## COMPLIANCE TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -003

PARTICULATE MATTER, SULFUR DI OXIDE, AND, VISIBLE EMISSIONS EVALUATION Febru a r y 25, 2005

Prepared For: Tampa Elec tric Compa n y Polk P ower Station P.O. Box 1 11 Tampa, Florida 33601-0111

Prepared By: Tampa Elec tric Compa n y Environme n tal, Health & Safety Environme n tal Service s Air Services Group

Envi ronme n tal Servi c es Ai r Servi c es Grou p 5010 Cau s e w ay Boul eva r d Tampa, Fl ori da 336 19- 6 1 30

### REPORT CERTIFICATION

I ha ve revi ewed the t e st performa nce, associated quality assura nce activities, the resulta n t calculations, a n d the contents of this report, a n d certify that a ll proj ect quality obj ectives have been met. Th is r

e port is approved for submitta l.

Signature:__________________________ Raymond A

. McDarby, Jr. Senior Envi ronmenta l Technician Quality Assurance/Quality Control Specialist Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

The sampling and subseque nt da ta entry/reduction det a iled in this report were cond ucted at m y d i rection

, and I here by certif y

th at th is test report is authentic and accurate to th e best of my knowledge.

Signature:__________________________ Charles R. Dufeny Enviro nme n tal Techni cian Test Team Lead Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

I ha ve revi ewed the t e sting deta ils and results subm itt e d in th is r e port, and hereby certify that this test report is authenti c and accurate to the best of my k n owle dge.

Signature:__________________________ Davi d A

. S m ith Coordi nator – Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

### TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1
2.0 DISCUSSION OF RESULTS 2
3.0 SOURCE DESCRIPTION/TEST PROCEDURES 3
4.0 TEST RESULTS PARTICULATE TEST SUMMARY (SOOT BLOWING) 6 PARTICULATE TEST SUMMARY (NON-SOOT BLOWING) 7
SULFUR DIOXIDE DATA SUMMARY 8
VISIBLE EMISSIONS DATA SU MMARY (SOOT BLOWING) 9
VISIBLE EMISSIONS DATA SU MMARY (NON-SOOT BLOWING) 10
HEAT INPUT AND FUEL CONSUMPTION SUMMARY 11
5.0 FIGURES
SAMPLING LOCATION DIAGRAM 13

APPENDICIES

A PARTICULTE TEST CALCULATIONS
B DAILY SULFUR DIOXIDE DATA SUMMARY
C PARTICULATE LABORATORY ANALYTICAL DATA
D BOILER/PRECIPITATOR OPERATIONAL DATA
E FUEL ANALYSIS
F FIELD DATA SHEETS
G SAMPLING EQUIPMENT CALIBRATIONS
H CHAIN OF CUSTODY
I TEST PARTICIPANTS1 

### 1.0 INTRODUCTION
On February 25, 2005, the Environmental Se rvices, Air Services Group of Tampa Electric Company, performed source emi ssion tests at the Big Bend Station, Boiler No. 3, emissions unit I.D.#0570039-003. Testing was conducted according to procedures stipulated by t he Florida Department of Environmental Protection (FDEP) for fossil fuel steam generators, and require ments in Title V
Permit # 0570039-021-AV.2 

### 2.0 DISCUSSION OF RESULTS
The particulate matter emission rate undersootblowing conditions was derived from three United States Environment al Protection Agency (USEPA) Reference Method 5-B test runs. The average of t he three test runs was 0.02 lb/mmBtu.
The FDEP allowable emission rate under soot blowing conditions is 0.03 lb/MMBtu, as listed in condition A.7.

The particulate matter emission rate under non-sootblowing conditions was derived from three USEPA Refe rence Method 5-B test runs. The average of the three test runs was 0.02 lb/MMBtu. The FDEP allowable emission rate under non-sootblowing conditions is 0.03 lb/ MMBtu, as listed in condition A.7.

The sulfur dioxide emission rate wa s determined using data provided by the Continuous Emissions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was determined to be 1037 lbs/hr. The FDEP allo wable emission rate is 3374 lbs/hr,
based on scenario 3 as listed in condition A.9.e.

Visible emissions were evaluated usi ng a Teledyne Instruments/Monitor Labs, LightHawk 560 transmissometer syst em (S/N 5600448/5600446), during both sootblowing and non-sootblowing testing. The 1-hour average opacity under sootblowing conditions was 3.5%. The 1-hour average opacity under nonsootblowing conditions was 3.5%. The FD EP allowable emission rate is 20%, as
listed in condition A.6.

During the tests performed on February 25, 2005, Boiler No. 3 was operated at an average heat input rate of 3845 mmBtu/hr and an average load of 377 megawatts. The average quantity of f uel burned was 160.4 tons per hour.3 

### 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The common stack 3 (CS003) source sampling location consists of a circular stack 28.83 feet in diameter with four sample ports located 90 degrees apart on t he stack circumference. Upstream and downstream gas flow disturbances were determined to be 8.51 and 2.99 stack diameters from the test ports, respectively. Using these criteria, a total of 24 sampling points were chosen for particu late sampling, as stipulated in USEPA Method 1 – “Sample and Velocity Traverse s for Stationary Sour ces”. A diagram of the stack sampling location is incl uded in Figure 1 along with other pertinent
information on the test site.

Boiler No. 3 is serviced by an electrostatic precipitator for the control of flyash emissions and a flue gas desulfurization (FGD) system for control of sulfur
dioxide emissions.

Particulate matter sampling was perfo rmed according to USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources". Particulate matter was collected on a high purity, borosilicate mi crofiber filter measuring 82mm in diameter. This dat a is included as Appendix A, and summarized on pages 6 (soot blowing c onditions), and 7 (non-soot blowing conditions) of this report.

Diluent gas sampling and analysis was performed according to USEPA Method 3 "Gas Analysis for Determination of Emi ssion Rate Correction Factor, or Excess Air”. Gas analysis was performed on-site using an Orsat analyzer.

Sulfur Dioxide (SO 2 ) and Carbon Dioxide (CO 2 ) data were provided by the Continuous Emissions Monitoring Syst em (CEMS), Data Acquisition and Handling System (DAHS). Averages were derived from the time frame of 09:12 through 15:18 EST, corresponding to the time frame of the particulate matter4 test. Data from 10:02 through 10:05 wa s not included in the averaging due to probe blowback (normal operations to ens ure that the sampling system remains clean). This data is included as Appendi x B, and summarized on page 8 of this report.

Visible emissions were assessed using t he installed Continuous Opacity Monitor (COM) system. This data is summariz ed on pages 9 (soot blowing conditions), and 10 (non-soot blowing conditions).5 

### 4.0 TEST RESULTS

### BI G BEND ST AT I O N PART I C ULAT E MATT ER D A T A SUMMARY

Run 1s Run 2s Run 3s V m(std ) , sc f 38.486 38.267 38.111

Bws , ratio 0.11940 0.11914 0.13428

O 2 , % volume 8 8 5

M

d , lb/lb - mole 30 .56 30.56 30.28

M

s , lb/lb - mole 29.06 29.06 28.63

Q s , ac f/min 1205845.8 1188859.2 1196891.6

Q s(std ) , dsc f /min 939879.4 925152.9 913440.6

I, % 99

. 2 100.2 101.1

C, lbs/dscf 9.80E-07 1 .13E -06 1 .03E -06

E m , lbs/hr 55.24 63.00 56.43

E r , lb/mmBtu 0.0155 0.0180 0.0132

Ma ss emissions (E m ), lbs/hr, ca lcula t ed a s : C x Q s ( st d ) x 60 m i nut e s

/

h our E m ission ra te (E r )

, lb / m m B tu , ca lcula t e d a s : C x 9780 d s cf/ m m B tu x ( 2 0.9/( 20.9-%O 2 )) 10 0.17

1.048 0E -06

58.223

0.01558 30 .467

28.918

1197 198.86

9261 57.66 T est Summa ry 38.288

0.124275

7.00 B o iler # 3 W E T-B O TTOM UTILITY B O ILE R Fe b r uar y 25, 2005

SOOT BLOWING

6

### BI G BEND ST AT I O N PART I C ULAT E MATT ER D A T A SUMMARY

R un 1 Run 2 Run 3 V m(std ) , sc f 37 .136 36.643 37.961

Bws , ratio 0.121 64 0.12159 0.13269

O 2 , % volume 8 8 8

M

d , lb/lb - mole 30 .56 30.56 30.56

M

s , lb/lb - mole 29.03 29.03 28.89

Q s , ac f/min 1158800.3 1142896.5 1181548.1

Q s(std ) , dsc f /min 901560.9 889030.0 909108.6

I, % 99

. 8 99.8 101.1

C, lbs/dscf 8.90E-07 1 .05E -06 9.93E -07

E m , lbs/hr 48.17 56.16 54.17

E r , lb/mmBtu 0.0141 0.0167 0.0157

Ma ss emissions (E m ), lbs/hr, ca lcula t ed a s : C x Q s ( st d ) x 60 m i nut e s

/

h our E m ission ra te (E r )

, lb / m m B tu , ca lcula t e d a s : C x 9780 d s cf/ m m B tu x ( 2 0.9/( 20.9-%O 2 )) 9.7881E -07

52 .833

0.01551 NON - SOOT BLOWING

28.986

1161 081.64

8998 99.87

10 0.23 37 .247

0.125309

8.00

30 .560 B o iler # 3 W E T-B O TTOM UTILITY B O ILE R Fe b r uar y 25, 2005

T est Summa ry

7

### BIG BEND ST ATI O N SU LFUR DIOXIDE DATA from CEMs

T est Period Information S t art Ti me 7 : 34 :0 0 E aste rn S t an dard Ti m e(ES T ) St o pT i m e 15: 58: 0 0 E a st e rn St a n d a rd T i me ( E ST ) T otal Time 8: 24 :0 0 Co rresp o n d i n gto th eti meframef o r th ePM test

.

Su lfur Diox i d e Da t a : RM - 19 SO 2 CO 2 SO 2 SO 2 ppmvw %

, we t l b/mmBtu l bs /h r 113. 66946 12. 61451 0. 270 1037. 45

Ca lcula tion Det a ils SO 2 , lb/mmBtu = SO 2 , ppmvw x C f x F c x( 100 / CO2 %, wet)
where: C

f = 1.6635E

- 0 7 (lb/sc f) /ppm SO 2 F c

= 18 00 scf/mm Btu SO 2 , lbs/hr = SO 2 , lb/m mBtu xHeat Input, mmBtu /h r where: Heat Input = 3845 mmB tu/hr, from Heat In put Calcu l ation Boiler #3 WET

- BOT T O MUT I L I T Y BOI L ER Fe b r u a r y 25, 2005

CEM DATA

8

### BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITOR

R e c o r d # D AT E T IME O PAC IT Y4 1 R e c o r d # D AT E T IME O PAC IT Y4 1 1 02/25/2005 73400 3.500 31 02/25/2005 80400 3.300 2 02/25/2005 73500 3.600 32 02/25/2005 80500 3.300 3 02/25/2005 73600 3.500 33 02/25/2005 80600 3.300 4 02/25/2005 73700 3.800 34 02/25/2005 80700 3.100 5 02/25/2005 73800 3.600 35 02/25/2005 80800 3.200 6 02/25/2005 73900 3.800 36 02/25/2005 80900 3.200 7 02/25/2005 74000 3.200 37 02/25/2005 81000 3.300 8 02/25/2005 74100 2.900 38 02/25/2005 81100 3.800 9 02/25/2005 74200 3.200 39 02/25/2005 81200 3.800 10 02/25/2005 74300 3.300 40 02/25/2005 81300 3.600 11 02/25/2005 74400 3.300 41 02/25/2005 81400 3.400 12 02/25/2005 74500 3.600 42 02/25/2005 81500 3.500 13 02/25/2005 74600 3.400 43 02/25/2005 81600 3.800 14 02/25/2005 74700 3.300 44 02/25/2005 81700 3.700 15 02/25/2005 74800 3.000 45 02/25/2005 81800 3.500 16 02/25/2005 74900 3.000 46 02/25/2005 81900 3.600 17 02/25/2005 75000 3.200 47 02/25/2005 82000 3.500 18 02/25/2005 75100 3.800 48 02/25/2005 82100 3.500 19 02/25/2005 75200 3.700 49 02/25/2005 82200 3.600 20 02/25/2005 75300 3.500 50 02/25/2005 82300 3.900 21 02/25/2005 75400 3.400 51 02/25/2005 82400 3.500 22 02/25/2005 75500 3.500 52 02/25/2005 82500 3.400 23 02/25/2005 75600 3.400 53 02/25/2005 82600 3.700 24 02/25/2005 75700 3.700 54 02/25/2005 82700 3.500 25 02/25/2005 75800 3.800 55 02/25/2005 82800 3.800 26 02/25/2005 75900 3.400 56 02/25/2005 82900 3.600 27 02/25/2005 80000 3.600 57 02/25/2005 83000 3.000 28 02/25/2005 80100 3.300 58 02/25/2005 83100 3.300 29 02/25/2005 80200 3.300 59 02/25/2005 83200 3.200 30 02/25/2005 80300 3.300 60 02/25/2005 83300 3.200

T e s tAver age: 3.450 % Minim u m O ne Minu te Aver age: 2.900 % Max i m u m O ne Minu te Aver age: 3.900 %

Max i m u m SixMinu te Aver age: 3.650 % B o iler #3 W E T B O TTOM UTILITY B O ILE R

SOOTB L OWING CONDITIONS

9

### BIG BEND STATION VISIBLE EMISSIONS DATA FROM OPACITY MONITO R

R e c o r d # D AT E T IME O PAC IT Y4 1 R e c o r d # D AT E T IME O PAC IT Y4 1 1 02/25/2005 90300 3.500 31 02/25/2005 93300 3.200 2 02/25/2005 90400 3.600 32 02/25/2005 93400 3.300 3 02/25/2005 90500 3.700 33 02/25/2005 93500 3.200 4 02/25/2005 90600 4.000 34 02/25/2005 93600 3.400 5 02/25/2005 90700 3.700 35 02/25/2005 93700 3.400 6 02/25/2005 90800 3.500 36 02/25/2005 93800 3.400 7 02/25/2005 90900 3.700 37 02/25/2005 93900 3.500 8 02/25/2005 91000 3.400 38 02/25/2005 94000 3.600 9 02/25/2005 91100 3.700 39 02/25/2005 94100 3.200 10 02/25/2005 91200 3.600 40 02/25/2005 94200 3.400 11 02/25/2005 91300 3.500 41 02/25/2005 94300 3.100 12 02/25/2005 91400 3.500 42 02/25/2005 94400 3.400 13 02/25/2005 91500 3.600 43 02/25/2005 94500 3.300 14 02/25/2005 91600 3.500 44 02/25/2005 94600 3.200 15 02/25/2005 91700 3.400 45 02/25/2005 94700 3.300 16 02/25/2005 91800 3.500 46 02/25/2005 94800 3.300 17 02/25/2005 91900 3.600 47 02/25/2005 94900 3.400 18 02/25/2005 92000 3.600 48 02/25/2005 95000 3.500 19 02/25/2005 92100 3.300 49 02/25/2005 95100 3.600 20 02/25/2005 92200 3.500 50 02/25/2005 95200 3.600 21 02/25/2005 92300 3.300 51 02/25/2005 95300 3.600 22 02/25/2005 92400 3.500 52 02/25/2005 95400 3.600 23 02/25/2005 92500 3.500 53 02/25/2005 95500 3.500 24 02/25/2005 92600 3.500 54 02/25/2005 95600 3.600 25 02/25/2005 92700 3.300 55 02/25/2005 95700 3.400 26 02/25/2005 92800 3.100 56 02/25/2005 95800 3.100 27 02/25/2005 92900 3.300 57 02/25/2005 95900 3.500 28 02/25/2005 93000 3.400 58 02/25/2005 100000 3.600 29 02/25/2005 93100 3.600 59 02/25/2005 100100 3.500 30 02/25/2005 93200 3.200 60 02/25/2005 100200 3.700

T e s tAver age: 3.458 % Minim u m O ne Minu te Aver age: 3.100 % Max i m u m O ne Minu te Aver age: 4.000 %

Max i m u m SixMinu te Aver age: 3.700 % B o iler #3 W E T B O TTOM UTILITY B O ILE R NON-SOO T B L OW ING C O N D ITIONS

10

### BI G BEND GENERATI NG STATI O N HEAT INPUT CALCULATIONS

Gross Hea t Ra t e , Pr evio us Mo nth ( J a nua ry) : 10193 KM Btu/ MWh 1. 0193E +07 M MBtu / M

Wh



### Me g aWatt Ho ur Inte g rato r Info rmatio n Initia l Int e g rator Readin g : 304844 M Wh Final Inte g rator Readin g : 308005 M Wh T o t a l : 3161 M Wh



### T est T i m eIn f o rm a tion T esti n gSt a rt T i me: 7 : 3 5 T esti n gE n d T i me: 15: 58

T otal Te st Ti me : 8.3 8 h ou rs



### Cal cul ate d He at I n p u t Avera g e Unit Loa d

, MW = MWh / ho urs: 377. 2 M W Hea t I n p u t
, MMBtu/ h = MMBtu/ MWh x MW: 3844. 8 m mBtu / h r



### Fue l Co nsumptio n Calculatio n

Laboratory Sample ID: A A 76139 Btu a s rec e ived : 11986 Btu/ lb T o n s of F u el Co nsum ed

, T o ns/ h r = ( mmBtu / h / Btu/ lb) x 500: 160. 4 T o n s/ho ur 

### Coa l F i re d Bo il er Num b er 3 Fe b r u ar y 25, 2005

1112 

### 5.0 FIGURESFI GURE 1 EX HA US T ST AC K 245 F T

. BIG BE N D S T AT IO N CS 0 0 3

PA RT I C ULAT E T R AVERSE POI N T S

OU T L ET 

## N A

B C D

PORT L O CATI ON

R E V I SE D 1 2

- 31- 96 BO I L ER N O

. 3 T EST LOCAT I ON

S T AC K D I AME T ER S D O W N ST R E A M F R O M D I ST UR BA NC E = 3. 0

S T AC K D I AME T ER S U PST RE AM F R O M D I ST UR BA NC E = 8. 5

ST A C KDI A M ET E R = 28. 8333 F T

. ST A C KAR EA= 652. 948 SQ.

PORT LEN G T H ’ S = 14 I N

. T R AV ER SE PO IN T

1

2

3

4

5

6 % O F S T AC K D I AM E T ER I N . F R O M S T AC K W A L L

2.1%

6.7%

11

. 8 %

17

. 7 %

25

. 0 %

35

. 6 % 7

. 2 7 IN

.

2 3 .1 8 IN

.

4 0 .8 3 IN

.
6 1 .2 4 IN

.
8 6 .5 0 IN

.
123. 18 I N

. 499 F T

.

254 F T

.

168 F T

. 86 F T

.

FGD

PR ES SU RIZ E D AN N U L U S

13

### APPENDIX A PARTICULTE TEST CALCULATIONSEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 1s Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, Ps : 29.72 "Hg Average Orifice Meter, ∆ H: 1.397 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.897 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 86.7 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 132.5 o F 8.0 % O 2 Average √∆ p: 0.517 "H 2 O 0.0 % CO Condensate Volume, Vlc : 110.7 ml 78.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std ) = 4.714E-02 x V lc 5.218 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 38.486 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.119 % FDA = 1.0 - B w s 0.881 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.56 lb./lb. mole M s= (M d x FDA) + (18.0 x B w s ) 29.06 lb./lb. mole

v s= 85.49 x C p x ( √∆ p) x ( √ (T s+ 460) / (M sx P s )) 30.78 ft/second Q s= v sx A sx 60 1205845.8 acf/minute Q s ( std )= Q sx FDA x (528 / (T s+ 460)) x (P s / 29.92)) 939879.4 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.2 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.017100 grams

Calculated Concentration and Emission Rate Data:

c s= (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c sx 17.647 x P sx (FDA / (T s+ 460) 0.005 grains/acf C = c s/ 7000 9.795E-07 lbs/dscf E M = C x Q s(std)x 60 55.2 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01552 lbs/MMBtuEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 2s Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.69 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, Ps : 29.65 "Hg Average Orifice Meter, ∆ H: 1.355 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.690 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 85.8 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 132.3 o F 8.0 % O 2 Average √∆ p: 0.510 "H 2 O 0.0 % CO Condensate Volume, Vlc : 109.8 ml 78.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std ) = 4.714E-02 x V lc 5.176 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 38.267 dscf B w s = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.119 % FDA = 1.0 - B w s 0.881 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.56 lb./lb. mole M s= (M d x FDA) + (18.0 x B w s ) 29.06 lb./lb. mole

v s= 85.49 x C p x ( √∆ p) x ( √ (T s+ 460) / (M sx P s )) 30.35 ft/second Q s= v sx A sx 60 1188859.2 acf/minute Q s ( std )= Q sx FDA x (528 / (T s+ 460)) x (P s / 29.92)) 925152.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.2 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.019700 grams

Calculated Concentration and Emission Rate Data:

c s= (15.432 x grams) / V m(std) 0.008 grains/dscf grains/acf = c sx 17.647 x P sx (FDA / (T s+ 460) 0.006 grains/acf C = c s/ 7000 1.135E-06 lbs/dscf E M = C x Q s(std)x 60 63.0 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01798 lbs/MMBtuEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Soot Blowing Run Number: 3s Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.64 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.61 "Hg Average Orifice Meter, ∆ H: 1.349 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.650 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 86.0 o F Gas Analysis: 13.0 % CO 2 Average Stack Temp., T s : 132.8 o F 5.0 % O 2 Average √∆ p: 0.509 "H 2 O 0.0 % CO Condensate Volume, V l c : 125.4 ml 82.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std )= 4.714E-02 x V l c 5.911 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 38.111 dscf B ws= V w ( std )/ (V m ( std ) + V w ( std ) ) 0.134 % FDA = 1.0 - B ws 0.866 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.28 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.63 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 30.55 ft/second Q s = v s x A s x 60 1196891.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 913440.6 dscf/minute I = (T s+ 460) x ((2.67E-03 x V lc ) + (V m(std)/ 17.647)) x 100 / ( θ x P sx A n x vsx 60) 101.1 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.017800 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.030E-06 lbs/dscf E M = C x Q s(std) x 60 56.4 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01324 lbs/MMBtuEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.72 "Hg Average Orifice Meter, ∆ H: 1.297 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.700 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 89.4 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 132.1 o F 8.0 % O 2 Average √∆ p: 0.497 "H 2 O 0.0 % CO Condensate Volume, V l c : 109.1 ml 78.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std )= 4.714E-02 x V l c 5.143 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 37.136 dscf B ws= V w ( std )/ (V m ( std ) + V w ( std ) ) 0.122 % FDA = 1.0 - B ws 0.878 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.56 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 29.03 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 29.58 ft/second Q s = v s x A s x 60 1158800.3 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 901560.9 dscf/minute I = (T s+ 460) x ((2.67E-03 x V lc ) + (V m(std)/ 17.647)) x 100 / ( θ x P sx A n x vsx 60) 99.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.015000 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.006 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.005 grains/acf C = c s / 7000 8.905E-07 lbs/dscf E M = C x Q s(std) x 60 48.2 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01411 lbs/MMBtuEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.72 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.69 "Hg Average Orifice Meter, ∆ H: 1.266 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 38.271 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 90.0 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 131.7 o F 8.0 % O 2 Average √∆ p: 0.490 "H 2 O 0.0 % CO Condensate Volume, V l c : 107.6 ml 78.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std )= 4.714E-02 x V l c 5.072 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 36.643 dscf B ws= V w ( std )/ (V m ( std ) + V w ( std ) ) 0.122 % FDA = 1.0 - B ws 0.878 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.56 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 29.03 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 29.17 ft/second Q s = v s x A s x 60 1142896.5 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 889030.0 dscf/minute I = (T s+ 460) x ((2.67E-03 x V lc ) + (V m(std)/ 17.647)) x 100 / ( θ x P sx A n x vsx 60) 99.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.017500 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.007 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.053E-06 lbs/dscf E M = C x Q s(std) x 60 56.2 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01668 lbs/MMBtuEnvironmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS003 - Common Stack 3 Unit Under Test: Boiler # 3 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: 02/25/05

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.287 inches Barometric Pressure, P b : 29.75 "Hg Nozzle Area, A n : 0.000449 ft 2 Stack Pressure, P s : 29.72 "Hg Average Orifice Meter, ∆ H: 1.334 "H 2 O Effective Stack Area, A s : 652.948 ft 2 Sample Volume, V m : 39.236 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 85.0 o F Gas Analysis: 14.0 % CO 2 Average Stack Temp., T s : 131.2 o F 8.0 % O 2 Average √∆ p: 0.506 "H 2 O 0.0 % CO Condensate Volume, V l c : 123.2 ml 78.0 % N 2 Meter Box Y: 1.001 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: Vw ( std )= 4.714E-02 x V l c 5.808 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 37.961 dscf B ws= V w ( std )/ (V m ( std ) + V w ( std ) ) 0.133 % FDA = 1.0 - B ws 0.867 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.56 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.89 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 30.16 ft/second Q s = v s x A s x 60 1181548.1 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 909108.6 dscf/minute I = (T s+ 460) x ((2.67E-03 x V lc ) + (V m(std)/ 17.647)) x 100 / ( θ x P sx A n x vsx 60) 101.1 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.017100 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0070 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0053 grains/acf C = c s / 7000 9.931E-07 lbs/dscf E M = C x Q s(std) x 60 54.2 lbs/hr E R= C x F d x (20.9 /(20.9 - %O 2 ) 0.01574 lbs/MMBtu

### APPENDIX B DAILY SULFUR DIOXIDE DATA SUMMARYSO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Averages- 12.6145 113.6695 Record# DATE TIME CO2_S32 SO2_S34 1 02/25/2005 7:34 12.69 116.1 2 02/25/2005 73500 12.69 112 3 02/25/2005 73600 12.59 100.4 4 02/25/2005 73700 12.64 90.8 5 02/25/2005 73800 12.67 93.3 6 02/25/2005 73900 12.69 97.4 7 02/25/2005 74000 12.64 102.5 8 02/25/2005 74100 12.59 107.4 9 02/25/2005 74200 12.69 108.4 10 02/25/2005 74300 12.74 109 11 02/25/2005 74400 12.72 115.9 12 02/25/2005 74500 12.69 113.8 13 02/25/2005 74600 12.72 108.8 14 02/25/2005 74700 12.7 104.7 15 02/25/2005 74800 12.73 108.8 16 02/25/2005 74900 12.7 114.6 17 02/25/2005 75000 12.67 112.6 18 02/25/2005 75100 12.62 112.2 19 02/25/2005 75200 12.65 119.3 20 02/25/2005 75300 12.59 121.6 21 02/25/2005 75400 12.63 123 22 02/25/2005 75500 12.7 127.6 23 02/25/2005 75600 12.66 126.7 24 02/25/2005 75700 12.66 115.2 25 02/25/2005 75800 12.68 109.5 26 02/25/2005 75900 12.67 103.1 27 02/25/2005 80000 12.66 101.2 28 02/25/2005 80100 12.63 106.6 29 02/25/2005 80200 12.63 108.9 30 02/25/2005 80300 12.62 110 31 02/25/2005 80400 12.63 105.8 32 02/25/2005 80500 12.67 108.9 33 02/25/2005 80600 12.62 111.5 34 02/25/2005 80700 12.55 114.3 35 02/25/2005 80800 12.61 111.2 36 02/25/2005 80900 12.64 109.3 37 02/25/2005 81000 12.59 113.8 38 02/25/2005 81100 12.66 119.2

1 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 39 02/25/2005 81200 12.61 120.9 40 02/25/2005 81300 12.56 118.9 41 02/25/2005 81400 12.69 120.5 42 02/25/2005 81500 12.67 121 43 02/25/2005 81600 12.65 118.6 44 02/25/2005 81700 12.64 111.7 45 02/25/2005 81800 12.6 102.8 46 02/25/2005 81900 12.55 99 47 02/25/2005 82000 12.59 100.5 48 02/25/2005 82100 12.61 105.7 49 02/25/2005 82200 12.65 105.4 50 02/25/2005 82300 12.62 100.7 51 02/25/2005 82400 12.62 101.9 52 02/25/2005 82500 12.56 106.2 53 02/25/2005 82600 12.59 112.9 54 02/25/2005 82700 12.57 110.3 55 02/25/2005 82800 12.55 111.3 56 02/25/2005 82900 12.64 121 57 02/25/2005 83000 12.61 121.9 58 02/25/2005 83100 12.59 111.4 59 02/25/2005 83200 12.62 106.4 60 02/25/2005 83300 12.65 112.9 61 02/25/2005 83400 12.66 115.8 62 02/25/2005 83500 12.67 112 63 02/25/2005 83600 12.63 111.8 64 02/25/2005 83700 12.65 117.1 65 02/25/2005 83800 12.63 122.3 66 02/25/2005 83900 12.62 120.7 67 02/25/2005 84000 12.62 119.3 68 02/25/2005 84100 12.55 121.6 69 02/25/2005 84200 12.53 125.2 70 02/25/2005 84300 12.57 121.5 71 02/25/2005 84400 12.56 108.1 72 02/25/2005 84500 12.62 103.9 73 02/25/2005 84600 12.58 103.8 74 02/25/2005 84700 12.59 100.6 75 02/25/2005 84800 12.58 98.4 76 02/25/2005 84900 12.64 98.4 77 02/25/2005 85000 12.61 98.7

2 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 78 02/25/2005 85100 12.55 91.4 79 02/25/2005 85200 12.61 92.1 80 02/25/2005 85300 12.64 97.4 81 02/25/2005 85400 12.59 99.4 82 02/25/2005 85500 12.65 102 83 02/25/2005 85600 12.62 99.2 84 02/25/2005 85700 12.61 103.1 85 02/25/2005 85800 12.67 108.1 86 02/25/2005 85900 12.72 115.8 87 02/25/2005 90000 12.69 106.5 88 02/25/2005 90100 12.74 92.8 89 02/25/2005 90200 12.75 86.5 90 02/25/2005 90300 12.72 91.6 91 02/25/2005 90400 12.69 96.9 92 02/25/2005 90500 12.71 99.6 93 02/25/2005 90600 12.69 97.8 94 02/25/2005 90700 12.61 97.3 95 02/25/2005 90800 12.66 102.7 96 02/25/2005 90900 12.71 104.5 97 02/25/2005 91000 12.69 108.1 98 02/25/2005 91100 12.62 111.1 99 02/25/2005 91200 12.7 105.2 100 02/25/2005 91300 12.67 101.3 101 02/25/2005 91400 12.67 109.1 102 02/25/2005 91500 12.69 114.1 103 02/25/2005 91600 12.68 132.7 104 02/25/2005 91700 12.64 165.5 105 02/25/2005 91800 12.68 170.4 106 02/25/2005 91900 12.67 168.7 107 02/25/2005 92000 12.68 165.6 108 02/25/2005 92100 12.71 157.2 109 02/25/2005 92200 12.73 136.3 110 02/25/2005 92300 12.72 138.5 111 02/25/2005 92400 12.74 172.2 112 02/25/2005 92500 12.65 201.9 113 02/25/2005 92600 12.6 209 114 02/25/2005 92700 12.64 204.9 115 02/25/2005 92800 12.65 205.5 116 02/25/2005 92900 12.8 212.2

3 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 117 02/25/2005 93000 12.9 215 118 02/25/2005 93100 12.79 200.2 119 02/25/2005 93200 12.83 189.3 120 02/25/2005 93300 12.89 181.6 121 02/25/2005 93400 12.86 168 122 02/25/2005 93500 12.81 167 123 02/25/2005 93600 12.83 163.4 124 02/25/2005 93700 12.85 160.6 125 02/25/2005 93800 12.89 167.4 126 02/25/2005 93900 12.91 167.2 127 02/25/2005 94000 12.9 154 128 02/25/2005 94100 12.85 138.2 129 02/25/2005 94200 12.82 133.3 130 02/25/2005 94300 12.86 134.3 131 02/25/2005 94400 12.87 127.8 132 02/25/2005 94500 12.88 126.3 133 02/25/2005 94600 12.86 127.1 134 02/25/2005 94700 12.81 132.3 135 02/25/2005 94800 12.79 130.1 136 02/25/2005 94900 12.74 125.8 137 02/25/2005 95000 12.76 129.6 138 02/25/2005 95100 12.82 136 139 02/25/2005 95200 12.8 129.9 140 02/25/2005 95300 12.79 124.1 141 02/25/2005 95400 12.85 132.1 142 02/25/2005 95500 12.88 140.4 143 02/25/2005 95600 12.82 137.9 144 02/25/2005 95700 12.8 125.4 145 02/25/2005 95800 12.82 122.4 146 02/25/2005 95900 12.82 125.2 147 02/25/2005 100000 12.86 119.9 148 02/25/2005 100100 12.85 111 153 02/25/2005 100600 12.44 116.9 154 02/25/2005 100700 12.62 111.2 155 02/25/2005 100800 12.74 111.9 10:02 through 10:05 removed from averaging period due to probe blowback.

4 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 156 02/25/2005 100900 12.73 112.6 157 02/25/2005 101000 12.73 113 158 02/25/2005 101100 12.74 116.7 159 02/25/2005 101200 12.67 117.9 160 02/25/2005 101300 12.7 112.6 161 02/25/2005 101400 12.8 115.7 162 02/25/2005 101500 12.73 115.8 163 02/25/2005 101600 12.74 120 164 02/25/2005 101700 12.79 117.3 165 02/25/2005 101800 12.73 116.2 166 02/25/2005 101900 12.79 125.2 167 02/25/2005 102000 12.83 123.2 168 02/25/2005 102100 12.72 123.5 169 02/25/2005 102200 12.72 128.2 170 02/25/2005 102300 12.78 118.7 171 02/25/2005 102400 12.84 116.7 172 02/25/2005 102500 12.84 111.5 173 02/25/2005 102600 12.82 105.2 174 02/25/2005 102700 12.8 103.1 175 02/25/2005 102800 12.81 106.7 176 02/25/2005 102900 12.78 111.4 177 02/25/2005 103000 12.89 113 178 02/25/2005 103100 12.8 106.9 179 02/25/2005 103200 12.81 108.1 180 02/25/2005 103300 12.82 112 181 02/25/2005 103400 12.8 114.2 182 02/25/2005 103500 12.73 113.7 183 02/25/2005 103600 12.73 114.7 184 02/25/2005 103700 12.74 120.2 185 02/25/2005 103800 12.7 117.7 186 02/25/2005 103900 12.74 118.2 187 02/25/2005 104000 12.75 117.3 188 02/25/2005 104100 12.77 111.4 189 02/25/2005 104200 12.75 109.2 190 02/25/2005 104300 12.79 113.1 191 02/25/2005 104400 12.74 112.8 192 02/25/2005 104500 12.75 118.2 193 02/25/2005 104600 12.77 115.4 194 02/25/2005 104700 12.75 114.3

5 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 195 02/25/2005 104800 12.72 116.6 196 02/25/2005 104900 12.76 122.3 197 02/25/2005 105000 12.79 125 198 02/25/2005 105100 12.79 116.2 199 02/25/2005 105200 12.79 106 200 02/25/2005 105300 12.78 98.6 201 02/25/2005 105400 12.8 97.4 202 02/25/2005 105500 12.73 96.5 203 02/25/2005 105600 12.77 96.4 204 02/25/2005 105700 12.77 95.8 205 02/25/2005 105800 12.73 96.2 206 02/25/2005 105900 12.72 97.1 207 02/25/2005 110000 12.74 96 208 02/25/2005 110100 12.74 95.3 209 02/25/2005 110200 12.78 98.5 210 02/25/2005 110300 12.8 105 211 02/25/2005 110400 12.8 104 212 02/25/2005 110500 12.77 101.7 213 02/25/2005 110600 12.81 105.1 214 02/25/2005 110700 12.82 112.8 215 02/25/2005 110800 12.88 114.5 216 02/25/2005 110900 12.84 109 217 02/25/2005 111000 12.74 108.1 218 02/25/2005 111100 12.7 112.4 219 02/25/2005 111200 12.7 113.8 220 02/25/2005 111300 12.71 112.2 221 02/25/2005 111400 12.82 111 222 02/25/2005 111500 12.74 102.2 223 02/25/2005 111600 12.7 95 224 02/25/2005 111700 12.74 93.2 225 02/25/2005 111800 12.75 96.8 226 02/25/2005 111900 12.7 96.6 227 02/25/2005 112000 12.7 97.9 228 02/25/2005 112100 12.7 100.6 229 02/25/2005 112200 12.74 103.1 230 02/25/2005 112300 12.73 110.6 231 02/25/2005 112400 12.73 110.9 232 02/25/2005 112500 12.67 105.8 233 02/25/2005 112600 12.74 102.6

6 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 234 02/25/2005 112700 12.76 102.4 235 02/25/2005 112800 12.69 107.5 236 02/25/2005 112900 12.75 104.3 237 02/25/2005 113000 12.64 101.8 238 02/25/2005 113100 12.6 103 239 02/25/2005 113200 12.62 107.6 240 02/25/2005 113300 12.7 103.8 241 02/25/2005 113400 12.74 102.5 242 02/25/2005 113500 12.65 105.7 243 02/25/2005 113600 12.7 112.3 244 02/25/2005 113700 12.7 116.6 245 02/25/2005 113800 12.74 117 246 02/25/2005 113900 12.74 112.9 247 02/25/2005 114000 12.77 106.4 248 02/25/2005 114100 12.65 99.6 249 02/25/2005 114200 12.65 93.4 250 02/25/2005 114300 12.75 96.2 251 02/25/2005 114400 12.73 97.3 252 02/25/2005 114500 12.62 100.2 253 02/25/2005 114600 12.66 99.5 254 02/25/2005 114700 12.61 96.8 255 02/25/2005 114800 12.69 100.8 256 02/25/2005 114900 12.63 107.5 257 02/25/2005 115000 12.6 108.6 258 02/25/2005 115100 12.56 106.5 259 02/25/2005 115200 12.59 107.8 260 02/25/2005 115300 12.6 110.6 261 02/25/2005 115400 12.65 116.3 262 02/25/2005 115500 12.65 108.5 263 02/25/2005 115600 12.62 108.6 264 02/25/2005 115700 12.57 109.1 265 02/25/2005 115800 12.61 110.2 266 02/25/2005 115900 12.64 115.6 267 02/25/2005 120000 12.66 109.2 268 02/25/2005 120100 12.63 101.3 269 02/25/2005 120200 12.67 101.1 270 02/25/2005 120300 12.69 101.8 271 02/25/2005 120400 12.67 97.5 272 02/25/2005 120500 12.67 101.6

7 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 273 02/25/2005 120600 12.61 106.2 274 02/25/2005 120700 12.58 107.7 275 02/25/2005 120800 12.57 103.6 276 02/25/2005 120900 12.6 107.3 277 02/25/2005 121000 12.65 111.3 278 02/25/2005 121100 12.66 110.5 279 02/25/2005 121200 12.67 104.6 280 02/25/2005 121300 12.6 102.8 281 02/25/2005 121400 12.6 101.9 282 02/25/2005 121500 12.59 107.1 283 02/25/2005 121600 12.6 113 284 02/25/2005 121700 12.64 114.4 285 02/25/2005 121800 12.58 110.9 286 02/25/2005 121900 12.53 112.1 287 02/25/2005 122000 12.58 117.9 288 02/25/2005 122100 12.63 115 289 02/25/2005 122200 12.65 103.7 290 02/25/2005 122300 12.61 96.6 291 02/25/2005 122400 12.61 96.6 292 02/25/2005 122500 12.67 99.4 293 02/25/2005 122600 12.61 99.3 294 02/25/2005 122700 12.7 99.9 295 02/25/2005 122800 12.66 99.8 296 02/25/2005 122900 12.67 96.7 297 02/25/2005 123000 12.7 98.1 298 02/25/2005 123100 12.66 100.2 299 02/25/2005 123200 12.61 105.7 300 02/25/2005 123300 12.62 104.1 301 02/25/2005 123400 12.57 103.5 302 02/25/2005 123500 12.59 105 303 02/25/2005 123600 12.6 108 304 02/25/2005 123700 12.62 110.5 305 02/25/2005 123800 12.63 108.6 306 02/25/2005 123900 12.63 107.9 307 02/25/2005 124000 12.66 116.3 308 02/25/2005 124100 12.65 121.2 309 02/25/2005 124200 12.63 116.1 310 02/25/2005 124300 12.62 114.7 311 02/25/2005 124400 12.63 113.8

8 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 312 02/25/2005 124500 12.61 112.4 313 02/25/2005 124600 12.54 116.5 314 02/25/2005 124700 12.6 121 315 02/25/2005 124800 12.67 117.8 316 02/25/2005 124900 12.53 113 317 02/25/2005 125000 12.52 116.2 318 02/25/2005 125100 12.55 115.5 319 02/25/2005 125200 12.65 115.4 320 02/25/2005 125300 12.67 110.6 321 02/25/2005 125400 12.62 102.2 322 02/25/2005 125500 12.56 100.6 323 02/25/2005 125600 12.58 102.7 324 02/25/2005 125700 12.59 109.7 325 02/25/2005 125800 12.61 109.5 326 02/25/2005 125900 12.59 101.4 327 02/25/2005 130000 12.58 98.8 328 02/25/2005 130100 12.56 102.4 329 02/25/2005 130200 12.6 108 330 02/25/2005 130300 12.59 105.6 331 02/25/2005 130400 12.64 100.8 332 02/25/2005 130500 12.66 102.6 333 02/25/2005 130600 12.66 109.4 334 02/25/2005 130700 12.62 111.5 335 02/25/2005 130800 12.62 110 336 02/25/2005 130900 12.63 109.8 337 02/25/2005 131000 12.66 114.5 338 02/25/2005 131100 12.63 118 339 02/25/2005 131200 12.6 116.4 340 02/25/2005 131300 12.56 123 341 02/25/2005 131400 12.6 123.7 342 02/25/2005 131500 12.61 120.5 343 02/25/2005 131600 12.59 121.1 344 02/25/2005 131700 12.6 125.2 345 02/25/2005 131800 12.59 118.5 346 02/25/2005 131900 12.58 105 347 02/25/2005 132000 12.59 100.8 348 02/25/2005 132100 12.64 101.6 349 02/25/2005 132200 12.61 102.3 350 02/25/2005 132300 12.59 103.1

9 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 351 02/25/2005 132400 12.63 104.7 352 02/25/2005 132500 12.59 108 353 02/25/2005 132600 12.55 105.3 354 02/25/2005 132700 12.58 106.7 355 02/25/2005 132800 12.61 109.7 356 02/25/2005 132900 12.58 114.9 357 02/25/2005 133000 12.59 118.1 358 02/25/2005 133100 12.61 115 359 02/25/2005 133200 12.61 116.1 360 02/25/2005 133300 12.6 113.5 361 02/25/2005 133400 12.61 108.9 362 02/25/2005 133500 12.6 106.5 363 02/25/2005 133600 12.59 110 364 02/25/2005 133700 12.57 111.8 365 02/25/2005 133800 12.55 111.6 366 02/25/2005 133900 12.56 120.6 367 02/25/2005 134000 12.66 122.1 368 02/25/2005 134100 12.64 117.4 369 02/25/2005 134200 12.5 115.4 370 02/25/2005 134300 12.51 116.7 371 02/25/2005 134400 12.54 108.9 372 02/25/2005 134500 12.62 104.8 373 02/25/2005 134600 12.57 102.3 374 02/25/2005 134700 12.54 107.7 375 02/25/2005 134800 12.5 107.5 376 02/25/2005 134900 12.55 111.7 377 02/25/2005 135000 12.65 111.6 378 02/25/2005 135100 12.59 109.4 379 02/25/2005 135200 12.63 109.8 380 02/25/2005 135300 12.64 109.3 381 02/25/2005 135400 12.56 106.4 382 02/25/2005 135500 12.55 112.6 383 02/25/2005 135600 12.55 114.8 384 02/25/2005 135700 12.49 111.6 385 02/25/2005 135800 12.52 114.3 386 02/25/2005 135900 12.6 117.5 387 02/25/2005 140000 12.47 124.2 388 02/25/2005 140100 12.4 122.6 389 02/25/2005 140200 12.44 118.2

10 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 390 02/25/2005 140300 12.4 121.5 391 02/25/2005 140400 12.41 128.4 392 02/25/2005 140500 12.45 122.9 393 02/25/2005 140600 12.39 114.4 394 02/25/2005 140700 12.43 120.8 395 02/25/2005 140800 12.5 123.1 396 02/25/2005 140900 12.5 125 397 02/25/2005 141000 12.4 120.8 398 02/25/2005 141100 12.46 120.5 399 02/25/2005 141200 12.48 121.8 400 02/25/2005 141300 12.52 120 401 02/25/2005 141400 12.54 118.3 402 02/25/2005 141500 12.57 120.9 403 02/25/2005 141600 12.46 116.7 404 02/25/2005 141700 12.44 112.2 405 02/25/2005 141800 12.55 106.4 406 02/25/2005 141900 12.53 103.3 407 02/25/2005 142000 12.52 105.7 408 02/25/2005 142100 12.42 110.3 409 02/25/2005 142200 12.36 107.3 410 02/25/2005 142300 12.49 108 411 02/25/2005 142400 12.48 114.4 412 02/25/2005 142500 12.48 116.6 413 02/25/2005 142600 12.43 111.4 414 02/25/2005 142700 12.48 105.3 415 02/25/2005 142800 12.52 105.7 416 02/25/2005 142900 12.47 109.4 417 02/25/2005 143000 12.45 108.9 418 02/25/2005 143100 12.46 102 419 02/25/2005 143200 12.43 105.9 420 02/25/2005 143300 12.35 106.5 421 02/25/2005 143400 12.33 107.1 422 02/25/2005 143500 12.43 106.5 423 02/25/2005 143600 12.43 109.5 424 02/25/2005 143700 12.44 113.7 425 02/25/2005 143800 12.48 119.9 426 02/25/2005 143900 12.52 119.9 427 02/25/2005 144000 12.49 117.3 428 02/25/2005 144100 12.46 122.6

11 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 429 02/25/2005 144200 12.43 118.9 430 02/25/2005 144300 12.48 104.6 431 02/25/2005 144400 12.45 96.5 432 02/25/2005 144500 12.47 93.7 433 02/25/2005 144600 12.48 98.4 434 02/25/2005 144700 12.47 100.3 435 02/25/2005 144800 12.48 103.5 436 02/25/2005 144900 12.44 100.3 437 02/25/2005 145000 12.49 102.7 438 02/25/2005 145100 12.48 106.1 439 02/25/2005 145200 12.45 107.7 440 02/25/2005 145300 12.48 104.3 441 02/25/2005 145400 12.4 105.7 442 02/25/2005 145500 12.39 106.6 443 02/25/2005 145600 12.43 108 444 02/25/2005 145700 12.38 109.8 445 02/25/2005 145800 12.44 115.8 446 02/25/2005 145900 12.44 121.4 447 02/25/2005 150000 12.49 117.8 448 02/25/2005 150100 12.44 115 449 02/25/2005 150200 12.34 112.4 450 02/25/2005 150300 12.39 110.7 451 02/25/2005 150400 12.4 110.1 452 02/25/2005 150500 12.34 114.9 453 02/25/2005 150600 12.37 115.6 454 02/25/2005 150700 12.38 111.4 455 02/25/2005 150800 12.33 109.5 456 02/25/2005 150900 12.36 116.2 457 02/25/2005 151000 12.37 120.7 458 02/25/2005 151100 12.44 121.7 459 02/25/2005 151200 12.43 123.4 460 02/25/2005 151300 12.42 123.5 461 02/25/2005 151400 12.36 120.8 462 02/25/2005 151500 12.31 119.6 463 02/25/2005 151600 12.37 122 464 02/25/2005 151700 12.41 127.4 465 02/25/2005 151800 12.42 127.2 466 02/25/2005 151900 12.37 112 467 02/25/2005 152000 12.36 99.8

12 of 13SO2 Data Big Bend 3

Big Bend 3 SO2 Compliance Record# DATE TIME CO2_S32 SO2_S34 468 02/25/2005 152100 12.48 98.6 469 02/25/2005 152200 12.46 101.5 470 02/25/2005 152300 12.47 105.8 471 02/25/2005 152400 12.41 109.6 472 02/25/2005 152500 12.39 108.7 473 02/25/2005 152600 12.37 105.5 474 02/25/2005 152700 12.4 105.8 475 02/25/2005 152800 12.43 109.8 476 02/25/2005 152900 12.39 109.7 477 02/25/2005 153000 12.4 107.8 478 02/25/2005 153100 12.4 112.1 479 02/25/2005 153200 12.36 115.8 480 02/25/2005 153300 12.34 120 481 02/25/2005 153400 12.39 118.3 482 02/25/2005 153500 12.46 119.5 483 02/25/2005 153600 12.47 120.8 484 02/25/2005 153700 12.4 114.6 485 02/25/2005 153800 12.47 112.6 486 02/25/2005 153900 12.47 115.2 487 02/25/2005 154000 12.39 114.9 488 02/25/2005 154100 12.38 119.1 489 02/25/2005 154200 12.38 118.8 490 02/25/2005 154300 12.41 115.2 491 02/25/2005 154400 12.41 105.5 492 02/25/2005 154500 12.32 96.9 493 02/25/2005 154600 12.32 99.6 494 02/25/2005 154700 12.35 105.3 495 02/25/2005 154800 12.37 104.6 496 02/25/2005 154900 12.42 109.7 497 02/25/2005 155000 12.38 105.9 498 02/25/2005 155100 12.45 101.8 499 02/25/2005 155200 12.46 100.2 500 02/25/2005 155300 12.32 99.5 501 02/25/2005 155400 12.29 96.6 502 02/25/2005 155500 12.36 96.7 503 02/25/2005 155600 12.4 103.2 504 02/25/2005 155700 12.31 103.9 505 02/25/2005 15:58 12.34 101.8 A verages: 12.615 113.669

13 of 13

### APPENDIX C PARTICULATE LABORATORY ANALYTICAL DATACustomer Big Bend Plant Big Bend Unit3Method 5-B Stack Test Completion Date02/25/2005Analyst GAH/SSSample NumberAA76139ACETONE BEAKER1st weighing Date 03/02/2005 Time 16:50 % RH 31.0%2nd weighing Date 03/03/2005 Time 15:18 % RH 38.0%3rd weighing Date 03/04/2005 Time 10:10 % RH 40.0%4th weighing Date 03/04/2005 Time 16:30 % RH 38.0%***Blank***Run 1 Run 2 Run 3 Run 1S Run 2S Run 3SAcetone Container IDAir 19 Air 5 Air R2 Air B2 Air 17 Air AA Air 05Acetone Rinse Vol.(Va), mls 200.0000 200 200 200 200 200 2001st Gross Wt., grams 106.4615 101.4518 103.7493 108.4180 105.1044 106.3647 106.82962nd Gross Wt., grams 106.4611 101.4508 103.7483 108.4162 105.1031 106.3629 106.82643rd Gross Wt., grams 106.4604 101.4506 103.7479 108.4165 105.1026 106.3629 106.82604th Gross Wt., grams 106.4603Avg. Gross Wt., grams 106.46130 101.45070 103.74810 108.41635 105.10285 106.36290 106.82620Tare Wt., grams 106.46030 101.44605 103.74060 108.40955 105.09725 106.35540 106.82100Acetone Blank Wt.,mg1.00 1.00 1.00 1.00 1.00 1.00 1.00Acetone Particulate Wt.,mg3.65 6.50 5.80 4.60 6.50 4.20Acetone Residue, mg/g0.0063Acetone Blank CriteriaFILTER1st weighingDate 03/01/2005 Time 16:50 % RH 43.0%Date 03/02/2005 Time 11:35 % RH 34.0%3rd weighing Date 03/02/2005 Time 17:40 % RH 31.0%4th weighing Date 03/03/2005 Time 15:10 % RH 38.0%Filter/Thimble ID 202315 202309 202310 202314 202307 202313 2023081st Gross Wt., grams 0.2651 0.2798 0.2753 0.2787 0.2802 0.2725 0.28282nd Gross Wt., grams 0.2650 0.2791 0.2745 0.2778 0.2794 0.2714 0.28213rd Gross Wt., grams 0.2651 0.2790 0.2745 0.2781 0.2801 0.2726 0.28284th Gross Wt., grams0.2802 0.2725 0.2829Avg. Gross Wt., grams 0.26505 0.27905 0.27450 0.27795 0.28015 0.27255 0.28285Tare Wt., grams 0.26495 0.26770 0.26350 0.26665 0.26765 0.25935 0.26925Filter Particulate Wt.,mg11.35 11.00 11.30 12.50 13.20 13.60Difference, milligrams0.1Total Sample Particulate Wt.,mg15.00 17.50 17.10 17.10 19.70 17.80OK to subtract acetone blankStart Here

### APPENDIX D BOILER/PRECIPITATOR OPERATIONAL DATA

### APPENDIX E FUEL ANALYSIS

### APPENDIX F FIELD DATA SHEETS

### APPENDIX G SAMPLING EQUIPMENT CALIBRATIONS

### SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 07) USEPA RM 5 INITIA L 10/05/2004 (ORIFICE) 1.001 POST TEST 03/01/2005 0.997

NOZZLE SN19 INITIA L 01/10/2005 CALIPER 0.287 POST TEST 03/01/2005 MEASUREMENTS 0.285

PYROMETER (PY 09) 01/04/2005 ASTM THERMOMETER + 2 o F
PITOT TUBE (PT 08) 01/19/2005 USEPA RM 2 C p = 0.84

BAROMETER (BR 02) 03/02/2005 NWS COMPARISON + 0.01" HgEnvironmental Services Air Services Group

Blue Team Manufacturer: Thermo Anderson Calibration Date: Model Number : MST-C1 Barometric Pressure: 30.25 "Hg Instrument Code Number: ^MB07 Theoretical Critical Vacuum: 14.27 "Hg L abWorks Sample Number: Calibrated By:

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 O Minutes f t 3 f t 3 f t 3 oF oF oF oF 0.62 15 3.577 10.434 6.857 79 81 79 81 1.15 15 93.523 102.765 9.242 83 78 79 81 1.90 15 69.792 81.726 11.934 81 89 87 81 3.65 15 21.691 38.150 16.459 85 96 86 96

Orifice K' Actual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3483 20.0 75 76 75.5 55 0.4660 19.0 77 75 76.0 63 0.5971 17.0 72 72 72.0 73 0.8177 14.0 73 73 73.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 (ratio) + 0.02 "H 2 O + 0.2

6.786 6.830 6.854 1.006 0.006 1.663 -0.044 9.154 9.133 9.174 0.998 -0.003 1.724 0.017 11.749 11.746 11.711 1.000 -0.001 1.709 0.001 16.088 16.071 16.053 0.999 -0.002 1.734 0.026 Averages: 1.001 1.707

Review/Approval: 8-Oct-04

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 10/05/2004

CRD

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly CalibrationEnvironmental Services Air Services Group

Manufacturer: Thermo Calibration Date: Model Number:MST Barometric Pressure: 30.1 "Hg Instrument Code Number: MB07 Theoretical Critical Vacuum: 14.20 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: BLUE

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 O Minutes ft 3 ft 3 ft 3 oF oF oF oF 1.10 10 354.350 360.474 6.124 73 77 74 78 1.10 10 360.474 366.612 6.138 74 78 75 78 1.10 10 366.612 372.762 6.150 75 78 75 79

Orifice K' Actual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4660 17.5 74 72 73.0 55 0.4660 17.5 72 72 72.0 55 0.4660 17.5 72 73 72.5

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 (ratio) + 0.02 "H 2 O + 0.2

6.088 6.076 6.099 0.998 0.000 1.663 0.004 6.094 6.081 6.093 0.998 0.001 1.657 -0.002 6.100 6.078 6.096 0.996 -0.001 1.657 -0.002 Averages: 0.997 1.659 Prior Y: 1.001 % Difference: 0.36%

Review/Approval: Date: Big Bend 3 compliance IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.

Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

Charles Dufeny 03/01/2005 POST - TEST CALIBRATION CHECK

3-Mar-2005 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. Critical OrificeEnvironmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET

Calibration Date: 01/10/2005 Responsible Party: Jorge A. Varino

Nozzle Nozzle Diameter, D n Maximum (cm) Average I.D. D 1 D 2 D 3 Difference, " D n , inches ^SN01 0.300 0.300 0.300 0.000 0.118 ^SN04 0.320 0.320 0.320 0.000 0.126 ^SN05 0.380 0.380 0.380 0.000 0.150 ^SN06 0.500 0.500 0.500 0.000 0.197 ^SN09 0.697 0.700 0.700 0.001 0.275 ^SN10 0.750 0.755 0.750 0.002 0.296 ^SN12 0.985 0.990 0.990 0.002 0.389 ^SN15 0.420 0.420 0.420 0.000 0.165 ^SN16 0.505 0.505 0.505 0.000 0.199 ^SN19 0.725 0.730 0.730 0.002 0.287 ^SN22 0.940 0.935 0.940 0.002 0.369 ^SN30 0.790 0.800 0.800 0.004 0.314 ^SN36 0.480 0.475 0.480 0.002 0.188 ^SN37 0.530 0.530 0.530 0.000 0.209 ^SN38 0.640 0.640 0.645 0.002 0.253 ^SN46 0.485 0.480 0.485 0.002 0.190 ^SN47 0.515 0.520 0.515 0.002 0.203 ^SN48 0.640 0.645 0.640 0.002 0.253 ^SN50 0.790 0.795 0.795 0.002 0.312 ^SN58 0.615 0.620 0.615 0.002 0.243 ^SN68 0.625 0.630 0.630 0.002 0.247 ^SN69 0.945 0.950 0.945 0.002 0.373 ^SN70 1.560 1.560 1.560 0.000 0.614 ^SN71 1.555 1.560 1.560 0.002 0.614 ^SN72 0.955 0.950 0.950 0.002 0.375 ^SN73 1.290 1.290 1.285 0.002 0.507 ^SN74 1.240 1.245 1.245 0.002 0.490 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".
QA/QC Review by: 13-Jan-05Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 03/01/2005 Calibration Personnel: Charles Dufeny Test Designation: Big Bend 3 Compliance

Nozzle Nozzle Diameter, D n Maximum (cm) Average Identifier D 1 D 2 D 3 Difference, " D n , inches

SN19 0.730 0.720 0.720 0.004 0.285

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".

Quarterly (pre-test) value for nozzle ID SN19 was 0.287

QA/QC Review by: 3-Mar-2005Pyrometer Calibration

Pyrometer Under Tes t Pyrometer Number: ^PY09 Labworks Sample # 0 Calibration Date: 01/04/2005

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: AOA024 Date of Last Calibration: 07/08/2004 Calibration Personnel (Typed and Signature): JORGE A VARINO

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 400 399 1 2 212 211 1 3 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 Pass 2 Pass 3 Pass

This data has been reviewed and is certified as meeting all project quality objectives.

Reviewer: Date: 6-Jan-2005c PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # pt08 Calibration Date: 01/19/2005 O p eratin g Quarter: 1 Openings Damaged?

___ Y

___ N Repaired?

____ Y ___ N ___ N/A

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.3 degrees Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.5 degrees Pass α < 10 degrees β 1 0 degrees Pass ( α 1 measured across top impact openings) β 2 0.4 degrees Pass ( α2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, A, Z, and W Determinations β 2 < 5 degrees (alongside bottom impact openings)
ψ 1.4 degrees Z< 0.32 cm (Asin ψ ) Α 2.375 cm W < 0.08 cm (Asin ο ) Ζ 0.058 cm Pass A distance between tips

ο angle of plane on side of pitots

ο 1.8 degrees ψ angle between tips W 0.075 cm Pass

NOTES All measurements are taken in accordance with the requirements of 40 CFR 60 Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specifi Methods", sub-section 3.1.1, Procurement of Apparatus and Supplies.

Comments: REVMOVABLE

Printed Name: Charles Dufeny Date: 01/19/2005

Quality Assurance Review / Approval: 21-Jan-2005

5010 Causeway Blvd., Tampa, FL. 33619Environmental Services Air Services Group

BAROMETER CALIBRATION Red Team Instrument Number: BR02 Calibration Date: 03/02/2005 Calibration Personnel: Charles Dufeny

Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 9:53 30.18 30.20 -0.02 10:53 30.20 30.20 0.00 12:53 30.15 30.16 -0.01

Avera g e Difference: -0.01

Note: Barometric readin g s must a g ree within + 0.1 "H g

. Current Reference is National Weather Service, Ruskin Florida.
Comments (Note any ad j ustments):

QA/QC Review by: Date: 4-Mar-2005

### APPENDIX H CHAIN OF CUSTODY

### APPENDIX I TEST PARTICIPANTS

### TEST PARTICIPANTS

AIR SERVICES GROUP ENVIRONMENTAL SERVICES
Charles Dufeny Environmental Technician Jorge Varino Technician Ray McDarby Senior Environmental Technician
BIG BEND STATION

Karen ZwolakSenior Environmental Consultant