## Exhaust Emissions Sampling Daltile, Muskogee, OK Kiln #l, Kiln #2, Trim Kiln, Scrubber Exhaust

April 21 - 22, 2005 Armstrong Environmental, Inc. Project W-2457-05

Report Prepared For: Bob Hurt Daltile 7834 C. F. Hawn Freeway Dallas, TX 75217

Report Prepared May 2, 2005 By: ArmstYong Environmental, Inc. 

## 7715 Sovereign Row Dallas, Texas 75247 (214) 631-0021

## I. INTRODUCTION

A series of tests was performed on the exhausts associated with Kiln #l, Ki1n #2, Trim Kiln, and the Scrubber at the Daltile facility in Muskogee, OK on April 21 - 22, 2005. The purpose of this test series was to determine the exhaust emission rate of PM, Hydrogen Fluoride, Hydrogen Chloride and Chlorine in terms of lbs/hr. Testing followed procedures detailed in Title 40: Code of Federal Regulations (40:CFR). Sampling was performed by Richard Taylor, Dan Barrera and Tom Armstrong of Armstrong Enviromnental, Inc. using two Apex Method 5 sampling trains. Three one hour test repetitions were performed on each source according to the following schedule:
Source Date Start Time Finish Time 

## Kiln #1 4/21/05 9:00 AM 1:02 PM Kiln #2 4/21/05 9:00 AM 1:03 PM Trim Kiln 4/21/05 2:35 PM 6:41 PM Scrubber 4/21/05 2:35 PM 3:36 PM Scrubber 4/22/05 8:15 AM 10:42 AM Submitted by:


# I

1

## II. SUMMARY

A series of tests was performed on the exhausts associated wit11 Kiln 91, Kiln #2, the Trim Kiln, and the Scrubber at the Daltile facility in Muskogee, OK on Apri121 - 22, 2005. Sampling was performed following procedures detailed in Title 40: Code of Federal Regulations.
Results of this test series are summarized in Tables 1- 4 Results indicate the following emission rates for Kiln #1:

Run # 

## 1 2 3 Avera e PM, lbs/hr 1.398 1.387 1.135 1.307 HF, lbs/hr 4.507 3.872 4.222 4.200 HCI, Ibs/hr 4.367 3.714 4.237 4.106 C12, lbs/hr 0.212 0.290 0.333 0.278 Results indicate the following emission rates for Kiln 42:

Run # 

## 1 2 3 AveraQe PM, lbs/hr 1.276 1.148 1.113 1.179 HF, lbs/hr 3.893 3.695 3.909 3.834 HCl, lbs/hr 4.306 3.840 4.349 4.165 C12, Ibs/hr 0.324 " 

## 0.413 0.331 0.356 Results indicate the following emission rates for the Trim Kiln:

Run # 

## 1 2 3 Avera 

## e PM, lbs/hr 1.009 1.135 0.723 0.956 HF, lbs/hr 1.639 1.635 1.291 1.522 HCl, lbs/hr 1.463 1.504 1.344 1.437 C12, lbs/hr 0.130 0.125 0.111 0.122 Results indicate the following emission rates for the Scrubber:

Run # 

## 1 2 3 Avera 

## e PM, lbs/hr 7.489 11.473 18.024 12.329 HF, Ibs/hr 0.118 0.120 0.087 0.108 HCI, lbs/hr 0.096 0.107 0.065 0.089 C12, lbs/hr 0.195 0.219 0.188 0.201

®0 1

579.6 44.10 21948.2 9807.4 588443 10.41 J o 4.00 16.00

10:30 AM 11:32 AM 36.179 101.7204

31.30 0.013349 1.122537

7.37 0.003143 0.264316
1.386853 3

581.0 45.28 22535.6 10082.5 604952 10.17 J 4.00 16.00

12:00 PM 1:02 PM 37.127 101.5383

30.09 0.012505 1.081077

1.50 0.000623 0.053892
1.134969

107.97 117.50 126.737 134.406 3.872142 4.22166 SUMMARY OF EMISSIONS TEST DATA ~

Table : 1 Plant : Daltile, Muskogee, OK Location : Kiln #1 Operator : R. Taylor Test Date : 21-Apr-05 Repetition : 1
STACK GAS Temperature, F 571.5 Velocity, fps 45.24 Volume Flow, acfm 22519.4

scfm 10134.0 scfh 608038 Moisture, % 10.48 0 CO2,

~ ' / o 3.00 02, % 17.00


### SAMPLE Start Time, hrs:min 9:00 AM Finish Time, hrs:min 10:01 AM Sample Volume, scf 35.762 Isokinetic Ratio, % 97.30843
PARTICULATE Front Half 

### Sample Weight, mg 31.47 Concentration, gr/scf 0.013578 Emissions, Ibs/hr 1.179806
Back Half 

### Sample Weight, mg Concentration, gr/scf Emissions, Ibs/hr
Total Particulate, Ibs/hr
HYDROGEN FLUORIDE 

### Sample Weight, mg Concentration, ppm Emissions, Ibs/hr 5.82 0.002511 0.218191
1.397997

120.22 142.758 4.506871

~ CHLORINE



### Sample Weight, mg Concentration, ppm Emissions, Ibs/hr 5.65 1.889154 0.211724 8.10 2.678335 0.290497 9.28 2.990126 0.333413
HYDROGEN CHLORIDE 

### Sample Weight, mg 116.49 103.55 117.93 Concentration, ppm 75.79956 66.60023 73.9137 Emissions, Ibs/hr 4.36721 3.713527 4.23694



## F25.48 26.64 0.009106 0.009588 0.944871 0.982419

5.47 3.55 0.001955 0.001278 0.202843 0.130915
1.147715 1.113334 SUMMARY OF EMISSIONS TEST DATA
Table : 2 Plant : Daltile, Muskogee, OK Location : Kiln #2 

### Operator : T. Armstrong Test Date : 21-Apr-05 Repetition : 1 

### STACK GAS Temperature, F 539.5 Velocity, fps 50.62 Volume Flow, acfm 25196.7

scfm 11859.0 scfh 711541 Moisture, % 9.28% CO2, % 3.00 02,

~ " / 0 17.00
SAMPLE Start Time, hrs:min 9:00 AM Finish Time, hrs:min 10:02 AM Sample Volume, scf 42.446 Isokinetic Ratio, % 99.08614
PARTICULATE Front Half 

### Sample Weight, mg 22.08 Concentration, gr/scf 0.008027 Emissions, Ibs/hr 0.816149
Back Half 

### Sample Weight, mg 12.45 Concentration, gr/scf 0.004526 Emissions, Ibs/hr 0.460193
Total Particulate, Ibs/hr 1.276341
HYDROGEN FLUORIDE Sample Weight, mg 105.31 Concentration, ppm 105.3681 Emissions, Ibs/hr 3.892719
CHLORINE Sample Weight, mg 8.76 Concentration, ppm 2.468188 Emissions, Ibs/hr 0.323706
HYDROGEN CHLORIDE Sample Weight, mg 116.49 Concentration, ppm 63.86364 Emissions, Ibs/hr 4.305864 2 3

551.4 551.7 51.77 51.53 25766.5 25649.2 12102.4 11950.2 726143 717014 8.39 0 9.09

~ " / 0 3.00 3.00 17.00 17.00

10:30 AM 12:00 PM 11:32 AM 1:03 PM 43.177 42.872 98.76632 99.31629

99.63 105.99 97.99323 104.9955 3.694551 3.908791

11.15 8.97 3.087873 2.502966 0.413289 0.330792

103.55 117.93 55.80527 64.00973 3.839757 4.34891

el

## III. PROCEDURES

The procedure for emissions sampling followed USEPA test methods as detailed in Title 40: Code of Federal Regulations. The following methods were used:
Method Title 1 Sample and Velocity Traverses for Stationary Sources
2 Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S

Pitot Tube)
3 Gas Analysis for CO2, 02, Excess Air and Dry Molecular Weight
5 Determination of Particulate Emissions from Stationary Sources
26A Determination of Hydrogen Halides and Halogens Emissions from

Stationary Sources 02 and CO2 were determined using FyRite Analyzers. PM. HF, HCI, and CL2 sampling was performed on each source for a duration of 60 minutes. Sampling points and dwe11 times were as follows:

Soui

- ee Points Dwell Time Kiln # 

## 1 24 2.5 minutes Kiln #2 24 2.5 minutes Trim Kiln 12 5 minutes Scrubber 20 3 minutes The sampling train was configured as follows: Glass Sampling Nozzle Heated Glass Lined Probe Heated teflon filter lmpinger #1 - 100 mis H20 Impinger #2 - 100 mis 0.1 N H2SO4 Impinger #3 - 100 mis 0.1 N H2SO4 Impinger #4 - 100 mis 0.1 N NaOH Iinpinger #5 - 100 mis 0.1 N NaOH hnpinger #6 - 200 grams silica Gel Analysis for PM was performed on the probe wash, filter, and solution from the first impinger. HF and HCl analysis was performed on an aliquot from the first impinger, and the solution from the 2nd and 3rd impingers. Analysis for C12 was performed on the

7

## solution from the 4th and 5th impingers. Analysis was performed using a Dionex 500

IC/HPLC.

# Appendix AEMISSION TEST SUMMARY

PLANT : Daltile, Muskogee, OK DATE : 21-Apr-05 PLACE: Kiln 41 RUN#:

. TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 88.9 NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) : 31.47 METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) : 5.82 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.25 GAS METER VOL.(Cu.Ft.) : 37.157 PERCENT CO2 3 BAROMETRIC PRESSURE 29.4 PERCENT 02 17 PERCENT CO 0
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) : 0
ENTER THE STACK AREA SHOWN ABOVE: 8.295768 FLOWS SAMPLED VOLUME (STD. CU .FT.): 35.7623 VOLUME OF WATER VAPOR (STD. CU .FT.): 4.1845 FRACTIONAL MOISTURE CONTENT 0.1048

DRY BASE: 80.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 MOLECULAR WT. OF STACK GAS (WET BASE): 27.9910 STACK PRESSURE (inch Hg): 29.3816 STACK GAS VELOCITY (ft/sec.): 45.2428 ACTUAL STACK GAS FLOW RATE (ACFM): 22519.4372 STANDARD STACK GAS FLOW RATE (SCFH): 608038.089
PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0136 PARTICULATE CONCENTRATION (LBS/SCF): 1.94E-06 PARTICULATE EMISSION (LBS/HR): 1.1798
BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0025 PARTICULATE CONCENTRATION (LBS/SCF): 3.59E-07 PARTICULATE EMISSION (LBS/HR): 0.2182 ISOKINETIC RATIO (%): 97.3084

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T.

deg F INLET OUTLET
1 534 0.28 0.52915 0.97 68 68 2 553 0.40 0.632456 1.35 70 68 3 565 0.41 0.640312 1.40 73 68 4 570 0.42 0.648074 1.40 74 69 5 574 0.43 0.655744 1.45 75 70 6 574 0.40 0.632456 135 76 70 7 571 0.31 0.556776 1.05 77 70 8 570 0.28 0.52915 0.94 78 70 9 570 0.24 0.489898 0.80 79 72 10 570 0.23 0.479583 0.77 79 72 11 567 0.21 0.458258 0.70 80 73 12 562 0.20 0.447214 0.67 80 74 13 562 0.19 0.43589 0.64 81 75 14 574 0.28 0.52915 0.94 82 75 15 577 0.34 0.583095 1.15 83 76 16 579 0.40 0.632456 1.35 84 77 17 582 0.40 0.632456 1.35 85 78 18 583 0.39 0.6245 1.35 85 78 19 583 0.35 0.591608 1.20 85 78 20 582 033 0.574456 1.10 85 79 21 583 0.32 0.565685 1.10 85 79 22 581 0.32 0.565685 1.10 85 79 23 578 0.30 0.547723 1.00 86 80 METER T. 24 572 0-27 0.519615 0.92 86 80 AVERAGE

571.5 0.5626 1.0854 80.0417 74.0833 77.0625 ~



### ~EMISSION TEST SUMMARY

PLANT : Daltile, Muskogee, OK DATE : 21,Apr-05 PLACE : Kiln =i RUN#: 2 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 89.3 NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) : 31.3 METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) : 7.37 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.25 GAS METER VOL.(Cu.Ft.) : 38.31 PERCENT CO2 4 BAROMETRIC PRESSURE 29.4 PERCENT 02 16 PERCENT CO 0
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inches) : STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inches) : NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) : 0
ENTER THE STACK AREA SHOWN ABOVE: 8.295768 FLOwS SAMPLED VOLUME (STD. CU .FT.): 36.1790 VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2034 FRACTIONAL MOISTURE CONTENT (%): 0.1041

DRY BASE: 80.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.2800 MOLECULAR WT. OF STACK GAS (WET BASE): 28.1059 STACK PRESSURE (inch Hg): 29.3816 STACK GAS VELOCITY (ft/sec.): 44.0952 ACTUAL STACK GAS FLOW RATE (ACFM): 21948.2207 STANDARD STACK GAS FLOW RATE (SCFH): 588442.815
PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0133 PARTICULATE CONCENTRATION (LBS/SCF): 1.91E-06 PARTICULATE EMISSION (LBS/HR): 1.1225
BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0031 PARTICULATE CONCENTRATION (LBS/SCF): 4.49E-07 PARTICULATE EMISSION (LBS/HR): 0.2643 ISOKINETIC RATIO (%): 101.7204

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T.

deg F INLET OUTLET
1 577 0.26 0.509902 0.88 83 82 2 583 0.37 0.608276 1.30 89 84 3 585 0.39 0.6245 1.30 90 84 4 587 0.40 0.632456 1.40 90 84 5 587 0.40 0.632456 1.40 90 85 6 587 0.40 0.632456 1.40 90 85 7 583 0.32 0.565685 1.10 90 85 8 581 0.28 0.52915 0.98 90 85 9 578 0.25 0.5 0.87 90 85 10 574 0.23 0.479583 0.80 90 85 11 568 0.20 0.447214 0.70 90 85 12 565 0.19 0.43589 0.67 90 85 13 572 0.19 0.43589 0.66 88 86 14 579 0.26 0.509902 0.91 89 86 15 587 0.34 0.583095 1.20 90 86 16 584 0.35 0.591608 1.20 90 86 17 587 0.37 0.608276 1.30 90 86 18 588 037 0.608276 1.30 90 86 19 576 0.25 0.5 0.88 90 86 20 579 0.27 0.519615 0.95 90 86 21 580 0.33 0.574456 1.20 89 86 22 584 0.30 0.547723 1.05 89 86 23 571 0.29 0.538516 1.00 89 86 METER T. 24 568 0.27 0.51•9615 0.94 89 86 AVERAGE
579.58333 0.5473 1.0579 89.3750 85.2500 87.3125

. ~ _~ EMISSION TEST SUMMARY

PLANT : Daltile, Muskogee, OK DATE : 21-Apr-05 PLACE: KilnTl RUN#: 3 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : NOZZLE DIAMETER (INCH.) : 0.3033 PARTICULATE WEIGHT (Front half mg) METER COEFFICIENT (Y) : 0.994 PARTICULATE WEIGHT (Back half mg) PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : GAS METER VOL.(Cu.Ft.) : 39372 PERCENT CO2 BAROMETRIC PRESSURE 29.4 PERCENT 02 PERCENT CO
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.000502 STACK AREA (Sq.Ft.) :
' ENTER THE STACK AREA SHOWN ABOVE: 8.295768

FLOWS SAMPLED VOLUME (STD. CU .FT.): 37.1274 VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2034 FRACTIONAL MOISTURE CONTENT (%): 0.1017

DRY BASE: 80.0000 MOLECULAR WT, OF STACK GAS (DRY BASE): 29.2800 MOLECULAR WT. OF STACK GAS (WET BASE): 28.1328 STACK PRESSURE (inch Hg): 29.3816 STACK GAS VELOCITY (ft/sec.): 45.2752 ACTUAL STACK GAS FLOW RATE (ACFM): 22535.5569 STANDARD STACK GAS FLOW RATE (SCFH): 604951.788

~ PARTICULATE

FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0125 PARTICULATE CONCENTRATION (LBS/SCF): 1.79E•06 PARTICULATE EMlSSION (LBS/HR): 1.0811 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0006 PARTICULATE CONCENTRATION (LBS/SCF): 8.91E-08 PARTICULATE EMISSION (LBS/HR): 0.0539 ISOKINETIC RATIO (%): 101.5383

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T.

deg F INLET OUTLET
1 582 0.27 0.519615 0.91 84 84 2 582 0.37 0.608276 1.30 86 84 3 586 0.41 0.640312 1.40 87 84 4 587 0.41 0.640312 1.40 88 84 5 585 0.40 0.632456 1.40 89 84 6 585 0.39 0.6245 1.35 89 84 7 585 0.31 0.556776 1.10 89 85 8 584 0.27 0.519615 1.00 90 85 9 582 0.25 0.5 0.87 90 85 10 578 0.26 0.509902 0.90 90 85 11 573 0.21 0.458258 0.73 90 85 12 563 0.19 0.43589 0.66 90 85 13 568 0.20 0.447214 0.70 89 86 14 579 0.27 0.519615 0.94 90 86 15 582 0.37 0.608276 1.30 91 87 16 587 0.40 0.632456 1.40 91 87 17 587 0.39 0.6245 1.35 92 87 18 590 0.39 0.6245 1.35 92 87 19 580 0.35 0.591608 1.20 92 88 20 587 0.36 0.6 1.25 93 88 21 586 0.34 0.583095 1.20 94 88 22 581 0.30 0.547723 1.00 94 89 23 575 0.29 0.538516 1.00 94 89 METER T. 24 571 0.27 0.519615 0.94 94 89 AVERAGE
581.04167 0.5618 1.1104 90.3333 86.0417 88.1875 89.3 30.09 1.5 0.25 4 16 O

0

~ .. ~EMISSION TEST SUMMARY

PLANT : Daltile, Muskogee, OK DATE : 21-Apr-05 PLACE: Kiln#2 RUN#: 1 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mIs) : NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : GAS METER VOL.(Cu.Ft.) : 44.606 PERCENT CO2 BAROMETRIC PRESSURE 29.4 PERCENT 02 PERCENT CO
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) :
ENTER THE STACK AREA SHOWN ABOVE: 8.295768 FLOWS SAMPLED VOLUME (STD. CU .FT.): 42.4462 VOLUME OF WATER VAPOR (STD. CU .FT.): 4.3399 FRACTIONAL MOISTURE CONTENT (%): 0.0928

DRY BASE: 80.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 MOLECULAR WT. OF STACK GAS (WET BASE): 28.1248 STACK PRESSURE (inch Hg): 29.3816 STACK GAS VELOCITY (ft/sec.): 50.6215 ACTUAL STACK GAS FLOW RATE (ACFM): 25196.6665 STANDARD STACK GAS FLOW RATE (SCFH): 711541.187
PARTI CU LATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0080 PARTICULATE CONCENTRATION (LBS/SCF): 1.15E-06 PARTICULATE EMISSION (LBS/HR): 0.8161 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0045 PARTICULATE CONCENTRATION (LBS/SCF): 6.47E•07 PARTICULATE EMISSION (LBS/HR): 0.4602 ISOKINETIC RATIO (°7,): 99.0861 92.2 22.08 12.45 0.25 3 17 0

0

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T

deg F INLET
485 519 532 539 539 544 545 548 549 548 545 sll 520 558 559 555 559 558 554 546 546 546 506 536
539.45833 0.6410 1.7542 85.6667 METER T OUTLET
71 71 71 72 72 73 73 74 75 75 76 76 78 79 79 80 80 81 81 82 82 83 83 METER T. 83 AVERAGE
77.0833 81.3750 ~ 1

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 0.45 0.67082 0.52 0.72111 0.56 0.748331 0.58 0.761577 0.55 0.74162 0.55 0.74162 0.52 0.72111 0.52 0.72111 0.52 0.72111 0.52 0.72111 0.54 0.734847 0.45 0.67082 0.60 0.774597 0.63 0.793725 0.G0 0.774597 0.55 0.74162 0.53 0.728011 0.53 0.728011 

### z 0.25 0.5 0.15 0.387298 0.11 0.331662 0.10 0.316228 0.10 0.316228 0.10 0.316228 1.80 2.10 2.30 2.30 2.20 2.20 2.00 2.00 2.00 2.00 2.10 1.80 2.30 2.50 2.50 2.30 2.20 

### zc 1.00 0.62 0.45 0.41 0.41 OA1 71

7 4 7 9 9 7 83 s2 fi3 85 86 86 ss 88 85 S9 89 a 8 90 90 90 90 90 90 90 90



## ~ ~~EMISSION TEST SUMMARY

PLANT: Daltile, Muskogee, OK DATE : 21-Apr

~ 05 PLACE: Kiln#t2 RUN#:, 2 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mIs) : NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : GAS METER VOL.(Cu.Ft.) : 46.04 PERCENT CO2 BAROMETRIC PRESSURE 29.4 PERCENT 02 PERCENT CO
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inches) : STACK AREA (Sq.Ft.) : 8.295768 STACKWIDTH(inches) : NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) :
ENTER THE STACK AREA SHOWN ABOVE: 8.295768 FLOWS SAMPLED VOLUME (STD. CU .FT.): 43.1775 VOLUME OF WATER VAPOR (STD. CU .FT.): 3.9539 FRACTIONAL MOISTURE CONTENT (%): 0.0839

DRY BASE: 80.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 MOLECULAR WT. OF STACK GAS (WET BASE): 28.2238 STACK PRESSURE (inch Hg): 29.3838 STACK GAS VELOCITY (ft/sec.): 51.7663 ACTUAL STACK GAS FLOW RATE (ACFM): 25766.4705 STANDARD STACK GAS FLOW RATE (SCFH): 726142.608 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0091 PARTICULATE CONCENTRATION (LBS/SCF): 1.30E•06 PARTICULATE EMISSION (LBS/HR): 0.9449 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0020 PARTICULATE CONCENTRATION (LBS/SCF): 2.79E•07 PARTICULATE EMISSION (LBS/HR): 02028 ISOKINETIC RATIO (%): 98.7663

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T.

deg F INLET OUTLET
1 552 0.50 0.707107 2.05 85 85 2 553 0.58 0.761577 2.40 87 86 3 555 0.58 0.761577 2.40 89 86 4 556 0.56 0.748331 2.30 91 85 5 557 0.55 0.74162 2.30 91 85 6 556 0.57 0.754983 2.30 92 85 7 555 0.54 0.734847 2.20 92 86 8 559 0.54 0.734847 2.20 93 86 9 558 0.55 0.74162 2.30 94 86 10 558 0.55 0.74162 2.30 94 87 11 557 0.53 0.728011 2.20 94 87 12 547 0.48 0.69282 2.00 94 87 13 541 0.60 0.774597 2.50 92 87 14 553 0.64 0.8 2.60 95 88 15 555 0.61 0.781025 2.50 94 88 16 554 0.53 0.728011 2.20 93 88 17 554 0.53 0.728011 2.20 93 88 18 553 0.55 0.74162 2.30 93 88 19 552 0.31 0.556776 1.30 93 88 20 548 0.17 0.412311 0.70 92 88 21 547 0.10 0.316228 0.41 92 88 22 547 0.12 0.34641 0.50 92 88 23 543 0.10 0.316228 0.41 92 88 METER T. 24 523 0.10 0.316228 0.41 92 88 AVERAGE
551.375 0.6528 1.8742 92.0417 86.9167 89.4792 84 25.48 5.47 -0.22 3 17 0

0

~EMISSION TEST SUMMARY
PLANT : Daftile, Muskogee, OK DATE : 21-Apr-05 PLACE : Kiln 42 RUN#: 3 TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 91.1 NOZZLE DIAMETER (INCH.) : 0.3027 PARTICULATE WEIGHT (Front half mg) : 26.64 METER COEFFICIENT (Y) : 0.989 PARTICULATE WEIGHT (Back half mg) : 3.55 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 0.24 GAS METER VOL.(Cu.Ft.) : 45.757 PERCENT CO2 3 BAROMETRIC PRESSURE 29.4 PERCENT 02 17 PERCENT CO 0
FOR CIRCULAR STACK FOR RECTANGULAR STACK STACK DIAMETER (inch): 39 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 8.295768 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.0005 STACK AREA (Sq.Ft.) : 0 ENTER THE STACK AREA SHOWN ABOVE: 8.295768 FLOWS SAMPLED VOLUME (STD. CU .FT.): 42.8720 VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2881 FRACTIONAL MOISTURE CONTENT (%): 0.0909

DRY BASE: 80.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.1600 MOLECULAR WT. OF STACK GAS (WET BASE): 28.1453 STACK PRESSURE (inch Hg): 29.3824 STACK GAS VELOCITY (ft/sec.): 51.5307 ACTUAL STACK GAS FLOW RATE (ACFM): 25649.1985 STANDARD STACK GAS FLOW RATE (SCFH): 717014.424 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0096 PARTICULATE CONCENTRATION (LBS/SCF): 1.37E-06 PARTICULATE EMISSION (LBS/HR): 0.9824 BACK HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0013 PARTICULATE CONCENTRATION (LBS/SCF): 1.83E-07 PARTICULATE EMISSION (LBS/HR): 0.1309 ISOKINETIC RATIO (%): 99.3163

POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T.

deg F INLET OUTLET
1 572 0.52 0.72111 2.10 87 87 2 537 0.48 0.69282 2.00 85 85 3 553 0.61 0.781025 2.50 87 85 4 554 0.65 0.806226 2.70 90 85 5 552 0.55 0.74162 2.30 91 85 6 557 0.55 0.74162 2.30 91 86 7 559 0.50 0.707107 2.00 92 86 8 559 0.55 0.74162 2.30 92 86 9 559 0.55 0.74162 2.30 92 86 10 558 0.55 0.74162 2.30 92 87 11 555 0.55 0.74162 2.30 92 87 12 533 0.48 0.69282 2.00 93 87 13 544 0.60 0.774597 2.50 92 88 14 551 0.64 0.8 2.60 93 88 15 551 0.55 0.74162 2.30 93 8II 16 553 0.55 0.74162 2.30 94 89 17 554 0.55 0.74162 2.30 95 89 18 556 0.56 0.748331 2.30 95 89 19 554 0.27 0.519615 1.10 95 90 20 551 0.15 0.387298 0.61 95 90 21 553 0.10 0.316228 0.41 95 90 22 549 0.10 0.316228 0.41 95 90 23 545 0.10 0.316228 0.41 95 90 METER T. 24 532 0.10 0.316228 0.41 95 90 AVERAGE
551.70833 0.6488 1.8646 92.3333 87.6250 89.9792



### ~ ~:

# Appendix B

### PARTICULATE ANALYTICAL DATA FORM Company: Daltile, Muskogee, OK Date: 4/21/05 Location: Kiln #1 Run 1 Run 2 Run 3 Density (Pa) 5 ': * ' 

### i db. 7$54 i Blank Concentration (Ca) .7. Rinse Volume (Vaw) .5

......... . Residue in Rinse (Wa) = Ca*" , Vaw*Pa 0.0004 0.0004 0.0004

Date of Weighing 

## P

Time Gross Weight 

### ."040 Date of Weighing

Time Gross Weight

Date of Weighing

....... . ...... .. ......

Time 7. 3-0: AM

........... . Beaker Tare Weight 

### 1 . - T. 

### 4.; 6.0 54 9 1 

### i 1 0 0 i 5'-' 

### 3 2 0. 1 Date of Weighing

Time V ;::::::::2 

### 9: p Beaker Tare Weight Average Gross Weight 114.6198 107.9072 100.9449 Less Blank Residue (Wa) 0.0004 0.0004 0.0004 Average Beaker Tare Weight 114.6054 107.8913 100.9321 Weight of Particulate in Rinse (mg) 13.97 15.50 12.39



### ACETONE BLANK ANALYTICAL DATA FORM Blank Volume (Va) Date of Weighing

Time Gross Weight Date of Weighing

Time

. 7.1 A'

...... Gross Weight Average Gross Weight 99.69895 Date of Weighing

Time Tare Weight Date of Weighing

Time Tare Weight Average Tare Weight 99.6983 Weight of Blank (Ma) 0.00065 Ca= Ma/(Va*Pa) = mg/g 0.00331 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank weight be subtracted from the sample weight.

### FILTER ANALITICAL DATA

Company: Daltile, Muskogee, OK Date: 4/21 /05 Location: Kiln #1 Exhaust Run J. Run 2 Run 3 

## Filter ID Number 84T::::::;::::_:: Date of Weighing

Time Gross Filter Wt. ;::a: t3::4#3.7- 0$8 Date of Weighing

Time :; ::3:~G; Rti~l: ; ;3:~5:P:fVI: :: :3;3~::Rh!►;: Gross Filter Wt. ;: : ;:0:`4€3-7, 9: -0:413:5:
Ave. Gross Filter Wt. 0.4079 0.4060 0.4135 Date of Weighing ~b " 1 = '[2%E3~::

Time Filter Tare Wt. Date of Weighing 194: .~. ~ ~....~.~.,_..~.,. .__.....~..~..,.-.,~ Time Filter Tare Wt. ii::::::O;09.04:
Ave. Filter Tare Wt. 0.3904 0.3902 0.3958 Wt. of PM on Filter (grams) 0.0175 0.0158 0.0177 Total Weight of Particulate (mg) 17.5 15.8 17.7

~ , { ~PARTICULATE ANALYTICAL DATA FORM
Company: Daltile, Muskogee, OK Date: 4/21/05 Location: Kiln #1 Exhaust Run I Run 2 Run 3 Density (Pa) Blank Concentration (Ca)

...... ..... Aliqout Volume (Vaw)

.......... 1 

### 9

. Total Volume Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0005 0.0005 0.0005

Date of Weighing

Time Gross Weight Date of Weighing

Time Gross Weight :01.;5 

### .0 `8 6.Z 5Q : :

Date of Weighing 1f .4 ID 5: Time -7...4 2- , AM : Beaker Tare Weight 81 ;

Date of Weighing

Time Beaker Tare Weight Average Gross Weight 101.9011 103.1940 96.2892 Less Blank Residue (Wa) 0.0005 0.0005 0.0005 Average Beaker Tare Weight 101.8962 103.1873 96.2882 Weight of Particulate in Rinse (mg) 4.41 6.16 0.56

Total Particulate (mg) 4.6379 6.4800 0.5853

H20 BLANK ANALYTICAL DATA FORM
Blank Volume (Va) Date of Weighing

Time Gross Weight Date of Weighing

Time .27.

. Gross Weight 5:

Average Gross Weight 105.95755 Date of Weighing

Time Tare Weight Date of Weighing

Time p Tare Weight Average Tare Weight 105.9569 Weight of Blank (Ma) 0.00065 Ca= Ma/(Va*Pa) = g/g 2.6E•06 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank weight be subtracted from the sample weight.

### PARTICULATE ANALYTICAL DATA FORM Company: Daltile, Muskogee, OK Date: 4/21/05 Location: Kiln #1 MeCi Rinse Run 1 Run 2 Run 3 Density (Pa) Blank Concentration (Ca) Rinse Volume (Vaw)

........... Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0002 0.0002 0.0001

Date of Weighing

Time P Gross Weight 8 .0 ~ Date of Weighing

Time .3 :A 4~ M:: Gross Weight

Date of Weighing -3

~ . 5v 4 .26

~ 65 :

Time 

## AM; 836 8 : 3 Beaker Tare Weight 

### 5 5 : Date of Weighing

Time

..... .. .. . '4 Beaker Tare Weight Average Gross Weight 106.0839 106,7466 98.6450 Less Blank Residue (Wa) 0.0002 0.0002 0.0001 Average Beaker Tare Weight 106.0826 106.7456 98.6439 Weight of Particulate in Rinse (mg) 1.18 0.89 0.91



### METHYLENE CHLORIDE BLANK 

### ANALYTICAL DATA FORM Blank Volume (Va) Date of Weighing

Time Gross Weight Date of Weighing

Time Gross Weight 1. 0. 44:8 8 a.9;: Average Gross Weight 104.88395 Date of Weighing 47

Time Tare Weight 04:8$36:; Date of Weighing 

### i 

## i i i0i

~ 

### - *3*

Time Tare Weight 5:: Average Tare Weight 104.88355 Weight of Blank (Ma) 0.0004 Ca= Ma/(Va*Pa) 

### = g/g 1.176E•06 Note: In no case should a blank residue greater than 

### 0.01 mg/g or 

### 0.001% of the blank wei ht be sWbtracted from the sample weight. 

### - 11

- 

# 4

### PARTICULATE ANALYTICAL DATA FORM
Company: Daltile, Muskogee, OK Date: 4/21/05 Location: Kiln #2 Run 

### I Run 2 Run 

### 3 Density (Pa) 7 5 1 .: -.51: Blank Concentration (Ca) Rinse Volume (Vaw) Residue in Rinse (Wa) 

### = Ca*Vaw*Pa 0.0003 0.0004 0.0004

Date of Weighing Z. 2

Time Gross Weight Date of Weighing

Time 'M Gross Weight 

### 70

Date of Weighing

Time 'M Beaker Tare Weight Date of Weighing

Time ~ 

### .1':::

: RM: 2 Beaker Tare Weight Average Gross Weight 102.2577 96.2301 113.9286 Less Blank Residue (Wa) 0.0003 0.0004 0.0004 Average Beaker Tare Weight 102.2502 96.2192 113.9169 Weight of Particulate in Rinse (mg) 7.18 10.48 11.24



### ACETONE BLANK ANALYTICAL DATA FORM
Blank Volume (Va) Date of Weighing

Time Gross Weight Date of Weighing Y- . Time A Gross Weight Average Gross Weight 99.69895 Date of Weighing 0.5i

Time Tare Weight Date of Weighing :: 

## .4 

## I 3 iD5:

Time Tare Weight Average Tare Weight 99.6983 Weight of Blank (Ma) 0,00065 Ca= Ma/(Va*Pa) = mg/g 0.00331 Note: In no case should a blank residue greater than 0.01 mg/g or 0.00IT o of the blank 

### weight be subtracted from the sample weight.

### FILTER ANALITICAL DATA

Company: Daltile, Muskogee, OK Date: 4/21 /05 Location: Kiln #2 Exhaust Run 1 Run 2 Run 3
Filter ID Number Date of Weighing



### Time 

## qlltl: Gross Filter Wt. 

## `3: :::::: fl:38

~ 

## 6: Date of Weighing

Time

~ :45:: Pi

~ !I:: Gross Filter Wt.


### Ave. Gross Filter Wt. 0.3832 0.3924 0.3857 Date of Weighing ..........., ............ 

### 910 ~ ...........



### ::~ I~~~f(?~':: 

### Time U; Filter Tare Wt. :::D:3883: :: :0:3774` Date of Weighing 

## -1:T1

- 3004: Time Filter Tare Wt.
Ave. Filter Tare Wt. 0.3683 0.3774 0.3703 Wt. of PM on Filter (grams) 0.0149 0.0150 0.0154 Total Weight of Particufate (mg) 14.9 15.0 15.4

s r.. ~PARTCULATEANALYT|CALOATAFORN1 Company: DaUi|e, Muokogee,OK Dmn: 4/21/05 LocaVon: Ki|n#2 MeQ Rinse

~ Run1 Run2 Run3
L ~ DonsKyVza

, B|ankConcontratinn(Ca) RinxeVo|umo(Vaw)

~ no,idueinRinso(ma)=Ca°Vaw°Pa 0.0002 0.0002 ' 0.0001

- DatoofVVoi g hin8 ' Timo GmxaWeight DatooiYVaighing

Timo

~ GmosVYeight ^ Datoo(YYoi8hing Timo BeahorTamWeiKht ~~~3S~~~~

~~ 1

~~~~~ : DatenfYVaighing

Timo B eaknr T am VV oight

~ AvoegeGroxsYYoi8ht 99,4023

-- 110

. 54 77 __- 10 4. 7 I 36 ~ LossB|unkRonidue(wa) O
, O0U2 0 ,00 0 1 4vnra ge 8aakorTamYVoi g ht 

### r --------- 99.4011 110.5467

.

--------- --------- YVeightof Particu|ate in Rinoe(m8) 0.97 0.83 0.65

Time

Time

Time

Time

~-/

~~ ~

### PARTICULATE ANALYTICAL DATA FORM Company: Daltile, Muskogee, OK Date: 4/21/05 Location: Kiln #2 Exhaust Run I Run 2 Run 3 Density (Pa) Blank Concentration (Ca) ;6 : 6: Aliqout Volume (Vaw) Total Volume

..... ::: no : 2 0 Residue in Rinse (Wa) = Ca*Vaw

- l

- Pa 0.0005 0.0005 0.0005

Date of Weighing

Time i -3't27 , . ; F M: Gross Weight Date of Weighing

Time Gross Weight

Date of Weighing

Time Beaker Tare Weight : 27 -5:: : . 7r

~ 0 2- 1 4 Z : Date of Weighing /4 - Time Beaker Tare Weight Average Gross Weight 96.1490 101.2191 102.5770 Less Blank Residue (Wa) 0.0005 0.0005 0.0005 Average Beaker Tare Weight 96.1376 101.2142 102.5737 Weight of Particulate in Rinse (mg) 10.91 4.41 2.76

Total Particulate (mg) 11.4800 4.6379 2.9011



### H20 BLANK ANALYTICAL DATA FORM
Blank Volume (Va) Date of Weighing

Time Gross Weight i 5 S. - .7. Date of Weighing

Time Gross Weight Average Gross Weight 105.95755 Date of Weighing V0

Time Tare Weight Date of Weighing

Time Tare Weight Average Tare Weight 105.9569 Weight of Blank (Ma) 0.00065 Ca= Ma/(Va*Pa) = g/g 2.6E•06 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001 0 , of the blank ,weight be subtracted from the sample weight. 

# -1Sheetl

Summary of Hydrogen Halide and Halogen Analysis


### Plant: ' Daltile, Muskogee, OK Date: 

### 4/21/05 Location: 

### Kiln #1 Exhaust

Run 

### # Imp # !Volume Dilution : Fl-, ug/ml 

### IHF, m9 

### ICI-, ug/ml 

### 'I HCI, mg



### 11 

## 11 2001 

### 20 27.421 115.493 1 1 

### 07 28 

## 1 115.4238

- 

### 1 

## j 1 

### 2001 201 28.151 118.56781 26.41 108.5568 111.9903
2'i 1 2001 201 23.66 99.65592 23.71 97.4544 21 

## 11 2001 201 

### 25.67 108.1221 24.34 100.0861

! Average 

### 103.8891 1 

### 98.77024 ---------------- 

### 31 

## 11 2001 201 26.66 

### 112.29191 29.081 119.577 3 1 

### 2001 201 27.21 lAverage 

## 1 114.56641



### 113.42921 26.27 108.0222



## 1 113.7996
Run # jlrnp# IVolume 

# I Dilution Fl -, ug/m I 

### IHF, mg !Cl-, ug/ml !HCl, mg



### 1128 1 i 12.03 3.166898 

## 1 16.791 431503 112 & 3 1 1 

### j I 12,17 1 3.2037531 18.231 4.68511 

### lAverage 

# 1 3.1853251

- 

# 74 - : 5

- 0667 -- 212 & 3 j 

### 250 1 1 15.21!, 

### 4.004033 1 18.62 L_118534 2j2 & 3 1 

## I 15.78 4.1540851 18.54 1 1 4.76478 jAverage 4.079059 

### 4.77506
312 & 3 

# 1 2501 

## 11 15.771 4.151453 1 1 15.92 4.09144 312 & 3 

## 1 2501 1 15.181 3.9961351 16.211 4.16597 lAverage 

## 1 4.0737941 4.128705 Hydrogen Halide Totals 

### !Run# 

## 1 120.21571 116.4904 

# 1 107.9681 103.5453 

# 1 117.5031 _LIL7.9283

un # 'Imp# IVolume IDilution 

### iCi-, ug/ml 1C12, mg 

# i

1 

### 2501 2 j 10.981 5.49 1 I 

### 2501 21 11.611 ___5.8051 5.6475
2501 21 16.15' 8.0751 

### 21 11 

### 250 21 16.251 8.1251 8.11

3 

## j 11 250 j 

### 21 18.621 9.311 

### 3 1250, 21 18.51 9.28'

Page 1 OASheetl

n3 Jo

### Conditioma


## Date Time

_ [omponont Koton z 10 ug/mI Fl— in H20

z 10 ug/ml Cl— in H20 : 03/23/2005 : 1O:41:59

l02'4OOmV

Fl- O. Cl- 1. 1O24.DOOmV Aroo Exbxnal

795,08 9.33 672.04

Compunent Number Ret«antion Aree ExteTnaI Unita Fl— 1 0'966 795.08 9.33 ug/ml Cl— 2 1.283 672.04 9.78 ug/ml

2 1467-13 19-10

~~

### Comditic>ms : 10 ug/ml Fl- in H20 z 10 ug/ml CI- in H20 Date : 03/23/2005 TIme : 10:48:34

-102'40OmV 1024'O0OmV

Area IExternaI Unita 832.60 M 9'79 ug/ml 673.10 M 9',79 ug/ml

1505-70 19-58 Fl` O. Cl- 1. Area Extmnal

832.60H YJY 673.10 M YJY

Component Number Retention Fl- 1 0.966 Cl- 2 1.300

2

~~~
~~

### Area External Unito 1908'65 21.78 ug/ml 1778'45 26.59 ug/ml Cnmponent Numbmr Retentlon Fl- l 0.983 cI- 2 1.316

N ComditlVma : 25 ug/ml Fl- in H20

z 25 ug/ml CI- in H20 Da±e : 03/23/2005 Time : 10:53:12

-102.4O0mV lD24.00OmV

Fl- O. U- 1908.65 21.78 Ci- 1.31 1778.46 26.59

~

~ ~{ ~J 

### ] ~t ~~

,

### Area ExternaI Unito 1993.17 22.71 ug/0l 1784.13 26.68 Vg/ml . 

### CVmponentFlC}- Number Retention 1 0'988 2 1.316

2 Conditions

uace Tim«p : 25 ug/ml Fl- in H20 z 25 ug/ml CI- In H20 : 03//23/2005 : 10:56:16

L02.4OVmV 1O24'OOOmV Aroa External

Fl_ V. 1998.17 22.71 C}- 1,31 1784.13 26.68

~ ~ ~

## Conditions =40 ug/ml F1- in H20 = 40 ug/ra1 CI- in 4-C20 aate = 03,`23/2005 Time = 11- 04 =1.3



### -102.4OGmV 

## Gompanent Reten "

Fl- 1. Cl- 1. 1424 . OCC?mV 

## Area External

2930.43 M 33.11 2397.15 M 36.38

Co€npanent 

### F= l -

## Cl

# z Number Retention
1 1.000 2 1.333 

## Area External Units
2930.93 M 33.11 ug/mI. 2397.15 M 36 .,38 ug/m l.
5328 _ C}9 69 _ 49



## ~ :~~

### 1024,0OOmV -1O2'4OOmV

_ t Re 

### t en



### '

Fl- 1.ClCnnditiona : 40 Vg/ml FI- in H20 : 40 ug/ml Cl- in H20 Date : 03/23/2005 Tim«a : 11:07:39

Arva Exhnnal

2948.90 33.30 2492.0 37.89

Numk/er Retwntinn Area ExternaI Unito 1 1.000 2948'90 33.30 'g/ml 4 2 1,333 2492.50 37.89 g/ml

5441.40 71-20 CompnnentFlCl0

~ 

### D

### Ccsnditions = 5 ugfml Fl° in H24 , = 5 ug/ml Cl— in Fi2E7 Date = 03.12302005 Time = 11=31=36

, —102 ®4GamV 1024 ,O4C?mV 

## Component Retention Area External

FI- 0. Cl- 1. 386,10 M 4.55 315.98 M 5.00

F 1-- 

## Cl— Component

E 

## Number Retention

1 0.950 2 1.266 

## Area ExternaZ UnitS 386.10 M 4.55 ugfml :315.98 M 5.00 ugim).

702 _ a8 9.55

~ 

# ~ ~t

### Condits.ans = 5 uglml Fi— in H20 = 5 ug/€nl CI:- 'Ln F320 t}ate = 03l23I2045 Ti€ne = 12=34=41

--1 C72 H 4QOmV 

## Companent Reten '

Fl - 

## o. C1

- 

## l. 1024 . QC7amV 

## Area External

380.84 M 4.93 299.84 M 4.74

Cotnponent 

## Number Retention Area External Units 

## Fl— 1 0.966 

### 380n80 M 4.93 ug/ml 

## C1— 2 1.283 299.80 M 4.74 ugfml



## © 680.60



# 4
,~ ~AMOC,tNT ZNJECTED

AREA 0.000 

### 0.000

2939 .915 40.000. 

# 1

2

3

4

5 

### Calibration fi.le = FZ-.cal

Avg s.l.ope crf curve : 76.13 Y—axis intercept= 0.00 Caeff nf 1i n regr : 0.88 hdn . Area AmQunt CF 0 - 0.000 0.000 0 K aC3Q 

## 1= 383.450 5,000 76.690 2: 813.840 10.000 81

~ 384 3= 1950.910 25.000 . 78 . a36 4 : 2939.915 40.000 73.498



# 43 ,

### AMQUNT INJECTED

AREA 0.00 

### 0.000

2444.825 40.000 

### 1

2

3

4



# s CaZibrativn file : Cl—=cal

Avg slope of curve = 63.17 Y--axis intereept= 0.00 

## Coeff of li.n regr: 0.85 No . Area Amount CF 

### 0: 0.000 0.000 0.000 1. 307.890 5.000 61.578 2= 672.570 10.000 67.257 3=.1781.290 25.000 71.252 4 ~ 2444 .825 40.000 61.121



## ~ Id

### ATea ExteTnal



### 211'M5 M 27A2 

### 1917.12 M 

### 28.07 

### conditions : 

### Daltile

: 

### Kiln #1 : 

### Run #1 

### Imp #1 z 

### Volume 200 mdsz D71-ut'Lon 1120 

### Date : 03/23/2005 

### Time : 

### 14:05:53

—102

~ 4OOmV 1024.00Om11.



### i 9 1 

### i 7 2 m



# m28.15 

## 26.40 2158.76 

## M 1843.43 M 1024.00OmV 

## Area Exterpal 0'

~ 

## 4 C.0 

## mn V 

## conditions

: 

## n-a-

1- -i- le Kiln #1 

### Run #1 

### Imp.#I Volume 200 mis Dilution 1/20 Date : 03/23/2005 

### Time : 

### 14:09:15

Compopent Number RetentionFi

## ci- 2 

## 1.350 1843u43 M 6 

## 4C. u im



### 4002.19 

## 54 SES



# 53Kiln #1 Run #2 imp,#1 VC-Oumiz MIR Date 03/23/2005 Time 14:16:41

1024 , OOOmV Area External

ri_ 1849.10 M 23.66

1.3 1684.93 M 23,70

2 i .3-

1 331 1684.93 M 23 -

- 70 uVml



# IN

### 'K, iln #1 Pun Date : 03/23/2005 Time : 14:20:10

ComponentRetefltiop

............................... ...................................... .................................... -........................ 024 . OOOPO! Area External

v 

## m 1994M M 25z67 1.3 1732,22 M 24.34

Component Number Retenti-on A 

### T - =-- a E

1737' M 24.34 ug/mi

## L'Onditions : Daltile : Kiln #1 : Run #3 Imp #1 : volume i200 mis Dilut.Lon 1/20 Date : 03/23/2005 Time 

## : 14:25:15



## 102 1 4 , OOQ - Mv Area EXteTflal



## MEN M 26.66 

# ri 2 9 . 0 B



# mz -t :-:1 1 K 1 ' L n

Date : 03/23/2005 Time : 14:27:42

. .

. . . . . . . ............................................................... ............. ............ ?IT z, R. P

2095.64 M 27,20 1837,30 M 26.27

Number R o n



## 2 

# 6 -

### CoDditioDs : 

### Dal

- 1-ile : 

### Kiln #2 Run #1 

### Imp #1 

## Vol-ume 200

, M- Is 

### Dilut ; Lon 1/20 

### Date : 03/23/2005 

### Time : 

### 14:33:38

102- 1 4.000mV ATea EA , '6erfla- 1

- .... . .. ............. g .. !:!:: , t. 1 1~ !tl:t!:! , .":!!::t: ,

.!!:!:!:!:!

~ -!!:t.

...................... . .............


## 2i

........... ........................... ............................... ................... ............................................................................................. ........................................ ............. 193535 

## M 24 184 1 778,06 

### M 24196

t t

(Z. 24 Uq/M

ji n



## ti

,

### r. x 

## ri 1-1. Wi E 1 m in Date- G%3/23/2C205

14:361: 17

R-1 te A Area Externai

ov ri 2MO 1-64535 M 23.17D 

### a ile Kiln #2 Run #2 Imp 

### #1 3 z .9 =CV , Date 

### : 03/23/2005 Time 

### : 14:41:32



### ................ ............... ....... ....... .........................................................

............. ......................

................. ................. ..... .. . .............................



### v i I *Cl* 

### 24" , . 0 0 0 

### m V 

## ATea Exterflal

J^ 1 - 177'

~ 

## M .0 7 2232

1831 : lx

Q ~ , , 86 

### r"! :: -,+

# 6 k--j 10 

### 2 4 = 0 0 V

,rp V 

### C, 2

~ 

### ' . V 

### 0 

## Kiln #2 Run 2#2 Imp 

### #1
Date 

### : 03123/2005 Time 

### : 14:44:04



## 174MM M 22.34 1714.45 M 24.10

### Cciprli tion4 -- Dal t-

-, I iz



### K I Lln #2 Run #3 Imp # I or, Date 03123/2005 Time 14:51:42



### 1024.00OmV

F 1-

# ciATea Exterpal

1914.18* M 24,52 1871.33 M 27.04

J, 

### 2 I



# m

# C, 3 1 'L 0 2 ~ 

### 0 0 0 m V 

### K i Lln #2 R u n t 

### I z Date 

### : 03/23/2005 Time 

### : 14:54:40

- 1 02 

### - 4

, C-3 

### 0 m 

### V Evtzr pa l

FZ 5. v 7 I i

- - 

### 1811,62 Vi 21". 

### 16
1743.47 M 24.45



### CC , 

### c ~ 

### n d i 

### t i


## Date Time : H20 Blank 

### : 03/23/2005 : 15 , :25:14



### 0 2 00 m V 1024-000mV Area ExteTnal



### n e.

### - \

. ~



### _ |` Conditions : 5 ug/mI Fl- in H25O4 : 5 ug/ml Cl- in H2SO4 Date : 03/24/2005 Time : 08:56c17

-102'4OD0V '

. - . ..

~ m~~ 

### (unkmmn) 0.00 ~ 

### on 1024.00OmV Area Exter0al 252.05 H/A

Fl- O, 487.09 5.56 Cl- 1.30 302.55 4.60

, Component Number Retention Area External Unito Fl- 1 0'966 487.09 5'56 ug/ml Cl- 2 1.300 302'55 4.60 ug/ml

2 789-64 10'17

r, ~

### Comdltinna


## Date Time

_ Cnmu000nt Rotontion : 5 4g/mI FT— in H2SO4

: S ug/ml CI— in H2S(J4 z 03/24/2005 : D8z58c21

102.4OOmV 1O24.00OmV

Fl- 0, Cl- 1. Aroa Externa}

446.87 5.07 294.47 4.49

Compmment Number Retention Area External Unita Fl— 1 0'966 446.87 5'07 ug/ml Cl- 2 1.300 294.47 4

~ 

### 49 ug/m}

2

n ~ /~

### Conditimno : 10 ug/ml Fl- in H2SO4 : lO ug/ml Cl- in H25O4 Daate : 03/24/2005 . Time c 09:03:24

-1O2.4D0mV 1024'00OmV Aroa Extmna}

Fl- O. 1

~ 

### - 864.80 10.16 C1- 1.31 531,35 8.12

4|

Component Number Retention Aree External Unita Fl- 1 0.983 864'80 10.16 ug/m} Cl- 2 1'316 531'35 8.12 ug/ml

2 1396'15 18'28

/ ~

### Condit= ons = 10 ug/ml F1— in N2SO4 = 10 ug/mi Cl-- in F;2SO4 

### date a 03124/2005 Time = 09=08=12

-°102 ,4C}OmV 

### 1424 . C?OC7mV 

## Component Retention Area External

Fl- 0. 873.40 M 

### 10.28 

### C1- 1.31 537.10_ m 

### 8.20



## ComponentF1w

### CJ.-

2 

## Number Retention
1. 0.983 2 1.316 

## Area External Units

873.90 M 10,28 uglml 537.10 M 8.20 ugJm l

1421 _00 18.48



## ~r ~

### Conditiono : 20 ug/ml Fl- in H2SO4 c 20 ug/m} [I- in H2SO4 Daate : 03/24/2005 Timf+ : 09r13:58

-102.4OOmV 1O24'O0OmV Area External

Fl- 1' 1578.65 18.07 Cl- 1.% 1090.30 17.74

Component Numbwr Retention Aree Extermal Unito Fl- 1 1.000 1578.65 18.07 ug/m} Cl- 2 1,333 1098,30 17'74 ug/ml

N

~ 

### A

~ 

### U `

### Cmnditloms
Date Time : 20 ug/nl Fl- in H2504 r 20 ug/mI Cl- in H2SO4 : 03/24/2005 : O9z16:1S

lO2.4D0mV lO24.O0OmV Arna Exbxnal

1603.90 M 18.36 1157.16 M 18.55 - !

r

~ 

### 1

^ FlCl- ' O. 1.3161/

| |

~ | ~



### CompVnent Number Retentimn Area ExternaI Unito Fl- 1 0'983 1603'90 M 18.35 ug/ml

~ 

### Cl- 2 1,316 1157'15 M 18.55 ug/ml

~~ ~~ L

### CnnditiVns : 40 ug/ml Fl- in H2SO4 : 40 ug/ml Cl- In H2SO4 Date z 03/24/2005 Tjme* : 09:22:19

-lO2.4OOmV

. . Reten

..

Fl- 1. C1- 1. 1024'00OmV Area Extmrnal

3389.30M #.y1 2500.47 H 43.\3

Cnmponent Number Retention Area Fl- * 1 1.016 3389'30 M 

## cl- 2 1'366 2500'47 M External Unito 44'91 ug/ml 43.13 ug/ml

### Condltioma
Date Time

_ Componont Kotontion : 40 Ug/m} Fl— in H2SO4

: 40 ug/mI Cl— ln H2SO4 : 03/'24/'2005 : O9c27:49

LO2.40OmV

Fl- 1' 1O24'000mV Area External

3393.75 M 44.97 2532.13 H 43.66

~



### Component Number Retention Area ExternaI Units Fl— l 1'O0O 3393'75M 44.97 ug/ml cl- 2 1'333 2532.13 M 43.66 uA/m}

2

~ ~~ ~a

### Ca.Iibrati

- 

### on fiile : FI

- 

### xcal

AREA 0.

8391 - 1 

### AMf3iiNT iNJECTFD 0.000 40.QC70


### 1

2

8



### 4

5

~

~

J

~ 

### Avg s.lape nf curve: 84.02 Y-axis intercept= 0.40 Coeff of .l i n r egr =. a. 9tJ 

### Nn. Area Amaunt
0. 0.000 Q.0(}tJ 1: 466.980 5.000 2: 869.350 10.000 3= 1591.275 20.000 4 = 3391 .525 40,000 

### CF
0.000 93.396 

### 86.935 79.564 84.788



# ~

### AMOE1NT INJECl`ED

AREA 0.000 0.00

2516.30 40.000

~ 

### 2

3

4

5 

### CaI. ibration f i 'le : CI.- . cal

Aug s1ape af Gurve = 58 .91 Y--axi.s i.ntercept: 0.00 Cneff af .lin regr : 0.85 Na . Area Amnunt GF
0. 0.000 0.000 0.000 1= 298.510 5.000 59 .7G2 2= 534.225 10.000 53.422 3 : 1127.725 20.000 S6.386 4 K 2516 .30b 40.000 62.908

~ ~~

### (Pnknown 

### ) O.

F]- O. C]- \. 83.6OH MIA 1O16'2O H

~ 

### 2.O3

1 

### 937,50 16.79 -
Conditiono : Da}tiIe" Muakogee, OK z Kiln #1 Enha4st c Run #1 Imp 2 & 3 . : VoIume 250 Dilution 1//1 Date : 03//24/2005 Time : 09:54:54

-1O2.4OOmV 1O24.O0OmV o Aroa Extmnal

CnmPonent Fl-

- Cl2

_
~

~

' /l 

### Number Retentinn Area Extermal Unita
1 0'950 1016'20 M 12.03 ug/ml 2 1,283 937.50 16'79 ug/ml

~~

### 1O24'0OOmV -1O2.4OOmV (unkmwn) O


## (un known) O D- O Cl- 1 'Arou External 27.90 N/A

07.03 K N/A 106.28 H 12.17 Conditiona : DeltiIe ~ Muokogee ° OK

: Kiln #1 Exhamst : Run #1 Imp 2 & 3 c Volume 250 DiIution 1/1 Date : 03/24//2005 Timm : 10:02c04

ComponentFlCl2 Numbmr Retentiun l O'966 2 1'300 Ar*aa ExtmrnaI Unita 1026'29 M 12.17 ug/ml 1022.90 18.23 ug/ml

2049'18 30'41

0 ~ ~ `~

### 1O24.00DmV -1O2.4OOmV uom - ~~ ~~ 

### .- . .. ..
~ 

### (unknoNn) O (uknown) O Fl- 1 C}- 1 Aroa Exbnoa1 0.0 MN

25.40 N/A 1245.60 H 16.21 Conditions c DaItile, Mus,kogee, OK

c KiIn #1 Exhaoot z Run #2 Imp 2 & 3

. : Volu0*» 250 DiIution I/1 Date : 03/24/2005

CompunentFlCiNumbmr Retention 1 l'00D 2 1.350 Aree Extermal Units

1245.60 M 15.21 ug/mI 1045'99 M 18.62 ug/ml

K

4 ~ ~ ~~

### Arma External Unito 1286'62 15.78 Ug/ml

~ 1 0 4 0 

### .88 1 8 

### .54 ug/ml

2327-50 34-32 ComPonent Number Retention Fl— 1 0.966 Cl— 2 1'316

FA Conditimna c Dalti}e ° , MuskuQee, OK

~ 

### Kiln #1 Enhaumt' : Run #2 Imp 2 & 3 : Volume 250 DiIution 1/1 Date 03/24/2005 Time c 10c08z59

—1O2.4OOmV Component Reten (uoknmwn) O. v (mkmwn) O. Fl- O. Cl- 1. )1G

U61 1O24.O0Omt Aroa External 0'20 N/A 34.45 N/A 1286.62 15.78

### N/A 15.77 15.92 (mknown) O Fl- 1 Cl- 1 32.80 1285,YOH 885.06 H Conditions Daltile ° Huskogee, OK

~ 

### Kiln #1 Exhaust z Aun #3 Imp 2 & 3

~ 

### Vo}ume 25(} DiTutIon 1/1 Dat+» : 03/24/2005 Timw : 10c14:19

-1O2.4DOmV 1O24'OODmV

CompmnentFlClN Numbe+r Retentiwn 1 1'O0D 2 1.350 Area ExtermaI Units

1285.90 M 15.77 ug/0l 885.85 M 15.92 ug/ml

2171-75 31-69

0D °

~

### 1O24.0QOmV -1O2.400mV Compopont Rotontivn (oDkmwn) O

F1- O Cl- 1 Aroa External 106.30 N/A

124161 15.18 902.68 16.21

Area ExternaI Units 1243'61 15.18 ug/ml 902'58 16.21 ug/ml

2146-19' 31-39 Component ' FlClNumber Re±ention 1 0.966 2 l'316

2 Conditions c Dalti}e, Muakogee, OK

z KiIn #1 EXhaust : Run #3 Imp 2 & 3 : Volume» 250 Dilution 1/1 Date : 03/24/2005 Time : 10:16:09

~] ~

### Comditions Dzxltile, Muskogwe, OK

~ 

### Ki}n #2 Emhaust

~ 

### Run #1 Imp 2 & 3 : Vo]ume 250 DiIution 1/1 Date z 03/24,/2005 Time : 10:21c13

-1O2.4OOmV 1O24.00OmV

~ 

### mmponeou Remn

r (unknown) O. Fl- O, O- 1. ti 

## on

..........

................ **

.... . ..... .......... ............... 

### Aroa Exhnnal

48.45 N/A 1333.90 M 16.43

ComponentFlClNumber Retentinn Ar*va External Units l 0.983 1333.90 M 16.43 ug/ml 2 1.333 1221.52 M 21'35 uQ/ml

'N'

`

~ ~JCompone 

### nt ReteT



## (un k 

## n o 

## w n) `' \«nKV»w»/ O. (unkmwn> O. Fl- O. Cl- 1. Ar*u Extmnu1 30.65 NW 75.00 NW 40.00 NN 1394.10 M 17.37 1276.15 N 22.14 Conditioms
~ 

### Daltile ° Muskogee, OK

~ 

### KiIn #2 Exhauet

~ 

### Hun #1 Imp 2 & 3 c VoIuma 250 Dilutiun 1/1 Date : 03/24/2005 Time : 10:23:03

-1O2.4O0mV 1024.O0OmV

FlclComponent



### 2 Number Retentimn

l 0.983 2 l'333 Area ExtermaI Unito

1394.10 M 17.27 ug/ml 1276.15 M 22.14 uA/ml

2670-25 39-41

## 1024.00OmV —102.4OOmV component 

## Retention

...........................................

............. 

### (Unhown) 0.6001 Fl

- ................. . ......

.................

............... 

# ci- 1.3661 1 .................. 

### Area External

45.60 N/A 1401.10 M 17,37 1307.06 M 

## 22.58 Conditions z Daltile, Muskogee, OK

z Kiln #2 Fxhaust : Run #2 Imp 2 

## & 3 

## : Volume 250 Dilution 1/1 Date : 03/24/2005 Time 

## : 10:28:12



## 2 1
,



### Component

## Fl

# cl -

ORP 

## Number Retention 1 1.016 2 1.366 Area External Units

1401.10 M 17.37 ug/ml 1:367.(36 M 22.58 ug/ml

2708-16 39-95



## -1 ,-) 

# rj J. 

## u

### 1024.00OmV -1O2.400mV

, _ ~ m~v~'

~ ~~ 

### (unknowo) O hmkmmn\ O Fl- O Cl- 1 Aroa Extmnal 78.00 N/A 22.40 N/A 1489.81 K 18.99 1272.67 H 22.09 Conditiono : DaltiIe" MuskoQee, OK

: Kiln #2 Exhaust ; RUn #2 Imp 2 & 3 : Volu0e 250 DilutIon 1/1 Date : 03/24/2005 Time : 10:30:03

FlC}- Component 

### Number Rmtention 1 O'983 2 1.333 Aree ExtermaI Units

1489.81 M 18.59 ug/m} 1272,67 M, 22'09 ug/ml

N 10

JLu
~

### 1024.0OOmV -102.4OOmV
.- . .. mm -

~~ . ~ . ~m 

### (unknown) O B- 1 C}- 1 43.90 NIA 1640,20 M 20.64 170.21 N 29,43 Conditinns : DaltiIe, Muskogee, QK

c Kiln #2 Exha4ot : Run #3 Imp 2 & 3

~ 

### Volume 250 DIlu±ion 1y1 Date : 03/24/2005 TIme : 10:35:03

^

.

CompnnentFlC

~ 

### -

2 Number Retention 1 1.000 2 1.366 Area External Units

1840.20 M 20-54 ug/ml 1782.21 M 29.43 ug/ml

3422'41 49-97

~ ~U~~

### Conditions t Daltile, Muskogee, OK Kiln #2 Exhaust Run #3 

### Imp 2 & 3 

### Volume 250 

### Dilution 1/1 

### Date = 03/2412005 Time = 10:36:56



### —102.4OOmV 1024.00OmV Component Retention 

## Area External (unknown) 0,300 , ................... .......... ........... ............. ............. ............ . ..... .............. ........... 79.90 

### N/A


## Fl- 0. 1 .........................
. ......... .... 1757.82 

### 21.85 ci- 1.350

........... . ........ 172E65 

## 28.54

21

41 . ..... ; 

# ~

............. . ............ ................. ...................... ...................... ................ ............. 

### Component Number Retention Area External Units Fl— 1 0.983 1757.82 21.85 

### ug/ml ci— 

### 2 1.350 1720.65 

### 28.54 ug/ml

2 3478- , 48 50.39



### J

### Conditimma z Da}tiIe, Muokogf,e, OK : H2SO4 Blank Date : 03/'24/2005 Time : 11:03:22

-1D2.4O0mV 1024'0OOmV Aroa Extmnal

Cmmpmn*nt Number Retentimn Area ExternaI Unito

0 O-OO D-OD

~ . j~ ~ v

### Conditionm : DaltiI*a ° Muskogee, OK : 20 ug/ml Fl- in 82SO4 : 20 uQ/ml Cl- in H2SO4 Date ': 03/24/2005 Time : 11:05c19

-1O2'40OmV lO24.00OmV LI UII



### F1- O. Cl- 1. 1649,15 20.64 1086.70 19.31

4 1

" Component Number Retention Area

~ 

### Fl- 1 0.983 1649.15 Cl- 2 1.300 1086'70 ExtermaI Unito 20'64 ug/ml 19.31 ug/ml

A^

~

## COnditioma c 5 ug/ml Cl— in NaOH Date : 03/24/2005 

## Time : 11:16:07

—1O2.40OmV Compunont Hotoobon 1O24.00OmV Aroa External

(VDkmwn) O. 801.50H Nt'A

Cl- 1. 106.90 H 5,12

Number Retention 

## 2 1.450 Arma ExtermaI Units

106.90 M 5'12 ug/ml

106'90 5'12

### (unkmmn)

Ci0,

1. Area Dtmnal

08,00H N/A

109.75 K 5.15 Cmnditiono : 5 ug/ml CI- in NaOH Date» : 03/24/2005

-102.4000V 1O24.00OmV

Compo 

### nent Number Retontion Area Extersal Units ' Cl- 2 1.433 109.75 M 5.15 ug/ml

1 109-75 5-15

1 jL
~ ~

### Lm 1O24.O0OmV

CnnditioOs : 10 ug/ml Cl— in Na0H Date : 03/24/2005 Time : 11:23:09

—1O2.40OmV Comp000nt Roton

(uokooNn) O.
C}- 1, Area Extmna1

695.85 N/A

281.25 0.00

Compmnent Number Retentimn Area External Wnits Cl— 2 1.483 281.25 10'00 ug/ml

1

-' I ~ ~~ ~
~

### Cnnditi'ona : 10 Vg/mI CI- in NaOH Date : 83/24y2005 Time c 11:25:52

~ 

### } -102-4OOmV

.. .' ^~ m -

~o~~ ~~n

r 

### L8 (Unkmown) O.
Cl- 1. i x1 1024.000mV Aroa [ximnal

715.90 N/A

Component Number Retention Area Externel Unita Cl- 2 1'483 256'20 M 9.28 ug/mI

1 256-20 9-28

1i\ ~~

### Conditimns : 15 ug/ml Cl— ln NaOH Datm : 03/24y2005 Time+ : 11:29:25

—lO2'4OOmV mmpopent ReLe

(umkmmn) O

Cl- 1 1O24'OOOmV Aroa [xtornal

_ Componmnt Number Retention Aree External Units Cl— 2 1.566 454.00 15.{)0 ug/ml "~ ` 1 ' 454-00 15-00

~{p

~~~

### l024.00OmV

Conditimns : 15 4g/ml Cl— in NaUH Date : Ti0m c 11:35:14

—lO2-4OOmV ----' Rete 

### D tion



### (onknown) 0.

O- 1. Airou External

875,80 N/A

451.00N 14.92 52.9OH N/A

Component Numbmr Retentimn Area External Unitm cl— 2 1.533 451'00 M 14,92 uQ/ml

1 451'00 14'92

JL

~ 

### «

### N/A 1.12 17.24 563.10 \04.83M 638.50H 1024.00DmV Arou Edernal -1O2'4OOmV

. '

. . .. mm ~no~ n~o



### (unkmmn) Fl_ Cl' O

~ 

### 1 Conditimna : 20 ug/mI CI- in NaOH Date z 03/24/2005 Time : 11:30:41

CVmponentFlclNumber Retention 1 1.150 2 1.466 Area ExternaI Units 104.83 M 1'12 ug/ml 638.50 M 17.24 ug/ml

K

~ ~ c~

### Conditzons : 20 ug7ml Cl— in NatlN Date i 03/24f2005 

### Time = 1 1 = 42.

~ 

### 45

-°102 . 4t7OmV 

## Componenlu Re'Lention

(iinknown) 0. F1- 1. C1- 1, 1024 .C7OGmV 

## Area External

558.90 NlA 96.38 M 1.03 581.41 Pf 19.08



## Campanent F1--

# ct2 

## Number Retention
1- 1.150 

### 2 1.453 Area Extez

- nal. Units 96.38 M 1.03 ugJml 581.41 M 19.08 ug/ml_

677.80 20 _ 12



## ~ ~ ~

### AMOtJNT IN.7ECTED

AREA 0.000 0.000

609.955 20.000
1

?

3

4

5 

### Caiibration file z CI- _0a1.



## Avg slope of curve= 30,50 Y--axis intercept= 0.00 Coeff of 1 i n rogr = 0.82


## No. Aroa Amount CF
0= 0.000 0.000 0.000 

### 1- 108.325 5.000 21.665 2= 268.725 10.000 26.873 3= 454.060 15 . OOC7 30.271 4 = 609.955 20.000 30.498

~ `'': I

~..~~

### CVnditioma : DalitIe, MushoQee, QK z Kiln #2 Exhauat : Run #1 Impa 4 & 5 : VoIume 250 DlIution 1/2 Date c 03/24/2005 Tima : 12:23:49

—102.4OOmV componept Reten .m

(unkoown) 0. UG

C1' L lO24'O0O0V Aroa [xtornul

178.90 NIA

305.00 10.98

Compnnent Number Retention Area External Units Cl— 2 1.486 305-00 10'98 ug/ml ' 1

~ <~ /

### Cmnditioma : Dalitlm, Muohogee, OK : Kiln #1 ExhaUet : Flun #1 Impa 4 & 5 : Volume 250 DiIutinn 1/2 Oate z 03,/24/2005 Time : 12:28:46

-IO2.400mV Componont Rotontino

(unkmmn) O.
Cl- 1. IO24'OD0mV Arva Exbnna}

182.80 N/A

328.46 K 11.61

CVmponent Mumbar Retention Area External Unita Cl- 2 1.466 328'45 M 11'61 uQ/mI

1 328'45 11-61

~~ 

### w

### 1O24'000mV -1O2.4OOmV Componoot Retentioo

(onknown) O C}- 1 322.70 N/A
490.00 H 16.16 ConditIons z Da|itle" Muokogee ° OK
7 

### Kiln #1 Exhaust z Run #2 Zmpa 4 & 5 - VoIume 250 niIution 1/2 Date : 03/24/2005 Time : 12:33z44

Compowent Number Rmtention Area External Dnite Cl- 2 1.466 490.00 M 16.15 uQ/ml

ki 490.00 16.15

-f e

~~~ ~~

## 1024.00OmV -1O2.4ODmV .-- ^

.. .. Aroa [xternal

0. 1, 1. N/A N/A 16.26 (unkmmn) (mkoown) ^' 329.30 53.00 493.16 H CVnditimma : Dalitle, Mushmgee, QK

: Kiln #1 Exhauat : Run #2 Zmpo 4 & 5 : VoIume 250 DiIutimn 1/'2 Dato c 03/24/2005 

## Time z 12:38:47

Component Number Retention Area Extermal Units Cl- 2 1.450 493-15 M 16'25 ug/mI

1 493'15 16-25

JLa 

## u

### Cmnditloma : DalltIe, Muskngee, OK : Kiln #1 Exhauot : Run 43 Z0pa 4 & 5 ' r Volume 250 DilutiVn 1/2 Date : 03/24/2005 TIme : 22:44:02

-102.4O0mV LI OD



## (un known) O.

1. (mkmwn) 1. 

# c {

- 

### ' 1, 1024'0O0mV Aron Extmnal

246.60 N/A 178.61 1.91 56.25 H/A 507.30 H 16,71

Component Number Rmtentimn Area External Units Fl- 1 1'016 178,61 1.91 ug/mI Cl- 2 1.450 507'30 M 16'71 uA/ml

2 685.91 18-62

~ ~ ~ ~-

### ' Conditions : Dalitle, Muskogee, 0{ c Kiln #1 Exhebst

~ 

### c Run #3 Zmpo 4 -& S : Volumm 250 DIIuti(»n 1/2 r Date : 03/24/2005 '| Time 12:49:03

-1O2.4O0mV

. Component Raten
` 

## (un known) O. 1. (mkmmn) 1.

~~ ' 

### ^^ 1. uio fl 

### 1O24'O0O0V Aroa Extmnal

20.74N N/A 195.92 H 2.10 100.04 N K/A 563.30 H 0.50

CmmpVnent Number Retentic>n Fl- 1 1.000 Cl- 2 1'450

FA Area External Unita 195.92 M 2'10 ug/ml 563.30 M 18'50 ug/ml

759-22 20'60

~ ~~~

### N/A 2.27 n/n 17.56 240.62 211.68 68.91 B4.00H 1O24.00OmV Arou External -1O2.40OmV

_ t R e 

### t er



### '



## (un known) 

## Fl- (unkmw8)CiO.

L 1. 1. Conditiono : Dalitle, Muokogee" 0K

: Kiln #2 Exhauot : RuD #1 Impa 4 & 5 : Vwlume 250 Dilutlmn 1/2 Date : 03/24/:

~ 

### 005 Timm : 12:54:13

Component Number Retention Area External Unita Fl- 1 1'00O 211.58 2'27 ug/ml Cl- 2 1.450 534'00 M 17.56 ug/ml

iN 745'58 19-83

~~~ 

### IS ~

### 1024'O0OmV

Conditions DalitIe, Muskogee° DK

~ 

### Kiln #2 E%hauot : Run #1 Imps 4 & 5

~ 

### Volume 350 DilutIon 1/2 Date : 03/24//2005 Timm 12:59:18

-102.4O0mV

_ t _ t '

(Lin 

### known) 0

1 (mknown) 1

## ciAroa External

2@.@ N/A 196.25 2.1O 65.35 N@ 531.10 17.47

Cmmponent Number Retention Area External Unita Fl- 1 1.016 196.25 2.10 ug/Unl Cl- 2 1.450 531'10 17.47 ug/ml

~ 

### 727-35 19-57

~ 

### J

~ 

### t

### Condltinma c DalitIe, Mushogme, 0K : Kiln #2 Exhauot : Run #2 Impa 4 & 5 : VoTume* 250 Dilutimn 1/2 Date : 03/24/2005 Time r 13c04r32

-lD2.4O0mV component Retention ^

~ (unknown) 0. Fl- \. Cl' 1. 1O24.0DOmV Area Extornal

250.40 H N/A 235.97 N 2.53 662,06 M 21`67

Componmnt Fl- Cl-' Number Retention Area External Unito 1 1'000 235'97 M. 2.53 ug/mT 2 1'466 662.05 M 21.67 ug/ml

K

A-3 ~

### 1024.00OmV -102.4OOmV (un n) 0. (unknown) O. Fl- 1. Cl- 1. Arou ExterUa} 51.90 N/A
254.39 N/A 237.17 2.54 700.70 M 22.91 Cmnditiono : DalitIe, Muokogee, DK

z Kiln #2 Exhauot

~ 

### Run #2 Impo 4 & 5

~ 

### Volume 250 Dilution 1/2 Date : 03/'24/2005 TIme : 13c09c37

Component 

### Numt`er Hetention Arwa External Units Fl- 1 1.000 237,17 2'54 ug/mI cl- 2 1.450 700.70 M 22.91 ug/ml

N

JL ^ D

### Condi-tiVns : Dalitle, Mushogee, OK : KiIn #2 Exhauet : Run #3 Impo 4 & 5 z Volume 250 Dilutinn 1/2 Date z 03//24/2005 Time : 13:14:42
-1O2,4O00V 1Q24.00DmV

(0kmmn) 0.81 Fl- 1, Cl- 1.46 259.52N N/A 253.67 N 2.71 550.30 H 18.0 0

,

Compunent Number Retmntlmn Ar*a Extermal Unita Fl- 1 1.000 253.57 M 2.71 uQ/ml cl- 2 1.466 550'30 M 18.09 ug/ml

F -P 803'87 20'80

1 p r ~ L~/

### Aroa [xterna1

(unkmwn\ O. F}- L Cl- 1. 264,86 N/A Z3;.93 2.56 540.90

Area ExternaI Units 238'93 2.56 ug/ml 540'90 17'79 ug/m}

779-83 26'34 ` Compnnent Number Retentlon Fl- 1 1.000 Cl- 2 1,450

FA Conditiono : Dalitlf*, Musko0ee, 0<

: Kiln #2 Exhauot : Run #3 Impa 4 & 5 c Volume 250 Dilution 1/2 Date : 03~/24/2005 Time : I3:19:52

-102.4OOmV 1024'O00mV -

~~~

## Cond 4

Ltions : Dalitle, Muskogee, OK

: NaOH Blank Date z 03/24/2005 Tirrie , 13-

- 58:07

102.400mV Component Retenti

(unknown) 0.81

(unknown) L 1024.00OmV Area External

1086.40 N/A

450.55 

## NIA

Component Number Retention Area External Units

0 0-00 0.00

A-

## 1024'OOOmV -lO2.4OOmV componont RetentioK___'

(uokmmn) 0.81
Cl- 1.4( Aroo [Xbnna}

767.50 H/A Cnnditimns : DaIitTe, Muokogee, 0{

z 10 ugymI CI- in NaQH Da\te : 03/24/2005 Time : 14:01:13

N

Component Number 

## Retention Area Extermal Unita 

## Cl- 2 1.466 304'02 10'95 ug/ml

791 304'02 10-95



# 40

# Appendix C

### I
1 0 

## FlEi LD DATz-k PLANTT: 

# Pw DATF-:.'71Z, , (l P,EPET!TiaN: I 

### LOCATIOIN

, (SOURCEF. 

### ):,kl

l lll fg OPERATOR: 4.:j — SAlv2LE TRAINT — 5" ' : f2 f , 

### INMTER BOX

~ 

### : BAROMETRIC PRESSURE: ZI 

# ~ -Av _3lF__NTI` TElvfPERAT

- 0

7 RE: p 5 -- .ASSUNIF_D 

### MOISTURE:, PROBE LENGTH: 

### NOZZLE DLALMETER; z STACK 

### DIAAI

- ETER: METER H: C 

### FACTOR: METER CO-EFFICIENT: 7 

### FILTER TARE: PRE-TEST LEAK CHECJ

~ 

### ._ 

### Meter.0, 65 cu.ft. @ 

### in. HG 

### pitntr i no 7 

### i in R?n 

### i

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# F ; ria!



## 16 0 _2 

## f zz, =4 

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### ' Meter: 6 

### l'o

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## DATEE: cylitr

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## 5_ REPETITION: -0 

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### UR C k// 

### OPERATOR: dZ-3

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### AM-PLE TRAIN

, IvMTER BOX BAROMETRIC PRE8SURE:Z,

~ 

### j, ANMIENT TEMPE RATTi

- PE: 

# '7 0 

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### o-963- 7 STACK 

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~ ' C 

### FACTOR:, 9~ METER CO-EFFICIENT:,

~ 

### 7.t/ FILTEA TARE: PRE-TEST LEAK CHECK 

### Meter: c7- 

### cu.ft. 

# @

1 ,9 in. HG Pitots: in. H20 

## FIELD DATA

!MPTINGERS ui ~ 

### `al I 

### al Fillal 

## k 1 0 3 ,41 > l "L)l-v)'j-(5"" 00 C90

CO2 02 

# q /t/l


### POST-TEST 

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## in

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# 3 0 V 

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### 02 

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### cuft @ /,

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PLANT: r

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~



### =: METER B OX y: ( Z :Y2 te ~~~ 

### B AROMETRIC PRESSURE: Z7 •`( AIdII3IENT 1EM1'ERATURE: ~ ~' 1 4 

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## SOTemperature Wieter Cafibrations

iti/eter Box #. 11 Date: 03J03J05 

### Cafibrated By: RT

Emtech Thermo Degrees F Checker Probe Stack Oven Exit Auxil ary
Point 1 32 29 30 29 30 30
Point 2 212 210 210 210 210 211
Point 3 752 750 751 750 751 751

Emtech Thermo Degrees it Checker Probe Stack Oven Exit Auxiliary
Point 1 492 489 490 489 490 490
Point 2 672 670 670 670 670 671
Point 3 1212 1210 1211 1210 1211 1211

Percent Difference 

### Probe Stack Oven Exit AuxifEary
Poini 1 0.609756 0.406504 0.609756 0.406504 0.406504
Point 2 0.297619 0.297619 0.297619 0.297619 0.14881
Point 3 0.165017 0.082508 0.165017 0.082508 0.082508



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### Nfeter Box #: 12 Date: 03/23/05 Calibrated By: RT

Emtech Thermo Degrees F Checker Probe Stack Oven Exit Auxillary
Point 1 32 31 31 31 31 31
Point 2 212 212 212 212 212 212
Point 3 752 755 755 755 755 755

Emtech Thermo Degrees R Checker Probe Stack Oven Exit Auxiliary
Point 1 492 491 491 491 491 491
Point 2 672 672 672 672 672 672
Point 3 1212 1215 1215 1215 1215 1215

Percent Difference Probe Stack Oven Exit Auxillary
Point 1 0.203252 0.203252 0.203252 0.203252 0.203252
Point 2 0 0 0 0 0
Point 3 0.246914 0.246914 0.246914 0.246914 0.246914



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