i

PUBLICATIONS

NBSIR 83-1694

HYDROGEN SULFIDE PROVISIONAL

THERMOPHYSICAL PROPERTIES FROM

188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. Goodwin

National Bureau of Standards

U.S. Department of Commerce

Boulder, Colorado 80303

October 1983

NBSIR 83-1694

HYDROGEN SULFIDE PROVISIONAL

THERMOPHYSICAL PROPERTIES FROM

188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. Goodwin

Chemical Engineering Science Division

National Engineering Laboratory

National Bureau of Standards

U.S. Department of Commerce

Boulder, Colorado 80303

October 1 983

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director

Contents

Page

1 . Introduction

2 . Physical Properties

2.1 Fixed-Point V-a lues

2.2 Melting Line and Vapor Pressures 2 2.3 The Orthobar ic Densities 2 2.4 The Second Virial Coefficient 3 2.5 The Equation of State 4 2.6 Tiie Ideal Gas Functions

2.7 The Heats of Vaporization

2.8 Saturated Liquid Enthalpies and Entropies

3. Computational Methods 8

3.1 The Homogeneous Domain

3.2 The Saturated Liquid 9 3.3 The Compressed Liquid

3.4 Fugacity Coefficients

4. Tests and Conclusions

5. Tables of Physical and Thermodynamic Properties

5.1 Calculated P-p-T Isocnores and Isotherms

5.2 The Joul e-Thomson, I nvers i on Locus 12

5.3 Properties of the Saturated Liquid

5.4 Properties Along Selected Isobars 12

6 . Ac knowl edgments

7. References 14

Appendix A. Fixed-Point Values for Hydrogen Sulfide

Appendix B. Symbols andUnits

Appendix C. Coexistence Data of Kay and Rambosek [27] 2U

Appendix D. Vapor Densities of Reamer, et al. [38] 21 Appendix E. P-p-T Data of Wright and Maass [49]

Appendix F. Computer Programs S3

Appendix C. Ideal Gas Functions by Haar, et al List of Fi gures

1. Dens i ty-temperature diagram of hydrogen sulfide

2. P-T locus of P-p-T data of Reamer and of Leins

3. P-T locus of P-p-T data of Rau

4. Specific heats, C

V (T) at 20.34 mol/L

List of Tables

1.

Comparisons of vapor pressure data for H^S

2. Comparisons of saturated liquid density data for H

2 S

3. Comparisons of saturated vapor density data for II^S

4. Coefficients of equation of state for hydrogen sulfide

5. Calculated critical isotherm for hydrogen sulfide

6. Comparisons for P-p-T data for hydrogen sulfide

7. Comparisons of ideal gas functions for hydrogen sulfide .... 00

i i i
Contents (continued)

List of Tables (continued)

Page

8. Interpolated ideal gas functions for hydrogen sulfide 67

9. Comparison with HgS thermofunctions by Starling 68

10. Calculated P(T) isocnores of hydrogen sulfide 69

11. Calculated P(p) isotherms of hydrogen sulfide 88

12. The J oul e-Thomson inversion locus for hydrogen sulfide 112

13. Properties of saturated liquid hydrogen sulfide 113

14. Properties of hydrogen sulfide along isobars 115
HYDROGEN SULFIDE PROVISIONAL THERMOP N YS 1 UAL PROPERTIED FROM

188 TO 700 K AT PRESSURES TO 75 MPa

Robert D. CoocUin

Chemical Engineering Science Division

National Engineering Laboratory

National Bureau of Standards

Boulder, Colorado 80303

T nermophy s i ca 1 properties of hydrogen sulfide are derived from

physical properties data by using our nonartalytic equation of state,

and are tabulated along isobars at integral temperatures. Results

include vapor pressures, orthobaric densities, the second virial

coefficient, the equation of state, the ideal gas state functions,

compressibility factors, densities, derivatives of the P(p,T) surface,

neats of vaporization, internal energies, enthalpies, entropies,

specific heats, fugacity coefficients, speeds of sound, and the

Joul e-Thomson inversion. Thermofunct i uns by another author are compared with present results.

key words: densities; enthalpies; entropies; equation of state;

fugacities; heats of vapor i zat i o n ; hydrogen sulfide; isobars;

isochores; isotherms; J ou 1 e-Tnomsoii inversion; orthobaric

densities; specific neats; speeds of sound; vapor pressures;

virial equation.

1 . I ntroduct i on Hydrogen sulfide (H^S) is a component of most fossil fuels. For thermodynamic properties computations, tne present report uses the highly-constrained,

nonanalytic equation of state to obtain a smooth and consistent P(p,T) surface

using the P-p-T data of Reamer, et al . [38], Lewis and Fredericks [Blj, Rau and

Mathia [ 3 6 j , and two preliminary isotherms communicated by Straty [43]. Ideal

gas state functions are from Baehr, et al . [1J.

Earlier compilations have been presented by Nest [48], and by Starling [48].

The work of Clarke and Clew [8] is especially valuable. A bibliography of

references appears in the book by Howarth [26a].

For orientation, figure 1 presents an outline of the densi ty-temperature

phase diagram for H^ S . Present fixed-point values are in Appendix n. Symbols

and units are in Appendix B. Appendices C, D, E and G give some experimental

data not used in the present report. Tiie computer programs are in Appendix •.

2. Piiysical Properties

2.1 Fi xed-P oi nt Values

The values selected for tne present work are listed in Appendix a.

(a) The Triple Point. Our T

t

= 187.66 K is based on the 193o valui or Giauque and Blue [17] which was 187.61 K based on (0°u = 273.1 0 k). in H3',

Kruis and Clusius [30j reported T

t

= 187.60 k. Our vapor pressure, and

orthobaric densities at the triple point are from eqs (2), (3), and {4 below.

(bj The Boiling Point. The temperature is from vapor pressure eq (l at a pressure, 1 atm = 0.1 01 325 MPa. Giauque and Blue observed - 212. '7 K on

1
their Y-scale, whereas the value from our formulation is = 212.874 K. Liquid

and vapor densities are from eqs (3) and (4) below.

(e) The Lritical Point. Cardoso purified his H-,

sample v/ith great care l 4]. Cardoso and arni [5] quote tlie critical temperature from earlier

authors as T

c = 373.55 + 0.1 K, and give their observations as tc = 100.40

+ 0.1°C (or, they say, 373.4 K). he have adopted T

c = 373.4 K. In this same paper [5] the critical pressure was 09.05 + 0.1 atm (90.23 bar), but in a report

on vapor pressures Cardoso L 6 ] gives P

c = 8&.90 + 0.1 atm, i.e., 90 .00 bar. Our

vapor pressure eq (2) uses data of Reamer, et al . [30] and yields 09.629 bar at

T

c = 373.40 K. Our critical density, 10.20 mol/L, was selected tediously by

inspecting the rectilinear diameter from orthobaric densities data of Reamer,

et al. [30], and the behavior of fitting functions, eqs (3) and (4).

2.2 Melting Line and Vapor Pressures

(a) The Melting Line. Ilo measurements have Deen found for the sol ia-1 iquiu

P m(T) relation of H^S. In present work this is used only to establish a lowtemperature limit for the isobar tabulations in table 14. Hence, we have usc-d

the reduced Simon equation.

P

r., * P

t + P o t(T/Tt

) n

- U (1)

with parameters for propane, n = 1.283, P 0

= 718 MPa.

(b) The Vapor Pressures. Table 1 presents a comparison of selected data

with the fitting function eq (2) below. Authors are identified by their Id's

given at the top of the table. Excluded data appear at the bottom of this table.

Our vapor -pressure equation is

£n[P

Q *10] = a/x + b + c*x + d*x 2 + e*x 2 + f*(l - x)*

3 (2)

where x = T /

c is the reduced temperature, pressure P Q

is in units of MPa, the

exponent is p

= 1.70, and

a = - 8.023 473 844 d = 9.690 908 499

b = 16.731 062 287 e

= -3.577 167 041

c

= -10:325 650 140 f = 3.174 310 817

The rms relative deviation for 54 selected data is 0.08 percent. The

experimental residual in the last column of table 1 is £n(P/P t )/£n(P

c /P

t

) -

(1 - T

t

/ T ) / (

1 - T .j. / T

c

)

. DPS/DT is the slope, in units of MPa/K.

2.3 The Orthobaric Densities

(a) Saturated Liquid Densities. Table 2 presents the comparisons of data

with eq (3) below. Author ID's appear at the top of this table. Our liquid

densities equation is

p^/p c

- 1 = a*u p + b*u + C‘u

2 + d*u 2 (3)

where u = (1 - T/T

c ), exponent 8 = 0.35, and

2
a = 1.9063 9527 c = -0.5709 1447

b = 0.8356 0589 cl = 0 .7234 7653

The mis relative deviation for 45 data is 0.033 percent. In taule 2, DD3/DT is

the slope, in units of (mol/L)/K.

(b) Saturated Vapor Densities. TaDle 3 compares data with eq (4) below.

Among autnor identifications at the top of this table, data at ID = 9 are from our virial eq (5) below. Data at ID = 10 we derived from heats of vaporization:

see section 2.4 below. Data at ID = 95 are computed via a selected rectilinear

diameter [coefficient b in eq (3)j with liquid data from eq (3). Divergent data

of Reamer, et al. [38J have been omitted (Appendix D). The fitting function is

designed to yield Z Q

( T

) —>1 as p —O. Let A

Q

= (Z

c

- 1) and define the

arguments

n(T) = ^ 0 (T)/P

C

, x ( T ) = T /

c

, u ( T ) = ( 1 - x )

.

The reduced vapor densities, p

g

= P Q

/ lZ q

« R * *T j , then are given by

io m = i + A • ii • o

u x”

2 *f(x)

f(x) = 1 + [A

^

• u p + A • u

d + A

3

* u + A

4 -u

2 . , 3-, + A r • u j

• 5 XP ,

XP = exp Lb • ( x - l)

3 /x]

where 8

= 0.35, a = 0.70, b = 2.0, and k

* = R. d

c , IIP a /

= -0 .7525 7980 a

4

= 2.1729 6301

l\ z

= -0 .8654 811 7 A

5 = -5.7660 7853

A

3 = 1.9754 3043

Tne first coefficient in eq ( 4 ) is constra i neu (fo r symmetry) in terms of

first coef f i c i ent , a , for the liquid in eq (3) » A

1 a • Z

c

/ ( Z

c

- 1), by

inspecting eq (4) at T very close to T

c

. The rms relative deviation for

weighted data is 0.12 percent. In table 3, DDS/DT is the slope, in units of

(mol/L)/K. Column F ( <. ) gives the experimental residual,

F <‘> 5 n Sxpt - i )/U c

- D3-x 2 /» .

2.4 The Second Virial Coefficient

Data at higher temperatures are available in tiie bout L»y D>mond and

Smith 1 3 j . At and below the boiling point we derived values for the second

virial coefficient, B ( T ) , with heats of vaporization at the b.p. of oiauque j u Blue l 1 7 j and of Frank and Clusius L 1 5 ] at 188.7 K, via tuo C 1 a p e y r u i i e q u a t i o

" . Using V

c

= 1.0/10.2 L/mol, a plot of all data yiolus

B(T)/V

C = 1.75- 3 . 0 • ( 3 7 3 / T ) , v 5

where B(T) is in units of L/mol. This was used to obtain some sdturat.ee v a .i o

’ densities at low temperatures by way of the truncated virial equation of state.

3
Z(P,T) 1 + B ( T ) • d + ... (5a)

where d is the density iri mol/L.

2.5 The Equation of State

The present equation of state (EOS) is valuable for use with inaccurate

P-p-T data because it is constrained to the coexistence boundary; it yields a maximum in C

v (p,T) at the critical point; and it has only three least-squares

coefficients. A general description was given by Goodwin [19]. The present form

of the EOS is the same as was used recently for isobutane [22].

Figures 2 and 3 show the P-T regions covered by P-p-T data of Reamer,

et al. [38], Lewis and Fredericks [31], and by Rao [36]. Two preliminary,

high-temperature isotherms communicated by Straty [43] were used with Reamer's

data for adjusting the EOS. The other data (including Reamer's near the C.P.) were ignored, but comparisons with the EOS also are presented in table 6 . In this table, some calculated densities fall in the opposite liquid-vapor phase

from the data, and so these deviations should be ignored.

Equation ( 6 ) is the outline of our EOS. For any density (isochore) the

coexistence temperature, T

Q (p), is obtained by iteration from eqs (3) or (4)

for the orthobaric densities; hence the vapor pressure, P [T Q (p)], is a function of density.

P - P Q (p) = pR * * [T - T

0 (p)] + p

2 R*T

c .F(p,T) ,

F ( P , T ) e B ( p )

• *(p,T) + C(p) • *(p,T) ,

( 6 )

where p is the reduced density.

The temperature-dependent functions in eq ( 6 ) are defined as folio w s , where

x e T/T c is the reduced temperature and x

Q

e T

q (p)/T c is the reduced

coexistence temperature.

*(P,T) = x

e *ex p[ b • ( 1 - T

q (p)/T)] - x^ , ( 6 a)

where e = 3/4, b e (1 - e) + (1 - e )

^ / ^ = 3 / 4 # and

y(p,T) e 1J

1 ( p , T ) / <|> q

( p ) - 1 ( 6 b)

where d 0 (p) is obtained from 4* ( p , T ) merely by replacing T with T (p), and, for

i|/(p,T) we use the argument,

u>(p,T) = [1 - 0 ( p ) / T ] , ( 6 c)

where e(p) is a locus of temperatures inside the coexistence envelope,

e ( P ) = T

q

( p ) • ex p[ -a • f ( p ) ]

f(p) = IP - 1

| 3 /(P t

- l ) 3

( 6 d)

in which p t is the reduced density of liquid at the triple point. Then,

*(p,T) e 1 - (u» - oj n /n

)

/ ( 1 - 1/n) • (6e)

4
Equations (6b, 6e) dictate behavior of the P(p,T) surface about tne critical

point (C.P.). We selected exponent value ri = 1.10 because it cannot oe established by fitting P-p-T data. Experimental data become inaccurate near tne

C.P., just where they are needed most to establish exponent q for the EOo.

Tne density-dependent coefficients in eq (6) are,

B(p) a B

] + B

2 -p

2

, ( 6 f

)

c(p) =

c i • ( p

- 1) *(P - 2) • exp[ - Y • P J • ( 6g)

We selected y

= 1/2 for an i nf 1 ect i on in p^ •C(p) at p = 1 , see eq (6 / , to

ODtain symmetry about the C.P.

Parameters arid coefficients of eq (6) for H 2 S thus are

,

a = 1 , 8

= 0.35, y

= 1/2 > e = 3/4, n

= 1 .1

B •] = 0.3932 5678 673

B

2 = 0.1329 0189 038

C

1

:0 0 0ro 0

II I 113

In fitting eq (6) to P-p-T data by least squares, we constrained tne slope of tne

critical isochore at the C.P. to equal the slope of vapor-pressure eq (2) at tne

C.P., 3P/3T = dP

Q /dT = 0.152 378 MPa/k. Table 4 gives behavior of tne coefficients, and table 5 shows behavior of the calculated critical isotherm. PVT uata

deviations are in table 6.

Specific heats on tiie critical isotherm can oe derived from our EdS at reduced densities near p

= 1 via

AC

v = - T -J (

2

P / 3

2

) -dp/p 2

.

Isochore curvatures, 3^P/3T , depend on t(p). y ( p , T ) ,

t(p,T) - ii/(p>l)/ij<

0 (p) - 1 >

*(p,T) = 1 - (a) - u) n /n ) / (

1 - l/n)

( aa

/

Differentiating \|»(p,T) twice vs. T via uj(p,T), dropping insensitive terms and

factors, 3 uj/3T, 3^jj/ 3T^, gives

2 2

3 4

P / 3T

4 (P - U-oi ( a

)

Howeve r

,

u) ( P , T

c ) s 1 - e(p)/T V b

0 ( p ) = T

0 (p) *expL- a* |p - 1 | °j . vt

how, let T

0 (p) be obtained from tne usual formulation of orthooaric densities

very near T c ,

P o

= 1 + a - L 1 - T

o (p)/T

c

j 1/J, Id)

5
T 1 0 (P)/T

C

- b .

| p

- 1

Also at p near 1,

3- 3 exp L- ot •

| p

- 1| J = 1 - a*|p - 1|

Thus from (b), (c), (e) and (f),

6 ( P ) /' 1 - c •

| P

- 1

u(p,T

c

)

». IP - 1

(e)

(f)

( 9 y

(li)

and, via ( a) , 0

2 P/8T 2

) % (p - 1) -|p - 1 | 3 * r'“ ^ (i ) along the critical isotherm near p

= 1.

To obtain C

v (p,Tc

) by integrating (i) vs. p, we have assumed that l/>

0 (p)

in (aa) will have negligible effect. It lias the approximate form near p

= 1,

3

1 / iji ( P ) t l + const.*|p-l|

Ue find two limiting values for exponent n • If ( 3

• n

- 6) = -2, i.e., n = 4/3,

then,

C

v (p,T

c

)

-x- - Jon |p - 1| , ( j )

and if n > 4/3, the behavior of C

v is wrong. Then, if (3*n - 6) —*--3, i.e.,

n —*1 .0

+

(r) = 1 excluded), we would ootain for n

= 1,

C

v

( p ,T

C

) ^ | p

- 1 | -1 (k)

Hence the exponent is restricted to 1 < n <_ 4/3, and, for our value n = 1.10,

C

v (p,Tc

) . |p - 1 |" 0 - 7, (1)

along the critical isotherm, and near p

= 1. In early work we, used a logarithmic form

4> ( p , T ) 1 - u> + to • x, n ( (D ) (m)

to obtain nonanalytic beliavior of the EOS. By methods analogous to tiie above,

always along the critical isotherm, we find that (m) gives a logarithmically

infinite rate of change of isochore slopes (3P/3T) vs. p at p

= 1 . This is

capable of producing an irregular critical isotherm, P ( p ) y

. The present

formulation of ^ ( p , T ) with an exponent, n

= 1.1, fields a linear dependence of

isochore slopes vs. p along the critical isotherm at p

= 1,

( 3P / 3 T

)

T * a - b«(p - 1 ) , (n)

c

by disregarding integral powers of p in the EOS.

6
2.6

Tne Ideal Gas Functions

Spectroscopic specific heats and ideal gas state tliermof uncti oris have been

tabulated by Bae hr, et al. [1], Stull and Prophet [44], and by Edmister [14]. .<e used data of Baehr and of Stull before receiving the Edmister report. Table 7 gives deviations from our fitting e-q (7) below. Table headings for Vi 0

- V. J

, etc. are given by H4-Hzz, etc. Upon discovering differences between data of

Baehr, ID = 1, and of Stull, ID = 2, we gave zero weights to the ID = 2 data wneri

fitting eg (7), by using x s T/100,

C°/R

P e x p ( - e / x

'

where e = 10.37, R = 8.3145 (J/mol)/K, and

AAo

u H n

- 0 .1 952 556

11.0377 525

-74.8072 768

6 *

2 - i (7)

330.650 146

-655.671 639

475.053 933

Table 8 gives interpolated values at integral temperatures. After present work

was completed, Dr. L. Haar kindly noted that he and coworkers computed ideal gas

state functions [ 2 3 a ] , and that ttie entropies differ significantly from tiiose

used here. For convenience in future work, these data are duplicated in

Appendix C. we have fit the Karmens' [25] version of willioit's G°(T) formula to the

highly precise H

2 S data of Baehr, et al. [1]; see table 7. By fitting to tne

Cp(T) data, the deviations were strongly systematic, to above 0.5 percent,

with an rms relative deviation of 0.34 percent [as compared with 0.012 percent

via our eq (7)]. By fitting to the (H° - H°) data, the systematic deviations

exceed 0.08 percent, rms = 0.055 percent [as compared with less than 0.01 percent

via our eq (7)].

2.7 The Heats of Vapori zat ion we have used the Clapeyron equation to compute heats of vaporization, , in J /mo 1

,

Q

= 1 00 »T •

( dP / dT ) V• ( v - v ) (6

vap 0 g x,

where dP

Q /dT from eq (2) is in units of bar/K, and v = 1 /

g

, v

v

= 1/d^, in

units of L/mol, are from eqs (3) and (4). Results are given in table 13.

2.8 Saturated Liquid Enthalpies and Entropies

These formulations save computer time when calculating compressed

thermofunctions at T < T

^

. He computed 24 data along the saturated liquid

boundary from T

t through T

c by using the ideal gas functions, tne EOS, ana heats of vaporization. Each of the following fitting equations is constrained to the end-point values. lie define the normalized argument,

u(T) = (T

c

- T ) / ( T c

- T

t ), when these enthalpies 1I Q

in J/mol are given eg

7
(H

0

- H

c

) / ( H t

- H

c

) = u + (u p - u ) • [A

i + A ^ • u

a + sum]

(9)

7

i 2 sum = Y A

i * u

i = 3

1

where 3

= 0.35, a = 0 . 70 , H t

= 0 .797 J/mol

,

H

c

= 17073.874 J/mol , and

A

1 = 0.456 446 719 A5 = 3.744 016 417

A

2

= 0.017 191 502 A

6

= -2.788 695 456

A

3 0.207 055 552 A

7 = 0.699 929 755

A

4

= -1.906 453 736

For the 22 data at T

t

< T < T

c

, the rms relative deviation is 0.021 percent

The greatest absolute differences are about 2 J/mol at T

= 370 .0 and T = 37

These enthalpies appear in table 13 under heading H.

The entropies, S

Q

in (J/nol)/K, have been formulated with a minimum of

constants because the formula is used to obtain specific heats along the liquid

boundary, C Q

( T ) = T • dS

Q

/ dT . The arguments are x(T) = T /

c

, u(T) e (T

c - T)/(T C

- T

t ), and we use the constant k = £n(T t /T c ), when,

( S o

“ S c^ 7 ^ S

t

“ V = u 3 + A-| • [£n( x) /k - u 3

] + A^-Lu 2

- u p

] , (10)

where 3 = 0.35, S

t = 109.28667, Sc = 167.26532 (J/mol)/K, and

A

1 = 0.412 265 764 Ao = 0.212 761 017

For the 22 entropies, obtained as described above at T

t

< T < T

c

, the rms relative deviation is 0.072 percent. The greatest absolute deviations are about

0.1 (J/mol)/K.

The saturated liquid specific heats, 0 (T) in (J/mol)/K, obtained from

eq (10), use S

n

= b

t

- S

c

, A3 e 1 - A-j - A ^ » and

sum = 2*A,, *u + A q *3*u p "* , (11)

L. O

when,

C 0 (T) = S

n

• L A 1 / k + x* sum* ( du/dx) ] , (12)

where (du/dx) e -

c

/ (

c

- T

t

)

. Results for b ( T ) are given in table 13 under

iieading 5, and for 1 (T) under heading OS.

3. Computational Methods

The numerical values for E and H in this report are based on the assigned

value, E = 0 at the liquid triple-point, obtained by use of the arbitrary value,

E^ = 13400.138 J/mol. Specific heats of Ciauque and Blue [17] could be

integrated to give the solid at T = 0 as reference state.

3.1 The Homogeneous Domain

The homogeneous domain of figure 1 includes all regions which can be

attained along isotherms starting at zero density without crossing the

8
vapoi -liquid dome, and without passing very close to the critical point at

T > T c . Computations start with ideal gas thermodynamic functions at zero density,

anu then continue by integrating numerically along isotherms by using the

equation of state in the following relations,

AE = / IP - T*(3P/3T)].dp/p 2

, (13)

AC

y = -T

-J ( 3 2 P/3T 2

) -dp/p 2

, (14)

o r

^ LS = R ^n[P / ( P RT ) ] + / LR - (3P/3T)/ Pj «dp/p . (15)

Jo

equation (15) is for use with initial entropies in hypothetical ideal gas states

at P° = 1 atm (0.101325 MPa). For all other initial states,

AS =

- J

(3P/3T).dp/p 2

. (15a)

In eacli (p,T) state, reached by above integrations, the following are computed,

H = E + P • v , (16;

C

p = C

v + T-( 3P/3T) 2 /[(3P/3T) •p

2

J 07 )

= C

p -(3P/3p)/C

v

. v 18;

3.2 The Saturated Liquid

Mt temperatures from the triple point to the critical point, thermofunctions

for the saturated vapor are obtained via eqs (13) through (16). Tnen eq (t>) for

the heat of vaporization, Q vap > is used to compute

AH = - Q , AS = AH/T , (

1 9

such that tne free energy of vaporization, AL = AH - T»£,S, is zero. See

section 2.8 for consistency of the formulations. Having obtained II and a for tr.c saturated liquid, E = H - P • v is computed.

The single-phase specific heat, L

v (p,T), at the saturateo liquid oounuar;.,

is obtained from eq (10) using C

Q (T) = T*dS Q /dT ano the thermodynamic relatio-.

C

v (p,T) = C q (T) + T-(3P/3T) *(d Pj,/dT)/p 2

where p^ is density of the saturated liquid,

tiiis boundary follow from eqs (17) and (18).

boiling point, the following values have been

Values for C

p

( p , T ) ana K ,7

For liquid II 25 at the normal

obta i ned

,

n

T

b = 2 1 2.874 K,

E

b = 1690 .3 J/mol

,

H

b

= lb 94 .3 0/mol

,

S

b

= 117.871 ^J/f9
3.3 The Compressed Liquid

Starting with abuve values for E, 5, and C

v on the saturated liquid

boundary, eqs (13), (14), and (15a) are used to integrate along isotherms, and

then H, C

p

, and U are obtained via eqs (16), (17), and (18).

3.4 Fugacity Coefficients

The fugacity coefficients in table 14 were computed along isotherms relative

to properties in hypothetical ideal gas states at a pressure, P° = 1 atm

(0.1 01 325 IlPa) ,

(f/P) = (P°/P) -exp UO/RTj . (21 ) For any (P,T) point, the isothermal free energy change is

^C = (H - E°

q

) - H° - T • ( S - S°) , (22)

in which the arbitrary value of E ° was added to tabulated values of H ( P , T

)

such that E(P,T) = 0 for liquid at the triple point.

4. Tests and Conclusions

Vapor pressures of H^b at T > 325 K iiere are based only on data of

Reamer, et al. [38], with no independent data for comparison. Saturated liquid

densities of Reamer, et al. at T > 325 K become smaller than our fitting function

by up to 2 percent. (Similarly, tneir vapor densities (not used uere) are greater than from our fitting function by several percent.) The liquid densities

of Baxter, et al. L 2 j we concluded to be wrong, and then found that Clarke and

Clew [8] had reached this same conclusion. The critical density of 1125 is not

known accurately. Data for vapor pressures and orthobaric densities measured by

Kay and Rarnbosek [27] were discovered after the present work was completed.

Their critical constants were T

c = 373.07 + .06 k, P

c

= 8.9432 MPa,

d

c = 10.167 mol/L. In .Appendix C the data are compared with our results from

eqs (2), (3), and (4). Their vapor pressures are slig fitly higher than ours (based on Reamer, et al.). Their orthobaric densities, however, uiverge from

ours at higher temperatures in the same sense as those of Reamer, et al.: liquid

densities are lower, and- vapor densities are higher. The critical temperatu re in

1 x [27] is lower tnan ours (373.40 K). Small changes in the assigned critical

temperature have an enormous effect on ttie "fit" of orthobaric densities data near T c

. The above experimental ortuobaric densities deviations suggest that

T c should be lower than used here. This simplistic conclusion, however, is not

necessarily correct, in view of gravitational effects in the experiments, because

the compressibility, 9p/9P, becomes infinite approaching the C.P. This problem

iias been addressed by Weinberger, et al. [47a], Ulybiri, et al. [46a], and by

Moldover, et al. [32a], in no case reaching a definitive method to adjust the

experimental observations.

Some vapor and liquid densities of Reamer, et al. [38], not used here, are given in Appendix D. The obscure "apparent molecular weights," M , of Wright ano Maass l 4 9 ] we finally ueduced yield densities p, in mol/L, via

10
P = (M/M

0

) • P / ( R • T

)

where M

Q

= 34.08 is the correct m.w., and we used their gas constant, R' = 0.08206

( L • atw/mol ) /K . Results are tabulated in Appendix E. It is improbable that tnese

data would significantly affect the EOS developed here.

Compressibility data in table 6 apparently are not of the accuracy and

precision usually needed to establish a valid EOS. Also, no data have been founo

from the t r i p 1 e- po i nt , 188 K, up to 278 K. With the present type of EOS,

however, our greatest problem for H^S has been to derive credible specific

iieats on the liquid boundary (see below).

Our derived heat of vaporization at the normal boiling point ( n b p ) is

18.679 kJ/'mol as compared with 1 8 .673 + 0.02 kJ/mol measured by Ciauque and Blue

(G/B) [17]. Our derived saturated liquid specific heat, C 0 (T), at the nbp is

68.77 (J/mol)/K as compared with 68.3 (d/mol)/K observed by C7B.

A comparison with thermofunctions derived by Starling l42j is presented in

taDl e S along seven isotherms from 25 5 through 478 K at pressures through 20 lir’a. The nearly constant enthalpy differences arise because we believe tiiat Starling

adjusted his ideal gas state enthalpies by the heat of formation of H^S from

the elements at stanaard conditions. The nearly constant entropy differences may

be due to different ideal gas state values used. Thus we conclude that our results are consistent with those of Starling.

The single-phase specific neats at the liquid boundary, L

v (p,T; 0

, are derived here for H?S via eq (20), which is a difference of two terms because

(dp^/dT) is negative. Values for L

v (p,T)0 under heading tV_ in table 14 diminisn

uniformly from tiie triple point temperature up to 350 K, above which they

increase sharply, as needed for consistency witii an infinity in C

y (p,T)

approaching tiie C.P. Our extensive efforts to modify this oehavior have been

f ru i 1 1 ess . For ethane [20], nitrogen trifluoride L23j, and for ethylene [47], C

v (p,T; 0 at first decreases vs. T, and then increases, in each case with a minimum near

(T

t + Tc )/2. For carbon monoxide [21], however, we encountered tne Same

general behavior as found here for H

£ 3

Values for C

p (p,T) in the compressed liquid depend uirectly on tne derived

t ( T ) along the liquid boundary, due to the method of computation. n consistency check along isobars can be made via C

p = (3H/3T)

p

. For isobar

P = 8.0 MPa in table 14, from T = 340 to 350 K, 611/^T = 91.31 ( J / m 0 1 ; / k , a no i<_

average specific heat is C

p = 91.73 (J/mol)/K, in good agreement, also in

this interval, L\\ = 913 J/mol, and T *63 = 908 J/mol, wnich agreement is gooo

considering the large (10 K) interval at T not far below i c

. Dr. [. Haar has suggested a closed loop consistency test. On figure 1,

compute along the 330 A isotherm from p

= 0 up to tiie liquid coexistence boundary

at p near 20 .34 mol/t. Then compute along this isochore up to 41b k toC . Tnen compute along the 415 K isotherm oown to p

- 0. Finally, at p

- c 0 r y u c

from 415 K down to the starting point at T = 330 k. Tne only computation not

already done is along the isochore at 20.34 mol/L from 3 30 to 415 n, aid tins

11
involves derived specific heats C

v

( T ) along this path, which data are well known

to be difficult to derive with good accuracy.

figure 4 is a plot of tnese isocnoric specific heats, estimated from out- table 14. As this curve is not easily represented by a polynomial, we nave summed the trapezoiual areas between adjacent points to compute AE aiiu AS from

330 to 415 K, and then have compared these results with changes obtained from

table 14:

AE , J /mol n S , J / mol /K

Integration of L

y (T) 3141 8.40

Estimated from table 14 3346 8.63

The differences of only about three percent probably are within uncertainty of

tiie numerical integration, and thus confirm the t hermody nam i c consistency of the

present work.

Experimental determinations of specific heats C

Q

( T ) for the saturated

liquid, and of C

v (p,T) for the compressed liquid are needed to obtain any

higher accuracy, because tne computation of these specific neats from only a P(p,T) surface is notoriously difficult, involving first arid second derivatives

and differences; and tne need for very accurate saturated vapor densities

(which usually arc not available).

5. Tables of Physical anu Thermodynamic Properties

5.1 Calculated P-p-T Isocnores and Isotherms

Tables 10 and 11 give a selection of isochores and isotherms computed by

equation of state (6). These are essential to examine behavior of the P(p,Tj

surface. They are a useful supplement to tne isobars of table 14 for

interpolating P-p-T values and their derivatives.

Tne tables of isocnores show that the isocnore curvatures are qualitatively

consistent with a maximum in the specific heat o

v (p,l) at the critical point.

The isotherm tables snow that 3P/3p is nonnegative and that pressure increases

monoton i cal ly with density along isotherms.

5.2 The Joule-Thorn son Inversion Locus

Table 12 gives the P-p-T locus of the JT inversion, ( 3 T / 3 P ) ^

= 0,

obtained from equation of state (6; under the condition, T*(3P/3T) = p*(3P/3p;.

Tnis table lias been computed to temperatures well above tuose of P-^,-1 data, to

show approach to a maximum in P-T coordinates.

6.3 Properties of the Saturated Liquid

Table 13 gives physical and thermodynamic properties of the saturated liquid

computed by methods of section 3. (Properties of tne saturated vapor can be

Obtained from Table 14 from values given at cue coexistence boundary for eacn

i sobar . ) 5.4 Properties Along Selected Isobars

Table 14 gives piiysical and thermodynamic properties on isobars, computed by

methods of section 3. These tables include values beyond tne range of the data

used for adjusting the equation of state. Small discontinuities may be detected

12
at T o . 96 o 1 1 P a uue to a C I i a n g 0 in tilt p a t n S c

= 373.40 k along isoburs at P > P c = of coi.iputation (section 3).

The first line of each table refers to freezing liquid on the P(T; melting

line. Eacn table at P < P

c contains a blank line for the transition from

saturated liquid to vapor, as seen ug tiie abrupt decrease of density.

6 . Acknowledgments

Many staff members of the Chemical Engineering Science Division of the

national Bureau of Standards (DBS) nave contributed valuaule suggestions,

references, and documents. kubert D. McCarty coritriouted trie essential

1 east- squares program, providing for constraints. James P. Ely inoicated the nev/

numerical integration procedure, and the simple method for obtaining fugacities.

Ileil A. Olien and Jo Mendenhall nave been of invaluable assistance in supplying

references arid in procuring documents. Karen A. Bowie deserves special

appreciation for preparing the manuscript for publication. he express grateful

appreciation for support of this work by tne Gas Research institute and the

technical coordination provided by Dr. Frank Little.

13
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modifications to polar yases. Chem. Eny. Science 32(9): 1 1 U 3 ; 1 97 7 . l13j Dyiuonu, J. H.; Smith, L. B. Tne virial coefficients ot pure yases unu mixtures. Fairlawn, N . J . : Oxforu Dniv. Press; 19 7 9.

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0^, H^S, P h

3

, A, COS, CH 4 und UijD. z. Phys. Cheni. (Leipziy) B42:

395-421; 1939.

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thermodynamic and spectroscopic values ot the entropy. J. Am. Cnem. Soc. 68 : 831-837; 1936, May.

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Lit>j uni li land, E. k.; Scheeline, H. W. Hi y n- pressu re vapor-liquid equilibrium:

For the systems p ropy 1 ene- i sobut a ne and pro H ane-hy droy eri sulfide.' Inu. thy-,

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pressures to 700 bar. Hat. bur. Stand. (d.S.) Tech. Note 084; 197o Auyust.

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pressures to 100 MPa. Submitted to J. them. Phys. Ref. Data.

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to 700 k at pressures to 70 MPa. Hat. Bur. Stand. (U. 8 .) Teen, note 1051;

19o2 January.

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1946 .

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Novemoe r

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15
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16
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17
Appendix A. Fixed-Point Values for Hydrogen Sulfide

Triple Point Boiling Point Critical Point

Temperature, K 18 7 .66 212.874 373.40

Pressure, PIP a 0.02320 0.101325 8.96291

Density, i.iol /L

Vapor 0 . U1 496 0 . 0 5 o4 3 10.2

Li quid 29 .136 27.845 10.2

18
Appendix B. Symbols and Units

Subscripts £ and t_ refer to critical and liquid triple points

Subscripts £ and £ refer to saturated vapor and liquid

Subscript £ refers to liquid-vapor coexistence

Superscript £ refers to ideal gas states

,y ,e ,n,p

B(T)

B ( P ) , C(p)

C

V (P,T)

C

p

( P ,

) C 0 (T)

aE(P,T)

E° H°o f/P

F(P,T)

C(P,T)

H(p,T)

J

Lmol

P

exponents in various equations

second virial coefficient, L/mol

coefficients in the EOS

isocnoric specific heat, J/mol/K

isobaric specific heat, J/mol/K

saturated liquid specific neat, J/mol/K

density, mol /

internal energy, J/mol

13 400.138 J/mol (arbitrary)

fugacity/pressure ratio

defined function for the EOS

Gibbs free energy, J/mol

enthal py , J / mol

enthalpy for ideal gas state at T

= joule, 1 N • m liter, 10“ 3 m

3 34.08 grams of

0

Ho s N/ m

3 pressure in MPa (1 MPa ) = 10

1 atm = 0.101325 MPa = 1.01325 bar

(

1 bar = 10 b

U/r.i 2

) ,

F

0 (T)

p

0 (p)

n(T)

* ( P ,T)

f(p,T)

Q v ap

RR*

P

S ( p , T

)

T

T

0 (P)

9 (p ) u (T

)

v

uj ( p , T )

H ( p , T ) x(T)

x 0 (p)

i.(P.P,T)

melting pressure, MPa

vapor pressure, MPa

P 0[ T 0

( p ) ] , vapor pressure as function of density, MPa

p 0

( T ) / P

c ’ reduced vapor pressure

function in t h e EOS

function in the EOS

AH vap , heat of vaporization, J/mol

gas constant, 8.3145 ( J / r.i o 1 ) / K , 0.0083145 (MP a • L / mol ) / K (0.0083145) d

c

, MPa/K

d/d c

, reduced density

ent ropy ,

( J /mo 1 ) /

temperature, K liquid-vapor coexistence temperature, is defined locus of temperatures, k defined in various equations

1/d, mol a 1 volume, L/mol

LI - e ( P j / T J , for the EOS

speed of sound, m/s

T/T reduced temperature

T (p) /T

c

. reduced coexistence temperature

the "compressibility factor"

19
Appendix C. Coexistence Data of Kay and Rambosek

HYDROGEN SULFIDE COEXISTENCE DATA OF KA Y/R AN80SEK» VS. RDG (CALC)

T PRESSURE. MPA LIODEN# HOL/L GASDEN, NOL/L

K DATA CALC PCNT DATA CALC PCNT DATA CALC PCNT

272.039 1.0032 .9991 .41 24.977 24.552 1.73 0.0000 0.0000 0.00

277.594 1.1728 1.1735 -.06 24.573 24.207 1.51 0.0000 0.0000 0.00

283.150 1.3707 1.3693 .10 24.159 23.853 1.28 0.0000 0.0000 0.00

283 .706 1.5865 1.5879 -.09 23.727 23.489 1.01 0.0000 0.0000 0.00

294.261 1.8285 1.8308 -.13 23.290 23.113 .77 0.0000 O.OOOC 0.00

299.817 2.0974 2.0995 -.10 22.843 22.723 .53 0.0000 0.0000 0.00

305.372 2.3945 2.3956 -.04 22.383 22.319 .28 0.0000 0.0000 0.00

310.928 2.7207 2.7206 .00 21.927 21.898 .13 1.3631 1.3582 .36

316.433 3. 0785 3.0762 .08 21.443 21.457 -.07 1.5605 1.5461 .93

322.039 3.4681 3.4640 .12 20.963 20.993 -.14 1.7720 1.7570 .85

327.594 3.8928 3.8858 .18 20.441 20. 501 -.29 2.0305 1.9948 1.79

333.150 4.3547 4.3434 .26 19.891 19. 977 -.43 2.3078 2.2645 1.91

333.706 4.8504 4.3389 .24 19.295 19.413 -.61 2.6321 2.5737 2.27

344.261 5.3839 5.3743 .27 18.660 18.797 -.73 3.0082 2.9331 2.56

349.817 5.9681 5.9521 .27 17.955 18.112 -.87 3.4594 3.3602 2.95

355.372 6.5941 6.5752 .29 17.179 17.331 -.87 4.0328 3.8846 3.82

360.928 7.2712 7.2470 .33 16,258 16.396 -.84 4.7473 4.5647 4.00

366.433 8.0013 7.9723 .36 15.041 15.170 -.85 5.7484 5.5460 3.65

3 72 .03 9 8.7901 8.7588 .36 12.526 12.956 -3.32 7.9904 7.5394 5.98

373.094 8.9432 8.9166 .30 10.120 11.623- 14.40 10.1666 8.6225 17.91

20
Appendix D. Vapor Densities of Reamer, et a 1 . [38]

(Not used in table 3)

Temperature, K Density, mol/L

282.706 0.6922

298.150 1 .0355

31 1 .539 1 .3941

323.1 50 1 .7739

331 .483 2.1824

338.761 2.6260

345.428 3.1 226

352.039 3.6909

358.094 4.3766

363.539 5.2177

368.706 6.4254

373 .1 50 9.5633

373.539 10.2354

Liquid densities not in table 2 368.706 14.201

37 3.1 50 10 .566

373.539 10.235

21
Appendix E. P-p-T Data of Wright and Maass.

T»K P, MPA MOL /L

320.15 , 3 2 3 6 9 P .163928

320.15 .363170 .139592

320.15 .326573 .123782

320.15 .236636 .093070

320.15 .235713 .093687

320.15 . 1

c 3 C f 3 .053121

320.15 .122923 .036630

320.25 . C 9

p 099 .037078

320.25 .095805 .036212

320.25 .050009 .018852

320.25 .050503 .019022

295.15 .32363? .177019

293.15 .375836 .156133

293.15 .309331 .127936

293.15 .257036 .105757

295.15 . 2 3 3 6 P 1 .095909

293.15 .1 P9051 .077333

293.15 . 1 30733 .057375

293.55 • 1 C 0° 5 B .030639

2 9 “ . 2 5 .099086 .030308

293.55 .099099 .030226

295.25 .093699 .030115

298.55 .065701 .026599

295.^5 .066953 .027138

295.65 .035157 .013203

298.65 .033717 .013022

273.25 .375302 . 1 7

0 75 273.25 .375169 .171668

273.25 .317307 .133291

773.15 . 2756 7 7 . 1 2 3 ? c 5 273.15 .221638 .09973*-

273.16 .17225? .07717e

273.15 .165320 .073093

273.15 .096232 .032793

273.15 .099285 .033126

273.1-6 .099072 .033070

273.15 .09P779 .033926

273.15 .0°6319 .033055

273.15 .096699 .033013

273.15 .050929 .022589

252.95 .302797 .201953

252.9; .338239 .163030

252.95 .305175 .150637

252.95 . 23??3P .113665

252.95 .212516 .103653

252 . 95 .160520 .07782?

252.95 .099938 .033103

252.98 .096079 , 03666 c 237.95 .271311 . 133CP6

237.95 .205983 .107372

237.95 .16?720 .083813

237.95 , 1 3 0 7 8 8 • 0 ? 6 9 ? 3 237.95 .100152 .051378

237.95 .063220 .033132

22
onnooonn

Appendix F. Computer Programs

BRnORA* H 2 S Thp r (n , IT>J ijT,TAPF?0*IN o U T *T4 o E20)

HYOPDGEN SULFIDE TH ER m 0 FIJ N C T I OS S , APPIL 15, 19«3 START.

C p-psaT * S*GK*(T-TSAT) + S * S * GK * T C P T* F ( S , T ) , W«F»E - F(S,T) « B(S)*XRF(S,T) + C(S)*XCE(S,T) F ( S ) * x E F ( S » T )

,

XRF * (X - VS), X * T/TC, XS * TS/TC,

XCF « ( x**EP ) *EXP ( A* ( 1-TS /T ) ) - X S * * E P, A * (1-EP)*S0RT(1-EP),

X E F # H(P,T)/HS(P) - 1.0, W # (1-TH/T), w E # W**E

,

H(P,T) # l.o - (W-ue/E) /(1-1/E >, E * ET.

B ( S ) * B1 + B2*S + R3*S7, C(S) # Cl C2*S + C3*$2,

E ( S ) # E1*(S-])*(S-EP)*Exp(-GA*S**IX).

G A # ( 2 *ER-3 ) M E

p -1 ) / I X FOP INFLECTION AT S 1.

W HE p E » P * DFN/DTRP, S * DEN/DCPT,

Common IX,pp,GK,GKK, A1.A2.A3, B 1 , P ? , 3 3 , C1.C2.C3, F1.E2.F3

Cr)M wn M /1 /A L ,RF,GA»OE»EP,E T . DCRT.TCRT.oCRT, DGAT,DTRP,TTRR,pTRb

C n«MOs/3/DPDT,0?PDT2,0PS0T,D° M DT,DPD0,DPDR,0TS0P,DTHDP,CDS0T

C0HMnN/4/XBl,xR2» XC1.XC2 , XE1.XE2, D X B D R » DX C n R , DX E DR

C 0

M M ON /6 / TSAT, THFTA, PSAT

CO'MnN/B/lK.lK, P,T,OEN, E.H.S, CV.CP.CSAT, W,UK

/ 1 1 / D

c L S , DELCV

CPMmpn/1?/7CRT»ZCALC«DZDT» 7 S AT , D7SDT, 7 F X, FRT.DFRTDT

Common / i q/ ON G, FG, HC-, SG, CVG.CPG.UG, OPGDT.DPGOD

CnMHlN/7l / T ° S ( 7 0

)

COMHON/95/ PIS, DIS, 0

0 T I S , D p D I

COmmon/sic/ T I , E Z Z » EZ.SZ.CVZ, H7,CPZ

OImfnSIQn H 7 A ( 1 r o ) , SZA(IOO), PR(99)

OATA(UK«R<r .o«),(PA=l. 01325), ( G J 8 . 3195)

1

Fn^iTds 2 F 1 C . 0 ) 7 FDPM4TLI5, 3F1G.0)

3 FDPHAT{?I1C)

5 F

r'°“AT ( I V ) 9 FORMAT ( 3F1C. 0

)

14 FORKATLl*-1 ! 21X * MVipnQEM SULFIOF ISO RAP AT 0 * * F9.5, 4H “PI/)

19 FORMAT ( l 4 X 1HT 9 X 'P HD E N BXlHZ 5 XS HDP/^T 5x6 HOP/OO

2 «X1M= R x

h H R X 1 M S B x 2 HC V 6 X 2 HC 0 PX3HF/P 5 X 1 H W / 3 1 4 X 1 HR 7XSHM n L/L 9 X 5X5HMPA/K 1 X9 H«

p

4 - L / MQL

4 4X5MJ/M0L 4XBHJ/M0L 2X7HJ/MOL/K 1X7MJ/M01/K 1X7HJ/MQL / K

c 11* IXBmim/SEC ) 17 f 0 ? M A T ( 6 X F9.R, E 1 2 .

‘p , F 9 . 5 , c 1 0 . 6 » F 1 0 . 4 ,

1 ?F9.1, FQ.3, 2 F 8 . 2 , Ell. 4, 16)

20 FORM AT ( 1H11*X*TFST IDEAL FNCTNF*/17X 3HT.K 7 X 3 HH Z A 7X3HSZA ) 21 FORMAT (

rv FI r ,2

,

F 1 0 . I , c

1 D . 3 ) 25 CALL PVTDATA

C NOTE , RETURN, IN CQFXIST AT 16+ FOR USE ONLY WITH SSATFIT.

CALL °EEP J CALL ISOTHRM

CALL JTLPCUS

CALL tarlic

C SAVE HZ A ( 100 ) , S 7 A ( 1 0 0 ) F R 0 M 190 THRU 7C0 K. 85 DO R5 J = 1 9 » 7 0 1 TI * 1 0 + J T CALL IDEAL i HZA(J) * w 7 86 SZ A ( J ) = SZ 84 GO TO 90

97 ppinT 20 T DC 88 J*19,70 % T 10*J

8 R PRINT 21* T, H 7 A ( J ) , SZA(J)

C

C COMPUTE THFR MOFUNC TIHN S CN ISOBARS. START PN THE M ELTING LINE.

C NOTE, I S 0 0 A P P-PCRT OR. 8 UT ISOTHERM T-TCPT IS EXCLUDED.

C ISO c ARS AT R UNDER °CRT TRAVERSE THE DO M E.

C NPTF USE OF OVAD .DATA. TO CRO^S THE » DO M F » .

C NOTE USE P F CSAT .DATA, fnP SPECIFIC HEATS IN CPMpRESSf '

1 L 1

1

1 0 •

23
Appendix F. Continued

C NOTE TPS(IX) USED BY C 0

M PR E S S AT T.LE.TCPT.

C GET FUGACITIESf F/R, VIA H,S, HZ(T),S7(T). (J.F.ELY).

90 IN - 1 t NI . 56 * READ 9, ( PP( I ) » I»1 »NI ) 91 DD 300 I I N , N I t IK « I $ LS - 0 9? P * P P ( T ) J IFU.F0.32) P PC R T 93 PK p/10 i PRINT 1*, PK % PRINT 16

100 T FTN0T*F(P) % CALL COMPRLC $ V-l/DEN % IW«W

101 Z * P/DPN/GKK/T

102 TI - T i CALL IDEAL $ GI3 » H-F77-4Z - TMS-SZ)

103 XP - E XP (GI B/GJ /T ) T FOP XP*PA/P * CALL CON

10* PRINT 17, T,DFN, 7, DPTIS, DPDIS, E,H,S»CV,CP, FOP, IV

105 IT - T/10 J IF(P.LT.pCPT) 110,180

C CASES FOR P LESS HAN PCPT.

110 T P S ( I k ) « TS « FINDTSF(O) $ k . L « 0 111 DO 150 J * 1 , 99 5 T * J T * 10*(IT*J)

112 IF(T.LT.TS) 113, 11«

113 CALL C 0

M P P E S % IV - W J 7 - P/DEN/GKK/T

11* m J T / 1 0 * GIP h-E7Z-hza(*) - T*(S-SZA(M))

115 XP • EXP(GIP/GJ/T) $ FOP * X P# P A / P S CALL CON

116 PRINT 17, T, 0 E N , Z, DPTIS,QP0IS, E , H, S , C V ,

0 , F0P,IV

117 GO TO 150

IIP LS « LS 1 1 IF(LS.EO.l) 120,130

C CASE FOR SATURATED LIQUID AND VAPOR.

120 T - TS T CALL COEXIST t Iw « u $ I ,r. . WG

121 Z • P/DEN/GRK/T % ZG p/DNG/G k K/T

123 GIP » H-EZ7-HZ - T*(S-SZ)

12* FOP * EXP(GI3/GJ/T)*pa/p $ CALL CON

125 PRINT 17, T , D E N , Z, DPTIS,DPDTS, E»H,S,CV,CP, FPP,IW

1?^ PRINT 5 ? DIS«0NG*W" \ DPTI S-DPGDT/10 T DPDIS DPGDD/10

127 PRINT 17, T » QNG > 7 G , D p T I S , 0 PD I S , FG, MG, S G, C VG» C PG, F 0 P , I WG

1?B T « JT

C CASES for THF HOMOGENEOUS DOMAIN.

130 I F ( JT.GT.500) 133,135

133 K K + l % T - JT - JT 4 1 0 * K 13* IF ( JT.GT.700) 3C0.135

135 CALL GENIUS T Iw » w * Z« p/DEn/Gkk/T

136 h J T / 1 0 i GIP * H-E 7 7 -HZ AM) - TMS-SZA(N))

137 xp « EXD(GIB/GJ/T) $ CO 0 « X o * o A / P $ CALL CON

1*1 PRINT 17, T,DEN, 7, OPTIS,OPDIS, E,H,S,CV,CP, FOP, TV 150 CONTINUE

C FOP P.GF.PCPT, CASES Fop T . L T . OR . T . G T . TC R T . 180 TPS ( IK ) TCRT % K L 0 1P1 DO 250 J-1,99 1 T - JT - 1 0 ( I T J

)

102 IF (T.LT.TCRT) 19", 210

C CASE A for t LESS Than TCRT.

190 CALL COMPRFS I IV V % 7 P/DEN/GKK/T

192 « .jt/10 5 GIP - h-E7Z-HZA(N) - T* ( S-S Z A <h )

)

193 XP * EXP(GIP/GJ/T) % FOP - X P * P A

/

p $ CALL CON

194 PRINT 17, T , 0 E N , Z, DPTIS, DPDIS, E.H,S,CV,CP, FOP,IW

195 GO TO 250

C CASE F n R T ABOVE TCRT, H0POGFNE0US DO-AIN.

210 IF ( JT.GT.50G) 233,220

213 K - K4l % T , jT . jt 10*K

21* IF (JT.GT.700) 300,220

220 CALL GENIUS S IW - W t Z • P/DEN/GKK/T

22* M .JT/1C $ GIP = H-FZZ-HZA(M) - TMS-SZA(M))

225 XP EX°(GIB / G J / T ) t FQP « XP7PA/P $ CALL CON

2’6 PRINT 17, T , DE N , Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IV 250 CONTINUE

300 CONTINUE

999 STO°

END

24
Appendix F. Continued

c

cc

c

c

c

SU bo Q'JT II-E COEXIST

GIVES T AT COEXISTENCE, GET BOTH VAPOR AND LIQUID FUNCTIONS.

FOR VAt>00, GET PNG.FG.HG.SC-* CVG .CPG, WG, DPGDT.DPGDD. -

c OR LIQUID. GET Dbn,p,h,S, C V , C b , C S A T, w . D°DT,DPDD.

COEXIST CALLED BY C Q

u D O L 0 . P NOT USED, *UST NOT CHANGE.

CC|H“Hn/i/4L ,BF,GA»DE,E p »FT. DCRT.TCRT.PCRT, DGAT,DTBO,TTRD,t>TRO

CO M HON/3/nPOT,D? D DT?,r)PSDT,DPMDT,D c, Dn,OPDO,DTSDP,DTHDP.DDSPT

CPHia N /o/ IN, Ik, D , t , 0 p N , F » H , S . CV.CR.CSAT, W.VK

COHMON/11/ DELS, DELCV

COSMGN/lo/ DN5.EG.HG.SG. CVG, CPG, WG. DPGDT.DPGDD

C0HN0N/9Q/ T I , E ? 7 » F7.SZ.CV7. H7,CPZ

DATA (0*1. 01325), (C-*Q.O«31A5),(W'»3A. 0 80 ) 1 FORMAT (1HQ Q x * T EXCEEDS TC R T IN COEXIST. * / ) WK * 10C000/W M

2 IP (T.GT.TCRT) ’.A

3 PPINT1 S STOP

A PS * ? S A T F ( T ) « DNG * DB DENGASP(T)

5 T I * T * CALLIDFAL * " » 15 T DA * L • 0 5 EG = C ZZ EZ PD PL R ( L , h , T, DA , QP ) «. hg = EG + 100*°S/D3

7 SC- « SZ DELS - 1 30*G* AL OG ( G*T*DB / 0 ) t GF * EG

B IF ( T.EO. TCPT ) 9,11

9

PX * D VTF(T.DB,1) i DPC-DT = DPDT i D P GDD * DPDD

10 C p G * CVG = w 0 * 0 * GO TO 15 11 C VC- * CVZ + DELCV < PX * PVTF(T.DB,l)

1 ? CPG CVG + 100*T/OBQD*(DOOT/OB)**? * WG * S QR T ( WK * C

D C-* D PDD/ C V G ) 13 PPGPT = DP0T $ OPC-DO * DPDD

NOW travprse THE . D0 M c» U^ING QVAP .DATA.,

15 DEN * DL * DENLIQF(T) % DDLDT * PPSQT t QV OVAPXF(T)

1 ,, H HG - QV f S * SG - OV/T S E « H - 1DQ*PS/DL

This PF TURN AT 16+ US F D ONLY WHEN CALLING SSATFIT, HSATPIT.

17 IF(T.fo.tcRT) 18,19

1 P PX * PVTP(T.DL.l) ? CP*CV*C SAT»«=0 T RETURN

19 CSAT » CSATXF(T) t »x « PVTF(T.DL.l)

22 C V * CSAT + ico*T*DPQT*DDLDT/QL/DL

?B CP = CV 1 00*T/PPDn * ( DPDT/DL ) ++?

30 W * SQR T ( WK*CP*D?no/CV) % RETURN

END

25
Appendix F. Continued

SUBROUTINE CG^PRES

C SAVES Cn MD UTFR TI“E INTEGRATING COMPRLIO AT T.LT.TCRT.

c FOR T = INTEGER MULTIPLES OF 10 K. FIPST ISOBAR USES COMPRLQ.

C F np SUCCEEDING ISOPARS, START ON PREVIOUS ISOBAR, EXCEPT -

C AT TEMPS GE TPS(IK-l) ON PREVIOU' ISOBAR, «UST USE COMPRLO.

COMMflN/1/ & L , BF»GA, 0 e , E R

, FT , DC R T , TC R T , PC R T , D G A T , D TR P , TT P P , PTR P CnM M 0N/?/DFDT,D2 5 DT2,DPSDT,DRMDT,DPDD,DPDR,DTSDP,DTH0R,DDSDT

COMNON/8/ IN, IK, o,T,DEN, E , H , S , CV,CP,CSAT, W,WK

COMMON/ll / DELS, DELCV

CO M MDN /? 1 / T P S ( 70

)

DIMENSION DK (AO) *fk ( 4 0 ) , S K ( 40 ) » C k ( 40

)

1 EOR M AT { 1H0 9X * T G.E. TCRT IN COMPPES. * / ) 2 IF (T.GE.TCRT) 3,4

3 PRINT 1 t STOP

4 J * T/10 t IF(T - 10*J ) 5 » fc 5 CALL COMPRLO < RETJRN

6 IE(IK.FO.IN) 7,9

7 CALL CO m °FLO

B DK ( J ) = D E N < EK(J)=E S S K ( J

) * S $ CK(J)=CV $ RETURN

C INTEGRATE F R G

M OLD OF N TO NEW DEN ON GIVEN ISOTHERM -

C E X C E

D T IF T EXCEEDS OLD TM4X, IJ S F CP m PRLO.

9

IF(T,GE.TPS( IK-1) ) GO TO 7 ID D A *0 K ( J ) $ DK(J) . D f N * DB * FINDF N F(T,P) * N - 13

11 EK(J) - E - E K ( J ) + EDEL F ( 1,N, T, CA,DB ) T H E + 100*P/DR

12 S k ( J ) = S * S K ( J ) + DELS i C K { J ) * CV = CK(J) DELCV

C GET NEW OP/DT, DP/no, C°, W. 15 p y . PVTF(T,DP,1) «• CP * C V + 100*T/npPD*(D D DT/DB)**3

30 W SDRT(WK*CP*PP r'D/CV) t P F TURN

F n n

SUBROUTINE COMPRLO

C GIVEN P,T FOP COMPR.ITO. AT T.LT.TC, GET DEN AND FUNCTIONS.

C REVISED TO USE HSATF, S^atf, CSATXF, BUT NOT COEXIST. TTMESAVER.

C INTEGRATE ALONG ISOTHERM T FROM SATLIO UP TO POINT (P,T).

CnMMnN/l/AL.BF,GA,DE,E D ,ET, DCRT,TCRT,°CRT, DGAT,DTRP,TTRP,PTRP

C0MMr)M/3/0PDT,D?PDT2,DPSDT,DPMDT,op0D,0PDR,DTSDP,DTHDR,DDSDT

COMm^n/b/ in, ik, p,T,DEN, E,H,S. CV.CP,CSAT, W,WK

COMM 3%| /i i / DFLS, DELCV

C? FUNGS

Ct C A LI S

1 format ( 1^0 9 X *T NOT UN D F R TCRT IN C n MPRLO. + /)

2 IF (T.GE.TCRT) 3,4

3 PRINT 1 J STOP

C GET PSAT, D F N L I 0 , AND SATLIO FUNCTIONS FOR START.

4 PS * PSATF(T) % DL = DFNIIQF(T) $ DDLDT = DDSDT

5 HS « m s A TF ( T ) 1 ES HS - 100WPS/DL % SS - SSATF(T)

9 PX.PVTFf T, D L , 0 ) t CVS - CSATXF(T) + 1 00* T

P D T + D DL D T / P L / DL

C 9 CVS * C V t A T F ( T ) C INTEGRATF IIP TO POINT (P,T).

10 D° * FINDFNF(T,P) % OX = DR - DL * IF(DX.GT.O) 11,20

11 M • li, t E « ES EDELE(1 ,m,T,DL,DB)

12 H - E 100*p/DP \ S « SS DELS 1 C V CVS DELCV

11

P x = PVTF(T,DB,1) « CP = CV 1C0*T/DPDD*( DRDT/DB)»*2

14 W - SQR T< WK*CP*DPDD/C V ) 5 DEN - DB % RETURN

20 DEN-DL * E«ES t H-HS % S-SS $ CV=CVS f PX * °VTE(T,DL,1)

21 CP * C V ) 03 * T / 0 D OD * (OP0T/DL ) + * 2 1 W * S OR T ( W K C P* D P D D / C V

)

30 RETURN

ENO

26
Appendix- F. Continued

SU3R0UTINE CON

CONVERT T n El UNITE FOR P, DEN, DP/DT, DP/DO,

CnMMnN/3/DPDT»02P0T?, DRSDT,DR*«DT,nROD,DPDP,QTSDR»DTHDR,DDSOT

CONDON /9 / IN , IK , R

, T » D E N , E » H » S » CV,CP,CSaT, W,W*

CnHMHN/Q5/ PIS, DIS, 0 3 T I S 0 p D I S DATA ( W M * ? 4 . 0 » ) 1 PIS * p/ 10 5 nis * 2 DPTIS OPOT/1C T 1P0IS « C°DD/1C

9 PET'JRN END

FUNCTION CSATXF (T)

HYDROGEN SULFIDE SATLTO ENTRHpy, J/NPL/K., RDG/NPS, 4/15/83.

YS - ( S-SC ) / ( ST-SC ) , X - T/TC, 4 L T - LNtTT/TC), U « ( T C-T ) / ( TC-TT )

,

C n NETR4lNJED 4T T R I P L F 4 N D CRITICAL POINTS.

Y R - IJR + 41*(LN(X)/AL T - UE) + 4 2 * ( U 2 - UE ) . D 4 T 4 ( TTPP-137.68) . ( T C

R T « 3 7 3 . 4 n ) r 4 T 4 (ES-C.75),(SE-0.65),(STRP = 1C'?.’«667),(SCRT-187.2653?)

0 4 T 4 ( ALT -0.88«01«42)

DATA (41-0.412265764), (A2-0. 212761 Cl 7)

1 FORM4T(1ho 9X CSATyp, T.GT.T r RT. * ) 2 IP(TCRT-T) 3,4,5

3 PRINT 1 ? ST-io

4 CSATXF - 0 « RETURN

5 SN - ETRP-SC?T 1 UN - TCRT-TTRP T X « T/TCkT

6 U = (TCRT-TJ/UN $ DUD X = -TCRT/IJN

7 43 « 1-41-42 ? SU M - 2 * A 2 *U 43*ES/U**SE

8 CSATXF SN MAI/ALT + X*SU M *PUDX) $ RETURN

FND

FUNCTION DFLTAF(T»D)

GET ( T * D p / OT - C* nD /P^) FOR THE J-T INVERSION CURVE.

C0YVQN/1 /AL»°E»GA,DP,E d ,ET, DCPT,TC5T,PCRT, ogat,dtrp, ttr p, ptrp

COMM n N /3/DPOT,D2PDT2»ORSDT,DPNOT,DPDD,OPr'P,DTSDR , D THD R , DO SOT

1 IMT-TCPT) 2,4,4

7 DL - OENLIOF(T) * TF(D-DL) 3,3,4

3 DELTAR = 1.CE+10G % RETURN

4 P - P V TR ( T , D , 1 ) 5 OELTAF - 4«S (T*PPTT-D*DPDP) % RETURN

END
Appendix F. Continued

FUNCTION DFN3AS c (T)

c u 2 s s &tp vaphr densities. rdg /nbs , april 15 , iq«3.

C DESIGNED fop 7 SAT - 1 AT L n w DENSITIES. 5/29/77.

r (7-l)/?N * ( P/PC ) * ( 1 /X2 )*F ( X ) , X = T/TC. U - C 1 - X )

,

C F ( x ) 1 + ( A 1 * U F * A p * U A G A3*'J AA*!J2 + . . )*XP,

C yp * EX°( (3G/X)*(*-1)**3).

Cnii M ON/l/AL»3E.GA»"iE»EP»ET, DCPT»TCPT,oCRT, DGAT .DTRP.TTRP.PTRP

CON^ON/3/DPrT,P2PDT2.DPSD7,DP'<OT,DPDD.D?DP»nTSDP,DTHDR.DnSDT

Cn“ M ON/l?/7CRT,7CALC.DZDT, ZSAT,DZSDT,zfx, F P T» D F R TDT

PI M ENSin^' A V ( 5 ) DATA (NFG- c ).(FG«0. 35). ( AG«0. 70 )»( B G»2.0)»(GKK»0. 083145)

D A T a ( s V * -c. 75257 9795. -D . « 5 5 A 8 11 7, 1 1 . Q7^pp<,?f , 2.172963C1A, -5 . 76607 *5 92

)

1 FHO^TllPO 9 X + T EXCEEDS TC IN OFNGASF. * / ) ? IP(TCPT-T) ?, A, 5

3 p c

m T 1

* STOP

A DFNPASF * DCRT « ZPy * 1 % DDSPT * 1.0F+1D0 t P F TUP N

5 7 N ZCPT-l y D C P C P T « P Pfatf(T)

6 PI * °/PC * D IT » ^PCPT/pc $ TC 1 T C

p T 7 y * T/TC T X 2

= y*y % u « l-y 5 UF = U**EC- $ UE1 - -FG«"JE/'J

A U A * u * * A C f t'Al * -AG*'JA/M

9 V * X- I « V2«V*V « VP«V*V’ T XP«EXP(RG*V3/X)

ID X P 1 - ( 3 * V 2 / * - V3/X2)*XP*PG

u y = a v ( i

)

u e + Avm+UA j yi = Avm*uFi + a v ( 2 ) *

a 1 1Z O

n H x.B.'JtS « L

* ^ - 2 1 UL = U**L

13 Y - Y + A V ( K ) * ! J L * Yl Yl - AV(*)*L*UL/U

1 a continue t Z f y * p = 1 + y * y p * f 1 « y * x

0

1 v 1 * x p 15 ZCALC = 7

S A T = 7 = 1 ZN*PJ* c /x?

16 PZSDT * OZDT « ( p I * (

1 -? * F / > ) / TC + C *PIT) + ZN/X2

17 D E N G A s F « P/T/7/GKK

18 PPSDT - ( P p S D T - p/T - PAP7PT/7) /T/Z/GKK $ RETURN

FNp

FUNCTION PEk'lioF(T)

C H 2 S SATLIOOFn, * n l / L , 3/21/83.

C D/PC - 1 « A 1 * UE A ? U » *'J « (1 - T/TC).

C nMM 0N/3 / CPrT,P?PPT2,D°SDT,DP M DT,DPDD.DPDR,DTSDP>DTHPP. DDSPT

DIMENSION A U (A

)

DATA (NFL-A),(EI*D.35),(DCFT»1C.2C)»(TCPT«373.A0)

P A T A ( A W = 1 .906?95 7 7, 0.83560539. -C . 6 70 9 1 A A7 , 0 . 7 2 3 A 76 c 3

)

1 FDP M AT(1HC 9 X *PPNLIDF = 0, T EXCEEDS TCPT. * / ) 2 IF (TCP T — T) ? , A , c

3 PRINT 1 T STOP

<i DF N L I OF » DC R T % DDSPT = -1.0E+10 I PFTLIPN

5 D-l-T/TCPT 5 U 1 T * - 1 / f C p T 1 UE»U**EL T UE T * E L * UE / U* U1

6 Y . A 'J ( 1 ) * U F * Y 1 T > A W ( 1 ) * 'J F T

7 DO 9 K ® 2

k

' c L « L « K-l « UL l'* + L

8 Y * Y AW(K)*UL t Y 1 T = Y1T + AW(*)*L*UL/U+U1T

9 CONTINUE T DENLIDF - DCRT*( 1 +Y)

10

DDSDT DCPT+Y1T « RETURN

END

28
0.0

o

o

o

Appendix F. Continued

FUNCTION EPF LF ( L , M, T, DA , DB ) C GET C MANGE OF E, S, CV WITH DENSITY ALONG ISOTHFRMS.

GET E DE L

c » PELS, DELCV from DA TP DP ON ISOTHEPM T. POMBFPG NUMERICAL INTEGRATION VIA -

C APNAHAN/LUTHER /HL^E S, APPLIED NU M F p IOAL METHODS, P. 90,

JOHN WILEY AND SON'S, INC., N.Y., 1969.

NOTP. NMAV . % NK . FINAL, TOTAL SUBDIVISIONS OF INTERVAL D *

,

CPM*inN/l/AL,BE,CA,PE>E D ,ET, nCPT,TC 0 T,PCPT, DGAT,DTRP,TTRP,PTRP

C0 M M0N/3/DPDT,D?PD T ’,0 o SDT,DPNDT,DPnD,DPDR,DTSDP,DTHDR,DDSDT

COMMON/11/ DELS, DELCV

C0 u M0N/l?/ZCPT,ZCALC,n7DT, ZSAT,D7SDT. ZFX, RRT,DRRTDT

DIMENSION F ( 2 C ) > S ( 2 0 ) , C C 2 0 ) DATA ( L D *= 1 ) , (01 = 0.00 001 ), < GO. 0 831A5)

1

pn?MA T (lM09Y*EDFLR L -*I2,5H, N «I3»5H, T « F8.3,6H, DA -E1C.A,

1 6 H , DE * E 1 0 . A , 6H, LD -12//

2 1DX 1WN 7X5HEPELR 8 X A HOE L S 7X5HDFLCV ) ? F 0 R M A T ( l H 0 9 X 6MEDIF * FI 0 . 3 , 8H, SDIR -FID. 5, 9H, CVDIF -F10.3)

3

FORMAT ( 6 X 15. F 1 2 . 3 , F 1 2 .

“5 , F12.3)

A format ( I

*-• 0 9 x *EOELF NG AT TC R T FOP CV AT DEN NEAP OR GT C.P.*/)

C FOP D A = 0 AND DP.LF.DI, TDEAL GAS, E D E L F - D E L

S - DE L C V = 0

C FOR DA=0 AND DE.CT.OI, START R PM 8 E P G WITH DA = DI,

C TO AVOID INFINITIES IN ORDINATE FUNCTIONS AT DA - 0.

5 N< i 1 t cm - DC PT / 2 < DZ - C.9°*DCRT

9 7K = 1.0 - 1/ZCPT « RK - 100*S* T C=T/DCPT

10 I F C L . F 0 . 0 ) 11, 1A

11 IP(D«.LE.DI) 12,13

12 EDELF OFLS * DELCV * 0 ? RETURN

13 DA = DI

C GET FIRST TRAPFZOIP AREA, c ( 1 ) ETC., FROM DA TO DE.

14 DX » DR"- DA « R - PVT P (T,DA,0) l IF(DA.LT.DM) 16,17

Ei , PKMZk*ZSAT*7FX + FRT - T+DFRTDT) < GO TP 18

1 7 EA = i C o*(P-T*DPQT)/DA/OA

18 IF(L.Eo.r) 19, ?C

19 SA - -pk*DFPTDT $ GO To 21 20 SA « -100*DPDT/DA/DA

’1 CA - -10C*T7D2ddT?/DA/DA

2? P = PVTF(T,D3,D) t IF(D8.LT.DM) 2

b , 2 A 53 £3 x R k + ( 7K * Z

c A T* 7 F X + FRT - T*D FR TOT ) J GO To 25

2A F3 100* ( o-T*D p DT ) /D8/D3

25 IF(L.EC.C) 26,27

26 s

a - -pk*dfptdt % GO TO 28

2? SB - -1CC*D ROT /D8 /03

?3 ra, « -] oo*T*D2PO T P /DB/DR

29 E(l)=(EA + FP)*DX/2 $ Fm = (SA+SP)*DX/2 » C(l)-(CA + C8)*rx/2

C INTERVAL HALVING, GET E(N+1), ETC.

3D DO 60 N . I , m % * « N + 1 31 JM * 2 **N - 1 t OXN - DX

/

2 * * N $ E(K) » S ( K > - C(K) • C 33 DO A5 J=1,JM,2 $ NK = NK+1 $ DN - DA J*DXN

34 p X RVTF(T,DN,0) % IF(ON.LT.DM) 35,36

3c £ a x RK*

(

ZP*7SAT*Z C X + FRT - T + DFRTDT) % GO TO 37

-36 E8 - 100*( P-T + DPOT ) 7DN/DN

37 IF(L.FO.O) 38,39

33 53 , _pk*DFPTDT 1 GO TO AO

39 S3 -130*DPDT/DN/QN

AD C 3

- -100*T*D2 p PT2/DN/DN

4 1 E(P) = F ( K ) f B l SCO S(K) SB % COO * C(K) + CP

A5 CONTINUE 1 E ( < ) = F ( N ) / 2 E ( O * n *N

29
Appendix F. Continued

46 S(K) x S ( N ) / ? * S ( K ) Q X N $ C < K ) = C ( N ) / 2 + C ( K ) 0 X N

r

C TEST FOR CON VF p GE NC E

50 E n x a 3 S ( E (k )-E (N )

}

5 SD-ARS ( S

( * )-S (N )

)

% CD= APS (C ( K )-C ( N )

)

53 IF (PP.LT.0.2) 54, 60

54 IF ( SD.LT.C .002 ) 5 5,60

55 IF (T.EO. TCPT. AND. PP.GT.QZ) C-0 TO 5 7 54 IF(CD.LT.0.04) 5T , 60

57 F D p L F = F ( K"

) $ DELS = S ( K ) S DELCV * C (K ) $ RETURN

60 CONTINUE $ N * M 1 N 3 x N-l t NP X N + l 61 PRINT 1, L, N, T, DA, D8, LD

62 PRINT 3, N m , F (

y

)

, S ( NM ) , C ( NR ) $ PRINT 3 , N , E (N) , S (N ) ,C (N ) 64 PRINT 3, NP,E(NP) »S(NP),C<NP) I PRINT 2, ED, SO, CD

33 STOP

END

FUNCTION F INDEN'F ( T» 3 ) C 0 N TSOThpRR T, PINT DEN, MOl/L, TC “TNI^IZE ( P -P C ) VIA CONSTATE.

rpMMO N /i/4(_,RF,r-,4,nc,FP,ET, DCR T, TCR T, RCR T , DGAT,DTRP,TTRP»PTRP

CDM*nNn/CiPDT,D2<> DT2tDPSDT.nPMDT,DPt'G,DPDPfDTSDP»DTHDP#DDSDT

DATA (GKK = 0.693145)

41 FDRMATdCiO <3 x *FINOFNF * 0, PAILS TD CONVERGE. * / ) 62 FOP“AT(].MO 9* FIN'IEMF . nCPT, DP/DP ZERO OR NEG. * / ) 6 3 Cfi»«AT(lwo cx +CINOFNF . 3, OOU n LF-VALUFO AT 0 * PSAT. * / ) 0^ = 1.1C+DTRP I IF(P.OT.O) 1,3 s

1 I c ( T-TCPT) 2.5,8

’ PS PSATF(T) 1 IP(P-PS) 3. 32.

3 OG * OFMTASF(T) % D = DG / 2 } GO TO 11

4 DL » OENLIOF(T) t 0 = (DL+DTPP)/2 T» GO TO 11

5 I p ( p- 3 C

p T) 6.33.7

6D-DCPT/2 T GO TO 11

7 D = 2»DCPT % GO TO 1

3 PC = PVTF(T.DCPT.O) % I F ( P- D C ) 6,33,7

11 00 30 J*1 , 50 « dp=°-°V t F (T.0,1 ) i I p ( A 3 S ( DP

/

0 ) -1 . OE-7 ) 31,31,12

12 I F ( DPOD.GT. C) 13,34

13 p>D * OP/DPOP ? I p ( A o $ (DD/0)-l .OF-7) 31,31,14

14 0 = 0 + 00 $ IF(O.GT.O.C) 16,15

16 0 » P/GKP/T ? GO TO 30

14 IF(C.GT.OM) 17,18

17 0 • OM 1 GO TO 30

13 IF(T-TCPT) 13,24,30

13 IF(o.LT.PS) 20,22

20 IF(D.GT.OG) 21.30

21 P - DG % GO TO 30

22 IF(D.LT.DL) 23,30

23 0 * OL 1 GO TO 30

24 IF(P.LT.PCPT) 25,27

25 IF(D.LT.nCPT) 30,26

?6 D * DC p T - C.02 $ GO TO 30

27 IF(D.GT.DCRT) 30,23

23 D « DC p T + C.02

30 CONTTNUE i PRINT 41 % STOP

31 FINDENF = D $ R p TUR N 3? PRINT 63 T STOP

33 PINOENF • DC P T % RETURN

34 c I N n F N F x DCRT I ppINT 42 6 PETUPN

35 FINnFNP = DPDT = D2P r'T2 = 0 % DPDD=GKK*T 1 D PD R » D P DD * DTR P 36 RETURN

END

30
Appendix F. Continued

FUNCTION FINDTfF(P)

C GIVEN o rjK thc mating LINE, fjnD T FOR p p n p AN E

C0mmon/1/AL,BF,GA,DE»E d ,ET, DCRT,TCRT,PCRT, DGAT,DTRP,TTPp,pTRP

DATA ( E*1 .203 ) . (A-7180.C)

1 X » <P-PTPP)/A + 1 t F I N D T M F . TTPP*X** ( 1 . 0 /E ) * RETURN

END

FUNCTION FINDTS c ( 0 > C GIVEN VAonc PRESSURE ITERATE T TO MINIMIZE (P-PC).

Common /I /AL>9E»G A ,DE»E 0

» ET» OCPT,TCRT,pCRT, DGAT,DTRP,TTPp,ptrp

COMMON/ 0/DPrT,n2POT?,DPSDT,DPNDT,DPDD,DPDP,DTSOR,DTHDR»DDSDT

1 fp^m AT( 1h3 Qy *FINDTSF * 0, FAILS T 0 CONVERGE. * / ) 7 FOR m AT(1mo 9x *FINO t S

c « 0, a EXCEEDS PCRT. * / ) 3 IHP-PCRT) A, 11,1?

A T = (TTPP+TCRT ) /?

D

n 9 J=l.SO ? D = * P - PSATF(T) 1 ADP * ABS(OP)

0 IF ( ADP/P-1. CE-7) 10,5,0

a IF ( ADP/QPSOT/T-1 .QF-7 ) 10,7,7

7 T = T PP/DPSDT % I F ( T-TCRT ) 9,9,0

3 T > TC R T

9 CONTINUE t PRINT 1 i STOP

10 fjnDTSF = T $ RETURN

11 F I N G j S F = TORT t R c TURN

1? PRINT ? $ STOP

END

SUBROUTINE GFNEO'JS

C given p,T fop the ho m OGENE'TUS domain -

C GET D F N AND FUNCTIONS AT ANY TF MD F®ATURF,

CnMM 3 M/3/r;ppj,02PDT?,D D SDT,DRMDT,0PDD, n PDP,DTSDP,DTHDR,DDSDT

COM-ON /« / IN, I®, P,T,DEN, E,H,S, CV,C S ,CSAT, w,WK

CO M M ON /ll/ dels, delcv

C0MMON/9G/ TI , E Z 7

, C7 ,SZ,CVZ, H Z , C P 7 DATA (O*1.C1325)«(G«D.O031A‘>)

3 TI . T T CALL IDEAL S IF(P.GT.C) A, 10

A D F n = D3 * FINDENP(T,P) i M x 15 T DA = L * 0

5 E * E Z 7 + EZ + EOELF(L» M »T»DA,DR) 1 H * F IC0*P/D9

5 S SZ + DELS - 100*G*ALOG<G*T*DB/0)

7 C V * CVZ DFLCV % P X * PVTF(T,DB,1)

n CP • CV 1 00*T /DPDO* ( DPDT/D3 ) **2

9 U SORT! VP*CP*D 0 DD/CV) 1 RETURN

10 D E N S * 0 « E E77 EZ « H - E + 100*G + T 1 CV-CVZ t CP-C*

17 W * SO p T(WK*CP*G*T/CV) * RETURN

END

31
Appendix F. Continued

SUBROUTINE GFNIUS

C VALID INLY FOR THE HQMQGE NE OUS DO M A IN.

C S A V E

F C 0 Mp UT E e TIm E wmfnj TABULATING FUNCTIONS ALONG ISOBARS.

C S A V F S OEN,E,S,CV ALONG ISOBARS FOB USE IN INTEGRATING TO NEXT

C HIGHER ISOBAR. VALID ONLY FDR «ON ETON IC A L L Y INCREASING ISOBAR

C PRESSURES, AND AT TEMPS. T * TNTEGFP MULTIPLES OF 10 K. COM', ON/?/DPDT,D2PDT2,DPSPT,DPMDT,DPDD,QPDP,DTSDP , DTHDP , DDSDT

CO m mon/P/ IN, IK, R.T.DEN, E > H , S , CV.C°,CSAT, W,WK

COMMON/11/ DEIS, DEICV

DIMENSION 0K( 100) , EK( 100), SK ( 100 ) ,CK( ICO)

1 F np w 4 T ( 1 (-0 9X * G E N T U S T NOT INTEGRAL. * / ) 2 J T/10 ? IF ( T - 10* J ) 3,4

3 CALL GENEOUS % RETURN

4 IF (IK. CO. IN) 5,9

5 CALL OENEDUS

5 DK(J) - DEN % E K ( J ) - E ? S *< f J ) « $ % CK(J)«CV T RETURN

C TNTEGBATF FROM OLD OF N IJP TD new DEN on GIVFN ISOTHERM.

9 DA * DK(J) % DK(J) => DEN = 03 = FINDENF(T,P) 1 N * 14

11 EK(J> * E * EK(J) + EDELF(1,N,T,DA,DB) i “ = E + 1D0+R/DB

13 FK(J) = S - S k ( J ) + DELS t C K ( J ) - CV - CK C J ) DE L C V

C NOW GET NEW DP/DT. 0° / DU, C p , W.

15 PX = PVTF(T,DB,1) % CP = CV 4 1C0*T /D D DD* (

3 DT / D B

) * * 2 3D W SOPT( WK*CP*DPDD/C V) % RETURN

END

CCC

FUNCTION h s A T c ( T

)

HYDROGEN S U L P I D F SATLIO FNTHAL°Y, J/ m H|.., RDG/N3S, 4/15/B3.

DEFINE YH # f H-HC ) / (HT-HC ) , X * ( TC-T ) / ( TC-TT ) , WHEN - YH « X (XE-X)*(AI + A ? * X H P A 3 * X A4*X? *•.,),

DIMENSION A H ( 7

)

1

12

34

56

7

99

DATA ( NCH.7) , ( F H=D . 35 ) , ( H£rO. 70)

DATA ( TTPP»l 87 .4,5 ) , ( TCRT = 373. 4C ) DATA (HTPP = G.7ST), (HCPT=1707B,R*<i)

D A T A ( A u * 0.456446719, 0.D171915C2, 0.207055352 , -1.904453730, 3.744014417, - ? . 7 R B 59 c 4 5 4 , 0.499929755)

FORMAT (1H0 9 X 3 HT »F 10 • 5 » + IN HSAT C (T) .*/)

IF(T.GT.TCRT) 3,4

PRINT 1, T % STOP

X (TCRT-T)/(TCRT-TTRP) % IF(X.LE.O) 5,6

HSATF * HC R T t RETURN

V = X*«ch - X S XH = X * * HF

F < « X V * ( A H ( 1 ) + A H ( 2 ' * X H ) $ p,D R K * 3 , N F H FX - PX + V*AH(K)*X**(K-P)

HSATF = HC R T - (HCPT-HTR P )*F* * RETURN

END

32
Appendix F. Continued

StmTJTIMF ideal

C H?s VIA 3 A E H R ET Al> 1968.

C°Z/9 * 4.0 + ( A 1 + x 4 A 7 4 A 3 / X 4 A 4 / X 7 4 . . )*FXP(-E/X), XXT/100.

Com«on/ 9Q/ T I , E 7 ? * EZ,SZ»CV7* HZ,CP7

DI‘*ENSI r'^ A (6)

DATA <NK - 6) ,(E - 10.37)

DATA (Fx8,3]45),(SI*76.146)»(HT»4.0168)

D A T A ( A = -0.19525562. 11.0377525, -74.8072768,

1

330.650148,

-655.671639, 475.053933)

1 XI TI/10C 5 xo . EXP(-E/XI )

3

C p * 4.0 $ DO 3 <«1,MK

3 CP * CP + A ( K ) *XP*XI + ( 2-K ) C numerical INTFRP ATI ON FDR mz/R, S7/R - 5H.S-D J N » A8S(TI-3C0) /4 4 1 % DX . { X

I -3 ) /

6 DO 10 J*1»N f X « 3.0 4 ( J -0 . 5 ) * D X $ XP * E X P ( -E / X ) 7 CPX >4.0 J DO » x=l, NK

3 CPX » C°x 4 A (K )*X 3 * X** ( 2-K ) 9 H H 4 C Py*n> * S S 4 CPX*DX/v

ID CONT

VUE « (HI*3 4 H ) / X I $ S = SI 4 S $ PT - P*TI

C CONVERT TC JOULES, MILES, KELVINS.

11 MZ * RT*h i P7 « u 7 - RT 1 S 7 * ?*S

17 C D 7 P * C ® 1 CVZ C D Z - P ? RETURN

E N n

SUBROUTINE ISOTHRm

c PRINT H 2 S CRITICAL IS3T~IER«.

C USE D » M P A , AND DEN REDUCED RY DC»T, NOT DTPP.

COM M ON/1 / A L »PE,GA,DE,EP*ET , DCPT,TCRT,PCRT, DGAT ,DTP°,TTRP,pTR®

CON‘'0N/3/DPDT,D3PDT3,DPSDT,DPMDT,DP0D,DPDR,nTSDP,DTHDR,DDSDT

Cn^IM /4 /X°l . X32 , XC 1 > XC 2 » XE1.XE2, D X3DR , DXC D® , D * EDR COM“ON/6/ TSAT, THETA, PSAT

1 FORMAT ( 1H1 1 4 X HYDROGEN SUL P IDF CRITICAL ISOTHERM //

1 1 5 x 4H TC * F 8 . 3 , * K * AH, DC « E 6 . 2 , * mql/L, ®C = * F 9 . 6 , M P A > / 2 1 5 X + A T Tmc C.R., DPS/DT -*F0.6, *, DP/DT F9.6»* “PA/K.4 //

3 6*4H r'/ r'r 8X5HTS/TC 7X6HDTS/DD 8X5HPS/®C 7X6 HD d S/DD

4 9X4HP/PC «X 5 HDp/oo qx5HDP/DT fX7HD?°/DT2 / 5 Z9X7mr-l/mdl 17VQHMPA-L /HPL 17X9H“PA-L /MOL 8X5hmpa/K 6X7hmp A /K/K)

p p OP ma T( 3 v F 6 . 3 , 7F13.9, F13.5)

3 PC P VT C ( TCPT,DCRT,0) t PCS « RCPT/10

4 U p B S DT « DPSDT/10 t D° X DT « D p r T / 1 0

5 PRINT 1, TCRT,DCRT. PCS, DPSSDT,DPxDT t DR D S - DCRT/DTRP

4 DO 12 J * 1 , 4 1 % DR* 0 . 8 9

c 4 0 . 00 5 J 1 DN D R * DC R T 7 PR P VTF ( TCRT , DN, 1 ) / OCR T * D p S D R DPSDT+DTSDR

8 TSN * TSAT/TCPT * ®SN * PSAT/PCRT

q DPOD = D

p DR*DPD <: / 1 0 t OTSDD = DTSCR *DR DS J D ® S DD - D® S OR DR D S / 1

10 D p D T « 0 ®9 T /I 0 T D2PDT2 * D2®DT2/10

I F ( j.EQ.21 ) D2 ®DT ? * 0 IP PRINT 2, DR, TSN,DTSDD, PSN,D®SDD, PR, DPDD, 0°DT,D2PDT2

30 RETURN

END

33
Appendix F. Continued

RU9P0UTINE JTLOCUS

C the J DUL E-THniS r'Ki INVERSION LOCUS FOR HYDROGEN SULFIDE.

C P F

p I V R THR J-T INVERSION CURVE. USE ROUTINE P F L T 4 F ( T , D I ) . CTM*r)M/l/AL,RE»GA»DF,E D »ET, DC p T.TC p T,PCRT, PGAT,DTRP,TTRP,PTRP

DIMENSION DM''0),DN(60>»TT(ft0),PP(60>

TATA (A=l.?275),(P=O.Ae5),(w“=3A.09)

1

FTP" AT ( 1 mi ifcx* jmjL F-THH- SIN INVEPSI n N LOCUS FOR HYDROGEN SULFIDE*/

1 1 7 X *(0I IS INITIAL DENSITY RPR ITERATION) * II

2 1 7 X 3 U T , K E X 2 n C I 5Y5HNOL/L 5X5hP,H°a

3 7 x 3 MT,v bx’hoi SX5HOOL/L 6X5HP,M D A ) ? pprmAT( 10X 110. 2 F 1 o , 3 . F 1 0 . 3 » 110. 2F10.3, F10.3)

3 FO p NAT( inn fcX*J0UL c -THOYS0N INVERSION LOCUS FOR H Y DR OG F n SULFIDE*

? // 17 x ahT.R 5X5HHPL/L 5X50®, “RA 7 X 3 H T , K 5x5HRpL/L 5X5HP,NPA ) A FORMATdC'X 110, 2 F 1 0 . 3 , TIG, 2 E 1 0 . 3 ) c save initial, trial density, dr ( i j - di.

5 n P 5 6 9 T A 2 7 0 % PRINT 1 6 00 2 *5 1=1, NP 9 DX = D.6A 9 T r TA + 10*1

7 X * T/TCPT 9 DR ( I ) =01= DCRT*EXP( A-B*X ) ID IF (T-TC p T) 11 ,1 2,12

11 DL = PEMTOP(T) 9 IF(DI.LT.OL) 23,12

1’ SS = n E L T A R ( T » n I ) $ DO 20 I T = 1 , 16

1A Dr^l-DX 9 SL =DEL TA= ( T , 0 ) 9 0=DI+DX 9 S P « 0 E L T AF ( T , 0

)

1 5 IP

(

SS-SL

)

19,16,16

16 IF ( S p-SL

)

10,17,17

17 SS = SL 9 DI =oi - 0 x 9 GO TO 20

19 IF ( SS-SD ) 20,20,16

19 SS = S° 9 01 - 01 + D» 2D Dx » OX 12 9 TT ( I ) = T 9 DN ( I ) = 01 9 Po (I) = PVTF(T,DI ,0)

’1 GO TO 25

} 1 TT( I) x T 9 DR ( I ) = om ( y ) « PP( I ) = 0 25 CONTINUE 9 N « NP/2

25 00 35 J=1,N 9 R * J N 27 IT r TT ( J ) 9 ITT = TT(K)

29 DR J = 0 R ( J ) 9 DNJ = 0 n

(

j ) 27 PR ^ » DR(R) 9 DNK = D N ( R ) 3D PPJ P P ( J ) /ID 9 °0R * P p ( R ) / 1 C 35 PRINT 2, IT, OKJ.DNJ, PPJ, ITT,CRK,PNR, ppr

',0 point 3 9 DO A 5 J»1,N .9 R « J N A1 IT « T T ( J ) 9 ITT * T T ( K ) 9 DNJ - DN(J) 9 PPJ • P D ( J ) / 1

A 2 DNR « DN(R) 9 PPR = 0 P ( R ) / 1 c- A5 PRINT A, IT, DNJ, PPJ, IT?, DNR, PPR 50 PFTIJPN END

34
Appendix F. Continued

SUBROUTINE KAY

C COMPARE H2S SATN. DATA Of K A Y/R AMBOSEK, 1953.

DATA (VN*3A,0B),(AL8*A53.592A)»(CUF*28.31665)

1 FORMAT ( Af 1 0 . 0

)

2 FOPHATdHl 13X *HYDRCGEN SULFIDE COEXISTENCE*

1 * DATA OF KAY/PAMBOSEK, VS. ROG (CALC) //

2 1 A X 1HT 7X13HPRESSURE, MPA 9X13HL IQDEN, NOL/L 9X1 3HG AS DEn, NOL/L/

3 1 A X 1HK 3(AXAHDATA AXAHCALC 2XANPCNT ) ) 3 FORMAT (5X F 10. 3# 2F8.A,Ffc.2, 2F8.3»F6.2, 2F8.A,F6.2)

5 PK « 1.01325/1A.696 $ DK - ALB/CUF/WN

10 PRINT 2 $ DO 30 J«l,99

11 READ 1# TF, PS I # D L 8, DG B \ IF(TF) 12,99

12 T • (TF A59.67)/i.e S PX - PK*PSI $ DLX - DK*DLB

13 PC - PSATF(T) $ PPCT * 1 00* ( P X- PC ) / PC 1A DLC » DENLIOF(T) $ DLPCT » 100* ( DLX-DLC ) /DLC

16 IF(DGB.EO.O) 17*18

17 DGX DGC • DGPCT - C J GO TO 20

18 DGX - DK*DGB $ DGC - DENGASF(T) $ DGPCT « 1 00* ( D GX-DGC ) / DGC

20 PX - PX/10 S PC * PC/10

30 PRINT 3* T, PX. PC, PPCT, DLX , DLC , DL PCT, DGX , DGC, DGPCT

99 RETURN S END

35
Appendix F. Continued

SUBROUTINE P C E«

C E * & M T N F PFHAVIPP O'1 Tme EOS COEFFICIENTS.

C B(S) # B1 + P?*S + B 3 * S 2 » C(S) « Cl C 2 * S + C3 + S2*

C F(S) » E1*(S-1)*(S-ER)*EXP(-GA*S**IX).

C WH E P F » D » PFN/DT3P, S n DEN/DCPT.

COmmpn T X, FP , GK ,G<* , 41,42,43, Bl, 82,83 , C1,C2,C3, E1,F2,E3

CDMM0N/1/AL»3E,GA,DE»EP,ET, DC P T , TC PT , PC P T , D G A T , D T P P , T T P P , P TP 3 CO M ^ON/3/DPDT,r>2PDT2»D p SDT»DP^DT,DPPO»DPDP,DTSDR»DTHDP»DD$QT

COMMOn/6/ TSAT, TMFTA, P S 4 T 4 FnPMATdHl 14X * E ON S T ATE CnE p FS., HYnpoGEN SULFIDE * //

1 15X6HTTPP E 1 3 • 8 » R4, TPLP -E13.6, «H, TCPT -E13.6, * K,* / ? 1SY6MPTPP = E 1 3 . 6 , bei, 0 p L P * E 1 3 • 6 , R4, PC p T -E13.6, * MPA,* / 3 lBX4-wnr,AT * FI 3 ,6 » pm. DGRP -E13.*, 84, DCPT -F13.6,* MOL/1,* / 4 15X6HDTPP -E13.6, 8H, DLPP -F13.6, 84, DCPT -E13.6,* M 0 L / L » * / 5 15XQMDPS/DTP * El 2 . 5 , * mpa/k, OVAPP, KJ/«DL -* F8.4//

4 IPX 4 m I X =12, 6M, fr -F6.3 / 5 1 5 X 4 M A L F 1 0 . 7 , 64, RE -F10.7, OH, GA -F10.7/

6 15X 4 4 D E -FID. 7, *>H, E= -Fin. 7, few, ET -F10.7 //

7 1 5 X 4 m 3-F14.il, 84, R 2 -Fl4.il, 64, R3 -Fl4.il/

8 1 8 X 4MC1 -F14.il, 84, C 2 -F14.il, 64, C3 -F14.1]/ ) 5 FORmaT( 15Y 44D/DC 5 *5 H'' r

'L /L 6X44TSAT 5X5HTHFTA 6X44P$AT

1 QX1HR 9 Y ] 4 C ) 6 FORMAT (9Y F10.2, FID. 4, 2F10.P, FIG. 4, 2 F 1

. 5

)

7 TR = F INnTSF ( 1 . 01325 ) I D GP - D F N G A S F

(

TB ) % DLB -DENLIQF(TB)

p OP - T n *n°SDT*(l/DGP - 1/DLR)/1C.0

7 PTP - PTRP/10 7 P3L«0.ini325 } por.pcpT/10 8 D°SDT -DPSDT /ID

10 PRINT 4. TTFP,TR,T:PT,PTP,PeL,PCP,PG4T,DGR,DCRT,

1 OTPP,DLP, DCPT, DPSDT, OR, IX, FP, A L , 3 F , G 4 , DE ,

3 , E T

,

2 C1.C2.C3, F1,E3,EB

11 PRINT 8 * N = 10*DTP°/nC»T 1 1’ DO 20 J = 1 , N i S = 0.1*

13 on * S *DC p T % S 2 - S * P * SN-S-1 $ SX - S * * I X 14SP-1 * I F ( E p . G T . 0) SP-S-ER

15 8 » 31 + p 2 * S

B 3 * S 2 1 C - Cl C2*S C3*S2

1 7 E = E1*SN*SP*F*P(-GA*SX)

17 TS4T-TS-TSATF(0N) <, Th-T4FT4F(DN) t p S S A T F ( T S ) / 1

20 PPTNT 6, S , P N , TS,T4,0S, C»E 7 PETUPN

END

FUNCTION p M E L T F ( T

)

C RROPANF MFLTING LINE. PAP, VIA PEFVES, SCOTT, AND BABP(JP),

r j. CHFM . 0 4 Y S , 40 ( 12), 366? (1964).

COMMON /I

/

AL , PE ,G A , DE .

P, E T, OC

T

,

TC PT , P

R T , DG A T

,

DTR P , TTR, P TP p C0MMON/3/DPCT,D2PDT2»DPSnT,PPMDT,DPDD,DPDR,DTSDR,DTHDP,DDS0T

DATA (A = 71 PC.O) , ( F « 1 .263

)

1 X - T/TTPP * XF X**E 7 OMELTF - PTPP 4 A*(XE-1)

? D p M D T » A*F*XE/X/TTRP I RETURN

END

36
Appendix F. Continued

SUBROUTINE PVTDATA

^2$ EOS CONSTANTS, RDG/NPS » APRIL 15, 19 03 . I^>tP,GK»GKt<» A 1 , A 2 , A 3 » 8 1 , B 2 , 3 3 » C1»C2»C3» E 1 » E 2 # E 3 CnM«rjv/l/AL»3E»GA»OE»EP»FT» DCRT>TCRT, 0 CRT> DGAT»DTR p >TTRP>PTRP

C'l^^DN /P/IN, IK, P»T»DFN» E»M,S, CV.CP.CSAT, W,WK COmmom/ip

/

7rPT,ZCALC»07DT, 7 S AT , DZ S C T » Z F X , FR T» OF RTDT

CORMON/RQ/ TI,E77, F7,SZ,CV7, H Z » C P 7 ID W* = 34. CPC $ TTRP = 107.86 S TC R T = 373.40

12 DC R T = 10.20 7 0

T RP * D F N L I Q F ( TTRP)

13 PTRP * °SATF(TTP°) 1 P C

p T » PSATF(TCRT)

17 GKK * O.C833 % G R GKK*DCRT

2D 7C R T = PCPT/DCRT/P^R /TCRT $ DGAT * 0 F MG A SF ( T TR P ) * al=1.D % PE * 0.75 $ GA 1.0/IX

22 DE E° « 0 * ER - 2.0 « ET « 1.10

’3 A1*A?=A3*C ? Fl*82*33*0 $ C1*C2*C3*0 % F1 = E2*E3«0

28 Cl = 0,3P a 2

c F7o^73 % C3 = 0 . 1327018703 9 1 FI * -0.31070871113

27 VK * 100000 /** $ E Z 7 * 13400.138

30 RETURN

FNO

FUNCTION PVTP(T,D. u

> C HVPR-'GEN SULFIDE EONSTATE, PVTF . P,PAR.

NOTE. RETURNS D*/DT, D2P/DT2. M = l RETURNS A l S DP/OD.

e-RSAT = S*GK*( T-T5AT) S * S* OK *T C R T*F ( S , T ) , WHERE -

C P ( S > T ) # P(S)*7PF(S»T) C(S)*XCF(S*T) E ( S)*XF F ( S,T)

,

C P(S) * PI + p?*S + 3 3 * S 2 » C(S) * Cl C 2 * S C3*S2>

C E ( S ) *

c l*( S-l )* (S-FR )4FyP(-PA*s+*iy)

C pc, ? # ofn/dtro, S # den/dcrt.

CQRRON Iv,ER,GK,GKK, a 1 , a 2 » A 3 » *1,82, *3, C1,C2»C3, E1,E2»E3

Cn*MnN/l/AL,P F,GA,OE»EP*ET* DCRT,TCRT,PCRT> DGAT,DTRP,TTPP,pTRp

CDMMDN/3/DPDT.D2PDT7,DPSDT>DP^DT,DPDD,DPDP»DTSDR,DTHDR,DDSDT

common /A /XP1 , XP2 , XC 1 > XC 2 » x c 1 » x E 2 * D xp DR , D xC DR , D X EDR COM*0N/E>/ TSAT, THETA, PSAT

COmmon/ 17/7CRT,ZCALC,OZ^T, 7SAT»07S r'T*ZFX» FRT,PFPTDT

1 S = D / DC R T %

c 2 = S*S % SN = S - 1 $ SN1 - 1 3 = s - E p ? S? 1 = 1 t S X S * * I X

5 G< « DCRT+GKK « TC - TC»T 1 DSDR » DT p P/DCRT

6 RG « S *0K $ GKT - GK * T r 7 TS4T=TS = t SATE(D) T PS A T= PS= °S ATF ( TS ) $ THETA«THETAP( D)

3 xC * x C P ( T , D ) ? y E * x E p ( T , D ) i C * (Cl + C3*S2)*S2

10 XP * EXP(-GA*SX) T S E * E 1 * S 2 11 S* « SE + SN*SR % F - S M * X P 12 F * C*XC + F * x F $ PI - C * XC 1 + F * XF 1 % F2 C*xC2 E*XE2

13 PVTF . PS + RGMT-TS) + GKT*F t FPT-P/S2 t 0 F R T DT • F 1 / S 2 / TC 13 DPDT = RG GK + F1 % D2 D DT 2 • GK+F2/TC S I F ( M ) 15,30

15 X R 1

* -IX*CA*SX/S i SF1 = 2 * F 1 + S 17 3“l . SF*SN*SR1 + SE*SN1*SR SF1*SN*SR

IP ED ( S M * X P 1 + S M. 1 )*XP*DSDP

IQ CD ( 2 *C 1 A*C3*S2 )*S*DSDP

20 FI = C*D XCDP CD* XC + F *D X F DR + FO*X E 2-3 DODR * (DPSDT-RG)*OTSDR ( T-T S ) +GK *D SDR + GK T* F 1 27 DPOD DPDR/DTPP

30 RETURN

END

37
Appendix F Continued

F UNC T I ON PSATF(T)

C H2S VAPOB PRESSURE, RAP, 3/21/83.

C L N ( P ) - P!/y + P2 + P 3 + X + P8*x? + P 5* X 3 + P6 M 1- X ) **E P P . Cn^ M nM/3/DPnT,n?P0T2»D D SnT,noMnT,0PnD,DPDP,DTSDP,DTHDP»DDS0T

ni-FNSIHN P J ( 6

)

DATA ( EPP*1 .70) , (TCPT- 373 . AO)

D A T A ( P J « -8 .023473 844 , 18.731082287, -10 .325650140,

1 9.890908499, - 3 .

T 7 1 6 ?0 8 1 , 3.178310817)

1 FOP84T(luo QX *T A ROVE TCPT IN P S A T F ( T ) . * / ) 8 X « T/TCPT $ V « 1.0 - X % IF (V) 7,0,9

7 0 P T N T 1 f STOP

R 7 = 71 = 0 % GO TD 10

9 Z V* * E

0 P f 71= -E°P*Z/V

10

D L - PJ f 6)*7 % P L 1

* P J ( 6 ) + 7

U 00 1 3 8x1.8 s L * <-2 t XL - X **L

1? p L = PL * P J ( K ) * X L « P L 1 * 0 L 1 + PJ ( 8 ) *1 *XL / X 13 CONTINUE 1 0 S A T F x FXP(DL)

15 DPSOT « PL1*PSATF/TCPT % SETUPN

END

FUNCTION 0 V A D x F ( T

)

C 0 V A p , J/MOL, VIA CLAPEXPON. ^ F N G A S F ( T ) CALLS dsaTF(T).

Cn88OK/-a/0POi,o?DpT5,OPSDT,DP M OT, r| PD r',D pr>R,rTSDF,OTHDP, rtDSDT

1 VL = 1 ,'J/OFNLIQF(T ) « V G = 1 . * /D F NGA S F ( T ) 2 0 V A p x f x 100*T*D°SDT* ( VG-VL

)

9 P F T IJ P N

E NO

FUNCTION S S A T f ( T

)

C H YD9 OGEV SULFIOE SAT1I0 FNTPODy, j/*OL/><., PDG/NPS, 4/15/03.

C YS - (S-SC) /( ST-SC ) , X . T/TC, ALT - LNtTT/TC )* U « ( TC-T ) / ( TC-TT )

,

C CONSTPMNFO AT T p T p L E ANO CPITICAL POINTS.

C YS = UE A1 ml M X ) /alt - UE ) + A 2 + ( U 2 - UE).

DATA ( TTPD=1R 7 .66) ,

(

T CPT*373.40)

DATA (ES-0.35),(FE-0.85),(STPP*109.?P667),(SCPT-167.26532)

DATA (ALT = -0.6 a P01 R *» 2 ) DATA ( A 1 *0 . 412268784), ( A?»0. 212761017)

1 FOP0AT(1HO 9 X 3HT -F10.5, * IN SSATF(T). * / ) 2 IF(TCBT-T) ?,4,5

3 P P I N T 1, T * STOP

4 S S A TF « SC P T $ P E TUP N

5 SN . S TP 0 - S C P T l UN - TCPT - TTP p % U » < TC R T— T ) / UN

7 y > T/T^T % U E « I J * * E S

0 YS - UE + AlMALCGm/ALT - UE) A2MUH' - UE ) 9 SSATF - SC p T + S N * Y S 5 PETUPN

END

38
Appendix F. Continued

SUBROUTINE STAPLNG

C COMPARE STAPLING H’S CEPAPTUPFS WITH RDG.

C HIS T,F. ° > D S I > V , C UP T /LB, h,BTU/LP» S»BTU/LB/R.

C T. KELVIN « (T,PANKINE )/1.8.

C 1 L" > 453.6924 GRAM, 1 CUPT - 28.31685 L, 1 BTU - 1055. JOULE.

C ONF PT'J * ( 453.5°24)*(4,184) / (1,8) - 1054.350 JOULES.

C TO CONV. LB TO Mn L » M l'LT. BY ( 5 2 . 592 4 ) /WM

C TO C^NV. CUPT/LB T n L/MOl, «ULT. BY ( 2 8 . 3 1 6 B 5 ) * WM / ( 4 5 3 , 5 9 ? 4 ) . C TO CONV. BTU TO JOULF, MILT. BY 1055.0.

C n C n NV. BTU/L a TO J/MOL, MULT. BY ( 1 0 5 5 . 0 ) * W * / ( 4 53 . 5 92 4 )

C TO CONV. BTU/LB/R TO J/M-U/K, MULT. BY 1 . 8 * ( 1 0 5 5 . 0 ) * W M / ( 4 5 3 . 5 92 4 ) . Common /i/al,«e,ga,de»ep,et, dcpt,tcrt,pcrt, dgat,dtrp,ttrp,ptrp

COMMON/?/ IN, IK, p,T,OEN, E » H > S > CV,CP»CSAT, W,WK

CnMMnN/cq/ T I , E 7 Z , EZ»S7»CVZ» HZ,CPZ

DATA ( R-R .3145 ), ( 9-1054.350 ) DATA (w M *34.0 fi ), (ALB = 453. 5924), (CUF-26. 31685)

1

Fnt«iT(l5, 4F10.0)

7 POPMAT ( 1HH3X*HYDP0GEN SIJLFIDE PROPERTIES, S T A P L IN G ( D A T A ) VS.*

1 * PCG(CALC)* //

2 1 4 K 1 H T 0 X 1 H P 8X14HDENSITY, MOL/L 1 0 X 1 5 HF N T H A L P Y, J/MOL

3 1 2 X lBMENTR^PY, J/moL/k / 4 l 4 X ] H K 4X3HMD 1 5X4HDAT A 5X4HCALC 2 X 4H PC NT

5 ?( s X4HDATA 5X4HCALC 5X4HDIFF) ) * P0PM 4 T( e x F10.3, 8F9.4, F6.2, 3F9.1, 3F9.3)

5 PK « 1.01325/14.696 IVK • ALB/WM/CUF

c b HK > 0*W M /ALB 1 SK 1.8+HK

6 SK « 4 .1 a 4*WM S HK - SK /l . 8 1C PRINT ? ? DO 50 J-1,99

11 PFAD 1, TTF, p S I * VB, H3, SB $ I F ( I TF . E 0 . 900 ) RETURN

12 T « ( I T F 4 5 9.67 ) / 1 . 8 t P - PK*PSI $ DX - VK/VB

13 HX • H K * H B $ SX - SK*SP » RT - R*T

r FOP EACH ( T » P ) POINT, GET MY D F N , (H-EZZ), S.

C AT T,LT. T CPT* EITHER GAS, OP LIOUID.

20 I F ( T. LT.TCPT ) 21,30

21 PS « p S A T F ( T ) % IF(P.GT.PS) 23,30

23 CALL C O

w P R L 0 % 1 X

It X EZ Z $ GO TO 40

30 CALL G E N F n i

1

! H « H - E 7 Z 40 D 0 1 F - DX - DEN T DPCT - 100*D0IF/DEN

41 H D I F - m* - H t SDIF - SX - S % pis - P/ 10

5 C PRINT 3, T, PI', DX, DEN, DPCT, HX > H, HDIF, SX, S, SDIF

99 RETURN 1 END

39
Appendix F. Continued

SUBROUTINE SURFACE

C PRINT H2S ISOCHORES, ISOTHERMS.

COMMON/1 / AL, BE»GA,DL , EP.ET, DCRT,TCRT,PCRT, DGAT,OTRP,TTRP,RTRP

COM MON/3/DPDT,D2PDT2»DPSDT,DPMDT, DPDD, DPDR,DTSDR,DTHDR,DDSDT

DATA (R - 0.0931*5)

1 FORMAT ( I 5, 2 F 1 0 • 0 ) 2 FORMAT(I5, FIO.O, 110)

5 FORMAT(IX)

6 FORMATdHl 10* *HYDPOGEN SULFIDE ISOCHORE AT* F7.3, * MOL/l* //

1 1 9 X 1 H T 9X1HP 9X1H2 6X5HDP/DD 7X5HDD/DT 5X5HDP/DT 5X7HD2P/DT2 / 2 19X1HK 7X3HMPA 1 2 X 9 H M P A-L / M OL 5X7HM0L/L/K 5X5HMPA/K 5 X7HMP A /K /K ) 7 FORMAT ( 1 OX F10.3, F10.A, F10.5, Fll.A, E12.A, F10.5, F12.7)

0

FORMATdHl 1 6 X *HYDRCGEN SULFIDE ISOTHERM AT*F9.3, * K * //

1 17X3HDEN 9X1HP 9 X 1H Z 6X5HDP/DD 7X5HDD/DT 5X5HDP/DT 5X7HD2P/DT2 / 2 15X5HMDL/L 7X3HMPA 12X9HMPA-L /MOL 5X7HM0L/L/K 5X5HMPA/K

3 5 X 7HMPA/K/K ) C PRINTOUT THE ISOCHORES.

20 DO 60 1-1,99 $ READ 2, IDD, DN, IT * IF(IDD) 21,99

21 IFd.EQ.20) ON - DTPP

30 PRINT 6, DN $ TS - TSATF(DN) $ PS - P VTF ( TS, DN, 1

)

31 Z - PS/DN/R/TS S DDDT - -DPDT/DPDD

PS-PS/10 i DPDD-DPDD/10 S DPDT-DPDT/10 S D2 PDT2 -D2PDT 2 / 10

32 PRINT 7, TS,PS,Z, DPDD, DDDT, DPDT, D2PDT2

50 DO 59 J-l 92, 720.IT $ TT - J S IF(TT.LE.TS) 59,52

52 PP PVTF(TT,DN,1) S IF ( P P . GT . 850 ) 60,55

55 Z - PP/DN/R/TT \ DDDT « -DPDT/DPDD

PP-PP/10 $ DPDD-DPDD/10 $ DPDT-DPDT/10 S D 2 PD T2 -D2 PD T2 /I

58 PRINT 7, TT,PP,Z, DP CD , DDDT , D POT , D2PDT2

59 CONTINUE

60 CONTINUE

C PRINTOUT THE ISOTHERMS.

99

DO 130 1-1,99 % READ 1, IDD, TT, D* i I F ( IDD) 100,999

100 IFfI.E0.13) TT - TCRT

101 PRINT 8, TT $ PM - PMELTF ( TT

)

102 IF(TT-TCRT) 103,103,10*

103 DG - DENGASF(TT) $ DL DENLIOF(TT)

10* L - 0 $ ns - DX 105 DO 120 N-1,900 $ DN « N*OS $ I F ( TT .L T . TC RT ) 106.117

106 IF(DN.GE.DG.AND.DN.LE.DL) 107,117

107 L L*1 % IF(L.EO.l) 108,120

108 PG « PVTF(TT,DG,1) $ Z • PG/DG/R/TT $ DDDT - -DPDT/DPDD

PG-PG/10 $ DPDD-DPDD/10 $ DPDT-DPDT/10 % D2 P D T2 -D2 PD T2 /I

109 PRINT 7, DG.PG.Z. DPDD, DDOT , DPDT , D2PDT2

110 PRINT 5 111 PL - PVTF ( TT,DL»1 ) $ Z - PL/DL/R/TT % DDDT - -DPDT/DPDD

PL-PL/10 % DPDD-DPDD/10 $ DPDT-DPDT/10 $ D 2 PD T2 -D 2 RD T2 / 10

112 PRINT 7, DL»PL,Z, DP DO , DDDT , D P DT , D2PDT2

116 GO TO 120

117 PP - PVTF ( TT.DN.l ) $ I F ( P P . GT . P M . OP . P P . GT . 850 ) 130, 118

118 Z - PP/DN/P/TT $ DDDT - -DPDT/DPDD

PP-PP/10 i DPDD-DPDD/10 t DPDT-DPDT/10 S D2 P DT2 -D2 PD T 2 / 10

119 PRINT 7 , DN , P P , Z , DPDD, DDDT, DPDT, D2PDT2

120 CONTINUE

130 CONTINUE

999 RETURN $ END

41)
Appendix F. Continued

SUBS P'JT INF TARLTO

C TABULATF UYPROGFN SULFIDE SATO, LICUID FUNCTIONS.

C0 MM 0N/l/4L» a E»F.A, r'F , F P , E T » DCRT,TCPT,oCRT, DGAT,DTR 0 »TTPP, p TRP CnNHON/B/C D PT,C?PDT?,OPSDT,DP M OT,DP[)0»DPDK,DTSDF,DTHDR»DDSDT

Cn us10N/6/ TSAT, THFTA, DSAT

CD^ON / a / IN, IK, p , T, PEN , £ , H , S , CV, CD, CSAT, W,WK

CrtMMON/12 / Z C R T , ZCALC ,OZDT , Z S A T, D Z SO T, 7 F X , F ft T , D FP TDT CQ"N0N/1Q/ DNG,EG,HG,SG, CVG,C D G,WG, DP&DT,0PGD0

C OR M on / 99 / T I , E Z 7 , FX.SZ,CVZ, HZ,CP7

DIMENSION DSa(6'‘'),TSA(6D)» d SA(60)»DLT(60),DPT(6O),DPD(6C)

DATA (C«O.De3145),(UR«36.08)

A FOPM AT( lHH3y*PPOPEPTIES OF SATURATE^ LIOUIO HYDROGEN SULFIDE*//

1 1 A X l H T 11 y I H D 3X5HDEN, L 7X5HDFN»G 3X5HZ.LIQ 3 X *5 H Z , G A S 2 *X*>HOPS/DT 3 X 6 HOD |_ / Q T 3X5HDP/DT 6X5H0P/D0 / 3 1AX UK 9 * 3 H N p A 3 Y 5 H M OL / L 7X5HMDL/L 16X

A 6X5HNPA/K 2X7HMOL/L/K 3X5HNPA/K 2X9H* p A-L/MOL ) 5 FOPM AT( 5XF1(,,3, F12.5, FR.2, F12.5, 2F3.5, F 1 1 . A , F 9 . 5 , F P . A , F H . A ) U pn? s.4 t ( 1 *-'l 1 3 y*d?D°EP T I E S OF SATURATED LIQUID HYDROGEN SULFIDE*//

1 14X l w T AXFHO,VAP R X 1 HF R X 1 FH 3 X 1 H S 2 0X7HCV A x 2 S A X 2 R C P 6XRHF/P 6X1HK / 3 1 A x 1«< AX C HJ/MHL AX 5 MJ/MHL 4X5HJ/N0L 2X7MJ/-0L/K

A 1X7HJ/ M PL / R 1X7MJXYHL/K lY7>3j/MrL/K m 5H*/SEC ) 12 FORMAT ( 5 X F 1 C « 3 » 3F9.1, F9.3» 3FB.2, F9.5, 17)

f COP PAGE QNF of TARLIO.

C INSERT BOILING POINT AT J = 7. 100 no s AO I PRINT p, « DO 15 0 J * 1 , N o « T=1P0+5*J

ID? IF(J.EO.l) T - TTRo t I F ( J

c 0 . 7 ) 106,10*

10* T * FJNDTSF (1 .01323)

IDA I F ( J , f T , -7 ) T = T - 5.0

125 IF(J.EO.NR) 126*13°

1 ? 5 T « TCRT * ns A ( J

) »0G*DL “OCR T J OLTfJ) DOLDT • 0

1 o 7 VG = VL = 1 . 0 / o C R T t ZG = ZCRT $ GO T° 1A1

139 D S A ( J ) = Dl = OCNLIDF(T) % DLT(J) = D C L 0 T = ODSOT

140 0 0 * OFNGASF(T) i 7 G 7CAT <1 VG * 1/DG $ VL • 1/DL

1 A 1 T S A ( J ) * T $ PX « D VTF(T,DL,1) « 0PT(J)*O°DT $ DPD(J)-DDDD

1AP PSA(J) = PS » PSAT % x x PS/DL/G/T

143 DC=PS/10 ? DPS0T*0°S0T/lO < OROT-OPOT/ID t D=0D=DDDD/10

150 print 5, T , P S * DLfOG, 7,ZG, DP SDT ,DDL0T , DP0T,0PDD

C PAGE 2* TARLIO. AVOID COEXIST, TTMFSaVER.

C GET FUG AC TTY GOFF., (F/P), VIA w7, S7* MG, SC-. 160 PRINT 11 T DC 180 J * 1 ,

3 S TxTSA(J) f DL*DSA(J) 1 DSxOSA(J)

161 DDLDT*DLT( J ) f DYOVAPXF(T) T S-S^ATF (T) ? H«HSATF(T)

157 F * h - 100*0$/°! i I F ( J , E 0 , N p ) 16 3, 1 6 A 163 CV = C S A T = CP = IW * 0 t G,n TC l^C

154 dx x 3VTF(T,0L,1) ? CSAT x CSATXF(T)

165 CV • CSAT + 10 0* T* D° DT* DDL DT / D L / 0L 166 C® * GV 100+T/0P0D* ( DPDT/OL ) **? $ I W = S OR T ( WK * C P* D D / C V

)

l^O TI * T S CALL IDEAL * GI9 = H - EZZ - HZ - T*(S-S?)

171 GJ - 100*G * FOP » l.C1325/PS*EXP(GIP/GJ/T)

130 p p I N T 12, T , 0 X , E,h,S, CV,CSAT,C p , FD°» IW 999 RETURN

END

41
Appendix F. Continued

FUNCTION THPTAF (OEM

)

TMETA - TSAT*EX P (U(S' ) . LET 0 * ( S-l ) / (ST-1 ) . WHERE ST - DTRP/OCRT, THEN - IF S < 1. U = AL*0**3» TF S > 1, U * -AL*0**3>

CO“"ON/l/AL,RF,r, a,DF,e d ,ET, OCR T» TC R T» D C R T, 0 G A T , D TR P , T TR p , P TR R C1M M ON/3/DPDT,n.3 p DT2,UDSUT,DPMDT,DPDO,DPDR, DTSDR, DTHDR.DDSDT

COMMON /6/ TSAT, tmpTA, PS AT

1 S * DEN/OCRT 4 osne * OTRP/DCRT 4 C * DSDR-1

2 0 - (S-l )

/

r $ 02 » 0*C 4 U - A L *0* 02

3 L'l « AL*3*02*DSDR /C 4 IF(O) 5 » 9 , A A U « -U 4 U1 « -Ml

5 X P = f X P ( U ) 4 THETAP * T S A T * X P 6 nTHQP * (TSAT+U1 0T4nR)*YP I RETIRE

q THE T AF » TCPT 4 OTHOP - 0 4 PETIJRN

F N n

FUNCTION TSATF(OEN)

ITFPATE T TO minimise (OFN-DCALC) VIA OENCASF (T) « DENLIOF(T).

IF TTFRATION f 4 j l E » PRINTOUT ONCE ON L y AND STOP AT K * 2.

C n«MnN/i/4L,PE»GA,0E»EP#ET, DCRT.TCRT.pCRT, DGAT,DTRP,TTRP,PTRR

Comm ON /3/UPDT,D’RUT?,D d S0T,DPMDT,DpDU,DddR, DTSDR, DTHDR,DDSDT

DATA (0*2.0), (fn*6.’«R0561)

NOTE, FN » EXP (0) - l.C.

1 FORMAT ( ] H 1 1 A X *TSATF(DFN) FAILS AT DEN * * F L 5 . 7 / /

1 15X EMOCALC 13 X? HDD 1 0 X 5 HDD S 0 T 13X2 HU T 12X3HT,W ) 2 fiopmat ( 5 X f El c .7)

3 * » 0 4 D * DEN AS* 0 / DC P T 4 YN = TCRT/TTPP-1 4 IF(O-DCRT) 5,30,6

5 ?T»DGA T/nCRT 4 F * A L n G ( S) / ALOG( 5 T ) * ( ( 1 — S ) / ( 1 — S T ) )**

4 SO TO 7 6 ST-DTPP/DCPT 4 U * ( ( S - 1 ) ( S T- 1 ) ) * * 3 4 F • ( E X P ( 0 * U

) -1 ) / F

7 T * TCPT/ ( vnmF+i

)

Bq 10

li

1713

1 A 1516IB70

71

7530

no 20 J = I , 5 C 4 IF(D-DCRT) 0,30,10

DC * DENGASF(T) 4 GO TO 11 DC * OENL IOF ( T

)

DO = 0 - DC 4 IF(APS(DD/D) .LT.l.CF-7 ) 25,1’

DT = DD/DDSOT 4 I F ( A R S < D T / T ) . L T . 1 . 0 E -7 ) 26,13

T - T + DT 4 IF ( T ) 1 A , 1 A , 1 5 T « TTRP « GO TO IB

IF ( T.LT.TCRT) IB, 16

T « TCPT - 0 . 0 0 0

n

2 IF(K.EO.l) PRINT 2, DC. D n , DDSOT, DT, T CONTINUE 4 K = K+l 4 IF(K.NE.l) STOP

4 CO TO A DTSDR - DTPP/DDSDT 4 RETURN

PRINT 1 , DEN

TSATF T 4 T S AT F FND TCRT DTSDR 4 RETURN
Appendix F. Continued

FUNCTION XCF(T.O)

C X C F « ( X**BF ) *E XP

{

A*( 1-TS /T ) ) - XS**RF. WHEPE -

C X # T/TC. XS * T S / T C > A # (1-BE) SOOT(l-PE).

xcp = u*fxp(a*V) - us. u n x**b> us n xs**b, v # ( 1 -ts/t).

CnMM-iM/i/AL, t'E»GA,OF»F t> »ET. DCRT.TCRT.pCPT, QGAT.DTPP.TTPP.PTRP

C0*H0s,/3/dPDT,Q2PQT2.0PFDT,DPMDT,DPQD,QPDR,DTSDP,QTHDP»1DSDT

CDMmon/^/xPI, XR 2, XC1.XC2. XE1.XE?. 0 X B DP , D X C 0 P , 0 X E DP COMMnn/6/ TSAT, TH F T A » °SAT

1 B x BE X PN - 1-3 X A • BN SO=T ( BN

)

2 TC » T C R T « T S = TSAT X X * T / TC $ X S

* TS/TC 1 XS1«DTSDP/TC

3 U = X7*B l U1 = 3*U/X $ U2 S -RNWiJl /X

9 US * x S **B $ US1 « B*US+XX1/XX

5 V X 1-TS/T X VIP . -OTCOR/T X V1X - TS /T/X X V2 x -2* V 1 X / * 6 P X F X P ( A * V ) x 3 1

x A*P X P 2 - A * P 1 7 PI R = PI *V1

$ pi x = pi+vi x $ P 2 X = p 1 * v? X •f P2*V1 X* V1X

3 xc F * U* D - US X 0 XC PR x U * p 1

- MSI * xci x U*P1X U1*P

9 XC 2

x IJ+D2X + 2*'J1*P 1 X + U2* p X RETUPN

E NH

FUNCTION XFF(T,n)

C ULTRA REVISION, "APCH 29, 1 9 B 1 , C X E p * H(P,T)/HMP) - 1.0. W # (1-TH/T), WE « W**E»

C H(P.T) # 1.0 - ( W-WF/F ) / { 1-1/ E ) > E * ET. COMMON /i/al, 3 f,ga,oe»e d .ft, dcrt.tcpt.pcpt, ogat.dtpp.ttrp.ptrp

COW“ON/3/C)PDT»D2 D DT2>'' :> P r)T»OP^OT»DP ri D.OPnP»r)TSDP»DTMPP.OOSOT

CQm^on/ 9/ XF1.XR2. XC1.XC2. XE1.XE2* OXBDP.OXCDP.OXE OR Cn^^HN/6/ TEAT. THETA, dSST

1 E = FT x F K = E / ( E - 1 ) i TC « TCPT

2 TS = TSAT « TH * THETA t X « T/TC

3 W - 1.0 - TH/T X I F ( W ) 3 C » 3 0 > E S W1P * -OTHQ P / T X W1X * TH/T/X X W 2 X * -2*Wlx/X

*, WE = W * * F $ WET x F*Wt/w T W E 1 R = WEI * Wl R 7 uE 1

v * WF1 * Wl x x w E 2 X

x WE 1 * W2 x ( E-i ) * WF 1 * wl X* Wl * / W

3

u « i - fw*(w-je/E) t HIP -E K * ( Wl R-W E 1 P / E

)

9

wi x « -EK*( W1X-WE1 X/F ) % u 2 X * -FR*( W2X-WE2X/E

)

10 wS = 1.0 - TH/TS X IF(WS) 11.11.12

11 HS * 1 I HS1 =0 % GO TO 16

1? vSl • (Th+DTSDP/TS - DTHDP)/TS

13 WS c = wS**F 1 WSE1 = F*WSE*WS1/WS

14 MB * 1 - EK + ( WS-WS C /F ) X MSI * - E K * ( W S

1 - W S E 1 / E ) 16 U 1.0/hS x U1 • -U*HS1/HS

20 ycc , H*U - 1.0 1 OXEDR - H + U 1 N1R*U

21 X F 1 X U*H1X X XE? = U*H2X $ PFTJPN

30 X E F x X F 1 * XF2 * OXEDR 0 X RETURN

END

43
Appendix U Ideal Gas Functions by Haar, et al

Table 3. Ideal gas thermodynamic functions for H2 S

°K c;R

(H°-Eo ) RT

~(F°-Ei

RT

—s° ~R

50 4.00286 2 3. 95091 866 13. 59988 72115 17. 55080 72981 60 4. 00288 13 3. 95957 619 14.32103 61086 18. 28061 61705

70 4. 00301 20 3. 96576 467 14.93189 52988 18. 89766 53454

80 4.00321 24 3. 97043 366 15. 46177 46787 19. 43220 47153

90 4.00345 28 3. 97409 295 15.92964 41887 19. 90373 42182

100 4. 00373 31 3. 97704 244 16. 34851 37917 20. 32555 38161 no 4.00404 39 3.97948 206 16. 72768 34635 20. 70716 34841

120 4.00443 51 3. 981.54 178 17. 07403 31876 21.05557 32055

130 4. 00494 72 3.98332 157 17.39279 29526 21.37612 29682

140 4.00566 103 3. 98489 141 17. 68805 27498 21.67294 27640

150 4.00669 148 3. 98630 132 17. 96303 25731 21. 94934 25863

160 4.00817 204 3. 98762 127 18.22034 24179 22. 20797 24305

170 4.01021 272 3.98889 125 18. 46213 22803 22. 45102 22929

180 4.01293 353 3.99014 129 18. 69016 21577 22. 68031 21706

190 4.01646 443 3. 99143 136 18. 90593 20477 22. 89737 20612 200 4. 02089 540 3. 99279 146 19. 11070 19484 23. 10349 19631 210 4. 02629 640 3. 99425 160 19.30554 18585 23.29980 18745

220 4. 03269 743 3. 99585 176 19. 49139 17766 23. 48725 17942

230 4.04012 844 3. 99761 194 19. 66905 17018 23. 66667 17212

240 4.04856 944 3. 99955 215 19. 83923 16331 23. 83879 16546 250 4. 05800 1040 4.00170 236 20. 00254 15700 24. 00425 15936

260 4. 06840 1130 4. 00406 259 20. 15954 15116 24. 16361 15375 270 4. 07970 1215 4.00605 283 20.31070 14576 24.31736 14858 280 4. 09185 1293 4. 00948 306 20. 4.5646 14075 24. 46594 14382

290 4. 10478 1366 4. 01254 330 20. 59721 13609 24. 60976 13938 300 4. 11844 1432 4.01584 354 20. 73330 13174 24. 74914 13528

310 4. 13276 1491 4. 01938 377 20. 86.504 12767 24. 88442 13144 320 4. 14767 1546 4. 02315 401 20. 99271 12386 25. 01586 12787 330 4. 16313 1595 4. 02716 423 21. 11657 12028 25. 14373 12452

340 4. 17908 1640 4.03139 445 21.23685 11692 25. 26825 12137 350 4, 19548 1680 4. 03584 467 21. 35377 11376 25. 38962 11843

360 4. 21228 1717 4. 04051 487 21. 46753 11077 25. 50805 11564 370 4. 22945 1752 4. 04538 508 21.57830 10795 25. 62369 11303 380 4. 24697 1782 4. 05046 526 21.68625 10529 25. 73672 11054 390 4. 26479 1811 4. 05572 646 21. 79154 10275 25. 84726 10821 400 4.28290 9429 4.06118 2982 21. 89429 48002 25. 95547 50984 450 4. 37719 9955 4. 09100 3355 22. 37431 43273 26. 46531 46629 500 4. 47674 10382 4. 12455 3671 22. 80704 39481 26. 93160 43152

650 4.58056 10705 4, 16126 3939 23. 20185 36375 27.36312 40313 600 4.68761 10909 4. 20065 4164 23. 56560 33786 27. 76625 37951 650 4. 79670 10981 4.24229 4352 23. 90346 31597 28. 14576 35949

700 4. 90651 10923 4.28581 4503 24. 21943 29722 28. 50525 34225

750 5. 01574 10751 4. 33084 4618 24. 51665 28098 28. 84750 32715

800 5. 12325 10481 4. 37702 4699 24. 79763 26676 29. 17465 31376

850 5.22806 10139 4. 42401 4751 25. 06439 25421 29. 48841 30171 900 5. 32945 9744 4. 47152 4773 25. 31860 24304 29. 79012 29078

950 5. 42689 9314 4.51925 4773 25. 56164 23303 30. 08090 28075

1000 5. 52003 8866 4. 56698 4751 25. 79467 22397 30. 36165 27149

1050 5. 60869 8410 4. 61449 4712 26.01864 21576 30. 63314 26287

1100 5. 69279 7960 4.66161 4658 26. 23440 20824 30. 89601 25483

1150 5. 77239 7518 4. 70819 4593 26. 44264 20136 31. 15084 24728

1200 5. 84757 13774 4. 75412 8951 26. 64400 38408 31.39812 47360

1300 5. 985312224 4. 84363 8600 27. 02808 36213 31.87172 44812

1400 6. 10755 10843 4. 92963 8222 27. 39021 34293 32. 31984 42515

1500 6.21598 9632 5.01185 7832 27. 73314 32598 32. 74499 40431 1600 6. 31230 8576 5.09017 7446 28. 05912 31084 33. 14930 38530

1700 6. 39806 7661 5. 16463 7069 28. 36996 29723 33. 53460 36792

1800 6 47467 6869 5. 23.532 6707 28. 66719 28487 33. 90252 35194

19(H) 6. 54331. 6182 5. 30239 6362 28. 95206 27361 34. 25446 33723

20(H) 6.60518 5588 5. 36601 6036 29. 22567 26328 34. 59169 32364 2100 6. 66106 5070 5. 42637 5730 29. 48895 25377 34.91533 31106 2200 6.71176 4621 5. 48367 5441 29. 74272 24497 35. 22639 29939

2300 6. 75797 4227 5. 53808 5172 29. 98769 23680 35. 52578 28852

24(H) 6. 80024 3882 5. 58980 4921 30. 22449 22919 35.81430 27840

2500 6. 83906 3.580 5. 63901 4685 30. 45368 22209 36. 09270 26894 2000 6. 87486 3312 5. 68586 4466 30. 67577 21543 36. 36164 26008

2700 6. 90798 3070 5. 73052 4261 30. 89120 20918 36. 62172 25179 2800 6. 93874 2866 5. 77313 4069 31. 10038 20330 36. 87351 244(H)

29(H) 6. 96740 2678 5 81382 3891 31 . 30368 19776 37. 11751 23666 3000 6.99418 4872 5. 85273 7289 31.50144 38009 37. 35417 45298 3200 7.04290 4331 5. 92562 6702 31.881.53 36128 37.80715 42830 | 3400 7.08621 3887 5. 99264 6185 32. 24281 34430 38. 23545 40616 i 3600 7. 12508 3520 6. 05449 5729 32. 58711 32890 38. 64161 38619 | 38(H) 7. 16028 3213 6. 11178 5324 32. 91601 31487 39. 02780 36810 4000 7. 19241 2954 6. 16502 4964 33. 23088 30201 39. 39590 35165 4200 7. 22195 2731 6. 21466 4641 33. 53289 29018 39. 74755 33660 4400 7. 24926 2538 6. 26107 4352 33. 82307 27929 40. 08415 32281 4600 7. 27464 2370 6. 30459 4092 34. 10236 26920 40. 40696 31011 4800 7. 20834 2222 6. 34551 3856 34. 37156 25982 40. 71707 29839

5000 7. 320.56 6.38407 34.63138 41.01546

Table 4. Ideal gas thermodynamic functions for HDS

°K ClR

( H°-Ei) RT

-(F°-Eh) RT ~R

50 4.00238 14 3.96864 563 14.84410 72410 18.81274 72974

60 4. 00252 22 3. 97427 405 15. 56820 61295 19. 54248 | 61700

70 4. 00274 26 3. 97832 307 16. 18115 53145 20. 15948 53451 80 4.00300 29 3.98139 242 16.71260 46908 20. 69399 ; 47150

90 4.00329 35 3.98381 196 17. 18168 41984 21. 16549 42181

100 4.00364 46 3. 98577 165 17.60152 37997 21. 58730 38161

110 4. 00410 66 3. 98742 141 17.98149 34701 21.96891 34843

120 4. 00476 101 3. 98883 126 18. 32850 31933 22.31734 32059

130 4. 00577 154 3.99009 118 18. 64783 29574 22. 63793 29691

140 4.00731 224 3. 99127 114 18. 94357 27541 22. 93484 27655

150 4. 00955 314 3. 99241 116 19.21898 25770 23.21139 25886

160 4.01269 419 3. 99357 124 19. 47668 24214 23. 47025 24339

170 4.01688 537 3. 99481 137 19. 71882 22838 23. 71364 22975

180 4. 02225 664 3.99618 154 19. 94720 21610 23. 94339 21764

190 4.02889 797 3. 99772 175 20. 16330 20510 24. 16103 20685

200 4. 03686 930 3.99947 200 20. 36840 19519 24. 36788 19718 210 4. 04616 1063 4.00147 227 20. 56359 18620 24. 56506 18847 220 4. 05679 1190 4.00374 256 20. 74979 17802 24. 75353 18059 230 4. 06869 1313 4.00630 287 20. 92781 17057 24. 93412 17343 240 4.08182 1428 4.00917 319 21. 09838 16373 25. 10755 16692 250 4. 09610 1535 4. 01236 351 21. 26211 15743 25. 27447 16095 260 4. 11145 1634 4. 01587 384 21.41954 15163 25. 43542 15547 270 4. 12779 1726 4.01971 417 21.57117 14627 25. 59089 15043 280 4. 14505 1808 4. 02388 448 21. 7K44 14128 25. 74132 14576 290 4. 16313 1884 4.02836 481 21.8.5872 13664 25. 88708 14146 300 4. 18197 1953 4.03317 511 21.99536 13233 26. 02854 13744 310 4. 20150 '2015 4.03828 541 22. 12769 12830 26. 16598 13371 320 4. 22165 2072 4. 04369 571 22. 25599 12452 26. 29969 13022 330 4. 24237 2123 4. 04940 599 22. 38051 12097 26. 42991 12696 340 4. 26360 2170 4. 05539 625 22. 50148 11765 26. 55687 12391

3.50 4. 28530 2212 4.06164 652 22.61913 11451 26. 68078 12103 360 4. 30742 2250 4.06816 677 22. 73364 11155 26.80181 11832 370 4.32992 2286 4. 07493 701 22. 84519 10877 26.92013 11578 380 4. 35278 2316 4.08194 724 22. 95396 10612 27.03591 11336 390 4. 37594 2345 4. 08918 747 23.06008 10362 27. 14927 11108 400 4. : 9939 12066 4.09665 4029 23. 16370 48480 27. 26035 52510

450 4. 52005 12430 4. 13694 4451 23. 64850 43814 27. 78545 48264

500 4. 64435 12565 4. 18145 4779 24. 08664 40075 28. 26809 44855

550 4. 77(HH) 12499 4. 22924 5028 24. 48739 37014 28. 71664 42041 600 4.89499 12267 4. 27952 5208 24. 85753 34459 29. 13705 39668 650 5.01766 11902 4.33160 5328 25. 20212 32295 29. 52373 37623

700 5. 13668 11438 4. 38488 5396 25. 52507 30436 29. 90996 35832

750 5. 25106 10904 4. 43884 5420 25. 82943 28821 3(1. 26828 34241 800 5 36010 1033(1 4. 49304 5407 26. 11764 27401 30. 61069 32808 850 5. 46340 9736 4. 54711 5364 26. 39165 26143 30. 93877 31506

900 5. 56076 9142 4. 60075 5296 26. 65308 25017 31. 25383 30314 950 5. 65218 8557 4. 65371 ^09 26. 90325 24004 31. 55697 29212

1000 5. 73775 7993 4. 70580 5106 27. 14329 23083 31.84909 28190

10.50 5.81768 7455 4. 75686 4993 27. 37412 22245 32. 13099 27238

11(H) 5. 89223 6945 4.80679 4873 27. 59657 21475 32. 40337 26347

1150 5. 96168 6467 4. 85552 4745 27.81132 20765 32. 66684 25511 1200 6. 02635 11624 4.90297 9099 28. 01897 3960S 32. 92195 48706

1300 6. 14259 10082 4, 99396 8573 28. 41.50.5 37326 33. 40901 459(H) 1400 6. 24341 8761 5. 07969 8057 2S. 78831 35324 33. 86801 43381

15(H) 6. 33102 7636 5. 16026 7561 29. 14155 33548 34. 30182 41108

1600 6. 40738 6680 5. 23587 7092 29. 47703 31957 34. 71290 39050

17(H) 6. 47418 5864 5. 30679 6652 29. 79660 30523 35. 10340 37175

1800 6. .53282 5168 5. 37331 6242 30. 10183 29221 35. 47515 35462

1900 6. 58450 4572 5. 43573 5860 30. 39404 28033 35. 82977 33893

2000 6. 63022 4059 5, 49433 5508 30. 67437 2694

36. 16870 32449

21(H) 6. 67081 3617 5. 54941 5181 30. 94378 25937 36. 49319 31118

2200 6. 70698 3233 5. 60122 4879 31. 20315 25007 36. 80437 29880

2300 6. 73931 2898 5. 65001 4600 31.45322 24144 37. 10323 28745

2400 6. 76829 2605 5. 69(H) 1 4342 31. 694(H) 23341 37. 39(H;s 27683

25(H) 6. 79434 2346 5. 73943 4103 3 1 . 92807 22592 37. 66751 26095

26(H) 6.81780 2119 5. 78046 3882 32. 15399 21889 37. 93446 25771 2700 6. 83899 1916 5.81928 3677 32. 37288 21230 38. 19217 24907

2H(H) 6. 85815 1735 5. 85605 3486 32. .58.518 20611 38. 44124 24097

29(H) 6. 87550 1573 5. 89091 3308 32. 79129 20028 38. 68221 23330 3000 6:89123 2720 5. 92399 6133 32. 991^7 38431 38. 91557 44564 3200 6. 91843 2236 5. 98532 5557 33. 37.588 36456 39. 36121 42012

34(H) 6. 94079 1830 6. 04089 .5052 33. 74044 34674 39. 78133 39726

36(H) 6. 95909 1483 6.09141 4607 34.08718 33060 40. 17859 37667

38(H) 6. 97392 1180 6. 13748 4213 34. 41778 31589 40. 05526 35803

4000 6. 98572 913 6. 17961 3862 34. 73367 30246 40, 91329 34107

42(H) 6. 99485 673 6. 21823 3546 35. 03613 29010 41. 25436 32556

44(H) 7. (H)l 58 454 6. 25369 3262 35. 32623 27872 4 1 . 57992 31134

46(H) 1 7. 00612 250 6. 28631 3005 35. 60495 26818 41.89126 29824

48(H) 7. 00862 60 6. 31636 2771 35.87313 25842 42 18950 28613

5(HHI 7. 00922 6. 34407 36. 13155 42. 47563

44
Hydrogen

Sulfide

45

200

300

400

500
o

o

CO

o

o

m

o

o

o

o

CO

*

edW ‘d

46

Figure

2.

P-T

lucus

of

P-p-T

data

of

Reamer

and

of

Lewis.
Hydrogen

Sulfide

o

o

00

edlfl ‘d

47

l

y

u

re
o

CM

"S’

o

"3

-

o

CD

CO

o

CO

CD CM 00 ^ CO CO

»/ioiu/r ‘(i)

A

o

O

CO

48

Figure

4.

Specific

neats,

C

v (

Tj

at

2U.S4

r.iol/L.
Table 1 Comparisons of vapor pressure data for H

2 S

hydrogen sulfide vapor pressure# MPA# epp 1.700

(l)REAMER# (2)GIAU0UE# (8)I.C.T.# (15)WEST# (2DCARD0S0

(32KLEMENC, ( 70 ) C L ARKE TTRO - 187.660# TBLP - 212.874# TC R T • 373.400

PTRo . ,02320# PC PT 8.96291# DPS/DTC « . 15238

A -8.023473844, 3 - 16.'731062287# c —io .:325650140

D • 9.690908499# E - -3.!577167041, f - 3.:174310817

ID WT T# K T/TC P# MPA CALCO PC N T DPS /DT P ESID

2 1.00 187.660 .50257 .02318 .02320 -.07 .00156 -.00012

2 1.00 188.400 .50455 .02438 .02438 .01 .00163 .00046

2 1.00 19 C . 556 .51033 .02810 .02810 -.01 .00163 .00163

70 1.00 193.150 .51727 .03318 .03319 -.03 .00210 .00293

2 1.00 193.890 . 51926 .03478 .03477 .02 .00218 .00336

2 1 . 00 197.030 .52766 .04219 .04217 .04 .00255 .00479

70 1.00 198.150 .53066 .04509 .04510 -.01 .00269 .00515

2 1.00 199.959 .53551 .05022 .05018 .09 .00293 .00601

70 1.00 203.150 . 54405 .06025 . 06 C 26 -.01 .00339 .00694

2 . 20 203.450 .54486 .06140 .06128 .20 .00344 .00738

2 .20 206.625 .55336 .07319 .07301 .23 .00396 .00635

70 1.00 203.150 .55745 .07925 .07925 -.00 .00423 ,00e34

2 .20 210.226 .56300 .08866 .08842 .27 .00461 .00929

70 1.00 212.875 .57010 .10133 .10133 -.00 .00514 .00936

70 1.00 212.074 .57036 .10103 .10184 -.01 .00516 .00938

70 1.00 213.150 .57084 .10274 .10275 -.01 .00520 .00941

2 .20 213. 216 .57101 .10339 .10309 .26 .005?1 .00991

70 1.00 218.150 .58423 .13144 .13145 -.01 .00631 .01019

70 1.00 223.150 .59762 .16608 . 16610 -.01 .00758 .01072

70 1.00 228.150 .61101 .20747 .20751 -.02 .00901 .01102

70 1.00 233.150 .62440 .25645 .25650 -.02 .01062 .01114

70 1.00 238.150 .63779 .313*9 .31395 -.02 .01240 .oiiio

70 1.00 243.150 .65118 .38070 .3e07B -.02 .01436 .01092

70 1.00 243.150 .66457 .45761 .45790 -.02 .01652 .01062

70 1.00 253.150 .67796 .54617 .54629 -.02 .01897 . 01C22

70 1.00 258.150 .69135 .64680 .64692 -.02 .02142 .00974

70 l .00 263.150 .70474 .76067 .76079 -.02 .02417 .00920

70 1.00 268.150 .71813 .88862 .8 e 892 -.01 .02712 •00 P 61

21 1.00 273.150 .73152 1.03352 1.03235 .11 .03029 . 00817

70 1.00 273.150 .73152 1.03230 1.03235 -.01 .03029 .00797

70 1.00 279.150 .74491 1.19219 1.19213 .01 .03366 .00732

70 1.00 283.150 .75030 1.36941 1.36930 .01 .03725 .00664

70 1.00 288.150 .77169 1.56527 1.56496 .02 .04105 .00596

1 . 20 293.150 .78508 1.77471 1.78018 -.31 .04507 .00471

70 1.00 293.150 .78508 1.78069 1.78018 .03 .04507 .00527

70 1.00 298.150 .79847 2.01667 2.01607 .03 .04932 .00459

70 1.00 303.150 .81186 2.27495 2.27374 .05 .05379 .00395

70 1.00 308.150 .82525 2.55592 2.55435 .06 .05849 .00330

1 1.00 310.928 .83269 2.71653 2.72059 -.15 .06120 .002.60

1 1.00 311.539 .83433 2.75790 2.75817 -.01 .06181 .00275

1 1.00 313.150 .83864 2.85443 2.85905 -.16 .06343 .00230

70 1.00 313.150 .83864 2.86111 2.85905 .07 .06343 .00269

70 1.00 318.150 .85204 3.19174 3 .18904 .08 .06861 .00212

70 1.00 323.150 .86543 3.54881 3.54556 .09 .07404 .00157

49
Table 1 Continued

HYDROGEN SULFIDE VAPOR PRESSURE* MPA, EPP • 1.700

ID WT T , K T/TC P , MPA C ALCD PC NT DPS /DT RESID

1 1.00 333.150 .89221 6.33562 6.36361 -.18 .08571 .00016

1 . 20 338.761 .90723 6.82633 6. 866 C 0 -.36 .09278 -.00061

1 1,00 366.261 .92196 5.37033 5.37626 -.07 .10011 -.00067

1 . 20 36 5 .2 8 .92509 5.51581 5.69203 .63 .10173 .00031

1 1.00 352.030 .96279 6.20528 6.19573 .15 .11129 -.00062

1 1.00 353.150 .96577 6.32180 6.32030 .02 .11297 -.00067

1 1.00 358.096 .95901 6.89676 6.89796 -.05 .12080 -.00085

1 1.00 360.928 .96660 7.26915 7.26701 .03 .12557 -.00071

1 1 . 00 3^3.539 .97359 7.58623 7.58087 .06 .13020 -.

CC 63

1 1.00 368.706 .98763 8.27371 8.27896 -.06 .16026 -.00057

32 0.00 188.200 .50602 .02616 . 02606 .62 .00161 .00103

32 0.00 193.200 .51761 .03393 .03329 1.91 .00210 .00618

32 0. 00 198 . 200 .53080 .06666 .06523 3.16 .00269 .01061

32 0.00 203.200 .56619 .06229 . C 6 0 6 3 3.08 .00360 .01206

32 0.00 208.200 .5575° .08158 .07967 2.66 .00626 .01277

32 0.00 210.200 . 56296 .09069 . 088’0 2.67 .00661 .01292

32 0.00 213.200 .57097 .10510 .10301 2.03 .00521 .01280

1 0.00 277.596 .76362 1.16521 1.17352 -.71 .03327 .00620

15 0.00 277.596 .76362 1.15832 1.17352 -1.30 .03327 .00520

1 0.00 282.706 . 75711 1.37895 1. 35286 1.93 .03692 .00990

21 0.00 287.950 .77116 1.51177 1.55676 -2.89 .06089 .00103

1 0.00 298.150 .79867 2.06863 2.01607 2.60 .06932 .00 e 86

2 1 0.00 301.000 .80611 2.11161 2.16020 -2 .25 .05186 .00033

21 0.00 309.800 .82967 2.60709 2.65218 -1.70 .06009 .00011

15 0.00 310.928 .83269 2.73722 2.72059 .61 .06120 .00387

21 0.00 319. 35 C .85525 3.22315 3.27216 -1.50 .06989 -.00069

1 0.00 323.150 .86563 3.66738 3.56556 -2.77 .07606 -.00330

21 0.00 329.350 .88203 3.97599 6.02663 -1.25 .08115 -.00132

1 0. 00 331.683 .88776 6 , 1 3685 6.20222 -1.56 .0 P 369 -.00206

21 0.00 333.250 .89267 6.32962 6.35199 -.51 .0 e 586 -.00062

21 0.00 337 . 800 .90666 6.71366 6.75563 -.88 .09156 -.00161

1 5 0.00 366.261 .92196 5.69512 5.37626 2.25 .10011 .00339

21 0. 00 351.600 .96108 6.05216 6.12692 -1.19 .11033 -.00267

21 0.00 358.750 .96077 6.96360 6.97756 -.68 .12189 -.00159

21 0. 00 360.900 .96652 7.19610 7.26350 -.65 .12552 -.001 86 15 0.00 360.928 .96660 7.62565 7.26701 2.66 .12557 .00333

21 0.00 363.650 .97335 7.52561 7.56928 -.58 .13003 -.00169

21 0.00 363.650 .97399 7.56087 7.59533 -.65 .13060 -.00167

2 1 0. CO 369.700 .99009 8.60592 8.61962 -.16 .16261 -.00066

21 0.00 370.000 .99089 8.50117 8. 66226 .66 .16307 . 00060

NP - 56, RMS PC T - .081

50
Table 2 Compari sons of saturated liquid density data for H

2 S.

HYDCOGEN SULFIDE SATLIQUID DENSITIES# EL .350

(l)REAMER, (8)1. C.T,# (32)KLENENC# (34)BA*TER# (70JCLARKE

TTPo 187.660# TBL P * 212.074, TC R T « 373.400

DTRP « 2 9.136, D L B

0 - 27.845, DC R T - 10.20

1.90639527 .83560589 -.57091447 .72347653

10 WT T»K T/TC KG/M3 MOL /L C ALCD PCNT DDS/DT

3 2 1.00 190.050 .50897 988.8 29.014 29.015 -.00 -.0507

32 1.00 192.050 .51433 995.4 28.914 28.913 .00 -.0508

32 1.00 194.050 .51968 981.5 28. 8C0 28.812 -.04 -.0509

32 1.00 196.050 .52504 978.4 20.709 20.710 -.00 -.0510

32 1.00 198.050 .53040 974 .

28.603 28.608 -.02 -.0510

32 1.00 200.050 . 53575 971.4 28.504 28. 506 -.01 -.0511

32 1.00 202 . C50 .54111 96 8.0 28.404 20.403 .00 -.0512

32 1.00 204.050 .54646 964 .4 28.296 23.301 -.01 -.0513

32 1.00 206.050 .55182 960.9 28.195 23.198 -.01 -.0515

32 1.00 206.050 .55718 957.4 28.093 28.095 -.01 -.0516

32 1.00 210.050 .56253 953.9 27.990 27.991 -.00 -.0517

32 1.00 212.050 .56769 950.4 27.857 27.888 -.00 -.0519

1 1.00 282.706 .75711 813.8 23.880 23 . 8e2 -.01 -.0645

1 1.00 298.150 . 79847 778.8 22.851 22.842 .04 -.0706

1 1 . 00 311 . 539 .83433 745.1 21.862 21 .850 .05 -.0779

1 1.00 323.150 .86543 711.6 20.879 20. 897 -.oe -.0068

1 0. 00 331.483 .88774 684.3 20.078 20.138 -.30 -.0956

1 0.00 338.761 .90723 657.8 19.302 19. 4C7 -.54 -.1059

1 0. 00 345.428 .92509 631.0 18.514 10.660 -.70 -.1191

1 0.00 352.039 .94279 600.9 17.632 17.814 -1.02 -.13P3

1 0. 00 358.094 .95901 568.7 16.688 16.897 -1.24 -.1670

1 0.00 363.539 .97359 532.6 15.628 15.872 -1.54 -.2155

1 0.00 368.706 .98743 484.0 14.201 14.510 -2.13 -.3359

70 1.00 193.150 .51727 983 .5 28.860 28.857 .01 -.0500

70 1 . 00 198.150 .53066 974 .8 28.604 28.603 .00 -.0510

70 1.00 203.150 . 54405 966.3 28.353 23. 347 .02 - • 0 s 1

70 1.00 208.150 .55745 957.3 23.090 28.090 .00 -.0516

70 1.00 212.875 .57010 949.0 27.847 27.845 .01 -.0519

70 1.00 212.974 .57036 949.0 27.047 27.840 .03 -.0519

70 1 . 00 213.150 .57084 948.5 27.832 27.831 .00 -.0519

70 1.00 218.150 .58423 939.9 27.579 27.570 .03 -.0524

70 1.00 223.150 .59762 930.9 27.315 27.307 .03 -.052e

70 1.00 228.150 .61101 921.8 27.049 27.042 .03 -.0533

70 1.00 233.150 . 62440 912.7 26.781 26. 774 .03 -.0539

70 1 . 00 238.150 .63779 903.3 26.504 26.502 .01 -.0546

70 1.00 243.150 .65118 893.6 26.226 26.228 -.01 - .0 5

K 3 70 1.00 248.150 .66457 884.3 25.947 25.949 -.01 -.0561

70 1.00 253.150 .67796 874.5 25.661 25.667 -.02 -.0570

70 1.00 258.150 .69135 864.5 25.368 25.379 -.04 -.0580

70 1.00 263.150 .70474 854.6 25.075 25.087 -.05 -.0591

70 1.00 268.150 .71813 044.4 24.777 24.708 -.05 -.0603

70 1.00 273.150 .73152 034.1 24.474 24.484 -.04 -.0616

70 1.00 278.150 .74491 823.6 24.166 24.172 -.03 -.0630

70 1.00 283.150 .75830 812.8 23.849 23.853 -.02 -.0646

70 1.00 288.150 .77169 801.9 23.529 23.526 .01 -.0664

70 1.00 293.150 .78508 790.5 23.196 23.189 .03 -.0634

70 1.00 298.150 .79847 778.8 22.852 22.842 .05 -.0706

70 1.00 303.150 .81196 766.7 22.497 22.483 .06 -.0730

70 1.00 308.150 .82525 754.0 22.124 22.111 .06 -.0758

70 1 . 00 313.150 .83864 740.7 21.734 21.724 .05 -.0790

70 1.00 318.150 .85204 726.5 2 1 . 3 1 7 21.320 -.01 -.0026

70 1.00 323.150 .86543 711.5 20.«77 20.697 -.09 -.0060

HP » 45# RHSPCT • .033

51
Table 3. Comparisons of saturated vapor density data for H

2 S.

HYDROGEN SULFIDE SATVAPQR DENSITIES# AG .70# BG 2.00

(l)REANER# (9IVIA 3 ( T ) » (10)VIA QVAP# (70JCLARKE# ( <5 5 ) V I A P.D.

TTR° 187.660# T9 L 3 - 212.87*# TCRT « 373. *00

DGAT .01*96. DG8P .058*3# DC R T - 10.20# ZCRT .28303

-.75257979* -.865*8120* 1.975*80377 2.172963661 -5 . 7660796*

ID VT T , K T/TC K G / M 3 HOL /L C ALCO PC N T DDS/DT F ( Z ) 70 .*2 193. 150 .51727 .710 . 0208 * .02083 .02 .00122 . 332 * 70 .*6 198.150 .53066 . 9*3 .02767 .02766 .03 .00152 . 8333

70 .50 203.150 . 5**05 1.233 .03617 .03615 . 0 * .00188 .836 8 70 . 5 * 208.150 . 557*5 1.587 . 0*658 . 0*657 .02 .00229 . 82*1

70 .57 212.875 .57010 1.992 . 058*5 . 058*3 . 02 . 0027 * . 8202

70 .57 212 . 97 * .57036 2.001 .05872 .05871 .02 .00275 . 822 * 70 .57 213.150 . 5708 * 2.017 .05917 .05919 -.03 .00277 . 800 * 70 .61 218.150 . 58*23 2 . 53 * . 07*35 . 07*33 .02 .00330 . 320 1 70 .65 223.150 .59762 3 . 1*7 . 0923 * .09231 .03 .00390 .8186

70 .68 228.150 .61101 3 . 86e . 113*9 . 113*8 .01 . 00*58 .8135

70 .71 233.150 . 62**0 *.711 . 1382 * .13819 .03 .00532 , ei37

70 . 7 * 238.150 .63779 5.689 .16695 .16685 . 06 .00615 . 81*0

70 .77 2 * 3.150 .65118 6.817 . 2000 * .19986 .09 .00707 .8137

70 .80 2 * 8.150 . 66*57 8.105 .23761 . 23765'’ .07 .00807 . 805 1 70 .82 253.150 .67796 9.570 .2 80 82 . 2P070 . 0 * .00917 .7970

70 . 8 * 258.150 .69135 11.233 .32960 . 329*8 . 0 * .01037 .7903

7 C .96 263.150 . 70 * 7 * 13.108 . 38*62 . 38*53 .02 .01167 .7830

70 .88 268.150 .71813 15.221 .**663 .** 6*1 .05 .01310 .7782

70 .90 273.150 .73152 17.585 .51600 .51570 .06 . 01 * 6 * .7715

70 .91 278.150 . 7**91 20.226 . 593*7 .59307 .07 .01633 . 76*7

70 .93 283.150 .75830 23.168 .67981 .67921 .09 .01816 . 7532

70 . 9 * 288.150 .77169 26. *39 .77580 . 77*89 .12 .02015 .7517

70 .95 293 .150 .78508 30.053 .881 83 .88097 .10 .02232 . 7*35

70 .96 298.150 . 798*7 3*. 080 1.00000 . 998*0 .16 . 02*69 . 738 2 70 .97 303.150 .81186 38. *95 1.12956 1.12829 .11 .02731 . 729 8 70 .97 30E.150 .82525 * 3 . 36 * 1 . 272*3 1.27192 . 0 * .03020 .7216

70 .98 313.150 . 83 86 * * 8.707 1 .*2918 1 .*3081 -.11 . 033*2 .7125

70 0.00 319.150 . 8520 * 5*. 537 1.60026 1.60682 -.*1 .03706 .7019

70 0.00 323.150 . 865*3 60.668 1.78603 1 . 80229 -.90 . 0*123 .6 896

9 .39 190. COC . 5088 * .589 . 01 728 .01727 .02 .00105 . 8 37 * 9 .*7 200.000 .53562 1 . 0*3 .03060 .03060 .01 .00165 . 822 5 9 .55 210.000 . 562*0 1.737 .05096 .05096 -.01 . 002*6 .. 3090

9 .62 220. CCO .58918

' 2 . 7*7 .08059 . oeo6 * -.05 .00352 .7970

9 .69 230.000 .61596 *.160 .12205 .12219 -.11 . 00 * 8 * .786 8 9 .75 2 * 0.000 . 6 * 27 * 6 * 07 * .17822 .17853 -.18 . 006*8 .7736

9 .81 250.000 .66952 8.602 .25239 . 2529 * -.22 . 008*6 . 7726

9 .85 2 * 0.000 .69630 11.873 . 3*839 . 3*909 -.20 . 0108 * . 7691

9 .89 270. CCO .72309 16 . 0*6 .*7083 .*7115 -.07 .01365 . 7 0 8 * 10 .38 lee. 750 . 505*9 . 5*5 .01599 .01600 -.08 .00099 .7063

10 .57 212.870 .57009 1.992 . 058 ** . 058*2 .03 . 0027 * . 325 1 95 .99 325.000 .87038 63.902 1.87506 1 .88012 -. 27 . 0*293 .7013

95 .99 330.000 .88377 71.650 2 . 102*0 2 . 1072e -.23 . 0*808 .7009

95 1 .00 335.000 .89716 80 . 38 * 2.35869 2.36267 -.17 . 05*27 . 702 * 95 1.00 3 * 0.000 .91055 90.322 2.65029 2 . 652 ** -.08 .06193 . 7063

95 1.00 3 * 5.000 . 9239 * 101.770 2.98621 2.98556 .02 .07176 .7128

95 1.00 350.000 .93733 115.187 3.37991 3.37571 .12 . 0

0 5 0 2 . 722 5 95 1.00 355.000 .95072 131 . 31 * 3.85312 3 . 8 * 5*5 .20 . 10*17 . 736 3 95 1 .00 360.000 . 96*11 151 .*90 *. **512 *.*3605 .20 . 13*79 . 7561

95 1.00 365.000 .97750 178.638 5 . 2*172 5.23790 .07 . 193*7 .785 8 95 1.00 370.000 .99089 222.319 6 . 523*3 6 . 5*170 -.28 . 370*7 . 339 9

N P - *8, RMSPCT • .123

52
Tao 1 e 4 Coefficients of equation of state for hydrogen sulfide

eonstate coeffs.* hydrogen sulfide

T TR p PTR P OGAT « DTP R • DPS /DTB

• 1 87660F D3 » TRIP « .231991E-01. p 9 L P =

. 149574E-01 , DG9P « .291360F+0P* DL 9 p -

* .51360E-02 mpa/K,

•212874E*03* TCRT « .1C1325E+00, PORT = .5«4329E-01> DC R T .278450E+O2* DC R T - OVAPP, RJ/MOL * 18.

.3734C0E+C3

.696291E+01 M 0 A ,

• 1 0200C E 02 8 0 L / L > .1C2C00E*02 M 0L /L »

I* • 2* FR « 2.030

Al • 1 . COOOOGC * BE o 7500000# GA • .5000000

DE O.OOCOOOO* FP * O.OOOCOOG* ET - 1.1000000

81 « .39825876573, BP * 0 . 0000 CO 00000 » 93 * .13290189038

Cl « -. 31070871113* C 2 * 0.30000000000* C3 * 0. OOOOCOOOOOO

D/DC M PL /

TSAT THETA PSAT 8 C .10 1.0200 299.017 266.817 2.0592 .39959 -.52866

.20 2 .0400 328.577 303.309 3.9641 .40357 -.43956

.30 3 . 0600 346.021 327.959 5.5526 .41022 -.35347

.40 4.0800 357.141 345.285 6.7636 .41952 -.27535

.50 5.1300 364.264 357.217 7.6757 .43148 -.20565

.60 6.1200 368 . 7?3 365.054 8.2914 . 4<t ‘-10 -.14533

.70 7.1400 371.369 369. 80 c 8.6602 . 46339 -.09455

.60 8.160C 372.762 372.297 8 .8666 .48331 -.05415

.90 9.1900 373.313 373.254 8.9496 .50591 -.02280

1.00 1C. 20CC 373.400 373.400 8.9629 .53116 0.00000

1.10 11.2200 373.319 373.260 8.9505 .55907 .01527

1.20 12.24CO 372.816 372.350 8.9746 .58964 .02420

1.30 13.2600 371.577 370 . C13 6.6909 .62286 .02 903

1.40 14.2600 369.360 365.683 8.3711 .65874 . 02799

1 .50 15.3000 365.994 358.903 7.9048 .69729 .0252?

1.80 16.3200 361.328 349.333 7.2974 .73849 .02073

1.70 1^.3400 355.310 336 . 764 6.5679 .78234 .01539

1.80 1 8.3600 347.892 321.129 5.7459 .82886 .00984

1.90 19.3900 339.016 302.508 4.8677 .87803 .00460

2.00 20.4000 328.699 241.139 3.9739 . 9 2 9 P6 0.00000

2.10 21.4200 316.933 257.409 3.1063 .98435 -.00377

2.20 22. 4400 303.734 231 . 848 2.3053 1.04150 -.00663

2.30 23.4600 289.139 205.107 1 .605 9 1.10131 -.00860

2 .40 24.4800 273.212 177.928 1.0342 1.16377 -.00977

2.50 25.5000 256.058 151.096 .6033 1.22889 -.01024

2.60 26.5200 237.828 125.363 .3100 1.29667 -.01016

2.70 27.5400 218.722 101.488 .1351 1.36711 -.00966

2.30 28. 56C0 199.984 79.976 . 0474 1 . 44021 -.00999

2.90 29.5800 178.882 61.235 .0124 1.51596 -.00793

53
Table

5.

Calculated

critical

isotherm

for

hydroyen

sulfide

cj an ro o CO CD CJ o 03 rH o CO an c- r- o DO 4 O' O o 4 X 4 X o DJ 4 X O' X o r-H rH 4 X p^ rH 4 X — 4 O 4 rH CD c- ao -H 03 sO o ro 03 03 4 r-H an ro DO DO o 03 x> CO CO X o co r-H 4 O' o 4 rH o rH X p* rH X o an an X p- p- ao O' rH C0 4 o 4 O o ro >o O' DO 03 o rH X X p^ cn o rH X o p«- 4 X rH o O' CD N X X X

"V. o O o o o O o rH rH rH rH co co CO cn an CO an o o o 4 CO p'- X 4 X co DO rH r-H f-H rH rH o o o o o o

Cl •< o o o o o o o o o o o O o O O O o rH DO rH o xT ro rH o o o o o o o o o o o o o o o o o

CO CL O z: 1 1 1 i # ( 1 1 1 I i 1 i i i 1 1 1 rH

1 o rH

o 4 H ao 03 CO O' r-H 03 4 4 O' OD O' OD CD 4 rH rH X X r- o X o X c- 4 o X o X X X O' X p~ o o

o 4 o 03 >r O CO o co O' r- OD O CO fn- an P- 4 xO o c- X CO xO co X 4 X OD rH rH X r- rH X O' o O' ao o 4

V, •< x p- CO o co >J* an o an an 03 O O 4 o CJ xO CO O' rH an CO CO X o rH rH xO o O' 4 X o o o O' o X o o

CL Cl 4 ro o CO co c- a> an 03 CJ co xO co O' ro an an xO co 4 o X o o O' 4 4 OD X X X X X CJ rH o p^ X p- o ZT m CJ rH O' fn- rH CD 4 O an O' cn an fn- OD an o CO CO xO o xO 4 xO o X X X O' 4 r-H o rH 4 CD X X

CD X >5- rH o an CJ O CD an co O 4 rH CD an DJ X CO O' an CO o D- X X co o O' X c- p- r^- p- p- p- OD o

r- GD CT o o rH co CO 4 4 an 03 ac O' O' o r-H rH co co ro 4 X X xO p^ cc O' O' o rH CJ X 4 X X OD o

CO CO CO 4 xT >T 4 4 4 4 4 4 4 4 4 an an an un an an X X X X X O' X X X X X X X X X X X X H rH H rH r-H rH rH rH rH rH rH rH rH rH rH rH rH f-H rH rH rH rH r-H rH rH f-H f-H f-H rH rH s=-H rH f-H rH rH rH rH rH rH f-H

o ~J CO o o an a co CJ 03 03 an CO c- 4 OD an CJ o an 4 xO o O' X X X X X X O' X CO o X X X X CJ X rH DJ X o O x o p- 4 co O' CJ CO CJ rH OD CO 03 xO rH rH f-H rH 4 o an X rH co xO 4 rH o X X X OD rH o rH X rH X f-H

^s. X O o p- X an 03 xC c- O' CJ rH CC an CO K- xO r-H C- o xO 03 c- rH CO rH o c- CJ r- X CJ ao O' r^- ac O' X o o

o m an CO CD an nT an c- CD o O' Cl rH CO CO CJ an rH X CO o rH o o r- 03 rH xO X o 4 O' X X rH an rH CD X o an 4 X O co rH rH o an cn O 4 O an 03 O' O xT 4 O o o X p^ CJ cn X c—

p^ OD c- o X o r- or »-H O' pi f-H 4

i O CP co ao o 0"1 ac. !fn on co CJ an CJ rH CO c- 4 rH O a o o o rH 4 X 4 X 4 O' X CJ o 4 X o X X X rH CD

*3 CD H x O' O an CO O CD O' 4 CO CJ rH o o O o o o o o o o o f-H CJ X 4 X O' CJ X O' X O' X CJ o CD

CL 4 4 co CJ CO co rH rH rH O o O C; o O o o o o o o o o o o o o o o o o o f-H rH rH DO co X 4 X X

Z~ o o o o o O O o O o o o O O O o o o o o o

fl o o o o o o o o o o o o o o G o o o o o

g X H an O' an CO ao O' o CO an u—

co rH CO o CO c- o o o 4 o o CJ o X ac o p^ f-H X o o Co 4 X o 4 Co

CL 0D o ao o an CO an ao o 03 un o ao an 4 ro CD o o o rH c- CP. X rH 4 4 O' 4 4 P- 4 o X 4 X O' 4

>*. O o ro an fn ac Cs» o co co CO 4 CD ac 4 r- O' O' o o G o o rv X CJ cv cc rH 4 O' X 4 rH co o o p 4 cc

CL 4 cc O CD ro 03 03 an CO c- rH 4 03 r- CD O' O' O' O' e o o o o G o C—

CJ X X o X O' D- p^ o 4 DJ X O' o x CD H CJ >J- an >c> c- ac CD O' O O' O' O' O' o o o o o o o c o o o c o o o rH rH CJ X 4 X CD o DJ X

CD CD O' o- O' O' O' O' O O' o O' a O' O' O' o o o o o o o G o o o c G c o o G o o o G o rH rH rH o O O' O' O' O' o O' o O' O' O' O' O' O' O' O' o o o o o o o o o o o o o o o o o G o o o o c o

• o O O' o O' o* o O' O' O' O' o o o O' O' O' o o o o o o o o o o o o o o o o o o o o o c o c

a O O' o O' o O' O' o O' O' o O' O' O' O' o o o o o o o G o o o o c o o o G o o o o o o o G

Q. 4 rH rH rH f-H f-H rH rH rH rH rH f-H f-H f-H f-H rH f-H rH rH rH rH f-H Z* Q-z: Q —

o 0L o cc O' o cr rH 4 C- c- XT c- an rH co an CD CO aN o a X X X CJ o 4 4 X X X 0—

X o rH p f— CJ O a O a o On CO ao rH ro o o 03 co un <V c- 03 fO Co O' o an co o ro X 4 X o X o 4 r- rH X 4 o p- X p- f-H ac ac O r- T O' r-H an P- rH co o O' O' Cx 0D o Cr CD o S*H X rr D- o Co co CO c- X O' X o o 4 c- c X X X co f-H X X X

CO x on 'v. x p- rH co o CD c xp C- o o cr. xT 4 03 cr o o xO O o X xO xO O' rH X X 4 an 4 CJ X o cc X rH rH X O' CD x co o _J x P- an CP f\.’ co 4 CJ O' xO 03 CO C- cn 4 m xO xC DJ o X rH X xT o X X CJ CD rH X X DJ X (V rH O' p- cc x.

O' xc g 1 CD O 4 03 m 03 IT a CO o 03 O' o ao O' O 4 o X o CO r- o O' rH rH f"- G X' X CJ r- rH G X o rH X X

• H <X H on ro rH co an o 03 4 cn 4 OD CO o ao X c- 4 o o o 4 o r^- r- X o a. o ac r- o X CD 4 f-H f—

f-H X

CD • Q. ao 4 H ac an co O' c- 4 CJ O au xT an CO co f-H rH O o o o o f—

r-H cv X X X CD O' r-H X X ac o X X O' cv X

B B ro ro CO co (V CJ rH H rH rH r-H C O O O O o o o o o o o o o o G o o o o rH rH rH rH CJ DJ PI c X X

O —

1 1 1 1 ! t i 1 1 1 1 1 1 1 1 t t 1 1 t a o G x h r-l o rH r—4 O' 03 rH an CJ 4 4 rH CD co 4 CO xO o o CJ o o X o 4 o cv O' XI 4 X 4 f-H rH ac p^ X. CD

•> a CL 4 p- 03 o o <r o O an r- CJ an 4 CD C- CO O cn an o xC o X c- X rH o a- X f-H xr XT O' X X o D\J X p

—

j

o "**, an p- an an 1— (Nj CD fn- ac r-H 03 r-» C- CO o 0D f"- CO co X CD CD CV co O' 4 X X X c- CD X r- CD DO CJ O' X p- a X

on cr CJ P- C CO O CO o 03 O' CO 4 CD 4 CO an 4 X O' o O' X 4 X cn X o cr p- c- X CC, ar o X p- PJ rH X

—

•» a H CO o P- CO an r- r- 03 ro O' an O co a> I'' ao o o O' o o o o X c- X X o XT o 4 X- o o CD X oo o f—

G an an O' O Cj On >r XT 03 c- ao CD o O' O' o o o c o O' o o o o O' O' CL ar X r X X 4 r (V rH O' a X

S' CP OC c

O a o O o O' O' O' O' O' O' O' o- o o o O' c O' o o a o o O' o o O' o O' o O' O' o o a X a m a O' o a O' o O' O' o O' O' o O' O' O' O' o o o o G o o o O o o O' o o O' o O' o O' O' o o o o O' O co o o O o o- o a o o O' O' o O' o O' O' o o o O' o o o o O' o o O' o o O' o O' O' O' o o o O' o O'

10

. rH

• rH

B o _J x 4 O' 03 an un xl- CO o on c- rH c- <\) O' c- o xO o o rH cc X X rH o X XT o CJ o XT r-H p^- rH DJ X 4 X X

B o O 4 Cu o o r- ac O' CJ 03 03 rH CD cr rH ar cr an o r-H o an r- X c- o xC cv <\ X f-J O' 4 Do X (P o Cj X cv

»- v. X on >c cc p- Co X* CJ o 03 o or O' O' ro co Co G CP. CJ c X 4 r- o X c DO f-H r- c- o r— cv 4 O' 4 4 X o X O G on "n. r^- o C H o IT o r-> xT 0

" CO cr C- o ar co CO X 4 xO o c CJ O' f-H r-H o X cv» c X f-H X DJ X f-H »—• X G o o V* _J CO r-H un co •4- 03 IT c- c- O (M rH <v 03 X DO X o xj X O' 4 r- X X f-H «—

4 X rH r-H rH X cv ac X Cl X

on O i CO p an 4 r- a^ O ro o: o r- O' 0. rH un o O C xT X o X O' o o 4 X CJ O' r—

X X o X p- 4 X o X X o •> a -r CC co (V CJ ro an c- o LO o O' 4 O xC O an o C\J G X X o X X f-H X o XT' O' X p- o X X X >C * O f-H CL 03 an an 03 ac rH 03 rH cc an 4 4 an X DO xi3 CP O o o cn xT rH X X DO X 4 o 4 o X 4 cv f-H rH p

an CJ o ao 0. xT co rH O' ac >c un 4 CO cv rH rH o O O o o o o f-H rH CJ X 4 X X c- O' o CJ X X p- O' f-H X

O

4 Q

CO co CO rH rH rH rH rH 1 1 1 8 1 1 1 1 1 1 • • rH

1 1 rH1

f-H

1 1 X

1 X

1 x

• G G cr r-i G ro CO o CD CO co O Cw co XT xO 4 o ao f- IT r-H G 4 a u> o o f-H X c ac ro u « o p- 4 cv 4 X Pi p an p- »- in p 03 03 CJ 03 4 4 CJ rv O rH rH 03 CJ 4 c CV X- e O' rH O' O' rH X X c> CD c X a< o G 4 o a< o X m UJ ro 4 03 ao cr rH an 03 an 4 4 c- 4 fn- r- r- rH r- O* o O' o p"- X a o o IT r- cv o O' O' r- DJ 4 O' cr X

X on on a p rc ao 03 rv a

-

' an ac 03 ro ac CJ an c- O O' O' o O' O' O' D- X CJ o cn O' G O' X Cl X 4 cv p- o rH — »— an cr CJ an fn O' rH CO 4 an o: ac ao O O' O' o a O' o O' O' O' O' O' a CD cr r* X x. 4 X cv o ao X cr r—

cr p D- a ao a a O' O' O' O' O' O' O' O' O a o o O' O' o o O' O' O' o o O' o a o o o O' o O' cc ar a a p- g 1— a o O O' O' O' O' O' O' O' r> o O O' O' O' o o O' o o o O' O' O' O' O' O' o O' o o o O' O' o O' o o a o

*— •a O' O' O' O' o O' O' O' O' O' O cr o O' O' o o o O' o o o O' O' O' o O' O' o O' o o o O' O' O' o O' o O' O' o o o o o O' O' O' O' O' O' O' O' O' O' o o o O' o o

rH o cr O' O' O' o O' o O' o o o o O' o o o o o o

g o an o an o a- o un o an o an o XT' o a> o an o an o an o X o X o X o X o XT o X e X o Xi G IT c o o o rH rH Co co CO co 4 4 ID O' xT o. r-. X X' O' O' o o f-H rH cv cv X X 4 4 O' X X X p- p- a or O' o o

o a o O' O' o O' O O' O' a O' a O' O' O' o O' a O' o o o o o o o o o o o o o o c e o o G G —

f-H r-H rH rH f-H f-H rH f-H f-H rH r-H r-H f-H rH f-H rH rH rH rH r-H rH

54
6. Comparisons for P-p-T data for hydrogen sulfide.

MVORDGEN sulfide pvt DAT 4 vs. eonstate

<1)REAMER» ( 2

)

l EW I S # ( 3

)

R AU» (4)STRATY

ID p N WT T,K HOL/L c alcd D , PC T P » H P A c alcd P > PC T

1 1 1.000 277.594 .0444 .0443 .17 .1013 .1015 -.17

1 2 1.000 277.594 .0607 .0605 .22 .1379 .1382 -.22

1 3 1.000 277.594 .0917 .0914 .30 .2068 .2074 -.29

1 4 1.000 277.594 .1232 .1228 .36 .2758 . 2768 -.35

1

c 1.000 277.594 .1552 .1546 .39 .3447 .3460 -.33

1 6 1.000 277.594 .1878 .1869 .45 .4137 .4155 -.43

1 7 0.000 277.594 .2547 . 2532 .58 .5516 .5546 -.54

1 e 0.000 277.594 . 3243 .3217 . 79 .6895 .6945 -.72

1 9 0.000 277.594 .4150 .4109 .99 .8618 . 8695 -. p « 1 10 0.000 277.594 .5101 .5046 1.10 1.0342 1.0442 -.95

1 1

1 .000 277.594 24.2300 24.2194 .04 1.3790 1.5600 - 11.61

1 12 1.000 277.594 24.2704 24.2596 .04 2.0684 2.2564 - 8.33

1 13 1.000 277.594 24.3109 24.2991 .05 2.7579 2.9651 - 6.99

1 1 * 1.000 277.594 24.3590 24.3382 .09 3.4474 3.8188 - 9.73

1 15 l.ooo 277.594 24.4072 24.3767 .13 4.1369 4.6904 - 11.80

1 15 1.000 277.594 24.4856 24.4522 .14 5.5158 6.1368 - 10.1

1 17 1.000 277.594 24 . 5644 24.5258 .16 6.8948 7.6321 - 9.66

1 1 P l.OCC 277.594 24 .6514 24.6153 . 1 5 8.6184 9.3275 - 7.60

1 19 1 .000 277.594 24.7428 24.7022 .16 10.3421 11.1632 -7.36

1 20 1 .000 277.594 24.8271 24.7867 .16 12.0658 12.9077 - 6.52

1 21 1.000 277.594 24.9121 24.8689 .17 13.7895 14.7130 - 6.2 3 1 2 ? l.OCC 277.594 24.9937 24 , 949 C .18 15.5132 16.4949 - 5.95

1 23 1.000 277.594 25.0719 25.0271 .18 17.2369 18.2466 - 5.53

1 24 1.000 277.594 25.1546 25. 1033 . 20 18 . 9606 20.1456 - 5.38

1 25 1.000 277.594 25.2339 25.1777 .22 20.6843 22.0121 - 6.03

1 26 1.000 277.594 25.3899 25.3216 .27 24.1317 25.8215 - 6.54

1 27 1.000 277.594 25.5356 25.4594 .30 27.5790 29.5460 - 6.66

1 28 1.000 277. 594 25.6583 25.5916 .26 31.0264 32.8103 - 5.44

1 2 <? 1.000 277.594 25.7822 25.7191 .25 34 .473 8 36.2274 1 4

“

CD 4

*

1 30 1.000 277.594 26.0845 25.9606 .48 41.3685 45.0927 - 8.26

1 31 1.000 277.594 26.3245 26.1866 .53 48.2633 52.6873 - 8.40

1 32 1.000 277.594 26.5338 26.3993 .51 55.1581 59.7268 - 7.65

1 33 1.000 277.594 26.7019 26.6005 .38 62.0528 65.6711 - 5.51

1 34 1.000 277.594 26.8091 26.7915 .07 68.9476 69.6035 -.94

1 35 1.000 310.928 .0395 .0395 .06 .1013 .1014 -.09

1 36 1.000 310.928 .0539 .0538 .04 .1379 .1380 -.04

1 37 1.000 310. 92e .0812 .0812 .03 .2068 .2069 -.03

1 3 P 1.000 310 . 9 ?« .1088 .1088 .05 .275 8 .2759 -.05

1 39 1.000 310.928 .1367 .1367 .01 . 3447 .3448 -.01

1 40 1.000 310.928 .1650 .1649 .07 .4137 . 414C -.07

1 41 1.000 310.928 .2222 .2222 .01 .5516 .5516 -.01

1 42 1.000 310.928 , 2«05 .2 807 -.06 .6895 .6891 .06

1 43 1.000 310.928 .3552 . 3558 -.17 . 8618 . 8605 .15

1 44 1.000 310.928 .4329 . 4330 -.02 1.0342 1.0340 .02

1 45 1.000 310 . 92P .5937 . 5947 -.17 1 . 3790 1.3768 .15

1 46 l.OCO 310.928 .9523 .9539 -.16 2.0684 2.0657 .13

1 47 1 .000 310.928 21.9071 21.9016 .02 2.7579 2.8107 - 1.83

1 48 1.000 310.928 21.9702 21.9720 -.01 3.4474 3.4295 .52

1 49 1.000 310.928 22.0336 22.0404 -.03 4.1369 4.0682 1 .69

1 50 1.000 310.928 22.1555 22.1717 -.07 5.5158 5.3419 3.26

1 51 1.000 310.928 22.2757 22.2966 -.09 6.8948 6.6591 3.84

1 52 1.000 310.928 22.4191 22.4447 -.11 8 .6184 8.3140 3.66

1 53 1.000 310.928 22.5644 22.5849 -.09 10.3421 10.0847 2.65

1 54 1.000 310.928 22.6987 22.7181 -.09 12.0658 11.8089 2.18

1 55 1.000 310.928 22.8248 22.8453 -.09 13.7805 13.5072 2.09

1 56 1.000 310.928 22.9491 22 . 9668 -.08 15.5132 1 5 .

5 6

q 1 . 65

1 57 1.000 310.928 23.0647 23.0835 -.08 17.2369 16.9563 1.66

55
Table 6 Conti nued

HYDROGEN SULFIDE PVT DATA VS . FONSTATE

( l ) REAMER , ( 2UEWIS , ( 3 ) R A U » ( 4JSTRATY

ID PN WT T,K MOL/L CALCC D » PC

P , 1PA C ALCD P * »CT

1 58 l.OOC 310.928 23.1816 23.1956 -.06 18.9606 18.7415 1.17

1 59 1.000 310.929 23.2894 23.3036 -.06 20.6843 20.4549 1 .12

1 60 1.000 310.928 23. 5082 23.5085 -.00 24.1317 24.1256 .02

1 61 1.000 310.928 23.7100 23.7006 .04 27.5790 27.7535 -.63

1 62 1.000 310.928 23.8975 23.8815 .07 31 .0264 31.3396 - 1.00

1 63 1.000 310.928 24.0771 24.0528 .10 34.4738 34.9779 -1.44

1 64 1.000 310.928 24.3924 24.3705 .09 41.3685 41.8675 - 1.19

1 65 1.000 310.928 24.6704 24.6608 .04 48.2633 48.4995 -.49

1 66 1.000 310.928 24.9315 24.9287 .01 5*. 1581 55.2308 -.13

1 67 1.000 310.928 25.1467 25.1779 -.12 62.0528 61.1637 1 .45

1 68 1.000 310.928 25.3457 25.4112 -.26 68.9476 66.9676 2.96

1 69 1.000 344.261 .0356 .0356 .01 .1013 .1013 -.01

1 70 1.000 344.261 .0485 .0485 -.00 .1379 .1379 .00

1 71 1 .000 344.261 .0730 .0730 -.04 .2068 .2068 .04

1 72 1.000 344.261 .0977 .0978 -.02 . 2758 . 2757 .02

1 73 1.000 344.261 .1226 .1227 -.08 .3447 . 344 5 .08

1 74 l.OOC 344.261 .1476 .1477 -.07 .4137 .4134 .07

1 75 1.000 344.261 .1982 .1985 -.13 .5516 .5509 .13

1 76 1.000 344. 261 .2495 . 2501 -.22 .6895 . 6880 .21

1 77 1.000 344.261 .3147 .3156 -.29 .8618 . 8595 .20

1 78 1.000 344.261 .3814 .3 82 5 -.28 1.0342 1.0315 .26

1 79 1.000 344.261 .5184 .5201 -.33 1 .3790 1.3747 .31

1 80 1.000 344.261 .8107 .8132 -.31 2.0684 2.0627 .28

1 81 1.000 344.261 1.1328 1 .1346 -.15 2.7579 2.7544 .13

1 8 ? 1.000 344.261 1.4971 1.4936 .23 3.4474 3.4536 -.13

1 83 1.000 344.261 1.9230 1.9072 .83 4.1369 4.1610 -.58

1 84 1.000 344.261 18.7044 18.8354 -.70 5.5158 5.0461 9.31

1 85 1 .000 344.261 19.0153 19.1740 -.83 6.8948 6.2178 10.89

1 86 1.000 344.261 19.3787 19.5296 -.77 8.6184 7.8508 9.78

1 97 1.000 344.261 19.6811 19.8343 -.77 10.3421 9.4459 9.49

1 88 1.000 344. 261 19.9306 20.1029 -.61 12.0658 11.2565 7.19

1 89 1.000 344.261 20.2535 20.3441 -.45 13.7895 13.1218 5.09

1 90 1.000 344.261 20 .4552 20.5638 -.53 15.5132 14.6423 5.95

1 91 1.000 344.261 20.6530 20.7661 -.54 17.2369 16.2566 6.03

1 92 1.000 344.261 20.8357 20.9539 -.56 18.9606 17.8612 6.16

1 93 1.000 344.261 21.0051 21.1295 -.59 20.6843 19.4513 6.34

1 94 1.000 344.261 21.3153 21.4505 -.63 24.1317 22.6322 6.63

1 95 1.000 344.261 21.5999 21.7391 -.64 27.5790 25.8739 6.59

1 96 1.000 344.261 21.8921 22.0020 -.50 31.0264 29.5490 5.00

1 97 1.000 344.261 22.1311 22.2441 -.51 34.4738 32.8304 5.01

1 99 1.000 344.261 22.5612 22.6788 -.52 41.3685 39.4111 4.97

1 99 1.000 344.261 22.9327 23.0623 -.56 48.2633 45 . 8442 5.28

1 100 1.000 344.261 23.2996 23.4067 -.46 55.1581 52.9399 4.19

1 101 1.000 344.261 23.6261 23.7201 -.40 62.0528 59.91 89 3.56

1 102 1.000 344.261 23.9690 24.0084 -.16 68.9476 67.9722 1.44

1 103 1.000 377.594 .0324 .0324 -.02 .1013 .1013 .02

1 104 1.000 377.594 .0441 . 0442 -.04 .1379 .1378 .04

1 105 1.000 377.594 .0664 .0664 -.06 .2068 .2067 .06

1 106 1.000 377.594 .0887 . 0888 -.09 .2758 . 2756 .09

1 107 1.000 377.594 .1112 .1113 -.10 .3447 .3444 .10

1 10 8 1.000 377.594 .1338 .1340 -.14 .4137 .4131 .13

1 109 1.000 377.594 .1794 .1797 -.18 .5516 . 5506 .18

1 110 l.OCO 377.594 .2253 .2259 -.28 .6895 .6876 .27

1 111 1.000 377.594 .2 835 . 2844 -.33 .8618 .8591 .32

1 112 1.000 377. 594 .3430 .3438 -. 22 1 .0342 1.0320 .21

1 113 1.000 377.594 .4630 .4649 -.42 1.3790 1.3734 .40

1 114 0.000 377.594 . 746 ] .7176 3.97 2.0684 2.1438 - 3.51

1 115 1.000 377.594 .9833 .9854 -.21 2.7579 2 . 7*28 .19

56
Table 6 Continued

HYDROGEN SULFIDE PVT DATA VS. EQNSTATE

(l)REAMER, (2UEWIS# (3)RAU> ( < ) S T R A T Y

10 PN WT T»K MOL/L C ALCD 0, PC T P, MPA C A L C 9 p»°CT

1 116 1.000 377.594 1.2713 1.2707 .05 3.4474 3. 4 A 8 8 -.04

1 117 1.000 377.594 1 .582 9 1.5772 .36 4.1369 4.1491 -.29

1 118 1.000 377.594 2.3015 2.2781 1.03 5.5158 5.5571 -.74

1 119 1.000 377.594 3.2361 3.1773 1 . 85 6.8948 6.9704 -1 .09

1 120 1.000 377.594 5.2008 5.1026 1.92 8.6184 8.6718 -.61

1 121 1.000 377.59*, 13 .9899 13.9092 .56 10.3421 10.3861 -.42

1 122 1.000 377.594 15.6796 15.6889 -.06 12.0658 12.0518 .1?

1 123 1.000 377.594 16.5463 16 . 5687 -.14 13.7895 13.7356 .39

1 124 1.000 377.594 17.1522 17.1845 -.19 15.5132 15.4104 .67

1 12 5 1.000 377.594 17.6434 17.6675 -.14 17.2369 17.1424 .55

1 126 l.OOC 377.594 18.0185 18.0689 -.28 18 . 9606 18.7284 1.24

1 127 1 .000 377. 59*. 18.3551 18.4148 -.32 20.6843 20.3699 1.54

1 129 1.000 377.594 18.9165 18.9938 -.41 24.1317 23.6275 2.13

1 129 1.000 377.594 19.3811 19.4718 -.47 27.5790 26.8792 2.60

1 130 1.000 377.594 19.7881 19.8817 -.47 31.0264 30.1961 2.75

1 131 1 .000 377.594 20.1617 20.2422 -.40 34.4738 33.6679 2.39

1 132 1.000 377.594 20.7493 20.8580 -.52 41.3685 40.0529 3.28

1 133 1.000 377.594 21.2531 21.3753 -.57 48.2633 46.5363 3.71

1 134 1.000 377.594 21.7199 21.8239 -.48 55.1581 53.4794 3.14

1 135 1 .000 377.594 22.1402 22.2214 -.37 62 .05 2 8 60.5816 2 .43

1 136 1.000 377.594 22.5676 22.579? -.05 68.9476 68.7109 .34

1 137 1 .000 410.928 .0297 .0297 -.04 .1013 .1013 .04

1 13 « 1.000 410.928 .0405 .0405 -.04 .1379 .1378 .04

1 139 1.000 410.928 .0609 .0609 -.08 . 2068 .2067 .08

1 140 1.000 410.928 .0814 .0814 -.08 . 275 8 . 2756 .08

1 141 1 .000 410.928 .1019 .1020 -.11 . 3447 . 3444 .10

1 142 l.OOC 410.928 .1225 .1227 -.18 .4137 .4130 .17

1 143 1.000 410.928 . 1640 .1643 -.21 .5516 . 5504 .21

1 144 1.000 410.928 . 2059 .2063 -.20 .6895 . 68 82 .19

1 145 1.000 410.928 .25 84 .2593 -.36 .8618 . 8588 .35

1 146 1.000 410.928 .3116 .3128 -.38 1.0342 1.0304 .37

1 147 1.000 410.928 .4193 .4216 -.54 1.3790 1.3719 .52

1 149 0.000 410.929 .6955 .6457 7.71 2.0684 2.2180 -6.74

1 149 1.000 410.928 .8763 . 8791 -.32 2.7579 2.7499 .29

1 1 5 C l.OCC 410.928 1.1202 1.1223 -.19 3.4474 3.4416 .17

1 151 1.000 410.928 1.3773 1.3765 .06 4.1369 4.1391 -.05

1 152 1.000 410.928 1 .9369 1.9249 .63 5.5158 5.5445 -.52

1 153 1.000 410.928 2.5753 2.5439 1.23 6.8948 6.9597 -.93

1 154 l.OCC 410.028 3.5361 3.4704 1.89 8.6184 8.7260 -1.23

1 155 1.000 410.928 4.7533 4.6886 1.38 10.3421 10.4191 -.74

1 156 1.000 410.929 6.4202 6.4575 -.58 12.0658 12.0360 .25

1 157 1.000 410.928 8.6821 8.9455 -2.94 13.7895 13.6149 1 .28

1 15 8 1.000 410.928 11,0472 11 .2058 -1.42 15.5132 15.3723 .92

1 159 1.000 410.928 12.7739 12.8059 -.25 17 .2369 17.1954 .24

1 160 1.000 410.928 13.8929 13.9282 -.25 18 . 960 * 18.8969 . 34

1 161 1.000 410.928 14 .7093 14.7606 -.35 20.6843 20.5643 .59

1 162 l.OOC 410.928 15.9229 15.9526 -.19 24.1317 24.0283 .43

1 163 1.000 410.928 16 .7820 16.8063 -.14 27.5790 27.4674 .41

1 164 1.000 410.928 17.4493 17.4743 -.14 31.0264 30.8840 . 46

1 16 5 1.000 410.928 17.9983 18.0255 -.15 34.4738 34.2895 .54

1 166 l.OOC 410.928 18.8741 18.9086 -.18 41.3685 41 .0640 .74

1 167 1.000 410.928 19.5419 19.6078 -.34 48.2633 47.5518 1.50

1 16 8 1.000 410.929 20.1363 20.1903 -.27 55.1541 54.4709 1.26

1 16 9 1 .000 410.928 20.682 3 20.6917 -.05 62.0528 61.9157 • 22

1 17 0 1.000 410.928 21.1884 21.1331 .26 68.9476 69.8704 -1 .32

1 171 1.000 444.261 .0275 .0275 -.03 .1013 .1013 • 0 3

1 172 1.000 444.261 .0374 .0375 -.03 .1379 .1378 . 0 3

1 173 1.000 444.261 .0562 .0563 -.07 .7068 • 2067 .07

57
T a b 1 e 6 Conti nued

HYDROGEN SULFIDE PVT DATA VS. EONSTATE

(l)REAMER, ( 2 ) L E WI S» (3)RAU, <*)STRATY

ID P h WT T,K HOI /L CALCD D, PC T P, HP A CALCD P»PCT

1 17* 1.000 ***.261 .0751 .0752 -.11 .2758 .2755 .11

1 175 1.000 ***.261 .09*0 .09*1 -.15 .3**7 .3**2 .1*

1 176 1.000 ***.261 .1130 .1132 -.18 .*137 .*129 .18

1 177 1.000 ***.261 .1511 .151* -.21 .5516 .5505 .20

1 1 7 P 1.000 ***.261 .1893 .1899 -.32 .6695 .6873 .31

1 179 1.000 *** .261 .2 377 . 2385 -.33 .6618 . 6590 .33

1 180 1.000 ***.261 .2866 . 28 7* -.28 1.03*2 1.031* .27

1 191 1.000 *** .261 . 3 85 1 . 3863 -.33 1.3790 1.37*6 .32

1 182 1 .000 ***.261 . 5859 .5 e 8 e -.*9 2.068* 2.0588 .*7

1 183 1.000 ***.261 .793 8 . 7972 -.*3 2 .7579 2.7*66 • ^ D

1 18* 1.000 ***. 261 1.0087 1.0117 -.30 3 .**7* 3. *379 .28

1 165 1.000 ***.261 1.2312 1.2326 -.13 *.1369 *.1320 .12

1 186 1.000 ***.261 1.7005 1.6971 .20 5.5158 5.5256 -.18

1 197 1.000 *** .261 2.209* 2.1967 .58 6.69*8 6.9266 -.*9

1 138 1.000 ***.261 2 . 912* 2.8863 .91 8.618* 8 . 6798 -.71

1 189 1 . 000 *** .261 3.7080 3.67*2 .92 10.3*21 10. *105 -.66

1 190 1.000 ***.261 *.6296 *.5970 .71 12.0656 12.1216 -.*6

1 191 1.000 *** .261 5.6823 5.69*1 -.21 13.7895 13.772* .12

1 192 1 .000 *** .261 6.8*8* 6.9761 -1 .82 15.5132 15 .

e 1* 1.05

1 193 1.000 ***.261 8.1271 8.3537 -2.71 17.2369 16.9530 1.67

1 1 9* 1 .coo ***.261 9.3730 9.6591 -2.96 18.9606 18.56*5 2.13

1 195 1 .000 ***.261 10.5*5* 10.7938 -2.30 20.68*3 20.2832 1.98

1 196 1 .000 ***. 261 12. *75* 12.5852 -.87 2*. 1317 23.8853 1.03

1 197 1.000 ***.261 13 .832 9 13.8939 -.** 27.5790 27.3939 .66

1 1 9 p 1.000 ***.261 1* . 831

1* . 8686 -.38 31 .026* 30.6058 . 72

1 199 1 .000 *** .261 15.6*30 15.6802 -.2* 3*. *736 3*. 2956 .52

1 200 1 . ooc ***.261 16.8793 16.8915 -.07 *1.3685 *1.2873 . 20

1 201 1.000 ***.261 17. POO ? 17.8060 -.03 *8.2633 *8.21*6 .10

1 20? 1 .coo ***.261 1 8 , 5 1 P 5 1 8. 8992 -.13 55 . 1 5 e 1 5* .91*0 .**

1 203 1.000 ***.261 19.1379 19.1601 -.1? 62.0528 61 .786* .*3

1 ’0* 1.000 ***. 261 19.727? 19.6936 . 17 68 .9*76 69. *132 -.67

ND > 20*, DNRMSPCT - .593, DNTPNDPCT « -. 119 , PHEANPCT 2.023

58
Table 6 Continued

HYr>enGEN SULFIDE PVT DATA VS. EONSTATE

(l)PEAYEP, ( 2) LEWIS# ( 3 ) R A U > ( A ) STR AT

ID P N WT T,K MOL /L CALCD D, PC T P, MP A CALCD P> p CT

A 2 0 5 1 .000 A93 .000 . 0 5 A 0 . 0 5 A 1 -.06 .220 8 . 2207 .06

A 206 1.000 A93.000 .0869 . 0870 -.11 . 3 5 A 1 . 3538 .11

A 207 1.000 A93 .000 .1395 .1398 -.18 .5670 . 666C .17

A 708 1.000 A93 .000 .1529 .1532 -•;9 .6207 .6195 .19

A 209 1.000 A93.000 . 1 80 A .1008 -.22 .7310 . 7? 9 A .22

A 210 1.000 A 9 3 . 000 . 2 2 A 2 . 2 2 A 8 -.26 . 90 6 A . 90AC .26

A 211 1.000 A 9 3 . 000 , 2 A 5 6 . 2 A6 3 -.28 . 991 A . 9e87 .27

A 212 1.000 A 93 . 000 .2 898 .2907 -.30 1.1665 1.1630 .30

A 213 1.000 A93.000 .3603 .3615 -.33 1 .AA38 1 . A392 .32

A 2 1 A 1.000 A93.000 . 3 9A6 . 3959 -.33 1.5781 1.5729 .33

A 21 S 1.000 A 9 3 . 000 .A656 . A6 7 1 -.33 1.8536 1.0A76 .32

A 216 1.000 A93 .000 .5788 . 5006 -.30 2 .2 881 2.2815 .29

A 217 1.000 A93. 000 . 63A0 .6358 -.28 2. A978 2 . A 9 1 2 .27

A 21 8 1.000 A93.000 , 7 A 8 1 . 7 A96 -.20 2.9263 2.9207 .19

A 319 1.000 A93.000 .9301 . 9305 -.OA 3.5975 3.5960 .OA

A 220 1.000 A93 .000 1.0137 1.0182 .05 3.9106 3.9203 -.OA

A 221 1 .000 A93.000 1.2019 1. 199C .25 A. 5718 A. 50 2<> -.23

A 22 2 1.000 A 93 .000 1 . A9A6 1. A860 .58 5 . 5 8 A 9 5.6151 - . 5 A A 723 l.COC A93.000 1.6370 1 . 62 Ae .75 6 .06AA 6.1060 -.68

A 2 2 A 1.000 A 9 3 . 000 1.9319 1.9116 1.06 7.0325 7.100C -.95

A 72 5 1 .000 A93.000 2.2052 2.1766 1.32 7.9001 7.9925 -1.16

A 226 1.000 A 9 3 . 000 2 . A027 2.3679 1 .A7 6.5102 8.6199 -1.27

A 227 1.000 A93.0C0 2.6315 2.5697 1.62 9.2001 9.3202 -1.37

A 228 1.000 A93.0C0 2 . 93 A 2 2.8838 1.75 10.0868 10.2353 -1 . A 5 A 22 9 1.000 A 9 3 . 000 3 . 1 0 A 6 3.0501 1.79 10.5737 10.7313 -1.A7

A 230 1.000 A93 .000 3 . 5 A36 3 . A 8 1

1.80 11.7895 11 . 9 6 0 A -1 .A3

A 731 1.000 A93.0C0 3 . 8605 3 . 795 A 1.72 12.6356 12 . 8 0 6 A -1 .3A

A 232 1.000 A93 .000 A . 2 26 A A. 1622 1 . 5 A 13.5026 1 3 . 7 A A 2 -1.13

A 233 1.000 A 9 3 . 000 A .7136 A . 6 5 7 A 1.21 1A.7987 1 A . 93 26 -.90

A 2 3 A 1.000 A 9 3 . 000 A . 9907 A.939A 1 .CA 1 5 . A 62 0 15.5817 -.76

A 735 1 .000 A93.0C0 5.6965 5.678C .33 17.1228 17.1632 -. ’A

A 236 1.000 A 93.000 6.2070 6 . 2 1 8 A -.18 18.2826 10.2586 .13

A 237 1.000 A93.000 6.7980 6 . 8 A 8 9 - . 7 A 19.6023 19. A96A . 5 A A 23 8 1.000 A 9 3 . 000 7.5870 7.6852 -1.2 6 21 .3A13 21.1359 .97

A 739 1.000 A 9 3 . 000 8.0197 8.1526 -1.63 22.3301 22 .0A67 1.29

A 2 A 0 1.000 A 93 . 000 9.3067 9.3191 -.13 2 A . 9 A 1 7 2 A . 9 1 2 3 .12

A 2A1 1.000 A93.000 9.9750 10.1256 -1 .A9 26.9A2

26. 553A 1 . A6

A 2 A 2 1.000 A93 .000 10.9190 11.0395 -1.09 29. A80A 29.1269 1.21

A ?A3 1.000 A93.00C 12.19A0 12.2393 -.37 33.3875 33.2256 . A9

A 2 A A 1,000 A 93 . 000 12.6500 12.9165 -2.00 35.9698 3A.9A68 2.93

A 2 A 5 1.000 523.150 . 0 A 8 A . 0 A 8 5 -.07 .2102 .2100 .07

A 2 A 6 1.000 523.150 .0511 .0511 -.07 .2216 . 2 2 1 A .07

A 2 A 7 1.000 523.150 .0561 .0562 -.08 . 2 A3 A .2A32 .03

A 2 A 8 1.000 523.150 .0565 .0565 -.0 8 . 2 A A 9 , 2 A A 7 .00

A 2 A 9 1.000 523.150 .0778 .0779 -.12 .3372 . 3360 .12

A 250 1.000 523.150 . 0 82 1 . 0822 -.13 , 3 5 5 A . 3550 .13

A 251 1.000 523.150 .0902 .0903 -.1A .3905 . 3899 .1A

A 252 1.000 523.150 .0907 .0909 -.1A . 392 0 .3923 .1A

A 253 1.000 523.150 .1251 .1253 -.19 . 5 AO 5 . 5395 .19

A 25 A 1.000 523.150 .1318 .1321 -.20 .5695 , 5 6 8 A .20

A 255 1.000 523.150 . 1 AA 9 . 1 A5 3 -.22 .6258 .62 AA .22

A 256 1.000 523.150 , 1 A5 7 . 1 A 6

-.22 .6292 .6270 .22

A 257 1.000 523.150 .2009 . 2015 -.29 . 86 A 8 . 8 6 2 A .29

A 258 1.000 523.150 .2118 . 2 1 2 A -.30 .9112 .9005 .30

A 259 1.000 523.150 .232 8 . 2336 -.32 1 .0007 . 9975 .32

A 260 1 .000 523.150 . 2 3 A

. 2 3 A 9 -.33 1.0062 1 .0030 .32

A 261 1.000 523.150 . 3227 . 32AC -.39 1.3806 1.3753 .39

59
Tabl e 6 Continued

hydrogen sulfide pvt data vs. eqnstate

(l)REAMER, ( 2 ) L E W I S > (3)RAU, ( A ) STR ATY

ID PN WT T»K MOL/l CALCD D, PC T P » M P A CALCD P» PCT

A 262 1.000 523. 15C . 3 A02 . 3A16 -.AO 1 .A5A0 1 . AA63 .AO

A 263 1.000 523.150 • 37A0 .3756 - . A 2 1.5957 1.5892 .Al

A 2 6 A 1.000 523.150 .3761 .3777 - . A 2 1 .60AA 1.5979 .Al

A 265 1.000 523.1 50 . A 5 1 3 . A 5 3 2 -.A3 1.9176 1.9095 . A2

A 266 1.000 523.150 .5032 , 505

-.A3 2 . 1 3 2 A 2 . 1 2 3 A .A 2 A 267 1.000 523.150 .5183 .5206 -.A3 2 . 1 9A 9 2.1056 . A 2 A 2 6 8 1.000 523.150 . 5 A 6A , 5 A 8 8 -.A3 2.3106 2.3010 .A 2 A 269 1.000 523.150 . “>626 . 5650 -. A2 2.3768 2.3670 .Al

A 270 1.000 523.150 .6008 . 6033 -. A1 2.5331 2.5229 .AO

A 271 1.000 523.150 . 60A2 .6067 -.Al 2.5A70 2.536P .AO

A 272 1.000 523.150 ,72A 8 . 72 7 A -.36 3.0362 3.0257 .35

A 273 1.000 523.150 . 8082 .8107 -. 31 3.3709 3.3610 .29

A 2 7 A 1.000 523.150 . 8326 . 8350 -.29 3.A603 3 . A 5 8 7 .20

A 275 1.000 523.150 . 8778 . 8800 -.25 3 . 6 A 79 3.6390 . 2 A A 276 1.000 523.150 . 9036 .9057 -.23 3 .7503 3 . 7 A 1 9 .22

A 277 1.000 523.150 .9650 . 9667 -. 10 3.9920 3.9851 .17

A 278 1.000 523.150 .9705 .9722 -.18 A. 0136 A. 0060 .17

A 279 1.000 523.150 1 .16AA 1 .16A3 .01 A. 7673 A .7678 -.01

A 2 8 n 1.000 523.150 1.2985 1 .2966 .15 5.2796 5.2870 -.1A

A 281 1.000 523.150 1 .3380 1.3355 . 19 5.A292 5 . A 3 90 -.13

A 282 1.000 523.150 1 . A109 1. A072 .27 5.7036 5.7179 -.25

A ?83 1.000 523.150 1 .A517 1.AA73 .31 5.8563 5 . 873A -.29

A 2 8 A 1.000 523.150 1.5510 1 . 5 A A 6 .Al 6.2251 6 . 2 A 92 -.39

A 285 1.000 523.1 50 1 .5595 1.5529 . A 2 6.2565 6.2813 -.39

A 286 1.000 523.150 1.7533 1 . 7 A 2 5 .62 6 . 96 5 A 7 . 00 5

-.57

A 287 1.000 523.150 1 .871 A 1.8578 .73 7.3910 7 . A A 0 8 -.67

A 288 1.000 523.150 2 . 0870 2.0681 .92 0.1556 8.2239 -.83

A 289 1.000 523.150 2.1502 2.1296 .97 8.3765 8. A502 -.87

A 290 1.000 523.150 2 .2682 2. 2AA6 1 .05 8.7859 8.8696 - . 9A

A 291 1.000 523.150 2.333A 2.3001 1.10 9.0102 9.0991 -.98

A 292 1.000 523.150 2 . A 92 9 2 . A 63 6 1.19 9.5537 9.6550 -1.0 5 A 293 1.000 523.150 2.5066 2. A770 1.19 9.6000 9.7023 -1.05

A 2 9 A 1.000 523.150 2.8172 2.7807 1.31 10.6358 10.7583 -1 .1A

A 295 1.000 523.150 3.0073 2.9673 1.35 11.2568 11.308A -1.16

A 296 1.000 523.150 3.3526 3 . 308 A 1.33 12.3620 12.5023 -1 .12

A 297 1.000 523.150 3.A613 3. A092 1. 53 1 2 . 68 1

12. 8A52 -1.27

A 298 1.000 523.150 3.6509 3.5991 1 .AA 1 3 . 27 A 2 1 3 . A 3 3 0 -1.19

A 299 1.000 523.150 3.7562 3.7013 1. A8 13.5687 13.7563 -1.22

A 300 1.000 523.150 A . 0 1 1 A 3.9579 1.35 1A.36AA 1 A . 52 37 -1.10

A 301 1.000 523.150 A. 0352 3.9815 1.35 1 A . A 3 A 9 1A. 59A6 -1.09

A 302 1 .000 523.150 A . 5 3 A 9 A. A886 1.03 15.9116 16.0A31 -.82

A 303 1.000 523.150 A.8A12 A . 8 0 3 0 .78 16.7977 16 . 901 A -.61

A 30 A 1.000 523.150 5.3983 5 . 3 8 A 1 .26 18.3771 18.A150 -.21

A 305 1.000 523.150 5.5617 5.5560 .09 18.8365 18.8A95 -.07

A 306 1.000 523.150 6.0358 6.0572 -.35 20 .1A71 20.0916 .28

A 307 l.OCO 523.150 6.AA51 6 , A 95 9 -.78 21.2003 21 . 1 A 95 .62

A 308 1 .000 523.150 6 . A 8 39 6.5379 -.83 2 1 . 3 8 0 A 21 .2A92 .65

A 309 1.000 523.150 7.2872 7.3960 -1.A7 23 . 600 A 23. 3100 1.21

A 310 1.000 523.150 7.7796 7. 9 10

-1.65 2 A , 95 1

2A.60A7 1 .Al

A 311 1.000 523.150 0 . 6

7 A 0 8, 8A75 -1.96 27.5259 27 . 03 AA 1.82

A 312 1.000 523.150 8.9381 9.1165 -1 .96 28.30AA 27.7857 1.87

A 313 1.000 523.150 9.6980 9. 87A 3 -1.79 30.6255 30.0670 1.86

A 31 A 1.000 523.150 10.3581 10.5228 -1.57 32.7913 32.2237 1 .76

A 315 1.000 523.150 10.A16A 1 0 . 5 6 A 5 -1.57 33.0072 3 2 . A 3 00 1.78

A 316 1.000 523.150 1 1 . 7 1 A 8 11.0213 -.90 37.760 8 37.3160 1 .19

NP - 112 , DN RMS PC T • . 90 2 » DNTRNDPCT . 0 A 1 , pmeanpct .631

60
Table 6 Cont i nued

HYDROGEN SULFIDE PVT DATA VS. EONSTATE

(l)REAMER, ( 2 ) l E WI S, (3>RAU, ( A ) STR A TY

ID PN WT t,k *01 / L CALCD D, PC T P » M P A CAICD Pf’CT

1 317 .001 360.928 17.7983 17.92A1 -.70 10.5835 10.1B6A 3.90

1 31 e .001 360 .928 16.8615 1 7 , 003 A -.83 6 . 2 ie 6 7 , 9 5 A 9 3.31

1 31 9 .001 360.928 A . AA96 A . 2 90 A 3.71 7 . 1 1 5 A 7.1952 -1.11

1 320 .001 360.928 A.00A6 3 • 8 A 77 A. 08 6.8396 6 . 9 A 68 -1 .5A

1 321 .001 366. A63 17.7983 17, 815 A -.10 12.7691 12.7102 . A 6

1 322 .001 366 .A83 16.8615 16.8887 -.16 10.20A2 1 0 . 1 A 6 5 .57

1 323 .001 366. A83 16.0185 16.0339 -.10 8.7701 8.7508 .22

1 3 2 A .001 366. A83 5.7209 5.A8AO A. 32 7.9565 8.0116 -.69

1 325 .001 366. A83 5.0058 A. BA7A 3.27 7.7359 7.8016 - . 8 A 1 326 .001 366. A83 A. AA96 A. 3133 3.16 7 , A 5 3 2 7 . 5 3 A 9 -1.0 8 1 327 .001 366. A83 A . 00 A 6 3.8770 3.29 7.1A30 7 . 2 A 1

-1.36

1 328 .001 372.039 16.8615 16.87A3 -.08 12.3761 12.3AA9 .25

1 32 9 .001 372.039 16.0185 16.0210 -.02 10.6869 10.6829 .OA

1 330 .001 372.039 1A.5622 1 A , A 65 3 .67 9.1700 9.2229 -.57

1 331 .001 372.039 1 3 . 3 A 8 7 13.6959 -2.53 8 . 8 80 A e . 8088 .81

l 332 .001 372.039 8.0092 7. A922 6.90 8.7563 8 . 78 A6 -.32

1 333 .001 372.039 6.67AA 6.5501 1.90 8.6598 8.67ee -.22

1 33 A .001 372.039 5.7209 5.6898 .55 8 « A 5 99 8.A696 -.11

1 33 5 .001 372.039 5.0058 A.9AA5 1. 2 A 8.1565 8.1871 -.37

1 336 .001 372.039 A.AA96 A. 3509 2.27 7.7980 7.8659 -.86

1 337 .001 372.039 A . 00 A 6 3.9070 2.50 7.AA63 7.5305 1.12

1 33 * .001 377. 59A 16.0185 16.0227 -.03 12.6312 12.6233 .06

1 339 .001 377. 59A 1 A, 5622 1A . 5052 .39 10.7282 10.7735 -. A2

1 3 A 0 .001 377. 59A 1 3 . 3 A 8 7 13.306A .32 10.0801 10.0952 -.15

1 3 A 1 .001 377. 59A 1 1 • A A 1 8 11.5511 -.95 9.7216 9.7096 .12

1 3 A 2 .001 377. 59A 10.0115 9.3513 1.63 9.5768 9.5883 -.12

1 3A3 .001 377. 59A 8.0092 7 . 8 A A 8 2. 10 9.A113 9 , A 3 0 1 -.20

1 3 A A .001 377. 59A 6.67AA 6.6732 .02 9.211 A 9.2117 -.00

1 3 A 5 .001 377. 59A 5.7209 5 . 6 A 16 1 . A

8 . 8 606.9131 -.37

1 3 A 6 .001 377. 59A 5.0058 A. 9023 2.11 8.5012 8.5632 -.72

1 3 A 7 .001 377. 59A A . A A96 A . 3 A A 7 2. A1 8.1062 8.1902 -1.00

1 3 A 8 .001 377. 59A A . OOA 6 3.908C 2 . A 7 7.7221 7 . 81 AC -1.19

1 3 A 9 .001 383.150 1 A . 5622 1A .535 5 .18 12.3071 12 .33A9 -.22

1 350 .001 383.150 13 . 3 A 8 7 13.3370 .09 11.3901 11.3966 -.06

1 351 .001 383.1 50 11 . AA1

11.6761 -2.01 10.7627 10. 70AA .55

1 352 .001 383.150 10.0115 10.0685 -.57 1 0 , A 2 A 9 1 0 . A 1 A 8 .10

1 353 .001 383.150 8.0092 e.lA20 -1.63 10.0939 10.0682 .26

1 3 5 A .001 383.150 6.67AA 6.6657 -.17 9. 735

9.7317 .OA

1 355 .001 383.150 5.7209 5. 6A27 1.39 9.3079 9 , 3 A 7 2 - . A 2 1 356 .001 383.150 5.0058 A. 9202 1 . 7 A 8.8736 8.9323 -.66

1 357 .001 383.150 A , AA96 A .3690 1.85 8 . A 3 9 2 8.5091 -.82

1 358 .001 383.150 A.00A6 3.9323 1.8A 8.0186 8.0933 -.92

1 359 .001 388.706 1 3 . 3 A 8 7 13. 5A39 — 1 . A A 12.8587 12.7070 1.19

1 360 .001 388.706 11 . A A 1

11.7979 -3.02 11 .BA52 11.70A3 1 .20

1 361 .001 388.706 10.0115 10.2187 -2.03 11.3005 11 .2A0A , 5 A 1 362 .001 3 68.706 0.0092 8.0178 -.11 10.7007 10.6982 .02

1 363 .001 388.706 6 . 6 7 A A 6.5A9A 1.91 10.1905 10 . 2 A 3 2 -.52

1 36 A .001 388.706 5.7209 5.5755 2.61 9.6871 9 . 77 A 2 -.89

1 365 .001 388.706 5.0058 A, 8803 2,57 9.1976 9.2958 -1.06

1 366 .001 388.706 A , AA96 A.A22A .61 8.7977 8 . 82 3 A -.29

1 367 .001 388.706 A . 00 A 6 3.9198 2.16 8.2737 8 . 3690 -1. 1A

1 368 .001- 39A.261 11.AA18 11.7618 -2.72 12 .879A 12.7077 1.35

1 369 .001 39A.261 10.0115 10.3012 -2.81 12.1830 12.0653 .93

1 370 .001 39A.261 8.0092 6.1153 -1.31 11.3626 11 .3226 .35

1 371 .001 3 9 A . 2 61 6.67AA 6.6211 .80 10.7213 10. 7A83 -.25

1 372 .001 39A.261 5.7209 5.5928 2.29 10.1077 1 0 . 1 9 5 A -.86

1 373 .001 39A.261 5.0056 A. 9081 1.99 9.5699 9.65 AA -.87

1 37 A .001 39A.261 A.AA96 A. 3717 1.78 9.0528 9.1336 - . 89

1 375 .001 39A.261 A.00A6 3.93A1 1.79 8 . 5 56 A 8 . 6 A 1 3 -.99

HP 59, DNRMSPCT • 2 .136, DNTPNDPCT - .898, P ME AN PC T • • 70A

61
Table 6 Cont i nued

HYDROGEN SULEIDE PVT DATA VS. EONSTATE

(l)REAHER# { 2 REWIS, ( 3 )RAU, (A)STRATY

ID PN WT T,K NOl/l CALCD D.PCT P, MPA CALCD P# °C T

2 376 .001 373.000 1*.0000 13.7151 2.08 9.1193 9.2150 - 1 . 0 * 2 377 .001 373.000 15.0000 15 . 2*66 -1.62 10.0312 9.8055 2.30

2 376 .001 373.000 16.0000 16.0967 -.60 11 . 1*58 10.9888 1 , * 3 2 37 9 .001 373.000 17.0000 17 . 1*15 -.83 13. *762 13 . 08*2 3.00

2 300 .001 373.000 18.0000 16.1003 -.55 16.9213 16 .

89 * 2.62

2 381 .001 373.000 19.0000 19 . 1*08 -. 7 * 22.5955 21 .6877 *.19

2 362 .001 373.000 20.0000 20.0917 -.*6 30.0935 29.2578 2 .66

2 383 .001 373.000 21.0000 21.0352 -.17 * 0 . 327 * 39.8677 1.10

2 38 * .001 373.000 22.0000 21.9770 .10 5*. 0062 5*. 3900 -.71

2 385 .001 373.000 23.0000 22 . 9*21 .25 72 ,** 7 * 73.7155 - 1.72

2 386 .001 393.000 8.0000 6.2872 27 . 2 * 10 .*365 11.1780 -6.6 3 2 3 B 7 .001 393.000 9.0000 6.9023 30 . 39 10 . 7*05 11.5220 - 6.78

2 388 .001 393.000 10.0000 8.1951 22.02 11 . 2*71 11.8738 - 5.28

2 389 .001 393.000 11.0000 9.6698 13.76 11.7537 12.2763 -*.26

2 390 .001 393.000 12.0000 10 . 963 * 9. *5 12.2603 12.7702 - 3.99

2 391 .001 393.000 13.0000 12 . 6 * 6 * 2.80 13.1723 13 .

32 * - 1 . 9 *

2 392 .001 393.000 1*.0000 13 . 818 * 1.31 1 * . 1 85 5 1 * . 3 8 8 * -1 .*1

2 393 .001 393.000 15.0000 1*. 8102 1.28 15.5027 15.8222 - 2.02

2 39 * .001 393.000 16.0000 16.0192 -.12 18.0359 17.9851 .28

2 395 .001 393.000 17.0000 16.9672 .19 21.0756 21.2018 -.60

2 396 .001 393.000 18.0000 16.0111 -.06 25.9392 25.8773 . 2 *

2 397 .001 393.000 19.0000 19 . 0 * 1 * -.22 32.8293 32 . 50*6 1.00

2 398 .001 393.000 20.0000 20.0161 -.08 * 1 . 8*72 * 1.6751 .*1

2 399 .001 393.000 21.0000 20 . 99*0 .03 5*. 0062 5*. 0926 -.16

2 *00 .001 393.000 22.0000 21 . 920 * .36 69.1037 70.5880 -2.10

2 *01 .001 393.000 23.0000 22.9192 .35 90.1792 92 .1332 - 2.12

2 *02 .001 * 13.000 8.0000 7 . 68*1 *.11 13.1723 13 . 39*1 -1.66

2 *03 .001 * 13.000 9.0000 8. *103 7 . 01 13.6789 1* . 0909 - 2.92

2 * 0 * .001 * 13.000 10.0000 9 . 68*2 3.26 1* .90 8 1 *. 83*8 -1 . 6 *

2 *05 .001 * 13.000 11.0000 10.6835 2.96 15 .

01 * 15 . 68*8 - 1.81

2 *06 .001 * 13.000 12.0000 11 . 6*37 3.06 16.3133 16.6979 -2.30

2 *07 .001 * 13.000 13.0000 12.6823 2.50 17.5292 17.9682 - 2 .**

2 *08 .001 * 13.000 1* .0000 13.9036 .69 19 .5 ** 19.6378 -.93

2 *09 .001 * 13.000 15.0000 15.0312 -.21 21.9875 21 . 90 ** .38

2 *10 .001 * 13.000 16.0000 16 . 05*1 -. 3 * 25.2299 25.0302 .80

2 *11 .001 * 13.000 17.0000 17.0070 -. 0 * 29 . 38*3 29 . 3*90 .12

2 *12 .001 * 13.000 18.0000 18.0273 -.15 35. *638 35 . 27*9 . 5 *

2 *13 .001 * 13.000 19.0000 19.0708 -.37 * 3.9751 * 3.3112 1.53

2 * 1 * .001 * 13.000 20.0000 20.0119 -.06 5 * .2089 5*. 0621 .27

2 *15 .001 * 13.000 21.0000 20 . 971 * . 1 * 67 . 786 * 68 . 2*65 -.67

2 *16 .001 * 13.000 22.0000 21.9129 .*0 8 * .9103 86.71 31 - 2.08

2 *17 .001 * 13.000 23.0000 22.8610 .61 106.7966 110. *532 - 3.31

2 *18 .001 * 33.000 8.0000 8 . 026 * -.33 15 . 60*1 15 . 576 * .18

2 *1 9 .001 * 33.000 9.0000 8.9806 .22 16.6173 16 . 638 * -.13

2 *20 .001 * 33.000 10.0000 10.1176 - 1.16 17 . 93*5 17.7897 .81

2 *21 .001 * 33.000 11.0000 11.0336 -.30 19 . 150 * 19.1027 .25

2 *22 .001 * 33.000 12.0000 12.0721 -.60 20.7716 20 . 6*86 .60

2 *23 .001 * 33.000 13.0000 13 . 21*9 - 1.63 23.0000 22 . 536 * 2.06

2 * 2 * .001 * 33.000 1*.0000 1 * . 2 1

8 - 1.55 25.5339 2*. 9227 2. *5

2 *25 .001 * 33.000 15.0000 15.0136 -.09 28.0670 28.0190 .17

2 *26 .001 * 33.000 16.0000 15.9828 .11 32.0187 32.0989 -.25

2 *27 .001 * 33.000 17.0000 17 . 0*59 -.27 37 . 79*2 37 . 507 * .76

2 *28 .001 * 33.000 18.0000 18.0265 -.15 ** .8870 **.6689 .*9

2 *29 .001 * 33.000 19.0000 19 . 038 * -.20 5 * .5129 5*. 0979 .77

2 *30 .001 * 33.000 20. 0000 20.0113 -.06 66.5705 66. *116 . 2 * 2 *31 .001 * 33.000 21.0000 20 . 9 e *9 .07 82.0733 82 . 3**1 -.33

2 *32 .001 * 33.000 22.0000 21.8875 .51 100 . 210 * 102.7608 -2. *8

62
Table 6 Continued

HYDROGEN SULFIDE PVT DATA VS . EONSTATE

( l ) PEAME ?, ( 2 ) LEWIS » ( 3 ) RAU # (*)STRATY

ID PN WT T,K MOl/L C ALCD D,PCT P » M P A CALCD P » PCT

2 *33 .001 * 33.000 23.0000 22.7968 .89 122.9072 128.6723 - * . * 3

7 * 3 * .001 * 53.000 8.0000 8.2136 - 2.60 10.0359 17.7356 1.69

? *35 .001 * 53.000 9.0000 9. *535 -*.80 19.8597 19.1707 3 .59

2 *36 .001 * 53.000 10.0000 10.2589 - 2.52 21.1769 20.7386 2.11

2 *37 .001 * 53.000 11.0000 11 . 2*37 - 2.17 23.0008 22.5239 2.12

2 *33 .001 *53 .000 12.0000 12.1368 -1.13 2*. 9260 2 * .6108 1.28

2 *39 .001 * 53.000 13.0000 13.1555 - 1.18 27 . 560 * 27.1215 1.62

2 ** 0 .001 * 53.000 1 * .0000 1 * . 0 7 7 8 -.55 30. *988 30.2263 .90

2 **1 .001 * 53.000 15.0000 15.0899 -.60 3 * . 551

3 *. 1*96 1.13

2 ** 2 .001 * 53.000 16.0000 16.0592 -.37 39.5168 39 . 177 * .87

2 ** 3 .001 * 53.000 17.0000 17.0725 -.*2 * 6 . 20*2 * 5.6657 1.18

2 *** .001 * 53.000 18.0000 18.0378 -.21 5*. *115 5*. 0503 .67

2 ** 5 .001 * 53.000 19.0000 19.0322 -.17 65.2533 6*. 8577 .61

2 **fc .001 * 53.000 20.0000 20.0072 -. 0 * 78 .8309 78 . 718 * . 1 *

2 ** 7 .001 * 53.000 21.0000 20.9112 .*2 9*. 6375 96.3810 - 1.81

? ** 8 .001 * 53.000 22.0000 21.7980 .93 113.7880 118.7282 -* .16

2 ** 9 .001 * 53.000 23.0000 22 . 7**7 1.12 139.0179 1 * 6 . 788 * - 5.29

2 *50 .001 * 73.000 8.0000 8.2761 - 3 . 3 * 20.3663 19.8773 2 .*6

2 *51 .001 * 73.000 9.0000 9.2092 - 2.27 22.0889 21.6905 1 . 8 *

2 *52 .001 * 73.000 10.0000 1 C . 2955 - 2.87 2*. 3180 23.6812 2.69

2 *53 .001 * 73.000 11.0000 11.3231 - 2 . e 5 26 . 7*98 25 . 9*51 3.10

2 *5 * .001 * 73.000 12 .0000 12 . 2 * 1 * - 1.97 29.2829 28.5780 2 .*7

2 *55 .001 * 73.000 13.0000 13.2017 - 1.53 32 .

2*0 31 . 71*9 2 . 2 *

2 *56 .001 * 73.000 1* .0000 1*. 0537 -.38 35.7677 35.5388 . 6 *

2 *57 . 0 C 1 * 73.000 15.0000 1* . 9806 .00 * 0.2260 * 0.2865 -.15

2 *5 9 .001 * 73.000 16.0000 16.0822 -.51 * 6 .8122 * 6.2563 1 .20

2 *5 9 .001 * 73.000 17.0000 17.0695 -. *1 5*. *115 53.8158 1.11

? *60 .001 * 73.000 18.0000 18.0203 -.11 63.6321 63. *127 .35

2 *61 .001 * 73.000 19.0000 I 8.9705 .16 75 .1 83 2 75.5856 -.53

2 *62 .001 * 73.000 20.0000 19 . 9*75 .26 90 .0779 90.9783 -.99

2 *63 .001 * 73.000 21.0000 20 . 91 ** . *1 108.5191 110 . 35*6 - 1 . 66

2 * 6 * .001 * 73.000 22.0000 21.7870 .98 128.9867 13*. 6131 -*.10

2 *65 .001 * 73.000 23.0000 22.6830 l .*0 1 5 * .5206 16 *. 9 CC 5 - 6 . 2 * 2 *66 .001 * 93.000 8.0000 8. *165 -* .95 22 .8995 22 . 00*8 * .07

2 *67 .001 * 93.000 9.0000 9. **02 -*.66 25.2299 2*. 1998 *.26

2 *68 .001 * 93.000 10.0000 10. *339 -*.16 27.7631 26.6175 *.30

2 *6 9 .001 * 93.000 11 .0000 11. *717 -*.11 30.8028 29.3639 *.90

2 *70 .001 * 93 .000 12.0000 12.3923 -3.17 33 . 9*39 32 . 5*61 * .29

2 *71 .001 * 93.000 13.0000 13.2321 - 1.75 37.2876 36.3110 2.69

2 *72 .001 * 93.000 1* .0000 1 *

19 ** - 1.37 * 1 . 0*72 * 0.8535 2. *3

2 *73 .001 * 93.000 15.0000 15 . 1*27 -. 9 * * 7.3188 **> .*229 1.93

2 * 7 * .001 * 93.000 16.0000 16.0871 -. 5 * 5*. 0062 53.3293 1 .27

2 *75 .001 * 93.000 17.0000 17.0166 -.10 62.1122 61.9523 . 2 o

2 *76 .001 * 93.000 19.0000 17.9663 .19 72 . 3*61 72.7513 -.56

2 *77 .001 * 93.000 19.0000 19 . 003 * -.02 86 .3289 86.2777 .06

2 *78 .001 * 93.000 20.0000 19.9979 .01 103 . 1*89 103.1086 - . 0 * 2 *79 .001 * 93.000 21 .0000 20 . 893 * .51 121.7927 12*. 2626 -1 . 9 P

2 *80 .001 * 93.000 22.0000 21.7030 1.37 1 * 2.0577 150 .

1*6 - 5.56

2 *81 .001 * 93.000 23.0000 22 . 6*99 1.55 170.6313 182 . 700 * - 6.61

so * 106 » D NR M S PC T - 5 • 0 95 » DNTRNDPC T » . 716 * P M E A N PC T - 1 . 9*6

63
Table 6 Conti nued

hvdptgen sulfide pvt data vs . eqnstate

( l ) REAMER * ( 2 ) L E W I S » ( 3 ) R A

» (

) STR ATY

ID PN WT T » K MGL/L C ALCD D » °C T P>MPA C ALCD P » PC T

3 48 2 .001 380.400 14 . 0540 15.3680 - 3.34 12 . 50 C 0 11 . 8546 5.44

3 483 .001 390.400 14.8436 14.9783 -.90 15.0000 14.7863 1.43

3 404 .001 398.600 14.8409 14.9897 -.94 17.5000 17.2266 1.59

3 485 .001 408.600 14.8361 14.7609 .51 20.0000 20.1722 -.85

3 486 .001 416.900 14 . ei 96 14.7819 .26 22.5000 22.6001 -.44

3 467 .001 426.600 14 . 8098 14 .

5 7 e 1.04 25.0000 25.4579 - 1.80

3 480 .001 435.600 14.8069 14.6211 1 .27 27.5000 28.1283 -2.23

3 48 9 .001 443.900 14.7942 14.6463 1.01 30.0000 30.5533 - 1.81

3 490 .001 451.600 14.7793 14.7099 .47 32.5000 32.7840 -.87

3 491 .001 460.400 14.7667 14.6097 .52 35.0000 35.3424 -.97

3 492 .001 477.900 14.7578 14.6632 .64 40.0000 40.4890 -1.21

3 493 .001 400.100 14.7458 14.5754 1.17 42 . 5000 43.4443 - 2.17

3 494 .001 495.900 14.7295 14.6163 .76 45.0000 45.6543 - 1.43

3 495 .001 506.900 14.7332 14.5065 1.56 47.5000 48.9228 - 2.91

3 496 .001 514.900 14.7169 14.5397 1.22 50.0000 51.1729 - 2.29

3 497 .001 532.100 14.7096 14.5493 1.10 55 . 0000 56.1755 - 2.09

3 498 .001 552.900 14.6683 14.4288 1.66 60.0000 61.9335 - 3.12

3 499 .001 522.900 14,6994 14.5698 .89 52 . *000 53.4023 - 1.69

3 500 .001 54 1.900 14.6060 14.5084 1.22 57.5000 58.8661 - 2.3 2 3 501 .001 389.900 9.9206 12.6319 - 21.46 12.5000 11 . 3898 9.75

3 50 ? .001 409.600 9.9118 10.8737 - 0.05 15.0000 14.2691 5.12

3 503 .001 4 2 . 600 9.9020 10.3129 - 3.98 17.5000 17.0305 2.76

3 504 .001 444.400 9.8922 10.3505 - 4.43 20.0000 19.3136 3.55

3 505 .001 461.900 9.8824 10.2303 - 3.48 22 .5000 21.8314 3.06

3 506 .001 480.100 9.0736 10.1203 -2 .44 25 .OOCO 24.4393 2.29

3 507 .001 490.100 9.8619 10.0501 - 1.07 27.5000 26.9981 l .«6

3 508 .001 515.900 9 .

5 C 3 10.0093 - 1.59 30.0000 29.5133 1 .65

3 *09 .001 533.900 9.0542 9.9710 - 1.17 32.5000 32.0953 1.26

3 510 .001 552.500 9.8416 9.9199 -.79 35.9000 34.6967 .87

3 511 .001 570.100 9.0280 9.9134 -.86 37,5000 37 . 136 C .90

3 512 .001 588.500 9.0135 9.0048 -.72 40.0000 39.6674 .84

3 513 .001 606.900 9.8020 9.8620 -.61 42 . 5000 42.1957 .72

3 514 .001 624.900 9 . 805 e 9.8539 -.49 45.0000 44.7366 .59

3 515 .001 643.900 9.7991 9.8242 -.25 47.5000 47.3525 .31

3 516 .001 663.900 9.7847 9.7773 .08 50.0000 50.0469 -.09

3 517 .001 701.900 9.7723 9.7416 .31 55.0000 55.2191 -.40

3 510 .001 740.400 9.7542 9.7078 .48 60.0000 60.3694 -.61

3 519 .001 402.100 7.2051 8.6120 - 16.34 12.5000 11 . 767 ? 6.23

3 520 .001 428.400 7.2062 7.9204 - 9.02 15.0000 14.3028 4.87

3 52 1 .001 454.400 7.2077 7.7284 - 6.74 17.5000 16.7604 4.41

3 522 .001 480 .100 7.2098 7.6621 - 5.90 20.0000 19.1586 4.39

3 523 .001 507.400 7 .

870 7.5639 - 4.98 22.5000 21.6230 4.06

3 524 .001 535.400 7.1839 7.4825 - 3 .99 25.0000 24.1626 3.47

3 525 .001 562.400 7.1927 7.4593 - 3.57 27.5000 26.6290 3.27

3 526 .001 589.400 7.1798 7.4459 - 3.57 30.0000 29.0080 3.42

3 527 .001 617.100 7.1762 7.4231 - 3.33 32.5000 31.4631 3.30

3 52 8 .001 645.400 7.1746 7.3958 - 2.99 35.0000 33.9652 3.05

3 529 .001 672.900 7.1726 7.3900 - 2.94 37.5000 36.3012 3.00

3 530 .001 702.100 7.1705 7.3596 - 2.57 40.0000 38.9345 2.74

3 53 1 .001 730.900 7.1690 7 . 341 * - 2.35 42.5000 41.4436 2.55

3 532 .001 759.900 7.1674 7.3250 - 2.15 45.0000 43.9594 2.37

3 533 .001 390.900 4.8900 5.0177 - 15.95 10.0000 9.3436 7.03

3 534 .001 435.600 4.8924 5.1979 - 5.8 8 12.5000 12.0526 3.71

3 535 .001 478.900 4 .8852 5.1039 - 4.28 15.0000 14.5392 3.17

3 536 .001 523.400 4.8852 5.0538 - 3.34 17.5000 17.0369 2.72

3 537 .001 568.100 4 . 882 8 5.0332 - 2.99 20.0000 19.4920 2.61

3 53 e .001 613.600 4.8733 5.0164 - 2.85 22.5000 21.9263 2.62

64
Ta bl e 6 Continued

HYDRDGF* SULFIDE PVT DATA VS. EONSTATE

(DREADER# <2»LEWIS* (3JRAU, <4>STRATY

ID P N WT T»K M 0L / L c alcd D, PC T P,MPA C ALCD P, =>CT 3 5 3 <5 .0C1 663.600 4.8709 4.9568 -1.73 25.0000 24.5966 1.64

3 5 0 .001 711.600 4 . 8662 4.9369 -1 .43 27.50C0 27.1717 1.39

3 541 .001 759.100 4.8614 4.9287 -1.37 30.0000 29.5968 1.36

3 542 .001 361.900 3.9293 4.341C -9.48 7.2000 6.9475 3.63

3 543 .001 365.900 3.0120 3.3915 -11.19 7.5000 6.9631 7 .71

3 544 .001 465.100 3.0184 3. 1779 -5.02 10.0000 9.5966 4.20

3 545 .001 544.600 3.0120 3.1351 -3.92 12.5000 12.0667 3.59

3 546 .001 628.700 3.0075 3.0944 -2.81 15.0000 14.6065 2.69

3 547 .001 715.300 3.0021 3.0625 -1.97 17.5000 17.1660 1.95

3 54 3 .001 342.300 3.0711 19.2100 -84.28 6.0000 5.3725 11.68

NP » 67, DNRMSPCT -11. 816, DNTPNDPCT - -4.044, PME ANPCT » 2.781

N P » 316, DNRMSPCT « . 723, DNTRNDPCT « -.061, PMEANPCT 1.520

65
Table 7. Comparisons of ideal d as functions for hydroyen sulfide.

HYDROGEN SULFIDE IDEAL GAS, J OUL E S , HOL E S , K E L VI N

(l)BAEHR, ( 2 ) J AN A F

ID T , K HZ-HZZ C ALCD PONT sz CALCD PONT C PZ CALCD PCNT

1 50.0 16 AA .6 16 A 5.0 -.03 157 . 5 A 3 157.560 -.01 33.27 33.26 .02

1 100.0 3308 . A 3308.2 .01 180.616 180.609 .00 33.29 33.28 .02

1 150.0 4973.2 4973.3 -.00 1

A . 1 10 194.110 .00 33.31 33.32 -.02

1 190.0 5973.3 5973 .

-.00 200 '. 188 200.188 .00 33.37 33.36 .01

1 200.0 66 A 1 ,1 66 A 1 . 3 -.00 703.705 203.706 -.00 33.43 33.43 .02

1 220.0 7310.7 7310.

-.00 206.898 206.896 .00 33.53 33.53 .01

1 24 C .0 79 P 2.9 7992.6 .00 209.825 209.819 .00 33.67 33.67 .00

1 2 5 0.0 9657.9 8657.6 .00 212 .527 212.520 .00 3 3. 84 33 . 84 -.01

1 2 6 C . 0 9226.

9336.3 .00 21^.038 215.035 .00 34.03 34.04 -.0 2

1 300 . 0 10019.3 10019.3 0 . 00 217.391 217.391 0 .00 3 A . 26 34 .26 -.02

1 320.0 10706.9 1 C 707.0 -.00 219.611 219.610 .00 34.51 34.51 -.01

1 3 A 0 .

11399.6 11399.8 -.00 221 . 71 A 221.710 .00 34.77 34.77 -.01

1 360.0 12097.7 12098.0 -.00 223.710 223.705 .00 35 . 05 35.05 .00

1 380.0 12801.7 12801.9 -.00 225 . 61 A 225.608 .00 35.34 35.34 .01

1 A 0 0 .

13511.7 13511.7 -.00 227 . A 35 227.428 .00 35.65 35.64 .01

1 A 2 0 .

1 A 227.8 1 A 227.7 .00 229.181 229.175 .00 35.96 35.95 .02

1 A A 0 .1 A 950.0 1 A 9 A 9.9 .00 230.860 230.855 .00 36.28 36.27 .02

1 A 60.0 15678.9 15678.6 .00 232 . A 73 232 . 47 A -.00 36.60 36.60 .01

1 A 8 0 .

16 A 1 A .0 16 A 13.9 .00 23 A . 0 A 5 234.039 .00 36.94 36.93 .01

1 500.0 17156.1 17155.9 .00 235.558 235.553 .00 37.27 37.27 .00

1 520.0 17905.1 1 790 A . 8 .00 237,030 237.022 .00 37 . 62 37.62 -.00

1 5 A 0.

18660.6 18660.6 .00 238 .452 238.448 .00 37.96 37.97 -.00

1 560.0 19 A 23.5 19 A 23.4 .00 239.840 239.835 .00 38.32 38.32 -.01

1 580.0 20193 .

20193 .

-.00 2 A 1 .187 2 A 1 . 1 86 .00 38.67 38.68 -.01

1 600.0 20970.5 20970.5 -.00 242.509 2 42 . 503 .00 39 . 03 39.04 -.01

1 620.0 2 1

5 A ,6 2 175 A . 9 -.00 2 A 3.789 243.789 .00 39.39 39.40 -.01

1 6 A 0 .

225 A 6.3 2 2 5 A 6 .

-.00 245 . 0 A 5 2 A 5 . 0 A 6 -.00 39.76 39.76 -.01

1 660.0 233 A 5.2 2 3 3 A 5 . A -.00 2 A 6.275 2 A 6.275 .00 40.12 40.13 -.01

1 680.0 2 A 151.0 2 A 151 .

-.00 2 A 7 . A 81 2 A 7 . A 78 .00 40 . 49 40.49 -.01

1 700.0 2 A 96 A.A 2 A 95 5 « 0 -.00 2 A 8 .662 248.657 .00 40.85 40.85 -.01

1 720.0 2 578 A .

25785.6 -.oc 249.817 249.813 .00 41.21 41.22 -.00

1 7 A 0 .

26613.0 26613.6 -.00 250 .948 250.947 .00 41.58 41 .58 -.00

1 760.0 27 AA 7.9 27 AA 8.

-.00 252.062 252.061 .00 41.94 41.93 .00

1 780.0 28290.2 28290.

-.00 253.160 253.155 .00 42.29 42.29 .01

1 800.0 291 A 0.0 291 A 0.3 -.00 254.232 254.230 .00 42.65 42.64 .01

1 820.0 29996.7 29996.7 .00 255 .288 255.287 .00 43.00 42.99 .01

1 8 A 0 .

30859.6 30860.0 -.00 256.328 256.327 .00 A 3 . 35 43.34 .01

1 860.0 31730.2 31730.2 -.00 257.359 257.351 .00 43.69 43.68 .01

1 980.0 32607.1 32607.2 -.00 258.365 258.359 .00 44.03 44.02 .01

1 000.0 3 3 A 91 .

33 A 91.0 .00 259 . 35 A 259.352 .00 44.36 44 .35 .01

1 020.0 3 A 381 . 5 3 A 381 •.00 260.335 260.331 .00 44.69 44.68 .01

1 060.0 361 82 .0 36181.5 .00 262 . 2 A 8 262.246 .00 45.32 45.32 .00

1 1000.0 380 C 7.2 38006.8 .00 264.110 264.109 .00 45.94 45.94 -.00

1 1050.0 A 0323.2 A 0322.5 .00 266.372 266.368 .00 46.68 46.68 -.01

1 1100.0 A 267 A .A 2 67 A . A -.00 268.558 268.556 .00 47 . 38 47.39 -.02

1 1150.0 A 5059 .A A 5060.5 -.00 270.679 270.677 .00 48.04 46.05 -.02

1 1200.0 A 7 A 77 .

A 7 A 78.

-.00 272 . 7 A 1 272.736 .00 48.67 48.68 -.02

1 1300.0 52 A 03.5 52 A 0 A .3 -.00 276.682 276.678 .00 49.82 49.81 .03

•> 200.0 66 A 6.

66 A 1 .3 .09 191.932 203 . 7 C 6 - 6.13 33.38 33.43 -.14

Z 300.0 10019.3 10019.3 0.00 205.859 217.391 - 5.60 34.21 34 .26 -.16

z AOO.O 13508.7 13511.7 -.02 215.886 227 . 42 « - 5.35 35.58 35 . 6 t -.17

z 500.0 1 7

A A .5 17155.9 -.07 223 .993 235.553 - 5.16 37.19 37.27 -.21

z 600.0 20952.0 20970.5 -.09 230.927 242.503 - 5.01 38.94 39.04 -.26

z 700.0 2 A 925.3 2 A 965.0 -.12 237.063 248.657 - 4.89 40.74 O •

CD VJ1 -.28

66
Tabl e 8 Interpolated ideal gas functions for hydrogen sulfide.

HYDROGEN SULFIDE IDEAL GAS, J OUL E S , H 0 L E S , K E L V IN

T,K EZ-EZZ HZ-HZZ SZ CVZ CPZ

180.0 4476.8 5973.4 200.188 25.05 33.36

190.0 4727.4 6307.2 201.992 25.08 33.39

200.0 4976.4 6641.3 203.706 25.11 33.43

210.0 5229.7 6975.8 205.338 25.16 33.47

220.0 5481.6 7310.7 206.896 25.21 33.53

230.0 5734.0 7646.3 208.388 25.28 33.59

2 A 0 .

5987.2 7992.6 209.819 25.35 33.67

250.0 6241.1 8319.7 211.195 25.43 33.75

260.0 6495.8 8657.6 212.520 25.52 33.84

270.0 6751.6 8996.5 213.799 25.62 33.93

290.0 7008.3 9336.3 215.035 25.72 34.04

290.0 7266.0 9677.3 216.231 25.83 34. 15 300.0 7525.0 10019.3 217.391 25.95 34.26

310.0 7785.0 10362.5 218.516 26.07 34.38

320.0 8046.4 10707.0 219.610 26.20 34.51

330.0 8309.0 11052.8 220.674 26.32 34.64

340.0 8572.9 11399.8 221 .710 26.46 34.77

3 50.0 8838.1 11748.2 222.720 26.60 34.91

360.0 9104.8 12098.0 223.705 26.74 35.05

370.0 9372.9 12449.2 224.668 26.88 35.19

390.0 9642.4 12801.9 225.608 27.03 35.34

390.0 9913.4 13156.1 226.528 27.18 35.49

400.0 10185.9 13511.7 227.428 27.33 35.64

410.0 10460.0 13868.9 228.310 27.48 35.80

420.0 10735.6 14227.7 229.175 27.64 35.95

430.0 11012.7 14598.0 230.023 27.60 36.11

440.0 11291.5 14949.9 230.855 27.96 36.27

450.0 11571.9 15313.4 231.672 28.12 36. 43

460.0 11853.9 15678.6 232.474 28.28 36.60

470.0 12137.6 16045.4 233.263 28.45 36.76

4 fiO.O 12422.9 16413.9 234.039 28.62 36.93

490.0 12709.9 16794.0 234.802 28.79 37.10

500.0 1

Q 98 .6 17155.9 235.553 2 8.96 37.27

510.0 13299,1 17529.5 236.293 29.13 37.44

520.0 13581.2 17904.8 237 .022 29.30 37.62

530.0 13875.1 19281.8 237.740 29. <,8 37.79

540.0 14170.7 18660.6 238.448 29.65 37.97

540.0 14468.1 19041.1 239,14'- 29. P3 38.14

560.0 14767.3 19423.4 239.835 30.01 38.32

570.0 15068.3 19807.5 240.515 30.18 38.50

590.0 15371.0 20193.4 241.186 30.36 38.68

590.0 15675.5 20591.1 241.849 30.54 3 8.86

600 .0 15981.8 20970.5 242.503 30.72 39.04

610.0 16290.0 21361.8 243.150 30.90 39.22

620.0 16599.9 21754.9 243.789 31 .08 39.40

630.0 16911.7 22149.8 244.421 31.27 39.58

640.0 17225.2 22546.5 245.046 31.45 39.76

650.0 17540.6 22945.0 245.664 31.63 39.94

660.0 17857.8 23345.4 246.275 31.81 40.13

670.0 18176.8 23747.6 246.880 31.99 40.31

680.0 18497.7 24151.5 247.478 32.18 40.49

690.0 18820.3 24557.3 248.071 32.36 40.67

700.0 19144.8 24965.0 248.657 32.54 40.85

710.0 19471.1 25374.4 249.238 32.72 41.03

720.0 19799.2 25785.6 249.813 3 2.90 41.22

730.0 20129.1 26198.7 250.383 33.08 *1.40

740.0 20460.8 26613.6 250.947 33.26 41.58

750.0 20794.3 27030.2 251.507 33.44 41.76

67
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CM CM CM CM CM CM CM CM CM CM CM rH -H rH rH rH r-H rH H *H —

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CM n O —4 ro r-H CM 0 f HD r—ro rH PM HD r*. HD -H ro —4 CM HD HD rH m H 'M HD HD rH <0 -4 CM HD HD rH ro rH CM HD N. HD H O' OD O' ro O r-H 0- ao O' CO O rH O' ao O co O rH O' ao CP ro O rH O' CD O' ro O rH O’ ao O' ro O rH O' ao CP CO O

«-H CM r—

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ro ro m rn ro ro O CP rp rp rp O rp ro ro CO ro ro ro ro a O' O' O' O' O' O' O' O' O’ O' O' O' O’ in in n m in in in CD ao <r> OD ao ao ao O O O O 0 O O in in in m in m m

in in n n n in n 0 O 0 0 O O O HD HD HD HD HD HD HD N p- p- p- Pt O' O' O' O' O' O O' <M PJ CM PJ PJ CM pj p- p- p^ p- Pr p- p- m m m in n n in H >—

rH -H -4 r-4 r-H HD HD nO HD HD HD >0 P- P- P- p^ p^ O' O' O' O O' CP O' CM nj CM PJ PJ PJ CM p» p- p- p^ P- CM CM CM CM rvi <M CM ro ro ro ro CO CO CO ro co CO CO CO ro ro co CO ro co CO CO <0 ro ro ro CO CO ro ro O' O' O' o- O’ O’ O' 0 0- O' O’ O' O’ O’

68
Table 10. Calculated P(T) isochores of hydrogen sulfide.

HYDROGEN SULFIDE ISOCHORE AT .500 MOL/L

T P Z DP/DD

K HP A MP4-L/M0L

27?. 065 .9999 ,88*03 1.7372

2 80.000 1.0373 .89110 1.8237

288.000 1 . 0 7 A 5 . 8 97 A 8 1.9036

296.000 1.1115 .90323 1.9917

30*. 000 1.1*81 . 908A5 2.0733

312.000 1 . 1 8 A 5 .91321 2 .1536

320.000 1.2207 .91758 2.2330

328.000 1.2567 .92160 2.3115

336.000 1.2925 .92532 2.389?

3 A A . 000 1 .32 82 .92877 2 . A663

352.000 1.3638 .93198 2.5*23

360.000 1.3993 .93*98 2.6186

368.000 l.A3*7 .93778 2 . 69 AA 376.000 1 . A700 .9A0A1 2.7695

3 8 A . 000 1 . 5052 .9*288 2 . 8 A A3

392.000 1 . 5A0* .9*521 2.9186

AOO.OOO 1 . 575

. 9A7A0 2.9930

A 08 . 000 1.6105 . 9A9A8 3.0669

A 1 6 . 000 1 . 6A5A . 951 AA 3.1*06

A2A. 000 1 .680A .95330 3.21*1

'*32.000 1.7152 .95507 3.287*

A AO. 000 1.7501 .95676 3.3605

A A8 .000 1 . 73A9 .95836 3. *33*

A56.000 1.8197 . 95988 3.5062

A6A .000 1 . 8 5 A A .9613* 3 . 5 7°

A 72 . 000 1 .8891 . 96273 3 .6513

A 80.000 1.9238 .96*06 3.7236

A 38 . 000 1 .956A .9653* 3.7959

A 96.000 1.9930 . 96656 3.86*0

50*. 000 2 .0276 .96773 3 .9*00

512.000 2.0622 . 96886 A. 0120

520. COO 2.0968 .9699* A. 0838

52P.OOO 2.1313 .97098 A. 1556

536.000 2.1659 .97198 A .2273

5*A .000 2. 2C0A .9729* A. 298?

552.000 2 .23AP .97387 A. 3705

560.000 2.2693 .97*77 A . A A 1

568.000 2.3038 .97563 A .5133

576.000 2.3382 .976*7 A. 58A7

5 8 A . 000 2.3727 .97727 A. 6560

592.000 2. A071 .97805 A. 7272

600.000 2 . AA15 .97881 A .798*

608.000 2. A759 .9795* A. 8696

616.000 2.5103 .9802* A.9A07

6 2 A . 000 2. 5AA6 .98093 5.0117

632.000 2.5790 .98159 5.0827

6 AO . 000 2 . 61 3 A .98223 5.1537

6*8.000 2.6*77 .98285 5.22A6

656.000 2.6820 .983*6 5.2955

66A.000 2 .716* .98*05 5.366A

672.000 2.7507 .98*62 5. A372

680. 000 2.7850 .98517 5.5080

688.000 2.8193 .98571 5.5788

696.000 2.8536 .9862* 5 .6*95

70* .000 2.8879 .98675 5.7202

712.000 2.9222 .9872* 5.7909

720.000 2.9565 .98772 5.8615

OO/DT DP/DT 0 2 p / 0 T2 MOL /L /< MPA/K MP4 /K/K

-•2730E-02 .00*7* -.000008*

-.256SE-02 .00*68 -.0000066

- . 2A29E-C 2 .00*6* -.000005*

- . 2 30 8 E -0 2 .00*60 -.00000*5

-.22 01E-02 .00*56 -.0000038

-.2 106E-02 ,00 A 5

-.0000032

-. 2020E-02 . 00*51 -.0000029

-.19A3E-02 , 00 A A 9 -.000002*

-.1P72E-02 , 00 A A 7 -.0000021

-.1 807E-02 •00AA6 -.0000019

-.17A7E-02 . 00 AAA -.0000017

-.1691E-02 .00**3 -.0000015

- .1 639E-02 • 00AA2 -.0000013

-•1591E-02 . 00 A A 1 -.0000012

-.15A6E-02 . OOAAO -.0000011

-.150AE-02 .00*39 -.0000010

-.1A6AE-02 .00*38 -.0000009

-.1A27E-02 .00*38 -.0000009

-.1 391E-02 .00*37 -.0000008

-.1357E-02 .00*36 -.0000007

-.1 326E-02 .00*36 -.0000006

-.1295E-02 .00*35 -.0000006

— . 1 266E-02 .00*35 -.0000005

-.1 239E-02 .00*3* -.0000005

-.1213E-P2 .00*3* -.0000005

-.1188E-02 .00*3* -.000000*

-.116AE-02 .00*33 -.000000*

-.11A1E-02 .00*33 -.000000*

-.1119E-02 .00*33 -.000000*

-.1097E-02 .00*32 -.0000003

-.1077E-0? . 00*32 -.0000003

-.1058E-02 .00*32 -.0000003

-.1039E-02 .00*32 -.0000003

-.1021E-02 .00*31 -.0000003

- . 1 00 3 E -0 2 .00*31 -.0000003

-.9862E-03 .00*31 -.0000002

- • 9699E-03 .00*31 -.0000002

-.95*2 E -0 3 .00*31 -.0000002

-.9390E-03 . 00*30 -.0000002

-.92A2E-03 .00*30 -.0000002

-•9100E-03 .00*30 -.0000002

- . 8962 E-0 3 .00*30 -.0000002

-.3828E-03 .00*30 -.0000002

-. 8698E-03 .00*30 -.0000002

-.8572E-03 .00*30 -.0000002

-. 8A50E-03 .00*30 -.0000001

-. 8332E-03 . 00*29 -.0000001

-.8216E-03 .00*29 -.0000001

— .810AE-03 .00*29 -.0000001

- , 7995 E -0 3 .00*29 -.0000001

-. 7890E-03 .00*29 -.0000001

-.7786E-03 .00*29 -.0000001

-. 7686E-03 .00*29 -.0000001

-.7588E-03 .00*29 -.0000001

-.7A93E-03 . 00*29 -.0000001

-.7A00E-03 .00*29 -.0000001

-.7309E-03 .00*28 -.0000001

69
2 98

304

312

320

328

336

344

3 82 360

368

376

3 84 392

400

408

416

424

432

440

448

4 56

464

472

4 80

4 88 496

504

512

520

528

536

544

552

560

568

576

584

5 92 600

608

6 16 624

632

640

649

656

664

672

680

688

696

704

712

720

Tabl e 10. Conti nued

HYDPHGFN SULFIDE ISOCHORE at 1.000 MOl/L

T p 7 DP/DD DO/ DT DP/DT D2P/DT2

K HP A MPA-L/MOL MOl /L /K HP A/K HPA/K/K

215 2.0193 .81438 1.5764 - .6 5 95 E -02 .01040 -.0000279

000 2.0790 .82251 1.6515 -.6206E-02 .01025 -.0000235

000 2.1603 .83275 1 .7517 -.5755E-02 .01008 -.0000190

000 2.2403 .84203 1.9485 -.5379E-02 . 00994 -.0000158

000 2.3194 .85048 1.9427 -.5058F-02 .00983 -.0000133

000 2. 3976 . 95823 2.0347 - . 4 78 1

E -0 2 .00973 -.0000114

000 2.4751 .86536 2.1249 -•4538E-02 .00964 -.0000099

000 2.5519 . 87194 2.2136 -.4323E-02 .00957 -.0000086

oco 2. 6282 . 87805 2.3009 -•4131E-02 .00950 -.0000076

000 2.7040 .88374 2.3872 -. 3957E-02 . 00945 -.0000067

000 2.7794 .88904 2.4724 -.3 801E-02 .00940 -.0000060

oco 2.8544 .89401 2.5567 -.3654E-02 .00935 -.0000054

000 2.9290 . 89867 2.6402 -.3526E-02 .00931 -.0000048

000 3.0033 .90304 2.7231 -.3406E-02 .00927 -.0000044

000 3.0774 .90717 2.8053 - . 3 2 94 E -0 2 .00924 -.0000039

000 3.1512 .91106 2.9869 -.3190E-02 .00921 -.0000036

000 3.2248 .91474 2.9681 -.3094E-02 .00918 -.0000033

000 3. 29*1 .9ie23 3.0497 - . 3 004 E -0 2

• . 00916 -.0000030

000 3.3713 .92153 3.1290 -.2919E-02 .00914 -.0000028

000 3.4443 .92467 3 . 2 0

0 8 -.2840E-02 .00911 -.0000025

000 3.5171 .92766 3.2883 -.2766F-02 .00909 -.0000023

000 3.5898 .93050 3.3675 -.2695E-02 . 00908 -.0000022

000 3.6624 .93322 3.4463 -.2629E-02 .00906 -.0000020

000 3.7348 .93581 3.5249 -•2566E-02 .00904 -.0000019

000 3.8071 .93828 3.6033 -.2506E-02 .00903 -.0000017

000 3.8792 .94065 3.6813 -.2449E-02 .00902 -.0000016

000 3.9513 . 94292 3.7592 -.2395E-02 .00900 -.0000015

000 4.0233 .94510 3.8348 -.2343E-02 . 00899 -.0000014

000 4.0952 .94718 3.9143 -.2294E-02 .00898 -.0000013

000 4.1670 .94919 3.9916 -. 2247E-02 .00897 -.0000013

000 4.2387 .95111 4.0687 -.2202E-02 .00896 -.0000012

000 4.3103 .95297 4.1456 -.2159E-02 , 00 F 9 5 -.0000011

000 4.3819 . 95475 4 .2224 -.2118E-02 .00894 -.0000011

000 4.4534 .95647 4.2990 - . 207 8 E -0 2 . 00893 -.0000010

000 4.5249 .95812 4.3755 - .2040E-02 .00893 -.0000010

000 4.5962 .95972 4.4519 - . 200 3 E-0 2 .0089? -.0000009

000 4.6676 .96126 4 .5281 -.1968E-02 .00891 -.0000009

000 4.7388 .96275 4.6043 -.1934E-02 . 00890 -.0000004

000 4.8100 . 96419 4.6803 - . 1 90 1

E -0 2 .00890 -.0000008

000 4.8812 .96558 4.7562 -•1870F-02 .00 ee9 -.0000007

000 4.9523 .96692 4.8320 -.1839E-02 .00889 -.0000007

000 5.0234 . 96822 4.9079 -.1810E-C2 .00888 -.0000007

000 5.0944 .96949 4.9834 -.1781E-02 .00888 -.0000006

000 5.1654 .97071 5.0589 -.1753E-C2 .00887 -.0000006

000 5.2364 .97189 5.1344 -.1727E-02 .00 887 -.0000006

000 5 . 3073 . 97304 5.2098 -.1701E-02 . 00886 -.0000006

000 5.3781 .97415 5.2851 -•1676E-02 .00886 -.0000005

,000 5.4490 .97523 5 . 3604 -.1651 F-C2 .00885 -.0000005

000 5.5198 . 97623 5.43^5 -.1628E-02 .00885 -.0000005

000 5.5905 . 97730 5.5106 -.1 605E-02 .00884 -.0000005

000 5.6613 .97830 5.5857 -•1583E-02 .00884 -.0000005

,000 5.7320 .97926 5.6607 -.1 561E-02 .00884 -.0000005

000 5.8027 .98020 5 .7356 -.1540E-02 .00 e83 -.0000004

000 5 .8733 .99111 5.3104 -.1 520E-02 .00883 -.0000004

70
Table 10. Conti nued

HYPCOGEN SULFIDE IS0CH09E AT 2.000 MOL /

T 0 Z DP/DD DD/DT OP /DT 02 P /0T2

K MPA mpa-l/mol MQL /L /K MP A/K MP A /K /<

327.709 3.8949 .71472 1.2175 -.1946E-C1 .02369 -.0000930

326.000 3.9017 .71535 1.2223 -.1 936E-01 .02366 -.0000920

336.000 4 .0884 .73172 1 .3487 -.1707E-01 . 02302 -.0000709

344.000 4.2704 .74653 1.4683 -.1533E-01 .02251 -.0000569

352.000 4.4488 .76004 1.5829 -.1396E-01 .02210 -.0000471

360.000 4 .6242 .77244 1.6936 -.1284E-01 .02175 -.000039°

366.000 4. 7970 .78389 1.8011 -.1191E-01 .02146 -.0000341

376.000 4 . 9676 .79450 1 .9061 -.1112E-C1 .02120 -.0000296

3*4.000 5.1364 .80437 2.0068 -.1045E-01 .02098 -.0000259

392.000 5.3034 .81359 2.1098 -.9854E-02 .02079 -.0000229

400.000 5.4690 .82221 2.2090 -.9333E-02 . 02062 -.0000203

406.000 5.6333 . 83031 2.3069 -. 8870E-02 .02046 -.0000192

416.000 5.7965 .83792 2.4036 -.8456E-02 .02032 -.0000163

424.000 5.9586 .84510 2.4991 -. 8083E-02 .02020 -.0000149

432.000 6.1197 .85188 2.5936 -. 7745E-02 .02009 -.0000134

440.000 6.2800 .85830 2.6873 -.7437E-C2 .01999 -.0000122

448.000 6.4395 . 86439 2 .7801 -.7155E-02 .01989 -.0000111

456.000 6.5983 .87016 2.6723 -.6P96E-02 .019ei -.0000102

464 . 000 6.7564 . 87566 2.9637 -.6657E-02 .01973 -.0000094

472.000 6.9140 .88089 3.0546 -.6435E-02 .01966 -.0000097

4 60.000 7.0710 .88567 3.1449 -.6229E-02 .01959 -.0000080

468.000 7.2274 .89063 3 .2347 -.6037E-02 .01 953 -.0000074

4 96.000 7.38 34 .99518 3. 32*0 -. 5858E-02 .01987 -.0000069

504.000 7.5390 ,89953 3.4128 -•5669E-C2 .01942 -.0000064

512.000 7.6941 .90369 3.5013 - • 5 53 1 E-P 2 .01937 -.0000060

520.000 7 . 64 88 .90769 3 .5896 -.5383E-02 .01932 -.0000056

528.000 8.0032 .91152 3.6771 -. 5242E-02 . 01928 -.0000053

536.000 6.1573 .91520 3.7645 -.5110E-02 .01924 -.0000049

5 4 A .000 8. 3110 .91973 3.8516 -.4964E-02 .01920 -.0000047

552.000 8.4645 .92213 3 .93*4 - . 4 86 5 E -0 2 .01 916 -.0000044

560.000 8.6176 . 92541 4.C250 -.4752E-02 .01913 -.0000041

568 . 000 8.7705 .92856 4.1113 -.4645E-02 .01910 -.0000039

576.000 8.9232 .93160 4.1973 - . 4 54 2 E -0 2 .01907 -.0000037

5 *4.000 9.0756 .93453 4.2831 -.4445E-02 .01904 -.0000035

592 .000 9. 2277 .93736 4.3687 -.4351E-02 .01901 -.0000033

600.000 9.3797 .94010 4 .4541 -.4262E-02 .01809 -.0000032

608.000 9.5315 .94274 4.5393 - . 4177 E ~0 2 .0189o -.0000030

616. COO 9.6831 .94529 4.6243 -.4095E-02 .01893 -.0000029

624.000 9.8344 .94776 4.7091 -.4016E-62 .01891 -. 0000027

632.000 9 , 9657 .95015 4.7938 -.3941E-02 .01889 -.0000026

640.000 10.1367 .95247 4.8783 -.3866E-C2 .01867 -.0000025

648.000 10.2876 .95471 4.9626 -.3799E-02 .01885 -.0000024

656.000 10.4383 .95689 5.0469 -. 3732E-02 .01883 -.0000023

664.000 10 .5869 .95900 5.1309 -.3667E-02 .01881 -.0000022

672.000 10.7394 .96104 5.2148 - . 3 605 E-0 2 .01880 -.0000021

680.000 10.8897 .96303 5.2966 -.3544E-02 .01878 -.0000020

688. OOC 11.0398 .96496 5.3823 -. 3486E-C2 .01876 -.0000020

696.000 11.1899 . 96683 5 .4668 -•3430E-02 .01875 -.0000019

7 06 .000 11.3396 .96865 5.5493 -.3376E-02 .01873 -.0000019

712.000 11 .4897 .97042 5.6326 -.3324E-02 .01*72 -.0000017

720.000 11.6394 .97214 5.7158 -.3273E-02 . 01871 -.0000017

71
Tab 1 e 10. Cont i nued

HYDROGEN SULFIDE ISOCHORE AT 4.000 HQL/L

T P Z DP/DD DD/DT DP /DT D2P/DT2

K MPA MPA-L/MOL MOL /L/K mpa/k MPA/K/K

356.435 6.6998 .56518 . 5666 -.9708E-01 .05500 -.0003395

360.000 6.8939 .57579 .634? -.05O2E-O1 .05392 -.0002724

368.000 7.3176 .59789 .7753 -.6721E-01 .05211 -.0001894

376.000 7.7289 .61807 .9077 -.5595 E-0

.05079 -.0001447

384.000 8.1310 .63667 1.0347 -.4808E-01 .04975 -.0001163

392.000 8.5255 .65394 1.1579 -.4224E-01 .04891 -.0000964

400.000 8.9138 .67005 1.2782 -. 3771 E-01 .04020 -. 0000818

408.000 9.2969 .68515 1.3963 -.3408E-01 .04759 -.0000705

416.000 9.6755 .69933 1.5124 -.3112E-01 .04706 -.0000615

424.000 10.0501 .71270 1 .6271 - . 2 86 4 E-0

.04660 -.0000542

432.000 10.4213 .72534 1.7404 -.2654E-01 .04619 -.0000482

440.000 10.7893 .73730 1.8525 -•2474E-01 .04503 -.0000432

*48.000 11.1546 .74865 1.9637 - . 2 31 7 E-0

.04550 -.0000399

456.000 11.5174 .75944 2 .0739 - . 2 1 80 E-0

.04520 -.0000352

464.000 11.8780 .76971 2 .1834 -.2058E-01 .04494 -.0000321

472.000 12.2365 .77950 2.2922 -•1950E-01 ,04469 -.0000293

480.000 12.5931 .79885 2 .4003 -.1 852E-01 . 04447 -.0000269

488.000 12.9480 .79778 2.5079 -.1765E-01 .04426 -.0000248

496.000 13.3013 .00633 2.6149 -. 1685E-01 .04407 -.0000229

504.000 13.6531 .81452 2.7214 - . 1 61 3 E -0

.0*389 -.0000212

512.000 14.0036 .82238 2.8275 -.1 547E-01 .04373 -.0000199

520.000 14.3528 . 82992 2.9331 - . 1 4 86 E —0

.04359 -.0000184

528.000 14.7008 .03716 3.0383 — . 1 42 9E -0.04343 -.0000172

536.000 1 5.0*77 .84413 3.1432 - . 1 37 8 E-0.04330 -.0000161

544.000 15.3936 .05083 3.2478 -•1329E-01 .04317 -.0000151

552.000 15 .7385 . 95729 3.3520 - . 1 2 95 E -0

.04306 -.0000142

560.000 16.0825 . 86352 3.4559 - . 1 24 3 E -0

.04295 -.0000134

568.000 16.4257 .0695? 3.5595 - . 1 204 E-0

.04284 -.0000127

576.000 16.7680 . 87531 3.6628 -.1167E-01 .04274 -.0000120

584.000 17.1096 .88091 3.7659 -•1133E-01 .04265 -.0000114

592.000 17.4504 .88632 3.8688 -.1100E-01 .04256 -.0000108

600.000 17.7906 .89154 3.9714 -•1070E-01 .04248 -.0000103

608. COO 18.1301 .89660 4.0737 - , 1 04 1

E -0

.04240 -.0000098

616.000 18.4690 .90150 4.1759 -.101 3E-01 .04232 -.0000093

624.000 18.9072 .90624 4.2778 -.9876E-02 .04225 -.0000089

632.000 19.1449 .91084 4.3796 -.9631E-02 .04218 -.0000095

6*0.000 19.4821 .91529 4.4812 -.9397E-02 .04211 -.0000082

648.000 19.8187 . 91961 4.5826 -.9176E-02 .04205 -.0000078

656.000 20.1549 .92300 4.6838 -. 8964E-02 . 04199 -.0000075

664.000 20.4905 .92787 4.7848 - • 876 3 E-02 .04193 -.0000072

672.000 20.8257 .93183 4.8857 -.9570E-02 .04187 -.0000069

680.000 21.1605 . 93566 4.9964 -. 8386E-02 .04182 -.0000067

688.000 21 . 4948 .93940 5.0869 -.8210E-02 .04176 -.0000064

696.000 21.8287 .94302 5.1873 -. 8041E-02 .04171 -.0000062

704.000 22.1622 .94655 5.2876 -•7880E-02 .04167 -.0000060

712.000 22 .4954 . 94998 5.3877 -.7725E-02 .04162 -.0000059

720.000 22.8281 .95333 5.4877 -.7576E-02 . 04157 -.0000056

11
Table 10. Continued.

HYDROGEN SULFIDE ISOCHORE AT 6.000 HOL/L

T p Z DP/DD

K MPA MP A-L/MOL

368.306 8.2230 .**75* .1830

376.000 8.8839 .*7362 .3196

3 8* . 000 9.5*65 .*983* .*503

392.000 10.1937 .52126 .5776

<*00. COO 1 0 • 829* .5*271 .7033

<*08.000 11 .*568 .56288 .82 82 <*16.000 12.0766 .58192 .9525

<*2<* .000 12.690* .59996 1.0765

*32.000 13.2999 .61708 1.2003

<*<*0.000 13.9028 .63338 1 .3238

*<*8.000 1* . 5026 .6*890 1 . * * 71 *56.000 15.0988 .66373 1 .570*

*6* .000 15.6918 .67790 1.6935

*72.000 16.2818 .691*7 1 .816*

*80.000 18.9691 .70**7 1.9393

*83.000 17. *539 .7169* 2.0621

*96.000 18.036* .72892 2.18*7

50*. 000 19.6169 .7*0** 2.3073

512.000 19.195* .75152 2. *297

520.000 19.7720 .76218 2.5521

523.000 20.3*70 .772*6 2.67**

536.000 20.9203 .78238 2 .7965

5** .000 21. *922 .7919* 2.9185

552.000 22.0626 .80118 3.0*05

560.000 22.6317 .81011 3.1623

568.000 23.1995 .8187* 3.28*0

576.000 23.7661 .82708 3. *056

58*. 000 2* .3316 .83516 3.5271

592.000 2*. 8960 .8*299 3.6*85

600.000 25 .*593 .85056 3 .7698

609.000 26.0216 .85791 3.8910

616.000 26.5829 . 8650* *.0121

62* .000 27.1*3* .87195 *.1330

632.000 27 .7029 . 87866 * .2538

6*0.000 28.2616 .88517 *.37*6

6*8.000 28.819* .89150 *.*952

656.000 29.3765 .89765 *.6157

66* .000 29.9327 .90363 *.7360

672.000 30. *883 .909** *.8563

680.000 31.0*31 .91510 * .976*

688.000 31.597? .92060 5.0965

696.000 32.1507 .92596 5.216*

70*. 000 32.703* .93119 5.3362

712.000 33.2556 .93626 5. *559

720.000 33.9071 .9*121 5.5755

DD/DT OP /DT D2P/DT2

MOL /L /K HP A/K HP A/</K

-.*828E+C0 .08835 -.0009176

-.2631E+C0 . 0 e *08 -.0003691

-.1815E+00 .0817* -.0002353

-•13P7E+00 .08013 -.0001735

-.1122E+00 .07890 -.0001370

-.9*0 7 E -0

.07791 -.0001127

-.8092E-01 . 0770e -.0000952

-.7095E-01 .07630 -.0000320

- . 631 2 E -0

.07576 -.0000716

-.5682E-01 .07522 -.000063*

-.5165E-01 .07*7* -.0000566

-.*732E-01 .07*32 -.0000509

- . *36 5 E -0

.07393 -.0000*61

- • * 05 1 E-0

.07358 -.0000*21

-.3777E-01 . 07325 -.0000336

-.3538E-01 .07296 -.0000355

-.3327E-01 .07268 -.0000329

-.3139E-01 .072*3 -.0000305

- . 297 1

E -0

.07219 -.0000285

-.2 820E-01 .07197 -.0000266

-•268*E-01 .07177 -.0000250

-.2559E-01 .07157 -.0000235

-.2**6E-01 . 07139 -.0000222

- , 2 3* 2 E -0

.07122 -.0000210

- . 2 2*7 E -0

.07106 -.0000199

-.2159E-01 .07090 -.0000199

- . 207 8 E -0

.07075 -.0000130

-.2002E-01 .07061 -.0000171

-.1932E-01 .070*8 -.000016*

-.1866E-01 .07035 -.0000157

-.1805E-01 .07023 -.0000150

-«17*7E-C1 .07011 -.00001**

- . 1 69* E -0

.07000 -.0000139

-.16A3E-01 .06989 -.000013*

-.1595E-01 . 06978 -.0000129

-.1550E-01 .06968 -.0000125

-.1508E-01 .06950 -.0000120

- • 1 *6 7E-0

.069*9 -.0000116

-. 1*29E-01 .069*0 -.0000113

- . 1 3 93 E -0

.06931 -.0000109

-.1358E-01 .06922 -.0000106

-.1325E-01 .0691* -.0000103

- . 1 29* E -0

. 069C6 -.0000100

- . 1 26* E -0

.06898 -.0000098

-•1236E-01 .06890 -.0000095

73
Tabl e 10. Cont i ruled

HYDROGEN SULFIDE ISOCHORE AT 8.000 MQL/L

T P Z DP/no DD/DT OP/DT D2P/DT2

K MPA MPA-L/MOL MOL /L /K MPA/K M? A /< /K

372.609 8 . 8*36 .35682 .0297 -.*061E+01 .12061 -.3031997

376.000 9.2*39 .36961 .08*6 -.1378E+01 .11656 -.0006050

3 8* .000 10.1631 .39789 .2116 -. 5373E+00 .11367 -.0002332

392.000 11.0659 .*2**0 .3*21 - • 3 27 8 E *0 0 .11215 -.00015*2

*00.000 11.9586 .**9*6 . *756 -.2336E+00 .11109 -.0001151

*08.000 12.8*39 .*7327 .6113 -.180*E+00 .11027 -.0000920

*16.000 13.7233 .*9595 .7*88 - . 1 *6* E *0 0 .10959 -.0000767

*2*. 000 1* .5977 .51760 .8878 -•1228E+00 .10903 -.0003658

*32.000 15. *679 .53830 1.0280 -.1056E+00 .10853 -.0000576

**0.000 16.33** .55612 1.1692 - • 92*5 E-0 1 .10810 -.0000512

**8.000 17.1976 .57712 1.311* -.821*E-01 .10771 -.0000*61

*56.000 18.0579 .59536 1 .*5*3 -• 7382E-01 .10736 -.0000*19

*6* .000 18.9155 .61288 1.5979 -.6699E-01 .1070* -.0000385

*72.000 19.7706 .62973 1.7*20 -•6128E-01 .1067* -.0000356

*eo.ooo 20.623* .6*59* 1.8866 - . 56* 3 E ~0

.106*7 -.0030331

*88.000 21 .*7*2 .66156 2 .0316 -• 5 22 8E -0

.10621 -.0000310

*96.000 22.3229 .67662 2.1770 -.*868E-01 .10597 -.0000291

50*. 000 23.1698 .6911* 2.3227 -.*553E-01 .10575 -.0000275

512.000 2*. 01*9 .70515 2. *687 -,*275E-01 .10553 -.0000261

520.000 2* .8583 .71869 2.61*8 - . *02 6 E-0.10533 -.00002*9

528.000 25.7001 .73177 2.7612 -.3807E-01 . 10513 -.0000238

536.000 26.5*05 .7***2 2.9078 - • 3 60 9E-0.10*95 -.0000228

5** .000 27.3793 .75665 3.05** -.3*30E-01 .10*77 -.0000219

552.000 28.2168 .76850 3 .2012 -.3267E-01 .10*60 -.0000210

560.000 2 9.0529 .77997 3.3*81 -.3119E-01 . 10**3 -.0000203

568.000 29.8877 .79108 3. *950 - . 2 98 * E -0

.10*27 -.0000196

576.000 30.7213 . 80185 3.6*19 -. 285 9 E—0.10*12 -.0000190

5 8* . 000 31.5536 .81229 3 .7889 -.27**E-01 .10397 -.000018*

592.000 32.38*8 . 822*2 3.9359 -.2638E-01 .10382 -.0000179

600.000 3 3 • 2 1 * p .83225 * .0829 -.2539E-01 .10368 -.000017*

608.000 3* .0*37 .8*180 *.2299 -.2**8E-01 .1035* -.0000170

616.000 3*. 8715 .85107 * .3768 - . 2 36 3 E -0

.103*1 -.0000166

62* .000 35 . 6982 . 86007 *.5238 -.2283E-01 .10328 -.0000162

632.000 36.5239 . 86883 * .6706 -.2208E-01 .10315 -.0000158

6*C • 000 37,3*86 .8773* *.817* - . 2 1 3 9 E —0 1 .10303 -.0000155

6*8.000 38.172* .88562 * .96*2 -.2073E-01 .10290 -.0000151

656.000 3e . 99 51 . 89368 5.1109 - . 201 1 E-0

.10278 -.00001*8

66*. 000 39.8169 .90152 5.2575 - . 1 95 3 E -0

.10267 -.00001*6

672.000 *0.6377 .90915 5. *0*0 -.1 898E-01 .10255 -.00001*3

680.000 *1 .*577 .91658 5.5505 - . 1 8*6 E -0

.102** -.30031*0

688.000 *2. 2767 .92382 5.6968 - • 1 796E-0

.10233 -.0000139

696.000 *3.09*9 .93087 5.8*31 — • 1 7* 9E — 0 1 .10222 -.0000135

70* .000 *3.9122 .93775 5.9892 -.17C5E-01 .10211 -.0000133

712.000 **.7287 . 9***5 6.1353 - . 1 66 3 E-0

.10200 -.0300131

720.000 *5 . 5**3 .95099 6.2812 -.1622E-01 .10190 -.0000129

74
Table 10. Continued

HYDROGEN SULFIDE .ISOCHORE AT 9.000 MOL/L

T P Z DP /DD DO/DT DP /DT D2P/DT2

K MPA MPA-L/MOL MOL/L/K MP A/K M? A /< /<

373.261 8.9417 .32013 .005? -.2574E+C2 .13586 -.0093263

376.000 9.3069 .33078 .0477 -•2772E+01 .13220 -.0004676

3 84 . 000 10.3550 .36036 .1806 -.7210E+00 .13023 -.0001510

392.000 11.3929 .38839 .3212 -.4025E+00 .12928 -.0000955

400.000 12.4242 .41508 .4663 -.2758E+00 .12862 -.0000714

408.000 13.4511 .44057 .6148 -.2084E+00 .12811 -.0000577

416.000 14.4742 .46497 . 7657 -.1667E+00 .12769 -.0000489

424.000 15.4942 .48834 .9188 -.1386E 00 .12732 -.0000427

432.000 16.5115 .51077 1.0735 -•1183E 00 .12700 -.0000382

440.000 17.5263 .53230 1.2296 -.1030E+00 .12671 -.0000347

448.000 18.5389 .55300 1 .3869 -.9117E-01 .12644 -.0000320

456.000 19.5494 .57291 1 . 5453 -. 8166E-01 .12619 -.0000299

464.000 20.5590 .59208 1.7045 -.7390E-01 .12596 -.0000201

472.000 21.5648 .61056 1 .9644 -.6744E-01 .12574 -.0000266

4 80.000 22.5699 .62836 2.0250 -.6199E-01 .12554 -.0000253

488.000 23.5734 .64554 2.1862 -.5733E-01 .12534 -.0000243

4 96.000 24.5753 .66212 2.3478 -•5330E-01 .12515 -.0000234

504.000 25.5758 .67814 2.5099 -.4979E-01 .12496 -.0000226

512.000 26. 5748 .69362 2.6723 -.4670E-01 .12479 -.0000219

520.000 27.5724 . 70858 2.0350 -.4396F-01 .12461 -.0000213

528.000 2P . 5686 .72306 2.9979 -.4151E-01 .12444 -.0000208

5 36.000 29.5635 .73708 3.1611 - . 3 93 2 E -0 1 .12428 -.0000203

544 . 000 30. 5571 .75064 3.3245 -.3734E-01 .12412 -.0000193

552.000 31 .5494 . 76379 3 .4880 -•3554E-01 .12396 -.0000194

560.000 32.5405 .77653 3.6516 -.3391E-01 .12381 -.0000191

568.000 33.5304 .78889 3.8153 -.3241E-01 .12366 -.0000187

576.000 34. 5190 .90086 3.9791 -. 3104E-01 .12351 -.0000184

584.000 35.5065 .81249 4 .1429 -.2979E-C1 .12336 -.0000181

592.000 36.4928 . 92377 4.3068 - , 2 86 1 E -0 1 .12322 -.0000179

600.000 37.4780 .83473 4 .4707 - . 2 75 3 E-0

.12308 -.0000176

609.000 38.4621 .84539 4.6345 -.2653E-01 .12294 -.0000173

616.000 39.4451 .85572 4.7983 -.2559E-01 .12280 -.0000171

624. OOC 40.4269 . 86578 4 .9621 - . 247 2 E -0

.12267 -.0000169

632.000 41.4077 .87556 5.1259 -•2390E-01 .12253 -.0000167

640.000 42.3874 .88507 5.2896 -.2314E-01 .12240 -.0000165

648.000 43.3661 . 89433 5.4532 -.2242E-01 .12227 -.0000163

656.000 44.3437 .90334 5.6168 -.2175E-01 .12214 -.0000161

664.000 45.3203 .91211 5.7802 -.211 1 E-0

.12201 -.0000159

672.000 46.2959 .92065 5.9436 -•2051E-C1 .12108 -.0000157

680.000 47.2705 .92897 6.1069 — , 1 994E-0 1 .12176 -.0000155

ftee.ooo 4e.2440 .93708 6.2700 - . 1 940E-0 1 .12164 -.00001 54 696.000 49.2166 .94498 6 .4331 -.1889E-01 .12151 -.0000152

704.000 50.1802 .95269 6.5960 -. 1 840E-01 .12139 -.0000150

712.000 51.1589 .96020 6.7588 -.1794E-01 .12127 -.0000149

720.000 52.1286 .96753 6.9215 -.1750E-01 .12115 -.0000147

75
Table 10. Cunt i nued

HYDROGEN SULFIDE ISOCHORE AT 10.200 MOL/L

T P Z OP/DD OD/DT DP/DT D2P/DT2

K 8 P A MPA-L/MOL MOL /L /K MPA/K mpa/</k

373.400 8.9629 .28303 0.0000 -R .15238 0.0000000

376.000 9.3591 .29350 .0448 -•3403E+01 .15238 -.0000006

384.000 10.5761 .32482 .1988 -.7663E+00 .15236 -.0000024

392.000 11 .7969 .35485 .3620 -.4208E+00 .15234 -.0000040

400.000 13.0154 .39367 . 5303 -.2872E+00 . 15230 -.0000055

408.000 14.2337 .41136 .7023 -.2168E+00 .15225 -.0000069

416.000 15.4514 .43796 . 8771 -.1735E+00 .15219 -.0000081

424.000 16.6687 .46355 1 .0542 -.1443E400 .15212 -.0000092

432.000 17.8854 .48818 1.2331 -.1233E+00 .15204 -.0000102

440.000 19.1014 .51189 1.4136 -.1075E+00 .15196 -.0000111

448. OCO 20.3167 .53474 1.5953 - . 9 52 0 E -0 1 .15187 -.0000119

456.000 21.5312 .55676 1 .7781 -.8535E-01 .15177 -.0000126

464.000 22.7450 .57800 1.9619 -.7731E-01 .15167 -.0000133

472.000 23.9579 .59851 2.1464 - .7061 E-0 1 .15166 -.0000139

4 80.000 25.1699 .61831 2.3317 -.6495E-01 .15144 -.0000145

488.000 26.3810 .63743 2.5175 -.6011E-01 .15133 -.0000149

496.000 27.5911 .65592 2.703° -.5592E-01 .15120 -.0000154

504.000 28.8002 . 6 7 3 ° 0 2 .8905 -.5227E-01 . .15108 -.0000153

512.000 30.0083 .69109 3.0776 - . 490 5 E -0

.15095 -.0000161

520.000 31.2154 .70783 3.2650 -.4619E-01 .15082 -.0000154

528.000 32. 4216 .72404 3.4526 -.4364E-01 .15069 -.0000167

536.000 33.6265 . 73974 3.6405 -.4136E-01 .15055 -.0000169

544.000 34.8304 .75496 3 . ° 2 8 5 -.3929E-01 .15042 -.0000172

552.000 36.0332 .76971 4.0166 -.3741E-01 .15028 -.0000173

560.000 37.2348 .78402 4.2048 -.3571E-01 . 15014 -.0003175

568.000 38.4354 . 79790 4.3931 -.3414E-01 .15000 -.0000176

576.000 39.6348 .81137 4.5814 -.3271E-01 .14986 -.0000177

584.000 40.8331 .82445 4 .7698 -.3139E-01 .14972 -.0003178

592.000 42.0303 .83715 4.9581 -.3017E-C1 .14957 -.0000179

600.000 43 .2263 .84949 5.1464 -.2904E-01 .14943 -.0000180

608.000 44.4212 .86149 5.3347 -.279°E-01 .14929 -.0000180

616.000 45.6149 . 87315 5.5229 -•2700E-01 .14914 -.3000180

624.000 46.8075 .88449 5.7110 -.2609E-01 .14900 -.0000181

632.000 47.9989 .89552 5.8991 -.2523E-01 .14885 -.0300181

640.000 49.1691 .90626 6.0870 - . 244 3 E-0

.14871 -.0000131

648.000 50.3782 .91671 6.2749 -.2368E-01 .14856 -.0000130

656.000 51 . 5661 . 92688 6.4626 -.2297E-01 .14842 -.0000180

664.000 52.7529 .93679 6.6502 -•2230E-01 .14828 -.0000180

672.000 53.9385 . 94644 6.8377 -.2166E-01 .14813 -.0000179

6 80.000 55.1230 .95585 7.0250 - . 2 107 E-0

.14799 -.0300179

688.000 56.3064 . 96501 7.2121 -.2C50E-01 .14785 -.0000173

696.000 57 .4886 .97395 7.3991 - . 1 996 E — 0

.14770 -.0000178

704.000 58.6696 .98266 7.5660 - • 1 94 5 E -0

.14756 -.0000177

712.000 59.8495 .99116 7.7726 -.1 897E-01 .14742 -.0000176

720.000 61.0283 .99945 7.9591 -.1850E-01 .14728 -.0000176

76
Table 10. Continued

hydrogen sulfide isochore at 11.000 mol /L

T p Z DP/DD DD/DT DP/DT D 2 p / 0 T2

K MPA MP A-L/MOL MOL /L /K MP A/K MP A /< l< 373.359 8.9567 .26280 .0019 -.8850E*02 . 16A90 .0187807

376.000 9.398A .27330 .0555 -.3027E*01 .16801 .0003320

38A.000 10.7A89 .30606 .2313 -. 732?E*00 .16936 . 0 0 C 0 9 9 3 392.000 12.1063 .33767 • A1 5 6 -.A089£ +00 .16996 .0000532

A 00 , 0 00 13.A676 .36813 .60A9 -.28166*00 , 1703

.0000391

A 08 , 000 1A .8315 . 3 97 A 6 .7977 21396*00 .17060 .0000275

A 1 6 . 000 16.1971 . A7571 .9931 -.17206+00 .17079 . 000019A

A2A. 000 17.56A0 . A 5 2 9 3 1.1907 -.1 A35E *00 .17092 .0000133

A32 .000 18.9317 • A7916 1.3900 -.12306*00 .17101 .0000035

AAO. 000 20 .2999 . 50AAA 1 .5907 -.1075E*00 .17106 .OOOOOA6

A A 8 . 000 21 . 6685 . 5 2 8 8 A 1.7927 -.95A36-01 .17108 .000001A

A 56 . 000 23.0372 .55238 1.9957 -.85736-01 .17108 - , 0000 0 1 A A6A.OOO 2A.A057 .57510 2.1995 - . 7777 E -0

.17106 -.0000037

A72 .000 2 5 . 77 A

.59705 2 .A0A1 -.711AE-01 .17102 -.0000058

A 80 . 000 27.1A20 .61826 2.6092 -.6552E-01 . 17097 -.0000075

A 8 8 . 000 28.5095 .63877 2.81A9 - .6071 E-0.17090 -.0000091

A96.000 2 9 , 876

.65859 3.0210 -. 565AE-01 .17082 -•00001DA

5 OA .000 31 . 2A27 .67778 3.2275 -.5290E-01 .17073 -.0000116

512.000 32.6082 .69635 3 . A 3 A 3 -. A9696-0

. 1706A -.0000127

520.000 33.9728 . 7 1 A 3 3 3.6A13 -.A683E-01 .17053 -.0000136

528.000 35.3367 .73175 3.8A85 -.AA28E-01 .170A2 -.0C001 A5

536.000 36.6995 . 7 A 8 6 3 A .0559 -.A199E-01 .17030 -.0000152

5AA .000 3 8 . 0 61. 76A99 A. 2633 - . 3992E -0 1 .17018 -.0000159

552.000 39.A223 .78086 A.A709 -.3 803E-01 .17005 -.0000165

560.000 AO. 7822 .79626 A. 6785 -.36326-01 .16991 -.0000170

568.000 A2.1A09 .81120 A .8860 -•3A75E-01 .16977 -.0000175

576.000 A3. A936 . 82570 5.0936 -.3330E-01 .16963 -.0000179

5 8 A . 000 AA . 855 1 . 83979 5.3011 -.3197E-01 . 169A9 -.0000182

592.000 A6.210A .953A7 5.5086 -.307AE-01 , 1 693 a -.0000135

600.000 A7 . 56A 5 . 86677 5 .7160 -.2960E-01 .16919 -.0000188

608.000 A8 . 9175 . 87969 5.9233 -.285AE-01 . 1690A -.0000191

616.000 50.2692 .89226 6.1305 -.2755E-01 .16889 -.0000193

62A.OOO 51.6197 . 90A A 9 6.3376 -. 2662E-01 .16873 -.000019A

632.000 52 .9689 .91638 6.5AA5 -.25766-01 .16858 -.0000196

6 AO . 000 5A. 31 69 .92795 6.7513 -.2A95E-01 . 168A2 -.0000197

6 A 8 .000 55.6636 .93922 6.9579 -.2A18E-01 .16826 -.0000198

656.000 57.0091 .95019 7 . 16 A3 -.23A6F-01 .16810 -.0000199

6 6 a . 000 58.3533 . 96088 7.3706 -.22796-01 • 16799 -.0000200

672.000 59.6962 .97129 7.5767 -.221AE-01 .16778 -.0000200

680.000 61.0378 • 981 A3 7.7626 -.215AE-01 .16762 -.0000201

6ee.ooo 62.3781 .99132 7.9883 - . 2096 E-0

.167A6 -.0000201

696.000 63 .7172 1.00096 8.1938 -.20A2E-01 .16730 -.0000201

7 OA . 000 65.05A9 1.01037 8.3991 -.19906-01 . 1671 A -.0000201

712.000 66.391A 1 . 0195 A 8 . 60A2 - . 1 9A 1 E-0

.16698 -.0000201

720.000 67.7266 1 .028A9 8.8090 -.1B9AE-P1 .16682 -.0000200

77
Table 10. Co nt i n ued

hydrogen sulfide isochore at 12.000 mol/l

T P Z DP/DD DD/DT DP/DT D2P /DT?

K P & MPA-l/MOL 00 L / L /

MPA /K 0P A/</K

372.990 0.9000 .23917 .0237 -.791 5E+01 .10745 .0045988

376.000 9 . A729 .25251 .1028 -•1861E+01 .19143 .0005925

3 PA .000 11.0167 .28754 .3156 -.6150E+00 . 19AC7 .0002057

392.000 12 .57A8 .32151 .5339 -.3659E+00 .19535 .0001257

A 00 . 000 1 A , 1 A 1

.35433 .7559 -.2595E+00 .19619 .0000830

A 08 . 000 15.7132 .38600 .9807 -.2007E+00 .19679 .0000852

A 16 .000 17.2094 .41655 1.2076 -.1633E+00 .19725 .0000495

A2A. 000 18.8689 . AA603 1 .4361 -.1376E+00 .19760 .0000378

A 3 2 . 000 20. A507 . A7AA7 1.6661 -.lieBE+OO .19786 . 0000288

AAO. 000 22 .03AA .50192 1.8972 -•1044E+00 .19806 .0000215

AA9. 000 23.6195 .52842 2.1292 -.9309E-01 .19821 .0000155

A 56 . 000 25.2056 .55401 2.3619 - . 83 96 E-0 1 .19831 .0000104

A 6 A . 000 26. 792A . 57873 2. 5954 -. 76AAE-01 .19838 .0000062

A 72 . 000 28.3796 .60262 2.8293 - . 701 3 E -0

.19841 .0000025

A 80.000 29.9669 .62572 3.0636 - .6477 E-0

.19042 -.0000007

A 08 . 000 31 .55A2 .64807 3.2983 -•6015E-01 .19840 -.0000035

A 96 . 000 33.1A13 .66968 3.5333 - . 561 AE -0. 19836 -.0000059

50A.000 3A .7279 .69061 3.7685 -•5262E-01 .19831 -.0000081

512.000 3 6 . 3 1 A

.71067 A. 0038 -.4951E-01 .19023 -.0000100

520.000 37 . 8997 .73049 A. 2392 -•4674E-01 .19815 -.0000116

520.000 39. A8A5 .74951 4.4747 -. AA26E-01 . 198C5 -.0000131

536.000 A 1 . 06 8 A .76794 4.7102 -.4202E-01 .19794 -.0000145

5AA .000 A 2 . 6 5 1 A .78581 A. 9457 -. A000E-01 .197e2 -.0000156

552.000 AA .2335 .80315 5.1812 -•3816E-01 .19769 -.0000167

560.000 A 5 . 8 1 A A .81997 5.4165 -.3647 E-0 1 .19755 -.0000176

560.000 A 7 . 3 9A 3 .83630 5.6518 -.3493E-01 .19741 -.0000185

5 7* . 000 A8.9729 .85215 5.8869 -•3351E-01 .19726 -.00001 92

5 8

. 0 00 50.5503 . 86755 6.1219 -•3220E-01 .19710 -.0000199

592.000 52.1265 .88251 6.3568 -.3098E-C1 .19694 -.0000205

600.000 53.7013 .09705 6.591A -.2985E-01 .19677 -.0000210

600.000 55.27A8 .91119 6.0259 -•2880E-01 .19660 -.0000215

616.000 56 . 8A70 . 92 4<?3 7.0602 -•2702E-O1 .19643 -.0000219

6 2 A . 000 58. 4177 .93330 7.2942 - . 2 691 E -0 1 . 19625 -.0000222

632.000 59.9870 .95131 7.5281 -

2 60 5 E-0.19607 -.0000226

6 AO . 000 61 . 55A9 .96397 7.7616 - . 252 A E-0

.19509 -.0000228

6A8.000 63.1213 .97630 7.9950 -•2443E-01 .19571 -.0000231

656.000 6A. 6062 .98830 8.2281 - . 2376E-0

.19552 -.0000233

6 6 A

,

000 66 .2496 1.00000 8.4609 -.2309E-01 .1953- -.0000235

672.000 67.8115 1.01139 8.6935 -•2245E-01 .19515 -.0000236

600.000 69.3720 1 .02249 8.9257 -.218AE-01 .19496 -.0000237

680.000 70.9300 1.03331 9.1578 -. 2127E-01 .19477 -.0000233

696.000 72 . A 682 1.0A386 9.3895 -.2072E-01 .19450 -.0000239

70A .000 7 A , 0 A A

1 .05414 9.6209 - . 202 0 E -0.19438 -.0000240

712.000 7 5 . 5 9 8 A 1.06418 9.8521 -.1971 E-0

.19419 -.0000240

720.000 77.1511 1.07397 10.0830 -.1924E-01 .19400 -.0000241

78
Table 10. Continued

HYDROGEN SULFIDE ISOCHORE AT 14.000 MOL /L

T P Z DP/DD DD/DT DP /DT D2P/DT2

K 6<PA HPA-L/MOL MOL/L/K MPA/K HR A /< /<

370.077 8.4733 .19670 .2630 -.9595E+00 .25237 .0011726

376.000 9.9822 .22807 .5003 -.5127E+00 .25651 .0004588

384.000 12.0462 .26950 .8114 -.3195E+00 . 25923 . 000259?

392.000 14.1273 .30961 1 .1204 -•2329E+00 .26095 .0001777

400.000 16.2200 .34836 1.4289 -.1835E+00 .26217 .0001311

408.000 18.3212 .38577 1 .7373 -.1514E+00 .26308 .0001002

416.000 20.4288 .42188 2.0457 -.1289E+00 .26379 .0000777

424.000 22.5414 .45672 2.354? -.1123E+00 .26434 .0000605

432.000 24.658C .49035 2.6626 - . 9 94 4 E -0

.26477 .0000469

440.000 26.7775 .52282 2 .9709 -.8923E-01 .26510 .0000357

448.000 28 . 8993 .55417 3.2792 -. 8092E-0

. 26535 .0000265

456. OOC 31 .0228 .58446 3.5873 -•7402E-01 .26553 .0000186

464.000 33.1476 .61372 3.8953 -.6820E-01 .26565 .0000119

472.000 35.2731 .64200 4.2030 -.6322E-01 .26572 .0000061

4 80.000 37. 3989 .66935 4.5106 -. 5892E-01 .26575 .0000011

488.000 39.5249 .69580 4.8178 -.5516E-01 .26574 -.0000033

496.000 41 .6507 .72140 5.1247 -•5185E-01 .26570 -.000007?

504.000 43.7760 .74618 5 .4313 -.4 891E-01 .26562 -.0000106

512.000 45.9006 .77017 5.7376 -.4628E-01 .26553 -.0000136

520. COO 48.0243 .79340 6.0434 -.4392E-01 .26541 -.0000162

526.000 50.1471 .81592 6.3489 -.4178E-01 .26527 -.0000186

536. OOC 52 ,26e6 .93774 6 .6540 -.3984E-01 .26511 -.0000207

544.000 54.3888 .85891 6.9587 -.3B07E-01 . 26494 -.0000226

552.000 56.5075 .87943 7.2630 - • 364 5 E-0.26475 -.0000243

560. COO 58.6247 .89935 7.5668 -.3496E-01 .26455 -.0000258

568.000 60.7403 .91868 7.8702 -.3359E-01 . 26434 -.0000272

576.000 62.9541 .93745 8.1731 -.3232E-01 .26411 -.0000234

5 84.000 64.9661 .95567 8.4755 -•3113E-01 .26386 -. 0000294

592.000 67.0762 . 97 3 3 e 8.7775 -.3004E-C1 .26364 -.0000304

600.000 69.1844 .99059 9.0789 - • 2 90 1 E-0

.26340 -.0000312

608.000 71 . 2906 1.00731 9.3799 -. 2805E-01 . 26314 -.0000320

616.000 73 .3947 1.02358 9.6805 - . 2 716 E-0

.26289 -.0000327

624.000 75.4967 1 .03939 9.9805 -.2631 E-01 .26262 -.0000332

632.000 77.5966 1.05478 10.2800 -.2552E-01 .26235 -.0000338

640.000 79.6944 1.06975 10.5790 -.2477E-0

.26208 -.000034?

648.000 81.7899 1.08433 10.8776 -.2407E-01 .26181 -.0000346

656.000 83.8833 1.09852 11.1756 -. 2340E-01 .26153 -.0000350

79
Ta bl e 1 (J. Conti nued

HYDROGEN SULFIDE ISOCHORE AT 16.000 MOL/L

T P Z DP/DO DD/DT DP/DT D2P/DT2

K MPA mpa-l/mol MI3L /L /K HOA /K MPA /K/K

362.932 7.5022 .15538 1.0347 -.3329E+C0 . 34440 . 0004766

364.000 7.8702 .16253 1.0937 -•3154E+00 . 34488 .0004371

366.000 9.2529 .18901 1.3116 - . 2641 E *00 .34641 .0003334

372.000 10.6410 .21502 1.5264 -„2277E*00 .34760 .0002680

376.000 12.0334 .24057 1.7391 -.2004E+00 . 34858 .0002222

380.000 13.4294 .26565 1 .9502 -•1792E 00 .34939 .0001878

3 64.000 14.8284 .29C27 2.1601 -.1621E+00 .35009 .0001607

366.000 16.2300 .31443 2 .3691 - • 1 460E + 00 .35069 .0001387

392.000 17. 6338 .33815 2.5772 - • 1 363E *00 . 35120 .0001203

396.000 19.0395 .36141 2.7847 -•1263E+00 .35165 .0031047

400.000 20.4469 .38425 2.9915 -•1177F*00 .35204 .000091

404.000 21.8558 . 40666 3 .1978 -.1102E+00 .35238 .0000793

408.000 23.2659 .42865 3.4036 -.1036E+00 . 35268 .0000688

412.000 24.6772 .45024 3.6089 -.9780E-01 .35294 .0000595

416.000 26.0894 .47143 3.8138 -.9260E-01 .35316 .0000511

420.000 27.5024 .49223 4.0183 -. 8793E-01 .35335 .0030435

424.000 28.9161 .51265 4.2225 -.8372E-01 .35351 .0000366

428.000 30.3304 .53269 4.4262 -.7990E-01 .35364 .0000303

432.000 31.7452 .55238 4.6296 -.7641F-01 .35375 .0000245

436.000 33.1604 .57171 4.6327 - .7 32 2 E-0

.35384 .0030192

440.000 34.5758 .59070 5.0355 - . 702 8 E -0

.35390 . 0000143

444.000 35.9916 .60934 5.2379 -.6757E-01 .35395 .0000097

448.000 37.4074 .62766 5.4401 -.6507E-01 . 35396 .0030055

452.000 38.8234 .64565 5.6419 -.62 74 E-0

.35399 .0300016

456.000 40.2394 .66333 5.8435 - . 605 3 E -0

. 35399 -.0000021

460.000 41.6553 .68070 6.0448 -.5856E-C1 .35398 -.0000055

464.000 43.0712 .69777 6.2458 - . 5667 E -0 1 .35395 -.0000086

468.000 44 .4869 .71455 6 .4465 -.5490E-01 .35391 -.0000116

472.000 45.9024 .73103 6.6470 -•5324E-01 .35386 -.0000144

476.000 47.3177 .74724 6.8472 - . 5 16 7E -0

.35379 -.0300170

4 80.000 48.7328 .76317 7.0471 -.501 9E-01 .35372 -.00001 94

484.000 50.1475 .77884 7.2468 -•4880E-01 .35364 -.0000217

488.000 51. 5619 .79424 7.4462 -•4748E-01 .35355 -.0000239

492.000 52.9759 . 80939 7.6454 -•4623E-01 .35345 -.0000259

496.000 54. 3e94 .82428 7.8443 - . 4 504 E -0.35334 -.0000278

500.000 55 . 8026 .83893 8 .0429 -.4392E-01 .35323 -.0000296

504.000 57.2152 .85335 8.2413 -.4285E-01 .35310 -.3000313

508.000 58.6274 . 86752 8.4395 - .4 1 82 E-0 1 . 3 5 2 9 ^ -.0000329

512.000 60.0390 .88147 8.6374 -.4085E-01 .35284 -.0000344

5 16.000 61.4501 . 89519 8.8351 — . 3 99 2 E -0 1 .35270 -.0000358

520.000 62.8606 . 90870 9.0325 -. 3903E-0 1 . 35255 -.0000372

524 .000 64.2705 .92199 9.2297 — • 3 81 8 E-0 1 .35240 -.0000384

528.000 65.6798 .93507 9.4266 -.3737E-01 .35225 -.0000396

532.000 67 .0885 .94794 9.6234 -.365 9E-C

.35209 -.0000407

536.000 68.4965 . 96061 9.8198 -.3584E-01 .35192 -.0000418

540.000 69.9039 .97309 10.0161 -.3512E-01 .35175 -.0000428

544.000 71.3105 .98537 10.2121 -•3443E-01 .35158 -.0003437

548.000 72 .7165 . 99746 10.4079 -•3376E-G1 .35140 -.0000446

552.000 74.1218 1.00937 10.6034 -.3312E-01 . 35122 -.0000454

556.000 75.5263 1.02110 10.7987 -•3251E-01 .35104 -.0000462

560.000 76.9301 1 .03265 10.9938 -.3191E-01 .35065 -.0000469

564 . 000 78.3331 1.04402 11 .1886 -.3134E-01 .35066 -.0303476

568.000 79.7354 1.05523 11.3333 - . 3 07 9E -0 1 . 35047 -.0000483

572.000 81.1369 1.06627 11.5777 - . 3 02 5 E -0

.35028 -.0300489

576.000 82.5376 1.07714 11.7718 -.2974E-01 .35008 -.0000495

580.000 83.9375 1.08786 11 .966 8 -.2924E-C1 .34986 -.0000500

80
Table 10. Continued

hydrogen sulfide isochore at 10.000 hol/l

T P Z DP/DD DD/DT DP/DT D2P/0T?

K MC& MPA-L /MOL MOL/L/K HP A /K M 0 A / K / K 350.667 6.0444 .11517 2.6721 -.1744E+00 .46610 .0001915

352.000 6.6660 .12654 2.7658 - • 1 6 86 E >00 .46635 .0001803

356.000 8.532e .16015 3.0453 ~ • 1 534 E 00 .46701 .0001514

360.000 10.4019 .19306 3 .3227 -.1407E+00 .46757 .0001280

364.000 12.2732 .22529 3.5985 - . 1 301 E +00 .46804 .0001034

368.000 14.1462 .25685 3.8727 -.1210E+00 .46844 .0000916

372.000 16.0206 .29776 4.1456 -.1131E+00 .46878 .0000770

376.000 17.8963 .31803 4 .4174 - • 1062 E>00 .46906 .0000641

380.000 19.7730 . 34768 4.6881 -. 1001E+00 .46929 . 0000527

384.000 21 .6506 .37673 4.9578 - • 9470 E-0

.46948 .0000424

380.000 23.5288 .40519 5.2266 -.8985E-01 .46963 .0000331

392.000 25.4076 .43308 5 .4946 -• 8549E-01 .46975 .0000246

396.000 27.2867 .46041 5.7617 -.8154E-01 .46983 .0000169

400.000 29.166? .48720 6.0282 -.7795E-01 .46988 .0000098

404.000 31 .0457 .51347 6.2939 - . 746 6 E-0

.46991 .0000033

408.000 32.0254 .53922 6.5589 -.7164E-01 .46991 -.0000028

412.000 34 . 8050 . 56446 6.8233 -.6887E-01 .46989 -.0000084

4 16.000 36.6845 .58922 7.0870 - . 6630E-0

.46964 -.0000136

420.000 36.5637 .61351 7.3501 - ,6391 E-0 1 .46978 -.0000184

424.000 40.4427 .63733 7.6127 -.6170E-01 .46970 -.0000229

428.000 42. 3213 .66070 7.8747 -. 5963E-01 .46960 -.0000271

432.000 44 .1994 .63363 8.1361 - • 5770E-0

.46948 -.0000310

436.000 46.0771 .70614 0 . 3970 -.5589E-01 .46935 -.0000347

440.000 47 ,9542 .72822 8 .6574 -.5420F-01 .46920 -.0000302

444.000 49.8307 .74990 8.9172 - . 5260E-C 1 . 46904 -.0000414

448.000 51 .7065 .77118 9.1766 -.5109E-01 .46887 -.0000444

452.000 53,9016 .79208 9.4355 - • 4967 F-0

.46869 -.0000473

456.000 55.4560 .81260 9 .6938 -.4833E-01 .46849 -.0000499

460.000 57.3296 .83275 9.9518 -. 4706E-01 .46829 -.0000525

464.000 59.2023 .85253 10.2092 -.4585 E-0

.46807 -.0000548

468.000 61.0741 .97197 10.4662 - . 4 47 0 E-0

.46785 -.0000570

472.000 62.9451 .89107 10.7227 - . 4 36 1 E-0

.46762 -.0000591

476.000 64.9151 .90983 10.9788 -.4257E-01 .46738 -.0000611

490.000 66.6841 .92827 11.2345 -.4150E-O1 .46713 -.0000629

404.000 68.5521 .94638 11.4097 -.4063E-01 .46607 -.0000647

488.000 70.4191 .96419 11.7446 - , 3 97 3 E-0

.46661 -.0000663

492.000 72.2850 .98169 11.9990 -.3887E-01 • 4 6 6 3 -.0000679

496.000 74.1498 .99009 12.2529 -.3804E-01 .46607 -.0000693

500. OOC 76.0135 1.01581 12.5065 -.3724E-01 .46579 -.0000707

504.000 77.8761 1.03244 12.7597 -.364 8E-0

.46550 -.0000719

508.000 79.7375 1.04879 13.0124 - . 3 57 5 E -0

.46521 -.0000731

512.000 81.5978 1.06488 13.2640 -.3505E-01 .46492 -.0000743

516.000 83.4569 1.08070 13.5167 -.3437E-01 .46462 -.0000753

81
Table 10. Continued.

HYDROGEN SULFIDE ISOCHORE AT 20.000 MOL /L

T P Z DP/DO DD/DT DP/DT D2P/DT2

K MPA NPA-L/MOL MOL /L /K MPA /K IP A /K /K

332. 918 4.3235 .07810 5.5111 -• 1 129E *00 .62217 .0000262

336.000 6.2413 .11170 5.7819 -.1076E*00 .62223 .0000180

34C.000 9.7303 .15441 6.1321 -.101 5E*00 .62229 .0000082

344.000 11.2195 .19613 6.4809 -.9602E-01 .62230 -.0000010

348.000 13.7097 .23699 6.8284 -.9H3E-01 . 62228 -.0000095

352.000 16.1977 .27672 7.1747 -.8672E-01 .62222 -.0000176

356.000 18.6*64 .31565 7.5199 -.*273E-01 .62214 -.0000251

360.000 21.174* .35371 7.8641 -.7 910 E-0

.62202 -.0000321

3 64.000 23.6626 .39093 8.2072 - . 7 577 E -0

.62188 -.0000397

369.000 26.1498 .42732 8.5492 -•7272E-01 .62171 -.0000449

37? .000 28.6363 .4629? 8.8904 -.6991E-C1 .62152 -.0000507

376.000 31.1220 .49775 9,2306 - . 6 73 1 E -0

.62131 -.0000552

380.000 33.6067 .53183 9.5698 - . 6490E -0 1 .62107 -.0000614

3*4.000 36.0905 .56519 9 .90*3 -.6266E-01 .62082 -.0000662

3*8.000 3*. 5733 .59784 10.2458 - . 605 7 E -0 1 .62054 -.0000708

3 92.000 41.0549 .62981 10.5826 - . 5 86 1 E -0 1 .62025 -.0000751

396.000 43.5353 .66112 10.9195 -. 5678E-01 .61994 -.0000792

400.000 46.0144 ,69178 11.2536 -.5506E-01 .61962 -.0000331

404.000 4e.492? .721*1 11.58*0 - • 5344 F-0

.61928 -.0000367

40* .000 50.9686 .75124 11 .9216 -.5192F-01 .61893 -.0000901

412.000 53.4436 .78007 12.2544 -.5048E-01 .61856 -.0000933

416.000 55.9171 . 80832 12.5866 - . 4 91 1 E -0 1 .61818 -.0000963

420.000 58.3890 .83602 12.9190 -.4782E-01 .61779 -.000099?

424 . 000 60.8594 .86317 13 .24*7 -.4660E-01 .61739 -.0001019

428.000 63.3281 .89979 13.5787 -.4544E-01 .61697 -.0001044

432.000 65.7951 .91589 13.9080 - ,443 3E-0

.61655 -.0001059

436.000 68.2605 . 94149 14.2367 -.4328F-01 .61612 -.0001090

440.000 70.7241 .96660 14.5647 -.4227E-01 .61568 -.0001112

444.000 73.1659 . 99124 14 . 8920 -. 4131E-01 .61523 -.0001131

449.000 75.6459 1.01541 15.2187 -•4040E-01 .61477 -.0001150

452.000 78.1041 1.03913 15.5448 -.3952E-01 .61431 -.0001167

456.000 80.5604 1.06241 15.8702 -.3 86 9 E-0

.51384 -.0001184

460.000 83.014* 1.08525 16.1950 -.3787E-01 .61336 -.0001199

82
Table 10. Conti nued

HYDROGEN SULFIDE ISOCHORE AT 22.000 MOL/l

T P Z DR/DD

K MPA MPA-L/MOL

309.602 2.6403 .04662 9.9105

310.000 2.9667 .05232 9.9542

312.000 4.6066 .09072 10.1739

314.000 6.2461 .10875 10.3932

3 16.000 7. 9952 .13642 10.6123

313.000 9.5240 .16373 10.8311

320.000 11.1623 .19070 11.0496

322.000 12.9002 .21732 11.2679

324.000 14.4376 .24361 11.4859

326.000 16.0746 .26957 11.7036

329.000 17.7112 .29520 11.9210

330.000 19.3473 .32051 12.1381

332.000 20.9828 .34552 12.3550

334.000 22.6179 .37021 12.5716

336.000 24. 2525 .39460 12.7879

339.000 25.8866 .41870 13.0040

340.000 27.5202 .44250 13.2198

342.000 29.1532 .46602 13.4354

344.000 30.7857 .48925 13.6506

346.000 32.4176 .51221 13.8656

345.000 34.0490 .53489 14.0804

3 90.000 35.6798 .55731 14 .2949

3 52.000 37. 3100 .57946 14.5091

354. OCO 3e . 9396 .60135 14.7231

356. OOC 40.5696 .62299 14.9368

359.000 42.1971 .64438 15 .1503

360.000 43.8249 .66552 15.3635

362.000 4.5.4520 .68641 15.5764

364.000 47.0786 .70707 15.7891

366.000 48.7045 .72749 16.0016

368.000 50.3297 .74768 16.213e

370.000 51.9543 .76765 16.4258

372.000 53.5783 .78738 16.6375

374.000 55.2015 .80690 16.8490

376.000 56.8241 .82620 17,0602

378.000 58.4460 .84529 17.2712

3eo.ooo 6 C . 067 3 .86416 17.4819

3 82.000 61 ,6e78 .88283 17.6924

394.000 63.3076 .90129 17.9027

386.000 64 . 9268 .91955 18.1127

388.000 66.5452 .93762 18.3225

390.000 68.1629 .95549 18.5321

392.000 69.7798 .97316 18.7414

394.000 71.3961 .99065 18.9505

3 96.000 73.0116 1 .00795 19.1594

399.000 74.6263 1.02506 19.3681

400.000 76.2404 1 .04200 19.5765

402.000 77.8536 1.05875 19.7846

404.000 79.4661 1.07533 19.9926

406.000 81 .0779 1.09174 20.2003

408.000 82.6889 1.10797 20.4078

410.000 84.2992 1.12404 20.6151

DD/DT DP /DT D2P/DT2

MOL/L/K MP A/K MP A/</<

-.9275E-01 .82008 -.0000913

-.8238E-01 .82004 -.0000919

-. 8058E-01 .81986 -.0000943

-.78P7E-01 .81966 -.0000977

- .772 2 E-0

.81947 -.0001006

-.7564E-01 .81926 -.0001033

-.7412E-01 .81905 -.0001064

-.7267E-01 .81884 -.0001092

-.7127F-01 ,81662 -.0001121

-.6993E-01 .81839 -.0001149

— .6863 E-0 1 .81816 -.0001176

-•6738E-01 .81792 -.0001204

- . 6 61 8 E -0

.81767 -.0001231

- . 6 50 2 E -0

.81743 -.0001257

-. 6390E-01 .81717 -.0001234

-•6282E-01 .81691 -.0001309

-• 6 1 77 E-0

. 81 665 -.0001335

-•6076E-0 1 .8163e -.0001359

-.5979E-01 .81610 -.0001334

-•5884E-01 .81582 -.0001408

-.5792E-01 .81554 -.0001431

-.5703E-01 .81525 -.0001454

-. 5617E-0

.81496 -.0001476

-•5533E-01 .81466 -.0001493

-•5452E-01 .81436 -.0001519

-.5373E-01 .81405 -.0001540

- . 5297E-0

.81374 -.0001560

-.5222E-01 .31343 -.0001530

-, 5150E-01 .81311 -.0001600

-•5079E-01 .81279 -.0001613

-. 5011E-01 .81246 -.0001637

-.494 4 E — 0

.81214 -.0001655

- . 4 87 9E-0

.81180 - • 0001

T 2 - • 4 81 6 E -0 1 .81147 -.0001639

-.4755E-01 .81113 -.0001705

- . 4694 E-0

.81078 -.0001722

— .4636E-01 .81044 -.0001737

- . 4 57 9E-0

.81009 -.0001752

-. 4523E-01 . 80974 -.0001767

-.4469E-01 .80938 -.0001781

- . 441 5 E-0

.80903 -.0001795

-•4364E-01 .80867 -.0001 a 09

- . 4 31 3 E -0

.80830 -.0001922

-.4263E-01 .80794 -.0001334

-.421 5E-01 .80757 -.0001 346

— . 4 16 8 E -0

.80720 -.0001859

-.4121E-01 . 80683 -.0001870

-.4076E-01 .60645 -.0001331

-.4032E-01 .80607 -.0001392

-.3999E-01 .80569 -.0001902

- . 3 94 6E -0 1 .80531 -.0001912

- . 3 90 5 E -0

.80493 -.0001922

83
Tabl e 10 . Cont i nued . hydrogen sulfide isochore at 24.000 hol/l

T P 7 DP/DD DD/DT DP/DT D2P/DT2

K MPA MPA-L/MOL MOL /L/K MP A/K MP A/K /K

280.867 1.2862 .02295 16.212* - .6607 E -0

1 .07113 -.0001067

282.000 2 .4995 .04442 16.3691 -.6542E-01 1.07092 -.0001039

2 84.000 4.6410 .08189 16.6456 -.6431E-01 1.07054 -.0001927

266.000 6.7817 .11883 16.9217 -.6324E-01 1.07015 -.0001966

2 88.000 8.9216 .15524 17.1975 -.6220E-01 1.06975 -.0002004

200.000 11.0607 .19113 17.4730 -.6120E-01 1.06935 -.0002041

202.000 13.1990 .22652 17.7401 - .602 3 E -0

1.06894 -.0002079

204.000 15.3364 .26141 18.C230 -.5929E-01 1.06852 -.0002116

206.000 17.4730 .29582 18 .2975 -.5637E-01 1.06809 -.0002152

208.000 19.6080 .32975 18.5717 - • 5749E-01 1 . 06765 -.0002188

300.000 21.7436 .36321 18.8456 - . 566 3 E -0 1 1.06721 -.0002224

302.000 23.8776 .39622 19.1192 -.55P0E-01 1.06677 -.0002259

304.000 26.0107 .42878 19.3924 -•5499E-01 1.06631 -.0002293

306.000 28.1428 .46089 19.6653 -. 5420E-01 1.06585 -.0002326

308.000 30.2741 .49258 19.9378 -.5344E-01 1.06538 -.0002359

3 10.000 32.4044 .52383 20.2100 -.5269E-01 1.06490 -.0002392

312.000 34.5337 .55468 20.4819 -.5197E-01 1.06442 -.0002423

314.000 36.6620 .58511 20.7535 -.512 7 E-01 1.06394 -.0002454

316.000 38.7894 .61515 21 .0247 -.5058E-C1 1.06344 -.0002484

310.000 40.9158 .64479 21.2955 -.4991E-01 1.06294 -.0002514

320.000 43.0412 .67404 21.5661 - • 492 6 E-0

1.06244 -.0002543

322.000 45.1655 .70292 21.8363 -.4863E-01 1.06192 -.0002571

324.000 47.2889 .73142 22.1061 -.4e01E-01 1.06141 -.0002590

326.000 49.4112 .75956 22.3757 -.4741 F-01 1.06089 -.0002624

328.000 51.5324 .73733 22 .6448 -.4683E-01 1 .06036 -.0002650

330.000 53.6526 .81476 22.9137 - . 462 5 E -0 1 1.05983 -.0002675

332.000 55.7717 . 84184 23.1822 - .4 56 9E-0

1.05929 -.0002700

334.000 57.8897 .06858 23.4504 - . 4 51 5 E -0

1.05875 -.0002724

336.000 60.0067 .89498 23 .71*2 -.4462E-C1 1.05820 -.0002747

338.000 62.1225 . 92105 23.9857 -.4409E-01 1.05765 -.0002769

340.000 64.2373 .94681 24.2529 -.4359E-01 1.05709 -.0002791

342.000 66.3509 .97224 24.5198 -.4309E-01 1.05653 -.0002812

344.000 68.4634 . 99736 24 .7863 -.4260E-01 1.05597 -.0002832

346.000 70.5740 1.02218 25.0524 -.4213E-01 1.05540 -.0002852

348.000 72.6850 1.04669 25.3183 -.4166 E-0

1.05483 -.0002871

3 50.000 74.7941 1.07091 25.5030 -.4121E-C1 1 .05425 -.0002889

352.000 76.9020 1.09483 25 .84~90 - • 4076 E —0

1 .05367 -.0002907

354.000 79.0087 1.11847 26. 113e -•4033E-01 1.05309 -.0002924

356.000 81.1143 1.14183 26.3783 - . 3 990 E -0

1.05250 -.0002941

35e.OOO 83.2187 1.16491 26.6425 - .3 94 8

E -0

1.05191 -•003295 7

84
Table 10. Continued.

HYDROGEN SULFIDE ISOCHORE AT 26.000 MOL/L

T P Z DP/DD

K MPA MPA-L / MOL 2* 7.245 .**31 .00829 2*. 58*9

2*8 . 000 1 .*939 .02787 2*. 7180

250. COO *.2765 .07913 25.070*

252.000 7.0580 .12956 25 .*223

25* .000 9.3382 .17917 25.7737

256.000 12.6173 .22799 26.12*7

258.000 15.3951 .27603 26. *751

260.000 18.1717 .32331 26.8250

262.000 20.9*70 .3698* 27.17**

26*. 000 23 .7209 .*156* 27.5233

266.000 26. *935 .*6073 27.8717

268 . 000 29.26*6 .50513 28.2195

270.000 32.03*6 .5*88* 28 . 5668

272.000 3*. 8030 .591 89 28.9136

27*. 000 37.5699 .63*28 29.2599

276.000 *0.335* .67603 29.6056

278.000 *3.0993 .71716 29.9508

280.000 *5.3617 . 75768 30.2955

2e2 .000 *8.6226 .79759 30.6397

28* .000 51 .3 820 .83692 30.9833

286.000 5*. 1397 .87567 31.326*

238.000 56.3958 .91386 31.6689

290.000 59.6503 .951*9 32.0109

292.000 62 .*032 .98859 32.352*

29*. 000 65.15*3 1.02515 32.693*

296.000 67.9039 1.06119 33.0338

29® .000 70.6517 1.09672 33.3737

300.000 73.3976 1.13175 33.7130

302.000 76.1*2? 1.16630 3*. 0519

30*. 000 78.88*8 1.20036 3*. 3902

306.000 81.6257 1.23395 3*. 7279

306.000 8* .36*8 1.26707 35.0652

DD/DT DP/DT D2 P/DT?

MQL/L/K MPA /K M» A/K/K

-. 5661E-01 1.39178 -.00027*1

-.5630E-01 1.39158 -.0002772

-• 5 5* 8 E-0

1.39101 -.000285*

- . 5 *6 9E -0

1.390*3 -.0002935

-.5392E-01 1.3898* -.0003013

-.5318E-01 1.38923 -.0003090

- . 52* 5 E -0

1.38860 -.0003165

-,517*E-01 1.38796 -.0003238

-.5105E-01 1.38731 -.0003309

*-.50388-01 1.3866* -.0003378

-

* 97 3 E -0 1 1.38596 -.0003**5

-.*909E-01 1.38526 -.0003511

-.*8*7E-01 1.38*55 -.000357*

-•*786E“01 1.38383 -.0003636

-.*727E-01 1.38310 -.0003698

- .* 66 9E-0

1.38235 -.000375*

- . *61 3E-01 1 .38160 -.0003810

-.*558E-C1 1.38083 -.0003365

-.*50*E-01 1. 380C5 -.0003917

-,**52E-01 1.37926 -.0003968

- . **00E-0

1.378*7 -.000*018

-.*350E-01 1.37766 -.000*065

- . * 301 E-0

1.3768* -.000*111

-,*253E-01 1.37601 -.000*158

-. *206E-C1 1.37518 -.000*199

-.*160E-01 1.37*33 -.000*2*0

-.*115F-01 1.373*8 -.000*230

- ,*071 E-01 1.37262 -.000*313

-. *023E-01 1.37175 -.000*355

-.3986E-01 1 . 37088 -.000*390

-.39*5E-01 1 . 37CC0 -.000**2*

-.3 90*E-01 1.36911 -.000**57

85
Table 10. Continued.

HYDPOGFN SULFIDE ISOCHORE AT 28.000 M L /

T P Z DP/DD OD/DT DP /DT D2P/DT2

K MPA M&A-L/MCL MOL /L /K MP A/K MPA/K/K

209.883 .0869 .00178 34.8306 -.5184E-01 1.80569 -.0003661

210.000 .2974 .00608 34.8572 -.5180E-01 1.80565 -.0003673

211.000 2.1029 .04281 35.0854 -•5145E-01 1.60528 -.0003770

212.000 3.9080 .07918 35.3134 -.5111E-01 1.80490 -.0003865

213.000 5.7127 .11520 35.5410 - . 5077 E -0

1.80450 -.0003959

214.000 7.5170 .15068 35.7685 - • 5044E-01 1.80410 -.0004051

215.000 9.3209 .13622 35.9957 — • 501 1

E -0

1.80369 -.0004141

216.000 11.1243 .22122 36.2227 -.4978E-01 1.80328 -.0004230

217.000 12.9274 .25589 36.4494 — .4 94 6

E -0

1.80285 -.0004317

218.000 14.7300 .29024 36.6759 - • 491 4 E “0

1.80241 -.0004403

2 19.000 16.5322 .32426 36.9021 -.4883E-01 1.80197 -.0004487

220.000 18.3340 .35796 37.1281 -.4852E-01 1.80151 -.0004570

221.000 20.1353 .39135 37.3538 -.4822E-01 1.80105 -.0004651

222.000 21.9361 .42444 37.5793 ~ .4791 F-0

1.80058 -.0004730

223.000 23.7364 .45721 37.8046 -.4762E-01 1.80011 -.0004 308

224.000 25.5363 .48968 38.0296 -.4732E-01 1.79962 -.0004985

225.000 27.3357 .52186 38.2543 -.4703E-01 1.79913 -.0004960

226.000 29.1345 .65374 38.4788 - • 4 674 E-0

1.70863 -.0005034

227.000 30.9329 .58533 38 .7031 -.4646E-01 1.79812 -.0005106

228.000 32.7308 .61663 38.9271 — . 4 61 8E -0

1.79761 -.0005177

229.000 34 . 52 e.64765 39.1509 -.4590E-C1 1.797C9 -.0005246

280. OCO 36.3250 .67840 39.3744 -.4563E-01 1.79656 -.0005315

231 .000 38.1213 .70886 39.5977 -.4536E-01 1.79603 -.0005381

232. OOC 39.9170 .73905 39.8207 -. 4509E-01 1.79548 -.0005447

233.000 41 .7122 .76898 40.0435 -•4482E-01 1.79494 -.0005511

234.000 43 . 5069 .79863 40.2660 -.445 6 E-01 .79438 -.0005574

235.000 45.3010 .82803 40.4833 -.4430E-01 1.79382 -.0005636

236.000 47.0945 .85716 40.7104 - . 440 5E-01.79326 -.0005696

237.000 48.8875 .88604 40.9322 -.4380E-01 1.79268 -.0005755

238.000 50.6799 .91467 41.1537 -.4355 E-01.79210 -.0005813

239.000 52.4717 .94305 41.3750 -.4330E-01 1 .79152 -.0005970

240.000 54.2629 .97118 41.5961 — . 4 306E-0

1.79093 -.0005925

241.000 56.0536 .99906 41.8169 “,4281 E-01.79034 -.0005979

242.000 57.6436 1.02671 42.0375 — .4257E-01 1.76973 -.0006033

243.000 59.6330 1.05411 42 .2578 -.4234E-01 1.78913 -.0006085

244.000 61 .4219 1 .08128 42.4779 -.4210E-01 1.78852 -.0006136

245.000 63.2101 1.10822 42.6977 -•4187E-01 1.78790 -.00061 86

246.000 64.9977 1.13493 42.9173 - • 4164 E-0

1.78728 -.0006234

247.000 66.7846 1.16141 43.1367 -.4142 E-0

1.78665 -.0006282

248.000 68.5710 1.18767 43.3558 -.4119E-01 1.78602 -.0006329

249.000 70.3567 1.21370 43.5747 -.4097E-01 1.78539 -.0006374

250.000 72.1417 1.2395’ 43.7933 -.4075E-01 1.76475 -.0006419

251.000 73.9262 1.26512 44.0117 -.4054E-01 1.78411 -.0006463

252.000 75.7099 1.29050 44.2299 -.4032E-01 1.78346 -.0006505

253.000 77.4931 1.31567 44.4478 - . 4 01 1 E-0

1.78280 -.0006547

254.000 79.2756 1.34064 44.6655 -.3990E-01 1.78215 -.0006588

255.000 81.0574 1.36539 44 .8829 — .3969E-01 1 .76149 -.0006527

256.000 82.8385 1.38995 45.1002 -. 3949E-01 1.78082 -.0006666

257.000 84.6190 1.41430 45.3171 - . 3 92 8 E -0

1.78015 -.0006704

86
Table 10. Continued.

HYDROGEN SULFIDE ISOCHOPE AT 29.136 HOL/L

T P Z DP/DD

K HP A MPA-L/MOL

1 87.660 .0232 .00051 41.3041

192. OCO 9.1102 .19597 42.4564

193.000 11.2027 .23961 42.7209

194,000 13.2947 .28289 42.9850

195.000 15.3861 .32571 43 .2488

196.000 17.4771 .36808 43.5122

197.000 19.5675 .41002 43.7752

19« .000 21.6573 .4515? 44.0379

199.000 23.7466 .49259 44.3001

200.000 25.8352 .53323 44.5620

201.000 27.9233 .57346 44.8235

202.000 30.0107 .61328 45.0946

203.000 32.0975 .65269 45 .3454

204.000 34.1837 .69171 45.6058

205.000 36.2693 .73033 45.8658

206.000 38.3541 .76856 46.1255

207.000 40.4384 .80641 46.3847

2C8.000 42.5219 . 84389 46.6437

209.000 44 .6047 .88099 46.9022

210.000 46.6869 .91772 47.1604

2 11.000 48.7683 .95409 47.4182

212.000 50.9490 .99010 47.6756

213.000 52.9290 1.02577 47.9327

714.000 55.0082 1 .06109 48.1895

215.000 57.0867 1 .09605 48.4458

2 1 * . 000 59.1644 1.13068 48.7019

217.000 61 .2414 1.16498 48.9575

218.000 63.3176 1 .19e95 49.2127

219.000 65.3930 1.23260 49 .4677

220.000 67.4676 1.2659? 49.7222

221.000 69.5414 1.29893 49.9764

222.000 71.6144 1.33163 50.2303

223.000 73.6866 1.36401 50 .4e38

224.000 75.7580 1.39609 50.7370

225.000 77.9286 1.42788 50.9899

226. OOC 79.9983 1.45936 51.2422

227.000 81 .9672 1.49056 51 .4943

228.000 84.0352 1 . 52146 51.7461

DD/DT DP/DT 02P/DT2

MOl/L/K H P A / K HP A /< K

-.5072E-01 2.09475 -.0004265

-.4929E-01 2.09275 -.0004931

-.4897E-01 2.09225 -.0005076

-.4866E-01 2.09174 -.0005218

-.4835 E -0

2 .09121 -.0005357

-.4805E-C1 2.09066 -.0005493

-.4775E-01 2.09011 -.0005626

-.4745E-01 2.08954 -.0005757

-.4715E-01 2.08896 -.0005834

- . 468 6E -0

2.09836 -.0006008

-.4658E-01 2.08776 -.0006130

-.4629E-01 2.08714 -.0006249

- .460 1 E-C

2.08651 -.0006366

-.4574E-01 2.09586 -.0006479

-.4546E-01 2.08521 -.0006591

-.4519E-01 2 . 0

fl 4 5 5 -.0006699

-.4493E-01 2.08387 -.0006905

-.4466E-01 2.09318 -.0006909

- • 4 440 E—0

2 . 08 ?49 -.0007011

-.4414E-01 2.08178 -.0007110

-.4389E-01 2.08107 -.0007206

- . 4 364 E -0

2.08034 -.0007301

-.4339E-01 2.07961 -.0007393

-.4314 E—0

2 . 0 7 8 P 6 -.0007483

- .4 2 90 E -0 1 2.07811 -.0007571

-.4265E-01 2.07735 -.0007657

-.4242E-01 2.07658 -.0007741

-.4218E-01 2.07580 -.000792?

-.4195E-01 2.07501 -.0007902

-.4172 E -02.07422 -.0007930

-.4149E-01 2.07342 -.0009056

-. 4126E-01 2.07261 -.0009129

-.4104E-01 2.07179 -.0008202

-.4082E-01 2.07097 -.0008272

- . 406 0 E -0

2.07014 -.0008340

- . 403 8E-01 2.06930 -.0009407

-.4017E-01 2.06846 -.0008472

-. 3996E-01 2.06761 -.0003536

87
Table 11. Calculated P(p) isotherms of hydrogen sulfide

HYDROGEN SULFIDE ISOTHERM AT 200.000 K

DEN P Z DP/DD DO/DT DP/DT D2P/DT2

MOL /L MPA MPA-L/MOL MOL/L/K MPA/K MO A /< /K

.031 .0503 .98861 1 .6233 -.1585E-03 .00026 -.0000001

28.508 .0503 .00106 37.6755 -.5121E-01 1.92988 -.0003921

28.600 3.5581 . 07881 38.6839 - . 5 05 1 E-0

1.95206 -.0008198

28.700 7,8758 .15668 39.7128 - . 897 8 E -0 I 1.97689 -.0008508

28.800 11.5012 .28015 80.7978 -.89C7E-01 2.00200 -.0008827

28.900 15.6358 .32535 81.3989 -.8839E-01 2.02738 -.0005163

29.000 19.8815 .81227 83.0163 -.8773E-C1 2.05303 -.0005513

29.100 28.2397 .50092 88.1501 -.8709E-01 2.07897 -.0005375

29.200 28.7120 .59131 85.3008 -.8687E-01 2.10518 -.0008250

29.300 33.3003 .68386 86.8673 -.8587E-01 2.13166 -.0006633

29.800 38.0061 .77739 87.6509 -.8530E-01 2.15882 -.0007080

29.500 82.8310 . 87311 88.8513 -.8878E-01 2.18586 -.0007858

29.600 87 .7769 .97068 50 .0687 -.8819E-01 2.21277 -.0007331

29.700 52.8853 1.07000 51.3031 -.8367E-01 2.28036 -.0003320

29.800 5B.03ei 1.17120 52.5586 -.8316E-01 2.26823 -.0008773

88
Table 11. Continued

HYDROGEN SULFIDE ISOTHERM AT 210.000 K DEN P Z DP/DO DD/DT DP/OT D 2 p / D T 2 MOL/L MPA MPA-l/MDL MOL /L /K HP A /K M P A / K / K .051 .0879 .98202 1.6806 -. 2568E-03 .00093 -.0030001

27. 999 .0873 .00179 39.7979 -.5185E-01 1.80927 -.0003650

28.000 .2979 .00608 39.8572 -.5180E-01 1.80565 -.0003573

28.100 3.8331 .07812 35.8582 -.5100E-01 1.82061 -.0003917

29.200 7.9696 .15170 36.9797 -.5022E-01 1.95182 -.0009173

28.300 11.208'i .22663 37.9069 - . 9997 E-0

1.87530 -.00G9491

28.900 15.0515 .30353 38.9597 -• 9 97 5 E-0

1 .99909 -.0009719

28.500 19.0000 .38182 90.0105 -. 9805E-01 1 .92303 -.0005009

28.800 23.0557 .96170 91 .0961 -.9738E-01 1.99729 -.0005309

28.700 27.2202 .59319 92.1938 -.9673E-01 1.97181 -.0005620

28.800 31.9950 .62632 93.3056 -.9610E-01 1.99659 -.0005993

28.900 35.8819 .71109 99.9337 -. 9550E-01 2 .02169 -.0006277

29.000 90.3823 .79751 95.5700 -.9991E-C1 2.09695 -.0006622

29.100 99 . 9980 .88561 96 .7380 -.9939E-01 2.07252 -.0006979

29.200 99.7306 .97591 97.9161 - . 9 37 9 E -0

2.09836 -.0007395

29.300 59.5618 1.06690 99.1100 -.9326 E-0

2.12996 -.0007725

29.900 59.5532 1.16012 50.3206 -.9279E-01 2.15Ce2 -.0008115

29.500 69.6965 1.25507 51 .5901 -.9229 F -0

2.17795 -.0008515

29.800 69.9633 1.35177 52.7925 - .9175E-0 1 2.20935 -.0008927

29.700 75.2055 1.95023 59.0539 -.9129F-01 2.23150 -.0009350

29.800 80.6797 1.55098 55.3329 - . 9 09 2 E-0

2.25893 -.0009789

89
Tab! e 11. Conti nued

HYDROGEN SULFIDE ISOTHERM AT 220.000 K

DEN P Z DP/DD DD/DT DP/DT D2P/DT2

MOL /L MPA MPA-L /MOL MOL/L/K MPA /K mo A /K K

.081 .1435 .97312 1.7269 -.3992 E-03 . 00069 -.0000003

27.473 .1435 .00286 31.9745 -.5273E-01 1.68589 -.0003406

27.500 1.0109 .02010 32 .2284 -.5249E-01 1.69165 -.0003459

27.600 4.2610 .08480 33.1778 -. 5164E-01 1.71314 -.0003663

27.700 7.6469 .15092 34.1424 -.5081E-01 1.73486 -.0003875

27.800 11.1100 .21848 35.1222 -. 5C02E-01 1.75683 -. 000409 7 27.900 14.6718 .28749 36.1174 -.4926E-01 1.77905 -.0004329

28.000 18.3340 .35796 37.1281 -.4852E-01 1.80151 -.0004570

28.100 22.0980 .42992 38.1543 -.4781E-01 1.82422 -.0004820

28.200 25.9654 .50337 39.1962 - • 471 3 E-0

1.84718 -.0005080

28.300 29.9370 .57833 40.2537 -.4647E-01 1.87039 -.0005350

28.400 34.0167 .65481 41.3271 -.4583E-01 1 .89385 -.0005629

28.500 38.2037 .73283 42.4164 -.4521E-01 1.91755 -.0005917

28.600 42.5005 .81240 43.5217 -.4461E-01 1.94151 -.0006215

28.700 46 .9086 .89354 44.6431 -.4403E-01 1.96572 -.0005524

28.800 51.4297 .97625 45.7807 -.4347E-01 1.99018 -.0006842

28.900 56.0653 1.06056 46.9345 -•4293F-01 2.01490 -.0007169

29.000 60.8171 1 . 14649 48.1047 -.4240E-01 2 .03987 -.0007506

29.100 65 . 6866 1.23403 49.2913 -.M90E-01 2.06509 -.0007053

29.200 70.6759 1.32321 50.4945 -.4140E-01 2.09056 -.0008209

29.300 75.7862 1.414C5 51 . 71*3 -.4092E-C1 2.11629 -.0008575

29.400 81.0193 1.50655 52.9509 -.4046E-01 2.14227 -.0008950

90
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 240.000 K DEN P Z DP/DD DD/DT DP /DT D2 P/DT2

MOL /L MPA MP A-L/MOL MOL /L /K MP A/K MP A /K /<

.100 .1939 .97155 1.8784 -.4547E-03 .00085 -.0000003

.179 .3375 .94745 1.7798 -.8819F-03 .00157 -.0000014

26.401 . 3375 .00641 26.5036 -.5533E-01 1 . 46643 -.0002917

26.500 2.9956 .05665 27.3261 -.5434E-01 1.48485 -.0003053

26.600 5.7704 .10871 28.1733 -.5337E-01 1.50372 -.0003197

26.700 8.6307 .16199 29.0349 -.5245E-01 1.52281 -.0003340

26.800 11 .5779 .21649 29.9110 -. 5156E-01 1.54210 -.0003505

26.900 14.6134 .27224 30.8019 -.5070E-01 1.56162 -.0003669

27.000 17.7383 .32924 31. 7075 - .4 987 E — 0

1.58135 -.0003339

27.100 20.9554 .38751 32 .6280 - • 4 90 8 E-0

1.60130 -.0004016

27.200 26.2649 .44706 33.5634 -.4831E-C1 1.62147 -.0004200

27.300 27.6686 .50790 34.5139 - .4757E-C 1 1.64186 -.0004391

27.400 31.1682 .57005 35.4795 -.4686E-01 1.66248 -.0004509

27.500 34 .7650 .63352 36.4604 -.4617E-01 1.68332 -.0004794

27. fcOO 38.4607 .69833 37.4566 -.4550E-01 1.70439 -.0005006

27.700 42.2568 .76449 30.4681 -.4486E-01 1.72568 -.0005225

27.600 46.1549 . 83200 39.4952 -.4424E-01 1.74720 -.0005451

27.900 50.1563 . 90090 40.5378 -.4364E-01 1.76895 -.0005604

28.000 54.2629 .97118 41.59fel -.4306E-01 1.79093 -.0005925

28.100 58.4761 1.04286 42.6701 -.4249E-01 1.01314 -.0006173

2 . 2 00 62,7975 1.11595 43.7599 — .4195E-0

1.03558 -.0006428

23.300 67 ,22efc 1.19048 44.8655 -.4142E-01 1.85825 -.0006691

28 . 400 71 .7712 1 .26644 45.9872 -.4091E-01 1.88116 -.0006961

28.500 76.4266 1.34386 47.1249 - , 404 1 E-0

1.90430 -.0007230

26.600 81.1967 1.42274 48.2787 -.3993E-01 1.92767 -.0007523

91
Tab! e 11. Cont i nued

HYDROGEN SULFIDE ISOTHERM AT 260.000 K

DEN P Z DP/DD DD/DT DP/OT D2P/DT2

MOL /L MPA MP A-L /MOL MOL/L/K MP A /K MPA/K/K

.100 .2109 .97559 2.0536 -.4135E-03 . 00085 -.0000002

.200 .4106 .94975 1.9409 -.8998E-03 .00175 -.0000010

.300 . 5991 .92374 1.8280 -.1480F-02 .00271 -.0000030

.349 .6875 .91095 1.7725 - .1 807E-02 .00320 -.0000045

25.272 .6875 .01258 21 .2991 - • 5 94 2 F-0

1.26562 -.0002424

25.300 1.2967 .02371 21.5015 - . 590 8 E-0

1.27022 -.0002452

2 5 . A 00 3 .4827 .06343 22.2211 -.578 9 E — 0

1.28648 -.0002551

25.500 5.7414 .10415 22.9541 - . 5676E-0 1 1.30293 -.0002655

25.600 8.0740 .14589 23.7007 - . 556 9E-0

1.31956 -.0002763

25.700 10.4820 .18867 24.4609 - • 546 3 E-0

1.33638 -.0002375

25.800 12.9667 .23249 25 .2350 - • 5 36 3 E-0

1.35338 -.0002991

25.900 15.5294 .27736 26.0230 - • 5267E-0

1.37058 -.0003112

26.000 18.1717 .32331 26.8250 -.517 4 E-0

1 . 38796 -.0003238

26.100 20.8949 .37033 27.6412 - . 508 5 E-0

1.40554 -.0003368

26.200 23.7004 .41845 28.4716 -.4999E-01 1.42332 -.0003502

26.300 26.5897 .46768 29.3164 - . 49 1 6E -0

1.44129 -.0003642

26.400 29.5642 .51803 30.1756 -.4837E-01 1.45946 -.0003786

26.500 32.6253 .56951 31.0495 -.4760E-01 1.47782 -.0003936

26.600 35.7746 .62213 31.9380 -.4685E-01 1.49639 -.0004090

26.700 39.0134 .6759? 32.8412 -.4614E-01 1.51516 -.0004250

26. POO 42.3433 .73087 33.7593 -•4544E-01 1.53414 -.0004414

26.900 45.765R .78701 34.6924 -.4477E-01 1.55331 -.0004584

27.000 49.2823 .84434 35.6405 -.4413 E -0

1.57270 -.0004759

27.100 52.8944 .90288 36.6037 -•4350E-01 1.59229 -.0004940

27.200 56.6035 .96264 37.5821 - . 42 90 E -0

1.61209 -.0005126

27.300 60.4113 1.02364 38.5759 -.42316-01 1.63210 -.0005317

27.400 64.3192 1.08588 39.5850 -•4174E-01 1.65232 -.0005514

27.500 68.3288 1.14937 40.6095 -.4119E-01 1.67275 -.0005716

27.600 72.4416 1.21414 41.6496 - . 4 06 6 E -0 1 1.69340 -.0005924

27.700 76.6593 1.28019 42.7053 -.4014E-01 1.71426 -.0006138

27. POO 80 . 9832 1 .34754 43 .7766 -.396 4 E-0

1 .73 533 -.0006357

92
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 280.000 K DEN P Z DP/DD DD/DT DR /DT 02 R/DT2

POL /L MPA MPA-L/MOL MOL /L /K MP A/K MPA / K / K .100 . 2 2 7 <5 .97872 2.2270 -.3799E-03 .00085 -.0000001

.200 .**5* .9565* 2.1238 -.81*5E-03 .00173 -.0000007

.300 .6527 .93*52 2 .0226 -.1315E-02 .00266 -.0000018

.*00 . 8*<5<5 .91272 1.9228 -.1 89*E-02 . 0036* -.0000037

.500 1.0373 .89110 1.8237 - . 2 56 8E -0 2 .00*68 -.0000066

.600 1.21*7 .86960 1.72*8 -.3359E-02 .00579 -.0000110

.62* 1.2556 . 86**9 1.7011 -.3568E-02 .00607 -.0000123

2*. 055 1.2556 .022*2 16. *159 -.6573E-01 1.07897 -.0001892

2*. 100 1 . <5<55 <5 .03557 16.680* -.6506E-01 1.08521 -.0001926

2* .200 3.6938 .06556 17 .2805 - • 6 36 1 E-C

1.09929 -.0002003

2*. 300 5. *52* .09638 17.8928 -.6223E-01 1.11352 -.0002083

2*. *00 7.2728 .12803 18.5173 -.6091E-01 1.12790 -.0002165

2*. 500 9.1562 .16053 19.15*3 -,596*E-01 1. 1*2*5 -.00022*9

2* .600 11.10*1 .19389 19.80*0 - . 5 8* 3 E-0

1.15715 -.0002336

2*. 700 13.1175 .22812 20. *663 -• 5727E-0 1 1.17202 -.0002*25

2*. 800 15.1977 .26323 21.1*15 -.5615E-01 1.18705 -.0002517

2*. <500 17.3*62 .29923 21.829e -. 5507E-01 1.20225 -.0002612

25.000 19.56*1 .3361* 22.5312 -.5*0*E-C1 1.21761 -.0002710

25 . 100 21.8529 .37397 23.2*58 - . 5 30 5 E-0

1.23315 -.0002811

25.200 2* .2138 .*1273 23.9739 -.5209E-01 1.2*885 -.0002915

25.300 26.6*81 .*52*3 2*. 7155 -.5117E-01 1.26*73 -.0003021

25. *00 29.1573 .*9308 25 .*707 -.502 8 E-01 .2807e -.0003132

25.500 31.7*27 .53*70 26.2397 -.*9*3E-01 1.29701 -.00032*5

25.600 3* .*057 .57729 27.C226 - . * 860 E -0

1.313*1 -.0003362

25.700 37.1*77 .62088 27.6196 - . *78 1 E-0

1 .37999 -.0003*32

25.800 39.9701 .665*6 28.6306 -,*70*E-01 1.3*676 -.0003606

25. <500 *2.97*3 .71105 29. *559 -.*630E-01 1 . 36370 -.000373*

26.000 *5.8617 .75768 30.2955 -.*558E-01 1.38083 -.0003865

26.100 *8.9339 .80533 31.1*96 -.**8 8 E-0

1.3991* -.000*000

26.200 52.0922 .95*0* 32 .0182 - • **2 1 E-0

1 .*1 56* -.000*139

26.300 55.3330 . 90380 32.9015 -.*356E-01 1 .*3333 -.000*201

26. *00 58.6729 .95*6* 33.7995 - . *2 9* E-0

1 .*5121 -.000**28

26.500 62.099* 1.00656 3*. 712* -.*2?3E-01 1 .*6927 -.000*579

26.600 65.6159 1.05958 35.6*02 - .* 1 7* E-0

1 .*8753 -.000*733

26.700 69.2270 1.11370 36.5831 -.*117 E-0

1.50598 -. 000**92

26.800 72 .9330 1.16895 37.5*10 - . * 06 1 E-0

1.52*63 -.0005055

26. <500 76.7357 1.22532 39.51*2 - . *00 8 E-0

1. 5*3*7 -.0005222

27.000 90.636* 1 .2 82 8* 39.5026 - . 3 95 5 E -0 1 1.56250 -.000539*

27.100 8*. 6367 1.3*151 *0.506* -.3905E-01 1.5817* -.0005570

93
Tabl e 11. Cont i nueu . hydrdgfn sulfide isothep m at 300.000 k

DEN P Z DP /DD DD/DT DP/DT D2P/0T2

MOL /L MPA MP A-L /MOL MOL/L/K MP A /« MP A/K/K

.?00 .4799 .96189 2.3036 -.7462E-03 .00172 -.0000004

.400 . 922 1 .92424 2 .1210 -.1689E-02 .00358 -.0000024

.600 1.3287 .88781 1.9454 -.2891E-02 . 00562 -.0000066

.800 1.7005 . 85218 1.7727 -.4439E-02 .00787 -.0000140

1.000 2.0378 .81696 1.5999 -.6469E-02 .01035 -.0000264

1.045 2.1088 .80907 1.5608 -.7011E-02 .01094 -.0000301

22.710 2.1038 .03723 11.9162 - . 7 57 3 E -0 1 .90244 -.0001269

22.800 3.1962 .05620 12.3389 - • 7401 E -0

.91317 -.0001331

23.000 5.7606 .10041 13.3119 - . 7 04 2 E -0

.93748 -.0001470

23.200 8.5238 .14730 14.3280 -. 6716E-01 .96233 -.0001612

23.400 11 .4947 .19694 15.3882 -.6419E-01 .98771 -.0001757

23.600 14.6821 .24941 16.4937 -.6146E-01 1.01364 -.0001907

23.800 18.0953 .30481 17.6458 - . 5 895 E -0

1.04014 -.0002062

24.000 21. 7436 .36321 18.8456 -.5663E-01 1.06721 -.0002224

24.200 25.6368 .42471 20.0943 -.5449E-01 1.09488 -.0002392

24.400 29.7847 .48938 21.3931 -.5250E-01 1.12316 -.0002568

24.600 34.1974 .55732 22.7430 -.5066E-01 1.15205 -.0002751

24.800 38.8854 . 62860 24.1452 -.4894E-0 1 1.18157 -.0002944

25.000 43.8591 .70334 25.6008 -.4733E-01 1.21174 -.0003146

25.200 49.1293 .78160 27.1106 -.4583E-01 1.24256 -.0003358

25.400 54.7070 .86348 28.6759 -.4443 E-0 1 1.27405 -.0003581

25.600 60 . 6034 . 94907 30.2974 -.4311E-01 1.30621 -.0003815

25. 800 66 . 8298 1 .03847 31.9762 -.4188E-01 1.33907 -.0004060

26.000 73.3976 1 .13175 33.7130 - . 4 07 1

F -0 1 1.37262 -.00043ie

26.200 80.3190 1.22902 35.5088 - . 3 962 E -0 1 1.40689 -.0004589

94
Taule 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 320.000 K DEN p Z DP/DD DD/DT DP /DT 02 0 !~) T? MOL /L MPA MPA-L/MHL MOL /L /K MP A/K MP A K /K

.200 .5142 .96623 2.4811 -.6698E-03 .00171 -.0000003

.*00 . 9934 .93341 2.3132 -. 1532E-C2 .00354 -.0000016

.600 1 .4400 .90206 2.1544 -.256QE-02 .00552 -.0000044

.800 1.6585 .87172 2.0004 - . 3 82 2 E -0 2 .00764 -.0000099

1.000 2.2403 .84203 1.8485 -.5379E-02 .00994 -.0000159

1.200 2 .594 9 .81274 1 .6971 -.7318E-02 .01242 -.0000256

1.400 2.9192 .78370 1.5456 -.9765E-C2 . 01509 -.0000394

1.600 3.2131 .75478 1.3935 - . 1290E-C

• 01 7 9 p -.0000533

1.677 3.3178 .74370 1.3349 -.1435E-01 .01915 -.0000633

21.166 3.3178 .05892 7.8623 - . 930 8

E -0 1 .73182 -.0000460

21.200 3.5884 .06362 7.9809 -.9213E-01 .73525 -.0000497

21. *00 5.2554 .09230 8.6948 - • 8 690 E -0.75555 -.0000637

21.600 7.0686 .12300 9.4434 -.8220E-01 .77628 -.0000792

21.800 9.0352 .15577 10.2280 -.7797E-01 .79744 -.0000924

22.000 11.1623 .19070 11 .0496 -.7412E-01 .81905 -.0001064

22.200 13.4576 •227e4 11.9095 - . 706 3 E -0. 84112 -.0001202

22.400 15.9287 .26727 12.8088 -.6743E-01 .86367 -.0001341

22.600 18.5838 .30906 13.7488 -.6449E-01 .88669 -.0001430

22.800 21.4310 .35323 14. 7305 -.6179E-01 .91022 -.0001621

23.000 24.4789 .40002 15.7552 -• 5930E-01 .93425 -.0001765

23.200 27.7361 .44934 16.8242 5699E-01 .95880 -.0001912

23.400 31 . 2116 .50132 17.9396 -. 5485E-01 .98389 -.0002062

23.600 34.9146 .55604 19.0995 -.5285E-01 1.00950 -.0002217

23 .800 38.8546 .61359 20.3093 -.5100E-01 1.03569 -.0002377

24.000 43.0412 .67404 21 .5661 - . 4 92 6 E -0

1.06244 -.0002543

24.200 47.4843 .73748 22.8740 -.4764E-01 1 . 08976 -.0002714

24.400 52.1942 . 90398 24.2331 -.4612E-01 1.11768 -.0002893

24.600 57.1811 .87364 25.6446 -.4470E-01 1.14620 -.0003079

24 . 800 62.4556 .94653 27.1096 -.4336E-01 1.17534 -.0003273

25.000 68.0286 1 .02274 28.6291 — . 4209E-01 1.20510 -.0003475

25.200 73.9110 1.10236 30.2041 -.4090E-01 1 .23 550 -.0003696

25.400 80.1140 1.18546 31.8356 - . 3 97 8 E -0

1.26654 -.0003906

95
Table 11 Continued

HYDROGEN SULFIDE ISOTHERM AT 340.000 K

DEN P Z DP/DO DD/DT DP/DT D2 P/DT2

MOL/L MPA MPA-L/MPL MOL /L /K MPA /K MP A /K /K

.400 1.0640 .94091 2.5014 - • 1 40 5 E-02 .00352 -.0000012

.POO 2.0068 .88736 2.2166 -.3382E-02 .00750 -.0000062

1.200 2.8389 .83686 1.9448 -.6175E-02 .01201 -.0000166

1.600 3.5630 .78773 1 .6759 -.1019E-01 .01708 -.0000345

2.000 4.1799 .73930 1.4092 - . 1 61 5E -0 1 . 02275 -.0000632

2.400 4.6909 .69141 1.1469 -.2533E-C1 .02906 -.0001093

2.652 4.9599 .66148 .9849 -.3391E-01 .03340 -.0001541

19.274 4.9599 .09103 4.3202 -•1299E+00 .56118 .0000785

19.600 6.4897 .11713 5.0897 - . 1 15 5 E 00 .58804 .0000443

20.000 8.7303 . 15441 6.1321 -.1015E+00 .62229 .0000082

20.400 11.4105 .19786 7.2885 -.9027E-01 .65796 -.0000237

20.900 14.5774 .24791 8.5669 -.8114E-01 .69516 -.0000529

21.200 18.2815 .30504 9.9758 -.7357E-01 .73395 -.0000903

21.600 22.5766 .36973 11.5237 -.6720E-01 .77442 -.0001070

22.000 27.5202 .44250 13 .2198 -.6177E-01 .81665 -.0001335

22.400 33.1734 . 52397 15.0733 -.5710E-01 .86072 -.0001602

22 .800 39.6011 .61441 17.0936 - . 5 304 E-0

.90671 -.0001879

23.200 46.8720 .71468 19.2909 -.494 9 F -0.95471 -.0002165

23.600 5 5 . 0 5 e6 .82527 21.6740 - .463 6 E-01.00481 -.0002469

24.000 64.2373 .94681 24.2529 -•4359E-01 1.05709 -. 0002791

24.400 74 .4882 1.07990 27.0368 - . 4 1 12 E -0

1.11164 -.0003137

96
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 360.000 K DEN D Z DP/DD

MOL /L MPA mpa-l/mol

.*00 1.13*0 .9*718 2.6868

. 800 2.1556 .90021 2. *253

1.200 3 .0761 .856*1 2.1782

1.600 3.8986 .81*05 1.93*6

2.000 * .62*2 .772** 1.6936

2. *00 5.25*1 .73139 1 . *571

2.800 5.7910 .69097 1.229*

3.200 6.2393 .651*0 1.01*3

3.600 6.60*6 .61292 .8152

*.000 6.8939 .57579 .63*?

*.*00 7.11*5 .5*020 .*718

* .*36 7.1312 .53707 .*581

16.567 7.131? .1*381 1.3963

16 .800 7. *861 .1*887 1.6*8*

17.200 8.2*01 .16005 2.1332

17.600 9.2022 .17*68 2.689*

18.000 10. *019 .19306 3.3227

18. *00 11.871* .21555 *.0391

18.800 13.6*51 .2*2*8 *.8**7

19.200 15.7600 .27*23 5 .7*61

19.600 18.2557 .31117 6.7502

20.000 21.17*8 .35371 7.86*1

20. *00 2*. 5626 .*0226 9.0955

20.800 28 .*679 .*5725 10 .*525

21.200 32.9*26 .5191* 11.9*36

21.600 38.0*19 .588*0 13.5775

22.000 *3.82*9 .6655? 15.3635

22. *00 50.35*2 .75102 17.3108

22 .800 57.6962 .8*5*2 19. *291

23.200 65.9215 .9*929 21.7280

23.600 75 . 1 C *0 1.06319 2*. 2173

DD/DT DP/DT D2P/DT2

MOL /L /K MP A/K MPA/K/K

-•1301E-02 .003*9 -.0000009

-• 30*8E-02 .00739 -.00000*5

- • 5 3 85 E-02 .01173 -.0000117

- • 853 6E-02 .01652 -.0000231

-.128*E-01 .02175 -.0000398

-.1881E-01 .027*1 -.0000625

-.2723E-01 .033*8 -.0000931

-.3936E-01 .03993 -.00013*0

-.5733E-01 .0*67* -.0001903

-.8502E-01 .05392 -.00027?*

- • 1 30 *E + C0 .06153 -.000*068

-.1359E+00 .0622* -.000*236

-.2691E+00 .37570 . 00037*9

-.236*E+00 .3897* .0003132

-.19*3E+00 .*1*59 .00023*?

-. 1638E + 00 .**051 .0001752

-.l*07E+00 .*6757 .0001280

-.122 8E *00 .*9583 .000088*

-.108*E*C0 .52536 .0000539

-. 9679E-01 .55619 .0000229

-.8717E-01 .588*0 -.0000055

- • 791 OE-0

.62202 -.0000321

-.7225E-01 .6571* -.0000575

-.6638E-01 .69380 -.0000823

-.6129E-01 .73207 -.0001067

- • 5 686 E-0

.77203 -.000131?

- . 5 2 97 E “0

.8137* -.0001560

- . * 95 2 E “0

.85729 -.0001816-

-.*6*6E-01 .9027* -.0002082

“.*373E-01 .95018 -.000236?

“,*128E-C1 .99967 -.0002657

97
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 365.000 K

DEN P Z DP/DD DD/DT DP/DT D2P/DT2

MOL/L MPA MPA-L /MOL MOL/L/K MPA /K MP A/K/K

.*00 1.1515 . 9*859 2.7328 - . 1 277E-02 .003*9 -.0000008

.800 2.1925 .90308 2 .*766 -.2976E-02 .00737 -.00000*2

1.200 3.13*6 .8607* 2.2350 -.5223E-02 .01167 -.0000108

1.600 3 .9809 .81985 1 .9970 -•8216E-02 .016*1 -.0000212

2.000 *.7325 .77970 1.7611 -.122*E-01 .02156 -.0000360

2. *00 5.390* .7*009 1.5297 - • 1 773 E-0.02712 -.0000560

2.800 5.9573 .70107 1.3066 -.2529E-01 .0330* -.0000919

3.200 6. *373 .66287 1 .0958 -.3587E-01 .03930 -.0001151

3.600 6.8361 .62571 .9008 - . 5093E-0

. 0*587 -.0001578

*.000 7.1603 .58985 .7237 - . 7 2 8*E-0.05272 -.0002139

*.*00 7. *176 .55550 . 5658 - • 1 057 E 00 .05982 -.0002908

* .800 7.6155 .52279 .*270 -.1573E+00 .06719 -.000*051

5.200 7.7616 .*918* . 3065 -.2***E+00 .07*89 -.0006011

5.238 7.7730 .*8900 .2959 -.2556E+00 .07565 -.0006277

15.5*2 7.7730 .16*80 .793* -.*0**E*00 .32081 .0005785

15.600 7.8205 .16519 .83*7 -.3880E+00 .32386 .0005503

16.000 8.2153 .16919 1.1*85 -.3006E+00 . 3*530 .000*057

16. *00 8.7*68 .1757* 1.5186 -•2*21E+00 .36769 .0003108

16.800 9. *38* •1*512 1.9501 — .2006E*00 .39112 .0002*15

17.200 10.3158 .19763 2 , **8* -.1698E+0Q .*1563 .0001871

17.600 11 .*068 .21356 3.0189 - • 1 *62 E 0 0 .**130 .0001*23

18.000 12.7*13 .2332* 3.6671 -.1277E+00 .*6815 .0001039

18. *00 1* .3516 .25701 * .3991 -.1128E+00 .*9623 .0000701

18 . 800 16.2725 .28521 5.2209 -.100?E+00 .52559 .0000395

19.200 18.5*12 .31821 6.1391 - . 906 1 E-0

.55628 .0000113

19.600 21.1976 .35637 7.1606 -. 8216E-01 ,58e3* -.0000151

20.000 2* .26*5 .*0010 8 .2928 -,7*99E-01 .6218* -.0000*03

20. *00 27.8*76 .**981 9.5*32 -.68S3E-C1 .65693 -.00006*6

20.800 31 . 9359 .50593 10.9200 -•6350E-C

.69337 -.0000836

21.200 36.6016 .56890 12. *317 -,580*E-O1 .73152 -.000112*

21.600 *1 . 900* .63920 1* .0871 -,5*76E-01 .77136 -.000136*

22.000 *7.8916 .71731 15.895* -. 511*E-01 .81295 -.0001609

22. *00 5* .6383 .80375 17.8660 - .*793E-0

.95637 -.0001862

22.800 62.2073 . 8990* 20.0086 - . * 507 E-0.90169 -.0002126

23.200 70.669* 1.00372 22.3328 — ,*2*9E-01 . 9*898 -.0002*03

23.600 80.0991 1.11837 2*. 8*83 - . *01 8E -0

.9983* -.0002696

98
Tabl e 11. Cont i n ued

HYDROGEN SULFIDE ISOTHERM AT 370.000 K DEN P Z DP/DD

“HL /L mpa MPA-L/MOL

.400 1.1689 .94994 2 .7787

.800 2.2293 .90583 2 .5275

1.200 3.1928 .86489 2.2912

1.600 4.0627 .82539 2.0585

2.000 4 .3398 .78662 1.8276

2.400 5.5253 .74836 1 . 600 e 2.800 6.1215 .71067 1.3819

3.200 6.6325 .67373 1 .1750

3.600 7.0636 .63780 .9832

4.000 7.4214 .60310 .8091

4 . 400 7.7133 . 56984 . 6537

4.800 7.9469 .53817 .5174

5.200 8.1298 .50820 .3997

5.600 8.2690 ,47999 .2995

6.000 8.3715 .45354 .2153

6.400 8.4432 .42883 .1454

6.542 e . 4622 .42049 .1236

14.032 8.4622 .19604 .2702

14.400 8.5660 .19382 .40^0

14.800 8 .7844 .19294 .5917

15.200 9.0650 .19386 .818®

15.600 9.4457 .19682 1 .0930

16.000 9.9464 .20207 1 .4193

16.400 10.58eP .20908 1.8026

16. POO 11 .3968 .22051 2 .24 80 17.200 12.3962 .23427 2.76C6

17.600 13.6149 .25146 3.3458

IP. 000 1 5.0e32 .27239 4.0093

18.400 16.8336 .29739 4 .7571

16 . 300 18.9009 .32680 5.5952

19.200 21.3227 .36100 6.5304

19.600 24.1391 .40034 7.5695

20.000 27.3931 .44522 8.7199

20.400 31.1309 .49605 9.9894

20 .eoo 35 .4016 .55325 11.3859

21.200 40.2577 .61727 12.9102

21.600 45.7554 .68857 14.5951

22.000 51.9543 .76765 16 . 4 2

e 8 22.400 58.9178 .85499 18.4197

22.800 66.7131 .95113 20.5864

23.200 75.4113 1 .05660 22.9358

DO/DT DP/DT D2P/DT2

MOL/L/K MP A /K hd A /K /K

-.1255E-02 .00349 -.0000008

- . 2 90 8 E -0 2 .00735 -.0000039

- . 507 2

E -0

.01162 -.0000100

-.7922E-02 .01631 -.0000195

-.1170E-01 .02139 -.0000328

-.1677E-01 .02685 -.0000505

-. 2363E-01 .03266 -.0000728

-.3299E-01 .03877 -.0001005

-.4591E-01 .04514 -.0001344

-.6396E-01 .05175 -.0001760

- . 8 954 E -0 1 .05854 -.0002273

-• 1265E+00 .06548 -.0002922

- . 1 81 5 E +00 .07254 -.0003774

-.2662E+00 .07972 -.0004953

-.4042E+00 .08702 -.0006795

-.6502E+00 .09453 -.0010169

-. 7P70E +00 .09726 -.0012232

-.9385E+00 .25342 .0011533

-.6619E+C0 .26940 .0007992

-.4P56E+00 .28734 .0005919

-.3740E+0C .30621 .0004609

-.2983E+00 . 32610 . 0003682

-.2445E+00 .34704 .0002975

-.2047E+00 . 36906 .0002407

-.1745E+00 .39220 .0001933

-.1509E+00 .41648 .0001524

-.1321E+CO .44194 .0001164

-.1169E+C0 .46861 .0000840

-.1044E+00 .49654 .0000544

-.9397E-01 .52576 .0000263

-.8519E-01 .55631 .0000009

-.7771E-01 .58825 -.0000239

-.7129E-01 .62162 -.0000478

-.6572E-01 . 65649 -.0000713

- . 60 86 E-0

.69291 -.0000945

-. 5658E-01 .73095 -.0001177

-.5280E-01 .77067 -.0001413

- , 4944 E-0

.81214 -.0001655

-.4644E-01 .85543 -.0001905

- . 4 37 5 E-0

.90061 -.0002166

-.4132E-01 .94777 -.0002440

99
Table 11. Continued.

HYDROGEN SULFIDE ISOTHEP" AT 373.400 K

DEN P Z DP/DD DD/DT DP/DT D2P/DT2

MOL /L MPA MPA-L /MOL MOL/L/K MP A/K MP A/iL/K

. 800 2.2543 .90763 2.5620 -.2 86 4E-02 .00734 -.0000037

1.800 4.1181 .82901 2. 0999 -.7735E-02 .01624 -.0000184

2,400 5.6163 .75376 1 .6484 -.1619E-01 .02669 -.000047?

3.200 6.7637 .68081 1.2277 -.3131E-01 . 03844 -.0000923

4.000 7.5964 .61170 .3654 -.5914E-01 .05118 -.0001569

4.800 8.1680 .54810 .5760 - . 1 1 2 1 F «-00 .06456 -.0002464

5.600 8.5375 .49106 .3593 -.2178E+00 .07826 -.0003720

6.400 8 .7599 .44087 . 2063 -.4460E+00 .09201 -.0005622

7.200 8 . Pei3 .39731 .1048 -.1007E*C1 .10561 -.0008787

8.000 8.9363 .35988 . 0434 -.2742F+01 .11893 -.0015094

0. «00 8.9587 .32791 .0118 -.1113E*02 .13187 -.0032227

9.600 8 . 9628 . 30072 .0010 -.1464E+03 .14422 -.01 30821

10.400 8.9629 .27759 .0000 -.3927E+04 .15494 .0798563

11.200 8.964? .25780 .0054 -.3126E+02 .16951 .005031?

12.000 8 . 9780 .24098 .0349 -.5402E+01 .18872 .0022175

12 . 800 9.0335 .22732 .1147 -.1849E+01 .21216 . 001199?

13.600 9.1832 .21749 .2760 -.8686E*00 .23977 .0007546

14.400 9.5059 .21263 . 5530 -.4911E+00 . 27156 .0005117

15.200 10.1086 .21421 .9821 -.3132E*00 ' .30759 .000350?

16.000 11.1279 .22402 1.6011 -.2173E+-00 .34796 .0002503

16.800 12.7313 .24409 2.4489 -•1604E+00 .39281 .0001482

17.600 15.1182 .27668 3 . 566P -.1240E+00 .44231 .0001016

18.400 18.5221 .32424 4 .9994 -.9935E-C1 .49671 .0000449

19.200 23. 2141 .38944 6.7955 -.8186E-01 .55630 -.0000057

20.000 29.5064 .47520 9.0095 -.6898E-01 .62145 -.0000527

20.800 37.7569 .58469 11.7020 -.5919E-01 .69258 -.0000983

21.600 48.3749 .72137 14.9397 -.5155E-01 .77018 -.0001445

22.400 61 .8252 .88901 18.7952 -.4548E-01 .85477 -.0001932

23.200 78.6323 1.09170 23.3440 -.4056E-01 .94694 -.0002464

100
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 375.000 K DEN P Z DP/DD

MOL /L MPA MPA-L/M0L

.800 2.2660 .00846 2.5782

1.600 4.1440 .83068 2.1102

2.400 5.6500 .75624 1.6707

3.200 6.8251 .68406 1.2522

4.000 7.6781 .61564 .8015

4.800 8.2710 .55265 .6031

5.600 8.6623 .40611 .3866

6.400 8.0064 .44633 .2334

7.200 0.0403 .40310 .1313

8.000 0.127] .36501 .0680

8.800 0.1675 .33412 .0364

0.600 0.1012 .30707 .0258

—

o r* o o 0. 2122 .28400 .0270

11 .200 0.2370 .26454 .0302

12.000 0.2818 .24808 .0768

12.800 0.3742 .23480 .1652

13.600 0. 5678 .22563 . 3350

14.400 0.0410 .22141 .6205

15.200 10.6012 .22360 1.0583

16.000 11 .6e5C .23423 1 .6861

16.800 13.3600 .25505 2.5430

17.600 15.8260 .28840 3.6706

18.40C 10.3160 .33671 5.113?

10.200 24.1042 .40265 6.0201

20.000 30.5006 .48012 0.1456

20.800 38.8640 .50028 11.8505

21.600 40.6070 .73658 15,1016

22.400 63.1026 .00480 18.0717

23.200 80.1471 1.10708 23.5370

DD/DT DP/DT 02P/DT2

MOL /L/K HP A/K MPA /</K

-.2 843F-02 .00733 -.0000036

-.7651E-02 .01621 -.0000180

-.1 593'E-Ol .02661 -.0000458

-•3058E-01 .03829 -.0000380

-.5713E-01 . 05004 -.0001402

-.1064E+00 .06418 -.0002296

-.2010E+00 .07770 -.0003347

-. 3008E4-00 .09110 -.0004800

-.7054E+00 . 10442 -.0006324

-.1701E+01 .11724 -.0007740

-•3559E+01 .12967 -.0007398

-.5520E+01 .14224 -.0003341

-. 5600E+01 .15598 .0001303

-•4386E+01 .17181 .0005090

-•2484E+01 .10075 .0003053

-.1294E+01 .21365 .0007338

-.7190E+00 .24062 .0005341

-.4388E+00 . 27231 .0004308

-.2912E+00 .30813 . 0003240

-.2066E+0C .34835 .0002324

-.1546E+00 . 30307 .0001570

-.1205E+00 .44247 .0000053

- . 971 6 E -0

.40678 .0000407

-. 8039E-01 .55620 -.0000085

-.6794E-01 .62137 -.0000540

-.5843E-01 .60242 -.0001000

- . 5 00 8 E-0

.76005 -.0001450

-.4504E-01 .85446 -.0001044

-. 4022E-01 . 94654 -.0002475

101
Ta b 1 e 11 Continued

HYDROGEN SULFIDE ISOTHERM AT 380.000 K

DEN P Z DP/DD DD/DT DP/DT D2P/DT2

MOL /L MPA MP A-L/MOL MOL/L/K MP A/K M° A /K /K

.800 2.3026 .91099 2.6286 -.2782E-02 .00731 -.0000034

1.600 A . 2 2 A 9 .83574 2.1793 -.7400E-02 .01613 -.0000166

2.400 5.7915 .76376 1.7395 -. 1517E-01 .02639 -.0000417

3.200 7.0155 .69389 1.3278 -.2852E-01 .03787 -.0000794

A. 000 7.9310 .62755 .9718 -.5170E-01 .05024 -.0001291

A. 800 8.5892 . 56636 .6857 -• 9208E-01 .06314 -.0001891

5.600 9.0469 .51132 .4698 -.1623E+00 . 07624 -.0002547

6 . A 00 9.3573 .46275 .3154 -•2830E+00 .08928 -.0003156

7.200 9.5650 . A2C47 .2115 - .482 9E 00 .10211 -.0003516

« .000 9.7063 .38401 .1476 - . 7 776 E 00 .11479 -.0003356

8.800 9.8099 .35283 .1163 -.1098E+01 .12765 -.0002521

9.600 9.8994 .32638 .1115 -.1267E+01 .14126 -.0001167

10.400 9.9930 .30412 .1243 -•1258E+01 .15630 .000037?

11.200 10.1016 .28546 .1506 -•1151E+01 .17336 .0001859

12.000 10.2423 .27015 . 2083 - . 926 8 E +00 .19308 .0003009

12.800 10.4495 .25838 .3209 -.6736E+00 .21614 .0003555

13.600 1C .7779 .25083 .5163 -.4703E+00 .24305 .0003499

1A.400 11.3074 .24853 . 8293 - . 3 306 E -t-00 .27414 .0003066

15.200 12.1455 .25290 1 . 2945 -.2391E+00 . 30955 .0002432

16.000 13.4294 .26565 1.950? - • 1 79? E +C 0 .34939 .0001878

16.800 15.3272 .28876 2.8360 -.1389E+00 .39379 .0001305

17.600 18.0394 .32441 3.9935 - • 1 10 9E OO .44290 .0000776

18.400 21.8012 .37501 5.4678 - . 9 08 9 E -0 1 .49695 . 0000287

19.200 26.8855 .44320 7.3083 -.7611E-01 .55622 -.0000172

20.000 33.6067 .53183 9.5698 -.6490E-01 .62107 -.0000614

20.800 42.3258 .64405 12.3135 -.5619E-01 .69191 -.0001052

21.600 53.4549 .78327 15.6067 -.4929E-01 .76921 -.0001502

22. AOO 67.4624 .95322 19.5222 -.4372E-01 .65348 -.0001931

23.200 84.8767 1.15793 24.1365 -.3916E-01 .94530 -.0002507

102
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 390.000 K DEN P Z DP/DD

MOL/L MPA MPA-L/MGL

.800 2.3756 .91576 2.7288

1.600 4.3e53 .84525 2.2978

2.400 6.0534 .77784 1.8742

3.200 7.3906 .71224 1 .4752

4.000 8.4275 .64974 1.1274

4.800 9.2121 .59186 .8456

5.600 9.7983 .53959 .6305

6.400 10.2368 .49327 .4752

7.200 10.5720 .45282 . 3706

8 . 000 10.8413 .41792 .3092

8.800 11.0769 .38818 ,2e59

9.600 11.3077 .36325 .2961

10.400 11.5573 .34271 . 3308

11.200 11.8419 .32607 .3856

12.000 12.1844 .31313 .4789

12.800 12.6246 .30416 .6341

13.600 13.2226 .29983 .8782

14.400 14.0617 .30114 1.2424

15.200 15.2518 .30944 1.7617

16.000 16.9316 .32635 2 .4733

16.800 19.2709 .35375 3.4169

17.600 22.4718 .39375 4.6348

18,400 26.7718 .44870 6.1726

19.200 32.4466 .52116 8.0806

20.000 39.8142 .61391 10.4143

20.800 49.2395 .73004 13.2356

21.600 61.1393 .87290 16.6125

22.400 75.9872 1.04615 20 .6184

DD/DT DP/DT D2P /0T2

MOL/L /K MPA /K HP A/K /K

-.2668E-02 .00728 -.0000030

-.6951E-02 .01597 -.0000143

-.1388E-01 .02601 -.0000352

-.2519E-01 .03716 -.0000648

-.4355E-01 .04910 -.0001008

-.7276E-01 .06153 -.0001390

-.1176E 00 .07416 -.0001730

-.1827E^00 .08683 -.0001942

-. 2686E + 00 . 09954 -.0001943

-.3638E+00 .11247 -.0001687

-.4406E400 .12596 -.0001198

-.4744E^00 .14048 -.0000557

-.4732E+00 .15652 .0000138

-.4528E+00 .17456 .0000816

-.4074E+00 .19506 .0001396

-.3448E+C0 .21861 .0001789

-•2797E+00 .24563 .0001945

-.2226E+00 .27652 .0001874

-.1769E+00 .31156 .0001633

-.1419E+C0 .35095 .0001291

-.1156E+00 . 39488 .0000900

-.9569E-01 .44353 .0000493

-.8054E-C1 .49713 .0000033

-.6880E-01 .55597 -.0000323

-. 5957E-01 . 62040 -.0000730

- , 521 9E-0

.69061 -.0001145

-.4621E-01 .76767 -.0001530

-.4130E-01 .85147 -.0002047

103
Tab! e 11 Continued.

HYDROGEN SULFIDE ISOTHERM AT *00.000 K

DEN P Z DP/DD DD/DT DP /DT D2P/DT2

OL/L MPA MPA-L/MOl MOL/L/K MPA/K MPA/K/K

.800 2. **83 .92018 2.8260 -•2565E-02 .00725 -.0000026

.600 *.5*** .85*00 2 .*1*3 - . 6 561 E -0 2 .0158* -.0000125

.*00 6.3119 .79077 2 .0057 -.1281E-01 .02568 -.0000300

.200 7.7591 .72906 1.6183 -.2260E-01 .03657 -.00005*1

.000 8.9138 .67005 1.2782 -.3771E-01 .0*820 -.0000818

.800 9.8210 .61520 1.0006 -.6026E-01 .06030 -.0001089

.600 10. 5320 .565*9 . 7873 -.9229E-01 .07266 -.0001302

.*00 11.0965 .52133 .6332 - • 1 3*5 E ••00 .08519 -.0001*0*

.200 11.5589 .*8271 .5311 - • 1 8** E 00 .09793 -.0001356

.000 11.9586 .**9*6 .*756 -.2336E+00 .11109 -.0001151

. 800 12.3313 .*213* .*631 -.2699E+00 .12*99 -.0000813

.600 12.7101 .39809 .*898 -.2859E+00 .1*002 -.0000393

.*00 13.1231 .379*1 .5*65 -.2866E+00 .15662 .0000058

.200 13.5910 .36*87 .6288 -.2786E+00 .17519 .0000*97

.000 1 * . 1 * 1

.35*33 .7559 -.2595E+00 .19619 .0000890

.800 1* . 818* .3*809 .9507 -•2315E^OO .22005 .0001159

.600 15.687* .3*683 1.2398 -•199*E+00 .2*722 .0001299

.*00 16.8352 .35153 1.6532 -,1682E^00 .27808 .0001289

.200 18.37*7 .363*8 2.22*9 - . 1 *07E +00 . 31293 .00011*9

.000 20. **69 .38*25 2.9915 - . 1 177E+00 .3520* .0000912

. 800 23.2236 .*1565 3.9927 -.9909E-01 .39563 .0000611

.600 26.9091 .*5972 5.2709 - , 8*2 2 E -01 .**391 .0000275

.*00 31.7*33 .51873 6.9723 -.723*E-01 .*9713 -.0000092

.200 38.00*5 .59517 8 .8*78 -.6279E-0 1 .55559 -.0000*51

.000 *6.01** .691 76 11.2536 -•5506E-01 .61962 -.0000831

.800 56.1*17 .81157 1* .152* -. *8735-01 .68963 -.0001227

.600 68.8080 .95783 17.6128 - • *3* 9E -0 1 . 76605 -.00016*7

.*00 8* .*916 1.13*15 21.7086 - , 3 91 3 E-0

.8*939 -.0002103

104
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 420.000 K DEN 0 Z DP/OD DD/DT DP/DT 02 p / DT 2 MOL /L MPA MPA-L/MOL MOL /L /K MPA/K M8A/K/K

.800 2 .5929 .92312 3.0245 -.2383E-02 .00721 -.0000021

1.600 4.8589 .86962 2.6422 -.5912E-02 .01562 -.0000096

2.400 6.8201 .81376 2.2612 - • 1 11 3 E-0

.02516 -.0000226

3.200 8.4807 .75892 1.8951 -•1881E-01 .03564 -.0000395

4.000 9.8633 .70612 1.5699 - . 298 3 E-0

.04683 -.0000577

4 .800 1 1.0079 .65672 1.3019 -.4494E-01 .05851 -.0000740

5.600 11.9627 .61172 1 .0953 - .6442 E-0

.07056 -.0000e52

6.400 12.7763 .57166 .9482 -.8750E-01 .08296 -.0000890

7.200 13.4946 .53671 . 8 567 -.1118E+00 .09581 -.0000340

8.000 14.1611 .50690 .8181 -.1336E+00 .10930 -.0000703

8.900 14.8173 .48217 .8310 -.1489E+00 .12371 -.0000512

9.600 15.5037 .46246 . 8925 -.1562E+00 .13938 -.0000275

10.400 16.2560 .44760 .9935 -.1577E+00 .15664 -.0000023

11.200 17.1025 .43728 1.1301 - • 1 55 6 E 00 .17587 .0000220

12.000 18.078P .43142 1.3217 -.1494E+00 .19743 .0000433

12.800 19.2380 .43039 1.5914 -.1393E*00 .22172 .0000591

13.600 20.6527 .43486 1.9651 -.1268E+00 .24911 . 0000675

14.400 22.4176 .44580 2.4719 -.1133E+00 .27997 .0000676

15.200 24.6520 .46443 3.1444 - . 1 001 E 00 .31461 .0000592

16.000 27.5024 .49223 4.0183 -.8793E-01 .35335 .0000435

16.800 31.1454 .53088 5.1328 -.7723E-01 .39643 .0000219

17.600 35.7904 .58233 6.5306 - . 6 80 1 E-0

.44412 -.0000041

19.400 41.6824 .64871 8.2585 -.6014E-0

.49670 -.0000334

19.200 49.1058 .73240 10.3684 -.534 9E-01 .55447 -.0000551

20.000 58.3890 .93602 12.9180 -.4782 E-0 1 .61779 -.0000992

20.900 69.9086 .96246 15.9709 -.4302E-C1 .68703 -.0001353

21.600 84.0953 1.11489 19.5970 -.3892E-01 .76264 -.0001754

105
Tab 1 e 11 Continued

HYDROGEN SULFIDE ISOTHERM AT 450.000 K

DEN P Z DP/DD DO/DT DP/DT D2P/DT2

MOL /L MPA M°A-L /MOL MOL/L /* MPA /K MP A/K /K

. 800 2.8082 .93819 3.3148 -.2158E-02 . 00715 -.0000015

1.600 5.3236 .88928 2.9747 -.5169E-02 .01538 -.0000069

2.400 7.5660 .84257 2.6306 -.9351E-02 .02460 -.0000157

3.200 9.5344 .79634 2.2940 -.1511E-01 .03467 -.0000267

4.000 11.2456 .75140 1.9913 -.2281E-01 .04542 -.0000379

4.800 12.7346 .70908 1.7408 -.3259E-01 .05673 -.0000475

5.600 14 .0469 .67041 1.5502 - .442 1 E-0 1 .06854 -.0000538

6.400 15.2313 .63607 1.4211 - . 5691 E-0 1 . 08087 -.0000553

7.200 16.3370 .60644 1.3533 -.6934E-01 .09383 -.0000523

8 . 000 17.4130 .58175 1.3470 -.798 9F-0

.10762 -.0000450

8.800 18.50P8 .56214 1 .4029 -.8730E-01 .12247 -.0000344

9.600 19.6737 .54773 1.5191 -.9127E-01 .13865 -.0000219

10.400 20.9531 .53848 1.6869 -.9276E-C1 .15647 -.0000088

11.200 22.3852 .53419' 1.9029 -.9261E-01 .17622 .0000038

12.000 24 .0160 .53490 2 .1873 -.9063E-01 .19824 .0000141

12.800 25.9093 .54100 2.5634 -. 8694E-0. 22285 .0000215

13.600 28.1467 .55319 3.0568 -.8192E-01 .25041 .0000246

14.400 30.8391 .57239 3.6959 -.7610E-01 .28124 .0000228

15.200 34 . 1094 .59977 4.5123 -.6996E-0.31567 .0000157

16.000 38.1154 . 63670 5.5411 - . 6 38 8 E -0

.35399 .0000035

16.800 43.0420 .68475 6.8208 - . 5 8 1 3 E -0.39650 -.0000133

17.600 49.1070 .74573 8 .3944 -•5283E-01 .44351 -.0000341

18.400 56.5641 .82163 10 .3095 -.4804E-01 .49529 -.0000584

19.200 65 . 7073 .91467 12.6189 -.4376E-01 .55219 -.0000357

20.000 76.8752 1.02733 15.3818 - . 3 99 5 E-0.61454 -.0001159

106
Table 11. Continued.

hydrogen sulfide isotherm at 500.000 K DEN P Z DP/DD DD/DT DP/DT 02 0 / 0 T 2 * OL /

MPA MPA-L/MOL MOL /L /K MPA/K ME> A /K /K

.800 3.16*2 .951*2 3.7908 -.1 871E-02 .00709 -.0000010

1.600 6.0851 .91*83 3.5117 -.*301E-02 .01510 -.00000*3

2. *00 e .779* . 87993 3.2220 - . 7** 5 E -02 .02399 -.0000095

3.200 11.2*00 .8**91 2.9317 -.11*8E-01 .0336* -.0000158

*.000 13 .*773 .810*7 2 .66«2 -.16*8E-01 ,0*39e -.0000221

*.800 1 5 . 5221 .77787 2. *531 - . 223 9E -0 1 . 05*9* -.0000273

5.600 17. *185 .7*820 2.2986 -.289*E-01 .06652 -.0000307

6. *00 19.2177 .72229 2.2107 -.3563E-01 .07878 -.0000320

7.200 20 . 97** .70073 2 .1932 -,*187E-01 .0918* -.0000311

8.000 22 . 7*66 .6839* 2.2*98 - . *70 5E-0 1 .10586 -.0000233

8.800 2* .59*6 .67228 2.3833 -• 8079E-01 .12105 -.00002*2

<5.600 26.580* .66601 2.5935 - . 5307F-0.1376* -.0000193

10. *00 28.7627 .66526 2.8725 -,5*26E-01 .15587 -.00001**

11 .200 31.1938 .66995 3.2179 -. 5*70E-01 .17601 -.0000101

12.000 33.93*7 .68023 3.6509 -.5*33E-01 .1983* -.0000070

12.800 37.06*9 .6965* * .195* -.5319E-01 .2231* -.0000059

13.600 *0.6838 .71958 * .8770 -.51*18-01 .25073 -.0000072

1*.*00 **.9123 .75023 5.72*2 -. *916E-01 .281*0 -.000011*

15.200 *9.89*9 .78960 6.7679 -,*661E-01 .315*7 -.0000189

16.000 55.8026 .83893 8.0*29 -.*392E-01 .35323 -.0000296

16.800 62.835* .89968 9.5877 -.*120E-01 .39*98 -.0000*37

17.600 71.2263 .973*7 1 1 . A*5* -.38538-01 . **10* -.0000609

18. *00 81 .2*** 1.06211 13.66** -•3599E-01 .*9173 -.0000812

107
Table 11 Continued

HYDROGEN SULFIDE ISOTHERM AT 550.000 K

DEN P Z DP/DD DD/DT DP/DT D2°/DT2

MOL/L MPA MPA-L/MOL MOL /L /K MP A/K MPA/K/K

.400 1 .7892 .97816 4.3876 - . 7 80 2 E -0 3 .00342 -.0000001

.600 3.5178 .96156 4.2599 -.1655E-02 .00705 -.0000007

1.200 5.1991 .94743 4.1475 - . 262 5 E -02 .01089 -.0000016

1.600 6.93 57 .93425 4.0346 -.3701E-02 .01493 -.0000029

2.000 8.4261 .92130 3.9168 - . 4 89 5 E -0 2 .01917 -.0000044

2.400 9.9685 .90828 3.7944 -.6220E-02 .02360 -.0000063

2.800 11.4614 .99512 3.6704 -.7687E-02 .02821 -.0000083

3.200 12.9051 .88188 3.5485 - • 930 1

E -0 2 .03300 -.0000104

3.600 14.3010 .86869 3.4326 -.1106E-01 .03796 -.0000125

4.000 15.6524 . 85570 3.3259 -•1295E-01 .04309 -.0000145

4.400 16.9634 .84307 3.2314 -.1497 E -0

.04837 -.0000163

4.eoo 18.2394 .83094 3 .1510 - . 1 70 8 E -0

.05383 -.0000179

5.200 19.4864 .81946 3.0866 - . 1 92 6 E -0

.05946 -.0000193

5.600 20.7109 .80875 3.0392 -.2147E-01 .06526 -.0000204

6. COO 21.9201 .79990 3.01C0 - • 2 367 E-0

.07126 -.0000213

6.400 23.1215 .79002 2.9998 -.2582E-01 .07746 -.0000218

6.800 24. 3226 .78217 3.0094 -.2787E-01 .08388 -.0000220

7.200 25.5318 .77544 3.0396 - . 2 97 8E-0

.09053 -.0000220

7.600 26.7572 .76989 3.0911 -.3153E-01 .09745 -.0000217

8. COO 28.0075 .76557 3 .1645 -•3307E-01 .10464 -.0000212

8.400 29.2918 .76255 3.2604 -.343 9E -0

.11214 -.0000206

8.800 30.6189 .76087 3.3791 - .3 550E-0

.11996 -.0000199

9.200 31.9981 .76057 3.5207 - . 3 63 9 E -0.12814 -.0000191

9.600 33.4385 .76169 3 .*847 -.3710E-01 .13670 -.0000184

10.000 34 . 9487 .76424 3.8697 - • 3764E-01 .14567 -.0000176

10.400 36.5368 .76824 4.0740 -•3806E-01 .15508 -.0000170

10.800 38.2106 .77368 4.2983 -•3838E-01 .16495 -.0000165

11.200 39.9796 .78057 4.5458 - . 3 85 7E-0

.17533 -.0000162

11.600 41.8507 .79894 4.8195 - . 3 864 E -0 1 .18624 -.0000162

12.000 43.8381 .79886 5.1223 -.3 860E-01 .19772 -.0000164

12.400 45.9529 .81039 5.4574 - . 3 844 E-0.20980 -.0000170

12.800 48.2087 .82360 5 .8280 - • 3 81 8 E-0

.22251 -.0000131

13.200 50.6205 .83860 6.2375 -•3782E-01 .23589 -.0000195

13.600 53.2044 . 85548 6.6892 -.3737E-01 .24997 -.0000214

14.000 55.9780 . 87436 7.1870 -•3684F-01 .26480 -.0000239

14.400 58.9606 .99537 7.7344 -.3625E-01 .28040 -.0000269

14.800 62.1727 .91863 8.3357 -.3561E-01 . 29681 -.0000305

15.200 65.6369 .94429 8 .9950 -.3492E-01 .31408 -.0000347

15.600 69.3771 .97251 9.7167 - , 341 9E-0

.33223 -.0000396

16.000 73.4192 1 .00344 10.5057 -•3344E-01 .35131 -.0000450

16.400 77.7912 1.03726 11.3667 -.3267E-C1 . 37136 -.0000511

16.800 82.5229 1.07415 12.3052 -.3189E-01 . 39240 -.0000579

108
Table 11. Continued.

HYDROGEN SULFIDE ISOTHERM AT 600.000 K DEN P 7 DP/DD

MOL/l MPA mpa-l/mol

.400 1.9602 .98233 4 .8272

.800 3.0696 . 96959 4.7246

1.200 5.7418 .95913 4.6370

1.600 7.5790 .94952 4.5404

2.000 9.3797 .94010 4 .4541

2.400 11 .1416 .93057 4.3545

2.800 12.8630 .92086 4.2524

3.20C 14.5437 .91104 4.1520

3.600 16.1853 .90122 4 .0571

4 . 000 17.7906 .89154 3.9714

4.400 19.3640 .88218 3.8979

4.800 20.9109 .87326 3.8393

5.200 22.4377 . 86494 3.7973

5.600 23.9512 .85734 3.7738

6.000 25.4593 .85056 3.7698

6.400 26.9699 .84472 3.7867

6.800 28.4916 .83989 3.8255

7.200 30.0333 .03615 3.8872

7.600 31.6045 .83358 3.9727

0.000 33.2148 .83225 4.0829

0.400 34.8742 .83222 4.2185

8 .300 36.5931 .83354 4.3801

0.200 36.3ei8 .83628 4.5677

9.600 40.2507 . 84C46 4.7010

10.000 42.2099 .84611 5.0109

10.400 44.2688 .85325 5.2795

10.800 46.4366 . 86189 5.5639

11.200 48.7235 .87203 5.8753

11.600 51.1409 .80374 6.2167

12.000 53.7013 .89705 6.5914

12.400 56.4189 .91204 7.0025

12.800 59.3087 .92880 7.4534

12.200 62.3873 .94740 7.9473

13.600 65.6728 .96796 8.4879

14.000 60.1844 .99059 9.0789

14.400 72.9431 1.01539 9.7242

14.800 76.9715 1.04251 10.4270

15.200 81.2937 1.07200 11.1939

DD/DT DP/DT D2°/DT2

MOL /L /K MP A/K MPA /K/K

— . 707 8 E — 0 3 .00342 -.0003001

-.1487E-02 .00702 -.0000005

-.2334E-02 .01082 -.0030011

-.3256E-02 .01481 -.0000020

-.4262E-02 .01098 -.0003032

-.5359E-02 .02334 -.0000045

-.6553E-02 .02787 -.0000059

-.7844E-02 .03257 -.0000073

-.9220E-O2 .03744 -.0300308

- . 1 070 E -0 1 . 04248 -.0030103

-.1223E-01 .04769 -.0000116

-.1382E-01 .05307 -.0030129

- . 1 54 4 E -0

.05864 -.0000140

-.1706E-01 .06439 -.0000149

“ • 1 866 E -0

.07035 -.0000157

“ . 202 1 E-0

.07652 -.0000163

-.2168E-01 .08292 -.3300160

-. 2304E-01 .08957 -.0000171

-.2429E-01 .09648 -.0000173

-.2539E-01 .10368 -.0000174

-.2636E-01 .11119 -.0300175

-.2717E-01 .11903 -.0000175

-.2785E-01 .12722 -.0000176

-.2840E-01 .13580 -.0000177

-.2885E-01 .14470 -.0000179

-.2921E-01 .15419 -.0003131

-.2949E-01 .16407 -.0000185

-.2969E-01 .17444 -.3000191

- . 2 90 1 E-0

.16533 -.0000199

-.2985E-01 .19677 -.0003210

-.2902E-C1 .20880 -.0300223

- . 2 97 1

E -C

.22144 -.0000240

-.2 954 E — 0

.23473 -.0000260

- • 2930E-0 1 . 24871 - . 03032 6<« - . 2 90 1

E -0

.26340 -.0000312

- . 2 06 8 E-0 1 .27884 -.0000345

-.2 03OE-O1 .29507 -.3000302

-•2788E-01 . 31213 -.0300424

109
Table 11. Continued

HYDROGEN SULFIDE ISOTHERM AT 650. OOO K

DEN p Z DP/DD DD/DT DP/DT D2P/DT2

MOL /L MPA MP A-L/MOL MOL/L/K MPA/K MP A/K/K

.AGO 2.1309 , 9857A 5 . 26 5

-.6A80E-03 .003A1 -.0000001

.000 A .2202 .97610 5.1859 - . 1 3 50 E-02 .00700 -.DOOOOOA

1.200 6.2816 .96858 5.1215 - . 2103E-02 .01077 -.0000009

1.600 8.3172 .96185 5.0557 -.2912E-02 . 01 A72 -.0000015

2.000 10.3253 .95526 A. 9837 -.3782E-02 .01685 -.000002A

2 . A 00 12 .303A . 9A 8 5 6 A. 9059 -.A718E-02 . 02 31 A -.0000033

2.800 1 A . 2 A9 6 . 9A1 66 A. 8253 -• 5722E-02 .02761 -. OOOOOAA

3.200 16.1638 . 93 A6A A ,7A60 “.6795 E-02 .03225 -.0000055

3.600 18.0A72 .92759 A. 6722 -.7931E-02 .03706 -.0000066

A .000 19.9028 .92067 A. 6079 - • 912 2 E-02 . 0A203 -.0000077

A. AOO 21.7352 . 91 AOS A. 5562 -.1036E-01 • 0A718 -.0000038

A. 800 23.5A99 .90782 A.52C1 -.1 162E-01 .05251 -.0000093

5.200 25.3536 .90217 A. 5017 -.1289E-01 .05803 -.0000107

5.600 27.1538 .89721 A. 5029 -.1A15E-01 .0637A -.0000116

6.000 28.9507 .89306 A. 5253 -.1539E-01 . 06966 -.0000123

6. AOO 30.7771 .88981 A. 5703 -.1658E-01 .07579 -.0000130

6.000 32.6182 .88757 A. 6392 -.1771E-01 .08217 -.0000136

7.200 3 A , A 9 1 B . 886A1 A .7332 -.1876E-01 .08879 -.00001A1

7.600 36. A062 . 886A1 A. 853A - . 1 972 E -0

.09569 -.00001 A6

8.000 38.3781 .88766 5.0009 -.2057E-01 .10287 -.0000151

0. AOO AO. A127 .89020 5.1765 -.2132E-01 .11037 -.0000155

0.800 A2.5232 . B9A12 5.3810 - • 2 1 96 E-0

.11819 -.0000160

9.200 A A , 721, 899A5 5.61A5 -.2251E-01 .12637 -.0000165

9.600 A 7 .0187 .90625 5.8769 -.2296E-01 . 13A93 -.0000170

10.000 A9.A265 . 91A 56 6.1669 -.2333E-01 . 1 A 3 8 9 -.0000177

10. AOO 51 . 9557 , 92 A 3 8 6 , A 831 -.2 36AE-01 .15328 -.000018A

10.800 5A. 6166 .93573 6.8265 -.2390E-01 .16312 -.0000193

11.200 57 o A2 1. 9A86A 7.2006 -.2A09E-01 . 1 7 3 A 5 -.000020A

11.600 60.3816 .96316 7 , 6 0 8 A -.2 A22E-01 .18A28 -.0000217

12.000 63.5126 .97933 8.0533 -.2 A30E-01 .19566 -.0000231

12. AOO 66.8296 • 9972

8.5385 -.2A31E-01 . 20761 -.0000 2 A9

12.800 70. 3A92 1.01695 9.067A -.2A28E-01 .22016 -.0000269

13.200 7A.0898 1 .03857 9 , 6 A 35 -.2A20E-C1 . 2 3 33 A -.0000291

13.600 70.0706 1.06219 10.2705 -.2A07E-01 • 2 A 7 1 9 -.0000318

1A .000 02.3135 1.08791 10.9521 - • 2390E-0 1 . 2617A -. 00003A7

110
Table i 1 . Continued.

hydrogen sulfide is-otherh AT 700.000 K DEN P Z DP/DD DD/DT DP /DT D2P/OT2

MOL /

MPA MP A-L/MOL MOL/ L/K MP A/K MP A/K/K

. A 00 2.301* .98856 5.702* - • 5 97 7 E-0 3 .003*1 -.0000001

.800 * . 569Q .981*8 5 .6**9 -.1238E-02 .00699 -.0000003

1.200 6.819? .97638 5.602* -.1916E-02 .01073 -.0000007

1.600 9.0515 .97200 5.5582 -.2636E-02 .01*65 -.0000012

2.000 11 .26*9 .96775 5.5076 - . 3*0 3 E-0

.0187* -.000001

2. *00 13 .*567 .96337 5 .*509 - . *2 1 9 E -0 2 .02300 -.0000026

2.800 15.6252 .95881 5.3913 -. 5086E-02 .027*2 -.000003*

3.200 17.7699 .95*12 5.3330 -.6002E-02 .03201 -.00000*3

3.600 1<=. 992* .9*9*0 5.2803 - . 6 96 2 E -0 2 .03676 -.0000052

*.000 21 . 9955 . 9**80 5 .2375 -.7960E-02 .0*169 -.0000061

* . *00 2*. 08*1 . 9 AO * 7 5.2090 -.998AE-02 . 0*679 -.0000070

*.800 26.16*1 .93655 5.19*8 - . 1 002 E -0

.05207 -.0000079

5.200 28.2*25 .93318 5.2005 -.1107 E-0

.05755 -.0000087

5.600 30.3272 .930*9 5.2270 -•1209E-01 .06322 -.000009*

6.000 32. *271 .92859 5.2763 -.1310E-01 . 06910 -.0000102

6. *00 3*. 5515 . 92758 5.3*99 -,1*06E-01 .07520 -.0000109

6.800 36.7105 .92757 5. *89* -.1A96E-01 .0815* -.0000115

7.200 36.91*7 .9286* 5.5761 -•1581E-C1 .0881* -.0000122

7.600 *1 .1752 . 93087 5.7313 -.1658E-01 . 09501 -.0000123

8.000 *3.5037 .93*33 5.9162 - . 1 72 7 E-0

.10216 -.000013*

8. *00 *5.9122 .93911 6.1318 -.1788E-01 .10963 -.00001*1

8.800 *8 .*133 .9*525 6.3790 - . 1 8* 1 E-0

.117*2 -.00001**

0.200 51.0197 .95283 6.6581 -.1886E-01 .12557 -.0000155

9.600 53 .7**1 .96189 6.9690 - . 1 92 * E -0 1 .13*09 -.0000163

10.000 56.5990 .972*7 7.3107 - . 1 95 6 E -0

.1*301 -.0000173

10. *00 59.5965 .98*59 7 .6816 - . 1 98 3 E-0

.15236 -.0000133

10.800 62.7*3* .99826 8.0832 -. 2006E-0 1 .16215 -.0000195

11.200 66.0676 1.01353 8.5187 -•202*E-01 .172*1 -.0000209

11.600 69.568* 1.030*3 8.9916 -•2037E-01 .18318 -.0000223

12.000 73.2663 1.0*903 9.5052 -.20A6E-01 .19**8 -.00002*0

12. *00 77.178* 1.069*0 10.0629 -. 2050E-0 1 . 2063* -.0000259

12.800 81.3230 1.09161 10.6691 - , 205 1 E-0 1 .21878 -.0000280

111
Table 12. The J ou 1 e-Thoi.ison inversion locus for h^droyen sulfide

T»K MOL/t P , M P 4 2 80 24 .055 1.256

2 90 23.402 1.642

300 22.712 2.125

310 22.498 8.326

320 22 .264 14.227

330 22 .040 19.836

340 21.816 35.164

350 21.592 30.218

360 21.368 35.009

370 21.144 39.544

3 80 20.920 43.837

3 90 20.696 47.882

400 20.472 51.703

410 20.247 55.302

420 20.02? 53.683

430 19.799 61.870

440 19.575 64.856

450 19.351 67.654

460 19.128 70.27?

470 16.90“’ 7 2 .719

480 16.663 75.002

490 1 6.462 77.129

500 1 8.241 79.109

510 16.021 80.948

520 17.803 82.665

530 17.5e5 94.235

540 17.369 85.698

550 17.155 87.C48

T,k MOL /L P,8PA

560 16.942 88.292

570 16 .731 89.438

580 16.521 90.499

590 16.314 91.454

6CC 16.109 92.335

610 15.904 93.140

620 15.703 93.87?

630 15.504 94.535

640 15.307 95.135

650 15.112 95.675

660 14.911 96.159

67C 14.729 96.590

680 14.541 96.972

69C 14.356 97.308

7 C 0 14.173 97.600

710 13 .99? 97.851

720 13.814 98.065

730 13.638 99.242

740 13.465 98.386

7 5 C 13.294 98.491

760 13.125 98.582

77C 12.959 98.638

780 12.795 98.668

79C 12 .633 98.675

800 12.474 9e .659

8 1 C 12.318 98.622

820 12.163 98.567

9 3 C 12.011 98.493

112
Table

13.

Properties

of

saturated

liquid

hydroyen

sulfide

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NBS-1 14A IREV. 2-80

U.s. DEPT. OF COMM.

4. TITLE AND SUBTITLE

HYDROGEN SULFIDE PROVISIONAL THERMOPHYSICAL PROPERTIES FROM IE TO 75 MPa

18 TO 700 K AT PRESSURES

5. AUTHOR(S)

Robert D. Goodwin

6. PERFORMING ORGANIZATION (If joint or other than N BS, see instructions)

NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE

WASHINGTON, D.C. 20234

7. Contract/Grant No.

8. Type of Report & Pe r iod Covered

BIBLIOGRAPHIC DATA

SHEET (See instructions)

1. PUBLICATION OR

REPORT NO. NBSIR 83-1694

2. Performing Organ. Report No, 3. Publication Date

October 1983

9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State. ZIP

)

Gas Research Institute

8600 West Bryn Mawr Avenue

Chicago, Illinois 60631

10. SUPPLEMENTARY NOTES

Document describes a computer program; SF-185, FIPS Software Summary, is attached.

11. ABSTRACT (A 200-word or less factual summary of most significant information. I f document includes a significan:

bibliography or literature survey, mention it here) Thermophysical properties of hydrogen sulfide are derived from physical properties

data by using our nonanalytic equation of state, and are tabulated along isobars at integral temperatures. Results include vapor pressures, orthobaric densities, the

second virial coefficient, the equation of state, the ideal gas state functions,

compressibility factors, densities, derivatives of the P(p,T) surface, heats of

vaporization, internal energies, enthalpies, entropies, specific heats, fugacity

coefficients, speeds of sound, and the Joule-Thomson inversion. Thermofunctions by

another author are compared with present results.

12. KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate v,-. densities; enthalpies; entropies; equation of state; fugacities; heats

tion; hydrogen sulfide; isobars; isochores; isotherms; Joule-Thomson i obari c densities; specific heats; speeds of sound; vapor pressures; vi

words by semicolons

of vaporizanversion; orthrial equation.

13. AVAILABILITY

rXl Unlimited

[

j For Official Distribution. Do Not Release to NTIS

|—| Order From Superintendent of Documents, U.S. Government Printing Office. Washington. D.c. 20402.

|~X| Order From National Technical Information Service (NTIS), Springfield, VA. 22 16 1

14. NO. OF

PRINTED PAGES

175

15. Price $16.00

' “ “ u$COmm»OC 6045*° *

:

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