NOTE: Draft determinations are marked with a " * " beside the RBLC ID.

Required fields are denoted by "+".

Report Date: 05/05/2010            Control Technology Determinations (Freeform)
Facility Information: ARVAH B. HOPKINS GENERATING STATION

RBLC ID: FL-0261

+ Corporate/Company Name: CITY OF TALLAHASSEE

+Facility Name: ARVAH B. HOPKINS GENERATING STATION Facility County: LEON Facility State: FL Facility ZIP Code: 32304 Facility Country: USA Facility Contact Name: ROBERT E. MCGARRAH Facility Contact Phone: 8508915534 Facility Contact Email: MCGARRAR@TALGOV.COM EPA Region: 4 Agency Code: FL001 Agency Name: FLORIDA DEPT. OF ENVIRONMENTAL PROTECTION Agency Contact: MS. TERESA HERON Agency Phone: (850)921-9529 Agency Email: teresa.heron@dep.state.fl.us Other Agency Contact Info: PROJECT ENGINEER: MIKE HALPIN, PROFESSIONAL ENGINEER BUREAU OF AIR REGULATION PHONE NO. 850/921-9519

+Permit Number: PSD-FL-343

+ SIC Code: 4911 NAICS Code: 221112 Facility Registry System Number: 110011349656 Application Accepted Received Date: 08/13/2004 ACT Permit Issuance Date: 10/26/2004 ACT Date determination entered in RBLC: 12/17/2004 Date determination last updated: 03/17/2005 Permit Type: B: Add new process to existing facility Permit URL: Facility Description: THIS FACILITY CONSISTS OF TWO FOSSIL FUEL FIRED STEAM GENERATORS AND TWO FOSSIL-FUEL FIRED COMBUSTION TURBINES AND ANCILLIARY EQUIPMENT. THIS PSD PERMIT IS FOR THE ADDITION OF TWO, 50 MW, SIMPLE CYCLE GENERAL ELECTRIC LM6000 PC SPRINT COMBUSTION TURBINES. Permit Notes: Previous PagePermit Notes:

Affected Boundaries: ARVAH B. HOPKINS GENERATING STATION

+Boundary (Class 1 Area or US Border Name): Bradwell Bay Boundary Type (Class 1 or Intl Border): CLASS1 Distance: < 100 km Class 1 Area State: FL

+Boundary (Class 1 Area or US Border Name): Saint Marks Boundary Type (Class 1 or Intl Border): CLASS1 Distance: < 100 km Class 1 Area State: FL

Facility-wide Emissions: ARVAH B. HOPKINS GENERATING STATION

+Pollutant Name: Carbon Monoxide Facility-wide Emissions Increase: 37.5000 (Tons/Year)

+Pollutant Name: Nitrogen Oxides (NOx) Facility-wide Emissions Increase: 52.2000 (Tons/Year)

+Pollutant Name: Particulate Matter (PM) Facility-wide Emissions Increase: 64.2000 (Tons/Year)

+Pollutant Name: Sulfur Oxides (SOx) Facility-wide Emissions Increase: 43.4000 (Tons/Year)

+Pollutant Name: Volatile Organic Compounds (VOC) Facility-wide Emissions Increase: 14.1000 (Tons/Year)

Process Information: ARVAH B. HOPKINS GENERATING STATION

+Process Name: TURBINE, SIMPLE CYCLE (2) FUEL OIL

+Process Type: 15.190 Primary Fuel: FUEL OIL Throughput: 50.00 Throughput Unit: MW Process Notes: HEAT INPUT: 434 MMBTU/HR (LHV) AT 29 DEGREES F, 0.05 %Process Notes: HEAT INPUT: 434 MMBTU/HR (LHV) AT 29 DEGREES F, 0.05 % FUEL OIL. HOURS OF OPERATION 5840 HOUR PER YEAR, 4000 HOURS MAY BE ON DISTILATE FUEL OIL. MODEL GENERAL ELECTRIC LM6000PC SPRINT

Pollutant Information: ARVAH B. HOPKINS GENERATING STATION - TURBINE, SIMPLE CYCLE (2) FUEL OIL

+Pollutant Name Sulfur Dioxide (SO2) Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

+ CAS Number: 7446-09-5 Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: LOW SULFUR FUEL (0.05% S) FUEL SAMPLING EACH DELIVERY Emission Limit 1: 10.3100 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: HOURS OF OPERATION 5840 DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL.+Pollutant Name Particulate matter, filterable < 10 μ (FPM10) Pollutant Group(s): ( Particulate Matter (PM) )

+ CAS Number: PM Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: CLEAN FUEL Emission Limit 1: 14.9400 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: HOURS OF OPERATION 5840 DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL. THE 10 % OPACITY STANDARD IS FOR FUEL OIL (14.94 LB/HR) AND NATURAL GAS (2.45 LB/HR).

+Pollutant Name Volatile Organic Compounds (VOC) Pollutant Group(s): ( Volatile Organic Compounds (VOC) )

+ CAS Number: VOC Test Method: Unspecified

+ Control Method Code: N

+ Control Method Description:Emission Limit 1: 3.0000 Emission Limit 1 Unit: PPMVD @15% O2 Emission Limit 1 Avg. Time/Condition: INITIAL ONLY TEST Emission Limit 2: 2.6600 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: NOT A PSD POLLUTANT. HOURS OF OPERATION 5840 DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL.

+Pollutant Name Sulfuric Acid (mist, vapors, etc) Pollutant Group(s): ( InOrganic Compounds , Particulate Matter (PM) )

+ CAS Number: 7664-93-9 Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: LOW SULFUR FUEL 0.05 % S CONTENT Emission Limit 1: 9.6600 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition:Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: HOURS OF OPERATION 5840 DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL (0.05% S).

+Pollutant Name Nitrogen Oxides (NOx) Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

+ CAS Number: 10102 Test Method: Unspecified

+ Control Method Code: B

+ Control Method Description: WATER INJECTION SYSTEM, SCR Emission Limit 1: 5.0000 Emission Limit 1 Unit: PPMVD @15% O2 Emission Limit 1 Avg. Time/Condition: 24 HOURS BLOCK AVERAGE Emission Limit 2: 8.6700 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 5.0000 Standard Emission Limit Unit: PPM @15% O2 Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSDOther Applicable Requirements: NSPS , MACT Did factors, other then air pollution technology considerations influence the BACT decisions?: N

+Percent Efficiency: 80.000 Compliance Verified: Unknown Cost Effectiveness: 6,700 ($/ton) Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: HOURS OF OPERATION 5840, DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL.

+Pollutant Name Carbon Monoxide Pollutant Group(s): ( InOrganic Compounds )

+ CAS Number: 630-08-0 Test Method: Unspecified

+ Control Method Code: A

+ Control Method Description: OXIDATION CATALYST Emission Limit 1: 6.0000 Emission Limit 1 Unit: PPMVD @ 15 % O2 Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 6.3500 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 6.0000 Standard Emission Limit Unit: PPM @ 15% O2 Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: UnknownCost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes: HOURS OF OPERATION 5840 DURING ANY CONSECUTIVE 12-HR PERIOD, 4000 OF WHICH MAY BE ON DISTILLATE FUEL OIL.

+Pollutant Name Visible Emissions (VE) Pollutant Group(s):

+ CAS Number: VE Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: CLEAN FUEL Emission Limit 1: 10.0000 Emission Limit 1 Unit: % OPACITY Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 10.0000 Standard Emission Limit Unit: % OPACITY Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:Process Information: ARVAH B. HOPKINS GENERATING STATION

+Process Name: TURBINE, SIMPLE CYCLE, NATURAL GAS, (2)

+Process Type: 15.110 Primary Fuel: NATURAL GAS Throughput: 50.00 Throughput Unit: mw Process Notes: HEAT INPUT 445 MMBTU/H (LHV) AT 29 DEGREES F. HOURS OF OPERATION: 5840, 4000 HOURS MAY BE FUEL OIL. GENERAL ELECTRIC LM6000PC SPRINT.

Pollutant Information: ARVAH B. HOPKINS GENERATING STATION - TURBINE, SIMPLE CYCLE, NATURAL GAS, (2)

+Pollutant Name Nitrogen Oxides (NOx) Pollutant Group(s): ( InOrganic Compounds , Oxides of Nitrogen (NOx) , Particulate Matter (PM) )

+ CAS Number: 10102 Test Method: Unspecified

+ Control Method Code: B

+ Control Method Description: WATER INJECTION SYSTEM, SCR Emission Limit 1: 5.0000 Emission Limit 1 Unit: PPMVD @15% O2 Emission Limit 1 Avg. Time/Condition: 24 H AVERAGE Emission Limit 2: 8.6200 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 5.0000 Standard Emission Limit Unit: PPM @ 15% O2 Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: NSPS , MACT Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: 6,700 ($/ton) Incremental CostIncremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2004 Pollutants/Compliance Notes:

+Pollutant Name Particulate matter, filterable < 10 μ (FPM10) Pollutant Group(s): ( Particulate Matter (PM) )

+ CAS Number: PM Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: CLEAN FUELS Emission Limit 1: 2.4500 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

+Pollutant Name Carbon MonoxidePollutant Group(s): ( InOrganic Compounds )

+ CAS Number: 630-08-0 Test Method: Unspecified

+ Control Method Code: A

+ Control Method Description: OXIDATION CATALYST Emission Limit 1: 6.0000 Emission Limit 1 Unit: PPMDV @ 15% O2 Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 6.2700 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 6.0000 Standard Emission Limit Unit: PPM @ 15% O2 Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

+Pollutant Name Sulfur Dioxide (SO2) Pollutant Group(s): ( InOrganic Compounds , Oxides of Sulfur (SOx) )

+ CAS Number: 7446-09-5 Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: LOW SULFUR FUEL: NATURAL GAS Emission Limit 1: 1.1300 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg.Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

+Pollutant Name Volatile Organic Compounds (VOC) Pollutant Group(s): ( Volatile Organic Compounds (VOC) )

+ CAS Number: VOC Test Method: Unspecified

+ Control Method Code: N

+ Control Method Description: Emission Limit 1: 3.0000 Emission Limit 1 Unit: PPMVD @15% O2 Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 1.7900 Emission Limit 2 Unit: LB/H Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard EmissionStandard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

+Pollutant Name Acid Mist / Gases Pollutant Group(s): ( Acid Gasses/Mist , Particulate Matter (PM) )

+ CAS Number: Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: LOW SULFUR FUEL (NATURAL GAS) Emission Limit 1: 1.1500 Emission Limit 1 Unit: LB/H Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 0 Standard Emission Limit Unit: Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: Other Case-by-Case Other Applicable Requirements: Did factors, other thenDid factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness: Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

+Pollutant Name Visible Emissions (VE) Pollutant Group(s):

+ CAS Number: VE Test Method: Unspecified

+ Control Method Code: P

+ Control Method Description: CLEAN FUEL Emission Limit 1: 10.0000 Emission Limit 1 Unit: % OPACITY Emission Limit 1 Avg. Time/Condition: Emission Limit 2: 0 Emission Limit 2 Unit: Emission Limit 2 Avg. Time/Condition: Standard Emission Limit: 10.0000 Standard Emission Limit Unit: % OPACITY Standard Limit Avg. Time/Condition:

+ Case-by-Case Basis: BACT-PSD Other Applicable Requirements: Did factors, other then air pollution technology considerations influence the BACT decisions?: U

+Percent Efficiency: Compliance Verified: Unknown Cost Effectiveness: Incremental Cost Effectiveness:Cost Verified (Y/N)?: No Dollar Year Used In Cost Estimates: 2005 Pollutants/Compliance Notes:

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