**Controlled PM10 Speciation from AP-42 Tables 1.3-2 & 1.3-4**

**Uncontrolled Utility Residual Oil Boiler** Assumes firing of # **2** oil with a sulfur content of **0.05** %S; therefore, A = 0.426 f(RH) = **1** Assumes heating value of **135,000** Btu/Gal and a heat input of **556** mmBtu/hr Uncontrolled PM10 Emissions **(Bold**Values from Tables 1.3-2 and 1.3-4.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mGal) (lb/mGal) (lb/mGal) Coef. (lb/mGal) (lb/mGal) Coef. (lb/mGal) Coef. (lb/mGal) (lb/mGal) Type Ext.Coef. (lb/mGal) Type Ext.Coef. Utility 4.01 **2.51** 0.68 0.6 **1.83** 1.70 1 0.14 10 **1.5** 1.28 SO4 3*f(RH) 0.23 SOA 4 Uncontrolled PM10 Emissions Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (% of Total) (% of Total) (% of Total) Coef. (% of Total) (% of Total) Coef. (% of Total) Coef. (% of Total) (% of Total) Type Ext.Coef. (% of Total) Type Ext.Coef. Utility 100% 62.6% 17.0% 0.6 45.6% 42.3% 1 3.4% 10 37.4% 31.8% SO4 3*f(RH) 5.6% SOA 4 Uncontrolled PM10 Emissions Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Utility 0.03 0.02 0.01 0.6 0.01 0.01 1 0.001 10 0.01 0.01 SO4 3*f(RH) 0.002 SOA 4 **If you are given Total PM10 emissions in lb/hr:** Uncontrolled PM10 Emissions **(Bold**Value is **Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef. Utility **6.7** 4.2 1.1 0.6 3.0 2.8 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4 Weighted Extinction 0.7 2.8 2.2 6.3 1.5 2.0 **If you are given Total PM10 emissions in lb/mmBtu:** Uncontrolled PM10 Emissions **(Bold**Value is **Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Utility **0.013** 0.008 0.002 0.6 0.006 0.005 1 0.000 10 0.005 0.004 SO4 3 0.001 SOA 4

Uncontrolled PM10 Emissions **(Bold**values from Table 1.3-2 and from Table 6 of EPA’s January 2002 DRAFT “Catalog of Global Emissions Inventories and Emission Inventory Tools for Black Carbon.”) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (% of Total) (% of Total) (% of Filterable) Coef. (% of Filterable) (% of Filterable) 1 (% of Filterable) Coef. (% of Total) (% of Condensible) Type Ext.Coef. (% of Condensible) Type Ext.Coef. Utility 100% 62.6% 27.1% 0.6 72.9% 67.5% 1 5.4% 10 37.4% **85%** SO4 3 **15%** SOA 4 (% of Fine) Coef. (% of Fine) Coef. 92.6% 1 **7.4%** 10 **If you are given Filterable PM10 emissions in lb/hr:** Uncontrolled PM10 Emissions **(Bold**Value is **Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/hr) (lb/hr) (lb/hr) Coef. (lb/hr) (lb/hr) Coef. (lb/hr) Coef. (lb/hr) (lb/hr) Type Ext.Coef. (lb/hr) Type Ext.Coef. Utility 6.7 **4.2** 1.1 0.6 3.0 2.8 1 0.2 10 2.5 2.1 SO4 3 0.4 SOA 4 **If you are given Filterable PM10 emissions in lb/mmBtu:** Uncontrolled PM10 Emissions **(Bold**Value is **Input**by user.) Boiler Total PM10 Filterable Coarse Ext. Fine Fine Soil Ext. Fine EC Ext. Condensible CPM IOR Particle CPM OR Particle Type (lb/mmBtu) (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Coef. (lb/mmBtu) Coef. (lb/mmBtu) (lb/mmBtu) Type Ext.Coef. (lb/mmBtu) Type Ext.Coef. Utility 0.013 **0.008** 0.002 0.6 0.006 0.005 1 0.000 10 0.005 0.004 SO4 3 0.001 SOA 4 Coarse 17.0% Coarse 1.1 Fine Soil 42.3% Fine Soil 2.8 Fine EC 3.4% Fine EC 0.2 CPM IOR 31.8% CPM IOR 2.1 CPM OR 5.6% CPM OR 0.4

100.0% 6.7

# 17.0%

42.3% 3.4% 31.8% 5.6% 

# Uncontrolled **Residual Oil** **- fired Utility Boiler PM10** **Speciation Profile** 

Coarse Fine Soil Fine EC CPM IOR CPM OR

# 1.1

2.8 0.2 2.1 0.4 

# Uncontrolled **Resdiual Oil** **- fired Utility Boiler PM10**  **Emissions (lb/hr)** 

Coarse Fine Soil Fine EC CPM IOR CPM OR

# Uncontrolled Residual Oil-fired Utility Boiler

**from A P-42 Table 1.3-4**  (User **may**directly

input**filterable**emission rate into cell E26 in lb/hr) Particle Cumulative Mass Fraction of PM10 Particle Emissions Size < Stated Size < Stated Size Size Range by size (um) **UNC** (%) (um) (lb/hr) 10 71% 100% 10-6 0.8 6 58% 82% 6-2.5 0.4 2.5 52% 73% 2.5-1.25 0.5 1.25 43% 61% 1.25-1.0 0.2 1 39% 55% 1.0-625 1.1 0.625 20% 28% 0.625-0 1.2
**CA LPUFF**  **Filterable Filterable**  Particle Particle Size Fraction Emissions Extinction Emissions Size (um) Range (um) (% of Total) (lb/hr) Coef. (g/sec) 8 10-6 18% 0.8 0.6 0.10 4.25 6-2.5 8% 0.4 0.6 0.04 27% Coarse >/= 2.5 micron 1.88 2.5-1.25 13% 0.5 1 0.07 73% Fine Soil </= 2.5 micron **1.25** 1.25-1 6% 0.2 1 0.03 0.813 1.6-25 27% 1.1 1 0.14 **0.625** 0.625-0 28% 1.2 1 0.12 10 0.03 7.4% of Fine is EC Totals 100% 4.2 0.53

# 18%

8%

13%

6% 27% 28% 

# Uncontrolled **Residual Oil** **- fired**  **Utility B** **oiler Fraction of Filterable**  **PM10**

10
-6 6
-2.5 2.5
-1.25 1.25
-1 1.6
-25 0.625
-0

# 0.8

0.4

0.5

0.2 1.1 1.2 **Uncontrolled Residual** **Oil -** **fired Utility B** **oiler Filterable PM10 Emissions (lb/hr) in Each** **Size Range**

10
-6 6
-2.5 2.5
-1.25 1.25
-1.0 1.0
-625 0.625
-0



# 0.2 1.1