UNITED STATES DEPARTMENT OF COMMERCE • Maurice H. Stans, Secretary

NATIONAL BUREAU OF STANDARDS • A. V. Asiin, Director

MICROWAVE SPECTRAL TABLES

Volume III. Polyatomic Molecules With Internal Rotation

Paul F. Wacker, Marian S. Cord, Donald G. Burkhard,

Jean D. Petersen, and Raymond F. Kukol

Institute for Basic Standards, National Bureau of Standards, Boulder, Colorado

. National Bureau of Standards.Monograph 70 — Volume III

Nat. Bur. Stand. (U.S.), Monogr. 70, 265 pages (June 1969) CODEN: NBSMA

Issued June 1969

For saJe by the Superintendent of Documents, U. S. Government Printing Office Washington, D.C. 20402 - Price $4.25
mmm bureau of stasdards

1UU435

Microwave Spectral Tables

This five-volume NBS Monograph presents a comprehensive compilation of microwave spectra including measured frequencies, assigned molecular species,

assigned quantum numbers, and molecular constants determined from these data.

All volumes are now available.

Titles of the volumes

I. Diatomic Molecules, $2.00

II. Line Strengths of Asymmetric Rotors, $3.00

III. Polyatomic Molecules With Internal Rotation, $4.25

IV. Polyatomic Molecules Without Internal Rotation, 5«50

V. Spectral Line Listing, $4.75

The volumes are available by purchase from the Superintendent of Documents, Govern- ment Printing Office, Washington, D.C. 20402. Orders from foreign countries should include an additional one-fourth of the price of the publication to cover the postage.

Library of Congress Catalog Card No. 63-62235

ii
Contents

Page

1. Introduction V

2. Explanation of tables VII

3. List of symbols, abbreviations and conversion factors X

4. Tables of microwave spectra of molecules listed according to empirical formula... 1 5. Index according to empirical formula 258

6. Index according to chemical name 259

7. Bibliography 261

iii

Microwave Spectral Tables

Volume III. Polyatomic Molecules With Internal Rotation

Paul F. Wacker, Marian S. Cord, Donald G. Burkhard,

Jean D. Petersen, and Raymond F. Kukol

Measured frequencies, assigned molecular species, and assigned quantum numbers are given for about 9.000 spectral lines of polyatomic molecules with internal rotation observed by coherent radiation techniques. Molecular data, such as rotational ctinstants, dipole moments, and various coupling

constants, determined by such techniques, are also tabulated. References are given for all included

data.

Key Words: Microwave spectra, molecular spectra, spectral lines, rotational constant, quadrupole

coupling! constants, internal rotation, hindered rotation, centrifugal distortion constarit, barrier height, dipole moment, polyatomic molecules, coherent radiation technique.

1. Introduction

This volume contains data on the microwave

spectra of 94 polyatomic molecules capable of exhibiting internal rotation, based upon a search

of the literature up to July, 1962, but including some

information of later dates. In most cases some

effects of internal rotation have been observed. In others it has not actually been observed but its existence can be inferred from structural informaI tion. These are molecules whose atoms can be

arranged in groups in such a way that the groups are capable of rotating separately about common axes. This rotation is hindered by a potential. In the case that the chemical bond between the nearest atoms in two adjacent groups is a single one, it is supposed that the potential is small enough to per- mit observations of internal rotation effects, and

j such molecules are contained in this volume even

f if the internal rotation has not been observed. However, when the bonds are of higher order, the barrier to rotation is so high that torsional effects are most conveniently treated with techniques ordi- narily used for vibration.

ji The theory of microwave spectra of molecules

I with internal rotation is briefly discussed by Townes

; and Schawlow ' and in more detail by Lin and

Swalen.^ The following qualitative discussion,

'l ' C. H. Townes and A. L. Schawlow, Microwave Spectroscopy,

McGraw Hill, N.Y. (1955).

li ^C. C. Lin and J. D. Swalen, Rev. Mod. Phys. 31, 841 (1959).

which is intended for readers not familiar with the

field, is limited to molecules with two rotatable

groups and therefore to a single internal rotation. The hindering potential can be expressed, by means of a Fourier series, as a function of the dif- ference a between the angular displacements of the

two groups about a convenient common axis. If each group has a plane of symmetry containing the

common axis, a may be defined so that no sine term

occurs in the series. Further, if either group has

axial symmetry, only terms in na (where n is an

integer) and its harmonics appear. Moreover,

of the non-constant terms of the series, only

the leading term is ordinarily considered; in most cases, agreement between theory and the

available experimental data is so good that more

laborious analysis is not considered justifiable.

Then with this approximation the potential may be

written as

V = ^(l-cos na), (1)

where n is an integer which depends upon the symmetry of the molecule. The barrier height, V

(Vn in the preceding approximation), is a principal

parameter to be determined by analysis of the

spectra.

V
The presence of internal motions greatly complicates the spectra. Therefore, it is not surprising

that the molecules which have been studied are

chiefly those where the situation is somewhat simplified by molecular symmetry. The principal theoretical treatments assume that at least one of the

internally rotating portions has at least a three-fold

axis of symmetry, i.e., that rotation of the group

through the angle 27r/p, where p is at least 3, yields a configuration which is indistinguishable from the

original. The commonly encountered methyl

group, as well as every symmetrically-substituted

methyl group, has a three-fold axis. This portion

is commonly referred to as the "top". If the first group has a p-fold axis and the second has a q-fold

axis, the integer n is the least common multiple of

p and q. Thus, n equals 3 if each rotatable group

is a methyl group or a symmetrically substituted

methyl group, or if one has three-fold symmetry and

the other has no axis of symmetry.

Associated with the internal motion is a torsional

quantum number v. If v is sufficiently low and if the barrier height Vn is sufficiently high that the

kinetic energy of torsional motion is small compared

to Vn, the internal motion can be considered that of torsional oscillation. However, the torsional

levels may be split by quantum mechanical tunneling between the n equivalent relative orientations;

this process is the angular analog of the well- known inversion of ammonia. In the opposite

extreme, in which the internal motion is a free

rotation, the levels are again split, although the

details are different.'' In either case, there are n states for each value of v, although there may

be some degeneracies among these states. In the most frequently studied case, for n = 3, each

rotational level is split into a single level of grouptheoretical species A and a doubly-degenerate

level of species E. For each given value of v, the A levels give rise to a spectrum which, to a

first approximation, is of the same form as the

spectrum of a rigid rotor, except that the rotational constants are functions of v. Transitions between

A and E levels are forbidden since the dipole

moment cannot be a function of a. In some cases

the spectrum due to the E levels may resemble

that of a rigid rotor and in other cases it may not, depending upon the barrier height and the asymmetry of the molecule. The separation between

pairs of A and E levels is a measure of the barrier

height and, therefore, is of prime interest. The

spectra due respectively to the A and E levels are usually distinguishable experimentally by the Stark

effect. The A spectrum, as with rigid asymmetric

rotors, exhibits a quadratic effect, while the E

•'This splitting occurs even for zero barrier.

spectrum often gives rise to a much larger Stark

effect, frequently of a linear or quasi-linear

character. The nature of the hyperfine pattern

also often can be used to distinguish between the

two types of spectra.

Two mathematical descriptions of these molecules have been widely used. One of these is called the Principal Axis Method (PAM). In this the internal motion is referred to the set of axes which makes the off-diagonal products of inertia of

the molecule as a whole equal to zero. It is fixed

to one of the two groups, which is referred to as the

"frame." If one of the two groups does not have

three-fold or higher axial symmetry, it is the one chosen as the frame because then the moments and

products of inertia are independent of the angle a, and if the principal axes have been selected to make

the products of inertia zero for one value of a, they

remain zero for all others. In this system the quantities which are of fundamental interest are: (1) the principal moments of inertia and their associated

rotational constants A, B, and C, where A ^ B ^ C;

(2) the moment of inertia I,, of the top with respect

to the axis of internal rotation; and (3) the direction

cosines (X) of the axis of internal rotation with re- spect to the principal axes. The other is the Internal Axis Method (lAM) in which the axis of internal rotation is chosen as one

of the axes used to express the rotational energy of

the molecule. Here the following quantities are

of fundamental interest: (1) moments of inertia and rotational constants with respect to the principal axes; (2) direction cosines of the internal axes

relative to the principal axes; (3) moments and

products of inertia of the whole molecule with

respect to the internal axes; and (4) the moments

of inertia of the two parts of the molecule with

respect to the internal axis.

In the Hamiltonian, the kinetic energy may be

expressed in three parts: (1) that due to the rotation

of the molecule; (2) that due to the internal rotation;

and (3) that due to interaction between (1) and (2). In the PAM, both the overall rotation and the in- ternal rotation are simply expressed, and the inter- action is treated as a perturbation; if the interaction

is readily handled, this procedure is quite convenient. In the lAM, the interaction terms are

ordinarily considerably smaller than in the PAM,

permitting a relatively simple perturbation treat- ment. The chief disadvantage of the lAM is that the failure to use principal axes complicates the

Hamiltonian by introducing terms containing

products of inertia. To provide further simplification, it may be necessary to introduce trans- formations to additional coordinate systems, each

vi
requiring the definition of additional quantities.

Further details, as well as the method of translating

between PAM and lAM data, can be found in the

review paper by Lin and Swalen.^ Such additional

symbols as are required for the purposes of these

tables will be defined later. In these tables an attempt has been made to

list quantities obtained directly from experiment and

to utilize structural information or hypotheses to the very minimum possible, since the latter are subject to change and, frequently, to controversy.

In cases where analysis requires some structural

information, the results from the authors' analyses

have been given in order to minimize the uncertainty

arising from structural information.

There do exist some nonuniformities of style as some authors have employed uncommon notations,

and it has been found desirable to have the results remain in their notation.

To minimize typographical errors, the data for the tables were punched on cards, converted to magnetic tape, listed, and then thoroughly compared with the original documents. No manual

typesetting was used for the tables proper or their

headings. Instead, the automatic photocomposition equipment of the Government Printing Office was controlled by tape prepared from the afore- mentioned data tape by means of computer pro- grams. The control tape commands necessarily were detailed and included those for the chemical

formulas, superscripts, subscripts, vertical and

horizontal lines, spacings, and all characters,

allowing for the variable character widths.

The Authors gratefully acknowledge invaluable

assistance: in reviewing, from Yardley Beers,

Robert Wallis and Jack Ross; in programming, from

Matthew S. Lojko, and Jean Tucker; in checking,

from Abiodun Afonga, Rudolph Haas, Emmett

MacKenzie, Nancy Mills, and Marion Hinchman.

The volume could not have been finished for publication without their contributions. Thanks are

also due the many scientists in the field of Micro- wave Spectroscopy who so graciously replied to requests for information.

2. Explanation of Tables

Data for these Microwave Spectral Tables have

been compiled from a review of articles found in all internationally recognized journals as well as private

communications regarding unpublished work.

Generally speaking, date and accuracy of data

measurement were the criteria by which any re- quired selection was made. An explanation of the

format and contents of the tables follows. The first line of data contains an identification

number and the Chemical Abstracts name. The

lines immediately following give alternate names,

if any. The last line of the heading contains the

empirical formula, the symmetry point groups,

and (where possible) the "quasi-" structural formula.

The first point group is for the molecule as a whole,

assuming only one isotopic form of each element

and the configuration believed to have the lowest

potential energy. The parentheses contain the

point group of each independently rotatable portion

(with associated bonds). For a straight-chain

molecule, the order is that of the structural formula.

Molecules are indexed first according to empirical

formula, as in Chemical Abstracts, then alphabetically by name. A numbering system has been

established for identification of the molecules and

their isotopic species for convenience in programming and referencing. Each molecule was given

a number ending in zero in order of its occurrence

on the list. Its species have been numbered

consecutively from that point, skipping the next

zero when the number of isotopic species exceeds

nine. Every species is given for which any molecular constants or spectral lines from microwave

sources have been reported through June 1962.

In the formulas for the species, mass numbers have

been placed as superscripts to the right of the

atomic symbols. Hydrogen is the one exception —

for the normal mass of 1 the superscript is omitted

and for deuterium (H-) the symbol D is used.

In the second column of the molecular constant

table, the overall symmetry point group (Pt. Gp.)

has been given for each isotopic species of the

molecule as the analysis permits. Some consideration of structural information was necessarily a part

of these assignments.

Most of the rotational constants tabulated have

been derived from microwave sources, and this is indicated by the M occurring after the values. In

a few instances, other experimental sources have

been designated by the code letter N for near

infrared measurements. Use of symmetry has

been made in reporting rotational constants. If, for example, the axis of symmetry of a symmetric top

is known to be the axis of least moment of inertia.

vii
then the constants B and C are equal and are so recorded. Every moment of inertia has been con- verted to the corresponding constant A, B, or C

(in megahertz) by muhiphcation with the ap- propriate conversion factor. These factors are given later. Centrifugal distortion effects are more important

in the microwave spectra of asymmetric rotors than

in the case of symmetric tops and more important

with light molecules than with heavy molecules.

The constants Dj and Djk are dependent upon the

rotational constants and the vibrational force

constants. Although both D., and Djk are small

in comparison with the values of the rotational constants, they serve to complicate the relationship

between the other parameters and the frequency v. Townes and Schawlow * state that Dj is always positive, but Djk is positive or negative depending upon

the type of molecule.

The asymmetry parameter

^ 2B-A-C

" A-C

is a measure of the variation from the symmetric

top. For a prolate top, k = — 1 and for an oblate top,

K —+ 1. Hence k ranges between these two values. In cases where the original papers have used other

parameters, these have been converted to k values. Formulas which were used for these conversions

are as follows:

3bpT|-l l + 3bo

bp— 1 1 — bo

bp and bo refer to prolate and oblate symmetric

tops respectively.

With planar molecules the inertial defect,

A=Ic — Ia~Ibi is frequently of interest. Classically, for a rigid molecule, this is zero, but in actuality it is nonzero becausp of the existence of zero point vibrations. In many instances, the total dipole moment /x was found in the literature, but it had not been

resolved into a, b, and c components. Symmetric

top molecules have two equal principal moments

of inertia, denoted by lb. The dipole moment of

such molecules lies along the principal axis with the

unequal moment of inertia. Some of the original

papers did not specify whether this moment of

inertia was smaller or larger than the two others and,

therefore, did not indicate whether this third axis

should be labelled a or c. An effort was made to

* Townes and Schawlow, Microwave Spectroscopy, McGrawHill Book Co., pp. 77-79, 105-109 (1955).

resolve this question by making use of available

structural information to calculate the moment of

inertia with respect to the symmetry axis according

to the formula

Isym — n m 1- sin- 0,

where n is here the number of equivalent off-axis atoms or groups, m is the mass of the off-axis atom

or group, 1 is its distance along the bond to the axis,

and (f) is the angle between the bond and the

symmetry axis. Where n = 3 and d is the angle

between the bonds from the axis to a pair of equivalent off-axis atoms, the formula becomes

Isym = 2 m 1- (1 — cos 6).

(Townes & Schawlow, p. 53)

Using the convention Ig ^ I^, = Ic, if the computed value was smaller than the given I^ then

the figure axis was a, if greater than I,, then the

figure axis was c. A symbol M follows the value

if the dipole moment was measured by microwave

techniques, usually the Stark effect. In the case of

asymmetric molecules, if the components of the

dipole moment were not specified, the reported

dipole moment was entered under the component

which was adjudged the major one (according to transitions assigned to frequency lines, or, if these were lacking, according to structural information

available). In addition, the letter u designates the

unknown (but possible) second or third component.

The code letter T is used after the dipole moment

entry if it was not obtained by microwave techniques

unless the moments were known to be obtained

from the Debye equation with temperature-variation data for the molar polarization of the gas or

liquid. In these cases designations G or L are used.

Dipole moment components known to be zero by

virtue of established symmetries are indicated by

an X after the data (for example, a component per- pendicular to the plane of symmetry, or one in a plane perpendicular to the axis of symmetry, would

always be zero). Effects of isotopic substitution on the symmetry of the molecule have been taken

into account. Quadrupole coupling constants, eQq, obtained

from hyperfine structure measurements are re- ported as found in the literature. These relate to the energy of interaction between the molecule and

the nuclear quadrupole moment. In some cases

the authors have reported these as referred to the

principal axes or with reference to a particular bond,

and if so, they are recorded thus. Potential barrier

heights are designated by V. Integer subscripts

viii
are used to designate components corresponding to individual terms in the Fourier series expressing

the potential. The number n is related to the

symmetry of the molecule as described in the intro- duction. In a few cases the reduced moment of

inertia (Ired) is given. Microwave values of the

torsional frequencies (which also provide measures

of the barriers) are given in cm~'. To facilitate later description of transitions involving excited

vibrational states, each vibrational mode excited

in any observed microwave transition is assigned a

letter subscript and is identified by the frequency

(X) in cm"' and the degeneracy d. The table of reported spectral lines for each molecule starts on the page with or following the molecular constant table. Lines for each isotopic molecular species are arranged in the following pattern:

ascending order of rotational quantum numbers

according to

(l)J', (2) J, (3) K:„ (4) K-i, (5) K;i, (6) K+i,

then in ascending magnitude of frequency. Immediately following the heading for the spectral

hnes the formula and identification number of the

isotopic molecular species are printed. For asymmetric tops the rotational quantum numbers are arranged in the pattern

J', K!_i, K+i J, K-i, K+i,

where primes denote upper state. For prolate or oblate symmetric tops the arrangement is

J', KLi^J, K_, or J', K;,^J, K+1,

respectively; for linear molecules simply J' «— J. Unassigned lines are so indicated. Blanks occur where the identification was not complete. It should be recognized that unassigned lines may be

due to impurities and may be spuriously associated

with a particular molecule.

Also, it should be mentioned that, in a few AJ = ±1 transitions of very asymmetric molecules,

it is difficult to ascertain which is the upper state even if quantum numbers have been assigned to both states. There is indication that some authors

have not clearly stated the existence of this uncertainty or that they have been careless with their

notation in this regard. In some instances clari- fication has been obtained, but in others this was

not possible. In any event the quantum numbers

on the left denote the state which is believed to be

the upper state. For the most part, unless there is reason to sup- pose otherwise, the ground vibrational state has

been assumed where the specific state was not mentioned. For each transition corresponding to an excited vibrational state, the vibrational quantum

number of each excited normal mode is given.

These are identified by v^, V(,, etc., the letter subscripts corresponding to the mode identifications

introduced in the molecular constant table. More than one format is used in the portion of

the table dealing with internal rotation, since the

appropriateness of format and notation varies with

the number of rotating groups, the symmetry of the molecule, and the barrier heights. Insofar as was

possible, the A and E state and n designation has

been maintained. However, special cases have

arisen where it was not possible to translate the

notation given in the article into these terms. Attempts have been made to use the same notation

found in the reference from which the material was taken and it "is not our purpose to duplicate

here detailed explanations of these special formats.

The reader should consult the referenced literature

for the author's explanation.

There is considerable nonuniformity in the listing

of hyperfine components mainly because many

times only a few of the rotational transitions of a given molecule may have their hyperfine splittings

analyzed. If the hyperfine splitting is resolved,

the individual lines are ordinarily reported separately in the present tables with the total angular

momenta F' and F of the upper and lower states, respectively. If the splitting is partially resolved,

the assigned F values are given for the resolved

Hnes. For large J values, the AF = AJ components

are relatively strong and displaced very fittle from

the frequency the line would have if there were no

hyperfine sphtting. If the hyperfine spfitting is quite small (less than 5MHz), the frequency of the

hypothetical line for zero quadrupole moment is commonly hsted and shifts from these frequencies

given in the tables of spectral lines or footnotes to them.

Efforts were made to determine from the author's

statement, the accuracies to which spectral hnes were measured, though in many cases, these were

not well defined in the literature. References are indicated for all data, but wherever practicable foot- notes have been given to obviate the necessity of

referring to these. References are arranged in order of year of publication, then alphabetically

according to first author and numbered consecutively. A few exceptions occur in the case of books

and of articles which were not reviewed until after the numbering had been completed and a change

in reference number would have necessitated

extensive changes throughout the whole volume.

ix
3. List of Symbols, Abbreviations, and Conversion Factors

Symbols and Abbreviations

The following symbols and abbreviations are listed in the order

in which they may first occur in the tables.

Molecular Constant Table

Double bond.

Triple bond. Extra (cyclic) bond between two atoms pre- ceding these symbols.

Asymmetric. As a superscript to an atomic symbol, indi- cates isotope not stated. Cis structure. Gauche structure. Trans structure. Symmetric.

Symmetry point group of the molecular

species.

Identification number of the molecule or molecular isotopic species. Rotation constants (MHz). A g B g C. Microwave determination. Near infrared determination.

Centrifugal distortion constants (MHz).

Ray s asymmetry parameter, (2B — A — C)/ (A-C).

Inertial defect (amu A^). Principal axes corresponding to A, B, and C,

respectively.

Components of the dipole moment along the

principal axes (Debye). Abbreviation for Debye units. Value not known.

Value precisely zero due to symmetry.

Barrier height, Vn,ax~ V^in (cal/mol). Accuracy of any previous quantity.

Reduced moment of inertia (amu A-). For a symmetric top, the electric quadrupole

coupling constant along the symmetry

axis (MHz).

Vibrational frequencies of modes a, b, . . excited in observed microwave spectral

lines (cm" '). Degeneracy of the preceding vibrational mode. Numbers are reference numbers as in the

bibliography.

Pt. Gp.

Id. No.

A, B, C

M

N

D.,,D.,k.Dk KA

a, b, c

A^a, b.

c

D

uX

V

Acc

I red eQq

d

Ref.

eQqa

Xaa' v„

la

la. h. 1

Va; Vb; . .

A. E, . . n

F!, ., . F

Electric quadrupole coupling constant along

indicated principal axis (MHz).

Coefficient of cos na in the Fourier series for

' the potential barrier function (cal/mol). Moment of inertia of rotatable group (amu A-). Moments of inertia of the whole molecule

with respect to the indicated principal

axes.

Spectral Line Table Quantum number of the vibrational mode

identified as a. b, . . in the molecular

constant table. The / quantum number

is given after a comma rather than as a superscript.

Symmetry species of the internal rotor state. Torsional quantum number.

Total angular momentum quantum number. Primed values are for the upper state, unprimed values for the lower state. Those with subscript / include nuclear

spin only for nucleus with largest eQq.

Conversion Factors

The following formulas were used to convert the literature values X to the values y of the tables. The respective units are given in parentheses. It should be pointed out that the conversion factor given here for amu-A- to MHz is based on the atomic weight scale in which C''-=12. However, most data covered in these tables were based on the older scale in which 0'«=16.

amu to MHz:

cm"' to MHz:

gm-cni- to MHz:

cm"' to cal/mol:

y(MHz) = (8.391420 X lO'i) x(amu A2)(1.6604345)

(5.0537497 x 10") x(amu A-)

y(MHz) = (2.997925 X 10") x (cm "

y(MHz) =

y(cal/moI) = 2.859 x(cm"')

. (8.3914204 X 10^) x(gm-cm-)

X
4. Tables of Microwave Spectra of Molecules

Listed According to Empirical Formula

xi

ll

10 Dioxygen Difluoride Miilccular Constant 'l"alj|c

F2O2 CjlC^C,) FOOF

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(IVIHz) D., D.,K K A

C2 11 20 266.18 M 5 011.09 M 4 360.14 M -.9182

c, 12 19 531.98 M 4 975.78 M 4 318.68 M -.9136

13 18 8.59.19 M 4 938.34 M 4 279.31 M -.9096

Id. No. /Aa Debye fib Debye |U,c Debye eQq

1 V2 Acc. ^reU COa d (o„ d CO,, d d

11 0. X 1.44 M 0. X 30000

References: ABC: 345 Dj: Djk: k: 345 A:

ix: 345 eQq: V: 345 I: o>:

Dioxygen Difluoride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine - Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

11 1, 1^ 0. 0. 0 Excited 1 24 484.06 345

1, 1^ 0, 0, 0 Ground 24 626.32 345

1. 1^ 0, 0. 0 Ground 1 24 715.57 345

1, 1^ 0, 0, 0 Ground 2 24 804.00 345

1, 0^ 1. 0, 1 Excited 1 15 81 7.85 345

1, 0^ 1, 0. 1 Ground 15 906.04 345

1, 0*- 1. 0, 1 Ground 1 16 016.74 345

1. 0^ 1, 0, 1 Ground 2 16 127.52 345

1. 0^ 1. 0. 1 Ground 3 16 239.55 345

1. 0^ 1, 0. 1 Ground 4 16 353. 345

2. 1. 2^ 1, 0, 1 Ground 33 346.88 345

2, 1. 2<- 1, 0, 1 Ground 1 33 414.80 345

2, 1. 2^ 1, 0, 1 Ground 2 33 480.62 345

2, 1. 2^ 1, 0, 1 Ground 3 33 539.31 345

2. 1. 1^ 2. 0. 2 Excited 1 16 491.51 345

2, 1, 1^ 2, 0, 2 Ground 16 577.38 345

2, 1, 1^ 2, 0, 2 Ground 1 16 700.24 345

2, 1, 1^ 2, 0, 2 Ground 2 16 822.03 345

2, 1, 1^ 2, 0, 2 Ground 3 16 944.86 345

2, 1, 2^ 3, 0, 3 Ground 13 406.8 .5 345

2, 2, 1^ 3. 1. 2 Ground 16 690.0 .5 345

3, 1, 2^ 3, 0, 3 Excited 1 17 540.88 .1 345

3, 1, 2<^ 3, 0, 3 Ground 17 622.05 .1 345

3. 1. 2^ 3, 0, 3 Ground 1 17 764.15 .1 345

1 3. 1. 2^ 3, 0, 3 Ground 2 1 17 903.30 .1 345

1
Dioxygen Difluoride Spectral Line Table

Isotopic Species iU. Rotational Vib State Tnt Rotor Hyperfine Frecjuency Acc. Ref. Quantum Nos. F' F' F F MHz ±MHz

11 3, 1, 2<— 3, 0, 3 Ground 3 18 042.39 .1 345

3, 1, 2«— 3, 0, 3 Ground 4 18 182.24 .1 345

4, 0, 4^ 3, 1, Ground 9 93^tj 0^14. XT'. 70i\j \ 345

4. 0, 4-^ 3, 1, Excited \ 93 43fi 63 \ 345

4, 0. 4^ 3, 1, Ground 1 93 4.4.3 7fi \ 345

4, 0, 4^^ 3, 1, 3 Ground 23 563.25 .1 345

4, 1, 4<- 3, 0, 3 Ground 49 860.8 .5 345

4, 1, 4<- 3, 0, Ground 1i /to 070 Q n: .0 4, 1, 4^ 3, 0, 6 Ground 9 .0 4, 1, 4, 0.

A4 Ground 1

. X

4, 1, 3<— 4, 0, 4 Ground 1 19 253.5 .5 345

4, 1, 3«— 4, 0, 4 Ground 2 19 418.45 .1 345

4, 1, 3^ 4, 0.

A

4- Ground Q IQ c:qi 7n 1 7 00 1 . ( u \ 345

5, 0, 5*- 4, 1.

A Ground Q 23 484 7 .0 345

5, 0, 5<— 4, 1, 4- Ground .5 345

5, 0, 4, 1, 4 Excited 1 33 700.7 .5 345

5, 0, 5^ 4, 1. 4 Ground 1 33 765.25 .1 345

5, 0, 5^ 4, 1, 4. Ground 3^ 871 f\ .5 345

5, 1. 4^ 5, 0,

cD Ground Z.1 91 nio 017.40'fO \ 345

Co.11

,

A 4 4'* c c0 Ground 1 91 99'^ ^ .5 345

c

J-*

11

,

A 4 4-* c A 5 Ground 2 21 424.8 .5 345

c 1 A4 0^ fi^1 5 Ground 3 21 620.05 .1 345

6, 1, 5^ 6, 0. 6 Excited 1 23 433.29 .1 345

6, 1. 5^ 6, 0. 6 Ground 23 488.36 .1 345

0, 11

,

c< f. 6 Ground 1 23 743.20 .1 345

6, 1, 5<— 6. 0, 6 Ground 2 23 986.65 .1 345

6. 1. 5*— 6, 0. 6 Ground 3 24 224.09 .1 345

7. 1, 6<- 7. 0. 7 Ground ZD96 oo^^.oo =^=^9 %9. 1

. 1 04*0

8, 1. 7^ 8. 0. 00 Ground ou ZOo.VO 1 9. 1, 8<— 9. 0. Q Ground 04. 000.DU 1

12 1, 1, 1<— 0, 0, 0 Ground 23 850.65 .1 345

1, 1, 0^ 1, 0, 1 Ground 15 213.30 .1 345

1, 1, o«- 1, 0,

11 Ground 11

1 qi Q ft^ ID OiV.OD 1

2, 1, 2'«— 1, 0, i Ground oZ 4'Oo.i .D 04.0 2, 1, 1«- 2, 0, Z Ground 1xoi^i «Q9 oyz.xo1 1

. 1

3, 1, 2*— 3, 0, 3 Ground 16 950.37 .1 345

3, 1, 2<- 3, 0,

Q Ground 11c.0 040

4, 0, 4^ 3, 1, Ground zo Vol.0

/

"I .1 5, 0, 5*- 4. 1,

/I Ground OA 171 Q c

.0 040

13 1, 1, 1^ 0. 0. 0 Ground 23 138.5 .5 345

1. 1, 0^ 1, 0, 1 Ground 14 579.88 .1 345

2. 1, 2^ 1, 0. 1 Ground 31 697.0 .5 345

2, 1, 1^ 2, 0, 2 1 _ ri~t 1 1 11 jH v_' I U LI I IU 1 5 961 76 345

3, 1, 2^ 3, 0. 3 Ground 16 327.46 .1 345

5. 0. 5^ 4, 1. 4 Ground 34 395.9 .5 345

F.i90'«0'

F.i''Oi

2
20 - Tetrafluorohydrazine Molecular (^oiislanl TahliF,N, C,(C„C,)

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) D., D.,K K A

C, 21 ,5 .576.21 M 3 189.35 M 2 812.95 M -.7276

Id. No. Debye Debye /Ac Debye eQq Acc. Ired Wa d CD,, d We d C0(i d

21 0. X 0. X 0.26 M >3000

References: ABC: 255 Dj: ' Djk: k: 2.55 A:

/a: 255 eQq: V: 255 I: co:

Add. Ref.: 362

Torsional frequency= 100 to 150 cm"'. Ref: 255.

Tetrafluorohydrazine

gp^^^^^, ^jne Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f; HypeF'

rfine FFrequency

MHz

Acc. ±MHz

Ref.

pi9N14N14pl9 21 2. 2, 0^ 1, 1, 0 Ground 19 582.6 .3 255

2, 2, 1^ 1, 1, 1 Ground 19 917.9 .2 255

3, 1, 2^ 2, 0, 2 Ground 21 725.0 .2 255

3, 2, 1*- 2, 1. 1 Ground 25 370.14 .05 255

3, 2, 2^ 2, 1, 2 Ground 26 297. 1. 255

3, 3, 0^ 2, 2. 0 Ground 30 868.47 .05 255

3, 3, 1^ 2, 2, 1 Ground 30 906.52 .05 255

4, 1, 3<- 3, 0, 3 Ground 28 549.9 .3 255

4, 2, 2^ 3, 1, 2 Ground 31 187.4 .1 255

4, 2, 3^ 3, 1, 3 Ground 32 856. 1. 255

9, 5, 4^ 9, 4, 6 Ground 22 866.9 .3 255

10, 5, 5^10, 4, 7 Ground 22 805.9 .3 255

11, 5, 6^11, 4, 8 Ground 22 788.3 .3 255

12, 5, 7^12, 4, 9 Ground 22 865.6 .3 255

13, 5, 8^13, 4,10 Ground 23 110.0 .3 255

14, 5, 9^14, 4,11 Ground 23 620.1 .3 255

14, 6, 8^14, 5,10 Ground 27 526.5 .3 255

15, 5,10^15, 4,12 Ground 24 512.5 .3 255

15, 6, 9^15, 5,11 Ground 27 461.3 .3 255

16, 6,10^16, 5,12 Ground 27 501.8 .3 255

17, 6,11^17, 5,13 Ground 27 723.1 .3 255

18, 6,12^18, 5,14 Ground 28 226.0 .3 255

19, 6,13<-19, 5,15 Ground 29 131.5 .3 255

20, 6,14^20, 5,16 Ground 30 572.0 .3 255

21, 6,15^21, 5,17 Ground 32 669.0 .3 255

3
30 -Nitric Acid HNO, Cs(Cs,C2v)

Molecular Constant Table HNO.

Isotopic Species Pt. rGp.n

Id.

INO. A (MHz) B(MHz) C (MHz) Dj DjK A

HN"0,f 31 13 011.15 M 12 099.93 M 6 260.60 M .73003 .11467 DN»OJ« c. 32 12 970.71 M 11 312.82 M 6 034.86 M .52192 .10710 HN'-^Or 33 13 012.35 M 12 096.97 M 6 260.09 M .72886 .11467

Id. No. /u,a Debye /u.t, Debye fj.^. Debye eQq V3 Acc. Iped OJa d d (Up d <Wd d

31 1.99 M 0.83 M 0. X 9400

References: ABC: 304

304

Dj: eQq:

Djk:V: 129

k: 304

I:

A: 304

For species 31, the quadrupole coupling constants are: eQqaa= 93± .05 MHz, eQqbb = For species 32, the quadrupole coupling constants are: eQqa.- = .82± .05 MHz, eQqbb = Ref: 304.

.82 ±.05 MHz, and eQqec =- -H ± .10 MHz.

-.62±.05 MHz, and eQqcc = - .20± .10 MHz.

Nitric Acid Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

HN'^Cf 31 1, 0. 1^ 0, 0, 0 Ground 0 18 360.06 304

1, 0, 1^ 0, 0, 0 Ground 2 18 360.48 304

1, 0, 1*- 0, 0, 0 Ground 1 18 360.78 304

1. 1, 1*- 0, 0, 0 Ground 1 19 271.45 304

1. 1, 0. 0, 0 Ground 2 19 271.69 304

1, 1, 1^ 0, 0. 0 Ground 0 1 19 272.06 304

2, 1. 2^ 1, 0, 1 Ground 31 792.80 304

2, 1, 2^ 1. 1. 1 Ground 1 0 30 881.24 304

2, 1, 2^ 1, 1, 1 Ground 3 2 30 881.69 304

2, 1, 2^ 1, 1, 1 Ground 2 1 30 881.92 304

2. 1. 1^ 2, 0, 2 Ground 17 616.03 147

2, 1, 1^ 2, 1, 2 Ground 17 517.51 304

3, 2, 1^ 3, 1, 2 Ground 16 700.74 147

3, 2, 1^ 3, 2, 2 Ground 16 215.59 304

3, 3, 1^ 3, 1, 2 Ground 22 161.00 147

3, 3, 0^ 3, 2, 1 Ground 9 447.97 147

3, 3. 1^ 3, 2, 2 Ground 21 676.16 147

4, 3, 1^ 4, 3, 2 Ground 14 534.25 304

5, 3, 2*- 5, 3, 3 Ground 29 175..32 304

5, 4, 1*- 5, 4, 2 Ground 12 540.98 304

6, 4, 2^ 6, 4, 3 Ground 27 369.67 304

6, 5, 1<- 6. 5. 2 Ground 10 344.23 304

7, 5, 2^ 7, 5, 3 Ground 24 903.51 304

7, 6, 1<- 7, 6, 2 Ground 8 097.58 304

8, 6, 2^ 8, 6, 3 Ground 22 147.00 304

9, 7, 2«- 9, 7. 3 Ground 18 969.56 304

10, 8, 2^10, 8, 3 Ground 15 628.19 304

11, 9, 2^11, 9, 3 Ground 12 317.35 304

12,10, 2^ 12,10, 3 Ground 9 245.56 304

4
Nitric Acid Spectral l.irjc

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine > Frequency Acc. R<-f. No. Quantum NOS Slate n F' F VI H /, _i_ ±

\/r 14.,

;VI li /.

1. 0. 1^ 0. 0. 0 (i round 0 1 17 .347.27 304

1, 0, 1^ 0, 0. 0 Criou nfi 2 i 17 347.64 304

1. 0, 1^ 0, 0. 0 Ground 1 1 17 347.89 304

1, 1, l'^ 0, 0. 0 (iround 1 1 19 00,5.40 304

1, 1, 1<- 0. 0. 0 Ground 2 1 19 00,5.61 304

1, 1, 1^ 0. 0. 0 Grou nd 0 1 19 005.89 304

2. 1, 2^ 1. 0, I C/Fou nd 31 075.40 304

2, 1, 2^ 1. 1. 1 GFrouud 1 0 29 417.40 304

2, 1, 2^ 1, 1, 1 Ground 2 1 29 417.40 304

2. 1, 2^ 1, 1, 1 Ground :5 2 29 417.40 304

2. 1. 1^ 2. 1. 2 Ground 15 832.83 304

3. 1. 2^ 3, 1. 3 \j I ((11111.1 29 138.41 304

3. 2, 1^ 3. 2. 2 (iround 13 579.09 304

4, 2, 2^ 4. 2. 3 Ground 27 215.84 304

4. 3. 1^ 4. 3. 2 (iround 10 807.99 304

5. 3, 2^ 5, 3, 3 Ground 24 229.63 304

5, 4, 1^ 5, 4. 2 Ground 7 833 96 304

6, 4, 2^ 6. 4. 3 Ground 20 396.03 304

7,8,

5. 2^ 7, 5. 3 Ground 16 065.29 304

5. 3^ 8. 5. 4 Ground .32 137.90 304

8, 6. 2^ 8. 6, 3 Ground 11 680.10 304

9, 6, 3^ 9, 6, 2 ( . i"o 1 1 n (

"1 26 938 68 304

10, 7, 3^10, 7, 4 Ground 21 229.43 304

11. 8. 3^ LI. 8, 4 Ground 15 553.69 304

12. 9. 3^ 12. 9, 4 Ground 10 487.08 304

33 1, 0. 1^ 0. 0. 0 Ground 18 357.05 304

1, 1. 1^ 0. 0. 0 Ground Jy 2/2. 44 304

2. 1. 2^ 1. 0, 1 Ground 31 792.60 304

2. 1. 2^ 1, 1. 1 Ground 30 877.22 304

749-587 0-69—

5
40 - Hydrogen Peroxide Molecular Constant Table

H2O2 C.,(C„Cs) HOOH

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D., DjK K A

C, 41 301 700. N 26 192. N 25 126. N

D2O.;" c. 42 162 700. N 23 749. N 22 165. N

HDOJ'^ c, 43 210 800. N 25 047. N 23 501. N

Id. No. /U-a Debye /Xh Debye IX,. Debye eQq V, Acc. Led OJa d (Uh d cu^. d

41 0. X 0. X 2.26 M 113

References: ABC: 355 Dj: Djk: k: A:

fi: 93 eQq: V: 93 I: (o:

Add. Ref.: 57

Torsional frequency = 314 cm Ref: 315.

r

6
Hydrogen Peroxide

gp^^^^^, ^^.^^ ^^^^j^

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.

I No. Quantum Nos. State n f: F' F, F MHz ±MHz

41 Not Reported 11 072.4 .5 115 Not Reported 14 829. .5 .2 115 Not Reported 16 0.32. 2. 115 Not Reported 22 0.54..5 .2 115 Not Reported 27 6.39.6 .2 115

Not Reported 3.5 916. 2. 115 Not Reported 37 .517.6 .2 115 Not Reported 39 033. 2. 115 Not Reported 39 49.5. 2. 115 Not Reported 39 760. 2. 115

42 Not Reported 10 068. 3. 302 Not Reported 10 209. 3. 302 Not Reported 10 560. 3. 302 Not Reported 11 112. 3. 302 Not Reported 11 .391. 3. 302

Not Reported 11 460. 3. 302 Not Reported 12 335. 3. 302 Not Reported 13 366. 3. 302 Not Reported 13 387. 3. 302 Not Reported 13 628. 3. 302

Not Reported 13 824. 3. 302

1\T * O 1 J Not Reported 14 340. 3. 302 Not Reported 14 428. 3. 302 Not Reported 14 453. 3. 302 Not Reported 14 861. 3. 302

Not Reported 15 068. 3. 302 Not Reported 15 253. 3. 302 Not Reported 15 570. 3. 302 Not Reported 15 684. 3. 302 Not Reported 15 890. 3. ,302

Not Reported 16 .344. 3. 302 Not Reported 16 483. 3. 302 Not Reported 16 613. 3. 302 Not Reported 16 803. 3. 302 Not Reported 17 152. 3. 302

Not Reported 19 322. 3. 302 Not Reported 19 854. 3. 302 Not Reported 20 728. 3. 302 Not Reported 20 990. 3. 302 Not Reported 22 725. 3. 302

Not Reported 23 207. 3. 302 Not Reported 23 571. 3. 302 Not Reported 23 694. 3. 302 Not Reported 24 152. 3. 302 Not Reported 24 204. 3. 302

Not Reported 24 545. 3. 302 Not Reported 24 778. 3. 302 Not Reported 25 040. 3. 302 Not Reported 25 235. 3. 302 Not Reported 25 560. 3. 302

7
Hydrogen Peroxide Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Ace. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

42 Not Reported 25 680. 3. 302

l\ot rteporteu 26 016. 3. 302 Not Reported 26 549. 3. 302 Not Reported 26 821. 3. 302 Not Reported 27 005. 3. 302

Not Reported 27 141. 3. 302

i>ot ixeporieu 97 1 Li loZ. 0. 3 AO Not Reported 27 282. 3. 302 Not Reported 27 645. 3. 302 Not Reported 27 681. 3. 302

Not Reported 27 830. 3. 302 Not Reported / ( oOo. q

0. Not Reported 27 899. 3. 302 Not Reported 28 105. 3. 302 Not Reported 28 373. 3. 302

Not Reported 28 694. 3. 302 Not Reported 00 "700 Q

0. oOz Not Reported 28 802. 3. 302 Not Reported 29 017. 3. 302 Not Reported 29 136. 3. 302

Not Reported 29 453. 3. 302 Not Reported on 7C0 oUZ Not Reported 29 962. 3. 302

1 Not Reported 29 984. 3. 302

i Not Reported 30 134. 3. 302

Not Reported 30 511. 3. 302

\ Not Reported D

0. oUz Not Reported 30 791. 3. 302 Not Reported 30 878. 3. 302 Not Reported 31 162. 3. 302

Not Reported 31 181. 3. 302 Not Reported Q

0. OUZ Not Reported 32 234. 3. 302 Not Reported 32 280. 3. 302 Not Reported 32 708. 3. 302

Not Reported 32 975. 3. 302

INot Keported o4 o4o. Q0. 9 AO aUz Not Reported 34 540. 3. 302 Not Reported 34 583. 3. 302 Not Reported 34 709. 3. 302

Not Reported 34 785. 1 3. 1 302 Not Reported 00 Uzo. j 0. 1 300 oUz Not Reported 35 466. 3. 302 Not Reported 35 515. 3. 302 Not Reported 35 560. 3. 302

Not Reported 35 732. 1 3. j 302 Not Reported 35 975. 3. 302 Not Reported 1 36 032. 3. 302 Not Reported 1

! 36 105. 3. 302 Not Reported 1 i 36 162. 3. 302

8
Hydrogen Peroxide Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Kotor

State n HypfF'

•rfinc

F, F

Frequency

MHz

Ace. ±MHz

Kef.

42 Not IH7lf'.7I rs i-' ( II > rtI V I i 36 268. 3. 302 Not Reported 36 482. 3. 302 Not Reported 37 076. 3. 302 Not Re ported 37 582. 3. 302 Not W R t w trt <^ri 38 132. 3. 302

Not Reported 38 304. 3. 302 Not Reported .38 752. 3. 302 Not Reported 38 799. 3. 302 Not Reported 39 659. 3. 302 HDOf 43 1, <— 1, 14 .503. 3. 302

2, 13 032. 3. 302

10 836. 3. 302

5, , ^ 5, , 37 526. 3. 302

6, . ^ 6, , 37 096. 3. 302

7, , 7, , 36 575. 3. 302

8, , ^ 8, , 10 336. 3. 302

8, . ^ 8, , 35 992. 3. 302

9. , ^ 9, , 16 382. 3. 302

9, 9, 35 332. 3. 302

10, •^10, 22 928. 3. 302

10 *—10, 34 598. 3. 302 U, ! ^u. I 29 923. 3. 302

11, , ^11. , 33 790. 3. 302

11 *-~ll. 33 791. 3. 302

12, <—12, 32 915. 3. 302

12, 32 917. 3. 302

12^

,' ^12,' [ 37 313. 3. 302

13, , ^13, , 31 952. 3. 302

13 <—13, 31 956. 3. 302

14, <—14, 30 921. 3. 302

14'

' ^14^ 30 928. 3. 302

15'

' ^15" ] 29 818. 3. 302

15, , ^15, , 29 830. 3. 302

16, , •<-16, , 28 631. 3. 302

16, , ^16, , 28 651. 3. 302

17, , ^17, , 27 375. 3. 302

17, , ^17, , 27 406. 3. 302

18, , «-18, , 26 036. 3. 302

18, , ^18. , 26 084. 3. 302

19, , ^19, , 24 624. 3. 302

19, , ^19, , 24 707. 3. 302

20, , ^20, , 23 130. 3. 302

20, , ^20, , 23 252. 3. 302

21, , ^21, , 21 553. 3. 302

21, , ^21. , 21 730. 3. 302

9
50 - Hydrazine

H4N2

Molecular Constant Table

C2(C,.C,

Isotopic Species Pt. Id. A (MHz) B (MHz) C(MHz) D., D.,K K A

Gp. No.

H^N'-'N'-'H^ C, 51 59 660. M .0278 .059

Id. No. Debye /u,i, Debye /J,;. Debye eQq V, Acc. I red OJa d 6l>|, d aJ^. d W(| d

51 0. X 1.75 M 0. X ^.09 1100 50

References: ABC: 346

ix: 346

Add. Ref.: 241

D,; 346 eQq: 346

D.,k: 346

V: 346

Inversion barrier height = 2800 ± 150, cal/mol. Calculated rotational constants: Af+ Bp = 481.56.5 ± .5 MHz, C(,= 119360±50 MHz.

Ref: 346.

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos.' State n F' F MHz ±MHz

HaN'-iN^H^ 51 1, 1^ 2, 0 Ground E 0 2 3 15 058.60 .05 346

1, 1^ 2, 0 Ground E 0 1 2 15 059.51 .05 346

1, 1^ 2, 0 (Ground E 0 2 3 15 060.23 .05 346

1, 1^ 2, 0 (jround E 0 3 4 15 061.12 .05 346

1, 1^ 2, 0 Ground E 0 1 2 15 061.94 .05 346

1. 1^ 2, 0 Ground E 0 1 1 15 062.65 .05 346

1, 1^ 2, 0 Ground E 0 1 0 15 063.45 .05 346

1, 1^ 2, 0 Ground E 0 2 3 15 064.36 .05 346

1, 1<- 2. 0 Ground E 0 1 2 15 065.06 .05 346

1. 1*- 2. 0 Ground E 0 2 3 15 066.02 .05 346

1, 1*- 2, 0 (Ground E 0 3 4 15 066.95 .05 346

1. 1<- 2, 0 Ground E 0 1 2 15 067.55 .05 346

1. 1^ 2. 0 (i round E 0 1 1 15 068.17 .05 346

1. 1^ 2, 0 Ground E 0 1 0 15 069.35 .05 346

1, 1^ 2. 0 Ground A 0 15 091.2 346

1, 1^ 2, 0 Ground A 0 15 102.4 346

1, 1^ 2. 0 Ground 15 109.6 .05 346

1, 1^ 2, 0 Ground A 0 31 064.3 346

1, 1^ 2, 0 Ground 31 070.3 .05 346

1, 1^ 2, 0 Ground E 0 1 2 31 071.44 .05 346

1, 1*- 2. 0 Ground E 0 2 3 31 072.25 .05 346

1, 1^ 2, 0 Ground E 0 3 4 31 073.21 .05 346

1, 1^ 2, 0

' Ground E 0 1 2 31 073.95 .05 346

1. 1^ 2, 0 Ground E 0 1 1 31 074.45 .05 346

1, 1- 2, 0 Ground A 0 31 075.5 346

' Rotational quantum numbers have been entered as ipven in reference, although hydrazine is not a symmetric top.

10
Hydrazine Spectral Line Table

Isotopic Species TrI 1\U la L It' 1 1 dl Vil) Staff Hyperfine /Vcc. Hcl'. Nn Qu3,ntum Nos. Staff n F' F MHz _IVi 11 £,

HaN'^N'-'Ha 51 1, 1^ 2, 0 Ground K 0 2 31 077.12 .05 346

1, 1<- 2, 0 Ground E 0 2 3 31 077.85 .05 346

1. 1^ 2, 0 Ground E 0 3 4 31 078.95 .05 346

1. 1^ 2, 0 Ground E 0 1 2 31 079..52 .05 346

1. 1^ 2, 0 Ground E 0 1 1 31 080.20 .05 346

3, 0-^ 2, 1 (Ground E 0 4 4 17 072.48 .05 346

3, 0<— 2, 1 Ground E 0 4 3 17 073.08 .05 346

3, 0^ 2, 1 Ground E 0 5 4 17 073.60 .05 346

3, 0^ 2. 1 Ground E 0 3 2 17 074.14 .05 346

3. 0^ 2. 1 Ground E 0 1 1 17 074.48 .05 346

3, 0^ 2, 1 Ground E 0 3 3 17 07.5.10 .05 346

3, 0<— 2, 1 Ground E 0 3 2

1 1 nnc OA 17 U/o.o4 AC .05

3, 0^ 2, 1 Ground E 0 4 4 17 078.11 .05 346

3, 0^ 2. 1 Ground E 0 4 3 17 078.78 .05 346

3. 0<- 2. 1 Ground E 0 5 4 17 079.35 .05 346

3, 0^ 2, 1 Ground E 0 3 2 17 079.81 .05 346

3, 0<— 2, 1 Ground E 0 1 1

1 "7 AOA 1 A

17 OoO.lU AC o4o

3. 0<- 2, 1 Ground E 0 3 3 17 080.85 .05 346

3. 0^ 2. 1 Ground E 0 3 2 17 081.33 .05 346

3, 0^ 2, 1 Ground 17 086.3 .05 346

3. 0^ 2, 1 Ground A 0 17 092.7 346

3, 0^ 2, 1 Ground A 0 17 104.1 346

3, 0<— 2, 1 («rnll nn 33 033 0 .05 346

3^ 0<— 2, 1 Ground A 0 33 054.2 346

3' 0<— 2, 1 Ground A 0 33 065.4 346

3, 0^ 2, 1 Ground E 0 4 4 33 077.98 .05 346

3, 0^ 2, 1 Ground E 0 4 3 33 078.78 .05 346

3, 0^ 2. 1 Ground E 0 5 4 33 079.36 .05 346

3, 0^ 2. 1 Ground E 0 3 2 33 079.80 .05 346

3, 0^ 2. 1 Ground E 0 1 1 33 080.14 .05 346

3, 0^ 2, 1 Ground E 0 3 3 33 080.78 .05 346

3, 0<— 2, 1 Ground E 0 3 2 33 081.36 .05 346

3, 0^ 2, 1 Ground E 0 4 4 33 083.82 .05 346

3, 0^ 2, 1 Ground E 0 4 3 33 084.28 .05 346

3, 0*- 2. 1 Ground E 0 5 4 33 084.90 .05 346

3, 0^ 2, 1 Ground E 0 3 2 33 085.52 .05 346

3, O'^ 2, 1 Ground I? A E 0 1 1 33 085.78 .05 346

3, 0^ 2, 1 Ground E 0 3 3 33 086.44 .05 346

3, 0-^ 2, 1 Ground E 0 3 2 33 087.04 .05 346

6, 2^ 7, 1 Ground A 0 12 946.7 346

6, 2^ 7. I Ground A 0 12 958.1 346

6, 2^^ 7, 1 Ground 13 113.3 .05 346

6, 2^ 7, 1 Ground A 0 13 279.8 346

6, 2^ 7, 1 Ground A 0 13 291.3 346

6, 2^ 7, 1 Ground A 0 28 844.2 346

6, 2^ 7, 1 Ground A 0 28 855.4 346

6, 2-^ 7, 1 Ground 29 053.6 .05 346

6, 2-^ 7, 1 Ground A 0 29 240.3 346

6, 2<- 7, 1 Ground A 0 29 251.8 346

8, 1^ 7, 2 Ground A 0 18 831.1 346

11
Hydrazine

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

51 8. 1*- 7. 2 (Ground A 0 18 842.2 346

8. l'^ 7, 2 (Ground 19 086.1 .05 346

8, 1^ 7, 2 Ground A 0 19 341.1 346

8, 1^ 7, 2 Ground A 0 19 3.52.5 346

8. 1^ 7. 2 (iroinid A 0 34 778.6 346

8. 1*- 7, 2 Ground A 0 34 790.4 346

8. ]«— 7. 2 Ground 35 004.7 .05 346

8. 1^ 7. 2 Ground A 0 35 207.8 346

8, 1^ 7. 2 Ground A 0 35 219.0 346

9. 1^ 8. 2 Ground A 0 66 902.0 .05 346

9, 1^ 8, 2 Ground A 0 67 .540.1 .05 346

11, 3*—12, 2 Urouno A 0 11 351.4 346

11, 3^12, 2 (Ground A 0 11 363.0 346

11, 3^12. 2 Ground A 0 26 883.9 346

11, 3^12, 2 Ground A 0 26 895.4 346

II, 3^12. 2 Ground A 0 26 934.0 346

11. 3*-12, 2 Ground A 0 26 945.4 346

13, 2*-I2, 3 (iround A 0 21 1.53.6 346

13, 2^12, 3 Ground A () 21 165.4 346

13, 2^12, 3 Ground A () 21 221.7 346

13, 2<-I2. 3 (Ground A 0 21 233.4 346

13, 2^12. 3 (Ground A 0 36 647.1 346

13, 2*-12, 3 Grou nd A 0 36 658.7 346

13. 2^12, 3 (rround A 0 36 717.4 346

13, 2<-I2. 3 (iround A 0 36 729.0 346

Not Reported 4 764.0 218 Not Reported 4 879.4 218 Not Reported 5 386.0 218 Not Reported 5 562.53 218 Not Reported 5 568.98 218

Not Reported 5 992. 218 Not Reported 6 144. 218 Not Reported 6 498.3 218 Not Reported 6 575.71 218 Not Reported 6 .588.6 218

Not Reported 6 759.91 218 Not Reported 7 444.9 218 Not Reported 7 977.76 218 Not Reported 8 134.63 218 Not Reported 8 147.09 218

Not Reported 8 270.73 218 Not Reported 8 273.57 218 Not Reported 8 478.7 218 Not Reported 8 824.0 218 Not Reported 9 227.5 218

Not Reported 9 543.51 218 Not Reported 9 555.23 218 Not Reported 9 689.62 218 Not Reported 9 689.72 218 Not Reported 9 689.80 218

12
Hydrazine Spectral Line Table

Isotopic Species

H,N>^N»H,

Id. No.

51

Rotational Quantum Nos.

Not Reported Not Reported Not Reported Not Reported

Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported

Not Reported

Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported

Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported

Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported

Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Vib. State Int. Rotor

State n Hyperfine

F,' F' F F

Frequency

MHz

Ace. ±MHz

9 697..59 11 351.2

11 351.56

11 388.0

11 390.0

11 406.2

11 413.67

12 424.12

12 772.8

13 151.3

13 191.71 13 192.5

13 193.29

13 194.13

13 279.22

13 280.02

13 422.6

13 542.53

13 .557.30 13 632.40

13 988.41

14 065.4

14 441.59

14 475.4

14 556.31

14 570.8

14 687.29

14 700.4

14 900.5

15 099.30

15 099.86

15 100.72

15 101.32

15 103.40

15 104.37

15 892.15

15 921.66

16 045.67

16 286.4

16 313.92

16 376.94

16 698.20

16 767.90

17 071.6

17 077.2

17 092.35

17 103.84

17 105.42

17 125.84

17 326.69

13
Hydrazine Spectral Line Table

Isotypic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n Fi' F' F MHz ±MHz

51 Not Reported 17 332.72 218 Not Reported 1 "7 ICll "71 Ol o Not Reported 17 865.95 218

iNOt Keported 18 086.02 218

Not Reported 18 118.9 218

Not Reported 18 663.70 218 Not Reported 1 o i^on Q

1

lo DO 1 .61 Ol Q Not Reported 18 691.44 218 Not Reported 18 781.43 218 Not Reported 18 824.0 218

Not Reported 18 830.96 218 Not Reported 1 O CiA A 1 /I Not Reported 19 088.39 218 Not Reported 19 118.8 218 Not Reported 19 125.6 218

Not Reported 19 126.2 218 Not Reported ly izo.vo 91 Q zlo Not Reported 19 127.65 218 Not Reported 19 128.86 218 Not Reported 19 129.54 218

Not Reported 19 129.88 218 Not Reported Ol 0 Zlo Not Reported 19 353.0 218 Not Reported 19 488.29 218 Not Reported

j 19 502.92 218

Not Reported ! 19 559.0 218

Not Reported iV DDI.

4

Ol Q Zlo Not Reported 19 672.93 218 Not Reported 19 804.8 218 Not Reported 19 806.06 218

Not Reported 19 874.46 218 Not Reported 1 Q Q7c: A/1 91 0 Zlo Not Reported 19 945.6 218 Not Reported 20 073.28 218 Not Reported 20 073.78 218

Not Reported 20 414.9 218 Not Reported on 707 m Zlo Not Reported 20 950.65 218 Not Reported 21 107.10 218 Not Reported 21 110.25 218

Not Reported 21 127.0 218 Not Reported Zi ZOO.4'0 Zlo 91 Q Not Reported 21 239.52 218 Not Reported 21 .527.14 218 Not Reported 21 661.71 218

Not Reported 22 235.35 218 Not Reported ZZ99 d.1 ^ ^ 'I'lO.o Zlo 91 ft Not Reported 22 516.50 218 Not Reported 22 766.98 218 Not Reported 22 779.30 218

14
Hydrazine Spectral Line Table

Isotopic Species Id. No.

H,N'^N'^H2 51

Rotational Quantum Nos.

Vib. State

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

i "( LI I IVt IJwl u Not Re ported Not Reported Not Reported

i^lOl ivcp'-.'iicii

TMnt Rpnr»rtf>fi

l\Ir»t i'lOl R(=»nf^rtPM H.CJJ'JI icu Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported Ground

Not Rpnnrtpn Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

INIiit RRn^irtpn Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Not Reported Ground

Int. Rotor

State n Hyperfine

f; I f' I f, if

Frequency

MHz

Acc. ±MHz

Ref.

22 839.43 218

22 839.91 218

22 902.87 218

23 119.2 218

23 130.70 218

23 131.19 218

23 230.27 218

23 771.02 218

24 120.0 218

24 285.79 218

24 286.23 218

24 377.18 218

24 824.59 218

24 923.34 218

24 935.41 218

25 078.38 218

25 201.35 218

25 213.53 218

26 162.06 218

26 346.36 218

26 605.60 218

26 872.2 218

26 874.2 218

26 937.28 218 26 950.5 218

26 992.83 218

26 995.23 218

27 027.4 218

27 088.7 218

28 002.87 218

28 025.6 218

28 207.9 218

28 218.66 218

28 222.08 218

28 830.5 218

28 855.75 218

28 933.1 218

29 010.24 218

29 011.74 218

9Q 01OiZ,.9 7^to 218

29 199.6 218

29 251.64 218

29 252.01 218

29 491.6 218

15
60 - Trifluoromethyl Sulfur Pentafluoride Molecular Constant Table CFsS Cs(C3v.C4v) CF3SF5

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D,, DjK K A

C'Ti^S^'Tl" c. 61 1 097.6 M 1 097.6 M

Id. No. Debye fji„ Debye /Xj. Debye eQq Acc. Iiftt OJa d ojii d oji- d ojd d

61 220

References: ABC: 55 Dj: D.,k: k: A:

H: eQq: V: 55 I: a>:

Torsional frequency=93.5± 25 cm-'. V,, = 219 ± 120 cm"'. Ref: 55.

No Spectral Lines

16
70-Formic Arid Molecular (^onslanl 'I'ahie Methanoic Acid CH2O2 C,(C„Q liCOOH

Isotopic Species Pt. Op.Id.

IVT - A (MHz) B(MHz) C(MHz) D., D.,K K A

HL'-'O 0 H 71 77 520.07 M 12 054.98 M 10 416.16 M .00928 —.0830 .12X3

I T 1 9 f\ 1 fi/*\ 1 fi ri 72 66 110. M 11 762.55 M 9 970.05 M .01042 Acre

r)/-12Q16Q!6lJ Cs 73 57 710. M 12 055.80 M 9 955.71 M .00845 -.0366 DC'-0"*0"'D Cs 74 50 815. M 11 759.80 M 9 .534.15 M .00837 -.0309 HC"0"'0"*H Cs 75 12 053.7 M 10 378.9 M

HC'20'«0"'H 76 76 .521. M 11 396.91 M 9 904.76 M

HC'-0"=0'«H c. 77 77 206. M 11 383..58 M 9 906.06 M

Id. No. /j-a Debye Debye /X,. Debye eQq V, Acc. Iieil COa d CO,, d aj(. d w„ d

71 1.391 M 0.26 M 0. X 17000

72 1.377 M 0.22 M 0. X

75 1.415 T

References: ABC: 179, 199, 235, 291. 305 D,: 305 Djk: 305 k: A: 235

ti.: 235. 347 eQq: V: 179 I: co:

Add. Refs.: 31, 46, 87, 110, 131, 156, 157

For species 71, the centrifugal distortion is : Dk= 3.12 MHz. Ref: 305. Its torsional frequency= 667± 41 cm '. Ref: 179. The centrifugal distortion for species 72 is: Dk= 1.77 MHz; for species 73 is: Dk= 1.21 MHz; and for species 74 is Dk= .75 MHz. Ref: 305.

17
Formic Acid

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Ace. Ref. No. Quantum Nos State n f;* 1 F' F, F MHz ±MHz

HC'^0"'0"^H 71 1 0, 0, 0. 0 22 471.22 .1 210

J 1_ 1<— 2, 0, 2 20 543.96 235 i 0! 2^ 1" 0, 1 44 911.68 .28 199

2, 1, 1^ 1. 1. 0 46 581.22 .29 199

2, 1^ 2<— 1 43 303.62 .27 199

3, 0, 2, 0, 2 67 291.05 .41 199

3. 1, 2<— 2. 1,' 1 69 8.52.03 .42 199

3. \. 3^ 2! I. 2 64 936.26 .40 199

3. 2, 1^ 2. 2, 0 67 536.09 .41 199

3. 2. 2<— 2. 2. 1 67 414.80 .41 199

3. 1. 2^ 3. 1, 3 9 831.98 235

4, 0, 4^ 3. 0, 3 89 579.18 .53 199

4. 0, 4^ 3. 1, 3 28 086.39 235

4, 1. 3^ 3. 1, 2 93 098.46 .56 199

4. 1, 4^ 3. 1. 3 86 545.92 .52 199

4. 2. 2^ 3. 2. 1 90 164.52 .54 199

4, 2. 3^ 3. 2. 2 1 89 861.52 .54 199

4, 3, 1^ 3. 3. 0 89 950.34 ..54 199

4. 3, 2^ 3, 3, 1 89 948.32 .54 199

4, 1, 3^ 4. 1, 4 16 382.2 200

5. 0. 5^ 4, 0, 4 111 746.65 .68 199

1, 4^ 4. 1. 3 116 311.35 .70 199

5"

1. 5^ 4" h 4 108 127.00 .65 199

5, 2, 3^ 4. 2. 2 112 891.75 .68 199

5 2^ 4<— 4_ 2, 3 112 287.29 .68 199

5 3, 2<— 4, 3, 1 112 467.04 .68 199

5 3 4 3 2 112 4.59.70 .68 199

5. 4! 1^ 4!

4' 0 112 432.60 .68 199

5. 4, 4. 4. 1 1 112 432.60 .68 199

5 1^ 4^ 5 1^ 5 24 568.99 .03 200

6. 0. 6<— 5. 0. 5 133 767.06 .81 199

6. j_ 5<— 5 4 139 481.70 .84 199

6. 1. 6«- 5. 1! 5 129 671.70 .78 199

6. 2, 4^ 5. 2, 3 135 737.70 .82 199

6. 2. 5.^ 5, 2, 4 134 686.20 .82 199

6, 3, 3.^ •5, 3. 2 135 004.74 .82 199

6. 3. 4^^ 5. 3! 3 134 985.36 .82 199

6^ 4^ 2^ 5. 4"

1 134 938.26 .82 199

6. 4. 3^ 5, 4, 2 134 938.26 .82 199

6. 5, 1^ 5. 5, 0 134 920.32 .82 199

6, 5, 2<— 5, 5, 1 134 920.32 .82 199

6. 1. s<— 6^ 1^ 6 34 378.86 235

7, 0. 7^ 6'

0, 6 155 617.9 210

7, 1. 6^ 6. 1, 5 162 598.4 210

7, 1. 7*- 6, 1, 6 151 176.1 I 210

7. 2. 5^ 6. 2. 4 1.58 721.0 .1 210

7. 2. 6^ 6, 2, 5 157 054.0 210

7, 3. 4*- 6, 3, 3 157 570.6 210

7. 3. 5^ 6. 3, 4 157 526.1 210

7, 4. 3«- 6. 4. 2 157 455.2 210

18
Formic Acid Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F,' F' E' 1 F MHz ±MHz

HC>20'«0"'H 71 7, 4, 4<— 6, 4, 3 157 455.2 .1 210

7. 5, <— 6, 5, 157 422.7 210

7. 6" ^ 6^ 6^ 157 412.9 ;} 210

7, 1, 6^ 7, 1, 7 45 801.13 235

8. 0, 8^ 7, 0, 7 177 283.0 1 210

8, 1, 7<- 7, 1, 6 185 650.3 .1 210

8, 1, 8^ 7, 1, 7 172 636.7 210

8, 2, 6^ 7, 2, 5 181 850.2 ;} 210

8, 2, 7<— 7, 2, 6 179 384.6 I 210

8, 3, 5^ 7, 3, 4 180 171.4 1 210

8. 3, 6^ 7, 3, 5 180 083.0 1 210

8, 4, 4^ 7, 4, 3 1 /y yoo.3 210

8, 4, 5^ 7, 4. 4 179 984.1 ;J 210

8, 5, <— 7, 5, 179 932.2 .1 210

8, 1, 7^ 8, 1, 8 58 815.46 235

9, 0. 9^ 8, 0, 8 198 755.7 1 210

9, 2, 7^ 8, 2. 6 205 127.9 210

9, 2, 8^ 8, 2. 7 201 673.6 ;j 210

9, 3, 6<— 8, 3, 5 202 815.4 1 210

9, 3, 7<- 8, 3, 6 202 654.0 I 210

9, 4, 8, 4, 4 202 530.0 .1 210

9^ 4' 6^ 8^ 4' 5 202 527.3 210

9. S, 4-^ 8^ 5. 3 202 449.9 ;} 210

9, 5. 5^ 8, 5, 4 202 449.9 I 210

9, 6, ^ 8, 6, 202 418.2 i 210

9, 7, 8, 7, 202 409.6 .1 210

9, 8, ^ 8, 8, 202 413.8 210

9, 2, 7-^ 9, 2, 8 9 696.83 235

11, 2, 9«-ll, 2,10 20 297.88 235

12, 2,10-^12, 2,11 27 758.05 235

13, 2,11^13, 2,12 36 830. 235

16, 3,13^16, 3,14 8 968.50 235

18, 3,15^18, 3,16 17 286. 235

19, 3,16-^19, 3,17 23 203.41 235

20, 3,17-^20, 3,18 30 523.12 235

24, 4,20^24, 4.21 9 410. 235

27, 4,23^27, 4,24 22 326.42 235

28, 4,24^28, 4,25 28 935. 235

29, 4,25^29, 4,26 36 915. 235

32, 5,27*-32, 5,28 8 662. 235

33, 5,28^33, 5,29 11 512. 235 Not Reported 16 989. 5. 67 Not Reported 24 595. 5. 67 Not Reported 25 218. 5. 67 Not Reported 26 342. 5. 67

HC'20"*0"=D 72 1, 0, 1^ 0, 0, 0 Ground 21 732.72 .10 100

2, 0, 2^ 1, 0, 1 Ground 43 421.36 .20 100

2, 1, 1^ 1, 1, 0 Ground 45 257.40 .20 100

2, 1, 2^ 1, 1, 1 Ground 41 672.98 .20 100

5, 1, 5^ 5, 1, 4 Ground 26 865.5 .3 179

19
Formic Acid Spectral Line Table

Isotopic Species Id. 1 Rotational Vib. State Int. Rotor Hyperf ine Frequency Acc. Ref. No. t Quantum Nos State n F' F MHz ±MHz 1

1 _[

HC'^0"^0"'D 72 7. 0. 7*- 6. 0. 6 ! Ground 149 753.66

1 •2 305

7. 1. 6^ 6. 1. •J [ 0rou n d 1 S7 770 81 •2 305

7. 1, 7^ 6. 1, 6 Ground 1 145 312.14 2 1 305

7( , •J* 0, 4 Ground 154 137.58 •2 305

7, 2. 6^ 6. 2. •5 Ground 151 778.74 •2 1 305

7. 3. 4^ 6. 3. 3 Ground 152 526.01 •2 305

7. 3. 5^ 6. 3, d. Grou nd 1 S'? 44.'? Rfl 2 1 7, 4. 3^ 6. 4, 2 \ Ground 152 344.38 •2 305

7, 4, 4^ 6. 4. J 1 Ground .2 .JOl) 7, 5. 6, 5, Ground 152 288.87 .2 305

7. 6. 6. 6. (iround 152 264.95 •2 305

DC'-0"'0"'H 73 1, 0, 0. 0. 0 Ground 22 011.3 i -3 179

2. 1, 1^ 1. 1. 0 yjl U Lii 1 LI 46 122 6 .6 179

2, 1, 1. 1. 1 Ground 1 41 923.0 .6 ! 179

/I 11 . 1 3 Ground 20 989.6 3 1 179

7. 0. 7^ 6. 0. 6 ! Ground 150 345.06 •2 1 305

7, 1. 6^ 6, 1. 5 ! Ground 160 392.07 2 305

7. 1, 7^ 6, 1. Ground 145 88? .2 305

7. 2, .5^ 6. 2. 4 Ground 1 157 241.48 .2 1 305

-7/,

/;0. o

z. 5 1 Ground 153 521.68 2 305

7, 3. 4*- 6. 3. 3 (jround 154 757.18 2 305

7, 3, 5«- 6. 3. 4 ! Ground 154 571.17 2 305

7. 4. 2^ 6. 4. 9 Ground •2 305

7. 4, 4^ 6. 4. 3 1 Ground 1 154 427.84 2 i 305

•7/, rD, O.

rJ. Ground 154 332.94 2 305

- 7, 6, 6. 6. Ground 154 285.66 2 305

DC'=0"'0"'D 74 1 1. 0, 0. 0. 0 1 Ground 21 293.9 .3 1 179

2. 1, 1^ 1, 1. i\u 1 Ground 44 813.4 .6 179

4. 1. 4^ 4. 1. 3 Ground 1 22 237.5 .3 1 179

0, A

u. o. 5 Ground 124 685.34 •2 305

6. 1. 5^ 5. 1, 4 Ground 133 623.69 •2 305

6. 1. 6^ 5. 1, 5 Ground 1 120 407.60 .2 305'

A ^ cr ->. o Gr(.)und 130 411.85 •2 305

6. 2. 5^ 5. 2. 4 (iround 1 127 342.80 .2 305

6. 3, 3^ 5. 3. 2 (»round 128 336.34 •2 305

0. Q

o. 5. QO. 3 Ground 128 203.04 2 1 305

6, 4, 2^ 5. 4, 1 Ground 1

1 128 077.64 2 1 305

6. 4. 3^ 5. 4. 2 Ground 128 075.90 •2 305

6. 5. 5, 5, Cjround 127 996.80 .2 305

HC"0"'0"*H 75 1 1, 0. 0. U. 0

' Ground

1

i 22 432.6 .3 [ 179

2, 1. 1. 1. 1 (iround 43 190.4 .6 I 179

HC'=0'«0"'H 76 1, 0. 0, 0. 0 ! Ground 1 21 301.67 •1 291

2, 1. 1^ 1. 1, u 1 Ground 44 095.5 9Q1

4. 1. 4^ 4. 1, 3 Ground 14 919.20 •1 i 291

5. 1. 5. 1. 4 Ground 22 372.49 •1 291

6. I. ()<- 6. 1. Ground 31 309.00 '1 291

HC'-0"^0'«H

! 77 1 1. 0. 1^ 0. 0, 0 round i 21 289.64 1 1 291

2, 1, 1^ 1, 1, 0 1 Ground 44 056.8 2 291

4, 1, 4^ 4. 1. 3 I Ground 14 773.56 1 1 291

5. 1. .5^ 5. L. 4 Ground 22 154.85 •1 291

6. 1. 6^ 6. 1. 5 Ground 1 31 003.73 .1 1 291

' Mirri's report of a bee-*— 5|5 transition ior DCOOD obviously involves a typoja-aphical error: the transition has been entered as 6|(i<— 5ir,.

20
80 - MetliyldifluDroarsine Molecular Constant Table CHjAsF, C,(C3v,C,) CH^AsP^.,

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) D., K A

81 5 414.49 M 5 318.28 M 3 871.88 M -3.7 -.5.4.5

Id. No. /u-a Debye /j-i, Debye /u-t. Debye eOq V3 Acc. Irecl CUa d W|, d aj(. d d

81 2.88'. L 0. X -220 13.30

1. The value given was determined fnun benzene solutions, of the compound. qu<iled from McClellan's Tables of Experimental Dipole Mtjmenls.

References: ABC: 329 D,,: 329 Djk: 329 x: A:

/x: 364 eQq: 329 V: 344 I: w:

Centrifugal distortion (A-states): Dk = 2.82± .32 x IQ-^ MHz. Coupling parameter: !„= 3.210± .040 amu A^. Ref: 329.

749-587 0-69—

3

21
Methyldifluoroarsine Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum NosVib. State

1 i Int. Rotor | State n F/

rlyperfine

F' 1 F,

1 F

Frequency

MHz

1 Acc. ±MHz 1

Ref.

81 3, 0, 3*- 2. 0, 2 i Ground ! A 0 5/2 5/2 24 733.01 •2 1 329

3, 0. 3^ 2, 0. 9 1 Ground E 0 9/2 7/9 '/z 9/1 lA Q t^c: 9 1 .z 1 Q90 ozy

1 3, 0, 3^ 2, 0. 2 \ Ground A 0 9/2 7/2 24 750.91 2 i 329

1 3,

r\u. 2 Ground 1 17 Au y/2 7/2 24 752.13 2 329

O 0, 3^ 2, 0, 2 Ground 1 A 0 3/2 1/2 24 757.70 •2 329

3, 0, 3^ 2. 0, 2 1 Ground 1 E 0 7/2 5/2 24 761.98 •2 1 329

3, 0, 3^ 2, 0, 9 1 Ground A 0 7/2 of Z

9/1 7A/1 Q7 Z'i /0^.O( 9.z 1 3, 0, 3*- 2, 0, 2 Ground i E 0 7/2 5/2 24 766.40 .2 329

3, A

u. Z, U, 2 i Ground n. U

1^ /9 0/Z 3/2 24 769.26 •2 329

Q

•J. 0, 3^ 2, 0, 2 Ground A 0 5/2 3/2 24 771.88 .2 329

3. 0, 3^ 2. 0, 2 1 Ground 1 A 0 7/2 7/2 24 819.80 2 329

3, 1. 3^ 2. 1. 9 Ground A 0 I 5/2 0/

Z

Z'+ 9/1 7*^^ iOO.Vlm 9.Z 1 590 ozV

3. 1. 3^ 2, 1. 2 Ground 1 E 0 9/2 7/2 24 748.55 •2 i 329

3, 1, 3<— 2. 1. 2 Ground AA 0 1 9/2 7/2 24 750.91 .2 329

1, 3^ 2. 1. 2 Ground E 0 9/2 7/2 24 752.13 •2 [ 329

3, 1, 3^ 2. 1, 2 ! Ground A 0 3/2 1/2 24 757.70 •2 329

3, 1. 3^ 2. 1. 9z 1 Ground E 0 7/2 z4 /oi.yo 9.z 1 3 on OZV

3, 1, 3^ 2. 1. 2 Ground A 0 7/2 5/2 24 764.87 2 329

3.

11, 2. 1, 2 i Ground A

u 7/2 5/2 24 766.40 .2 329

O

1, 3^ 2. 1, 2 Ground E 0 5/2 3/2 24 769.26 •2 329

3, 1, 3^ 2, 1, 2 1 Ground 1 A 0 1 5/2 3/2 24 771.88 .2 329

3, 1, 3^ 2. 1, Z 1 Ground A 0 7/2 '/z 9/1 fti Q ftn Z^- OLV.oU 9.Z OZV

4, 0, 4^ 3. 0, 3 Ground 1 E 0 11/2 9/2 32 494.96 2 329

4, u. 4.<— J, U. 3 Ground A

1 u 1 LljZ 9/2 32 497.75 2 329

0, 4^ 3. 0. 3 Ground ! A 0 1 5/2 3/2 32 502.80 •2 329

4. 0. 4^ 3, 0, 3 1 Ground 1 A 0 1 9/2 7/2 32 506.10 2 329

4, 1, 4^ 3, 1, 1 Ground i E 0 11/2 Q/9 y/z '^9 AQA Of. 9.Z 1 OZV

4, 1. 4<- 3, 1, 3 Ground A 0 11/2 9/2 32 497.75 •2 329

4, 11

,

o. i. 3 Ground 1 AA C\ 1 u D/Z 3/2 32 502.80 •2 329

A

1. 4^ 3. 1, 3 Ground A 0 9/2 7/2 32 506.10 •2 329

7, 2, 5^ 7. 2. 6 1 Ground 1 A 0 17/2 17/2 16 797.27 .05 1 329

7, 2. 5^ 7. 2. D I Ground 1 A 0 11/2 1 1 /9 1iUf> 80'^ ouo.uof>8 .uo 1 •JZ 7

7, 3, 5^ 7, 1, 6 Ground A 0 17/2 17/2 16 797.27 .05 329

7, Q

' . 1, 6 Ground A AU 1 11/2 11/2 16 803.68 .05 1 329

•7

< , 3, 4^ 7, 3, 5 Ground A 0 17/2 17/2 13 741.67 .05 1 329

7, 3, 4^ 7, 3, 5 i Ground 1 A 0 1 11/21 11/2 13 747.12 .05 1 329

7. 4, 4^ 7. 2, 0 1 Ground 1 A 0 17/21 15 7/11 A7 oZV

7. 4, 4^ 7, 2. Ground 1 A 0 11/21 11/2 13 747.12 .05 1 329

8, 4, 4<— 8. 4. 5 Ground 1 A

1 A 0 1 19/2 19/2 13 737.52 .05 1 329

8. 4, 4-^ 8. 4. 5 Ground t A 0 13/2 13/2 13 741.32 .05 329

8, 5, 4<- 8, 3, 5 Ground A 0 1 19/21 19/2 13 737.52 .05 329

8, 5, 4^ 8, 3,

cO Ground A 0 13/21 1 Q /9 io/z -\ o 7/11 oo

.uo I 190

9, 4, 5^ 9, 4. 6 Ground A 0 21/21 21/2 16 788.91 .05 1 329

9, 4, 5^ 9, 4, 6 Ground A 0 15/21 15/2 16 792.16 .05 329

9. 5, 5^ 9, 3, 6 Ground 1 A 0 21/2 21/2 16 788.91 .05 329 ,

9, 5, 5^ 9, 3, 6 1 Ground 1 A 0 [ 15/21 15/2 16 792.16 .05 329

10, 4, 6^10, 4, Ground 1 E 0 1 17/2 17/2 19 839.13 .05 329

10, 4. 6^10. 4, Ground A 0 23/2 23/2 19 839.97 .05 1 329

10. 4, 6^10. 4, 7 Ground A 0 17/2 17/2 19 842.75 .05 1 329

10. 4, 6^10, 4, 7 Ground E 0 17/21 17/2 19 843.71 .05 329

22
Methyldinuoroarsine Spectral IJne Table

Isotopic Species Id. Rotational Vib. State

1 1 Int. Kotor [ Hyperfine Frequency Acc. Ref. No. Quantum Nos State n 1 f; F' F,

1 F MHz ±MHz

81 10, 5, 6^10, 3. 7 Ground I E 0 1 17/2 17/2 19 8.39.13 .05 329

10, 5, e'^io. 3, 7 1 Ground A 0 23/2 23/2 iv 839.97 .05 329

10, 5, 6^10, 3, Ground 1 A 0 i 17/2 17/2 19 842.75 .05 .329 10, 5, 6<—10, 3, 7 Ground E 0 1 17/2 17/2 19 843.71 .05 329

10, 5. 5^10. 5, 6 Ground i A 0 i 23/2 2.3/2 16 785.12 .05 329

10, 5, 5^10, 5, 6 1 Ground 1 A 0 1 17/2 17/2 16 787.50 .05 329

10, 6, 5-^10, 4, o 1 Ground A 0 23/2 23/2 to (OO.IZ OOA 329

10, 6, 5^10, 4, 6 1 Ground A 0 17/2 17/2 16 787.50 .05 329

10, 6, 4<—10, 6, 5 1 Ground A 0 23/2 23/2 13 728.97 .05 329

10. 6, 4^10. 6, 5 1 Ground A 0 1 17/2 17/2 13 730.97 .05 329

10, 7, 4^10. 5, 5 1 Ground 1 A 0 1 23/2 23/2 13 728.97 .05 329

10, 7, 4^10, 5, 0 1 Ground A 0 17/2 17/2 1 Q "7 9 0 0*7 AC .05 329

11, 5, 6^11, 5, Ground 1 E 0 19/2 19/2 19 8.34.67 .05 329

11, 5, 6<—11, 5, 7 Ground ! A 0 25/2 25/2 19 8.36.16 .05 329

11, 5, 6^11, 5, Ground A 0 19/2 no/0 19 8.38.21 .05 329

11, 5, 6<-ll, 5. 7 Ground 1 E 0 19/2 119/2 19 839.13 .05 329

11, 6, 6^11, 4, /

1 t^rounu 1 E 0 19/2 119/2 in o Q ,1 iv 004-.0/ oc .05 0 OA 329

11, 6, 6^11, 4, 7 Ground A 0 25/2 25/2 19 836.16 .05 329

11, 6, 6<—11, 4, 7 Ground 1 A 0 19/2 il9/2 19 8.38.21 .05 329

11, 6, 6*-ll, 4, 7 Ground E 0 19/2 19 8.39.13 .05 329

11, 6. 5^11. 6, 6 1 Ground 1 A 0 1 25/2 125/2 16 781.11 .05 329

11, 6, 5^11, 6, 6 1 Ground A 0 19/2 119/2 1 "70.") nc 16 /oz.vo .05 DOA 329

11, 7, 5«-ll, 5, 6 1 Ground A 0 25/2 25/2 16 781.11 .05 329

11, 7. 5«—11, 5. 6 1 Ground A 0 1 19/2 19/2 16 782.95 .05 329

11. 7. 4^11. 7, 5 1 Ground A 0 1 25/2 13 723.91 .05 329

11, 8, 4^11, 6, 5 1 Ground i A 0 1 25/2 125/2 13 723.91 .05 329

12, 6, 6-^12, 6, 7 ! Ground 1 A 0 27/2 27/2 ly 061.12. AC .05 OOA 329

12, 6, 6-^12, 6, 7 Ground 1 A 0 21/2 21/2 19 833.84 .05 329

12, 7, 6-«—12, 5, 7 Ground 1 A 0 27/2 27/2 19 832.22 .05 329

12, 7. 6^12. 5. 7 Ground 1 A 0 21/2 21/2 19 833.84 .05 329

12, 7, 5^12, 7, 6 Ground 1 E 0 1 27/2 127/2 16 773.67 .05 329

12, 7, 5-^12, 7, o [ Ground 1 E 0 21/2 21/2 1 A 77R no Id ( /o.uy Q9Q ozy

12, 7, 5'^12, 7, 6 Ground A 0 27/2 127/2 16 776.75 .05 329

12, 7, 5<—12, 7, 6 Ground E 0 27/2 27/2 16 777.84 .05 329

12, 7, 5^12, 7, 6 Ground A 0 21/2 21/2 16 778.19 .05 329

12, 7, 5^12, 7, 6 1 Ground E 0 \ 21/2 121/2 16 779.21 .05 329

12, 8, 5^12, 6, o I Ground E 0 1 27/2 27/2 1 A 77"2 A7 10 / (0.0/ ^90 ozy

12, 8, 5^12, 6, 6 Ground E 0 21/2 21/2 16 775.09 .05 329

12, o

o. b<—12, 0, 6 Ground A 0 27/2 27/2 16 776.75 .05 329

12, 8, 5'^12, 6, 6 Ground E 0 1 27/2 27/2 16 777.84 .05 329

12. 8. 5^12, 6, 6 1 Ground A 0 1 21/2 |21/2 16 778.19 .05 329

12, 8, 5^12, 6, 0 1 Irround E 0 21/2 21/2 1 770 9

10 / /y.zi .Uo

13, 7, 6*-13, 7, 7 1 Ground A 0 29/2 29/2 19 827.98 .05 329

13, 7, 6^13, 7, 7 1 Ground A 0 23/2 23/2 19 829.30 .05 329

13. 8. 6^13. 6, 7 Ground A 0 29/2 129/2 19 827.98 .05 329

13, 8. 6^13, 6. 7 1 Ground A 0 23/2 123/2 19 829.30 .05 329

13, 8, 5^13, 8, 6 Ground A 0 23/2 23/2 16 773.02 .05 329

13, 9, 5^13, 7. 6 Ground A 0 i 23/2 123/2 16 773.02 .05 329

14, 8. 6^14. 8. 7 Ground A 0 31/2 131/2 19 823.39 .05 329

I 14, 8, 6^14. 8, 7 Ground A 0 25/2 125/2 19 824.47 .05 329

I

23
Methyldifluoroarsine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

81 14, 9. 6^14. 7, 7 Ground A 0 31/2 31/2 19 823.39 .05 329

14, 9. O'^M, 7, 7 Ground 25/2 25/2 19 824.47 .05 329

15, 9, 6^15, 9, 7 Ground A 0 31/2 31/2 19 809.09 .05 329

15, 9, 6^15, 9, 7 Ground A 0 29/2 29/2 19 809.94 .05 329

15, 9, 6^15, 9, 7 Ground A 0 33/2 33/2 19 818.39 .05 329

15, 9, 6^15, 9, 7 Ground A 0 27/2 27/2 19 819.38 .05 329

15,10, D<— 15, o. 7 (jround A 0 31/2 31/2 19 809.09 .05 329

15,10, 6«-15, 8, 7 Ground A 0 29/2 29/2 19 809.94 .05 329

15,10, 6^15, 8, 7 Ground A 0 33/2 33/2 19 818.39 .05 329

15,10, 6^15, 8, 7 Ground A 0 27/2 27/2 19 819.38 .05 329

16,10, 6^16,10, 7 Ground A 0 33/2 33/2 19 804.60 .05 329

16,10. 6'^16.10, 7 Ground A 0 31/2 31/2 19 805.38 .05 329

16,10. 6^16,10, 7 Ground A 0 35/2 35/2 19 812.87 .05 329

16,10. 6^16,10, 7 Ground A 0 29/2 29/2 19 813.68 .05 329

16,11, 6^16, 9, 7 Ground A 0 33/2 33/2 19 804.60 .05 329

16,11, 6^16, 9, 7 Ground A 0 31/2 31/2 19 805.38 .05 329

16,11, 6'^16, 9, 7 Ground A 0 35/2 35/2 19 812.87 .05 329

16,11, 6^16, 9, 7 Ground A 0 29/2 29/2 19 813.68 .05 329

16,11, .5^16,11, 6 Ground A 0 33/2 33/2 16 745.69 .05 329

-

16,11, 5^16,11, 6 (iround A 0 31/2 31/2 16 746.44 .05 329

16.11. 5^16.11, 6 Ground A 0 35/2 35/2 16 753.14 .05 329

16.11. 5'^16,11, 6 Oround A 0 29/2 29/2 16 753.84 .05 329

16.12, 5^16,10, 6 (jround A 0 33/2 33/2 16 745.69 .05 329

16.12. 5^16,10, 6 Ground A 0 1 31/2 31/2 16 746.44 .05 329

16,12, 5^16,10, 6 Ground A 0 j 35/2 35/2 16 753.14 .05 329

- 16.12, 5^16,10, 6 Ground A 0 1 29/2 29/2 16 753.84 .05 329

16.12. 4'^16,12, 5 Ground A 0 [ 33/2 33/2 13 673.03 .05 329

16,12, 4^16,12, 5 (Jround A 0 1 31/2 31/2 13 673.74 .05 329

16.12. 4^16,12, 5 Ground E 0 133/2 33/2 13 677.04 .05 329

16,12, 4^16,12, 5 (Ground E 0 I 31/2 31/2 13 677.67 .05 329

16,12, 4^16,12, 5 (Ground A 0 i 35/2 35/2 13 679.95 .05 329

16,12, 4^^16,12, 5 (Ground A 0 I 29/2 29/2 13 680.63 .05 329

16,12, 4^16,12, 5 Ground E 0 1 35/2 35/2 13 683.88 .05 329

16,12, 4*-16,12, 5 Ground E 0 1 29/2 29/2 13 684.50 .05 329

16,13, 4^16,11, 5 Ground E 0 33/2 33/2 13 674.34 .05 329

16,13, 4^16,11, 5 Ground E 0 31/2 31/2 13 675.04 .05 329

16,13, 4^^16,11, 5 Ground A 0 1 33/2 33/2 1 O ^ "70 13 678.73 .05 329

16,13, 4^16,11, 5 Ground A 0 1 31/2 31/2 13 679.34 .05 329

16.13. 4^16.11, 5 Ground E 0 1 35/2 35/2 13 681.13 .05 329

16.13. 4^16,11, 5 Ground E 0 j 29/2 29/2 13 681.72 .05 329

16,13, 4^16,11, 5 (; round A 0 1 35/2 35/2 13 685.30 .05 329

16,13, 4<—16,11, 5 (Jround A 0 1 29/2 29/2 13 685.89 .05 329

17.11, 6^17,11, 7 Ground A 0 35/2 35/2 19 799.25 .05 329

17,11, 6^17,11. 7 round A 0 37/2 37/2 19 806.78 .05 329

17,11, 6^17,11, 7 Ground A 0 31/2 31/2 19 807.40 .05 329

17.12. 6^17.10. 7 Ground A 0 35/2 35/2 19 799.25 .05 329

17.12. 6^17,10, 7 Ground A 0 37/2 37/2 19 806.78 .05 329

17,12, 6^17,10, 7 (i round A 0 31/2 31/2 19 807.40 .05 329

17,12, 5^17.12, 6 Ground A 0 35/2 35/2 16 738.29 .05 329

17,12, 5^17,12, 6 Ground A 0 33/2 33/2 16 738.84 .05 329

24
Methyldifluoroarsine Spectral IJne Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State 1 Int. Rot

1 State

orn Hyperfine

F/ t F' 1 F, 1 F

p^retjuency

MHz

Acc. ±MHz 1Ref.

81 17.12, .5^17,12, 6 1 (iround E 0 35/2 35/2 16 7.39..50

j .05 1 329

17,12, 5^17,12, 6 1 Ground 1 E 0 33/2 33/2 16 740.00 .05 1 .329 17,12, 5'^17.12, 6 Ground E 0 37/2 37/2 16 742.70 .05 329

17,12. 5'^17.12. 6 1 Ground E 0 31/21 131/2 16 743.13 .05 329

17.12. .5'^17.12. 6 Gro u n d A 0 37/2 37/2 16 745.03 .05 329

17,12, 5-^17,12. 6 i Ground A 0 131/2 |31/2 16 745.69 .05 1 329

17,13, 5^17,11, 6 Ground A 0 [35/2| 135/2 16 738.29 .05 329

17,13, 5«-17,ll, 6 Ground A 0 33/21 133/2 16 738.84 .05 1 329

17,13, 5«-17,ll, 6 1 Ground E 0 135/2 35/2 16 739.50 .05 1 329

17,13, S'^n.ll. 6 ( >und E 0 33/2 33/2 16 740.00 .05 329

17.13. 5^17.11, 6 1 Ground 1 E 0 i37/2| 137/2 16 742.70 .05 329

17,13, 5^17,11, 6 Ground E 0 |31/2i 131/2 16 743.13 .05 329

17,13, 5^17,11, 6 Ground A 0 137/2

137/2 16 745.03 .05 329

17,13, 5^17,11, 6 Ground 1 A 0 131/2 [31/2 16 745.69 .05 329

17,13, 4'^17,13, 5 Ground A 0 135/2 35/2 13 658.73 .05 329

17,13, 4^17,13, 5 j Ground 1 A 0 i33/2| |33/2 13 659.24 .05 1 329

17,13, 4'^17,13, Ground E 0 |35/2 |35/2 13 663.71 .05 329

17,13. 4'^17.13. 5 Ground E 0 133/2 133/2 13 664.28 .05 I .329 17,13, 4^17,13, 5 Ground A 0 137/2 37/2 13 665.24 .05 329

17,13, 4^17,13, 5 Ground A 0 |31/2 31/2 13 665.81 .05 329

17,13, 4^17.13. 5 1 Ground ! E 0 1 |37/2| 137/2 13 670.12 .05 329

17,13, 4'^17.13. 5 Ground E 0 131/2 131/2 13 670.61 .05 329

17,14, 4'^17,12, 5 1 Ground E 0 !35/2| 135/2 13 662.75 .05 1 329

17,14, 4^17.12, 5 1 Ground E 0 33/2 33/2 13 663.27 .05 1 329

17,14, 4'^17.12. 5 Ground A 0 35/2 35/2 13 667.71 .05 i 329

17,14, 4^17,12, 5 1 Ground 1 A 0 i |33/2t [33/2 13 668.23 .05 329

17,14, 4^^17,12, Ground E 0 37/21 137/2 13 668.90 .05 329

17,14, 4^^17,12, 5 Ground E 0 31/21 131/2 13 669.39 .05 329

17,14, 4^^17,12, 5 Ground A 0 37/2| 37/2 13 673.74 .05 329

17,14, 4^17,12. 5 Ground A 0 1 131/21 31/2 13 674.34 .05 ! 329

18,13, 5^18.13. 6 1 Ground 1 E 0 137/2] 137/2 16 727.30 .05 329

18.13. 5^18,13. 6 Ground E 0 135/2 3.5/2 16 727.80 .05 329

1 18,13, 5^18,13, 6 Ground 1 E 0 |37/2| 37/2 16 730.71 .05 329

18,13, 5^18,13, 6 Ground E 0 35/2 35/2 16 731.22 .05 329

18.13, 5^18.13. 6 Ground E 0 39/2 39/2 16 733.47 .05 1 329

1 18,13, 5^18,13. 6 1 Ground E 0

133/21 133/2 16 733.96 .05 1 329

18,13, 5^18,13, 6 Ground E 0 39/2 39/2 16 736.85 .05 329

18,13, 5^18,13, 6 1 Ground E 0 33/2 33/2 16 737.38 .05 329

18,14. 5^18,12. 6 Ground E 0 37/2 37/2 16 727.30 .05 1 329

18.14. 5^18.12. 6 [ Ground j E 0 35/2 35/2 16 727.80 .05 329

1 18.14. 5^18.12. 6 1 Ground E 0 1 37/2 37/2 16 730.71 .05 329

18.14. 5^18,12, 6 Ground ! E 0 35/2 35/2 16 731.22 .05 329

18,14, .5^18,12, 6 Ground E 0 139/21 139/2 16 733.47 .05 329

18,14, 5^18.12. 6 1 Ground 1 E 0 1 33/2 133/2 16 733.96 .05 329

18,14, 5^18.12, 6 1 Ground E 0 1 139/21 39/2 16 736.85 .05 1 329

1 18,14. .5^18,12, 6 i Ground 1 E 0

133/21 133/2 16 737.38 .05 1 329

1 18,14. 4^18.14. 5 Ground A 0 37/2 137/2 13 641.15 .05 1 329

18,14, 4^18.14. 5 1 Ground A 0 135/21 35/2 13 641.60 .05 329

18.14. 4^18,14, 5 Ground 1 A 0 39/2 [39/2 13 647.31 .05 1 329

1 18,14. 4^18,14, 5 Ground I E 0 37/2 137/2 13 647.31 .05 1 329

25
Methyldifluoroarsine

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos

j

State n F' E* 1 F MHz ±MHz

81 18,14, 4^^18,14,

] 5 i Ground A 0 33/2 33/2 13 647.79 .05 329

18,14, 4^18,14, Ground E 0 35/2 35/2 13 647.79 .05 329 18J4^ 4^18*14^ 5 Ground E 0 39/2 39/2 13 653.49 .05 329

18,14, 4*-18,14, 5 Ground E 0 33/2 33/2 13 653.97 .05 329

18,15, 4'^18,13, 5 Ground E 0 37/2 37/2 13 649.58 .05 329

18,15, 4*-18,13, 5 ! Ground E 0 35/2 35/2 13 650.09 .05 329

18,15, 4^18,13, Ground A 0 37/2 37/2 13 655.27 .05 329 1845^ 4^18,13^ 5 Ground E 0 39/2 39/2 13 655.27 .05 329

18,15, 4<-18,13, 5 Ground A 0 35/2 35/2 13 655.68 .05 329

18,15, 4<-18,13, 5 Ground E 0 33/2 33/2 13 655.68 .05 329

18,15, 4'^18,13, 5 1 Ground A 0 .39/2 39/2 13 660.85 .05 329

18,15, 4*-18,13, Ground A 0 33/2 33/2 13 661.24 .05 329

19,14. 5^19,14, 6 Ground A 0 39/2 39/2 16 719.06 .05 329

19,14, 5'^19.14, 6 Ground A 0 37/2 37/2 16 719.53 .05 329

19.14. 5^19,14, 6 Ground E 0 39/2 39/2 16 720.59 .05 329

19,14, 5«-19,14, 6 1 Ground E 0 37/2 37/2 16 721.05 .05 329

19.14. 5^19,14, 6 Ground A 0 41/2 41/2 16 724.80 .05 329 19J4" 5^19,14, 6 Ground A 0 35/2 35/2 16 725.24 .05 329

19,14, 5^19,14. 6 Ground E 0 41/2 41/2 16 726.29 .05 329

19.14. 5^19.14, 6 Ground E 0 35/2 35/2 16 726.71 .05 329

19,15, 5^^19,13, 6 1 Ground E 0 39/2 39/2 16 717.31 .05 329

19,15. 5<—19,13, 6 Ground E 0 37/2 37/2 16 717.75 .05 329

19'l5^ 5^19*13' 6 Ground A 0 39/2 39/2 16 719.53 .05 329

19.15. 5^19,13, 6 Ground A 0 37/2 37/2 16 719.98 .05 329

19.15. 5^19,13, 6 Ground E 0 41/2 41/2 16 723.04 .05 329

-

19.15. 5'^19,13, 6 Ground E 0 35/2 35/2 16 723.52 .05 329

19,15. 5^19.13. 6 Ground A 0 41/2 41/2 16 725.24 .05 329 19J5! 5^19"l3' 6 Ground A 0 35/2 35/2 16 725.70 .05 329

20.14. 6^20.14. 7 Ground A 0 41/2 41/2 19 777.80 .05 329

20,14, 6'^20,14, 7 Ground A 0 39/2 39/2 19 778.22 .05 329

20,14, 6*-20,14, 7 ! Ground A 0 43/2 43/2 19 783.53 .05 329 20J4, 6<—20'l4, 1 Ground A 0 37/2 37/2 19 783.93 .05 329 20a5' 6^20"l3' 7 Ground A 0 41/2 41/2 19 777.80 .05 329

20,15, 6^20,13, 7 Ground A 0 39/2 39/2 19 778.22 .05 329

20,15, 6^20,13, 7 Ground A 0 43/2 43/2 19 783.53 .05 329

20,15, 6<—20,13, 7 1 Ground A 0 37/2 37/2 19 783.93 .05 329

20,15. 5^^20,15, 6 Ground A 0 41/2 41/2 16 707.06 .05 329 2OJ5! 5^20J5' 6 Ground A 0 39/2 39/2 16 707.45 .05 329

20,15. 5^20,15. 6 Ground E 0 41/2 41/2 16 708.90 .05 329

20,15, 5<—20.15. 6 Ground E 0 39/2 39/2 16 709.30 .05 329

20,15, 5«-20.15. 6 Ground A 0 43/2 43/2 16 712.50 .05 329

20,15, 5^20,15, 6 Ground A 0 37/2 37/2 16 712.76 .05 329

20"l5" 5^20'l5" 6 (Ground E 0 43/2 43/2 16 714.30 .05 329

20,15, 5^20.15, 6 1 Ground E 0 37/2 37/2 16 714.65 .05 329

20,16. 5^20.14. 6 Ground E 0 41/2 41/2 16 705.82 .05 329

20.16. 5<-20.14, 6 1 Ground E 0 39/2 39/2 16 706.22 .05 329

20.16. 5^20,14, 6 (jround A 0 41/2 41/2 16 708.04 .05 329

20,16, 5^20,14, 6 Ground A 0 39/2 39/2 16 708.44 :05 329

20,16, 5^20,14, 6 Ground E 0 43/2 43/2 16 711.15 .05 329

20,16, 5^20,14. 6 Ground E 0 37/2 37/2 16 711.55 .05 329

26
Methyldifluoroarsine Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum NosVib. State 1 Int. Rotor

[ State n F,'

1

Hype

F'

rfine F1 F

Frequency

MHz

Acc. ±MHzRef.

81 20,16, 5<—20,14, 6 Ground A 0 43/2 43/2 16 713.39 .05 329

20,16, 5<—20,14, 6 Ground A 0 37/2 37/2

1 y "711 "vo 16 713.73 .05 329

2l'l5! 6^2l'l5! 7 Ground 1 A 0 43/2 43/2 19 768.51 .05 329

21,15, 6^21,15, 7 Ground A 0 41/2 41/2 19 768.95 .05 329

21,15, 6<—21,15, 7 Ground 1 A 0 45/2 45/2 19 773.93 .05 329

21,15, 6'^21,15, 7 Ground 1 A 0 39/2 39/2 19 774.22 .05 329

21,16, 6<—21,14 7 Ground ! A 0 43/2 43/2 19 768.51 .05 329 2U6i 6^21J4i 7 Ground 1 A 0 41/2 41/2 19 768.95 .05 329

21,16, 6^21,14, 7 Ground 1 A 0 45/2 45/2 19 773.93 .05 329

21 16, 6<—21,14 7 Ground A 0 39/2 39/2 19 774.22 .05 329

22,16. 6*—22,16 7 Ground 1 E 0 45/2 45/2 19 756.43 .05 329

22,16, 6<—22,16 7 Ground 1 A 0 43/2 43/2 19 758.40 .05 329 22J6i 6^22'l6' 7 Ground A 0 45/2 45/2 19 758.40 .05 329

22,16, 6^22,16, 7 Ground E 0 43/2 43/2 19 759..34 .05 329

22 16, 6^^22,16 7 Ground E 0 41/2 41/2 19 761.35 .05 329

22 16, 6<—22 16 7 Ground A 0 47/2 47/2 19 763.34 .05 329

22,16 6<—22,16 7 Ground 1 A 0 41/2 41/2 19 763..34 .05 329 22J6' 6^22*16! 7 Ground 1 E 0 47/2 47/2 19 764.30 .05 329

22,17, 6-^22,15, 7 Ground 1 E 0 45/2 45/2 19 756.43 .05 329

22 17, 6<—22,15, 7 Ground A 0 43/2 43/2 19 7.58.40 .05 329

22 17, 6-^22,15, 7 Ground A 0 45/2 45/2 19 758.40 .05 329

22,17, 6*—22,15, 7 Ground E 0 43/2 43/2 19 759.34 .05 329 22,n[ 6^2245' 7 Ground 43/2 43/2 19 759.34 .05 329

22,17, 6^22,15, 7 Ground E 0 41/2 41/2 19 761.35 .05 329

22,17, 6*—22,15, 7 Ground A 0 47/2 47/2 19 763.34 .05 329

22,17, 6<—22,15,

7' Ground A 0 41/2 41/2 19 763.34 .05 329

22,17, 6<—22,15, 7 Ground E 0 47/2 47/2 19 764.30 .05 329 22,n] 6^2245! 7 Ground 47/2 47/2 19 764.30 .05 329

22,17, 5^22,17, 6 Ground 1 E 0 45/2 45/2 16 680.39 .05 329

22,17, 5^^22,17, 6 Ground E 0 43/2 43/2 16 680.63 .05 329

22,17, 5<—22,17, 6 Ground A 0 47/2 47/2 16 682.54 .05 329

22,17, 5<—22,17, 6 Ground A 0 41/2 41/2 16 682.87 .05 329 2247^ 5^2247,' 6 Ground 1 E 0 47/2 47/2 16 685.19 .05 329

22,17, 5<-22,17, 6 Ground 1 E 0 41/2 41/2 16 685.46 .05 329

22,18, 5^22.16, 6 Ground A 0 45/2 45/2 16 680.13 .05 329

22,18, 5*—22,16, 6 Ground A 0 43/2 43/2 16 680.39 .05 329

22,18, 5^22,16, 6 Ground E 0 47/2 47/2 16 682.54 .05 329

22^18! 5^2246^ 6 Ground 1 E 0 41/2 41/2 16 682.87 .05 329

22,18, 5^22,16, 6 Ground 1 A 0 47/2 47/2 16 684.93 .05 329

22,18, 5'^22,16, 6 Ground A 0 41/2 41/2 16 685.19 .05 329

23,17, 6^23,17, 7 Ground E 0 47/2 47/2 19 745.16 .05 329 23J7! 6<—23,17! 7 Ground 1 A 0 45/2 45/2 19 746.89 .05 329 23a7[ 6^23J7," 7 Ground A 0 47/2 47/2 19 746.89 .05 329

23,17, 6«-23,17, 7 Ground E 0 45/2 45/2 19 747.82 .05 329

23,17, 6^23,17, 7 Ground 1 E 0 43/2 43/2 19 749.81 .05 329

23,17, 6^23.17, 7 Ground 1 A 0 49/2 49/2 19 751.49 .05 329

23,17, 6^23,17, 7 Ground A 0 43/2 43/2 19 751.49 .05 329

23,17, 6^23,17, 7 Ground 1 E 0 49/2 49/2 19 752.44 .05 329

23,18, 6^23,16, 7 Ground E 0 47/2 47/2 19 745.16 .05 329

23,18, 6<-23,16, 7 Ground 1 A 0 45/2 45/2 19 746.89 .05 329

27
Methyldifluoroarsine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor j ^yperfine Frequency Acc.

1 Ref. No. Quantum Nos. State n | F^' F' p MHz ±MHz 1

81 23,18, 6^23,16, 7 Ground

1 A 0 ] 47/2 47/2 19 746.89 .05 329

23,18, 6^23,16, 7 Ground E 0 45/2 45/2 19 747.82 .05 329

23,18, 6^23,16, 7 Ground E 0 43/2 43/2 19 749.81 .05 329

23,18, 6'^23,16, 7 Ground A 0 49/2 49/2 19 751.49 .05 329

23,18, 6^23,16, 7 Ground A 0 43/2 43/2 19 751.49 .05 329

23,18, 6^23,16, 7 Ground E 0 j 49/2 49/2 19 752.44 .05 329

'

'' 23,18, 5^23,18, 6 Ground A 0 47/2 47/2 16 659.49 .05 329

23,18, 5^23,18, 6 Ground A 0 45/2 45/2 16 6.59.86 .05 329

23,18, 5^23,18, 6 Ground E 0 47/2 47/2 16 663.09 .05 329

23,18, 5^23,18. 6 .Ground E 0 45/2 45/2 16 663.35 .05 329

23,18, 5<-23,18, 6 Ground A 0 i 49/2 49/2 16 664.29 .05 329

23,18, 5^23.18, 6 Ground A 0 43/2 43/2 16 664.56 .05 329

23,18, 5^23,18, 6 Ground E 0 49/2 49/2 16 667.74 .05 329

23,18, 5^23,18, 6 Ground E 0 43/2 43/2 16 667.99 .05 329

23,19. 5^23,17, 6 Ground E 0 47/2 47/2 16 660.96 .05 329

23,19, 5^23,17, 6 Ground E 0 1 45/2 45/2 16 661.14 .05 329

23,19, 5-^23,17, 6 Ground A 0 45/2 45/2 16 663.76 .05 329

23,19, 5^23,17, 6 Ground E 0 49/2 49/2 16 665.55 .05 329

23,19, 5^23,17, 6 Ground E 0 43/2 43/2 16 665.82 .05 329

23,19, 5^23,17, 6 Ground A 0 49/2 49/2 16 667.99 .05 329

23,19, 5^23,17, 6 Ground A 0 43/2 43/2 16 668.31 .05 329

24,18, 6^24,18, 7 Ground E 0 49/2 49/2 19 732.30 .05 329

24,18, 6^24,18, 7 Ground A 0 47/2 47/2 19 733.79 .05 329

24,18, 6^24,18, 7 Ground A 0 1 49/2 49/2 19 733.79 .05 329

24.18, 6^24,18, 7 Ground E 0 , 47/2 47/2 19 734.90 .05 329

24,18, 6^24,18, 7 Ground E 0 [ 45/2 45/2 19 736.79 .05 329

24,18, 6^24,18, 7 Ground A 0 51/2 51/2 19 738.29 .05 329

24,18, 6^24,18, 7 Ground A 0 45/2 45/2 19 738.29 .05 329

24,18, 6*-24,18, 7 Ground E 0 51/2 51/2 19 739.39 .05 329

24,19, 6^24,17, 7 Ground E 0 49/2 49/2 19 732.30 .05 329

24,19, 6^24,17, 7 Ground A 0 1 47/2 47/2 19 733.79 .05 329

24,19, 6^24,17, 7 Ground A 0 49/2 49/2 19 733.79 .05 329

24,19, 6^24,17, 7 Ground E 0 47/2 47/2 19 734.90 .05 329

24,19, 6^24,17, 7 Ground E 0 1 45/2 45/2 19 736.79 .05 329

24,19, 6^24,17, 7 Ground A 0 1 51/2 51/2 19 738.29 .05 329

24,19, 6^24,17, 7 Ground A 0 1 45/2 45/2 19 738.29 .05 329

24,19, 6^24,17, 7 Ground E 0 51/2 51/2 19 739.39 .05 329

24,19, 5^24,19, 6 Ground A 0 49/2 49/2 16 639.06 .05 329

24,19, 5^24,19, 6 Ground A 0 47/2 47/2 16 639.36 .05 329

24,19. 5^24,19. 6 Ground E 0 j 51/2 51/2 16 647.94 .05 329

24,19, 5<-24,19, 6 Ground E 0 1 45/2 45/2 16 648.05 .05 329

24,20, 5^24,18, 6 Ground E 0 49/2 49/2 16 642.15 .05 329

24,20, 5^24,18, 6 Ground E 0 47/2 47/2 16 642.38 .05 329

24,20, 5^24,18, 6 Ground A 0 1 49/2 49/2 16 644.97 .05 329

24,20, 5*-24,18, 6 Ground A 0 1 47/2 47/2 16 645.19 .05 329

24,20, 5^24,18, 6 Ground E 0 [ 51/2 51/2 16 646.57 .05 329

24,20, 5^24,18, 6 Ground E 0 45/2 45/2 16 646.82 .05 329

24,20, 5^24,18, 6 Ground A 0 51/2 51/2 16 649.41 .05 329

24,20, 5^24,18, 6 Ground A 0 1 45/2 45/2 16 649.63 .05 329

25,19. 6<-25.19, 7 Ground E 0 51/2 51/2 19 718.14 .05 329

28
Methyldifluoroarsine Spectral Line Table

Isotopic Species Id. Rotational Vib. State

1 Int. Rotor Hyperfine Y rcquency

1 Acc. Ref. No. Quantum Nos. [ State n F' F' E1 F MHz 1 ±MHz

81 25,19, 6^25,19, 7 1 Ground 1 A 0 49/2 49/2 19 719.24 1 .05 329

25,19, 6'^25,19, 7 Ground 1 A 0 51/2 51/2

'\ (\ T\ f\ O /I 19 119.2^ 1 .05 329

25,19, 6^25,19, 7 Ground 1 E 0 49/2 49/2 19 720.54 ! .05 329

25,19, 6^25,19, 7 Ground 1 E 0 47/2 47/2 19 722.36 .05 329

25,19, 6^25,19, 7 Ground 1 A 0 53/2 53/2 19 723.46 .05 329

25,19. 6^25.19, 7 Ground 1 A 0 47/2 47/2 19 723.46 .05 329

25,19, 6*—25,19, 7 Ground E 0 53/2 53/2 19 724.74 1 .05 329

25,20, 6^25,18, 7 Ground E 0 51/2 51/2 19 718.14 1 .05 329

25,20, 6-^25,18, 7 Ground A 0 49/2 49/2 19 719.24 .05 329

25,20, 6^25,18, 7 Ground 1 A 0 51/2 51/2 19 719.24 .05 329

25,20, 6^25,18. 7 1 Ground 1 E 0 49/2 49/2 19 720.54 1 .05 329

25,20, 0<—25,18, 7 1 Ground E 0 47/2 47/2 19 722.36 1 .05 329

25,20, 6^25,18, 7 Ground A 0 47/2 47/2 19 723.46 .05 329

25,20, 6<-25.18, 7 Ground E 0 53/2 53/2 19 724.74 1 .05 329

25,20. 5^25.20, 6 1 Ground 1 A 0 51/2 51/2 16 615.68 .05 329

25,20, 5^25,20, 6 Ground A 0 49/2 49/2 16 615.92 .05 329

25,20, 5^^25,20, 6 Ground A 0 53/2 53/2 16 620.20 .05 329

25,20, 5^25,20, 6 Ground A 0 47/2 47/2 16 620.45 1 .05 329

25.20, 5^25.20, 6 Ground E 0 51/2 51/2 16 620.96 .05 329

25,20, 5^25.20. 6 Ground E 0 49/2 49/2 16 621.21 .05 329

25,20, 5^25,20, 6 1 Ground 1 E 0 53/2 53/2 16 625.44 1 .05 329

25,20. 5'^25.2U. 6 1 Ground E 0 47/2 47/2 16 625.75 1 .05 329

25.21. 5^25.19. 6 Ground E 0 51/2 51/2 16 621.38 1 .05 329

25,21. 5^25.19. 6 Ground E 0 49/2 49/2 16 621.61 1 .05 329

25,21, 5^25,19, 6 Ground 1 A 0 51/2 51/2 16 624.54 1 .05 329

25,21, 5^25,19. 6 t Ground I A 0 49/2 49/2 16 624.78 I .05 329

25.21. 5^^25.19. 6 Ground E 0 53/2 53/2 16 625.44 [ .05 329

25.21. 5^25.19. 6 Ground E 0 47/2 47/2 16 625.75 .05 329

25,21, 5^25,19, 6 Ground A 0 53/2 53/2 16 628.81 1 .05 329

25,21. 5*-25.19, 6 Ground A 0 47/2 47/2 16 629.05 .05 329

26,20, 6^26,20, 7 1 Ground 1 E 0 53/2 53/2 19 702.69 .05 329

26,20, 6*—26,20. 7 1 Ground A 0 51/2 51/2 1 A "7 AO ^ O 19 703.62 .05 329

26,20, 6*-26,20, 7 Ground A 0 53/2 53/2 19 703.62 .05 329

26,20, 6^26,20, 7 Ground 1 E 0 51/2 51/2 19 704.87 .05 329

26,20, 6^26,20, 7 Ground 1 E 0 49/2 49/2 19 706.70 .05 329

26,20, 6^26,20, 7 1 Ground 1 A 0 55/2 55/2 19 707.62 .05 329

O/; OA , OiC OA 26,20, 6<—26.20. 7 i Ground A 0 49/2 49/2 1 A "TA"? O 19 707.62 .05 329

26.20. 6^26.20, 7 Ground 1 E 0 55/2 55/2 19 708.87 .05 329

26.21. 6^26,19, 7 Ground E 0 53/2 53/2 19 702.69 .05 329

26.21. 6^26.19. 7 Ground A 0 51/2 51/2 19 703.62 .05 329

26,21, 6^26,19, 7 Ground 1 A 0 53/2 53/2 19 703.62 .05 329

O*; Ol J <~iC lA 26,21, 6*—26,19, 7 Ground E 0 51/2 51/2 19 704.87 .05 329

26,21, 6<-26,19, 7 Ground E 0 49/2 49/2 19 706.70 .05 329

26,21, 6^26,19, 7 Ground A 0 55/2 55/2 19 707.62 .05 329

26,21, 6^26,19, 7 Ground A 0 49/2 49/2 19 707.62 .05 329

26,21, 6^26,19, 7 Ground 1 E 0 55/2 55/2 19 708.87 .05 329

26,21, 5<-26,21, 6 Ground 1 A 0 53/2 53/2 16 589.19 .05 329

26,21. 5^26.21. 6 Ground A 0 51/2 51/2 16 589.19 .05 329

26.21. 5^26.21, 6 Ground A 0 55/2 55/2 16 593.72 .05 329

26,21. 5^26.21, 6 Ground A 0 49/2 49/2 16 593.72 .05 329

29
Methyldifluoroarsine

Spectral Line Table

Isotopic Species 1(1. 1 Rotational | Vib. State Int. Rot or Hypecfine 1 Frequency Acc. Ref. No. [ Quantum Nos. [ State n f; 1 f' I f, F 1

1 1 MHz ±MHz

C'-H.,As^'>Fi^ 81 26.21. 5^26.21. 6 Ground 1 E 0 153/2] 153/2! 16 595.32 .05 329 Ground 1 F 1 n\j 151/21 51/2i

1 f^Q'^l ^9 iO DVO.OZ QOO ozv

1 26,21, .5^26,21. 6 Ground 1 E 0 |55/2| [55/21 16 599.81 .05 329

26.21. 5<-26.21, 6 Ground E 0 [49/2 [49/2 16 599.81 .05 329

26.22. 5^26.20. 6 1 Ground E 0 !53/2 [53/21 16 598.89 .05 329

j 26.22. 5^26.20. 6 [ Ground 1 E 0 i51/2! [51/21 16 598.89 .05 329

9A 99 ^* 9/=i 90 A 1

1 ZD.ZZ, 0* ZD.ZU, O 1 Ground A U |53/2| [53/21 to oUz.zz .1)0 0 OA 329

i 26.22. 5^26.20. 6 Ground A 0 [51/21 [51/21 16 602.22 .05 329

26.22. 5<-26.20, 6 Ground ! E 0 [55/2i [55/21 16 602.97 .05 329

26,22. 5^26,20. 6 Ground 1 E 0 49/2 [49/2 16 602.97 .05 329

1 26.22. 5^26.20. 6 Ground 1 A 0 55/2i [55/2[ 16 606.36 .05 329

1 9ft 99 9ft 9n ft Ground 1 A n 149/2 49/2 [ 10 OUD.OO .Uo QOO ozy

27,22, 5-^27,22, 6 Ground 1 A 0 [55/2[ 55/2[ 16 558.95 .05 329

27,22, 5^27,22, 6 Ground A 0 [53/2[ |53/2[ 16 558.95 .05 329

27,22, .5^27,22, 6 Ground 1 A 0 57/2 |57/2| 16 563.55 .05 329

i 27,22, 5^27,22, 6 j Ground 1 A 0 |51/2[ |51/2| 16 .563.55 .05 329

97 99 ^< 97 99 ft Ground 1 ^ u 55/2 55/2 10 DOD.OO ozy Q9Q

27,22, 5^27,22, 6 Ground E 0 53/2 [53/2 16 565.86 .05 329

1 27,22, 5^27,22, 6 Ground E 0 57/2 [57/2 16 570.36 .05 329

i 27.22, 5^27,22, 6 Ground E 0 [51/2 (51/21 16 570.36 .05 329

1 27,23, 5^27,21, 6 Ground i E 0 [55/2[ |55/2| 16 574.40 .05 329

97 9^ 97 91 ft Ground 1 ^ n 1 u [53/2[ 53/2| 10 0 iHe.^yj .Uo ozy

27,23, 5^27,21, 6 Ground A 0 55/2[ 55/2 16 577.85 .05 329

27,23, 5^27,21, 6 Ground 1 A 0 |53/2( [53/2 16 .577.85 .05 329

27,23, 5^27,21, 6 Ground 1 E 0 57/2 [57/2| 16 578.40 .05 329

27,23, 5^27.21. 6 [ Ground 1 E 0 \ [51/2[ |51/2| 16 578.40 .05 329

97 9'^ ^< 97 91 ft Ground i A (\ 1 57/2 [57/2! 10 DfSl.OO .Uo 39Q ozV

27.23. 5^27.21. 6 Ground A 0 51/2 [51/21 16 581.88 .05 329

28.23. 5^28.23, 6 Ground 1 A 0 [57/21 57/2 16 524.58 .05 329

28,23, 5^28.23, 6 Ground A 0 |55/2[ |55/2| 16 524.58 .05 329

28.23. 5^28,23, 6 j Ground 1 A 0 1 |59/2| [59/21 16 .529.17 .05 329

9fi 9^ ^< 98 9^ ft CrrtJUnd A n 1 53/2 53/2[ 10 oZV.l / .Uo 590 ozV

28,24, 5^28,22, 6 Ground 1 A 0 [57/2 57/2 16 .551..39 .05 329

28,24, 5^28,22, 6 Ground t A 0 [55/2 |55/2[ 16 551.39 .05 329

28,24, 5^28,22, 6 Ground 1 A 0 [59/2[ 59/2 16 .555.31 .05 329

28,24. 5^28.22. 6 ! Ground 1 A 0 1 |53/2|

i 1

[53/2[

1

16 555.31 .05 329

30
90 - Methyldifluoroborane Molecular (Constant Table CH3BF2 Cs(C3v,C2v) CH;,BF,

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D,, K A

C'^H^B'Ti'* Cs 91 8 ,329.01 M

1 4 650.52 M 0.257

Id. No. /Xa Debye jLi|, Debye /Lij. Debye eQq v„ Acc. OJa d Wii d W(. d w,i d

91 1.67 M

1 0. X 13.77 .03

References: ABC: 186 Dj: ' Bj^: k: A: 116

ju.: 186 eQq: V: 186 I: w:

Add. Refs.: 125, 195

Rotational constant for BF2 group only: A= 10586.73 MHz. Ref: 186.

Methyldifluoroborane c- 1 t t> 1 1 bpectral Line 1 able

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine

] Frequency | Acc. | Ref. No. Quantum Nos. 1 State n F' F, F MHz ±MHz

C'2H,B"Fi" 91 1, , ^ 0, . (Jround eO 12 979.4 1 .1 186

2, Ciround eO 3 773.5 .1 186

2. Ground oO 22 280.6 .1 186

2. Ground o3 23 999.7 1 .1 186

2, Ground o3 24 278.8 .1 186

2, Ground o2 25 635.5 i .1 1 186

2. Ground 1 e3 25 817.4 .1 186

2, Ground i e2 26 054.3 t .1 186

2, Ground 1 e3 26 201.6 1 .1 186

2, Ground o2 26 276.7 1 .1 186

2, Ground 1 ol 26 590.5 1 .1 1 186

2, Ground o3 27 625.8 1 .1 186

2. Ground o3 27 904.3 .1 186

2, Ground oO 29 637.6 .1 186

3, ^ ^ 2"

^ Ground oO 32 291.8 1 .1 186

4, , ^ 4. , Ground I oO 31 575.1 1 .1 I 186

6, , 6. . Ground oO 25 107.2 .1 186

9, , ^ 9, , Ground 1 oO 26 548.0 .1 186

12. , ^12. . Ground oO

1 25 848.0 1 .1

I 186

31
100 - Methvltrichlorosermane

C3v(C3v^C3v)

Molecular Constant Table CHoGeCL

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) Dj DjK K A

C'2H3Ge^°Clf C3V 101 C'^HaGe'^ClfCF" Cs 106 1 585. M 1 567. M 1 192. M

C'-H3Ge"Clf C3V 107 1 599.3 M 1 599.3 M

Id. No. fjL^ Debye Mb Debye /u,(. Debye eQq V Acc. I red OJa d OJb d (jj^. d Wa d

101 0. X 0. X 2.63'' M

1. Value recorded was for compound in benzene solution, no gas determination being available.

References: ABC: 216,217

IJl: 382

D,,: eQq:

Methyltrichlorogermane Spectral Line Table

Isotopic Species Id. Rotational [ Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. \ State n F' F MHz 1 ±MHz

C'^H3Ge"CP=^Clf 104 3. 2, 2^ 2. 1. 2 ! 9 315. 15. 216

5, 2, 4^ 4, 1, 4 15 530. 1 15. 216

6, 2, 6^ 5, 1. 4 1 18 665. 1 15. 216

C'2H3Ge"ClfCr" 105 3, 2, 2^ 2, 1. 2 1 9 455. 1 15. 216

5. 2. 4^ 4, 1. 4 1 15 755. 15. 216

6, 2, 6^ 5. 1, 4 18 910. 1 15. 216

8, 3, 6^ 7, 2, 6 1 25 220. 1 15. 216

C'2H3Ge"Clf 107 3. ^ 2. 1 9 595. 15. 217

5. ^ 4. 15 995. 15. 217

6, *- 5, 19 190. 1 15. 217

8, ^ 7. 25 590. 1 15. 217

32
110 - Methyltrichlorosilane Moler ular (^i)nstaiit 'I'ahle Methyltrichlorosilicane CH^ClaSi C3v(C3v.C3v) CH^SiCl.,

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C(MHz) D.,K K A

C'^HjSi^sClf Ill 1 769.836 M 1 769.836 M 1 317. M <.010

C'^HaSi^Clf C3V 112 1 699.791 M 1 699.791 M

Id. No. /j-a Debye Debye jLij. Debye eQq V Acc. I red OJa d Wi, d to,, d d

Ill 0. X 0. X 1.93' L

1. Benzene soIuli<in deterininaliun of diptile mnment is value given; no gas determinati(jn value was available.

References: ABC: 79, 303 Dj: Djk: 79 k: A:

ju,: 364 eQq: V: I: <a: Add. Ref.: 58, 85

Methyltrichlorosilane Spectral Line Table

Isotopic Species Id. Rotational

1 Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

C'^HaSi-^Clf Ill 9. ^ 8,

1

j 31 840. 1 20. 79

10. ^ 9. 1 Excited 35 396.71 1 -5 1 79

11. ^10, 1 38 950. 20. 1 79

12. ^11, 1 42 500. 25. I 79

C'^HsSi^^Clf 112 9. ^ 8,

1

1 Excited 30 569.09 i -5 79

10. ^ 9, Excited 33 995.81 1 -5 79

C'^HsSi^^ClfCP' 113 9. . ^ 8. . 31 410. 1 10. 79

10, . ^ 9. . 1 Excited 34 902.3 t -5 79

11. , ^10. .

! 38 400. i 10. 79

12, , ^11. , 1 41 900. I 20. 79

C'^HaSi^^CP^Cli^ 114 9, . ^ 8. ,

i

1 Ground 30 980. 1 20. 1 79

10, . ^ 9, , 1 Ground 34 400. 1 20. i 79

11. . ^10. . 1 Ground 1 1 1 37 900. 1 20. ' 79

12. . ^11. . Ground

1 1

41 310. 1 20. 79

33
120 - Methyltritluonigermane' Molecular Constant Table

CHaFjGe C.,v(C3v.C3v) CHsGeFs

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) Dj DjK K A

C'-HaGe'Ti" 121 3 257. M 3 2.57. M

Id. No. /Xa Debye /x„ Debye fi^. Debye eQq V Acc. O);, d CO,, d d aj,| d

121 3.8 M 0. X 0. X

1. Absorption spectrum in the 10-30 kMHz range has been observed and records obtained for lines corresponding to transitions J = 2*— 1.3*—2.4*—3. for both ground and excited

states of interna! rotation. However, these have not been reported in available literature.

References: ABC: 387 Dj: Djk: k: A:

/x: 387 eQq: V: I: w:

No spectral lines

130 - Methyltrifluorosilane Molecular Constant Table

Methyltrifluorosilicane

CH.FaSi C..jv(C3v,C3v) CHjSiFj

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) Djk K A

C'-^HjSi^T^^ 131 3 715.66 M 3 715.66 M .001 <.003

C'-^D.^Si-T,!^ 132 3 314.56 M 3 314.56 M

C'-^'D^Si^T;!" C3V 133 3 245.84 M 3 245.84 M

C'^HjDSi^T.^" Cs 134 4 007. M 3 574.15 M 3 556.00 M

C'^HD^Si^^Ff 135 4 Oil. M 3 448.23 M 3 418.60 M

Id. No. /ia Debye /xi, Debye /x^. Debye eQq V3 Acc. I red OJa d oji, d (Uj. d (Oa d

131 2.483 M 0. X 0. X 1200

References: ABC: 194. 303 D,,: 136 D,k: 136 k: A:

95 eQq: V: 48 I: o>: Add. Refs.: 29. 43. 130. 374

Torsional frequency 141 cm '. Ref: 43.

34
Methyltrifluorosilane Spectral Line Table

-— '—

r

1 Isotopic Species | Id. Rotational Vib. Slate Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F

C'^HaSi^Tis 131 3, 2, Excited 22 242.1 136

3, *- 2, Excited 22 244.4 136

3, ^ 2. Excited 22 267.48 136

3, «- 2, Excited 22 278.47 1 36

3, ^ 2, Ground 22 293.87 .1 1.36

3, ^ 2. Excited 22 296.97 136

3. ^ 2, Excited 22 323.32 136

4. ^ 3, Excited 29 656.06 136

4, 3. Excited 29 659.06 136

4. ^ 3, Excited 29 689.70 A O

4, ^ 3, Excited 29 690.07 A O

4, 3, Excited 29 704.12 48

4. ^ 3, Excited 29 704.70 48

4, 3, Excited on "70/1 on A Q

4, ^ 3, Ground OA "70/1 29 7/4.99 .1 i.30

4, *- 3. Excited on "700 1 0 29 //9.13

4, ^ 3. Excited 29 764.24 136

5. ^ 4, Excited 37 025.7 1.36

5, ^ 4, Excited 61 034.4 lot) 5, ^ 4. Excited 37 046.5 136

5, ^ 4. Excited 37 069.91 loo

5, ^ 4, Excited 37 073.67 136

5, ^ 4, Excited 37 082.2 136

5, ^ 4, Excited 37 112.05 136

5, 4, Excited 37 112.32 136

5. ^ 4, Excited 37 129.86 136

5, ^ 4, Excited 37 129.98 136

5, ^ 4, Ground 37 156.07 .1 136

5, ^ 4, Excited 37 161.16 too

5. ^ 4. Excited 37 205.16 136

C'^DaSi^'^FJ^' 132 4, 3, Excited 26 440.62 136

4, ^ 3, Excited 26 463.93 136

4, ^ 3, Excited 26 488.90 136

4, ^ 3. Ground 26 516.20 .1 ioO

4, ^ 3, Excited 26 545.72 loo

5. ^ 4, Excited 32 975.4

5. ^ 4, Excited 32 999.3 136

5, ^ 4, Excited 33 006.1 136

5. ^ 4, Excited 33 022.6 loo

5. ^ 4, Excited 33 026.2 too

5. ^ 4, Excited 33 032.3 136

5, 4. Excited 33 050.53 136

5, ^ 4. Excited 33 052.04 136

5, ^ 4. Excited 33 063.5 136

5, ^ 4, Excited 33 079.78 136

5, ^ 4, Excited 33 095.30 136

5. ^ 4, Excited 33 110.97 136

5, ^ 4, Excited 33 132.71 136

5, ^ 4, Ground 33 145.02 .1 136

5. <— 4, Excited 33 148.51 I ou

5. 4.

1 1 1 Excited1 1 1

1 1 I

1 i ! .

1 33 181.81 1

\

I 136

35
140 - Formaldoxime

Formaldehyde Oxime; Formoxime

Molecular Constant Table

CH3NO Cs(Cs,Cs) CH,NOH

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D,, K A

c,

Cs

141 14267 678.28 M

66 167.74 M

11 8.59.25 M

11 081.66 M

10 080.07 M

9 484.57 M

Id. No. /LX-a Debye /A„ Debye Debye eQq V Acc. I red COa d Oil, d (1)^. d aj,i d

141

142

0.397 M 0.18 M 0. X 3.0

3.1

References: ABC: 295 Dj: Djk: k: A:

m: 295, 354 eQq: 295 V: I: w:

Add. Refs.: 348. 354. 376

For the first excited torsional state, the rotational constants for species 141 are: A = 66633.02 MHz, B= 11829.56 MHz, and C= 10087.99 MHz; anf for species 142 are: A= 64950.82 MHz. B= 11061.53 MHz, and C= 9503.03 MHz. The torsional frequency for species 141

is 330 + 30 cm-'. Ref: 295.

36
Formaldoxime Spectral Line Table

Isotopic Species Id. R itational Vib. State Int. Rotor Hyperfine F'rpfl 11 pncV Acc. 1 Ref. No. Quantum Nos. State n r

ITr MHz ±MHz

C'^HjN^O'SH 141 1

1 ^ V/, nu, 0 Ground 1 Au

1X 21 916.06 .10 1 295

1 1 < A 0 Ground 1 z9 1 21 917.40 .10 295

1, 0, 1^ 0, 0, 0 (V. J

_ r(1 t

1

1

1LI1 1n1 HVJ I

1 X 21 918.33 .10 295

1, 0, 1^ 0, 0, 0 1 ^rni inn Au 1 91 937 80 .10 295

11

,

1 * u, Au. 0 1 -»roii n H 2 1 21 939.17 .10 i 295

1 n 1 * u. Au, 0 Ground 11

11 21 940.06 .10 295

11

,

1 < 9 1 * Z, A 2 Ground 1

11 9Z 11 007.38 .10 295

1, i; 1^ 2, 0, 2 (v_7l » 1J* 1U1 n1 1 HLl 9z z9 1 1 008 8R .10 295

1, 1^ 2, 0, 2 ( .mi 1 fl ri I

11

1 1 1 008 88 .10 295

1 1X *—^ z.9 AU, 2 ( tVCt 1 1 n H I 2 3 1 1 009 (SS .10 295

11

,

1 < 9 X z. A 2 Ground 1 AW

1X 11 012.32 .10 295

X ^ z, A 2 Ground ]^ 9 11 980.31 .10 295

1, 1^ 2, 0, 2 ( .r* 11 1 riM z9 z9 11 981.85 .10 295

1, 1^ 2. 0. 2 Ground 1X ]^ 11 981.85 .10 295

11 ^ 1X *—^ z.9 n 2 ( irni 1 nrr 2 3 11 982.69 .10 295

1 X ^ z

,

Q 2 Ground Au X 11 985.43 .10 1 295

nu. Z^ X

.

Au. 1 Ground 1 ao z9 43 794.02 .10 ! 295

2, 0, 2*- 1. 0. 1 1 .mi 1 n H 2 ]^ 43 794.02 .10 295

2, 0, 2^ 1. 0, 1 1 . ro 1 1 n H ao z9 43 836.50 . 10xu 295

9 n 9« 1 Z* 1

.

nu. 1 Ground 2 1 43 836.50 .10 i 295

9 9^ 1 Z* 1

,

1 Ground z9 z9 43 837.38 .10 295

9 9^ 1 Z* i

,

n 1 Ground 1X A 43 837.38 .10 295

2, 1. 1^ 1, 1. 0 ( .ro 1 1 n H 1X Au 45 657 30 .10 295

2, 1, 1^ 1, 1, 0

a 9z 45 657 30 . 10xu 295

9 11

,

11

,

0 ( .mi 1 n

H

2 1 45 658 40 . 10xu 295

Z.9 1A* 9< 1 Z* 1

.

1 1 Ground 1 0o z9 42 093.42 .10 i 295

9 1i

,

9.^ 1 Z* 1

.

1

,

1 Ground 1X AU 42 097.58 .10 295

2. 1, 2^ 1. 1. I Vjf 1 U U IIU ao z9 49 099 35 .10 295

2. 1. 2^ 1. 1. I ( .roi 1 n H z9 1X 42 1 00 24 .10 1 295

9 11 ^ 1 * 9 1 * Z, 2 ( .rrti 1 n

H

\_T1 L/ U 1 lU 2 2 59 418 76 .xu10 1 295

9 1i

,

i ^ z. n 2 Ground ao

ao 59 418.76

1 .10 1 295

z.9 11

,

1 < 9 i z. nV, 2 Ground TX

1X 59 418.76 .10 295

3, 0, 3*- 2, 1, 2 ( .rn 1 1 n H z9 1X 1 1 567 22 .10 295

3, 0, 3^^ 2. 1, 2 v7l U HI ILI d. ao 1 1 567 73 .10 ! 295

a 0 z ^ 1 2 ( .ro 1 1 n H 3 2 1 1 569 21 .10 i 295

a 1 9< Q Z* o.1

1 , 3 Ground 2 2 10 672.20 .10 295

Q^111

,

9< 3 Z* o. 1 3 Ground A 4. 10 672.88 .10 295

i' 3, 1, 2^ 3, 1. 3 Ground ao

ao 10 675.03 .10 295

\ 4, 0, 4^ 3, 1, 3 Ground co 4* 35 782 59 .10 295

A 1 3 1 » ri'i 1 1 n H 3 2 35 789 59 .10 1 295

n 1

J.

,

3 Ground d.4" a 35 783.93 .10 295

d 1

.

1 4 Ground Co

c; o 17 784.10 .10 295

4. 1. 3^ 4. 1. 4 I » rr» 1 1 n H a a 17 784.10 .10 295

4, 1, 3^ 4. 1. 4 ( -wVCi 1 1 n

H

I" 1 7 786 54 .10 1 295

5. 1. 4^ 5. 1, 5 1 .TAii n

H

6 6 96 664 83 .10 295

5, 1. 4^ 5. 1. 5 Ground 4 4 26 664.83 .10 295

5, 1, 4«- 5, 1. 5 Ground 5 5 26 667.27 .10 295

5, 2, 4^ 6, 1, 5 Ground 1 5 6 17 744.62 .10 1 295

5, 2, 4^ 6. 1. 5 Ground 1 4 5 17 745.95 .10 295

5. 2, 4^ 6. 1. 5 Ground 1 6 7 17 745.95 .10 i 295

749-587 0-69—

4

37
Formaldoxime

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f;1

^[vD€ F'rfine E1 F

Frecjuency

MHz

Acc. ±MHz

Ref.

C'^H,N'^0"'H 141 5, 2, 4^ 6. 1, 5 Ground 5 6 20 332.08 .10 295

5, 2, 4^^ 6, 1, 5 Ground 4 5 20 333.55 .10 295

5, 2, 4^ 6, 1, 5 Ground 6 7 20 333.55 .10 295

7. 2. 5^ 8, 1, 8 Ground 8 9 33 029.62 .10 295

7, 2, 5^ 8, 1, 8 Ground 6 7 33 029.62 .10 295

7. 2, 5^ 8, 1, 8 Ground 7 8 33 031.20 .10 295

8, 1, 7^ 7, 2, 6 Ground 9 8 35 878.00 .10 295

8. 1, 7^ 7, 2, 6 Ground 7 6 35 878.00 .10 295

8, 1, 7^ 7, 2, 6 Ground 8 7 35 879.33 .10 295

8, 2. 6^ 9, 1, 9 Ground 1 9 10 18 993.86 .10 295

8, 2, 6<- 9. 1, 9 Ground 1 7 8 18 993.86 .10 295

8, 2, 6^ 9, 1, 9 Ground 1 8 9 18 995.60 .10 295

8, 2, 6^ 9, 1, 9 Ground 9 10 22 992.67 .10 295

8, 2, 6<- 9, 1, 9 Ground 7 8 22 992.67 .10 295

8, 2, 6^ 9, 1, 9 Ground 8 9 22 994.40 .10 295

9, 2, 7«- 9, 2, 8 Ground 10 10 • 13 113.34 .10 295

9, 2, 7-^ 9, 2, 8 Ground 8 8 13 113.34 .10 295

9, 2, 7^ 9, 2. 8 Ground 9 9 13 114.20 .10 295

9, 2, 7^10, 1.10 Ground 10 11 15 265.32 .10 295

9, 2, 7^10, 1,10 Ground 8 9 15 265.32 .10 295

9, 2, 7^10, 1,10 Ground 9 10 15 267.31 .10 295

10, 2, S'^IO, 2, 9 Ground 1 11 11 18 770.96 .10 295

10, 2, 8^10, 2, 9 Ground 1 9 9 18 770.96 .10 295

10, 2, 8^10, 2, 9 Ground 1 10 10 18 771.93 .10 295

10, 2, 8^10, 2, 9 Ground 11 11 19 226.21 .10 295

10, 2, 8^10, 2, 9 Ground 9 9 19 226.21 .10 295

10, 2, 8^10, 2, 9 Ground 10 10 19 227.17 .10 295

10, 3, 8*-ll, 2, 9 Ground 10 11 22 021.47 .10 295

10, 3, B'^ll, 2, 9 Ground 9 10 22 022.37 .10 295

10, 3, 8^11, 2, 9 Ground 11 12 22 022.37 .10 295

11, 2, 9^11, 2,10 Ground 10 10 26 999.14 .10 295

11, 2, 9^11, 2,10 Ground 12 12 26 999.14 .10 295

11, 2, 9<-ll, 2,10 Ground 11 11 27 000.07 .10 295

11, 3, 8^12, 2,11 Ground 10 11 31 633.09 .10 295

11, 3, 8-^12, 2,11 Ground 12 13 31 633.09 .10 295

11, 3. 8^12, 2,11 Ground 11 12 31 633.42 .10 295

12, 3, 9<-13, 2,12 Ground 11 12 14 294.70 .10 295

12, 3, 9^13, 2,12 Ground 13 14 14 294.70 .10 295

12, 3, 9<-13, 2,12 Ground 12 13 14 295.11 .10 295

16, 3,13^16, 3,14 Ground 15 15 15 105.64 .10 295

16, 3,13^16, 3,14 Ground 17 17 15 105.64 .10 295

16, 3,13^16, 3,14 Ground 16 16 15 106.03 .10 295

17, 3,14<-17, 3,15 Ground 18 18 20 993.06 .10 295

17, 3J4^17^ 3J5 Ground 16 16 20 993.06 .10 295

17, 3,14^17, 3,15 Ground 17 17 20 993.56 .10 295

C'^HjN'-'O'^D 142 1, 0, 1^ 0, 0, 0 2 1 20 566.08 .10 295

1, 0, 1^ 0, 0, 0 1 1 20 566.97 .10 295

1, 1, 1^ 2, 0, 2 Ground 1 1 2 12 791.54 .10 295

1, 1. 1^ 2, 0, 2 Ground 1 2 3 12 793.90 .10 295

1, 1, 1^ 2, 0, 2 Ground [ 1 1 2 13 986.09 .10 295

38
Formaldoxime Spectral Line Table

Isotopic Species Id. Kolationul Vib. State Iiii. Koi 1 lypcrline Frequency Ace. Ucl. No. Quantum Nos. Stale n F' F' F'1 F MH/. ±MHz

142 1, 1, 1<— 2. 0. 2 Ground 2 3 13 988.28 . 1

0

295

1. 1<— 2. 0

'. 2 (Ground 0 1 13 990.74 .10 295

2, q\ 2^ 1" 0! 1 Ground 1 2 1 41 095.33 .10 295

2, 0, 2<- 1, 0, 1 Ground 1 3 2 41 095.53 .10 295

2, 0. 2*- 1. 0. 1 1 1 41 096.43 .10 295

2, 0, 2^^ 1. 0. 1 3 2 41 097.95 .10 295

2^ 0^ 1. 0'

1 2 1 41 097.95 .10 295

2^ q\ 2^ 1, 0, 1 1 0 41 098.76 .10 295

2, 0, 2^ 1. 0. 1 2 2 41 098.76 .10 295

2, 1, 1<- 1, 1. 0 3 2 42 728.98 .10 295

2, 1, 1<— 1. 1, 0 1 0 42 728.98 1 .10 295

2,

1'

1, \] 1 0 39 533.53 .10 295

2, 1, 2<- 1. 1, J 3 2 39 535.25 .10 295

2, 1, 2-^ 1. 1. I 2 1 39 .536.16 t .10 295

2, 1. 2^ 1, 1, I 1 1 39 536.88 I .10 295

2, 1, 2*- 1, 1, 1 Ground 1 1 0 39 568.84 1 .10 295

2] 1, 2<— 1, 1, Ground 1 3 2 39 570.50 .10 295

2, 1, 2^ 1, 1, j Ground 1 2 1 39 571.43 .10 295

4, 0, 4^ 3, 1, 3 Ground 5 4 30 677.65 .10 295

4, 0, 4^^ 3. 1. 3 Ground 3 2 30 677.65 .10 295

4, 0, 4^ 3. 1, 3 Ground 4 3 30 679.05 .10 295

5! 1, 4^ 5, 1, 5 Ground 1 4 4 23 360.03 .10 295

5! \\ 4^ 5^ l] 5 Ground 1 6 6 23 360.03 .10 295

5, 1, 4^ 5, 1, 5 Ground 1 5 5 23 362.43 .10 295

5. 1. 4^ 5, 1, 5 Ground 6 6 23 938.78 .10 295

5, 1^ 4«— 5. 1. 5 Ground 4 4 23 938.78 i .10 295

5, 4^^ 5 1^ 5 Ground 5 5 23 941.21 .10 295

si

2' 4^ 6^ 1! 5 Ground 1 5 6 24 669.18 .10 295

5, 2, 4^ 6, 1, 5 Ground 1 4 5 24 670.63 .10 295

5, 2. 4<— 6, 1, 5 Ground 1 6 7 24 670.63 .10 295

5, 2. 4^ 6, I, 5 Ground 5 6 27 911.82 .10 295

5^ 2, 4^^ 6, 1, 5 (Ground 6 5 27 913.06 .10 295

5' 2' 4^ 6^ l] 5 Ciround 6 7 27 913.06 .10 295

8, 1, 7^ 7, 2, 6 Ground 9 8 24 380.58 .10 295

8, 1. 7<— 7, 2, 6 (Ground 7 6 24 380.58 .10 295

8. 1, 7^ 7. 2, 6 Ground 8 7 24 381.78 .10 295

8, 2, 6^ 9, 1, 9 Ground 1 7 8 22 238.36 .10 295

8, 2, 6^ 9, 1, 9 Ground 1 9 10 22 238.36 .10 295

8, 2, 6^ 9. 1. 9 (Ground 1 8 9 22 240.09 .10 295

8, 2, 6^ 9. 1, 9 Ground 9 10 26 961.70 .10 295

8, 2, 6*- 9. 1. 9 Ground 7 8 26 961.70 .10 295

8, 2, 6^ 9. 1. 9 (iround 8 9 26 963.42 .10 295

11, 2. 9^11. 2.10 Ground 1 10 10 21 834.41 .10 295

11, 2. 9^11. 2.10 (Jround 1 12 12 21 834.41 .10 295

11, 2. 9^11. 2.10 Ground 1 11 11 21 835.32 .10 295

11, 2, 9^11. 2.10 Ground 12 12 22 421.45 .10 295

11. 2. 9^11. 2.10 (Jround 10 1 10 22 421.45 .10 295

11. 2. 9^11. 2.10 Ground 11 11 22 422.37 .10

1

295

.1

39
150 . Formamide Molecular Constant Table Methanamide

CH3NO C,(Cs.Cs) HCONH2

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) Dj K A

HC'^0"*N'^H., c, 151 72 716.12 M 11 373.75 M 9 833.72 M .0086 c-HDN"C'-HO"^ c, 152 61 345.91 M 11 009.91 M 9 334.09 M .0029 t-HDN'^C'^HO'" c, 153 71 179.61 M 10 473.30 M 9 132.47 M —.0154

DjN'-'C'^HO"* Ci 154 59 715.99 M 10 193.58 M 8 710.35 M —.0207

HaN'-'C'-DO'*' c, 155 54 948.39 M 11 373.07 M 9 419.70 M .0175 156 72 448.6J M 11 054.40 M 9 589.93 M .0058 c, 157 54 733.59 M 11 052.66 M 9 193.12 M .0155 c-HDN'^C'-HO"' c, 158 61 27.5.15 M 10 721.79 M 9 124.91 M .0011 t-HDN'^C'^HO'" c, 159 70 820.47 M 10 223.17 M 8 936.16 M -.0163

D.N'-^C'^HO'" c, 161 .59 594.17 M 9 964.80 M 8 540.45 M -.0221

Id. No. jjia Debye fjLi, Debye /X, Debye eQq V Acc. I red CO;, d oj,, d 01^. d (0,1 d

151

152

153

154

3.62 M 0.85 M 304 1

229 1

246 1

170 1

References: ABC: 278 Dj: Djk: k: A: 278

m: 177 eQq: V: I: w: 278

eQq along the principal axes: eQqaa= 1.9 MHz. eQqbb= 1-7 MHz, and eQqec = — 3.6 MHz. Barrier height (inversion-wagging mode) = 1060 ± 150 cal/mol. Torsional frequency: for H2 species is 600 ±50 cm"'; for D2 species is 490 ±40 cm '. Ref: 278, 142.

40

i
Forniamicle S|ic(licil l.iiic I'alile

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperf'ine Frequency Acc. Ref. No. Quantum NOS. State n F' F MHz ±MHz

HC'^O'^N'^H, 151 1, 0, 1<— 0. 0, 0 1 21 190.7 278

1, 0, l'^ 0, 0, 0 Ground 0 1 21 206.56 .1 177

1, 0, 1^ 0, 0, 0 Ground 2 1 21 207.43 177

1, 0, 1^ 0, 0, 0 Ground 1 1 21 207.96 1 77

1. 1, 1^ 2, 0. 2 Ground 1 2 18 956.28 •1 177

1, 1, l'^ 2, 0, 2 Ground 0 1 18 9.56.28 ] 177

1, 1, 1-^ 2, 0. 2 Ground 2 1 3 18 956.28 177

2, 0, 2^ 1. 0, 1 Ground 42 386.07 278

2, 1, 2^ 1. 1. 1 Ground 40 874.91 278

4, 0, 3, 1. 3 Ground 4 1 3 26 924.05 •1 177

4, 0, 4^^ 3. 1. 3 Ground 3 1 2 26 924.05 177

4, 0, 4^^ 3. 1. 3 Ground 5 1 4 26 924.05 1 177

4, 1, 3^ 4, 1. 4 Ground 4 1 4 15 390.80 •1 177

4, 1, 3^ 4. 1, 4 Ground 5 5 15 392.71 1 177

4, 1, 3<- 4. 1. 4 Ground 3 3 15 392.88 •1 177

5, 1, 4^^ 5. 1, 5 Ground 5 5 23 080.06 177

5, 1, 4<- 5, 1, 5 Ground 4 4 23 081.86 • 1 177

5, 1. 4-^ 5. 1. 5 Ground 6 6 23 082.26 1 177

6, 1. 5«— 6. 1. 6 Ground 6 6 32 296.18 177

6, 1, 5^ 6. 1, 6 Ciround 7

-7

I 32 298.19 177

6, 1. 5^ 6, 1. 6 (iround 5 5 32 298.19 177

6, 2, 5^ 7. 1, 6 (hound 5 6 16 960.96 177

6, 2, 5^ 7. 1. 6 Ground 7

nO 16 960.96 177

6, 2, 5^ 7, 1. 6 CJround 6

-71 16 960.96 177

c-HDN'-'C'-HO"' 152 1. 0. 1<— 0. 0, 0 1 20 341.2 278

1, 0. 1<— 0, 0, 0 Ground 20 344.25 .1 177

1, 1, 1^ 2. 0, 2 Ground 9 689.15 278

2, 0, 2^ 1. 0, 1 Ground /I A £i An Co 40 647.52 .2 177

2, 1, 1-^ 1. 1. 0 (Ground 42 363.74 I to

2, 1, 2^ 1. 1. 1 Ground 39 013.50 .2 177

3, 0, 3^ 2. 1. 2 Ground 12 166.33 278

4. 0. 4^^ 3. 1, 3 Ground o /I £.'~ic\ f\r\ 34 639.00 278

4, 2, 3^^ 5, 1, 4 Ground 39 492.18 278

5, 1. 4«— 5, 1. 5 Ground 5 5 25 113.15 .1 177

5, 1, 4^ 5, 1, 5 Ground 6 6 25 115.24 .1 177

5. 1. 4^ 5. 1, 5 Ground 4 4 25 115.24 .1 177

7, 1. 6«— 6. 2. 5 Ground 11 423.09 278

153 1, 0. 1^ 0, 0. 0 Ground 19 606.11 .1 177

1, 0, l'^ 0, 0, 0 1 19 621.6 278

1, 1, 1^ 2. 0. 2 Ground 21 516.74 278

2, 0, 2^ 1. 0. 1 Ground 39 190.40 .2 177

2, 1, l'^ 1. 1. 0 Ground 40 551.94 .2 177

2, 1, 2^ 1. 1, 1 Ground 37 870.72 .2 177

4, 0, 4^ 3. 1. 3 Ground 20 751.45 278

5. 0, 5^ 4. 1. 4 Ground 42 642.30 278

5, 1, 4^ 5. 1, co Ground 5 5

or) 1 88 1 1 77

5, 1, 4^ 5. 1. 5 Ground 4 4 20 105.84 .1 177

1 5. 1. 4*- 5, 1, Ground 6 6 20 105.84 .1 177

7. 1. 6^ 6. 2, 5 Ground 28 596.20 278

41
Formamide

Spectral Line Table

Isotopic Species 1

A

la. Rotational Vib. State Int. Rotor Hyperfine 1

r requency

1 Ace. Ref. Quantum Nos. State n F' F, F Mnz ±MHz

154 1, 0, 1*- 0, 0, 0 Ground 18 904.01 .1 177

1, 0, 1^ 0, 0, 0 1 18 929.5 278

1, 1, 1^ 2, 0, o

z Ground 11 747.37 278

2, 0, 2^ 1, 0, 1 Ground O "7 Tin OA 37 775.20 .2 177

2, 1, 1^ 1, 1, A

U Ground 39 290.66 .2 177

2, 1, 2<— 1, 1, 1 Ground 36 325.76 .2 177

4, 0, 4<— 3, 1, 3 Ground 29 328.44 278

5, 1, 4<— 5, 1, 5 Ground 5 5 22 229.78 .1 177

5, 1, 4*— r5, 1, 5 Ground 6 6 22 231.80 .1 177

5, 1, 4^ 5, 1, o L» round 4 4

no OQl OA ZZ Zo l.oU 1.1 ill

6, 1, 5*- 5. 2,

A4 Ground ZZ zuy.zi' 0'70 Z/O

155 1, u. 1<— AtJ, 0, 0 Ground 20 792.77 278

2, 0, 2<— 1, 0, 1 Ground 41 521.85 278

2, 1, 2^ 1, 1, 1 Ground 39 632.17 278

3, 0, 3*— 2, 1, 2 Ground 20 435.77 278

3, 2, 2^ 4. 1,

QO Ground 4U OOO.oi Z lo

7, 1, 6^ 6. 2,

rD Ground 9 '7 '7^C 1 '7 0'70 z/o

156 1, 0, 1<— 0. 0, 0 Ground 20 664.33 278

1, 1, 1<— 2, 0, 2 Ground 20 131.44 278

2, 0, 2<— 1, 0, 1 Ground 41 262.58 278

2, 1, 2^ 1, 1, 1 Ground 39 824.19 278

4, 0, 4^ 3. 1, Q Lrround Zl 4/U.oU Zlo

7, 1. 6<— 6, 2,

rO Ground Zl Voo.yo 0*70 Zlo

HaN'^C'^DO'" 157 1, 0. 1^ 0, 0, 0 Ground 20 245.78 278

2, 0, 2<— 1, 0, 1 Ground 40 433.42 278

2, 1, 2*— 1, 1, 1 Ground OO ^ QO AO oo OoZ.UZ 0^70 Z/O

3, 0, 3<— 2, 1, 2 Ground 18 625.75 278

4, 0, 4«— 3, 1, 3 Ground 41 117.81 278

4. 2, 3^ 5, 1, Ground 1 Q nOO Q/1

7, 1, 6*— 6, 2,

cJ Ground

c-HDN-'^C'-HO'" 158 1, 0. 1^ 0, 0, 0 Ground 19 846.70 278

1, 1, 1^ 2, 0, 2 Ground 10 897.20 278

2, 0, 2«— 1, 0, 1 Ground Qo (^c.c, on

2, 1, l'^ 1, 1, A Ground

2, 1. 2^ 1, 1, 1 Ground 38 096.52 278

3, 0, 3-^- 2, 1, z Ground 1 A OQ7 QQ Z lO

4, 0, 4^ 3, 1, 3 Ground QO OOn "71 Z/O

6, 1, 5^ 5, 2, 4 Ground lo o/y.oo Zlo

t-HDN'^C'^HO^" 159 1, 0, 1^ 0. 0, 0 Ground 19 159.33 278

1, 1, 1^ 2, 0, 2 Ground 22 298.92 278

2. 0, 2<- 1, 0, 1 Ground 38 z98.z6 278

2, 1, 1^ 1, 1, 0 Ground 39 605.82 278

2, 1, 2^ 1, 1. 1 Ground 37 031.65 278

4. 0. 4^ 3, 1, 3 Ground 18 964.62 278

5. 0. 5^ 4. 1. 4 Ground 40 332.08 278

161 1, 0, 1^ 0. 0, 0 Ground 18 505.25 278

1, 1, 1^ 2. 0, 2 Ground 12 649.10 278

2. 0, 2<- 1, 0, 1 Ground 0£. AOA AA 36 980.00 278

2, 1, 1<- 1, 1, 0 Ground 38 434.56 278

2, 1, 2^ 1, 1, 1 Ground 35 586.15 278

4, 0, 4^ 3, 1, 3 Ground 27 516.69 278

6, 1, 5^ 5, 2, 4 Ground 25 418.95 278

42
170 . Nitroniethane Mol(H ular Constant 'I'ahic CH3NO2 C,(C3v,C2v) CH.NO^

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D., D.,K K A

171 13 277.5 M 10 542.7 M 5 876.7 M .16 172 13 277.5 M 8 697.1 M 5 254.3 M

... .12

. .

Id. No. fia Debye IXu Debye jj-c Debye eQq V. Acc. oj\, d a)(. d w,i d

171 3.46 M 6.03 .03

172 5.19 . .03

References: ABC: 155 Dj: D,,k: 155 k: A:

155 eQq: V: 155 I: w: Add. Refs.: 13. 19, 70, 99, 125, 265, 281

For species 171, V12 < .05 cal/mol. For species 172, V12 < .05 cal/mol. Ref: 155.

Nitromethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

C'^HsN^OJ" 171 2, 0, ^ 1. 0, Ground 30 037.2 .2 155

2, 0, ^ 1, 0, Ground 32 826. 2. 155

2, 0, ^ 1, 0, Ground 32 859.5 .2 155

2, 0, ^ 1, 0, Ground 32 959.2 .2 155

2, 1, ^ 1, 1, Ground 31 677.3 .2 155

2, 1, ^ 1, 1, Ground 32 034.1 .2 155

2, 1, <- 1. 1, Ground 32 189.7 .2 155

2. 1, ^ 1, 1. Ground 32 660. 2. 155

2, 1, ^ 1, 1, Ground 32 692. 2. 155

2, 1, ^ 1, 1, Ground 32 921. 2. 155

2, 1, ^ 1, 1, Ground 32 985. 2. 155

2, 1, ^ 1, 1. Ground 33 476.5 .2 155

2, 1, ^ 1, 1, Ground 33 643.5 .2 155

2. 1, ^ 1, 1, Ground 33 988.5 .2 155

3, 0, ^ 2, 0, Ground 41 534.9 .2 155

43
Nitromethane

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n F/ ^yperfine

F' 1 F,

1 F

Frequency

MHz

Acc. ±MHz

Ref.

171 Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported

Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported Not Reported Not Reported

Not Reported Not Reported Not Reported

Not Reported Not Reported

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

Ground

16 199.43

16 342. 16 407.48

16 414.84

16 419.50

16 527.51

16 561.51

16 689. 16 721.81

16 807.

16 823. 16 915. 16 948. 17 053. 17 228.

- 17 255.29

17 346.40

17 365.

17 462. 17 513.

17 530. 17 624.66

17 645.77

17 864. 17 904.86

17 972.15

18 068. 18 102. 18 112. 18 136.

18 172. 18 239. 18 256. 18 574. 18 609.

18 665. 18 794.95

18 810. 18 817.69

18 821.93

18 938. 19 025. 19 055. 19 233. 19 370.

19 420. 19 468.86

19 486.13

19 .509.18 19 560.95

19 576. 19 619.86

19 719. 19 794. 19 828.

5.

5.

5.

5.

5.

5.

5.

5.

5.5.

5.

5.

5.

5.

5.

5.5.

5.

5.

5.

5.5.

5.

5.

5.

5.5.

5.

5.

5.

5.

5.

5.

5.

13252

132

132

132

132 13252

132

52

52

52

52

52

52

132

13252

52

52

52

132

13252

132

13252

52

52

52

52

52

52

52

52

52

13252

132

132

52

5252

52

52

52 132

132

132

132

52

13252

52

52

44
Nitromethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperf'ine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

171 Not Reported Ground 20 031.30 132 Not Reported Ground 20 084.41 132 Not Reported Ground 20 188. 5. 52 Not Reported Ground 20 260. 5. 52 Not Reported Ground 20 296.75 132

Not Reported Ground 20 385. 13 Not Reported Ground OA /IOC r

.D. OZ Not Reported Ground 21 190. 5. 52 Not Reported Ground 21 500. 5. 52 Not Reported Ground 21 970. 19

Not Reported Ground 22 040. 70

[Not Reported Ground ZZ UoO. lO i.6Z Not Reported Ground 22 068. 5. 52 Not Reported Ground 22 271.57 132 Not Reported Ground 22 332. 5. 52

Not Reported Ground 22 .372.15 132 Not Reported Ground ZZ oyo.yo 1 QO LoZ Not Reported Ground 22 418. 5. 52 Not Reported Ground 22 465. 70 Not Reported Ground 22 478. 5. 52

Not Reported Ground 22 489. 5. 52 Not Reported Ground 22 528. 5. 52 Not Reported Ground 22 536. 5. 52 Not Reported Ground 22 580. 19 Not Reported Ground 22 620. 19

Not Reported Ground 22 628. 5. 52 Not Reported Ground 22 651. 5. 52 Not Reported Ground 22 701. 5. 52 Not Reported Ground 22 710. 70 Not Reported Ground 22 820. 5. 52

Not Reported Ground 22 830. 70 Not Reported Ground OQ f\f\A Z6 UU4. C

O.

t^O dZ Not Reported Ground 23 015. 70 Not Reported Ground 23 021. 5. 19 Not Reported Ground 23 250. 13

Not Reported Ground 23 260. 70 Not Reported Ground OO OOQ Ol 23 293.91 1 OO 132 Not Reported Ground 23 330.30 132 Not Reported Ground 23 458.88 132 Not Reported Ground 23 470. 70

Not Reported Ground 23 483. 5. 19 Not Reported Ground 23 499. 5. 52 Not Reported Ground 23 594. 5. 52 Not Reported Ground 23 652.02 132 Not Reported Ground 23 661. 5. 52

Not Reported Ground 23 668.03 132 Not Reported Ground 23 680. 70 Not Reported Ground 23 700.01 132 Not Reported Ground 23 706. 5. 19 Not Reported Ground 23 746.16 132

45
Nitromethane

Spectral Line Table

Isotopic Species Id. No.Rotational Quantum Nos.Vib. State Int. Rotor

State n f; Hyp«

F'

; rfine

F, I F

1

Frequency

MHz

1 Acc. ±MHz

1 Ref.

t

171 Not Reported Ground 23 754. 5. 52 Not Reported Ground Zo (OZ. co. OZ Not Reported Ground 23 798. 5. 52 Not Reported Ground 23 896. 5. 52 Not Reported Ground 23 939. 5. 52

Not Reported Ground 24 017. 5. 19 Not Reported Ground

Not Reported Ground 24 140. 5. 52 Not Reported Ground 24 286. 5. 52 Not Reported Ground 24 320. 13

Not Reported Ground 24 338. 5. 52 Not Reported Ground 0. OZ^0 Not Reported Ground 24 420. 5. 52 Not Reported Ground 24 428. 5. 19 Not Reported Ground 24 437.80 132

Not Reported Ground - 24 445. 70 Not Reported orounu OA CTflA Z^ OUO. CO. Not Reported Ground 24 592.85 132 Not Reported Ground 24 599. 5. 19 Not Reported Ground 24 605. 70

Not Reported Ground 24 658. 5. 52 Not Reported vjrounu Z4 Oo i .UU loZ Not Reported Ground 24 879.62 132 Not Reported Ground 24 959. 5. 52 Not Reported Ground 25 224. 5. 52

Not Reported Ground 25 371.95 132 Not Reported Gr<jund 1lOZ^9 Not Reported Ground 25 403.82 132 Not Reported Ground 25 412. 5. 19 Not Reported Ground 25 420. 70

Not Reported Ground 25 684. 5. 52 Not Reported Ground ZO 1 Ul

.

•J, Not Reported Ground 25 877.28 132 Not Reported Ground 25 912.55 132 Not Reported Ground 25 923.90 132

Not Reported Ground 25 942.44 132 Not Reported Ground 0^ZD 071 n*^ V / 1 -UO loZ Not Reported Ground 26 024.73 132 Not Reported Ground 28 268.49 132 Not Reported Ground 29 572.23 132

Not Reported Ground 29 797.36 132 Not Reported Ground OA CO/; OA XoZ Not Reported Ground 30 754.75 132 Not Reported Ground 30 768.28 132 Not Reported Ground 30 784.13 132

Not Reported Ground 30 795.32 132 Not Reported Ground oioi n9/1 UZ'+.'+Z Al 1 59 loZ Not Reported Ground 31 052.99 132 Not Reported Ground 32 192.21 132

j Not Reported Ground 32 446.09 132

1 Not Reported Ground 32 595.16 132

1 Not Reported • Ground 32 827.63 132

1 Not Reported Ground 32 851.00 132

1 Not Reported Ground 32 858.99 132

1 Not Reported Ground 32 953.30 132

46
Nitromethane Spectra) I.ine Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F/ F' F, F MHz ±MHz

171 Not Reported (iround 32 970.81 132 Not Reported (- / ro u n d 32 99S 86 132 Not Reported Ground 33 292.34 132 Not Reported Ground 33 345.34 132 Not Reported Ground 33 376.80 132

Not Reported Ground 33 396.58 132 Not Reported Grou nd 33 477 35 132 Not Reported Ground 33 896.63 132 Not Reported Ground 33 904.84 132 Not Reported Ground 33 908.06 132

Not Reported Ground 33 929.63 132

1Kyi-Fni(J U1 n1 1 H

U

33 984 11 132 Not Reported Ground 33 995.68 132 Not Reported Ground 34 032.79 132 Not Reported Ground 34 040.42 132

Not Reported Ground 35 511.81 132

f . rr» 1 1 n H 35 521.62 132 Not Reported Ground 35 655.46 132 Not Reported Ground 36 815.0 132 Not Reported Ground 36 830.0 132

Not Reported Ground 36 941.21 132

1\ nt RRT^ortfn ( .ml 1 nn 36 954.07 132 Not Reported Ground 36 984.23 132 Not Reported Ground 37 061.79 132 Not Reported Ground 37 210.6 132

Not Reported Ground 37 215.17 132

IMot RpnArtf*n C^round 37 254 66 132 Not Reported Ground 37 622.16 132 Not Reported Ground 37 659.84 132 Not Reported Ground 38 680.78 132

Not Reported Ground 39 531.29 132 Not Reported Ground 07 64,9 o'*^.o^ 64 132 Not Reported Ground 39 804.42 132 Not Reported Ground 39 809.83 132 Not Reported Ground 39 917.60 132

Not Reported Ground 39 942.66 132 Not Reported Ground 40 n^^i 48 132 Not Reported Ground • 40 070.6 132 Not Reported Ground 40 106.6 132 Not Reported Ground 40 229.30 132

Not Reported Ground 40 285.16 132 Mot W f* ririrff^H 1 .mil ti H 40 338 98 132 Not Reported Ground 40 386.20 132 Not Reported Ground 40 411.32 132 Not Reported Ground 40 582.20 132

Not Reported Ground 40 606.69 132 Not Reported Ground 40 682.11 132 Not Reported Ground 40 799.31 132 Not Reported Ground 40 898.49 132 Not Reported Ground 41 040.98 132

I

47
Nitromethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

172 2. 0. 1. 0, Ground 26 572.5 .2 155

2. 0, 1, 0. VTl HI lU 97 SQd R .z9 loo

2. 0, 1- 0. Ground 27 916.7 .2 155 n Ground 27 987.7 .2 155

2, 1. 1; 1. Ground 27 176.6 .2 155

2. 1. <— 1, 1, Ground 27 461.1 .2 155

2, 1. 1, 1, t ^rni i nn 27 470. z.o 9 n 100

2. 1.

j- }' Ground 27 804. 2.0 155

2 I Ground 27 816. 2.0 155

2^ h 1; 1; Ground 27 944. 2.0 155

2, 1. 1, 1, Ground 27 978. 2.0 155

2, 1, •<— 1, 1, ( I ro 1 1 n ri zo98 oz^971 .7Q .z9 100

2, 1, }• }• Ground 28 344. 2.0 155

2. 1 Ground 28 621.6 .2 155

2"

3! 2, I. Ground 33 264. 1.0 155

3, 0. <— 2, 0, Ground . 37 465.3 .2 155

3. 0. 2. 0. Ground 41 792.5 1.0 155

3, 0, 2, 0, Ground 41 827.5 1.0 155

3 0 2 n Ground 41 864. 1.0 155

3!

0"

2! 0, Ground 41 924.8 .2 155

- 3, 0. 2, 0. Ground 42 187.2 .2 155

3, 1, 2. 1, 1 mFi^i 1 n ri \j I tj li 1 lU dfl Q99 Q .z9 loo

3, 1. 2, 1, Ground 41 253.7 .2 155

Q

•J*

11

.

-^^ i. Ground 41 736.0 .2 155

3, 1, 2. 1, Ground 41 745.6 .2 155

3, 1, <— 2, 1, Ground 41 924.9 .2 155

3. 1. 2, 1, 1V 7

_ rt\i 1 {JHim 1 n H dl OQ'i 4. 2 155

3, 1, 2. 1, Ground 42 640. 2.0 155

3 1i

.

9 11

,

Ground 42 906.8 .2 155

3. 1. 2, 1, Ground 42 980.2 .2 155

3. 2. 2, 2, Ground 40 983.2 .2 155

3. 2. <- 2, 2, vTl <J li 1 lU 41 467.2 2 155

3. 2, 2, 2, Ground 41 592.7 .2 155

3, 2, 2, 2. Ground 41 638. 2.0 155

3, 2, 2, 2, Ground 41 856. 1.0 155

3. 2, 2. 2, Ground 41 966. 2.0 155

3, 2. 2. 2. Ground 42 030. 2.0 155

3. 2. 2, 2. Ground 42 391.4 .2 155

48
180 -Methyl Nitrate' Molc^cular Consta/jl luhlc

CH3NO., CslCjv.C^v.Cav) CH,.,ONO.,

Isotopic Species I'l. (;p.

III. No. A (MHz) B(MH/.) C(MHz) D., D.,K K A

C'2H30"'N'-'Oi'' 181 11 79.5.06 M 4 707.52 M 3 438.29 M -.6962 .019

C'2D30"'N'^Oi" < 182 11 030.54 M 4 124.97 M 3 121.87 M

< 183 11 6.57.1 M 4 427.23 M 3 276.39 M

a-C'^H,DO'«N'-'0^'' 184 11 485.2 M 4.524.25 M 3 347.67 M

Id. No. /Xa Debye Debye /Xj. Debye eQq V3 Acc. Ireil QJa d ojh d Ol;. d fajji d

181 3.08 M 0.25 M 0. X 2321 340 1

1. Statistical entropy for this molecule is reported as 72.15 cal/deg. Third law entropy is reported as 75.89 cal/deg. The discrepancy is not understood.

References: ABC: 317 Dj: Djk: k: 317 A: 317

Ijl: 317 eQq: V: 317: I: w: 373

V2 (N02)= 9100 ±2600 cal/mol. Torsional frequency (NO2)=130±20 cm"'. V3(CH3)=2321 cal/mol. Torsional frequency (CH3) = 188,5 cm~'. Constants for excited (NO2) torsional states: for v= 1, Ia = 43.115 amu A-- Ib= 107.463 amu A-, and 1^= 146.850 amu A-;

for v=2, Ia = 43.356 amu A^, 1^= 107.545 amu A-, and 1^= 146.683 amu A^. Ref: 317.

Methyl Nitrate gp^^^^^l ^j^e Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

181 1, 0, 1^ 0, 0, 0 Ground 8 145.90 .2 317

2. 0. 2^ 1. 0, 1 Ground E 2 16 048.11 317

2. 0. 2^ 1. 0. 1 Ground A 2 16 058.80 317

2, 0, 2^ 1, 0, 1 Ground 16 135.85 317

2. 0. 2*- 1, 0, 1 Ground 1 16 138.27 317

2, 0, 2^ 1, 0, 1 Ground 2 16 139.49 317

2. 1. 1^ 1. 1, 0 Ground A 2 17 468.25 317

2. 1. 1<- 1, 1. 0 Ground 2 17 548.41 317

2. 1, 1^ 1, 1, 0 Ground 1 17 555.17 317

2, 1, 1^ 1, 1, 0 Ground 17 560.84 317

2, 1, 2^ 1. 1, 1 Ground 15 022.38 317

2, 1, 2^ 1, 1, 1 Ground 1 15 031.69 317

2, 1, 2<- 1, 1, 1 Ground 2 15 039.95 317

3. 0. 3^ 2, 0, 2 Ground E 2 23 706.45 317

3, 0, 3^ 2, 0, 2 Ground A 2 23 721.64 317

3. 0. 3^ 2, 0, 2 Ground 23 829.45 317

3, 0, 3^ 2, 0, 2 Ground 1 23 834.15 317

3, 0, 3-^ 2, 0, 2 Ground 2 23 837.43 317

3, 0, 3^ 2, 0, 2 Ground 3 23 839.80 317

3, 1, 2^ 2, 1, 1 Ground E 2 26 041.92 317

49
Methyl Nitrate Spectral Line Table

Isotopic Species Id. Rotational ViVi V lu. oStaff late Int Rotor Hyperfine Fre{juency Acc. I\cl. No. Quantum Nos. St3.tC IT' r r _ivi nz

181 o.

11

,

9<^ 9 1 Z, i. 1 Ground A 2 26 101.23 .1 317

0o, 1 9.^ 9 1 Z, i. 1 Ground 4 26 197.05 317

3, 1, 2-^ 2, 1, Ground qo 9A 9riQ 9/1 ZO zUo.Z^ Ql 7 ol / 3, 1, 2^ 2, 1, Ground 9Z 9A 9 1 Q nc; ZD ZIV.UO |

Ql 7 Ol I

*>

*J'. 11 , 9<^ Z* 9 1 Z, i. Ground 11 9AZO 99» ZZO.OZA9 7 01 I

Q

J. 11 , 9^Z^ 9 1 Z^ 1

,

1 Ground 26 237.30 .1 317

ao.11 ^ z9 1

, 1

,

2 Ground A 2 22 340.04 317

3, 1. 3^ 2. 1, 9Z Ground rHi 9Z 99 '\fx^ 70 ZZ oOD. i 7 ^17 Ol / 3. 1. 3^ 2. 1, 9Z Ground 99 ddl ZZ Hb'+l.Do ^1 7 01 / Q 9 9 9 AU Ground ZD9(^ Hztd. U4''*.c5U RH 7 Ol /

3 9 3 Ground 31 652.05 .1 317 4 Q 4-^ 3 Ground E 2 30 997.1 317

4^ 4^ 3, 0,

oo Ground 4

l\ z9 Ol UlU.OZ Ol^1 7I 4, 0, 4^ 3, 0, q Ground 31 1 /to A9 Ol^ 1 7( A 0, u. q Ground 1i Ol31 1lOi.yu c7 on Ol^1 7i

/I 3 Ground 2

' 31 165.00 .1 317

/I 1, 2 Ground E 2 34 546.63 317

4, 1, 3^ 3, 1, 9Z Ground j4' OA 771 ill. .^"Tt AA 01^17/ 4, 1, 4^ 3, 1, q Ground AA 9Z ZV Ooo.OD 1 7 01 / A

i. A ^ 3 1 q Ground r 9Z ZV90 OO i

9Z. 1 7 01 I

/I 11,/I , 3 1 J* 1, 3 Ground 29 765.97 317

4, 1, 4^ 3, 1, 3 Ground 1 29 785.75 317

A4, o

z. z*— 3, z.

1i Ground OO oyo.

Co. 01 / 4, 2, 3^ 3, 2, 9Z Ground q9 qo oZ ^01.00 ^1 7 ol / 4, 0o. l'^ 3, 3. A

u Ground Q9 Qq9 7C OZ Voz. /O 1 7 ol /

4, 1, 4<— 4, 1, Ground 1 9 ^; AO A f\ iz ouy.4u

'\ q 1

ol / 4, 2, 3<— 4, (J, 4 Ground 32 964.20 317

6, 2, 5^ 6, 2, 4 Ground o t)OO.UU 317 Ol / 9, 3, 7^ 9, 3,

/:0 Ground o oUU.O^ 317 01/

C'2D,,0"^N'^0i'' 182 9 Z*^ 1 Ground 14 396.45 317

2, 1. 1^ 1, 1, 0 Ground 15 501.59 317

3, 0, 3^ 2, 0, 9 Ground 91 Q/l 7 7/1 Zl O'* / . /4 q 1

"7 ol / 1, 9^z< 9 1 Z, 1, 1 Ground 9Q 1 Qf^ 9Q Zo loD.zo qi 7 ol / i , 9 1 Z, 1, z9 Ground ZU iOi.Ol ol /

183 9 A 9.^ Z* 1 n 1 , u. 1 Ground 15 280.53 317

2, 1, 1*- 1, 1. A

u Ground 1 f, C r Q AO 10 OOo.Uo

•| 317 ol / 9 \ 1 1 11 Ground 1 A 9C^ on

14- ZOO.O i 317 Ol / 4. 0^ 4^ 3, 0. QO Ground 9Q A90 317 Ol /

a-C'2H,D0"'N"0^'* 184 2, 0. 2^ 1, 0, 1 Ground 15 606.90 •1 317

2, 1. 1^ 1, 1. 0 1 U U 1 1

U

^f, iU 090 7^0.**^ 4.9 317

2, 1, 2^ 1. 1, 1 Ground 14 567.27 317

3. 0, 3^ 2. 0, 2 Ground 23 080.34 317

4. 0. 4^ 3, 0. 3 Ground 30 217.30 317

50
190- Methyldifluorosilane Molecular Constant I aM.- Methyldifluorosilicane

CH^FjSi Cs(C3v,Q CHsSiHFj

Isotopic Species Pt. Cr,

Id. Nn0. A (MHz) B(MHz) C (MHz) Dj D,K K A

ni2ij c:28iJiri9 A c 1 Ql ly 1 6 847.25 M 6 120.40 M 3 755.61 M

L. rlsoi rlr2 c 1 09 6 846.33 M 6 120.40 M 3 755.61 M

pizo c:291JF»9 lit 2

1 0"^

1 Vo 6 835.39 M 6 111.15 M 3 755.66 M

L. ii3'5i or

1 Qd, 6 825.69 M 6 102.07 M 3 755.64 M

P1314 C:28lJiri9 A 6 843.27 M 5 897.90 M 3 671.67 M

pisiJ c:28iJri9 r c 1iVU 6 842.33 M 5 897.90 M 3 671.67 M

O30I ur 2 -A p 1 Q7 6 556.15 M 5 885.07 M 3 754.35 M

C'^HjSpsDFJ^-E Cs 198 6 555.19 M 5 885.07 M 3 754.35 M

C'^DaSi^^DF^'' Cs 199 6 258.43 M 5 002.52 M 3 377.71 M

C'^DjSi^^DFI" Cs 201 6 276.31 M 4 996.50 M 3 377.63 M

s-C'^H^DSi^^HFJ" Cs 203 6 '4.16 M 5 774.09 M 3 663.21 M

a-C'^H^DSi^^HFJ^ c, 204 6. 796.64 M 5 737.71 M 3 596.89 M

Id. No. /Lia Debye IXiy Debye /u-t Debye eQq V3 Acc. Ired COg d OJh d oj, d ojj d

191 2.01 M 0. X 0.62 M 1255 30

References: ABC: 23, 29, 234, 290 Dj

At: 234 eQq

Djk:V: 234

k:

I:

51
Methyldifluorosilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

191 2. 0, 2^ 1, 0, 1 Ground A 0 17 970.57 234

2, 1, 1<— 1, 0, 1 Ground A 0 25 208.47 234

2, 1, 1^ 1, 1, 0 Ground A 0 22 116.80 234

2, 1, 2^ 1, 1, 1 Ground A 0 17 387.22 234

2, 2. 0^ 1, 1. 0 Ground A 0 26 078.78 234

2. 2, 1^ 1, 1, 1 Ground A 0 26 662.15 234

Q A o ^ o r\ o

3, 0, o<— /, 0, 2 Ground A 0 25 304.74 234

3, 1, 2^ 2, 1, 1 Ground A 0 31 124.90 234

3, 1, 3^ 2, 1, 2 Ground A 0 25 179.49 234

3. 2, 1^ 2, 2, 0 Ground A 0 33 951.02 234

3. 2, 2^ 2, 2. 1 Ground A 0 29 627.82 234

6, 1, 6*— 6, 1, 5 Ground A 0 29 667.8 154

7, 2, 6^ 7, 2, 5 Ground A 0 29 552.40 154

7, 3, 5^ 7, 3, 4 Ground A 0 23 745.10 154

8, 3, 6^ 8, 3, 5 Ground 29 360.07 154

8, 4, 5^ 8, 4, 4 Ground 0 - 23 128.45 154

9, 4, o«— 9, 4, 5 Ground on ACO OA 29 052.30 154

9. 5. 5^ 9, 5, 4 Ground A 0 22 051.38 154

10, 5. 6^10, 5, 5 Ground 28 540.65 154

10, 6, 5<-10, 6, 4 Ground A 0 20 369.85 154

11, 6, 6^11, 6, ,5 Ground A 0 27 688.80 154

11, 7, 5-<— 11, 7, 4 Ground A 0 18 063.86 154

12, 7, 6^12, 7, 5 Ground A 0 26 319.80 154 Not Reported Ground 17 416.0 154 Not Reported Ground 17 462.4 154

- Not Reported Ground 17 647.2 154

INot Reported Ground 17 717.1 Not Reported Ground 17 719.3 154 Not Reported Ground 17 817.1 154 Not Reported Ground 18 147.8 1.54

Not Reported Ground 18 150.2 154 Not Reported Ground 1 O OAO O 18 292.3 154 Not Reported Ground 18 403.1 154 Not Reported Ground 18 761.6 154 Not Reported Ground 24 060.7 154

Not Reported Ground 24 064.1 154 Not Reported Ground

Not Reported Ground 24 092.5 154 Not Reported Ground 24 236.3 154 Not Reported Ground 24 238.2 154

Not Reported Ground 24 267.4 154 Not Reported Ground 0/1 OQO Q z4 ZoZ.o Not Reported Ground 24 293.7 154 Not Reported Ground 25 069.6 154 Not Reported Ground 25 145.6 154

Not Reported Ground 25 173.4 154 Not Reported Ground 25 221.9 154 Not Reported Ground 25 383.5 154 Not Reported Ground 25 598.7 154 Not Reported Ground 25 649.2 154

52
Methyldifluorosilane Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n

riype F'

rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

C'^HjSi^WJ^-A 191 Not Reported Ground 27 688.9 1.54 Not Reported Ground 28 871.5 154 Not Reported Ground 28 873.4 1.54 Not Reported Ground 28 910.4 154 Not Reported Ground 28 914.3 154

Not Reported Ground 29 018.2 1.54 Not Reported Ground 29 088..

5

154 Not Reported Ground 29 204.6 1.54 Not Reported Ground 29 219.2 1.54 Not Reported Ground 29 336.4 154

INot Reported Ground 29 343.8 154 Not Reported Ground 29 625.6 1.54

C'2H3Si2«HFJ''-E 192 2, 0. 2^ 1, 0. 1 Ground E 0 17 970.08 2.34

2, 1, 1^ 1, 0, 1 Ground E 0 25 207.67 234

2, 1, 1^ 1, 1, 0 Ground E 0 22 116.80 234

O 1 0,£ 1 1 i., 1, 1, 1, 1 Ground E 0 17 387.22 234

2, 2, 0^ 1, 1, 0 Ground E 0 26 076.68 234

2, 2, 1^ 1, 1, 1 Ground E 0 26 659.23 234

3, 0. 3^ 2, 0, 2 Ground 17 (\ )L U

OC QAO ri Zo4

3, 1, 2*- 2, 1, 1 Ground E 0 31 123.75 234

3, 1, 3*— Z, 1, o

z Ground E 0 25 180.66 234

3, 2, 1^ 2, 2, 6 Ground E 0 33 951.02 234

3, 2, 2-^ 2, 2, 1 Ground E 0 29 627.82 234

6, 1, 6^ 6, 1, 5 Ground T? A L I) OA O 29 662.8 154

7, 2, 6*— 7, 2, 5 Ground E 0 29 549.49 154

7, 3, 5^ 7, 3, 4 Ground E 0 23 744.20 154

9, 5, 5^ 9, 5, 4 Ground E 0 22 054.51 154

10, 6, .5^10. 6, 4 Ground E U OA Ar\ ZU 61 /.40 154

11, 6, 6^11, 6, 5 Ground E 0 27 690.15 154

11, 7, 5<—11, 7, 4 Ground E 0 18 074.90 154

12, 7, 6^12, 7, 5 Ground E 0 26 326.02 154

C'^HsSi^'HFl^ 193 2, 0, 2^ 1, 0, 1 Ground 0 17 959.50 234

2. 1. 1^ 1, 1. 0 Ground E 0 22 089.10 234

2, 1, 1^ 1, 1. 0 Ground A 0 22 089.10 234

2, 1, 2^^ 1. 1, 1 Ground A 0 17 378.12 234

2, 1, 2^ 1. 1. 1 Ground E 0 17 378.12 234

3, 0. S'^ 2, 0, 2 Ground E 0 25 292.55 234

3, 0, 3^ 2. 0, 2 Ground A 0 25 294.58 234

3, 1, 2'^ 2, 1, 1 Ground 0 31 091.11 234

3, 1, 3^ 2, 1, 2 Ground A 0 25 170.35 234

3, 1, 3^ 2. 1. 2 Ground E 0 25 171.55 234

o, z, /<— Z, Z, 1 Ground A 0 29 600.40 234

3, 2, 2^ 2, 2, 1 Ground A 0 29 600.40 234

C'^HjSi^HFI" 194 2, 0, 2^ 1, 0, 1 Ground 0 17 949.49 234

2, 1, 1^ 1, 1, 0 Ground AA A(J 1 22 061.84 234

2, 1, 1«- 1, 1, 0 Ground E 0 1 22 061.84 234

3. 0, 3^ 2, 0, 2 Ground E 0 25 282.51 234

3, 0, 3<- 2, 0. 2 Ground A 0 25 284.83 234

3, 1, 3^ 2. 1, 2 Ground 0 1 25 160.94 234

749-587 0-69—

5

53
Methyldifluorosilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

194 oo. z. 1 Ground A 0 29 573.50 234

3. 2. 2^ 2, 2, 1 Ground E 0 29 573.50 234

C'''H3Si2"HF^^-A 195 2, 0, 2^ 1. 0. 1 Ground A 0 17 615.39 234

Z. 1.

11, nu Ground A 0 Zl ooo.oi 9^/1 Zo4'

2, 1, 2«- 1, 1, 1 Ground A 0 16 912.91 234

3, 0, 3^ 2. 0, 2 Ground AA

Au 24 794.63 234

3, 1. 2<- 2. 1. 1 Ground A 0 30 420.24 234

3, 1, 3^ 2. 1. 2 Ground 0 24 592.56 234

0o. z. 1^ z. z. 0 Ground A 0 32 622.61 234

3, 2, 2^ 2, 2, 1 Ground A 0 28 708.60 234

C'-'H3Si'^»'HFJ'*-E 196 o

Z, Au. Z< i. nu. 1 Ground E 0 17 614.88 234

2, 1. 1^ 1. 1. nu Ground E 0 91 ^7 Zl oOo.Oi ZO'*

2, 1, 2^ 1. 1, 1 Ground 17n, A

u 16 912.91 234

3, 0, 3^ 2, 0, 2 Ground E 0 24 793.40 234

3. 1. 2^ 2, 1, 1 Ground E 0 ZO^

o

z. oZ, 0 Ground E 0 32 622.61 234

3, 2, 2<- 2, 2, 1 Ground E 0 28 708.60 234

C'-HjSi^-DFf-A 197 2, 0, 2^ 1, 0, 1 Ground A 0 17 684.10 234

2, 1, 1*- 1. 1. U Ground A 0 9'^d. Zo4*

2, 1, 2^ 1. 1. 1 Ground A 0 17 148.13 234

A

o* Z, Au. 2 Ground A 0 25 032.63 234

3, 1. 2^ 2, 1, 1 Ground A 0 30 288.46 234

3. 1, 3^ 2. 1. 2 Ground A 0 24 914.95 234

3. 2, 1^ 2, 2,

r\u Ground A 0 OZ39 OUO Qfl? 71

tZo^

3, 2, 2<- 2, 2, 1 Ground A 0 28 917.93 234

7, 2. 6-^ 7, 2, 5 Ground A 0 26 996.8 154

11, 6. 6^11. 6, 5 Ground A 0 24 904.4 1.54

12. 7. 6^12, 7, 5 Ground A 0 23 583.7 154 Not Reported Ground A 0 10 VDZ.V 1104- '^d. Not Reported Ground A 0 21 661.4 154 Not Reported Ground A 0 21 763.5 154 Not Reported Ground A 0 21 766.5 154

Not Reported Ground A 0 27 262.5 154 Not Reported Ground A 0 97 979 n Not Reported Ground A 0 28 849.1 154 Not Reported Ground A 0 28 853.3 154 Not Reported Ground A 0 29 911.8 154

C'-HaSi-^DF^^-E 198 2. 0, 2^ 1. 0. 1 Ground E 0 17 683.49 234

2, 1, 1*- 1, 1, A

(J Ground E 0 Zl H'Uy.DO

2, 1, 2^ 1. 1. 1 Ground E 0 17 148.13 234

3. 0. 3^ 2, 0, 2 Ground E 0 25 030.55 234

3, 1, 2<- 2, 1. 1 Ground E 0 30 287.49 234

3, 1, 3^ 2, 1, 2 Ground E 0 24 916.13 234

3, 2, 1^ 2, 2, nu Ground E 0 OZQO OUiJ. Qfl^ 71i 1 3, 2, 2^ 2, 2, 1 Ground E 0 28 917.93 234

7, 2. 6^ 7. 2, 5 Ground E 0 26 993.5 154

11. 6. 6^11. 6. .5 Ground E 0 24 906.3 154

12. 7. 6^12, 7, 5 Ground E 0 23 589.7 154

54
Methyldifluorosilane Spectral lAnc lahle

Isotopic Species Id.

iNO. Rotational Quantum Nos.

Vib. i5tate Int. Kotor

State n c

iype

rc

rfine c r

[

r requency MHz

AAcc.

_l_lV/f IT„ ±Mnz

Kei.

199 2, 0, 2<— 1, 0, 1 Ground 15 903.16 290

2, 1, 1^ 1, 0, 1 Ground 21 292.84 • 1 290

2, 1, 1^ 1. 1, 0 Ground 18 38.5.27 290

2, 1, 2^ 1, 1, 1 Ground 15 135.65 290

'

2, 2, 0^ 1, 1, 0 Ground 23 091. .51 290

2, 2, I*— 1, 1, 1 Ground 23 858.82 290

3, 0, 3<— 2, 0, 2 Ground 22 627.94 290

3, 1, 2*— 2, 1, 1 Ground 26 796.36 ;j 290

3, 1, 3^ 2, 1, 2 Ground 22 255.23 •1 290'

3, 2, 1^ 2, 2, 0 Ground 27 653.13 •1 290

3, 2, 2<— 2, 2, 1 Ground 25 140.47 .1 290

C'^DjSi^DFI^ 201 2, 0, 2<- 1, 0, 1 Ground 15 894.60 2. 290

2, 1, 1-^ 1, 1, 0 Ground 18 367.14 2. 290

3, 0, 3-^ 2, 0, 2 Ground 11 620.04 2. 290

3, 1, 3<- 2, 1, 2 Ground 22 247.70 2. 290

3, 2, 2<- 2, 2, 1 Ground o c TOO or» 25 122.39 2. 290

C'^DaSi^^DFJ" 202 2, 0, 2<— 1, 0, 1 Ground 15 885.81 2. 290

2, 1. 1^ 1, 1, 0 Ground 18 349.40 2. 290

3, 1, 3^ 2, 1, 2 Ground OO o /I r\ /; o 22 240.68 2. 290

3, 2, 2^^ 2, 2, 1 Ground oc 1 no or\ 25 103.39 2. 290

s-C'^HjDSPHFJ* 203 1, 0, 1<— 0, 0, 0 Ground 9 437.10 2. 290

2, 0, 2*- 1, 0, 1 Ground 17 447.21 2. 290

2, 1, 1-^ 1, 1, 0 Ground 20 985.49 o

z. OOA

2, 1, 2^ 1, 1, 1 Ground lo 106.1 Z z. zyu

3, 0, 3^^ 2, 0, 2 Ground OA /;OA /I O 24 620.48 o

/. OOA zyu

3, 1, 2«— 2, 1, 1 Ground 29 966.89 2. 290

3, 1, 3^^ 2, 1, 2 Ground 24 417.34 2. 290

3, 2, 1^ 2, 2, 0 Ground 32 002.61 2. OAA 290

3, 2, 2<^ 2, 2, 1 Ground OO oil £.r\ 28 311.60 2. onA 290

4, 1, 4<- 3, 1, 3 Ground 31 824.00 o

z. OOA zyu

a-C'^HjDSi^^HFJ' 204 1, 0, 1<— 0, 0, 0 Ground 9 334.73 2. 290

2, 0, 2^^ 1, 0, 1 Ground 17 281.36 2. 290

2, 1, l'^ 1, 1, 0 Ground 20 810.02 2. 290

2, 1, 2^ 1, 1, 1 Ground 16 528.39 2. OOA zyu

3, 0, S'^ 2, 0, 2 Ground 0/1 OOC OA 24 325.20 2. OOA zyu

3, 0, 3^ 2, 0, 2 Ground 24 328.18 2. 290

3, 1, 2*— 2, 1, 1 Ground 29 787.24 2. 290

3, 1, 2<- 2, 1. 1 Ground 29 789.34 2. 290

3, 1, 3^ 2. 1, 2 Ground 24 078.27 2. 290

3, 1, 3^ 2, 1, 2 Ground 24 083.22 2. 290

3, 2, 1^ 2, 2, 0 Ground 31 678.18 2. 290

3, 2, 2^ 2, 2, 1 Ground 28 004.28 2. 290

4. 1, 4^ 3, 1, 3 (Ground 31 370.12 2. 290

1. Reassignments of two lines which the authors refer to as 2n^lii and 3|3<—2ii have been made, since these assignments are forbidden. These hnes are taken to be 2i2*— In and 3|2<—2i2 respectively.

55
210 - Methanol Molecular Constant Table Methyl Alcohol CH,0 Cs(C3v,Cs) CH3OH

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C(MHz) D,,K K A

C'2H30"^H Cs 211 127 602.57 M 24 629.2 M 23 761.0 M 0.3681 -.98 C'^H30"^D Cs 212 109 536.86 M 23 395.3 M 21 968.5 M

V_-. 1 ijj V-/ J. X c 213 127 600.63 M 24 018.3 M 23 191.9 M

Cs 214 70 511.82 M 19 822.8 M 19 256.0 M

Cs 215 109 534.00 M 22 794.7 M 21 438.0 M

C'^D30'^D Cs 216 64 627.78 M 18 868.0 M 17 928.8 M

Cs 217 127 333.42 M 23 590.4 M 22 784.1 M

1

Id. No. /^a Debye ju,h Debye /Xe Debye eQq V3 Acc. I red cob d cUc d coa d

211 0. X 1.440 M 0.885 M 1070

212 371 5

213 0. X 1.439 M 0.886 M

217 0. X 1.437 M 0.890 M

References: ABC: 122 Dj: D,k: 3.52 k: 148 A:

;u.: 54

' eQq: V: 148, 344 I: w:

Add. Refs.: 5, 6, 12. 14, 15, 22, 24, 25, 27, 35, 39, 51, 52, 54, 60, 72, 105, 120, 133, 169, 192; 208, 238, 240, 310, 351', 386

Torsional frequency = 270 cm '. Ref: 192.

r

56
Methanol

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f; HypeF'

rfine

Fl F

Frequency

MHz

Acc. ±MHz

Kef.

C'2H30"'H 211 1, 0, 1^ 0, 0, 0 Ground A 2 48 178.0 1. 121

1, 0, 1^ 0, 0, 0 (J round E 2 48 192.12 .5 121

1, 0, 1^ 0, 0, 0 Ground E 1 48 247.89 .5 121

1, 0, 1«— 0, 0, 0 (iround A 1 48 257.49 .5 121

1, 0, 1^ 0, 0, 0 Ground A 0 48 372.60 .5 121

1, 0, 1^ 0, 0, 0 Ground E 0 48 377.09 .5 121

1, 0, l'^ 0, 0, 0 49 867.2 396

2. 2, ^ 2, 1, Ground EH 0 24 934.38 .1 37

2, 1, «- 3, 0, Ground E(-) 0 19 967. 72

3, 1, ^ 2, 0, Ground E(+) 0 12 178.6 • 1 310

3, 2, ^ 3, 1, Ground EH 0 24 928.70 37

4, 0, 3, 1, Ground EH 0 28 316.03

•} 37

4, 1, *— 3, 0, Ground EH 0 36 169.24 !i 37

4, 2, ^ 4, 1, Ground EH 0 24 933.47 •1 37

4, 3. ^ 5, 2. Ground 0 10 002. 133

5, 2, 3<— 4, 3, 2 Ground 9 978.6 280

5, 2, 4<— 4, 3, 1 Ground 10 058.3

•} 280

5, 1, ^ 5, 1, Ground 12 511.0 .1 310

5, 2, ^ 5, 1, Ground EH 0 24 959.08 •1 37

6. 2, ^ 5, 3, Ground A 0 38 293.5 1 37

6, 2, 5, 3, Ground A 0 38 452.69 37

6, 2, 6, 1, Ground EH 0 25 018.14 J 37

7, 2, <- 7, 1, Ground EH 0 25 124.88 !i 37

8, 2, 7, 1, Ground EH 0 37 703.72 •1 37

8, 2, ^ 8, 1, Ground EH 0 25 294.41 •1 37

9, 1, 8, 2, Ground EH 0 9 936.2

•} 310

9, 2, 9, 1, Ground EH 0 25 541.43 37

10, 2, *-io. 1, Ground EH 0 25 878.18 A 37

11, 2, ^11, 1, Ground EH 0 26 313.11 1 37

12, 2, ^12, 1, Ground EH 0 26 847.27 1 37

13, 2, ^13, 1, Ground EH 0 27 472.54

•J 37

14, 2, *-14, 1, Ground EH 0 28 169.31 37

15, 2, «—15, 1, Ground EH 0 28 905.70 '.\ 37

16, 2, ^16, 1, Ground EH 0 29 636.91 •1 37

17, 2. ^17, 1, Ground EH 0 30 308.00 •1 37

18, 2, <—18, 1, Ground EH 0 30 858.40 J

37

19, 2, •^19, 1, Ground EH 0 31 226.70 37

20, 2, *-20, 1, Ground EH 0 31 358.31 .1 37

21, 2, ^21, 1, Ground EH 0 31 209.75 •1 37

22, 2, ^22, 1, Ground EH 0 30 752.26 •1 37

23, 2, «-23, 1, Ground EH 0 29 973.06 }

37

24, 2, ^24, 1, Ground EH 0 28 874.45 37

25, 2, <-25, 1, Ground EH 0 27 470.99 .1 37

o

z, zo, 1, Ground u 25 787.12 •1 37

27, 2, ^27, 1, Ground EH 0 23 854.25 •1 37

28, 2, ^28, 1, Ground EH 0 21 708.68 j

37

29, 2, ^29, 1, Ground EH 0 IV oVU. lo o I 30, 2, «-30, 1, Ground EH 0 16 941.6 37

31, 2, ^31, 1, Ground EH 0 14 407.8 310

32, 2, ^32, 1, Ground EH 0 11 841.9 310

57
Methanol

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. Mo. Quantum Nos. State n F' F MHz ±MHz

/"^ 1 o.T T / \ 1 T T C'^H30'*'H 211 33, 2, <—33, 1, Ground 0 8 198. 133

2, , ^ 1, , Ground 8 380. 133

8, , ^ 7, , Ground 9 960. 133

12, , -^11, , Ground 7 816. 133

14, , <—13, , Ground 16 395. 133

Not Reported Ground 7 587. 133 Not Reported Ground 7 680. 133 Not Reported Ground 11 050.5 .1 310 Not Reported Ground 12 229.4 •1 310 Not Reported Ground 12 770.9 1 310

Not Reported Ground 14 084.8 310 Not Reported Ground 14 300.3 ;} 310 Not Reported Ground 14 317.6 ^1 310 Not Reported Ground 15 214.1 •1 310 Not Reported Ground 15 303.4 •1 310

Not Reported Ground 16 395.8 5. 52 Not Reported Ground 16 556. 5. 52 Not Reported Ground 17 507. 5. 52 Not Reported Ground 17 514. 133 Not Reported Ground 17 911.1 .1 37

Not Reported Ground 18 161.4 5. 52 Not Reported Ground 18 222. 133 Not Reported Ground 18 266.4 5. 52 Not Reported Ground 19 139. 5. 52 Not Reported Ground 19 162. 133

Not Reported Ground 19 252. 133 Not Reported Ground 20 171.07 .1 37 Not Reported Ground 20 346.83 .1 37 Not Reported Ground 20 898. 5. 12 Not Reported Ground 20 908.87 .1 37

Not Reported Ground 20 970.65 .1 37 Not Reported Ground 20 989. 5. 12 Not Reported Ground 21 244.2 .1 37 Not Reported Ground 21 550.31 .1 37 Not Reported Ground 22 095. 5. 12

Not Reported Ground 23 033. 5. 12 Not Reported Ground 23 121.20 .1 37 Not Reported Ground 23 347.53 .1 37 Not Reported Ground 23 415. 5. 12 Not Reported Ground 23 444.82 .1 37

Not Reported Ground 23 450. 5. 12 Not Reported Ground 23 457. 5. 19 Not Reported Ground 23 861. 5. 12 Not Reported Ground 24 040. 5. 12 Not Reported Ground 24 081. 5. 12

Not Reported Ground 24 317. 5. 12 Not Reported Ground 9zl 7 Z** DOO. L 1 O^7i Not Reported Ground 24 901. 5. 19 Not Reported Ground 24 913. 5. 19 Not Reported 24 926. 5. 15

58
Methanol Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f;

fiype

F'

rfinc

F, F

Frequency

MHz

Acc. ±MHz

Ref.

C'^H30"^H 211 Not Reported Ground 24 954.6 12 Not Reported Ground 24 977.

r0. 19 Not Reported Ground 24 997. 5. 19 Not Reported (iround 25 017.8 12 Not Reported (iround 25 050. 5. 12

Not Reported (Ground 25 056.31 .1 37 Not Reported (/round c

a.

1 <\ ly Not Reported Ground 25 151. 5. 19 Not Reported Ground 25 289. 5. 19 Not Reported Ground 25 300.3 12

Not Reported Ground 25 312. 5. 19 Not Reported Ground ZD OZZ.VO 1

. 1 O I Not Reported (Jround 25 332. 5. 19 Not Reported (iround 25 349. 5. 19 Not Reported Ground 25 385. 5. 12

Not Reported Ground 25 796. 5. 12 Not Reported Ground ZD oVcS.

C

O. IZ Not Reported Ground 26 120..50 .1 37 Not Reported Ground 26 550.15 .1 37 Not Reported Ground 26 562. 5. 12

Not Reported Ground 26 778.9 .1 37 Not Reported Ground OA 7QQ 1 Q Zt3 /oo.lo . 1 O ( Not Reported Ground 26 854. 13 Not Reported Ground 27 227.02 .1 37 Not Reported Ground 27 283.29 .1 37

Not Reported Ground 27 450. 13 Not Reported Ground on "700 1 .1 Not Reported Ground 27 817.50 .1 37 Not Reported Ground 27 820.87 .1 37 Not Reported Ground 28 119.5 .1 37

Not Reported Ground 28 500. 13 Not Reported Ground ZO DOU. Not Reported Ground 28 969.9 .1 37 Not Reported Ground 29 113.76 .1 37 Not Reported Ground 29 889.33 .1 37

Not Reported Ground 29 950. 13 Not Reported Ground oo t^no AA oU O/o.OO 1 .1 6

1

Not Reported Ground 30 693.42 .1 37 Not Reported Ground 31 673.05 .1 37 Not Reported Ground 31 757.42 .1 37

Not Reported Ground 31 977.82 .1 37 Not Reported Ground 61 6l'4.6l .1 Not Reported Ground 32 398.44 .1 37 Not Reported Ground 33 089.91 .1 37 Not Reported Ground 33 414.1 .1 37

Not Reported Ground 33 566.20 .1 37 Not Reported Ground 33 568.2 .1 37 Not Reported Ground 33 691.63 .1 37 Not Reported Ground 33 693.74 .1 37 Not Reported Ground 34 001.35 .1 37

59
Methanol Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

211 Not Reported Ground 34 003.69 .1 37 Not Reported Ground cJ4 ZOO.91 .1 37 Not Reported Ground 34 417.86 .1 37 Not Reported Ground 35 161.6 .1 37 Not Reported Ground 35 478.55 .1 37

Not Reported Ground 35 738.32 .1 37 Not Reported 36 240. 396 Not Reported Ground 36 248.14 .1 37 Not Reported Ground 37 044.68 .1 37 Not Reported 37 690. 396

Not Reported 38 290. 396 Not Reported JO 1 5 c OO ODD. 396 Not Reported 38 445. 396 Not Reported 42 280. 396 Not Reported 44 100. 396

Not Reported • 46 610. .396 Not Reported 47 870. 396 Not Reported 48 010. 396 Not Reported 48 260. 396 Not Reported 48 406. 396

Not Reported 48 707.7 396 Not Reported 49 032. 396 Not Reported 49 750. 396

212 1. 0. 1^ 0, 0, 0 Ground A 2 45 189.46 1.0 121

1, 0, 1<— 0, 0, (J Ground 17 O

Jl z l.U 1 0

1

Izl

1, 0. 1^ 0, 0, 0 Ground E 1 45 259.44 1. 121

1, 0, 1^ 0, 0, 0 Ground A 1 45 265.78 1. 121

1, 0. 1^ 0, 0, 0 Ground A 0 45 344.30 1. 121

1, 0, 1-^ 0, 0, 0 Ground E 0 45 359.43 1. 121

1, 0, 1*— 0, 0, 0

/IT o cn T 47 c>59.7 396 Not Reported 47 052. 396 Not Reported 47 266. 396 Not Reported 47 346. 396

213 1, 0, 1^ 0, 0, 0 Ground A 2 47 019.5 1.0 121

1, 0, 1<— 0, 0, 0 Ground T? O h z 47 0^0.16 .5 121

1, 0. 1<- 0. 0, 0 Ground E 1 47 083.82 .5 121

1, 0, 1<- 0, 0, 0 Ground A 1 47 094.11 .5 121

1, 0, 1^ 0, 0, 0 Ground A 0 47 205.20 .5 121

1, 0, 1^ 0, 0, 0 Ground E 0 47 209.63 .5 121

1, 0, 1<— 0, 0, 0 48 529.6 396

2, 2, <- 2, 1, Ground EH 0 27 052.97 37

3. 2, ^ 3, 1, Ground EH 0 27 047.19 .1 37

4, 2, <- 4, 1, Ground EH 0 27 050.45 > .1 37

5. 2, <- 5. 1, Ground EH 0 27 072.17 •1 37

6, 2, 6, 1, Ground EH 0

:}

Q7O ( 7, 2, 7, 1, Ground EH 0 27 215.60 37

8, 2, ^ 8, 1, Ground EH 0 27 364.12 37

9. 2. ^ 9, 1. Ground EH 0 27 581.65 37

10, 2, ^10, 1, Ground EH 0 27 880.04 .1 37

60
Methanol

Spectral Line Table

Isotopic Species Id. No.Rotational Quantum Nos.

Vib. State Int. Rotor

State n F",'

1

Hyp(

F'

;rfin( FI FFrequency

MHz

Acc. ±MH-/,

Ref.

C'^HjO'-'H 213 11. 2, ^11. 1, Ground EH 0 28 267.71 .1 37

12, 2, *-12, 1, Ground E(-) 0 28 747.67 37

13, , •^12, , Ground 26 979.03 • 1 37

13, , ^12, , Ground 26 980.40 • 1 37

13, . ^12, , Ground 27 104.80 1 37

13, , ^12, , Ground 27 105.93 .1 37

13, 2, <—13, 1, Ground E(-) 0 29 315.20 37

14, 2, <—14, 1, Ground EH 0 29 955.72 •1 37

15, 2, ^15, 1, Ground EH 0 30 643.69 • 1 37

16, 2, ^16, 1, Ground EH 0 31 342.31 1 1 37

17, 2, ^17, 1, Ground EH 0 32 004.43 • 1 37

18, 2, *-18, 1, Ground EH 0 32 575.53 37

19, 2, *-19, 1, Ground EH 0 32 998.94 1 37

20. 2, ^20. 1, Ground EH 0 33 220.05 1 37

21. 2. ^21. 1. Ground EH 0 33 192.97 • 1 37

22, 2, ^22, 1, Ground EH 0 32 883.47 •1 37

23, 2, ^23, 1, Ground EH 0 32 271.10 37

24, 2, <-24, 1, Ground EH 0 31 350.19 • 1 37

25, 2, ^25, 1, Ground EH 0 30 127.80 I 37

26, 2, ^26, 1, Ground EH 0 28 621.04 • 1 37

27, 2. ^27. 1. Ground EH 0 26 855.01 1 37

28. 2. ^28. 1. Ground EH 0 24 860.62 37

29, 2. ^29. 1, Ground EH 0 22 672.90 1 37

30, 2. ^30, 1, Ground EH 0 20 329.32 • 1 37

31, 2. ^31, 1. Ground EH 0 17 870.5 •1 37

Not Reported Ground 28 869.59 • 1 1 37 Not Reported 47 080. 39o Not Reported 47 760. 396 Not Reported 47 899.3 1 396 Not Reported 47 950.1 1 396

Not Reported 49 070.8 1 396

C'2D30"^H 214 1, 0. 1^ 0, 0, 0 Ground A 2 38 923.97 | .5 I 121

1. 0, 1«- 0, 0, 0 Ground E 2 38 928.89 .5 1 121

1. 0, 1^ 0, 0, 0 Ground E 1 38 972.05 1 .5 j 121

1. 0. 1^ 0. 0. 0 Ground A 1 38 982.88 .5 1 121

1. 0. 1^ 0. 0, 0 Ground A 0 39 066.21 .5 121

1. 0, 1^ 0. 0, 0 1 Ground E 0 39 069.25 j .5 1 121

2. . ^ 1. . Ground 37 229.8 1 .5 121

2. . ^ 1. . Ground 40 649.5 .5 121

2, , ^ 1. • Ground 43 453.7 .5 1 121

4, , ^ 3, . Ground 35 748.2 1 .5 1 121

5, , ^ 4, , Ground 43 .501.5 I .5 j 121 Not Reported | Ground 17 775.1 .5 121 Not Reported | Ground 17 839.1 .5 121 Not Reported | Ground 17 918.9 .5 121 Not Reported [ Ground 18 081.2 .5 121

Not Reported | Ground 18 097.0 1 .5 121 Not Reported Ground 18 227.3 .5 1 121 Not Reported ] Ground | 18 395.6 .5 1 121

61
Methanol

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

214 Not Reported Ground 18 588.6 .5 121 Not Reported Ground .5 121 Not Reported Ground 18 923.7 .5 121 Not Reported Ground 19 294.5 .5 121 Not Reported Ground 19 844.8 .5 121

Not Reported Ground 19 905.8 .5 121 Not Reported Oround c.0 1 0

izl Not Reported Ground 20 642.5 .5 121 Not Reported Ground 21 236.4 .5 121 Not Reported Ground 21 519.5 .5 121

Not Reported Ground 22 174.1 .5 121 Not Reported Ground DDU.O 191 XZ

Not Reported Ground 23 313.9 .5 121 Not Reported Ground 23 750.0 .5 121 '

1

1 . Not Reported Ground 24 691.9 .5 121

1 - ,

•

- Not Reported Ground . 25 133.2 .5 121 Not Reported Ground ZD / C.O 1 91 Izl Not Reported Ground 26 715.3 .5 121 Not Reported Ground 27 982.7 .5 121 Not Reported Ground 28 032.7 .5 121

Not Reported Ground 28 311.9 .5 121 Not Reported Ground Zo oil./ r

.O 1 91 IZl Not Reported Ground 35 805.7 .5 121 Not Reported Ground 35 810.8 .5 121 Not Reported Ground 36 332.7 .5 121

Not Reported Ground 36 422.9 .5 121 Not Reported Ground /I no o c.O 1 Ol IZL Not Reported Ground 36 663.0 .5 121 Not Reported Ground 37 322.8 .5 121 Not Reported Ground 37 462.6 .5 121

Not Reported Ground 37 900.0 .5 121 Not Reported Ground oo Udz.O .o 191 IZ

Not Reported Ground 38 132.8 .5 121 Not Reported Ground 38 967.6 .5 121 Not Reported Ground 40 229.8 .5 121

Not Reported Ground .0 191 Not Reported Ground 42 163.8 .5 121 Not Reported Ground 42 292.1 .5 121 Not Reported Ground 43 325.0 .5 121

215 1, 0. 1^ 0, 0, 0 Ground A 2 44 076.55 .5 121

1, U, 1*— U, U, U Ground IT 0 C

.0 191

1, 0, 1^ 0, 0, 0 Ground E 1 44 144.06 .5 121

T1, A

U,

1i'^j: AAA u, u, u Ground AA 1i A A 1 c: 1 AO c

.0 1 91 IZl

1, 0, 1^ 0, 0, 0 Ground A 0 44 228.26 .5 121

1

1, 0. 1«- 0, 0. 0 Ground E 0 44 241.43 .5 121

' C'^DjC'D 216 1. 0. 1^ 0. 0, 0 Ground A 2 36 673.93 .5 121

1. 0, 1^ 0, 0, 0 Ground A 1 36 730.94 .5 121

1, 0. 1^ 0. 0, 0 Ground A 0 36 799.01 .5 121 Not Reported 30 505. 396

r

62
Methanol Spectral Line Table

Isotopic Species TH Rotational Vih Statp nil. Int l\UlUi ri rtt nr Hyperfine Ref. Nn Quantum Nos. Qt;4t^ n F r MHz ±MHz

216 INOl R A 30 600. 396

l>OI Reported 31 140. 396 Not Reported 32 190. 396 Not Reported 32 325. 396 Nnt I > Ol Reported 32 790. 396

Nnt R A rie ported 33 340. 396 Not Reported 33 965. 396 Not Reported 34 410. 396 Not Reported 35 090 ovo Not ivcpui ICU 35 100. 396

Not IVC JJIH lCU 35 165. 396 Not XiC JM.'I ICU 35 215. 396 Not Reported 35 335. 396 Not Reported 35 440. 396 Not 35 748.2 396

Not ivcpui ICU 35 805.7 396 Not 35 810.8 396 Not Reported 36 080.0 396 Not Reported 36 332.7 396 Not Reported 36 4?? Q 396

Not R A rxeporteu 36 483.9 396

IMOl Reported 36 655. 396 Not Reported 36 946 4 396 Not Reported 36 987. 396 Nnt 1 1 Ol Reported 37 030. 396

Nnt R J Keported 37 229.8 396 Nnt Reported 37 322.8 396 Not Reported 37 325. 396 Not Reported 57 /IOC OVD Nnt Reported

Nnt R t A iveporteci 37 900. 396 Nnt i >! Ol Reported 38 052.6 396 Not Reported 38 132.8 396 Not Reported 38 530 396 Not IVCpUI ICLI 38 967 0 396

Not ivcpui ICU 39 048. 396 Not 39 065. 396 Not Reported 40 083. 396 Not Reported 40 240. 396 Not Reported 40 640. 396

Not ri *i nn»*t <in ivcpol ICU 40 940. 396 Not Reported 41 230. 396 Not Reported 41 540. 396 Not Reported 41 688. 396 Not Reported 41 750. 396

Not Reported 42 000. 396 Not Reported 42 020. 396 Not Reported 42 150. 396 Not Reported 42 285. 396 Not Reported 42 700. 396

63
Methanol

Spectral Line Table

Isotopic Species Id. Rotatiinial V'ib. State Int. Rotor Hyperfine Erecjuency Acc. Ref. No. Quantum Nos. State n F' F' p MHz ±MHz

216 Not Reported 43 34S. 396 Not Reported 43 525. 396 Not Re| torted 43 545. 396 Not Reported 43 630 396 Not Reported 43 99S. 396

217 2, 2. ^ 2. 1, Ground EH 0 33 918.97 .1 37

3, 2, 3. 1, Ground EH 0 33 925.49 37

4, 2. 4. 1, ( ^rnii nn EH 0 33 943 63 •j 37

5, 2. 5, 1, Ground Eh 0 33 981.35 |

37

6. 2. «— 6, 1, Ground Eh 0 34 048.42 \37

7, 2. ^ 7, 1, Ground EH 0 34 155.63 .1 37

8, 2, ^ 8, 1, Ground EH 0 34 314.64 37

9, 2, <— 9, 1, Ground EH 0 34 536.74 }

37

10, 2. -^10, li Ground Eh 0 34 831.64 37

ll' 2^ ^ll' l! Ground EH 0 35 206.11 37

12. 2. ^12. 1, Ground EH 0 - 35 661.78 .1 37

13, 2, ^13, 1, Ground EH 0 36 193.55 37

14, 2, <-14, 1, Ground Eh 0 36 787.33

•} 37

is! 2, <—is! l! Ground EH 0 37 418.97 37

16^ 2! <—16^ L Ground EH 0 38 053.87 37

17. 2. ^17. 1. Ground EH 0 38 647.87 .1 37

18. 2, ^18, 1, (Ground EH 0 39 149.41 37

19. 2. ^19, 1. (Ground EH 0 39 505.01 •J 37

20. 2. ^20, 1, Ground EH 0 39 661.80 37

21. 2. ^21. 1. Ground EH 0 39 574.97 37

- 22. 2, ^22, 1, (Ground EH 0 39 210.48 37

23, 2, ^23, 1, ( iround EH 0 38 547.73 37

24, 2, ^24, 1, (Ground EH 0 37 579.85 37

25. 2. ^2S, 1, Ground EH 0 36 312.57 37

26. 2. ^26. 1. (rround EH 0 34 761.75 .1 1 37

64
220- Methanethiol Molecular (Constant 'I'aMe Methyl Mercaptan

CH^S C,(C.,v,Cs) CH,SH

Isotopic Species Pt. Gp

Id. No. A (MHz) B (MHz) C(MHz) Dj DjK K A

Cs 221 170 303. M 12 907.36 M 12 384.04 M

Cs 222 170 296. M 12 433.73 M 11 947.34 M

Cs 223 91 026. M 12 659.24 M 11 727.55 M

Cs 224 120 849. M 10 541.56 M 10 189.68 M

Cs 225 170 016. M 12 694.62 M 12 186.94 M

C>2H,S'-^H Cs 226 170 155. M 12 797.80 M 12 282.55 M

Id. No. /Lia Debye juLi, Debye /Ae Debye eQq v.. Acc. Ired tOa d Wb d ail- d d

221 1.33 M 0.73 M 0. X 1270 1.0

References: ABC: 106 Dj: Djk: k: A:

ix: 286 eQq: V: 344 I: to:

Add. Refs.: 38. 47. 84. 107. 141'. 164

Torsional frequency =200 cm-'. Ref: 286. eQqaa = - 27.57 ± .05 MHz. Ref: 383.

Methanethiol

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

221 1, 0. 1^ 0. 0. 0 Ground A 3 25 126.9 .1 174

1, 0, 1^ 0, 0, 0 Ground E 3 25 142.2 .1 174

1, 0, 1^ 0. 0. 0 Ground A 2 25 143.6 .1 174

1, 0. 1^ 0. 0. 0 Ground E 2 25 154.8 .1 174

1. 0. 1^ 0. 0. 0 Ground E 1 25 206.8 .1 174

1. 0. 1^ 0, 0. 0 Ground A 1 25 219.7 .1 174

1, 0, 1*- 0. 0, 0 Ground A 0 25 290.8 .1 174

1, 0, 1^ 0, 0, 0 Ground E 0 25 291.8 .1 174

1. 1. 2, 0, Ground E(+) 0 14 764.5 .1 174

2. 1, 1, 0, Ground E(+) 1 18 417.6 286

2. 1. 3. 0. Ground E(-) 0 23 339.2 .1 174

2, 1, 2^ 3. 0, 3 Ground A 0 29 091.9 .1 174

3, 2, 1«- 2, 1, 2 Ground A 1 15 339.0 286

3. 2. 2^ 2, 1, 1 Ground A 1 14 320.2 286

4, 0, 3. 1. Ground 35 857.4 286

5, 0, 4, 1, Ground E(-) 0 26 994.2 174

5, 0, 5^ 4, 1, 4 Ground A 0 23 256.9 174

5, 1, 4^ 5, 1, 5 Ground 7 846.0 174

6, 1, 5^ 6, 1, 6 Ground 10 983.4 174

7. 1. 6^ 7. 1. 7 Ground 14 643.1 174

65
Methanethiol

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

C'^HgS^^H 221 8, 1, 7^ 8, 1, 8 Ground 18 824.2 .1 174

8, 2, *— 9, 1, Ground EM 0 18 0S9 S \ 174

9" h 8^ 9] 1] 9 Ground 23 526.2 .1 174

9, 2, ^10, 1, Ground 21 973.2 286

9. 2. 8^10, 1, 9 Ground A 0 25 659.7 .1 174

10. 1. 9<-10. 1,10 Ground 28 747.9 .1 174

10. 2. 8-<— 11. 1,11 Ground 33 077.9 286 u. h ^10] 2] Ground 35 913.5 286

12, 1, ^11, 2, Ground 23 801.8 286

12. 1.11^11, 2,10 Ground 30 741.8 286

14, 1,14^13, 2,11 Ground 30 508.6 286 Not Reported Ground 14 146.3 174 Not Reported Ground 14 548.4 A 174 Not Reported Ground 14 865.1 • 1 174 Not Reported Ground 14 888.0 • 1 174

Not Reported Ground 15 089.3

•} 174 Not Reported Ground 15 102.2 174 Not Reported Ground 15 103.5 \\ 174 Not Reported Ground 15 123.2 1 174 Not Reported Ground 15 165.1 174

Not Reported Ground 15 335.9 174 Not Reported Ground 16 057.0 174 Not Reported Ground 16 059.8 .1 1 174 Not Reported Ground 16 066.1 .1 174 Not Reported Ground 16 796.4 .1 174

Not Reported Ground 17 320.4 174 Not Reported Ground 18 257.8 174 Not Reported Ground 18 396.0 174 Not Reported Ground 18 431.8 174 Not Reported Ground 18 446.3 174

Not Reported Ground 18 494.1 174

( » vn 1 1 n H 18 499.7 174 Not Reported Ground 18 509.7 174 Not Reported Ground 18 586.1 174 Not Reported Ground 18 675.6 174

Not Reported Ground 18 778.6 174 Not Reported Ground 18 806.4 174 Not Reported Ground 18 895.7 174 Not Reported Ground 18 991.8 174 Not Reported Ground 19 027.1 174

Not Reported Ground 19 173.0 174 Not Reported Ground 19 273.6 174 Not Reported Ground 19 334.0 174 Not Reported Ground 19 510.4 174 Not Reported Ground 19 568.3 174

Not Reported Ground 19 702.9 174 Not Reported (/round 19 912.2 174 Not Reported Ground 19 999.9 174 Not Reported (Ground 20 052.6 174 Not Reported (iround 20 138.6 174

Not Reported Ground 20 241.9 174 Not Reported, L> round zO 606.Z 174 Not Reported Ground 20 646.4 174 Not Reported (iround 20 928.9 174 Not Reported Ground 21 057.4 174

66
Methanethiol Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hypertine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

221 Not Reported (iround 21 131.1 174 Not Reported (iround m fin 1 "7 21 231.7

;} 174 Not Reported Ground 21 519.9 174 Not Reported Ground 21 555.6 174 Not Reported Ground 21 734.6 174

Not Reported (Ground 21 766.6 1 174 Not Reported Ground 21 865.5

;j 174 Not Reported Ground 21 877.1 174 Not Reported Ground 21 901.0 .1 174 Not Reported Ground 21 943.5 \ 174

Not Heported (iround 22 269.4 •1 174 Not Reported Ground CIO ortr\ n 22 329.8

;} 174 Not Reported Ground 22 560.2 174 Not Reported Ground 22 661.4 1 174 Not Reported Ground 22 827.3 I 174

Not Reported Ground 23 073.8 1 174 Not Reported Ground 23 078.2

;} 174 Not Reported Ground 23 230.3 174 Not Reported Ground 23 494.4 .1 174 Not Reported Ground 23 520.4 I 174

Not Reported Ground 23 566.6 •1 174 Not Reported Ground 23 617.3 j

174 Not Reported Ground 23 773.8 174 Not Reported Ground 23 989.0 I 174 Not Reported Ground 24 067.5 I 174

Not Reported Ground 24 485.0 174 Not Reported Ground 24 988.5 174 Not Reported Ground 25 009.0 j

174 Not Reported Ground 25 121.4 174 Not Reported Ground 25 562.0 i 174

Not Reported Ground 25 917.5 .1 174 Not Reported Ground 26 077.4 174 Not Reported Ground 26 144.7 ;} 174 Not Reported Ground 26 388.4 I 174 Not Reported Ground 26 758.1 174

Not Reported Ground 26 947.0 .1 174 Not Reported Ground 27 235.8 174 Not Reported Ground 27 333.9 ;} 174 Not Reported Ground 27 364.5 174 Not Reported Ground 27 402.2 I 174

Not Reported Ground 27 419.4 1 174 Not Reported Ground 27 444.5

;} 174 Not Reported Ground 27 911.9 174 Not Reported Ground 28 078.2 174 Not Reported Ground 28 275.1 I 174

Not Reported Ground 28 530.1 .1 174 Not Reported Ground 28 593.5 174 Not Reported Ground 28 686.8 }

174 Not Reported Ground 28 786.0 I 174 Not Reported Ground 28 910.8 174

Not Reported Ground 28 990.3 .1 174 Not Reported Ground 29 073.9 174 Not Reported Ground 29 074.4 174 Not Reported Ground 29 436.3 174 Not Reported Ground 29 526.2 174

67
Methanethioi

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F/ F' F, F MHz ±MHz

221 Not Reported Ground 29 574.4 .1 174 Not Reported Ground 29 593.1 .1 174 Not Reported Ground 29 772.81 286 Not Reported Ground 30 083.34 286 Not Reported Ground 30 366.66 286

Not Reported Ground 30 395.6 286 Not Reported Oround on AAf. o OU 'ViO.O ZOO Not Reported Ground 30 487.4 286 Not Reported Ground 30 626.50 286 Not Reported Ground 30 652.31 286

Not Reported Ground 30 666.43 286 Not Reported Ground oU o._)y. to Zoo Not Reported Ground 30 874.84 286 Not Reported Ground 30 972.32 286 Not Reported Ground 31 051.0 286

Not Reported Ground 31 068.24 286 Not Reported Ground 31 252.87 286 Not Reported Ground 31 378.7 286 Not Reported Ground 31 414.80 286 Not Reported Ground 31 450.2 286

Not Reported Ground 31 476.5 286 Not Reported Ground 31 479.3 286 Not Reported Ground 31 489.3 286 Not Reported Ground 31 496.2 286 Not Reported Ground 31 500.8 286

Not Reported Ground 31 522.7 286 Not Reported Ground 31 527.2 286 Not Reported Ground 31 529.9 286 Not Reported Ground 31 540.4 286 Not Reported Ground 31 555.09 286

Not Re|)orted Ground 31 563.8 286

INot Ke|)orted Lrround 31 567.9 Zoo Not Reported Ground 31 571.8 286 Not Reported (Ground 31 575.4 286

.1 Not Reported Ground 31 675.02 286

Not Reported Ground 31 776.04 286

INot Reported Ground 0 1 OCO C/1 ZOO Not Reported Ground 31 880.2 286 Not Reported Ground 31 927.27 286 Not Reported Ground 31 980.68 286

Not Reported Ground 31 989.58 286

[Not Reported Ground 31 y94. /4 ZOO Not Reported Ground 32 002.23 286 Not Reported Ground 32 011.70 286 Not Reported Ground 32 021.14 286

Not Reported Ground 32 022.71 286 Not Reported Ground 32 U34.0Z Zoo Not Re|)orted Ground 32 047.20 286 Not Reported Ground 32 050.46 286 Not Reported Ground 32 059.35 286

Not Reported Ground 32 070.04 286 Not Reported Ground 32 070.15 286 Not Reported Ground 32 078.93 286 Not Reported Ground 32 081.32 286 Not Reported Ground 32 084.51 286

68
Methanethiol Spectral Line Table

Isotopic Species Id. Rdlalional Vib. State Int. Rotor Hyperline Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

C'-H3S-'2H 221 Not Rejjorted ( Iniiiiid ,32 085.74 286 Not Reported ( Mound ZoO Not Reported (Ground 32 819.24 286 Not Reported (iround 32 820.71 286 Not Reported (Ground 32 827.91 286

Not Reported (Ground 32 844.33 286 Not Reported Ground OO 0'7A OA Zoo Not Reported Ground 32 880.05 286 Not Reported Ground 32 922.31 286 Not Reported (Jround 32 994.15 286

Not Reported Ground 33 095.66 286 Not Reported Ground 33 096.66 286 Not Reported (iround 33 233.51 286 Not Reported Ground 33 277.30 286 Not Reported ( Ground 33 414.78 286

Not Reported Ground 33 416.85 286 Not Reported Irround OO a An OA 66 647.zO 286 Not Reported Ground 33 658.81 286 Not Reported Ground 33 738.45 286 Not Reported Ground 33 838.93 286

Not Reported Ground 33 858.74 286 Not Reported Ground 66 938.69 286 Not Reported Ground 34 013.70 286 Not Reported Ground 34 193.09 286 Not Reported Ground 34 237.2 286

Not Reported (iround 34 298.00 286 Not Reported Ground OA /I OO OC 286 Not Reported Ground 34 527.38 286 Not Reported Ground 34 616.85 286 Not Reported Gr round 34 733.89 286

Not Reported (Ground 34 942.56 286 Not Reported (iround 35 255.73 286 Not Reported (Ground 35 373.8 286 Not Reported Ground 35 521.54 286 Not Reported Ground 35 543.34 286

Not Reported (iround 35 547.33 286 Not Reported tJround 35 552.2 286 Not Reported (-round 35 597.59 286 Not Reported Ground 35 731.0 286 Not Reported Ground 35 754.19 286

Not Reported Ground 35 791.03 286 Not Reported Ground 35 792.1 286 Not Reported Ground 35 846.05 286 Not Reported Ground 35 873.42 286 Not Reported (iround 35 924.22 286

Not Reported Ground 36 026.20 286 Not Reported Ground 0£^ C\OC\ O"? 36 030.8/ oo^ Zoo Not Reported (iround 36 172.20 286 Not Reported (Ground 36 216.46 286 Not Reported (iround 36 281.75 286

Not Reported (iround 36 354.69 286 Not Reported Ground oe^ c oc 1

"7 Zoo Not Reported Ground 36 597.09 286 Not Reported Ground 36 822.40 286 Not Reported Ground 36 824.83 286

Not Reported Ground 36 871.10 286 Not Reported Ground 37 220.42 286 Not Reported Ground 37 437.33 286

749-587 0-69—

6

69
Methanethiol

Spectral Line Table

Isotopic Species Id. Rotationa Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

222 1. 0. 1^ 0. 0, 0 1 Cjround A 2 24 245.0 174

1, 0, 1^ 0, 0, 0 1 (iround E 2 24 256.2 174

1. 0, 1*- 0, 0, 0 Ground E 1 24 306.2 174

1, 0, 1^ 0, 0, 0 (Ground A 1 24 318.5 174

1, 0, 1^ 0, 0, 0 Ground E 0 24 388.0 174

1, 0, 1<- 0. 0. 0 Ground A 0 24 389.1 174

C'^H,S-*^D 223 1, 0, 1^ 0, 0, 0 1 Ground A 3 24 302.9 174

1, 0, 1^ 0, 0, 0 1 Ground A 2 24 322.2 174

1, 0. 1^ 0, 0, 0 1 Ground E 2 24 330.3 174

1, 0, 1^ 0, 0. 0 1 Ground E 1 24 385.9 174

1, 0. 1^ 0, 0, 0 Ground A 1 24 388.3 174

1, 0, 1^ 0, 0, 0 ! Ground A 0 24 456.0 174

C'^DaS^^H 224 1, 0, 1^ 0, 0, 0 1 Ground A 2 20 619.0 174

1, 0, 1^ 0, 0, 0 1 Ground E 2 20 627.6 174

1. 0, 1^ 0, 0, 0 Ground E 1 20 674.8 174

1. 0, 1^ 0, 0, 0 Ground A 1 20 678.9 174

1. 0, 1^ 0, 0, 0 Ground A 0 20 732.0 174

1. 0. 1^ 0, 0, 0 Ground E 0 OA "7 0 0 O 20 732.8 174

C'^HjS^^H 225 1. 0, 1^ 0, 0, 0 1 Ground 24 878.9 119

1. 0. 1^ 0, 0, 0 1 Ground 24 879.8 119

226 1. 0, 1^ 0, 0. 0 Ground 25 078.7 119

1, 0, 1^ 0, 0, 0 1

1

Ground ! 25 079.6 119

70
230 - Chloromethylsilane Molecular Conslant Table

Chloromethylsilicane

CH^ClSi C,(C3v,Q CH,Ci.SiH,

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D., D.,K K A

Cs 231 21 759.21 M 3 204.08 M 2 938.09 M .004 C'^HjCFSi^^H,, Cs 232 21 692.92 M 3 125.14 M 2 870.40 M

Cs 233 21 080.42 M 3 204.37 M 2 925.47 M

Cs 234 21 726.82 M 3 155.41 M 2 896.53 M

Cs 235 17 282.73 M 3 172.57 M 2 864.21 M

C'^HDCPSPHj c, 236 19 250.99 M 3 190.78 M 2 898.44 M

C'2H,CPSi-«D3 Cs 237 17 .536.11 M 2 925.97 M 2 707.51 M

i

Id. No. /u-a Debye ^ih Debye /u.(. Debye eQq V3 Acc. Iretl oih d oi,. d a)(i d

231 -32.51 2550 50

References: ABC: 358 ,Dj:358 D,,k: k: A: eQq: 358 V: 358 I: w:

71
Chloromethylsilane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n 1 F' E F MHz ±MHz

C'^HXF=^Si2»H3 231 4, 0, 4^ 3, 0, 3 Ground 24 539.45 .2 358

4, 1, 3-^ 3. 1. 2 Ground 25 093.48 .2 358

4! 1] 4^ 3. 1. 3 Ground 24 030.18 .2 358

5, 0, 5^ 4. 0. 4 Ground 1 30 517.53 .2 358

5, 0, 5^ 4. 0, 4 Ground 30 652.24 .2 358

5, 1, 4^^ 4, 1. 3 Ground 1 31 203.74 .2 358

5, 1, 4^^ 4, 1, 3 Ground 31 360.87 .2 358

5^ h 5^ 4! L 4 Ground 1 29 915.57 .2 358

5, 1, 5^ 4, 1, 4 Ground 30 032.34 .2 358

5, 1, 4-e- 5, 0, 5 Ground 7/2 7/2 20 757.70 .2 358

5. 1, 4^ 5, 0, 5 Ground 13/2 13/2 20 759.47 .2 358

5, 1, 4^ 5, 0, 5 Ground 20 761.87 .2 358

5. 1, 4^ 5, 0, 5 Ground 9/2 9/2 20 763.92 .2 358

5. 1, 4^ 5, 0, 5 Ground 11/2 11/2 20 765.66 .2 358

6. 1, S'^ 6, 0, 6 Ground 9/2 9/2 21 631.36 .2 358

6. 1, 5^ 6, 0, 6 Ground 15/2 15/2 21 632.81 .2 358

6, 1, 5^ 6, 0, 6 Ground 21 634.98 .2 358

6. 1, 5^ 6, 0, 6 Ground 11/2 11/2 21 637.41 .2 358

6. 1, 5^ 6, 0, 6 Ground 13/2 13/2 21 638.88 .2 358

7. 1. 6^ 7, 0, 7 Ground 1 22 477.10 .2 358

7, 1, 6^ 7, 0, 7 Ground 11/2 11/2 22 681.16 .2 358

7^ 1, 6^ 7, 0, 7 Ground 17/2 17/2 22 682.47 .2 358

7!

1" 6^ 7' 0^ 7 Ground 22 684.78 .2 358

7, 1, 6*- 7, 0, 7 Ground 13/2 13/2 22 687.29 .2 358

7, 1, 6^ 7, 0, 7 Ground 15/2 15/2 22 688.51 .2 358

8. 1, 7^ 8, 0, 8 Ground 1 23 674.57 .2 358

8. 1, 7^ 8, 0, 8 Ground 13/2 13/2 23 920.73 .2 358

8^ 1, 7^ 8, 0, 8 Ground 19/2 19/2 23 921.78 .2 358

8, 1, 7^ 8, 0, 8 Ground 23 924.41 .2 358

8, 1, 1^ 8, 0, 8 Ground 15/2 15/2 23 926.95 .2 358

8. 1, 7^ 8, 0, 8 Ground 17/2 17/2 23 927.90 .2 358

9, 1, 8*- 9, 0, 9 Ground 15/2 15/2 25 364.62 .2 358

9, 1, 8^ 9, 0, 9 Ground 21/2 21/2 25 365.55 .2 358

9, 1, 8<^ 9, 0, 9 Ground 25 368.30 .2 358

9, 1, 8^ 9. 0, 9 Ground 17/2 17/2 25 370.91 .2 358

9, 1, 8^ 9, 0, 9 Ground 19/2 19/2 25 371.91 .2 358

9, 3, 6^10. 2. 9 Ground A 32 233.43 .2 358

9, 3, 6^10. 2, 9 Ground E 32 234.65 .2 358

9. 3, 6^10. 2, 9 Ground A 32 235.62 .2 358

9, 3, 6^10, 2, 9 Ground E 1 32 236.82 .2 358

9, 3, 7*—10, 2, 8 Ground A 30 914.77 .2 358

9'

3, 7^10, 2, 8 Ground E 30 915.52 .2 358

10! 1. 9^10, 0,10 Ground 26 672.38 .2 358

10, 1, 9*- 10, 0,10 Ground 17/2 17/2 27 027.28 .2 358

10, 1. 9^10, 0,10 Ground 23/2 23/2 27 028.20 .2 358

10, 1, 9^10, 0,10 Ground 27 031.04 .2 358

10, 1. 9^10, 0,10 Ground 19/2 19/2 27 033.77 .2 358

10, 1, 9^10, 0,10 Ground 21/2 21/2 27 034.75 .2 358

10, 3, 7^11, 2,10 Ground A 1 26 282.6 .2 358

10, 3, 7^11, 2,10 Ground E 1 26 283.9 .2 358

1. The two sets of numbers given for two of the transitions in the first excited torsional state are a result of the partially resolved hyperfine structure due to quadrupole coupling.

72
Chloromethylsilane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

C'^H^CPSi^^Ha 231 10, 3. 7^11, 2,10 Ground A 1 26 284.7 .2 358

10, 3, 7^11, 2,10 Ground E 1 26 285.8 .2 358

10, 3, S'^ll, 2, 9 Ground A 1 24 383.97 .2 358

10. 3, 8<— 11, 2, 9 Ground E 1 24 384.93 .2 358

11, 1,10*—11, 0,11 Ground 28 501.29 .2 3.58

11, 1,10^11, 0,11 Ground 19/2 19/2 28 923.43 .2 358

11, 1.10^11, 0,11 Ground 25/2 25/2 28 924.30 .2 358

11 11 A ^ 11 All

11, 1,10*—11, 0,11 Ground OO AO"? 28 927.25 .2 358

11 11A-- 11 All

11, 1,10<—11, 0,11 Ground 21/2 21/2 OO AOA AO 28 930.08 .2 358

11 llA^ 11 All

11, 1,10^11, 0,11 Ground 23/2 23/2 28 931.01 .2 358

12, 1,11^12, 0,12 Ground 21/2 21/2 31 066.54 .2 358

12, 1,11^12, 0,12 Ground 27/2 27/2 31 067.32 .2 358

12, 1, 11^^12, 0,12 Ground 31 070.41 .2 358

12, 1,11^^12, 0,12 Ground 23/2 23/2 31 073.42 .2 358

12, 1,11*-12, 0,12 Ground 25/2 25/2 31 074.25 .2 358

C'^HjCF'Si^^Hj 232 4, 0, 4^ 3, 0. 3 Ground 23 955.17 .2 358

4, 1, 3^ 3, 1, 2 Ground 24 485.10 .2 358

4, 1, 4^ 3, 1, 3 Ground 23 466.80 .2 358

5, 0, 5*- 4, 0, 4 Ground 29 923.80 .2 358

5, 1, 4<— 4, 1, 3 Ground 30 601.08 .2 358

6, 1, 5<- 6, 0, 6 Ground 21 511.17 .2 358

7, 1, 6^ 7, 0. 7 Ground 22 511.60 .2 358

8, 1, 7^ 8, Q, 8 Ground 23 692.14 .2 358

10, 1, 9'^10. 0.10 Ground 26 645.25 .2 358

11, LlO'^ll, 0,11 Ground 28 445.64 .2 358

C'-'HaCF^Si^sHa 233 4, 0, 4^ 3, 0, 3 Ground 24 485.55 .05 324

4, 1, 3^ 3, 1, 2 Ground 7/2 9/2 5/2 7/2 25 068.4 .1 324

4, 1, 3<— 3, 1, 2 Ground 25 068.86 .2 358

4, 1, 3<— 3, 1, 2 Ground 5/2 11/2 3/2 9/2 25 0o9.o .1 324

4, 1, 4<— 3, 1, 3 Ground 5/2 7/2 3/2 5/2 23 953.1 .1 324

4, 1, 4^ 3, 1, 3 Ground 23 953.63 .2 358

4, 1, 4^ 3, 1, 3 Ground 9/2 11/2 7/2 9/2 23 953.9 .1 324

5, 0, 5<— 4, 0, 4 Ground 30 582.3 .1 324

5, 0, 5<— 4, 0, 4 Ground 30 582.35 .2 358

5, 1, 4^^ 4, 1, 3 Ground 9/2 11/2 7/2 9/2

11 1 tin OA 31 329.88 .05 324

5, 1, 4^ 4, 1, 3 Ground 31 330.29 .2 358

5, 1, 4^ 4. 1, 3 Ground 7/2 13/2 5/2 11/2 31 330.68 .05 324

5, 1, 5<^ 4, 1, 4 Ground 7/2 9/2 5/2 7/2 29 935.7 .1 324

5, 1, 5<— 4, 1, 4 Ground 29 936.02 .2 358

5. 1, 5<— 4, 1, 4 Ground 11/2 13/2 9/2 11/2 29 936.2 .1 324

6, 0, 6^ 5, 1, 5 Ground 9/2 7/2 20 643.52 .05 324

6, 0, 6^ 5, 1. 5 Ground 15/2 13/2 20 644.81 .05 324

6, 0, 5, 1, 5 Ground 11/2 9/2 20 646.97 .05 324

6, 0. 6'^ 5, 1, 5 Ground 13/2 11/2 20 648.29 .05 324

8, 1, 7^ 8. 0, 8 Ground io// lo// 23 542.4 .1 324

o, i, o, U, o Ground 19/2 19/2 .1 oz^-

8, 1, 7*- 8, 0, 8 Ground 23 546.17 .2 358

8, 1, 7^ 8. 0. 8 Ground 17/2 17/2 23 549.7 .1 324

9, 1, 8^ 9, 0. 9 Ground 15/2 15/2 25 077.48 .05 324

9, 1, 8^ 9. 0. 9 Ground 21/2 21/2 25 078.50 .05 324

1. See fuotnote preceding page.

73
Chloromethylsilane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

233 9, 1, 8^ 9, 0, 9 Ground 25 081.23 .2 358

9, 1, 8^ 9. 0, 9 Ground 17/2 17/2 25 083.90 .05 324

9, 1. 8<— 9. 0, 9 Ground 19/2 19/2 25 084.85 .05 324

10. 1. 9'^10, 0,10 Ground 17/2 17/2 26 848.5 .1 324

10, 1, 9<— 10, 0,10 Ground 23/2 23/2 26 849.4 .1 324

10, 1, 9^10, 0,10 Ground 26 852.29 .2 358

10, 1. 9^10, 0,10 Ground 19/2 19/2 26 855.1 .1 324

10, 1, 9<—10, 0,10 Ground 21/2 21/2 26 856.0 .1 324

IT iin^ 11 rill

11. 1,10*—11, 0,11 Ground 19/2 19/2 28 870.45 .05 324

11. 1.10^11, 0.11 Ground 25/2 25/2 28 871.18 .05 324

11 iin, 11 /^ii

11, 1.10<—11, 0,11 Ground 28 874.24 .2 358

11 iir»- 11 r\ii

11, 1.10-^11. 0.11 Ground 21/2 21/2 Oct or" 28 877.25 .05 324

11 iir»- 11 /"111 11. l.lO'^ll. 0.11 Ground 23/2 23/2 28 877.90 .05 324

C'^H^CP^Si^^Hj 234 4. 0. 4^ 3. 0. 3 Ground 24 179.0 .1 324

4. 0. 4^ 3. 0. 3 (iround 24 179.60 .2 358

4. 1. 3-^ 3. 1. 2 Ground 7/2 9/2 5/2 7/2 . 24 718.0 .1 324

4. 1, 3«— 3. 1. 2 Ground 5/2 11/2 3/2 9/2 24 718.0 .1 324

4, 1, 3<— 3. 1. 2 Ground n A '7 1 f> 1 24 718.01 .2 358

5, 0. 5^ 4, 0. 4 Ground 30 203.92 .05 324

5, 0, 5^ 4. 0. 4 Ground 30 203.97 .2 358

5, 1. 4^^ 4, 1, 3 Ground 7/2 13/2 5/2 11/2 30 892.78 .05 324

5. 1, 4'<^ 4. 1. 3 Ground 9/2 11/2 7/2 9/2 30 892.78 .05 324

5. 1. 4«— 4. 1. 3 Ground 30 892.79 .2 358

5. 1. 5^ 4. 1. 4 Ground 7/2 9/2 5/2 7/2 29 599.25 .05 324

5. 1. 5^ 4. 1. 4 Ground 11/2 13/2 9/2 11/2 29 599.25 .05 324

- " 5. 1. 5^ 4. 1, 4 Ground 29 599.32 .2 358

7, 0. 7-^ 6, 1, 6 (Ground 11/2 9/2 26 075.08 .05 324

7. 0. 7<— 6, 1, 6 Ground 17/2 15/2

f\i r\f\ 26 076.00 .05 324

7. 0, 7^ 6, 1, 6 Ground 13/2 11/2 26 078.28 .05 324

7, 0, 7^ 6, 1, 6 Ground 15/2 13/2 26 079.28 .05 324

8, 1, 7<— 8, 0, 8 Ground 19/2 19/2 23 776.

z

•1 324

8, 1, 7«— 8. 0. 8 (Ground 23 779.57 358

8, 1, 7^ 8. 0, 8 Ground 17/2 17/2 23 782.8 •1 324

9, 1. 8<- 9. 0, 9 (iround 15/2 15/2 25 180.8 324

9, 1, 8^ 9, 0, 9 Ground 21/2 21/2 25 181.6 .1 324

9, 1, 8^ 9, 0, 9 (Ground 25 184.38 358

9, 1, 8^ 9. 0. 9 (iround 17/2 17/2 25 187.0 •1 324

9. 1. 8^ 9. 0. 9 Ground 19/2 19/2 25 187.9 •1 324

10. 1. 9^10. 0.10 Ground 17/2 17/2 26 790.7 324

10. 1. 9^10. 0.10 (iround 23/2 23/2 26 791.7 'l 324

10. I. 9^10. 0.10 Ground 26 794.74 358

10. 1, 9<—10. 0.10 Ground 19/2 19/2 26 797.7 324

10. 1, 9^10. 0.10 Ground 21/2 21/2 26 798.7 ;} 324

11. l.lO'^ll. 0.11 Ground oc /o 2o/z Zo/Z 28 626.79 .05 324

11. 1.10^11. 0.11 Ground 28 630.20 .2 358

11. 1.10*-11. 0.11 Ground 23/2 23/2 Zo OOO.DZ ^94. OZ4*

c'^D^cr'-^Sim, 235 4, 0, 4^ 3. 0. 3 Ground 1 23 992.05 .2 358

1 4, 0, 4^ 3, 0, 3 (iround 24 095.95 .2 358

4, 1, 3^ 3, 1, 2 (Ground 1 24 631.06 .2 358

74
Chloromethylsilane Spectral I-ine Table

Id. No.

RotS-tioritii Qu3.ntum Nos.Vib. State Int. Rotor

State n F' F' F MHz

Acc. ±MHz

Ref.

C'-D^CPSPHj 235 4, 1, 3<- 3. 1. 2 Ground 24 7.52.39 .2 358

4, 1, 4<- 3, 1, 3 Ground 1 23 429.48 .2 358

4, 1, 4<— 3, 1, 3 Ground 23 519.83 2 358

5^ 0, 5<— 4, 0, 4 Ground 1 29 9.54.65 2 .358

5, 1, 4^ 4, 1, 3 Ground 1 30 779.07 2 358

5, 1, 4-^ 4, 1, 3 Ground .30 930.22 .2 3,58

5, 1, 5-^ 4, I, 4 Ground 1 29 277.72 .2 358

5, 1, 5<- 4, 1,4 Ground 29 389.83 .2 358

7' 1] 6«- 7' 0' 7 Ground 19 057.54 .2 358

8, 1. 1*— s' 0' 8 Ground 1 20 397.79 2 358

8, 1. 1<- 8, 0, 8 Ground 20 593.01 .2 358

9, 1, 8^ 9, 0, 9 Ground 22 399.13 .2 358

10, 1, 9<-10, 0,10 Ground 24 495.28 2 358

12^ l'll<-12^ 042 Ground 1 29 142.97 .2 358

12' l'll*-12' oil2 Ground 29 613.69 .2 358

236 4, 0, 4^ 3. 0, 3 Ground 24 316.27 .2 358

5, 1, 4*- 4, 1, 3 Ground 31 156.99 .2 358

29 696 89 2 358

5, 1, 4^ 5. 0. 5 Ground 18 508.34 .2 358

6, 1. 5^ 6. 0. 6 Ground 19 490.20 .2 358

8, 1. 7<— 8. 0, 8 Ground 22 089.27 .2 358

9^ 1, 8«— 9, 0^ 9 Ground 23 742.34 .2 358

237 4, 0, 4^ 3, 0, 3 Ground 1 22 435.80 .2 358

4, 0, 4^^ 3, 0, 3 Ground 22 508.38 .2 358

4, 1, 3^^ 3, 1, 2 Ground 22 964.29 .2 358

4, 1, 4<— 3^ \, 3 Ground 22 091.50 .2 358

5' 0" 5^ 4' 0' 4 Ground 1 28 028.14 .2 358

5, 0, 5^ 4, 0. 4 Ground 28 116.99 .2 358

5, 1, 4^^ 4, 1, 3 Ground 1 28 592.69 .2 358

5, 1, 4*- 4, 1, 3 Ground 28 700.44 .2 358

5, 1, 5«- 4, 1, 4 Ground 1 27 534.57 2 358

5, 1, S'^ 4, 1. 4 Ground 27 609.21 2 358

7. 1, 6-^ 7, 0. 7 Ground 18 011.15 .2 358

8, 1, 7^ 8, 0, 8 Ground 19 034.52 .2 358

9, 1, 8*- 9, 0, 9 Ground 1 20 003.13 2 358

9'

1^ S'^ 9, q\ 9 Ground 20 228.29 .2 358

10, 1, 9^10, 0,10 Ground 1 21 330.46 .2 358

10. 1, 9^10, 0,10 Ground 21 604.26 .2 358

11. 1,10^11, 0,11 Ground 1 22 844.72 .2 358

75
240 - Methylmonofluoiosilane Molecular Constant Table ' Methylmonofluorosilicane

CH.,FSi C,(C3„Cs) CHgSiH^F

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) Dj K A

C'HjSr^HjF"* Cs 241 20 050. M 6 753.80 M 5 545 26 M

C'^HsSPHjF''' Cs 242 19 848. M 6 753.94 M 5 529.58 M

C'^HaSPHaF'" Cs 243 19 657. M 6 753 92 M 5 514.79 M

C'^DsSi-^^HaF'^ Cs 244 17 412. M 5 786 60 M 4 846 70 M

C'^HaSi^^DaF'" Cs 245 15 954. M 6 493.07 M 5 335.23 M

C^^DgSi^^HaF'*' Cs 246 17 087. M 5 784.62 M 4 819.59 M

s-C'^H^DSi^'^HsF'^ Cs 247 20 000. M 6 270.63 M 5 212.80 M

a-C'^HjOSi^sH^F'^ c, 248 18 630. M 6 454.62 M 5 317.16 M

C^HjSpsHjF'^ Cs 249 19 900. M 6 542.15 M 5 390.80 M

C'^DjSi^^'HaF''* Cs 251 17 248. M 5 785.63 M 4 832.80 M

C'2H3Si^»HDF'^ Cs 252 17 855. M 6 636.34 M 5 427.57 M

Id. No. Debye /j-i, Debye jJL^. Debye eQq V,3 Acc. Ired Wa d OJlj d co^. d (0,1 d

241 1.67 M 0..39 M 0. X 1559 30

References: ABC: 233. 290' Dj: Djk: k: A:

/x: 233 eQq: • V: 233 I: o:

Coupling parameter: la ==3.132 amu A^. Ref: 233. Torsional frequency 261 cm~'. Ref: 209.

76
Methylmonofluorosilane Spectral Line Table

Isotopic Species Id. No.

Rotalidiial Quantum Nos.Vil). State Int. Rotor

State n

Iy|)( F'rlin( F1 F

Frequency

MHz

1

] Acc.

! ±MHz

Ref.

C'^HaSi^'HaF'" 241 2. 0. 2<- 1. 0. 1 (Ground A 1 24 492.10 .10 233

2, 0, 2^ 1, 0. 1 (iround E 1 24 .500.10 .10 233

2, 0, 2^ 1, 0, 1 ( iround 24 .519.10 .10 233

2, 1, 1^ 1, 1. 0 (iround E 1 2,5 630.50 .10 2.33

2, 1, 1^ 1, I, 0 (iriiund A 0 25 771.30 .10 233

2. 1, 1^ 1, 1, 0 (Ground 25 806.77 .10 233

2, 1, 2<— 1, 1, 1 (Ground A 1 23 370.40 .10 233

2, 1, 2<- 1, 1, 1 (iround 23 389.50 .10 233

2, 1, 2^ 1, 1, 1 Ground E 1 23 .531.00 .10 2.33

3, 0, 3^ 2, 0, 2 Ground 36 583.44 .10 233

3, 1. 2^ 2, 1, 1 Ground E 0 38 658.40 1 .10 151

3. 1. 2<— 2, 1, 1 Ground A 0 38 658.92 .10 151

3, 2, 1^ 2, 2, 0 Ground 37 210.60 .10 233

3. 2. 2^ 2, 2, 1 Ground 36 897.80 .10 233

.5. 1. 4^ .5, 1, 5 Ground E 0 18 038.80 .10 233

.5, 1. 4^ .5. 1, ,5 Ground A 0 18 040..50 .10 233

6, 1. .5^ 6, 1, 6 Ground E 0 25 110.42 .10 233

6, 1, .5^ 6, 1, 6 Ground A 0 25 113.08 .10 233

7, 1. 6^ 7. 1, 7 Ground E 0 33 175.33 .10 233

7. 1. 6^ 7. 1. 7 Ground A 0 33 178.93 .10 233

9, 2. 7<- 9, 2. 8 Ground E 0 19 693.37 .10 233

9, 2, 7<— 9, 2, 8 Ground A 0 19 694.15 .10 233

10, 2, 8-^10. 2, 9 Ground E 0 27 060.92 .10 233

10, 2, 8^10. 2, 9 Ground A 0 27 062.30 .10 233 Not Reported 17 571.94 •1 151

Not Reported 17 573.95 .1 151 Not Reported 20 035.0 .1 151 Not Reported 20 263.58 .1 151 Not Reported 21 923.25 .1 151 Not Reported 21 924.75 .1 151

Not Reported 23 383.04 .1 151 Not Reported 25 492.96 .1 151 Not Reported 25 771.34 .1 151 Not Reported 26 402.76 .1 151 Not Reported 26 405.2 .1 151

Not Reported 26 519.40 .1 151 Not Reported 26 589.80 .1 151 Not Reported 26 741.37 .1 151 Not Reported 26 745.20 .1 151 Not Reported 28 695.25 1 151

C>2H3Si2»H2F''' 242 2. 0. 2^ 1, 0. 1 Ground 24 484.70 .10 233

2. 1, 1^ 1, 1, 0 Ground 25 791.38 .10 233

2, 1, 2^ 1, 1, 1 Ground 23 342.66 .10 233

C'2H,,Si-«'H2F'" 243 2. 0. 2^ 1. 0, 1 Ground 24 451.59 .10 233

2. 1. 1<- 1, 1, 0 Ground 25 776.55 .10 233

2, 1. 2^ 1, 1, 1 Ground 23 298.30 .10 233

C'^D.Si^^HjF'" 244 2, 0, 2^ 1, 0, 1 Ground 1 21 197.28 .10 290

2, 0, 2^ 1, 0, 1 (iround 21 211..54 .10 233

2. 1. 1^ 1. 1. 0 Ground 1 22 183.99 .10 290

77
Methylmonofluorosilane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

C'^DsSi^^HsF'" 244 2, 1, 1^ 1. 1, 0 Ground 22 206.50 .10 233

2, 1, 2-^ 1. 1. 1 Ground ZVJ oiV.oV 1 n . iU

2, 1, 2<- 1. 1. 1 Ground 20 326.70 .10 233

Qo. A

u. z.

rvu. z Ground 31 681.20 .10 233

3, 1, 2^ 2, 1, 1 Ground 33 274.15 .10 233

3. 2, 1*- 2, 2, 0 Ground 32 117.38 .10 233

6, 1, 5^ 6. 1, 6 Ground 1 Q ^I'X Ci'X 1 c\ .lU Zoo

7, 1, 6^ 7, 1 7 Ground 25 908.00 .10 233

A

U. OZ Q Ground 19 793.05 .10 233

11, 2, 9^11, 2 10 Ground 26 256.50 .10 233

C'2H3Si'"'D2F'^ 245 2, 0, 2^ 1. 0 1 Ground A 1 23 530.00 .10 233

2, 0. 2^ 1. 0 1 Grou nd E 1 9Q CQfi 9c: in Zoo

2, 0, 2^ 1. 0. 1 Ground 23 556.56 .10 233

9 1 1 1 Au Ground 24 814.44 .10 233

2, 1, 1. 1, 1 Ground 22 498.71 .10 233

3, 0, 3^ 2. 0, 2 Ground 35 089.71 .10 233

3. 2, 2^ 2, 2. 1 OO T*OJ.OO . 1lOn 9^^ zoo

5, 1, 4^ 5, 1, 5 Ground E 0 17 215.30 .10 233

J, 1 4^ 5, \ 5 Ground A 0 17 216.80 .10 233

6. 1. 5^ 6, \\ 6 Ground E 0 23 865.70 .10 233

6, 1. 5^ 6. 1, 6 Ground A 0 23 868.02 .10 233

8, 2, 6^ 8, 2, 7 15 547.9 \ 151

9, 2, 7^ 9, 2, 8 Ground E 0 21 019.80 !io 233

9, 2, 7<- 9, 2, 8 VJl OUIIU A 0 .10 233

10, 2, 8^10. 2. 9 Ground E 0 29 530.95 .10 233

10, 2, 8^ 10, 2, 9 Ground A 0 29 532.75 .10 233

C'^DaSi-'OHsF'^ 246 2, 0. 2^ 1, 0. 1 Ground 1 21 134.95 .10 290

2, 0, 2^ 1, 0, 1 Grou nd Zl91 MR14*0. lf\ 1 U 1 f> . lO Z7U

2, 1, 1^ 1, 1. 0 Ground 1 22 151. 1. 290

9 11

,

1^ 1, 1 AVJ Ground 22 173.46 .10 290

2, 1, 2<- 1. 1, 1 Ground 1 20 236.06 .10 290

2, 1. 2<^ 1, 1, 1 Ground 20 243.40 .10 290

3. 0, 3^ 2. 0. 2 yyl O UllU 31 577.4 \ 290

3, 1, 2^ 2, 1, 1 Ground 33 224.40 AO 290

oJ,

11, 3^ 2.11

,

z Ground 30 328.58 .10 290

3, 2, 2*- 2, 2, 1 Ground 31 813.56 .10 290

s-C'^HjDSi^^H^F'*' 247 2. 0, 2^ 1, 0. 1 Ground 22 907.78 .10 233

2, 1. 1^ 1, 1, 0 Ground Z^" 9A 094. UZI*. 7n( o . 1lOn 233

9 11 , 2^ 1, 1

1i Ground 21 909.03 .10 233

2, 0, 3^ 2. 0, 2 Ground 34 215.20 .10 233

3. 1. 2^ 2, 1, 1 Ground 35 999.00 .10 233

3, 1, 3^ 2, 1, 2 round ^9 897 ^8 .10 233

7, 1, 6^ 7. 1, 7 Ground 29 194.80 .10 233

10. 2, 8^10, 2, 9 Ground 21 694.80 .10 233

11. 2. 9^11, 2, 10 Ground 28 864.70 .10 233

a-C'^HaDSi-'^HsF'^ 248 2, 0. 2^ 1. 0, 1 Ground 23 467.05 .1 233

2, 1, 1^ 1. 1, 0 Ground 24 681.03 .1 233

2, 1, 2^ 1. 1, 1 Ground 22 406.4! .1 233

2, 0. 3^ 2, 0, 2 Ground 35 013.50 .1 233

r

78

•i
Methylmonolluorosilane

g^,^^,^^, , j^^, ^^j^,^^

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frecjuency Acc. Ref. No. Quantum Nos. r r MHz ±MHz

248 r> 1 9«— 9 J 1 Ground 36 972.82 .1 2.33

a 1 J 2 (iround 33 562.20 .1 233

a 9 ]<_ 2 2 0 Ground 35 616.20 233

3 2 2<— 2, 2_ 1 Ground 35 315.64 233

6^ 5^ 6'

l" 6 Ground 23 626 60 •} 233

7 6*— 7 J 7 Ground 31 201. 233

C'^HaSFHjF'^ 249 9 0o. 9<— 1 0 1 Ground 23 794.44 .10 233

9 1 1 <— 1 \ 0 Ground 25 017.26 .10 233

2, 1, 2^ 1, \, 1 ( ^ ro u nd 22 714.55 10 233

3, 0, 3^ 2, 0, 2 Ground .10 233

3, 1, 2^ 2, 1, 1 Ground •^7 47Q 80 .10 233

a 9 1 9 2, 0 Ground 36 083.60 .10 233

a 9 9<— 9 2, 1 Ground 35 799.60 .10 233

If) o R<—in 2, 9 Ground E 0 25 091.04 .10 233

in 9 R«—1 n 2, 9 Ground A 0 25 091.97 .10 233

11, 2, 9^11, 2,10 Ground E 0 aa 106 55 .10 233

1

oz. Q< 1 1 2.10 ( wToi I nn A 0 ^H lOQ 80 10 233

251 Z. n 0. 1 Ground 1 21 165.26 .10 290

2. 0, 2^ 1. 0. 1 Ground 21 179.40 .10 290

2, 1, 1^ 1, 1, 0 1 m1 1 TT H 99 lfS7 96 .10 290

o 11

1, 0 \J \. \J\Xl.V\X 9? 1 8Q ftQ 10 290

11

9.^ 1 1, 1 V71 \J LlllU 90 97fi 44 .10 290

9 1

9* 1 Z* 1

1, 1 Ground 20 284.02 .10 290

3, 0, 3^ 2. 0, 2 ( •rn 1 1 n H ^1 fS98 7^ . 10lO 290

3. 1, 3^ 2. 1, 2 (V 7»rni 1 IJ U1 1n1 H

^0 ^Ql 14 .10 290

9 9^ 9 Z* Z. 2, 1 ( . r* 1 1 1 n (1 Ol OO'-t-tJ 10 290

C'^HsSpsHDF'^ 252 2, 0. 2^ 1, 0. 1 Ground 24 034.80 .10 233

2, 1, 1^ 1, 1. 0 Ground 25 336.60 .10 233

2, 1, 2^ 1, 1, 1 1V.J. mI u MU nULiH 99 Ql Q nS 10 9^^

3, 0. 3^ 2. 0, 2 Ground 35 825.50 .10 233

3, 1, 2^ 2, 1, 1 Ground 37 943.80 .10 233

3. 1. 3^ 2. 1, 2 Ground 34 322.20 .10 233

3, 2. 1^ 2. 2, 0 Ground 36 192.50 .10 233

79
260 - Methylamine Molecular Constant Table Aminomethane

CH,,N . Cs(C3v,Cs) CH3NH2

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) K A

C'-H.N'-'H.

C'^D.N'-'D,

Cs 261 262

22 626.1 M

52 401.00 M

21 703.1 M

16 .549.52 M

10 314.8 M

15 571.72 M 199.66

Id. No. jtXa Debye Debye fx,. Debye eQq v.. Acc. I red aia d W|, d aj(. d (0,1 d

261

262

0.304 M

0.265 M

0. X

0. X

1.247 M

1.299 M

1980

684.7 2

References: ABC: 180, 187 Dj: D.,k: «: A: 180

Ijl: 180 eQq: V: 180, 344 I: ca: Add. Refs.: 22. 56, 74. 82. 83. 91, 96. 97. 117. 138, 168

For species 261. the quadrupole coupling constants are: Xaa= 2.3 MHz, Xbb = 2.0 MHz. Xcc = ^4.3 MHz. Ref: 180. Its inversion split- ting constant is 28604 MHz. Ref: 173. Its torsional frequency is 264 cm"'. Ref: 168. A,, = 29358 MHz for N= 1. Ref: 139. For

species 262. the quadrupole coupling constants are: Xaa = 2.35 MHz, Xbb = 2.12 MHz, and Xcc = ~4.47 MHz. Ref: 180. Its inversion

splitting constant is 2246±5 MHz. Ref: 173. Its torsional frequency is 201 cm Ref: 168.

80
Methylamine Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rot

State

orn f; Hype

F'

rfint

F, F

Frequency

MHz

Acc. ±MHzRei.

261 2, 0, 1, 1, Ground 9 706.10 .1 379

2, 0, <— 1, 1, Ground '^78

4, 2, 5, 1, Ground 10 262.41 .1 379

d. 9 C 1 J, 1

,

Ground 14 437.67 .1 379

4, 2, 5, 1, Ground 17 47.5.66 .1 379

4, 2, .5, 1. Ground 17 476.28 .1 379

4, 2, 5, 1. Ground 1 0 11f\ m 1 4, 2, 5, 1, Ground 19 777.85 .1 379

oz. O, 1

,

Ground 23 340.67 .04 379

4, 2, 5, 1, Ground 23 341.31 .1 379'

4, 2, «— 5, 1, Ground 28 .533.92 .1 379

4, 2, <— 5. 1, Ground \ an i;ac; q 01

4, 2, 5, 1, Ground A 0 36 4.52.1 91

A 9 C 1 Ground EH 0 28 534. 187

6, 1, 5, 2, Ground 12 592.65 .1 379

6, 1, 5, 2, Ground 13 175.80 378

6, 1, *— 5, 2, Ground 1 ^ 1 77 10 V i i .04- ^7Q

6, 1, 5, 2. Ground 21 930.00 .1 379

o, z. Ground 21 931.48 .1 379

6, 1, <_ 5. 2, Ground 23 449.39 .1 379

6, 1, <— 5, 2, Ground 23 449.65 .1 379

6, 1. <— 5, 2, Ground Z.O 4*00. i t 1 0 /y

6, 1, 5, 2, Ground A 0 29 312.4 91

0. 1 Ground E(+) 0 29 771.4 91

6, 1, 5. 2. Ground EH 0 13 176. 187

6, 1, 6, 1, Ground 18 475.8 378

6, 1, 6, 1, Ground ISiO 489 4-OZ.4'd. 0^781 0

7, 1, 7, 1, Ground 24 634.04 378

7 7 1 Ground 24 647.08 378

7, 3, 8. 2. Ground A 0 46 545. 187

7, 3, 8, 2, Ground A 0 48 082. 187

7, 3. 8, 2, Ground 4 nu 48 aa7 1 ft7 7, 3, 8, 2, Ground A 0 49 915. 187

a

o, 9 2 Ground EH 0 4 660. 187

s! 3, 9! 2! Ground A 0 5 767. 187

8, 3, 9, 2. Ground EH 0 6 450. 187

8, 3, 9, 2, C^round D 00 i . 1 R7

8, 3, 9, 2, Ground 15 907.61 .1 379

1 n 9 9, 3, Ground 28 515.45 .1 379

10, 2, 9, 3, Ground 41 658.42 378

10, 2, 9, 3, Ground 43 498.32 378

10, 2, 9, 3, Ground 40 990 A4 "^79 0/0

10, 1, ^10, 1. Ground 48 392.46 378

10, 1. ^10, 1, Ground 48 400.26 378

11, 4, ^12, 3, Ground 23 683.17 .1 379

11, 4, ^12, 3, Ground 23 861.40 .04 379

11, 4, •^12, 3, Ground A 0 32 104. 187

11, 4, ^12, 3, Ground A 0 32 283. 187

11, 4, ^12, 3, Ground EH 0 32 708. 187

11, 4, «-12, 3, Ground EH 0 43 040.72 378

1. Tentative assignments of the following lines were made by D. R, tide. Jr. in a letter to the Journal of Chemical Physics 20. 1812, (1952):

4, 2^5, 4 23,340.92 MHz.

6,.5<-52.3 23,449.90 MHz.

42.3—5,. 5 36,452.60 MHz.

However, in a later pubUcalion. these lines v/ere not identified and have been so recorded.

81
Methylamine

Spectral Line Table

Isotopic Species Id. . No.

Rotational Quantum Nos.Vib. State Int. Rot

State

orn f; Hyp€

F'

rfin€

F, F

Frequency

MHz

Acc. ±MHz

Ref.

261 11 4, ^12, 3, Ground 43 404.8 378

13 3, ^12, 4, Ground E(+) 0 6 270. 187

13 3, «-12, 4, Ground 8 411.94 .1 379

13 3, <—12. 4, Ground 11 961.29 .1 379

13

3' ^12" 4" Ground 12 162.44 .1 379

13 3, ^12, 4, Ground A 0 12 444. 187

13 3, •^12. 4. Ground 20 547.17 .04 379

13 3, ^12, 4, Ground 20 831.28 .04 379

14 3. *—13, 4, Ground EH 0 45 995. 187

15 5] ^16' 4" Ground 12 238.84 .1 379

15 5. ^16, 4, Ground 12 258.96 .1 379

15 5, *-16, 4, Ground 16 681.80 .1 379

15 5, ^16, 4, Ground 21 712.65 .1 379

15 5 *~16, 4, Ground 23 409.16 .1 379

15 5] ^16^ 4^ Ground 23 429.42 .1 379

15 5. *-16, 4, Ground EH 0 27 504. 187

15 5. ^16, 4. ( . rn 1 1 n H ' 27 758 40 1 379

17 4, ^16. 5. Ground 16 947.65 .1 379

17 4, <— 15 5, Ground 21 019.17 .1 379

17

4" ^16" 5, Ground 21 051.62 .1 379

17 4, ^16, 5, Ground 22 722.62 .04 379

17 4, ^16, 5, Ground EH 0 22 723. 187

17 4, -^16, 5, Ground A 0 32 155. 187

17 4 <—16 5 Ground A 0 32 187. 187

17

4" ^16^ 5, Ground EH 0 33 152. 187

18 6, ^19, 5, Ground EH 0 45 958. 187

18 6, ^19, 5, Ground EH 0 47 335. 187

18 6, ^19, 5, Ground EH 0 48 415. 187 18 6, <—19, 5 Ground A 0 49 426. 187 19

6" ^20' 5! Ground A 0 4 858. 187

19 6. ^20, 5, Ground A 0 4 860. 187

19 6, •^20, 5, Ground 0 6 500. 187

19 6, <-20, 5, Ground 13 415.33 .1 379

19 6, ^20, 5, Ground 13 416.57 .1 379

21 5. ^20, 6, Ground A 0 30 565. 187

21 5, *-20. 6. Ground A 0 30 566. 187 21 5, ^20. 6. Ground 42 104.30 378

21 5, ^20, 6, Ground 42 804.58 378

21 5. ^20, 6, Ground 43 346.58 378 Not Reported 2 781.95 .5 138

Not Reported 2 782.62 .5 138 Not Reported 3 015.17 .5 138 Not Reported 3 019.90 .5 138 Not Reported 3 389.74 .5 138 Not Reported 3 483.67 .5 138

Not Reported 3 505.76 .5 138 Not Reported C

.0 loo Not Reported 3 921.96 .5 138 Not Reported 4 076.65 .01 138 Not Reported 4 129.01 .5 138

82
Methylamine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. Slate n F' F, F MHz ±MHz

261 Not Reported 4 129.84 .5 1.-58 Not Rejjorted d 1/19 1

c; .o Not Reported 4 480.55 .5 1.38 Not Reported 4 543.00 .5 1.38 Not Reported 4 660.42 .5 1,38

Not Reported 4 857.86 .5 1.38 Not Reported A Qf^O QQ 4 O.jV.OO C.O 1 QQ 1.50 Not Reported 4 963.00 .5 138 Not Reported 5 006.82 .5 138 Not Reported 5 284.82 .01 1.38

Not Reported 5 546.75 .5 1.38 Not Reported o OUZ.O / C loo Not Reported 5 679.92 .5 1.38 Not Reported 5 680.84 .5 138 Not Reported 5 766.68 .5 1.38

Not Reported 5 876.61 .5 138 Not Reported O IOj.0'4' .0 1 QQ 1 JO Not Reported 6 172.20 .5 138 Not Reported 6 246.42 .5 138 Not Reported 6 269.81 .5 1.38

Not Reported 6 349.51 .5 138 Not Reported -O 1iOO^fi Not Reported 6 450.42 .5 138 Not Reported 6 469.43 .5 138 Not Reported 6 487.99 .5 138

Not Reported 6 500.42 .5 138 Not Reported A Af^c: fx A .Ui Loo Not Reported 6 748.80 .5 138 Not Reported 6 837.58 .5 138 Not Reported 6 867.17 .5 138

Not Reported Ground 6 894.81 .04 97 Not Reported Ground 0 VOV.OZ .1 Q7 Not Reported Ground 7 000.71 .1 97 Not Reported Ground 7 115.14 .1 97 Not Reported Ground 7 213.43 .1 97

Not Reported Ground 7 253.64 .1 97 Not Reported 7 QQ9 QQ I ooZ.Vo .Ul 1 QQ loo Not Reported 7 383.78 .01 138 Not Reported 7 515.56 .5 138 Not Reported Ground 7 718.11 .1 97

Not Reported Ground 7 727.74 .04 97 Not Reported Ground Q7 Not Reported Ground 7 896.89 .1 97 Not Reported Ground 7 911.49 .04 97 Not Reported Ground 8 131.59 .1 97

Not Reported Ground 8 201.65 .04 97 Not Reported Ground 8 233.22 .1 97 Not Reported Ground 8 268.99 .1 97 Not Reported Ground 8 684.29 .04 97 Not Reported Ground 8 813.22 .1 97

83
Methylamine

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frecjuency Acc. Ref. No. Quantum Nos. State n F' F' p MHz ±MHz

C'-HaN'^Ha 261 Not Reported Ground 8 884.29 .1 97 Not Reported Ground 8 950.90 .1 97

^^nt rSfriortpH 04 Q7 Not Reported Ground 9 079.39 .04 97 Not Reported Ground 9 127.61 .04 97

Not Reported Ground 9 128.14 .04 97 Not Reported Ground 9 223.83 .1 97 Not Reported Ground 9 285.77 .1 97 Not Reported Ground 9 452.63 .1 97 Not Reported Ground 9 453.06 .1 97

Not Reported Ground 9 459.96 .1 97 Not Reported Ground 9 584.09 .1 97 Not Reported Ground 9 779.33 .04 97 Not Reported Ground 9 938.95 .04 97 Not Reported Ground 10 108.45 .1 97

Not Reported Ground 10 109.61 .1 97 Not Reported Ground 10 178.86 .1 97 Not Reported Ground 10 240.48 .04 97 Not Reported Ground 10 379.79 .1 97 Not Reported Ground 10 381.21 .1 97

Not Reported Ground 11 786.82 378 Not Reported Ground 11 819.80 378 Not Reported Ground 11 878.90 .04 97 Not Reported Ground 12 061.92 .1 97 Not Reported Ground 12 271.51 .1 97

Not Reported Ground 12 306.86 .1 97 Not Reported Ground 12 444.04 .04 97 Not Reported Ground 12 445. 378 Not Reported Ground 12 482.96 .04 97 Not Reported Ground 12 484.56 .04 97

Not Reported Ground 12 744.25 .04 97 Not Reported Ground 12 841.24 .1 97 Not Reported Ground 12 903.16 .1 97 Not Reported Ground 13 050.32 .1 97 Not Reported Ground 13 242.99 .1 97

Not Reported Ground 13 336.58 .1 97 Not Reported Ground 13 390.07 .1 97 Not Reported Ground 13 464.76 .1 97 Not Reported Ground 13 528.26 .04 97 Not Reported Ground 13 592.68 .1 97

Not Reported Ground 13 799.79 .1 97 Not Reported Ground 13 897.60 .1 97 Not Reported Ground 13 932.46 .04 97 Not Reported Ground 14 033.54 .04 97 Not Reported Ground 14 044.39 .04 97

Not Reported Ground 14 098.16 .1 97 Not Reported Ground 14 115.35 .1 97 Not Reported Ground 14 215.99 .1 97 Not Reported Ground 14 339.06 .1 97 Not Reported Ground 14 494.64 .04 97

84
Methylamine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

261 Not Reported Ground 14 771.22 .1 97 Not Reported Ground 14 910.71 .04 97 Not Reported Ground 14 961.12 378 Not Reported Ground 15 047.4.3 .1 97 Not Reported Ground 15 094.56 .1 97

Not Reported Ground 15 109.45 .1 97 Not Reported Ground 15 141.72 .1 97 Not Reported Ground 15 146.16 .04 97 Not Reported Ground 15 252.52 .1 97 Not Reported Ground 15 357.69 .04 97

Not Reported Ground 1 C On'7 "70 15 iHl.ll .04 97 Not Reported Ground 15 842.14 .04 97 Not Reported Ground 15 999.68 .1 97 Not Reported Ground 16 088.98 .04 97 Not Reported Ground 16 089.84 .04 97

Not Reported Ground 16 228.00 378 Not Reported Ground 16 240.64 .1 97 Not Reported Ground 16 373.56 378 Not Reported Ground 16 410.63 .04 97 Not Reported Ground 16 661.73 .04 97

Not Reported Ground 16 670.02 .04 97 Not Reported Ground 16 742.98 .04 97 Not Reported Ground 16 911.46 .1 97 Not Reported Ground 17 042.46 .04 97 Not Reported Ground 17 108.99 .04 97

Not Reported Ground 17 148.36 378 Not Reported Ground 17 200.97 .04 97 Not Reported Ground 17 228.32 .1 97 Not Reported Ground 17 237.77 .1 97 Not Reported Ground 17 238.04 .1 97

Not Reported Ground 17 263.86 .1 97 Not Reported Ground 17 302.03 .04 97 Not Reported Ground 17 345.10 .1 97 Not Reported Ground 17 345.70 .1 97 Not Reported Ground 17 360.58 .1 97

Not Reported Ground 17 361.10 .1 97 Not Reported Ground 17 585.33 .1 97 Not Reported Ground 17 660.45 .1 97 Not Reported Ground 17 849.46 .04 97 Not Reported Ground 17 874.52 .1 97

Not Reported Ground 17 887.20 .1 97 Not Reported Ground 17 913.74 .04 97 Not Reported Ground 18 023.18 .1 97 Not Reported Ground 18 348.40 378 Not Reported 18 486. 187

Not Reported Ground 18 562.40 .1 97 Not Reported Ground io DOO.ou 1 Q7 Not Reported Ground 18 884.52 .1 97 Not Reported Ground 18 928.16 378 Not Reported Ground 19 013.55 .04 97

749-587 0-69—7 85
Methylamine

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc.

...

Ref.

jNo. Quantum Nos. State n f; F' F MHz ±MHz

261 Not Reported Ground 19 110.66 .04 97 Not Reported Ground 19 724.62 .04 97 Not Reported Ground 19 919.56 .04 97 Not Reported Ground 19 933.82 .1 97 Not Reported Ground 20 076.00 .04 97

Not Reported Ground 20 243.54 .04 97 Not Reported Ground 20 302.80 378 Not Reported Ground 20 325.82 .1 97 Not Reported Ground 20 911.74 .1 97 Not Reported Ground 20 947.05 .1 97

Not Reported Ground 20 971.70 .1 97 Not Reported Ground 20 973.15 .1 97 Not Reported Ground 21 013.62 .1 97 Not Reported Ground 21 027.06 .1 97 Not Reported Ground 21 035.13 .1 97

Not Reported Ground 21 244.56 .1 97 Not Reported Ground 21 297.12 .04 97 Not Reported Ground 21 477.62 .1 97 Not Reported Uround 21 614.33 .1 97 Not Reported Ground 21 765.23 .1 97

Not Reported Ground 21 842.31 .04 97 Not Reported Ground 22 060.71 378 Not Reported Ground 22 082.37 378 Not Reported Ground 22 112.46 .1 97 Not Reported Ground 22 258.35 .04 97

Not Reported Ground 22 369.95 378

- Not Reported Ground 22 381.96 378 Not Reported Ground 22 507.42 378 Not Reported Ground 22 527.93 .04 97 Not Reported Ground 22 528.21 .04 97

Not Reported Ground 22 581.49 .1 97 Not Reported Ground 22 588.42 .1 97 Not Reported Ground 22 637.08 378 Not Reported Ground 22 759.22 .04 97 Not Reported Ground 11 759.63 .1 97

Not Reported Ground 22 765.62 .1 97 Not Reported Ground 22 818.83 378 Not Reported Ground 22 980.95 .1 97 Not Reported Ground 22 981.60 .1 97 Not Reported Ground 23 071.58 378

Not Reported Ground 23 090.83 378 Not Reported Ground 23 106.34 378 Not Reported Ground 23 119.06 .04 97 Not Reported Ground 23 219.21 .1 97 Not Reported Ground 23 300.79 .1 97

Not Reported Ground 23 311.31 .1 97 Not Reported Ground OS 31 c; Zo oio.oo 07 Not Reported Ground 23 424.70 .1 97 Not Reported Ground 23 432.84 .1 97 Not Reported Ground 23 608.52 378

86
Methylamine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

261 Not Reported Ground 23 873.61 .04 97 Not Reported Ground 24 019 01 .1 97 Not Reported Ground 24 037.31 378 Not Reported Ground 24 078.75 .1 97 Not Reported Ground 24 320.57 .1 97

Not Reported Ground 24 382.16 .1 97

1 -T"«^i 1 Ti ri \Jl (J UJIU ^'T too. JO O J o Not Reported Ground 24 472.77 378 Not Reported Ground 24 520.75 .1 97 Not Reported Ground 24 889.42 .04 97

Not Reported Ground 24 889.80 .1 97 Not Reported Ground 24 993.76 .1 97 Not Reported Ground 25 063.65 .04 97 Not Reported Ground 25 206.62 .04 97 Not Reported Ground 25 401.99 1 97

Not Reported Ground 25 507.61 •1 97 Not Reported Ground 25 810.49 .1 97 Not Reported Ground 25 810.96 .1 97 Not Reported Ground 25 861.23 .1 97 Not Reported Ground 26 134.72 .1 97

Not Reported Ground 26 339.57 .1 97

i 'I U I IVC JJUi icu (vJl^rni 1 n ri <J UI Id 96 44.8 1

I 97 Not Reported Ground 26 487.00 .1 97 Not Reported Ground 26 493.54 .1 97 Not Reported Ground 26 493.82 .1 97

Not Reported Ground 26 588.65 .1 97

ZiLI KJtJ^.OXJ I 97 Not Reported Ground 26 695.43 .1 97 Not Reported Ground 26 717.89 .1 97 Not Reported Ground 26 728.77 .1 97

Not Reported Ground 26 733.54 .1 97 Not Reported Ground 27 S2S 13 .1 97 Not Reported Ground 27 445.47 .1 97 Not Reported Ground 27 504.75 .1 97 Not Reported Ground 27 553.24 378

Not Reported Ground 28 107.75 .04 97 Not Reported Ground 28 142.85 .04 97 Not Reported Ground 28 183.46 97 Not Reported Ground 28 186.02 .1 97 Not Reported Ground 28 380.93 .1 97

Not Reported Ground 29 055.20 97

l\nt Rf^nnrtpn 29 138 85 •J 97 Not Reported Ground 29 147.37 A 97 Not Reported Ground 29 191.47 .1 97 Not Reported Ground 29 244.20 .1 97

Not Reported Ground 29 770.2 111 Not Reported Ground 29 771.40 111 Not Reported Ground 30 025.9 111 Not Reported Ground 30 088.5 111 Not Reported Ground 30 226.8 111

87
Methylamine

gp^^^^^l ^.^^ ^^j^j^

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f; ^ype

F'

rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

261 Not Reported Ground 30 236.7 Ill Not Reported Ground 30 564.89

\ Not Reported Ground 30 566.42 111 Not Reported Ground 30 721.3 111 Not Reported Ground 31 140.5 111

Not Reported Ground 31 220.80 111 Not Reported Ground 31 221.20 Not Reported Ground 31 328.0 111 Not Reported Ground 31 583.41 111 Not Reported Ground 31 583.87 111

Not Reported Ground 31 846.1 111 Not Reported Ground 32 104.0 Not Reported Ground 32 112.7 111 Not Reported Ground 32 155.3 111 Not Reported Ground 32 187.0 111

Not Reported Ground 32 279.9 111 Not Reported Ground 32 283.3 Not Reported Ground 32 287.7 111 Not Reported Ground 32 634.2 111 Not Reported Ground 32 709.0 111

- - Not Reported Ground 32 916.8 111 Not Reported Ground 3/ 985.3 Not Reported Ground 33 136.5 111 Not Reported Ground 33 152.3 111 Not Reported Ground 33 302.0 111

Not Reported Ground 33 386.4 111 Not Reported Ground oo ooo o 66 ooo.Z Not Reported Ground 33 422.3 111 Not Reported Ground 33 506.8 111 Not Reported Ground 33 563.3 111

Not Reported Ground 33 599.1 111 Not Reported Ground 33 619.9 Not Reported Ground 33 631.5 111 Not Reported Ground 33 636.8 111 Not Reported Ground 33 639.5 111

Not Reported Ground 33 654.3 111 Not Reported Ground 33 862.2 Not Reported Ground 33 917.5 111 Not Reported Ground 33 990.5 111 Not Reported Ground 34 203. 111

Not Reported Ground 34 280.0 111 Not Reported Ground 0/1 Q 1 /I Q 34 ol4.o Not Reported Ground 34 527.7 111 Not Reported Ground 34 623.8 111 Not Reported Ground 34 773.1 111

Not Reported Ground 34 835.1 111 Not Reported Ground 34 896.7 Not Reported Ground 34 907.8 Not Reported Ground 35 185. Not Reported Ground 35 241.

88
Methylamine Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n F/

riypc F'rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

261 Not Reported (iround 36 015.0 Ill Not Reported (/round 111 ill Not Reported Ground 36 885.4 111

INot Reported Ground 36 957.5 111 Not Reported (iround 37 .564. 111

Not Reported Ground 37 8.54. 111 Not Reported Ground 1 1

1

1 i 1 Not Reported (Ground 41 615.12 187

INot Reported (iround 41 615.76 187 Not Reported Ground 41 658.42 378

Not Reported Ground 41 830.54 187 Not Reported Ground lO 1 Not Reported Ground 42 622.36 187

[yOi Reported (iround 42 720.94 187 Not Reported (Jround 43 040.72 378

Not Reported Ground 43 220.12 187 Not Reported Gro u nd

d.a 711 an Not Reported Ground 43 728.61 187

INot Reported Ground 44 188.60 187 Not Reported 44 205. 187

Not Reported 44 214. 187 Not Reported VTIOUllU l-^* Z,OU. 1 u Not Reported Ground 44 462.1 187

l\ot Reported Ground 44 573.06 187 Not Reported Ground 44 826.66 187

Not Reported Ground 44 967.40 187 Not Reported Ground ZOD.Oo 1 f!7 Not Reported Ground 45 324.22 187

iNOt Reported Ground 45 325.04 187 Not Reported Ground 45 336.60 187

Not Reported Ground 45 458.06 187 Not Reported Ground 4,q yen 1 ft? Not Reported Ground 45 769.96 187

INot Reported Ground 45 865.08 187 Not Reported Ground 45 957.66 187

Not Reported Ground 45 994.56 187 Not Reported Ground dft ifi^ ftd Not Reported (f round 46 368.42 187

iNOt Reported Ground 46 544.84 187 Not Reported Ground 46 575.18 187

Not Reported Ground 46 771.70 187 Not Reported Ground 4-0 OOO.U 1 ft7 Not Reported Ground 47 032.08 187 Not Reported Ground 47 075.84 187 Not Reported Ground 47 239.84 187

Not Reported Ground 47 334.60 187 Not Reported (Ground 47 608.08 187 Not Reported Ground 47 732.44 187 Not Reported Ground 48 180.38 187 Not Reported Ground 48 243.46 187

89
Methylamine

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rot

State

orn Hype

f; I F'

1

rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

261 Not Reported 48 385. 187 Not Reported Ground /to OCm HA 4o 000.64 378 Not Reported Ground 48 404.06 187 Not Reported Ground 48 414.83 187 Not Reported Ground 48 547.14 187

Not Reported Ground 48 715.82 187 Not Reported Ground 1 on Not Reported Ground 49 085.76 187 Not Reported Ground 49 086.38 187 Not Reported Ground 49 148.90 187

Not Reported Ground 49 426.06 187 Not Reported Ground 4y oou.uu 187 Not Reported Ground 49 614.02 187 Not Keported Ground 49 874.58 378 Not Reported Ground 49 952.46 187

Not Reported Ground 50 399.24 187 Not Reported Ground OU 4'Z0.4U Not Reported Ground 50 558.60 187 Not Reported Ground 50 658.48 187

- Not Reported Ground oU o/o.oU

Not Reported Ground 50 934.64 187 Not Reported Ground 51 048.46 187

262 1, 0, 1-^ 0, 0. 0 Ground 32 121.23 180

1, 1, 1^ 1. 0, 1 Ground c n

U

oc; /;qa 91 oo OVO.Zl

1. 1. 1^ 1, 0, 1 Ground A 0 35 812.36 180

1, 1, l'^ 1, 0, 1 Ground E 0 35 866.^0- 180

1, 1, 1^ 1, 0, 1 Ground A 0 36 109.50 180

2, 1, 2^ 2, 0, 2 Ground E 0 34 755.67 180

2, 1, 2^ 2, 0, 2 ijrouna AA u

OA OCA AO 04 oo4.4o 1 QO loU

2, 1, 2^ 2, 0, 2 Ground E 0 34 911.62 180

2, 1, 2<— 2, 0, 2 Ground A 0 35 151.58 180

3, 1, 3^ 3, 0, 3 Ground E 0 33 360.49 180

3, 1, 3^ 3, 0. 3 Ground A 0 33 454.41 180

3, 1, 3^ 3, 0, 3 Ground jl oo olz.oo loU

3, 1, 3^ 3. 0, 3 Ground A 0 33 751.65 180

4, 1, 3*- 3, 2. 1 Ground A 0 23 967.46 180

4, 1, 3-^ 3, 2, 1 Ground A 0 24 125.48 180

4, 1, 3^ 3, 2, 1 Ground E 0 24 230.29 180

4, 1. 3^ 3, 2, 1 Ground t, u

0/1 AO 1 oo loU

4, 1, 3^ 3, 2, 2 Ground E 0 24 342.40 180

4, 1, 3<— 3, 2, 2 Ground E 0 24 489.58 180

4, 1, 4^ 4, 0. 4 Ground E 0 31 565.45 180

4, 1, 4^ 4, 0, 4 Ground A 0 31 656.92 180

4, 1, 4^ 4, 0, 4 Ground 17

SL. Ayj oi i 10,ZD loU

4, 1, 4^ 4, 0, 4 Ground A 0 31 954.11 180

5, 1, 5^ 5. 0, 5 Ground E 0 29 431.36 180

5, 1. 5^ 5, 0, 5 Ground A 0 29 520.90 180

5, 1, 5^ 5, 0, 5 Ground E 0 29 581.31 180

5, 1, 5^ 5. 0, 5 Ground A 0 29 817.76 180

90
Methylamine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

C'''D3lN"D2 7, 1, 7^ 7, 0,

-7

( Ground z4 44o.o5 180

7, 1, 7<- 7, 0. 7 Ground A 0 24 531.04 180

7, 1, 7«- 7, 0, 7 Ground E 0 24 595.38 180

7, 1, 7*- 7, 0, 7 Ground A 0 24 826.54 180

263 1, 0, l'^ 0, 0, 0 36 436.2 .5 312

1, 0, l'^ 0, 0, A

U OO 400.0 r.O 312

2, , 2, , 28 601.6 .5 312

3, , *- 2, , 25 570.4 .5 312

3, , ^ 2, , 27 815.0 .5 312

3, , (-3, , 37 015.4 .5 312

3, , «- 3, , 0*7 nc 1 A oi Vol.

.5 312

4, , ^ 3, , 24 913.1 .5 312

4, , 3, , 31 656.2 .5 312

4, , *- 4, , 36 451.1 .5 312

4, , <- 4, , 37 386.3 .5 312

5, , 5, , 35 588.1 .5 312

5, , ^ 5, , 35 590.6 .5 312

6, , 6, , 35 171.4 .5 312

6, , 6, , 37 427.1 .5 312

7, , 6, , 34 670. 312 Not Reported or QOA c r

.0 312 Not Reported 27 472.5 .5 312 Not Reported 29 507.2 .5 312 Not Reported 29 913.2 .5 312

Not Reported 30 010.5 .5 312 Not Reported on fxcn 0 c.O olz Not Reported 31 422.9 .5 312 Not Reported 31 933.7 .5 312 Not Reported 32 178.0 .5 312

Not Reported 32 267.4 .5 312 Not Reported OO ooo rt r.0 0 1 o 312 Not Reported 32 968.3 .5 312 Not Reported 33 160.4 .5 312 Not Reported 33 664.2 .5 312

Not Reported 33 692.1 .5 312 Not Reported OO OOU. 0 1 o olz Not Reported 33 900. 312 Not Reported 34 625. 312 Not Reported 34 962.4 .5 312

Not Reported 34 995.0 .5 312 Not Reported 35 100. 312 Not Reported 35 135.7 .5 312 Not Reported 35 202.1 .5 312 Not Reported 35 324.7 .5 312

Not Reported 36 753.7 .5 312 Not Reported OC Ol c c o6 816.6 .5 312 Not Reported 36 856.9 .5 312 Not Reported 37 148. 10. 312 Not Reported 37 230. 10. 312

Not Reported 37 320.9 1 .5 312 Not Reported 1 37 807.9 1 .5 312 Not Reported 1 37 812.2 .5 312 Not Reported 37 840.5 .5 312 Not Reported

1

38 023.7 1

1

.5 312

91
270 . Methylphosphine

CH,P Cs(C3v,C,

Molecular Constant Table CH.PH,

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) Dj K A

C'^HaP^'Hs 271 71 869.5 M 11 792.6 M 11 677.7 M

Id. No. /u-a Debye Debye /JL^ Debye eQq V3 Ace. I red Wa d C0|, d d CO,, d

271 0.958 M 0. X 0.541 M 685.2 5

References: ABC: 325

ix: 325

Dj:

eQq:

Coupling parameter: Ia= 3.212 amu A^- Ref: 325.

-'JK- V: 325

k:

I:

A:

0):

Methylphosphine

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum NOS. State n F/ F' F MHz ±MHz

C'^HaP^'Hz 271 Q 0, 0, 0 Ground A 4 23 224.6 • 1 325

I, 0 1^ 0, 0, 0 Ground E 3 23 250.0 • 1 325

1, 0 1^ 0, 0, 0 Ground A 3 23 279.0 • 1 325

1, 0 1^ 0' 0' 0 Ground A 2 23 314.8 325

1, 0 1^ 0. 0, 0 Ground E 2 23 324.2 •J 325

1, 0 1^ 0, 0, 0 Ground E 1 23 394.8 • 1 325

1. 0 1^ 0, 0. 0 Ground A 1 23 395.9 • 1 325

1, 0 1^ 0, 0, 0 Ground 0 23 470.3 1 325

1, 1 0^ 2, 0. 2 Ground E 0 13 437.1

;J 325

1, 1 0^ 2, 0, 2 Ground A 0 13 451.8 325

1, 1 1^ 2, 0, 2 Ground E 0 12 756.4 325

2, 0 2^ 0, 1 Ground E 1 46 789.2 325

2, 0 2^ 0, 1 Ground A 1 46 791.4 325

2, 0 2^ 0, 1 Ground 0 46 940.1 325

2, 1 1^ 1. 0 Ground E 1 46 791.5 325

2, 1, 1^ 1, 0 Ground A 1 46 895.1 325

2, 1, 1^ 1, 0 Ground E 0 46 975.7 325

2, 1, 1^ 1, 0 Ground A 0 47 052.2 325

2, 1, 2^ 1, 0 Ground A 1 46 685.8 325

2, 1, 2^ 1, 1 Ground E 1 46 787.4 325

2, 1, 2^ 1, 1 Ground A 0 46 827.3 325

2, 1, 2^ 1, 1 Ground E 0 46 904.6 325

4, 0, 4^ 1, 2 Ground A 0 33 202.0 325

6, 2, 4^ 1, 6 Ground E 0 14 695.6 325

6, 2, 4^ 1, 6 Ground A 0 14 991.7 325

6, 2, 5^ 7, 1, 7 Ground E 0 17 142.2 325

6, 2, 5^ 7, 1, 7 Ground A 0 18 141.1 325

9, 1, 8^ 8, 2, 6 Ground A 0 32 864.5 325

9, 1, 8^ 8, 2, 6 Ground E 0 33 158.1 325

9, 1, 9^ 8, 2, 7 Ground A 0 27 819.0 325

9, 1, 9^ 8, 2, 7 Ground E 0 28 820.8 325

14, 2, 12^13, 3,10 Ground A 0 27 720.4 325

14, 2, 12^13, 3,10 Ground E 0 28 332.3 325

14, 2, 13^13, 3,11 Ground A 0 27 435.8 325

14, 2, 13^13. 3,11 Ground E 0 27 737.9 325

92
280 - Methylgermane Molecular Constant Table CHgGe C3v(C3v,C3v) CH^jGeHj

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) D., DjK K

C'2H3Ge'»H3 G3V 281 8 710.65 M 8 710.65 M .025 C'^HjGe'^H:, C3V 282 8 679.39 M 8 679.39 M

C'2H3Ge"H3 C3V 283 8 664.44 M

n y y A A A 8 664.44 M .025 C'2H3Ge'^H3 C3V 284 a 649.68 M 8 649.68 M

C'2H3Ge'''H3 C3V 285 8 621.48 M 8 621.48 M

C'^H3Ge'»H3 C3V 286 8 337.34 M 8 337.34 M

C'^HaGe'^Hj c 287 8 305.40 M 8 305.40 M

C'^H3Ge'''H3 C3V 288 8 275.09 M 8 275.09 M

C'^H3Ge'8H3 C3V 289^ 8 246.20 M 8 246.20 M

C'2H3GeTMD3 C3V 291 7 993.00 M 7 993.00 M

C'2H3Ge^2D3 C3V 292 7 971.06 M 7 971.06 M

C'^HjGe'^Da C3V 293 7 950.08 M 7 950.08 M

C'2D3Ge'»H3 G3V 294 7 097.27 M 7 097.27 M

C'^DjGe^^Hj C3V 295 7 067.29 M 7 067.29 M

C'2D3Ge^^H3 C3V 296 7 038.80 M 7 038.80 M

C'2H3Ge'»H2D Cs 297 8 600.70 M 8 313.68 M

C'^HjGe^^H^D Cs 298 8 572.10 M 8 286.83 M

C'^HaGe^^'H^D Cs 299 8 544.89 M 8 261.25 M

C'2H3GeTMHD2 Cs 301 8 361.24 M 8 076.18 M

C'^HaGe^HDj Cs 302 8 335.64 M 8 052.44 M

C'2H3Ge^^HD2 Cs 303 8 311.26 M 8 029.80 M

C'2H2DGeTMH3 Cs 304 8 143.64 M 8 020.12 M

<-s oUo 8 112.37 M 7 989.86 M

Cs 306 8 082.68 M 7 961.06 M

C'^H3Ge^'^D3 C3V 307 7 930.11 M 7 930.11 M

Ci='D3Ge^«H3 C3V 308 7 011.67 M 7 011.67 M

Id. No. ju.a Debye ju-b Debye Debye eQq V3 Acc. I red Wa d OJh d We d W(j d

281

283

284

0.635 M

0.651 M

0. X

0. X

0. X

0. X

3

. ..J

1239 25

References: ABC: 206, 248 Dj: Djk: 248 k: A:

M: 248, 377 eQq: 248 V: 248 I: w: Add. Ref.: 205

The coupling parameter for species 299 and 303 is: Ia= 3.125 amu A^ The couphng parameter for species 306 is: Ia = 6.251 amu A^. Ref: 248.

93
Methylgermane Spectral Line Table

Isotopic Species Id. Rotationa Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum NOS. State n f; F' F, F MHz ±MHz

C'^HaGe^'Ha 281 1, 0^ 0. 0 Ground 17 421.36 .10 248

2, 0^ 1, 0 Ground 34 842.46 .10 248

282 1 0, 0 Ground 17 358.78 .10 248

2, 0^ 1, 0 Ground 34 717.54 .10 248

C'^HjGe^Ha 283 1, 0^ 0, 0 Ground 11/2 9/2 17 328.4 .10 248

1, 0^ 0, 0 Ground 17 328.4 .10 248

1, 0^ 0, 0 Ground 9/2 9/2 17 328.9 .10 248

2, 1^ 1, 1 Ground 13/2 11/2 34 656.75 .10 248

2, 1^ 1, 1 Ground 9/2 9/2 34 657.23 .10 248

2, 1^ 1, 1 Ground 11/2 9/2 34 657.23 .10 248

C'^HjGe'^Ha 284 1, 0^ 0, 0 Ground E 1 17 257.3 .10 248

1, 0-^ 0 0 Ground \ I 17 258.8 .10 248 0<— 0, 0 Ground 17 299.43 .10 248

2] 0^ 1, 0 Ground E 1 34 514.5 .10 248

2, 0^ 1 0 Ground J 34 517.6 .10 248

2, 0^ 1, 0 Ground 34 598.62 .10 248

C'^HaGe^^Hs 285 11 , n* 0, 0 Ground 17 242.86 .10 248

2, 0^ 1, 0 Ground 34 485.90 .10 248

286 1, 0^ 0, 0 Ground 16 674.75 .10 248

2, 0^ 1, 0 v^l (J UllLl 33 349 30 .10 248

C'^HsGe^^Ha 287 1, u*— 0, 0 Ground 16 610.80 .10 248

2, 0^ 1, 0 Ground 33 221.62 .10 248

C'^HaGe'-'Hs 288 1, 0^ 0, 0 Ground E 1 16 510.1 .10 248

1, 0 ( rn 1 1 n H 11 16 511.5 .10 248

1 0, 0 Ground 16 550.20 .10 248

2, o->- 1, 0 Gro u nd E 1 33 020.2 .10 248

2, 0^ 1 0 Ground \ I 33 023.0 .10 248

2. 0^ 1, 0 Ground 33 100.38 .10 248

C^HsGe'^Hj 289 1 , n< 0, 0 Ground 16 492.60 .10 248

2, 0-^ 1, 0 ( •w^ct^^nf\ 32 984.82 .10 248

C''^H3{;e^»D3 291 1, 0^ 0, 0 Ground 15 985.97 .10 248

2, 0^ 1, 0 Ground 31 972.02 .10 248

C'^HsGe'^Dj 292 1, 0^ 0, 0 Ground 15 942.15 .10 248

2, 0^ 1 0 Ground 31 884.25 .10 248

pi2i_f rp74r) 293 1, 0^ 0, 0 (v7i-r rr\\ f

1Li1 n1 iUH 15 900.15 .10 248

2, 0^ 1

,

0 Ground IT 11 31 729.5 .10 248

2, 0^ 1, 0 Ground A 1 31 730.7 .10 248

2, 0^ 1, 0 \Jl KjUIIkJL 31 800 35 .10 248

C'^DaGe'^Hj 294 1, 0^ 0, 0 Ground 14 194.60 .10 248

2, 0^ 1, 0 Ground 28 389.10 .10 248

C'^DjGe'^Ha 295 1, 0^ 0, 0 Ground 14 134.73 .10 248

2, 0^ 1, 0 Ground 28 269.15 .10 248

94
Methylgermane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n F/ F' F, F MHz ±MHz

C'^DjGe^Ha 296 ]^ o<— 0, 0 Ground 14 077.80 .10 248

1! o<- 0! 0 Ground 14 105.9 .10 248

2, 0-^ 1, 0 Ground 28 155.20 .10 248

2, o<— 1, 0 Ground 28 211.9 .10 248

C'^HaGe^HjD 297 2, 0, 2<— 1, 0, 1 Ground AE 0 33 827.32 .10 248'

2, 1^ 1, 1, 0 Ground E 0 33 987.35 .10 248

2, 1] 1^ 0 Ground A 0 34 115.77 .10 248

2, 1, 2^ 1, 1, 1 Ground A 0 33 541.74 .10 248

2, 1, 2^^ 1, 1, 1 Ground AE 0 33 670.44 .10 248

C'^HjGe'^H^D 298 2, 0, 2-^ 1, 0, 1 Ground AE 0 33 716.38 .10 248 '

2, 1, 1<- 1, 1, 0 Ground E 0 66 874.76 .10 248

2, 1, l'^ 1, 1, 0 Ground A 0 34 003.14 .10 248

2, 1, 2<^ 1, 1, 1 Ground A 0 33 432.60 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 33 560.98 .10 248

C'^HjGe^HjD 299 2, 0, 2«- 1, 0, 1 Ground AE 0 33 610.80 .10 248'

2, 1, l'^ 1, 1, 0 Ground E 0 66 Ibl.bb .10 248

2, 1, 1^ 1, 1, 0 Ground A 0 33 895.92 .10 248

2, 1, 2^ 1, 1, 1 Ground A 0 33 328.63 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 33 767.80 .10 248

C'^HjGe^'HDj 301 1, 0, 1<— 0, 0, 0 Ground AE 0 16 437.5 .10 248'

2, 0, 2<— 1, 0, 1 Ground AE 0 61 873.10 .10 248

2, 1^ 1<— 1, 1, 0 Ground E 0 33 075.77 .10 248

2 \ 2«— \ \ 0 Ground A 0 33 159.90 .10 248

2! \\ 2^ h 1! 1 Ground A 0 32 589.79 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 32 674.06 .10 248

C'^'HsGe^HDj 302 1, 0, 1«— 0, 0, 0 Ground AE 0 16 388.2 .10 248'

2] 0! 2<— \\ q\ 1 Ground AE 0 32 774.60 .10 248

2' 1' 1<- \\ \\ 0 Ground E 0 32 975.24 .10 248

2, 1, 1, 1, 0 Ground A 0 66 059.35 .10 248

2, 1, 2<- 1, 1, I Ground A 0 32 492.95 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 32 577.29 .10 248

C'^HgGe'^HD^ 303 1, 0. l'^ 0, 0, 0 Ground AE 0 16 341.2 .10 248'

2, 0, 2<- 1, 0, 1 Ground AE 0 61 60O.5O .10 248

2, 1, l'^ 1, 1, 0 Ground E 0 32 879.44 .10 248

2, 1, 1«- 1, 1, 0 Ground A 0 61 963.60 .10 O/l 0

2, 1, 2^ 1. 1, 1 Ground A 0 32 400.66 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 32 485.06 .10 248

C'^HjDGe'OHj 304 1, 0, 0, 0, 0 Ground AE 0 16 163.70 .10 248'

2, 0, 2<- 1, 0, 1 Ground AE 0 61 327.55 .10 248

2, \\ 1<— 1! 1! 0 Ground E 0 32 359.02 .10 248

2! \\ 1!

1' 0 Ground A 0 32 451.02 .10 248

2, 1, 2-^ 1, 1, 1 Ground A 0 32 203.98 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 32 295.85 .10 248

C'^HjDGe^Ha 305 1, 0, 1^ 0. 0, 0 Ground AE 0 16 102.40 .10 248'

2, 0, 2<- 1, 0, 1 Ground AE 0 32 204.25 .10 248'

2, 1, 1<- 1, 1, 0 Ground E 0 32 235.50 .10 248

2. 1, 1^ 1, 1, 0 Ground A 0 32 326.96 .10 248

1. For the ground torsional level, the loi»—Ow and 2o2<— loi Unes did not show significant A-E splitting.

95
Methylgermane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f;1 F' E1 F MHz ±MHz

C'2H2DGe"H3 305 2, 1, 2^^ 1, 1, 1 Ground A 0 32 081.95 .10 248

2. 1, 2*- 1, 1, 1 Ground AE 0 32 173.40 .10 248

C'^HzDGe^'Ha 306 1, 0, 1^ 0, 0, 0 Ground AE 0 16 043.80 .10 248'

2, 0, 2«— 1, 0, 1 Ground AE 0 32 087.40 .10 248'

2, 1, 1^ 1, 1, 0 Ground E 0 32 118.06 .10 248

2, 1, 1^ 1, 1, u Ground A 0 oZ /Uv.lO .10 248

2, 1, 2<- 1, 1, 1 Ground A 0 31 965.84 .10 248

2, 1, 2^ 1, 1, 1 Ground AE 0 32 056.74 .10 248

307 2. 0<- 1, 0 Ground 31 720.45 .10 248

C'^DaGe^'^Ha 308 2. 0^ 1, 0 Ground 28 046.70 .10 248

1. For the ground torsional level, the loi'*~Ooo and 2o2'*— loi lines did not show significant A-E splitting.

96
310 - Methylsilane Molecular Constant Table

Methylsilicane

CHeSi C;,v(C,,v,C.,v) CHaSiH;,

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D., DjK K A

c 311 10 968.96 M 10 968.96 M -.001

C3V 312 10 606.52 M 10 606.52 M

C3V 313 10 885.54 M 10 885.54 M

C'^H,SiTMH, C3V 314 10 806.53 M 10 806.53 M

C'^HjSFDj 315 9 622.78 M 9 622.78 M

r 316 9 572. M 9 572. M

*'-3'"' '-'3 r 317 9 525. M 9 525. M

r^3v 318 8 079.03 M 8 079.03 M

c 319 8 028.81 M 8 028.81 M

C'^DjSPDj r^3V 321 7 981.12 M 7 981.12 M

c 322 7 889.68 M 7 889.68 M

C'^DjSPHs c^3V 323 9 119.98 M 9 119.98 M

Csv 324 9 040.82 M 9 040.82 M

C'2H3Si''H2D Cs 325 46 750. M 10 671.21 M 10 270.68 M

C'^H3Si''HD2 326 39 717. M 10 229.72 M 9 822.25 M

C'2H2DSi''H3 Cs 327 10 346.48 M 10 148.29 M

C'^H2DSi''D3 Cs 328 9 100.18 M 8 948.85 M

C'2D3Si"H2D Cs 329 8 874.74 M 8 597.77 M

C'2D3Si''HD2 Cs 331 31 300. M 8 533.77 M 8 250.06 M

s-C'2H2DSi"H2D Cs 332 10 035.66 M 9 523.42 M

a-C'2H2DSi''H2D c, 333 9 962.01 M 9 645.77 M

s-C'2H2DSi''HD2 Cs 334 9 494.63 M 9 315.03 M

a-C'^H2DSi''HD2 c, 335 9 615.96 M 9 1.53.46 M

1

Id. No. /u-a Debye Debye /Xt Debye eQq V3 Acc. Irfd OJa d aj|, d (Oj. d (u„ d

311 0.73 M 0. X 0. X 1660

References: ABC: 28, 172 Dj: 172 D,,k: k: A:

M: 28, 172 eQq: V: 344 I: o:

Add. Refs.: 90, 130, 141, 170, 287

Ve < 150 cal/mol. Ref: 258.

97
Methylsilane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f;1 F' E' I F MHz ±MHz

C'^HsSi^SHa 312 1, 0, 21 150.7 172

1, ^ 0, 21 213.04 172

C'^DjSi^'Da 318 1, ^ 0, 16 085.3 .4 172

1, <- 0, 16 125.04 .3 172

1, 0, 16 158.06 .2 172

2, ^ 32 170.41 .15 172

2, ^ }; 32 239.63 .15 172

2, <— 32 316.07 .15 172

C'^DsSi^sDs 319 2, 1, 32 115.25 .15 172

C'^DgSi^ODs 321 2, 1, 31 924.49 .15 172

C'^DjSi^sDa 322 2, 31 558.70 .3 172

C'^DgSi^'SHj 323 1, ^ 0, 18 150.0 .3 172

1, ^ 0, 18 192.81 .2 172

1, ^ 0, 18 239.95 .15 172

C'^DoSi^^H, 324 1, 0, 18 081.65 .3 172

C'2H3Si''H2D 325 1, 0, 1^ 0, 0, 0 20 801.74 172

1, 0, 1<- 0, 0, 0 20 906.36 .1 172

1, 0, 1^ 0, 0, 0 20 941.87 .1 172

2, 0, 2^^ 1, 0, 1 41 758.92 172

2, 0, 2*- 1, 0, 1 41 880.10 .4 172

2, 1, 1-^ 1, 1, 0 E 0 42 264.12 .4 172

2, 1, 1*- 1, 1, 0 A 0 42 283.52 .2 172

2, 1, 2-^ 1, 1, 1 A 0 41 482.84 .2 172

2, 1, 2-^ 1, 1, 1 E 0 41 502.14 .4 172

8, 1, 7^ 8, 1, 8 14 405.90 .1 172

9. 1. 8^ 9, 1, 9 17 998.95 .2 172

10, 1, 9-^ 10, 1,10 21 986.66 172

11, 1,10^ 11, 1,11 26 365.07 172

12, 1,11-^ 12, 1,12 31 130.43 172 Not Reported 14 404.95 172

C'2H3Si''HD2 326 1, 0, 1^ 0, 0, 0 19 995.56 .1 172

1, 0, 1^ 0, 0, 0 20 052.10 .1 172

2, 0, 2^ 1. 0, 1 40 100.00 .4 172

2, 1, 1^ 1, 1, 0 E 0 40 503.64 .4 172

2, 1. 1^ 1, 1, 0 A 0 40 510.98 .4 172

2, 1, 2^ 1, 1, 1 A 0 39 696.34 .2 172

2, 1, 2^ I, 1, 1 E 0 39 703.74 .2 172

8, 1, 7^ 8, 1, 8 14 651.55 .1 172

9, 1, 8^ 9, 1, 9 18 303.84 .1 172

10, I. 9^10, 1,10 22 353.73 .2 172

11, 1,10<- 11, 1,11 26 797.15 .2 172

12, 1,11-^12, 1,12 31 627.61 .2 172 Not Reported 14 649.60 .2 172 Not Reported 14 663.02 172

98
Methylsilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Acc. Ref. No. Quantum Nos. r r MHz ±MHz

C'2H2DSi''H3 327 1, 0, 1*- 0, 0, 0 20 437.6 172

I 0 l<— 0, 0, 0 20 494.80 172

2 0 2<— I 0 1 40 988.76 .4 172

2 I I 0 0 41 155.38 .2 172

2^ 1«— 1^ 0 0 41 187.62 .2 172

2, 1, 2<- 1, 1, 1 0 40 791.24 .2 172

2 2*— 1^ 1 I E 0 40 823.44 .2 172

C'2H2DSi''D3 328 1, 0, 1, 0, 0 18 002.90 .2 172

1, 0, 1, 0, 0 18 049.08 .1 172

2 0 2*— I 0 I % 097 S5 .2 172

9 1 1^ 1 1 0\J E 0 36 246 1

7

.3 172

9 1 1 < 1 1 nu

A

\ Au 36 249.26 .3 172

2, 1, 2^ 1, 1, 1 •JkJ 0 t J.J-' .3 172

2, 1, 2^ 1, 1, 1 A

A

U .2 172

9 11

,

11 , 1i. 11 E 0 9 1X 791 z

C'^DsSibH^D 329 11

,

Au, A AU 17 428.89 .3 172

1 A AU, A AU 17 472.57 .1 172

2, 0, 2^ 1, 0, 1 "M. 949 (S^ .2 172

2, 1, 1^ 1, 1, 0

A U .z9 172

11

,

9<Z*^

11

,

11

,

1I A 0 9 172

C'^DaSi^HDj 331 1 nu, nu. u. u 16 743.20 172

1 0 Q Q 16 783.88 .2 172

2, 0, 2-^ 1^ 1 33 323 172

2, 0, 2-^ 1, 0, 1 33 409 81 .2 172

2^ 0, 2<— 1^ 0, 1 33 483.80 .2 172

2 0, 2^^ 1^ 0, 1 33 565.07 .2 172

2^ 1^ 1<_ 0 \ 0 33 851.17 .2 172

2! 1! 2^ I,

1'

1 33 213.00 .2 172

2, 1, 2^ 1, 1, 1 u 33 283.75 .2 172

8, 1, 7^ 8, 1, 8 10 208.20 .2 172

9, 1, 8^ 9, 1, 9 12 754.31 .2 172

10, 1, 9^ 10. 1, 10 15 579.07 .2 172

11, 1, 10^ 11, 1, 11 1 8 679 69 .3 172

12, 1, 11^ 12, 1, 12 22 053.50 .3 172

14, 1, 13^ 14, 1, 14 29 600.50 1. 172

15, 1,14^15, 1,15 J<J 759 J J 7. 1J. 71 .4 172 Not Reported 00 ft^Q ooy,\j0 .4 172

s-C'^H2DSi''H2D 332 1, 0, 19 559.2 172

2, 0, 2<^ 1, 0, 1 J^97 1J. 11 11 .Ot 84 172

2, 1, 1^ 1, 1, 0 H9 699 99 172

2, 1, 2^ 1, 1, 1 38 605 44 172

a-C'2H2DSi''H2D 333 1, 0, 19 607.85 172

2, 0! 2^ 1, 0! 1 39 21 3 18 172

2, 1, 1^ 1, 1, 0 39 531 54 172

2, 1. 2^^ 1, 1, 1 ^8 899 06 172

s-C"^H2DSi''HD2 334 1, 0, 18 809.74 .1 172

2,

0' 2^ 1, 0, 1 37 618 28 172

2, 1, 1^ 1, 1, 0 ^7 798 60 172

2, 1, 2^ 1, 1, 1 37 439 40 172

a-C'2H2DSi''HD2 335 1, 0, 18 720.19 .1 172

1, 0, J8 769.49 .1 172

2, 0, 2^ 1, 0! 1 37 533.0 172

2, 1, 1«- 1, 1, 0 38 001.08 172

2, 1, 2^^ 1, 1, 1 37 076.08 172

99
340 - Methyltin Molecular Constant Table Methylstannane

CHeSn C3v(C3v,C3v) CHjSnHs

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) Dj DjK K A

C'2H3Sn""H3 C3V 341 6906.35' M

1

Id. No. /Xa Debye /Xb Debye ^L^. Debye eQq Va Acc. Ired d ojb d oic d

1 ^

1

d

1 341 0.68 M 0. X 0. X 650 30

1. Cahill and Butcher call this rotational constant B,, although they do not indicate that any non-torsional mode was excited.

References: ABC: 314 D,,: Djk: , k: A:

ix: 40 eQq: V: 314 I: w: Methyltin v c . 1 i

• -r 1,1 spectral Line lable

Isotopic Dpecies Id.

1 Rotational Vii). State Int. Rotor Hyperfine r requency

1 AAcc. Ret. No. Quantum Nos. State n F' F MHz ±MHz

1 21 1 C 1 1 KT 1 C'''H3hn"''H3 341 1, <^ U, Ground A 010 "7/10 '70 13 /4y. /u 314

1, ^ u. Ground 6 13 ioo.ZZ 314

1, *~ 0, Lrrouna AA 0Z 13 /5/.0/ 314

1, ^ 0, Ground E 2 13 759.66 314

1, ^ 0. Ground E 1 13 775.97 314

1, <— 0, Ground A 1

1 1) i'70 no 13 770.92 314

1, «— 0, Ground 0 13 800.31 314

2, 1, Ground z7 558.79 .10 40

2. ^ 1. Ground 27 600.80 .10 40 C 'Habn °H3 1, <^ U, tjround AA Q3 13 /oy.y4 314

1, *~ 0. Ground AA 0Z 13 / /8.ZZ 314

1, ^ 0. Ground E 1 13 796.43 314

1. 0. Ground A 1 13 799.38 314

1, « U, Ground A

u lo BZU.O/ 31/1

2, ^ 1, Ground 27 641.99 .10 40

C>2H3Sn"^H3 343 1, *~ 0, Ground A z

1 0 n^i oi 13 /6/.81 01/1 314

1. ^ 0, Ground E 1 13 786.22 314 Ground A 1 1 Q 7QQ 1 1

1, ^ 0, Ground 0 13 810.73 314

2, ^ 1. Ground 27 621.20 .10 40

C'^HsSn^sHj 344 1, *- 0, Ground A 2 13 747.81 314

1, *- 0, Ground E 1 13 765.89 314

1, ^ 0, Ground A 1 13 768.87 314

1, «- 0, Ground 0 13 790.49 314

2, 1, Ground 27 580.52 .10 40

C'2H3Sn'2»H3 345 1, 0, Ground A 3 13 729.81 314

1, ^ 0, Ground E 3 13 735.34 314

1, ^ 0, Ground A 2 13 737.98 314

1, *- 0, Ground E 1 13 756.27 314

1, ^ 0, Ground A 1 13 759.20 314

1, ^ 0. Ground 0 13 780.72 314

2, *- 1. Ground 27 517.58 .10 40

2, ^ 1. • Ground 27 560.69 .10 40

C'2H3Sn>-2H3 346 1, ^ 0, Ground E 1 13 736.90 314

1, ^ 0, Ground A 1 13 740.01 314

1, ^ 0. Ground 0 13 761.24 314

C'^HgSn'^^Hg 347 1, ^ 0, Ground A 1 13 721.1 314

1, ^ 0, Ground 0 13 742.56 314

100
350 - Acetyl Bromide Molecular Constant Tahle

EthanoyI Bromide

CjHjBrO C,(C,„C,) CH3C0Br

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) D,, D,,K K A

C'2H3C'20"'Br^'' C'^H3C>20"'Br«'

Cs

Cs

351 352

10 126.35 M

10 126.11 M

3 027.02 M

3 001.64 M

2 362.52 M

2 347.12 M

Id. No. /Xa Debye /X|, Debye /Lie Debye eQq V3 Acc. I red CUa d OJl, d to,, d £0,1 d

351

352

2.43 T 0. X -770 1306

1304

References: ABC: 289 Dj: D.,k: k:

/x: 395 eQq: 289 V: 289 I:

For species 351 , the quadrupole coupling constants are Xaa = 460 ± 3 MHz, Xbb = — 277 ± 1 MHz, Xcc = — 183 ± 3 MHz, eQq = — 770 MHz,

and the couphng parameter is la = 3. 14 amu A^. For species 352, the quadrupole coupling constants arexaa = 385±3 MHz, Xbb — ~232

± 1 MHz, Xcc = - 153 ±3 MHz, and the couphng parameter is la = 3. 14 amu A^. Ref: 289.

749-587 0-69—

8

101
Acetyl Bromide

Spectral Line Table

Isotopic Species T 1 id. Rotational Vib. btate Int. Kotor Hyperfine Frequency Acc. Ref.

INo. Quantum Nos. state n F' F MHz ±MHz

C'^HaC'^O'^Br" 351 1, 1, 1<- 0, 0, 0 Ground 3/2 3/2 12 433.58 .15 289

1, 1, 1<- 0, 0, 0 Ground 5/2 3/2 12 502.61 .15 289

1, 1, 1-^ 0, 0, 0 Ground 1/2 3/2 12 558.12 .15 289

2, 1. 2^ 1, 0, 1 Ground 5/2 3/2 17 154.98 .15 289

2, 1, 1, 0, 1 Ground 7/2 5/2 17 223.65 .15 289

3, 1, 3<- 2, 0, 2 Ground 7/2 5/2 21 592.05 .15 289

3, 1, 3<— 2, 0, 2 Ground 9/2 7/2 21 631.72 .15 289

3, 1, 3^ 2, 0, 2 Ground 5/2 3/2 21 638.05 .15 289

3, 1, 3^ 2, 0, 2 (jround 3/2 1/2 21 677.89 .15 289

4, 1, 4<— 3, 0, 3 Ground 9/2 7/2 25 756.54 .15 289

4, 1, 3, 0, 3 Ground 7/2 5/2 25 778.50 .15 289

4, 1, 4«— 3, 0, 3 Ground 11/2 9/2 25 783.12 .15 289

4, 1, 4^ 3, 0, 3 Ground 5/z 3/2 ZD 805.56 .15 289

4, 1, 3^ 3, 1, Z Ground 17 Ci t, U 11/2 9/2 oo noi^ 7A

zz /86. /9 .15 289

4, 1, 3*— 3, 1, Z Ground AA nU 11/2 9/2 oo 707 /f 7 ZZ /0/.4/ .15 289

4, 1, 3<— 3, 1, 2 Ground 5/Z 3/2 22 794.65 289

4, 1, 3<— 3, 1, 2 Ground E 0 9/2 7/2 22 797.44 .15 289

4, 1, 3^ 3, 1. Z Ground AA AU 9/2 7/2 oo 7^7 A£ ZZ /S'/.96 .15 289

4, 1, 3^ 3, 1, Z Ground 17 A 7/2 5/2 -oo OAO OA ZZ 803.90 .15 289

4, 1, 3<— 3, 1, 2 Ground A A A U 7/2 5/2 oo OAC 1 C ZZ 805.15 .15 289

4, 1, 4<— 3, 1, 3 Ground 11/2 9/2 20 139.43 .15 289

4, 1, 4<— 3, 1, 3 Ground 5/2 3/2 20 143.77 .15 289

4, 1. 4^ 3. 1, 3 Ground 9/2 7/2 OA 1 CA /in ZU 150.49 1 r .15 289

4, 1, 4^ 3, 1, 3 Ground 7/2 5/2 OA 1 C A AO zU 154.92 .15 289

5, 0, 5«— 4, 0, 4 Ground 11/2 9/2 o^; 1 AO OA 26 108.30 .15 289

5. 0, 5<— 4, 0, 4 Ground 13/2 11/2 26 111.40 .15 289

5, 0, 5<— 4, 0, 4 Ground 9/2 7/2 26 116.67 .15 289

5, 0, 5-^ 4, 0, 4 Ground 7/2 5/2 O/I 1 1 A O Z6 119.37 .15 289

5, 0, 5^ 4, 1, 4 Ground 13/2 11/2 zl 450.87 .15 289

5, 0, 5<— 4, 1, 4 Ground 7/2 5/2 on /I C A 0'7 zl 450.87 .15 289

5, 0, 5<— 4, 1, 4 Ground 11/2 9/2 21 471.39 .15 289

5, 0, 5<— 4, 1, 4 Ground 9/2 7/2 21 471.39 .15 289

5, 1, 5^ 4, 1, 4 Ground 13/2 11/2 OC 1 A^ C 0 Zd lUo.oo .to OOA ZoV

5, 1, 5^ 4, 1, 4 Ground 7/2 5/2 OC 1 1 A OA z5 110.84 .15 OOA z8y

5, 1, 5*- 4. 1, 4 Ground 11/2 9/2 25 111.43 .15 289

5, 1, 5^ 4, 1, 4 Ground 9/2 7/2 25 115.74 .15 289

7, 1, 6^ 7, 0, 7 Ground E 0 11/2 11/2 20 171.49 .15 289

7, 1, 7, 0, 7 Ground A 0 11/2 11/2 OA 1 HA £^1 l\j 1 /4.0/ .15 oon z8y

7, 1, 6^ 7, 0, 7 Ground E 0 17/2 17/2 OA 1 '7 /I an 20 174.67 .15 OOA z89

7, 1, 6<— 7, 0, 7 Ground A A A 0 17/2 17/2 OA 1 77 zO 1 / /.o3

1 r .15 OQO Zov

7, 1, 7, 0, 7 Ground E 0 13/2 13/2 20 186.19 .15 289

7, 1, 6'^ 7, 0, 7 Ground A 0 13/2 13/2 20 189.13 .15 289

7 1, 0* 7I . 7 Ground E 0 15/2 15/2 OA 1 OA 1 O 20 189.13 .15 289

7, 1, 6^ 7, 0, 7 Ground A 0 15/2 15/2 20 192.05 .15 289

8, 1, 7^ 8, 0, 8 Ground E 0 13/2 1io/Z %n 24 442.49 .15 289

8, 1, 7^ 8, 0, 3 1V_7l _T"ni U Uliil 1 n A 0 13/2 13/2 94 44S 67 289

8, 1, 7^ 8, 0, 8 Ground E 0 19/2 19/2 24 445.67 289

8, 1, 7^ 8, 0, 8 Ground A 0 19/2 19/2 24 449.17 .15 289

8, 1, 8. 0, 8 Ground E 0 115/2 15/2 24 458.58 .15 289

8, 1, 7^ 8, 0, 8 Ground E 0 117/2 17/2 24 461.41 .15 289

102
Acetyl Bromide Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

C'^HjC'^O'^Br's 351 8, 1, 7-^ 8, 0, 8 Ground A 0 15/2 15/2 24 462.07 .15 289

O 1 1 J— O A O

8, 1, 7<— 8, 0, o Lrround A A A 0 17/2 17/2 O/l AHA i\C\ z4 464.90 .15 289

8, 3, 5<- 8, 2, 6 Ground 17/2 17/2 32 602.01 .15 289

8, 3, 5<- 8, 2, 6 Ground 15/2 15/2 32 607.52 .15 289

8, 3, 5<^ 8, 2, 6 Ground 19/2 19/2 32 633.34 .15 289

8, 3, 5-^ 8, 2, 6 Ground 13/2 13/2 32 638.93 .15 289

c\ o n 1 o

y, z, /«— y, 1, o Ground I? A OA A O 1 A

1

zu ozi.yi 289

9, 2, 7-^ 9, 1, 8 Ground A 0 20 623.67 289

9, 3, 6^ 9, 2, 7 Ground 19/2 19/2 31 115.92 .15 289

9, 3, 6-^ 9, 2, 7 Ground 17/2 17/2 31 119.74 .15 289

9, 3, 6^ 9, 2, 7 Ground 21/2 21/2 31 141.07 .15 289

9, 3, 6«— 9, z, 7 Ground 15/2 15/2 31 145.05 .15 289

10, 2, 8^10, 1, 9 Ground E 0 17/2 17/2 22 722.86 .15 289

10, 2, 8-^10, 1, 9 Ground E 0 23/2 23/2 22 723.66 .15 289

10, 2, 8<-10, 1, 9 Ground A 0 17/2 17/2 22 725.54 .15 289

10, 2, 8^10, 1, 9 Ground A 0 23/2 23/2 22 726.34 .15 289

1 rv o O.C lA 1 n

lU, Z, o<—lu, 1, y Ground Yu U 19/2 19/2 OO TO"? OO ZZ ill .oZ .lo OOA Zoy

10, 2, 8*-10, 1, 9 Ground E 0 21/2 21/2 22 727.85 .15 289

10, 2, 8^10, 1, 9 Ground A 0 19/2 19/2 22 729.99 .15 289

10, 2, 8^10, 1, 9 Ground A 0 21/2 21/2 22 730.54 .15 289

11, 2, 9-^11, 1,10 Ground E 0 19/2 19/2 25 637.62 .15 289

11, z, y*—11, i,iu Ground IT A 25/2 25/2 ZD OOO.OO 1 r .15 OOA zsy

11, 2, 9-^11, 1,10 Ground A 0 19/2 19/2 25 641.10 .15 289

11, 2, 9^11, 1,10 Ground A 0 25/2 25/2 25 642.22 .15 289

11, 2, 9-^11, 1,10 Ground E 0 21/2 21/2 25 645.62 .15 289

11, 2, 9-^11, 1,10 Ground E 0 23/2 23/2 25 646.50 .15 289

11, z, y<—11, i,iu Ground AA AU 21/2 21/2 OC ^/f A OA zo o4y. zu .15 OOA zoy

11, 2, 9-^11, 1,10 Ground A 0 23/2 23/2 25 650.34 .15 289

11, 3, 8*-ll, 2, 9 Ground 23/2 23/2 28 710.85 .15 289

11. 3. 8<-ll. 2, 9 Ground 21/2 21/2 28 712.58 .15 289

11, 3, 8^11, 2, 9 Ground 25/2 25/2 28 725.02 .15 289

1111, o,

o o*— o,^ 111,ionz, y Ground 19/2 19/2 OO "70/^ AO Zo /zo.yz 1 r .15 OCA Zoy

12, 3, 9^12, 2,10 Ground 25/2 25/2 28 198.0 289

iz, o, y*—Iz, Z,1U Ground 23/2 23/2 OQ 1 QQ A Zo lyo.u OQO Zoy

12, 3, 9-^12, 2,10 Ground 27/2 27/2 28 208.0 289

12, 3, 9'^12, 2,10 Ground 21/2 21/2 28 208.0 289

C'^H3C'20"^Br8' 352 1, 1, 1^ 0, 0, 0 Ground 3/2 3/2 12 426.91 .15 289 111 i. 1, 1*^^ AAA U, U, U Ground 5/2 3/2 IZ 4o4. lo 1 r .15 9QQ

1, 1, 1*- 0, 0, 0 Ground 1/2 3/2 12 531.19 .15 289

2, 1, 2-^ 1. 0, 1 Ground 3/2 3/2 17 090.78 .15 289

2, 1, 2^ 1, 0, 1 Ground 5/2 3/2 17 117.81 .3 289

2, 1, 1*- 1, 0, 1 Ground 7/2 5/2 17 175.72 .15 289

o, 1, o<— Z, U. Z Ground 7/2 5/2 Ol CO/1 AO .io OQQ Zoy

3, 1, 3<- 2, 0, 2 Ground 9/2 7/2 21 557.11 .15 289

3, 1, 3<- 2, 0, 2 Ground 5/2 3/2 21 562.60 .15 289

3, 1, 3*- 2. 0, 2 Ground 3/2 1/2 21 595.04 .15 289

4, 0, 4-^ 3, 0, 3 Ground 9/2 7/2 20 971.00 .15 289

4, 0, 4^ 3, 0, 3 Ground 11/2 9/2 20 973.66 .15 289

4, 0, 4-^ 3, 0, 3 Ground 7/2 5/2 20 982.43 .15 289

103
Acetyl Bromide Spectral Line Table

Isotopic Species Id. Rotationa Vib. State Int. Rotor Hyperfine Frequency Ace. Ref. No. Quantum Nos. State n F' F' F F MHz ±MHz

C'2H3C'20"'Br»' 352 4 0 4<— 3, 0, 3 Ground 5/2 3/2 20 984.47 .15 289 4 I 4-^ 9 Q 3 Ground 7/9 25 662.47 .15 289

4! I, 4-^ 3, 0^ 3 Ground 7/2 5/2 25 680.83 .15 289

4, 1, 4*- 3, 0, 3 Ground 11/2 9/9 25 684.46 .15 289

4 I 4<— 3 Q 3 Ground 5/2 3/2 25 703.40 .15 289

4 I 3 I 2 Ground A 0 11/2 9/9 22 606.54 .15 289

1L 4

•30, I 2 Ground 5/2 3/2 22 614.59 .15 289

4. 1, 3^ 3, l] 2 Ground A 0 Q/2 7/2 22 616.98 .15 289

4, 1. 3^ 3, 1, 2 Ground A 0 7/9 5/2 22 623.21 .15 289

4 I 4*— 3 I 3 Ground 11/2 9/2 19 999.26 .15 289

4 I 4*— 3 3 Ground 5/2 3/2 20 003.13 .15 289

4, 4*— 3, 3 Ground 9/2 7/2 20 007.96 .15 289

4!

1' 4^ 3'

1, 3 Ground 7/2 5/2 20 012.11 .15 289

5. 0. 5^ 4, 0, 4 Ground 11/2 9/2 25 930.24 .15 289

5, 0, 5.^ 4, 0, 4 Ground 13/2 11/2 25 932.46 .15 289

5, 0, 5.^ 4, 0, 4 Ground 9/2 7/2 25 936.96 .15 289

5, 0, 5<— 4, 0, 4 Ground 7/2 5/2 25 938.87 .15 289

5^ ol 5^ 4! 1, 4 Ground 13/2 11/2 21 220.85 .15 289

5, 0, 5^ 4, 1, 4 Ground 7/2 5/2 21 220.85 .15 289

4 \ 4 Ground 11/2 9/2 21 238.52 .15 289

c;< d T1

,

4 Ground 9/2 7/9 21 238.52 .15 289

c

0, 1i

,

^1 4 Ground 11/2 9/9 29 628.40 .15 289

5, 1, 5^ 4, 0, 4 Ground 9/9 7/9 29 638.95 .15 289

5. 1, 5^ 4, 0, 4 Ground 1 ^/9 11/2 29 644.39 .15 289

C 11

,

A'4', 4 Ground 7/2 5/2 29 655.20 .15 289

C 11

,

0* 4 Ground 1 ^/9 11/2 24 932.92 .15 289

C 1i

,

d 1 4 Ground 5/2 24 936.55 .15 289

5, 1, 5<- 4, 1, 4 Ground 11/2 9/9 24 937.28 .15 289

5, 1, 5*- 4, 1, 4 Ground 9/9 7/9 24 940.70 .15 289

f.On n0, 0^ c 11

,

5 Ground 15/2 13/2 27 041.92 289

u, \ 5 Ground 9/9 7/9 27 041.92 289

5 0 6<— 5, \ 5 Ground 13/2 11/2 27 053.88 289

6^ 0! 6^ 5^ I, 5 Ground 11/2 9/2 27 053.88 289

7, 1, 6^ 7, 0, 7 Ground E 0 11/2 11/2 19 966.22 .15 289

7 I 6<— 7 0, 7 Ground A 0 11/2 11/2 19 969.09 .15 289

7_ I 6'^ 7 Q 7 Ground E 0 17/2 17/2 19 969.09 .15 289

7^ 6<— 7 0, 7 Ground A 0 17/2 17/2 19 971.96 .15 289

7"

1. 6*- 7! 0, 7 Ground E 0 13/2 13/2 19 978.80 .15 289

7, 1, 6<- 7, 0, 7 Ground A 0 13/2 13/2 19 981.44 .15 289

7 J 6<— 7 0 7 Ground E 0 15/2 15/2 19 981.44 .15 289

7*

,

1 0* 7 nu. 7 Ground A 0 15/2 15/2 19 984.18 .15 289

Q

0, 1 Q0, nu. 8 Ground E 0 13/2 13/2 24 170.70 .15 289

8, 1, 7^ 8, 0, 8 Ground E 0 19/2 19/2 24 173.27 .15 289

8, 1, 7*- 8. 0, 8 Ground A 0 13/2 13/2 24 174.40 .15 289

8, 1, 7^ 8, 0. 8 Ground A 0 19/2 19/2 24 176.97 .15 289

8, 1, 7^ 8, 0, 8 Ground E 0 15/2 15/2 24 184.13 .15 289

8, 1, 7^ 8, 0, 8 Ground E 0 17/2 17/2 24 186.53 .15 289

8, 1, 7^ 8, 0, 8 Ground A 0 15/2 15/2 24 187.65 .15 289

8, 1, 7^ 8, 0, 8 Ground A 0 17/2 17/2 24 190.15 .15 289

8. 3. 5^ 8, 2, 6 Ground 17/2 17/2 32 804.90 .15 289

104
Acetyl Bromide Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Qu,antum Nos. State n * I F' R F MHz ±MHz

C'^HsC'^O'^BrS' 352 8, 3, 5^ 8, 2, 6 Ground 15/2 15/2 32 809.49 .15 289

8, 3, 5<— 8, 2, 6 Ground 19/2 19/2 32 830.87 .15 289

8, 3, 5^ 8, 2, 6 Ground 13/2 13/2 32 835.67 .15 289

9, 2, 7<- 9, 1, 8 Ground E 0 20 541.46 289

9, 2, 7<- 9, 1, 8 Ground A 0 20 543.00 289

9, 3, 6-^ 9, 2, 7 Ground 19/2 19/2 31 326.92 .15 289

9, 3, 6<- 9, 2, 7 Ground 17/2 17/2 31 ,3.30.21 .15 289

9, 3, 9, 2, 7 Ground 21/2 21/2 31 348.15 .15 289

9, 3, 6«- 9, 2, 7 Ground 15/2 15/2 31 351. .55 .15 289

10, 2, 8«-10, 1, 9 Ground E 0 17/2 17/2 22 561.01 .15 289

10, 2, 8^10, 1, 9 Ground E 0 23/2 23/2 22 561.63 .15 289

10, 2, 8-^10, 1, 9 Ground A 0 17/2 17/2 22 563.55 .15 289

10, 2, 8^10, 1, 9 Ground A 0 23/2 23/2 22 564.33 289

10, 2, 8-^10, 1, 9 Ground E 0 19/2 19/2 22 564.33 289

10, 2, 8-^10, 1, 9 Ground E 0 21/2 21/2 22 564.77 .15 289

10, 2, 8^10, 1, 9 Ground A 0 19/2 19/2 22 566.91 .15 289

10, 2, 8<—10, 1, 9 Ground A 0 21/2 21/2 22 .567.38 .15 289

11, 2, 9*-ll, 1,10 Ground E 0 19/2 19/2 25 379.89 .15 289

11, 2, 9<-ll, 1,10 Ground E 0 25/2 25/2 25 380.83 .15 289

11, 2, 9^11, 1,10 Ground A 0 19/2 19/2 25 383.41 .15 289

11, 2, 9^11, 1,10 Ground A 0 25/2 25/2 25 384.32 .15 289

11, 2, 9<—11, 1,10 Ground E 0 21/2 21/2 25 386.35 .15 289

11, 2, 9<-ll, 1,10 Ground E 0 23/2 23/2 25 387.14 .15 289

11, 2, 9-^11, 1,10 Ground A 0 21/2 21/2 25 389.77 .15 289

11, 2, g'^ll, 1,10 Ground A 0 23/2 23/2 25 390.60 .15 289

11, 3, 8^11, 2, 9 Ground 23/2 23/2 28 876.40 .4 289

11, 3, 8«-ll, 2, 9 Ground 21/2 21/2 28 877.80 .4 289

11, 3, 8*-!!, 2, 9 Ground 25/2 25/2 28 889.0 .4 289

11, 3, 8^11, 2, 9 Ground 19/2 19/2 28 890.4 .4 289

12, 3, 9^12, 2,10 Ground 25/2 25/2 28 305.51 289

12, 3, 9^12, 2,10 Ground 23/2 23/2 28 305.51 289

12, 3, 9-^12, 2,10 Ground 21/2 21/2 28 313.04 289

12, 3, 9^12, 2,10 Ground 27/2 27/2 28 313.04 289

105
360 -Acetyl Chloride Molecular Constant Table

Ethanoyl Chloride C2H3CIO Cs(C3v,Cj CH3COCI

Isotopic Species Pt. Id.

INO. A (MHz) B(MHz) C (MHz) K A

10 162.39 M 4 946.66 M 3 393.07 M

c 10 160.60 M 4 808.74 M 3 327.40 M

c 8 758.77 M 4 532.73 M 3 098.77 M

n 8 753.45 M 4 408.08 M 3 039.17 M

c oOO 9 973.64 M 4 691.78 M 3 252.28 M

„ pl2ljf nri2n'6pi35 c 9 444.93 M 4 867.07 M 3 303.13 M

PISH pl2r\16pl35

y^ rl3<^ yj <_1 c 9 894.47 M 4 868.35 M 3 326.21 M

C^HjC'^O'^CP^ Cs 368 9 889.14 M 4 731.58 M 3 261.38 M

C'^HaC^O'^CP^ Cs 369 10 159.49 M 4 932.06 M 3 385.97 M

C'^HgC'^QX'CP^ Cs 371 C'2H3C'20"*CP^ Cs 372 9 623.48 M 4 841.02 M 3 282.56 M

Id. No. ju,a Debye /Xt, Debye |Ji^ Debye eQq V3 Acc. Ired OJa d coh d <J)^. d (0,1 d

361 2.72 T 0. X 1296 30

362 1296 30

367 1287

368 1301

369 1283

371 1296

372 1315

References: ABC: 337,384 Dj: Djk: k: A:

H: 393 eQq: V: 337 I: w: Add. Ref.: 153

Id. No. Quadrupole Coupling Constants Coupling Parameter

Xaa(MHz) Xbb(MHz) Xcc(MHz) L (amu A^).

361 -58.0 36.4 21.6 3.1158 362 -45.5 28.5 17.0 3.1158 363 -53.2 31.7 21.5 3.1158 364 -42.9 25.4 17.5 3.1158 367-372 3.1158

Ref: 337.

106
Acetyl Chloride

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rot

State

orn f; Hype

F'

'rfine FFrequency

MHz

Acc. ±MHz

1 Ref.

C'^'HaC'^O'^CP 361 2, 1, 2<- 1, 0, 1 Ground AE 0 3/2 1/2 20 327.30 .2 337

2, 1, 2«- 1, 0, 1 1 -rr* 1 1 r) H AE 0 1 19 2 00 / 2, 1, 2<- 1, 0, 1 Ground AE 0 5/2 5/2 20 334.80 .2 337

9 11

,

11

,

11 Ground AE 0 7/2 5/2 20 340.25 .2 337

2, 1, 2-^ 1, 0, 1 Ground AE 0 5/2 3/2 20 349.25 .2 337

2, 1, 2-^ 1, 0, 1 Ground AE 0 3/2 3/2 20 353.25 .2 337

2, 2, 1-^ 2, 1, 2 Ground 20 298.0 2 384

2, 2, 1*- 2, 1, 2 Ground 20 305.0 .2 384

a 11

,

9 Ground AE 0 7/2 5/2 19 926.80 .2 337

3, 0, 3^ 2, 1, 2 Ground AE 0 5/2 3/2 19 928.25 .2 337

3, 0, 3^ 2, 1, 2 Ground AE 0 5/2 5/2 19 932.10 .2 337

3, 0, 3<- 2, 1, 2 Ground AE 0 9/2 7/2 19 934.00 .2 337

3, 0, 3-^ 2, 1, 2 Ground AE 0 3/2 1/2 19 936.00 .2 337

3 0 3«— 2 I 2 Ground AE 0 3/2 3/2 19 941.80 .2 337

3!

1' 3^ 2] 0, 2 Ground AE 0 7/2 7/2 26 467.75 .2 337

3, 1, 3<- 2, 0, 2 Ground AE 0 3/2 1/2 26 471.05 .2 337

3, 1, 3^ 2. 0, 2 Ground AE 0 5/2 3/2 26 476.55 .2 337

3, 1, 3^ 2, 0, 2 Ground AE 0 9/2 7/2 26 476.55 .2 337

3

0, I 2 Q 2 Ground AE 0 7/2 5/2 26 481.53 .2 337

3, 3-^ 2] 0! 2 Ground AE 0 5/2 5/2 26 485.20 .2 337

3, 1, 3-^ 2, 0, 2 Ground AE 0 3/2 3/2 26 485.20 .2 337

3, 2, 2-<- 3, 1, 3 Gro u nd 22 800.0 .2 384

3, 2, 2«- 3, 1, 3 Ground 22 804.3 .2 384

4 0 4<— 3 I 3 Ground E 0 7/2 5/2 28 278.10 .2 337

4!

0' 4^ 3'

1! 3 Ground E 0 9/2 7/2 28 278.10 .2 337

4, 0, 4^ 3, 1, 3 Ground A 0 9/2 7/2 28 278.78 .2 337

4, 0, 4<- 3, 1, 3 Ground A 0 7/2 5/2 28 278 78 .2 337

4, 0, 4-^ 3, 1, 3 Ground E 0 11/2 9/2 28 281.08 .2 337 4 0 4<— 3 I 3 Ground E 0 5/2 3/2 28 281.08 .2 337

4! 0! 4-^ 3! I, 3 Ground A 0 5/2 3/2 28 281.76 .2 337

4, 0, 4^ 3, 1, 3 Ground A 0 11/2 9/2 28 281.76 .2 337

4, 1, 3^ 4. 0, 4 Ground 16 743.0 .2 384

4, 1, 3^ 4, 0, 4 Ground 16 753.0 .2 384

4 \ 4 n 4 Ground 16 755.0 .2 384

4! 2, 2*- 4^ 1, 3 Ground 14 810.8 .2 384

4, 2, 2<- 4, 1. 3 Ground 14 814.2 .2 384

4, 2, 2^ 4, 1, 3 ( -.mil n

H

14 817.2 2 384

4, 2, 3^ 4, 1, 4 Ground E 0 5 5 26 181.00 .2 337

A A 1 A4' Ground E 0 11 11 26 182.60 .2 337

4, 2, 3^ 4. 1, 4 Ground A 0 5 5 26 182.60 .2 337

4, 2, 3^ 4, 1, 4 Ground A 0 11 11 26 183.95 .2 337

4, 2, 3^ 4, 1, 4 \Jl OUllU 0 7 7 2 337

4, 2, 3-^ 4, 1, 4 Ground E 0 9 9 26 186.80 .2 337

4, 2, 3«- 4, 1, 4 Ground A 0 7 7 26 186.80 .2 337

4, 2, 3^ 4, 1, 4 Ground A 0 9 9 26 188.30 .2 337

5, 1, 4-^ 5, 0, 5 Ground E 0 9/2 9/2 23 090.50 .2 337

5, 1, 4<- 5, 0, 5 Ground E 0 11/2 11/2 23 090.50 .2 337

5, 1, 4-^ 5, 0, 5 Ground E 0 13/2 13/2 23 092.30 .2 337

5, 1, 4'<- 5, 0, 5 Ground E 0 7/2 7/2 23 092.30 .2 337

5, 1, 4«- 5, 0, 5 Ground A 0 9/2 9/2 23 095.25 .2 337

107
Acetyl Chloride

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frc cj ucnc y Acc. Ref. No. Quantum Nos State F' F' E MHz ±MHz

C'2H3C'-0"^CP^ 361 5, 1, 4«— 5, 0, 5 Ground A 0 11/2 11/2 23 095.25 .2 337

5^ l' 4*- 5^

0' 5 Ground A 0 7/2 7/2 23 097.14 .2 337

5, 1, 4^ 5] 0^ 5 Ground A 0 13/2 13/2 23 097.14 .2 337

5, 2, 3^ 5, 1, 4 Ground 16 083.2 .2 384

5, 2, 3-^ 5, 1. 4 Ground 16 085.0 .2 384

5, 2, 3^^ 5, 1, 4 Ground 16 086.8 .2 384

5, 3, 2<- 5, 2, 3 Ground AE 0 7/2 7/2 25 150.65 .2 337

5, 3! 2^ 5, 2, 3 Ground AE 0 13/2 13/2 25 153.00 .2 337

5, 3, 2-^ 5, 2, 3 Ground AE 0 9/2 9/2 25 159.20 .2 337

5, 3. 2<- 5, 2, 3 Ground AE 0 11/2 11/2 25 161.60 .2 337

6, 2, 4^^ 6, 1, 5 Ground E 0 1.5/2 15/2 19 125.31 .2 337

6, 2, 4^^ 6, 1, 5 Ground E 0 9/2 9/2 19 125.31 .2 337

6, 2, 4*- 6, 1, 5 Ground E 0 13/2 13/2 19 125.31 .2 337

6, 2, 4<- 6, 1, 5 Ground E 0 11/2 11/2 19 125.31 .2 337

6, 2, 4*- 6, 1, 5 Ground A 0 15/2 15/2 19 128.55 .2 337

6, 2, 4^^ 6, 1, 5 Ground A 0 13/2 13/2 19 128.55 .2 337

6^ 2] 4^^ 6^ 1^ 5 Ground A 0 11/2 11/2 19 128.55 .2 337

6, 2, 4^ 6'1, 5 Ground A 0 9/2 9/2 19 128.55 .2 337

6, 3, 3^ 6, 2. 4 Ground AE 0 9/2 9/2 23 260.30 .2 337

6, 3, 3^^ 6. 2, 4 Ground AE 0 15/2 15/2 23 261.50 .2 337

6, 3, 3<— 6, 2. 4 Ground AE 0 11/2 11/2 23 265.75 .2 337

6, 3, 3<— 6^ 2, 4 Ground AE 0 13/2 13/2 23 267.00 .2 337

ll 2, 5^ 7, 1! 6 Ground E 0 15/2 15/2 24 086.30 .2 337

7, 2. 5^ 7, 1, 6 Ground 0 13/2 13/2 24 086.30 .2 337

7, 2, 5<- 7, 1, 6 Ground E 0 11 11 24 087.55 .2 337

7, 2, S'^ 7, 1. 6 Ground E 0 17/2 17/2 24 087.55 .2 337

7. 2, 5<— 7^ 1. 6 Ground A 0 15 15 24 091.40 .2 337

7^ 2! 5*- 7! I. 6 Ground A 0 13 13 24 091.40 .2 337

7, 2, 5^ 7, 1, 6 Ground A 0 11 11 24 092.65 .2 337

7, 2, 5^ 7, 1, 6 Ground A 0 17 17 24 092.65 .2 337

7, 3, 4^ 7, 2, 5 Ground E 0 11 11 22 344.40 .2 337

7^ 3' 4<- 7' 2' 5 Ground E 0 17 17 22 345.20 .2 337

l] 3] 4^ 7^ 2! 5 Ground A 0 11 11 22 345.20 .2 337

7, 3, 4^ 7, 2, 5 Ground A 0 17 17 22 346.02 .2 337

7, 3, 4<— 7, 2, 5 Ground E 0 13 13 22 347.65 .2 337

7^ 3, 4<— 7, 2, 5 Ground E 0 15 15 22 348.40 .2 337

7^ 3, 4<— 7, 2, 5 Ground A 0 13 13 22 348.40 .2 337

7, 3! 4-^ 7! 2! 5 Ground A 0 15 15 22 349.23 .2 337

8, 3, 5^ 8, 2, 6 Ground E 0 13 13 23 073.27 .2 337

8. 3 S'^ 8, 2, 6 Ground E 0 19 19 23 073.27 .2 337

8, 3. 5-^ 8, 2, 6 Ground E 0 15 15 23 074.50 .2 337

8, 3. 5^ 8, 2. 6 Ground E 0 17 17 23 074.50 .2 337

8, 3] 5-^ 8^ 2] 6 Ground A 0 13 13 23 075.56 .2 337

8, 3. 5^ 8, 2, 6 Ground A Q 19 19 23 075.56 .2 337

8. 3, 5^ 8. 2, 6 Ground A 0 15/2 15/2 23 076.80 .2 337

8, 3, 5^ 8, 2, 6 Ground A 0 17/2 17/2 23 076.80 .2 337

9, 3, 6^ 9, 2, 7 Ground E 0 19/2 19/2 25 860.85 .2 337

9, 3, 6^ 9, 2, 7 Ground E 0 17/2 |17/2 25 860.85 .2 337

9, 3, 6-<- 9, 2. 7 Ground E 0 21/2 121/2 25 860.85 .2 337

9, 3. 6^ 9, 2. 7 Ground E 0 15/2 115/21 25 860.85 2 1 337

108
Acetyl Chloride Spectral Line I'ahlc

Isotopic Species la. Rotational V ijj. Oldie Int. Rotor Hyperfine Fretjuency ACC. ixei. iNO. Quantum Nos. state n

17' 17' r F ivinz ivi nz

C'^HjC 361 9, 3, 6«— 9, 2, 7 Ground A 0 19/2 19/2 25 865.30 .2 337

9, 3, 6^ 9, 2, 7 Ground A 0 17/2 17/2 25 865.,30 .2 337

9, 3, 6*- 9, 2, 7 round A 0 21/2 21/2 Z.J 0O.J.OU .z 66 ( 9, 3, 6<- 9, 2, 7 Ground A 0 15/2 15/2 ZD OO.J.oU 9• Z 00 ( 10, 3, T'^IO, 2, Q0 Ground E 0 21/2 21/2 OU OOD.OO 9.Z 0.5 /

10, 3, 7<—10, 2, 8 Ground E 0 19/2 19/2 30 836.85 .2 337

10, 3, T'^IO, 2, 8 Ground E 0 23/2 23/2 30 837.95 .2 337

10, 3, 7^10, 2, 00 Ground E 0 17/2 17/2 ou 00 i .vo 9.z 10, 3, 7^10, 2, Q0 Ground A 0 21/2 21/2 9.Z qQ7

10, 3, 7*—10, 2. Q0 Ground A 0 19/2 19/2 .z9 ^^7

10, 3, 7'^10, 2, 8 Ground A 0 23/2 23/2 30 844.77 .2 337

10, 3, 7*—10, 2, 8 Ground A 0 17/2 17/2 30 844.77 .2 337

11, 4, 7^11, 3, 00 Ground h 0 19/2 19/2 zy90 ftl 01 7i .O.J 9.Z ^^7

11. 4, 7^11, 3, 00 Ground E 0 25/2 25/2 ZV90 HI0 1 7( .GO 9• Z ^^7

11, 4, 7<—11, 3, 00 Ground E 0 21/2 21/2 90 Ri 0 no .z9 Oo (

11, 4, 7'^11, 3, 8 Ground E 0 23/2 23/2 29 819.00 .2 337

11, 4, 7<—11, 3, 8 Ground *A 0 19/2 19/2 29 820.30 .2 337

11, 4, 7^11, 3, 0 Ground AA 0 zo/z 25/2 90 R9n 0.z 00^^7/ 11, 4, 7^11, 3, Q0 Ground A 0 21/2 21/2 Z790 891 OZ1.4'U dn .Z9 00^^7/ 11, 4, 7«—11, 3, Q0 Ground A 0 23/2 23/2 90^.y R91 0^1.4-0 dn 0.z 00 /

12Q16(2p7 362 2, 1, 2^ 1, 0, 1 Ground 20 142.4 .2 384

2, 1, 2<- 1, 0, 1 Ground 20 149.3 .2 384

3, 1, 3-^ 2, 0, 9 Ground AE 0 3/2 1/2 ZD 10.3. jU 9Z qQ7

3, 1, 3^ 2, 0, 0L Ground AE 0 5/2 3/2 ZO lOV.lU 9.z 3Q7 66 i 3, 1, 3«- 2, 0, Z Ground AE 0 9/2 7/2 OA 1 AO 1 V\ ZO lOV.lU 9.z QQ7

3, 1, 3«— 2, 0, 2 Ground AE 0 7/2 5/2 26 172.95 .2 337

3, 3, 0<— 3, 2, 1 Ground 29 342.20 .1 384

3, 3, 0«- 3, 2, 11 Ground ZV o4o.'+Z 1

3, 3, 0^ 3, 2, i Ground ZV O'+u.O'J

"1 .1 60^

3, 3, 0<— 3, 2, 11 Ground 9QZ7 OOU.lO ^^n 1 ^ 1.i Outn

u,

A ^ Q

1, 3 Ground A 0 11/2 9/2 27 046.88 .2 337

A4, 0, 4<— 0, 1, 3 Ground E 0 11/2 9/2 27 046.88 .2 337

4, 0, 4^ 3, 1, 0 Ground AA 0

c In 3/2 .Z9 ^^7

4, 0, 4^ 3, 1, 0 Ground t, 0 5/z 3/2 Z97i Od^i 04-0. RS00 9 00 i

4', U,

A ^ 30,

11, •X 0 Ground E 0 9/2 7/2 C97 d09 Ofi i 4'VZ. "O 9 ^^7

4, 0, 4<— 3, 1, 3 Ground 17 0 7/2 o/z 27 492.96 .2 337

A4, 0, 4<— 3, 1, 3 Ground AA 0 9/2 7/2 27 493.69 .2 337

4, 0, 4^ 3, 1, Q0 Ground A 0 7/2 5/2 97^ t dO^ 470.07fiO .z 00^^71 4, 0, 4^ 3, 1, Q Ground E 0 11/z 9/2 z97/ dOR 470.dfl 4-0 .z9 ^^7

4, 0, 4<— 3, 1, a0 Ground E 0 5/2 3/2 97Z dO'^ dfl ' 4VD.4'U .z9 00^^7i

4, 0, 4*— 3, 1, 3 Ground A 0 11/2 9/2 27 496.12 .2 337

A4, u. 4<— /I ^ Q0, 1, 3 Ground AA 0 5/z 3/2 27 496.12 .2 337

5 3, 2*— 5, 2^ a0 Ground AE 0 7/2 7/2 oc n/:o Of) Z.J VOZ.oU Z9 ^^7 00 t 3' 2^ 5'

2! Q Ground AE 0 13/2 13/2 ZO yo^-.uo .z9 ^^7

5, 3, 2^ 5, 2, a0 Ground AE Q 0/9 9/9 y/z ZO VDV.UU .z9 ^^7

5, 3, 2^ 5, 2, 3 Ground AE 0 11/2 11/2 25 970.85 .2 337

6, 2, 4^ 6, 1, 5 Ground E 0 13/2 13/2 18 695.28 .2 337

6, 2, 4^ 6, 1, 5 Ground E 0 11/2 11/2 18 695.28 .2 337

6, 2, 4<- 6, 1, 5 Ground E 0 15/2 15/2 18 695.28 .2 337

6, 2, 4*- 6, 1, 5 Ground E 0 9/2 9/2 18 695.28 .2 337

109
Acetyl Chloride

Spectral Line Table

Isotopic Species la. Rotational viD. otaie Int. Rotor Hyperfine iTr^^..^^ r requency

AAcc. Kei.

INo. Quantum NOS State n F' F MHz ±MHz

C'2H3C'-0"^CP' 362 6, 2, 4<— 6, 1, 5 Ground A 0 13/2 13/2 18 697.87 .2 337

6, 2, 4<— 6, 1. 5 Ground A 0 11/2 11/2 18 697.87 .2 337

6, 2, 4-^ 6, 1,

Co Ground A 0 15/2 15/2 lo mi.oi .2 337

6, 2, 4*- 6, 1,

cO Ground A 0 9/2 9/2 lo oy/.o/ .2 337

6, 3, 3*— 6. 2. /I Ground AE 0 9/2 9/2 OA f\l A on .z 00 /

6, 3, 3-<— 6, 2, 4 Ground AE 0 15/2 15/2 24 015.90 .2 337

6, 3, 3^^ 6, 2, 4 Ground AE 0 11/2 11/2 24 019.20 .2 337

6. 3, 3^ 6. 2, 4- Ground AE 0 13/2 13/2 OA r\of\ of\ 0

.z 007

7, 2, 5^ 7, 1, 0 Ground E 0 1 15/2 15/2 Zo 1 / z.zz

0

.z 007 661

7, 2, 5<— 7, 1. 0 Ground E 0 13/2 13/2 zo 1 1 z.zz, 0.z 007

7, 2, 5<— 7, 1, 6 Ground L u 17/2 17/2 23 172.22 .2 337

7, 2, 5<— 7, 1. 6 Ground nu 11/2 11/2 23 172.22 .2 337

7, 2, 5^ 7, 1, o Ground AA nu 15/2 15/2 90 1 7^ r

A

0

.z 3Q7 00 / 7, 2, 5^ 7, 1, o Ground A 0 13/2 13/2 ZO 1 lO.oKJ 0

.z 357 00 i 7, 2,

r ^ -7 1. o Ground A 0 17/2 17/2 Zo i / O.OU 0

.z 337 00 i

-7/, o

Z, 1. 6 Ground A

AU 11/2 11/2 23 176.50 .2 337

7, 3, 4<— 7, 2, 5 Ground I/ AU 11/2 11/2 22 846.60 .2 337

7, 3, 4^ 7, 2, D Ground T?t. AVJ 17/2 17/2 99 QA7 97 Zz o'* / .Z 1 0

.Z 337 00 / 7, 3, 4^ 7, 2, c0 Ground AA 0 11/2 11/2 99 «A7 97 ZZ 0^ / . Z / 9.Z 337 00 /

-7/, 03,

,1 -7 2, o Ground A 0 17/2 17/2 ZZ99 ftdfl Ot'O.UU no 9.Z 337 00 /

7, 3, 4<— 7, 2, 5 Ground 1h, A

u 13/2 13/2 22 849.41 .2 337

7, 3, 4*— 7, 2, 5 Ground IE

A

U 15/2 15/2 22 850.10 .2 337

7, 3, 4*- 7, 2, c0 Ground A

A

U 13/2 13/2 99ZZ ft^n oDU.iUin 9.Z 337 00 I 7, 3, 4^ 7. 2, D Ground A 0 15/2 15/2 99 pc:n HI ZZ oDU.Oo 9-Z 337 00 / 8, 2, 6*— 8, 1, 7 Ground E 0 17/2 17/2 OA oAo on zV o<*z.ZU 9.Z 337

8, 2, 6<— 8, 1, 7 Ground E u 15/2 15/2 29 342.20 .2 337

8, 2, 6'^ 8, 1, 7 Ground A U 19/2 19/2 29 343.42 .2 337

8, 2, 6^ 8. 1, Ground A U 13/2 13/2 OA OA Q /I 0 zV o4o.4z 9.z 337 00 / 8, 2, 6^ 8, 1, 7 Ground E 0 17/2 17/2 on OAQ OA ZV o4o.oU 9.Z 337 00 / 8, 2, 6^ 8, 1, 7 Ground E 0 15/2 15/2 OA OAQ OA Zy o4o.oU 9.z 337 00 /

8, 2, 6<— 8, 1, 7 Ground A 0 19/2 19/2 29 350.15 .2 337

8, 2, 6*— 8, 1, 7 Ground A 0 13/2 13/2 29 350.15 .2 337

8, 3, 5*- 8, 2, 0 Ground E 0 13/2 13/2 00 1 OA QA ZO IZU.VU 9.Z 337 00 / 8, 3, 5^ 8, 2, 0 Ground E 0 19/2 19/2 00 1 OA AA ZO IZU.VU 9.Z 337 00 / 8, 3, 5*- 8, 2,

/;O Ground E 0 15/2 15/2 00 1 OA AA ZO izu.yu 9.z 337 00 /

8, 3, 5<— 8, 2, 6 Ground E 0 17/2 17/2 23 120.90 .2 337

8, 3, 5«— 8, 2, 6 Ground A 0 13/2 13/2 23 122.25 .2 337

8, 3, 5^ 8, 2,

/rD Ground A 0 19/2 19/2 00 1 00 OC ZO IZZ.ZC) 9.Z 337 00 / 8, 3, 5^ 8, 2, 0 Ground A 0 15/2 15/2 00 1 00 OC ZO Izz.zo 9.z 337 00 / 8, 3, S'^ 8, 2. 0 Ground A 0 17/2 17/2 93 1 99 91^ ZO IzZ.zo 9.Z 337 00 /

9, 3, 6'^ 9, 2, 7 Ground E 0 19/2 19/2 25 279.18 .2 337

9, 3, 6«— 9, 2, 7 Ground E 0 17/2 17/2 25 279.18 .2 337

Q 3

2, 7 Ground E 0 21/2 21/2 OC 070 1 Q zo z /y.io .z 3Q7

9, 3, 6^ 9, 2,

-7 Ground E 0 15/2 15/2 Zo ZiV.lo 0

.z 3Q7

9, 3, 6^ 9. 9 / Ground A 0

OC 000 00 Zo ZoZ.yZ .z QQ7 00 I

9, 3, 6^ 9, 2, 7 Ground A 0 17/2 17/2 25 282.92 .2 337

9. 3. 6^ 9. 2, 7 Ground A 0 21/2 21/2 25 282.92 .2 337

9. 3, 6^ 9, 2, 7 Ground A 0 15/2 15/2 25 282.92 .2 337

10, 3. 7^10. 2. 8 Ground E 0 21/2 21/2 29 521.30 .2 337

10. 3, 7^10, 2, 8 Ground E 0 19/2 19/2 29 521.30 .2 337

110
Acetyl Chloride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n F' F' Fj Y MHz ±MHz

C'^HjC'^O'^CF' 362 10 3 7<—10 2 8 Ground E 0 23/2 23/2 29 522.04 .2 337

10 3 7*—10 2 8 Ground E 0 17/2 17/2 29 522.04 .2 337

lo! 3! 7—loi 2, 8 Ground A 0 21/2 21/2 29 527.40 .2 337

10, 3, 7^10, 2, 8 Ground A 0 19/2 19/2 29 527.40 .2 337

10 3 •7«_jQ 2, 8 Ground A 0 23/2 23/2 29 528.13 .2 337

10, 3, 7'^10, 2, 8 Ground A 0 17/2 17/2 29 528.13 .2 337

lli 4^ 7^11! 3! 8 Ground E 0 19/2 19/2 20 067.30 .2 337

11, 4, 7*-ll, 3, 8 Ground E 0 25/2 25/2 20 067.30 .2 337

11, 4, 7<—11, 3, 8 Ground A 0 23/2 23/2 29 821.40 .2 337

11, 4, 7*-lL 3' 8 Ground A 0 21/2 21/2 29 821.40 .2 337

11, 4, 7'^11, 3, 8 Ground E 0 21/2 21/2 30 068.48 .2 ,337 ii! 4i 7^11! 3! 8 Ground E 0 23/2 23/2 30 068.48 .2 337

11, 4, 7^11, 3, 8 Ground A 0 19/2 19/2 30 069.05 .2 337

11, 4, 7'^11, 3, 8 Ground A 0 25/2 25/2 30 069.05 .2 337

363 2, 1, 2<- 1, 0, 1 Ground AE 0 1/2 1/2 18 048.30 337

2, 1, 2<— 1, 0, 1 Ground AE 0 5/2 5/2 18 049.90 337

2'

1, 2*- 1, 0, 1 Ground AE 0 7/2 5/2 18 055.36 337

2, 1, 2<^ 1, 0, 1 Ground AE 0 5/2 3/2 18 062.50 337

3, 0, 3<- 2, 1, 2 Ground 18 644.05 .1 384

3, 0, 3<- 2, 1, 2 Ground 18 648.50 .1 384

3! 0, 3<- 2, 1, 2 Ground 18 650.70 .1 384

s]

1' 3^ 2! 0! 2 Ground AE 0 3/2 1/2 23 662.10 337

3, 1, 3^ 2, 0, 2 Ground AE 0 5/2 3/2 23 666.35 337

3. 1, 3«— 2, 0, 2 Ground AE 0 9/2 7/2 23 667.22 337

3, 3-^ 2, 0. 2 Ground AE 0 7/2 5/2 23 671.50 337

3! 1^ 3*- 2^ 0, 2 Ground AE 0 3/2 3/2 23 674.50 337

4! ol 4-^ 3' 1' 3 Ground AE 0 7/2 5/2 26 125.90 337

4, 0, 4^ 3, 1, 3 Ground AE 0 9/2 7/2 26 125.90 337

4, 0, 4<— 3, 1, 3 Ground AE 0 5/2 3/2 26 128.35 337

4, 0, 4<— 3, 1, 3 Ground AE 0 11/2 9/2 26 128.35 337

4^ 1^ 4<- 3' 0] 3 Ground AE 0 5/2 3/2 29 066.43 337

4, 1, 4-^ S, 0, 3 Ground AE 0 7/2 5/2 29 068.51 337

4, 1, 4^^ 3, 0, 3 Ground AE 0 11/2 9/2 29 068.51 337

4, 1, 4,1- 3. 0, 3 Ground AE 0 9/2 7/2 29 070.50 337

4, 1, 4*- 3, 0, 3 Ground AE 0 7/2 7/2 29 074.00 337

4, 2, 3<— 4, 1, 4 Ground AE 0 11/2 11/2 22 441.05 337

4! 2, 3^ 4'1, 4 Ground AE 0 5/2 5/2 22 441.05 337

4, 2, 3^ 4, 1, 4 Ground AE 0 7/2 7/2 22 444.25 337

4 2, 3<— 4 2 4 Ground AE 0 9/2 9/2 22 444.25 337

5 3 2*— 5 2 3 Ground AE 0 7/? 7/2 20 171.82 337

5 3 2*— 5 2 3 Ground AE 0 13/2 13/2 20 173.96 337

5, 3! 2*- 5! 2! 3 Ground AE 0 9/9 9/2 20 179.30 337

5, 3, 2-^ 5, 2, 3 Ground AE 0 11/2 11/2 20 181.40 337

5, 3, 2*- 5, 2, 3 Ground 20 183.80 .1 384

5, 3, 3^ 5, 2, 4 Ground AE 0 7/2 7/2 27 010.3 337

5, 3, 3«- 5, 2, 4 Ground AE 0 13/2 13/2 27 011.9 337

5, 3, 3-^ 5, 2, 4 Ground AE 0 9/2 9/2 27 016.2 337

5, 3, 3^ 5, 2, 4 Ground AE 0 11/2 11/2 27 017.7 337

6, 3, 3^ 6, 2, 4 Ground AE 0 9/2 9/2 18 724.40 337

6, 3, 3^ 6, 2, 4 Ground AE 0 15/2 15/2 18 724.40 337

111
Acetyl Chloride

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frecjuency Acc, Ref. No. Quantum Nos State n F' F' F p MHz ±MHz

C'2D3C'20"'CP-^ 363 6, 3, 3.^ 6, 2, 4 Ground AE 0 11/2 11/2 18 725.55 337

6, 3 3«— 4 Ground AE 0 13/2 13/2 18 725.55 337

?! 2! 5^ 7, I, 6 Ground AE 0 11/2 11/2 22 027.80 337

7, 2, 5^ 7, 1, 6 Ground AE 0 17/2 17/2 22 027.80 337

7^ 2, 5«— 7, 1, 6 Ground AE 0 13/2 13/2 22 028.93 337

7 2^ 5«— 7, 1, 6 Ground AE 0 15/2 15/2 22 028.93 337

7 3 4<— 7, 2, 5 Ground AE 0 11/2 11/2 18 427.00 337

?! 3! 4^ 7!

2' 5 Ground AE 0 17/2 17/2 18 427.00 337

7, 3, 4^ 7, 2, 5 Ground AE 0 13/2 13/2 18 429.23 337

7 3 4^ 7 2 5 Ground AE 0 15/2 15/2 18 429.23 337

8 3, 5«— 8 2 6 Ground AE 0 13/2 13/2 19 836.38 337

8, 3, 5^ 8, 2, 6 Ground AE 0 19/2 19/2 19 836.38 337

8^ 3^ 5^ 8^ 2! 6 Ground AE 0 15/2 15/2 19 837.06 337

8, 3, 5^ 8, 2, 6 Ground AE 0 17/2 17/2 19 837.06 337

9 3, 6<— 9, 2, 7 Ground AE 0 19/2 19/2 23 242.90 337

g_ 3, 6^^ 9, 2, 7 Ground AE 0 17/2 17/2 23 242.90 337

9 3, 6<— 9, 2, 7 Ground AE 0 21/2 21/2 23 242.90 337

9^ 3! 6^ 9!

2' 7 Ground AE 0 15/2 15/2 23 242.90 337

9, 4, 5^ 9, 3, 6 Ground AE 0 15/2 15/2 24 862.10 337

- 9 4 5<_ 9 3 6 Ground AE 0 21/2 21/2 24 862.10 337

9_ 4, 5.^ 9, 3, 6 Ground AE 0 17/2 17/2 24 865.15 337

9 4 5«_ 9 3 6 Ground AE 0 19/2 19/2 24 865.15 337

lo! 4! 6^10! 3] 7 Ground AE 0 17/2 17/2 24 235.00 337

10, 4, 6^10, 3, 7 Ground AE 0 23/2 23/2 24 235.00 337

10 4 5<_ 10 3 7 Ground AE 0 19/2 19/2 24 236.35 337

10 4 6<— [0 3 7 Ground AE 0 21/2 21/2 24 236.35 337

11, 4^ 7«— [1, 3, 8 Ground AE 0 19/2 19/2 25 585.28 337

11^ 4^ 7^11^ 3, 8 Ground AE 0 25/2 25/2 25 585.28 337

11, 4, 7«- 11, 3, 8 Ground AE 0 21/2 21/2 25 585.28 337

11, 4, 7<— .1, 3, 8 Ground AE 0 23/2 23/2 25 585.28 337

C'2D3C'^0"^CF 364 3, 1_ 3.^ 2, 0, 2 Ground AE 0 9/2 7/2 23 382.73 337

3, 3<— 2, 0, 2 Ground AE 0 7/2 5/2 23 386.40 337

3^ I, 3^ 2!

0' 2 Ground AE 0 3/2 3/2 23 388.60 337

4, 0, 4^ 3, 1, 3 Ground AE 0 7/2 5/2 25 441.10 337

4, 0, 4«— 3, 1, 3 Ground AE 0 9/2 7/2 25 441.10 337

4. 0, 4^^ 3, 1, 3 Ground AE 0 5/2 3/2 25 443.15 337

4, 0, 4^^ 3, 1, 3 Ground AE 0 11/2 9/2 25 443.15 337

4^ 4«- 3'0, 3 Ground 28 662.85 .1 384

4, 1, 4^ 3, 0, 3 Ground 28 664.17 .1 384

4 ]^ 4^^ 3 0, 3 Ground AE 0 11/2 9/2 28 667.02 337

4 J 4<— 3 0 3 Ground AE 0 7/2 5/2 28 667.02 337

4. 1 0, V, 3 Ground AE 0 9/9 7/2 28 668.73 337

5, 0, 5^ 4, 1, 4 Ground 32 346.0 .2 384

6, 3, 4^ 6, 2, 5 Ground 29 179.00 .1 384

7, 2. 5^ 7, 1, 6 Ground AE 0 11/2 11/2 21 123.0 337

7, 2. 7, 1, 6 Ground AE 0 17/2 17/2 21 123.0 337

7, 2, 5^ 7. 1, 6 Ground AE 0 15/2 15/2 21 123.0 337

7, 2, 5*- 7. 1, 6 Ground AE 0 13/2 13/2 21 123.0 337

7, 3, 4*- 7, 2, 5 Ground AE 0 17/2 17/2 18 730.03 337

7, 3, 4^ 7, 2, 5 Ground AE 0 11/2 11/2 18 730.03 337

112
Acetyl Chloride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State F' F' F F MHz ±MHz

C'2D3C'20"'C1" 364 3, 4*— 7, 2, 5 Ground AE 0 15/2 15/2 18 732.27 337

7^ 3, 4<— 7^ 2, 5 Ground AE 0 13/2 13/2 18 732.27 337

s'

3' 5^ 8'

2! 6 Ground AE 0 13/2 13/2 19 667.25 337

8, 3, 5^ 8, 2, 6 Ground AE 0 19/2 19/2 19 667.25 337

8, 3, 5<— 8^ 2, 6 Ground AE 0 17/2 17/2 19 667.25 337

8, 3, 5<— 8, 2, 6 Ground AE 0 15/2 15/2 19 667.25 337

9^ 3, 6<— 9, 2, 7 Ground AE 0 19/2 19/2 22 470.92 337

9\ 3! 6^ 9^ 2! 7 Ground AE 0 21/2 21/2 22 470.92 337

9, 3, 6-^ 9, 2, 7 Ground AE 0 17/2 17/2 22 470.92 337

9^ 3, 6'^ 9, 2, 7 Ground AE 0 15/2 15/2 22 470.92 337

9^ 4, 5-^ 9, 3, 6 Ground AE 0 21/2 21/2 25 827.40 .337

9'

4^ 5<— 9,

3' 6 Ground AE 0 15/2 15/2 25 827.40 .337

9^ 4! 5^ 9, 3! 6 Ground AE 0 17/2 17/2 25 829.70 337

9, 4, 5*- 9, 3, 6 Ground AE 0 19/2 19/2 25 829.70 337

10, 4, 6-^10, 3, 7 Ground AE 0 23/2 23/2 24 725.0 337

10, 4_ 6<—10, 3 7 Ground AE 0 17/2 17/2 24 725.0 337

10! 4^ 6-^10,' 3! 7 Ground AE 0 19/2 19/2 24 725.0 337

10, 4, 6^10, 3, 7 Ground AE 0 21/2 21/2 24 725.0 .337 \\ 4, 7<—11, 3, 8 Ground AE 0 19/2 19/2 25 356.28 337

\\ 4 7*—11 3 8 Ground AE 0 25/2 25/2 25 356.28 337

1

11, 4 7<—1

' ^ 1 1

,

J0, 8 Ground AE 0 23/2 23/2 25 357.04 337

11, 4, 7^11, 3, 8 Ground AE 0 21/2 21/2 25 357.04 337

12, 4, 8^12, 3, 9 Ground 28 139.55 .1 384

^ 9 A 0* iZ, q 9 Ground 28 141.00 .1 384

s-C'2H2DC'20"*CP= 365 Q 11

,

2 Ground 18 758.5 .2 337

a

0, u. 0^ z.

11

,

2 Ground 18 759.0 .2 384

3, 1, 3^ 2, 0, 2 Ground 25 623.0 .2 337

4, 0, 4^ 3, 1, 3 Ground 26 821.50 .1 384

I", u. 4'* 0, 11

,

3 Ground 26 822.75 .2 337

4 0, 4*— 3, 3 Ground 26 824.00 .1 384

5 1 4<— 5, 0, 5 Ground 21 695.4 .2 384

5! 1! 4^ 5! 0! 5 Ground 21 697.58 .2 337 '

5, 1, 4^ 5, 0, 5 Ground 21 698.15 .1 384

5, 1^ 4«— 5^ 0, 5 Ground 21 699.75 .1 384

3, 2«— 5, 2, 3 Ground 25 655.5 .2 384

3, 2«- 5'2, 3 Ground 25 657.85 .2 337

6! 2! 4^ 6^ 1! 5 Ground 18 275.45 .2 337

6, 3, 3^ 6, 2, 4 Ground 23 737.50 .2 337

7_ 2, 5<— 7, 1^ 6 Ground 22 573.05 .1 384

7 2, 5*— 7, 1^ 6 Ground 22 574.10 .1 384

7 2 5«— 7, 1^ 6 Ground 25 573.58 .2 337

7' 3I 4-^ 7! 2, 5 Ground 22 544.60 .1 384

7, 3, 4-^ 7, 2, 5 Ground 22 546.25 .2 337

7, 3, 4-^ 7, 2, 5 Ground 22 547.90 .1 384

8, 2, 6^ 8, 1, 7 Ground 28 513.80 .1 384

8, 2, 6^ 8, 1, 7 Ground 28 514.05 .2 337

8, 3, 5^ 8. 2, 6 Ground 22 726.75 .1 384

8, 3, 5^ 8. 2, 6 Ground 22 727.54 .2 337

8, 3, 5^ 8, 2, 6 Ground 22 728.32 .1 384

9, 3, 6«- 9, 2, 7 Ground 24 722.25 .2 337

1. The transition in Sinnotl's article listed as 5is*~5o5 is forbidden and assumed to have been a misprint. It has been entered as 5n*—5o5, an allowable "b" transition.

113
Acetyl Chloride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F,' F' F, F MHz ±MHz

365 10, 3, 7^10. 2, 8 Ground 28 739.25 .2 337

a-C'2H2DC'20"'CP^ 366 2 2<— -[ 0 1 Ground 19 352.5 .2 384

4 0 4^ 3! I 3 Ground 27 896.28 .1 384

4! 0! 4^ 3, 1, 3 Ground 27 897.37 .2 337

4, 0, 4-^ 3, 1, 3 Ground 27 898.46 .1 384

4 I 4^ 3, 0 3 Ground 31 064.53 .1 384

4 I 4<— 3, 0 3 Ground 31 065.70 .2 337

4 I 4-^ 3! 0 3 Ground 31 066.86 .1 384

5! I, 4^ 5, 0! 5 Ground 22 782.10 .1 384

5, 1, 4^ 5, 0, 5 Ground 22 784.10 .2 337

5, 1^ 4^^ 5, 0, 5 Ground 22 786.10 .1 384

5, 3, 2«— 5, 2, 3 Ground 21 840.5 .2 384

5, 3! 2-^ 5,

2' 3 Ground 21 844.75 .2 337

6^ 2] 4-^ 6, I. 5 Ground 18 577.95 .2 337

6, 2, 4^ 6, 1, 5 Ground 18 578.3 .2 384

7^ 2, 5<- 7, 1, 6 Ground 24 015.28 .2 337

7, 3. 4^ 7, 2, 5 Ground 19 987.2 .2 384

7, 3, 4*- 7, 2, 5 Ground 19 988.0 .2 337

s'

3' 5^ 8, 2! 6 Ground 21 565.5 .2 337

9, 3, 6^ 9, 2, 7 Ground 25 324.9 .2 337

9^ 4, 5*- 9, 3. 6 Ground 26 909.85 .1 384

9, 4, 5^ 9, 3, 6 Ground 26 911.43 .2 337

9, 4, 5^ 9, 3, 6 Ground 26 913.00 1 384

10, 3, 7^10, 2, 8 Ground 31 193.77 .1 384

10, 3 7^10, 2, 8 Ground 31 195.35 .1 384

10, 3 7^ 10. 2, 8 Ground 31 196.34 .1 384

10, 3, 7^10, 2, 8 Ground 31 197.88 .1 384

10, 4, 6-^10. 3, 7 Ground 26 281.5 .2 337

10 4, 6^10, 3, 7 Ground 26 282.0 .2 384

C'^H3C'20"^CF 367 4, 0, 4^ 3, 1^ 3 Ground E 0 9/2 7/2 27 813.90 .2 337

4^

0" 4^ 3, 3 Ground E 0 7/2 5/2 27 813.90 .2 337

4! 0, 4^ 3, h 3 Ground A 0 9/2 7/2 27 813.90 .2 337

4, 0, 4<- 3, 1, 3 Ground A 0 7/2 5/2 27 813.90 .2 337

4, 0, 4<- 3, 1, 3 Ground E 0 11/2 9/2 27 816.80 .2 337

4, 0, 4^ 3, 1, 3 Ground E 0 5/2 3/2 27 816.80 .2 337

4, 0, 4*- 3. 1^ 3 Ground A 0 11/2 9/2 27 816.80 .2 337

4!

0' 4<- 3, 1! 3 Ground A 0 5/2 3/2 27 816.80 .2 337

5, 3, 2^ 5. 2, 3 Ground AE 0 7/2 7/2 24 179.60 .2 337

5 3, 2->- 5, 2^ 3 Ground AE 0 13/2 13/2 24 181.90 .2 337

5, 3, 2<- 5, 2^ 3 Ground AE 0 9/2 9/2 24 188.08 .2 337

5 3, 2^ 5, 2^ 3 Ground AE 0 11/2 11/2 24 190.08 .2 337

6^ 2, 4^ 6,

1' 5 Ground E 0 13/2 13/2 18 816.30 .2 337

6, 2, 4^ 6, 1, 5 Ground E 0 11/2 11/2 18 816.30 .2 337

6, 2, 4^ 6, 1, 5 Ground E 0 15/2 15/2 18 816.30 .2 337

6, 2, 4-^ 6. 1, 5 Ground E 0 9/2 9/2 18 816.30 .2 337

6, 2, 4-^ 6, 1, 5 Ground A 0 13/2 13/2 18 819.38 .2 337

6, 2, 4^ 6, 1, 5 Ground A 0 11/2 11/2 18 819.38 .2 337

6, 2, 4*- 6, 1, 5 Ground A 0 15/2 15/2 18 819.38 .2 337

6, 2. 4<- 6, 1, 5 Ground A 0 9/2 9/2 18 819.38 .2 337

114
Acetyl Chloride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperf ine Frequency Acc. Ref. No. Quantum Nos. State n F,' F' F, F MHz ±MHz

C'^H3C'20"«CP=> 367 6, 3, 3^ 6, 2, 4 Ground AE 0 9/2 9/2 22 371.19 .2 337

6, 3, 3-^ 6, 2, 4 1V^I_ i^^*UU1 1 nIIU AE 0 15/2 15/2 99 O^711 1.17IQ .z 00 i 6, 3, 3^ 6, 2, 4 Ground AE 0 11/2 11/2 22 376.,50 .2 337

6, 3, o*^ 0, Z, 4 Ground AE 0 13/2 13/2 22 376.50 .2 337

7, 2, 5^ 7, 1, 6 Ground E 0 15/2 15/2 23 841.25 .2 337

7, 2, 5^ 7, 1, 6 Ground E 0 13/2 13/2 23 841.25 .2 337

7, 2, 5^ 7, 1, 5 1 . r<"» 1 1 n H E 0 17/2 17/2 9"^ 849 ^9 2 00 1 7, 2, 5-^ 7, 1, 6 Ground E 0 11/2 11/2 23 842.59 .2 .337

7, 2, 5<— 7, 1, 6 Ground A 0 15/2 15/2 23 846.17 .2 .337

7, 2, 5*- 7, 1, 6 Ground A 0 13/2 13/2 23 846.17 .2 337

7, 2, 5^ 7, 1, 6 Ground A 0 17/2 17/2 23 847.47 .2 337

7, 2, 5-^ 7, 1, yj Ground A 0 11/2 11/2 oo 04.7 4.7 ^^7

8, 3, S'^ 8, 2, 6 Ground E 0 13/2 13/2 22 491.47 .2 337

o

o, 3,

r o O

o, Z, 6 Ground E 0 19/2 19/2 22 491.47 .2 337

8, 3, 5^ 8, 2, 6 Ground E 0 15/2 15/2 22 492.59 .2 337

8, 3, 5^ 8, 2, 6 Ground E 0 17/2 17/2 22 492.59 .2 337

8, 3, 5^ 8, 2, Xjrl U li I ILl A 0 13/2 13/2 99 49^ 90 2 337

8, 3, 5-^ 8, 2, 6 Ground A 0 19/2 19/2 22 493.90 .1 337

8, 3, 5«— 8, 2, 6 Ground A 0 15/2 15/2 22 495.00 .2 337

8, 3, 5^ 8, 2, 6 Ground A 0 17/2 17/2 22 495.00 .2 337

9, 3, 6-^ 9, 2, 7 Ground E 0 19/2 19/2 25 466.03 .2 337

9, 3, 6'«— 9, 2, 7 Ground E 0 17/2 17/2 Z.O **uu.oo .z9 00 i 9, 3, 6^ 9, 2, 7 Ground E 0 21/2 21/2 25 466.03 .2 337

9, 3, 6-^ 9, 2, 7 Ground I?£j u lO/Z 25 466.03 .2 337

9, 3, 6<- 9, 2, 7 Ground A 0 19/2 19/2 25 470.35 .2 337

9, 3, 6-^ 9, 2. 7 Ground A 0 17/2 17/2 25 470.35 .2 337

9, 3, 6<— 9, 2, 7 Ground A 0 21/2 21/2 25 470.35 .2 337

9, 3, 6^ 9, 2, 7 Ground A 0 15/2 15/2 25 470.35 .2 337

C'^HjC'^O'^Cl" 368 4, 0, 4^ 3, 1, 3 Ground E 0 9/2 7/2 27 044.25 .2 337

4, 0, 4^ 3, 1, QO Ground E 0 7/2 5/2 97 044 9'i .z9 ^^7

4, 0, 4^ 3, 1, 3 Ground A 0 9/2 7/2 27 044.25 .2 337

4, 0, 4<— 3, 1, 3 Ground A 0 7/2 5/2 27 044.25 .2 337

7, 2, 5-^ 7, 1, 6 Ground E 0 15/2 15/2 22 908.0 .2 337

7, 2, 5^ 7, 1, 6 Ground E 0 13/2 13/2 22 908.0 .2 337

7, 2, 5^ 7, 1, 5 \jl OUIIU E 0 17/2 17/2 99 908 0 2 337

7, 2, 5^ 7, 1, 6 Ground E 0 11/2 11/2 22 908.0 .2 337

/, 0* /, 1, 6 Ground A 0 15/2 15/2 22 912.1 .2 337

7, 2, 5^ 7, 1, 6 Ground A 0 13/2 13/2 22 912.1 .2 337

7, 2, 5^ 7, 1, 6 Ground A 0 17/2 17/2 22 912.1 .2 337

7, 2, 5^ 7, 1, 5 1 _ m1 1 n <~i V_y I U U I Ili A 0 11/2 11/2 22 912.1 .2 337

9, 3, 6^ 9, 2, 7 Ground E 0 19/2 19/2 24 822.00 .2 337

n

y.

>> 3, o*~ y, z. 7 Ground E 0 17/2 17/2 24 822.00 .2 337

9, 3, 6^ 9, 2, 7 Ground E 0 21/2 21/2 24 822.00 .2 337

9, 3, 6^ 9, 2, 7 Ground E 0 15/2 15/2 24 822.00 .2 337

9, 3, 6-^ 9, 2, 7 Gro und A 0 19/2 19/2 94 89 1^8 2 337

9, 3, 6"^ 9, 2, 7 Ground A 0 17/2 17/2 24 825.58 .2 337

9, 3, 6-^ 9, 2. 7 Ground A 0 21/2 21/2 24 825.58 .2 337

9, 3, 6*- 9. 2, 7 Ground A 0 15/2 15/2 24 825.58 .2 337

10, 3, 7^10, 2, 8 Ground E 0 21/2 21/2 29 932.42 .2 337

115
Acetyl Chloride

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n f; F' F MHz ±MHz

368 1iU,n o

.J, 8 Ground E 0 19/2 19/2 29 932.42 .2 337

10, 3, 7-^10, 2, 3 E 0 23/2 23/2 .z9 QQ7

10, 3, 7^10, 2, 8 Ground S-i nU 17/9 1 //Z 17/9 1 //Z 29 932.42 .2 337

10, 3, 7^10, 2, 8 Ground A 0 23/2 23/2 29 938.48 .2 337

10, 3, 7^10, 2, Q0 Ground A 0 21/2 21/2 9Q Q^Q AO. .z

1 n Q 1 A O

i

*^ iU, z. 8 Ground A 0 19/2 19/2 29 938.48 .2 337

10, 3, 7^10, 2, 8 Ground A 0 17/2 17/2 29 938.48 .2 337

C'2H3C'30"^CF 369 4, 0, 4^ 3, 1, 3 Ground E 0 9/2 7/2 28 196.8 .2 337

4, 0, 4^ 3, 1, 3 1\_7i _ n~iUimr\ UIIU. E 0 7/2 5/2 90 1 qf, Q .z9 ^^7

4, 0, 4^ 3, 1, 3 Ground A 0 9/2 7/2 28 196.8 .2 337

A n

^, 4-* O, 1, 3 Ground A 0 7/2 5/2 28 196.8 .2 337

4, 0, 4*- 3, 1, 3 Ground E 0 11/2 9/2 28 199.6 .2 337

4, 0, 4-^ 3, 1, 3 Ground E 0 5/2 3/2 28 199.6 .2 337

4, 0, 4^ 3, 1, 3 Ground A 0 11/2 9/2 90 1 QQ A ZO .z9 5^7

4, 0, 4^ 3, 1, 3 Ground A 0 5/2 3/2 28 199.6 .2 337

'J, 2*— 5 2 3 Ground AE 0 7/2 7/2 25 223.87 .2 337

5, 3, 2^ 5' 2] 3 Ground AE 0 13/2 13/2 • 25 227.20 .2 337

5, 3, 2*- 5, 2, 3 Ground AE 0 9/2 9/2 25 230.51 .2 337

5, 3, 2^ 5, 2, 3 1 w m1 1 n iH AE 0 11/2 11/2 95 9^9 97 2 337

7, 2, 5*- 7. 1, 6 Ground E 0 15/2 15/2 23 989.95 .2 337

7 9 c:« 7 1 6 Ground E 0 13/2 13/2 23 989.95 .2 337

7, 2, 5^ 7, 1, 6 Ground E 0 17/2 17/2 23 991.05 .2 337

7, 2, 5^ 7, 1, 6 Ground E 0 11/2 11/2 23 991.05 .2 337

7, 2, 5^ 7, 1, 5 1 — frti 1 n /I V7I UUIIU A 0 15/2 15/2 .z9 00 i 7, 2, 5^ 7, 1, 6 Ground A 0 13/2 13/2 23 995.15 .2 337

/, r ^ 7 1 0*^ <, i. 6 Ground A 0 17/2 17/2 23 996.28 .2 337

7, 2, 5^ 7, 1. 6 Ground A 0 11/2 11/2 23 996.28 .2 337

8, 3, 5^ 8, 2. 6 Ground E 0 13/2 13/2 23 066.35 .2 337

8, 3, 5^ 8, 2, 0 Ground E 0 19/2 19/2 90 rif^f. oc Zo uoo.oo .z9 00 ( 8, 3, 5^ 8, 2, 6 Ground E 0 15/2 15/2 23 067.67 .2 337

Qo.

0o. 0^ 0, Z, 6 Ground E 0 17/2 17/2 23 067.67 .2 337

8, 3, 5^ 8, 2, 6 Ground A 0 13/2 13/2 23 068.63 .2 337

8, 3, 5^ 8, 2, 6 Ground A 0 19/2 19/2 23 068.63 .2 337

8, 3, 5^ 8, 2, U Ground A 0 15/2 15/2 9a of-Q on 2 337

8, 3, 5^ 8, 2, 6 Ground A 0 17/2 17/2 23 069.90 .2 337

Q OO, 7 Ground E 0 19/2 19/2 25 791.85 .2 337

9, 3, 6^ 9. 2, 7 Ground E 0 17/2 17/2 25 791.85 .2 337

9, 3. 6^ 9, 2, 7 Ground E 0 21/2 21/2 25 791.85 .2 337

9, 3, 6*- 9, 2, 7 Ground E 0 15/2 15/2 Z. J 1 71 .O.J 2 337

9, 3. 6^ 9, 2, 7 Ground A 0 19/2 19/2 25 796.17 .2 337

V, J, y, z. 7 Ground A 0 17/2 17/2 25 796.17 .2 337

9, 3. 6^ 9, 2, 7 Ground A 0 21/2 21/2 25 796.17 .2 337

9. 3, 6^ 9, 2, 7 Ground A 0 15/2 15/2 25 796.17 .2 337

10, 3, 7*-10, 2, Q0 Ground E 0 21/2 21/2 2 337

10, 3, 7^10, 2, 8 Ground E 0 19/2 19/2 30 696.01 .2 337

10, 3, 7^10, 2, 8 Ground E 0 23/2 23/2 30 697.15 .2 337

10. 3, 7*-10, 2, 8 Ground E 0 17/2 17/2 30 697.15 .2 337

10, 3, 7^10, 2, 8 Ground A 0 21/2 21/2 30 702.86 .2 337

10, 3, 7-^10, 2, 8 Ground A 0 19/2 19/2 30 702.86 .2 337

116
Acetyl Chloride Spectral Line Table

Isotopic Species Id. Rotationa1 Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.

iNo. Quantum IN OS State n F' F iVlrlz

C'^HjC'^O'^CP 10, 3, 7^10, 00 Ground AA A Zo/Z Z6jZ .z9 ^H7 00 / 10, 3, 7^10, 9 Q

0 Ground A U

17/0 l IjZ ou /u.j.yy 9.Z 00 (

C'^H3C'-'0"'L1-" 6(1 1 A

lU, 3, /<—lU, 9Z, Q0 Lrrounci E 0 21/2 21/2 90 ^on 01 zy oyu.yi .z 557 00 / 10, 3, 7^10, 2, 8 Ground 17t, U

1 0/0 ly/z ly/z 29 390.91 .2 337

10, 3, 7^10, 2, 8 Ground l?£j A OQ /O Z6IZ Z6IZ 29 390.91 .2 .337

1 n Q-J, lU, 9 Q0 Ground E 0 17/2 17/2 zy90 oyu.yi 'ion 01 9Z 00H7/ lU, Q•J^

1 A / * lU, 9Z, Q0 Ground A 0 21/2 21/2 zy9Q ^IQA 07 oyo.y / 9.Z 557 00 (

lU, Q 7^^ 1 A

2, 8 Ground AA

A

U

1 Q/9 10/9 29 396.97 .2 337

10, 3, 7^10, z,9 00 Ground A

/\ AU Zo/ Z 9^/9 Zo/

Z

OA QQA Q7 0.z 00 ( 10, 3, 7^10, z.9 00 Ground AA

A\J i i/Z L i jZ OA on/; 07 .z

c H3L. u cr 0 Q z.9 7 round E 0 19/2 19/2 OC 1 AC ZO 4-11 .U.J .z9 00 / 0 0^ f.^ 0 2, 7 Ground AA

AU ly/z 10/9 iyf Z 25 414.85 .2 337

0 Q 0

2, 7 Ground AA

A

yj 17/9 1 i fZ L i (Z 25 414.85 .2 337

9, 3, 6^ 9, 9z. 7 Ground AA A

U

91 /9 Zl/z 91 /9 ZljZ 9^^ Al A Qc: 9Z 00557i 9, 3, 6^ 9, 9z. 7 Ground AA

r\V

1

c: /9 Ld/Z 1 /9 ZO9^^ Al A. ^-l^-.oO .z9 557 00 i

Q

y, n

0, 0 0* V, 9 7 vrround E 0 21/2 21/2 ZO '*4'l.U0 9.Z 00557/ y.

0O1 0 0* V, 2, 7 Ground 17IL A

u

1 c: /9 ID/Z 25 441.05 .2 337

y.

Q

•J, (1^ 0*— 0y. 2, 7 Ground 17H, A

u I i fZ 17/9 L I/Z 25 441.05 .2 337

10, 3, 7^10, 9Z, Q Ground A

u

91 /9 Zi/Z Zl/Z ouic\ OQO yoo.yuon 9.z 557 Oo / 10, 3, 7^10, 9z. 00 Ground 17 A

u

10/9 1 0/0 ou

OA Qoo yoo.yvj on .z9 00557/

1 AlU, J, 9 Q0 Ijrouna E 0 23/2 23/2 ouin OQQ yoo.yuon 9.Z 557 Oo / 1 A J, / * lU, 2, 8 Ground 17r. AU Li IZ 1 7 /o

I IjZ 30 988.90 .2 337

1 A J, /^lU, 2, 8 Ground AA A 01/0 ZijZ ZljZ 30 995.70 .2 337

10, 3, 7^10, 9z. Q Ground AA A 10/0 1^1 z

10/0 ou yyo. /u 9Z 557 00 / 10, 3, 7^10, Q0 Ground AA A ZojZ ZojZ ou

OA QO"^ 7n yyo. /u 9Z 557 00 i

1 AID,

0^1

-7,v 1 A 9z. Q0 L^rouna A 0 17/2 17/2 ouin Qoc: 7n yyo. /u 9.z 557 00 i 11,

A

'*1

-7,£ 1 1 3, 8 Ground 17sL Au

1 Q/O

\.\>IZ 10/0 28 338.33 .2 337

11, 4,

7^:: 1 1

/ ^1 i, 3, 8 Ground 17H. Au ZojZ ZO/Z 28 338.33 .2 337

11, 4, 7^11, Q Q0 i^rouna ¥7 A

U

01/0 ZljZ ZL/Z Zo9Q ^^ft 11 000.00 9.Z 00557( 11, 4, 7^11, Q Q0 Ground 17 Au ZojZ ZojZ Zo9Q "^QQ 11 OOo.OO 9.z 005571

1 1 ii. A4, Q0 Ground A 0 19/2 19/2 Zo9Q Q/1 1 in O^-l . lU 9.Z 00557/ 1 1 /I 4, 3, 8 Ground AA

A(J ZbjZ ZofZ 28 341.10 .2 337

1 1 ii. A /*—11, 3, 8 Ground AA A 01/0 ZljZ Zl/Z 28 341.10 .2 337

11, 4, 7^11, 0, Q0 Ground AA A ZojZ Zo/Z Zo9Q Q/1 1 in O'+i.lU 9.z 557 00 / 12, 4, 8^12, Q Ground r?t, AU

01/0 ZljZ ZljZ 11 Ql 1 ACi Oi Oll.4'U 9.Z 00557/

12, 4, 8^12, Q Ground E 0 27/2 27/2 •^1 Q1 1 /in 01 oii.^-u 9.z 00557/ 12 4 8*—12 3, 9 Ground t, A

Z6IZ ZolZ 31 811.40 .2 337

12!

4' 8^-12^ 3, 9 Ground E 0 25/2 25/2 31 811.40 .2 337

12, 4, 8^12, 0, Qy Ground j\ Q 21/2 21/2 01 017 cc ol ol / .00 9.Z 557 00 / 12, 4, 8^12, 3, 9 Ground A 0 27/2 27/2 31 817.55 .2 337

12, 4, 8^12, 3, 9 Ground A 0 23/2 23/2 31 817.55 .2 337

12, 4, 8^12, 3, 9 Ground A 0 25/2 25/2 31 817.55 .2 337

749-587 0-69—

9

117
380- 1,1,1-Trichloroethane' Molecular Constant Table

Methylchloroform C2H3CI3 CsvCCsv.Cav) CH3CCI3

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MH2) C (MHz) Dj K A

C'^HjC'^Clf C3V 381 2 372.6 M 2 372.6 M

Id. No. fia Debye /j-b Debye Debye eQq V3 Acc. I red cjb d aj(. d Wa d

381 0. X 0. X 1.79 G 3000

1. Assumed CCI3 configuration as in chloroform and CH3 as in methane. References: ABC: 53 Dj: Djk: k: A:

fj.: -388 eQq: V: 113 I: w: Add. Ref.: 160

1 , 1 , 1-Trichloroethane

Spectral Line Table

Isotopic Species Id. No.Rotational Quantum Nos.Vib. State Int. Rotor

State n F.' ^ypeF'

rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

C'^HjC'^Clf 381 5. ^ 4,

8, ^ 7, Ground

Ground

23 735. 37 955.88

10..40 158

53

I

I

118
390 - Acetyl Fluoride Ethanoyl Fluoride Molecular Constant TabU

CHoCOF

Isotopic Species Pt. GdId. No. A (MHz) B(MHz) C (MHz) D., K A

c. 391 11 039.28 M 9 685.65 M 5 322.05 M 3.000 C'^D3C"0"'F"' 392 10 319.46 M 7 986.06 M 4 763.02 M 6.153 C^HjC'^O'^'F"' Cs 393 11 038.83 M 9 309.72 M 5 206.44 M

C'^HjC'^O'T"' Cs 394 10 522.74 M 9 470.63 M 5 136.20 M

s-C'^HDjC'^O'T'' Cs 395 10 586.16 M 8 420.42 M 4 971.86 M 6.112 a-C'^HDjC'^O'^F"' c, 396 10 .591.19 M 8 467.89 M 4 908.64 M

s-C'2H2DC'20"'F"' Cs 397 10 919.20 M 8 971.39 M 5 075.09 M 3.036 a-C'^HaDC'^O'T'" c, 398 10 805.96 M 9 016.47 M 5 134.54 M

Cs 399 11 034.56 M 9 686.60 M 5 321.32 M

Cs 401 10 315.05 M 7 985.33 M 4 761.80 M

Id. No. jUa Debye jj-u Debye /Lij. Debye eQq V3 Acc. I red OJa d a)|, d o),. d 0),! d

391 2.83 M 0.88 M 0. X 1041 6

392 1031 6

394 2.92 M 0.30 M 0. X 1055 6

References: ABC: 263

fi: 263 Add. Ref.: 150

Dj:

eQq:

Djk:V: 263

A: 263

oj:

For species 391, 392, 393, and 394, the coupling parameter is !«= 3.158 amu A^. Ref: 263.

119
Acetyl Fluoride

ctral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz 1

C'-HgC'^O'T'^ 391 1. 0. 1^ 0. 0, 0 1 (Jround A 0 15 007.91 2 1 263

2. 0. 2^ 1, 0, 1 1 Ground E 0 26 734.61 •2 263

2. 0, 2^ 1. 0. 1 (Ground A 0 26 739.20 .2 263

2, 1. 1^ 1. 1, 0 Ground A 0 34 379.40 •2 263

2, 1, 2^ 1. 1, 1 Ground A 0 25 651.87 .2 263

2, 1, 1^ 2, 1, 2 1 (rround 13 091.42 •2 261

3. 0,

Q ^ O f\ O* /, U, 9 1 Ground E 0 37 051.64 2 i 263

3, 0, 3^ 2, 0. 2 Ground A 0 37 0.55.85 2 263

3. 1, 2^ 3. 1. 3 Ground E 0 24 072.41 •2 263

3. 1, 2^ 3. 1, 3 1 Ground A 0 24 079.83 .2 263

4. 2, 2^ 4, 2, 3 1 Ground A 0 22 512.80 •2 1 263

4, 2, o 1 Ground E 0

OO CIO 10 o

.Z 1 263

5, 3, 2^ 5. 3, 3 i (rround A 0 20 073.25 •2 263

5. 3, 2*- 5. 3. 3 Ground E 0 20 094.58 2 263

6, 4, 2^ 6, 4, 3 Ground A 0 16 935.00 2 263

6, 4, 2^ 6, 4, 3 ! Ground E 0 16 972.60 .2 i 263

8, 5, 3*— 8, 5, 4 1 Ground A 0 •2 i 263

8, 5, 3-^ 8, 5. 4 Ground E 0 26 732.94 •2 263

9. 6, 3^ 9. 6. 4 Ground A 0 22 427.90 2 263

9. 6. 3^ 9. 6. 4 Ground E 0 22 505.64 •2 263

10. 7. 3^10. 7, 4 Ground A 0 17 745.20 2 263

10. 7. 3«— 10. 7, 4 Ground E 0

1

"7 OOn OC?

1 / o6\>.Z6 o.Z 263 Not Reported Ground 15 802.28 2 261 Not Reported (Ground 15 886.51 •2 261 Not Reported (Ground 15 938.33 2 261

Not Reported Ground 16 205.5 .-2 1 261 Not Reported (Ground 16 243.4 *^ .2 1 261 Not Reported Ground 16 273.5 •2 261 Not Reported Ground 16 285.8 .2 261 Not Reported Ground 16 314.8 •2 261

Not Reported Ground 20 095.87 2 261 Not Reported Ground no CIA OA o-Z ZOl Not Reported Ground 22 556.28 •2 261 Not Reported Ground 23 470.99 2 261 Not Reported Ground 23 487.11 •2 261

Not Reported Ground 24 017.14 .2 261 Not Reported Ground 9/1 1 "^Q 7Q Z4- loo. /

O

9 1 ZOl Not Reported Ground 25 186.63 •2 261 Not Reported Ground 25 279.90 2 261 Not Reported Ground 25 354.51 •2 261

Not Reported Ground 25 382.23 •2 261 Not Reported (iround OCT /ino 9 1 .Z 9A1 ZOl Not Reported (iround 25 408.60 •2 261 Not Reported Ground 25 413.40 2 261 Not Reported Ground 25 437.8 •2 261

Not Reported (iround 25 619.50 •2 261 Not Reported Ground 25 658.53 •2 261

i Not Reported Ground 26 144.27 •2 261

1 Not Reported Ground 26 239.61 '2 261

1 Not Reported Ground 26 612.3 2 261

120
Acetyl Fluoride Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Rel. No. Quantum Nos. State n f;1 F' F F MHz ±MHz

C'^H3C'^0"'F'" 391 Not Reported Ground 26 668.7 .2 261 Not Reported Ground 26 723.74 .2 261

C'^DjC'^O'T"' 392 2, 0, 2^ 1, 0, 1 Ground A 0 I 23 722.63 .2 263

2, 1, 1<— 1, 1, 0 Ground A 0 28 721.12 .2 263

2, 1, 2<— 1, 1, 1 Ground A 0 22 275.12 .2 263

3, 1, 3<- 3, 1, 2 Ground A 0 18 608.04 .2 263

4. 1, 3*- 4, 1, 4 Ground A 0 28 226.45 .2 263

4, 2, 2^ 4. 2. 3 Ground A 0 15 186.50 .2 263

5, 2, S'^ 5, 2, 4 Ground A 0 25 426.89 .2 263

6, 3, 3<- 6, 3, 4 Ground A 0 20 948.04 .2 263

7, 4, 3<— 7, 4, 4 Ground A 0 15 438.90 .2 263

7, 4,-3^ 7, 4, 4 Ground E 0 15 440.93 .2 263

8, 4, 4^ 8, 4, 5 Ground A 0 26 977.99 .2 263

8, 4, 4^ 8, 4, 5 Ground E 0 26 980.24 .2 263

9, 5, 4-^ 9, 5, 5 Ground A 0 20 356.01 .2 263

9, 5, 4-^ 9, 5, 5 Ground E 0 20 359.26 .2 263

10, 6, 4^10, 6, 5 Ground A 0 13 528.40 .2 263

10. 6, 4^10, 6, 5 Ground E 0 13 531.55 .2 263

11, 6, 5^11, 6, 6 Ground A 0 25 680.09 .2 263

11, 6, 5<-ll, 6, 6 Ground E 0 25 684.02 .2 263

12, 7, 5^12, 7, 6 Ground A 0 17 650.87 .2 263

12. 7, 5^12. 7. 6 Ground E 0 17 655.53 .2 263

Not Reported Ground OA ono oc .2 261 Not Reported Ground 23 861.4 .2 261

393 2, 0, 2^ 1, 0, 1 Ground E 0 26 214.86 .2 263

2, 0, 2^ 1. 0, 1 Ground A 0 26 218.70 .2 263

2. 1. 1^ 1. 1. 0 Ground A 0 33 135.80 .2 263

2, 1, 2^ 1, 1, 1 Ground A 0 24 929.38 .2 263

3, 1. 2^ 3, 1, 3 Ground A 0 23 045.70 .2 263

3, 1, 2^ 3, 1, 3 Ground E 0 23 050.60 .2 263

4, 2, 2-^ 4, 2, 3 Ground A 0 20 768.85 .2 263

4, 2, 2^ 4, 2, 3 Ground E 0 20 776.98 .2 263

6, 3, 3^ 6, 3, 4 Ground A 0 29 965.25 .2 263

6, 3, 3^ 6, 3, 4 Ground E 0 29 979.27 .2 263

7, 4. 3^ 7, 4, 4 Ground A 0 26 192.50 .2 263

7, 4, 3^ 7, 4, 4 Ground E 0 26 228.50 .2 263

8, 5. 3^ 8, 5, 4 Ground A 0 21 405.82 .2 263

8, 5, 3^ 8, 5, 4 Ground E 0 21 462.35 .2 263

10, 6, 4^10. 6, 5 Ground A 0 30 501.80 .2 263

10, 6. 4^10. 6, 5 Ground E 0 30 577.20 .2 263

11, 7. 4^11, 7, 5 Ground A 0 1 24 337.70 .2 263

11, 7, 4-^11, 7, 5 Ground E 0 24 435.85 .2 263

12, 8, 4^12, 8. 5 Ground A 0 17 915.80 .2 263

12, 8, 4^12, 8, 5 Ground E 0 1 18 024.90 .2 263

C'^HjC'^O'T'" 394 1. 1, 1^ 0, 0, 0 Ground A 0 1 14 606.97 •2 1 263

2, 0, 2<- 1, 0, 1 Ground E 0 25 760.73 .2 1 263

2, 0, 2-^ 1, 0, 1 Ground A 0 25 764.98 2 1 263

2, 1, 1<- 1, 1, 1 Ground A 0 1 33 547.57 2 1 263

2. 1. 2^ 1, 1. 1 Ground A 0 24 879.75 2 1 263

121
Acetyl Fluoride Spectral Line Table

Isotopic Species la. Rotational V ID. oiaie Int. Rot 3r Hyperfine Frequency Acc. ilet. Quantum Nos. State n

1?' r

IT r ivinz 3:Mrlz

394 4, 2, 2<^ 4, 2, 3 Ground A 0 22 525.39 .2 263

4, 2, 2-^ 4, 2, 3 Ground E 0 22 527.51 .2 263

5, 3, 2^ 5, 3,

00 Ground AA U 00 '7'70 An

.2 263

5, 3, 2^ 5, 3,

00 OrouncI nU

00 '700 /t A .2 263

6, 4, 2-<- 6, 4, 0 Ground A U io 60ZA0 .2 263

6, 4, 2^^ 6, 4, 3 Ground E 0 18 414.95 .2 263

8, 5, 3«- 8, 5, 4 Ground A 0 28 646.37 .2 263

8; 5, 3^^ 8, 5,

/I 4 Ground T?t, AU Zo 600. 18 .2 263

9, 6, 3^^ 9, 6, 4 Ground A 0 25 563.55 .2 263

9, 6, 3^ 9, 6, 4 Ground E 0 25 626.39 .2 263

10, 7, 3^10, 7, 4 Ground A

r\U 21 868.34 .2 263

10, 7, 3'^10, 7, 4 Ground T? u

0 1 OCT one zi 952.95 .2 263

s-C'2HD2C'20"T''' 395 2, 0, 2^^ 1, 0, 1 Ground 24 756.10 .2 263

2, 1, 1^ 1, 1, 0 Ground 30 233.13 .2 263

2, 1, 2<- 1, 1,

1 Ground 00 QD£: An 0

.z o/;o zoo

6, 3, 3*- 6, 3,

/i 4 Ground zo 4UU.UU 0

.z OAO z63

7, 4, S'^ 7, 4, 4 Ground 18 233.5 .2 263

8, 4, 4^^ 8, 4, Ground ou o4y.y 0

.z OAO zoo

9, 5, 4^ 9, 5, 5 Ground z4 490.4 .2 263

- 12, 7, 5<-12, 7,

z:0 Ground 00 CIO /I zo 0I0.4 0

.z 261

a-C'TM2C'20«'F>=* : 396 2, 0, 2^ 1, 0, 1 Ground 24 612.25 .2 263

2, 1, 1^ 1, 1, 0 Ground 30 312.30 .2 263

2, 1, 2^ 1, 1, 1 Ground 00 1 no on ZO lyo.oO 0

.z 263

s! I, 2^ 3, 1, 3 Ground on DC/; 00 zO o56.zz .2 261

3, 1, 2^ 3, 1, 3 Ground on 0 cn /I c zO o59.45 .2 261

4, 2, 2^ 4, 2, 3 Ground 17 319.30 .2 263

6. 3, 3^ 6, 3, 4 Ground 24 460.30 .2 263

7, 4, 3^ 7, 4, 4 Ground in /1 1 0 An ly 41Z.UU .2 263

7! 4^ 3^ 7' 4^ 4 Ground T /1 1 0 nc ly 4io.yD .2 263

8, 4, 4«- 8, 4, 5 Ground 00 AC OTA 0/ (Joz.iU .2 263

8, 4, 4^ 8, 4, 5 Ground 32 054.10 .2 263

9, 5, 4*- 9, 5, 5 Ground 26 193.05 .2 263

9, 5, 4'^ 9, 5, 5 Ground o^; 1 n/; ^n ZO iyo.ou 0

.z OAO zoo

10, 6, 4'^10, 6, 5 Ground 19 467.27 .2 263

10, 6, 4^10, 6, 5 Ground 19 471.22 .2 263

12, 7, 6^12, 7, 5 Ground oc m 0 1 0 ZD yiz.io .Z Zol

12, 7, 6'^12, 7,

r0 Ground oc m CO ZD yi ( .Do 0

.z OA!

s-C'2H2DC'20"*F'^ 397 2, 0, 2^ 1, 0, 1 Ground 25 576.50 .2 263

2, 1, l'^ 1, 1, 0 Ground 31 989.25 .2 263

2, 1, 2^^ 1, 1, 1 Ground Z4 lyo.OD 0

.z ZOo

7, 4, 3«- 7, 4, 4 Ground 00 OQl zo zol. rD. ZOO

1 n f.0, 6, 5 Ground oc CI 0 1 3 Zo Diy.io 0

.Z zOo

a-C'^HaDC'^O'-'F''* 398 2, 0, 2^ 1, 0, 1 Ground 25 719.08 .2 263

2, 0, 2^ 1, 0, 1 Ground 25 720.39 .2 263

2, 1, 1^ 1, 1, 0 Ground 31 283.38 .2 263

2, 1, 2*- 1, 1. 1 Ground 24 420.07 .2 263

3, 1, 2^ 3, 1, 3 Ground 21 907.91 .2 261

3, 1, 2^ 3, 1, 3 Ground 21 909.71 .2 261

122
Acetyl Fluoride Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos. Vib State Int. Rotor

State n F' lypeF'

ft icuu^ii^y

MHz

Ace ±MHz

Ref.

a-C'2H2DC'20"^F"' 398 4, 1,

A4, 1, 4 Ground 32 191.8 .2 261

A oi. /I4, Z, Qo Ground 19 487.98 .2 263

4, 2, 2-^ 4, 2, 3 1 - tTil 1 0

5, 2, 3-^ 5, 2, 4 \jV (J U llU o\j tot ,o 1 2

5, 2, 3«— rJ. o

z. 4 V7l vJ li IIU 2 261

5, 3, 2^ 5, 3, 3 Ground 16 089.5 .2 261

5, 3, 2«— 5, 3, 3 Ground 16 097.6 .2 261

6, 3, 3*- 6, 3, 4 Ground ZO9ft 090 77 UZV. 1 / 9.Z 9Aq ZOO

6, 3, 3'«— 6, 3, 4 Ground 28 035.49 .2 263

7, 4, 7, 4,

A4 Ground 23 998.35 .2 263

7, 4. 3^ 7, 4, 4 V7round 9dZ4' 01uiu.zu n 90 .Z9 Zuo

o

o. 4, 4<— o

o.

A4,

rO Ground IQ Od.7 ^9 o.z zoo

399 oz, 1, 1, It

11 Ground 25 650.62 .2 263

3, 1, 2<- 3, 1, 3 Ground E 1 24 082.77 .2 263

3, 1, 2<- 3, 1, 3 Ground A

}

94, f)R9 84. 2

9 9.* Z* 4-, z.9 o Ground rHi 99 ^9'i 09 2

/I 9 9<Z* z.9 t5q A

.A 99 S96 1 S 2 263

cD,

o

o, Z^^ c

^»

o Ground A 20 099.10 .2 263

5, 3, 2^ 5, 3, 3 1v^l. T(\ 1U1 n1 lUH E 1 20 099 20 .2 263

9, 6, 3^ 9. 6, 4 1V71.Frti 1 n ri \J \X\\\X E 22 506 26 .2 263

9, 6, .3^ 9. 6, 4 \ .-mil Ti

H

\J\. U UllU A J 22 506 98 2 263

401 2. 0, 2^ 1, 1, 1 Ground 23 717.18 .2 263

2. 1, 2^ 1, 1, 1 Ground 22 270.72 .2 263

3, 1, 2^ 3, 1, 3 Ground 18 609.24 .2 263

6, 3, 3^ 6, 3, 4 Ground 20 963.63 .2 263

9, 5, 4<- 9, 5. 5 Ground E 1 20 391.43 .2 263

9, 5, 4^ 9. 5. 5 Ground A 1 20 391.54 .2 263

123
410-1,1.1 -Trifluoroethane Molecular Constant Table

Metliyl Fluoroform C2H3F3 C3v(C3v,C3v) CH3CF3

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) Dj DjK K A

C3V 411 5 185.14 M 5 185.14 M .002 <.005

Cs 412 5 465.8 M 4 976.41 M 4 947.46 M .0014 Cs 413 5 390. M 4 804.78 M 4 743.28 M

414 4 605.87 M 4 605.87 M

C"H3C'TJ^ C3V 415 5 060.12 M 5 060.12 M

Id. No. Ma Debye IXt, Debye /Lii- Debye eQq v., Acr. I red COa d to,, d 0)^. d ojd d

411 2.27 M 0. X 0. X 3350 120

References: ' ABC: 135. 165. 188, 194 D,,: 135. 188 D.,k: 135 k: - A:

M: 370 eQq: V: 51 I: a: Add. Refs.: 18, 21, 30

Torsional frequency= 234±40 cm"'. Ref: 43.

1,1,1-Trifluoroethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc, Ref. No. Quantum Nos. State n F/ F' F MHz ±MHz

C'^HaC'-F^" 411 2, ^ 1, Excited 20 675.2 135

2, ^ 1, Excited 20 678.2 135

2, ^ 1, Excited 20 694.8 135

2, ^ 1, Excited 20 708.18 135

2, ^ 1, Excited 20 709.7 135

2, ^ 1, Excited 20 725.0 135

2, ^ 1, Ground 20 740.53 .1 135

2, ^ 1, Excited 20 757.4 135

2, ^ 1, Excited 30 978.5 95

3, ^ 2, Ground 30 996.5 95

3, 2, Excited 31 012.82 135

3, ^ 2, Excited 31 017.20 135

3, ^ 2, Excited 31 042.2 135

3, ^ 2, Excited 31 062.06 135

3, ^ 2, Excited 31 063.97 135

3, ^ 2, Excited 31 064.68 135

3, <- 2, Excited 31 086.8 135

3, ^ 2, Ground 31 110.67 .1 135

3, ^ 2. Excited 31 136.0 135

4, ^ 3, Excited 41 356.06 135

4, ^ 3, Excited 41 415.94 135

4. ^ 3, Excited 41 418.30 135

4, ^3, Excited 41 419.48 135

4, ^ 3, Ground 41 480.72 .1 135 Not Reported 20 707.4 95

124
1,1,1-Trifluoroethane Spectral Line Table

Isotopic Species TrI Rotational Vih State Tnt Rntnr Hyperfine Frccjucncy Acc. Ref.

iNO. Quantum Nos. 3tHt€ n F' F, F MHz ±MHz

412 2, 0, 1, 0, 1 Ground 19 846.45 .2 188

2, 1, 1, 1, 0 Ground 19 876.68 .2 188

2, 1^ 2<— 1, 1, 11 Ground 19 818.74 2 188

s! o! 3^ 2, Q, 0z Ground 2 188

3, 1, 2^ 2, 1,

11 Ground 90 ftl 4. Oft 2 188

3, 1, 2, 3^ 2, 1, 2 Ground 29 727.20 .2 188

3, 1^ 2, 2, 0 Ground 29 776.39 .2 188

3, 2, 2<— 2, 2, 1 Ground 9Q 771 66 2 188

5^ o" 5^ 4! 0, A, Ground 40 =^Q4 2 188

5. 1, 4^ 4, 1, a Gro und 4Q 68^ 90 2 188

5, 1, 5^ 4, 1, 4 Ground 49 541.22 .2 188

5, X 3^ 4, 2, 2 Ground 49 640.22 .2 188

5, 2, 4-^ 4, 2,

30 Ground 4Q 616 09 2 188

5, 3, 2^ 4, 3, 1 Ground .2 188

5, 3, 3^ 4, 3, 2 Ground 49 623.16 .2 188

5. 4, 1<- 4, 4, 0 1 _ t*i^ 1 1 n ri V7l UUIIU 49 621.46 .2 188

5. 4, 2*- 4, 4, I

1 _ 1 1 n ri VjI UUIILl 49 621.46 .2 188 Not Reported 29 695.6 165

413 2, 0, 2^ 1, 0, 1 Ground 19 090.0 .2 165

2, 1, 1^ 1, 1, 0 Ground 19 157.8 .2 165

2, 1, 1^ 1, 1, u Ground 28 519.5 2 165

2, 1, 2^ 1. 1,

1I Ground 1Q n^d 7 2 165

3. 0, 3^ 2, 0. z9 Ground zo uzo.o .z 16=^

3,

3.

1, 2^ 2, 1, 1 Ground 28 734.7 .2 165

1, 3^ 2, 1, 2 Ground 28 549.1 .2 165

3. 1, 3*- 2. 1, 2 Ground 28 607.4 .2 165

3, 2, 1^ 2, 2, 0 Ground 28 661.7 .2 165

3, 2, 1*- 2, 2, Gro und 98 705 6 2 165

3, 2, 2*- 2, 2,

11 v^rouncl .z9 100

414 2, 1, Ground 18 423.6 .2 165

2, 1, Ground 97 SI n s 2 I6S

2, 1, Ground 27 563.0 !2 165

2. 1, Ground 27 597.5 .2 165

3, 2, Ground 27 6.35.9 .2 165

125
420 - Methyl Isothiocyanate Molecular Constant Table C2H3NS Cs(C3v,C,) CH3NCS

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) Dj DjK K A

C'^HaN'^C'^S^^ Cs 421 78 200. M 2 548. M 2 506. M .0036 .4020

Id. No. /Aa Debye fj.^ Debye Debye eQq V Acc. I red OJa d Wii d CDj. d cOd d

421 3.18 T 0. X 300 1 600 1

References: ABC: 20 Dj: 20 Djk: 20 k: A:

395 eQq: V: ' I: co: 20

Torsional frequency= 200 cm"'. Ref: 20.

Methyl Isothiocyanate Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

C'^HgN'-'C'^S''^ 421 4, , *- 3, , Ground 20 216. 20

4, , ^3, , 0: 1 20 241. 20

4, , ^3, , 1; 0 20 350. 20

4. , ^3, , 1 20 443. 20

4, 1, 4^ 3, 1, 3 Ground 20 140. 20

5, , •^4, , Ground 25 269. 20

5, , ^4, , 0; 1 25 306. 20

5, , 4, , 1; 0 25 442. 20

5, , ^ 4, , 1 25 550. 20 Ground 20

5, 1, 4^ 4, 1, 3 1 25 653. 20

5. 1, 5^ 4, 1, 4 Ground 25 195. 20

C^HgN^C'^S^^ 422 5, , ^ 4, , Ground 24 143. 20

C'^HjN'^C'^S^^ 423 5, , ^4, , Ground 25 002. 20

C'^HgN'^C'^S^^ 424 5, , ^4, , Ground 24 930. 20

C'^HaN'^C'^S^" 425 4, , ^ 3, , Ground 19 700. 20

4, , ^ 3, , 1 19 929. 20

5, , 4, , Ground 24 609. 20

5, , ^ 4, , 1 24 910. 20

6, , ^ 5, , Ground 29 540. 20

6, , ^ 5, , Ground 29 700. 20 CH^NbCS" 426 4, , ^3, , 20 020. 20

4, , ^3, , 20 230. 20

4, , ^ 3, , 20 413. 20

5, , ^ 4, , 24 824. 20

5, , ^ 4, , 24 971. 20

5, , ^4, , 25 077. 20

5, , ^4, ,

. 25 100. 20

5, , ^4, , 25 161. 20

5, , ^4, , 25 390. 20

5, , ^4, , 25 409. 20

126
430 -Methyl Thiocyanate Molecular (Constant Table Methyl Sulfocyanate

C2H3NS C,(C3v,Cs) CH3SCN

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) D., K A

C'^HjS'^C'^N" 431

Id. No. /Aa Debye Mb Debye Debye eQq >• V Acc. Ireil tUa d wi, d ai(. d

431 3.16 T 0. X

References: ABC: Dj: Djk: A:

fi: 395 eQq: V: I: co:

The average rotational constant (B+ C)/2 is: .09462 ± .00005 cm"'. Ref: 20.

Methyl Thiocyanate

gp^^^^^, ^.^^ ^^^^^

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

C'^'HsS'^C'^'N" 431 4, . ^ 3, , Excited 22 680. 10. 20

5, , ^4, , Excited 28 380. 10. 20

127
440- l-Chloro-2-Fluoroethane Molecular Constant Table

C2H4CIF C,(Cs,Cs) CH2FCH2CI

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) Dj K A

c. 441 13 606.45 M 3 289.9 M 2 876.75 M -.923 F'^HXFH.CP c, 442 -.9262

Id. No. /Lia Debye IXb Debye fi^. Debye eQq V Acc. I red (1)^ d C0|, d (1)^ d (0(1 d

441 1.97' T

1. Dipole moments given in Maryult and Buckley range from 1.84 to 1.97 D. Since the cis- form would be expected to yield a higher value for the dipole moment, that value is quoted here. References: ABC: 231 Dj: Djk: , « 231, 259 A:

/x: 393 eQq: V: I: co: Add. Ref.: 185

For species 441, Xaa = - 23.5 MHz, Xbb = -8.8 MHz. and Xcc = 32.3 MHz. Ref: 231. For species 442, Xaa = - 17.6 MHz, Xbb = -6.1 MHz, and Xcc = 23.7 MHz, and A-C= 10744.55 MHz. Ref: 259.

l-Chloro-2-Fluoroethane

Spectral Line Table

Isotopic Species Id. Rotatit nal Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n Ft' F' F MHz ±MHz

F' 441 1. 1, 0^ 1. 0, 1 Ground 10 729.7 231

2, 1, 2^ 1, 0, 1 Ground 22 236.7 231

2, 1, 1^ 2, 0, 2 Ground 11 155. 231

3, 1, 3^ 2, 0, 2 Ground 27 786.4 231

3, 1, 2<- 3, 0, 3 Ground 11 815.4 231

4, 0, 4^ 3, 1, 3 Ground 15 204.6 231

4, 1, 3^ 4, 0, 4 Ground 12 736.4 231

5, 0, 5*- 4, 1, 4 Ground 21 979.4 231

5, 1, 4^ 5, 0, 5 Ground 13 952.1 231

6, 0. 6^ 5, 1, 5 Ground 28 812. 231

6, 1, 5^ 6, 0, 6 Ground 15 500.3 .1 231

F' "H^Cl^H.^CF' 442 1, 1, 0*- 1, 0, 1 Ground 10 744.55 259

2, 1, 1^ 2, 0, 2 Ground 11 152.15 259

3, 1, 2^ 3, 0, 3 Ground 11 784.5 259

4, 1, 3^ 4, 0, 4 Ground 12 665.0 259

5, 1, 4^ 5, 0, 5 Ground i

1 13 825.4 259

1. An apparent misprint in one of the transitions given in Mukhtarov's article has been assumed to mean Sij"—2o2 rather than Si.i'i-So.i.

128
450 - 1,2-Dichloroethane Molecular CoristanI 'I'attle

C2H4CI2 Gs{Cs,CJ CH2CICH2CI

Isotopic Species Pt. Gd

Id. No. A (MHz) B (MHz) C (MHz) D., DjK K A

C2 451 9 299. ^M 2 510. ^M 2 090. ^M -.883

g-C'^HzCF-^C'^HaCl" 452 9 239. ^M 2 447. ^M 2 0.32. ^M -.884

453 9 180. ^M 2 385. '^M 1 974. ^M -.885

Id. No. /Lia Debye /Xb Debye fjLc Debye eQq V Acc. Ired OJa d (t>b d &>c d &J<i d

451 0. X 1.60" T 0. X

1. The dipole moment of the gauche form must occur along the axis of symmetry of the molecule, which in this case is the b-axis. Widely varying dipole moment values are given

in references, indicating that it is poorly known. One of the higher values was chosen since the gauche form would be expected to have a higher dipole moment.

2. The rotational constants were based upon "possible" identification of observed lines.

References: ABC: 134 Dj: Djk: A:

fj.: 393 eQq: V: I: to:

1,2-Diehloroethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n Ft' F' F, F MHz ±MHz

g-C'^HjCF^C'^HjCF^ 451 2, 2, 1<- 1, 1, 0 30 190. 134"

3, 2, 2^ 2, 1, 1 34 418. 1341

5, 1, 5-^ 4, 0, 4 27 289. 134'

6, 1, 6^ 5, 0, 5 30 992. 134'

11, 1,10^11, 0,11 27 160. 134'

12, 1,11^12, 0,12 30 650. 134'

1. The authors state that these identifications of the observed lines are "possible"

129
460- 1.1-Difluoroethane Molecular Constant Table

CsfQv.Cs) CH.,CHF2

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) Dj K A

C'^HjC'-^HFJ" 461 9 491.95 M 8 962.65 M 5 170.43 M .75504

Id. No. /Aa Debye jiib Debye fjL^ Debye eQq V3 Acc. Ired a)a d d cUc d d

461 2.01 M 0. X 1.12 M 3180 5.122 395 1

References: ABC: 98 Dj: Djk: k: 98 A:

ix: 292 eQq: V: 258 • I: 98 w: 98

Torsional frequency = 235 cm~'. Ref: 98. s

1 , 1-Difluoroethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

C'^HgC'^HFf 461 1, 1, 0*- 0, 0. 0 Ground 1 18 425.9 137

1. 1. 0*- 0, 0, 0 Ground 18 454.7 .1 98

2, 0, 2«- 1, 0, 1 1 24 894.3 J 98

2, 0, 2^ 1, 0, 1 Ground 1 24 926.6 137

2, 0, 2^ 1, 0. 1 Ground 24 951.6 .1 98

2, 1, 1^ 1, 0, 1 Ground 1 31 966.3 137

2, 1, 1«- 1, 0, 1 Ground 36 379.9 .1 98

2, 1, 1^ 1, 1, 0 Ground 32 049.0 .1 98

2, 1, 2^ 1, 1, 1 1 24 382.5 .1 98

2, 1, 2*- 1, 1, 1 Ground 1 24 425.7 137

2, 1, 2*- 1, 1, 1 Ground 24 473.8 .1 98

2, 2, o<- 1, 1, 0 Ground 36 959.4 .1 98

2, 2, l'^ 1. 1, 1 Ground 37 438.4 .1 98

3, 0, 2<- 2, 0, 1 Ground 35 097.0 .1 98

3, 1, 3^ 2, 1, 2 Ground 35 049.0 .1 98

3, 1, 2-^ 3, 1, 3 Ground 20 059.7 .1 98

3, 2, 2^ 3, 0, 3 Ground 20 317.9 .1 98

4, 1, 3^ 4, 1, 4 Ground 28 290.1 .1 98

4, 2, 3^ 4, 0, 4 Ground 28 312.4 .1 98

4, 2, 2^ 4, 2, 3 Ground 19 705.1 .1 98

4, 3, 2-^ 4, 1, 3 Ground 20 470.9 .1 98

5, 1, 4<- 5, 1, 5 Ground 36 403.3 .1 98

5, 2, 4-^ 5, 0, 5 Ground 36 403.3 .1 98

5, 2, 3^ 5, 2, 4 Ground 28 192.1 .1 98

5, 3, 3^ 5, 1, 4 Ground 28 280.6 .1 98

130
1,1-Difluoroethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

C'^HaC'^HFJs 461 5, 3, 2«- 5, 3, 3 Ground 19 055.8 .1 98

5, 4, 2^ 5, 2, 3 Gro u nd Lt\j f 70.^

6, 2, 4-^ 6, 2, 5 Ground 36 351.2 .1 98

6, 3, 4<— 6, 1, 5 Ground 36 358.5 .1 98

6, 3, 3^ 6, 3, 4 Ground 27 991.3 .1 98

6, 4, 3<- 6, 2, 4 Ground 28 254.8 .1 98

6, 4, 2*- 6, 4, QO (^round IS Ofil 9 1 vo

6, 5, 2^ 6, 3, 3 Ground 21 399.2 .1 98

6, 5, 2*— 6, 3, 3 Ground A 1 21 496.7 137

6, 5, 2*- 6, 3, 3 Ground E 1 21 498.2 137

7, 3, 4^ 7, 3, 5 Ground 36 263.9 .1 98

7, 4, 4-^ 7, 2, 5 1 tTT*! mH 36 291.4 .1 98

7, 4, 3^ 7, 4, 4 Ground 27 618!3 A 98

-7 r 3*— 7, 3, 4 Ground 28 265.6 .1 98

7, 6, 2-^ 7, 4, 3 Ground 22 423.1 137

7, 6, 2<- 7, 4, 3 Ground A 1 22 635.8 137

7, 6, 2^ 7, 4, 3 1 - rr\ 1 1 r» /I I \j U IIU E 1 99 0 137

8, 5, 3*- 8, 5, 4 Ground E 1 26 740.4 137

QO, C0, QO, C 4 Ground A 1 26 741.1 137

8, 5, 3^ 8, 5, 4 Ground 26 985.8 .1 98

8, 6, 3^ 8, 4, 4 Ground 28 364.6 .1 98

8, 7, 2^^ 8, 5, 3 Ground 23 996.4 137

8, 7, 2*- 8, 5, 3 Ground A 1 24 408.7 137

Qo. 7 QO,

i; "J, 3 Ground E 1 24 412.3 137

9, 7, 3^ 9, 5, 4 Ground 28 630.2 .1 66

9, 8, 2-^ 9, 6, 3 Ground 26 303.3 137

9, 8, 2*- 9, 6, 3 Ground A 1 '?f\ Q77 Q

9, 8, 2^ 9, 6, 3 Ground E 1 26 983.1 137

10, 7, 3*- 10, 7, 4 Ground E 1 24 099.1 137

10, 7, 3^ 10, 7, 4 Ground A 1 24 101.7 137

10, 7, 3^ 10, 7, 4 Ground 24 621.7 137

11, 8, 3^11, 8, Ground E 1 io * 11, 8, 3-^ 11, 8, 4 Ground A 1 22 139.7 137

11, 8, 3^ 11, 8, 4 Ground 22 822.2 137

12, 9, 3^12, 9, 4 Ground E 1 19 813.4 137

12, 9, 3*-12, 9, 4 Ground A 1 19 818.0 137

12, 9, 3^12, 9, 4 Ground 20 662.0 137

II

131
470 - Acetaldehyde Molecular Constant ^able

Ethanal

Cs(C3v,Cs) CH3CHO

Isotopic Species r t. Gp.la. No. A (MHz) B(MHz) C(MHz) UjK K A

Cs 471 56 920.5 M 10 165.1 M 9 100.0 M -.0028

Cs 472 34 990.6 M 8 577.9 M 7 531.4 M -.0021

Cs 473 9 864.80 M 8 637.07 M

Cs 474 41 798. M 8 590.23 M 7 816.87 M -.0023

Cs 475 8 779.55 M 8 174.35 M

C'^HjC'^HO Cs 476 56 757.22 M 9 857.50 M 8 848.74 M

C'2H3C'3HO'« Cs 477 55 816.3 M 10 162.6 M 9 069.6 M

C'^HjC'-^HO'" Cs 478 55 650.1 M 9 853.46 M 8 818.68 M

Cs 479 56 267. M 9 677.77 M 8 692.46 M -.0028

Id. No. ;Ma Debye fj-h Debye /Ltc Debye eQq V3 Acc. I red Wa d Wb d ojc d (0,1 d

471 2.55 M 0.87 M 0. X 1162 30

472 1151 30

474 1143 39

References: ABC: 171 Dj: 171 Djk: k: A:

jU.: 171 eQq: V: 171 I: <u: Add. Refs.: 23, 51, 144, 236 For species 471. Vg < 50 cal/mol. For species 472, \e < 58 cal/mol. For species 474, Ve < 39 cal/mol. Ref: 171.

132
Acetaldehyde Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n E'

~I VDf

F'

rfinc

F, F

Precjuency

MHz

Acc. ±MHzRef.

C'^HjC'^HO's 471 1, 0, 1<- 0, 0, 0 Ground A 0 19 225.7 .2 171

1, 0, I*- 0, 0, 0 Ground E 0 19 262.3 .3 171

I, 0, 1«- 0, 0, 0 Ground A 0 19 265.3 .2 171

I, 0, 1«— 0, 0, 0 Ground A 0 19 268.27 .2 171

2, 0, 2*- 1, o[ 1 Ground E 0 38 506.4 .4 171

2, 0, 2'^ 1, 0, 1 Ground A 0 38 512.3 .3 171

2, 0, 2<- 1, 0, 1 Ground A 0 38 522.86 .3 171

2, 0, 2<- 1, 1, 1 Ground A 0 8 243.0 .5 171

2, 1, l'^ 1, 1. 0 Ground E 0 39 362.46 .4 171

2, 1, l'^ 1, 1, 0 Ground A 0 39 454.94 .3 171

2, 1, 1^ 1, 1, 0 Ground A 0 39 594.86 .3 171

2, 1, 2<— 1, 1, 1 Ground A 0 37 464.58 .3 171

2, 1, 2<— U L 1 Ground A 0 37 515.24 .3 171

2, I, 2<— 1, 1, 1 Ground E 0 37 687.18 .4 171

3, 0, 3^ 2. 1, 2 Ground A 0 12 015.05 .2 171

3, 0, 3-^ 2, 1, 2 Ground E 0 12 666.62 .4 171

4, 0, 4-^ 3, 1, 3 Ground A 0 32 709.25 .2 171

5] I, 4<- 5' l] 5 Ground A 0 15 968.60 .2 171

5, 1, 4<- 5, 1, 5 Ground E 0 15 988.80 .3 171

6, 1, 5<^ 6, I, 6 Ground E 0 22 326.56 .3 171

6, 1, 5^ 6, L 6 Ground A 0 22 346.18 .2 171

7, 1, 6-^ 7, 1, 7 Ground E 0 29 718.83 .3 171

7, 1, 6<- 7, 1, 7 Ground A 0 29 774.15 .2 171

8, 1, 7*- 1, 8 Ground E 0 38 151.3 .4 171

8, 1, 7-^ 8, 1, 8 Ground A 0 38 241.2 .3 171

11, 2, Q'^ll, 2,10 Ground A 0 12 158.31 .2 171

12, 2,10«-12, 2,11 Ground A 0 16 682.08 .2 171

13, 2,11^^13, 2,12 Ground A 0 22 208.47 .2 171

14, 2,12^14, 2,13 Ground A 0 28 797.83 .2 171 Not Reported Ground 8 723.11 141

Not Reported Ground 12 338.17 141 Not Reported Ground 12 366.25 141 Not Reported 12 381.40 141 Not Reported 12 391.52 141 Not Reported 16 541.75 141

Not Reported 16 551.01 141 Not Reported Ground 16 657.45 141 Not Reported Ground 16 870.93 141 Not Reported Ground 16 913.79 141 Not Reported 17 018.35 141

Not Reported 20 650.80 141 Not Reported 20' 701.5 141 Not Reported 21 640.36 141 Not Reported 21 651.27 141 Not Reported 21 768.25 141

Not Reported 22 087.00 141 Not Reported 22 234.82 141 Not Reported 22 313.79 141 Not Reported 22 464.77 141 Not Reported 22 738.93 141

749-587 0-69— 10 133
Acetaldehyde

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

C'^HjC'^HO"^ 471 Not Reported 22 986.53 141 Not Reported 23 364.79 141 Not Reported 23 553.26 141 Not Reported 23 577.38 141 Not Reported 27 206.96 141

Not Reported 27 214.44 141 Not Reported 27 231.02 141 Not Reported 27 445.4 141 Not Reported 27 526.04 141 Not Reported 27 773.33 141

Not Reported 28 330.59 141 Not Reported 28 788.00 141 Not Reported - 28 789.01 141 Not Reported 28 920.40 141 Not Reported 28 974.95 141

Not Reported 29 077.76 141 Not Reported 29 093.30 141 Not Reported 29 123.5 141 Not Reported 29 396.99 141 Not Reported 29 832. 141

' Not Reported 30 830.61 141 Not Reported 33 312.64 141 Not Reported 34 711.88 141 Not Reported 35 320.94 141 Not Reported 36 489.52 141

Not Reported 36 602.12 141 Not Reported 36 613.28 141 Not Reported 37 291.0 141 Not Reported Ground A 0 37 708.80 .3 171 Not Reported 38 339.24 141

Not Reported 38 833.0 141

C'^DaC'^DO'" 472 1, 0, 1^ 0, 0, 0 Ground A 0 16 109.59 .1 171

1, 0, 1<— 0, 0, 0 Ground A 0 16 116.45 .5 171

i] o\ 1^ I, I, 0 Ground E 0 27 430.55 .4 171

1, 0, 1^ 1, 1, 0 Ground A 0 27 459.13 .2 171

2, 0, 2^ 1, 0, 1 Ground E 0 32 187.05 .1 171

2, 0, 2^ 1, 0, 1 Ground A 0 32 187.52 .1 171

2, 1, 1<— 1, 1, 0 Ground E 0 33 262.94 .1 171

2, l] 1*- 1^ I, 0 Ground A 0 33 264.34 .1 171

2, 1, 2^ 1, 1, 1 Ground A 0 31 171.36 .2 171

2, 0, 2^ 2, 1, 1 Ground E 0 28 506.78 .4 171

2, 0, 2^ 2, 1, 1 Ground A 0 28 536.30 .2 171

3, 0, 3<— 2, 1, 2 Ground A 0 22 808.47 .2 171

3! 0\ 3^ 2^ I, 2 Ground E 0 22 837.22 .4 171

6, 1, 5^ 6, 1, 6 Ground E 0 21 919.74 .3 171

6, 1, 5-^ 6, 1, 6 Ground A 0 21 926.40 .2 171

7, 1, 6^ 7, 1, 7 Ground E 0 29 170.90 .4 171

7, 1, 6<- 7, 1, 7 Ground A 0 29 179.77 .2 171

8, 1, 7<- 8, 1, 8 Ground E 0 37 397.40 .4 1 171

134
Acetaldehyde Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Ace. Ref. No. Quantum Nos. State n F/ F' F, F MHz ±MHz

472 8, 1, 7^ 8, 1, 8 Ground A 0 37 409.18 .3 171

11 9 Q<— 1 1 9 If) 11, Z, V* 11, Z,1U Oround A n IR QAA. Cc: 9 1 7 1 1 i 1 11, 2, 9-^11, 2,10 Ground E 0 18 849.74 .3 171

12, 2,10-«-12, 2,11 Ground A 0 25 228.77 .1 171

12, 2,10^12, 2,11 Ground E 0 25 234.17 .2 171

13, 2,11^13, 2,12 Ground A 0 32 720.26 .1 171

10 9 11 <_i 0 9 19 E 0 .5 171 Not Reported 18 963.78 141 Not Reported 21 819.28 141 Not Reported 22 756.43 141

Not Reported 26 433.48 141

141 Not Reported 26 481.08 141 Not Reported 26 494.55 141 Not Reported 26 666.14 141

Not Reported 26 772.7 141 Not Reported 29 186.9 141 Not Reported 29 221.05 141

s-C'^'H^DC'^'HO's 473 1, 0, 1^ 0, 0, 0 Ground 18 501.87 .1 171

1, u, 1* u, u, u Ground 1 171

1, 0, 1-^ 0, 0, 0 Ground 18 677.30 .2 171

1, 0, 1^ 0, 0, 0 Ground 18 679.28 .2 171

2, 0, 2^^ 1, 0, 1 Ground 36 975. 3. 171

2, 0, 2<r- 1. 0, 1 Ground 36 981.7 .3 171

Z,9 11, 1-^1 1^^ 1, in1, u Ground OOao i«7 lO / .z9 .Oq 171 1 / i 2, 1, 1^ 1, 1, 0 Ground 38 231.25 .5 171

2, 1, 2«- 1, 1, 1 Ground 35 775.8 .3 171

4, 1, 3^ 4, 1, 4 Ground 12 273.5 .3 171

4, 1, 3^ 4, 1, 4 Ground 12 660.45 .2 171

O, 1, T*^ O, 1, o

1 _T*^M 1 n /I V7l UUIIU 18lO 4,09 'tO^.'tU 4,n .3 171

5, 1, 4^ 5, 1, 5 Ground 18 594.39 .2 171

6, 1, 5-^ 6, 1, 6 Ground 25 748.55 .3 171

6, 1, 5<- 6, 1, 6 Ground 25 889.3 .5 171

6, 1, 5^ 6, 1, 6 Ground 25 917.11 .2 171 Not Reported 1 9 7()f\ 9^1 14.1 I'll Not Reported 16 938.2 141 Not Reported 17 234.91 141 Not Reported 17 263.05 141

Not Reported 17 777.2 141 Not Reported 11 7/ Rf\Si oOo.o» 114'1 41 Not Reported 18 991.57 141 Not Reported 22 978. 141 Not Reported 25 724.83 141

Not Reported 26 105.14 141 Not Reported 28 571.69 141 Not Reported 28 586.2 141 Not Reported 29 467.7 141 Not Reported 29 550.43 141

135
Acetaldehyde Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

474 1, 0 1-^ 0, 0, 0 Ground A 0 16 407.00 .2 171

2, 0, 2^ 1, 0, 1 Ground E 0 ^9 7QQ QQ A 1/1

2, 0, 2<- 1, 0, 1 Ground A 0 32 801.27 .2 171

o

z.

r\

>J, 1, 1 Ground A 0 32 854.7 171

2, 1, 1<- 1, 0, 1 Ground A 0 33 587.42 .2 171

2, 1, 1^ 1, 1, 0 Ground E 0 33 577.06 .4 171

2, 1, 2«- 1, 1, 1 Ground A 0

1

. i 1/1

2, 1, 2^ 1, 1, 1 Ground E 0 32 0.50.00 2. 171

/

' 4, 1, A

U, Ground E 0 37 527.60 .5 171

4, 1, 3*- 4, 0, 4 Ground A 0 37 626.28 .3 171

5, 1, 4^ 5, 0, 5 Ground E 0 39 664.22 .5 171

5, 1, 4^ 5, 0, 5 V^l OUllU A 0 07 (UO.'tU 0 11/171

6, 1, 5<- 6, 1, 6 Ground E 0 16 208.84 .5 171

£.O,11, 5^ 6,11

,

o Ground A 0 16 224.33 .3 171

7, 1, 6^ 7, 1, 7 Ground E 0 21 596.15 .4 171

7, 1, 6^ 7, 1, 7 Ground A 0 21 616.82 .2 171

8, 1, 7<- 8, 1, 8 Ground E 0

A 1 71 1 i i 8, 1, 7^ 8, 1, 8 Ground AA nU 27 762.42 .2 171

13, 2, 11-^13, 2, 12 Ground A 0 16 433.52 .3 171

13, 2 11^13. 2, 12 Ground E 0 If:, 4.4,9 OA c

.o

14, 2, 12^14, 2, 13 Ground A 0 21 292.13 .3 171

14, 2 12^ 14, 2, 13 Ground E 0 21 303.65 .4 171

s-C'^HDzC'^HO'" 475 1, 0 1^ 0, 0, 0 Ground 16 953.90 .2 171

1, 0 1^ 0, 0, 0 Ground 1 fi Qon fid. .z 171

1, 0, 1^ 0, 0, 0 Ground 17 056.65 .3 171

2, 1 2^ 1, 1, 1 Ground 33 302.30 .3 171

7, 1 6^ 7, 1, 7 Ground - ID VZD.oD .Z9 171 1/1

Qo.

11 7^ 8, 1 Qo Ground 21 752.05 .2 171

9, 1, 8«- 9, 1, 9 Ground 21 170.68 .2 171

C'^HsC'^HO 476 1, 0, 1^ 0, 0, 0 Ground E 0 18 703.69 .1 171

1, 0, 1^ 0, 0, 0 VTl OUllU A 0 1 8 706 46 1 171

2, 0, 2^ 1, 0, 1 Ground E 0 37 391.12 .2 171 n 2<- 1, t Ground A 0 37 396.36 .2 171

2, 0, 2^ 1, 1, 1 Ground A 0 9 513.06 .2 171

2, 1, 1<- 1, 1, 0 Ground E 0 38 186.94 .3 171

2, 1, 1^ 1, 1, 0 Ground A u ooQQ Aon ^^yj.oxj ^ft \ 1 71

- 2, 1, 2-<- 1, 1, 1 Ground A 0 36 402.86 .3 171

2, 1, 2<r- 1, 1, 1 Ground E 0 .5 171

3, 0, 3^ 2, 1, 2 Ground A 0 10 146.83 .2 171

4, 0, 4^ 3, 1, 3 Ground A 0 30 216.05 .2 171

C'^HjC'^HO'" 477 1, 0, 1^ 0, 0, 0 Ground E 0 19 229.94 .2 171

1, 0, 1^ 0, 0, 0 Ground A 0 1 Q 9^9 .o 111171

2, 0, 2<^ 1, 0, 1 Ground E 0 38 439.56 .2 171

2, 0, 2*- 1, 0, 1 Ground A 0 38 445.38 .2 171

2, 1, 1^ 1, 1, 0 Ground E 0 39 343.4 .5 171

2, 1, 1^ 1, 1, 0 Ground A 0 39 557.00 .3 171

2, 1, 2*- 1, 1, 1 Ground A 0 37 370.9 .2 171

2, 1, 2-^ 1, 1, 1 Ground E 0 37 574.6 1. 171

136
Acetaldehyde Spectral Line Table

Isotopic Species Id. No.

a-C''H,DC'2H0'«

a-C'2HD,C"H0"'

477

478

479

481

482

Rotational Quantum Nos.

Vib. State Int. Rotor

State n

1 f; nlype

F'

rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

3, 0, 3*- 2, 1, 2 Ground A 0 13 039.14 .2 171

4', U, 4-* a, i. Jo Ground A 0 33 725. 1. 171

1, U, i* VJ, u, nu Ground E 0 18 670.03 .3 171

1i, nU, 11*< nou, u. Ground A 0 18 672.20 .2 171

2, 0, 2^ 1, 0, 1 Ground E 0 37 322.20 .2 171

2, 0, 2^ 1, 0, 1 Ground A 0 37 326.98 .2 171

9 1 1 «— 1 1 Q Ground E 0 38 164.5 .4 171

9 1 1 «— 1 1 0 Ground A 0 38 378.82 .2 171

9 1 9«— 1 1 \ Ground A 0 36 309.26 .3 171

2, 1, 2-^ 1, 1, 1 Ground E 0 36 515.58 .2 171

3, 0, 3<- 2, 1, 2 Ground A 0 11 167.75 .2 171 ^ Q 3^ 3 Ground A 0 31 229.94 .2 171

1, 0, 1^ 0, 0, 0 Ground E 0 18 367.75 .5 171

1, 0, 1*- 0, 0, 0 Ground A 0 18 370.23 .5 171

2 0 2«— 1 0 Ground E 0 36 719.90 .4 171

2 0 2*— 1 0 Ground A 0 36 725.26 .4 171

2 1 1<— 1 1 0 Ground A 0 37 724.4 1. 171

5, 1, 4^ 5, 1, 5 Ground A 0 14 772.90 .3 171

6, 1, 5<- 6, 1, 6 Ground A 0 20 674.05 .2 171

7 1 6<— 7, 1, 7 Ground A 0 27 547.7 .5 171

J Q Q Q 0 Ground 18 001.96 .2 171

2 Q Q Q 0 Ground 18 005.15 .2 171

li o' 1^ 0, 0, 0 Ground 18 043.35 .3 171

1, 0, 1^ 0, 0, 0 Ground 18 263.51 .3 171

1i, nU, 1 <— nVJ, nw. 0 Ground 18 350.10 .3 171

2 0 2*— 1 0 \ Ground 35 989.85 .3 171

9 n 9<— 1 rt \ Ground 35 991.70 .3 171

2, 1, 1^ 1, 1, 0 Ground 36 799. 3. 171

2, 1, 2^ 1, 1, 1 Ground 35 206.37 .5 171

9 1 9«— 1 1 \ Ground 35 321.1 .5 171

5, 1, 4^ 5. 1. 5 Ground 12 319.72 .3 171

5, 1. 4^ 5, 1, 5 Ground 12 339.69 .2 171

0, 1, O, 1, o Ground 17 234.91 .3 171

O, 1, 0* O, 1, u Ground 17 263.05 .2 171

7 1 7 T 7 Ground 22 964.06 .2 171

7, 1, 6^ 7, 1, 7 Ground 23 000.94 .2 171

8, 1, 7^ 8, 1, 8 Ground 29 500.67 .2 171

O, 1, O, 1, QO Ground 29 548.31 .2 171

i, U, 1* u, u, 0u Ground 17 363.35 .2 171

1 n 1 < on Ground 17 387.12 .3 171

2, 0, 2^ 1, 0, 1 Ground 34 706.02 .2 171

2, 0, 2^ 1, 0, 1 Ground 34 707.32 .2 171

2 1 1«— 1 1, 0 Ground 35 711.86 .3 171

2, 1, 2^^ 1, 1, 1 Ground 33 741.3 .5 171

5, 1, 4^ 5, 1, 5 Ground 14 827.5 .3 171

5, 1, 4-^ 5, 1, 5 Ground 14 839.05 .3 171

6, 1, 5^ 6, 1, 6 Ground 20 746.48 .2 171

6, 1, 5^ 6, 1, 6 Ground 20 761.20 .2 171

7, 1, 6*- 7, 1, 7 Ground 27 634.90 .5 171

7. 1, 6^ 7. 1. 7 Ground 27 655.01 .2 171

137
490 - Acetic Acid

Ethanoic Acid

Molecular Constant Table

C,(C3v,Cs,Cs) CH3COOH

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) Dj K A

C'2H3C'20"=0'«H Cs 491 11 073. M 9 056. M 4 864. M

C'2D3C'20'<*0'«H Cs

. . .

.

492

Id. No. /u,a Debye jXb Debye /Lie Debye eQq V3 Acc. Ired OJa d cOb d (Ue d coji d

. 491

492

1.74 T 0. X 496

467

References: ABC: 145 Dj: Djk: k: A:

Im: 393 eQq: V: 193 I: to: Add. Ref.: 75

Rotational constants for the excited state: A= 11139 MHz. 3=9110 MHz, and C = 4868 MHz. Ref: 145.

f

138
Acetic Acid Spectral Line Table

Isotopic Species Id. Rotational Vib State Int. Rotor Hyperfine Acc. Ref. Quantum Nos. State n F' rF' r MHz ±MHz

C'2H3C'20"^0'«H 491 1 , 1, 1<— 0, 0, 0 Ground Ei Ayj 16 418.82 .4 193

1 , 1, I*— u, u, 0 Ground A

u 16 741.72 .4 193

2 , 0, 2<- 1, 0, Grou nd ZO ao. 14S

2 , 0, 2*- 1, 0, J EjXcitcd ZO9'i 171 ill. ao. 14S

0z Z< 1, 1, I

r* vr*! tori Z.J iOO. a

0. 14S 140

z Z* 1, 1, 1 Ground A

j\ u 24 920.64 .4 193

oz n Z* 1, 1, 1 Ground Hi 0u 25 156.42 .4 193

2 , 1, 2^ 1, 0, 1 25 742. 3. 145

2 , 1, 2^^ 1, 0, 1

1y^iwTTii 1 n rl (J LI iiLi yj 4 IQ^ 1 yo

o 1

1 9rf "1 A

Z* 1, u. J VtI uu IIU A 0 Z971 O^Q4^'T. 19IZ .TP4 IQ^

OZ1

, 1,

9^^ 1 1 Z* 1, i, 1 Ground 23 648. 3. 145

1

» 9^ 1 Z* 1 1, i. 1 Excited 23 713. 3. 145

2 1, 1-^ 2, 0, 2 (V 7 Tct 1

1U1 n1 lUH 1 2 989 83 382

2 » 2, 1"^ 2, 1, 2 1 > TAi 1 n rl \ 7 I U li i 1(J 18 625. 3. 145

9 9z. Z, I, 2 JLJ I V_, t_J 18 814. 3. 145

QO

1 Z* o, U, 3 Ground 23 540.87 382

0 9 1* O, 1, 2 Ground 0 12 398.58 .4 193

3 3, 0-^ 3, 2, 1VT1>rm1^ UI n1 lUH 1 9 984 48 382

4 2, 2<- 4, 1, 3 1 . rn linn 21 463..58 382

Q 1* 'f, z. 2 1 . m1 1 n H 1 3 381 7Q 382

5

o

z. o«— O, 1, 4 Ground 33 021.39 382

5 4, 1<— 0, 3, 2 Ground A

/\ Au 16 539.43 .4 193

5 4, 2^ 5, 3, ao Ground Z790 071.U0 ^Ql fift ooz ^R9

6 3, 3^ 6, 2, 4 Ground OO^fl OZ1^911 .4-0 4f> ooz ^R9

6 4, 2<— 6, 3, 0 Ground IQ Qn7 7Q Ooz ^H9

6 5, 1*— 6, 4, 2 Ground A A

u 22 082.56 .4 193

7 4, 3*— 7, 3, 4 Ground 27 525.60 382

7 5, 2<^ 7, 4, ao Ground 90 ^'^7 H4 ooz ^89

7 6, 1^ 7, 5, z Ground A A

u Z79Q =^99 ^^7 OZZ.O J 4 IQ^ 1 70

8 5, 4. Ground Z<J Zt-U.^U ooz ^R9

8 5, o, o. 4 Ground 20 209.32 382

8 6, 9rf Q C Z< o, D, 3 Ground 24 587.82 382

9 6, 3^ 9, 5, 4 0 24 949 SI 4 193

9 6, 3^ 9, 6, 4 i mil n ri 14 577 35 382

10 7, lu, o, 4 Ground 27 444.98 382

Not ixeporteQ 22 324. 3. 145 Not Reported 22 356. 3. 145 Not Reported 22 542. 3. 145 Not Reported 22 583. 3. 145 Not Reported 22 616. 3. 145

Not i\eporteci 22 681. 3. 145 Not Reported 22 827. 3. 145 Not Reported 22 943. 3. 145 Not Reported 22 968. 3. 145 Not Reported 23 042. 3. 145

Not Reported 23 179. 3. 145 Not Reported 23 317. 3. 145 Not Reported 23 405. 3. 145 Not Reported 23 422. 3. 145 Not Reported 23 426. 3. 145

139
Acetic Acid

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frecjuency Acc. Ref. No. Quantum Nos. State n F' Y' p MHz ±MHz

C'2H3C'^0'«0"^H 491 Not Reported 23 429. 3. 145 Not Reported 23 471. 3. 145 Not Reported 23 574. 3. 145 Not Reported 23 623. 3. 145 Not Reported 23 703. 3. 145

Not Reported 23 717. 3. 145 Not Reported 23 809. 3. 145 Not Reported 23 813. 3. 145 Not Reported 23 819. 3. 145 Not Reported 23 966. 3. 145

Not Reported 24 132. 3. 145 Not Reported 24 208. 3. 145 Not Reported

- 24 298. 3. 145 Not Reported 24 334. 3. 145 Not Reported 24 340. 3. 145

Not Reported 24 385. 3. 145 Not Reported 24 456. 3. 145 Not Reported 24 968. 3. 145 Not Reported 25 083. 3. 145 Not Reported 25 320. 3. 145

Not Reported 25 327. 3. 145 Not Reported 25 339. 3. 145 Not Reported 25 506. 3. 145

492 1, 1, 1^ 0, 0, 0 E 0 15 329.70 .4 193

1, 1, 1^ 0, 0. 0 A 0 15 364.93 .4 193

2, 0, 2<— 1, 1, 1 A 0 20 964.23 .4 193

2' 0^ 2<— L h 1 E 0 20 992.55 .4 193

2, 1, 2«— 1, 0, 1 E 0 24 871.11 .4 193

2, 1, 2^ 1, 0, 1 A 0 24 902.31 .4 193

2, 1, 2^ 3, 0, 3 Ground 32 068.90 382

2, 1, 2^^ 3, 0, 3 Ground 32 076.50 382

3, 1, 3^^ 2, 0, 2 E 0 33 596.36 .4 193

s] 1, 3-^ 2, 0, 2 A 0 33 621.42 .4 193

6, 4, 2*- 6, 3, 3 Ground 19 495.85 382

7, 3, 4^ 7. 2, 5 Ground 30 800.79 382

7, 4, 3<— 7, 3, 4 Ground 20 773.23 382

7! 5! 2^ 7^ 4^ 3 Ground 26 773.22 382

Q A A 4. Q 0 0, 0, 0, D Ground 26 870.71 382

9, 5, 4«- 9, 4, 5 Ground 25 422.18 382

11. 6, 5^11. 5, 6 Ground 30 008.04 382

140
500 - Methyl Formate

Methyl Methanoate

Molecular Constant Table

Q(Cs,Cs,C3v) HCOOCH3

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) Dj DjK K A

HC'20"'0"'C'^H3-A Cs 501 19 985.71 M 6 914.63 M 5 304.47 M

HC'^0"^0"'C'^H3-E Cs 502 19 980.47 M 6 913.57 M 5 304.47 M

503 18 479.14 M 6 768.88 M 5 109.74 M

DC'^0"'0"'C'^H3-E 504 18 474.52 M 6 768.05 M 5 109.74 M

s-HC'^0"^0"*C'^H2D-A 505 19 921.53 M 6 415.20 M 5 004.33 M

a-HC'^0"^0"'C'^H2D c, 506 18 517.36 M 6 729.88 M 5 165.06 M

HC''^0"'0"'C'^D3-A 507 17 261.81 M 6 101.92 M 4 778.01 M

HC'^0"'0'*'C'^H3-A Cs 508 19 802.81 M 6 865.29 M 5 262.63 M

HC'20"'0"*C'2H3-E Cs 509 19 798.20 M 6 864.24 M 5 262.63 M

HCi2oi60'sc"H3-A Cs 511 19 769.19 M 6 743.18 M 5 188.19 M

HC'^0'W«C"H3-E Cs 512 19 764.12 M 6 742.22 M 5 188.32 M

HC'^O'sO'^C'^Hj-A Cs 513 19 529.40 M 6 617.77 M 5 097.36 M

HC>20"*0'«C'2H3-E Cs 514 19 525.20 M 6 616.72 M 5 097.36 M

HC'20"'0'»C'2H3-A Cs 515 19 326.61 M 6 849.43 M 5 219.01 M

HC12016018C>2H3-E Cs 516 19 322.21 M 6 848.42 M 5 219.01 M

Id. No. fi^ Debye /Xb Debye /Li(. Debye eQq Va Acc. Ired OJa d (Oh d d <xia d

501

507

1.63 M

1.60 M

0.68 M

0.76 M

0. X

0. X

1190 40

References: ABC: 239 Dj: Djk: k: A:

/i: 239 eQq: V: 239 I: w:

Coupling parameter: Ia=3.21 amu A-. Ref; 239.

141
Methyl Formate

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.' No. Quantum Nos. State n f; F' F MHz ±MHz

JJ(^120160>6C'2H3-A 501 1, 0, 1«- 0, 0, 0 Ground A 0 12 219.29 .2 239

1, 1, 0^ 1, 0, 1 Ground A 0 14 681.13 .2 239

2, 0, 2<- 1, 0, 1 Ground A 0 24 298.40 .2 239

- 2, 1, 1^ 1, 1, 0 Ground A 0 26 048.35 .2 239

2, 1. 2^ 1, 1, 1 Ground A 0 22 827.91 .2 239

2, 1, 1*- 2, 0, 2 Ground A 0 16 431.54 .2 239

3, 1, 2<- 3, 0, 3 Ground A 0 19 307.57 .2 239

3, 1, 2^ 3, 1, 3 Ground A 0 9 653.41 .35 239

4, 1, 3<— 4, 0, 4 Ground A 0 23 562.38 .2 239

4, 1, 3*— 4, 1, 4 Ground A 0 16 047.96 .35 239

5, 1, 4*- 5, 0, 5 Ground A 0 29 417.37 .2 239

5, 1, 4<— 5, 1, 5 Ground A 0 23 939.81 .35 239

6, 2, 4<— 6, 2, 5 Ground A 0 8 577.35 .35 239

7, 2, 5^ 7, 2, 6 Ground A 0 14 279.19 .35 239

8, 2, 6^ 8, 2, 7 Ground A 0 21 680.87 .35 239

HC'20'*'0"'C'^H3-E 502 1, 0, 1<— 0, 0, 0 Ground E 0 12 218.21 .2 239

1, 1, O'^ 1, 0, 1 Ground E 0 14 676.59 .2 239

2, 0, 2'«— 1, 0, 1 Ground E 0 24 296.60 .2 239

2, 1, 1<— 1, 1, 0 Ground E 0 26 044.80 .2 239

2, 1, 1^ 2, 0, 2 Ground E 0 16 425.54 .2 239

3, 1, 2^^ 3, 0, 3 Ground E 0 19 298.88 .2 239 - 3, 1, 2<— 3, 1, 3 Ground E 0 9 647.10 .35 239

4, 1, 3<- 4, 0, 4 Ground E 0 23 550.84 .2 239

4, 1, 3^^ 4, 1, 4 Ground E 0 16 037.23 .35 239

5, 1, 4^ 5, 0, 5 Ground E 0 29 401.50 .2 239

5, 1, 4-^ 5, 1, 5 Ground E 0 23 923.07 .35 239

6, 2, 4<- 6, 2, 5 Ground E 0 8 571.07 .35 239

7, 2, 5-^ 7, 2, 6 Ground E 0 14 267.17 .35 239

8, 2, 6<- 8, 2, 7 Ground E 0 21 663.10 .35 239

DC'^0"'0"^C'2H3-A 503 1, 0, 1«- 0, 0, 0 Ground A 0 11 878.80 .2 239

1, 1, 0^ 1, 0, 1 Ground A 0 13 369.38 .35 239

2, 0, 2^ 1, 0, 1 Ground A 0 23 593.08 .2 239

2, 1, 1^ 1, 1, 0 Ground A 0 25 416.57 .2 239

2! I, 2«— 1, 1! 1 Ground A 0 22 097.89 .2 239

2, 1, 1* 0, 2 Ground A 0 15 192.82 .35 239

3, 1, 2^ 3, 0, 3 Ground A 0 18 219.75 .2 239

3, 1^ 2^ 3, 3 Ground A 0 9 945.74 .2 239

4! I, 3-^ 4, 0! 4 Ground A 0 22 730.32 .2 239

5, 1, 4^ 5, 0, 5 Ground A 0 28 936.10 .2 239

5, 1, 4^ 5, 1, 5 Ground A 0 24 605.93 .35 239

6, 2, 4^ 6, 2, 5 Ground A 0 9 762.83 .35 239

7, 2, 5^ 7, 2, 6 Ground A 0 16 035.33 .35 239

s! 2! 6^ 8, 2! 7 Ground A 0 24 027.98 .35 239

DC12QI6016C12H3-E 504 1, 0, 1^ 0, 0, 0 Ground E 0 11 877.95 .2 239

1, 1, 0^ 1, 0, 1 Ground IT£j n

u 13 365.18 .35 239

2, 0, 2^ 1, 0, 1 Ground E 0 23 591.48 .2 239

2, 1, 1^ 1, 1, 0 Ground E 0 2 239 '

2, 1, 1^ 2, 0, 2 Ground E 0 15 187.25 .2 239

3, 1, 2^ 3, 0, 3 Ground E 0 18 212.03 .2 239

142
Methyl Formate Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F.' F' F, F MHz ±MHz

DC'20"=0'«C'2H3-E 504 3, 1, 2*— 3, 1, 3 Ground E 0 9 939.98 .2 239

4, 1, 3-^ 4, 0, 4 1 . rrti 1 n rl E 0 99 71 Q Aft 2 239

5, 1, 4^ 5, 0, 5 Ground rtj A

U 29 921.44 .2 239

5, 1, 4^ 5, 1, 5 Ground E 0 24 591.85 .35 239

6, 2, 4^ 6, 2, 5 1 aroi I n H E 0 9 756.44 .35 239

7, 2, 5*— 7, 2, 6 Ground E 0 16 024.25 .35 239

8, 2, 6^ 8, 2, 7 Ground E 0 24 011.56 .35 239

s-HC'='0"'0'«C'^H2D-A 505 1, 0, 1^ 0, 0, 0 Ground A 0 11 419.54 .2 239

1, 1, 0^ 1, 0, I 1 wTAi 1 n ri (J UJIU A 0 .35 9^Q

2, 0, 2<— 1, 0, 1 Ground A 0 22 733.95 .2 239

2, 1, 1*- 1, 1, 0 Ground A 0 24 250.27 .35 239

2, 1, 2^ 1, 1, 1 Ground AA u 21 427.79 .2 239

2, 1, 1^ 2, 0, 2 1VtI U UllU 1 n A 0 2 coy 9^Q

3, 1, 2^ 3, 0, 3 Ground A 0 18 896.82 .2 239

4, 1, 3*— 4, 0, 4 Ground A 0 22 508.77 .35 239

5, 1, 4*- 5, 0, 5 Ground A 0 27 466.07 .2 239

aHC'20'«0"'C'2H2D 506 1, 0, 1-^ 0, 0, 0 Ground A 0 11 895.09 .2 239

1, 1, 0*- 1, 0, 2 (V7lwiTti U lillU 1 n H A 0 1 ^ ^51 99 .35 239

2, 0, 2*— 1, 0, 1 Ground A 0 23 644.75 .2 239

2, 1, 1^ 1, 1, 0 Ground A 0 25 354.60 .2 239

2, 1, 2^ 1, 1, 1 Ground AA u 22 225.13 .2 239

2, 1, 1^ 2, 0, 2 E 0 1 5 061 90 2 239

2, 1, 1^ 2, 0, 2 Ground A 0 15 063.28 .2 239

r 11, 4*— o, U, 5 Ground A 0 27 864.67 .2 239

5, 1, 4^^ 5, 0, 5 Ground A 0 27 868.96 .2 239

HC'20"'0"'C'2D3-A 507 1, 0, 1^ 0. 0, 0 Ground A 0 10 879.95 .2 239

1, 1, 1-^ 0, 0, 0 ( » m1 1 n H A 0 22 039 23 .35 239

2, 0, 2-^ 1, 0, 1 Ground A 0 21 648.80 .2 239

o

z. 1, 1*— 1, 1, 0 Ground A 0 23 083.86 .2 239

2, 1, 2<- 1, 1, 1 Ground A 0 20 435.80 .2 239

2, 1, 1^ 2, 0, 2 Ground A 0 13 918.67 .2 239

o*— z, 1, 2 A 0 22 254 27 .35 239

3, 1, 2^ 3, 0, 3 Ground A 0 16 270.80 .2 239

4, 1, 3^ 4, 0, 4 Ground A nu 19 744.04 .2 239

4, 1, 3-^ 4, 1, 4 Ground A 0 13 199.17 .35 239

5, 1, 4-^ 5, 0, 5 Ground A 0 24 521.48 .2 239

r 11, 4* o, 1, 5 Ground A 0 19 697.49 .35 239

7, 2, 5^ 7. 2, 6 Ground A 0 11 461.77 .35 239

HC'30"'0"'C'2H3-A 508 1, 0, 1^ 0, 0, 0 Ground A 0 12 127.96 .2 239

2, 0, 2->- 1, 0, 1 -wrni 1 n H A 0 24 115.85 .2 239

2, 1, 1^ 1, 1, 0 Ground A 0 25 858.48 .2 239

2, 1, 2-^ 1, 1, 1 Ground A 0 22 653.03 .2 239

2, 1, 1-^ 2, 0, 2 Ground A 0 16 282.62 .35 239

3, 1, 2<- 3, 0, 3 Ground A 0 19 147.85 .2 239

4, 1, 3^ 4, 0, 4 Ground A 0 23 388.31 .2 239

5, 1, 4^ 5, 0, 5 Ground A 0 29 223.59 .2 239

143
Methyl Formate

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

HC'^O'^O'^C'^Ha-E 509 1^ 0, I'*— 0, 0, 0 Ground E 0 12 127.05 .2 239

2! 0, 2<- I, 0! 1 Ground E 0 24 114.02 .2 239

2, 1. 1^ 1, 1, 0 Ground E 0 25 854.88 .2 239

2, 1, 1^ 2, 0, 2 Ground E 0 16 276.50 .35 239

3, 1, 2^ 3, 0, 3 Ground E 0 19 139.68 .2 239

4, 1, 3*- 4, 0, 4 Ground E 0 23 376.87 .2 239

s. I, 4^ 5^

0' 5 Ground E 0 29 208.06 .2 239 HC'^O'^O'^CHa-A 511 1, 0, 1^ 0, 0, 0 Ground A 0 11 930.69 .2 239

2, 0, 2<^ 1, 0, 1 Ground A 0 23 731.54 .2 239

2' 1' 1^ 1, 1, 0 Ground A .0 25 417.99 .2 239

2, 1, 2^ 1. 1, 1 Ground A 0 22 307.45 .2 239

2, 1, 1«- 2, 0, 2 Ground A 0 16 266.40 .35 239

3, 1, 2^ 3. 0, 3 Ground A 0 19 032.18 .2 239

4, 1, 3^ 4, 0, 4 Ground A 0 23 116.71 .2 239

5'

1, 4^ 5' 0' 5 Ground A 0 28 735.17 .2 239

HC'^0"*0"^C'^H3-E 512 2, 0, 2^ 1, 0, 1 Ground E 0 23 729.67 .2 239

2, 1, 1^ 1. 1, 0 Ground E 0 25 414.42 .2 239

2, 1, 1^ 2, 0, 2 Ground E 0 16 260.44 .35 239

3, 1, 2*- 3, 0, 3 Ground E 0 19 024.13 .2 239

4, 1, 3^ 4, 0, 4 Ground E 0 23 105.61 .2 239

5, 1, 4^ 5, 0, 5 Ground E 0 28 720.05 .2 239

HC'20"'0"*C'2H3-A 513 1, 0, 1^ 0, 0. 0 Ground A 0 11 714.45 .2 239

2 0 2<— 1 0 1 Ground A 0 23 303.55 .2 239

2'

I, 1^ I, I, 0 Ground A 0 24 950.66 .2 239

2, 1, 2^ 1, 1, 1 Ground A 0 21 909.38 .2 239

2, 1, 1^ 2, 0, 2 Ground A 0 16 078.66 .35 239

3, 1, 2^ 3, 0, 3 Ground A 0 18 777.42 .2 239

4, 3<— 4, 0, 4 Ground A 0 22 760.03 .2 239

5! 1, 4^ 5^ 0! 5 Ground A 0 28 238.31 .2 239

HC'^O'^C'C'^Ha-E 514 2, 0, 2^ 1, 0, 1 Ground E 0 23 301.71 .2 239

2, 1, 1^ 1, 1, 0 Ground E 0 24 947.31 .2 239

2, 1, 1^ 2, 0, 2 Ground E 0 16 073.13 .35 239

3, 1, 2^ 3, 0, 3 Ground E 0 18 770.0 .35 239

4, 1, 3^ 4, 0, 4 Ground E 0 22 749.66 .2 239

5, 1, 4^ 5, 0. 5 Ground E 0 28 223.58 .35 239

HC'-O'^O'^C'^Hj-A 515 1, 0, 1^ 0, 0, 0 Ground A 0 12 068.35 .2 239

2 0, 2<— 1 0, 1 Ground A 0 23 987.49 .2 239

2!

1' 1^ 1! 1, 0 Ground A 0 25 767.30 .35 239

2, 1, 2<- 1, 1, 1 Ground A 0 22 506.30 .2 239

2, 1, 1^ 2, 0, 2 Ground A 0 15 887.28 .35 239

3, 1, 2^ 3, 0, 3 Ground A 0 18 825.46 .2 239

4, 1, 3^ 4, 0, 4 Ground A 0 23 185.78 .2 239

5, 1, 4^ 5, 0, 5 Ground A 0 29 187.25 .2 239

HC''^0"*0"*C'^H3-E 516 2, 0. 2^ 1, 0, 1 Ground E 0 23 985.67 .2 239

2, 1, 1^ 1, 1, 0 Ground E 0 25 764.42 .35 239

2, 1, 1<- 2, 0, 2 Ground E 0 15 881.96 .35 239

3, 1, 2^ 3, 0, 3 Ground E 0 18 818.13 .35 239

4, 1, 3^ 4, 0, 4 Ground E 0 23 174.82 .2 239

5, 1, 4^ 5, 0, 5 Ground E 0 29 171.96 .2 239

144
520 - Bromoethane Molecular Constant Table

Ethyl Bromide

CjHjBr Cs(C3v,Cs) CHsCH^Br

Isotopic Species Pt. Op.

Id. Mr. INO. A (MHz) B(MHz) C (MHz) Dj DjK K A

L HsC rl2Dr"' Cs ozl 29 956.15 M 3 803.89 M 3 522.93 M —.youo 1 /I Q

DZZ 29 947.74 M 3 781.04 M 3 503.18 M QAQ7

L, U^L^ n.2Dr 24 664.76 M 3 297.80 M 3 076.22 M

l> 1131^ U2t>r n 23 213.50 M 3 675.63 M 3 373.57 M

C U3t> rljDr OZO 24 658.36 M 3 276.93 M 3 057.95 M

C9A DZO 23 207.08 M 3 652.69 M 3 354.07 M

C'^HjC'^HzBr^'' Cs 527 29 147.7 M 3 765.51 M 3 478.75 M

C^HsC'^HjBr" Cs 528 29 665.0 M 3 669.97 M 3 403.97 M

C'^HjCm^Br*' Cs 529 29 124.7 M 3 742.39 M 3 458.83 M

C'^H3C'2H2Br'" 531 29 659.1 M 3 647.37 M 3 384.41 M

i

Id. No. /Aa Debye ^ib Debye ^JL^. Debye eQq V Ace.

' ^red CDa d (Ub d d

521

522

2.03 T 0. X 537.5

450.9

3567 30 5.11

References: ABC: 361 Dj: Djk: k: 197 A: 253

M: 393 eQq: 197 V: 253 I: 124

I Add. Refs.: 50. 269

Torsional frequency = 202 cm"'. Ref: 197.

145
Bromoethane

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f;

Jlype F'

rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

C'^HjC'^H^Br^'* 521 3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 21 966.25 .05 361

3, 0, 3^ 2, 0, 2 Ground 111 o/z oi cam oc zl yo6.z6 .05 361

3, 0, 3^ 2, 0, 2 Ground 21 972.6 124

3, 0, 3<— 2, 0, 2 Ground 3/2 1/2 21 991.60 .05 361

3, 0, 3^ 2, 0, 2 Ground 5/2 3/2 21 992.44 .05 361

3, 1, 2-^ 2, 1, 1 Ground 3/2 1/2 22 386.74 .05 361

3, 1, 2^ 2, 1, 1 Ground y/z 7 /O 7/2 OO OOO 1 o zz 3oo.l3 .05 361

3, 1, 2^ 2, 1, 1 Ground 5/2 3/2 22 409.10 .05 361

3, 1, 2*— 2, 1, 1 Ground 7/2 5/2 22 415.50 .05 361

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 21 545.67 .05 361

3, 1, 3^ 2, 1, 2 Ground 3/2 1/2 21 550.04 .05 361

3, 1, 3*- 2, 1, 2 Ground Ol C C7 O Zl OD /.Z 197

3, 1, 3^ 2, 1, 2 Ground 7/2 5/2 21 571.56 .05 361

3, 1, 3<— Z, 1, 2 Ground 5/2 3/2 21 576.45 .05 361

3, 2, 1^ 2, 2, 0 Ground 3/2 1/2 21 885.70 197

3, 2, 1^ 2. 2, 0 Ground E 1 9/2 7/2 21 903.41 .10 253

3, 2, 1^ 2, 2, 0 Ground A 1 y/z 7 /O //Z 1 o .lU oczoo

3, 2, 1^ 2, 2, 0 Ground 9/2 7/2 21 959.77 197

3, Z, Z, I) Ground 21 989.7 197

3, 2, 1^ 2, 2, 0 Ground 5/2 3/2 21 990.15 197

3, 2, 1^ 2, 2, 0 Ground E \ 7/2 5/2 22 007.57 .10 253

3, 2, 1^ 2, 2, 0 Ground A \ 7 /O '/z D/Z ZZ uuy.oU .10 OCQ

3, 2, 1«- 2, 2, 0 Ground 7/2 5/2 22 064.16 197

3, 2, 2<— 2, 2, 1 Ground 3/2 1/2 21 876.90 197

3, 2, 2^ 2, 2, 1 Ground A 9/2 7/2 21 896.58 .10 253

3, 2, 2<- 2, 2, 1 Ground E \ 9/2 7/2 21 898.43 .10 253

3, 2, 2^ 2, 2, 1 Ground o/o y/z n /o

11

1

Ol OCT OO Zl yoi.zu 197

3, 2, 2-^ 2, 2, 1 Ground 21 981.1 197

3, 2, 2<— 2, 2, 1 Ground 5/2 312 21 981.20 197

3, 2, 2-^ 2, 2, 1 Ground A 7/2 5/2 22 001.05 .10 253

3, 2, 2-^ 2, 2, 1 Ground E \ 7/2 5/2 22 002.99 .01 253

3, 2, 2^ 2, 2, 1 Ground 7 /O 7/2 o/z OO OC C ZZ 055.60 197

4, 1, 4^ 3, 1, 3 Ground 11/2 9/2 28 733.50 197

4, 1. 4^ 3, 1, 3 Ground 28 740.1 197

4, 1, 4^ 3, 1, 3 Ground 5/2 3/2 28 740.80 197

4, 1, 4^ 3, 1, 3 Ground 9/2 7/2 28 743.80 197

4, 1, 4^ 3, 1, 3 Ground '/z OIL OQ 7C1 AA Zo (Ol.UU 1 Q7

4, 2, 2^ 3, 2, 1 Ground E 1 7/2 5/2 29 265.88 .01 253

4, 2, i*^ 3, Z, 1 Ground AA 1 7/2 5/2 29 266.88 .01 253

4, 2, 3^ 3, 2, 2 Ground A 1 11/2 9/2 29 217.71 .01 253

4, 2, 3-^ 3, 2, 2 Ground E 1 11/2 9/2 29 218.71 .01 253

4, 2, 3^ 3, 2, 2 Ground A 1 y/z 7 /9 //Z OQ OCQ OA Zoo

4, 2, 3^ 3, 2, 2 Ground E 1 9/2 7/2 29 260.47 .01 253

5, 1, 4<- 5, 0, 5 Ground 13/2 11/2 28 445.75 .05 361

5, 1, 4^ 5, 0, 5 Ground 11/2 9/2 28 453.58 .05 361

5. 1, 4^ 5, 0, 5 Ground 15/2 13/2 28 473.63 .05 361

5, 1, 4^ 5, 0, 5 Ground 9/2 7/2 28 480.95 .05 361

7, 1, 6^ 7, 0, 7 Ground 17/2 15/2 30 431.79 .05 361

7, 1, 6^ 7, 0, 7 Ground 15/2 13/2 30 436.59 .05 361

7, 1. 6^ 7, 0, 7 Ground 19/2 17/2 30 455.39 .05 361

146
Bromoethane Spectral Line Table

Isotopic Species Id.

NTINo. Rotational Quantum Nos.

Vib. State Int. Rotor

State n Hyp<

r

;rfin< r Frequency

MHz

Acc. niMnzRef.

C'^HsC'^HaBrTM 521 7, 1. 6<- 7, 0, 7 (Ground 13/2 11/2 30 460.07 .05 361

C'2H;iC'2H2Br«' 522 3, 0, 3«- 2, 0, 2 Ground 7/2 5/2 21 839.67 .05 .361

3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 Zl o39.6/ .05 30

3, 0, 3^ 2, 0, 2 Ground 3/2 1/2 21 860.97 .05 361

3, 0, 3<- 2, 0, 2 Ground 5/2 3/2 21 861.55 .05 .361

3, 1, '2<^ 2, 1, 1 Ground 3/2 1/2 22 256.63 .05 361

3. 1, 2<^ 2, 1, 1 Ground 9/2 7/2 22 258.07 .05 361

3, 1, 2^ 2, 1, 1 Ground 5/z 3/2 22 275.75 .05 361

3, 1, 2-e- 2, 1, 1 Ground 7/2 5/2 22 280.80 .05 361

3, 1, 3-^ 2, 1, 2 Ground 9/2 7/2 21 424.66 .05 361

3, 1, 3<- 2, 1. 2 Ground 3/2 1/2 21 428.29 .05 361

3, 1, 3^ 2, 1, 2 Ground 21 434.1 197

3, 1. 3^ 2, 1, 2 Ground 7/2 5/z Zl 446.4I AC .05 361

3, 1. 3^ 2. 1. 2 Ground 5/2 3/2 21 450.32 .05 361

3. 2, 1^ 2, 2, 0 Ground 3/2 1/2 21 774.92 197

3, 2, 1^ 2, 2, 0 Ground E 1 9/2 7/2 21 780.69 .01 253

3, 2, 1^ 2, 2, 0 Ground A 1 9/2 7/2 21 782.67 .01 253

3, 2, 1-^ 2, 2, 0 Oround 9/2 7/2 zl o3/.10 1 A"? 197

3, 2, 1^ 2, 2, 0 Ground 21 862.0 197

3, 2, 1^ 2, 2. 0 Ground 5/2 3/2 21 862.13 197

3, 2, 1^ 2, 2, 0 Ground E 1 7/2 5/2 21 867.70 .01 253

3, 2, 1^ 2, 2, 0 Ground A 1 7/2 5/2 21 869.65 .01 253

3. 2. 1^ 2, 2, 0 Ground 7/2 D/Z 0 1 00/1 1 A 197

3, 2, 2^ 2, 2, 1 Ground 9/2 7/2 21 828.23 197

3, 2, 2^ 2, 2, 1 Ground 21 853.3 197

3, 2. 2^ 2, 2. 1 Ground 5/2 3/2 21 853.46 197

3, 2, 2«- 2, 2, 1 Ground 7/2 5/2 21 915.73 197

4, 1, 4^ 3, 1, 3 Ground 11/2 9/2 OO C7t\ OA z8 5/0.80 197

4, 1, 4-^ 3, 1. 3 Ground 28 576.3 197

4, 1, 4^ 3, 1, 3 Ground 5/2 3/2 28 576.70 197

4, 1, 4^ 3, 1, 3 Ground 9/2 7/2 28 579.50 197

4, 1, 4^ 3, 1, 3 Ground 7/2 5/2 28 585.70 197

4, 2, 3^ 3. 2. 2 Ground A 1 9/2 7/2 z9 093.65 .01 253

4, 2. 3^ 3. 2, 2 Ground E 1 9/2 7/2 29 094.66 .01 253

5. 1. 4^ 5, 0, 5 Ground 11/2 11/2 28 436.96 .05 361

5, 1, 4^ 5, 0, 5 Ground 9/2 9/2 28 443.22 .05 361

5, 1, 4^ 5. 0, 5 Ground 13/2 13/2 28 460.03 .05 361

5, 1, 4^ 5, 0, 5 Ground //z zo WO.iy AC .05 361

7, 1, 6^ 7, 0, 7 Ground 15/2 15/2 30 398.44 .05 361

7, 1, 6^ 7, 0, 7 Ground 13/2 13/2 30 402.48 .05 361

7, 1. 6^ 7, 0. 7 Ground 17/2 17/2 30 418.10 .05 361

7, 1, 6^ 7. 0. 7 Ground 11/2 11/2 30 422.02 .05 361

C'^DjC'^HaBr'" 523 3, 0, 3^ 2, 0, 2 Ground 7/2 5/2 19 109.86 .05 361

3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 19 110.67 .05 361

3, 0, 3*- 2, 0. 2 Ground 3/2 1/2 19 133.69 .05 361

3, 0, 3^ 2, 0, 2 Ground 5/2 3/2 19 135.33 .05 361

3, 1, 2^ 2. 1, 1 Ground 3/2 1/2 19 439.72 .05 361

147
Bromoethane

Spectral Line Table

Isotopic Species Id. Rotational

1

i Vib. State 1 Int. Rotor Hyperfine Frequency Acc. Ref.

iNO.

1 Quantum Nos. 1

1

1 State n F' F MHz ±MHz

C U-jL HaBr " C O Q 3, 1, 2 2,1,1

! 1

! Ground |

1 9/2| 7/2 19 441.68 .05 361

3, 1, 2-^ 2, 1, 1 1 Ground | 5/2j 1 3/2 19 460.56 .05 361

3, 1, 2-^ 2, 1, 1 1 Ground | 7/2 5/2 19 467.83 .05 361 3,1,3*— 2, 1, 2 Ground | 9/2 7/2 18 777.32 .05 361

3, 1, 3 2, 1, 2 1 Ground

1

3/2 1/2 18 782.26 .05 361

3, 1, 3 *— 2, 1, 2 1 Ground 7/2 5/2 18 801.98 .05 361

3, 1, 3-^ 2, 1, 2 Ground 5/2 3/2 18 807.27 .05 361

6, 1, 5^ 6, 0, 6 1 Ground 13/2 13/2 23 881.79 .05 361

0,

1i, o

r ^*— AAA 0, U, 0 Ground 11/2 11/2 23 888.35 .05 361

z:0, 11,0*— C .1 0,AAAU, 0 Ground 15/2 15/2 23 909.10 .05 361

6, 1,5*— 6, 0. 6 Ground 9/2 9/2 23 915.29 .05 361

7, 1, 6^ 7, 0, 7 Ground 15/2 15/2 24 731.52 .05 361

7, 1, 6*- 7, 0, 7 Ground 13/2 13/2 24 736.91 .05 361

7, 1, 6 *— 7, 0, 7 Ground 17/2 17/2 24 757.70 .05 361

'7 1 A ^ "7 A "7 /, 1,0*— 7, 0, 7 Ground 11/2 11/2 24 762.80 .05 361

524 o r> o ^ o A ri 3, 0, 3 *— 2, 0, 2 Ground 9/2 7/2 21 128.81 .05 361

3, 0, 3-^ 2, 0, 2 Ground 7/2 5/2 21 132.01 .05 361

3, 0, 3-^ 2, 0, 2 Ground 5/2 3/2 21 157.81 .05 361

3, U, 3 *— 2, 0, 2 Ground 3/2 1/2 21 162.20 .05 361

3, 1, 2 *— 2, 1, 1 Ground 3/2 1/2 21 584.83 .05 361

3, 1,2*— 2, 1, 1 Ground 9/2 1 7/2 21 590.35 .05 361

3, 1, 2-^ 2, 1, 1 Ground 5/2 3/2 21 616.46 .05 361

3, 1, 2-^ 2, 1, 1 Ground 7/2 1 5/2 21 617.29 .05 361

3, 1,3*— 2, i, 2 Ground 9/2 1 7/2 20 680.26 .05 361

3, 1,3*— 2, 1, 2 Ground 3/2 1 1/2 20 684.07 .05 361

3, 1, 3 *— 2, 1, 2 Ground 7/2 5/2 20 707.16 .05 361

3, 1, 3^ 2, 1, 2 Ground 5/2 3/2 20 711.43 .05 361

5, 1, 4-^ 5, 0, 5 Ground 11/2 11/2 22 035.23 .05 361 5,1,4*— 5, 0, 5 Ground 9/2 9/2 22 042.53 .05 361

5, 1,4*— 5, 0, 5 Ground 13/2 13/2 •22 061.39 .05 361

5, 1,4*— 5, 0, 5 Ground 7/2 7/2 22 068.60 .05 361

6, 1, 5-^ 6, 0, 6 Ground 13/2 13/2 23 036.91 .05 361

6, 1, S'^ 6, 0, 6 Ground 11/2 11/2 23 041.97 .05 361

6, 1,5*— 6, 0, 6 Ground 15/2 15/2 23 060.18 .05 361

6, 1,5*— 6, 0, 6 Ground 9/2 9/2 23 065.47 .05 361

7, 1, 6*- 7, 0, 7 Ground 15/2 15/2 i 24 240.94 .05 361

7, 1, 6-^ 7, 0, 7 Ground 13/2 13/2! 24 245.82 .05 361

7, 1,6*- 7, 0, 7 Ground 17/2 17/2 24 263.26 .05 361

7, 1, 6 *- 7, 0, 7 Ground 11/2 11/2 24 267.19 .05 361

C'^D^C'-HaBr"' 525 3, 0, 3 <— 2, 0, 2 Ground 7/2 5/2 18 993.67 .05 361

3, 0, 3 ^ 2, 0, 2 Ground 9/2 7/2 .18 994.08 .05 361

3, 0, 3<- 2, 0, 2 Ground 3/2 1/2 19 013.66 .05 361

3, 0, 3 2, 0, 2 Ground 5/2 3/2

~\ c\ r\'\ A "7 r" 19 014.75 .05 361

3, 1, 2 2, 1, 1 Ground 3/2 1/2 19 320.66 .05 361

3, 1, 2'^ 2, 1, 1 Ground 9/2 7/2 19 322.63 .05 361

3, 1, 2^ 2, 1, 1 Ground 5/2 3/2 19 338.73 .05 361

3, 1, 2-^ 2, 1, 1 ! Ground ! 7/2 5/2! 19 344.35 ! .05 361

148
Bromoethane Spectral I-ine Table

Isotopic Species Id. Rotational Vil). State Int. Hotor Hyperiine Fre(|U('ncy Ace. Ref. No. Quantum Nos. State n F'

1

1

r MHz ± IVI H /,

C'2D;,C''^H2Br*" 525 3, 1, 3-«- 2, 1, 2 Ground 9/2 7/2 18 665.63 1 .05 .361

3, 1, 3<- 2, 1, 2 Ground 3/2 1/2 18 669.75 .05 361

3, 1, 3-<- 2, 1, 2 Ground 7/2 5/2 18 686.28 .05 361

1, 0 * 9 19 Ground 5/2 3/2 18 690.79 AC .05 .561

6, 1, 5«- 6, 0, 6 Ground 13/2 13/2 23 868.13 1 .05 .361

6 0 6 Ground 11/2 11/2 26 873.61 1 .05 001

6, 1, 5^ 0! 6 Ground 15/2 15/2 23 890.79 1 .05 361

6, 1, 5-«- 6, 0, 6 Ground 9/2 9/2 23 896.07 .05 361

7, 1, 6<- 7, 0, 7 Ground 15/2 15/2 24 706.90 1 .05 361

7, 1, 6^ 7, 0, 7 Ground 13/2 13/2 24 711.31 1 .05 361

7 1, 6 <— 7, 0, 7 Ground 17/2 .UD 00

1

7, 1! 6«- 7^ 0, 7 Ground 11/2 11/2 OA 721 AO 24 /ol.Oz

C'^BjC'^DaBr"' 526 3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 21 002.59 .05 361

3, 0, 3^ 2, 0, 2 Ground 7/2 5/2 21 005.19 i .05 361

3, 0, 3*- 2, 0, 2 Ground 5/2 3/2 21 026.68 { .05 361

a 0, 3 <— 2, 0, 2 Ground 3/2 1/2 21 030.18 .05 361

3, h 2*- 2! 1' 1 Ground 3/2 1/2 21 454.68 .05 361

3, 1, 2<- 2, 1, 1 Ground 9/2 7/2 21 459.19 .05 361

3, 1, 2<- 2, 1, 1 Ground 5/2 3/2 21 481.07 .05 361

3, 1, 2*- 2, 1, 1 Ground 7/2 5/2 21 481.74 .05 361

3 1,3*— 2, 1, 2 Ground 9/2 7/2 20 560.17 .05 361

3! 3<- 2! 1! 2 Ground 3/2 1/2 20 563.36 .05 361

3, 1, 3«- 2, 1, 2 Ground 7/2 5/2 20 582.64 .05 361

3, 1, 3^ 2, 1, 2 Ground 5/2 3/2 20 586.21 .05 361

5, 1, 4-^ 5, 0, 5 Ground 11/2 11/2 22 024.46 .05 361

5 1 4 <— 5 0, 5 Ground 9/2 9/2 22 030.70 .05 361

5! 1! 4-^ 5, 0, 5 Ground 13/2 13/2 22 046.34 .05 361

5, 1, 4'«- 5, 0, 5 Ground 7/2 7/2 22 052.26 .05 361

6, 1, 5<- 6, 0, 6 Ground 13/2 13/2 23 012.88 .05 361

6, 1, 5 <— 6, 0, 6 Ground 11/2 11/2 23 017.24 .05 361

6, 1' 5'«- 6^ 0! 6 Ground 15/2 15/2 23 032.66 .05 361

6, 1, 5*- 6, 0, 6 Ground 9/2 9/2 23 036.91 .05 361

7, 1, 6^ 7, 0, 7 Ground 15/2 15/2 24 201.97 .05 361

7, 1, 6<- 7, 0, 7 Ground 13/2 13/2 24 205.84 .05 361

7^ 1,6*— 7, 0, 7 Ground 17/2 17/2 24 220.70 .05 361

7! 1! 6^ 7! 0, 7 Ground 11/2 11/2 24 224.11 .05 361

C'^HjC'^HaBrTM 527 3, 0, 3-^ 2, 0, 2 Ground 9/2 7/2 21 718.20 .05 361

3, 0, 3-^ 2, "D, 2 Ground 5/2 3/2 21 744.70 .05 361

3, 1, 2<- 2, 1, 1 Ground 3/2 1/2 22 147.69 .05 361

3, 1, 2 <- 2, 1, 1 Ground 9/2 7/2 22 149.41 .05 361

3, 1, 2 ^ 2, 1. 1 Ground 5/2 3/2 22 170.88 .05 361

3, 1, 2-^ 2, 1, 1 Ground 7/2 5/2 22 176.84 .05 361

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 91 OQQ ai Zl ZoV.ol 001

3, 1, 3-^ 2, 1, 2 Ground 3/2 1/2 21 293.52 .05 361

3, 1, 3^ 2, 1, 2 Ground 7/2 \ 5/2 21 315.48 .05 361

3, 1, 3^ 2, 1, 2 ! Ground 1

1 5/2 ! 3/2 21 320.07 .05 361

749-587 0-69— 1

1

149
Bromoethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F,'_ F' F, F MHz ±MHz

C'-'H.C'-H.BrTM 528 3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 21 208.90 .05 361

3, 0, 3^ 2, 0, 2 ( -.rriii Ti r\ 5/2 3/2 • UD

3, 1, 2*- 2, 1, 1 Ground 3/2 1/2 21 605.90 .05 361

a n1, 9 1 1 Ground 9/2 7/2 21 606.77 .05 361

3, 1, 2«- 2, 1, 1 Ground 5/2 3/2 21 626.46 .05 361

3, 1, 2*- 2, 1, 1 Ground 7/2 5/2 21 634.34 .05 361

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 90 sno Qd. .uo 00

1

3, 1, 3^ 2, 1, 2 Ground 3/2 1/2 20 814.35 .05 361

3 1 a 9 1

,

2 Ground 7/2 5/2 20 835.57 .05 361

3, 1, 3^ 2, 1, 2 Ground 5/2 3/2 20 840.44 .05 361

C'-H^C'-'H^Br"' 529 3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 21 590.10 .05 361

1 3, 0, 3'^ 2, 0, 2 Ground 5/2 3/2 91 f>i 9 m -UD

3, 1, 2<^ 2, 1, 1 Ground 1 3/2 1/2 22 016.12 .05 361

a 11

)

9 11

,

1 Ground 9/2 7/2 22 017.62 .05 361

3, 1, 2^ 2, 1, 1 Ground 5/2 3/2 22 035.68 .05 361

3. 1, 2-^ 2, 1. 1 Ground 7/2 5/2 22 040.21 .05 361

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 91 Ififi Q7 oOl

3, 1, 3<- 2, 1, 2 Ground 3/2 1/2 21 170.52 .05 361

a 3 2 I 2 Ground 7/2 5/2 21 188.89 .05 361

3, h 3-^ 2! 1, 2 Ground 5/2 3/2 21 192.78 .05 361

C'-'H,C'^H2Br«' 531 3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 21 083.35 .05 361

3, 0, 3^ 2, 0, 2 Ground 5/2, 3/2 91 104 47 .00 00^fiii 3. 1, 2, 1, 1 Ground 9/2 7/2 21 447.98 .05 361

3, 1, 2^ 2, 1, 1 Ground 5/2 3/2 21 494.67 .05 361

3, 1, 2*- 2, 1, 1 Ground 7/2 5/2 21 501.20 .05 361

3, 1, 3^ 2. 1, 2 Ground 9/2 7/2 20 689.88 .05 361

3, 1, 3^ 2, 1. 2 Ground 3/2 1/2 20 693.57 .05 361

3, 1, 3^ 2, 1, 2 Ground 7/2 5/2 20 711.4P .05 361

3, 1, 3^ 2. 1. 2 Ground 5/2 3/2 20 71'5.41 .05 361

150
540 - Chloroethane Molecular Constant Table

Ethyl Chloride C2H5CI C,(C.,„C,) CH-iCHjCl

Isotopic Species Pt. GdId. No. A (MHz) B (MHz) C (MHz) Dj K A

(-120 pi2IJ (-135 541 31 337.35 M 5 493.69 M 4 962.30 M 18.9

(-1214 ri2u rm r 542 31 285.20 M 5 378.99 M 4 867.23 M

r 543 31 293.39 M 5 098.65 M 4 637.60 M

g-C'^HzDC'^H^CPs c, 544 28 307.27 M 5 297.52 M 4 784.93 M

C'^HaC'^HzCP^ Cs 545 31 081.22 M 5 325.59 M 4 818.56 M

C'^HjCHzCP^ Cs 546 30 523.34 M 5 472.41 M 4 923.99 M

C'^H.C'^DjCF^ Cs 547 24 140.20 M 5 352.75 M 4 772.09 M

J I I L

Id. No. fjLa Debye |Lib Debye /lie Debye eQq V3 Ace. I red CUa d tUh d (Ue d oj,, d

541 1.79 M 0. X ^9.20 3560 12 336 1

542 -38.65

543 -49.32

544 ^7.36

545 ^8.48

546 ^9.51

547 -51.07

References: ABC: 196, 357 Dj: Djk: k: A: 253

127 eOq: 357 V: 253 I: w: 253

Torsional frequency = 242.5 cm"'. Ref: 253. Coupling Parameter: Ia= 3.1613 amu A^. Ref: 357.

151
Chloroethane

Spectral Line Table

Id. Rotational Vih Statp Int. Rotor Hyperfine Frequency Acc. i\ei. No. Quantum Nos State n

IT' 1?' r r ivinz

541 1,

1 A A

0 Ground 0/0 3/2 10 446.11 .05 357

1,

11^^ A A U, 0, 0 Ground 10 456.00 .05 357

1, 0, 1^ 0, 0, 0 Ground o/z 3/2 1 Ci A^P A(\ .Uo 00 ( 1, 0, 1^ 0, 0, 0 Ground 1/2 3/2 lu '^'Oo.o i .UD oO / 2, A

u. 2-^ 1, 0, I 3/2 1/2 Zu oVl.^-O .Uo 00 /

Z, f\0, 0^ 1 A z<— 1, U, 1 Ground o/z 5/2 20 892.41 .05 357

2, 0, 2*— 1, 0, 1 Ground 20 903.77 .05 357

2, 0, 2^ 1, 0, I Ground o/z o/z 9n onJ. ft7 oc; -Uo 00 / 2, 0, 2^ 1, 0, 1 Ground 7/2 5/2 zu9n QO/I VU4'.c5 / .Uo oO / 2, 0, 2*— 1, 0, Ground 3/2 3/2 ZU90 Qlyio.ov ^ ^^Q .UO 0^ oO /

iiz, 1, 1<— 1, 1, 0 Ground A o/z o/z 21 376.08 .1 196

z.

11,

1 ^ 1 T 1, 1, 0 Ground A o/z o/z 21 378.65 .1 196

2, 1, 1*- 1, 1, 1 1 n /I KjI UUIIU

AA o/z o/z .ii 000.uz 1

. 1

1 OA

2, 1, 1^ 1, 1, 0 \y I U Li IIU

AA //z DjZ Z.1 000.4*7 1

. 1 1 Qfx

1i. 1^ 1, 1, 0 A 1 3/2 1/2 91Z.X 074.00 ^94, 8^ 1

. 1

o

Z, 1

1 ^ 1 1 i* 1, 1, 0 Ground A11 i/Z i/z 21 398.18 .1 196

1i.

1 ^ 1 1 1* I, I, 0 Ground D/Z ofZ 21 433.79 .05 357

2, 1, 1^ 1, 1, 0 1 -JTii 1 n ri Vrl UUIIU. o/z O/Z 91 d^fi 97 0'^ .UO 00^^7/ 2, 1. 1^ 1, 1, 0 1 -r/^i 1 n ri VJl (J UllLI O/Z o/z 91 4.4.9 7^ .uo 00^^7( o

z. 1, l'^ 1, 1, 0 1 .rrii (J lilI n1 HLi 91 44.3 38 01^ .uo 00^^7{

2, 1, l'^ 1, 1, 0 Ground '7 /O '/z DjZ 21 446.21 .05 357

2, 1, l'^ 1, 1, 0 Ground 3/2 1/2 21 452.27 .05 357

2, 1, Ground 1/2 1/2 Zl 4'OD.OZ .uo 00 i 2, 1, 2^ 1!

1'

1i Ground o/z o/z ZU90 ^71 RO 0 / i .OU 0^: .uo 00 / 2, 1, 2^ 1, 1, 11 Ground 5/2 5/2 ZU90 0

'^74. flJ^

( 4'. 00 • 0^UO 00 i

2, 1, 2<— 1, 1, 1 Ground 9 /O 6JZ o/z 20 377.89 .05 357

2, 1, 2*— 1. 1, 1 Ground 20 380.58 .05 357

2, 1, 2^ 1, 1, 2 Ground 7/2 0/2 Z.U 90 ooo. '^8'^ 7QI y

0=1 .uo 00 1 2, 1, 2^ 1, 1, 1 Ground 1 /o 1/Z 1/2 90 '^Q9 86 .uo 00 i 3, 2, 1<— 2, 2, n Ground E 1 7/2 5/2 31 31 1 qc; 01 oil .70 1

0

. 1 u ZOO

3, 2, 1*— 2, 2, 0 Ground A 1 '/z .5/2 31 314.48 .10 253

3, 2, 1*— 2, 2, 0 Ground 1 ojl OjZ 31 320.82 .10 253

3. 2, 1^ 2, 2, 0 Ground AA 11 ^ /o 01

A

ci/Z 01"^1 OiiO.OU '?9'? ^fi .10 zoo

3, 2, 1^ 2. 2, Au Ground t,

11 0/0 9/2 7(jZ 0

^11 OilT'.O ^94, ^7i 10 zoo

0o. z. i'^ z, z. Ground A 1 9/2 7/2 0^11 OZU. ^96 78( 0 .10 253

3, 2, 1-^ z, z. 0 Ground 17

Jl, 1 oil 1/2 31 333.03 .10 253

3, 2, 1*— 2, 2, 0 Ground AA 1 Q /O ojl 1/2 31 335.62 .10 253

3, 2, 1«- 2, 2, Q '/z OjZ 0^11 04'^4SJ. 781

0

.10 253

3, 2. 1^ 2. 2, n\j 1 o/z .3/2 01 oot.uo .10 253

3, 2, 1<— 2, 2, Q Ground 7/2 5/2 01^1 07^Ql1 .00 J 196

3, 2, 1^ 2, 2, 0 Ground 31 400.29 .1 196

3, 2, l'^ 2, 2, 0 Ground ojZ 3 /o o/z 31 400.44 .1 196

3 2 1<— 2, 2, nV Ground 91

Z

7 /O '/2 0

311 d,0^ T-UO. 78/ 0

1

. 1

1 Ofi 1 7U

3!

2' 1^ 2' 2' 0 Ground o/z 1/2 31 412.5 I 196

3, 2, 2^ 2, 2, 11 Ground A 1 7/2 5/2 ^1 989 (SfS .10 253

3, 2, 2^ 2, 2, 1 Ground E 1 7/2 5/2 31 285.27 .10 253

3, 2, 2^ 2. 2, 1 Ground A 0 5/2 3/2 31 291.62 .10 253

3, 2, 2^ 2, 2, 1 Ground E 0 5/2 3/2 31 294.25 .10 253

3, 2, 2^ 2, 2, 1 Ground A 1 9/2 7/2 31 295.17 .10 253

3, 2, 2^ 2, 2, 1 Ground E 1 9/2 7/2 31 297.67 .10 253

152
Chloroethane Spectral Line Table

Isotopic Species Id. Rotational Vil). State Int. Rotor Hyperf'ine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

541 3, 2, 2<- 2, 2, 1 Ground A 1 3/2 1/2 31 303.94 .10 253

3, 2, 2<^ 2, 2, 1 Ground E 1 3/2 1/2 31 306.46 .10 253

3, 2, 2^ 2, 2, 1 1 7/2 5/2 31 312.97 .10 253

9

o, 0 9*— 9 9 1 1 5/2 3/2 31 321.86 .10 253

3, 2, 2^ 2, 2, 1 1 9/2 7/2 31 325.49 .10 2.53

3, 2, 2^ 2, 2, 1 1 3/2 1/2 31 333.95 .10 2.53 3, 2, 2-^ 2, 2, 1 Ground 7/2 5/2 31 359.15 .1 196

3, 2, 2^ 2, 2, 1 Ground 5/2 3/2 31 367^95 .1 196

3 2 2<— 2 2 1 Ground 31 368.07 .1 196

3! 2! 2-^ 2! 2! 1 Ground 9/2 7/2 31 371.65 .1 196

3, 2, 2^ 2, 2, 1 Ground 3/2 1/2 31 380.55 .1 196

3, 1. 2^ 3, 0, 3 Ground 3/2 3/2 27 734.22 .05 357

3, 1. 2^ 3, 0, 3 Ground 9/2 9/2 27 737.03 .05 357

3 1 2«— 3 0 3 Ground 5/2 5/2 27 740.18 .05 357

3]

1" 2*- S, 0, 3 Ground 7/2 7/2 27 742.95 .05 357

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 28 862.92 .05 357

4, I, 3^ 4, 0, 4 Ground 11/2 11/2 28 864.73 .05 357

4, 1, 3-^ 4, 0, 4 Ground 7/2 7/2 28 867.92 .05 357

4 3<_ 4 Q 4 Ground 9/2 9/2 28 869.63 .05 357

5, 0! 5^ 4' 1' 4 Ground 28 563.29 .05 357

542 1. 0. 1^ 0, 0, 0 'Ground 3/2 3/2 10 238.66 .05 324

1. 0. 1^ 0, 0, 0 Ground 5/2 3/2 10 248.08 .05 324

1. 0. 1^ 0, 0, 0 Ground 1/2 3/2 10 255.97 .05 324

9 1 1 1 1 0 Ground 5/2 3/2 20 996.90 .05 324

2, 1, 1<- 1, 1, 0 Ground 3/2 3/2 20 998.48 .05 324

2, I, 1^ 1, 1, 0 Ground 5/2 5/2 21 003.51 .05 324

2, 1, 1<- 1, 1, 0 Ground 7/2 5/2 21 006.28 .05 324

2. 1. 1^ 1, 1. 0 Ground 3/2 1/2 21 011.02 .05 324

2 1 ]<— 1 I 0 Ground 1/2 1/2 21 013.94 .05 324

2, i! l] 1'

1 Ground 5/2 3/2 19 973.43 .05 324

2, 1, 2^ 1, 1. 1 Ground 5/2 5/2 19 976.16 .05 324

2, 1, 2^ I, 1, 1 Ground 3/2 3/2 19 978.51 .05 324

2, 1, 2^ I, I, 1 Ground 7/2 5/2 19 983.22 .05 324

/' 2 I 2<— 1 1 1 Ground 1/2 1/2 19 990.44 .05 324

/ 3! I, 2^ 0] 3 Ground 3/2 3/2 27 726.70 .05 324

3, 1, 2«- 3, 0, 3 Ground 9/2 9/2 27 728.65 .05 324

3, 1, 2^ 3, 0, 3 Ground 5/2 5/2 27 730.75 .05 324

3, 1, 2«- 3, 0, 3 Ground 7/2 7/2 27 733.35 .05 324

4 3<_ 4 4 Ground 5/2 5/2 28 810.74 .05 324

4! I, 3^ 4! 0! 4 Ground 11/2 11/2 28 812.06 .05 324

4, 1, 3^ 4, 0, 4 Ground 7/2 7/2 28 814.56 .05 324

4, 1, 3<- 4, 0, 4 Ground 9/2 9/2 28 815.92 .05 324

5, 0, 5^ 4, 1, 4 Ground 27 382.99 .05 357

5, 1, 4^ 5, 0, 5 Ground 7/2 7/2 30 206.62 .05 324

5, 1, 4^ 5, 0, 5 Ground 13/2 13/2 30 207.53 .05 324

5, 1. 4^ 5, 0, 5 Ground 9/2 9/2 30 209.95 .05 324

5, 1, 4^ 5, 0, 5 Ground 11/2 11/2 30 210.87 .05 324

153
Chloroethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n 1 F' F1 F MHz ±MHz

t-C'^H^DC'^HXP^ 543 1, 0. 1*- 0. 0. 0 Ground 3/2 3/2 9 726.45 .05 324

1. 0. 1^ 0. 0, u Ground 5/2 3/2

r\ TOO 11 9 738.77 .05 324

1. 0. 1^ 0, 0, 0 Ground 1/2 3/2 9 748.59 .05 324

2, 1, 1-^ 1, 0 Ground 5/2 3/2 19 923.90 .05 324

2, 1, 1^ }; 1, 0 Ground 3/2 3/2 19 926.35 .05 324

2, 1. 1^ 1. 0 Ground 5/2 5/2 19 932.95 .05 324

2, 1. 1^ 1, u Ground 7/2 5/2 1 A C\0£, OA 19 936.21) .05 324

2, 1. 1^ \. 1, 0 Ground 3/2 1/2 19 942.45 .05 324

i 2, 1, 1<— \

1, 0 Ground 1/2 1/2 19 945.95 .05 324

2, 1, 2^ 1, 1 (iround 5/2 3/2 19 002.3 .05 324

2, 1. 2^ 1, 1 Ground 5/2 5/2 19 005.8 .05 324

2, 1. 2^ \ 1, 1 Ground 3/2 3/2 19 008.6 .05 324

2. 1, 2^ i' 1, 1 Ground 7/2 5/2 19 014.6 .05 324

2, 1, 2<— 1, 1 Ground 1/2 1/2 19 023.9 .05 324

3, 2, 1^ 2' 2, 0 Ground 7/2 5/2 29 224.23 .1 196

3, 2. 1^ 2. 2. 0 Ground 5/2 3/2 29 233.08 1 196

3. 2. 1^ 2, 2. A Ground 9/2 7/2 29 236.53 196

3, 2, 1^ 2. 2, 0 (Jround 3/2 1/2 29 245.64 ;J 196

3. 2, 2<— 2, 2, 1 (Ground 7/2 5/2 29 200.14 .1 196

3, 2, 2^ 2, 2, 1 (Ground 5/2 3/2 29 208.89 .1 196

3, 2, 2^ 2, 2, 1 Ground 9/2 7/2 29 212.44 .1 196

3, 1^ 2^ 3, 0, 3 C/round 3/2 3/2

0 "7 00 A 1 A

27 830.10 .05 324

3, 1, 2^ 3, 0, 3 Ground 9/2 9/2 27 832.83 .05 324

3, 1, 1*^ 3, 0, 3 Ground 5/2 5/2 27 835.97 .05 324

3. 1, 2*- 3. 0, 3 (Ground 7/2 7/2 27 838.62 .05 324

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 28 801.67 .05 324

4, 1, 3^ 4, 0, 4 Ground 11/2 11/2 00 OAO OA 28 803.29 .05 324

4, 1, 3^ 4, 0, 4 Ground 7/2 7/2 28 806.52 .05 324

4, 1, 3^ 4, 0. 4 Ground 9/2 9/2 28 808.10 .05 324

5, 0, 5^ 4, 1, 4 (Ground 24 368.57 .05 357

5, 1, 4^ 5, 0, 5 Ground 7/2 7/2 OA A/I 0 C /I AC .05 62.'* 5, 1. 4^ 5, 0, 5 Ciround 13/2 13/2 30 049.65 .05 324

5. 1, 4«- 5, 0, 5 (Ground 9/2 9/2 30 052.73 .05 324

5, 1, 5. 0, 5 Ground 11/2 11/2 30 053.86 .05 324

-C'2H2DC'2H.,Cr'^ 544 1. 0, 0, 0, 0 (Jround 3/2 3/2 10 072.98 .05 324

1, 0, 0, 0, 0 Irround 5/2 3/2 1 A AO/I AO 10 084.92 AC .05 00 /I

1, 0. 1^ 0. 0, 0 Ground 1/2 3/2 10 094.21 .05 324

2, 1. 1, 0 Ground 5/2 3/2 20 668.28 .05 324

2, 1.

}•

1, 0 (iround 3/2 3/2 20 670.34 .05 324

2, 1, 1, 0 (iround 5/2 5/2 20 677.17 .05 324

2, 1. 1, 0 Ground 7/2 5/2 OA CQ(\ AA 20 680.09 AC .Uo

2, 1, 1^ 1, 0 (Ground 3/2 1/2 20 686.34 .05 324

2, 1, 1, 0 (Ground 1/2 1/2 20 689.31 .05 324

2, 1, 2^ }; 1, 1 (Jround 5/2 3/2 19 643.6 .05 324

2, 1, 2^ 1, 1 (Ground 5/2 5/2 19 646.4 .05 324

2. 1, 2^ 1, 1 (iround 3/2 3/2 1 A C A A

19 650.0 .05

2. 1. 2*- 1, 1 Ground 7/2 5/2 19 655.4 .05 324

2, 1, 2*- 1, 1 Ground 1/2 1/2 19 664.2 .05 324

3. 2, 1^ 2'2, 0 (Ground 7/2 5/2 30 272.84 .1 196

3, 2. 1^ 2. 2. 0 (Jround 5/2 3/2 30 281.45 .1 196

154
Chloroethane Spectral Line Table

Isotopic Species

1 Id.

i Rotational Vib. State Int. Rotor Hyperfine Frequency Ace. 1 Ref. No. Quantum Nos State n F' F MHz ±MHz 1

g-C'^HjDC'^HaCP 544 3, 2, 1^ 2, 2, 0 Ground 9/2 7/2 30 284.50 196

3 9 1*— 9 9 n\j Ground 3/2 1/2 1 1 i 7U

3, 2, 2^ 2, 2, 1 Ground 7/2 5/2 30 238.96 j 196

3, 2, 2-^ 2, 2, 1 Ground 5/2 3/2 .30 247.36 .1 196

3, 2, 2^ 2, 2. 1 Ground 9/2 7/2 30 250.87 .1 196

3, 2, 2-^ 2, 2, 1 Ground 3/2 1/2 30 259.08 •1 i 196

3 1 2<— 3 0

5 Ground 3/2 3/2 Zt" 000.7 I .yjo ^94.

3! 1! 2^ 3! 3 Ground 9/2 9/2 24 838.76 .05 324

3, 1, 2*- 3, 0, 3 Ground 5/2 5/2 24 842.03 .05 1 324

3, 1, 2^ 3. 0, 3 Ground 7/2 7/2 24 844.87 .05 1 324

5, 0, 5<- 4, 1, 4 Ground 29 433.82 .05 i 357

c: 0 Ground 7/2 7/2 .yjo \ ^9d

5, 1, 4-^ 5, 0, 5 Ground 13/2 13/2 27 343.98 .05 1 324

5, 1, 4^ 5, 0, 5 Ground 9/2 9/2 27 347.22 .05 ! 324

5, 1, 4^ 5, 0. 5 Ground 11/2 11/2 27 348.50 .05 1 324

u, 1, O*^ U, V, 0 Ground 9/2 9/2 90 1 HA 9^ .uo 1

1 oZ4' ?9d.

6, 1, 5^ 6. 0. 6 Ground 15/2 15/2 29 105.22 .05 1 324

6, 1, 5^ 6, 0, 6 Ground 11/2 11/2 29 108.62 .05 1 324

6, 1. 5^ 6. 0, 6 Ground 13/2 13/2 29 109.55 .05 1 324

545 2, 0, 2^ 1, 0. 1 Ground 5/2 3/2 20 313.27 .05 i 324

9 fiu, 9«— .i^ 11, nu.

11 Ground 7/2 5/2 9n 1 1^ (19 .yjo j OZt* ^94.

2, 0, 2^ 1, 0, 1 Ground 3/2 3/2 20 322.10 .05 1 324

2, 1, 1^ 1. 1. 0 Ground 5/2 3/2 20 785.85 .05 1 324

2, 1. 1^ 1. 1. 0 Ground 5/2 5/2 20 794.83 .05 1 324

2. 1. 1^ 1, 1, 0 Ground 7/2 5/2 20 798.02 .05 324

2. 1 1 1 Q Ground 3/2 1/2 ZU9(1 Sfld 0U4'.101 .yjo OZ'r

2! 1^ 1^ I. 1. 0 Ground 1/2 1/2 20 807.44 .05 1 324

2, 1. 2^ 1, 1, 1 Ground 5/2 3/2 19 772.27 .05 ! 324

2, 1, 2^ 1, 1, 1 Ground 5/2 5/2 19 775.61 .05 324

2, 1, 2^ 1, 1, 1 Ground 3/2 3/2 19 778.66 .05 1 324

9 1 9«— 1 1 1 Ground 7/2 5/2 1 Q 7JM d.9 ^9d. OZ.He 2. 1, 2^ 1. ], 1 Ground 1/2 1/2 19 793.4 .05 1 324

3. 1, 2^ 3. 0, 3 Ground 3/2 3/2 27 557.89 .05 1 324

3, 1. 2^ 3. 0, 3 Ground 9/2 9/2 27 560.62 .05 i 324

3, 1, 2^ 3, 0, 3 Ground 5/2 5/2 27 563.76 .05 324

0,^ 11. 9«— tj, ^ nu. 0 Ground 7/2 7/2 Z I JDO.DO .\Jo oz^- ^9d.

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 28 632.35 .05 324

4, 1, 3^ 4, 0, 4 Ground 11/2 11/2 28 634.10 .05 324

4, 1, 3^ 4. 0. 4 Ground 7/2 7/2 28 637.11 .05 1 324

4, 1, 3^ 4, 0, 4 Ground 9/2 9/2 28 638.88 .05 j 324

c: Ground 7/2 7/2 ou uio.il .uo 1 OZ^

5, 1, 4<- 5, 0, 5 Ground 13/2 13/2 30 016.32 .05 1 324

5, 1, 4^ 5, 0, 5 1 Ground 9/2 9/2 30 019.42 .05 1 324

5. 1, 4«- 5, 0, 5 Ground 11/2 11/2 30 020.68 .05 324

546 1, 0. 1^ 0. 0, 0 1 Ground | 3/2 3/2 10 386.51 .05 1 324

1, 0 1<— 0 0 V 1 Ground | 5/2 3/2 lU 070.00 .uo 1 •^94. OZ'*

l] 0. 1^ 0^ 0' 0 1 Ground | 1/2 3/2 10 408.78 .05 324

2, 0, 2^ 1, 0, 1 Ground | 3/2 1/2 20 771.41 .05 324

2, 0, 2^ 1. 0. 1 Ground j 5/2 5/2 20 772.35 .05 i 324

2, 0. 2^ 1. 0. 1 i (Jround | 7/2| 5/2 20 784.91 .05 324

155
Chloroethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frccj ucnc y Acc. Ref. No. Quantum Nos V State n F' F' F p MHz ±MHz

C'^HjC'^HjCP 546 2, 0, 2^ 1. 0, 1 Ground 3/2 3/2 20 793.67 .05 324

2, 1, l'^ 1. 1, 0 Ground 5/2 3/2 21 331.72 .05 324

2, 1, 1^ 1, 1, 0 Ground 3/2 3/2 21 334.11 .05 324

2, 1, 1^ 1. 1, 0 Ground 5/2 5/2 21 340.42 .05 324

2, 1, 1^ 1. 1, 0 Ground 7/2 5/2 21 344.00 .05 324

2, 1, 1^ 1, 1, 0 Ground 3/2 1/2 21 349.93 .05 324

i 2, 1. 1, 1, 0 Ground 1/2 1/2 21 353.66 .05 324

2. 1, 2^ 1, 1, 1 Ground 5/2 3/2 20 235.21 .05 324

2, 1, 2«— 1, 1, 1 Ground 5/2 5/2 20 238.71 .05 324

2, 1, 2<— 1, 1, 1 Ground 3/2 3/2 20 241.57 .05 324

2, 1, 2<— 1, 1, 1 Ground 7/2 5/2 20 247.70 .05 324 2-^ l! l' 1 Ground 1/2 J. ^ 1/2 20 256.75 .05 324

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 28 173.62 .05 324

4, 1, 3<— 4, 0, 4 Ground 11/2 11/2 28 175.25 .05 324

4 J 3<_ 4 Q 4 Ground 7/2 7/2 28 178.26 .05 324

4 1 3<— 4. 0 4 Ground 9/2 9/2 28 179.95 .05 324

5! 0! 5^ 4'1! 4 Ground 29 109.25 .05 357

5, 1, 4-^ 5, 0, 5 Ground 7/9 7/9 29 682.75 .05 324

5, 1, 4<— 5 0, 5 Ground 13/2 13/2 29 683.97 .05 324

5, 1, 4^^ 5, 0, 5 Ground Q/9 Q/9 29 686.99 .05 324

5, 1, 4-^ 5, 0, 5 Ground 11/2 11/2 29 688.18 .05 324

C'-H.,C'2D2CP^ 547 2, 0, 2^ 1, 0, 1 Ground 3/2 1/2 20 223.65 .05 324

2 0 2<— 1 0 1 Ground 5/2 5/2 20 224.63 .05 324

2 0 2*— 1, 0, 1 Ground 20 236.43 .05 357

2' 0! 2<— 1! 0'

1 Ground 5/2 3/2 20 237.46 .05 324

2. 0, 2<— 1, 0, 1 Ground 3/2 3/2 20 246.72 .05 324

2. 1, 1^ 1, 1, 0 Ground 5/2 3/2 20 820.49 .05 324

0 Ground 3/2 3/2 20 823.26 .05 324

9 1 1 1 1 0 Ground 5/2 5/2 20 829.38 .05 324

0 Ground 20 830.34 .05 357

0 Ground 7/2 5/2 20 833.26 .05 324

2, 1, 1^ 1, 1, 0 Ground 3/2 1 /9 20 839.28 .05 324

9 11 4, 1 1 Z, 1, 1* 1, 1, 0 Ground 1/2 1 /2 20 843.07 .05 324

9 1 9< 1 1 Z, 1 , Z* 1 , 1

,

1 Ground 5/2 3/2 19 659.54 .05 324

2, 1, 2-^ 1, 1, 1 Ground 5/2 5/2 19 663.44 .05 324

2, 1, 2<- 1, 1, 1 Ground 3/2 3/2 19 665.87 .05 324

2, 1, 2^ 1, 1. 1 Ground 19 669.02 .05 357

2, 1, 2^ 1, 1. 1 Ground 7/9 5/2 19 672.38 .05 324

2, 1, 2^ 1, 1, 1 ( .mil n

H

1 /9 1 /9 19± If 681 yjyj J. - 83\j%J .05 324

3, 1, 2^ 3, 0, 3 Ground 3/2 3/2 20 872.9 .05 324

3, 1, 2*- 3. 0, 3 Ground 9/2 9/2 20 875.6 .05 324

3, 1, 2^ 3. 0, 3 Ground 20 877.60 .05 357

3, 1, 2*- 3, 0, 3 Ground 5/2 5/2 20 878.7 .05 324

3, 1, 2<- 3, 0, 3 Ground 7/2 7/2 20 881.6 .05 324

4, 1. 3^ 4. 0. 4 Ground 5/2 5/2 22 140.38 .05 324

4, 1, 3^ 4. 0, 4 Ground 11/2 11/2 22 142.19 .05 324

4, 1, 3^ 4, 0, 4 Ground 22 143.89 .05 357

4, 1, 3^ 4, 0, 4 Ground 7/2 7/2 22 145.19 .05 324

4, 1, 3^ 4, 0, 4 Ground 9/2 9/2 22 147.03 .05 324

156
Chloroethane Spectral Line Table

Isotopic Species lu.

INO. Nn

R.ot3tion3.1 Quantum Nos.

Int 1111. Rntnr IVOlOl State n F'

riypt

F' MHz

Acc. ±MHz

Ref.

C'^HaC'^DjCP 547 5, 1, 4^^ 5, 0, 5 Ground 7/2 7/2 23 795.5 .05 324

5, 1, 4^ 5, 0, 5 Ground 13/2 13/2 23 796.68 .05 324

o, i, 4* o, U, o Ground OQ 7QQ on .UO OO ( O, 1, O, u, o Ground Q/9 95 7QQ 7 Zo / W. i .UO oZ^-

c 1 /t^ ^ n ^ O, 1, 4* 0, U, o Ground 11/9 11/9 95 onn 0 Zo ouu.v .Uo 59/1 oZ4-

7, 1, 7, 0, 7 Ground 11/2 11/2 28 448.6 .05 324

7, 1, 6-^ 7, 0, 7 Ground 17/2 17/2 28 449.4 .05 324 Ground Zo ^-ol .uu O.J 5^7/ 7 1 iCrf 7 f\ 7 Ground 161 z, 15/9 OQ /I CO c Zo 4oZ.o .Uo 59/1 oZ"* 7 1 z;^ 7 0 7 Ground 1 C/9 Zo 4oo.o .ud 59/1 oZ^

548 Not Reported 20 387.36 .05 324 Not Reported 20 786.80 .05 324 Not Reported on 7QO Qi

.yjo ^9d Not Reported on 709 79 .UO ^94 Not Reported ZU 004*. 7 .yjo ^9d

Not Reported 20 888.2 .05 324 Not Reported 22 150.31 .05 324

99 1 SI (11 .05 324

iiUL [\l r»t rt *i r^/^i"t llcp'JI ICLi 94 '^fiQ fSl .05 324

i'lui iicpui ICU .05 324

Not Reported 26 912.37 .05 324 Not Reported 26 914.32 .05 324

9(S Ql 7 fi'^ 324 Not Reported OA QOn QQ ZU 7ZU.VO •UO ^9d

ilUL IVcpUl led 9^> 09^ R9 324

Not Reported 26 992.78 .05 324 Not Reported 26 995.60 .05 324 Not Reported 97 d.87 HI oz^ Not Reported Z/97 dSQ ^oV.jO"^^i .UO oZ4 ^94 Not Reported 27 492.74 .05 324

Not Reported 27 494.32 .05 324 Not Reported 29 454.08 .05 324 Not Reported 29 544.1 .05 324

157
I

550 - Fluoroethane Molecular Constant Table

Ethyl Fluoride C,H,F C,(C:,v.Cs) CH.CH^F

Isotopic Species Pt. Id. No. A (MHz) B(MHz) C(MHz) D,, D.,K X A

C'^RjC'^HaF'" Cs 551 36 070.30 M 9 364.54 M 8 199.74 M -.9164

C'^H:iC'^HDF"' c, 552 31 140.2 M 9 252.63 M 7 995.51 M

{r-C'-H^DC'^HjF'" Cs 553 32 601.8 M 8 953.99 M 7 866.31 M

t-C'^HsDC'-HaF"' Cs 554 35 693.3 M 8 623.86 M 7 611.59 M

/~< 1 '> ¥ ¥ 1 •* ¥ ¥ ¥"' 1 O C'^H;,C''H2F"* Cs 555 35 250.1 M 9 365.66 M 8 157.15 M

1 "I ¥ ¥ /"> 1 •> ¥ ¥ ¥"* I U C"H:,C'''H2F'" Cs 556 35 915.4 M 9 089.05 M 7 980.16 M'

C'^H^DC'^HDF'" ' c, 557 28 503.6 M 8 825.73 M 7 696.11 Ml

C'^HDX'-HDF'" ' c, 558 26 206.1 M 8 457.65 M 7 405.06 Ml

C'^HC'^HDF'" ' c, 559 28 416.3 M 8 872.88 M 7 649.87 Ml

C'^DHDC'-HDF'" • c, 561 28 183.7 M 8 185.21 M 7 187.84 Ml

C'^DH^C'^HDF"' ' c, 562 30 887.7 M 8 528.66 M 7 437.53 Ml i

C'^D^HC'-HDF'-' ' c, 563 28 101.0 M 8 227.57 M 7 147.50 Ml 1

Id. No. Debye jLti, Debye ju,,. Debye eQq V:, Acc. I,.,. (Uji d oji, d o), d oj,i d

551 1.69 M 1.00 M 0. X 3306 4.359 440 1

1. Configurations a. b. and c belong to the same isotopic molecular species, as do configurations d, e, and f. Similarly, the gauche and trans- forms belong to the same isotopic molecular species. Since the form is "gauche" as stated in table 1. not "cis" as in table 3, the term "cis" was assumed to be a typographical error. As Bak et aJ. treated the configurations independently, each configuration is given its own species number. References: ABC: 108. 274 D,: D,,k: k: 108 A:

M: 108 eQq: V: 258 | I: 108 oj: 108 Add, Refs,: 236, 323

Torsional frequency= 270 cm"'. Ref: 108,

158
Fluoroethane Spectral Line Table

Isotopic Species la. Rotational Quantum Nos.

V ID. oiaie ini. rvoior State n V TT' r

rfinc

r

F^rec|uency

ivinz Acc.i^ivinz Ref.

C'^HsC'^HaF'*' 551 1, 0, 1<- 0, 0, 0 Ground A 1 17 530.5 137

1, 0, 1-^ 0, 0, 0 Ground 17 549.69 215

1, U, 1*^ u, u, u Ground 1 7 c^A

1 / oOHf.OO Zlo

1, 1, U<— I, U, 1 Ground AA 1i 97 7 Z / (0/ .i 1 Q "7

1, 1, U*^ 1, U, 1 Ground 97 77/1 Zl.T

1, 1, 0^ 1, 0, 1 Ground 27 809.78 215

1, 1, 0-^ 1, 0, 1 Ground 27 870.71 215

U, Z* 1, U, 1 Ground A 1 QC f\OA 9 to ( Z, U, 1, U, i Orouna or n/cn OD UOU. zi.D z, U, z^ i, U, 1 Ground 3 c: AO 1 1 .10 1 AO

2, 1, 1^ 1. 1, 0 Ground 33 963.77 .10 108

2, 1, 2^ 1. 1, 1 Ground 36 293.37 .10 108

Z,9 71* 11*< 9z, 0u, 9z Ground JT. i 90 QC.A A la ( Z,9 1i, 11*« z,9 0u, z9 Ground ZO9ft Q^^O VOU.'tZ d9 ZIO 91

Z,9 1i, 1«— 1^^ z,9 0u, z9 Ground 9ft Qftd ^ 91

2, 1, 1^ 2, 0, 2 Ground 29 072.68 .10 108

2, 2, 1^ 3. 1, 2 Ground 25 698.47 .10 108

O, 1, Zr Ground F 1 ZU 700. U7 236

O, Z, 1, ^ Ground A 1 96 QdO "id zou

^ fl 9 19 Ground Of. Qf.^ no ZD Zoo

3, 1, 3^ 2, 2, 0 Ground 32 723.83 .10 108

3, 1, 2*- 3, 0, 3 Ground A 1 30 802.1 137

O, 1, Z* Oy U, o i^rounu OA QAQ 99 oU oUo. ZZ 91 £^ zlo

O, 1, z* o, U, O Ground Q A OA Q 1 c: 91 C zio

'i', i, 4-, U, ^ Ground 00 DOO.OO 1 A .iU 1 AQ lUo

5, 1, 4-^ 5, 0, 5 Ground 37 042.99 .10 108

5, 1, 4^ 5, 1, 5 Ground A 1 17 229.8 137

O, 1, O, i, O Ground 91 Q zlo

O, 1, 4'* O, i, O Ground 91 ^ zlo

0, O, Z*^ O, Z, 0 Ground 1 A 1 AQ lUo

5, 3, 3^ 6, 2, 4 Ground 28 990.30 215

6, 1, 5^ 5, 2, 4 Ground 35 263.45 .10 108

O, I, 0, 1, o Ground OA 7A Z'^ oVo. /U .lU 1 AQ lUo

7 1 7«— 9 d Ground 91 c:95 Zi DZo.oO 91c: zla

7 1 6<— 7 17 Ground 09 /lAQ QQ -lU 1 n 1 Oft

Not Reported 20 636.57 215 Not Reported 20 642.17 215

91Zl dOR H?70.00 91ZIO

liUl M r»t H,CJJUll.CLi ri r»r»rt f^H 91 "^d? Qd 91ZIO^

iMAt R f^TiArt f^f\ Zl91 7Q9 17Z.OO ZIO 91

Not Reported 21 828.32 215 Not Reported 22 463.5 215

[\l /^t rC » r^r^Tt oiH 97 9nd ZIO 91 ^

i'lUl IXcpOl Leu Zl97 OiO.Oo '^l ZIO 91 ^ Not Reported 97 HflQ 78 91ZIO

Not Reported 27 839.05 215 Not Reported 28 961.55 215 Not Reported 28 984.5 215 Not Reported 30 881.71 215 Not Reported 32 087.89 215

159
Fluoroethane

Spectral Line Table

Isotopic Species Rotational V ID. ctlaie ini. iioior Hyperfine Frequency Acc. net.

Nr. Quantum Nos. State n F/ F' F ivirlz 3:iVlriz

C'^HaC'^F'^ 552 1. 1, 0^ 1, 0, 1 Ground 23 144.5 274

2, 1, 1<- 2, 0, 2 Ground 24 454.2 •1 274

9 9 1 oq Ground i V Do / .O 97/1 Z

Qo. 1, z* A q Ground zo9*. oio. CI 7/ Z /4

c 1A* 9 3 Ground 27 773.2 274

5, 1, 4^ 5, 1,

c;o Lrround iO Ol 7. i 974. Z /4

6, 1, 6^ 5, 2, 3o Ground ZU OOO.T* Z97/L / 4

1 0, i. D Ground ZD9ft zoo.o 9Q3 % Z97/1 /4

g-C'^H^DC'^HoF'" 553 11,

1

1i. A

u. 1 Ground 24 735.6 .1 274

9 1,

1 9 A

2 Ground 25 860.0 •1 274

2. 2, 0^ 3, 1, q Ground ZD 404.O 97/1 2, 2, 1^ 3, 1, 9z Ground io o 1 i.D

"j 97/1 Z i 4

Q A

'J. 9Z^ 1 9z Ground 97 71 7 c; 97/1 Z i 4

Q

1,

9^^ Z* A

^1 3 Ground 27 615.1 .1 274

r 11,

A^, 9Z, 3 Ground 19 443.8 •1 274

5. 3, 2<- 6, 2, o Ground ZU 04U.V 97/1 Z /4

6, 1. 5^ 6, 1, o Ground 99ZZ 77A J 1 o.z9 Z /4

-7/, i. D, o

z. 't Ground ZO /40.0 "I 97/1 Z /4

t-CH^DC'^HaF'^ 554 1. 1, 0^ 1, 0, 1 Ground 28 081.6 .1 274

O

/, i. — 9 A

^1 2 Ground 29 122.0 •1 274

o.

(\u. 9z. 1, 9z Ground ZZ99 c:nQ A OUV.O 97/1 Z /4

' QJ, o

z.

/i4, 1 4 Ground 23 056.7 \\ 274

/:0, 1 0,11, 6 Ground 21 217.3 274

6, 1, 5*- 6, 2, 4' vrround 9d. Q'^'^ fT Zl* Z97/1 i 4

QO, 71

,

Z,9 c: 0 Ground Zi91 O^-Z.o '^d.9 R Z97/t (4

C'^HaC'^H^F'' 555 1 nu. 1 ^ A

»Ji AU, 0 Ground 17 522.7 .1 274

1, 1 (\^ 1 A

-

1 Ground 27 092.7 274

2v 1, 2, 0, 9z Ground zo O'tO. 1 274

2, 2. 1^ 3. 1, z9 Ground zo95 Z70. 9qc: 7J 97d Z 1 ^

qPi n 9z.,

1 z9 Ground 97 AQQ Q Z i uoo.o Z ( 4-

c 1I

.

c:D.

1i. 5 Ground 18 103.9 .1 274

c

"J, z* fio. 9z. 5 Ground 27 874.3

•j 274

5, 3, 3^ 6, 2, Ground ZO9^ 09^ UZO. 11 Z97d/ 4- 6, 1, 5^ 6, 1, 0 Ground zo9^ oUO.O qn^ ^ Z97il /4

'7<, 1, / * o. z. 4 Ground ZZ99 f\l'\ 0 ft /o.o Z97/1 i 4

C^HjC'^HsF'^ 556 1. 1, 0^ 1, 0, 1 Ground 27 935.2 .1 274

o

Z, 9Z,

"1 ^ Q

J, 1, 2 Ground 27 624.6

•j 274

QJ. n

U, OZ, 1 z9 Ground 9c, q9i n ZO oZi.U Z

Q

«J. 9Z, 1* /I4, i. 4 Ground 19 663.2 274

o»

11. 0,

1i

,

6 Ground 23 233.1 274

6, 3, 3^ 6, 2, 0 Orouncl Z97d.i^- 7, 1, 7«— 6, 2. 4 Ground io oOO.O 97d.

C'-HzDC'^HDF'' 557 1, 1. 0^ 1, 0, 1 Ground 20 806.9 .1 274

2, 1, 1^ 2, 0, 2 Ground 21 984.1 274

3, 1. 2*- 3, 0, 3 Ground 23 837.4 }

274

4, 1. 3*- 4, 0, 4 Ground 26 466.0 274

4, 3, 1^ 5, 2, 4 Ground 18 868.2 274

6, 1, 6^ 5, 2, 3 Ground 24 395. 1,. 274

160
Fluoroethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum N State n F,' F' F1 F MHz ±MHz

C'^HaDC'^HDF's 557 6, 1, 5^ 6, 1, 6 Ground 23 618.7 .1 274

C'^HDaC'^HDF'^ 558 o<— 1, 0, 1 Ground 18 800.5 J

274

9 J 2, 0, 2 1 _>*J"11 1 Tl iH 19 898.9 274

QO, 11

,

3, 0, 3 Ground 21 630.4

•[ 274

4, I 3«_ 4! 0^ 4 01 UUIlii 24 090.2 274

6, l] 6*- 5' 2' 3 Ground 27 245.5 .1 274

5 I 5<— 6, 1, 6 Ground 22 001.9 1 274

C'^HDHC'^HDF'^ 559 I I Q<— 1, 0, 1 Ground 20 766.0 274

2 I ]<— 2, 0, 2 Ground 22 045.2 274

s! 1. 2<- 3'

0, 3 Ground 24 066! 1 .1 274

6, 1, 6^^ 5'

2, 3 Ground 23 322.7 .1 274

6, 1, 5<— 6, I, 6 Ground 25 551.1 • 1 274

C'^DHDC'TOF's 561 1^ 1^ o«— 1, 0, 1 Ground 20 995.7 274

2I

1' 1<— 2, 0, 2 rr» 1 1 n n 22 029.5 274

2, 2! 0^ 3, 1, 3 Ground 18 418.7 !i 274

3, 0, 3^ 2' 1' 2 Ground 26 935.4 •1 274

3, 2«— 3! 0, 3 Ground 23 647.6 .1 274

4, 3.^- 4, 0, 4 Ground 25 928.2 J

274

4 3! 1<— 5, 2, 4 1 - m1 1 n rf \jU UllU 25 823.1 274

5'

\, 4^ 4]

2' 3 Ground 22 613!8 .1 274

6, 1, 6^ 5' 2' 3 Ground 18 610.4 .1 274

6, 5.^ (>] i! 6 Ground 20 875.3 .1 274

C'^DHzC'^HDF'^ 562 1, 1, 0^ 1, 0, 1 Ground 23 450.0

•| 274

2, 1, 1^ 2] 0^ 2 1 »roi I n H 24 580.2 274

2, 2, 0*— 3'

r. 3 Ground 24 152.3 .1 274

3' 0' 3<— 2, 1, 2 Ground 26 433.5 .1 274

3' 1' 2«— 3, 0, 3 Ground 26 348.0 274

5, 1, 4'^ 4, 2, 3 Ground 19 048.2 .1 274

6. 1, e] 1] 6 Ground 22 841.0 1 274

7^ 1^ 7*— 6, 2, 4 Ground 24 405.0 .1 274

C'^DzHC'^HDF'^ 563 1^ 1^ o<— 1, 0, 1 Ground 20 953.7 274

2I 1^ 1^ 2", 0^ 2 i^rnii nrl 22 076.1 274

2, 2, 0^ 3'

1, 3 Ground 18 418.7 A 274

3, 0, 3^ 2, 1, 2 Ground 27 116.9 1 274

3, 1, 2^ 3, 0, 3 Ground 23 840.0 1 274

4, 1. 3*- 4, 0, 4 Ground 26 335.9

:} 274

4, 3, 1^ 5, 2, 4 Ground 25 432.2 274

5, 1, 4^ 4, 2, 3 Ground 23 451.0 274

6, 1. 6^ 5, 2, 3 Ground 17 717.2 274

6. 1, 5^ 6. 1, 6 Ground 22 592.7 274

161
570 - lodoethane

Ethyl Iodide

Cs(C3v,Cs)

Molecular Constant Table

CH3CH2I

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) Dj DjK K A

571 29 106.2 M 2 979.2 M 2 797.1 M .05 ' -0.151

Id. No. /Aa Debye ju-b Debye ix^ Debye eQq V3 Acc. Ired COa d

1

ojb d OJe d CD(, d

571 1.75 M 0.25 M 0. X -1771 3200

1

1. According to a private communication from Kasuya, .05 is the correct value for Dj.

References: ABC: 283

ix: 283

Dj: 283 eQq: 283

Djk: 283

V: 284

Torsional frequency = 230 cm-'. Ref: 284. Centrifugal distortion parameter: Dk= .36 ± .05 MHz. Ref: 283.

lodoethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

C'^HsC'^H^r" 571 1. 0, 1^ 0, 0, 0 Ground 5/2 5/2 5 542.08 .05 283

1, 0, 1<- 0, 0, 0 Ground 7/2 5/2 5 852.44 .05 283

1, 0, \<- 0, 0, 0 Ground 3/2 5/2 5 988.1 .5 283

2, 1. 1*- 2, 0, 2 Ground 9/2 9/2 26 438.02 .05 283

2. 1, 1^ 2, 0, 2 Ground 7/2 5/2 26 538.5 1. 283

2, 1, 1^ 2, 0, 2 Ground 7/2 7/2 26 620. 2. 283

2, 1, 1^ 2, 0, 2 Ground 5/2 7/2 26 647.50 .05 283

3, 0, 3^ 2, 0, 2 Ground 9/2 9/2 17 070.40 .05 283

3, 0, 3^ 2, 0, 2 Ground 3/2 1/2 17 194. 2. 283

3, 0, 3^ 2, 0, 2 Ground 5/2 3/2 17 212.40 .05 283

3, 0, 3^ 2, 0, 2 Ground 7/2 5/2 17 283.82 .05 283

3, 0, 3<- 2, 0, 2 Ground 11/2 9/2 17 342.28 .05 283

3, 0, 3^ 2, 0, 2 Ground 9/2 7/2 17 354.96 .05 283

3, 0, 3^ 2, 0, 2 Ground 3/2 3/2 17 382.34 .05 283

3, 1, 2«- 2, 1, 1 Ground 7/2 5/2 17 549.70 284

3, 1, 2^ 2, 1, Ground 9/2 7/2 17 574.5 284

3, 1, 2^ 2. 1, Ground 9/2 7/2 17 575.24 284

3, 1, 2^ 2, 1, Ground 11/2 9/2 17 643.66 284

3, 1, 2^ 2, 1, Ground 3/2 3/2 17 662.8 284

3, 1, 2^ 2, 1, Ground 1/2 1/2 17 676.2 284

3, 1, 3*- 2, 1, 2 Ground 5/2 3/2 16 976.8 284

3, 1, 3^ 2, 1, 2 Ground 3/2 1/2 17 007.76 284

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 17 033.75 284

3, 1, 3^ 2, 1, 2 Ground 9/2 7/2 17 034.84 284

3, 1, 3^ 2, 1, 2 Ground 11/2 9/2 17 096.08 284

162
lodoethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n f; F' F MHz ±MHz

C'^HaC'^HJ'" 571 3, 1, 3^ 2, 1, 2 Ground 5/2 5/2 17 110.23 284

3, 2, 1-^ 2, 2, 0 ( . m1 1 n H 9/2 7/2 11 1 .J.J. vz .05 283

3, 2, 1«- 2, 2, 0 Ground 7/2 5/2 17 227.84 .05 283

QO, O

Z, Z, 0 Ground 11/2 9/2 17 443.60 .05 283

3, 2, 2*- 2, 2, 1 Ground 9/2 7/2 17 152.32 .05 283

3, 2, 2-^ 2, 2, 1 Ground 7/2 5/2 17 227.84 .05 283

3, 2, 2^ 2, 2, 1 11/2 9/2 1 1 4-oo.Uo .05 283

3, 1, 2-^ 3, 0, 3 Ground 11/2 11/2 26 744. 244

Q 1i. Q /< O, A

^. 3 Ground 11/2 11/2 26 745.74 .05 283

3, 1, 2-^ 3, 0, 3 (iround 5/2 5/2 26 796. 244

3, 1, 2^ 3, 0, 3 Ground 7/2 7/2 26 835.20 .05 283

3, 1, 2«- 3, 0, 3 (\J\.> rAU1HI1 ninH 9/2 9/2 .05 283

3, 1, 2^ 3, 0, 3 Ground 7/2 9/2 26 843.04 .05 283

Q 11, 3 Ground 9/2 9/2 26 845. 244

3, 1, 2<- 3, 0, 3 Ground 5/2 7/2 26 900. 1. 283

3, 1, 2^^ 3, 0, 3 Ground 3/2 5/2 26 928. 1. 283

4, 1, 3^ 3, 1, 2 ( » T(\ 1 1 n fi 9/2 7/2 ZO 4'14'.00 284

4, 1, 3^ 3, 1, 2 Ground 11/2 9/2 23 438.13 284

4, 1, 3<— 3, 1, 2 (Jround 13/2 11/2 23 467.01 284

4, 1, 3-^ 3, 1, 2 (Ground 5/2 3/2 23 474.88 284

4, 1, 4-^ 3, 1, 3 (Ground 7/2 5/2 22 690.03 284

4, 1, 4-^ 3, 1, ao ( ^round 9/2 7/2 ^04"

4, 1, 4^ 3, 1. 3 Ground 3/2 1/2 22 734.40 284

4, 1, 4*- 3, 1, 3 Ground 11/2 9/2 22 740.73 284

4, 1, 4-^ 3, 1, 3 Ground 13/2 11/2 22 759.50 284

4, 2, 2^ 3, 2, 1 Ground 9/2 7/2 23 050.34 .05 283

4, 2, 2-^ 3, 2, 1 Ground 11/2 9/2 93 n'^Q 77 .00 zoo

4, 2, 2^ 3, 2, 1 Ground 7/2 5/2 23 090.64 .05 283

4, 2, 2<— 3, 2, 1 Ground 13/2 11/2 23 167.05 .05 283

4, 2, 3^ 3, 2, 2 Ground 9/2 7/2 23 042.24 .05 283

4, 2, 3^ 3, 2, 2 Ground 11/2 9/2 23 050.34 .05 283

4, 2, 3^ 3. 2, 9 Ground 7/2 5/2 Lo9a fift^ Uoo.Oo^fl .uo 9S^ zoo

4, 2, 3^ 3, 2, 2 Ground 13/2 11/2 23 158.50 .05 283

A4, o

J. 1<— 3, 3, 0 Ground 11/2 9/2 22 968.75 .05 283

4, 3. 1*- 3, 3, 0 Ground 9/2 7/2 22 978.44 .05 283

4, 3, 1^ 3, 3, 0 Ground 7/2 5/2 23 116.56 .05 283

4, 3, l'^ 3, 3, Q Gro und 13/2 11/2 9a 914. an .00 98^

4, 3, 2-^ 3, 3, 1 Ground 11/2 9/2 22 968.75 .05 283

A 3,

o 2<— a, 3, 1 Ground 9/2 7/2 22 978.44 .05 283

4, 3, 2^ 3, 3, 1 Ground 7/2 5/2 23 116.56 .05 283

4, 3, 2^^ 3. 3, 1 Ground 13/2 11/2 23 214.30 .05 283

4, 1, 3^ 4, 0, 4 Gro und 3/2 3/2 Z i U7Z.OU 283

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 27 096. 244

4. 1, 3<- 4, 0, 4 Ground 13/2 13/2 27 110.00 .05 283

4, 1, 3^ 4, 0, 4 Ground 5/2 5/2 27 126. 1. 283

4, 1, 3<- 4. 0, 4 Ground 7/2 7/2 27 161. 1. 283

4, 1, 3*- 4, 0, 4 Ground 7/2 7/2 27 166. 244

4, 1, 3^ 4, 0, 4 Ground 9/2 9/2 27 194.28 .05 283

4, 1, 3^ 4, 0, 4 Ground 11/2 11/2 27 196.26 .05 283

5, 1, 4*- 4, 1, 3 9/2 7/2 29 319.70 284

163
lodoethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

571 5, 1, 4^ 4, 1, 3 7/2 5/2 29 320.60 284

5, 1, 4<- 4, 1, 3 11/2 9/2 29 324.64 284

5, 1, 4-^ 4, 1, 3 5/2 3/2 29 332.26 284

5, 1, 4<- 4, 1, 3 13/2 11/2 29 337.28 284

5, 1, 4*- 4, 1, 3 15/2 13/2 29 357.16 284

5, 1, 5<- 4, 1, 4 Ground 7/2 5/2 28 389.12 284

5, 1, 5<- 4. 1, 4 Ground 9/2 7/2 28 390.42 284

5, 1, 5-^ 4, 1, 4 Ground 11/2 9/2 28 405.78 284

5, 1, 5«- 4, 1, 4 5/2 3/2 28 413.20 284

5, 1, 5<- 4, 1, 4 Ground 13/2 11/2 28 425.40 284

5, 1, 5<- 4, 1, 4 Ground 15/2 13/2 28 433.50 284

5, 1, 4<- 5, 0, 5 hxcited A 0 5/2 5/2 27 430.70 284

5, 1, 4-^ 5, 0, 5 Excited E 0 5/2 5/2 27 432.46 284

5, 1, 4-^ 5, 0, 5 Excited A 0 13/2 13/2 27 501. 284

5, 1, 4-^ 5, 0, 5 Excited E 0 13/2 13/2 27 502. 284

5, I, 4-^ 5, 0. 5 Excited A 0 11/2 11/2 27 528.10 284

5, 1, 4*- 5, 0, 5 Excited E 0 11/2 11/2 27 529.56 284

5, 1, 4^ 5, 0, 5 Ground 5/2 5/2 27 562.46 284

5, 1, 4^ 5, 0, 5 Ground 5/2 5/2 27 565. 244

5, 1, 4^ 5, 0. 5 Ground 9/2 9/2 27 593.5 284

5. 1, 4<— 5, 0, 5 Ground 15/2 15/2 27 595. 244

1, 4<- 5, 0, 5 Ground 7/2 7/2 27 596. 284

I, 4^ 5, o] 5 Ground 7/2 7/2 27 596.0 1. 283

5, 1, 4-^ 5, 0, 5 Ground 15/2 15/2 27 597.48 .05 283

5, 1^ 4«_ 5^ 0, 5 Ground 15/2 15/2 27 597.48 284

5, 1, 4^^ 5, 0, 5 Ground 13/2 13/2 27 638. 244

5, 1, 4*- 5, 0, 5 Ground 13/2 13/2 27 639.18 .05 283

5, 1, 4-^ 5, 0. 5 Ground 13/2 13/2 27 639.18 284

5, 1, 4«- 5, 0, 5 Ground 11/2 11/2 27 663. 244

5, 1, 4-^ 5, 0, 5 Ground 11/2 11/2 27 664.54 .05 283

5, 1, 4^ 5, 0, 5 Ground 11/2 11/2 27 664.54 284

6^ 1^ 5-^ 6^ 0^ 6 Excited 7/2 7/2 28 154.7 .5 284

6, 1. 5-^ 6, 0, 6 Excited A 0 9/2 9/2 28 171.66 284

6, 1, 5<- 6, 0, 6 Excited E 0 9/2 9/2 28 173.18 284

6, 1, 5<- 6, 0, 6 Excited A 0 17/2 17/2 28 186.94 284

6, 1, S'^ 6, 0, 6 Excited E 0 17/2 17/2 28 188.82 284

6, 1, 5^ 6. 0, 6 Excited A 0 11/2 11/2 28 219.44 284

6, 1, 5^ 6, 0, 6 Excited E 0 11/2 11/2 28 221.33 284

6, 1, 5«- 6, 0, 6 Excited A 0 15/2 15/2 28 235.42 284

6, 1, 5«- 6, 0. 6 Excited E 0 15/2 15/2 28 237.20 284

6, 1, 5^ 6, 0, 6 Excited 13/2 13/2 28 246.1 .5 284

6, 1, 5^ 6, 0, 6 Ground 7/2 7/2 28 264.34 284

6, 1, 5^ 6, 0, 6 Ground 9/2 9/2 28 275.88 284

6, 1, 5^ 6. 0, 6 Ground 17/2 17/2 28 291.66 284

6, 1. 5<- 6, 0, 6 Ground 11/2 11/2 28 324.08 284

6, 1, 5*- 6, 0, 6 Ground 15/2 15/2 28 339.12 284

6, 1, 5^ 6, 0, 6 Ground 13/2 13/2 28 347.34 284

164
580 - Ethanol

Ethyl Alcohol C2H6O Cs(C3viCs,Cs)

Molecular Constant Table

CH3CH2OH

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) Dj DjK K A

581 33 326.64 M 9 112.96 M 8 019.39 M -.9136

Id. No. /Xa Debye /At, Debye /ie Debye eQq v.. Acc. Ired OJa d (tic d d

581 1.18 M 1.46 M 0. X 3000

References: ABC: 268

fi: 268

Add. Ref.: 369

Dj: eQq:

Djk:V: 113

k: 268

I:

A:

Ethanol

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

/~"12U /^I2U /~»lfiUI C H3C'''H2U'"'hl 581 1, 0, I*— 0, 0, 0 Ground 17 132.35 268

1, 1, 0-^ 1, 0, 1 Ground 25 307.25 .01 268

2, 1, 1-^ 2, 0, 2 Ground 26 437.15 .01 268

3, 1, 2<- 2, 2, 1 Ground 19 629.0 .1 268

4, 2, 3^ 5, 1, 4 Ground 19 343.9 .1 268

5, 1, 4«— 5, 1, 5 Ground 1 ^ OAA OC 16 399.85 .01 268

6, 2, 4'^ 5, 3, 3 Ground 19 006.19 .01 268

6, 2. 5-^ 5, 3, 2 Ground 21 501. 268

6, 1, 5^ 6, 1, 6 Ground 22 890.95 .01 268

7, 3, 5-^ 8, 2, 6 Ground 18 772.5 .1 268

9, 1, 8<- 8, 3, 5 Ground 23 769. 268

9, 3, 7^ 8, 4, 4 Ground 18 367.8 .1 268

10, 3, 7-^11, 1,10 Ground 20 513.18 .01 268

10, 4, 6-^11, 3, 9 Ground 20 285. 268

10, 4, 7^11, 3, 8 Ground 22 474.13 .01 268

Not Reported 21 572.00 .01 268' Not Reported 22 820. 19 Not Reported 23 081. 19 Not Reported 23 148. 19 Not Reported 23 428.83 .01 268'

Not Reported 23 555. 19 Not Reported 23 605. 19 Not Reported 24 288.71 .01 268' Not Reported 24 295. 19 Not Reported 24 369. 19

Not Reported 24 383.24 .01 268' Not Reported 24 384.04 .01 268 > Not Reported 24 385. 19 Not Reported 25 069. 19 Not Reported 25 307.03 .01 268

Not Reported 26 148.24 .01 268 1 Not Reported 26 436.88 .01 268

1. For the following lines, quoted from Schafer's thesis, limiting J quantum numbers are given as follows: 24,288.71 MHz. J S3 26,148.24 MHz. Js7

21,572.00 MHz. J 3 4 24,383.24 MHz. J s 8

23,428.83 MHz. J & 4 24,384.04 MHz. J 3 8

In all cases. AJ= 0.

749-587 0-69— 12 165
590 - Methoxymetharie

Dimethyl Ether; Methyl Ether CzHgO C2v(CsiC2v»Cs)

Molecular Constant Table

(CH3)20

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) Dj DjK K A

591 38 788.5 M 10 056.6 M 8 886.9 M

592 25 696.4 M 7 483.9 M 6 798.1 M

(C'^D3)(C'2H3)0'« 593 30 912.7 M 8 635.5 M 7 747.7 M

(C"H3)(C'2H3)0'8 Cs 594 38 615.6 M 9 795.6 M 8 673.5 M

595 37 172.1 M 10 058.2 M 8 799.4 M

s-(C'2H2D)(C'2H3)0'« 596 38 281.6 M 9 309.1 M 8 277.9 M

a-CC'^HjDXC'^HslO"' c, 597 34 764.1 M 9 642.3 M 8 537.2 M

Id. No. /Xa Debye iu,h Debye /X(. Debye eQq V3 Acc. I red OJa d aj|, d d (Da d

591

592

0. X

0. X

1.302 M

1.319 M

0. X

0. X

2720

References: ABC: 360

360 eQq:

Djk:

V: 243

166
Methoxymethane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F' F

1 F MHz ±MHz

591 1, 1, 1<- 0, 0, 0 Ground 47 675.4 .2 360

1, 1, 0<- 1, 0, 1 Excited 29 850. 20. 342

1, 1, 0*- 1, 0, 1 Excited 29 880. 20. 342

1, 1, 0«- 1, 0, 1 Ground 29 901.4 .2 360

1, 1, 0<- 1, 0, 1 Excited 29 931. 5. 342

1, 1, 0<- 1, 0, 1 Excited 29 937. 5. 342

1, 1, 0<- 1, 0, 1 Excited 29 946.2 .2 342

1, 1, 0^ 1, 0, 1 Excited 29 957.6 1. 342

1, 1, 0<- 1, 0, 1 Excited 29 971.1 1. 342

1, 1, 0<- 1, 0, 1 Excited 29 976.5 1. 342

1, 1, 0<- 1, 0, 1 Excited 29 990.8 1. 342

2, 0, l'^ 1, 1, 1 Ground 9 119.7 .5 360

2, 1, l'^ 2, 0, 2 Excited 31 055. 5. 342

2, 1, 1«- 2, 0, 2 Excited 31 065. 5. 342

2, 1, 1«- 2, 0, 2 Excited 31 085. 5. 342

2, 1, 1<- 2, 0, 2 Excited 31 090. 5. 342

2, 1, 1<- 2, 0, 2 Excited 31 095.0 .2 342

2, 1, 1-^ 2, 0, 2 Excited 31 103. 1. 342

2, 1, l'^ 2, 0, 2 Ground 31 106.3 .2 360

2, 1, l'^ 2, 0, 2 Excited 31 125. 20. 342

2, 1, 1«- 2, 0, 2 Excited 31 135. 20. 342

2, 1, l'^ 2, 0, 2 Excited 31 145. 20. 342

2, 1, 1^ 2, 0, 2 Excited 31 180. 20. 342

3, 0, 2, 1, 2 Ground 29 092.1 .5 360

3, 1, 2<- 2, 2, 1 Ground 27 629.5 .5 360

3, 1, 3-^ 2, 2, 0 Ground 34 682.5 .5 360

3, 1, 2^ 3, 0, 3 Excited 32 748.4 .2 342

3, 1, 2^ 3, 0. 3 Excited 32 872.9 .2 342

3, 1, 2^^ 3, 0, 3 Excited 32 897.0 1. 342

3, 1, 2«- 3, 0, 3 Excited 32 898.5 1. 342

3, 1, 2<- 3, 0, 3 Excited 32 945. 20. 342

3, 1, 2^^ 3, 0, 3 Excited 32 965. 20. 342

3, 1, 2«- 3, 0, 3 Excited 32 970. 20. 342

3, 1, 1-^ 3, 0, 3 Ground 32 978.5 .5 360

3, 1, 2^ 3, 0, 3 Excited 33 020. 20. 342

3, 1, 2<- 3, 0, 3 Excited 33 030. 20. 342

3, 1, 2^^ 3, 0, 3 Excited 33 060. 20. 342

4, 1, 3^ 4, 0, 4 Excited 35 325. 20. 342

4, 1, 3<- 4, 0, 4 Excited 35 335. 20. 342

4, 1, 3-^ 4, 0, 4 Excited 35 390. 20. 342

4, 1, 3«- 4, 0, 4 Excited 35 525. 20. 342

4, 1, 3^ 4, 0, 4 Excited 35 550. 20. 342

4, 1, 3-^ 4, 0, 4 Excited 35 575. 20. 342

4, 1, 3<- 4, 0, 4 Ground 35 593.4 .5 360

4, 1, 3-^ 4, 0, 4 Excited 35 615. 20. 342

4, 1, 3*- 4, 0, 4 Excited 35 660. 20. 342

T*. 1. 't, U, 4- Ground oo 0 zU.

5, 1, 4<- 5, 0, 5 Ground 39 047.1 .5 360

6, 1, 5^ 6. 0, 5 Ground 43 450. 20. 342

9, 2, 7^ 8, 3, 6 Ground 31 980. 20. 342

167
Methoxymethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

591 12, 3, 9'e-ll, 4, 8 Ground 26 598.6 .2 342 Not Reported Ground 8 060. 1. 342 Not Reported Ground 8 074. 1. 342 Not Reported Ground 8 114. 1. 342 Not Reported Ground 8 165. 5. 342

Not Reported Ground 8 898. 5. 342 Not Reported Ground 8 911. 5. 342 Not Reported Ground 8 955. 5. 342 Not Reported Ground 9 150. 5. 342 Not Reported Ground 23 275. 20. 342

Not Reported Ground 24 310. 20. 342 Not Reported Ground 24 425. 20. 342 Not Reported Ground 28 200! 20! 342 Not Reported Ground 29 430. 20. 342 Not Reported Ground 30 350. 20. 342

Not Reported Ground 32 425. 20. 342 Not Reported Ground 35 030. 20. 342 Not Reported Ground 35 140. 20. 342 Not Reported Ground 36 440. 20. 342 Not Reported Ground 36 450. 20. 342

Not Reported Ground 36 870. 20. 342 Not Reported Ground 37 890. 20. 342 Not Reported Ground 38 660. 20. 342 Not Reported Ground 38 675. 20. 342 Not Reported Ground 38 690. 20. 342

Not Reported Ground 39 800. 20. 342

592 1, 1, 1-^ 0, 0, 0 Ground 32 494.5 .2 360

1, 1, 0«— 1, 0, 1 (rTTillnn 1 8 898 3 2 360

1, I, 0^ 1, 0, 1 Ground 18 912.8 .2 342

2, 0, 2^ 1, 1,1 Ground 10 332.3 .5 360

2, 1, 1-^ 2, 0, 2 Ground 19 603.2 .2 360

3, 0, 3^ 2, 1, 2 Ground 25 223.6 .5 360

3, 1, 2«- 3, 0, 3 Ground 20 695.5 .5 360

4' 1' 3^ 4, 0, 4 Excited 22 072.2 .2 342

4, 1, 3«- 4, 0, 4 Excited 22 081.4 .2 342

4, 1, 3^ 4, 0, 4 Excited 22 208.3 .2 342

4, 1, 3-^ 4, 0, 4 Excited 22 213.6 .2 342

4, 1, 3^^ 4, 0, 4 Ground 22 216.9 .5 360

5, 1, 4^ 5, 0, 5 Ground 24 219.8 .5 360 Not Reported Ground 10 400. 5. 342 Not Reported Ground 10 415. 5. 342

Not Reported Ground 10 425. 5. 342 Not Reported Ground 19 140. 20. 342 Not Reported Ground 19 607.1 .2 342 Not Reported Ground 19 650. 20. 342 Not Reported Ground 19 720. 20. 342

Not Reported Ground 22 045. 2. 342 Not Reported Ground 22 065. 2. 342 Not Reported Ground 24 170. 20. 342

168
Methoxymethane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency 1 Acc. 1 Ref. No. Quantum Nos. State n F,' F' F, F MHz i ±MHz 1

592 Not Reported (Ground 24 180. 1 20. 1 342 Not Reported Ground 24 185. 20. .342 Not Reported Ground .32 185.4 1 -2 342 Not Reported (iround 40 185.4 1 20. 342

(C>^D3)(C'^H3)0>« 593 1, 1, 1^ 0, 0, 0 Ground 38 659. 1 1.0 342

1, 1. 0*— 1, 0, 1 Ground 23 164.9 .2 1 360

1, 1, 0^ 1. 0, 1 Excited 23 175. 20. 1 342

2, 0, 2^ 1. 1, 1 (iround 10 463.1 1 -2 360

2, 1, 1^ 2, 0, 2 Ground 24 078.7 1 .2 1 360

3, 0, 3-^ 2, 1, 2 Ground 27 630.0 1 -1 1 360

4, 1, 3<— 4, 0, 4 Ground z7 47o.b c

1 -O \ ooU Not Reported Ground 24 035. 20. i 342 Not Reported Ground 24 055. 1 20. 1 342 Not Reported Ground 24 075. 20. 342

Not Reported Ground OA lie o^Z Not Reported Ground 24 125. t 20. 1 342 Not Reported Ground 38 6.38. .5 i 342 Not Reported Ground 38 649.5 .5 1 342

(C'^H3)(C'^H3)0"' 594 1, 1, 0^ 1, 0. 1 Ground 29 942.1 2 1 360

2, 0, 2*— 1, 1, 1 Ground 8 086.2 2 1 360

2, 1. 1^ 2, 0, 2 Ground 31 096.3 •2 360

3, 0, 3*- 2, 1, 2 Ground 27 548.3 .5 1 360

3, 1, 2^ 3, 0, 3 Ground 32 887.4 .5 1 360

595 1, 1, 0^ 1, 0, 1 Ground 28 372.7 •2 1 360

1, 1, u*— 1, U, Excited /y boo. OAZU. 1 Q /I O o4Z

1, 1, 0^ 1, 0, 1 Excited 29 660. 20. ! 342

1, 1. 0^ 1, 0, 1 Excited 29 695. 20. 342

1, 1, 0<- 1, 0. 1 Excited 29 710. 20. 342

1, 1, 0^ 1, 0, 1 Excited 29 720. 20. 1 342

1 Ground 10 558.5 1 -2 360

2, 1, 1^ 2, 0, 2 Ground 29 674.3 2 360

3, 0, 3^ 2, 1, 2 Ground 30 503.0 •5 1 360

3, 1, 2^ 3, 0, 3 Ground 31 706.2 .5 360

s-(C'2H2D)(C'2H3)0"' 596 1, 1. 0^ 1, 0, 1 Ground 30 003.6 1 -2 i 360

2, 1, 1<— 2, 0, 2 Ground 31 061.8 1 -2 1 360

3, 0, 3^ 2, 1, 2 Ground 24 684.6 •2 360

3, 1, 2^ 3, 0, 3 Ground 32 699.5 1 -5 360

5, 1, 5-^ 4, 2, 2 Ground 8 828.6 .5 360

Not Reported Ground 8 890. 5. 1 342

INot neported Ground o nc

A

1 5. 1 342 Not Reported Ground 8 960. 5. 342 Not Reported Ground 24 640. 1 20. 342 Not Reported Ground 24 660. 20. 342

Not Reported Ground 24 700. 1 20. 1 342 Not Reported Ground /oU. OA

1 zu. 1 Q /I O o4Z Not Reported Ground 24 785. 1 20. 1 342 Not Reported Ground 24 875. 20. 342 Not Reported Ground 24 900. 1 20. 1 342

Not Reported Ground 24 980. 20. 1 342

169
Methoxymethane

Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rotor

State n f;

riype F'rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

s-(C'2H2D)(C'2H3)0'« 596 Not Reported Ground 24 995. 20. 342 Not Reported Ground 25 000. 20. 342 Not Reported Ground 25 020. 20. 342 Not Reported Ground 25 030. 20. 342 Not Reported Ground 25 035. 20. 342

Not Reported Ground 27 200. 20. 342 Not Reported Ground 27 240. 20. 342 Not Reported Ground 27 250. 20. 342 Not Reported Ground 27 290. 20. 342 Not Reported Ground 27 325. 20. 342

Not Reported Ground 29 135. 20. 342-

Not Reported Ground 29 140. 20. 342 Not Reported Ground 29 150. 20. 342 Not Reported Ground 29 520. 20. 342 Not Reported Ground 29 535. 20. 342

Not Reported Ground 29 540. 20. 342 Not Reported (jround 29 550. 20. 342 Not Reported Ground 29 555. 20. 342 Not Reported Ground 29 560. 20. 342 Not Reported Ground 29 590. 20. 342

Not Reported Ground 29 600. 20. 342 Not neported Ground 29 630. 20. 342 Not Reported Ground 29 680. 20. 342 Not Reported Ground 29 730. 20. 342 Not Reported Ground 29 835. fo. 342

Not Reported Ground on ooA zy ooU. ZU. 342 Not "^.eported Ground 29 895. 20. 342 Not Reported Ground 31 000. 20. 342 Not Reported Ground 31 200. 20. 342

597 1, 1, 0^ 1, 0, 1 Ground 26 226.9 .2 360

2, 0, 2-^ 1, 1, 1 Ground 11 201.6 .2 360

2, 1, 1^ 2, 0, 2 Ground 27 367.7 .2 360

3, 0, 3<- 2, 1, 2 Ground 30 343.3 .5 360

3, 1, 2^ 3, 0, 3 Ground 29 145.4 .5 360

r

170
600 - Dimethyl Sulfide Molecular Constant Table

Methylthiomethane; Methyl Sulfide C,H,S C2v(C3„C3„C2,,) (CH;,)2S

Isotopic Species Pt. Gn

Id. No. A (MHz) B (MHz) C (MHz) Dj K A

,pi2fr \ C32 Co 601 17 809.82 M 7 621.03 M 5 717.79 M 6.3049

C2V 602 17 398.72 M 7 621.36 M 5 674.63 M 6.3002

C'^HjS^^c'^Hj Cs 603 17 612.44 M 7 412.37 M 5 579.66 M 6.3016

s-C'^H^DS^^C'^Ha Cs 604 17 794.97 M 7 069.04 M 5 401.69 M 6..3.344

a-C'^HzDS^^c'^Hj c, 605 16 557.01 M 7 335.25 M 5 512.05 M 7.6369

C'^HjS^^C'^Dj Cs 606 15 480.51 M 6 595.97

• M 5 067.40 M 9.5369

Id. No. /Lta Debye /u-h Debye fj.^ Debye eQq V3 Acc. I red a>a d aji, d oji- d oju d

601 0. X 1.50 M 0. X 2132 6

606 2118 3

References: ABC: 332 Dj: Djk: k: A: 332

M: 332 eQq: V: 332 I: w:

Add. Refs: 279, 311. 334

For species 601, the coupling parameter is: la = 3.204 amu A^. For species 606, the couphng parameters are: Iq, = 3.204 amu A^, and la =6.403 amu A^. Its rotational constants for first excited tor- sional states are: for CD3, A = 15486.59 MHz, B = 6570.58 MHz, and G = 5060.61 MHz; for CH3, A = 15409.49 MHz, B = 6564.46 MHz, and C = 5057.68 MHz. Ref: 332.

171
Dimethyl Sulfide Spectral Line Table

Isotopic Species Id. Rotational Vih State Tnt Rnt<»r Hyperfine Frccjucncy Acc. ftrvei. of No. Quantum Nos State n

IT' XT' r r MHz

601 1 l<— u. u. 0 Ground 23 527.26 .05 356

1, 1*— AU, A0 Ground 23 527.50 .05 356 { 1. 1*- 0. 0, 0 Ground A A fl ZO90 OZC97 f.(\ i .ou .UD ooZ

1- 1. 1^ 0, 0, nu Ground Zo DZ I . i 0 .UD oDO

1' 1, o<— 1, 0, 1i Ground 1IZ9 noi UVi. 79/ z .uo oDO

1' 1, o<— 1, 0, 1 Ground 12 091.96 .05 356

1, o<— 1, 0, 1 Ground AA 0 12 092.03 .05 332

i; 1, 0^ 1, 0, 11 Ground 1 9 009 90 iZ UVZ.ZU oc: oDO

2] 0, 2^ 1, 1, 11 Ground 1 A 9/1 19 oc; .UD ODD

2, 0. 2<— 1. 1, 1i Ground A A n 9d.^ 97 0"^ .UD ddZ

2, 0, 2-^ 1, 1, 1 Ground 16 246.28 .05 356

2, 0, 2^^ 1, 1, 1 Ground 16 246.45 .05 356

2, 1, 2^ 1, 0, 1 Ground- 04- OA. QMVOZ.oZQ9 .UD ODO

2, 1, 2<- 1, 0, 11 Ground 04* VOo.UD .UD oDO

z. 1,

o.^ 1, A

u.

11 Ground OA, Qf,0 90 .UD DDO

2, 2, l*— 1. 1. 0 Ground 59 144.77 .05 356

2, 2, 1<— 1. 1, 0 Ground 59 144.89 .05 356

2, 2, 1^ 1. 1. Ground J7 140.00 .uo 000

2, 2, 1^ 1. 1. 0 Ground 07 14U. OZ .uo 000

2, 1. 1*— 2. 0. Ground 1/1 14 zo9^71 .uz ^i9 .uo 000

2, 1, 1<— 2, 0, 2 Ground AA 0 14 237.82 .05 332

2, 1, 2, 0, 2 Ground 14 237.88 .05 356

2, 1, 1^ 2, 0, 9 Ground 14 ZOO. 10 .UD 000

2, 1, 2^ 2, 2. 1 Ground 19IZ 114Z.OO d.9 .UD 000

2. 1, 2<— 2. 2. 1 Ground 19IZ 1140. d."? Oi^7 .UD 000

2, 1, 2*— 2, 2, 1 Ground 12 143.86 .05 356

2, 1, 2<— 2, 2, 1 Ground 12 143.99 .05 356

2, 2, 0^ 2. 1. 1 Ground OA Oflf. fLQ oU OUO.OV .Uo ODD

2, 2, 0^ 2, 1,

11 Ground QA QAA Qa OU OUD.OO .Uo ODO

2, 2, O-*— 2. 1, 11 Ground ovan 807 OU 1 .00 .uo oou

2. 2, o<— 2, 1, 1 Ground 30 807.95 .05 356

2, 2, 2, 1, 2 Ground 36 273.68 .05 356

2, 2, 1^ 2, 1, 9 Ground OUOf, z97a1 0 ,01 Ql .uo OOU

2, 2, 1^ 2, 1, 9 Ground Of, 97d t;n OU Z ( 4.0U .Uo OOU

2, 2, 1<— 2, 1, z9 Ground aft 97r; 91; OU z / o.zo .uo OOU

3, 0. 3<— 2. 1, 2 Ground 30 542.49 .05 356

3, 0, 3*— 2. 1, 2 Ground 30 542.60 .05 356

3, 0, 3^ 2, 1, z9 Ground OUan 04Z. CA9 70( U 05 356

3, 1, 2^ 3. 0, C^round II 7I S7<1 0 / 4. Q870 .uo 356

3. 1. 2^ 3. 0, a0 Grou nd I . I . u 1J. 7J R7^ 0 J (J 98 05 332

3, 1. 2<— 3, 0, 3 Ground 17 875.29 .05 356

3. 1, 2^^ 3, 0, 3 Ground AA 0 17 875.58 .05 332

3 2<— 3 0, Ground 1Li7 87"^ 0 f>^ t O.Ul • Uo OOU

3!

2' 1^ 3!

1' 9 Ground 90 flfin 9R .uo OOU

3, 2, 1^ 3. 1, 9z Ground zv uuu.ou .uo OOU

3, 2, 1^ 3, 1, 2 Ground 29 061.45 .05 356

3, 2, 2^ 3, 1, 3 Ground 39 272.12 .05 354

3, 2, 2<- 3, 1, 3 Ground 39 272.87 .05 356

3, 2, 2^ 3, 1, 3 Ground 1 39 273.64 .05 356

4. 1, 3^ 3. 2. 2 Ground 28 738.25 .05 356

i

172
Dimethyl Sulfide Spectral Line Table

Isotopic Species Id. IXULcLLIUIlctl nil. I\UIUI Hyperfine Ref. No. Qusntum Nos St3.tc n F' F'r

IT ITr ±MHz

601 4, 1, 3«- 3, 2, 2 Ground 28 7.38.69 .05 356

4, 1, 3-^ 3, 2, 2 Ground 28 7.39.14 .05 356

4 2 3<_ 4 Q 4 Ground zo9^ ^'^^ 9'^ 000.zo n'; oou

4, 2 3«_ 4 Q 4 Ground 93 91:3 Q1 zo 000.0

n'^ ooz ^^9

1, T", U, d4 Ground 93 3i;3 f.A, zo 000.04 n'^ OOU

4, 1. 3<- 4, 0, 4 Ground EE 0 23 353.66 .05 332

4, 1, 3«- 4, 0, 4 Ground AA 0 23 3.54.03 .05 332

A, 1 a«_ 4, n 4 Ground ZO 004.U.J n^ 000

I", 4", 1, 3O Ground 97 Q39 HQ .uo 000

d. 9 9«— d 1 QO Ground z97 fi^9 fi^ / ooz.uo O.0U

4, 2, 2^ 4, 1, 3 Ground 27 833.20 .05 356

4, 2, 3^ 4, 1, 4 Ground 43 321.37 .05 356

A, 9 Q< A, 1 Z, 4-, i. d4 Ground AO 399 TO 40 ozz.io .uo n'^ 000

d Z,9 d 1 4", 1, d4 Ground d940 ozz. 999 0870 .uo oou

A, O,9 11^<— d4", Z,9 9 Ground 00 left 100. 711 X .uo n'^ oou

4, 3, 1^ 4, 2, 2 Ground 53 189.22 .05 356

4, 3, 1^ 4, 2, 2 Ground 53 189.91 .05 356

A 9 1 «— d 9 9 Ground 00 ion 171,/, ft'^ 00 .uo n^i oou

d4", O,^ Z^9^^ d4, 9Z, O Ground OU 407.U7 .uo n'^ oou

d4*. O,^ 9<— Z^ d4, 9Z. o Ground OU 407..J7 .UO n'^ OOU

4, 3, 2^ 4, 2, 3 Ground 56 460.57 .05 356

4, 3, 2^ 4, 2, 3 Ground 56 461.78 .05 356

J, Z, 4, O, 9 Ground A A n 11 7( (17^ v ( 0.0^i71 .uo n'l OOZ

O, Z. 4, O, 9 Ground 1,1. \) 11 7/ n7d U i 4. 70( u .uo ooz ^^9

O, Z, 4, O, 9 Ground 11 7/ 07"^ yj 1 0.40d"^ .uo n'^ ooz ^^9

5, 2, 3*- 4, 3, 2 Ground EA 0 17 075.97 .05 332

5, 1, 4^ 5, 0, 5 Ground 30 822.84 .05 356

O, 1, T-* o, u.

co Ground 30 Q93 39 .uo 000

O, 1, 4^ O, u.

c: o Ground 30 »93 so .uo 000

O, Z. O, 1, d4 Ground 97Z J 7R7 / 0 / .V/7 no • UO OOU

5, 2, 3^ 5, 1, 4 Ground 27 787.63 .05 356

5, 2, 3^ 5, 1, 4 Ground 27 788.17 .05 356

O,^ 9Z, d<— 4^ O, 1i.

i:; •J Ground dS40 dlS 410.048d .uo oou

1^ 9 d*— 1 O, Z, 4^ .J, i. o Ground dft 40 dlQ 41V. 79/ Z .uo n'^ oou

^ 9 d<— 1 O, Z, 4^ O, 1,

c:o Ground dft 40 d9n 4ZU.UUf\(\ .uo n'l oou

5, 3, 2^ 5, 2, 3 Ground 50 797.50 .05 356

5, 3, 2^ 5, 2, 3 Ground 50 798.49 .05 356

o, o,^ z^9<— o, z.9

•3 Ground qO 700 dS .uo n'^ oou

3 Ground 171 i nd7 U4 i .00 ^'i .05 356

6 1 6<— 5 2 3 Ground AA 0 11 7/ nd7 V/4 i .0^71 05 332

6, 1, 6^ 5, 2, 3 Ground 17 048.23 .05 356

6, 1, 6^ 5, 2, 3 Ground EE 0 17 048.25 .05 332

6 1 6<— 5 2, 3 V71 UUIIU 17 049.12 .05 356

6 2 4^^ 5 3 3 1 -rr\i in lA V7I UUliU 04^d Vi'^9 uoz.oo^'i .05 356

f>O, 9Z, d«— 4^ O, O,^

3O Ground 3A fiCS IQ 04 000. 17 .uo n'^ oou

6, 2, 4^ 5, 3, 3 Ground 34 653.95 .05 356

6, 2, 4*- 5, 3, 3 Ground 34 654.08 .05 356

6, 2, 5^ 5, 3, 2 Ground AA 0 20 768.25 .05 332

6, 2, 5^ 5, 3, 2 Ground 20 768.31 .05 356

6, 2, 5-^ 5, 3, 2 Ground EE 0 20 769.17 .05 332

173
Dimethyl Sulfide Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F' F F MHz ±MHz

601 6, 2, 5<- 5, 3, 2 Ground 20 769.23 .05 356

^10, 2,O 5«— C ^ 5,COO3, 2 Ground 20 770.09 .05 332

6, 2, 5^ 5, 3, 2 Ground 20 770.10 .05 356

6, 2, 5^ 5. 3, 2 Ground 20 770.21 .05 356

6, 1, 5^ 6. 0, 6 Ground 40 068.47 .05 356

6, 1, 5^ 6, 0, 6 Ground 40 069.09 .05 356

6, 1, 5<— 6, 0, 6 Ground 40 069.70 .05 356

6, 2, 4^ 6, 1, 5 Ground 29 452.88 .05 356

6, 2, 4^ 6, 1, 5 Ground 29 453.41 .05 356

6, 2, 4^ 6, 1, 5 Ground 29 453.93 .05 356

6, 2, 5^ 6, 1, 6 Ground 54 518.60 .05 356

6, 2, S"— 6, 1, 6 Ground 54 519.54 .05 356

6, 2, 5^ 6, 1, 6 Ground 54 520.48 .05 356

6, 3, 3^ 6, 2, 4 Ground 47 775.11 .05 356

6, 3, 3^ 6, 2, 4 Ground 47 776.06 .05 356

6, 3, 3^ 6, 2, 4 Ground 47 777.01 .05 356

6, 3, 4*— 6, 2, 5 Ground C f\ COO AA 59 588.00 .05 356

6, 3, 4^ 6, 2, 5 Ground 59 589.10 .05 356

ij 6, 3, 4^ 6, 2, 5 Ground 59 590.19 .05 356

li

! 6, 4, 3*- 7, 3, 4 Ground AA 0 20 590.99 .05 332

• 6, 4, 3«- 7. 3. 4 Ground EE 0 20 592.70 .05 332

6, 4, 3^ 7, 3, 4 Ground AE 0 20 593.52 .05 332

6, 4, 3^ 7, 3, 4 Ground EA 0 20 595.36 .05 332

7. 1, 7^ 6, 2, 4 Ground 16 647.89 .05 356

7, 1, 7^ 6, 2, 4 Ground 16 648.91 .05 356

7, 1, 7-^ 6, 2, 4 Ground 16 649.94 .05 356

7, 2, 6<— 6, 3, 3 Ground 30 398.95 .05 356

7, 2, 6^ 6, 3, 3 Ground 30 399.88 .05 356

7, 2, 6^ 6, 3, 3 Ground 30 400.80 .05 356

7, 3. 5^ 6, 4. 2 Ground EE 0 16 892.80 .05 332

7, 3, 5^ 6, 4, 2 Ground 16 894.33 .05 332

i 7, 3, 5<- 6, 4, 2 Ground AA 0 76 891.91 .05 332

7, 1, 6<- 7, 0, 7 Ground 50 547.58 .05 356

j 7, 1, 6^ 7, 0, 7 Ground 50 548.33 .05 356

7, 1, 6^ 7, 0, 7 Ground 50 549.11 .05 356

7, 2, 5^ 7, 1, 6 Ground 33 210.66 .05 356

7, 2, S'^ 7, 1, 6 Ground 33 211.20 .05 356

7, 2, 5^ 7, 1, 6 Ground 33 211.73 .05 356

7, 2, 6^ 7, 1, 7 Ground 61 526.00 .05 356

7, 2, 6^ 7, 1, 7 Ground 61 527.05 .05 356

7, 2, 6^ 7, 1, 7 Ground 61 528.10 .05 356

7, 3, 4^^ 7, 2, 5 Ground 44 762.10 .05 356

7, 3, 4^ 7, 2, 5 Ground 44 762.99 .05 356

7, 3, 4^ 7, 2, 5 Ground 44 763.86 .05 356

7, 3, 5^ 7, 2, 6 Ground 62 433.00 .05 356

7, 3, 5^ 7, 2. 6 Ground 62 434.12 .05 356

7, 3, 5<- 7. 2, 6 Ground 62 435.22 .05 356

8, 2, 7^ 7, 3, 4 Ground 37 805.82 .05 356

'

8, 2, 7^ 7. 3, 4 Ground 37 807.71 .05 356

8, 2, 7^ 7, 3, 4 Ground 37 846.77 .05 356

174
Dimethyl Sulfide Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n

1 F/ iyperfine

F' 1 F,

1

F

Frequency

MHz

1 1 Acc. 1 ±MHz

1

Ref.

601 8, 1, 7<— 8, 0, 8 Ground 1 61 .594.68 .05 1 356

8, 1, 7*— 8, 0, 8 Ground 61 59.5.62 .05 1 356

8, I, si 0! 8 Ground 61 596.57 .05 1 3.56

8, 2, 6-^ 8, 1, 7 Ground 39 285.65 .05 1 356

8, 2^ 6<— 8, 1, 7 Ground 1

1 39 286.23 .05 1 356

8, 2, 6<— 8, 1. 7 Ground 1 39 286.80 .05 1 356

8, 3^ 5«_ 8^ 2, Ground 42 572.36 .05 j 356

8^ 3! 5^ 8! 2, 6 Ground 42 573.17 05 356

8, 3, 5«- 8, 2, 6 Ground 1 42 573.97 .05 356

9 2 8*— 8 3 5 Ground 1

1 42 361.59 [ .05 356

9 2. 8<— 8, 3, 5 Ground 1 42 362.56 1 .05 356

9 2, 8<— 8 3, 5 Ground 42 363.55 .05 356

9^ 2, 7^ 9! \\ 8 Ground 47 641.04 .05 356

9, 2, 7^ 9, 1, 8 Ground 1 47 641.70 .05 356

9^ 2, 7<— 9, 1, 8 Ground 1

1 47 642.37 •05 356

9^ 3, 6<— 9, 2, 7 Ground 1 41 972.48 ! .05 356

9^ 3, 6<— 9, 2, 7 Ground 41 973.22 .05 1 356

9, 3^ 6^ 9^ 2! 7 Ground 41 973.95 i .05 1 356

10, 2, 9^ 9, 3, 6 Ground 1 43 636.47 1 .05 356

10, 2, 9<— 9, 3, 5 Ground 1

1 43 637.52 1 .05 356

10, 2, 9*— 9, 3, 5 Ground 1 43 638.57 .05 1 356

10, 5, 5^ 9, 6, 4 Ground AA 0 14 515.57 .05 332

lo! si 5^ 9^ 6^ 4 Ground EE 0 14 517.27 i .05 332

10. 5, 5^ 9, 6, 4 Ground 1 14 518.96 .05 332

10, 2, 8*—10, 1. 9 Ground 1

1 57 887.28 05 356

10, 2^ 8<— 10, 1, 9 Ground 1 57 888.07 1 .05 1 356

10, 2, 8^10, 1, 9 Ground 57 888.86 .05 356

lo! 3^ 7^10! 2, 8 Ground 43 543.45 .05 356

10, 3, 7^10. 2. 8 Ground 1 43 544.14 .05 356

10, 3, 7*—10, 2, 8 Ground 1

1 43 544.84 .05 356

10, 4, 6«—10, 3, 7 Ground 1 63 236.56 1 OS 1 356

10, 4 6<—10 3 7 Ground 63 237.73 .05 356

lo! 4^ 6^10! 3! 7 Ground 63 238.90 .05 356

11, 2,10^10, 3, 7 Ground 1 41 529.13 05 356

11, ^ 7 X V/ '--'1 '-'4 7 Ground 1

1 41 530 31 1 .05 356

11, 2,10<—10, 3, 7 Ground 1 41 531.49 1 .05 1 356

11, 3, 8*—11, 2, 9 Ground 47 653.80 05 356

ii! 3] 8-^11! 2' 9 Ground 47 654.47 1 .05 1 356

11, 3, 8-^11, 2, 9 Ground 1 47 655.14 .05 1 356

11, 4, 7'^11, 3, 8 Ground 1

1 59 181.48 .05 i 356

11, 4, 7^11, 3. 8 Ground 1 59 182.54 i .05 356

11, 4, 7^11, 3, 8 Ground 59 183.59 .05 i 356

12! 2,11^11. 3. 8 Ground 36 258.98 .05 356

12, 2,11^11. 3. 8 Ground 1 36 260.33 .05 356

12, 2.11^11, 3. 8 Ground 1

1 36 261.67 .05 356

12, 3, 9-^12, 2.10 Ground 1 54 439.22 05 1 356

12, 3, 9^12, 2,10 Ground 54 439.92 05 356

12, 3, 9^12, 2,10 Ground 54 440.61 1 .05 1 356

12, 4, 8^12. 3. 9 (Ground 56 285.75 1 .05 1 356

12, 4, 8^12. 3, 9 Ground 56 286.69 i .05 i 356

175
Dimethyl Sulfide Sp^^^^^j ^.^^

Isotopic Species

1 Id.1 Rotational1 Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F, F MHz ±MHz

601 12, 4, 8^12, 3, 9 Ground 56 287.63 .05 356

13 2 12-^12 3 9 O'l OOO

13, 2,12^12, 3, 9 Ground 28 279.87 .05 356

13, 2,12<-12, 3, 9 Ground 28 281.45 .05 356

14, 2,13«-13, 3.10 Ground 18 1 99 20 .05

14, 2,13^13, 3,10 Ground 18 201.03 .05 356

14, 2,13^13. 3.10 Ground 18 202.86 .05 356

|pl2IJ ) C34 602 1, 1, 1-^ 0. 0. 0 1 -wTcw I n H 0^

\\ \\ 0*- \\ o\ 1 Ground 11 724.09 .05 332

2, 1, 1^ 2, 0. 2 Ground 13 933.60 .05 332

3, 1. 2<- 3. 0, 3 Ground 17 697.30 .05 332

PISLT C32pl2I-f 603 1, 1, 1^ 0. 0, 0 ( -wrrti 1 n

H

2'^ 102 10 .05 ^^2

1^ 1^ 0^ \\ q\ 1 Ground 12 032.78 .05 332

2. 1. 1^ 2, 0, 2 Ground 14 090.96 .05 332

3. 1, 2^ 3, 0, 3 Ground 17 569.40 .05 332

s-C'^H^DS^^C'^Hs 604 1. 1, 1^ 0, 0. 0 Ground 23 196.66 .05 332

1, 1, O'^ 1, 0, 1 ( vTrt nn H 1 2 '^Q'^ 2ft .05 332

2, q\ 2^ \\ \\ 1 Ground 14 035.40 .05 332

9 1 1^ 2 0 2 1 -wTCi 1 1 n H 1XT'4 240 ^0 .05 332

3, 1, 2^ 3, 0, 3 Ground 17 327.39 !05 332

4, 1, 3^ 4, 0, 4 Ground 21 947.29 .05 332

605 1, 1, 1^ 0, 0, 0 Ground 22 069.05 .05 332

1, 1, 0^ 1, 0, 1 Ground 11 044.96 .05 332

2, q\ 2^ \\ l\ 1 Ground 16 228.21 !05 332

2, 1. l'^ 2, 0, 2 13 1 12 72 .05 332

3^ \, 2<- 3^ 0^ 3 Ground 16 633.37 !05 332

4, 1, 3^ 4, 0, 4 Ground 21 942.79 .05 332

C'^HjS^^C'^Da 606 1, 1. 1^ 0. 0, 0 Ground A 20 547.20 .05 332

2^ 0, 0, 0 i\ji.t"iUilUIIU 1 n H A 0 20 547 90 .05 332

\\ \\ 1^ o! 0^ 0 Ground E 20 553.47 !05 332

1. 1, 0*- 1. 0, 1 Ground A 0 10 413.11 .05 332

1, 1, 0^ 1. 0. 1 Ground A 10 425.98 .05 332

1. 1. 0^ 1, 0, 1 Ground A 10 432.81 .05 332

1, 1, O'^ 10 1 £ 10 441 92 .05 332

2, oi 2^ \\ \\ 1 Ground A 0 14 261.38 !05 332

2, 1, 1^ 2, 0, 2 Ground A 12 111.96 .05 332

2, 1. 1*- 2. 0. 2 Ground A 12 114.76 .05 332

2, 1, 1^ 2, 0, 2 Ground A 0 12 122.46 .05 332

0 11, 11^ 0 nV/, ^2 1 _TTii in H 12 123 88 .05 332

3. 1. 2^ 3. 0, 3 Ground A 14 943.65 .05 332

3, 1, 2^ 3, 0, 3 Ground A 14 949.04 .05 332

3. 1. 2^ 3, 0, 3 Ground E 14 954.42 .05 332

3, 1. 2*- 3, 0, 3 Ground A 0 15 001.68 .05 332 4 1 4 0 4 VtI OUliU 19 190.49 .05 332

4, 1, 3^ 4. 0. 4 Ground E 19 204.21 .05 332

4, 1, 3<- 4, 0, 4 Ground A 1 19 206.75 .05 332'

4, 1, 3^ 4, 0, 4 Ground E 0 1 19 327.03 .05 332

4, 1. 3<- 4. 0, 4 Ground A 0

1

1 19 327.31 1 .05 332

5, 1. 4^ 5, 0, 5 Ground A 25 040.66 .05 332

5, 1, 4^ 5, 0, 5 Ground A 0 1

1 25 249.00 1

i .05

i 332

r

176
610 -Vinyl Silane Molecular Constant Tahle

Ethenylsilane; Ethylene Silane; Ethenesilicane CjHeSi QCs.Cav) CHjiCHSiH^

Isotopic species Pt Gp.Id. No. A (MHz) B(MHz) C (MHz) D, A

Si^sHjC'^HrC'^Hj Cs 611 34 159. M 5 275.20 M 4 820.80 M

Cs 612 24 703.00 M 4 773.26 M 4 404.48 M

Si^'HsC'^HiC'^H^ Cs 613 5 214.40 M 4 769.61 M

Cs 614 5 156.96 M 4 721.31 M

Si2»H3C'3H:C'2H2 Cs 615 5 249.80 M 4 787.15 M

Si='«H3C'2D:C'2H2 Cs 616 5 232.29 M 4 673.35 M

c-Si2«H3C'2H:C'2HD Cs 617 5 137.09 M 4 625.41 M

t-Si28H3C'='H:C'2HD Cs 618 4 888.84 M 4 496.24 M

Cs 619 5 214.80 M 4 666.31 M

a-Si2»H2DC'^H:C'-H2 c, 621 5 035.33 M 4 669.87 M

Cs . 622 4 815.64 M 4 539.21 M

c, 623 4 984.80 M 4 526.28 M

Si28H3C'^H:C"H2 Cs 624 5 114.83 M 4 682.70 M

Id. No. ^la Debye /Ah Debye jU,^. Debye eQq V3 Acc. I red OJa d cji, d (u^. d (jja d

611 0.648 M

1 0.133 M 0. X 1500 30

References: ABC: 331 Dj: Djk: k: A:

fi: 331 eQq: V: 331 I: oj:

Coupling Parameter, Ia= 5.7923 amu A^. Ref: 331.

177
Vinyl Silane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. ( iti!intii m Mnc State n F' i F' 1 F 1 F ivxn/ —ivinz

>_7i 1 A3*-' IX. ' '2 611 1 f) 1 <— 0 0 0 K7L U UllU. A 1 1XOn nRQ V/OV.7O Q^i .00 00 1 1, 0, 1^ 0. 0, 0 Ground E 1 10 090.73 .05 331

1, 0, 1-^ 0, 0, 0 Ground 10 095.99 .05 331

1, 1, 0*~ 1, 0, 1 Ground E 0 29 337. 10. 331

1, 1, 0^ 1, 0, 1 Ground A 0 29 343. 10. 331

0 0 o<_ 1 0 1

4 \J ^ ^ \J, 1

1 _frki 1 n r1 Vxl UUllU A 1 on 1 yd 7c: ZU X i 4'. J 0 .uo 00

1

2, 0, 2<- 1, 0, 1 Ground E 1 20 176.20 .05 331

2, 0, 2<- 1, 0, 1 Ground 20 186.62 .05 331

2, 1, l'^ 1, 1, 0 1vJl-rrii (JUlI nlUH E 1 zo 000.0 0=^ •Uo

2, 1, 1<— 1, 1, 0 1 —TTiii n r\ yjfl tJUllU A 1 zo9n ft91 uzx.o8 0^

2 1, 1«— 1, 1, 0 1 _ T"/^ 1 1 n ri V7l UUIIQ ZU90 f\Af\ U4U.40d^ .vjo 001

2] 1] 2<- 1" 1' 1 Ground 19 737.64 .05 331

2, 1, 2^ 1, 1. 1 Ground A 1 19 738.6 .05 331

2 1 2<— 111 Ground FHi 1X IQly S'^^ 000.7Q O'^ 00

1

01 1 <_ 0 n 0

^4 1^ 1 ^4 ^ 1KjL— TTki U UlIU. 1 n H E 0 90 784. 1 n ^^1

vrrounQ A n on 70Q Z7 toy. 1

0

00

1

7, 1, 6^ 7, 1, 7 Ground E 0 12 714.59 .05 331

7. 1. 6^ 7, 1, 7 Ground A 0 12 715.13 .05 331

- 8 1 7<— 8 18 Ground HiF n0 Ift xo 000. ^^R 77/ 1 .uo n"^ 001

8 1 7*— 8 18 Ground A 0 1ft xo 007.4- '?^Q d7( .uo n=i 001

9. 1, 8^ 9, 1, 9 Ground E 0 20 408.43 .05 331

9, 1, 8^ 9, 1, 9 Ground A 0 20 409.38 .05 331

10, X, ^ ^ Jto, 1,10 1 _i"r»i 1 n iH E 0 24 919.07 .05 001

inio, 11, Q«—in10, 11,10in Ground A 0 Z^9d 09n 7ZO.ZO90 .00 O^i oox ^^1

c:28r) (--120. (--1214 612 1 n 1 <— 0 n n VTl (J UlUJ A 1 9 174.9 .05 oox ^^1

1, 0, 1^ 0. 0, 0 Ground 9 177.78 .05 331

1. 1. 0^ 1, 0, 1 Ground 20 298.50 .05 331

9 n 9<— 1 n 1 Ground i\A 1X 1xo8 Ot-^.^O ^d.d Q'i .uo n'^ 001 ^^1 2 0 2<— 10 1 Ground xo 000.04* .05 "1^1 001

2 1 1<— 110 vxround E 1 18xo 7ni (OX .zo 9n .uo n'^ oox

2, 1" 1<- 1" 1! 0 Ground A 1 18 702.11 .05 331

2, 1, 1^ 1, 1, 0 Ground 18 724.23 .05 331

Z,9 1X, 9-^ 1X, 1X, n0 Ground A 1 1 7 QOft 7

1

X 1 yylj. I X .uo 00^^1

1

Z,9 1 9<— 1 1 f> X, X, X, 0 Ground V 1 £j X

1X 7( 007 yy 1 .00 8^ .uo n'; 00^^1i

2, 1, 2^ 1, 1, 1 Ground 17 986.70 .05 331

2, 1, 1^ 2, 0, 2 Ground 20 672.34 .05 331

1 9<— n ^ 0, X, z^ 0, 0, 0 Ground 91 949 S4 .05 331

4,4*, 1X, 0^Q«_ d.4-, n d 0, 4" Ground 99 090 "^1 05 001 ^^1

613 2, 0, 2<r- 1, 0, 1 Ground 19 962.92 .10 331

z,9 11 , 11

<*11 , in1 , u Ground 9nzo 414XZ.OX 9 81 10 oox

z,9 11 , z*9< 111 1 , 1 , 1 Ground IQX7 ozo.zz "19^ 99 10 331

Si3''H3C'^H:C'-^H2 614 2, 0, 2^ 1, 0, 1 Ground 19 751.60 .10 331

9Z, 1X , 1X <—^ 1X , inX , u Ground zo9n 1Q9 X7Z.ZO9'i .10 331

9Z, 1X , Z^9<— 111 X , X , X Ground 1^10 0Z0.7X ^9n 01 .10 331

Si^'HjC'^HiC'^H., 615 2, 0, 2^ 1. 0, 1 Ground 20 067.88 .10 331

2, 1. 1^ 1, 1, 0 Ground 20 536.54 .10 331

2, 1. 2^ 1, 1, 1 Ground 19 611.24 .10 331

178
Vinyl Silane Spectral Line Table

Isotopic Species Id. Nr. Rdtational Quantum Nos.

1

1 Vib. State Int. Rotor

btate n

1

1 Hyp<

f

;rfin(

f", F

Frequency

MHz

1 Acc. ±MHz

Ref.

Si-^«H3C"2D:C'2H2 61G 2, 0, 2<- 1, 0. 1 (Ground 19 801. .56 .10 331 oil ^ 1 1 n l»round 1 20 370.22 .10 .331 O 1 111 l^round 19 252.34 .10 331

c-Si^"H:,C'2H:C'-^HD 617 2,oil0, 2^ 1, 0, 1 (Ground 19 517.07 .10 331

^ 1 1 n (iround 9A AO/; fx> zu UoO.Oo .10 331

O 1 Orfi 111 Ground 19 013.32 .10 .331

t-Si2"H3C'2H:C'2HD 618 2, 0, 2-^ 1, 0, 1 Ground 18 766.27 .10 331 oilA 1 1 A Z, 1. 1*^ 1, 1. u Ground 19 162.76 .10 331

Z,9 11, Z*9^ 111 1, 1, 1 Ground 1 o 077 £-7 .10 331

s-Si2"H2DC'2H:C'2H2 619 1, 1, 0^ 0, 0. 0 Ground 9 881.05 .10 331

2.oil0, 2-^ 1, 0. 1 Ground 19 752.92 .10 331

- 1 1 A z, 1, 1<— 1, 1, 0 Ground 20 310.72 .10 331

9Z, 11. 9^Z< 111 1, 1, 1 Ground 19 213.72 .10 331

621 1, 1, 0^ 0, 0, 0 Ground y lUO.io .10 331

2, 0, 2*- 1, 0, 1 Ground .10 331

9 11 , 1 1 A Z, 1, 1*— 1, 1, U Ground 19 775.85 .10 331

i-, 9 11,

9,^^ 111 1, 1, 1 Ground 19 044.95 .10 331

s-Si^'HDzC'^HrC'^Hj 622 1 1 n<_ n 0 0 Ground 9 354.8 .10 331

2, 0, 2^ 1, 0, 1 Ground 18 707! 1 .10 331

2, 1. 1^ 1, 1, 0 Ground 18 986.14 .10 331

2, 1, 2^ 1, 1, 1 Ground 18 433.27 .10 331 a-Si^sHDjC'^HiC'^Hj 623 1, 1, 0^ 0, 0, 0 Ground 9 511.02 .10 331

2, 0, 2*- 1, 0, 1 Ground 19 015.05 .10 331

9 11 - 1 1 A Z, 1, 1*^ 1, 1, u Ground 19 480.67 .10 331

Z,9 11, Z*0* 111 1, 1, 1 Ground 18 563.63 .10 331

Si28H3C'2H:C'''H2 624 2, 0, 2<— 1. 0, 1

1 _T*r^i 1 n jH V^I UUllli 19 590.25 1 A .11)

j 331

2.' L 1-^ l" l! 0 Ground 20 027.20 .10 331

1

1

2, 1, 2^ 1, 1, 1 Ground

1 19 162.94 .10 331

179
630 - Ethylamine

Aminoethane

Molecular Constant Table

Cs(C3viC2v^Cs)

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) Dj K A

631

Id. No. /Xa Debye /Xh Debye fj.^. Debye eQq V Acc. Ired OJa d (jL)i, d w,. d d

631 1.22 T 0. X 3500

References: ABC:

367

Dj:

eQq: V: 113

Ethylamine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

N'-'H^CJ-H, 631 Not Reported Ground 22 130.04 .2 94 Not Reported Ground 22 564.05 .2 94 Not Reported Ground 22 603.51 .2 94 Not Reported Ground 22 618.89 .2 94 Not Reported Ground 22 625.17 .2 94

Not Reported Ground 22 635.94 2 94 Not Reported Ground 22 641.95 .2 94 Not Reported Ground 22 668.35 2 94 Not Reported Ground 22 751.86 .2 94 Not Reported Ground 22 789.47 .2 94

Not Reported Ground 22 815.64 .2 94 Not Reported Ground 22 909.23 .2 94 Not Reported Ground 22 975.73 .2 94 Not Reported Ground 23 033.75 .2 94 Not Reported Ground 23 045.44 .2 94

Not Reported Ground 23 196.14 .2 94 Not Reported Ground 24 261.72 .2 94 Not Reported Ground 23 264.16 .2 94

i' Not Reported Ground 24 291.18 .2 94 Not Reported Ground 24 418.80 .2 94

Not Reported Ground 24 695.13 .2 94 Not Reported Ground 24 802.94 .2 94 Not Reported Ground 25 328.64 .2 94

r

180
640 . Diniethylsilane Mulccijlar Constant 'I'alili- Dimethylsilicane

C,H,S\ C2v(C3v,C3v,C,,v) (CH,)2SiH,

Isotopic Species 1PtI. Gp.

lu. No. A (MHz) B(MHz) C (MHz) n L'jK

(C'2H,),Si^«H2 C2V 641 16 754.24 M 5 945.44 M 4 896.50 M

C'^H^C'-DaSPH^ Cs 642 14 740.79 M 5 198.82 M 4 342.47 M

(C'-HslaSi-^Da C2V 643 13 716.25 M 5 749.07 M 4 722.39 M

C2V 644 16 606.85 M 5 945.56 M 4 883.83 M

C2V 645 16 467.26 M 5 945.50 M 4 871.52 M

Cs 646 16 605.08 M 5 785.65 M 4 775.22 M

Id. No. /Xa Debye /Lti, Debye /X(. Debye eQq V.3 Acc. I red ojy d oil, d (!)(. d (till d

641 0. X 0.75 M 0. X 1649 3

642 1647 3

643 1646 3

References: ABC: 333 Dj: Djk: k: A:

fi: 333 eQq: V: 333 I: w:

Add. Refs.: 209. 262. 287

Coupling parameters listed for the following species: 641: Ia= 3.1635 amu A'^; 642: Ia= 3.1635 for CH3 group and Iq= 6.3221 for CD3

group; 643: I,, = 3. 1635. Ref: 333.

749-587 0-69— 13 181
Dimethylsilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n E'1 F' E1 F MHz ±MHz

(C'-HaljSim, 641 ]. 1^ 0. 0, 0 Ground AE+EA 0 21 649.82 .05 333

I 1, 1^ 0. 0, 0 Ground EE 0 21 651.08 .05 333

1, 1, 1^ 0, 0, 0 Ground AA 0 21 652.35 .05 333

1, o<— 1, 0, 1 Ground AE+EA 0 11 857.06 .05 333

\-

1, 0^ 1, 0. 1 Ground EE 0 11 858.19 .05 333

1, 1, 0^ 1, 0, 1 Ground AA 0 11 859.33 .05 333

2, 1, 1^ 2, 0, 2 Ground AE+EA 0 iZ 978.49 .05 333

2. 1, 1^ 2, 0, 2 Ground EE 0 12 979.76 .05 333

2. 1, 1<— 2, 0, 2 Ground AA 0 12 981.03 .05 333

3. 0. 3^ 2. 1. 2 Ground AA 0 22 402.03 .05 333

3, 0. 3^ 2, 1, 2 Ground EE 0 22 402.90 .05 333

3, 0, 3^ 2, 1, 2 (jround AE+EA 0 1 O'T 4r\o OA

zz 403.oO .05 333

3. 1, 2<- 3, 0, 3 Ground AE+EA 0 14 792.71 .05 333

03, 1, z<— 3, A 3 Ground EE 0 14 794.11 .05 333

3, 1, 2^ 3, 0, 3 Ground AA 0 14 795.50 .05 333

4, 1, 3^ 4. 0, 4 Ground AE+EA 0 17 441.16 .05 333

4. 1, 3^ 4. 0, 4 Oround EE 0 1 / 442. /z AC .05 333

4, 1, 3«— 4, 0, 4 Ground AA 0 17 444.27 .05 333

5. 1. 4^ 5. 0. 5 Ground AE+EA 0 21 068.32 .05 333

5, 1, 4^ 5, 0, 5 Ground EE 0 21 070.13 .05 333

5. 1, 4^ 5, 0. 5 Ground AA 0 21 071.97 .05 333

6. 1, 5^ 6, 0, 6 Ground AE+EA 0 25 771.55 .05 333

6, 1, 5*- 6. 0, 6 Ground EE 0 25 773.65 .05 333

6. 1, 5^ 6, 0, 6 Ground AA 0 25 775.75 .05 333

C'^HaC'^DjSi^^Ha 642 1, 1. 1^ 0. 0, 0 Ground E 0 19 082.67 .05 333

1. 1, 1^ 0, 0, 0 Ground A 0 19 083.52 .05 333

1, 1, 0^ 1, 0, 1 Ground E 0 10 397.79 .05 333

1, 1, O'^ 1, 0, 1 Ground A 0 10 398.58 .05 333

2, 1, 1^ 2, 0, 2 Ground E 0 11 309.18 .05 333

2, 1, 1^ 2, 0, 2 Ground A 0 11 310.02 .05 333

3, 0. 3^ 2, 1, 2 Ground A 0 19 663.69 .05 333

3. 0, 3<- 2, 1, 2 Ground E 0 19 664.24 .05 333

3, 1, 2^^ 3, 0, 3 Ground E 0 12 776.79 .05 333

3. 1, 2^ 3. 0. 3 Ground A 0 12 777.78 .05 333

4, 1, 3*- 4, 0, 4 Ground E 0 14 909.62 .05 333

4, 1, 3<- 4, 0, 4 Ground A 0 14 910.75 .05 333

5, 1, 4^ 5, 0, 5 Ground E 0 17 823.41 .05 333

5, 1, 4^ 5, 0, 5 Ground A 0 17 824.74 .05 333

5, 2, 3^ 5, 1, 4 Ground E 0 25 590.10 262

5, 2, 3.^ 5, 1, 4 Ground A 0 25 592.00 262

6, 1. 5<^ 6. 0. 6 Ground E 0 21 604.75 .05 333

6. 1. 5^ 6, 0, 6 Ground A 0 21 606.33 .05 333

6, 2, 4^ 6, 1, 5 Ground E 0 24 994.91 262

6, 2, 4^ 6, 1, 5 Ground A 0 24 996.80 262

(C'^Hgj^Si^^D^ 643 1. 1^ 0, 0, 0 Ground AE+EA 0 18 438.12 .05 333

1, 1^ 0, 0, 0 Ground EE 0 18 438.86 .05 333

1, 1^ 0, 0. 0 Ground AA 0 18 439.63 .05 333

1, 0^ 1, 0, 1 Ground AE+EA 0 8 993.41 .05 333

1, 0^ 1, 0, 1 Ground EE 0 8 994.12 .05 333

1, 1. 0^ 1, 0, 1 Ground AA 0 8 994.82 .05 333

182
Dimethylsilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor No. Quantum Nos. State n

643 2, 2^ 0, 2 Ground AE+EA 0

\ 2«— 2 0 2 Ground EE 0

i. \, 1-^ 2! 0! 2 Ground AA 0

3, 0. 3-^ 2, 1, 2 Ground AA 0

3 Q 3<_ 2 1 2 (iround EE 0

n j<_ 2 2 Ground AE+EA 0

3 \ 2<— 3 Q 3 Ground AE+EA 0

i. \, 2-^ 3^ oi 3 Ground EE 0

3, 1, 2^ 3, 0, 3 Ground AA 0

4^ 1, 3<— 4, 0, 4 Ground AE+EA 0

4, 1, 3<— 4, 0, 4 Ground EE 0

4,

1' 3«- 4! 4 Ground AA 0

s! 4-^ 5! 0! 5 Ground AE+EA 0

5, 1, 4^ 5, 0, 5 Ground EE 0

5, 1, 4<- 5, 0, 5 Ground AA 0

644 1, 1. 1<~ 0, 0, 0 Ground AE+EA 0

1, 1, 1*- 0, 0, 0 Ground EE 0

1, 1, 1^ 0, 0, 0 Ground AA 0

4, 1, 3<— 4. 0, 4 Ground AE+EA 0

4, 1. 3<- 4. 0! 4 Ground EE 0

4, 1, 3«— 4. 0. 4 Ground AA 0

\, 4^ 5^ 0. 5 Ground AE+EA 0

5, 1, 4^ 5, 0, 5 Ground EE 0

5, 1 4<— 5, 0, 5 Ground AA 0

645 \ \ 2<— 0, 0, 0 Ground AE+EA 0

\, 1^ 0! 0! 0 Ground EE 0

1, 1. 1^ 0. 0, 0 Ground AA 0

4^ 2^ 3<— 4_ 0, 4 Ground AE+EA 0

4^ \^ 3<— 4^ 0 4 Ground EE 0

4, 1^ 3«— 4, 0, 4 Ground AA 0

5', \, 4^ si oi 5 Ground AE+EA 0

5, 1, 4-^ 5, 0, 5 Ground EE 0

5, 1, 4<— 5, 0, 5 Ground AA 0

646 1, 1_ 1<— 0, 0, 0 Ground AE+EA 0

1, 1, 1<— 0, 0, 0 Ground EE 0

1, \. 1^ oi 0" 0 Ground AA 0

4, 1. 3^ 4, 0. 4 Ground AE+EA 0

4, 1. 3<— 4, 0, 4 Ground EE 0

4, 1, 3^ 4. 0, 4 Ground AA 0

i 5, 1, 4^ 5, 0, 5 Ground AE+EA 0

1 5, 1, 4^ 5, 0, 5 Ground EE 0

1 5, 1, 4^ 5, 0. 5 Ground AA 0

1 6. 1. 5^ 6, 0. 6 Ground AE+EA 0

6, 1, 5^ 6, 0, 6 Ground EE 0

6. 1. 5^ 6, 0. 6 Ground AA 0

Hyperfine

f; F' E F

Frequency | Acc. i R( MHz I ±MHz

(C>'=H3)2Si^«D2

(C'2H3)2Si^«H2

:(C'^H3)2Si-'»H2

C'5H3C>2H3Si2«H2

10 1 12.93 ! .05 1 333

10 1 13.72 1 .05 1 333

10 114.53 1 .05 1 333 24 012.43 .05 1 3.33 24 012.92 1 .05 333

24 013.39 1 .05 1 333

11 958.60 1 .05 1 333

11 9.59.51 .05 i 333

11 960.42 .05 333

14 695.69 1 .05 1 333

14 o9d. 10 1 0.50

Ac: 000

18 462.82 .05 1 333

18 464.11 .05 1 333

10 4'DD.OD 1 .UD 1 000

000

21 491.07 .20 1 333

21 492.33 1 .20 1 333

1 "7 QOyl OA 1 / o94.yo .ZD \ 000

1 / oVo.ol .zU j

I / o9o.U0 .ZU 1 006

21 086.34 .20 1 333

21 088.16 .20 333

21 089.93 .20 1 333

Zl 337.99 1 .20 1 333

21 339.18 1 .20 1 333

21 340.20 .20 1 333

17 353.41 1 .20 1 333

17 354.68 1 .20 1 333

17 356.26 ] .20 1 666

21 106.76 .20 i 333

21 108.42 .20 333

zl 110. zz OA 1 .zO 1 Q Q Q 666

01 Q "70 A n 11 i /9.40 1 OA .zO 1 0 Q Q 666

Zl JoU. (0 1 OA .zO 1 666

21 382.00 .20 1 333

17 180.01 1 .20 1 333

1 / lol.oo 1 OA .zO 1 0 3 9 666

17 183.30 j .20 1 333

20 646.21 .20 1 333

20 647.95 .20 1 333

20 649.83 .20 1 333

24 142.60 .20 i 333

25 144.60 1 .20 1 333

25 146.60 1 .20 1 333

183
650 - Ethylsilane

Ethylsilicane

C,H„Si

Molecular Constant Table

C,(C;jv,C,.C

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) D,, D,,K K A

C'2H:5C'2H,Si"H, 651

Id. No. fjL.^ Debye Debye Debye eQq V3 Acc. lied oji, d ctjj, d oj„ d

651 0.72 M 0.36 M 0. X 1940 40

References: ABC:

/x: 306

D.,: eQq:

D,,k: V: 306,

No spectral lines

660 - Trifluoroacetic Acid-Formic Acid Complex

C:3H,F,0,

Molecular Constant Table CF,COOHHCOOH

B + C = 1 154.4 MHz. Ref: 316.

Trifluoroacetic Acid-Formic Acid Complex Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

C'T;',''C'-^0'"0"'HHC'^0"'0"'H 661 3, , ^ 2, , 1 Ground 3 462.2 316

7. , ^ 6. . 1 Ground 8 079.1 316

8, . ^ 7. , Ground 9 235.2 316

9, , ^ 8. , I Ground 10 388.5 316

16, . ^15, , 1 Ground 18 473.0 316

17, , ^16, , 1 Ground 19 621.8 316

18, , ^17, , Ground 20 779.2 316

19, . ^18, , Ground 21 9.38.5 316

C'T;',"C'-^0"^0"'D-HC'-0"'0'«H 662 16, *-15, (Ground 18 397.0 343

19. , ^18, , Ground 21 842.7 343

C'-F.fC'20'«0"'HHC'-0"'0"'D 663 16, . ^15, , [ Ground 18 351.7 343

19, , ^18, . 1 Ground 21 794.2 343

C'-F;V'C''^0"'0"'D-HC'20"'0"^D 664 16, , ^15, , 1 Ground 18 270.0 343

19. , ^18, . ! (iround 21 669.7 343

ii:; 184
670 - Fyruvonilrile

Acetyl Cyanide; 2-Oxopropanenitrile

C3H3NO C,(C,„C,)

Molecular (!onstaiil Talilc

ch..,co(:n

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D.1 K A

C'2H3C'20"^C'2N"'' Cs 671 10 185.46 M 4 157.53 M 3 002.75 M 2.871 C"H3C'^0"'C'2N"' Cs 672 9 906.07 M 4 105.57 M 2 951.68 M 2.897

C'^H3C'^0"'C'-^N'^ Cs 673 10 184.58 M 4 125.37 M 2 986.21 M 2.890

C'2H3C'20"'C'2N'^ C.S 674 9 657.42 M 4 085.73 M 2 918.86 M 2.883 c. 675 8 728.40 M 3 875.60 M 2 772.32 M 6.008 676 8 722.81 M 3 870.29 M 2 769.23 M 6.021

Id. No. fjLs Debye /ixi, Debye fi^ Debye eQq V,., Acc. CO;, d CO,, d to,, d w,, d

671 2.42 M 2.46 M 0. X 1210 30

672 1226

673 1214

674 1204

References: ABC: 246

fi: 246

Dj:

eQq:

D,,k: V: 288

A: 246

01:

For all species, the coupling parameter is: la =3.1421 amu A^. For species 677, (A— C)/2=3545 MHz. For species 678, (A— C)/2 = 3235.5 MHz. For species 679, (A - C)/2 = 3257.5 MHz. Ref: 246.

185
Pyruvonitrile Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n

I F' E1 F MHz ±MHz

671 1. 1. 1^ 0. 0. 0 Ground 13 188.21 .2 246

2, 0, 2^ 1. 0. 1 Ground 14 170.15 .2 246

2, 0, 2<- 1. 1, 1 Ground 8 142.5 .3 246

2, 1, 2->~ 1. 0, 1 Ground 19 193.60 .2 246

2, 1. 1^ 1. 1, 0 Ground 1 15 475.34 .2 246

2, 1, 2^^ 1, 1, 1 Ground 13 165.78 .2 246

3, 0. 3^ 2, 0, 2 Ground E 0 20 894.60 .2 246

3, 0. 3^^ 2, 0, 2 Ground A 0 20 895.08 .2 246

3, 0, 3^ 2. 1, 2 Ground 15 871.37 .2 246

3. 1, 2^ 2. 1, 1 Ground 23 112.13 .2 246

3, 1. 3^ 2. 1, 2 Ground 19 659.98 .2 246

3. 2, 2^ 2, 2, 1 Ground 1 21 481.42 .2 246

3. 1. 2^ 3. 0, 3 Ground 10 705.27 .2 246

4. 0. 4^ 3. 1, 3 Ground 23 479.26 .2 246

4. 1, 3^ 3, 1, 2 Ground 1 E 0 30 608.53 .2 246

4. 1, 3^ 3, 1, 2 Ground 1 A 0 30 610.27 .2 246

4, 1, 4*- 3, 1, 3 Ground 26 064.43 .2 246

4, 3, 1^ 3, 3, 0 Ground 28 981.60 .2 246

5, 0. 5^ 4. 0. 4 Ground 33 344.70 .2 246

5. 0. 5^ 4. 1. 4 Ground 30 759.12 .2 246

5. 1. 4^ 4. 2. 3 Ground I E 1 23 527.46 .2 246

5. 1. 4^ 4. 2. 3 Ground A 0 23 529.29 .2 246

5. 2. 3^ 5. 1. 4 Ground 16 497.52 .2 246

6. 1. 5^ 6. 0, 6 Ground 1 E 1 24 205.33 .2 246

6, 1, 5^ 6. 0. 6 Ground A 1 24 211.49 .2 246

6. 2. 4^ 6. 1, 5 Ground 17 576.96 .2 246

6. 3. 3^ 6, 2, 4 Ground 28 180.80 .2 246

7, 1. 6^ 7, 0, 7 Ground i E 1 30 537.91 .2 246

7, 1, 6«- 7, 0, 7 Ground A 1 30 545.52 .2 246

7. 2, S<- 7, 1, 6 Ground ! E 1 19 935.72 .2 246

7, 2. 5«- 7. 1, 6 Ground 1 A 1 19 939.43 .2 246

7, 3. 4^ 7, 2, 5 Ground 26 389.94 .2 246

8. 2, 6^ 8. 1, 7 Ground 1 E 1 23 711.10 .2 246

8. 2. 6'^ 8, 1, 7 Ground A 1 23 716.83 .2 246

8. 3. 5-^ 8, 2, 6 Ground E 1 25 141.40 .2 246

8, 3, 5^ 8, 2, 6 Ground 1 A I 25 142.58 .2 246

9, 2. 7^ 9, 1, 8 Ground E I 28 859.57 .2 246

9, 2. 7^ 9. 1, 8 Ground A 1 28 867.37 .2 246

9. 3. 6^ 9, 2, 7 Ground E 1 24 899.85 .2 246

9. 3. 6^ 9, 2, 7 Ground 1 A 1 24 901.87 .2 246

10. 3. 7*-10. 2. 8 Ground 1 E 1 26 008.42 .2 246

10. 3. 7^10, 2, 8 Ground i A I 26 012.18 .2 246

11. 3. 8^11, 2, 9 Ground 1 E 0 28 680.63 .2 246

11. 3. 8^11, 2, 9 Ground 1 A 0 28 686.62 .2 246

11, 4, 7^11. 3, 8 Ground 34 771. .3 246

12. 3. 9^12, 2,10 Ground E 0 32 978.82 .2 246

12. 3. 9«-12, 2,10 Ground 1 A 0 32 987.34 .2 246

12. 4. 8^12, 3, 9 Ground 33 169.95 .2 246

186
Pyruvonitrile Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency

1 Acc. 1 Ref. No. Quantum Nos Sl3.tC F' F' p MHz ±MHz

672 1

1inVI, 11 0 Ground 12 858.27 2 1 246

9 11, nu. 1 Ground 13 959.01 .2 i 24^

2, 1, 2<- 1, 0, 1 Ground 18 761.11 •2 246

2, 1, 1^ 1, 1, 0 Ground 15 268.39 •2 246

9 1X , 9«— X , X

1 Ground 12 960.62 2 1 246

a 1X , 0^ z.9 n 2 Ground 24 150.7 .3 i 246

4 Q 4«— 3 0 3 Ground 26 817.10 .2 246

4^ I, 4^ 3! 0! 3 Ground 29 228.46 •2 i 246

4, 1, 4*- 3, 1, 3 Ground 25 644.76 .2 246

4, 2, 2«— 3, 2^ 1 Ground 29 518.4 .3 1 246

5, 0, 5<— 4^ 0, 4 Ground 32 773.38 2 1 246

7^ 3 4«— 7^ 2 5 Ground 25 278.01 •2 246

8,

2' 6-^ 8^ 1! 7 Ground E 0 23 536.65 .2 246

8, 2, 6^ 8, 1, 7 Ground 0 23 541.99 .2 1 246

8, 3, 5<— 8, 2, 6 Ground 24 161.20 .2 246

9_ 2. 7«- 9. 1 8 Ground £ 0 28 789.33 •2 246

9^ 2, 7^ 9. 1_ 8 Ground A 0 28 796.36 •2 246

9^

3" 6^ 9, 2! 7 Ground 24 109.5 •2 246

10, 3. 7*- 10, 2, 8 Ground E 0 25 448.26 .2 ' 246

10, 3 7^10. 2 8 Ground A 0 25 452.03 2 i 246

11 3 8^ 11. 2 9 Ground £ 0 28 375.46 .2 I 246

1

IX, 50, 8^11, 2 9 Ground A Q 28 381.10 •2 246

11, 4, 7^11, 3' 8 Ground 33 182.59 •2 246

12, 3, 9*- 12, 2. 10 Ground r 32 918.68 .2 246

1 9 a0, 9^ 12, z.9 10 Ground A 0 32 927.01 2 246

673 1X

1^ 0, 0 0 Ground 13 170.70 •2 i 246

z.9 u. 2^ 1, nu. 1 Ground 14 076.57 •2 I 246

2, 1. 2^ 1, 0, 1 Ground 19 143.21 .2 246

2, 1. 1^ 1, 1, 0 Ground 15 362.32 2 i 246

2 2^ 1, 1 Ground 13 083.99 •2 246

3. 3^ 2, 0, 2 Ground 24 605.75 2 246

3, 2*- 2. 1 Ground 0 22 945.22 •2 246

3! 1, 2^ 2, I, 1 Ground A 0 22 946.19 2 246

3, 1, 3^ 2, 1, 2 Ground 19 537.93 2 246 4 0, 4-^ 3, 0 3 Ground 27 110.93 .2 1 246

4, 0, 4^ 3. 1 3 Ground 23 270.4 .4 i 246

4 4^ 3. 0. 3 Ground 29 478.10 2 246

4! h 3^ 3. 1^ 2 Ground 30 394.56 •2 246

4. 1. 4^ 3, 1, 3 Ground 25 907.24 2 1 246

4_ 2_ 3^ 3. 2_ 2 Ground 28 332.05 2 246

0, Q 5^ 4. 0. 4 Ground 33 161.23 j 2 1 246

c: 0, 0 5^ 4, 1X

4 Ground 30 524.12 •2 246

5, 1, 5-^ 4, 1, 4 Ground 32 181.45 .2 246

6, 3, 3^ 6, 2, 4 Ground 28 389.86 •2 246

7. 2, 5^ 7, 1, 6 Ground E 0 19 824.98 •2 1 246

7, 2, 5^ 7. 1. 6 Ground A 0 19 828.54 •2 ! 246

7, 3, 4^ 7, 2. 5 Ground 26 593.24 •2 i 246

8, 2, 6^ 8, 1, 7 Ground E 0 23 487.74 2 246

8, 2, 6*- 8, 1, 7 Ground A 0 23 492.79 | •2 246

8. 3. 5*- 8, 2, 6 Ground E 0 25 299.99 j 2 246

i

187
Pyruvonitrile

Spectral Line Table

Isotopic Species Id. Rotational | Vib. State Int. Rotor Hypertine Frecjuency Acc 1 Ref.

1 No. Quantum Nos. | StcltC F' F' ^1 r MHz ±MHz

673 QO, QJ, 5^ 8, 9 ft z, 0 Ground A

r\. AU 25 301.05

1 2 ! 246

0 z.9 7^ 9, 1i Q , 0 1 Ground Hi nyj 28 513.87 •2 246

9, 2, 7<- 9, 1, 8 Ground Au 28 52 1 60 .2 246

9, 3, 6^ 9, 2, 7 Ground I? A 24 971.91 •2 Q 5

-->, 6^ 9, 9 7 Ground A 0 94, 973 89 •2 1

10, 3, 7^10, 2, 8 Ground jr A0 25 954..59 • 2 1 246

10, 3, 7^10, 2, 8 Ground A 0 25 958.15 • 2 246

1 11, 3, 8^11, 2, 9 Ground E 0 28 467.34 •2 1 246

11, 3, 8*- 11, 2, 9 Ground A 0 28 473.03 2 1 246

12, 3, 9^12, 2,10 Ground £ 0 32 586.38 2 246

12, 3, 9^12, 2,10 Ground 0 32 594.33 •2 246

12, 4, 8^12, 3, 9 Ground 33 415.93 2 246

C'^H3C''^0"*C'^N" 674 J 1^ 0, 0 0 Ground 12 577. 2. 246

2 0, 2^ 1, 0, 1 Ground 13 844.50 •2 246

•i l] 2<- 1, 0] 1 1 Ground 18 414.00 •2 246

2, 1, 1^ 1, 1, 0 Ground 15 176.04 •2 246

9 11

,

2^ 1, 1 1 Ground 12 842.31 2 246

9O, 1 3.^ 2, n 9 1 Ground 23 733.95 •2 1 246

4 0 4^ 3'

1 , 0 [ Ground 23 174.95 •2 246

4^ 1, 4^ 3, 1. 3 Ground 25 392.84 2 1 246

5, 0, 5^ 4, 1, 4 Ground 30 186.53 2 1 246

5 5.^ 4. 1 4 Ground 31 519.18 •2 1 246

6, 3, 3^ 6, 2, 4 Ground 0 25 774.16 2 i 246

6, 3, 3^ 6^ 2, 4 Ground 0 25 775.01 2 246

l] 3^ 4^ 7. 2^ 5 1 Ground 24 132.67 •2 246

8, 2, 5.^ 8, 1. 7 Ground E 0 23 607.22 •2 246

8 2 6<— 8, 1, 7 Ground A 0 23 612.92 2 246

8, 3, 5<— 3 2, 6 1 Ground 23 191.46 •2 1 246

V, 6^ 9'

z,9 7t

\ Ground 23 401.52 2 246

0 0o. 6^ 9, Z,9 7'1 Ground A 0 23 403.71 •2 246

1 n qo. i ^ iU, 9 fi Z, 0 Ground T? Au 25 076.08 •2 246

1 A oo. t ^ 1 n 9 Q Z, 0 Ground AA A 25 080.16 2 246

11. 4. 7<_ 11 3. 8 1 ( »?"ni 1 nn 31 542.42 •2 246

1 9 /I 8^12' Q 0 1 Ground 30 531.92 •2 246

C'-D,C'-0"^C'2N" 675 1 1 1^ 0. n n 1 U U Ground 11 500.72 .3 246

9 n

u. 2^ 1, n 1 1 u. 1 Ground 13 128.25 •2 246

2. 1, 2^ 1. 0.

1

( .I'Al 1 n

n

v7 I VJ Li i lU 17 046.5 .5 246

2. 1, 1^ 1. 1,

0

( .m1 1 n H 14 399.12 •2 ! 246

9 1 2^ 1, 1 1 1 Ground 12 192.56 •2 246

O, AU, 3<^ 2, n 9 1 Ground 19 297.8 .3 1 246

o. 1 2^ 2. 1 1 1 Ground 21 484.8 .3 246

4. 0, 4^ 3, 0, 3 Ground 25 106.62 2 246

4. 0. 4^ 3, 1, 3 1 Ground 22 297.6 •2 1 246

4, 1, 4^ 3, 0, 3 ( , round 26 903.58 2 1 246

4, 1. 3<- 3, 1, 2 1 Ground 28 410.93 2 1 246

4. 1. 4^ 3. 1, 3 Ground 24 093.70 2 246

4, 2, 3^ 3, 2, 2 Ground 26 461.42 •2 246

5, 1, 5^ 4, 0, 4 Ground 1

1 31 690.10 2 246

1, 5^ 4, 1, 4 (jround 1 29 895.95 ' -3 1 246

188
Pyruvonitrile Spectral Line Table

Isotopic Species Id. Rotalionul Vib. Slate Int. Rotor Hyperfine 1 Frequency 1 Acc. Ref. No. Quanluni Nos State n F' F, F 1 MH/ 1 ±MHz

C''D;,C'-0"'C'''N'-' 675 5, 2, 4*- 4, 2, 3 (Ground 1 32 867.29 1 -2 246

5, 3, 2^ 5, 2, Ground 23 897.3 9

1 .Z 9/1

Z'+O

6. 2. 4^ 6, I, .5 (Ground 1 1 l.D IVZ.O •2 246

7, I.

r , -7 1 6 (Ground 1

1 17 969.7 •2 246

8. 3, 5<- 8. 2. 6 (iround 1

1 20 267.8 •2 246

9. 3, 6^ 9, 2, 7 (iround 20 873..53 .2 246

9, 4, 5^ 9, 3, u C/Found 1

1 30 889.66 1 9.Z 9/1

Z^O

10. 3, 7^10, 2, 8 (; round 1

1 ZZ V.3j.oU 2 246

10, 4, 6^10, 3, 7 ( ' rou n d 28 69.5.97 1 9.Z Z40 9/1 11. 3, 8^11, 2, 9 (iround 26 550.51 1 -2 246

12, 4, 8^12, 3, 9 Ground 26 781.28 •2 246

C'2D.,C'-'0"'C'^N"' 676 1, 1, 1^ 0, 0. 0 Ground 2 246

2, 1, 2^ 1, 0, 1 Ground 1 17 0.30..50 1 9.Z 9/1 z4d

2, 1. 1^ 1, 1, 0 Ground 14 380.50 2 246

1

I*— 1, 1, 1 Ground 12 177.98 1 -2 246

4, 0. 4^ 3, 0, 3 Ground 1 1 25 076.94 i -2 246

4, 1, 4^ 3, 0, 3 Ground 1 26 877.25 2 246

4, 1, 4^ 3, 1, Ground 1 24 065.46 1 9 9/1

4, 2, 3-^ 3, 2, 2 Ground 1 26 427.20 .2 246

z.9 3 Ground 32 826 45 .2 246

5, 3, 2^ 5, 2, 3 Ciround 23 888.35 .2 246

10, 3, 7^10, 2, 8 Ground 1 1 22 907.56 .2 246

10, 4, 6^10, 3, 7 Grou nd 28 705.21 2 Z4'0 11. 3, 8^11, 2, 9 (Ground 1

1 26 507.05 .2 246

i J. , 8 Ground 1 1 27 152.82 .2 246

12, 4, 8^12, 3. 9 Ground 1 1 26 771.04 .2 246

s-C'2H2DC'20"^C>2N'^ 677 3, 1, 3^ 2, 0. 2 (iron nd 1

1 23 976.34 .2 246

3, 1, 2^ 2, 1, 1i ( » r( m nd 1 22 174.5 9.Z 9/1

4, 0, 4^ 3. 1, 3 Ground 1 22 417.94 .2 246

Qo. 9 7 Ground 1 22 617.57 .2 246

9. 3, 6^ 9, 2, 7 (iround 1 24 655.85 .2 246

a-C'^HD2C'20>''C'2N" 678 /:0, i. O*— 0, U, 6 Ground 1

1 22 833. 1. 246

7. 3, 4^ 7, 2, Ground 1 23 321.5 .z Z4*0

8, 2, ()<- 8, 1, 7 Ground 1 22 351.7 .2 246

8, 3, 5^ 8, 2. 6 Ground i

1 22 358.8 .2 246

9, 3, 6^ 9, 2, 7( Ground 1 i 22 454.2 9.Z 9/1

Z4d

lU, •J, 8 Ground 1 1 23 897.77 .2 246

10, 3, 7^10. 2, 8 Ground 1 23 911.19 .2 246

a-C'^H^DC'^O'^C'^N'^ 679 3, 1, 3^ 2, 0, 2 Ground 1 23 591.75 246

3, 1, 2^ 2, 1, 11 Ground 22 748.5 Z'*0 9AA

4, 0, 4^ 3, 1, 3 Ground 1 1 23 451.09 246

o.

11 , 0, u, 6 Ground 1 1 24 014.94 246

7, 3, 4^ 7, 2, 5 Ground 1 23 044.93 246

8, 2, 6^ 8, 1, 7 Ground 1 1 23 568.45 246

8, 2. 6^ 8, 1, 7 Ground 1 23 570.53 9/1

8, 3, 5^ 8, 2, 6 Ground 1 22 276.07 246

9, 3, 6^ 9, 2, 7 Ground 1 22 726.47 246

10, 3, 7*-10, 2, 8 Ground 1 1 24 691.50 246

10. 3. 7^10, 2, 8 Ground 1

1 24 692.58 246

1

jl

189
680 -Methyl Ketene Molecular Constant Table Methyl Ethenone C3H4O QC3v.Cs) CHjCHiCO

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) D,, DjK K A

C'^HaC'^HiC'^O"^ Cs 681 38 350. ' M 4 507.40 M 4 136.97 M

Id. No. /Xa Debye fXi, Debye fjL,. Debye eQq Acc. I red OJa d C0|, d ftjj. d ai,i d

681 1.79 M 0. X 1200 10

1

1. This constant was calculated assuming L=3.14 amu A- Rotational constants were calculated from I'a values extrapolated to infinite barrier height.

References: ABC: 341 Dj: Djk: k: A:

fJi- 341 eQq: V: 341 I: (o:

Coupling parameter (methyl group): la = 3.14 amu A-. Ref: 341.

Methyl Ketene c ^ 1 t

• t li ^ bpectral Lme 1 able

Isotopic Species Id. Rotational Vib. State Int. Rot or Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' Ft F MHz ±MHz

C'2H3C'-^H:C'-0"' 681 2, 0, 2^ 1, 0, 1 Ground E 0 17 285.1 .1 341

2, 0. 2^ 1, 0, 1 Ground A 0 17 285.9 .1 341

2, 1. 1^ 1, 1, 0 Ground E 0 17 621.4 .1 341

2, 1, 1^ 1. 1, 0 Ground A 0 17 659.9 .1 341

2. 1. 2<- 1. 1, 1 Ground A 0 16 918.5 .1 341

2. 1, 2^ 1. 1, 1 Ground E 0 16 955.5 .1 341

3, 0, 3^ 2, 0. 2 Ground E 0 25 919.8 .1 341

3. 0. 3^ 2, 0, 2 Ground A 0 25 921.0 .1 341

3. 1. 2^ 2, 1. 1 Ground- E 0 26 474.7 .1 341

3, 1. 2^ 2, 1, 1 Ground A 0 26 487.7 .1 341

3, 1, 3<- 2, 1, 2 Ground A 0 25 375.6 .1 341

3, 1, 3^ 2, 1, 2 Ground E 0 25 386.4 .1 341

3. 2. 2, 2, Ground E 0 25 835.2 .1 341 '

3, 2. 2. 2, Ground E 0 26 023.4 .1 341 •

3, 2. 1^ 2, 2, 0 Ground A 0 25 946.8 .1 341

3, 2, 2^ 2, 2, 1 Ground A 0 25 934.9 .1 341

' Definite assignments fur these lines were not given.

190
690 - s-trans-Acrolein Acrylaldehyde; Propenal; Acrylic Aldehyde

C^H.O Cs(Cs,C,

Molecular (Jonstaiil Table

CH2:CHCH0

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D.,K K A

C'-^H2:C'2HC'2HO"' C, 691 4 659.53 M 4 242.71 M 0.05

Id. No. /Xa Debye Ht, Debye jx^. Debye eQq V, Acc. I red OJa d (Oh d O),. d w,i d

691 3.06 M 0.54 M 0. X 5000

References: ABC: 198

fi: 198 Add. Ref.: 103

Dj:

eQq:

D,

V: 198

A: 198

Rotational constants for excited torsional states: v=l: 8 = 4666.19 ±.02 MHz,

v=2: B= 4672. 10 ±.02 MHz,

v=3: B = 4678.69 ±.02 MHz,

The torsional frequency is 200±50 cm '. Ref: 198.

C = 4259.66 ±.02 MHz

C = 4273.56 ±.02 MHz

C = 4290.29 ±.02 MHz.

s-trans-Acrolein Spectral Line Table

Isotopic Species Id. Rotational Vib. State

1 Int. Rotor 1 Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

691 2, 1, 1<- 1. 0, 1 Ground 1 18 258.18 198

2. 1, 1^ 1. 1, 0 Ground 0 18 211.08 198

3, 0, 3^ 2, 0, 2 Ground 0 26 694.37 198

3, 0. 3<- 2, 0, 2 Ground 1 26 765.43 198

3, 0, 3^ 2. 0. 2 Ground 2 26 824.88 198

3, 0, 3^ 2. 0, 2 Ground 3 26 895.18 198

3, 1, 2^ 2, 1, 1 Ground 0 27 329.62 198

3, 1, 2^ 2, 1, 1 Ground 2 27 432.89 198

3, 1, 2<r- 2, 1, 1 Ground 3 27 487.70 198

3, 1, 3^ 2. 1, 2 Ground 0 26 079.47 198

3, 1, 3^ 2, 1, 2 Ground 1 26 165.87 198

3, 1, 3-^ 2. 1, 2 Ground 3 26 322.50 198

4, 0, 4^ 3, 0. 3 Ground 0 35 577.96 198

4, 0, 4<- 3, 0, 3 Ground 2 35 752.72 198

4, 0, 4-^ 3, 0, 3 Ground 3 35 846.64 198

4. 1. 3^ 3. 1. 2 Ground 0

1 36 436.03 1 198

191
700 - cis-l-Fluoropropene Molecular Constant Table

cis-a-Fluoropropylene; tis-Propenyl Fluoride C3H5F C,(C3v.Cs.Cs) CH3CH:CHF

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) D., K A

c-C'2H3C>2H:C'2HF'^-A 701 17 830.24 M 5 657.32 M 4 406.91 M 3.013 c-C'^HaC'^HiC'^HF'^-E 702 17 824.02 M 5 6.56.19 M 4 406.79 M

Id. No. /u-a Debye /X|, Debye fji^. Debye eQq V3 Acc. Irfd Wa d C0|, d (t)^. d Wti d

701 1.04 M 1.02 M 0. X 1057 50

References: ABC: 342 Dj: D.,k: k: A: 342

jLt: 342 eQq: V: 342 I: w:

192
cis-l-Fluoropropene Spectral l.iiic I able

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rot

State

orn FiHype

V

•rtinf FFrequency

MHz

Acc. ±MHz

\ Ket.

1

c-C'^HsC'^HiC'-HF'-'-A 701 1, u. 0, 0 A 0 10 064.23 .2 342

1, 1,

A,^ 1 U< 1, i A 0 13 423..33 .2 342

2. 0, 2^ 1. 0, 1

AA 0

OA Ao^; 00 zO 036. oz .2 342

2. 1. 2^ 1, 0. 1

AA

AU0 1 AC A 0(\ 0 q /1

1i , 1 1 1* i.1 A

u

AA

A

U zl 0/0.0/ 0.1 q /1

11, Z* i. 1, i A 0 18 877.93 .2 342

9 1 1 ,t 9z, A 9z A 0 14 765.85 .2 342

3, 0, 3^ 2, 0. 2

AA

A

U zy OZV.OD 0.z

q /1

o4z

3. 0, 3^ 2, 1. 2

AA 0

1 0 0 1 c do 0

.z q /1342

oJ, Jl.

0.,: 0

i. 11

AA 0

qO AAO OA 61 OOo.oO .2 342

O

"J?

11, q^ 0 11, z A 0 28 261.19 .2 342

I, z, AU A 0 30 555.37 .2 342

3, 1, 2«- 3, 0, 3

AA 0

1 £i (\A C OA 16 945.20 .2 342

3, 2, 1^ 3, 1. 2

AA 0 35 155.36 .2 342

0, 4<— A ^ q3, 1, 3

AA 0 OA AOO lA z9 9z3. /4 .2 342

4, 1, 3^ 4, 0, 4 A 0 20 136.88 .2 342

4, 2, 2*- 4, 1, 3 A 0 33 666.44 .2 342

r

-3. 1,

/) r 4<— 5, A r0

AA 0 z4 515.44 .2 342

rJ. z,

q^^ c 1i,

AA 0

on A OA 0 A 3z 4o0./4 .2 342

£.o,

1 0^ 0, A

0 A 0 30 187.73 .2 342

6, 2, 4^ 6, 1, 5

AA 0

0 1 nqo A 0 31 938.43 .2 342

7, 2, 5<- 7, 1, 6

AA

A

u

q 0 q qo "7i OZ 000. /0

.z

q/1

o4z

Q 9z. 0* p0,

11 7 AAA

u

q q AT '7 33 91 /.60 0

.z

q ,1

34z c-C^HjC'^HiCW^-E 702 11^ AU,

"1 4 A A A

U E 0 10 062.98 .2 342

1i. 1iA* 1 A 1i E 0 13 419.40 .2 342

2, 0, 2^ 1, 0, 1 Jb A

u OA AO/I AO ZU Uo^.^Hs 0.z

3/1 0 olz

2, 1. 2*- 1, 0, 1

T?H, Au ol U'tO. /o 0.z

3/1

OftZ 9z. 1 1 * i . 1i

Au

IT' Lj A

u

01 q7q OA zl 0 /o.yu 0.zq/i 0 o4z

z.

11

Z* 1

i-^ 1i E 0 18 877.90 .2 342

z,

11, i* Z, A

U, 9z E 0 14 759.00 .2 342

3, 0, 3^ 2, 0, 2

XT' 0 OA GO/: qA 29 OZ6.39 .2 342

3, 0, 3^ 2, 1, 2

T?h, Au

OA nOO "7/1 ZV yzz. /4 0

.z q /1o4z

q

i. z<— z. i. X A qo AAq o/:; OZ UUo.z6 0

.z q /1o4z

q

•J. i. 0^q . 0Z,

1i. z E 0 28 259.80 .2 342

qJ. i. A q0 E 0 16 936.38 .2 342

4, 1. 3^ 4, 0, 4 h 0 OA TOO l/i zO 123.76 .2 342

4, 2*— 4, \ 3 t 0 33 661.10 .2 342

5'

\. 4^ 5! 0^ .5 L 0 24 498.38 .2 342

5, 2. 3^ 5, 1, 4 E 0 32 471.40 .2 342

6. 1, .5^ 6, 0. 6 £ 0 •J\J lUO.OV .2 342

6. 2, 4^ 6, 1, 5 E 0 1 31 927.71 .2 342

7, 2, 5^ 7. 1, 6 E 0 32 325.08 .2 342

8. 2, 6^ 8, 1, 7 E 0 33 900.78 .2 342

193
710- trans-Fluoropropene Molecular Constant Table

trans-Fluoropropylene: trans-Propenyl Fluoride C3H5F Cs(C,,,.Cj CHjCHrCHF

Isotypic Species Pt. Gp.Id. No. A (MHz) B (MHz) C(MHz) Dj K A

711 42 680. M 3 878.34 M 3 637.02 M

Id. No. /j-a Debye Debye /X;. Debye eQq V:, Acc. ("a "d oj,, d (0^. d (0,1 d

711 1.85 M 0.02 M 0. X 2207 100

References: ABC: 189 Dj: D,,k:

' k: A:

ft: 189 eQq: V: 189 I: oj:

Rotational constants (first excited torsional state): B= 3891.52 MHz, C = 3624.22 MHz. Ref. 189.

194
trans-Fluoropropene Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Ace. Ref. No. Quantum Nos. State F' F" F F MHz ±MHz

711 9 z^ Q 1 Ground A 0 15 029.68 189

o 11 ^ 11

0 Ground I 15 115.1 189

2, 1, 1^ 1, 0 (Ground 15 271.35 .1 189

2, 1, 1^ 1, 0 Ground \ 0 15 272.05 189

z,9 1 }'

I 0 Ground A 1 15 298.7 189

9 1 z^ 1 Ground \ 14 761. 189

2, ] 2-^ 1 Ground 0 14 789.20 189

2, 1! 2^ 1; I, 1 Ground E 14 789.91 .1 189

2, 1, 1, 1 Ground E 1 14 944.2 189

3. 0, 3«— 2, 0, 2 Ground A 0 22 .541.90 189

3, 2<— 2, 1^ 1 Ground E 1 22 784.40 189

3 2<— 2^ 1 1 Ground A 0 22 907.60 189

3!

1' 2^ 2, ll 1 Ground E 22 908.10 .1 189

3, 1, 2-^ 2, 1, 1 Ground A 1 22 947.90 189

3 '" 3<— 2_ 2 Ground A 1 22 146.00 189

3 I 3<— 2_ I 2 Ground A 0 22 183.49 189

3 I 3<— 2 I 2 Ground E 22 184.00 .1 189

3! I, 3-^ 2'

I, 2 Ground E I 22 308.50 189

3, 2, 1^ 2, 2, 0 Ground E 22 548.08 .1 189

0, 2 }<_ 2 2 0 Ground A 0 22 550.06 189

3 2 2<— 2_ 2_ 1 Ground A 0 22 546.07 189

3

0, 2 2<— 2 2 1 Ground E 22 548.10 .1 189

4, 0! 4^ 3! 0! 3 Ground A 0 30 081.20 189

4, 1. 3^ 3, 1. 2 Ground E J 30 486.4 189

4 3.^ 3 I 2 Ground A 0 30 542.05 189

4 J 3<_ 3 I 2 Ground A 1 30 596.0 189 4 4^^ 3 I 3 Ground A I 29 527.6 189

4! li 4^ 3!

1" 3 Ground A 0 29 576.65 189

4, 1, 4^ 3. 1. 3 Ground E 1 29 638.0 189

4, 2^ 2«— 3. 2. 1 Ground A 0 30 071.05 189

4 2 2<— 3 2_ 1 Ground E 30 075.50 .1 189 4 2 3<— 3 2 2 (Ground E 30 056.33 .1 189

4! 2! 3-^ 3' 2! 2 Ground A 0 30 060.63 189

4, 3, 1^ 3, 3, 0 Ground A 0 30 063.60 189

4, 3, 2<- 3, 3, 1 Ground A 0 30 063.60 189

5. 0, 5^ 4, 0, 4 Ground A 0 37 554.80 189

5, 1, 5^ 4, 1, 4 Ground A n0 36 968.20 189

5, 2, 3^ 4, 2, 2 Ground E 37 590.00 .1 189

5. 2. 3^ 4, 2. 2 Ground A 0 37 595.6 189

5, 3. 2*- 4, 3, 1 Ground A 0 37 580.50 189

5. 3. 3^ 4. 3, 2 Ground A 0 37 580.50 189

195
720-2-Fluoropropene Molecular Constant Table

2-Fluoropropylene; Isopropenyl Fluoride C3H5F C,(C3v,Cs) CH3CF:CH2

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D., D.,K K A

721 10 169.40 M 9 041..36 M 4 927.16 M .56963 3.023

Id. No. /Xa Debye Debye fji^. Debye eQq V. Acc. CUa d d C^J^. d (0,i d

721 0.92 M 1.31 M 0. X 2440 16

1

References: ABC: 264 Dj: D,,k: k: 264 A: 264

ix: 264 eQq: V: 264 I: at:

V3=2432±ll cal/mol. Asymmetry Parameter for first exc. state: k=.565268. Coupling Parameter: Ia = 3.11 amu A-. Rotational constants for first exc. state: A= 10163.05 MHz, B= 9024.19 MHz., C = 4923.68 MHz. Ve < 50 cal/mol. Ref: 264.

2-Fluoropropene ' ' Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.

1\0. Quantum Nos. State n r r MHz itivirlz

L risL r :C n2 721 1, 0, 1^ 0. 0, AU Ground A 1

1 *? ri/i 0 AC io y4o.Uo .1 1, 0, 1^ 0, 0. 0 Ground 13 968.65 .1 264

1, 1, 1^ 0, 0. 0 Ground 15 096.93 .1 264

2, 0, 2^ 1, 0, 1 Ground A 24 727.07 .1 264

2, 0, 2^ 1. 0. 1 Ground E 24 728.61 .1 264

2, 0, 2«- 1, 0, 1 Ground 24 749.12 .1 264

2. 0. 2^ 1, 1, 1 Ground E 23 589.01 .1 264

2. 0, 2^ 1, 1. 1 Ground A 23 589.65 .1 264

2, 0. 2^ 1, 1, 1 Ground 23 621.03 .1 264

2, 1, 2^ 1. 0. 1 Ground A 24 932.50 .1 264

2, 1, 2-^ 1. 0. 1 Ground E 24 935.22 .1 264

2, 1, 2^ 1, 0, 1 Ground 24 950.96 .1 264

2. 1, 2<- 1, 1, 1 Ground A 23 795.23 -.1 264

2, 1, 2^ 1, 1, 1 Ground 23 822.91 .1 264

2, 1. 1^ 2, 0, 2 Ground 12 545.38 .1 264

2, 1, 1^ 2. 1, 2 Ground 12 343.48 .1 264

2, 2, 1^ 2, 1, 2 Ground 15 727.42 .1 264

3, 1, 2*- 3, 0, 3 Ground 22 562.48 J 264

3, 2, 1^ 3, 1, 2 Ground A 1 11 724.93 .1 264

3, 2, 1^ 3, 1, 2 Ground E 1 11 725.89 .1 264

3, 2, 1^ 3. 1. 2 Ground 11 760.50 .1 264

3, 2, 2^ 3. 1, 3 Ground A 1 23 465.32 .1 264

3, 2, 2^ 3, 1, 3 Ground E 1 23 472.10 .1 264

3, 2, 2^ 3, 1, 3 Ground 23 509.02 .1 264

3, 2. 1^ 3, 2, 2 Ground 10 790.88 .1 264

3. 3. 0^ 3, 2, 1 Ground 8 892.53 .1 264

4, 2, 4^ 4. 1, 3 Ground 21 481.14 .1 264

4, 2, 2^ 4, 2, 3 Ground 21 323.23 .1 264

4, 3, 1^ 4, 2. 2 Ground A 1 11 521.81 .1 264

4, 3, 1^ 4, 2. 2 Ground E 1 11 525.52 .1 264

196
2-Fluori>prijpene Spectral Line 1 al)le

Isotopic Species 1

Id. No.Rotational Quantum Nos.

Vib. State Int. Rotor

State n

1?' I?' r

rline

17' 17r

P retjuency

MHz

Acc. ±MHz

iiei

721 4, 3, 1<- 4, 2, 2 (iround 11 542.43 .1 264

4, 3, 2<— 4, 2, 3 Ground A 1 23 975.38 i .1 264

4, 3, 2^ 4, 2, 3 Ground E 1 23 983.98 1 .1 OA/1

4, 3, 2^ 4, 2, 3 (/round Z4 U1U.4Z

4, 3, 1<— 4, 3, 2 Ground 8 855.45 ;I

4, 4, 0«— 4, 3, 1 Ground 1 O Q Oil Q C

•| 264

4, 4, 0<— 4, 3, 1 Ground A 1 IZ 'too. .Do 264

4, 4, 0-^ 4, 3, 1 Ground E 1 |

9A/1

4, 4, 1-^ 4, 3, 2 Ground 1 n m*? AO ZO'r

5, 3, 2*— 5, 2, 3 Ground 19 977.08

5, 3, 2^ 5, 3, 3 Ground 19 369.15 264

5, 4. 1^ 5, 3, 2 Ground 12 291.71 264

5, 4, 1^ 5, 3, 2 Ground A 1 12 301.64 OA/1

5, 4, 1-^ 5, 3, 2 Ground E 1 12 311.73 OA/1 ZU4-

5, 4. 2^^ 5, 3, 3 Ground A 1 24 924.15 OA/1

5, 4, 2^ 5, 3, 3 Ground E 1 24 935.22 264

5, 4, 2^ 5, 3, 3 Ground 24 943.63 264

5, 5, 0-^ 5, 4, 1 Ground 16 984.60 264

5, 5, 1^ 5, 4, 2 Ground 23 028.32 ZO'+

6, 4, 6, 3, 3 Ground 18 479.63 Z04

6, 4. 2^ 6, 4, 3 Ground E 1 16 639.41 1 .1 264

6, 4, 2^^ 6. 4, 3 Ground A 1 16 651.87 I .1 264

6, 4, 2<- 6, 4, 3 Oround 16 778.12 1 .1 zo4'

6, 5. 1^ 6, 4. 2 Ground 14 285.60 264

6. 5, 1^ 6, 4, 2 Ground A 1 14 342.40 264

6, 5, 1^ 6, 4, 2 Ground E 1 14 363.37 264

7, 5, 2^ 7, 5, 3 Ground E 1 13 589.71 264

7, 5, 2^^ 7, 5. 3 Ground A 1 13 606.97 ZD*

7. 5. 2^ 7, 5, 3 Ground 13 753.18 ZD*

7, 6, 1^ 7, 5, 2 Ground 17 668.70 OA/1

8, 5, 3^ 8, 5, 4 Ground E 1 26 107.98 264

8, 5, 3^ 8, 5, 4 Ground A 1 26 125.28 264

8, 6, 2^ 8, 5, 3 Ground A 1 17 723.34 OA/1

8, 6. 2^ 8, 5, 3 Ground 17 727.50 OA/1

8, 6. 2-^ 8, 5, 3 Ground E 1 17 734.82 OA/1

8, 6, 2*— 8. 6. 3 Ground E 1 10 379.75 264

8, 6, 2^^ 8. 6, 3 Ground A 1 10 399.20 264

8, 6, 2^ 8, 6, 3 Ground 10 556.52 OA/1 Z04

8, 7. 1^ 8, 6, 2 Ground E 0 22 347.90 OA/1

8, 7, 1«— 8, 6, 2 Ground A 0 22 348.72 OA/1 ZO'+

9, 6, 3^ 9. 5, 4 Ground E 1 24 959.57 264

9, 6, 3<- 9, 5, 4 Ground A 1 24 969.90 264

9, 6, 3^ 9, 5, 4 Ground 25 116.76 OA/1 Z04

9, 6, 3^ 9, 6, 4 Ground A 0 22 866.67 OA/I Z04

9, 6, 3^ 9, 6, 4 Ground E 0 22 867.00 OA/I Z04

9, 7, 2^ 9, 6, 3 Ground E 0 19 318.79 264

9, 7, 2^ 9, 6, 3 Ground A 0 19 319.22 264

10, 7, 3^10, 6, 4 Ground E 1 23 411.49 264

10, 7, 3^10, 6. 4 Ground A 1 23 415.40 264

10, 7, 3^10, 6. 4 Ground 23 524.40 264

749-587 0-69— 14 197
2-Fluoropropene

Spectral Line Table

Isotopic Species

1

1 Id. Rotational 1 Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.

1 No. Quantum Nos. State n F'

1 F' 1 F1

1 F MHz ±MHz

C'2H3C'T'>*:C'2H2 721 10. 7. 3^10, 7. 4 1 Ground A 0 18 900.32 .1 264

1 Ground E 0

1 o c\{\r\ r>o 18 900.98 264

10. 8, 2^10, 7, '3

1 Ground E 0 22 496.34 ;J 264

10, 8. 2^10. 7, 3 Ground A 0 22 497.12 J 264

11, 8, 3^11, 7, 4 1 Ground A 1 23 039.75 \ 264

11, 8, 3^11, 7, 4 1 Ground E 1 23 048.95 ^1 264

11

1 i , O,Q 1i 17/1 i, i , '*

1 Ground OO A*70 OO z3 072.82 264

11, 8, 3^11, 8, 4 1 Ground E 1 14 427.78 264

11, 8, 3^11, 8, 4 Ground A 1 14 463.24 264

. ^ - 11. 8. 3^11. 8, 4 Ground A 0 14 732.60 264

11. 8, 3^11. 8, 4 Ground ' E 0 14 733.20 264

IZ, y, 6* Iz, o, 4 (jround E 0 24 187.55 264

12, 9, 3^12, 8. 4 Ground A 0 24 188.04 264

12, 9, 3^12. 8. 4 Ground A 1 24 256.57 264

12. 9. 3^12. 8, 4 Ground E 1 24 285.62 264

12, 9, 3^12, 9, 4 Ground E \ 10 433.24 264

li, 9, 3*—Iz, 9, 4 Ground A \ 10 467.23 264

12, 9, 3^12, 9, 4 Ground 0 10 727.50 264

12, 9, 3^12, 9, 4 Ground E 0 10 728.17 264

13. 9. 4-^13, 9, 5 Ground A 0 24 322.79 J 264

13, 9, 4^13, 9, 5 Ground E 0 24 323.70 264

1 /I 1 n /I 1 /I 1 r\ c 14, lU, 4*—14,1U, 0 Ground A 0 19 253.42 264

14,10, 4^14,10, 5 Ground E 0 19 254.38 264

15,11, 4^15,11. 5 Ground A 0 14 325.40 264

15,11. 4^15.11. 5 Ground E 0 14 326.40 264

16.12, 4^16.12. 5 Ground A 0 9 950.12 264

lo.iz, 4<—iD.lz. a Ground E 0 9 950.92 264

17.12, 5^17,12, 6 Ground A 0 24 117.22 264

17,12, 5^17,12, 6 Ground E 0 24 118.48 264

19,14, 5^19,14, 6 Ground A 0 13 019.59 264

19,14, 5^19,14. 6 Ground E 0 13 020.78 264

on 1 c OA 1 c /; zU.lo. O'^ZU.lo. 0 Ground A 0 8 668.27 264

20.15, 5^20.15. 6 Ground E 0 8 669.25 264

21,15, 6^21,15, 7 Ground A 0 22 635.18 264

21,15, 6^21,15, 7 Ground E 0 22 636.78 264

22,16, 6^22,16, 7 Ground A 0 16 460.77 264 001£ 00 1/C "7 zz, 16, 6^zz.l6, 7 Ground E 0 16 462.12 264

23,17, 6<-23,17, 7 Ground A 0 11 235.41 264

23,17, 6^23.17, 7 Ground E 0 11 236.52 264

25.18. 7^25.18. 8 Ground A 0 20 278.56 264

25,18, 7^25,18, 8 Ground E 0 20 280.18 264

o£ in "7,* o^; in o Ground A 01 A 1 c "7 no 14 157.08 264

26,19, 7^26.19. 8 Ground E 0 14 158.38 264

27,20, 7^27,20, 8 Ground A 0 9 307.38 264

27,20, 7^27,20, 8 Ground E 0 9 308.35 264

28,20, 8^28,20, 9 Ground A 0 24 475.02 •1 264

oQ on Q-^ OQ on Q ZO,ZU, O* ZO.ZU. V Ground E 0 1 OA All no z4 4/ / .Uz Z04

29.21. 8^29.21, 9 Ground A 0 17 444.90

;i 26429.21. 8^29,21, 9 Ground E 0 17 446.35 264

30.22. 8^30.22. 9 Ground A 0 1 11 726.82 264

30,22, 8^30.22. 9 Ground E 0 1 11 727.84 1

!

.1 264

198
730- Pn,|jionitrile \\<>U; uUf ( „n>lanl

PropanenitrilerEthvl Cvanide CsH.N ' Cs(C;,,.Cj c,h,(;n

Isotopic Species rPtI. Gp.

la. No. B (MHz) C(MHz) n K

A

IS

C'2H:,C'2H,C'-N'^ Cs 731 27 663.30 M 4 714.14 M 4 235.14 M .0035 -.0496 -.96 CmiC'-HX^N'-* 732 27 200. M 4 689.77 M 4 214.87 M

C'^D.C'-HDC'-N'^ c, 733 20 400. M 4 169.47 M 3 7,36.83 M

Id. No. fia Debye /u,|| Debye fjL,. Debye eQq V:, Acc. (ij., d oil, d oj,. d o),, d

731 3.78 M 1.38 M 0. X -3.3 3050 220 1

References: ABC: 178, 249 Dj: 249 Djk: 249 k: 249 A:

M: 249 eQq: 249 V: 249 I: w: 394

Propionitrile Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State

Vg

Int. Rotor

State n F Hype

; F'

rfine

F, F

Frequency

MHz

Acc. ±MHz

Ref.

C'^HjC'^HsC'^N'^ 731 1, 1, O'^ 1, 0, 1 Ground 23 428.1 .2 249

2, 0, 2<- 1, 0, 1 Ground 17 891.0 .2 249

2, 0, 2^ 1. 0, 1 Ground A 1 17 896.9 .2 249'

2, 0, 2^ 1. 0, 1 1 17 920.3 .2 249

2, 1, 1^ 1, 1. 0 Ground 18 377.5 .2 249

2, 1, 1^ 1, 1, 0 1 18 398.0 .2 249

2, 1, 2^ 1. 1. 1 Ground 17 419.8 .2 249

2, 1, 2^ 1, 1. 1 Ground A 1 17 431.3 .2 249'

2, 1. 2^ 1, 1, 1 1 17 457.6 .2 249

2, 1, 1^ 2. 0. 2 Ground 23 915.0 .2 249

3, 0, 3^ 2, 0, 2 Ground 26 817.80 .1 249

3, 0, 3^ 2, 0, 2 Ground A 1 26 829.3 .2 249'

3, 0, 3^ 2, 0. 2 1 26 860.5 .2 249

3, 1, 2«- 2, 1, 1 Ground 27 561.71 .1 249

3, 1, 2^ 2. 1. 1 Ground A 1 27 562.9 .2 249'

3, 1, 2^ 2. 1, 1 Excited 27 576.62 .1 178

3, 1, 2^ 2. 1, 1 1 27 592.2 .2 249

3, 1, 3^ 2, 1, 2 Ground 26 124.57 .1 249

3, 1, 3^ 2, 1, 2 Excited 26 143.64 .1 178

3, 1, 3^ 2, 1, 2 Ground A 1 26 144.2 .2 249'

3, 1, 3^ 2, 1, 2 Excited 26 180.33 .1 178

3, 1, 3^ 2, 1, 2 1 26 180.7 .2 249

3, 2, 1-^ 2, 2, 0 Ground 3 2 26 877.45 .1 249

3, 2. 1^ 2, 2. 0 Ground 26 878.27 .1 249

3, 2, 1^ 2, 2, 0 Ground E 1 26 878.3 .2 249

3, 2, 1^ 2, 2, 0 Ground 4 3 26 878.54 .1 249

3, 2, 1*- 2, 2, 0 Ground 2 1 26 879.08 .1 249

3, 2, 1^ 2, 2, 0 Ground A 1 26 885.3 .2 249'

3, 2, 1^ 2, 2, 0 1 3

i

26 922.1 .2 249

3, 2, 2-^ 2, 2, 1 Ground 2 26 847.89 .1 249

1 See footnotC/at end of table.

199
Propionitrile

Spectral Line Table

Rotational Vib. State Int. Rotor Hyperfine Frequency 1 Acc. Ref. Quantum Nos. St3.tC ^1V r 1 F r MHz ±MHz

3, 2, 2^ 2, 2, 1 Ground

1

1 26 848.70 • 1 249

3. 2, 2-^ 2, 2, 1 1 Ground A

4- qo 26 848.95 .1 249

3, 2, 2^ 2, 2. 1 Ground 9 1 26 849.51 .1 249

3, 2, 2*- 2, 2, 1 Ground /A. A 1 26 859.1 .2 249'

3, 2, 2^ 2. 2, 1 Ground E 1 26 866.1 .2 249

3, 2, 2^ 2, 2, 1 1 26 889.6 .2 249

o, I, z<— 3, 0. 3 Ground 24 658.69 .1 249

4, 0, 4^ 3, 0, 3 Ground 35 722.18 .1 249

4, 0, 4^ 3, 0, 3 Ground \ 35 742.5 .2 249'

4, 0. 4^ 3, 0, 3 1 35 776.5 .2 249

4. 1, 4^ 3, 1, 3 Ground 34 824.10 .1 249

4, 1, 4<— 3, 1, 3 1 34 898.0 .2 249

4, 1, 4^ 3, 1, 3 Ground A \ 35 855.2 .2 249'

4, 2, 2^ 3, 2, 1 Ground 35 866.1 .2 249

4, 2. 2^ 3, 2, 1 Ground E 1 35 867.6 .2 249

4, 2. 2*- 3, 2, 1 Ground AA

1I 35 871.8 .2 249'

4. 2, 2^^ 3, 2, 1 1 35 926.0 .2 249

4, 2, 3^ 3, 2. 2 Ground QO 35 791.80 .1 249

4. 2. 3^ 3, 2. 2 Ground 35 792.1 .2 249

4. 2. 3^ 3. 2. 2 Ground 5 4 35 792.29 .1 249

4. 2, 3^ 3, 2, 2 Ground oq 9 35 792.29 .1 249

4, 2, 3-^ 3, 2, 2 Ground A i 35 806.3 .2 249'

4. 2. 3^ 3, 2, 2 Ground Vn.

11 35 810.8 .2 249

4. 2, 3^ 3, 2, 2 1 35 844.6 .2 249

4, 3, 1^ 3, 3, 0 Ground 4 3 35 813.85 .1 249

4. 3. 1^ 3, 3, 0 Ground 35 814.6 .2 249

4, 3, l'^ 3, 3, 0 Ground Co

A4' 35 814.96 .1 249

4, 3, 1^ 3, 3, 0 Ground O

9Z 35i-8r4.96 .1 249

4, 3, 1^ 3, 3. 0 Ground AA

11 35 830.4 .2 249"

4, 3, 1^ 3, 3, 0 1 35 861.4 .2 249

4, 3, 2^ 3, 3, 1 Ground A QO 35 813.85 .1 249

4, 3. 2-^ 3, 3, 1 Ground 35 814.6 .2 249

4, 3, 2^ 3, 3, 1 Ground CD

/I 4- 35 814.96 .1 249

4, 3. 2<- 3, 3,^1 Ground oo

9 35 814.96 .1 249

4, 3, 2^ 3, 3, 1 Ground A 1 35 830.4 .2 249'

4, 3, 2^ 3. 3. 1 1 35 861.4 .2 249

4, 1, 3<— 4, 0. 4 Ground 25 676.20 .1 249

5, 0, 5^ 4, 1, 4 Ground 23 710.80 .1 249

5. 1, 4-^ 5. 0, 5 Ground 26 988.70 .1 249

6, 1, 6, 0, 6 Ground 28 622.28 .1 249

Not Reported Excited 27 626.49 .1 178

3. 0. 3^ 2, 0. 2 Ground 26 684.09 .1 178

3, 1, 2<— 2, 1, 1 Ground 27 421.62 .1 178

3. 1, 3^ 2. 1. 2 Ground 25 996.90 .1 178

3, 2, \^ 2. 2, 0 Ground 26 743.8 .5 178

3, 2, 2^ 2. 2. 1 Ground 26 713.9 .5 178

3, 0, 3^ 2, 0, 2 Ground 23 684.68 .1 178

3, 1, 2^ 2, 1, 1 Ground 24 362.51 .1 178

3, 1, 3^ 2, 1, 2 Ground 23 064.59 .1 178

3, 2, 1^ 2, 2, 0 Ground 23 745.08 .1 178

3. 2, 2^ 2, 2. 1 Ground

1 23 719.06 .1 178

Isotopic Species Id. No.

C'^H^C'-HX'^N'

C'2H.>C'2H,C''^N'*

C'^D,C''HDC'^N"'

731

732

733

1. The lines in the first excited torsiunal state identified to be of the A species may be of the unresolved AE states.

200
740 - Propene

Propylene; Methylethylene

Miilccular (^iiiislanl I alile

C.,(C..jv.C •Cjv) CH,CH:CH.,

Isotopic Species

1

Pt. Gp.Id. No. A(MH z) B(MHz) C(MHz) K A

C'-HaC'^HrC'^Hj Cs 741 46 070. M 9 SOS ?8 M 8 134.16 M 105.5 a-C'^HjDC'^HiC'^Hj Ci 742 44 085. M 8 658.80 M 7 718.14 M

s-C'-HjDC'-HrC'^Hs Cs 743 40 615. M 9 066.92 M 7 765.90 M

C'-HjC'-'HiC'^Ha Cs 744 45 296. M 9 304.16 M 8 107.13 M 101.6 c-C'-H3C'^H:C'^HD c, 745 M 9 037.30 M 7 727.27 M

t-C'-HjC'^HiC'^HD c, 746 M 8 .545.34 M 7 539.87 M

C'-HjC'-DiC'^Ho Cs 747 M 9 298.96 M 7 834.74 M

Cs 748 M 9 045.15 M 7 930.54 M

C>^H3C>-H:C'-'H2 Cs 749 M 9 045.54 M 7 928.40 M

t

Id. No. /ia Debye jLtb Debye jU.,. Debye eQq V:, Acc. OJa d oji, d c<j(. d oj,, d

741 0.360 M 0.05 M 0. X 1978 17

References: ABC: 181. 213, 327

M: 181 Add. Ref.: 298

eQq:

D,

V: 181

A: 181

Coupling Parameter: Ia = 3.120 amu A'-. Ref: 326.

201
Propene

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

741 11

,

0. 0. 0 Ground 17 439.49 .03 181

2, 0, 2*- 1, 0, 1 1 -.Fni 1 n H E 0 .03 181

2, 0, 2^ 1i n , u. 1 Ground AA

AU 34 851.52 !03 181

2, 1, 1^ 1. 1, 0 Ground E 0 36 049.29 .03 181

2. 1. 1^ 1. 1. 0 (V »rrn 7 1 l_» U1 n1 i HLI A 0 36 050 21 .03 181

2, 1, 2^ 1. 1, 1 Ground A 0 33 707.81 .03 181

2, 1, 2^ 1 Ground Hi AU 33 708.26 .03 181

742 1. 0. 1^ 0, 0. 0 ( -^rAi I n

H

yjri u liiiu 16i.yj 01377I . 15L\j .15 213

AU, 1, 0, 1 Ground 32 735.34 m 327

2, 1, 1. 1. 0 Ground 33 695.17 .05 327

2, 1. 2^ 1 Ground 31 813.36 .05 327

s-r'-H^DC'-Hr'^Hn 743 1, 0. 1^ 0, 0, 0 ( irnii nn 16 832.90 .15 213

2, 0, 2^ 1, 0. 1 Ground 33 626.41 !05 327

2 I 1«_ 1, 1. 0 Ground 34 966.94 .05 327

2! I, 2<- 1, 1, 1 Ground 32 364.93 .05 327

C'2H3C"H:C'2H2 744 1 nu. 1 ^ 0, 0, 0 Ground 17 411.29 .03 181

2, 0, 2^ 1, 0, 1 Ground E 0 34 793.13 .03 181

2, 0, 2^ 1i, nu. 1 Ground 4\ yl 34 793.38 .03 181

- 2, 1, 1^ 1. 1, 0 Ground E 0 36 019.03 .03 181 -

2, 1, 1^ 1, 1, 0 ( .rmi nrl A 0 36 019.84 .03 181

2, 1. 2<- 1, 1. 1 Ground A 0 33 625.62 .03 181

2. 1, 2*- 1 1 1, 1, 1 Ground A

U 33 626.01 .03 181

„ ri2T-r pl2IJ.pi2I-fr) 745 2; 0. 2<- 1, 0. I V7I UtillU 33 499 06 .05 327

2. 1, 1^ 1, 1, 0 Ground E 0 34 849.69 .05 327

2. 1. 1<— 1. 1. 0 Ground 34 850.14 .05 327

2, 1. 2^ 1, 1, 1 Ground 32 229.17 .05 327

t-C'2H3C'^H:C'-HD 746 2, 0, 2->- 1, 0, 1 Ground A 0 32 160.37 .05 327

2. 1, 1^ 1, 1, 0 Ground E 0

^1 185 46 .05 327

2. 1, 1*— 1, 1, 0 Ground A 0 33 186.35 .05 327

2, 1, 2^ 1, 1, 1 Ground A 0 31 174.64 .05 327

2, 1. 2^ 1 Ground 1?

li, Au 31 175.18 .05 327

pi2TJ ri2T\.ri2TJ 747 2, 0, 2^ 1. 0, 1 V.7 1 (_Hi 1 1

U

34 223.64 .05 327

1

* 1, 1, 0 Ground E 0 35 742.37 !05 327

2, 1, 1*- 1, 1, 0 Ground 35 742.81 .05 327

2, 1, 2*- 1 1 1 Ground 32 813.39 .05 327

pl3IJ pl2U.pI2I-f 748 2, 0, 2^ 1. 0, 1 ( .rri 1 1 n H 33 937.14 .10 327

2, 1, 1^ 1, 1, 0 Ground E 0 35 076.09 .7 327

2, 1, 1^ 1. 1, 0 Ground 35 077.02 .10 327

2. 1, 2^ 1, 1, 1 Ground 32 847.20 .10 327

C'2H3C'2H:C"H2 749 2. 0. 2^ 1, 0, 1 Ground 33 933.42 .10 327

2, 1, 1^ 1. 1, 0 Ground E 0 35 075.07 .7 327

2, 1, 1*- 1, 1, 0 Ground 35 076.09 .10 327

2, 1, 2<- 1, 1. 1 Ground 32 841.16 .10 327

202
750 - Acetone

2 -Propanone;Dimethyl Ketone

C.,H„0 ^2v(C3v,C3v,C^v)

Moli-culai- Coiislaiil Talile

(CH.i)2C0

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) D., D.,K K A

(C'2H.,)2C'20'" C2V

C2V

751 752

10 165.20 M

8 469.40 M

8 515.27 M

6 419.60 M

4 910.15 M

4 011.28 M

Id. No. /j-a Debye ix„ Debye fji^. Debye eQq v.. Acc. OJa d &>i, d tOj. d d

751

752

0. X 2.90 M 0. X 274

2.58

References: ABC: 271 Dj: D.,k: k:

fj.: 271 eQq: V: 271 I: Add. Refs.: 62. 237

Rotational Constants:

(C'2 H3)2C'20'« Torsional State (C'^DsfeC'^O's A =

B =

C =

10185.99 MHz

8519.75 MHz

4910.05 MHz

A and B A =8471.50 MHz

B = 6420.00 MHz

C = 401 1.26 MHz

A =

B =

C =

10170.40 MHz

8516.33 MHz

4910.15 MHz

Q A =8469.94 MHz

B = 6419.68 MHz

C= 4011.28 MHz

A =

B =

C =

10154.81 MHz

8513.10 MHz

4910.15 MHz

E A =8468.34 MHz

B = 6419.42 MHz

C = 4011.30 MHz

Ia = 3.138 Rotational Parameter

Ref: 271.

la =6.272

Acetone

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

751 1, 1. 1^ 0. 0, 0 Ground EE 0 15 038.47 .04 2712

1, 1, 1^ 0. 0, 0 Ground E3 0 15 064.91 .04 271

1, 1, 1-^ 0, 0, 0 Ground EE 0 15 074.05 .04 27P

1, 1, 1^ 0, 0, 0 Ground A 0 15 096.36 .04 271

2, 0. 2^ 1. 1, 1 Ground EE 0 20 820.89 .04 27P

2, 0, 2^ 1. 1, 1 Ground 0 22 793.22 .04 271

2, 0, 2<- 1, 1, 1 Ground E3 0 22 794.24 .04 271

2, 0, 2<- 1. 1, 1 Ground EE 0 22 800.37 .04 271'

2, 1, 2<- 1, 0, 1 Ground EE 0 24 876.48 .04 27P

2, 1, 2^ 1, 0, 1 Ground E3 0 24 888.30 .04 271

2, 1, 2^ 1, 0, 1 Ground EE 0 24 899.44 .04 271'

2, 1, 2*- 1, 0, 1 Ground A 0 24 916.41 .04 271

2, 2, 1^ 1. 1, 0 Ground EE 0 35 220.0 .04 27P

2, 2, 1^ 1. 1, 0 Ground E3 0 35 371.46 .04 271

2, 2. 1^ 1. 1, 0 Ground EE 0 35 381.40 .04 271'

1. These lines correspond to the 0 levels in Swalen and Costain's article. Due to incompatibihty of notation they were indicated only as doubly-degenerate excited lines.

2. These lines correspond to the Ei and E2 lines in Swalen and Costain's article. Due to incompatibility of notation they were indicated only as doubly-degenerate excited lines.

203
Acetone

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref.

! No. Quantum Nos. State n f; F' F MHz ±MHz

(C'-H:,).C'-0"^ 751 2, 2, 1^ 1, 1, 0 Ground A 0 35 468.06 .04 271

\ Not Reported 22 410. 5. 19 Not Reported 22 500. 5. 19 Not Reported 22 560. 5. 19 Not Reported 22 940. 5. 19

Not Reported 23 339. 5. 19 Not Reported 23 603. 5. 19 Not Reported 23 661. 5. 19 Not Reported 23 749. 5. 19

i^oL iiepoi Leo 23 778. 5. 19

Not Reported 23 793. 5. 19 Not Reported 23 827. 5. 19 Not Reported 23 839. 5. 19 Not Reported 23 934. 5. 19

l' Not Reported 24 102. 5. 19

Not Reported '24 646. 5. 19 Not Reported 24 691. 5. 19 Not Reported 24 758. 5. 19 Not Reported 26 661.5 62 Not Reported 28 340.0 62

Not Reported 28 622.3 62 Not Reported 30 070. 62

752 1. 1, 1^ 0. 0, 0 Ground E 0 12 479.45 .04 271

1, 1. 1^ 0, 0, 0 Ground EE 0 12 481.21 .04 271'

1. 1, 1^ 0, 0, 0 Ground A 0 12 482.76 .04 271

2, 0. 2^ 1, 1. 1 Ground A 0 17 589.27 .04 271

Z.0 U,

f\ z*0* 111 i, i, 1 Ground EE 0 17 589.80 .04 271'

2, 0. 2^ I. I. 1 Ground E 0 17 590.35 .04 271

2, 1, 2^ 1, 0, 1 Ground E 0 20 502.24 .04 271

2, 1, 2^ 1, 0. 1 Ground EE 0 20 503.80 .04 271'

2, 1. 2^ 1, 0, 1 Ground A 0 20 505.26 .04 271

2, 2, 0^ 1, 1, 1 Ground E3 0 33 046.62 .04 271

2, 2, 0^ 1, 1, 1 Ground E, 0 33 047.70 .04 271

2, 2, 0^ 1, 1, 1 Ground EE 0 33 051.65 .04 271'

2, 2, 0*- 1, 1, 1 Ground A 0 33 056.22 .04 271

2, 2, 1^ 1. 1. 0 ( .rniinH E, 0 ?9 41 5 18 .04 271

2, 2. 1^ 1. 1, 0 E^ 0 ?9 416 '78 .04 271

2, 2, 1^ 1, 1, 0 (iround EE 0 29 420.63 .04 271'

2, 2, \^ 1. 1, 0 Ground A 0 29 425.84 .04 271

3. 2, 2^ 2, 1, 1 Ground E 0 37 438.80 .U'i 271

3, 2, 2^ 2, 1, 1 Ground EE 0 37 443.15 .04 271'

3, 2, 2^ 2. 2, 1 Ground A 0 37 447.95 .04 271

1. These lines correspond to the Q levels in Swalen and Costain's article. Due to incompatibility of notation they were indicated only as doubly-degenerate excited lines.

204
760- 1,2-Epoxypropane Molecular Consluiil I able Propylene Oxide; Propane Oxide; Methyloxirane

CgHgO C,(C,v.C,) CH.,C*H0C*H2

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) D,, D..K K A

C'2H3C'%HO"'C'%H2 c, 761 18 02.3.72 M 6 682.12 M .5 951.48 M 2.97 4.20 -.8790

Id. No. /Xa Debye Debye /x^. Debye eQq V:, Acc. Ola d w„ d CO,, d aj,| d

761 0.95 M 1.67 M 0..56 M 2560 70

References: ABC: 191 Dj: 212 D.,k: 212 k: 191 A:

fji: 191 eQq: V: 212 I: m:

Coupling parameter: Ia= 3.194 amu A-. Ao=4.11 MHz. Ref: 212. Rotational constants (v= 1): for state A, A= 18010.82 MHz, B = 6669.93 MHz, and C = 5944.82 MHz; for state E, A= 18016.20 MHz,

B = 6670.01 MHz, and C= 5945.10 MHz. Asymmetry parameters (v= 1): for state A. k = - .879809; for state E, k = - .879893. Ref: 191.

1,2-Epoxypropane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rot or Hyperfine Frequency Acc. Ref. No. Quantum NOS State n F' F MHz j ±MHz

C'^HaC'^HO'^C'^Hz 761 0. 1^ 0. 0. 0 Ground E 2 12 595.01 214

0, 1^ 0, 0. 0 Ground A 2 12 598.99 214

0, 1^ 0. 0, 0 Ground 1 12 614.92 214

0, 1^ 0, 0, 0 Ground 12 633.52 214

1, 0^ 0. 0, 0 Ground 24 705.86 214

1, 1^ 0. 0, 0 Ground A 1 23 955.64 214

1. 1^ 0, 0, 0 Ground E 1 23 960.29 214

1, 1^ 0, 0, 0 Ground 23 975.20 214

1, 1^ 0. 0, 0 Ground A 2 24 032.19 214

1, 0^ 1, 0, 1 Ground 12 072.04 214

1, 1, 1^ 1, 0, 1 Ground 11 341.70 214

2, 0, 2^ 1. 0, 1 Ground E 2 25 156.18 214

2, 0. 2^ 1. 0, 1 Ground A 2 25 165.43 214

2, 0, 2^ 1, 0, 1 Ground 25 196.48 214

2, 0, 2^ 1, 0, 1 Ground 25 232.90 214

2, 0, 2^ 1. 1, 1 Ground E 1 13 851.47 214

2, 0. 2^ 1. 1, 1 Ground A 1 13 855.30 214

2, 0, 2^ 1. 1. 1 (Ground 13 891.15 214

2, 1. 1^ 1. 0. 1 Ground A 1 38 021.11 214

2, 1, 1^ 1, 0. 1 Ground E 1 38 026.70 214

2, 1, 1^ 1. 0. 1 (Ground 38 070.06 214

2, 1, 2^ 1, 0, 1 Ground E 2 35 566.15 214

2, 1, 2^ 1, 0, 1 Ground A 1 35 845.46 214

2, 1, 2^ 1, 0, 1 Ground E 1 35 850.67 214

2, 1, 2^ 1, 0, 1 Ground 35 878.14 214

205
1 ,2-Epoxypropane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State

1 Int. Rotor Hyperfine Frequency

1 Acc.

1 Ref.

1 No.

1 Quantum Nos.

1

State n F'

1 F'

1

1 F

1

1 F

1 MHz

1

1 ±MHz

C'2H3C'-*HO"'C'%H2 761 2, 1. 2^^ 1, 0, 1 Ground A 2 35 913.04 .1 214

2, 1. 1^ 1. 1. 0 Ground 2.5 997.85 .1 214

2. 1. 2^ 1, 1, 1 Ground 24 536.55 .1 214

2, 1, l'^ 2, 0. 2 Ground A 1 12 825.07 .1 214

2, 1, 1^ 2, 0, 2 Ground E 1 12 830.22 .1 214

2, 1. 1^ 2, 0, 2 1 Ground 12 837.32 .1 214

2, 1, 1^ 2, 0, 2 Ground A 2 12 901.27 .1 214

2, 2, 0^ 2, 1, 1 Ground A 1 34 055.65 .1 214

2, 2, 0*- 2, 1, 1 Ground 34 058.49 .1 214

2, 2, 0^ 2. 1. 1 Ground E 1 34 111.51 .1 214

2, 2, 1^ 2. 1, 1 Ground E 1 33 997.63 .1 214

2, 2. 1^ 2. 1, 1 Ground A 1 34 022.78 .1 214

2, 2, 1^ 2. 1. 1 Ground 34 024.55 .1 214

2, 2, 1^ 2, 1, 2 Ground E 1 36 173.03 .1 214

2. 2. 1^ 2. 1, 2 Ground A 1 36 198.17 .1 214

2, 2, 1^ 2, 1, 2 1 Ground 36 216.40 .1 214

3, 0, 3^ 2, 0, 2 Ground E 2 37 651.04 .1 214

1 3, 0, 3^ 2, 0, 2 Ground A 2 37 666.36 .1 214

3, 0, 3^ 2, 0, 2 Ground 37 710.31 .1 214

3, 0^ z.9 n 2 Ground 37 764.,55 .1 214

"- 3, no.

11

,

2 1 Ground A 0z 26 918.07 .1 214

3, u, 1 2 Ground rHi i 27 056.70 .1 214

3, 0, 3^ 2. 1, 2

' 1vtIIJUIIO .m1 1 mH AA

"11 z 1 uu 1.01 ]^ 214

3, 0, 3^ 2. 1, 2 Ground 97 1 10 10 1 214

3

nu. 0* Z,

11

,

2 Ground E 2 97 94.0 8=; n

. 1 Z91d14-

3, 1, 2*- 2, 1, 1 j Ground E 2 38 757.75 .1 214

3, 1, 2*- 2! 1, 1 Ground A 2 38 852.54 .1 214

3, I, 2^ 2' h 1 Ground 1 38 910.96 .1 214

3. 1, 2^ 2, 1, 1 Ground 38 974.35 .1 214

3. 1, 3^ 2. 1. 2 Ground A 2 36 700.24 .1 214

3, 1, 3<— 2, 1, 2 1 Ground A 1 36 736.13 .1 214

3. 1. 3<— 2. 1, 2 Ground E 1 36 737.03 .1 214

3, 1, 3^ 2. 1, 2 Ground E 2 36 774.08 .1 214

3, 1, 3^ 2, 1, 2 1 Ground 36 783.14 .1 214

3. 2, 1<- 2, 2, 0 1 Ground E 2 37 855.93 .1 214

3, 2, 1<— 2, 2, 0 1 Ground A 2 37 926.73 .1 214

3. 2. 1^ 2' 2, 0 Ground E 1 37 954.79 .1 214

3. 2" 1^ 2^ 2^ 0 Ground A 1 37 979.00 .1 214

3. 2, 1^ 2, 2, 0 Ground 38 036.22 .1 214

3. 2, 2^ 2, 2, 1 Ground A 2 37 796.16 .1 214

3. 2, 2<— 2, 2, 1 Ground A 1 37 844.07 .1 214

3. 2, 2^ 2, 2, 1 Ground E 2 37 853.03 .1 214

3. 2^ 2^ 2^ 2^ 1 Ground E 1 37 869.28 .1 214

3. 2. 2^ 2, 2. 1 Ground 37 900.09 .1 214

3, 1, 2^ 3, 0, 3 (i round A 1 14 025.86 .1 214

3, 1, 2^ 3, 0, 3 1 Ground E 1 14 030.68 .1 214

3, 1, 2^ 3, 0. 3 1 Ground 14 047.52 .1 214

3, 1, 2^ 3, 0, 3 (-round E 2 1 14 084.31 .1 214

3, 1, 2^ 3, 0, 3 Ground A 2 1 14 087.32 .1 214

3, 2. 1^ 3, 1, 2 Ground 1 33 120.72 .1 214

206
1,2-Epoxypropane Spectral IJne Table

Isotopic Species Id.

ATINo. Rotational Quantum Nos.

Vib. State Int. Rotor

State n

Hlype F'rfine F

Frequency

MHz

Acc. ±MHzKel.

C'-H3C'2*HO"'C'%H2 761 3, 2, 1^ 3, 1, 2 (iround A 1 33 124.24 214

3, 2, l'^ 3, 1, 2 Ground E 1 33 155.45 !i 214

3, 2^ 2^ 3^ \\ 2 (irouiid 32 9,50.24 •1 214

3, 2, 2^ 3, 1, 2 (iround 1 32 956.15 •1 214

3, 2, 2^ 3, 1, 3 (Ground E 1 37 .305.41 1 214

3, 2, 2<- 3, 1, 3 Ground A 1 37 306.66 214

3, 2, 2-^ 3, 1, 3 Ground 37 333.28 A 214

4. 1, 3^ 3, 2, 2 Ground A 0 18 972.75 •1 214

4, 1, 3^ 3, 2, 2 Ground E 0 18 973.03 1 214

4, 1, 4^^ 3, 2, 1 Ground 11 502.18 • 1 214

4, 1, 3^ 4, 0, 4 (.ir(»und A 1 15 738.20 214

4! 1,' 3<— 4, 0, 4 (iround E 2 15 741.10 A 214

4! \\ 3<- 4^ 0^ 4 (iround E 1 15 742.20 1 214

4, 1, 3^ 4. 0. 4 Ground 15 775.13 1 214

4, 1, 3^ 4, 0, 4 Ground A 2 15 777.87 • 1 214

4, 2, 2<— 4. 1^ 3 Ground 32 041.80 214

4" 2' 2<— 4. 1^ 3 Ground A 1 32 049.35 !i 214

4"

2. 2^ 4"1! 3 Ground E 1 32 065.55 1 214

4. 2. 3<- 4, 1, 4 Ground 38 834.10 1 214

c3> 1 A ^ C n

(J, c0 Ground Z 18 015.71 1 214

r

t>. 1,

j\ ^ C 4* 0, n

u.

cD (V

»y roI v7 1HI1 n1 Hu

*A i 1 8 045 84 214

r0.1i. 4^ 0,r0 Ground 1 18 048.95 'i 214

5. 1, 4^ 5, 0. 5 Ground A 2 18 053.85 .1 214

5, 1, 4^ 5, 0, 5 Ground 18 104.06 214

ra. z.

n ^ r 3<— 0, 1, Ground AU 30 961.14 .1 214

5 2 3<— 5 ]^ 4 Ground A 0 30 961.40 214

5. 2 3*— 5 ]^ 4 Ground A J 30 973.40 A 214

5" 2' 3^ 5!1' 4 Ground E 1 30 990.50 1 214

6, 2, 4^ 5, 3, 3 Ground A 0 19 105.40 1 214

6, 2^ 4«— 5^ 3, 3 Ground 0 19 106.02 1 214

6, 2, S'^ 5, 3, 2 Ground A 0 16 786.62 214

6, 2, 3^ 2 Ground E 0 16 786.96 !i 214

6^ 1! 5^ 6^ 0! 6 Ground E 2 20 963.10 •1 214

6, 1, S'^ 6, 0, 6 Ground A 2 20 995.83 -1 214

6, 1, 5-^ 6, 0, 6 Ground A 1 21 029.92 -1 214

6, 1. 5<— 6. 0. 6 Ground E 1 21 032.25 214

6'

1, 5^ 6, 0. 6 Ground 21 115.40 .1 214

6^ 2, 4^ 6'

1, 5 Ground E 0 30 038.11 1 214

6, 2, 4^ 6. 1, 5 Ground A 0 30 038.37 •1 214

6, 2, 4^^ 6, 1. 5 Ground A 1 30 048.77 1 214

6, 2, 4^ 6, 1, 5 Ground E 1 30 064.48 214

5' 5' 4' 3 Ground 16 653.80 A 214

l\ 2! 5^ 3! 4 Ground A 0 33 018.10 • 1 214

7. 2. 5^ 6, 3. 4 Ground E 0 33 018.62 • 1 214

7, 2, 6^ 6, 3, 3 Ground 28 938.18 1 214

7. 1. 6^ 7. 0, 7 Ground E 2 Z'i 000.OU Zll

7. 1. 6^ 7, 0, 7 Ground A 2 24 663.52 214

7, 1, 6^ 7, 0. 7 Ground A 1 24 749.23 214

7, 1, 6^ 7, 0. 7 (iround E 1 24 750.32 214

7, 1, 6^ 7, 0, 7 Ground 24 869.10 214

207
1 ,2-Epoxypropane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

C'-H3C'-*HO"'C'^H2 761 7, 1, 5^ 7, 1. 6 Ground 25 436.20 •1 214

7, 2, 7, 1, 0 Ground E 0

01/1 zl4

7. 2, 5^ 7, 1, 6 Ground A 0 29 435.50 ;i 214

7 z. 1, 6 Ground A 1 29 438.42 .1 214

7, 2, 5^ 7, 1, 6 Ground E 1 29 452..50 .1 214

7. 6, ^ 8, 5, Ground E 0 27 428.17 1 214'

7, 6, ^ 8. 5, Ground E 0 Z / '+ZO..JZ

7, 6, ^ 8, 5, Ground A 0 27 429.04 \i 214'

Qo.

Q

•J. 4, 4 Ground E 0 20 049.26 .1 214

8. 3. 5^ 7, 4, 4 Ground A 0 20 053.31 .1 214

8. 3, 5^ 7, 4, 4 Ground E 0 20 054,58 •1 214

8. 3, 6^ 7, 4, o Ground

8, 3, 6^ 7, 4, 3 Ground E 0 19 603.72 \i 214

8, 1, 7-^ 8, 0, 8 Ground A 2 29 075.76 .1 214

8. 1, 7^ 8, 0, 8 Ground E 2 29 082.36 .1 214

8. 1, 7*- 8, 0, 8 Ground 29 220.78 •1 214

8, 1, 7^ 8, 0, Qo Ground zV ooU.oo Z14'

8, 1, 7^ 8. 1. 8 Ground 25 853,9 J 214

8. 2, 6*- 8, 1, 7 Ground A 1 29 289,95 .1 214

8, 2, 6^ 8, 1, 7 Ground E 0 29 301,61 .1 214

- '-

8, 2, 6^ 8. 1, 7 (iround A 0 29 301,82 •1 214

8. 2, 6^ 8, 1. 7 Ground E 1 Ol /I Zl^

8, 2, 7^ 8, 1, 7 Ground 22 912.6 ;} 214

8, 6, 3^^ 9, 5, 4 Ground 14 701,45 214

9. 3, 6*- 8, 4, 5 Ground A 0 33 247.86 214

9. 3. 6^ 8. 4, .5 Ground E 0 33 248.84 214

9, 3, 7^ 8, 4,

/I Ground A 0 OZ .1 1 214

9, 3, 7^ 8. 4. 4 Ground E 0 32 347.71 214

9, 4, 8, 5, 4 Ground A 0 8 906.22 214

9, 4, 5^ 8, 5, 4 Ground E 0 8 907.53 214

9, 1, 8^ 9, 0, 9 Ground A 2 34 201.56 214

9, 1, 8^ 9, 0, Ground E 2 34 254.08 214

9. 1, 8^ 9, 0, 9 Ground E 1 34 407.03 I .1 214

9. 1, 8<— 9, 0, 9 Ground A 1 34 408.24 214

9, 1, 8«- 9, 0, 9 Ground 34 611.20 214

9, 2. 7^ 9, 1, 8 Ground A 1 29 730,32 214

9, 2. 7^ 9, 1, oo Ground E 1 29 740,80 214

9, 2, 7^ 9, 1, 8 Ground E 0 29 764,80 214

9, 2, 1-^ 9, 1, 8 Ground A 0 29 765.05 214

9, 2, 8^ 9, 1, 8 Ground 20 234.15 214

9, 7, ^10, 6, Ground E 0 25 479.05 214'

9, 7, ^10, 6, Ground A 0 25 480.04 214'

10, 4, 6^ 9, 5, 5 Ground E 0 21 772.39 214

10, 4, 6^ 9, 5, 5 Ground A 0 21 774.11 214

10, 4, 6^ 9, 5. 5 Ground E 0 21 776.73 214

10, 4, 7^ 9, 5, 4 Ground E 0 21 700.53 214

10, 4, 7^ 9, 5, 4 Ground A 0 21 701.65 214

10, 4, 7^ 9. 5. 4 Ground E 0 21 704.80 214

10, 1, 9^10, 0,10 Ground 40 469.72 214

10, 2, 8^10, 1, 9 Ground A 1 1 1 30 864.26 j .1 214

1. In the labeling of transitions, the K+i subscript has been omitted whenever the asymmetry sphtting of the rotational levels is less than .1 MHz.

208
1,2-E poxy propane .Spectral l-iiic I able

Isotopic Species Id. Rotational Vih. Slate Int. K( ptor Ilyperfint Fre<iuency Ace. Ref. No. Quant iini Nos. State n F' F MHz ±MHz

761 10. 2. 8^10, 1, 9 (_i round E 1 1 .30 872.70 214

10, 2, 8^10, 1, 9 Ground 30 930.46 !i 214

11, 4, 7*-io. 5, 6 Ground E 0 j 34 722.35 •1 214

11^ 4^ 7^10' 5^ 6 Ground A 0 34 724.83 1 214

11, 4, 7-^10, 5, 6 Ground E 0 34 726.82 •1 214

11. 4, 8^10, 5. 5 Ground E 0 34 570.45 214

11, 4, 8^10, 5. 5 Ground A 0 34 571.04 A 214

11, 4, 8'^10, 5, 5 Ground E 0 34 574.92 • 1 214 u. 5. 6^10, 6, 5 Ground A 0 10 845.88 1 214

11, 5, 6^10, 6, 5 Ground E 0 10 846.38 • 1 214

11, 2, 9*-ll, 1,10 Ground A 1 32 777.28 214

11, 2, 9^11, 1,10 Ground E 1 32 782.77 '.\ 214

11, 2. 9<-ll, 1,10 Ground 32 883.48 • 1 214

11, 8, ^12, 7, Ground E Q 23 526.15 .1 214'

11, 8, ^12, 7. Ground A 0 23 527.00 • 1 214'

12, 5, 7^11, 6. 6 Ground E 0 23 679.29 214

12, 5, 7^11, 6, 6 Ground A 0 23 680.51 '.\ 214

12, 5, 7^11, 6, 6 Ground E 0 23 683.96 1 214

12'

5, 8^11, 6' 5 Ground E 0 23 668.22 1 214

12, 5, 8<-ll, 6, 5 Ground A 0 23 670.17 .1 214

12, 5, 8^11. 6, 5 Ground E 0 23 672.94 214

12, 2,10*-12, 1.11 Ground 1 35 .537^88 'a 214

iz. 2,10^12, 111 Ground 35 690.23 .1 214

13, 5, 8*-12, 6, 7 Ground E 0 36 563.90 .1 214

13. 5. 8^12. 6. 7 Ground A 0 36 565.29 .1 214

13, 5, 8^12, 6, 7 vrrounc E 0 OU 000.4-1 91 d

13. 5. 9^12, 6, 6 Ground E 0 36 540.92 A 214

io. 5. 9^12, 0, 0 Ground A 0 36 542.27 .1 214

13, 5. 9^12. 6. 6 Ground E 0 36 545.43 .1 214

13, 6. 7^12. 7. 6 Ground A 0 12 801.74 .1 214

13, 6. 7^12. 7. 6 v)" round E 0 1Li.9 809 00.-. 4.8 4*0 214

13. 2.11^13. 1,12 Ground 39 388.43 'a 214

13, 9, *-14, 8 Ground E 0 21 568.32 .1 214'

13, 9, ^14, 8^ Ground A u 21 569.20 .1 214'

14, 6. 8^13, 7, 7 Ground 25 623.46 .1 214

14. 6. 9^13, 7, 6 Ground A 0 25 622.24 214

14, 6. 9^13, 7, 6 Ground E 0 25 623.66 A 214

15, 7. ^14, 8. Ground A 0 14 760.68 1 214'

15. 7. ^14. 8^ Ground E 0 14 761.60 1 214'

15.10. ^16. 9. Ground E 0 19 608.29 1 214'

15,10. ^16, 9, Ground E 0 19 608.64 214'

15.10. ^16. 9. Ground A 0 19 609.28 !i 214'

16. 7. ^15. 8, Ground A 0 27 575.98 1 214'

16. 7. ^15, 8. Ground E 0 27 576.76 •1 214'

17, 8, ^16, 9, Ground A 0 16 721.31 1 214'

17, 8, *-16, 9, Ground E 0 16 lll.li 214'

17,11, ^18,10, Ground E 0 17 645.83 214'

17.11. *-18,10, Ground E 0 17 646.35 214'

17.11. ^18,10, Ground A 0 17 646.86 214'

18. 8. ^17, 9, (; round A 0 29 530.32 214'

1. See footnote preceding page.

209
1,2-Epoxypropane

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor [ Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F,' F' EI F MHz ±MHz

C'-H^C'^HO-'^C'^H, 761 18. 8. ^17. 9. Ground E 1 29 531.24 .1 214'

19. 9. ^18.10, Ground A 0 18 682.74 214'

19, 9. ^18.10. ( iround E 0 18 683.46 j 214'

19. 9. ^18,10, Ciround E 0 18 683.77 214'

• 19,12. •^20,11. Ground E 0 15 681.55'j 214'

19.12. *-20.11, Ground A 0 15 682.39 214'

20, 9. •^19,10, Ground A 0 31 486.76 214'

20. 9. ^19.10. Ground E 0 31 487.41 | 214'

20. 9. ^19.10, Ground E 0 31 487.79 A 214'

21.10. ^20.11, (Ground A 0 20 644.92 214'

21.10. ^20.11. Ground E 0 20 645.46 .1 214'

21.10. «—20.11, (jround E 0 20 645.91 •1 214'

21.13. *-22.12. C/round E 0 13 715..56 .1 214'

21.13, •^22,12. Ground A 0 13 716.40 214'

22,10, «-21,ll. Ciround A 0 33 444.73 214'

22.10. ^21,11, Ground E 0 33 445.03 .1 214'

22,10. ^21,11, Ground E 0 33 445.65 • 1 214'

22,14. <-23,13, Ground E 0 24 484.77 214'

22,14. ^23,13. Ground A 0 24 485.56 214'

23.11. ^22,12. Ground A 0 22 607.49 214'

23.11. ^22.12, Ground E 0 22 607.74 .1 214'

23,11, *-22.12. Ground E 0 22 608.43 }

214'

23.14. ^24,13. Ground E 0 11 747.79 214'

23,14, ^24,13, Ground A 0 11 748.57 214'

23,15, «-24,14, Ground E 0 35 237.97 l 214'

23,15, ^24.14. Ground A 0 35 238.67 .1 214'

23,15. ^24.14. Ground E 0 35 238.97 .1 214'

24.11. <-23,12, (iround A 0 35 402.99 .1 214'

24,11, ^23,12, (iround E 0 35 403.15 214'

24,11. ^23,12, Ground E 0 35 403.83 l 214'

25,12, *-24.13, Ground A 0 24 570.46 .1 214'

25,12, ^24,13, Ground E 0 24 571.27 214'

26,12. *-25.13. Ground A 0 37 361.64

•} 214'

26.12, ^25,13, Ground E 0 37 362.45 I 214'

26.13. ^25,14, Ground A 0 13 759.98 I 214'

26,13, ^25,14. Ground E 0 13 760.70 .1 214'

27,15. ^26,14, Ground A 0 26 533.12 214'

27.15. ^26.14. Ground E 0 26 533.80 ;} 214'

28.13. ^27,14, Ground A 0 39 320.40 I 214'

28,13, <-27,14, Ground E 0 39 321.14 I 214'

28,14, ^27,15, Ground E 0 15 725.83 .1 214'

28,14, «—27.15. Ground A 0 15 725.98 214'

28.14. «-27.15. Ground E 0 15 726.58 ;} 214'

29.14. ^28.15. Ground E 0 28 496.04 I 214'

29,14, ^28,15, Ground A 0 28 496.19 214'

29,14, <-28.15. Ground E 0 28 496.98 214'

30,14, ^29,15, Ground A 0 41 279.30 214'

30.14. ^29,15, Ground E 0 41 279.97 ! .1 214'

30.15, ^29.16. Ground E 0 17 692.15 I .1 214'

1 i 30,15, ^29,16, Ground A 0 17 692.55 1 .1 214'

1. In the labeling of transitions, the K+i subscript has been omitted whenever the asymmetry splitting nf the rotational levels is Jess than .1 MHz.

210
1,2-Epoxy propane Spi-ctral Line Tal)le

Isotopic Species Id. Rotational Int Rol or Hyperfine Acc. Ref. Nn1> o. Quantum Nos. State IT' r c

^\ r MHz ±MHz

C'2H3C'^HO"*C'^H2 761 30,15, •^29,16, Ground E 0 17 692.97 .1 214'

31,15, ^30,16, Ground 30 459.2 .1 214'

32,16, ^31,17, Ground E 0 19 658.93 .1 214'

32,16, ^31,17, Ground A 0 19 659.50 .1 214'

32,16, <—31,17, Ground E 0 19 659.80 .1 214'

33,16, <—32,17, Ground E 0 32 422..30 .1 214'

33,16, *—32,17, Ground A 0 32 422.83 .1 214'

33,16. ^32.17. Ground E 0

o o /loo c\r\ 62 423.09 .1 214'

34,17, ^33,18, Ground E 0 21 625.78 .1 214'

34,17, «—33.18, Ground A 0 21 626.39 .1 214'

35,17, <—34.18, Ground E 0 34 385.90 .1 214'

35,17, <—34,18, Ground A 0 34 386.62 .1 214'

36,18, ^35,19, Ground E 0 23 593.09 .1 214'

36,18, ^35,19. Ground 1'L 0

oo coo 26 593.50 .1 Ol A 1 211

36,18, <—35.19. Ground A 0

oo Cf\A AIT 26 594.05 .1 Ol /*! 214

37,18, <—36,19, Ground E 0 36 348.78 .1 214'

37,18, <—36,19, Ground A 0 36 349.51 .1 214'

38,19, ^37,20, Ground E 0 25 560.73 .1 214'

38,19. <-37.20, Ground A 0 25 561.43 .1 214'

39,19, ^38,20, Ground E 0 38 312.52 .1 214'

39,19, ^38,20, Ground E 0 38 313.08 .1 214'

39,19, ^38,20, Ground A 0 38 313.23 .1 214'

40,20, ^39,21, Ground E 0 27 528.39 .1 214'

40,20, ^39,21, Ground E 0 27 528.84 1 214'

40,20, •^39,21, Ground A 0 27 529.07 •1 214'

41,20, <—40,21. Ground E 0 40 275.31 .1 214'

41,20, <—40.21. Ground A 0 40 276.05 .1 214'

42,21, ^41.22. Ground E 0 29 496.35 .1 214'

42,21, ^1.22. Ground h 0

or* Af\^ £Lf\ 29 496.60 .1 214'

42,21, <—41.22, Ground A 0 29 497.04 •1 214'

44,22. ^43,23, Ground E 0 31 464.36 .1 214'

44,22. ^3,23, Ground A 0 31 464.96 .1 214'

46,23, *-45,24, Ground E 01 33 432.64 .1 214'

46,23, ^5,24, Ground A 0

O O /I O 1 oo 33 433.28 •1 214'

48,24, ^7.25. Ground E 0

or" A f\f\ f\ A 35 400.94 •1 214'

48,24. ^7.25. Ground A 0 35 401.45 .1 214' Not Reported Ground 9 797.13 .1 214

Not Reported Ground 9 798.95 .1 214 Not Reported Ground 9 799.75 •1 214 Not Reported Ground 10 786.85 • 1 214

Not Reported Ground 10 816.43 .1 214 Not Reported Ground 10 939.88 •1 214 Not Reported Ground 11 087.72 .1 214 Not Reported Ground 11 466.80 .1 214 Not Reported Ground 12 596.59 1 .1 214

Not Reported 1 _T"j^i 1 Ti ri \Ji. 13 273.35 1 214 Not Reported Ground 13 279.04 1 1 1 214

Not Reported Ground 14 053.63 i 1 1 214 Not Reported Ground 1 1 1 14 739.48 ! 1 1 214 Not Reported Ground 1 1 14 756.47 ! • 1 1 214

1. See footnote preceding page.

211
1,2-Epoxy propane Spectral Line Table

Isotopic Species Id. Rotational 1 Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n 1 F' F,

1 F MHz ±MHz

C'2H;,C'^HO"'C'2*H2 761 Not Reported 1 Ground 15 731.38 .1 214

Not Reported 1 Ground 15 756.36 .1 214

Not Reported Ground 17 986.82 .1 214

(.mil Tin 1 8 028 1

1

.1 214 Not Reported Ground 18 043.35 .1 214

Not Reported 1 Ground 19 602.38 .1 214 Not Reported 1 Ground 19 660.31 .1 214 Not Reported Ground 20 545.78 .1 214 Not Reported Ground 20 942.26 .1 214 20 953 54 .1 214

Not Reported 1 Ground 21 019.01 .1 214 Not Reported 1 Ground 21 060.27 .1 214 Not Reported Ground 21 346.97 .1 214 Not Rept irted Ground 23 946.91 1 214 % . Not Rep<(rted Ground 23 951.99 .1 214

Not Reported 1 Ground 24 034.84 .1 214 Not Reported 1 Ground 24 678.02 .1 214 Not Reported Ground 25 145.18 .1 214 Ground 25 149.28 .1 214

1l\nt 1 l.» I Rfnurtpn H^7 t ' 1 L C V-i Ground 25 1.59.28 .1 214

Not Reported (iround 25 222.45 .1 214 Not Reported Ground 25 637.07 .1 214 Not Rep<->rted Ground I 214 Not Reported Grt)und I 214 Not Reported I Ground 97 1 97 d.^ I 214

Not Reported 1 Ground 27 138.22 .1 214 Not Reported 1 Ground 27 159.69 .1 214

( .ro 1 1 n H 27 186 05 I 214 Not Reported Ground 27 196.07 .1 214 Not Reported Ground 27 241.74 .1 214

Not Reported Ground 27 432.92 .1 214 Not Reported 1 (iround 28 421.47 .1 214

N<>t Reported round 28 863.35 .1 214

l\nt RptKirtpn Ground 28 955.44 .1 214

1 .rci 1 1 n H 28 975 36 .1 214

Not Reported 1 Ground 29 069.38 .1 214

Not Reported 1 Ground 29 123.46 .1 214

Not Reported C^round 29 213.55 .1 214

K.f 1 (.HI I i U 29 370 43 214

Not Reported Ground 29 371.74 .1 214

Not Reported 1 Ground 29 373.24 .1 214 Not Reported 1 Ground 29 499.04 .1 214

li(,H ivtrpoi ItrO I ( f U 1 lU 29 604 65 214

( .ri'i 1 1 n ri 29 684.32 .1 214

111.11 IVCIJ'JI ICV-i ( .roil n

H

30 434.95 .1 214

Not Reported 1 Ground 30 438.57 .1 214

Not Reported 1 Ground 30 835.45 .1 214 Not Reported 1 Ground 31 025.99 .1 214 Not Reported Ground 31 026.88 .1 214 Not Reported Ground 1 31 031.88 .1 214

212
1,2-Epoxypiopane Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vil). State Int. Rolor

State n iypeF'

rfine

F, F

Frequency

MHz

Ace. Kef. ±MHz 1

1

C'2H,,C'2*HO"'C'%H2 761 Not R t\nrt f*f\ Ground 31 0.34.24

1 .1 1 214

Not Ground 31 167.79 .1 1 214 Not Re|»trted Ground 31 168.63 .1 ! 214 Not Reported Ground 31 299.81 .1 i 214 Not Reported Ground 31 .300.41 .1 ' 214

Not Rep<)rted (Ground 31 465.89 .1 j 214 Not Rep< trted (iround 32 332.64 .1 1 214 Not Reported (Ground 32 847.29 .1 j 214 Not Reported Ground 32 848.94 .1 214 Not Reported Ground 32 948.69 .1 : 214

i Not Reported Ground 32 974.99 .1 1 214

Not Re port ed Ground 33 141.61 .1 ' 214 Not Reported Ground 33 216.01 .1 i 214 Not Reported Ground 34 070.35 .1 214 Not Reported Ground 34 187.18 .1 ! 214

! Not Reported Ground 34 200.10 .1 j 214 Not Reported Ground 34 262.44 .1 j 214 Not Reported Ground 34 306.81 .1 1 214 Not Reported Ground .34 310.92 .1 214 Reported Ground 34 572.69 .1 1 214

1 Not Keported Ground 34 722.92 .1 1 214

INOl Reported Ground 35 571.32 .1 j 214 Not Reported Ground 35 776.82 .1 214 Not Reported Ground 35 840.37 .1 t 214

INOt Reported Ground 36 211..58 .1 1 214

1 Not Reported Ground 36 831.82 .1 214 Not H <^ f"Kirt f^H Ground 37 610.25 .1 1 214 Not Reported Ground 37 617.40 .1 214 Not Reported Ground 37 658.65 .1 214 Not Reported Ground 37 660.53 .1 214

i Not Reported Ground 37 698.01 .1 1 214 Not Reported Ground 37 769.29 .1 214 Not Reported Ground 37 782.96 .1 1 214 Not Reported Ground 37 791.71 .1 1 214 Not Reported Ground 37 799.76 .1 i 214

1 Not Reported Ground 37 841.92 .1 1 214 Not Reported Ground 37 870.87 .1 I 214 Not Reported Ground 37 879.45 .1 214 Not Reported Ground 37 953.44 .1 I 214 Not Reported Ground 37 985.33 .1 i 214

! Not Reported Ground 38 762.75 .1 1 214 Not Reported Ground 38 836.98 .1 I 214 Not Reported Ground 38 861.90 .1 ! 214 Not Reported Ground 38 989.23 .1 214 Not Reported Ground 39 000.03 .1 1 214

1

f Not Reported Ground 39 003.23 .1 214

749-587 0-69— 15 213
770 - 1-Chloropropane Molecular Constant Table

n-Propyl Chloride C.HjCl Cs(C3v.C2v.Cs) C3H7CI

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) Dj K A

t-C'^HsC'^H.^C'^H^CP'^ Cs 771 2 379.7 M 2 271.7 M

t-C'^H.C'-H^C'-HXF Cs 772 2 325.8 M 2 222.4 M

g-C'-H-iC'-^HaC'^H^CF"^ c, 773 11 829.22 M 3 322.58 M 2 853.06 M

g-C'^H.C'-H^C'-HjCP c, 774 11 788.12 M 3 249.02 M 2 796.44 M

Id. No. fis Debye /xi, Debye /J,,. Debye eOq V3 Acc. Ireii OJa d aj|, d d d

771 2.05 T 0. X 3250

References: ABC: 365 D.i: D,,k: k:: A:

fji: 393 ' eQq: V: 365 I:

' co:

Add. Ref.: 388

1-Ciiloropropane Spectral Line Table

Isotopic Species Id. Rotationa Vib. State Int. Rotor Hyperfine Frequency Acc. Ret. No. Quantum Nos. State n 1 f; F' F MHz ±MHz

t-C'-H^C'-HX'-HaCP'' 771 4, 1. 3-^ 3. 1. 2 (iround A 0 1 18 820.72 .2 365

4, 1. 4^ 3, 1, 3 (iround A 0 18 389.10 .2 365

5. 1. 4^ 4. 1, 3 1 (iround A 0 23 .525.21 .2 365

5, 1, 5^ 4, 1, 4 (iron nd A 0 22 985.16 .2 365

6, 1. 5^ 5. 1. 4 1 ( iround A 0 28 228.93 .2 365

6. 1. 6^ 5, 1, 5 (Ground A 0 27 580.96 .2 365

t-C'-H;,C'-H.,C'-HXr'' 772 4. 1, 3^ 3. 1. 2 Crrt)und A 0 18 398.68 .2 365

4, 1, 4^ 3, 1. 3 1 (iround A 0 17 985.71 .2 365

5. 1, 4^ 4, 1, 3 1 Ground A 0 22 998.38 .2 365

5, 1. 5^ 4. 1, 4 (iround A 0 22 480.92 .2 365

6, 1, 5^ 5. 1, 4 (Jround A 0 27 596.50 .2 365

6. 1. 6^ 5. 1. 5 (iri)und A 0 26 976.65 .2 365

--C'2H.,C'-H.,C'-^HXF-^ 773 1, 1. 1^ 0. 0. 0 I Griiund A 0 14 682.93 .2 365

2. 1. 2«- 1. 0. 1 (Ground A 0 20 388.94 .2 365

2, 1, 1^ 1. 1. 0 Ground A 0 12 820.80 .2 365

2, 1. 2^ 1. 1. 1 1 (Ground A 0 11 881.80 .2 365

3. 0. 3^ 2. 0. 2 (Ground A 0 18 4.50.95 .2 365

3, 1, 2^ 2, 1, 1 1 (Ground A 0 19 218.84 .2 365

3. 1, 3^ 2. 1, 2 (Ground A 0 17 810.83 .2 365

4, 0. 4^ 3, 0. 3 Ground A 0 24 514.76 .2 365

4, 1, 3^ 3, 1, 2 1 (iround A 0 25 601.63 .2 365

4, 1. 4^ 3. 1, 3 Ground A 0 23 726.51 .2 365

4, 2.

2, 2^ 3. 2'. 1 i Ground A 0 24 874.53 .2 365

4. 3^ 3, 2, 2 Ground A 0 24 687.66 .2 365

4, 2. 2^ 4, 1. 3 (Ground A 0 24 196.71 .2 365

5, 0. 5^ 4, 0. 4 (iround A 0 30 507.94 .2 365

5, 1. 4^ 4. 1. 3 t Ground A 0 31 962.82 .2 365

214
1-Chloropropane Spectral Line I aide

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rotor

State n 1

Hyp<

F'

irfin(

1 F,

1 i F

Frecjuency

MHz

Acc. ±MHz

Ref.

773 5, 1, .5^ 4, 1, 4 Ground A 0 29 62.5.73 .2 365

5. 2, 3^ 4, 2, 2 Ground A 0 31 204.3.5 .2 365 Ground A 0 30 835.52 .2 365

O, Z, O* O, 1, 4 t^round A 0 23 438.25 .2 365

0, Z, 4* 0, 1. 0 t>r(iund A 0 22 739.83 .2 365

7, 2, 5^ 7. 1. 6 (iround A 0 22 198.83 .2 365

8, 1, 7^ 8. 0, 8 Ground A 0 19 801.74 .2 365

<5, Z, 0* o, 1, / L>rouna A 0

O 1 AAO 11 21 908.77 .2 365 Ground A 0 23 101.55 .2 365

/. < y. 1 , o Ground A 0

O 1 AC O fT C 21 953.55 .2 365

10, 1, 9*-10, 0,10 Ground A 0 26 847.33 .2 365

10, 2, 8^10, 1, 9 Ground A 0 22 404.11 .2 365

111 11 A* 1 1 nil 1 . 1 .lU* 1 J , U,l 1 (»round A 0 OA "7 A

.2 365

11 o 1 1 1 1

J 1, z, V* 1 1 , i.iu (around A 0 Z6 ^19.44 .2 365

12, 2,10^12. 1,11 (iround A 0 24 747.74 .2 365

1 O oil 41 1 Q 1 1 O lo, Z,ll< lo, 1,1/ (/round A 0 26 726.06 .2 365

1/1 9 1 9< 1 A 1 1 Q I'*, z,14* I'*, l,lo Ground A 0

OA OTC OO 29 2/5. zo .2 365

It: O 1 9<_1 C 1 1 A C^round A 0

QO Q A^ A C OZ OV4.4-0 o

.2 000

774 2, 1, 10 1 (.jrouncl A 0 90 Ml A A o

.Z OO.J

O, O, VJ, ^ Ground A 0 1LO« HA/^ yjOO.DD o

.Z .300 3 1 2<— 2 11 Crround A 0 lo OU4-.1U o

.Z OOO

3, 1, 3-^ 2, 1, 2 Ground A 0 17 466.78 .2 365

4, 0, 4-^ 3, 0, 3 Ground A 0 24 007.67 2 365

4, 1. 3«— 3, 1, 2 Oround A 0 25 050.53 .2 365

4, 1. 4*— 3. 1, 3 Ground A 0

O "J O /I O A 1 16 Z'iZAi .2 365

4, 2, 2*— 3, 2, 1 Ground A 0

O /I O A A /in 24 344.40 .2 365

4, 2, 3^ 3, 2, 2 Ground A 0 24 168.19 .2 365

4, 2, 2^ 4, 1, 3 Ground A 0 24 327.14 .2 365

5, 0, 5«— 4, 0, 4 Ground A 0

OA OOO "70 29 883.72 •2 365

5, 1, 4^^ 4, 1, 3 Ground A 0 31 275.86 •2 365

5, 1, 5<— 4, 1, 4 Ground A 0

Of^ AOO OO 29 022.88 •2 365

5, 2, 3^ 4, 2, 2 Ground A 0 30 530.25 .2 365

5, 2, 4^ 4, 2, 3 Ground A 0 .30 187.94 .2 365

5, 2, 3^^ 5, 1, 4 Ground A 0

O O CO! AO 23 581.92 .2 365

6, 2, 4'«— 6, 1, .5 Ground A 0

OO OOO AO 22 883.98 .2 365

7, 2, S'^ 7. 1, 6 Ground A 0 22 326.14 .2 365

8. 1, 7^ 8. 0, 8 Ground A 0 19 352.82 .2 365

8, 2, 6«- 8. 1, 7 Ground A 0 21 996.93 .2 365

9, 1, 8«— 9, 0, 9 Ground A 0

O O C "X A AO 22 514.93 .2 365

9, 2, 7*— 9, 1, a Ground A 0

O 1 00*7 A 0

.z oOo

10, 1, 9<—10, 0,10 Ground A 0 OA lie c\o ZD 110.1)0 o

.Z OOO

10. 2. 8^10, 1, 9 Ground A 0 22 339.23 .2 365

11, 1,10^11, 0,11 Ground A 0 30 098.56 .2 365

11, 2, 9^11, 1,10 Ground A 0 23 137.29 .2 365

12, 2,10^12, 1,11 Ground A 0 24 420.34 .2 365

14, 2,12^14, 1,13 Ground A 0 28 578.27 .2 365

1.5. 2.13^1.5, 1.14 (iron nd A 0 31 482.71 .2 365

215
780- Propane Molecular Constant Table Dimethylmelhane

CjHg C2v(C3v.C2v.C3v) CH3CH2CH3

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) Dj K A

Cjv 781 29 207.36 M « 446 07 M 7 458.98 M <.05

Cs 782 29 092.05 M 8 228.77 M 7 281.73 M

C^v 783 28 660.50 M 8 447.11 M 7 423.19 M

c, 784 25 829.94 M 8 358.76 M 7 283.00 M

s-C'^DH^C'^HaC'^Hj c. 785 29 017.79 M 7 838.32 M 6 971.96 M

a-CH^DC'^H^C'^H;, c, 786 26 828.97 M 8 123.10 M 7 185.14 M

Id. No. /Xa Debye Debye fji,. Debye eQq v.. Acc. I red COa d (U|, d 0)^. d to,, d

781 0. X 0.083 M 0. X 3400

Reference ABC: 296

/x: 296

s:

e Oq:

Djk:

V

296

113

k:

I:

A:

w:' Add. Ref.: 146 .-

Torsional frequency = 250 cm '. Ref: 296.

216
Propane .Spectral Line I'able

Isotopic Species Id. No.Rotational Quantum Nos.Vib. State Int. Rotor

State n ^yptF'

rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

pl20 pi2U rM2ri 781 1, 1, 1^ 0, 0, 0 .06 296

1, 1, 0-^ 1, 0, 1 Ground 21 748.37 !03 296

2, 1, 1-^ 2, 0, 2 Ground 22 769.74 .03 296

3, 1, 2^ 3, 0, 3 ( .T"(M 1 n ri V,J 1 1 f u 1 1 Ll .03 296

4, 1, 3«- 4, 0, 4 Ground 26 609.24 .03 296

5. 1. 4^ .5, 0, .5 Ground 29 592..51 .03 296

f.0. 1 0^ 0. Au. A0 Ground 33 414.72 .03 296

(-130 ri2ij ri2H 782 1, 1, 1^ 0. 0. 0 (V 7

• 1rn(_f 1U1 n1 lUH .12 296

2, 1, 1^ 2, 0, 2 Ground 22 788.80 .06 296

3, 1, 2*- 3, 0. 3 .06 296

4. 1, 3^ 4, 0, 4 Ground 26 4,56.74 !06 296

"J-. I

nU, cD Ground 29 298..58 .06 296

0, A 0 Ground 32 9.33..58 .06 296

783 1, 1, 1^ 0. 0. 0 ( I ret 1 1 n H 36 083 69 .12 296

2, 1, 1^ 2, 0. 2 Ground 22 299.03 .06 296

3, 1, 2^ 3, 0, 3 (V.7. TCi 1 LI 1li1 nIIUM 9^ 961 76 06 296

4, 1, 3^ 4, 0, 4 Ground 26 306.35 :o6 296

i; 11

Au. c0 Ground 29 432.48 .06 296

0, 11

0*^ q< A

0. Au. A Ground 33 446.47 .06 296

C'^H^C'-HDC'^Ha 784 1. 1. 1^ 0, 0, 0 Ground 33 112.93 12 296

2. 1, 1^ 2, 0, 2 Ground 19 670.78 .06 296

3. 1, 2^ 3, 0, 3 (\J-w-rrH 1 Ll1 n1 1 Hu 21 44S 48 .06 296

4, 1, 3^ 4, 0, 4 Ground 23 971.76 .06 296

q^- 11

A c

.J Ground 27 370.09 .06 296

f.0, Ii

Au. 0 Ground 31 7.59.70 .06 296

s-C'^DHjC'^HaC'^Ha 785 1, 1, 1^ 0. 0, 0 1Kj, r*I l-l1 1U1 n1 1 HL1 35 989 76 12 296

2, 1, 1^ 2. 0, 2 Ground 22 938.16 .06 296

3, 1, 2«- 3, 0, 3 1 -mTl~\ I 1 Tl H 94 H94 96 .06 296

4, 1, 3*- 4, 0, 4 Ground 26 262.62 !06 296

r

>>» 1, A c0 Ground 28 822.23 .06 296

6, 1, .5^ 6, 0. 6 Ground 32 083.91 .06 296

a.ri2H r)(-i2u (--1214 786 1, 1. 1^ 0, 0. 0 vj'rounu 34, 014 10 1 9 296

2, 1, 1^ 2, 0, 2 Ground 20 616.12 .06 296

3, 1, 2^ 3, 0, 3 Ground 22 137.98 .06 296

4, 1, 3^ 4. 0. 4 Ground 24 283.11 .06 296

5, 1, 4^ 5, 0, 5 Ground 27 141.90 .06 296

6, 1. .5^ 6. 0. 6 Ground 30 811.32 .06 296

217
790 - Trimethylarsine Molecular Constant Table C3H9AS C3v(C3v.C3v,C3v) (CHaj^As

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) D., K A

C3V 791 4 724.98 M 4 724.98 M .003

Id. No. /.(a Debye ;u,„ Debye fi^. Debye eQq V3 Acc. cjh d ojj. d toj, d

791 0. X 0. X 0.86 M -203.2 2000 500

References: ABC: 2.54 D.,: 254 Djk: k: A:

Ai: 254 eQq: 2.54 V: 254 I: oj:

Rotational constant for the excited state: By = 4748.9 MHz. Ref: 254.

imethylarsine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hypeifine Frequency Acc. Ref. No. Quantum Nos. Sta.tc n f; F' F MHz ±MHz

(C'-^H3),As'-^' 791 2, 0^ 1, 0 Ground 5/2 3/2 18 904.22 .05 254

2. 0<— 1, 0 Ground 7/2 5/2 18 904.22 .05 254

2, 1*- 1. 1 Ground 5/2 3/2 18 861.48 .05 254

2. 1^ 1. 1 Ground 5/2 5/2 18 886.8 254

2, 1^ 1, 1 Ground 7/2 5/2 18 912.15 .05 254

2, 1^ 1, 1 Ground 3/2 1/2 18 925.3 254

3. 0^ 2. 0 Ground 7/2 7/2 28 302. 254

3. 0^ 2. 0 Ground 5/2 3/2 28 339.44 .05 254

3, 0^ 2, 0 Ground 3/2 1/2 28 339.44 .05 254

3, 0^ 2, 0 Ground 7/2 5/2 28 351.95 .05 254

3. 0^ 2. 0 Ground 9/2 7/2 28 351.95 .05 254

3, 0^ 2. 0 Ground 3/2 3/2 28 390.13 .05 254

3, 1^ 2. 1 Ground 7/2 7/2 28 316.95 .05 254

3. 1^ 2, 1 Ground 7/2 5/2 28 342.11 .05 254

3, 1^ 2. 1 Ground 5/2 3/2 28 342.11 .05 254

3. 1^ 2, 1 Ground 3/2 1/2 28 354.93 .05 254

3, 1^ 2, 1 Ground 9/2 7/2 28 354.93 .05 254

3, 1^ 2, 1 Ground 5/2 5/2 28 360.04 .05 254

3, 1^ 2, 1 Ground 3/2 3/2 28 380.00 .05 254

3, 2^ 2, 2 Ground 5/2 5/2 28 313.36 .05 254

3, 2^ 2, 2 Ground 7/2 5/2 28 313.36 .05 254

3, 2^ 2, 2 Ground 3/2 3/2 28 349.62 .05 254

3, 2^ 2, 2 Ground 5/2 3/2 28 349.62 .05 254

3, 2^ 2, 2 Ground 7/2 7/2 28 364.13 .05 254

3. 2<- 2, 2 Ground 9/2 7/2 28 364.13 .05 254

3. 2^ 2. 2 Ground 1/2 1/2 28 400.43 .05 254

3. 2^ 2. 2 Ground 3/2

1

1/2 28 400.43 .05 254

218
800 - Trifluoroborane-trimethylamine Molec ular (JonstanI Table

C:jH9BF;jN C,-iv(C3v.C3v,C,iv>C:)v, C3v,C,v) F,B-N(CH.,),

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) D,, D,,K K A

F:',''B"-N"(C'-H;,):, C.,v 801 1 7.50. ^M

Id. No. /Xa Debye ;u,|, Debye /X,. Debye eQq V Acc. I rod Wa d Wl, d 0),. d d

801 5. 'M 0. X 0. X

1. Since it is not stated whether this molecule is a prolate or oblate top, the I(jtal dipole moment may be entered under either or /x,.. For convenience, it has been entered here

as

2, Measurements were made on a mixture of isotopes. B" (81%) and B'" (19%). Either B= C (prolate) or A= B (oblate).

References: ABC: 308 D.,: D.,k: k: A:

ix: 308 eQq: V: I: w:

Trifluoroborane-trimethylamine

Spectra! Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n f; ^ypeF'

rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

FJ^B^-N^lC'^H,,):, 801 2, ^ 1. 3. ^ 2, 9, ^ 8, 10. ^ 9,

6 990. 10 480. 31 500. 35 000.

308' 308' 308'

308'

1. The values given are average frequencies of broad unresolved lines of varying widths.

2119
810 - Triinetliylbromosilane Molecular Constant Table

Trimelliylbroniosilicane

C,,H„BrSi C,v(C,,.C..,v.C3v) (CH^j^SiBr

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) D., K A

(C'2H3)3Si'^«BrTM

(C'^H^j^Si^^Br"' r^3V

811 8121 461.95 M

1 449.13 M

1 461.95 .M

1 449.13 M

Id. No. Debye jai, Debye |x^. Debye eQq V Acc. I|ell (Ua d

j

OJii d

j

CtJ^. d oj,, d

811 2..36 L 0. X 0. X

References: ABC: 149 D.,: D,,k: k: A:

ix: 372 eQq: V: I: tu: Add. Ref.: 104

thylbromosilane c . i i ui bpectral Line 1 able

Isotopic bpecies T JId. Rotational Vib. btate Int. Kotor Hyperfine r requency Acc. Ref.

INO. Quantum Nos. State n Fi

IT' r

1r IVlnz ±MHz

(C'^Hjl^Si-^BrTM 811 10. ^ 9, Ground 29 238.7 .3 149

11. ^10, 32 112.2 .4 149

11. ^10, 32 124.6 .4 149

11. ^10, 32 139.0 .4 149

11. ^10. Ground 32 162.0 .3 149

11. *-10. 32 194.3 .4 149

11. «-io. 32 202.2 .4 149

12. ^11, 35 032.9 .4 149

12, ^11, 35 045.8 .4 149

12, ^11, 35 061.2 .4 149

12, ^11, Ground 35 087.4 .3 149

12, ^11. 35 121.9 .4 149

13, ^12, Ground 38 010.8 .3 149

(C'2H3)3Si-''Br»' 812 10. ^ 9, Ground 28 982.5 .3 149

11. ^10. 31 831.6 .4 149

11. ^10, 31 842.1 .4 149

11. ^10, 31 856.2 .4 149

11, «-10, Ground 31 880.5 .3 149

11. ^10, 31 913.2 .4 149

11. ^10, 31 920.2 .4 149

12, ^11, 34 725.2 .4 149

12, ^11, 34 736.9 -.4 149

12, ^11, 34 753.2 .4 149

12, ^11, Ground 34 779.1 .3 149

12. ^11, 34 814.1 .4 149

12, ^11, , 34 822.4 .4 149

13, ^12, Ground 37 675.3 .4 149

14, ^13, Ground 40 575.5 .3 149

220
820 - Trimethylchlorosiiane

Trimethylf hlorosilicane Molecular Constant Tahic

C3H9ClSi C3v(C;jv,C3v,C3v) (CH;j);jSi

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D., D.,K K A

(C'2H,,)3Si2«CF'^ r 821 2 197.441 M 2 197.441 M <.010

(C'2H,,)3Si-«cr" C3V 822 2 147.883 M 2 147.883 M

Id. No. /u-a Debye fjLi, Debye /X;. Debye eQc, V Acc. OJ., d ai|, d CO,, d oj,, d

821 2.02 L 0. X 0. X

References: ABC: 79, 303 Dj: D.,k: 79 k: A:

ju,: 167 eQq: V: I: w:

Add. Refs.: 80, 85

Trimethylchlorosiiane Spectral Line Table

Isotopic Species Id. No.Rotational Quantum Nos.Vib. State Int. Rotor

State n

1 iype

F'

rfine

F, F

Frequency

MHz

1 Acc. [ ±MHz 1

Ref.

(C'^H3)3Si28CF 821 5. 4, Ground 21 974.00 .3 1 79

7. 6, Ground 30 762.89 2 79

8, 7, Excited 35 107.16 .3 1 79

8, 7, Excited 35 133.71 .3 1 79

8, 7, Ground 35 157.01 .3 i 79

8, 7, Excited 35 198.47 .3 1 79

8, 7, Excited 35 219.92 .3 1 79

9, 8, Excited 39 524.50 .3 79

9, 8, Excited 39 550.89 .3 1 79

9, 8, Excited 39 597.95 .3 t 79

9, 8, Excited 39 622.21 .3 1 79

(C'^H3 822 8, 7, Excited 34 317.44 .5

1 79

8. 7. Excited 34 343.20 .5 1 79

8. 7, Ground 34 366.12 .5 i 79

8. 7, Excited 34 406.36 .5 79

8. 7, Excited 34 426.86 .5 79

9. 8. Excited 38 607.26 .5 79

9. 8, Excited 38 636.09 5 79

9. 8, Excited 38 662.28 .5 1 79

9, 8, Excited 38 707.44 .5 79

9. 8. Excited j 38 731.09 .5 79

221
830- Trimethylfluorosilane Molecular Constant Table

Trimethylfluorosilicane

CaH^FSi C3v(C3v.C3v.C3v) (CH^I^SiF

Isotopic Species Pt. Gp.

Id. No... A (MHz) B(MHz) C(MHz) D,, K A

(C'2H3)3Si2«F'*' c 831 3 411.00 M 3 411.00 M

I

References: ABC: 88 Dj: Djk: k: A:

At: eQq: V: I: w: Add. Ret.: 219

Trimethylfluorosilane

Sp^^.^^^, ^ine Table

Isotopic Species Id. No.

Rotational Quantum Nos.

Vib. State Int. Rotor

State n HypeF'

rfine FFrequency

MHz

Acc. ±MHzRef.

(C'-H3)3Si2«F'>' 831 4. ^ 3, Ground 27 287.8 .3 88

5. ^ 4. Excited 34 088.6 .5 88

5, ^ 4, Excited 34 094.9 .5 88

5, ^ 4, Ground 34 109.8 .3 88

5, ^ 4. Excited 34 133.4 .3 88

5, ^ 4. Excited 34 148. 88

5. <- 4. Excited 34 171. 88

5. *- 4. Excited 34 219.0 .5 88

6, ^ 5, Excited 40 906.3 .3 88

6. ^ 5. Excited 40 913.0 .5 88

6, -.5. Ground 40 931.6 .3 88

6, ^ 5, Excited 40 959.4 .5 88

6. ^ 5, Excited 40 977. 88

6. -.5. Excited 41 008. 88

6. ^ 5, Excited 41 062.5 .5 88

222

I
840 - Trimethyliodosilane Molecular Constant 'I'alilc Trimethyliodosilicane

CsHjSi c,,,(C;,„C3v,c,v) (cn,),sii

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D., D,K K A

(C'2H3).,Si2«I'" 841 1 096.42 M 1 096.42 M

Id. No. fjL^ Debye (U-h Debye fjL,. Debye eQq V Acc. a)„ d oju d d d

841 2.46 L 0. X 0. X

References: ABC: 152 Dj: D,,,: k: A:

/a: 167 eQq: V: I: w: Add. Refs.: 104. 167

Trimethyliod.Ksilane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

(C'-H;j)3Si2«I'" 841 15, ^14, Excited 32 834.2 .4 152

15, ^14, Excited 32 847.4 .4 1.52 15, ^14, Excited 32 854.4 .4 152

15, ^14, Excited 32 874.3 .4 152

15, -^14, Ground 32 892.9 .3 152

15, ^14, Excited 32 917.2 .4 152

15, ^14, Excited 32 940.2 .4 152

15, ^14, Excited 32 948.9 .4 152

16, ^15, Excited 35 038.3 .4 152

16, <-15, Excited 35 044.9 .4 152

16. ^15, Excited 35 064.7 .4 152

16, ^15, Ground 35 085.2 .3 152

16, ^15, Excited 35 111.0 .4 152

16. ^15, Excited 35 136.4 .4 1.52 16. ^15, Excited 35 145.9 .4 152

17, ^16, Excited 37 210.6 .4 152

17, ^16, Excited 37 227.4 .4 152

17, ^16, Excited 37 234.7 .4 152

17, ^16. Excited 37 256.4 .4 152

17, ^16, Ground 37 278.0 .3 152

17, ^16, Excited 37 305.3 .4 152

17. ^16. Excited 37 331.7 .4 152

17. ^16. Excited 37 342.7 .4 1.52

223
850 - Tiimethylamine Molecular Constant Table C3H,N C,,,(C.,v,C3v.C3v) (CH,),N

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) D.J D.IK K A

(C''^H3)..,N'^ 851 852

8 720.86 M

8 719..3 M

8 720.86 M

8 445.5 M 5 200, M

.005 .000

Id. No. /Xa Debye /X|, Debye yu,;. Debye eQq v.., Acc. Wa d oji, d oj;. d C(j,i d

851 0. X 0. X 0.612 M -5.47 4400

References: ABC: 225 D,,: 225 Djk: 225 k: A:

Ai: 225 eQq: 225 V: 225 I: (o: Add. Refs.: 242. 282

Torsional frequencies: A2 = 263 cm"'. E=290 cm"'. Ref: 225. The A2 mode is forbidden in both the infrared and Raman spectra, but

a Raman hne at 274 cm"' may perhaps be identified with the E torsion.

Trimethylamine Spectral Line Table

Isotopic Species Id. Rotatifnial Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F' F F MHz ±MHz

(C'2H;,);jN'^ 851 1. ^0. ( 'round 17 375.0 .3 225'

1. ^0, ( rround 17 380.8 .3 225'

1. ^0, (Ground 17 .387.9 .3 225'

1. ^ 0. Ground A 2 17 401. 1. 225'

1. 0. (iround E 1 17 407.45 .10

1, 0, Ground A 1 17 421.41 .10 225 '

1, 0 0, 0 Ground 1 1 17 440.33 225

1" 0' Ground A 0 17 441.71 .03 225'

1, 0 0, 0 Ground 2 1 17 441.98 225

1, 0 0! 0 Ground 0 1 17 444.43 225

1, 0, Excited 17 477. 1. 225 '

2, 1. Ground 34 749.0 .3 225 '

2, 1, Ground 34 760.9 .3 225 '

2, 1. Ground E 1 34 774.0 .3 225'

2. 1, Ciround 34 775.7 .3 225 '

2, 1, Ground A 2 34 800.0 .3 225'

2. 1, Ground E 1 34 814.84 .05 225 '

2, 1, Ground A 1 34 842.61 .05 225 '

2, 1, Ground E 1 34 855.4 .3 225 '

2, 0 1, 0 Ground 2 2 34 881.68 225

2, 0 1, 0 Ground 1 0 34 881.94 225

2, 0 1, 0 (iround A 0 34 883.31 .03 225

2. 0 1. 0 Ground 3 2 34 883.42 225

2, 0 1, 0 (iround 1 1 34 886.04 225

2, 1. Excited 34 955.6 .3 225 '

2. 1 1. 1 Ground 2 1 34 881.94 225

2, 1 1. 1 (Ground 2 2 34 882.79 225

2, 1 1, 1 Ground A 0 34 883.32 .03 225

2. 1 1. r Ground 3 2 34 883.65 225

2. 1 1, 1 Ground 1 0 34 885.38 225

(C'^H..,)2C'-'H,.,N'^ 852 1, 1. 0^ 0. 0. 0 Ground 17 165.0 .5 225

2. 1. 1^ 1, 0, 1 Ground 34 055.7 .5 225

2. 2. 0^ 1. 1. 0 Ground 34 346.2 .2 225

2. 2. 1^ 1. 1. 1 ( iround 34 603.5 .5 225

1. \ possible bul not certain identification of some of the torsional satellites is made in Table II of Lide's paper. Also a tentative identification of two n<in-torsionai excited vibrational states is made in the same table. 224
860-Trinietliylphosphine Molecular (Jouslanl Tahli- C^H^P C.,v(C,v,C,v.C:,v) (CH.,),,P

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D., D,K K A

Cs

861 8625 816.24 M

.S 809.07 M

5 816.24 M

S 640.73 M 3 669. M

.003

Id. No. Ma Debye fjLi, Debye fi,. Debye eQq V:, Ace. d Wi, d O);. d tu,j d

861 0. X 0. X 1.192 M 2600 316' 1 253' 2

1. The vibrational frequencies for the i<iw lying S;, and 6,. vibrational modes by microwave analysis are in Lide and Mann's article on isobutane, and it is shown that the previous IR or Raman identifications for these modes should be reversed.

References: ABC: 226 Dj: 226 Djk: k: A:

IJl: 226 eQq: V: 226 I: w: 226

Rotational Constants for excited states (By): t^: 5809.91 MHz; t^: 5806.49 MHz; Sa: 5823.94 MHz; S^: 5817.80. Torsional frequencies:

Ta: 197 ±20 cm-'; t^: 223 ±20 cm"'. Ref: 226.

Trimelhylphosphine Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine - Frequency Acc. Ref. No. Quantum Nos. State n F,' F' F MHz ±MHz

(C'^H3)3P^' 861 2. ^ 1, Ground E 1 23 225.87 226

2, ^ 1, Ground A 1 23 239.54 226

2, ^ 1, Ground 23 264.86 .03 226

2. <- 1. 23 271.20 226

2, ^ 1, 1 23 295.71 226

2. 1<- 1. 1 Excited E 1 23 262.8 226'

2. 1^ 1. 1 Excited E 1 23 188.65 .03 226'

2, 1^ 1. 1 Excited E 1 23 225.87 .03 226'

3, ^ 2, Ground E 1 34 839. 226

3, ^ 2, Ground A 1 34 859.10 226

3, <- 2, Ground 34 897.11 .03 226

3, ^ 2, 34 907. 226

3, ^ 2. 1 34 943.46 226

3. 0^ 2, 0 Excited E 1 34 839.96 .03 226'

3. 1^ 2. 1 Excited E 1 34 894.2 226'

3, 1^ 2, 1 Excited E 1 34 782.7 226'

3, 1*- 2, 1 Excited E 1 34 839.05 .03 226'

3, 2^ 2, 2 Excited E 1 34 837.25 .03 226'

862 3, 1, 2^ 2. 0. 2 Ground 34 308.4 226

3, 2. 1^ 2. 1, 1 Ground 34 103.5 226

3. 2. 2^ 2. 1, 2 Ground 34 349.3 226

3. 3. 0^ 2. 2. 0 Ground 34 390.5 226

3. 3. 1^ 2. 2. 1 Ground 34 608.1 226

1. /-doubling occurs here in the singly excited torsional state. A simple treatment of this is given in the reference by Lide and Mann.

225
870 - Trimethylsilane Molecular Constant Table

Trimethylsilicane

C;jH,oSi C3v(C-jv.C,jv-C3v) (CH3)3SiH

Isotopic Species rl. Gp.

la. No. A (MHz) B(MHz) C(MHz) UjK K A

(C'-H3)3Si'*'H 871 5 345.15 M 5 345.15 M 3 166. M

(C'2H3)3Si-«D 872 5 1.59.71 M 5 159.71 M

(C'^H3)3Si2^H 873 5 337.84 M 5 337.84 M

(C'.2H3)3Si^^D C3V 874 5 153.87 M 5 153.87 M

(C'2H3)3Si-TMH C,3v 875 5 330.84 M 5 330.84 M

(C'-^H3)3SPD C3V 876 5 148.13 M 5 148.13 M

C'-=H3(C'2H3)2Si''H Cs 877 5 342.14 M 5 172.63 M 3 105. M

(C'3H3)2C'^H3Si''H Cs 878 5 2.54.02 M 5 086.00 M 3 135. M

(C'2D3)2C'2H3Si"H C,s 879 4 724.61 M 4 216.49 M 2 656. M

s-C'-H2D(C'-H3)2bi"D Cs 881 5 070.23 M 4 905.69 M 3 101. M

c, 882 5 157.86 M 4 859.67 M 3 050. M

s-C'^D,H(C'-H3)2Si''D 883 5 076.72 M 4 662.40 M 2 945. M - a-C!-D,H(C'-H3)2Si"D c, 884 5 052.74 M 4 650.07 M 2 992. M

Id. No. Debye fji\, Debye jj.,. Debye eQq V3 Acc. I red W;, d Oil, d w^. d aj,| d

871 0. X 0. X 0.525 M 1830 400

References: ABC: 307 ' Dj

307 eQq

Add. Ref.: 287

For species 879. the calculated torsional frequencies are: 0J2= 104 cm"', and 0^3= 141 cm"', and C03= 141 cm '. Ref: 307.

D,

V: 307

k:

I:

A:

226
Trimethylsilane Spectral Line Table

Isotopic Species Id. Rotaliona! Vib. State Int. Kolor Hyperline i''rc(|uciuy Acc. Kef. No. Quantum Nos. State n F' F' F F MHz ±iVIHz

(C'^H;,)3Si'^»H 871 1. ^ 0. Ground 10 690.34 .10 307

2, *- 1. Ground 21 380..S8 .10 307

3, ^ 2, Excited 32 040.2 .2 134

3, 2, Excited 32 043.3 .3 1.34 3, ^ 2. (^round 32 070.2 .1 134

3, 2. Excited .32 101.2 .1 1.34 3. 2, Excited 32 1.59.9 .2 1,34 3, ^ 2. Excited 32 248.4 .2 1.34

(C'2H3)3Si^*'D 872 1. ^ 0, Ground 10 319.4 .10 307

2. - <- 1, Ground 20 638.87 .10 307

3, 2, Excited 30 928..5 .1 1.34 3, ^ 2. Excited 30 933.4 .2 134

3, 2. Ground 30 957.0 .1 134

3. ^ 2, Excited 30 982.0 .2 134

3, 2, Excited 31 04/.

.z 1.34

(C'2H3),,Si2"H 873 2, *- 1. Ground 21 351.36 .20 307

3, 2, Ground 62 Ozo.l .2 134

(C>2H3)3Si2''D 874 2, ^ 1, Ground 20 615.49 .20 307

3, 2. (Ground 30 916.4 .1

1 Q /I

(C'^H3)3Si-'"H 875 2. ^ 1. Ground 21 323..35 .20 307

3. 2. Ground 31 984.1 .3 134

(C'2H,)iSi3''D 876 2, «- 1, Ground 20 592..50 .20 307

3, ^ 2, Ground 30 875.6 .2 134

C'^H3(C''^H3)2Si''H 877 1. 1. 0^ 0. 0, 0 Ground 10 514.75 .1 307

2. 1, 1^ 1, 0, 1 Ground 20 860.02 .1 307

2, 2, 0^ 1, 1, 0 Ground 21 039.24 .1 307

2, 2, 1— 1, 1, 1 Ground 21 199.01 .1 307

(C''H3)2C'2H3Si"H 878 2, 1. 1^ 1, 0, 1 Ground 20 512.02 .1 307

2, 2, 0^ 1, 1, 0 Ground 20 690.03 .1 307

2, 2, 1^ 1. 1, 1 Ground 20 848.06 .1 307

(C'^D3)2C'^H3^i"H 879 1, 1, 0^ 0. 0, 0 Ground 8 941.09 .1 307

2, 1. 1^ 1. 0, 1 Ground 17 346.60 .2 30/

2, 1. 1^ 1, 0, 1 Ground 17 358.67 .2 307

2, 1. 1^ 1. 0, 1 Ground 17 374.08 .1 307

2. 2. 0^ 1, 1, 0 Ground 17 966.81 .2 307

2. 2, 0^ 1. 1, 0 Ground 17 974.66 .2 307

2, 2, 0-^ 1, 1. 0 Ground 17 987.14 •1 307

2, 2, 1^ 1, 1. 1 Ground 18 372.55 .2 307

2, 2, 1^ 1, 1. 1 Ground 18 378.75 .2 307

2, 2, 1*- 1, 1, 1 Ground 18 390.30 .1 307

s-C'2H2D(C'2H3)2Si''D 881 2. 1, 1*- 1. 0. 1 (iround 19 787.30 .10 307

2, 2, 0-^ 1. 1, 0 (Ground 19 962.62 .10 307

2, 2, 1^ 1, 1. 1 Ground 20 116.38 .10 307

a-C'2H2D(C"2H3),Si"D 882 2. 1, 1-^ 1, 0, 1 Ground 19 736.85 .10 307

2. 2^ 0^ 1, 1, 0 Ground 20 068.81 .10 307

2^ 2^ 1^ \, \, 1 Ground 20 333.25 .10 307

s-C'2D2H(C'2H3)2Si'>D 883 2, 1. 1^ 1, 0. 1 Ground 19 063.92 .10 307

2. 2, 0^ 1. 1, 0 Ground 19 544.30 .10 307

2. 2, 1^ 1. 1. 1 (i round 19 892.55 .10 307

a-C'2D2H(C'2H3)2Si''D 884 2, 1, 1^ 1. 0, 1 Ground 19 002.95 .10 307

2. 2. 0^ 1, 1, 0 Ground 19 470.41 .10 307

2. 2, 1^ 1, 1, 1 Ground 19 808.32 .10 307

227
890- l.l,l-Trifluoro-2-Butyne

Methyllrifluoromethylacetylene Molecular Constant Table

C4H3F:, C,v(C:,v,C3v) CH:,C:CCF,

Isotopic Species Pt.

(;p.

id. No. A (MHz) B{MHz) C(MHz) D., K A

C'-H;,C'2|C'-C'Tf,'* C.,v 891 1 369.70 M 1 369.70 M .001 .998 C'-D,C'^:C'^C'T.i'* C:,v 892 1 229.15 M 1 229.15 M

C.v 893 1 329.84 M 1 329.84 M

C,v 894 1 356.78 M 1 356.78 M

C'^D,C>-'!C'^C'T>'* C:,v 895 1 219.81 M 1 219.81 M

C'2D,C'2|C'-C'-T;'," C.,v 896 1 226.93 M 1 226.93 M

C'-D.HC'-iC'^C'-F'" Cs 897 1 271.85 M 1 271.85 M

I

Id. No. /Xa Debye /u,i, Debye /i.,. Debye eQq V:, Acc. U>-, d OJl, d oj,. d co,i d

891 300

References: ABC: 162 D,: D,,k: 112 k: 162 A:

ix: eQq: V: 350 I: co: Add. Refs.: 65, 247

I

228
UJ-Tri£luoro-2-ButYne_ _ Spectral Line Table

Isotopic Species la.

INo. Rotational Quantum Nos.

ViD. State Int. Kotor

State n

17' ^1

J.Type

I?' r

rfine

r

r requency MHz IV/f If „ Acc.

±lVlnz

Met.

C'2H,,C'-^lC'2C''Fi'* 891 7, 6. Ground 19 176.2 .1 162

7, *~ 6, hixcited 19 214.8 . 1

1 AO lOZ

7, 6. Excited Iv ZoZA 1

. 1 1 AO lOZ

7, ^ 6, Excited 19 291.0 .1 162

7, <- 6, Excited 19 328. 2. 162

8, «— 7, Ground 1 1 AO IDZ

9, *— 8. Ground 24 654.5 .1 162

10, ^ 9. Ground 27 393.6 .1 162

ovz 8, <— 7, Ground 1 0 AAA ly 000.0 1 .1 1 AO

10, *~ 9, (iround ^4 OOZ.O 1 1 AO

11, <—10, (Jround 27 041.8 .1 162

7, 6, (/round C

..J 1lOZAO

8. <— 7, (>round 01 07Q n c.0 1 AO XOZ

9, *— 8, Ground Zo / .U

c 1lOZAO

10. ^ 9, Ground 26 596.5 .5 162

C'2H,,C'''lC'2C>2FJ« 7, 6. Ground 1 Q OQ c: n lo Wo.U C

.0 1lOZAO

8, 7. Ground 01 IfiQ ^ c

.0 1 AO

9. ^ 8. Ground 24 422.5 .5 162

10. <- 9. Ground 27 135.0 .5 162

/"izn i;i • 12/^ 1 2171*) L U3L : L Lone ova 8, «— 7, Ground ty Dio.u c.D 1 AO lOZ

10. <— 9, Ground 24 397.0 .5 162

11. ^10, Ground 26 836.0 2. 162

/~'12T~k 12 • 12/^ I;1T71M L U3C : C C r 3 896 8. ^ 7, Ground ly ooi.u r.D 1 AO lOZ

10. ^ 9. Ground OA C DO 0 r.0 1 AO loz

11, ^10, Ground 26 992.0 .5 162

C'2D2HC'-^:C'2C>2F'« 897 8, , ^7, , Ground 20 349.5 .5 162

9, . Ground 22 893.5 .1 162

10, , *- 9, , Ground 25 436.8 .1 162

11, , *-io , , Ground 27 980.8 .1 162

749-587 0-69— 16 229
900- l-Chloro-2-Butyne i Molecular Constant Table

C.HsCl C,(C;,v.Cj CH:,C:CCH,C1

Isotopic Species Pt. Id. No. A (MHz) B(MHz) C(MHz) D, K A

C'^H.C'^lC'^C'-^H^CP

C'2H,C'2|C'^C''^H,Cr" Cs

901 90217 631. M

17 329. M

1 490.55 M

1 4,59.76 M

1 385.06 M

1 357.26 M

0.40

0.27

-28.4

-21.6

Id. No. /Aa Debye Debye /u., Debye eQq V:, Acc. OJa d eo], d oj, d oj,, d

901 2.17 T 0. X <100

References: ABC: 252 Dj: 252 Djk: 252 k: A:

fji: 380 eQq: V: 252 I: ' w: Add. Ref.: 221

230
l-Chloro-2-Bulyne Spectral Line Table

Isotopic Species Id.

INo. Kotational Quantum Nos.

Vib. State Int. Kotor

State n

I?'

1

Hyp<

I?' r

17frequency

Mriz

Acc. xMHz

net.

C'==H3C'2iC'2C'2H2CP 901 7, 0, 7<- 6, 0, 6 Ground 20 100. 252

-7 1/; ^ £ 1 c Ground 20 491.7 .15 252

/, 1, /<— 0, 1, 0 Ground 1 A ICO O

19 7.53.23 .05 252

I, o, 't*— 0, 6, o Ground OA 1 "J/i "7 zU 13o. / .15 252 nor^ £. 0 A

I, 6, D<— t), 6, 4 Ground OA 1 O/; "7 zO 136.7 .15 252

7. 4, 3^ 6, 4, 2 Ground 20 137.8 .15 252

7, 4, 4<— 6, 4, 3 Ground 20 137.8 .15 252

o, U, o<— 7, 0, 7 Ground 22 960.93 .05 252

O 1 ^7.^ "7 1 £

0, 1, /, 1, O Ground flo /I 1 Ad z3 416.04 .05 252

o,O 1I, o<— O.^ "TIT 7, 1, 7 Ground 22 572.56 .05 252

8, 2, 6«- 7. 2, 5 Ground 23 042.71 .05 252

O O *7.i '7 O £

o, z, /<— /, Z, O Ground on AAA CA 22 999.59 .05 252

O O C ^ T o /I o, 3, 5*— /, 3, 4 Ground O O A 1 /I A 26 014.4 .15 252

O 0 '7 O C o, 3, 0*— /, 3, 5 Ground OO Al A A 23 014.4 .15 252

O A A ^ n A 'i o, 4, 4*— /, 4, o Ground 09 Al A A 23 014.4 .15 252

8, 4, 5-^ 7, 4, 4 Ground 23 014.4 .15 252

o n Q A Q Ground OC Ol "7 "7

Z5 ol /. /U AC .05 OC o 252

y, 1, o*^ o, 1, / Ground 0<; OOCi OA Z6 Joy.o4 AC .05 oco 252

y, 1, y*— o, 1, o Ground OC OAA A"7 25 oyu.6/ AC .05 252

y, Z, /«— o, Z, 0 Ground OC AOO 25 933.76 .05 252

9, 2, 8-^ 8, 2, 7 Ground 25 872.05 .05 252

y, o, 0*— o, o, 0 Ground OC OAO O 25 892.2 .15 252

y, o, I* o, 0 Ground OC OAO O z5 oyz.z

1 c .15 252

y, 4, 0*— o, 4, 4 Ground OC OAO O z5 oyz.z

1 c .15 252

y, 4, O*^ o, 4, O Ground OC OAO O 25 8y2.2 1 c .15 252

10, 0,10-^ 9, 0. 9 Ground 28 669.96 .05 252

lU, 1, y«— y, 1, o Ground OA O^ 1 OO z9 261. ZO .05 252

lU, 1,10*— 9, 1, 9 Ground OO OA^ 1 28 207.61 .05 252

lA O O.* A O "7 lu, z, o<— y, Z, / Ground OO OOO OO 28 828.23 .05 252

10, 2, 9<- 9, 2, 8 Ground 28 743.74 .05 252

10, 3, 7*— 9, 3, 6 Ground 28 772.3 .15 252

lA O 0.j^ A O 7

10, 3, 8<— 9, 3, 7 Ground OO '7'7f\ O 28 770.2 .15 252

1 A A A /I C lu, 4, o«— y, 4, 0 Ground OO Tin o 28 liv.Z .15 252

in A n^ c\ A c

lU, 4, /«— y, 4, O Ground OO "7"7A O 28 /70.2 .15 252

C'^'HsC'^iC'^C'^HaCl" 902 9, 0, 9*- 8, 0, 8 Ground 25 293.3 .3 252

y, 1, y«^ o, 1, o Ground OA Qni A z4 o/ /.4 .6 252

y, 3, o«— o, 3, 5 Ground OC 0£0 25 363.7 .3 252

y, 3, /<— 8. 3, 0 Ground OC o^o •? 25 363. / .3 252

9, 4, 5*— 8, 4, 4 Ground OC 0/^0 "7 25 363. / .3 252

9, 4. 6-^ 8, 4, 5 Ground 25 363.7 .3 252

1lu,A Au,iu<— 1 A.t AAA y, u, y Ground OO AO^ A ZO Uo/.y .6 252

1 A 1 A.I A 1 O

lU, 1, y<^ y, 1, o Ground OO i^i^ 1 c ZO 661.5 .3 252

1 A 11 A^ A 1 A

10, 1,10«— 9, 1, 9 Ground O"? £0 "7 "7 z / 061.1 .3 252

10, 3, l'^ 9, 3, 6 Ground 28 183.7 .3 252

10, 3, 8^ 9, 3, 7 Ground 28 183.7 .3 252

10, 5, 5<- 9, 5, 4 Ground 28 183.7 i .3 252

10, 5, 6*- 9, 5, 5 Ground 28 183.7 i .3 252

11, O.llWO, 0,10 Ground 30 877.9 •3 252

231
910- 2-Fluoro-l,3-Butadiene Molecular Constant Table

Fluoroprene

C4H5F Cs(Cs,Cs.Cs) CH2:CHCF:CH2

Isotopic Species Pt. Gp. M.

No. A (MHz) B (MHz) C (MHz) D,, K A

C'^H2:C'2HC'T"':C'^H2 Cs 911 10 006.26 M 4 264.35 M 2 989.21 M -.64 .049

Id. No._ fjLg, Debye fjit, Debye /Ac Debye eQq V Acc. Ired COa d cOb d o)c d Wd d

911 0.288 M 1.388 M 0. X 280' 1

References: ABC: 385 Dj: Djk: k: 385 ^- 385

M: 385 eQq: V: I: o): 385

1. This value was given by Lide for the lowest bending mode.

2-Fluoro-l,3-Butadiene

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F,' F' F MHz ±MHz

911 1, 1. 1^ 0, 0, 0 Ground A 0 12 995.53 .03 385

2. 1. 2^ 1, 0, 1 Ground A 0 18 973.87 .03 385

2, 2. 0^ 1, 1, 1 Ground A 0 34 472.81 .03 385

2, 2, 1^ 1, 1, 0 Ground A 0 33 007.94 .03 385

2, 1, 2^ 2, 0, 2 Ground A 0 8 481.94 .03 385

2, 2, 1^ 2, 1, 2 Ground A 0 21 051.13 .03 385

3, 1, 3^ 2, 0, 2 Ground A 3 24 301.42 .03 385

3, 1, 3^^ 2, 0, 2 1 A 1 24 352.94 .03 385

3, 1, 3<- 2, 0, 2 Ground A 1 24 358.82 .03 385

3, 1, 3^ 2, 0, 2 Ground A 0 24 393.53 .03 385

3, 2, 2^ 3, 1, 3 Ground A 0 23 074.5 .2 385

4, 0, 4-^ 3. 1, 3 1 A 0 23 904.63 .03 385

4, 0, 4^ 3. 1, 3 Ground A 0 23 959.42 .03 385

4, 0, 4^ 3, 1, 3 1 A 1 23 962.2 .2 385

4, 0, 4^ 3, 1. 3 Ground A 1 24 007.74 .03 385

4, 0, 4*- 3. 1. 3 Ground A 2 24 051.09 .03 385

4, 0, 4^ 3, 1, 3 Ground A 3 24 089.49 .03 385,

4, 1, 3^ 4, 0, 4 Ground A 0 14 799.7 .2 385

4, 2, 3^ 4, 1, 4 Ground A 0 25 807.92 .03 385

5. 0, 5^ 4, 1, 4 1 A 0 31 080.55 .03 385

5, 0, 5^ 4, 1, 4 1 A 1 31 134.21 .03 385

5, 0, 5^ 4, 1, 4 Ground A 0 31 140.55 .03 385

5, 0, 5^ 4, 1, 4 Ground A 1 31 185.84 .03 385

5, 0, 5^ 4, 1, 4 Ground A 2 31 227.04 .03 385

5, 0. 5^ 4/ 1, 4 Ground A 3 1 31 263.84 .03 385

232
2-Fluoro-l,3-Butadiene Spectral Line Table

Isotopic Species T JId.

l>lo. Rotational Quantum Nos.

Vib. State Int. Rotor

State n iype

I?' r

rfine

Fi

r;' r Frequency

MHz

Acc. ±MHzRef.

C'^HjiC'^HC'^F'-'iC'^H^ 911 5, 1, 5<— 4, 0, 4 (iround AA n 34 586.04 .03 385

5, 1, 4«— 4, 2, 3 Ground AA U 25 249.7 .2 385

5, 2, 3-e- 5, 1, 4 Ground A 0 16 148.9 .2 385

5, 2, 4^ 5, 1, 5 Ground A 0 99 940 6 .2 385

5, 3, 2<— 5, 2, 3 Ground AA 27 324.1 .2 385

5, 3, 2*— 5, 2, 3 Ground AA 0z 27 766.71 .03 385

5, 3, 2<— 5, 2, 3 Ground AA 1 28 031.28 .03 385

5, 3, 2^ 5, 2, 3 1 A 1 98 1 6'^ .03 385

5, 3, 2^ 5, 2, 3 Ground A 0 98 V?'^ QO .03 385

5, 3, 2<— 5, 2, 3

1i A 0 98 SOI 90 .03 385

6, 1, 5-^ 6, 0, 6 Ground AA

A 25 316.9 .2 385

6, 1, 5*— 6, 0, 6 Ground AA

00 25 492.18 .03 385

6, 1, 5^ 6, 0, 6 Ground A 2

9=1 ^•j f\H9 U0Z..00 88 .03 385

6, 1, 5*- 6, 0, 6 Ground A 1

9"^ 889 fi'? .03 385

6, 1, 5<— 6, 0, 6 Ground A

AU 9*1 089 4"^ .03 385

6. 1, 5<— 6, 0, 6 1 A U 26 231.29 .03 385

6, 2, 4.*— 6, 1, 5 Ground A

A

u 17 778.5 .2 385

6, 3, 3^ 6, 2, 4 Ground A 0 96 '^86 94 .03 385

7, 2, 5^ 7, 1, 6 Ground A 0 20 907.7 2 385

7, 3, 4^ 7, 2, 5 Ground A 4 9^ 8'i'^ 8 2 385

7, 3, 4^ 7, 2, 5 Ground A 3 24 036.17 .03 385

7, 3, 4^ 7, 2, 5 Ground A 2 24 243.23 .03 385

7, 3, 4^^ 7, 2, 5 Ground A 1 Z4 4/0.Zd .06 000

7' 3' 4*- 7^ 2! 5 1 A 1 0 /I coo OA 24 583.81) AO .U3 Q OC OOD

7, 3, 4*- 7, 2, 5 Ground A 0

OA '700 1 A z4 /,iZ.lU .Uo 000

7

/, Q

•J,

/I ^ 7 CD 1 A nU 24 887.38 .03 385

Q0, z. 0^ Q

0, 11, Ground AA A 24 858.1 .2 385

8, 2, 6^ 8, 1, 7 Ground A 3 OQ A07 lA 0'? 000

8, 2, 6^ 8, 1, 7 Ground A 2 9^ 91 9 (SQ 0^ 000

Q z. A* Q0, 1 7 Vjl 0 Ul lU 11 9S 40fi 9'i .03 385

0 9z. f:,^ 0* Q

0, i. 7 Ground AA

AU 25 605.61 .03 385

QO1 z.

i:,^ 0* Q 1 , 7 1 AAAU 25 743.60 .03 385

8, 3, 5^ 8, 2, 6 VTI (.nil 1 LI A 3 9^ 9Q4 78 .03 385

8. 3, 5^ 8, 2, 6 1 w rt'\ 1 1 n /H A 2 9^ 491 94 .03 385

Q

0, 0, Q0, z. 0 1 _ 1"/ m r> V ' HfUim AA

11 9^ 709 41 .03 385

Q0, -J, Q0, z. 0 1

AA 1 23 814.66 .03 385

Q

0, 0, 0*

Q

0, z. 0 Ground AA

A

u 23 948.98 .03 385

8. 3, 5^ 8, 2, 6

11 A 0 94 C\C)f\ 1 9 0^ 000

9, 3. 6^ 9, 2, 7 Ground A 3 9^ 87Q 1

.03 385

y. 3, 6<— 9, 2, 7 Ground AA 2 94 079 8S .03 385

9, 3, 6<— 9, 2, 7 Ground AA 1 24 284.40 .03 385

9, 3, 6*— 9, 2, 7 1

AA 1 24 392.35 .03 385

9, 3, 6^ 9, 2, 7 Ground A 0 Z^- DiZ.oU .Uo

9, 3, 6^ 9, 2, 7

11 A 0 Z^94, fi'^xl DD 1 . 7^/ 0 -Uo OOD

10, 3, 7*— 0, 2, 8 Ground AA 4

9^ QAQ 1 .z9 000

10, 3, 7<- 10, 2, 8 Ground A 3 26 091.38 .03 385

10, 3, 7^10, 2, 8 Ground A 2 26 293.23 .03 385

10, 3, 7^10, 2, 8 Ground A 1 96 "^08 ^^4 .uo 0^ 000

10, 3, 7^10, 2, 8 1 A 1 26 626.69 .03 385

10, 3, 7^10, 2, 8 Ground A 0 26 735.76 .03 385

10, 3, 7^10, 2, 8 1 A 0 26 886.28 .03 385

11, 3, 8^ 11, 2, 9 Ground A 0 30 754.10 .03 385

233
920 - trans-Crotononitrile Molecular Constant Table

trans-2-Butenenitrile: trans-Crotonic Nitrile; trans-Propenyl Cyanide

C^H.N Cs(C3v,Cs) t-CH3CH:CHCN

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) D,, D.,K K A

t-C'-H3C'^H:C'2HC"2N'^ Cs 921 38 200. M 2 297.05 M 2 195.22 M .00034 -.0126

Id. No. jUa Debye Debye jLi(. Debye eQq V:, Acc. Ired Wa d Wh d We d Wd d

921 4.5 T 0. X >2100

References: ABC: 293

Im: 293

Dj: 293 eQq:

Djk: 293

V: 293

trans-Crotononitrile Spectral Line Table

Isotopic apecies T 1 Id. No.Kotationai Quantum Nos.

Vib. State Int. Kotor

btate n

r T Hypt

17' r nine

IT" K17r Frequency

MHz

Acc. ±Miiz

Kei.

t-C'2H3C'2H:C'2HC'2N'^ 921 3, 0, 2, 0, Ground 13 475.89 .5 293

3, 1, <— 2, 1, Ground 13 324.45 .5 293

3, 1, «— 2, 1, Ground 13 629.06 .5 293

3, 2. <— 2, 2, Ground 13 477.2 .5 293

4, 0, ^ 3, 0, Ground 17 966.75 .5 293

4. 1. <- 3, 1, Ground 17 765.04 .5 293

4. 1. <— 3, 1, Ground 18 172.15 .5 293

4, 2, ^ 3, 2, Ground 17 970.0 .5 293

/I 0 * O 0

4-, O, * O, O, Ground 1 7 070 n t:

5, 0, <- 4. 0. Ground 22 456.90 .5 293

5, 1, ^ 4, 1, Ground 22 205.78 .5 293

5, 1, <- 4, 1, Ground 22 714.99 .5 293

5, 3, ^ 4, 3, Ground 22 463.68 .5 293

5. 4, <- 4, 4, Ground 22 463.68 .5 293

6, 0, <- 5, 0, Ground 26 945.74 .5 293

6, 1, ^ 5, 1, Ground 26 646.22 .5 293

6, 1, ^ 5, 1, Ground 27 257.39 .5 293

6, 2, 5, 2, Ground 26 953.3 .5 293

6, 2, 5, 2, Ground 26 961.1 .5 293

6, 3. 5, 3, Ground 26 956.48 .5 293

6, 4, ^ 5, 4, Ground 26 956.48 .5 293

6, 5, <- 5. 5, Ground 26 957.60 .5 293

8, 0, 7, 0, Ground 35 919.24 .5 293

8. 1, ^ 7, 1, Ground 35 526.03 .5 293

8. 1. ^ 7, 1, Ground 36 340.65 .5 293

8, 2, <- 7, 2, Ground 25 954.3 .5 293

8, 2, ^ 7, 2, Ground 35 936.2 .5 293

8, 3, <- 7, 3, Ground 35 942.6 .5 293

8. 4, ^ 7, 4, Ground 35 942.6 .5 293

8, 5, <- 7. 5, Ground 35 943.5 .5 293

8, 6. <- 7, 6, Ground 35 945.6 .5 293

8. 7. ^ 7, 7, (Ground 35 948.4 .5 293

234 j
930 - 1,2-Butadiene Molecular Constant Table

Methylallene

C,He C,(C3v,C,) CH3CH:C:CH,

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) Dj K A

C'2H3C'2H:C"2:C'2H2 931 33 860. M 4 201.26 M 3 928.11 M .0012 -.054 1.52.8

Id. No. /Xa Debye Hh Debye jU,(. Debye eQq V;, Ace. Irecl ojb d ClJe d «Jd d

931 0.394 M 0.070 M 0. X 1589 6

References:

ABC: 182 Dj: 182 Djk: 182 k: A: 182

/x: 182- eQq: V: 182 I: O):

1,2-Butadiene Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n

IT' r r MHz ±MHz

r'lzu r'i2i4.r'i2.r'i2i4

L. 113^. ri:L- 1I2 2, 0. 2«- 1, 0, I r A vj'rounQ E 0 16 256.76 .03 182

2, 0, 2^ 1, 0, 1 Ground A 0 16 256.93 .03 182

2, 1, 1^ 1, 1, 0 Ground E 0 16 529.90 .03 182

2, 1, 1^ 1, 1, 0 Ground A 0 16 532.29 .03 182

2, 1, 2^ 1, 1, 1 Ground A 0 15 985.82 .03 182

2, 1, 2-^ 1, 1, 1 Ground E 0 15 987.84 .03 182

3, 0, 3^ 2, 0, 2 Ground E 0 24 380.36 .03 182

3, 0, 3<- 2, 0, 2 Ground A 0 24 380.63 .03 182

3, 1, 2-^ 2, 1, 1 Ground E 0 24 796.20 .03 182

3. 1, 2<- 2, 1, 1 Ground A 0 24 797.09 .03 182

3, 1, 3^ 2, 1, 2 Ground A 0 23 977.46 .03 182

3, 1, 3^ 2, 1, 2 Ground E 0 23 977.89 .03 182

3, 2, 1^ 2. 2, 0 Ground E 0 24 393.2 .1 182

3, 2, 1^ 2,

2,

2, 0 Ground A 0 24 396.90 .03 182

3, 2, 2^ 2, 1 Ground A 0 24 389.35 .03 182

3, 2, 2^ 2, 2, 1 Ground E 0 24 392.8 .03 182

4, 0, 4^ 3, 0. 3 Ground E 0 32 498.28 .03 182

4, 0. 4^ 3, 0, 3 Ground A 0 32 498.63 .03 182

4, 1. 3^ 3, 1, 2 Ground E 0 33 059.64 .03 182

4. 1. 3^ 3, 1. 2 Ground A 0 33 060.34 .03 182

4, 1, 4*- 3, 1. 3 Ground A 0 31 967.61 .03 182

4, 1, 4^ 3, 1, 3 Ground E 0 31 967.67 .03 182

4, 2, 2^ 3, 2, 1 Ground E 0 32 528.1 .1 182

4, 2, 2^ 3, 2,

2,

1 Ground A 0 32 536.26 .03 182

4. 2, 3^ 3. 2 Ground A 0 32 517.58 .03 182

4, 2, 3«- 3, 2, 2 Ground E 0 32 525.0 182

4, 3, 1-^ 3, 3. 0 (Ground E 0 32 525.0 182

4, 3, 1-^ 3. 3, 0 Ground A 0 32 525.0 182

4, 3, 2^ 3, 3, 1 Ground E 0 32 525.0 182

4, 3. 2^ 3, 3. 1 Ground A 0 32 525.0 !l 182

235
940- 2-Methylpropene

Isobutylene

C4H8 C2v(C3v*C3v,C2v)

Molecular Constant Table

(CH3)2C:CH2

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) Dj K A

941 9 133.32 M 8 381.75 M 4 615.99 M

a-C'2H2DC'2H3C'':C'-H2 c, 942 8 819.46 M 7 981.08 M 4 469.59 M

s-C'2H2DC'2H3C'2:C'2H2 943 9 132.59 M 7 788.98 M 4 431.05 M

944 8 693.49 M 8 114.67 M 4 422.67 M

c, 945 9 074.31 M 8 149.00 M 4 529.72 M

{C'^H3)2C>":C'3H2 C2 946 8 810.08 M 8 381.73 M 4 531.84 M 1

Id. No. /Xa Debye /Ah Debye fjL^. Debye eQq V3 Acc. Ired tOa d ojh d aj(. d

941 0. X 0.503 M 0. X 2210

References: ABC: 326,366

ix: 326 eQq: V: 326

236
2-Methylpropene Spectral Line Table

Isotopic Species Id. R )tational Vib. State Int. Rotor Hyperf'ine Frequency Acc. Ref. No. Quantum Nos State F''1 F' F F MHz ±MHz

(C'2H3)2C'2:C'^H2 941 2 0, 2<- 1 1, 1 Ground 22 128.0.5 .05 326

2 1, 2<- 1 0, 1 Ground 22 981.28 .05 326

2 2, 1^ 1 1, 0 Ground 32 01.5.95 .05 326

3 0, 3<- 2 1, 2 Ground 31 768.96 .05 326

3 1, 3<- 2 0, 2 Ground 31 879.31 .05 326

3 1, 2^^ 3 0, 3 Ground 20 279.79 .05 326

3 2, 2<- 3 1, 3 Ground 20 767.71 .05 326

4 1, 3<- 4 0, 4 Ground 28 771.06 .05 326

4 2, 2*- 4 1, 3 Ground 19 669.25 .05 326

4 2, 3^ 4 1, 4 Ground 28 830.61 .05 326

4 3, 2*- 4 2, 3 Ground 21 026.60 .05 326

5 2, 3<— 5 1, 4 Ground 28 .557.28 .05 326

5 3! 2<- 5 2! 3 Ground 18 703.70 .05 326

5 4, 2<- 5 3. 3 Ground 21 519.40 .05 326

5 5, 1^ 5 4, 2 Ground 18 358.45 .05 326

6 3, 3^ 6 2, 4 Ground 28 121.48 .05 326

6 4, 3<— 6 3, 4 Ground 28 775.67 .05 326

6 5^ 2*- 6 4! 3 Ground 22 320.86 .05 326

6 6, 1<- 6 5, 2 Ground 20 766.70 .05 326

6 6, 1^ 6 5, 2 Ground EH 0 20 767.19 326

6 6. 1<- 6 5. 2 Ground E(+) 0 20 767.23 326

7 5, 3^ 7 4, 4 Ground 28 851.31 .05 326

7 6, 2^ 7, 5, 3 Ground 23 490.64 .05 326

7 7, O'^ 7, 6, 1 Ground 19 736.70 .05 326

7 7, O'^ 7, 6, 1 Ground EH 0 19 737.40 326

7 7, 1<— 7, 6, 2 Ground 23 524.94 .05 326

7, 7, 1-^ 7, 6, 2 Ground E 0 23 525.58 326

8, 6, 3^ 8, 5, 4 Ground 29 089.07 .05 326

8 8, 0^ 8, 7, 1 Ground 23 994.84 .05 326

8 8, 0^ 8, 7, 1 Ground EH 0 23 995.50 326

9, 6, 3^ 9, 5, 4 Ground 24 638.80 .05 326

9, 8, 1^ 9, 7, 2 Ground 18 747.34 .05 326

9, 8, 1^ 9, 7, 2 Ground E 0 18 748.06 326

9, 9, 0^ 9, 8, 1 Ground 28 220.48 .05 326

9, 9, 0^ 9, 8, 1 Ground EH 0 28 221.17 326

10, 7, 3'^10, 6, 4 Ground 22 976.59 .05 326

ll! 9! 2'^11, 8^ 3 Ground 18 473.09 .05 326

11, 9, 2^11, 8, 3 Ground EH 0 18 473.73 326

12, 10, 2^12, 9, 3 Ground 21 449.36 .05 326

12, 10, 2^12, 9, 3 Ground EH 0 21 450.11 326

12, 10, 2^12, 9, 3 Ground EH 0 21 450.14 326

14^ 12! 2^14, 11! 3 Ground 29 909.89 .05 326

14, 12, 2*-14, 11, 3 Ground EH 0 29 910.98 326

14, 12, 2-^14, 11, 3 Ground EH 0 29 911.02 326

942 2, 0, 2*- 1. 1, 1 Ground 21 256.85 .05 326

2, 1, 2^ 1, 0,

"11 Ground zZ LLiS.LZ. ozo

2, 2, 1^ 1, 1, 0 Ground 30 927.96 .05 326

3, 0, 3<- 2, 1, 2 Ground 30 657.22 .05 326

3, 1, 3«- 2, 0, 2 Ground 30 803.61 .05 326

3, 2, 2^ 3, 1, 3 Ground 19 730.99 .05 326

237
2-Methylpropene

Spectral Line Table

Isotopic Species la. Rotational Vib. State Int. Kotor Hyperfine Frequency Acc. Ref. No. Quantum Nos State n F' F MHz ±MHz

a-L £1.2'-'^ "3^ •'-^ '^2 4, 2, 2^ 4, 1, 0 Ground 18 347.00 .05 326

4, 3, 2<— 4, 2, 0 Ground 20 065.05 .05 326

s-C''=H2DC'2H3C'2:C'2H2 943 2, 0. 2^ 1, 1, 1 Ground 20 752.87 .05 326

2, 1, 2*- 1, 0, 1 Ground 22 425.74 .05 326

2. 2. 1^ 1, 1, 0 Ground 31 828.82 .05 326

3, 0, 3-^ 2, 1, 2 Ground 30 377.99 .05 326

3. 1, 3-^ 2, 0, 2 Ground 30 759.55 .05 326

3. 1, 2^ 3, 0, 3 Ground 18 852.70 .05 326

3, 2, 2^^ 3, 1, 3 Ground 20 334.26 .05 326

(C>2H3),C'2:C'2HD 944 2, 0, 2^ 1, 1, 1 Ground 21 319.80 366

2, 1, 2^ 1, 0, 1 Ground 21 961.51 366

2, 2, 1^ 1, 1, 0 Ground 30 503.15 366

3, 0, 3^ 2, 1, 2 Ground 30 475.68 366

3. 1, 3^ 2, 0, 2 Ground 30 542.80 366

3, 1, 2^ 3, 0, 3 Ground 19 639.41 366

3, 1, 2^ 3, 1, 3 Ground 19 944.54 366

945 1, 1, 1<- 0, 0, 0 Ground 13 604.08 366

2, 0, 2^^ 1, 1, 1 Ground 21 582.34 366

- 2, 1, 2^ 1, 0, 1 Ground 22 663.50 366

2, 2, l'^ 1, 1, 0 Ground 31 752.65 366

3, 0, 3-^ 2, 1, 2 Ground 31 153.16 366

3, 1. 3<- 2, 0, 2 Ground 31 325.69 366

3, 1, 2<- 3, 0, 3 Ground 19 764.88 366

4, 2, 2^ 4, 1, 3 Ground 18 905.09 366

4, 3. 2^ 4, 2, 3 Ground 20 889.82 366

946 1, 1, 1«- 0, 0, 0 Ground 13 342.01 366

2. 0. 2^ 1, 1, 1 Ground 21 943.47 366

2, 1, 2^ 1, 0, 1 Ground 22 405.60 366

2, 2, 1, 1, 0 Ground 30 962.08 366

3. 0, 3^ 2, 1. 2 Ground 31 233.01 366

3, 1, 3^ 2, 0, 2 Ground 31 268.52 366

3, 1, 2^ 3. 0, Ground ZU90 1 7A 07 1 i 4-.^ / 3, 2, 2^ 3, 1, 3 Ground 20 340.93 366

4, 2, 2^ 4, 1, 3 Ground 19 947.74 366

4, 3, 2^ 4, 2, 3 Ground 20 429.62 366

238
950- cis-2,3-Epoxybutane Molecular (Constant 'I'alile

C^HkO Cs(C;,v,Cs,C,v) CH3C*H,0C*CH3

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) D., D.,K K A

C>2H,C'^H20'«C'%C'2H, Cs 951 8 057.71 M 4 461.36 M 3 468.60 M -.567

Id. No. jUa Debye /u,|, Debye /x,. Debye eQq V.-. Acc. Ired (Oa d &»], d CUi- d oj<i d

951 0. X 1.55 M 1.32 M 1607 150

References: ABC: 335 Dj: Djk: k: A:

fi: 335 eQq: V: 335 I:

Coupling Parameter: Ia= 3.194 amu A2. Ref: 335.

cis-2,3-Epoxybutane c . i i t ui ' spectral Line 1 able

Isotopic Species Id. No.Rotational Quantum Nos.

ViD. State Int. Rotor

State n HypeF'

rfine

F, F

r requency MHzAcc. ±MHz

net.

C'^HaC'^HjO'^C'^C'^Ha 951 1, 1, 1«- 0. 0, 0 Ground 11 526.30 .2 335

2, 1, 1-e- 1, 0, 1 Ground 21 441.30 .2 335

i, z< i, u, i Ground .z 2. 2, 1^ 1. 1, 1 Ground 28 634.49 .2 335

2, 2, 0^ 2, 1, 1 Ground 10 967.72 .2 335

3, 0, 3^ 2, 1, 2 Ground 20 327.53 .2 335

3, 2, 1-=- 3, 1, 2 Ground 10 281.98 .2 335

3, 2, 2^ 3, 1, 2 Ground 9 423.92 .2 335

4, 1, 3^ 4, 0, 4 Ground 10 887.01 .2 335

4, 2, 2-^ 4, 1, 3 Ground 10 099.17 .2 335

4, 3, 2^ 4, 2, 3 Ground 21 011.14 .2 335

5, 2, 3*- 5, 1, 4 Ground 10 771.40 .2 335

7, 3, 5^ 7, 2, 5 Ground 11 973.07 .2 335

7, 3, 5^ 7, 2, 6 Ground 24 993.89 .2 335

8, 2, 6^^ 8, 1, 7 Ground EE 0 19 666.15 .2 335

8, 2, 6-^ 8. 1, 7 Ground AE 0 19 667.05 .2 335

8, 2, 6<- 8, 1, 7 Ground AA 0 19 667.94 .2 335

8, 3, 6^ 8, 2, 6 Ground 9 168.84 .2 335

8, 4, 4-^ 8, 3, 5 Ground 23 798.49 .2 335

10, 4, 6-^10, 3, 7 Ground 20 556.93 .2 335

11, 4, 7<-ll, 3, 8 Ground 20 201.05 .2 335

16, 6,11*-16, 5,11 Ground AE 0 26 072.78 .2 335

17, 6,12^17, 5,12 Ground AA 0 20 888.81 .2 335

17, 6,12-^17, 5,12 Ground AE 0 20 889.68 .2 335

17, 6,12^17, 5,12 Ground EE 0 20 890.57 .2 335

19, 6,14<^19, 5,14 Ground AA 0 11 204.67 .2 335

19, 6,14*-19, 5,14 Ground AE 0 11 205.59 .2 335

19. 6,14-^19, 5,14 Ground EE 0 11 206.47 .2 335

23, 7,17-^23, 6,17 Ground AA 0 9 641.95 .2 335

23, 7,17^23, 6,17 Ground AE 0 9 643.07 .2 335

23, 7,17-^23, 6,17 Ground EE 0 9 644.25 •2 335

239
960- 2-Bromo-2-Methylpropane Molecular Constant Table

tert-Butyl Bromide

C,H,Br C;,v(C;,v,C3v.C,v) (CHjljCBr

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) Dj K A

(C'^HjIjC'^Br'"

C3V

C3V

961 9622 044.2 M

2 028.3 M

2 044.2 M

2 028.3 M

Id. No. /Lia Debye jU,,, Debye /u,,. Debye eQq V Acc. I red OJa d W|, d d w,i d

961

962

2.21 M 0. X 0. X 511.6

427.4

References: ABC: 339 Dj: D,k: k: , A:

M: 339 eQq: 339 V: I: w: Add. Ref.: 33

240
2-Bromo-2-Methylpropane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F' F F MHz ±MHz

961 5, *- 4, Oround 20 441.9 .3 1.34

5, 0^ 4! 0 Ground 11/2 0/9 20 4.39.6 .5 3.39' 5, 0^ 4, 0 Ground 13/2 11/2 20 439.6 .5 339'

5, 0<— 4, 0 Ground 7/9 5/2 20 448.1 .5 339'

5] 0<- 4^ 0 Ground 9/2 7/2 20 449.6 .5 339

5, l'^ 4, 1 Ground 13/2 11/2 20 437.6 .5 339

5. 1^ 4. 1 Ground 7/2 5/2 20 443.3 .5 339

5, 1<- 4. 1 Ground 11/2 9/2 20 443.7 .5 339

5, l<- 4, 1 Ground 9/2 7/2 20 448.1 .5 339'

5, 2<- 4, 2 Ground 7/2 5/2 20 427.3 .5 339

5, 2<- 4, 2 Ground 13/2 11/2 20 431.7 .5 3.39

5, 2-^ 4, 2 Ground 9/2 7/2 20 453.3 .5 339

5, 2<- 4, 2 Ground 11/2 9/2 20 456.8 .5 339

5, 3<- 4, 3 Ground 7/2 5/2 20 400.9 .5 339

5, 3^^ 4, 3 Ground 13/2 11/2 20 421.0 .5 339

5, 3<- 4, 3 Ground 9/2 7/2 20 459.7 .5 339

5! 3-^ 4! 3 Ground 11/2 0/9 20 479.0 .5 339

5, 4^ 4, 4 Ground 7/9 5/2 20 365.3 .5 339

5, 4<- 4, 4 Ground 13/2 11/2 20 406.5 .5 339

5. 4<— 4' 4 Ground 0/9 7/9 20 468.0 .5 339

5, 4«— 4, 4 Ground 11/2 9/2 20 509.3 .5 339

6^ ^ 5^ Ground 24 538.1 .3 134

7, <- 6, Ground 28 622.2 .3 134

8, ^ 7, Ground 32 720.8 .3 134

9, ^ 8, Ground 36 809.8 .3 134

10, 9, Ground 40 831.8 .3 134

962 5, 0^ 4, 0 Ground 11/2 9/2 20 281.2 .5 339'

5, 0<- 4, 0 Ground 13/2 11/2 20 281.2 .5 339'

5, 0^ 4, 0 Ground 7/2 5/2 20 288.9 .5 339'

5, O'^ 4, 0 Ground 9/2 7/2 20 288.9 .5 339'

5, l'^ 4, 1 Ground 13/2 11/2 20 279.5 .5 339

5, 1<— 4, 1 Ground 11/2 9/2 20 284.7 .5 339

5^ 1^ 4^ 1 Ground 9/2 7/2 20 289.6 .5 339

5, 2^ 4, 2 Ground 7/2 5/2 20 271.3 .5 339

5, 2*- 4, 2 Ground 13/2 11/2 20 274.4 .5 339

5, 2<— 4' 2 Ground 9/2 7/2 20 293.2 .5 339

5, 2«— 4, 2 Ground 11/2 9/2 20 295.6 .5 339

5! 3-^ 4i 3 Ground 7/9 5/2 20 249.8 .5 339

5, 3*- 4, 3 Ground 13/2 11/2 20 265.9 .5 339

5, 3<— 4, 3 Ground Q/9 7/9 20 297.8 .5 339

5, 3<— 4, 3 Ground 11/2 0/9 y/

20 313.8 .5 339

5, 4<— 4, 4 Ground 7/2 5/2 20 219.7 .5 339

5, 4^ 4^ 4 Ground 110/^/9z 1 1 /9 20 253.5 .5 339

5, 4*- 4, 4 Ground Q/9 7/9 //z 20 304.6 .5 339

5^ 4«_ 4_ 4 Ground 11/2 0/2 y/

20 339.4 .5 339

6. «— 5, Ground 24 346.4 .3 134

7, ^ 6, Ground 28 405.8 .3 134

8. <— 7, Ground 32 464.8 .3 134

9! ^ 8^ Ground 36 521.8 .3 134

10, ^ 9, Ground 40 565.0 .3 134

1. There is a slight uncertainty as tu which identification corresponds to which frequency for the 5o*—4t) and 5i'^4| transitions in the (CHafeCBr^^ species of Table I. reference 339.

It is assumed that the assignment shown is correct.

241
970 - 2-Chloro-2-Methylpropane

tert-Butyl Chloride

C3v(C3v,C3v,C3v)

Molecular Constant Table

(CH3)3CC1

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C(MHz) Dj K A

(C'2H3)3C'2CP C3V 971 3 017.69 M 3 017.69 M

(C'2H3)3C'^cr" C3V 972 2 953.54 M 2 953.54 M

(C>2H3)3C'-^CP C3V 973 3 014.25 M 3 014.25 M

vvj n3;3\_. r,

'-3V 974 2 949.79 M 2 949.79 M

C'^HsCC'^Hjl^C'^CP'^ Cs 975 4 460. M 3 002.36 M 2 965.87 M

(C'2D3)3C'2CF C3V 976 2 552.52 M 2 552.52 M

(C'2D3)3C'^CP' C3V 977 2 500.22 M 2 500.22 M

Id. No. fjia Debye fX), Debye Debye eQq V Ace. Ired Wa d OJh d (t)^. d 0),, d

971 2.13 M 0. X 0. X -66.9

References: ABC: 340, 363

IJ.: 363 Add. Ref.: 359

Dj:

eQq: 363 V:

A:

242
2-Chloro-2-Methylpropane Spectral Line Table

Isotopic Species Id. No.Rotational Quantum Nos.Vib. State Int. Rotor

State n

•lype F'rfine

F, F

Frequency

MHz

Acc. ±MHzRef.

971 3, <- 2, Ground 18 106.35 .10 363

3, 0<- 2, 0 Ground 3/2 1/2 18 102.76 .1 3.59

3, 0<— 2, 0 Ground 5/2 3/2 18 102.76 .1 359

3, 0<- 2, 0 Ground 7/2 5/2 18 107.19 .15 363

3, 0^ 2, 0 Ground 9/2 7/2 18 107.19 .15 363

3, 1^ 2, 1 Ground 7/2 7/2 18 095.24 .1 359

3, l'^ 2, 1 (Ground 5/2 3/2 18 103.84 .15 363

3, 1<— 2, 1 Ground 7/2 5/2 18 103.84 .15 363

3, 1^ 2, 1 Ground 3/2 1/2 18 108.06 .15 363

3. 1^ 2, 1 Ground 9/2 7/2 18 108.06 .15 363

3, 1^ 2, 1 Ground 5/2 5/2 18 109.66 .1 359

3, 1^ 2, 1 Ground 3/2 3/2 18 116.23 .1 359

3, 2*— 2, 2 Ground 7/2 5/2 18 094.42 .15 363

3, 2^ 2, 2 Ground 5/2 5/2 18 094.42 .15 363

3, 2^ 2, 2 Ground 3/2 3/2 18 106.19 .1 359

3, 2<- 2, 2 Ground 5/2 3/2 18 106.19 .1 359

3, 2^ 2, 2 Ground 7/2 7/2 18 111.15 .15 363

3, 2<— 2, 2 Ground 9/2 7/2 18 111.15 .15 363

3. 2^ 2, 2 Ground 3/2 1/2 18 122.08 .1 359

4, ^ 3, Ground 24 141.5 .10 134

5, <— 4, Ground 30 176.8 .10 363

6, ^ 5, Ground 36 212.3 .10 363

7, ^ 6, Ground 42 243.8 .3 134

(C'^HjjaC'^CF 972 4. ^ 3, Ground 23 627.3 .3 134

5, <— 4, Ground 29 535.6 .3 363

6, ^ 5, Ground 35 442.3 .3 363

7, ^ 6, Ground 41 330. 30. 33

(C'2H3)3C'3CP= 973 5, ^ 4, Ground 30 142.5 363

6, ^ 5, Ground 36 171.1 363

(C'2H3)3C'-^CF 974 5, ^ 4, Ground 29 498.0 363

6, ^ 5, Ground 35 397.3 363

975 5, 0, 5<- 4, 0, 4 Ground 29 827.79 .20 363

5, 1, 4^ 4, 1, 3 Ground 29 929.33 .20 363

5, 1, 5*— 4, 1, 4 Ground 29 747.06 .20 363

6, 0, 6^ 5, 0, 5 Ground 35 785.80 .20 363

6, I, 5*— 5, 1, 4 Ground 35 913.15 .20 363

6, 1, 6^ 5, 1. 5 Ground 35 694.66 .20 363

(C'2D3)3C'2CP'^ 976 4, ^ 3, Ground 20 417.9 3. 340

5, ^ 4, Ground 25 528.0 3. 340

977 4, ^ 3, Ground 20 001.5 3. 340

5, 4, Ground 25 002.5 3. 340

A

I

243
980 - 2-Fluoro-2-Methylpropane Molecular Constant Table

tert-Butyl Fluoride

C4Hi,t C..,v(C3viC3v,C3v) (CH:j),.jCF

Pt Cp.Id. No. A (MHz) B (MHz) C (MHz) D, '--'JK

(C'-HJ;,C'-F'''

C'^'H;,(C'-H:,)X'''^F'"

981 9824 712.15 M

4 704.34 M

4 712.15 M

4 610.46 M 4 431.26 M

.0018

Id. No. fji^ Debye Debye /Xj. Debye eQq V:, Acc. Ired COa d w„ d (D^. d d

981

982

0. X

0. u

0. X

0. X

1.959 M

1.959 M

4300 428 1 493 2

References: ABC: 226 D,,: 226 Djk: k: A:

ix: 226 eQq: V: 226 I: - to: 226

Add. Refs.: 63, 64

Rotational constants (6^) for various vibrational modes:Ta: 4709.04 MHz; t,: 4708.78 MHz; 8^:4720.52 MHz; Se: 4713.73 MHz; p^: 4704.10 MHz. Torsional frequencies: ra:223 ± 25 cm~'. Ref: 226. Extra Reference: 184.

244
2-Fluoro-2-Methylpropane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rot or Hyperfine Frequency Acc. Ref. No. Quantum Nos. V : V,

a ' Ml State n F' F' F F MHz ±MHz

(C'^HiKCF'*' 981 1, 0<- 0, 0 Excited 9 408.0 226

1, 0<- 0, 0 Ground E 1 9 417.7 226

1, O'^ 0, 0 Ground A 1 9 418.0 226

1, 0-^ q\ 0 Ground 9 424.30 226

1, 0^ 0, 0 0; 1 9 427.3 226

1, 0-^ 0, 0 1; 0 9 441.0 226

2, Excited 18 815.92 226

2, E 3 18 817.5 63

2. ^ \. E 2 18 825.3 63

2, ^ ^• Ground A 1 18 836.09 .03 226

2, E 1 18 836.3 63

2, Ground 18 848.53 .03 226

2, ^ J' E 0 18 849.8 63

2. ^ 1; 1; 0 18 854.9 226

2, ^ ^' 0; 1 18 882.01 226

2, 0^ 1. 0 E 1 18 834.50 226'

2^ 1^ 1, 1 E 1 18 821.63 226'

2' 1«- L 1 E 1 18 835.3 226'

3^ ^ 2^ Excited 28 224.5 226

3, ^ 2, Ground A 1 28 254.05 .03 226

3, <- 2, Ground 28 272.72 .03 226

3, ^ 2, 1; 0 28 282.19 226

3, ^ 2, 0; 1 28 323.09 226

3, 0<- 2, 0 E 1 28 250.32 226'

3, l'^ 2, 1 E 1 28 232.47 226'

3, l'^ 2, 1 E 1 28 251.82 226'

3^ 2^ 2! 2 E 1 28 252.49 226'

3, 2^ 2, 2 E 1 28 254.8 226'

C"H,(C"2H,),C'2F"* 982 2, 1, l'^ 1, 0, 1 Ground 18 536. 226

2^ 2^ 0^ I, I, 0 Ground 18 658. 226

2, 2, 1«- 1, 1, 1 Ground 18 723. 226

3, 1, 2^ 2, 0, 2 Ground 27 844.69 .03 226

3. 2, 1^ 2, 1, 1 Ground 27 824.92 .03 226

3, 2, 2^ 2, 1. 2 Ground 27 944.38 .03 226

3, 3, 0^ 2, 2, 0 Ground 28 044.08 .03 226

3. 3. 1^ 2, 2, 1 (iround 28 100.92 .03 226

1. /-doubling occurs here in the singly excited torsional state. A simple treatment of this is given in the reference by Lide and Mann.

749-587 0-69— 17 245
990 - 2-Iodo-2-Methylpropane Molecular Constant Table

tert-Butyl Iodide C4H9I C3v(C3v,C3v,C3v) (CH3)3CI

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C (MHz) K A

c 991 1 562. M 1 562. M

Id. No. /u-a Debye /X|, Debye /u,,. Debye eQq V Acc. I red Wa d oji, d (1)^. d ojd d

991 2.13 M 0. X 0. X

References: ABC: 33 Dj: Djk: k: A: 388 eQq: V: I: co: Add. Ref.: 389

2-Iodo-2-Methylpropane Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F MHz ±MHz

(C'2H3)3C'^r" 991 9, 8, Ground 28 085. 30. 33

10, ^ 9, Ground 31 185. 30. 33

11, -^10, Ground 34 310. 30. 33

12, •^11, Ground 37 490. 30. 33

13, ^12, Ground 40 570. 30. 33

246
1000- 2-Methylpropane Molecular Constant Table

Isobutane; Trimethylmethane

C4H,„ C3v(C3v,C3v,C.tv) (CH;,),.,CH

Isotopic Species Pt. Gp.

Id. No. A (MHz) B (MHz) C (MHz) DjK K

1001 7 789.45 M 7 789.45 M .011 1002 7 773.88 M 7 773.88 M

C3V 1003 7 540.82 M 7 540.82 M

c. 1004 7 788.28 M 7 546.10 M 4431. M

s-lC'^HjDKC'^HajjC'^H 1005 7 629.15 M 7 378.95 M 4 466. M

a-(C'2H2DKC'2H3)2C'2H c, 1006 7 782.70 M 7 259.37 M 4 319. M

Id. No. ix^ Debye fj-h Debye ^t(. Debye eQq V3 Acc. I red a)a d C0|, d o),. d oja d

1001

1003

0. X

0. X

0. X

0. X

0.132 M

0.141 M

3900 426 1 365 2

References: ABC: 266, 297 Dj: 297 Djk: k: A:

fJi: 266, 297 eQq: V: 226 I: 266 Add. Ref.: 146

Rotational constants (Bv) for various excited vibrational modes: t^: 7782.84 MHz; t^: 7774.67 MHz; 8a: 7790.3 MHz; 6e: 7795.0 MHz.

Torsional frequencies: t^: 225±20 cm-'; t^: 280±20 cm"'. Ref: 226.

2-Methylpropane Sp^^,^^j Lj^e Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n F' F MHz ±MHz

1001 1. *- 0. Ground A 0 15 578.9 226

2. Ground E 1 31 098.35 .03 226

2. Ground A 1 31 130.99 .03 226

2, Ground A 0 31 157.46 .03 297

2. 1; 0 A 0 31 161. 226

2, 0; 1 A 0 31 180. 226

(C'^H3)3C'^H 1002 2, A 0 31 095.18 .10 297

(C'^H3)3C'^D 1003 2, A 0 30 162.95 .05 297

(C"H3)(C'2H3)2C'2H 1004 2, 1. 1^ 1. 0. 1 A 0 30 426.24 .10 297

2, 2, 0<- 1, 1, 0 A 0 30 682.00 .10 297

2, 2, 1^ 1, 1, 1 A 0 30 910.58 .10 297

s-(C'2H2D)(C"2H3)2C>2H 1005 2, 1. 1^ 1. 0. 1 A 0 29 765.6 1. 297

2, 2, 0^ 1, 1, 0 A 0 30 031.28 .10 297

2. 2. 1^ 1. 1, 1 A 0 30 266.06 .20 297

a-(C'2H2D)(C'^H3)2C'2H 1006 2, 1, 1-^ 1, 0, 1 A 0 29 560.45 .05 297

2, 2, 0-^ 1, 1, 0 A 0 30 147.92 .05 297

2, 2, 1<- 1. 1, 1 A 0

1 30 607.11

1

.05 297

247
1010 - Ethoxyethane Molecular Constant Table

Diethyl Ether C,H,„0 C,v(Cs,Cs) C2H5OC2H5

Isotopic Species Pt. Gp.

Id. No. A (MHz) B(MHz) C (MHz) D., K A

1011

Id. No. |U.a Debye jUb Debye jU-c Debye eQq V Acc. Ired (Oa d (Oh d ai(. d (Oa d

1011 1.17 T

References: ABC: Dj: Djk: k: A:

ju: 372 • eQq: V: I: w:

Ethoxyethane o » 1 i • t ui ^ bpectral Line 1 able

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n

1 F' F,1 F MHz ±MHz

1011 Not Reported 19 230. 396 Not Reported 19 440. 396 Not Reported 19 590. 396 Not Reported 20 260. 396 Not Reported 20 320. 396

Not Reported 20 510. 396 Not Reported 20 570. 396 Not Reported 20 720. 396 Not Reported 20 740. 396 Not Reported 20 880. 396

Not Reported 20 950. 396 Not Reported 20 965. 396 Not Reported 21 000. 396 Not Reported 21 175. 396 Not Reported 21 230. 396

Not Reported 21 310. 396 Not Reported 21 340. 396 Not Reported 21 450. 396 Not Reported 21 560. 396 Not Reported 21 780. 396

Not Reported 21 850. 396 Not Reported 21 890. 396 Not Reported 22 015. 396 Not Reported 22 215. 396 Not Reported 22 490. 396

Not Reported 22 900. 396 Not Reported' 23 080. 396 Not Reported 23 250. 396

248
1020 - 2,2-Dimethylpropanenitrile Molecular Constant Table

tert-Butyl Cyanide; Trimethylacetonitrile; a,a-Dimethylpropionitrile

C5H9N C,,(C,v,C,,v.Cr,v) (CHa).,CCN

Isotopic Species Pt. Gp.Id. No. A (MHz) B (MHz) C (MHz) D,,K K A

(C'^HjjjC'^C'^N'^

(C'^H3)(C'2H3)2C'2C'^N"' (C'^H3)3C'2C'3N"'

C3V

C3V Cs

1021 1022

1023 10244 513. M

2 749.89 M

2 676.87 M

2 738.45 M

2 7.32.16 M

2 749.89 M

2 676.87 M

2 707.87 M

2 732.16 M

Id. No. /Aa Debye /Ltb Debye /Lte Debye eQq V3 Acc. I red OJa d (o„ d d

1021 3.95 M 0. X 0. X 4000 183' 1

1. Nugent, Mann and Lide state that evidence indicates that the frequency of the degenerate skeletal bending mude ior tertiary-butyl cyanide is approximately the same as for

tertiary-butyl acetylene.

References: ABC: 353 Dj: Djk: k: A:

ft: 353 eQq: V: 353 I: oj: 353

Add. Ref.: 202

Rotational constants (Bv) for various excited vibrational modes: t.^: 2748.84 MHz; t^: 2748.42 MHz; /3e: 2752.15 MHz. Ref: 353.

2,2-Dimethylpropanenitrile Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum NOS. < State n Ft' F' F MHz ±MHz

(C'^H3)3C>2C'2N"' 1021 4, 1^ 3, 1 Ground 21 999.8 .2 190

4, 2^ 3, 2 Ground 21 999.8 .2 190

4, 3*- 3, 3 Ground 21 999.8 .2 190

5, 4, Ground E 1 27 484.2 .1 353

5. 4, Ground A 1 27 488.4 .1 353

5. 4. Ground 27 498.9 .1 353

5, 4. 1, 0 27 521.5 .1 353

5, 1^ 4, 1 1,+ 1 27 539.1 .1 353>

5, 1^ 4, 1 Ground E 1 27 474.9 .1 353'

(C'2H3)3C'^C'2N'^ 1022 4, 1^ 3, 1 Ground 21 414.8 .2 190

4, 2-^ 3, 2 Ground 21 414.8 .2 190

4, 3-^ 3, 3 Ground 21 414.8 .2 190

5. <— 4, Ground 26 768.7 .1 353

(C'3H3)(C'2H3)2C'2C>^N" 1023 5, 0, 5<- 4, 0, 4 Ground 27 223.8 .1 353

5, 1. 4^ 4. 1, 3 Ground 27 306.5 .1 353

5, 1, 5^ 4. 1. 4 Ground 27 153.6 .1 353

5. 2, 4^ 4, 2. 3 Ground 27 238.6 .1 353

4, 1. 3, 1, Ground 21 850. 10. 190

4, 2. 3, 2, Ground 21 788. 2. 190

4, 3, 3, 3, Ground 21 788. 2. 190

(C'^H3)3C'^C"N"* 1024 4, 1^ 3. 1 Ground 21 850. 10. 190

4, 2^ 3, 2 Ground 21 850. 10. 190

4, 3^ 3, 3 Ground 21 850. 10. 190

5. 4, Ground 27 321.6 .1 353

1. Strong satellites of the J = 5*—4 line were assigned by Nugent. Mann and Lide to the lowest lying vibrational states, two of these lines to the degenerate skeletal bending mode

which is the lowest lying Raman band. The weaker of these lines has been assigned to the /-type doublet A^^+ 1. / = + 1. /-type doubling also occurred for a line in the first excited

torsional state, a similar pattern to that for the bending mode having been observed and assigned to K = — 1, / — — 1. The other components of the doublets were not resolved because

of overlapping by unidentified vibrational satellites.

249
1030 -tert -Butyl Isocyanide

a,a-Dimethylethyl Carbylamine

C,H,N

Molecular Constant Table

(CH,).,CNC

No molecular constant data

tert-Butyl Isocyanide Spectral Line Table

Isotopic Species Id. No.

Rotational Quantum Nos.Vib. State Int. Rotor

State n

1

f;' iypeF'

rfine FFrequency

MHz

Acc. ±MHzRef.

(C'^HjlaC'^N'-'C'-'

(C'2H3)3C'2N"'C'2

1031

1032

4, ^ 3.

4. ^ 3,

Ground

(iround

1

22 786.5

23 475.4

203

203

1040- Nitrobenzene

CfiH.NO. C-jv( C2v'G2\

Molecular Constant Table

CeHsNO.,

Isotopic Species Ft. Gp.Id. No. A (MHz) B(MHz) C(MHz) D,, D.,K K A

Ci2H.,N'^0^''

1

1041 4 011.7 M 1 283.8 M 974.3 M -.7962 -.9

Id. No. |ia Debye Debye /u,,. Debye eQq V Acc. I red OJa d W[, d to,, d aj,i d

1041 4.23 M 0. X 0. X

References: ABC: 309

H: 309 eQq:

Djk: V:

k: 309

I:

A: 309

u:

Nitrobenzene Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz

1041 4. 0, 4^ 3. 0, 3 Ground 8 793. 1.5 309

4, 1, 3^ 3, 1, 2 Ground 9 598. 1.5 309

4, 2, 2^ 3. 2, 1 Ground 9 251. 10. 309

4, 2, 3^ 3, 2. 2 Ground 9 013. 1.5 309

4, 3, 1^ 3, 3, 0 Ground 9 085. 2.5 309

4,

8,

3,

2, 2^ 3. 3.

2,

1 Ground 9 085. 2.5 309 7<- 7. 6 Ground 17 765. 2. 309

8. 3, 6^ 7, 3, 5 Ground 18 239. 6. 309

CO

co_ 4, 5<- 7, 4, 4' Ground 18 239. 6. 309

5. 4^ 7, 5, 3 Ground 18 200. 4. 309

8, 6, 2^ 7, 6, 1 Ground 18 160. 5. 309

8, 6, 3^ 7, 6, 2 Ground 18 160. 5. 309

8, 7, 2-^ 7, 7, 1 Ground 18 142. 4. 309

8, 7, 3^ 7,

8,

7, 2 Ground 18 142. 4. 309

9, 0, 9*- 0, 8 Ground 18 572. 2. 309

10, 2, 8^ 9. 2, 7 Ground 23 985. 3. 309

10, 4. 6<- 9, 4, 5 Ground 22 972. 3. 309

10, 4. 7<- 9, 4, 6 Ground 22 883. 3. -

309

250
1050- Phenol Molcmlar Coiislaiil 'I'uIpIc Carbolic Acid; Hydroxybenzene

CbH^O C, C„H,-,()H

Isotopic Species Ft. Cp.Id. No. A (MHz) B(MHz) C(MHz) D,, D.,K K A

Cs 1051 5 650.46 M 2 619.20 M 1 789.84 M

L -.5704

Id. No. /Xa Debye fjLu Debye /i,. Debye eQq Acc. (iJa d CO,, d CO, d w,i d

1051 1.45' T

1 0. X 1100

1 100.1

1. Ma an<i t^b would be expected to be roughly equal. Since only "b" type transitions have been observed and components of ^ have not been resolved, the total dipole moment

was entered as fl^-

References: ABC: 285 D.,: D,,,- k: 285 A:

/x: 393 eQq: V: 285 I: w:

251
Spectral Line Table

Isotopic Species Trl Rotational V lu. OLalc iiii. rioioi Hyperfine Frecjuency

1 Acc. riei. No. Quantum Nos. State n F' Vr

ITr ivi jnz —IViXlZ

1051 4, 0, 3, 1, 3 Ground 14 733.1 285"

4, 0, 4^ 3, 1

.

3 Ground 14 844.9 285"

4, 1, 4^ 3. 0,

QO Ground 1 / ZOo.o Zoo

4, 1, 4^ 3, 0.

JO Ground 1 7 QAC" 1 1 / OOO.l OOC

1

Z85

5, 0, 5^ 4, 1, 4- Ground 285'

5, 0, 5^^ 4, 1, 4 Ground 19 031.50 285'

5, 1, 5^^ 4, 0, 4 Ground 20 353.2 285'

5, 1, 5-^ 4, 0.

A Ground 20 465.3 285'

5. 4. l'^ 5, 3. z Ground OO QOQ 7 16 6o6. i 285'

5, 4, 1^ 5, 3, o

z Ground IS 494.8 285'

5. 4. 2^^ 5, 3. 3 Ground 23 814.0 285'

5. 4, 2^^ 5, 3, 3 Ground 23 925.5 285'

6, 0, 6^ 5, 1, c0 Ground OO OZ. A 07 zz 854.8/ 285'

6, 0, 6^ 5, 1,

r0 Ground oo ri^7 07 Z2 90 /.O/ 285'

6, 1, 6<— 5. 0,

c0 Ground coo on OOC

1

Zoo

6, 1, 6-<— 5, 0, 5 Ground 23 710.65 285'

6, 4, 2«— 6, 3, 3 Ground 22 689.5 285'

6, 4, 2<- 6, 3,

o0 Ground zz tiUU.O Zoo

6, 4, 3^ 6. 3, 4- Ground 9^ 9 ZD oO i.Z Zoo

6, 4, 3<— 6, 3, Ground oq 07Q A Zoo

7. 0. 7<— 6, 1, 6 Ground 26 623.56 285'

7, 0, 7^ 6, 1, 6 Ground 26 735.31 285'

7, 1. 7-^ 6, 1, 0 Ground ZD WO.ZI Zoo

7, 1, 7^ 6, 1, 0 Ground 07 OQ7 no Zoo

7, 4, 3^ 7, 3.

/I Ground Zl 04D.0 Zoo

-

7, 4, 3*- 7, 3, 4 Ground 21 658.1 285'

7, 4, 4<- 7, 3, 5 Ground 24 095.4 285'

7, 4, 7. 3,

rO Lrround 0/1 OA^; O Z4 ZUO.O 285'

8. 4, 4^ 8, 3.

rD Ground OA OOO C ZU UoZ.o OOC 1 Zoo

8, 4, 4^ 8, 3,

rO Ground OO 1 /I c o ZU 140.0 OOC 1 Z85

8, 4. 5^ 8. 3, 6 Ground 24 604.4 285'

8. 4, 5^ 8. 3, 6 Ground 24 715.9 285'

9, 4, 5^ 9, 3, O Ground 1 O /I /^A C lo 4oU.o OOC 1 Zoo

9, 4, 5^ 9, 3, 0 Ground TO C 70 1 lo 0 (Z.l OOC I Zoo

9. 4. 6^ 9, 3.

"7 Ground Zo 4oy.4 OQCI Zoo

9, 4, 6^ 9, 3. 7 Ground 25 601.4 285'

10, 4, 6^10. 3. 7 Ground 17 284.4 285'

10, 4, 6*-10. 3, 7 Ground 1 7 %<Sf^ 9 1 / oVO.Z ZoO

10, 4, 7^10. 3. Qo Ground 9A Q91 7 ZO oZl. / ZoO

10, 4, 7^10. 3, QO Ground ZO yoz.tt Zf>D

11, 4, 7^11, 3, 8 Ground 16 945.3 285'

11, 4, 7^11, 3, 8 (Ground 17 056.8 285'

11. 4, 8^11, 3, 9 Ground 28 629.7 285'

11. 4, 8^11. 3, Q Gr<>und 98 7A1 9 ZOO

12, 4, 8^12, 3, 9 Ground 17 752.3 285'

12. 4. 8^12. 3. 9 (Ground 17 864.0

1

285'

1. The splitting of each hne in the spectrum is due to internal rotation of the OH group.

252
1060- l-Chloro-3,3-Dimethyl-l-Butyne lVl<il( ( ulai CoiiMjuI 'l al,l<- tert-Butyl Chloroacetylene CeH.Cl C,v(C.,v,C3v,C3v) (CH.,),,CCiCCI

Isotopic Species r t. Gp.

Id. No. A (iVlrlZJ nU.I K A

(C'2H,,).,C'2C'2:C'2Cl-» (C'2H,);,C'2C'2|C'2CF C.,v

1061 1062

891.69 M

868.24 M

891.69 M

868.24 M

References: ABC: 313 D,,: Djk: k: A:

li: eQq: V: I: w:

l-Chloro-3,3-Dimethyl-l-Butyne

Spectral Line Table

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency 1 Acc. 1 Ref. No. Quantum Nos. State n f; F' F MHz 1 ±MHz 1

1061 11, ^10, Ground 19 617.1 .5 [ 313

12, «-ll, Ground 21 400.5 1 -5 313

13, ^12, Ground 23 183.7 .5 313

14, ^13, Ground 24 967.1 .5 313

(C'^HaljC'^C'^lC'^CF 1062 11, ^10, Ground 19 101.2 1 -5 ! 313

12, ^11, Ground 20 837.7 .5

1

1 313

253
1070 - 3,3-Dimethyl-l-Butyne Molecular Constant Table

tert-Butyl Acetylene

C„H,„ C;,v(C:,v,C:,v,C,iv) (CH^ljCClCH

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) K A

(C''^H3):iC'-C'^:C''^H 1071 2 683.18 M 2 683.18 M

(C'-HajsC'^C'^iC'^D 1072 2 531.09 M 2 531.09 M

(C'^H3)3C'2C'2iC'''H Cyv 1073 2 609.35 M 2 609.35 M

(C'2H.)):jC'2C"!C'^H C:,v 1074 2 665.90 M 2 665.90 M

(C'^H.,),,C'^C'2!C'-'D C;,v 1075 2 467.53 M 2 467.53 M

C:,v 1076 2 516.83 M 2 516.83 M

C'''H3(C'2H:,)2C'2C''^!C'2H Cs 1077 2 672.45 M 2 643.36 M

C'^HalC'^ROjC'-C'^iC'-D c. 1078 2 520.65 M 2 494.72 M

Id. No. /Lia Dehye IJ.U Debye /Xi- Debye eQq V:, Acc. I,.e„ Wa d CO], d u>,. d o),, d

1071 0.661 M 0. X 0. X

1 4000 183 1

References: ABC: 313, 353 ' Dj: Djk: k: A:

fj.: 353 - eQq: V: 353 I: o,- 353

Rotational constants (Bv) for various excited vibrational modes: t^: 2682.05 MHz, 7^: 2681.67 MHz, and (3^: 2685.77 MHz. Ref: 353.

254
3,3-Dimethyl-l-Butyne Spectral Line Table

Isotopic Species Id. Rotational Vib. State

1 Int. Rotor Hyperfine

1 1 1

1 Frequency | .'Kcc. | Ref. No. Quantum Nos. State n F/ 1 F' F, F ! MHz 1 ±MHz 1

1071 2, *- 1, (iround 1 10 732.9 1 .1 1 353

3, <- 2, Ciround 16 099.3 i .1 1 353

4, <— 3, Ground 21 453.5 1 .1 1 353

4! <- 3I Ground 21 4.56.4 1 .1 1 353

4, *- 3, Ground 21 465.5 1 .1 1 3.53

4, <- 3, 1, 0

1 21 486.4 1 .1 1 353

4, 1<- 3, 1 1,+ 1 21 499.7 i .1 1 3.53" 4, 1<- 3, 1 Ground 21 446.0 1 .1 1 Q C Q 1

5, <- 4, Ground 26 816.8 1 .1 1 3.53

5. <- 4, Ground 26 820.4 1 .1 353

5, <- 4, Ground 26 831.9 .1 1 353

5, 4, 1, 0 zo 00/. ( 1 .1 j 353

5, 1<- 4, 1 1,+ 1 26 874.5 .1 1 Qc:q 1

5, l-«- 4, 1 Ground 26 807.3 1 .1 353'

6, *- 5, Ground 32 179.8 1 .1 3.53

6, <- 5, Ground 32 184.3 1 .1 I 353

6, 5, 1, 0 32 229.0 .1 3.53

6, ^ 5, Ground 32 198.0 .1 000

6, 1«- 5, 1 1,+ 1 32 249.5 .1 353'

6, 1«- 5, 1 Ground 32 168.4 .1 353'

1072 4. ^ 3, Ground 20 248.8 ! .1 0 C Q

5, <- 4, Ground 25 310.9 .1 353

6, <- 5, Ground 30 373.0 1 .1 353

(C'^H3)3C'^C'^ = C'^H 1073 4. 3, Ground 20874.9 1 .1 0 c 0

5, <- 4. Ground 26 093.5 1 .1 353

6, «- 5, Ground 31 312.1 1 .1 353

//~'19TT \ /~'I9/~'I't«/~'1'?II (C'^H3)3C'^C'':C'^H 1074 4, 3. Ground 21 327.2 i .1 000

5, <- 4, Ground 26 659.1 .1 353

6, «- 5, Ground 31 990.5 .1

1

353

(C'^H3)3C'^C'^!C'-'D 1075 4, <- 3, Ground 19 740.3 1 .1 5, 4, Ground 24 675.4 .1 353

6, «- 5, Ground 29 610.2 .1 353

(C'2H3)3C'^C'':C'^D 1076 4, «- 3, Ground 20 134.6 1 .1 600

5, 4, Ground 25 168.2 .1 353

6, ^ 5, Ground 30 201.9 .1 353

C'-''H3(C'2H3)2C'2C'2|C'2H 1077 4, 1, 3^ 3, 1, 2 Ground 21 320.8 1 .1 353

4, 1, 4^ 3, 1, 3 Ground 21 204.4 1 .1 353

5. 1. 4-^ 4, 1, 3 Ground 26 650.1 1 .1 0 C 3 000

5, 1, 5^ 4. 1. 4 Ground 26 504.7 .1 353

6, \. 5^ 5. 1. 4 Ground 31 979.1 1 .1

6, 1, 6^ 5, 1, 5 Ground 31 804.5 1 .1 353

C'''H3(C'^H3)2C'2C''^lC'2D 1078 4, 1, 3<- 3, 1, 2 Ground 20 112.4 1 .1 353

4, 1, 4-^ 3, 1, 3 Ground 1 20 009.0 1 .1 353

5, 1, 4-^ 4, 1, 3 Ground 1 25 140.6 1 .1 0 C Q

5, 1, 5^ 4. 1, 4 (iround 25 010.9 .1 353

6, 1, 5«- 5, 1. 4 Ground 30 167.8 1 .1 353

1 6. 1. 6^ 5. 1. 5 (iround ]

1 30 012.2 1 .1 353

1. Strong satellites of the J = 4'*—3, S*—4, 6<—5 lines were assigned by Nugent, Mann, and Lide to the lowest lying vibrational slates, two of these being assigned to the degenerate

skeletal bending mode which is the lowest Raman band, identified at 183 cm"'. The weaker of these lines was assigned to the /-type doublet K = + 1. / = + 1. /-type doubhng was

also assigned for hnes in the first excited torsional mode, a similar pattern to that for the bending mode having been observed. These were assigned toK = — 1,/ = — 1. The other components of the doublets are not resolved because of overlapping by unidentified vibrational satellites.

255
1080 - Trimethylamine-Trimethylborane Molecular Constant Table

C3v,C3v) (CH3)3N • B(CH3)3

Isotopic Species Pt. Gp.Id. No. A (MHz) B(MHz) C(MHz) K A

(C'2H3)3N'^-B>'(C'^H3)3 C3V 1081 1 573.7 M 1 573.7 M

Id. No. /Xa Debye /j-h Debye Debye eQq V Acc. I red (1)^ d oti, d CD,, d (o^ d

1081 3.92 L 0. X 0. X

References: ABC: 256 ix: 364

Add. Ref.: 301

Trimethylamine-Trimethylborane Spectral Line Table

Isotopic Species 1 Id. 1 Rotational Vib. State Int. Rotor Hyperfine Frequency j Acc. j Ref.

1 No. 1 Quantum Nos. j State n | . \' F' 1 F, 1 F MHz 1 ±MHz 1

(C'2H3)3N'-'-B"(C'-H3)3 1081 1 6. ^ 5. 1 1 1 18 884. 10. I 256

7, ^ 6, 1 1 1 22 039. 10. 1 256

8, *- 7,

!

' 1 25 179. 10. 256

9. *- 8, 1 J \ 1

— i i

28 318. 10. 1 J I 256

256
1090 - Ethynylbenzene Molecular (>)nstanl Tahle

Phenylacetylene; Phenylethyne

Isotopic Species Pt. Gp:

Id. No. A (MHz) B(MHz) C(MHz) D,, D.,K K A

1091 5 662.86 M 1 530.09 M 1 204.38 M -.8539 .80

Id. No. /u-a Debye fih Debye fii- Debye eQq V Ace. I red tOa d a>b d (0,. d w,i d

1091 0.78 T 0. X

L_ .

References: ABC: 313 k: 313 A: 338 /x: 395

Ethynylbenzene „ , , . rw> , ^ spectral Line 1 able

Isotopic Species Id. Rotational Vib. State Int. Rotor Hyperfine Frequency Acc. j Ref. No. Quantum Nos. State n f; F' F, F MHz ±MHz 1

1091 8, 3, 6^ 7, 3, 5 Ground 22 023.6 .5 1 313

8, 4, 4^ 7. 4, 3 Ground 22 009.5 .5 313

8, 4, 5^ 7, 4, 4 Ground 22 003.4 .5 1 313

8, 5, 3^ 7, 5, 2 Ground 21 966.7 .5 313

8, 5, 4^ 7, 5, 3 Ground 21 966.7 .5 313

8, 6, 2^ 7, 6, 1 Ground 21 945.9 .5 i 313

8, 6, 3^ 7, 6, 2 Ground 21 945.9 .5 1 313

8, 7, 1^ 7, 7, 0 Ground 21 933.8 .5 313

8, 7, 2^ 7, 7, 1 Ground 21 933.8 .5 313

9, 4, 5^ 8, 4, 4 Ground 24 796.4 .5 313

9, 5, 4^ 8, 5, 3 Ground 24 732.1 .5 j 313

9, 5. 5^ 8, 5, 4 Ground 24 732.1 .5 313

9, 6, 3^ 8, 6, 2 Ground 24 702.7 .5 j 313

9, 6, 4<- 8, 6, 3 Ground 24 702.7 .5 313

9, 7, 2^ 8, 7, 1 Ground 24 685.6 .5 1 313

9, 7, 3^ 8, 7, 2 Ground 24 685.6 .5 1 313

9, 8, 1^ 8, 8, 0 Ground 24 674.5 .5 313

1 9,

1

8, 2«- 8, 8, 1 Ground !

i

24 674.5 .5 1

\

313

257
5. Index According to Empirical Formula

Formula Id. No. Page Formula Id. No. Page Inorganic

F2O2 10 F4N2 20 HNO3 30 H2O2 40 H4N2 50 Organic

CFsS 60 CH2O2 70 CH3ASF2 80 CH3BF2 90

CH.3Cl.,Ge 100

CH.3Cl3Si 110 CHaFjGe 120 CHaFaSi 130 CH3NO 140 CH3NO 150 CH3NO2 170 CH3NO3 180 CH4F2Si 190 CH40 210 CH4S 220 CHsClSi 230 CHsFSi 240 CH,,N 260 CH5P 270 CHeGe 280 CHsSi 310 CHsSn 340 CiH^BrO 350 C2H3CIO 360 C2H3CI3 380 C2H3FO 390 C2H3F3 410 C2H3NS 420 C2H,3NS 430 C2H4CIF 440 C2H4CI2 450 C2H4F2 460 C2H40 470 C2H4O2 490 C2H4O2 500 C2H5Br 520 C2H5CI 540 C2H5F 550 C2H51 570 C2H60 580 CzHeO 590

134

610

16

17

213132

3334

34

3640

4349

5156

65

717680

92

9397

100

101 106

118

119

124

126

127 128

129

130

132 138

141 145

151

1.58 162 165 166

Organic (continued)

CzHeS 600 171 CjHeSi 610 177 C2H7N 630 180 CiHsSi 640 181 C2H8Si 650 184 C.,H3F304 660 184 C3H3NO 670 185 C3H40 680 190 C3H40 690 191 C3H5F 700 192 C3H5F 710 194 C3H5F 720 196 C3H5N 730 199 CjHe 740 201 C3H60 750 203 C3H60 760 205 C3H7CI 770 214 C3H8 780 216 C3H9AS 790 218 C3H9BF3N 800 219 CaHsBrSi 810 220

C:,H9ClSi 820 221 CaHaFSi 830 222 C^HJSi 840 223 CHaN 850 224 C3H9P 860 225

C3H,oSi 870 226 C4H3F3 890 228

C4H.,C1 900 230 C4H5F 910 232 C4H5N 920 234 C4H6 930 235 C4H8 940 236 C4H80 950 239 C4H9Br 960 240 C4H9CI 970 242 C4H9F 980 244 C4H91 990 246

C4H,o 1000 247 C4H,oO 1010 248 C5H9N 1020 249 C5H9N 1030 2.50 C6H5NO2 1040 250 CeHeO 1050 251 C6H9CI 1060 253 CsHio 1070 254 CeH.sBN 1080 256 CgHs 1090 257

258
6. Index According to Chemical Name

Name Id. No. Page A

Acetaldehyde 470 1.12 Acetic Acid 490 138 Acetone 750 203 Acetyl Bromide 350 101 Acetyl Chloride 360 106 Acetyl Cyanide 670 185 Acetyl Fluoride 390 119

s-trare5-Acrolein 690 191 Acrylaldehyde (see 5-fra/w- Acrolein) 690 191 Acrylic Aldehyde (see 5-tran5- Acrolein) 690 191 Aminoethane (see Ethylamine) 630 180 Aminomethane (see Methylamine) 260 80 B

Bromoethane 520 145 2-Bromo-2-methylpropane 960 240

1, 2-Butadiene 930 235

«rans-2-ButenenitriIe 920 234 C

Carbolic Acid (see Phenol) 1050 251 l-Chloro-2-butyne 900 230

l-Chloro-3, 3-dimethyl-l-butyne 1060 253 Chloroethane 540 151

1-Chloro-2-fluoroethane 440 128

2-Chloro-2-methylpropane 970 242

Chloromethylsilane 230 71 Chloromethylsilicane (see Chloromethylsilane)... 230 71 1-Chloropropane 770 214

frarei-Crotonic Nitrile (see irani-Crotononitrile)... 920 234

trans-Crotononitrile 920 234 D

1, 2-Dichloroethane 450 129

Diethyl Ether 1010 248

1, 1-Difluoroethane 460 130

1, l-Dimethyl-3-butyne 1070 254 Dimethyl Ether (see Methoxymethane) 590 166 a,a-Dimethylethyl Carbylamine (see tert-Bulyl Isocyanide) 1030 250

Dimethyl Ketone (see Acetone) 750 203 Dimethylmethane (see Propane) 780 216

2, 2-Dimethylpropanenitrile 1020 249

a,a-Dimethylpropionitrile (see 2, 2-Dimethylpropanenitrile) 1020 249 Dioxygen Difluoride 10 1 Dimethylsilane 640 181 Dimethylsilicane (see Dimethylsilane) 640 181 Dimethyl Sulfide 600 171 E

cis-2, 3-Epoxybutane 950 239

1, 2-Epoxypropane 760 205 Ethanal (see Acetaldehyde) 470 132 Ethanoic Acid (see Acetic Acid) 490 138 Ethanol 580 165

Name id. No, Pa«e

Ethanoyl Bromide (see Acetyl Bromide) 350 101 Ethanoyl Chloride (see Acetyl Chloride) 360 106 Ethanoyl Fluoride (see Acetyl Fluoride) 390 119

Ethenesilicane (see Vinyl Silane) 610 177 Ethoxyethane 1010 248

Ethyl Alcohol (see Ethanol) 580 165 Ethyl Bromide (see Bromoethane) 520 145

Ethyl Chloride (see Chloroethane) 540 151 Ethyl Cyanide (see Propionitrile) 730 199

Ethyl Fluoride (see Fluoroethane) 550 158

Ethyl Iodide (see lodoethane) 570 162 Ethylamine 630 180 Ethylene Silane (see Vinyl SUane) 610 177

Ethylsilane 650 184

Ethylsilicane (see Ethylsilane) 650 184 Ethynylbenzene 1090 257

F

2-Fluoro-l, 3-butadiene 910 232 Fluoroethane 550 158 2-Fluoro-2-methylpropane 980 244

Fluoroprene (see 2-Fluoro-l, 3-butadiene) 910 232 2-Fluoropropene 720 1%

ct5- 1-Fluoropropene 700 192 trans-Fluoropropene 710 194 2-Fluoropropylene (see 2-Fluoropropene) 720 196

c/s-a-Fluoropropylene (see cis- l-Fluoropropene)... 700 192 irans-Fluoropropylene (see fra/is-Fluoropropene)... 710 194 Formaldehyde Oxime (see Formaldoxime) 140 36 Formaldoxime 140 36 Formamide 150 40

Formic Acid 70 17 Formoxime (see Formaldoxime) 140 36 H

Hydrazine 50 10 Hydrogen Peroxide 40 6 Hydroxybenzene (see Phenol) 1050 251

I

lodoethane 570 162 2-Iodo-2-methylpropane 990 246

Isobutane (see 2-Methylpropane) 1000 247

Isobutylene (see 2-Methylpropene) 940 236

Isopropenyl Fluoride (see 2-Fluoropropene) 720 196 M

Methanamide (see Formamide) 150 40

Methanethiol 220 65 Methanoic Acid (see Formic Acid) 70 17 Methanol 210 56 Methoxymethane 590 166 Methyl Alcohol (see Methanol) 210 56

Methylallene (see 1, 2-Butadiene) 930 235 Methylamine 260 80 Methylchloroform (see 1, 1, l-Trichloroethane)... 380 118

259
6. Index According to Chemical Name (continued)

Name Id. No. Page

Methyldifluoroarsine 80 21 Methyldifluoroborane 90 31 Methyldifluorosilane 190 51 Metliyldifluorosilicane (see Methyldifluorosilane) 190 .51 Methyl Ethenone (see Methyl Ketene) 680 190 Methyl Ether (see Methoxymethane) 590 166 Methylethylene (see Propene) 740 201 Methyl Fluoroform (see 1, 1, l-Trifluoroethane)... 410 124 Methyl Formate 500 141 Methylgermane 280 9,3 Methyl Isothiocyanate 420 126 Methyl Ketene 680 190 Methyl Mercaptan (see Methanethiol) 220 65 Methyl Methanoate (see Methyl Formate) 500 141 Methylmonofluorosilane 240 76 Methylmonofluorosilicane (see Methylmonofluorosilane) 240 76 Methyl Nitrate 180 49 Methyloxirane (see 1, 2-Epoxypropane) 760 205 Methylphosphine 270 92 2-Methylpropane 1000 247 2-Methylpropene 940 236

Methylsilane 310 97

Methylsilicane (see Methylsilane) 310 97 Methylstannane 340 100 Methyl Nitrate 180 49 Methyl Sulfocyanate (see Methyl Thiocyanate)... 430 127 Methyl Thiocyanate 430 127 Methylthiomethane (see Dimethyl Sulfide) 600 171 Methyltin (see Methylstannane) 340 100 Methyltrichlorogermane 100 32 Methyhrichlorosilane 110 33 Methyltrifluorogermane 120 34

Methyltrifluoromethylacetylene (see 1, 1, 1-Tri- fluoro-2-butyne) 890 228

Methyhrifluorosilane 130 34

Methyltrifluorosihcane (see methyhrifluorosilane) 130 34

N

Nitric Acid 30 4 Nitrobenzene 1040 2.50 Nitromethane 170 43

O

2-Oxopropanenitrile (see Pyruvonitrile ) 670 185

P

Phenol 1050 251 Phenylacetylene (see Phenylethyne) 1090 257 Phenylethyne 1090 257 Propane 780 216

Propanenitrile (see Propionitrile) 730 199 2-Propanone (see Acetone) 750 203 Propenal (see s-trans- Acrolein) 690 191 Propene 740 201 Propene Oxide (see 1, 2-Epoxypropane) 760 205

Name id. No. Page

iraras-Propenyl Cyanide (see trans-2-Hutenenitrile) 920 2.34 ci5-Propenyl Fluoride (see cis-l-Fluoropropene)... 700 192 trani-Propenyl Fluoride (see iraras-Fluoropro- pene) 710 194 ) Propionitrile 730 199

n-Propyl Chloride (see 1-Chloropropane) 770 214 , Propylene (see Propene) 740 201 | Propylene Oxide (see 1,2-Epoxypropane) 760 205

Pyruvonitrile 670 185 , T i

ierf-Butyl Acetylene (see 1, l-Dimethyl-3- 1 butyne) 1070 254

tert-Butyl Bromide (see 2-Bromo-2-methylpropane) 960 240

(erf-Butyl Chloride (see 2-Chloro-2-methylpropane) rTrr.Tr. -97t) 242

terf-Butyl Cyanide (see 2, 2-Dimethyl Propanenitrile) 1020 249

ferf-Butyl Chloroacetylene

(see l-Chloro-3, 3-Dimethyl-l-Butyne) 1060 253

j tert-Butyl Fluoride

j (see 2-Fluoro-2-methylpropane) 980 244 ; fert-Butyl Iodide (see 2-Iodo-2-methylpropane)... 990 246 I fert-Butyl Isocyanide 1030 250

Tetrafluorohydrazine 20 3 Tribromosilane 810 220

1. 1, 1-Trichloroethane 380 118

Trifluoroacetic Acid-Formic Acid Complex 660 184 Trifluoroborane-Trimethylamine 800 219

1, 1, l-Trifluoro-2-butyne 890 228

1, 1, l-Trifluoroethane 410 124

Trifluoromethyl Sulfur Pentafluoride 60 16 Trimethylacetonitrile

(see 2, 2-Dimethyl Propionitrile) 1020 249 Trimethylamine 850 224

Trimethlyamine-trimethylborane 1080 2.56 Trimethylarsine 790 218 Trimethylbromoethane

(see 2-Bromo-2-methylpropene) 960 240

Trimethylbromosilane 810 220

Trimethylbromosilicane 810 220 Trimethylchloromethane

(see 2-Chloro-2-methylpropene) 970 242

Trimethylchlorosilane 820 221 Trimethyichlorosilicane

(see Trimethylchlorosilane) 820 221 Trimethylfluoromethane

(see 2-Fluoro-2-methylpropane) 980 244

Trimethylfluorosilane 830 222

Trimethylfluorosilicane

(see Trimethylfluorosilane) 830 222 Trimethyliodomethane

(see 2-Iodo-2-methylpropane) 990 246

Trimethyliodosilane 840 223

Trimethyliodosilicane

(see Trimethyliodosilane) 840 223 Trimethylmethane (see 2-Methylpropane) 1000 247 Trimethylphosphine 860 225

Trimethylsilane 870 226

Trimethylsihcane (see Trimethylsilane) 870 226

260
7. Bibliography

[1] H. Eyring, J. Am. Chem. Soc. S4,3191 (1932).

[2] J. B. Howard, Phys. Rev. 51, 53 (1937).

[3] E. Gorin, J. Walter, and H. Eyring, J. Am. Chem. Soc. 61,

1876(1939).

[4] G. L. Lewis and C. P. Smyth, J. Chem. Phys. 7, 1085 (1939).

[5] B. L. Crawford, J. Chem. Phys. 8, 744L (1940).

[6] J. S. Koehler and D. M. Dennison, Phys. Rev. 57, 1006

(1940).

[7] A. Langseth and H. J. Bernstein, J. Chem. Phys. 8,410

(1940).

[8] G. Glockler and C. Sage, J. Chem. Phys. 9, 387 (1941).

[9] K. S. Pitzer, J. Chem. Phys. 10,605L (1942).

[10] W. D. Hershberger, J. Appi. Phys. 17 (1946).

[11] J. E. Waher and W. D. Hershberger, J. Appl. Phys. 17,

814 (1946).

[12] B. P. Dailey, Phys. Rev. 72, 84 (1947).

[13] B. P. Dailey and E. B. Wilson, Phys. Rev. 72,522(1947).

[14] W. D. Hershberger and J. Turkevich, Phys. Rev. 71, 554

(1947). [15] C. H. Millar, Thesis, McGill U. (1947).

[16] C. I. Beard and B. P. Dailey, MITRLE Tech. Rep. #79

(1948). [17] D. K. Coles, Phys. Rev. 74, 1194 (1948).

[18] W. F. Edgell and A. Roberts, J. Chem. Phys. 16, 1002

(1948). [19] B. Bak, E. S. Knudsen, and E. Madsen, Phys. Rev. 75,

1622L (1949).

[20] C. I. Beard and B. P. Dailey, J. Am. Chem. Soc. 71, 929

(1949). [21] B. P. Dailey, R. G. Shulman, and H. Minden, Phys. Rev. 75, 1319A (1949).

[22] H. D. Edwards, O. R. Gilliam, and W. Gordy, Phys. Rev. 76, 196A (1949).

[23] G. H. Millman and R. C. Raymond, J. Appl. Phys. 20,413

(1949).

[24] D. K. Coles, W. E. Good, and R. H. Hughes, Phys. Rev. 77,

741 A (1950).

[25] B. Girdwood, Can. J. Res. 28, 180 (1950).

[26] H. S. Gutowsky and H. B. Levine, J. Chem. Phys. 18 (1950).

[27] J. O. Halford, J. Chem. Phys. 18, 361 (1950).

[28] D. R. Lide, Jr., and D. K. Coles, Phys. Rev. 80, 911 (1950).

[29] H. T. Minden, J. M. Mays, and B. P. Dailey, Phys. Rev. 78,

347 (1950).

[30] J. R. Nielsen, H. H. Claassen, and D. C. Smith, J. Chem.

Phys. 18, 1471 (1950).

[31] W. J. Pietenpol. J. D. Rogers, and D. Williams, Phys. Rev. 78, 480L (1950).

[32] J. Sheridan and W. Gordy, Phys. Rev. 77, 719L (1950).

[33] J.Q. Williams and W. Gordy, J. Chem. Phys. 18,994(1950).

[34] Tang Au-Chin, J. Chinese Chem. Soc. 18, 1 (1951).

[35] D. G. Burkhard and D. M. Dennison, Phys. Rev. 84, 408

(1951).

[36] R. Freymann, Physica 17, 328 (1951).

[37] R. H. Hughes, W. E. Good, and D. K. Coles, Phys. Rev. 84,

418 (1951).

[38] F. K. Hurd and W. D. Hershberger, Phys. Rev. 82, 95L

(1951).

[39] C. K. Jen, Phys. Rev. 81, 197 (1951).

[40] D. R. Lide, Jr., J. Chem. Phys. 19, 1605 (1951).

[41] C. C. Loomis and M. W. P. Strandberg, J. Phys. Chem. 81,

798 (1951).

[42] N. W. Luft, Disc. Faraday Soc. 10, 117 (1951).

[43] H. T. Minden and B. P. Dailey, Phys. Rev. 82,338A (1951).

[44] L. J. Oosterhoff, Disc. Faraday Soc. 10, 79 (1951).

[45] K. Pitzer, Disc. Faraday Soc. 10,66(1951).

[46] J. D. Rogers and D. Williams, Phys. Rev. 83,210A (1951).

[47] T. M. Shaw and J. J. Windle, J. Chem. Phys. 19, I063L

(1951). [48] J. Sheridan and W. Gordy, J. Chem. Phys. 19, 965 (1951).

[49] J. G. Aston, Disc. Faraday Soc. 10, 73 (1952).

[50] F. H. Branin and C. P. Smyth, J. Chem. Phys. 20, 1121

(1952). [51] B. P. Dailey, Annals, N.Y. Acad. Sci. 55, 915 (1952).

[.52] G. Erlandsson, Ark. Fys. 6, 69 (1952) (Paper 7). [53] S. N. Ghosh, R. Trambarulo, and W. Gordy, J. Chem. Phys.

20, 605 (1952).

[54] E. V. Ivash, Diss. Abstr. 12, 483 (1952).

[55] P. Kisliuk and G. A. Silvey, J. Chem. Phys. 20, 517 (19,52). [56] D. R. Lide, Jr., J. Chem. Phys. 20, 1812 (19.52). [57] J. T. Massey and D. R. Bianco, Phys. Rev. 85, 717 (19.52). [58] R. Mockler, J. H. Bailey, and W. Gordy, Phys. Rev. 87, 172

(1952).

[59] D. C. Smith and R. A. Saunders, J. Chem. Phys. 20, 847

(1952).

[60] A. V. Stuart and G. B. B. M. Sutherland, J. Chem. Phys. 20,

1977 (1952).

[61] J. Van Dranen, J. Chem. Phys. 20, 1982 (1952).

[62] T. L. Weatherly and D. Williams, J. Chem. Phys. 20, 755

(1952). [63] F. A. Andersen, B. Bak, and J. Rastrup-Andersen, Acta Chem. Scand. 7, 643 (1953).

[64] F. Andersen, J. Rastrup-Andersen, B. Bak, O. Bastiansen,

E. Risberg, and L. Smedvik, J. Chem. Phys. 21, 373

(1953). [65] B. Bak, L. Hansen, and J. Rastrup-Andersen, J. Chem.

Phys. 21,1612(1953).

[66] B. P. Dailey, G. K. Fraenkel, and R. S. Halford, Crystal

Chem. Phys. Qtrly. Columbia U. Rep. 7, Aug. -Oct.

(1953), Contr. DA 36-039-SC-15472.

[67] G. Erlandsson, Ark. Fys. 6, 491 (19.53). [68] F. E. Harris and B. J. Alder, Nature 172, 774 (1953).

[69] W. H. Haynie and R. R. Nielsen, J. Chem. Phys. 21, 1839

(1953).

[70] B. L. Hicks and T. E. Turner, BRL Memo rept. no. 703, Aug.

(1953).

[71] E. V. Ivash and D. M. Dennison, Phys. Rev. 89, 895 (1953).

[72] E. V. Ivash and D. M. Dennison, J. Chem. Phys. 21, 1804

(1953).

[73] Krishnaji and P. Swarup, J. Appl. Phys. 24, 1525 (1953).

[74] D. R. Lide, Jr., J. Chem. Phys. 21, 571 (1953).

[75] J. H. N. Loubser, J. Chem. Phys. 21, 2231 (1953).

[76] N. W. Luft, J. Chem. Phys. 21, 179 (1953).

[77] N. W. Luft and K. H. Todhunter, J. Chem. Phys. 21, 2225

(1953).

[78] N. W. Luft, Trans. Faraday Soc. 49, 118(1953).

[79] R. C. Mockler, J. H. Bailey, and W. Gordy, J. Chem. Phys.

21, 1710 (1953).

[80] R. C. Mockler and W. Gordy, Phys. Rev. 91,222 (1953).

[81] G. W. Robinson and C. D. Cornwell, J. Chem. Phys. 21,

1436 (1953).

[82] K. Shimoda and T. Nishikawa, J. Phys. Soc. Japan 8, 133

(1953).

[83] K. Shimoda and T. Nishikawa. J. Phys. Soc. Japan 8, 425

(1953). [84] N. Solimene and B. P. Dailey, Phys. Rev. 91, 464 (1953).

[85] M. C. Tobin, J. Am. Chem. Soc. 75, 1788(1953).

[86] Tang Au-Chin, Sci. Sinica 3, 279 (1954).

[87] B. P. Dailey, Columbia U. Final Rep. AD-62019 (1954).

[88] R. C. Gunton, J. F. OUom, and H. N. Rexroad, J. Chem.

Phys. 22, 1942 (1954).

[89] A. Jache, G. Blevins, and W. Gordy, Phys. Rev. 95, 299A

(1954).

749-587 0-69— 18 261
[90] D. Kivelson, J. Chem. Phys. 22, 1733 (1954).

[91] D. R. Lide, Jr., J. Chem. Phys. 22, 1613 (1954).

[92] N. W. Luft. J. Chem. Phys. 22, 1814 (1954).

[93] J. T. Massey and D. R. Bianco, J. Chem. Phys. 22 , 442

(1954).

[94] M. Matricon and M. Bonnet, J. Phys. Radium 15, 647

(1954).

[95] H. T. Minden, Diss. Abstr. 14, 1563 (1954).

[96] K. Shimoda, T. Nishikawa, and T. Itoh, J. Chem. Phys. 22,

1456 (1954).

[97] K. Shimoda, T. Nishikawa, and T. Itoh, J. Phys. Sec. Japan 9, 974 (1954).

[98] N. Solimene and B. P. Dailey, J. Chem. Phys. 22, 2042

(1954).

[99] E. Tannenbaum, R. D. Johnson, R. J. Myers, and W. D. Gwinn, J. Chem. Phys. 22,949(1954).

[100] R. Trambarulo and P. M. Moser, J. Chem. Phys. 22, 1622

(1954). [101] R. S. Wagner and B. P. Dailey, J. Chem. Phys. 22, 14.59 (1954). [102] A. I. Barchukov, T. M. Minaeva, and A. M. Prokhorov,

Zhur. Eksptl. i Teoret. Fiz 29,892 (1955). [103] J. Fine, J. H. Goldstein, and J. W. Simmons, J. Chem. Phys.

23, 601 (1955). [104] R. C. Gunton, J. F. Ollom, and H. N. Rexroad, W. Va. U.

Final Rept. (1953-1955), Contr. DA-36-061-ORD-392.

[105] E. V. Ivash, J. C. M. Li, and K. S. Pitzer, J. Chem. Phys.

23, 1814 (1955). [106] R. W. Kilb, J. Chem. Phys. 23, 1736 (1955). [107] T. Kojima and T. Nishikawa, J. Phys. Soc. Japan 10, 240

(1955). [108] J. Kraitchman and B. P. Dailey, J. Chem. Phys. 23, 184

(1955). [109] R. J. Kurland, J. Chem. Phys. 23, 2202 (1955). [110] R. G. Lerner, J. P. Friend, and B. P. Dailey, J. Chem. Phys.

23, 210 (1955). [Ill] D. R. Lide, Jr., Private communication 12-7-55.

[112] D. R. Lide, Jr., and D. Kivelson, J. Chem. Phys. 23, 2191

(1955). [113] N. W. Luft, Z. Elektrochem. 59, 46 (1955). [114] E. A. Mason and M. M. Kreevoy, J. Am. Chem. Soc. 77,

5808 (1955). [115] J. T. Massey and R. W. Hart, J. Chem. Phys. 23,942(1955).

[116] R. E. Naylor, Jr., Thesis, Harvard U. (1955). [117] T. Nishikawa, T. Itoh, and K. Shimoda, J. Chem. Phys. 23,

1735 (1955). [118] T. Sidei and S. Yano, J. Chem. Phys. 23, 1554 (1955). [119] N. Solimene and B. P. Dailey, J. Chem. Phys. 23, 124

(1955). [120] J. D. Swalen, J. Chem. Phys. 23, 1739 (1955). [121] P. Venkataswarlu, H. D. Edwards, and W. Gordy, J. Chem.

Phys. 23, 1195 (1955). [122] P. Venkataswarlu and W. Gordy, J. Chem. Phys. 23, 1200

(1955). [123] R. S. Wagner and B. P. Dailey, J. Chem. Phys. 23, 1355

(1955). [124] R. S. Wagner, N. Solimene, and B. P. Dailey, J. Chem.

Phys. 23, 599 (1955). [125] E. G. Wilson. C. C. Lin, and D. R. Lide, Jr., J. Chem. Phys.

23, 136 (1955). [126] B. Bak, J. Chem. Phys. 24, 918 (1956). [127] A. I. Barchukov, T. M. Minaeva, and A. M. Prokhorov,

Sov. Phys. JETP 2, 760 (1956). [128] D. G. Burkhard, Trans. Faraday Soc. 52, 1 (1956). [129] H. Cohn, C. K. Ingold, and H. G. Poole, J. Chem. Phys. 24,

162 (1956).

130

131 132

133 134

135

136

137

138

139 140

141 142

143 144

145

146

147 148

149

150

151

152

153 154

155

156

157

158

159

160

161

162

163 164

165

166

167

168

169

170

171

172 173

[174]

T. P. Das, J. Chem. Phys. 25, 379 (1956). G. Erlandsson, J. Chem. Phys. 25, 379 (1956). R. C. Ferguson, Thesis, Harvard U. (1956). H. G. Fitzky, H. Happ, Z. Naturforsch. 11a, 957 (1956). R. C. Gunton and J. F. Ollom. W. Va. U. Final Rept. (1955-

1956), Contr. DA-36-061-ORD-511.

J. S. Heeks, L. F. Thomas, and J. Sheridan, Private communication, 7-4-56, J. Sheridan.

J. S. Heeks, L. F. Thomas, J. Sheridan, Private communication, 7-4-56, J. Sheridan.

D. R. Herschbach, Chem. Phys. 25 , 358 (1956). H. Hirikawa, A. Miyahara, and K. Shimoda, J. Phys. Soc. Japan 11, 334 (1956). T. Itoh, J. Phys. Soc. Japan 11, 264 (1956). R. W. Kilb, Private Communication (1956). R. W. Kilb, Thesis, Harvard U. (1956). R. J. Kurland, Bull. Am. Phys. Soc. Ser. II, 1, 12 (1956).

J. C. M. Li and K. S. Pitzer, J. Phys. Chem. 60, 466 (1956). C. C. Lin and R. W. Kilb, J. Chem. Phys 24, 631 (1956).

J. H. N. Loubser, Private communication 2-20-56.

A. A. Maryott and G. Birnbaum, J. Chem. Phys. 24, 1022

(1956). D. J. Millen and J. R. Morton, Chem. and Ind. 954 (1956). T. Nishikawa, J. Phys. Soc. Japan 11, 781 (1956).

J. F. Ollom, A. A. Sinisgalli, H. N. Rexroad, and R. C. Gunton, J. Chem. Phys. 24, 487 (1956). L. Pierce, Bull. Am. Phys. Soc. Ser. II, 1, 198 (1956). L. Pierce, Abst. for Columbus Symposium on Spectroscopy

(June, 1956). H. N. Rexroad, D. W. Howgate, R. C. Gunton, and J. F. Ollom, J. Chem. Phys. 24, 625 (1956). K. M. Sinnott, Bull. Am. Phys. Soc. 2, 1, 198 (1956).

J. D. Swalen, Abst. for Columbus Symposium on Spectros- copy (June, 1956). E. Tannenbaum, R. J. Myers, and W. D. Gwinn, J. Chem.

Phys. 25, 42 (1956). R. Wertheimer, Compt. rend. 242, 243 (1956). R. Wertheimer, Compt. rend. 242, 1591 (1956). W. von Zeil, Elektrochem 60, 752 (1956). W. von Zeil, Z. Elektrochem 60, 1204 (1956). W. von Zeil, Z. Naturforsch. 11a, 677 (1956). A. I. Barchukov, T. M. Murina, and A. M. Prokhorov,

Fizicheskii Sbornik III. Tom I., 75 (1957). B. Bak, Hansen-Nygaard, and E. Tannenbaum, J. Chem.

Phys. 26, 241 (1957). G. Birnbaum, J. Chem. Phys. 27, 360 (1957). A. Budzanowiski, K. Grotowski, J. A. Janik, W. Kolos,

F. Maniawski, H. Rzany, A. Szkatula, and A. Wanic,

Acta Phys. Polon. 16, 335 (1957). W. F. Edgell, G. B. Miller, and J. W. Amy, J. Am. Chem.

Soc. 79, 2391 (1957). G. Erlandsson, Duke U. Rept. #19, Aug.-Nov. (1957), Contr. AF 18 (600) 497. V. J. Goubeau and H. Sommer, Z. fur anorg. und allgemeine

chemie 289, 14 (1957). A. P. Gray and R. C. Lord, J. Chem. Phys. 26, 690 (1957). K. T. Hecht and D. M. Dennison, J. Chem. Phys. 26, 48

(1957). D. R. Herschbach, J. Chem. Phys. 27, 1420 (1957). R. W. Kilb, C. C. Lin, and E. B. Wilson, Jr., J. Chem. Phys.

26, 1695 (1957). R. W. Kilb and L. Pierce, J. Chem. Phys. 27, 108 (1957). D. Kivelson and D. R. Lide, Jr., J. Chem. Phys. 27, 353

(1957). T. Kojima and T. Nishikawa, J. Phys. Soc. Japan 12, 680

(1957).

262
[175] Krishnaji and G. P. Srivastava, Phys. Rev. 106, 1186 (1957). [176] Krishnaji and G. P. Srivastava, Proc. Phys. Soc. 70B, 621

(1957). [177] R. J. Kurland and E. B. Wilson, .)r., J. Chem. Phys. 27,

585 (1957). [178] R. G. Lerner and B. P. Dailey, .1. Chem. Phys. 26, 678

(1957). [179] R. G. Lerner, B. P. Dailey, and J. P. Friend, J. Chem. Phys.

26, 680 (1957). [180] D. R. Lide, Jr., J. Chem. Phys. 27, 343 (1957). [181] D. R. Lide, Jr. and D. E. Mann, J. Chem. Phys. 27, 686

(1957). [182] D. R. Lide, Jr. and D. E. Mann, J. Chem. Phys. 27, 874

(1957). [183] D. R. Lide, Jr. and D. E. Mann, Private Communication

(Aug. 1957). [184] D. E. Mann, N. Acquista, and D. R. Lide, Jr., Private communication (Nov. 1957). [185] I. A. Mukhtarov, Soviet Phys. "Doklady" 2, 357 (Eng.

trans) (1957). [186] R. E. Naylor and E. B. Wilson, Jr., J. Chem. Phys. 26,

1057 (1957). [187] T. Nishikawa, J. Phys. Soc. Japan 12, 668 (1957). [188] E. I. Sherrard, L. F. Thomas, and J. Sheridan, Private communication, J. Sheridan 1-29-1957.

[189] S. Siegel, J. Chem. Phys. 27, 989 (1957). [190] T. Sparstad and E. Amble, J. Chem. Phys. 27, 317 (1957). [191] J. D. Swalen and D. R. Herschbach, J. Chem. Phys. 27,

100 (1957). [192] P. R. Swan, Jr. and M. W. P. Strandberg, J. Mol. Spectr.

1, 333 (1957). [193] W. J. Tabor, J. Chem. Phys. 27, 974 (1957). [194] L. F. Thomas, J. S. Heeks, and J. Sheridan, Z. Elektrochem. 61, 935 (Eng. Trans) (1957). [195] H. J. Von Becher, Z. fur anorg. and allgemeine chemie

291, 151 (1957). [196] R. S. Wagner and B. P. Dailey, J. Chem. Phys. 26, 1588

(1957). [197] R. S. Wagner, B. P. Dailey, and N. Solimene, J. Chem.

Phys. 26, 1593 (1957). [198] R. Wagner, J. Fine, J. W. Simmonds, and J. H. Goldstein, J. Chem. Phys. 26, 634 (1957). [199] R. Wertheimer, Ann. Telecomm. 12, 267 (19.57). [200] R. Wertheimer. Arch. Sci. 10, Spec. No. 184 (1957). [201] E. B. Wilson, Jr., Proc. Nat'L Acad. Sci. U.S. 43, 816

(1957). [202] W. von Zeil and J. F. Pfrommer, Z. fiir Elektrochemie 6, 938 (1957). [203] B. Bak, L. Hansen-Nygaard, and J. Rastrup-Andersen, J. Mol Spectr. 2, 54 (1958). [204] A. I. Barchukov, T. M. Murina, and A. M. Prokhorov,

Optika i Spektroskopiya 4, 521 (1958). [205] A. I. Barchukov and A. M. Prokhorov, Optika i Spektroskopiya 4, 799 (1958). [206] A. I. Barchukov and A. M. Prokhorov, Optika i Spektroskopiya 5, 530 (1958). [207] G. Boudouris and D. Ilias, Compt. rend. 246, 1407 (1958).

[208] A. Dymanus, Utrecht U. Diss. (1958). [209] E. A. V. Ellsworth, M. Onyszchuk, and N. Sheppard, J. Chem. Soc. London, 1453 (1958). [210] G.-Erlandsson, J. Chem. Phys. 28, 71 (1958). [211] H. Eyring, G. H. Stewart, and R. P. Smith, Proc. Nat'l. Acad. Sci. U.S. 44, 259 (1958). [212] D. R. Herschbach and J. D. Swalen. J. Chem. Phys. 29,

761 (1958).

[213] D. R. Herschbach and L. C. Krisher, J. Chem. Phys. 28,

728 (19,58). [214] D. Herschbach and J. Swalen, Private communication,

Herschbach, 1-10-1958.

[215] D. Herschbach, Private communication, E. B. Wilson, Jr. 1216] N. A. Irisova, Izvest. Akad. Nauk S.S.S.R., Ser. Fiz. 22,

1.307 (1958). [217] N. A. Irisova, Optika i Spektroskopiya 4, 543 (19.58). [218] T. Kojima, H. Hirakawa, and T. Oka, J. Phys. .Soc. Japan

13, 321 (1958). [219] V. H. Kriegsmann, Z. fur anorg. und allgemeine chemie

2 94, 113 (1958). [220] V. W. Laurie, Private communication (1958). [221] V. W. Laurie and D. R. Lide, Jr., Bull. Am. Phys. Soc,

Ser. II, 3, 415 (1958). [222] D. R. Lide, Jr., Private communication (1958). [223] D. R. Lide, Jr., Private communication (1958). [224] D. R. Lide, Jr., J. Chem. Phys. 29, 1426 (19.58). [225] D. R. Lide, Jr. and D. E. Mann, J. Chem. Phys. 28, 572

(1958). [226] D. R. Lide, Jr. and D. E. Mann, J. Chem. Phys. 29, 914

(1958). [227] D. R. Lide, Jr. and D. E. Mann, Private communication

(1958).

[228] C. C. Lin, Am. J. Phys. 26, 319 (1958). [229] J. D. Swalen and D. R. Herschbach, Harvard U. Rept.

Contr. N5ori-186614 (1958). [230] Y. Morino and K. Kuchitsu, J. Chem. Phys. 28, 175 (1958). [231] I. A. Mukhtarov, Izvest. Akad. Nauk S.S.S.R., Ser. Fiz. 22, 1154 (1958). [232] L. Pauling, Proc. Natl. Acad. Sci. U.S. 44, 211 (1958). [233] L, Pierce, J. Chem. Phys. 29, 383 (1958). {234] J. D. Swalen and B. P. Stoicheff, J. Chem. Phys. 28, 671

(1958). [235] R. Trambarulo, A. Clark, and C. Hearns, J. Chem. Phys.

28, 736 (1958). [236] P. H. Verdier and E. B. Wilson, Jr., J. Chem. Phys. 29,

340 (1958). [237] T. L. Weatherly, Diss. Abstr. 18, 1469 (1958). [238] D. G. Burkhard and D. M. Dennison, J. Mol. Spectr. 3, 299

(1959). [239] R. F. Curl, Jr., J. Chem. Phys. 30, 1529 (1959). [240] H. Dreizler and H. D. Rudolph. Z. Naturforsch. 14a, 758

(1959). [241] E. F. Fricke, Rep. Aviation Corp. New York, Rept. F-5028-

101, 44. [242] O. Givaudon, Compt. Rend. 248, 1494 (1959). [243] P. H. Kasai and R. J. Myers, J. Chem. Phys. 30, 1096

(1959). [244] T. Kasuya and T. Oka, J. Phys. Soc. Japan 14, 980 (1959). [245] L. C. Krisher, Harvard U. Rept., C.N. 186614.(1959).

[246] L. C. Krisher and E. B. Wilson, Jr., J. Chem. Phys. 31,882

(1959). [247] V. W. Laurie, J. Chem. Phys. 30, 1101 (1959). [248] V. W. Laurie, J. Chem. Phys. 30, 1210 (1959). [249] V. W. Laurie, J. Chem. Phys. 31, 1500 (1959). [250] V. W. Laurie, Private communication (1959). [251] V. W. Laurie and D. R. Lide, Jr., Private communication

(1959). [252] V. W. Laurie and D. R. Lide, Jr.. J. Chem. Phys. 31, 939

(1959).

[253] D. R. Lide, Jr., J. Chem. Phys. 30, 37 (1959). [254] D. R. Lide, Jr., Spectrochim. Acta 15 , 473 (1959).

[255] D. R. Lide, Jr., and D. E. Mann, J. Chem. Phys. 31, 1129

(1959).

263
[256] D. R. Lide, Jr.. R. W. Taft, and P. Love, J. Chem. Phys. 31,

561 (1959). [257] S. Lifson. J. Chem. Phys. 30, 964 (1959). [258] C. C. Lin and J. D. Swalen, Rev. Mod. Phys. 31,841 (1959). [259] I. A. Mukhtarov. Optika i Spektroskopiya6, 260 (1959). [260] L. J. Nugent, Diss. Abstr. 19, 3150 (1959). [261] L. Pierce, Private communication (1959). [262] L. Pierce, J. Chem. Phys. 31, 547 (1959). [263] L. Pierce and L. C. Krisher, J. Chem. Phys. 3 1 , 875 (1959). [264] L. Pierce and J. M. O'Reilly, J. Mol. Spect. 3, 536 (1959). [265] L. H. Piette and W. A. Anderson, J. Chem. Phys. 30, 899

(1959). [266] D. C. Reitz, J. Chem. Phys. 30, 1364 (1959). [267] H. D. Rudolph and H. Dreizler, Private communication

(1959). [268] G. E. Schafer, U. of Colo. Tech. Rept. 7 (1959), Contr. DA-23-072-O RD-1059.

[269] G. P. Srivastava, Ind. J. of Phys. 33, 367 (1959). [270] G. P. Srivastava, Proc. Phys. Soc. 74, 401 (1959). [271] J. D. Swalen and C. C. Costain, J. Chem. Phys. 31, 1562

(1959) . [272] J. S. Waugh, J. H. Loehlin. F. A. Cotton, and D. P. Shoe- maker, J. Chem. Phys. 31, 1434 (1959). [273] W. Weltner, Jr., J. Chem. Phys. 31, 264 (1959). [274] B. Bak. S. Detoni, L. Hansen-Nygaard, and J. T. Nielsen,

Spectrochimica Acta 16, 376 (1960). [275] D. G. Burkhard, J. Opt. Soc. Am. 50, #12. 1214 (1960). [276] H. Chessin and R. W. Whitmore, Acta Cryst. 13, 274

(1960). [2771 W. L. Chnton, J. Chem. Phys. 33, 632 (1960). [278] C. C. Costain, J. M. Dowling, J. Chem. Phys. 32, 158

(1960). [279] H. Dreizler, W. Maier, and H. D. Rudolph, Arch. Sci. (Switzerland) 13, Fasc. Spec. 137 (1960). [280] H. Dreizler and H. D. Rudolph, Z. Naturforschg. ISA, 1013

(1960). [281] P. Gray and L. W. Reeves, J. Chem. Phys. 32, 1878 (1960). [282] D. Bias and G. Boudouris, Compt. rend. 250, 1833 (1960). [283] T. Kasuya and T. Oka, J. Phys. Soc. Japan 15, 296 (1960). [284] T. Kasuya, J. Phys. Soc. Japan 15, 1273 (1960). [285] T. Kojima, J. Phys. Soc. Japan 15, 284 (1960). [286] T. Kojima, J. Phys. Soc. Japan 15, 1284 (1960). [287] L F. Kovalev, Opt. and Spectr. 8, 166 (1960). [288] L. C. Krisher, J. Chem. Phys. 33, 304 (1960). [289] L. C. Krisher, J. Chem. Phys. 33, 1237 (1960). [290] L. C. Krisher and L. Pierce, J. Chem. Phys. 32, 1619 (1960). [291] G. H. Kwei and R. F. Curl, Jr., J. Chem. Phys. 32, 1.592 (1960). [292] G. H. Kwei and D. R. Herschbach, J. Chem. Phys. 32,

1270 (1960). [293] V. W. Laurie, J. Chem. Phys. 32, 1588 (1960). [294] V. W. Laurie, Private communication (1960). [295] I. N. Levine, Private communication.

[296] D. R. Lide, Jr., J. Chem. Phys. 33, 1514 (1960). [297] D. R. Lide, Jr., J. Chem. Phys. 33, 1519 (1960). [298] D. R. Lide, Jr., J. Chem. Phys. 33, 1879 (1960).

[299] D. R. Lide. Jr., Private communication.

[300] D. R. Lide, Jr., Private communication.

[301] D. R. Lide, Jr., J. Chem. Phys. 32, 1570 (1960). [302] J. T. Massey, C. J. Beard, and C. K. Jen, J. Mol. Spectr. 5, 405 ( 1960). [303] Y. Mikawa, Nippon Kazaku Zasshi 81, 1512 (1960). [304] D. J. MiUen and J. R. Morton, J. Chem. Soc. 1523 (1960).

[30.5] A. M. Mirri, Nuovo Cimento 18, 5 (1960). [306] D. H. Petersen and L. Pierce, Spect. Acta 16, 1272 (1960).

[307] L. Pierce and D. H. Petersen, J. Chem. Phys. 33 , 907

(1960). [308] A. M. Prokhorov and G. P. Shipulo, Opt. and Spectr. 8, 218 (1960). [309] K. E. Reinert, Z. Naturforsch. 15a, 85 (1960). [310] H. D. Rudolph, H. Dreizler, and W. Maier, Z. Naturforsch. 15a, 274 (1960). [311] H. D. Rudolph, H. Dreizler, and W. Maier, Z. Naturforsch. 15a, 742 (1960). [312] K. V. L. N. Sastry, Proc. Indian Acad. Sci., 51 A, 301

(1960). [313] W. von Zeil, M. Winnewisser, H. K. Bodenseh, and H. Bucheret, Z. Naturforsch. 15a, 1011 (1960). [314] P. Cahill and S. Butcher, J. Chem. Phys. 35, 2255 (1961). [315] D. Chin and P. A. Giguere, J. Chem. Phys. 34, 690 (1961). [316] C. C. Costain and G. P. Srivastava, J. Chem. Phys. 35,

1903 (1961). [317] W. B. Dixon and E. B. Wilson, Jr., J. Chem. Phys. 35, 191

(1961). [318] H. Dreizler, Z. Naturforsch. 16a, 477 (1961). [319] H. Dreizler, Z. Naturforsch. 16a, 1354 (1961). [320] D. F. Eggers. Jr., and H. E. Wright, J. Chem. Phys. 35,

1045 (1961). [321] P. A. Giguere and O. Bain, Private communication.

[322] P. A. Giguere and I. D. Liu, Private communication.

[323] M. Hayashi and L. Pierce, J. Chem. Phys. 35, 1148 (1961). [324] G. D. Jacobs, Thesis, Mich. State U. (1961).

[32.5] T. Kojima, E. L. Breig, and C. C. Lin, J. Chem. Phys. 35,

2139 (1961). [326] V. W. Laurie, J. Chem. Phys. 34, 1516 (1961). [3271 D. R. Lide, Jr., and D. Christensen, J. Chem. Phys. 35,

1374 (1961). [328] B. L. Livshito, Opt. and Spect. 10, 73 (1961). [329] L. J. Nugent and C. D. Cornwell, Private communication

(1961). [330] L. J. Nugent, D. E. Mann, and D. R. Lide, Jr., Private communication (1961). [331] J. M. O'Reilly and L. Pierce, J. Chem. Phys. 34, 1176

(1961). [332] L. Pierce and M. Hayashi, J. Chem. Phys. 35, 479 (1961). [333] L. Pierce, J. Chem. Phys. 34, 498 (1961). [334] L. Pierce and M. Hayashi, Private communication (1961). [335] M. L. Sage, J. Chem. Phys. 35, 142 (1961). [336] R. H. Schwendeman, J. Mol. Spectr. 6, 301 (1961). [337] K. M. Sinnott, J. Chem. Phys. 34, 851 (1961). [338] M. Winnewisser, H. K. Bodenseh, and W. von Zeil. 5th

E. Congr. Mol. Spectr. (1961) (Amsterdam).

[339] W. von Zeil, M. Winnewisser, and W. Huttner, Z. Naturforschung. 16a, 11 (1961). [340] W. von Zeil, M. Winnewisser, and K. MuUer. Z. Naturforsch. 16a, 1250 (1961).

[341] B. Bak, D. Christensen, L. Hansen-Nygaard. and J. Rastrup- Andersen, Spect. Acta 18, 1421 (1962). [342] R. A. Beaudet and E. B. Wilson. Jr., J. Chem. Phys. 37,

1133 (1962). [343] C. C. Costain and G. P. Srivastava, Proc. Inst. Symposium

on Molec. Struct, and Spectr. Tokyo, C 306-1 (1962). [344] D. R. Herschbach, Proc. Inst. Symposium on Molec.

Struct. & Spectr. Tokyo, C 401-1 (1962). [345] R. H. Jackson. J. Chem. Soc. 4585 (1962). [346] T. Kasuya, Sci. Papers, Inst. Phys. & Chem. Res. 56, 1 (1962) . [347] H. Kim, R. Keller, and W. D. Gwinn, J. Chem. Phys. 37,

2748 (1962). [348] I. N. Levine, J. Mol. Spectr. 8, 276 (1962).

264
[349] D. R. Lide. Jr., Private communication (1962). [350] V. Magnasco, Nuovo Cimento 24, 425 (1962). [351] A. Mozumder, Proc. Nat. Inst. Sci., India 28, 57 (1962).

[352] A. Mozumder, Proc. Nat. Inst. Sci., India 28, 74 (1962).

[353] L. J. Nugent, D. E. Mann, and D. R. Lide, Jr., J. Chem.

Phys. 36, 965 (1962). [354] M. G. K. PiUai, J. Phys. Chem. 66, 179 (1962). [355] R. L. Redington, W. B. Olson, and P. C. Cross, J. Chem.

Phys. 36, 1311 (1962).

[356] V. H. D. Rudolph, Z. Naturforsch. 17a, 288 (1962).

[357] R. H. Schwendeman and G. D. Jacobs, J. Chem. Phys. 36,

1245 (1962).

[358] R. H. Schwendeman and G. D. Jacobs, J. Chem. Phys. 36,

1251 (1962). [359] W. von Zeil, W. Huttner, and W. Plein, Z. Naturforsch. 17a, 823 (1962). [360] U. Blukis, P. H. Kasai. and R. J. Myers, J. Chem. Phys.

38, 2753 (1963). [361] C. Flanagan and L. Pierce, J. Chem. Phys. 38, 2963 (1963). [362] Y. I. Kolov and V. M. Tateyskii, Opt. and Spect. 14, 237

(1963).

[.363] D. R. Lide, Jr., and M. Jen, J. Chem. Phys. 38, 1504 (1963). [364] A. L. McClellan, Tables of Exp. Dipole Moments W. H. Freeman & Co. (1963).

[365] T. N. Sarachman, Private communication (1963).

[3661 L. H. Scharpen and V. W. Laurie, J. Chem. Phys. 39, 1732

(1963). [367] G. A. Barclay, R. F. W. Lefebre, and B. M. Smythe. Trans. Faraday Soc. 46, 812 (1950). [368] R. G. Shulman and B. P. Dailey. Phys. Rev. 78, 145 (1950). [369] G. M. Barrow, J. Chem. Phys. 20, 1739 (1952). [370] S. N. Ghosh, R. Trambarulo, and W. Gordy, Phys. Rev. 87,

172 (1952). [371] H. J. Von Becher, Z. fur anorg. und allgemeine chemie

270, 273 (1952). [372] E. L. Reilly, C. Curran. and P. A. McCusker, J. Am. Chem.

Soc. 76, 3311 (1954). [373] J. C. D. Brand and T. M. Cawthon, J. Am. Chem. Soc. 77,

319 (1955). [374] R. L. Collins and J. R. Nielsen. J. Chem. Phys. 23, 351

(1955).

[375] A. Palm and M. Kilpatrick, J. Chem. Phys. 23, 1.562(19.55). [376] S. Califano and W. Luitke. Z. Phys. Chem. 6, 83 (19.56).

[377] V. W. Laurie, Chimia, Harvard U. Spec. .Mol. 5, #.53 (19.56). [378] T. Nishikawa, Private communication (1956). [379] K. Shimoda, Private communication (19.56). [380] T. Chiba, T. Shimozawa, I. Mujazawa, and Y. Morino, Bull. Chem. Soc. Japan 30, 223 (1957). [381] A. H. Sharbaugh, Private communication.

[382] W. J. Tabor, Thesis, Harvard U. (1957). [383] G. Bird and C. H. Townes, Phys. Rev. 94, 1203 (19.54).

[384] K. M. Sinnott, Private communication (1956).

[.385] D. R. Lide, Jr., J. Chem. Phys. 37, 2074 (1962). [386] C. A. Burrus and W. Gordy, Phys. Rev. 101, .599 (19.56). [387] N. A. Irisova and E. M. Dianov, Opt. and Spectr. 9, 136

(1961). [388] J. K. Brown and N. Sheppard, Trans. Far. Soc. 50, 1164

(1954). [389] D. E. Gray (Coordinating Editor), American Institute of Physics Handbook, McGraw-Hill Book Co., Inc., New

York (1957). [390] Gerhard Herzberg, Molecular Spectra and Molecular Structure. I. Spectra of Diatomic Molecules, D. Van Nostrand,

New York (1947). [391] Gerhard Herzberg. Molecular Spectra and .Molecular Structure, II. Infrared and Raman Spectra of Polyatomic

Molecules, D. Van Nostrand, New York (1947).

[392] C. H. Townes and A. L. Schawlow, Microwave Spectroscopy, McGraw-Hill Book Co., Inc., New York (1955). [393] A. A. Maryott and F. Buckley, Table of Dielectric Constants and Dipole Moments of Substances in the Gaseous State, NBS Circular 537 (June 25, 1953).

[394| Arnold Euken, (Editor), Landolt-Biirnstein: Zahlen-Werte und Funktionen aus Physik, Chemie, .Astronomic, Geophysik und Technik (6th Edition), Springer-Verlag,

Berlin (1950). [395] L. G. Wesson, Tables of Electric Dipole Moments, The

Technology Press, M.I.T. (1947). [396] P. Kisliuk and C. H. Townes, Molecular Microwave Spectra

Tables, NBS Circular 518 (June 23, 1952).

265 u s. GOVERNMENT PRINTING OFFICE : 1969 O —7*9-587