p.1 

OAR Box 1413 

Prepped by Ollie Stewart 

Document Number: 

4.7) 11-1-47 

Docket Number: 

A-94-52 

Printed 7/9/2008 3:11:22 PM Sheet 47 of 114 
P.2 

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Exhaust Emission Sampling 

Thermo-Oxidizer Efficiency Testing 

Composite Technology, Inc., Ft. Worth, TX 

July 2, 1991 

Armstrong Environmental, Inc. 

Project W-1065-91 

Report Prepared For: 

Mr. Tom Walczyk 

Composite Technology, Inc. 

1005 Blue Mound Road 

Ft. Worth, TX 76131 

Report Prepared July 3, 1991 By 

Armstrong Environmental, Inc. 

4747 Irving Blvd. #204 

Dallas, Texas 75247 

(214) 631 - 0021 
P.3 

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h. INTRODUCTION 

A series of tests were conducted on the Thermo-Oxidizer inlet and 

exhaust stacks at the Composite Technology, Inc. facility in 

Fort Worth, TX on July 2, 1991. 

The purpose of this test series was to determine the total 

concentration of VOCs on the inlet and exhaust stack and 

to determine the efficiency of the Thermo-Oxidizer. 

Testing followed procedures outlined in Title 40: Code of Federal 

Regulations (40:CFR). 

Sampling was conducted by Joe Barrera, Jeff Lovett, and Jerry 

Salinas of Armstrong Environmental, Inc. using two Beckman Model 

400A FID analyzers, and a HACH Series 100 GC/FID. 

Present during the test series were Bill Chafin and James Sandel 

of the Ft. Worth Texas Air Control Board. 

Testing was conducted over a a five hour period. 

Submitted by: 

Armstrong Environmental, Inc. 

eg) g^& AAA*L\S6US 

Joe Barrera 

Project Manager 

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SUMMARY OF EMISSIONS TEST DATA 

TABLE: 1 

PLANT: Composite Technology 

OPERATOR: J. Barrera, J. Lovett, & J. Salinas 

LOCATION: Thermo-Oxidizer Inlet 

TEST DATE: 

REPETITION: 

STACK GAS 

Temperature, F 

Velocity, fps 

Volume Flow, acfm 

scfm 

scfh 

Moisture, % 

C02, % 

02, % 

SAMPLE 

Start Time, hrs:min 

Finish Time, hrs:min 

VOC asi C3Hf 

Concentration,'ppm 

Emissions, lbs/hr 

C^tHtfA^) 

2/91 

1 

93.88 

38.91 

14079 

13263 

795782 

1.0 

0 

20.0 

10:14am 

11:15am 

784.7 

71.13 

7/2/91 

2 

94.38 

38.23 

13832 

13019 

781117 

1.0 

0 

20.0 

12:36pm 

1:37pm 

709.8 

63.16 

7/2/91 

3 

96.25 

36.02 

13033 

12222 

733299 

1.0 

0 

20.0 

1:55pm 

3:00pm 

698.3 

58.33 £L{,-M [fyfrWL <ufi-

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SUMMARY 

TABLE: 2 

OF EMISSIONS 

PLANT: Composite Technology 

OPERATOR: J. Barrera, J. Lovett, & J. 

LOCATION: Thermo-Oxidizer Exhaust 

TEST DATE: 

REPETITION: 

STACK GAS 

Temperature, F 

Velocity, fps 

Volume Flow, acfm 

scfm 

scfh 

Moisture, % 

C02, % 

02, % 

SAMPLE 

Start Time, hrs:min 

Finish Time, hrs:min 

SL. y ^pVO C as C3H8 ^>>

 ! 

).f p ^(Concentration, ppm 

<*5r 

H***-

"""* <2 

^ 

Emissions, lbs/hr 

• TOLUENE rc, fo) 

1

 Concentration, ppm 

Emissions, lbs/hr 

- STYRENE C^iS 

Concentration, ppm 

Emissions, lbs/hr 

METHYL ETHYL KETONE 

Concentration, ppm 

pv. LEmissions, lbs/hr 

7/2/91 

1 

453.9 

48.92 

23117 

13073 

784389 

2.0 

0 

20.0 

10:14am 

11:15am 

1.402 

0.125 

1.14 

0.213 

0.57 

0.12 

ND 

ND 

4 

H' 

TEST DATA 

Salinas 

7/2/91 

2 

456.4 

51.90 

24526 

13829 

829766 

2.0 

0 

20.0 

12:36pm 

1:37pm 

1.340 

0.127 

3.04 

0.600 

2.28 

0.509 

0.12 

0.019 

i 

7/2/91 

3 

• 462.6 

50.48 

23855 

13362 

801738 

2.0 

0 

20.0 

1:55pm 

3:00pm 

1.392 ^ 

• — 0.127/ § 

1.37 / A^ 

0.261 / ^T 

V 

0.85 / N 

0.183/ ^ 

ND 

ND 

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III PROCEDURES 

The procedure for emission testing followed USEPA methods as 

outlined in Appendix A of Title 40: Code of Federal Regulations. 

The following methods were used: 

Method 

1 

18 

25A 

Title 

Sample and Velocity Traverses for Stationary 

Sources 

Determination of Stack Gas Velocity (Standard 

Pitot Tube) 

Determination of C02, 02, Excess Air, and Dry 

Molecular Weight 

Measurement of Gaseous Organic Compound 

Emissions by Gas Chromatography 

Determination of Total Gasous Organic 

Concentration Using a Flame Ionization 

Analyzer 

The FID analyzers were spanned with Certified 988.4 ppm, 196.4 

ppm, and 27.2ppm in nitrogen standards. The standards were 

introduced from the stack end of the sample line with Tedlar gas 

bags. 

Velocity traverses were conducted immediately after each run at 

16 points, 8 points per traverse. 

C02 and 02 were determimned using Fyrite analyzers. 

VOC component breakdown was determined using a HACH Series 100 

GC/FID. Integrated gas bag samples were taken using a 

parastalltic pump from the exhaust line of the FID used to sample 

the incinerator exhaust. Standards and samples were introduced 

to the GC via a heated 5 ml sample loop. 

J 

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38', 

Breeching 

Grade 

35 ft . 

10 ft , 6 in. 

12 ft . 5 in. 

1 

Composite Technologies 

Incinerator Exhaust 

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22 inches 

28 inches 

Composite Technologies 

Incinerator Inlet Duct 

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APPENDIX A 

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CpmpositeJTechnology^ 

Thermo-Oxidizer Inlet 

Repetition #1 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS. DRY BASIS, MD 

(.44 * %C02) + (.32 * % 02) + (.28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS. WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) = 28.692 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.86544 

STACK GAS VELOCITY. FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 38.91469 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 14079.34 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 795782.1 

%C02 = 0 

%02 = 20 

%CO - 0 

%N2 = 80 

STACK TEMPERATURE, F = 93.88 

SQUARE ROOT OF DELTA P = .5719 

STATIC PRESSURE, IN H20 = -.47 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 1 

AREA OF STACK, SQUARE FT. = 6.03 / 

PITOT CO-EFFICIENT, CP = .99 

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P.11 

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Composite Technology 

Thermo-Oxidizer Inlet 

Repetition #2 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS, DRY BASIS, MD 

(.44 * %C02) + (.32 * % 02) + (.28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS, WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) » 28.692 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.86691 

STACK GAS VELOCITY, FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 38.23014 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 13831.66 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 781116.8 

%C02 = 0 

%02 = 20 

%CO »• 0 

%N2 =8 0 

STACK TEMPERATURE, F = 94.38 

SQUARE ROOT OF DELTA P = .5616 

STATIC PRESSURE, IN H20 = -.45 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 1 i 

AREA OF STACK, SQUARE FT. = 6.03 

PITOT CO-EFFICIENT, CP = .99 

1 

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Composite Technology 

Thermo-Oxidizer Inlet 

Repetition #3 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS. DRY BASIS. MD 

(.44 * %C02) + (.32 * % 02) + (.28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS, WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) = 28.692 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.85662 

STACK GAS VELOCITY, FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 36.02327 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 13033.22 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 733299.1 

%C02 = 0 

%02 = 20 

%CO = 0 

%N2 =8 0 

STACK TEMPERATURE, F = 96.25 

SQUARE ROOT OF DELTA P = .5282 

STATIC PRESSURE, IN H20 = -.59 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 1 

AREA OF STACK, SQUARE FT. = 6.03 

PITOT CO-EFFICIENT, CP = .99 

I 

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P.13 

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Composite Technology 

Thermo-Oxidizer Exhaust 

Repetition #1 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS, DRY BASIS, MD 

(.44 * %C02) + (.32 * % 02) + (.28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS, WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) = 28.584 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.8853 

STACK GAS VELOCITY, FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 48.91769 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 23116.54 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 784388.8 

%C02 = 0 

%02- = 20 

%CO = 0 

%N2 = 80 

STACK TEMPERATURE, F = 453.9 

SQUARE ROOT OF DELTA P - .5588 

STATIC PRESSURE, IN H20 = -.2 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 2 

AREA OF,STACK, SQUARE FT. = 7.876 

PITOT CO-EFFICIENT, CP = .99 

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Composite Technology 

Thermo-Oxidizer Exhaust 

Repetition #2 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS, DRY BASIS, MD 

(.44 * %C02) + (.32 * % 02) + (,28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS. WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) = 28.584 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.87868 

STACK GAS VELOCITY, FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 51.90063 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 24526.16 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 829765.7 

%C02 = 0 

%02 =2 0 

%C0 = 0 

%N2 = 80 

STACK TEMPERATURE, F = 456.4 

SQUARE ROOT OF DELTA P = .592 

STATIC PRESSURE, IN H20 = -.29 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 2 

AREA OF STACK, SQUARE FT. = 7.876 

PITOT CO-EFFICIENT, CP = .99 

13 
P.15 

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Composite Technology 

Thermo-Oxidizer Exhaust 

Repetition #3 

7/2/91 

MOLECULAR WEIGHT OF STACK GAS. DRY BASIS, MD 

(.44 * %C02) + (.32 * % 02) + (.28 * (N2 + CO)) = 28.8 

MOLECULAR WEIGHT OF STACK GAS, WET BASIS, MS 

MD * (1 - BWS) + (18 * BWS) = 28.584 

STACK GAS PRESSURE, IN HG, PS 

PBAR + (STATIC/13.6) = 29.88235 

STACK GAS VELOCITY, FPS 

85.49 * CP * (SQR P(TS / (PS * MS))) = 50.4806 

VOLUME FLOW RATE, ACFM 

60 * AS * VS = 23855.11 

VOLUME FLOW RATE, SCFH 

3600 * (1 - BWS) * VS * AS * ((528 * PBAR) / (TS * 29.92)) = 801738 

%C02 = 0 

%02 = 20 

%CO = 0 

%N2 = 80 

STACK TEMPERATURE, F = 462.6 

SQUARE ROOT OF DELTA P = .5739 

STATIC PRESSURE, IN H20 = -.24 

BAROMETRIC PRESSURE, IN HG = 29.9 

PERCENT WATER VAPOR (BWS * 100) = 2 

AREA OF STACK, SQUARE FT. = 7.876 

PITOT CO-EFFICIENT, CP = .99 

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CALCULATION SUMMARY FOR «** ^\yc^c 5-k^-vro/ 

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7/2/91 

LOCATION # 1 

SAMPLER # 1 

SAMPLE VOLUME. STANDARD CONDITIONS 

V * (P / 760) *((298 / (T + 273) = 12.62039 STANDARD LITERS 

SAMPLE CONCENTRATION. PPM 

(CT *24.47) / (VS * MW) = 16.8497 PPM 

SAMPLE VOLUME. LITERS =12. 7 

BAROMETRIC PRESSURE. MM HG = 759.46 

AMBIENT TEMPERATURE. C = 26.66667 

SAMPLE WEIGHT. MICROGRAMS CT = 905 

MOLECULAR WEIGHT OF mek, MW = 104.14 

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CALCULATION SUMMARY FOR mek £4**~*(«vrc( 

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LOCATION # 1 

SAMPLER # 1 

SAMPLE VOLUME. STANDARD CONDITIONS 

V * (P / 760) *((298 / (T + 273) = 12.62039 STANDARD LITERS 

SAMPLE CONCENTRATION. PPM 

(CT *24.47) / (VS * MW) = 32.4723 PPM 

i 

SAMPLE VOLUME. LITERS = 12.7 

BAROMETRIC PRESSURE. MM HG = 759.46 

AMBIENT TEMPERATURE. C = 26.66667 

SAMPLE WEIGHT. MICROGRAMS CT = 1207.5 

MOLECULAR WEIGHT OF inek, MW = 72.1 

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SAMPLE VOLUME. STANDARD CONDITIONS 

V * (P / 760) *((298 / (T + 273) = 12.62039 STANDARD LITERS 

SAMPLE CONCENTRATION. PPM 

(CT *24.47) / (VS * MW) = 9.112719 PPM 

SAMPLE VOLUME. LITERS = 12.7 

BAROMETRIC PRESSURE. MM HG = 759.46 

AMBIENT TEMPERATURE. C = 26.66667 

SAMPLE WEIGHT. MICROGRAMS CT = 433 

MOLECULAR WEIGHT OF mek, MW = 92.13 

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Scott Specialty Gases 8cott 

a division of Ski^ri Froa I 

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Cuteiir i '' 

HUHOIIICHV1I0KIEHTAL 

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27.20 

27.20 

27.20 

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100.00 

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13.51 

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41.41 4? 4M 0 41.92 1.24 

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10.11 11 19.50 10.20 -1.57 

0.00 0 0.00 0.10 1.00 

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Tour P.O. I i 1002 

Eipiration Date i 9-14-92 

Cylinder Nuaber I AAL-14732 

Cylinder Prenure 1900 paig 

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PROPANE 

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lllttttltlllltlttllltltlttlttltttltttttllttl 

ENTATIO N 

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8(1181 

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ZERO ! TEST 

BAS ! 6AS 

(aV) ! (aV) 

DATE I 

RESULTS !' 

PPH ! 

REFERENCE 

SAS 

CONC. (aV) 

0.00 

0.00 

0.00 

39.90 

39.50 

39.50 

CALCULATED 

RESULTS 

196.4 

196.4 

196.4 

196.4 

196.4 

196.4 

498.5 PPH 100.00 

100.00 

100.00 

AVERAGE l 196.4 PPH 

ANALYTICAL PRINCIPLE 

FLAKE IONIZATION DETECTOR 

CALIBRATION CURVE 1 it 0E6REE 

SRNI CONC. SPLIT DVN FITTED PERCENT 

(CRN t) PPH PT (I) (aV) VALUE ERROR 

2645A 498.5 100 100.00 

169.2 3B 38.20 

100.0 20 20.30 

9B.S4 

0.0000 

20 19.90 

0 0.00 

0 

0 

498.5 

189.9 

100.6 

9B.SS 

0.0000 

0.0000 

0.00 

-0.00 

0.40 

0.58 

0.04 

0.00 

0.00 

0.00 

I GHIS - SAS MANUFACTURER'S miMc%m&-*-*Ccm w &&})*ZStmM & 

2643 98.54 LOM 19.90 

N/A 169.2 BHISt 38.20 

/^a/i^mU> 

98.58 

189.9 

0.01 

0.40 
WS Scott Specialty Gases a division of 

Seott Environmental Technology, Inc. 

1200 COMBERMERE STREET, TROY, MICHIGAN 48084 (313) 680-2060 

Cuitoaor i 

AIUISTRQNB ENVIRONMENTAL 

TONARHSTROMB 

4747 IRVINS BLVO 

SUITE 204 

DALLAS, TI. 75247 

tttt CERTIFICATE OF ANALYSIS - EPA PROTOCOL BASES tilt 

PERFORMED ACCORDINB TO SECTION 3.0.4 

Certified Per Traceability Procedure I 81 

Protocol I 1 

Fiiel 

Traceable 

F040ft 

Shipped Froa I Scott Troy 

Our Project I i 520722 

Your P.O. I i 1002 

Expiration Date i 9-14-92 

Cylinder Nuaber ALN-004374 

Cylinder Prenure 1900 piig 

Certified Accuracy 1 Z 

REFERENC E STD SAS ANALYZE R 

IIIIIIIIIIIIMSIIIItltllttltttttlttttttlfllt 

••: • '..CERTIFIED I 

COMPONENT ' CONC. I 

PROPANE 988.4 PPH. I 

V - . ••.•'"••: I 

t 

-XiALANCE SAS I HITROGEN . t 

I 

i^llllttlttllltlttttlltttllltttltttttttttttt 

SRU 

(CRN I ) 

& ANALYSIS 

ZERO ! 

6AS ! 

(aV) : 

o.oo ; 

o.oo : 

o.oo : 

• 

TEST 

6AS • 

(aV) 

97.90 

97.90 

97.90 

RESULTS 

PPH 

990.3 

990.3 

990.3 

REFERENCE REFERENCE 

'* 6AS 6AS 

CONC. (aV) 

973.3 PPH 96.40 

96.40 

96.40 

RESULTS 

PPH i 

975.1 

975.1 

975.1 

ANALYTICAL PRINCIPLE 

FLAME IONIZATION DETECTOR 

DATE l 3-

CALCULATED 

RESULTS 

988.4 

988.4 

988.4 

AVERAGE l . 988.4 PPH 

aBaaaaBSBaBaaaaaBaBaaaaaaaBaaaaaBBBaaaBaBaaBaaBaBaaaaaaaaaaBaaasaaBaaaBaBaBaaaaaaaaaaaa 

I SHIS - SAS MANUFACTURER'S INTERNAL STANDARD Analyat I . .. . - - . - _ -

TfcccfrlUbai'orofthUCcop.aytoiM*^ 

Or^^K. Approved 

rtplKtaint t wrarfhy ttn 

By i / <nfafi<< <A*> 

II 

II 

II 

II 

II 

II 

. 1 

II 

11 

II 

II 

• • 

II 

II 

II 

II 

II 

II 

II 

II 

.1 

II 

II 

11 

11 

II 

II 

II 

II 

II 

II 

II 

• 1 

aaat 

•mmmmmtm 

SRHI 

CALIBRATION CU 

........ ......... 

CONC. SPLIT 

(CRN 1) PPH PT (I) 

2646 

2646 

naaaaaai 

RVE 

DVH 

(aV) 

1012 100 100.00 

973.2 96 

799.B 79 

279.7 28 

1B9.2 19 

0.0000 0 

0 

1B9.2 LOH 

973.2 HIGH 

96.40 

79.10 

27.60 

16.60 

-0.01 

18.60 

96.40 

lit 

......... 

FITTED 

VALUE 

1012 

975.1 

B00.3 

279.7 

1B8.7 

0.0000 

0.00 

18B.7 

973 

DE6REE 

-*»—— • 

PERCENT 

ERROR 

0.00 

0.20 

0.03 

0.00 

-0.24 

0.00 

0.00 

-0.24 

0.20 

BaaaaMaaaaaBaaaaaaaaaaBaaaaaaaaaaaBaa 
P.54 

IV 

i 

]-. 

.1 

I* . 

.!• • 

*• •* • 

i f ••' *.. . •.. * • 

! 

ATIONAL 

PECtALTY WASE8 SlJ 

DIVISION Of NATIONAL WEIMUSUfflT CO, INC 

CERTIFICATE OF ANALYSIS 

P.O.k«U0tt 

•UoNrdTftoaal* M u NX. V799 

ftNi»919/M44*t 

TOJ COMPOSITE TECH DATS HFORTIDl i/16/9 1 

UFRRENCBl 

68-1224 7 

MATERIAL SUBKXTTSD: METHYL METHACRYLATE IN NITROGEN, CERTIFIED 

SfFORMMION REQUESTED! RATIO ANALYSIS 

METHOD OF ANALYSIS* TOTAL HYDROCARBON ANALYZER 

RB8ULT OF INVBSTIOWIONt 

COMPONENT 

METHYL METHACRYLATE 

N2 

SPECIFICATION 

$0 ppm 

COWCtttTRATION 

50* 7 ppifr 

BALANCE 

j, 

i 

I 

"THIS REPORT STATES ACCURATELY THE RESULTS OF THE INVESTIGATION MADE UPON THB 

MATERIALS SUBMITTED TO THE ANALYTICAL LABORATORY. EVERT ETFORT HAS BEEN MADE 

TO DETERMINE OBJECTIVELY, THE INFORMATION REQUESTED: HOWEVER. IN C0NNBCI10H 

WITH ITS RENDERING OF THIS REPORT, NATIONAL SPECIALTY GASES SHALL HAVE NO 

LIABILITY IN EXCESS OF ITS ESTABLISHED CHARGE FOR THE SERVICE. ANY USE OF 

THIS REPORT OR THE INFORMATION CONTAINED UBRBIN SHALL BE AT THE SOLE BISK OF 

THE usn.** 

SS 
P.55 

t 

I 

r 

} • • 

i 

ATIONAL 

PENALTY mtHB 

DIVISION OP NATIONAL WRDttl WPW CQ.JNC 

CERTIFICATE OF ANALYSIS 

P.aiaa 13019 

RaoMtdi WMgb Mi. N.C 17709 

fttnt'WMi-im 

TOl COMPOSITE T6CH DATE REPORTED 5/16/9 1 

EBFEUNCBl 

MATERIAL SUBMITTED] METHYL ETHYL KETONE I N NITROGEN, CERTIFIED 

INFORMATION REQUEST EC I RATIO ANALYSIS 

i 

METHOD OF ANALYSIS! TOTAL HTDKOCARBON ANALYZES 

RESULT OV INVESTICATIONI 

a 

I ' 

L ". . ' 

COMPONENT 

MEK 

N2 

• 

SPECIFICATION 

50 ppm 

CONCBfTRATlOH 

48. 7 ppm 

BALANCE 

i • 

"THIS REPORT STATES ACCURATELY THE RESULTS OF THE INVESTIGATION MADE UPON THE 

MATERIALS SUBMITTED TO THE ANALYTICAL LABORATORY. EVERY EFFORT HAS BEEN HADE 

TO DETERMINE OBJECTIVELY. TNE INFORMATION REQUESTEDi HOWEVER, IN CONNECTION 

WITH ITS RENDERING OF THIS REPORT, NATIONAL SPECIALTY CASES SHALL HAVE MO 

LIABILITY IN EXCESS OF ITS ESTABLISHED CHARGE FOR THE SERVICE. ANY U8E OF 

THIS REPORT OR THE INFORMATION CONTAINED HEREIN SHALL BB AT THE SOLE RISK OF 

U U USER.*1 

%f 

s4-
P.56 

I 

ATIONAL 

PENALTY mSE8 

DIVISION Of NATIONAL WIIBEW SUPM.V TO, INC 

CERTIFICATE OF ANALYSIS 

P.O.BMI30 H 

•fcaaattkTrfo^tPort N.C. 27709 

n*im.9wsu-*m 

TOi COMPOSITS TECH DATE REPORWDl 5/16/9 1 

REFERENCE! 16-1212 9 

MATERIAL 8 UBMITTED I TOLUENE IN NITROGEN, CERTIFIED 

< 

INFORMATICS REQUESTED! RATIO ANALYSIS 

I 

METHOD OF ANALYSIS} TOTAL HYDROCARBON ANALYZER 

RE8ULT OF INVESTIGATION. 

1 

COMPONENT 

T0L9ENE 

N2 

SPECIFICATION 

5 0 ppm 

COWCtttTlATIOW 

51. 9 ppm 

BALANCE 

AUTHORISE AUTHOR! ) SIGNATURE I 

"THIS REPORT STATES ACCURATELY TIIE RESULTS OF THB INVESTIGATION MADE UPON THE 

MATERIALS SUBMITTED TO THE ANALYTICAL LABORATORY. EVERY EFFORT HAS BEEN MADE 

TO DETERMINE OBJECTIVELY, THE INFORMATION REQUBSTBDl HOWEVER, IN CONNECTION 

WITH ITS RENDERING OF THIS REPORT, NATIONAL SPECIALTY OASES SHALL HAVE NO 

LIABILITY IN EXCESS OF ITS ESTABLISHED CHARGE FOR THE SERVICE. ANY USE OF 

THIS REPORT OR THE INFORMATION CONTAINED HEREIN SHALL BE AT THE SOLE RISK OF 

THE USER." 

J: 

1 

«.• 

SS" 
P.57 

if 

1 

ATIONAL 

SPECIALTY UASES GA, 

OIVlStON OP NATIONAL WELDERS SUPPLY CO., INC 

CERTIFICATE OF ANALYSIS 

P.O. Box 12013 

toward* Trtatgfe Park, N.C 27709 

Phona 919/5444772 

] 

'J 

i 

TO: COMPOSITE TECH DATE REK)RTED::

 6/21/9 1 

REFERENCE: 88^1257 6 

MATERIAL SUBMITTED: STYRENE IN AIR 

CERTIFIED CYLINDER* CC-10333 1 

INFORMATION REQUESTED: RATIO ANALYSIS 

METHOD OF ANALYSIS: TOTAL HYDROCARBON MONITOR 

RESULT OF INVESTIGATION: 

J 

COMPONENT 

STYRENE 

AIR BALANCE 

SPECIFICATION 

20ppm 

CONCENTRATION 

22.1pp m 

i 

J 

I 

^J ^c 

AUTHOR! IGNATURE 

"TIIIS REPORT STATES ACCURATELY THE RESULTS OF THE INVESTIGATION HADE UPON THE 

MATERIALS SUBMITTED TO THE ANALYTICAL LABORATORY. EVERY EFFORT HAS SEEN MADE 

TO DETERMINE OBJECTIVELY, THE INFORMATION REQUESTED: HOWEVER, IN CONNECTION 

WITH ITS RENDERING OF THIS REPORT, NATIONAL SPECIALTY GASES SHALL HAVE N0 

LIABILITY IN EXCESS OF ITS ESTABLISHED CHARGE FOR THE SERVICE. ANY USE OF 

THIS REPORT OR THE INFORMATION CONTAINED HEREIN SHALL BE AT THE SOLE RISK OF 

THE USER." 

J •4.r 

'•' ^tc > 
P.58 

APPENDIX F 

J / 

I 

J 

--S3-
P.59 

J 

I 

J 

Capture efficiency monitoring was performed by Composite Technology, 

Inc. (CTI) personnel and observed by both EPA and TACB officials. 

All VOC emission sources at CTI are within permanent total enclosures 

that meet EPA's proposed guidelines for claiming 100 percent capture. 

The five criteria for claiming "Total Enclosure" are as follows: 

1) Access doors and windows closed during routine operations. 

2) Negative pressure Inside enclosure. 

3) Minimum Indraft air velocity of 200 ft/m1n through openings. 

4) VOC sources not close to Indraft openings. 

5) Openings 1n enclosure of less than 5 percent of the total 

enclosure surface area (walls, celling and floor). 

A more detailed explanation of these criteria can be found 1n 

Appendix F . 

It was shown to both EPA and TACB officials that access doors and 

windows of all enclosures are kept closed during routine operations. 

Keeping all windows and doors closed during production runs 1s the 

standard operating procedure. 

Indraft air velocities of 200 ft/min will only produce a negative 

pressure of about 0.004 inches of water column. CTI personnel were 

unable to measure this low pressure inside any of the enclosures due to 

the lack of Instrumentation (on site) capable of measuring less than 0.01 

Inches of water column. However, since Indraft velocities of 200 ft/min 

were conslstantly seen It could be assumed that there Is Indeed negative 

pressure within the enclosures. 

Indraft air velocities of at least 200 ft/min were being 

achieved through all enclosure openings and were observed by both EPA and 

TACB officials. There were, however, fluctuations between 150 and 200 

ft/min at some openings along the panel line enclosure while employees 

were entering/exiting the area. Velocities were never seen to drop below 

150 ft/m1n and once the entrance/exit was closed, velocities stabilized 

at or above 200 ft/m1n. 

All VOC sources within the enclosures meet the criteria of being at 

least four equ1valant diameters away from any openings except for the 

openings at the exit to the panel line enclosure. However, this should 

pose no problems since the Indraft velocities at these openings are at or 

above 200 ft/m1n. 

sS 
P.60 

1 

j 

Finally, openings In the enclosed areas are less than the allowable 5 

percent. Surface area calculation for each enclosure can be found 1n 

Appendix F . Based on the Indraft velocities at all openings and the 

total volume of air being removed from the enclosure the following 

calculation shows that the open area 1s far less than allowed. 

Opening Area. • [Volume Removed (CFH)]/[Opening Velocities (ft/min)] 

Example: Panel Enclosure 

Opening Area - 6000 CFH/200 ft/min 

- 30 sq. ft. 

Allowable Open Area - 0.05(3040 sq. ft.) 

- 152 sq. ft. 

Open Area less than Allowable 

If the actual open area was greater than the calculated open area, using 

the above formula, Indraft air velocities could not be met. 

2^ 
P.61 

l" 

i 

l 

l 

J 

1 

ENCLOSURE SURFACE AREA CALCULATIONS 

Hlxroom: 20' X 40' X 12' (4500 CFM) 

Total Surface Area - (2x20x12) I (2x40x12) I (2x40x20) 

- 3040 ft squared 

Allowable Open Area less than 0.05(3040) 

less than 152 ft squared 

Panel: 17' X 52' X 8' (6000 CFM) 

Total Surface Area - (2x17x8) + (2x52x8) + (2x17x52) 

* 2872 ft squared 

Allowable open area less than 0.05(2872) 

| less than 143 rt squared 

Hetrolac Booth: 8' X 8' X 8' (Booth) - (Inline) 

, 26'6" X V X V (Tunnel) (6500 CFH) 

Total Surface Area - (6x8x8) + (2x26.5x2) + (2x7x26.5) 

1 + (2x3x7) 

- 889 ft squared 

Allowable Open Area less than 0.05(889) - 44 ft squared 

I Hetrolac Booth: 8' X 8' X 8' (Booth) (Offline) J 23' X 5' X V (Tunnel) (6500 CFH) 

Total Surface Area - (6x8x8) + (2x23x2) + (2x5x23) + 

(2x5x2) 

J - 726 ft squared 

Allowable Open Area less than 0.05(726) » 36 ft squared 

i 

Pultrusion: Enclosure surface areas vary depending on die being used. 

By observing these enclosures, it can be seen that the 

open area 1s far lessthan what would be allowed. 

Based on the surface areas of the mixing room, panel Un e and both 

hetrolac booths, and by viewing the open areas of these enclosures, it 

can be seon that the maximum of 5% 1s not exceeded. 

J 
P.6 2 

'*•••«• 

rv . Again, achieving a high capture efGclcccy ii not difficult or expensive, if nb'wasider'atfen isidei n 

•' be given to operator convenience.! For this reason. It Is foolish for a purchaser to ask fora 

fi— ^-f-a . V! J -. - A ^.i*..* ^ .^. r .'.J.V^. i |»J | 1a« A .-*- - I . al^tattt .A. t A - ill- . ^ Z V . »1I ll't l 

fjCo 

1 ... For example) afteV a"weJtT|mJ^cn^o?te^ .tjfc^l^J^p^^tt^Jfttolc ^ fc leiw jteSsL.i 

•;/webImmediately, befb^the web ha^reashedjjhe qyen.prjdryer.:-bn§ t&ofyt way of iHw^Vi i 

.^.capttfcirtgihbievapb^ 

-they reach the oven, where "the vapors can then be picked up by the oven exhaust tysieml -. V -J-J: 

y - o l ^^vefeft-tfeyidai^bfthework.) ^ 

.. • ,-- • 

a. 

/ -plants'will sometimes Instat! ctese'&pture systems just so .their operatora'ean have an ocfcrlesa'^S-

. ."work area. 

.Use a "totalenclosure" approach wjheft '.'. 

' extremely high capture efficiency is needed 

. or.when close capture devices arc-'^ m -

Jr- - •*.'• /•— 

.- PROPOSED UA CUIDEUHZS 

, ixOR TOTAL EXCLOSURT-

.,**. 

* /•>• ^c«r de&icni Hintc-* datd dunsy " 

' * - 'KAmmdniemrcicA.' •'".'" .' J~ Z ' \iT 

" .1 -

1 

In 19S3,~the 5?A proposed ~a capture V- -

• procedure;* which' wuWJ^anftKe )fc?M)*e'' 

-legal presumption -bf iQQ% capture" * • 

\ without fli fteflfrcmenj far formal; r r: 

"-canters '?««!*- At the date of this" ••''**-

Anting, the pr'eccsecT-pfccedure'a sta:/-

being debated; buroany states have" V . 

.' a beady eked ptiraiu baseit on it, &nd it 

has acquired de facto status. ' 

Specifically, the following definition * 

applies: 

IT a source is located inside a "total 

enclosure* and all emissions art directed to 

a control device, the requirement to measure the efficiency of capture is waived, and 

presumed 100%. Ey definition then, a "total enclosure* precludes fu.gi.ive emissions. Such aa 

enclosure can be described as a structure tiut completely surrounds or enshrouds an affected 

facility such that al! VOC emissions are contained and directed .through an exhaust stack or 

•into an oven. Aa entire building car. function aa a total enclosure (see Item 5 below) if the 

conditions above are satisfied. 

•2 ' ffttavt priMS-^Jiisldd tjvilasurn .* "'1 •* 

*•.. K • M-AuftUtri vHln./m'air vrte«*iy cf. }&} /brit*. i •.. • 

•i. •'CCieuuj not t&v 10 indraft op-twp. 

J. * MLifcun optnutp In room ofUn 'Jxin S& of 

. wai indofln Jtvfut ana. • • 

. Vr'^h *ictcl in£!cr&4\ &A mU auuru IC0% df tetel 

.jptunfruUrpopoiedripitufoH 

'^ .« 

J. 

I 

TMBasiQ or VOC Opiure S>«easity Messrs. R1 . KCBSIPM; ? £ A R C Sbarp • Foal Drift 7/90 ?i|t 7 .•: 1 ::: 

G / " 

« 

.. 

M 

t — 

• 'a . 

•^•-I -
• • • . • ..***• • • "• • • < * • • 

7";

 :y.'. y T°.S.Hft1tyto^ 

P.63 

I drafwipemng (NDO) Is defined aJ an opening that is not connected Jo a *u^fc"wych a " • \ j : •"• 

I.,..;;;'.0.1 . .r.-v *r- tatt'pr.blower»vlnitalled.- yry*.^::_y ^ ••V-*-y> 

j f "*. •';.•. %-J . .. . . . ». tavlnaai.n^ . «>w m^-"v— » • -— •"r-i-** •A.#1T-^--^-——i—.*i*~ ' *»iv- . •»*»»»*''• *V wwwl'ftS**Mtt'' v£..,. » f .. . .. . .'— •-•. 

. . . %:• ."-. • -_• c." TheTaverage velbclty'ihrough all NDOs must be at leasfigflp ft/jnlti. and it must be proven 

that all air flow Is continuously into the enclosure (If the average velocity is at least 500 

•

;

 .-.•:"!?.. „... ."• ft/min, sudb.proof is not jequtrcd.) ;' ,\c . -—« . »* • - ' .::. • J. -2 . *... . -

i In effect, bee builds a house around the VOC source. 

a a> .—. 

• -/ .--•; - *~E3cTos£bnl!*V,it'l^ « 

consfstscf t£ un*n"si!.srantf Vscrcca tfcater.-a'rcl! cca;j;, an even and V rewind stand; 

er.clcxe only tha tc',) 'totter.-/ ,

N

rii^c 1t.fi "the only potential scares c f ftigitive VOCi: 

* Seal all cbnncctibpj between theezcinsure and the even. A balanced oven is already a 

•total enclosure; and sealing lhe even sides .to the newly-built enebsure (around the coater) 

creates ene, overall total enclosure. '" 

»• Where Vises! in;pc;iic/i of the process li needed, use window made of wire-reinforced' • 

safcry glass, so that the operator dees act need to enter the enclosure. (CUar plastic or • 

plexiglass can also be used, but these tend to become :!cudcd by certain common solvents, 

such as ketones.) . 

m » Where physical access tc the process !s needed for short periods of time, use self-closing. 

J 

J 

hinged access doors or windows. 

J . . . Tbe. Basics of VOC apeunr.S^ems by Mesi*. R. J. Mc3%ee. P i A R C Sb*p - ffteaj DnA 7/90,. ftp I \ J' •-

'-J .*. " . . :. :• - . i ' - ..;.• ; •-- »•• £• . •.•• - ]C /^n Z7 ill.*.*.*.- - • - - -•!* •'••?l-*»-^VV->?£'; ^jf' *:' -' *** ^*' ^