 Oxy DP 2.92E+00 Average 1.21E+01 2.38E+00 Oxy DP 4.98E+00 Median 8.98E+00 2.19E+00 Oxy DP 7.90E+00 7.90E+00 2.07E+00 Standard Deviation 6.25E+00 4.65E-01 Oxy DP 2.76E+00 Minimum 6.26E+00 1.83E+00 Oxy DP 4.84E+00 Maximum 2.48E+01 3.21E+00 Oxy DP 6.46E+00 6.46E+00 1.87E+00 Skewness 1.01E+00 6.97E-01 Oxy DP 6.79E+00 SE Skewness 4.71E-01 4.71E-01 Oxy DP 4.55E+00 Skewness Test Non-normal Normal Oxy DP 7.85E+00 7.85E+00 2.06E+00 Kurtosis -5.92E-01 -1.06E+00 Oxy DP 9.05E+00 SE Kurtosis 9.43E-01 9.43E-01 Oxy DP 4.20E+00 Kurtosis Test Normal Normal Oxy DP 8.98E+00 8.98E+00 2.19E+00 t-statistic for UPL 2.48E+00 2.48E+00 Oxy DP 5.91E+00 UPL 2.79E+01 3.50E+01 Oxy DP 4.14E+00 Oxy DP 7.27E+00 7.27E+00 1.98E+00 Average for variability analysis 1.21E+01 Oxy DP 5.90E+00 RDL 4.75E+00 Oxy DP 4.10E+00 3 x RDL 1.43E+01 Oxy DP 7.08E+00 7.08E+00 1.96E+00 UPL 3.50E+01ppmw Oxy DP 6.71E+00 **MA CT Floor**  **3.50E+01 ppmw**  Oxy DP 4.42E+00 Oxy DP 7.52E+00 7.52E+00 2.02E+00 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value for the rule making. Oxy DP 6.39E+00 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability for the rule making Oxy DP 4.05E+00 Oxy DP 7.31E+00 7.31E+00 1.99E+00 Oxy DP 4.94E+00 Oxy DP 3.96E+00 Oxy DP 6.66E+00 6.66E+00 1.90E+00 Oxy DP 1.26E+01 Oxy DP 4.72E+00 Oxy DP 1.23E+01 1.23E+01 2.51E+00 Oxy DP 7.78E+00 Oxy DP 4.17E+00 Oxy DP 8.91E+00 8.91E+00 2.19E+00 Oxy DP 6.98E+00 Oxy DP 3.92E+00 Oxy DP 7.90E+00 7.90E+00 2.07E+00 Oxy DP 6.25E+00 Oxy DP 4.07E+00 Oxy DP 7.22E+00 7.22E+00 1.98E+00 Oxy DP 7.77E+00 Oxy DP 4.31E+00 Oxy DP 8.79E+00 8.79E+00 2.17E+00 Oxy DP 1.31E+01 Oxy DP 3.82E+00 Oxy DP 1.12E+01 1.12E+01 2.42E+00 Oxy DP 1.68E+01 Oxy DP 3.89E+00 Oxy DP 1.31E+01 1.31E+01 2.57E+00 Oxy DP 1.42E+01 Oxy DP 4.01E+00 Oxy DP 1.21E+01 1.21E+01 2.49E+00 Oxy DP 1.58E+01 Oxy DP 3.23E+00 Oxy DP 1.90E+01 1.90E+01 2.95E+00 Oxy DP 8.78E+00 Oxy DP 4.09E+00 Oxy DP 9.24E+00 9.24E+00 2.22E+00 Oxy DP 2.80E+00 Oxy DP 4.21E+00 Oxy DP 6.26E+00 6.26E+00 1.83E+00 Oxy DP 1.69E+01 Oxy DP 3.41E+00 Oxy DP 2.03E+01 2.03E+01 3.01E+00 Oxy DP 1.80E+01 Oxy DP 3.33E+00 Oxy DP 2.13E+01 2.13E+01 3.06E+00 Oxy DP 1.75E+01 Oxy DP 3.55E+00 Oxy DP 2.10E+01 2.10E+01 3.05E+00 Oxy DP 2.11E+01 Oxy DP 3.72E+00 Oxy DP 2.48E+01 2.48E+01 3.21E+00 Oxy DP 2.09E+01 Oxy DP 3.16E+00 Oxy DP 2.41E+01 2.41E+01 3.18E+00 Oxy DP 2.01E+01 Oxy DP 2.79E+00 Oxy DP 2.29E+01 2.29E+01 3.13E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

**GACT Worst Performer Determination GACT Limit Calculation** 

Resin Type Dispersion Resin Type Dispersion Percentile: 9.99E+01 **GACT Limit (ppmw) 1.43E+03**  Data Average of Vinyl Chloride Concentration (ppmw)

Facility Sum of NR Count of Vinyl Chloride Concentration (ppmw) Sum of BDLAverage of Vinyl Chloride Concentration (ppmw) Rank Facility

Date Total Vinyl Chloride (ppmw) PolyOne - Pedricktown 3.50E+02 1.46E+03 0.00E+00 1.44E+02 1 Formosa - Delaware City 1/1/2007 #DIV/0! PolyOne - Henry 2.17E+02 1.46E+03 0.00E+00 3.81E+02 2 1/2/2007 #DIV/0! Formosa - Delaware City 2.57E+02 1.46E+03 0.00E+00 5.34E+02 3 1/3/2007 6.70E+02 6.70E+02 Grand Total 8.24E+02 4.38E+03 0.00E+00 3.59E+02 1/4/2007 6.31E+02 6.31E+02 1/5/2007 4.87E+02 4.87E+02 1/6/2007 5.16E+02 5.16E+02 1/7/2007 6.90E+02 6.90E+02 1/8/2007 5.50E+02 5.50E+02 1/9/2007 5.69E+02 5.69E+02 1/10/2007 5.88E+02 5.88E+02 1/11/2007 4.91E+02 4.91E+02 1/12/2007 8.01E+02 8.01E+02 1/13/2007 #DIV/0! 1/14/2007 #DIV/0! 1/15/2007 #DIV/0! 1/16/2007 #DIV/0! 1/17/2007 #DIV/0! 1/18/2007 #DIV/0! 1/19/2007 #DIV/0! 1/20/2007 #DIV/0! 1/21/2007 #DIV/0! 1/22/2007 #DIV/0! 1/23/2007 #DIV/0! 1/24/2007 #DIV/0! 1/25/2007 #DIV/0! 1/26/2007 #DIV/0! 1/27/2007 #DIV/0! 1/28/2007 #DIV/0! 1/29/2007 #DIV/0! 1/30/2007 #DIV/0! 1/31/2007 #DIV/0! 2/1/2007 #DIV/0! 2/2/2007 #DIV/0! 2/3/2007 #DIV/0! 2/4/2007 5.58E+02 5.58E+02 2/5/2007 4.18E+02 4.18E+02 2/6/2007 3.93E+02 3.93E+02 2/7/2007 4.01E+02 4.01E+02 2/8/2007 3.94E+02 3.94E+02 2/9/2007 4.42E+02 4.42E+02 2/10/2007 4.03E+02 4.03E+02 2/11/2007 4.89E+02 4.89E+02 2/12/2007 4.54E+02 4.54E+02 2/13/2007 4.51E+02 4.51E+02 2/14/2007 4.20E+02 4.20E+02 2/15/2007 5.34E+02 5.34E+02 2/16/2007 5.20E+02 5.20E+02 2/17/2007 6.15E+02 6.15E+02 2/18/2007 6.73E+02 6.73E+02 2/19/2007 7.46E+02 7.46E+02 2/20/2007 7.93E+02 7.93E+02 2/21/2007 9.31E+02 9.31E+02 2/22/2007 5.16E+02 5.16E+02 2/23/2007 5.80E+02 5.80E+02 2/24/2007 5.89E+02 5.89E+02 2/25/2007 5.68E+02 5.68E+02 2/26/2007 4.92E+02 4.92E+02 2/27/2007 5.73E+02 5.73E+02 2/28/2007 5.24E+02 5.24E+02 3/1/2007 4.91E+02 4.91E+02 3/2/2007 2.84E+02 2.84E+02 3/3/2007 5.34E+02 5.34E+02 3/4/2007 6.87E+02 6.87E+02 3/5/2007 4.75E+02 4.75E+02 3/6/2007 5.85E+02 5.85E+02 3/7/2007 5.58E+02 5.58E+02 3/8/2007 6.97E+02 6.97E+02 3/9/2007 6.52E+02 6.52E+02 3/10/2007 5.22E+02 5.22E+02 3/11/2007 6.19E+02 6.19E+02 3/12/2007 6.60E+02 6.60E+02 3/13/2007 5.87E+02 5.87E+02 3/14/2007 5.60E+02 5.60E+02 3/15/2007 #DIV/0! 3/16/2007 #DIV/0! 3/17/2007 #DIV/0! 3/18/2007 #DIV/0! 3/19/2007 #DIV/0! 3/20/2007 #DIV/0! 3/21/2007 #DIV/0! 3/22/2007 #DIV/0! 3/23/2007 #DIV/0! 3/24/2007 #DIV/0! 3/25/2007 #DIV/0! 3/26/2007 #DIV/0! 3/27/2007 #DIV/0! 3/28/2007 #DIV/0! 3/29/2007 #DIV/0! 3/30/2007 #DIV/0! 3/31/2007 #DIV/0! 4/1/2007 #DIV/0! 4/2/2007 2.73E+02 2.73E+02 4/3/2007 2.32E+02 2.32E+02 4/4/2007 3.45E+02 3.45E+02 4/5/2007 3.26E+02 3.26E+02 4/6/2007 4.40E+02 4.40E+02 4/7/2007 3.37E+02 3.37E+02 4/8/2007 3.07E+02 3.07E+02 4/9/2007 3.56E+02 3.56E+02 4/10/2007 3.85E+02 3.85E+02 4/11/2007 3.28E+02 3.28E+02 4/12/2007 4.34E+02 4.34E+02 4/13/2007 3.28E+02 3.28E+02 4/14/2007 4.44E+02 4.44E+02 4/15/2007 3.82E+02 3.82E+02 4/16/2007 3.16E+02 3.16E+02 4/17/2007 4.93E+02 4.93E+02 4/18/2007 4.04E+02 4.04E+02 4/19/2007 3.41E+02 3.41E+02 4/20/2007 4.94E+02 4.94E+02 4/21/2007 4.49E+02 4.49E+02 4/22/2007 5.60E+02 5.60E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

4/23/2007 4.25E+02 4.25E+02 4/24/2007 6.95E+02 6.95E+02 4/25/2007 4.83E+02 4.83E+02 4/26/2007 4.40E+02 4.40E+02 4/27/2007 3.50E+02 3.50E+02 4/28/2007 3.73E+02 3.73E+02 4/29/2007 4.43E+02 4.43E+02 4/30/2007 2.84E+02 2.84E+02 5/1/2007 3.21E+02 3.21E+02 5/2/2007 3.86E+02 3.86E+02 5/3/2007 4.19E+02 4.19E+02 5/4/2007 4.00E+02 4.00E+02 5/5/2007 3.98E+02 3.98E+02 5/6/2007 3.89E+02 3.89E+02 5/7/2007 4.18E+02 4.18E+02 5/8/2007 3.96E+02 3.96E+02 5/9/2007 4.38E+02 4.38E+02 5/10/2007 3.98E+02 3.98E+02 5/11/2007 3.84E+02 3.84E+02 5/12/2007 3.79E+02 3.79E+02 5/13/2007 4.30E+02 4.30E+02 5/14/2007 4.30E+02 4.30E+02 5/15/2007 4.07E+02 4.07E+02 5/16/2007 3.47E+02 3.47E+02 5/17/2007 3.26E+02 3.26E+02 5/18/2007 3.59E+02 3.59E+02 5/19/2007 3.81E+02 3.81E+02 5/20/2007 3.35E+02 3.35E+02 5/21/2007 4.79E+02 4.79E+02 5/22/2007 6.87E+02 6.87E+02 5/23/2007 3.41E+02 3.41E+02 5/24/2007 2.93E+02 2.93E+02 5/25/2007 2.10E+02 2.10E+02 5/26/2007 2.72E+02 2.72E+02 5/27/2007 2.87E+02 2.87E+02 5/28/2007 2.50E+02 2.50E+02 5/29/2007 #DIV/0! 5/30/2007 #DIV/0! 5/31/2007 #DIV/0! 6/1/2007 #DIV/0! 6/2/2007 #DIV/0! 6/3/2007 #DIV/0! 6/4/2007 #DIV/0! 6/5/2007 #DIV/0! 6/6/2007 #DIV/0! 6/7/2007 #DIV/0! 6/8/2007 #DIV/0! 6/9/2007 #DIV/0! 6/10/2007 #DIV/0! 6/11/2007 #DIV/0! 6/12/2007 #DIV/0! 6/13/2007 #DIV/0! 6/14/2007 #DIV/0! 6/15/2007 #DIV/0! 6/16/2007 #DIV/0! 6/17/2007 #DIV/0! 6/18/2007 #DIV/0! 6/19/2007 3.39E+02 3.39E+02 6/20/2007 3.48E+02 3.48E+02 6/21/2007 3.66E+02 3.66E+02 6/22/2007 3.88E+02 3.88E+02 6/23/2007 3.97E+02 3.97E+02 6/24/2007 4.89E+02 4.89E+02 6/25/2007 4.99E+02 4.99E+02 6/26/2007 4.70E+02 4.70E+02 6/27/2007 5.18E+02 5.18E+02 6/28/2007 4.91E+02 4.91E+02 6/29/2007 5.91E+02 5.91E+02 6/30/2007 3.81E+02 3.81E+02 7/1/2007 3.60E+02 3.60E+02 7/2/2007 3.46E+02 3.46E+02 7/3/2007 2.92E+02 2.92E+02 7/4/2007 3.31E+02 3.31E+02 7/5/2007 4.16E+02 4.16E+02 7/6/2007 6.00E+02 6.00E+02 7/7/2007 6.41E+02 6.41E+02 7/8/2007 4.55E+02 4.55E+02 7/9/2007 5.80E+02 5.80E+02 7/10/2007 6.36E+02 6.36E+02 7/11/2007 5.91E+02 5.91E+02 7/12/2007 4.74E+02 4.74E+02 7/13/2007 5.31E+02 5.31E+02 7/14/2007 2.11E+02 2.11E+02 7/15/2007 3.83E+02 3.83E+02 7/16/2007 5.44E+02 5.44E+02 7/17/2007 5.79E+02 5.79E+02 7/18/2007 6.95E+02 6.95E+02 7/19/2007 6.66E+02 6.66E+02 7/20/2007 6.66E+02 6.66E+02 7/21/2007 5.77E+02 5.77E+02 7/22/2007 5.84E+02 5.84E+02 7/23/2007 6.44E+02 6.44E+02 7/24/2007 6.22E+02 6.22E+02 7/25/2007 5.08E+02 5.08E+02 7/26/2007 4.94E+02 4.94E+02 7/27/2007 5.65E+02 5.65E+02 7/28/2007 7.00E+02 7.00E+02 7/29/2007 6.56E+02 6.56E+02 7/30/2007 5.81E+02 5.81E+02 7/31/2007 5.35E+02 5.35E+02 8/1/2007 5.35E+02 5.35E+02 8/2/2007 3.71E+02 3.71E+02 8/3/2007 4.03E+02 4.03E+02 8/4/2007 5.86E+02 5.86E+02 8/5/2007 5.37E+02 5.37E+02 8/6/2007 4.29E+02 4.29E+02 8/7/2007 5.58E+02 5.58E+02 8/8/2007 6.74E+02 6.74E+02 8/9/2007 #DIV/0! 8/10/2007 4.79E+02 4.79E+02 8/11/2007 #DIV/0! 8/12/2007 #DIV/0! 8/13/2007 #DIV/0! 8/14/2007 #DIV/0! 8/15/2007 #DIV/0! 8/16/2007 #DIV/0! 8/17/2007 #DIV/0! 8/18/2007 #DIV/0! 8/19/2007 #DIV/0! 8/20/2007 #DIV/0! 8/21/2007 #DIV/0! 8/22/2007 #DIV/0! 8/23/2007 #DIV/0! 8/24/2007 #DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

8/25/2007 #DIV/0! 8/26/2007 #DIV/0! 8/27/2007 #DIV/0! 8/28/2007 #DIV/0! 8/29/2007 #DIV/0! 8/30/2007 4.61E+02 4.61E+02 8/31/2007 5.92E+02 5.92E+02 9/1/2007 5.46E+02 5.46E+02 9/2/2007 3.07E+02 3.07E+02 9/3/2007 3.52E+02 3.52E+02 9/4/2007 2.76E+02 2.76E+02 9/5/2007 4.95E+02 4.95E+02 9/6/2007 2.35E+02 2.35E+02 9/7/2007 3.35E+02 3.35E+02 9/8/2007 4.45E+02 4.45E+02 9/9/2007 4.89E+02 4.89E+02 9/10/2007 4.38E+02 4.38E+02 9/11/2007 3.77E+02 3.77E+02 9/12/2007 3.55E+02 3.55E+02 9/13/2007 4.06E+02 4.06E+02 9/14/2007 3.29E+02 3.29E+02 9/15/2007 3.76E+02 3.76E+02 9/16/2007 3.99E+02 3.99E+02 9/17/2007 3.44E+02 3.44E+02 9/18/2007 3.55E+02 3.55E+02 9/19/2007 2.76E+02 2.76E+02 9/20/2007 3.48E+02 3.48E+02 9/21/2007 3.34E+02 3.34E+02 9/22/2007 3.10E+02 3.10E+02 9/23/2007 3.33E+02 3.33E+02 9/24/2007 4.26E+02 4.26E+02 9/25/2007 4.07E+02 4.07E+02 9/26/2007 3.92E+02 3.92E+02 9/27/2007 3.88E+02 3.88E+02 9/28/2007 4.43E+02 4.43E+02 9/29/2007 4.37E+02 4.37E+02 9/30/2007 3.72E+02 3.72E+02 10/1/2007 4.28E+02 4.28E+02 10/2/2007 3.90E+02 3.90E+02 10/3/2007 4.61E+02 4.61E+02 10/4/2007 2.49E+02 2.49E+02 10/5/2007 #DIV/0! 10/6/2007 #DIV/0! 10/7/2007 #DIV/0! 10/8/2007 #DIV/0! 10/9/2007 #DIV/0! 10/10/2007 #DIV/0! 10/11/2007 #DIV/0! 10/12/2007 #DIV/0! 10/13/2007 #DIV/0! 10/14/2007 #DIV/0! 10/15/2007 #DIV/0! 10/16/2007 #DIV/0! 10/17/2007 4.92E+02 4.92E+02 10/18/2007 5.52E+02 5.52E+02 10/19/2007 4.17E+02 4.17E+02 10/20/2007 4.45E+02 4.45E+02 10/21/2007 3.87E+02 3.87E+02 10/22/2007 3.68E+02 3.68E+02 10/23/2007 4.55E+02 4.55E+02 10/24/2007 3.89E+02 3.89E+02 10/25/2007 3.84E+02 3.84E+02 10/26/2007 5.16E+02 5.16E+02 10/27/2007 7.79E+02 7.79E+02 10/28/2007 4.88E+02 4.88E+02 10/29/2007 3.14E+02 3.14E+02 10/30/2007 4.30E+02 4.30E+02 10/31/2007 #DIV/0! 11/1/2007 1.00E+03 1.00E+03 11/2/2007 8.29E+02 8.29E+02 11/3/2007 #DIV/0! 11/4/2007 1.62E+01 1.62E+01 11/5/2007 6.25E+02 6.25E+02 11/6/2007 5.94E+02 5.94E+02 11/7/2007 6.12E+02 6.12E+02 11/8/2007 6.65E+02 6.65E+02 11/9/2007 8.06E+02 8.06E+02 11/10/2007 #DIV/0! 11/11/2007 #DIV/0! 11/12/2007 4.06E+02 4.06E+02 11/13/2007 3.97E+02 3.97E+02 11/14/2007 3.22E+02 3.22E+02 11/15/2007 1.73E+02 1.73E+02 11/16/2007 3.28E+02 3.28E+02 11/17/2007 #DIV/0! 11/18/2007 6.22E+02 6.22E+02 11/19/2007 5.02E+02 5.02E+02 11/20/2007 3.55E+02 3.55E+02 11/21/2007 3.69E+02 3.69E+02 11/22/2007 2.88E+02 2.88E+02 11/23/2007 1.01E+03 1.01E+03 11/24/2007 #DIV/0! 11/25/2007 #DIV/0! 11/26/2007 #DIV/0! 11/27/2007 #DIV/0! 11/28/2007 6.06E+02 6.06E+02 11/29/2007 3.87E+02 3.87E+02 11/30/2007 4.12E+02 4.12E+02 12/1/2007 4.91E+02 4.91E+02 12/2/2007 4.54E+02 4.54E+02 12/3/2007 3.83E+02 3.83E+02 12/4/2007 4.26E+02 4.26E+02 12/5/2007 4.76E+02 4.76E+02 12/6/2007 4.00E+02 4.00E+02 12/7/2007 4.44E+02 4.44E+02 12/8/2007 4.50E+02 4.50E+02 12/9/2007 4.58E+02 4.58E+02 12/10/2007 6.77E+02 6.77E+02 12/11/2007 8.58E+02 8.58E+02 12/12/2007 5.19E+02 5.19E+02 12/13/2007 7.18E+02 7.18E+02 12/14/2007 6.08E+02 6.08E+02 12/15/2007 1.07E+03 1.07E+03 12/16/2007 8.73E+02 8.73E+02 12/17/2007 6.85E+02 6.85E+02 12/18/2007 7.17E+02 7.17E+02 12/19/2007 6.52E+02 6.52E+02 12/20/2007 7.20E+02 7.20E+02 12/21/2007 8.60E+02 8.60E+02 12/22/2007 7.56E+02 7.56E+02 12/23/2007 9.16E+02 9.16E+02 12/24/2007 6.57E+02 6.57E+02 12/25/2007 5.10E+02 5.10E+02 12/26/2007 5.44E+02 5.44E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

12/27/2007 5.74E+02 5.74E+02 12/28/2007 6.30E+02 6.30E+02 12/29/2007 6.31E+02 6.31E+02 12/30/2007 5.76E+02 5.76E+02 12/31/2007 4.75E+02 4.75E+02 1/1/2008 4.66E+02 4.66E+02 1/2/2008 5.39E+02 5.39E+02 1/3/2008 4.07E+02 4.07E+02 1/4/2008 4.36E+02 4.36E+02 1/5/2008 #DIV/0! 1/6/2008 #DIV/0! 1/7/2008 2.67E+02 2.67E+02 1/8/2008 4.57E+02 4.57E+02 1/9/2008 3.17E+02 3.17E+02 1/10/2008 2.75E+02 2.75E+02 1/11/2008 3.67E+02 3.67E+02 1/12/2008 3.23E+02 3.23E+02 1/13/2008 #DIV/0! 1/14/2008 4.08E+02 4.08E+02 1/15/2008 3.64E+02 3.64E+02 1/16/2008 5.49E+02 5.49E+02 1/17/2008 4.66E+02 4.66E+02 1/18/2008 4.56E+02 4.56E+02 1/19/2008 #DIV/0! 1/20/2008 #DIV/0! 1/21/2008 6.23E+02 6.23E+02 1/22/2008 6.88E+02 6.88E+02 1/23/2008 5.64E+02 5.64E+02 1/24/2008 6.79E+02 6.79E+02 1/25/2008 7.29E+02 7.29E+02 1/26/2008 8.28E+02 8.28E+02 1/27/2008 6.69E+02 6.69E+02 1/28/2008 5.02E+02 5.02E+02 1/29/2008 6.17E+02 6.17E+02 1/30/2008 5.88E+02 5.88E+02 1/31/2008 6.10E+02 6.10E+02 2/1/2008 6.35E+02 6.35E+02 2/2/2008 5.92E+02 5.92E+02 2/3/2008 6.51E+02 6.51E+02 2/4/2008 6.16E+02 6.16E+02 2/5/2008 4.67E+02 4.67E+02 2/6/2008 3.28E+02 3.28E+02 2/7/2008 5.55E+02 5.55E+02 2/8/2008 5.20E+02 5.20E+02 2/9/2008 6.24E+02 6.24E+02 2/10/2008 7.19E+02 7.19E+02 2/11/2008 5.05E+02 5.05E+02 2/12/2008 4.84E+02 4.84E+02 2/13/2008 3.95E+02 3.95E+02 2/14/2008 3.08E+02 3.08E+02 2/15/2008 4.00E+02 4.00E+02 2/16/2008 #DIV/0! 2/17/2008 #DIV/0! 2/18/2008 4.56E+02 4.56E+02 2/19/2008 5.54E+02 5.54E+02 2/20/2008 6.66E+02 6.66E+02 2/21/2008 4.70E+02 4.70E+02 2/22/2008 4.92E+02 4.92E+02 2/23/2008 #DIV/0! 2/24/2008 #DIV/0! 2/25/2008 6.40E+02 6.40E+02 2/26/2008 4.12E+02 4.12E+02 2/27/2008 3.97E+02 3.97E+02 2/28/2008 5.43E+02 5.43E+02 2/29/2008 4.89E+02 4.89E+02 3/1/2008 3.92E+02 3.92E+02 3/2/2008 4.22E+02 4.22E+02 3/3/2008 2.82E+02 2.82E+02 3/4/2008 4.19E+02 4.19E+02 3/5/2008 6.21E+02 6.21E+02 3/6/2008 6.22E+02 6.22E+02 3/7/2008 6.31E+02 6.31E+02 3/8/2008 4.81E+02 4.81E+02 3/9/2008 5.19E+02 5.19E+02 3/10/2008 4.71E+02 4.71E+02 3/11/2008 5.14E+02 5.14E+02 3/12/2008 3.97E+02 3.97E+02 3/13/2008 5.17E+02 5.17E+02 3/14/2008 4.34E+02 4.34E+02 3/15/2008 4.71E+02 4.71E+02 3/16/2008 4.92E+02 4.92E+02 3/17/2008 5.28E+02 5.28E+02 3/18/2008 6.81E+02 6.81E+02 3/19/2008 7.02E+02 7.02E+02 3/20/2008 6.97E+02 6.97E+02 3/21/2008 7.60E+02 7.60E+02 3/22/2008 7.71E+02 7.71E+02 3/23/2008 8.87E+02 8.87E+02 3/24/2008 7.28E+02 7.28E+02 3/25/2008 7.37E+02 7.37E+02 3/26/2008 6.82E+02 6.82E+02 3/27/2008 #DIV/0! 3/28/2008 #DIV/0! 3/29/2008 9.96E+02 9.96E+02 3/30/2008 7.82E+02 7.82E+02 3/31/2008 3.62E+02 3.62E+02 4/1/2008 3.78E+02 3.78E+02 4/2/2008 4.37E+02 4.37E+02 4/3/2008 4.92E+02 4.92E+02 4/4/2008 4.27E+02 4.27E+02 4/5/2008 3.90E+02 3.90E+02 4/6/2008 4.46E+02 4.46E+02 4/7/2008 3.75E+02 3.75E+02 4/8/2008 5.03E+02 5.03E+02 4/9/2008 8.66E+02 8.66E+02 4/10/2008 9.46E+02 9.46E+02 4/11/2008 7.41E+02 7.41E+02 4/12/2008 6.15E+02 6.15E+02 4/13/2008 7.37E+02 7.37E+02 4/14/2008 5.94E+02 5.94E+02 4/15/2008 5.38E+02 5.38E+02 4/16/2008 6.52E+02 6.52E+02 4/17/2008 4.14E+02 4.14E+02 4/18/2008 3.60E+02 3.60E+02 4/19/2008 #DIV/0! 4/20/2008 #DIV/0! 4/21/2008 #DIV/0! 4/22/2008 #DIV/0! 4/23/2008 #DIV/0! 4/24/2008 #DIV/0! 4/25/2008 #DIV/0! 4/26/2008 #DIV/0! 4/27/2008 #DIV/0! 4/28/2008 #DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

4/29/2008 #DIV/0! 4/30/2008 7.73E+02 7.73E+02 5/1/2008 7.23E+02 7.23E+02 5/2/2008 6.92E+02 6.92E+02 5/3/2008 7.42E+02 7.42E+02 5/4/2008 7.68E+02 7.68E+02 5/5/2008 6.47E+02 6.47E+02 5/6/2008 4.05E+02 4.05E+02 5/7/2008 7.62E+02 7.62E+02 5/8/2008 7.30E+02 7.30E+02 5/9/2008 6.64E+02 6.64E+02 5/10/2008 7.71E+02 7.71E+02 5/11/2008 5.91E+02 5.91E+02 5/12/2008 5.07E+02 5.07E+02 5/13/2008 5.71E+02 5.71E+02 5/14/2008 5.09E+02 5.09E+02 5/15/2008 5.52E+02 5.52E+02 5/16/2008 5.59E+02 5.59E+02 5/17/2008 5.93E+02 5.93E+02 5/18/2008 3.06E+02 3.06E+02 5/19/2008 8.33E+02 8.33E+02 5/20/2008 4.01E+02 4.01E+02 5/21/2008 3.39E+02 3.39E+02 5/22/2008 3.68E+02 3.68E+02 5/23/2008 4.30E+02 4.30E+02 5/24/2008 #DIV/0! 5/25/2008 #DIV/0! 5/26/2008 3.75E+02 3.75E+02 5/27/2008 3.89E+02 3.89E+02 5/28/2008 3.50E+02 3.50E+02 5/29/2008 4.47E+02 4.47E+02 5/30/2008 3.96E+02 3.96E+02 5/31/2008 #DIV/0! 6/1/2008 #DIV/0! 6/2/2008 #DIV/0! 6/3/2008 #DIV/0! 6/4/2008 #DIV/0! 6/5/2008 1.82E+01 1.82E+01 6/6/2008 5.61E+02 5.61E+02 6/7/2008 5.06E+02 5.06E+02 6/8/2008 5.52E+02 5.52E+02 6/9/2008 8.11E+02 8.11E+02 6/10/2008 1.02E+03 1.02E+03 6/11/2008 1.09E+03 1.09E+03 6/12/2008 6.19E+02 6.19E+02 6/13/2008 7.52E+02 7.52E+02 6/14/2008 9.06E+02 9.06E+02 6/15/2008 6.32E+02 6.32E+02 6/16/2008 7.61E+02 7.61E+02 6/17/2008 7.58E+02 7.58E+02 6/18/2008 8.51E+02 8.51E+02 6/19/2008 6.19E+02 6.19E+02 6/20/2008 8.03E+02 8.03E+02 6/21/2008 7.21E+02 7.21E+02 6/22/2008 6.46E+02 6.46E+02 6/23/2008 7.47E+02 7.47E+02 6/24/2008 6.09E+02 6.09E+02 6/25/2008 7.93E+02 7.93E+02 6/26/2008 6.82E+02 6.82E+02 6/27/2008 6.08E+02 6.08E+02 6/28/2008 3.65E+02 3.65E+02 6/29/2008 5.07E+02 5.07E+02 6/30/2008 4.21E+02 4.21E+02 7/1/2008 2.31E+02 2.31E+02 7/2/2008 4.07E+02 4.07E+02 7/3/2008 4.32E+02 4.32E+02 7/4/2008 3.79E+02 3.79E+02 7/5/2008 4.67E+02 4.67E+02 7/6/2008 5.03E+02 5.03E+02 7/7/2008 4.16E+02 4.16E+02 7/8/2008 3.80E+02 3.80E+02 7/9/2008 4.67E+02 4.67E+02 7/10/2008 8.42E+02 8.42E+02 7/11/2008 6.28E+02 6.28E+02 7/12/2008 7.31E+02 7.31E+02 7/13/2008 7.64E+02 7.64E+02 7/14/2008 7.32E+02 7.32E+02 7/15/2008 6.28E+02 6.28E+02 7/16/2008 8.64E+02 8.64E+02 7/17/2008 8.93E+02 8.93E+02 7/18/2008 4.85E+02 4.85E+02 7/19/2008 5.50E+02 5.50E+02 7/20/2008 5.40E+02 5.40E+02 7/21/2008 5.48E+02 5.48E+02 7/22/2008 4.87E+02 4.87E+02 7/23/2008 4.78E+02 4.78E+02 7/24/2008 4.60E+02 4.60E+02 7/25/2008 #DIV/0! 7/26/2008 #DIV/0! 7/27/2008 5.54E+02 5.54E+02 7/28/2008 #DIV/0! 7/29/2008 #DIV/0! 7/30/2008 #DIV/0! 7/31/2008 4.45E+02 4.45E+02 8/1/2008 5.31E+02 5.31E+02 8/2/2008 #DIV/0! 8/3/2008 #DIV/0! 8/4/2008 3.05E+02 3.05E+02 8/5/2008 5.42E+02 5.42E+02 8/6/2008 2.89E+02 2.89E+02 8/7/2008 2.52E+02 2.52E+02 8/8/2008 5.50E+02 5.50E+02 8/9/2008 #DIV/0! 8/10/2008 #DIV/0! 8/11/2008 1.13E+03 1.13E+03 8/12/2008 7.79E+02 7.79E+02 8/13/2008 9.69E+02 9.69E+02 8/14/2008 7.48E+02 7.48E+02 8/15/2008 5.47E+02 5.47E+02 8/16/2008 #DIV/0! 8/17/2008 #DIV/0! 8/18/2008 3.58E+02 3.58E+02 8/19/2008 8.47E+02 8.47E+02 8/20/2008 2.39E+02 2.39E+02 8/21/2008 3.63E+02 3.63E+02 8/22/2008 4.44E+02 4.44E+02 8/23/2008 4.68E+02 4.68E+02 8/24/2008 5.98E+02 5.98E+02 8/25/2008 4.85E+02 4.85E+02 8/26/2008 5.42E+02 5.42E+02 8/27/2008 5.20E+02 5.20E+02 8/28/2008 3.85E+02 3.85E+02 8/29/2008 3.70E+02 3.70E+02 8/30/2008 #DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

8/31/2008 #DIV/0! 9/1/2008 7.69E+02 7.69E+02 9/2/2008 6.87E+02 6.87E+02 9/3/2008 7.32E+02 7.32E+02 9/4/2008 6.27E+02 6.27E+02 9/5/2008 5.30E+02 5.30E+02 9/6/2008 5.89E+02 5.89E+02 9/7/2008 6.27E+02 6.27E+02 9/8/2008 8.40E+02 8.40E+02 9/9/2008 8.24E+02 8.24E+02 9/10/2008 8.61E+02 8.61E+02 9/11/2008 6.01E+02 6.01E+02 9/12/2008 5.59E+02 5.59E+02 9/13/2008 3.60E+02 3.60E+02 9/14/2008 4.30E+02 4.30E+02 9/15/2008 4.76E+02 4.76E+02 9/16/2008 4.47E+02 4.47E+02 9/17/2008 6.04E+02 6.04E+02 9/18/2008 8.37E+02 8.37E+02 9/19/2008 6.92E+02 6.92E+02 9/20/2008 #DIV/0! 9/21/2008 #DIV/0! 9/22/2008 1.01E+03 1.01E+03 9/23/2008 6.72E+02 6.72E+02 9/24/2008 5.03E+02 5.03E+02 9/25/2008 6.83E+02 6.83E+02 9/26/2008 6.38E+02 6.38E+02 9/27/2008 5.85E+02 5.85E+02 9/28/2008 #DIV/0! 9/29/2008 7.49E+02 7.49E+02 9/30/2008 4.62E+02 4.62E+02 10/1/2008 6.33E+02 6.33E+02 10/2/2008 6.54E+02 6.54E+02 10/3/2008 5.32E+02 5.32E+02 10/4/2008 #DIV/0! 10/5/2008 #DIV/0! 10/6/2008 6.96E+02 6.96E+02 10/7/2008 4.41E+02 4.41E+02 10/8/2008 8.49E+02 8.49E+02 10/9/2008 7.49E+02 7.49E+02 10/10/2008 7.11E+02 7.11E+02 10/11/2008 6.04E+02 6.04E+02 10/12/2008 6.69E+02 6.69E+02 10/13/2008 7.13E+02 7.13E+02 10/14/2008 6.95E+02 6.95E+02 10/15/2008 6.35E+02 6.35E+02 10/16/2008 5.22E+02 5.22E+02 10/17/2008 4.31E+02 4.31E+02 10/18/2008 5.78E+02 5.78E+02 10/19/2008 6.76E+02 6.76E+02 10/20/2008 5.70E+02 5.70E+02 10/21/2008 4.31E+02 4.31E+02 10/22/2008 7.23E+02 7.23E+02 10/23/2008 5.77E+02 5.77E+02 10/24/2008 8.78E+02 8.78E+02 10/25/2008 6.28E+02 6.28E+02 10/26/2008 8.36E+02 8.36E+02 10/27/2008 6.52E+02 6.52E+02 10/28/2008 6.97E+02 6.97E+02 10/29/2008 1.19E+03 1.19E+03 10/30/2008 8.65E+02 8.65E+02 10/31/2008 7.80E+02 7.80E+02 11/1/2008 6.54E+02 6.54E+02 11/2/2008 6.94E+02 6.94E+02 11/3/2008 9.73E+02 9.73E+02 11/4/2008 8.29E+02 8.29E+02 11/5/2008 6.58E+02 6.58E+02 11/6/2008 5.13E+02 5.13E+02 11/7/2008 5.90E+02 5.90E+02 11/8/2008 4.09E+02 4.09E+02 11/9/2008 4.81E+02 4.81E+02 11/10/2008 4.12E+02 4.12E+02 11/11/2008 4.69E+02 4.69E+02 11/12/2008 5.84E+02 5.84E+02 11/13/2008 5.20E+02 5.20E+02 11/14/2008 5.79E+02 5.79E+02 11/15/2008 6.08E+02 6.08E+02 11/16/2008 4.75E+02 4.75E+02 11/17/2008 6.53E+02 6.53E+02 11/18/2008 5.05E+02 5.05E+02 11/19/2008 #DIV/0! 11/20/2008 #DIV/0! 11/21/2008 #DIV/0! 11/22/2008 #DIV/0! 11/23/2008 #DIV/0! 11/24/2008 #DIV/0! 11/25/2008 #DIV/0! 11/26/2008 #DIV/0! 11/27/2008 #DIV/0! 11/28/2008 #DIV/0! 11/29/2008 #DIV/0! 11/30/2008 #DIV/0! 12/1/2008 #DIV/0! 12/2/2008 #DIV/0! 12/3/2008 #DIV/0! 12/4/2008 #DIV/0! 12/5/2008 #DIV/0! 12/6/2008 #DIV/0! 12/7/2008 #DIV/0! 12/8/2008 7.77E+02 7.77E+02 12/9/2008 8.10E+02 8.10E+02 12/10/2008 5.39E+02 5.39E+02 12/11/2008 4.60E+02 4.60E+02 12/12/2008 6.99E+02 6.99E+02 12/13/2008 6.05E+02 6.05E+02 12/14/2008 5.89E+02 5.89E+02 12/15/2008 5.75E+02 5.75E+02 12/16/2008 5.26E+02 5.26E+02 12/17/2008 4.17E+02 4.17E+02 12/18/2008 4.70E+02 4.70E+02 12/19/2008 #DIV/0! 12/20/2008 #DIV/0! 12/21/2008 #DIV/0! 12/22/2008 #DIV/0! 12/23/2008 #DIV/0! 12/24/2008 #DIV/0! 12/25/2008 #DIV/0! 12/26/2008 #DIV/0! 12/27/2008 #DIV/0! 12/28/2008 #DIV/0! 12/29/2008 #DIV/0! 12/30/2008 #DIV/0! 12/31/2008 #DIV/0! 1/1/2009 #DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

1/2/2009 #DIV/0! 1/3/2009 #DIV/0! 1/4/2009 #DIV/0! 1/5/2009 #DIV/0! 1/6/2009 4.25E+02 4.25E+02 1/7/2009 3.94E+02 3.94E+02 1/8/2009 4.91E+02 4.91E+02 1/9/2009 5.66E+02 5.66E+02 1/10/2009 4.09E+02 4.09E+02 1/11/2009 3.81E+02 3.81E+02 1/12/2009 2.80E+02 2.80E+02 1/13/2009 #DIV/0! 1/14/2009 #DIV/0! 1/15/2009 #DIV/0! 1/16/2009 #DIV/0! 1/17/2009 #DIV/0! 1/18/2009 #DIV/0! 1/19/2009 #DIV/0! 1/20/2009 #DIV/0! 1/21/2009 #DIV/0! 1/22/2009 #DIV/0! 1/23/2009 #DIV/0! 1/24/2009 #DIV/0! 1/25/2009 #DIV/0! 1/26/2009 #DIV/0! 1/27/2009 #DIV/0! 1/28/2009 3.57E+02 3.57E+02 1/29/2009 5.43E+02 5.43E+02 1/30/2009 6.92E+02 6.92E+02 1/31/2009 6.26E+02 6.26E+02 2/1/2009 8.94E+02 8.94E+02 2/2/2009 1.02E+03 1.02E+03 2/3/2009 7.22E+02 7.22E+02 2/4/2009 #DIV/0! 2/5/2009 #DIV/0! 2/6/2009 7.43E+02 7.43E+02 2/7/2009 8.54E+02 8.54E+02 2/8/2009 5.36E+02 5.36E+02 2/9/2009 4.76E+02 4.76E+02 2/10/2009 6.44E+02 6.44E+02 2/11/2009 4.04E+02 4.04E+02 2/12/2009 4.45E+02 4.45E+02 2/13/2009 5.79E+02 5.79E+02 2/14/2009 5.75E+02 5.75E+02 2/15/2009 #DIV/0! 2/16/2009 #DIV/0! 2/17/2009 #DIV/0! 2/18/2009 #DIV/0! 2/19/2009 #DIV/0! 2/20/2009 #DIV/0! 2/21/2009 #DIV/0! 2/22/2009 #DIV/0! 2/23/2009 #DIV/0! 2/24/2009 #DIV/0! 2/25/2009 #DIV/0! 2/26/2009 #DIV/0! 2/27/2009 #DIV/0! 2/28/2009 #DIV/0! 3/1/2009 #DIV/0! 3/2/2009 #DIV/0! 3/3/2009 #DIV/0! 3/4/2009 3.25E+02 3.25E+02 3/5/2009 3.62E+02 3.62E+02 3/6/2009 3.12E+02 3.12E+02 3/7/2009 3.98E+02 3.98E+02 3/8/2009 3.69E+02 3.69E+02 3/9/2009 3.48E+02 3.48E+02 3/10/2009 2.68E+02 2.68E+02 3/11/2009 2.90E+02 2.90E+02 3/12/2009 4.70E+02 4.70E+02 3/13/2009 3.13E+02 3.13E+02 3/14/2009 4.99E+02 4.99E+02 3/15/2009 3.99E+02 3.99E+02 3/16/2009 2.78E+02 2.78E+02 3/17/2009 3.95E+02 3.95E+02 3/18/2009 3.72E+02 3.72E+02 3/19/2009 3.54E+02 3.54E+02 3/20/2009 3.47E+02 3.47E+02 3/21/2009 6.26E+02 6.26E+02 3/22/2009 4.17E+02 4.17E+02 3/23/2009 5.32E+02 5.32E+02 3/24/2009 5.01E+02 5.01E+02 3/25/2009 #DIV/0! 3/26/2009 #DIV/0! 3/27/2009 #DIV/0! 3/28/2009 #DIV/0! 3/29/2009 #DIV/0! 3/30/2009 4.20E+02 4.20E+02 3/31/2009 6.08E+02 6.08E+02 4/1/2009 4.93E+02 4.93E+02 4/2/2009 4.14E+02 4.14E+02 4/3/2009 4.45E+02 4.45E+02 4/4/2009 4.86E+02 4.86E+02 4/5/2009 6.26E+02 6.26E+02 4/6/2009 4.82E+02 4.82E+02 4/7/2009 7.67E+02 7.67E+02 4/8/2009 7.65E+02 7.65E+02 4/9/2009 1.02E+03 1.02E+03 4/10/2009 #DIV/0! 4/11/2009 #DIV/0! 4/12/2009 #DIV/0! 4/13/2009 #DIV/0! 4/14/2009 #DIV/0! 4/15/2009 #DIV/0! 4/16/2009 #DIV/0! 4/17/2009 #DIV/0! 4/18/2009 4.80E+02 4.80E+02 4/19/2009 5.47E+02 5.47E+02 4/20/2009 5.25E+02 5.25E+02 4/21/2009 4.37E+02 4.37E+02 4/22/2009 4.79E+02 4.79E+02 4/23/2009 4.86E+02 4.86E+02 4/24/2009 3.28E+02 3.28E+02 4/25/2009 #DIV/0! 4/26/2009 #DIV/0! 4/27/2009 3.05E+02 3.05E+02 4/28/2009 1.44E+02 1.44E+02 4/29/2009 3.90E+02 3.90E+02 4/30/2009 3.87E+02 3.87E+02 5/1/2009 4.74E+02 4.74E+02 5/2/2009 4.85E+02 4.85E+02 5/3/2009 6.30E+02 6.30E+02 5/4/2009 4.03E+02 4.03E+02 5/5/2009 3.24E+02 3.24E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

5/6/2009 3.35E+02 3.35E+02 5/7/2009 3.56E+02 3.56E+02 5/8/2009 4.84E+02 4.84E+02 5/9/2009 4.88E+02 4.88E+02 5/10/2009 4.21E+02 4.21E+02 5/11/2009 4.97E+02 4.97E+02 5/12/2009 4.79E+02 4.79E+02 5/13/2009 3.15E+02 3.15E+02 5/14/2009 3.71E+02 3.71E+02 5/15/2009 6.07E+02 6.07E+02 5/16/2009 #DIV/0! 5/17/2009 #DIV/0! 5/18/2009 2.98E+02 2.98E+02 5/19/2009 #DIV/0! 5/20/2009 #DIV/0! 5/21/2009 #DIV/0! 5/22/2009 5.55E+02 5.55E+02 5/23/2009 7.19E+02 7.19E+02 5/24/2009 5.98E+02 5.98E+02 5/25/2009 #DIV/0! 5/26/2009 #DIV/0! 5/27/2009 7.52E+02 7.52E+02 5/28/2009 8.06E+02 8.06E+02 5/29/2009 7.20E+02 7.20E+02 5/30/2009 #DIV/0! 5/31/2009 #DIV/0! 6/1/2009 5.70E+02 5.70E+02 6/2/2009 3.88E+02 3.88E+02 6/3/2009 4.18E+02 4.18E+02 6/4/2009 3.24E+02 3.24E+02 6/5/2009 3.26E+02 3.26E+02 6/6/2009 4.63E+02 4.63E+02 6/7/2009 5.40E+02 5.40E+02 6/8/2009 4.66E+02 4.66E+02 6/9/2009 4.75E+02 4.75E+02 6/10/2009 5.40E+02 5.40E+02 6/11/2009 5.21E+02 5.21E+02 6/12/2009 3.75E+02 3.75E+02 6/13/2009 5.04E+02 5.04E+02 6/14/2009 5.00E+02 5.00E+02 6/15/2009 4.17E+02 4.17E+02 6/16/2009 2.68E+02 2.68E+02 6/17/2009 4.62E+02 4.62E+02 6/18/2009 4.90E+02 4.90E+02 6/19/2009 9.48E+02 9.48E+02 6/20/2009 #DIV/0! 6/21/2009 #DIV/0! 6/22/2009 5.77E+02 5.77E+02 6/23/2009 7.49E+02 7.49E+02 6/24/2009 5.95E+02 5.95E+02 6/25/2009 6.81E+02 6.81E+02 6/26/2009 5.70E+02 5.70E+02 6/27/2009 8.12E+02 8.12E+02 6/28/2009 #DIV/0! 6/29/2009 3.60E+02 3.60E+02 6/30/2009 #DIV/0! 7/1/2009 2.07E+02 2.07E+02 7/2/2009 3.77E+02 3.77E+02 7/3/2009 #DIV/0! 7/4/2009 #DIV/0! 7/5/2009 #DIV/0! 7/6/2009 4.21E+02 4.21E+02 7/7/2009 5.31E+02 5.31E+02 7/8/2009 5.49E+02 5.49E+02 7/9/2009 6.04E+02 6.04E+02 7/10/2009 7.69E+02 7.69E+02 7/11/2009 5.41E+02 5.41E+02 7/12/2009 5.21E+02 5.21E+02 7/13/2009 3.98E+02 3.98E+02 7/14/2009 4.97E+02 4.97E+02 7/15/2009 5.66E+02 5.66E+02 7/16/2009 8.74E+02 8.74E+02 7/17/2009 4.59E+02 4.59E+02 7/18/2009 8.07E+02 8.07E+02 7/19/2009 2.56E+02 2.56E+02 7/20/2009 3.84E+02 3.84E+02 7/21/2009 3.49E+02 3.49E+02 7/22/2009 5.14E+02 5.14E+02 7/23/2009 3.25E+02 3.25E+02 7/24/2009 5.09E+02 5.09E+02 7/25/2009 3.85E+02 3.85E+02 7/26/2009 3.10E+02 3.10E+02 7/27/2009 2.52E+02 2.52E+02 7/28/2009 4.49E+02 4.49E+02 7/29/2009 4.04E+02 4.04E+02 7/30/2009 6.01E+02 6.01E+02 7/31/2009 3.48E+02 3.48E+02 8/1/2009 3.44E+02 3.44E+02 8/2/2009 6.31E+02 6.31E+02 8/3/2009 4.27E+02 4.27E+02 8/4/2009 4.39E+02 4.39E+02 8/5/2009 4.63E+02 4.63E+02 8/6/2009 3.50E+02 3.50E+02 8/7/2009 3.83E+02 3.83E+02 8/8/2009 4.38E+02 4.38E+02 8/9/2009 5.47E+02 5.47E+02 8/10/2009 6.41E+02 6.41E+02 8/11/2009 6.35E+02 6.35E+02 8/12/2009 6.90E+02 6.90E+02 8/13/2009 6.44E+02 6.44E+02 8/14/2009 5.84E+02 5.84E+02 8/15/2009 4.92E+02 4.92E+02 8/16/2009 7.17E+02 7.17E+02 8/17/2009 4.39E+02 4.39E+02 8/18/2009 4.48E+02 4.48E+02 8/19/2009 3.76E+02 3.76E+02 8/20/2009 2.79E+02 2.79E+02 8/21/2009 4.07E+02 4.07E+02 8/22/2009 4.06E+02 4.06E+02 8/23/2009 3.84E+02 3.84E+02 8/24/2009 3.57E+02 3.57E+02 8/25/2009 3.99E+02 3.99E+02 8/26/2009 4.17E+02 4.17E+02 8/27/2009 4.07E+02 4.07E+02 8/28/2009 4.18E+02 4.18E+02 8/29/2009 5.13E+02 5.13E+02 8/30/2009 6.27E+02 6.27E+02 8/31/2009 9.29E+02 9.29E+02 9/1/2009 7.20E+02 7.20E+02 9/2/2009 5.57E+02 5.57E+02 9/3/2009 6.03E+02 6.03E+02 9/4/2009 4.76E+02 4.76E+02 9/5/2009 4.99E+02 4.99E+02 9/6/2009 6.22E+02 6.22E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

9/7/2009 8.02E+02 8.02E+02 9/8/2009 5.64E+02 5.64E+02 9/9/2009 5.53E+02 5.53E+02 9/10/2009 5.31E+02 5.31E+02 9/11/2009 6.37E+02 6.37E+02 9/12/2009 5.76E+02 5.76E+02 9/13/2009 5.98E+02 5.98E+02 9/14/2009 4.38E+02 4.38E+02 9/15/2009 5.50E+02 5.50E+02 9/16/2009 5.92E+02 5.92E+02 9/17/2009 3.55E+02 3.55E+02 9/18/2009 5.11E+02 5.11E+02 9/19/2009 3.71E+02 3.71E+02 9/20/2009 5.88E+02 5.88E+02 9/21/2009 5.73E+02 5.73E+02 9/22/2009 4.92E+02 4.92E+02 9/23/2009 3.23E+02 3.23E+02 9/24/2009 3.94E+02 3.94E+02 9/25/2009 3.60E+02 3.60E+02 9/26/2009 3.11E+02 3.11E+02 9/27/2009 4.24E+02 4.24E+02 9/28/2009 4.34E+02 4.34E+02 9/29/2009 4.73E+02 4.73E+02 9/30/2009 4.54E+02 4.54E+02 10/1/2009 5.03E+02 5.03E+02 10/2/2009 5.50E+02 5.50E+02 10/3/2009 6.22E+02 6.22E+02 10/4/2009 6.36E+02 6.36E+02 10/5/2009 5.05E+02 5.05E+02 10/6/2009 4.94E+02 4.94E+02 10/7/2009 4.90E+02 4.90E+02 10/8/2009 6.90E+02 6.90E+02 10/9/2009 4.76E+02 4.76E+02 10/10/2009 7.66E+02 7.66E+02 10/11/2009 1.36E+02 1.36E+02 10/12/2009 4.05E+02 4.05E+02 10/13/2009 5.64E+02 5.64E+02 10/14/2009 6.15E+02 6.15E+02 10/15/2009 4.01E+02 4.01E+02 10/16/2009 5.30E+02 5.30E+02 10/17/2009 6.91E+02 6.91E+02 10/18/2009 6.29E+02 6.29E+02 10/19/2009 7.84E+02 7.84E+02 10/20/2009 5.21E+02 5.21E+02 10/21/2009 4.05E+02 4.05E+02 10/22/2009 4.90E+02 4.90E+02 10/23/2009 4.65E+02 4.65E+02 10/24/2009 3.58E+02 3.58E+02 10/25/2009 6.58E+02 6.58E+02 10/26/2009 5.31E+02 5.31E+02 10/27/2009 5.32E+02 5.32E+02 10/28/2009 3.18E+02 3.18E+02 10/29/2009 8.04E+02 8.04E+02 10/30/2009 7.02E+02 7.02E+02 10/31/2009 1.99E+02 1.99E+02 11/1/2009 5.35E+02 5.35E+02 11/2/2009 5.41E+02 5.41E+02 11/3/2009 3.46E+02 3.46E+02 11/4/2009 6.33E+02 6.33E+02 11/5/2009 4.69E+02 4.69E+02 11/6/2009 4.34E+02 4.34E+02 11/7/2009 5.16E+02 5.16E+02 11/8/2009 5.86E+02 5.86E+02 11/9/2009 4.05E+02 4.05E+02 11/10/2009 4.61E+02 4.61E+02 11/11/2009 5.98E+02 5.98E+02 11/12/2009 1.03E+03 1.03E+03 11/13/2009 5.81E+02 5.81E+02 11/14/2009 4.40E+02 4.40E+02 11/15/2009 5.02E+02 5.02E+02 11/16/2009 3.74E+02 3.74E+02 11/17/2009 4.57E+02 4.57E+02 11/18/2009 4.35E+02 4.35E+02 11/19/2009 2.66E+02 2.66E+02 11/20/2009 7.69E+02 7.69E+02 11/21/2009 8.37E+02 8.37E+02 11/22/2009 1.20E+03 1.20E+03 11/23/2009 7.45E+02 7.45E+02 11/24/2009 8.53E+02 8.53E+02 11/25/2009 6.44E+02 6.44E+02 11/26/2009 1.22E+03 1.22E+03 11/27/2009 8.09E+02 8.09E+02 11/28/2009 2.21E+02 2.21E+02 11/29/2009 3.24E+02 3.24E+02 11/30/2009 3.29E+02 3.29E+02 12/1/2009 3.28E+02 3.28E+02 12/2/2009 2.28E+02 2.28E+02 12/3/2009 5.20E+02 5.20E+02 12/4/2009 5.21E+02 5.21E+02 12/5/2009 4.67E+02 4.67E+02 12/6/2009 7.20E+02 7.20E+02 12/7/2009 6.73E+02 6.73E+02 12/8/2009 5.32E+02 5.32E+02 12/9/2009 6.78E+02 6.78E+02 12/10/2009 4.21E+02 4.21E+02 12/11/2009 5.48E+02 5.48E+02 12/12/2009 4.77E+02 4.77E+02 12/13/2009 4.26E+02 4.26E+02 12/14/2009 5.38E+02 5.38E+02 12/15/2009 5.65E+02 5.65E+02 12/16/2009 4.54E+02 4.54E+02 12/17/2009 5.09E+02 5.09E+02 12/18/2009 4.00E+02 4.00E+02 12/19/2009 8.22E+02 8.22E+02 12/20/2009 6.02E+02 6.02E+02 12/21/2009 1.12E+03 1.12E+03 12/22/2009 #DIV/0! 12/23/2009 1.20E+03 1.20E+03 12/24/2009 5.31E+02 5.31E+02 12/25/2009 1.03E+03 1.03E+03 12/26/2009 1.04E+03 1.04E+03 12/27/2009 6.80E+02 6.80E+02 12/28/2009 5.70E+02 5.70E+02 12/29/2009 8.68E+02 8.68E+02 12/30/2009 8.53E+02 8.53E+02 12/31/2009 6.44E+02 6.44E+02 1/1/2010 3.06E+02 3.06E+02 1/2/2010 3.73E+02 3.73E+02 1/3/2010 6.43E+02 6.43E+02 1/4/2010 3.11E+02 3.11E+02 1/5/2010 2.38E+02 2.38E+02 1/6/2010 2.00E+02 2.00E+02 1/7/2010 4.52E+02 4.52E+02 1/8/2010 3.09E+02 3.09E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

1/9/2010 5.93E+02 5.93E+02 1/10/2010 7.19E+02 7.19E+02 1/11/2010 3.41E+02 3.41E+02 1/12/2010 3.84E+02 3.84E+02 1/13/2010 5.17E+02 5.17E+02 1/14/2010 3.72E+02 3.72E+02 1/15/2010 3.94E+02 3.94E+02 1/16/2010 6.61E+02 6.61E+02 1/17/2010 7.40E+02 7.40E+02 1/18/2010 5.47E+02 5.47E+02 1/19/2010 1.25E+03 1.25E+03 1/20/2010 9.25E+02 9.25E+02 1/21/2010 8.20E+02 8.20E+02 1/22/2010 1.16E+03 1.16E+03 1/23/2010 7.71E+02 7.71E+02 1/24/2010 7.29E+02 7.29E+02 1/25/2010 4.45E+02 4.45E+02 1/26/2010 7.39E+02 7.39E+02 1/27/2010 5.20E+02 5.20E+02 1/28/2010 8.92E+02 8.92E+02 1/29/2010 5.87E+02 5.87E+02 1/30/2010 9.63E+02 9.63E+02 1/31/2010 8.73E+02 8.73E+02 2/1/2010 5.00E+02 5.00E+02 2/2/2010 5.81E+02 5.81E+02 2/3/2010 8.23E+02 8.23E+02 2/4/2010 5.82E+02 5.82E+02 2/5/2010 6.52E+02 6.52E+02 2/6/2010 5.59E+02 5.59E+02 2/7/2010 5.88E+02 5.88E+02 2/8/2010 6.05E+02 6.05E+02 2/9/2010 8.39E+02 8.39E+02 2/10/2010 5.85E+02 5.85E+02 2/11/2010 6.38E+02 6.38E+02 2/12/2010 6.98E+02 6.98E+02 2/13/2010 2.79E+02 2.79E+02 2/14/2010 3.04E+02 3.04E+02 2/15/2010 7.45E+02 7.45E+02 2/16/2010 4.84E+02 4.84E+02 2/17/2010 5.36E+02 5.36E+02 2/18/2010 3.94E+02 3.94E+02 2/19/2010 5.14E+02 5.14E+02 2/20/2010 3.69E+02 3.69E+02 2/21/2010 1.87E+02 1.87E+02 2/22/2010 2.83E+02 2.83E+02 2/23/2010 3.78E+02 3.78E+02 2/24/2010 1.71E+02 1.71E+02 2/25/2010 2.27E+02 2.27E+02 2/26/2010 3.27E+02 3.27E+02 2/27/2010 2.38E+02 2.38E+02 2/28/2010 2.15E+02 2.15E+02 3/1/2010 6.60E+02 6.60E+02 3/2/2010 6.31E+02 6.31E+02 3/3/2010 6.76E+02 6.76E+02 3/4/2010 #DIV/0! 3/5/2010 8.09E+02 8.09E+02 3/6/2010 6.53E+02 6.53E+02 3/7/2010 7.38E+02 7.38E+02 3/8/2010 5.90E+02 5.90E+02 3/9/2010 7.42E+02 7.42E+02 3/10/2010 6.28E+02 6.28E+02 3/11/2010 7.31E+02 7.31E+02 3/12/2010 6.39E+02 6.39E+02 3/13/2010 5.68E+02 5.68E+02 3/14/2010 5.89E+02 5.89E+02 3/15/2010 6.98E+02 6.98E+02 3/16/2010 8.18E+02 8.18E+02 3/17/2010 4.74E+02 4.74E+02 3/18/2010 4.72E+02 4.72E+02 3/19/2010 5.76E+02 5.76E+02 3/20/2010 4.92E+02 4.92E+02 3/21/2010 4.25E+02 4.25E+02 3/22/2010 4.43E+02 4.43E+02 3/23/2010 4.15E+02 4.15E+02 3/24/2010 5.52E+02 5.52E+02 3/25/2010 5.52E+02 5.52E+02 3/26/2010 5.67E+02 5.67E+02 3/27/2010 7.52E+02 7.52E+02 3/28/2010 4.65E+02 4.65E+02 3/29/2010 4.09E+02 4.09E+02 3/30/2010 3.08E+02 3.08E+02 3/31/2010 6.06E+02 6.06E+02 4/1/2010 1.02E+03 1.02E+03 4/2/2010 1.56E+02 1.56E+02 4/3/2010 3.49E+02 3.49E+02 4/4/2010 3.48E+02 3.48E+02 4/5/2010 3.18E+02 3.18E+02 4/6/2010 4.50E+02 4.50E+02 4/7/2010 2.59E+02 2.59E+02 4/8/2010 3.18E+02 3.18E+02 4/9/2010 3.10E+02 3.10E+02 4/10/2010 4.20E+02 4.20E+02 4/11/2010 3.73E+02 3.73E+02 4/12/2010 4.58E+02 4.58E+02 4/13/2010 4.02E+02 4.02E+02 4/14/2010 7.34E+02 7.34E+02 4/15/2010 4.74E+02 4.74E+02 4/16/2010 8.19E+02 8.19E+02 4/17/2010 4.81E+02 4.81E+02 4/18/2010 6.83E+02 6.83E+02 4/19/2010 3.27E+02 3.27E+02 4/20/2010 5.94E+02 5.94E+02 4/21/2010 5.57E+02 5.57E+02 4/22/2010 4.97E+02 4.97E+02 4/23/2010 6.07E+02 6.07E+02 4/24/2010 5.49E+02 5.49E+02 4/25/2010 8.99E+02 8.99E+02 4/26/2010 6.72E+02 6.72E+02 4/27/2010 7.47E+02 7.47E+02 4/28/2010 6.60E+02 6.60E+02 4/29/2010 4.61E+02 4.61E+02 4/30/2010 5.16E+02 5.16E+02 5/1/2010 7.37E+02 7.37E+02 5/2/2010 6.32E+02 6.32E+02 5/3/2010 7.05E+02 7.05E+02 5/4/2010 6.66E+02 6.66E+02 5/5/2010 6.50E+02 6.50E+02 5/6/2010 3.50E+02 3.50E+02 5/7/2010 4.16E+02 4.16E+02 5/8/2010 4.51E+02 4.51E+02 5/9/2010 3.92E+02 3.92E+02 5/10/2010 3.83E+02 3.83E+02 5/11/2010 4.16E+02 4.16E+02 5/12/2010 3.16E+02 3.16E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

5/13/2010 1.92E+02 1.92E+02 5/14/2010 3.98E+02 3.98E+02 5/15/2010 5.77E+02 5.77E+02 5/16/2010 5.33E+02 5.33E+02 5/17/2010 4.74E+02 4.74E+02 5/18/2010 8.19E+02 8.19E+02 5/19/2010 7.77E+02 7.77E+02 5/20/2010 4.49E+02 4.49E+02 5/21/2010 3.36E+02 3.36E+02 5/22/2010 4.18E+02 4.18E+02 5/23/2010 3.81E+02 3.81E+02 5/24/2010 7.21E+02 7.21E+02 5/25/2010 6.85E+02 6.85E+02 5/26/2010 7.63E+02 7.63E+02 5/27/2010 7.58E+02 7.58E+02 5/28/2010 6.87E+02 6.87E+02 5/29/2010 6.35E+02 6.35E+02 5/30/2010 9.25E+02 9.25E+02 5/31/2010 2.16E+02 2.16E+02 6/1/2010 2.49E+02 2.49E+02 6/2/2010 1.00E+02 1.00E+02 6/3/2010 3.47E+02 3.47E+02 6/4/2010 6.84E+02 6.84E+02 6/5/2010 4.64E+02 4.64E+02 6/6/2010 4.54E+02 4.54E+02 6/7/2010 2.88E+02 2.88E+02 6/8/2010 3.48E+02 3.48E+02 6/9/2010 3.05E+02 3.05E+02 6/10/2010 3.40E+02 3.40E+02 6/11/2010 3.40E+02 3.40E+02 6/12/2010 3.30E+02 3.30E+02 6/13/2010 3.50E+02 3.50E+02 6/14/2010 3.65E+02 3.65E+02 6/15/2010 4.14E+02 4.14E+02 6/16/2010 5.84E+02 5.84E+02 6/17/2010 4.72E+02 4.72E+02 6/18/2010 5.38E+02 5.38E+02 6/19/2010 4.95E+02 4.95E+02 6/20/2010 5.28E+02 5.28E+02 6/21/2010 4.41E+02 4.41E+02 6/22/2010 5.04E+02 5.04E+02 6/23/2010 5.23E+02 5.23E+02 6/24/2010 4.16E+02 4.16E+02 6/25/2010 5.15E+02 5.15E+02 6/26/2010 4.66E+02 4.66E+02 6/27/2010 5.11E+02 5.11E+02 6/28/2010 3.54E+02 3.54E+02 6/29/2010 5.11E+02 5.11E+02 6/30/2010 4.22E+02 4.22E+02 7/1/2010 5.62E+02 5.62E+02 7/2/2010 7.45E+02 7.45E+02 7/3/2010 6.61E+02 6.61E+02 7/4/2010 5.99E+02 5.99E+02 7/5/2010 4.99E+02 4.99E+02 7/6/2010 7.77E+02 7.77E+02 7/7/2010 4.05E+02 4.05E+02 7/8/2010 6.28E+02 6.28E+02 7/9/2010 7.22E+02 7.22E+02 7/10/2010 6.44E+02 6.44E+02 7/11/2010 5.27E+02 5.27E+02 7/12/2010 4.55E+02 4.55E+02 7/13/2010 5.05E+02 5.05E+02 7/14/2010 4.19E+02 4.19E+02 7/15/2010 5.48E+02 5.48E+02 7/16/2010 4.64E+02 4.64E+02 7/17/2010 5.38E+02 5.38E+02 7/18/2010 3.85E+02 3.85E+02 7/19/2010 4.21E+02 4.21E+02 7/20/2010 5.63E+02 5.63E+02 7/21/2010 5.58E+02 5.58E+02 7/22/2010 5.88E+02 5.88E+02 7/23/2010 5.87E+02 5.87E+02 7/24/2010 6.73E+02 6.73E+02 7/25/2010 4.07E+02 4.07E+02 7/26/2010 1.00E+03 1.00E+03 7/27/2010 6.35E+02 6.35E+02 7/28/2010 5.26E+02 5.26E+02 7/29/2010 4.39E+02 4.39E+02 7/30/2010 5.99E+02 5.99E+02 7/31/2010 3.87E+02 3.87E+02 8/1/2010 4.48E+02 4.48E+02 8/2/2010 4.39E+02 4.39E+02 8/3/2010 3.70E+02 3.70E+02 8/4/2010 3.92E+02 3.92E+02 8/5/2010 4.25E+02 4.25E+02 8/6/2010 4.10E+02 4.10E+02 8/7/2010 3.99E+02 3.99E+02 8/8/2010 6.43E+02 6.43E+02 8/9/2010 7.73E+02 7.73E+02 8/10/2010 7.36E+02 7.36E+02 8/11/2010 7.79E+02 7.79E+02 8/12/2010 7.10E+02 7.10E+02 8/13/2010 6.69E+02 6.69E+02 8/14/2010 8.29E+02 8.29E+02 8/15/2010 1.44E+03 1.44E+03 8/16/2010 7.36E+02 7.36E+02 8/17/2010 8.86E+02 8.86E+02 8/18/2010 5.97E+02 5.97E+02 8/19/2010 4.84E+02 4.84E+02 8/20/2010 7.84E+02 7.84E+02 8/21/2010 7.05E+02 7.05E+02 8/22/2010 6.88E+02 6.88E+02 8/23/2010 5.87E+02 5.87E+02 8/24/2010 5.67E+02 5.67E+02 8/25/2010 6.86E+02 6.86E+02 8/26/2010 6.44E+02 6.44E+02 8/27/2010 5.79E+02 5.79E+02 8/28/2010 5.80E+02 5.80E+02 8/29/2010 5.79E+02 5.79E+02 8/30/2010 3.75E+02 3.75E+02 8/31/2010 3.00E+02 3.00E+02 9/1/2010 3.43E+02 3.43E+02 9/2/2010 3.52E+02 3.52E+02 9/3/2010 6.15E+02 6.15E+02 9/4/2010 5.74E+02 5.74E+02 9/5/2010 6.76E+02 6.76E+02 9/6/2010 5.60E+02 5.60E+02 9/7/2010 4.97E+02 4.97E+02 9/8/2010 5.75E+02 5.75E+02 9/9/2010 4.96E+02 4.96E+02 9/10/2010 4.87E+02 4.87E+02 9/11/2010 8.80E+02 8.80E+02 9/12/2010 9.69E+02 9.69E+02 9/13/2010 5.18E+02 5.18E+02

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing Area Sources - VC**

9/14/2010 4.56E+02 4.56E+02 9/15/2010 7.16E+02 7.16E+02 9/16/2010 5.36E+02 5.36E+02 9/17/2010 2.30E+02 2.30E+02 9/18/2010 2.83E+02 2.83E+02 9/19/2010 2.61E+02 2.61E+02 9/20/2010 3.52E+02 3.52E+02 9/21/2010 2.82E+02 2.82E+02 9/22/2010 3.18E+02 3.18E+02 9/23/2010 3.67E+02 3.67E+02 9/24/2010 5.19E+02 5.19E+02 9/25/2010 4.50E+02 4.50E+02 9/26/2010 3.92E+02 3.92E+02 9/27/2010 2.99E+02 2.99E+02 9/28/2010 3.17E+02 3.17E+02 9/29/2010 2.44E+02 2.44E+02 9/30/2010 5.66E+02 5.66E+02 10/1/2010 4.51E+02 4.51E+02 10/2/2010 5.40E+02 5.40E+02 10/3/2010 4.66E+02 4.66E+02 10/4/2010 3.19E+02 3.19E+02 10/5/2010 2.84E+02 2.84E+02 10/6/2010 5.19E+02 5.19E+02 10/7/2010 3.37E+02 3.37E+02 10/8/2010 4.10E+02 4.10E+02 10/9/2010 3.83E+02 3.83E+02 10/10/2010 #DIV/0! 10/11/2010 4.58E+02 4.58E+02 10/12/2010 4.43E+02 4.43E+02 10/13/2010 3.78E+02 3.78E+02 10/14/2010 8.01E+02 8.01E+02 10/15/2010 5.98E+02 5.98E+02 10/16/2010 6.41E+02 6.41E+02 10/17/2010 7.28E+02 7.28E+02 10/18/2010 5.36E+02 5.36E+02 10/19/2010 5.40E+02 5.40E+02 10/20/2010 5.14E+02 5.14E+02 10/21/2010 6.55E+02 6.55E+02 10/22/2010 4.52E+02 4.52E+02 10/23/2010 4.11E+02 4.11E+02 10/24/2010 2.93E+02 2.93E+02 10/25/2010 3.02E+02 3.02E+02 10/26/2010 3.01E+02 3.01E+02 10/27/2010 5.13E+02 5.13E+02 10/28/2010 4.05E+02 4.05E+02 10/29/2010 4.15E+02 4.15E+02 10/30/2010 8.78E+02 8.78E+02 10/31/2010 4.38E+02 4.38E+02 11/1/2010 6.52E+02 6.52E+02 11/2/2010 5.56E+02 5.56E+02 11/3/2010 5.57E+02 5.57E+02 11/4/2010 5.08E+02 5.08E+02 11/5/2010 4.92E+02 4.92E+02 11/6/2010 6.26E+02 6.26E+02 11/7/2010 5.99E+02 5.99E+02 11/8/2010 8.67E+02 8.67E+02 11/9/2010 3.65E+02 3.65E+02 11/10/2010 4.70E+02 4.70E+02 11/11/2010 1.40E+03 1.40E+03 11/12/2010 4.61E+02 4.61E+02 11/13/2010 5.15E+02 5.15E+02 11/14/2010 4.99E+02 4.99E+02 11/15/2010 5.21E+02 5.21E+02 11/16/2010 4.62E+02 4.62E+02 11/17/2010 3.45E+02 3.45E+02 11/18/2010 3.89E+02 3.89E+02 11/19/2010 2.25E+02 2.25E+02 11/20/2010 3.77E+02 3.77E+02 11/21/2010 4.81E+02 4.81E+02 11/22/2010 5.27E+02 5.27E+02 11/23/2010 5.39E+02 5.39E+02 11/24/2010 3.74E+02 3.74E+02 11/25/2010 4.56E+02 4.56E+02 11/26/2010 5.46E+02 5.46E+02 11/27/2010 5.20E+02 5.20E+02 11/28/2010 5.69E+02 5.69E+02 11/29/2010 6.50E+02 6.50E+02 11/30/2010 4.88E+02 4.88E+02 12/1/2010 5.70E+02 5.70E+02 12/2/2010 6.69E+02 6.69E+02 12/3/2010 6.67E+02 6.67E+02 12/4/2010 6.14E+02 6.14E+02 12/5/2010 5.29E+02 5.29E+02 12/6/2010 9.22E+02 9.22E+02 12/7/2010 1.61E+03 1.61E+03 12/8/2010 4.80E+02 4.80E+02 12/9/2010 5.66E+02 5.66E+02 12/10/2010 5.23E+02 5.23E+02 12/11/2010 5.61E+02 5.61E+02 12/12/2010 4.53E+02 4.53E+02 12/13/2010 5.76E+02 5.76E+02 12/14/2010 6.07E+02 6.07E+02 12/15/2010 5.44E+02 5.44E+02 12/16/2010 3.97E+02 3.97E+02 12/17/2010 3.57E+02 3.57E+02 12/18/2010 4.70E+02 4.70E+02 12/19/2010 5.37E+02 5.37E+02 12/20/2010 4.35E+02 4.35E+02 12/21/2010 4.20E+02 4.20E+02 12/22/2010 3.34E+02 3.34E+02 12/23/2010 3.80E+02 3.80E+02 12/24/2010 9.17E+02 9.17E+02 12/25/2010 8.10E+02 8.10E+02 12/26/2010 7.58E+02 7.58E+02 12/27/2010 5.59E+02 5.59E+02 12/28/2010 7.55E+02 7.55E+02 12/29/2010 8.63E+02 8.63E+02 12/30/2010 1.08E+03 1.08E+03 12/31/2010 #DIV/0!

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**New**

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing A rea Sources - Total Non-VC HA** **P**

**GACT Worst Performer Determination**

Method Method 8260B Resin Type Dispersion HAP (0=no, 1=yes) 1 Wet Resin From Stripper Bottoms Exclude Data (0=no, 1=yes) 0

Average of Wet Resin from Stripper Bottoms, ppm Analyte_Std

Reporting Plant Sample Date AcetaldehydeAcetophenone Cumene Ethyl Chloride Ethylene

DichlorideEthylidene

Dichloride Formaldehyde Methanol Methyl Chloride

FPC DE 1/12/2010 1.06E+01 6.25E+00 7.87E-01 2.46E-011.10E+01 2.20E-01 1/13/2010 9.29E+00 1.01E+011.15E+00 7.09E-015.90E+00 3.64E-01 1/14/2010 1.16E+01 5.81E+001.03E+00 4.55E-011.10E+01 2.13E-01 1/15/2010 6.69E+00 6.10E+00 6.82E-01 1.40E-011.20E+01 2.40E-01 1/16/2010 1.29E+01 1.02E+01 6.47E-01 2.13E-01 1.20E-01 1.30E-01 1/17/2010 2.38E+01 1.44E+01 5.69E-01 2.77E-01 1.20E-01 2.50E-01 1/18/2010 1.41E+01 1.24E+01 5.94E-01 1.40E-015.90E+00 2.50E-01 1/19/2010 1.69E+01 4.38E+00 3.61E-01 1.40E-019.80E+00 1.60E-01 1/20/2010 1.28E+01 1.63E+01 8.86E-01 1.49E-019.10E+00 2.20E-01 1/29/2010 4.70E+01 1.96E+011.12E+00 3.74E-011.00E+01 8.49E-01 1/30/2010 3.62E+01 7.29E+00 4.48E-01 1.50E-011.00E+01 2.80E-01 1/31/2010 3.18E+01 4.30E+00 2.72E-01 1.83E-011.30E+01 2.30E-01 2/1/2010 1.14E+01 6.36E+00 3.82E-01 1.40E-015.80E+00 2.93E-01 2/2/2010 4.00E+00 1.12E+011.35E+00 6.90E-01 1.80E-01 2.20E-01 2/3/2010 2.53E+00 1.03E+011.35E+00 6.80E-01 1.10E-01 4.20E-01 2/4/2010 2.68E+00 8.99E+001.35E+00 6.80E-01 1.10E-01 2.10E-01 2/6/2010 5.32E+00 9.72E+001.14E+00 3.90E-011.10E+00 2.20E-01 2/7/2010 3.84E+00 9.04E+001.20E+00 3.61E-011.10E+00 5.80E-01 2/10/2010 1.43E+00 8.09E+00 4.75E-01 3.43E-011.20E+00 1.20E-01 2/11/2010 2.26E+00 1.46E+01 7.15E-01 5.44E-011.20E+00 2.30E-01 2/13/2010 5.18E-01 6.33E+00 4.44E-01 1.40E-011.20E+00 1.20E-01 P1-Henry 12/9/2009 6.60E+001.30E+016.60E+00 6.60E+00 1.30E+01 12/10/2009 3.70E+007.40E+003.70E+00 3.70E+00 7.40E+00 12/11/2009 1.40E+002.80E+001.40E+00 1.40E+00 2.80E+00 12/12/2009 1.80E+003.50E+001.80E+00 1.80E+00 3.50E+00 12/13/2009 1.80E+003.50E+001.80E+00 1.80E+00 3.50E+00 12/14/2009 1.70E-01 3.50E-01 1.70E-01 1.70E-01 3.50E-01 12/15/2009 1.80E+003.60E+001.80E+00 1.80E+00 3.60E+00 12/16/2009 1.60E+003.20E+001.60E+00 1.60E+00 3.20E+00 12/17/2009 1.90E-01 3.80E-01 1.90E-01 1.90E-01 3.80E-01 12/18/2009 4.40E+008.80E+004.40E+00 4.40E+00 8.80E+00 12/19/2009 2.70E+005.50E+002.70E+00 2.70E+00 5.50E+00 12/20/2009 5.20E+001.00E+015.20E+00 5.20E+00 1.00E+01 1/5/2010 8.10E+008.10E+008.10E+00 8.10E+00 1.60E+01 1/6/2010 3.40E+003.40E+003.40E+00 3.40E+00 6.80E+00 1/7/2010 3.60E+003.60E+003.60E+00 3.60E+00 7.10E+00 1/8/2010 6.40E+006.40E+006.40E+00 6.40E+00 1.30E+01 1/9/2010 5.40E+005.40E+005.40E+00 5.40E+00 1.10E+01 1/10/2010 3.70E+003.70E+003.70E+00 3.70E+00 7.40E+00 1/11/2010 4.20E+004.20E+004.20E+00 4.20E+00 8.50E+00 1/12/2010 4.20E+004.20E+004.20E+00 4.20E+00 8.30E+00 1/13/2010 5.10E+005.10E+005.10E+00 5.10E+00 1.00E+01 1/14/2010 4.90E+004.90E+004.90E+00 4.90E+00 9.80E+00 1/15/2010 5.10E+005.10E+005.10E+00 5.10E+00 1.00E+01 1/16/2010 3.30E+003.30E+003.30E+00 3.30E+00 6.70E+00 1/17/2010 1.10E+011.10E+011.10E+01 1.10E+01 2.20E+01 1/18/2010 1.10E+011.10E+011.10E+01 1.10E+01 2.30E+01 1/19/2010 4.60E+004.60E+004.60E+00 4.60E+00 9.20E+00 1/20/2010 3.80E+003.80E+003.80E+00 3.80E+00 7.60E+00 1/21/2010 1.70E+001.70E+001.70E+00 1.70E+00 3.30E+00 1/22/2010 5.30E+005.30E+005.30E+00 5.30E+00 1.10E+01 P1-Ptown 12/2/2009 6.00E-02 1.10E+00 2.00E-016.40E+00 1.42E-01 5.50E-02 4.73E-011.57E+01 7.73E-01 12/3/2009 6.00E-02 2.30E+00 2.10E-016.30E+00 1.40E-01 5.50E-02 5.23E-011.11E+01 6.43E-01 12/4/2009 9.56E-02 1.10E+00 2.10E-011.74E+01 2.38E-01 7.54E-02 6.36E-011.22E+01 9.66E-01 12/5/2009 4.70E-02 1.80E+00 1.60E-013.68E+00 2.07E-01 9.22E-02 1.56E-01 4.80E-02 5.00E-02 12/6/2009 2.67E-01 2.75E+01 6.74E-013.68E+01 4.42E-01 1.10E-01 3.95E-013.10E+004.42E+00 12/7/2009 5.52E-01 2.20E+00 9.32E-015.43E+01 7.56E-01 2.13E-01 3.41E-012.02E+025.55E+00 12/8/2009 2.64E-01 2.30E+00 4.00E-012.10E+01 4.72E-01 1.22E-01 6.31E-012.85E+011.16E+00 12/9/2009 3.42E-01 2.30E+00 3.70E-012.84E+01 6.01E-01 1.29E-01 5.10E-015.80E+003.20E+00 12/10/2009 4.14E-01 2.30E+00 7.70E-013.94E+01 5.17E-01 2.00E-01 3.89E-016.30E+005.45E+00 12/11/2009 4.82E-01 1.59E+011.81E+005.44E+01 8.29E-01 1.30E-01 3.43E-011.20E+013.41E+00 12/12/2009 12/13/2009 4.20E-01 2.20E+00 4.00E-014.73E+01 5.95E-01 1.10E-01 3.81E-011.30E+014.10E+00 12/14/2009 1.09E-01 2.30E+00 7.40E-014.16E+01 9.54E-01 2.00E-01 1.50E-013.10E+002.10E+00 12/15/2009 4.34E-01 2.30E+00 7.40E-011.55E+01 9.73E-01 2.00E-01 1.72E-011.20E+01 2.40E-01 12/16/2009 1.30E+00 2.30E+00 2.10E-013.62E+01 5.10E-01 6.91E-02 5.02E-011.20E+013.58E+00 12/17/2009 2.93E-01 2.20E+00 2.00E-011.82E+01 3.60E-01 5.30E-02 3.87E-011.30E+01 6.70E-01 12/18/2009 3.62E-01 2.30E+00 4.10E-015.17E+01 6.31E-01 1.10E-01 3.21E-011.20E+015.32E+00 1/4/2010 6.19E-01 2.30E+00 8.60E-015.91E+01 9.65E-01 2.30E-01 5.11E-012.71E+014.71E+00 1/5/2010 8.34E-01 2.30E+00 7.40E-013.79E+01 4.90E-01 2.00E-01 6.16E-013.75E+013.13E+00 1/6/2010 1.09E+00 2.30E+002.20E+006.57E+011.40E+00 5.70E-01 6.32E-011.07E+015.40E+00 1/7/2010 8.36E-01 2.30E+00 4.10E-011.66E+01 3.27E-01 1.10E-01 1.18E+008.11E+00 6.95E-01 1/8/2010 1.00E+00 2.20E+00 3.50E-013.75E+01 2.30E-01 9.30E-02 3.98E-017.84E+003.67E+00 1/9/2010 9.37E-01 2.20E+00 8.10E-014.47E+01 5.40E-01 2.10E-01 9.03E-012.57E+014.53E+00 1/10/2010 1/11/2010 1.84E+00 2.30E+00 5.41E-018.16E+011.21E+00 1.40E-01 7.38E-016.10E+005.92E+00 1/12/2010 3.51E+00 4.64E+01 8.53E-014.53E+01 5.85E-01 2.00E-01 2.71E+006.10E+001.76E+00 1/13/2010 1.06E+00 2.40E-01 2.20E-012.72E+01 3.16E-01 5.90E-02 7.83E-01 6.30E-015.89E+00 1/14/2010 7.23E-01 2.30E+00 8.26E-011.79E+01 4.36E-01 1.00E-01 6.90E-011.20E+011.97E+00 1/15/2010 7.49E-01 2.30E+00 3.70E-012.64E+01 7.25E-01 1.00E-01 6.11E-011.20E+012.38E+00 1/16/2010 2.20E-011.40E+001.12E+02 9.50E-01 3.80E-01 1.20E+011.95E+01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing A rea Sources - Total Non-VC HA** **P**

Facility Average of Total HAP Rank

P1-Henry 2.63E+01 1 FPC DE 2.90E+01 2 P1-Ptown 6.47E+01 3

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing A rea Sources - Total Non-VC HA** **P**

**GACT Limit Data New Sources** 

Method Method 8260B Resin Type Dispersion HAP (0=no, 1=yes) 1 Wet Resin From Stripper Bottoms Exclude Data (0=no, 1=yes) 0

Average of Wet Resin from Stripper Bottoms, ppm Analyte_Std

Reporting Plant Sample Date BDL (0=no, 1=yes) Acetaldehyde Acetopheno

ne Cumene Ethyl Chloride Ethylene

DichlorideEthylidene

Dichloride Formaldeh

yde Methanol Methyl Chloride

P1-Ptown 12/2/2009 0 6.40E+00 1.42E-01 4.73E-01 1.57E+01 7.73E-01 1 6.00E-02 1.10E+00 2.00E-01 5.50E-02 12/2/2009 Total 6.00E-02 1.10E+00 2.00E-016.40E+00 1.42E-01 5.50E-02 4.73E-01 1.57E+01 7.73E-01 12/3/2009 0 6.30E+00 5.23E-01 1.11E+01 6.43E-01

1 6.00E-02 2.30E+00 2.10E-01 1.40E-01 5.50E-02 12/3/2009 Total 6.00E-02 2.30E+00 2.10E-016.30E+00 1.40E-01 5.50E-02 5.23E-01 1.11E+01 6.43E-01 12/4/2009 0 9.56E-02 1.74E+01 2.38E-01 7.54E-02 6.36E-01 1.22E+01 9.66E-01

1 1.10E+00 2.10E-01 12/4/2009 Total 9.56E-02 1.10E+00 2.10E-011.74E+01 2.38E-01 7.54E-02 6.36E-01 1.22E+01 9.66E-01 12/5/2009 0 3.68E+00 2.07E-01 9.22E-02 1.56E-01

1 4.70E-02 1.80E+00 1.60E-01 4.80E-02 5.00E-02 12/5/2009 Total 4.70E-02 1.80E+00 1.60E-013.68E+00 2.07E-01 9.22E-02 1.56E-01 4.80E-02 5.00E-02 12/6/2009 0 2.67E-01 2.75E+01 6.74E-013.68E+01 4.42E-01 3.95E-01 4.42E+00

1 1.10E-01 3.10E+00 12/6/2009 Total 2.67E-01 2.75E+01 6.74E-013.68E+01 4.42E-01 1.10E-01 3.95E-01 3.10E+00 4.42E+00 12/7/2009 0 5.52E-01 9.32E-015.43E+01 7.56E-01 2.13E-01 3.41E-01 2.02E+02 5.55E+00

1 2.20E+00 12/7/2009 Total 5.52E-01 2.20E+00 9.32E-015.43E+01 7.56E-01 2.13E-01 3.41E-01 2.02E+02 5.55E+00 12/8/2009 0 2.64E-01 2.10E+01 4.72E-01 1.22E-01 6.31E-01 2.85E+01 1.16E+00

1 2.30E+00 4.00E-01 12/8/2009 Total 2.64E-01 2.30E+00 4.00E-012.10E+01 4.72E-01 1.22E-01 6.31E-01 2.85E+01 1.16E+00 12/9/2009 0 3.42E-01 2.84E+01 6.01E-01 1.29E-01 5.10E-01 3.20E+00

1 2.30E+00 3.70E-01 5.80E+00 12/9/2009 Total 3.42E-01 2.30E+00 3.70E-012.84E+01 6.01E-01 1.29E-01 5.10E-01 5.80E+00 3.20E+00 12/10/2009 0 4.14E-01 3.94E+01 5.17E-01 3.89E-01 5.45E+00 1 2.30E+00 7.70E-01 2.00E-01 6.30E+00 12/10/2009 Total 4.14E-01 2.30E+00 7.70E-013.94E+01 5.17E-01 2.00E-01 3.89E-01 6.30E+00 5.45E+00 12/11/2009 0 4.82E-01 1.59E+011.81E+005.44E+01 8.29E-01 1.30E-01 3.43E-01 3.41E+00 1 1.20E+01 12/11/2009 Total 4.82E-01 1.59E+011.81E+005.44E+01 8.29E-01 1.30E-01 3.43E-01 1.20E+01 3.41E+00 12/12/2009 0 12/12/2009 Total 12/13/2009 0 4.20E-01 4.73E+01 5.95E-01 3.81E-01 4.10E+00 1 2.20E+00 4.00E-01 1.10E-01 1.30E+01 12/13/2009 Total 4.20E-01 2.20E+00 4.00E-014.73E+01 5.95E-01 1.10E-01 3.81E-01 1.30E+01 4.10E+00 12/14/2009 0 1.09E-01 4.16E+01 9.54E-01 2.10E+00 1 2.30E+00 7.40E-01 2.00E-01 1.50E-01 3.10E+00 12/14/2009 Total 1.09E-01 2.30E+00 7.40E-014.16E+01 9.54E-01 2.00E-01 1.50E-01 3.10E+00 2.10E+00 12/15/2009 0 4.34E-01 1.55E+01 9.73E-01 1.72E-01 1 2.30E+00 7.40E-01 2.00E-01 1.20E+01 2.40E-01 12/15/2009 Total 4.34E-01 2.30E+00 7.40E-011.55E+01 9.73E-01 2.00E-01 1.72E-01 1.20E+01 2.40E-01 12/16/2009 0 1.30E+00 3.62E+01 5.10E-01 6.91E-02 5.02E-01 3.58E+00 1 2.30E+00 2.10E-01 1.20E+01 12/16/2009 Total 1.30E+00 2.30E+00 2.10E-013.62E+01 5.10E-01 6.91E-02 5.02E-01 1.20E+01 3.58E+00 12/17/2009 0 2.93E-01 1.82E+01 3.60E-01 3.87E-01 6.70E-01 1 2.20E+00 2.00E-01 5.30E-02 1.30E+01 12/17/2009 Total 2.93E-01 2.20E+00 2.00E-011.82E+01 3.60E-01 5.30E-02 3.87E-01 1.30E+01 6.70E-01 12/18/2009 0 3.62E-01 5.17E+01 6.31E-01 3.21E-01 5.32E+00 1 2.30E+00 4.10E-01 1.10E-01 1.20E+01 12/18/2009 Total 3.62E-01 2.30E+00 4.10E-015.17E+01 6.31E-01 1.10E-01 3.21E-01 1.20E+01 5.32E+00

1/4/2010 0 6.19E-01 5.91E+01 9.65E-01 5.11E-01 2.71E+01 4.71E+00

1 2.30E+00 8.60E-01 2.30E-01 1/4/2010 Total 6.19E-01 2.30E+00 8.60E-015.91E+01 9.65E-01 2.30E-01 5.11E-01 2.71E+01 4.71E+00

1/5/2010 0 8.34E-01 3.79E+01 6.16E-01 3.75E+01 3.13E+00

1 2.30E+00 7.40E-01 4.90E-01 2.00E-01 1/5/2010 Total 8.34E-01 2.30E+00 7.40E-013.79E+01 4.90E-01 2.00E-01 6.16E-01 3.75E+01 3.13E+00

1/6/2010 0 1.09E+00 6.57E+01 6.32E-01 1.07E+01 5.40E+00

1 2.30E+002.20E+00 1.40E+00 5.70E-01 1/6/2010 Total 1.09E+00 2.30E+002.20E+006.57E+01 1.40E+00 5.70E-01 6.32E-01 1.07E+01 5.40E+00

1/7/2010 0 8.36E-01 1.66E+01 3.27E-01 1.18E+00 8.11E+00 6.95E-01

1 2.30E+00 4.10E-01 1.10E-01 1/7/2010 Total 8.36E-01 2.30E+00 4.10E-011.66E+01 3.27E-01 1.10E-01 1.18E+00 8.11E+00 6.95E-01

1/8/2010 0 1.00E+00 3.75E+01 3.98E-01 7.84E+00 3.67E+00

1 2.20E+00 3.50E-01 2.30E-01 9.30E-02 1/8/2010 Total 1.00E+00 2.20E+00 3.50E-013.75E+01 2.30E-01 9.30E-02 3.98E-01 7.84E+00 3.67E+00

1/9/2010 0 9.37E-01 4.47E+01 9.03E-01 2.57E+01 4.53E+00

1 2.20E+00 8.10E-01 5.40E-01 2.10E-01 1/9/2010 Total 9.37E-01 2.20E+00 8.10E-014.47E+01 5.40E-01 2.10E-01 9.03E-01 2.57E+01 4.53E+00 1/10/2010 0 1/10/2010 Total 1/11/2010 0 1.84E+00 5.41E-018.16E+01 1.21E+00 7.38E-01 5.92E+00

1 2.30E+00 1.40E-01 6.10E+00 1/11/2010 Total 1.84E+00 2.30E+00 5.41E-018.16E+01 1.21E+00 1.40E-01 7.38E-01 6.10E+00 5.92E+00 1/12/2010 0 3.51E+00 4.64E+01 8.53E-014.53E+01 5.85E-01 2.71E+00 1.76E+00

1 2.00E-01 6.10E+00 1/12/2010 Total 3.51E+00 4.64E+01 8.53E-014.53E+01 5.85E-01 2.00E-01 2.71E+00 6.10E+00 1.76E+00 1/13/2010 0 1.06E+00 2.72E+01 3.16E-01 7.83E-01 5.89E+00

1 2.40E-01 2.20E-01 5.90E-02 6.30E-01 1/13/2010 Total 1.06E+00 2.40E-01 2.20E-012.72E+01 3.16E-01 5.90E-02 7.83E-01 6.30E-01 5.89E+00 1/14/2010 0 7.23E-01 8.26E-011.79E+01 4.36E-01 6.90E-01 1.97E+00

1 2.30E+00 1.00E-01 1.20E+01 1/14/2010 Total 7.23E-01 2.30E+00 8.26E-011.79E+01 4.36E-01 1.00E-01 6.90E-01 1.20E+01 1.97E+00 1/15/2010 0 7.49E-01 2.64E+01 7.25E-01 6.11E-01 2.38E+00

1 2.30E+00 3.70E-01 1.00E-01 1.20E+01 1/15/2010 Total 7.49E-01 2.30E+00 3.70E-012.64E+01 7.25E-01 1.00E-01 6.11E-01 1.20E+01 2.38E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

1/16/2010 0 1.12E+02 1.95E+01 1 2.20E-011.40E+00 9.50E-01 3.80E-01 1.20E+01 1/16/2010 Total 2.20E-011.40E+001.12E+02 9.50E-01 3.80E-01 1.20E+01 1.95E+01

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing A rea Sources - Total Non-VC HA** **P**
**Detection Limit Analysis**

Facility HAP Sum Daily HAP Sum ln Total

HAP

P1-Ptown 2.35E+01 0.00E+00 P1-Ptown 1.42E+00 1.00E+00 P1-Ptown 2.49E+01 2.49E+01 3.21E+00 P1-Ptown 1.86E+01 0.00E+00 P1-Ptown 2.77E+00 1.00E+00 P1-Ptown 2.13E+01 2.13E+01 3.06E+00 P1-Ptown 3.16E+01 0.00E+00 P1-Ptown 1.31E+00 1.00E+00 P1-Ptown 3.29E+01 3.29E+01 3.49E+00 P1-Ptown 4.14E+00 0.00E+00 P1-Ptown 2.11E+00 1.00E+00 P1-Ptown 6.24E+00 6.24E+00 1.83E+00 P1-Ptown 7.05E+01 0.00E+00 P1-Ptown 3.21E+00 1.00E+00 P1-Ptown 7.37E+01 7.37E+01 4.30E+00 P1-Ptown 2.65E+02 0.00E+00 P1-Ptown 2.20E+00 1.00E+00 P1-Ptown 2.67E+02 2.67E+02 5.59E+00 P1-Ptown 5.21E+01 0.00E+00 P1-Ptown 2.70E+00 1.00E+00 P1-Ptown 5.48E+01 5.48E+01 4.00E+00 P1-Ptown 3.32E+01 0.00E+00 P1-Ptown 8.47E+00 1.00E+00 P1-Ptown 4.17E+01 4.17E+01 3.73E+00 P1-Ptown 4.62E+01 0.00E+00 P1-Ptown 9.57E+00 1.00E+00 P1-Ptown 5.57E+01 5.57E+01 4.02E+00 P1-Ptown 7.73E+01 0.00E+00 P1-Ptown 1.20E+01 1.00E+00 P1-Ptown 8.93E+01 8.93E+01 4.49E+00 P1-Ptown 0.00E+00 0.00E+00 P1-Ptown 0.00E+00 P1-Ptown 5.28E+01 0.00E+00 P1-Ptown 1.57E+01 1.00E+00 P1-Ptown 6.85E+01 6.85E+01 4.23E+00 P1-Ptown 4.48E+01 0.00E+00 P1-Ptown 6.49E+00 1.00E+00 P1-Ptown 5.13E+01 5.13E+01 3.94E+00 P1-Ptown 1.71E+01 0.00E+00 P1-Ptown 1.55E+01 1.00E+00 P1-Ptown 3.26E+01 3.26E+01 3.48E+00 P1-Ptown 4.22E+01 0.00E+00 P1-Ptown 1.45E+01 1.00E+00 P1-Ptown 5.67E+01 5.67E+01 4.04E+00 P1-Ptown 1.99E+01 0.00E+00 P1-Ptown 1.55E+01 1.00E+00 P1-Ptown 3.54E+01 3.54E+01 3.57E+00 P1-Ptown 5.83E+01 0.00E+00 P1-Ptown 1.48E+01 1.00E+00 P1-Ptown 7.32E+01 7.32E+01 4.29E+00 P1-Ptown 9.30E+01 0.00E+00 P1-Ptown 3.39E+00 1.00E+00 P1-Ptown 9.64E+01 9.64E+01 4.57E+00 P1-Ptown 8.00E+01 0.00E+00 P1-Ptown 3.73E+00 1.00E+00 P1-Ptown 8.37E+01 8.37E+01 4.43E+00 P1-Ptown 8.35E+01 0.00E+00 P1-Ptown 6.47E+00 1.00E+00 P1-Ptown 9.00E+01 9.00E+01 4.50E+00 P1-Ptown 2.77E+01 0.00E+00 P1-Ptown 2.82E+00 1.00E+00 P1-Ptown 3.06E+01 3.06E+01 3.42E+00 P1-Ptown 5.04E+01 0.00E+00 P1-Ptown 2.87E+00 1.00E+00 P1-Ptown 5.33E+01 5.33E+01 3.98E+00 P1-Ptown 7.68E+01 0.00E+00 P1-Ptown 3.76E+00 1.00E+00 P1-Ptown 8.05E+01 8.05E+01 4.39E+00 P1-Ptown 0.00E+00 0.00E+00 P1-Ptown 0.00E+00 P1-Ptown 9.18E+01 0.00E+00 P1-Ptown 8.54E+00 1.00E+00 P1-Ptown 1.00E+02 1.00E+02 4.61E+00 P1-Ptown 1.01E+02 0.00E+00 P1-Ptown 6.30E+00 1.00E+00 P1-Ptown 1.07E+02 1.07E+02 4.68E+00 P1-Ptown 3.52E+01 0.00E+00 P1-Ptown 1.15E+00 1.00E+00 P1-Ptown 3.64E+01 3.64E+01 3.59E+00 P1-Ptown 2.25E+01 0.00E+00 P1-Ptown 1.44E+01 1.00E+00 P1-Ptown 3.69E+01 3.69E+01 3.61E+00 P1-Ptown 3.09E+01 0.00E+00 P1-Ptown 1.48E+01 1.00E+00 P1-Ptown 4.56E+01 4.56E+01 3.82E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

P1-Ptown 1.32E+02 0.00E+00 P1-Ptown 1.50E+01 1.00E+00 P1-Ptown 1.46E+02 1.46E+02 4.99E+00

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resins - Dispersion - Existing A rea Sources - Total Non-VC HA** **P**
**GACT Limit and Variability Calculation New Sources** 

Total Non-VC HAP PL 

### 9.90E+01

**Normal Lognormal** 

n 2.80E+01 2.80E+01

m 1.00E+00 1.00E+00 Average 6.76E+01 3.99E+00 Median 5.53E+01 4.01E+00 Standard Deviation 5.00E+01 7.04E-01 Minimum 6.24E+00 1.83E+00 Maximum 2.67E+02 5.59E+00 Skewness 2.52E+00 -6.73E-01 SE Skewness 4.63E-01 4.63E-01 Skewness Test Non-normal Normal Kurtosis 8.89E+00 2.56E+00 SE Kurtosis 9.26E-01 9.26E-01 Kurtosis Test Non-normal Non-normal t-statistic for UPL 2.47E+00 2.47E+00 UPL 1.93E+02 3.19E+02

Average for variability analysis 6.76E+01 Max DL < or = avg 4.75E+00 3x Max DL 1.43E+01 UPL 3.19E+02ppmw **GACT Floor 3.19E+02** **ppmw**

1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value for the rule making. 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability for the rule making

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Resin Sampling and Monitoring**

Low High Average **Cost of US EPA Method 8260B [1]** $201 $400 $301

**Initial Compliance**

3outlet tests x 2 strippers2 

# $1,803.00

**Total Compliance Cost** $1,803.00

**CRF (20 yr, 7%):** (0.07*(1+0.07)^20)/((1+0.07)^20-1) 0.09439



# Annual Cost of Initial Compliance `= (3 inlet tests*Avg Cost*2 Strippers)*CRF **$170.19**

**Monitoring**

1tests per month for each type of resin x 2 strippers2 

# $601.00

Certain Teed Lake Charles B 1 $7,212.00 Certain Teed Lake Charles B 1 $7,212.00

2. Average number of strippers calculated from facility submitted survey data 1. National Environmental Methods Index Website https://www.nemi.gov/apex/f?p=237:38:951365369293524::::P38_METHOD_ID:7041

**Company Location**  **Resin Type Number of**  **Resin Types TA** **C of**

**Resin Testing** 

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012



# CertainTeed Lake Charles Resin Emission Estimate **Using Reported Survey Data**

P-2

**Emission Point ID Vinyl chloride**  **Methyl chloride (Chloromethane)**  **Ethyl chloride**

**(Chloroethane) 1,3-Butadiene**  **Ethylene dichloride (1,2-**  **Dichloroethane)** (EP-x) (pounds) (pounds) (pounds) (pounds) (pounds)
EP-6 2.20E+02 4.10E+02 1.54E+02 1.40E+01 4.00E+00
EP-7 2.19E+02 4.08E+02 1.63E+02 1.40E+01 3.00E+00

P-1

**Emission Point ID Vinyl chloride**  **Methyl chloride (Chloromethane)**  **Ethyl chloride**

**(Chloroethane) 1,3-Butadiene**  **Ethylene dichloride (1,2-**  **Dichloroethane)** (EP-x) (pounds) (pounds) (pounds) (pounds) (pounds)
EP-1 4.00E+02 7.45E+02 2.98E+02 2.60E+01 6.00E+00
EP-2 3.98E+02 7.41E+02 2.96E+02 2.50E+01 6.00E+00
EP-3a 3.20E+02 5.95E+02 2.38E+02 2.10E+01 5.00E+00 EP-3b 3.20E+02 5.95E+02 2.38E+02 2.10E+01 5.00E+00

TOTAL (lbs/yr) 1.88E+03 3.49E+03 1.39E+03 1.21E+02 2.90E+01 TOTAL (tpy) 9.39E-01 1.75E+00 6.94E-01 6.05E-02 1.45E-02

**TOTAL VC (tpy) 9.39E-01**  **TOTAL NON-VC HAP (tpy) 5.57E+00** 

# ATTACHMENT D- RESINS ANALYSIS

02/09/2012

**Ethylene glycol**

(pounds)
7.22E+02
7.00E+02

**Ethylene glycol**

(pounds)
1.31E+03
1.27E+03
1.05E+03
1.05E+03

6.10E+03
3.05E+00

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012



# Wastewater Summary

**Calculated GACT Baseline**

**Calculated Limits Existing Area Source Current**  **Level of Performance (Least Controlled, Avg**  **Concentrations) Existing Area Source**  **Current Level of Control (Least**  **Controlled, Variability Included)**  **New Area Source Current level of Performance**  **New Area Source Current level of Control** 

**Vinyl Chloride (ppmw) 4.00E-01**  2.10E+00 4.00E-01 2.10E+00 **Total Non-VC HAP (ppmw) 1.80E-02**  1.80E-02 1.80E-02 1.80E-02



## Existing and New Source GACT Summary for Wastewater (Option 2)

**Pollutant Existing Area Source Current**  **Level of Performance (Least Controlled, Avg**  **Concentrations) Major Existing Source**  **Requirements Emissions for Current Level of**  **Control Emissions Reductions as a** 

**Result of Complaince with Major Existing Source**  **Requirements (tons/yr)**

**Vinyl Chloride (ppmw) 4.00E-01**  6.80E+00 9.03E-01

- **Total Non-VC HAP (ppmw) 1.80E-02**  1.10E+02 1.31E+01



## -

**Existing Source GACT Summary for Wastewater (Option 3)**

**Pollutant Existing Area Source Current**  **Level of Performance (Least Controlled, Avg**  **Concentrations) Major New Source**  **Requirement Emissions for Current Level of**  **Control Emissions Reductions as a** 

**Result of Complaince with Major New Source**  **Requirements (tons/yr)**

**Vinyl Chloride (ppmw) 4.00E-01**  2.80E-01 9.03E-01 8.55E-03 **Total Non-VC HAP (ppmw) 1.80E-02**  1.80E-02 1.31E+01 1.22E+01



## New Source GACT Summary for Wastewater (Option 3) (Based on OxyVinyls Deer Park)

**Pollutant New Area Source Current**  **Level of Performance (Least Controlled, Avg**  **Concentrations) Major New Source**  **Requirement Emissions for Current Level of**  **Control Emissions Reductions as a** 

**Result of Complaince with Major New Source**  **Requirements (tons/yr)**

**Vinyl Chloride (ppmw) 4.00E-01**  2.80E-01 6.34E-01 1.31E-01 **Total Non-VC HAP (ppmw) 1.80E-02**  1.80E-02 9.44E+00 8.91E+00



## GACT Analysis - Wastewater - Existing and New - Area Source - Costs to Meet NEW MACT Floor

**Cost Component CTLC**  **OVDP Model New Facility (Based on**  **OxyVinyls Deer Park)**



## Initial Costs Control Equipment Capital Cost Hard Pipe / Pump / Motor for Uncontrolled Stream 150155.34 234074.35 234074.35 New Wastewater Stripper 4162340.18 7816537.83 7816537.83 Initial Wastewater Testing 981.00 981.00 981.00 Initial Record Keeping and Reporting Cost 2733.51 2733.51 2733.51 **Total Initial Costs 4316210.02**  **8054326.70 8054326.70**  **Annual Costs** Annualized Capital Cost Hard Pip / Pump / Motor for Uncontrolled Stream 14168.30 22084.61 22084.61 New Wastewater Stripper 392895.47 737825.88 737825.88 Annual Hardpipe/Pump/Motor Equipment Cost 13975.96 16462.59 13975.96 Annual Wastewater Stripper Cost 574607.30 1204593.50 1204593.50 Annualized Initial Testing and Monitoring Cost1 

## 0.00 0.00 0.00 Annual Testing and Monitoring Cost 6376.50 6376.50 6376.50 Annual Record Keeping and Reporting Cost 3511.84 3511.84 3511.84 **Total Annual Cost 1005535.37**  **1990854.91 1988368.29**  1 - Initial Testing Cost less than annual; therefore, no amortization of initial testing cost

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - New and Existing Area Sources - VC**

CTLC Baseline - VC **OVDP Baseline - VC 0.4** **ppm**

**Averages based on Daily Averages** 

### Average of Avg VC Conc **New Source - Monthly** Company Month/Yr Total LN **Normal LN** 


### OXYDP Jan-08 2.65E-01-1.33E+00 Sample Size 1.20E+01 1.20E+01 

### Feb-08 2.83E-01-1.26E+00 Compliance Avg Period 1.00E+00 1.00E+00


### Mar-08 1.47E-01-1.92E+00 Average 3.99E-01-1.19E+00 

### Apr-08 4.80E-01-7.34E-01 Median 2.89E-01-1.24E+00 

### May-08 2.95E-01-1.22E+00 Standard Deviation 4.16E-01 6.77E-01


### Jun-08 2.22E-01-1.51E+00 Minimum 1.20E-01-2.12E+00 

### Jul-08 3.38E-01-1.09E+00 Maximum 1.67E+00 5.14E-01 

### Aug-08 3.15E-01-1.16E+00 Skewness 3.05E+00 1.32E+00 

### Sep-08 1.67E+00 5.14E-01 SE Skewness 7.07E-01 7.07E-01


### Oct-08 1.90E-01-1.66E+00 Skewness Test Non-normal Normal


### Nov-08 1.20E-01-2.12E+00 Kurtosis 9.92E+00 3.17E+00


### Dec-08 4.58E-01-7.82E-01 SE Kurtosis 1.41E+00 1.41E+00
Kurtosis Test Non-normalNon-normal 99.0% t-statistic for UPL 2.72E+00 2.72E+00 99.0% UPL 1.57E+00 2.07E+00

average in variability analysis 3.99E-01 Max DL < or = avg 1.00E-02 3x Max DL 3.00E-02 99.0% UPL 2.07E+00ppm **MACT Floor Limit 2.10E+00** 

### ppm 1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value

2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - New and Existing Area Sources - Total Non-VC HAP**

**MACT Floor Data Set** Company & Facility Originating Equipment Acetaldehyde EDC MeOH MIBK Total Non-VC HAP Rank OxyVinyls Deer Park Waste Water Stripper 1.80E-02 1.80E-02 1 Formosa Baton Rouge Wastew ater Stripping Columns 3.00E-01 3.00E-01 2 Westlake Calvert City Water Stripper Col Feed Heat Exch 2.26E+00 2.26E+00 3 Shintech Freeport HEAT EXCHANGER 3.90E+01 2.59E-01 3.93E+01 4 Shintech Addis Waste Water Stripper 4.00E+01 2.60E-01 4.03E+01 5 Shintech Plaquemine Waste Water Stripper 4.00E+01 3.00E-01 4.03E+01 6 **Note: CTLC did not provide any WW concentration data other than VC for Stripper Outlet**

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - Existing Area Sources - Baseline & Reductions & Hardpiping/Stripper Costs**

**Option 2 Analysis for New and Existing Area Sources** Pollutant Existing Source (ppmw) New Source (ppmw) VC 6.80E+00 2.80E-01 Total Non_VC HAP 1.10E+02 1.80E-02

**Stripper Outlet Wastewater Baseline Estimation**

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Stripper WW (Gal) 2008 Stripper Outlet**  **(Gals)/Lb of Resin 2008 Stripper Outlet**  **(Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **% Reduction of VC** 

**Conc Needed to meet New Source MACT**  **floor limit Total Non-VC** 

**HAP Conc W/ Avg for Non**  **Report (PMW)**  **% Reduction of** 

**Total Non-VC HAP Conc**  **Needed to meet MACT**  **floor limit Baseline VC** 

**(Tons/YR) Baseline** 

**Total Non VCHAP**  **(Tons/YR) VC Reduction** 

**(Tons Per Year)**  **Total Non**

**VC HAP Reduction**  **(Tons/yr)**

Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 3.60E+03 8.05E-06 3.60E+03 4.00E-01 3.00E-01 1.80E-02

- 6.01E-06 2.70E-07 1.80E-06 0.00E+00 Dow Midland Other 2.16E+07No Formosa Baton Rouge Other Yes 9.17E+08 1.37E+07 Formosa Delaware Dispersion Yes 1.43E+08 Formosa Point Comfort Other Yes 1.57E+09 OxyVinyls Deer Park Other Yes 5.51E+08 1.73E+07 3.99E-01 2.98E-01 1.80E-02

- 2.87E-02 1.30E-03 8.55E-03 0.00E+00 OxyVinyls Pasadena Other Yes 2.10E+09 6.40E+07 OxyVinyls Pedricktown Other 3.51E+08 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 4.95E+06 6.52E-02 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 2.47E+05 6.21E-03 Shintech Addis Other Yes 6.24E+08 1.48E+07 Shintech Freeport Other Yes 3.20E+09 2.70E+07 Shintech Plaquemine Other Yes 1.30E+09 3.80E+06 Westlake Calvert City Other 1.10E+09No 8.00E+08 2.89E+07 2.63E-02 Westlake Geismar Other 4.76E+08No 5.73E+08 1.32E+07 2.78E-02 Georgia Gulf Aberdeen Other 1.00E+09 1.06E+07 Georgia Gulf Plaquemine Other 1.20E+09

Average* 3.14E-02 *Average does not include CTLC due to absence of H20 **UNCONTROLLED WASTEWATER STREAMS** in Bulk process **Wastewater Stripper Outlet Concentration Limits (Monthly Basis)**

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - Existing Area Sources - Baseline & Reductions & Hardpiping/Stripper Costs**

**UnControlled Data** Data FacilityName Sum of Total WW (GAL) Sum of VC2 Sum of Total Non-VC HAP2 Formosa Plastics Corporation Baton Rouge 3.42E+08 1.43E-01 Georgia Gulf Chemicals Aberdeen Facility 2.77E+07 0.00E+00 Lake Charles Polymer Plant 5.96E+07 6.22E-04 OxyVinyls Deer Park 0.00E+00 OxyVinyls Pasadena 4.62E+08 0.00E+00 1.44E+00 PolyOne Henry 4.13E+07 3.44E-01 Shintech Addis 5.11E+07 7.94E-03 2.49E+00 Shintech Freeport 2.70E+07 6.76E-04 4.42E+00 Shintech Plaquemine 1.00E+07 2.80E-03 6.20E-01 Westlake Calvert City 6.46E+07 0.00E+00 6.10E-01 Westlake Geismar 1.11E+08 6.67E-03

**Company & Facility Total WW (GAL)**  **Tons VC Tons Total Non-VC HAP**  **VC Conc (PPMW) Total Non-VC HAP Conc (PPMW)**  Formosa Baton Rouge 3.42E+08 1.43E-01 1.00E-01 Georgia Gulf Aberdeen 2.77E+07 0.00E+00 0.00E+00 Certain Teed Lake Charles 5.96E+07 6.22E-04 2.50E-03 OxyVinyls Deer Park 0.00E+00 OxyVinyls Pasadena 4.62E+08 0.00E+00 1.44E+00 0.00E+00 7.47E-01 PolyOne Henry 4.13E+07 3.44E-01 2.00E+00 Shintech Addis 5.11E+07 7.94E-03 2.49E+00 3.72E-02 1.17E+01 Shintech Freeport 2.70E+07 6.76E-04 4.42E+00 6.00E-03 3.93E+01 Shintech Plaquemine 1.00E+07 2.80E-03 6.20E-01 6.69E-02 1.48E+01 Westlake Calvert City 6.46E+07 0.00E+00 6.10E-01 0.00E+00 2.26E+00 Westlake Geismar 1.11E+08 6.67E-03 1.45E-02 Average 2.23E-01 1.38E+01

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Uncontrolled WW (Gal) 2008 Uncontrolled**  **Flow (Gals/Lb of Resin**  **2008 Uncontrolled**

**Flow (Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **Total Non-VC HAP**

**Conc W/ Avg for Non Report (PMW)**  **Baseline VC**

**(Tons/YR) Baseline Total** 

**Non-VC HAP (Tons/YR)**  **Hardpipe TCI**

**($) Hardpipe** 

**TAC ($/yr) Hardpipe CR** 

**($/yr) VC** 

**Reductions (tpy)**  **Non-VC**

**HAP Reductions**  **(tpy)** Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 5.96E+07 1.33E-01 5.96E+07 2.50E-03 1.38E+01 6.22E-04 3.42E+00 1.50E+05 1.40E+04 1.42E+04 0.00E+00 3.42E+00 Dow Midland Other 2.16E+07No 6.00E+06 Formosa Baton Rouge Other Yes 9.17E+08 3.42E+08 3.42E+08 Formosa Delaware Dispersion Yes 1.43E+08 3.98E+07 Formosa Point Comfort Other Yes 1.57E+09 4.35E+08 OxyVinyls Deer Park Other Yes 5.51E+08 1.53E+08 2.50E-03 1.38E+01 1.60E-03 8.79E+00 2.34E+05 1.65E+04 2.21E+04 0.00E+00 8.78E+00 OxyVinyls Pasadena Other Yes 2.10E+09 4.62E+08 4.62E+08 OxyVinyls Pedricktown Other 3.51E+08 9.74E+07 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 4.13E+07 5.43E-01 4.13E+07 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 1.11E+07 Shintech Addis Other Yes 6.24E+08 5.11E+07 5.11E+07 Shintech Freeport Other Yes 3.20E+09 2.70E+07 2.70E+07 Shintech Plaquemine Other Yes 1.30E+09 1.00E+07 1.00E+07 Westlake Calvert City Other 1.10E+09No 8.00E+08 6.46E+07 5.88E-02 6.46E+07 Westlake Geismar Other 4.76E+08No 5.73E+08 1.11E+08 2.32E-01 1.11E+08 Georgia Gulf Aberdeen Other 1.00E+09 2.77E+07 2.77E+07 Georgia Gulf Plaquemine Other 1.20E+09 3.33E+08

Average* 2.78E-01 *Average does not include CTLC due to absence of H20 in Bulk process (see "Hardpipe Costing" sheet)

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - Existing Area Sources - Baseline & Reductions & Hardpiping/Stripper Costs**

**MAINTENANCE WW STREAMS**

**Company & Facility Total WW (GAL)**  **VC Conc (PPMW)**  **Total Non-VC HAP Conc (PPMW)**  PolyOne Henry 2.22E+07 2.00E+00 Shintech Freeport 4.30E+05 7.70E-02 Westlake Calvert City 1.21E+06 Westlake Geismar 8.52E+05 2.25E+00 2.13E+00 7.70E-02

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Main WW (Gal) 2008 Maint Flow**  **(Gals/Lb of Resin 2008 Maint Flow**  **(Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **TOHAP Conc W/ Avg**

**for Non-Report (PMW)**  **Baseline VC**

**(Tons/YR) Baseline** 

**TOHAP (Tons/YR)**  Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 4.41E+07 2.13E+00 7.70E-02 3.91E-01 1.42E-02 Dow Midland Other 2.16E+07No 2.13E+06 Formosa Baton Rouge Other Yes 9.17E+08 9.03E+07 Formosa Delaware Dispersion Yes 1.43E+08 1.41E+07 Formosa Point Comfort Other Yes 1.57E+09 1.54E+08 OxyVinyls Deer Park Other Yes 5.51E+08 5.43E+07 2.13E+00 7.70E-02 4.81E-01 1.74E-02 OxyVinyls Pasadena Other Yes 2.10E+09 2.07E+08 OxyVinyls Pedricktown Other 3.51E+08 3.45E+07 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 2.22E+07 2.93E-01 2.22E+07 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 3.92E+06 Shintech Addis Other Yes 6.24E+08 6.15E+07 Shintech Freeport Other Yes 3.20E+09 4.30E+05 4.30E+05 Shintech Plaquemine Other Yes 1.30E+09 1.28E+08 Westlake Calvert City Other 1.10E+09No 8.00E+08 1.21E+06 1.10E-03 1.21E+06 Westlake Geismar Other 4.76E+08No 5.73E+08 8.52E+05 1.79E-03 8.52E+05 Georgia Gulf Aberdeen Other 1.00E+09 9.86E+07 Georgia Gulf Plaquemine Other 1.20E+09 1.18E+08

Average* 9.85E-02 *Average does not include CTLC due to absence of H20 in Bulk process **Stripper Outlet, Uncontrolled, and Maint. Wastewater Combined**

**Company & Facility Resin Type**  **Baseline VC (Tons/YR)**  **Baseline Total Non-VC**

**HAP (Tons/YR) VC Reduction**  **(Tons Per Year) Total Non-VC HAP Reduction**  **(Tons Per Year)** Certain Teed - Lake Charles Bulk 3.91E-01 3.44E+00 1.80E-06 3.42E+00 OxyVinyls Deer Park Suspension 5.12E-01 8.81E+00 8.55E-03 8.78E+00

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - New Area Sources - Baseline & Reductions & Hardpiping Costs**

**Option 2 Analysis for New and Existing Area Sources** Pollutant Existing Source (ppmw) New Source (ppmw) VC 6.80E+00 2.80E-01 Total Non_VC HAP 110.00 0.018

**Stripper Outlet Wastewater Baseline Estimation**

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Stripper WW (Gal) 2008 Stripper Outlet**  **(Gals)/Lb of Resin 2008 Stripper Outlet**  **(Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **% Reduction of VC** 

**Conc Needed to meet MACT floor limit**  **Total Non-VC**

**HAP Conc W/ Avg for Non**  **Report (PMW)**  **% Reduction of** 

**Total Non-VC HAP Conc**  **Needed to meet MACT**  **floor limit Baseline VC** 

**(Tons/YR) Baseline** 

**Total Non VCHAP**  **(Tons/YR) VC Reduction** 

**(Tons Per Year)**  **Total Non**

**VC HAP Reduction**  **(Tons/yr)**

Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 3.60E+03 8.05E-06 Dow Midland Other 2.16E+07No Formosa Baton Rouge Other Yes 9.17E+08 1.37E+07 Formosa Delaware Dispersion Yes 1.43E+08 Formosa Point Comfort Other Yes 1.57E+09 OxyVinyls Deer Park Other Yes 5.51E+08 1.73E+07 2.10E+00 8.67E-01 1.80E-02

- 1.51E-01 1.30E-03 1.31E-01 0.00E+00 OxyVinyls Pasadena Other Yes 2.10E+09 6.40E+07 OxyVinyls Pedricktown Other 3.51E+08 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 4.95E+06 6.52E-02 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 2.47E+05 6.21E-03 Shintech Addis Other Yes 6.24E+08 1.48E+07 Shintech Freeport Other Yes 3.20E+09 2.70E+07 Shintech Plaquemine Other Yes 1.30E+09 3.80E+06 Westlake Calvert City Other 1.10E+09No 8.00E+08 2.89E+07 2.63E-02 Westlake Geismar Other 4.76E+08No 5.73E+08 1.32E+07 2.78E-02 Georgia Gulf Aberdeen Other 1.00E+09 1.06E+07 Georgia Gulf Plaquemine Other 1.20E+09

Average* 3.14E-02 *Average does not include CTLC due to absence of H20 **UNCONTROLLED WASTEWATER STREAMS** in Bulk process **Wastewater Stripper Outlet Concentration Limits (Monthly Basis)**

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - New Area Sources - Baseline & Reductions & Hardpiping Costs**

**UnControlled Data** Data FacilityName Sum of Total WW (GAL) Sum of VC2 Sum of Total Non-VC HAP2 Formosa Plastics Corporation Baton Rouge 3.42E+08 1.43E-01 Georgia Gulf Chemicals Aberdeen Facility 2.77E+07 0.00E+00 Lake Charles Polymer Plant 5.96E+07 6.22E-04 OxyVinyls Deer Park 0.00E+00 OxyVinyls Pasadena 4.62E+08 0.00E+00 1.44E+00 PolyOne Henry 4.13E+07 3.44E-01 Shintech Addis 5.11E+07 7.94E-03 2.49E+00 Shintech Freeport 2.70E+07 6.76E-04 4.42E+00 Shintech Plaquemine 1.00E+07 2.80E-03 6.20E-01 Westlake Calvert City 6.46E+07 0.00E+00 6.10E-01 Westlake Geismar 1.11E+08 6.67E-03

**Company & Facility Total WW (GAL)**  **Tons VC Tons Total Non-VC HAP**  **VC Conc (PPMW) Total Non-VC HAP Conc (PPMW)**  Formosa Baton Rouge 3.42E+08 1.43E-01 1.00E-01 Georgia Gulf Aberdeen 2.77E+07 0.00E+00 0.00E+00 Certain Teed Lake Charles 5.96E+07 6.22E-04 2.50E-03 OxyVinyls Deer Park 0.00E+00 OxyVinyls Pasadena 4.62E+08 0.00E+00 1.44E+00 0.00E+00 7.47E-01 PolyOne Henry 4.13E+07 3.44E-01 2.00E+00 Shintech Addis 5.11E+07 7.94E-03 2.49E+00 3.72E-02 1.17E+01 Shintech Freeport 2.70E+07 6.76E-04 4.42E+00 6.00E-03 3.93E+01 Shintech Plaquemine 1.00E+07 2.80E-03 6.20E-01 6.69E-02 1.48E+01 Westlake Calvert City 6.46E+07 0.00E+00 6.10E-01 0.00E+00 2.26E+00 Westlake Geismar 1.11E+08 6.67E-03 1.45E-02 Average 2.23E-01 1.38E+01

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Uncontrolled WW (Gal) 2008 Uncontrolled**  **Flow (Gals/Lb of Resin**  **2008 Uncontrolled**

**Flow (Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **Total Non-VC HAP**

**Conc W/ Avg for Non Report (PMW)**  **Baseline VC**

**(Tons/YR) Baseline Total** 

**Non-VC HAP (Tons/YR)**  **Hardpipe TCI**

**($) Hardpipe** 

**TAC ($/yr) Hardpipe CR** 

**($/yr) VC** 

**Reductions (tpy)**  **Non-VC**

**HAP Reductions**  **(tpy)** Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 5.96E+07 1.33E-01 5.96E+07 Dow Midland Other 2.16E+07No 6.00E+06 Formosa Baton Rouge Other Yes 9.17E+08 3.42E+08 3.42E+08 Formosa Delaware Dispersion Yes 1.43E+08 3.98E+07 Formosa Point Comfort Other Yes 1.57E+09 4.35E+08 OxyVinyls Deer Park Other Yes 5.51E+08 1.53E+08 2.50E-03 1.38E+01 1.60E-03 8.79E+00 2.34E+05 1.65E+04 2.21E+04 0.00E+00 8.78E+00 OxyVinyls Pasadena Other Yes 2.10E+09 4.62E+08 4.62E+08 OxyVinyls Pedricktown Other 3.51E+08 9.74E+07 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 4.13E+07 5.43E-01 4.13E+07 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 1.11E+07 Shintech Addis Other Yes 6.24E+08 5.11E+07 5.11E+07 Shintech Freeport Other Yes 3.20E+09 2.70E+07 2.70E+07 Shintech Plaquemine Other Yes 1.30E+09 1.00E+07 1.00E+07 Westlake Calvert City Other 1.10E+09No 8.00E+08 6.46E+07 5.88E-02 6.46E+07 Westlake Geismar Other 4.76E+08No 5.73E+08 1.11E+08 2.32E-01 1.11E+08 Georgia Gulf Aberdeen Other 1.00E+09 2.77E+07 2.77E+07 Georgia Gulf Plaquemine Other 1.20E+09 3.33E+08

Average* 2.78E-01 *Average does not include CTLC due to absence of H20 in Bulk process (see "Hardpipe Costing" sheet)

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - New Area Sources - Baseline & Reductions & Hardpiping Costs**

**MAINTENANCE WW STREAMS**

**Company & Facility Total WW (GAL)**  **VC Conc (PPMW)**  **Total Non-VC HAP Conc (PPMW)**  PolyOne Henry 2.22E+07 2.00E+00 Shintech Freeport 4.30E+05 7.70E-02 Westlake Calvert City 1.21E+06 Westlake Geismar 8.52E+05 2.25E+00 2.13E+00 7.70E-02

**Company & Facility Resin Type**  **2008 lbs of Resin**  **2008 lb of Resin CBI? 2006 Capacity**  **2008 Main WW (Gal) 2008 Maint Flow**  **(Gals/Lb of Resin 2008 Maint Flow**  **(Gals/YR) VC Conc W/ Avg** 

**for Non-Report (PPMW)**  **TOHAP Conc W/ Avg**

**for Non-Report (PMW)**  **Baseline VC**

**(Tons/YR) Baseline** 

**TOHAP (Tons/YR)**  Certain Teed Lake Charles Bulk 4.47E+08No 4.81E+08 4.41E+07 Dow Midland Other 2.16E+07No 2.13E+06 Formosa Baton Rouge Other Yes 9.17E+08 9.03E+07 Formosa Delaware Dispersion Yes 1.43E+08 1.41E+07 Formosa Point Comfort Other Yes 1.57E+09 1.54E+08 OxyVinyls Deer Park Other Yes 5.51E+08 5.43E+07 2.13E+00 7.70E-02 4.81E-01 1.74E-02 OxyVinyls Pasadena Other Yes 2.10E+09 2.07E+08 OxyVinyls Pedricktown Other 3.51E+08 3.45E+07 PolyOne Henry Other/Dispersion 7.60E+07No 1.26E+08 2.22E+07 2.93E-01 2.22E+07 PolyOne Pedricktown Dispersion 3.98E+07No 1.30E+08 3.92E+06 Shintech Addis Other Yes 6.24E+08 6.15E+07 Shintech Freeport Other Yes 3.20E+09 4.30E+05 4.30E+05 Shintech Plaquemine Other Yes 1.30E+09 1.28E+08 Westlake Calvert City Other 1.10E+09No 8.00E+08 1.21E+06 1.10E-03 1.21E+06 Westlake Geismar Other 4.76E+08No 5.73E+08 8.52E+05 1.79E-03 8.52E+05 Georgia Gulf Aberdeen Other 1.00E+09 9.86E+07 Georgia Gulf Plaquemine Other 1.20E+09 1.18E+08

Average* 9.85E-02 *Average does not include CTLC due to absence of H20 in Bulk process **Stripper Outlet, Uncontrolled, and Maint. Wastewater Combined**

**Company & Facility Resin Type**  **Baseline VC (Tons/YR)**  **Baseline Total Non-VC**

**HAP (Tons/YR) VC Reduction**  **(Tons Per Year) Total Non-VC HAP Reduction**  **(Tons Per Year)** OxyVinyls Deer Park Suspension 6.34E-01 8.81E+00 1.31E-01 8.78E+00

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - Steam Stripper Costing**

**Steam Stripper - PVC Resin - Cost A nalysis - VC and TOH**  **Company** Westlake Chemical Corporation Certain Teed Lake Charles Certain Teed

Lake Charles **Facility** Westlake Geismar **Process Type** Suspension Bulk Bulk **Process Type Std** Suspension Bulk Bulk **Process Unit ID** P-1 **Stripped Resin Stream ID** S-1 **Stripping Type** Continuous Continuous Continuous **An nual Production**  476,390,000 447,348,640 551,155,000 **Inlet Stream Flow, liters/min** 1930 0.02704 130For CTLC and Model - sum of stripper outlet and uncontrolled streams **A. Parameters**  (Inputs and Ex ample Calculation)

1. Stripper inlet flow rate,lpm (Q) 500 1930 0 130 2. Annual operating hours, hr/yr (H) 8400 8400 8400 8400 3. Steamto Feed Ratio, kg /l (S) 0.096 0.060 0.060 0.060 4. Electricity use, kWhr/day (EU) 260 260 260 260 5. Operating labor rate, $/hr (LR) [2] $34.60 $34.60 $34.60 $34.60 6. Electricity cost, $/kWh (EC) [3] $0.07 $0.07 $0.07 $0.07 7. Water cost, $/1,000 gal (WC) [4] $0.20 $0.20 $0.20 $0.20 8. Steamcost, $/1,000 lb (SC) [4] $4.65 $4.65 $4.65 $4.65 9. Capital recovery factor = [i x (1 + i)a] / [(1 + i)a- 1], where i = interest rate, a = equipment life a. Equipment CRF, 20-yr life, 7% interest 0.09439 0.09439 0.09439 0.09439

10. Cost index a. 2010 641.1 641.1 641.1 641.1 b. 1989 356.0 356.0 356.0 356.0

**B. Total Capital Investment** 1. $ = 0.3731 x Q^0.267 x

10^6 $0 estimated total capital provided by facility 2. $ /lpm = $ / Q $0

**C. Direct A nnual Operating Costs, $/yr**  1. Electricity = EU / (24 hr/day) x H x EC $6,079 $6,079 $6,079 $6,079 2. Steam = Q x S x (2.2 lb/kg) x

(60 min/hr) x

H x SC / 1000 $247,484 $596,994 $8 $40,154 3. Water = Q x (5220 liters water-min / liters feed-day) x (1 day / 24 hr) x

H x (0.264 gal/liter) x WC / 1000 $0 $186,159 $3 $12,521

4. Operating labor = (1 hr/shift) x (1 shift/8 hr) x

H x LR $36,330 $0 $0 $0 5. Supervisory labor = 0.15 x (operating labor) $5,450 $0 $0 $0 6. Maintenance labor = (0.5 hr/shift) x (1 shift/8 hr) x

H x (LR x 1.1) $19,982 $0 $0 $0 7. Maintenance materials = 0.02 x TCI $0 $0 $0 $0

**D. Indirect A nnual Costs, $/yr**  1. Overhead = 0.6 x (labor + maintenance materials) $37,057 $0 $0 $0 2. Property tax

es, insurance, and administration = 0.04 x TCI $0 $0 $0 $0

3. Capital recovery = Equipment CRF x TCI $0 $0 $0 $0

**F. Include in A nnual Cost?**  yes yes yes

**F. Total A nnual Cost**  1. $/yr = Direct Annual Costs + Indirect Annual Costs - Recovery Credit $352,381 **$789,232 $6,090**  **$58,754** Sources: 1. Cost equations: HON BID, Vol 1-b and 1-c, Nov 1992 (EPA-453/D-92-016c) 2. Operating labor rate: Bureau of Labor Statistics, Occupational Employment Statistics, May 2008 National Industry-Specific Occupational Employment and Wage Estimates 3. Electricity cost: Energy Information Administration. Average Industrial Retail Price of Electricity: October 2009. 4. Water cost and steam cost: Air Compliance Advisor,version 7.5

. 5. ICIS, http://www.icis.com/v2/chemicals/9076567/vinyl-chloride/pricing.html, October 20, 2010. (Avg. $690/tonne = $0.313/lb)

**Parameters/Costs Equation** 

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater - Steam Stripper Costing**

**Steam Stripper - PVC Resin - Cost A nalysis - VC and TOH**  **Company** Westlake Chemical Corporation Certain Teed Lake Charles Ox

yVinyls Deer Park **Facility** Westlake Geismar **Process Type** Suspension Bulk Suspension **Process Type Std** Suspension Bulk Suspension **Process Unit ID** P-1 **Stripped Resin Stream ID** S-1 **Stripping Type** Continuous Continuous Continuous **An nual Production**  476,390,000 447,348,640 551,155,000 **Inlet Stream Flow, liters/min** 1930 448 1280 **A. Parameters**  (Inputs and Ex ample Calculation)

1. Stripper inlet flow rate,lpm (Q) 500 1930 448 1280 2. Annual operating hours, hr/yr (H) 8400 8400 8400 8400 3. Steamto Feed Ratio, kg /l (S) 0.096 0.060 0.060 0.060 4. Electricity use, kWhr/day (EU) 260 260 260 260 5. Operating labor rate, $/hr (LR) [2] $34.60 $34.60 $34.60 $34.60 6. Electricity cost, $/kWh (EC) [3] $0.07 $0.07 $0.07 $0.07 7. Water cost, $/1,000 gal (WC) [4] $0.20 $0.20 $0.20 $0.20 8. Steamcost, $/1,000 lb (SC) [4] $4.65 $4.65 $4.65 $4.65 9. Capital recovery factor = [i x (1 + i)a] / [(1 + i)a- 1], where i = interest rate, a = equipment life a. Equipment CRF, 20-yr life, 7% interest 0.09439 0.09439 0.09439 0.09439

10. Cost index a. 2010 641.1 641.1 641.1 641.1 b. 1989 356.0 356.0 356.0 356.0

**B. Total Capital Investment** 1. $ = 0.3731 x Q^0.267 x

10^6 $0 **$10,000,000 $4,162,340**  **$7,816,538** 2. $ /lpm = $ / Q $0 $5,182 $9,295 $6,107

**C. Direct A nnual Operating Costs, $/yr**  1. Electricity = EU / (24 hr/day) x H x EC $6,079 $0 $0 $0 2. Steam = Q x S x (2.2 lb/kg) x

(60 min/hr) x

H x SC / 1000 $247,484 $0 $138,518 $355,815 3. Water = Q x (5220 liters water-min / liters feed-day) x (1 day / 24 hr) x

H x (0.264 gal/liter) x WC / 1000 $0 $0 $43,194 $110,953

4. Operating labor = (1 hr/shift) x (1 shift/8 hr) x

H x LR $36,330 $0 $0 $0 5. Supervisory labor = 0.15 x (operating labor) $5,450 $0 $0 $0 6. Maintenance labor = (0.5 hr/shift) x (1 shift/8 hr) x

H x (LR x 1.1) $19,982 $0 $0 $0 7. Maintenance materials = 0.02 x TCI $0 $0 $0 $0

**D. Indirect A nnual Costs, $/yr**  1. Overhead = 0.6 x (labor + maintenance materials) $37,057 $0 $0 $0 2. Property tax

es, insurance, and administration = 0.04 x TCI $0 $0 $0 $0

3. Capital recovery = Equipment CRF x TCI $0 $943,929 $392,895 $737,826

**F. Include in A nnual Cost?**  yes yes yes

**F. Total A nnual Cost**  1. $/yr = Direct Annual Costs + Indirect Annual Costs - Recovery Credit $352,381 **$943,929 $574,607**  **$1,204,593** Sources: 1. Cost equations: HON BID, Vol 1-b and 1-c, Nov 1992 (EPA-453/D-92-016c) 2. Operating labor rate: Bureau of Labor Statistics, Occupational Employment Statistics, May 2008 National Industry-Specific Occupational Employment and Wage Estimates 3. Electricity cost: Energy Information Administration. Average Industrial Retail Price of Electricity: October 2009. 4. Water cost and steam cost: Air Compliance Advisor,version 7.5

. 5. ICIS, http://www.icis.com/v2/chemicals/9076567/vinyl-chloride/pricing.html, October 20, 2010. (Avg. $690/tonne = $0.313/lb)

**Parameters/Costs Equation** 

Difference in cost due to controlling previously uncontrolled streams

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Cost of Piping Additional Steams to Wastewater Stripper Feed Tank**

Wastewater Flow (GPM) 5.00E+01 Wastewater Flow (m^3/sec) 3.15E-03 Fluid Density (kg/m^3) 9.83E+02

Optimum Pipe Diameter (m) 6.66E-02 Optimum Pipe Diameter (inches) 2.62E+00 Caluclated (Rounded) Pipe Diameter (inches) 3.00E+00 **Estimated Pipe Cost (304 Stainless)* (Jan. 2002 Dollars) $/linear foot** **5.00E+01**<----- **Estimated Pipe Cost (Carbon Steel)* (Jan. 2002 Dollars) $/linear foot** **3.30E+00 Pump and Pumping Cost** 

Pump cost (w/o motor)† 3.00E+031000 gpm, 20 ft, general purpose centrifugal Power Output (kW) (brake power) 1.13E+01 Pump motor cost§ 2.00E+03Alternating Current, Explosion proof (~13 kW) Motor Efficiency‡ 8.70E-01~11.25 bkW Power requirement † (kW) 1.29E+01 Operating hours per year (Hrs) 8.40E+03 Electricity Cost ($/kWh) 7.00E-02 Electricity Cost per year ($/yr) **7.60E+03 Total Capital Investment** 

Assumed length of pipe run (ft) 5.00E+02 Purchased cost of pipe (Stainless Steel) 2.50E+04 Purchased cost of pump 3.00E+03 Purchased cost of motor 2.00E+03 Equipment Cost 3.00E+04 Installation Factor** (Ratio of total cost for fittings and installation to the purchase cost for the new pipe) 1.40E+00 Installation Cost (includes pump and moto) 4.20E+04 Tax and Freight Factor†† 8.00E-02 Tax and Freight Cost 2.40E+03 Total Capital Investment (Jan. 2002) 7.44E+04 CE - July 02 (Pipes, Valves, and Fittings) 5.64E+02 CE - Feb 2010 (Pipes, Valves, and Fittings) 7.96E+02 **Total Capital Investment (Feb. 2010) 1.05E+05**  **Annual Cost**

Annual interest rate (fraction): 7.00E-02 System life (years): 2.00E+01 Capital recovery factor: 9.44E-02 Taxes, Insurance, Admin Factor 4.00E-02 Electricity 7.60E+03 Taxes Insurance, Administrative 4.20E+03 Capital Recovery 9.92E+03 **Total Annual Cost ($/yr) 1.18E+04** does not incl. capital recovery

* From Figure 12-4 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers ** pg. 404 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers †Estimated from Figure 12-19 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers § Estimated from Figure 12-24 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers ‡ Estimated from Figure 12-18 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers †† - Eqn. 10.39 pg. 10-49 OAQPS Control Cost Manual Fifth Edition Feb. 1996 pg. 10-51 OAQPS Cost Control Manual (Ductwork)

**Pipe Cost $/Linear Foot**

Diameter 304/L. Stainless (Sch 40) Carbon Steel (Sch 40) 1.00E+00 1.70E+01 9.00E-01 2.00E+00 3.10E+01 2.10E+00 3.00E+00 5.00E+01 3.30E+00 4.00E+00 7.00E+01 5.80E+00 5.00E+00 9.00E+01 7.50E+00 6.00E+00 1.20E+02 1.00E+01 7.00E+00 1.60E+02 1.30E+01 8.00E+00 1.90E+02 1.70E+01 9.00E+00 2.10E+02 1.90E+01 1.00E+01 2.30E+02 2.00E+01 * From Figure 12-4 Peters, Timmerhaus, & West. Plant Design and Economics for Chemical Engineers

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Cost of Piping Additional Steams to Wastewater Stripper Feed Tank Assumptions** 

Assume Hard pipe wastewater flow to Stripper Feed Tank Assume all piped flow is turbulent Assume water temperature of 140F **Optimum Pipe Diameter Calculation Eq. (12-15) Peters, Timmerhaus, & West pg. 501** 

Where: Di,opt=optimum pipe diameter in meters

mv

### =volumetric flow rate (m^3/sec)

p=fluid density kg/m^3

Assumed 20 ft of head

GPM TCI TAC CR 1.00E+014.73E+041.40E+044.47E+031.84E+04 5.00E+011.05E+051.18E+049.92E+032.17E+04 1.00E+021.40E+051.32E+041.32E+042.64E+04 5.00E+022.98E+051.95E+042.81E+044.76E+04 1.00E+034.20E+052.44E+043.97E+046.41E+04

y = 16203x0.4706 

### R2 = 0.9996

y =

-0.0029x2

### + 15.149x + 12295 R2 = 0.9613 y = 1529.6x0.4705 

### R2 = 0.9996

0.00E+00 5.00E+04 1.00E+05 1.50E+05 2.00E+05 2.50E+05 3.00E+05 3.50E+05 4.00E+05 4.50E+05

0.00E+00 2.00E+02 4.00E+02 6.00E+02 8.00E+02 1.00E+03 1.20E+03 TCI

TAC

CR
Power (TCI)
Poly. (TAC)
Power (CR)

R2 = 0.9613 0.00E+00
0.00E+00 2.00E+02 4.00E+02 6.00E+02 8.00E+02 1.00E+03 1.20E+03

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

**Wastewater Testing and Monitoring Cost Algorithm**

**Wastewater Sampling and Monitoring Cost of US EPA Method 8260B**  $201 $400 $301*National Environmental Methods Index Website https://www.nemi.gov/apex/f?p=237:38:951365369293524::::P38_METHOD_ID:7041 **Cost of US EPA Method 305** $190http://analyticallaboratories.com/page.cfm?pageid=90 (Cost of Volatile Organics) **Cost of US EPA Method 107** $0Assume no cost since facilities are presumably already testing VC (Based on VI submitted data).

Number of Initial Test Runs 1.00 Number of Strippers 1.00 Number of Continuous Test Runs 1.00 Number of Continuous Tests per Year Monthly Testing 12.00

**Num ber of Uncontrolled Streams**  **(As reported in survey data) Num** **ber of Uncontrolled Streams with average for**  **mi ssing data**  **Non-VC HAP MeOH**  **VC VC**  **Total Non-VC**  **HAP MeOH**  **VC Total Non**  **VC HAP MeOH** 

CTLC/OVDP/Model Facility 1 1 $300.50 $190.00 $0.00 $0.00 $300.50 $190.00 $0.00 $3,606.00 $2,280.00 $981.00 $6,376.50

**Facility Name**  **Num ber of Wastewater streams**  Formosa Plastics Corporation Baton Rouge 1 Georgia Gulf Chemicals Aberdeen Facility 1 Lake Charles Polymer Plant 1 OxyVinyls Deer Park 1 OxyVinyls Pasadena 7 PolyOne Henry 6 Shintech Addis 3 Shintech Freeport 1 Shintech Plaquemine 2 Union Carbide Texas City 6 Westlake Calvert City 1 Westlake Geismar 2 Average 3 **In itial Uncontrolled Stream Testing**  **Stripper Outlet Testing**

**Total Initial Cost ($)**  **Total**

**Annualized Cost**  **In itial**  **Continuous**

# ATTACHMENT E- WASTEWATER ANALYSIS

02/09/2012

# ATTACHMENT F- HEAT EXCHANGER ANALYSIS

02/09/2012

**Heat Exchange Systems - Summary of Clarification Data Submitted to EPA Calculated Emissions, Reductions, and Costs** 

**Company Facility**  **CT # Flow Rate (gpm)**  **Pollutant Measured Leak Action Level**  **Units Monitoring Frequency**  **Monitoring Method Note(s)**  OVP Conc (ppbw)5.93

1 10,000Vinyl chloride Weekly Water sampling - GC headspace % of LAL 12%

2 5,000Vinyl chloride Weekly Water sampling - GC headspace Avg LAL (ppbw) 1363 Based on M107 only

Vinyl chloride 10000ppbw Quarterly Method 415.1 Avg Conc (ppbw) 162
LAL (ppbw) 50 Cost per Repair ($/tower/yr) 4300

Formosa Baton Rouge 1 48,000Vinyl chloride 10ppbw Daily Method 601 DOR LAL (ppbw) 800

1 6,000 [no data]

2 3,000 [no data] DOR Period (days)120

Formosa Point Comfort 158700 Repairs per yr 1

1 13,500Vinyl chloride 250ppbw Quarterly Method 107

2 18,000Vinyl chloride 250ppbw Quarterly Method 107 **REPORTED EMISSIONS**  **FROM SURVEY VC Conc**  **LA L**  **BASELINE EMISSIONS EMISSION**  **REDUCTIONS REPAIR COSTS** 

3 18,000Vinyl chloride 250ppbw Quarterly Method 107 **VC (tpy) (ppbw)**  **(ppbw) VC (tpy)**  **VC (tpy) ($/yr)** 

1 40,000 [cw pressure > process pressure] 1.62E+02 1.36E+03 3.54E+00 2.45E+00 4.30E+03

2 22,300 [cw pressure > process pressure] 1.62E+02 1.36E+03 1.77E+00 1.22E+00 4.30E+03

3 1,181 [no heat exchangers] 1.19E+03 1.00E+04 4.29E+01 4.11E+01 4.30E+03

4 11,000 [utility system] Vinyl chloride 5000ppbw Monthly Method 107 1.19E+00 1.00E+01 1.25E-01 0.00E+00 4.30E+03

1.62E+02 1.36E+03 2.13E+00 1.47E+00 4.30E+03

1.62E+02 1.36E+03 1.06E+00 7.34E-01 4.30E+03 Vinyl chloride 5000ppbw Monthly Method 107 1.62E+02 1.36E+03 5.62E+01 3.88E+01 4.30E+03

2.97E+01 2.50E+02 8.78E-01 0.00E+00 4.30E+03

2.97E+01 2.50E+02 1.17E+00 0.00E+00 4.30E+03 Vinyl chloride 50ppbw Monthly Method 107 2.97E+01 2.50E+02 1.17E+00 0.00E+00 4.30E+03

4.30E+03

4.30E+03 Vinyl chloride 50ppbw Monthly Method 107 4.30E+03

4.30E+03

5.93E+02 5.00E+03 1.09E+01 1.00E+01 4.30E+03

OxyVinyls Pedricktown 1 13,333Vinyl chloride 1000ppbv Continuous Similar to M106 and M21 [continuous monitoring of air above cooling tower] PolyOne Henry 39000 5.93E+02 5.00E+03 1.56E+00 1.43E+00 4.30E+03

1 1,900

2 1,850

Shintech Addis 449 9.40E-02 5.93E+00 5.00E+01 9.40E-02 0.00E+00 4.30E+03

Shintech Freeport 360
Shintech Plaquemine 433
Westlake Calvert City 1 23,000 [no data] 1.81E-01 5.93E+00 5.00E+01 1.81E-01 0.00E+00 4.30E+03

Westlake Geismar 1 10,653Vinyl chloride 50ppbw Yearly Method 107

1.19E+02 1.00E+03 3.47E+00 2.01E+00 4.30E+03

1.62E+02 1.36E+03 1.38E+01 9.54E+00 4.30E+03

1.62E+02 1.36E+03 6.73E-01 4.65E-01 4.30E+03

1.62E+02 1.36E+03 6.55E-01 4.53E-01 4.30E+03

1.62E+02 1.36E+03 1.59E-01 1.10E-01 4.30E+03

1.62E+02 1.36E+03 1.28E-01 8.81E-02 4.30E+03

1.62E+02 1.36E+03 1.53E-01 1.06E-01 4.30E+03

1.62E+02 1.36E+03 8.15E+00 5.63E+00 4.30E+03

5.93E+00 5.00E+01 1.39E-01 0.00E+00 4.30E+03

**1.51E+02 1.16E+02**  **1.16E+05** CertainTeed Lake Charles

Dow Midland 1 16,500

Formosa Delaware City

Georgia Gulf Aberdeen

Georgia Gulf Plaquemine

OxyVinyls Deer Park 1

PolyOne Pedricktown 8,400

2 1,200

OxyVinyls Pasadena 1 9,000

2 11,600

# ATTACHMENT F- HEAT EXCHANGER ANALYSIS

02/09/2012

**Calculated Emissions, Reductions, and Costs**

**Total Capital Cost Total Annual Cost**  **Control Equip T&M**  **$ $/yr**  **VCM HCl**  **D/F TOH**  **VCM HCl**  **D/F TOH** 

**Control Equip Capital Cost ($)**  **Testing and**  **Monitoring Equip**  **Capital Cost ($)**  **Control Equip**

**Annualized Capital Cost**  **($/yr) Control Equipmen Annual Cost ($/yr)**  **Testing and Monitoring**  **Equip Annualized**  **Initial Cost ($/yr)**  **Testing and**

**Monitoring Annual Cost**  **($/yr) Total Capital** 

**Cost ($) Total Annualized** 

**Cost ($/yr) Baseline - VCM**  **(TPY) Baseline - HCl** 

**(TPY) Baseline - D/F** 

**(TPY) Baseline - TOH** 

**(TPY) Reduction - VCM -** 

**(TPY) Reduction - HCl** 

**(TPY) Reductio** 

**n - D/F (TPY)**  **Reductio**

**n - TOH (TPY)** 

Certain Teed - Lake Charles Area Source Bulk 8.60E+03 5.31E+00 5.31E+00 3.67E+00 3.67E+00 PolyOne - Henry PVC - Only Suspension, Dispersion, Suspension Blending 4.30E+03 1.38E+01 1.38E+01 9.54E+00 9.54E+00 PolyOne - Pedricktown PVC - Only Dispersion 8.60E+03 1.33E+00 1.33E+00 9.18E-01 9.18E-01 Formosa - Delaware City PVC - Only Dispersion, Copolymer (VACO-D) 8.60E+03 3.19E+00 3.19E+00 2.20E+00 2.20E+00

Dow - Midland PVC - Combined Copolymer (VDCO-S) 4.30E+03 4.29E+01 4.29E+01 4.11E+01 4.11E+01 Formosa - Baton Rouge PVC - Combined Suspension 4.30E+03 1.25E-01 1.25E-01 0.00E+00 0.00E+00

Formosa - Point Comfort PVC - Combined Suspension 4.30E+03 5.62E+01 5.62E+01 3.88E+01 3.88E+01

Georgia Gulf - Aberdeen PVC - Only Suspension 1.29E+04 3.22E+00 3.22E+00 0.00E+00 0.00E+00

Georgia Gulf - Plaquemine PVC - Combined Suspension 1.72E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 OxyVinyls - Deer Park PVC - Combined Suspension 8.60E+03 1.25E+01 1.25E+01 1.14E+01 1.14E+01 OxyVinyls - Pasadena PVC - Only Suspension 8.60E+03 2.75E-01 2.75E-01 0.00E+00 0.00E+00 OxyVinyls - Pedricktown PVC - Only Suspension 4.30E+03 3.47E+00 3.47E+00 2.01E+00 2.01E+00

Shintech - Addis PVC - Only Suspension 4.30E+03 1.59E-01 1.59E-01 1.10E-01 1.10E-01 Shintech - Freeport PVC - Only Suspension 4.30E+03 1.28E-01 1.28E-01 8.81E-02 8.81E-02 Shintech - Plaquemine PVC - Combined Suspension 4.30E+03 1.53E-01 1.53E-01 1.06E-01 1.06E-01

Westlake - Calvert City PVC - Combined Suspension 4.30E+03 8.15E+00 8.15E+00 5.63E+00 5.63E+00

Westlake - Geismar PVC - Combined Suspension 4.30E+03 1.39E-01 1.39E-01 0.00E+00 0.00E+00 **Control Equip T&M** 

**MACT Floor Costs Baseline Emissions and MACT Floor Emissions Reductions**  **MACT Floor Capital Cost ($) MACT Floor - Annual Costs ($/yr)**  **Baseline Emissions (TPY) MACT Floor Emissions Reductions (TPY)** 

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Summary & Costs** 

**RTI Equipment Leaks Options Cost Summary Capital Costs**  **Annualized Capital Costs Annual Costs**  **Total Annualized Costs**

Pumps - Option 1 2.23E+03 

### 3.65E+02 7.85E+01 4.43E+02 Valves - Option 1 

### 4.53E+03 6.43E+02 2.39E+02 8.82E+02 Connectors - Option 1 

### 5.75E+04 8.16E+03 6.18E+03 1.43E+04
Total 

### 6.42E+04 9.17E+03 6.50E+03 1.57E+04

**Cost Summary for PRD Monitoring Systems**

**CTLC** 

### 1.13E+05 1.61E+04

**Cost Summary for Equipment Leaks**

**Company LDAR Program** **[1]** 

### (A) PRV Monitoring **System Capital Cost ($) (B) Capital Cost**  **Increase of LDAR ($) (C) Initial Record Keeping**  **and Reporting (D) TCI ($)**  **C=A+B+C (E) Annualized** 

**Capital Cost Increase of**  **LDAR (F) Annual Increase** 

**in LDAR Cost (G) Total Annualized** 

**Increase LDAR Cost G=E+F**  **(H) Annualize**

**Capital Cost of PRV Monitoring**  **System ($) (I) Annual** 

**Record Keeping and Reporting**  **(J) TAC ($)**

**J=G+H+I Baseline** 

**Emission[2] (Tons/yr)**  **Estimated Emission**

**Reductions (Tons/yr)**

Certain Teed - Lake Charles 40CFR61 V 1.13E+05 6.42E+04 2.62E+03 1.80E+05 9.17E+03 6.50E+03 1.57E+04 1.61E+04 4.49E+03 3.63E+04 1.00E+01 4.64E+00 OxyVinyls Deer Park 40CFR61 V 1.13E+05 6.42E+04 2.62E+03 1.80E+05 9.17E+03 6.50E+03 1.57E+04 1.61E+04 4.49E+03 3.63E+04 1.00E+01 4.64E+00 New Source Model 40CFR61 V 1.13E+05 6.42E+04 2.62E+03 1.80E+05 9.17E+03 6.50E+03 1.57E+04 1.61E+04 4.49E+03 3.63E+04 1.00E+01 4.64E+00

**Component**

Source Type **EPA PRD Monitoring Costs** 

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Emissions**

**Type of Component Number of**  **Components 1**  

### SubpartV Emission **Factor (kg/hr/equipment)**  **Subpart UU Emission Factor**  **(kr/hr/equipment) Subpart V**  **Emissions (Tons/yr)**  **Subpart UU**

**Emissions (Tons/yr)**  **Emission**

**Reduction (Tons/yr)** 

**Pump Seals** * Light-liquid service 15 2.51E-03 6.95E-04 3.49E-01 9.65E-02 2.52E-01 * Heavy-liquid service 0

**Valves** * Gas/vapor service 762 3.52E-04 2.03E-04 2.48E+00 1.43E+00 1.05E+00 * Light-liquid service 153 3.90E-04 2.32E-04 5.53E-01 3.29E-01 2.24E-01 * Heavy-liquid service 0

**Connectors** * Flanges - gas/vapor 0 3.07E-04 3.07E-04 0.00E+00 0.00E+00 0.00E+00 * Flanges - light liquid 2,322 3.07E-04 1.62E-04 6.60E+00 3.48E+00 3.12E+00 * Flanges -heavy liquid 0

**Agitators** * Light-liquid service 0 2.51E-03 2.51E-03 0.00E+00 0.00E+00 0.00E+00 * Heavy-liquid service 0

**Pressure Relief Devices** * Disks 2 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 * Disk holders, valves,etc. 2 NA NA

**Open-ended Valves** 33 3.33E-05 3.33E-05 1.02E-02 1.02E-02 0.00E+00

**Sampling Connections** 8 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00

**Compressor Vent** 0 2.28E-02 2.28E-02 0.00E+00 0.00E+00 0.00E+00

**Facility Total 1.00E+01**  **5.35E+00 4.64E+00** 

Equipment Counts from "Testing-Inspections-Environmental" "Re: Stratified data for 2008 monitoring" Bruce Brocka, Certain Teed Corp. Note that Flanges/Connectors were not Gas/Vapor or Light Liquid Specified - Assumed Light Liquid.

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Subpart V Cost (Based on CTLC Equipment Counts)**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent Repaired OnLine Repair

Time (hours) Labor Charge ($/hr) Annual OnLine Leak Repair Cost ($/yr) Percent

Requiring Further RepairRepair

Time (hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Pump Seals**

* Light-liquid service 1.50E+01 2.38E+01 7.42E+02 1.20E+01 1.50E+00 5.80E+02 1.16E+02 2.42E+003.63E-01 2.29E-014.11E-011.00E+02############ 4.36E+02 0.00E+00############# 0.00E+00 6.17E-01 9.31E+01 * Heavy-liquid service 0.00E+00 1.10E+00 0.00E+00

**Valves** * Gas/vapor service 7.62E+02 2.38E+01 1.83E+04 2.00E+00 1.50E+00 2.29E+03 3.34E-012.55E+00 3.34E-015.09E+007.50E+01############ 4.22E+01 2.50E+01############# 3.37E+02 7.64E+00 * Light-liquid service 1.53E+02 2.38E+01 3.68E+03 2.00E+00 1.50E+00 4.59E+02 3.34E-015.11E-01 3.34E-011.02E+007.50E+01############ 8.48E+00 2.50E+01############# 6.77E+01 1.53E+00 * Heavy-liquid service 0.00E+00 1.10E+00 0.00E+00

**Connectors** * Flanges - gas/vapor 0.00E+00 1.10E+00 0.00E+00 * Flanges - light liquid 2.32E+03 1.10E+00 2.56E+03 * Flanges -heavy liquid 0.00E+00 1.10E+00 0.00E+00

**Agitators** * Light-liquid service 0.00E+00 2.38E+01 0.00E+00 1.20E+01 1.50E+00 0.00E+00 0.00E+00 2.42E+000.00E+00 2.29E-010.00E+001.00E+02############ 0.00E+00 0.00E+00############# 0.00E+00 0.00E+00 0.00E+00 * Heavy-liquid service 0.00E+00 1.10E+00 0.00E+00

**Pressure Relief Devices** * Disks 2.00E+00 1.22E+02 2.44E+02 0.00E+00 2.00E+00 0.00E+00 4.88E+00 9.77E+00 * Disk holders, valves,etc. 2.00E+00 6.37E+03 1.27E+04 5.00E+00 6.37E+02 5.10E+02

**Open-ended Valves** 3.30E+01 1.41E+02 4.65E+03 5.00E+00 2.33E+02 1.86E+02

**Sampling Connections** 8.00E+00 6.88E+02 5.50E+03 5.00E+00 2.75E+02 2.20E+02

**Compressor Vent** 0.00E+00 1.05E+04 0.00E+00 5.00E+00 0.00E+00 0.00E+00

**Replacement Pump Seals** 1.50E+01 2.83E+02 1.03E+02 **Monitoring Instrument** 1.00E+00 1.08E+04 1.08E+04 **Data Collection System** 1.00E+00 1.45E+04 1.45E+04

hr/activity $/hr **Administrative and Reports** 2.50E+02 9.27E+01 2.32E+04 **Planning and Training** 3.20E+02 9.27E+01 2.97E+04

**TOTALS** 7.39E+04 2.97E+04 3.33E+03 1.27E+03 4.87E+02 4.05E+02 1.77E+01 2.32E+04 1.02E+03

Capital Costs 103,539 Capital Rec. Fac for Pump Seals and Rupture Disks 0.244

Capital Rec. Fac for All other Equipment 0.142

Annualized Capital Costs 14,738 Annual Expenses 29,700 Annual Fixed Costs ($/yr) 103,049 44,438 Annual Variable Costs ($/yr) 26,861

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Pumps Option 1 Cost (Based on CTLC Equipment Counts)**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent Repaired OnLine Repair

Time (hours) Labor Charge ($/hr) Annual OnLine Leak Repair Cost ($/yr) Percent

Requiring Further RepairRepair

Time (hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Pump Seals**

* Light-liquid service 1.50E+01 0.00E+00 2.15E+03 1.20E+01 1.50E+00 1.55E+03 1.30E+02 1.35E+012.02E+00 2.56E-014.61E-011.00E+02############ 4.89E+02 0.00E+00############# 0.00E+00 6.92E-01 1.04E+02 * Heavy-liquid service 0.00E+00 0.00E+00 0.00E+00

**Replacement Pump Seals** 4.00E+01 2.83E+02 5.72E+02
hr/activity $/hr **Administrative and Reports** 0.00E+00 9.27E+01 0.00E+00 **Planning and Training** 0.00E+00 9.27E+01 0.00E+00

**TOTALS** 2.72E+03 0.00E+00 1.55E+03 1.30E+02 4.89E+02 0.00E+00 1.85E+00 0.00E+00 1.04E+02

Capital Costs 2.72E+03 Capital Rec. Fac for Pump Seals and Rupture Disks 2.44E-01

Capital Rec. Fac for All other Equipment 1.42E-01

Annualized Capital Costs 4.44E+02 Annual Expenses 2.27E+03

**Baseline Monitoring**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent Repaired OnLine Repair

Time (hours) Labor Charge ($/hr) Annual OnLine Leak Repair Cost ($/yr) Percent

Requiring Further RepairRepair

Time (hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Pump Seals**

* Light-liquid service 1.50E+01 0.00E+00 3.85E+02 1.20E+01 1.50E+00 1.55E+03 1.16E+02 2.42E+003.63E-01 2.29E-014.11E-011.00E+02############ 4.36E+02 0.00E+00############# 0.00E+00 6.17E-01 9.31E+01 * Heavy-liquid service 0.00E+00 0.00E+00 0.00E+00

**Replacement Pump Seals** 4.00E+01 2.83E+02 1.03E+02
hr/activity $/hr **Administrative and Reports** 0.00E+00 9.27E+01 0.00E+00 **Planning and Training** 0.00E+00 9.27E+01 0.00E+00

**TOTALS** 4.88E+02 0.00E+00 1.55E+03 1.16E+02 4.36E+02 0.00E+00 1.85E+00 0.00E+00 9.31E+01 Monitoring Repair Capital Costs 4.88E+02 4.88E+02 Capital Rec. Fac for Pump Seals and Rupture Disks 2.44E-01

Capital Rec. Fac for All other Equipment 1.42E-01

Annualized Capital Costs 7.98E+01 7.98E+01 Annual Expenses 2.19E+03 1.55E+03 5.52E+02

**Incremental Capital Costs 2.23E+03**  **Incremental Annual Costs 4.43E+02** 

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Valves Option 1 Cost (Based on CTLC Equipment Counts)**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent

Repaired OnLine Repair

Time (hours) Labor

Charge ($/hr) Annual

OnLine Leak Repair Cost ($/yr) Percent

Requiring Further Repair Repair

Time (hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Valves**

* Gas/vapor service 7.62E+02 0.00E+00 4.20E+03 2.00E+00 1.50E+00 2.29E+03 7.24E+00 5.52E+01 5.06E-01 7.71E+007.50E+01 1.67E-01 6.62E+01 6.40E+01 2.50E+01 4.00E+006.62E+01 5.11E+02 1.16E+01 * Light-liquid service 1.53E+02 0.00E+00 5.63E+02 2.00E+00 1.50E+00 4.59E+02 4.84E+00 7.41E+00 5.06E-01 1.55E+007.50E+01 1.67E-01 6.62E+01 1.28E+01 2.50E+01 4.00E+006.62E+01 1.03E+02 2.32E+00 * Heavy-liquid service 0.00E+00 0.00E+00 0.00E+00 hr/activity $/hr **Administrative and Reports** 0.00E+00 9.27E+01 0.00E+00 **Planning and Training** 0.00E+00 9.27E+01 0.00E+00

**TOTALS** 4.76E+03 0.00E+00 2.75E+03 0.00E+00 7.68E+01 6.13E+02 1.39E+01 0.00E+00 0.00E+00

Capital Costs 4.76E+03 Capital Rec. Fac for Pump Seals and Rupture Disks 2.44E-01

Capital Rec. Fac for All other Equipment 1.42E-01

Annualized Capital Costs 6.76E+02 Annual Expenses 3.45E+03

**Baseline Monitoring**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent

Repaired OnLine Repair

Time (hours) Labor

Charge ($/hr) Annual

OnLine Leak Repair Cost ($/yr) Percent

Requiring Further Repair Repair

Time (hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Valves**

* Gas/vapor service 7.62E+02 0.00E+00 1.94E+02 2.00E+00 1.50E+00 2.29E+03 3.34E-01 2.55E+00 3.34E-01 5.09E+007.50E+01 1.67E-01 6.62E+01 4.22E+01 2.50E+01 4.00E+006.62E+01 3.37E+02 7.64E+00 * Light-liquid service 1.53E+02 0.00E+00 3.89E+01 2.00E+00 1.50E+00 4.59E+02 3.34E-01 5.11E-01 3.34E-01 1.02E+007.50E+01 1.67E-01 6.62E+01 8.48E+002.50E+01 4.00E+006.62E+01 6.77E+01 1.53E+00 * Heavy-liquid service 0.00E+00 0.00E+00 0.00E+00 hr/activity $/hr **Administrative and Reports** 0.00E+00 9.27E+01 0.00E+00 **Planning and Training** 0.00E+00 9.27E+01 0.00E+00

**TOTALS** 2.32E+02 0.00E+00 2.75E+03 0.00E+00 5.07E+01 4.05E+02 9.17E+00 0.00E+00 0.00E+00

Capital Costs 2.32E+02 Capital Rec. Fac for Pump Seals and Rupture Disks 2.44E-01

Capital Rec. Fac for All other Equipment 1.42E-01

Annualized Capital Costs 3.30E+01 Annual Expenses 3.21E+03

**Incremental Capital Costs 4.53E+03**  **Incremental Annual Costs 8.82E+02** 

# ATTACHMENT G- EQUIPMENT LEAKS ANALYSIS

02/09/2012

**Equipment Leaks Connectors Option 1 Cost (Based on CTLC Equipment Counts)**

Type of Component Number of Components Initial

Monitoring Fee or Unit Cost ($/comp) Initial LDAR

Costs ($/yr) (Capital) Initial LDAR

Admin. Costs Frequency of

Monitoring (times/yr) Subsequent

Monitoring Fee ($/comp) or Charge (%) Annual

Monitoring Costs ($/yr) Annual

Maintenance Costs ($/yr) Initial Leak

Frequency (%) Initial

Number of Leaks Subsequent

Leak Frequency (%) Annual

Number of Leaks Percent

Repaired OnLine Repair

Time (hours) Labor

Charge ($/hr) Annual

OnLine Leak Repair Cost ($/yr) Percent

Requiring Further RepairRepair Time

(hours) Labor

Charge ($/hr) Annual Offline

Leak Repair Cost ($/yr) Monitoring

to Verify Repair ($) Annual

Admin. Cost ($/yr) Annual

Misc. Charges ($/yr)

Model 2 **Connectors**

* Flanges - gas/vapor 0.00E+00 2.38E+01 0.00E+00 2.00E-01 2.50E+00 0.00E+00 3.60E-01 0.00E+00 3.60E-01 0.00E+007.50E+01 1.67E-01 6.62E+01 0.00E+00 2.50E+01 2.00E+00####### 0.00E+00 0.00E+00 * Flanges - light liquid 2.32E+03 2.38E+01 5.56E+04 2.50E-01 2.50E+00 1.45E+03 3.60E-01 8.36E+00 3.60E-01 2.09E+007.50E+01 1.67E-01 6.62E+01 1.73E+01 2.50E+01 2.00E+00####### 6.92E+01 5.22E+00 * Flanges -heavy liquid 0.00E+00 0.00E+00 0.00E+00

hr/activity $/hr **Administrative and Reports** 5.00E+01 9.27E+01 4.64E+03 **Planning and Training** 2.00E+01 9.27E+01 1.85E+03

1.45E+03 0.00E+00 1.73E+01 6.92E+01 5.22E+00 0.00E+00 0.00E+00 **TOTALS** 5.56E+04 1.85E+03 1.45E+03 0.00E+00 1.73E+01 6.92E+01 5.22E+00 4.64E+03 0.00E+00

Capital Costs **5.75E+04** Capital Rec. Fac for Pump Seals and Rupture Disks 2.44E-01

Capital Rec. Fac for All other Equipment 1.42E-01

Annualized Capital Costs **8.16E+03** Annual Expenses **6.18E+03**

# ATTACHMENT H- OTHER EMISSION SOURCES ANALYSIS

02/09/2012

**Other Emission Sources**

Calculated GACT Baseline

**Emission Source Existing Source**  **New Source Notes**  **Reactor Openings** Subpart F Subpart F
**Gas Holders** No Control No Control No Gas Holders at Existing Area Sources



### Existing and New

Source GACT Summary for Other Emission Sources

**Emission Source Existing Source**  **GACT Limit Option 1 Limit (Existing** 

**Source Requirements) Emissions Reductions as a Result of**  **Option 1 Complaince (tons/yr) Reactor Openings**  Subpart F Subpart F

- **Gas Holders** No Control Floating Objects 

### 6.16E-01

**GACT Analysis - OES - New and Existing Area Sources Cost Component**  **CTLC OVDP**  **Model New Facility** 

### Initial Costs Control Equipment Capital Cost 5.00E+03 Initial Record Keeping and Reporting Cost 1.10E+03 1.10E+03 1.10E+03 **Total Initial Costs 1.10E+03**  **1.10E+03 6.10E+03**  **Annual Costs** Annualized Capital Cost 9.28E+02 Annual Equipment Cost 5.50E+02 Annual Record Keeping and Reporting Cost 1.55E+03 1.55E+03 1.55E+03 **Total Annual Cost 1.55E+03**  **1.55E+03 3.03E+03** 

# ATTACHMENT H- OTHER EMISSION SOURCES ANALYSIS

02/09/2012

**Other Emission Sources - Reactor Opening Emissions**

**Total VOC Vinyl Chloride**  **Methanol Total VOC**  **Vinyl Chloride Methanol**  **Total Organic HAP**  **Company Facility**  **Process VC (tpy)**  **TOH (TPY)**

CertainTeed Lake Charles B Reactor Openings 6.69E+01 0.00E+00 6.69E+01 0.00E+00 6.69E+01 CertainTeed Lake Charles B 3.35E-02 3.35E-02 Dow Midland S 0.00E+00 6.69E+01 0.00E+00 6.69E+01 Dow Midland S 3.35E-02 3.35E-02 Dow (Union Carbide) Texas City SL Filter Openings 8.81E-01 0.00E+00 6.69E+01 8.81E-01 6.78E+01 Dow (Union Carbide) Texas City SL 3.35E-02 3.39E-02 Formosa Baton Rouge S Filter Openings 1.03E+02 1.03E+02 1.03E+02 1.03E+02 0.00E+00 1.03E+02 Formosa Baton Rouge S 5.13E-02 5.13E-02 Formosa Baton Rouge S Reactor Openings 8.62E+01 8.62E+01 8.62E+01 8.62E+01 0.00E+00 8.62E+01 Formosa Baton Rouge S 4.31E-02 4.31E-02 Formosa Baton Rouge S Vessel Openings 1.03E+02 1.03E+02 1.03E+02 1.03E+02 0.00E+00 1.03E+02 Formosa Baton Rouge S 5.13E-02 5.13E-02 Formosa Deleware City D Reactor Openings 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Formosa Deleware City D 0.00E+00 0.00E+00 Formosa Point Comfort - PVC Unit S Filter Openings 1.60E-01 1.60E-01 1.60E-01 1.60E-01 0.00E+00 1.60E-01 Formosa Point Comfort - PVC Unit S 8.00E-05 8.00E-05 Formosa Point Comfort - PVC Unit S Reactor Openings 2.13E+02 2.13E+02 2.13E+02 2.13E+02 0.00E+00 2.13E+02 Formosa Point Comfort - PVC Unit S 1.07E-01 1.07E-01 Formosa Point Comfort - PVC Unit S Stripping Column 1.90E+00 1.90E+00 1.90E+00 1.90E+00 0.00E+00 1.90E+00 Formosa Point Comfort - PVC Unit S 9.50E-04 9.50E-04 Formosa Point Comfort - PVC Unit S Vessel Openings 9.96E+00 9.96E+00 9.96E+00 9.96E+00 0.00E+00 9.96E+00 Formosa Point Comfort - PVC Unit S 4.98E-03 4.98E-03 Georgia Gulf Aberdeen S Vessel Openings 0.00E+00 6.69E+01 0.00E+00 6.69E+01 Georgia Gulf Aberdeen S 3.35E-02 3.35E-02 Georgia Gulf Plaquemine S Reactor Openings 0.00E+00 6.69E+01 0.00E+00 6.69E+01 Georgia Gulf Plaquemine S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Filter Openings 5.50E-03 5.50E-03 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Foam Trap 5.70E-02 5.70E-02 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Reactor Openings 3.03E+01 3.03E+01 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Stripping Column 3.04E-01 3.04E-01 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Vessel Openings 1.01E+00 1.01E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Deer Park S Waste Water Stripper 0.00E+00 0.00E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Deer Park S 3.35E-02 3.35E-02 OxyVinyls Pasadena S Condensers 1.90E-01 1.90E-01 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pasadena S 3.35E-02 3.35E-02 OxyVinyls Pasadena S Filter Openings 4.70E-02 4.70E-02 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pasadena S 3.35E-02 3.35E-02 OxyVinyls Pasadena S Reactor Openings 8.23E+00 8.23E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pasadena S 3.35E-02 3.35E-02 OxyVinyls Pasadena S Vessel Openings 2.61E+01 1.00E-02 2.61E+01 1.00E-02 0.00E+00 1.00E-02 OxyVinyls Pasadena S 5.00E-06 5.00E-06 OxyVinyls Pasadena S Wash Columns 8.60E-01 8.60E-01 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pasadena S 3.35E-02 3.35E-02 OxyVinyls Pedricktown S Filter Openings 0.00E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pedricktown S 3.35E-02 3.35E-02 OxyVinyls Pedricktown S Reactor Openings 4.89E+00 4.89E+00 4.89E+00 4.89E+00 0.00E+00 4.89E+00 OxyVinyls Pedricktown S 2.45E-03 2.45E-03 OxyVinyls Pedricktown S Recovery Separators 0.00E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pedricktown S 3.35E-02 3.35E-02 OxyVinyls Pedricktown S Stripping Column 4.89E+00 4.89E+00 4.89E+00 4.89E+00 0.00E+00 4.89E+00 OxyVinyls Pedricktown S 2.45E-03 2.45E-03 OxyVinyls Pedricktown S Vessel Openings 0.00E+00 6.69E+01 0.00E+00 6.69E+01 OxyVinyls Pedricktown S 3.35E-02 3.35E-02 PolyOne Henry S, D Reactor Openings 0.00E+00 6.69E+01 0.00E+00 6.69E+01 PolyOne Henry S, D 3.35E-02 3.35E-02 PolyOne Pedricktown D Reactor Openings 7.69E+03 5.49E+05 4.00E-02 4.00E-02 0.00E+00 4.00E-02 PolyOne Pedricktown D 2.00E-05 2.00E-05 PolyOne Pedricktown D Vessel Openings 3.58E-02 3.58E-02 3.58E-02 3.58E-02 0.00E+00 3.58E-02 PolyOne Pedricktown D 1.79E-05 1.79E-05 Shintech Addis S Reactor Openings 1.33E+01 1.33E+01 1.33E+01 1.33E+01 0.00E+00 1.33E+01 Shintech Addis S 6.65E-03 6.65E-03 Shintech Freeport S Reactor Openings 3.90E+02 0.00E+00 3.90E+02 0.00E+00 3.90E+02 Shintech Freeport S 1.95E-01 1.95E-01 Shintech Freeport S Storage Sphere 5.11E+00 0.00E+00 5.11E+00 0.00E+00 5.11E+00 Shintech Freeport S 2.56E-03 2.56E-03 Shintech Plaquemine S Reactor Openings 5.00E+02 5.00E+02 5.00E+02 5.00E+02 0.00E+00 5.00E+02 Shintech Plaquemine S 2.50E-01 2.50E-01 Westlake Calvert City S Reactor Openings 1.78E+02 1.78E+02 1.78E+02 1.78E+02 0.00E+00 1.78E+02 Westlake Calvert City S 8.88E-02 8.88E-02 Westlake Calvert City S Stripping Column 2.72E+00 2.72E+00 2.72E+00 2.72E+00 0.00E+00 2.72E+00 Westlake Calvert City S 1.36E-03 1.36E-03 Westlake Calvert City S Vessel Openings 3.00E-03 3.00E-03 3.00E-03 3.00E-03 0.00E+00 3.00E-03 Westlake Calvert City S 1.50E-06 1.50E-06 Westlake Geismar S Reactor Openings 1.05E+02 1.05E+02 1.05E+02 1.05E+02 0.00E+00 1.05E+02 Westlake Geismar S 5.25E-02 5.25E-02

* Excluded: compressors, pumps, exchangers. **Average of Reported Emissions >0 lb/yr  PolyOne included with dispersion. Bulk 0.00E+00 6.69E+01 0.00E+00 ** Bulk** 0.00E+00 3.35E-02 0.00E+00 3.35E-02 *** Dow - Midland added; no emissions reported from equipment openings. Dispersion 3.58E-02 3.58E-02 0.00E+00 **Dispersion** 3.79E-05 3.35E-02 0.00E+00 3.35E-02 All Other 5.57E+01 1.01E+02 8.81E-01 **All Other** 6.96E-01 1.40E+00 0.00E+00 1.40E+00 Reported values from PolyOne - Pedricktown excluded. **TOTAL** 6.96E-01 **1.46E+00** 0.00E+00 **1.46E+00** Average value applied to PolyOne - Pedricktown 0.6960 **Total 2008 Emissions (lbs) Company**  **Facility Process**  **Equipment Total 2008 Emissions (lbs)** 

# ATTACHMENT H- OTHER EMISSION SOURCES ANALYSIS

02/09/2012

**Other Emission Sources - Gas Holders**

Facility Number of Gas Holders Total Initial Cost Annualized Capital Cost Annual Equipment Cost Total Annualized Cost Emission Reduction (TPY) New Model Area Source 1 5.00E+03 9.28E+02 5.50E+02 1.48E+03 6.16E-01

**Public Comment Data** 15 gas holders at 7 locations1


### Total annual fugitive emissions1 

### A small gas holder's estimated fugitive emissions are approximately 0.88 tons per year VCM, while larger gas holder could emit 3.3. (Average = 2.09 TPY) Floating Object installed Cost2 

### $5,000per gas holder Estimated emission reduction from floating objects2 

### 70% Westlake Geismar cost of mats (does not include installation)2 

### $3,000**Option 1 Lim it (Existing Source Requirements)**  

### Table B.2 Total Capital Investment and Total Annualized Cost Estimate: Flow Indicator - Gas Phase

**Component Equation**  **Cost ($) Capital and Other Initial Costs**  **Total Capital Investment ($2011)** TCI **5.00E+03 Annualized Costs**  Maintenance and repairs3 

### O&M=.07*TCI 3.50E+02
Taxes, Insurance3 

### TI=0.04*TCI 2.00E+02
Interest Rate3 

### i 7.00E-02 Equi pment Life3

### (years) n 7.00E+00 Capital Recovery Factor4 

### CRF=(i*(1+i)n

### )/((1+i)n

### -1) 1.86E-01 Capital Recovery 4 

### CR=CFR*TCI 9.28E+02 **Total Annualized Costs ($/yr) ($2011)** TAC=O&M+TI+CR **1.48E+03**

**LOW HIGH**  **Area Source VCM Removed (ton/yr)** (ton per gas holder)*(%Reduction) **6.16E-01 2.31E+00** 

**References** 1 - Com ments Of The Vinyl Institute, Inc., PVC Mact Working Group. Docket ID No. EPA-HQ-OAR-2002-0037 2 - Krock, Richard P. Memorandum to Ms. Jodi Howard. "Vinyl Institute Response to EPA Request for Additional Information on Work Practices for Gasholders at PVC Resin Manufacturing Facilities." September 22, 2011 3 - Peters, Ti

mmerhaus, and West. "Plant Design and Economics for Chemical Engineers." Fifth Edition. McGraw Hill. New York, NY. 2003. pg. 268 4 - U.S. EPA. "Ai

r Pollution Control

Cost Manual." Sixth Edition (EPA/452/B-02-001). January 2002 pg 2-21

# ATTACHMENT H- OTHER EMISSION SOURCES ANALYSIS

02/09/2012

# ATTACHMENT J- STORAGE VESSELS ANALYSIS

02/09/2012

**Storage - Baseline Emissions**

**Baseline Emissions A nalysis for Storage Tanks** 

**Total VOC Total Organic HA** **P Vinyl Chloride**  **Total VOC Total Organic HA** **P Vinyl Chloride**  **Total VOC Total Organic HA** **P Vinyl Chloride**  CertainTeed Lake Charles B 2.00E-01 2.00E-01 2.00E-01 2.00E-01 0.00E+00 1.00E-04 0.00E+00 Formosa Delaware City D 7.06E+02 7.06E+02 7.06E+02 7.06E+02 0.00E+00 3.53E-01 0.00E+00 PolyOne Henry D 7.06E+02 7.06E+02 0.00E+00 3.53E-01 0.00E+00 PolyOne Pedricktown D 7.06E+02 7.06E+02 0.00E+00 3.53E-01 0.00E+00 Dow Midland S 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Dow (Union Carbide)Tex as City SL 7.20E+02 7.20E+02 7.20E+02 7.20E+02 6.72E+02 3.60E-01 3.36E-01 Formosa Baton Rouge S 2.01E+03 2.44E+03 2.01E+03 2.44E+03 6.72E+02 1.22E+00 3.36E-01 Formosa Point Comfort - PVC S 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 Georgia Gulf Aberdeen S 1.02E+03 9.85E+02 6.72E+02 4.92E-01 3.36E-01 Georgia Gulf Plaquemine S 1.02E+03 9.85E+02 6.72E+02 4.92E-01 3.36E-01 Ox yVinyls Deer Park S 1.02E+03 9.85E+02 6.72E+02 4.92E-01 3.36E-01 Ox yVinyls Pasadena S 1.02E+03 9.85E+02 6.72E+02 4.92E-01 3.36E-01 Ox yVinyls Pedricktown S 1.02E+03 9.85E+02 6.72E+02 4.92E-01 3.36E-01 Shintech Addis S 2.58E+03 2.12E+03 1.80E+03 2.58E+03 2.12E+03 1.80E+03 1.06E+00 8.99E-01 Shintech Freeport S 1.31E+03 4.03E+02 1.31E+03 4.03E+02 6.72E+02 2.02E-01 3.36E-01 Shintech Plaquemine S 4.20E+02 1.80E+02 1.80E+02 4.20E+02 1.80E+02 1.80E+02 9.02E-02 9.02E-02 Westlake Calvert City S 9.60E-02 0.00E+00 9.60E-02 0.00E+00 6.72E+02 0.00E+00 3.36E-01 Westlake Geismar S 7.36E+01 4.65E+01 3.94E+01 7.36E+01 4.65E+01 3.94E+01 2.32E-02 1.97E-02

**Av erage of Reported Emissions >0 lb/yr**  **Totals in Tons per Year** Bulk 2.00E-01 2.00E-01 0.00E+00 **Bulk** 1.00E-04 1.00E-04 0.00E+00 Dispersion 7.06E+02 7.06E+02 0.00E+00 **Dispersion** 1.06E+00 1.06E+00 0.00E+00 All Other 1.02E+03 9.85E+02 6.72E+02 **Al l Other**  5.74E+00 5.06E+00 3.70E+00 **TOTA L**  **6.80E+00 6.12E+00**  **3.70E+00** 6.12E+00 3.70E+00 * PolyOne - Henry included in dispersion category. **Baseline Emissions, tons/yr**

** Average of reported emissions grater than zero for each category applied to facilities in that category that did not report emissions. *** Certain Teed did not report a value for Vinyl Chloride - Since there are no other bulk facilities, a value of zero

was assumed **Company Facility**  **Process Reported Emissions, lb/yr**  **Baseline Emissions, lb/yr**