A 1 1 1

0

2 155770

Reference

NBSIR 84-3006

NBS

PUBLICATIONS

AlllOb 437140

EXPERIMENTAL THERMAL

CONDUCTIVITY VALUES FOR

HYDROGEN, METHANE, ETHANE

AND PROPANE

National Bureau of Standards

U.S. Department of Commerce

Boulder, Colorado 80303

May 1984

QC —

100

.U56

34-3006

1934

NBSIR 84-3006

: NATIONAL SUREA0

OF STANDARDS

LIBRARY

EXPERIMENTAL THERMAL

CONDUCTIVITY VALUES FOR

HYDROGEN, METHANE, ETHANE

AND PROPANE

H.M. Roder

Chemical Engineering Sciences Division

National Engineering Laboratory

National Bureau of Standards

U.S. Department of Commerce

Boulder, Colorado 80303

May 1984

Prepared for: NASA-Lewis Research Center

Cleveland, Ohio 44135

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

CONTENTS

Page

1 . I ntroduc ti on 1 2. Hydrogen Results 2 3. Methane Results 26

4. Ethane Results 39

5. Propane Results 51

6. References 5b

List of Tables

Table 1. The thermal conductivity of hydrogen, normal and near normal

compositions 4 Table 2. The thermal conductivity of hydrogen, para and para-rich

compositions 19

Table 3. The thermal conductivity of methane 27

Table 4. The thermal conductivity of ethane 40

Table 5. The thermal conductivity of propane 52

iii

Experimental Thermal Conductivity Values for

Hydrogen, Methane, Ethane and Propane

Hans M. Roder

Chemical Engineering bcience Division

National Engineering Laboratory

National Bureau of Standards

Boulder, Colorado 80303

The experimental measurements of thermal conductivity as obtained in a transient hot wire apparatus for hydrogen, methane, ethane ana propane are recorded

.

Key words: ethane; hot wire; hydrogen; measurements; methane; propane;

thermal conductivity; transient.

1. Introduction

New experimental measurements of the thermal conductivity of fluids are always of

interest, expecially if the measurement is an absolute one, and if the results are as accurate as those that can be obtained from a transient hot wire apparatus. Perhaps

the single drawback of a transient hot wire system is the rapid accumulation of large

quantities of data. This report is the archival record of results on hydrogen,

methane, ethane and propane with a minimum of text since analysis, explanation and

discussion of the results are given in the references of sections 2, 3, 4, and 5.

The measurements were made with a transient hot wire thermal conductivity

apparatus [l] 1 which has been tested with nitrogen [1], helium [1] and argon [2,3].

The system has been used previously to measure the thermal conductivity surface of

oxygen [4]. The temperature range of the instrument is 77 to 325 K and the pressure

range is from near zero to 70 MPa.

The scheme used to measure the thermal conductivity surface of a given fluid is

to conduct the measurements along isotherms. The spacing in temperature is chosen to

be around 20 K resulting in a change of several percent in thermal conductivity

between different isotherms. On each isotherm measurements are made at a number of

different pressures. The spacing in pressure is arranged to give a spacing in density

of about 1 mol/L. Finally, replicate measurements at the same cell temperature and

pressure are made with three or four different power levels. The replicate measurenents serve to verify the absence of convection, and, because the experimental

temperatures vary with the applied power level, the measurements are actually

independent of each other.

The sections for the individual fluids give the references where the results have

5een or will be published, the tables of data, the correlating equations in the form

5 f computer programs which were used to adjust the thermal conductivity values to the

lominal tempe ra tu res , and the equations of state used to infer densities from the

neasured pressures and temperatures. Recorded in the tables of data are the run ana

'•Numbers in brackets indicate the literature references at the end of the paper.

1
the point numbers, the pressure, temperature and density of the fluid, the applied

power, the experimental thermal conductivity, and its associated linear regression

statistic STAT. For hydrogen the ortho-para composition is given as well. In the

analysis of the thermal conductivity surface it is desirable to have the thermal

conductivities at integral values of temperature. Therefore, each point has been

adjusted at constant density to the nominal isotherm temperature by a slight shift in

temperature using the correlating equations for the surface in question. Printed in

the data tables are the adjusted thermal conductivities at the nominal isotherm

temperature as well as the deviation between the adjusted values and the correlating

surf ac e.

2. Hydrogen Results

A total of 1645 points were measured. Normal and near normal compositions are found in Table 1, para and para-rich compositions in Table 2. Preliminary, normal

results are reported in [5], a summary of the para results in [6], and the analysis of

the thermal conductivity surface for both normal and para including the assignment of

composition in [7]. The computer programs developed for the thermal, conductivity of

hydrogen are shown below. The equation of state usea for hydrogen is given in L8].

FUNCTION TC0PH2( DD,TIN,0P)

C INPUT, DENSITY MOL/L, TEMPERATURE K, OP PARA FRACTION

C OUTPUT, THERMAL CONDUCTIVITY OF HYDROGEN, W/M.K, 4 FEB 84

DIMENSION T N Z ( 2 6 ) ,TPZ(26) , TT (26) , G ( 3

)

DATA( TNZ( I ) ,1=1 ,26) /.0505, .0568, .0632, .0695 , .0763, .0829, .0896

,

1 .0962 ,. 1026 , .1092 , .1 157 , .1220, . 1282 , .1342 ,. 1401 , .1458 , .1514 , 2 .156 9 ,. 162 2 ,. 1674,. 1725,. 1774,. 1823,. 187 0 ,. 1917 ,. 196 2/

DATA( TPZ( I ) , 1 = 1 ,26) / .0529 , .0617 , .0714 , .0816 , .0924 , .1028 ,. 1125 , 1 .1213, .12 94 , .1365, .142 7, .1482, .1530 , .1574, .1614, .1651, .1687,

2 . 1723 , .17 58 , .1793 , .1828 , .1863 ,

. 1899 , .1935 , .1972 , .2010/

DATA(TT( I ), 1=1 ,26 )/70 . ,80 . ,90 . ,100. ,110. ,120. ,130 . ,140 . ,150.

,

1 160., 170., 180., 190., 2 00., 210., 2 20., 2 30 ., 240., 2 50 ., 26 0., 2 70 .,

2 280 . ,290 . ,300. ,310. ,320 ./

DATA G/. 15843126U4E-02 ,

. 386 1 1 03 1 93E- 04 , .1066433014E-06/

DO 3 1=1,26

I F ( T I N . LT . TT ( I) ) GO TO 4

3 CONTINUE

4 CONTINUE

TCZN = TNZ( I - 1 ) + ( TNZ ( I ) - T N Z ( 1-1 ) ) * ( TI Im-TT ( I - 1 ) )/(TT( I ) - T T ( I - 1 ) ) TCZP = TPZ( I- 1 ) + ( TPZ ( I

) -TPZ ( 1-1) ) * ( TI N-TT ( 1-1) ) / ( TT ( I

) -TT ( 1-1)

)

OPDIFF=TCZP-TCZN

TCZADJ=0PDIFF/0.75*(0P-0 .25

)

FACTO R=1 .0-0. 028484+0. 000070588*T IN TCZ=TCZN*FACT0R+TCZADJ+CRITH2(DD,TIN)

TC0PH2=TCZ+G(l)*UD+(G(2)+b(3)*TIN)*(EXP(2.1*Du**0.36)-1.0)

RETURN

END

FUNCTION CRITH2( RHO.TEMP)

C ADAPTED FROM 02 FOR HIGH TEMPERATURE H2

C VALID FROM 78 K UP, AMP L IS LINEAR

DATA (TC = 32.938) ,(RH0C = 15.556)

T=TEMP

D E N = R H 0

I F ( T . GT . 7 7 . .AND. T . LT . 1 08 . 35658 ) GO TO 4 CRITH2=0

.

RETURN

4 CONTINUE

AMPL=0 .00635 36 3-0. 00 00 586 3*T

DELT=T-TC

2
RHOC E NT=R HOC- 0.008 22 9*UELT**1 .5

DELRHO=OEN-RHOCENT

Xl= . 138*DELRH0

CRITH2=AMPL*EXP ( - X 1 * * 2

)

RETURN

END
Table 1. The Thermal Conductivity of Hydrogen* Normal and Near Normal Compositions

Experimental AdJ. Thermal Conductivity

Therma

1

Norn. Temperature dev 1 atlon

Run Pt. Pressure Temperature Dens 1 ty para Power Conduct! vl ty STAT 300.0 K exp. -calc.

MPa K mol /L f ract 1 on W/m W/m.K W/m.K percent

38062 67.316 297.768 18.9805 .2500 .55030 .24302 .005 .24419 -.68

38063 67.317 298.415 18.9512 .2500 . 789 ei .24253 .004 .24336 -.96

38064 67.317 299.194 18.9160 .2500 1.07232 .24341 .002 .24383 -.69

38065 67.318 300.090 18.8758 .2500 1.39816 .24437 .002 .24432 -.41

38066 67.318 300.631 18.8514 .2500 1.57690 .24440 .002 .24407 -.46

38067 64.867 297.711 18.5013 .2500 .54945 .24053 .005 .24173 -.72

38068 64.867 298.214 18.4787 .2500 .78817 .23852 .004 .23945 -1.63

38069 64.868 298.990 18.4442 .2500 1.07035 .24043 .002 .24096 -.92

38070 64.871 299.845 18.4066 .2500 1.39577 .24125 .002 .24133 -.69

38071 61.368 297.491 17.8033 .2500 .55041 .23614 .005 .23744 - 1.12

38072 61.368 298.203 17.7720 .2500 .79029 .23660 .003 .23753 - 1.01

38073 61.368 299.058 17.7346 .2500 1.07325 .23706 .002 .23755 -.93

38074 61.368 300.016 17.6928 .2500 1.39959 .23751 .002 .23750 -.87

38075 57.884 297.556 17.0723 .2500 .55050 .23312 .002 .23438 -.99

38076 57.886 298.134 17.0478 .2500 .79029 .23381 .003 .23477 -.77

38077 57.886 299.143 17.0047 .2500 1.07315 .23381 .002 .23425 -.91

38078 57.886 300.119 16.9632 .2500 1.39937 .23409 .002 .23403 -.93

38079 54.612 297.614 16.3631 .2500 .55052 .23012 .006 .23134 -.95

38080 54.612 298.347 16.3327 .2500 .79021 .23090 .003 .23175 -.71

38081 54.613 299.210 16.2969 .2500 1.07312 .23117 .001 .23158 -.72

38082 54.613 300.201 16.2559 .2500 1.39916 .23185 .002 .23175 -.57

38083 50.862 297.577 15.5263 .2500 .55084 .22693 .004 .22816 -.79

3 80 84 50.862 298.253 15.4991 .2500 .79046 .22803 .003 .22892 -.41

38085 50.862 299.140 15.4634 .2500 1.07319 .22782 .003 .22826 -.63

38086 50.863 300.177 15.4220 .2500 1.39915 .22821 .003 .22812 -.62

38087 47.428 297.686 14.7260 .2500 .55080 .22382 .005 .22499 -.76

38088 47.427 298.435 14.6965 .2500 .79098 .22420 .003 .22499 -.71

38089 47.428 299.335 14.6618 .2500 1.07436 .22451 .002 .22485 -.71

38090 47.428 300.433 14.6193 .2500 1.40067 .22477 .002 .22455 -.77

38091 43.926 297.777 13.8814 .2500 .55041 .22035 .003 .22147 -.87

38092 43.926 298.473 13.8554 .2500 .79045 .22068 .003 .22145 -.84

38093 43.926 299.408 13.8205 .2500 1.07351 .22143 .002 .22173 -.65

38094 43.927 300.455 13.7818 .2500 1.39957 .22223 .002 .22200 -.46

38095 40.423 297.744 13.0096 .2500 .55011 .21760 .004 .21873 -.65

38096 40.423 298.510 12.9821 .2500 .78964 .21795 .002 .21870 -.62

38097 40.423 299.421 12.9497 .2500 1.07237 .21613 .002 .21842 -.70

38098 40.423 300.493 12.9118 .2500 1.39902 .21879 .002 .21854 -.58

38001 40.963 297.338 13.1609 .2500 .54935 .21762 .005 .21895 -.80

38002 40.961 299.537 13.0813 .2500 1.22817 .21906 .002 .21929 -.52

38003 40.961 300.024 13.0639 .2500 1.39645 .21921 .002 .21920 -.53

38004 40.956 298.980 13.1001 .2500 1.07091 .21882 .002 .21933 -.53

38005 40.956 298.075 13.1327 .2500 .78840 .21858 .003 .21954 -.48

38006 40.955 296.934 13.1736 .2500 .44605 .21761 .006 .21915 -.74

38007 37.588 297.362 12.2918 .2500 .54965 .21408 .005 .21540 - 1.03

38008 37.588 298.200 12.2630 .2500 .78899 .21587 .003 .21677 -.34

38009 37.588 299.088 12.2326 .2500 1.07152 .21608 .002 .21653 -.40

38010 37.588 300.273 12.1924 .2500 1.39673 .21613 .002 .21599 -.59

38011 34.239 297.331 11.3990 .2500 .54955 .21170 .005 .21302 -.72

38012 34.239 298.263 11.3688 .2500 .78855 .21213 .003 .21299 -.69

38013 34.239 299.145 11.3403 .2500 1.07117 .21292 .002 .21334 -.48

38014 34.239 300.265 11.3044 .2500 1.39663 .21348 .002 .21335 -.42

38015 30.257 300.410 10.2008 .2500 1.39649 .20982 .002 .20962 -.52

38016 30.257 299.195 10.2367 .2500 1.07123 .20958 .002 .20998 -.40

38017 30.257 298.212 10.2659 .2500 .78866 .20897 .003 .20985 -.50

38018 30.256 297.402 10.2899 .2500 .54934 .20741 .005 .20869 - 1.10

38019 27.168 297.074 9.4062 .2500 .44597 .20547 .006 .20691 -.66

38020 27.168 297.861 9.3843 .2500 .66358 .20581 .004 .20686 -.65

38021 27.168 293.753 9.3596 .2500 .92446 .20598 .002 .20659 -.75

38022 27.168 299.838 9.3297 .2500 1.22839 .20700 .002 .20708 -.47

38023 23.554 297.126 8.3184 .2500 .44591 .20143 .003 .20284 - 1.12

38024 23.554 297.849 8.3003 .2500 .66296 .20199 .003 .20304 -.99

38025 23.554 298.734 8.2782 .2500 .92333 .20309 .002 .20371 -.63

38026 23.554 299.842 8.2508 .2500 1.22688 .20356 .002 .20364 -.63

38027 19.866 297.138 7.1623 .2500 .44540 .19910 .008 .20049 -.72

38028 19.866 297.992 7.1433 .2500 .66278 .19930 .002 .20028 -.80

38029 19.866 298.920 7.1230 .2500 .92347 .20008 .003 .20061 -.61

38030 19.866 300.086 7.0977 .2500 1.22702 .20042 .002 .20038 -.69

38031 16.373 297.221 6.0193 .2500 .44611 .19494 .006 .19629 - 1.37

38032 16.373 298.019 6.0043 .2500 .66450 .19658 .003 .19754 -.71

38033 16.373 299.112 5.9838 .2500 .92562 .19754 .003 .19797 -.47

38034 16.372 300.315 5.9613 .2500 1.23002 .19772 .003 .19757 -.64

4
38035 12.758 297.355 4.7862 .2500 .44657 .19324 .006 .19452 -.75

38036 12.758 298.273 4.7723 .2500 .66447 .19326 .004 .19410 -.95

38037 12.758 299.323 4.7564 .2500 .92559 .19410 .003 .19443 -.76

38038 12.758 300.545 4.7381 . 2500 1.22979 .19515 .002 .19489 -.50

38039 9.260 297.425 3.5443 .2500 .44636 .18987 .006 .19111 -1.05

38040 9.260 299.322 3.5341 .2500 .66434 .19050 .004 .19131 -.93

38041 9.260 299.453 3.5212 .2500 .92532 .19185 .003 .19211 -.49

38042 9.260 300.748 3.5066 .2500 1.22949 .19218 .003 .19182 -.63

38043 5.727 297.505 2.2373 .2500 .44633 .18793 .006 .18913 -.61

38044 5.726 298.485 2.2299 .2500 .66416 .18838 .004 .18911 -.61

38045 5.726 299.640 2.2214 . 2500 .92518 .18097 .003 .18914 -.58

38046 5.726 300.259 2.2169 .2500 1.07196 .18946 .003 .18934 -.47

38u4? 6 .893 297.716 2.2229 .2500 .44666 .18926 .006 .19036 .06 38048 5.693 299 .651 2.2161 . 2600 .66476 . 10965 .004 .19030 .04

3 9049 5.893 ?9<J.788 2.2078 . 2500 .92586 .19971 .003 .19981 -.21

3PP50 5.693 300.348 2.2038 .2500 1.07272 .19022 .003 .19005 -.08

38051 2.258 297.621 .9003 .2500 .44603 .19491 .007 .13605 -.79

3805? 2.253 293.059 .8990 . 2600 . 54952 .18500 .009 .18593 -.85

38053 2.258 298.540 .3976 .2500 .66375 .19539 .008 .18609 -.77

38054 2.258 299.116 .8958 .2500 .78887 .18565 .006 .18607 -.77

38055 2.258 299.740 .8937 . 2500 .92466 .18631 .005 .18643 -.58

Expe r 1 ment a 1 AdJ. Thermal Conductivity

Ther ma 1 Nom. Temperature deviation

Run Pt. Pressure Temperature Dens 1 ty para P oxer Conduct 1 v 1 ty STAT 250.0 K exp . -c a 1 c

.

"Pa K mo 1 / L Tract Ion V/m W/i».K W/a.K percent

39001 68.197 248.921 21.6909 .2500 1.01362 .22923 .003 .22987 -1.09

3900? 88.200 249.852 21.6364 .2500 1.30044 .23207 .002 .23216 .03 39003 68.206 250.275 21.6129 .2500 1.45637 .23115 .002 .23099 -.42

39004 64.709 250.364 20.8806 .2500 1.45645 .22716 .001 .22695 -.46

39005 64.712 249.414 20.9363 .2500 1.15140 .22849 .002 .22884 .24 39006 64.713 249.831 20.9122 .2500 1.29928 . 22680 .001 .22690 -.55

39007 61.375 249.570 20.2074 .2500 1.15329 .22385 .002 .22410 -.16

39008 61.378 249.934 20.1872 .2500 1.30198 .22371 .002 .22375 -.28

39009 61.376 250.427 20.1589 .2500 1.45928 .22439 .002 .22414 -.03

39010 57.953 249.526 19. 4446 .2500 1.15376 .22009 .002 .22037 -.12

39011 57.953 249.909 19.4231 .2500 1.30197 .22021 .002 .22026 -.12

39012 57.953 250.414 19.3951 .2500 1.45931 .21959 .002 .21935 -.48

3 9013 54.237 249.528 18.5801 . 2500 1.15346 .21594 .002 .21621 -.13

39014 54.237 250.074 18.5502 .2500 1.30159 .21638 .002 .21634 -.00

39015 54.237 250.546 18.5245 .2500 1.45883 .21663 .001 .21632 .04 39016 50.961 250.669 17.7263 .2500 1.45964 .21313 .002 .21275 .08 39017 5C.961 2*0.081 17.7576 .2500 1.30216 .21266 .002 .21261 -.05

39018 5C .962 249.628 1 7 .782 0 .2500 1.15371 .21291 .002 .21302 .10 30010 4?.?48 249.234 16.8919 .2500 1.01461 .20514 .002 .20858 -.16

39020 47.3*9 249.732 16.3662 . 2600 1.15368 . 20909 .003 .20923 .20 39021 47.349 250,233 16.8400 .2500 1.30199 .20977 .002 .20964 .45 39022 42.152 249.390 15.5019 .2500 1 .01439 .20374 .002 .20408 .44 39023 42.152 249.868 15.4788 .2500 1.15350 .20169 .002 .20176 -.66

39024 42.152 250.386 15.4533 . 2500 1.30195 .20326 .002 .20305 .03 39025 40.164 249.472 14.9461 .2500 1.01442 .19934 .002 .19964 -.69

39026 40.164 249.954 14.9227 .2500 1.15359 .20080 .002 .20083 -.05

39027 40.164 250.471 14.8980 .2500 1.30186 .20111 .001 .20085 .01 39028 36.828 249.500 13.9859 .2500 1.01438 .19627 .002 .19655 -.43

39029 36.828 249.946 13.9654 .2500 1.15361 .19831 .002 .19834 .51 39030 36.828 250.546 13.9379 .2500 1.30174 .19677 .002 .19647 -.39

39031 33.386 249.614 12.9476 .2500 1.01438 . 19506 .002 .19527 .80 39032 33.386 250.103 12.9264 .2500 1.15348 .19235 .002 .19229 -.69

39033 33.366 250.639 12.9031 .2500 1.30194 .19375 .002 .19340 -.08

39034 29.369 249.701 11.6779 .2500 1.01313 .18964 .002 .18981 .19 39035 29.369 250.187 11.6583 .2500 1.15231 .18981 .002 .18971 .17

39036 29.369 249.157 11.6998 .2500 .88308 .18988 .003 .19035 .43 39037 26.273 249.263 10.6714 .2500 .88483 .18566 .002 .18607 -.11

39038 26.271 2*9.794 10.6507 . 2500 1 .01561 .18550 .002 .18561 -.32

39039 26.270 250.357 1C. 6295 .2500 1.15512 .18706 .002 .10667 .39 30040 2’ . °40 249.392 9.4798 .2500 .08537 .18227 .002 .18260 -.06

39041 22.840 249.951 9.4607 .2600 1.01564 .18256 .003 . 16259 -.04

39042 22.840 250.526 9.4412 .2500 1.155C3 .18265 .001 .18236 -.12

39043 19.32? 249.667 0 . 1964 . 2500 .88486 .17973 .002 .17991 .44 39044 19.322 250.136 8.1823 .2500 1.01501 .17996 .002 .17909 • 44

3 9045 19. 3?3 250.707 3.1656 .2500 1.154C4 . 18025 .002 .17987 .47

39C46 17.251 249.217 7.4297 .2500 .76268 .17692 .003 .17735 .16 39047 17.251 249.723 7.4157 .2500 .88382 .17712 .002 .17727 .13 39048 17.251 250.233 7.4017 .2500 1.01412 .17750 .002 . 17738 .21 39049 15.213 249.202 6.6399 .2500 .76365 .17461 .003 .17504 -.00

39050 15.213 249.692 6.6277 .2500 .88538 .17530 .003 .17547 .26 39051 15.213 250.276 6.6132 .2500 1.01593 .17554 .003 .17539 .24 39052 13.128 249.285 5.8069 . 2500 .76382 .17276 .003 .17315 .09

39053 13.128 249.799 5.7956 .2500 .08525 .17281 .003 .17292 -.02

39054 13.128 250.344 5.7836 .2500 1.01583 .17315 .002 .17297 • 02 39055 11.082 249.337 4.9673 . 2500 .76365 .17034 .002 .17070 -.17

39056 11.032 249.839 4.9578 .2500 .88507 .17079 .002 .17088 -.06

39057 11.082 250.448 4.9462 .2500 1.01536 .17146 .002 .17122 .16 39058 9.044 249.427 4.1071 .2500 .76360 .16837 .003 .16868 -.21

5
3 0059 9.044 249.972 4.0984 .2500 .88511 .16958 .002 .16960 .35 39060 9.043 250.568 4.0887 .2500 1.01545 .16926 .003 .16896 -.02

39061 6.749 249.008 3.1166 .2500 .65145 .16586 .004 .16639 -.28

39062 6.747 249.535 3.1093 .2500 .76390 .16624 .002 .16649 -.21

39063 6.747 250.167 3.1016 .2500 .88518 .16713 .004 .16704 .13 39064 4.793 249.121 2.2413 . 2500 .65132 .16475 .003 .16522 .13 39065 4.792 249.652 2.2363 .2500 .76381 .16518 .003 .16537 .22 39066 4.792 250.272 2.2308 .2500 .88536 .16476 .003 .16462 -.23

39067 2.833 249.330 1.3409 .2500 .65129 . 16312 .004 .16348 .19 39068 2.833 249.943 1.3377 .2500 .76365 .16419 .004 .16422 .64 39060 2.832 249.584 1.3392 .2500 .70636 .16333 .004 .16355 .23 39070 1.278 249.363 .6111 .2500 .65055 .16284 .012 .16318 .89

Exper 1 mental Adj. Thermal Conduct 1 v Ity

Therma

1

Nom

.

Temperature deviation

'J n P t . Pressure Temperature Dens 1 ty para Power Conductl vl ty STAT 200.0 K exp. -calc.

MPa K mo 1 / L Tract Ion W/m W/m.K W/m.K percent

4 000 1 68.69? 199,987 25.1397 .2500 1.02232 .22167 .001 .22168 .33 40002 6 0 • 6P 9 200, 2e4 25.1157 .2500 1.14618 .22142 .002 .22123 .20 40003 68.688 200.678 25.0844 .2500 1.27732 .22147 .001 .22101 .19 40O04 64.982 1 99.822 24.3445 .2500 1.02239 .21614 .001 .21626 .10 40005 64.984 200.184 24.3166 .2500 1.14684 .21567 .001 .21555 -.16

40006 64.984 200.631 24.2816 .2500 1.27824 .21632 .001 .21590 .10

4 000 7 61.616 199.949 23.5697 .2500 1.02309 .21085 .002 .21088 -.28

40008 61 .617 200.360 23.5381 .2500 1.14706 .21149 .002 .21125 -.02

40009 61.617 200.771 23.5063 .2500 1.27824 .21222 .002 .21171 .28 40010 58.091 200.071 22.7245 .2500 1.02327 .20742 .002 .20737 .32 40011 58.091 200.446 22.6957 .2500 1.14740 .20762 .002 .20733 .38 40012 58.092 200.811 22.6681 .2500 1.27873 .20753 .002 .20700 .29 40013 54.613 200.117 21.8588 .2500 1.02287 . 20246 .001 .20238 .18 40014 54.613 200.523 21.8280 .2500 1.14669 .20246 .001 .20212 .12 40015 54.614 200.891 21.8004 .2500 1.27856 .20296 .001 .20238 .32 40016 51.083 200.217 20.9342 .2500 1.02358 .19864 .001 .19850 .62 40017 51.085 200.646 20.9028 .2500 1.14747 .19875 .001 .19833 .62 40018 51.087 201.034 20.8746 .2500 1.27892 .19834 .001 .19767 .36 40019 47.666 200.290 19.9974 .2500 1.02318 .19386 .002 .19367 .52 40020 47.666 200.710 19.9670 .2500 1.14727 .19427 .001 .19381 .66 40021 47.663 201.069 19.9412 .2500 1.27872 .19480 .001 .19411 .88 40022 44.034 200.136 18.9673 .2500 1.02235 .18936 .001 .18927 .74 40023 44.036 200.558 18.9379 .2500 1.14635 .18933 .001 .18897 .65 40024 44.037 201.025 18.9051 .2500 1.27756 .18956 .001 .18891 .69 40025 40.646 199.784 17.9683 .2500 .90496 .18455 .002 .18469 .66 40026 40.647 200.181 17.9409 .2500 1.02178 .18456 .002 .18445 .59 40027 40.647 200.650 17.9086 .2500 1.14565 .18512 .001 .18471 .81 40029 37.112 200.291 16.8074 .2500 1.02147 .17984 .007 .17966 .57 40031 33.560 199.928 15.6336 .2500 .90463 .17450 .003 .17455 .30 40033 33.560 200.757 15.5808 .2500 1.14535 .17616 .003 .17569 1.06

40034 30.078 199.904 14.3914 .2500 .90530 .17072 .002 .17078 .78 40035 30.077 200.344 14.3644 .2500 1.02218 .17064 .002 .17043 .63 40036 30.076 200.895 14.3308 .2500 1.14629 .17145 .002 .17090 .97 40037 26.575 199.751 13.0738 .2500 .79580 .16571 .002 .16586 .58 40038 26.575 200.145 13.0511 .2500 .90524 .16607 .002 .16598 .69 40039 26.575 200.651 13.0224 .2500 1.02239 .16664 .002 .16624 .90 40040 22.879 199.858 11.5790 .2500 .79588 .16059 .002 .16068 .35 40041 22.879 200.288 11.5566 .2500 .90562 .16106 .001 .16088 .52 40042 22.879 200.740 11.5333 .2500 1.02265 .16201 .001 .16156 .98 40043 19.483 199.966 10.1205 .2500 .79602 ,15699 .001 .15701 .79 40044 19.483 200.421 10.0993 .2500 .90567 .15691 .001 .15666 .61 40045 19.483 200.956 10.0746 .2500 1.02286 .15794 .002 .15736 1.10

40046 17.235 200.156 9.1031 .2500 .79726 .15421 .002 .15412 .78 40047 17.236 200.641 9.0829 .2500 .90748 .15451 .002 .15412 .82 40048 17.236 199.592 9.1275 .2500 .69464 .15378 .002 . 15403 .68 40049 15.172 199.644 8.1624 .2500 .69481 .15113 .002 .15135 .63 40050 15.172 200.109 8.1445 .2500 .79769 .15145 .002 .15138 .69 40051 15.172 200.587 8.1261 .2500 .90781 .15196 .002 .15161 .87 40052 13.207 199.661 7.2134 .2500 .69490 .14845 .002 .14866 .47 40053 13.207 200.243 7.1933 .2500 .79756 .14911 .002 .14896 .71 40054 13.208 200.781 7.1751 .2500 .90762 .14944 .002 .14897 .75 40055 11.114 199.898 6.1609 .2500 .69505 .14641 .002 .14647 .74 40056 11.114 200.370 6.1468 .2500 .79784 .14675 .002 .14653 .81 40057 11.114 199.387 6.1762 .2500 .59924 .14620 .002 .14657 .79 40058 9.000 199.540 5.0789 .2500 .59936 .14321 .003 .14349 .44 40059 9.000 199.950 5.0683 .2500 .69505 .14399 .002 .14402 .82 40060 9.000 200.528 5.0540 .2500 .79790 .14399 .002 .14368 .61 40061 6.801 199.593 3.9004 .2500 .59941 .14044 .002 .14069 .32 40062 6.801 200.109 3.8904 .2500 .69510 .14109 .002 .14103 .57 40063 6.800 200.734 3.8781 .2500 .79816 .14153 .002 .14109 .64 40064 4.840 199.729 2.8144 .2500 .59967 .13810 .002 .13826 .24 40065 4.840 200.328 2.8061 .2500 .69528 . 13884 .002 .13865 .53 40066 4.840 200.943 2.7976 .2500 .79832 .13907 .002 .13851 .44 40067 2.771 199.535 1.6372 .2500 .51119 .13563 .003 .13591 .27 40068 2.771 200.034 1.6331 .2500 .59970 .13605 .003 .13603 .36 40069 2.770 200.606 1.6281 . 2500 .69563 .13691 .002 .13655 .75

6
Run Pt. Pressure STAT

HPe TemperatureK

Experl mental

Ther ma

I

Density para Power Conductivity

mol/L fraction W/t W/m.K

AdJ. Thermal Conductivity

Norn. Temperature deviation

175.0 K exp. -calc.

M/m.K percent

41001 68.280 173.727 27.3095 .2500 .87423 .21719 .002 .21813 .34 41002 68.271 174.002 27.2817 .2500 .98033 .21704 .002 .21777 .27 41003 68.267 174.232 27.2594 .2501 1.09242 .21722 .002 .21778 .34 41004 68.262 174.685 27.2162 .2501 1.21069 .21612 .001 . 21635 -.18

41005 64.900 174.085 26.5262 .2502 .97983 .21166 .001 .21233 .07 41006 64.903 174.388 26.4986 .2502 1.09201 .21216 .002 .21260 .29

41007 64.904 174.807 26.4599 .2503 1.21049 .21206 .001 .21220 .22 41008 61.485 174.165 25.7274 .2506 .97969 .20616 .002 .20676 -.15

41009 61.486 174.402 25.7056 .2506 1.09201 .20702 .002 .20745 .25 41010 61.485 174.775 25.6710 .2506 1.21007 .20656 .002 .20672 -.00

41011 57.521 174.194 24. 7598 .2509 .97971 .19986 .002 .20043 -.37

41012 57.521 174.499 24.7316 .2509 1.09196 .20087 .001 .20123 .11 41013 57.521 174.964 24.6891 .2509 1.20985 .20101 .001 .20104 .14 41014 54.101 174.296 23.8738 .2510 .97961 .19579 .002 .19629 .13 41015 54.103 174.682 23.8394 .2510 1.09202 .19695 .002 .19717 .68 41016 54.106 175.083 23.8037 .2511 1.20996 .19576 .001 .19570 .03 41017 50.803 174.317 22.9842 .2512 .97969 .19134 .002 .19182 .37 41018 50.805 174.782 22.9428 .2512 1.09209 .19145 .002 .19160 .38 41019 50.808 175.128 22.9123 .2512 1.20989 .19173 .001 .19164 .49 41020 47.167 174.035 21.9770 .2514 .87467 .18548 .001 .18615 .20

41021 47.169 174.382 21.9465 .2514 .98122 .18563 .001 .18606 .23 41022 47.172 174.812 21.9092 .2514 1.09421 .18656 .001 .18669 .67 41023 43.851 174.201 20.9667 .2516 .87509 .18065 .002 .18120 .26 41024 43.854 174.485 20.9426 .2516 .98101 .18118 .002 .18153 .51 41025 43.855 174.872 20.9093 .2516 1.09368 .18115 .002 .18124 .44 41026 40.172 174.298 19.7875 .2517 .87624 .17525 .001 .17573 .33 41027 40.174 174.646 19.7582 .2518 .98326 .17544 .001 .17568 .38 41028 40.174 175.096 19.7197 .2518 1.09618 .17586 .001 .17579 .54 41029 36.927 174.375 18.6843 .2519 .87655 .17083 .002 .17125 .59 41030 36.929 174.787 18.6504 .2519 .98334 .17116 .002 .17130 .71 41031 36.930 175.267 18.6109 .2520 1.09673 .17132 .001 .17114 .71 41032 32.668 174.133 17.1625 . 2576 .77613 .16602 .002 .16660 1.50

41033 32.669 174.570 17.1278 .2576 .87653 .16613 .002 .16642 1.48

41034 32.669 174.955 17.0971 .2576 .98305 .16624 .002 .16627 1.47

41035 29.963 174.243 16.1085 .2578 .77579 .16072 .002 .16122 .76 41036 29.963 174.559 16.0841 .2578 .87603 .16060 .002 .16089 .62 41037 29.964 175.032 16.0480 .2578 .98297 .16112 .001 .16110 .83 41038 26.454 174.253 14.6676 .2579 .77575 .15547 .002 .15596 .79

41039 26.455 174.697 14.6356 .2579 .87619 .15602 .002 .15622 1.03

41040 26.455 175.130 14.6044 .2580 .98281 .15623 .002 .15615 1 . C 5 41041 22.841 174.348 13.0698 .2581 .77620 .15013 .002 .15055 .82 41042 22.842 174.824 13.0385 . 2581 .87671 .15032 .002 .15043 .81 41043 22.842 173.882 13.1019 .25 82 .68174 .14976 .002 .15049 .71 41044 19.491 174.194 11.4975 .2563 .68225 .14486 .002 .14538 .67 41045 19.491 174.609 11.4726 .2583 .77658 .14531 .002 .14556 .85

41046 19.491 175.071 11.4446 .2583 .87708 .14560 .002 .14555 .90 41047 17.250 174.282 10.3730 .2585 .68311 .14134 .002 .14160 .49 41048 17.250 174.741 10.3473 .2585 .77766 .14190 .002 .14207 .72 41049 17.250 175.169 10.3235 .2585 .87878 .14211 .002 .14200 .73

41050 15.124 174.340 9.2612 .2586 .68355 .13862 .001 .13904 .73

41051 15.124 174.734 9.2412 .2586 .77798 .13837 .002 .13854 .41 41052 15.125 175.289 9.2134 .2587 .87905 .13934 .002 .13916 .90

41053 13.057 174.471 8.1318 .2589 .68424 .13550 .002 .13584 .57 41054 13.057 174.990 8.1083 .2589 .77891 .13573 .002 .13574 .54 41055 13.057 175.531 8.0841 .2590 .87995 .13593 .002 .13559 .48 41056 11.071 174.641 7.0040 .2591 .68466 .13294 .002 .13317 .70

41057 11.071 175.073 6.9870 .2591 .77931 .13337 .002 .13332 .84 41058 11.071 174.112 7.0249 .2591 .59593 .13273 .003 .13329 .75 41059 9.033 174.295 5.8226 .2593 .59609 .12962 .002 .13007 .49

41060 9.033 174.732 5.8082 . 2593 .68459 .13012 .002 .13029 .68 41061 9.033 175.250 5.7911 .2593 .77948 .13048 .002 .13032 .74 41062 6.920 174.443 4.5327 .2594 .59629 .12708 .002 .12743 .71 41063 6.920 174.970 4.5188 .2595 .68480 .12694 .002 .12696 .36

41064 6.920 175.500 4.5052 .2595 .77970 .12755 .002 .12723 .60 41065 4.882 173.985 3.2570 .2596 .51413 .12382 .003 ..12446 .53 41066 4.882 174.558 3.2458 .2596 .59652 .12420 .002 .12448 .56

41067 4.882 175.129 3.2352 .2596 .68526 .12467 .002 .12459 .67

41068 2.741 174.413 1.8533 .2598 .51455 .12061 .002 .12098 .03 41069 2.740 174.834 1.8486 .2598 .59699 .12147 .002 .12157 .52 41070 2.739 175.487 1.8410 .2598 .68593 .12162 .002 .12131 .32 41071 1.399 174.073 .9572 .2599 .43832 .11843 .007 .11901 -.16

41072 1.399 174.548 .9542 .2600 .51447 .11870 .004 .11898 -.18

41073 1.398 175.156 .9504 .2600 .59707 .11947 .004 .11937 .16

7
Experimental Ad J. Thermal Conductivity

Thermal Norn. Temperature deviation

Run Pt. Pressure Temperature Dens 1 1 y pare Power Conduc 1 1 v 1 ty STAT 150.0 K exp. -calc.

MP 0 K mol /l fraction W/m W/m.K W/m.K percent

42001 69.746 147.874 30.2675 . 2500 .81224 .21817 .002 .21982 .16 42002 69.744 148.179 30.2331 .2501 .90545 .21814 .002 .21955 .15 42003 69.744 148.277 30.2223 .2502 1.00369 .21846 .001 .21979 .30 42004 64.986 147.912 29.2164 .2506 .81198 .21032 .002 .21191 .10 42005 64.988 148.394 29.1631 .2507 .90561 .21067 .001 .21189 .28 42006 64.990 148.461 29.1560 .2507 1.00371 .21047 .001 .21164 .18 42007 61.347 147.978 28.3618 .2511 .81240 .20484 .002 .20636 .34 42008 61.347 148.216 28.3352 .2512 .90561 .20479 .002 .20613 <31 42009 61.346 148.617 28.2904 .2512 1.00414 .20516 .002 .20620 .49 42012 57.952 148.657 27.4548 .2522 1.00571 .19946 .002 .20046 .44 42016 50.845 148.244 25.6136 .2533 .81363 .18741 .002 .18869 .35 42017 50.848 148.473 25.5891 . 2533 .90710 .18781 .003 .18892 .55 42010 50.051 148.917 25.5407 .2534 1.00615 .18604 .002 .18683 -.41

42019 47.463 148.370 24,6207 .2538 .81368 .18168 .002 .18285 .34 42020 47.466 148.628 24.5933 .2538 .90713 . 18024 .002 .18123 -.46

42021 47.469 148.930 24.5607 .2539 1.00596 .18277 .002 .18354 .90 42022 43.992 148.424 23.5471 .2543 .81462 .17637 .002 .17749 .68 42023 43.995 148.759 23.5115 .2544 .90871 .17447 .003 .17535 -.42

42024 43.997 149.173 23.4667 .2545 1.00809 .17676 .001 .17735 .84 42025 40.499 148.614 22.3797 .2549 .81538 .17035 .002 .17132 .67 42026 40.502 148.903 22.3492 .2549 .90906 .16993 .001 .17070 .39 42027 40.505 149.222 22.3158 .2550 1.00840 . 16981 .001 .17036 .29 42028 36.919 148.585 21.1223 .2555 .81534 .16403 .001 .16501 .61 42029 36.922 148.962 21.0831 .2555 .90931 .16407 .001 .16479 .58 42030 36.925 149.372 21.0405 .2556 1.00892 .16389 .001 .16433 .42 42031 33.442 148.807 19.7814 . 2560 .81571 .15788 .001 .15870 .53 42032 33.445 149.219 19.7396 .2561 .90994 .15802 .001 .15656 .56 42033 33.447 149.476 19.7137 .2562 1.00891 .15714 .004 .15750 -.04

42037 29.856 149.029 18.2912 .2746 .81697 .15317 .002 .15383 1.10

42038 29.857 148.672 18.3276 .2746 .72797 .15181 .002 .15272 .28 42039 29.858 149.394 18.2551 .2747 .91095 .15374 .002 .15415 1.40

42040 26.414 148.766 16.7905 .2752 .72754 .14673 .002 .14756 .92 42041 26.414 149.099 16.7586 .2753 .81630 .14613 .002 .14674 .45 42042 26.415 149.490 16.7206 .27*3 .91059 .14592 .002 .14626 .22 42043 22.870 148.853 15.0746 .2758 .72882 .13961 .002 .14038 .31 42044 22.871 149.261 15.0384 .2758 .81817 . 14059 .002 .14108 .90 42045 22.872 149.692 14.9999 .2759 .91300 .14018 .002 .14039 .50 42046 19.390 149.067 13.2308 .2763 .72952 .13417 .002 .13479 .75 42047 19.391 149.542 13.1924 .2763 .01891 .13404 .002 .13434 .51 42048 19.392 148.644 13.2670 .2764 .64532 .13430 .001 .13520 .96 42049 17.298 148.802 12.0776 .2769 .64558 .13039 .002 .13118 .74 42050 17.298 149.190 12.0479 .2769 .72948 .12975 .002 .13028 .12 42051 17.299 149.615 12.0154 .2770 . 81888 .13129 .002 .13154 1.15

42052 15.145 148.865 10.8000 .2774 .64560 .12743 .002 .12818 1.33

42053 15.145 149.333 10.7670 .2775 .72972 .12743 .003 .12787 1.16

42054 15.145 149.666 10.7439 .2775 .81893 .12577 .003 .12599 -.26

42055 13.127 149.082 9.5332 .2730 .64598 .12303 .002 .12363 .52 42056 13.128 149.569 9.5016 .2780 .73006 .12300 .002 .12327 .29 42057 13.129 149.752 9.4915 .2781 .01894 .12314 .005 .12330 .34 42058 11.131 148.811 8.2510 .2792 .56792 . 11940 .002 .12017 .40 42059 11.131 149.184 8.2302 .2793 .64687 .12043 .002 .12096 1.09

42060 11.131 149.609 8.2067 .2794 .73122 .12026 .002 .12051 .77 42061 9.048 140.907 6.8295 .2798 .56830 .11593 .003 .11664 .37 42062 9.049 149.358 6.0087 .2799 . 64732 .11634 .002 .11676 .51 42063 9.049 149.754 6.7905 .2799 .73159 .11840 .010 .11856 2.05

42064 6.036 148.622 5.2673 .2803 .49489 .11272 .003 .11361 .87 42066 6.836 149.633 5.2307 .2804 .64795 . 11276 .003 .11300 .40 42067 4.815 148.736 3.7663 .2809 .49519 .10847 .002 .10929 -.10

42068 4.814 149.215 3.7537 .2809 .56918 .10899 .002 .10950 .12 42069 4.814 149.702 3.7410 .2810 .64836 .10930 .005 .10949 .14 42070 2.794 148.610 2.2198 .2814 .42708 .10570 .003 .10660 .33 42071 2.793 149.078 2.2121 .2814 .49574 .10555 .002 .10614 -.08

42072 2.793 149.641 2.2034 .2815 .56993 .10583 .002 .10606 -.15

Exper 1 mental Ad J. Thermal Conductivity

Thermal Norn. Temperature dev 1 at 1 on Run Pt

.

Pressure T emperature Dens 1 ty para Power Conduct 1 v 1 ty STAT 125.0 K exp. -cal c. “Pa K mo 1 /L f ract Ion W/m W/m.K W/m.K percent

43001 67.856 124.136 32.7359 .2501 .89157 .21885 .001 .21957 .23 43002 67.850 124.499 32.6876 .2502 .97971 .21829 .001 .21871 .02 43003 67.845 124.771 32.6509 .2504 1.07174 .21821 .001 .21840 .02 43004 61.906 124.286 31.3874 . 2514 .8Q144 .20791 .002 .20849 .10 43005 61.9C9 124.453 31.3660 .2516 .97894 .20765 .001 .20810 -.01

43006 61.911 124.884 31.3093 .2517 1.07147 .20846 .001 .20855 .42 43007 56.209 124.326 29.9935 . 2529 .89167 .19718 .002 .19772 -.09

43008 56.214 124.668 29.9488 .2531 .97980 .19773 .001 .19800 .21 43009 56.219 124.117 30.0242 .2532 .80756 .19701 .001 .19772 -.21

43010 51.045 124.491 28.5946 .2544 .89323 .18792 .001 .18832 .07

8
*3011 51.0*6 12*. 772 28.5568 .25*6 .981** .1877* .001 .18792 -.01

*3012 51.0*8 12*. 058 28.65*0 .25*8 .80869 .18779 .002 .18853 -.03

*3013 *6. *12 12*. 292 27.2721 .2565 .8108* .17856 .002 .17911 -.29

*301* *6 . * 1* 12*. 659 27.222* .2567 .89538 .180*2 .002 .18068 .76 *3015 *6. *15 12*. 975 27.1798 .2569 .98378 .13002 .002 .1800* .55 *3016 *2.165 12*. *19 25.9038 .2582 .81130 .17013 .001 .17057 -.*5

*3017 *2.168 12*. 802 25.8525 .2583 .89590 .17072 .001 .17087 -.10

*3016 *2.171 125.090 25.81*1 .258* .98*21 .17118 .001 .17111 .17 *3019 38.30* 12*. 660 2*. 5313 .2595 .81186 .16*51 .001 .16*76 .71 *3020 38.309 12*. 875 2*. 5035 .2596 .89589 .16*17 .001 .16*26 .50

*3021 38.312 125.300 2*.**6* .2597 .98*76 .16386 .001 .1636* .31 *3022 38.31* 12*. 3*0 2*. 5788 .2598 .73091 .163*2 .001 .16391 .03 *3023 3*. 523 1 2* . ** 8 23.1259 .2609 .731*7 . 15597 .001 .15638 .12 *302* 3*. 527 12*. 696 23.0936 .2609 .81181 .15686 .001 .15708 .67 *3025 3*. 529 125.060 23.0*51 .2610 .89658 .15650 .001 .156*6 .*3 *3026 31.151 12*. 262 21.7525 .2620 .65626 . 1*86* .002 .1*918 -.19

*3027 31.155 12*. 53* 21.7170 .2621 .73217 .1*939 .001 .1*973 .29 *3026 31.157 12*. 855 21.67*7 .2622 .81271 .15011 .002 .15022 .75 *3029 28.273 12*. 37* 20. *390 .2632 .65666 .1*3** .002 .1*389 .31 *3030 28.275 12*. 719 20.39*3 .2633 .73280 .1**29 .002 .1***9 .86 *3031 28.277 125.103 20. 3**6 .263* .81371 .1**31 .001 .1**2* .8* *3032 25.33* 12*. 602 18.9707 .2957 .65879 .13813 .002 .138*2 .25 *3033 25.33* 12*. 918 18.9298 . 2958 .73*63 .13867 .002 .13873 .60 *303* 25.33* 125.3*6 18.87*6 .2959 .815*7 .13886 .001 .13861 .67 *3035 22.92* 12*. 735 17.678* .2970 .65829 .13355 .002 .1337* .61 *3036 22.925 125.115 17.6313 .2971 .73*83 .13365 .002 .13357 .61 *3037 22.926 125.521 17.5812 .2971 .81587 .13272 .002 .1323* -.16

*3038 20.560 12*. *69 16.3663 .2983 .58631 .12836 .002 .1287* .55 *3039 20.561 12*. 816 16.3250 .2983 .658*0 .1273* .002 .127*7 -.33

*30*0 20.563 125.203 16.2793 .298* .73*89 .12658 .002 .126*3 -1.02

*30*1 18.328 12*. 635 1* . 9826 .2995 .58678 .12289 .002 .12315 -.05

*30*2 18.329 12*. 9** 1*.9*76 .2996 .6588* .12285 .002 .12289 -.17

*30*3 18.330 125.301 1 * . 90 80 .2997 .73527 .123*7 .002 .12326 .2* *30** 16.199 12*. 351 13.6211 .3007 .5192* .11783 .002 .11829 -.*0

*30*5 16.200 12*. 7*1 13.5798 .3008 .5871* .11887 .002 .11905 .35 *30*6 16.201 125.1*1 13.5378 .3008 .659*7 .11922 .002 .11912 .52 *30*7 1* . 175 12*. 516 12.1915 .3021 .5196* .11*02 .002 .11*36 -.0*

*30*8 1* .176 12*. 865 12.1576 .3022 .58758 .11*62 .002 .11*71 .35 *30*9 1* . 176 125.305 12.11*5 .3023 .66008 .11*83 .002 .11*62 .37 *3050 12. *12 12*. 228 10.9157 .3035 .*5635 .10961 .003 .11015 -.56

*3051 12. *12 12*. 610 10.8815 . 3036 .52006 .1109* .002 .11121 .*9 *3052 12. *12 12*. 988 10.8*79 .3037 .58809 .10996 .002 .10997 -.56

*3053 10.7*1 12*. *18 9.601* .30*8 .*5687 .10713 .003 .1075* .29

*305* 10.7*1 12*. 851 9.5666 .30*8 .52072 .10756 .002 .10766 .*9

*3056 8.986 12*. *79 8.1693 .3059 .*5710 .103*9 .002 .10385 .25

*3057 8.986 12*. 970 8.1357 .3060 .52117 .103*6 .001 .103*8 -.03

*3058 8.987 125. **8 8.1033 .3060 .58959 .1032* .002 .10293 -.*9

*3059 7.335 12*. 702 6.7556 .3070 .*5770 .09979 .002 .10000 -.22

*3060 7.338 125.055 6.738* .3071 .52137 .10025 .001 .10021 .03 *3061 7.338 125.553 6.7101 .3072 .59007 .10087 .001 .100*9 .37 *3062 5.871 125.067 5. *557 . 3081 .*5909 .09703 .002 .09698 -.31

*3063 5.871 125.38* 5. **07 .3082 .52312 .097*3 .002 .09716 -.10

*306* 5.871 12*. *08 5. *860 .3083 .39878 .09676 .002 .09717 -.20

*3065 *.292 12*. 62* *.0*92 .3093 .39931 .09358 .002 .0938* -.*8

*3066 *.292 125.070 *.0336 .309* .*5933 .09*13 .002 .09*08 -.18

*3067 *.292 125.562 *.0170 .309* .52366 .09*7* .001 .09*35 .1* *3068 2.905 12*. 360 2.7701 .3103 .3**02 .09071 .003 .09115 -.59

*3069 2.90* 12*. 821 2.7587 .310* .3998* .09136 .002 .091*8 -.20

*3070 2.90* 125.357 2.7*61 .3105 .*6000 .09170 .002 .091*5 -.21

*3071 1 • *56 12*. 689 1.3950 .311* .3**77 .08800 .002 .08821 -.91

*3072 1 .*55 125.190 1.3886 .3115 .*0070 .08828 .002 .08615 -.98

*3073 1 . *55 125.771 1.3817 .3116 .*6115 .08870 .002 .08817 -.9*

Exper 1 mental AdJ. Thermal C onduct 1 v 1 1

y

Thermal Norn

.

Temper at ur a deviation

Run Pt. Pressure T emperature Dens 1 ty para Power Conductivity STAT 100.0 K exp.-celo.

MPa K mo 1 /L fraction W/m W/m.K W/m.K percent

**001 68.096 98.621 36. *360 .2502 .79090 .22907 .001 .2302* -.11

**002 68.09* 98.718 36. *207 .250* . 8616* .22831 .001 .229*0 -.*2

**003 68.093 98.905 36.3915 .2507 .93621 .22836 .001 .22929 -.35

**00* 61.010 98.776 3*. 9060 .252* .79212 .21527 .001 .21628 -.10

**005 61.017 98.85* 3*. 89*9 .2526 .86271 .21**8 .001 .215*2 -.*6

**006 61.021 99.101 3*. 8568 .2529 .93800 .21*85 .001 .21559 -.22

**007 5*. 798 98.703 33. *539 .25** .79173 .20222 .001 .20326 -.**

**008 5*. 808 99.081 33.39*3 .25*7 .86*** .20255 .001 .20329 -.18

**009 5*. 815 99.2*8 33.3689 .2550 .93905 . 20251 .001 .20311 -.17

**010 *8.88* 98.6*3 31.9132 .2567 .72390 .18952 .001 .19056 -.71

**011 *8.890 98.831 31.8830 .2569 .79283 .19006 .001 .19098 -.*0

**012 *8.895 99.175 31.826* .2571 .865*6 .18976 .001 .190*1 -.*8

**013 *3.759 98.837 30.3791 .2600 .72516 .17881 .002 .17970 -.59

**01* *3.763 99.183 30.3206 .2603 .79538 .17952 .001 .18015 -.11

**015 *3.765 99.281 30.30*6 .2605 .866*2 .17826 .001 .17881 -.80

**016 39.158 98.785 28.88*0 .2621 .66062 . 1680* .002 .16895 -.98

**017 39.162 99.006 28.8*6* .2623 .72625 .16890 .001 .16965 -.42

9
4*018 39.165 99.290 28.7973 .2625 .79605 .16869 .001 .16922 -.49

44019 35.033 98.870 27.3622 .2641 .66213 .15962 .001 .16045 -.35

44020 35.036 99.114 27.3193 .2643 .72840 .15932 .001 .15997 -.49

44021 35.039 99.542 27.2435 .2646 .79939 .15978 .001 .16012 -.12

44022 31.342 99.101 25.8130 .2665 .66333 .15113 .001 .15178 -.14

44023 31.344 99.339 25.7706 .2667 .72957 .15073 .001 .15121 -.37

44024 31 .346 99.737 25.6987 .2669 .80017 .15148 .001 .15167 .20 44025 28.088 99.236 24.3058 .2687 .66426 .14270 .001 .14324 -.44

44026 28.091 99.522 24.2545 .2689 .73082 .14262 .001 .14296 -.45

44027 28.094 99.808 24.2034 .2691 .80095 .14264 .001 .14278 -.39

44028 24.915 99.126 22.7098 .2705 .60178 .13453 .001 . 13514 -.57

44029 24.917 99.333 22.6728 .2707 .66495 .13551 .002 .13597 .18 44030 24.919 99.743 22.5982 .2709 .73228 .13548 .001 .13566 .21 44031 22.369 99.320 21.2305 .2723 .60287 .12883 .001 .12929 .16 44032 22.370 99.606 21.1787 .2725 .66641 .12847 .001 .12874 -.10

44033 22.371 99.885 21.1285 .2727 .73307 .12884 .002 .12892 .21 44034 19.941 99.521 19.6723 .3167 .60468 .12298 .001 .12331 .14 44035 19.941 100.065 19.5745 .3169 .66978 .12327 .001 .12322 .39 44036 19.942 99.152 19.7395 .3172 .54390 .12212 .002 .12270 -.59

44037 17.807 99.310 18.2366 .3183 .54444 .11702 .001 .11748 .00 44038 17.807 99.620 18.1823 .3165 .60488 .11683 .002 .11708 -.16

44039 17.808 100.051 18.1074 .3187 .66945 .11784 .002 .11780 .69 44043 13.722 99.281 15.0037 .3221 .48895 .10509 .002 .10555 -.58

44044 13.722 99.583 14.9557 .3223 .54650 .10577 .002 .10604 .03 44045 13.722 99.889 14.9072 .3226 .60714 .10588 .002 .10595 .09 44046 12.338 99.026 13.8070 .3240 .43541 .10130 .001 .10191 -.48

44047 12.338 99.403 13.7499 .3242 .48950 .10156 .002 .10193 -.29

44048 12.338 99.797 13.6910 .3244 .54727 .10160 .002 .10173 -.32

44049 10.558 99.186 12.0813 .3257 .43610 .09608 .002 .09658 -.74

44050 10.558 99.533 12.0342 .3259 .49014 .09675 .002 .09704 -.13

44051 10.558 99.980 11.9741 .3260 .54829 .09724 .002 .09725 .26 44053 9.258 99.327 10.7436 . 3282 .43692 .09297 .002 .09339 -.23

44054 9.258 99.744 10.6927 .3284 .49129 .09324 .002 .09340 -.07

44055 7.582 99.265 8.9573 .3296 .38685 .08817 .002 .08863 -.32

44056 7.582 99.720 8.9109 .3298 .43840 .08834 .002 .08851 -.32

44057 7.582 100.090 8.8732 .3301 .49289 .08864 .002 .08856 -.14

44058 6.374 99.118 7.6189 .3313 .33958 .08469 .002 .08525 -.42

44059 6.374 99.445 7.5905 .3314 .38735 .08499 .002 .08534 -.23

44060 6.374 99.754 7.5636 .3316 .43842 .08526 .002 .08542 -.07

44061 5.019 99.173 6.0474 .3328 .33983 .08085 .001 .08138 -.65

44062 5.019 99.671 6.0131 .3330 .38819 .08131 .001 .08152 -.39

44063 5.019 100.034 5.9884 .3332 .43950 .08156 .001 .08154 -.30

44064 3.782 98.967 4.5909 .3344 .29593 .07733 .003 .07800 -.88

44065 3.782 99.496 4.5637 .3345 .34119 .07780 .002 .07813 -.64

44066 3.782 99.835 4.5465 .3347 .38924 .07805 .002 .07816 -.56

44067 2.525 99.318 3.0616 .3359 .29702 .07459 .002 .07504 -.60

44068 2.524 99.786 3.0456 .3361 .34213 .07470 .002 .07484 -.82

44069 2.524 100.139 3.0340 .3363 .39040 .07493 .002 .07483 -.81

44070 1.160 99.649 1.4025 .3377 .29796 .07098 .002 .07121 -1.40

44071 1.160 99.141 1.4095 .3377 .25585 .07043 .002 .07100 -1.73

44072 1.159 100.092 1.3947 .3380 .34325 .07145 .002 .07138 -1.14

Exper 1 mental Ad J. Therma

1

C onduct 1 v 1 ty Thermal Nom. Temper at ure deviation

Run Pt. Pressure T emperature Density para Power Conductl vl ty STAT 78.0 K exp. -calc.

MPa K mol /L tract Ion W/m W/m.K W/m.K percen

45001 67.360 77.293 39.7938 .2502 .65559 .24717 .002 .24781 1.11

45002 67.359 77.431 39.7700 .2505 .71036 .24705 .002 .24757 1.11

45003 67.359 77.443 39.7679 .2508 .76588 .24612 .002 .24663 .75 45004 59.513 77.093 38.2826 .2514 .65405 .22929 .002 .23009 .29 45005 59.515 77.214 38.2614 .2520 .70822 .22812 .001 .22881 -.18

45006 59.517 77.483 38.2129 .2525 .76641 .22826 .001 .22871 -.01

45007 52.263 77.436 36.6092 .2543 .65768 .21474 .001 .21522 .86 45008 52.273 77.477 36.6036 .2546 .71128 .21353 .001 .21397 .30 45009 52.279 77.712 36.5604 .2549 .76945 .21343 .001 .21367 .35 45010 46.117 77.503 35.0514 .2571 .65804 .19966 .001 .20007 .25 45011 46.125 77.616 35.0311 .2574 .71289 .19896 .001 .19928 -.06

45012 46.134 77.802 34.9963 .2576 .77051 .19891 .001 .19907 -.01

45013 40.443 77.497 33.4339 .2596 .65817 .18500 .001 .18540 -.47

45014 40.449 77.846 33.3629 .2598 .71516 .18463 .001 .18475 -.52

45015 40.456 77.973 33.3383 .2601 .77253 . 18455 .001 .18457 -.51

45016 35.433 77.707 31.7536 .2642 .66138 .17242 .001 .17265 -.52

45017 35.437 77.914 31.7093 .2646 .71770 .17440 .001 .17447 .71 45018 35.440 78.068 31.6765 .2649 .77546 .17209 .001 .17204 -.55

45019 30.515 77.834 29.8626 .2668 .66270 .15902 .001 .15915 -.80

45020 30.522 78.114 29.8007 .2634 .71909 .15927 .001 .15918 -.50

45021 30.529 77.609 29.9205 .2638 .60922 .15874 .002 .15904 -1.10

45022 27.438 77.836 28.5242 .2698 .61252 .15084 .001 .15096 -.58

45023 27.443 78.279 28.4207 .2701 .66917 .15225 .001 .15204 .55 45024 27.446 78.243 28.4307 .2704 .72336 .15042 .001 .15024 -.68

45025 23.780 77.777 26.7173 .2726 .56042 .13996 .002 .14012 -.73

45026 23.785 78.067 26.6471 .2729 .61289 .14031 .002 .14026 -.35

45027 23.78P 78.288 26.5937 .2732 .66761 .14033 .002 .14012 -.24

45028 20.996 77.722 25.1239 .2751 .51255 .13125 .002 .13145 -.81

10
*5029 21.000 77.9*7 25.0679 .275* .5619* .13170 .002 .13174 -.37

*5030 21.003 78.179 25.0099 .2757 .61389 .13171 .002 .13158 -.26

*5031 18.653 77. ei 9 23.5500 .2775 .51328 .12328 .002 .12340 -1.03

*5032 18.656 76.033 23. *962 .2778 .56256 .12371 .002 .12369 -.59

*5033 18.659 78.365 23. *107 .2781 .61561 .12363 .002 .12338 -.51

*503* 16.632 77.619 22.0876 . 2829 .46700 .11620 .002 .11646 -1.32

*5035 16.633 77.976 21.9925 .2956 .51539 .11731 .002 .11733 -.28

*5036 16.63* 78.280 21.9118 .283* . 56560 .11720 .002 .11701 -.19

*5037 l *.5 e 9 77.825 2 C .2865 .2856 .46853 .10950 .002 .10961 -.80

*5038 1* . 591 78.123 20.2088 .2859 .51652 .10993 .002 .10985 -.30

*5039 1 * . 5 93 73. *72 20.117* .2861 .56716 .11041 .002 .11011 .25 *50*0 12.981 77.733 13.7561 . 2 eeo .42*58 .10444 .002 .10461 -.08

*50*1 12.983 77.961 18.6978 .2883 .4697* .10420 .002 .10422 -.24

*50*2 12.986 78.380 18.5901 .2 e 87 .51856 .10462 .002 .10438 .28 *50*3 12.775 78.053 18. *589 .332* .42639 .10*62 .002 .10459 .66 *50** 12.77* 78.263 18. *031 . 3326 .47150 .10*57 .002 .10*40 .69 *50*5 12.77* 78. *82 18.3*57 .3328 .51690 .10483 .003 .10452 1.00

*50*6 11.967 77.733 17.6811 .33*1 .38285 .10143 .003 .10160 .44 *50*7 11.967 78.078 17.5912 .33*3 .42630 .10107 .002 .10102 .18 *50*8 11.967 78.263 17.5*36 .3346 .47116 .10092 .002 .10075 .07

*50*9 10.990 77.8*6 16.5*10 .3363 .38351 .09679 .002 .09689 -.46

*5050 10.991 78.020 16. *979 .3366 .42623 .09720 .003 .09719 -.00

*5051 10.992 78.35* 16. *15* .3368 .47220 .09731 .003 .09759 .68 *5052 10.220 77.788 15.62*0 .3381 .38337 .09385 .002 .09398 -.44

*5053 10.220 78.085 15.5522 .3383 .42677 .09403 .002 .09398 -.20

*505* 10.221 78.611 15.426* .3385 .*73 e 5 .09445 .003 .09407 .33 *5055 9.3*0 77.9** 1* . *63 5 .3399 .38421 .09048 .003 .09051 -.31

*5056 9.3*1 78.303 14.3819 .3401 .42797 .09132 .003 .09113 .65 *5057 9.3*2 78.560 14.32*1 .3*03 .47357 .09072 .003 .09038 .01 *5058 8.51* 78.122 13.3116 .3*16 .38512 . 08723 .003 .08721 -.15

*5059 8.515 78.397 13.2529 .3*18 .42875 .08756 .003 .08732 .18 *5060 8.515 78.722 13.18*1 .3*20 .47478 .08795 .003 .08751 .63 *5061 7.532 77.983 11.9*83 .3**5 .34538 .08321 .002 .08322 -.17

*5062 7.532 78.2*7 11.8958 .3**7 .38624 .08366 .003 .08351 .35 *5063 7.533 78.708 11.8060 .3**9 .43080 .08429 .003 .08385 1.07

*506* 6.335 78.221 10.1123 .3*64 .3*647 .07857 .003 .07843 .31 *5065 6.335 78.55* 10.0567 . 3466 .38785 .07895 .003 .07860 .72 *5066 6.336 77.820 10.1819 .3469 .30728 .07838 .003 .07849 .14 *5067 5.308 78.031 8.5370 .3484 .30850 .07393 .003 .07391 -.04

*5068 5.309 78.368 8.490* .3*86 .3*743 .07427 .003 .07403 .29 *5069 5.309 78.699 8. 4**3 .3*88 .36894 .07458 .003 .07413 .58 *5070 *.027 78.055 6.4697 .3502 .27352 .06887 .002 .06883 .19 *5071 *.027 78. *23 6.4315 .350* .31022 .06915 .003 .06888 .39 *5072 *.027 78.797 6.3931 .3506 .34961 .07004 .003 .06952 1.45

*5073 3.177 77.793 5.1030 .3520 .23961 .06489 .002 .06503 -.70

*507* 3.177 78.150 5.07*5 .3522 .27398 .06562 .002 .06552 .16 *5075 3.177 78.573 5.0*12 .3524 .31109 .06599 .002 .06562 .42 *5076 2.028 78.170 3.2066 .3540 .24106 .06140 .002 .06129 -.07

*5077 2.028 78.5*8 3.1888 . 3542 .27570 .06160 .002 .06124 -.09

*5078 2.028 77.816 3.2228 .35*4 .20896 .06118 .003 .06130 -.11

*5079 1.062 78.135 1.6606 .3562 .21002 .05770 .002 .05761 -1.03

*5080 1.062 78.536 1.651* .3563 .24240 .05825 .002 .05790 -.50

*5081 1.062 78.968 1.6*17 .356* .277*7 .05851 .002 .05787 -.51

Exper 1 mental AdJ. Thermal C onduct 1 v 1 ty

Thermal Norn. Temper atur a deviation

un Pt

.

Pressure T enper ature Dens 1 ty para Power Conductivity STAT 225.0 K exp. -e ale. MPa K mo 1 /L fraction w / V/m.K W/m.K pa rear* 50001 65.283 22*. *06 22.6231 .2500 .48910 .22233 .003 .22270 .16 50002 65.282 225.0*0 22.5801 .2500 .68162 .22212 .002 .22209 .02 50003 65.277 225.709 22.53*4 .2500 .90626 .22195 .001 .22150 -.13

5000* 65. 278 226. *80 22.4830 .2500 1.16370 . 22253 .001 .22160 .04 50005 62.011 22*. 969 21.8632 .2500 .68138 .21770 .002 .21772 -.16

50006 62.011 225.398 21.8348 .2500 .78944 .21828 .002 .21803 .05 50007 62.010 226.093 21.7838 .2500 1.03025 . 21768 .001 .21700 -.31

50008 62.011 226.519 21.7610 .2500 1.16288 .21833 .001 .21738 -.06

50009 5 e .5*5 225.027 21.0648 .2500 .6eoe5 .21347 .002 .21345 -.17

50010 58.5*6 225.335 21.04*8 .2500 .78939 .21363 .002 .21342 -.14

50011 58.5*5 226.161 20.9909 .2500 1.03004 .21379 .001 .21307 -.17

50012 58.5*5 226.522 20.9674 .2500 1.16261 .21415 .001 .21321 -.05

50013 55.131 225.051 20.2*79 .2500 .68065 .209*1 .002 .20938 -.11

5001* 55.131 225.3*3 20.2291 . 2500 . 7 8 8 e 6 . 20975 .002 .20954 -.01

50015 55.130 226.1*1 2 C .1780 .2500 1.02962 .20942 .001 .20872 -.28

50016 55.130 226.596 20.1489 .2500 1.16216 .20974 .001 .20876 -.19

50017 51.503 225.127 19.3387 .2500 .68053 .20478 .002 .20470 -.25

50018 51.503 225. *19 19. 3203 .2500 .78887 .20481 .002 .20455 -.28

50019 51.503 226.218 19.2705 . 2500 1.02982 .20511 .002 .20437 -.26

50020 51.50* 226.635 19.2*46 .2500 1.16254 .20594 .001 .20494 .08 50021 *6.012 225.093 18.4307 .2500 .68078 . 20105 .002 .20099 -.01

50022 *8.012 225.529 18.4040 .2500 .78881 .20087 .002 .20055 -.17

50023 *8.011 226.352 18.3536 .2500 1.02983 .20120 .002 .20038 -.14

5002* *8.012 226.82* 18.3250 .2500 1.16212 .20132 .001 .20022 -.16

50025 **.613 225.22* 17.4960 .2500 .68087 .19734 .002 .19721 .17

50026 **.612 225.56* 17.4756 .2500 .78919 .19691 .002 .19657 -.11

1

1
50027 44.611 226.418 17.4246 .2500 1.03017 .19740 .001 .19655 -.01

50028 44.611 226.901 17.3961 .2500 1.16261 .19758 .001 .19644 -.01

5 002 9 41.030 225.294 16.4687 .2500 .68081 .19321 .002 .19303 .24 50030 41.031 225.672 16.4470 .2500 .78914 .19292 .002 .19252 .02 50031 41.031 226.629 16.3924 .2500 1.02971 .19313 .001 .19216 -.05

50032 41.032 227.009 16.3710 .2500 1.16262 .19324 .001 .19204 -.07

50033 37.511 225.394 15.4083 .2500 .68071 . 18842 .002 .18819 -.09

50034 37.512 225.703 15.3907 .2500 .78927 .18876 .002 .18834 .02 50035 37.512 226.669 15.3377 .2500 1.03010 .18885 .001 .18786 -.12

50036 37.512 227.099 15.3143 .2500 1.16273 .18923 .001 .18799 -.01

50037 34.124 225.484 19.3365 .2500 .68061 .18418 .002 .18389 -.25

50038 34.124 224.937 14.3652 .2500 .58040 .18403 .002 .18407 -.21

50039 34.124 226. 2^9 14.2946 .2500 .90542 .18497 .002 .18422 .01 50040 34.124 226.703 14.2724 .2500 1.03010 .18526 .001 .18426 .08 50041 30.527 225.093 13.1650 .2500 .58067 .18017 .003 .18012 -.05

50042 30.526 225.453 13.1468 .2500 .68068 .18052 .002 .18026 .06 50043 30.527 226.365 13.1018 .2500 .90543 .18062 .001 .17982 -.09

50C44 30.527 226.871 13.0771 . 2500 1.02995 .18122 .001 .18013 .12 50045 26.973 225.120 11.9219 .2500 .58053 .17628 .002 .17621 .07 50046 26.973 225.528 11.9030 .2500 .68059 .17621 .002 .17590 -.07

50047 26.973 226.416 11.8622 .2500 .90552 .17675 .001 .17593 .02 50048 26.973 226.973 11.8368 .2500 1.03002 .17691 .001 .17576 -.03

50049 23.907 225.201 10.7929 .2500 .58043 .17226 .002 .17214 -.24

50050 23.907 225.602 10.7755 .2500 .68076 .17277 .002 .17242 -.05

50051 23.907 226.471 10.7389 .2500 .90574 .17324 .002 .17239 -.00

50052 23.907 227.050 10.7143 .2500 1.03022 .17340 .001 .17221 -.06

50053 21.069 224.922 9.7146 .2500 .48835 .15888 .003 .16892 -.26

50054 21.068 225.266 9.7008 .2500 .58053 .16939 .002 .16924 -.06

50055 21.068 226.169 9.6654 .2500 .78944 .16990 .002 .16923 -.00

50056 21.067 226.639 0.6471 .2500 .90587 .17017 .001 .16923 .03 50057 18.640 224.632 8.7540 .2500 .40474 .16670 .004 .16691 .14 50058 18.641 225.029 8.7399 .2500 .48892 .16758 .003 .16756 .55 50059 18.641 225.797 8.7126 .2500 .68159 .16773 .002 .16727 .43 50060 18.640 226.240 8.6966 .2500 .79018 .16732 .002 .16661 .05 50061 16.404 224.567 7.8290 .2500 .40372 .16424 .003 .16449 .18 50062 16.403 224.976 7.8153 .2500 .48778 .16458 .003 .16459 .26 50063 16.403 225.826 7.7878 .2500 .68015 .16488 .002 .16441 .20 50064 16.404 226.249 7.7744 .2500 .78850 .16436 .002 .16415 .06 50065 14.229 224.508 6.8981 . 2500 .40439 .16101 .004 .16129 -.32

50066 14.228 224.867 6.8874 .2500 .48878 .16211 .003 .16219 .25 50067 14.228 225.835 6.8593 .2500 .68147 .16248 .002 .16200 .18 50068 14.228 226.343 6.8449 .2500 .79019 .16261 .002 .16184 .11 50069 12.350 224.588 6.0651 .2500 .40429 .15974 .004 .15997 .14 50070 12.350 224.187 6.0754 .2500 .32798 .15946 .005 .15992 .09 50071 12.350 225.330 6.0460 .2500 .58097 .16011 .002 .15992 .13 50072 12.349 225.790 6.0339 .2500 .68139 .16071 .002 .16026 .36 50073 10.330 224.211 5.1543 .2500 .32798 .15756 .006 .15801 .26 50074 10.330 224.544 5.1468 .2500 .40421 .15745 .004 .15771 .08 50075 10.329 225.389 5.1280 .2500 .58080 .15785 .002 .15763 .06 50076 10.329 225.927 5.1160 .2500 .68119 .15806 .002 .15753 .01 50077 8.287 224.279 4.1935 .2500 .32790 .15431 .005 .15472 -.45

50078 8.286 224.626 4.1870 .2500 .40411 .15546 .004 .15567 .17 50079 8.286 225.577 4.1697 .2500 .58072 .15560 .003 .15527 -.06

50080 8.285 226.039 4.1610 .2500 .68118 .15585 .002 .15526 -.06

50081 6.214 224.310 3.1905 .2500 .32782 .15299 .005 .15338 .09 50082 6.213 224.667 3.1850 .2 500 .40408 .15291 .004 .15310 -.08

50083 6.213 225.569 3.1723 .2500 .58060 .15322 .002 .15290 -.20

50084 6.213 226.196 3.1635 .2500 .68090 .15361 .002 .15293 -.16

50086 4.288 224.928 2.2254 .2500 .40516 .15079 .004 .15083 -.26

50087 4.288 225.780 2.2169 . 2500 .58239 .15118 .003 .15074 -.31

50088 4.288 226.328 2.2116 .2500 .68317 .15165 .002 .15090 -.19

50089 2.236 224.510 1.1791 .2500 .32879 .14884 .007 .14912 .00 50090 2.235 224.950 1.1764 .2500 .40530 .14885 .005 .14888 -.15

50091 2.235 225.455 1.1736 .2500 .48977 .14949 .004 .14923 .09 50092 2.234 225.974 1.1707 .2500 .58250 .14956 .003 .14901 -.06

50093 .877 224.608 .4670 .2500 .32877 .14856 .017 .14878 .72 50094 .8 77 224.132 .4678 .2500 .26030 .14704 .018 .14753 -.13

50095 .877 225.034 .4657 .2500 .40508 .14779 .013 .14777 .04 50096 .876 225.551 .4645 .2500 .48972 .14814 .010 .14783 .08

Experl mental AdJ. Therma

1

Conduct 1 v Ity

Thermal Norn. Temperature deviation

Sun Pt. Pressure T emperature Dens 1 ty para Power Conductl vl ty STAT 275.0 K exp.-calc.

MPa K mol /L Tract Ion W /» W/m.K W/m.K percent

51001 67.487 273.381 20.1964 .2500 .49930 .23821 .003 .23910 .19 51002 67.482 274.076 20.1595 .2500 .71668 .23757 .002 .23808 -.15

51003 67.477 274.702 20.1264 .2500 .97351 .23763 .002 .23779 -.20

51004 67.479 275.605 20.0807 .2500 1.26947 .23812 .001 .23779 -.10

51005 63.698 273.526 19.4578 .2500 .60252 .23348 .003 .23428 -.23

51006 63.097 273.884 19.4395 .2500 .71602 .23417 .003 .23478 .02 51007 63.894 274.680 19.3986 .2500 .97246 .23432 .002 .23449 -.01

51008 63.891 275.532 19.3553 .2500 1.26838 .23461 .001 .23432 .00 51009 60.469 273.439 18.7390 .2500 .60324 .23001 .003 .23066 -.18

51010 60.467 273.867 18.7174 .2500 .71717 .23034 .002 .23095 -.09

12
MOll 60.466 274.661 . 18.6780 .2500 .97442 .23088 .002 .23106 .04 51012 60.466 275.568 18 . 6333’ .2500 1.27095 .23084 .001 .23053 -.09

51013 57.015 273 . 47 ? 17.9834 .2500 .60337 .22699 .003 .22781 .07 51014 57.012 273.823 17.9656 .2500 .71711 .22661 .002 .22724 -.15

51015 57.011 274.654 17.9251 .2500 .97384 .22670 .002 .22689 -.22

51016 57.010 275.599 17.8795 .2500 1.27030 .22715 .001 .22683 -.16

51017 53.442 273.516 17.1721 .2500 .60329 .22314 .003 .22393 -.01

51018 53.439 273.866 17.1550 .2500 .71707 .22317 .002 .22378 -.05

51019 53.438 274.684 17.1161 .2500 .97371 .22330 .002 .22347 -.11

51020 53.437 275.568 17.0743 .2500 1.27020 .22384 .001 .22354 .00 51021 49.994 273.540 16.3605 .2500 .60374 .21961 .003 .22039 -.02

51022 49.994 273.923 16.3429 .2500 .71774 .22023 .002 .22080 .20 51023 49.994 274.772 16.3041 .2500 .97494 .21982 .002 .21994 -.11

51024 49.994 275.203 16.2845 .2500 1.11830 .22018 .001 .22007 -.01

51025 46.509 273.619 15.5063 .2500 .60374 .21559 .003 .21632 -.25

51026 46.508 273.947 15.4915 .2500 .71749 .21625 .002 .21681 .00 51027 46.507 274.836 15.4521 .2500 .97466 .21625 .002 .21634 -.14

51028 46.506 275.259 15.4332 .2500 1.11823 .21650 .001 .21636 -.09

51029 43.000 273.638 14.6150 .2500 .60362 .21289 .003 .21360 .13 51030 42.999 274.015 14.5986 .2500 .71745 .21272 .002 .21324 -.01

51031 42.999 274.850 14.5631 .2500 .97452 .21285 .002 .21293 -.09

51032 42.998 275.310 14.5435 .2500 1.11802 .21327 .002 .21311 .03 51033 39.533 273.652 13.6988 .2500 .60368 .20900 .002 .20970 -.08

51034 39.533 274.086 13.6811 .2500 .71734 .20893 .002 .20941 -.19

51035 39.532 274.950 13.6458 .2500 .97444 .20970 .001 .20973 .03 51036 39.532 275.386 13.6281 .2500 1.11797 .20995 .001 .20975 .07 51037 36.061 273.285 12.7587 .2500 .49957 .20438 .003 .20527 -.59

51038 36.061 273.676 12.7433 .2500 .60346 .20512 .002 .20581 -.30

51039 36.058 274.517 12.7100 .2500 .84068 .20538 .002 .20563 -.33

51040 36.054 276.016 12.6896 . 2500 .97415 .20611 .001 .20610 -.07

51041 32.664 273.339 11.7829 .2500 .49959 .20155 .003 .20241 -.37

51042 32.662 273.748 11.7676 .2500 .60345 .20228 .003 .20293 -.08

51043 32.661 274.568 11.7374 .2500 .84072 .20243 .002 .20265 -.17

51044 32.660 275.061 11.7190 .2500 .97434 .20302 .001 .20299 .03 51045 29.043 273.390 10.6985 .2500 .49947 .19855 .003 .19938 -.13

51046 29.041 273.767 10.6853 .2500 .60348 .19888 .002 .19951 -.04

51047 29.040 274.620 10.6562 .2500 .84102 .19895 .002 .19914 -.18

51048 29.040 275.151 10.6382 .2500 .97449 .19926 .002 .19918 -.13

51053 22.852 272.990 8.7441 .2500 .40505 .19278 .004 .19380 .00 51054 22.851 273.239 8.7365 .2500 .49928 .19322 .003 .19411 .17 51055 22.851 273.638 8.7251 .2500 .60316 .19340 .002 .19409 .18 51056 22.850 274.023 8.7138 .2500 .71690 .19390 .002 .19440 .35 51057 20.257 272.675 7.8814 .2500 .40469 .19041 .004 .19159 .10 51058 20.257 273.103 7.8701 .2500 .49842 .19062 .004 .19158 .11 51059 20.257 273.545 7.8583 .2500 .60204 .19112 .003 .19186 .27 51060 20.256 273.918 7.8484 .2500 .71572 .19146 .002 .19201 .36 51061 17.954 272.671 7.0835 .2500 .40448 .18772 .005 . 18890 -.20

51062 17.954 273.029 7.0747 .2500 .49836 .18882 .003 .18982 .30 51063 17.953 273.462 7.0642 .2500 .60194 .18852 .003 .18930 .04 51064 17.953 273.978 7.0518 .2500 .71543 .18879 .002 .18931 .06 51065 15.886 272.708 6.3460 .2500 .40580 .18633 .005 .18749 .05 51066 15.886 273.136 6.3366 .2500 .50012 .18649 .003 .18743 .04 51067 15.885 273.559 6.3274 .2500 .60417 .18670 .003 .18743 .05 51068 15.885 274.484 6.3075 .2500 .84191 .18735 .002 .18761 .17 51069 13.633 273.164 5.5129 .2500 .50016 .18439 .003 .18531 -.01

51070 13.632 273.541 5.5054 .2500 .60423 .18455 .003 .18528 -.01

51071 13.631 274.605 5.4850 .2500 .84187 .18486 .002 .18506 -.11

51072 13.631 275.178 5.4740 .2500 .97542 .18550 .002 .18541 .10 51073 11.534 273.181 4.7242 .2500 .50013 .18226 .003 .18317 -.15

51074 11.533 273.659 4.7162 .2500 .60400 .18262 .003 .18329 -.08

51075 11.533 274.157 4.7080 .2500 .71792 .18306 .002 .18348 .04 51076 11.533 274.718 4.6987 .2500 .84157 .18321 .002 .18335 -.02

51077 9.560 273.189 3.9637 .2500 .50009 .18057 .004 .18148 -.13

51078 9.560 273.701 3.9564 .2500 .60401 .18142 .003 .18207 .21 51079 9.559 274.220 3.9490 .2500 .71792 . 18150 .003 .18189 .12 51080 9.558 274.766 3.9411 .2500 .84156 .18158 .002 .18170 .02 51081 7.163 273.344 3.0125 .2500 .49994 .17824 .003 .17907 -.30

51082 7.162 273.759 3.0078 .2500 .60391 .17934 .003 .17996 .20 51083 7.162 274.338 3.0015 .2500 .71776 .17669 .002 .17902 -.32

51084 7.161 274.888 2.9955 .2500 .84148 .17966 .002 .17972 .08 51085 5.095 273.390 2.1703 .2500 .49994 .17699 .004 .17779 -.02

51086 5.095 273.887 2.1663 .2500 .60380 .17710 .003 .17766 -.09

51087 5.094 274.491 2.1615 .2500 .71760 .17706 .003 .17731 -.28

51088 5.094 275.018 2.1572 .2500 .84142 .17773 .002 .17772 -.04

51089 3.102 273.518 1.3375 .2500 .49982 .17516 .006 .17590 -.12

51090 3.102 274.081 1.3347 .2500 .60370 .17571 .005 .17617 .03 51091 3.101 274.653 1.3316 .2500 .71755 .17564 .004 .17581 -.16

51092 3.101 275.261 1.3286 .2500 .84127 .17617 .004 .17604 -.03

51093 1.010 273.647 .4410 .2500 .49967 .17390 .021 .17457 .15 51094 1.009 273.179 .4414 .2500 .40550 .17407 .023 .17498 .38

51095 1.009 274.771 .4387 .2500 .71745 .17398 .018 .17409 -.13

51096 1.008 274.180 .4394 .2500 .60360 .17338 .020 .17379 -.30

13
Run Pt. Pressure Temperature STAT

MPa K

Experl mental

Ther ma

I

Density para Power Conductivity

mol/l fraction W/m W/m.K

AdJ. Thermal Conductivity

Norn. Temperature deviation

294.0 K exp. -calc.

W/m.K percent

48001 68.201 294.472 19.3040 .2500 .54185 .24464 .004 .24439 .02 48002 68.201 295.298 19.2656 .2500 .77786 .24519 .003 .24451 .15 48003 68.203 296.045 19.2316 .2500 1.05639 .24544 .002 .24436 .16 48004 68.202 296.886 19.1925 .2500 1.37762 .24602 .001 .24450 .30 48005 68.206 297.548 19.1629 .2500 1.55348 .24605 .002 .24418 .23 48006 64.894 294.603 18.6473 .2500 .54186 .24138 .004 .24106 .01 48007 64.691 295.289 18.6156 .2500 .77779 .24242 .002 .24175 .36 48008 64.897 296.064 18.5814 . 2500 1.05619 .24191 .002 .24083 .05 48009 64.897 297.042 18.5374 .2500 1.37706 .24242 .001 .24083 .14 48010 61.437 294.345 17.9572 .2500 .43984 .23741 .005 .23723 -.20

48011 61.437 294.964 17.9296 .2500 .65470 .23856 .003 .23806 .20 48012 61.438 295.714 17,8962 .2500 .91194 .23936 .003 .23847 .44 48013 61.437 296.639 17.8552 .2500 1.21172 .23933 .002 .23796 .31 48014 61.437 297.079 17.8357 .2500 1.37783 .23932 .001 .23772 .25 48015 57.806 294.696 17.1793 .2500 .54215 .23509 .004 .23473 .27 48016 57.806 295.456 17.1463 .2500 .77801 .23532 .002 .23457 .27 48017 57.805 296.254 17.1115 .2500 1.05667 .23551 .002 .23435 .24 48018 57.805 297.254 17.0684 .2500 1.37767 .23595 .001 .23427 .29 48019 54.207 294.796 16.3926 .2500 .54221 .23138 .004 .23097 .17 48020 54.208 295.491 16.3634 .2500 .77840 .23193 .002 .23117 .30 48021 54.207 296.244 16.3316 .2500 1.05731 .23217 .002 .23102 .30 48022 54.207 297.325 16.2862 .2500 1.37817 .23243 .002 .23073 .26 48023 50.785 294.727 15.6250 .2500 .54239 .22807 .004 .22770 .17 48024 50.783 295.429 15.5958 .2500 .77851 .22850 .002 .22777 .25 48025 50.783 296.338 15.5586 .2500 1.05724 .22891 .001 .22772 .30 48026 50.782 297.419 15.5144 .2500 1.37822 .22912 .001 .22738 .23 48027 47.398 294.786 14.8331 .2500 .54230 .22505 .004 .22465 .25 48028 47.398 295.528 14.8038 .2500 .77833 .22504 .002 .22427 .13 48029 47.399 296.356 14.7712 .2500 1.05718 .22594 .002 .22475 .40 48030 47.399 297.501 14.7264 .2500 1.37803 .22618 .001 .22441 .33 48031 43.906 294.812 13.9886 .2500 .54226 .22119 .003 .22078 -.00

48032 43.906 295.571 13.9597 .2500 .77824 . 22212 .002 .22133 .29 48033 43.906 296.489 13.9249 .2500 1.05668 .22251 .002 .22126 .32 48034 43.906 297.023 13.9047 .2500 1.21206 .22285 .002 .22133 .39 48035 40.302 295.186 13.0710 .2500 .65502 .21855 .003 .21796 .26 48036 40.302 295.664 13.0537 .2500 .77827 .21925 .002 .21842 .50 48037 40.302 296.556 13.0215 .2500 1.05696 .21925 .002 .21797 .35 48038 40.301 297.094 13.0018 .2500 1.21222 .21957 .001 .21802 .41 48039 36.857 295.251 12.1718 .2500 .65485 .21533 .003 .21471 .24 48040 36.857 295.708 12.1561 .2500 .77812 .21552 .002 .21467 .24 48041 36.856 296.647 12.1237 .2500 1.05668 .21591 .002 .21459 .26 48042 36.856 297.177 12.1055 .2500 1.21200 .21629 .001 .21471 .34 48043 33.618 295.296 11.2955 .2500 .65495 .21217 .002 .21153 .13 48044 33.618 295.772 11.2801 .2500 .77827 .21270 .002 .21182 .30 48045 33.618 296.714 11.2496 .2500 1.05682 .21308 .002 .21174 .30 48046 33.617 297.218 11.2332 .2500 1.21216 .21329 .001 .21170 .31 48047 30.276 295.373 10.3567 .2500 .65484 .20953 .002 .20885 .30 48048 30.275 295.691 10.3470 .2500 .77854 .20980 .002 .20897 .37 48049 30.275 296.806 10.3133 .2500 1.05682 .21025 .001 .20887 .37 48050 30.275 297.397 10.2956 .2500 1.21168 .21026 .001 .20858 .26 48051 27.386 295.390 9.5177 .2500 .65497 .20694 .002 .20626 .29 48052 27.385 295.831 9.5050 .2500 .77880 .20689 .002 .20599 .18 48053 27.384 296.913 9.4743 .2500 1.05746 .20758 .001 .20615 .30 48054 27.384 297.388 9.4610 .2500 1.21311 .20795 .001 .20629 .39 48055 24.579 295.492 8.6737 .2500 .65542 .20435 .002 .20362 .21 48056 24.579 295.922 8.6625 .2500 .77882 .20451 .002 .20357 .20 48057 24.579 296.403 8.6499 .2500 .91298 .20485 .001 .20367 .27 48058 24.578 297.003 8.6341 .2500 1.05756 .20508 .001 .20361 .26 48060 21.923 296.493 7.8285 .2500 .78002 .20257 .002 .20135 .27 48061 21.924 296.958 7.8175 .2500 .91447 .20276 .002 .20132 .26 48062 21.924 297.486 7.8051 .2500 1.05954 .20316 .002 .20146 .35 48063 19.551 296.028 7.0853 .2500 .65611 .20003 .003 .19904 .11 48064 19.550 296.457 7.0759 .2500 .78020 .20024 .002 .19904 .13 48065 19.550 297.042 7.0631 .2500 .91434 .20066 .002 .19918 .21 48066 19.550 297.526 7.0523 .2500 1.05906 .20131 .002 .19959 .43 48067 16.900 296.036 6.2174 .2500 .65637 .19809 .002 .19710 .27 48068 16.900 296.551 6.2074 .2500 .77997 .19788 .002 .19664 .05 48069 16.899 297.049 6.1975 .2500 .91427 .19845 .002 .19697 .23 48070 16.899 297.646 6.1860 .2500 1.05916 .19877 .002 .19700 .26 48071 14.783 295.725 5.5104 .2500 .54335 .19622 .003 .19538 .29 48072 14.783 296.067 5.5043 .2500 .65632 .19625 .002 .19525 .23 48073 14.782 296.652 5.4939 .2500 .77997 .19622 .002 .19494 .08 48074 14.781 297.186 5.4844 .2500 .91412 .19667 .002 .19513 .19 48075 14.781 297.763 5.4744 .2500 1.05912 .19695 .001 .19513 .21 48076 12.314 296.233 4.6482 .2500 .65636 .19424 .002 .19316 .21 48077 12.313 296.732 4.6405 .2500 .77986 .19439 .002 .19307 .18 48078 12.313 297.236 4.6330 .2500 .91416 .19462 .002 .19306 .18 48079 12.313 297.846 4.6238 .2500 1.05935 .19493 .002 .19307 .20 48080 10.243 295.834 3.9183 .2500 .54333 .19186 .003 .19097 -.05

14
*8081 10.2*3 296.296 3.9123 .2500 .65638 .192** .003 .1913* .15 *8082 10.2*2 296.815 3.9055 .2500 .78000 .19270 .002 .1913* .16 *8083 10.2*1 297.373 3.8983 .2500 .91*31 .19302 .002 .19139 .20 *608* 7.8 39 295.895 3.0*05 .2500 .5*336 . 1896* .00* .18873 -.20

*8089 7.839 296.37* 3.0356 .2500 .65630 .19088 .003 .1897* .3* *8086 7.838 296.9*0 3.0298 .2500 .77986 .19075 .002 .18933 .13 *8087 7.837 297. *56 3.02** . 2500 .91*19 .19083 .002 .18916 .05 *8088 5.600 296.029 2.2000 .2500 .5*360 .18816 .003 .18718 -.07

*8089 5.599 296.538 2.1961 .2500 .6567* .188*3 .00* .18721 -.05

*8090 5.599 297.086 2.1918 .2500 .78061 .18913 .002 .18765 .19 *8091 5.598 297.689 2.1872 .2500 .91502 .18939 .002 .18762 .18 *8092 3.196 296.11* 1.273* .2500 .5*390 .18656 .005 .1855* .08 *8093 3.195 296.679 1.2707 .2500 .65685 .18670 .007 .185*1 .01 *809* 3.195 297.2*0 1.2680 .2500 .78037 .1872* .006 .18568 .16 *8099 3.19* 297.80* 1.2655 .2500 .91507 .1875* .005 .18571 .18 *8096 .667 296.172 .2696 .2500 .5*309 .18590 .020 .18*86 .80 *8097 .665 296.673 .268* .2500 .65637 .18588 .013 .18*60 .66 *8098 .66* 297.3*0 .2675 .2500 .78000 .185** .011 .1838* .26 *8099 .66* 297.999 .2668 .2500 .91*33 .18668 .023 .18*76 .75

Exper 1 nental AdJ. Thernal Conduct 1 v 1 ty Ther na

1

Non. Tecperat ur e deviation

Run Pt. Pressure Tenperature Dens 1 ty pare Power Conduct! vl ty ST AT 313.5 K exp ,-c a 1 c

•

MPa K no 1 / L f ract Ion W/n U/n.K W/n.K percent

*9001 67.26* 312.8*6 18.3086 . 2500 .80815 .2*95* .002 .2*987 .15 *9002 67.268 313.710 18.2730 .2500 1.09711 .25007 .002 .2*996 .26

*9003 67.273 31*. 672 18.233* .2500 1 .*3058 .250*1 .002 .2*982 .28 *900* 67.275 315.182 18.212* .2500 1.61350 .25092 .001 .25007 .*2 *9009 63.90* 312.582 17.6685 .2500 .67987 . 2*606 .003 .2*652 .05 *9006 63.905 312.950 17.653* .2500 .80768 .2*65* .002 .2*681 .20 *9007 63.906 313.693 17.6228 .2500 1.09693 .2*711 .002 .2*701 .3* *9008 63.905 31*. 733 17.5798 .2500 1 . *2 97* .2*772 .001 .2*710 .*6 *9009 60.370 312.567 16.9627 .2500 .67977 .2*351 .003 .2*397 .36 *9010 60.370 312.8*0 16.9516 .2500 .80781 .2*353 .002 .2*386 .33 *9011 60.371 313.729 16.9157 .2500 1.09691 .2*387 .002 .2*376 .36 *9012 60. 366 31*. 7*1 16.87*1 .2500 1 . *2986 .2**08 .001 .2*3*6 .32 *9013 56.886 312.61* 16.2*16 .2500 .67957 .239** .002 .23988 .01 *901* 56.866 312.9** 16.2286 .2500 .80757 .23987 .002 .2*01* .1* *9019 56.885 313.819 16.1939 .2500 1.09656 .2*013 .001 .2*002 .15 *9016 56.885 31*. 877 16.1525 .2500 1 . *2 961 .2*12* .001 .2*056 .*5 *9017 53.323 312.635 15. *805 .2500 .67951 .23720 .003 .23762 .** *9018 53.322 313.028 15. *65* .2500 .807** .23692 .002 .23715 .27

*9019 53.322 313.831 15. *3*7 .2500 1.0966* .23739 .001 .23723 .35 *9020 53.322 31*. 898 15.39*2 .2500 1 .*2 9*9 .23795 .002 .23726 .** *9021 *9.701 312.650 1*.6803 .2500 .67939 .2337* .003 .23*15 .37 *9022 *9,702 313.0*7 1* . 6659 . 2500 .807*5 .233*8 .002 .23370 .20

*9023 *9.702 313.961 1*.632* .2500 1.09626 .23*10 .002 .23388 .33 *902* *9.702 31*. 899 1*.5981 .2500 1 .*295* .23*68 .001 .23*00 .*5 *9029 *6.273 312.599 13.8989 .2500 .67962 .23086 .002 .23130 .*7 *9026 *6.272 313.02* 13.8837 . 2500 .80751 .23059 .002 .23082 .29

*9027 *6.271 313.982 13.8*96 .2500 1.09628 .23103 .002 .23080 .3* *9028 *6.27* 315.056 13.8122 .2500 1 . *2 899 .23130 .001 .23055 .29

*9029 *2.7*8 312.756 13.0599 .2500 .67938 .2273* .003 .22770 .29

*9030 *2.751 313.118 13.0*82 .2500 .8073* .22781 .002 .22799 .** *9031 *2.751 31*. 066 13.0161 .2500 1.09622 .22813 .002 .22786 .*3 *9032 *2.751 315.103 12.9811 .2500 l.*29*0 .22826 .001 .227*9 .32 *9033 39.293 312.771 12.2128 .2500 .67915 .22379 .002 .22*1* .06 *903* 39.293 313.167 12.1999 .2500 .80723 .22*6* .002 .22*80 .38 *9039 39.293 31*. 112 12.1695 .2500 1.09602 .22512 .002 .22*83 .** *9036 39.291 315.169 12.1353 .2500 1 . *2 912 . 22576 .001 .22*96 .55 *9037 35.795 312.833 11.3229 .2500 .67920 .22136 .003 .22168 .33

*9038 35.795 313.12* 11.31*0 .2500 .80756 .22181 .002 .22199 .*9 *9039 35.795 31*. 18* 11.2817 .2500 1.09607 .22203 .001 .22170 .*1 *90*0 35.795 315.255 11.2*92 .2500 1 .*2917 .22276 .001 .22192 .55 *90*1 32.292 312.871 10.3991 .2500 .67927 .21779 .002 .21809 .08 *90*2 32.292 313.162 10.3907 .2500 .80757 .21891 .002 .21907 .5* *90*3 32.291 31*. 23* 10.3600 . 2500 1.09619 .21913 .002 .21878 .*5 *90** 32.290 315.3*0 10.3286 .2500 1 . *2 931 .22001 .001 .2191* .66 *90*9 28.803 312.895 9.***6 .2500 .67916 .21557 .003 .21586 .*1 *90*6 28.803 313.365 9. *32* .2500 .80706 .21588 .002 .2159* .*7 *90*7 23.803 31*. 251 9. *091 .2500 1.09616 .21623 .001 .21588 .*7 *90*8 28.802 31*. 879 9.3925 .2500 1.25667 .21616 .001 .21551 .31 *90*9 25.907 312.896 8.6258 .2500 .67920 .21318 .003 .213*6 .*3 *9050 25.907 313.3*9 8.61*6 . 2500 .80713 .21366 .002 .21373 .57 *9091 25.906 31*. 389 8.5891 .2500 1.09591 .21380 .002 .21338 .*3 *9052 25.906 31*. 970 8.57*9 .2500 1.25669 .21398 .002 .21329 .*2 *9053 23. *15 312.991 7.8979 .2500 .67921 .21086 .002 .21110 .30 *905* 23. *15 313. *53 7.8872 .2500 .80703 .211** .002 .211*6 • *6 *9055 23. *1* 31*. *92 7.8635 .2500 1.09600 .21202 .002 .21155 .36 *9056 23. *1* 315.090 7.8500 .2500 1.25670 .2121* .001 .21139 .30

*9057 21.000 312.627 7.1829 .2500 .56712 .20979 .003 .21020 .80

*9058 21.000 312.300 7.1897 .2500 .*600* .20889 .00* .209*5 • ** *9059 21.000 313.635 7.1619 .2500 .81323 .21011 .002 .21005 .76 *9060 21.000 31*. 139 7.151* .2500 .95308 .21001 .002 .20971 .61

15
$9061 18.660 312.273 6.4706 .2500 .45971 .20771 .004 .20828 .79 $9062 18.660 312.630 6.4636 .2500 .56633 .20802 .004 .20843 .87 $9063 18.659 313.51$ 6. $467 .2500 .8128$ .20763 .002 .20762 .51 $906$ 18.659 31$. 078 6.4361 .2500 .95246 .20815 .002 .20788 .64 $9065 16.279 312.289 5.718$ .2500 .45947 .20507 .004 .20563 .45 $9066 16.278 312.675 5.7116 .2500 .56605 .20485 .003 .20523 .26 $9067 16.278 313.580 5.6961 .2500 .81235 .20532 .002 .20528 .30 $9068 16.277 31$. 156 5.6863 .2500 .95211 .20621 .003 .20590 .62 $9069 13.970 312. 2$2 $.9708 .2500 .45945 .20329 .004 .20388 .49 $9070 13.969 312.668 $.9642 .2500 .56602 .2039$ .003 .20433 .71 $9071 13.969 313.599 $.9502 .2500 .81222 .20386 .002 .20381 .48 $9072 13.969 31$. 200 $.9413 .2500 .95176 .20411 .002 .20378 .48 $9073 11.63$ 312.280 $.1928 .2500 .45921 .20103 .003 .20160 .27 $907$ 11.633 312.672 $.1876 .2500 .56582 .20143 .003 .20181 .39 $9075 11.632 313 .669 $.1747 .2500 .81205 .20201 .003 .20193 .46 $9076 11.632 31$. 287 $.1668 .2500 .95156 .20229 .003 .20192 .46 $9077 9.309 312.36$ 3.3981 .2500 .45920 .19957 .004 .20010 .43 $90?8 9.309 312.806 3.3933 .2500 .56559 .19910 .003 .19942 .10 $9079 9.308 313.822 3.3825 .2500 .81183 .19999 .003 .19984 .32 $9080 9.307 3 1$ . 3$9 3.3768 . 2500 .9514$ .20019 .003 .19980 .30 $9081 6.793 312.399 2.5147 .2500 .45926 .19738 .006 .19789 .30 $9082 6.792 312.860 2.5110 .2500 .56579 .19819 .004 .19849 .60 $9083 6.791 313.85$ 2.5028 . 2500 .81169 . 19832 .002 .19816 .44 $908$ 6.790 314.559 2.4970 .2500 .9513$ .19810 .001 .19761 .17 $9085 $.$99 312.492 1.6869 .2500 .45921 .1957$ .008 .19621 .33 $9086 $.$98 312.889 1.6847 .2500 .56578 .19585 .004 .19613 .30 $9087 $.$98 314.037 1.6786 .2500 .81178 . 1964$ .006 .19619 .33 $9088 $.$98 314.687 1.6751 .2500 .95133 .19636 .005 .19581 .14 $9089 2. $27 312.141 .9221 .2500 .36368 .19312 .009 .19375 -.13

$9090 2. $26 312.413 .9209 .2500 .45915 .19336 .007 .19386 -.06

$9091 2. $26 313.36* .9180 .2500 .68332 .19418 .006 .19424 .13 $9092 2. $25 313.922 .9162 .2500 .81199 .19443 .002 .19424 .13 $9093 1.009 311.73$ .3870 .2500 .27946 .1915$ .012 .19235 -.29

$909$ 1.009 312.130 .3866 .2500 .36367 .19307 .010 .19370 .41 $9095 1.009 312.5*5 .3860 .2500 .45901 .19236 .010 .19280 -.05

$9096 1.009 313.068 .3853 .2500 .56547 .19313 .009 .19333 .22 $9097 1.007 313.560 . 3841 .2500 .68309 .19426 .009 .19423 .68

Expe r 1 men t a 1 Ad J. Thermal Conduct 1 v Ity Ther ma

1

Nom

.

Temperature deviation

Run Pt. Pressure Temperature Dens 1 ty para p ouer Conduct 1 v 1 ty STAT 125.0 K exp. -calc.

MPa K TO 1 / L fraction W/m W/m.K W/m.K pe rcent 76001 63.517 126.038 31.5280 .2500 .81039 .20899 .001 .20814 -.57

76002 63.517 126.258 31.4992 .2501 .8944$ .20873 .001 .20770 -.68

76003 63.515 126.425 31.4770 .2502 .98283 .20903 .001 .20787 -.52

7600$ 63.515 126.8$$ 31.4225 .2503 1.0765$ .20914 .001 .20764 -.43

76005 56.672 126.183 29.8632 .2516 .81186 .19716 .001 .19622 -.36

76006 56.676 126.386 29.837$ .2517 .89597 .19681 .001 .19571 -.53

76007 56.676 126.7*5 29.7900 .2518 .98461 .19658 .001 .19519 -.62

76008 56.683 125.872 29.9072 .2519 .73129 .19756 .001 .19686 -.19

76009 51.036 126.05$ 28.3811 .2531 .73223 .18686 .001 .18604 -.36

76010 51.039 126.199 28.3626 . 2532 .81169 .18665 .001 .18571 -.47

76011 51.0$1 126.585 28.3117 .2532 .896*8 .18675 .001 .18551 -.40

76012 51.0$$ 126.82$ 28.2805 .2533 .98492 .18632 .001 .18490 -.62

76013 $6,372 126.103 27.0138 .254$ .73237 .17816 .001 .17731 -.36

7601$ $6,375 125.826 27.0523 .2545 .65637 .17828 .001 .17765 -.31

76015 $6,378 126.472 26.9661 .2546 .81316 .17780 .001 .17667 -.56

76016 $6,380 126.649 26.9430 .2546 .89770 .17789 .001 .17662 -.50

76017 $2,211 125.932 25.7129 .2560 .65731 .17066 .001 .16995 -.13

76018 $2,212 126.210 25.6757 .2561 .73298 .17028 .001 .16936 -.35

76019 $2.21$ 126.406 25.6501 .2562 .81347 .17062 .001 .16956 -.15

76020 $2,216 126.906 25.5836 .2563 .89882 .17053 .001 .16909 -.20

76021 38 • 2$9 126.108 24.3141 .257$ .65781 .16280 .001 .16197 -.23

76022 38.251 126.433 24.2712 .2575 .7339$ .16280 .001 .16173 -.24

76023 38.25$ 126.738 24.2311 .2576 .81456 .16292 .001 .16162 -.17

7602$ 38.255 126.995 24.197* .2577 .89920 .16317 .001 .16168 -.03

76025 3$. 728 125.862 23.0155 .2589 .5865$ .15617 .001 .15553 -.03

76026 3$. 731 126.196 22.9717 .2590 .65848 .15563 .001 .15475 -.39

76027 3$. 732 126.408 22.9439 .2590 .73439 .15569 .001 .15465 -.37

76028 3$. 733 126.827 22.8883 .2591 .81518 .15585 .001 .15451 -.28

76029 31.282 125.922 21.5861 .2603 .58678 .14915 .002 .14848 -.10

76030 31.285 126.310 21.5357 .260$ .65889 .14911 .001 .14816 -.15

76031 31.286 126.536 21.506* .260$ .73498 .1*911 .001 .14799 -.17

76032 31.287 126.898 21.4595 .2605 .81576 .14903 .001 .14765 -.26

76033 28.212 125.866 20.2110 .2617 .52017 .14332 .002 .14268 .20 7603$ 28.213 126.090 20.1847 .2618 .58741 .14323 .001 .14245 .12 76035 28.21$ 126.417 20.1427 .2619 .65965 .14320 .001 .14218 .06 76036 28.215 126.778 20.0967 .2619 .73618 .14305 .001 .14177 -.09

76037 25. $73 125.981 18.8642 .2935 .52009 .13875 .002 .13804 .34 76038 25. $7$ 126.287 18.8259 .2936 .58803 .13880 .001 .13787 .33 76039 25. $76 126.698 18.7746 .2936 .66020 .13882 .001 .13759 .28 760*0 25. $76 126.972 18.7400 .2937 .73658 .13 879 .001 .13736 .22 760$ 1 23. 0$5 126.080 17.5772 .29*8 .5203$ .13328 .001 .13250 .02 760$2 23.0*6 126.38$ 17.5405 .29*9 .5882$ .13350 .001 .13250 .13

16
760*3 23.0*6 126.701 17.5026 .29*9 .66051 .13363 .001 .132*1 .16 760*4 23.0*9 127. C96 17.4550 .2950 .73729 .13360 .001 .13209 .06 760*6 20.333 125.834 16.0685 .2960 .45705 .12765 .001 .12706 .12 760*6 20.33* 126.245 16.0210 .2961 .52084 .12765 .001 .12676 .03 760*7 20.335 126.466 15.9958 .2962 .58870 .12777 .001 .12672 .07 760*0 20.336 126.861 15.9501 .2962 .66099 .12780 .001 .12647 -.01

760*9 18.3*9 125.950 14.8467 .2973 .45769 .12359 .001 .12292 .19 76050 18.350 126.2*5 14.81*3 .297* .52115 .12357 .001 .12269 .09 76051 18.352 126.689 14.7657 .2975 .589*8 .12371 .001 .12251 .08 76052 18.352 127.016 14.7300 .2976 .66181 .12368 .001 .12225 -.0*

76053 16.180 125.9*1 13.4390 . 2985 .45765 .11901 .001 .11835 .19 7605* 16.181 126.333 13.3990 .2986 .52156 .11916 .001 .11822 .18 76055 16.182 126.803 13.3507 .2987 .58980 .11922 .001 .11795 .06 76056 16.183 127.138 13.3166 .2988 .66223 .11917 .001 .11766 -.07

76057 14.30* 125.737 12.1640 .3001 .39863 .11505 .001 .11*53 .23 76058 14.30* 126.000 12.138* .3001 .45791 .11*92 .001 .11*22 .02 76059 14.30* 126.363 12.1036 .3002 .52176 .11513 .001 .11417 .07 76060 14.30* 126.963 12.0461 .3003 .59061 .115*2 .001 .1140* .10 76061 12.491 125.915 10.8242 .3013 .39892 .1112* .001 .11060 .1* 76062 12.491 126.318 10.789* .3014 .45877 .11147 .001 .11055 .18 76063 12.491 126.663 10.7592 .3015 .52257 .11138 .001 .11022 -.05

7606* 12.492 127.066 10.72*7 .3016 .59109 .11162 .001 .11018 -.00

76065 10.7*6 125.686 9.5039 .3026 .3*388 .10739 .00* .10691 .01 76066 10.7*6 126.034 9.4765 .3027 .39925 .10768 .002 .10696 .11 76067 10.7*7 126.428 9.4463 .3028 .45890 .10777 .002 .10678 .01 76068 10.7*7 126.795 9.4178 .3029 .52288 .10787 .001 .10662 -.06

76069 9.007 125.761 8.0985 .30*4 .3***2 .10395 .002 .10342 .05 76070 9.007 126.038 8.0797 .30*5 .39975 .10*15 .001 .103*3 .10 76071 9.007 126.435 8.0530 .30*6 .45962 .10**0 .001 .103*0 .13 76072 9.007 126.959 8.0180 .30*7 .52*13 .10*50 .001 .1031* -.0*

76073 7.3*0 125.452 6.7170 .3058 .29321 .10033 .002 .10002 -.08

7607* 7.3*0 125.869 6.6935 . 3058 .34*58 .10061 .002 .10001 -.03

76075 7.339 126.198 6.67*7 .3059 .39995 .10076 .001 .09993 -.07

76076 7.3*0 126.597 6.6527 .3060 .45998 .10094 .001 .09983 -.11

76077 5.932 125.581 5.4859 .3070 .29336 .09782 .002 .097*2 .10 76078 5.932 125.873 5.4724 .3071 .3**67 .0978* .001 .0972* -.06

76079 5.932 126.38* 5.4*90 .3072 .40052 .09813 .001 .09717 -.08

76060 5.932 126.857 5.4275 .3072 .46057 .09826 .001 .09698 -.23

76081 *.*29 125.692 4.1369 . 3088 .29353 .09501 .002 .09*53 .08 76082 *.*29 126.047 4.12*6 .3088 .3**82 .0951* .001 .09**2 -.01

76083 *.*29 126.532 4.1080 .3089 .40062 .09530 .001 .09*24 -.16

7608* *.*29 126.999 4.0921 .3090 .46075 .09552 .001 .09*1* -.2*

76085 2.893 125.557 2.7317 . 3099 .24678 .09185 .00* .091*7 -.1*

76086 2.092 125.956 2.7223 .3099 .29398 .0925* .002 .09188 .33 76087 2.893 126.307 2.7148 .3100 .34527 .09202 .001 .09112 -.49

76088 2.892 126.725 2.7048 .3101 .40113 .09266 .002 .091*7 -.08

76089 1.456 125.724 1.3836 .3114 .2*709 .08920 .002 .08870 -.33

76090 1.456 126.0*1 1.3797 .3115 .29*26 .089*0 .002 .08868 -.35

76091 1.456 126.558 1.3740 .3115 .3*598 .08955 .002 .088*8 -.57

76092 1.456 127.085 1.3681 .3116 .40227 .08999 .001 .08855 -.47

Exper 1 menta

1

AdJ. Thermal Conductivity

Thermal Now, Temperature deviation

Run Pt. Pressure Temper atur e Dens 1 ty para Power Conduct 1 v 1 ty STAT 125.0 K axp.-calo.

MPa K mo 1 /

1

f ract Ion W/m W/n.K W/H.K percent

75001 12.728 125.345 11.0524 .2500 .34298 .11028 .002 .11005 .38 75002 12.727 125.709 11.0191 . 2500 .3982* . 1106* .002 .11016 .57 75003 12.727 126.129 10.9813 .2500 .45795 .11072 .001 .10995 .48 7500* 12.727 126.549 10.9*39 .2500 .52196 .11095 .001 .10990 .33 75005 11.333 125.391 9.9868 .2500 .34309 .107*6 .002 .10720 .47 75006 11.334 125.813 9.9523 . 2500 .39832 .10730 .001 .10675 .1*

75007 11.334 126.140 9.9255 .2500 .45778 .10783 .001 .10706 .50 75008 11.334 126.665 9.8828 .2500 .52199 .10800 .001 .10687 .43 75009 9.891 125.636 8.8273 .2500 .3*357 .10*20 .003 .10377 .11 75010 9.892 125.682 8.8095 .2500 .39883 .10*71 .001 .10*12 .49

75011 9.892 126.182 8.7875 .2500 .*5e37 .10*80 .001 .10*00 .** 75012 9.892 126.734 8.7480 .2500 .52265 .10503 .001 .10386 .40 75013 8.514 125.709 7.6938 .2500 .3*379 .10179 .002 .10131 .48 7501* 8.51* 126.053 7.6720 .2500 .39899 .10183 .001 .10112 .3* 75015 8.514 126.405 7.6494 .2500 .45875 .10206 .001 .10112 .39 75016 8.514 126.936 7.6157 .2500 .52306 .1022* .001 .1009* .30 75017 6.949 125.6*3 6.3701 .2500 .3436* .098*6 .001 .09803 .3* 75018 6.949 126.050 6.3*82 .2500 .39911 .0987* .001 .0980* .40

75019 6.949 126.516 6.3237 .2500 .45901 .09897 .001 .09795 .37 75020 6.949 125.339 6.3868 .2500 .292*9 .09818 .001 .09795 .22 75021 5.572 125.848 5.1550 .2500 .3**1* .09570 .001 .09513 .17 75022 6.572 126.285 5.1361 .2500 .3998* .09611 .001 .09525 .3* 75023 5.572 126.665 5.1198 .2500 .45988 .0963* .001 .09523 .33

7502* 5.572 125.52* 5.1690 .2500 .29300 .0955* .002 .09319 .20 75025 4.065 125.69* 3.8065 .2500 .29331 .0927* .001 .09228 .21 75026 4.065 125.956 3.7982 .2500 .3**53 .09285 .001 .09221 .16

75027 4.065 126.485 3.7815 .2500 .400*2 .0933* .001 .09233 .3* 75028 4.065 126.925 3.7678 .2500 .460*8 .09362 .001 .0923* .36 75029 2.652 125.328 2.5128 .2500 .24635 .08962 .002 .089*0 -.06

17
^5030 2.652 1 25.82"' 2.5025 .2500 .29359 .09011 .001 .08956 .14 75031 2.65? 126.31? 2.4925 .2500 .34503 .09038 .001 .08951 .11 75032 2.652 126.624 2.4861 .2500 .40071 .09065 .001 .08957 .19 75033 1.169 125.624 1.1138 .2500 .24683 .08693 .001 .08652 -.25

75034 1.169 126.081 1.1096 .2500 .29421 .08699 .001 .08627 -.52

75035 1.169 126.492 1.1060 . 2500 .34569 .08733 .001 .08634 -.43

75036 1.169 125.080 1.1187 .2500 .20368 .08650 .002 .08653 -.24

75037 .424 125.329 .4064 .2500 .20388 .08516 .004 .08494 -.52

75038 .424 125.700 .4052 .2500 .24683 .08542 .004 .08496 -.50

75039 .424 126.170 .4037 .2500 .29431 .08563 .002 .08485 -.62

75040 .424 126.681 .4021 .2500 .34591 .08562 .002 .08450 -1.03

Exper 1 mental Ad J. Therm at Conduct 1 v Ity Ther ma 1 Non . Temperature deviation

tun Pt. Pressure Temperature Oens 1 ty para Power Conductivity STAT 100.0 K exp. -calc*

MPa K mo 1 / L tract Ion W/ir W/m.K W/m.K percent

77001 11.216 103.400 12.1546 . 2500 .35296 .09744 .001 .09530 -1.04

77002 11.216 103.754 12.1092 .2500 .40301 .09769 .001 .09532 -.87

77003 11.216 103.438 12.0855 .2500 .45536 .09745 .001 .09497 -1.18

77004 11.215 104.462 12.0189 .2500 .51226 .09762 .001 .09481 -1.15

77005 9.842 103.118 10.8769 .2500 . 30707 .09387 .002 .09192 -.86

77006 9.643 103.506 10.8326 .2600 .35325 .09389 .002 .09169 -.97

77007 9.843 103. e45 10.7936 .2500 .40289 .09387 .001 .09146 -1.11

77008 9.843 104.174 10.7558 .2500 .45608 .09406 .001 .09144 -1.01

77009 8.449 103.237 9.4674 .2500 .30742 .09030 .002 .08827 -.76

77010 8.450 103.577 9.4332 .2500 .35375 .09014 .002 .08789 -1.09

77011 8.451 104.049 9,3859 .2500 .40387 .09048 .001 .08794 -.90

77012 8.452 102.860 9.5095 .2500 .26446 .08999 .002 .06819 -.97

77013 6.896 103.170 7.8434 .2500 .26510 .08642 .002 .08441 -.51

77014 6.897 103.371 7.8266 .2500 .30779 .08627 .002 .08413 -.79

77015 6.897 103.763 7.7936 .2500 .35426 .08637 .001 .08399 -.87

77016 6.897 104.141 7.7622 .2500 .40421 .08651 .001 .08389 -.90

77017 5.557 102.997 6.3946 .2500 .22585 .08278 .002 .06086 -.64

77018 5.557 103.102 6.3873 .2500 .26521 .08271 .002 .08072 -.79

77019 5.557 103.523 6.3586 .2500 .30835 .08276 .001 .08050 -.99

77020 5.557 103.939 6.3300 .2500 .35510 .08294 .001 .08041 -1.01

77021 4.111 103.051 4.7657 .2500 .22604 .07930 .001 .07732 -.51

77022 4.111 103.294 4.7530 .2500 .26561 .07913 .001 .07698 -.90

77023 4.112 103.779 4.7291 .2500 .30909 .07944 .001 .07698 -.84

77024 4.112 104.134 4.7117 .2500 .35575 .07945 .001 .07676 -1.08

77025 2.775 103.220 3.2258 .2500 .22648 .07598 .002 .07386 -.78

77026 2.775 103.567 3.2145 .2500 .26642 .07618 .001 .07383 -.78

77027 2.775 104.008 3.1998 .2500 .30984 .07637 .001 .07374 -.88

77028 2.775 104.494 3.1838 .2500 .35685 .07662 .001 .07367 -.93

77029 1.287 103.001 1.5029 .2500 .19011 .07234 .002 .07035 -.91

77030 1.296 103.440 1.4959 .2500 .22696 .07264 .002 .07036 -.88

77031 1.286 103.904 1.4889 .2500 .26708 .07278 .001 .07019 -1.10

77032 1.286 104.355 1.4822 .2500 .31079 .07309 .001 .07020 -1.06

77033 .556 103.129 .6490 .2500 .19037 .07083 .005 .06875 -.87

77034 .556 103.520 .6465 .2500 .22712 .07105 .004 .06871 -.93

77035 .556 103.833 .6441 .2500 .26702 .07133 .004 .06878 -.81

77036 .556 104.556 .6396 .2500 .31138 .07187 .004 .06884 -.71

18
Table 2. The Thermal Conductivity of Hydrogen* Para and Para-rlch Compositions

Experimental AdJ. Thermal Conductivity

Thermal Norn. Temper at ur e deviation

Run Pt. Pressure Temperature Pens 1 1

y

para Power Conduct 1 v 1 ty STAT 100.0 K exp.-calc.

MPa K mo 1 / L fraction W/IT W/m.K W/m.K pe rcen'

59001 11.521 98.763 13.0739 .9979 .33528 .10771 .002 .10891 -1.97

>9002 11.522 99.056 13.0380 .9979 .38252 . 10881 .001 .10975 -1.10

59003 11.522 99.708 12.9530 . 9979 .58665 .10911 .001 .10939 -1.16

5 900* 11.522 99.976 12.9051 .9979 .55353 .10905 .001 .10906 -1.36

59005 10.078 9 8 . e 8 7 11.6515 .9979 .33588 . 10520 .001 .10528 -1.53

59006 10.C78 99.200 11.6001 .9979 .38317 .10587 .001 .10565 -1 .07 59007 10.079 99.555 11.5557 .9979 .53353 .10512 .001 .10556 -1.03

59008 10.080 99.932 11.5057 .9979 .58756 .10581 .002 .10588 -1.56

59009 8.669 99.028 10.1606 .9979 .33629 .10073 .002 .10167 -1.15

59010 8.670 99.327 10.1265 .9979 .38355 .10080 .001 .10155 -1.27

59011 8.671 99.700 10.0839 .9979 .53510 .10109 .001 .10138 -1.23

59012 8.671 99.925 10.0585 .9979 .58757 .10152 .001 .10159 -1.05

59013 7.155 93.899 8.5086 .9979 .29290 .09661 .001 .09768 -.89

59015 7.155 99.113 8.5882 .9979 .33666 .09656 .001 .09732 -1.21

59015 7.155 99.515 8.5595 .9979 .38530 .09685 .001 .09732 -1.11

59016 7.156 99.955 8.5085 .9979 .53555 .09721 .002 .09726 -1.07

59017 5.790 98.959 6.9620 .9979 .29308 .09265 .002 .09367 -1.18

59018 5.790 99.303 6.9350 .9979 .33737 .09319 .001 .09367 -.89

59019 5.790 99.620 6.9092 .9979 .38569 .09338 .001 .09375 -.96

59020 5.790 100.007 6.8787 .9979 .53561 .09368 .001 .09367 -.97

59021 5.370 9R.779 5.3056 .9979 .25255 .08903 .001 .09025 -.80

59022 5.370 99.059 5.2881 .9979 .29335 .08928 .001 .09021 -.79

59023 5.370 99.572 5.2639 .9979 .33788 .08970 .001 .09022 -.72

59025 5.370 99.801 5.2553 .9979 .38550 .08981 .001 .09001 -.91

59025 2.958 98.931 3.5998 .9979 .25286 .08563 .001 .08670 -.67

59026 2.958 99.251 3.5875 .9979 .29385 .08577 .001 .08652 -.85

59027 2.958 99.653 3.5725 .9979 .33831 .08630 .001 .08666 -.65

59028 2.958 99.988 3.5589 .9979 .38620 .08665 .001 .08665 -.62

59029 1.552 98,790 1.7595 .9979 .21531 .08166 .001 .08287 -.82

59030 1.552 99.167 1.7525 .9979 . 25337 .08211 .001 .08295 -.72

59031 1.552 99.586 1.7557 .9979 .29575 .08251 .001 .08293 -.73

59032 1.552 100.018 1.7367 .9979 .33958 .08282 .001 .08280 -.86

Expe r 1 mental AdJ. Thermal Conductivity

Thermal Norn. Temperature deviation

Run Pt. Pressure Temperature Dens 1 ty para Power Conduct 1 » 1 ty STAT 125.0 K exp. -calc.

mo b K mo 1 /L fraction V/m W/m.K W/m.K pe rcen'

58001 11.635 123.793 10.3559 .9979 .39325 .12715 .001 .12833 -.55

58002 11.635 125.037 10.3357 .9979 .55195 . 12706 .001 .12800 -.76

58003 11.635 125.355 10.3077 .9979 .51585 .12753 .002 .12806 -.65

58005 11.635 125.755 10.2753 .9979 .58187 . 12807 .001 .12832 -.38

58005 10.210 123.830 9.2218 .9979 .39357 .12553 .002 .12567 -.27

58006 10.210 125.192 9.1939 .9979 .55226 .12570 .001 .12559 -.36

58007 10.210 125.579 9.1719 .9979 .51511 .12585 .001 .12535 -.52

58008 10.211 125.902 9.1395 .9979 .58267 .12522 .001 .12532 -.38

58009 8.722 123.955 7.9851 • 997q .39378 .12161 .001 .12263 -.20

58010 8.722 125.351 7.9585 .9979 .55262 .12181 .002 .12255 -.30

58011 8.722 125.597 7.9511 .9979 .51555 .12168 .002 .12207 -.57

58012 8.722 125.018 7.9131 .9979 .58305 .12256 .001 .12255 -.21

58013 7.186 125.021 6.6660 .9979 .39500 .11855 .001 .11950 -.27

58015 7.187 125.385 6.6556 .9979 .55292 .11892 .001 .11952 -.13

58015 7.187 125.755 6.6257 .9979 .51608 .11901 .001 .11925 -.32

58016 7.187 125.185 6.6005 .9979 .50389 .11968 .002 .11950 -.06

58017 5.550 125.153 5.1117 .9979 .39553 .11559 .001 .11632 .09 58018 5.550 123.775 5.1279 .9979 .33963 .11527 .001 .11656 .18 58019 5.550 125.505 5.0960 .9979 .55335 .11602 .001 .11650 .28 58020 5.550 125.899 5.0789 .9979 .51658 .11580 .002 .11590 -.21

58021 5.223 123.851 5.0123 .99 79 .33983 .11221 .001 .11332 -.57

58022 5.223 125.288 3.9975 .9979 .39573 .11350 .001 .11509 .23 58023 5.223 125.712 3.9831 .9979 .55383 .11369 .001 .11397 .15 58025 5.223 125.153 3.9683 .9979 .51727 .11372 .001 .11357 -.17

58025 2.858 125.050 2.7253 .9979 .35006 .11025 .002 .11117 -.05

58026 2.858 125.595 2.7151 .9979 .39515 . 11085 .001 .11135 .13 58027 2.858 125.877 2.7055 .9979 .55522 .11113 .001 .11125 .06 58028 2.858 125.265 2.6968 .9979 . 51779 . 11136 .001 .11110 -.03

58029 1.531 123.922 1.5763 .9979 .28992 .10775 .002 .10878 .01 58030 1.531 125.357 1.5708 .9979 .35065 .10785 .001 .10858 -.23

58031 1.531 125.703 1.5665 .9979 .39553 .10859 .001 .10878 .03 58032 1.531 125.150 1.5612 .9979 .55501 . 10895 .001 .10681 .07

19
Experl mental AdJ. Therma 1 Conduct 1 v 1 ty

Therma

1

Norn. Temperature deviation

Run Pt. Pressure Temperature Dens 1 ty pare Power Conduct 1 vl ty STAT 175.0 K exp. -calc.

MPa K mol /l fraction W/m W/m.K W/m.K percent

56001 11.850 173.061 7.5158 .9979 .63338 .15851 .002 .15960 -.07

56002 11.869 173.658 7.6979 .9979 .50861 .15966 .001 .16032 .61 56003 11.869 173.726 7.6866 .9979 .59008 .15899 .001 .15970 .06 56006 11.869 176.101 7.6705 .9979 .67767 .15932 .001 .15982 .16 56005 10.398 173.116 6.6726 .9979 .63363 .15710 .001 .15815 .32 56006 10.398 173.680 6.6587 .9979 .50861 .15671 .002 .15755 -.03

56007 10.398 173.811 6.6662 .9979 .58986 .15676 .001 .15760 -.11

56000 10.398 176.133 6.6361 .9979 .67726 .15696 .001 .15766 -.07

56009 8.859 173.022 5.7603 .9979 .63366 .15573 .006 .15683 .85 56010 8.859 173.622 5.7671 .9979 .50857 .15699 .001 .15586 .26 56011 8.859 173.858 5.7327 .9979 .59013 .15686 .001 .15567 .03 56012 8.859 176.262 5.7195 .9979 .67753 .15552 .002 .15593 .35 56013 7.333 173.176 6.8226 .9979 .63379 .15228 .002 .15329 -.05

56016 7.333 173.692 6.8136 .9979 .50896 .15279 .001 .15362 .19 56015 7.333 173.910 6.8021 .9979 .59065 .15303 .001 .15363 .21 56016 7.333 176.635 6.7876 .9979 .67811 .15329 .001 .15360 .21 56017 5.971 173.301 3.9659 .9979 .63383 .15055 .002 .15169 .00 56018 5.971 173.680 3.9572 .9979 .50908 .15076 .002 .15169 .01 56019 5.971 173.995 3.9501 .9979 .59068 .15166 .001 .15201 .37 56020 5.971 176.650 3.9397 .9979 .67817 .15119 .001 .15169 .06 56021 6.560 173.330 3.0611 .9979 .63392 .16880 .002 .16972 .10 56022 6.560 173.700 3.0566 .9979 .50922 .16907 .001 .16979 .15 56023 6.560 176.179 3.0661 .9979 .59065 .16937 .001 .16982 .19 56026 6.560 176.606 3.0386 .9979 .67831 .16965 .001 .16987 .23 56025 3.200 173.666 2.1683 .9979 .63611 .16681 .002 .16766 -.06

56027 3.199 176.201 2.1586 .9979 .59169 .16762 .001 .16786 .08 56028 3.199 176.830 2.1506 .9979 .67962 .16759 .001 .16768 -.02

56029 1.781 172.760 1.2261 .9979 .30223 .16562 .005 .16665 .52 56030 1.781 173.101 1.2217 .9979 .36560 .16662 .005 .16566 -.15

56031 1.781 173.919 1.2159 .9979 .51039 .16586 .003 .16663 .38 56032 1.780 176.600 1.2123 .9979 .59203 .16597 .002 .16630 .30 56033 1.059 172.756 .7316 .9979 .30219 .16603 .012 .16526 .23 56036 1.059 173.127 .7300 .9979 .36531 .16558 .008 .16661 1.16

56035 1.059 173.626 .7288 .9979 .63665 .16601 .006 .16688 -.06

56036 1.059 173.957 .7266 .9979 .51015 .16571 .006 .16628 .93 Exper 1 mental AdJ. Thermal C onduct I v 1 ty

Therma

1

Nom. Temperature dev latlon Run Pt. P ressure Temperature Dens 1 ty para Power Conductl v 1 ty STAT 200.0 K exp. -calc.

MPa K mo 1 /L fraction W/e W/m.K W/m.K percent

55001 12.020 190.876 6.6506 .9979 .50726 .16859 .001 .16909 -.36

55002 12.020 199.265 6.6381 .9979 .59505 .16823 .003 .16856 -.66

55003 12.020 199.666 6.6258 .9979 .68993 .16917 .001 .16933 -.18

55006 12.020 200.108 6.6110 .9979 .79196 .16907 .001 .16903 -.36

55005 10.561 198.906 5.9080 .9979 .50735 .16762 .002 .16791 -.00

55006 10.561 199.358 5.8969 .9979 .59697 .16666 .001 .16693 -.57

55007 10.561 199.703 5.8850 .9979 .69006 .16711 .001 .16726 -.37

55008 10.561 200.163 5.8719 .9979 .79205 .16726 .001 .16719 -.38

55009 9.167 198.956 5.1706 .9979 .50730 .16518 .002 .16565 -.36

55010 9.167 199.628 5.1586 .9979 .59512 .16517 .001 .16563 -.65

55011 9.167 199.766 5.1506 .9979 .69011 .16551 .001 .16562 -.32

55012 9.167 200.199 5.1391 .9979 .79226 .16567 .001 .16559 -.33

55013 7.723 198.966 6.6126 .9979 .50736 .16363 .001 .16609 -.25

55016 7.723 199.609 6.6027 .9979 .59512 .16388 .001 .16616 -.20

55015 7.723 199.860 6.3936 .9979 .69030 .16383 .001 .16390 -.36

55016 7.723 200.378 6.3817 .9979 .79237 .16609 .001 .16396 -.30

55017 6.603 198.658 3.7002 .9979 .62668 .16162 .002 .16222 -.65

55018 6.603 199.073 3.6926 .9979 .50729 .16195 .001 .16236 -.35

55019 6.603 199.677 3.6852 .9979 .59508 .15232 .001 .16255 -.22

55020 6.603 200.069 3.6766 .9979 .68996 .16217 .001 .16215 -.65

55021 5.000 198.772 2.9178 .9979 .62662 .15983 .002 .16037 -.57

55022 5.000 199.196 2.9117 .9979 .50736 .16035 .002 .16071 -.35

55023 5.000 199.597 2.9059 .9979 .59509 .16005 .002 .16023 -.66

55026 5.000 200.071 2.8990 .9979 .69018 .16071 .001 .16068 -.35

55025 3.533 198.826 2.0836 .9979 .62631 .15801 .002 .15853 -.66

55026 3.533 199.207 2.0796 .9979 .50735 .15860 .002 .15895 -.39

55027 3.533 199.695 2.0763 .9979 .59526 .15896 .002 .15910 -.29

55028 3.533 200.166 2.0693 .9979 .69030 .15683 .001 .15876 -.69

55029 2.266 198.576 1.3373 .9979 .35292 .15656 .006 .15717 -.58

55030 2.263 198.850 1.3352 .9979 .62658 .15698 .003 .15769 -.37

55031 2.263 199.258 1.3325 .9979 .50766 .15652 .003 .15685 -.78

55032 2.263 199.785 1.3290 .9979 .59533 .15738 .003 .15768 -.38

55033 1.002 198.662 .6031 .9979 .35279 .15581 .012 .15669 -.10

55036 1.002 198.828 .6020 .9979 .62665 .15532 .012 .15586 -.52

55035 1.002 199.297 .6006 .9979 .50713 .15516 .010 .15567 -.75

55036 1.002 199.735 .5991 .9979 .59505 .15551 .008 .15563 -.65

20
Exper 1 mental Ad j. Therma

1

Conduct I v Ity

Thermal Nom. Temperature deviation

Sun Pt. Pressure Temperature Dens 1 ty part Power Conduct 1 v 1 ty STAT 225.0 K exp. -calc.

MPa K mo 1 / L tract Ion W / m W/m.K W/m.K percent

5*001 11.782 223.012 5.8*87 .9979 .*0191 .17683 .003 .17756 .05 5*002 11.782 223.3*0 5.8*0* .9979 .*8575 .17658 .002 .17719 -.15

5*003 11.782 223.692 5.8316 .9979 .577*2 .17661 .002 .17709 -.20

5*00* 11.782 22*. 210 5.8187 .9979 .67710 .17683 .001 .17712 -.16

5*005 11.782 22*. 682 5.8070 .9979 .78*79 .17669 .001 .17681 -.33

5*006 11.781 225.1*9 5.7953 .9979 .90091 .17678 .001 .17672 -.36

**007 10.368 223. *06 5.1901 .9979 .*8568 .17*17 .002 .17*76 -.67

5*008 10.369 223.79* 5.1816 .9979 .577*0 .17505 .001 .175*9 -.2*

5*009 10.369 22*. 229 5.1719 .9979 .67716 .17*88 .001 .17516 -.*1

5*010 10.369 22*. 693 5.1616 .9979 .78*99 .17551 .001 .17562 -.1*

5*011 8.850 223.521 *.*757 .9979 .*85*5 .17302 .002 .17356 -.*2

5*012 8.850 223.859 *.*691 .9979 .57739 .17338 .002 .17380 -.28

5*013 8.850 22*. 276 *.*611 .9979 .6771* .17328 .001 .17355 -.*2

5*01* 8.850 22*. 771 *.*515 .9979 .78*95 .17360 .001 .17368 -.32

5*015 7.361 223. *51 3.7631 .9979 .*8567 .17166 .002 .17223 -.29

5*016 7.361 223.880 3.7561 .9979 .577*5 .171*1 .001 .17182 -.51

5*017 7.361 22*. 367 3.7*81 .9979 .67726 .1720* .001 .17227 -.2*

5*018 7.361 22*. 877 3.7398 .9979 .78508 .17205 .001 .17210 -.33

5*019 6.059 223.536 3.12*8 .9979 .*8569 .17020 .002 .1707* -.36

5*020 6.059 223.991 3.1186 .9979 .57753 .16991 .001 .17028 -.62

5*021 6.059 22*. *90 3.1117 .9979 .67719 .170*1 .001 .17060 -.*2

5*022 6.059 22*. 960 3.105* .9979 .78512 .17089 .001 .17090 -.23

5*023 *.628 223.626 2. *096 .9979 .*656* .16807 .002 .16857 -.76

5*02* *.628 22*. 059 2. *050 .9979 .577*6 .16867 .001 .16901 -.*9

5*025 *.628 22*. 5*7 2.3998 .9979 .67721 .16859 .001 .16876 -.6*

5*026 *.628 225.09* 2.39*1 .9979 .78513 .16922 .001 .16919 -.37

5*027 3.269 223.690 1.7181 .9979 .*8586 .16673 .002 .16721 -.7*

5*028 3.269 22*. 186 1.71*3 .9979 .57771 .16775 .001 .16805 -.23

5*029 3.269 22*. 699 1.710* .9979 .677*9 .167*8 .001 .16759 -.50

5*030 3.269 223.292 1.7211 .9979 .*0197 .16673 .002 .16735 -.65

5*031 1.8*2 223.183 .9799 .9979 .*0190 .165*2 .003 .16608 -.53

5*032 1.8*2 223.629 .9780 .9979 .*8563 .16613 .002 .16663 -.20

5*033 1.8*2 22*. 070 .9759 .9979 .577*7 .16559 .002 .16593 -.62

5*03* 1.8*2 22*. 580 .9737 .9979 .6772* .16620 .002 .16635 -.36

5*035 .987 223.280 .5280 .9979 .*0181 .16*50 .009 .16513 -.58

5*036 .987 223.69* .5270 .9979 .*855* .16*56 .007 .1650* -.63

5*037 .986 22*. 088 .5257 .9979 .577*8 .16555 .006 .16588 -.12

5*038 .986 22*. 552 .52*6 .9979 .67720 .16*90 .005 .16506 -.61

Experl mental Ad J. Therma

1

Conduct 1 v Ity Ther ma

1

Nom. Temperat ur e dev 1 atlon

Run Pt. Pressure T emperature Dens 1 ty para Power Conductl vl ty STAT 150.0 K exp. -cal c. MPe K mo 1 /L tract Ion W/m W/m.K W/m.K pa rcent

57001 11.718 1*8.367 8.665* .9979 .*2*2* .1*529 .001 .1*662 .13 57002 11.718 1*8.697 8.6*61 .9979 .*9217 .1*561 .001 .1*667 .20 57003 11.718 1*9.030 8.6266 .9979 .56531 .1*57* .001 .1*653 .1* 5700* 11.718 1*9. *98 8.5996 .9979 .6*386 .1*590 .001 .1*631 .03 57005 10.293 1*8. *71 7.7065 .9979 .*2*38 .1*263 .002 .1*387 -.09

57006 10.293 1*8.759 7.691* .9979 .*9239 .1*271 .002 .1*372 -.17

57007 10.293 1*9.090 7.67*1 .9979 .56559 .1*357 .002 .1**31 .27

57008 10.293 1*9. *80 7.6539 .9979 .6**02 .1*375 .001 .1**17 .21 57009 8.820 1*8. *5* 6.691* .9979 .*2*55 .1*026 .002 .1*152 -.02

57010 8.821 1*8.793 6.6761 .9979 .*92*6 .1*061 .002 .1*159 .06 57011 8.821 1*9.28* 6.6538 .9979 .56570 .1*123 .001 .1*181 .25 57012 8.821 1*9.6** 6.6375 .9979 .6**37 .1*118 .001 .1*1*7 .0* 57013 7.3*3 1*8.50* 5.6387 .9979 .*2*71 .13796 .002 .13917 .05 5701* 7.3*3 1*8. 9*3 5.6219 .9979 .*9271 .13896 .002 .13982 .5* 57015 7.3*3 1*9.353 5.6062 .9979 .56616 .1390* .001 .13956 .38 57016 7.3*3 1*9.692 5.5932 .9979 .6**79 .13911 .001 .13936 .26

57017 6.100 1*0.31* *.7385 .9979 .36193 .1360* .003 .137*0 .22 57018 6.100 1*8.63* *.7281 .9979 .*2*78 .13611 .002 .13722 .10

57019 6.100 1*9.00* *.7161 .9979 .*9298 .13680 .001 .13761 .*0 57020 6.100 1*9.38* *.7038 .9979 .56631 .13668 .002 .13718 .11 57021 *.633 1*8.371 3.6381 .9979 .3621* .13*01 .001 .13533 .*3 57022 *.633 1*8.668 3.6307 .9979 .*2503 .13390 .002 .13*98 .18 57023 *.633 1*9.180 3.6180 .9979 .*9332 .13**9 .001 .13515 .33 5702* *.633 1*9.601 3.6076 .9979 .56686 .13*75 .001 .13507 .29

57025 3.251 1*8. *93 2.5770 .9979 .36219 .1317* .002 .13296 .30

57026 3.251 1*8.892 2.5699 .9979 .*2539 .13215 .001 .1330* .37 57027 3.251 1*9.205 2.56** .9979 .*9352 .132** .001 .13308 .*1 57028 3.251 1*9. 6*7 2.5567 .9979 .56723 .13283 .001 .13311 .*5 57029 1.909 1*8.308 1.5296 .9979 .30*56 .12936 .002 .13072 .18 57030 1.909 1*8.606 1.5265 .9979 .36251 .12965 .002 .13077 .22 57031 1.909 1*9.102 1.5213 .9979 .*2561 .13017 .001 .13089 .32 57032 1.909 1*9.51* 1.5171 .9979 .*9*18 .13050 .001 . 13089 .33 57033 .989 1*8.303 .7969 .9979 .30*58 .12871 .003 .13008 .77 5703* .989 1*8.67* .79*9 .9979 .36252 .12858 .003 .12965 .*5 57035 .989 1*9.070 .7928 .9979 .*2567 .12929 .002 .1300* .75 57036 .989 1*9. 5*2 .7903 .9979 .*9*20 .12973 .002 .13010 .80

21
Experimental AdJ. Thermal Conductivity

Ther ma

1

Nom. Temperature deviation

Run Pt. Pressure Temperature Density para Power Conduct 1 v 1 ty STAT 150.0 K exp. -cal c. NPa K mo 1 / L fraction W / m W/m.K W/m.K percent

'7037 67.238 148.553 29.6486 .8395 .80988 .23443 .001 .23573 -.07

57038 67.237 148.823 29.6183 .8394 .90293 .23495 .001 .23601 .15

5 7039 67.236 149.427 29.5514 .8393 1.10476 .23455 .001 .23507 -.04

57040 67.233 149.774 29.5124 .8392 1.21290 .23430 .001 .23450 -.16

57041 62.544 148.652 28.5701 . 8380 .81012 .22640 .001 .22760 -.22

57042 62.547 148.884 28.5450 .8379 .90317 .22743 .001 .22842 .22 57043 62.548 149.525 28.4741 .8378 1.10540 .22700 .001 .22742 .00 57044 62.549 149.867 28.4367 .8377 1.21404 .22682 .001 .22694 -.09

57045 59.169 148.70? 27.7525 .8365 .81034 .22192 .002 .22306 .28 57046 59.172 148.898 27.7314 .8364 .90318 .22151 .001 .22248 .08 57047 59.173 149.614 27.6524 .8363 1.10558 .22163 .001 .22197 .09 57048 59.174 149.904 27.6206 .8362 1.21424 .22159 .001 .22167 .06 57049 55.839 148.394 26.9450 .8352 .72241 .21537 .001 .21677 -.15

57050 55.841 148.739 26.9073 .8351 .81019 . 21534 .001 .21644 -.19

57051 55.843 149.335 26.8414 .8350 1.00217 .21554 .001 .21612 -.14

57052 55.846 149.638 26.8087 .8349 1.10550 .21600 .001 .21631 .05 57053 52.246 148.551 25.9689 .8338 .72292 .20960 .001 .21085 -.03

57054 52.249 148.851 25.9363 .8337 .81086 .20995 .001 .21094 .11 57055 52.251 149.423 25.8735 .8336 1.00242 .20997 .001 .21047 .07 57056 52.253 149.733 25.8399 .8335 1.10609 .20985 0.000 .21008 -.02

57057 48.865 148.599 25.0083 .8325 .72275 . 20402 .001 .20522 .04 57058 48.868 149. C81 24.9557 .8324 .81092 .20415 .001 .20493 .05 57059 48.869 149.454 24.9150 .8323 1.00273 .20406 .001 .20453 -.03

57060 48.870 149.842 24.8727 . 8322 1.10663 .20467 .001 .20480 .23 57061 45.353 149.400 23.9766 .8311 .64032 . 19797 .001 .19932 .04 57062 45.355 148.593 23.9559 .8310 .72297 .19807 .001 .19926 .07 57063 45.357 149.270 23.8820 .8309 .90440 .19781 .001 .19843 -.14

57064 45.359 149.496 23.8580 .8308 1.00285 .19864 .001 .19907 .25 57065 41.808 148.481 22.8329 .8297 .64042 .19157 .001 .19284 -.11

57066 41.809 148.679 22.8117 .8296 .72317 .19183 .001 .19293 -.00

57067 41.811 149.382 22.7358 .82 95 .90480 .19164 .001 .19216 -.20

57068 41.812 149.648 22.7075 .8294 1.00351 .19223 .001 .19252 .07 57069 36.361 148.490 21.6514 . 8282 .64076 .18614 .001 .18739 .19 57070 38.362 148.821 21.6162 .8281 .72361 .18621 .001 .18719 .17 57071 38.364 149.491 21.5449 .8280 .90537 . 18654 .001 .18696 .24 57072 38.365 149.776 21.5150 .8279 1.00423 .18603 .001 .18622 -.08

57073 34.820 148.301 20.3686 .8268 .56320 .17928 .001 .18067 -.13

57074 34.822 148.661 20.3314 . 8267 .64104 .17959 .001 .18069 -.03

57075 34.823 149.183 20.2769 .8266 .81236 . 18010 .001 .18077 .16 57076 34.824 149.602 20.2334 . 8266 .90597 .17983 .001 .18016 -.07

57077 31.396 148.377 19,0027 .8255 .56343 .17375 .001 .17507 .15 57078 31.398 148.686 18.9715 . 8254 .64109 .17402 .001 . 17509 .23 57079 31.398 149.382 18.9006 .8253 .81284 .17405 .001 .17455 .10 57080 31.399 149.727 18.8659 .8252 .90661 .17426 .001 .17448 .15 57081 27.893 148.479 17.4904 .8242 .56365 .16716 .002 .16838 -.09

57082 27.894 148.817 17.4575 .8241 .64155 .16747 .002 .16842 .01 57083 27.898 149.505 17.3906 .8240 .81334 .16833 .001 .16873 .35 57084 27.897 149.850 17.3572 .8239 .90720 .16850 .001 .16862 .36 57085 27.889 148.606 17.4759 .7908 .56374 .16472 .001 .16583 -.88

57086 27.889 148.833 17.4535 .7908 .64183 .16522 .001 .16615 -.63

57087 27.889 149.469 17.3908 .7907 .81370 .16576 .001 .16618 -.46

57088 27.889 149.836 17.3551 .7906 .90766 .16580 .001 .16593 -.53

57089 24.286 148.124 15.8426 .7897 .49126 .15812 .001 .15960 -.91

57090 24.287 148.500 15.8076 .7896 .56419 .15850 .001 .15968 -.77

57091 24.288 149.243 15.7389 .7895 .72567 .15910 .001 .15970 -.61

57092 24.288 149.574 15.7086 .7895 .81439 .15930 .003 .15964 -.58

57093 21.442 148.284 14.3941 .7885 .49160 .15362 .002 .15496 -.61

57094 21.442 148.515 14.3739 .7884 .56433 .15355 .001 .15471 -.73

57095 21.444 149.305 14.3051 .7883 .72610 .15455 .001 .15509 -.33

57096 21.444 149.660 14. 2746 .7883 .81494 . 15469 .001 .15496 -.35

57097 19.315 148.368 13.2480 .7872 .49151 .15010 .001 .15137 -.48

57098 19.316 148.634 13.2261 .7871 .56429 .14998 .001 .15104 -.65

57099 19.316 149.047 13.1920 .7871 .64267 .14977 .002 .15051 -.93

57100 19.317 149.452 13.1589 .7870 .72617 .15040 .001 .15083 -.65

57101 17.231 148.450 12.0664 .7860 .49188 .14658 .001 .14778 -.40

57102 17.232 148.656 12.0506 .7859 .56474 .14646 .001 .14750 -.55

57103 17.232 149.103 12.0162 .7859 .64331 .14677 .001 .14747 -.51

57104 17.232 149.526 11.9837 .7658 .72695 .14707 .001 .14744 -.46

57105 15.026 148.615 10.7457 .7845 .49211 .14287 .001 .14394 -.35

57106 15.027 149.807 10.7326 .7844 .56498 .14288 .001 .14380 -.42

57107 15.027 149.286 10.6990 .7843 .64346 .14292 .001 .14347 -.58

57108 15.028 149.636 10.6748 .7843 .72724 .14329 .001 .14357 -.46

57109 13.084 148.552 9.5389 .7832 .49199 .13947 .001 .14058 -.34

57110 13.084 149.020 9.5096 .7832 .56532 .13961 .002 .14036 -.44

57111 13.084 149.340 9.4895 .7831 .64370 .13989 .001 .14040 -.37

57112 13.084 149.827 9.4589 .7830 .72768 .14019 .001 .14032 -.37

57113 11.011 148.337 8.1977 . 7821 .42426 .13631 .001 .13758 .05 57114 11.011 148.702 8.1774 .7820 .49227 .13625 .001 .13724 -.16

57115 11.011 149.067 8.1573 .7819 .56553 .13637 .001 .13708 -.24

22
37116 11.011 169.510 8.1332 .7819 .66609 .13686 .001 .13726 -.08

37117 9.016 168.367 6.8315 .7809 .62652 .13261 .001 .13387 -.19

57118 9.016 168.871 6.8071 .7808 .69271 .13295 .001 .13381 -.19

57119 9.016 169.268 6.7896 .7807 .56599 .13277 .002 .13336 -.51

57120 9.016 169.607 6.7733 .7807 .66639 .13360 .001 .13370 -.21

57121 6.705 168.535 5.1750 .7796 .62668 .12906 .001 .13015 -.08

57122 6.705 168.931 5.1610 .7795 .69303 .12973 .001 .13056 .26 57123 6.705 169.366 5.1657 .7796 .56635 .12987 .001 .13035 .13 57126 6.705 169.869 5.1287 .7796 .66515 .13023 .001 .13036 .15 57125 6.660 168.282 3.6609 .7786 .36201 .12578 .001 .12708 .11 57126 6.660 168.675 3.6510 .7783 .62503 .12598 .001 .12698 .05 57127 6.660 169.223 3.6373 .7783 .69336 .12637 .001 .12696 .05 57128 6.660 169.558 3.6290 .7782 .56679 .12676 .001 .12710 .17 37129 2.627 168.570 2.0906 .7776 .36228 .12259 .001 .12367 -.03

57130 2.627 168.968 2.0853 .7773 .62537 .12293 .001 .12373 .02 57131 2.627 169.396 2.0789 .7772 .69366 .12329 .001 .12375 .05 57132 2.627 169.880 2.0721 .7772 .56728 .12381 .001 .12390 .19

Exper i mental Ad J. Thermal Conduct 1 v 1 ty

Thermal Norn. Tempera t ure deviation

Run Pt. Pressure Temperature Dens 1 ty para Poue r Conductl vl ty STAT 250.0 K exp. -calc.

HP* K mol /L Tract Ion W / W/a.K W/m.K pe rcent

53002 66.968 256.020 21.1381 .8675 .66329 .26196 .001 .26016 -.02

53003 66.969 256.732 21.0976 .8673 .90091 .26212 .001 .26000 .01 53006 66.968 255.690 21.0565 .8670 1.17560 .26207 .001 .23961 -.05

53007 63.632 256.635 20.3776 .8665 .77762 .23799 .001 .23602 -.06

53008 63.632 255.139 20.3380 .8663 1.03356 .23763 .001 .23535 -.26

53009 63.632 255.682 20.3188 .8661 1.17552 .23829 .001 .23585 .02 53011 59.925 256.016 19.6379 .8617 .66326 .23633 .002 .23256 .10 53012 59.926 256.660 19.6162 .8615 .77760 .23387 .001 .23191 -.12

53013 59.926 255.219 19.5713 .8616 1.03335 .23390 .001 .23160 -.17

53016 59.922 255.560 19.5526 .8612 1.17525 .23631 .001 .23186 -.01

53016 56.565 256.096 18.8752 .8369 .66318 .23061 .001 .22862 .06 53017 56.566 256.391 18.8590 .83 67 .77761 .23050 .001 .22858 .06 53018 56.563 255.187 18.8159 .8366 1.03369 .23109 .002 .22882 .26 53019 56.562 255.607 18.7931 .8366 1.17526 .23066 .001 .22819 .03 53021 53.106 256.170 18.0607 .8339 .66316 .22636 .002 .22655 -.05

53022 53.105 256.571 18.0393 .8338 .77722 .22636 .002 .22635 -.10

53023 53.106 255.300 18.0007 .8336 1.03358 .22622 .001 .22392 -.21

53026 53.103 255.765 17.9761 .8336 1.175C9 .22701 .001 .22651 .10 53026 69.500 256.162 17.1828 .8312 .66315 .22258 .002 .22079 .06 53027 69.699 256.603 17.1591 .8311 .77726 .22270 .001 .22072 .05 53028 69.698 255.378 17.1191 .8309 1.03351 .22276 .001 .22066 .01 53029 69.698 255.862 17.0956 .8307 1.17519 .22281 .001 .22029 -.01

53031 60.370 253.953 16.7905 . 8281 .55775 .21236 .002 .21069 -.10

53032 60.369 256.226 16.7775 .8279 .66315 .21329 .001 .21151 .31 53033 60.368 255.091 16.7369 .8277 .90077 .21250 .001 .21035 -.16

53036 60.367 255.520 16.7167 .82 76 1.03363 .21330 .001 .21097 .17

53036 36.797 253.920 13.7766 .8252 .55787 .20886 .002 .20722 .07

53037 36.796 256.291 13.7596 .8251 .66301 .20885 .001 .20705 .02 53038 36.796 255.105 13.7233 .8269 .90082 .20965 .001 .20731 .21 53039 36.795 255.606 13.7011 .8267 1.03330 .20929 .001 . 20696 .07 53061 33.258 253.980 12.7215 .7510 .55728 .20329 .002 .20157 -.22

53062 33.258 256.373 12.7068 .7508 .66258 .20362 .002 .20173 -.11

53063 33.258 255.137 12.6727 .7507 .90023 .20353 .001 .20131 -.26

53066 33.257 255.621 12.6526 .7505 1.03270 .20610 .001 .20167 -.05

53066 29.812 253.751 11.6583 .7686 .55697 .19920 .002 .19759 -.62

53067 29.812 256.218 11.6399 .7686 .66188 .19927 .002 .19766 -.66

53068 29.811 255.113 11.6066 .7683 .89921 .20022 .001 .19802 -.11

53069 29.811 255.576 11.5866 .7682 1.03161 .20025 .001 .19785 -.17

53051 26.260 253.511 10.5031 .7662 .66106 .19696 .003 .19366 -.68

53052 26.260 253.825 10.6916 .7661 .55699 .19552 .002 .19386 -.63

53053 26.239 256.675 10.6603 .7659 .77636 .19596 .002 .19396 -.36

53056 26.239 255.139 10.6636 .7658 .89966 .19638 .001 .19618 -.20

53056 22.961 253.566 9.3753 .7660 .66095 .19276 .002 .19123 -.07

53057 22.960 253.865 9.3651 .7639 .55706 .19296 .002 .19132 -.01

53058 22.939 256.733 9.3355 .7638 .77621 .19260 .001 .19039 -.65

53059 22.938 255.179 9.3206 .7636 .89970 .19280 .001 .19060 -.32

53061 19.378 253.535 8.1019 .7615 .66121 .18837 .002 .18687 -.68

53062 19.376 253.963 8.0896 .7613 .55731 .18882 .002 . 18715 -.31

53063 19.376 256.852 8.0629 .7611 .77669 .18906 .002 .18700 -.35

53066 19.375 255.522 8.0633 .7609 .89975 .18910 .001 .18676 -.65

53066 15.867 253.665 6.7828 .7385 .66131 .18510 .002 .18356 -.38

53067 15.866 256.016 6.7735 .7386 .55731 .18599 .002 .18630 .03

53068 15.866 256.885 6.7517 .7382 .77685 .18571 .002 .18365 -.29

53069 15.866 255.621 6.7386 .7381 .90023 .18603 .002 .18376 -.22

53071 13.129 253.707 5.7113 .7339 .66136 .18216 .002 .18058 -.53

53072 13.128 256.116 5.7026 .7337 .55726 .18278 .002 .18106 -.25

53073 13.128 256.937 5.6850 .7336 .77696 .18357 .002 .18169 .01 53076 13.128 255.520 5.6727 .7335 .90051 .18367 .001 .18136 -.05

53076 10.997 253.720 6.8506 .7317 .66135 .18037 .002 .17880 -.36

53077 10.997 256.162 6.8623 .7315 .55727 .18061 .002 .17886 -.32

53078 10.997 256.656 6.8332 .7316 .66261 .18083 .002 .17887 -.30

53079 10.996 255.113 6.8268 .7313 .77666 .18156 .001 .17939 -.00

23
5 3001 8.968 253.900 4.0136 . 7294 .46114 .17850 .003 .17686 -.37

53082 8.9«7 254.291 4.0072 .7292 .55722 .17857 .002 .17676 -.41

53083 8.987 254 .778 3.9998 .7290 .66240 .17921 .002 .17720 -.15

53084 8.986 255.226 3.9927 .7208 .77680 .17948 .002 .17728 -.10

5 3065 6.828 253.903 3.0924 .7271 .46119 . 17667 .003 .17503 -.24

53087 6.828 254.294 3.0876 . 7269 .55726 .17689 .002 .17509 -.20

53088 6.828 254.845 3.0810 .7268 .66227 .17694 .002 .17490 -.30

53089 6.827 255.342 3.075C .7267 . 77652 .17712 .902 .17487 -.31

53091 4.791 253.932 2.1986 .7248 .46176 .17411 .003 .17246 -.62

53092 4.790 254 .385 2.1944 .7246 .55781 .17498 .002 .17314 -.22

53093 4.790 254.952 2.1896 .7244 .66315 .17504 .002 .17296 -.32

53094 4.790 256.495 2.1849 .7242 .77750 .17562 .002 .17331 -.10

53096 2.782 253.984 1.2935 .7221 .46160 .17358 .006 .17191 .15 53097 2.7*2 254.454 1.2909 .7220 .55769 .17301 .005 .17114 -.29

53093 2.781 254.978 1.2880 .7218 .66303 .17325 .004 .17116 -.27

53099 2.781 255.503 1.2852 .7216 .77743 .17396 .004 .17165 .02 53101 .8 41 253 .610 .3966 .7187 .37459 .17174 .008 .17022 .25 53102 .841 254.033 . 3960 .7186 .46161 .17150 .006 .16981 .01 53103 .840 254.567 .3948 .7184 .55771 . 17173 .007 .16981 .01 53104 .840 255.105 .3940 .71 83 .66302 .17220 .006 .17005 .16 Exper 1 mental AdJ. Thermal Conduct 1 v Ity Therma 1 Norn. Temperature deviation

Pun Pt. Pressure T e«nsr ature Dens 1 1 y para Power Conduct! y 1 ty STAT 250.0 K exp. -calc.

MPa K mol /L tract Ion H /if W/m.K W/m.K percent

53105 12.019 252.681 5.2867 .9979 .45959 .18528 .002 .18431 -.54

53106 12.010 252.985 5.2806 .9979 .55537 .18577 .002 .18469 -.32

531C7 12.019 253.467 5.2711 .9979 .66012 .18549 .002 .18424 -.56

53108 12.019 253.963 5.2612 .9979 .77390 .18620 .002 .18477 -.26

53109 12.019 254.473 5.2512 .9979 .89710 . 18613 .001 .18451 -.38

53110 10.479 252.774 4.6541 .9979 .45944 .18345 .003 .18245 -.76

53111 10.479 253.087 4.6485 .9979 .55512 .18407 .002 .16296 -.47

53112 10.479 253.528 4. 6408 .9979 .65996 .18406 .002 .18279 -.55

53113 10.479 254.015 4.6321 .9979 .77374 .18465 .002 .18320 -.32

53114 9.030 252.700 4.0499 .9979 .45959 .18249 .003 .18152 -.52

53115 9.030 253.131 4.0433 .9979 .55517 .18302 .002 .18189 -.30

53116 9.030 253.529 4. 0368 .9979 .66009 .18291 .002 .18164 -.44

53117 9.029 254.062 4.0285 .9979 .77384 .18311 .001 .18165 -.42

53116 7.516 252.672 3.4047 .9979 .45962 .18075 .003 .17979 -.70

53119 7.516 253.120 3. 3987 .9979 .55518 .18127 .002 .18015 -.49

53120 7.515 253.664 3.3915 . 9979 .65989 .18099 .002 .17967 -.74

53121 7.515 254.108 3.3857 .9979 .77383 .18155 .002 .18007 -.51

63122 6.123 252.758 2.7982 .9979 .45949 .17922 .003 .17823 -.85

53123 6.123 253.202 2.7934 .9979 .55505 .17955 .002 .17840 -.74

53124 6.123 253.664 2.7882 .9979 .65982 .18024 .002 .17693 -.44

53125 6.122 254.160 2.7828 .9979 .77372 .18023 .002 .17874 -.54

53126 4.689 252.851 2.1621 .9979 .45942 .17824 .002 .17722 -.67

53127 4.688 253.306 2.1581 .9979 .55499 .17831 .002 .17713 -.72

53128 4.6*8 253.787 2.1541 .9979 .65988 .17871 .002 .17735 -.58

53129 4.668 254.271 2.1499 .9979 .77377 .17917 .002 .17764 -.42

53130 3.308 252.879 1. 5393 .9979 .45935 .17756 .004 .17653 -.34

53131 3.306 253.388 1.5362 .9979 . 55501 .17755 .004 .17634 -.45

53132 3.307 253.789 1.5335 .9979 .65990 .17757 .003 .17622 -.52

53133 3.307 254.400 1.5299 .9979 .77365 .17766 .003 .17609 -.59

53135 1.979 253.010 .9286 .9979 .45936 .17699 .006 .17592 .00 53136 1.979 253.452 .9267 .9979 .55499 .17804 .005 .17681 .51 53137 1.979 254 .CIO .9247 .9979 .65977 .17779 .004 .17636 .26 53138 .862 252. *26 .4084 .9979 .37263 . 17607 .007 .17517 .16 53139 .862 252.885 .4077 .9979 .45925 .17601 .006 .17498 .06 53140 .862 253.399 .4067 .9979 .55489 .17576 .006 .17455 -.19

53141 .861 253.971 .4056 .9979 .65955 .17626 .006 .17484 -.02

Exper 1 mental AdJ. Thermal Conduct 1 v i ty

Therma

1

Mom. Temperature deviation

Run Pt. Pressure Temperature Oens 1 ty para Power Conduct 1 v 1 ty STAT 275.0 K exp. -calc.

MPa K mo 1 / L tract Ion W/m W/m.K W/m.K percent

52025 65.619 272.048 19.8873 .7425 .49750 .24126 .003 .24261 -.30

52026 65.617 272.575 19.8599 .7424 .71468 .24215 .002 .24326 .03 52027 65.617 273.340 19.8206 .7422 .97075 .24204 .001 .24280 -.08

52028 65.615 274.217 19.7755 .7420 1.26586 .24266 .001 .24302 .11 52029 62.103 272.306 19.1437 .7407 .60111 .23853 .002 .23975 .09 52030 62 .103 272.663 19.1257 .7405 .71438 .23850 .002 .23956 .05 52031 62.101 273.330 19.0919 .7404 .97065 .23890 .002 .23966 .16 52032 62.101 274.242 19.0461 .7402 1.26574 .23878 .001 .23912 .03 52034 58.809 272.948 18.4042 .7307 .83759 .23488 .002 .23580 -.04

52035 58.808 273.809 18.3616 .7386 1.11297 .23493 .001 .23546 -.10

52036 58.807 274.268 18.3389 .7384 1.26559 .23528 .001 .23561 .01 52037 55.039 272.605 17.5811 .7371 .71444 .23100 .002 .23207 .01 52038 55.037 273.099 17.5571 .7369 .83722 .23132 .001 .23217 .10 52039 55.036 273.847 17.5210 .7368 1.11311 .23138 .001 .23189 .05 52040 55.036 274.315 17.4986 .7366 1.26567 .23163 .001 .23194 .12 52041 51.614 272.695 16.7846 .7353 * .71427 .22755 .001 .22857 .05 52042 51.613 272.992 16.7704 .7351 .83736 .22786 .002 .22875 .15

24
5 2043 51 .612 273.921 16.7268 .7350 1.11276 .22790 .001 . 22838 .07 5204* 51.611 274.372 16.7058 .7348 1.26550 .22793 .001 .22821 .04 52045 48.126 272.730 15.9452 .7335 .71409 .22426 .002 .22526 .18 52046 48.125 273.137 15.9266 .7333 .83696 .22404 .001 .22486 .03 52047 48.124 273.948 15.3897 .7332 1.11248 .22464 .001 .22510 .21 52048 4P.122 274.406 15.8687 .7330 1.26524 .22447 .001 .22473 .09 52040 44.583 272.690 15.0625 .7317 .71416 .22029 .001 .22130 .02 52050 44.582 273.142 15.0424 .7316 .83696 .22056 .001 . 22137 .09 52051 44.580 274.061 15.0020 .7314 1.11257 .22085 .001 .22126 .12 52C52 44 . 5«C 274.515 14.9823 .7313 1.26505 .22088 .001 .22109 .08 52053 41 .045 27 2 .392 14.1554 .7299 .60071 .21635 .002 .21748 -.11

52054 41 .044 272.751 14. 1400 .7298 .71397 . 21680 .002 .21777 .06

52055 41.042 273.616 14.1035 .7297 .96972 .21736 .001 .21796 .21 52056 41.041 274.051 14.0851 .7295 1.11255 .21724 .001 .21765 .10 52057 37.572 272.436 13.2131 .7282 .60072 . 21342 .002 .21452 .14 52050 37.571 272.731 13.2009 .7280 .71406 .21344 .002 .21442 .12 52059 37.570 273.664 13.1636 .7279 .96902 .21390 .001 .21447 .21 52060 37.569 274.132 13.1440 .7278 1.11246 .21401 .001 .21438 .20 52061 33.985 272.606 12. 1940 .7264 .60049 . 20903 .002 .21005 -.27

52062 33.984 272.866 12.1838 .7263 .71397 .20960 .002 .21051 -.04

52063 33.983 273.823 12.1477 .7261 .96968 .20990 .001 .21040 -.03

52064 33.983 274.217 12.1328 .7260 1.11255 . 21036 .001 .21069 .13 52065 30.464 272.508 11.1601 .7246 .60087 .20632 .002 .20708 -.05

52066 30.463 273.015 11.1421 .7245 .71420 .20644 .002 .20728 .08 52067 30.463 273.988 11 .1078 .7244 .97000 .20629 .001 .20672 -.14

52068 30.462 274.360 11.0946 .7242 1.11332 . 20702 .001 .20729 .16 52069 27.070 272.635 10.1129 .7230 .60099 .20235 .003 .20335 -.26

52070 27.070 273.006 10.1007 .7220 .71425 .20324 .002 .20408 .12 52071 27.068 273.051 10.0697 .7227 .97040 . 20311 .001 .20355 -.09

52072 27.067 274.414 10.0544 .7225 1.11349 .20375 .001 .20400 .15

52073 23.529 272.677 8.9761 .7212 .60109 .20002 .002 .20100 .25 52074 23.528 273.105 0.9631 .7211 .71425 .19960 .002 .20040 -.03

52075 23.527 274.059 8.9349 .7210 .97037 . 19994 .002 .20034 -.02

52076 23.527 274.627 8.9181 .7208 1.11294 .20031 .001 .20047 .07 52077 19.963 272.318 7.7901 .7195 .49753 .19608 .003 .19720 .02 52076 19.963 272.726 7. 7792 .7194 .60094 .19637 .002 .19732 .10 52079 19.962 273.620 7.7558 .7192 .83737 .19637 .002 .19695 -.06

52080 19.960 274.175 7.7409 .7191 .97027 .19664 .001 .19699 -.02

52081 16.435 272.438 6.5496 .7177 .49747 .19283 .003 . 19390 .01 42082 16.435 272.804 6.5412 .7176 .60093 .19286 .002 .19378 -.05

52083 16.434 273.801 6.5188 .7175 .83737 .19370 .002 .19420 .20 52004 16.434 274.273 6.5083 .7174 .97039 .19391 .001 .19421 .22 52085 13.093 272.528 5.3230 .7161 .49757 .19012 .002 . 19115 .16 52086 13.092 272.973 5.3153 .7160 .60087 .19017 .002 .19101 .10

52087 13.091 273.858 5.2987 .7158 .83755 .19032 .002 .19079 .01 52088 13.090 274.498 5.2867 .7157 .97050 .19074 .002 .19095 .11

Exoerl mental AdJ. Therma 1 C onduct 1 v 1 ty Therma 1 Nom

.

Temper a tur e deviation

Run Pt. Pressure T emperature Oens 1 ty para Power Conduct 1 » 1 ty STAT 275.0 K exp. -calc.

MPa K m o 1 / L f ract Ion U/r rf/m.K W/m.K percent

52001 12 .400 272.024 5.0724 .9979 .49695 .19311 .002 .19419 .18 52002 12.398 272.454 5.0642 .9979 .59991 .19167 .002 .19259 -.64

520C3 12.398 272.968 5.0551 .9979 .71325 .19341 .002 . 19415 .18 52004 12.398 273.473 5.0462 .9979 .83616 .19325 .002 .19380 .01 52005 10.365 272.095 4.2925 .9979 .49652 .19059 .003 .19164 -.20

52006 10.365 272.535 4.2857 .9979 .59982 .19059 .003 .19148 -.28

52007 10. 365 273.025 4.2784 .9979 .71285 .19115 .002 .19186 -.07

52008 10.365 273.520 4.2709 .9979 .83565 .19121 .002 .19175 -.12

52009 8.093 272.134 3.3986 .9979 .49638 .18855 .003 .18958 -.23

52010 8.092 272.602 3.3928 .9979 . 59954 . 19882 .003 .18969 -.17

52011 8.092 273.057 3.3872 .9979 .71305 .18825 .002 .18895 -.56

52012 8.092 273.589 3.3807 .9979 .83615 .18918 .002 .18969 -.16

52013 6.030 272.139 2.5650 .9979 .49698 .18696 .002 .18799 -.13

52014 6.030 272.603 2.5608 .9979 .60034 .18675 .002 .18761 -.32

52015 6.029 273.153 2.5554 .9979 .71346 .18714 .002 .18781 -.21

52016 6.029 273.685 2.5506 .9979 .83655 .18724 .002 .18771 -.26

52017 3.888 272.391 1.6750 .9979 .49698 .18496 .003 .18590 -.26

52018 3.888 272.939 1.6715 .9979 .60031 .18555 .002 .18629 -.04

52019 3.888 273.455 1.6684 .9979 .71361 . 18581 .002 .18637 .00

52020 3.088 274.059 1.6646 .9979 .83650 .18596 .002 . 10630 -.0)

52021 1.836 272.003 .8023 .9979 .40317 .18304 .004 .18412 -.27

52022 1 .836 272.426 .8009 .9979 .49653 .18314 .004 .18406 -.30

52023 1.836 272.781 .7999 .9979 .60008 .18338 .004 .18418 -.23

52024 1.836 273.399 . 7981 .9979 .71265 .18396 .003 . 18463 -.04

25
3. Methane Results

A total of 900 points are given in Table 3. The results are reported in [9].

The computer programs developed for the thermal conductivity surface of methane are shown below. The equation of state used for methane is given in [8].

FUNCTION CH4TC ( RH 0 , T

)

DIMENSION A ( 4 ) , B ( 9 ) C CO EF FROM TC021 AND MINIMS, 31 MAR 84 2ND PASS

DATA A/-.8863333440E-02

1 , .2419639784E-03 , - .6997019196E-06 , .1224609018E-08/

DATA B/

1 .2773027550E-02 , - .2477683184E-05 1458682 1 98E + 02

1 . 198276037 IE-01 ,

. 100966 501 0E-03 , - . 2 5 9546 030 6E- 07

1 ,

. 369 1 5053 1 5E + 01 , .6857505926E-02 3009401 784E-04/

TERM1=A(1)+A(2)*T+A(3)*T**2+A(4)*T**3

TERM2=(B(1)+B(2)*T)*RH0

BEE=EXP(B(3)+B(4)*T+B(5)*T**2+B(6)*T**3)

ENN=B(7)+B(8)*T+B(9)*T**2

TERM3=BEE*RH0**ENN

CH4TC=TERM1+TERM2+TERM3+CH4CRIT(RH0,T)

RETURN

END

FUNCTION CH4CRIT(RH0,TEMP)

DIMENSION C ( 6

)

C COEF FROM TC021 AND MINIMS, 31 MAR 84 2ND PASS

DATA C/ .2054937228E+00

1 . 1850000000E + 03 ,

. 9 5 1 7 5406 80E - 02 , - . 2 94448 1 2 20E -04

1 .2244399588E+00 , . 1 7 207 10 404 E+00 / DATA (TC = 190.555) ,(RH0C = 10.0)

T=TE MP DEN=RH0

IF(T.LT.TC) T=TC+ ( TC-T

)

IF(T.LT.377.991) GO TO 4 CH4CR IT = 0 . RETURN

4 CONTINUE

AMP L= C ( 1 ) / ( T+C ( 2 ) )+C(3)+C(4)*T

DELRH0=DEN-RH0C

X 1 = C ( 5

) *D EL RHU

IF(DEN.GT.IO.O) XI = C ( 6

) *DEL RHO

C H4C R IT=AMP L* EXP (-X 1**2)

RETURN

END

26
Table 3. The Thermal Conductivity of Methane

Exper I mental Adjusted Thermal Conduct 1 v 1 ty

Therma

1

at a non Inal devl at Ion Sun Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 110 K fro* correlation

HPa K mo 1 / L w/m W/m.K W/m.K percent

*0020 .561 111.827 26.3519 .99832 .18427 0.000 .18371 -.50

70027 .556 111.655 26.3671 .91576 .18476 0.000 .18425 -.36

70026 .551 111.255 26.4032 . 03558 .18475 .001 .18436 -.68

7C025 .546 110.983 26.4275 .75983 .18512 .001 ,ie482 -.69

70C24 11.644 111.762 26.9517 .9973 8 .19681 .001 .19623 -.14

70023 11.641 111.363 26.9838 .91369 .19679 .001 .19634 -.42

70022 11.635 111.215 26.9955 .83522 .19754 .001 .19714 -.13

70021 11.630 110.985 27.0138 .75969 .19758 .001 .19725 -.26

70020 22.698 111.768 27.4612 1.08182 .20704 .001 .20643 -. 36 70019 22.693 111.688 27.4569 .99618 .20762 0.000 .20703 -.12

70018 22.688 111 .301 27.4951 .91297 .20775 0.000 .20730 -.29

70017 22.682 111.173 27.5043 .83448 .20846 0.000 .20805 -.02

70016 34.119 111.613 27.9245 1.08073 .21681 0.000 .21622 -.52

70015 34.117 111.472 27.9339 .99554 .21779 0.000 .21725 -.14

70014 34.112 111.231 27.9499 .91203 .21761 .001 .21716 -.35

70013 34.109 110.997 27.9655 .83355 .21796 0.000 .21759 -.31

70012 44.939 111.508 28.2995 1.07935 .22569 0.000 .22511 -.36

70011 44.932 111.347 28.3092 .99349 .22602 0.000 .22550 -.29

70010 44.926 111.101 28.3243 .91114 .22624 0.000 .22582 -.30

70009 44.920 110.863 28.3387 .83233 .22667 .001 .22634 -.22

70008 56.744 111.433 28.6493 1.07906 .23494 .001 .23437 .07 70007 56.740 111.101 28.6635 .99259 .23517 .001 .23470 .06 70006 56.735 110.963 28.6757 .91048 .23542 .001 .23503 .08 70005 56.726 110.745 28.6879 .83168 .23554 .001 .23524 .04 70004 68.635 111.218 28.9598 1.07687 .24325 .001 .24275 .38 70003 69.639 111.104 28.9658 .99131 .24368 .001 .24322 .52 70002 68.647 110. e94 28.9771 .90959 .24381 .001 .24344 .49 70001 68.659 110.631 2°. 9911 . 83064 .24405 .001 .24379 .49

Expe r 1 rent a 1 Adjusted Thermal Conduct 1 v 1 ty Thermal at a nominal deviation

Run Pt. Pressure Temperature Density Power Conduc t i v 1 ty STAT Temperature of 135 K from correlation

HPa K mo 1 /L V/m W/ai.K W/m.K percent

73028 .316 134.645 . 3021 .05668 .01483 .003 .01487 .16 73027 .316 134.119 .3035 .04600 .01475 .005 .01486 .02 73026 .315 133.606 .3038 .03644 .01475 .007 .01492 .43 73025 .314 133.127 .3048 .02801 .01471 .009 .01494 . 54 69028 .778 135.369 24.0430 .88406 .15136 .001 .15128 .26 69027 .772 135.054 24.0767 .79706 .15181 .001 .15180 .27 69026 .761 134.663 24.1181 .71438 .15203 .001 .15210 .04 69025 .745 134.383 24.1468 .63671 .15245 .001 .15258 .06

69024 11.718 135.395 24.9494 .97511 .16643 .001 .16634 .35 69023 11.715 135.072 24.9780 .88321 .16687 .001 .16685 .36 69022 11.709 134.724 25.0086 .79593 .16708 .001 .16715 .22 69021 11.694 134.433 25.0335 .71378 .16755 .001 .16768 .28 69020 22.964 135.255 25.6876 .97428 .17951 .001 .17945 .25 69019 22.963 134.855 25.7189 . 68273 .18009 .001 .18013 .30 69018 22.961 134.596 25.7390 .79537 .17996 .001 .18006 .06 69017 22.959 134.300 25.7620 .71306 .18038 .001 .16056 .09 69016 34.181 135.304 26.2824 1.06951 .19082 .001 .19074 .16 69015 34.180 134.903 26.3051 .97323 .19106 .001 .19106 .09

69014 34.177 134.717 26.3239 .88175 .19153 .001 .19161 .18 69013 34.172 134.482 26.3403 .79479 .19175 .001 .19189 .16 69012 45.585 135.055 26.8156 1,06806 .20144 0.000 .20142 .07 69011 45.577 134.801 26.8319 .97227 . 20170 .001 .20176 .06 69010 45.574 134.607 26.8444 .88134 .20224 .001 .20235 .22 69009 45.564 134.390 26.8581 .79411 .20225 .001 .20242 .12 69008 56.761 135.242 27.2397 1.16753 .21085 .001 .21070 .20

69007 56.753 134.920 27. 2590 1.06714 .21114 0.000 .21116 .18 69006 56.743 134.722 27.2706 .97144 .21186 0.000 .21194 .43 69005 56.735 134.408 27.2894 .88007 .21176 .001 .21193 .23 69004 67.925 135.053 27.6305 1.16634 .21996 0.000 .21994 .40 69003 67.926 134.764 27.6468 1.06592 .22006 0.000 .22013 .32 69002 67.926 134.496 27,6620 .97010 .22036 .001 .22051 .33 69001 67.928 134.259 27.6754 .87933 .22067 0.000 .22089 .37 Exper 1 ment a 1 Adjusted There*

1

Conduct 1 v 1 ty The r n a 1 at a nominal da v 1 at 1 on Run Pt. Pressure Temperature Dens 1 ty Power Conduc 1 1 v 1 ty STAT Temperature of 145 K fro* cor r a 1 a 1 1 on MPa K mo 1 / L W/m W/a.K W/a.K P ar cant 73024 .357 145.151 .3142 .07480 .01597 .003 .01595 -.68

73023 .357 144.549 .3158 .06186 .01590 .005 .01595 -.70

73022 .357 144.034 .3171 .05020 .01584 .008 .01595 -.72

73021 .357 143.587 .3183 .03980 .01584 .010 .01600 -.41

27
73020 .650 1 ** .7*6 .6117 .07*62 .01658 .005 .01661 -1.13

73019 .650 1** .258 .61*7 .06176 .01659 .003 .01668 -.77

73018 .650 1*3.690 .6182 .05011 .01660 .005 .01675 -.37

73017 .650 1*3. *03 .6200 .03975 .01652 .006 .01671 -.67

Exper i mental Adjusted Thermal Conduct 1 v 1 ty

Therma 1 at a nominal devl at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 155 K from correlation

MPa K mol /L W/m W/m.K W/m.K percent

73011 .*29 15*. 710 .35*7 .06710 .01708 .003 .01711 -1.16

73010 .*29 15*. 129 .3563 .05**8 .01717 .006 .01727 -.26

73009 .*29 153.687 .3575 .0*320 .01697 .006 .01712 -1.16

73012 .*29 153.161 .3587 .03323 .01691 .009 .01712 -1.17

73008 .731 155.000 .63*2 .08101 .01781 .003 .01781 -1.07

73007 .731 15*. *60 .6373 .06703 .01773 .004 .01779 -1.22

73006 .731 153.993 .6*01 .05*** .01771 .006 .01783 -1.07

73005 .731 153. *93 .6*29 .0*317 .01762 .007 .01779 -1.30

7300* 1.082 15*. 611 1.0133 .08091 .01876 .003 .01880 -.76

73003 1.082 15*. 165 1.018* .06699 .01866 .00* .01875 -1.09

73002 1.082 153.622 1.0252 .05*38 .0186* .00* .01880 -.96

73001 1.082 153.277 1.0293 .0*313 .01852 .008 .01872 -1«*5

7*032 1.600 155.515 21.6615 .75753 .12179 .001 .12170 .12 7*031 1.599 155.080 21.7236 .670*2 .12260 .001 .12259 .22 7*030 1.598 15*. 711 21.7755 .58883 .12306 .001 .12311 .12 7*029 1.595 15*. 339 21.827* .5126* .123** 0.000 .12355 -.0*

7*027 6.757 155.315 22. *861 .75677 .13193 0.000 .13187 -.19

7*026 6.755 15*. 878 22.5359 .6697* .13263 .001 .13265 -.11

7*025 6.75* 15*. 565 22.5715 .58861 .1329* .001 .13302 -.19

7*028 6.757 15*. 223 22.6107 .51217 .13318 .001 .13332 -.37

7*023 1* • 577 155. *8* 23.3*3* .8*885 .1*399 0.000 .1*390 -.22

7*022 1*. 576 155.132 23.3765 .7565* .1**** 0.000 .1***2 -.20

7*021 1* . 575 15*. 797 23. *079 .66996 .1**87 .001 .1**91 -.18

7*02* 1*. 579 15*. *91 23. *370 .58816 .1*520 .001 .1*530 -.22

7*019 25.316 155.595 2*. 230* .9*55* .15793 .001 .15781 -.12

7*018 25.31* 155.239 2*. 2588 .8*799 .15829 .001 .1582* -.1*

7*017 25.310 15*. 966 2*. 2803 .75577 .15867 .001 .15868 -.09

7*020 25.318 15*. 586 24.3112 .66902 .15889 .001 .15897 -.22

7*016 36.001 155.72* 2*. 9255 1.0*788 .16952 0.000 .16937 -.23

7*015 36.001 155. *02 2*. 9*85 .9**69 .16996 0.000 .16988 -.17

7*01* 35.997 15*. 976 2*. 9786 .8*668 .17056 .001 .17056 -.08

7*013 35.978 15*. 755 2*. 9933 .75506 .17093 .001 .17098 .01 7*012 *6.637 155.563 25.5217 1. 0*7*0 .18080 .001 .18068 .07 7*011 *6.631 155.228 25.5*33 .9**03 .1809* .001 .18089 -.0*

7*010 *6.626 15*. 890 25.5652 .8*655 .181*8 .001 .18150 .07 7*009 *6.626 15*. 570 25.5861 .75*82 .18185 .001 .1819* .10 7*008 56.930 155. *19 26.0179 1.0*587 .19060 .001 .19051 .23 7*007 56.927 15*. 980 26.0*** .9*299 .19079 .001 .19079 .10 7*006 56.921 15*. 681 26.062* .8*57* .19118 .001 .19125 .16 7*005 56.919 15*. *20 26.0781 .75*25 .1915* .001 .191 67 .21 7*00* 67.027 155.151 26. *526 1. 0**80 .199*6 .001 .199*3 .31 7*003 67.028 15*. 88* 26. *679 .9*232 .199*2 .001 .199*5 .16 7*002 67.035 15*. 56* 26. *865 .8*507 .20013 .001 .20023 .36 7*001 67.0*3 15*. 23* 26.5056 .75325 .20037 .001 .20055 .32 Exper Imental Adjusted Therma

1

Conduct 1 v 1 ty Therma

1

•t a nominal devl at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 vl ty STAT Temperature of 165 K from correlation

MPe K mo I / L W/m W/m.K W/m.K percent

72028 .**6 165.2*9 .3*18 .08726 .01821 .002 .01818 -1.25

72027 .**6 16*. 627 .3*36 .07221 .01811 .003 .01815 -1.**

72026 .**6 16*. 008 .3*51 .05865 .01807 .00* .01818 -1.30

72025 .**6 163.65* .3*60 .0*651 .01803 .005 .01818 -1.31

7202* .935 16*. 789 .7705 .08715 .01912 .002 .0191* -1.69

72023 .935 16*. 336 .7739 .07215 .01912 .003 .01919 -l.*7

72022 .935 163.737 .7780 .05859 .01903 .00* .01917 -1.6*

72021 .935 163.372 .7805 .0*6*6 .01891 .006 .01909 -2.09

72020 1.657 16*. 151 1.5796 .08695 .021*1 .003 .02151 -.07

72019 1.657 163.770 1.5879 .07200 .021** .00* .02158 .17 72018 1.657 163. *35 1.595* .05850 .021*7 .005 .02165 .39 72017 1.657 163.111 1.6032 .0*6*0 .021*1 .008 .02163 .19

Exper Imental Adjusted Therma

1

Conduct 1 v 1 ty Therma 1 at a nominal dev 1 at Ion Run Pt. Pressure T emper ature Dens 1 ty Power Conduc 1 1 v 1 ty STAT Temperature of 175 K from correlation

MPa K mo 1 /L W/m W/m.K W/m.K percent

72016 .*06 175. *67 .2899 .09352 .01922 .003 .01917 -1.25

72015 .*06 17*. 780 .2911 .07739 .01909 .003 .01911 -1.55

7201* .*06 17*. 2** .2921 .06287 .01911 .00* .01920 -1.13

72013 .*06 173.672 .2932 .0*986 .01908 .006 .01923 -.96

72012 1.015 17*. 9*6 .7777 .09332 .02029 .003 .02030 -1.58

72011 1.015 17*. 370 .7812 .07730 .02015 .00* .02022 -1.99

72010 1.015 173.887 .78*6 .06280 .02015 .005 .02028 -1.76

28
72009 1.015 173.424 .7875 .04981 .02010 .007 .02020 - 1.78

73008 1.751 174.393 1.5010 .09314 .02207 .003 .02214 - 1.50

72007 1.751 173.934 1.5075 .07713 .02203 .004 .02215 - 1.54

72006 1.751 173.504 1.5156 .06260 .02216 .005 .02234 -.79

72005 1 .752 173.135 1.5227 .04975 .02194 .008 .02216 - 1.68

72004 2.4 59 173.762 2.4825 .09304 .02567 .003 .02583 2.45

72003 2.460 173.415 2.5012 .07706 .02579 .005 .02600 2.86

72002 2.461 173.064 2.5206 .06264 .02585 .007 .02610 3.04

72001 2.462 172.766 2.5379 .04973 .02528 .013 .02557 . 82 67043 2.648 175.359 18.2186 .59371 .09304 .001 .09297 2.26

67042 2.648 174.924 18.3394 .51177 .09383 .001 .09384 2.19

67041 2.547 174.506 18.4513 .43594 .09495 .001 .09505 2.52

67044 2 . 649 173.979 18.5893 .36649 .09518 .002 .09537 1.70

67039 4.616 175.226 19.1810 .59337 .09977 .001 .09973 a . oo 67038 4.616 174.785 19.2656 .51143 .10043 .001 .10047 .98 67037 4.615 174.407 19.3373 .43593 ' .10107 .001 .10117 1.04

67040 4.616 174.021 19.4102 .36631 .10129 .002 .10146 .66 67035 12.710 175.360 21.0598 .68097 .11736 .001 .11730 -.37

67034 12.708 175.020 21.0983 .59287 .11769 .001 .11769 -.42

67033 12.705 174.534 21.1532 .51103 .11818 .001 .11826 -.47

67036 12.712 174.088 21.2049 .43563 .11862 .002 .11877 -.54

67031 19.724 175.653 21.9938 .77379 .12832 .001 .12821 -.66

67030 19.722 175.178 22.0380 .67968 . 12901 .001 .12898 -.50

67029 19.720 174.793 22.0738 .59215 .12957 .001 .12960 -.38

67032 19.724 174.357 22.1148 .51049 .12980 .002 .12991 -.55

67028 26.457 175.719 22.6933 .87385 .13772 .001 .13760 -.50

67027 26.455 175.380 22.7210 .77339 .13811 .001 .13805 -.54

67026 26.450 174.924 22.7580 .67937 .13861 .001 .13862 -.49

67025 26.446 174.570 22.7867 .59182 .13879 .001 .13886 -.61

67024 33.801 175.558 23.3340 .87331 .14701 .001 .14692 -.49

67023 33.796 175.163 23.3629 .77308 .14743 .001 .14740 -.46

67022 33.792 174.813 23.3886 .67929 .14773 .001 .14776 -.47

67021 33.794 174.483 23.4131 .59172 .14827 .001 .14836 -.32

67020 41.291 175.820 23.3580 .97911 .15522 .001 .15508 -.40

67019 41.288 175.338 23.8907 .87291 .15573 .001 .15567 -.35

67018 41.285 175.061 23.9094 .77301 .15608 .001 .15607 -.29

67017 41.276 174.654 23.9367 .67921 .15653 .001 .15659 -.23

67016 48.148 175.705 24.3009 .97839 .16260 0.000 .16248 -.24

67015 48.149 175.305 24.3266 .87240 .16291 .001 .16286 -.27

67014 46.142 174.788 24.3593 .77253 .16332 .001 .16336 -.30

6 7013 48.145 174.596 24. 3718 .67878 .16348 .001 .16355 -.31

67012 55.061 175.547 24.7033 .97742 .16959 .001 .16950 -.12

67011 55.062 175.051 24.7335 .87138 .16993 .001 .16992 -.17

67010 55.058 174.704 24.7543 .77194 .17064 .001 .17069 .07 67009 55.051 174.439 24.7700 .67827 .17091 .001 .17101 .09 67007 61.637 175.386 25.0515 .97739 .17583 0.000 .17576 -.04

67006 61 .642 175.017 25.0731 .87147 .17636 .001 .17636 .08 67005 61.637 174.659 25.0936 .77164 .17657 .001 .17663 .02 67008 61 .641 174.273 25.1162 .67816 .17702 .001 .17715 .09

67004 68.363 175.485 25.3635 1.09890 .18195 0.000 .18186 .19 67003 68.360 175.204 25.3790 .97707 . 18224 .001 .18220 .22 67002 68.375 174.804 25.4018 .87098 .18235 0.000 .18238 .08 67001 68.379 174.506 25.4185 .77133 .18264 .001 .18273 .10 Exper 1 mental Adjusted Thermal Cond uc 1 1 v 1 ty Thermal at a non Inal dev 1 at 1 on Run Pt. Pressure Temperature Oens I ty Power Conduct 1 v 1 ty STAT Temperature of 185 K from cor re 1 at MPa K mo 1 /L W/m W/m.K W/m.K percent

71020 .752 1 85.421 . 5200 .08289 .02072 .003 .02067 - 2.34

71019 .752 184.903 .5218 .06734 .02077 .003 .02078 - 1.79

71018 .752 184.371 .5236 .05343 .02079 .004 .02087 - 1.40

71017 .752 183.963 .5256 .04113 .02011 .006 .02024 -4. 57 71016 1.507 185.602 1.1246 .09995 .02216 .002 .02208 - 2.97

71015 1.508 185.087 1.1296 .08280 .02209 .002 .02208 - 3.02

71014 1.508 184.516 1.1350 .06728 .02206 .003 .02213 - 2.86

71013 1.508 184.171 1.1385 .05340 .02151 .004 .02162 - 5.30

71012 2.252 185.078 1.8568 • 0997 e .02416 .002 .02415 - 2.69

71011 2.251 184.541 1.8676 .08267 .02397 .003 .02404 - 3.26

71010 2.252 184.292 1.8732 .06718 .02374 .004 .02385 - 4.15

71009 2.252 183.844 1.8827 .05334 .02407 .005 .02425 - 2.55

71008 2.884 184.688 2.6675 .09972 .02694 .002 .02701 - 1.38

71007 2.884 184.300 2.6644 .08261 .02699 .002 .02714 - 1.10

71006 2.884 133.918 2.7014 .06714 .02692 .004 .02715 - 1.29

71005 2.885 183.674 2.7130 .05331 .02723 .007 .02750 -.11

71024 3.449 184.243 3.7462 .09967 .03246 .003 .03270 3.57

71023 3.449 183.964 3.7775 .08262 .03251 .003 .03284 3.36

71022 3.450 183.733 3.8053 .06717 .03364 .006 .03405 6.62

71021 3.450 183.486 3.8352 .05334 .03404 .005 .03452 7.33

29
Experimental Adjusted Thermal Conductivity

Thermal at a nominal deviation

Run Pt. Pressure

MPa Temperature

K Dens 1 ty

mol /L PowerW/m

Conduct 1 vl ty

W/m .K STAT Temperature of 197 K W/m.K

from correlat

percent

66105 1.013 200.259 .6521 .10870 .02272 .002 .02242 -1.52

66104 1.013 199.676 .6545 .09004 .02271 .002 .02246 -1.34

66103 1.013 199.006 .6574 .07318 .02269 .003 .02251 -1.18

66102 1.014 199.033 .6576 .07318 .02260 .005 .02241 -1.60

66101 1 .014 198.544 .6596 .05806 .02258 .005 .02244 -1.50

66099 1. 531 199.330 1.0328 .09005 .02344 .003 .02324 -2.12

66098 1.531 198.735 1.0371 .07319 .02344 .005 .02329 -1.94

66097 1.532 193.347 1 .0405 .05809 .02324 .006 .02313 -2.71

66100 1.531 198.016 1.0421 .04472 .02290 .009 .02282 -4.13

66095 2.669 199.379 2.0020 .10857 .02582 .003 .02569 -2.86

66094 2.670 198.893 2.0117 .08996 .02592 .005 .02582 -2.45

66093 2.671 198.471 2.0210 .07311 .02586 .004 .02578 -2.69

66096 2.669 198.055 2.0272 .05804 .02589 .007 .02584 -2.55

66091 3.520 198.901 2.9427 .10837 .02876 .003 .02876 -2.42

66090 3.520 198.535 2.9573 .08981 .02894 .004 .02895 -1.94

66089 3.520 198.178 2.9718 .07303 .02884 .006 .02885 -2.46

66092 3.519 197.847 2.9850 .05795 .02874 .007 .02875 -2.97

66087 4.156 198.920 3.8460 .12859 .03241 .003 .03258 -1.19

66086 4.156 198.545 3.8737 .10828 .03246 .004 .03261 -1.46

66085 4.156 198.129 3.9052 .08978 .03235 .005 .03247 -2.31

66088 4.156 197.856 3.9265 .07300 .03271 .007 .03281 -1.54

66083 4.568 198.576 4.6497 .12856 .03611 .003 .03644 -.76

66082 4.568 198.243 4.6911 .10825 .03640 .005 .03667 -.67

66081 4.569 197.957 4.7297 .08973 .03666 .007 .03688 -.64

66084 4.568 197.623 4.7720 .07297 .03688 .008 .03704 -.82

66080 4.860 198.546 5.3693 .15048 .04013 .003 .04066 .11 66079 4.860 198.321 5.4130 .12849 .04052 .004 .04099 .30 66078 4.861 197.947 5.4901 .10820 .04067 .005 .04104 -.69

66077 4.861 197.737 5.5374 .08967 .04065 .006 .04095 -1.58

66076 5.049 198.059 6.0930 .12831 .04489 .007 .04545 .95 66075 5.049 197.769 6.1833 .10808 .04498 .005 .04541 -.40

66074 5.049 197.600 6.239C .08961 .04524 .006 .04559 -.79

66073 5.049 197.361 6.3237 .07290 .04518 .010 .04540 -2.41

66072 5.172 197.928 6. 6566 .12830 .04844 .004 .04907 .78 66071 5.172 197.711 6.7500 .10812 .04906 .005 .04957 .53 66070 5.172 197.542 6.8278 .08966 .04972 .008 .05012 .60 66069 5.172 197.323 6.9353 .07291 .04996 .010 .05021 -.65

66068 5.229 197.897 6.9547 .12830 .05060 .004 .05128 1.18

66067 5.229 197.733 7.0374 .10811 .05105 .006 .05163 .78 66066 5.230 197.549 7.1380 .08967 .05194 .008 .05239 .95 66065 5.229 197.367 7. 2409 .07292 .05249 .011 .05281 .43 66063 5.328 197.769 7.6037 .12833 .05377 .004 .05448 -.92

66062 5.328 197.637 7.6956 .10809 .05438 .005 .05499 -1.08

66061 5.329 197.424 7.8603 .08963 .05510 .006 .05553 -2.01

66064 5.328 197.318 7.9374 .07289 .05535 .010 .05568 -2.62

66059 5.407 197.894 8.0502 .15027 .05720 .003 .05812 .45 66058 5.408 197.711 8.2045 .12831 .05796 .003 .05872 -.15

66057 5.408 197.560 8.3377 .10812 .05854 .005 .05916 -.77

66060 5.407 197.396 8.4911 .08963 .05971 .007 .06017 -.59

66055 5.500 198.115 8.5425 .19936 .06127 .004 .06250 2.69

66054 5.500 197.914 8.7342 .17396 .06186 .004 .06291 1.62

66053 5.500 197.829 8.8188 .15027 .06256 .004 .06353 1.85 66056 5.499 197.597 9.0554 .12829 .06301 .004 .06374 .25 66052 5.692 198.226 9.9294 .22642 .06875 .004 .07025 4.15

66051 5.692 198.053 10. 1199 .19930 .06921 .003 .07052 3.60

66050 5.692 197.882 10.3134 .17384 .06919 .005 .07030 2.42 66049 5.693 197.678 10.5520 .15021 .07018 .004 .07104 2.42

66048 5.965 198.474 11.4627 .25546 .07159 .002 .07324 2.17

66047 5.966 198.275 11.6526 .22652 .07175 .003 .07317 1.51

66C46 5.966 198.070 11.8428 .19934 .07203 .003 .07321 1.03 66045 5.967 197.904 12.0007 .17397 .07253 .004 .07352 1.02

66043 6. 571 193.471 13.6041 .25559 .07406 .004 .07520 -.75

66042 6.571 198.290 13.7018 .22661 .07372 .003 .07471 -1.67

66041 6.572 198.023 13.8421 .19942 .07424 .003 .07501 -1.63

66044 6.571 197.943 13.8813 .17398 .07435 .004 .07506 -1.68

66040 7.445 198.650 14.9564 .28629 .07703 .002 .07786 -1.39

66039 7.446 198.306 15.0761 .22651 .07759 .003 .07824 -1.34

66038 7.447 197.917 15.2077 .17375 .07758 .005 .07803 -2.13

66037 7.447 197.672 15.2885 .12617 .07822 .007 .07854 -1.78

66036 8.P99 198.998 16.1642 .35314 .08202 .002 .08258 -.74

66035 8.809 198.586 16.2628 .28635 .08243 .003 .08287 -.90

66034 8.900 193.134 16. 3691 .22666 .08295 .003 .08326 -1.00

66033 8.900 197.859 16.4329 .17394 .08331 .005 .08355 -1.00

66032 11.180 199.382 17.3129 .42637 .08843 .001 .08872 -.28

66031 11 .180 198.850 17.4059 .35272 .08894 .003 .08916 -.40

66030 11.180 198.640 17.4426 .28598 .08921 .003 .08940 -.37

66029 11.180 198.159 17.5256 .22649 .08973 .003 .08987 -.41

66027 14.451 199.233 18.4565 .42651 .09632 .001 .09635 -.25

66026 14.449 198.829 18.5106 .35280 .09669 .001 .09671 -.30

30
*6025 16.669 199.513 18.5530 .28617 .09701 .002 .09703 -.30

66028 16.652 197.985 18.8267 .22656 .09736 .003 .09737 -.52

68026 19.223 199.667 19.5067 .50675 . 1C559 .002 .10566 .13 68023 19.221 199.171 19.5579 .62611 .10573 .002 .10561 -.16

66022 19. 217 198.766 19.6010 .35261 • 1C 577 .006 .10567 -.67

66021 19.216 198.521 19.6269 .28592 .10675 .003 , 1C666 .26 66020 26.073 200.860 20.5018 .69178 .11655 .001 .11616 -.80

86019 26.073 200.358 20.5662 .59659 .11503 .001 .11669 -.75

68018 26.070 199.962 20.5827 .50866 .11566 .001 .11517 -.67

66017 26.067 199.518 20.6201 .62762 .11552 .002 .11527 -.93

66016 35.287 201.161 21.5630 .79622 .12669 .001 .12618 -.75

88015 35.265 200.662 21.6000 .69191 . 12733 .001 .12688 -.55

68016 35.263 200.211 21 .6319 .59665 .12763 .001 .12726 -.58

68013 35.263 199.725 21.6680 .50861 .12779 .002 .12766 -.75

66012 67.267 200.885 22.8301 .79606 . 16078 .001 .16027 -.51

68011 67. 266 200.367 22.6629 .69175 .16161 .001 .16097 -.33

6601C 67.260 199.(589 22.6868 .59658 .16138 .001 .16098 -.55

86009 67.238 199.680 22.7063 .50871 .16176 .002 .16139 -.66

68008 62.619 201.166 23. 6617 .90315 .15625 .001 .15570 -.06

66007 82.619 200.687 23.6683 .79601 .15668 .001 .15619 .01 88006 82.620 200.378 23.6855 .69177 .15687 .001 .15662 -.01

66005 62.621 200.002 23.7065 .59670 .15719 .001 .15679 .02 66006 69.613 201.156 26.0268 .90256 .16311 .001 .16256 .67 66003 69.617 200. 7C8 26.0688 .79352 .16328 .001 .16279 .38 66002 69.621 2C0.328 26.0690 .69139 .16356 .001 .16312 .38 66001 69.626 200.030 26.085C . 59653 .16391 .002 .16351 .66

Exper i mental Adjusted Thermal Co nduct 1 v I ty Therma 1 at a nominal dev 1 at 1 on Run Pt. Pressure Temperature Pens 1 ty Power Conductivity STAT Temperature of 215 K from correlat

HP* K no 1 /l W/m W/m.K W/m.K percent

65106 1.068 215.053 .8330 .09777 .02660 .003 .02639 -.53

65103 1 .068 216.689 . 6350 .07968 .02627 .006 .02632 -.86

65102 1.068 213.967 .6369 .06308 .02632 .005 .02663 -.62

65101 1 .068 213.626 .6388 .06859 .02611 .008 .02628 -1.08

65100 1.767 215.328 1 .0771 .11797 .02539 .003 .02536 -.89

65099 1.767 216.790 1.0808 .09775 .02536 .003 .02536 -.90

65098 1.767 216.260 1 .0866 .07968 .02527 .006 .02535 -1.00

65097 1.768 213 .806 1.0880 .06309 .02512 .006 .02526 -1.66

65096 3.035 216.866 2.0509 .11789 .02766 .003 .02765 -1.27

65095 3.036 216.326 2.0606 .09770 .02769 .006 .02755 -1.73

65096 3.036 213.866 2.0696 .07962 .02786 .011 .02797 -.30

65093 3.038 213.566 2.0751 .06307 .02761 .007 .02775 -1.16

65092 6.165 216.631 3. 1067 .11779 .03069 .003 .03076 -.52

65091 6.165 216.021 3.1187 .09766 • 03 C6 8 .006 .03076 -.58

850°0 6.165 213.625 3.1328 .07939 .03067 .005 .03078 -.65

8 50 8 9 6.165 213.296 3.1666 .06306 .03069 .008 .03082 -.61

85088 5.021 215.366 6.0275 .18965 .03386 .002 .03382 . 13 65087 5.021 216.628 ‘.0802 .13982 .03398 .003 .03601 .18 65086 5.021 213.776 6.1196 .09759 .03621 .005 .03628 . 56 65085 5.021 213. C72 6. 1625 .06306 .03639 .008 .03669 .75 85083 5.810 216.675 5.1726 .18951 .03866 .002 .03865 1.32

65082 5.811 216.639 5.1976 .18361 .03821 .003 .03822 .67 65081 5 .813 216.016 5.2626 .13970 .03806 .003 .03308 -.38

65086 5.810 213.567 5.2860 .11768 .03916 .006 .03918 2.03

65078 6.372 216.369 6.1863 .18936 .06281 .003 .06279 1.63

65077 6.373 216.079 6.2311 .16353 .06283 .006 .06280 .97 65080 6.370 213.712 6. 2823 .13961 .06267 .006 .06263 .03 65079 6.371 213.676 6.3220 . 11760 .06309 .005 .06303 .56 65076 6.928 213.936 7.6666 .18925 .06797 .002 .06787 -.13

65075 6.929 213.759 7. 6878 .16366 .06831 .003 .06819 .12 65076 6.929 213.375 7.5799 .13957 .06862 .005 .06866 -.21

65073 6.930 213.185 7.6293 .11757 .06903 .005 .06886 .11 65071 7.356 213.566 8.5867 .16366 .05295 .003 .05275 -.66

65070 7.357 213.306 8.6668 .13958 .05301 .005 .05276 -1.28

65069 7.358 213.126 8.7236 .11757 .05368 .007 .05360 -.52

65072 7.356 212.961 8.7709 .09765 .05366 .006 .05335 -.99

65067 7.759 213.712 9.5366 .18925 .05666 .006 .05623 -1.25

65066 7.759 213.375 9.8677 .16369 .05737 .003 .05710 -.65

65065 7.760 213.200 9.7090 .13953 .05756 .006 .05726 -.56

65068 7.759 213.080 9.7685 .11757 .05726 .006 .05696 -1.J7

65066 8.256 213.798 10.6266 .21678 . 06038 .002 .06019 -.88

65063 8.255 213.577 10.7022 .18916 .06079 .003 .06056 -.67

65062 8.255 213.615 10.7578 .16337 .06106 .003 .06079 -.60

65061 8.255 213.191 10.3356 .13967 .06131 .005 .06102 -.6)

65059 8.697 213.762 11.5056 .21680 .06366 .003 .06326 -. 6 ) 65058 6.697 213.550 11.5691 .18915 .06392 .003 .06372 -.07

65057 8.696 213.369 11.6358 .16336 .06611 .005 .06388 -.15

65060 8.696 213.106 11.7127 .13952 .06669 .005 .06622 .01 65055 9.310 213.965 12.6179 .26619 .06672 .002 .06661 .21 65056 9.311 213.662 12.5139 .21667 .06707 .003 .06692 .22 65053 9.312 213.675 12.5662 .18903 .06706 .003 .06668 -.09

65056 9.3 09 213.336 12.5017 .16326 .06726 .005 .06706 .00 85052 10.068 216,6*5 13.1872 .36632 .06921 .002 .06916 .29

31
65051 10.069 214.386 13.2576 .31107 .06976 .002 .06971 .66 65050 10.069 214.165 13.3158 .27768 .06979 .002 .06973 .39 65049 10.070 213.890 13.3873 .24623 .07016 .002 .07008 .53 65047 11.106 214.865 14.1448 .38360 .07303 .001 .07303 .71 65048 11.106 214.535 14.2180 .34629 .07333 .001 .07331 .71 65046 11.106 214.277 14.2756 .31111 .07371 .002 .07369 .90 65045 11.107 213.865 14.3675 .24629 .07406 .002 .07405 .88 65044 12.417 215.388 14.9938 .46314 .07699 .001 .07699 1.19

65043 12.418 214.771 15.1117 .38329 .07741 .002 .07741 1.03 65042 12.420 214.164 15.2277 .31081 .07800 .002 .07801 1.09

65041 12.422 213.575 15.3397 .24620 .07822 .002 .07824 .70 6504 C 14.257 215.850 35.9152 .55204 .08117 .001 .08114 .64 65039 14.257 215.227 16.0150 .46405 .08180 .001 .08179 .78 65038 14.257 214.710 16.0978 .38386 .08221 .001 .08222 .74 65037 14.256 214.290 16.1641 .31119 .08228 .001 .08231 .40 65036 16.764 216.298 16.8559 .64676 .08664 .001 .08655 .50 65035 16.766 215.635 16.9464 .55128 .08724 .001 .08719 .57 65034 16.764 215.026 17.0276 .46349 .08762 .001 .08762 .45 65033 16.767 214.509 17.0979 .38344 .08784 .001 .08788 .22 65032 20.275 215.935 17.9292 .64659 .09375 0.000 .09366 .08 65031 20.274 215.396 17.9898 .55110 .09422 0.000 .09418 .14 65030 20.273 214.891 18.0466 .46331 .09476 .001 .09477 .30 65029 20.270 214.387 18.1027 . 3 R 337 .09491 .001 .09497 .06 65028 24.891 216.265 16.8882 .74910 .10143 .001 .10129 -.13

65027 24.888 215.719 18.9400 .64594 .10199 .001 .10191 .04 65026 24.888 215.148 18.9947 .55067 .10220 .001 .10218 -.17

65025 24.886 214.700 19.0371 .46303 .10268 .001 .10271 -.02 65024 31.251 215.940 19.9356 .74886 .11115 .001 .11103 -.22

65023 31.251 215.396 19.9800 .64577 .11137 .001 .11132 -.36

65022 31.248 214.911 20.0192 .55055 .11176 .001 .11177 -.32

65021 31.245 214.518 20.0508 .46298 .11199 .001 .11205 -.35

65020 39.620 215.647 20.9638 .74856 .12178 .001 .12170 -.52

65019 39.618 215.127 21.0001 .64561 .12224 .001 .12222 -.43

65018 39.614 214.645 21.0334 .55037 .12254 .001 .12259 -.45

65017 39.613 214.236 21.0620 .46262 .12271 .001 .12281 -.53

65016 4 e .553 215.862 21.7900 .85834 .13178 0.000 .13167 -.44

65015 48.554 215.441 21.8164 .74778 .13202 0.000 .13196 -.47

65014 48.549 214.911 21.8490 .64510 .13238 0.000 .13239 -.45

65013 48.547 214 . 4"0 21.8758 .55003 .13296 .001 .13303 -.23

65012 57.652 216.114 22.4806 .97647 . 141 C 3 0.000 .14089 -.26

65011 57.648 215.631 22.5078 .85823 .14139 0.000 .14131 -.23

65010 57.648 215.140 22. 5357 .74779 .14170 0.000 .14168 -.23

65009 57.645 214.778 22.5561 .64478 .14182 .001 .14185 -.31

65008 66.100 215.841 23 . 0*71 .97558 .14935 .001 .14925 -.05

65007 66.103 215.368 23.0823 .85774 .14975 .001 .14971 .01 65006 66.101 214.932 23.1052 .74729 .15016 .001 .15017 .10 65005 66.103 214.525 23.1269 .64455 .15037 .001 .15043 .06 65004 69.263 215.706 23.2560 .97469 .15259 .001 .15251 .19 65003 69.269 215.349 23.2748 .85686 .15309 .001 .15305 .36 65002 69.277 214.975 23.2946 .74659 .15329 .001 .15329 .33 65001 69.276 214.553 23.3164 .64403 .15348 .001 .15353 .28

Exper 1 mental Adjusted Thermal Conduct 1 v 1 ty Thermal at a nominal deviation

Run Pt. Pressure Temperature Dens 1 ty Power Conductivity STAT Temperature of 235 K from correlat

Mt>e K mo 1 /L V/m W /m .K W/m.K percent

62096 .977 234.956 .5207 .13003 .02653 .002 .02653 .27 62095 .978 234.383 .5225 • 10 7 72 .02645 .003 .02652 .20 62094 .978 233 .637 .5244 .08761 .02634 .004 .02649 .09 62093 .979 233.152 .5261 .06955 .02632 .006 .02653 .20 62092 3.145 236.032 1.8367 .20927 .02945 .001 .02934 -.60

42091 3.146 235.316 1.8457 .18078 .02945 .002 .02942 -.41

62090 3.147 234.753 1.8534 .15426 .02935 .002 .02938 -.61

62089 3.148 234.261 1.8598 .12990 .02936 .003 .02944 -.45

62088 5.135 235.158 3.3495 .20902 .03353 .002 .03351 .41 62087 5.135 234.655 3.3645 .18052 .03361 .002 .03364 .67 62086 5.135 234.220 3. 3776 .15411 .03361 .002 .03368 .68 62085 5.135 233.740 3.3923 .12978 .03361 .003 .03373 .70 62084 7.129 236.400 5.1611 .34399 .03839 .002 .03829 - 1.72 62083 7.129 235.396 5.2257 .27225 .03946 .001 .03943 .67 62082 7.131 234.339 5.2973 .20893 .03952 .004 .03957 .38 62081 7.132 233.533 5.3543 .15405 .04043 .006 .04053 2.26

62080 9.424 235.044 7.9786 .34344 .04971 .002 .04971 -.14

62079 9.425 234.249 3.0886 .27190 .05104 .003 .05105 1.63

62078 9.426 233.554 8.1888 .20877 .05041 .002 .05043 -.38

62077 9.427 232.938 8.2807 .15395 .05029 .004 .05031 - 1.35

62076 11 .469 23 * .259 10.3682 .42343 .05858 .001 .05858 -.32

62075 11.470 234.432 10.5075 .34347 .05903 .001 .05903 -.37

62074 11.471 233.788 1 C . 6182 .27188 .05974 .002 .05975 .18 62073 11.472 233.227 10.7162 .20865 .05926 .003 .05927 -1.20

62072 13.600 235.523 12.2555 .51176 .06554 .001 .06552 .12 62071 13.600 234.841 12.3636 .42330 .06603 .001 .06603 .29 62070 13.601 234.078 12.4860 .34350 .06642 .001 .06645 .23 62069 13.602 233.513 12.5781 .27182 .06670 .003 .06675 . 16

32
62060 15.750 235.351 13.6925 .51118 .07173 .001 .07171 .89 62067 15.750 23*. 621 13. 7970 .*2296 .07219 .001 .07221 .96 62066 15.751 23*. 020 13.8826 .3*302 .07238 .002 .072** .76 62065 15.751 233. *72 13.9629 .2716* .07282 .003 .07291 .93 6206* 17.692 235.036 1* .706 9 .51102 .076** .001 .076** 1.01

62063 17.692 23*. *25 1* . 7865 .*2271 .07687 .001 .07691 1.12

62062 17.693 233.812 1 *. 8 669 .3*272 .07712 .002 .07721 .98 62061 17.693 233.3*9 14.9277 .2716* .077*0 .002 .07753 1.00

62060 20.536 23*. 799 15.83*6 .51100 .08188 .001 .08190 .31 62059 20.535 23*. 255 15.8969 .*2276 .08272 .001 .08279 .95 62058 20.535 233.698 15.9611 .3*28* .08318 .002 .08331 1.11 62057 20.535 233.233 16.01*6 .27156 .083*8 .003 .08366 1.1*

62056 23. *11 235.3*3 16.6*32 .60773 .0873* .001 .08730 .79 62055 23. *11 23*. 72* 16.7071 .51105 .08768 .001 .08771 .77 6205* 23. *11 23*. 109 16.7706 .*2275 .0878* .001 .0879* .55 62053 23. *10 233.639 16.8190 .3*290 .088*5 .002 .08860 .93 62052 26.932 235.025 17.5263 .60728 .09332 .001 .09332 .59 62051 26.932 23*. 553 17.5701 .51070 .09311 .001 .09316 .08 62050 26.932 23*. 168 17.6055 .*2253 .09383 .001 .09393 .61 620*9 26.931 233.5*6 17.6629 .3*273 .09395 .002 .09*13 .36 620*0 30.360 235.1*8 18.1965 .60725 .098** .001 .098*2 .*5 620*7 30.366 23*. 592 10.2*31 .51076 .0989* .001 .09899 .6* 620*6 30.361 23*. 2*0 18.2713 .*225* .09922 .002 .09931 .73 620*5 30.360 233.560 18.3291 .3*268 .09935 .002 .09953 .*7 620** 3*. 092 23*. 96* 18.83*6 .60778 .10331 .001 .10331 -.08

620*3 3*. 091 23*. 389 18.8791 .51113 .10359 .001 .10367 -.12

620*2 3*. 090 233.80* 18.92** .*2296 .10395 .001 .10*10 -.09

620*1 3*. 009 233. *73 18.9501 .3*297 .10356 .002 .10376 -.65

620*0 37.551 235. *26 19.3017 .71222 .10755 .001 .107*9 -.15

62039 37.5*7 23*. 763 19.3*95 .60739 .1079* .001 .10797 -.12

62030 37.5*7 23*. 319 19.3817 .51071 .1082* .001 .10833 -.07

62037 37.5*3 233.8*9 19. *15* .*2265 .10825 .001 .108*0 -.30

62036 *1.022 235.318 19.7569 .7122* .11189 .001 .11185 -.17

62035 *1.021 23*. 701 19.7989 .607*0 .11212 .001 .11216 -.26

6203* *1.021 23*. 205 19.8330 .51079 .11239 .001 .112*9 -.27

62033 *1.018 233 .707 19.8669 .*2271 .11263 .002 .11280 -.30

62032 **.35* 235.189 20.1521 .71220 .11637 .001 .11635 .26 62031 **.35* 23*. 6*1 20.1878 .60716 .11599 .001 .1160* -.33

62030 **.351 23*. 130 20.2208 .510*7 .116*3 .001 .1165* -.19

62029 **.350 233.731 20.2*67 .*22*8 .11693 .002 .11709 .05 62020 *7.931 235.016 20.5*03 .71216 .12000 .001 .12000 -.1*

62027 *7.932 23*. 521 20.5712 .6072* .12028 .001 .1203* -.13

62026 *7.927 23*. 030 20.6012 .51071 .12052 .002 .1206* -.15

62025 *7.928 233.633 20.6258 .*2257 .120*9 .002 .12066 -.36

6202* 51.2** 23*. 971 20.8636 .71202 .123*1 .001 .123*1 -.26

62023 51.2*6 23*. *5* 20.89*6 .6071* .12389 .001 .12396 -.10

62022 51.2*3 23*. 029 20.9197 .51053 .12*23 .001 .12*35 -.01

62021 51.2*0 233.650 20.9*20 .*22*0 .12*65 .002 .12*82 .16 62020 55.105 235. **0 21.1818 .82*88 .12730 .001 .12725 -.09

62019 55.10* 23*. 91* 21.2117 .71153 .12766 .001 .12767 -.03

62010 55.102 23*. 391 21.2*13 .60687 .12801 .001 .12808 .02 62017 55.098 233.958 21.2657 .51030 .12822 .002 .12835 -.00

62016 58. *18 235.316 21. *6** .82*9* .13073 .001 .13069 -.01

62015 58. *16 23*. 89* 21.4875 .71153 .13080 .001 .13081 -. 13 6201* 58. *16 23*. *36 21.5128 .60661 .13120 .001 .13127 -.01

62013 58. *13 233.899 21.5*21 .5103* .13157 .002 .13170 .05 62012 61.887 235.300 21.7356 .82502 .13*15 .001 .13*11 .09 62011 61.887 23*. 767 21.76** .71169 . 13**8 .001 .13*51 . 11 62010 61.885 23*. 277 21.7903 .60696 .13*61 .001 .13*69 .01 62009 61.882 233.911 21.8097 .5102* .13*51 .002 .13*63 -.21

62000 65.387 235.226 21.9966 .82*66 .13752 .001 .137*9 . 17 62007 65.38* 23*. 756 22.0207 .71132 .13780 .001 .13783 .19

62006 65.382 23*. 1*1 22.052* .60686 .1383* .002 .136** .33 62005 65.381 233.8*2 22.0677 ,51016 .13807 .002 .13820 .02 6200* 68.761 235.239 22.2299 .82*19 .1*080 .001 .1*077 .37 62003 68.761 23*. 730 22.255* .71111 .1*10* .001 .1*107 .3* 62002 68.757 234.268 22.2783 .606*9 .1*156 .001 .1*16* .53 62001 68.757 233.731 22.305* .51010 .1*160 .002 .1*17* . 35 Exper 1 menta

1

Adjusted Thermal C ond uc 1 1 v 1 1 y Therma

1

at a nom Inal deviation

Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 255 K from correlation

MPa K mo 1 / L W/m W/m.K W/m. K per cent 61092 1.020 255.835 .*9*6 .1*2*9 .02906 .003 .02896 .70 61091 1.020 255.177 .*96* .11810 .02900 .00* .02898 .75 6109* 1.019 25*. 6*5 .*968 .09603 .02887 .005 .02891 .53

61093 1.019 253.9*3 .*905 .07628 .02881 .007 .0269* .60

61090 2.71* 256.518 1.3862 .19011 .03098 .002 .03080 .21 61009 2.71* 255.86* 1.3913 .1691* .03081 .002 .03071 -.11

61000 2.716 255.237 1.3966 .1*2*7 .03080 .003 .03077 .0* 61007 2.717 25*. 735 1 .*006 .11810 .03076 .00* .03079 .08 61006 *.718 255.777 2.5921 .19790 .03381 .002 .03372 .52 61005 *.721 255.276 2.6022 .16888 .03367 .003 .0336* .21 6100* *.726 25*. 679 2.615* .1*232 .03365 .00* .03369 .25

33
& 108 3 4.732 254.209 2.6271 .11795 .03350 .004 .03359 -.12

6109 ? 6.551 256.067 3.8324 .22926 .03709 .002 .03698 .68 61096 6.552 255.011 3.8646 .16905 .03707 .003 .03707 .69 61095 6.555 254.140 3.8929 .11812 .03697 .004 .03706 .46 61079 6.558 253.452 3.9163 .07630 .03716 .008 .03732 .98 61082 6.788 256.771 3.9825 .29824 .03763 .001 .03744 .81 61081 6.788 255.562 4.0205 .22895 .03765 .002 .03759 .92 61080 6.789 254.504 4.0554 .16882 .03768 .003 .03773 1.04

61078 8.785 256.308 5.5387 .29843 .04254 .002 .04242 1.35

61077 8.785 255.358 5.5894 .22912 .04274 .003 .04271 1.62

61076 8.785 254.477 5.6379 .16903 .04276 .003 .04281 1.47

61075 8.786 253.831 5.6746 .11806 .04315 .006 .04325 2.21

61076 11.182 256.639 7.5248 .37633 .04911 .001 .04900 .15 61073 11.183 255.633 7.6096 .29800 .04934 .001 .04930 .11 61072 11.183 254.824 7.6799 .22863 .04949 .001 .04950 -.02

61071 11.187 254.114 7.7455 .16884 .04973 .002 .04979 .06 61070 13.268 256.101 9.2866 .37622 .05538 .001 .05532 -.42

61069 13.269 255.217 9.3799 .29802 .05549 .001 .05548 -.75

61068 13.270 254.473 9.4601 .22888 .05559 .001 .05562 - 1.02

61067 13.273 253.901 9.5237 .16887 .05589 .002 .05595 -.84

61066 15.396 256.416 10.7802 .46416 .06085 .001 .06076 -.33

61065 15.397 255.651 10.8652 .37648 .06112 .001 .06108 -.32

61064 15.399 254.967 10.9428 .29803 .06134 .001 .06134 -.35

61063 15.401 254.357 11.0123 .22883 .06167 .002 .06171 -.17

61062 17.518 256.151 12.0678 .46392 .06596 .001 .06587 .10 61061 17.519 255.415 12.1484 .37629 .06619 .001 .06616 .05 61060 17.521 254.730 12.2248 .29801 .06643 .001 .06645 .04 61059 17.522 254.159 12.2883 .22884 .06667 .001 .06673 .09 61057 20.351 255.901 13.4372 .46368 .07195 0.000 .07187 .53 61056 20.352 255.130 13.5171 .37618 .07227 .001 .07226 .58 61055 20.353 254.542 13.5789 .29782 .07266 .001 .07270 .80 61058 20.351 254.029 13.6315 .22875 .07260 .001 .07269 .46 61054 23.422 256.273 14.5472 .56062 .07746 0.000 .07732 .74 61053 23.422 255.560 14.6155 .46396 .07781 .001 .07775 .84 61052 23.423 254.902 14.6790 .37633 .07792 .001 .07793 .65 61051 23.423 254.313 14.7359 .29804 .07809 .001 .07817 .57 61050 26.850 255.901 15.6055 .56029 .08305 .001 .08294 .51 61049 26.850 255.234 15.6645 .46356 .08338 .001 .08335 .59 61048 26.851 254.549 15.7257 .37613 .08345 .002 .08351 .34 61047 26.849 254.205 15.7556 .29770 .08391 .002 .08401 .72 61046 30.401 255.776 16.4802 .56014 .08833 .001 .08823 .32 61045 30.399 255.193 16.5276 .46342 .08852 .001 .08850 .27 61044 30.400 254.584 16.5776 .37603 .08907 .001 .08912 .60 61043 30.397 254.087 16.6177 .29777 .08915 .002 .08927 .46 61042 33.905 255.663 17.2043 .56015 .09323 .001 .09314 .21 61041 33 .907 255.054 17.2509 .46350 .09361 .001 .09360 .34 61040 33.909 254.579 17.2875 .37602 .09388 .001 .09394 .41 61039 33.909 254.064 17.3268 .29769 .09394 .002 .09406 .24 61038 37.376 255.663 17.8138 .55991 .09780 .001 .09771 .19 61037 37.374 255.091 17.8543 .46338 .09811 .001 .09810 .26 61036 37.373 254.512 17.8955 .37606 .09820 .002 .09827 .10 61035 37.374 254.068 17.9274 .29770 .09838 .002 .09851 .08 61034 40.731 256.199 18.2959 .66481 .10193 .001 .10177 .35 61033 40.729 255.692 18.3298 .55936 .10218 .001 .10209 .39 61032 40.727 255.244 18.3598 .46315 .10249 .001 .10246 .50 61030 44.631 256.203 18.8319 .66637 .10593 .001 .10577 -.21

61029 44.631 255.607 18.8697 .56050 .10628 .001 .10620 -.12

61028 44.631 254.993 18.9087 .46397 .10634 .001 • 1 C 634 -.32

61027 44.632 254.544 18.9373 .37645 .10682 .002 .10688 -.05

61026 48.090 256.097 19.2644 .66640 .10970 .001 .10956 -.32

61025 48.089 255.479 19.3017 .56065 .11007 .001 .11001 -.23

61024 48.089 254.909 19.3363 .46402 .11033 .002 .11034 -.21

61023 48.087 254.428 19.3653 .37632 .11059 .002 .11066 -.17

61022 51.674 255.939 19.6753 .66635 .11361 .001 .11349 -.28

61021 51.673 255.358 19.7088 .56051 .11379 .001 .11374 -.34

61020 51.672 254.925 19.7338 .46380 .11397 .001 .11398 -.35

61019 51.673 254.412 19.7636 .37609 .11422 .002 .11429 -.33

61018 56.210 256.371 20.1124 .78108 .11793 .001 .11776 -.33

61017 56.209 255.786 20.1444 .66598 .11819 .001 .11809 -.33

61016 56.207 255.239 20.1742 .56023 .11843 .001 .11840 -.32

61015 56.208 254.711 20.2032 .46369 .11839 .002 .11843 -.55

61014 56.203 254.267 20.2272 .37609 .11912 .002 .11921 -.10

61012 59.687 255.471 20.4844 .66526 .12184 .001 .12178 -.19

61013 59.690 255.429 20.4868 .66531 .12189 .001 .12184 -.16

61010 59.684 254.396 20.5409 .46317 .12209 .002 .12216 -.37

61009 59.683 254.078 20.5578 .37569 .12246 .002 .12257 -.18

61008 63.260 255.957 20.7686 .78036 .12586 .002 .12575 .55 61007 63.260 255.379 20.7981 .66515 . 12659 .003 .12655 .92 61006 63.255 254.993 20.8173 .55951 .12468 .003 .12468 -.73

61005 63.252 254.436 20.8456 .46299 .12537 .002 .12543 -.38

61004 66.477 255.922 21 .0323 .77958 .12880 .001 .12870 . 56 61003 66.480 255.361 21.0603 .66483 .12865 .001 .12861 .25 61002 66.474 254.827 21.0863 .55938 .12888 .002 .12890 .25 61001 66.473 254.429 21.1059 .46281 .12852 .001 .12858 -.17

34
Experimental Adjusted Theraal Conductivity

Thermal at a nominal deviation

Run Pt. Pressure Temperature Pens 1 ty Power Conductivity STAT Temperature of 275 K from cor re lat 0P a K mo 1 /L W/m W/m .K W/m.K percent

63100 1.015 275.820 .6533 .15667 .03152 .003 .03161 .62

6 30 99 1.015 275.218 .6563 .12805 .03166 .006 .03161 .61 63098 1.015 276.623 .6557 .10617 .03136 .006 .03139 .56 63097 1.016 276.083 .6569 .08270 .03136 .006 .03166 .76 63096 2.695 276.019 1.1567 .18276 .03288 .002 .03275 .08 63095 2.695 275.382 1.1581 .15600 .03289 .003 .03286 .36 83096 2.696 276.765 1.1617 .12766 .03277 .006 .03280 .20 63093 2.697 276.285 1.1667 .10385 .03276 .005 .03283 .28 63092 6.666 275.566 2.1666 .18263 .03509 .002 .03502 . 18 63091 6.667 275.066 2.1703 .15388 .03695 .003 .03696 -.08

63090 6.668 276.633 2.1779 .12765 .03699 .006 .03506 .22 63089 6.669 276.021 2. 1830 .10386 .03689 .005 .03501 .05 63088 6.508 275.252 3.3376 .18298 . 03 8C6 .003 .03801 .72 63087 6.500 276.818 3.3662 .15623 .03809 .003 .03811 .93 63006 6.507 276.356 3. 3553 .12793 .03807 .006 .03815 .97 63085 6.507 276.121 3.3599 .10617 .03816 .005 .03827 1.25

63086 8.601 277.316 6.6373 .32366 .06135 .001 .06108 1.12

63083 8.602 276.766 6.6551 .28686 .06136 .002 .06113 1.13

63082 8.605 276.190 6.6739 .26858 .06126 .001 .06112 .97 63081 8.607 275.561 6.6950 .21676 .06120 .002 .06116 .87 63080 10.552 276.595 5.8601 .32376 .06551 .001 .06536 1.17

63079 10.553 276.056 5.8653 .28500 .06568 .001 .06537 1.06

63078 10.555 275.617 5.8866 .26862 .06563 .002 .06536 .90

63077 10.559 275.127 5.9119 .21676 .06567 .002 .06566 .93 63076 12.673 276.632 7.2307 .36663 .05006 .001 .06988 .76 63075 12.676 276.126 7.2618 .32326 .05012 .001 .05001 .77 63076 12.675 275.660 7.2925 .28656 • 05 CCS .002 .05002 .57 63073 12.670 275.203 7.3212 .26835 .05007 .002 .05005 .63 63072 16.652 276.728 8.6852 .60823 . 05639 .001 .05623 .31 63071 16.653 276.201 8.5237 .36665 .05663 .001 .05632 .22 63070 16.655 275.829 8.5513 .32336 .05669 .002 .05661 .20 63069 16.656 275.608 0.5026 .28658 .05652 .002 .05668 .12 63068 16.956 276.365 9.8597 .60830 .05929 .001 .05917 .07 63067 16.956 275.929 9.8929 .36658 .05965 .001 .05937 .20 63066 16.956 275.539 9.9250 .32329 .05961 .001 .05936 -.00

63065 16.957 275.111 9.9603 .29652 .05939 .002 .05938 -.19

63066 19.153 276.052 11.0121 .60856 .06356 .001 .06366 .03 63063 19.156 275.716 11.0606 .36676 .06373 .001 .06366 .18 63062 19.155 275.280 11.0768 .32359 .06382 .002 .06379 .16

63061 19.155 275.006 11.0999 .28682 .06383 .002 .06383 .08 63060 21.322 276.700 11.9263 .50337 .06766 .001 .06728 .36 63059 21.323 275.909 11.9898 .60861 .06757 .001 .06767 .23 63058 21.326 275.069 12.0602 .32360 .06782 .002 .06781 .30 63057 21.325 276.513 12.1070 .26851 .06786 .003 .06789 .13 63056 23.529 276.628 12.8000 .50352 .07133 .001 .07116 .57 63055 23.529 275.693 12.8606 .60869 .07166 .001 .07138 . 50 63056 23.531 276.982 12.9192 .32356 .07168 .002 .07168 .56

63053 23.535 276.601 12.9686 .26863 .07155 .003 .07162 .16 63052 26.983 276.181 13.9511 .50296 .07678 .001 .07663 .67 63051 26.986 275.683 16.0059 .60809 .07696 .001 .07690 .66 63050 26.986 276.770 16.0625 .32330 .07718 .002 .07721 .70

63069 26.988 276.268 16.1062 .26830 .07728 .003 .07738 .66 63068 30.686 276.033 16.9166 .50312 .08188 .001 .08176 .71 63067 30.687 275.358 16.9651 .60826 .08186 .003 .08181 .66

63066 30.688 276.715 15.0136 .32361 .08231 .002 .08235 .78 63065 30.690 276.239 15.0695 .26832 .08232 .003 .08262 .63 63066 33.987 276.667 15.6786 .60766 .08653 .001 .08630 . 83 63063 33.989 276.018 15.7232 .50276 .08678 .002 .08666 .90 63062 33.987 275.268 15.7773 .60817 .08686 .002 .08680 .72 63061 33.991 276.869 15.8051 .32315 .08710 .002 .00712 . 88 63060 37.531 276.150 16.6198 .60705 .09067 0.000 .09050 .23 63039 37.530 275.502 16.6630 .50262 .08976 .002 .08969 -.98

63038 37.529 276.868 16.5068 .60772 .09182 .001 .09186 1.07

63037 37.528 276.390 16.5375 .32291 .08826 .002 .08835 -3.08

63036 61.156 276.052 17.0581 .60709 .09692 0.000 .09677 .10 63035 61.153 275.385 1 7 .1006 .50251 .09586 .001 .09580 .87 63036 61.151 276.737 17.1616 .60785 .09528 .001 .09532 .05 63033 61.151 276.280 17.1709 .32303 .09576 .001 .09586 .60

63032 66.660 275.921 17.6090 .60719 .09929 .001 .09916 .63 63031 66.660 275.286 17.6677 .50258 .10015 .001 .10011 1.08

63030 66.660 276.679 17.6865 .60788 .09936 .002 .09961 .10

63029 66.660 276.171 17.7156 .32297 .09927 .001 .09939 -.16

63028 68.079 275.776 16.0960 .60693 .10277 .001 .10266 .11 63027 68.080 275.237 18.1255 .50235 .10290 .001 .10287 .09

63026 68.078 276.656 18.1590 .60762 .10286 .001 .10289 -.13

63025 68.078 276.170 18.1876 .32293 .10366 .001 .10376 .66 63026 51.736 276.282 18.5276 .72176 .10665 .001 .10627 .18 63023 51 .733 275.668 18.5617 .60700 .10652 .001 .10663 .03 63022 51.733 275.120 18.5922 .50235 .10682 .001 .10680 .16

35
63021 53.732 274.692 18.6215 .40764 .10677 .001 .10683 -.05

63020 55.237 276.367 18.9287 .72086 .10987 .001 . 1C969 .14 63019 55.235 275.610 18.9690 .60660 .11000 .001 .10992 .03 63018 55.235 275.048 18.9990 .50223 .11026 .001 .11025 .10 63017 55.233 274.537 19.0262 .40756 .11059 .001 .11065 .24 63016 58.740 276.173 19.3137 .72115 .11329 .001 .11314 .14 63015 58.747 275.531 19.3467 .60682 .11347 .001 .11340 .11 63014 58.743 274.999 19.3742 .50221 .11361 .001 .11361 .07 63013 58.749 274.471 19.4015 .40762 .11393 .001 .11400 .19 63012 62.502 276.101 19.6879 .72083 .11694 .001 .11680 .30 63011 62.503 275.477 19.7190 .60654 .11710 .001 .11704 .25 63010 62.499 274.905 19.7470 .50205 .11722 .002 .11723 .18 63009 62.497 274.457 19.7691 .40740 .11744 .002 .11751 .24 63008 65.832 275.948 20.0016 .72167 .12004 .001 .11993 '.38 63007 65.838 275.385 20.0291 .60707 .12010 .001 .12005 .26 63006 65.640 274.943 20.0507 .50242 .12014 .002 .12015 .16 63005 65.839 274.423 20.0756 .40757 .12016 .002 .12023 .02 63004 69.251 276.499 20.2712 .84619 .12280 .001 .12263 .40 63003 69.252 275.940 20.2974 .72168 .12306 .001 .12295 .45 63002 69.254 275.379 20.3237 .60710 .12327 .001 .12323 .45 63001 69.256 274.798 20.3509 .50235 .12333 .002 .12335 .33 Experl mental Adjusted Thermal Conduct 1 v 1 ty

Therma 1 at a nominal dev I at 1 on Run Pt. Pressure Temperature Density Power Conduc 1 1 v 1 ty STAT Temperature of 295 K from correlat

MPa K mo 1 /L W/ffl W/m.K W/m.K percent

64096 .988 296.783 .4076 .19678 .03402 .001 .03376 -.49

64095 .988 296.042 .4087 .16582 .03389 .002 .03374 -.56

64094 .988 295.352 .4098 .13751 .03383 .002 .03378 -.44

64093 .989 294.797 .4110 .11185 .03357 .003 .03360 -.98

64092 1.949 296.430 .8198 .19679 .03477 .002 .03456 -.63

64091 1.949 295.783 .8218 .16583 .03465 .002 .03454 -.72

64090 1.950 295.177 .8242 .13753 .03465 .002 .03462 -.47

64089 1.950 294.638 .8260 .11181 .03451 .004 .03456 -.66

64088 3.911 296. C23 1.7091 .19687 .03648 .002 .03633 -.91

64087 3.912 295.413 1.7140 .16594 .03651 .002 .03645 -.61

64086 3.913 294.915 1.7180 .13757 .03640 .003 .03641 -.74

64085 3.914 294.458 1.7220 .11184 .03638 .003 .03646 -.63

64083 5.976 296.320 2.7045 .23054 .03882 .002 .03863 -.61

64082 5.978 298.741 2.7133 .19686 .03879 .002 .03869 -.53

64081 5.981 295.153 2.7226 .16583 .03866 .003 .03864 -.70

64084 5.974 294.671 2.7256 .13760 .03862 .003 .03867 -.65

64080 8.077 295.849 3.7900 .30408 .04152 .001 .04140 -.15

64079 8.079 295.213 3.8044 .26540 .04159 .001 .04156 .14 64078 8.082 294.626 3.8184 .22936 .04152 .001 .04157 .08 64077 8.087 294.136 3.8317 .19587 .04146 .002 .04158 .02 64076 10.365 295.366 5.0327 .30417 .04499 .001 .04494 .35 64075 10.367 294.726 5.0539 .26549 .04503 .001 .04507 .49 64074 10.369 294. 2?4 5.0689 .22937 .04496 .001 .04506 .37 64073 10.373 293.791 5.0863 .19590 .04498 .001 .04514 .45 64072 12.169 294.991 6.0388 .30407 .04808 .001 .04808 .60 64071 12.171 294.453 6.0612 .26539 .04798 .001 .04805 .39 64070 12.173 293.987 6.0808 .22933 .04622 .002 .04835 .88 64069 12.176 293.540 6.1007 .19590 .04813 .002 .04832 .68 64068 14.295 296.186 7.1437 .43623 .05170 .001 .05155 .27 64067 14.297 295.091 7.1977 .34554 .05178 .001 .05177 .33 64066 14.297 294.119 7.2458 .26546 .05174 .001 .05185 .17 64065 14.299 293.367 7. 2843 .19579 .05159 .002 .05179 -.20

64064 16.379 295.764 8.2537 .43502 .05529 .001 .05520 -.21

64063 16.379 294.721 8.3126 .34532 .05535 .001 .05538 -.26

64062 16.381 293.904 8.3600 .26521 .05534 .002 .05547 -.41

64061 16.382 293.091 8.4079 .19581 .05532 .002 .05554 -.59

64060 18.657 295.420 9.3030 .43576 .05917 .001 .05912 -.57

64059 18.658 294.415 9.4460 .34537 .05936 .001 .05943 -.44

64058 18.659 293.583 9. 4990 .26536 .05936 .002 .05953 -.61

64057 18.662 292.903 9.5440 .19582 .05952 .003 .05977 -.48

64056 21.429 295.068 10.6132 .43616 .06390 .001 .06389 -.36

64055 21 .432 294.252 10.6684 .3454? .06409 .003 .06418 -.24

64054 21.432 293.482 10.7200 .26544 .06409 .002 .06428 -.40

64053 21.434 292.793 10.7671 .19593 .06431 .004 .06458 -.21

64052 25.128 295.659 11.9458 .53780 .06921 .002 .06912 -.62

64051 25.12? 294.864 11.9987 .43644 .06971 .001 .06973 -.07

64050 25.128 294.012 12.0565 .34590 .06969 .002 .06982 -.29

64049 25.126 293.449 12.0942 .26552 .06976 .003 .06997 -.31

64048 28.719 295.578 13.0659 .53714 .07460 .001 .07452 -.07

64047 28.716 294.771 13.1185 .43594 .07485 .001 .07488 .09 64046 28.712 294.080 13.1632 .34540 .07495 .002 .07508 .08 64045 28.713 293.601 13.1955 .26524 .07484 .003 .07504 -.18

64044 32.484 296.573 13.9937 .65080 .07914 .001 .07890 -.28

64043 32.483 295.711 14.0486 .53881 .07927 .001 .07916 -.31

64042 32.484 295.042 14.0918 .43712 .07926 .001 .07925 -.47

64041 32 .485 294.303 14.1396 .34634 . 07989 .002 .08000 .15 64040 36. 134 296.404 14.8338 .65093 .08342 .001 .08320 -.52

64039 36.135 298.521 14.8886 .53897 .08366 .001 .08358 -.43

36
6*038 36.136 29*. 862 1* . 92 98 .*3735 .0838* .001 .08386 -.37

6*037 36.136 29*. 272 1*. 9667 .3*6*3 .08398 .002 .08*09 -.3*

6*036 39 . **2 296.32* 15. 5008 .65087 .08733 .001 .08712 -.**

6*035 39 . **2 295.531 15.5*82 .53889 .087*3 .001 .08735 -.51

6*03* 39.*** 29*. 765 15.59*6 .*37*9 .08756 .002 .08760 -.5*

6*033 39.*** 29*. 155 15.631* .3*659 .08786 .002 .08799 -.3*

6*032 *2.826 296.156 16.1165 .65110 .09103 .001 .09085 -.53

6*031 *2.826 295. *72 16.1560 .53893 .09127 .001 .09119 -.*3

6*030 *2.827 29*. 753 16.1979 .*37*6 .09125 .001 .09129 -.62

6*020 *2.«27 29*. 259 16. 2266 .3*638 .09136 .001 .091*8 -.62

6*028 *6.333 296.097 16.68*8 .65081 .09*70 .001 .09*53 -.59

6*027 *6.333 295.3*7 16.7267 .5389* .09*92 .001 .09*87 -.5*

6*026 *6.333 29*. 739 16.7605 .*3735 .09*97 .001 .09501 -.63

6*025 *6.33* 29*. 112 16.7959 .3*655 .0952* .001 .09538 -.*9

6*02* *9.99e 296.096 17.2192 .65100 .098*7 .001 .09830 -.5*

6*023 50,000 295, 3*q 17.2589 .53908 .09867 .001 .09862 -.51

6*022 50.000 29*. 6^2 17. 295* .*3753 .09883 .001 .09888 -.50

6*021 50.001 29*. 162 17.3230 .3*655 .0991* .001 .09927 -.31

6*020 53.680 295.878 17.7173 .65037 .10213 .001 .10200 -.50

6*010 53.681 295.267 17.7*91 .5383* .10220 .001 .10216 -.57

6*018 53. 682 29*. 552 17.7863 .*370* .10237 .001 .102** -.58

6*017 53.685 29*. 003 17.8151 .3*631 .102*9 .002 .1026* -.59

6*016 57.061 295.330 18.1555 .65059 .105*1 .001 .10536 -.50

6*015 57.060 29*. 706 18.1867 .53859 . 10558 .001 .10562 -.*9

6*01* 57.061 29*. 110 19.2167 .*3712 .1058* .001 .10597 -.38

6*013 57.062 293.609 19.2*20 .3*613 .1057* .001 .1059* -.60

6*012 60.576 295.232 19.55*9 .6*96* .10865 .001 .10862 -.*5

6*011 60. 576 29*. 6*9 19.5831 .53*89 .10885 .001 .10890 -.*0

6*010 60.578 29*. 036 18.6130 .*366* .10897 .001 .10910 -.**

6*000 60.577 293.630 19.6327 .3*590 .10909 .002 .10928 -.*2

6*008 63.953 295.187 18.9095 .65023 .11177 .001 .1117* -.28

6*007 63.958 29*. 555 18.9397 .53831 .1120* .001 .11210 -.19

6*006 63.952 29*. 012 18.96*6 .*3686 .11193 .002 .11206 -.*1

6*005 63. <551 293. *75 18.9898 .3*595 .112*1 .002 .11261 -.11

6*00* 67.319 295.776 19.2118 .77273 .11*71 .001 .11*61 -.0*

6*003 67.321 295.113 19.2*19 .65036 .11*91 .001 .11*89 -.02

6*002 67.320 29*. 631 19.26*0 .538** .11510 .002 .11515 .03 6*001 67.323 29*. 106 19.2861 .*3691 .11521 .002 .11532 .00

Exper 1 rental Adjusted Thermal Conduct 1 v 1 ty

Ther ira 1 at a nominal deviation

Run Pt. Pressure T emperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 310 K f r oa correlation

HPa K no 1 / L W/m W/m.K W/a.K p er cant

60100 1 .076 309.085 .*258 .173e* .03591 .003 .03606 -.57

60090 1.076 308.3*1 .*270 .1**26 .03610 .003 .03636 .28 60098 1.077 307.755 .*282 .11737 . 03581 .005 .03617 -.27

60097 1.077 307.128 .*291 .09326 .03558 .006 .0360* -.6*

60096 2.675 309.21* 1.0856 .2063* .037*2 .002 .0375* -.18

60095 2.675 308.62* 1.0881 .17389 .03733 .002 .03755 -.18

6009* 2.676 308.033 1.0908 .1**21 .03701 .00* .03732 -.81

60093 2.678 307. *1* 1.0939 .11735 .03693 .005 .0373* -.78

60092 *.7*3 3C9.391 1.98** .2*167 .03936 .002 .039*5 -.12

60091 *.7*3 308.8*9 1.9889 .20631 .03910 .002 .03928 -.59

60090 *.7*3 308.250 1.99*2 .17*01 .03915 .002 .039*2 -.25

60089 *.7** 307.6*8 1.9996 .1**25 .03901 .003 .03937 -.*0

60088 6.732 309.635 2.8926 .27951 .0*1*8 .002 .0*15* .06 60087 6.732 309.0*0 2.9007 .2*155 .0*153 .002 .0*168 .35 60086 6.733 308. *6* 2.9086 .20630 .0*1*6 .002 .0*170 .35 60085 6.733 307.9*1 2.9159 .17389 .0*127 .003 .0*159 .05 6008* 8.876 309.267 3.9213 .27950 .0**26 .002 .0**37 .90 60083 8.876 308.712 3.932* .2*1*6 .0*395 .002 .0**15 .33 60082 8.877 308.170 3.9*36 .20633 .0**02 .002 .0**30 .61 600ei 8.877 307.710 3.9533 .17389 .0**03 .003 .0**38 .73 60080 11.038 310.021 *.9610 .36387 .0*719 .001 .0*719 1.01

60079 11.039 308.899 *.9916 .27955 .0*715 .001 .0*731 1.10

60078 11.039 307.879 5.0197 .20636 .0*683 .002 .0*715 .50 60077 11.039 307.031 5.0*35 .1**25 .0*695 .003 .0*739 .95 60076 13.1*7 309.673 6.0076 .36383 .05009 .001 .0501* .75 60075 13.1*7 308.603 6. 0**8 .27955 .0*996 .001 .05016 .50 6007* 13.1*8 307.6*2 6.0786 .206*2 .05023 .902 .05057 1.17

60073 13.1*8 306.8*1 6.1075 .1**27 .05033 .003 .05079 l.*2

60072 15.185 309.353 7.0079 .36383 .05320 .001 .05329 .63 60071 15.186 308.309 7.0518 .27961 .05323 .001 .053*7 .69

60070 15.196 307.523 7.0852 .20635 .05323 .001 .05358 .69

60069 15.186 306.7*6 7.1185 .1**28 .05325 .002 .05371 .71 60068 17.278 310.102 7.9505 .*5930 .05639 .001 .05630 .33 60067 17.278 309.975 8.0039 .36381 .056*7 .001 .05661 .*1 60066 17. 277 308.110 8.0*52 .279*8 .056** .001 .05671 . 12 60065 17.276 307.320 8.0833 .20629 .056*6 .002 .05683 .10 6006* 19. *6* 309.770 8.9257 .*5913 .05973 .001 .05976 .06 60063 19. *63 308.761 8.9783 .3638* .05986 .001 .06003 .21 60062 19. *63 307.9** 9.0216 .27951 .05983 .001 .06012 • 00 60061 19. *62 307.225 9.0596 .20632 .06000 .002 .06039 .29

60060 22. *18 309. *80 10.1219 .*5925 .06*11 .001 .06*19 -.00

37
60059 22 . 41 « 308.591 10.1725 .36391 .06422 .001 .06442 -.01

60058 22.418 307.806 10.2174 .27970 .06422 .002 .06454 -.11

60057 22.418 307.109 10.2575 .20643 .06411 .003 .06453 -.37

600^6 26.028 309.260 11.3035 .45915 .06920 .001 .06931 -.08

60055 26.028 308.444 11.4416 .36385 .06941 .001 .06965 .11 60054 26.028 307.756 11.4821 .27957 .06941 .002 .06975 .01 60053 26.028 307.136 11.5190 .20632 .06952 .003 .06996 .08 60052 29.477 310.093 12.3802 .56605 .07393 .001 .07392 .31 60051 29.477 309.235 12.4302 .45930 .07395 .001 .07407 .22 60050 29.476 308.527 12.4718 .36374 .07417 .002 .07441 .41 600*9 29.475 307.869 12.5103 .27962 .07430 .002 .07464 .49 6004 B 33 .098 309.694 13.3468 .56642 .07815 .001 .07820 -.07

60047 33.097 308.929 13.3909 .45962 .07827 .001 .07845 -.03

60046 33.098 308.143 13.4369 .36424 .07833 .001 .07864 -.08

60045 33 .098 307.480 13.4758 .27986 .07850 .301 .07892 .03 60044 36.518 309.498 14.1404 . 56640 . 08199 .001 .08208 -.28

60043 36.519 308.688 14.1867 .45974 .08222 .001 .08244 -.13

60042 36.520 308.056 14.2230 .36418 .08215 .001 .08246 -.32

60041 36.521 307.447 14.2583 .27977 .08216 .002 .08259 -.41

60040 39.909 309.222 14.8464 .56604 .08588 .001 .08601 -.18

60039 39.909 308. c 50 14.8839 .45928 .08603 .001 .08628 -.12

60036 39.911 307.881 14.9216 .36395 .08621 .001 .08657 -.03

60037 39.914 307.206 14.9600 .27972 .08623 .002 .08671 -.12

60036 43.084 309.943 15.3906 .68368 .08913 .001 .08914 -.21

60035 43.083 309.132 15.4344 .56615 .08928 .001 .08943 -.18

60034 43.081 308.403 15.4736 .45964 .08918 .002 .08945 -.41

60033 43.079 307.807 15.5057 .36412 .08970 .002 .09008 .07 60032 46.727 309.716 16.0098 .68405 • 093 C 3 .001 .09308 -.05

60031 46.727 309.019 16.0464 .56624 .09312 .001 .09329 -.07

60030 46.726 308.324 16.0828 .45963 .09305 .002 .09333 -.27

60029 46.725 307.749 16.1130 .36403 .09325 .002 .09363 -.16

60028 50.127 309.703 16.5254 .68344 .09630 .001 .09635 -.11

60027 50.126 308.899 16.5662 .56592 .09644 .001 .09662 -.11

60026 50.126 308.226 16.6007 .45933 .09638 .001 .09668 -.29

60025 50.126 307.650 16.6302 .36396 .09665 .002 .09704 -.12

60024 53.476 309.618 16.9956 .68350 .09950 .001 .09956 -.08

60023 53.476 308.897 17.0313 .56589 .09960 .001 .09978 -.11

60022 53.476 308.209 17.0554 .45939 .09974 .001 .10003 -.10

60021 53.475 307.616 17.0949 .36402 . 099 e 2 .002 .10021 -.13

60020 57.009 309.416 17.4585 .68371 .10283 .001 .10292 .01 60019 57.009 308.753 17.4904 .56610 .10306 .001 .10326 .11 60018 57.009 308.134 17.5202 .45956 .10301 .002 .10331 -.05

60017 57.008 307.513 17.5501 .36411 .10321 .002 .10360 .02 60016 60.531 309.315 17.9809 .68393 .10601 .001 .10612 .09 60015 60.530 308.655 17.9116 .56630 .10623 .001 .10644 .17 60014 60.531 308 . C 72 17.9389 .45961 .10653 .003 .10682 .34 60013 60.531 307.537 17.9640 .36404 .10647 .002 .10684 .19 60012 64.078 309.320 18.2716 .68251 .10919 .001 .10929 .27 60011 64.078 308.648 18.3021 .56485 .10926 .001 .10946 .20 60010 64.075 308.025 18.3300 .45896 .10942 .002 .10971 .23 60009 64.077 307.462 18.3558 .36370 .10948 .002 .10985 .18 60003 66.672 313.129 18.3733 .68185 .11038 .001 .10992 .12 60002 66.678 312.494 18.4018 .56460 .11055 .001 .11019 .16 60004 66.670 311.828 18.4301 .45825 .11076 .001 .11050 .24 60001 66.685 311.372 18.4517 .36312 .11071 .002 .11051 .10 60008 67.415 309.358 18.6139 .68343 .11215 .001 .11224 .49 60007 67.414 308.758 18.6402 .56591 .11244 .001 .11261 .63 60006 67.414 308.136 18.6676 .45943 .11259 .002 .11285 .65 60005 67.416 307.614 18.6909 .36422 .11278 .003 .11311 .71

38
4. Ethane Results

A total of 797 points are given in Table 4. The results are reported in [10].

The computer programs developed for the thermal conductivity surface of ethane are shown below. The equation of state used for ethane is given in [11].

FUNCTION C2H6TC ( RHO , T

)

C COEF. FR0‘* TC021 AND MINIMS 15 MAR 84, 4TH PASS

DIMENSION A ( 3 ), B ( 9

)

DATA A/- .4324979108E-02

1 , .4892828913E-04 ,

. 1 2 50947 1 55E-06 / DATA B/

1 .2377714804E-02 , - . 7 2 76 7 58542E-06 , - . 1022365973E + 02

1 .3617304226E-01 ,. 1027484150E-03 ,. 1229770283E-08

1 , .2685444816E + 0 1 , .13451 17409E-01 , - . 37 61 8535 1 1 E-04/

TERM1=A( 1 )+A(2)*T+A(3)*T**2

TERM2=(B(1)+B(2)*T)*RH0

BEE=EXP(B(3)+B(4)*T+B(5)*T**2+B(6)*T**3)

ENN=B(7)+B(8)*T+B(9)*T**2

TERM3=BEE*RH0**ENN

C2H6TC=TERM1+TERM2+TERM3+C2H6CR( RHO , T

)

RETURN

END

FUNCTION C2H6CR ( RHO ,TEMP

)

C COEF. FROM TC021 AND MINIMS 15 MAR 84, 4TH PASS

DIMENSION C ( 6

)

DATA (TC=305.33) ,(RH0C=6.80)

DATA C/- .6179783534E-01

1 ,- .3020000000E + 03 , .3546146027E + 00 , - . 1036454167E-02

1 ,- .3170704764E + 00 ,

. 3237818922E+00 / T=TEMP

DEN=RH0

IF(T.LT.TC) T=TC+(TC-T)

IF(T.LT.340.597) GO TO 4 C2H6CR=0

.

RETURN

4 CONTINUE

AMPL=C(1)/(T+C(2) )+C(3)+C(4)*T

DELRH0=DEN-RH0C

X1=C(5)*DELRH0

I F ( DEN . GT . 6 . 80 ) X 1 = C ( 6

) *DELRH0

C2H6CR=AMPL*EXP(-X1**2)

RETURN

END

39
Table 4. The Thermal Conductivity of Ethane

Expe r 1 mental Adjusted Thermal Conduct 1 v 1 ty

Thermal at a nominal dev 1 at 1 on Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 110 K from correlation

MPa K mo 1 /L W/m W/m.K W/m.K percent

81072 .719 112.472 20.8794 1.18021 .23728 .001 .23613 .01 81071 .717 112.265 20.8869 1.08943 .23765 .001 .23659 .09 81070 .714 112.125 20.8920 1.00333 .23842 .001 .23743 .36 81069 .713 111.929 20.8991 .92003 .23852 .001 .23761 .34 81068 14.436 112.488 21.0719 1.17941 .24436 0.000 .24314 .07 81067 14.432 112.263 21.0796 1.08880 .24454 .001 .24343 .07 81066 14.428 111.945 21.0907 1.00152 .24455 .001 .24359 -.03

81065 14.424 111.866 21.0934 .91961 .24605 .002 .24513 . 56 81064 27.531 112.380 21.2477 1.17833 .25066 0.000 .24944 .02 81063 27.522 112.271 21.2513 1.08768 .25083 .001 .24967 .06 81062 27.514 112.016 21.2597 1.00108 .25107 .001 .25004 .08 81061 27.507 111.860 21. 2648 .91871 .25158 .001 .25062 .24 81060 41.111 112.368 21.4165 1.17716 .25664 .001 .25538 -.12

81059 41.092 112.085 21.4254 1.08650 .25644 .001 .25533 -.27

81058 41.105 111.867 21.4326 .99996 .25671 .001 .25571 -.23

81057 41.095 111.688 21.4383 .91763 .25698 .001 .25607 -.17

81056 54.606 112.228 21.5798 1.17584 .26166 .001 .26063 -.48

81055 54.602 112.043 21.5856 1.08571 .26227 .001 .26114 -.37

81054 54.592 111.958 21.5881 1.00016 .26280 .001 .26171 -.19

81053 54.584 111.824 21.5922 .91759 .26277 .001 .26175 -.23

81052 69.187 111.681 21.7602 .91630 .26869 .001 .26772 -.44

81051 69.187 112.147 21.7460 1.08608 .26853 .001 .26729 -.39

81050 69.182 112.291 21.7416 1.17576 .26808 .001 .26676 -.52

81049 69.183 111.984 21.7509 .99974 .26873 .001 .26758 -.35

Exper 1 mental Adjusted Ther ma

1

Conduct! v 1 ty Thermal at • nominal dev I at I on Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 135 K from correlation

MPa K mo 1 /L W/m W/m.K W/m.K percent

81096 .443 134.971 20.0461 1.16453 .21724 0.000 .21725 .14 81095 .441 134.640 20.0584 1.06426 .21770 0.000 .21782 .21 81094 .439 134.361 20.0687 .96848 .21762 0.000 .21783 .05 81093 .437 134.071 20.0795 .87763 .21817 0.000 .21847 .18 81092 13.900 134.854 20.2847 1.16385 .22558 0.000 .22563 .20 81091 13.896 134.565 20.2947 1.06351 .22591 0.000 .22606 .23 81090 13.892 134.184 20.3080 .96755 .22579 0.000 .22607 .03 81089 13.886 134.078 20.3116 .87726 .22667 .001 .22699 .38 81088 27.791 134.744 20.5084 1.16294 .23321 0.000 .23330 .07 81087 27.783 134.456 20.5179 1.06278 .23357 .001 .23376 .12 81086 27.777 134.246 20.5247 .96747 .23395 0.000 .23422 .21 81085 27.772 134.088 20.5299 .87687 .23434 .001 .23467 .32 81084 40.170 134.918 20.6844 1.26688 .23997 .001 .24000 .18 81083 40.158 134.690 20.6914 1.16220 .24001 0.000 .24013 .12 81082 40.151 134.471 20.6983 1.06229 .24029 .001 .24049 .17 81081 40.146 134.226 20.7060 .96729 • 24 C66 .001 .24095 .24 81080 53.222 134.401 20.8796 1.06189 .24702 0.000 .24725 .15 81079 53.219 134.180 20.8863 .96629 .24709 0.000 .24741 .11 81078 53.210 134.994 20.8614 1.26674 .24647 0.000 .24647 .12 81077 53.203 134.748 20.8688 1.16220 .24677 .001 .24687 .16 81076 66.735 134.363 21.0553 1.06149 .25355 .001 .25381 .08 81075 66.733 135.047 21.0352 1.37460 .25389 .004 .25387 .41 81074 66.732 134.838 21.0413 1.26622 .25306 0.000 .25313 .03 81073 66.731 134.711 21.0450 1.16176 .25338 0.000 .25350 .12 Experl mental Adjusted Ther ma 1 Conductl vl ty

Ther me 1 at a nominal dev 1 at ion Run Pt. Pressure T emper ature Dens 1 ty Power Conductivity STAT Temperature of 155 K from correlation

MPa K mol /L W/m W/m.K W/m.K percent

81024 .951 156.011 19.2625 1.05211 .19721 .001 .19698 .20 81023 .950 155.629 19.2771 .94894 .19766 .001 .19752 .23 81022 .950 155.403 19.2858 .85082 .19783 .001 .19774 .21 81021 .948 155.076 19.2982 .75849 .19815 .001 .19813 .21 81020 13.362 156.240 19.5215 1.15979 .20547 .001 .20517 .11 81019 13.368 155.886 19.5342 1.05120 .20589 .001 .20568 .15 81018 13.365 155.578 19.5451 .94788 .20601 .001 .20587 .07 81017 13.371 155.271 19.5561 .85014 .20655 .001 .20648 .19 81016 27.360 156.006 19.7976 1.15866 .21455 .001 .21430 .05 81015 27.335 155.801 19.8039 1.04995 .21483 .001 .21463 .10 81014 27.358 155.382 19.8182 .94674 . 21534 .001 .21524 .16 81013 27.345 155.255 19.8222 .84912 .21546 .001 .21539 .17 81012 40.840 155.870 20.0346 1.15800 .22250 .001 .22227 -.07

81011 40.845 155.644 20.0417 1.04989 .22309 .001 .22292 .11 81010 40.853 155.268 20.0537 .94635 .22315 .001 .22308 -.00

81009 40.866 155.129 20.0582 .84880 .22345 .001 .22342 .08

40
81006 53.815 156.283 20.2280 1.27105 .22987 0.000 .22952 .09

81007 53.813 155.908 20.2392 1.15699 .23018 .001 .22993 .09 81006 53.813 155 .688 20.2458 1.04892 .23056 .001 .23037 .18 81005 53.808 155.405 20.2542 .94565 .23066 .001 .23055 .12 81004 67.356 156.172 20.4315 1.27085 .23758 .001 .23725 .20 81003 67.356 155.796 20.4422 1.15668 .23770 .001 .23747 .13 81002 67.352 155.602 20.4477 1.04875 .23814 .001 .23797 .25 81001 67.348 155.390 20.4538 .94524 .23802

Exper 1 mentsl

Therm*

1

.001 .23791

Adjusted Theraal

at a nominal

.13 Conduct 1 v 1 ty devl at Ion Bun Pt. Pressure

HP*

T emper ature

K Dens 1 tymo 1 /L PowerW/»

Conductl vi ty

W /» • K STAT Temperature of 175 K W/m.K

f roa cor re 1 at 1 on percent

81048 1.019 175.465 18.5019 .97794 .17714 .001 .17706 -.20

81047 1.018 175.148 18.5146 .87206 .17754 .001 .17751 -.16

81046 1.014 174.727 18.5314 .77209 .17816 .001 .17821 -.04

81045 1.013 174.391 18.5448 .67870 .17852 .001 .17863 -.03

81044 13.930 175.765 18.8323 1.08985 .18721 0.000 .18707 -.10

81043 13.927 175.293 18.8492 .97715 .18733 .001 .18728 -.27

81042 13.923 174.912 18.8631 .87128 .18770 .001 .18772 -.26

81041 13.916 174.645 18.8726 .77168 .18813 .001 .18819 -.16

81040 27.796 175.447 19.1589 1.08822 .19703 0.000 .19695 -.26

81039 27.794 175.218 19.1665 .97629 .19726 .001 .19722 -.24

81038 27.798 174.668 19.1850 .87053 .19783 .001 .19789 -.20

81037 27.797 174.450 19.1923 .77088 .19822 .001 .19832 -.10

81036 41.317 175.339 19.4336 1.08796 .20591 .001 .20584 -.27

81035 41 .317 174.999 19.4442 .97617 .20635 .001 .20635 -.19

81034 41 .317 174.650 19.4551 .87058 .20681 .001 .20688 -.11

81033 41.310 174.355 19.4642 .77100 .20717 .001 .20730 -.06

81032 53.962 175.581 19.6560 1.20648 .21372 .001 .21360 -.13

81031 53.957 175.267 19.6652 1.08805 .21395 .001 .21390 -.14

81030 53.955 175.004 19.6730 .97625 .21426 .001 .21426 -.10

81029 53.949 174.706 19.6817 .87025 .21430 .001 .21436 -.19

81028 66.405 175.540 19.8657 1.20471 .22104 .001 .22093 -.11

81027 66.399 175.276 19.3731 1.08657 .22136 .001 .22130 -.06

81026 66.379 174.808 19.8860 .97479 .22167 .001 .22171 -.08

81025 66.377 174.635 19.8909 .86914 .22202

Experl rental

Therm*

1

.001 .22210

Adjusted Theraal

at a noalnal

.02 Conductl v 1 ty

deviation

Bun Pt. Pressure

HP* Temperature

K Dens 1 ty

mo 1 /L PowerW/m

Conduc 1 1 y 1 ty

W/m.K

STAT Temperature of 195 K W/m.Kfrom correlation

percent

80040 .950 195.294 17.6766 .87502 .15772 .001 .15768 -.08

80039 .969 194.368 17.6949 .76891 .15803 .001 .15805 -.15

80038 .948 194.550 17.7085 .67000 .15849 .001 .15855 -.05

80037 .947 194.219 17.7227 .57768 .15892 .001 . 15903 .02 80036 14.520 195.460 18.1208 .98654 .16938 .001 .16931 -.25

80035 14.520 195.134 18.1330 .87347 .17005 .001 .17003 -.03

80034 14.521 194.717 13.1487 .76785 .17051 .001 .17055 .02 80033 14.520 194.349 18.1625 .66885 .17075 .001 .17084 -.03

80032 27.378 195.334 18.4779 .98607 .17982 .001 .17977 -.08

80031 27.372 194.895 18.4927 .87365 .18035 .001 .18037 .01 80030 27.368 194.640 18.5013 .76780 .18052 .001 .18057 -.01

80029 27.363 194.243 18.5147 .66881 .18098 .001 .18109 .06 80028 39.331 195.664 18.7522 1.10423 .18798 .001 .18788 -.11

80027 39.325 195.269 18.7646 .98474 .18860 .001 .18856 .05 80026 39.325 194.871 18.7773 .87231 .18888 .001 .18890 .02 80025 39.318 194.474 18.7897 .76704 .18934 .001 .18942 .10 80024 53.388 195.893 19.0434 1.23022 .19732 .001 .19719 .03 80023 53.388 195.491 19.0553 1.10390 .19762 .001 .19755 .02 80022 53.386 195.045 19.0685 .98461 .19809 .001 .19808 .08 80021 53.379 194.639 19.0804 .87217 .19842 .001 .19847 .09

80020 67.210 195.695 19.3123 1.23013 .20594 .001 .20584 .02 80019 67.208 195.277 19.3240 1.10370 .20610 .001 .20606 -.06

80018 67.210 194.985 19.3322 .98419 .20646 .001 .20646 .00 80017 67.215 194.585 19.3435 .87159 .20692 .001 .20698 .07 80016 .926 195.273 17.6766 .87406 .15702 .001 .15698 -.52

80015 .926 194.811 17.6965 .76831 .15755 .001 .15758 -.47

80014 .926 194.391 17.7145 .66929 .15794 .001 .15803 -.48

80013 .926 194.165 17.7242 .57725 .15832 .001 .15844 -.38

80012 11.514 195.518 18.0269 .98613 .16633 0.000 .16626 -.54

80011 11.513 195.096 18.0432 .87354 .16677 .001 .16676 -.50

80010 11.503 194.602 18.0619 .76784 .16740 .001 .16746 -.39

80009 11.498 194.370 18.0707 .66893 . 16741 .001 .16750 -.51

80008 20.838 195.405 18.3032 .98625 .17422 .001 .17416 -.41

80007 20.835 195.011 18.3172 .87366 .17463 .001 .17463 -.37

80006 20 .837 194.625 18.3311 .76796 .17514 .001 .17519 -.27

80005 20.831 194.297 18.3426 .66887 .17518 .001 .17528 -.41

80004 29.520 195.695 18.5194 1.10534 .18063 .001 .18053 -.13

80003 29.517 195.272 18.5336 .98565 .18099 .001 .18095 -.33

80002 29.510 194.914 18.5455 .87292 .18151 .001 .18152 -.21

80001 29.503 194.507 18.5590 .76735 .18201 .001 .18208 -.12

41
Experimental Adjusted Thermal Conductivity

Thermal at a nominal deviation

! un Pt

.

Pressure Temperature Oens 1 ty Power Conductlvl ty STAT Temperature of 215 K from correlation

MPa K mo 1 / L W/m W/m.K W/m.K percent

8 0066 1.071 215.119 16.7880 .76791 .13923 .001 .13921 .22 80063 1.071 216.672 16.8092 .66502 .13935 .001 .13939 -.00

80062 1.070 216.330 16.8253 .56983 .13992 .001 .16001 .18 80061 1.069 213.891 16.8659 .66250 .16007 .002 .16022 -.01

80060 16.225 215.378 17.3638 .85777 .15186 .001 .15179 -.20

80059 16.226 216.926 17.3617 .76762 .15262 .001 .15263 -*07

80058 16.221 216.510 17.3780 .66667 .15276 .001 .15282 -.07

80057 16.219 216.110 17.3937 .56978 .15299 .002 .15311 -.16

80056 27.596 215.508 17.7876 .97568 .16312 .001 .16306 -.22

80055 27.590 215.106 17.8015 .85729 .16372 .001 .16371 -.05

80056 27.587 216.652 17.8173 .76706 .16606 .001 .16608 -.07

80053 27.588 216.335 17.8286 .66636 .16665 .001 .16653 .02 80052 60.919 215.396 18.1631 .97639 . 17357 .001 .17352 -.06

80051 60.926 215.020 18.1752 .85669 .17363 .001 .17363 -.29

80050 60.929 216.622 18.1880 .76633 .17616 .001 .17619 -.06

80069 60.933 216.260 18.1996 .66372 .17667 .001 .17656 -.03

80068 53.959 215.637 18.6712 1.09933 .18253 .001 .18265 .05 80067 53.960 215.290 18.6815 .97363 .18275 .001 .18272 .02 80066 53.957 216.860 18.6961 .85612 .18337 .001 .18339 .19 80065 53.951 216.636 18.5066 .76606 .18361 .001 .18368 .15 80066 67. 563 215.666 18.7687 1.09909 .19185 .001 .19180 .31 80063 67.563 216.923 18.7832 .97606 .19211 .001 .19212 .26 80062 67.566 216.769 18.7880 .85595 .19233 .001 .19236 .29 80061 67. 539 216.269 18.8013 .76590 .19230 .001 .19238 .09 Experimental Adjusted Thermal Conduct I v 1 ty

Therma

1

at a nominal dev 1 at 1 on

fun Pt. Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 225 K from correlation

MPa K mol /L W/m W/m .K W/m.K percent

83032 .282 226.278 .1580 .08368 .01371 .003 .01358 1.56

83031 .282 225.662 .1586 .06638 .01358 .006 .01353 1.21

83030 .282 226.662 .1595 .05111 .01367 .005 .01353 1.16

83029 .282 223.753 .1601 .03786 .01368 .008 .01361 1.76

83028 .601 223.606 .2363 .03786 .01359 .008 .01376 1.66

83027 .606 226.066 . 2339 .08366 .01388 .003 .01377 1.71

83026 .609 225.279 .2365 .06637 .01380 .006 .01377 1.67

83025 .611 226.256 .2395 .05109 .01373 .006 .01381 1.89

Exper 1 mertal Adjusted Thermal Conduct 1 v 1 ty

Therma 1 at a nominal deviation

fun Pt. Pressure T emper ature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 235 K from correlation

MPa K mo 1 / L W/m V/m.K W/m.K perce nt

83066 .270 232.979 .1661 .02789 .01611 .012 .01633 -.56

83063 .270 235.295 .1665 .06957 .01666 .003 .01663 .19 83062 .271 236.388 .1655 .05358 .01633 .005 .01660 -.05

83061 .271 233.661 .1660 .03970 .01625 .007 .01639 -.07

83060 .609 235.876 .2236 .08767 .01676 .003 .01665 .69 83039 .612 235.098 .2266 .06958 .01663 .006 .01662 .26 83038 .615 236.239 .2287 .05357 .01651 .005 .01659 .06 83037 .617 233.532 .2311 .03970 .01666 .007 .01662 .18 03036 .602 235.696 .3622 .08761 .01506 .003 .01699 .99 83035 .606 336.802 .3663 .06955 .01696 .003 .01698 .90 83036 .609 236.098 .3698 .05356 .01689 .005 .01699 .89 83033 .613 233.668 .3535 .03967 .01681 .007 .01697 .75 79076 1.736 235.623 15.7923 .71227 .12106 .001 .12095 .16 79075 1 .736 235.120 15.8196 .60752 .12156 .001 .12156 .21 79076 1.736 236.698 15.8627 .51087 .12180 .002 .12186 .09 79073 16.816 235.837 16.5361 .82606 .13586 .001 .13573 -.20

79072 16.808 235.390 16.5565 .71237 .13610 .001 .13605 -.26

79071 16.307 236.896 16. 5751 .60772 .13665 .002 .13666 -.29

79070 16.795 236.395 16.5955 .51085 .13631 .002 .13639 -.67

79069 29.769 236.015 17.1375 .96638 .16932 .001 .16919 -.30

79068 29.768 235.693 17.1559 .82669 .16983 .001 .16977 -.21

79067 29.765 235.039 17.1718 .71163 .16997 .001 .16997 -.33

79066 29.762 236.575 17.1881 .60696 .15037 .002 .15062 -.28

79065 66.685 235.715 17.6800 .96607 .16310 .001 .16302 -.00

79066 66.681 235.230 17.6950 .82658 . 16316 .001 .16311 -.18

79063 66.6e0 2 36 . 8

1

7 17.7077 .71162 .16366 .001 .16366 -.17

79062 66.676 236.553 17.7157 .60633 .16336 .002 .16339 -.36

79061 67.096 235.860 18.1935 1.07669 .17702 0.000 .17693 .16 79060 67.093 235.608 18.2060 .96683 .17730 .001 .17726 .13 79059 67.096 235.000 18.2173 .82353 .17776 .001 .17776 .26 79058 67.099 236.578 18.2291 .71059 .17815 .001 .17819 .29

42
Experl mental Adjusted Thermal Conduct 1 v 1 ty Therma 1 at a nominal dev 1 at 1 on Run Pt. Pressure Temperature Dens 1 ty Power Conduc 1 1 v i ty STAT Temperature of 265 K from corre lati on MPa K mo 1 /l V/m V/m.K V/m.K percent

83012 .296 266.118 .1699 .09166 .01568 .003 .01536 -.96

83011 .296 265.283 .1505 .07276 .01537 .006 .01536 -1.07

83010 .296 266.378 .1511 .05606 .01525 .005 .01532 -1.21

83009 .295 263.666 .1520 .06152 .01525 .008 .01560 -.71

83008 .681 265.875 .2526 .09162 .01578 .003 .01568 -.28

83007 .681 265.065 .2536 .07272 .01553 .006 .01552 -1.33

83006 .681 266.183 .2568 .05602 .01558 .005 .01567 -.39

83009 .681 263.666 . 2557 .06151 .01561 .008 .01558 -1.00

83006 .633 265.735 .3620 .09175 .01590 .006 .01582 -.66

83003 .636 266.967 .3669 .07281 .01582 .006 .01582 -.67

83002 .661 266.163 .3695 .05609 .01576 .006 .01585 -.56

83001 .665 263.571 .3529 .06155 .01569 .009 .01585 -.63

Exper i mental Adjusted Thermal Conduct I v 1 ty

Therma 1 at a nom In al dev 1 at 1 on Run Pt. Pressure Temperature Dens 1 ty P ower Conduct 1 v 1 ty STAT Temperature of 255 K from correlation

MPe K mo 1 /L V/m V/m.K V/m.K percent

83026 .309 253.199 .1529 .03051 .01610 .016 .01630 -1.96

83023 .309 255.368 .1516 .07606 .01630 .005 .01626 -2.21

83022 .309 256.535 .1520 .05859 .01629 .006 .01636 -1.69

83021 .309 253.732 .1525 .06362 .01616 .008 .01628 -2.07

83020 .708 255.761 .3667 .09572 .01701 .003 .01692 -.98

83019 .708 256.898 .3686 .07602 .01693 .006 .01696 -.90

83016 .708 256.158 .3698 .05855 .01686 .005 .01693 -.96

83017 .708 253.565 .3710 .06360 .01672 .009 .01688 -1.29

83016 1.082 253.366 .6071 .06338 .01750 .008 .01768 .37 83013 1.086 255.373 .6003 .09570 .01769 .003 .01765 .26 83016 1.087 256.680 .6050 .07596 .01765 .006 .01769 .61 83013 1.090 253.937 .6101 .05851 .01757 .005 .01769 .37

79101 2.677 256.669 16.7729 .77306 .10665 .001 .10656 .85 79100 2.669 253.960 16.8063 .65908 .10696 .001 .10713 .92 79099 2.661 253.325 16,8626 .55661 .10729 .002 .10756 .73 79098 2.651 252.902 16.8678 .65869 .10731 .002 . 10766 .62 79097 12.529 256.110 15.6003 .77181 .11972 .001 .11985 -.17

79096 12.525 253.596 15.6262 .65828 .12022 .001 .12063 -.06

79095 12.519 253.101 15,6669 .55377 .12081 .002 .12110 . 16 79096 12.521 252.573 15.6718 .65866 .12085 .002 .12121 -.16

79093 20.228 256.603 16.0363 .89508 .12799 .001 .12808 -.23

79092 20.226 253.858 16,0565 .77210 .12823 .001 .12839 -.33

79091 20.226 253.388 16.0759 .65866 .12861 .001 .12886 -.28

79090 20.222 252.996 16.0918 .55379 .12921 .002 .12950 -.02

79089 33.115 256.159 16.6260 .89381 .16065 .001 .16056 -.01

79088 33.115 253.660 16.6615 .77110 .16056 .001 .16072 -.17

79087 33.115 253.187 16.6581 .65770 .16081 .002 .16105 -.19

79086 33.120 253.031 16.6638 .60628 .16107 .001 .16133 -.08

79085 68.192 256.116 17.1569 .95866 .15268 .001 .15278 .20 79086 68.196 253.881 17.1622 .89373 .15305 .001 .15318 .35 79083 68.196 253.385 17.1776 .77139 .15326 .001 .15365 .29 79082 66.188 253.005 17.1991 .65775 .15335 .001 .15358 .20 79081 67.252 256.209 17.6909 1.02500 .16612 .001 .16620 .66 79080 67.252 253.703 17.7068 .89360 .16666 .001 .16659 .68 79079 67.252 253.193 17.7188 .77097 .16670 .001 .16688 .65 79078 67.252 252.879 17.7275 .65739 .16692 .001 .16713 .66

Exp er 1 menta

1

Adjusted Thermal Conduct 1 v 1 ty

Thermal at a nominal deviation

Run Pt. Pressure Temperature Dens 1 ty P owe r Conduct 1 vl ty STAT Temperature of 265 K from cor r a 1 at 1 on MPa K *0 1 /L V/m V/m.K V/m.K percent

82065 .269 265.102 .1162 .07917 .01731 .006 .01730 -2.20

82066 .269 266.337 .1166 .06099 .01722 .005 .01730 -2.22

82063 .269 263.562 .1169 .06521 .01710 .008 .01727 -2.60

82062 .269 262.977 .1172 .03177 .01706 .012 .01729 -2.25

82061 .682 265.752 .2306 .09969 .01757 .006 .01768 -2.55

82060 .682 266.908 .2315 .07915 .01759 .006 .01760 -1.88

82059 .682 266.097 .2323 .06098 .01766 .006 .01756 -2.10

82058 .682 263.393 .2331 .06518 .01766 .009 .01762 -1.76

82057 .853 265.636 .6296 .09962 .0iei9 .003 .01816 -1.26

82056 .853 266.620 .6312 .07912 .01806 .006 .01810 -1.66

82055 .853 263.885 .6328 .06095 .01796 .006 .01809 -1.57

82056 .853 263.258 .6363 .06519 .01788 .008 .01808 -1.61

82053 1.153 265.203 .6079 .09966 .01866 .005 .01862 -.76

82052 1.155 266.356 .6123 .07915 .01 858 .006 .01865 -.39

82051 1.158 263.693 .6169 .06097 .01852 .006 .01867 -.56

82050 1.161 263.160 .6205 .06519 .01866 .010 .01867 -.38

82069 1.523 266.825 .8596 .09966 .01961 .003 .01963 1.63

82068 1.525 266.132 .8662 .07913 .01959 .005 .01969 1.87

82067 1.528 263.678 .8726 .06097 .01969 .006 .01966 1.68

43
820*6 1.532 262.98* .8792 0*517 .019*3 009 01966 1.60

Exoer 1 mental Adjusted Thermal Conduct 1 v 1 ty

Therma 1 at a nominal devl at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conduct 1 vl ty STAT Temperature of 275 K from correlation

MPa K mo 1 / L W/m W/m.K W/m.K percent

82089 .330 275.153 .1*89 .08240 .018*2 .003 .018*0 -3.11

82088 .330 27*. 297 .1*9* .06351 .01838 .006 .018*7 -2.72

82087 .330 273.611 .1*98 .0*708 .01828 .008 .018*6 -2.79

82086 .330 273.020 .1502 .03310 .01801 .01* .01827 -3.89

82085 .698 275.652 .3276 .10373 .01901 .003 .01892 -2. *0 8208* .698 27*. 7** .3289 .082*1 .01887 .00* .01890 -2.52

82083 .698 27*. 038 .3300 .063*8 .01879 .005 .01892 -2. *6 82082 .698 273.395 .3310 .0*706 .01870 .009 .01891 -2.50

82081 1.037 275.327 . 5085 .10372 .01952 .003 .019*8 -1.61

82080 1.037 27*. 5** .5105 .08239 .019*0 .00* .019*6 -1.71

82079 1.037 273.897 .5123 .063*7 .01923 .005 .01938 -2.16

82078 1.037 273.27* .5139 .0*707 .01916 .008 .01939 -2.10

82077 1.299 275.168 . 6601 .10370 .01989 .002 .01987 -1.37

82076 1.302 27*. 37* .6651 .08236 .0198* .004 .01993 -1.12

32075 1.312 273.772 .6736 .063*7 .01976 .005 .01993 -1.20

8207* 1.316 273.259 .6782 .0*705 .01971 .010 .01995 -1.1*

82073 1.609 275.682 .85*8 .12757 .02065 .002 .02055 -.21

82072 1 .613 274.976 .8613 .10375 .02059 .003 .02059 -.08

82071 1 .618 27*. 238 .86 90 .082*0 .020*9 .00* .02060 -.13

82070 1.619 273.6*9 .8735 .063*9 .020*4 .006 .0206* -.01

82069 2.062 275.238 1.1950 .1275* .02212 .003 .02208 3.05

82068 2.06* 27*. 610 1.2038 .10376 .02217 .003 .02223 3.61 82067 2.066 273.90* 1.213* .082*0 .02211 .00* .02228 3.73

82066 2.069 273.369 1.2219 .063*7 .02206 .006 .02232 3.79

79026 *.962 276.523 13.53*5 .71938 .09236 .001 .09207 1.38

79025 *.960 275.92* 13.5805 .60512 .0927* .001 .09256 1.25

7902* *.959 275.201 13.6355 .50102 .09356 .001 .09352 1 . *7 79023 *.959 27*. 611 13.6802 .*0657 .09396 .002 .09*03 1.36

79022 *.959 27*. 197 13.7111 .3220* .09*37 .002 .09*52 1.42

79021 11.792 276.1*8 14.4292 .71955 .1037* .001 .10353 -.03

79020 11.792 275.5*6 14.4620 .60527 .10*07 .001 .10397 -.10

79019 11.793 27*. 955 14.49*1 .50101 .10*55 .001 .10*56 -.01

79018 11.792 2 7* . **0 14.5210 .40662 .10503 .002 .10513 .13 79017 19.380 275.8*0 1

c

. 066 6 .719*8 .11352 .001 .11338 -.38

79016 19.382 275.289 15.0913 .6051* .11381 .001 .11376 -.*0

79015 19.381 27*. 798 15.1131 .50085 .11*23 .001 .11*26 -.28

7901* 19.381 27*. 335 15.1336 .*0639 .11*55 .002 .11*66 -.2*

79013 32.560 27*. *66 15.8752 .50075 .12802 .002 .12810 -.11

79012 32.562 276.1*1 15.814* .8*290 .12681 .001 .1266* -.37

79011 32.561 275.511 I s . 8373 .71910 .1272* .001 .12716 -.29

79010 32. 558 27*. 956 15.8573 .60*68 .12762 .001 .12763 -.22

79009 *8.703 276.9*2 16.46*6 1.11881 .1*02* .001 .13998 .08 79008 *8.703 276.326 16.4837 .975*9 .1*060 .001 .1*0*2 .11 79007 *8.701 275.7*5 16.5017 .8*178 .1*085 .001 .1*075 .08 79006 *8.699 275.265 16.5165 .71801 .1*112 .001 .1*108 .10 79005 65.593 277.211 17.0107 1.27276 .15281 .001 .15256 .68 7900* 65.593 276.677 17.025* 1.119*6 .15320 .001 .15301 .76 79003 65.619 276.110 17.0*19 .97570 .153*5 .001 .15332 .73 79002 65.618 275.551 17.0573 .8*216 .15375 .001 .15369 .7* 79001 65.622 275.160 17.0682 .71829 .15*23 .001 .15*21 .92

Experl ment a 1 Adjusted Thermal Conduct 1 v 1 ty

Thermal at a nominal dev 1 at 1 on Run Pt. Pressure Temperature Den* 1 ty Power Conductlvl ty STAT Temperature of 285 K from correlation

MPa K mol /L W/m V/m.K W/m.K percent

82021 .2*7 286.16* .1060 .1076* .01960 .002 .019*5 -3.71

82020 .2*7 285.222 .106* .08552 .01953 .003 .01950 -3.**

82019 .2*7 28*. *0* .1070 .06589 .01937 .005 .019*5 -3.73

82018 . 2*8 283.6*8 .1075 .0*88* .01933 .006 .01951 -3. *2 82017 .821 283.3** .3772 .0*886 .01991 .008 .02013 -3. *5 82016 .821 285.52* .3736 .10768 .02019 .003 .02012 -3.48

82015 .821 28*. 73* .37*9 .08552 .02003 .003 .02007 -3.77

8201* .821 28*. 032 .3763 .06589 .02010 .005 .02023 -2.9*

82013 1 • **9 283.715 .7163 .06590 .02081 .005 .02099 -3.31

82012 l.**9 285.881 .7077 .13239 .02116 .002 .02103 -2.99

82011 1 . *50 285.110 .7112 .10767 .02112 .002 .02110 -2.70

82010 1 .*50 28*. 391 .71*2 .08552 .02103 .003 .02112 -2.68

82009 2.190 286.150 1.188* .15950 .02301 .002 .02283 -.67

82008 2.191 285.32* 1.196* .13229 .02296 .002 .02293 -.32

82007 2.191 28* .05* 1.2088 .085*5 .02292 .002 .02307 .1* 82006 2.192 283.033 1.219* .0*883 .0227* .007 .02305 -.06

82005 2.193 28*. 680 1.20*1 .10762 .02288 .003 .02293 -.*1

8200* 2.779 285.413 1.7119 .15957 .02565 .002 .02557 3.80 82003 2.779 284.073 1.7*03 .10766 .02585 .003 .02603 5.11

82002 2.779 266.061 1.6992 .18939 .02562 .002 .025*2 3.39

82001 2.779 284.671 1 .727* .13232 .02573 .003 .02579 *. *2

44
E x p e r 1 it e n t a 1 Adjusted Thermal Conduct 1 v 1 ty Therira 1 at a nos 1 na

1

deviation

Bun P t

.

Pressure Temperature Dens 1 ty Power Condue 1 1 v 1 ty STAT Temperature of 295 K from correlation

*Pa K no 1 /L W/m W / m . K W/m.K percent

820*5 . 299 296.023 .1200 .11166 • 0208C .003 .02067 -*.10

82C** .289 29*;. 0** .1205 .08871 . 02 C68 .005 .02067 -*.06

820*3 .289 29*. 331 . 12 OP .06833 .020*5 .007 .0205* -4.76

8 20*2 .299 293.565 .1211 .05070 .020*6 .010 .02065 -4.20

820*1 .855 296.326 .3729 .13725 .021*5 .003 .02127 -4.18

820*0 .855 295.392 .37*3 .11167 .02131 .00* .02126 -4.27

82039 .855 29*. 709 .375* .08866 .02132 .00* .02136 -3.79

82C38 .955 293.982 . 3766 .06833 .02120 .007 .0213* -3.92

8203? 1 .37e 295.892 .6337 .13730 .02208 .002 .02196 -4.15

8203* 1 ,3«* 295.161 .6392 .11166 .02199 .003 .02197 -*.17

82035 1 .39* 2^*. *29 .6*15 .08869 .0219* .005 .02202 -3. 96 8203* 1.388 293.7*2 .6*58 .06837 .02168 .006 .02185 -4.80

82033 2.118 293. **1 1.0786 .06835 .02322 .006 .023*5 -3.1*

82032 2.121 295. *10 1.0666 .1372* .023*1 .002 .02335 -3. ** 82031 2.123 29*. 653 1.0730 .11166 .02335 .003 .023*0 -3.30

82030 2.125 29*. 060 1.0791 .0886? .02326 .005 .023*2 -3.29

82029 2.967 295. *07 1.7078 .165*6 .02621 .002 .0261* -1.08

82028 2.971 29*. 702 1.7235 .1372* .02632 .003 .02637 -. *2 8202? 2.973 29*. 072 1 .7366 .11162 .02621 .00* .02637 -.61

82026 2.975 293.616 1.7*78 .0886* .026*0 .006 .02665 .25 92025 3.508 203.665 2 .3689 .11153 .03067 .005 .03097 4.99

8202* 3. 508 29*. 579 2.3308 .16532 .03027 .003 .03036 3.73

82023 3.508 29*. 115 2.3*90 .1371* . 03 C* 0 .00* .03060 4.15

82022 3.509 295.195 2.3072 .19617 .03002 .002 .02998 2.89

93069 .311 296.227 .1293 .11175 .02083 .003 .02067 -4.19

83067 .311 295.393 .1297 ,08e75 .02063 .006 .02058 -4.66

83066 .311 29*. 659 .1303 .068*1 .02060 .010 .0206* -4.33

83065 .311 293.906 .1307 .05073 .02051 .011 .02065 -4.29

8306* .8*0 293.702 .3698 .05071 .02116 .008 .02133 -3.65

83063 .8*0 295.810 .3667 .11172 .02139 .003 .0212e -4.06

93062 .8*0 295.069 .3678 .08875 .02127 .005 .02126 -4.18

83061 .8*0 29*. 373 .3689 .068*0 .02115 .007 .02123 -4.32

83060 1.36* 293. *70 .6337 .05071 .0217* .009 .02195 -4.18

83059 1.36* 295 .500 .6275 .11172 .02205 .003 .02198 -3.96

83058 1.36* 29*. 790 .6297 .08877 .02185 .005 .021 ee -*.*7

83057 1.36* 29*. 083 .6319 .068*1 . C2189 .006 .02202 -3.85

83056 2.1** 293.755 1.0935 .068*0 .02326 .006 .023*5 -3.37

83055 2.1*5 295.763 1.0795 .13732 .023*7 .003 .02336 -3.58

8305* 2.1*5 29*. 979 1.0851 .11176 .023*3 .003 .023*3 -3.32

83053 2.1*5 29*. *12 1.0892 .08877 .023*6 .006 .02355 -2.87

83052 2.923 293.95* 1.6^25 .0887* .0259* .005 .02612 -.91

83051 2.923 295.783 1.6618 .16559 .02593 .002 .02580 -1.72

83050 2.923 295.168 1.6722 .137.3 2 .02599 .003 .02596 -1.23

930*9 2.92* 29*. 5*6 1.6830 .11177 .02579 .005 .02587 -1.75

830*8 3.399 295.866 2.1327 .19658 .02872 .002 .02855 1.01

830*7 3.389 295.2** 2.1518 .1656* .02882 .002 .02877 1.46

830*6 3.399 294.691 2.1696 .13739 .02883 .003 .02890 1.59

830*5 3.390 294.168 2.187* .11170 .02901 .00* .02918 2.27

79057 5 .509 295.599 11.8597 .6*928 .07877 .001 .07862 2.60

79056 5.506 295.2*0 11.9018 .59221 .07918 .001 .07912 2.76

79055 5.503 294.776 11.9560 .53771 .07939 .001 .079*5 2.35

7905* 5.501 294.211 12.0213 .43623 .07998 .001 .08017 2.71

79053 5.500 293.5*8 12.0963 .3*553 .080*0 .001 .08075 2.53

79052 11.965 296.07* 13.28*9 .70935 .09160 .001 .09137 -.28

79051 11 .967 295.6*2 13.3122 .6*959 .09177 .001 .09163 -.36

79050 11.969 294.97* 13.35*4 .53758 .09202 .001 .09203 -.31

790*9 11.969 294.359 13. 3925 .43631 .09221 .001 .0923* -.68

790*9 11.970 293.856 13.4239 .3*567 .09279 .001 .09303 -.37

790*7 18.8*6 296.312 14.0700 .7716* .1013* .001 .10108 -.96

790*6 18.8*6 295.386 14.1150 .6*960 .10167 .001 .10159 -1.00

790*5 18.9*8 294.831 14.1*20 .53763 .1020* .001 .10207 -.96

790** 19.8*8 294.201 14.1725 .43637 .102*6 .001 .10262 -.88

790*3 18.8*8 293.719 14.1957 .3*570 .102*5 .001 .10270 -1.12

790*2 25.995 295.702 14.6650 .77211 . 10975 .001 .10960 -1.16

790*1 25.885 295.166 14.6905 .6*959 .11008 .001 .11005 -1.11

790*0 25.882 294.560 1* . ?1 5* .53763 .11021 .001 .11029 -1.2*

79039 25.885 293 .962 14.7*0* .43660 .11078 .002 .11097 -.97

79038 35.690 296.260 15.2*88 .90500 .11973 .001 .11951 -.67

79037 35.692 295.539 15.27*7 .77215 .11970 .001 .11961 -.96

79036 35.699 294.99* 15.29*4 .6*96* .12055 .001 .12055 -.**

79035 35.690 294.37* 15.3162 .53783 .12017 .001 .12028 -.96

7903* *9.708 296.69* 15.8916 1.0*823 .131*8 0.000 .13122 -.32

79033 *9.709 295. 818 l

1;. 9187 .90523 .13le7 .001 .1317* -.29

79032 *9.709 295.290 15.9353 .77225 .13213 .001 .13209 -.26

79031 *9.70* 294.619 15.9556 .65007 .1322* .001 .13230 -.39

79030 66.761 296.067 16.5290 1.0*916 .1**58 .001 .1***4 .*1 79029 66.763 295.429 16.5*65 .905*7 .1**92 .001 .1**86 ,46

79029 66.770 294.891 16.561* .77260 .1*512 .001 .1*513 • ** 79027 66.776 294.396 16.5750 .65002 .1*553 .001 .1*361 .38

45
Experimental Adjusted Thermal Conductivity

Thereat at a nominal deviation

Run Pt. Pressure Temperature Oens 1 1 y Power Conduct 1 v 1 ty STAT Teaperature of 305 K froa correlation

hPa K aol/L W/s W/e.K W/a. K percent

8*0*1 .2*1 302.965 .097* .05229 .02218 .012 .02239 -1.26

8*0*0 .2*1 303.561 .0972 .07051 .02206 .306 .02220 -2.11

8*039 .2*1 30* . **9 .0969 .091*8 .02196 .00* .02201 -3.01

8*038 .2*1 305.309 .0967 .11522 .02221 .00* .02218 -2.20

8*037 .639 302.718 .2667 .0523* .02232 .009 .02255 -2. *3 8*036 .639 303.335 .2660 .07058 .02250 .00* .02266 -1.92

8*035 .639 30*. 85* .26*5 .11516 .02256 .003 .02257 -2.30

8*03* .639 30*. 006 .2653 .091*1 .02252 .005 .02261 -2.1*

8*033 .959 305.696 .*057 .1*19* ,02307 .002 .02298 -2.06

8*032 .959 302.7*5 .*107 .05236 .02250 .007 .02271 -3.31

3*031 .959 303.313 .*097 .07062 .02266 .005 .02281 -2.86

8*030 .959 30*. 07* .*085 .09161 .02276 .003 .0228* -2.7*

8*029 .959 30*. 938 .*070 .11521 .02286 .002 .02286 -2.59

8*028 1.521 306.007 .6757 .17088 .02395 .002 .02360 -1.59

8*027 1.521 303.238 .68*7 .070*e .023*6 .005 .02359 -2.57

8*026 1.521 305.362 .6778 .1*166 .02382 .002 .02380 -1.60

8*025 1.521 30*. 51* .6805 .11508 .02375 .003 .02378 -1.7*

8*023 1.8*9 306.272 .8*67 .16998 .02*58 .002 .02*37 -1.18

8*022 1.8*9 305.761 .8*89 .1*11* .02*53 .002 .02**3 . -.96

8*021 1.8*9 30*. *22 .85*9 .11*2* .02*26 .003 .02*28 -1.6*

8*020 1.8*9 30*. 209 .8559 .09110 .02*23 .00* .02*27 -1.73

8*019 1.8*9 303.597 .8587 .070*5 .02375 .005 .02383 -3.61

8*018 1.853 303.292 .86*9 .070*9 .02*18 .005 .02*29 -1.7*

8*017 1.858 305.293 .8557 .1*152 .02*22 .002 .02*22 -1.93

8*016 1.858 30*. *9* .859* .11501 .02*02 .003 .02*0* -2.73

8*015 1.858 303.861 .8623 .09133 .02397 .003 .02*03 -2.80

8*01* 2.501 306.756 1.2260 .20287 .02581 .301 .025*7 -1.36

8*013 2.501 30*. 906 1.2*10 .1*1*3 .025*7 .001 .025*7 -1.56

8*012 2.501 30*. 332 1.2*57 .11507 .025*1 .002 .025*1 -1.86

8*011 2.501 306.052 1.2316 .17100 .02556 .001 .02537 -1.81

8*010 3.157 30*. 396 1.7239 .11553 .02762 .003 .02756 -.03

8*009 3.157 30*. 6*5 1.7200 .1*152 .0276* .002 .02760 .16 8*008 3.157 305.885 1.7012 .202*6 .02767 .001 .02750 .07 8*007 3.157 305.553 1.7062 .17096 .02769 .302 .02765 .53 8*006 3.792 305.536 2.3036 .20253 .03126 .001 .03125 3.76

8*005 3.792 307.396 2.2*95 .27562 .03122 .001 .030*6 2.12

8*00* 3.793 306.273 2.2819 .23720 .03110 .001 .03071 2 . *0 3*003 3.793 30*. 935 2.3226 .17072 .03110 .002 .03108 2.93

8*002 3.793 30*. 128 2.3*87 .11533 .031*6 .002 .03125 3.05

8*001 3.793 303.535 2.3686 .09152 .031** .00* .03117 2. *7

E xpe r 1 aent al Adjusted Theraal Conduct 1 v 1 ty Theraa 1 at a nominal deviation

Run Pt. Pressure Temperature Oens 1 ty Power Conduct 1 v 1 ty STAT Teaperature of 312 K froa correlation

XPe K vo 1 / L V/m W/e.K W/e.K percent

85165 .117 315.52* .0**8 .11631 .02283 .003 .022*0 -*.76

8516* .117 31*. *8* .0*51 .0923* .022e2 .00* .02252 -*.23

85163 .117 313.667 .0*52 .07116 .02269 .007 .022*9 -*.37

85162 .121 312.81* .0*68 .05268 .02218 .007 .02208 -6.31

85161 .637 31*. 792 .25*2 .11629 .0239* .903 .02361 -1.68

85160 .637 313.738 .2551 .0923* .0238* .005 .02363 -1.56

85159 .638 313.15* .2558 .07106 .02369 .006 .02355 -1.93

85158 .638 312. *99 .2566 .05262 .02361 .006 .02355 -1.95

8 5157 1.076 31*. *60 .**38 .11626 .02**1 .003 .02*12 -1.59

85156 1.077 313.728 .**53 .09230 .02*2* .303 .02*0* -1.97

85155 1.077 313.012 .**66 .07111 .02*05 .005 .02393 -2. *3 8515* 1.077 312. *39 .**78 .05266 .02*06 .310 .02*01 -2.11

85153 1.919 31*. 805 .8*68 .1*291 .02553 .002 .02522 -1.7*

85152 1.919 313.965 .8503 .11610 .02525 .002 .02503 -2.5*

85151 1.923 313.310 .8555 .09216 .02526 .003 .02511 -2.27

8 5150 1.92* 312.571 .8589 .07098 .02*87 .005 .02*81 -3.58

851*9 2.577 31*. 525 1.2135 .1*298 .02669 .002 .026*3 -1.53

851*8 2.573 313.751 1.2166 .11619 .02660 .002 .026*2 -1.62

851*7 2.573 313.090 1.2215 .09223 .0265* .003 .026*2 -1.65

851*6 2.573 312. *8* 1.2262 .07101 .02653 .005 .026*8 -1.51

851*5 3.121 31*. 137 1.5666 .1*292 .02805 .002 .02785 -1.00

851** 3.121 313.535 1.5736 .11620 .02788 .002 .02773 -1.52

851*3 3.121 312. *97 1.5859 .07109 .02795 .005 .02790 -1.08

851*2 3.121 312.873 1.581* .09217 .02792 .003 .0278* -1.26

851*1 3.872 31*. 577 2.1*9* .17260 .03083 .002 .03066 -.17

851*0 3.872 313.83* 2.1661 .1*295 .03085 .002 .03072 -.2*

85139 3.872 313.183 2.1811 .11618 .03069 .003 .03061 -.87

85138 3.870 312.670 2.1911 .09223 .03062 .003 .03057 -1.15

85137 *.016 31*. 380 2.2883 .172*7 .031*8 .002 .0313* -.28

85136 *.016 313.708 2.3058 .1*289 .031*2 .003 .03131 -.66

85135 *.016 313.05* 2.3233 .11610 .03121 .003 .0311* -1.52

8513* *.016 309.155 2. **02 .09312 .03205 .00* .0323* .26 85133 *.556 311 .722 3.0285 .03729 .03*8* .31* .03*85 -3.30

46
85132

85131

85130

85129

85128

85126

85125

85128

85123

85122

85121

85120

85119

85118

85117

85116

85115

85118

85113

85112

85111

85110

85109

85108

85107

85106

85105

85108

85103

85102

85101

85100

85099

85098

85097

85096

85095

85098

85093

85092

85091

85090

35089

85088

85087

85086 8 5085 85088

85083

85082

8*081

85080

85079

35078

85077

35076 8 5075

85078

85073

85072

85071

85070

35069

85068

85067

85066

85065

85068

85063

85062

85061

85060

85059

85053

85057

85056

85055

85058

85053

85052

85051

85050

85089

85068

85087 8886466666444555555555555555555c555C55555555555555c5c55555666666666666666667677888899 5 56 312.873 2.9648 .11682 .03550 .003 .03548 -.21

,556 311.752 3.0268 .05298 .03528 .011 .03529 - 1.98

,556 312.101 3.0069 .07148 .03539 .007 .03539 -1.30

556 312.375 2.9917 .09266 .03504 .004 .03503 - 2.03

,789 312.983 3.2522 .11708 .03728 .003 .03728 -.98

,789 312.000 3.3247 .03746 .03699 .018 .03699 - 3.30

,789 311.899 3.3326 .05311 .03829 .011 .03829 .05

788 312.323 3.2994 .07179 .03831 .007 .03831 .77

,750 316.586 3.0395 .09254 .03693 .005 .03700 2.50

,898 312.203 3.5946 .09236 .03966 .005 .03966 - 1.89

908 313.328 3.5090 .17236 .03903 .002 .03907 - 1.60

,908 312.858 3.5518 .14290 .03945 .003 .03947 - 1.46

,908 312.889 3.5915 .11610 .03941 .003 .03942 - 2.45

,111 313.386 3.9436 . 2047 e .04262 .002 .04273 - 1.80

111 312.085 4.1425 .09246 .04415 .007 .04416 - 2.73

,111 312.980 4.0003 .17248 .04309 .003 .04317 - 1.99

,111 312.558 4.0642 .14295 .04358 .005 .04362 - 2.29

111 311.923 4.1713 .11614 .04409 .007 .04408 - 3.52

208 312.082 4.4616 .11646 .04704 .006 .04704 - 3.02

,208 313 . C 07 4.2601 .20475 .04513 .003 .04524 - 2.77

,208 312.519 4.3558 .17245 .04583 .003 .04589 - 3.35

208 312.071 4.4548 .14263 .04624 .004 .04625 - 4.65

827 312 . C 95 5.5904 .11681 .05962 .007 .05964 .34

,827 312.909 5.1924 .20515 .05547 .004 .05566 -.08

827 312.897 5.3762 .17287 .05626 .004 .05637 - 1.96

,827 312.528 5.3651 .14388 . 057 e 9 .005 .05800 1.10

,817 313.180 5.0542 .24013 .05482 .003 .05506 1.27

,818 312.829 5.3524 .20441 .05518 .004 .05527 - 3.57

818 312.065 5.5454 .17217 .05688 .004 .05689 - 3.76

818 311.837 5.6833 .14262 . 0577

C .009 .05767 -4.49

,899 312.758 5.6999 .23993 .06068 .003 .06087 .77 899 312.852 5.8855 .20502 .06256 .003 .06267 1.14

899 312.830 5.8996 .17307 .06433 .005 .06444 3.67

899 311.620 6.5363 .14255 .06516 .006 .06507 - 2.14

576 312.283 6.6322 .20452 .06744 .004 .06752 . 78 576 311.910 6.9576 .17228 .06822 .004 .06820 -.39

576 311.810 7.0474 .14281 .06930 .006 .06926 .67

576 311.488 7.3857 .11599 .07008 .010 .06997 .38

603 312.282 6.8541 .20474 .06877 .004 .06865 1.16

603 311.992 7.1066 .17243 .06897 .004 .06897 -.03

60 ? 311.693 7.3723 .14280 .07008 .007 .07002 .48

608 311.888 7.5572 .11601 .07084 .003 .07075 1.05

671 312.881 7.2406 .23953 .06933 .003 .06945 .10

671 312.179 7.4552 .20444 .06953 .004 .06957 -.39

671 311.801 7.7586 .17217 .07028 .005 .07024 .04

672 311.720 7.8248 .14265 .06992 .007 .06987 -.56

770 312.890 7.8348 .23955 .06920 .003 .06931 - 1.38

770 312.170 8.0535 .20458 .06898 .004 .06901 - 1.90

770 311.882 8.5041 .17249 .06910 .005 .06905 - 1.63

770 311.609 8.4069 .14270 .06976 .007 .06972 -.73

830 312.513 8.1296 .23963 .06921 .003 .06931 - 1.46

830 312.199 e .3183 .20457 .06938 .003 .06941 - 1.23

830 311.858 8.5103 .17222 .06893 .003 .06891 - 1.82

830 311.788 8.5483 .14270 .06959 .005 .06957 -.84

924 312.939 e .2861 .27743 .06883 .002 .06900 - 1.85

928 312.838 8.5514 .23960 .06891 .002 .06897 - 1.71

928 312.183 8.6740 .20449 .06949 .003 .06951 -.81

928 311.910 8.8008 .17215 .06877 .003 .06876 - 1.80

06 9 313.330 8.6013 .31840 .06363 .001 .06884 - 1 . 86 069 313.030 8.7329 .27769 .06835 .002 .06848 - 2.28

069 312.630 8.8986 .23990 .06894 .002 .06900 - 1.38

069 312.361 9.0037 .20471 .06884 .003 .06686 -1.51

060 312.057 9.1176 .17264 .06930 .004 .06930 -.82

209 313.189 9.0398 . 31800 .06862 .001 .06872 - 1.70

209 312.903 9.1253 .27756 .06893 .002 .06899 - 1.27

209 312.603 9.2256 .23979 .06897 .002 .06900 - 1.24

209 311.863 9.4564 .20472 .06902 .003 .06902 - 1.26

248 318.216 8.7263 .31905 .06883 .002 .06919 - 1.23

288 313.237 9.0856 .27633 .06830 .002 .06840 - 2.16

288 312.998 9.1674 .23871 .06325 .002 .06831 - 2.26

288 312.566 9.3050 .20357 .06838 .003 .06840 - 2.13

716 318.753 9.4612 .45519 .06923 .001 .06939 -.73

716 313.885 9.6705 .36013 .06947 .001 .06949 -.79

716 313.289 9.8145 .27657 .06956 .002 .06953 -.97

716 312 . 5 C 8 9.9738 .20386 , 07 008 .003 .07005 -.59

,163 315.859 9.7634 .45906 .07124 .001 .07134 1.68

593 318.022 9.4674 .36015 .07068 .001 .07077 1.21

163 313.825 10.2187 .27687 .07127 .002 .07117 .20

163 313 . COC 10.2916 .20415 .07144 .003 .07136 .16

,211 315.405 10.6367 .56036 .07305 .001 .07272 .32

212 314.630 10.7374 .45492 .07370 .001 .07341 .64

211 313.835 10.8374 .35992 .07391 .002 .07368 .36

,212 313.032 10.9366 .27607 .07415 .002 .07401 .11

,831 316.074 11.1319 .61931 .07657 .001 .07600 1.27

,832 315.284 11.2129 .50825 .07715 .001 .07666 1.46

47
8 5046 9.432 314.756 11.2662 .40874 .07777 .001 .07734 1.89

85045 9.432 313.377 11 .4026 .31677 .07712 .001 .07689 .11 85040 11.269 316.248 11.7116 .67838 .08027 .009 .07951 .49 85039 11.269 315.470 11.7746 . 56170 .08075 .001 .08012 .60 85038 11.270 314.704 11.3364 .45528 .08082 .001 .08031 .20 85037 11.271 314.003 11.8923 .36056 .08123 .001 .08085 .27 P5036 13.578 316.056 12.2548 .67678 .08437 .001 .08356 -.45

85035 13.578 315.417 12.2977 .56072 .08482 .001 .08413 -.26

85034 13.578 314.603 12.3522 .45521 .08509 .001 .08456 -.39

85033 13.578 314.061 12.3882 .36073 .08535 .001 .08493 -.38

85032 16.869 316.350 12.7900 .67867 .09006 .001 .08914 -.38

85031 16.869 315.570 12.3341 .56242 .09057 .001 .08981 -.18

85030 16.869 314.803 12.3773 .45616 .09055 .001 .08995 -.56

85029 16.868 314.136 12.9146 .36056 .09054 .002 .09008 -.88

85028 21.226 314.309 13.4370 .36149 .09684 .002 .09634 -.82

85027 21.227 316.080 13.3516 .67871 .09598 .002 .09510 -1.01

85026 21.227 315.357 13.3866 .56194 .09655 .001 .09583 -.70

85025 21.229 314.639 13.4214 .45526 .09649 .002 .09592 -1.05

85024 26.236 315.862 13.8473 .80670 .10239 .001 .10157 -.88

85023 26.236 315.135 13.8783 .67867 .10255 .001 .10189 -.98

85022 26.236 314.700 13.8968 .56193 .10273 .001 .10216 -.96

85021 26.237 313.834 13.9337 .45514 .10273 .001 .10234 -1.26

85020 32.898 314.272 14.4190 .45567 .10970 .001 .10924 -1.15

85019 32.897 315.836 14.3600 .80604 .10958 .001 .10979 -.77

85018 32.898 315.195 14.3842 .67830 . 10984 .001 . 10919 -.73

85017 32.897 314.436 14.4128 .56114 .10983 .001 .10933 -.98

85016 41.600 316.300 14.8765 .94484 .11775 .001 .11691 -.42

85015 41.600 315.651 14.8983 .30583 .11783 .001 .11712 -.53

85014 41.598 314.843 14.9253 .67776 .11804 .001 .11749 -.58

85013 41.594 314.511 14.9361 .56098 .11815 .002 .11767 -.57

85012 52.114 315.977 15.4056 .94518 .12695 .001 .12624 .23 85011 52.101 315.292 15.4258 .80568 .12702 .001 .12643 .12 85010 52.090 314.743 15.4418 .67851 .12719 .001 .12670 .12 85009 52.074 314.133 15.4595 .56149 .12737 .001 .12699 .11 85008 64.284 315.536 15.9107 .94339 .13618 .001 .13562 .71 85007 64.268 315.223 15.9188 .80575 .13637 .001 .13586 .78 85006 64.267 314.630 15.9350 .67815 .13670 .001 .13628 .88 85005 64.269 314.152 15.9482 .56092 .13695 .001 .13661 .94 85004 68.124 315.798 16.0419 .94451 .13904 .001 .13845 1.05

85003 68.123 315.147 16.0592 .80528 .13923 .001 .13875 1.03

85002 68.121 314.576 16.0745 .67839 .13985 .001 .13946 1.33 85001 68.120 313.879 16.0931 .56189 .14024 .001 .13995 1.44

78125 2.580 315.282 1.2097 .14275 .02620 .003 .02586 -3.70

78124 2.580 314.669 1 .2142 .11610 .02605 .004 .02577 -4.12

7 81 2 3 2.580 314.116 1.2182 .09222 .02601 .006 .02579 -4.11

78122 2.580 313.470 1.2230 .07103 .02627 .013 .02612 -2.88

78121 5.386 313.851 4.7000 .27624 .05131 .010 .05166 1.59

78120 5.386 313.411 4.8213 .23866 .05241 .004 .05268 1.20

78119 5.386 313.264 4.8686 .20418 .05397 .004 .05421 3. 12 78118 5.386 313.035 4.9423 .17211 .05528 .004 .05548 4.01

78117 5.3 86 312.901 4.9884 .14273 .05664 .007 .05671 5.29

78116 5.386 312.630 5.0883 .11618 .05773 .009 .05785 5.45 78115 5.492 313.283 5.3893 .23897 .06008 .004 .06040 4.65

78114 5.492 313.023 5.5132 .20417 .06183 .004 .06209 5.39

78113 5.492 312.802 5,6292 .17211 .06353 .006 .06373 6.20

78112 5 .492 312.702 5.6880 .14275 .06454 .007 .06472 6.83

78111 5.492 312.541 5.7841 .11616 .06581 .010 .06595 7.32

78110 5.570 313.209 5.9191 .23904 .06512 .004 .06547 4.95

78109 5.570 313.050 6.0179 .20416 .06627 .007 .06658 5.36

78108 5 .571 312.735 6.2354 .17214 .06758 .008 .06779 4.73

73107 5.571 312.613 6.3253 .14279 .06808 .008 .06825 4.49

78106 5.571 312.552 6.3715 .11615 .06942 .010 .06957 5.88

78105 5.602 313.181 6.1561 .23910 .06670 .005 .06706 4.52

78104 5.602 313.013 6.2709 .20415 .06757 .006 .06787 4.49

78103 5.602 312.859 6.3812 .17209 .06871 .006 .06896 4.96

78102 5.602 312.694 6.5062 .14276 .06929 .008 .06949 4.60

78101 5.602 312.525 6.6393 .11618 .06896 .011 .06911 3.01 78100 5.633 313.310 6.2907 .23908 .06757 .004 .06798 4.45

78099 5.633 313.221 6.3516 .20424 .06868 .005 .06906 5.37 78098 5.633 312.929 6.5666 .17219 .06920 .006 .06948 4.09

78097 5.633 312.704 6.7417 .14283 .06974 .008 .06995 3.44 78096 5.633 312.570 6.8520 .11620 .06989 .010 .07005 2.87

78095 5.736 313.253 7.0596 .20429 .06858 .005 .06897 .20 78094 5.736 312.657 7.5128 .11620 .06844 .010 .06861 -1.94

78093 5.737 313.187 7.1154 .20434 .06900 .005 .06936 .51 78092 5.737 312.924 7.3135 .17222 .06868 .006 .06894 -. 89 78091 5.737 312.745 7.4513 .14282 .06830 .008 .06850 -1.95

Exper 1 menta

1

Adjusted Thermal Conduct 1 v 1 ty

Thermal at a nominal dev l at Ion un Pt. Pressure T emperature Dens 1 ty Power Conduct 1 v 1 ty STAT Temperature of 325 K from correlat

mp b K mo 1 / L W/m W/m.K W/m.K percent

86145 .212 322.509 .0799 .03659 .02449 .014 .02479 -1.34

86144 .212 325.164 .0794 .11447 .02487 .004 .02485 -1.09

48
86143 .212 324.231 .0796 .09091 .02488 .004 .02497 -.60

86142 .212 323.528 .0799 .07005 .02484 .006 .02502 -.42

86141 .21 2 322.741 .0802 .05187 .02417 .010 .02444 - 2.79

86140 .778 322.892 .3044 .05202 .02502 .008 .02527 - 1.55

86139 .779 324.818 .3025 .11454 .02551 .003 .02553 -.48

86138 .779 324.104 . 3032 .09095 .02544 .004 .02554 -.44

86137 .779 323.142 .3044 .06997 .02529 .005 .02551 -.60

86136 1.326 324.110 .5361 .09118 .02616 .005 .02626 .11 86135 1.326 324.425 .5354 .11439 .02589 .003 .02595 - 1.06

86134 1.327 325.134 .5341 .14058 .02621 .002 .02619 -.12

86133 1.327 325.667 .5329 .16949 .02622 .002 .02615 -.30

86132 2.422 323.528 1.0690 .09096 .02751 .004 .02765 -.00

86131 2.422 324.158 1.0656 .11453 .02771 .003 .02779 .53 86130 2.422 324.601 1.0631 .14064 .02780 .003 .02784 .73 86129 2.422 325.203 1.0598 .16956 .02759 .002 .02757 -.20

86128 2.422 326.009 1.0555 .20099 .02772 .001 .02762 .03 86127 3.089 323.991 1.4451 .11471 .02871 .003 .02879 .05 86126 3.089 325.322 1.4332 .14043 .02873 .002 .02870 -.12

86125 3.089 325.307 1.4333 .16954 .02898 .002 .02896 .75 86124 3.089 325.584 1.4309 .20086 .02888 .001 .02883 .35 86123 3.998 324.024 2.0674 .14075 .03126 .002 .03129 1.11

86122 4.000 324.589 2.0582 .16946 .03127 .002 .03128 1.19

86121 4.000 325.140 2.0486 .20092 .03137 .001 .03136 1.56

86120 4.000 325.733 2.0390 .23501 .03135 .001 .03132 1.55

86119 4.436 324.464 2.4204 .16965 .03300 .002 .03300 1.82 86118 4.438 324.965 2.4102 .20132 .03301 .002 .03301 1.99

86117 4.436 325.494 2.3954 .23544 .03328 .001 .03328 2.97

86116 4.438 326.066 2.3831 .27203 .03300 .001 .03300 2.30

86115 4.927 323.930 2.9222 .16970 .03549 .002 .03542 1.77

86114 4.927 324.510 2.8996 .20125 .03555 .002 .03552 2.38

86113 4.928 325.048 2.8796 .23526 .03552 .001 .03552 2.68

86112 4.92 8 325.295 2.8704 .27201 .03543 .001 .03545 2.60

86111 5.352 324.150 3.4325 .20158 .03871 .002 .03858 2.41

86110 5.349 324.621 3.4001 .23561 .03857 .001 .03851 2.75

86109 5.349 325.147 3.3700 .27270 .03855 .001 .03857 3.36

86108 5.350 326.750 3.2859 .31231 .03817 .001 .03840 4.20

86107 5.660 323.776 3.9290 .20105 .04175 .002 .04144 1.47

86106 5.660 324.289 3.8840 .23531 .04146 .002 .04128 1.83

86105 5.661 324.542 3.8632 .27220 .04130 .002 .04119 1.94

86104 5.661 324.907 3.8332 .31153 .04123 .002 .04121 2.47

86103 5.887 323.874 4.3381 .20136 .04479 .003 .04440 1.58

86102 5.887 324.053 4.3169 .23559 .04444 .003 .04411 1.30

86101 5.888 324.312 4.2883 .27213 .04410 .002 .04387 1.21

86100 5.888 324.771 4.2373 .31182 .04377 .002 .04369 1.65

86099 6.127 323.525 4.9210 .20124 .04873 .003 .04801 .05 86098 6.127 323.874 4.8617 .23570 .04841 .002 .04788 .69 86097 6.127 324.345 4.7859 .27279 .04785 .002 .04755 1.19

86096 6.127 324.549 4.7545 .31182 .04708 .002 .04688 .27 86095 6.261 323.904 5.1946 .23619 .05104 .033 .05044 .84 86094 6.261 324.325 5.1138 .27338 .05019 .026 .04983 .82 86093 6.261 324.505 5.0808 .31283 .05021 .021 .04995 1.55

86092 6.261 324.897 5.0115 .35449 .04951 .024 .04946 1.61

86091 6.261 325.266 4.9495 .39955 .04866 .020 .04879 1.21

86090 6.271 325.846 4.8784 .40305 .04952 .020 .04993 4.52

86089 6.271 324.760 5.0596 .35514 .04968 .024 .04955 1.08

86088 6.271 324.005 5.2008 .31212 .05000 .029 .04945 - 1.24

86087 6.271 323.494 5.3053 .27176 .05046 .035 .04960 - 2.47

86086 6.460 324.172 5.6801 .31317 .05402 .032 .05349 -.02

86085 6.460 326.309 5.2373 .55170 .05123 .014 .05197 3.15

86084 6.461 325.022 5.4903 .44760 .05200 .017 .05201 -.29

86083 6.461 324.185 5.6790 .35454 .05333 .026 .05281 - 1.29

86082 6.461 323.175 5.9384 .27173 .05495 .038 .05372 - 2.82

86081 6.785 325.811 6.1799 .55226 .05640 .014 .05698 .41 86080 6.785 324.856 6.4330 .44793 .05742 .020 .05731 - 1.57

86079 6.786 323.931 6.7035 .35471 .05827 .028 .05749 - 3.73

86078 6.786 323.040 6.9817 .27180 .05910 .041 .05768 - 5.59

86077 6.878 325.765 6.4445 .55231 .05770 .015 .05826 -.03

86076 6.879 324.914 6.6799 .44815 .05895 .015 .05889 - 1.06

86075 6.879 324.042 6.9369 .35488 .05987 .002 .05917 - 2.61

86074 6.879 323.136 7.2205 .27185 .06056 .002 .05924 - 4.43

86073 7 .178 325.695 7.2393 .55240 .06125 .002 .06175 -.31

86072 7.179 324.714 7.5164 .44778 .06185 .001 .06166 - 2.00

86071 7.179 323.969 7.7304 .35489 .06270 .001 .06204 - 2.39

86070 7.179 323.059 7.9941 .27201 .06301 .002 .06188 - 3.79

86069 7.413 325.677 7.7714 .55245 .06298 .001 .06341 -.36

86068 7.413 324.723 8.0228 .44808 .06341 .001 .06325 - 1.65

86067 7.414 323.985 8.2163 .35488 .06386 .002 .06331 - 2.27

86066 7.414 323.084 8.4486 .27205 .06424 .002 .06332 - 3.09

86065 7.615 326.504 7.9592 .66735 .06338 .001 .06429 .24 86064 7.615 325.489 8.2063 .55178 .06410 .001 .06437 -.56

86063 7.616 324.602 8.4203 .44779 .06455 .001 .06435 - 1.34

86062 7.616 323.783 8.6138 .35410 .06447 .001 .06394 - 2.69

86061 8.061 326.641 8.6364 .66782 .06562 .001 .06634 .96 86060 8.061 325.669 8.8334 .55261 .06623 .001 .06649 • 46 86059 8.062 324.766 9.0121 .44807 .06655 .001 .06647 -.21

49
86058 6.063 323.950 9.1696 . 35672 .06669 .001 .06639 -.97

86057 0.771 327.097 9.3383 .67155 .06869 .001 .06922 2.65

86056 8.772 326.617 9.6655 .55622 .06926 .001 .06955 2.64

86055 8.772 325.389 9.6038 .65163 .06969 .001 .06976 1.97

86056 8.772 326 . C 53 9.8030 .35529 .06952 .001 .06960 .38 «6053 9.521 328.172 9.7680 .67796 .07179 .001 .07226 6.69

86052 9.521 327.339 9.8766 .56171 .07265 .001 .07272 6.53

36051 9.522 327.636 9.8386 .65856 .07338 .001 .07371 6.02

86050 9.523 328.307 9.7513 .36923 .07511 .001 .07560 8.82 86069 10.691 327.633 10.6926 .67620 .07666 .001 .07661 2.91

86068 10.690 327.360 1 C . 6997 .55976 .07529 .001 .07526 3.69

86067 10.690 325.038 10.7330 .66961 .07677 .001 .07677 1.18

86066 10.691 323.933 10.8617 .35666 .07666 .001 .07656 -.07

86065 11.988 327.970 10.9668 .67576 .07803 .001 .07778 3.20

86066 11.988 327.699 10.9682 .56396 .07926 .001 .07902 6.52

86063 11.939 326.368 11.0839 .65529 .07911 .001 .07897 3.62

86062 11.989 325.560 11 .1521 .36007 .07870 .002 .07866 2.37

86061 11.990 326.688 11.2238 .36161 .07878 .001 .07882 1.91

86060 16.669 326.292 11.8818 .35399 .08232 .001 .08265 -.54

86039 16.669 326.367 11.7627 .66660 .08126 .001 .08101 -.76

86038 16.670 325.661 11.8065 .56972 .08168 .001 .08160 -.96

86037 16.670 326.670 11.8567 .66582 .08159 .001 .08165 - 1.24 86036 17.218 326.216 12.3939 .35605 .08623 .001 .06639 -1.80

86035 17.217 326.757 12.3623 .66685 .08665 .001 .08670 - 1.06

86036 17.218 326.165 12.2819 .66639 .08575 .001 .08552 - 1.49

86033 17.217 325.625 12.3237 .56970 .08608 .001 .08599 - 1.43

86032 20.957 326.063 12.9279 .66837 .09272 .001 .09293 -.97

86031 20.957 326.081 12.8271 .79235 • 0919 C .001 .09166 - 1.10

86030 20.957 325.606 12.8610 .66703 .09227 .001 .09218 -.95

86029 20.957 325.016 12.8805 .55392 .09296 .001 .09296 -.35

86028 25.559 323.871 13.6388 .66868 .09871 .001 .09896 - 1.04

86027 25.563 325.636 13.3617 .79062 .09761 .001 .09767 - 1.60

86026 25.563 326.837 13.3969 .66693 .09789 .001 .09793 - 1.57

86025 25.566 32^.029 13.6326 .56996 .09783 .001 .09805 - 1.90

86026 31.503 326.318 13.8558 .92756 . 10613 .001 .10386 - 1.49

86023 31.503 325.608 13.8912 .79066 .10662 .001 .10633 - 1.47

86022 31.502 326.666 13.9209 .66505 .10680 .001 .10688 - 1.31

86021 31.503 326.056 13.9638 .55078 . 10679 .001 .10500 - 1.49

86020 38.525 323.917 16.6355 .55208 .11265 .001 .11288 -.49

86019 3 e • 525 326.025 16.3619 .92856 .11136 .001 .11116 - 1.11

86018 38.525 325.271 16.3882 .79158 .11161 .001 .11155 - 1.07

86017 38.525 323.662 16.6521 .66736 .11227 .001 .11260 -.95

86016 67.679 323.767 16.9669 .55230 .12037 .001 .12061 -.33

86015 67 , 67 e 327.091 16.8603 .92575 .11066 .001 .11822 - 1.01

86016 67.678 326.967 16.9078 .79107 .11986 .001 .11985 -.49

86013 67.679 326.170 16.9322 .66567 .12020 .001 .12037 -.38

86012 51.756 326.213 15.0803 1.07568 .12322 .001 .12298 -.10

86011 51.759 325.387 15.1056 .92795 .12336 .001 .12326 -.19

86010 51.760 326.761 15.1263 .79138 .12357 .001 .12362 -.15

86009 51.757 326.069 15.1656 .66536 .12368 .001 .12366 -.38

86008 66.209 325.860 15.6253 1.07560 .13313 .001 .13298 .81 86007 66.207 325.163 15.6663 .92781 .13328 .001 .13325 .77 06006 66.205 326.696 15.6626 .79169 .13330 .001 .13339 .64 86005 66.202 326.126 15.6726 .66669 .13331 .001 .13366 .57 86006 67.171 325.753 15.7611 1.07660 .13699 .001 .13686 .75 86003 6^.176 325.167 15.7569 .92731 .13515 .001 .13512 .74 06002 67.175 326.588 15.7726 .79101 .13515 .001 .13522 .62 86001 67.176 323.892 15.7910 .66552 .13530 .001 .13569 .58

50
5. Propane Results

A total of 400 points are given in Table 5. The results are reported in [12].

The computer programs developed for the thermal conductivity surface of propane are shown below. The equation of state used for propane is given in [13].

FUNCTION THERMR( DD ,T)

C PROPANE THERMAL CONDUCTIVITY, RODER AND CASTRO

DIMENSION GT(9),ET(8),FT(4) ,G(7)

DATA ( NT R= 1

)

IF(NTR.EQ.O) GO TO 1 GT( 1)=-1 .0893811033E + 06

GT ( 2 ) = 8.3432978294E+05

GT (3)=-2 .2709027355E+05

GT ( 4

) = 1.6678663676E+04

GT ( 5 ) = 4.3473205647E+03

GT (6 )=-l . 1777846709E+03

GT ( 7 ) = 1 .2154258330E+02

GT ( 8

) = -6 .0405969210E+00

GT ( 9

) = 1 .2073736806E-01

ET(l)=-1.0924494641E+0i

ET ( 2 ) = - 9 .5984868950E-02

ET ( 3

) = 1.4806220800E+01

ET ( 4) = 2.5545815041 E+04

ET ( 5

) =- 1 .8740978557E+04

ET ( 6

) = 1 .2697095137 E+03

E T ( 7 ) = 1 . 3890247487E + 02

ET ( 8

) =0 . 22

1

FT ( 1 ) = -l .1498131307E + 00

FT ( 2

) = 7 .8853 122149E-01

FT ( 3 ) = 1 .12

FT ( 4

) =358 .9 EM = 44 . 10

G ( 1

) =- . 578825E+1

G ( 2

) = . 181340E+3

G ( 3

) = . 963981E+1

G (4 )=- .130794E+4

G ( 5

) = .114746E+1

G ( 6

) =- . 982209E+2

G ( 7 ) = .47 6504E + 4 NTR = 0

1 CONTINUE

C RETURNS TC IN MW/M.K , T IN K, D IN G/CM**3

D=DD*EM/1000

.

TF=T**(l./3.)

TFF=T** ( - 4 . / 3 .

)

SUM = 0 DO 20 1=1,9

TFF=TFF*TF

20 SUM=SUM+GT( I

) *TFF

DILV=SUM

FDCV=(FT(1)+FT(2)*(FT(3)-AL0G(T/FT(4)))**2)*D

THE=(D-0.221)/0.221

DD01=D**0 .1 THE05=THE*D**0.5

TCCALC=G(1)+G(2)/T+G(3)*DD01+G(4)*DD01/T**1.5

1 +G(5)*THE05+G(6)*THE05/T+G(7)*THE05/T**2

THERMR=DILV+FDCV+EXP(TCCALC)

RETURN

END

51
T ah I e 5 . Th Therms! Conductivity of Propane

Experl mental Adjusted Thermal Conduct i v 1 ty Therma

1

at a nominal deviation

Pun Pt. Pressure Temperature Density Power Conduc 1 1 v 1 ty STAT Temperature of 299 K from correlation

“P» K mol /L W/m W/m.K W/m.K percent

3 001? 1.587 296.214 11.2778 .14049 .09353 .050 .09379 -1.02

30014 1.587 296.569 11.2651 .20104 .09352 .030 .09375 -.82 30015 1.588 296.996 11.2498 .27239 . 09345 .019 .09364 -.65

30016 1.588 297.538 11.2303 .35450 .09401 .013 .09415 .27 30017 1.588 298.053 11.2117 .44763 .09371 .009 .09380 .25 30013 1 .588 298.685 11.1807 .55153 .09352 .007 .09355 .42 30019 1. K 88 299.361 11.1639 .66618 .09324 .005 .09321 . 52 30020 1.588 300.134 11.1354 .79163 .09275 .004 .09265 .45 30021 1 .588 300.942 11.1054 .92782 .09192 .003 .09174 .04 30022 1.588 296.995 11.2499 .27183 .09361 .019 .09380 -.48

30023 1.588 297.467 11.2329 .35411 .09344 .012 .09358 -.38

30C24 1.588 297.967 11.2148 .44716 .09420 .009 .09430 .72 30025 1 .588 293.643 11.1902 .55085 .09352 .006 .09355 .40 30026 1.583 299.321 11.1654 .66542 .09332 .004 .09329 .58 30027 1.588 300.133 11.1355 .79066 .09293 .004 .09283 .65 30028 1.588 300.924 11.1061 .92700 .09236 .003 .09218 .51

3 2001 67.559 297.562 13.2452 .54936 . 14011 .009 .14028 -.22

32002 67.514 296.701 13.2587 .35296 .13991 .018 .14019 -.57

320C3 67.510 298.413 13.2302 .78840 .13942 .006 .13949 -.47

32004 67.510 299.575 13.2109 1.07074 .13924 .003 .13917 -.29

32005 67.503 298.062 13.2360 .66310 .13949 .007 .13960 -.51

32006 67.496 P 9 8 , 9 54 13.2210 .92416 .13898 .004 .13899 -.64

32007 67.496 3C0.251 13.1995 1.22805 .13937 .003 .13922 -.02

32008 67.492 297.381 13.2471 .54923 .13967 .009 .13986 -. 56 32009 59.635 297.065 13.1120 .44570 .13627 .013 .13650 -.16

32010 59.635 297.070 13.0963 .66332 .13576 .006 .13588 -.28

32011 59.635 299.124 13.0763 .92377 .13507 .004 .13506 -.47

32012 59.641 300.438 13.0537 1.22746 .13474 .003 .13457 -.36

32013 59.643 298.587 13.0858 .78789 .13543 .005 .13548 -.36

32014 52.256 297.148 12.9669 .44541 .13214 .012 .13235 -.21

32015 52.260 298.025 12.9511 .66292 . 13100 .007 .13111 -.83

32016 52.264 299.178 12.9303 .92336 .13122 .004 .13120 -.33

32017 52.268 300.486 12.9068 1.22715 .13063 .003 .13046 -.40

32018 52.264 299.840 12.9184 1.06977 .13086 .003 .13076 -.41

32019 44.940 296.803 12.8173 .35281 .12742 .014 .12767 -.72

32020 44.942 297.617 12.8019 .54878 .12814 .007 .12829 .09 32021 44.945 293.753 12.7804 .78764 .12730 .005 .12733 -.22

32022 44.948 299.393 12.7683 .92322 .12706 .004 .12702 -.22

32023 44.949 300.001 12.7568 1.07002 .12642 .003 .12631 -.54

32024 44.950 300.730 12.7430 1.22717 .12643 .003 .12624 -.31

32025 37.620 296.803 12.6447 .35302 .12335 .016 .12359 -.42

32026 37.616 297.760 12.6253 .54905 .12356 .009 .12369 .07 32027 37.613 293.834 12.6027 .78815 .12294 .005 .12295 -.07

32028 37.605 300.212 12.5758 1.07053 .12222 .003 .12209 -.23

32029 37.598 299.503 12.5899 .92396 . 12238 .004 .12233 -.3,2 32031 30.485 297.326 12.4447 .44571 .11 821 .011 .11839 -.64

32032 30.485 298.339 12.4230 .66335 .11793 .005 .11800 -.53

32033 30.487 299.681 12.3942 .92398 .11757 .004 .11750 -.37

32034 23.164 296.509 12.2413 .27111 .11419 .022 .11445 .07 32035 23.164 297.351 12.2217 .44542 .11392 .011 .11409 .15 32036 23.166 298.443 12.1964 .66295 .11277 .005 .11283 -.45

32037 23.166 299.738 12. 1663 .92354 .11190 .004 .11182 -.75

32038 23.166 300.473 12.1491 1.06999 .11195 .003 .11180 -.42

32039 16.446 296.703 11.9999 .27170 .10778 .021 .10801 -.91

32040 16.447 297.447 11.9809 .44621 .10795 .010 .10810 -.45

32041 16.449 298.624 11.9510 .66407 . 10782 .006 .10786 -.08

32042 16.454 300.037 11.9150 .92507 .10669 .004 .10659 -.56

32043 16.456 300.846 11.8943 1.07174 .10672 .004 .10654 -.20

32044 9.642 296.255 11.7240 .20041 .10243 .031 .10270 -.53

32045 9.644 298.165 11.6690 .54982 .10248 .007 .10256 .41 32046 9.644 297.121 11.6992 .35343 .10200 .013 .10218 -.55 32047 9.646 299.586 11.6279 .78903 .10088 .004 .10082 -.50

32048 9.648 300.244 11.6088 .92514 .10073 .003 .10061 -.35

32050 3.216 297.201 11.3486 .35349 .09510 .011 .09527 -.80

32051 3.216 298.393 11.3078 .54977 .09470 .006 .09476 -.56

32052 3.217 299.778 11.2600 .78929 . 09410 .004 .09403 -.42

32053 3.217 300.519 11.2343 .92538 .09343 .003 .09329 -.72

32054 3.220 301.422 11.2028 1.07206 .09322 .002 .09299 -.44

Expe r 1 mental Adjusted Thermal Conduct 1 vl ty Thermal at a nominal dev 1 at 1 on Pun Pt. Pressure T emperature Dens 1 1 y Power Conduc 1 1 v 1 ty STAT Temperature of 261 K from correlation

MPa K mol /L W/m W/m .K W/m.K percent

37003 68.062 259.694 13.8871 .47623 . 15786 .017 .15804 1.24

37004 68.062 260.425 13.8748 .68392 .15747 .006 .15755 1.19

52
37005 68.065 261. *02 13.8583 .92900 .15706 .00* .15701 1.20

37006 68.065 262. *23 13.8*11 1.21185 .15612 .00* .15593 .89 37007 60. *21 259.059 13.7860 .306*0 .15372 .027 .15398 .82 37008 60. *1* 259.688 13.77*9 .*7663 .15*68 .01* .15*85 1.61

37009 60. *1* 260. *00 13.762* .68*53 .1536* .007 .15372 1.15 37010 60. *07 261.330 13.7*61 .93021 .1531* .005 .15310 1.10

37011 60. *07 262. **1 13.7267 1.21355 .15217 .003 .15198 .79 37012 53 • *"* 259.027 13.6773 .30600 .15078 .026 .15103 1.22

37013 53. *57 259.6*7 13.6661 .*7615 .1506* .01* .15081 1.31

3701* 53. *57 260.361 13.6532 .68386 .15000 .008 .15008 1.10

37015 53. *6* 261.3*0 13.6357 .92902 . 1*907 .005 .1*903 .77 37016 53. *6* 262. *15 13.6163 1.21196 .1*8*1 .003 .1*823 .65 37018 *6. *59 258.983 13.560* .30615 .1*620 .025 .1*6*5 .6* 37019 *6. *57 259.273 13.55*9 .38665 .1*719 .018 .1*7*0 l.*0

37020 *6. *59 259.977 13.5*17 .5757* .1*670 .010 .1*683 1.29

37021 *6. *59 260.8*1 13.5255 .80235 .1*595 .006 .1*597 1.05

37022 *6. *59 261.933 13.5051 1.06666 .1*529 .00* .1*518 .9* 37023 39.293 259.118 13. *273 .30615 .1*3*3 .025 .1*366 1.5*

3702* 39.292 259.638 13. *171 .*7656 .1*219 .013 .1*235 .85 37025 39.292 260.518 13.3998 .68*3* .1*236 .008 .1*2*2 1.26

37026 39.295 261.523 13.3802 .92965 .1*1*7 .005 .1*1*1 .96 37027 39.295 262.595 13.3592 1.21328 .1*068 .003 .1*0*9 .76

37028 32.175 259.103 13.2860 .30621 .13931 .02* .13953 1.61

37029 32.180 259.787 13.2721 .*7638 .13866 .013 .13882 l.*0

37030 32.180 260.587 13.2557 .68*27 .13778 .007 .13783 1.03

37031 32.180 261.611 13.23*6 .9297* .137*0 .005 .13733 1.11

37032 32.180 262.79* 13.2103 1.2130* .13638 .003 .13617 .78 37033 2*. 91* 258.918 13.1307 .235*8 .13301 .035 .1332* .28 3703* 2*. 91* 259. *76 13.1186 .38731 .13*66 .017 .13*83 1.70

37035 2*. 920 260.263 13.1016 .57666 .13*1* .009 .13*22 1.61

37036 2*. 921 261.165 13.0820 .80381 .13331 .006 .13329 1.33

37037 2*. 920 262.3** 13.056* 1.06859 .13231 .00* .13216 1.02

37038 18.290 258.92* 12.9689 .23568 .13057 .03* .13079 1.79

37039 18.290 259. *86 12.9560 .3873* .1299* .016 .13010 1.53

370*0 18.290 260. *62 12.933* .57651 .12899 .009 .12905 1.20

370*1 18.29* 261.351 12.9130 .80387 .12861 .005 .12857 1.25

370*2 18.29* 262. *39 12.8878 1.06885 .12805 .003 .12790 1.25

370*3 11.36* 258.951 12.7775 .23570 .12522 .033 .125*3 1.58

370** 11.36* 259.61* 12.7610 .38739 .12*79 .016 .12*93 1.52

370*5 11.370 260. *82 12.7396 .57670 .12338 .008 .123*3 .77 370*6 11.370 261. *61 12.7152 .80383 .12389 .005 .1238* 1.59

370*7 11.373 262.620 12.6863 1.06882 .12311 .003 .12295 1 . *6 370*8 3.8 5* 259.09* 12.5322 .23563 .11919 .031 .11938 1.68

370*9 3.656 259.723 12.5150 .38732 .11910 .013 .11922 1.90

37050 3.858 260.577 12. *915 .57679 .11759 .008 .11763 1.05

37051 3.862 261.67* 12. *613 .80391 .11778 .005 .11771 1.72

37052 3.86* 262.861 12. *283 1.06900 .11*8* .003 .11*66 -.22

Exper 1 mental Adjusted Thermal Conductivity

Therma

1

at a nominal devl at Ion Run Pt

.

Pressure Temperature Dens 1 ty Power Conduct 1 v 1 ty ST AT Temperature of 227 K from correlation

MPa K mo 1 /L W/m W/m .K W/m. K percent

31002 67. *11 226.290 1*.**92 .59031 .16955 .011 .16967 -.76

31003 67. *13 227.015 1*.*367 .802*0 .16975 .007 .16975 -.**

3100* 67. *1* 227.870 1*.*219 1.0*721 .16873 .005 .16859 -.80

31005 67. *1* 228.719 1* .*073 1.32506 .16901 .003 .16873 -.*0

31006 67. *11 225. **0 1*. *638 .333** .16967 .028 .16993 -.92

31007 67. *11 225.956 1*.*5*9 .*9650 .16952 .015 .16969 -.87

31008 67. *08 226.628 1*. **33 .6921* .16891 .009 .16897 -1.0*

31009 67. *10 227.3*5 1*.*309 .92066 .16927 .006 .16921 -.63

31010 67. *13 228.136 1* .* 173 1.18196 .16921 .00* .16903 -.**

31011 67. *11 229.207 1*,3988 l.*76*6 ,16 ei 7 .003 .16782 -.76

31012 59.530 225.816 1* .35 99 .*1085 .16*9* .019 .16513 -1.5*

31013 59.535 226. *23 1*. 3*91 .59011 .16595 .011 .1660* -.75

3101* 59.5*0 227.071 1* .3377 .80221 .16600 .007 .16599 -.53

31015 59.537 227.860 1*.3236 1.0*705 .16551 .005 .16538 -.60

31016 59.538 228.78* 1*.3072 1.32*99 .16501 .003 .16*73 -.63

31017 52.268 225.667 1* .2671 .*1101 .1628* .019 .1630* -.80

31018 52.277 226.263 1*. 2563 .5901* .1626* .011 .16275 -.75

31019 52.278 227.052 1*.2*18 .8023* .16228 .007 .16227 -.73

31020 52.283 227.837 1*. 2275 1. 0*7*6 .16228 .005 .16215 -.*9

31021 52.283 228.808 1*.2097 1.32550 .16172 .003 .161*5 -.55

31022 52.288 229.302 1*. 2007 1 .*773* .1616* .003 .16130 -.*5

3102* **.798 226.377 1* . 1* 88 .59026 .15876 .011 .15885 -.86

31025 **.800 227.102 1* .13 51 .802*0 .158*9 .007 .158*8 -.80

31026 **.802 227.936 16.1193 1. 0*7*8 .15810 .00* .15796 -.79

31027 **.802 228.8*7 1*.1020 1.32587 .15791 .003 .1576* -.62

31028 38.290 225.792 1*.062* .*1099 .15562 .013 .15579 -.95

31029 38.291 226. *08 1* .0503 .590*1 .15575 .009 .15583 -.66

31030 38.299 227.261 1*. 0337 .802*1 .15509 .007 .15505 -.81

31031 38.299 227.999 1* .01 93 1.0*76* .15*81 .00* .15*67 -.75

31032 38.301 228.961 1*.0005 1.3258* .15*** .003 .15*17 -.67

31035 30.901 226.7*6 13.92*0 .69320 .151*3 .008 .151*6 -.81

31036 30.890 227.662 13.9051 .92205 .15070 .005 .15061 -.97

53
31037 30.881 228.530 13.8872 1.18421 .15065 .003 .15045 -.70

31038 23.806 225.571 13.8243 .33381 .14794 .023 .14813 -.92

31039 23.803 226.127 13.8124 .49712 .14728 .012 .14739 -1.16

31040 23.806 226.823 13.7976 .69317 .14717 .008 .14719 -.98

31041 23.808 227.630 13.7805 .92219 .14672 .005 .14664 -.99

31042 23.808 228.670 13.7583 1.18401 .14666 .003 .14645 -.65

31043 16.024 225.557 13.6759 .33381 .14297 .022 .14315 -1.19

31044 16.026 226.145 13.6627 .49733 .14251 .012 .14262 -1.28

31045 16.026 226.856 13.6467 .69337 .14251 .008 .14253 -1.00

31046 16.030 227.832 13.6246 .92233 .14196 .005 .14186 -1.01

31047 16.033 228.749 13.6042 1.18457 .14201 .003 .14180 -.61

31048 9.604 225.376 13.5449 .26443 .13800 .031 .13819 -1.96

31049 9.607 225.882 13.5329 .41157 .13828 .016 .13841 -1.54

31050 9.606 226.623 13.5154 .59130 .13806 .009 .13810 -1.39

31051 9.609 227.423 13.4965 .80397 .13798 .006 .13793 -1.11

31052 9.610 228.365 13.4741 1.04937 .13790 .004 .13774 -.78

31053 2.883 225.432 13.3866 .26446 .13409 .026 .13427 -1.50

31054 2.884 225.986 13.3727 .41160 .13414 .015 .13425 -1.22

31055 2.886 226.589 13.3575 .59153 .13384 .009 .13389 -1.17

31056 2.888 227.474 13.3351 .80411 . 13330 .006 .13325 -1.18

31057 2.888 228.446 13.3105 1.04963 .13307 .004 .13291 -.92

31058 2.889 228.986 13.2968 1.18497 .13293 .003 .13271 -.78

Exper 1 mental Adjusted Thermal Conduct 1 v 1 ty

Thermal at a nominal dev i at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conductivity STAT Temperature of 196 K from correlation

MPa K mo ! /L W/m V/m.K W/m. K percent

36001 67.881 196.026 14.9818 .78257 .18567 .007 .18566 -.08

36002 67.899 195.213 14.9963 .50144 .18656 .016 .18672 .18 36003 67.902 195.410 14.9928 .58811 .18634 .011 .18646 .12 36004 67.908 196.445 14.9747 .89010 .18592 .007 .18583 .16 36005 67.914 195.776 14.9865 .68154 .18641 .009 .18646 .25 36006 67.916 197.248 14.9607 1.12637 .18534 .005 .18509 .06 36007 61.052 195.283 14.9241 .50124 .18301 .016 .18315 -.20

36008 61.057 195.773 14.9153 .68147 .18342 .010 .18347 .16 36009 61.058 196.412 14.9039 .88970 .18274 .007 .18266 -.04

36010 61.062 197.150 14.8906 1.12638 .18240 .005 .18217 -.02

36011 61.069 197.606 14.8825 1.25526 .18232 .004 .18200 .06 36012 53.545 195.266 14.8426 .50102 .18078 .014 .18092 .31 36013 53.553 195.704 14.8346 .68129 .17952 .010 .17958 -.26

36014 53.565 196.493 14.8201 .88944 . 17958 .007 .17949 -.00

36015 53.570 197.263 14.8060 1.12623 .17913 .004 .17889 -.03

36016 53.578 197.585 14.8001 1.25490 .17889 .004 .17859 -.08

36017 46.473 194.948 14.7672 .42176 .17762 .020 .17782 .19 36018 46.480 195.395 14.7588 .58834 . 17692 .012 .17703 -.07

36019 46.484 196.099 14.7455 .78288 .17647 .008 .17645 -.12

36020 46.489 196.779 14.7327 1.00551 .17612 .005 .17598 -.11

36021 46.494 197.677 14.7157 1.25669 .17551 .003 .17520 -.19

36022 38.784 194.988 14.6728 .42203 .17293 .019 .17311 -.48

36023 38.787 195.514 14.6625 .58838 .17302 .012 .17311 -.26

36024 38.795 196.107 14.6510 .78287 .17284 .008 .17282 -.18

36025 38.803 196.868 14.6362 1.00578 .17246 .005 .17231 -.17

36026 38.812 197.782 14.6184 1.25712 .17179 .003 .17148 -.27

36027 30.800 194.734 14.5738 .34897 .17023 .025 .17045 .07 36028 30.803 195.167 14.5651 .50166 .16998 .014 .17012 .07 36029 30.805 195.844 14.5513 .68235 .16954 .009 .16957 .03 36030 30.808 196.543 14.5372 .89114 .16884 .005 .16875 -.15

36031 30.812 197.509 14.5176 1.12810 .16842 .004 .16817 -.08

36032 22.911 194.735 14.4633 .34928 .16589 .024 .16610 -.17

36033 22.918 195.281 14.4519 .50189 .16643 .014 .16655 .34 36034 22.921 195.960 14.4376 .68251 .16500 .009 .16501 -.29

36035 22.924 196.655 14.4229 .89137 .16473 .005 .16462 -.21

36036 22.926 197.423 14.4068 1.12861 .16437 .004 .16414 -.16

36037 16.394 194.567 14.3689 .28333 .16315 .033 .16338 .17 36038 16.394 195.058 14.3581 .42209 .16225 .018 .16240 -.20

36039 16.399 195.523 14.3480 .58870 .16237 .011 .16244 .04 36040 16.400 196.331 14.3304 .78322 .16150 .006 .16145 -.21

36041 16.404 197.129 14.3130 1.00619 .16128 .005 .16111 -.05

36042 16.406 197.466 14.3056 1.12848 .16103 .004 .16080 -.08

36043 9.045 194.614 14.2486 .28328 .15942 .032 .15963 .38 36044 9.044 195.106 14.2373 .42196 .15829 .017 .15842 -.14

36045 9.045 195.609 14.2258 .58858 .15761 .009 .15767 -.38

35046 9.045 196.354 14.2087 .78307 .15741 .007 .15736 -. 21 35047 9.045 197.105 14.1915 1.00629 .15703 .005 .15687 -.16

35048 9.047 197.543 14.1815 1.12842 .15666 .004 .15644 -.23

36049 1.947 194.588 14.1235 .28353 .15546 .031 .15566 .49 36050 1.949 195.095 14.1113 .42248 .15410 .017 .15423 -.18

36051 1.950 195.614 14.0989 .58938 .15400 .010 .15405 -.03

36052 1.952 196.334 14.0816 .78445 .15353 .007 .15348 -.04

36053 1.955 197.248 14.0597 1.00784 .15295 .004 .15278 -.04

36054 1.962 197.629 14.0506 1.13019 .15264 .004 .15242 -.09

54
Experimental Adjusted Thermal Conductivity

Thermal at a nominal deviation

Run Pt. Pressure Temperature Dens 1 ty Power Conductivity STAT Temperature of 170 K from correlation

HPa K <rol/L W/m W/m.K W/a.K percent

330C1 67.127 168.18 s 15.4696 .29368 .19826 .037 .19874 -.46

33002 67.121 168.522 15.4635 .42482 .20009 .021 .20048 .52 33003 67.120 168.914 15.4565 . 57786 .19885 .013 .19914 -.00

3 3004 67.114 169.452 15.4466 .75458 .19868 .009 .19382 .04 33005 67.111 170.019 15.4366 .95562 .19845 .006 .19845 .07 33006 67.111 170.833 15.4220 1.18085 .19829 .005 .19807 . 18 33007 67.108 171.138 15.4165 1.30263 .19798 .004 .19769 .10 33008 59.259 163.351 15.3967 .35728 .19475 .024 .19517 -.76

33009 59.258 168.727 15.3897 .49834 .19545 .014 .19578 -.31

33010 59.264 169.099 15.3830 . 66304 .19594 .010 .19617 .04 33011 59.267 169.924 15.3678 ,85224 .19539 .007 .19541 -.04

33012 59.265 170.420 15.3587 1.06518 .19526 .005 .19515 .02 33013 59.273 171.148 15.3454 1.30271 .19484 .004 .19455 -.01

33014 51.755 168.276 15. 3279 .35732 .19390 .025 .19433 .24 33015 51.757 168.737 15.3193 .49836 .19350 .015 .19381 .16 33016 51 .752 169.257 15.3094 .66332 .19323 .011 .19341 .16 33017 51.753 169.787 15.2994 .35221 .19274 .008 .19279 .05 33013 51.747 170.418 15.2875 1.06533 .19222 .005 .19212 -.06

33019 51.764 171.196 15.2730 1.30336 .19190 .004 .19161 -.02

33020 44.330 168.303 15.2544 .35731 .19064 .025 .19105 .08 33021 44. 338 168.750 15.2459 .49838 . 19042 .016 .19072 .08 33022 44.344 169.233 15.2366 .66306 .ie993 .010 .19011 -.04

33023 44.344 169.831 15.2250 .85202 .18989 .007 .18993 .10 33024 44 .354 170.494 15.2123 1.06510 .18910 .005 .18898 -.13

33025 44.351 171.224 15.1982 1.30275 .18877 .003 .18848 -.10

33026 37.043 168.161 15.1814 .35707 .18748 .026 .18790 -.06

33027 37.054 168.649 15.1722 .49815 .18754 .016 .18785 .10 33028 37.071 169.289 15.1597 .66316 .18736 .010 .18752 .19 33029 37.078 169.838 15.1489 .85332 .18631 .007 .18635 -.22

33030 37 .O^P 170.557 15.1346 1.06747 .18616 .005 .18603 -.09

33031 37.082 171.311 15.1197 1.30452 .18547 .004 .18517 -.24

33032 29.244 168.692 15.0854 .49892 .18423 .015 .18452 .12 33033 29.257 169.185 15.0755 .66390 .18334 .010 .18352 -.22

33034 29.262 169.912 15.0607 .85301 .18282 .007 .18284 -.28

33035 29.270 170.398 15.0508 1.06665 .18283 .005 .18274 -.13

33036 29.285 170.870 15.0413 1.18221 .18221 .004 .18202 -.33

33037 21.866 168.582 15.0015 .42523 .18068 .017 .18098 -.07

33038 21.874 169.045 14.9918 .57848 .18037 .012 .18057 -.10

33039 21.881 169.589 14.9804 .75559 .17998 .008 .18007 -.14

33040 21.898 170.209 14.9675 .95695 .17958 .005 .17954 -.17

33041 21.906 170.965 14.9516 1.18252 .17912 .004 .17892 -.19

33042 14.907 168.591 14.9148 .42518 .17779 .019 .17808 .10 33043 14.928 169.062 14.9048 .57822 .17696 .011 .17715 -.21

33044 14.935 169.633 14.8924 .75518 .17653 .007 .17660 -.26

33045 14.950 170.298 14.8781 .95638 .17629 .006 .17623 -.18

33046 14.962 171.038 14. 8621 1.18166 .17571 .004 .17550 -.26

33047 7.748 168.130 14.8290 . 29605 .173e7 .032 .17423 -.31

33048 7.758 168.524 14.8214 .42563 .17416 .017 .17445 -.02

33049 7.771 169.025 14.3102 .5^901 .17409 .011 .17428 .11 33050 7.781 169.746 14.7941 .75631 .17293 .007 .17298 -.31

33051 7.793 170.367 14.7802 .95802 .17289 .005 .17282 -.11

33052 7.802 171.165 14.7623 1.18425 .17219 .004 .17197 -.24

33053 1.042 168.057 14.7368 .29620 .16943 .031 .16980 -.99

33054 1.042 168.447 14.7277 .42570 .17109 .018 .17138 .14 33055 1.041 168.922 14.7165 .57905 .17041 .011 .17061 -.08

33056 1.041 169.624 14.7001 .75649 .16985 .003 .16992 -.15

33057 1.041 170.251 14.6854 .95825 .16920 .005 .16915 -. 30 33058 1.041 171. C53 14.6665 1.18431 .16865 .004 .16846 -.33

Experl *ent al Adjusted Theraal Conduct 1 vl ty Ther »a 1 at a nominal dev 1 at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conduc 1 1 v 1 ty STAT Temperature of 140 K from corre latl on HPa K mol /L V/m W/m.K W/r.K percent

34001 66.728 138.618 16.0035 .33830 . 21299 .031 .21351 .28 34002 66.726 138.936 15.9976 .46006 .21351 .017 .21391 .58 34003 66.741 139.456 15.9882 .60118 .21325 .013 .21345 • 56

3 4004 66.744 139. e24 15.9315 .76130 .21292 .008 .21299 .47

34005 66.744 140.286 15.9730 .94099 .21316 .005 .21305 .68 34006 66.746 140.896 15.9619 1.14119 .21276 .004 .21243 • 61 34007 59.962 138.778 15.9510 . 33809 .21151 .030 .21196 .60 34008 59.962 139.030 15.9463 .45990 .21139 .019 .21175 .60 34009 59.973 139.438 15.9387 .60092 .21044 .013 .21065 .21 34010 59.981 139.822 15.9316 .76100 .21139 .008 .21145 .75 34C11 59.984 140.300 15.9227 .94058 .21030 .007 .21019 .34

34012 59.982 140.929 1

E

• 91 10 1.14088 .21001 .004 .20968 .11 34013 51.482 138.735 15.8869 .33816 .20903 .030 .2C948 .72 34014 51.487 138. e94 15.8839 .45970 .20888 .019 .20928 .68 34015 51.490 139.321 15.8758 .60059 .20816 .013 .20840 .42

55
34016 51 .487 139.865 15.8653 .76092 .20809 .009 .20814 .51 34017 51.500 140.319 15.8567 .94029 .20749 .007 .20738 .32 34018 51.507 140.921 15.8453 1.13973 .20728 .005 .20696 .34 34019 43.276 138.725 15.8211 .33830 .20502 .029 .20546 .10 34020 43.271 138.924 15.9172 .46042 .20620 .019 .20657 .72 34021 43.268 139.369 15.8084 .60160 .20495 .012 .20517 .21 34022 43.268 139.814 15.7997 .76231 .20516 .009 .20522 .41 34023 43.272 140.416 15.7879 .94308 .20507 .006 .20493 .51 34024 43.276 141.033 15.7758 1.14107 .20466 .005 .20431 .45 34026 35.897 139.049 15.7523 .46016 .20370 .018 .20402 .78 34027 35.899 139.469 15.7439 .60116 .20340 .012 .20358 .73 34028 35.912 139.989 15.7335 .76147 .20244 .009 .20244 .38 34029 35.924 140.409 15.7252 .94079 .20215 .006 .20201 .33 34030 35.926 140.985 15.7136 1.14072 .20158 .004 .20125 .19 34031 29.307 138.706 15.7009 .33841 .20167 .029 .20210 .86 34032 29.307 138.981 15.6953 .46051 .20154 .018 .20188 .86 34033 29.317 139.463 15.6854 .60198 .20060 .011 .20078 .51 34034 29.320 139.943 15.6756 .76264 .19975 .008 .19977 .21 34035 29.320 140.503 15.6641 .94333 .20007 .006 .19991 .51 34036 29.327 141.050 15.6529 1.14363 .19932 .005 .19898 .27 34037 22.775 138.679 15.6410 .33855 .19730 .028 .19773 -.13

34038 22.775 139.156 15.6310 .46065 .19854 .018 .19881 .62 34039 22.797 139.494 15.6241 .60170 .19830 .012 .19846 .58 34040 22.797 139.876 15.6161 .76208 .19728 .008 .19732 .16 34041 22.804 140.492 15.6032 .94269 .19766 .006 .19750 .51 34042 22.807 141.080 15.5908 1.14261 .19666 .005 .19632 .16 34043 15.268 138.767 15.5660 .33861 .19690 .026 .19729 1.14

34044 15.253 139.119 15.5583 .46068 .19638 .018 .19665 .97 34045 15.255 139.508 15.5499 .60185 .19546 .012 .19561 .61 34046 15.252 140.007 15.5391 .76248 .19451 .008 .19451 .26 34047 15.253 140.601 15.5262 .94249 .19409 .006 .19391 .21 34048 15.256 141.203 15.5132 1.14326 .19389 .004 .19353 .27 34049 8.458 139.716 15.4971 .33865 .19396 .028 .19435 1.02

34050 8.469 139.054 15.4897 .46059 .19243 .017 .19272 .32 34051 8.476 139.447 15.4811 .60173 .19210 .012 .19227 .26 34052 8.476 140.005 15.4687 .76260 .19228 .007 .19228 .51 34053 8.493 140.469 15.4585 .94276 .19188 .006 .19174 .44 34054 8.496 141.215 15.4420 1.14337 .19108 .005 .19072 .23 34055 2.585 138.767 15.4319 .33893 .19094 .027 .19130 .73 34056 2.585 139.170 15.4232 .46102 .18984 .016 .19008 .27 34057 2.592 139.504 15.4156 .60222 .19034 .010 .19049 .63 34058 2.595 140.055 15.4031 .76322 .18983 .007 .18981 .53 34059 2.604 140.600 15.3908 .94347 .18931 .006 .18914 .42 34060 2.610 141.265 15.3757 1.14450 .18899 .004 .18863 .45

Exper 1 mental Adjusted Thermal Conduct I v 1 ty

Therma 1 at a nominal devl at Ion Run Pt. Pressure Temperature Dens 1 ty Power Conductivity STAT Temperature of 112 K from correlation

MPa K mo 1 / L W/m W/m.K W/m.K percent

35002 65.496 111.560 16.4969 .45484 .22052 .018 .22077 -.19

35003 65.500 111.859 16.4913 .57629 .22068 .012 .22076 -.09

35004 65.503 112.251 16.4840 .71290 .22006 .010 .21992 -.33

35005 65.516 112.467 16.4800 .78691 .22019 .007 .21992 -.25

35006 65.518 112.737 16.4750 .86492 .22039 .007 .21997 -.13

35007 58.233 111.160 16.4607 .34796 .21792 .025 .21840 -.57

35008 58.232 111.505 16.4541 .45478 .21788 .017 .21816 -.55

35009 58.230 111.810 16.4483 .57617 .21815 .011 .21826 -.40

35010 58.220 112.155 16.4417 .71263 .21796 .009 .21787 -.44

35011 58.220 112.372 16.4375 .78647 .21842 .008 .21821 -.21

35012 58.217 112.554 16.4340 .86435 .21798 .007 .21767 -.39

35013 58.217 112.810 16.4292 .94595 .21814 .006 .21769 -.29

35014 58.219 113.018 16.4252 1.03146 .21771 .005 .21714 -.46

35015 58.209 113.279 16.4202 1.12119 .21787 .004 .21716 -.36

35016 51.090 111.181 16.4157 .34792 .21772 .028 .21818 .20 35017 51.087 111.420 16.4111 .45456 .21744 .019 .21777 .10 35018 51.089 111.799 16.4037 .57598 .21617 .013 .21628 -.44

35019 51.090 112.152 16.3969 .71248 .21611 .009 .21603 -.43

35020 51.087 112.329 16.3934 .78636 .21600 .007 .21582 -.45

35021 51.089 112.530 16.3895 .86416 .21605 .006 .21576 -.41

35022 43.810 111.249 16.3671 .34816 .21256 .026 .21298 -1.27

35023 43.820 111.609 16.3600 .45526 .21467 .016 .21489 -.24

35024 43.816 111.974 16.3528 . 57718 .21401 .013 .21402 -.50

35025 43.816 112.165 16.3490 .71369 .21427 .009 .21418 -.35

35026 43.812 112.561 16.3411 .86587 .21389 .007 .21358 -.48

35027 37.217 111.283 16.3219 .34810 .21191 .027 .21231 -.71

35028 37.225 111.566 16.3162 .45475 .21350 .018 .21374 .08 35029 37.229 111.854 16.3104 .57624 .21331 .013 .21339 .03 35030 37.242 112.700 16.2934 .86512 .21250 .007 .21212 -.24

35031 37.242 112.294 16.3016 .71321 .21238 .009 .21222 -.35

35032 29.922 111.342 16.2693 .34831 .21125 .027 .21161 -.02

35033 29.926 111.601 16.2640 .45509 .21156 .018 .21178 .17 35034 29.932 111.824 16.2595 .57639 .21111 .012 .21121 -.02

35035 29.945 112.282 16.2501 .71333 .21071 .009 .21056 -.14

35036 29.950 112.527 16.2451 .78763 .21040 .008 .21012 -.26

56
35037 29.949 112.732 16.2409 .86560 .21053 .007 .21014 •§ 16 35039 23.069 111.133 16.2234 .34796 .20982 .023 .21029 .25 35040 23.078 111.441 16.2170 .45494 .20875 .018 .20905 -.22

35041 23.085 111.923 16.2069 .57696 .20900 .012 .20904 -.03

35042 23.095 112.307 16.1989 .71384 .20913 .008 .20897 .09

35043 23.100 112.708 16.1905 .86587 .20892 .006 .20855 .05 33044 15.502 111.205 16.1638 .34820 .20671 .024 .20713 -.11

33045 15.506 111.565 16.1560 .45514 .20628 .016 .20651 -.26

35046 15.312 111.921 16.1484 .57703 .20719 .012 .20723 • 23 35047 15.516 112.184 16.1427 .71331 .20634 .009 .20624 -.14

35046 15.320 112.720 16.1312 .86567 .20673 .006 .20636 .14 35049 8.380 111.246 16.1054 .34831 .20376 .025 .20415 -.43

35030 8.383 111.550 16.0987 .45524 .20440 .017 .20463 -,or

35051 8.383 111.886 16.0913 .57688 .20465 .011 .20471 .11 35052 8.366 112.305 16.0821 .71365 .20466 .009 .20450 .*19 33053 8.388 112.489 16.0780 .78756 .20447 .008 .20422 .13 35054 8.391 112.756 16.0721 .86595 .20452 .006 .20413 .20, 35055 2.388 111.128 16.0576 .34812 .20356 .025 .20401 .42 35056 2.394 111.535 16.0464 .45518 .20252 .017 .20276 -.02

35057 2.394 111.915 16.0398 .57712 .20239 .012 .20243 -.01

35058 2.394 112.280 16.0316 .71371 .20239 .009 .20225 .05 35059 2.396 112.461 16.0275 .78764 .20280 .007 .20257 .29 35060 2.404 112.709 16.0219 .86595 .20242 .007 .20206 .15

67
6. References

[1] Roder, H. M. A transient hot wire thermal conductivity apparatus for fluids. J. Res. Nat. Bur. Stand. (U.S.). 86(5): 457-493; 1981 September-October

.

[2] de Castro, C. A. N.; Roder, H. M. Absolute determination of the thermal

conductivity of argon at room temperature and pressures up to 68 MPa. J. Res.

Nat. Bur. Stand. (U.S.). 86(3): 293-307; 1981 May-June.

[3] de Castro, C. A. N.; Roder, H. M. The thermal conductivity of argon at 300.65 K. Evidence for a critical enhancement? Sengers, J. V., ed. Proceedings of the 8th

symposium on thermophysical properties; 1981 June 15-18; Gaitherburg, Maryland.

ASME, New York; 1982. 241-246.

[4] Roder, H. M. The thermal conductivity of oxygen. J. Res. Nat. Bur. Stand.

(U.S.). 87(4): 279-310; 1982 July-August.

[5] Roder, H. M. Thermal conductivity of normal hydrogen. Hust, J. G., ed. Thermal

Conductivity 17; 1981 June 15-18; Gaithersburg, Maryland. Plenum, New York;

1983. 257-264.

[6] Roder, H. M. Thermal conductivity of parahydrogen . J. Chem. Engr. Data (in

press)

.

[7] Roder, H. M. The thermal conductivity of hydrogen for temperatures between 78

and 310 K with pressures to 70 MPa. Internat. J. Thermophys. (in press).

[8] McCarty, R. D. Interactive fortran IV computer programs for the thermodynamic

and transport properties of selected cryogens [fluids pack]. Nat. Bur. Stand.

(U.S.) Tech. Note 1025; 1980 October. 112 p. [9] Roder, H. M. The thermal conductivity of methane for temperatures between 110

and 310 K with pressures to 70 MPa. Submitted to Internat. J. Thermophys.

[10] Roder, H. M.; Nieto de Castro, C. A. The thermal conductivity of ethane for

temperatures between 110 and 325 K with pressures to 70 MPa. Submitted to 9th

European conf. on thermophysical properties. Proceedings to be published in

High Temperatures-Hi gh Pressures.

[11] Goodwin, R. D.; Roder, H. M.; Straty, G. C. Thermophysical properties of ethane,

from 90 to 600 K at pressures to 700 bar. Nat. Bur. Stand. (U.S.) Tech. Note

684; 1976 August. 326 p. [12] Koder, H. M.; de Castro, C. A. N. Thermal conductivity of liquid propane. J. Chem. Engr. Data 27(1): 12-15; 1982 January.

[13] Goodwin, R. D. Unpublished; an improved version very similar to: Goodwin, R. D. Nat. Bur. Stand. (U.S.) NBSIR 77-860; 1977 July; Goodwin, R. D. Adv. Chem. Ser.

No. 182; 1979. 345; and Goodwin, R. U.; Haynes, W. M. Thermophysical properties

of propane from 85 to 700 K at pressures to 70 MPa. Nat. Bur. Stand. (U.S.)

Monograph 170; 1982 April. 249 p.

58
U.5. DEPT. OF COMM.

BIBLIOGRAPHIC DATA

1. PUBLICATION OR

REPORT NO.

2. Performing Organ. Report No. 3. Publication Date

SHEET (See instructions) NBSIR 84-3006 May 1984

4. TITLE AND SUBTITLE

EXPERIMENTAL THERMAL CONDUCTIVITY VALUES FOR HYDROGEN, METHANE, ETHANE AND

PROPANE

5. AUTHOR(S)

H. M. Roder

6 . PERFORMING ORGANIZATION (If joint or other than N BS, see instructions)

national bureau of standards

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

7. Contract/Grant No. C-32369-C

8. Type of Report & Period Covered

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State, ZIP)

NASA-Lewis Research Center

Cleveland, Ohio 44135

10. SUPPLEMENTARY NOTES

_2 Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant

bi bl iography or literature survey, mention it here)

The experimental measurements of thermal conductivity as obtained in a transient hot

wire apparatus for hydrogen, methane, ethane and propane are recorded.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by co ethane; hot wire; hydrogen; measurements; methane; propane; thermal conductivity;

transient.

13. AVAILABILITY

[~~X] Unlimited

| | For Official Distribution. Do Not Release to NTIS

2] Order From Superintendent of Documents, U.S. Government Printing Office, Washington, D.C.

20402.

t_X] Order From National Technical Information Service (NTIS), Springfield, VA. 22161

14. NO. OF

PRINTED PAGES

64

15. Price

$ 10.00

*U.S. GOVERNMENT PRINTING 0FFICE:1984—779-893/9382 fCOuu.QC