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## Exhaust Emissions Sampling Daltite, Muskogee, OK Scrubber Inlet and Exhaust May 19, 2005 Armstrong Envir-onmental, Inc. Project W-2462-05

Report Prepared For: Bob Hurt Daltile 7834 C. F. Hawn Freeway Dallas, TX 75217

Report Prepared May 23, 2005 By: Armstrong Environmental, Inc. 7715 Sovereign Row Dallas, Texas 75247 (214) 631-0021

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~ TABLE OF CONTENTS

I. Introduction U. Summary 

## III. Procedures N. Appendices A. Calculation Summaries B. Continuous Emissions Monitor Summaries C. Analytical Summaries D. Field Data Sheets E. Equipment Calibrations F. Standard Gas Certifications 

## Page
1 

## 2-4 5-6

7-12 13 - 40 41 - 118 119 - 124 125 - 129 130 - 138

### in



## I. INTRODUCTION


# ~ A series of tests was performed on the inlet and exhaust associated with the scrubber at

the Daltile facility in Muskogee, OK on May 19, 2005. ' The purpose of this test series was to determine the exhaust emission rate of PM, CO,

NOx, VOC, S02, HF, HCL, and C12 and the removal efficiency of PM, HF, HCL, and

## ■ C12. Testing followed procedures detailed in Title 40: Code of Federal Regulations (40:CFR). Sampling was performed by Richard Taylor, Dan Barrera and Tom Armstrong of Armstrong Environmental, Inc. using two Apex Method 5 sampling trains, an EcoPhysics 70S continuous NOx analyzer, a Fuji 3300 NDIR continuous CO analyzer, a Western Research 721 AT continuous S02 analyzer, and a ThermoEnvironmental Mode151 continuous FID analyzer. Three one hour test repetitions were performed, commencing at 9:10 AM and ending at 1:13 PM. Submitted by: ic.



# ~ 1 

# r ;N

556.5 36.86 47876.3 21656.6 

### 1299394 11.00% 5.00 16.00


### 10:40 AM 11:40 AM 33.069 103.6303

23.55 0.010988 2.040431

13.72 0.006402 1.188735 3.229166

88.27 113.3548 7.647588

11.04 3.993807 0.956533 3

558.8 37.41 48592.9 22105.5 

### 1326329 10.27% 4.00 17.00

12:10 PM 1:14 PM 33.597 103.1485

26.55 0.012193 2.311099

2.66 0.001222 0.231545 2.542644

97.17 122.8263 8.45836

10.79 3.841953 0.939237

105.66 113.83 74.35084 78.84252 9.154474 9.908738 

### t

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~ SUMMARY OF EMISSIONS TEST DATA



### ~ Table : 2 Plant : Daltile, Muskogee, OK Location : Scrubber Inlet Operator : R. Taylor Test Date : 19-May-05 Repetition : 1 

### STACK GAS Temperature, F 554.4 Velocity, fps 37.71 Volume Flow, acfm 48981.9

scfm 22142.4 scfh 1328545 Moisture, % 11.24% CO2, % 5.00 02, °% 16.00 SAMPLE Start Time, hrs:min 9:10 AM Finish Time, hrs:min 10:10 AM Sample Volume, scf 33.727 Isokinetic Ratio, % 103.3725 PARTICULATE Front Half 

### Sample Weight, mg 22.23 Concentration, gr/scf 0.01017 Emissions, Ibs/hr 1.930868 Back Half 

### Sample Weight, mg Concentration, gr/scf Emissions, Ibs/hr Total Particulate, Ibs/hr HYDROGEN FLUORIDE 

### Sample Weight, mg Concentration, ppm Emissions, Ibs/hr CHLORINE 

### Sample Weight, mg Concentration, ppm Emissions, Ibs/hr HYDROGEN CHLORIDE 

### Sample Weight, mg Concentration, ppm Emissions, Ibs/hr 9.52 0.004355 0.826894 2.757762

91.17 114.7946 7.918469

11.62 4.121648 1.009297

112.83 77.85209 9.800609 

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## III. PROCEDURES

The procedure for emissions sampling followed USEPA test methods as detailed in Title 40: Code of Federal Regulations. The following methods were used: Method Title 

## 1 Sample and Velocity Traverses for Stationary Sources 2 Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S

Pitot Tube) 3 Gas Analysis for CO2, 02, Excess Air and Dry Molecular Weight 5 Determination of Particulate Emissions from Stationary Sources 6C Determination of Sulfur Dioxide Emissions from Stationary Sources

(Instrumental Analyzer Procedure) 7E Determination of Nitrogen Oxides Emissions from Stationary Sources

(Instrumental Analyzer Procedure) 10 Determination of Carbon Monoxide Emissions from Stationary Sources 25A Determination of Total Gaseous Organic Concentration using a Flame

Ionization Analyzer 26A Determination of Hydrogen Halides and Halogens Emissions from

Stationary Sources 02 and CO2 were determined using FyRite Analyzers. PM. HF, HCI, and C12 sampling was performed on the scrubber exhaust for 3 minutes at each of 20 points, 10 points per traverse, making a total run duration of 60 minutes. PM, HF, HCI, and C12 sampling was performed on the scrubber inlet for 5 minutes at each of 12 points (traversing a single port twice) making a total run duration of 60 minutes. Each sampling train was configured as follows: Glass Sampling Nozzle Heated Glass Lined Probe Heated teflon filter Impinger # 1- 100 mis H20 Impinger #2 - 100 mis 0.1 N H2SO4 Impinger #3 - 100 mis 0.1 N NaOH Impinger 94 - 100 mis 0.1 N NaOH Impinger #5 - 200 grams silica Gel 

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# rx Analysis for PM was performed on the probe wash, filter, and solution from the first

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## impinger. HF and HCl analysis was performed on an aliquot from the first impinger, and

the solution from the 2nd impinger. Analysis for C12 was performed on the solution from

_ the 3rd and 4th impingers. Analysis was performed using a Dionex LC20 IC/HPLC.

VOC as C3H8 was determined using a ThermoEnvironmental Model 51 continuous FID analyzer. The analyzer was calibrated with 48.8 ppm, 28.8 ppm, and 15.2 ppm C3H8 in Air USEPA Protocol 1 gas standards, zeroed with N2. 

## i Nitrogen Oxides were determined using an EcoPhysics 70S continuous NOx analyzer.

The analyzer was calibrated with 92.8 ppm and 51.3 ppm NOx in N2 EPA Protocol 1 gas standards, and zeroed with N2.

~ 

## Carbon monoxide was determined using a Fuji 3300 NDIR continuous CO analyzer. The

analyzer was calibrated with 105 ppm and a 47.3 ppm CO in N2 EPA Protocol 1 gas

, standards, and zeroed with N2.

Sulfur dioxide was determined on the scrubber exhaust using a Western Research 721 AT e continuous S02 analyzer. The analyzer was calibrated with 101 ppm and a 50.1 ppm

S02 in N2 EPA Protocol 1 gas standards, zeroed with N2.



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u Appendix A

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## 1 EMISSION TEST SUMMARY ® PLANT : Daltile, Muskogee, OK

DATE : 19-May-05 PLACE : Scrubber Inlet RUN# : 1



### ~ TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : 90.7

NOZZLE DIAMETER (lNCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) : 22.23 METER COEFFICIENT (Y) : 0.993 PARTICULATE WEIGHT (Back half mg) : 9.52 PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : •1.7 

### ~ GAS METER VOL.(Cu.Ft.) : 36.211 PERCENT CO2 5

BAROMETRIC PRESSURE 29.4 PERCENT 02 16 PERCENT CO 0

## ■ FOR CIRCULAR STACK FOR RECTANGULAR STACK

## ■ STACK DIAMETER (inch): 63 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) : 0



### ~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754

FLOWS SAMPLED VOLUME (STD. CU .FT.): 33.7265 , VOLUME OF WATER VAPOR (STD. CU .FT.): 4.2692

FRACTIONAL MOISTURE CONTENT (Q/): 0.1124

DRY BASE: 79.0000

-- 1 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.4400 

# ~ MOLECULAR WT. OF STACK GAS (WET BASE): 28.1546 STACK PRESSURE (inch Hg): 29.2750 STACK GAS VELOCITY (ft/sec.): 37.7117 ACTUAL STACK GAS FLOW RATE (ACFM): 48981.9172 

# ~ STANDARD STACK GAS FLOW RATE (SCFH): 1328544.81

PARTICULATE 

# ~ FRONT HALF 

# ~ PARTICULATE CONCENTRATION (GR./SCF): 0.0102

PARTICULATE CONCENTRATION (LBS/SCF): 1.45E-06 PARTICULATE EMISSION (LBS/HR): 1.9309



### ~ BACK HALF

PARTICUTATE CONCENTRATION (GR./SCF): 0.0044 PARTICULATE CONCENTRATION (LBS/SCF): 6.22E-07 

# ~ PARTICULATE EMISSION (LBS/HR): 0.8269

, ISOKINETIC RATIO (%): 103.3725 

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~ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. deg F INLET OUTLET 

### ~ 1 560 0.21 0.458258 0.83 85 85

2 560 0.24 0.489898 0.96 92 86 

# ~ 3 563 0.25 0.5 1.00 97 87 4 564 0.24 0.489898 0.96 98 88 5 563 0.21 0.458258 0.83 99 89 6 521 0.19 0.43589 0.75 98 90 

# ~ 7 548 0.20 0.447214 0.80 99 90 8 558 0.25 0.5 1.00 100 91 9 561 0.27 0.519615 1.10 102 92 10 562 0.25 0.5 1.00 103 93 

# ~ 11 561 0.22 0.469042 0.89 104 94

12 532 0.17 0.412311 0.68 103 95 554.41667 0.4734 0.9000 98.3333 90.0000 94.1667 

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## d

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## / EMISSION TEST SUMMARY

### ■ PLANT : Daltile, Muskogee, OK

### ■ __ DATE : 19-May-05

PLACE : Scrubber Inlet RUN#: 2

### ■ TEST DURATION (MINUTES) : 60 LIQUID COLLECTED (mis) : NOZZLE DIAMETER (INCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) METER COEFFICIENT (Y) : 0.993 PARTICULATE WEIGHT (Back half mg) PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : 

## ~ GAS METER VOL.(Cu.Ft.) : 35.84 PERCENT CO2

BAROMETRIC PRESSURE 29.4 PERCENT 02 PERCENT CO ; ' FOR CIRCULAR STACK FOR RECTANGULAR STACK

STACK DIAMETER (inch): 63 STACK LENGTH(inches) : STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inches) : NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) :



## ~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754

FLOWS SAMPLED VOLUME (STD. CU .FT.): 33.0688 

# ~ VOLUME OF WATER VAPOR (STD. CU .FT.): 4.0857

FRACTIONAL MOISTURE CONTENT (%): 0.1100

DRY BASE: 79.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.4400 

# ~ MOLECULAR WT. OF STACK GAS (WET BASE): 28.1820 STACK PRESSURE (inch Hg): 29.2750 STACK GAS VELOCITY (ft/sec.): 36.8605 

# ~ ACTUAL STACK GAS FLOW RATE (ACFM): 47876.2934

STANDARD STACK GAS FLOW RATE (SCFH): 1299394.21 PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): 0.0110 PARTICULATE CONCENTRATION (LBS/SCF): 1.57E-06 PARTICULATE EMISSION (LBS/HR): 2.0404

.. 

# ~ BACK HALF 

# ~ PARTICULATE CONCENTRATION (GR./SCF): 0.0064

PARTICULATE CONCENTRATION (LBS/SCF): 9.15E-07 PARTICULATE EMISSION (LBS/HR): 1.1887 ' ISOKINETIC RATIO (%): 103.6303



# ~ $ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. deg F INLET OUTLET 1 561 0.20 0.447214 0.81 94 93 2 563 0.24 0.489898 0.97 99 94 

# ~ 3 562 0.21 0.458258 1.05 102 94

4 558 0.24 0.489898 0.97 103 94 

# ~ 5 559 0.22 0.469042 0.89 103 95

6 534 0.15 0.387298 0.60 103 95 , 1 7 554 0.22 0.469042 0.89 105 96 2 8 562 0.23 0.479583 0.93 105 96

9 565 0.25 0.5 1.00 106 96 10 563 0.24 0.489898 0.97 106 97

, e 11 562 0.22 0.469042 0.88 107 98

12 535 0.16 0.4 0.64 106 98

556.5 0.4624 0.8833 103.2500 95.5000 99.3750 86.8 23.55 13.72 -1.7 5 16 0

C



# ~ ~EMISSION TEST SUMMARY

~ PLANT : Daltile, Muskogee, OK

DATE : 19-May-05 PLACE : Scrubber Inlet RUN#: 3

~ TEST DURATION (MINUTES) : 60 LIQUtD COLLECTED (mis) : 81.7
~ NOZZLE DIAMETER (INCH.) : 0.3123 PARTICULATE WEIGHT (Front half mg) : 26.55 ' METER COEFFlCIENT (Y) : 0.993 PARTICULATE WElGHT (Back half mg) : 2.66

PITOT COEFFICIENT (Cp) : 0.84 STATIC PRESSURE (in. H20) : -1.8 ~ GAS METER VOL.(Cu.Ft.) : 36.627 PERCENT CO2 4

BAROMETRIC PRESSURE 29.4 PERCENT 02 17 PERCENT CO 0 ! FOR ClRCULAR STACK FOR RECTANGULAR STACK

STACK DIAMETER (inch): 63 STACK LENGTH(inchs) : STACK AREA (Sq.Ft.) : 21.64754 STACK WIDTH(inchs) : NOZZLE AREA (feet): 0.000532 STACK AREA (Sq.Ft.) : 0

~ ENTER THE STACK AREA SHOWN ABOVE: 21.64754

FLOWS 

# ~ SAMPLED VOLUME (STD. CU .FT.): 33.5974

VOLUME OF WATER VAPOR (STD. CU .FT.): 3.8456 FRACTIONAL MOISTURE CONTENT (%}: 0.1027

DRY BASE: 79.0000 MOLECULAR WT. OF STACK GAS (DRY BASE): 29.3200 

# ~ MOLECULAR WT. OF STACK GAS (WET BASE): 28.1574 STACK PRESSURE (inch Hg): 29.2676 STACK GAS VELOCITY (ft/sec.): 37.4122 

# ~ ACTUAL STACK GAS FLOW RATE (ACFM): 48592.8813

STANDARD STACK GAS FLOW RATE (SCFH): 1326328.97 PARTICULATE 

# ~ FRONT HALF

PARTICULATE CONCENTRATION (GR./SCF): 0.0122 PARTICULATE CONCENTRATION (LBS/SCF): 1.74E-06 PARTICULATE EMISSION (LBS/HR): 2.3111 ! BACK HALF

PARTICULATE CONCENTRATION (GR./SCF): 0.0012 PARTICULATE CONCENTRATION (LBS/SCF): 1.75E•07 PARTICULATE EMISSION (LBS/HR): 0.2315 

# ~ ISOKINETIC RATIO (%): 103.1485



# ~ POINTS STACK T. DELTA P SQUAR D.P DELTA H METER T. METER T. deg F INLET OUTLET 

## ~ 1 556 0.20 0.447214 0.84 100 99

2 567 0.24 0.489898 1.00 104 99 3 568 0.25 0.5 1.00 105 100 4 561 0.24 0.489898 1.00 105 98 5 561 0.22 0.469042 0.92 105 98 6 536 0.17 0.412311 0.71 106 98 

# ~ 7 544 0.22 0.469042 0.92 102 99 8 565 0.23 0.479583 0.96 107 99 9 567 0.27 0.519615 1.10 108 100 10 562 0.24 0.489898 1.00 110 101 

## ~ 11 562 0.22 0.469042 0.91 110 101

12 556 0.15 0.387298 0.62 110 101

558.75 0.4686 0.9150 106.0000 99.4167 102.7083 

# ~

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### A



# Appendix B



# IDate of Woighirg

~ Timo 8mxxVYoi0ht

~ DateofYYeiQhinA

~ ~ Tima

~ GmxsYYoight

~ DataofYvvighinQ

~ Timo BeakorToreVYeight

~ ~ DatoufYVoi8h\ng Time BoakerTamYVoight

~ ~ AveegoGmxsvVvioht Leox B|unk Rosidue(0a) AvuraAe BoakorTareVVoiQht 110.6581

~ ~ WeightofParUcu|atnin Rinxe(m8) 

## Ow

10.15 PARTCULATEANALY7ICAL DATARJRM Cvmpany: DaUi(e, Munkogun OK Qate: 5/19/05 Lncabvn: 3cmbher|n|et nunz nuno Run3 Donuity(pa) B|ankConcontmUnn(Ca) u RinooVoiumo(Vaw)

RosiduoinRinso(Na)=Ca°Vaw°Pa

~ 0 z 005 i 0D004

Nl N|

Time

Time

Time

Time

~ ;~ ~~

### RLTERANAL|T|CALD/T7\

Coropany: Oa@le.Munkugae.OK Data: 5/19/05 Locmtimn: Sorubber|n|*t RunI Run2 Run3 Fi|tar|ONunnber DobaofVVeighing

Tinna Gr000Fi|tevVVL Date ofVVoighhng

//mo Gross FilteVVL Av*.GrooaFihorVVL 0.3804 0.3896 0 . 3886 DeteofVVeighing

Time FU(erToroVVL DoteofVVeighinQ

Time Fi|terTaro VVL Ave.Fi|barToreVVL 0.3641 0.3734 0 .3 7 21 VVt. ofPK8un Fi|her(gnanno) 0.0183 0.0161 0.0 184 Toto|VVeightofParUcu\ata (nng) 16.3 161 18.4 0 0

1 1
°

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# r, PARTICULATE ANALYTICAL DATA FORM Company: Daltile, DIOUPW igk Date: 5/19/05 Location: Scrubber Inlet Run 1 Run 2 Run 3 Density (Pa) Blank Concentration (Ca) Rinse Volume (Vaw) Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0008 0.0008 0.0008

Date of Weighing

Time `7 M. Gross Weight .5 --.*: Date of Weighing

Time 1 3 .- ZCY P. M:

............... Gross Weight A
Date of Weighing

Time Beaker Tare Weight Date of Weighing 2.0

Time 

### -a M' Beaker Tare Weight Average Gross Weight 101.9667 100.0664 115.7113 Less Blank Residue (Wa) 0.0008 0.0008 0.0008 Average Beaker Tare Weight 101.9579 100.0531 115.7088 Weight of Particulate in Rinse (mg) 7.99 12.54 1,69
H20 BLANK ANALYTICAL DATA FORM Blank Volume (Va) Date of Weighing 5

Time Gross Weight 2: Date of Weighing

Time

..... ..... Gross Weight Average Gross Weight 109.76515 Date of Weighing

Time Tare Weight Date of Weighing

Time Tare Weiglit Average Tare Weight 109.7642 Weight of Blank (Ma) 0.00095_ Ca= Ma/(Va*Pa) = g/g 3.8E-06 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank weight be subtracted from the sample weight.

## 11

PARTICULATE ANALYTICAL DATA FORM Company: Daltile, Muskogee, OK Date: 5/19/05 Location: Scrubber Inlet Run I Run 2 Run 3 Density (Pa)

........ ....... ......... Blank Concentration (Ca) Rinse Volume (Vaw)

........ ......... Residue in Rinse (Wa) = Ca*Vaw*Pa 0.0002 0.0002 0.0002

Date of Weighing 

## 0

Time Gross Weight 6 , 14.4 ; Date of Weighing

Time

... ...... ... Gross Weight
Date of Weighing

Time

.............. ... AM:

.... Beaker Tare Weight Date of Weighing

Time

. ;40 p

..... Beaker Tare Weight Average Gross Weight 106.8071 111.6146 117.4807 Less Blank Residue (Wa) 0.0002 0.0002 0.0002 Average Beaker Tare Weight 106.8054 111.6132 117.4796 Weight of Particulate in Rinse (mg) 1.53 1.18 0.97

METHYLENE CHLORIDE BLANK ANALYTICAL DATA FORM Blank Volume (Va) Date of Weighing

Time Gross Weight Date of Weighing

Time AW: Gross Weight Average Gross Weight 99.59895 Date of Weighing

Time Tare Weight Date of Weighing

Time Tare Weight Average Tare Weight 99.5985 Weight of Blank (Ma) 0.00045 Ca= Ma/(Va*Pa) = g/g 1.324E-06 Note: In no case should a blank residue greater than 0.01 mg/g or 0.001% of the blank weight be subtracted from the sample weight.Sheetl

Summary of HF, 

### HCI, and C12

- Analysis Plant: Daltile, Muskogee, OK

- Co

- cation: Scrubber Inlet 6a

- te.-

- 5/19/05 Run # Imp # Volume Dilution Fl-, ug/mi HF, mg 

### Cl-, ug/mi 

### HCI, mg



### 1 200 20 

### 19.97 84.1136

. 4 

### 26.32 

### 108.2278 1 200 20 

### 21.83 91.94796 26.46 

### 108.8035 Average 

### 88.0308 108.5157 2 

### 1 200 20 19.49 

### 82.09188 25.46 104.6915



### 1 200 20 

### 20.86 

### 87.862321 23.39 96.17968 Average 84.9771 

### 100.4356 3 1 200 20 

### 19.16 80.70192 26.86, 110.4483 

### 3 1 200 20 

### 20.81 87.65172 

### 25.99 106.8709 

### I Average 

### 84.17682 108.6596 Imp # Volume Dilution Fl-, ug/mi HF, mg 

### CI-, ug/mi 

### HCI, mg

2 

### 150 1 20.08 

### 3.171636 27.33 4.214286

- 2 

### 150 1 19.61 3.0974 28.68 4.422456 Average 

### 3.134518 4.318371 2 2 

### 150 1 20.84 

### 3.291678 34.69 

### 5.349198 21 2 

### 150 1 20.81 3.28694 33.05 

### 5.09631 Average 

### 3.289309 5.222754 3 - 2 

### 150 1 

### 19.13 3.021584 34.02 5.245884

2 

### 150 1 18.77 2.964722 

### 33.06 5.097852 Average 

### 2.993153 

### 5.171868 Total Run 

### 1 

### 91.16532 112.8341

Run 2 

### 88.26641 

### 105.6584 Run 

### 3 87.16997 

### _ 113.8315

# -Run 

### Imp # Volume Dilution 

### Cl-, ug/mi 

### C12, mg 

### 1 3 

### & 4 

### 300 1 37.91 11.373 

### 1 - 3 

### & 4 

### 300 1 39.57 11.871 11.622 2 

### 3 & 4 

### 300 1 36.68 11.004 2 3&4 

### 300 1 36.89 11.067 11.0355 

### 300 300 1



### 1 36.22 35.73 . 

### 10.866

10.719 

### 10.7925 L~ , 

# E



# I -7

r- 

# 0 Page 

### 1 0

### Conditions : 5 

### ug/ml Fl— in H20 

### : 5 ug/ml - Cl— in H20 Date 

### : 05/21/2005 Time z 08:52:21


### —102.4OOmV Component Reten (unknown) 0.

- 

### Fl- 0. 

## ci- 1. LIU11 

### 1024.00OmV Area External 172.10 N/A

420.60 4.75 276.90 4.24

Component Number Retention Area External Units Fl— 1 0.950 420.60 4.75 ug/ml cl— 2 1.266 276.90 4.24 ug/ml

2 697.50 8-99

Igl e 

## jo ExteSDOI



# 51- 

# 1

## ~ 412.10 M 4.7 279.00 M 4.9 F1- 0. Ci- 1. 

## Canditians ? § Ugiffil Ej=

©ate 05/21/2005 

## Time : 09-09=41

—102 .400mV 1024.00OmU 

## Component Retention Area Externi

Component 

## Number Retenti©n Area External Units Fl-- 1 0.950 

## 412.10 M 4.77 ug/ml 

## ca.— 2 1.250 279.00 P1 4.96 ug/ml .

K 691_10 9_73



# 0 52 

# 7

### Conditions : 10 ug/ml Fl- in H20 : 10 ug/ml C-1- in H20 Date 

### : 05/21/2005 Time 

### : 09:14:09


### -102.4OOmV Component Reten

Fl- 0. 

## cl- 1. 

### 1024.00OmV Area Externa

906.73 10.6 573.34 8.8



### Component Number Retention Area External Units Fl- 0.950 906,73 10.67 ug/ml 

## ci- 2' 1.266 573.34 8.86 ug/ml

VA 1480.08 19-53



### r /-. o-3

### 0 v '

~ @
~ 

### Fl- O.

Cl- \. -1O2'4O0mV Componon¢ Re 

### ton Conditions : 10 ug/ml Fl- in H20

: lO uQ/ml Cl- in R20 Qate : 05/21/2005 Time : 09:16:48
1024'ODOmV Area Exterm

862.70M 1O.1 S78.0H 8. ~



### Cmmpomant Numbmr Retention Arma External Unita Fl- 1. 0.966 862.70 M 10.17 ug/ml Cl- 2 1.266 578'50 M 8'92 ug/ml

2 1441-20 19-09

~

~ ~~

### Conditions 

## Date Time

_ Comyonont Redootio/L : 20 ug/ml Fl- in H20

: 20 ug/ml Cl- in H20 : 05/21/2005 : 09:2l:24
L02'40O0V l024'000mV Area Exherm

Fl- O. C}- 1. 1658.71 H 1184.48 N 0.~

~ ~

~ ~

~ ~ 

### Component

FlClNumber Hetention l O'966 2 1.266 Arma ExterneI Unita

1658.71 M 18.96 ug/ml 1184.48 M 18.60 ug/ml
2

~r
~~~ 

### U = Conditinno 

## Date Time

_ Componont Rotnotioo : 20 ugyml Fl- im H30

: 20 mg/ml CI- in H20 : 05/21/2005

~ 

### 09-

- 24c10
LO2.40OmV 1O24.00OmV

F1' O. C}- 1.2 ~ 

# Am 1715.99 1%D.60 M.(

0.,

CompmnentFlClNumber Retention 1 0.950 2 1.266 1715.99 19'62ug/ml

1227.60 / 19.21 ug/ml
2

c ~n ~~ri

### Conditions Date 

## Time

Component Retention = 40 ug/ml Fl— in H20



## = 40 ug/ml Cl— in H20 : 05/21/2005 : 09-28=24 

### 102 .4f7qmV 1024,OQOmV 

## Area Ezterng

F1- 0. 3236.27 M 39.3 

## C1- 1. 2639:5b M 42.7 

## 11

U

Component Number Retention 

## Area External Units



## Fl— 1 0.966 3238.27 M 39.32 ug/ml 

## C1— 2 1.300 2639.56 N1 42.75 ug/m1

VA 5877.83 82.07



### 5 / ~1024.00OmV



## Conditions

©ate 

## Time

Component Rete = 40 ug/ml Fl- in H20

= 40 ug/ml Cl- in H20 = 05/21/2005 = 09=31-16
102.400mV



## F1- 0 C1- 1 

## Area Ezterni

3339.19 40. 1 2529.69. 41.0 

## l i

-~ ~ 

# 4

~

~

~ J

~

~

~

~

~



# ~

~

~ '

, 

# e

~ r Component Number Retention Area External Units

Fl- 1 0.983 3339.19 40.58 ug/ml Cl- 2 1.300 2529.69 41.01 ug/ml

2 5868.88 81_59



# N o

### AMOUNT INJECTEd

AREA 0.000 0.00



### 3288.73 40.000 1
2
3

i~ W



### 5 } 

## Calibration file = Fl-_cal

Avg slope of curve: 84.32 Y-axis intercept= 0.00 Coeff of 1 i n regr : 0.90 

## No. Area Amount CF 0= 0.000 0.000 0.000 1= 416.350 5.000 83.270 2 ~ 

### 884.715 10.000 88.472 3: 1687.350 20.000 84.367 4= 3288.730 40.000 82.218



# 59

# ~
1 Calibration file = Cl-.cal

AMOUNT'INJECTED AREA O _ 000 40.000 0.0

2584.6 

## Avg slope of curve; 61.78 Y-axis intercept= 0.00 Coeff of la.n regr: 0.90 

## No. Area Amount O» 0.000 0.000 1: 277.950 5.000 2 = 575.920 10.000 3= 1206.040 20.000 4- 2584.625 40.000 

## ~
1

~

~

~

~



# ~

~

~

~ ma 0.000 55.590 57.592 60.302 64.616 1 2
3

4

5



## ~ ~~I

~l ~~

~ ~

~

~ ~

~

~ /w

~ 

### Componmnt koto

hmknmm\ 0 '^ " C}' I Cnnditimnm : Daltilm° 8crubber Inlet

: Rwn #1 Imp #1 : VoIume 200 Dilution 1/28 Date z 05/21/'20{)5 Time 10:02:11 -1O2,4O0mV 1024.0OOmV

CumponentFlClNumber Retention 1 0.983 2 1.316 Arou [xbmx

44.20 N/i 1684,90H 19'' 1641.36 H 26' ~



### Area ExtermaI Units 1684.90 M 19.97 ug/ml 1641.36 M 26'32 ug/ml
VA

~~ ~~

### CnnditIono : Daltile, Scrubber Inlet : Run #1 Imp #1 : Volume 200 Dilution 1/20 Date : 05^'21^'2005 Time : 10:06:35

~ 

### U

D U -1O2.4OOmV

Component Retei

.


## (un known) O R- O C1- 1 /noa [xhnn

23.60 N/ 1834'20 H 21. 1651.46 H 26. 1024.000mV

Compmnent Number Rmtentimn Area Extmrnal Units Fl- 1 0.966 1834'20 M 21.83 ug/ml Cl- 2 1.300 1651.46 M 26.46 ug/ml

2 3405'66 48'30

~~ 

### mm

## Conditions : Daltile, Scrubber In1et = Run #2 Imp #1 = Voiume 200 Dilution 1/20 Date = 05/21/2005 Time = 10:11-38
-102.400mV Companent Rete "


## (unknown). 0 F1- 0 C1- 1 

## Area Exterr

57.25 Mi 1646.75 M 19. 1582.68 M 25. 

## 1024.00OmV

C ..,. f

C

Component 

## Number Retention Area External. Units



## Fi— 1 0.966 1646_75 M 19.49 ug/ml 

## Cl— 2 1.300 

## 1582.68 M 25.46 ug/ml

~ 3229.43 44.96



# 69

### AToa Exbnr 34.90 N/ 1756.55H 20. 1440.00 H 23.

r*
~ ~~v ~ 

### | ^ Cmnditions : Daltile, Scrubber Inlet : Run #2 Imp #1 : Vmlume 200 DiIution 1/20 Date : 05/21/2005 Time : 10:16:20

~ ~

~ ~ 

### -102.40OmV

rxmovnmm, 0eteotio" _-,-_' -- (uokoown) O Fl- O C}- 1 1024.00OmV

Area External Unito 1756.5S M 20'86 ug/ml 1440.00 M 23.39 ug/ml Compmmant Number Retention Fl- 1 0'96& Cl- 2 l'300

~ 

### 1

## : Daltile, Scrubber Inlet z Run #3 Imp #1 : Volume 200 Dilution 1/20 : 05/21/2005 = 10:21-31
t02 .400mV 1024.00OmV Conditions

Date 

## Time

Component Retention 

# i

._.. 

## (unknown) 0.700 Fl- 0. 1 - Cl- 1.316 

### Area Externi

23.20 N/i 1620.25 M 19.: 1679.05 M 26.1



## Cornponent Number Retention Area External Units Fl-- 1 0.983 1620.25 M 19.16 ug/ml C1— 2 1.316 1679.05 M 26.86 ug/mJ.

2 3299_30 46.03

rt ~ 

## f .i

### '^ ' ~ 

### Conditlnna


## Date Time

- ~ 

### Daltilm, Sorubber ZnIet

~ 

### Run #3 Imp #1

~ 

### VoIume 200 Dilution 1/20 : 05/21/2005 z 1D:26:23
L02'4OOmV lO24'OOOmV Aroa [xtern.

~ ~ 

### Fl- 0. 

# mm 1752.10 N 20.1 1619.01 H 25,'

CumponentFlclK Number Retentlon 1 0.966 2 1.316 Area Extermal Hnito 1752.10 M 2 0 

### .81 ug/ml 1619'0 1 

### M 25.99 ug/ml
3371'11 48'80

n ~ ~ ~Conditions 

### : H20 Blank Date 

### : 05/21/2005 

## I 

## Time : 10:32:09

I —102.4OOmV

Component Retention



### . ........ (unknown) 

### 0.533 

# ~ 1024.00OmV 

## Area 45.35 Exterr



### NY 

## RE

I

Component Number Retention Area External Units



## m



# 7 1 3

### C«/nditimno : 5 ug/ml.Fl- in H2SO4 : 5 uQ/mI Cl- in H2SO4 Datm z 05/21/2005 Time , : 10:35:27
-1O2'4O0mV ' 1024.00OmV ^ -

-

^

/ Number Retention Area Extmrn'al Units 1 0'950 350.80 4.21 ug/ml 2 1.233 230'20 M 4.14 ug/ml Fl- O. 350.80 4.; %0.2OH 4.:

CompnnentFlClVA

r/ ~ ~~

### Cnnditimma : 5 ug/ml FI- in H2SO4 : 5 ugyml Cl- in H2SO4 Date : 05/21/2005 Time : 10r37c12 -1O2,40OmV Component ketontio l024'OOOmV Area Extorn

B- O.- Cl- 1.: !1W %0.6O 4. 23L7OM 4.

Component Number.Retmntion Area Extermal Units Fl- l 0.966 370.60 4.45 ug/ml Cl- 2 1.216 231.70 M 4.17 ug/ml

2

n ~

### 817.75 9. 552.40 M 9. 

## Fl- 0 C1- 1 Conditions = 10 uglml Fl- in H25O4



## = 10 uglml Cl- in N2SO4 ( Date : 05121l2005 Time = 10-42=47

-102 .400mtt 

### 1024 .OQQmV 

## Component Retention Area Extern

Compcsnent

## FlCl2 

## Number Retention 1 0.950 

### 2 1.233 

## Area External Units

817.75 9.36 uglml 552.40 M 9.66 ug/ml
1370.15 19_02



### t~ ~

### —1O2'4OOmV

Com0000nt Rotondoo

_ (unkmmn) O.
Fl_ O. lO24'OOOmV Area Extern 27.80 N/

827.95 10. 510.45 H 9. Conditlmno : 1{} ug/ml Fl— in H2SO4

c 10 ug/ml Cl— in H2SO4 Datm : 05/21/2005 Time : 10:49:44

` Compmnent Number Retention Area Externe*l Units Fl— 1 0.950 827.95 10'05 ug/ml Cl- 2 1.233 510.45 M 9'38 ug/ml

2

^ r/ ~ ~~

### Nl m ~ 

### Conditimne

~~~~ Timm

_ ~ ~ ~ ~~~ ~en 

### (unkmwn) O.

Fl- 0. Cl- 1. : 15 ugJml Fl- in H2SO4 : 15 ug/ml tl- in H2SO4 : 05/21/2005 : 1O:55:l7
L02'4OOmV 1O24.00OmV Arou Exbnn 30.70 N/

18N.00H 14.' 853.95 H 14.

Component Number Retention Are*a ExternaI Unito Fl- 1 0.950 1204.00 M 14.41 uQ/ml Cl- 2 1.233 853.95 M 14.78 ug/ml

~ ~~

### Cmnditiono 

### Date Time
Cumponont kotontion (unknown) 0.08

Fl- O. Cl- 1.21 : 15 ug/ml Fl— in H2SO4 : 15 ug/ml Cl— in H2SO4 : 05/21y2005 : lU:57:O2
1O2.40OmV 1O24.O00mV

. Area Exbnp 256.27 N/

1216.50 14.

Compmnent Number Retentlon Area External Unite Fl— 1 0.950 1216,50 14.55 ug/ml Cl- 2 1.216 877,95 15.14 ug/ml

2

~~

### Conditinnm : 20 eg/ml Fl- in H25O4 : 20 ugyml Cl- in H2SO4 Dete : 05/21/2005 Time : .11

~ 

### O2:23
-102'.40DmV Comoonen 

### t --

Fl- O Cl- 1

| "

~ N|
~

~ ~ 

### 1O24'OOOmV

1665^75 20. 1110.60 H 0'

Component Number Retention Aree Enternal Units Fl- 1 O,966 1665.75 20'48 ug/ml Cl- 2 1'250 1110.60 M 18.56 ug/ml

2 2776-35 89.04

~~ ~p

### lO24.00OmV Area Exbxm 79.20 N/i 78.72 Nli 93.61 Nh 1661.50 H 19.1 1529.40 H 28'( / `

U r 

### " `
8 »

U »
N n
N N

~

'

~
~

~

~
~ ~

~
~ ' ~ 

### Conditioma : Dalt1Ie, 8orubber InIet : Run #1 Zmp #2 : Volume 150 DiIution 1/1 Date : 05/21/2005 7[ime z 11:39:25
-102'4OOmV 

### Component koton

- 

### un k 

### nown -- `' \«nxmmo> o. (onknown) O. Fl- O, Cl- 1.

Compmnent Number RwtentInn Fl- , 1 0'966 Cl- 2 1'216

K Lm

`

~~ 

### Area Externol Unito 1661.50 M 19.61 ug/ml 1529'40 M 28.68 ug/ml

### : Daltile, Sorubber Znlet : Run #2 Zmp #2 : Volume 150 Dilution 1/1 : 05/21/2005 : 1l:44:39
iO2.40OmV 1024.0OOmV Conditionm



## Date Time
Comp000nt 8otontion (uokmmo) O

Fl- O.



### 1[ Area Extern 39.00 N/

170.81 H 20.

' Component Number Hetmn±inn Arma External Vnito Fl- l 0.966 1781.81 M 20.84 ug/ml Cl- 2 1'233 1826'50 M 34.68 ug/ml
2 . 3802'31 55-52

~ ~ '' 

### /-

### Conditinna : DaltiIe, Scrubbmr Inlet : Run #2 Imp #2 : Volumw 150 Dilution 1/~1 Date c 05/21/2005 Time : 11:46:28
-102.400mV Comp000nt Roton 1oo oVkDVwn O. (unkmmn} O. /unkumm\ O. Fl- O, Cl- 1, lO24'0OOmV Aron Exherm 72.30 NN 109.20 NA 01,0 NII 1779.06 20.( 1741.55 33.(

Component Numbar Retention Area ExternaI Unito Fl- 1 0.966 1779,06 ' 20'81 ug/ml Cl- 2 1.216 1741.55 33'05 ug/ml

2

Q ~ ~u

## Fl- 0.

C1- 1. .,..... (
~ ~ 1. .,.. 

### 233
2 .,...

3 .........

4 . ..,. 

### Conclitions



## Date Time

Component Retention : Daltile, 5crubber Inlet

: Run #3 Imp #2 : 4+olume 154 Dilution 1/1 : 05/21/2005 : 11:52:03

L02 .400mV 1024 .00OmtI 

## Area Extern,

1614.22 19.: 

### 1788.28 34.(

, r



### Component 

## Number Retenti.on Area External Units F1- 1 0.966 1614.22 19.13 uQ/ml C1-- 

### 2 1.233 1788.28 34.02 ug/ml

kA 3402.50 53 _ 14



# 94

### AToa Exbnm 79.80 NN 80.70 NN 1579.43 M 10." 1741.77 M 33.( Conditions ; Daltilm, Scrubber Inlet

: Run #3 Zmp #3

~ 

### Volume 150 Dilution 1//1 Date 05/21/2005 Time
~ 

### ll

- 53

~ 

### 52
-102.40OmV ~ 

### CompoRent 

### Reten (uokoowo) 0. (unknown) O. 8- 0. C\- 1. 1O24'0DOmV

N Component Number Rwtention Arma ExternaI Units

Fl- I 0.950 1579.43 M 18.77 ug/ml Cl- 2 1.216 1741,77 M 33.06 ug/ml

2

~

~~

### Canditians = H2SO4 B3ank Date = 05121/2005 Time = 11=59=39
-102.400mV Component Retention (unknown) 0 (unknown) 0 1024.QOOmV Area Extern 26.35 N/
34.80 N/

Compnnent Number Retention Area External Units

J s_•H 

# a •Lo



# 9 61024.00OmV 

## Area Extern

Conditions : 5 ug/ml C1— in NaOH

Date : 05/21/2005 

## Time : 12=10=18

—102 . 4OOmV 

## Component Rete
(unknown) 0
C1

- 1 (unknown) i 778.30 N1
90.10 M ' 5. , 170.27 M N/;

Component 

## Number Retention Area External Units C1— 2 1.400 

### 90 „10 h1 5 .00 ug/ml

1 90_10 5.00

`7

~ (

### Condltions : 5 ug/ml Cl— in NaOH Qate z 05/21/2005 Time : 12:16:18
—1O2.400mV Component 8etoD
(unknown) O. C\- 1' 1024.O00mV kroa Exbmm

NW.80N NA
94.00 N S.< u

.......... . ... ................ ................ .............. ........... ........ ..... ....

. ......... . .........



### Compmnent Number Retentlon Area External Qnits 2 1.416. 94.00 M 5.04 ug/0l
1 94'00 5'04

{ ~ 

### ~ au

### 1D24.O0OmV —102.400mV Compone 

### nt Reton ion
xnknown O. (unkxowo) O. C\- 1. Area Extern
26.0 N/ 670.90 NK 200.76 10.1 Conditi«xno : 10 uQ/mI Cl— in NaOH Date : 05/21/2085 Time : 12:19c55

Component Mumbvar Rmtention Area Extmrnafl Units Cl— 2 1'383 200.75 10.00 ug/ml

M

~~ ~0

### Conditions : 10 ug/ml C1— in NaOH Date = 05/21/2005 

### Time = 12:22=28
—102.4OOmV Component Retention 1.024 .00OmV 

## Area Eztern
(unknown) 0.8001 ~



### 1. .,... ~ 

### Cl- 1.400

~ 2 

### _ .... ;

3

.... : 710.45 N/
203.70 M 10.



### Component 

## Number Retention Area External Units C1— 2 1.400 203.70 M 10.02 ug/ml

1 203_70 10.02

### Conditions 15ug/ml Cl- in NaDH 0ate : 05/21/2005 Timm : 12:25:42
-102.4DOmV ----' Rete 

### n tion 

### 1O24.O0OmV Area Exbern

895.80 N/


### 301.80 14. (uokmmo) O.
Cl- l.'

Cnmpnnent Number Retentinn Area External Unito cl- 2 1.450 301.80 14.51 ug/ml

1 301'80 14'51

~U~916.80 N/;
299.50 14.- 

## (unknown)_ 0
C1- 1 

## Conditions : 15 uglml Cl— in Na©H Date : 05/21l2005 Ti.me = 12=27=56 --102.4(JOmV 

## Component Retention 1024 .00OmV 

## Area Extern

Component 

## Number Retention Area External Units 

## Cl- 2 1.450 

## 299.50 14.41 uglml

1 299.50 14.41

~.~ 

### .1e)

### (unkmmn) . O.

Fl- 1. Cl- 1. 555.70 N/ 66.65 H O. 440.80 H 22. Conditic/ne : 20 u8/ml Cl- im NaOH Date : 05/21/2005 Time : 12:31:08
-1O2.4O0mV 1O24.00OmV Area [xtern

ComPoneant Number Retmntion Area Extermal Qnits Fl- 1 1'116 66.65 M 0.92 ug/ml Cl- 2 1'416 440.80 M 22.12 ug/ml

F4

~

~~ 

### l

~ 

### Ua1024.00OmV —102 . 4OOmV 

## Comaonent Retention
(unknown) 0. 

### F1- 1. C1- 1. 

## Area Extern

531.05 N/i 59.20 M 0.1 439.90 M 22.( 

## Conditions z 20 uglml C1— in NaOH Date = 05/21/2005 Time = 12.33=39

Component 

## Number Retention Area External Units F1— 1 1.133 

## 59.20 M 0.82 ug1m1 C1— 2 1.416 439.90 M 22.08 ug/m.l

2 499_10 22_90


# n r.

i~ i



# ~ 

# i

## AMOUNT INJECTED

AREfi 0.000 0.00



### 440.35+ 20.000 1

2

3

4

G 

# s Calibratian.file = Cl—_cal

Avg slnpe of curve= 22.02 Y--axa,s intercept- 0.00 

### f Cneff cf l.in regr = 0.79



## No. 'Rrea RmOunt CF



# ~ 0. 0.000 0.400 0.000



### 1- 92.050 5.000. 18.410 2: 202.275 10.000 20.227 3: 300.650 15.000 20.043 ' 4: 440.350 20.000 22.018



## A_ U a

### Conditionm : D 

### a ItiIm 5 

### c rubb 

### er Znlmt

~ 

### Run #1 Impo 3 & 4 : VoIume 300 Dilution 1//1 Date 05/21,/2005 Time : 13:08:04
-1O2'4OOmV 1024.(}O0mV COmDOnent Retention &re Extmm
(unkoonn) O
O- 1 746.80N Nlt

Component Cl- - - ' Numb e 

### r Re 

### tention Ar e 

### e E xt 

### mrmal Un1ts 2 1.433 940.80 M' 37.91 ug/ml - 1

~~~~

## Extern'; N! 

## N/
39 . : 

## Area 37.25
744.68 M
987.15 M --102 .400mV 

## Component Reten ' (unknown) 0. (unknown) 0.
Cl- 1.1 1024_QOOmV 

## Conditions : Daltile Scrubber Znlet

w Run #1 Imps 3& 4 = Volume 300 Dilution 1/1 Date = 05/21/2005 

## Time = 13=13=10

Component 

## Number Retention Area External Units Cl- 2 1.433 987.15 M 39.57 ug/ml

1 . 987_15 39.57

1 ~1Q24.aOQmV 

### —1Q2.4QbmV 

### Component Retention (unknown) 0.016{.... ...................

. I .....,..,.. ......... ....,.. I

~ 

### (unknown) 0.800
................ ~,~ 

## (unknown) 1 .300 .1:

~ Cl- 1.416 : ;a ir....... ...

....... 

## Area Extern 29.10 M/
790.63 M M/ 49.61 M N/, 

### 906.50 M 36.1 Conditions : [3altile Serubber Inlet

- Run #2 Imps 3 & 4 = Volume 300 Dilution 1/1 date = 05/21/2005 

### Time : 13:18=18

11



### Component 

## Number Retention Area . External Units 

## Cl- 2 1.416 906.50 h4 

### 36.68 ug/ml

1 ?1MINWO 36_68

< •i

~ 

### 6

### Conditions : DaItlle SoTubber Inlet : Run #2 Imps 3 & 4 : VoIume 300 Dilution 1/~1 Datm : 05~/21/2005 Time : 13:25:35
—1D2.40OmV Component Reten
(unkoowo) O. (unknowo) 1. Cl- 1. ' 1024'(}O0mV Arou Fxhmr

783.83H N/ 66.03H N/ 912.25 H 36.

Component Number Retmntion Arma External Wnits Cl— 2 1.416 912.25 M 36.89 ug/ml

1 912-25 36-89

~~~~

### 1024'OOOmV -102'4OOmV component ' t .
(unknown) O (unkmown) 1 

## Cl- 1 753.78H kN 110.WM NN 898.50 N 36.; Conditions : 0altile SoTubbmr Znlet

: Run #3 

### Impo 3 

### & 4 

### : Voluma 300Dilution 1y1 Date z 05/21/2005 Time - 13:30-:50

Compmnent Number Retentlon Are«u External Unito Cl- 2 1.433 893.50 M 36.22 ug/ml

1

## Conditions = Daltile Scrubber Inlet = Run #3 Imps 3 & 4 

### = 'Jolume 340 Dilution 1/1 Date = 05/21/2005 Time = 13:36=02
-102 .404mV 

### Component Rete


## (unknown) 0 (unknown) 1 Cl- 1 

## Area Extern

752.02 M 

## NI 92.64 M 

## NI 879.80 M 35. 

### 1024.00OmV

Component 

## Number Retention Area External Units Cl-- 2 1.433 879.80 M 35.73 ug/m].

1 879.80 35:73

~ 

### M t 

## L I

### Conditions z NaOH Blank Date : 05/21/2005 Time : 13:41:31
-102.400mV 1024.00OmV Component Reten
(unknown) 0.



### Component Number Retention Area External Units



### 541 rolwolti Area Extern

1004.65 NI;

.&-f 

## L-18

# Appendix D ~

### '7 1 ~ 

### A, 

## Fi rE LD 

# D ATA PLANT 

## REPFTiubj
~



## T: 

## - 6 

## IMPINGERS L OCATION (SOURCE 

## OPERATOR: SANIPLE 

## TR-AIN iiiitial Final METER BOX,,: BAROMETRIC PRESSURE: 43 

## t ANMI'ENT .a I 01D 

## 44 ASSUNIED 

## MOIS PROBE LENGTH: 

## 97 qO;7 NOZZLE DIAMETEI. 

## "'A STACK 

## DIAMETER:

METER H: l

, 

## 61bi l, CO2 02 

### C 

## FACTOR METER CO 

## FICIENT: FILTFR TARF:.,3gqo i57 07 

## PRE-TEST LEAK CHEi CK POST-TEST LEA-K CHECK 

## Meter:&?. C 9 ,5 

## cu.ft. @ 

## /-(In.. HG 

## Meter: 0 cuft CCD, 

## in. HG Pitot: iii; H20 Pitots., 

### c in. H20 

## ;4- u ijL n e- 

## u I.V. 'fr, Pli 

# E2L 21Y 

# q

Z,- 

# 6 'IA57 Z ,5

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# ' 

# t D 6'

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# z' I 2, 61 [~ 2.- 

# 1 1, o 0,3 

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# zz- 1 ` 31 

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# ~ ` 103 J 5 - 121 ~ 

# I V"D 

# T -T

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# o ~,~S~~ Uyn e1 

## F :CE 

## L D DATI
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### PLANT: k r J DATE: S ^

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### REPETITION:

~ 

### -- LOCATIQN (SOTJRCE -):SGrJ ~I~ ~~y` ~ ~ 

### IMPMGERS OPERATOR: SAMPLE TRA.IN n: ~ 

### Initial Final 1 1 /a ~ r~ -1r l,
~ cc i5`' 

### METER BOX

~ 

### : 

### l!7 %BA.ROMETRIC PRESSURE: ~ I ~2 ~ cx~ ~„I~ F `f ~ 

### Jl` r3 Le~~~ r/; 

### A"Ia,fBIENT TEMPERATURE: ASSUIviED MOISTLlRE: ? #5 2p o ~ 

### PROBE LENGTH: $ ~ 

### NOZZLE DL4 YIETER: - 

### r6 STACK DLA.II2ETER: METER H: /. S ~o~ 

### CO2 02 C FACTOR: ~ V~ : c~ 

### METER CO-EF'F{'YCIEN.T: j FILTER TARE: , 

### ~ 

# 7

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# Y ;` ~'~ PRE-TEST LEAK CHECK Meter: 6.oj7. , 

### cu.ft. , ~ . ~ j 

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### cu. 

# ft . @$" in. HG Pitots: `i/. (a7

~ /.Sf in_ H2(7 p7 in Tn(-1-

Ti=ne

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# I I I I

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### PLANT - 0 ' U4, I -

D A - jE: 

## REPETIT ION: 

## LOCALTION (SO UR CF 

## OPERATOR: "I

-1 SAMPLE 

## TRAIN t:7 - 

## NMTER BOX BAROMETRIC PRESSURE.
- Z5 AlvMIENT TEIVIPE
. RATURE: ASSUNMI) MOISTORE: 7 2) PROBE LENGTH: rr NOZZLE DIAETER: , 

# 3po

M STACK DIAMETFR:63 METER H: /I qo C 

## FACTOR: METER CO-E ' 

## FFICIENT--,'
~ 

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# TARE;o, , -3'

~ ,- 

# z-/ ( PRE-TES I T LEAK CHECK 

## Mete-r.0- 00 S
-- cult. @ - t o 

## in HG

P-1

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## 4U in. ' H20 Pitots: .14 ~ 

## FIELD DATA

IMPENGERS iiiitial Fiiial 

## I I oo 11 

## Is

- e -2 lo - 

## 0 43. 1 Llo ;) ki( 

### PA / 7U I t "
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CO2 02

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## f
POST-TEST LF 4 i cliECK Meter: 6 i& ~ cu.A. 5 - 7 in 

## HG Pitots.*_;

~ - - - in. k2G.

t



# H j l r t 

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# 11 06 1 .: 

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### Temperature Meter Calibrations



### Meter Box #: 10 Date: 02/21/05 Calibrated B : RT

Emtech Thermo 

### De rees F Checker Probe Stack Oven Exit Auxilla ry 

### Point 1 32 31 31 31 30 31 Point 2 212 210 210 210 210 210 Point 3 752 750 750 750 750 750

Emtech Thermo 

### De rees R Checker Probe Stack Oven Exit Auxilla Point 1 492 491 491 491 490 491 Point 2 672 670 670 670 670 670 Point 3 1212 1210 1210 1210 1210 1210

Percent Difference Probe Stack Oven Exit Auxilia ry Point 1 0.203252 0.203252 0.203252 0.406504 0.203252 Point 2 0.297619 0.297619 0.297619 0.297619 0.297619 Point 3 0.165017 0.165017 0.165017 0.165017 0.165017

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### Temperature tVfeter Ca{ibrations

Meter Box #: 11 Date: 03/03/05 

### Calibrated By: RT

Emtech Thermo Degrees F Checker Probe Stack Oven Exit Auxillary Point 1 32 29 30 29 30 30 Point 2 212 210 210 210 210 211 Point 3 752 750 751 750 751 751



### Emtech Thermo Degrees R Checker Probe Stack Oven Exit Auxiliary Point 1 492 489 490 489 490 490 Point 2 672 670 670 670 670 671 Point 3 1212 1210 1211 1210 1211 1211

Percent Difference 

### Probe Stack Oven Exit Auxiliary Point 1 0.609756 0.406504 0.609756 0.406504 0.406504 Point 2 0.297619 0.297619 0.297619 0.297619 0.14881 Point 3 0.165017 0.082508 0.165017 0.082508 0.082508

$ ~ ~

# Appendix 

# F



# Q

### Reference Standard

Description Expiration date Cylinder Number GMIS 1/19/2006 CC177157 * GMIS CC177157 Tracebility Description Expiration date Cylinder Number NTRM 6/1/2006 SG9199568 

### Instrumentation Description Modet # Date Last Clibrated Horiba Process Analyzer VIA-510-S02 6/15/2004 

### Anayisis Results: Z= zero gas, S= standard gas, X= sampfe gas 

# Specealty Gas Products

3106 Pasadena Freeway Pasadena,Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 7/13/2004 Customer: Matheson-Trigas Description: S02 in N2 - EPA Protocol Cy(inder No: CC88735 

### Requested Component

. Concentration Sulfur Dioxide 100ppm Nitrogen, Balance Project No: 9970 Exp. Date: 7/13/2006 Cylinder Pressure: 1900psig Certified Concentration 

### 101 ppm Accuracy 1%

Concentration 793.8ppm S02
Concentration 1997ppm S02 Principle NDIR



### First Triad - S02 Z1= -0.90 S1= 791.9 S2= 794.0 Z2= -0.70 Z3= -0.90 X3= 99.2 Curve: Y=1.971+0.999869*X Average = 100.6ppm Second Triad - S02 X1= 98.7 Z1= -0.90 S1= 794 X2= 99.0 S2= 793.2 Z2= -0.60 S3= 792.6 Z3= -0.60 X3= 99.30 Average =100.9ppm X1= 99.0 X2= 99.2 S3= 793.4

' Analyst

~ '_ Lin9 Wen--'
- 

## ~~

--~ 

### THIS STAN'D"AKU IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. ' DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG

# ■ -4 0

# ■

# I



# I 

# Specialty Gas Products 3106 Pasadena Freeway Pasadena,Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 7/13/2004 Customer: Matheson-Trigas Project No: 9969 Description: S02 in N2 - EPA Protocol Exp. Date: 7/13/2006 Cylinder No: CC177434 Cylinder Pressure: 1900psig Requested Certified Component Concentration Concentration Accuracy Sulfur Dioxide 50ppm 50.1 ppm 1% Nitrogen, Balance

Reference Standard Description Expiration date Cylinder Number Concentration NTRM 6/1/2006 Sg9135833 99.8ppm S02 Instrumentation Description Model 

### # Date Last Clibrated Principle Horiba Process Analyzer VIA-510-S02 7/7/2004 NDIR Anaytsis Results: Z= zero gas, S= standard gas, X= sample gas
First Triad 

### - S02 Second Triad 

### - S02 Z1= -1.30 S1= 999.90 X1= 502.60 Z1= -0.80 S1= 997.90 X1= 500.30 S2= 999.90 Z2= -0.70 X2= 503.60 S2= 998.70 Z2= -0.10 X2= 500.30 Z3= 0.00 X3= 503.60 S3= 999.90 Z3= -0.20 X3= 501.60 S3= 999.30 Curve: Y=0.0064+0.09986*X Average 

### = 50.15ppm Average =49.98ppm

Analyst: G LincyWeri THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSlG



## v

### ~ 

# Specialty Gas Prodacts 3106 Pasadena Freeway 

# I Pasadena,Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 11 /21 /2003 ( Customer: Trigas Project No: 5233-002 Description: CO in N2 - EPA Protocol Exp. Date: 11/21/2006



## ~ = Cylinder No: CC176566 Cylinder Pressure: 1900psig Requested Certified 

## ~ Component Concentration Concentration Carbon Monoxide 50ppm 47:3ppm Nitrogen, Balance ! Reference Standard 

### Description Expiration date Cylinder Number NTRM 7/1 /2006 SG9133548 

### s lnstrumentation 

## ~ ' Description Model # Date Last Clibrated Horiba Process Analyzer VIA-510-CO 11 /4/03 

### ' Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas First Triad - CO Second Triad - CO Z1= 0.00 S1= 97.30 X1= 47.10 Z1= 0.00 S1= 97.24 S2= 97.28 Z2= 0.00 X2= 47.08 S2= 97.20 Z2= 0.00 

## ~ Z3= 0.02 X3= 47.12 S3= 97.30 Z3= 0.00 X3= 47.18



## ~ Average = 47.19ppm Average = 47.38ppm 

### Accuracy 1%



### Concentration 97.3ppm CO

.- 501:

X1= 47.26 X2= 47.32 S3= 97.24

Analys t: -

> 

### THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES.

, i DO NOT USE THIS STANDARD iF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

# i

# Specialty Gas Products 3106 Pasadena Freeway 

### Pasadena, Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 11 /21 /2003 Customer: Trigas Project No: 5233-001 Description: CO in N2 - EPA Protocol Exp. Date: 11/21/2006 Cylinder No: CC176544 Cylinder Pressure: 1900psig Requested Certified Component 

### Concentration Concentration Accuracy Carbon Monozide 100ppm 105pprn 1% Nitrogen, Balance



### Reference Standard Description 

### NTRM Instrumentation Description Horiba Process Analyzer 

### Expiration date Cylinder Number Concentration 7/1 /2006 SG9133548 97.3ppm CO


### Model # Date Last Clibrated Principle VIA-510-CO 1114/03 NDIR 

### Anayisis Results: Z= zero gas, S= standard gas, X= sample gas First Triad - CO Second Triad - CO Z1= 0.00 S1= 97.30 X1= 105.36 Z1= 0.00 S1= 97.24 S2= 97.28 Z2= 0.00 X2= 105.34 S2= 97.20 Z2= 0.00 Z3= 0.02 X3= 105.40 S3= 97.30 Z3= 0.00 X3= 105.28 X1= 105.30 X2= 105.26 S3= 97.24 Average = 105.48ppm Average = 105.47ppm



### ~ Analyst:--=-- --- 3 

### ~ ' THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES.


### ~ DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG

, 

### ~-~ ;..1 f



# specialty Gas Products

3106 Pasadena Freeway Pasadena, Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 6/10/2004 Customer: Trigas , Project No: 9208 Description: NO in N2 - EPA Protocol Exp. Date: 6/10/2006 Cylinder No: CC143176 Cy(inder Pressure: 1900psig 

### Requested Certified Component Concentration Concentration Accuracy Nitric Oxide 50ppm 50.2 ppm 1% Nitrogen, Balance NOx = 51.3ppm
Reference Standard 

# ~ Description Expiration date Cylinder Number GMIS 4/14/2006 CC176941 Instrumentation

.


## ~ Description Model # Date Last Clibrated

Horiba Process Analyzer CLA-510SS 6/7/2004


# ~ Anayisis Results: Z= zero gat; S= standard gas, X= sample gas

First Triad - NO Second Triad - NO Z1= -1.40 S1= 990.3 X1= 483.90 Z1= -1.30 S1= 993.0 S2= 990.8 Z2= -1.50 X2= 482.50 S2= 993.6 Z2= -1.20 Z3= -1.50 X3= 480.50

, S3= 986.1 Z3= -1.40 X3= 483.80



## ~ Average = 50.16ppm Average = 50.21 ppm Cunre: Y = 0.416937 + 0.102986*X Concentration 97.3ppm NO Principle Chemi

X1= 485.50 X2=. 484.90 S3= 992.2

Analyst: THIS ST 

## ~ ;N

" DARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG 

# 0 

# i 1 ts 4Description Expiration date Cylinder Number

GMIS 4/14/2006 CC176941 Instrumentation Description Model 

### # Date Last Clibrated Horiba Process Anaiyzer CLA-510SS 6/7/2004 Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas First Triad 

### - NO Second Triad 

### - NO Z1= -1.40 S1= 990.3 X1= 886.60 Z1= -1.30 S1= 993.0 S2= 990.8 Z2= -1.50 X2= 885.90 S2= 993.6 Z2= -1.20 Z3= -1.50 X3= 883.30 S3= 986.1 Z3= -1.40 X3= 889.60 

# u Concentration 97.3ppm NO Principle Chemi

X1= 894.20 X2= 892.40 S3= 992.2 

# Specialty Gas Products

3106 Pasadena Freeway Pasadena, Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 6/10/2004 Customer: Trigas Project No: 9209 Description: NO in N2 - EPA Protocol Exp. Date: 6/10/2006 Cylinder No: SG880778 Cylinder Pressure: 1900psig Requested Certified Component Concentration Concentration Accuracy Nitric Oxide 90ppm 91.9 ppm 1% Nitrogen, Balance NOx = 92.8ppm

Reference Standard

Average = 91.7ppm Average = 92.05ppm Curve: Y = 0.416937 + 0.102986*X

' Analyst:

' THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG

# Specialty Gas Prodc.fcts 3106 Pasadena Freeway Pasadena,Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 6/7/2004


# ~ Customer: Trigas Description: Propane in Air - EPA Protocol


# ~ Cylinder No: CC177391 Requested Component Concentration Propane 50 ppm 

### Air, Balance Project: 9211-01 Exp. Date: 6/7/2007 Cylinder Pressure: 1900psig Certified Concentration 48.8 ppm 

### Accuracy 1%

' Reference Standard Description Expiration date Cy(inder Number 

# ~ NTRM 7/2/2004 SG9183302 

### Instrumentation Description Model # Date Last Clibrated 

# ~ Horiba Process Analyzer FIA-510 5/24/2004 

### Anayisis Results: Z= zero gas, S= standard gas, X= sample gas
' First Triad - Propane Z1= 0.60 S1= 207.90 X1= 97.60 S2= 207.70 Z2= 0.60 X2= 97.20 

# ~ Z3= 0.60 X3= 97.50 S3= 208.00 Curve: Y=-0.05085+0.501149"X Average = 48.78pm Concentration 103.6 ppm Propane 

### Principle 

### FIA

, , Analyst: C ----

✓ " 

### ~ . THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES.


### ~ DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG )



### ~ ~ 

# i~ 

# MAT H E S QN CE

~ 

# . '

~ 

# IFICATE dF ANAL3LSIS -EPA PRO'I`O COL. 1VIIXTU72E 

# TRt•GAS

R 

## 1650 Enterprise Parkway, Twinsburg, Ohici 44087 e 2 :1 5-648-4000

.:ustomer: MATHESON TRI-GAS - DALLAS pCyfinder Number: SX-36727 sylinder pressure: 2000 L-ast Analysis date: 8/7/2003

1 1Expiration Date: 8/7/06

Component : Propane Certified Conc: 15.2 ± 0.15 PPM .:. :.... '

~ Protocol: Reference # Lot AA G 1 262579 109— 36-31020 ' DO T

.

USE THIS.CYLINDER W. H1=,,;`: : P,RESSURE FALLS_BEL01N 1.:50 PSIG'-'.^_
REPLICATE RESPONSES Date: 8/7/2003 Date:

15.2 PPM >:15.2 PPM ` 15:1 PPM

, .:.. :. .... ... _

..... .;:;•;,. ....
. .::.:: :: •.: ... :;: ......,. ... - - 

### ALANCE GAS: Air

t2EFERENCE STANDARDS


### ~ Component:

~ ;• 

### ~ Propane : ::::.: .:.::.. :.::. : .:. . . : . .. ..::. :... ..: . ... .:.. : . ;.: ,:-.: :... ....:. SRM #: SRM-1.666b C linder #: Y Ca1-011826


### ~ Concentration: 9.73 ppm

IPERTIFICATION INSTRUMENTS

Component: Propane :.. Make/Model: Varian 3800 GC



### ~ Seri?I Number: LR-92489 Measurement Principle: TC, FID Last Calibration: 8/7/2003

ido 

## ~ es:



## ~ 

# l This certification was performed according to EPA Traceability Protocol for Assay & Certification of Gaseous 

### Calibration Standards September 1997, using procedure G1 and/or G2.

4


# ~ alyst_ A


### ~ • Date 

### 81812003



# ~



# ~

## i
! 

# 1' 

# SpeciaIty Gas Products 3106 Pasadena Freeway Pasadena,Texas 77503 (713) 534-8217 Fax(713) 534-8133 Date: 6/7/2004 Custorner: Trigas Description: Propane in Air - EPA Protocol Cylinder No: SX41680 Requested Concentration 

### 30 ppm Project: 9210-01 Exp. Date: 617/2007 Cylinder Pressure: 1900psig Certified Concentration 28.8 ppm 

### Accuracy 1% Component Propane Air, Balance

Reference Standard Description Concentration 

# ~ NTRM 7/2/2004 SG9183302 103.6 ppm Propane

Instrumentation

~ 

### Description Model # Date Last Ctibrated Principie Horiba Process Analyzer FIA-510 5/24/2004 FIA Anaylsis Results: Z= zero gas, S= standard gas, X= sample gas


# ~ First Triad - Propane Z1= 0.60 S1= 207.90 X1= 57.60 S2= 207.70 Z2= 0.60 X2= 57.50 

# ~ Z3= 0.60 X3= 57.40 S3= 208.00 Curve: Y=-0.05085+0.501149'X Average = 28.77pm



# ~
Analysj 

# ~ —. ~ ~-~
, ; THIS STANDARD IS NIST TRACEABLE. IT WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES. ; DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 150 PSIG



# ~

~ Expiration date Cylinder Number



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