Instructions for filling in the Emission Test Template

This Information Collection Request (ICR) spreadsheet is intended to collect information about emission data from fossil fue l burning power plants and which test methods were used to do so for cases where the test methods are not currently supported by the Electronic Reporting Tool (ERT). This spreadsheet should only be used if the method is not in the ERT or if you do not have access to a lab which performs methods that are in the ERT. You must complete at least 3 separate runs or sampling events for each of the requested constituents. This spreadsheet is intended to be used for one boiler of one facility. Data for multiple boilers should be handled by using separate copies of this spreadsheet. Fields shaded in yellow are required. All cells that are shaded in green are populated using drop

- down lists. You do not need to populate cells shaded in gray, as they are automatically populated from the Boiler Information worksheet. Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_EmisTestMethods.xls (example: 8100_Unit_2_EmisTestMethods.xls).

Please refer to the following steps when using these spreadsheets.

Boiler Information Worksheet

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the control device configuration.

Emission Data Worksheets

The emission data worksheets are provided for each constituent or constituent family required for this analysis. On each spreadsheet, you must enter boiler operating information during sampling, fuel input information, and emission test results. There are generally 1 to 3 emission test results records to be entered depending on the constituent or constituent family. For example, CO only requires 1 record with 3 sample events, while Mercury requires that you enter both Hg0 and Hg +2 , or if the Ontario

- Hydro Method was used, you would need to enter Hg 0, HgP, and Hg +2 . However, both the Speciated Volatile Organic HAP and Speciated Semi

- Volatile Organic HAP worksheets allow you to use a drop

- down provided in the Constituent field to define as many records as needed to record each HAP that you have results for. General instructions follow for these worksheets:

Boiler Operation Information

1. Please provide the values of all requested parameters for each of test run/sample. 2. Please provide any other supporting information or comments in the Other Supporting Information field.

Fuel Information

1. Please enter what types of fuel are being used in your boiler using the drop

- downs in the Fuel Type Selection field. You may enter up to 4 fuel types. If you are not burning one or more of the fuel types entered in one or more samples, then enter an input rate of zero. 2. Please enter the unit of measure using the drop down provided. 3. Please enter the test method used to determine the fuel input rate. 4. Please provide any other information that you feel may be important in the Other Supporting Information field.

Emission Data

1. Some constituents ask for the emission rate results of each run in two different units of measure, while others do not. If emission rate results are requested in two different units of measure (ex. lb/MMBtu (Pounds per million BTU) and ppmvd @ 7% O 2 (parts per million by volume dry basis at 7 percent oxygen)), you are required to provide both. 2. Please provide the test method used. This may or may not match the example given in the Test Method Used field. Please ensure that the name includes the owning organization of the test method (ex. U.S. EPA Method 0010). 3. Please provide any other information that you feel may be important in the Other Supporting Information field. 4. If data sheets and QA/QC documentation tables are provided for the test method you are entering data for please also enter these data.EIA

Facility Code Facility Name Boiler ID

2364 Merrimack Station 2Control Device Configuraton

Listed (by

boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICRListed (by boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICREIA

Facility Code Facility Name Boiler ID 2364 Merrimack Station 2

1 03/29/10 11:35 2 03/30/10 7:35 3 03/31/10 7:40 Run Number Test Start Date Test Start TimePlease note QA/QC documentation starting in Column "AI"

Me asured Value (μg/dscm) Basis (Wet or Dry)

03/29/10 15:44 9.90 Dry 03/30/10 10:00 11.61 Dry 03/31/10 10:05 10.03 Dry Test End Time Test End Date Total Vapor Phase Mercury Emission Test ResultsPlease note QA/QC documentation starting in Column "AI"

Test Method Used Data Flag (ADL, BDL, DDL) Test Method

Comments (lb/mmBtu)

U.S. EPA Method 30B ADL 7.09E-06 U.S. EPA Method 30B ADL 8.37E-06 U.S. EPA Method 30B ADL 7.28E-06 Total Vapor Phase Mercury Emission Test Results Steam Output (1000 lb/hr)Fuel Input Rate

7.7 15.54 3.76 678,214 335.6 3150 8.3 15.43 3.83 685,381 335.5 3142 8.3 15.31 3.88 686,797 334.9 3120 Flue Gas Temperature (F) Flue Gas Moisture (%) Total Heat Input (mmBtu/hr) Flue Gas CO 2(%) Flue Gas

O 2(%) Flue Gas

Flow Rate (scfm)Fuel Type Units of Me asure Me asurement

Me thod Fuel Input

Rate Fuel Type Units of

Me asure Me asurement

Me thod Fuel Input

Rate
bitum inous MMBtu/hr F-Factor bitum inous MMBtu/hr F-Factor bitum inous MMBtu/hr F-Factor Fuel #1 Fuel #2Fuel Type Units of Me asure Me asurement

Me thod Fuel Input

Rate Fuel Type Units of Me asure Me asurement

Me thod Fuel #3 Fuel #4QA /QC Documentation

Trap ID Section 1

Ma ss (ng) Section 2

Ma ss (ng) Total

Ma ss (ng) Initial

Spike (ng) Total NonSpike (ng)
32796 916 16 932 0 932 68604 1270 0 1270 0 1270 68628 1160 0.2 1160.2 0 1160.2 Other Supporting InformationSample

Volume (dscm) Volume

Difference (%) Volume Diff. Limit Breaktrough

(%) Breaktrough

Limit Concentration

(μg/dscm) Trap ID

0.125656 4.54 1.75 7.42 23810 0.123447 3.36 0.00 10.29 23830 0.121776 0.12 0.02 9.53 66656 ≤ 20% of field recovery test ≤10% of Section 1 Hg

ma ss for Hg Trap #1Section 1

Ma ss Section 2

Ma ss Total

Ma ss Initial

Spike Total NonSpike Sample

Volume Volume

Difference (%) Volume Diff. Limit 3,600.0 1.1 3,601.1 2000 1,601.1 0.129224 4.54 3,650.0 1.2 3,651.2 2000 1,651.2 0.12778 3.36 3,300.0 0.0 3,300.0 2000 1,300.0 0.123475 0.12 ≤ 20% of field recovery test Trap #2Breaktrough (%) Breaktrough Limit Concentration

(μg/dscm) Ab s. diff. RD (%) Limit C rec

0.03 12.39 4.97 25.11 20.45 0.03 12.92 2.63 11.35 18.29 0.00 10.53 1.00 4.99 17.2 Me asured Spike Recovery ( R ) Paired Trap Agreement (RD)

≥ 10 % RD mass for Hg conc. >1 μg/dscm: or ≤10% of Section 1 Hg mass for Hg conc. >1R (%) by

Run R avg (%) Limit

132.14 116.84 106.16 Average Recovery

, between 85 and Me asured Spike Recovery ( R )

118.38Fuel

anthracite bitum inous subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) sy nfuel petroleum coke other

Relative to Control Device Upstream Downstream

Fuel Input Units of Measure MMBtu/hr standard cubic feet per minute (scfm) gallon/m inute lb/hour ton/day

Exhaust Flow Rate Units of Measure acfm dscfm

Exhaust Temperature Units of Measure deg C deg F

Test Method Used for Fuel Input Rate F-Factor gas fuel meter boiler efficiency

calculation Other

CO Test Method U.S. EPA Method 10A U.S. EPA Method 10B

Formaldehyde Test Method U.S. EPA Method 320U.S. EPA Method 0011

U.S. EPA Method 316

CH4 Test Method U.S. EPA Method 18 U.S. EPA Method 320

SO2 Test Method U.S. EPA Method 6

Hg Test Method U.S. EPA Method 30B

Speciated Volatile Organic HAP M ethod U.S. EPA Method 0031 with SW -846 Method 8260B U.S. EPA Method 0031/TO-15

Speciated Semi-Volatile Organic HAP M ethod U.S. EPA Method 0010 with SW -846 Method 8270C U.S. EPA Method 0010 with SW -846 Method 8270D

HCN Test Method U.S. EPA Conditional Test Method 033 (CTM-033) U.S. EPA Method 320 CARB 426 U.S. EPA Method 26A-Mod

O2/CO2 Test Method U.S. EPA Method 3B

NOX Test Method U.S. EPA Method 7 U.S. EPA Method 7A U.S. EPA Method 7B U.S. EPA Method 7C U.S. EPA Method 7D

TDS/TSS Test Method Standard Test Method for Filterable and Nonfilterable Matter in W ater ASTM D5907 Standard Methods of the Examination of W ater and W astewater Method 2540B

Control Configuration 

### Listed (by boiler) in Question 16 (page 17) of the questionnaire Listed (by boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICRHg Ontario Hydro Test Method

ASTM Method D6784

HCL Test Methods U.S. EPA Method 320 U.S. EPA Method 26

HF Test Methods U.S. EPA Method 320 U.S. EPA Method 26

Basis We t DryConstituent CAS Methyl chloride 74-87-3 1,1,2-Trichloroethane 79-00-5 1,1-Dimethy lhydrazine 57-14-7 1,2,4-Trichlorobenzene 120-82-1 1,2-Dibromo-3-chloropropane 96-12-8 1,2-Epoxy butane (1,2-butylene oxide) 106-88-7 1,2-Propy leneim ine (2-methy laziridine) 75-55-8 1,3-Butadiene 106-99-0 1,3-Dichloropropene 542-75-6 1,3-Propane sultone 1120-71-4 1,4-Dichlorobenzene (p-) 106-46-7 1,4-Dioxane (1,4-Diethy lene oxide) 123-91-1 2,2,4-Trimethy l pentane 540-84-1 2-Nitropropane 79-46-9 Acetaldehyde 75-07-0 Acetonitrile (cyanom ethane) 75-05-8 Acetophenone 98-86-2 Acrolein (2-propenal) 107-02-8 Acrylam ide 79-06-1 Acrylic acid 79-10-7 Acrylonitrile (2-propenenitrile) 107-13-1 Ally l chloride (3-chloropropene) 107-05-1 Aniline (am inobenzene) 62-53-3 Benzene 71-43-2 Benzyl chloride (a-chlorotoluene) 100-44-7 Beta-Propiolactone 57-57-8 Bis(2-Chloroethy l)ether 111-44-4 Bis(chloromethy l) ether 542-88-1 Bromoform (tribromomethane) 75-25-2 Carbon disulfide 75-15-0 Carbon tetrachloride 56-23-5 Carbony l sulfide 463-58-1 Catechol (o-hydroxy phenol) 120-80-9 Chloroacetic acid 79-11-8 Chlorobenzene 108-90-7 Chloroform 67-66-3 Chloromethy l m ethy l ether 107-30-2 Chloroprene (2-chloro-1,3-butadiene) 126-99-8 Cresy lic acid (cresol isomer mixture) 1319-77-3 Cumene (isopropy lbenzene) 98-82-8 Diazom ethane 334-88-3 Diethy l sulfate 64-67-5 Dim ethy l sulfate 77-78-1 Dim ethy lcarbamy l chloride 79-44-7 Epichlorohydrin (1-chloro-2,3-epoxy propane) 106-89-8 Ethyl acry late 140-88-5 Ethyl carbamate (urethane) 51-79-6 Ethyl chloride 75-00-3 Speciated Volatile Organic HAPsEthylbenzene 100-41-4 Ethylene dibrom ide (1,2-dibromoethane) 106-93-4 Ethylene dichloride (1,2-dichloroethane) 107-06-2 Ethylene oxide 75-21-8 Ethyleneim ine (aziridine) 151-56-4 Ethylidene dichloride (1,1-dichloroethane) 75-34-3 Formaldehyde 50-00-0 Hexachlorobutadiene 87-68-3 Hexachloroethane 67-72-1 Hexane 110-54-3 Isophorone 78-59-1 1, 1, 2, 2-Tetrachloroethane 79-34-5 Methanol 67-56-1 Methyl bromide 74-83-9. Methyl chloroform (1,1,1-trichloroethane) 71-55-6 Methyl ethy l ketone (2-butanone) 78-93-3 Methyl iodide 74-88-4 Methyl isobutyl ketone (hexone) 108-10-1 Methyl isocyanate 624-83-9 Methyl m ethacry late 80-62-6 Methyl tert-butyl ether 1634-04-4 Methylene chloride 75-09-2 Methylhydrazine 60-34-4 m-Xy lene 108-38-3 N,N-Dimethy laniline 100-23-2 N,N-Dimethy lformamide 68-12-2 Nitrobenzene 98-95-3 N-Nitrosodimethy lam ine 62-75-9 N-Nitrosomorpholine 59-89-2 N-Nitroso-N-methy lurea 684-93-5 o-Cresol 95-48-7 o-Xy lene 95-47-6 Phenol 108-95-2 Phosgene 75-44-5 Propionaldehyde 123-38-6

Propylene dichloride (1,2-dichloropropane) 78-87-5 Propylene oxide 75-56-9 p-Xy lene 106-42-3 Sty rene 100-42-5 Sty rene oxide 96-09-3 Tetrachloroethy lene 127-18-4 Toluene 108-88-3 Trichloroethy lene 79-01-6 Triethy lam ine 121-44-8 Viny l acetate 108-05-04 Viny l bromide 593-60-2 Viny l chloride (chloroethene) 75-01-4 Viny lidene chloride 75-35-4 Xy lenes (isomer & mixtures) 1330-20-7 

### Listed (by boiler) in the Configuration Order Section of the Facility Unit Configurations Section of the Electronic ICRSpeciated Semi-volatile Organic HAPs

Constituent CAS 2-Methy lnaphthalene 91-57-6 Acenaphthene 83-32-9 Acenaphthylene 208-96-8 Anthracene 120-12-7 Benzo(a)anthracene 56-55-3 Benzo(a)py rene 50-32-8 Benzo(b)fluoranthene 205-99-2 Benzo(e)py rene 192-97-2 Benzo(g,h,i)perylene 191-24-2 Benzo(k)fluoranthene 207-08-9 Chrysene 218-01-9 Dibenzo(a,h)anthracene 53-70-3 Fluoranthene 206-44-0 Fluorene 86-73-7 Indeno(1,2,3-cd)py rene 193-39-5 Naphthalene 91-20-3 Perylene 77392-71-3 Phenanthrene 85-01-8 Py rene 129-00-0 Acetophenone 98-86-2 2-Acety lam inofluorene 53-96-3 1-Acety l-2-thiourea 591-08-2 Aldrin 309-00-2 2-Aminoanthraquinone 117-79-3 Am inoazobenzene 60-09-3 4-Aminobipheny l 92-67-1 3-Amino-9-ethy lcarbazole 132-32-1 Anilazine 101-05-3 Aniline 62-53-3 o-Anisidine 90-04-0 Aramite 140-57-8 Aroclor 1016 12674-11-2 Aroclor 1221 11104-28-2 Aroclor 1232 11141-16-5 Aroclor 1242 53469-21-9 Aroclor 1248 12672-29-6 Aroclor 1254 11097-69-1 Aroclor 1260 11096-82-5 Azinphos-m ethy l 86-50-0 Barban 101-27-9 Benzidine 92-87-5 Benzoic acid 65-85-0 p-Benzoquinone 106-51-4 Benzyl alcohol 100-51-6

α-BHC 319-84-6 β-BHC 319-85-7 δ-BHC 319-86-8 γ-BHC (Lindane) 58-89-9Bis(2-chloroethoxy)methane 111-91-1

Bis(2-chloroethy l) ether 111-44-4 Bis(2-chloroisopropy l) ether 39638-32-9 Bis(2-ethylhexy l) phthalate 117-81-7 4-Bromopheny l pheny l ether 101-55-3 Bromoxy nil 1689-84-5 Butyl benzy l phthalate 85-68-7 Captafol 2425-06-1 Captan 133-06-2 Carbary l 63-25-2 Carbofuran 1563-66-2 Carbophenothion 786-19-6 Chlordane (NOS) 57-74-9 Chlorfenvinphos 470-90-6 4-Chloroaniline 106-47-8 Chlorobenzilate 510-15-6 5-Chloro-2-methy laniline 95-79-4 4-Chloro-3-methy lphenol 59-50-7 3-(Chloromethy l)py ridine hydrochloride 6959-48-4 1-Chloronaphthalene 90-13-1 2-Chloronaphthalene 91-58-7 2-Chlorophenol 95-57-8 4-Chloro-1,2-pheny lenediam ine 95-83-0 4-Chloro-1,3-pheny lenediam ine 5131-60-2 4-Chloropheny l pheny l ether 7005-72-3 Coumaphos 56-72-4 p-Cresidine 120-71-8 Crotoxy phos 7700-17-6 2-Cyclohexy l-4,6-dinitro-phenol 131-89-5 4,4'-DDD 72-54-8 4,4'-DDE 72-55-9 4,4'-DDT 50-29-3 Demeton-O 298-03-3 Demeton-S 126-75-0 Diallate (cis or trans) 2303-16-4

2,4-Diaminotoluene 95-80-7 Dibenz(a,j)acridine 224-42-0 Dibenzofuran 132-64-9 Dibenzo(a,e)py rene 192-65-4 1,2-Dibromo-3-chloropropane 96-12-8 Di-n-buty l phthalate 84-74-2 Dichlone 117-80-6 1,2-Dichlorobenzene 95-50-1 1,3-Dichlorobenzene 541-73-1 1,4-Dichlorobenzene 106-46-7 3,3'-Dichlorobenzidine 91-94-1 2,4-Dichlorophenol 120-83-2 2,6-Dichlorophenol 87-65-0 Dichlorovos 62-73-7 Dicrotophos 141-66-2 Dieldrin 60-57-1Diethy l phthalate 84-66-2

Diethy lstilbestrol 56-53-1 Diethy l sulfate 64-67-5 Dim ethoate 60-51-5 3,3'-Dimethoxy benzidine 119-90-4 Dim ethy lam inoazobenzene 60-11-7 7,12-Dimethy lbenz(a)-anthracene 57-97-6 3,3'-Dimethy lbenzidine 119-93-7 α,α-Dimethy lphenethy lam ine 122-09-8 2,4-Dimethy lphenol 105-67-9 Dim ethy l phthalate 131-11-3 1,2-Dinitrobenzene 528-29-0 1,3-Dinitrobenzene 99-65-0 1,4-Dinitrobenzene 100-25-4 4,6-Dinitro-2-methy lphenol 534-52-1 2,4-Dinitrophenol 51-28-5 2,4-Dinitrotoluene 121-14-2 2,6-Dinitrotoluene 606-20-2 Dinocap 39300-45-3 Dinoseb 88-85-7 Dipheny lam ine 122-39-4 5,5-Dipheny lhydantoin 57-41-0 1,2-Dipheny lhydrazine 122-66-7 Di-n-octy l phthalate 117-84-0 Disulfoton 298-04-4 Endosulfan I 959-98-8 Endosulfan II 33213-65-9 Endosulfan sulfate 1031-07-8 Endrin 72-20-8 Endrin aldehyde 7421-93-4 Endrin ketone 53494-70-5 X X ND X X 53494-70-5 EPN 2104-64-5 Ethion 563-12-2 Ethyl carbamate 51-79-6 Ethyl m ethanesulfonate 62-50-0 Famphur 52-85-7 Fensulfothion 115-90-2 Fenthion 55-38-9 Fluchloralin 33245-39-5 2-Fluorobipheny l (surr) 321-60-8 2-Fluorophenol (surr) 367-12-4 Heptachlor 76-44-8 Heptachlor epoxide 1024-57-3 Hexachlorobenzene 118-74-1 Hexachlorobutadiene 87-68-3 Hexachlorocyclopentadiene 77-47-4 Hexachloroethane 67-72-1 Hexachlorophene 70-30-4 Hexachloropropene 1888-71-7 Hexamethy lphosphoramide 680-31-9 Hydroquinone 123-31-9 Isodrin 465-73-6 Isophorone 78-59-1 Isosafrole 120-58-1Kepone 143-50-0

Leptophos 21609-90-5 Malathion 121-75-5 Maleic anhydride 108-31-6 Mestranol 72-33-3 Methapy rilene 91-80-5 Methoxychlor 72-43-5 3-Methy lcholanthrene 56-49-5 4,4'-Methy lenebis (2-chloroaniline) 101-14-4 4,4'-Methy lenebis(N,N-dimethy laniline) 101-61-1 Methyl m ethanesulfonate 66-27-3 Methyl parathion 298-00-0 2-Methy lphenol 95-48-7 3-Methy lphenol 108-39-4 4-Methy lphenol 106-44-5 Mevinphos 7786-34-7 Mexacarbate 315-18-4 Mirex 2385-85-5 Monocrotophos 6923-22-4 Naled 300-76-5 1,4-Naphthoquinone 130-15-4 1-Naphthy lam ine 134-32-7 2-Naphthy lam ine 91-59-8 Nicotine 54-11-5 5-Nitroacenaphthene 602-87-9 2-Nitroaniline 88-74-4 3-Nitroaniline 99-09-2 4-Nitroaniline 100-01-6 5-Nitro-o-anisidine 99-59-2 Nitrobenzene 98-95-3 4-Nitrobipheny l 92-93-3 Nitrofen 1836-75-5 2-Nitrophenol 88-75-5 4-Nitrophenol 100-02-7 5-Nitro-o-toluidine 99-55-8 Nitroquinoline-1-oxide 56-57-5 N-Nitrosodi-n-buty lam ine 924-16-3 N-Nitrosodiethylam ine 55-18-5 N-Nitrosodimethy lam ine 62-75-9 N-Nitrosodipheny lam ine 86-30-6 N-Nitrosodi-n-propy lam ine 621-64-7 N-Nitrosomethy lethylam ine 10595-95-6 N-Nitrosomorpholine 59-89-2 N-Nitrosopiperidine 100-75-4 N-Nitrosopy rrolidine 930-55-2 Octamethyl py rophosphoramide 152-16-9 4,4'-Oxydianiline 101-80-4 Parathion 56-38-2 Pentachlorobenzene 608-93-5 Pentachloronitrobenzene 82-68-8 Pentachlorophenol 87-86-5 Phenacetin 62-44-2 Phenobarbital 50-06-6 Phenol 108-95-2 1,4-Phenylenediam ine 106-50-3Phorate 298-02-2

Phosalone 2310-17-0 Phosmet 732-11-6 Phosphamidon 13171-21-6 Phthalic anhydride 85-44-9 2-Picoline (2-Methylpy ridine) 109-06-8 Piperony l sulfoxide 120-62-7 Pronamide 23950-58-5 Propy lthiouracil 51-52-5 Resorcinol 108-46-3 Safrole 94-59-7 Strychnine 57-24-9 Sulfallate 95-06-7 Terbufos 13071-79-9 1,2,4,5-Tetrachlorobenzene 95-94-3 2,3,4,6-Tetrachlorophenol 58-90-2 Tetrachlorvinphos 961-11-5 Tetraethy l dithiopy rophosphate 3689-24-5 Tetraethy l py rophosphate 107-49-3 Thionazine 297-97-2 Thiophenol (Benzenethiol) 108-98-5 Toluene diisocyanate 584-84-9 o-Toluidine 95-53-4 Toxaphene 8001-35-2 1,2,4-Trichlorobenzene 120-82-1 2,4,5-Trichlorophenol 95-95-4 2,4,6-Trichlorophenol 88-06-2 Trifluralin 1582-09-8 2,4,5-Trimethy laniline 137-17-7 Trimethy l phosphate 512-56-1 1,3,5-Trinitrobenzene 99-35-4 Tris(2,3-dibromopropy l) phosphate 126-72-7 Tri-p-toly l phosphate 78-32-0 O,O,O-Triethyl phosphorothioate 126-68-1