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Exhaust Emissions Sampling 

Daltite, Muskogee, OK 

Scrubber Inlet and Exhaust 

May 19, 2005 

Armstrong Envir-onmental, Inc. 

Project W-2462-05 

Report Prepared For: 

Bob Hurt 

Daltile 

7834 C. F. Hawn Freeway 

Dallas, TX 75217 

Report Prepared May 23, 2005 By: 

Armstrong Environmental, Inc. 

7715 Sovereign Row 

Dallas, Texas 75247 

(214) 631-0021 
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1 

-A 

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TABLE OF CONTENTS 

I. Introduction 

U. Summary 

III. Procedures 

N. Appendices 

A. Calculation Summaries 

B. Continuous Emissions Monitor Summaries 

C. Analytical Summaries 

D. Field Data Sheets 

E. Equipment Calibrations 

F. Standard Gas Certifications 

Page 

1 

2-4 

5-6 

7-12 

13 - 40 

41 - 118 

119 - 124 

125 - 129 

130 - 138 
in 

I. INTRODUCTION 

~ A series of tests was performed on the inlet and exhaust associated with the scrubber at 

the Daltile facility in Muskogee, OK on May 19, 2005. 

' The purpose of this test series was to determine the exhaust emission rate of PM, CO, 

NOx, VOC, S02, HF, HCL, and C12 and the removal efficiency of PM, HF, HCL, and 

■ C12. 

Testing followed procedures detailed in Title 40: Code of Federal Regulations (40:CFR). 

Sampling was performed by Richard Taylor, Dan Barrera and Tom Armstrong of 

Armstrong Environmental, Inc. using two Apex Method 5 sampling trains, an EcoPhysics 

70S continuous NOx analyzer, a Fuji 3300 NDIR continuous CO analyzer, a Western 

Research 721 AT continuous S02 analyzer, and a ThermoEnvironmental Mode151 

continuous FID analyzer. 

Three one hour test repetitions were performed, commencing at 9:10 AM and ending at 

1:13 PM. 

Submitted by: 

ic. 

~ 1 

r 

; 
N 

556.5 

36.86 

47876.3 

21656.6 

1299394 

11.00% 

5.00 

16.00 

10:40 AM 

11:40 AM 

33.069 

103.6303 

23.55 

0.010988 

2.040431 

13.72 

0.006402 

1.188735 

3.229166 

88.27 

113.3548 

7.647588 

11.04 

3.993807 

0.956533 

3 

558.8 

37.41 

48592.9 

22105.5 

1326329 

10.27% 

4.00 

17.00 

12:10 PM 

1:14 PM 

33.597 

103.1485 

26.55 

0.012193 

2.311099 

2.66 

0.001222 

0.231545 

2.542644 

97.17 

122.8263 

8.45836 

10.79 

3.841953 

0.939237 

105.66 113.83 

74.35084 78.84252 

9.154474 9.908738 

t 

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SUMMARY OF EMISSIONS TEST DATA 

~ 

Table : 2 

Plant : Daltile, Muskogee, OK 

Location : Scrubber Inlet 

Operator : R. Taylor 

Test Date : 19-May-05 

Repetition : 1 

STACK GAS 

Temperature, F 554.4 

Velocity, fps 37.71 

Volume Flow, acfm 48981.9 

scfm 22142.4 

scfh 1328545 

Moisture, % 11.24% 

CO2, % 5.00 

02, °% 16.00 

SAMPLE 

Start Time, hrs:min 9:10 AM 

Finish Time, hrs:min 10:10 AM 

Sample Volume, scf 33.727 

Isokinetic Ratio, % 103.3725 

PARTICULATE 

Front Half 

Sample Weight, mg 22.23 

Concentration, gr/scf 0.01017 

Emissions, Ibs/hr 1.930868 

Back Half 

Sample Weight, mg 

Concentration, gr/scf 

Emissions, Ibs/hr 

Total Particulate, Ibs/hr 

HYDROGEN FLUORIDE 

Sample Weight, mg 

Concentration, ppm 

Emissions, Ibs/hr 

CHLORINE 

Sample Weight, mg 

Concentration, ppm 

Emissions, Ibs/hr 

HYDROGEN CHLORIDE 

Sample Weight, mg 

Concentration, ppm 

Emissions, Ibs/hr 

9.52 

0.004355 

0.826894 

2.757762 

91.17 

114.7946 

7.918469 

11.62 

4.121648 

1.009297 

112.83 

77.85209 

9.800609 

n 

i 3 
III. PROCEDURES 

The procedure for emissions sampling followed USEPA test methods as detailed in Title 

40: Code of Federal Regulations. The following methods were used: 

Method Title 

1 Sample and Velocity Traverses for Stationary Sources 

2 Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S 

Pitot Tube) 

3 Gas Analysis for CO2, 02, Excess Air and Dry Molecular Weight 

5 Determination of Particulate Emissions from Stationary Sources 

6C Determination of Sulfur Dioxide Emissions from Stationary Sources 

(Instrumental Analyzer Procedure) 

7E Determination of Nitrogen Oxides Emissions from Stationary Sources 

(Instrumental Analyzer Procedure) 

10 Determination of Carbon Monoxide Emissions from Stationary Sources 

25A Determination of Total Gaseous Organic Concentration using a Flame 

Ionization Analyzer 

26A Determination of Hydrogen Halides and Halogens Emissions from 

Stationary Sources 

02 and CO2 were determined using FyRite Analyzers. 

PM. HF, HCI, and C12 sampling was performed on the scrubber exhaust for 3 minutes at 

each of 20 points, 10 points per traverse, making a total run duration of 60 minutes. PM, 

HF, HCI, and C12 sampling was performed on the scrubber inlet for 5 minutes at each of 

12 points (traversing a single port twice) making a total run duration of 60 minutes. Each 

sampling train was configured as follows: 

Glass Sampling Nozzle 

Heated Glass Lined Probe 

Heated teflon filter 

Impinger # 1- 100 mis H20 

Impinger #2 - 100 mis 0.1 N H2SO4 

Impinger #3 - 100 mis 0.1 N NaOH 

Impinger 94 - 100 mis 0.1 N NaOH 

Impinger #5 - 200 grams silica Gel 

6 

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4 
rx 

Analysis for PM was performed on the probe wash, filter, and solution from the first 

~ impinger. HF and HCl analysis was performed on an aliquot from the first impinger, and 

the solution from the 2nd impinger. Analysis for C12 was performed on the solution from 

_ the 3rd and 4th impingers. Analysis was performed using a Dionex LC20 IC/HPLC. 

VOC as C3H8 was determined using a ThermoEnvironmental Model 51 continuous FID 

analyzer. The analyzer was calibrated with 48.8 ppm, 28.8 ppm, and 15.2 ppm C3H8 in 

Air USEPA Protocol 1 gas standards, zeroed with N2. 

i Nitrogen Oxides were determined using an EcoPhysics 70S continuous NOx analyzer. 

The analyzer was calibrated with 92.8 ppm and 51.3 ppm NOx in N2 EPA Protocol 1 gas 

standards, and zeroed with N2. 

~ 

Carbon monoxide was determined using a Fuji 3300 NDIR continuous CO analyzer. The 

analyzer was calibrated with 105 ppm and a 47.3 ppm CO in N2 EPA Protocol 1 gas 

, standards, and zeroed with N2. 

Sulfur dioxide was determined on the scrubber exhaust using a Western Research 721 AT 

e continuous S02 analyzer. The analyzer was calibrated with 101 ppm and a 50.1 ppm 

S02 in N2 EPA Protocol 1 gas standards, zeroed with N2. 

~ 

~ 6 
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Appendix A 
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1 

EMISSION TEST SUMMARY 

® PLANT : Daltile, Muskogee, OK 

DATE : 19-May-05 

PLACE : Scrubber Inlet 

RUN# : 1 

~ TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 90.7 

NOZZLE DIAMETER (lNCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) : 22.23 

METER COEFFICIENT (Y) : 0.993 PARTICULATE WEIGHT (Back half mg) : 9.52 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : •1.7 

~ GAS METER VOL.(Cu.Ft.) : 36.211 PERCENT CO2 5 

BAROMETRIC PRESSURE 29.4 PERCENT 02 16 

PERCENT CO 0 

■ FOR CIRCULAR STACK FOR RECTANGULAR STACK 

■ STACK DIAMETER (inch): 63 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) : 0 

~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754 

FLOWS 

, SAMPLED VOLUME (STD. CU .FT.): 33.7265 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2692 

FRACTIONAL MOISTURE CONTENT (Q/): 0.1124 

DRY BASE: 79.0000 

-- 1 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.4400 

~ MOLECULAR WT. OF STACK GAS (WET BASE): 28.1546 

STACK PRESSURE (inch Hg): 29.2750 

STACK GAS VELOCITY (ft/sec.): 37.7117 

ACTUAL STACK GAS FLOW RATE (ACFM): 48981.9172 

~ STANDARD STACK GAS FLOW RATE (SCFH): 1328544.81 

PARTICULATE 

~ FRONT HALF 

~ PARTICULATE CONCENTRATION (GR./SCF): 0.0102 

PARTICULATE CONCENTRATION (LBS/SCF): 1.45E-06 

PARTICULATE EMISSION (LBS/HR): 1.9309 

~ BACK HALF 

PARTICUTATE CONCENTRATION (GR./SCF): 0.0044 

PARTICULATE CONCENTRATION (LBS/SCF): 6.22E-07 

~ PARTICULATE EMISSION (LBS/HR): 0.8269 

, ISOKINETIC RATIO (%): 103.3725 

~ 

~ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET ~ 

1 560 0.21 0.458258 0.83 85 85 

~ 2 560 0.24 0.489898 0.96 92 86 

3 563 0.25 0.5 1.00 97 87 

4 564 0.24 0.489898 0.96 98 88 

5 563 0.21 0.458258 0.83 99 89 

6 521 0.19 0.43589 0.75 98 90 

~ 7 548 0.20 0.447214 0.80 99 90 

8 558 0.25 0.5 1.00 100 91 

9 561 0.27 0.519615 1.10 102 92 

10 562 0.25 0.5 1.00 103 93 

~ 

11 561 0.22 0.469042 0.89 104 94 

12 532 0.17 0.412311 0.68 103 95 

554.41667 0.4734 0.9000 98.3333 90.0000 94.1667 

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EMISSION TEST SUMMARY 

■ PLANT : Daltile, Muskogee, OK 

■ __ DATE : 19-May-05 

PLACE : Scrubber Inlet 

RUN#: 2 

■ TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 

NOZZLE DIAMETER (INCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) 

METER COEFFICIENT (Y) : 0.993 PARTICULATE WEIGHT (Back half mg) 

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 

~ GAS METER VOL.(Cu.Ft.) : 35.84 PERCENT CO2 

BAROMETRIC PRESSURE 29.4 PERCENT 02 

PERCENT CO 

; 

' FOR CIRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 63 STACK LENGTH(inches) : 

STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inches) : 

NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) : 

~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754 

FLOWS 

~ SAMPLED VOLUME (STD. CU .FT.): 33.0688 

VOLUME OF WATER VAPOR (STD. CU .FT.): 4.0857 

FRACTIONAL MOISTURE CONTENT (%): 0.1100 

DRY BASE: 79.0000 

MOLECULAR WT. OF STACK GAS (DRY BASE): 29.4400 

~ MOLECULAR WT. OF STACK GAS (WET BASE): 28.1820 

STACK PRESSURE (inch Hg): 29.2750 

STACK GAS VELOCITY (ft/sec.): 36.8605 

~ ACTUAL STACK GAS FLOW RATE (ACFM): 47876.2934 

STANDARD STACK GAS FLOW RATE (SCFH): 1299394.21 

PARTICULATE 

FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0110 

PARTICULATE CONCENTRATION (LBS/SCF): 1.57E-06 

PARTICULATE EMISSION (LBS/HR): 2.0404 

..~ 

~ BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0064 

PARTICULATE CONCENTRATION (LBS/SCF): 9.15E-07 

PARTICULATE EMISSION (LBS/HR): 1.1887 

' ISOKINETIC RATIO (%): 103.6303 

~$ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

1 561 0.20 0.447214 0.81 94 93 

2 563 0.24 0.489898 0.97 99 94 

~ 3 562 0.21 0.458258 1.05 102 94 

4 558 0.24 0.489898 0.97 103 94 

~ 5 559 0.22 0.469042 0.89 103 95 

,1 6 534 0.15 0.387298 0.60 103 95 

7 554 0.22 0.469042 0.89 105 96 

2 8 562 0.23 0.479583 0.93 105 96 

9 565 0.25 0.5 1.00 106 96 

10 563 0.24 0.489898 0.97 106 97 

,e 

11 562 0.22 0.469042 0.88 107 98 

12 535 0.16 0.4 0.64 106 98 

556.5 0.4624 0.8833 103.2500 95.5000 99.3750 

86.8 

23.55 

13.72 

-1.7 

5 

16 

0 

C 

~ ~ 
EMISSION TEST SUMMARY 

~ PLANT : Daltile, Muskogee, OK 

DATE : 19-May-05 

PLACE : Scrubber Inlet 

RUN#: 3 

~ TEST DURATION (MINUTES) : 60 LIQUtD COLLECTED (mis) : 81.7 

~ NOZZLE DIAMETER (INCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) : 26.55 

' METER COEFFlCIENT (Y) : 0.993 PARTICULATE WElGHT (Back half mg) : 2.66 

~ PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : -1.8 

GAS METER VOL.(Cu.Ft.) : 36.627 PERCENT CO2 4 

BAROMETRIC PRESSURE 29.4 PERCENT 02 17 

PERCENT CO 0 

! FOR ClRCULAR STACK FOR RECTANGULAR STACK 

STACK DIAMETER (inch): 63 STACK LENGTH(inchs) : 

STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inchs) : 

NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) : 0 

~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754 

FLOWS 

~ SAMPLED VOLUME (STD. CU .FT.): 33.5974 

VOLUME OF WATER VAPOR (STD. CU .FT.): 3.8456 

FRACTIONAL MOISTURE CONTENT (%}: 0.1027 

DRY BASE: 79.0000 

~ MOLECULAR WT. OF STACK GAS (DRY BASE): 29.3200 

MOLECULAR WT. OF STACK GAS (WET BASE): 28.1574 

STACK PRESSURE (inch Hg): 29.2676 

STACK GAS VELOCITY (ft/sec.): 37.4122 

~ ACTUAL STACK GAS FLOW RATE (ACFM): 48592.8813 

STANDARD STACK GAS FLOW RATE (SCFH): 1326328.97 

PARTICULATE 

~ FRONT HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0122 

PARTICULATE CONCENTRATION (LBS/SCF): 1.74E-06 

PARTICULATE EMISSION (LBS/HR): 2.3111 

! BACK HALF 

PARTICULATE CONCENTRATION (GR./SCF): 0.0012 

PARTICULATE CONCENTRATION (LBS/SCF): 1.75E•07 

PARTICULATE EMISSION (LBS/HR): 0.2315 

~ ISOKINETIC RATIO (%): 103.1485 

~ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. 

deg F INLET OUTLET 

~ 

1 556 0.20 0.447214 0.84 100 99 

2 567 0.24 0.489898 1.00 104 99 

3 568 0.25 0.5 1.00 105 100 

4 561 0.24 0.489898 1.00 105 98 

5 561 0.22 0.469042 0.92 105 98 

~ 6 536 0.17 0.412311 0.71 106 98 

7 544 0.22 0.469042 0.92 102 99 

8 565 0.23 0.479583 0.96 107 99 

9 567 0.27 0.519615 1.10 108 100 

~ 10 562 0.24 0.489898 1.00 110 101 

11 562 0.22 0.469042 0.91 110 101 

12 556 0.15 0.387298 0.62 110 101 

~ 558.75 0.4686 0.9150 106.0000 99.4167 102.7083 

~ 
A 

Appendix B 

I 
Date of Woighirg 

~ Timo 

8mxxVYoi0ht 

~ DateofYYeiQhinA 

~ ~ Tima 

~ 

GmxsYYoight 

~ DataofYvvighinQ 

~ Timo 

BeakorToreVYeight 

~ 

~ DatoufYVoi8h\ng 

Time 

BoakerTamYVoight 

~ 

~ AveegoGmxsvVvioht 

Leox B|unk Rosidue(0a) 

AvuraAe BoakorTareVVoiQht 110.6581 

~ 

~ WeightofParUcu|atnin Rinxe(m8) 

Ow 

10.15 

PARTCULATEANALY7ICAL DATARJRM 

Cvmpany: DaUi(e, Munkogun OK 

Qate: 5/19/05 

Lncabvn: 3cmbher|n|et 

nunz nuno Run3 

Donuity(pa) 

B|ankConcontmUnn(Ca) 

u RinooVoiumo(Vaw) 

RosiduoinRinso(Na)=Ca°Vaw°Pa ~0z 005i 0D004 

Nl 

N| 

Time 

Time 

Time 

Time 

~ ;~ 

~~ 
RLTERANAL|T|CALD/T7\ 

Coropany: Oa@le.Munkugae.OK 

Data: 5/19/05 

Locmtimn: Sorubber|n|*t 

RunI Run2 Run3 

Fi|tar|ONunnber 

DobaofVVeighing 

Tinna 

Gr000Fi|tevVVL 

Date ofVVoighhng 

//mo 

Gross FilteVVL 

Av*.GrooaFihorVVL 0.3804 0.3896 0 . 3886 

DeteofVVeighing 

Time 

FU(erToroVVL 

DoteofVVeighinQ 

Time 

Fi|terTaro VVL 

Ave.Fi|barToreVVL 0.3641 0.3734 0.3721 

VVt. ofPK8un Fi|her(gnanno) 0.0183 0.0161 0.0 184 

Toto|VVeightofParUcu\ata (nng) 16.3 161 18.4 

0 0 

11 

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~n 

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r, 

PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, DIOUPW igk 

Date: 5/19/05 

Location: Scrubber Inlet 

Run 1 Run 2 Run 3 

Density (Pa) 

Blank Concentration (Ca) 

Rinse Volume (Vaw) 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0008 0.0008 0.0008 

Date of Weighing 

Time `7 M. 

Gross Weight .5 --.*: 

Date of Weighing 

Time 1 ............... 3.- ZCY P. M: 

Gross Weight A 

Date of Weighing 

Time 

Beaker Tare Weight 

Date of Weighing 2.0 

Time -a M' 

Beaker Tare Weight 

Average Gross Weight 101.9667 100.0664 115.7113 

Less Blank Residue (Wa) 0.0008 0.0008 0.0008 

Average Beaker Tare Weight 101.9579 100.0531 115.7088 

Weight of Particulate in Rinse (mg) 7.99 12.54 1,69 

H20 BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 5 

Time 

Gross Weight 2: 

Date of Weighing 

Time ..... ..... 

Gross Weight 

Average Gross Weight 109.76515 

Date of Weighing 

Time 

Tare Weight 

Date of Weighing 

Time 

Tare Weiglit 

Average Tare Weight 109.7642 

Weight of Blank (Ma) 0.00095_ 

Ca= Ma/(Va*Pa) = g/g 3.8E-06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank 

weight be subtracted from the sample weight. 
11 

PARTICULATE ANALYTICAL DATA FORM 

Company: Daltile, Muskogee, OK 

Date: 5/19/05 

Location: Scrubber Inlet 

Run I Run 2 Run 3 

Density (Pa) ........ ....... ......... 

Blank Concentration (Ca) 

Rinse Volume (Vaw) ........ ......... 

Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0002 0.0002 0.0002 

Date of Weighing 0 

Time 

Gross Weight 6,14.4 ; 

Date of Weighing 

Time ... ...... ... 

Gross Weight 

Date of Weighing 

Time .............. ... AM: .... 

Beaker Tare Weight 

Date of Weighing 

Time . ;40 p 

..... 

Beaker Tare Weight 

Average Gross Weight 106.8071 111.6146 117.4807 

Less Blank Residue (Wa) 0.0002 0.0002 0.0002 

Average Beaker Tare Weight 106.8054 111.6132 117.4796 

Weight of Particulate in Rinse (mg) 1.53 1.18 0.97 

METHYLENE CHLORIDE BLANK ANALYTICAL DATA FORM 

Blank Volume (Va) 

Date of Weighing 

Time 

Gross Weight 

Date of Weighing 

Time AW: 

Gross Weight 

Average Gross Weight 99.59895 

Date of Weighing 

Time 

Tare Weight 

Date of Weighing 

Time 

Tare Weight 

Average Tare Weight 99.5985 

Weight of Blank (Ma) 0.00045 

Ca= Ma/(Va*Pa) = g/g 1.324E-06 

Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank 

weight be subtracted from the sample weight. 
Sheetl 

Summary of HF, HCI, and C12-Analysis 

Plant: Daltile, Muskogee, OK 

-Co-cation: Scrubber Inlet 

6a-te.- -5/19/05 

Run # Imp # Volume Dilution Fl-, ug/mi HF, mg Cl-, ug/mi HCI, mg 

1 200 20 19.97 84.1136.4 26.32 108.2278 

1 200 20 21.83 91.94796 26.46 108.8035 

Average 88.0308 108.5157 

2 1 200 20 19.49 82.09188 25.46 104.6915 

1 200 20 20.86 87.862321 23.39 96.17968 

Average 84.9771 100.4356 

3 1 200 20 19.16 80.70192 26.86, 110.4483 

3 1 200 20 20.81 87.65172 25.99 106.8709 

I Average 84.17682 108.6596 

Imp # Volume Dilution Fl-, ug/mi HF, mg CI-, ug/mi HCI, mg 

2 150 1 20.08 3.171636 27.33 4.214286 

-2 150 1 19.61 3.0974 28.68 4.422456 

Average 3.134518 4.318371 

2 2 150 1 20.84 3.291678 34.69 5.349198 

21 2 150 1 20.81 3.28694 33.05 5.09631 

Average 3.289309 5.222754 

3 - 2 150 1 19.13 3.021584 34.02 5.245884 

2 150 1 18.77 2.964722 33.06 5.097852 

Average 2.993153 5.171868 

Total Run 1 91.16532 112.8341 

Run 2 88.26641 105.6584 

Run 3 87.16997 

_ 

113.8315 

-Run # Imp # Volume Dilution Cl-, ug/mi C12, mg 

1 3 & 4 300 1 37.91 11.373 

1 - 3 & 4 300 1 39.57 11.871 

11.622 

2 3 & 4 300 1 36.68 11.004 

2 3&4 300 1 36.89 11.067 

11.0355 

300 

300 

1 

1 

36.22 

35.73. 10.866 

10.719 

10.7925 

L~, E 

I 

-7 

r- 0 

Page 1 0 
Conditions : 5 ug/ml Fl— in H20 

: 5 ug/ml - Cl— in H20 

Date : 05/21/2005 

Time z 08:52:21 

—102.4OOmV 

Component Reten 

(unknown) 0. 

- Fl- 0. 

ci- 1. 

LIU11 

1024.00OmV 

Area External 

172.10 N/A 

420.60 4.75 

276.90 4.24 

Component Number Retention Area External Units 

Fl— 1 0.950 420.60 4.75 ug/ml 

cl— 2 1.266 276.90 4.24 ug/ml 

2 697.50 8-99 

Igl ejo ExteSDOI 

51- 

1 
~ 

412.10 M 4.7 

279.00 M 4.9 

F1- 0. 

Ci- 1. 

Canditians ? § Ugiffil Ej= 

©ate 05/21/2005 

Time : 09-09=41 

—102 .400mV 1024.00OmU 

Component Retention Area Externi 

Component Number Retenti©n Area External Units 

Fl-- 1 0.950 412.10 M 4.77 ug/ml 

ca.— 2 1.250 279.00 P1 4.96 ug/ml . 

K 691_10 9_73 

0 

52 

7 
Conditions : 10 ug/ml Fl- in H20 

: 10 ug/ml C-1- in H20 

Date : 05/21/2005 

Time : 09:14:09 

-102.4OOmV 

Component Reten 

Fl- 0. 

cl- 1. 

1024.00OmV 

Area Externa 

906.73 10.6 

573.34 8.8 

Component Number Retention Area External Units 

Fl- 0.950 906,73 10.67 ug/ml 

ci- 2' 1.266 573.34 8.86 ug/ml 

VA 1480.08 19-53 

r /-. 

o-3 
0 v 

' 

~ 

@ 

~ 

Fl- O. 

Cl- \. 

-1O2'4O0mV 

Componon¢ Reton 

Conditions : 10 ug/ml Fl- in H20 

: lO uQ/ml Cl- in R20 

Qate : 05/21/2005 

Time : 09:16:48 

1024'ODOmV 

Area Exterm 

862.70M 1O.1 

S78.0H 8. ~ 

Cmmpomant Numbmr Retention Arma External Unita 

Fl- 1. 0.966 862.70 M 10.17 ug/ml 

Cl- 2 1.266 578'50 M 8'92 ug/ml 

2 1441-20 19-09 

~ 

~~~
Conditions 

Date 

Time 

_ 

Comyonont Redootio/L 

: 20 ug/ml Fl- in H20 

: 20 ug/ml Cl- in H20 

: 05/21/2005 

: 09:2l:24 

L02'40O0V l024'000mV 

Area Exherm 

Fl- O. 

C}- 1. 

1658.71 H 

1184.48 N 

0.~ 

~ 

~ 

~ 

~ 

~ 

~ 

Component 

FlClNumber Hetention 

l O'966 

2 1.266 

Arma ExterneI Unita 

1658.71 M 18.96 ug/ml 

1184.48 M 18.60 ug/ml 

2 

~r 

~~ 
~= U 

Conditinno 

Date 

Time 

_ 

Componont Rotnotioo 

: 20 ugyml Fl- im H30 

: 20 mg/ml CI- in H20 

: 05/21/2005 

~ 09-- 24c10 

LO2.40OmV 1O24.00OmV 

F1' O. 

C}- 1.2 ~ Am 1715.99 

1%D.60 

M.( 

0., 

Compmnent 

FlClNumber Retention 

1 0.950 

2 1.266 

1715.99 19'62ug/ml 

1227.60 / 19.21 ug/ml 

2 

c~n 

~~ri 
Conditions 

Date 

Time 

Component Retention 

= 40 ug/ml Fl— in H20 

= 40 ug/ml Cl— in H20 

: 05/21/2005 

: 09-28=24 

102 .4f7qmV 1024,OQOmV 

Area Ezterng 

F1- 0. 3236.27 M 39.3 

C1- 1. 2639:5b M 42.7 

11 

U 

Component Number Retention Area External Units 

Fl— 1 0.966 3238.27 M 39.32 ug/ml 

C1— 2 1.300 2639.56 N1 42.75 ug/m1 

VA 5877.83 82.07 

5 /~ 
1024.00OmV 

Conditions 

©ate 

Time 

Component Rete 

= 40 ug/ml Fl- in H20 

= 40 ug/ml Cl- in H20 

= 05/21/2005 

= 09=31-16 

102.400mV 

F1- 0 

C1- 1 

Area Ezterni 

3339.19 40. 1 

2529.69. 41.0 

l 

i 

-~ 

~ 4 

~ 

~ 

~ 

J 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

' 

, 

e 

~ 

r 

Component Number Retention Area External Units 

Fl- 1 0.983 3339.19 40.58 ug/ml 

Cl- 2 1.300 2529.69 41.01 ug/ml 

2 5868.88 81_59 

No 
AMOUNT INJECTEd 

AREA 0.000 

0.00 

3288.73 

40.000 

1 

2 

3 

i~ 

W 

5 

} 

Calibration file = Fl-_cal 

Avg slope of curve: 84.32 

Y-axis intercept= 0.00 

Coeff of 1 i n regr : 0.90 

No. Area Amount CF 

0= 0.000 0.000 0.000 

1= 416.350 5.000 83.270 

2 ~ 884.715 10.000 88.472 

3: 1687.350 20.000 84.367 

4= 3288.730 40.000 82.218 

59 
~ 

1 

Calibration file = Cl-.cal 

AMOUNT'INJECTED 

AREA O _ 000 40.000 

0.0 

2584.6 

Avg slope of curve; 61.78 

Y-axis intercept= 0.00 

Coeff of la.n regr: 0.90 

No. Area Amount 

O» 0.000 0.000 

1: 277.950 5.000 

2 = 575.920 10.000 

3= 1206.040 20.000 

4- 2584.625 40.000 

~ 

1 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

ma 

0.000 

55.590 

57.592 

60.302 

64.616 

1 

2 

3 

4 

5 

~ ~~ 
I 

~l 

~~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ /w 

~ 

Componmnt koto 

hmknmm\ 0 

'^ " 

C}' I 

Cnnditimnm : Daltilm° 8crubber Inlet 

: Rwn #1 Imp #1 

: VoIume 200 Dilution 1/28 

Date z 05/21/'20{)5 

Time 10:02:11 

-1O2,4O0mV 1024.0OOmV 

Cumponent 

FlClNumber Retention 

1 0.983 

2 1.316 

Arou [xbmx 

44.20 N/i 

1684,90H 19'' 

1641.36 H 26' ~ 

Area ExtermaI Units 

1684.90 M 19.97 ug/ml 

1641.36 M 26'32 ug/ml 

VA 

~~ 

~~ 
CnnditIono : Daltile, Scrubber Inlet 

: Run #1 Imp #1 

: Volume 200 Dilution 1/20 

Date : 05^'21^'2005 

Time : 10:06:35 

~ 

U 

D U 

-1O2.4OOmV 

Component Retei . 

(un known) O 

R- O 

C1- 1 

/noa [xhnn 

23.60 N/ 

1834'20 H 21. 

1651.46 H 26. 

1024.000mV 

Compmnent Number Rmtentimn Area Extmrnal Units 

Fl- 1 0.966 1834'20 M 21.83 ug/ml 

Cl- 2 1.300 1651.46 M 26.46 ug/ml 

2 3405'66 48'30 

~~ 

mm 
Conditions : Daltile, Scrubber In1et 

= Run #2 Imp #1 

= Voiume 200 Dilution 1/20 

Date = 05/21/2005 

Time = 10:11-38 

-102.400mV 

Companent Rete " 

(unknown). 0 

F1- 0 

C1- 1 

Area Exterr 

57.25 Mi 

1646.75 M 19. 

1582.68 M 25. 

1024.00OmV 

C

f ..,.

C 

Component Number Retention Area External. Units 

Fi— 1 0.966 1646_75 M 19.49 ug/ml 

Cl— 2 1.300 1582.68 M 25.46 ug/ml 

~ 3229.43 44.96 

69 
AToa Exbnr 

34.90 N/ 

1756.55H 20. 

1440.00 H 23. 

r*

~ 

~~v 

~ 

| ^ Cmnditions : Daltile, Scrubber Inlet 

: Run #2 Imp #1 

: Vmlume 200 DiIution 1/20 

Date : 05/21/2005 

Time : 10:16:20 

~ 

~ 

~ 

~ 

-102.40OmV 

rxmovnmm, _-,-_' -- 0eteotio" 

(uokoown) O 

Fl- O 

C}- 1 

1024.00OmV 

Area External Unito 

1756.5S M 20'86 ug/ml 

1440.00 M 23.39 ug/ml 

Compmmant Number Retention 

Fl- 1 0'96& 

Cl- 2 l'300 

~1 
: Daltile, Scrubber Inlet 

z Run #3 Imp #1 

: Volume 200 Dilution 1/20 

: 05/21/2005 

= 10:21-31 

t02 .400mV 1024.00OmV 

Conditions 

Date 

Time 

Component Retention i._.. 

(unknown) 0.700 

Fl- 0. 1 - 

Cl- 1.316 

Area Externi 

23.20 N/i 

1620.25 M 19.: 

1679.05 M 26.1 

Cornponent Number Retention Area External Units 

Fl-- 1 0.983 1620.25 M 19.16 ug/ml 

C1— 2 1.316 1679.05 M 26.86 ug/mJ. 

2 3299_30 46.03 

rt ~ f .i 
'^ 

' 

~ Conditlnna 

Date 

Time 

- 

~ Daltilm, Sorubber ZnIet 

~ Run #3 Imp #1 

~ VoIume 200 Dilution 1/20 

: 05/21/2005 

z 1D:26:23 

L02'4OOmV lO24'OOOmV 

Aroa [xtern. 

~ 

~ 

Fl- 0. mm 1752.10 N 20.1 

1619.01 H 25,' 

Cumponent 

FlclK 

Number Retentlon 

1 0.966 

2 1.316 

Area Extermal Hnito 

1752.10 M 20 .81 ug/ml 

1619'0 1 M 25.99 ug/ml 

3371'11 48'80 

n ~ 

~ ~ 
Conditions : H20 Blank 

Date : 05/21/2005 

I Time : 10:32:09 

I 

—102.4OOmV 

Component Retention 

(unknown) 0.533~ . ........ 

1024.00OmV 

Area 

45.35 

Exterr 

NY 

RE 

I 

Component Number Retention Area External Units 

m 

71 3 
C«/nditimno : 5 ug/ml.Fl- in H2SO4 

: 5 uQ/mI Cl- in H2SO4 

Datm z 05/21/2005 

Time,: 10:35:27 

-1O2'4O0mV ' 1024.00OmV ^ 

- 

- 

^ 

/ 

Number Retention Area Extmrn'al Units 

1 0'950 350.80 4.21 ug/ml 

2 1.233 230'20 M 4.14 ug/ml 

Fl- O. 350.80 4.; 

%0.2OH 4.: 

Compnnent 

FlClVA 

r/ ~ 

~~ 
Cnnditimma : 5 ug/ml FI- in H2SO4 

: 5 ugyml Cl- in H2SO4 

Date : 05/21/2005 

Time : 10r37c12 

-1O2,40OmV 

Component ketontio 

l024'OOOmV 

Area Extorn 

B- O.- 

Cl- 1.: !1W 

%0.6O 4. 

23L7OM 4. 

Component Number.Retmntion Area Extermal Units 

Fl- l 0.966 370.60 4.45 ug/ml 

Cl- 2 1.216 231.70 M 4.17 ug/ml 

2 

n ~ 
817.75 9. 

552.40 M 9. 

Fl- 0 

C1- 1 

Conditions = 10 uglml Fl- in H25O4 

= 10 uglml Cl- in N2SO4 

( Date : 05121l2005 

Time = 10-42=47 

-102 .400mtt 1024 .OQQmV 

Component Retention Area Extern 

Compcsnent 

FlCl2 

Number Retention 

1 0.950 

2 1.233 

Area External Units 

817.75 9.36 uglml 

552.40 M 9.66 ug/ml 

1370.15 19_02 

t~ ~ 
—1O2'4OOmV 

Com0000nt _ Rotondoo 

(unkmmn) O. 

Fl_ O. 

lO24'OOOmV 

Area Extern 

27.80 N/ 

827.95 10. 

510.45 H 9. 

Conditlmno : 1{} ug/ml Fl— in H2SO4 

c 10 ug/ml Cl— in H2SO4 

Datm : 05/21/2005 

Time : 10:49:44 

` 

Compmnent Number Retention Area Externe*l Units 

Fl— 1 0.950 827.95 10'05 ug/ml 

Cl- 2 1.233 510.45 M 9'38 ug/ml 

2 

^ r/ ~ 

~~ 
Nl m~ 

Conditimne 

~~~~ 

Timm 

_ ~ ~ ~ ~~~ ~en 

(unkmwn) O. 

Fl- 0. 

Cl- 1. 

: 15 ugJml Fl- in H2SO4 

: 15 ug/ml tl- in H2SO4 

: 05/21/2005 

: 1O:55:l7 

L02'4OOmV 1O24.00OmV 

Arou Exbnn 

30.70 N/ 

18N.00H 14.' 

853.95 H 14. 

Component Number Retention Are*a ExternaI Unito 

Fl- 1 0.950 1204.00 M 14.41 uQ/ml 

Cl- 2 1.233 853.95 M 14.78 ug/ml 

~ 

~~ 
Cmnditiono 

Date 

Time 

Cumponont kotontion 

(unknown) 0.08 

Fl- O. 

Cl- 1.21 

: 15 ug/ml Fl— in H2SO4 

: 15 ug/ml Cl— in H2SO4 

: 05/21y2005 

: lU:57:O2 

1O2.40OmV 1O24.O00mV 

. Area Exbnp 

256.27 N/ 

1216.50 14. 

Compmnent Number Retentlon Area External Unite 

Fl— 1 0.950 1216,50 14.55 ug/ml 

Cl- 2 1.216 877,95 15.14 ug/ml 

2 

~~ 
Conditinnm : 20 eg/ml Fl- in H25O4 

: 20 ugyml Cl- in H2SO4 

 Dete : 05/21/2005 

Time : .11 ~ O2:23 

-102'.40DmV 

Comoonen t -- 

Fl- O 

Cl- 1 

| 

" 

~ 

N| 

~ ~ 

~ 

1O24'OOOmV 

1665^75 20. 

1110.60 H 0' 

Component Number Retention Aree Enternal Units 

Fl- 1 O,966 1665.75 20'48 ug/ml 

Cl- 2 1'250 1110.60 M 18.56 ug/ml 

2 2776-35 89.04 

~~ 

~p 
lO24.00OmV 

Area Exbxm 

79.20 N/i 

78.72 Nli 

93.61 Nh 

1661.50 H 19.1 

1529.40 H 28'( 

/ 

` 

U 

r

" 

` 

8 » 

U » 

N 

n 

N N 

~ 

' 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

~ 

' ~ 

Conditioma : Dalt1Ie, 8orubber InIet 

: Run #1 Zmp #2 

: Volume 150 DiIution 1/1 

Date : 05/21/2005 

7[ime z 11:39:25 

-102'4OOmV 

Component koton 

un- k nown -- `' 

\«nxmmo> o. 

(onknown) O. 

Fl- O, 

Cl- 1. 

Compmnent Number RwtentInn 

Fl- , 1 0'966 

Cl- 2 1'216 

K 

Lm 

` 

~~ 

Area Externol Unito 

1661.50 M 19.61 ug/ml 

1529'40 M 28.68 ug/ml 
: Daltile, Sorubber Znlet 

: Run #2 Zmp #2 

: Volume 150 Dilution 1/1 

: 05/21/2005 

: 1l:44:39 

iO2.40OmV 1024.0OOmV 

Conditionm 

Date 

Time 

Comp000nt 8otontion 

(uokmmo) O 

Fl- O. 1[ 

Area Extern 

39.00 N/ 

170.81 H 20. 

' 

Component Number Hetmn±inn Arma External Vnito 

Fl- l 0.966 1781.81 M 20.84 ug/ml 

Cl- 2 1'233 1826'50 M 34.68 ug/ml 

 2 . 3802'31 55-52 

~ 

~

'' /- 
Conditinna : DaltiIe, Scrubbmr Inlet 

: Run #2 Imp #2 

: Volumw 150 Dilution 1/~1 

Date c05/21/2005 

Time : 11:46:28 

 -102.400mV 

Comp000nt Roton 1oo 

oVkDVwn O. 

(unkmmn} O. 

/unkumm\ O. 

Fl- O, 

Cl- 1, 

lO24'0OOmV 

Aron Exherm 

72.30 NN 

109.20 NA 

01,0 NII 

1779.06 20.( 

1741.55 33.( 

Component Numbar Retention Area ExternaI Unito 

Fl- 1 0.966 1779,06 ' 20'81 ug/ml 

Cl- 2 1.216 1741.55 33'05 ug/ml 

2 

Q ~ 

~u 
Fl- 0. 

C1- 1. 

.,..... 

( ~ ~ 1. .,.. 

233 

2 .,... 

3 ......... 

4 . ..,. 

Conclitions 

Date 

Time 

Component Retention 

: Daltile, 5crubber Inlet 

: Run #3 Imp #2 

: 4+olume 154 Dilution 1/1 

: 05/21/2005 

: 11:52:03 

L02 .400mV 1024 .00OmtI 

Area Extern, 

1614.22 19.: 

1788.28 34.( 

,r 

Component Number Retenti.on Area External Units 

F1- 1 0.966 1614.22 19.13 uQ/ml 

C1-- 2 1.233 1788.28 34.02 ug/ml 

kA 3402.50 53 _ 14 

94 
AToa Exbnm 

79.80 NN 

80.70 NN 

1579.43 M 10." 

1741.77 M 33.( 

Conditions ; Daltilm, Scrubber Inlet 

: Run #3 Zmp #3 

~ Volume 150 Dilution 1//1 

Date 05/21/2005 

Time ~ ll - 53 ~ 52 

-102.40OmV ~ 

CompoRent Reten 

(uokoowo) 0. 

(unknown) O. 

8- 0. 

C\- 1. 

1O24'0DOmV 

N Component Number Rwtention Arma ExternaI Units 

Fl- I 0.950 1579.43 M 18.77 ug/ml 

Cl- 2 1.216 1741,77 M 33.06 ug/ml 

2 

~ 

~~ 
Canditians = H2SO4 B3ank 

Date = 05121/2005 

Time = 11=59=39 

-102.400mV 

Component Retention 

(unknown) 0 

(unknown) 0 

1024.QOOmV 

Area Extern 

26.35 N/ 

34.80 N/ 

Compnnent Number Retention Area External Units 

J s_•H a •Lo 

9 6 
1024.00OmV 

Area Extern 

Conditions : 5 ug/ml C1— in NaOH 

Date : 05/21/2005 

Time : 12=10=18 

—102 . 4OOmV 

Component Rete 

(unknown) 0 

C1 - 1 

(unknown) i 

778.30 N1 

90.10 M ' 5. , 

170.27 M N/; 

Component Number Retention Area External Units 

C1— 2 1.400 90 „10 h1 5 .00 ug/ml 

1 90_10 5.00 

`7 ~ ( 
Condltions : 5 ug/ml Cl— in NaOH 

Qate z 05/21/2005 

Time : 12:16:18 

—1O2.400mV 

Component 8etoD 

(unknown) O. 

C\- 1' 

1024.O00mV 

kroa Exbmm 

NW.80N NA 

94.00 N S.< 

u 

.......... . ... ................ ................ .............. ........... ........ ..... .... 

. ......... . ......... 

Compmnent Number Retentlon Area External Qnits 

2 1.416. 94.00 M 5.04 ug/0l 

1 94'00 5'04 

{~ 

~ 

au 
—102.400mV 1D24.O0OmV 

Compone nt Reton ion 

xnknown O. 

(unkxowo) O. 

C\- 1. 

Area Extern 

26.0 N/ 

670.90 NK 

200.76 10.1 

Conditi«xno : 10 uQ/mI Cl— in NaOH 

Date : 05/21/2085 

Time : 12:19c55 

Component Mumbvar Rmtention Area Extmrnafl Units 

Cl— 2 1'383 200.75 10.00 ug/ml 

M 

~~ 

~0 
Conditions : 10 ug/ml C1— in NaOH 

Date = 05/21/2005 

Time = 12:22=28 

—102.4OOmV 

Component Retention 

1.024 .00OmV 

Area Eztern 

(unknown) 0.8001 ~ 1. .,... ~ 

Cl- 1.400 

~ 2 _ .... ; 

3 .... : 

710.45 N/ 

203.70 M 10. 

Component Number Retention Area External Units 

C1— 2 1.400 203.70 M 10.02 ug/ml 

 1 203_70 10.02 
Conditions 15ug/ml Cl- in NaDH 

0ate : 05/21/2005 

Timm : 12:25:42 

-102.4DOmV 

----' Rete ntion 

1O24.O0OmV 

Area Exbern 

895.80 N/ 

301.80 14. 

(uokmmo) O. 

Cl- l.' 

Cnmpnnent Number Retentinn Area External Unito 

cl- 2 1.450 301.80 14.51 ug/ml 

1 301'80 14'51 

~U~ 
916.80 N/; 

299.50 14.- 

(unknown)_ 0 

C1- 1 

Conditions : 15 uglml Cl— in Na©H 

Date : 05/21l2005 

Ti.me = 12=27=56 

--102.4(JOmV 

Component Retention 

1024 .00OmV 

Area Extern 

Component Number Retention Area External Units 

Cl- 2 1.450 299.50 14.41 uglml 

1 299.50 14.41 

~.~.1e) 
(unkmmn) . O. 

Fl- 1. 

Cl- 1. 

555.70 N/ 

66.65 H O. 

440.80 H 22. 

Conditic/ne : 20 u8/ml Cl- im NaOH 

Date : 05/21/2005 

Time : 12:31:08 

-1O2.4O0mV 1O24.00OmV 

Area [xtern 

ComPoneant Number Retmntion Area Extermal Qnits 

Fl- 1 1'116 66.65 M 0.92 ug/ml 

Cl- 2 1'416 440.80 M 22.12 ug/ml 

F4 

~ ~~l 

~ Ua 
—102 . 4OOmV 1024.00OmV 

Comaonent Retention 

(unknown) 0. 

F1- 1. 

C1- 1. 

Area Extern 

531.05 N/i 

59.20 M 0.1 

439.90 M 22.( 

Conditions z 20 uglml C1— in NaOH 

Date = 05/21/2005 

Time = 12.33=39 

Component Number Retention Area External Units 

F1— 1 1.133 59.20 M 0.82 ug1m1 

C1— 2 1.416 439.90 M 22.08 ug/m.l 

2 499_10 22_90 

n 

r. 

i~ i 

~ 

i 
AMOUNT INJECTED 

AREfi 0.000 

0.00 

440.35+ 

20.000 

1 

2 

3 

4 

G 

s 

Calibratian.file = Cl—_cal 

Avg slnpe of curve= 22.02 

Y--axa,s intercept- 0.00 

f Cneff cf l.in regr = 0.79 

No. 'Rrea RmOunt CF 

~ 0. 0.000 0.400 0.000 

1- 92.050 5.000. 18.410 

2: 202.275 10.000 20.227 

3: 300.650 15.000 20.043 

' 4: 440.350 20.000 22.018 

A_ U a 
Conditionm : Da ItiIm 5crubberZnlmt 

~ Run #1 Impo 3 & 4 

: VoIume 300 Dilution 1//1 

Date 05/21,/2005 

Time : 13:08:04 

-1O2'4OOmV 1024.(}O0mV 

COmDOnent Retention &re Extmm 

(unkoonn) O 

O- 1 

746.80N Nlt 

Component 

Cl- 

- - ' 

Number Retention Aree Extmrmal Un1ts 

2 1.433 940.80 M' 37.91 ug/ml - 

1 

~~~~ 
Extern'; 

N! 

N/ 

39 . : 

Area 

37.25 

744.68 M 

987.15 M 

--102 .400mV 

Component Reten ' 

(unknown) 0. 

(unknown) 0. 

Cl- 1.1 

1024_QOOmV 

Conditions : Daltile Scrubber Znlet 

w Run #1 Imps 3& 4 

= Volume 300 Dilution 1/1 

Date = 05/21/2005 

Time = 13=13=10 

Component Number Retention Area External Units 

Cl- 2 1.433 987.15 M 39.57 ug/ml 

1 . 987_15 39.57 

1 ~ 
—1Q2.4QbmV 1Q24.aOQmV 

Component Retention 

(unknown) 

0.016{.... ................... .I.....,..,.. ......... ....,.. 

I ~ (unknown) 0.800 ................ ~,~ 

(unknown) 1 .300 .1:~ 

Cl- 1.416 : ;a ir....... .......... 

Area Extern 

29.10 M/ 

790.63 M M/ 

49.61 M N/, 

906.50 M 36.1 

Conditions : [3altile Serubber Inlet 

- Run #2 Imps 3 & 4 

= Volume 300 Dilution 1/1 

date = 05/21/2005 

Time : 13:18=18 

11 

Component Number Retention Area . External Units 

Cl- 2 1.416 906.50 h4 36.68 ug/ml 

1 ?1MINWO 36_68 

< •i 

~ 6 
Conditions : DaItlle SoTubber Inlet 

: Run #2 Imps 3 & 4 

: VoIume 300 Dilution 1/~1 

Datm : 05~/21/2005 

Time : 13:25:35 

—1D2.40OmV 

Component Reten 

(unkoowo) O. 

(unknowo) 1. 

Cl- 1. 

' 

1024'(}O0mV 

Arou Fxhmr 

783.83H N/ 

66.03H N/ 

912.25 H 36. 

Component Number Retmntion Arma External Wnits 

Cl— 2 1.416 912.25 M 36.89 ug/ml 

1 912-25 36-89 

~~~~ 
-102'4OOmV 1024'OOOmV 

component ' t . 

(unknown) O 

(unkmown) 1 

Cl- 1 

753.78H kN 

110.WM NN 

898.50 N 36.; 

Conditions : 0altile SoTubbmr Znlet 

: Run #3 Impo 3 & 4 

: Voluma 300Dilution 1y1 

Date z 05/21/2005 

Time - 13:30-:50 

Compmnent Number Retentlon Are«u External Unito 

Cl- 2 1.433 893.50 M 36.22 ug/ml 

1 
Conditions = Daltile Scrubber Inlet 

= Run #3 Imps 3 & 4 

= 'Jolume 340 Dilution 1/1 

Date = 05/21/2005 

Time = 13:36=02 

-102 .404mV 

Component Rete 

(unknown) 0 

(unknown) 1 

Cl- 1 

Area Extern 

752.02 M NI 

92.64 M NI 

879.80 M 35. 

1024.00OmV 

Component Number Retention Area External Units 

Cl-- 2 1.433 879.80 M 35.73 ug/m]. 

1 879.80 35:73 

~M t 

L I 
Conditions z NaOH Blank 

Date : 05/21/2005 

Time : 13:41:31 

-102.400mV 1024.00OmV 

Component Reten 

(unknown) 0. 

Component Number Retention Area External Units 

541 rolwolti 

Area Extern 

1004.65 NI; 

.&-f 

L-18 
Appendix D 

~ 
'7 

Fi rE LD D ATA 1 ~ A, 

PLANTREPFTiubj~T: - 

LOCATION 6 (SOURCE IMPINGERS 

OPERATOR: 

SANIPLE TR-AIN 

iiiitial Final 

METER BOX,,: 

BAROMETRIC PRESSURE: 43 t 

ANMI'ENT .a I 01D 44 

ASSUNIED MOIS 

PROBE LENGTH: 97 

NOZZLE DIAMETEI. qO;7 "'A STACK DIAMETER: 

METER H: l, 61bil, CO2 02 

C FACTORMETER CO FICIENT: 

FILTFR TARF:.,3gqoi57 07 

PRE-TEST LEAK CHEi CK POST-TEST LEA-K CHECK 

Meter:&?. C9 ,5 cu.ft. @ /-(In.. HG Meter: 0 cuft CCD, in. HG 

Pitot: iii; H20 Pitots., c in. H20 

;4- u ijL n e- u I.V. 'fr, Pli 

E2L 

21Y q Z,- 6 'IA57 

Z,5 

c ' t D 6' 

-z' I 

2,61 

[~2.- 1 1, o 0,3 7 T A 

1115:7) zz- 1 `31 lqw- -1 lloq IF q Z5-6 

11 //, ~ ` 103 J 5- 121~ 

I V"D T-T 

z 

7 - 

u 

p 
~. 

~ 

~ p ~ o ~,~S~~Uyn e1 F:CELD DATI~ 

PLANT: k r J 

DATE: S^> // 9 ~as 

REPETITION: ~-- 

LOCATIQN (SOTJRCE -):SGrJ~I~ ~~y` ~ ~ IMPMGERS 

OPERATOR: 

SAMPLE TRA.IN n: ~ 

Initial Final 

1 1 /a~ r~-1r l,~cc i5`' 

METER BOX ~: l!7 

%BA.ROMETRIC PRESSURE: ~ I 

~2 ~ cx~ ~„I~ F`f ~Jl` 

r3 Le~~~r/; 

A"Ia,fBIENT TEMPERATURE: 

ASSUIviED MOISTLlRE: ? #5 2po ~ 

PROBE LENGTH: $ ~ 

NOZZLE DL4 YIETER: - 

r6 

STACK DLA.II2ETER: 

METER H: /. S~o~ CO2 02 

C FACTOR: ~ V~ : c~ 

METER CO-EF'F{'YCIEN.T: j 

FILTER TARE: , ~7- Y;` ~'~ 

PRE-TEST LEAK CHECK 

Meter: 6.oj7., 

 cu.ft. ,~. ~j l~L n. HG 

POST-TEST LEAK Clfl~✓ CK 

Meier: °.O(U cu.ft. @$" in. HG 

Pitots: `i/. (a7 ~/.Sf in_ H2(7 p7 in Tn(-1- 

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PROBE LENGTH: rr 

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FIELD DATA 

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Temperature Meter Calibrations 

Meter Box #: 10 

Date: 02/21/05 

Calibrated B : RT 

Emtech Thermo 

De rees F Checker Probe Stack Oven Exit Auxilla ry 

Point 1 32 31 31 31 30 31 

Point 2 212 210 210 210 210 210 

Point 3 752 750 750 750 750 750 

Emtech Thermo 

De rees R Checker Probe Stack Oven Exit Auxilla 

Point 1 492 491 491 491 490 491 

Point 2 672 670 670 670 670 670 

Point 3 1212 1210 1210 1210 1210 1210 

Percent Difference 

Probe Stack Oven Exit Auxiliary 

Point 1 0.203252 0.203252 0.203252 0.406504 0.203252 

Point 2 0.297619 0.297619 0.297619 0.297619 0.297619 

Point 3 0.165017 0.165017 0.165017 0.165017 0.165017 

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Meter Box #: 11 

Date: 03/03/05 

Calibrated By: RT 

Emtech Thermo 

Degrees F Checker Probe Stack Oven Exit Auxillary 

Point 1 32 29 30 29 30 30 

Point 2 212 210 210 210 210 211 

Point 3 752 750 751 750 751 751 

Emtech Thermo 

Degrees R Checker Probe Stack Oven Exit Auxiliary 

Point 1 492 489 490 489 490 490 

Point 2 672 670 670 670 670 671 

Point 3 1212 1210 1211 1210 1211 1211 

Percent Difference 

Probe Stack Oven Exit Auxiliary 

Point 1 0.609756 0.406504 0.609756 0.406504 0.406504 

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Point 3 0.165017 0.082508 0.165017 0.082508 0.082508 

$ ~ ~ 
Appendix F 

Q 
Reference Standard 

Description Expiration date Cylinder Number 

GMIS 1/19/2006 CC177157 

* GMIS CC177157 Tracebility 

Description Expiration date Cylinder Number 

NTRM 6/1/2006 SG9199568 

Instrumentation 

Description Modet # Date Last Clibrated 

Horiba Process Analyzer VIA-510-S02 6/15/2004 

Anayisis Results: Z= zero gas, S= standard gas, X= sampfe gas 

Specealty Gas Products 

3106 Pasadena Freeway 

Pasadena,Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 7/13/2004 

Customer: Matheson-Trigas 

Description: S02 in N2 - EPA Protocol 

Cy(inder No: CC88735 

Requested 

Component . Concentration 

Sulfur Dioxide 100ppm 

Nitrogen, Balance 

Project No: 9970 

Exp. Date: 7/13/2006 

Cylinder Pressure: 1900psig 

Certified 

Concentration 

101 ppm 

Accuracy 

1% 

Concentration 

793.8ppm S02 

Concentration 

1997ppm S02 

Principle 

NDIR 

First Triad - S02 

Z1= -0.90 S1= 791.9 

S2= 794.0 Z2= -0.70 

Z3= -0.90 X3= 99.2 

Curve: Y=1.971+0.999869*X 

Average = 100.6ppm 

Second Triad - S02 

X1= 98.7 Z1= -0.90 S1= 794 

X2= 99.0 S2= 793.2 Z2= -0.60 

S3= 792.6 Z3= -0.60 X3= 99.30 

Average =100.9ppm 

X1= 99.0 

X2= 99.2 

S3= 793.4 

' Analyst~'_ 

Lin9 Wen--' ~~ - --~ 

THIS STAN'D"AKU IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

' DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

■ 

-4 0 

■ 
I 

I 

Specialty Gas Products 

3106 Pasadena Freeway 

Pasadena,Texas 77503 

 (713) 534-8217 Fax(713) 534-8133 

Date: 7/13/2004 

Customer: Matheson-Trigas Project No: 9969 

Description: S02 in N2 - EPA Protocol Exp. Date: 7/13/2006 

Cylinder No: CC177434 Cylinder Pressure: 1900psig 

Requested Certified 

Component Concentration Concentration Accuracy 

Sulfur Dioxide 50ppm 50.1 ppm 1% 

Nitrogen, Balance 

Reference Standard 

Description Expiration date Cylinder Number Concentration 

NTRM 6/1/2006 Sg9135833 99.8ppm S02 

Instrumentation 

Description Model # Date Last Clibrated Principle 

Horiba Process Analyzer VIA-510-S02 7/7/2004 NDIR 

Anaytsis Results: Z= zero gas, S= standard gas, X= sample gas 

First Triad - S02 Second Triad - S02 

Z1= -1.30 S1= 999.90 X1= 502.60 Z1= -0.80 S1= 997.90 X1= 500.30 

S2= 999.90 Z2= -0.70 X2= 503.60 S2= 998.70 Z2= -0.10 X2= 500.30 

Z3= 0.00 X3= 503.60 S3= 999.90 Z3= -0.20 X3= 501.60 S3= 999.30 

Curve: Y=0.0064+0.09986*X 

Average = 50.15ppm Average =49.98ppm 

Analyst: G 

LincyWeri 

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSlG 

v 
~ Specialty Gas Prodacts 

3106 Pasadena Freeway 

I Pasadena,Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 11 /21 /2003 

( Customer: Trigas Project No: 5233-002 

Description: CO in N2 - EPA Protocol Exp. Date: 11/21/2006 

~ = Cylinder No: CC176566 Cylinder Pressure: 1900psig 

Requested Certified 

~ Component Concentration Concentration 

Carbon Monoxide 50ppm 47:3ppm 

Nitrogen, Balance 

! 

Reference Standard 

Description Expiration date Cylinder Number 

NTRM 7/1 /2006 SG9133548 

s lnstrumentation ~ 

' Description Model # Date Last Clibrated 

Horiba Process Analyzer VIA-510-CO 11 /4/03 

' Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas 

First Triad - CO Second Triad - CO 

Z1= 0.00 S1= 97.30 X1= 47.10 Z1= 0.00 S1= 97.24 

~ S2= 97.28 Z2= 0.00 X2= 47.08 S2= 97.20 Z2= 0.00 

Z3= 0.02 X3= 47.12 S3= 97.30 Z3= 0.00 X3= 47.18 

~ 

Average = 47.19ppm Average = 47.38ppm 

Accuracy 

1% 

Concentration 

97.3ppm CO 

.- 

501: 

X1= 47.26 

X2= 47.32 

S3= 97.24 

Analyst: - > 

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

,iDO NOT USE THIS STANDARD iF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

i 
Specialty Gas Products 

3106 Pasadena Freeway 

Pasadena, Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 11 /21 /2003 

Customer: Trigas Project No: 5233-001 

Description: CO in N2 - EPA Protocol Exp. Date: 11/21/2006 

Cylinder No: CC176544 Cylinder Pressure: 1900psig 

Requested Certified 

Component Concentration Concentration Accuracy 

Carbon Monozide 100ppm 105pprn 1% 

Nitrogen, Balance 

Reference Standard 

Description 

NTRM 

Instrumentation 

Description 

Horiba Process Analyzer 

Expiration date Cylinder Number Concentration 

7/1 /2006 SG9133548 97.3ppm CO 

Model # Date Last Clibrated Principle 

VIA-510-CO 1114/03 NDIR 

Anayisis Results: Z= zero gas, S= standard gas, X= sample gas 

First Triad - CO Second Triad - CO 

Z1= 0.00 S1= 97.30 X1= 105.36 Z1= 0.00 S1= 97.24 

S2= 97.28 Z2= 0.00 X2= 105.34 S2= 97.20 Z2= 0.00 

Z3= 0.02 X3= 105.40 S3= 97.30 Z3= 0.00 X3= 105.28 

X1= 105.30 

X2= 105.26 

S3= 97.24 

Average = 105.48ppm Average = 105.47ppm 

~ Analyst:--=----- 

3 ~ 

' THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

~ DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

, ~-~;.. 
1 

f 

specialty Gas Products 

3106 Pasadena Freeway 

Pasadena, Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 6/10/2004 

Customer: Trigas , Project No: 9208 

Description: NO in N2 - EPA Protocol Exp. Date: 6/10/2006 

Cylinder No: CC143176 Cy(inder Pressure: 1900psig 

Requested Certified 

Component Concentration Concentration Accuracy 

Nitric Oxide 50ppm 50.2 ppm 1% 

Nitrogen, Balance 

NOx = 51.3ppm 

Reference Standard 

~ Description Expiration date Cylinder Number 

GMIS 4/14/2006 CC176941 

Instrumentation . ~ Description Model # Date Last Clibrated 

Horiba Process Analyzer CLA-510SS 6/7/2004 

~ Anayisis Results: Z= zero gat; S= standard gas, X= sample gas 

First Triad - NO Second Triad - NO 

Z1= -1.40 S1= 990.3 X1= 483.90 Z1= -1.30 S1= 993.0 

S2= 990.8 Z2= -1.50 X2= 482.50 S2= 993.6 Z2= -1.20 

Z3= -1.50 X3= 480.50 

, 

S3= 986.1 Z3= -1.40 X3= 483.80 

~ Average = 50.16ppm Average = 50.21 ppm 

Cunre: Y = 0.416937 + 0.102986*X 

Concentration 

97.3ppm NO 

Principle 

Chemi 

X1= 485.50 

X2=. 484.90 

S3= 992.2 

Analyst: 

THIS ST~" DARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. ;N

DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

0 

i 1 ts 4 
Description Expiration date Cylinder Number 

GMIS 4/14/2006 CC176941 

Instrumentation 

Description Model # Date Last Clibrated 

Horiba Process Anaiyzer CLA-510SS 6/7/2004 

Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas 

First Triad - NO Second Triad - NO 

Z1= -1.40 S1= 990.3 X1= 886.60 Z1= -1.30 S1= 993.0 

S2= 990.8 Z2= -1.50 X2= 885.90 S2= 993.6 Z2= -1.20 

Z3= -1.50 X3= 883.30 S3= 986.1 Z3= -1.40 X3= 889.60 

u 

Concentration 

97.3ppm NO 

Principle 

Chemi 

X1= 894.20 

X2= 892.40 

S3= 992.2 

Specialty Gas Products 

3106 Pasadena Freeway 

Pasadena, Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 6/10/2004 

Customer: Trigas Project No: 9209 

Description: NO in N2 - EPA Protocol Exp. Date: 6/10/2006 

Cylinder No: SG880778 Cylinder Pressure: 1900psig 

Requested Certified 

Component Concentration Concentration Accuracy 

Nitric Oxide 90ppm 91.9 ppm 1% 

Nitrogen, Balance 

NOx = 92.8ppm 

Reference Standard 

Average = 91.7ppm Average = 92.05ppm 

Curve: Y = 0.416937 + 0.102986*X 

' Analyst: 

'

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 
Specialty Gas Prodc.fcts 

3106 Pasadena Freeway 

Pasadena,Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 6/7/2004 

~ Customer: Trigas 

Description: Propane in Air - EPA Protocol 

~ Cylinder No: CC177391 

Requested 

Component Concentration 

Propane 50 ppm 

Air, Balance 

Project: 9211-01 

Exp. Date: 6/7/2007 

Cylinder Pressure: 1900psig 

Certified 

Concentration 

48.8 ppm 

Accuracy 

1% 

' Reference Standard 

Description Expiration date Cy(inder Number 

~ NTRM 7/2/2004 SG9183302 

Instrumentation 

Description Model # Date Last Clibrated 

~ Horiba Process Analyzer FIA-510 5/24/2004 

Anayisis Results: Z= zero gas, S= standard gas, X= sample gas 

' First Triad - Propane 

Z1= 0.60 S1= 207.90 X1= 97.60 

S2= 207.70 Z2= 0.60 X2= 97.20 

~ Z3= 0.60 X3= 97.50 S3= 208.00 

Curve: Y=-0.05085+0.501149"X 

Average = 48.78pm 

Concentration 

103.6 ppm Propane 

Principle 

FIA 

, 

, Analyst: C ---- 

✓"~

. 

THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

~ DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

) 

~ ~ i 
~ MAT H E S QN CE~'.~IFICATE dF ANAL3LSIS -EPA PRO'I`O COL. 1VIIXTU72E 

TRt•GAS 

R 

1650 Enterprise Parkway, Twinsburg, Ohici 44087 e 2 :1 5-648-4000 

.:ustomer: MATHESON TRI-GAS - DALLAS 

pCyfinder Number: SX-36727 

sylinder pressure: 2000 

L-ast Analysis date: 8/7/2003 

11Expiration Date: 8/7/06 

Component : Propane 

Certified Conc: 15.2 ± 0.15 PPM .:. :.... ' 

~ 

Protocol: Reference # Lot AA 

G 1 262579 109— 36-31020 

' DO 

T . 

 USE THIS.CYLINDER W. H1=,,;`:: 

P,RESSURE FALLS_BEL01N 1.:50 PSIG'-'.^_ 

REPLICATE RESPONSES 

Date: 8/7/2003 Date: 

15.2 PPM 

>:15.2 PPM 

` 15:1 PPM 

, .:.. :. .... ... _ ..... 

......,. ... .;:;•;,. .... . .::.:: :: •.: ... :;: - - 

ALANCE GAS: Air 

t2EFERENCE STANDARDS 

~ Component: 

~~ ;• Propane 

: ::::.: .:.::.. :.::. : .:. . . : . .. ..::. ..: . ... .:.. : . ;.: :... ,:-.: :... ....:. 

SRM #: SRM-1.666b 

C linder #: Y Ca1-011826 

~ Concentration: 9.73 ppm 

IPERTIFICATION INSTRUMENTS 

Component: Propane :.. 

Make/Model: Varian 3800 GC 

~ Seri?I Number: LR-92489 

Measurement Principle: TC, FID 

Last Calibration: 8/7/2003 

ido ~es: 

~ 

l

This certification was performed according to EPA Traceability Protocol for Assay & Certification of Gaseous 

Calibration Standards September 1997, using procedure G1 and/or G2. 

4 

~ 

alyst_ 

A 

~ • Date 81812003 

~ 

~ 
i 

! 

1' 

SpeciaIty Gas Products 

3106 Pasadena Freeway 

Pasadena,Texas 77503 

(713) 534-8217 Fax(713) 534-8133 

Date: 6/7/2004 

Custorner: Trigas 

Description: Propane in Air - EPA Protocol 

Cylinder No: SX41680 

Requested 

Concentration 

30 ppm 

Project: 9210-01 

Exp. Date: 617/2007 

Cylinder Pressure: 1900psig 

Certified 

Concentration 

28.8 ppm 

Accuracy 

1% 

Component 

Propane 

Air, Balance 

Reference Standard 

Description Concentration 

~ NTRM 7/2/2004 SG9183302 103.6 ppm Propane 

Instrumentation 

~ 

Description Model # Date Last Ctibrated Principie 

Horiba Process Analyzer FIA-510 5/24/2004 FIA 

Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas 

~ First Triad - Propane 

Z1= 0.60 S1= 207.90 X1= 57.60 

S2= 207.70 Z2= 0.60 X2= 57.50 

~ Z3= 0.60 X3= 57.40 S3= 208.00 

Curve: Y=-0.05085+0.501149'X 

Average = 28.77pm 

~ 

Analysj~ ~-~ —.~ 

, 

; THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. 

; DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

~ 

~ 

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