Exhaust Emissions Sampling 

Daltile, Muskogee, OK 

Kiln #l, Kiln #2, Trim Kiln, Scrubber Exhaust 

April 21 - 22, 2005 

Armstrong Environmental, Inc. 

Project W-2457-05 

Report Prepared For: 

Bob Hurt 

Daltile 

7834 C. F. Hawn Freeway 

Dallas, TX 75217 

Report Prepared May 2, 2005 By: 

ArmstYong Environmental, Inc. 

7715 Sovereign Row 

Dallas, Texas 75247 

(214) 631-0021 
I. INTRODUCTION 

A series of tests was performed on the exhausts associated with Kiln #l, Ki1n #2, Trim 

Kiln, and the Scrubber at the Daltile facility in Muskogee, OK on April 21 - 22, 2005. 

The purpose of this test series was to determine the exhaust emission rate of PM, 

Hydrogen Fluoride, Hydrogen Chloride and Chlorine in terms of lbs/hr. 

Testing followed procedures detailed in Title 40: Code of Federal Regulations (40:CFR). 

Sampling was performed by Richard Taylor, Dan Barrera and Tom Armstrong of 

Armstrong Enviromnental, Inc. using two Apex Method 5 sampling trains. 

Three one hour test repetitions were performed on each source according to the following 

schedule: 

Source Date Start Time Finish Time 

Kiln #1 4/21/05 9:00 AM 1:02 PM 

Kiln #2 4/21/05 9:00 AM 1:03 PM 

Trim Kiln 4/21/05 2:35 PM 6:41 PM 

Scrubber 4/21/05 2:35 PM 3:36 PM 

Scrubber 4/22/05 8:15 AM 10:42 AM 

Submitted by: 

I 

1 
II. SUMMARY 

A series of tests was performed on the exhausts associated wit11 Kiln 91, Kiln #2, the 

Trim Kiln, and the Scrubber at the Daltile facility in Muskogee, OK on Apri121 - 22, 

2005. 

Sampling was performed following procedures detailed in Title 40: Code of Federal 

Regulations. 

Results of this test series are summarized in Tables 1- 4 

Results indicate the following emission rates for Kiln #1: 

Run # 1 2 3 Avera e 

PM, lbs/hr 1.398 1.387 1.135 1.307 

HF, lbs/hr 4.507 3.872 4.222 4.200 

HCI, Ibs/hr 4.367 3.714 4.237 4.106 

C12, lbs/hr 0.212 0.290 0.333 0.278 

Results indicate the following emission rates for Kiln 42: 

Run # 1 2 3 AveraQe 

PM, lbs/hr 1.276 1.148 1.113 1.179 

HF, lbs/hr 3.893 3.695 3.909 3.834 

HCl, lbs/hr 4.306 3.840 4.349 4.165 

C12, Ibs/hr 0.324 " 0.413 0.331 0.356 

Results indicate the following emission rates for the Trim Kiln: 

Run # 1 2 3 Avera e 

PM, lbs/hr 1.009 1.135 0.723 0.956 

HF, lbs/hr 1.639 1.635 1.291 1.522 

HCl, lbs/hr 1.463 1.504 1.344 1.437 

C12, lbs/hr 0.130 0.125 0.111 0.122 

Results indicate the following emission rates for the Scrubber: 

Run # 1 2 3 Avera e 

PM, lbs/hr 7.489 11.473 18.024 12.329 

HF, Ibs/hr 0.118 0.120 0.087 0.108 

HCI, lbs/hr 0.096 0.107 0.065 0.089 

C12, lbs/hr 0.195 0.219 0.188 0.201 

® 
01 

579.6 

44.10 

21948.2 

9807.4 

588443 

10.41 Jo 

4.00 

16.00 

10:30 AM 

11:32 AM 

36.179 

101.7204 

31.30 

0.013349 

1.122537 

7.37 

0.003143 

0.264316 

1.386853 

3 

581.0 

45.28 

22535.6 

10082.5 

604952 

10.17 J 

4.00 

16.00 

12:00 PM 

1:02 PM 

37.127 

101.5383 

30.09 

0.012505 

1.081077 

1.50 

0.000623 

0.053892 

1.134969 

107.97 117.50 

126.737 134.406 

3.872142 4.22166 

SUMMARY OF EMISSIONS TEST DATA 

~ 

Table : 1 

Plant : Daltile, Muskogee, OK 

Location : Kiln #1 

Operator : R. Taylor 

Test Date : 21-Apr-05 

Repetition : 1 

STACK GAS 

Temperature, F 571.5 

Velocity, fps 45.24 

Volume Flow, acfm 22519.4 

scfm 10134.0 

scfh 608038 

Moisture, % 10.48 0 

CO2, ~/'o 3.00 

02, % 17.00 

SAMPLE 

Start Time, hrs:min 9:00 AM 

Finish Time, hrs:min 10:01 AM 

Sample Volume, scf 35.762 

Isokinetic Ratio, % 97.30843 

PARTICULATE 

Front Half 

Sample Weight, mg 31.47 

Concentration, gr/scf 0.013578 

Emissions, Ibs/hr 1.179806 

Back Half 

Sample Weight, mg 

Concentration, gr/scf 

Emissions, Ibs/hr 

Total Particulate, Ibs/hr 

HYDROGEN FLUORIDE 

Sample Weight, mg 

Concentration, ppm 

Emissions, Ibs/hr 

5.82 

0.002511 

0.218191 

1.397997 

120.22 

142.758 

4.506871 

~ 

CHLORINE 

Sample Weight, mg 

Concentration, ppm 

Emissions, Ibs/hr 

5.65 

1.889154 

0.211724 

8.10 

2.678335 

0.290497 

9.28 

2.990126 

0.333413 

HYDROGEN CHLORIDE 

Sample Weight, mg 116.49 103.55 117.93 

Concentration, ppm 75.79956 66.60023 73.9137 

Emissions, Ibs/hr 4.36721 3.713527 4.23694 

F 
25.48 26.64 

0.009106 0.009588 

0.944871 0.982419 

5.47 3.55 

0.001955 0.001278 

0.202843 0.130915 

1.147715 1.113334 

SUMMARY OF EMISSIONS TEST DATA 

Table : 2 

Plant : Daltile, Muskogee, OK 

Location : Kiln #2 

Operator : T. Armstrong 

Test Date : 21-Apr-05 

Repetition : 1 

STACK GAS 

Temperature, F 539.5 

Velocity, fps 50.62 

Volume Flow, acfm 25196.7 

scfm 11859.0 

scfh 711541 

Moisture, % 9.28% 

CO2, % 3.00 

02, ~/"0 17.00 

SAMPLE 

Start Time, hrs:min 9:00 AM 

Finish Time, hrs:min 10:02 AM 

Sample Volume, scf 42.446 

Isokinetic Ratio, % 99.08614 

PARTICULATE 

Front Half 

Sample Weight, mg 22.08 

Concentration, gr/scf 0.008027 

Emissions, Ibs/hr 0.816149 

Back Half 

Sample Weight, mg 12.45 

Concentration, gr/scf 0.004526 

Emissions, Ibs/hr 0.460193 

Total Particulate, Ibs/hr 1.276341 

HYDROGEN FLUORIDE 

Sample Weight, mg 105.31 

Concentration, ppm 105.3681 

Emissions, Ibs/hr 3.892719 

CHLORINE 

Sample Weight, mg 8.76 

Concentration, ppm 2.468188 

Emissions, Ibs/hr 0.323706 

HYDROGEN CHLORIDE 

Sample Weight, mg 116.49 

Concentration, ppm 63.86364 

Emissions, Ibs/hr 4.305864 

2 3 

551.4 551.7 

51.77 51.53 

25766.5 25649.2 

12102.4 11950.2 

726143 717014 

8.39 0 9.09 ~/"0 

3.00 3.00 

17.00 17.00 

10:30 AM 12:00 PM 

11:32 AM 1:03 PM 

43.177 42.872 

98.76632 99.31629 

99.63 105.99 

97.99323 104.9955 

3.694551 3.908791 

11.15 8.97 

3.087873 2.502966 

0.413289 0.330792 

103.55 117.93 

55.80527 64.00973 

3.839757 4.34891 

el 
III. PROCEDURES 

The procedure for emissions sampling followed USEPA test methods as detailed in Title 

40: Code of Federal Regulations. The following methods were used: 

Method Title 

1 Sample and Velocity Traverses for Stationary Sources 

2 Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S 

Pitot Tube) 

3 Gas Analysis for CO2, 02, Excess Air and Dry Molecular Weight 

5 Determination of Particulate Emissions from Stationary Sources 

26A Determination of Hydrogen Halides and Halogens Emissions from 

Stationary Sources 

02 and CO2 were determined using FyRite Analyzers. 

PM. HF, HCI, and CL2 sampling was performed on each source for a duration of 60 

minutes. Sampling points and dwe11 times were as follows: 

Soui- ee Points Dwell Time 

Kiln # 1 24 2.5 minutes 

Kiln #2 24 2.5 minutes 

Trim Kiln 12 5 minutes 

Scrubber 20 3 minutes 

The sampling train was configured as follows: 

Glass Sampling Nozzle 

Heated Glass Lined Probe 

Heated teflon filter 

lmpinger #1 - 100 mis H20 

Impinger #2 - 100 mis 0.1 N H2SO4 

Impinger #3 - 100 mis 0.1 N H2SO4 

Impinger #4 - 100 mis 0.1 N NaOH 

Iinpinger #5 - 100 mis 0.1 N NaOH 

hnpinger #6 - 200 grams silica Gel 

Analysis for PM was performed on the probe wash, filter, and solution from the first 

impinger. HF and HCl analysis was performed on an aliquot from the first impinger, and 

the solution from the 2nd and 3rd impingers. Analysis for C12 was performed on the 

7 
solution from the 4th and 5th impingers. Analysis was performed using a Dionex 500 

IC/HPLC. 
Appendix A 
EMISSION TEST SUMMARY 

PLANT : Daltile, Muskogee, OK 

DATE : 21-Apr-05 

PLACE: Kiln 41 

RUN#: . 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 88.9 

NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) : 31.47 

METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) : 5.82 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.25 

GAS METER VOL.(Cu.Ft.) : 37.157 PERCENT CO2 3 

BAROMETRIC PRESSURE 29.4 PERCENT 02 17 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 35.7623 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.1845 

FRACTIONAL MOISTURE CONTENT 0.1048 

DRY BASE: 80.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 

MOLECULAR WT. OF STACK GAS (WET BASE): 27.9910 

STACK PRESSURE (inch Hg): 29.3816 

STACK GAS VELOCITY (ft/sec.): 45.2428 

ACTUAL STACK GAS FLOW RATE (ACFM): 22519.4372 

STANDARD STACK GAS FLOW RATE (SCFH): 608038.089 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0136 

PARTICULATE CONCENTRATION (LBS/SCF): 1.94E-06 

PARTICULATE EMISSION (LBS/HR): 1.1798 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0025 

PARTICULATE CONCENTRATION (LBS/SCF): 3.59E-07 

PARTICULATE EMISSION (LBS/HR): 0.2182 

ISOKINETIC RATIO (%): 97.3084 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 534 0.28 0.52915 0.97 68 68 

2 553 0.40 0.632456 1.35 70 68 

3 565 0.41 0.640312 1.40 73 68 

4 570 0.42 0.648074 1.40 74 69 

5 574 0.43 0.655744 1.45 75 70 

6 574 0.40 0.632456 135 76 70 

7 571 0.31 0.556776 1.05 77 70 

8 570 0.28 0.52915 0.94 78 70 

9 570 0.24 0.489898 0.80 79 72 

10 570 0.23 0.479583 0.77 79 72 

11 567 0.21 0.458258 0.70 80 73 

12 562 0.20 0.447214 0.67 80 74 

13 562 0.19 0.43589 0.64 81 75 

14 574 0.28 0.52915 0.94 82 75 

15 577 0.34 0.583095 1.15 83 76 

16 579 0.40 0.632456 1.35 84 77 

17 582 0.40 0.632456 1.35 85 78 

18 583 0.39 0.6245 1.35 85 78 

19 583 0.35 0.591608 1.20 85 78 

20 582 033 0.574456 1.10 85 79 

21 583 0.32 0.565685 1.10 85 79 

22 581 0.32 0.565685 1.10 85 79 

23 578 0.30 0.547723 1.00 86 80 METER T. 

24 572 0-27 0.519615 0.92 86 80 AVERAGE 

571.5 0.5626 1.0854 80.0417 74.0833 77.0625 

~ 

~ 
EMISSION TEST SUMMARY 

PLANT : Daltile, Muskogee, OK 

DATE : 21,Apr-05 

PLACE : Kiln =i 

RUN#: 2 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 89.3 

NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) : 31.3 

METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) : 7.37 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.25 

GAS METER VOL.(Cu.Ft.) : 38.31 PERCENT CO2 4 

BAROMETRIC PRESSURE 29.4 PERCENT 02 16 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inches) : 

STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inches) : 

NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOwS 

SAMPLED VOLUME (STD. CU .FT.): 36.1790 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2034 

FRACTIONAL MOISTURE CONTENT (%): 0.1041 

DRY BASE: 80.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.2800 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.1059 

STACK PRESSURE (inch Hg): 29.3816 

STACK GAS VELOCITY (ft/sec.): 44.0952 

ACTUAL STACK GAS FLOW RATE (ACFM): 21948.2207 

STANDARD STACK GAS FLOW RATE (SCFH): 588442.815 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0133 

PARTICULATE CONCENTRATION (LBS/SCF): 1.91E-06 

PARTICULATE EMISSION (LBS/HR): 1.1225 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0031 

PARTICULATE CONCENTRATION (LBS/SCF): 4.49E-07 

PARTICULATE EMISSION (LBS/HR): 0.2643 

ISOKINETIC RATIO (%): 101.7204 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 577 0.26 0.509902 0.88 83 82 

2 583 0.37 0.608276 1.30 89 84 

3 585 0.39 0.6245 1.30 90 84 

4 587 0.40 0.632456 1.40 90 84 

5 587 0.40 0.632456 1.40 90 85 

6 587 0.40 0.632456 1.40 90 85 

7 583 0.32 0.565685 1.10 90 85 

8 581 0.28 0.52915 0.98 90 85 

9 578 0.25 0.5 0.87 90 85 

10 574 0.23 0.479583 0.80 90 85 

11 568 0.20 0.447214 0.70 90 85 

12 565 0.19 0.43589 0.67 90 85 

13 572 0.19 0.43589 0.66 88 86 

14 579 0.26 0.509902 0.91 89 86 

15 587 0.34 0.583095 1.20 90 86 

16 584 0.35 0.591608 1.20 90 86 

17 587 0.37 0.608276 1.30 90 86 

18 588 037 0.608276 1.30 90 86 

19 576 0.25 0.5 0.88 90 86 

20 579 0.27 0.519615 0.95 90 86 

21 580 0.33 0.574456 1.20 89 86 

22 584 0.30 0.547723 1.05 89 86 

23 571 0.29 0.538516 1.00 89 86 METER T. 

24 568 0.27 0.51•9615 0.94 89 86 AVERAGE 

579.58333 0.5473 1.0579 89.3750 85.2500 87.3125 

.~_ 
~ 

EMISSION TEST SUMMARY 

PLANT : Daltile, Muskogee, OK 

DATE : 21-Apr-05 

PLACE: KilnTl 

RUN#: 3 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 

NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) 

METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 

GAS METER VOL.(Cu.Ft.) : 39372 PERCENT CO2 

BAROMETRIC PRESSURE 29.4 PERCENT 02 

PERCENT CO 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) : 

' ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 37.1274 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2034 

FRACTIONAL MOISTURE CONTENT (%): 0.1017 

DRY BASE: 80.0000 

MOLECULAR WT, OF STACK GAS (DRY BASE): 29.2800 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.1328 

STACK PRESSURE (inch Hg): 29.3816 

STACK GAS VELOCITY (ft/sec.): 45.2752 

ACTUAL STACK GAS FLOW RATE (ACFM): 22535.5569 

STANDARD STACK GAS FLOW RATE (SCFH): 604951.788 

~ PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0125 

PARTICULATE CONCENTRATION (LBS/SCF): 1.79E•06 

PARTICULATE EMlSSION (LBS/HR): 1.0811 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0006 

PARTICULATE CONCENTRATION (LBS/SCF): 8.91E-08 

PARTICULATE EMISSION (LBS/HR): 0.0539 

ISOKINETIC RATIO (%): 101.5383 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 582 0.27 0.519615 0.91 84 84 

2 582 0.37 0.608276 1.30 86 84 

3 586 0.41 0.640312 1.40 87 84 

4 587 0.41 0.640312 1.40 88 84 

5 585 0.40 0.632456 1.40 89 84 

6 585 0.39 0.6245 1.35 89 84 

7 585 0.31 0.556776 1.10 89 85 

8 584 0.27 0.519615 1.00 90 85 

9 582 0.25 0.5 0.87 90 85 

10 578 0.26 0.509902 0.90 90 85 

11 573 0.21 0.458258 0.73 90 85 

12 563 0.19 0.43589 0.66 90 85 

13 568 0.20 0.447214 0.70 89 86 

14 579 0.27 0.519615 0.94 90 86 

15 582 0.37 0.608276 1.30 91 87 

16 587 0.40 0.632456 1.40 91 87 

17 587 0.39 0.6245 1.35 92 87 

18 590 0.39 0.6245 1.35 92 87 

19 580 0.35 0.591608 1.20 92 88 

20 587 0.36 0.6 1.25 93 88 

21 586 0.34 0.583095 1.20 94 88 

22 581 0.30 0.547723 1.00 94 89 

23 575 0.29 0.538516 1.00 94 89 METER T. 

24 571 0.27 0.519615 0.94 94 89 AVERAGE 

581.04167 0.5618 1.1104 90.3333 86.0417 88.1875 

89.3 

30.09 

1.5 

0.25 

4 

16 

O 

0 

~.. ~ 
EMISSION TEST SUMMARY 

PLANT : Daltile, Muskogee, OK 

DATE : 21-Apr-05 

PLACE: Kiln#2 

RUN#: 1 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mIs) : 

NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) 

METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 

GAS METER VOL.(Cu.Ft.) : 44.606 PERCENT CO2 

BAROMETRIC PRESSURE 29.4 PERCENT 02 

PERCENT CO 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) : 

ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 42.4462 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.3399 

FRACTIONAL MOISTURE CONTENT (%): 0.0928 

DRY BASE: 80.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.1248 

STACK PRESSURE (inch Hg): 29.3816 

STACK GAS VELOCITY (ft/sec.): 50.6215 

ACTUAL STACK GAS FLOW RATE (ACFM): 25196.6665 

STANDARD STACK GAS FLOW RATE (SCFH): 711541.187 

PARTI CU LATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0080 

PARTICULATE CONCENTRATION (LBS/SCF): 1.15E-06 

PARTICULATE EMISSION (LBS/HR): 0.8161 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0045 

PARTICULATE CONCENTRATION (LBS/SCF): 6.47E•07 

PARTICULATE EMISSION (LBS/HR): 0.4602 

ISOKINETIC RATIO (°7,): 99.0861 

92.2 

22.08 

12.45 

0.25 

3 

17 

0 

0 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T 

deg F INLET 

485 

519 

532 

539 

539 

544 

545 

548 

549 

548 

545 

sll 

520 

558 

559 

555 

559 

558 

554 

546 

546 

546 

506 

536 

539.45833 0.6410 1.7542 85.6667 

METER T 

OUTLET 

71 

71 

71 

72 

72 

73 

73 

74 

75 

75 

76 

76 

78 

79 

79 

80 

80 

81 

81 

82 

82 

83 

83 METER T. 

83 AVERAGE 

77.0833 81.3750 ~ 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 

0.45 0.67082 

0.52 0.72111 

0.56 0.748331 

0.58 0.761577 

0.55 0.74162 

0.55 0.74162 

0.52 0.72111 

0.52 0.72111 

0.52 0.72111 

0.52 0.72111 

0.54 0.734847 

0.45 0.67082 

0.60 0.774597 

0.63 0.793725 

0.G0 0.774597 

0.55 0.74162 

0.53 0.728011 

0.53 0.728011 z 

0.25 0.5 

0.15 0.387298 

0.11 0.331662 

0.10 0.316228 

0.10 0.316228 

0.10 0.316228 

1.80 

2.10 

2.30 

2.30 

2.20 

2.20 

2.00 

2.00 

2.00 

2.00 

2.10 

1.80 

2.30 

2.50 

2.50 

2.30 

2.20 

zc 

1.00 

0.62 

0.45 

0.41 

0.41 

OA1 

71 

74 

79 

7 9 

83 

s2 

fi3 

85 

86 

86 

ss 

88 

85 

S9 

89 

8 a 

90 

90 

90 

90 

90 

90 

90 

90 

~ ~~ 
EMISSION TEST SUMMARY 

PLANT: Daltile, Muskogee, OK 

DATE : 21-Apr ~ 05 

PLACE: Kiln#t2 

RUN#:, 2 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mIs) : 

NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) 

METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 

GAS METER VOL.(Cu.Ft.) : 46.04 PERCENT CO2 

BAROMETRIC PRESSURE 29.4 PERCENT 02 

PERCENT CO 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inches) : 

STACK AREA (Sq.Ft.) : 8.295768 STACKWIDTH(inches) : 

NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) : 

ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 43.1775 

VOLUME OF WATER VAPOR (STD. CU .FT.): 3.9539 

FRACTIONAL MOISTURE CONTENT (%): 0.0839 

DRY BASE: 80.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.2238 

STACK PRESSURE (inch Hg): 29.3838 

STACK GAS VELOCITY (ft/sec.): 51.7663 

ACTUAL STACK GAS FLOW RATE (ACFM): 25766.4705 

STANDARD STACK GAS FLOW RATE (SCFH): 726142.608 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0091 

PARTICULATE CONCENTRATION (LBS/SCF): 1.30E•06 

PARTICULATE EMISSION (LBS/HR): 0.9449 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0020 

PARTICULATE CONCENTRATION (LBS/SCF): 2.79E•07 

PARTICULATE EMISSION (LBS/HR): 02028 

ISOKINETIC RATIO (%): 98.7663 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 552 0.50 0.707107 2.05 85 85 

2 553 0.58 0.761577 2.40 87 86 

3 555 0.58 0.761577 2.40 89 86 

4 556 0.56 0.748331 2.30 91 85 

5 557 0.55 0.74162 2.30 91 85 

6 556 0.57 0.754983 2.30 92 85 

7 555 0.54 0.734847 2.20 92 86 

8 559 0.54 0.734847 2.20 93 86 

9 558 0.55 0.74162 2.30 94 86 

10 558 0.55 0.74162 2.30 94 87 

11 557 0.53 0.728011 2.20 94 87 

12 547 0.48 0.69282 2.00 94 87 

13 541 0.60 0.774597 2.50 92 87 

14 553 0.64 0.8 2.60 95 88 

15 555 0.61 0.781025 2.50 94 88 

16 554 0.53 0.728011 2.20 93 88 

17 554 0.53 0.728011 2.20 93 88 

18 553 0.55 0.74162 2.30 93 88 

19 552 0.31 0.556776 1.30 93 88 

20 548 0.17 0.412311 0.70 92 88 

21 547 0.10 0.316228 0.41 92 88 

22 547 0.12 0.34641 0.50 92 88 

23 543 0.10 0.316228 0.41 92 88 METER T. 

24 523 0.10 0.316228 0.41 92 88 AVERAGE 

551.375 0.6528 1.8742 92.0417 86.9167 89.4792 

84 

25.48 

5.47 

-0.22 

3 

17 

0 

0 

~ 
EMISSION TEST SUMMARY 

PLANT : Daftile, Muskogee, OK 

DATE : 21-Apr-05 

PLACE : Kiln 42 

RUN#: 3 

TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 91.1 

NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) : 26.64 

METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) : 3.55 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.24 

GAS METER VOL.(Cu.Ft.) : 45.757 PERCENT CO2 3 

BAROMETRIC PRESSURE 29.4 PERCENT 02 17 

PERCENT CO 0 

FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) : 0 

ENTER THE STACK AREA SHOWN ABOVE: 8.295768 

FLOWS 

SAMPLED VOLUME (STD. CU .FT.): 42.8720 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2881 

FRACTIONAL MOISTURE CONTENT (%): 0.0909 

DRY BASE: 80.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.1453 

STACK PRESSURE (inch Hg): 29.3824 

STACK GAS VELOCITY (ft/sec.): 51.5307 

ACTUAL STACK GAS FLOW RATE (ACFM): 25649.1985 

STANDARD STACK GAS FLOW RATE (SCFH): 717014.424 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0096 

PARTICULATE CONCENTRATION (LBS/SCF): 1.37E-06 

PARTICULATE EMISSION (LBS/HR): 0.9824 

BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0013 

PARTICULATE CONCENTRATION (LBS/SCF): 1.83E-07 

PARTICULATE EMISSION (LBS/HR): 0.1309 

ISOKINETIC RATIO (%): 99.3163 

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 572 0.52 0.72111 2.10 87 87 

2 537 0.48 0.69282 2.00 85 85 

3 553 0.61 0.781025 2.50 87 85 

4 554 0.65 0.806226 2.70 90 85 

5 552 0.55 0.74162 2.30 91 85 

6 557 0.55 0.74162 2.30 91 86 

7 559 0.50 0.707107 2.00 92 86 

8 559 0.55 0.74162 2.30 92 86 

9 559 0.55 0.74162 2.30 92 86 

10 558 0.55 0.74162 2.30 92 87 

11 555 0.55 0.74162 2.30 92 87 

12 533 0.48 0.69282 2.00 93 87 

13 544 0.60 0.774597 2.50 92 88 

14 551 0.64 0.8 2.60 93 88 

15 551 0.55 0.74162 2.30 93 8II 

16 553 0.55 0.74162 2.30 94 89 

17 554 0.55 0.74162 2.30 95 89 

18 556 0.56 0.748331 2.30 95 89 

19 554 0.27 0.519615 1.10 95 90 

20 551 0.15 0.387298 0.61 95 90 

21 553 0.10 0.316228 0.41 95 90 

22 549 0.10 0.316228 0.41 95 90 

23 545 0.10 0.316228 0.41 95 90 METER T. 

24 532 0.10 0.316228 0.41 95 90 AVERAGE 

551.70833 0.6488 1.8646 92.3333 87.6250 89.9792 

~ ~: 
Appendix B 
PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 4/21/05 

Location: Kiln #1 

Run 1 Run 2 Run 3 

Density (Pa) 5': * ' i db. 7$54 i 

Blank Concentration (Ca) .7. 

Rinse Volume (Vaw) .5 ......... . 

Residue in Rinse (Wa) = Ca*",Vaw*Pa 0.0004 0.0004 0.0004 

Date of Weighing P 

Time 

Gross Weight ."040 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing ....... . ...... .. ...... 

Time ........... 7. 3-0: AM . 

Beaker Tare Weight 1. -T. 4.; 6.0 54 9 1 i10 0 i 5'-' 3 2 0.1 

Date of Weighing 

Time V ;::::::::2 9: p 

Beaker Tare Weight 

Average Gross Weight 114.6198 107.9072 100.9449 

Less Blank Residue (Wa) 0.0004 0.0004 0.0004 

Average Beaker Tare Weight 114.6054 107.8913 100.9321 

Weight of Particulate in Rinse (mg) 13.97 15.50 12.39 

ACETONE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time ...... . 7.1 A' 

Gross Weight 

Average Gross Weight 99.69895 

Date of Weighing 

Time 

Tare Weight 

Date of Weighing 

Time 

Tare Weight 

Average Tare Weight 99.6983 

Weight of Blank (Ma) 0.00065 

Ca= Ma/(Va*Pa) = mg/g 0.00331 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank 

weight be subtracted from the sample weight. 
FILTER ANALITICAL DATA 

Company: Daltile, Muskogee, OK 

Date: 4/21 /05 

Location: Kiln #1 Exhaust 

Run J. Run 2 Run 3 

Filter ID Number 84T::::::;::::_:: 

Date of Weighing 

Time 

Gross Filter Wt. ;::a: t3::4#3.7- 0$8 

Date of Weighing 

Time :; ::3:~G; Rti~l: ; ;3:~5:P:fVI: :: :3;3~::Rh!►;: 

Gross Filter Wt. ;: : ;:0:`4€3-7, 9: -0:413:5: 

Ave. Gross Filter Wt. 0.4079 0.4060 0.4135 

Date of Weighing ~b " 1 = '[2%E3~:: 

Time 

Filter Tare Wt. 

Date of Weighing 194: .~. ~....~.~.,_..~.,. ~ .__.....~..~..,.-.,~ 

Time 

Filter Tare Wt. ii::::::O;09.04: 

Ave. Filter Tare Wt. 0.3904 0.3902 0.3958 

Wt. of PM on Filter (grams) 0.0175 0.0158 0.0177 

Total Weight of Particulate (mg) 17.5 15.8 17.7 

~, {~ 
PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 4/21/05 

Location: Kiln #1 Exhaust 

Run I Run 2 Run 3 

Density (Pa) 

Blank Concentration (Ca) ...... ..... 

Aliqout Volume (Vaw) .......... 1 9. 

Total Volume 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0005 0.0005 0.0005 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time 

Gross Weight :01.;5 .0 6.Z 5Q `8 :: 

Date of Weighing 1f.4 ID 5: 

Time -7...4 2-, AM: 

Beaker Tare Weight 81 ; 

Date of Weighing 

Time 

Beaker Tare Weight 

Average Gross Weight 101.9011 103.1940 96.2892 

Less Blank Residue (Wa) 0.0005 0.0005 0.0005 

Average Beaker Tare Weight 101.8962 103.1873 96.2882 

Weight of Particulate in Rinse (mg) 4.41 6.16 0.56 

Total Particulate (mg) 4.6379 6.4800 0.5853 

H20 BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time .27. . 

Gross Weight 

5: 

Average Gross Weight 105.95755 

Date of Weighing 

Time 

Tare Weight 

Date of Weighing 

Time p 

Tare Weight 

Average Tare Weight 105.9569 

Weight of Blank (Ma) 0.00065 

Ca= Ma/(Va*Pa) = g/g 2.6E•06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank 

weight be subtracted from the sample weight. 
PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 4/21/05 

Location: Kiln #1 MeCi Rinse 

Run 1 Run 2 Run 3 

Density (Pa) 

Blank Concentration (Ca) 

Rinse Volume (Vaw) ........... 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0002 0.0002 0.0001 

Date of Weighing 

Time P 

Gross Weight 8 .0~ 

Date of Weighing 

Time .3 4~ :A M:: 

Gross Weight 

Date of Weighing -3~. 5v 4 .26 ~65: 

Time AM; 836 8:3 

Beaker Tare Weight 5 5 : 

Date of Weighing 

Time ..... .. 

.. . 

'4 

Beaker Tare Weight 

Average Gross Weight 106.0839 106,7466 98.6450 

Less Blank Residue (Wa) 0.0002 0.0002 0.0001 

Average Beaker Tare Weight 106.0826 106.7456 98.6439 

Weight of Particulate in Rinse (mg) 1.18 0.89 0.91 

METHYLENE CHLORIDE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time 

Gross Weight 1. 0.44:88a.9;: 

Average Gross Weight 104.88395 

Date of Weighing 47 

Time 

Tare Weight 04:8$36:; 

Date of Weighing i i i i0i~- *3* 

Time 

Tare Weight 5:: 

Average Tare Weight 104.88355 

Weight of Blank (Ma) 0.0004 

Ca= Ma/(Va*Pa) = g/g 1.176E•06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank 

wei ht be sWbtracted from the sample weight. - 

11 - 4 
PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 4/21/05 

Location: Kiln #2 

Run I Run 2 Run 3 

Density (Pa) 7 5 1.: -.51: 

Blank Concentration (Ca) 

Rinse Volume (Vaw) 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0003 0.0004 0.0004 

Date of Weighing Z. 2 

Time 

Gross Weight 

Date of Weighing 

Time 'M 

Gross Weight 70 

Date of Weighing 

Time 'M 

Beaker Tare Weight 

Date of Weighing 

Time ~ .1':::: RM: 2 

Beaker Tare Weight 

Average Gross Weight 102.2577 96.2301 113.9286 

Less Blank Residue (Wa) 0.0003 0.0004 0.0004 

Average Beaker Tare Weight 102.2502 96.2192 113.9169 

Weight of Particulate in Rinse (mg) 7.18 10.48 11.24 

ACETONE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing Y-. 

Time A 

Gross Weight 

Average Gross Weight 99.69895 

Date of Weighing 0.5i 

Time 

Tare Weight 

Date of Weighing :: .4I 3iD5: 

Time 

Tare Weight 

Average Tare Weight 99.6983 

Weight of Blank (Ma) 0,00065 

Ca= Ma/(Va*Pa) = mg/g 0.00331 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.00IToof the blank 

weight be subtracted from the sample weight. 
FILTER ANALITICAL DATA 

Company: Daltile, Muskogee, OK 

Date: 4/21 /05 

Location: Kiln #2 Exhaust 

Run 1 Run 2 Run 3 

Filter ID Number 

Date of Weighing 

Time qlltl: 

Gross Filter Wt. `3: :::::: fl:38~6: 

Date of Weighing 

Time ~:45:: Pi~!I:: 

Gross Filter Wt. 

Ave. Gross Filter Wt. 0.3832 0.3924 0.3857 

Date of Weighing 

..........., ............ 

910~ 

........... 

::~ I~~~f(?~':: 

Time U; 

Filter Tare Wt. :::D:3883: :: :0:3774` 

Date of Weighing -1:T1-3004: 

Time 

Filter Tare Wt. 

Ave. Filter Tare Wt. 0.3683 0.3774 0.3703 

Wt. of PM on Filter (grams) 0.0149 0.0150 0.0154 

Total Weight of Particufate (mg) 14.9 15.0 15.4 

s r..~ 
PARTCULATEANALYT|CALOATAFORN1 

Company: DaUi|e, Muokogee,OK 

Dmn: 4/21/05 

LocaVon: Ki|n#2 MeQ Rinse 

~ Run1 Run2 Run3 

L ~ DonsKyVza 

, B|ankConcontratinn(Ca) 

RinxeVo|umo(Vaw) 

~ no,idueinRinso(ma)=Ca°Vaw°Pa 0.0002 0.0002' 0.0001 

- DatoofVVoighin8 ' Timo 

GmxaWeight 

DatooiYVaighing 

Timo 

~ GmosVYeight 

^ 

Datoo(YYoi8hing 

Timo 

BeahorTamWeiKht ~~~3S~~~~ ~~ 1~~~~~ : 

DatenfYVaighing 

Timo 

B eaknr T am VV oight 

~ AvoegeGroxsYYoi8ht 99,4023 

-- 110 . 5477 __-104. 7I

36~ 

LossB|unkRonidue(wa) O , O0U2 0,000 1 

4vnrage 8aakorTamYVoight 

r

--------- 99.4011 110.5467 --------- . --------- 

YVeightof Particu|ate in Rinoe(m8) 0.97 0.83 0.65 

Time 

Time 

Time 

Time 

~-/ 

~~ ~ 
PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 4/21/05 

Location: Kiln #2 Exhaust 

Run I Run 2 Run 3 

Density (Pa) 

Blank Concentration (Ca) ;6: 6: 

Aliqout Volume (Vaw) 

Total Volume ..... :::no: 2 0 

Residue in Rinse (Wa) = Ca*Vaw-l- Pa 0.0005 0.0005 0.0005 

Date of Weighing 

Time i -3't27,. ; F M: 

Gross Weight 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time 

Beaker Tare Weight : : 27-5:: . 

7r ~ 0 2- 1 4 Z : 

Date of Weighing /4- 

Time 

Beaker Tare Weight 

Average Gross Weight 96.1490 101.2191 102.5770 

Less Blank Residue (Wa) 0.0005 0.0005 0.0005 

Average Beaker Tare Weight 96.1376 101.2142 102.5737 

Weight of Particulate in Rinse (mg) 10.91 4.41 2.76 

Total Particulate (mg) 11.4800 4.6379 2.9011 

H20 BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight i 5 S.-.7. 

Date of Weighing 

Time 

Gross Weight 

Average Gross Weight 105.95755 

Date of Weighing V0 

Time 

Tare Weight 

Date of Weighing 

Time 

Tare Weight 

Average Tare Weight 105.9569 

Weight of Blank (Ma) 0.00065 

Ca= Ma/(Va*Pa) = g/g 2.6E•06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001 0, of the blank 

,weight be subtracted from the sample weight. 

-1 
Sheetl 

Summary of Hydrogen Halide and Halogen Analysis 

Plant: ' Daltile, Muskogee,OK 

Date: 4/21/05 

Location: Kiln #1 Exhaust 

Run # Imp # !Volume Dilution : Fl-, ug/ml IHF, m9 ICI-, ug/ml 'I HCI, mg 

11 11 2001 20 27.421 115.493 11 28 07 1 115.4238 - 

1 j 1 2001 201 28.151 118.56781 26.41 108.5568 

111.9903 

2'i 1 2001 201 23.66 99.65592 23.71 97.4544 

21 11 2001 201 25.67 108.1221 24.34 100.0861 

! Average 103.8891 1 98.77024 

---------------- 

31 11 2001 201 26.66 112.29191 29.081 119.577 

3 1 2001 201 27.21 

lAverage 1 

114.56641 

113.42921 

26.27 108.0222 

1 113.7996 

Run # jlrnp# IVolume I Dilution Fl -, ug/m I IHF, mg !Cl-, ug/ml !HCl, mg 

1128 1 i 12.03 3.166898 1 16.791 431503 

112 & 3 1 1 j I 12,17 13.2037531 18.231 4.68511 

lAverage 1 3.1853251 -74-:5-0667-- 

212 & 3 j 250 1 1 15.21!, 4.004033 1 18.62 L_118534 

2j2 & 3 1 I 15.78 4.1540851 18.54 11 4.76478 

jAverage 4.079059 4.77506 

312 & 3 1 2501 11 15.771 4.151453 11 15.92 4.09144 

312 & 3 1 2501 1 15.181 3.9961351 16.211 4.16597 

lAverage 1 4.0737941 4.128705 

Hydrogen Halide Totals !Run# 1 120.21571 116.4904 

1 107.9681 103.5453 

1 117.5031 _LIL7.9283 

un # 'Imp# IVolume IDilution iCi-, ug/ml 1C12, mg i 

1 2501 2 j 10.981 5.49 

1I 2501 21 11.611 ___5.8051 

5.6475 

2501 21 16.15' 8.0751 

21 11 250 21 16.251 8.1251 

8.11 

3 j 11 250j 21 18.621 9.311 

3 1250, 21 18.51 

9.28' 

Page 1 OA 
Sheetl 

n3 Jo 
Conditioma 

Date 

Time 

_ 

[omponont Koton 

z 10 ug/mI Fl— in H20 

z 10 ug/ml Cl— in H20 

: 03/23/2005 

: 1O:41:59 

l02'4OOmV 

Fl- O. 

Cl- 1. 

1O24.DOOmV 

Aroo Exbxnal 

795,08 9.33 

672.04 

 Compunent Number Ret«antion Aree ExteTnaI Unita 

Fl— 1 0'966 795.08 9.33 ug/ml 

Cl— 2 1.283 672.04 9.78 ug/ml 

2 1467-13 19-10 

~~ 
Comditic>ms : 10 ug/ml Fl- in H20 

z 10 ug/ml CI- in H20 

Date : 03/23/2005 

TIme : 10:48:34 

-102'40OmV 1024'O0OmV 

Area IExternaI Unita 

832.60 M 9'79 ug/ml 

673.10 M 9',79 ug/ml 

1505-70 19-58 

Fl` O. 

Cl- 1. 

Area Extmnal 

832.60H YJY 

673.10 M YJY 

Component Number Retention 

Fl- 1 0.966 

Cl- 2 1.300 

2 

~~~ 

~~ 
Area External Unito 

1908'65 21.78 ug/ml 

1778'45 26.59 ug/ml 

Cnmponent Numbmr Retentlon 

Fl- l 0.983 

cI- 2 1.316 

N 

ComditlVma : 25 ug/ml Fl- in H20 

z 25 ug/ml CI- in H20 

Da±e : 03/23/2005 

Time : 10:53:12 

-102.4O0mV lD24.00OmV 

Fl- O. U- 1908.65 21.78 

Ci- 1.31 1778.46 26.59 

~ 

~ 

~{ 

~J 

] ~t 

~~ 

, 
Area ExternaI Unito 

1993.17 22.71 ug/0l 

1784.13 26.68 Vg/ml 

. CVmponent 

FlC}- 

Number Retention 

1 0'988 

2 1.316 

2 

Conditions 

uace 

Tim«p 

: 25 ug/ml Fl- in H20 

z 25 ug/ml CI- In H20 

: 03//23/2005 

: 10:56:16 

L02.4OVmV 1O24'OOOmV 

Aroa External 

Fl_ V. 1998.17 22.71 

C}- 1,31 1784.13 26.68 

~ ~ 

~ 
Conditions =40 ug/ml F1- in H20 

= 40 ug/ra1 CI- in 4-C20 

aate = 03,`23/2005 

Time = 11- 04 =1.3 

-102.4OGmV 

Gompanent Reten " 

Fl- 1. 

Cl- 1. 

1424 . OCC?mV 

Area External 

2930.43 M 33.11 

2397.15 M 36.38 

Co€npanent 

F= l - 

Clz 

Number Retention 

1 1.000 

2 1.333 

Area External Units 

2930.93 M 33.11 ug/mI. 

2397.15 M 36 .,38 ug/m l. 

5328 _ C}9 69 _ 49 

~ :~~ 
-1O2'4OOmV 1024,0OOmV 

_ t Re ten  ' 

Fl- 1. 

ClCnnditiona : 40 Vg/ml FI- in H20 

: 40 ug/ml Cl- in H20 

Date : 03/23/2005 

Tim«a : 11:07:39 

Arva Exhnnal 

2948.90 33.30 

2492.0 37.89 

Numk/er Retwntinn Area ExternaI Unito 

1 1.000 2948'90 33.30 'g/ml 

2 1,333 2492.50 37.89 g/ml 4 

5441.40 71-20 

Compnnent 

FlCl0 

~ D 
Ccsnditions = 5 ugfml Fl° in H24 , 

= 5 ug/ml Cl— in Fi2E7 

Date = 03.12302005 

Time = 11=31=36 

, 

—102 ®4GamV 1024 ,O4C?mV 

Component Retention Area External 

FI- 0. 

Cl- 1. 

386,10 M 4.55 

315.98 M 5.00 

F 1-- 

Cl— 

Component 

E 

Number Retention 

1 0.950 

2 1.266 

Area ExternaZ UnitS 

386.10 M 4.55 ugfml 

:315.98 M 5.00 ugim). 

702 _ a8 9.55 

~ ~ ~t 
Condits.ans = 5 uglml Fi— in H20 

= 5 ug/€nl CI:- 'Ln F320 

t}ate = 03l23I2045 

Ti€ne = 12=34=41 

--1 C72 H 4QOmV 

Companent Reten ' 

Fl- o. 

C1 - l. 

1024 . QC7amV 

Area External 

380.84 M 4.93 

299.84 M 4.74 

Cotnponent Number Retention Area External Units 

Fl— 1 0.966 380n80 M 4.93 ug/ml 

C1— 2 1.283 299.80 M 4.74 ugfml 

© 680.60 

4

,~

~ 
AMOC,tNT ZNJECTED 

AREA 0.000 

0.000 

2939 .915 

40.000. 

1 

2 

3 

4 

5 

Calibration fi.le = FZ-.cal 

Avg s.l.ope crf curve : 76.13 

Y—axis intercept= 0.00 

Caeff nf 1i n regr : 0.88 

hdn . Area AmQunt CF 

0 - 0.000 0.000 0 K aC3Q 

1= 383.450 5,000 76.690 

2: 813.840 10.000 81 ~ 384 

3= 1950.910 25.000 . 78 . a36 

4 : 2939.915 40.000 73.498 

43, 
AMQUNT INJECTED 

AREA 0.00 

0.000 

2444.825 

40.000 

1 

2 

3 

4 

s 

CaZibrativn file : Cl—=cal 

Avg slope of curve = 63.17 

Y--axis intereept= 0.00 

Coeff of li.n regr: 0.85 

No . Area Amount CF 

0: 0.000 0.000 0.000 

1. 307.890 5.000 61.578 

2= 672.570 10.000 67.257 

3=.1781.290 25.000 71.252 

4 ~ 2444 .825 40.000 61.121 

~ Id 
ATea ExteTnal 

211'M5 M 27A2 

1917.12 M 28.07 

conditions : Daltile 

: Kiln #1 

: Run #1 Imp #1 

z Volume 200 mdsz D71-ut'Lon 1120 

Date : 03/23/2005 

Time : 14:05:53 

—102 ~ 4OOmV 1024.00Om11. 

i 91 i 7 2 m 

m 
28.15 

26.40 

2158.76 M 

1843.43 M 

1024.00OmV 

Area Exterpal 

0' ~ 4 C.0 mn V 

conditions : n-a-1--i-le 

Kiln #1 

Run #1 Imp.#I 

Volume 200 mis Dilution 1/20 

Date : 03/23/2005 

Time : 14:09:15 

Compopent Number Retention 

Fici- 2 1.350 1843u43 M 6 4C. u im 

4002.19 54 SES 

53 
Kiln #1 

Run #2 imp,#1 

VC-Oumiz MIR 

Date 03/23/2005 

Time 14:16:41 

1024, OOOmV 

Area External 

ri_ 1849.10 M 23.66 

1.3 1684.93 M 23,70 

2 i .3-1 331 1684.93 M 23 - -70 uVml 

IN 
'K, iln #1 

Pun 

Date : 03/23/2005 

Time : 14:20:10 

ComponentRetefltiop ............................... ...................................... .................................... -........................ 

024 . OOOPO! 

Area External 

v m 1994M M 25z67 

1.3 1732,22 M 24.34 

Component Number Retenti-on A T- =--a E 

1737' M 24.34 ug/mi 
L'Onditions : Daltile 

: Kiln #1 

: Run #3 Imp #1 

: volume i200 mis Dilut.Lon 1/20 

Date : 03/23/2005 

Time : 14:25:15 

1021 4,OOQ-Mv 

Area EXteTflal 

MEN M 26.66 

ri 2 9 . 0 B 

m 
z -t :-:1 1 

K 1 'L n 

Date : 03/23/2005 

Time : 14:27:42 

. . 

. . . . . . . ............................................................... ............. ............ ?IT z, R. P 

2095.64 M 27,20 

1837,30 M 26.27 

Number R o n 

6 - 2 
CoDditioDs : Dal -1-ile 

: Kiln #2 

Run #1 Imp #1 

Vol-ume 200, M-Is Dilut ;Lon 1/20 

Date : 03/23/2005 

Time : 14:33:38 

102-1 4.000mV 

ATea EA,'6erfla-1 

- .... . .. ............. g .. !:!:: , t.11~ !tl:t!:! ,.":!!::t: ,.!!:!:!:!:! -!!:t. ~ ...................... . ............. 

2i 

........... ........................... ............................... ................... ............................................................................................. ........................................ ............. 

193535 M 24 184 

1 778,06 M 24196 

t t 

(Z. 24 Uq/M 

ji 

nti , 
r. x ri 1-1. 

Wi E 1 in m

Date- G%3/23/2C205 

14:361: 17 

R-1 te A Area Externai 

ov ri 2MO 

1-64535 M 23.17 
D a ile 

Kiln #2 

Run #2 Imp #1 

3 z .9 =CV, Date : 03/23/2005 

Time : 14:41:32 

................ ............... ....... ....... ......................................................... 

............. 

...................... 

................. 

................. 

..... .. . ............................. 

vi 

I *Cl* 24", . 0 0 0 m V 

ATea Exterflal 

1 -177' .0 7 ~ J^ M 2232 

1831 : 

lx Q ~ , ,

86 r"! :: -,+ 
6 k--j 

C, ' 2 . ~ V 0 10 2 4 = 0 0 V, rp V 

Kiln #2 

Run 2#2 Imp #1 

Date : 03123/2005 

Time : 14:44:04 

174MM M 22.34 

1714.45 M 24.10 
Cciprlition4 -- Dal t- -, I iz 

K ILln #2 

Run #3 Imp # I 

or, 

Date 03123/2005 

Time 14:51:42 

1024.00OmV 

F 1- 

ciATea Exterpal 

1914.18* M 24,52 

1871.33 M 27.04 

2 I J, 

m 
C, 3 

1 

'L 0 2 ~ 0 0 0 m V 

K iLln #2 

R u n 

t I z 

Date : 03/23/2005 

Time : 14:54:40 

- 1 02 - 4, C-3 0 m V 

Evtzr pa l 

FZ 5. v7 I i-- 

1811,62 Vi 21". 16 

1743.47 M 24.45 

C 
C, c ~ n d i t i 

Date 

Time 

: H20 Blank 

: 03/23/2005 

: 15,:25:14 

0 2 00 m V 1024-000mV 

Area ExteTnal 

n e. 
- 

\ 

. ~ 

_ |` 

Conditions : 5 ug/mI Fl- in H25O4 

: 5 ug/ml Cl- in H2SO4 

Date : 03/24/2005 

Time : 08:56c17 

-102'4OD0V ' . - . .. 

~ m~~ 

(unkmmn) 0.00 

~ on 

1024.00OmV 

Area Exter0al 

252.05 H/A 

Fl- O, 487.09 5.56 

Cl- 1.30 302.55 4.60 

, Component Number Retention Area External Unito 

Fl- 1 0'966 487.09 5'56 ug/ml 

Cl- 2 1.300 302'55 4.60 ug/ml 

2 789-64 10'17 

r, ~ 
Comdltinna 

Date 

Time 

_ 

Cnmu000nt Rotontion 

: 5 4g/mI FT— in H2SO4 

: S ug/ml CI— in H2S(J4 

z 03/24/2005 

: D8z58c21 

102.4OOmV 1O24.00OmV 

Fl- 0, 

Cl- 1. 

Aroa Externa} 

446.87 5.07 

294.47 4.49 

Compmment Number Retention Area External Unita 

Fl— 1 0'966 446.87 5'07 ug/ml 

Cl- 2 1.300 294.47 4 ~ 49 ug/m} 

2 

n ~ 

/~ 
Conditimno : 10 ug/ml Fl- in H2SO4 

: lO ug/ml Cl- in H25O4 

Daate : 03/24/2005 . 

Time c 09:03:24 

-1O2.4D0mV 1024'00OmV 

Aroa Extmna} 

Fl- O. 1 ~- 864.80 10.16 

C1- 1.31 531,35 8.12 

4| 

Component Number Retention Aree External Unita 

Fl- 1 0.983 864'80 10.16 ug/m} 

Cl- 2 1'316 531'35 8.12 ug/ml 

2 1396'15 18'28 

/ ~ 
Condit= ons = 10 ug/ml F1— in N2SO4 

= 10 ug/mi Cl-- in F;2SO4 

date a 03124/2005 

Time = 09=08=12 

-°102 ,4C}OmV 1424 . C?OC7mV 

Component Retention Area External 

Fl- 0. 873.40 M 10.28 

C1- 1.31 537.10_ m 8.20 

Component 

F1wCJ.- 

2 

Number Retention 

1. 0.983 

2 1.316 

Area External Units 

873.90 M 10,28 uglml 

537.10 M 8.20 ugJm l 

1421 _00 18.48 

~r ~ 
Conditiono : 20 ug/ml Fl- in H2SO4 

c 20 ug/m} [I- in H2SO4 

Daate : 03/24/2005 

Timf+ : 09r13:58 

-102.4OOmV 1O24'O0OmV 

Area External 

Fl- 1' 1578.65 18.07 

Cl- 1.% 1090.30 17.74 

Component Numbwr Retention Aree Extermal Unito 

Fl- 1 1.000 1578.65 18.07 ug/m} 

Cl- 2 1,333 1098,30 17'74 ug/ml 

N 

~ A 

~ U ` 
Cmnditloms 

Date 

Time 

: 20 ug/nl Fl- in H2504 

r 20 ug/mI Cl- in H2SO4 

: 03/24/2005 

: O9z16:1S 

lO2.4D0mV lO24.O0OmV 

Arna Exbxnal 

1603.90 M 18.36 

1157.16 M 18.55 

- 

! 

r 

~ 1 

^ FlCl- ' 

O. 

1.3161/ | | ~ 

| ~ 

 CompVnent Number Retentimn Area ExternaI Unito 

Fl- 1 0'983 1603'90 M 18.35 ug/ml 

~ Cl- 2 1,316 1157'15 M 18.55 ug/ml 

~~ 

~~ 

L 
CnnditiVns : 40 ug/ml Fl- in H2SO4 

: 40 ug/ml Cl- In H2SO4 

Date z 03/24/2005 

Tjme* : 09:22:19 

-lO2.4OOmV 

. . Reten .. 

Fl- 1. 

C1- 1. 

1024'00OmV 

Area Extmrnal 

3389.30M #.y1 

2500.47 H 43.\3 

Cnmponent Number Retention Area 

Fl-* 1 1.016 3389'30 M 

cl- 2 1'366 2500'47 M 

External Unito 

44'91 ug/ml 

43.13 ug/ml 
Condltioma 

Date 

Time 

_ 

Componont Kotontion 

: 40 Ug/m} Fl— in H2SO4 

: 40 ug/mI Cl— ln H2SO4 

: 03/'24/'2005 

: O9c27:49 

LO2.40OmV 

Fl- 1' 

1O24'000mV 

Area External 

3393.75 M 44.97 

2532.13 H 43.66 

~ 

Component Number Retention Area ExternaI Units 

Fl— l 1'O0O 3393'75M 44.97 ug/ml 

cl- 2 1'333 2532.13 M 43.66 uA/m} 

2 

~ ~~ 

~a 
Ca.Iibrati-on fiile : FI-xcal 

AREA 

0. 

8391 - 1 

AMf3iiNT iNJECTFD 

0.000 40.QC70 

1 

2 

8 

4 

5 

~ 

~ 

J 

~ 

Avg s.lape nf curve: 84.02 

Y-axis intercept= 0.40 

Coeff of .l i n r egr =. a. 9tJ 

Nn. Area Amaunt 

0. 0.000 Q.0(}tJ 

1: 466.980 5.000 

2: 869.350 10.000 

3= 1591.275 20.000 

4 = 3391 .525 40,000 

CF 

0.000 

93.396 

86.935 

79.564 

84.788 

~ 
AMOE1NT INJECl`ED 

AREA 0.000 

0.00 

2516.30 

40.000 

~ 

2 

3 

4 

5 

CaI. ibration f i 'le : CI.- . cal 

Aug s1ape af Gurve = 58 .91 

Y--axi.s i.ntercept: 0.00 

Cneff af .lin regr : 0.85 

Na . Area Amnunt GF 

0. 0.000 0.000 0.000 

1= 298.510 5.000 59 .7G2 

2= 534.225 10.000 53.422 

3 : 1127.725 20.000 S6.386 

4 K 2516 .30b 40.000 62.908 

~ ~~ 
(Pnknown ) O. 

F]- O. 

C]- \. 

83.6OH MIA 

1O16'2O H ~ 2.O3 

1 937,50 16.79 

- 

Conditiono : Da}tiIe" Muakogee, OK 

z Kiln #1 Enha4st 

c Run #1 Imp 2 & 3 . 

: VoIume 250 Dilution 1//1 

Date : 03//24/2005 

Time : 09:54:54 

-1O2.4OOmV 1O24.O0OmV 

o Aroa Extmnal 

CnmPonent 

Fl- 

- Cl2 

_ 

~ 

~ 

' 

/l 

Number Retentinn Area Extermal Unita 

1 0'950 1016'20 M 12.03 ug/ml 

2 1,283 937.50 16'79 ug/ml 

~~ 
-1O2.4OOmV 1O24'0OOmV 

(unkmwn) O 

(un known) O 

D- O 

Cl- 1 

'Arou External 

27.90 N/A 

07.03 K N/A 

106.28 H 12.17 

Conditiona : DeltiIe ~ Muokogee ° OK 

: Kiln #1 Exhamst 

: Run #1 Imp 2 & 3 

c Volume 250 DiIution 1/1 

Date : 03/24//2005 

Timm : 10:02c04 

Component 

FlCl2 

Numbmr Retentiun 

l O'966 

2 1'300 

Ar*aa ExtmrnaI Unita 

1026'29 M 12.17 ug/ml 

1022.90 18.23 ug/ml 

2049'18 30'41 

0 ~ 

~ `~ 
-1O2.4OOmV 1O24.00DmV 

uom

-

~~ ~~ 

.- . .. .. 

~ 

(unknoNn) O 

(uknown) O 

Fl- 1 

C}- 1 

Aroa Exbnoa1 

0.0 MN 

25.40 N/A 

1245.60 H 16.21 

Conditions c DaItile, Mus,kogee, OK 

c KiIn #1 Exhaoot 

z Run #2 Imp 2 & 3 

. : Volu0*» 250 DiIution I/1 

Date : 03/24/2005 

Compunent 

FlCiNumbmr Retention 

1 l'00D 

2 1.350 

Aree Extermal Units 

1245.60 M 15.21 ug/mI 

1045'99 M 18.62 ug/ml 

K 

4~ ~ 

~~ 
Arma External Unito 

1286'62 15.78 Ug/ml~ 1 0 40 .88 1 8 .54 ug/ml 

2327-50 34-32 

ComPonent Number Retention 

Fl— 1 0.966 

Cl— 2 1'316 

FA 

Conditimna cDalti}e ° ,MuskuQee, OK 

~ Kiln #1 Enhaumt' 

: Run #2 Imp 2 & 3 

: Volume 250 DiIution 1/1 

Date 03/24/2005 

Time c 10c08z59 

—1O2.4OOmV 

Component Reten 

(uoknmwn) O. 

v 

(mkmwn) O. 

Fl- O. 

Cl- 1. 

)1G 

U61 

1O24.O0Omt 

Aroa External 

0'20 N/A 

34.45 N/A 

1286.62 15.78 
N/A 

15.77 

15.92 

(mknown) O 

Fl- 1 

Cl- 1 

32.80 

1285,YOH 

885.06 H 

Conditions Daltile °Huskogee, OK 

~ Kiln #1 Exhaust 

z Aun #3 Imp 2 & 3 

~ Vo}ume 25(} DiTutIon 1/1 

Dat+» : 03/24/2005 

Timw : 10c14:19 

-1O2.4DOmV 1O24'OODmV 

Compmnent 

FlClN 

Numbe+r Retentiwn 

1 1'O0D 

2 1.350 

Area ExtermaI Units 

1285.90 M 15.77 ug/0l 

885.85 M 15.92 ug/ml 

2171-75 31-69 

0D

° 

~ 
-1O2.400mV 1O24.0QOmV 

Compopont Rotontivn 

(oDkmwn) O 

F1- O 

Cl- 1 

Aroa External 

106.30 N/A 

124161 15.18 

902.68 16.21 

Area ExternaI Units 

1243'61 15.18 ug/ml 

902'58 16.21 ug/ml 

2146-19' 31-39 

Component 

' 

FlClNumber Re±ention 

1 0.966 

2 l'316 

2 

Conditions c Dalti}e, Muakogee, OK 

z KiIn #1 EXhaust 

: Run #3 Imp 2 & 3 

: Volume» 250 Dilution 1/1 

Date : 03/24/2005 

Time : 10:16:09 

~] ~ 
Comditions Dzxltile, Muskogwe, OK 

~ Ki}n #2 Emhaust 

~ Run #1 Imp 2 & 3 

: Vo]ume 250 DiIution 1/1 

Date z 03/24,/2005 

Time : 10:21c13 

-1O2.4OOmV 1O24.00OmV 

~ mmponeou Remn 

r (unknown) O. 

Fl- O, 

O- 1. 

tion .......... 

................ ** .... . ..... .......... ............... 

Aroa Exhnnal 

48.45 N/A 

1333.90 M 16.43 

Component 

FlClNumber Retentinn Ar*va External Units 

l 0.983 1333.90 M 16.43 ug/ml 

2 1.333 1221.52 M 21'35 uQ/ml 

'N' 

` 

~ ~J 
Compone nt ReteT 

(un kn ow n) `' 

\«nKV»w»/ O. 

(unkmwn> O. 

Fl- O. 

Cl- 1. 

Ar*u Extmnu1 

30.65 NW 

75.00 NW 

40.00 NN 

1394.10 M 17.37 

1276.15 N 22.14 

Conditioms ~ Daltile ° Muskogee, OK 

~ KiIn #2 Exhauet 

~ Hun #1 Imp 2 & 3 

c VoIuma 250 Dilutiun 1/1 

Date : 03/24/2005 

Time : 10:23:03 

-1O2.4O0mV 1024.O0OmV 

FlclComponent 

2 

Number Retentimn 

l 0.983 

2 l'333 

Area ExtermaI Unito 

1394.10 M 17.27 ug/ml 

1276.15 M 22.14 uA/ml 

2670-25 39-41 
—102.4OOmV 1024.00OmV 

component Retention ........................................... 

............. 

(Unhown) 0.6001 

Fl - 

................. . ...... 

................. 

............... ci- 1.3661 1 .................. 

Area External 

45.60 N/A 

1401.10 M 17,37 

1307.06 M 22.58 

Conditions z Daltile, Muskogee, OK 

z Kiln #2 Fxhaust 

: Run #2 Imp 2 & 3 

: Volume 250 Dilution 1/1 

Date : 03/24/2005 

Time : 10:28:12 

2 1, 

Component 

Flcl - 

ORP 

Number Retention 

1 1.016 

2 1.366 

Area External Units 

1401.10 M 17.37 ug/ml 

1:367.(36 M 22.58 ug/ml 

2708-16 39-95 

-1 ,-) rj 

J. u 
-1O2.400mV 1024.00OmV 

, _ ~ m~v~' ~ ~~ 

(unknowo) O 

hmkmmn\ O 

Fl- O 

Cl- 1 

Aroa Extmnal 

78.00 N/A 

22.40 N/A 

1489.81 K 18.99 

1272.67 H 22.09 

Conditiono : DaltiIe" MuskoQee, OK 

: Kiln #2 Exhaust 

; RUn #2 Imp 2 & 3 

: Volu0e 250 DilutIon 1/1 

Date : 03/24/2005 

Time : 10:30:03 

FlC}- 

Component Number Rmtention 

1 O'983 

2 1.333 

Aree ExtermaI Units 

1489.81 M 18.59 ug/m} 

1272,67 M, 22'09 ug/ml 

10 N

JLu ~ 
-102.4OOmV 1024.0OOmV 

.- . .. mm-

~~

. 

~ . ~m 

(unknown) O 

B- 1 

C}- 1 

43.90 NIA 

1640,20 M 20.64 

170.21 N 29,43 

Conditinns : DaltiIe, Muskogee, QK 

c Kiln #2 Exha4ot 

: Run #3 Imp 2 & 3 

~ Volume 250 DIlu±ion 1y1 

Date : 03/24/2005 

TIme : 10:35:03 

^ . 

Compnnent 

FlC ~

- 

2 

Number Retention 

1 1.000 

2 1.366 

Area External Units 

1840.20 M 20-54 ug/ml 

1782.21 M 29.43 ug/ml 

3422'41 49-97 

~ 

~U~~ 
Conditions t Daltile, Muskogee, OK 

Kiln #2 Exhaust 

Run #3 Imp 2 & 3 

Volume 250 Dilution 1/1 

Date = 03/2412005 

Time = 10:36:56 

—102.4OOmV 1024.00OmV 

Component Retention Area External 

(unknown) 0,300 , 

................... .......... ........... ............. ............. ............ . ..... .............. ........... 

79.90 N/A 

Fl- 0. 1 ......................... 

. ......... .... 1757.82 21.85 

ci- 1.350 

........... . ........ 

172E65 28.54 

21 

41

. ..... ; ~ 

............. . ............ ................. ...................... ...................... ................ ............. 

Component Number Retention Area External Units 

Fl— 1 0.983 1757.82 21.85 ug/ml 

ci— 2 1.350 1720.65 28.54 ug/ml 

2 3478-,48 50.39 

J 
Conditimma z Da}tiIe, Muokogf,e, OK 

: H2SO4 Blank 

Date : 03/'24/2005 

Time : 11:03:22 

-1D2.4O0mV 1024'0OOmV 

Aroa Extmnal 

Cmmpmn*nt Number Retentimn Area ExternaI Unito 

0 O-OO D-OD 

~ 

. 

j~ ~ v 
Conditionm : DaltiI*a °Muskogee, OK 

: 20 ug/ml Fl- in 82SO4 

: 20 uQ/ml Cl- in H2SO4 

Date ': 03/24/2005 

Time : 11:05c19 

-1O2'40OmV lO24.00OmV 

LI UII 

F1- O. 

Cl- 1. 

1649,15 20.64 

1086.70 19.31 

4 1 

" Component Number Retention Area 

~ Fl- 1 0.983 1649.15 

Cl- 2 1.300 1086'70 

ExtermaI Unito 

20'64 ug/ml 

19.31 ug/ml 

A^ ~ 
COnditioma c 5 ug/ml Cl— in NaOH 

Date : 03/24/2005 

Time : 11:16:07 

—1O2.40OmV 

Compunont Hotoobon 

1O24.00OmV 

Aroa External 

(VDkmwn) O. 801.50H Nt'A 

Cl- 1. 106.90 H 5,12 

Number Retention 

2 1.450 

Arma ExtermaI Units 

106.90 M 5'12 ug/ml 

106'90 5'12 
(unkmmn) 

Ci0, 1. 

Area Dtmnal 

08,00H N/A 

109.75 K 5.15 

Cmnditiono : 5 ug/ml CI- in NaOH 

Date» : 03/24/2005 

-102.4000V 1O24.00OmV 

Compo nent Number Retontion Area Extersal Units 

' 

Cl- 2 1.433 109.75 M 5.15 ug/ml 

1 109-75 5-15 

1 

jL ~ ~ 
Lm 

1O24.O0OmV 

CnnditioOs : 10 ug/ml Cl— in Na0H 

Date : 03/24/2005 

Time : 11:23:09 

—1O2.40OmV 

Comp000nt Roton 

(uokooNn) O. 

C}- 1, 

Area Extmna1 

695.85 N/A 

281.25 0.00 

Compmnent Number Retentimn Area External Wnits 

Cl— 2 1.483 281.25 10'00 ug/ml 

1 

-' I ~ ~~

~ 

~ 
Cnnditi'ona : 10 Vg/mI CI- in NaOH 

Date : 83/24y2005 

Time c11:25:52 

~ } -102-4OOmV 

.. .' ^~ m-

~o~~ ~~n 

r 

L8 (Unkmown) O. 

Cl- 1. i 

x1 

1024.000mV 

Aroa [ximnal 

715.90 N/A 

Component Number Retention Area Externel Unita 

Cl- 2 1'483 256'20 M 9.28 ug/mI 

1 256-20 9-28 

1i\ ~~ 
Conditimns : 15 ug/ml Cl— ln NaOH 

Datm : 03/24y2005 

Time+ : 11:29:25 

—lO2'4OOmV 

mmpopent ReLe 

(umkmmn) O 

Cl- 1 

1O24'OOOmV 

Aroa [xtornal 

_ Componmnt Number Retention Aree External Units 

"~ Cl— 2 1.566 454.00 15.{)0 ug/ml 

` 

1 

' 

454-00 15-00 

~{p 

~~~ 
l024.00OmV 

Conditimns : 15 4g/ml Cl— in NaUH 

Date : 

Ti0m c11:35:14 

—lO2-4OOmV 

----' Rete D tion 

(onknown) 0. 

O- 1. 

Airou External 

875,80 N/A 

451.00N 14.92 

52.9OH N/A 

Component Numbmr Retentimn Area External Unitm 

cl— 2 1.533 451'00 M 14,92 uQ/ml 

1 451'00 14'92 

JL ~ « 
N/A 

1.12 

17.24 

563.10 

\04.83M 

638.50H 

1024.00DmV 

Arou Edernal 

-1O2'4OOmV 

. ' . . .. mm~no~ n~o 

(unkmmn) 

Fl_ 

Cl' 

O 

~ 

1 

Conditimna : 20 ug/mI CI- in NaOH 

Date z 03/24/2005 

Time : 11:30:41 

CVmponent 

FlclNumber Retention 

1 1.150 

2 1.466 

Area ExternaI Units 

104.83 M 1'12 ug/ml 

638.50 M 17.24 ug/ml 

K 

~ ~ c~ 
Conditzons : 20 ug7ml Cl— in NatlN 

Date i 03/24f2005 

Time = 1 1 = 42. ~ 45 

-°102 . 4t7OmV 

Componenlu Re'Lention 

(iinknown) 0. 

F1- 1. 

C1- 1, 

1024 .C7OGmV 

Area External 

558.90 NlA 

96.38 M 1.03 

581.41 Pf 19.08 

Campanent 

F1-- 

ct2 

Number Retention 

1- 1.150 

2 1.453 

Area Extez- nal. Units 

96.38 M 1.03 ugJml 

581.41 M 19.08 ug/ml_ 

677.80 20 _ 12 

~ ~ ~ 
AMOtJNT IN.7ECTED 

AREA 0.000 

0.000 

609.955 

20.000 

1 

? 

3 

4 

5 

Caiibration file z CI- _0a1. 

Avg slope of curve= 30,50 

Y--axis intercept= 0.00 

Coeff of 1 i n rogr = 0.82 

No. Aroa Amount CF 

0= 0.000 0.000 0.000 

1- 108.325 5.000 21.665 

2= 268.725 10.000 26.873 

3= 454.060 15 . OOC7 30.271 

4 = 609.955 20.000 30.498 

~ `'': I 

~..~~ 
CVnditioma : DalitIe, MushoQee, QK 

z Kiln #2 Exhauat 

: Run #1 Impa 4 & 5 

: VoIume 250 DlIution 1/2 

Date c 03/24/2005 

Tima : 12:23:49 

—102.4OOmV 

componept Reten .m 

(unkoown) 0. UG 

C1' L 

lO24'O0O0V 

Aroa [xtornul 

178.90 NIA 

305.00 10.98 

Compnnent Number Retention Area External Units 

Cl— 2 1.486 305-00 10'98 ug/ml 

' 

1 

~ <~ / 
Cmnditioma : Dalitlm, Muohogee, OK 

: Kiln #1 ExhaUet 

: Flun #1 Impa 4 & 5 

: Volume 250 DiIutinn 1/2 

Oate z 03,/24/2005 

Time : 12:28:46 

-IO2.400mV 

Componont Rotontino 

(unkmmn) O. 

Cl- 1. 

IO24'OD0mV 

Arva Exbnna} 

182.80 N/A 

328.46 K 11.61 

CVmponent Mumbar Retention Area External Unita 

Cl- 2 1.466 328'45 M 11'61 uQ/mI 

1 328'45 11-61 

~~ w 
-1O2.4OOmV 1O24'000mV 

Componoot Retentioo 

(onknown) O 

C}- 1 

322.70 N/A 

490.00 H 16.16 

ConditIons z Da|itle" Muokogee ° OK 

7Kiln #1 Exhaust 

z Run #2 Zmpa 4 & 5 

- VoIume 250 niIution 1/2 

Date : 03/24/2005 

Time : 12:33z44 

Compowent Number Rmtention Area External Dnite 

Cl- 2 1.466 490.00 M 16.15 uQ/ml 

ki 490.00 16.15 

-f e 

~~~

~~ 
-1O2.4ODmV 1024.00OmV .-- ^ .. .. 

Aroa [xternal 

0. 

1, 

1. 

N/A 

N/A 

16.26 

(unkmmn) 

(mkoown) 

^' 

329.30 

53.00 

493.16 H 

CVnditimma : Dalitle, Mushmgee, QK 

: Kiln #1 Exhauat 

: Run #2 Zmpo 4 & 5 

: VoIume 250 DiIutimn 1/'2 

Dato c 03/24/2005 

Time z 12:38:47 

Component Number Retention Area Extermal Units 

Cl- 2 1.450 493-15 M 16'25 ug/mI 

1 493'15 16-25 

JLa u 
Cmnditloma : DalltIe, Muskngee, OK 

: Kiln #1 Exhauot 

: Run 43 Z0pa 4 & 5 ' 

r Volume 250 DilutiVn 1/2 

Date : 03/24/2005 

TIme : 22:44:02 

-102.4O0mV 

LI OD 

(un known) O. 

1. 

(mkmwn) 1. 

c { - 

' 

1, 

1024'0O0mV 

Aron Extmnal 

246.60 N/A 

178.61 1.91 

56.25 H/A 

507.30 H 16,71 

Component Number Rmtentimn Area External Units 

Fl- 1 1'016 178,61 1.91 ug/mI 

Cl- 2 1.450 507'30 M 16'71 uA/ml 

2 685.91 18-62 

~ ~ ~ ~- 
' Conditions : Dalitle, Muskogee, 0{ 

c Kiln #1 Exhebst 

~ c Run #3 Zmpo 4 -& S 

: Volumm 250 DIIuti(»n 1/2 

r Date : 03/24/2005 

'| Time 12:49:03 

-1O2.4O0mV 

. Component Raten 

` 

(un known) O. 

1. 

(mkmmn) 1. 

~~ 

' 

^^ 1. 

uio fl 

1O24'O0O0V 

Aroa Extmnal 

20.74N N/A 

195.92 H 2.10 

100.04 N K/A 

563.30 H 0.50 

CmmpVnent Number Retentic>n 

Fl- 1 1.000 

Cl- 2 1'450 

FA 

Area External Unita 

195.92 M 2'10 ug/ml 

563.30 M 18'50 ug/ml 

759-22 20'60 

~ ~~~ 
N/A 

2.27 

n/n 

17.56 

240.62 

211.68 

68.91 

B4.00H 

1O24.00OmV 

Arou External 

-1O2.40OmV 

_ t R eter 

 ' 

(un known) 

Fl- 

(unkmw8) 

CiO. 

L 

1. 

1. 

Conditiono : Dalitle, Muokogee" 0K 

: Kiln #2 Exhauot 

: RuD #1 Impa 4 & 5 

: Vwlume 250 Dilutlmn 1/2 

Date : 03/24/: ~005 

Timm : 12:54:13 

Component Number Retention Area External Unita 

Fl- 1 1'00O 211.58 2'27 ug/ml 

Cl- 2 1.450 534'00 M 17.56 ug/ml 

iN 745'58 19-83 

~~~ IS ~ 
1024'O0OmV 

Conditions DalitIe, Muskogee° DK 

~ Kiln #2 E%hauot 

: Run #1 Imps 4 & 5 

~ Volume 350 DilutIon 1/2 

Date : 03/24//2005 

Timm 12:59:18 

-102.4O0mV 

_ t _ t ' 

(Lin known) 0 

1 

(mknown) 1 ciAroa External 

2@.@ N/A 

196.25 2.1O 

65.35 N@ 

531.10 17.47 

Cmmponent Number Retention Area External Unita 

Fl- 1 1.016 196.25 2.10 ug/Unl 

Cl- 2 1.450 531'10 17.47 ug/ml 

~ 727-35 19-57 

~ J ~t 
Condltinma c DalitIe, Mushogme, 0K 

: Kiln #2 Exhauot 

: Run #2 Impa 4 & 5 

: VoTume* 250 Dilutimn 1/2 

Date : 03/24/2005 

Time r 13c04r32 

-lD2.4O0mV 

component Retention ^ 

~ 

(unknown) 0. 

Fl- \. 

Cl' 1. 

1O24.0DOmV 

Area Extornal 

250.40 H N/A 

235.97 N 2.53 

662,06 M 21`67 

Componmnt 

Fl- Cl-' 

Number Retention Area External Unito 

1 1'000 235'97 M. 2.53 ug/mT 

2 1'466 662.05 M 21.67 ug/ml 

K 

A-3 ~ 
-102.4OOmV 1024.00OmV 

(un n) 0. 

(unknown) O. 

Fl- 1. 

Cl- 1. 

Arou ExterUa} 

51.90 N/A 

254.39 N/A 

237.17 2.54 

700.70 M 22.91 

Cmnditiono : DalitIe, Muokogee, DK 

z Kiln #2 Exhauot 

~ Run #2 Impo 4 & 5 

~ Volume 250 Dilution 1/2 

Date : 03/'24/2005 

TIme : 13c09c37 

Component Numt`er Hetention Arwa External Units 

Fl- 1 1.000 237,17 2'54 ug/mI 

cl- 2 1.450 700.70 M 22.91 ug/ml 

N 

JL ^ D 
Condi-tiVns : Dalitle, Mushogee, OK 

: KiIn #2 Exhauet 

: Run #3 Impo 4 & 5 

z Volume 250 Dilutinn 1/2 

Date z 03//24/2005 

Time : 13:14:42 

-1O2,4O00V 1Q24.00DmV 

(0kmmn) 0.81 

Fl- 1, 

Cl- 1.46 

259.52N N/A 

253.67 N 2.71 

550.30 H 18.00, 

Compunent Number Retmntlmn Ar*a Extermal Unita 

Fl- 1 1.000 253.57 M 2.71 uQ/ml 

cl- 2 1.466 550'30 M 18.09 ug/ml 

F-P 803'87 20'80 

1 p r~ 

L~/ 
Aroa [xterna1 

(unkmwn\ O. 

F}- L 

Cl- 1. 

264,86 N/A 

Z3;.93 2.56 

540.90 

Area ExternaI Units 

238'93 2.56 ug/ml 

540'90 17'79 ug/m} 

779-83 26'34 

` Compnnent Number Retentlon 

Fl- 1 1.000 

Cl- 2 1,450 

FA 

Conditiono : Dalitlf*, Musko0ee, 0< 

: Kiln #2 Exhauot 

: Run #3 Impa 4 & 5 

c Volume 250 Dilution 1/2 

Date : 03~/24/2005 

Time : I3:19:52 

-102.4OOmV 1024'O00mV - 

~~~ 
Cond 4Ltions : Dalitle, Muskogee, OK 

: NaOH Blank 

Date z 03/24/2005 

Tirrie , 13-- 58:07 

102.400mV 

Component Retenti 

(unknown) 0.81 

(unknown) L 

1024.00OmV 

Area External 

1086.40 N/A 

450.55 NIA 

Component Number Retention Area External Units 

0 0-00 0.00 

A- 
-lO2.4OOmV 1024'OOOmV 

componont RetentioK___' 

(uokmmn) 0.81 

Cl- 1.4( 

Aroo [Xbnna} 

767.50 H/A 

Cnnditimns : DaIitTe, Muokogee, 0{ 

z 10 ugymI CI- in NaQH 

Da\te : 03/24/2005 

Time : 14:01:13 

N 

Component Number Retention Area Extermal Unita 

Cl- 2 1.466 304'02 10'95 ug/ml 

791 304'02 10-95 

40 
Appendix C 
I 

1 0 FlEi LD DATz-k 

PLANTT: Pw 

DATF-:.'71Z,, (l 

P,EPET!TiaN: I 

LOCATIOIN, (SOURCEF. ):,klllll fg 

OPERATOR: 4.:j— 

SAlv2LE TRAINT —5"' : f2f, INMTER BOX ~: 

BAROMETRIC PRESSURE: ZI ~ 

-Av_3lF__NTI` TElvfPERAT-07RE: p 5-- 

.ASSUNIF_D MOISTURE:, 

PROBE LENGTH: 

NOZZLE DLALMETER;z 

STACK DIAAI-ETER: 

METER H: 

C FACTOR: 

METER CO-EFFICIENT: 7 

FILTER TARE: 

PRE-TEST LEAK CHECJ~._ Meter.0, 65 cu.ft. @ in. HG 

pitntr i no 7 i in R?n 

i-iiitial F ; ria! 

16 0 

_2 f zz, 

=4 1 /, 00 /., XZ, 

'5 

~

6 

CO2 02 

POST-TEST LE-4-K CHE

Meter: 6 l'o-LIl, cuf t. @ irn' : HG 

Pifnf ~ : y,✓ 0. in- R20- 

t 

FF as 

I~ :~ 2~r 1,5-3 TU I 1 .61 

-~ 

2 1,~ L 1 6z-- I 

F, 

1 1'/, Vr, V7. 3 17T 1 -7 6-0 

/ 

C) 

~

- 7- 2_7 

_?o 

1 11 1,40. k I 17q ks ~ 16q- I 

1 1,6q l Ae l,j 1 -2 

7j J;Z' 7— 1 1 &ir- 

-3 

r2< ~ I o 

171 1(b I o/ 

0 ( 1-5- ~53 1,13 51 J/, 2- JiV7, ~z- I ~J—j?" s - 1 16 ~ 

Y~ _P l 
_" " 

" 

PLANT: ///4 

DATEE: cylitr~~5_ 

REPETITION: 

-0 CATION (S 0 UR C k// 

OPERATOR: dZ-3— 

S AM-PLE TRAIN, 

IvMTER BOX 

BAROMETRIC PRE8SURE:Z, ~j, 

ANMIENT TEMPE RATTi-PE: '7 0 

ASSUTNED MOISTURE:. '7' 

PROBE LENGTH: 5 0 " 

NOZZLE I)LkMETER: o-963-7 

STACK DIAMETER:_3 j 

METER H: ~' 

C FACTOR:, 9~ 

METER CO-EFFICIENT:, ~7.t/ 

FILTEA TARE: 

PRE-TEST LEAK CHECK 

Meter: c7- cu.ft. @ 1 ,9 in. HG 

Pitots: in. H20 

FIELD DATA 

!MPTINGERS 

I ui~ al `al Fillal 

k 

1 03 

,41 > l"L)l-v)'j-(5"" 00 

C90 

CO2 02 

q /t/l 

POST-TEST LE-A-K CHECK 

Meter: Cu.ft. in. HG 

Pitots: (&, 1& ~

' 

7 in.H20- 

D'It 

cu., 't - I _ ~ ' I iniet - . - I utli J~C:JJL' 

Tcmp 1~ ldi 

I n ; 3z:> 1 157 1:19- 1, 219 1 1 88 7 7, g(D 15,? - 2 Z~6 Y_ - 

15T3 1 1 . I /, 3,, Ev, 3 1 ,77 IV' IM' 16/1 1.3 

1 1 - 1,3 1a93 1 To 9Y I W'/' V-3 1 

6s 

q5- 1 1 jz- I I lz,~ Ic J I z, ~ 

12j"I C-( I 

77- -7 7K, 

I -Z- I I -es- 11j ljo' I I ZT3 1~q I 

_-L 15-5-?-1 1 1 2- J . ;,-) 1 7 0 1 -6' 1 

L 

~~ I 

OX I /1_1- KC ' I I 61' C 

176 . 1 

Z---' 1-3 

L3 

5,22j' -------- 
;W 

FIE' LD D ATA, 

PLANTT: 

A D A TE: 

REPETITION:_3 

(SOURCE RS 

OPERAi OR 65~~l alitip! `-7inal 

SA.NPLE TP—AIN. 

NETERBOX#: 

BAROME'TRIC PRESSURE: 2-7, 4/ 

Q 

. lao _kV31 ENIT TE1,2BRATURE: 7 5' 

ASSU JNMD MOISTb-RE: 5 T5 

PROBELENGTH: 

NOZZLEDLA.METER: 0 30V 

STALCK DLAMETER: 97, 3 3~ 

KETER H: CO2 02 

C FACTOR: 

METER CO-EFFICIENT: 

Fft,TER TARE: 

PRE—TEST LEA-K CHECK POST-TEST LEA-K CHEC 

Meter: 6 cuft @ /,~' in. HG Meter: 0,b7 cu.ft. irn. HG 

Pitots: r&.X'_57' in. H20 Pitots ' '&, .r'L/ in. k20. 

e-'- u 

ley 

_c; 

Temp T,mp 

1~%o- I I 

L 15-9z 1,3_ 

IT 7 

I ql 1 .11, q 13 z3,t I ~ - I I L~O' ~ 

'10 ~z- _~_l 

C) 5_/ 

LY El 

zx~ 1-5.Tz- 1 , Z, - s—I * I 1 Vr I 16 - v 

z6K 9 1 12-0, 1 6s 1 

3 6 

- - 1339-,o q( k 15- 5 1 12-1 

L 1 - kv, ~ 1 ,5)- 1 lz-yi I 

F I" q I I'/ v 1'71 1 2-,~~ ~2— 

11,13 _Vv- 1 1 Y13Z k6b 

1 13 6 1,37 1 X 3 3. 

15~ 1,35- 1 Z, ~n I6 s 1 

• --~_ 1 7 - 1 sa - 7 —) 

1-7 C6_ 1 

4;v 

2- z, ~ L/ 1 

Y , 

z- P-f--~ 794 - 11 1 1 

o! - j 
-2,1 2- , L 

TlT _2_ 

02 

/2. n 

-TEST LEA-K CHECK 

/9- .'06 b cu.ft. @A0 in. HG 

n, z_•-_!., i,,- i42o, 

~, -i fj_e PLAI\TT: feOLt:11- i 

E),ZTE: 

REPETITION, : 

LOCATIONT (SOURCE=): 1—i 

OPERATOR:'~ /t 

SAYPLE TRAJN, 

MSTER BOX t 2— 

BAROM-ETRIC PRESSURE: 

AlABIENT TEMTERATTJJRE: (o 

ASSU-NIED MOISTTiRE: 

PROBE LENGTH: 

NOZZLE DIAMETER: 

STACK DLA-METER: 2`7 )/ 

ATETER H: _71U2_ 

C FACTOR.: 

METER CO-EFFICIENT: 

FILTER TARE: 

PRE-TEST-LEA,K CHECK 

MeLer: D OeO cuft 

 @6 t

g Ill. IfG 

Pitot ,z • lof n 4 in T4?n 

1MMIN. -GE, RS 

Tiiitial 

1, CP a 

:L, 3 

5 

-6 Z--,o 

CO2 

3,0 

e, " FIELD DAT.k 

po 

Dc~ Vri~ 

l' fii Mp 

71 2 c - n 

s Z~~_ e/o 7 

2i , z3 ~ 7. 7"j - 

2, ~p 7q ~ 2-_ Z,- 

1, 2.1 DyZ o 1 1 2- -5- 0 1 1 7.: 0 1 

2 6 7 7--p 

VP 2-'~6 1 1 '231 Z*5-0 G7 7,o 

2­9 1 2-,Vp, 3. L151 ~~ 1 2- (V,61 1 7,- -o 

1: 1 .1 "0 2,6-0 , v 6 1 -,,,J- f —7 5-9' 6 J z'_ 1 7, -o 

-o 

2-./ 2-6-9. J 221 7 ✓ 1 7Z / I s- a , T) 

L~;Z , -2 6 

(P9, '601 Z5-9, fl 1 5'1-- 1 Z; -7, 

1 2, Ja7 1 

2- , 

V2_1 I .~j 1 1 1 2, 2- 1 U 7~ I ,;~o 1 2s-,~ j 6 1 -;? - 

5: 1 S31 I 2,L 1 6 1 1 9 1 2,1? 1 67 1 

10 

7 , 

136 y 1 .2-6- 1 1 1 1 1 9 1 1 Z ~-( 71 1 

3, ~O 

7 Y2-,, 12- ~ A 1 2 -0 1 

6-t 0 1 - S-) 4S 2`Q 

 -0 _ZA~ 2- 0 

2-1 `oj 'e' 1 2- ~--ej (L,_G 1. 2- _rD 
FlEi LD DATA 

PLANT: 

rDATE: 

REPETITION: T= 

LOCATIO?~ (SOI RCE -): ( ` J ~ ~~ ~ IMI'A `t`GERS 

OPBRATOR: ~ ~ Initial Final 

SAMPLE TRATN ~=: 

METER B OX y: ( Z :Y2 te~~~ 

B AROMETRIC PRESSURE: Z7 •`( 

AIdII3IENT 1EM1'ERATURE: ~ ~' 14 

.ASSU`IvIED MOISTTi-RE: pqo 

PROBE LENGTH: 2- r6 

NOZZLE DTrA.METER: . 3~ 2~7 2'~ u' o 

STACK DIAMETER: 

METER H: G,7Q Z CO2 02 

C FACTOR: 

METER CO-EFFICIENT: 0 ` ~ °~ ✓ 

FILTER TARE: 

PRE-TEST LEAK CHEC j POST-TEST LEAK CHECK 

Meter:p . o t5_ cu.ft. in. HG Meter: .F.~' r 0t,T Z.ft. @',;? in. F3G 

Pitotz. n 6'Z,in. H20 Pitots:i5 in. H20 

! ~~` r { 

ces F' 

t~ ~ ~ .`? V I . ti ti ~.~f ~ 

~ 

r ~V 

n~ ie F ~ Gi.,F_ 

, ...."9~..e• ✓~ ~ ~~ ~ ~ ~~~ : 

ni c ~_~~ cut[e. ,t ~ -- Temo_ 

~ ~ 3 7 ~ L-^ ! L f V 

G 7 

I2 i ~ F ci GSZ 

! 1 s~6~ Is--r_ i z,?1,(, ;( I gs-I z6 31 6,vr I C~•~- 

! ~ ! .'qO 517 2. 3 p 9, 57! zs-~l 

cl' 

~2q 

2 ,3 ( 36ar ~-~i .i~l ( Gg~ .~s~ ~ ~ ! y, S

~ 

s-1 ! z ~~~z~ i I ~y !~i Z~-~ 6~ !Y-5- 

5S7 ~ S`3 ! ~ ~ ~t ~~,r'- 

T i I_ I rr ,- 1 oa 

vy -('r f- I ~-7 1 -z'~ 

~ Ilr~+~~~; ~~ i~~< I Y ~ I I~~s 1~~~: i~ ~ 1 aP7 I a IG~ ~}~ 

I ~ ~s~_I Y ~ y I I .~ f ~ ! ~ /1 ~ I °s- 

{ r07 I 55 5 1 ~t~,.l1 { ~-~ I 3l ~ • 71 ~'y 1 99 { ~~ 3{ ~~ ( .~~o 

y I I 4 ~~~ ! ~ ~~ ! z . z ! ~ r6 ~_! ~ s 

1~s~ ! ~ ~~3 ~ ! ~ z ! ~ ) g r ~ I 931 ~~ ! ~~ ~ I ~~ { 

~ ' ~ I 

! 7 I ~~~ zZ ~~~ ~ ~G I fs~ I ~ ~ I~ O 

Z?~~• 

~ 6, { ~ 2~ 

~I ~ <{ , ~~-I { ~s-oI ~~~r~l ~~-I ~~I zs~! 6(0; 

~~~ ~ ?-{ ~~ { . 7 i ~~ ! 2 ~ 

IFP ~I I ~ ~.~I ~ 1 0 1 1 ~~r / 1 3~ , %I ~ z-I ?F I ~S~~I ~ ~ 1 :~- - ~ 

~~l~ a~ 1 

~e~•~ . I ~ I I I I 1 ~'~~ ( I I ~ I~`-~ ~~- 
FIELD DATA 

P L A IN T: R" 

REPEETITION: .1 

LOCATIONT (SOURCE=) 

OPERAI' OR- . _v_14 

SA2v~1?LE TR_AJN 

METERBOX#: 

BAROMETRIC PRESSURE:2-9 

_AlvmIENT -ITEIMPERATURE: 7? 

ASSU-NED MOISTU-RE: 9 

PROBELENGTH: -/2- 

NOZZLE DLAMETER: t ~ 02_7 

STACKDIAMETER: 

METER H: / , 7 0 

C FACTOR: q 

METER CO-EFFICIENT: 

FILTF-R TARE: 

PRE-TEST LEAK CHECK 

Meter: 0 ~ 06>9~c—uft.@/6-in.HG 

Pitots: 0 1420 

RS 

initial Final 

42 ;> 

,3 

44 

41 6 .5(, 

CO2 02 

-3,0 17.0 

POST-TEST LEAK CHECK 

Meter: l lcu.ft. @ t"O iii. HG 

Pitots: ~-- • 0, in. i120. 

/0T - - 1 1 q-1 S? 572~_ 1- Z y 3ep, 87 3-7 72-. s s- 7 o: 

~.~ f z y 6 7 46 

Z, 7 S i 8d;_ L-V(J l9 -7 Y f 

to 2, 31 334519, 2_1 .91. gJ_. 1 25-11 1 

sc: Z-5 

2­01 5 ~ z J': 8G zcl I 

- , I -S q,7 I 92- V 

2'a 

7 , 87 
Appendix D 
IZ31 

ai 

E 

O 

O N 

c? 

. 

+ 

tm 

ca 

O > 

cu 

2 

co 

> 

7i 

co 

~ 

0 -Q 

I Cc 

0 

5 

0 

co c4 

C) "a 

LL 

0 co 

kTA 

"ZiE 

O 

O 

E 

C14 

C? 

co 

'6 > 

co 03 co E 

o 

,2 > 

2 -_a 

co –0 

LL

C) 

a) 

O 

(D 

w, ~ = P 

ff o0 

co 11) m 

co c') m 'd 0 co co co co .0 

LL 

t2 m (1) 

C.4 oo Lo m tn u-, 

z o C) 0 0 

-o 

(D < 

~ .. !Z 

(t: 0) 11 It 11 

ui = 

q C') U~ ci in 

co co co (M 0 

> E E z E= > 0 E (D 

6c)--NUJ 

0 E E 0= O:s 

n q 

co co OC) co co oi 

82 

411), > --6 n; ;~ ~; ~; u-, 

< 

i 0 

WNI 

M .0 .0 co 00 U5 m m Z to 

CL cco co co co co 

E E 

tm 

(D 

co co co 00 00 

E LO LO tO LO LO 

< 

0

Of 

U) E Lq q < C— C14 U') co Lo 

(D Co U- 0 0 m 

0 z < z 

a 

< > 0 

0 

M 

lx 

^y " 

> 

F, 

< 

CN co LLI 0 Ci 7 U? CR 0 E 6777 LQ 7 

E LL 

0 0 — — — — — 

0 Za 

: 

: 

< o C,4 

C) .2 M: 

0 0 a) 

> 

Co 

-j 

^o M LO (D Lf) (D ti 

E CO 

C) 

of m cl (0 ci 0 0) C4 LO 

co co co cn 0) 

EO U) m U) U') 

ui 

C~ C) 0 a 

C) o 0 

0 

< ID 9 C? a E C) ui 

I 

Z > 

cz 0 

0) E 0 

'o < 0 C) co CS) 

ca 

Q) m 0 C) 

w U) 0 m o < ^ CD 0) 0) 0) (;~ 

:sc) a) cs 6 6 0 

E 75 IL E < 7a 

> 

E 0 0 0 0 

c A I co co 00 co cn 0 0 0 U*) 0 0 

Co E 0 

LU x 

cz cq c: 

mn 0 o LU E c c c c LU C-4 -0 0— .0 Ln 0 2 'm 0 ~5 --c' :; 

co co 0) a) 0 Ul) LO LO 0 0 

< 

z 4D X : I z -,T cq w 

E 0 10 0 0 

< < 

ui > z 

ui il. . 0 4) 6 

a_ < LU 

~7 2 

i . 

: ~S 

Q: 

E -6— 

ui C) CD 0 C~ c~ 0 

N IL E E 

F- 

= = 0 CO M to 

c; .6 

LU 

X 'z~ 8 

U') c 

4i o ~E 2 0 E LU — — :) 

U) ui -j ft0 

00 

LU m ca 

> 

2 

to 

ui () 

FL > 

< 

(D E 0 LU m m m O~ C'l 

(D 0 m 

5 Lu 0 V m m 

< 4 4 4 cl~ Cd 

ID 

0 

> 0) 0 cl) O)o 

> 00 0 

> 

m= c 0 0 0 0 0 

0 U) co 0) 

o — 0 LU 

co 

cl) 0 O C) 0 ui w^ N "I c'! LQ 1-: 0 0 0 to w 0 0 (D 0 

ID (Ii c; C6 (6 r-: 

E 

w cr 

0 

~: 0 0 E LL U) > C) > 

< LO (1) 0 C, 

Cl! U~ O~ (R q 

< (D u ~- :a 

0 .0 n n M Fx Cf 00 C) CD — C, 

8 

)- 

X 

2 W =0 M 

<r 00 

D -i -,~i "i 06 

0 0 0- 0- D Of > 

00 

SO 
Temperature Wieter Cafibrations 

iti/eter Box #. 11 

Date: 03J03J05 

Cafibrated By: RT 

Emtech Thermo 

Degrees F Checker Probe Stack Oven Exit Auxil ary 

Point 1 32 29 30 29 30 30 

Point 2 212 210 210 210 210 211 

Point 3 752 750 751 750 751 751 

Emtech Thermo 

Degrees it Checker Probe Stack Oven Exit Auxiliary 

Point 1 492 489 490 489 490 490 

Point 2 672 670 670 670 670 671 

Point 3 1212 1210 1211 1210 1211 1211 

Percent Difference 

Probe Stack Oven Exit AuxifEary 

Poini 1 0.609756 0.406504 0.609756 0.406504 0.406504 

Point 2 0.297619 0.297619 0.297619 0.297619 0.14881 

Point 3 0.165017 0.082508 0.165017 0.082508 0.082508 

~vl~ 
~ 

2 

~ 

d 

~ 

c~ 

i 

~ 

~ 

i 

\ 

.\ 

\ 

~V~ 

\ SI` 

`o ~ @ 

E 

0 

0 

O N 

to p 

m + 

m m y ~ N_ 

E 

to ~ @ o- ~ 

m E m ar 04 @ y 

y = ~ 

Y o s ;o 

y C N 

E c ~ 

00 

a : 

Y CO _ \ 

o > 

m 

~ E 

`o L -~ 

o ~ : 

} 

p O 

 2 _@n` Z W L m 

O U' 

! U C •', • 

c @' 

c N ~ N . 

, O ~ _ p ~ .,s U 

O @ @ - w 

o 

N 

 z 

:2 m y a 2 

'a :3 .°_ cca U) 

O 

o a) O co 

U. U O O 

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O 

i, 

u 

N 

O 

~ 

T 

m 

co 

m 

0 

n 1 

1 

I 

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~ 

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(D 

0) 

i 

(D 

> 

Q 

~ ~i 

W 

O 

~ O O n N G tt) O O O O 

Q f+M9 M ~ M co 

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Temperature Meter Calibrations 

Nfeter Box #: 12 

Date: 03/23/05 

Calibrated By: RT 

Emtech Thermo 

Degrees F Checker Probe Stack Oven Exit Auxillary 

Point 1 32 31 31 31 31 31 

Point 2 212 212 212 212 212 212 

Point 3 752 755 755 755 755 755 

Emtech Thermo 

Degrees R Checker Probe Stack Oven Exit Auxiliary 

Point 1 492 491 491 491 491 491 

Point 2 672 672 672 672 672 672 

Point 3 1212 1215 1215 1215 1215 1215 

Percent Difference 

Probe Stack Oven Exit Auxillary 

Point 1 0.203252 0.203252 0.203252 0.203252 0.203252 

Point 2 0 0 0 0 0 

Point 3 0.246914 0.246914 0.246914 0.246914 0.246914 

~.62 
Bar.ometer. CaIilirations . 

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