A 11 ID 2 1457m

NATL INST OF STANDARDS & TECH R.I.C.

All 1021 45709

/NSRDS-NBS

QC100 .U573 V59;1977 C.1 NBS-PUB-C 1964 O

V

1*

«o \ ^P> /

NSRDS-NBS 59

^fAU 0*

U.S. DEPARTMENT OF COMMERCE /

National Bureau of Standards

NSRDS

Selected

Specific Rates of Reactions

of Transients from Water

in Aqueous Solution.

III. Hydroxyl Radical

and Perhydroxyl Radical

and Their Radical Ions
NATIONAL BUREAU OF STANDARDS

The National Bureau of Standards 1 was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation’s science and technology

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$<—

\DD

exO,

^

yxnh

c V

Selected Specific Rates of

Reactions of Transients from Water

in Aqueous Solution.

III. Hydroxyl Radical and Perhydroxyl Radical

and Their Radical Ions

Farhataziz and Alberta B. Ross

Radiation Chemistry Data Center,

Radiation Laboratory,

University of Notre Dame,

Notre Dame, Indiana 46556

NSRDSt n

U.S. DEPARTMENT OF COMMERCE, Elliot L. Richardson, Secretary

Edward 0. Vetter, Under Secretary

Dr. Betsy Ancker-Johnson, Assistant Secretary for Science and Technology

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting Director

» > v Issued January 1977
Library of Congress Cataloging in Publication Data

Anbar, Michael.

Selected specific rates of reaction of transients from water in aqueous solution.

(National standard reference data series, NSRDS-NBS 43, 51, 59) “CODEN: NSRDAP.”

Includes bibliographical references. CONTENTS: 1. Hydrated election. —2. Hydrogen atom.

3. Hydroxyl radical and perhydroxyl radical and their radical ions. Supt. of Docs, no.: C 13.48:59

1. Water. 2. Radiation chemistry. I. Bambenek, Mark, joint author.

II. Ross, Alberta, joint author. III. Farhataziz, joint author. IV. Title. V. Series: United States. National Bureau of Standards. National stan- dard reference data series, NSRDS-NBS 43. [etc.] QC100.U573 no. 43 [QD651.W3] 389'.6’08s [546’.22] 72-600064

NSRDS-NBS 59

Nat. Stand. Ref. Data Ser.,Nat. Bur. Stand. (U.S.), 59, 122 pages (Jan. 1977)

CODEN: NSRDAP

(g) 1977 by the Secretary of Commerce on Behalf of the United States Government

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Foreword

The National Standard Reference Data System provides access to the quantitative data of physical science, critically evaluated and compiled for convenience and readily accessible through a

variety of distribution channels. The System was established in 1963 by action of the President’s

Office of Science and Technology and the Federal Council for Science and Technology, and

responsibility to administer it was assigned to the National Bureau of Standards.

NSRDS receives advice and planning assistance from a Review Committee of the National

Research Council of the National Academy of Sciences-National Academy of Engineering. A number of Advisory Panels, each concerned with a single technical area, meet regularly to examine

major portions of the program, assign relative priorities, and identify specific key problems in

need of further attention. For selected specific topics, the Advisory Panels sponsor subpanels

which make detailed studies of users’ needs, the present state of knowledge, and existing data re- sources as a basis for recommending one or more data compilation activities. This assembly of

advisory services contributes greatly to the guidance of NSRDS activities. The System now includes a complex of data centers and other activities in academic insti- tutions and other laboratories. Components of the NSRDS produce compilations of critically

evaluated data, reviews of the state of quantitative knowledge in specialized areas, and computations of useful functions derived from standard reference data. The centers and projects also

establish criteria for evaluation and compilation of data and recommend improvements in ex- perimental techniques. They are normally associated with research in the relevant field. The technical scope of NSRDS is indicated by the categories of projects active or being

planned: nuclear properties, atomic and molecular properties, solid state properties, thermodynamic and transport properties, chemical kinetics, and colloid and surface properties.

Reliable data on the properties of matter and materials are a major foundation of scientific and technical progress. Such important activities as basic scientific research, industrial quality control, development of new materials for building and other technologies, measuring and correcting

environmental pollution depend on quality reference data. In NSRDS, the Bureau’s responsibility

to support American science, industry, and commerce is vitally fulfilled.

Ernest Ambler, Acting Director

III
Preface

This report is one of a series of data publications on radiation chemistry; the aim of the series

is to compile, evaluate, and present the numerical results on processes occurring in systems which

have been subjected to ionizing radiation. Various kinds of data are important in radiation chemistry. The quantities which were measured first were the observed radiation yields or G values (molecules formed or destroyed per 100 eV). Various indirect methods based on G values have been used to determine yields of transient species and relative rates of reactions. The spectral properties (optical,

electron spin resonance) of transients have provided a direct method for their identification, and rates of the very fast reactions of transients which occur in irradiated systems have been measured directly

by spectroscopic methods. Conductivity and luminescence methods have also provided a means of

measuring properties of transients and their kinetics. Some reactions which occur in irradiated systems

have also been studied by other methods, such as photochemistry, electric discharge, ultrasonics, chemical initiation, electron impact, etc. The emphasis in these publications is on the data of radiation

chemistry, but where other pertinent data exist, they are included.

The data of radiation chemistry are voluminous; thousands of systems have been investigated.

As a result there are certain collections, e.g. rate constants of particular types of reactions or certain

properties of transients, for which tabulations of the data are considered essential, but for which

critical assessment of each value is impossible. On the other hand, certain systems and properties

have been studied so extensively that critical examination of these data is desirable and timely.

Authors of this series of data publications have been asked to evaluate the extent to which the data can be critically assessed, to describe their criteria for evaluation, and to designate preferred values

whenever possible.

IV
Contents

Page Foreword Ill Preface IV

Introduction 1 Table 1. Values of A used for normalizing relative rates 4

Table 2. Reactions of OH with transients from water (3. 1-3.7) 5

Table 3. Reactions of OH with inorganic solutes (3.8-3.122) 7

Table 4. Reactions of OH with organic solutes (3.123-3.758) 22

Table 5. Reactions of O

- with water, transients from water, inorganic solutes, and organic

solutes (4.1—4.121) 68

Table 6. Reactions of H0‘2(0^) with transients from water, inorganic solutes and organic

solutes (5.1—5.65) 78

Formula index 87

References 100

V

Selected Specific Rates of Reactions of Transients from

Water in Aqueous Solution. III. Hydroxyl

Radical and Perhydroxyl Radical and their Radical Ions

Farhataziz and Alberta B. Ross

Radiation Chemistry Data Center, Radiation Laboratory*,

University of Notre Dame,

Notre Dame , IN 46556

Rates of reactions of OH and H02 with organic and inorganic molecules, ions and transients in aqueous solution have been tabulated, as well as the rates for the corresponding radical ions in aqueous

solution (0

_ and 0;r). Most of the rates have been obtained by radiation chemistry methods, both pulsed

and steady-state; data from photochemistry and thermal methods are also included. Rates for over one

thousand reactions are listed.

Key words: Aqueous solution; chemical kinetics; data compilation; hydroxyl radical; oxide radical ion; perhydroxyl radical; radiation chemistry; rates; superoxide ion.

1. Introduction

The short-lived products of water radiolysis for low LET radiation (cobalt-60 gamma rays, X-rays,

and electrons with energies of about 30 keV and above) are e~q

, H and OH. In the presence of oxygen,

hydrated electrons and hydrogen atoms are converted to other short-lived species, 0 2 and H02. The

pAf^s of OH and H02 are 11.9 (65-0386, 66-0424) and 4.88 (70-0304), respectively; i.e., 0~ and 02 can be

produced from the equilibria:

OH ^ H+ + 0-

H02 ^ H+ + 02-

Thus, by adjusting only pH and the concentration of 02 in water, one can produce e~q

, H, OH, H02 , 0 2 and 0~. All of these species have been characterized and their reactions with hundreds of inorganic and

organic compounds have been studied. In the previous compilations, NSRDS-NBS 43 and Supplement

(73-0030, 75-0002) and NSRDS-NBS 51 (75-0001), the specific rate constants for e~

q and H have been

collected. The present compilation is an extension of the series and covers the specific rates for the

reactions of OH, H02 , O' , and 02

. The literature is covered up to the latter part of 1975.

Methods

The majority of the data in this compilation are from investigations in radiation chemistry. However,

data from photochemistry, Fenton's reaction, and other methods are also included. The rate constants of

short-lived species are measured by* steady-state and pulse techniques. The steady-state investigations

yield ratios of rate constants which are deduced from an assumed mechanism. Values of specific rates

*The Radiation Laboratory is operated under contract with The Energy Research and Development Administration. The work of the Center is supported jointly by The National Bureau of Standards, Office of Standard Reference Data and The Energy

Research and Development Administration. This is ERDA Document COO-38-816.

1
from steady-state investigations may be as accurate as those measured by other methods. However, in

many cases, the mechanisms are complex and the values measured with steady-state techniques must

be accepted with caution. By pulse techniques, it is possible to study a reaction directly if one can

either measure disappearance of a reactant (decay kinetics, d.k.) or formation of a product {product

buildup kinetics, p.b.k.) during the course of a reaction by methods such as optical spectroscopy,

electrical conductivity, etc. Unfortunately, due to experimental difficulties, such investigations are

possible for only a few of the reactions compiled in these tables. The specific rates for other reactions

have been measured by competition kinetics (c.k.) using pulse techniques.

In the present compilation an attempt was made to be as comprehensive as possible and include

measurements of the rates of the same reaction by various methods, as well as measurements by the

same method by different authors; values superseded by later measurements by the same authors have

been omitted. Certain relative values are omitted if the standard reactions were not well characterized or

if the relative values were in wide disagreement with values measured by several other methods.

Examples of such data are those which have been obtained using the decolorization of organic dyes by

OH or the oxidation of hydroxylaminedisulfonate ion by OH as the standard reactions.

Extended sections on radiation chemical, photochemical and chemical methods of generating OH

and O

-

, and on the methods for rate determination, and the mechanisms for the reactions are found in

NSRDS-NBS 46 (73-0299). The reader is also referred to that review for an analysis of complications

which may occur in various systems.

Arrangement of Tables

In order to provide for internal consistency in the tables, values for rates of a number of competing

reactions have been chosen to convert the rate ratios into relative rates. Those values are listed in table

1 and have been taken, whenever possible, from the review of Dorfman and Adams, NSRDS-NBS 46

(73-0299), where a critical analysis of the hydroxyl radical rate data has been made and "most reliable

values" selected for a number of reactions; some of the values have been taken from an earlier paper on

standardization of OH rate data by Willson, Greenstock, Adams, Wageman and Dorfman (71-0578).

Many of the values chosen are the most recent directly determined rates; the references to those

determinations are cited in the last column of table 1. Reactions of OH with other transient species from water are listed in table 2. The reactions of

inorganic solutes with OH are listed in table 3 in alphabetical order by main element. The reactions of

organic solutes with OH are listed in table 4 in alphabetical order by name. In most cases IUPAC

nomenclature has been used. The reactions of O” and H02 (02 ~) are listed by the same arrangement in

tables 5 and 6, respectively.

The format of the tables is similar to previous parts of this series. Reactions are included in column

2 when products or mechanism have been studied. When several reactions are given, the reactions are

labelled (I), (II), etc. and the rates in columns 4 and 5 are labelled (I), (II), kx , kn , etc.; if the rate in

column 4 or 5 is not so labelled the value represents the sum of the rates for all contributing reactions.

Reactions are second order and the rates have the units dm3 mol_1 s

_1 unless otherwise specified in the

tables. Values for radical combination and disproportionation rates (entries 3.3, 4.5, 5.4 and 5.35) are for

k (and not 2k as usually determined) unless it was not clear which was reported, in which case the value

is the one given by the authors. Values of k which have been directly measured are given with the error

limits as reported by the authors. The ratios of rate constants in the Ratio column are given in the form

k/kx where kx symbolizes the rate of the competing reaction of the same short-lived species with X. In the Comments column ratios may be given as k/kx or kx

/ky where k, kx , and ky are rates of the same

short-lived species with the reactant in column 2, X, and Y, respectively. For some of the entries only a

ratio is given, but in most cases relative rates have been calculated from the ratios and are listed under

the k column. The values of k obtained from ratios are designated as relative (rel.) and have been

calculated by using the rates in table 1 (or, in a few cases, using a rate given under Comments). At the

end of each entry for solutes which have been used in competition studies a list of entry numbers is given in which ratios involving that solute are reported.

Columns are included identifying the source of the radical and the method of measurement; other

2
information is given under Comments, such as activation energy, frequency factor, equilibrium constant,

deuterium isotope effect (k H /kD ). Temperature is 20-25°C, or assumed to be at room temperature, unless

otherwise specified.

Abbreviations which have been used are tabulated at the end of this section. References are designated by number as assigned by the Radiation Chemistry Data Center; the first two digits of the

number specify the year. The references are given at the end of the tables. A formula index for the

solutes refers to entry numbers in the various tables and includes references to the tables of e~

q and H

reactions already published.

Abbreviations and Symbols

A

abs.

abstr. acac

ala

anal.

approx.

(3-t.

bicarb

biol. bisulf

BzOcalcd.

carb

chem.

c. k. concn.

condy.

cor. cyst

d. k. detd.

eEDTA

en

e-r.

esr

est. Et

EtOH

Fenton

ferro

formn.

f.phot.

G

y-r.

gly

hydr

3HX

frequency factor

absorption

abstraction

acetylacetone

alanine

analysis

approximate

beta radiolysis

bicarbonate ion

biological

bisulfate ion

benzoate ion

calculated

carbonate ion

chemical analysis

competition kinetics

concentration

electrical conductivity

corrected

Cysteamine

decay kinetics

determined

activation energy

extinction coefficient (in cm2 mol_1 or M-1 cm-1

) ethylenediaminetetraacetate

ethylenediamine

electron radiolysis esr spectroscopy

estimated

ethyl

ethanol

Fenton's reaction (Fe 2+ + H2 02 ) ferrocyanide ion

formation

flash photolysis

radiation yield (per 100 eV)

gamma radiolysis

glycine

hydrogen

3—hexenedioate ion

ident. identification

k specific rate (in dm3 mol-1 s

-1 unless

otherwise specified)

K equilibrium constant

lum. luminescence

M mol/dm3 Me methyl

MeOH methanol

d ionic strength

math. mathematical

meas. measured

mol.wt. molecular weight

nat natural pH

NB nitrobenzene

obs. observed

opt. optical spectroscopy

oxy oxygen

PA~ phenylacetate ion

p.b.k. product buildup kinetics

perox hydrogen peroxide

PhH benzene

phot. photolysis

P negative logarithm of the acid dissociation

constant, e.g., where

ah + h2 o — a- + h3o + PNBA- p—nitrobenzoate ion

pol. polarography

p.r. pulse radiolysis

2-PrOH 2—propanol

py pyridine

r. radiolysis

rel. relative

RNO p—nitroso—N,N—dimethylaniline

soln. solution

therm. thermal

thym thymine

TNM tetranitromethane

trac. tracer techniques

unpubl. unpublished

vise. viscosimetry

X-r. X-radiolysis

3
Table 1. Values of k used for normalizing relative rates

Reactant* Reaction fc(dm

3 mol *s *) Comment Ref.' OH Reactions

bicarb (3.20) OH + HCOJ—» OH' + HC03 or H2 0 + CO; 3.6 x 10

7 b 73-1031

carb (3.21) OH + CO\-^ OH' + C03

' 3.65 x 108 b,c 70-0247

CNS~ (3.25) OH + CNS' —» CNSOH' 1.1 x 10

10 b,c,d 72-0122

Fe 2+ (3.52) OH + Fe 2+ —» OH + Fe 3+ 2.3 x 10

8 b 72-0354

ferro (3.54) OH + Fe(CN)^' —» OH' + Fe(CN)3 ' 9.3 x 10 9 b,c 73-1039

I - (3.66) OH + I-> OH'+ I 1.2 x 10 10 b 72-0122

PhH (3.186) OH + C 6H6 —> C 6 H6 OH 7.8 x 10 9 b,c 68-0304

BzCT (3.191) OH + C 6 H5COO'-+ (OH)C6 Hs COO~ 5.7 x 109 b,c 71-0578

EtOH (3.3581 OH + ch3ch2 oh h2o + ch3 choh 1.85 x 10

9 c,d —

HCOO- (3.384) OH + HCOO

H

z O + COO' 3.5 x 109 d —

MeOH (3.511) OH + CH3 OH H2 0 + CH2 OH 9 x 10

8 c,d —

NB (3.565) OH + C 6Hs N02 ^ (OH)C6 Hs N02 3.2 x 10

9 b,c 68-0304

PNBA' (3.567) OH + p-N02 C6 H4COO'-> (OH)p-N02 C 6 H4 COO' 2.6 x 10

9 b,c 68-0304

RNO (3.582) OH + p—NOC6H4 N(CH3) 2 —

products 1.25 x

10'° b,c 69-0156

PA

- (3.611) OH + C 6H5CH2 COO'^ (OH)C 6HsCH2 COO' 7.9 x 10 9 b,c 68-0304

2-PrOH (3.637) OH + (CH3) 2 CHOH H2 0 + (CH3) 2COH 2.2 x 109 d —

thym (3.711) OH + C 5 H6N2 02 -^ C 5 H6 N2 02 *0H (6-addn.) 5.4 x 10

9 d g O Reactions

oxy (4.29) O + 02 —* O3 3.6 x 10

9 b,c 69-0379

EtOH (4.65) O' + CH3 CH2 OH ^ OH' + C 2 H4 OH 1.1 x 10

9 b,c 70-0080

3HX (4.75) 0 + o2cch2 ch=chch2 co2 '^

OH' + o2cch2 chchchco2

6.5 x 10

s b 75-1003

MeOH (4.80) O' + CH3 OH OH' + ch2 oh 5.8 x 10

8 b,c 70-0080

2-PrOH (4.95) O' + CH3 CHOHCH3 -^ OH' + (CH3) 2 COH 1.5 x 10

9 e —

'Number in parentheses indicates the number of the reaction in the following tables.

b Most recently reported directly determined rate. 'Cited by Dorfman and Adams in NSRDS-NBS 46 (73-0299) as "most reliable values — values of which

the accuracy (within the stated experimental uncertainty or lacking such a statement, within ± 30%) seems least open to question"; more than one such value is cited in NSRDS-NBS 46 for some reactions.

dMean value of measured rates with k(OH + EtOH) = 1.85 x 109dm3 mol 's1 as a secondary reference

standard: Willson, Greenstock, Adams, Wageman and Dorfman (71-0578).

'Mean value of relative rates normalized for values listed in this table for competing reactions. Reference for the most recently reported directly measured rate. ‘Recent directly determined rates are 5.1 x 10

9 at natural pH (71-0578) and 5.5 x 10

9 at pH 9 (72-0047).

4
Table 2. Reactions of OH with transients from water

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.1 basic 3 x 10 10 — See 1.7, 1.8, 73-0030

OH + e.'^OH' NSRDS-NBS 43. 3.2 H acid ~ 2 x

10'° — — — See 2.3, 75-0001

OH + H -» H20 NSRDS-NBS 51. 3.3 OH 7 (4 ± 1) x 10

9 W^roS = p.r. chem. assumed 62-0052

OH + OH —> H2 02 (rel.) 1.9 x lO"5 *p*ro. = 4-5 x mol*s/dm 3 107

; obs. intensi—

ty effect on H2 02 and 02 concn.

0.4 6 x 10

9 (rel.) k/k H = 0.5 p.r. chem. obs. G(H2); data 63-0043

fitting based on mechanism; assumed

2&(H + H) = *(H + OH) = 1.2 x 10

10

. 3 6 x 10

9 (rel.) p.r. chem. obs. G(H2 ) and 64—0092

G(02 ) in H2 02 soln.; data

fitting based on mechanism;

assumed /:(H + OH)

= 3.2 x 10

10

; A:(H + H) =

1.3 x 10

10

. 3.7 (5.2 ± 0.7) x 10

9 — p.r. opt. d. k. ; e(260 nm) =

370 cm2 mol '. 65-0010

~7 5.5 x 10

9 (rel.) klk lmo = 0.59 p.r. opt. c.k.; obs. Fe(CN)3 ' at 420 nm; data fitting

66-0424

based on mechanism.

7 (5.2 ± 0.5) x 109 p.r. opt. d.k.; e(200-250

nm) = 450-530 cm

2 mol *; cor. for H and OH'.

69-0083

For other ratios see: 3.5, 3.6, 3.7, 3.12, 3.26, 3.82. 3.4 O' >12 « 2.6 x 10

10 (rel.) — p.r. opt. c.k. with 66-0424

OH + O'^ HO' Fe(CN)9 '; pK.(OH) = 11.9 ± 0.2;

est. based on numerous

assumptions.

3.5 ho 2 7 ~ 3 x 10

9 (rel.) k-k(H + H202 )/ p.r. chem. assumed 62-0052

(I) OH + H02 ^ h 2 o 3 ^perox^(H + H02) /:(H + H2 02) =

(II) OH + H02 -* = 74 /c(H + H02 ) and

H 2 0 + 02 >2 6 x 10

9 (rel.) oX

II p.r. chem.

^ perox = 4-7 X 10

7

. obs. G(H 2 02 ); 63-0043

data fitting based on mechanism;

assumed k OH =

6 x 10

9

. 2-3 ^i/^h — 2.3 e-r. opt. obs. G(H2 03

). 63-0075

0.8 1.4 x 10

10 (rel.) k/k Fe 2+ = 60 p.r. chem. obs. G(Fe 3+

) at ~ 10 22 eVg 's *. 64-0049

3 1.5 x 10

10 (rel.) — p.r. chem. obs. G(H2) and 64-0092

G(H 2 02 ); data

fitting based on mechanism;

assumed k 0H - 6 x 10 9

; *(H + H) = 1.3 x 10“

5
Table 2. Reactions of OH with transients from water — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.5 cont. 0.46- 7.1 x 10 9 (rel.) OX

II CO p.r. chem. obs. G(H2 02 ); 68-0014

6.75 best fit; pa:.(H02) =

4.45 ± 0.10; assumed k OH - 6 x 109

. 3.6 H2 0 2

+ 0.46- 1.27 x 10 10 (rel.) k/kOH = 2.12 p.r. chem. data fitting; 68-0014

OH + H202

+ ^ 1.51 p/r(H 2 0 + ^ H + +

h3 o

+ + 02 H02) = 1.2 ± 0.3; assumed k OH -

6 x 10 9. 3.7 o2

- 2.74- 1.01 x 10 10 (rel.) oh = 1-08 p.r. chem. obs. G(H2 02); 68-0014

OH + 02 ^ 6.75 data fitting; OH + 02 pk (H0 2 ^ h+

+ O^) = 4.45 ±

0.10; assumed

k OH = 6 x 10

9

. 7 (8.0 ± 1) x 10

9 — e-r. condy. — 69-0547

6
Table 3. Reactions of OH with inorganic solutes

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.8 Ag

+ 7 (1.50 ± 0.10) x 1010 — p.r. opt. p.b.k. 68-0436

OH + Ag+ —

* ~5 (6.3 ± 1.2) x 10

9 k/k MeOH = 7 ± 1 p.r. condy. c.k.; 2—fold 70-0512

Ag2+ + OH’ (rel.)

8.4 x 10

9(rel.)

increase in H

+

did not change

rate; may be

OH + Ag+ ^ AgOH4-

3.9 As0 2 10.7 klk c„b = 23 p.r. opt. c.k. 65-0190

9 7.6 x 10 9 (rel.) k/k rno = 0.607 7-r. opt. c.k. 65-0356

3.10 Au(CN)2 7 (4.7 ± 0.8) x 109 — p.r. opt. p.b.k. at 330 nm. 68-0302

OH + Au(CN)2 —2 5 x 109 (rel.) k/k MeOH =5.5 p.r. opt. c.k. 68-0302

Au(II) + OH"

3.11 bh; 11- 1.2 x 10 10 — p.r. opt. p.b.k. at 400 or 70-1046

bh;+ oh-» 12.83 280 nm. BH,+ OH -

3.12 Br

_ — 1 x 10

9 (rel.) k/k e,oh = 0.6 y-T. chem. c.k. 62-0053

(I) OH + Br-?± 2.2 — klk hydt = 830 y-r. chem. obs. G(H 2 02

). 63-0076

BrOH ~11 5.8 x 108 (rel.) klk c„b = 1-6 p.r. opt. c.k. 64-0131

BrOH ^Br + OH 0.8 1.6 x 10

10 (rel.) k/k on = 2.5 p.r. calcd. obs. G(H2 02); 64-0294

Br + Br- ^ Br;r math, anal.; BrOH - + Br - ^ assume k 0H = Br'+ OH'

7, 1.1 x 10 9 (rel.) k/kfaQ— — 0.20 y-r. trac.

6.4 x 10

9

; method approx,

c.k.; meas. 65-0099

10.5

14co2

. — 5 x 10

8 (rel.) klk Uno = 0.054 phot. — c.k. 65-0247

9 1.1 x 10

9 (rel.) k/k hno = 0.089 y-r. opt. c.k. 65-0356

7 1 x 10

9 — p.r. opt. p.b.k. at 360 nm. 65-0382

2 5 x 10

9 p.r. opt. p.b.k.; it is proposed that reaction may be

OH + (Br—H^

Br + H2 0.

65-0382

7 3.9 x 10

9 (rel.) k/k Mc0H = 4-4 ± y-r. chem. c.k. in 66-0118

0.5 NO-MeOH-KBr soln. 6 1.2 x 10

9 (rel.) k/k^tOH = 0.645 y-r. — c.k.; obs. G(H 2 o2

).

66-0423

9 1.1 x 10

9 (rel.) k/k^ow = 0.58 y-r. opt. c.k. with RNO. 66-0423

5-9 (1.2 ± 0.15) x 10

9

1 x 10

9 (rel.)

p.r. opt. p.b.k. at 365 nm;

k constant at this pH range but increases at low pH and decreases

at higher pH.

66-0425

~6 k/kfron = 0.56 ± y-r. chem. c.k. 66-0621,

0.04 67-0131

2.7 6.5 x 10

9 (rel.) k/kftOH = 3.5 ± y-r. chem. c.k. 66-0621,

0.4 67-0131

1.3 1 x 10

10 (rel.) k/k e,oh

_ 5.6 ± y-r. chem. c.k. 66-0621,

0.4 67-0131

~6 1.1 x 10

9 (rel.) klk Mt. OH = 1.2 ± y-r. chem. c.k. 66-0621,

0.1 67-0131

2.7 8.1 x 10

9 (rel.) k/k MeOH = ^ B ± y-r. chem. c.k. 66-0621,

0.9 67-0131

1.3 1.1 x 10

10 (rel.) k/k McoH = 12 ± 1 y-r. chem. c.k. 66-0621,

67-0131

2 3.1 x 10

10 (rel.) k/k rno = 2-5 Fenton opt. c.k. 67-0555

5.5 1.2 x 10

9 (rel.) k/k NB = 0.38 r. opt. c.k.; obs. 68-0494

o— nitrophenol

formn.

7
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.12 cont. 5.5 2.2 x 109 (rel.) k/kpiM — 0.28 y-r. opt. c.k. with 69-0279

Safranine T. 3.0 5.0 x 109 (rel.) ^/^PhH = 0.64 y-r. opt. c.k. with

Safranine T.

69-0279

2.0 1.0 x 10 10 (rel.) kfk phH — 1-3 y-r- opt. c.k. with

Safranine T. 69-0279

1-2, 4.3 x 10

9 (rel.) k/k2-PrOH =1-94 y-r- chem. c.k.; obs. 68-0602

6.98 G(acetone).

12- (8.9 ± 1.7) x 108 — f.phot. opt. c.k.; effect on 69-7340

13 (rel.) decay of 03 at 430 nm.

1.2 x 10

9 (rel.) ^•/^EtOH = 0.64 p.r. opt. c.k.; N2 0—satd.;

ratio = 4 in 02 —satd. 1.0 M Br" soln.

71-0137

9 1.75 x 10

9 (rel.) k/kfwo = 0.14 y-r. opt. c.k.; Em =

—6.2 ± 0.9 kcal/ mol (—26 kj/mol)

(-8 to 23°C).

71-0469

1-7 (1.06 ± 0.08) x — p.r. opt. p.b.k. at 360 nm 72-0018

10 10 (I) (Br^). 9- — — p.r. opt. p.b.k. at 365 nm 72-0148

11.5

For other ratios see: 3.32, 3.110, 3.394, 3.627.

(Br^); =

(2.86 ± 1.4) x 10 3 dm 3 /mol.

3.13 OD + Br" —

»

1.3 7.95 x 10

9 (rel.) k/k EtOH = 4.3 ± y-r. chem. c.k. in DjO; obs. 68-0015

OD'+ Br 0.4 G(D2 02

). 6 6.8 x 10 8 (rel.) k/k eioh = 0.37 ± y-r. chem. c.k. in D2 0. 68-0015

0.04

3.14 BrO" 11- 4.5 x 109 (rel.) — p.r. opt. c.k.; rel. to 68-0153

OH + BrO—

>

13 k(OH + C03 2") = BrO + OH- 4.2 x 10

8

, more tha" two rate constants involved

in analysis.

12- (1.4 ± 0.8) x 109 — f.phot. opt. c.k.; effect on 69-7340

13 (rel.) decay of 03 at 430 nm.

3.15 BrO j 13 1.9 x 10

9 (rel.) — p.r. opt. c.k.; relative 68-0153

OH + Br02 —

»

to i(OH + CO2 ") = Br0 2 + OH"

12- (1.4 ± 0.8) x 10

9 f.phot. opt.

4.2 x 10

8

; more

than two rate constants involved

in analysis; assume

k( OH + BrO^) =

k(O" + BrO^).

c.k.; effect on 69-7340

13 (rel.) decay of 03 at 430 nm.

3.16 Br0 3

" 12- (3.9 ± 2.3) x 10* — f.phot. opt. c.k.; effect on 69-7340

OH + BrOj —

»

13 (rel.) decay of 03 at BrO 3 + OH" 410 nm.

3.17 BrO; — < 10

7 — p.r. opt. d.k. (OH). 73-0106

3.18 CO 0.4- (4.6 - 5.8) x 108 k/k Ffl 2 + = 2-2.5 Fenton chem. c.k. 57-0014

OH + CO -* COOH 0.7 (rel.) ~1 8.7 x 108 (rel.) k/kpt 2+ = 3.79 Fenton chem. c.k. 57-0014

~1 8.3 x 10 8 (rel.) k/kfe 2+ = 3.6 ± y-r. chem. c.k. 63-0014

0.5

7 — = 13.0 phot. chem. c.k. 63-7005 — — */* ^,= 72 phot. chem. c.k. 69-7045

8
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.19 C02 4 < 106 — p.r. opt. no abs. at 600 65-0384

OH + C02 ^ HCOs nm.

3.20 HCOJ 6.5 1 x 10 7 — p.r. opt. p.b.k. at 600 nm. 65-0384

OH + hco3 -+ 8.4 1.5 x 10

7 — p.r. opt. p.b.k. at 600 nm. 66-0139

H 2 0 + COjor nat. (4.9 ± 0.6) x 10

7 — p.r. opt. p.b.k.; 3.3 x 69-0052

HC03 + OH' (7.9 ± 1) x 10

7 10"3 M HC03 ; authors have no

interpretation

which value is correct. — (4.9 ± 0.5) x 10

7 — p.r. opt. p.b.k. 69-0379

(3.6 ± 0.3) x 10 7 p.r. opt.

.

b.k. at 578 nm;

.

k. with 2-PrOH

gave 3.8 x 10

7

.

73-1031

For other ratios see: 3.57, 3.64, 3.384. 3.21 cor 11 3.8 x 10

8 (rel.) Ar/fc,- = 0.029 ± p.r. opt. c.k. 65-0010

OH + cor- 0.003 OH" + CO" 11 3.5 x 10 8 — p.r. opt. p.b.k. at 580 nm. 65-0010

10.5 ~ 4.5 x 10

8 (rel.) - 0.08 y-r. trac. c.k.; meas. UC02

.

65-0099

2 x 10

8 p.r. opt. p.b.k.; 02 -satd.

soln.; competing

reactions may

interfere.

66-0001

<11.6 4.2 x 10

8 p.r. opt. p.b.k.; k is pH dependent;

calcn. is indirect.

66-0139

10.6 (4.0 ± 0.2) x 10

8 — p.r. opt. p.b.k. at 600 nm. 69-0379

11 4.7 x 10 8 (rel.) — f.phot. opt. c.k.; soln. con— 69-7218

tains NOJ and

ethanol; rel. to *(OH + EtOH) =

2 x 10

9 and k(0 + C 2 H5 OH) = 1 x 10

9

. 11 3.65 x 10

8 — p.r. opt. p.b.k. 70-0247

For other ratios see: 3.9, 3.12, 3.14, 3.15, 3.25, 3.29, 3.30, 3.63, 3.66, 3.82, 3.92, 3.93, 3.94 , 3.95, 3.96, 3.97, 3.104, 3.105, 3.108, 3.109, 3.116,

3.143, 3.225, 3.351, 3.358, 3.369, 3.384, 3.403, 3.459, 3.511, 3.586, 3.615,

3.636, 3.696, 3.697, 3.698, 3.745. 3.22 c 2 N 2 — < 10

7 — p.r. opt. kinetic anal, of 71-0038

OH + (CN) 2 -> abs. spectra of CNCNOH transients in N2 0 soln. (OH and

C 2 N2"). 3.23 CN" 9 4.5 x 10

9 (rel.) ^/^rno = 0-36 y-r. opt. c.k. 65-0356

3.24 HCN — 7 x 10

7 (rel.) ^/^hcoo- ^ 0.02 y-r. chem. c.k. 73-0364

3.25 CNS" — 5.8 x 10

9 (rel.) klk c .rb = 16 p.r. opt. c.k. 64-0131

OH + CNS" —

7 6.6 x 10

9 — p.r. opt. p.b.k. at 500 nm. 65-0190

CNSOH" 2,7 1.2 x 10

10 (rel.) klk cmTb = 33 p.r. opt. c.k. 65-0190

CNSOH" CNS +2-2.2 9.7 x 10

9 (rel.) klk tbym = 1.80 ± y-r. opt. c.k. 67-0461

OH" 0.25 CNS- + CNS ^ 5-5.5 1 x 10

10 (rel.) */*.„,.= 1-95 ± y-r. opt. c.k. 67-0461

(CNS)" 0.30 9 1.2 x 10

10 (rel.) k/k rno = 0.95 y-r. opt. c.k. 67-0555

2-12 (7.5 ± 0.5) x 10 9 — p.r. opt. p.b.k. at 500 nm. 68-0316

9
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.25 cont. 2-7 2.8 x 10 10 p.r. opt. p.b.k. (CNS)2 ; earlier papers assumed CNS is absorbing species;

for mechansim

study see also 72-0126.

68-0375

5.5 1.2 x 10 10 (rel.) h/k nb = 3.6 r. opt. c.k.; obs. o—nitrophenol

formn.

68-0494

7 6.7 x 10

9 (rel.) k/k EtOH = 3.6 f.phot. chem. c.k.; soln. contains NOj.

69-7218

1 x 10

10 (rel.) ^/^EtOH = 5.5

k/k MeOH = 11-5

p.r. opt. c.k.; N2 0—satd.;

ratios 6.4 and

13.4 resp., in 02 —satd. soln. contg. 0.2 M

thiocyanate.

71-0137

— (1.08 ± 0.10) x 10 10 — p.r. opt. p.b.k. (CNS)2 at 475 nm.

72-0122

For other ratios see: 3.33, 3.34, 3.37, 3.66, 3.71, 3.74, 3.75, 3.76, 3.77,

3.86, 3.87, 3. 102, 3. 103, 3..107, 3. 110, 3. 117, 3..121, 3..124, 3..125, 3. 126, 3.129, 3.130, 3.131, 3.135, 3.138, 3.139, 3.140, 3.142, 3.143, 3.146, 3.147,

3.148, 3.151, 3.153, 3.155, 3.156, 3.157, 3.159, 3.163, 3.168, 3.169, 3.170,

3.171, 3.177, 3.178, 3.179, 3.181, 3.186, 3.191, 3.193, 3.197, 3.198, 3.202,

3.212, 3.219, 3.222, 3.223, 3.224, 3.225, 3.226, 3.227, 3.229, 3.230, 3.231,

3.232, 3.233, 3.234, 3.235, 3.237, 3.240, 3.241, 3.243, 3.245, 3.247, 3.256,

3.262, 3.263, 3.264, 3.266, 3.269, 3.270, 3.285, 3.288, 3.289, 3.290, 3.292,

3.293, 3.295, 3.296, 3.297, 3.298, 3.300, 3.311, 3.312, 3.318, 3.323, 3.328,

3.329, 3.330, 3.331, 3.332, 3.336, 3.338, 3.339, 3.342, 3.357, 3.358, 3.361,

3.362, 3.363, 3.364, 3.366, 3.369, 3.372, 3.375, 3.381, 3.383, 3.385, 3.390,

3.396, 3.397, 3.398, 3.402, 3.403, 3.404, 3.405, 3.406, 3.407, 3.410, 3.411,

3.412, 3.413, 3.415, 3.416, 3.417, 3.418, 3.421, 3.433, 3.434. 3.442, 3.443, 3.444--6, 3.451, 3.453, 3.459, 3.473, 3.479, 3.480, 3.481, 3.483, 3.486, 3.487

3.488, 3.489, 3.491, 3.493--3.495, 3.498, 3.503, 3.506, 3.508, 3.509a , 3.510,

3.511, 3.513, 3.520, 3.521. 3.522, 3.523, 3.524, 3.527, 3.528, 3.532, 3.535,

3.538, 3.543, 3.544, 3.545, 3.546, 3.547, 3.548, 3.554, 3.565, 3.573, 3.578,

3.580, 3.581, 3.592, 3.593, 3.594, 3.600, 3.602, 3.603, 3.604, 3.605, 3.606,

3.607, 3.613, 3.614, 3.616, 3.618, 3.621, 3.624, 3.628, 3.629, 3.630, 3.631,

3.634, 3.636, 3.637, 3.640, 3.645, 3.646, 3.649, 3.650, 3.656, 3.657, 3.659,

3.664, 3.665, 3.669, 3.670, 3.673, 3.674, 3.696, 3.703, 3.705, 3.706, 3.707,

3.709, 3.710, 3.711, 3.717, 3.718, 3.719, 3.723, 3.724, 3.726, 3.727, 3.730,

3.735, 3.737, 3.740, 3.743, 3.744, 3.746, 3.747, 3.748, 3.750, 3.751. 3.25a Cd 2+ — < 5 x 10

s — p.r. opt. c.k. with Cu 2+

. 75-1027

3.25b Cd + — 2 x 10 10 — p.r. opt.. d.k. at 300 nm; 75-1064

OH + Cd + -+ condy. Cd + from e~q + Cd 2+ OH" + Cd2+

3.26 Ce3+ OH + Ce3+ 0.4- */* buuu = 900 ± p.r. c.k. 60-0099

Ce4+ + OH" 2 300

0.8 3.2 x 108 (rel.) OX

II X o

1to p.r. calcd. math, anal.; 64-0294 assume k OH =8.1

x 10

8

; method approx. 0 — k/kucOOH - 1-9 — •y-r. chem. c.k.; 4 M H2 S04

. 69-0634

0.2 2.6- 2.9 x 10

s (rel.) ^/^EtOH = 0.154 p.r. opt. c.k. 71-0137

2.95

10
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.26 cont. 0.8 — k/k^lHSO,"] -y-r. chem. c.k.; computer 72-0094 = 930 ± 110 M"1 fitting based on

4 M — = 30 ± 3 M"1 mechanism; super— h2 so4 cedes 57—0003.

For other ratios see: 3.118. 3.27 cr 1-2.5 8.9 x 10 7 to 6.4 x k/k Me0H = 0.099 p.r. opt. c.k.; k decreases 64-0149

(I) OH+Cl-^CIOH- 10

8 (rel.) to 0.715 with pH and is

(II) C10H- + H+ ^ p, dependent;

Cl + H2 0 meas. abs. of Cl2 (III) ci + ci- ^ at 365 nm.

C12- 1-2.7 6.7 x 10 7 to 1.6 x 0.00725 p.r. opt. c.k.; k decreases 64-0149

10 9 (rel.) to 0.169 with pH and is

/x dependent.

1-3 (1.16 to 2.16) x 10 10 — p.r. opt. p.b.k.; k 64-0149

dm6 mol 2 s

1 includes [H +

]; not cor. for /a. 0-3 (0.32 to 1.84) x 10 10 — p.r. opt. p.b.k.; k 64-0149

dm6 mol"2 s"

1 includes [H +

];

fx = 0.012-1. -1-3 1.0 x 10 I0dm6 mol 2 s" ' k/k lhym = 1.9 ± y-r. chem. c.k.; k defined 65-0133

(rel.) 0.3 dm’mol 1 for OH + H

+ + Cl“-> Cl + H2 0.

9 < 1.25 x 106 (rel.) ^/^rno ^ 10 y-r. opt. c.k. 65-0356

2 5.2 x 10

8 (rel.) k/k rno = 0.042 Fenton opt. c.k. 67-0555

~0.1 4.8 x 10 9 (rel.) k/k rno = 0.381 Fenton opt. c.k. 67-0555

0.8- (1.5 ± 0.3) x 10

10 — p.r. opt. p.b.k.; k refers 68-0313

3.4 dm6 mol"2 s"' to OH + Cl" + H3 0

+ ^ Cl + 2H2 0.

1.1 3.5 x 10 7 (rel.) k/k Mc0H = 0.039 y-r. chem. c.k.; based on

^2-PrOH/^MeOH =

3.0.

69-0647

1.1 3.7 x 10

7 (rel.) k/k EtOH = 0.020 y-r. chem. c.k.; based on 69-0647

^2-PiOh/^EiOH =

1.61.

1 7 x 10

8 (rel.) k/k lhym = 0.13 Fenton esr c.k.; klk^T„

=

9.5; pH dependent;

also with Ti(III)—

H2 02

.

69-5278

1.3 2 x 10

8 (rel.) k/k Mc0H - 0.24 ± y-r. chem. c.k. 71-0931

0.04 6 < 10 6 ^/^MeOH < 0.001 y-r. chem. c.k. 71-0931

~2 (4.3 ± 0.4) x 10

9

(I) — p.r. opt. d.k. at 240 nm 73-1039

(2.1 ± 0.7) x 10

10 as well as p.b.k.

(II) at 340 nm (Cl^); 2.1 x 10

10 (III) Kx = 0.70 ± 0.13M" 1 /:„= 1.6 x 10

7

; JCm = 1.9 x lO

5 ^"1

. ~2 1.9 x 10

10 — p.r. opt. p.b.k. at 350 nm 73-1089

dm6 mol"2 s"’ (Cl^); k refers

to OH + Cl" + H3 0

+

. For other ratios see: 3.291, 3.594. 3.28 od + cr + d 3 o

+ ~2 1.6 x

10'° — p.r. opt. p.b.k. (see above) 73-1089

2D 2 0 + Cl dm 6 mol 2 s

1 *„/*„= 117.

3.29 CIO' — =£ 2 x 10

8 — f.phot. opt. estd. 71-7236

OH + CIO" —

11 8.2 x 10

9 (rel.) k/k ctrh - 22.5 p.r. opt. c.k. 72-0301

CIO + OH"

3.30 CIO" — (1.3 ± 0.4) x 10

9 — f.phot. opt. d.k. at 360 nm; 71-7236

OH + C10"->- assume £(OH + OH)

C10 2 + OH'

11 5.7 x 10

9 (rel.) */*«*= 15-7 p.r. opt.

= 5 x 10

9

; be9t fit. c.k. 72-0301

11
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.31 CIO 3‘ 11 < 10 6 (rel.) — p.r. opt. no effect on COJ 72-0301

4 x 10

s f.phot. opt.

formn. in carbonate soln. estd. 71-7236

3.32 C10 2 5.8- — k/k Br- = 1 y-r. chem. c.k. in 2—6 M 67-0019

OH + C10 2 ^ HCIO3 6.0

or —» H

+ + CIO”

*/*pTM > 200 •y-r. chem.

CIO^; based on

an assumed

mechanism,

c.k. assumed 67-0028

3.32a Co 2+ ~ 2 x 10 6 VKy6r > 100

p.r. opt.

values.

c.k. with Cu2+. 75-1027

3.33 Co(NH3) 3+ — « 1.1 x 10® (rel.) ^/^CNS — 10 p.r. opt. c.k. 71-0282

3.34 Co(BzO”)(NH 3 ) 2+ — (3.3 - 3.8) x 10

9 cns - = 0-3 — p.r. opt. c.k.; 02 —satd. 71-0282

(rel.)

(6. 3-6.7) x 10

9 0.35

p.r. opt. p.b.k. at 345 nm. 71-0282

3.34a Co(NH 3 ) sPy

3+ 5.2 6.5 x 10® — p.r. opt. p.b.k. at 320 nm. 75-1088

3.35 Co(CN) s N03” — 1.2 x 10® (rel.) k/k rno = 0.0094 y-r. opt. c.k.; depends on 71-0407

3.36 Co(acac) 3+ 1—7 4.8 x 10

9 (rel.) ^/^EtOH = 2.6 r. chem.

^CN_/^RNO = 0-42.

c.k. 70-0094

3.37 Cr(II) 1 4.8 x 10

9 (rel.) klkCN$— = 0.44 p.r. opt. c.k. 72-0240

3.38

OH + Cr(II) -* OH” + Cr(III) Cr3+ 0.4- k/k hydt = 0.0082 y-r. chem. c.k.; assume 63-0197

OH + Cr

3+ —» 1.4 Cr 4+ + OH”

0.4-1 */*h,dr= 7 ±2 y-r. chem.

^biaulf/^hydr 0.0039.

c.k.; 65-0052

3.39 Cr(CN)5 N03” —

(Unexplained discrepancy

7.9 x 10

9 (rel.)

' in the above data.) RNO = 0.63 y-r. opt.

^ bnulf / ^ hydr 0.011.

c.k.; assumed 69-0531

7 x 10

9 (rel.) RNO = 0.56 y-r. opt.

k(OH + CN”) =

3.0 x 10

9

. c.k.; depends on 71-0407

3.40 Cr(V) — 5 x 10

10 y-r. est. ^CN /^RNO = 0-42. reoxidation of 73-0186

3.41

OH + Cr(V) -+ OH” + Cr(VI)

Cu 2+ 7 3.5 x 10® p.r. opt.

transient from e”

q or H reaction with chromate,

p.b.k. at 313 nm. 65-0044,

OH + Cu 2+ -» Cu 3+ + OH” or — 3.6 x 10® (rel.) */*e,oh = 0.196 p.r. opt. c.k.; meas. Cu 3+ 65-0394

65-0394

-+ Cu(OH)2+ + Cu(OH) 2 — 3.5 x 10® (rel.) ^/^MeOH = 0.385 p.r. opt.

at 313 nm.

c.k.; meas. Cu 3+ 65-0394

~5 3 x 10® (rel.) ^/^1-BuOH = p.r. condy.

at 313 nm.

c.k.; assume 70-0512

3-6 (3.1 ± 0.3) x 10® 0.67 ± 0.07

p.r. opt. ^McOh/^i-BuOH

p.b.k. at 300 nm. 71-0174

5.7 (3.1 ± 0.6) x 10® — p.r. opt. p.b.k. at 300 nm. 71-0775

3.42 Cu(en) 2

+ 6.5 (3.0 ± 0.6) x 109 — p.r. opt. p.b.k. 71-0775

3.43

OH + Cu(en) 2+ -* 10.2 OH” + Cu(en) 2

+ 11.2 Cu(gly) 2

+ 6.1

(5.0 ± 1.0) x 10

9

(8.0 ± 2.0) x 10

9

(1.5 ± 0.3) x 10

9 —

p.r. opt. p.b.k. 71-0775

3.44

OH + Cu(gly) 2

+ —

>

OH” + Cu(gly) 2

+

Cu(ala) 2+ 6.3 (1.4 ± 0.3) x 109 p.r. opt. p.b.k. 71-0775

3.45

(see 3.43) Cu(/3-ala) 2

+ 5.8 (1.2 ± 0.2) x 10

9 p.r. opt. p.b.k. 71-0775

3.46

(see 3.43)

Cu(CH 3 CH2 CH(NH^)COO”)

(see 3.43) 6.1

2 +

2 (2.0 ± 0.4) x 10

9 p.r. opt. p.b.k. 71-0775

12
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.47 Cu(CH3CH(NH3

+)CH2 COO)2+

2 (see 3.43) 6.0 (1.2 ± 0.2) x 10

9 — p.r. opt. p.b.k. 71-0775

3.48 Cu(NH3CH2 CH2CH2 COO~):2 +

2 (see 3.43) 4.8 (1.1 ± 0.2) x 10

9 — p.r. opt. p.b.k. 71-0775

3.49 Cu((CH3) 2C(NH^)COO~)2+

(see 3.43) 6.2 (1.8 ± 0.4) x 109 — p.r. opt. p.b.k. 71-0775

3.50 Cu(EDTA)2" ~7 4 x 10

9 (rel.) ^/^MeOH =4.4 X-r. chem. c.k. 73-0078

3.51 Eu 2+ — 9 x 10® — p.r. opt. d.k. (Eu 2+

). 71-0311

OH + Eu2+ —* 2 (1.3 ± 0.2) x 10 9 — p.r. opt. d.k.; transient 73-1084

OH"+ Eu3+ Eu(II) formed

in Eu(III) soln. 3.52 Fe 2+ 1.2- — */*perc ,= (2.99 Fenton chem. c.k.; Ea(OH + 51-9004

OH + Fe

2+ Fe3+ 1.9 ± 0.2) X 10"2 H2 02 ) - E.(OH +

+ OH" Fe 2+

) = 3.5 kcal/mol(14.6

kj/mol). 0.4 — k/kH = 6.2 x 10"3 p.r. c.k. obs. G(H2 ) and

G(Fe 3+

); math.

60-0099

anal. 0.3 > 10® — p.r. opt. p.b.k. at 305 nm;

(Fe

3+

).

64-0090

0.4 1.7 x 10

9 (rel.) ^/^E«OH = 9.9 p.r. opt. c.k. 64-0242

0.8 1.2 x 10

9 (rel.) k/k phu = 0. 15 y-r.. chem. c.k. 66-0645,

e—r. 67-0504

3.5 (5 ± 1) x 10® p.r. opt. p.b.k.; reported

reaction is OH +

Fe aq 2+ —» Fe(OH)2+.

66-0716

2 5 x 10® (rel.) k/k rno = 0.04 Fenton opt. c.k. 67-0555

4.5- 3.4 x 10® (rel.) ^/^EtOH = 0.183 p.r. opt. c.k. 71-0137

6.2

1 (2.3 ± 0.2) x 10® p.r. opt. p.b.k. at 240 nm;

no temp, dependence 17—67°C.

72-0354

For other ratios see: 3.5, 3.18, 3.56, 3.58, 3.59, 3.60, 3.77, 3.114, 3.123,

3.131, 3.149, 3.150, 3.185, 3.186, 3.190, 3.192, 3.221, 3.224, 3.239 , 3.245,

3.251, 3.307, 3.320, 3.326, 3.358, 3.360, 3.365, 3.369, 3.371, 3.382, 3.404,

3.409, 3.451, 3.486, 3.491, 3.511, 3.522, 3.531, 3.546, 3.565, 3.612 , 3.620,

3.636, 3.637, 3.638, 3.639, 3.642, 3.656, 3.680, 3.693, 3.694, 3.704, 3.724. 3.53 OD + Fe

2+ —

1 (9.4 ± 0.8) x 10 7 — p.r. opt. p.b.k. at 240 nm; 72-0354

OD' + Fe

3+ in D2 0.

3.54 Fe(CN)J" 7 (1.1 ± 0.2) x 10

10 — p.r. opt. p.b.k. at 420 nm. 64-0213

OH + Fe(CN)J” -> 7 8.7 x 10 9 (rel.) k/k EloH = 4-7 p.r. opt. c.k. 65-0007

OH- + Fe(CN)3- 7 2.0 x 10

10 (rel.) k/k x - = 1.67 ± p.r. opt. c.k.; meas. abs. 65-0010

0.018 of I

2 at 400 nm.

7, 1.2 x 10

10 (rel.) klk Bx0 - = 2.1 ± y-r. trac. c.k.; meas. 65-0099

10.7 0.4

14co 2

. 9 1.2 x 10

10 (rel.) k/k RNo = ( y-r. opt. c.k. 65-0356

3-7 (1.07 ± 0.10) x 10

10 — p.r. opt. p.b.k. at 420 nm. 66-0424 — 1 x 10 10 (rel.) ^./^EtOH = 3.4 p.r. opt. c.k.; N2 0-satd.; 71-0137

1.1 x 10

10 (rel.) k/k MeoH = (2.4 ratios 5 and 11.5, resp. in 02 -satd.

soln. contg. 0.05 M ferrocyanide.

nat. (9.3 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 410 nm. 71-0578

13
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH Ratio Source Method Comment Ref.

3.54 cont. 0-7 (1.25 ± 0.1) x 10 10

3.60

3.61

3.62

(1.12 ± 0.17) x 10

10 —

(9.3 ± 0.5) x 10 9

For other ratios see: 3.3, 3.12, 3.27, 3.62, 3.85, 3.128,

3.151, 3.152, 3.168, 3.169, 3.191, 3.225, 3.231, 3.233, 3

3.369, 3.384, 3.385, 3.394, 3.403, 3.405, 3.406, 3.473-3

3.545, 3.546, 3.590, 3.614, 3.636, 3.637, 3.664, 3.686, 3

p.r. opt. p.b.k. at 420 nm; 72—0431

calcd. /r(OH +

HFe(CN)6

3-) =

(9.0 ± 0.9) x 10

9 and k(OH + H2Fe(CN)6

2-) =

(1.7 ± 0.5) x 10

9

. p.r. opt. p.b.k. at 420 nm; 73—1031

c.k. with 2—PrOH

gave 8.0 x 10

9

. p.r. opt. p.b.k. ; p. = 0.002 73—1039

to 10. 3.131, 3.134, 3.143,

.310, 3.358, 3.367,

,473a, 3.506, 3.511, 3.527,

.697, 3.711, 3.746. 3.55 OD + Fe(CN)J--> nat (9.7 ± 1.0) x 10

9 — p.r. opt. p.b.k. at 420 nm; 72-0354

OD' + Fe(CN)3 ' in Dz O.

3.56 Fe 3+ acid (7.9 ± 0.5) x 10

7 k/kFt 2+ = (3.45 ± p.r. — c.k. 66-0715

(rel.) 0.2) x 10'1 For other ratio see: 3.358. 3.57 Fe(CN)5 N0 2 ' — 7.9 x 10

6 (rel.) klk blcirh = 0.22 p.r. opt. c.k.; meas. abs.

of CO j at 600 nm.

69-0052

3.58 Fe(EDTA)' 1 4.8 x 10

8 (rel.) klkfK 2+ = 2.1 X-r. chem. c.k. 71-0202

OH + Fe(EDTA)' —

>

1.5 x 10 9 (rel.) k/k MeoH = 1-7 H 2 0 + prod. 6 9.9 x 10

8 (rel.) ^/^MeOH = 1-10 X-r. chem. c.k. 75-0159

3.59 h 2 7 — 0.94 y-r. chem. c.k. 52-0004

OH + H2-^ ~1 3.4 x 10 7 (rel.) k/k Fe 2+ = 0.15 Fenton chem. c.k. 57-0014

H 2 0 +.H 1 2.7 x 10

7 (rel.) k/k Ft 2 + = 0.116 Fenton chem. c.k. 57-9007

1.57 3.2 x 10

7 (rel.) k/k Fe 2+ = 0.14 y-r. chem. c.k. 58-0004

2.1 4.0 x 10

7 (rel.) k/k Fe 2+ = 0.175 y-r. chem. c.k. 58-0004

~7 — klk^ = 1.0 y-r. chem. c.k. 58-0012

~1 (3.2 ± 0.2) x 10

7 k/k Fe 2+ = 0.14 Fenton chem. c.k.; Ea(OH + H2) 59-0028

(rel.) ± 0.01 - E. (OH + Fe 2+

) =

2.7 ± 0.3 kcal/mol

(11.3 kj/mol);

/l(OH + H2 )M(OH +

Fe2+

) = 14 ± 6. 0.4 3.1 x 10 7 (rel.) k/k F'2+ = 0.135 y-r chem. c.k. 59-0064,

61-0100,

63-0004

7 — klk^x = 0.93 ± phot. chem. c.k. 62-7001

0.03

2 — */* ^=0.95 y-r. chem. c.k. 64-0212

3 3.5 x 10

7 — p.r. opt. d.k. 65-0010 — (6.0 ± 2.0) x 10

7 — p.r. opt. d.k. at 260 nm. 66-0426

For other ratios see: 3.12, 3.32, 3.38, 3.62, 3.82, 3.106, 3.118, 3.121, 3.291. d 2 OH + D 2 -* DHO + D

>2 (1.2 ± 0.1) x 10

7

(rel.)

k/k F' 2+ = 0.050 ±

0.005

Fenton chem. c.k.; £.(OH + D 2) - £.(OH + Fe 2+

) =

3.4 ± 0.2 kcal/mol

(14.2 kj/mol);

/l(OH + D 2)//l(OH +

Fe2+

) = 16 ± 6.

59-0028

d 2 OD + D 2 —

>

D 2 0 + D

alk. (1.6 ± 0.2) x 10

7 p.r. opt. p.b.k. (meas.

ejfrom D + OD-^e^ + D20).

68-0061

OH~

OH + OH -» H 2 0

3.5-

11

2.9 x 10

9 (rel.) k/k r = 0.22 phot. chem. c.k. 62-0057

+ O' alk. 5.6 x 109 (rel.) klkUm = 0.6 p.r. — c.k.; estd. 65-0007

10-

14

3.0 x 10 8 (rel.) k/k r = 0.025 y-r. chem. c.k.; pH effect on yields.

65-0219

14
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.62 cont. 11 (1.2 ± 0.3) x 10

10 — p.r. opt. c.k. with MeOH 70-0511

(rel.) and EtOH; soln. contains CO7 - and

HCOj; assume

k(0~ + H2 0) =

I. 7 x 10 6 and p/l,(OH) =

II. 9. For other ratios see: 3.107. 3.63 HO2

' 13 8.3 x 10

9 — p.r. opt. p.b.k. at 260 nm; 68-0298

OH + H02 —involves various OH + H02 11 1.4& + k(0 + H2 02 ) p.r. opt.

assumptions,

c.k.; value 69-0379 = (8 ± 0.8) x 109 relative to

(rel.) *c„b = (4 ± 0.2) x 10

8 and p/C„(OH) —

11.9; p. = 0.4.

alk. 1.4 x

10'° — p.r. condy. computer anal.; more than one

72-0404

rate constant

involved in calcn. — (5 ± 1.5) x 10

9 — phot. opt. c.k.; calcd. from 73-7575

(rel.) ^/^RNO at pH 7-10.52.

3.64 h 2 o2 — (4.5 ± 0.4) x 10

7 — p.r. opt. Data fitting; G 62-0052

OH + H2 02 -> values. ho 2 + h2 o 3 1.2 x 10

7 (rel.) p.r. opt. Data fitting; G

values; rel. to *(H + H) = 1.3 x 10

10

.

64-0092

7 (2.6 ± 0.8) x 10

7 k/kr = (2.2 ± p.r. opt. c.k. 65-0010

(rel.) 0.7) x 10”3 — 1.7 x 10

7 (rel.) k/k RN0 = 0.00136 p.r. opt. c.k. 69-0156

8.4 6.5 x 10 7 (rel.) bicarb = 1-3 p.r. opt. c.k. 69-0379

7 (1.7 ± 0.3) x 10

7 k/k RN0 = 0.00136 phot. opt. c.k. 73-7575

(rel.) 6 4.5 x 10 7 (rel.) k/k RNO = 0.0036 phot. opt. c.k. 74-0052

For other ratios see : 3.3, 3.5, 3.18, 3.32, 3.52, 3.59, 3.77, 3.115, 3.592, 3.711. 3.65 HgCl 5.0 ~ 10

10 — p.r. opt. d.k. at 235 nm; 73-0043

OH + HgCl —* HgCl + reaction of e”

q + OH” or or H with HgCl 2 Hg(OH)Cl + H

+ + Cl”

gives HgCl.

3.66 I” neut. (1.02 ± 0.13) x 10

10 — p.r. opt. p.b.k.; I

2 is 65-0010

(I) OH + I”—> HOI” meas.; assumed

(II) HOI” —* OH” + I that OH + I”—

(111) 1 + 1- ^ i2-

10.5 1.4 x 10'° (rel.) k/k B,0 - = 2.37 ± y-r. trac.

OH” + I is rate determining step,

c.k.; meas. 65-0099

0.12 G( hC02

). 9 1.4 x 10

10 (rel.) k/k rno = 1-14 y-r. opt. c.k. 65-0356 — — k/kjcQQ = 3.8 y-r. trac. c.k.; obs.

3 HHO. 68-0209

9 1.2 x 10

10 (rel.) ^/^RNO = 0.96 ± y-r. opt. c.k.; Oz —satd. 68-0310

0.07. — 3.4 x

10'° — p.r. opt. p.b.k.; method

is indirect.

68-0375

7 1.2 x 10

10 (rel.) */*b.o- = 2.1 y-r. chem. c.k. 68-0494

5.5 1.2 x 10 10 (rel.) z03 II Oo CO y-r. opt. c.k.; obs. o-nitrophenol

formn.

68-0494

15
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.66 cont. 2 1.1 x 10 10 (rel.) ^/^phH = 1-46 y-r. opt. c.k. with

Safranine T. 69-0279

3-5.5 7.4 x 10

9 (rel.) ^/^PhH = 0-93 y-r. opt. c.k. with

Safranine T.

69-0279

0-2 1.6 x 10 10 (rel.) k/k 2-PrOH = 7.1 ± 0.2

y-r. chem. c.k.; obs. G(acetone).68-0602

6.98 1.8 x 10 10 (rel.) k/k 2-PrOH = 8. 1 ± 0.1

y-r. chem. c.k.; /a = 0.1 —

1.1.

68-0602

11 6.6 x 10 9 (rel.) */*carb = 18 p.r. opt. c.k. 69-0379 — 2.4 x 10

10 (rel.) k/k cns - = 2.14 p.r. opt. c.k. 70-1226 — 4.0 x 10 10 (rel.) k/k nb = 12.6 p.r. opt. c.k. 70-1226

1 x 10 10 (rel.) k/k e,oh = 3.5 p.r. opt. c.k.; N2 0—satd.;

ratio 7 in Oz satd. 0.1 MI- soln.

71-0137

9 1.5 x 10

10 (rel.) k/kjiHQ = 1.22 r. opt. c.k.; E, = 0.7 ±0.3 kcal/mol

(2.9 kj/mol)

(265-296 K).

71-0469

~6 1.4 x 10

10 (rel.) k/k Mc0H = 15.2 ±

0.9

-y-r. chem. c.k. 71-0931 — (1.21 ± 0.08) x 10

10 — p.r. opt. p.b.k. at 385 nm 72-0122

(I2); ^1 —

^m>

k n = (1.2 ± 1.0) x

1

/-\8 — 1 10 s . For other ratios see : 3.21, 3.54, 3.62, 3.64, 3.91, 3.110, 3.128, 3.129, 3.131,

3.186, 3.220, 3.228, 3.343, 3.358, 3.365, 3.371, 3.384, 3.385, 3.394, 3.482,

3.511, 3.592, 3.637, 3.647, 3.711. 3.67 IOJ 12.4- (9.2 ± 0.8) x 108 — f.phot. chem. d.k. at 430 nm 70-0018

OH + IO;-* I0 3 13.6 (rel.) (O^; value is + Oh- based on

k( O + 02 —* O3) =

2.5 x 10

9

. 7 =£ 5 x 10

7 (rel.) p.r. opt. c.k. with EtOH

and 2-PrOH; obs. decrease in abs.

at 360 nm.

72-0017

6 (1.1 ± 0.1) x 10

7 — p.r. opt. p.b.k. at 360 nm. 73-0027

3.68 io; 5.6 (4.5 ± 0.5) x 10

8 — p.r. opt. p.b.k. at 520 nm; 71-0274

OH + 10;^ OH" + computei anal. 71-0335

IO4

3.69 Mn2+ OH + Mn2+ —

>

— ^ 1.4 x 10

8 — p.r. opt. p.b.k. at 450 nm. 65-0395

Mn 3+ + OH'

3.70 Mn(CN)5 N03~ — 4.2 x 10

9 (rel.) k/k rno

=-- 0.34 y-r. opt. c.k.; depends on

^cn 1 k rno = 0-42.

71-0407

3.70a Mo(CN)g- — (5.8 ± 0.6) x 10

9 k/k bicarb = 16 p.r. opt. c.k. 73-1031

OH + Mo(CN)g- —(rel.) OH" + Mo(CN)g3.71 nh 3 — 1.0 x 108 — p.r. opt. d.k. (OH) or 72-0109

OH + NH3 ^ H z O + p.b.k. at 530 nm nh 2 11.3 1.5 x 10

7 (rel.) k/k CNS~ = 0.00135 p.r. opt. (NH 2

). c.k.; includes 72-0460

3.6 x 10 7 (rel.) k/k MeOH = 0.04 0 + nh3

. 3.72 nh 2 — 9.5 x 10

9 — p.r. chem. effect of NH3 72-0109

OH + NH2 ^ NH 2 OH concn. on G(NH 2 OH).

3.73 n,” 9 1.1 x 10

10 (rel.) k/k RNo

== 0.86 y-r. opt. c.k. 65-0356

oh + n;-» n 3 + 9.2 1.1 x 10

10 (rel.) klk Bt0 ~ = 2.0 p.r. opt. c.k.; meas. abs 70-0649

OH- of N 3 at 278 nm.

3.74 NH 2 OH 8 9.5 x 10

9 (rel.) k/kcNs~ = 0.86 p.r. opt. c.k. 71-0493

3.75 nh 3 oh + 4 ^ 5.0 x 10

8 (rel.) k/k Ctis~ = 0.0455 p.r. opt. c.k. 71-0493

16
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment

3.76 NH2 NH2 10 OH + NH2 NH2 ^

h2 0 + n 2 h3

1.4 x 10 10 (rel.) k/k,cns — = 1-3 p.r. opt. c.k.

3.77 nh2 nh3 ~1

OH + NH2 NH3

+ ^ 2 h 2 o + n2 h;

~ 2 x 10

7 (rel.) k/k rt 2+ = 0.09 k/k^ = 1 ±

0.1

y-r.

r. chem.

chem.

c.k. calcd. assuming

mechanism.

6 1.0 x 10 9 (rel.) k/k CNS - = 0.091 p.r. opt. c.k. 3.78 NOH(S03 )*' 8.4-

OH + N0H(S03) 2 ~ 12 - H2 0 + 0N(S03) 2

“

5.7 x 10 8 (rel.) k/k PhH = 0.073 . e—r. esr obs. buildup of ON(S03

-)

2 ; k probably is concn. dependent. — 4.94 x 10 8 (rel.) k/kpbH — 0.063 — — calcd. 3.79 N0(S03) 2 ' (Fremy's

salt)

2.6 x 10

10 — — — calcd.

3.80 NO 7 OH + NO —> NO' + H

+ 1.1 x 10

10 (rel.) klkMCoH = 12.5 y-r. chem. c.k. (for product

ident. see 70—0228

7 8.9 x 10

9 (rel.) k/kfrOH = 4.8 ±

0.6

y-r. chem. c.k.

7 1.1 x 10

10 (rel.) k1 k 2~pro\i = 4.8 ±

0.6

y-r. chem. c.k. — — nitrite = 16

± 0.4

f.phot. opt. c.k.

7 1 x

10’° — p.r. opt. p.b.k. at 220 nm

(N0 2

-). 3.81 N0 2 9 OH + N02 ^ H02 NO

1.3 x 10

9 p.r. opt. meas. buildup of abs. at 302 nm

in N03 soln.; calcn. involves fc(OH + OH) =

0.6 x 10

10 and

k for N03 ' (+ H2 0

-» N02 + 20H' =

5.5 x 10

4 s

’. 3.82 no2 — 1.2 x 10

10 (rel.) klkctTb = 32 p.r. opt. c.k. OH + NO'-» N0 2 + —

OH'

1.1 x 10

10 k/k OH = 1.45 p.r. calcd. math. anal, of data from N03 soln.; assume

k OH = 7.6 x 10

9

. 10.7 6.6 x 10

9 (rel.) */*..* = 18 p.r. opt. c.k. 9 8.1 x 10

9 (rel.) k/k rno = 0-65 y-r. opt. c.k. 5.9 x 10

9 (rel.) k/k McoH ~ 6 5 ±

0.8

y-r. chem. c.k. in NO-MeOH-KNO.

solns. — — 125 y-r. chem. c.k. — — k/kjQQQ— - 3.0 y-r. trac. c.k.; obs.

3 HHO.

9 7.1 x 10

9 (rel.) k/k rno = 0.57 ±

0.03

y-r. opt. c.k.

11 7.3 x 10 9 (rel.) klk c.,b = 20 p.r. opt. c.k. acid 1 x 10

10 (rel.) ^/^MeOH = p.r. condy. c.k.

alk. 8.5 x 109 (rel.) k/k^oH = 9-4 p.r. condy. c.k. >12 1 x 10

10 (rel.) k/k(O' + 02 ) =

4.0 ± 0.4

f.phot. opt. c.k.; meas. dependence of 03 decay rate on OH' and NO'.

9 1.1 x 10 10 (rel.)

For other ratios see:

klk^o = 0.86

3.80.

y-r. opt. c.k.; £.= - 1.0 ±1.0 kcal/mol

(-4.2 kj/mol)

(-8 to 23°C).

Ref.

72-0003

62-0136

56-7004

72-0003

68-0471

71-0596

71-0596

66-0118

66-0118

66-0118

70-7264

73-0096

70-0151

64-0131

64-0294

65-0190

65-

0356

66-

0118

67-

0032

68-

0209

68-

0310

69-

0379

70-

0254

70-0254

70-7264

71-0469

17
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.83 NOJ

OH + N03"-*

9 < 5 x 10 s (rel.) — — — c.k. with RNO. 66-0843

OH + N03 3.84 hno3 (+no 3

-) ~0 -

— p.r. opt. p.b.k. (N03) at 67-0002

OH + HN03 ^ 635 nm; pseudo—

h2 o + no3

~0-l — — p.r. opt.

first order rate =

1.5 x 10

5 s"1 at 0.1 M HN03 and 4.2 x

10

5 s

1 at 0.4 or

1.0 M HN03. p.b.k.; rate of formn. of N03 (2 to 12) x 10V1

; first order in H

+ and N03

.

69-0417

4 M — ^[H ][NO^]/k HCOOH y-r. chem. c.k. in Ce(III)— 72-0263

hno3 = 0.21 ± 0.03 M Ce(IV)-HCOOH soln.

^Ce(IlI)/^HCOOH = 4.1. For ratio see: 3.720a

3.84a Ni 2+ — < 5 x 10

s — p.r. opt. c.k. with Cu 2+ 75-1027

3.85 Ni(CN)2 " — (9.1 ± 0.5) x 10

9 klktmo=0.98 p.r. opt. c.k.; also 74-1072

OH + Ni(CN) 2 ~-> (rel.) p.b.k. at OH" + Ni(CN); 250 nm.

3.86 Ni(en) 2 + 8.0 (6.0-7. 2) x 10

8 k/k CNS - = 0-035 p.r. opt. c.k.; cor. for 72-0461

OH + Ni(en)

2+ —» (rel.) - 0.065 OH + en. OH" + Ni(en) 8 + 8.5 (4. 1-7.2) x 10

9 k/k cns — 0.37—

(rel.) 0.65

9.0 (5.5—6.6) x 10

9 k/k cns~ = 0.5—

(rel.) 0.6 10.0 (5. 5-9.4) x 10

9 k/k cns - = 0.5—

(rel.) 0.85

3.87 Ni(gly)

2 + 10.0 (4.9-7. 7) x 109 k/k cns — = 0.45 — p.r. opt. c.k.; cor. for 72-0461

OH + Ni(gly)

2 + —* (rel.) 0.7 OH + glycine.

OH"+ Ni(gly)

8 +

3.88 Ni(EDTA)2' 7 2.8 x 10

9 (rel.) ^/^MeOH = 3.1 X-r. chem. c.k. 72-0173

2.1 x 10 9 (rel.) k/k hcoo- = 0.61 3.88a Os(CN) 6 4" — (1.03 ± 0.12) x 10

10 — p.r. opt. p.b.k. at 330 and 73-1031

OH + Os(CN)6

4 " 8.6 x 10

9 (rel.) k/k 2-PrOH = 4 410 nm; also c.k. OH" + Os(CN) 8

" 1.02 x 10 10 (rel.) k/k MeOH = 0-3 3.88b Os(NH 3) 5 N 2 2+ — 1 x 10 10 — p.r. opt. p.b.k. at 380 nm. 75-0309,

OH + Os(NH 3 ) 5 N 2 2+ 75-1099 — h 2 o + Os(NH3 ) 4NH2 N 2 2+

3.89 (NaP0 3 ) n < 5 x 10

6 p.r. opt. no absorbing

product formed;

n t 50.

74-0036

3.90 h 3 po 4 0.0 2.6 x 10

6 (rel.) k/k\[eon — 0.0028 p.r. opt. c.k.; ob9. H2 P04 73-1049

OH + H3 P04 -> radical at 500 nm. h 2 o + h 2 po4 3.91 h2 po4

" ~7 < 1.2 x 10

7 (rel.) k/k r < 0.001 p.r. opt. c.k.; contains 65-0010

oh + h 2 po;-+ HP02 "(pA.=

H 2 P04 + OH"

3.85- 2.2 x 10

6 (rel.) k/k\icoH = 0.0024 p.r. opt.

7.2). c.k.; obs. phos— 73-1049

4.0 phate radical

at 500 nm.

18
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment

3.92 HPOj" — < 5 x 106 (rel.) k/kcub < 0.012 p.r. opt. c.k. 9.0- (7.9 ± 0.4) x 10

s — p.r. opt. p.b.k. at 500 nm;

12.3 also k = 9 x 10

s by c.k. with MeOH.

3.93 PO3 " — < 10

7 (rel.) k/k cirb < 0.025 p.r. opt. c.k. 3.94 p2 or — < 4 x 10 6 (rel.) klk c„b < 0.01 p.r. opt. c.k. 10.3 (9 ± 1) x 10s — p.r. opt. p.b.k. at 590 nm.

3.95 h 2 po- 10.7 1.7 x 10 9 (rel.) klkc„b = 4.7 p.r. opt. c.k. 3.% poJ- 10.7 3.5 x 10

9 (rel.) klk c„b = 9.5 p.r. opt. c.k. 3.97 OH + PdCl *--» — (6.3 ± 0.3) x 10

9 ^/^t-BuOH = 12 p.r. opt. c.k. in 0.01 M

Pd(III) (rel.) NaCl, assume

^i-BuOH = 5-2 X 10

8

; it = 1.2 x 10

,0 in 1M NaCl.

3.98 Pr

3+ 5.8 2 x 10

6 (ave.) — p.r. opt. p.b.k. at 300 nm; OH + Pr

3+ -* also detd. by

OH + Pr4+ c.k. with H2 02 or CNS".

3.5 ~ 3.5 x 10

6 — p.r. opt. p.b.k. at 290 nm.

3.99 ptcir

OH + PtCl*"-+

-11 (8 ± 2) x 10

9 — p.r. opt. p.b.k. at 450 nm.

Pt(III) + OH"

3.100 Pt(CN)*"

OH + Pt(CN)’"

~2 1.1 x 10 10 (rel.) k/k mcoh = 12 p.r. opt. c.k.

Pt(III) + OH"

3.100a Ru(CN)4 " — (5.7 ± 0.8) x 10

9 — p.r. opt. p.b.k. at 330, 355

OH + Ru(CN)j" —

and 470 nm; c.k. OH" + Ru(CN)3 " with 2— PrOH gave

4.4 x 109. 3.101 Ru(NH3) sN2 + — 4.8 x 10

9 — p.r. opt. p.b.k. at 440—44

OH + Ru(NH3) 5N2 + nm. - OH" + Ru(NH3) 5 N

3+

3.102 h2s 6 1.9 x 10 10 (rel.) ^/^CNS 1 1-7 p.r. opt. c.k. OH + H2 S 2- 2.2 x 10

10 (rel.) k/k Cf)s~ = 2 ± p.r. opt. c.k. H 2 0 + HS 5.7 0.5 6 1.4 x 10

10 (rel.) ^/^MeOH = 15 p.r. opt. c.k. 5.5 1.5 x 10 10 (rel.) k/k hcoo- = 4.4 p.r. opt. c.k. 3.103 HS" — 9 x 109 (rel.) ^/^cns — = 0-82 p.r. opt. c.k.; also with OH + HS" —

MeOH, formate

OH" + SH ion. 10.5 8.4 x 10 9 (rel.) k/k MeOH = 9.3 p.r. opt. c.k. 10.5 9.4 x 10

9 (rel.) k/k hcoo- = 2-7 p.r. opt. c.k. 3.104 hso3

- — 9.5 x 10

9 (rel.) klk c„b = 26 p.r. opt. c.k. 3.105 sor — 5.5 x 10

9 (rel.) k/k CBrb = 15 p.r. opt. c.k. 3.106 hso; 0.8 — k/k hcooh = y-r. chem. c.k.; rel to OH + hso;^ 0.0026 kce 3+ Ikncoou = HSO* + OH" or 1.7. so;+ h 2 o 0.8 — k/k bydT = 0.005 phot. chem. c.k. 0.8 — klki\coon ~ 0-0016 y-r. chem. c.k.

1 — klk HCOOH = 0.0013 phot. chem. c.k. 0.8 — klkncoon — 0.0011 phot. chem. c.k. 0.4 — klk HCOOH = 0.0009 phot. chem. c.k. 0.1- — klk byAl = 0.0039 y-r. chem. c.k. 0.8

0.4-1 — ^hydr = 0.011 y-r. chem. c.k. ~7 1.6 x 10

6 (rel.) k/kfAeOH = 0.0018 p.r. opt. c.k., reaction is oh + hso;-^ h2 o

+ SO* at this pH.

Ref.

70-0302

73-1049

70-0302

70-0302

73-

1049 65-0190

65-0190

74-

1087 71-

0311,

72-

0066

73-1084

69-0144

69-0144

73-1031

71-0234

67-0273

67-0684

67-0684

67-0684

67-0273

67-0684

67-0684

64-0131

64-0131

57-0003

62-

7001

63-

0048

63-0048

63-0048

63-0048

63-0197

65-

0052

66-

0019

19
Table 3. Reactions of OH with inorganic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3. 106 cont. ~7 6.9 x 10 5 — p.r. opt. p.b.k.; see 66-0019

above.

0--0.8 — klk h,dr = 0.01 y-r. chem. c.k. 66-0029

0.3-2 1.2 x 10

6 (rel.) = 1-5 X y-r. opt. c.k. with 69-0279

10"4 Safranine T. 4 M 1.5 x 10 6 — p.r. opt. estd. from d.k. 73-1030

h 2 so4

For other ratios see: 3.26, 3.385, 3.511, 3.637.

SO;; 0.4k(OH + SO^ + k(H +

so;) = 3.3 x 109

.

3.107 s 2oJ- — — Won- = 1-2 -y-r. chem. c.k. 71-0927

OH + S 2 0

2 "^ 1.2 x 10

9 (rel.) = 1.3 S 2 0 3 + OH 3 x 10 9 (rel.) k/kfrOH = 1-9

1.6 x 10

9 (rel.) k/k 2-PrOH = 0.8 — (8 ± 1.5) x 109 ^/^cns = 0.78 p.r. opt. c.k. 73-1027

(rel.) 3.108 HSO”

OH + HSO5 —

>

— 3.5 x 10 8 (rel.) */*„rb = 0.97 p.r. opt. c.k. 69-0158

SO s + H2 0 or -» HSOs + OH3.109 s 2 o;- < 10

6 p.r. reaction not

obs.; c.k. with

CO2 ".

69-0158

3.110 H 2 Se 1.0 (1.0 ± 0.3) x 10 10 — p.r. opt. c.k.; rel. to 69-0564

OH + H2 Se (rel.) k(OH + CNS") = 6.6 HSe + H2 0 x 10

9

, k( OH + I") =

7.0 x 10

9

, k( OH +

Br") = 5.0 x 10

9

. 3.111 HSe" 8.5- (5.5 ± 0.1) x 10

9 — p.r. opt. c.k.; meas. H2 Se7 69-0564

OH + HSe 11.5 (rel.) at 410 nm; rel. HSe + OH" to k(OH + 2-PrOH)

1.3 x 10

9

, IdOH +

—

HCOO-) = 2.5 x 109

. 3.112 SeO 2 " 7 2.7 x 10

9 — p.r. opt. p.b.k. at 435 nm. 65-0190

7 4.6 x 10 9 (rel.) klk£t on = 2.46 p.r. opt. c.k. 65-0190

7 4.9 x 10 9 (rel.) ^/^MeOH =5.42 p.r. opt. c.k. 65-0190

3.113 Sm 2+ — 6 x 10

9 — p.r. opt. d.k. (Sm 2+

). 71-0311

OH + Sm 2+ —* 3-6 (6.2 ± 0.8) x 10

9 — p.r. opt. d.k. (Sm 2+ 73-1084

OH" + Sm3+ formed

in Sm 3+ soln.) 3.114 Sn 2+ 0.8 (1.6 ± 0.2) x 10

9 k/kfc 2+ = 7 ± y-r. chem. c.k. 59-0007

Sn 2+ + OH-* (rel.) 0.7 Sn 3+ + OH"

3.115 H 2Te0 3 + HTe03 0.4 ^pero* = 0.71 y-r. chem. c.k.; prelim. 67-0553

OH + Te(IV) -» value. Te(V) 0.4 ^p.ro, = 0.11 y-r. chem. c.k. 68-0356

3.116 TeO 2 " 10.7 3.5 x 10

9 (rel.) k/kc„b = 9.5 p.r. opt. c.k. 65-0190

3.117 Ti 3+ OH + Ti

3+ —

»

~1 1.2 x 10

9 (rel.) klk CNs~ = 0.11 p.r. opt. c.k. 72-0240

OH" + Ti

4+

3.117a Ti0(C 2 04) 2

2' OH + Ti0(C 2 04 ) 2

2" — — klk B - = 13 y-r. chem. c.k. 74-0521

—

Ti0(C 2 04) + C0 2 + C02 + OH

3.118 Tr 0.4 — klk Ce3+ = 38 y-r. chem. c.k. 56-0004

OH + Tl

+ (+ H+

) —

»

0.8 — k/k ce 3+ = 42 phot. chem. c.k. 57-7001

Tl

2+ + H2 0 0.8 — klk hyAr = 218 ± y-r. chem. c.k. 66-0029

60

6.5 (7.6 ± 1) x 10

9 — p.r. opt. p.b.k. at 260 nm. 66-0097

20
Table 3. Reactions of OH with inorganic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3. 118 cont. 1 (1.0 ± 0.1) x

10'° — p.r. opt. p.b.k.; cor. for 74-1017

H + Tl

2+

, OH +

Tl 2+

, OH + H, etc. For other ratios see : 3.294. 3.119 Tm(II)

OH + Tm(Il) —

OH + Tm(III)

3-6 (7 ± 1) x 10

9 p.r. opt. d.k. of Tm(II)

formed in Tm(III)

soln.

73-1084

3.120 U(IV) ~ 2 x 10 9 y-x. chem. estd. by c.k. with C 2 0

2-

; U(IV)

formed in U02

+

soln.

71-0542

3.121 vo 2+ OH + V02+ -^

acid — klk hyAr = 11 ±3 y-r. chem. c.k. 66-0029

V0 2

+ + H+ -1 2.5 x 108 (rel.) k/k cns- = 0 023 p.r. opt. c.k. 72-0240

3.122 Yb 2+ — 3 x 10

9 — p.r. opt. d.k. (Yb 2+

). 71-0311

OH + Yb 2+ —» OH - Yb 3+ 2 (3.2 ± 0.3) x 10

9 p.r. opt. d.k. (Yb 2+ formed on p.r. of Yb 3+ soln.).

73-1084

3.122a Zn 2+ OH + Zn 2+ —» OH + Zn 3+

< 5 x 10

s p.r. opt. c.k. with Cu 2+

. 75-1027

21
Table 4. Reactions of OH with organic solutes

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.123 acetaldehyde 1 5 x 10

8 (rel.) k/kfe 2+ = 2.2 Fenton ehem. c.k. 49-0002

3.124 acetamide 9

(I) OH + CH3CONH2 -+

1.3 x 10

7 (rel.) k/k^gt oH = 0-0071 y-r. opt. c.k. with RNO. 66-0423

H 2 0 + CH2 CONH2 5.5

(II) OH + CH3 CONH2

1.9 x 10

8 (rel.) klk CNS - = 0.017 p.r. opt. c.k. 70-0098

-» H2 0 + —

ch3 conh

1.9 x 10

8 (rel.) k/kcus~ = 0.017 p.r. opt. c.k.; k u = 9.5 x 10

7 by anal, of transient spectra.

71-0645

3.125 2-acetamido-2-

deoxy— dgalactose

1.6 x 10

9 (rel.) k/k CNS - = 0.147 p.r. opt. c.k. 70-3081

3.126 2-acetamido-2-

deoxy- dglucose

3.1 x 10

9 (rel.) klk cm

- = 0.279 p.r. opt. c.k. 70-3081

3.127 acetanilide 9 5 x 10

9 (rel.) k/k e,oh = 2.73 y-r. opt. c.k. with RNO. 66-0441

3.128 acetate ion 10.7 6.3 x 10

7 (rel.) klk BlQ - = 0.011 y-r. trac. c.k. ; meas.14 C02

. 65-0099

9.0 8.8 x 10

7 (rel.) k/k RN0 = 0.00

7

y-r. opt. c.k. 65-0356

9 7.2 x 10

7 (rel.) k/kfrOH ~ 0.039 y-r. opt. c.k. with RNO. 66-0423

nat. 7.0 x 10

7 (rel.) k/k (mo = 0.0075 p.r. opt. c.k. 71-0578 — 8.5 x 10

7 — p.r. opt. p.b.k. at 350 nm. 71-0578 — 1.2 x 10

8 (rel.) k/k x - = 0.0092 p.r. opt. c.k.; obs. I 2

. 73-0020

3.129 acetic acid 1.0 1.8 x 10

7 (rel.) k/k x - = (1.4 ±

0.2) x 10~3 p.r. opt. c.k. 65-0010

1 (9.2 ± 3.8) x 10

6 — p.r. opt. d.k. at 260 nm. 65-0010

1 2.3 x 10

7 (rel.) k/k CNS - = 0.0021 p.r. opt. c.k. 65-0387

2-2.2 2.3 x 10

7 (rel.) klk t hyn, = 0.0043 y-r. opt. c.k. 67-0461

1 2 x 10

7 (rel.) k/k thym = 0.0037 Fenton esr c-k.; k/k perm =

0.27.

69-5278

1 1.9 x 10

7 (rel.) k/k lhym = 0.0035 Ti(III) + H2 0

esr

2

c-k.; k/k

p„ox =

0.25.

69-5278

~0 — k 1 k acrylamide 0.01

Fenton pol. c.k. 72-9162

1 2.0 x 10

7 (rel.) k/k MeOH = 0.022 Fenton chem. c.k.

;

k MeOH 1 k pe 2 + = 4.3.

73-9341

3.130 acetoin 2.0 OH + CH 3CH(OH)COCH3

8.5 x 10

8 (rel.) klk CNS - = 0.077 p.r. opt. c.k. 65-0387

-» CH3 COHCOCH 3—

+ H,0

1.2 x 10

9 (rel.) klkcfis~ = 0. 1

1

p.r. opt. c.k. 68-0249

3.131 acetone 7 9.0 x 10

7 (rel.) */*,- = (7.5 ±

0.8) x 10'3 p.r. opt. c.k. 65-0010

10.7 9.1 x 10 7 (rel.) klk BM- = 0.016 y-r. trac. c.k.; meas. HC02

. 65-0099

6-7 9.7 x 10

7 (rel.) k/k cns- = 0.0088 p.r. opt. c.k. 65-0387

9 7.2 x 10

7 (rel.) k/k BlOB = 0.039 y-r. opt. c.k. with RNO. 66-0423

0.8 3.8 x 10

7 (rel.) k/k Fc 2 + = 0.165 Fenton chem. c.k. 66-9002

2-2.2 7.6 x 10

7 (rel.) k/k thym = 0.014 ± 0.0015

y-r. opt. c.k. 67-0461

9 ~ 7 x 10

7 (rel.) k/k rno ~ 0.0056 y-r. opt. c.k. 67-0555

nat. 1.2 x 10

8 (rel.) k/k tm.= 0.0129 p.r. opt

.

c.k. 71-0578

1 7.2 x 10' (rel.) k/k MeOH = 0.080 Fenton chem. c.k.

;

k MeOH Ik Fe- 1 = 4.3.

73-9341

3.132 acetone-c/6 1 2.3 x 10

7 (rel.) k/k MeOH = 0.026 Fenton chem. c.k.;

k MeOH Fe - + = 4-3.

73-9341

3.133 acetonitrile 9 3.6 x 10 6 (rel.) k/kfrOH = 0.0019 y-r. opt. c.k. with RNO. 66-0423 — 7.7 x 10

6 (rel.) k/k hcoo - = 0.0022 y-r. chem. c.k.; obs. f/(C0 2

). 73-0364 — 2.2 x 10 7 (rel.) k/k PNB,- = 0.0085 p.r. opt. c.k. 75-1003

3.134 acetophenone 9 4.8 x 10

9 (rel.) k/k e,qh = 2.6 y-r. opt. c.k. with RNO. 66-0441

OH + C 6 H 5 COCH 3 7 QHC 6 H s COCH3

(6.5 ± 0.7) x 10 9 p.r. opt. p.b.k. at 372 nm

(hydroxyxyxlo—

hexadienyl radical); cor. for (OH + OH) and

(H + aromatic).

68-0304

22
T \bi.e 4. Reactions of OH with organic solutes - Contin ued

No. Solute and Reaction pH A Ratjo Source Method Comment Ref.

3.134 cont. nat. 5.2 x 10

9 (rel.) = 0.56 p.r. opt. c.k. 71-0578 — 5.4 x 10

9 — P-r. opt. p.b.k. at 372 nm. 71-0578

3.135 /V-acetylalanine, 9.2 4.6 x 10 8 (rel.) A/A CNS - = 0.042 p.r. opt. c.k. 70-0099

negative ion 3.136 N—acetylalanyl- 9.0 3.0 x 10

9 — p.r. opt. p.b.k. 75-1004

aianylalanine,

negative ion 3.137 acetylene 2.15 — k/k HCOOH = 2. 1 y-r. chem. c.k. 68-0502

3.138 /V— acetylglucosamine 3. 1 x 10

9 (rel.)

4.2 x 10

8 (rel.)

k/k cns- = 0.279 p.r. opt. c.k.; unpubl.

data of G.O.

Phillips and

N. Worthington.

68-0352

3.139 /V-acetylglycine, 8.7 A/A cnS — = 0.038 p.r. opt. c.k. 70-0099

negative ion 7.8 x 10

8 3.140 /V-acetylglycylgly- 8.6 (rel.) A/A cns - = 0.071 p.r. opt. c.k. 70-0099

cine, negative

ion 4-(2-acetylsulfamoyl)phthalanilic acid See thalamyd (3.700). 3.141 acriflavin 1.2 x 10

10 p.r. opt. d.k. at 450 nm

(dye) or p.b.k.

at 300—400 nm.

70-0241

3.142 acrolein — 7.0 x 10

9 (rel.) kl^cNS ~ 0-54 p.r. opt. c.k. 70-0165

OH + CH 2 =CHCHO

adduct

3.143 acrylamide 10.7 3.4 x 10

9 (rel.) klk Bl0 - = 0-59 y-r. trac. c.k.; meas. HC0 2

. 65-0099

OH + 3.3 x 10

9 (rel.) ^/^cns — = 0-3 ± p.r. opt. c.k. 67-0171

CH2 =CHCONH2 ~6 0.07 —» adduct 7 4. 1 x 10 9 (rel.) klk Bz0 - = 0.72 r. lum. c.k.; salicylate detd. at 405 nm.

68-0494

-12 6.2 x 10

9 (rel.) klk carb = I? p.r. opt. c.k. at pH 10.9 and 12.9.

70-0052

nat. 4.7 x 10

9 (rel.) klk lcTTo = 0.505 p.r. opt. c.k. 71-0578 — 6.8 x 10

9 — p.r. opt. p.b.k. at 390 nm. 71-0578

For other ratios see: 3.129, 3. 145, 3.247, 3.283, 3.368. 3.452, 3.563. 3.144 acrylic acid 1 1.4 x 10

9 (rel.) k/kyicOH — 1-58 Fenton chem. c.k.; k MeO\\/k Fe^ + = 4-3.

73-9341

3.145 acrylonitrile -0 — k/ k acrylamide 1.8 k/k cns - = 0.08

Fenton pol. c.k. 72-9162

3. 146 adenine 2-2.2 8.8 x 10

8 (rel.) p.r. opt. c.k. 65-0388

OH + C 5 H 3 N 4 NH 2 5-5.5 3.8 x 10

9 (rel.) k/k cns - 0.35 p.r. opt. c.k. 65-0388 —* adduct 7.3- 5.1 x 10

9 (rel.) k/kcNs~ = 0.46 p.r. opt. c.k. 65-0388

7.5

7 2.8 x 10

9 (rel.) k/k CNS - = (0.25 p.r. opt. c.k.; cor. for 68-0316 ± 0.05) failure of H 2 02 to completely scavenge e aq . 5.7 (5.8 ± 0.3) x 10

9 — p.r. opt. p.b.k. at 450 nm. 70-3069

6-7 5.8 x 10

9 (rel.) k/k rno = 0.464 y-r. opt. c.k.; 17°C. 75-0294

3.147 adenosine 2-2.2 1.9 x 10

9 (rel.) k/kcNS~ = 0.17 p.r. opt. c.k. 65-0388

5-5.2 3.8 x 10

9 (rel.) k/k cns - = 0.35 p.r. opt. c.k. 65-0388

7.6- 4.2 x 1

0

9 (rel.) A/A cns- = 0.38 p.r. opt. c.k. 65-0388

7.8 3.148 adenosine 5' — 2-2.2 1.2 x 10

9 (rel.) A/A'cns- = 0.11 p.r. opt. c.k. 65-0381

phosphate (aden- 5.2- 3.0 x 10

9 (rel.) k/k cns = 0.27 p.r. opt. c.k. 65-0.3R1

ylic acid) 5.5 9 4.0 x 10

9 (rel.) k/k rno = 0.32 y-r. opt. c.k. 67-0551

6.9 (4.7 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 350 nm. 70-306'

7 4.7 x 10

9 — p.r. opt. p.b.k. 73-107

3.149 adipic acid 1 2.9 x 10

8 (rel.) A.'/Ap

e 2+ = 1.25 Fenton chem. c.k. 49-000

2-2.2 1.7 x 10

9 (rel.) k/k t hym = 0.32 ±

n m

y-r. opt. c.k. 67-046

23
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.150 alanine, positive 1 2.8 x 10 7 (rel.) k/k Fc 2 + = 0.12 Fenton chem. c.k. 49-0002

ion 2-2.2

1

4.8 x 10

7 (rel.) 4.4 x 10 7 (rel.) kIKhym = 0.0089

k/k liiym = 0.0082

y-r. Fentonopt. esr

c.k.

c.k.; klkpttox =

0.59.

67-0461

69-5278

3.151 alanine, zwitterion

6.0

5.5-6

6.8

4.6 x 10 7 (rel.)

7.7 x 10 7 (rel.) 7.9 x 10 7 (rel.)

k/k(crTO = 0.005

k/kCNS- = 0.00697

k/k rno = 0.0063

X-r.

p.r. y-r.

opt.

opt. opt.

c.k.; not cor. for H2 02

. c.k.

c.k.

62-0023

65-0388

73-0548

3.152 alanine, negative

ion

9.75 6.5 x 10 8 (rel.) klki'rro = 0.07 X-r. opt. c.k.; not cor. for H2 02

.

62-0023

3.153 alanine anhydride 5.0

11.0

1.8 x 10 9 (rel.) 1.8 x 10

9 (rel.)

k/kcm

- = 0.164

k/k CNS - = 0.164

p.r.

p.r.

opt.

opt.

c.k.

c.k. 71-0554

71-0554

3.154 alanylglycine,

positive ion

2-2.2 1.6 x 10

8 (rel.) k/klhym = 0.03 y-r. opt. c.k. 65-0388

3.155 ALDH (yeast alco— 9 1.6 x 10

11 (rel.) k/k Rfi 0 = 12.9 y-r. opt. c.k. 67-0555

hoi dehydrogenase) — 6.7 x 10

10 (rel.) 1.5 x 10 11 (rel.)

k/kcns— = 6.

1

k/k nb = 48

p.r. opt. c.k. 70-1226

3.155a aldolase 5.5 1.9 x 10 u

p.r. opt. p.b.k. at 330 nm; enzyme from rabbit muscle.

75-3058

3.156 allyl alcohol 7 2.0 x 10

9 (rel.) k/kcns - = 0.18 p.r. opt. c.k. 65-0387

OH + CH2 CHCH2 OH 7.0 ^ch,ohchch2 oh + ch2 chohch2 oh

(6.0 ± 1.5) x 10

9 p.r. opt. p.b.k. 73-1070

3.157 allylammonium ion 4 8.6 x 10

9 (rel.) k/k cns - = 0.785 p.r. opt. c.k. 70-0371

3.158 p— aminobenzoate 9

ion OH + NH2 C 6 H 4COCT ^

NH 2 (OH)C 6 H4COOH

7.9 x 10

9 (rel.) k/k e,oh = 4.3 y-r. opt. c.k. with RNO. 66-0441

3.159 p-aminobenzoic 6-7

acid OH + NH2 C 6 H4 COOH -> NH 2(OH)C 6 H4COOH

1.6 x 10

10 (rel.) ^/^CNS = 1-5 p.r. opt. c.k. 65-0387

3.160 2-aminobutyric

acid

2-2.2 3.8 x 10

8 (rel.) klk lhrm = 0.07 ±

0.005

y-r. opt. c.k. 67-0461

3.161 3-aminobutyric

acid

2-2.2 7.8 x 10

7 (rel.) klk thym = 0.0145 ± 0.0015

y-r. opt. c.k. 67-0461

3.162 4-aminobutyric

acid

2-2.2 2.2 x 10 8 (rel.) klk t hym = 0.040 ±

0.004

y-r. opt. c.k. 67-0461

3.163 2-amino-2-deoxyD-galactose — 1.2 x 10

9 (rel.) k/kcNs~ 0.106 p.r. opt. c.k. 70-3081

3.164 5-aminoindole 9.0 (3.17 ± 0.31) x

10'°

(rel.)

y-r. opt. c.k. with RNO;

rel. to /c(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.165 2-aminopyridine 9 8.4 x 10

9 (rel.) klk Rtio = 0.67 ±

0.12

y-r. opt. c.k. 69-0280

3.166 4-aminopyridine 9 5.0 x 10

9 (rel.) k/k^Q = 0.40 ±

0.01

y-r. opt. c.k. 69-0280

3.167 2-aminopyrimidine

amyl alcohol

tert- amyl alcohol

6-7

See 1 See 2

4.0 x 10

8 (rel.) -pentanol (3.602). -methyl-2-butanol

k/knfio = 0.032

(3.526).

y-r. opt. c.k.; 17°C. 75-0294

3.168 amylamine 7.9 x 10 9 (rel.) 9.0 x 10

9 (rel.) 5.8 x 10

9 (rel.)

klk (mo = 0.85

k/kcjis~ = 0.82

k/k nb = 2.8

p.r. opt. c.k.; calcd. from

obs. values at pH

8-13.1.

73-0016

3.169 amylammonium ion 4 9.8 x 10

9 (rel.) 5.6 x 10

9 (rel.) 4.7 x 10 9 (rel.) 2.8 x 10

9 (rel.)

k/kcns~ ~ 0-89

k/k u„0 = 0-6

k/k cns - = 0.43

k/k NB = 0.87

p.r.

p.r.

opt.

opt.

c.k.

c.k.; calcd. from

obs. values at pH

8-13.1.

70-0371

73-0016

24
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.170 aniline 10.7 7.1 x 109 (rel.) k/k Bl0 ~ = 1.24 y-x. trac. c.k.; meas.

14 C02

. 65-0099

OH + C6 H5 NH2 ^ 9 8.9 x 10

9 (rel.) ^/^EtOH == 4.8 y-x. opt. c.k. with RNO. 66-0441

C 6 HsNH + H2 0 or 7.5-9 2.9 x 10 10 (rel.) k/k CNS~ = 2.6 p.r. opt. c.k. 69-0573

-* OHC6 H5NH2 2.8 x 10

10 (rel.) k/k CNS~ = 2.58 p.r. opt. c.k. 72-0289

8,11 (1.4 ± 0.3) x

10*° p.r. opt. p.b.k. at 355 nm,

(cyclohexadienyl

radical), 295 nm

(anilino radical), and 500 nm.

72-0289

3.171 anilinium ion 3 5.4 x 10

9 (rel.) ^/^CNS~ = 0.49 p.r. opt. c.k. 69-0573

OH + C6H5 NH3+ ^ ~4 (4.8 ± 0.8) x 109 — p.r. opt. p.b.k. at 415 nm. 72-0289

C 6 H sNH2 + H2 0 or OHC6H5NH3 3.172 anisole 9 6.0 x 10

9 (rel.) ^/^EtOH == 3.27 y-r. opt. c.k. with RNO. 66-0441

OH + C6 H5 OCH3 -» 7 (12 ± 3) x 10

9 — p.r. opt. p.b.k. 68-0304

(OH)C 6Hs OCH3

9 5.7 x 10 9 (rel.) ^/^RNO = 0.45 ± y-r. opt.

at 330 nm; cor. for (OH + OH) and

(H + aromatic),

c.k. 69-0280

0.04

(5.4 ± 0.5) x 10

9 — p.r. — — 75-1171

3.173 anthranilic acid 1.1 x 10

10 — p.r. opt. p.b.k. 74-1063

3.174 9,10-anthra- 7.2 x 10 9 — p.r. opt. p.b.k. ~ 460 nm; 72-0391

quinone— 1—

sulfonate ion OH addn.

3.175 9,10-anthra- — 5.6 x 10

9 — p.r. opt. p.b.k. ~ 460 nm; 72-0391

quinone-2-

sulfonate ion OH addn.

3.176 9-anthroate ion 9 8.0 x 10

9 — p.r. opt. p.b.k. 73-0110

3.177 arginine 2-2.2 7.8 x 10

s (rel.) k/k u.ym = 0.145 y-r. opt. c.k. 65-0388

2-2.2 6.7 x 108 (rel.) k/k cns - = 0.061 p.r. opt. c.k. 65-0388

6.5- 3.5 x 10

9 (rel.) klk CNs~ = 0.32 p.r. opt. c.k. 65-0388

7.5 6.7 5.7 x 108 (rel.) klk^o = 0.045 y-r. opt. c.k. 73-0548

3.178 ascorbate ion 7 1.3 x 10

10 (rel.) k/k CNs~ = 1.17 p.r. opt. c.k. 72-0266

(H abstr.) 7 (1.1 ± 0.3) x 10

10 p.r. opt. p.b.k. at 360 nm;

also detd.

k/k phenylalanine =

1.0 ± 0.05.

73-3006

3.179 ascorbic acid 1 1.2 x 10 10 (rel.) k/kcns - = 1.1 p.r. opt. c.k. 65-0387

1.5 8.2 x 10

9 (rel.) k/k cns- = 0.75 p.r. opt. c.k. 72-0266

3.180 asparagine 2-2.2 3.2 x 10 7 (rel.) k/k,hym = (6.0 ± y-r. opt. c.k. 67-0461

0.5) x 10~3

6.6 4.9 x 10

7 (rel.) klk RN0 = 0.0039 y-r. opt. c.k. 73-0548

3.181 aspartic acid 2-2.2 3.3 x 10 7 (rel.) klktbyn, = 0.0061 y-r. opt. c.k. 65-0388

6.8-7 7.5 x 10

7 (rel.) k/k CNs~ 0.0068 p.r. opt. c.k. 65-0388

6.5 4.9 x 10

7 (rel.) k/k rN0 = 0.0039 y-r. opt. c.k. 73-0548

3.182 azelaic acid 2-2.2 4.6 x 10

9 (rel.) k/k lhym = 0.85 ± y-r. opt. c.k. 67-0461

0.10

3.183 Bacteriophage T7 ~5 x 10

9 (rel.) y-r. opt. c.k. with ferro- cyanide; obs.

G(ferri).

70-3048

3.184 benzaldehyde 9 4.4 x 109 (rel.) klk^No = 0.35 ± y-r. opt. c.k. 69-0280

0.03

3.185 benzamide 1 1.5 x 109 (rel.) k/k Fe 2+ --= 6.6 Fenton chem. c.k. 49-0003

9 4.4 x 10 9 (rel.) k/k EloH

-= 2.4 y-r. opt. c.k. with RNO. 66-0441

25
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.186 benzene 1 7.4 x 10" (rel.) k/kFf. 2+ = 3.2 Fenton chem. c.k. 49-0003

OH + C6H6 —» — (4.3 ± 0.9) x 10

9 — p.r. opt. p.b.k. at 313 nm. 62-0020

C 6 H6OH 3 (3.3 ± 0.8) x 109 — p.r. opt. p.b.k. at 313 nm. 64-0115

~7 3.7 x 10

9 (rel.) k!k x - = 0.31 ±

0.03

p.r. opt. c.k.; obs. I

2 at 400 nm.

65-0010

10.5 6.8 x 10 9 (rel.) k/k BiO — = 1-2 y-r. trac. c.k.; meas. wC02

. 65-0099

3 6.3 x 10 9 (rel.) ^/^BiOH —1*1 y-r. trac. c.k.; meas.

14C02

. 65-0099

6-7 5 x 10

9 (rel.) k/k cns— = 0.455 p.r. opt. c.k. 65-0387

~1 2.3 x 10

9 (rel.) klkFe 2+ = 6.7 y-r. chem. c.k. 66-0645

2-2.2 5.4 x 109 (rel.) k/k*ym = 1.00 ±

0.08

y-r. opt. c.k. 65-0388,

67-0461

9 3.2 x 109 (rel.) k/knrio — 0.26 y-r. opt. c.k. 67-0555

7 (7.8 ± 1.1) x 10

9 p.r. opt. p.b.k. at 313 nm;

cor. for (OH + OH)

and (H + aromatic).

68-0304

~1.2 4.8 x 10

9 (rel.) k/k 2-PrOH = 2.2 y-r. chem. c.k. 68-0602

6.98 5.1 x 10 9 (rel.) k/k 2—ptoh — 2.3 y-r. chem. c.k. 68-0602

9 4.4 x 109 (rel.) k/k RNo = 0.35 y-r. opt. c.k. 69-0280

7.0 7.5 x 10

9 (rel.) ^/^pnba - = 2.9 p.r. opt c.k.; formn. of 70-0211

PNBA~ — OH adduct

at 415 nm.

8.2 x 10

9 (rel.) ^/^cns - = 0.745 p.r. opt. c.k.; k lowered

in presence of surfactants.

71-0001,

71-0586

1. 7-1.8 4.4 x 10

9 (rel.) For other ratios see

:

3.12,

k/k

2

-ptoh ~ 2.0

3.52, 3.66, 3.78, 3.106,

Fenton chem.

3.667, 3.668, 3.711.

c.k. 74-9006

3.187 benzene-d6 OH + C 6 D6 —

c 6 d6oh

(4.7 ± 0.9) x 10

9 p.r. opt. p.b.k. at 313 nm. 62-0020

3.188 benzenesulfonamide 9 2.8 x 109 (rel.) klk Et0n =1.5 y-r. opt. c.k. with RNO. 66-0441

2.8 x 10

9 (rel.) y-r. opt. c.k. with RNO,

assuming k(OH +

sulfanilic acid) = 2.93 x 109

.

73-0094

3.189 benzenesulfonate 9 3.0 x 10

9 (rel.) k/kEto}i =1.6 y-r. opt. c.k. with RNO. 66-0441

ion 7 OH + C 6 H5 S03-»

ohc 6 h5 soj

(4.7 ± 0.6) x 109 p.r. opt. p.b.k.

at 315 nm; cor.

for (OH + OH) and

(H + aromatic).

68-0304

3.190 benzenesulfonic 1 acid

1.1 x 10

9 (rel.) k/k Fe 2+ = 4.7 Fenton chem. c.k. 49-0003

3.191 benzoate ion 6-7 5.5 x 10 9 (rel.) k/kcns — = 0.5 p.r. opt. c.k. 65-0387

OH + C 6 H5 COO~-» 9 4.2 x 10

9 (rel.) k/kEton = 2.3 y-r. opt. c.k. with RNO. 66-0441

OHC6 H5 COO" 6-9.4 (6.0 ± 0.7) x 10

9 p.r. opt. p.b.k. at 330 nm;

cor. for (OH + OH)

and (H + aromatic).

68-0304

5.5 6.4 x 10 9 (rel.) k/kfijj = 2.0 r. opt. c.k.; obs. formn.

of o-nitrophenol.

68-0494

9 4.6 x 109 (rel.) klk Eno = 0.37 ±

0.01

y-r. opt. c.k. 69-0280 — 3.2 x 10

9 (rel.) ^/^cns = 0.29 p.r. opt. c.k. 71-0282

nat. 5.4 x 10

9 (rel.) klk"m

= 0.581 p.r. opt. c.k. 71-0578 — 5.7 x 10 9 — p.r. opt. p.b.k. at 330 nm. 71-0578

2.5 x 10

9 (rel.) y—r. opt. c.k. with RNO

assuming k(OH +

sulfandic acid) = 2.93 x 10

9

. For other ratios see: 3.12, 3.21, 3.54, 3.66, 3.73, 3.128, 3.131, 3.143, 3.170,

3.186, 3.192, 3.193, 3.248, 3.358, 3.384, 3.406, 3.511, 3.565, 3.607, 3.608, 3.669.

73-0094

3.192 benzoic acid 1 1.6 x 10 9 (rel.) k/k Fe 2+ = 7.0 Fenton chem. c.k. 49-0003

OH + C 6 Hs COOH -» 3 HOC6H5 COOH

(2.1 ± 0.3) x 10

9 — p.r. opt. p.b.k. at 340-350

nm.

64-0115

26
Tabi.E 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.192 cont. 3 5.7 x lO’frel.) = 1 y-r. trac. c.k.; meas.

G(

14 C02

).

65-0099

3 (4.3 ± 0.8) x 10

9 p.r. opt. p.b.k. at 340 nm;

cor. for (H + BzOH)

and (OH + OH)

68-0229

3.193 benzonitrile 10.7 OH + C6 H s CN

3.4 x 10 9 (rel.) k/k Bzo~ = 0-59 y-r. trac. c.k.; meas.

G( 14C02

).

65-0099

OHC6 H 5 CN 9 3.6 x 10

9 (rel.) ^/^EtOH = 1-96 y-r. opt. c.k. with RNO. 66-0441

7 (4.9 ± 0.6) x 10

9 p.r. opt. p.b.k. at 348 nm;

cor. for (OH + O.H)

and (H + aromatic).

68-0304

6.3 8.5 x 10 9 — p.r. opt. p.b.k. 70-0657 — 3.8 x 10

9 (rel.) k/k cns - = 0.35 p.r. opt. c.k. 70-0657

3.194 benzophenone (8.7 ± 1.5) x 10

9 — p.r. opt. p.b.kj. at 380 nm. 68-0727

OH + C 6 H 5 COC 6 H5 -> C 6H5(OH)COC 6H5

(9 ± 2) x 10

9 — p.r. opt. p.b.k. at 330 nm. 75-1125

3.195 benzoquinone 1.2 x 10

9 — p.r. opt. p.b.k. (OH adduct) 67-0121

3.196 benzyl alcohol 7 OH + C 6 H 5 CH 2 OH

OHC6 H 5 CH 2 OH

(8.4 ± 1.2) x 10

9 p.r. opt. p.b.k. at 320 nm;

cor. for (OH + OH)

and (H + aromatic).

68-0304

9 4.6 x 10

9 (rel.) k/k rno = 0-37 ±

0.02

y-r. opt. c.k. 69-0280

3.197 benzylammonium ion 4 1.2 x 10

10 (rel.) k/k CNS - = 1-14 p.r. opt. c.k. 70-0371

3.198 /3-benzylglucoside ~7 4.2 x 10

10 (rel.) k/k cns - = 3.79 p.r. opt. c.k. 71-0480

3.198a benzyl methyl 1.7— 1.8 ether

1.2 x 10

10 (rel.) ^/^2-PrOH = 3.5 Fenton chem. c.k. with 1 —

phenylethanol.

74-9006

3.199 benzylpenicillin 7.1 x 10

9 (rel.) o ON 1 II

O. < y-r. opt. c.k. with RNO. 73-0134

3.200 benzylpenicjlloic acid

7. 1 x 10

9 (rel.) o ON l II

a. < y-r. opt. c.k. with RNO. 73-0134

3.201 benzyltrimethyl- 5.0 ammonium ion

6.8 x 10

9 (rel.) ^/^2-PfOH -3.1 r. chem. c.k. 68-0205

3.202 biacetyl

OH + CH 3 COCOCH 3 ^

h 2 o + CH 2 COCOCH3

1.6 x 10

8 (rel.) k/k cns - = 0-015 p.r. opt. c.k. 68-0249

3.202a biphenyl (9.0 ± 1.0) x 10

9 — p.r. opt. p.b.k. 75-1096

3.203 4-biphenylcarboxy- 9

late ion

6.8 x 10

9 — p.r. opt. p.b.k. 73-0110

3.204 2,2'-biphenyldi— 9

carboxylate ion (diphenate ion)

7.0 x 10 9 p.r. opt. p.b.k. 73-0110

3.205 4,4' — biphenyldi- 9 carboxylate ion

8.3 x 10 9 — p.r. opt. p.b.k. 73-0110

3.206 2,2'-bipyridine 9.3 6.2 x 10

9 — p.r. opt. p.b.k. 71-0582

3.207 4,4' — bipyridine 9.3 5.3 x 10

9 — p.r. opt. p.b.k. 71-0582

3.208 bromoacetate ion 9 4.4 x 10

7 (rel.) k/k EtOH = 0.024 y-r. opt. c.k. with RNO. 66-0423

3.209 p-bromobenzoate 9

ion

3. 1 x 10

9 (rel.) k/k eioh = 1-08 y-r. opt. c.k. with RNO. 66-0441

3.210 2-bromoethanol 7.8 x 10

8 (rel.) k/kfrOH = 0.42 y-r. opt. c.k. with RNO. 67-0050

3.211 5-bromoindole 9.0 (1.57 ± 0.18) x 10

10

(rel.)

y-r. opt. c.k. with RNO;

rel. to &(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.212 5-bromoorotate ion 7 3 x 10

9 — p.r. opt. p.b.k. at 340 nm. 73-0002

7 6.6 x 10

9 (rel.) k/k cNS — = 0.6 p.r. opt. c.k. 73-0002

3.212a l-(p-bromo- 1.7-1.

8

phenyl)ethanol

7.0 x 10

9 (rel.) k/kj-ptOH = 3.2 Fenton chem. c.k. 74-9006

3.213 m-bromophenyl-/!-

D-glucopyranoside

3.2 x 10

9 (rel.) — y-r. opt. c.k. with RNO;

k( OH + X) = 4.4 x

71-0056

1() 9 (X = phenyl-/3—

D-glucopyranoside)

as standard.

27
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.214 2-bromopropion— 8.5 2.2 x 10® (rel.) k/k EtOH = 0.12 y-r. opt. c.k. with RNO. 67-0050

ate ion 3.215 3-bromopropionate 8.5 2.2 x 10® (rel.) klk£t on = 0.12 y-r. opt. c.k. with RNO. 67-0050

ion 3.216 2-bromopyridine 9 2.4 x 10

9 (rel.) = 0.19 ± y-r. opt. c.k. 69-0280

0.01 3.217 3-bromopyridine 9 1 . 1 x 10 9 (rel.) klk^o := 0.09 ± y-r. opt. c.k. 69-0280

0.01 3.218 a-bromotetronate 7 7.7 x 10

9 — p.r. opt. d.k. at 258 nm 74-1053

ion as well as p.b.k.

OH + C 4 H 2 Br0 3 at 360 nm.

-* HBr + C 4 H 2 04 3.219 5-bromouracil (BU) 9 4.2 x 10

9 (rel.) ^'/^RNO

:= 0.34 r. opt. c.k. 67-0555

OH + BU -> BUOH 7.0 3.6 x 10 9 — p.r. opt. p.b.k. at 335 nm;

complex kinetics.

69-0558

7 4.0 x 10

9 (rel.) k/kcNS~ = 0.364 p.r. opt. c.k. 72-0049

7 5.6 x 10

9 — p.r. opt. p.b.k. at 340 nm. 72-0049

11 5.8 x 10

9 — p.r. opt. p.b.k. at 340 nm. 72-0049

3.220 1,3-butadiene 7.7 x 10

9 (rel.) klky- = 0.64 p.r. opt. c.k.; obs. formn.

of 1 2 at 400 nm.

67-0041

3.221 1,2-butanediol 1 4.4 x 10

6 (rel.) k/k pe 2+ = 0.019 therm. chem. c.k.; persulfate

oxidation.

49-0002

3.222 1 ,3-butanediol 7 2.2 x 10

9 (rel.) k/k cns - = 0.197 p.r. opt. c.k. 65-0387

9 2.4 x 10

9 (rel.) k/kfaQH = 1.3 y-r. opt. c.k. with RNO. 66-0423

3.223 1 ,4-butanediol 7 3.2 x 10

9 (rel.) k/k Cfis~ = 0.29 p.r. opt. c.k. 65-0387

9 3.0 x 10

9 (rel.) k/k EtOH = 1.6 y-r. opt. c.k. with RNO. 66-0423

3.224 2,3-butanediol 1 2.3 x 10

6 (rel.) k/kfc 2+ = 0.010 therm. chem. c.k.; persulfate 49-0002

(I) OH + (MeCHOH) 2 —* oxidation. MeCHOHCOHMe 7 1.3 x 10

9 (rel.) k/k cns - = 0.12 p.r. opt. c.k. 65-0387 + H 2 0 — — klllky = 0.41 p.r. opt. detd. % a-alcohol 73-0126

(II) OH + (MeCHOH) 2 radical by react- -* CH 2 CHOHCHOHMe + ion with TNM;

h 2 o =£0.1% alkoxy

radical detd. by

reaction with I 3.225 1-butanol 2-2.2 4.6 x 10

9 (rel.) k1 k := 0.85 ± y-r. opt. c.k. 67-0461

(I) OH + C 3 H 7 CH 2 OH 0.08 H 2 0 + 5-5.5 4.6 x 10

9 (rel.) k/k |hym

:= 0.85 ± y-r. opt. c.k. 67-0461

C 3 H 7 CHOH 0.10 (34%, 69-0522) 7 4.0 x 10

9 (rel.) k/k C i rb == 11 p.r. opt. c.k. 65-0190

(II) OH + C 3 H 7 CH 2 OH 7 3.7 x 10

9 (rel.) k/k cns

- = 0.34 p.r. opt. c.k. 65-0387

H 2 0 + 9 3.7 x 10

9 (rel.) k/k EtOH = 2 y-r. opt. c.k. with RNO. 66-0423

CH 3 CH2CHCH 2 OH nat. 4.0 x 10

9 (rel. ) k/k(c no == 0.43 p.r. opt. c.k. 71-0578

+CH 3 CHCH 2 CH 2 OH . k\nlki ^0.1 p.r. opt. detd. % a-alcohol 73-0126

+CH 2 CH 2 CH 2 CH 2 OH ku/ky - 1.4 and alkoxy radicals by reaction with

(III) OH + TNM and I”, resp. C 3 H 7 CH 2 OH-* — 6 x 10

8 (rel.) k/k MeOH = 0.62 Ti(III) esr c.k. 73-5253

h 2 o + c 3 h 7 ch 2 o

For other ratios see

:

3.310.

+ h 2 o2

3.226 2-butanol 2-2.2 2.7 x 1() 9 (rel.) k/k Ihym = 0.50 ± y-r. opt. c.k. 67-0461

OH + C 2 H s CHOHCH 0.05 -» H 2 0 + 7 3.1 x 10

9 (rel.) k/k cns

-- = 0.28 p.r. opt. c.k. 65-0387

C 2 H s COHCH 3 9 (53%, 69-0522) + CH 3 CHCHOHCH3 , etc.

2.4 x 10

9 (rel.) k/k EtOH = 1.3 y-r. opt. c.k. with RNO. 66-0423

/er/-butanol .See 2 -methyl-2-propanol (3.546). 3.227 2-butanone 6-7 9.0 x 10® (rel.) k/k CNS

- = 0.082 p.r. opt. c.k. 65-0387

28
Tabu: 4. Reactions of OH with organic solutes — Contin ued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.228 1-butene 7.7 x 10 9 (rel.) ft/it,- = 0.64 p.r. opt. c.k. ; obs. formn.

of I 2 at 400 nm.

67-0041

3.229 l-butene-3-one 8.5 x 10

9 (rel.) ^/^cns — = 0.77 p.r. opt. c.k. 70-0165

3.230 (V-tert-butylaceta— 5—6

mide

ter/-butyl alcohol See 2

1.1 x 10

9 (rel.) k/k CNS - = 0. 103 ±

0.01 -methyl— 2-propanol (3.546).

p.r. opt. c.k. 71-0414

3.231 butylamine 7.3 x 10

9 (rel.) 8.3 x 10 9 (rel.) 5.4 x 10

9 (rel.)

k/k (mo = 0.79 k/kcNS~ = 0.75

k/k NB =1-7

p.r. opt. c.k.; calcd. from

obs. values at pH 8-13.1.

73-0016

3.232 tert-butylamine 12 OH + (CH3 ) 3 CNH2 -* h 2 o + •CH 2(CH 3 ) 2 CNH 2 + (CH 3 ) 3CNH

6.0 x 10

9 (rel.) p.r. opt. c.k., extrapolated value based on

k/kcfis~ ~ 3.64 x

10”' (obs.) at pH 10.9.

71-0585

3.233 butylammonium ion 4 5.5 x 10

9 (rel.) k/kcns~ = 0.5 p.r. opt. c.k. 70-0371

2.8 x 10

9 (rel.) 3. 1 x 10 9 (rel.) 2.05 x 10

9 (rel.)

k/k {mo = 0.3

&/A.'cns — = 0.28

k/k m = 0.64

p.r. opt. c.k.; calcd. from obs. values

at pH 8—13.1.

73-0016

3.234 /ert-butylammonium 4 2.4 x 10

8 (rel.) k/k CNS - = 0.022 p.r. opt. c.k. 70-0371

ion 3.2 7.0 x 10

8 (rel.) oh + (Ch3 ) 3 cnh;-^

h 2 o + •CH 2(CH3) 2 CNH3 butyleneoxide-1,2 See 1,2-epoxybutane (3.352).

k/k CNS- = 0.0636 p.r. opt. c.k. 71-0585

3.235 tert — butyl mercap— 7 tan OH + (CH 3 ) 3 CSH -» H 2 0 + (CH 3 ) 3 CS

1.9 x 10

10 (rel.) k/kcus~ = 1-7 p.r. opt. c.k. 69-0553

3.236 p-terf-butylphenol 9 1.9 x 10

10 (rel.) k/k rno = 1-49 ±

0.26

y-r. opt. c.k. 72-0837

3.237 butyraldehyde 2.0 3.8 x 10

9 (rel.) k/kcNs~ = 0.35 p.r. opt. c.k. 65-0387

3.238 butyrate ion 9 1.85 x 10

9 (rel.) k/k £,OH = 1 y-r. opt. c.k. with RNO. 66-0423

3.239 butyric acid 1 1.6 x 10

8 (rel.) k/kFe 2+ = 0.72 Fenton chem. c.k. 49-0002

2-2.2 1.9 x 10

9 (rel.) klk thym = 0.35 ±

0.03

y-r. opt. c.k. 67-0461

3.240 carbon disulfide 7.6 OH + CS 2 -^ CS 2 OH

^CSO- + H +

8.0 x 10

9 (rel.) k/kctis~ ~ 0.73 p.r. opt. c.k.; meas. abs. increase at 280 nm (CS 2 OH) or

at 500 nm.

67-0687,

73-1015

3.241 carboxymethylcellulose (polyanion)

2.6 x 10

9 (rel.) k/kcN&~ = 0.24 p.r. opt. c.k.; concn. in monomer units.

68-0352

3.242 carboxypeptidase A 7.8 (6.9 ± 1.0) x 10

10 p.r. opt. p.b.k. at 320 nm;

contains ~ 15% H

reaction product.

73-1060

3.243 catalase 1.4 x 10

11 (rel.) klkcns~ = 12.58 p.r. opt. c.k.; mol.

wt. 2.5 x 10

s

.

66-0499

3.244 cellobiose 6.5 3.6 x 10

9 (rel.) k/k rno = 0.29 ±

0.01

y-r. opt. c.k. 69-0580

3.245 chloral hydrate 1 1. 1 x 10

9 (rel.) klk rc 2 + = 4.7 Fenton chem. c.k. 49-0002

OH + CC1 3 CH(0H)2

. ^H2 0 + CC13C(0H)23.15 x 10

9 (rel.) k/k CNS - = 0.285 p.r. opt. c.k. 73-0062

3.246 chloroacetate ion 9 5.5 x 10 7 (rel.) k/k eioh = 0.0296 y-r. opt. c.k. with RNO. 66-0423

(I) OH + C1CH 2 C00"6.5 — H 2 0 + C1CHCOCT

6 x 10

9 (I) (rel.) 1.5 x 10 8 (II) (rel.) kjk u = 4.0

k nl

k

MeOH s 0.08

y-r. chem. c.k. 69-0422

(II) OH + CICH 2 COO~

-» cr + products

29
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH^ A Ratio Source Method Comment Ref.

3.247 chloroacetic 2-2.2 8.1 x 10 7 (rel.) klk lhym = 0.015 ± y-r. opt. c.k. 67-0461

acid 0.0015

1 4.3 x 10 7 (rel.) A/ACNS - = 0.00394 p.r. opt. c.k. 65-0387

~0 — kfk’acrylamide Fenton pol. c.k. 72-9162

0.012

3.248 chlorobenzene 10.7 6.3 x 10

9 (rel.) 03 o

II o y-r. trac. c.k. ; meas.

14 C02

. 65-0099

9 4.5 x 10

9 (rel.) ^/^RNO — 0.36 ± y-r. opt. c.k. 69-0280

0.05 3.248a o— chlorobenzoate 7 6.8 x 10 9 (rel.) k/k 2-PrOH = 3.1 y-r. chem. c.k. 74-0167

ion 3.248b m-chlorobenzoate 7 6.3 x 10

9 (rel.) ^'/A 2-PrOH = 2.8 y-r. chem. c.k. 74-0167

ion 3.249 p—chlorobenzoate 9 3.2 x 10

9 (rel.) ^/^EtOH = 1-75 y-r. opt. c.k. with RNO. 66-0441

ion 6-9.4 (5.0 ± 0.8) x 10

9 — p.r. opt. p.b.k. at 345 nm; 68-0304

OH + C1C 6 H 4C00' cor. for (OH + OH)

Cl(OH)C 6 H4 COO" and (H + aromatic).

7 7.3 x 10 9 (rel.) 2-PrOH = 3.3 y-r. chem. c.k. 74-0167

3.250 2— chloroethanol — 9.25 x 10

8 (rel.) ^/^EtOH = 8-5 y-r. opt. c.k. with RNO. 67-0050

3.251 chloroform 0.4 1.0 x 10' (rel.) A/A Fe 2+ = 0.043 /3-r. chem. c.k. 60-0016

OH + CHC1 3 -^ 0.4 5.3 x 10 6 (rel.) A/A Fe 2+ = 0.023 Fenton chem. c.k. 60-0016

h 2 o + CC13 9 1.4 x 10

7 (rel.) ^/^eioh = 0.0077 y-r. opt. c.k. with RNO. 66-0423 — 7.4 x 10

6 (rel.) — r. chem. c.k. with Fe

2+

. 66-9002

5.5- ~ 5 x 10

6 (rel.) — y-r. chem. est. from effect 70-0013

5.8 of Fe

2+ on G(C1 ). 3.252 5— chloroindole 9.0 (1.91 ± 0.04) x

10'° — y-r. opt. c.k. with RNO; 71-0556

(rel.) rel. to A(OH + tryptophan) = 1.25 x 10

10

. 3.253 m—chlorophenol 9 7.2 x 10

9 (rel.) k/k RNO = 0.58 ± y-r. opt. c.k. 72-0837

0.05 3.254 o-chlorophenol 9 8.2 x 10

9 (rel.) k/k rno = 0.66 ± y-r. opt. c.k. 72-0837

0.12 3.255 m-chlorophenyl— — 3.2 x 10

9 (rel.) — y-r. opt. c.k. with RNO; 71-0056

/3— D -glucopyrano- rel. to phenyl—

side (3— r> — glucopyranoside

(X); A(OH + X) =

4.4 x 10

9

. 3.256 p— chlorophenyl— — 3.4 x 10

9 (rel.) -

y-r. opt. c.k. with RNO; 71-0056

/3-n-gluco- relative to phenylpyranoside /3— I) -glucopyranoside

(X); A(OH + X) =

4.4 x 10

9

. — 5.7 x 10

9 (rel.) A/A CNS - = 0.515 p.r. opt. c.k. 71-0056

3.257 2-chloropropionate 8.5 2.4 x 10

8 (rel.) k/k eioh = 0.13 y-r. opt. c.k. with RNO. 67-0050

ion 3.258 3— chloropropion— 8.5 3.1 x 10

8 (rel.) k/kfroH = 0.17 y-r. opt. c.k. with RNO. 67-0050

ate ion 3.259 2— chloropyridine 9 1.75 x 10 9 (rel.) ^/^RNO = 0. 14 ± y-r. opt. c.k. 69-0280

0.01 3.260 4— chloropyridine 9 3. 1 x 10

9 (rel.) k/k rno = 0.25 ± y-r. opt. c.k. 69-0280

0.01 3.261 chlorotrifluoro- — - 5 x 10

8 (rel.) — — — c.k. with BzO ; 70-0407

methane cited from

unpubl. data. 3.262 5— chlorouracil 7 5.2 x 10 9 (rel.) k/k cns - = 0.472 p.r. opt. c.k. 72-0049

7 5.5 x 10

9 — p.r. opt. p.b.k. at 340 nm. 72-0049

11 5.8 x 10

9 — p.r. opt. p.b.k. at 340 nm. 72-0049

3.263 chondroitin — 8.0 x 10

8 (rel.) ^/^cns - = 0.0/3 p.r. opt. c.k.; concn. of 70-3081

4—sulfate I polyanion in hexose units. 3.264 chondroitin — 6.8 x 10 8 (rel.) A/A Cns~ = 0.062 p.r. opt. c.k.; concn. in 70-3081

6-sulfate I hexose units.

30
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.265 a—chymotrypsin 6.6 3.5 x 10 10 (rel.) ^/^RNO = 2.8 -y-r. opt. c.k. 73-0548

3.266 citric acid 2-2.2 5.4 x 10

8 (rel.) kIKhyn. = 0.10 ±

0.051

y-r. opt. c.k. 67-0461

1 5.0 x 10

7 (rel.) k/k CNS — = 0.00455 p.r. opt. c.k. 65-0387

3.267 collagen 4.0 x 10 u

(rel.) p.r. opt. c.k. with CNS ; reference rate not

given; mol. wt. 360,000.

68-3007

3.268 o—cresol 9 1.1 x 10 10 (rel.) k/k rno = 0.90 ±

0.15

y-r. opt. c.k. 72-0837

3.269 p-cresol 9 1.3 x 10

10 (rel.) k/k rno = 1 -04 ±

0.09

y-r. opt. c.k. 72-0837

5.5 (1.2 ± 0.2) x

10'°

(rel.) klkcns— = 1.1 p.r. opt. c.k. 73-0003

3.270 crotonaldehyde 5.8 x 10

9 (rel.) ^/^cns — = 0.53 p.r. opt. c.k. 70-0165

3.271 crotonic acid 1 2.7 x 109 (rel.) klk MeOH =2.96 Fenton chem. c.k.; ^m.oh/^f. 2+ = 4.3.

73-9341

3.272 cyanoacetate ion 9 1.6 x 10 7 (rel.) k/k e,oh = 0.0084 y-r. opt. c.k. with RNO. 66-0423

3.272a cyanocobalamin 6.5 x 10 9 — p.r. opt. p.b.k. at 310—330

nm.

74-1105

3.273 5-cyanoindole 9.0 (1.06 ± 0.24) x 10

10

(rel.)

y-r. opt. c.k. with RNO;

rel. to &(OH + tryptophan) = 1.25 x 10

10

.

71-0556

3.274 l-(p-cyano- 1.7-1.

8

phenyl)—

ethanol

3.3 x 10

9 (rel.) k/k^o = 1.3 Fenton chem. c.k. with 1—

phenylethanol.

74-9006

3.275 p—cyanophenyl—

/?- D -glucopyranoside

3.5 x 10

9 (rel.) y-r. opt. c.k. with RNO;

rel. to &(OH + X) =

4.4 x 10

9

, X =

phenyl-/?- d —glucopyranoside.

71-0056

3.276 cyclobutane- 9

carboxylate ion

3.0 x 10

9 (rel.) k/k eioh = 1-6 y-r. opt. c.k. with RNO. 66-0423

3.277 cycloheptanol 1. 7-1.8 2.0 x 10

9 (rel.) klk 2-PrOH =0.91 Fenton chem. c.k. 74-9006

3.278 cycloheptanol- 1.7-1.

8

1 -d

1.5 x 10

9 (rel.) ^/^2-PrOH = 0.70 Fenton chem. c.k. with 1—

phenylethanol.

74-9006

3.279 cycloheptatriene (7 ± 2) x 109 (rel.) p.r. opt. c.k. with CNS”;

reference rate not given.

71-0710

3.280 1,3-cyclohexadiene 7.0 OH + C 6 H8 -+ h2 o + C 6 H 7 and C 6 H8OH

1 x 10

10 (rel.) ^/^PNBA - = 3-8 p.r. opt. c.k., formn. of PNBA~-OH adduct

at 415 nm; 30%

H abstraction.

70-0211

3.281 1,4-cyclohexadiene 7.0 OH + C 6H8 — H2 0 + C 6 H7 and C 6 H8 OH

7.7 x 10v (rel.) k/k pnba - = 2.96 p.r. opt. c.k.; formn. of PNBA'-OH

adduct at 415 nm; 45% H abstraction.

70-0211

3.282 cyclohexanecar- 9

boxylate ion

5.4 x 109 (rel.) klk^toH =2.9 y-r. opt. c.k. with RNO. 66-0423

3.283 /rans-l,2-cyclo- ~0

hexanediaminetetraacetic acid

k/k tCryUmlde =

2.0

Fenton pol. c.k. 72-9162

3.284 cyclohexene 7.0 OH + C6 H 10 —

H 2 0 + c 6 h.

8.8 x 10

9 (rel.) ^/^PNBA~ = 3-4 p.r. opt. c.k.; formn. of PNBA'-OH

adduct at 415 nm.

70-0211

31
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.285 cyclohexylammonium 4 1.0 x 10

10 (rel.

)

k\kCNS - = 0.96 p.r. opt. c.k. 70-0371

ion 3.286 cyclopentane

OH + C S H 10 -*

3.0 x 109 (rel.) k/k PNBA~

- = 1.15 p.r. opt. c.k. 74-1052

h 2 o + c 5 h.

3.287 cyclopenlanecar— 9 4.1 x 10

9 (rel.) k/k EtOH

== 2.2 y-r. opt. c.k. with RNO. 66-0423

boxylate ion 3.288 cyclopentene 7.0 x 10

9 (rel.) k/k CNS - = 0.64 p.r. opt. c.k. 74-1052

3.289 cysteamine (cyst) 1.4 1.6 x 10

10 (rel.) k/k CNS - = 1.44 p.r. opt. c.k. 67-0554

OH + 6.5, 9 1.4 x 10

10 (rel.) k/k CNS - = 1.29 p.r. opt. c.k. 67-0554

nh2 ch>ch2 sh 1 1.9 x 10

lo (rel.) kI k = 3.5 Fenton esr c.k.; kjk^ = 69-5278

-> NH 2CH2CH2S 251. + h2 o k/

k

urttc ii == 3.45 p.r. esr c.k. 72-3003

For other ratios see: 3.627. 3.290 cysteine 1 1.3 x 10

10 (rel.) k/kcfis~ = 1.2 p.r. opt. c.k. 65-0387

2-2.2 5.9 x 10

9 (rel.) k/k , hym = 1.10 ± y-r. opt. c.k. 67-0461

0.10

ca. 3.4 x 10

9 — p.r. opt. p.b.k. 69-0638

1 8.5 x 10

9 (rel.) k/k t hym = 1.53 Fenton esr c-k.; k/k^ =

112.

69-5278

7 4.0 x 10

lo (rel.) k/k lhim = 7.42 p.r. esr c.k. 72-3003

7 k1 k UTEC{\ == 6.21 p.r. esr c.k. 72-3003

0.4 1.7 x 10

lo (rel.) k/k cns - = 1.5 p.r. opt. c.k.; ± 15%; 73-0090

5.8 1.9 x 10

10 (rel.) k/kCfis~ = 1.7 not cor. for 9.8 1.8 x 10

10 (rel.) k/kcMS~ = 1.6 ionization; pKm =

10.8 1.8 x 10

10 (rel.) k/k cns - = 1.6 1.8, 8.3, 10.8. 3.291 cystine 2 k/k c

]— = 24 y-r. chem. c.k. 63-0127

2-2.2 6.5 x 10

9 (rel.) klk t hym = 1.03 y-r. opt. c.k. 65-0388

ca. 3-4 x 10

9 — p.r. opt. p.b.k. 69-0638

1 9.6 x 10

9 (rel.) k/k (hym = 1.76 Fenton esr c.k.; k/k^„

= 130.

69-5278

6.5 2.1 x 10

9 (rel.) k/k rno = 0.168 y-r. opt. c.k. 73-0548

3.292 cytidine 2-2.2 3.3 x 10

9 (rel.) klk Ct4s~ = 0.303 p.r. opt. c.k. 65-0388

5.2- 5 x 10

9 (rel.) k/k CNs~ = 0.45 p.r. opt. c.k. 65-0388

5.4 7.2- 4.6 x 10

9 (rel.) k/k cns - = 0.42 p.r. opt. c.k. 65-0388

7.4

5.6 (6.4 ± 0.2) x 10

4 p.r. opt. p.b.k. at 350 nm. 70-3069

7 5.8 x 10

9 — p.r. opt. p.b.k. (OH addn.) 73-1071

3.293 cytidine-5'- 2-2.2 2.5 x 10* (rel.) k/k cns - = 0.23 p.r. opt. c.k. 65-0388

phosphate 7. 4-7. 6 4.4 x 10

9 (rel.) k/k cns - = 0.4 p.r. opt. c.k. 65-0388

(5'— cytidylic 7.3 (4.9 ± 0.2) x 10

9 — p.r. opt. p.b.k. at 425 nm. 70-3069

acid) 7 4.7 x 10

9 — p.r. opt. p.b.k. at 425 nm

(OH adduct).

73-1071

3.294 cytochrome C 5-10 k/khyi, — 500 X-r. chem. c.k. 62-3002

(ferri) 5.5 x 10

l ° (rel.) k/kj^+ = 5.5 y-r. opt. c.k.; absorbance 67-3020

change at 550 nm; assume = 10

10

; k(OH + Fe

2+ cytC) =

4.6 x 10

10

1.4 x 10

10 p.r. opt. p.b.k. at 550 nm;

cor. for H + H,

H + OH, H + cyt C

by computer anal.

72-1002

5.4, 2.7 x 10

10 (rel.) 7

k/k thym 5 ± 1 y-r. opt. c.k. 72-3071

i 6.3 6.1 x 10

l °(rei.) k/k rno = 4.1 y-r. opt. c.k. 73-0548

3.295 cytosine 2-2.2 3.1 x 10

9 (rel.) k/k cns - = 0.28 p.r. opt. c.k. 65-0388

5-6 4.5 x 10* (rel.) k/kcNS~ = 0.41 p.r. opt. c.k. 65-0388

7.4- 4.9 x 10

9 (rel.) k/k cns - = 0.447 p.r. opt. c.k. 65-0388

7.6

11.4 57x 10

9 p.r. opt. p.b.k. at 335 nm. 68-0597

32
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.295 cont. 5.8 (6.2 ± 0.4) x 109 — p.r. opt. p.b.k. at 450 nm. 70-3069

7 (6.8 ± 0.5) x 10

9 — p.r. opt. p.b.k. 73-1071

6-7 4.0 x 10

9 (rel.) k/k RNO == 0.32 y-r. opt. c.k.; 17°C. 75-0294

3.296 deoxyadenylic 2-2.2 1.4 x 10

9 (rel.) k/k cns - = 0.124 p.r. opt. c.k. 65-0388

acid 6.4- 3.5 x 10

9 (rel.) klk Cns~ = 0.32 p.r. opt. c.k. 65-0388

6.6 3.297 deoxycytidylie 2-2.2 3.0 x 10 9 (rel.) k/kCNS — = 0.27 p.r. opt. c.k. 65-0388

acid 4. 3-4.5?’3.8"xlo9

(rel.)l; klk Cns~ = 0.35 p.r. opt. c.k. 65-0388

6.7-7 5.0 x 10

9 (rel.) k/k cNS — = 0.455 p.r. opt. c.k. 65-0388

7 4.9 x 10

9 — p.r. opt. p.b.k. 73-1071

3.298 deoxyguanylic 2-2.2 4.6 x 10

9 (rel.) klk ctiS — = 0.42 p.r. opt. c.k. 65-0388

acid 6.5-7 6.8 x 10

9 (rel.) k/k CNS — = 0.62 p.r. opt. c.k. 65-0388

3.299 deoxyribose — 1.9 x 10

9 — — — — 66-0845

3.300 2—deoxy-2-sulfo- — 2.1 x 10 9 (rel.) k/k CNS— = 0.192 p.r. opt. c.k. 70-3081

amino—

D

-glucose

3.301 dextran 7 > 10

9 (rel.) p.r. opt. c.k. with CNS",

BzO", RNO;

k varies with chain

length; k per monomer unit.

70-0394

diamide See N,N,N',N'—tetramethyl— 1,2—diazenedicarboxamide (3.696). 3.301a di— ferf-butyl — (6.5 ± 1.5) x 10

9 — p.r. opt. p.b.k. 75-1089

disulfide OH + C 4 H9 SSC 4 H9 OH" + RSSR +

3.302 1 , 1 -dichloroethyl- — (4.1 ± 0.4) x 10

9 — p.r. opt. c.k. with CNS"; 71-0709

ene (rel.) reference rate OH + CH2 =CC12 ^ not given.

ch 2 ohcci2 3.303 1,2-dichloroethyl- — (5.0 ± 0.4) x 10

9 — p.r. condy. p.b.k. (Cl ); 71-0709

ene (CHClOHCHCl

OH + CHC1=CHC1 H

+ + C1 + CHCl(OH)CHCl

(4.4 ± 0.4) x 109 p.r. opt. CHOCHC1).

c.k. with CNS"; 71-0709

(rel.) reference rate not given. 3.304 1,4-dicyano— — (7.2 ± 0.7) x 10

8 klk}Aeo}\ = 0.8 p.r. opt. c.k.; obs. 73-0121

benzene (rel.) buildup of OH

OH + C 6 H4(CN) 2 -» adduct at 370 nm. C 6 H 4OH(CN)2 3.305 1,2— diethoxy- 9 2.2 x 10

9 (rel.) k/k EtOH

:= 1.2 y-r. opt. c.k. with RNO. 66-0423

ethane

3.306 diethoxymethane 9 1.6 x 10

9 (rel.) klk EtOH

:= 0.84 y-r. opt. c.k. with RNO. 66-0423

3.307 diethylammonium 1 9.2 x 10

7 (rel.) k/k Ee 2+ = 0.4 Fenton chem. c.k. 49-0002

ion 3.307a diethyl disulfide — (1.4 ± 0.5) x 10

l ° — p.r. opt. p.b.k. 75-1089

OH + C 2 H 5 SSC 2 H5 —> OH" + RSSR +

3.308 diethyleneglycol 9 2.0 x 109 (rel.) k/k ElOH = 1.1 y-r. opt. c.k. with RNO. 66-0423

3.309 diethyleneglycol 9 3.1 x 10

9 (rel.) k/k e,oh = 1.7 y-r. opt. c.k. with RNO. 66-0423

diethyl ether

3.310 diethylenetri- 6.0 1.6 x 10

9 (rel.) k/k(eTTO == 0.17 y-r. chem. c.k.; obs. 72-0169

aminepentaacetic k/k buoh = 1.36 G(-DTPA).

acid k/k ,_buOH “ 8.6 OH + DTPA -» H 2 0 + C0 2 + prod. 3.311 diethyl malonate 6-7 6.5 x 10

8 (rel.) k/k CNS = 0.0591 p.r. opt. c.k. 65-0387

3.312 diethyl succinate 6-7 7.8 x 10

8 (rel.) k/k CNS~ = 0.071 p.r. opt. c.k. 65-0387

3.313 1,2-difluoroben- — 4.5 x 109 (rel.) — p.r. opt. c.k. with CNS"; 73-0054

zene reference rate not given.

33
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.314 1,4-difluoroben— 6 x 10 9 (rel.) — p.r. opt. c.k. with CNS'; 73-0054

zene reference rate not given. 3.315 dihydro—6-methyl- 2.3 x 10

9 — p.r. opt. p.b.k. at 500 nm; 74-1085

uracil

1 x 109 p.r. opt.

true rate should be lower,

c.k. with tert— 74-1085

BuOH, CNS - and EtOH.

3.316 dihydroorotate ion 7 3.0 x 10

9 — p.r. opt. p.b.k. (OH

adduct).

70-0567

3.317 5,6—dihydrothy— ~7 2.2 x 10 9 — p.r. opt. p.b.k.; obs. 68-0312

mine ~12.4 0.4 x 10 9 transients at 400

(pH = 7) and 320

(pH = 12.4) nm.

7 1.6 x 10

9 — — — cited from

69-0012.

70-0567 — <2.2 x 109 — p.r. opt. p.b.k. at 500 nm. 74-1085

6-8 1.5 x 10 9 (rel.) k/k RNO = 0.12 •y-r. opt. c.k.; 17°C. 75-0294

3.318 dihydrouracil 7 < (2.1 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 420 nm. 69-0571

7 (1.2 ± 0.2) x 10

9 ^/^CNS~ == (0.11 p.r. opt. c.k.; cor. for 69-0571

(rel.) ± 0.02) incomplete scavenging of e~q by

H2 02. 7 1.3 x 10

9 — — — cited from

69-0012.

70-0567 — <2.0 x 10

9 — p.r. opt. p.b.k. at 500 nm. 74-1085

m-dihydroxybenzene See m-hydroxyphenol (3.455). o-dihydroxybenzene See o--hydroxyphenol (3.456). p-dihydroxybenzene See hydroquinone (3.446). 3.319 2,5— dihydroxy— 1 3.1 x 10

9 (rel.) ^/^MeOH = 3.38 Fenton chem. c.k.; 73-9350

2,5—dimethyl- ^MeOH/^Fe 2+ = 4-3. 3—hexyne

3.320 4,5-dihydroxy-2,7- 0.1 8.5 x 10

7 (rel.) k/k Fe 2+ = 0.37 y-r. chem. c.k. 67-0025

naphthalenedisulfonic acid 3.320a 1,2-dimethoxyben- (5.2 ± 0.5) x 10

9 — p.r. — — 75-1171

zene

3.320b 1,3-dimethoxyben- (7.2 ± 0.7) x 10

9 — p.r. — — 75-1171

zene

3.320c 1,4-dimethoxyben- . (7.0 ± 0.7) x 10

9 — p.r. — — 75-1171

zene

3.321 1,2-dimethoxyethane 9 1.6 x 10

9 (rel.) ^/^EtOH = 0.85 y-r. opt. c.k. with RNO. 66-0423

3.322 dimethoxymethane 9 5.7 x 10

8 (rel.) ^/^EtOH = 0.31 y-r. opt. c.k. with RNO. 66-0423

3.323 (V,N-dimethyl- 5.5 3.5 x 10 9 (rel.) k/k CNS - == 0.32 p.r. opt. c.k. 70-0098,

acetamide 71-0645

OH + CH3 CON(CH3 ) 2 H 20 + CH3 CON(CH 3)CH 2 3.324 dimethylammonium 1 ~ 10

6

(I) — e-T. esr estd. from drop 72-5118

ion in aminium radical

(I) OH + (CH 3) 2 NH2+ -+ signal on addn. of H 2 0 + (CH3 ) 2 NH+

(II) OH + (CH3) 2 NH2 + /erf-BuOH.

-* H 2 0 + CH2(CH 3 )NH 2

+

3.325 iV,N-dimethyIaniline 9 8.9 x 109 (rel.) k/kfrOH ~ 4.8 y-r. opt. c.k. with RNO. 66-0441 — 1.3 x 10

10 — p.r. opt. p.b.k. at 455 and

330 nm.

72-0289

3.326 N,N-dimethylanil- 1 1.5 x 10 9 (rel.) klkf, 2 + = 6.6 Fenton chem. c.k. 49-0003

inium ion

34
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.327 3,3-dimethylbuty- 9

rate ion

1.7 x 109 (rel.) k/k ElOH = 0.9 y-r. opt. c.k. with RNO. 66-0423

3.327a dimethyl disulfide OH + CH3SSCH3 -* OH” + RSSR +

(1.7 ± 0.3) x 1Cl'° p.r. opt. p.b.k. 75-1089

3.328 N,N—dimethyl— 5.5 formamide1.7 x 109 (rel.) k/k cns~ = 0.155 p.r. opt. c.k. 70-0098

3.329 1,1-dimethyl— 9.2 hydrazine

1.6 x 10

10 (rel.) k/kcNS— = 1-45 p.r. opt. c.k. 72-0003

3.330 1,2—dimethyl— 10.1 hydrazine1.4 x 10

10 (rel.) k/k cns - = p.r. opt. c.k. 72-0003

3.331 1,1-dimethyl- 3.5 hydrazinium ion

8.1 x 10" (rel.) ^I^cns~ =0.074 p.r. opt. c.k. 72-0003

3.332 1,2—dimethyl— 3.5 hydrazinium ion

7.2 x 10 8 (rel.) k/kcns- = 0.065 p.r. opt. c.k. 72-0003

3.333 1,2—dimethylindole 9.0 (1.25 ± 0.02) x

(rel.)

10

10 y-r. opt. c.k. with RNO;

rel. to A:(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.334 1,3—dimethylindole 9.0 (1.01 ± 0.08) x

(rel.)

10

10 y-r. opt. c.k. with RNO;

rel. to A:(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.335 2,3-dimethylindole 9.0 (1.26 ± 0.01) x

(rel.)

10

10 y-r. opt. c.k. with RNO;

rel. to &(OH +

tryptophan) =

1.25 x 10'°.

71-0556

3.336 2.4-dimethylphenyl-/J- d

gluco—

pyranoside

4.5 x 109 (rel.) ^/^cns - = 0.41 p.r. opt. c.k. 71-0056

3.337 3,4-dimethyl—

phenyl-/)- d~

glucopyranoside

3.6 x 109 (rel.) y-r. opt. c.k. with RNO,

rel. to k(OH + X) =

4.4 x 10

9

, X =

phenyl-/3-D—gluco—

pyranoside.

71-0056

3.337a 2,2-dimethyl— 1— 1. 7-1.8

phenyl- 1-

propanol

1.1 x 10

10 (rel.) ^/^2-PtOH = 5-2 Fenton chem. c.k. with

1-phenylethanol.

74-9006

3.338 dimethyl phosphate

ion OH + (CH30)2 P0”->

h2 o + CH2 0(CH3 0)P0 2

1.2 x 10 8 (rel.) mcns- = o.on p.r. opt. c.k. 72-3008

3.339 /V,/V-dimethylpiv- 5-6 3.9 x 109 (rel.) alamide

dimethyl sulfide See methyl sulfide (3.552).

k/k cns - ” 0.357 p.r. opt. c.k. 71-0414

3.340 2,4-dimethyl- 9

pyridine

3.1 x 10

9 (rel.) klk^No = 0.25 ±

0.01

y-r. opt. c.k. 69-0280

3.341 2,6-dimethyl- 9

pyridine

3 x 10 9 (rel.) k/k rno = 0.24 ±

0.01

y-r. opt. c.k. 69-0280

3.341a dimethyl sulfone 1.5 < 6 x 10 6 Ti(III) + H2 02

esr estd. rel. to

k( OH + Ti(III)) =

3 x 10

9

.

75-5237

3.342 dimethyl sulfoxide 7.0 x 10

9 (rel.) 5.8 x 10

9 (rel.) For other ratios see: 3.348.

k/k CNS— = 0.64

k/k CNS — = 0.53

p.r.

p.r.

opt.

opt.

c.k.

c.k.

67-0186

73-1077

35
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH Ratio Source Method Comment Ref.

3.343 1,4— dioxane

OH + C 4 H8 02 ^

H 2 0 + C 4 H 7 02

7 2.8 x 10 9 (rel.)

2-2.2 2.0 x 10

9 (rel.)

1.8 x 10

9 (rel.)

/:/&,- = 0.23 ± p.r. opt. c.k.; obs. I 2 0.02 formn. at 400 nm.

65-0010

3.344 diphenylacetate For other ratios see: 3.627

9.1 4 x 109

3.345

ion diphenylamine 9 1.3 x 10 10 (rel.)

3.345a di-2-propyl (2.0 ± 1.0) x 10

10

3.346

disulfide OH + C 3 H 7 SSC,H 7 - OH + RSSR +

2,2'— dithiobis- 1 1.4 x 10

10 (rel.)

3.347

(ethylamine)

dithiothreitol 7 (1.5 ± 0.5) x 10

10

3.348

OH + SHCH 2CHOHCHOHCH2 S' - H 2 0 + •SCH 2 CHOHCHOHCH2 S" DNA — — 10

9 (rel.) OH + DNA -* 9 — 1.2 x 10

13 (rel.) transient —7 0.6 x 10

9 -12.4 0.6 xlO9

< 2.6 x 10

8 (rel.

)

7.5 1.3 x 10

13

7 (4 ± 1) x 10

8

3 x 10

8 (rel.)

5.2 x 10

8

7.0 1.8 x 10

8 (rel.)

k/k lhym = 0.37 ±

0.04

y-r- opt. c.k. 65-0388,

67-0461

k/k ElOH = 1 y-r. opt. c.k. with RNO. 66-0423

k/k ,-BuOH = 3-5 Ti(III) + H2 02esr c.k. 74-5144 — p.r. opt. p.b.k. at 340 nm. 72-0047

^/^RNO = 1-04 ±

0.04

y-r. opt. c.k. 69-0280

p.r. opt. p.b.k. 75-1089

kIKhym = 2.6 Fenton esr c.k.; klk pciox =

186.

69-5278

p.r. opt. p.b.k. at 300 nm;

ratio with phenylalanine = 2.

73-1020

p.r. opt. c.k. with CNS . 65-0388

^/^RNO — y-r. opt. c.k.; mol. wt.

5 x 10

6

.

67-0555

p.r. opt. p.b.k.; obs.

transients at 400 (pH = 7) and

320 (pH = 12.4) nm; assume

nucleotides (mol.

wt. 350) react independently.

68-0312

p.r. opt. c.k. with CNS ; based on nucleotide concn.

;

68-0845

p.r. opt. p.b.k. at 310 and

420 nm; k = 8 x 10

8 per nucleotide base group.

69-0018 — p.r. opt. p.b.k. at 340 nm;

k per base unit.

73-1071

y-r. trac. c.k.; effect of 73-1077

/cr/-BuOH, EtOH,

2-PrOH, tso-BuOH,

isoamyl alcohol and dimethyl

sulfoxide on binding

of

l4C-nitrofurazone

to DNA.

p.r. opt. d.k. as well as

p.b.k. at 400 nm;

rate in terms of nucleotide concn.

(mol. wt. 360).

73-3016

y-r. trac. c.k. assuming

&(OH + dimethyl

sulfoxide) = 6 x 10

9

; effect on

binding of

73-3080

36
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment

3.348 cont. 14C-nitrofurazone

in N2 0 satd. 0.3%

DNA; k per base group of mol. wt. s 330. — — — p.r. opt. k for DNA-bound

proflavine — 2 x

10

9

. 3.349 dodecyl sodium — 7.6 x 109

(rel.) — p.r. opt. c.k. with CNS~;

sulfate ^cns not given; k = 5.0 x 108 for concn. > 8. 1 x 1(T

3 M.

3.350 egg white p.r. opt. p.b.k. at 420 nm

(cystine anion

radical); OH halflife < 5 x 10"9

s. 3.351 eosin, dianion — 1.8 x 10 10 (I)(rel.) *./*«rb=50 p.r. opt. c.k.

(I) OH + S -» 10.5 1.2 x 10

,0 (I + II) ^1 + Il/^c*rb = — — c.k.; cor for charge transfer (rel.) 34 presence of HCOj.

(II) OH + S -» 9.0 k x = 1.7 x 10

9 — p.r. opt. X abs. at 450 nm.

addn. 9.0 k a = 6 x 10

8 — p.r. opt. adduct abs. at 600 nm.

3.352 1,2-epoxybutane 9 7.6 x 10

8 (rel.) k/k EtOH = 0.41 y-T. opt. c.k. with RNO.

3.353 1,2-epoxypropane 9 2.4 x 10® (rel.) k/k EtoH = 0-13 -y-r. opt. c.k. with RNO.

3.354 2,3-epoxypropanol 9 4.6 x 10

8 (rel.) k/k e,oh = 0.246 y-r. opt. c.k. with RNO.

3.355 erythritol 9 2.0 x 10

9 (rel.) k/k EtOH = 11 y-r. opt. c.k. with RNO.

3.356 ethane 1.2 — k/k hcooh = 10 ± 1 y-r. chem. c.k. 3.357 ethanesulfonate — 1.0 x 10 8 (rel.) k/k cns- = 0.0091 p.r. opt. c.k. ion 3.358 ethanol (EtOH) 1 8.7 x 108 (rel.) k/k Fc 2 + = 3.8 Fenton chem. c.k.

(I) OH + EtOH -* 6.6, 1.1 x 10

9

(rel.) k/ktmo = 0.12 X-r. opt. c.k.; not cor. H 2 0 + CHjCHOH 10.5 for H 202

.

(II) OH + EtOH — 1.3 x 109(rel.) klk^= 3.6 p.r. opt. c.k. H 20 + CH2CH 2OH 7 1.9 x 10

9 (rel.) k/klmo = 0.21 p.r. opt. c.k.

(III) OH + EtOH 7 9.1 x 108 (rel.) k/k r = 0.076 ± p.r. opt. c.k.; I

2 formn.

H 2 0 + ch3 ch2 o 0.007 meas. at 400 nm.

3, 1.6 x 10

9 (rel.) k/k BtQ - = 0.29 y-r. trac. c.k.; meas. UC02 10.5 — 1.5 x 109 (rel.) klkhm = 0.16 phot. — c.k. 9.0 1.8 x 109 (rel.) klk Bno = 0. 146 y-T. opt. c.k.; meas. at 400 nm.

2-2.2 2.0 x 10

9 (rel.) k/klhym = 0.37 ± y-T. opt. c.k. 0.035 5-5.5 1.8 x 10

9 (rel.) klk lbym = 0.33± y-r. opt. c.k. 0.035

7, ~1.8 x 10

9 (rel.) klk cttb ^ 4.8 p.r. opt. c.k. 10.7

7 1.8 x 10 9 (rel.) k/k CNS— = 0.164 p.r. opt. c.k. 2 1.65 x 10

9 (rel.) k/kctis— = 0. 15 p.r. opt. c.k. 7 1.9 x 10 9 (rel.) k/kCf4s~ = 0- p.r. opt. c.k. 1.9 x 10

9 (rel.) k/k^oH =2.1 p.r. opt. c.k. with HS04 , meas. abs. at 450 nm. (SO^). — — k/kjQQQ— = 0.53 y-r. trac. c.k. — 1.8 x 10

9 (rel.) k/k Blo~ = 0.31 p.r. opt. c.k.; obs. — 1.8 x 109 (rel.) k/k PA - = 0.23 hydroxycyclo- — 1.8 x 109 (rel). klk PNB\~ = 0-70 hexadienyl radical buildup.

5.5 1.7 x 109 (re!.) k/k NB = 0.54 r. opt. c.k. 7 1.7 x 10

9 (rel.) klk BM- = 0.29 r. lum. c.k.

Ref.

75-3094

71-0586

73-1059

66-

0501

67-

0038

68-

0309

68-0309

66-0423

66-0423

66-0423

66-0423

66-

0265

68-0352

49-0002

62-0023

64-

0131

65-

0007

65-0010

67-

0041 65-0099

65-0247

65-0356

65-0388,

67-0461

65-0388,

67-0461

65-0190

65-0190

65-0387

65-

0387

66-

0019

68-0209

68-0304

68-0494

68-0494

37
T \Bl.t; 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.358 cont. —1.2 1.4 x 10 9 (rel.) ^/^2-PrOH = 0-63 y-r. chem. c.k. 68-0602

6.98 1.3 x 10

9 (rel.) k/k 2-PrOH = 0-61 y-r. chem. c.k. 68-0602 — 1.6 x 10 9 (rel.) k/k rno = 0 - 128 p.r. opt. c.k. 69-0156

1 2.1 x 10

9 (rel.) klk t hym = 0.395 Fenton esr c.k.

;

klk^ = 28.9.

69-5278

1 1.9 x 10

9 (rel.) klk thym = 0.35 Ti(III) esr c.k.; 69-5278 - H2 02 klk^ = 24.9. — k\/kn = 8.6 y-r. chem. c.k. with H 2 02

. 70-0338

11 2.0 x 10

9 (rel.) ^carb=5.5 p.r. opt. c.k. ; assume

pA'.(OH) = 11.9.

70-0511 — k llk u = 6.0 ± y-r. chem. c.k. with H 2 02 ; 71-0081

0.2 * H /* D (U = 1-24 ±

0.04; * H/* D

(II) =

1.55 ± 0.06 or 2.28 ± 0 .20. 9 6.2 x 10

8 (rel.) klkntto =0.05 y-r. opt. c.k.; £„= -4.0 ±

1.1 kcal/mol

(-16.7 ± 4.5 kj/mol) at —8 to 23°C.

71-0469

nat. 1.9 x 10

9 (rel.) klk tm„=0.2 p.r. opt. c.k. 71-0578

0.82 1 .7 x 10

9

(I) (rel.) kilkf' 2+ = 7.32 Fenton chem. c.k.; also re- 71-9132

1.6 x 10 8 (II) (rel.) k ulk fc 2 + = 0.69 ported k/k Fe .j+ =

7.0. — — k ll /k l = 0.16 p.r. opt. detd. % of 73-0126

kmlk t = 0.03 a—alcohol and

ethoxy radicals by reaction with TNM and I , resp. — 1.65 x 10

9 (rel.) klk tmo =0.18 p.r. opt. c.k. 73-1046

7,10.6 1.5 x 10

9 (rel.) RNO = 12 phot. opt. c.k. ; H 2 0 2 soln; 73-7575 assume

k H2 O2M RNO For other ratios see: 3.12, 3.13, 3.25, 3.26, 3.27, 3.36, 3.41, 3.52, 3.54, 3.66, 3.80, 3.107, 3.112, 3.124, 3.127, 3.128, 3.131, 3.133, 3.134, 3.158,

3.170, 3.172, 3.185, 3.188, 3.189, 3.191, 3.193, 3.203, 3.209, 3.210, 3.214,

3.215, 3.222-3, 3.225, 3.226, 3.238, 3.246, 3.249, 3.250, 3.251, 3.257, 3.258,

3.272., 3.276, 3.282, 3.287, 3.305, 3.306, 3.308, 3.309, 3.321, 3.322 , 3.325,

3.327., 3.352, 3.353, 3.354, 3.355, 3.359, 3.360, 3.369, 3.370, 3.371 , 3.378,

3.380., 3.403, 3.405, 3.406, 3.408, 3.439, 3.440, 3.449, 3.502, 3.509 , 3.511,

3.512., 3.514, 3.515, 3.516, 3.522, 3.523, 3.524, 3.526, 3.529, 3.530 , 3.534,

3.545., 3.546, 3.549, 3.565, 3.566, 3.567, 3.573, 3.592, 3.593, 3.598 , 3.601,

3.602., 3.607, 3.609, 3.610, 3.611, 3.620, 3.622, 3.634, 3.635, 3.636 , 3.637,

3.638., 3.641, 3.669, 3.673, 3.690, 3.693, 3.695, 3.698, 3.711, 3.712 , 3.720a,

3.723., 3.724, 3.731, 3.732, 3.752. 3.359 ethanol-Js 6 1.1 X 10

9 (rel.) k/k Et0H = 0.62 y-r. chem. c.k. with Br . 66--0423 OH + C 2 D 5 OH -+ HDO + CD3CDOH

3.360 2-ethoxyethanol 9 1.7 x 10

9 (rel.) k/k eioh = 0.9 y-r. opt. c.k. with RNO. 66--0423

3.361 ethyl acetate 1 2.5 x 10

8 (rel.) k/k Fe 2 + = 1.1 Fenton chem. c.k. 49--0002

6 -7 4.0 x 10

8 (rel.) k/k cns

-• = 0.0364 p.r. opt. c.k. 65--0387

2.0- 2.8 x 10

8 (rel.) k/k t hym

:= 0.052; ± y-r. opt. c.k. 67--0461

2.2 0.004

3.362 ethylamine 12 1.3 x 10

10 (rel.) — p.r. opt. c.k.; calcd. 71--0585 from k/k CNS - = 1.0

at pH 1 1.2. — 3.2 x 10

9 (rel.) k/k nb = 1.3 p.r. opt. c.k.; calcd. from 73--0016

6.4 x 10

9 (rel.) k/kcfis~- = 0.58 values obs. at pH 8-13.1.

38
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.363 ethylammonium ion 2 7.8 x 10

7 (rel.) k/kCNS - = 0.0071 p.r. opt. c.k. 70-0371

4 5.1 x 10

8 (rel.) k/k CNS - = 0.0464 p.r. opt. c.k. 70-0371

3.1 3.0 x 10 8 (rel.) k/k CNS - = 0.0273 p.r. opt. c.k. 71-0585 — 3.8 x 10

8 (rel.) k/k m = 0.085 p.r. opt. c.k.; calcd. from 73-0016

6 x 10 8 (rel.) k/k cns - = 0.54 values obs. at pH 8-13.1.

3.364 ethyl butyrate 6-7 1.6 x 10 9 (rel.) k/k CNS - = 0.146 p.r. opt. c.k. 65-0387

3.365 ethylene — 4.9 x 10 8 (rel.) k/k ¥e 2+ = 2.13 y-r. opt. c.k. 67-0037

(I) OH + CH 2 =CH 2 — 4.8 x 10

9

(I + II) * 1+n/*i- = 0-402 p.r. opt. c.k.; meas. I

2 67-0041

-» .ch 2 ch2 oh (rel.) at 400 nm.

(II) OH + CH 2 =CH 2 (1.0 ± 0.2) x 10

9 — p.r. opt. c.k. with CNS’ 67-0269

-» ch2 =ch* + h 2 o (rel.) and HC03 ; details not given.

7 k\ilk\ = 0.3 y-r- chem. meas. 67-0522

G(alcohols). 3.366 ethylenediamine 4 — 3.5 x 10

7 (rel.) — — — c.k. with EtOH. 66-0401

8.0 (5.3 ± 1.0) x 10

8 k/k cns - = 0.0265 p.r. opt. c.k.; at pH 72-0461

(rel.) 8.5, 9.0, 10.0

ratio is 0.225,

0.3 and 0.5, resp. 3.367 ethylenediamine 9 2.6 x 10

9 (rel.) klk Uno = 0.28 y-r. opt. c.k. with RNO 67-0555

tetraacetate ion assuming ^ RN0 =

k ferro * 7 1.2 x 10

9 (rel.) k/k hno = 0.096 phot. opt. c.k.; H2 02 73-7575

10 4.8 x 10

9 (rel.) k/k uno = 0.38 soln; assume

10.3 5.8 x 10

9 (rel.) k/k rno = 0.46 k h2 ojk rno <<1-

10.6 6.3 x 10

9 (rel.) kl kftNo = 0.5 3.368 ethylenediamine- — 5.3 x 10

9 (rel.) k/k MeOH =5.9 X-r. chem. c.k. 72-0056

tetraacetic -0 -

k/k acrylamide Fenton pol. c.k. 72-9162

acid 2.2 3.369 ethyleneglycol 1 8.3 x 10

7 (rel.) k/k Ff.r+ = 0.36 therm. chem. c.k.; persulfate 49-0002

OH + CH 2 OHCH2 OH -* oxidation. H 2 0 + 7 1 .6 x 10

9 (rel.) k/k carb = 4.3 p.r. opt. c.k. 65-0190

CH2 OHCHOH 7 1 .4 x 10

9 (rel.) k1 k qns~ = 0.13 p.r. opt. c.k. 65-0387

9 1 .5 x 10

9 (rel.) k/k eioh = 0.82 y-r. opt. c.k. with RNO. 66-0423

6 1.1 x 10

9 (rel.) k/k eioh = 0.62 y-r. chem. c.k. with Br . 66-0423

2-2.2 1.7 x 10

9 (rel.) klk t hym = 0.32 ± y-r- opt. c.k. 67-0461

0.03

nat. 1.5 x 10

9 (rel.) klkum = 0. 158 p.r. opt. c.k. 71-0578 — — — p.r. opt. > 0.1% alkoxy 73-0126

radical detd. by

reaction with I . — 2.1 x 10

9 (rel.) k/k,",„ = 0.225 p.r. opt. c.k. 73-1046

3.370 ethylene oxide 9 6.7 x 10

7 (rel.) klk EiOH = 0.036 y-r. opt. c.k. with RNO. 66-0423

3.371 ethyl ether 1 1 .5 x 10

9 (rel.) k/k Fe 2+ = 6.4 Fenton chem. c.k. 49-0002

~7 4.9 x 10

9 (rel.) */*,- = 0.38 ± p.r. opt. c.k.; meas. I 2 65-0010

0.04 formn. at 400 nm.

9 1 .4 x 10

9 (rel.) k/k Eioh =0.74 y-r- opt. c.k. with RNO. 66-0423

2 2.8 x 10

9 (rel.) klk thym = 0.52 ± y-r. opt. c.k. 67-0461

0.04 ~1.2 2.5 x 10

9 (rel.) k/k 2 -prOH = T 15 y-r. chem. c.k. 68-0602

6.98 2.6 x 10

9 (rel.) k/k 2 -PrOH = 1-20 y-r. chem. c.k. 68-0602

3.372 ethyl formate 6-7 3.8 x 1() 8 (rel.) k/k cns- = 0.035 p.r. opt. c.k. 65-0387

3.373 /V-ethylmaleamie 6.0 7.0 x I0

9 — p.r. opt. p.b.k. 72-0144

acid

39
T \m,K 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment

3.374 N—ethylmaleimide — 4.3 x 10

9 (rel.) k/k thym = (0.8 ± X-r. opt. c.k. 0.1) 6.0 9.0 x 10

9 — p.r. opt. p.b.k. 3.375 4—ethyl—5- hydroxy— 6.5 1 .4 x 10

9 (rel.) k/k RNO = 0.11 ± y-r. opt. c.k. 2— melhylpyridine 0.01 3.375a 1 — (/?

ethyl — 1 .7-1.8 1.5 x 10'°(rel.) k/k 2-PrOH - 6.7 Fenton chem. c.k. with 1 —

phenyl)ethanoI phenylethanol.

3.376 ethyl propionate 6 -7 8.7 x 10 8 (rel.) k/kCNS

- = 0.079 p.r. opt. c.k. Flagyl See 1 — (2 — hydroxyethyl)-2-methyl-5--nitroimidazole (3.452a). 3.377 fluorescein — (1.4 ± 0.2) x 10

9 — p.r. opt. computer anal. OH + dye —* adduct — (1.6 ± 0.3) x 10

9 — p.r. opt. computer anal. OH + dye -> X* + (X* = semiOH“ oxidized fluor—

escein.

10 1.2 x 10

l ° — p.r. opt. d.k. as well as

p.b.k. 3.378 fluoroacetate ion 9 3.0 x 10

7 (rel.) k/k EtOH = 0.016 y-r. opt. c.k. with RNO.

3.379 fluorobenzene — 8 x 10

9 (rel.) — p.r. opt. c.k. with CNS ; reference rate not given. 3.380 p—fluorobenzoate 9 3.5 x 10

9 (rel.) k/k EtOH = 1.88 y-r. opt. c.k. with RNO.

ion 3.381 5-fluorouracil 7 5.2 x 10

9 (rel.) k/k CNS

-- = 0.472 p.r. opt. c.k.

7 5.5 x 10

9 — p.r. opt. p.b.k. at 340 nm.

11 6.0 x 10 9 — p.r. opt. p.b.k. at 340 nm.

3.382 formaldehyde 1 6.9 x 10

8 (rel.) k/k F'2+ = 3.0 Fenton chem. c.k. OH + HCHO -> 1.3 k1 k oxaii c acid r. chem. c.k. H 2 0 + CHO 40

3.383 formamide 5.5 < 5.0 x 10

8 (rel.) k/k cns“- < 0.045 p.r. opt. c.k. 3.384 formate 'ion 5.8- ~ 1.9 x 10

9 (rel.) k/k ( crro s 0.2 X-r. opt. c.k.; not cor. OH + HCOO“ —

»

10.1 for H 2 02

. H 2 0 + COO“ 7 2.9 x 10

9 (rel.) */*,- == 0.24 ± p.r. opt. c.k.; I

2 formn. 0.002 at 400 nm.

10.7 3.5 x 10

9 (rel.) k/k B*0~ = 0.62 y-r. trac. c.k. ; meas.

14C02

. — 2.4 x 10

9 (rel.) k/k ferTo = 0.26 phot. — c.k. 9.0 4.0 x 10

9 (rel.) k/k rno = 0.32 ± y-r. opt. c.k. 0.02 2-5 3.4 x 10

9 (rel.) k/k l hym = 0.63 ± y-r. opt. c.k.; calcd. k 0.06 on basis of rates obtained with formic/formate

systems as function of pH.

7 3.8 x 10

9 (rel.) k/kfttQ~ = 0.66 r. chem. c.k. 6.98 2.9 x 10

9 (rel.

)

k/k 2-pk)h = 1-34 y-r. chem. c.k. — 2.2 x 10

9 (rel.) k/k rno = 6. 1 76 p.r. opt. c.k.

11 4.0 x 10

9 (rel.) klk c„h = 10.6 p.r. opt. c.k. with CO 2

(p = 0.4); assumed

pA.(OH) = 11.9 8.4 2.9 x 10

9 (rel.) k/k bicarb = 86 p.r. opt. c.k. meas. COv

nat. 2.8 x 10

9 (rel.) klk tmo = 0.301 p.r. opt. c.k. For other ratios see: 3.24, 3.88, 3.102, 3.103, 3.111, 3.133, 3.137, 3.400,

3.592, 3.643, 3.682, 3.742. For ratios with 3 HC()2 see: 3.66, 3.82, 3.357, 3.511, 3.637. 3.385 formic acid 2.5 6.5 x 10

8 (rel.) klk (tm * 0.07 X-r. opt. c.k.; not cor. OH + HCOOH -+ H 2 0 + COOH 1.0 1.6 x 10

8 (rel.) k/k r = (1.3 ± p.r. opt.

for H 2 0 2. c.k.; oils, formn

1 1.3 x 1() 8 (rel.)

0.2) x 10"2

k/k cNs - = 0.01 14 p.r. opt

.

of 1 2 at 400 nm.

c.k.

Ref.

69-0562

72-0144

69-0580

74-9006

65-0387

68-0172

68-0172

73-

6068.

74-

1063 66-0423

73-0054

66-

0441

72-0049

72-0049

72-0049

49-0002

68-0503

70-0098

62-0023

65-0010

65-0099

65-0247

65-0356

67-

0461

68-

0494

68-0602

69-

0156

69-0379

69-0379

71-0578

62-0023

65-0010

65-0387

40
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.385 cont. 2-5 1.6 x 10

8 (rel.) k/k lhym = 0.03 ± y-r. opt. c.k.; calcd. k on 67-0461

0.03 basis of rates obtained with formic/formate

system as a function of pH.

-1.2 1.3 x 10 8 (rel.) A.7^

2 -PrOH = 006 y-r- chem. c.k. 68-0602

1 1.5 x 10 8 (rel.) hym = 0.028 Fenton esr C-k-; k/k perox =

1.95.

69-5278

1 1.5 x 10 8 (rel.) klk t hym = 0.028 Ti(III) esr c-k.; k/k

P"OX =

- H,0, 1.98. 0.8 — klk biaM [HS0 41 y-r. chem. c.k.; computer 72-0094 = 690 ± 80 anal. 0 — = 14.6 ± 0.6 For other ratios see : 3.26, 3.84, 3.106, 3.137, 3.356. 3.386 fumaric acid 1 1.1 x 10

9 (rel.) k/k: MeOH - 1-24 Fenton chem. c k.; k McOH /k Fc 2+ = 4.3.

73-9341

3.387 Furadantin 7 9.3 x 10

9 — p.r. opt. p.b.k. as well as

d.k.

73-1018

3.388 2-furaldehyde 9 7.75 x 10

9 (rel.) ^/^RNO = 0.62 ± y-r. opt. c.k. 73-0301

0.04

3.389 Furamazone 7 1.03 x 10

10 — p.r. opt. p.b.k. as well as

d.k.

73-1018

3.390 furan 3.8 x 10

9 (rel.) k/kcNs~ ~ 0.35 p.r. opt. c.k. 71-0360

0H + C 4 H4 0-^ 9 1.45 x 10

10 (rel.) ^/^’rno = 1-16 ± y-r. opt. c.k. 73-0301

(0H)C 4 H40 0.05

3.391 furfuryl alcohol 9 1.5 x 10

10 (rel.) k/

k

rno = 1-19 ± y-r. opt. c.k. 73-0301

0.10

3.392 2-furoate ion 9 1.15 x 10

10 (rel.) klkfttio = 0.92 ± y-r. opt. c.k. 73-0301

0.16 3.393 gelatin 9. 1 x 10

10 (rel.) p.r. opt. c.k. with CNS ; reference rate not given; mol. wt. 100,000.

68-3007

3.394 glucose 7.4 x 10

8 (rel.) klk Uno s 0.08 phot. — c.k. 65-0247

(I) OH + C 6 H 12 06 — 1.2 x 10

9 (rel.) klk { - = 0.

1

p.r. opt. c.k. 65-0391 —» deoxyglueose 2-2.2 2.2 x 10

9 (rel.) klk t hym = 0.40 ± y-r. opt. c.k. 67-0461

(II) OH + C 6 H 12 06 0.03 —» malondialde- 6.5 3.8 x 10

8 (rel.) k/k rno = 0.03 ± y-r. opt. c.k. 69-0580

hyde 0.01 8.8 — k \l k Rr = 0.865 p.r. chem. c.k. 70-0251 — *„/*„r" = 0 ' 642 p.r. chem. c.k. 70-0251

3.395 glucosephosphate 6.5 1.6 x 10

8 (rel.) k/k rno = 0.013 ± y-r. opt. c.k. 69-0580

0.003

3.396 l)-glucuronate ion 3.0 x 10

9 (rel.) k/k cns~ = 0.27 p.r. opt. c.k. 70-0509,

70-3081

3.397 glucuronic acid acid 1 .3 x 10 9 (rel.) k/kcNs~ = 0.12 p.r. opt. c.k. 70-0509

3.398 p-glucuronolactone 1 .6 x 10

9 (rel.) k/kcNs~ = 0.15 p.r. opt. c.k. 70-0509

3.399 glutamic acid 2-2.2 1.4 x 10 8 (rel.) klk lhym = 0.0255 y-r. opt. c.k. 65-0388

6.5 2.3 x 10

8 (rel.) k/k rno = 0.018 y-r. opt. c.k. 73-0548

3.400 glutamine 2-2.2 1 .6 x 10

8 (rel.) klk thym = 0.029 ± y-r. opt. c.k. 67-0461

0.003

6.0 5.4 x 10

8 (rel.) klk rno = 0.043 y-r. opt. c.k. 67-0461

3.401 glutaric acid 2-2.2 7.0 x 1

0

8 (rel.) k/k tbym = 0.13 ± y-r. opt. c.k. 67-0461

0.01 3.402 glutathione 1 1.4 x 1

0

10 (rel.) k/k CNS~ = T3 p.r. opt. c.k. 65-0387

(reduced) 1 1.4 x 10

10 (rel.) klk lhym = 2.6 Fenton esr c.k.; k/k ft:tol = 69-5278

186. (oxidized) 1 1.1 x 1()

10 (rel.) klk lhym = 1.98 Fenton esr c.k.; k/k prrot = 69-5278

143.

41
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.403 glycerol ' 1.9 x 10 9 (rel.) kl k C*Tb = 5.3 p.r. opt. c.k. 64-0131

7 1.8 x 10

9 (rel.) kl k crb = 4.8 p.r. opt. c.k. 65-0190

10.7 1.9 x 10 9 (rel.) */* «rb = 5.1 p.r. opt. c.k. 65-0190,

65-0387

9.0 2.0 x 10

9 (rel.) klk RNO = 0.164 ± y-T. opt. c.k. 65-0356

0.008

7 1.5 x 10 9 (rel.) klk CNS - = 0.14 p.r. opt. c.k. 65-0387

9 1.85 x 10

9 (rel.) klk EtOH

== 1 y-r. opt. c.k. with RNO. 66-0423

2-2.2 1.9 x 10

9 (rel.) klk xhym = 0.35 ± y-r. opt. c.k. 67-0461

0.03

nat. 1.9 x 10 9 (rel.)

rro = 0.204 p.r. opt. c.k. 71-0578 — 2.0 x 10 9 (rel.) kl k CNS- = 0.18 p.r. opt. c.k. 73-1077

1.6 x 10

9 (rel.) klkie rro = 0.17 3.404 glycine, positive 1 8 x 10

6 (rel.) kl k fc 2+ == 0.035 Fenton chem. c.k. 49-0002

ion 1 1.6 x 10

7 (rel.) kl kCNS~ = 0.0015 p.r. opt. c.k. 65-0387

2.8 8.1 x 10

6 (rel.) klkl taym = 0.0015 y-r. opt. c.k. 65-0388

2.8-3 1.0 x 10

7 (rel.) kl k CNS - = 0.00091 p.r. opt. c.k. 65-0388

3.405 glycine, 7.0 5.6 x 10

6 (rel.) klk fcrro = 0.0006 X-r. opt. c.k.; not cor. 62-0023

zwitterion for H2 02

. — 2.6 x 10 8 (rel.) kfk (cTTO = 0.028 phot. — c.k. 65-0247

5.8-6 1.6 x 10 7 (rel.) kl k CNS - = 0.0015 p.r. opt. c.k. 65-0388

5 4.6 x 10

6 (rel.) kl k EtOH

== 0.0025 y-r. opt. c.k. with RNO. 66-0423

6.7 1.7 x 10

7 (rel.) klk RNO - = 0.00135 y-r. opt. c.k. 73-0548

3.406 glycine, negative 9.45 8.4 x 10

8 (rel.) kl k lCTTO = 0.09 X-r. opt. c.k.; not cor. 62-0023

ion for H 2 02

. 10.5 2.8 x 10

9 (rel.) klk Urro = 0.3 X-r. opt. c.k.; not cor. 62-0023

for H2 02

. 10.5 2.7 x 10

9 (rel.) klk BiO - = 0.47 y-r. trac. c.k.; meas.

14C02

. 65-0099

9.5- 1.9 x 10 9 (rel.) k!k CNS- = 0.17 p.r. opt. c.k. 65-0388

9.7 12 2.0 x 10

9 (rel.) kl k EtOH

== 1.1 y-r. opt. c.k. with RNO. 66-0423

10.0 5.3 x 10

9 (rel.) kl k CNS - = 0.485 p.r. opt. c.k. 72-0461

3.407 glycine anhydride 5.0 1.2 x 10

9 (rel.) klk CNS - = 0.11 p.r. opt. c.k. 71-0554

11.0 1.2 x 10

9 (rel.) klk CNS - = 0.11 p.r. opt. c.k. 71-0554

3.408 glycolate ion 9 7.1 x 10

8 (rel.) klk EtOH

== 0.386 y-r. opt. c.k. with RNO. 66-0423

5.5, 7.0 (8.6 ± 0.7) x 10

8 klk CNS - = 0.078 p.r. opt. c.k. 75-1053

(rel.) 3.409 glycolic acid 1 4.6 x 10 8 (rel.) kl k Fc 2+ == 2.0 Fenton chem. c.k. 49-0002

2-2.2 4.6 x 10

8 (rel.) */*«h,o. = 0.085 ± y-r. opt. c.k. 67-0461

0.005

3.410 glycylalanine 2-2.2 1.8 x 10

8 (rel.) klk thym = 0.0339 y-r. opt. c.k. 65-0388

5.5-6 3.5 x 10 8 (rel.) klk CNS _ = 0.032 p.r. opt. c.k. 65-0388

3.411 glycylglycine. 2-2.2 1.4 x 10

8 (rel.) kl k , hyn. = 0.0252 y-r. opt. c.k. 65-0388

positive ion 2. 2-2.

4

1.6 x 10

8 (rel.) klk CNS - = 0.0144 p.r. opt. c.k. 65-0388

3.412 glycylglycine. 6-7 2.6 x 10 8 (rel.) klk CNS - = 0.024 p.r. opt. c.k. 65-0387

zwitterion 5.5-6 2.2 x 10

8 (rel.) kl k CNS - = 0.0197 p.r. opt. c.k. 65-0388

4.2 4.4 x 10

8 (rel.) kl k CNS - = 0.04 p.r. opt. c.k. 70-0099

3.413 glycylglycine, 10.5 5.2 x 10

9 (rel.) kl k CNS - = 0.47 p.r. opt. c.k. 70-0099

negative ion 3.414 glycylglycine 3.3 2.7 x 10

8 — p.r. opt. p.b.k. 75-1004

amide

3.415 glycylglycylgly- 2-2.2 1.6 x 10

8 (rel.) */*«hyn, = 0.029 y-r. opt. c.k. 65-0388

cine, positive 2.8-3 2.4 x 10 8 (rel.) kl k CNS - = 0.022 p.r. opt. c.k. 65-0388

ion 3.416 glycylglycylgly- 5.5-6 1.8 x 10 9 (rel.) kl k CNS - = 0.16 p.r. opt. c.k. 65-0388

cine, zwitterion 8.5- 1.8 x 10

9 (rel.) kl k CNS - = 0.16 p.r. opt. c.k. 65-0388

8.7

5.4 7.3 x 10 8 (rel.) kl k CNS - = 0.066 p.r. opt. c.k. 70-0099

42
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.417 glycylglycylgly—

cine, negative

ion

10.6 5.0 x 10

9 (rel.) ^/^CNS - = 0.455 p.r. opt. c.k. 70-0099

3.418 glycylglycylgly- 2-2.2 2.4 x 10

8 (rel.) ^/^,hym = 0.045 •y-r. opt. c.k. 65-0388

cylglycine,

positive ion

2.4-

2.6

3.5 x 10

8 (rel.) ^/^CNS~ = 0.032 p.r. opt. c.k. 65-0388

zwitterion 5.5-6

7.7-

7.9

4.5 x 10 8 (rel.) 1.2 x 10 9 (rel.)k/k cns~

klk CNS —

= 0.041 = 0.11

p.r.

p.r.

opt.

opt.

c.k.

c.k.

65-0388

65-0388

negative ion 9.5-

9.7

3.0 x 10

9 (rel.) k/k CfiS - = 0.27 p.r. opt. c.k. 65-0388

3.419 glycylisoleucine

positive ion

2-2.2 2.4 x 109 (rel.) klk thym = 0.452 y-r. opt. c.k. 65-0388

3.420 glycylleucine

positive ion

2-2.2 2.6 x 10

9 (rel.) k/k t hym = 0.484 y-r. opt. c.k. 65-0388

3.421 glycylmethionine 2-2.2 4.4 x 10

8 (rel.) k/k t hym = 0.081 y-r. opt. c.k. 65-0388

positive ion 2-2.2 1.1 x 10 8 (rel.) k/k Cns~ = 0.00985 p.r. opt. c.k. 65-0388

zwitterion 5-5.2 2.2 x 10 8 (rel.) k/k cns~ = 0.0197 p.r. opt. c.k. 65-0388

3.422 glycylphenyl—

alanine, positive ion

2-2.2 8.9 x 10

8 (rel.) k/k lhym = 0.165 y-r. opt. c.k. 65-0388

3.423 glycylproline,

positive ion

2-2.2 1.5 x 10

9 (rel.) klk t hym = 0.27 y-r. opt. c.k. 65-0388

3.424 glycylserine,

positive ion

2-2.2 5.9 x 10

8 (rel.) k/k lhym = 0.11 y-r. opt. c.k. 65-0388

3.425 glycyltyrosine,

positive ion

2-2.2 9.7 x 10

9 (rel.) k/k t hym = 1.8 y-r. opt. c.k. 65-0388

3.426 glycylvaline,

positive ion

2-2.2 1.2 x 10

9 (rel.) k/k thym = 0.226 y-r. opt. c.k. 65-0388

3.427 glyoxal

OH + CHOCHO -* H 2 0 + COCHO

1.3 k/k oxalic acid 46r. chem. c.k. 68-0503

3.428 guanine

10.0

1.05 x 10

10

9.2 x 10

9 (rel.) k/k rno — 0.74 y-r. opt. c.k.; 17°C.

66-0845

75-0294

3.429 guanosine 9 7.6 x 10

9 (rel.) k/k rno = 0.61 y-r. opt. c.k. 67-0555

3.430 guanylic acid 6.7 (4.7 ± 0.2) x 10

9 — p.r. opt. p.b.k. at 325 nm. 70-3069

3.431 hemin — ~ 1.0 x

10'° — — — — 66-0844

3.432 hemoglobin — 3.6 x 10

10 — — — — 66-0844

3.433 heparin 3.6 x 10

8 (rel.) klkcNS~ = 0.033 p.r. opt. c.k.; concn. of polyanion in hex—

ose units.

68-0352,

70-3081

3.434 heparin, desulfated

8.0 x 10

8 (rel.) k/k CNs~ = 0.073 p.r. opt. c.k.; concn. of polyanion in hexose units.

70-3081

3.435 1-heptanol 2-2.2 6.2 x 10

9 (rel.) k/k lhym =

0.10

1.15 ± y-r. opt. c.k. 67-0461

3.436 hexadecyltrimethylammonium

bromide

1.1 x 10 10 (rel.) k/kutOH z= 11.8 p.r. opt. c.k.; meas. Br 2 at 360 nm; concn. < 9 x 10’4 M;

at higher concn.

ratio = 2.4.

71-0001

71-0586

3.437 2,4-hexadien-l-ol 7.0 (9.8 ± 1.0) x 10

9 — p.r. opt. p.b.k. 73-1070

3.438 hexafluorobenzene

OH + C6F6 —> addn. — F"+ H

+ +

•c 6f5 =o

2 x 10

9 (rel.) p.r. opt. c.k. with CNS ; 280 nm. abs. grows in at same

rate as condy. (F~).

73-0054

3.438a hexamethylbenzene ~7 7.2 x 10

9 p.r. opt. p.b.k.; OH addn.

as well as H abstr. (< 50%).

75-1009

3.439 1,6-hexanediol 9 4.6 x 109 (rel.) k/kfaQH == 2.46 y-r. opt. c.k. with RNO. 66-0423

43
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.440 hexanoate ion 9 3.9 x 10 9 (rel.) k/k eioh = 2.

1

y-T. opt. c.k. with RNO. 66-0423

3.441 1— hexanol 2—2.2 5.9 x 10

9 (rel.) */**,» = 1.10 ±

0.10

y-r. opt. c.k. 67-0461

3.442 histidine 2-2.2 1.9 x 10

9 (rel.) */*cns- = 0.174 p.r. opt. c.k. 65-0388

6-7 5.0 x 10

9 (rel.) k/

k

cns = 0.455 p.r. opt. c.k. 65-0388

6.7 4.3 x 10 9 (rel.) k/k rno = 0-34 y-r. opt. c.k. 73-0548

3.443 histidylhistidine 5.5—

6.5

9.0 x 10

9 (rel.) k/k CNS ~ = 0.82 p.r. opt. c.k. 65-0388

3.444 hyaluronic acid 1.3 x 10 9 (rel.) k/kCNS- = 0.116 p.r. opt. c.k.; based on

disaccharide unit.

67-0730

6.7 x 10 8 (rel.) k/kCNS - = 0.061 p.r. opt. c.k.; concn. of polyanion in hexose units.68-0352,

70-3081

3.445 hyaluronic acid, sulfated6.0 x 10

8 (rel.) k/k CNS- = 0.055 p.r. opt. c.k.; concn.

of polyanion in hexose units.

70-3081

3.446 hydroquinone 6-7 2.1 x 10 10 (rel.) k/k CNs~ = 1-88 p.r. opt. c.k. 65-0387

OH + HOC 6 H4 OH-^

C 6 H 4(OH) 3

1 x 10

10 (rel.) klk Mc0li = 10.8 p.r. opt. c.k. with HS04 ; obs. decreased abs.

at 450 nm.

66-0019

9 5.5 x 10

9 (rel.) k/kjifio = 0.44 ±

0.12

y-r. opt. c.k. 72-0837

3.447 hydroxocobalamin ~10 10 — — — c.k. with RNO. 72-3046

3.447a hydroxyacetamide 8.5

o— hydroxybenzaldehyde See

(1.1 ± 0.1) x 10

9

(rel.) salicylaldehyde (3.668a).

k/k cns = 0.1 p.r. opt. c.k. 75-1053

3.448 p—hydroxybenz— 9 1.0 x 10 9 (rel.) aldehyde o— hydroxybenzoate ion See salicylate ion (3.669).

^/^RNO = 0-82 ±

0.2

y-r. opt. c.k. 72-0837

3.449 p-hydroxybenzoate 9 5.5 x 10

9 (rel.) k/kfrOH — 2.95 y-r. opt. c.k. with RNO. 66-0441

ion 7 OH + OHC 6 H4 COO

(OH)2 C 6 H4COCT

(9 ± 2) x 10

9 p.r. opt. p.b.k. at 375;

cor. for (OH + OH) and

(H + aromatic).

68-0304

9 8.7 x 10

9 (rel.) k/k rno = 0-^0 — y-r. opt. c.k. 72-0837

3.450 2-hydroxybutyric 1 acid6.9 x 10 8 (rel.) k/k f'2+ = 3.0 Fenton chem. c.k. 49-0002

3.451 2— hydroxyethyl

acetate

8.5 x 10

8 (rel.) k/k cns - = 8.25

x 10'2 p.r. opt. c.k. 75-1126

3.452 2— hydroxyethyl— —0

ethylenediaminetriacetic acid

k/k acrylamide 1.9

Fenton pol. c.k. 72-9162

3.453 1— (2— hydroxyethyl)—

2-methyl-5-

4. 1 x 10

9 (rel.) k/kcNS~ = 0-37 p.r. opt. c.k.; d.k. at 320 nm gave k = 10

9

.

74-1135

nitroimidazole (5.5 ± 0.2) x 10

9 — p.r. opt. p.b.k. at 420 nm. 75-1067

3.454 2— hydroxyethyl— 11 sulfide ion OH + OH(CH 2 ) 2 S'

OH' + OH(CH 2 ) 2 S*

4.0 x 10

9 (± 15%) p.r. opt. p.b.k. at 410—

420 nm (RSSR').

69-0553

3.454a l-(2-hydroxy-3-

methoxypropyl)-2-

nitroimidazole

(7.1 ± 0.3) x 10

9 p.r. opt. p.b.k. at 475 nm. 75-1067

3.455 5-hydroxyindole 9.0 (1.67 ± 0.10) x 10'° (rel.)

y-r. opt. c.k. with RNO;

rel. to /c(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.456 m-hydroxyphenol 9 1.2 x 10

10 (rel.) k/k rno = 0-97 ±

0.12

y-r. opt. c.k. 72-0837

3.457 o-hydroxyphenol 9 1.1 x 10

10 (rel. )

p-hydroxyphenol See hydroquinone (3.446).

k/k uno = 0.89 ±

0.14

y-r. opt. c.k. 72-0837

44
Tabi.K 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.458 p— hydroxyphenyl— — 2.7 x 10 9 (rel.) — y-r. opt. c.k. with RNO; 71-0056

/}— D -glucopyrano rel. to k = 4.4 x

side 10 9 for phenyl

/?— D—glucopyrano—

side. 3.459 p— hydroxyphenyl— 10.6 2.1 x 10 10 (rel.) klk c<rb = 58.5 p.r. opt. c.k. 68-0062

propionate ion 6.3 (1.2 ± 0.2) x 10

10 k/kcNs~ = 1-1 p.r. opt. c.k. 73-0003

(rel.) 11.0 (1.6 ± 0.2) x 10

10 klk CNS— — 1.45 p.r. opt. c.k. 73-0003

(rel.) 3.460 p— hydroxyphenyl— 4.6 1.3 x 10

10 (rel.) k1k wcoo = 3.7 p.r. opt. c.k.; P Aa = 4.6, 68-0062

propionic acid

3.6 x 10

8 (rel.)

10.1. 3.461 hydroxyproline 2-2.2 k/k lhym = 0.066 y-r. opt. c.k. 65-0388

6.8 3.2 x 10

8 (rel.) k/kfitio = 0.0255 y-r. opt. c.k. 73-0548

3.461a 2— hydroxypro— 4.5, (1.3 ± 0.3) x 10

9 ^/^cns — = 0- 12 p.r. opt. c.k. 75-1053

pionamide 7.0 (rel.) 3.461b 2— hydroxypurine 6-7 5.0 x 10

9 (rel.) k/k RNo ~ 0.4 y-r. opt. c.k.; 17°C. 75-0294

3.462 2— hydroxypyridine. 9 4.8 x 10

9 (rel.) k/k rno = 0.38 ± y-r. opt. c.k. 69-0280

anion 0.01 3.463 3— hydroxypyridine 6.5 6.8 x 10

9 (rel.) k/kft^o ~ 0.54 ± y-r. opt. c.k. 69-0280

0.03 3.464 3— hydroxypyridine. 9 5.4 x 10

9 (rel.) k/k rno = 0.43 ± y-r. opt. c.k. 69-0280

anion 0.02 3.465 4- hydroxypyridine 9 2.75 x 10

9 (rel.) k/k rno = 0.23 ± y-r. opt. c.k. 69-0280

anion 0.01 3.466 a - hydroxytetronate 7 4.7 x 10

9 (rel.) — p.r. opt. p.b.k. at 360 nm. 74-1053

ion 3.466a hypoxanthine 6-7 2.7 x 10 9 (rel.) k/kjifio = 0.22 y-r. opt. c.k.; 17°C. 75-0294

3.467 imidazole 3.4 5.5 x 10

9 — p.r. opt. p.b.k.; OH addn.; 75-1066

6.8 8.7 x 10

9 pAa = 7.1, 14.5. 10.9 1.2 x 10 10

3.468 indole 9.0 (1.37 ± 0.05) x 10

10 — y-r. opt. c.k. with RNO; 71-0556

(rel.) rel. to £(OH +

tryptophan) =

1.25 x 10

10

. 9.0 (3.18 ± 0.25) x

10'° — p.r. opt. p.b.k. at 320 nm. 71-0556 — 1.3 x 10

10 (rel.) ^/^2-PrOH = 3-9 y-r. chem. c.k. 72-0541

3.469 indole-3—acetic — 1.1 x 10 10 (rel.) ^/^2-PrOH = 3-0 y-r. chem. c.k. 72-0541

acid 3.470 indole-5-acetic 9.0 (0.79 ± 0.07) x 10

10 — y-r. opt. c.k. with RNO; 71-0556

acid (rel.) rel. to &(OH +

tryptophan) =

1.25 x 10

10

. 3.471 indole-3- propionic — 1.4 x 10

10 (rel.) ^/^2-PrOH = 0.5 y-r. chem. c.k. 72-0541

acid 3.472 indoline 9.0 (2.02 ± 0.14) x 10

10 — y-r. opt. c.k. with RNO; 71-0556

(rel.) rel. to £(OH +

tryptophan) =

1.25 x

10‘°. 9.0 (3.83 ± 0.48) x 10

10 — p.r. opt. p.b.k. at 320 nm. 71-0556

3.473 inositol 6.5 1.0 x 10

10 (rel.) k/k rno = 0.8 ± y-r. opt. c.k. 69-0580

0.1 — 1.4 x 10

9 (rel.) ^/^cns = 0. 13 p.r. opt. c.k. 73-1077

1.8 x 10

9 (rel.) k/k(crTO =0.19

3.473a iodoacetic acid 1 (5 ± 1) x 10

9 (rel.) klk (mo = 0.54 p.r. opt. c.k. 74-5286

3.474 iodobenzene 9 5 x 10

9 (rel.) k/k hno = 0.40 ± y-r. opt. c.k. 69-0280

0.02 3.475 2-iodobenzoate ion 9 4.5 x 10

9 (rel.) — — — c.k. with RNO. 66-0843

3.476 3-iodobenzoate ion 9 2.9 x 10

9 (rel.) — — — c.k. with RNO. 66-0843

45
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.477 4— iodobenzoate ion 9 2.5 x 10 9 (rel.) — — — c.k. with RNO. 66-0843

3.478 iodomethane 1.4 x 10

9 (rel.) kl k MeOH = 1.54 -y-r. chem. c.k.; meas. I 2 69-0019

OH + CH 3

I -* yields.

CH 3 OH + I 3.479 3—iodopropionic (1.2 - 4.0) x 10

8 k/ k CNS~ = (1.1 - p.r. opt. c.k. 70-1226

acid (rel.) 3.6) x 10“2

1.6 x 10 8 (rel.) kl k NB = 0.051 p.r. opt. c.k. 70-1226

isoamyl alcohol See 3 -methyl— 1— butanol (3.527). 3.480 isoamylammonium 4 7.8 x 10

9 (rel.) kl k Ct4S = 0.714 p.r. opt. c.k. 70-0371

ion isobutanol See 2--methyl— 1—propanol (3.545). 3.481 isobutylammonium 4 3.1 x 10

9 (rel.) k/ k CNS = 0.278 p.r. opt. c.k. 70-0371

ion 3.482 isobutylene 5.9 x 10

9 (rel.) klkx - = 0.49 p.r. opt. c.k.; meas. I 2 at 400 nm.

67-0041

3.483 isobutyramide 5—6 1.6 x 10

9 (rel.) kl k cns — = 0.143 p.r. opt. c.k. 71-0414

3.483a isoguanine 11.0 1.23 x 10

10 (rel.) kl k RNO == 0.98 y-r. opt. c.k.; 17°C. 75-0294

3.484 isoleucine 2—2.2 1.8 x 10 9 (rel.) kl k < hyn == 0.34 y-r. opt. c.k. 65-0388

6.6 1.7 x 10

9 (rel.) kl k RNO == 0.14 y-r. opt. c.k. 73-0548

3.485 isoorotate ion 7 4.0 x 10

9 — p.r. opt. p.b.k. (OH

adduct).

70-0567

6-7 2.5 x 10

9 (rel.) kl k RNO == 0.2 y-r. opt. c.k.; 17°C. 75-0294

isopropanol See 2— propanol (3.637). 3.486 isopropyl acetate 1 2.9 x 10® (rel.) k/kye 2+ := 1.25 Fenton chem. c.k. 49-0002

6-7 4.5 x 10® (rel.) kl k cNS~ = 0.041 p.r. opt. c.k. 65-0387

2.0 4.3 x 10® (rel.) kl k CNS~ = 0.0395 p.r. opt. c.k. 65-0387

3.487 isopropylamine 12.0 1 .3 x 10

10 (rel.) — p.r. opt. c.k.; value 71-0585

OH + (CH 3 ) 2 CHNH 2 extrapolated from

-> H 2 0 + obs. k/k CN

s

— = (CH 3) 2 CNH 2 8.2 x 10' 1 at pH

10.8. 3.488 isopropylammonium 3.0 5.0 x 10® (rel.) kl k CNS - = 0.0455 p.r. opt. c.k. 71-0585

ion OH + (CH 3 ) 2 CHNH; 4 4.7 x 10® (rel.) kl k CNS = 0.0429 p.r. opt. c.k. 70-0371

h 2 o + CH 2 (CH 3 )CHNH 3

+

3.489 keratan sulfate 7.9 x 10® (rel.) kl k CNS - = 0.072 p.r. opt. c.k. 71-0067

3.490 lactate ion 9 4.8 x 10

9 (rel.) — — — c.k. with RNO. 66-0843 — 7 x 10® — p.r. — prelim, value. 74-1007

3.491 lactic acid 1 3.9 x 10® (rel.) k/k jr e 2+ ;= 1.7 Fenton chem. c.k. 49-0002

2-2.2 6.5 x 10® (rel.) kl k thym

== 0.12 ± y-r. opt. c.k. 67-0461

0.01

1 4.3 x 10® (rel.) kl k CNS - = 0.0393 p.r. opt. c.k. 65-0387

3.492 lactose 6.5 2.4 x 10

9 (rel.) kl k RNO == 0.19 ± y-r. opt. c.k. 69-0580

0.02 3.493 leucine, positive 2—2.2 1.5 x 10

9 (rel.) kl k CNS - = 0.14 p.r. opt. c.k. 65-0388

ion 2—2.2 2.0 x 10

9 (rel.) kl k thym

== 0.37 y-r. opt. c.k. 65-0388

3.494 leucine, 5.5-6 1.6 x 10

9 (rel.) kl k CNS - = 0.15 p.r. opt. c.k. 65-0388

zwitterion 6.9 1.8 x 10

9 (rel.) kl k RNO == 0.145 y-r. opt. c.k. 73-0548

3.495 leucine, negative 9.7— 3.7 x 10

9 (rel.) klk CNS - = 0.34 p.r. opt. c.k. 65-0388

ion 9.9 3.496 luminol 9.5 8.7 x 10

9 — p.r. opt. p.b.k. 73-1068

3.497 lysine 2—2.2 6.5 x 10® (rel.) kl k thym

=- 0.12 y-r. opt. c.k. 65-0388

6.6 3.5 x 10® (rel.) kl k RNO == 0.028 y-r. opt. c.k. 73-0548

3.497a lysine vasopressin —6 (1.4 ± 0.2) x 10

10 — p.r. opt. p.b.k. at 325 nm. 74-1102

3.498 lysozyme 9 1.9 x 10

10 (rel.) klk RNO == 1.49 y-r. opt. c.k. 67-0555

5.6 5.2 x 10

10 (rel.) kl k CNS - = 4.7 p.r. opt. c.k.; mol. wt. 15,000; k is upper limit.

68-0683

7.4 4.9 x 10*° — p.r. opt. p.b.k. at 350 nm. 69-3039

46
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.498 cont. 7.4 — ^/^t-BuOH = 56 — — c.k. 69-3039

6.4 4.2 x 10

10 (rel.) ^/^RNO = 5.4 y—r - opt. c.k. 73-0548

3.499 malate ion (8.6 ± 0.8) x 10

8 — p.r. — prelim, value. 74-1007

3.500 maleic acid 1 4.6 x 10

8 (rel.) k/k MeOH = 0.515 Fenton chem. c -k.; ^MeOH/^Fe 2 + = 4.3.

73-9341

3.501 malic acid 2—2.2 5.4 x 10 8 (rel.) k/k tbym =0A0±

0.01 y—r- opt. c.k. 67-0461

3.502 malonate ion 9 5.5 x 10 7 (rel.) k/k eioh = 0.0296 y-r. opt. c.k. with RNO. 66-0423

3.503 malonic acid 6—7 3.0 x 10 8 (rel.) k/k CNS - = 0.0273 p.r. opt. c.k. 65-0387

2-2.2 2.0 x 10

7 (rel.) = 0-0037 y-r. opt. c.k. 67-0461

1 2.6 x 10

7 (rel.) k/k MeOH = 0.017 Fenton chem. c.k.

;

^MeOH/^Fe 2+ = 4 '3.

73-9341

3.504 melibiose 6.5 3.8 x 10

9 (rel.) ^/^RNO = 0-3 ±

0.1

y-r. opt. c.k. 69-0580

3.505 menaquinone

(Vitamin K3 ) 2— mercaptoacetate ion See

5.5 x 10

9

thioglycolate ion (3.705).

73-0026

3.506 2— mercaptoethanol 6—7 8.5 x 10

9 (rel.) ^•/^cns - = 0.773 p.r. opt. c.k. 65-0387

OH + OH(CH2 ) 2 SH —>7 2.7 x 10 10 (rel.) k/k CNS — = 2.43 p.r. opt. c.k. 69-0553

H 2 0 + OH(CH2 ) 2 S* 6.5 6.0 x 10 9 (rel.) k/khlTO = 0.65 p.r. opt. c.k. 71-0175

6 3.3 x 10

9 (rel.) */*NU= L04 p.r. opt. c.k. ; cor. for H. 71-0175

6 1.8 x 10*°(rel.) See also 2-hydroxyethylsulfide ion (3.453). 2-mercaptoethylamine See cysteamine (3.286). 2-mercaptopropionate ion See thiolactate ion (3.706).

k/kcNS - ~ 1.68 p.r. opt. c.k. 71-0175

3.508 3-mercaptopro— 6.0 3.0 x 10

l° (rel.) pionate ion 10.7 2.1 x 10

10 (rel.)

2— mercaptovaline See penicillamine (3.596).

k/kcNS~ = 2-7 ±

0.4

^•/^CNS - = 1-9 ±

0.3

p.r. opt. c.k.; p

K

a = 4.3, 10.3 for the acid.

73-0090

3.509 methane 9 2.4 x 10 8 (rel.) ^/^•EtOH = 0.13 y-r. opt. c.k. with RNO. 66-0423

OH + CH4 —

5.5 h 2 o + ch 3

(1.21 ± 0.4) x 10

8 — p.r. opt. d.k. (OH) at 250 nm.

72-0445

3.509a methanesulfonic

acid

1.3 x 10

9 (rel.) k/k cns — = 0.114 p.r. opt. c.k. 75-1072

3.510 methanethiol 7 OH + CH3 SH

H2 0 + CH3 S

See also methylsulfide ion

3.3 x 10 10 (rel.)

(3.553).

k/kctis— = 3.04 p.r. opt. c.k. 69-0553

3.511 methanol (MeOH) 1 5.3 x 10

8 (rel.) k/kfe 2+ = 2.3 Fenton chem. c.k. 49-0002

(I) OH + CH3 OH 7 h 2 o + CH2 OH

6.0 x 10

s (rel.) klk t - = 0.046 ±

0.004

p.r. opt. c.k.; meas. I 2 at 400 nm.

65-0010

(II) OH + CH3 OH ^10.5

H 2 0 + ch 3 o

9.7 x 10

8 (rel.) klk M- = 0.n y-r. trac. c.k.; formn. of

,4C0 2

.

65-0099

7 8.8 x 10 8 (rel.) = 2.4 p.r. opt. c.k. 65-0190

10.7 8.4 x 10

8 (rel.) k/kcmib = 2.3 p.r. opt. c.k. 65-0190

7.0 7.7 x 10

8 (rel.) = 0.07 p.r. opt. c.k. 65-0190 — 5.7 x 10

8 (rel.) klk tm0 = 0.061 phot. — c.k. 65-0247

9.0 1.1 x 10

9 (rel.) k/k RNO = 8.6 ±

0.4) x 10'2 y-r. opt. c.k. 65-0356

2 7.4 x 10

8 (rel.) k/kcfis - — 0.067 p.r. opt. c.k. 65-0387

7 8.0 x 10

s (rel.) k/k CNS - = 0.073 p.r. opt. c.k. 65-0387

4.5 3 x 10

8 y-r. chem. est. from yields

in carboxylation

of methanol.

65-0375

2-2.2 8.6 x 10

s (rel.) k/k lbym = 0.16 ±

0.015

y-r. opt. c.k. 65-0388,

67-0461

5-5.5 9.4 x 10

8 (rel.) ^,hym = 0.175 ±

0.015

y-r. opt. c.k. 65-0388,

67-0461

47
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.511 cont. — klk bi.uH = 550 p.r. opt. c.k.; obs. formn. 66-0019

of S04 at 450 nm.

6 8.6 x 10

8 (rel.) ^/^EtOH = 0-464 y-r. chem. c.k. with Br“. 66-0423

9 1.0 x 10

9 (rel.) klk£t0H = 0.555 y-r. opt. c.k. with RNO. 66-0423 — 5.5 x 10 8 (rel.) k/k x - = 0.046 p.r. opt. c.k.; meas. I 2 at 400 nm.

67-0041

2 2.8 x 10

9 (rel.) k/knno = 0.22 Fenton opt. c.k. 67-0555 — — klk TCOO— =0.3 y-r. trac. c.k.; meas.

3 HHO

produced.

68-0209

9 1 x 10

9 (rel.) ^/^RNO = 0.08 y-r. opt. c.k. 68-0310 — 8.0 x 10

8 (rel.) 03 o 1 II © p.r. opt. c.k.; obs. 68-0304

8.3 x 10 8 (rel.) k/k PA - = 0.105 hydroxycyclohex—

8.3 x 10

8 (rel.)

6.4 x 10

8 (rel.)

^/^PNBA - = 0.32 adienyl radical buildup.

~1.2 k/k 2-prOH = 0.29 y-r. chem. c.k. 68-0602

6.98 7.9 x 10

8 (rel.)

9.5 x 10 8 (rel.)

k/k 2-PfQw = 0.36 y-r. chem. c.k.; /la = 0.1;

ratio = 0.34 at

IX = 1.1.

68-0602 — k/

k

rno = 0.076 p.r. opt. c.k. 69-0156

1 1.1 x 10

9 (rel.) k/k lhym = 0.206 Fenton esr c.k.; k/k^ = 69-5278

15.0.

1 9.8 x 10® (rel.) k/k xhym = 0.18 Ti(III) esr c.k.; k/k^Iol = 69-5278 - H2 0 2 12.8. 9 1.1 x 10

9 (rel.) klk^Q = 0.09 y-r. opt. c.k.; Et =

— 1.9 ± 0.08 kcal/ mol(7.9kj/mol) at -8 to 23°C.

71-0469

,nat. 8.6 x 10

8 (rel.) klk Uno = 0.0925 p.r. opt. c.k. 71-0578

0.82 9.9 x 10

8 (rel.) k/k Fe 2+ = 4.30 Fenton chem. c.k. 71-9132

k u/k x = 0.075 p.r. opt. hydroxymethyl

radical identified by reaction with TNM, methoxy

radical by I .

73-0126

-1 1.3 x 10

9 (rel.) klk^oH =0.63 y-r. chem. obs. effect of alcohols on oxid. Sb(III) — Sb(IV).

73-0289

10.4 1.2 x 10

9 (rel.) k/

k

FxoH =0.62 X-r. lum. obs. effect, of 73-6068

alcohols on quenching

chemiluminescence

from fluorescein. For other ratios see: 3.8, 3.10, 3.12, 3.25, 3.27, 3.41, 3.50, 3.54, 3.58, 3.66,

3.71, 3.80, 3.82, 3.88, 3.90, 3.91, 3.100, 3.102, 3.103, 3.106, 3.107, 3.112, 3.129,

3.131, 3.132, 3.144, 3.225, 3.246, 3.271, 3.304, 3.319, 3.358, 3.368, 3.386, 3.436,

3.446, 3.478, 3.500, 3.503, 3.546, 3.592, 3.593, 3.636, 3.637, 3.669, 3.673, 3.680,

3.698, 3.711, 3.755. 3.512 methanol—d3 6 4.2 x 10

8 (rel.) k/k e,oh = 0.227 p.r. chem. c.k. with Br . 66-0423

OH + CDjOH -* HDO + CD2 OH

3.513 methionine 6-7 8.5 x 10

9 (rel.) k/k CNS~

- = 0.77 p.r. opt. c.k. 65-0387

2 -2.2 6.5 x 10

9 (rel.) k/k thym = 1.2 y-r. opt. c.k. 65-0388

5.5- 8.1 x 10

9 (rel.) k/kcns~- = 0.74 p.r. opt. c.k. 65-0388

5.7 6.6 6.5 x 10

9 (rel.) k/k rno = 0.52 y-r. opt. c.k. 73-0548

3.514 methoxyacetate ion 9 6.0 x 10 8 (rel.) k/k e,oh = 0.323 y-r. opt. c.k. with RNO. 66-0423

3.515 p- methoxy benzoate 9 5.0 x 10

9 (rel.) k/k EtOH = 2.7 y-r. opt. c.k. with RNO. 66-0441

ion 3.516 2- methoxyethanol 9 1.3 x 10

9 (rel.) k/k e,oh = 0.7 y-r. opt. c.k. with RNO. 66-0423

48
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.517 5— methoxyindole 9.0 (1.39 ± 0.04) x 10 10 — •y-r. opt. c.k. with RNO; 71-0556

(rel.) rel. to £(OH +

tryptophan) =

(1.25 ± 0.3) x 10

10

. 3.517a 1 — methoxy-2— 1 .7-1.8 8.6 x 10

9 (rel.) ^/^2-PrOH — 3.9 Fenton chem. c.k. with 1 — 74-9006

methyl— 1 —

phenylpropane

1.5 x 10 10 (rel.)

phenylethanol.

3.518 o— methoxyphenol 9 ^/^RNO = 1.18 ± y-r. opt. c.k. 72-0837

0.15 3.519 p— methoxyphenol 9 1.45 x 10

10 (rel.) ^/^RNO = 1.15 ± y-r. opt. c.k. 72-0837

0.23 3.520 p— methoxyphenyl- — 7.0 x 10

9 (rel.) — p.r. opt. c.k. with RNO; 71-0056

/3-D-gluco- rel. to &(OH + X) =

pyranoside

1.1 x 10 10 (rel.) ^/^CNS~• = 1.04 p.r. opt.

4.4 x 10

9 where

X = phenyl-/3~Dglucopyranoside.

c.k. 71-0056

3.521 /V-methylacetamide 5.5 1.6 x 109 (rel.) ^/^CNS~ = 0.146 p.r. opt. c.k. 70-0098,

OH + CHjCONHCH3 71-0645

ch 3conhch2 + h2 o

3.522 methyl acetate 1 2 x 10® (rel.) k/k Fc 2+ = 0.85 Fenton chem. c.k. 49-0002

6i-7 1.2 x 10® (rel.) k/k CNS

-- = 0.0106 p.r. opt. c.k. 65-0387

2.0 1.3 x 10® (rel.) k/k CNS

-- = 0.0121 p.r. opt. c.k. 65-0387

9 1. 1 x 10® (rel.) ^/^ElOH = 0.0595 y-r. opt. c.k. with RNO. 66-0423

3.523 methylamine 12 2.4 x 10

9 (rel.) k/

k

EtOH = 1.3 y-r. opt. c.k. with RNO. 66-0423

OH + CH3 NH2 -+ 11.5- 4.7 x 10

9 (rel.) = 1.47 p.r. opt. c.k. 69-0573

h 2 o + CH2 NH2 12.5 + CH3 NH 10.5 1.8 x 10 9 (rel.) k/k CNs~ = 0.16 p.r. opt. c.k. 71-0595

11.1 3.3 x 10

9 (rel.) k/k nr = 1.04 p.r. opt. c.k.; at pH 9.7, 12.8 ratio = 0. 13 and 1.5, resp.

71-0595

3.524 methylammonium ion 5 1.9 x 10

7 (rel.) k/k E,OH = 0.0103 y-r. opt. c.k. with RNO. 66-0423

6-8 7.5 x 10

7 (rel.) k/k nr = 0.0234 p.r. opt. c.k. 69-0573

2 2.8 x 10

? (rel.) k/k Ctis~

- = 0.0025 p.r. opt. c.k. 70-0371

4 3.5 x 10

7 (rel.) klk CNS~

- = 0.0032 p.r. opt. c.k. 70-0371

7 5.9 x 10

7 (rel.) klk CfiS -- = 0.0054 p.r. opt. c.k. 70-0371

3.525 methylarabinoside 6.5 2.4 x 10

9 (rel.) k/k RNO = 0.19 ± y-r. opt. c.k. 69-0580

0.04 3.526 2-methyl-2-butanol 9 1.85 x 10

9 (rel.) k/k EiOH = 1.0 y-r. opt. c.k. with RNO. 66-0423

3.527 3- methyl- 1 -butanol — 3.8 x 10

9 (rel.) k/k CNs~

- = 0.34 p.r. opt. c.k. 73-1077

(isoamyl alcohol) 3.4 x 10

9 (rel.) k/k fetTO == 0.36 3.528 methyl butyrate 6-7 1.7 x 10

9 (rel.) k/k cns“ = 0.152 p.r. opt. c.k. 65-0387

3.529 2-methylbutyrate 9 2.2 x 10

9 (rel.) k/k £,OH = 1.18 y-r. opt. c.k. with RNO. 66-0423

ion 3.530 3-methylbutyrate 9 2.3 x 10

9 (rel.) klk EloH = 1.27 y-r. opt. c.k. with RNO. 66-0423

ion 3.531 3-methylbutyric 1 7.6 x 10® (rel.) klk Fe 2+ = 3.3 Fenton chem. c.k. 49-0002

acid 3.532 5-methylcysteine 5.4 8.0 x 10

9 (rel.) keens'- = 0.73 — — c.k.; pAa = 2,8.8. 73-0090

11.0 7.9 x 10 9 (rel.) k/k cns”

- = 0.72 3.533 5-methylcytosine 4.2 (4.7 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 450 nm. 70-3069

6-7 5.2 x 10

9 (rel.) k/k^no = 0.42 y-r. opt. c.k.; 17°C. 75-0294

3.534 methylene blue — 4.1 x 10

10 (rel.) k/k E|OH = 22 y-r. chem. c.k. ; obs. 71-0682

OH + MB+ —> MB2+ + G(-MB +

). OH'

3.535 (V-methylformamide 5.5 1.2 x 10

9 (rel.) k/k CNS

-- = 0.11 p.r. opt. c.k. 70-0098

3.536 methylgalactoside 6.5 1.6 x 10

9 (rel.) k/k rno = 0.13 ± y-r. opt. c.k. 69-0580

0.01 3.537 methylglucoside 6.5 2.4 x 10

9 (rel.) k/k rno = 0.19 ± y-r. opt. c.k. 69-0580

0.02 3.538 O-methylhydroxyl- 4.5 ^ 4.0 x 10® (rel.) klk Cfis~

- = 0.036 p.r. opt. c.k. 71-0493

amine 9.1 1.4 x 10

10 (rel.) k/kcNs'- = 1.3 p.r. opt. c.k. 71-0493

49
Tabi.K 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.538a N—methylimidazole 5.4 9.4

5.0 x 10 9

8.1 x 10

9 — p.r. opt. p.b.k.; p.Ka = 7.0; OH addn.

75-1066

3.539 1 — methylindole 9.0 (1.45 ± 0.01) x 10

10

(rel.)

y-r. opt. c.k. with RNO;

rel. to i(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.540 2— methylindole 9.0 1.44 x 10 lc (rel.) y-r. opt. c.k. with RNO;

rel. to &(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

9.0 (3.41 ± 0.28) x 10

10 — p.r. opt. p.b.k. at 320 nm. 71-0556

3.541 3— methylindole 9.0 (1.05 ± 0.09) x 10 10

(rel.)

y-r. opt. c.k. with RNO;

rel. to fc(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

9.0 (3.34 ± 0.08) x 10

10 — p.r. opt. p.b.k. at 320 nm. 71-0556

3.542 5— methylindole 9.0 (1.66 ± 0.06) x 10

10

(rel.)

y-r. opt. c.k. with RNO;

rel. to fc(OH +

tryptophan) =

1.25 x 10

10

.

71-0556

3.543 N— methylisobutyr— 5—6 1.9 x 10

9 (rel.) amide

methyl mercaptan See methanethiol (3.510).

k/k cns - = 176 p.r. opt. c.k. 71-0414

3.543a 2— methyl^4— 1.7— 1.8 phenyl—2— butanol

6.8 x 10

9 (rel.) k/k 2-PrOH =3.1 Fenton chem. c.k. with cyclo—

heptanol.

74-9006

3.543b 2— methyl-5— 1.7— 1.8 phenyl—2— pentanol < 4.4 x 10

7 (rel.) kIk

2

-pyoh = ^ 0.02 Fenton chem. c.k. with 3—

pentanol.

74-9006

3.543c 2— methyl— 1— 1.7-1.

8

phenyl- 1— propanol

1.1 x 10

10 (rel.) k/k 2 —ptoh — 5.0 Fenton chem. c.k. with 1—

phenylethanol.

74-9006

3.543d 2— methyl— 1— 1.7-1.

8

phenyl— 1 —

propanol- \—d

9.9 x 10

9 (rel.) k1 k 2 -ptoh = 4.5 Fenton chem. c.k. with 1—

phenylethanol.

74-9006

3.543e 2-methyl— 1— 1.7— 1.8 phenyl—2— propanol

2.0 x 10

10 (rel.) k/k 2-PrOH = 9-0 Fenton chem. c.k. with cyclo—

heptanol.

74-9006

3.544 N—methylpivalamide 5-6 2.4 x 10

9 (rel.) k/k CNS - = 0.218 p.r. opt. c.k. 71-0414

3.545 2— methyl— 1— pro— 7 3.3 x 10

9 (rel.) k/k CNS - = 0.303 p.r. opt. c.k. 65-0387

panol 9 3.5 x 10

9 (rel.) k/kpxQH =1.9 y-r. opt. c.k. with RNO. 66-0423

(isobutanol) 2-2.2

OH + (CH 3 ) 2 CHCH 2 OH

3.8 x 10

9 (rel.) klk t hym = 0.70 ±

0.05

y-r. opt. c.k. 67-0461 — (CH 3) 2 CHCHOH

(75%, 69-0522) + h 2 o + CH 3 CH(CH 2 )CH 2 OH, etc.

3.6 x 10

9 (rel.) 2.6 x 10

9 (rel.)

k/kcNS~ = 0-33

klk Uno = 0.28

p.r. opt. c.k. 73-1077

3.546 2-methyl— 2— propa— 1 1.4 x 10

s (rel.) k/k fc 2+ = 0.0065 Fenton chem. c.k. 49-0002

nol (tert- buta- 7 4.2 x 10

8 (rel.) k/k CNS - = 0.038 p.r. opt. c.k. 65-0387

nol) 9 4.6 x 10

8 (rel.) k/

k

£( oh = 0-25 y-r. opt. c.k. with RNO. 66-0423

(I) OH + 2-2.2

(CH 3 ) 3 COH —

7.3 x 10

8 (rel.) */* thym = 0.135 ± 0.015

y-r. opt. c.k. 67-0461

65-0388

(CH 3 ) 2 COHCH 2 + nat. 5.2 x 10

8 (rel.) k/k icno = 0.056 p.r. opt. c.k. 71-0578

H 2 0 0.82 4.3 x 10

8 (rel.) k/kye 2+ =1.90 Fenton chem. c.k. 71-9132

(II) OH + (CH 3 ) 3 COH -* H 2 0 + (CH 3 ) 3 CO

kjkl = 0.045 p.r. opt. detd. % alkoxy

radical by reaction with 1".

73-0126 — ~6 x 10

8 (rel.) klk(,,oH — 0.33 Fenton chem. c.k. 73-9105

7 5.8 x 10 8 (rel.) k/k MeoH = 0-65 Ti(III) + H9 09

esr obs. radical

ratios.

74-5144

1.7-1.

8

2.2 x 10

7 (rel.)

For other ratios see:

k!k 2-pxQw — 0.01

3.41, 3.97, 3.310, 3

Fenton

.343, 3.498.

chem. c.k. with 3—

pentanol.

74-9006

50
(KMHHII (1053

Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.547 ,/V-methylpropionamide

5-6 1 .4 x 109 (rel.) k/k CNS — = 0.13 p.r. opt. c.k. 71-0414

3.548 methyl propionate 6-7 4.5 x 10

8 (rel.) k/k cNS — = 0.041 p.r. opt. c.k. 65-0387

3.549 2— methylpropionate

ion (isobutyrate

ion)

9 1.3 x 10

9 (rel.) k/k EiOH = 0.68 y-r. opt. c.k. with RNO. 66-0423

3.550 2-methylpyridine 9 2.5 x 10 9 (rel.) k/k RN0 =

0.01

0.20 ± y-r. opt. c.k. 69-0280

3.551 3-methylpyridine 9 2.4 x 10

9 (rel.) II zOO

0.19 ± y-r. opt. c.k. 69-0280

3.552 methyl sulfide OH + CH3 SCH 3 ^

CH 3 S(OH)CH 3 -^ (CH 3SCH 3) + + OH

5.2 x 10

9 (rel.) p.r. opt. c.k. with MeOH,

2-PrOH and HCOO

meas. abs. at 470 nm (CH3 SCH3 ) +

.

67-0186

3.553 methylsulfide ion OH + CH 3 S"->

OH" + CH3 S

11 (6.0 ± 0.9) x 10

9 p.r. opt. p.b.k. at 410—420

nm. (RSSR ).

69-0553

3.554 methyl thiogly— 5.1 colate 10.6 5— methyluracil See thymine

Metronidazole See l-(2— hyd

2.1 x 10

10 (rel.) 1.8 x 10

10 (rel.) (3.711). roxyethyl)—2— methyl—5-

k/k cns — 1-9 k/kcNs~ = 1-6

-nitroimidazole (3.453).

p.r. opt. c.k. ; pK = 7.8 73-0090

3.555 1-naphthaleneacetic acid — 1 x 10

10 (rel.) k/k 2-PrOH = 4.6 y-r. chem. c.k. 72-0541

3.556 1 — naphthoate ion 9 7.9 x 10

9 — p.r. opt. p.b.k. 73-0110

3.557 2— naphthoate ion 9 7.6 x 10

9 — p.r. opt. p.b.k. 73-0110

3.558

3.559

nicotinamide

omitted

9.0 1.5 x 10

9 — p.r. opt. p.b.k. 71-0582

3.560 nicotinate ion 9

9.1

1.6 x 10

9 (rel.)

2.3 x 10

9

k/k rno =

0.01

0.13 ± y-r.

p.r.

opt.

opt.

c.k.

p.b.k.

69-0280

71-0582

3.561 nicotinic acid 3.1 2.6 x 10

8 — p.r. opt. p.b.k. 71-0582

3.562 nicotinuric acid 7.5 1.1 x 10

9 — p.r. opt. p.b.k. 71-0582

3.563

3.564

3.565

3.566

3.567

3.568

nitrilotriacetic acid 5-nitrobarbituric

acid nitrobenzene

OH + C 6 H 5 N0 2 - ohc 6 h 5 no2

k/k acrylamide 0.36Fenton pol.

5.9 (9.2 ± 0.9) x 10

7.8 x 10

9

1 6.7 x 10

8 (rel.) 10.5 2.2 x 10

9 (rel.)

9 3.3 x 10

9 (rel.) (4.7 ± 0.5) x 10

9

3.5 x 10

9 (rel.) 2.9 x 10

9 (rel.) 7 (3.2 ± 0.4) x 10

9

2.8 x 10

9 (rel.

)

k/kfe 2 + k/k BtO~

k/k f,oh

= 2.9

- = 0.39

= 1.8

klk CNS~ — 0.318

k/k e,oh = 1-55

k/k 3^0 = 0.49

p.r.

Fenton

y-r.

y-r.

p.r.

p.r. y-r.

p.r.

3.1 x 10

9 (rel.

)

kjk f = 0.25 ± yopt.

chem.

trac.

opt.

opt. opt.

opt.

opt.

:hem.

opt.

c. k.

.

b.k. at 420 nm.

d. k. at 350 nm.

.

k. c.k. ; meas. UC02 formn.

c.k. with RNO.

.

b.k. at 410 nm.

.

k. c.k. with RNO.

.

b.k. at 410 nm;

cor. for (OH + OH)

and (H + aromatic).

.

k.; meas. sali- cylate formn.

c.k.

72-9162

73-1003

49-

65-

66- 67-

67- 68 - 68-

0003

0099

0441 0458

0458

0157

0304

68-

0.01 For other ratios see: 3.12, 3.25, 3.66, 3.155, 3.168, 3.169, 3.191, 3.231,

3.233, 3.358, 3.362, 3.479, 3.506, 3.523, 3.524, 3.645, 3.646. nitrobenzene-Jr

p-nitrobenzoate

ion (PNBA)

9 6-9.4

3 x 10

9 (rel.) 2 x 10

9 (rel.) (2.6 ± 0.4) x 10 9

k/k E k/k E

= 1.64 = 1.06

y-r.

y-r.

p.r. OH + N02 C 6 H 4 C00"

N0 2 C 6 H 4(0H)C00'

an/i-5-nitro-2-

furaldoxime

(nifuroxime)

For other ratios see: 3.133, 3.186, 3.280-1, 3.284, 3.286, 3.358,

1.0 xlO 10 p.r.

opt. c.k. with RNO.

opt. c.k. with RNO.

opt. p.b.k. at 420 nm;

cor. for (OH + OH)

and (H + aromatic).

3.511.

opt. p.b.k. at 500 nm

as well as d.k. at 360 nm.

69

68 - 66 - 68

0494

0280

0157

0441 0304

73-1018

51
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.569 5— nitro-2—furalde— 7 5.5 x 10 9 — p.r. opt. p.b.k. at 500 nm 73-1018

hyde as well as d.k. at 360 nm.

3.570 5— nitro— 2— furalde— 7 1.06 x 10

10 — p.r. opt. p.b.k. at 500 nm 73-1018.

hyde semicarbazone as well as d.k. at 73-3016

(nitrofurazone) 360 nm.

3.571 5— nitrofuroate 7 5.3 x 10

9 — p.r. opt. p.b.k. at 500 nm 73-1018.

ion as well as d.k.

at 300 nm.

73-0114

3.572 5-nitroindole 9.0 (1.25 ± 0.24) x 10

l ° 7-r. opt. c.k. with RNO;

rel. to &(OH +

tryptophan) =

(1.25 ± 0.3) x

10

10

.

71-0556

3.573 nitromethane 9 3. 1 x 10

8 (rel.) k/k E,OH == 0.168 y-r. opt. c.k. with RNO. 66-0423 — =£ 8.4 x 10

6 (rel.) ^/^CNS~ =£ 7.6 x p.r. opt. c.k. 66-0800

10

4 3.574 nitromethane ion OH + CH2 =NO“~*

10.5 (8.5 ± 1.5) x 10

9 — p.r. opt. p.b.k. at 280 nm. 68-0342

CH 2 (0H)N0 2 3.575 5— nitro—6—

methyluracil

5.9 (5.3 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 420 nm. 73-1003

3.576 5— nitroorotate ion 5.9 (5.8 ± 0.6) x 10

9 — p.r. opt. p.b.k. at 420 nm. 73-1003

3.577 m— nitrophenol 9 7.1 x 10

v (rel.) ^/^RNO = 0.57 ± y-r. opt. c.k. 72-0837

0.05 3.577a o— nitrophenol 9 9.2 x 10

9 (rel.) ^/^RNO = 0.74 ± y-r. opt. c.k. 72-0837

0.06 3.577b p-nitrophenol — (3.8 ± 0.6) x 10

9 — p.r. opt. p.b.k. at 290 nm. 68-0303

OH + H0C h H 4 N0 2 —

»

d.k. at 400 nm. HOC 6 H4 NOJ+ h

+ 9 7.6 x 10

9 (rel.) k/k RNO = 0.61 ± y-r. opt. c.k. 72-0837

0.08

3.578 o-nitrophenyl-/3- d — — 3.0 x 10

9 (rel.) — y-r. opt. c.k. with RNO; 71-0056

glucopyranoside rel. to &(OH + X) =

4.4 x 10

9 where X =

phenyl )3-|)-glucopyranoside. — 4.8 x 10

9 (rel.) k/k CNS - = 0.44 p.r. opt. c.k. 71-0056

3.579 m-nitrophenyl— — 3.4 x 10

9 (rel.) — y-r. opt. c.k. with RNO; 71-0056

j8-I)-gluco- rel. to /c(OH + X) =

pyranoside 4.4 x 10

9 where X =

phenyl /3— p-gluco—

pyranoside.

3.580 p-nitrophenyl— — 2.8 x 10

9 (rel.) — y-r. opt. c.k. with RNO; 71-0056

/3-R-gluco- rel. to k x = 4.4 pyranoside x 10

9 where X =

phenyl /3-|)-glucopyranoside. — 4.3 x 10

9 (rel.) k/k cns~ = 0.395 p.r. opt. c.k. 71-0056

3.581 nitrosobenzene 7.0 1.1 x 10

10 — p.r. opt. p.b.k. at 285 nm. 66-0433

OH + C 6 H 5 NO -* 7.0 1.8 x 10

10 (rel.) k/k cns - = 1-67 p.r. opt. c.k. 67-0688, c 6 h 5 no2 + h

+ 66-0433

3.582 p-nitrosodimethyl- 9.0 ca. 1 .0 x 10

10 (rel.) — y-r. opt. c.k. with 18 dif- 65-0356

aniline (RNO) ferent compounds;

meas. loss of abs.

at 440 nm; k/k (ttTro = */*,- I I52
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.582 cont. — 1.8 x 10

10 — p.r. opt. d.k. at 440 nm. 68-0066 — (1.8 S ± 0.15) x 10

10

(rel.) — p.r. opt. c.k. with HCOO , I”, AsOj, N02

68-0066

7,9.0

(7.1 ± 0.5) x 10

9

(rel.)

y-r. opt. c.k. with Br , HCOO-

, EtOH.

In N2 0 saturated

solution with concn. of above

scavengers for complete OH

removal, dye

still bleaches.

68-0066

7 (1.25 ± 0.2) x 10

10 — p.r. opt. d.k. at 440 nm. 69-0156

For other ratios see: 3.9, 3.12, 3.23, 3.25, 3.27, 3.35, 3.39, 3.52, 3.54, 3.63,

3.64, 3.66, 3.70, 3.73, 3.82, 3.128, 3.131, 3.146, 3.148, 3.151, 3.155, 3.165, 3.166,

3.172, 3.177, 3.180, 3.181, 3.184, 3.186, 3.191, 3.196, 3.216, 3.217, 3.219, 3.236,

3.244, 3.248, 3.253, 3.254, 3.259, 3.260, 3.265, 3.268, 3.269, 3.291, 3.294-5, 3.318,

3.340, 3.341, 3.345, 3.348, 3.358, 3.367, 3.375, 3.384, 3.388, 3.390, 3.391,

3.392, 3.394, 3.395, 3.399, 3.400, 3.403, 3.405, 3.428, 3.429, 3.442, 3.446, 3.448,

3.449, 3.456, 3.457, 3.461, 3.461a, 3.462, 3.463, 3.464, 3.465, 3.466a, 3.473,

3.474, 3.483a, 3.484, 3.485, 3.492, 3.494, 3.497, 3.498, 3.504, 3.511, 3.513, 3.518,

3.519, 3.525, 3.533, 3.536, 3.537, 3.550, 3.551, 3.560, 3.565, 3.577, 3.583, 3.590,

3.592, 3.607, 3.608, 3.614, 3.615, 3.633, 3.637, 3.648, 3.648a, 3.649, 3.651-5, 3.657a

3.660, 3.663, 3.664, 3.666, 3.669, 3.674, 3.676, 3.677, 3.689, 3.708, 3.711, 3.714,

3.715, 3.716, 3.728, 3.733, 3.737, 3.743, 3.746, 3.749, 3.749a, 3.750, 3.751, 3.753, 3.754a. 3.583 p-nitro-o- toluene-- 1.6 x 10

9 (rel.) k/k rno — 0. 128 r. opt. c.k. 72-0425

sulfonic acid 3.584 5-nitrouracil 5.9 (5.4 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 420 nm. 73-1003

7.4 x 10

9 d.k. at 350 nm. — (6.5 ± 1) x 10

9 — p.r. opt. p.b.k. as well

as d.k.

73-0145

3.585 norleucine 2.2 3 x 10

9 (rel.) */*,h,m = 0.55 ± -y-r. opt. c.k. 67-0461

0.06

3.586 norpseudopellet- 10.5 6.7 x 10

9 (rel.) */* c.rb = 18.4 p.r. opt. c.k.; cor. for 71-0061

tierine TV— oxyl

(NPPN)

CO^+ NPPN.

7 (4.7 - 4.2) x 10

9 — p.r. opt. d.k. at 242 nm. 71-0061

3.587 norvaline 2-2.2 1.5 x 10

9 (rel.) */*.hyo, = 0.28 ± y-r. opt. c.k. 67-0461

0.02 3.588 1-octanol 2-2.2 6.5 x 10

9 (rel.) */*,hym = 1.20 ± y-r. opt. c.k. 67-0461

0.15

3.589 ornithine 2-2.2 1.7 x 10

8 (rel.) */*.hym = 0.032 ± y-r. opt. c.k. 67-0461

0.003

3.590 orotate ion 5.2 5.8 x 10

9 (rel.) */*f.rro=0.62 p.r. opt. c.k. 70-0567

11 5.3 x 10

9 — p.r. opt. p.b.k. at 340 nm (OH adduct).

70-0567

11 5.0 x 10 9 p.r. opt. d.k. at 280 nm

(5,6-double bond);

ave. £(pH 5—11) by

all methods =

5.2 x 10

9

; k decreases at pH < 5.

70-0567

6-7 4.5 x 10

9 (rel.) rno = 0.36 y-r. opt. c.k.; 17°C. 73-0294

3.591 orotidine 7 4.0 x 109 — p.r. opt. p.b.k. (OH 70-0567

adduct).

53
Tabi.K 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment

3.592 oxalate ion 9.0 OH + C 2 04 ~->

8.4 x 10

6 (rel.) k/k RNO = 6.7 X 10“4 (± 15%)

y-r. opt. c.k. OH+COOCOO' 9-13 —> co2 + co2 + OH'

k 1 k ncoo =

k(0 + C 2 04 )/ k(0~ + HCOO)

y-r. trac. meas. formn. of h2 c 2 o4

.

7 1 x 10

7 (rel.) k/k £t oH = 0.00565 y-r. chem. c.k.

7 1 x 10 7 (rel.) ^MeOH= 0-0112 y-r. chem. c.k.

7 — klk^ = 0.208 y-r. opt. c.k. 6 7.8 x 10

6 (rel.) k/k cNS - = 0.0007 p.r. opt. c.k. — 1 .6 x 10

7 (rel.) k/k x - = 0.0012 p.r. opt. c.k.; obs. I

2 formn.

3.593 oxalate ion, 2.7 hydrogen

5.6 x 10® (rel.) 6.9 x 10 8 (rel.) ^/^EtOH = 0.3

k/k MeOH = 0.77

y-r. chem. c.k. OH + hc 2 o;^ 3 OH” + C02 + C02 H

4.7 x 10

7 (rel.) k/k cns = 0.00425 p.r. opt. c.k.

3.594 oxalic acid 1.3, OH + (COOH)2 -* 2.7 < 10

7 (rel.) — y-r. chem. c.k. with MeOH

and EtOH.

H 2 0 + C02 +C02 H 2.0-

2.2

9.2 x 10

6 (rel.) klk lhym = (1.7 ±

0.7) x 10'3 y-r. opt. c.k.

0.5 1.45 x 10 6 (rel.) k/k CNs~ = 0.00013 p.r. opt. c.k. 1.5

For other ratios

k/kcx- = 1.3

see: 3.382, 3.427.

X-r. pol. effect of Cl and

oxalic acid on

reaction of U (VI).

3.594a oxytocin ~6 (1.3 ± 0.2) x 10

10 — p.r. opt. p.b.k. at 330 nm.

3.595 papain 6.4 4.7 x 10

10

paraldehyde See 2,4,6— trimethyl— 1,3,5— trioxane (3.731).

p.r. opt. p.b.k. at 310—

350 nm.

5.596 DI. — penicillamine 1 5.9 x 109 (rel.) */**,«= 1-09 Fenton esr c.k.; */*p.r.x = 79.2. 3.597 penicillamine 1 disulfide

8.1 x 10

9 (rel.) k/k lhym = 1.5 Fenton esr c.k.; klk^TOI =

110. 3.598 pentaerythritol 9 3.2 x 10

9 (rel.) k/kfrOH = 1-73 y-r. opt. c.k. with RNO

3.599 1,4— pentadien-3— 7.0

ol

(1.0 ± 0.2) x 10

10 — p.r. opt. p.b.k.

3.600 pentafluorobenzene 4 x 10

9 (rel.) ^/^cns— = 0.36 p.r. opt. p.b.k. 3.600a pentamethylbenzene ~7 7.5 x 10

9 p.r. opt. p.b.k.; OH addn. and H abstr.; rate

for H abstr. = 2.4

x 10

9

. 3.601 1,5-pentanediol 9 pentanoate ion See valerate

3.5 x 10

9 (rel.) ion (3.752).

k/k eioh = 1-9 y-r. opt. c.k. with RNO.

3.602 1-pentanol 9 4.9 x 10

9 (rel.) k/k e,oh = 2.65 y-r. opt. c.k. with RNO.

2-2.2 5. 1 x 10

9 (rel.) */**,. = 0.95 ±

0.10

y-r. opt. c.k.

5-5.5 5.5 x 10

9 (rel.) klk thym = 1.02 ±

0.10

y-r. opt. c.k. — 3.7 x 10

9 (rel.) 3.5 x 10

9 (rel.) ^/^cns - = 0.34

k/k CNs~ ~ 0.38

p.r. opt. c.k.

3.602a 3-pentanol 1.7— 1.8 2.4 x 10

9 (rel.) klk2-PrOH = 1-1 Fenton chem. c.k. with cycloheptanol. 3.603 2-pentanone 6-7 1.9 x 10

9 (rel.) klk cns- = 0.174 p.r. opt. c.k. 3.604 3-pentanone 6-7 1.4 x 10

9 (rel.) pentylamine See amylamine (3.168). pentylammonium ion See amylammonium ion

k/kcNS~ = 0.123

(3.169).

p.r. opt. c.k.

3.605 phenethyl alcohol 7.0 x 10

9 (rel.) 5.1 x 10

9 (rel.)

k/kcNs~ = 0.64

klk Cfi S — = 0.55

p.r. opt. c.k.

3.606 phenethylammonium 4 9.8 x 10 9 (rel.) k/kcns — = 0.89 p.r. opt. c.k. ion

65- Ref.

0356

66-

0151,

66-0621

67-

0131,

66-0621

67-0131

70-

1050

71-

0041

73-0020

67-0131,

66-0621

71-0041

66-0621,

67-0131

67-0461

71-0041

71-0542

74-1102

72-3042

69-5278

69-5278

66-0423

73-1070

73-0054

75-1009

66-0423

66-

0423

67-

0461

67-0461

73-

1077

74-

9006

65-0387

65-0387

73-1077

70-0371

54
Tabi.K 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.607 phenol 7.0 6.2 x 10 9 (rel.) k/k Bzo - = 1.08 y-r. trac. c.k. ; meas. UC02

. 65-0099

OH + C6 H5 OH 6-7 1.8 x 10

10 (rel.) = 1.61 p.r. opt. c.k. 65-0387

C 6 H 5(OH) 2 9 8.6 x 10

9 (rel.) k/kftOH = 4.64 y-r. opt. c.k. with RNO. 66-0441

7.4- (1.4 ± 0.3) x 10

10 — p.r. opt. p.b.k. at 330 nm. 67-0122

l . 1 ~1.2 9.7 x 10 9 (rel.) k/k 2-PrOH = 4.4 y-r. chem. c.k. 68-0602

6.98 1.1 x 10

10 (rel.) k/k 2-PrOH = 5.2 y-r. chem. c.k. 68-0602

9 8.5 x 10

9 (rel.) k/k rno = 0.68 ± y-r. opt. c.k. 72-0837

0.02 3.608 phenoxide ion 10.7 9.2 x 10

9 (rel.) k/k Bzo~ == 1.62 y-r. trac. c.k. ; meas.14 C02

. 65-0099

OH + C 6H50“

C 6 H 5(0H)0

3.608a p-phenoxybenzoate — 7.0 x 10

9 — p.r. opt. p.b.k.; OH addn. 75-1001

ion 3.609 phenylacetamide 9 5 x 10

9 (rel.) k/k eioh = 2.73 y-r. opt. c.k. with RNO. 66-0441

3.610 phenyl acetate 9 5 x 10

9 (rel.) k/k £( oh = 2.73 y-r. opt. c.k. with RNO. 66-0441

3.611 phenylacetate ion 9 4.6 x 10

9 (rel.) k/k EtOH = 2.36 y-r. opt. c.k. 66-0441

(PA") 6-8 (7.9 ± 1.1) x 109 — p.r. opt. p.b.k. at 325 nm. 68-0304

cor. for (OH + OH)

and (H + aromatic).

For other ratios see: 3.199, 3.200, 3.358, 3.511. 3.612 phenylacetic acid 1 1. 1 x 10

9 (rel.) 1.8 x 10

10 (rel.)

k/k Fc 2+ = 4.8

k/k 2-pfoh = 8.2

Fenton

y-r. chem.chem.

c.k. c.k.

49-0003

72-0541

3.613 phenylalanine. 2-2.2 5.7 x 10

9 (rel.) k/k CfiS - = 0.515 p.r. opt. c.k. 65-0388

positive ion 2-2.2 7.7 x 10

9 (rel.) klk thym = 1.42 ±

0.08

y-r. opt. c.k. 65-0388,

67-0461

3.614 phenylalanine,

zwitterion

5.5-6 5.8 x 10

9 (rel.)

nat. 6 x 10

9 (rel.) nat. 6.6 x 10

9

6.9 7.2 x 10

9 (rel.) For other ratios see:

k/kcws = 0-83

klk lmo = 0.645

k/k rno = 0-57

3.178, 3.347, 3.697.

y-r.

p.r.

p.r. y-r.

opt.

opt. opt.

opt.

c.k.

c.k.

.

b.k. at 300 nm.

.

k.

65-0388,

67-0461

71-0578

71-0578

73-0548

3.615 phenylalanine, 10.6 8.4 x 10

9 (rel.) klk caTb = 23 p.r. opt. c.k. 68-0062

negative ion — 1.5 x 10

9 frel.) k/k rno = 0.12 p.r. opt. c.k. 69-0156

3.615a 1 — phenyl—3—

butanol

1.7-1.

8

2.0 x 10

10 (rel.) k/k 2-PrOH = 9 Fenton chem. c.k. with 1 —

phenylethanol.

74-9006

3.615b 1 — phenylethanol 1.7-1.

8

1.3 x 1()

10 (rel.) k/k 2-pk)h = 6.8 Fenton chem. c.k. with cycloheptanol.

74-9006

3.615c

1-

phenylethanol1 -d

2-

phenylethanol Se

1.7-1. 8 1.3 x 10'° (rel.)

’e phenethyl alcohol (3.605).

k/k 2-pkjh = 6-9 Fenton chem. c.k. with bromo—

phenylethanol.

74-9006

3.616 phenyl-/3-pglucopyranoside

6.8 4.4 x 10 9 — p.r. opt. p.b.k. at 300 nm. 71-0055,

71-0056

OH + C 6 H 5 OC 6 H n - C 6 H 5(OH)OC 6 H

0 5 5.8 x 10

9 (rel.) .i°5For other ratios see: 3.580, 3.729.

k/kcss~ = 0-63

3.213, 3.255, 3.256, 3.274,

p.r. opt.

3.337, 3.458, 3.520,

c.k.

3.578, 3.579,

71-0055,

71-0056

3.617 phenylhydroxylamine3.7-

11.5

1.5 x 10'° — p.r. opt. p.b.k. at 290 nm. 67-0191,

67-0688

OH + C 6 H 5 NHOH

-> C 6H5(OH)NHOH

2 x 10

l ° (rel.) k/kcNS~ ~ 1-82 p.r. opt. c.k. 67-0688

3.617a 1-phenyl- 1 —

propanol

1.7-1.

8

1.2 x 10

10 (rel.) k/k 2-PrOH = 8.5 Fenton chem. c.k. with 1 —

phenylethanol.

74-9006

3.617b l-phenyl-2-

propanol

1.7-1.

8

2.4 x 10

10 (rel.) k/k 2-PrOH = H Fenton chem. c.k. with 1 —

phenylethanol.

74-9006

3.617c 2-phenyl-2-

propanol

1.7-1.

8

5.3 x 10

9 (rel.

)

k/k 2-PrOH = 2.4 Fenton chem. c.k. with cycloheptanol.

74-9006

3.618 phthalate ion 9 5.9 x 10

9

3.0 x 10

9 (rel.) —

p.r. y-r.

opt.

opt.

.

b.k.

.

k. with RNO

assuming A(OH +

sulfanilic acid) = 2.93 x 10

9

.

73-01 10 73-0094

55
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

k/k thym = 0.55 ± y—r. opt. c.k. 67—0461

0.06

3.619 pimelic acid 2-2.2 3 x 10 9 (rel.)

3.620 pinacol 1 2.9 x 10 8 (rel.) 9 5.4 x 10

8 (rel.) 3.621 pivalamide 5-6 1.4 x 10

9 (rel.) 3.622 pivalate ion 9 1.4 x 109 (rel.) 3.623 polyacrylate ion — (3.2 - 4.5) x 10

:

(rel.)

3.624 polyadenylic acid 4.6 1.6 x 10

8 (rel.) (poly A) 5.9 2.8 x 10

8 (rel.) 6.3 3.6 x 10

8 (rel.) 7.3 3.8 x 10 8 (rel.) 7 (9 ± 1) x 10

8

3.625 polyadenylic + 7

00 +1 X O

LO — uridylic acid

(poly A + U)

3.626 polycytidylic acid 7 (1.2 ± 0.1) x 10

9

(poly C)

3.627 polyethylene oxide 7.3 > 2.4 x 10

8 (rel.) H abstr.

7 > 10

9 (rel.)

< 2.0 x 10

9 (rel.)

(2. 8-7. 6) x 10

8 (rel.)

k/k Fc 2 + = 1-25 Fenton chem. c.k. 49-0002

k/k^Qw = 0.29 y-r. opt. c.k. with RNO. 66-0423

k/k CNS - = 0.132 p.r. opt. c.k. 71-0414

k/k Fton = 0.78 y-r. opt. c.k. with RNO. 66-0423

p.r. opt. c.k. with RNO

and CNS'; k depends on chain

length; at mol.

wt. 9 x 10

3 k =

(1—>3) x 10 8 as pH

varies 2 —> 8.

73-1095

k/k criS - = 0.015

k/k CNS - = 0.025

k/kctiS - = 0.033

k/k CNS — = 0.035

p.r. opt. c.k. ; rate in terms of nucleotide concn.

68-0845 — p.r. opt. p.b.k. 73-1071 — p.r. opt. p.b.k. 73-1071

p.r. opt. p.b.k. at 425 nm;

e = 780 ± 80; mol. wt. > 10

5

.

73-1071

klkcy.t = 2.86

x 10"2 p.r. opt. c.k.; k based on monomer unit of mol. wt. 44, and

*«,.,= 8-5 x 10

9

.

69-0088

p.r. opt. c.k. with CNS , BzO and RNO;

k based on monomer unit; varies with chain length

and concn.

70-0394

r. vise. c.k.; k >>2.0

x 10

6

; effect

of dioxane on

crosslinking;

rel. to k(OH +

dioxane) = 2.35 x 10

9

.

70-2058

— p.r. opt. c.k.; k depends

on concn. and mol.

73-1046

~ 1 x 10

9 (rel.) k/k

3.628 poly(ethylenesul— 1.2 x 10® (rel.) k/k

fonate) (polyanion) 3.629 polyoxyethylene— 1.1 x 10 10 (rel.) k/k (15)nonylphenol

(Igepal CO-730)

wt. of polymer;

rel. to ferro— cyanide or 1 . = 0.026 r. chem. c.k.; effect of 73-2129,

Br” on product

yields, assume

/c(OH + Br') =

3.7 x

10'°.

73-2126

- = 0.0106 p.r. opt. c.k.; concn. in monomer units.

68-0352

- = 1 p.r. opt. c.k.; concn. 71-0001 < 10'4 M\ at higher concn.

k decreases.

71-0586

56
T \hi.k 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.630 poly(styrenesul— 3.3 x 10 8 (rel.) k/kCNS - = 0.0303 p.r. opt. c.k.; concn. in 68-0352

fonate)

(polyanion) monomer units.

3.631 polyuridylic acid 7 < (3.8 ± 0.4) x 10

9 — p.r. opt. p.b.k. 69-0571

(poly U) 7 1.4 x 10

9 (rel.) k/kCNS~ = 0.13 ± p.r. opt. c.k.; rate 69-0571

0.06 per base unit.

7 (1.25 ± 0.05) x 10

9 — p.r. opt. p.b.k. at 390 nm. 73-1071

3.632 polyvinyl— 7 > 10 '° (rel.) — p.r. opt. c.k. with CNS , 70-0394

pyrrolidone BzO and RNO; k varies with chain

length and is per monomer unit. 3.632a proflavine (1.0 i: 0.2) x 10

10 p.r. opt. d.k. at 444 nm;

deduced k = 2 x 10

9

for dye bound to DNA.

75-3094

3.633 proline 2—2.2 3.1 x 10 8 (rel.) k/k thym

-= 0.0565 y-r. opt. c.k. 65-0388

6.8 6.5 x 10

8 (rel.) k/

k

risjo

== 0.052 y-r. opt. c.k. 73-0548

3.634 1,2-propanediol 7 1.7 x 10

9 (rel.) k/k cns - = 0.153 p.r. opt. c.k. 65-0387

(I)0H + C 3 H 8 0 2 9 1.7 x 10

9 (rel.) k/

k

eioh = 0.9 y-r. opt. c.k. with RNO. 66-0423

MeCHOHCHOH 6 1.6 x 10

9 (rel.) k/k EtOH = 0.855 y-r. chem. c.k. with Br . 66-0423

or MeCOHCH >OH 2-2.2 1.9 x 10

9 (rel.) klk lhym == 0.35 ± y-r. opt. c.k. 67-0461

+ H 2 0 0.03

(II) OH + C 3 H 8 0 2 — k\\!k l = 0.26 p.r. opt. detd. % a—alco— 73-0126

-* CH 2 CHOHCH2 OH hoi radical by + h 2 o reaction with TNM

=£ 0.1% alkoxy radical detd. by reaction with I . 3.635 1,3-propanediol 9 2.4 x 10

9 (rel.) k/k eioh = 1.3 y-r. opt. c.k. with RNO. 66-0423

6 2.0 x 10

9 (rel.) k/k e,oh = 1.1 y-r. chem. c.k. with Br . 66-0423

3.636 1-propanol (PrOH) 1 6.0 x 10

8 (rel.) k/k pe 2+ = 2.6 Fenton chem. c.k. 49-0002

(I) OH + PrOH -> 7, 2.7 x 10

9 (rel.) k/k carb == 7.5 p.r. opt. c.k. 65-0190,

H,0 + MeCH2CHOH 10.7 65-0387

(61%, 69-0522) 7 2.5 x 10

9 (rel.) k/k cns - = 0.223 p.r. opt. c.k. 65-0387

(II) OH + PrOH -> 9 2.8 x 10

9 (rel.) k/k El0H = 1.5 y-r. opt. c.k. with RNO. 66-0423

H 2 0 + MeCHCH2 0H 2-2.2 3.2 x 10

9 (rel.) k/k t hy m

== 0.60 ± y-r. opt. c.k. 67-0461

(III) OH + PrOH -* 0.05 H 20 + MeCH2CH20 -5-5.5 3.0 x 10

9 (rel.) k/k thym == 0.56 ± y-r. opt. c.k. 67-0461

0.06

nat. 2.7 x 10

9 (rel.) k/k („jo == 0.29 p.r. opt. c.k. 71-0578 — — ku/k\ = 0.86 p.r. opt. detd. % of 73-0126

kiu/k\ 55 0.01 a—alcohol and

alkoxy radicals by

reaction with TNM and I

, resp. — 1.5 x 10

9 (rel.) k/k mcoh = 1.65 Ti(IIl) + H,0,

esr c.k. 73-5253

3.637 2-propanol (2-Pr()H) 1 6.9 x 10® (rel.) k/k 2 + = 3.0 Fenton chem. c.k. 49-0002

(1) OH + 2- PrOH —> 7 2.2 x 10

9 (rel.) k/k x - = 0.17 ± p.r. opt. c.k. 65-0010,

H 2 0 + (CH 3 ) 2 COH 0.006 67-0041

(89%), 69-0522) — 2.1 x 10

9 (rel.) k/k(er,o == 0.23 phot. — c.k. 65-0247

(II) OH + 2-PrOH 9.0 2.1 x 10

9 (rel.) k/k RNO ;= 0.17 y-r. opt. c.k. 65-0356

-^H 2 0+ 7 6.5 x 10

9 (rel.) k/k cns = 0.591 p.r. opt. c.k. 65-0387

CH 3 CHOHCH2 2-2.2 2.1 x 10 9 (rel.) k/k ,h, m

:= 0.387 y-r. opt. c.k. 65-0388

(III) OH + — 3.2 x 10

9 (rel.) k/k MeOH = 3.6 p.r. opt. c.k. with HS04

. 66-0019

2— PrOH -» H 2 0 + 6.8 1.4 x 10

9 (rel.) k/k (erro == 0.15 ± X-r. — c.k. 66-0234

CHjCHOCHj 0.03 6 2.2 x 10

9 (rel.) k/k F.iOH = 1.2 y-r. chem. c.k. with Br . 66-0423

9 2.0 x 10

9 (rel.) k/k eioh = 1.1 y-r. opt. c.k. with RNO. 66-0423

57
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction

3.637 cont.

pH k Ratio Source Method Comment

2-2.2 2.3 x 10 9 (rel.) */*.by- = 0.42 ± y-r. opt. c.k. 0.03 5-5.5 2.3 x 10

9 (rel.) klk*ym = 0.42 ± y-r. opt. c.k. 0.05 — — kjk tcoo — 0.45 y-r. trac. c.k.; meas.

3 HHO.

2-10 1.9 x 10 9 (rel.) ^/^cns - = 0- 17 p.r. opt. c.k. — 1.5 x 10

9 (rel.) k/k RNO = 0. 12 p.r. opt. c.k. — k l /k n = 6.2 r. — c.k. with H2 02

. — *,/*„= 5.2 ± y-r. chem. c.k. with H2 02 ; 0.1 *h/* d

(I) = ±

0.05; k H lk D(U) =

2.08 ± 0.12 or 2.15 ± 0.16.

nat. 2.0 x 10 9 (rel.) */*«.„. = 0.216 p.r. opt. c.k. 0.82 1.3 x 10

9 (rel.) (I) k\lkye 2+ = 5.73 Fenton chem. c.k. 0.82 2.1 x 10 8 (rel.) (II) k ulkyc 2+ = 0.92 Fenton chem. c.k. 0 — klk^ [HS041 y-r. chem. c.k.; computer = 202 ± 12 AT1 anal.; 4 M H2 S04

. 0.8 — uiftHSO,! y-r. chem. c.k.; computer = (1.1 ± 0.2) x anal. 10 4 M

_1

0 — kui/ki — 1-4 ± y-r. chem. calcd. by compar0.3 ing oxid. of Ce(III) in HCOOH

and 2—PrOH solns. — — k l /k u = 6.4 p.r. opt. detd. % of k m/k l = 0.014 a—alcohol and

alkoxy radicals by reaction with TNM and I", resp. 10.4 2.3 x 10 9 (rel.) k/k^iQH = 1-23 X-r. lum. c.k.; effect of alcohols on quenching of chemiluminescence from

fluorescein.

3.638

3.639

3.640

2-propanol-2-d 6

(I) OH + 0.82 (CH 3 ) 2 CDOH^

HDO + (CH 3 ) 2 COH

(II) OH + (CH 3 ) 2 CDOH -h> H 2 0 + CH 2 CDOHCH3 2-propanol-d6 0.82

(I) OH + (CD 3 ) 2 CHOH

H 2 0 + (CD 3 ) 2 COH

(II) OH + (CD 3 ) 2 CHOH -* HDO + CD3 CHOHCD2 propionamide 5-6

OH + C 2 H 5 CONH -> H 2 0 + CH3 CHCONH2 + CH 2 CH 2 CONH2 + CH 3 CH 2 CONH

For other ratios see : 3.12, 3.66, 3.80, 3.107, 3.111, 3.186, 3.198a, 3.201, 3.212a,

3.248a-3.249, 3.274, 3.277-8, 3.337a, 3.358, 3.371, 3.375a, 3.384, 3.385, 3.468,

3.469, 3.471, 3.511, 3.517a, 3.543a-e, 3.546, 3.555, 3.602, 3.607, 3.612, 3.615a-c,

3,617a-c, 3.687, 3.695a.

1.4 x 10

9 (rel.) k/kftOH = 0.78 y-r. chem. c.k. 7.9 x 10 8 (I) (rel.) k ll k ye 2+ = 3.42 Fenton chem. c.k. 2.1 x 10

8 (II) (rel.) k\i/k re 2+ = 0.91

1.2 x 10

9 (I) (rel.) k \l k ye 2 + = 5.43 Fenton chem. c.k. 5.0 x 10

7 (II) (rel.) k III kye 2+ = 0.22

7.0 x 10

8 (rel.) k/k CNS — - 0.064 p.r. opt. c.k. CH3 CHCONH2 formed; anal, of transient spectra.

Ref.

67-0461 67-

0461 68-

0209

68-

0316

69-

0156

70-

0104

71-

0081

71-0578

71-9132

71-

9132

72-

0094

72-0094

72-0094

73-0126

73-6068

66-0423

71-9132

71-9132

71-0414,

71-0645
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.641 propionate ion 9 8.0 x 10

8 (rel.) k/k EtOH = 0-43 y-r. opt. c.k. with RNO. 66-0423

3.642 propionic acid 1 2.0 x 10

8 (rel.) k/k Fe 2+ = 0.86 Fenton chem. c.k. 49-0002

2-2.2 5.2 x 10 8 (rel.) */* thym = 0-097 ± y-r. opt. c.k. 67-0461

0.01 3.643 propionitrile — 1.0 x 10

8 (rel.) ^/^hcoo- = 0.029 y-r. chem. c.k. 73-0364

3.644 propyl acetate 6-7 1.4 x 10 9 (rel.) ^cns- = 0-124 p.r. opt. c.k. 65-0387

3.645 propylamine — 7.3 x 109 (rel.) k/k cns - = 0.66 p.r. opt. c.k. 73-0016

4.8 x 10

9 (rel.) ^/^NB = 1-5 2— propylamine See isopropylamine (3.487). 3.646 propylammonium 2 7.5 x 10

8 (rel.) k/k cns - = 0.068 p.r. opt. c.k. 70-0371

ion 4 1.6 x 10

9 (rel.) k/k CNS - = 0.143 p.r. opt. c.k. 70-0371 — 1.4 x 10

9 (rel.) k/k cns - = 0. 13 p.r. opt. c.k. 73-0016

6.7 x 10

9 (rel.) k/k NB = 0.21 3.647 propylene — 8.3 x 10

9 (rel.) A#,- = 0.64 p.r. opt. c.k. 67-0041

propylene oxide See 1,2— epoxypropane (3.353). 3.648 propyl gallate 6.5 1.2 x 10

10 (rel.) k/k RNO = 0.94 ± y-r. opt. c.k. 69-0580

0.16 3.648a purine 6-7 3.0 x 10 8 (rel.) k/k rno = 0.024 y-r. opt. c.k.; 17°C. 75-0294

3.649 pyridine 7 (3.0 ± 0.6) x 10

9 k/k cns - = 0.272 ± p.r. opt. c.k. 67-0251

OH + C SHS N (rel.) 0.054 OHC s H 5 N + 9 2 x 10

9 (rel.) k/k Rjvjo = 0. 16 y-r. opt. c.k. 69-0280

C 5 H 5 N-OH 7.0 1.8 x 10

9 — p.r. opt. p.b.k. 71-0582

3.650 pyridine-d5 7 (2.7 ± 0.9) x 10

9 k/k cns - = 2-42 x p.r. opt. c.k. 67-0251

(rel.) 10

-1 (± 0.073) 3.651 3— pyridine— 9 1 x 10

9 (rel.) k/k rno = 0.08 y-r. opt. c.k. 69-0280

carboxamide

3.652 4— pyridine— 9 1.5 x 10

9 (rel.) k/kjmo — 0.12 y-r. opt. c.k. 69-0280

carboxamide

3.653 3-pyridinecar- 9 2.3 x 10

9 (rel.) 50 Zo

II © s y-r. opt. c.k. 69-0280

boxylate ion 3.654 4—pyridinecar- 9 2.6 x 10 9 (rel.) k/k RNO — 0.21 y-r. opt. c.k. 69-0280

boxylate ion 3.655 4-pyridinenitrile 9 7.5 x 10® (rel.) k/kjifio = 0.06 y-r. opt. c.k. 69-0280

3.656 pyridinium ion 1 4.1 x 10 7 (rel.) k/k Fe 2+ = 0.18 Fenton chem. c.k. 49-0002

OH + C 5 H5 NH + ^ 1-2 (3.3 ± 0.7) x 10

7 k/k cns~ = (3 ± p.r. opt. c.k. 67-0251

ohc 5 h 5 nh + (rel.) 0.6) x 10~3

2.0 2 x 10

7 — p.r. opt. p.b.k. 71-0582

3.657 pyridinium ion-ds 1-2 3.6 x 10

7 (rel.) ^/^cns — = (3-3 ± p.r. opt. c.k. 67-0251

1) x 10'3

3.657a pyridoxine(PH) 7.2 6.3 x 10

9 — p.r. opt. p.b.k. 75-1024

ph 2 + 3.6 4.3 x 10

9 —

P" 10.5 7.4 x 10 9 —

3.657b pyrimidine 6-7 1.6 x 10

8 (rel.) k/kftNo = 0.013 y-r. opt. c.k.; 17°C. 75-0294

3.658 pyrrole — 1.5 x 10

l ° — p.r. opt. p.b.k. at 300 nm. 71-0360

OH + C 4 H4 NH

(OH)C 4 H4 NH

3.659 pyrrolidinium ion 6.2 5.7 x 10

9 (rel.) k/kcNS~ = 0.52 p.r. opt. c.k.; see also 75-1016

70-0006.

3.660 pyruvate ion 9 3.1 x 10 7 (rel.) k/k rno = 0.0025 y-r. opt. c.k.; assume 67-0555

^RNO = k [orro- 3.661 rennin 6.4 2.1 x 10

10 (rel.) — X-r. biol. effects of 73-3030

methanol, malonate,

glycerol, ethanol,

glycylglycine,

formate, glucose

and adenine on enzyme inacti3.662 Rhodamine B ~ 10

10 (RhB)

vation.

opt. d.k. at 530 nm 67-0239,

(RhB) as well as 67-6053

p.b.k. at 460 nm. 59
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.663 ribonuclease — 2.6 x 10 10 (rel.) — p.r. opt. c.k. with CNS-

; 68-3007

(T = 20°C) mol. wt. 13,683;

5.2 x 10 10 (rel.) (T = 60°C)

ref. rate not given.

3.5 (3.6 ± 0.5) x 10

10 — p.r. opt. p.b.k. 72-3079

5.6 (1.9 ± 0.3) x 10 10 —

~7 (2.4 ± 0.6) x 10 10 —

6.5 2.5 x 10 10 (rel.) k/k RNO = 2 -y-r. opt. c.k. 73-0548

3.664 ribose 9 2.1 x 10

9 (rel.)

4.4 x 10 s (rel.)

k/k RNO = 0.17 -y-r. opt. c.k.; assume

^rno = k (cm .

67-0555

6.5 k/k RNO = 0.035 ± y-r. opt. c.k. 69-0580

0.03

7 1.6 x 10

9 (rel.) k/k CNS - = 0.145 p.r. opt. c.k. 73-1071 — 1.2 x 10

9 (rel.) ^/^CNS - = 0.11 p.r. opt. c.k. 73-1077 — 1.0 x 10

9 (rel.) = 0.101 p.r. opt. c.k. 73-1077

3.665 ribose—5—phosphate: 7 1.3 x 10 9 (rel.) k/k cns - = 0.12 p.r. opt. c.k. 73-1071

3.666 RNA 6.5 1 .9 x 10 9 (rel.) ^/^RNO = 0.15 ± y-r. opt. c.k. 69-0580

0.02 3.667 Safranine T

(S.T)

3-5.5 9.3 x 10

9 (rel.) k/k phH = 1.19 y-r. chem. c.k.; OH addn. 69-0279

3.668 Safranine T, pro—

tonated (S.TH +

) OH + S.TH + —»

0.4 3.4 x 10

10 (rel.) k/k Phll = 4.35 y-r. chem. c.k. 69-0279

OH-S.TH +

3.668a salicylaldehyde 9 8.6 x 10 9 (rel.) k/k RNO = 0.69 ± y-r. opt. c.k. 72-0837

0.16 3.669 salicylate ion 10.7 5.8 x 10

9 (rel.) k/k Bzo~

'= 1.01 y-r. trac. c.k.; meas. 65-0099

OH + HOC 6 H 4COO - -^ uco 2

. (HO)2C 6 H4COCP 9.0 9.4 x 10

9 (rel.) klk Rfto = 0.752 ± y-r. opt. c.k. 65-0356

0.038

7 1.2 x 10 10 — p.r. opt. p.b.k. at 350 nm. 68-0305

7 2.0 x 10

10 (rel.) k/kcns~ = 1.8 ± p.r. opt. c.k. 68-0305

0.2 9 8.6 x 109 (rel.) k/k rno = 0.69 ± y-r. opt. c.k. 72-0837

0.16 3.670 sarcosine 5.0, 2.6 x 10

9 (rel.) k/k CNS~ = 0.236 p.r. opt. c.k. 71-0554

anhydride 11.0 3.671 sebacic acid 2-2.2 5.4 x 10

9 (rel.) k/k t hym = 1.00 ± y-r. opt. c.k. 67-0461

0.10

3.672 selenocystine 7 1.0 x 10

10 — p.r. opt. p.b.k. at 460 nm 73-1010

(RSeSeR) (RSe*); c.k. with CNS - gave

He = 1.7 x 10

10

. 3.672a selenomethionine 7 ~ 1 x 10

10 p.r. opt.

.

b.k. at 380 nm;

.

k. gave k/k CNS -

= 1.2.

74-1092

3.673 selenourea 6.5 6.9 x 10

9 — p.r. opt. d.k. at 250 nm. 70-0240

OH + NH 2 CSeNH 2 -> 5.5 x 10

9 — p.r. opt. p.b.k. at 410 nm. 70-0240

H 2 0 + NHCSeNH 2 1.2 x 10

10 (rel.) k/k cNS ~ = 1.09 p.r. opt. c.k. 70-0240

1.1 x 10 10 (rel.) k/k E(Oh == 6.2 p.r. opt. c.k. 70-0240

1.2 x 10 10 (rel.) k/k m,OH := 13.8 p.r. opt. c.k. 70-0240

3.674 serine 2-2.2 2.5 x 10

8 (rel.) k/kcNs~ = 0.0228 p.r. opt. c.k. 65-0388

5.5-6 3.2 x 10

s (rel.) k/kcns~ = 0.0288 p.r. opt. c.k. 65-0388

2-2.2 2.9 x 10

s (rel.) k/k lhym = 0.0532 y-r. opt. c.k. 65-0388

6.6 2.3 x 10 8 (rel.) k/k rno = 0.184 y-r. opt. c.k. 73-0548

3.675 serum albumin. — 2.3 x 10

l ° — — — — 66-0844

human — ~ 6 x

10'° — — — ealed. 70-0253

3.676 starch, corn 6.5 2.8 x 10

7 (rel.) k/k RNo = 0.0023 ± y-r. opt. c.k. 69-0580

0.002

60
Table 4. Reactions of OH with organic solutes —-Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.677 starch, waxy 6.5 2.5 x 10 7 (rel.) k/k rno = 0.002 ±

0.003

y-r. opt. c.k. 69-0580

3.678 styrene 5.5 (6.0 ± 0.6) x 109 p.r. opt. p.b.k. at 320 nm 74—1138

(66% C 6 Hs CHCH2 OH)

and 345 nm (33%

ring addn.). 3.679 suberic acid 2—2.2 4.0 x 10

9 (rel.) klktbym = 0.75 ±

0.07

y-r. opt. c.k. 67-0461

3.680 succinic acid 1 7 x 10

6 (rel.) k/k V' 2 + = 0.03 Fenton chem. c.k. 49-0002

2-2.2 1.4 x 10 8 (rel.) */*.hym = 0.026 ±

0.002

y-r. opt. c.k. 67-0461

1 8.9 x 10 7 (rel.) k/k MeOH = 0.097 Fenton chem. c.k.; ^MeOH/^Fe2+ = 4.3.

73-9341

3.681 succinimide 3.5 5.0 x 10 8 — p.r. opt. p.b.k. 71-0145

3.682 succinonitrile 3.0 x 10

7 (rel.) k/k\iQQQ~ - 0.012 y-r. chem. c.k. 73-0364

3.683 sucrose 2—2.2 2.8 x 10 9 (rel.) */*,hym = 0.52 ±

0.05

y-r. opt. c.k. 67-0461

3.684 sulfacetamide, Na 4.7 x 10

9 (rel.) — y-r. — c.k. with RNO. 71-0128

3.685 sulfaguanidine 3.1 x 10

9 (rel.) y-r. opt. c.k. with RNO

assuming l(OH +

sulfanilic acid) =

2.93 x 10

9

.

73-0094

3.686 sulfanilamide 3.2 x 10

9 (rel.) — y-r. — c.k. with RNO. 71-0128

1.6 x 10

9 (rel.) y-r. opt. c.k. with RNO;

rel. to £(OH +

sulfanilic acid) =

2.93 x 10

9

.

73-0094

7-8 1.9 x 10

9 (rel.) klk imo = 0.21 y-r. chem. c.k. 74-0283

3.687 sulfanilic acid 3.4 x 109 (rel.) — y-r. — c.k. with RNO. 71-0128

0.4 2.1 x 10 9 (rel.) k1 k 2—pxon = 0-^5 y-r. chem. c.k. 73-0270

2.93 x 10

9 p.r. For other ratios see: 3.189, 3.191, 3.700, 3.701, 3.702. sulfasuccidine See 4—(2— thiazolylsulfamoyl)succanilic acid (3.701). sulfathiazole See N'—(2— thiazolyl)sulfanilamide (3.702).

opt. p.b.k. at 270 nm. 73-0094

3.687a superoxide dis— 7.2 5.3 x 10 mutase

TAN See 2,2,6,6-tetramethylpiperidone-./V-oxyl (3.697).

p.r. opt. p.b.k. at 330 nm; 74-3081

rate for bovine enzyme; human enzyme

gave k = 4.6 x 10

10

.

3.688 tartaric acid 2-2.2 5.9 x 10 (rel.) klk thym = 0.11 ±

0.01

y-r. opt. c.k. 67-0461

3.689 tartrate ion 9 6.7 x 10 8 (rel.) klkjwo — 0.054 y-r. opt. c.k.; assume

k ferro =

^RNO'

67-0555

9 7.5 x 10

8 (rel.) klkftno ~ 0.06 r. opt. c.k.; Et = -1.2 ±

0.3 kcal/mol(-5kJ/

mol) (-8 to 23°).

71-0469

3.690 terephthalate ion 9 3.2 x 109 (rel.) k/kfrOH = 1-75 y-r. opt. c.k. with RNO. 66-0441

3.691 tetrachloro- ethylene

OH + CC1 2 =CC12 ^

(2.3 ± 0.3) x 10

9 p.r. condy. p.b.k. (CP); 71-0709

(CCl 2 CCl 2 OH

h

+ + cr + ccijcoci)

CC1 2 CC1 2 0H — (1.7 ± 0.3) x 10

9

(rel.)

p.r. opt. c.k. with CNS ; reference rate not

given.

71-0709

3.692 1,2,3,4-tetrafluorobenzene

5 x 10

9 (rel.) — p.r. opt. c.k. with CNS . 73-0054

3.693 tetrahydrofuran 1 1.4 x 10

9 (rel.) */*r.2+ = 6.2 Fenton chem. c.k. 49-0002

9 2.7 x 10

9 (rel.) k/k EtOH = f-46 y-r. opt. c.k. with RNO. 66-0423

3.694 tetrahydropyran 1 1.0 x 10

9 (rel.) k/k Fe 2 + = 4.5 Fenton chem. c.k. 49-0002

61
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.695 tetrahydroxysuc— 9 1.3 x 10 9 (rel.) ^/^EtOH == 0.7 -y-r. opt. c.k. with RNO. 66-0423

cinate ion 3.695a a-tetralol 1.7-1.

8.1 x 10

9 (rel.) kl k2-PrOH = 3.7 Fenton chem. c.k. with 1—

phenylethanol.

74-9006

3.695b 1,2, 3, 4—tetra— ~7 7.2 x 10 9 — p.r. opt. p.b.k.; OH addn. 75-1009

methylbenzene as well as H abstr.

rate for H abstr. =

1.9 x 10

9

. 3.695c 1,2, 3, 5—tetra— ~7 7.1 x 10

9 — p.r. opt. p.b.k.; OH addn. 75-1009

methylbenzene and H abstr.; rate

for H abstr. = 1.8 x 109

. 3.695d 1,2,4,5-tetra— ~7 7.0 x 10

9 — p.r. opt. p.b.k.; OH addn. 75-1009

methylbenzene and H abstr.; rate (Durene) for H abstr. = 1.8 x 10

9

. 3.696 N,N,N',N'—tetra— 7.1 7.7 x 10

9 — p.r. opt. p.b.k. at 400 nm; 74-1061

methyl— 1,2— dia— 7 3 x 10

9 (rel.) klk CtiS~ = 0.27 p.r. opt. c.k. 74-1061

zenedicarboxamide 10.3-

1110.5

4.8 x 10 9 (rel.) */* crb = 14.1 p.r. opt. c.k. 74-1061

3.697 2, 2, 6, 6—tetra- 3.8 x 10

9 (rel.) */* e«fa = 10.5 p.r. opt. c.k.; cor. for 71-0061

methylpiperidone CO”+ TAN.

TV— oxyl (TAN) 7 (4.1 ± 0.4) x 10

9 — p.r. opt. d.k. at 230 nm. 71-0061

5-6 < 10® (rel.) kl kicTTO < 10~2 p.r. opt. c.k. 71-0618

nat. (3.3 ± 0.3) x 10

9 k/k x = 5.2 ± 0.4 p.r. opt. c.k. with phenyl— 72-3021

(rel.) alanine (X); k x = 6.3 x 10

9

; cor. for H; obs. X abs. at 320 nm.

3.698 tetrasulfonated 10.7 7.3 x 10

9 (rel.) k>k «rb = 20 y-r. chem. c.k. 69-0827

Cu phthalo— 7.6 x 10

9 (rel.) kl k EtOH == 4.1 y-r. chem. c.k. 69-0827

cyanine 7.7 x 10

9 (rel.) kl k MeOH == 8.6 y-r. chem. c.k. 69-0827

3.699 tetronate ion 7 9.2 x 10

9 — p.r. opt. d.k. at 248 nm. 74-1053

3.700 thalamyd 6.3 x 10

9 (rel.) y-r. opt. c.k. with RNO

rel. to k(OH +

sulfanilic acid) =

2.93 x 10

9

.

73-0094

3.701 4— (2— thiazolyl— — 4.6 x 10

9 (rel.) — y-r. opt. c.k. with RNO 73-0094

sulfamoyl)- rel. to k(OH +

succinanilic acid sulfanilic acid) =

(sulfasuccidine) 2.93 x 10

9

. 3.702 N'—(2— thiazolyl)— — 7.8 x 10

9 (rel.) — y-r. opt. c.k. with RNO 73-0094

sulfanilamide rel. to k(OH +

(sulfathiazole) sulfanilic acid) =

2.93 x 10

9

. 3.703 thiodiglycolic 1 6.0 x 10

9 (rel.) klk CNS — = 0.546 p.r. opt. c.k. 65-0387

acid 3.704 thioglycolic acid 1 6.2 x 10

8 (rel.) kl k Fe2+

== 2.7 Fenton chem. c.k. 49-0002

3.705 thioglycolate ion 6.6 5.9 x 10

9 (rel.) kl k CNS - = 0.53 p.r. opt. c.k. ; pKt = 3.7, 73-0090

11.1 5.5 x 10

9 (rel.) kl k CNS— = 0.05 10.3 for thioglycolic acid. 3.706 thiolactate ion 7.2 1.7 x 10

10 (rel.) kl k CNS- = 1.55 p.r. opt. /II Tf* 6 A a *• 73-0090

10.8 1.6 x 10 10 (rel.) klk CNS~ = 1.45 10.7 for thiolactic acid. 3.707 thiophene

OH + C 4 H 4 S -> — 3.3 x 10

9 (rel.) kl k CNS - = 0.304 p.r. opt. c.k. 71-0360

(OH)C 4 H 4 S

3.708 threonine 2-2.2 3.9 x 10

8 (rel.) klk lhym = 0.0727 y-r. opt. c.k. 65-0388

6.6 5.1 x 10

8 (rel.) k!k RNO = 0.041 y-r. opt. c.k. 73-0548

62
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.709 thymidine 2-2.2 4.6 x 10 9 (rel.) k/k cns~ = 0.417 p.r. opt. c.k. 65-0388

5-5.2 5.0 x 10

9 (rel.) k/k cns~ = 0.455 p.r. opt. c.k. 65-0388

7.4- 4.6 x 10

9 (rel.) klk CNS~ = 0.417 p.r. opt. c.k. 65-0388

7.6 ~7 4.7 x 109 — p.r. opt. p.b.k. at 375 68-0312

-12.4 2.1 x 10 9 (pH = 7) and 400

(pH = 12.4) nm.

5.6 (5.3 ± 0.5) x 10

9 — p.r. opt. p.b.k. at 400 nm. 70-3069

3.710 thymidylic 2-2.2 4.3 x 10

9 (rel.) k/kCfis~ ~ 0.394 p.r. opt. c.k.; NH4 salt. 65-0388

acid 6.5- 5.2 x 10

9 (rel.) k/kCNS- = 0.477 p.r. opt. c.k.; NH4 salt. 65-0388

7.0 3.711 thymine 0.7- 3.7 x 10

9 (rel.) ^/^EtOH = 2.00 ± y-r. opt. c.k. 65-0133

OH addn. to 7 0.10 5,6—double bond 1 5.2 x 10

9 (rel.) klk CNS — = 0.47 p.r. opt. c.k. 65-0387

2-2.2 5.2 x 10

9 (rel.) k/kcNs~~ = 0.47 p.r. opt. c.k. 65-0388

5-5.5 5.0 x 10

9 (rel.) k/k CNS - = 0.455 p.r. opt. c.k. 65-0388

7.2- 5.3 x 10 9 (rel.) k/kcns - = 0.485 p.r. opt. c.k. 65-0388

7.4

2 7.8 x 10

9 (rel.) k/k RhH = 1 y-r. opt. c.k. 67-0461

9 6.2 x 10

9 (rel.) k/k rno = 0.5 y-r. opt. c.k.; assume

k ftrro = ^RNO’

67-0555

-7 7.4 x 10

9 — p.r. opt. p.b.k.; obs. 68-0312

-11 3.9 x 10 9 transient at 400

-12.4 1.1 x 10

9 and 550 (pH =

12.4) nm. — 5.6 x 10

9 (rel.) klk t - = 0.435 X-r. opt. c.k. 68-0359 — 4. 1 x 10

9 (rel.) ^•/^MeOH = ^ -55 X-r. opt. c.k. 68-0359 — 4.9 x 10

9 (rel.) k/k Et0H =2.63 X-r. opt. c.k. 68-0359

7 7.4 x 109 — p.r. opt. p.b.k. at 400 nm

(adduct).

68-0597

7 (7.4 ± 0.5) x 10

9 p.r. opt. d. k. ; obs. disappearance of 5,6—double bond

at 270 nm.

69-0571

7 (4.6 ± 0.3) x 10

9 — p.r. opt. p.b.k.; OH—adduct

obs. at 385 nm.

69-0571

7 7.6 x 10

9 (rel.) k/kcfis~ = (0.69 ± p.r. opt. c.k.; cor. for 69-0571

0.15) incomplete scav.

of e;

q by H2 0 2

.

1 — klk _= 72.4 Fe(II) esr c.k. 69-5278 + H2 C»2

1 — klk fcrox =7\.5 Ti(III) esr c.k. 69-5278 + H 2 C*2 6.1 (5.6 ± 0.4) x 10

9 — p.r. opt. p.b.k. at 400 nm. 70-3069

nat. 4.7 x 10

9 (rel.) k/kfeTTO = 0.505 p.r. opt. c.k. 71-0578

nat. 5.1 x 10

9 — p.r. opt. d.k. 71-0578

9 5.5 x 10

9 — p.r. opt. p.b.k. at 375 nm. 72-0047

6-7 4.7 x 10

9 (rel.) k/kjmo = 0.38 y-r. opt. c.k.; 17°C. 75-0294

For other ratios see: 3.25, 3.27, 3.129, 3.131, ,3.149, 3.150, 3.154, 3.160, 3.161,

3.162, 3.177, 3.180, 3.181, 3.182, 3.186, 3.225, 3.226, 3.239, 3.247, 3.266, 3.289-90,

3.291-94, 3.343, 3.346, 3.358, 3.361, 3.369, 3.371, 3.374, 3.384, 3.385, 3.394,

3.399, 3.400, 3.401, 3.402, 3.403, 3.404, 3.409, 3.410, 3.411, 3.415, 3.418, 3.419,

3.420, 3.421, 3.422, 3.423, 3.424, 3.425, 3.426, 3.435, 3.441, 3.461, 3.484, 3.491,

3.493, 3.497, 3.501, 3.503, 3.507, 3.511, 3.513, 3.545, 3.546, 3.585, 3.587, 3.588,

3.589, 3.594, 3.596, 3.597, 3.602, 3.613, 3.619, 3.633, 3.634, 3.636, 3.637, 3.642,

3.671, 3.674, 3.679, 3.680, 3.683, 3.688, 3.708, 3.735, 3.741, 3.753. 3.712 p-toluate ion 9 4.4 x 10

9 (rel.) k/k e,oh — 2.38 y-r. opt. c.k. with RNO. 66-0441

OH + CHjC 6 H 4 C00’9 8 x 10

9 — p.r. opt. p.b.k. at 340 nm. 72-0047

-» CH 3(OH)C 6 H 4 COO"

63
Tabi.i; 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.713 toluene 3

(I) OH + C 6 H s CH 3 ->

(3.0 ± 0.7) x 10 9 — p.r. opt. p.b.k. at 313 64-0115

and 309 nm. C 6 H 5CH2 + ~1

h 2 o

(11) OH + C 6 H S CH 3 -* C 6 H s(OH)CH 3

6.8 x 10

9

4.0 x 10

8

(I) /,//„ = 0.033

p.r. opt. p.b.k. at 73-0089,

258 nm (C 6 H 5 CH2

). 75-1009

3.714 o-toluenesulfonate

ion

3.2 x 10

9 (rel.) k/k RN0 = 0.258 r. opt. c.k. 72-0425

3.715 m— toluenesulfonate

ion

3.8 x 10

9 (rel.) /// Rno = 0.303 r. opt. c.k. 72-0425

3.716 p- toluenesulfonate 9 1.8 x 10 9 (rel.) — — — c.k. with RNO. 66—0843

ion 3.7 x 10

9 (rel.) klk RN0 = 0.294 r. opt. c.k. with RNO. 72-0425

3.717 <)— tolyl-/?-i)-gluco— 5.3 x 10

9 (rel.) k/k cns~ = 0.485 p.r. opt. c.k. 71-0056

pyranoside 3.4 x 10

9 (rel.) y-r- opt. c.k. with RNO; 71-0056

relative to A(OH +

X) = 4.4 x 10

9

, X =

phenyl-/?— p—gluco—

pyranoside. 3.718 w-tolyl—/?— p-gluco—

pyranoside

3.0 x 10

9 (rel.) y-r- opt. c.k. with RNO; 71-0056

relative to A(OH +

X) = 4.4 x 10

9

, X =

phenyl-/?— p—gluco—

pyranoside. — 6.2 x 10

9 (rel.) k/k'cns~ = 0-56 p.r. opt. c.k. 71-0056

3.719 /?— tolyl— /3— D —

glucopyranoside

2.7 x 10

9 (rel.) y-r- opt. c.k. with RNO; 71-0056

rel. to A(OH + X) =

4.4 x 10

9

, X =

phenyl-/?- r>— gluco—

pyranoside. — 3.6 x 10

9 (rel.) k/kcNs~ = 0-33 p.r. opt. c.k. 71-0056

3.720 p— tolyl —

^—

/3 — D — 8.7 x 10

9

thioglucopyranoside

triacetoneamine— /V-oxyl(TAN) See 2,2,6,6-tetramethylpiperidone— N—ox

p.r.

yl (3.697).

opt. transient absorbs 70—1056

at 320 nm.

3.720a tributyl phosphate 1.2 1.03 x 10

10 (rel.) k/k e,oh — 3 - 3 y-r. chem. c.k.; Z-7 Z-'hno3 = 74—0439

77. 3.721 1, 1,2-trichloro—

ethylene

OH + CHCI=CC1 2 -^

(4.0 ± 0.4) x 10

9 p.r. condy. p.b.k. (Cl"); 71-0709

(CHCIOHCCI,^ H

+ +

Cl" + CCl 2 CHO).

CHC1(0H)CC1 2 — (2.6 ± 0.3) x 10

9

(rel.)

p.r. opt. c.k. with CNS”; 71-0709

reference rate not given

3.722 2,4,6-trichlorophenyl-/3- 1 ) -glucopyranoside1.9 x 10

9 (rel.) y-r- opt. c.k. with RNO; 71—0056

rel. to /(OH + X) =

4.4 x 10

9

, X =

phenyl-/?- 1 ) -glucopyranoside.

3.723 triethylamine

(I) OH + El 3 N

H 2 0 + CH 3 CHNEt 2 (II) OH + Et 3 N

1.1 x 10

10 (rel.) k/k cns - = ^ p.r. opt. c.k.; extrapolat— 71—0585

ed value based on

/•//• CNS — = 0.73 at pH 11. -» 1I

2 0 + 12 CH 2 CH 2 NEt2

3.7 x 10

9

(I) (rel.) k il k EtoH = 2 y-r- chem. c.k.; no II 71-0590

obs.; may be

O reaction. 3.724 triethylammonium 1 1.8 x 10

8 (rel.) /•/* Fe 2+ = 0.8 Fenton chem. c.k. 49-0002

ion 3.6 3.5 x 10 s (rel.) /•// CNS - = 0.032 p.r. opt. c.k. 71-0585

(I) OH + Et 3 NH + —» 1.5, CH3 CHNH+Et2 6.5 + H 2 0

(II) OH + Et 3 NH + —

II 2 0 + CH 2 CH 2 NH + Et 2

1.3 x 10® (rel.) k \lk £iqw = 0.068 y-r- chem. c.k .;/„//,= 71-0590

0.76.

3.725 trifluoroacetate 9

ion

2 x 10

s (rel.) — — — c.k. with RNO. 66-0843

3.725a 1 ,2,3-trimethoxybenzene(8.0 ± 0.8) x 10

9 — p.r. — — 75-1171

64
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.725b 1,2,4-trimethoxy—

benzene

(8.1 ± 0.8) x 109 — p.r. — — 75-1171

3.725c 1,3,5-trimethoxy- (8.1 ± 0.8) x 109 benzene

trimethylacetate ion See privalate ion (3.622).

p.r. 75-1171

3.726 trimethylamine

OH + (CH3) 3 N -* H 2 0 + CH2 N(CH 3 ) 2

1.3 x 10 10 (rel.) ^/^CNS~ = 1.2 p.r. opt. c.k.; extrapolated value based

on k/k CNS- = 1.1

at pH 10.9.

71-0585

3.727 trimethylammonium 7.5 ion OH + (CH 3) 3 NH + -* h2o + CH 2 NH + (CH3) 2

4 x 108 (rel.) k/k cns - = 0.0364 p.r. opt. c.k. 71-0585

3.727a 1,2,3— trimethyl— ~7

benzene

7.0 x 10

9 p.r. opt. p.b.k.; OH addn.

as well as H abstr.

;

rate for H abstr. =

1.3 x 10

9

.

75-1009

3.727b 1,2,4— trimethyl— ~7

benzene

6.2 x 10

9 p.r. opt. p.b.k. ; OH addn. and H abstr.; rate

for H abstr. = 1.15 x 10

9

.

75-1009

3.727c 1,3,5— trimethyl- ~7

benzene

(Mesitylene)

6.4 x 10

9 p.r. opt. p.b.k.; OH addn. and H abstr.; rate

for H abstr. = 1.2 x 10

9

.

75-1009

3.728 2,4,6—trimethyl— 6.5 3— hydroxypyridine

2.5 x 10

9 (rel.) ^/^RNO =

0.03

0.20 ± y-r. opt. c.k. 69-0580

3.729 2,4,5—trimethyl—

phenyl-/3-D—glucopyranoside

3.2 x 10

9 (rel.) y-r. opt. c.k. with RNO;

rel. to &(OH + X) =

4.4 x 10

9

, X =

phenyl—j8—D—gluco—

pyranoside.

71-0056

3.730 trimethyl phosphate

OH + (CHs O)3 PO

H 2 0 + CH 2 0(CH 3 0)2 P0

1.2 x 10® (rel.) k/k CNS - = 0.011 p.r. opt. c.k. 72-3008

3.731 2,4,6-trimethyl- 9 1,3,5-trioxane

1 x 10

9 (rel.) k/

k

gtOH = 0.546 y-r. opt. c.k. with RNO. 66-0423

3.732 1,3,5-trioxane 9 4.9 x 10

8 (rel.) trypaflavin See acriflavin (3.141).

k/k EtOH = 0.264 y-r. opt. c.k. with RNO. 66-0423

3.733 trypsin

~7

2.5 x 10

10 (rel.)

(8.2 ± 1.2) x 10

10 —

X-r.

p.r.

biol

opt.

effect on enzyme

inact. compared

with acetone,

glycylglycine,

glycerol, glucose,

ethanol, formate

ion. p.b.k. at 330 nm.

or c.k. with glucose (k = lx

10

9

).

67-3044

71-3069

6.3 3.9 x 10

10 (rel.) k/k RNO = 3.1 y-r. opt. c.k. 73-0548

3.734 trypainogen 7.4 (8.5 ± 0.5) x 10 10

(rel.)

p.r. opt. c.k. with glucose

(k = 1 x 10

9

); obs. 330 nm abs.

71-3069

3.735 tryptophan, 2-2.2 1.1 x 10

10 (rel.) k/k CNS - = 0.985 p.r. opt. c.k. 65-0388

positive ion 2-2.2 7.7 x 10 9 (rel.) */*.hym =

0.15

1.42 ± y-r. opt. c.k.; k from

initial slope of competition plot.

65-0388,

67-0461

65
Table 4. Reactions of OH with organic solutes - Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.736 l,— tryptophan. 1 (1.25 ± 0.2) x 10

10 — p.r. opt. p.b.k. at 560 nm. 69-0459

positive ion 3.737 tryptophan. 6.1- 1.4 x 10 10 (rel.) klkCNS~ = 1.29 p.r. opt. c.k. 65-0388

zwitterion 6.3

6.2 7.8 x 10

9 (rel.) kl k RNO = 0.62 y-r. opt. c.k. 73-0548

3.738 L _ tryptophan. 8.8 (1.2 ± 0.3) x 10

10 — p.r. opt. p.b.k. at 310 nm. 69-0459

zwitterion For other ratios see : 3.211, 3.252, 3.273, 3.333, 3.334, 3.335, 3.454, 3.468, 3.470,

3.472, 3.517, 3.539, 3.540, 3.541, 3.542. 3.739 omitted

3.740 tyramine. 11.2 (1.5 ± 0.2) x 10

10 klk cm = 1.36 p.r. opt. c.k. 73-0003

negative ion

1 x 10

10 3.741 tyrosine. 2-2.2 (rel.) klklhym = 1.87 p.r. opt. c.k. 65-0388

positive ion 3.742 L —( —

)

tyrosine. 4.0 1.5 x 10

10 (rel.) k/

hcoo

-- = 4.2 p.r. opt. c.k.; meas. 68-0062

positive ion transient at 310—320 nm.

3.743 tyrosine, 5.2 (1.4 ± 0.3) x 10 10 kl k CNS = 1.3 p.r. opt. c.k. 73-0003

negative ion 6.5

(rel.) 1.05 x 10

10 (rel.) kl k RNO = 0.84 y-r. opt. c.k. 73-0548

3.744 tyrosine, 11.2 (1.3 ± 0.3) x 10

10 k/k cns - = 1.2 p.r. opt. c.k. 73-0003

dinegative ion (rel.) 3.745 L-(-)-tyrosine, 10.6 2 x 10 10 (rel.) */*c«b = 53.7 p.r. opt. c.k. 68-0062

negative ion 3.746 uracil 9.0 6.8 x 10

9 (rel.) kl k RNO = 0.542 ± y-r. opt. c.k. 65-0356,

OH + C 5 H6 N 2 02 - 0.027 67-0555

C 5 H 6 N 2 0 2 *OH 2-2.2 4.8 x 10

9 (rel.) kl k CNS - = 0.44 p.r. opt. c.k. 65-0388

5-5.2 5.2 x 10

9 (rel.) klk CNS - = 0.469 p.r. opt. c.k. 65-0388

7.3- 5.2 x 10

9 (rel.) kl k CNS - = 0.477 p.r. opt. c.k. 65-0388

7.5

7.0 (7.4 ± 1.0) x 10

9 — p.r. opt. d.k. at 270 nm. 68-0316

6.5 7.4 x 10

9 (rel.) kl k CNS - = 0.67 p.r. opt. c.k.; cor. for 68-0316,

e not scav. by

10

2 m h2 o2

.

69-0571

7 (6.0 ± 0.3) x 10

9 — p.r. opt. d.k. at 270 nm. 69-0571

7 (6.5 ± 0.7) x 10

9 — p.r. opt. p.b.k. at 385 nm. 69-0571

5.9 (5.8 ± 0.2) x 10

9 — p.r. opt. p.b.k. at 400 nm. 70-3069

nat. 4.2 x IQ

9 (rel.) Fierro = 0.452 p.r. opt. c.k. 71-0578 — 6.0 x 10

9 — p.r. opt. p.b.k. as well as

as d.k.

73-3016

6-7 4.5 x 10

9 (rel.) kl k RNO = 0.36 y-r. opt. c.k.; 17°C. 75-0294

For other ratios see: 3.289, 3.290. 3.747 uracil dinucleo— 7 (3.8 ± 0.2) x 10

9 — p.r. opt. d.k. at 270 nm. 69-0571

tide (UpU) 7 5.3 x 10

9 (rel.) kl k CNS - = 0.48 ± p.r. opt. c.k.; rates calcd. 69-0571

0.08 per nucleotide base.

uracil mononucleotides See uridine monophosphate (3.751). 3.748 uracil oligo— 7 (4.3 ± 0.2) x 10

9 — p.r. opt. d.k. at 270 nm. 69-0571

nucleotide 7 4 x 10

9 (rel.) klk CNS - = 0.36 ± p.r. opt. c.k.; rate calcd. 69-0571

(oligo U) 0.07 per nucleotide

base.

uracil polynucleotide (poly U) See polyuridylic acid (3.631). 3.749 urea 9.0 < 1.25 x 10

6 kl k RNO < 10~4 y-r. opt. c.k. 65-0356

3.749a uric acid 6-7 7.2 x 10

9 (rel.) kl k RNO = 0.58 y-r. opt. c.k.; 17°C. 75-0294

3.750 uridine 7 4.2 x 10

9 (rel.) kl k CNS - = 0.38 ± p.r. opt. c.k.; cor. for 68-0316,

0.08 incomplete scavenging of e\

q by

H2 02.

69-0571

7 (6.5 ± 0.5) x 10

9 — p.r. opt. d.k. at 270 nm. 69-0571

7 (4.1 ± 0.2) x 10

9 — p.r. opt. p.b.k.; OH adduct

obs. at 385 nm.

69-0571

6.5 2.4 x 10

9 (rel.) kl k RNO = 0.19 y-r. opt. c.k. 69-0580

66
Table 4. Reactions of OH with organic solutes — Continued

No. Solute and Reaction pH k Ratio Source Method Comment Ref.

3.750 cont. 5.4 (4.5 ± 0.3) x 10

9 — p.r. opt. p.b.k. at 400 nm. 70-3069

7 4. 1 x 10

9 (rel.) klk CfiS~ = 0.36 p.r. opt. c.k.; unpubl.

data.

73-1071

3.751 uridine monophos-- 7 5.2 x 10

9 (rel.) kl k CNS - = 0.47 ± p.r. opt. c.k.; cor. for 68-0316,

phate 0.1 incomplete scav. 69-0571

(uridylic acid)

7 (4.6 ± 0.3) x 109 p.r. opt.

of e,

q by H2 02

. d.k. at 270 nm. 69-0571

7 (4.0 ± 0.4) x 10

9 — p.r. opt. p.b.k.; OH

adduct obs. at

69-0571

385 nm.

6.5 2.5 x 10 9 (rel.) kl k RNO = 0.2 ± y-T. opt. c.k. 69-0580

0.02

7.0 (5.1 ± 0.3) x 10

9 — p.r. opt. p.b.k. at 400 nm. 70-3069

7 4.5 x 109 — p.r. opt. p.b.k. at 390 nm. 73-1071

3.752 valerate ion 9 2.9 x 10

9 (rel.) ^/^EtOH = 1.55 y-r. opt. c.k. with RNO. 66-0423

3.753 valine 2-2.2 7.2 x 10

8 (rel.) kl k , hy m = 0.134 y-r. opt. c.k. 65-0388

6.6 6.6 x 10 8 (rel.) kl k RHO = 0.053 y-r. opt. c.k. 73-0548

3.754 vinyl chloride — (7.1 ± 0.5) x 10

9 — p.r. opt. c.k. with CNS ; 71-0709

OH + CH2 =CHC1 -> (rel.) reference rate ch 2 ohchci not given.

vinyl methyl ketone See 1--butene-3—one (3.229). Vitamin B12 See c yanocobalamin (3.272a). Vitamin B12a See hydroxocobalamin (3.447). 3.754a xanthine 8.0 8.9 x 10

9 (rel.) kl k RNO = 0.71 y-r. opt. c.k.; 17°C. 75-0294

3.755 o—xylene ~7 6.7 x 10 9 p.r. opt. p.b.k.; OH addn. and H abstr.; rate

for H abstr. =

8.0 x 10

8

.

75-1009

3.756 m-xylene ~7 7.5 x 10

9 p.r. opt. p.b.k.; OH addn. and H abstr.; rate

for H abstr. 9.0 x 10

8

.

75-1009

3.757 p-xylene ~7 7.0 x 10

9 p.r. opt. p.b.k. ; OH addn. and H abstr.; rate

for H abstr. 8.4 x 10

s

.

75-1009

3.758 xylenol orange 11 2.2 x 10

10 (rel.) kl k MeOH == 24.5 y-r. opt. c.k. 71-0437

67
Table 5. Reactions of O with water, transients from water, inorganic solutes, and organic solutes

No. Solute and reaction pH k Ratio Source Method Comment

4.1 H2 0

o + h2 o^ 11 2 x 10

6 (rel.) k/k EtOH = (9.6 p.r. opt. c.k. with CO2

; OH' + OH ± 1.0) x 10'2 N2 0 and 02 -satd. MH2 0] solns.

11 1.5 x 10 6 (rel.) ^/^MeOH = p.r. opt. c.k. with CO2 '; ± 0.1) x 10' 1 N2 0 and 02 -satd. A4[H 2 0] solns. 8-8.8 (1.75 ± 0.4) x 10

6 — p.r. opt. c.k.; soln. con—

(rel.) tains ferrocyanide

with methanol or ethanol; assumed

k( O + ferro) =£ 3 x

10

7

, k(0 + EtOH) = 9.8 x 10

8

, k(0~ + MeOH) = 5.3 x 10

8

. 4.2 O —* 1st order 13- 4.3 x 10 4 s

1 (rel.) k/koiy = (1-2 f.phot. opt. d.k. of o;. decay 13.7 ± 0.24) x 10 5 dm 3 mol

>13 4.3 x 10

4 s1 (rel.) */*„,= ( 1.2 p.r. opt. d.k. of 03

. ± 0.4) x 10'5 dm 3 mol

4.3 e a„ O' + e~^~* 20H' alk. ~ 2 x 10

10 — — — See 1.9, SI. 5, NSRDS-NBS 43 and supplement.

4.4 OH

O' + OH —» H02 alk. < 2.6 x 10

10 See 3.4 (Table 2) 4.5 O'

0 + O'-* O

2 ' 12- ~ 1 x 109 p.r. opt. curve fitting; 13 N2 0-Fe(CN)4 '

soln. 13 8.3 x 10

9 (rel.) k/k oxy = 2.3 p.r. opt. c.k.; obs. 03

. >12 «9x 10

8 (rel.) p.r. opt. c.k. with

Fe(CN)g~; est. based on numerous

assumptions;

pK.(OH) = 11.9. 4.6 bh;

O' + bh;+ (H 2 0) 11- < 4 x 10

8 p.r. opt. calcd. from

BH 4 + 20H~ 12.83 p.b.k.; assumed

pAT.(OH) = 11.8 and k(OH + BH^) =

1.2 x 10

10

. 4.7 Br' 0- + Br ^BrO 2 - 13 4.5 x 10

7 (rel.) k/k 2-pion = 0.03 y-r. chem. c.k.; obs. Br0 2 -(+H2 0) G(acetone). Br + 20H' 6-7 2 x 10

8 (rel.) k/kpxOH = 0. 18 p.r. opt. c.k.; soln. k/k MeoH = 0.34 contains N 2 0

(^.'q + n 2 ° -* N 2 + O').

4.8 BrO'

O" + BrO'(+ H 2 0) 11- 4.4 x 10

9 (rel.) */*(OH + CO2 ') = p.r. opt. c.k.; pAT a(OH) =

-> BrO + O

2' or 13 11 11.9; p. = 0.4. BrO + 20H' 12- (2.0 ± 0.4) x 10

9 — f.phot. opt. d.k. of 03 ; 13 (rel.) anal, of data is complex.

Ref.

70-0511 70-

0511 71-

0137

68-

7277

69-

0002

73-0030

75-0002

64-0213

66-0001

66-0424

70-

1046

68-0602

71-

0137

68-

0153

69-

7340

68
Tabi.k 5. Reactions of O’ with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.9 BrC>2 O' + BrC> 2 (+ H 2 0) 13 1.7 x 10 9 (rel.) k/k(OH + CO2 ") = p.r. opt. c.k.; assume 68-0153

Br0 2 + 20H“ 4.5 *(OH + BrO^ =

1.9 x 10

9 and

pK.(OH) = 11.9;

ix = 0.4. 12 -

( 1.1 ± 0 . 2) x 10

9 — f.phot. opt. d.k. of Oj; data 69-7340

13 (rel.) anal, is complex.

4.10 BrO~

O’ + BrO^(+ H 2 0) 12- ( 1.2 ± 0 . 2) x 10

6 f.phot. chem. c.k. of O3 ; more 69-7340 —» Br03 + 20H" 13 (rel.) than one rate involved in calcn.; may be up to 30%

lower.

4.11 Br0 4

' 7 < 10

7 — p.r. opt. very slow or no reaction.

73-0106

4.12 CNS’

O' + CNS" (+ H 2 0) 13.5 1.0 x 10 9 p.r. opt. p.b.k.; assume 65-0386

-» CNSOH" + OH" product is CNS.

CNSOH- + CNS-^ 6-7 1.6 x 10

9 (rel.) ^/^EtOH = 1.5 p.r. opt. c.k. 71-0137

(CNS);+ OH" 1.6 x 10 9 (rel.) ^/^MeOH = 2.8 CNSOH- ^ CNS + al k - 1.1 x 10

9 — p.r. opt. p.b.k. at 0.36 M 71-0137

OH" NaOH; k = 1.3 x CNS + CNS- ^ 10

9 at 1.08 M

(CNS)" NaOH.

13 (3.7 ± 0.3) x 10

9 — p.r. opt. p.b.k. 72-0126

4.13 CO 2 " 0 + CO3 (+ H2 0) — =£ 10

7 p.r. opt. no details given. 66-0139 —» CO3 + 20H' 14 =£ 5 x 10

s — p.r. opt. p.b.k. 70-0247

4.14

3+ Ce

O’ + Ce3+ —» 2.3- 6.6 x 10

8 (rel.) ^/^EtOH = 0.6 ± p.r. opt. c.k.; assuming 71-0137

Ce 4+ + 20H 2.6 0.2 k(O + H2 0) =

1.75 x 10

6

. 4.15 CIO'

O'+CIO’-^ 13 ( 2.2 ± 0 . 1 ) x 10

8 k/k( OH + CO2 ') = p.r. opt. c.k. 72-0301

CIO + O

2 " (rel.) 0.6 4.16 CIO 2

' O'+CIO"^ 13 (1.7 ± 0.1) x 10

8 k/k(OH + CO2 ") = p.r. opt. c.k. 72-0301

cio 2 + O

2

' (rel.) 0.48

4.17 CIO 3 13 < 10

6 p.r. opt. no effect on COs formn. in carbonate

soln.

72-0301

4.18 Fe

2+ O’ + Fe

2+ —> 4.4- 3.5 x 10

9 (rel.) Wk ElOH = 3.2 ± p.r. opt. c.k. 71-0137

Fe

3+ + 20H' 4.8 1.2 4.19 Fe(CN)4 ' 0'+Fe(CN)4 " 13 5.8 x 10 8 (rel.) k/k MeOH = 0.98 y-r. chem. c.k.; assuming 63-0072

(+ HjO) —> Fe(CN) b

" that at pH = 13 + 20H" most of OH is present as O ; not

cor. for OH.

13 1.5 x 10

9 (rel.) k/

k

eioh = 1.36 p.r. opt. c -k-i k ElOH/k OTy = 0.35; not cor.

for OH.

65-0007

13 9 x 10 8 (rel.) k/k hcoo = 0.9 ± X-r. chem. c.k.; assuming 67-0064

0.1 k( O" + HCOO') = 1 10

9

; not cor. for

X

OH. — « 3 x 10

7 — p.r. opt. estd. from A' obt = 2.57 x 10

8 and

71-0137

69
Tablk 5. Reactions of O with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4. 19 cont. 1.6 x 10

8 for 0.366 and 1.11 M NaOH,

resp. 4.20 Fe0 4 , Fe0 2 14 — k t lk n = 0.03 y-r. chem. c.k. ; K = 10'4 67-0614

(I) 0“ + FeO 7 ' for Fe(OH)3 +

(+ H 2 0)^ HFeO7 OH' ^ Fe(OH)4- is

4- HO'

(II) 0 + Fe0 2 —>

involved in calcn.

FeOr

4.21 h 2 O' + h2 ^ h + 13.3 (8 ± 4) x 10 7 p.r. opt. rel. to 2k = 1.1 65-0009

OH' (rel.) x 10

10 for e~

q +

e;

q H 2 + 20H'

4.22 HO'

O' + HO'^ OH- 13.0 (1.0 ± 0.4) x 10

9 k/k oxy = 0.28 ± p.r. opt. c.k.; k is a com— 67-0132

+ O 2 (rel.) 0.12 posite of O + H02 , O + H2 02 and OH + HO' (69-0002).

alk. 3.9 x 10

8 (rel.) p.r. opt. p.b.k. at 260 nm;

anal, of data is complex.

68-0298

13- 7 x 10

8 (rel.) klk oxy = 0.2 f.phot. opt. c.k. ; obs. 03 at 68-7277

13.7 430 nm.

11- (7.2 ± 0.8) x 10

8 k/k( OH + CO7-

) = p.r. opt. c.k.; /j. = 0.4; 69-0379

13 (rel.) 1.98 cor. for OH and HC03

.

4.23 h 2 o 2 alk. s 5 x 10

7 — p.r. opt. p.b.k. at 260 nm; 68-0298

0" + h 2 o 2 -» h 2 o more than one + o 2 rate constant is involved in calcn.

11 k + 1.4 &(OH + H02~) — p.r. opt. c.k. with CO7

; 69-0379 = (8 ± 0.8) x rel. to &(OH +

10

9 (rel.) CO7 ') = (4 ±

0.2) x 10

8 and

pA'.(OH) = 11.9;

ix = 0.4. 4.24 r

0 + I (-f H z O) 13 (8.6 ± 1) x 10

8 A:/A:(OH + CO7 ') = p.r. opt. c.k. with CO7

; 69-0379

20H~ + I (rel.) 2.3 cor. for 11C0 3 and

OH present.

13 2.8 x 10

9 (rel.) k/

2~PfOH = 1-^2 y-r. chem. c.k.; obs. (7(ace— 68-0602

14 2.6 x 10

9 (rel.) k/k 2-PrOH = l-^O tone); /j. = 0.1;

ratio increases

with /x. 6-7 2.6 x 10

9 (rel.) k/

eioh = 2.35 p.r. opt. c.k. 71-0137

2.5 x 10

9 (rel.) k/kmeOH = 4.35

alk. 2.0 x 10

9 p.r. opt. p.b.k. at 0.58 M

NaOH; l=1.9x

10

9 at 1.1 M

NaOH.

71-0137

70
Table 5. Reactions of O' with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.24 cont. alk. 2.2 x 109 (rel.) k/k eioh = 2.04 p.r. opt. c.k. 71-0137

2.3 x 10

9 (rel.) ^/^MeOH = 3.85 p.r. opt. c.k. 71-0137

4.25 IO'

0 + IO (+ HzO) 13.6 6 x 10

9 (rel.) k/koiy = 1.84 f.phot. opt. c.k.; effect of 70-0018

-» 20H“ + 10 IO' on decay of O3

. 4.26 io0 + I03 (+ H2 0) 12.4 2.9 x 10 8 (rel.) k/k „iy = 0.08 f.phot. opt. c.k.; effect of 70-0018

-h> I03 + 20H' I 03 on decay of 03

. or —» IO 4

' 12.6 (3 ± 0.5) x 10

9 p.r. opt. p.b.k. at 360 nm

(IO 4 ); cor. for

72-0017

OH reaction. 12.05 1.6 x 10

9 p.r. opt. p.b.k. at 360 nm

(IO3

).

73-0027

4.27 no2 0 + N02 (+ H2 0) 13 (2.4 ± 0.3) x 10

8 k/k(OH + CO7

) = p.r. opt. c.k. with CO7

; 69-0379

-* 20H + N02 (rel.) 0.67 cor. for OH and

HCOj.

12 3.6 x 10

8 (rel.) k/k oxy = 101 f.phot. opt. c.k.; obs. O3 at 430 nm; based

on k(OH + NO^)/ koxy = 4.0 ± 0.4.

70-7264

For other ratios see4.32. 4.28 Ni(dimethylgly- >13 (2.5 ± 0.3) x 10

9 p.r. opt. p.b.k. at 440 nm; 72-0584

v 2+ oxime) incl. oxid. of free ligand. 4.29 0 2 (oxy)

0 + 02 > 03 13 2.5 x 109 p.r. opt. p.b.k. at 430 nm. 66-0001

alk. 4 x 10

9 — unpubl. data

cited.

66-0424

~11 3.6 x 10

9 p.r. opt. p.b.k. at 430 nm. 69-0379

For other ratios see: 4.80, 4.89, 4.103.

4.2, 4.5, 4.22, 4.25-7, 4.33, 4.48, 4.65,

4.30 03

0 + 03 —> O4 or 13- (8 ± 2) x 10

8 (rel.) f.phot. opt. d.k. at 430 nm; 68-7277 —

0 2 + 0 2 13.7 complex anal, uses other rate constants. >13 ~ 5 x 10

8 p.r. opt. d.k.; k estd. 69-0002

4.31 HPO^' 12.35 2.7 x 106 (rel.) ^/^MeOH = 0.0046 p.r. — c.k.; /x = 0.75. 73-1049

4.32 RuOj0' + RuO*' >13 k/k nitrile = 7-6 y~T. chem. c.k. 68-0063

(+ H2 0) —» RuO^

20H'

+

4.33 SOl~

0'+ S0j'-» 14 3 x 10

8 (rel.) k/k oxy = 0.083 opt. c.k.; obs. 03 71-0461

SO 3 + 20H' at 430 nm.

4.34 acetate ion 14 5 x 10

7 (rel.) k/k 3\\x — 0.077 p.r. opt. c.k. 75-1003

0 + CH 3COO

OH' + CH 2 COO‘

4.35 acetonitrile 14 2.2 x 10

8 (rel.) k/k 3H\ = 0.34 p.r. opt. c.k. 75-1003

4.36 acetylenedicar- 14 =£ 10

7 (rel.) k/k 3HX = 0.063 p.r. opt. c.k.; cor. for 75-1003

boxylate ion OH reactions; k ob.=4x 10

7

. 4.37 aconitate ion 14 ~ 1.5 x 10" p.r. opt. p.b.k. (allylic radicals from H

abstr.).

75-1003

4.38 acrylamide ~12 (6.4 ± 0.8) x 10

8 k/k(OH + CO7 ') = p.r. opt. c.k. with CO3 '; 70-0052

(rel.) 1.75 fi - 0.4; assume

pAT.(OH) = 11.9.

71
Table 5. Reactions of 0 with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.39 acrylate ion 14 1.5 x 10 8 (rel.) k/k3HX = 0.307 p.r. opt. c.k.;cor. for OH 75-1003

(cor.) + acrylate ion. 4.40 adipate ion 14 4.5 x 10

8 (rel.) ^/^3HX = 0.69 p.r. opt. c.k. 75-1003

4.41 allyl alcohol 14.0 (2.9 ± 0.5) x 10

9 — p.r. opt. p.b.k.; H abstr. 73-1070

14 2.2 x 10

9 (rel.)

5 x 10 8

k/k 3hx = 3.4 p.r. opt. c.k. with ethanol

^3Hx/^EiOH = 0-53.

75-1003

4.42 allylbenzene 14 — p.r. opt. p.b.k. (allylic radicals).75-1003

4.43 allyl cyanide 14 1.05 x 10

9 (rel.) k/k 3nx = 1.61 p.r. opt. c.k. 75-1003

4.44 amylamine — 1.6 x 10

10 (rel.) ktk f.TM = 1.7 p.r. opt. c.k.; calcd. 73-0016

1.42 x 10

10 (rel.) k/k CNS - = 1.3 from obs. val—

9.0 x 10 9 (rel.) k/k nb == 2.8 ues at pH 8—

13.1 assuming

equal OH and O

rates for ferro, CNS'and NB.

4.45 aniline 13.3 (3.1 ± 0.6) x 10

9 — p.r. opt. p.b.k. at 300 and 72-0289

O' + C 6 H 5 NH 2 400 nm.

-> OH' + 14 1.6 x 10 9 — p.r. opt. p.b.k.; cor. for 75-1002

C 6 H 5 NH OH; kob = 1.7 x

10

9

. 4.46 9— anthroate ion 14 4.8 x 10

8 — p.r. opt. p.b.k.; cor. for OH.

73-0110

4.47 benzene 13 7.5 x 10

7 (rel.) ^/^2-PrOH — 0.05 y-r. chem. c.k. 68-0602

4.48 benzoate ion >13 < 8 x 10

6 (rel.) k/k BX1 •C 0.0024 p.r. opt. c.k.; obs 69-0002

O' + C 6 H s COO' -» 03 at 430 nm; ohc 6 hs coq- + p/C.(OH) = 11.8 ± OH' 2; assume fc(OH + C 6 H 5 COO) =

6 x 10

9

. 14 4 x 10

7 p.r. opt. p.b.k.; cor. for OH; k ob.= 8.5 x 10

7

.

72-0047

4.49 benzonitrile 14 / 7 x 10

7 (rel.) klk3nx = 0.154 p.r. opt. c.k.; cor. for 75-1003,

0" + c 6 h 5 cn OH contribution 75-1002

(+ H 2 0)-* oh

C 6 H 5 (OH)CN

' + kob, = 1.0 x 10

8

.

4.50 4-biphenylcar- 14 7.0 x 10 7 — p.r. opt. p.b.k.; cor. for 73-0110

boxylate ion OH.

4.51 2,2'— biphenyl— 14 =£ 2.9 x 10

7 — p.r. opt. p.b.k.; cor. for 73-0110

dicarboxylate

ion (diphenate

OH.

ion) 4.52 4,4' — biphenyldi— 14 ^ 2.8 x 10

7 — p.r. opt. p.b.k.; cor. for 73-0110

carboxylate ion OH.

4.53 2— butene— 1,4— diol 14 2.3 x 10

9 (rel.) k/k 3Hx = 3.54 p.r. opt. c.k. with ethanol, 75-1003

^3Hx/^EtOH = 0-53. 2-butenenitrile See crotononitrile (4.60). 3-butenenitrile See allyl cyanide (4.43). 2-butenoate ion .See crotonate ion (4.59). 4.54 3— butenoate ion 14 7.2 x 10

8 (rel.) k/k 3Hx = 1.1 p.r. opt. c.k. 75-1003

4.55 butylamine — 1.3 x 10

10 (rel.) k/k (e rro = 1.4 p.r. opt. c.k.; k calcd. 73-0016

1.34 x 10

10 (rel.) k/k CNs - = 1.2 frm obs. values

7.7 x 10

9 (rel.) k/k nb == 2.4 at pH = 8-13.1

assuming k Q — =

k oh for ferro, CNS' and NB.

4.56 butyrate ion 14 6.5 x 10® (rel.) k/k 3nx = 1.0 p.r. opt. c.k.; H abstr. 75-1003

4.57 citrate ion 14 4.2 x 10

7 (rel.) k/k 3Hx = 0.0645 p.r. opt. c.k. 75-1003

4.58 o— cresol See o— methylphenoxide ion (4.82a)

72
Table 5. Reactions of O

- with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.59 crotonate ion 14 9.0 x 10 8 p.r. opt. p.b.k. at 250 nm

(allylic radical); also c.k. with ethanol and 3HX.

75-1003

4.60 crotononitrile 14 9.9 x 10

8 (rel.) ^/^3HX = 1-53 p.r. opt. c.k. 75-1003

4.61 cyanoacetate ion 14 4.1 x 10 8 (rel.) k/k 3HX = 0.63 p.r. opt. c.k. 75-1003

4.62 p—cyanophenoxide 14 6.2 x 10 8 — p.r. opt. p.b.k.; cor. for 75-1002

ion OH; k obs = 6.8 x o + cnc6 h4 ct 10

8

. (+ H2 0)-* 20H~ + cnc6h4o

4.63 p—cyanotoluene See p-tolunitrile (4.112). 4.64 diphenylacetate 14 6 x 10

7 — p.r. opt. p.b.k.; cor. for 72-0047

ion OH; k obs = 9 x O' + (C 6H5) 2CHCOCr 10

7

.

* (Ce^s^C-COO

OH-

' +

4.65 ethanol >13 1.2 x 10

9 (rel.) k/k ox1 = 0.35 p.r. opt. c.k. 65-0007

CT+ C 2 H5 OH-^ >13 1.2 x 10 9 (rel.) klk oxy = 0.337 ± p.r. opt. c.k. 69-0002

OH’ + *C 2 H4 OH 0.028 ^ C 2H40 + H + 13 1.1 x 10 9 (rel.) k/k oxy = 0.324 f.phot. opt. c.k.; soln. contains NOj.

69-7218

13.92 (11.3 ± 1.7) x 10

8 — p.r. opt. p.b.k. at 360 nm

(*C 2 H4 0

_

).

70-0080

11 9.5 x 10 8 (rel.) k/k(OU + CO7 ’) = p.r. opt. c.k. 70-0511

2.6 14 4.5 x 10

8 (rel.) k/k(OU + EtOH) = X-r. lum. obs. effect of 73-6068

0.24 quenching

chemiluminescence

from fluorescein

at pH 10.4 and

14. 14 1.22 x 10

9 (rel.) ^/^3HX = 1-89 p.r. opt. c.k.; obs. reduction in allylic radical formn. from 3HX by addn.

of EtOH.

75-1003

For other ratios see: 4.1, 4.7, 4.12, 4.14, 4.18, 4.19, 4.24,

4.95, 4.114. 4.66 ethylamine — 5.8 x 10

9 (rel.) k/k NB = 1 -8 p.r. opt. c.k.; calcd. k 73-0016

8.9 x 10 9 (rel.) k/k cns~ = 8.

1

from obs. values

at pH 8— 13.

1

assuming equal OH

and O rates for NB

and CNS . 4.67 ethyl ether 13 1.2 x 10

9 (rel.) k/k 2~PrOH = 0.79 y-r. chem. c.k. 68-0602

4.68 formate ion — — = 410 y-r. chem. c.k. 66-0621,

66-0151

13 9 x 10

8 (rel.) ^/^2-PrOH = 0.60 y-r. chem. c.k. 68-0602

14 1.0 x 10

9 (rel.) k/k 2-pk)h = 0.68 11- 1.3 x 10

9 (rel.) k/k(OH + CO7 ’) = p.r. opt. c.k. ; p. = 0.4; 69-0379

13 3.5 assume pK,(OH) =

11.9. For other ratios see: 4.19. 4.69 fumarate ion 14 *£ 10 7 (rel.) klk mx = 0- 063 p.r. opt. c.k. ;cor. 75-1003

for OH, k ob.=

4 x 10

7

. 4.70 glutaconate ion 14 3.0 x 10 8 p.r. opt. p.b.k. at 250-270 nm (allylic radical); also c.k. with EtOH.

75-1003

73
Table 5. Reactions of O with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.71 glycine, negative 14

ion

5.6 x 10 8 (rel.) k/k 3hx = 0.865 p.r. opt. c.k. 75-1003

4.72 2,4-hexadien-l —ol 14.0 (4.3 ± 0.8) x 10

9 — p.r. opt. p.b.k.; H abstr. 73-1070

4.72a hexamethylbenzene —13

O” + C 6(CH 3) 6 —

OH’ + C 6(CH 3) 5(CH2 )

- 2.5 x 10

9 p.r. opt. p.b.k. 75-1009

4.73 hexanoate ion 14 1.44 x 109 (rel.) ^/^3HX = 2-2 p.r. opt. c.k. 75-1003

4.74 2— hexene— 1,6— 14 dioate ion6.9 x 10

8 p.r. opt. p.b.k. at 250—270 nm (allylic radical); also c.k. with EtOH.

75-1003

4.75 3— hexene— 1,6— 14 (6.5 ± 0.3) x 10

8

dioate ion (3HX)

O" + o 2cch 2 ch=chch 2 co2

- —> OH" + o 2 cch2 chchchco2

- For other ratios see: 4.34, 4.35, 4.36, 4.39,

4.54, 4.56, 4.57, 4.60, 4.61, 4.65, 4.69, 4.71

4.83, 4.84, 4.94, 4.95, 4.96, 4.97, 4.102. o-hydroxybenzaldehyde See salicylaldehyde (4.100). o—hydroxybenzoate ion See salicylate ion (4.101).

p.r. opt. p.b.k. at 266 nm (allylic radicals); cor.

for background

reactions; k obt =

6.3 x 10

8

. 4.40, 4.41, 4.43, 4.49, 4.53,

, 4.73, 4.76, 4.77, 4.78, 4.79,

75-1003

4.76 maleate ion 14 — 3 x 10 (rel.) ^3HX = 0.123 p.r. opt. c.k.; cor. for OH, * ob. 8 x 10

7

.

75-1003

4.77 malonate ion 14 2.1 x 10

7 (rel.) k/k 3HX = 0.0323 p.r. opt. c.k. 75-1003

4.78 methacrylonitrile 14 1.76 x 10

9 (rel.) 3HX = 2-7 p.r. opt. c.k. 75-1003

4.79 methacrylate ion 14 4.8 x 10 8 (rel.) ^/^ 3HX = 0.74 p.r. opt. c.k. 75-1003

4.80 methanol >13

(I) O

- + CH3 OH -*

7 x 10

8 (rel.) klk oxy = 0.209 ±

0.014

p.r. opt. c.k. 69-0002

OH"+-CH 2 OH 13.92 ^ • ch2 o- + h +

(5.8 ± 0.8) x 10

8 — p.r. opt. p.b.k. at 360 nm

(•CH 2 CT).

70-0080

(II) O' + CH 3 OH -> >13

OH - + CH 3 0*

For other ratios see:

k a /ki = 0.075 p.r. opt.

4.1, 4.7, 4.12, 4.18, 4.24, 4.31, 4.95.

detd. % of a—

alcohol and al- koxy radicals by reactions with TNM and I , resp.

73-0126

4.81 0 — methoxyphenoxide 13

ion

7 x 10

8 (rel.) ^/^2-PiOH — 0.46 ± 0.09 y-r- chem. c.k. 72-0837

4.82 methylamine 13.1 7.5 x 10

9 (rel.) ^/^cns — = 0.71 p.r. opt. c.k. assuming

* CNS - = 1.1 x 10

10

.

71-0595

4.82a o-methylphenoxide 13

ion

5 x 10

8 (rel.) k/k 2 _prOH = 0.33 ± 0.03

y-r. chem. c.k. 72-0837

4.82b p-methylphenoxide 14

ion

(i) o

- + ch3 c 6 h 4 o- OH"+ CH 2 C 6 H4 0'

(ii) o- + ch 3 c 6 h 4 ct

(+ H 2 0) —> 20H + ch 3 c 6 h 5 0

1.6 x 10

9

(I + ID

1.0 x 10

9 (I)

p.r. opt. p.b.k.; cor. for OH; * obi = 1.65

x 10

9

.

75-1002

4.83 2-methyl-2- 14 propanol (tert- butanol)

3.3 x 10

8 (rel.) k/k 3HX = 0.51 p.r. opt. c.k. 75-1003

4.84 muconate ion 14 - 2 x 10

9 (rel.) k/k 3HX = 3.1 p.r. opt. c.k. 75-1003

4.85 1-naphthoate ion 14 1.2 x 10

8 — p.r. opt. p.b.k.; cor. for OH.

73-0110

4.86 2— naphthoate ion 14 1.3 x 10

8 — p.r. opt. p.b.k.; cor. for OH.

73-0110

74
Table 5. Reactions of O' with water, transients from water, inorganic solutes, and organic solutes - Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.87 nitrobenzene 14 o"+ c 6 h 5 no2 (+ h2 0) - C 6 H5(OH)N0 2 + OH'

< 7 x 10 7 p.r. opt. p.b.k.; cor. for OH; k ob, ^ 1 x 10

8

.

75-1002

4.88

f.<

p— nitrotoluene 14 O' + ch3c 6 h4 no 2 -> OH + ch 2 c 6 h4 no 27.6 x 10 8 p.r. opt. p.b.k.; cor. for OH; k obs = 8 x

1

0

8

; k for abstr. from methyl

group = 7 x 10

8

.

75-1002

4.89 oxalate ion 13 O 4- C 2 O4

(4- H 2 0) —

C0 2 4- 20H

4- C02

.

2.6 x 10

7 (rel.)

For other ratios see:

k/k oxy = 7.2 x 10'3

4.68.

y-r. chem. c.k. ; ratio in D2 0 = 9.4 x 10'3

.

66-0068,

66-0621

68-0015

4.89a 1, 4— pentadien-3-ol 14.0 (2.4 ± 05) X 10” — p.r. opt. p.b.k. 4.89b pentamethylbenzene —13

0 + C 6 H(CH 3 ) s —

OH' + C 6 H(CH 3 ) 4(CH 2 )

2.6 x 10

9 p.r. opt. p.b.k. 75-1009

4.90 phenoxide ion 13 1.

1

x 10

9 (rel.) */* 2 prOH = 0-^5 y-r. chem. c.k. 68-0602

0'+C6 H5 0 14

(+ H 2 0) -» 20H"

+ c 6 h 5 o

6.5 x 10

8 p.r. opt. p.b.k. at 402 nm

(phenoxyl

radical); cor.

for OH addn.; kob.= 7.1 x 10

8

.

75-1001,

75-1002

4.91 phenoxybenzoate 14

ion

1.6 x 10

8 p.r. opt. p.b.k. at 337 nm

(hydroxycyclo—

hexadienyl radical); cor. for OH;

*,*.= 2.1 x 10

8

.

75-1001,

75-1002

4.92 phenylacetate 14

ion O' + C 6 H 5 CH2 COO'

(+ H 2 0)-» OH'

+ HOC 6 H 5CH 2 COO'

(2 ± 0 . 6) x 10

8 p.r. opt. p.b.k. at 290 nm;

k ob, = 2.2 x 10

8

; assume OH contri- bution is 6.2 x 10

7

.

72-0047

4.93 phthalate ion, 14 dianion

=s 1.8 x 10

7 — p.r. opt. p.b.k.; cor. for OH.

73-0110

4.94 1-propanol 14 1.51 x 10

9 (rel.) */* 3Hx = 2.32 p.r. opt. c.k. 75-1003

4.95 2-propanol 13 1.7 x 10

9 (rel.) */* e,oh =1-56 y-r. chem. c.k. 68-0602

(I)0‘+ 13 1.5 x 10

9 (rel.) k/k MeOH ~ 2.56 y-r. chem. c.k. 68-0602

(CH 3 ) 2 CHOH-+ 14 1.6 x 10

9 (rel.) k/k e,oh = 1-43 y-r. chem. c.k. 68-0602

OH" + (CH 3 ) 2 COH14 1.2 x 10

9 (rel.) k/k MeOH =2.13 y-r. chem. c.k. 68-0602

(II)0"+ 13.5 (CH 3 ) 2 CHOH -* OH'

+ CH 2 (CH 3 )CHOH

kjk u = 5.6 ±

0.3

y-r. chem. c.k.; k H/k D( I) =

1.35 ± 0.10 and

*h/*d(H) = 3.26 ±

0.23.

72-0167

14 1.22 x 10

9 (rel.) For other ratios see:

k/k 3Hx = 1 -88

4.7, 4.23, 4.34, 4.40-2,

p.r. 4.48.opt. c.k. 75-1003

4.96 propionate ion 14 3.3 x 10

8 (rel.) k/k 3 nx = 0-51 p.r. opt. c.k. 75-1003

4.97 propionitrile 14 1.0 x 10

9 (rel.) k/k 3 Hx = 1 .54 p.r. opt. c.k. 75-1003

4.98 propylamine 1.02 x 10

10 (rel.) 6.4 x 10

9 (rel.)

k/kcn<=- = 0.93

klk NB = 2.0

p.r. opt. c.k., calcd. from obs. values

at pH 8—13.

1

assuming equal O

and OH rates for CNS ' and NB.

73-0016

4.99 pyridine 14 O' + C 5 H 5 N (+ H 2 0) — OH" + C 5 H 5 N(OH)

< 7 x 10

7 p.r. opt. p.b.k.; cor. for OH; k obt « 1 x 10

8

.

75-1002

4.99a pyrrolidine 13.2 2.1 x 10

10 (rel.) k/kcns~ = p.r. opt. c.k. assuming

kCNS - = 1.1 x 10 “. 75-1016
Table 5. Reactions of O with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.100 salicylaldehyde, 13 anion

4.0 x 10 8 (rel.) ^/^2-PrOH = 0.27 ± 0.06

•y-r. chem. c.k. 72-0837

4.101 salicylate ion 13 O + 02 CC6 H 4 0 (+4.8 x 10

8 (rel.) k/k 2-PiOH = 0-32 ± 0.05.

y-r. chem. c.k. 72-0837

H 2 0) —» 20H' + 14 -o 2 cc6 h 4o4.5 x 10

8 p.r. opt. p.b.k.; cor. for OH; *ob. = 5.1 x 10

8

.

75-1002

4.102 succinate ion 14 1.35 x 10

8 (rel.) k/k 3m = 0.207 p.r. opt. c.k. 75-1003

4.103 1,2, 3, 4—tetra— ~13

methylbenzene

(prehnitine)

O' + C 6 H 2(CH 3 ) 4 — OH + C 6 H2(CH3) 3 CH 2

2.4 x 10

9 p.r. opt. p.b.k. 75-1009

4.104 1,2, 3, 5—tetra- -—13 methylbenzene

(isodurene)

2.6 x 10

9 p.r. opt. p.b.k. 75-1009

4.105 1,2,4, 5— tetra— —13

methylbenzene

(durene)

2.3 x 10

9 p.r. opt. p.b.k. 75-1009

4.106 2,2,6,6-tetra- 13 methyl-4-piperidone

N—oxyl (TAN)

1.6 x 10

9 (rel.) k/koxy = 0.46 p.r. opt. c.k. 71-0618

4.107 thymine >13 4 x 10

8 — p.r. opt. p.b.k. 72-0047

4.108 o-toluate ion 14 0" + ch 3 c 6 h4 co 2 OH' + ch 2 c 6 h 4co 2

3.4 x 10® p.r. opt. p.b.k.; cor. for OH; k abm = 3.8

X 10 ®; /c .b..r =

3 X 10 8.

75-1002

4.109 m-toluate ion 14 7.5 x 10

8 p.r. ' opt. p.b.k.; cor. for OH; 7.9 x 10

8

; k mb.u = 7 x 10

8

.

75-1002

4.110 p—toluate ion 14 5 x 10

8 p.r. opt. p.b.k. at 280 nm;

contribution of OH reaction < 10%.

72-0047

14 8.2 x 10 8 p.r. opt. p.b.k.; cor. for OH ;*ob. = 8 6 x 108 ;/c.b.„= 8

x 10

8

.

75-1002

4.111 toluene —13

O' + C 6 H 5CH3 -^ C 6 H s CH 2 + OH'

(2.1 ± 0.3) x 109 p.r. opt. p.b.k. 73-0089,

75-1009

4.112 p-tolunitrile 14 O' + CH 3 C 6 H4 CN

-> OH' 4- ch 2 c 6 h4 cn

8.8 x 10

8 p.r. opt. p.b.k.; cor. for OH; * ob.= 9.2 x 10

8

; k,b.u = 8

x 10®.

75-1002

4.113 p-toluidine 14

(I) O' + CH 3 C 6 H 4 NH 2 -> OH' + CH 2 C 6 H 4 NH 2 (II) O' + CH 3C 6 H 4 NH 2 -»• OH' + ch 3 c 6 h4 nh

3.0 x 10

9

(I + II) 1.5 x 10

9

(I)

p.r. opt. p.b.k.; cor. for OH; * obi = 3.1 x 10

9

.

75-1002

4.114 triethylamine 12 2.4 x 10

9 (rel.) ElOH = ^ y-r. chem. c.k. ; may be OH

reaction.

71-0590

4.115 1,2,3-trimethyl- —13

benzene

O + C 6 H 3 (CH 3) 3 —» OH' + C 6 H 3(CH3 ) 2 (CH 2 )

2.1 x 10

9 p.r. opt. p.b.k. 75-1009

76
Table 5. Reactions of 0 with water, transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

4.116 1,2,4-trimethyl

benzene — 13 2.1 x 109 — p.r. opt. p.b.k. 75-1009

4.117 1,3,5— trimethyl—

benzene

~13 2.4 x 10

9 — p.r. opt. p.b.k. 75-1009

4.118 uracil 13.5 4.1 x 10 9 (rel.) */*(OH + CNS") p.r. opt. c.k.; authors 68-0316, = 0.374 doubtful about

value.

69-0571

12 1.8 x 10

9 p.r. opt. d.k.; double

bond bleaching; value from graph.

69-0571

4.119 o—xylene

0 + C6H4(CH3) 2 * — 13 1.8 x 109 — p.r. opt. p.b.k. 75-1009

OH" + C 6 H4(CH3)(CH 2) 4.120 m—xylene — 13 2.2 x 10

9 — p.r. opt. p.b.k. 75-1009

4.121 p—xylene -13 1.8 x 10

9 — p.r. opt. p.b.k. 75-1009

77
Table 6. Reactions of H02 (H 2 02 and O^) with transients from water, inorganic solutes, and organic solutes

No. Solute and reaction pH k Ratio Source Method Comment Ref. h2 o

5.1

2 Reactions

OH

h2 o;+oh-^ — See 3.6, Table 2. ho2 5.2

H 3 0

+ + 02 Reactions

H

ho2 +h-+h2 o2 See 2.4, 75-0001

5.3 OH

ho 2 +oh->h2 o —

NSRDS-NBS 51.

See 3.5, Table 2. •

5.4 + 0 2 or —> H 2 03 ho 2 H0 2 + HO2 —* nat. (3.4 ± 2.5) x 10

6 phot. chem. k at 25°C. 53-0014

H 2 02 + 02 nat. 3.1 x 10 6 — y-r. chem. k at 0°C; no pH 53-0014

2.7 2.5 x 10 6 f.phot. opt.

effects discussed;

rates are probably for 02 + 02

. d.k.; e(254 nm) = 62-0050

0.5- (2.4 ± 0.4) x 10

6 therm. esr

350 mol

_1 cm2

. d.k.; flow syst— 62-0054

1.55

2 2.3 x 10

6

, e—T. chem.

em; Ce4* + H2 02 soln. ; = 5.9 ±

0.4 kcal/mol(25kJ/

mol),

c.k.; obs. 63-0075

1.7-

2.2 x 10

6 (rel.)

2.7 x 10

6 p.r. opt.

reaction of H02 with tetranitro— methane,

d.k.; e(253.7 nm) 64-0064

3.0

1 ~ 2 x 10

6 y-r. chem.

= 830 ± 125 dm3 mol"1 cm

_1

. c.k.; rotating 65-0046

2 (2.5 ± 0.5) x 10

6 p.r. opt.

sector method;

H2 02 soln. d.k. 66-0001

2.8- 2.5 x 10

6 — e—r. chem. c.k.; also from 66-0614

2.9

2.65 x 10

6 therm. esr

Ce(IV) + H2 02 ; k decreases

below pH 2 and

increases above

pH 3. d.k.; from Ce(IV) 68-9083

0.3-2 0.7 x 10

6 p.r. opt.

+H2 0 2 ; E.= 4.7 kcal/mol (19.6 kj

/

mol).

d.k.; e(254 nm) = 68-0382

2-5 6.7 x 10 s p.r. opt.

540 dm 3 mol 'em '; more than one rate constant is involved in calcn.; k =

2.8 x 10

9 exp

(-4900/RT).

d.k.; €(240 nm) = 69-0418

0-7.7 7.6 x 10

s p.r. opt.

1150 dm3 mor'cm -1 pAT.(H0 2) = 4.8. d.k.; pE,(H02 ) = 70-0304

0 k H

/k D =7

4.88. Et in D2 0 = 7.1 70-0642

5.5 knlkD = 3 ± 0.4 kcal/mol

(29.7 kj/mol);

unpubl. data. 78
Table 6. Reactions of H02 (H 2 0+ and 0“) with transients from water, inorgamc solutes, and organic solutes —Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

0

1.1

(9 ± 1) x 10 s

2.8 x 10

6 — Ce(IV) + h2 o2

opt. e(230 nm) = 1100 dm3 mol 'em

70-0920,

69-9139

0-2 (1.35 ± 0.3) x 106 — f.phot. opt. d.k.; c(240 nm) =

10

3 dm 3 mol 'em '. 70-0920

5.5

2.6-7

o 2

106 - 10 7 e—r. chem. obs. H02 reaction with tetra— nitromethane in formate soln.

72-0308

H0 2 + 02 -^H02 7 ~ 2 x 10 8 — f.phot. opt. c.k. 62-0050 + 02 7 1 x 10 7 — f.phot. opt. d.k.; data of 53-0014.

62-0050 — < 7 x 10

7 — e—r. chem. flow technique;

pH effects, c.k.

63-0075

7 5.3 x 10

7 — p.r. opt. d.k. 66-0001

0-5 3 x 10 7 p.r. opt. d.k.; more than one rate constant

is involved in calcn.

68-0382

2-9.7 7.9 x 10

7 — p.r. opt. d.k.; pA\(H0 2 ) =

4.8.

69-0418

5.6

0-7.7

Br 2

8.5 x 10

7 p.r. opt. d.k.; p^,(H02 ) = 4.88.

70-0304

H02 + Br 2 —* H

+ ~1

+ Br + Br + 0 2

(1-5- o s) x 10

8

(rel.)

p.r. opt. c.k.; indirect estimation; more

than one rate constant is involved.

65-0382

2 < 4 x 10

6 p.r. opt. p.b.k. and d.k.

;

mechanistic anal, of data.

65-0383

5.7

2-7

Br2 H02 + Br2 —> 2 Br 2 + H02

( 1.1 !S;J)x 10

8

(rel.)

k/k x

- 4 x 10'4

e—r

y-r.

chem.

chem.

c.k. in formate—

Br2 soln. ; rel. to k( 0 2 + C(N0 2 ) 4) = 2 x 10

9

.

c.k.; * x = &(H0 2 + Br2 ) x £(Br 2 + Br 2 —

Brj + Br

_

)

1/2

.

72-0308

65-0055

2 (3.8 ± 0.9) x 10

9

(rel.)

p.r. opt. d.k.; k/e(Br^) =

(4.6 ± 0.4) x 10

s

cm/s; more than one rate constant is involved

in calcn.

65-0382

5.8

2

BrJ

(1.6 ± 0.5) x 10

9

(rel.)

p.r. opt. c.k.; obs. decay

of Br 2 + Br 2 —

Br^ + Br~ at 360 nm; data fitting.

65-0383

H02 + Brj —» H

+ + 2 Br 2 + Br + 02

(1 ± 0.5) x 10

8

(rel.) — p.r. opt. c.k.; mechanistic

anal.

65-0383

2-7 < 10 7 (rel.) e—r. chem. c.k. in formate— Br2 soln. ; rel. to k( 0 2 + C(N02 ) 4) 2 x 109

.

72-0308

79
Table 6. Reactions of H02 (H 2 0^ and 0 2 ) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.9 CNS

H0 2 + CNS -» CNS" 1 1.6 x 10

9 (rel.) p.r. opt. c.k.; pH effect 65-0386 + H

+ + 02 on decay CNS + CNS -* (CNS)2

. 5.10 Ce 3+ H02 + Ce 3+

(4- H

+

) 0.4 (2.1 ± 0.2) x 10 s p.r. opt. p.b.k. at 320 nm. 74-1107

Ce4+ + H 2 0 2 Ce(IV).

5.11 Ce4+ H0 2 + Ce4+ —

0.4 k/kCe3+ = 7.7 therm. chem. 0°C. 57-9009

Ce 3+ + H

+ + 02 0.4 k/kCc3+ = 13 ± 2 therm. chem. d.k.; flow technique;

Ce(IV) + H2 02.

63-9017

5.12 Cu +

(I) H0 2 + Cu + 2.3 6 x 10

8

(I) phot. opt. rotating sector; 69-7082,

(+H 2 0)-* Cu 2+ + kjku = 2.4 /x = 0.1; soln. 69-7083

H 2 02 + OH" contains Cu 2+

(II) H 2 0;+ Cu + —

and 4.5 M H2 02 ; Cu 2+ + H2 02 see also 73—7514.

(III) H 202 + Cu + 0.8-2 > 10

9

(I) — p.r. opt. d.k. at 245 nm; 73-0112

Cu 2+ + OH + Cu 2+ soln. OH" 2.3 2.3 x 10

9

(I) kl /k m = 0.015 phot. opt. rotating sector; 73-7514

x fc(H0 2 + Cu2+

) assume - Ms 4.7 x 103

; fc(H0 2 + Cu 2+

) =

3.4 x 10

7

. 5.13

2+ Cu

(I) H0 2 + Cu 2+ —* 1.35- kjk rc 2 + = 3.5 - Fenton chem. c.k.; pH depen- 51-9004

Cu + + H

+ + 02 2.65 103 dent; 0°C.

(II) 0 2 + Cu 2+ —

~2 ki/kfc 2+ 55 y-r. chem. c.k.; 0.01 M H

+ 55-0039

Cu + + 0 2 2.3 1.5 x 10

7 (I) — f.phot. opt. d.k. at 254 nm. 62-0050

0.4 ^,//c Fe 2+ = 0.4 y-r. chem. c.k. 66-0334,

68-0355

2.3 — kjk u = 0.06 phot. opt. rotating sector. 69-7083

0.8-2 ~ 10 8 (I) — p.r. opt. d.k. at 245 nm. 73-0112

>2.5 — kl/k ll = 0.024 phot. opt. rotating sector. 73-7514

5.14 Fe

2+ H0 2 + Fe

2+ —* 1.35- k/k F^+ = 1.0-7 Fenton chem. c.k. ; pH depen- 51-9004

Fe

3+ *H0 2 or 2.65 dent; at 0°C

Fe

2+ + HO'(+ H+

) ratio = 1.1—8. Fe(OH) 2 + 2.7 k/k Ft: 3 + = 3.3 y-r. chem. c.k.; at pH 2.0 57-0010

1I 2 0 2 ratio = 9, at pH ~ 0.5 ratio > 100.

58-0004

~2 k/k Fe 3+ = 160- y—r. chem. c.k.; at pH 0.8 60-0102

190 ratio is 300. 0.3 7.3 x 10

s p.r. opt. p.b.k. at 305 nm;

several reactions

are involved in analysis.

64-0090

0-2.1 (2.1 ± 0.4) x 10

6 — p.r. opt. p.b.k.; obs. (Fe

3+ *HO J);

69-0434

supercedes

value in 64-0090.

0.38-

o

*/*„..!+ = 30[H + ]M y-r. chem. c.k. 69-0642

Z

l (1.2 ± 0.5) x 10

6 — p.r. opt. p.b.k. at 250 nm; 73-0038

(25°C) fjL = 1.0; k = 9.1

x 10

s at 20°C; E. =

10.0 ± 1.0 kcal/mol

For other ratios see5.13, 5.28, 5.44. (42 kj/mol).

80
Table 6. Reactions of H02 (H 2 O.J and 02 ) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.15 Fe(CN)4 ~ H02 + Fe(CN) 4 “-^ ~2 1.64 x 10

s p.r. opt. p.b.k. at 420 nm 65-0007

HO 2 + Fe(CN)

3- 0.46- (3.0 ± 1.5) x 10

4 p.r. opt.

(ferricyanide).

p.b.k. at 420—460 72-0431

4.37 nm; pH effects obs. H0 2 + HFe(CN)3

" (1.4 ± 0.1) x 10 s H0 2 + H2 Fe(CN)j~ (1.0 ± 0.3) x 10

4 H0 2 + KFe(CN) 3-

(3.0 ± 1.5) x 10

4

5.16 Fe 3+ H02 + Fe 3+ —

1 k/k H + = 1.20 y-T. chem. c.k. 69-0642

Fe 2+ + H

+ + 02 For other ratios see: 5.14, 5.43. 5.17 H

+ ho2 + h

+ — h2 o 2 + For ratio see : 5.16. 5.18 h 2 o 2 H0 2 + H2 02 —

530 y-r. chem. no pH effects 52-0018

h 2 o + o2 + oh considered; ter- mination rate k(2HO z + H2 02) =

2.7 x 10

10dm6 mol 2 s

*. nat. 3.7 ± 1.6 phot. chem. propagation step

in chain reaction; k at 25°C; no pH

effects considered;

see 5.46.

53-0014

nat. 1.1 y-r. chem. k at 0°C. no pH

effects considered;

probably for 02 + H2 02

.

53-0014

1 1 x 10~2 y-r. chem. mechanistic fit; k at 10°C; concn. H2 02 ~ 1-35 M.

65-0046

0.8- 0.20 ± 0.01 (rel.) k/k( H02 + H02 ) = y-r. chem. c.k.; obs. 69-0643

1.5 1.8 x 10~7 G(-H 2 02 ); includes &(H 2 0 2 + H2 02 —

Ha O

+ + 02 + OH);

A:(HO z + H02 ) =

1.1 x 10

6

. 5.19 MnO;

H0 2 + Mn04 —2 8 x 10

6 p.r. opt. d.k. 65-0385

H

+ + 0 2 + MnO 2-

5.20 Os04 H0 2 + 0s0 4 —

<1 5.7 x 10

s (rel.) k/k( H02 + HOz ) = y-r. chem. c.k.; obs. 64-0050

0s04 + H + O 2 0.24 G(H 2 02); k (H0 2 + H02 ) =

2.35 x 10

6

; dose

rate 9.7 x 10

18 eVcm 3 h V

5.21 Te(IV)

H0 2 + Te(IV) ->• 0.4 - 7.5 x 10

3 (rel.) k/k( H02 + H02 ) = y-r. chem. c.k.; preliminary 67-0553

Te(VI) + OH 3 x 10'3 value; assume k (H0 2 + H02 ) =

2.5 x 106. 0.4 > 50 (rel.) k/k( H02 + H0 2 ) 5= y-r. chem. c.k.; more than 68-0356

2 x 10's one rate involved

in calcn.; ^(H02 + H0 2 ) = 2.5 x

10

6

.

81
Table 6. Reactions of HO? (H 2 02+ and 02_

) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.22 Th(IV)

(I) H0 2 + Th(IV) -1 =? 5 x 10

6

(I) therm. esr /C,= (1.7 ± 0.4) 73-9071 ^ Th(IV)-H0 2 (8.0 ± 2.0) x 10 s (II) x 10 s A/~*; d.k. as

(II) H02 + Th(IV)- (5 ± 2) x 10

2 (III) well as p.b.k.;

H0 2 -* Th(IV) + Ce4+ + H 2 02 soln. h 2 o2 + 02 (1.8 ± 0.2) x 10

6 (I) — p.r. opt. p.b.k.; Kt = 74-1107

(III) 2Th(IV)-H0 2 (4 ± 1) x 10

4 A/~l

. -» 2Th(IV) + H 2 0 2 + 0 2 5.23 Tl

2+ ho 2 + ti 2+ ^ 1 (2.5 ± 1) x 10

9 p.r. opt. d.k. (Tl2+

); rel. 66-0097

Tl

+ + H+ + 0 2 (rel.) to k(Tl2+ + Tl

2+

) = 2.3 x 10

9

. 5.24 uo 2+

(I) HO2 + U0.2 + ^ -1 2= 1 x 10

5

(I) therm. esr d.k. as well as 73-9071

U(VI)-H0 2 (9.0 ± 1.5) x 10

5 p.b.k.; Ce4+ +

(II) U(VI)-H0 2 + (II) - H2 02 ; Kx = (2.7 H0 2 ^ U(VI) + H 2 0 2 + 0 2

± 0.4) 10

3 M

_1

.

(III) 2U(VI)-H0 2 —

1 (1.5 ± 0.1) x 10

s

(I) p.r. opt. p.b.k. and d.k.; 74-1107

2U(VI) + H 2 02 + O2 (5 ± 1) x 10 s (II) Kl = (1.7 ± 0.3)

(8 ± 2) x 10

4 (III) X io3 at\

5.25 V0(0 2) + H0 2 + V0(0 2 ) + ^ _ (9.4 ± 1) x 10

4 k/k(H02 + H0 2 ) = therm. esr flow technique; 70-9058

complex (rel.) 0.1 Ce4* + H2 02 ; as- sume /:(H0 2 + H02) = 9 x 10

s

. 5.26 cyclohexaneper— — 2.26 x 10

6 — -y-r. chem. detd. H 2 02 and 67-0737

oxy radical (R0 2 ) R02 H yields; as— H0 2 + RO 2 —> 0 2 + sume k( R02 + R02) ro 2 h = 2.7 x 10

6

; see

also 5.49. 5.26a cytochrome C 5.3 5 x 10

s - 5 x 10

6 — p.r. opt. d.k. at 550 nm. 75-3093

(ferro) 5.27 cytochrome C 1.84 — — p.r. opt. no reaction obs. 71-0327

H0 2 +Fe3+ —cyt 1.2—6.2 — — p.r. opt. no reaction. 75-3093 —* no reaction 5.28 ethylene

ho 2 + c 2 h 4 — klk Fe 2+ = 0.167 y-r. chem. c.k. 67-0037

c 2 h 4 ooh

5.28a horseradish — 2.2 x 10

8 — p.r. opt. d.k.; detd. k at 74-1148

peroxidase

Compound I pH 3.8 to 8.8.

5.29 indigodisulfonate 0.4 8.5 x 10

3 (rel.) k/k( HOs + H02 ) = y-r. opt. c.k.; assume 68-0059

H0 2 + dye —> 3.9 x 10'3 k( ho 2 + HOj) =

decoloration 2.2 x 10

6

; G(H0 2 ) = 3.6. 5.30 indigotrisulfonate 0.4 4.5 x 10

3 (rel.) k/k( H02 + H0 2 ) = y-r. opt. c.k.; assume 68-0059

H0 2 + dye —2 x 10'4 k( H0 2 + H02 ) =

decoloration 2.2 x 10

6

; G(H0 2 ) = 3.6. 5.31 indigotetrasulfo— 0.4 7.7 x 10

2 (rel.) k/k( H02 + H02 ) = y-r. opt. c.k.; assume 68-0059

nate 3.5 x 10“4 k( H0 2 + H02 ) = HO s + dye —

2.2 x 10

6

; decoloration G(H0 2 ) = 3.6. 5.31a N ADH-lactate — — 1.2 x 10

6 — p.r. opt. d.k.; detd. from 74-1159

dehydrogenase k obt at pH 4.4 to

9; see also 5.61a.

82
Table 6. Reactions of H02 (H 2Ol; and 0 2 ) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.32 tetranitromethane

H02 + C(N02 ) 4 ^

0-6 < 10

s — p.r. opt. p.b.k. 65-0183

C(N02)j + no2 H

+ + 02 Reactions

5.33 e mq o2-+ or — 1.3 x 10 10 — — — See 1.10, NSRDS-NBS 43.

73-0030

5.34 OH

02 + OH —> 1 x 10

10 See 3.7, Table 2. OH“+ 02 5.35 02 02 + 02 (+ H2 0) 5.5 1.45 x 10

7 p.r. condy. d.k. 60-0101 —* H02 + o2 60-0121 + OH“

11 2.7 x 10 5 f.phot. opt. d.k.

62-0050

62-0050 — 1.5 x 10

7 — e—r. chem. c.k. ; pH effects, flow techniques.

63-0075

5-7 1.7 x 10 7 p.r. opt. d.k.; 6(253.7 nm) = 980 ± 140 dm3 mol 'em '.

64-0064

7 5 x 10

7 — y-r. chem. rotating sector method; H2 02 soln.

65-0046

5.5 1.45 x 10

7 — p.r. condy. d.k. 67-0213

5.5 2.2 x 10

7 — f.phot. opt. d.k.; e(260 nm) =

"HX) dm3 mol 'em '. 67-7012

5.7 5.8 x 10

7 — f.phot. opt. d.k.; 6(250 nm) =

1030 dm3 mol 'cm '. 67-7012

12.8 1.4 x 10

8 — f.phot. opt. d.k.; e(260 nm) =

900 dm3 mol ’cm ’. 67-7012

10.5 5.8 x 10 7 — f.phot. opt. d.k.; e(260 nm) =

900 dm'mol 'em

67-7012

5 1.2 x 10

7 — p.r. opt. d.k.; 6(241 nm) =

890 dm'mol 'cm '. 68-0382

k = 4 x 10

8 exp(-2100/RT); more than one rate constant is involved

in calcn. ~5- < 10

s — p.r. opt. d.k.; e(240 nm) = 69-0418

9.7 1970 dm 3 mol 'em '; k probably < 10

3

. 13 < 10 2 — p.r. opt. d.k. ; pAa (H0 2 ) =

4.88.

70-0304 — < 10 2 — — — reaction with cytochrome C.

71-0327

alk. 1.0 x 10

7 — f.phot. condy. d.k. (20°C); k =

1.63 x 10

7 at

72-0404

50°C; 9 x 10~S M NaOH.

5.36 Br2 02 + Br2 —* 2-7 (5.6 ± 0.7) x 10

9 e-r. chem. c.k. in formate— 72-0308

0 2 + Br2 (rel.) Br2 soln. ; rel. to k( 0 2 + C(N0 2 ) 4 ) = 2 x 10

9

. 5.37 Brj

02 + Brs —> 2-7 (3.8 ± 0.7) x 10

9 e—r. chem. c.k. in formate— 72-0308

0 2 + Br~ + Br2 (rel.) Br2 soln. ; rel. to *(

0

2 + C(N0 2 ) 4) = 2 x 10

9

; soln. contains 0.2 M Br . 83
Table 6. Reactions of H02 (H2Oj and O^) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.38 HOBr

0 2 + HOBr 2-7 (9.5 ± 0.8) x 10

8 e—r. chem. c.k. in formate— 72-0308

OH + 02 + Br (rel.) Br2 soln.; rel. to k(0 2 + C(N02 ) 4) = 2 x 10

9

. 5.39 co'

0 2 + C03 —

~13 1.5 x 10 9 p.r. opt. d.k. at 600 as 66-0001

CO 2- or —* well as 260 nm; O a + CO 3 e(600 nm) for CO3 =

1.8 x 10\ e(260

nm) for 02 = 1.22 x 103dm 3 mol"1 cm~

1

. 12.8 1.3 x 10

8 — f.phot. opt. d.k. 67-7012 — (4 ± 1) x 10 8 — f.phot. opt. d.k. at 260 nm 70-0247

and 60Q_nm;

at 260 nm e(C0 2

)

- 410 and e(O^) =

1850 dm3 mol" l cm"1. 5.40 HCO3 0 2 + HCO3 —

5.5 1-2 x 10 6 p.r. condy. d.k. 72-0404-

CO 3 + H02 (rotating sector); C02 soln. 5.41 C10 2 0 2 + CIO 2 —

5-7 k/k(0 2 + CQ°' 5 -y-r. chem. c.k. 67-0028

0 2 + cio 2 = 1.7 ± 0.6

a^-0.5 -0.5 M s 5.42 Cu + 0 2 + Cu + + -3-6.5 10 10 p.r. opt. d.k. at 245 nm in 73-0112

(2H 2 0) —» Cu 2+ + H2 0 2 + 20H

Cu 2+ soln.

5.43

2+ Cu

0~+ Cu 2+ —

1.35- k/k Ft 3 + = 25 Fenton chem. c.k. 51-9002

Cu + + 02 2.65 51-9005

-3-6.5 8 x 10

9 — p.r. opt. d.k. at 245 nm. 73-0112

For values of 1(H0 2 + Cu 2+ )/*(0"+ Cu 2+

) See 5.13. 5.44 Fe 3+ 02 + Fe 3+ —

<3 k K(U02)lk(H0 2 y-r. chem. c.k. 63-0004

Fe 2+ + 0 2 + Fe 2+

) = 3.6

x 10"3 — k K(U02)/k(H0 2 Fenton chem. c.k. 51-9004 + Fe 2+

) = 7 x 10'3

5.45 Fe(CN)3 - 0 2 + Fe(CN);* —

9.5- (2.7 ± 0.9) x 10

2 p.r. opt. p.b.k. at 420-440 72-0431

0 2 + Fe(CN)*'

0 2 + KFe(CN)j" —

9.7

(6.2 ± 0 . 6) x 10

3 nm; /x = 0.

0 2 + KFe(CN) 3 "

5.46 H 2 0 2 ~7 16.0 ± 3.3 (rel.) k/k(02 + 0^) phot. chem. obs. rate of H 2 02 74-7351

0 2 + H 2 0 2 —> = 9.5 x 10

" 7 decompn.; assumed

OH + OH" + 0 2 k(02 + OJ = 1.7 x 10

7

; recalcd. from

53-0014 k = 9.0, and

from 62-0163 k = 12.0. 5.47 benzoquinone ~7 9.6 x 10

8 — p.r. opt. p.b.k. at 430 nm. 71-0619

0" + 0=C6 H 4 =0 6.9 (9.0 ±0.9) x 10 8 — p.r. opt. p.b.k. at 430 nm. 73-0049

0=C 6 H 4 0 + 0 2 7.0 9.8 x 10

s — p.r. opt. p.b.k. at 430 nm. 73-0068

5.48 cyanocobalamin — — — p.r. — no reaction 73-0116

(Vitamin B l2 )

84
Table 6. Reactions of H02 (H2Oj and 0;r) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.49 cyclohexaneperoxy radical (R0 2 ) 0 2 + R02 (+H +

) —

R0 2 H + o2

2.54 x 10

8 y-r. chem. pH dependence

of H2 02 and R02 H

yields; assume *(R0 2 + ROz ) =

2.7 x 10

6

; see 5.26.

67-0737

5.50 cysteine 7 0 2 + RSH(+H +

) —

> 5 x 10 4 — y-r. chem. obs. G(H 2 02 ) as function of dose.

70-0882

RS + H2 02 3-5.1 ~ 1.8 x 10

4 — y-r. chem. obs. increase in G(H 2 02 ) with pH.

74-0188

5.50a cytochrome C

(ferro) — — p.r. opt. no reaction. 75-3093

5.51 cytochrome C 8.4 0 2 + Fe

3+ —cyt C

Fe 2+ —cyt C

1.6 x 10 s therm. esr d.k.; 02 from

tetraacetylribo—

flavin + 02.

69-9128

8.5 1.1 x 10

s — p.r. opt. p.b.k. at 550 nm. 71-0327

10.4 8 x 10 3 — p.r. opt. p.b.k. at 550 nm. 71-0327

7 2.4 x 106 — p.r. opt. p.b.k. 75-1012

9.3 1.5 x 10 s — p.r. opt. p.b.k. 75-1012

4.7—6.7 (1.4 ± 0.15) x 106 — p.r. opt. p.b.k. at 550 nm; 75-3093

from pH effect pATa (cyt C) = 7.45,

9.2; *=(3.0 ± 0.4) x 10

s for the form

present above pH

7.45; the form

present above pH

9.2 does not react; £.= 21.2 at pH

6.75 and 19.9 kj/mol at pH 8.6. 5.52 2,5-dichloro-p- 7.0 benzoquinone

l,2-dihydroxybenzene-3,5-

1.1 xlO9

-disulfonate ion See tiron (5.64).

p.r. opt. p.b.k. at 430 nm. 73-0068

5.52a 2,3—dimethylbenzoquinone

- 7 (4.5 ± 1) x 10

8 — p.r. opt. p.b.k. 73-0125

5.53 2,5-dimethyl-/?- 7.0 7.5 x 10 8

' — p.r. opt. p.b.k. at 430 nm. 73-0068

benzoquinone 7 (3.6 ± 1) x 10

8 — p.r. opt. p.b.k. 73-0125

5.53a 2,6-dimethylbenzoquinone

7

00 00 +1 X O

LO — p.r. opt. p.b.k. 73-0125

5.54 4,4'-dimethyll,l'-bipyridylium

chloride (Paraquat radical)

6.5 x 10 8 p.r. opt. calcd. from d.k.; *(0 2 + PQ+

) =

7.7 x 10

8

.

73-1074

5.54a 2,3—dimethylnaphthoquinone

7 4 x 10

6 p.r. opt. detd. from equil. const, and d.k. of semiquinone.

73-0125

5.55 diphenoquinone 7.0 (1.4 ± 0.14) x 10

9 — p.r. opt. p.b.k. at 400 nm 73-0068

5.55a DNA 6.2, 9.2 < 5 x 10

6 — p.r. — — 75-3051

5.55b duroquinone 7 5 x 10

6 p.r. opt. detd. from equil. const, and d.k.

of semiquinone.

73-0125

5.55c horseradish

peroxidase

Compound I

7-8.8 1.6 x 10 6 p.r. opt. d.k. as well as

p.b.k., detd. k

at pH 3.8 to 8.8.

74-1148,

74-3069

5.56 hydroquinone 7.0 (1.6 ± 0.1) x 10

7 — p.r. opt. p.b.k. at 430 nm. 73-0068

0'+ OHC6 H4OH

HOj-+ 0HC6 H4 0»

-> o=c6 h 4 o + h

+

85
Table 6. Reactions of HO2 (H 2 0 + and 0 2

) with transients from water, inorganic solutes, and organic solutes — Continued

No. Solute and reaction pH k Ratio Source Method Comment Ref.

5.57 2— methyl—

/

7 —benzo— 7.0 8.0 x 10 8 — p.r. opt. p.b.k. at 430 nm. 73-0068

quinone 7 (7.6 ± 1) x 10

8 p.r. opt. p.b.k. (semiqui—

none).

73-0125

5.58 1,2-naphthoquinone 7.0 7.2 x 10

8 — p.r. opt. p.b.k. at 365 nm. 73-0068

5.59 1,2— naphthoquinone 7.0 4—sulfonate ion

8.4 x 10 8 — p.r. opt. p.b.k. at 365 nm. 73-0068

5.60

5.61

1,4— naphthoquinone 7.0 2— sulfonate ion nicotinamide—adenine dinucleotide,

reduced (NADH)

6.6 x 10 8 p.r. opt. p.b.k. at 400 nm. 73-0068

0 2 + NADH (+ H

+

) —*8.6 H 2 02 + NAD-

<<27 X-r. biol. upper limit estd.

for soln. contg.

KBr and Oz.

71-0158

5.61a NADH-lactate 7—9

dehydrogenase

3.6 x 10

4 — p.r. opt. d.k. 74-1159

5.62 superoxide dismu— 5.3—

tase (E) 9.5 Dismutation of 02 (see 5.35)

1.8 x 10

9

is catalyzed by E.

p.r. opt. d.k. at 250 nm

(O^) as well as 650 nm (Cu); enz- yme from bovine

blood.

72-3066

7 (1.4 ± 0.2) x 10

9 p.r. opt. d.k. at 245 nm

(O^); enzyme from

bovine blood.

72-1007,

72-3078

7.5 (1.2 ± 0.2) x 10

9 p.r. opt. d.k. at 650 nm

(E); soln. contains Na formate

and EDTA; enzyme

from bovine blood.

73-0109

5.0-

9.5 ~ 2 x 10

9 (rel.) chem.,

biol.

opt. c.k. (bovine Cu—Zn 73-3052

enzyme); assume

k( 02 + cyt C) =

1.1 x 10

s and

k( 02 + C(N02 ) 4) = 1.9 x 10

9

; rel. rates at pH 6.0—

10.2 also detd. for E.coli Mn and Fe enzymes and chicken

liver mitochondria

Mn enzyme.

5.7-

10.5

1.5 x 10

9 p.r. opt. d.k. at 690 nm; Cu enzyme from

human blood.

73-3132

9.0-

9.9

(2.37 ± 0.18) x 10

9 p.r. opt. d.k. at 250 nm;

bovine Cu-Zn

enzyme; supersedes 72-3066.

74-3017

7.9 (1.3 ± 0.15) x 10

9 — p.r. opt. d.k. at 248 nm;

E.coli Mn enzyme.

74-3059

9-10.2 2.3 x 10

9

Paraquat radical See 4,4-dimethyl-l, l'-bipyridylium chloride (5.54). 2,3,5,6-tetramethylbenzoquinone See duroquinone (5.55a).

elec. pol. obs. increased 02 formn. with enzyme

addn.

74-3132

5.63 tetranitromethane (2.0 ± 0.4) x 10

9 — p.r. opt. p.b.k. 64-0133

0 2 + C(N0 2 ) 4 -+ 0 2 5.6- + C(N0 2 ) 3'+ N02 6.2

(1.9 ± 0.4) x 10

9 — p.r. opt. p.b.k. 65-0183

5.64 tiron 7 5 x 10

8 — p.r. opt. p.b.k. at 400 nm. 75-1087

(1,2-dihydroxy- 7 benzene—3,5—disul—

fonate ion)

1.5 x 10

8 (rel.) k/k benzoquinone 0.17

p.r. opt. c.k.; assume

Ic benxoquinone = 9 x 10

8

.

75-1087

5.65 Vitamin K, 7 < 2 x 10

s p.r. opt. detd. from equil. const, and d.k. of semiquinone.

73-0125

86
Formula index

The following formula list refers to entry numbers, not only in the preceding tables, but also in the

tables of rates of hydrated electron and hydrogen atom reactions published as part I (and Supplemental

data) and part II. The first digit of the entry number identifies the section of the tables where the entry can be found.

1. Part I. Hydrated electron 73—0030 (NSRDS—NBS 43) SI. Hydrated electron. Supplemental data 75—0002 (NSRDS—NBS 43—Supp)

2. Part II. Hydrogen Atom 75-0001 (NSRDS—NBS 51)

3. Part III. Hydroxyl radical (this work, tables 2—4)

4. Part III. Oxide ion (this work, table 5)

5. Part III. Perhydroxyl radical and superoxide ion

(this work, table 6).

Thus, there are entries for Ag+ in the tables of hydrated electron reactions (1.11), hydrogen atom

reactions (2.5) and hydroxyl radical reactions (3.8), while Br04 entries are found in the supplemental

tables for hydrated electrons (SI. 6), hydroxyl radical reactions (3.17), and oxide ion reactions (4.11).

Ag + Silver(I) ion, 1.11, 2.5, 3.8 AgH6 N 2 Diamminesilver(I) ion, 1.12 Al

3+ Aluminum(III) ion, 1.16 A1H 404 Aluminate ion, 1.17 AsF6 Hexafluoroarsenate(V) ion, 1.24, 2.7 AsH04 Arsenate ion, 1.23 AsOj Arsenite ion, 1 . 22 , 2 . 6 , 3.9 AuC14 Tetrachloroaurate(III) ion, 2.8 BF4 Tetrafluoroborate ion, 1.26 BH4 Tetrahydroborate ion, 3.11, 4.6 B 40

2 Tetraborate ion 2.9 Br“ Bromide ion, 2 . 10a, 3.12, 3.13, 4.7 BrCoH 15 N

2 + Bromopentaamminecobalt(III) ion, 1.67 BrHO Hypobromous acid, 5.38 8rH 15 N 5 Ru 2+ Bromopentaammineruthenium(III) ion, SI. 56 BrO Hypobromite ion, 1.28, 3.14, 4.8 Br0 2 Bromite ion, 1.29, 3.15, 4.9 Br03 Bromate ion, 1.30, 2 . 11 , 3.16, 4.10 Br04 Perbromate ion, Si. 6 , 3.17, 4.11 Br 2 Bromine, 2 . 10 , 5.6, 5.36 Br 2 , 1.27, 5.7

BrJ, 5.8, 5.37 CBrF3 Bromotrifluoromethane, 1.347a CCIF, Chlorotrifluoromethane, 1.378, 2.189, 3.261 CC1 2 F 2 Dichlorodifluoromethane, 1.399a, 2.211 CCljF Trichlorofluoromethane, 1.635, 2.377 CC1 4 Carbon tetrachloride, 1 . 355 , 2.177 CD02 d-Formale ion, 2.240 CF3

1 Trifluoroiodomethane, 1.638a CF4 Tetrafluoromethane, 2.359 CHC13 Chloroform, 1.367, 2.183, 3.251 CHD02 d-Formic acid, 2.242 CHD3O Methanol-dj, 2.298, 3.512 CHN Hydrogen cyanide. Si. 7, 2.15, 3.24 CHO“ Formate ion, 1.434, 2.239, 3.384, 4.68 CHO“ Bicarbonate ion, 1.33, 2.14, 3 . 20, 5.40

CH 2 C1 2 Dichloromethane (Methylene chloride), SI. 266, 2.212 CH 2

I 2 Diiodomethane (Methylene iodide), SI. 322

CII 2 0 Formaldehyde, 1.432, 2.238, 3.382 CH 2 02 Formic acid, 1.435, SI. 246, 2.241, 3.385 CH 3 CI Chloromethane, 1.367a, SI. 174, 2.184 CH 3 DO Methanol-d, 2.297 CH3

I Iodomethane, 1.495, 2.275, 3.478 CH3 NO Formamide, 1.433, SI. 245, 3.383 CH3 N0 2 Nitromethane, 1.553, 1.554, SI. 348, 2.311, 3.573 CH3 N02 Nitromethane anion, SI. 349, 3.5?4 CH3 0~ Methoxide ion, 2.299 CH 3 S Methyl sulfide ion, 3.553 CH4 Methane, 1.519, 2.294, 3.509 CH4 N 2 0 Urea, 1.650, 2.386, 3.749 CH4 N 2 S Thiourea, 1.624, 2.370 CH4 N 2 Se Selenourea, 1.609, 2.352, 3.673 CH40 Methanol, 1.521, 2.296, 3.511, 4.80 CH403 S Methanesulfonic acid, 3.509a CH4S Methanethiol, 1.520, 2.295, 3.510 CHS N Methylamine, 3.523, 4.82 CH5 NO AC-Methylhydroxylamine, SI. 328; O-Methylhydroxylamine, SI. 329, 3.538 CHS N 3 Guanidine, 1.463, 1.464, 2.259 CH6 N

+ Methylammonium ion, 1.524, 2.301, 3.524 CH6 NO + N—Methylhydroxylammonium ion, SI. 330; 0-MethylhydroxyIammonium ion, SI. 331 CH6 N 2 Methylhydrazine, SI. 325

CH 7 N 2 Methylhydrazinium ion, SI. 326

CH 14 CoN s0

2 + Cyanoaquotetraamminecobalt(III) ion, 1.71 CH 15 CoNj + Cyanopentaamminecobalt(III) ion, 1.68, 2.29 CH 15 CoN 6S

2+ Thiocyanatopentaamminecobalt(III) ion, 1.69, 2.30 CN Cyanide ion, 1.35, 2.16, 3.23 CNO Cyanate ion, 1.36 CNS, 5.9

87
CNS” Thiocyanate ion, 1.37, SI. 9, 2.18, 3.25, 4.12 CN 30 1 Trinitromethyl ion, 1.642 CN 40 8 Tetranitromethane, 1.618, 2.364, 5.63 CO Carbon monoxide, 1.31, 2.12, 3.18 C0 2 Carbon dioxide, 1.32, 2.13, 3.19 CO“, 5.39 C03 Carbonate ion, 1.34, 3.21, 4.13 CS 2 Carbon disulfide, 1.354, 2.176, 3.240 C 2 AgN.2 Dicyanoargentate(I) ion, 1.13 C 2 AuN 2 Dicyanoaurate(I) ion, 1.25, 3.10 C 2 C1 3 0 2 Trichloroacetate ion, 1.634 C 2 C1 4 Tetrachloroethylene, 1.633a, 3.691 C 2 D 3 0 2 Acetate ion—

3 , 2.108 C 2 F3 0 2 Trifluoroacetate ion, 1.637, 3.725 C 2 HC12 0 2 Dichloroacetate ion, 1.396a C 2 HC13 1,1,2-Trichloroethylene, 1.634a, 3.721 C 2 HD 5 0 Ethanol-d5 , 3.359 C 2 H03 Glyoxylate ion, 2.257 C 2 H04 Oxalate ion, hydrogen, 1.570, 2.316, 3.593 C 2 H 2 Acetylene, 1.295, 2.114, 3.137 C 2 H 2 Br0 2 Bromoacetate ion, 1.335, 2.158, 3.208 C 2 H 2 C10 2 Chloroacetate ion, 1.358, 2.178, 3.246 C 2 H 2 C1 2 1,1-Dichloroethylene, 1.399b, 3.302; 1,2-Dichloroethylene, 1.399c, 3.303 C 2 H2F0 2 Fluoroacetate ion, 1.423, 2.236, 3.378 C 2 H 2 I0 2 Iodoacetate ion, 1.488 C 2 H 2 N0 3 Oxamate ion, 1.572, SI. 359

C 2 H 2 0 2 Glyoxal, 2.256, 3.427 C 2 H 2 0 3 Glyoxylic acid, SI. 273, 2.258 C 2 H 2 0 4 Oxalic acid, 1.571, 2.316-7, 3.594 C 2 H3 Br0 2 Bromoacetic acid, 2.159 C 2 H 3 C1 Vinyl chloride, 1.658a, 3.754 C 2 H 3 C10 2 Chloroacetic acid, 1.359, 2.179, 3.247 C 2 H 3 C1 3 0 2 Chloral hydrate, SI. 171. 3.245 C 2 H3 I0 2 Iodoacetic acid, 3.473a C 2 H 3 N Acetonitrile, 1.292, 2.111, 3.133, 4.35 C 2 H3 0 2 Acetate ion, 1.287, SI. 77, 2.107, 3.128, 4.34 C 2 H3 0 2 S“ Thioglycolate ion, 1.621, SI. 416, 3.705 C 2 H3 03 Glycolate ion, 2.252, 3.408 C 2 H4 Ethylene, 1.419, 2.229, 3.365, 5.28 C 2 H4CdN0 2 Glycinatocadmium(ll) ion, 1.43 C 2 H4 D 2 0 Ethanol-d2 , 2.225 C 2 H4 INO Iodoacetamide, SI. 292

C 2 H4 NNi0 2 Glycinatonickel(II) ion, 1.196 C 2 H4 N 2 Aminoacetonitrile, 2.125 C 2 H4 N 2 0 2 Oxamide, SI. 360

C 2 H40 Acetaldehyde, 1.284, 2.104, 3.123; Ethylene oxide, 3.370 C 2 H4 0 2 Acetic acid, 1.288, SI. 78, 2.109, 3.129 C 2 H40 2 S Thioglycolic acid, 2.367, 3.704 C 2 H4 0 3 Glycolic acid, SI. 260, 2.253, 3.409 C 2 H5 Br 1— Bromoethane, 1.339, 2.160 C 2 Hs BrO 2— Bromoethanol, 1.340, 2.161, 3.210 C 2 H5 C1 Chloroethane, 2.181 C 2 Hs C10 2— Chloroethanol, 1.366, SI. 173, 2.182, 3.250 C 2 H 5

I Iodoethane, 1.494 C 2 Hs NO Acetaldoxime, 1.285; Acetamide, 1.286, SI. 75, 2.105, 3.124; /V-Methylformamide, 1.530, SI. 323, 3.535 C 2 Hs N0 2 Glycine, 1.443-5, SI. 256-8, 2.250-1,

3.404-3.406, 4.71; Glycine, copper salt, 1.116a; Hydroxyacetamide, SI. 284, 3.447a; Nitroethane, 2.310

C 2 H 5 NS Thioacetamide, 2.365 C 2 H5 N 3 0 2 Biuret, SI. 154 C 2 Hs O Ethoxide ion, 2.226 C 2 H 5 OS 2-Hydroxyethylsulfide ion, 3.454 C 2 H 5 0 3 S Ethanesulfonate ion, SI. 234, 3.357 C 2 H 6 Ethane, 2.223, 3.356 C 2 H 6 N 2 0 2— Aminoacetamide(Glycine amide), SI. 115 C 2 H 60 Ethanol, 1.411, 2.224, 3.358, 4.65 C 2 H6OS Dimethyl sulfoxide, 1.405, SI. 227, 3.342;

2—

Mercaptoethanol, 1.514, SI. 304, 2.292, 3.506 C 2 H 6 0 2 Ethylene glycol, 2.231, 3.369 C 2 H6 0 2 S Dimethyl sulfone, 3.341a

C 2 H6 0 4 P~ Dimethyl phosphate ion, 3.338 C 2 H 6 S Methyl sulfide, 1.404, 3.552 C 2 H 6 S 2 Dimethyl disulfide, 3.327a C 2 H 7 N Ethylamine, SI. 236, 3.362, 4.66 C 2 H 7 NO 2-Aminoethanol, 2.126 C 2 H 7 NS Cysteamine, 1.389, SI. 193, 2.204, 3.289 C 2 H 7 04 P Ethyldihydrogen phosphate, 2.233 C 2 H 8 CdN 2

+ Ethylenediaminecadmium(II) ion, 1.48 C 2 H 8 N

+ Dimethylammonium ion, 3.324; Ethylammonium ion, 1.417, SI. 237, 3.363 C 2 H 8 N 2 1,1-Dimethylhydrazine, SI. 222, 3.329;

1.2-

Dimethylhydrazine, SI. 223, 3.330; Ethylenediamine, 3.366 C 2 H8 N 2 Ni

2+ Ethylenediaminenickel(II) ion, 1.202 C 2 H 9 N 2 1,1-Dimethylhydrazinium ion, SI. 220, 3.331;

1.2-

Dimethylhydrazinium ion, SI. 221, 3.332 C 2 H 10T1

+ Diethylthallium ion, 1.401 C 2 H 15 CoF3 N

2+ Trifluoroacetatopentaamminecobalt(III) ion, 2.38 C 2 H 18 CoN s 0 2 + Acetatopentaamminecobalt(III) ion, 1.72, 2.36 C 2 N 2 Cyanogen, SI. 8, 2.17, 3.22 C 2 04

~ Oxalate ion, 1.569, 2.315, 3.592, 4.89 C 3 D6 0 Acetone-d6 , 3.132 C 3 HD 7 0 2-Propanol-d7 , 2.336 C 3 H 2 D 6 0 2-Propanol-d6 , 3.639 C 3 H 2 N02 Cyanoacetate ion, 1.382, 3.272, 4.61 C 3 H2 N 2 Malononitrile, 2.291 C 3 H2 0 4 ~ Malonate ion, SI. 302, 3.502, 4.77 c 3 h3f 3 0 a, a, a—Trifluoroacetone, 1.638 C 3 H3F 3 0 2 Methyl trifluoroacetate, 1.537 C 3 H3 N Acrylonitrile, SI. 102, 3.145 C 3 H3 NS Thiazole, 1.619 C 3 H3 N02 Cyanoacetic acid, 2.192 C 3 H3 02 Acrylate ioh, SI. 100, 4.39 C 3 H 3 0 3 Pyruvate ion, 1.601, 3.660 C 3 H3 04 Hydrogen malonate ion, 1.513, Si. 250

C 3 H4 Br0 2 2— Bromopropionate ion, 1.346, 2.164, 3.214;

3—

Bromopropionate ion, 1.347, 2.165, 3.215 C 3 H4 C10 2 2— Chloropropionate ion, 1.375, 2.185, 3.257; 3—Chloropropionate ion, 1.376, 2.186, 3.258 C 3 H4 I0 2 2-Iodopropionate ion, 1.497; 3-Iodopropionate

ion, SI. 293

C 3 H 4N 2 Imidazole, 1.484, 2.273, 3.467 C 3 H 4 N 2 0 3 Barbituric acid, SI. 130 C 3 H 4 0 Acrolein, 3.142 C 3 H 4 0 2 Acrylic acid, SI. 101, 3.144 C 3 H 4 04 Malonic acid, SI. 303, 2.290, 3.503 C 3 H 4 0 5 Tartronic acid, 2.358

88
C 3Hs Br0 2 2— Bromopropionic acid, 2.166; 3— Bromopropionic

acid, 2.167 C 3H5C1Q 2 2-Chloropropionic acid, 2.187; 3—Chloropropionic acid, 2.188 C 3 H 5FO Fluoroacetone, 1.424 C 3 H5F02 Methyl fluoroacetate, 1.529 C 3 H 5 I0 2 3-Iodopropionic acid, 3.479 C 3 H 5N Propionitrile, 1.593, 2.339, 3.643, 4.97 C 3 H 5 NO Acrylamide, 1.299, SI. 99, 2.118, 3.143, 4.38 C 3 Hs N03 N-Formylglycine, Si. 247 C 3 Hs N 2 Imidazolium ion, 1.485 C 3 Hs 02 Propionate ion, 2.337, 3.641, 4.96 C 3 Hs02 S" 2-Mercaptopropionate ion (Thiolactate ion), SI. 304a, 3.706; 3— Mercaptopropionate ion, SI. 305, 3.508 C 3 H503 Lactate ion, 1.501, SI. 296, 3.490; Methoxyacetate

ion, 3.514 C 3 H6 Cyclopropane, 2.202; Propylene, 2.340, 3.647 C 3 H 6C1N0 2-Chloropropionamide, 1.373; 3-Chloropropionamide, 1.374 C 3 H6 N 2 02 Malonamide, SI. 300

C 3 H60 Acetone, 1.289, SI. 80, 2.110, 3.131; Allyl alcohol,

1.309, 2.124, 3.156, 4.41; 1,2-Epoxypropane, 3.353 C 3 H602 2,3— Epoxypropanol, 3.354; Ethyl formate, 3.372; Methyl acetate, 2.300, 3.522; Propionic

acid, SI. 386, 2.338, 3.642 C 3 H60 2 S 2-Mercaptopropionic acid, SI. 306, 2.292a; 3-Mercaptopropionic acid, SI. 307, 2.292b; Methyl thioglycolate, SI. 336, 3.554 C 3 H 60 3 Lactic acid, SI. 297, 2.285, 3.491; Methyl

2-hydroxyacetate, 1.532, SI. 327;

1,3,5, -Trioxane, SI. 431, 3.732 C 3 H 7 Br 1-Bromopropane, 1.345 C 3 H7 C1 1-Chloropropane, 1.372 C 3 H7 DO 2-Propanol-2-d, 2.335, 3.638 C 3 H7

I 1—Iodopropane, 1.496 C 3 H7 NO Acetone oxime, 1.291, SI. 81; N,N—Dimethylforma—

mide, 1.403, SI. 218, 3.328; N-Methylacetamide, 3.521; Propionamide, 1.592, SI. 385, 3.640 C 3H7N02 Alanine, 1.303-4, SI. 110, 2.122, 3.150-3.152;

/3-Alanine, 1.305, SI. Ill, 2.123; 2-Hydroxypropionamide, 3.461a; Methyl

2— aminoacetate (Glycine methyl ester), 1.523, SI. 318; 1—Nitropropane, 2.312; Sarcosine, 1.608, 2.351 C 3 H7 N0 2 S Cysteine, 1.390-2, SI. 194, 2.205-6, 3.290, 5.50 C 3 H7N0 3 Serine, 1.610, 2.353, 3.674 C 3 H8 Propane, 2.332 C 3 H8 N

+ Allylammonium ion, 3.157 C 3 HaO 1-Propanol, 2.333, 3.636, 4.94; 2-Propanol, 2.334,

3.637, 4.95 C 3H8 0 2 Dimethoxymethane, 3.322; 2-Methoxyethanol, 3.516; 1,2-Propanediol, 3.634; 1,3-Propanediol,

2.331, 3.635 C 3H80 3 Glycerol, 2.249, 3.403 C 3 H9N Isopropylamine, 1.500a, 3.487; Propylamine, SI. 387,

3.645, 4.98; Trimethylamine, 3.726 C 3 H9 N 3S Mercaptoethylguanidine, 1.515 C 3 H9 04P Trimethyl phosphate, SI. 430, 3.730 C 3H 10N

+ Isopropylammonium ion, 3.488; Propylammonium

ion, 1.593a, SI. 388, 3.646; Trimethylam—

monium ion, 3.727

C 3 H 10 N 2 Trimethylhydrazine, SI. 428

C 3 H u N 2 Trimethylhydrazinium ion, SI. 429

C 303 Oxomalonate ion, SI. 362

C 4CdN 4 ~ Tetracyanocadmate(II) ion, 1.42, 2.20 C 4CuN 4 Tetracyanocuprate(II) ion, 1.122 C 4 H 2 Br0 3 a-Bromotetronate ion, 3.218 C 4 H 2 04 Acetylenedicarboxylic acid, 2.115 C 4 H 2 04

~ Fumarate ion, 1.436, 4.69; Maleate ion, 1.512, SI. 299, 4.76 C 4 H 3 BrN 2 0 2 5— Bromouracil, 1.348, SI. 159, 2.168, 3.219 C 4 H 3 C1N 2 0 2 5-Chlorouracil, SI. 178, 2.190, 3.262 C 4 H3FN 2 0 2 5-Fluorouracil, SI. 244, 2.237, 3.381 C 4 H 3 IN 2 0 2 Iodouracil, 1.499 C 4 H 3 N 2 03 Barbiturate ion, 2.140 C 4 H3 N 3 04 5-Nitrouracil, SI. 355, 3.584 C 4 H 3 N 3 05 5-Nitrobarbituric acid, SI. 340, 3.564 C 4 H 3 0 3 Tetronate ion, 3.699 C 4 H3 04 Hydrogen fumarate ion, 2.243; Hydrogen maleate ion, 1.511, SI. 299; a- Hydroxytetronate ion, 3.466 C 4 H 3 0 3 Oxalacetate ion, 1.568, SI. 358

C 4 H4CrO[0 Dioxalatodiaquochromate(III) ion, 1.111 C 4 H4 N 2 Pyrazine, 2.343; Pyridazine, 2.344; Pyrimidine,

2.347, 3.657b; Succinonitrile, 2.682 C 4 H 4 N 2 0 2 Uracil, 1.647-8, SI. 437, 2.385, 3.746, 4.118 C 4 H4 N 2 0 2 S Thiobarbituric acid, 1.620 C 4 H 4 N 2 03 Barbituric acid, 2.141 C 4 H 4 0 Furan, 1.437, 3.390 C 4 H4 04 Fumaric acid, 2.244, 3.386; Maleic acid, 2.288, 3.500 C 4 H 4 04

" Succinate ion, 1.614, SI. 401, 2.354, 4.102 C 4 H4 04 S

2 ” Thiodiacetate ion, SI. 414 C 4 H 4 04 S 2 2,2'-Dithiobisacetate ion, SI. 229

C 4 H405 Oxalacetic acid, 2.314 C 4 H4 0

2 ~ Malate ion, 1.510, 3.499 C 4 H406 2,3— Dihydroxyfumaric acid, 2.216 C 4H4Oj~ Tartrate ion, 3.689 C 4 H4 08 Tetrahydroxysuccinate ion, 3.695 C 4 H4 S Thiophene, 1.622, 3.707 C 4 H5 N 3-Butenenitrile (Allyl cyanide), 1.351, 4.43; Crotononitrile, 4.60; Methacrylonitrile,

4.78; Pyrrole, 1.597, 3.658 C 4 Hs N02 Methyl cyanoacetate, 1.526; Succinimide, 1.615, SI. 403, 3.681 C 4 Hs N04 Aspartate ion, 1.322 C 4 H5 N3 2-Aminopyrimidine, 1.313, 3.167; 4-Aminopyrimi—

dine, 1.313a C 4Hs N 3 0 Cytosine, 1.396, SI. 204, 2.209, 3.295 C 4 H5 0 2 3— Butenoate ion, 4.54; Crotonate ion, SI. 188, 4.59; Methacrylate ion, 1.518, SI. 309, 4.79 C 4Hs03 Acetoacetate ion, SI. 79 C 4H504 Succinate ion, 1.613, SI. 401 C 4 H6 1,3-Butadiene, 1.349, 2.168a, 3.220 C 4H6 N03 N—Acetylglycine, 2.117, 3.139 C 4 H6N04 Aspartate ion, 1.321, 2.138 C 4H6 N 2 N-Methylimidazole, 3.538a C 4 H6 N 2 0 2 Glycine anhydride, SI. 259, 3.407; Hydrouracil,

1.474, 3.318 C 4 H6 N 3 04 P Cytidine-5'— phosphate, 3.290 C 4 H6 0 l-Butene-3—one, 3.229; Crotonaldehyde, 3.270 C 4 H6 0 2 Biacetyl, 2.155, 3.202; 2,3— Butanedione, 1.350; Crotonic acid, SI. 189, 3.271; Cyclopro—

panecarboxylic acid, 2.203; Methacrylic

89
acid, SI. 310; Methyl acrylate, SI. 315; Vinyl acetate, SI. 439

C 4 H6 04 Succinic acid, SI. 402, 2.355, 3.680 C 4 H6 0 4S Thiodiglycolic acid, 2.366, 3.703; Thiomalic

acid, 2.368 C 4 H6 04 S 2 Dithiodiglycolic acid, 2.219 C 4 H 6O s Malic acid, 2.289, 3.501 C 4H6 06 Tartaric acid, 2.357, 3.688

-C 4 H 7 N Isobutyronitrile, 2.281 C 4 H 7 NO Methacrylamide, SI. 308; 2— Pyrrolidone, 1.600 C 4 H 7 N0 2 Diacetamide, SI. 208

C 4 H 7 N0 3 N—Acetylglycine, 1.296, SI. 87 C 4 H 7 N04 Aspartic acid, SI. 128, 2.139, 3.181; Iminodiacetic acid, 2.274 C 4 H 7 0 2 Butyrate ion, 2.174, 3.238, 4.56; 2-Methylpropionate ion (Isobutyrate ion), 2.279, 3.549 C 4 H8 1-Butene, 2.173, 3.228; Isobutylene, 2.278, 3.482 C 4 H 8 CdN 2 0 4 Bis(glycinato)cadmium(II), 1.44 C 4 H 8 CuN 2 0 4

+ Bis(glycinato)copper(II) ion, 3.43 C 4 H 8 N0 2 4-Aminobutyrate ion, 1.312 C 4 H 8 N 2 Ni0 2 Dimethylglyoximenickelate(II) ion, 4.28 C 4 H 8 N 2 Ni0 4 Bis(glycinato)nickel(II), 1.197 C 4 H8 N 2 0 2 N—Acetylglycine amide, SI. 88; Succinamide, SI. 400

C 4 H 8 N 2 03 Asparagine, 1.319-20, 2.137, 3.180; Glycylglycine, 1.450-2, SI. 261-2, 2.254, 3.411-13

C 4 H 8 0 2-Butanone, 3.227; Butyraldehyde, 3.237; 1,2-Epoxybutane, 3.352; Tetrahydrofuran, 2.360, 3.693 C 4 H8 0 2 Acetoin, 3.130; 2-Butene-l,4-diol, 4.53; Butyric

acid, 2.175, 3.239; Dioxane, 2.218, 3.343; Ethyl acetate, 1.415, 2.227, 3.361; 3-Hydroxy-2— butanone, 1.480; Isobutyric

acid, 2.280; Methyl propionate, 1.536, 3.548 C 4 H8 03 2-Hydroxybutyric acid, 3.450, 2— Hydroxyethyl

acetate, 3.451 C 4 H9 Br 1-Bromobutane, 1.338 C 4 H9 C1 1— Chlorobutane, 1.364; 2—Chlorobutane, 1.365;

1—

Chloro— 2— methylpropane, 1.368 C 4 H9

I 1-Iodobutane, 1.493 C 4 H9 N Pyrrolidine, 1.598-9, 3.659, 4.99a C 4 H 9 NO Af,A/-Dimethylacetamide, SI. 215, 3.323; 7V-Ethyl—

acetamide, 1.414; Isobutyramide, 3.483; N-Methylpropionamide, 3.547 C 4 H9 NOS /V— Acetylcysteamine, SI. 85

C 4 H9 N0 2 2- Aminobutyric acid, 2.125a, 3.160; 3— Aminobutyric acid, 3.161; 4—Aminobutyric acid, 3.162; 2— Amino—2— methylpropionic acid, 2.127; Ethyl 2— aminoacetate, 1.416 C 4 H9 N0 2 S Cysteine, methyl ester, SI. 195; S-Methylcysteine,

SI. 319, 3.532 C 4 H9 N0 3 2— Methyl—2— nitro—1— propanol, 1.556; Threonine,

1.625, 2.371, 3.708 C 4H9 N04 2— Methyl—2— nitro-1, 3— propanediol, 1.555 C 4H9 N3 0 Acetone semicarbazone, 1.290 C 4 H9 N 3 0 2 Creatine, 1.381; Glycylglycine amide, SI. 263, 3.414 C 4H l0 Butane, 2.169; Isobutane, 2.276 C 4 H 10 N

+ Pyrrolidinium ion, 1.599, 3.659 C 4 H 10O 1-Butanol, 2.170, 3.225; 2-Butanol, 2.171, 3.226; Ethyl ether, 1.421, 2.232, 3.371, 4.67;

2-

Methyl-l-propanol (Isobutanol), 2.277,

3.546, 4.83; 2— Methyl—2— propanol (tert— Butanol), 1.352, 2.172, 3.545

C 4 H 10O 2 1,2— Butanediol, 3.221; 1,3— Butanediol, 3.222; 1,4— Butanediol, 3.223; 2,3— Butanediol,

3.224; 1,2— Dimethoxyethane, 3.321; 2—Ethoxyethanol, 3.360 C 4 H 10O 2 S 2 Dithiothreitol, 3.347 C 4 H 10O3 Diethyleneglycol, 3.308 C 4 H 10O4 Erythritol, 3.355 C 4 H 10S tert-Butylmercaptan, 1.353, 3.235 C 4 H 10S 2 Diethyl disulfide, 3.307a

C 4 H 10T1

+ Diethylthallium ion, 1.401 C 4 H u N Butylamine, SI. 161, 3.231, 4.55; /err-Butylamine,

3.232 C 4 H,,NO A/,(V-Diethylhydroxylamine, SI. 212

C 4 H 12 N

+ Butylammonium ion, SI. 162, 3.233; /er/-Butylam—

monium ion, 1.352a, 3.234; Diethylammoniutn

ion, 3.307; Isobutylammonium ion, 3.481 C 4 H 12 NO + N,N— Diethylhydroxylammonium ion, SI. 211 C 4 H 12 N 2 S 2,2'— Dithiobis(ethylamine), 3.346 C 4 H 12 N 2 S 2 Cystamine, 1.388, SI. 192 C 4 H 16 CdN 4 + Bis(ethylenediamine)cadmium(II) ion, 1.49 C 4 H 16 C1 2 CoN4 Dichlorobis(ethylenediamine)cobalt(III) ion, 1.87, 2.43 C 4 H 16 Cl 2 CrN 4 Dichlorobis(ethylenediamine)chromium(III)

ion, 1.107 C 4 H 16 CoF2 N 4 Difluorobis(ethylenediamine)cobalt(III) ion,

1.86, 2.42 C 4 H 16 CuN4 + Bis(ethylenediamine)copper(II) ion, 3.42 C 4 H 16 N4 Ni 2+ Bis(ethylenediamine)nickel(II) ion, 1.203 C 4 H 18ClCoN 2 + Chloroamminebis(ethylenediamine)cobalt(III)

ion, 1.89 C 4 H 18 CoFN 4 0

2+ Fluoroaquobis(ethylenediamine)cobalt(III)

ion, 1.91 C 4 H,8 CoN 5 04 Fumaratopentaamminecobalt(III) ion, 1.73, 2.32 C 4 H 18 CoN6 0

2+ Nitroamminebis(ethylenediamine)cobalt(III)

ion, 1.90 C 4 H 20CoN4 O2 + Diaquobis(ethylenediamine)cobalt(III) ion, 2.41 C 4 HgN 4

' Tetracyanomercurate(II) ion, 1.150 C 4 N4 Ni 2 Tetracyanonickelate(II) ion, 1.195, 3.85 C 4 N4 Pd 2 ~ Tetracyanopalladate(II) ion, 1.221 C 4N4 Pt

2 ~ Tetracyanoplatinate(II) ion, 1.226, SI. 53, 2.93, 3.100 C 4 N4Zn 2 ~ Tetracyanozincate(II) ion, 1.279 C 404 Acetylenedicarboxylate ion, 4.36 C 409Ti 2 Bisoxalatooxotitanate(IV) ion, 3.117a C s ClCoN 3- Chloropentacyanocobaltate(III) ion, 1.77 CjCoINj” Iodopentacyanocobaltate(III) ion, SI. 20 C sCoN 3 Pentacyanocobaltate(II) ion, 1.59, Si. 14 C 5 CoN 6 0

3 Nitrosylpentacyanocobaltate ion, SI. 21, 3.35 C s CoN 6 0 2 Nitropentacyanocobaltate(III) ion, 1.80 C s CoN 8 Azidopentacyanocobaltate(III) ion, 1.79 C 5CrN 6 0

3 Nitrosylpentacyanochromate ion, SI. 23, 3.39 C 5 D 5 N Pyridine-tfs , 3.650 C s FeN 60

2 Nitrosylpentacyanoferrate(III) ion, 1.138, 3.57 C 5 HCoN 8 Hydridopentacyanocobaltate(III) ion, SI. 16 C 5 HCoN 5 0

3 Hydroxypentacyanocobaltate(III) ion, 1.78, SI. 19 C S HD S N

+ Pyridinium ion -<f 5 , 3.657 C s H 2 BrN 2 0 4 5-Bromoorotate ion, SI. 155 C s H 2 CoN 5 0

2 ~ Aquopentacyanocobaltate(III) ion, SI. 18 C 5 H 2 N05 5-Nitrofuroate ion, SI. 347, 3.571 C 5 H 2 N 3 06 5— Nitroorotate ion, 3.576 C 5 H 3 BrN 2 04 5-Bromoorotic acid, SI. 156, 2.162, 3.212

90
C 5 H3FeNj Pentacyanoammineferrate(II) ion, 1.135 C s H3 N04 5-Nitro—2-furaldehyde, SI. 343, 3.569 C<:H,N,07 Isoorotate ion, 1.500c, 3.485; Orotate ion, 1.567, 3.590 C 5 H3 N 3 06 5-Nitroorotic acid, SI. 351 C 5 H 303 2— Furoate ion, 3.392 C 5H4 BrN 2-Bromopyridine, 3.216; 3-Bromopyridine, 3.217 C s H4C1N 2—Chloropyridine, 3.259; 3—Chloropyridine, 3.260 C s H4 NO~ 2-Hydroxypyridine, anion, 3.462; 3-Hydroxypyridine,

anion, 3.464; 4-Hydroxypyridine, anion, 3.465 C 5 H4N 2 04 Isoorotic acid, 2.283; zl«//-5-Nitro-2-furaldoxime, SI. 346, 2.310a, 3.568; Orotic acid, 2.313 C 5H4 N 4 Purine, 1.595, SI. 389, 2.342, 3.648a C 5 H4 N 40 Hydroxypurine, 3.461b; Hypoxanthine, 1.483, 3.466a C 5 H 4 N4 0 2 Xanthine, 3.754a C 5 H4 N4 03 Uric acid, 1.651, 3.749a C s H40 2 2-Furaldehyde, 3.388 C s H4 04

~ Glutaconate ion, 4.70 C 5 H 4 0 3 2-Oxoglutarate ion, 1.573, SI. 361 C S H S N Pyridine, 1.596, SI. 391, 2.345, 3.649, 4.99 C s Hs NO 3-Hydroxypyridine, 3.463 C s Hs N03 7V-Acetylalanine, 3.135 C s H 5 N 2 04 Hydroorotate ion, 1.472a, 3.316 C 5 H5 N3 04 5-Nitro-6-methyluracil, SI. 350, 3.575 C 5 Hs N 5 Adenine, 1.300, SI. 105, 2.119, 3.146 C 5 H5 N s O Guanine, SI. 274, 3.428; Isoguanine, 3.483a C 5 H 5 04 Methyl fumarate ion, SI. 324

C s H 6

I Iodobenzene, 3.474 C 5 H6 N

+ Pyridinium ion, 2.346, 3.656 C s H6 N 2 2-Aminopyridine, 3.165; 4— Aminopyridine, 3.166 C s H6 N2 02 6—Methyluracil, 1.539, 2.303; Thymine, 1.627, SI. 418, 2.374, 3.711, 4.107 C 5 H 602 Furfuryl alcohol, 3.391 C 5 H7 N0 2 Ethyl cyanoacetate, 1.418; N—Methylsuccinimide,

SI. 335

C 5 H7 N30 1 —Methylcytosine, SI. 320; 5-Methylcytosine,

1.527, 3.533 C 5H7 0 2 Cyclobutanecarboxylate ion, 3.276 C S H8 Cyclopentene, 3.288 C s H8 N04 Glutamate ion, 1.440, 2.246 CsH8 N 2 02 Dihydro-6-methyluracil, 3.315; 5,6-Dihydrothymine, 1.473a, 2.217, 3.317 C5 H8 0 1 ,4—Pentadien-3-ol, 3.599, 4.89a CsH80 2 Acetylacetone, 2.113; Cyclobutanecarboxylic acid, 2.193; Ethyl acrylate, SI. 235; Methyl

methacrylate, SI. 332

C 5 H8 04 Glutaric acid, 3.401 C sH9 N Trimethylacetonitrile, 2.379 C s H,N02 Proline, 1.590-1, 2.330, 3.633 C s H9N03 N-Acetylalanine, 1.293, 1.294, 2.116; N-Acetylglycine, methyl ester, SI. 89; N-Acetylsarcosine, SI. 96; Hydroxyproline, 1.482,

2.272, 3.461 C s H9 N03 S N—Acetylcysteine, SI. 86 C 5 H9N04 Glutamic acid, 2.247, 3.399 C s H90 2 2— Methylbutyrate ion, 3.529; 3— Methylbutyrate ion (Isovalerate ion), 2.284, 3.530; Pentanoate

ion (Valerate ion), 2.319, 3.752; Trimethylacetate ion (Pivalate ion), 2.378, 3.622 C s H 909P Ribose—5-phosphate, 3.665 C S H 10 Cyclopentane, 2.200, 3.286

C 5 H 10 N 2 O3 Alanylglycine, 1.307, 3.154; Glutamine, 3.400; Glycylalanine, 1.447, 3.410; Glycylsarco—

sine, SI. 272; Sarcosylglycine, SI. 395

C S H 10 N 2 O4 Glycylserine, 3.424 C s H 10O 2-Pentanone, 3.603; 3-Pentanone, 3.604; Tetrahydropyran, 3.694 C 5 H 10 O 2 Ethyl propionate, 3.376; Isopropylacetate, 3.486; Methyl butyrate, 3.528; 2-Methylbutyric

acid, 2.302; 3-Methylbutyric acid (Isovaleric acid), 3.531; Propyl acetate, 3.644; Trimethylacetic acid (Pivalic acid), 1.588 C 5 Hi0 O4 Deoxyribose, SI. 205, 2.210, 3.299 C S H 10 O 5 Arabinose, 1.315, 2.133; Ribose, 1.605, 2.349,

3.664; Xylose, 1.661 C 5 H„NO 7V-Methylisobutyramide, 3.543; Pivalamide, Si. 380, 3.621 C S H ,,N0 2 Norvaline, 2.312a, 3.587; Valine, 1.657—8,

2.387-8, 3.753 C 5 H u N02 S 3-Mercaptovaline (Penicillamine), 1.517, SI. 365,

2.317a, 3.596; Methionine, 1.522, SI. 314,

2.298a, 3.513 C 5 H n N0 2 Se Selenomethionine, 3.672a C s H 12 Pentane, 2.318 C S H i 2 N0 2 Betaine, 2.154 C S H i 2 N 2 02 Ornithine, 3.589 C 5 H,2 0 2-Methyl-2-butanol, 3.526; 3-Methyl-l-butanol

(Isobutanol), 3.527; Neopentyl alcohol, 2.305; 1— Pentanol, 3.602; 3—Pentanol, 3.602a C S H

|

2 02 Diethoxymethane, 3.306; 1,5— Pentanediol, 3.601 C S H 12 04 Pentaerythritol, 3.598 C s H 13 N Amylamine, 1.313b, SI. 121, 3.168, 4.44; Isoamylamine, 1.499a C 5H,4N

+ Amylammonium ion, SI. 122, 3.169; Isoamylammonium

ion, 3.480 C 5 H 16 CoN4 03 Carbonatobis(ethylenediamine)cobalt(III) ion, 1.88, 2.44 C 5 H20CoN 6 3+ Pentaamminepyridinecobalt (III) ion, 3.34a C sMnN6 O

s Nitrosylpentacyanomanganate ion, 3.70 C 6CoNg“ Hexacyanocobaltate(III) ion, 1.76, SI. 15, 2.35 C 6 CoN 6 S

3 Pentacyanothiocyanatocobaltate(III) ion, SI. 17 C 6 Co0 3

2 Trioxalatocobaltate(III) ion, SI. 17 C 6CrN 3 Hexacyanochromate(III) ion, 1.105 C 6CrN8 Hexacyanochromate(II) ion, 1.100 C 6Cr0 12 Trioxalatochromate(III) ion, Si. 24, 2.51 C 6 D s N02 Nitrobenzene-d5 , 3.566 C 6 D6 Benzene- d6 , 3.187 C 6F6 Hexafluorobenzene, 1.465c, SI. 279, 3.438 C 6 FeN 3 Hexacyanoferrate(III) ion, 1.137, SI. 30, 2.63, 5.45 C 6FeN 8

~ Hexacyanoferrate(II) ion, 1.134, 3.54, 3.55, 4.19, 5.15 C 6Fe0 3 2 Trioxalatoferrate(III) ion, 2.64 C 6 HFS Pentafluorobenzene, 1.573a, Si. 367, 3.600 C 6 HFeN 8 Hydrogen hexacyanoferrate(II) ion, SI. 29 C 6H 2 C1 2 02 2,5— Dichloro—p—benzoquinone, 5.52 ^6H 2 F4 1,2,3, 4-Tetrafluorobenzene, 1.633b, SI. 411, 3.692 C 6 H 2 N 3 0 7 Picrate ion, 1.587 C 6 H3 08 Aconitate ion, 1.297, 4.37 CsH 4 BrO o— Bromophenoxide ion, 1.341; m— Bromophenoxide

ion, 1.342; p-Bromophenoxide ion, 1.344, SI. 158 C 6 H 4 C10 o—Chlorophenoxide ion, 1.369; m—Chlorophenoxide

ion, 1.370; p— Chlorphenoxide ion, 1.371

91
C 6 H4C1 2 o— Dichlorobenzene, 1.397; m—Dichlorobenzene, 1.398; p—Dichlorobenzene, 1.399 C 6 H4FO o—Fluorophenoxide ion, 1.429; m—Fluorophenoxide

ion, 1.430; p—Fluorophenoxide. ion, 1.431 C 6 H4F2 o~ Difluorobenzene, SI. 213, 3.313; p— Difluorobenzene,

SI. 214, 3.314 C 6 H 4 N0 2 Isonicotinate ion, 1.500b; Nicotinate ion, 1.549, 3.560; Picolinate ion (2— Pyridinecarboxy—

late ion), 1.586a; 3— Pyridinecarboxylate

ion, 3.653; 4-Pyridinecarboxylate ion, 3.654 C 6 H4 NOJ o-Nitrophenoxide ion, 1.557; m-Nitrophenoxide

ion, 1.558; p— Nitrophenoxide ion, 1.560 C 6 H 4 N 2 3-Pyridinenitrile, 3.655 C 6 H 4 02 Benzoquinone, 1.330, SI. 138, 2.152, 3.195, 5.47 C 6 H 4 04 Muconate ion, 4.84 C 6H4 O8S 2 2- Tiron (1.2-Dihydroxybenzene-3,5-disulfonate ion). 5.64 C 6 H s Br Bromobenzene, 1.336 C 6 H 5 BrO p— Bromophenol, 1.343, SI. 157, 2.163 C 6 H 5 C1 Chlorobenzene, 1.360, 3.248 C 6 H 5 C10 w-Chlorphenol, 3.253; o— Chlorophenol, 3.254 C 6 H 5 F Fluorobenzene, 1.425, SI. 243, 3.379 C 6 H5

I Iodobenzene, 1.489 C 6 H 5 NO Nitrosobenzene, 1.563, 3.581 C 6 H 5 N0 2 Nicotinic acid, 2.306, 3.561; Nitrobenzene, 1.551, SI. 341, 2.308, 3.565, 4.87 C 5 H s N02 Nitrobenzene anion, SI. 342

C 6 H 5 N03 m-Nitrophenol, 3.577; o-Nitrophenol, 3.577a; p—Nitrophenol, 1.559, SI. 352, 3.577b

C 6 Hs O~ Phenoxide ion, 1.576, SI. 370, 3.608, 4.90 C6 H s 0 2 p-Hydroxyphenoxide ion, 1.473 C 6 H s 03 S~ Benzenesulfonate ion, 1.326, 2.145, 3.189 C 6 H5 0 7 ~ Citrate ion, 4.57 C 6 H 5 S Thiophenoxide ion, 1.623 C 6 H6 Benzene, 1.324, SI. 132, 2.144, 3.186, 4.47 C 6 H 6 A1N0 6 Nitrilotriacetatoaluminum(III), 1.19 C 6 H6 As0 3 Phenylarsonate(V) ion, 1.581 C 6 H6 NNiO 8 Nitrilotriacetatonickelate(II) ion, 1.199 C 6 H6 N03 S- Sulfanilate ion, 1.616, SI. 406

C 6 H6 NC>r Nitrilotriacetate ion, 1.550 C 6 H6N06 Zn~ Nitrilotriacetatozincate(II) ion, 1.281 C 6 H6 N 2 0 Isonicotinamide, 1.500a; Nicotinamide, 1.546a,

3.558; 3— Pyridinecarboxamide, 3.651; 4—Pyridinecarboxyamide, 3.652 C 6 H6 N 4 0 4 5— Nitro-2-furaldehyde semicarbazone, SI. 345, 3.570 C 6 H6 0 Phenol, 1.575, SI. 369, 2.320, 3.607 C 6 H6 0 2 Hydroquinone, 3.446, 5.56; m—Hydroxyphenol, 3.456; o—Hydroxyphenol, 3.457 C 6H60 3 S Benzenesulfonic acid, 3.190 C 6 H6 0 4 2— Hexene— 1,6— dioate ion, 4.74; 3— Hexene-1,6—dioate

ion, 4.75 C 6 H6 S Thiophenol, 2.369 C 6 H 7 N Aniline, 1.314, SI. 123, 2.128, 3.170, 4.45 C 6 H 7 NO Phenylhydroxylamine, 1.582, 3.617 C 6 H 7 N0 2 N-Ethylmaleimide, 1.421a, SI. 239, 2.234, 3.374 C 6 H 7 N0 2 S Benzenesulfonamide, 1.325, SI. 133, 3.188 C 6 H 7 N0 3 S Sulfanilic acid, 1.616a, SI. 407, 3.687 C 6 H 7 N 5 2-Methyladenine, SI. 316; 7— Methyladenine, SI. 317

C 6H 7 0 2 Sorbate ion, SI. 397

C 6 H 7 0j Ascorbate ion, SI. 127, 2.135, 3.178 C 6 H 7 0 7 Citrate ion, 1.380; Isocitrate ion, 1.500

C 6 H 8 1,3—Cyclohexadiene, 1.384, 2.195, 3.280; 1,4— Cyclo—

hexadiene, 1.385, 2.196, 3.281 C 6 H 8 CoN 2 0 8 Dioxalatoethylenediaminecobaltate(III) ion, 2.46 C 6 H 8 N 2— Methylpyridine, 3.550; 3—Methylpyridine, 3.551 C 6 H8 N

+ Anilinium ion, 2.129, 3.171 C 6 H 8 N03 Af-Ethylmaleamate ion, SI. 238

C 6 H8 N 2 o-Phenylenediamine, 2.325; m—Phenylenediamine,

2.326; p—Phenylenediamine, 2.327 C 6 H 8 N 2 0 2 1,3— Dimethyluracil, 1.406; 1,6— Dimethyluracil,

1.407; 3,6-Dimethyluracil, 1.408; 4-Ethoxy—

uracil, 1.413 C 6 H 8 N 2 02 S Sulfanilamide, 1.615b, SI. 405, 3.686 C 6 H 8 0 2 Sorbic acid, SI. 398

C 6 H 8 04 Dimethyl fumarate, SI. 219, 3.217a; Dimethyl maleate,

SI. 224 C 6 H8 0 4 Adipate ion, 4.40 C 6 H 8 04 S

2 3,3'—Thiodipropionate ion, SI. 415

C 6 H 8 0 4S 2 2,2'— Dithiobispropionate ion, SI. 230

C 6 H 8 06 Ascorbic acid, 2.136, 3.179; n-Glucuronolactone,

3.398 C 6 H 8 0 7 Citric acid, 2.191, 3.266 C 6 H9 NO N—Vinylpyrrolidone, SI. 442 C 6 H 9 N0 3 N—Ethylmaleamic acid, 2.233a, 3.373 C 6 H 9 N06 Nitrilotriacetic acid, 2.307, 3.563 C 6 H 9 N 2 04 N—Acetylglycylglycine, SI. 90, 3.140 C 6 H 9 N 3 0 2 Histidine, 1.466-8, 2.269, 3.442 C 6 H9 N 3 0 3 l-(2-Hydroxyethyl)-2-methyl-5-nitroimidazole,

3.453 C 6 H 9 0 2 Cyclopentanecarboxylate ion, 3.287 C 6 H907 n—Glucuronate ion, 1.439a, SI. 252, 3.396 C 6 H 10 Cyclohexene, 1.387, 2.198, 3.284 C 6 H 10 N 2 O2 Alanine anhydride, SI. 112, 3.153; Sarcosine

anhydride, SI. 394, 3.670 C 6 H , 0 N 3 O6 Glycylasparagine, 1 .448-9

C 6 H 10O Cyclohexanone, 1.386; 2,4-Hexadien-l-ol, 3.437, 4.72 C ftH jqO 2 1-Cyclopentanecarboxylic acid, 2.201 C 6 H 10 O3 Ethyl acetoacetate, 2.228 C 6 H 10 O4 Adipic acid, 3.149 C 6 H , 0 O 7 Glucuronic acid, 3.397 C 6H n N3 0 3 N-Acetylglycylglycine amide, SI. 191 C 6H U N 3 04 Glycylglycylglycine, 1.453—1.455, SI. 266— 7, 2.255, 3.415-7

C 6 H u 0 2 Hexanoate ion, 2.264, 3.440, 4.73; 3,3— Dimethylbutyrate ion, 3.327 C 6H 12 Cyclohexane, 2.197 C 6H 12 A1N 3 06 Tris(glycinato)aluminum(III), 1.18 C 6 H 12 CdN 3 08 Tris(glycinato)cadmate(II) ion, 1.45 C 6 H 12 CuN 2 04

+ Bis(2— aminopropionato)copper(II) ion, 3.44; Bis(3-aminopropionato)copper(II) ion, 3.45 C 6 H 12 CuN 3 0 6 Tris(glycinato)cuprate(II) ion, 1.117 C 6 H 12 HgN 3 06 Tris(glycinato)mercurate(II) ion, 1.151 C 6 H 12 MnN 3 0 6 Tris(glycinato)manganate(II) ion, 1.171 C 6 H 12 N 20 3 Alanylalanine, 1.306; Glycylglycine, ethyl

ester, SI. 264

C 6 H 12 N 2 0 4 S 2 Cystine, 1.393, 1.394, SI. 196-7, 2.207, 3.291 C 6 H 12 N 2 0 4 Se 2 Selenocystine, SI. 396, 3.672 C 6 H 12 N 3 Ni0 8 TrisfglycinatolnickelatefH) ion, 1.198 C 6 H 12 N 3 06 Pb~ Tris(glycinato)plumbate(II) ion, 1.216 C 6 H i 2 N 3 06 Zn“ Tris(glycinato)zincate(II) ion, 1.283 C 6 H 12 N 4 0 2 N,N,N' ,N'-Tetram ethyl- 1 ,2-diazenedicarboxamide

('Diamide'), 3.696

92
C 6 H i 2 N 4 0 3 Glycylglycylglycine amide, SI. 268

C 6 H 12 0 Vinyl isobutyl ether, SI. 441 C 6 H i 2 0 2 Cyclohexaneperoxy radical, 5.26, 5.49; Ethyl butyrate, 3.364; Hexanoic acid, 2.265; Methyl

trimethylacetate (Methyl pivalate), 1.538 C 6 H 12 0 3 2,4,6— Trimethyl-1,3, 5-trioxane, 3.731 C 6 H 12 0 5 Methylarabinoside, 3.525 C 6 H 12 06 Glucose, 1.439, 2.245, 3.394; Inositol, 3.473 C 6 H 13 N Cyclohexylamine, 1.387a; Hexamethyleneimine, 2.261 C 6 H 13 NO N-Zert-Butylacetamide, SI. 160, 3.230; N,N— Diethylacetamide, SI. 210; (V-Methylpivalamide, 3.544 C 6 H 13 N0 2 Isoleucine, 2.282, 3.484; Leucine, 1.502, 2.286, 3.493-5; Norleucine, 1.566, 3.585 C 6 H 13 NOs 2— Amino—2—deoxy—p—galactose, SI. 118, 3.163; Glucosamine, 1.438 C 6 H 13 N08S 2-Deoxy-2-sulfoamino-|)—glucose, SI. 206, 3.300 C 6 H 13 09 P Glucosephosphate, 3.395 C 6 H 14 Hexane, 2.262 C 6 H 14 N

+ Cyclohexylammonium ion, 3.285 C 6 H 14 N 2 0 2 Lysine, 1.508, 2.287, 3.497 C 6 H 14 N 4 0 2 Arginine, 1.316-8, 2.134, 3.177 C 6 H 14 0 1 -Hexanol, 2.266, 3.441 C 6 H 14 02 1,1-Diethoxyethane, 3.305; 1,6— Hexanediol, 3.439; Pinacol, 3.620 C 6 H 14 06 Sorbitol, 1.611 C 6 H 14 S 2 Di-2-propyl disulfide, 3.345a C 6 Hi5 N Triethylamine, 3.723, 4.114 C 6 H 16 CoN 4 04 Oxalatobis(ethylenediamine)cobalt(III) ion, 2.45 C 6 H 16CoN 6 S 2 Dithiocyantobis(ethylenediamine)cobalt(III)

ion, 1.92 C 6 H 16 CrN6 S 2 Dithiocyanatobis(ethylenediamine)chromium(III)

ion, 1.108 C 6 H 16 N

+ 1-Hexylammonium ion, 2.267; Triethylammonium ion, 3.724 C 6 H 16 N 2 1,6— Hexanediamine, 2.263 C 6 H 16 N 6 S 2 Bis(2— guanidinoethyl)disulfide, 1.516 C 6 H 24CdN8 + Tris(ethylenediamine)cadmium(II) ion, 1.50 C 6 H 24CoN 8

+ Tris(ethylenediamine)cobalt(III) ion, 1.85, 2.40 C 6 H24CrN 8

+ Tris(ethylenediamine)chromium(III) ion, 1.106 C 6 H24 CuN8 Tris(ethylenediamine)copper(II) ion, 1.121 C 6 H24 HgN8

+ Tris(ethylenediamine)mercury(II) ion, 1.149 C 6 H 24 N 6 Ni 2+ Tris(ethylenediamine)nickel(II) ion, 1.204 C 6H 24 N6 Pb 2+ Tris(ethylenediamine)lead(II) ion, 1.219 C 6 H 24 N 6 Zn 2+ Tris(ethylenediamine)zinc(II) ion, 1.278 C 6MnN8 Hexacyanomanganate(II) ion, 1.174 C 6N 4 Tetracyanoethylene, 1.617 C 6 N 6 0s 4 Hexacyanoosmate(II) ion, 1.207 C 6 N 6 Ru 4 Hexacyanoruthenate(II) ion, 1.231 C 7 H 4Br0 2 p-Bromobenzoate ion, 1.337, 3.209 C 7 H4C10 2 o-Chlorobenzoate ion, 1.361, 3.248a; m-Chlorobenzoate ion, 1.362, 3.248b; p-Chlorobenzoate ion, 1.363, 3.249 C 7 H 4F0 2 o— Fluorobenzoate ion, 1.426; m— Fluorobenzoate ion, 1.427; p— Fluorobenzoate ion, 1.428, 3.380 C 7 H4I0 2 o— Iodobenzoate ion, 1.490, 3.475; m— Iodobenzoate

ion, 1.491, 3.476; p-Iodobenzoate ion, 1.492, 3.477 C 7 H 4 NO p-Cyanophenoxide ion, 4.62 C 7 H 4 N0 4 p-Nitrobenzoate ion, 3.567 C 7 H 40 3 Salicylate ion, dianion, 4. 101 C 7 H 5C10 2 p-Chlorobenzoic acid, 2.180 C 7 H 5 C1 3 a,a,a-Trichlorotoluene, 1.636

C 7 H 5 F 3 a,a,a— Trifluorotoluene, 1.639 C 7 H s N Benzonitrile, 1.328, 2.150, 3.193, 4.49 C 7 H 5 NO o— Hydroxybenzonitrile, 1.477; m-Hydroxybenzonitrile,

1.478; p—Hydroxybenzonitrile, 1.479 C 7 H5 N04 p-Nitrobenzoic acid, 2.309 C 7 H 5 0 2 Benzoate ion, 1.327, 2.148, 3.191, 4.48; Salicylaldehyde, anion, 4.100 C 7 Hs03 w— Hydroxybenzoate ion, 1.475; p-Hydroxybenzoate

ion, 1.476, 3.449; Salicylate ion, 1.607, 2.350, 3.669 C 7 H 6 N0 2 p- Aminobenzoate ion, 1.310, SI. 116, 3.158 C 7 H 6 N 2 o-Aminobenzonitrile, 1.311 C 7 H 6 N 4 O s Furamazone, SI. 250, 3.389 C 7 H 6 0 Benzaldehyde, 2.142, 3.184 C 7 H 602 Benzoic acid, 1.327a, SI. 135, 2.149, 3.192; p-Hydroxybenzaldehyde, 3.448; Salicylaldehyde,

3.668a; 2— Methyl—p—benzoquinone, 5.57 C 7 H 6 03 p-Hydroxybenzoic acid, 2.270 C 7 H 7 Tropylium ion, 2.381 C 7 H 7 Br Benzyl bromide, SI. 145 C 7 H 7 C1 Benzyl chloride, 1.332, SI. 146; p—Chlorotoluene,

1.377 C 7 H7

I p-Iodotoluene, 1.498 C 7 H 7 N Vinylpyridine, 1.659 C 7 H 7 NO Benzamide, 1.323, SI. 131, 2.143, 3.185 C 7 H 7 N02 p— Aminobenzoic acid, 3.159; Anthanilic acid (o-Aminobenzoic acid), 3.173; p-Nitrotoluene, 1.565, 4.88 C 7 H 7 NOs S p-Nitro—o—toluenesulfonic acid, 3.583 C 7 H 7 CT o—Methylphenoxide ion, 4.82a; p—Methylphenoxide

ion, 4.82b C 7 H7 02 p—Methoxyphenoxide ion, 4.81 C 7 H 7 03 S o-Toluenesulfonate ion, 3.714; m—Toluenesulfonate

ion, 3.715; p—Toluenesulfonate ion, 1.632, SI. 420, 3.716 C 7 H8 Cycloheptatriene, SI. 191, 2.194, 3.279; Toluene,

1.631, 2.375, 3.713, 4.111 C 7 H8 N

+ Vinylpyridinium ion, 1.660 C 7 Hg O Anisole, 2.130, 3.172; Benzyl alcohol, 1.330, SI. 144, 2.153, 3.196; o—Cresol, 3.268; p—Cresol,

SI. 186, 3.269; Hydroxycycloheptatriene,

SI. 285

C 7 H8 G 2 o— Methoxyphenol, 3.518; p—Methoxyphenol, 3.519 C 7 H8 S Benzyl mercaptan, SI. 149 C 7 H9 N Benzylamine, 1.331a; p—Toluidine, SI. 421, 4.113 C 7 H9 N 2 0 1-Methylnicotinamide, 1.535 GtHjqN 2,4-Dimethylpyridine, 3.340; 2,6— Dimethylpyridine,

3.341 C7 Hi0 N+ Benzylammonium ion, 3.197 C 7 H

i

0N 2 O 2 4— Ethoxy— 1—methyluracil, 1.412; 1,3,5-Trimethyluracil, 1.641 C 7 H 10 N 4 O 2 S Sulfaguanidine, SI. 404, 3.685 C 7 H h 0 2 Cyclohexanecarboxylate ion, 3.282 C 7 H 12 N 2 0 3 Glycylproline, 1.459, 3.423 C 7 H 12 N 2 04 S 2 Djenkolate ion(3,3'— Methylenedithiobis(2—

aminopropionate ion)), 1.409 C 7 H 12 04 Diethyl malonate, 3.311; Pimelic acid, 3.619 C 7 H 13 N 3 04 )3— Alanylglycylglycine, SI. 113; Glycylglycyl-

/3— alanine, SI. 265

C 7 H 14 N 2 0 3 Glycylvaline, 1.462, 3.426 C 7 H 14 N 2 0 3 S Glycylmethionine, 3.421 C 7 H 14 0 Cycloheptanol, 3.277—8

C 7 H l4 06 Methylgalactoside, 3.536; Methylglucoside, 3.537 C 7 H, 5 NO N,A^-Dimethylpivalamide, SI. 226, 3.339

93
C 7 H 16 0 1 — Heptanol, 3.435 C 7 H 20CoN 5 O 2

+ Benzoatopentaamminecobalt(III) ion, 2.39, 3.34 C 8 H4 N0 2 p-Cyanobenzoate ion, 1.383 C g H4 N 2 o-Dicyanobenzene, 2.213; m-Dicyanobenzene, 2.214; p—Dicyanobenzene, SI. 209, 2.215, 3.304 C g H4 0 4 " o-Phthalate ion, 1.584, 3.618, 4.93; m— Phthalate

ion, 1.585; p— Phthalate ion, 1.586, 3.690 C g H 5 0 4 o-Phthalate ion, 1.583 C 8 H 6 BrN 5-Bromoindole, 3.211 C 8 H 6 C1N 5-Chloroindole, 3.252 C 8 H 6 C10 2 2-Chloro-2-phenylacetate ion, SI. 175 C 8 H 6 N04 p-Nitrophenylacetate ion, 1.561 C 8 H 6 N 2 02 5— Nitroindole, 3.572 C 8 H 6 N 4 05 Furadantin, SI. 249, 3.387 C 8 H 6 04 Phthalic acid, SI. 379

C 8 H 7 N Indole, 1.487, SI. 289, 2.274a, 3.468; p-Tolunitrile,

1.633, 4.112 C 8 H 7 NO 5-Hydroxyindole, 3.455 C 8 H 7 NS Benzylthiocyanate, SI. 153 C 8 H 7 N 3 0 2 Luminol, 3.496 C 8 H 7 0 2 Phenylacetate ion, 1.577, SI. 372, 2.322, 3.611,

4.92; o — Toluate ion, 1.628, 4.108; m—Tol—

uate ion, 1.629, 4.109; p-Toluate ion, 1.630, 3.712, 4.110 C 8 H 7 0j p-Methoxybenzoate ion, 3.515 C 8 H 8 Styrene, 1.612,3.678

C 8 H8 IN0 3 Iodotyrosine, SI. 294

C 8 H8 N 2 5- Aminoindole, 3.164 C 8 H8 N 2 03 Nicotinuric acid, 1.549a, 3.562 C 8 H g O Acetophenone, SI. 82, 2.112, 3.134 C 8 H8 0 2 Benzyl formate, SI. 147; 2,3—Dimethylbenzoquinone,

5.52a; 2,5-Dimethyl-p— benzoquinone, 5.53; 2,6— Dimethylbenzoquinone, 5.53a; Phenyl

acetate, 2.321, 3.610; Phenylacetic

acid, 2.323, 3.612 C 8 H9 BrO 1—(p— Bromophenyl)— 1—ethanol, 3.212a

C 8 H9 C! l-Chloro-2-phenylethane, SI. 176 C 8 H9 N Indoline, 3.472 C 8 H9 NO Acetanilide, 2.106, 3.127; Phenylacetamide, 3.609 C 8 H9 N0 2 Phenylglycine, SI. 377

C 8 H 10 o—Xylene, 3.755, 4.119; m—Xylene, 3.756, 4.120; p—Xylene, 3.757, 4.121 C 8 H 10N 2 O p—Nitrosodimethylaniline, 1.564, 3.582 C 8 H 10 N 2 O3 S Sulfacetamide, 1.615a, 3.684 C g H 10O Benzyl methyl ether, 3.198a; Phenethyl alcohol, 3.605; 1-Phenylethanol, 3.615b—

C 8 H 10O 2 1,2—Dimethoxybenzene, 3.320a; 1,3— Dimethoxyben—

zene, 3.320b; 1,4— Dimethoxybenzene,

3.320c C 8 H 10O4 cis— 4—Cyclohexene— 1,2—dicarboxylic acid, 2.199 C 8H uN N,N—Dimethylaniline, 3.325; Phenethylamine, 1.574a C g H n NO 4—Ethyl-5— hydroxy—2— methylpyridine, 3.375; 2,4,6—

Trimethyl-3—hydroxypyridine, 3.728; Tyra—

mine, SI. 435, 3.740 C 8 H u N0 3 Pyridoxine, 3.657a C 8 H 12 N

+ N,N—Dimethylanilinium ion, 3.326; Phenethylammoni- um ion, 3.606 C 8 H 12 N0 2 Norpseudopelletierine N—oxyl, SI. 356, 3.586 C 8 H 12 N 2 0 2 2,4— Diethoxypyrimidine, 1.400 C 8 H 12 N 2 0 3 S 6—Aminopenicillanic acid, SI. 119 C 8 H,3 N 3 0 5 N-Acetylglycylglycylglycine, SI. 92 C 8 H 13 0 2 S 2 Lipoate ion, 1.507, SI. 298

C 8 H 14N4 O s Glycylglycylglycylglycine, 3.418 C 8 H 140 2 2,5-Dihydroxy— 2,5—dimethyl-3— hexyne, 3.319

C 8 H 14 04 Diethylsuccinate, 3.312; Suberic acid, 3.679 C 8 Hi5 N06 2-Acetamido-2—deoxy— D-galactose, SI. 76, 3.125; 2-

Acetamido— 2-deoxy-p—glucose, 3. 126; N—Acetylglucosamine, 3.138 C 8 H 15 N 5 0 4 Glycylglycylglycylglycine amide, SI. 269

C 8 H 16 CuN 2 0 4

+ Bis(2-aminobutyrato)copper(II) ion, 3.46; Bis(3-aminobutyrato)copper(II) ion, 3.47; Bis(4-aminobutyrato)copper(II) ion, 3.48; Bis(2-amino-2-methylpropionato)copper(II) ion, 3.49 C 8 H 16 N 2 0 3 Glycylisoleucine, 3.419; Glycylleucine, 1.456-7,

3.420; Leucylglycine, 1.504 C 8 H 16 N 2 04 S 2 Cystine, dimethylester, SI. 198; Homocystine,

1.470 C 8 H 18 0 1-Octanol, 3.588 C 8 H 18 0 3 Diethyleneglycol, diethyl ether, 3.309 C 8 H 18 S 2 Di-/er/-butyl disulfide, 3.301a C 8 H 19 CoN s 04 Terephthatopentaamminecobalt(III) ion, 1.74 C 8 H 26 CoNg + Bis(diethylenetriamine)cobalt(III) ion, 1.93 C 8 H 34 Co 2 N 9 0 2

+ Tetrakis(ethylenediamine)—p-amidoperoxodicobalt(III) ion, 1.94 C 8 MoN 8 Octacyanomolybdate(IV) ion, 1.176 C 9 H 3 09 Trimesate ion, 1.640 C 9 H 6 N02 Indole-2—carboxylate ion, 1.487a; Indole-3—carboxylate ion, 1.487b; Indole-5-carboxylate ion, 1.487c C 9 H6 N 2 5— Cyanoindole, 3.273 C 9 H606 1,3,5-Benzenetricarboxylic acid, 2.146 C 9 H 7 02 Cinnamate ion, 1.379 C 9 H8 NO 1—(p— Cyanophenyl)— 1—ethanol, 3.274 C 9 H 8 02 Vinyl benzoate, SI. 440

C 9 H8 0 3 p— Hydroxyphenylpropionate ion, 3.459 C 9 H9 N 1—Methylindole, 3.539; 2— Methylindole, 1.533, 3.540;

3—

Methylindole, 1.534, 3.541; 5— Methylindole,

3.542 C 9 H9 NO Cinnamamide, SI. 183; 5-MethoxyindoIe, 3.517 C 9 H9 N0 3 Hippuric acid, 2.268 C 9 H9 N0 7 2—Nitro—2—furaldehyde, diacetate, SI. 344

C 9 H9 N3 0 2 S 2 Sulfathiazole, SI. 409, 3.702 C 9 H 9 0 2 Hydrocinnamate ion, 1.471 C 9 H 9 03 p-Hydroxyphenylpropionate ion, 1.481, SI. 287, 2.270a C 9 H 10 Allylbenzene, 4.42 C 9 H 10N 2 5,6— Dimethylbenzimidazole, SI. 216

C 9 H 10O Phenylacetone, SI. 373

C 9 H 10O 2 Benzyl acetate, SI. 143; Hydrocinnamic acid, 1.472 C 9 H 10O 3 p— Hydroxyphenylpropionic acid, 2.271, 3.460 C 9 H u N0 2 Phenylalanine, 1.578, 1.579, SI. 374, 2.324,

3.613-5

C 9 H u N0 3 Tyrosine, 1.645, 1.646, SI. 436, 2.384, 3.741-5

C 9 H u N04 3—(3,4-Dihydroxyphenyl)alanine, 1.402 C 9 H u N 3 0 7 P Cytidine 2', 3'— cyclicphosphate ion, SI. 201 C 9 H 12 1,2,3— Trimethylbenzene (Hemimellitene), 3.727a, 4.115; 1,2,4-Trimethylbenzene (Pseudocumene), 3.727b,

4.116; 1,3,5— Trimethylbenzene (Mesitylene),

2.293, 3.727c, 4.117 C 9 H 12 N 2 0 Phenylalanine amide, SI. 375

C 9 H 12 N 2 0 6 Uridine, 1.652-3, 3.750 C 9 H 12 N 3 Oa P Cytidine 5'— phosphate(5'—Cytidylic acid), SI. 200, 3.293 C 9 H 12 0 1— Phenyl— 1— propanol, 3.617a; l-Phenyl-2-propanol,

3.617b; 2-Phenyl-2-propanol, 3.617c C 9 H 12 0 3 1,2,3-Trimethoxybenzene, 3.725a; 1,2,4-Trimethoxybenzene, 3.725b; 1 ,3,5-Trimethoxybenzene,

3.725c

94
C9 H,3 N2 09 P Uridine monophosphate(Uridylic acid), 1.654—6,

3.751 C 9 H 13 N3 05 Cytidine, 1.395, SI. 99, 3.292 C 9 H 14 N

+ Trimethylanilinium ion, 2.380 C 9 H 14 N 3 0 7 P Deoxycytidylic acid, 3.297 C 9 H 16 N0 2 2,2,6,6— Tetramethyl—4-piperidone N—oxyl (TAN),

SI. 412, 2.363, 3.697, 4.106 C 9 H 16 04 Azelaic acid, 3.182 C 9 H le N 2 03 Alanylleucine, 1.308; Leucylalanine, 1.503 C 10 Co2 N 10O 2 Decacyano-jz— peroxodicobalt(III) ion, 1.95 C 10 H s Os S 1,2-Naphthoquinone—2—sulfonate ion, SI. 338,

5.59; l,4-Naphthoquinone-2-sulfonate ion, SI. 339, 2.304, 5.60 C 10 H 6 NO2 Quinoline-2-carboxylate ion, 1.602a C 10 H6 O2 1,2-Naphthoquinone, 5.58 C 10 H 7 CT 1 — Naphthyloxide ion, 1.543; 2-Naphthyloxide ion, 1.544 C 10 H g Naphthalene, 1.540 C 10 H e NO2 Indole—3—acetate ion, SI. 290

C 10 H 8 N 2 2,2'-Bipyridine, 1.334, 2.156, 3.206; 4,4'-Bipyridine, 1.334a, 2.157, 3.207 C 10 H 8 O8S 2 4,5-Dihydroxy-2,7-naphthalenedisulfonic acid, 3.320 C 10 H,NO, Indole-3-acetic acid. 2.274b, 3.469; Indole5—acetic acid, 3.470 C 10 H9 N3 Dipyridylamine, 1.408c C , 0 H ,,N 1,2-Dimethylindole, 3.333; 1,3-Dimethylindole,

3.334; 2,3— Dimethylindole, 3.335 C 10 H uNO3 N—Acetylphenylglycine, SI. 95 C 10H 12 AgN 2 08 Ethylenediaminetetraacetatoargentate(I)

ion, 1.15 Cj0 H 12 A1N 2 O8 Ethylenediaminetetraacetatoaluminate(III)

ion, 1.21 C,0H 12 CdN2 O8 Ethylenediaminetetraacetatocadmate(II) ion, 1.47 C 10H 12 CeN 2 08 Ethylenediaminetetraacetatocerate(III) ion, 1.52 C 10H 12 CoN 2 08 Ethylenediaminetetraacetatocobaltate(III)

ion, 1.84 C 10H 12CoN 2 08 Ethylenediaminetetraacetatocobaltate(II)

ion, 1.60 C 10 H 12CrN 2 O8 Ethylenediaminetetraacetatochromate(III)

ion, 1.109 C 10 H 12 CuN 2 O8 Ethylenediaminetetraacetatocuprate(II) ion, 1.119, 3.50 C 10 H 12 DyN 2 08 Ethylenediaminetetraacetatodysprosate(III)

ion, 1.124 Ci0Hi2 ErN 2 O 8 Ethylenediaminetetraacetatoerbate(III) ion, 1.126 C i0 H 12 EuN 2 Og Ethylenediaminetetraacetatoeuropate(III)

ion, 1.128 Ci0 H 12 FeN 2 O8 Ethylenediaminetetraacetatoferrate(II) ion, 1.133 C,0H 12 FeN 2 O8 Ethylenediaminetetraacetatoferrate(III) ion, 1.139, 3.58 C 10 H 12 GaN 2 08 Ethylenediaminetetraacetatogallate(III) ion, 1.140 C 10H J 2 GdN2 0 8 Ethylenediaminetetraacetatogadolinate(III)

ion, 1.142 C 10 H 12 HgN2 O8 Ethylenediaminetetraacetatomercurate(II)

ion, 1.153 C 10H 12 HoN 2 08 Ethylenediaminetetraacetatoholmate(III) ion, 1.155

C 10 H 12 InN 2 O8 Ethylenediaminetetraacetatoindate(III) ion, 1.161 C 10 H I 2 LaN 2 08 Ethylenediaminetetraacetatolanthanate(III)

ion, 1.167 C 10 H 12 LuN 2 O g Ethylenediaminetetraacetatolutetate(III)

ion, 1.169 C 10 H 12 MnN 2 O 8 Ethylenediaminetetraacetatomanganate(II) ion, 1.173 C l0 H 12 N 2 Nd08 Ethylenediaminetetraacetatoneodymate(III)

ion, 1.192 C 10 H l 2 N 2 Ni0 8 Ethylenediaminetetraacetatonickelate(II) ion, 1.201, 3.88 C 10 H i 2 N 2 04 Thymine dimer, SI. 419

C,0 H 12 N 2 O s S 7-Aminocephalosporanic acid, SI. 117 C 10 H , 2 N 2 Og Orotidine, 1.567b, 3.591 C 10 H 12 N 2 08

~ Ethylenediaminetetraacetate ion, 1.420, 3.367 C

)

0 H 12 N 2 08 Pb 2 " Ethylenediaminetetraacetatoplumbate(II) ion, 1.218 C 10 H 12 N 2 08 Pr” Ethylenediaminetetraacetatopraseodymate(III)

ion, 1.224 C I0 H 12 N 2 08 Sc~ Ethylenediaminetetraacetatoscandate(III)

ion, 1.244 Ci0 H 12 N 2 O8 Sm" Ethylenediaminetetraacetatosamarate(III) ion, 1.251 C l0 H 12 N 2 08 Sn 2 ~ Ethylenediaminetetraacetatostannate(II)

ion, 1.255 C 10 H 12 N 2 O8Tb- Ethylenediaminetetraacetatoterbate(III) ion, 1.259 C 10 H 12 N 2 O8Ti- Ethylenediametetraacetatotitanate(III) ion, 1.262 C 10 H 12 N 2 O 8Tm~ Ethylenediaminetetraacetatothulate(III) ion, 1.267 C 10 H 12 N 2 O8 Y Ethylenediaminetetraacetatoyttrate(III) ion, 1.271 C 10H 12 N 2 08Yb Ethylenediaminetetraacetatoytterbate(III)

ion, 1.273 C 10 H 12 N 2 0 8Zn 2 Ethylenediaminetetraacetatozincate(II) ion, 1.280 C 10 Hj2 O a-Tetralol, 3.695a C 10 H 12 0 2 Duroquinone, 5.55b C 10 H 12 O s Propylgallate, 3.648 C 10 H l 3 N 5O4 Adenosine, 1.301, SI. 108, 2.120, 3.147 C 10 H 13 N 5O s Guanosine, 3.429 C10H14 1,2,3,4-Tetramethylbenzene (Prehnitine), 3.695a, 4.103; 1,2, 3, 5—Tetramethylbenzene (Isodurene),

3.695b, 4.104; 1,2, 4, 5—Tetramethylbenzene

(Durene), 3.695c, 4.105 C 10 H 14 N 2 O4 S Methylpenicillin, SI. 334

Ci0H 14 N 2 O 5 Thymidine, 2.373, 3.709 C 10 H 14 N 5 O6 P Deoxyadenylic acid, 3.296 C 10 H i 4N s O 7 P Deoxyguanylic acid, 3.298; Adenosine—5'— phos—

phate(Adenylic acid), 1.302, SI. 109, 2.121, 3.148 C 10 H 14 N 5 O 8 P Guanylic acid, 3.430 C 10 H 14 0 p-(/er/-Butyl)phenol, 3.236; 1—(p— Ethylphenyl)—

1—ethanol, 3.375a; 2-Methyl-l— phenyl— 1 —

propanol, 3.453c—d; 2— Methyl— 1— phenyl—2—

propanol, 3.543e; l-Phenyl-3-butanol,

3.615a C 10 H 15 N 2 O8 P Thymidylic acid, 1.626, 2.372, 3.710 C i 0 H i 6 N

+ Benzyltrimethylammonium ion, 3.201 C 10 H 16 N 2 Af, N, N'

,

A^',-Tetramethyl-p-phenylenediamine, 2.362 Ci0 H 16N 2 O 8 Ethylenediaminetetraacetic acid, 2.230, 3.368 C,0 H 17 N 3 O6 S Glutathione, reduced, 1.441, SI. 254, 2.248, 3.402

95
C 10 H 18 N 2 0 7 2-Hydroxyethylethylenediaminetriacetic acid, 3.452 C 10 H 18 0 4 Sebacic acid, 3.671 C 10 H 19 N 3 0 4 Leucylglycylglycine, 1.505, 1.506 C ,oH 20 N 2 04 S 2 Penicillamine disulfide, SI. 366, 3.597 C u H 7 N 1-Naphthonitrile, 1.545; 2-Naphthonitrile, 1.546 C U H 7 0 2 1-Naphthoate ion, 1.541, 3.556, 4.85; 2-Naphthoate

ion, 1.542, 3.557, 4.86 C U H 8 0 2 2-Methyl-l,4-naphthoquinone, (Menaquinone), SI. 333, 3.505 C U H 10 NO 2 lndole-3-propionate ion, SI. 291 C U H ,,N0 2 lndole-3-propionic acid, 2.274c, 3.471 C ,,H 12 C1N0 3 7V-(2-Chloroacetyl)phenylalanine, SI. 172 C u H 12 N 2 0 2 Tryptophan, 1.643, 1.644, S1.434, 2.382-3,

3.735-8

C n H 13 N03 7V-Acetylphenylalanine, SI. 93 C,,H 14 N 2 0 2 TV-Acetylphenylalanine amide, SI. 94

C,,H 14 N 2 0 3 Glycylphenylalanine, 1.458, SI. 270, 3.422 C ,,H 14 N 2 0 4 Glycyltyrosine, 1.461, 3.425 C1 1 Hi g Pentamethylbenzene, 3.600a, 4.89b C n H 16 0 2,2-Dimethyl-l-phenyl-l-propanol, 3.337a; 1— Methoxy

2— methyl— 1-phenylpropane, 3.517a; 2—

Methyl-4-phenyl-2-butanol, 3.543a C n H 19 N3 Os N—Acetylalanylalanylalanine, SI. 83, 3.136; N—Acetylsarcosylsarcosylsarcosine, SI. 97 C 12 H8 N 2 1,10-Phenanthroline, 1.574 C l2 H 8 0 2 Diphenoquinone, 5.55 C 12 H9 NO 2— Benzoylpyridine, SI. 140, 2.152a; 3— Benzoylpyri—

dine, SI. 141, 2.152b; 4—Benzoylpyridine,

SI. 142, 2.152c C 12 H io Biphenyl, 3.202a C 12 H 10O 2 2,3-Dimethylnaphthoquinone, 5.54a; 1—Naphthaleneacetic acid, 2.303a, 3.555 C 12H uN Diphenylamine, 3.345 C l2 H 12 AgN 2 0^ 2 Bis(nitrilotriacetato)argentate(I) ion, 1.14 C , 2 H 12 A1N 2 0^ 2 Bis(nitrilotriacetato)aluminate(III) ion, 1.20 C 12 H 12 CdN 2 0, 2 Bis(nitrilotriacetato)cadmate(II) ion, 1.46 C 12 Hj2 CoN 2 0 12

~ Bis(nitrilotriacetato)cobaltate(II) ion, 1.59a C 12 H 12 CuN 2 0

4

2 Bis(nitrilotriacetato)cuprate(II) ion, 1.118 C 12 H 12 HgN 2 0 12 Bis(nitrilotriacetato)mercurate(II) ion, 1.152 C 12 H 12 MnN 2 0

,

2 Bis(nitrilotriacetato)manganate(II) ion, 1.172 C l2 H 12 N 2 NiO: 2 Bis(nitrilotriacetato)nickelate(II) ion, 1.200 C 12 H 12 N 2 0 2 S Sulfanilamide, 1.615b C 12 H 12 N 2 0 12 Pb Bis(nitrilotriacetato)plumbate(II) ion, 1.217 C 12 H 12 N 2 0 12 Zn 4 Bis(nitrilotriacetato)zincate(II) ion, 1.282 C 12 H i 3C1 306 2,4,6— Trichlorophenyl-/3— D-glucopyranoside,

3.722 C 12 H 14 C1 2 N 2 4,4' — Dimethyl— 1,1 '—bipyridylium chloride, SI. 217, 5.53 C 12 H ls Br0 6 w-Bromophenyl-/3-D-glucopyranoside, 3.213 C 12 H 15 C10 6 m—Chlorophenyl-/3-p— glucopyranoside, 3.255; p-Chlorophenyl-/3-D—glucopyranoside,

SI. 177, 3.256 C 12 H ls NOg o-Nitrophenyl-/3-[) -glucopyranoside, SI. 353,

3.578; m-Nitrophenyl-/3-o -glucopyranoside.

3.579; p—Nitrophenyl-/3— D—glucopyranoside,

SI. 354, 3.580 C 12 H 16 N 60 3 Histidylhistidine, 1.469, 3.443 C i 2 H , 606 Phenyl-0- D-glucopyranoside, SI. 378, 2.328, 3.616 C I2 H 16 0 7 p-Hydroxyphenyl-/3- D-glucopyranoside, SI. 286, 3.458 C 12 H 18 Hexamethylbenzene, 3.438a, 4.72a C 12 H,a O 2-Methyl—5— phenyl— 2—pentanol, 3.543b

C 12 H 22 0 ,, Cellobiose, 3.244; Lactose, 3.492; Melibiose,

3.504; Sucrose, 2.356, 3.683 C 12 H 24 N 2 03 Leucylleucine, 1.507 C 12 H 2S Na04 S Dodecyl sodium sulfate, 1.409a, SI. 232,

2.221, 3.349 C 12 H 27 04 P Tributyl phosphate, 3.720a C 12 H33 ClN 3 Pd + Chloro-l,l,7,7-tetraethyldiethylenetriaminepalladium(II) ion, 1.222 C 12 H 33 ClN 3 Pt

+ Chloro— 1,1, 7, 7— tetraethyldiethylenetriamine—

platinum(II) ion, 1.227 C 13 H 8 0 Fluorenone, SI. 241, 2.235 C 13 H9 0 2 Biphenyl-4-carboxylate ion, 1.333a, 3.203, 4.50 C 13 H 9 0 3 p-Phenoxybenzoate ion, 3.608a, 4.91 C 13 H 10 O Benzophenone, 1.329, SI. 137, 2.151, 3.194 C 13 H 12 NO + 3-Benzoyl-A^— methylpyridinium ion, SI. 139 C 13 H 12 N 3 + Proflavine, 3.632a C 13 H 13 N3 05 S 2 Sulfasuccidine, SI. 408, 3.701 C 13 H 15 N06 p-Cyanophenyl-/3-D—glucopyranoside, 3.275 C 13 H 15 N 3 03 Glycyltryptophan, 1.460 Ci3 H,7 N 3 04 Glycylphenylalanylglycine, SI. 271; Phenylal—

anylglycylglycine, SI. 376

C 13 H 18 Os S p—Tolyl—S—/3 — d—thioglucopyranoside, SI. 425, 3.720 C 13 H 18 06 /8-Benzylglucoside, SI. 148, 3.198; o—Tolyl-/3— D —

glucopyranoside, SI. 422, 3.717; m—Tolyl—

/3 -d—glucopyranoside, SI. 423, 3.718; p—

Tolyl-/3-D-glycopyranoside, SI. 424, 2.376, 3.719 C 13 H 18 0 7 p—Methoxyphenyl-j8— D-glucopyranoside, 3.520 C 14H 7 O s S 9, 10-Anthraquinone— 1—sulfonate ion, SI. 124, 3.174;

9, 10- Anthraquinone—2-sulfonate ion, SI. 125,

2.132, 3.175 C 14 H804

~ 2,2'-Biphenyldicarboxylate ion (Diphenate ion), 1.408a, 3.204, 4.51; 4,4'-Biphenyldicar—

boxylate ion, 1.408a, 3.205, 4.52 C 14 H 10 Anthracene, 2.131 C 14 H 10O Anthrone, SI. 126 C 14H 10O 2 Benzil, SI. 134, 2.147 C 14 H u0 2 Diphenylacetate ion, 3.344, 4.64 C , 4 H 12 0 2 Benzoin, SI. 136 C 14 H 14C1N 3 Acriflavin, 1.298a, SI. 98, 3.141 C i4H 20O6 2,3— Dimethylphenyl-/3-D— glucopyranoside, SI. 225, 3.336; 3,4— Dimethylphenyl—/3— D-gluco—

pyranoside, 3.337 C 14 H 220 8 trans— 1,2— Cyclohexanediaminetetraacetic acid, 3.283 C 14 H 23 N 3 O 10 Diethylenetriaminepentaacetic acid, 3.310 C 15 H 902 9-Anthroate ion, 3.176, 4.46 C 15 H 14N 206 S 2 Cephalothin, SI. 169 c 15H

40 1,3— Diphenylacetone, SI. 228

Riboflavin, 1.603 C ls H 2206 2,4,5-Trimethylphenyl-/3-D-glucopyranoside,

3.729 C 15 H mN 3 0 10 Glutamylglutamylglutamic acid, SI. 253

C

,

s H 24Co08 + Tris(acetylacetonato)cobalt(III) ion, 1.98, 2.48, 3.36

96
C,6H6N 20 14 S: Indigotetrasulfonate ion, 1.486, 5.31 C 16 H 7 N 2 O u

S

3 ~ Indigotrisulfonate ion, 5.30 C,6 H 8 N 2 0 8 Sr Indigodisulfonate ion, 5.29 C 16 H 10 Pyrene, SI. 390

C 16 H 14 N 2 06 S Thalamyd, SI. 413, 3.700 C 16 H 18C1N 3 S Methylene blue, 1.528, 3.534 C 16 H 18 N 2 04 S Benzylpenicillin, SI. 150, 3.199 C 16 H 18 N 2 0 5 S Phenoxymethylpenicillin, SI. 371 C 16 H 19 N 3 04S Ampicillin, SI. 120 C

i

6 H 20 N 2 O s S Benzylpenicilloic acid, SI. 152, 3.200 C 16 H 2 ,N 3 08 S Cephalosporin C, SI. 168 C„H 18 N 2 06 S Carbenicillin, SI. 163 C 17 H 20C1N 3 Acridine orange, 1.298 C 17 H 20 N 2 O 4 S Benzylpenicillin, methyl ester, SI. 151 C 17H 20 N 2 O6S Methecillin, SI. 313

C 18 H„N s 09 S p-Sulfodiphenylpicrylhydrazyl, SI. 410

C 18 H i 4 N 3 04 S 2 Cephaloridine, SI. 167 C 18 H 2oN 2 03 Phenylalanylphenylalanine, 1.580 C 18 H 22 N 2 04 S Phenethicillin, SI. 368

C 18 H 31 02 Oleate ion, SI. 357 C 18 H 35 0 2 Stearate ion, SI. 399

C 19 H 18 C1N 3 05 S Cloxacillin, SI. 184 C I9 H 22 N 2 06 S Penamecillin, SI. 364

C 19 H42 BrN Hexadecyltrimethylammonium bromide, 1.465a, SI. 278, 2.260, 3.436 C^HjBr^jOj" Eosin (Tetrabromofluorescein), 1.410, 3.351 CjoHg^Oj” Erythrosin (Tetraiodofluorescein), SI. 233, 2.361 CjoHuO^

F

luoroscein (anion), 1.422 CjoH^Oj Fluorescein, SI. 242, 3.377 C^H 19 C1N 4 Safranine T, 1.577, 3.667, 3.668 C 20 H32 N6 0 12 S 2 Glutathione, oxidized (disulfide), 1.442, SI. 255

C jqH 6 Os N-Acetylalanylalanylalanylalanylalanylalanine,

SI. 84

C 21 H 18 Os S Cresol red, SI. 187 C 2 iH 27F06 Triamcinolone, SI. 426 ^ 21 ^ 28 ^ 7 ^ 10^2 Nicotinamide— adenine dinucleotide, 1.547,

1.548, 5.61 C 2 ]H3o0 5 Hydrocortisone, SI. 282

(^iH^CIN Hexadecylpyridinium chloride, 1.465b C23H 32 06 Hydrocortisone acetate, SI. 283

C 24 H 30F2 O6 Fluocinolone acetonide, SI. 240

C 24 H3 iF0 6 Triamcinolone acetonide, SI. 427 C^H^FO*, /3-Methazone valerate, SI. 311 ^ 28 ^3 iF*lN 2 03 Rhodamine B, SI. 392, 3.662 C^H^CoN 3 " Tris(2,2'-bipyridine)cobalt(III) ion, 1.96 ^ 3oH 24FeN^ + Tris(2,2'-bipyridine)iron(III) ion, 2.65 C 3oH 24 N 6 Rh 3+ Tris(2,2'-bipyridine)rhodium(III) ion, 1.230 C 30 H 24 N 6 Ru 2+ Tris(2,2'— bipyridine)ruthenium(II) ion, SI. 54 ^ 3oH 24 N 6 Ru 3+ Tris(2,2'-bipyridine)ruthenium(III) ion, SI. 60, 2.93a CsoH 32 N 2 0 10S Xylenol orange, SI. 443, 3.758 CjiH^Oj Vitamin K,, 5.65 C 32 H 16 CuN 80 12 S 4 Tetrasulfonated Cu phthalocyanine, 3.698 C 34 H 32 ClFeN 4 04 Hemin, 1.464a, 3.431 C 36 H 24 CoN 4

+ Tris(l,10-phenanthroline)cobalt(III) ion, 1.97 C 36 H 24FeN 3+ Tris(l,10-phenanthroline)iron(III) ion, 2.66 C^HjjCoN,* Tris(2,2',6',2"-terpyridine)cobalt(III) ion, SI. 22 CftjHooCoN 14 0 14 P Cyanocobalamin, SI. 190, 3.272a, 5.48 Cd + 3.25b Cd 2+ Cadmium (II) ion, 1.38. SI. 10, 2.19, 3.25a

CdClH 6 0 3 Chlorotriaquocadmium(II) ion, 1.40 CdH6 I0 3 Iodotriaquocadmium(II) ion, 1.41 CdH 12 N 4 Tetraamminecadmium(II) ion, 1.39 Ce3+ Cerium(III) ion, 1.51, 3.26, 4.14, 5.10 Ce 4+ Cerium(IV) ion, 2.21, 5.11 CP Chloride ion, 1.53, 2.21a, 3.27, 3.28 CICoH 1S N

2+ Chloropentaamminecobalt(III) ion, 1.66 ClCrH 15 N

2+ Chloropentaamminechromium(III) ion, 1.103, 2.49 ClFe 2+ Chloroiron(III) ion, 2.61 C1H ls N 5 Ru 2+ Chloropentaammineruthenium(III) ion, 1.233, SI. 57 ClHg Mercury(I) chloride, 3.65 CIO Hypochlorite ion, 1.54, SI. 11, 3.29, 4.15 C10 2 Chlorine dioxide, 3.32, 5.41 ClOjChlorite ion, SI. 12, 3.30, 4.16 ClOjChlorate ion, 1.55, SI. 13, 3.31, 4.17 C104 Perchlorate ion, 1.56 Cl 2 CrH 8 04 Dichlorotetraaquochromium(III) ion, 2.50

Cl 2 Fe

+ Dichloroiron(III) ion, 2.62

Cl 2 Hg Mercury(II) chloride, SI. 33

Cl 4 Pd 2 Tetrachloropalladate(II) ion, 1.220, 3.97

Cl 4 Pt

2 Tetrachloroplatinate(II) ion, 1.225, SI. 52, 3.99 Cl 6 Ir

2~ Hexachloroiridate(IV) ion, 1.164 Cl 6 Ir

3^ Hexachloroiridate(III) ion, 1.162 Cl6 Pt

2- Hexachloroplatinate(IV) ion, 1.228 Co 2+ Cobalt(II) ion, 1.57, 3.32a CoBrH 15 N

2+ Bromopentaamminecobalt(III) ion, 2.27 CoC1H 15N

2+ Chloropentaamminecobalt(III) ion, 2.26 CoFH ls N

2+ Fluoropentaamminecobalt(III) ion, 1.65, 2.25 CoH9 N606 Trinitrotrisamminecobalt(III), 2.34 CoH 15 IN 2+ Iodopentaamminecobalt(III) ion, 2.28 CoH 15N5 04P Phosphatopentaamminecobalt(III), 2.37 CoH 15 N6 02 + Nitropentaamminecobalt(III) ion, 2.33 CoH 15 N 8

+ Azidopentaamminecobalt(III) ion, 1.70, 2.31 CoH 16 N40 2

+ Diaquotetraamminecobalt(III) ion, 1.63 CoH 16 N s0

2+ Hydroxopentaamminecobalt(III) ion, 1.64, 2.24,

CoH 17 N s0

3+ Aquopentaamminecobalt(III) ion, 1.62, 2.23 CoH 18 N 4

+ Hexaamminecobalt(III) ion, 1.61, 2.22, 3.33 CoN 6 0 12

~ Hexanitrocobaltate(III) ion, 1.81 CoO 2 Cobaltate(II) ion, 1.58 Co2 H 30 N 10O 2 + Decaammine—/x— dioxodicobalt(III) ion, 1.75 Cr2+ Chromium(II) ion, 1.99, 3.37 Cr3+ Chromium(III) ion, 1.102, 3.38

Cr(V), 3.40 CrF4 ~ Hexafluorochromate(III) ion, 1.104 CrF 4 Hexafluorochromate(II) ion, 1.101 Cr0 4 Chromate(VI) ion, 1.112, 2.52 Cr 20 7 Dichromate(VI) ion, 1.113, 2.53 Cr40 12 Trichromatochromate(III) ion, 1.114 Cu\ 5.12, 5.42 Cu 2+ Copper(II) ion, 1.115, SI. 25, 2.54, 3.41, 5.13, 5.43 CuH404 Tetrahydroxocuprate(II) ion, 1.116 CuH 12 N 4 + Tetraamminecopper(II) ion, 1.120 D Deuterium atom, 1.6, SI. 4; see also part II (75—0001)

D

+ Deuteron, 1.144 DO, 1.8; see also part III, tables 2—4. D 2 Deuterium, 2.68, 3.60, 3.61 D 2 0 Deuterium oxide, 1.2 D 2 02 Deuterium peroxide, 1.147 D 2 S Deuterium sulfide, 1.235, 2.93c Dy 3+ Dysprosium(III) ion, 1.123 Er

3+ Erbium(III) ion, 1.125 Eu 2+ Europium(II) ion, 3.51 Fu 3 * Europium(III) ion, 1.127, SI. 26

97
F” Fluoride ion, 1.129, 2.55 FFe 2+ Fluoroiron(III) ion, 2.60 FH Hydrofluoric acid, 1.130 FH 6 Ni0 3 Fluorotriaquonickel(II) ion, 1.194 F2 Fe

+ Difluoroiron(III) ion, 2.60 F 2 H~, 1.131 F3 Sn Trifluorostannate(II) ion, 1.253, 2.97 F6 Fe

3 ~ Hexafluoroferrate(III) ion, 1.136 F6 S Sulfur hexafluoride, 1.237, SI. 62 F6 Si

2 ~ Hexafluorosilicate(IV) ion, 1.249 F6 Sn 2” Hexafluorostannate(IV) ion, 1.257, 2.99 F6Ti 2 ~ Hexafluorotitanate(IV) ion, 1.264 Fe

2+ Iron(II) ion, 1.132, 2.56, 3.52, 3.53, 4.18, 5.14 Fe

3+ Iron(III) ion, SI. 27, 2.57, 3.56, 5.16, 5.44 FeH 2+ Hydroiron(III) ion, 2.59 FeH0 2+ Hydroxoiron(III) ion, 2.58 Fe0 2 , 4.20 FeO 2-

, 4.20 Fe0 4 S

+ Sulfatoiron(III)ion,Sl.28

Gd 3+ Gadolinium(III) ion, 1.141 H Hydrogen atom, 1.5, SI. 3; see also part II (75-0001)

H

+

, 1.143, SI. 31, 2.67, 5.17 HN02 Nitrous acid, 2.84 HNOj Nitric acid, 3.84 HN0 7 S 2 ~ Hydroxylaminedisulfonate ion, 1.185, 3.78 HO Hydroxyl radical, 1.7, 2.3; see also part III, tables 2-4. HO Hydroxide ion, 2.90, 3.62 HOZn + Hydroxozinc(II) ion, 1.275 H02 Perhydroxyl radical, 2.4, 3.5; see also part III, table 6. H02 Hydroperoxide ion, 1.148, 3.63, 4.22 H03 P

3 Hydrogenphosphite ion, 2.91 H03 S Bisulfite ion, SI. 64, 3.104 H04P

2 Hydrogenphosphate ion, SI. 49, 2.92, 3.92, 4.31 H04S~ Bisulfate ion, 3.106 HOs S Peroxysulfate ion, 1.241, 3.108 H07 P 2 Pyrophosphate ion, SI. 50 HS Bisulfide ion, 1.236, SI. 61, 3.103 HSe Hydroselenide ion, 1.246, 3.111 H 2 , 1.145, 3.59, 4.21 H 2N Amide radical, 3.72 H 2 N03 S Sulfamate ion, 1.183 H 2 0 Water, 1.1, 4.1 H 2 0 2 Hydrogen peroxide, 1.146, SI. 32, 2.69, 3.64, 4.23,

5.18. 5.46 H 2 02 , 3.6 H 2 0 2 P Hypophosphite(III) ion, 1.209, 3.95 H 2 03 P Phosphite ion, 1.210 H 2 0 3Te Telluric(IV) acid, 3.115, 5.21 H 2 04 P Dihydrogenphosphate ion, 1.211, SI. 48, 2.91b, 3.91 H 2 0 5 S Peroxysulfuric acid, 2.95 H 2 S Hydrogen sulfide, 1.234, 3.102 H 2 Se Hydrogen selenide, 1.245, 3.110 H 3 N Ammonia, 2.80, 3.71 H 3 NO Hydroxylamine, 1.181, SI. 40, 3.74 H 3 04 P Phosphoric acid, 2.91a, 3.90 H 4 N

+ Ammonium ion, 1.178, 2.78 H 4 NO + Hydroxylammonium ion, 1.182, SI. 41, 3.75 H 4 N 2 Hydrazine, 1.179, SI. 38, 3.76

II 404Zn 2 Tetrahydroxozincate(II) ion, 1.276 H 5 N 2 Hydrazinium ion, 1.180, SI. 39, 2.79, 3.77 H 12 N 4Zn 2+ Tetraamminezinc(II) ion, 1.277 H 15 IN 5 Ru 2+ lodopentaammineruthenium(III) ion, SI. 58

H ls N 7 Ru 2+ Pentaamminenitrogenoruthenium(III) ion, 1.231a,

SI. 55, 3.301 Hi6 N 5 ORu 2+ Hydroxopentaammineruthenium(III) ion, SI. 59 H 18 IrN 8 + Hexaammineiridium(III) ion, 1.163 ^igN 6 0s 3+ Hexaammineosmium(III) ion, 1.208 H 18 N 6 Rh 3+ Hexaamminerhodium(III) ion, 1.229 H 18 N 6 Ru 3+ Hexaammineruthenium(III) ion, 1.232 Hg2+

, 2.70 Hg2 +

, 2.70a Ho 2+ Holmium(III) ion, 1.154

1 Iodide ion, SI. 34, 2.72, 3.66, 4.24 IO Hypoiodite ion, 4.25 10 3 Iodate ion, 1.158, 2.75, 3.67, 4.26 10 4 Periodate ion, 1.159, 3.68

I 2 Iodine, 1.156, SI. 35, 2.71

1 2 , 2.73

1 3 , 1.157, 2.74

In

3+ Indium(III) ion, 1.160 K

+ Potassium(I) ion, 1.165, SI. 36 La 3+ Lanthanum(III) ion, 1.166 Lu 3+ Lutetium(III) ion, 1.168 Mn 2+ Manganese(II) ion, 1.170, 2.76, 3.69 Mn04 Permanganate ion, 1.175, 2.77, 5.19 NO Nitric oxide, 1.187, 2.82, 3.80 N02 Nitrogen dioxide, 3.81 N0 2 Nitrite ion, 1.188, SI. 43, 2.85, 3.82, 4.27 N03 Nitrate ion, 1.189, SI. 44, 2.86, 3.83 N0 7 S 2 Nitrosyldisulfonate ion (Fremy's salt), 1.184, 2.87, 3.79 N 2 0 Nitrous oxide, 1.186, SI. 42, 2.83 N“ Azide ion, 1.177, 2.81, 3.73 Na + Sodium(I) ion, 1.190 Nd 3+ Neodymium(III) ion, 1.191 Ni 2+ Nickel(II) ion, 1.193, Si. 45, 2.88, 3.84a O , 1.9, SI. 5, 3.4; see also part III, table 5. OV2+ Oxyvanadium(IV) ion, 3.121 02 Oxygen, 1.205-6, SI. 47, 2.89, 4.29 Oz , 1.10, 3.7; see also part III, table 6. 02 Pb 2 Plumbate(II) ion, 1.215 0 2 Sn 2 Stannate(II) ion, 1.252 0 2 U

2+ Uranyl(VI) ion, 1.268, 2.102 03 , Ozonide ion, 4.30 Os P

3 Phosphite ion, 3.96 03 S

2~ Sulfite ion, 1.238, SI. 63, 3.105, 4.33 03 S 2 Thiosulfate ion, 1.240, SI. 65, 3.107 03 Sb Antimonate(V) ion, 1.243 03 Se

2 Selenite(IV) ion, 3.112 0 3 Sn 2 ~ Stannate(IV) ion, 1.256 0 3Te 2“ Tellurate(IV) ion, 1.260, 3.116 0 3Ti 2 Titanate(IV) ion, 1.263 0 3 V~ Vanadate(V) ion, 1.269 0 3 V

+ Oxyvanadium(VI) ion, 5.25 040s Osmium tetroxide, 5.20 04 P

3 Phosphate ion, 3.93 04 Ru 2 Ruthenate(VI) ion, 4.32 04 S

2 Sul/ate ion, 1.239 04 Se 2 Selenate ion, 1.248 04Te 2 Tellurate(VI) ion, 1.261 06 S 2 ~ Dithionate ion, SI. 67 065 3 Trithionate ion, SI. 69

06 5 4 Tetrathionate ion, SI. 70 0 7 P 2 Pyrophosphate ion, 1.212, 3.94 Og S 2 Peroxydisulfate ion, 1.242, SI. 68, 2.94, 3.109 Pb 2+ Lead(II) ion, 1.214

98
Pr(III), 1.223, SI. 51, 2.92a, 3.98 Sm 2+ Samarium(II) ion, 3.113 Sm3+ Samarium(III) ion, 1.250, SI. 71

Sn(II), 2.96, 3.114

Sn(IV), 2.98 Tb 3+ Terbium(III) ion, 1.258

Te(VI), 2.100

Th(IV), 5.22

Ti

3+ Titanium(III) ion, 3.117

Tl

+ Thallium(I) ion, 1.265, SI. 72, 2.101, 3.118, 5.23

Tm(II), 3.119 Tm 3+ Thulium(III) ion, 1.266 Y

3+ Yttrium(III) ion, 1.270

U(IV), 3.120

U(VI), 5.24 Yb 2+ Ytterbium(II) ion, 3.122 Yb3+ Ytterbium(III) ion, 1.272, SI. 73 Zn 2+ Zinc(II) ion, 1.274, SI. 74, 2.103, 3.122a

99
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FARADAY SOC. 65(563): 2981-7 (1969). 69-0531 Jezowska-Trzebiatowska, B.; Kalecinska, E.; Kalecinski, J., The rate of reaction between nitrosylpentacyanochromate(III) and hydroxyl radicals in gamma-radiolysis, BULL. ACAD. POL. SCI. SER. SCI. CHIM. 17(4): 225-31 (1969). 69-0547 Beck, G., Elektrische Leitfaehigkeitsmessungen zum

Nachweis geladener Zwischenprodukte der Pulsradiolyse, INT.

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Pulsradiolyse einfacher Merkaptane in Luft freier waessriger

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q and OH radicals with simple peptides in aqueous solution. Optical absorption spectra of intermediates. J. AMER. CHEM.

SOC. 92(16): 4763-68 (1970). 70-0104 Burchill, C.E.: Ginns, I.S.. Radiation-induced oxidation of 2-propanol by hydrogen peroxide in aqueous solutions. CAN. J. CHEM. 48: 1232-8 (1970). 70-0151 Graetzel, M.; Henglein, A.; Taniguchi, S., Pulsradiolylische

Beobachtungen ueber die Reduktion des N03 ~-ions und ueber

Bildung und Zerfall der persalpetrigen Saeure in waessriger Loesung. BER. BUNSENGES. PHYSIK. CHEM. 74(3): 292-8

(1970). 70-0165 Lilie. J.; Henglein. A., Pulsradiolytische L ntersuchung der

Oxidation von ungesaettigten Kafbonylverbindungen in waessriger Loesung: Hydratisierte Enole als Zwischenprodukte, BER. BUNSENGES. PHYSIK. CHEM. 74(4): 388-93 (1970). 70-0211 Michael, B.D.; Hart, E.J.. The rate constants of hydrated

electron, hydrogen atom, and hydroxyl radical reactions with benzene, 1.3-cyclohexadiene, 1,4-cyclohexadiene. and

cyclohexene. J. PHYS. CHEM. 74(15): 2878-84(1970). 70-0228 Graetzel. M.: Taniguchi. S.: Henglein. A., Pulsradiolytische

Untersuchung der NO-Oxydation und des Gleichgewichts N 2 03

<—»NO + N0 2 in waessriger Loesung. BER. BUNSENGES.

PHYSIK. CHEM. 74(5): 488-92 (1970). 70-0240 Badiello. R.; Fielden. E.M., Pulse radiolysis of seleniumcontaining radioprotectors: I. Selenourea. INT. J. RADIAT.

BIOL. 17(1): 1-14 (1970). 70-0241 Pruetz. W.A.; Land, E.J.. Chemiluminescent reactions after pulse radiolysis of aqueous solutions of acriflavin. Effects of halides and pseudo halides. J. PHYS. CHEM. 74(10): 2107-14

(1970). 70-0247 Behar. D.; Czapski. G.: Duchovny. I.. Carbonate radical in flash photolysis and pulse radiolysis of aqueous carbonate

solutions, J. PHYS. CHEM. 74(10): 2206-10 (1970). 70-0251 Scherz, H., Formation of deoxycompounds and

malondialdehyde in irradiated aqueous solutions of carbohydrates and related compounds. RADIAT. RES. 43(1): 12-24 (1970). 70-0253 Husain. A.; Ovadia. J.: Grossweiner, L.I., Pulse radiolysis of the eosin-human serum albumin complex. TRANS. FARADAY

SOC. 66(6): 1472-84 (1970). 70-0254 Barker, G.C.; Fowles, P.; Stringer. B., Pulse radiolytic induced transient electrical conductance in liquid solutions. Part 2. radiolysis of aqueous solutions of N03 , N02 and Fe(CN)6

3 “, TRANS. FARADAY SOC. 66(6): 1509-19(1970). 70-0302 Black, E.D.: Hayon, E.. Pulse radiolysis of phosphate anions H 2 P04 ". HP04

2 ", P043 ~, and P 2 0 7 4-

in aqueous solutions. J. PHYS. CHEM. 74(17): 3199-3203 (1970). 70-0304 Behar. D.; Czapski. G.: Rahani, J.; Dorfman, L.M.; Schwarz,

H.A., The acid dissociation constant and decay kinetics of the perhydroxyl radical. J. PHYS. CHEM. 74(17): 3209-13 (1970). 70-0338 Burchill. C.E.; Ginns. I.S.. The radiation induced oxidation of ethanol and methanol by hydrogen peroxide in aqueous

solution. CAN. J. CHEM. 48(16): 2628-32 (1970). 70-0371 Getoff, N.; Schwoerer, F., Pulsradiolytische Bestimmung von Gesehwindigkeitskonstanten der Reaklionen einiger amine mil

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Phillips. G.O.; Worthington, N.W., Effects of ionizing radiations on glucuronic acid, RADIAT. RES. 43: 34-44 (1970). Buxton, G.V., Pulse radiolysis of aqueous solutions. Rate of reaction of OH with OH". TRANS. FARADAY SOC. 66(7): 1656-60 (1970). Barker, G.C.; Fowles, P., Pulse radiolytic induced transient

electrical conductance in liquid solutions. Part 3. Radiolysis of aqueous solutions of some inorganic systems, TRANS.

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cysteine solutions at neutral pH. The role of RSSR and 02 , INT. J. RADIAT. PHYS. CHEM. 2: 159-66(1970). Behar, D.; Czapski, G., Ozonide and hydroperoxy radicals in flash photolysis of hydrogen peroxide, ISRAEL J. CHEM. 8: 699-708 (1970). Baxendale, J.H.; Breccia, A.; Ward, M.D., Pulse and

-y-radiolysis of borohydride ion in aqueous solution, INT. J. RADIAT. PHYS. CHEM. 2(4): 167-76 (1970). Micic, O.I.; Kosanic, M.M.; Nenadovic, M.T., Effect of absorbed dose on the yields of radiolytic products in neutral aqueous solutions of oxalate ion and oxygen, INT. J. RADIAT. PHYS. CHEM. 2(4): 209-16 (1970). Christie Hospital and Holt Radium Inst., Paterson

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hydrated electrons, and ionizing radiation on bacteriophage T 7 in aqueous solution, RADIAT. RES. 44: 345-58 (1970). Theard, L.M.: Peterson, F.C.; Voight, R.L., Pulse radiolysis studies of aqueous solutions of aminothiols and compounds

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Reactions of connective tissue and related polyanions with hydrated electrons and hydroxyl radicals, CARBOHYDRATE

RES. 12: 253-60 (1970). Treinin, A.; Hayon, E., Absorption spectra and reaction

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9058 Samuni, A.; Czapski, G., ESR study of a complex formation between H02 radical and peroxy-vanadium (V) ion, ISRAEL J CHEM. 8(3): 563-73 (1970).

71-

0001 Patterson, L.K.; Bansal. K.M.; Fendler, J.H., Pulse radiolytic' investigations of hydroxy-radical reactivities in micellar

solutions, CHEM. COMMUN. (3): 152-3 (1971). 71-0038 Draganic, I.G.; Draganic, Z.D.; Holroyd. R.A., Pulse radiolysis

of aqueous cyanogen solution, J. PHYS. CHEM. 75(5): 608-12

(1971). 71-0041 Getoff, N.; Schwoerer, F.; Markovic, V.M.; Sehested. k.: Nielsen, S.O., Pulse radiolysis of oxalic acid and oxalates, J. PHYS. CHEM. 75: 749 (1971). 71-0055 Phillips, G.O.; Filby, W.G.; Moore, J.S.; Davies, J.V., Radiation studies of aryl glycosides. Part II. Mechanism of radiolysis of phenyl /3-d-glucopyranoside in aqueous solution, CARBOHYDRATE RES. 16(1): 89-103 (1971). 71-0056 Phillips, G.O.; Filby, W.G.; Moore, J.S.; Davies, J.V., Radiation studies of aryl glycosides. Part 111. The reactivity of aryl glucosides towards hydroxyl radicals and hydrated

electrons. CARBOHYDRATE RES. 16(1): 105-111 (1971). 71-0061 Fielden, E.M.; Roberts, P.B., Pulse radiolysis studies of the

radiosensitizer Nor-pseudopelletierine-N-oxyl(NPPN). I. Radiation chemistry, INT. J. RADIAT. BIOL. 20(4): 355-62

(1971). 71-0067 Jooyandeh, F.; Moore, J.S.; Morgan, R.E.; Phillips, G.O.. Chemical effects of -y-irradiation of aqueous solutions of heparin and keratan sulphate. RADIAT. RES. 45(3): 455-61 (1971). 71-0081 Burchill, C.E.; Thompson, G.F., Kinetic isotope effects in the radiation-induced oxidation of alcohols by hydrogen peroxide in aqueous solution, CAN. J. CHEM. 49(8): 1305-9 (1971). 71-0128 Phillips, G.O.; Power, DM.: Sewart, M., Effects of

•y-irradiation on sodium sulphacetamide, RADIAT. RES. 46(2): 236-50 (1971). 71-0137 Zehavi, D.; Rabani, J., Pulse radiolytic investigation of O a radical ions, J. PHYS. CHEM. 75(11): 1738-44 ( 1971 ). 71-0145 Simic, M.; Hayon. E., I npubl. data. 71-0158 Land, E.J.; Swallow, A.J., One-electron reactions in biochemical systems as studied by pulse radiolysis. IY

r

. Oxidation of dihydronicotinamide-adenine dinucleotide, BIOCHIM. BIOPIIYS. ACTA 234: 34-42 ( 1971 ). 71-0174 Meyerstein, D., Trivalent copper. I. A pulse radiolytic study of the chemical properties of the aquo complex. INORG. CHEM.

10(3): 638-41 (1971). 71-0175 Jayson. G.G.; Stirling. D.A.; Swallow. A.J.. Pulse- and

X-radiolysis of 2-mercaptoethanol in aqueous solution, INT. J. RADIAT. BIOL. 19(2): 143-56 (1971). 71-0202 Bhattacharyya, S.N.; Kundu, K.P., The radiation chemistry of aqueous solutions of ferric elhylenediamine tetraacetate, INT.

J. RADIAT. PHYS. CHEM. 3(1): 1-10(1971). 71-0234 Baxendale, J.H.; Mulazzani, Q.C., A study of the oxidation and reduction of Ru(NH 3 ) 5 N 2 2+ by y- and electron pulse

radiolysis, J. INORG. NIICL. CHEM. 33(3): 823-30(1971). 71-0274 Barat, F.; Cilles, L.; Hickel, B.; Lesigne, B . Transient

species in the pulse radiolysis of periodate ion in neutral aqueous solutions, CHEM. COMMUN. (15): 847-8 (1971). 71-0282 Cohen, H.; Meyerstein, I)., Oxidation of benzoatopentaammineeobalt(III) by hydroxyl radicals. J. AMER. CHEM.

SOC. 9.3(17): 4179-83 (1971). 71-0311 Faraggi, M.; be der. A.; Tendler. Y.. Pulse radiolysis of lanthanides. Aqueous solutions, Proc. of the 9th Rare Earth

Res. Conf. Vol. II., Sessions l-N, Virginia Polytech Inst, and

State Univ., Blacksburg, Va., Oct. 10-14. 1971. p. 560-72.

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Land, E.J.; Swallow, A.J., One-electron reactions in biochemical systems as studied by pulse radiolysis. V. Cytochrome c, ARCH. BIOCHEM. BIOPHYS. 145: 365-72

(1971). Barat, F.; Gilles, L.; Hickel. B.; Lesigne, B., Transient

species in the pulse radiolysis of periodate ion in neutral aqueous solution, BER. BUNSENGES. PHYSIK. CHEM. 75(7): 636 (1971).

Lilie, J., Pulsradiolytische Untersuchung der oxydativen

Ringoeffnung von Furan, Thiophen und Pyrrol, Z. NATURFORSCH. PT. B 26(3): 197-202 (1971). Jezowska-Trzebiatowska, B.; Kalecinska, E.; Kalecinski, J., On the reactivity of pentacyanonitrosyl ions of transition elements towards hydrated electrons and hydroxyl radicals, BULL. ACAD. POL. SCI. SER. SCI. CHIM. 19(4): 265-75

(1971). Hayon, E.; Ibata, T.; Lichtin, N.N.; Simic, M., Sites of attack

of hydroxyl radicals on amides in aqueous solution. II. The

effects of branching a to carbonyl and to nitrogen, J. AMER.

CHEM. SOC. 93(21): 5388-94 (1971). Gupta, B.L.; Hart, E.J., Radiation chemistry of some

sulfonephthalein dyes, RAD1AT. RES. 48(1): 8-19 (1971). Zagorski, Z.P.; Sehested, K.; Nielsen, S.O., Pulse radiolysis

of aqueous alkaline sulfite solutions, J. PHYS. CHEM. 75(23): 3510-7 (1971). Kules, L; Schiller, R., The kinetics of OH radical reactions in irradiated ordinary and supercooled water, Proc. of the Third Tihany Symposium on Radiation Chemistry, May 10-15, 1971,

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Vol. 2, p.1163-72.

Fel', N.S.; Nedoborova, L.I.; Kudryashov, L.I.; Dolin, P.I.; Kochetkov, N.K., Radiolysis of aqueous solutions of aromatic

glucosides, HIGH ENERGY CHEM. 5(3): 215-20 (1971), Transl. from Khim. Vys. Energ. 5: 241 (1971). Simic, M.; Hayon, E., Intermediates produced from the oneelectron oxidation and reduction of hydroxylamines. Acid-base

properties of the amino, hydroxyamino, and methoxyamino

radicals, J. AM. CHEM. SOC. 93(23): 5982-6 (1971). Ohno, S.-I.; Sasaki, T., Polarographic study of the X-ray- induced reduction of uranyl ions in aqueous solution, RADIOISOTOPES (TOKYO) 20(5): 211-6 (1971). Hayon, E.; Simic, M., Pulse radiolysis study of cyclic peptides

in aqueous solution. Absorption spectrum of the peptide radical NHCHCO-, J. AMER. CHEM. SOC. 93(25): 6781-6(1971). Iddon, B.; Phillips, G.O.; Robbins, K.E.; Davies, J.V., Radiation chemistry of aqueous solutions of indole and its derivatives, J. CHEM. SOC. PT. B (10): 1887-92 (1971). Willson, R.L.; Greenstock, C.L.; Adams, G.E.; Wageman, R.; Dorfman, L.M., The standardization of hydroxyl radical rate data from radiation chemistry, 1NT. J. RADIAT. PHYS.

CHEM. 3(3): 211-20 (1971). Simic, M.; Ebert, M., Pulse radiolysis of aqueous solutions of carboxy, carbamido and pyridyl derivatives of pyridine, INT. J. RADIAT. PHYS. CHEM. 3(3): 259-72 (1971). Simic, M.; Neta, P.; Hayon, E., Pulse radiolytic inveslijation

of aliphatic amines in aqueous solution, INT. J. RADIAT. PHYS. CHEM. 3(3): 309-20 (1971). Bansal, K.M.; Patterson, L.K.; Fendler, E.J.; Fendler, J.H., Reactions of hydrated electrons, hydrogen atoms and hydroxyl

radicals in micellar systems, INT. J. RADIAT. PHYS. CHEM.

3(3): 321-31 (1971). Clay, P.G.; Rashid, M., The radiolysis of aqueous solutions of triethylamine and related amines, INT. J. RADIAT. PHYS.

CHEM. 3(3): 367-76 (1971).

71-0595 Getoff, N.; Schwoerer, F., Pulsradiolyse von Melhylamin in waesseriger Loesung, INT. J. RADIAT. PHYS. CHEM. 3(3): 429-39 (1971). 71-0596 Mantaka, A.E.; Marketos, D.G.: Rakintzis, N.Th.; Stein. G.. On the yield of oxidizing radicals in the radiolysis of aqueous

solutions. Solutions of H0N(S03 ) 2

2 ~. at pH 11, INT. J. RADIAT. PHYS. CHEM. 3(3): 441-5(1971). 71-0618 Willson, R.L., Pulse radiolysis studies on reaction of triacetoneamine-N-oxyL with radiation-induced free radicals, TRANS. FARADAY SOC. 67(10): 3008-19 (1971). 71-0619 Willson, R.L., Pulse radiolysis studies of electron transfer in aqueous quinone solutions, TRANS. FARADAY SOC. 67(10): 3020-9 (1971). 71-0645 Lichtin, N.N., Selectivity in fast reactions of aqueous OHradicals with amides. ISRAEL J. CHEM. 9(3): 397-403 (1971). 71-0682 Ohno, S.; Sakumoto, A.; Sasaki, T.; Kawatsura, K.; Furukawa, K., Measurements of optical absorption spectra under Co-y irradiation. Aqueous methylene blue solutions containing oxygen, BULL. CHEM. SOC. JAPAN 44(12): 3265-8

(1971). 71-0709 Koester, R.; Asmus, K.-D., Die Reaktionen chlorierter Aethylene mit hydratisierten Elektronen und OH-Radikalen in waessriger Loesung, Z. NATURFORSCH. PT. B 26(11): 1 1 OS- 16 (1971). 71-0710 Schoeneshoefer. M., Pulse radiolysis of the trop> lium-ion. tropylcarbinol and tropilidene in aqueous solution, Z. NATURFORSCH. PT. B 26(11): 1120-4(1971). 71-0775 Meyerstein, D., Trivalent copper. II. A pulse radiolytic study

of the formation and decomposition of amino complexes,

INORG. CHEM. 10(10): 2244-9 (1971). 71-0927 Natroshvili, G.R.; Panchvidze, N.V.; Nanobashvili, H.M..

Radiation oxidation of bivalent sulfur in aqueous solutions, Proc. of the Third Tihany Symposium on Radiation Chemistry,

Vol. 2, J. Dobo and P. Hedvig (eds.), Akademiai Kiado,

Budapest, Hungary, 1972, p. 1281-91. 71-0930 Nilsson, K.; Pagsberg, P., The reduction of ferricytochrome C

to ferrocytochrome C studied by pulse radiolysis. Ibid., p. 13 II7. 71-0931 Kosanic, M.M.; Draganic, I.G., Correlation between the yields

of primary H 2 0 2 in water y-radiolysis and the halide ion

reactivities (pH 0.5 - 6.0), Ibid., p. 1319-32. 71-3069 Masuda, T.; Ovadia, J.; Grossweiner, L.I.. The pulse

radiolysis and inactivation of trypsin, INT. J. RADIAT. BIOL.

20(5): 447-59 (1971). 71-7236 Barat, F.; Gilles, L.: Hickel, B.; Lesigne, B., Flash photolysis

of chlorate ion in aqueous solution, J. PHYS. CHEM. 75(14): 2177-81 (1971). 71-9132 Walling, C.; Kato, S., The oxidation of alcohols by Fenton's

reagent. The effect of copper ion, J. AMER. CHEM. SOC.

93(17): 4275-81 (1971).

71-

9316 Baxendale, J.H.; Ward, M.D.; Wardman, P., Heats of ionization of H0 2 and OH in aqueous solution, TRANS.

FARADAY SOC. 67(9): 2532-7 (1971).

72-

0003 Hayon, E.; Simic, M., Intermediates produced from the oneelectron oxidation of hydrazine. Evidence for the formation and decay of tetrazane and triazene, J. AMER. CHEM. SOC. 94(1): 42-7 (1972). 72-0017 Barat, F.; Gilles, L.; Hickel, B.; Lesigne, B., Pulsed radiolysis and flash photolysis of iodates in aqueous solution, J. PHYS.

CHEM. 76(3): 302-7 (1972). 72-0018 Zehavi, D.; Rabani. J., The oxidation of aqueous bromide ions. by hydroxyl radicals. A pulse radiolytic investigation. J. PHYS. CHEM. 76(3): 312-9 (1972). 72-0047 Neta. P.; Hoffman, M.Z.; Simic, M., Electron spin resonance

108
and pulse radiolysis studies of the reactions of OH and O

radicals with aromatic and olefinic compounds. J. PHYS.

CHEM. 76(6): 847-53 (1972). 72-0049 Patterson, L.K.; Bansal. K.M., Pulse radiolysis studies of 5-halouracils in aqueous solutions, J. PHYS. CHEM. 76(17): 2392-9 (1972). 72-0056 Bhattacharyya, S.N.; kundu. K.P.. X-Irradiation of aqueous

solutions of ethylenediamine tetraacetic acid (EDTA), INT. J. RADIAT. PHYS. CHEM. 4(1): 31-41 (1972). 72-0066 Faraggi, M.; Feder, A., Pulse radiolysis studies in lanthanide aqueous solutions. II. Formation, spectrum, and some chemical

properties of praseodymium(IV) in aqueous solution, J. CHEM.

PHYS. 56(7): 3294-7 (1972). 72-0094 Matthews, R.W.; Mahlman, H.A.; Sworski, T.J., Elementary

processes in the radiolysis of aqueous sulfuric acid solutions. Determinations of both G 0H and G S04 -, J. PHYS. CHEM. 76(9): 1265-72 (1972). 72-0109. Pagsberg, P.B., Investigation of the NH2 radical produced by

pulse radiolysis of ammonia in aqueous solution, RISO-256,

Jan., 1972, p.209-21. (Danish Atomic Energy Commission Res.

Establishment). 72-0122 Ellison, D.H.; Salmon, G.A.; Wilkinson, F., Nanosecond pulse

radiolysis of methanolic and aqueous solutions of readily oxidizable solutes, PROC. ROY. SOC. LONDON SER. A

328(1572): 23-36 (1972). 72-0126 Behar, D.; Bevan, P.L.T.; Scholes, G., Pulse radiolysis of aqueous thiocyanate solutions. Nature of the intermediate

transient species, J. PHYS. CHEM. 76(11): 1537-42 (1972). 72-0144 Hayon, E.; Simic. M., Radiation sensitization reactions of N-ethylmaleimide with model compounds, RADIAT. RES.

50(3): 464-78 (1972). 72-0148 Behar. D., Pulse radiolysis studies on Br in aqueous solution: the mechanism of Br 2 ~ formation, J. PHYS. CHEM. 76(13): 1815-8 (1972). 72-0167 Burchill, C.E.; Wollner, G.P., Radiation-induced oxidation of 2-propanol by nitrous oxide in alkaline aqueous solution, CAN.

J. CHEM. 50(11): 1751-6 (1972). 72-0169 Bibler, N.E., Gamma and alpha radiolysis of aqueous solutions

of diethylenetriaminepentaacetic acid, J. INORG. NUCL.

CHEM. 34(4): 1417-25 (1972). 72-0173 Bhattacharyya, S.N.; kundu, k.P., On the radiolysis of aqueous solutions of nickel (II) ethylenediamine tetraacetate, RADIAT. RES. 51(1): 45-55 (1972). 72-0240 Samuni, A.; Meisel, D.; Czapski, G., The kinetics of the oxidation of chromium(II), titanium(III), and vanadium(IV) by

hydrogen peroxide and hydroxyl radicals, J. CHEM. SOC. DALTON TRANS.: 1273-7 (1972). 72-0263 Matthews, R.W.; Mahlman, H.A.; Sworski, T.J., Elementary

processes in the radiolysis of aqueous nitric acid solutions: Determination of both G(OH) and G(N() 3

), J. PHYS. CHEM.

76(19): 2680-4 (1972). 72-0266 Sehoeneshoefer, M., Pulsradiolytisehe Ilntersuchung zur Oxidation der Ascorbinsaeure (lurch OIl-Radikalc und HalogcnRadikal-komplexe in waessriger Loesung, Z. N A TURFORSCH.

PT. B 27(6): 649-59 (1972). 72-0289 Christensen, H., Pulse radiolysis of aqueous solutions of aniline and substituted anilines, INT. J. RADIAT. PHYS.

CHEM. 4(3): 311-33 (1972). 72-0301 Buxton, G.V.; Subhani, M.S.. Radiation chemistry and

photochemistry of oxyehlorinc ions. Part I Radiolysis of aqueous solutions of hypochlorite and chlorite ions, j. CHEM.

SOC. FARADAY TRANS. I 08(5): 947-57 (1972). 72-0308 Sutton, H.C.; Downes, M.T., Reactions of the H() 2 radical in

aqueous solution with bromine and related compounds, J. CHEM. SOC. FARADAY TRANS. I 68(8): 1498-507 (1972). 72-0354 Jayson, G.G.; Parsons, B.J.; Swallow, A.J., Oxidation of ferrous ions by hydroxyl radicals, J. CHEM. SOC. FARADAY

TRANS. I 68: 2053-8 (1972). 72-0391 Hulme, B E.; Land, E.J.; Phillips, G.O., Pulse radiolysis of

9, 10-anthraquinones. Part 1. Radicals, J. CHEM. SOC. FARADAY TRANS. I 68(10): 1992-2002 (1972). 72-0404 Schmidt, k.H, Electrical conductivity techniques for studying

the kinetics of radiation-induced chemical reactions in aqueous

solutions, INT. J. RADIAT. PHYS. CHEM. 4(4): 439-68 (1972). 72-0425 Basinski, A.; Lerke, G., Reactivity of certain aromatic compounds with respect to the OH radical, BULL. ACAD.

POL. SCI. SER. SCI. CHIM. 20(4): 319-22 (1972). 72-0431 Zehavi, D.; Rabani, J., Pulse radiolysis of the aqueous ferro- ferricyanide system. L The reactions of OH, HOz , and 02 radicals, J. PHYS. CHEM. 76(25): 3703-9 (1972). 72-0445 Stevens, G.C.; Clarke, R.M.; Hart, E.J., Radiolysis of aqueous methane solutions, J. PHYS. CHEM. 76(25): 3863-7 (1972). 72-0460 Lati, J.; Meyerstein, D.. Trivalent nickel. I. A pulse radiolytic study of the formation and decomposition of the ammoniacal

complex in aqueous solution, INORG. CHEM. 11(10): 2393-7

(1972). 72-0461 Lati, J.; Meyerstein, D., Trivalent nickel. II. A pulse radiolytic study of the formation and decomposition of the ethylenediamine and glycine complexes in aqueous solution, INORG. CHEM. 11(10): 2397-401 (1972). 72-0541 Shetiya, R.S.; Rao, E.N.; Shankar, J., Determination of rate constants for the reactions of H, OH and e aq with indole-3- acetic acid and other plant hormones, RADIAT. EFF. 14(3-4): 185-9 (1972). 72-0584 Lati, J.; Meyerstein, D., Comments on the nature of the oxidized form of the nickel dimethylglyoxime complex, ISRAEL

J. CHEM. 10(3): 735-8 (1972). 72-0837 Savel'eva, O.S.; Shevchuk, L.G.; Vysotskaya, N.A., Reactions

of substituted phenols with hydroxyl radicals and their dissociated form O , J. ORG. CHEM. USSR 8(2): 283-6 (1972), Translated from Zh. Org. khim.

72-1002 Nilsson, E., The reduction of ferricytochrome c studied by

pulse radiolysis, ISRAEL J. CHEM. 10(6): 1011-9 (1972). 72-1007 Rabani, J.; klug, D.; Fridovich, I.. Decay of the H0 2 and 02 radicals catalyzed by superoxide dismutase. A pulse radiolytic investigation, ISRAEL J. CHEM. 10(6): 1095-1106(1972). 72-3003 Nucifora, G.; Smaller, B.; Remko, R.; Avery, E.C., Transient

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78(23): 2330-4 (1974). 74-1135 Willson, R.L.; Gilbert, B.C.; Marshall. P.D.R.; Norman.

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(1974). Snook, M.E.; Hamilton, G.A., Oxidation and fragmentation of some phenyl-substituted alcohois and ethers by peroxydisulfate and Fenton's reagent, J. AMER. CHEM. SOC. 96(3): 860-9

(1974). Anbar, M.; Farhataziz; Ross, A.B., Selected specific rales of reactions of transients from water in aqueous solution. II. Hydrogen atom, NSRDS-NBS 51, 1975. 56p. (U.S. Govt.

Printing Office, Washington, D.C.). Ross, A.B., Selected specific rates of reactions of transients from water in aqueous solution. I. Hydrated electron. Supplemental data, NSRDS-NBS 43-Supp., 1975, 43p. (U.S. Govt. Printing Office, Washington, D.C.). Kundu, K.P.; Matsuura. N., Gamma-radiolysis of ferric ethylene diamine tetra acetate in neutral aqueous solution, INT. J. RADIAT. P11YS. CHEM. 7: 565-71 (1975). Masuda, T.; Shinohara, H.; Kondo, M., Reactions of hydroxyl

radicals with nucleic acid bases and the related compounds in gamma-irradiated aqueous solution, J. RADIAT. RES. 16(3): 153-61 (1975). Venturi, M.; Breccia, A.; Mulazzani, Q.G.; Ward, M.D.,

Radiolysis of the pentaammine-(dinitrogen)osmium(2+) ion in aqueous solution, ATTI ACCAD. NAZ. LINCEI, CL. SCI.

FIS., MAT. NAT., REND. 56(3): .366-71 (1975). Neta, P.; Schuler, R.H., Oxidation of phenol to phenoxyl

radical by O . J. AM. CHEM. SOC. 97(4): 912-3 (1975). Neta, P.; Schuler, RTF, The reactivity of O toward aromatic compounds, RADIAT. RES. 64(2): 233-6 (1975). Neta, P.; Schuler, R.H., Rale constants for the reaction of O

-

radicals with organic substrates in aqueous solution, J. PHYS.

CHEM. 79(1): 1-6 (1975). Rao, P.S.; Hayon, E., Reaction of hydroxyl radicals with oligopeptides in aqueous solutions. A pulse radiolysis study, J. PHYS. CHEM. 79(2): 109-15 (1975). Sehested, K.; Corfitzen. H.; Christensen, H.C.; Hart, E.J.. Rates of reaction of O--

. OH and H with methylated benzenes

in aqueous solution. Optical spectra of radicals, J. PHYS.

CHEM. 79(4): 310-5 (1975). Simie, M.G.; Taub, I. A.; Toeei, J.: Hurwitz, P.A., free

radical reduction of ferrieytoehrome-C, BIOCHEM. BIOPHYS.

RES. COMMllN. 62(2): 161-7 (1975). Getoff, N.; Sehwoerer, F.. Pulse radiolysis of pyrrolidine (C 4 H a NH) in aqueous solution, INT. .). RADIAT. PHYS. CHEM. 7(1): 47-9 (1975). Moorthy, P.N.; Hayon, E., One-electron redox reactions of water-soluble vitamins. 111. Pyridoxine and pyridoxal phosphate

(Vitamin B 6 ), J. AMER. CHEM. SOC. 97(8): 2048-52 (1975). Buxton, G.V.; Sellers, R.M., Pulse radiolysis study of monovalent cadmium, cobalt, nickel and zinc in aqueous

solution. Part 1. Formation and decay of the monovalent ions,

J. CHEM. SOC. FARADY TRANS. I 71(3): 558-67 (1975).

Bell, J.A.; Grunwald, E.; Hayon, E., Kinetics of deprotonation

of organic free radicals in water. Reaction of HOCHCOj , HOCHCONHj, and HOCCH 3 CONH 2 with various bases, J. AMER. CHEM. SOC. 97(11): 2995-3000 ( 1975).

75-1064 Kelm, M.; Lilie, J.; Henglein, A., Pulse radiolytic investigation

of the reduction of eadmium(II) ions, J. CHEM. SOC. FARADAY TRANS. I 71(5): 1132-42(1975). 75-1066 Rao, P.S.; Simie, M.; Hayon, E., Pulse radiolysis study of imidazole and histidine in water, J. PHYS. CHEM. 79(1.3): 1260-3 (1975). 75-1067 Whillans, D.W.; Adams, G.E., Electron-affinic sensitization. VI. A pulse radiolysis and esr comparison of some 2- and

5-nitroimidazoles, RADIAT. RES. 62: 407-21 (1975). 75-1072 Lind, J.; Eriksen, T.E., Pulse radiolysis of methane sulphonic

acid, RADIOCHEM. RADIOANAL. LETT. 21(3-4): 177-81

(1975). 75-1087 Greenstock. C.L.; Miller, R.W., The oxidation of tiron by

superoxide ion: kinetics of the reaction in aqueous solution and

in chloroplasts, BIOCHEM. BIOPHYS. ACTA 396(1): 11-6

(1975). 75-1088 HoTfman, M.Z.; Kimmel, D.W., Induced electron transfer in the reaction of hydroxyl radicals with pyridinepentaamminecobalt(III) ion in aqueous solution, J. CHEM. SOC. CHEM. COMMUN. (14): 549-50 (1975). 75-1089 Bonifacic, M.; Schaefer, K.; Moeckel, IT; Asmus, K.D.,

Primary steps in the reactions of organic disulfides with hydroxyl radicals in aqueous solution, J. PHYS. CHEM. 79(15): 1496-502 (1975). 75-1096 Sehested, K.; Hart, E.J., Formation and decay of the biphenyl

cation radical in aqueous acidic solution, J. PHYS. CHEM.

79(16): 1639-42 (1975). 75-1099 Semerano, G., Flash photolysis and pulse radiolysis in coordination chemistry, COORDINATION CHEM. REVS.

16(1/2): 185-94 (1975). 75-1125 Brede, O.; Helmstreil, W.; Mehnert, R., Pulsradiolyse von Benzophenon in waessriger Loesung, Z. PHYS. CHEM.

(LEIPZIG) 256(3): 513-21 (1975). 75-1126 Matsushige, T.; Koltzenburg, G.; Schulte-Frohlinde, D., Pulse

radiolysis of aqueous solutions of acetic acid 2-hydroxyethyl

ester. Fast elimination of acetic acid from a primary radical, BER. BUNSENGES. PHYSIK. CHEM. 79(8): 657-61 (1975). 75-1171 O'Neill, P.; Steenken, S.; Schulte-Frohlinde, D., Formation of radical cations of methoxylated benzenes by reaction with OH

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(1975). 75-3051 van Hemmen, J.J.; Meuling, W.J.A., Inactivation of biologically active DNA by y-ray-induced superoxide radicals and their dismutation products singlet molecular oxygen and hydrogen peroxide, BIOCHIM. BIOPHYS. ACTA 402: 1.33-41 (1975). 75-3058 Felieioli, R.; Montagnoli, G.; Monti, S.; Moore, J.S.; Phillips, G.O.; Sosnowski, A., Radiation inactivation of rabbit muscle

aldolase, INT. J. RADIAT. BIOL., 27(6): 525-32 (1975). 75-3093 Butler. J.; Jayson, G.G.; Swallow, A.J., The reaction between

the superoxide anion radical and cytochrome e, BIOCHIM.

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113
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Selected Specific Rates of Reactions of Transients from Water

in Aqueous Solution. III. Hydroxyl Radical and Perhydroxyl

Radical and their Radical Ions

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Rates of reactions of OH and HCL with organic and inorganic molecules, ions, and

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