# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City: State: Texas Zip Code: 77046

Country: US

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 575

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City: State: LA Zip Code: 70764

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 30 Houston 3 Greenway

Plaza, Suite 1150 Shintech Inc.

225-685-1199

jbell@shin-tech.com Shintech Louisiana, LLC - Plaquemine Plant

26270 Hwy

405 South River Road

Plaquem ine

James S. Bell

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER**

Process Unit ID: P-1

Process Equipment ID: P-WWS Wastewater Feed Rate (lb/hr): 23,681 Feed Temperature (°F): 180 Feed Inlet Pressure (psia): 24.7 Liquid Loading Rate (liters/m2): 13,257 SteamFeed Rate (lb/hr): 1,500 Steamto Feed Ratio (kg steam/liter of wastewater): 0.069 Operating Temperature (°F): 216 Operating Pressure (psig): 1.2 Total Number of Stages: 12 Overall Calculated Tray Efficiency: 0.998 Stripping Factor: Flow configuration (countercurrent, cocurrent): Countercurrent Number of Actual Trays: 12 Colum n Height (meters): 8.2

Year Equipm ent Installed: 2008 Equipm ent Currently

Regulated Under (cite regulations): 40 CFR 61.64(e); 65(b) and 40 CFR 63.43 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions**

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

40 CFR 61.64(e); 65(b) and 40 CFR 63.43 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: 10,742 liters/hour liters

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

22,710 liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary**November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater PVC Production Process Wastewater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3 4**  **5 6**  **7 8**  **9 10**  **11 12**  **13**

**Min Max**  **Average** P-1 P-Ca 88,000 198,000 165,000 Estimated 365 P-Ca PVC Slurry Centrifuge RECYC Plaquemine W astewater Treatment Yes P-1 P-Cb 88,000 198,000 165,000 Estimated 365 P-Cb PVC Slurry Centrifuge RECYC Plaquemine W astewater Treatment Yes P-1 P-Cc 88,000 198,000 165,000 Estimated 365 P-Cc PVC Slurry Centrifuge RECYC Plaquemine W astewater Treatment Yes P-1 P-Cd 88,000 198,000 165,000 Estimated 365 P-Cd PVC Slurry Centrifuge RECYC Plaquemine W astewater Treatment Yes

**Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5**  **6 7**  **8 9**  **10 11**  **12 13** 

**Min Max**  **Average** P-1 P-WWS Steam Stripping Continuous P-WWS 57,600 87,120 68,112 Measured 365 WWT Plaquemine W astewater Treatment Yes

**Table 3. PVC Process Wastewater Destination Codes Table Code**  Wastewater treatment system WWT Provide name of the wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall Discharge to POTW , no treatment POTW RAW Provide name of POTW Discharge to PrOTW , no treatment PrOTW RAW Provide name of PrOTW Zero discharge or alternative disposal method ZEROALT Describe method Recycle to process RECYC Describe where in the process the stream is recycled Other OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3 4**  **5 6**  **7**

**Min Max**  **Average** The Min, Max and Average are calculated from the 32 day campaign. **Operating Days Per Year**  **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process**  **equipment and its destination? Originating PVC Process**  **Equipment Description**

**PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Associated Destination Information** 

(Refer to Table 3 below) **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream**

Centrifuge water **PVC Process Wastewater**  **Stream ID**

Centrifuge water **Originating PVC Process Equipment ID**  **PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below) **Associated Destination Information**  **2**

**Flow Rate Determination**  **Method**

Centrifuge water **PVC Process Wastewater Stream Flow Rate (gallons per day)** 

Centrifuge water

**PVC Process Wastewater**  **Treatment System ID**  **Flow Rate Determination**  **Method Operating Days** 

**Per Year Type of Process**  **Wastewater Treatment System**  **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?**  **14**

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Destination Description** 

**PVC Process Wastewater**  **Treatment System ID**  **Operating Days Per Year**  **PVC Process Unit ID**  **PVC Process Wastewater**  **Stream ID Is this**  **process wastewater**  **treatment system batch** 

**or continuous**  **operation?**

**Flow Rate Determination**  **Method**

NA **PVC Process Wastewater Stream Flow Rate (gallons per day)** 

**Process Wastewater Stream Flow Rate**

**(gallons per day) 1** 

**Source of Process Wastewater Stream**

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s)**

107211 Ethylene glycol SW-846-8015C 4 Non-detect 4 Non-detect 4 Non-detect UJ 10 Non-detect UJ 67561 Methanol SW-846-8015C 57 J 58 J 58 J 62 J 75070 Acetaldehyde SW-846-8315A 4.98 J 5.4 5.37 5.29 50000 Formaldehyde SW-846-8315A 0.15 Non-detect UJ 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 51285 2,4-dinitrophenol SW-846-8270D 0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect 0.175 Non-detect 98862 Acetophenone SW-846-8270D 4.16 4.27 3.54 3.88 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 123319 Hydroquinone SW-846-8270D 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 108952 Phenol SW-846-8270D 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 106990 1,3-butadiene SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 540841 2,2,4-trimethylpentane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 71432 Benzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 108907 Chlorobenzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 67663 Chloroform SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 126998 Chloroprene SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 98828 Cumene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.01 J 0.01 0.011 0.01 100414 Ethylbenzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.031 0.037 0.036 0.041 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 74873 Methyl chloride (Chloromethane) SW-846-8260B 0.01 0.01 0.008 0.013 75092 Methylene chloride SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 110543 n-Hexane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 108883 Toluene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 79005 1,1,2-Trichloroethane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 108054 Vinyl acetate SW-846-8260B 0.002 Non-detect R 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 593602 Vinyl bromide SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 75014 Vinyl chloride EPA Method 107 0.015 J 0.02 0.03 0.023 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B 0.57 0.638 0.582 0.673 **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->**  Suspension Suspension Suspension Suspension

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) -->**

SP-PL-1-1 130029-1 SP-PL-1-2 SP-PL-1-3 SP-PL-1-4 130029-4 130029-5 130029-6 **1**

215.6 42.6 01/03/13 **2**

45.8 44 43.6 **3**

216.1 **4** 01/04/13 01/05/13

216 216 01/06/13

**Flow Rate Determination Method -->** Measured Measured Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect UJ 10 Non-detect UJ 10 Non-detect UJ 10 Non-detect UJ 63 J 69 J 63 J 57 J 4.25 5.62 6.08 5.92 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect UJ 1.75 4.6 4.71 2.97 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.01 0.014 0.002 J 0.003 J 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.024 0.032 0.03 0.024 0.001 Non-detect 0.002 J 0.001 Non-detect 0.002 Non-detect 0.007 0.008 0.003 J 0.004 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.02 0.043 0.008 J 0.05 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.266 0.487 0.723 0.641 Suspension Suspension Suspension Suspension

SP-PL-1-5 SP-PL-1-6 130029-7 130029-8 SP-PL-1-7 Measured Measured

SP-PL-1-8 215.6 215.6 49.9 59.3 **5 7**  **8**

43.4 **6**

Measured 215.8 215.1 60.5 01/07/13 01/08/13 01/09/13 01/10/13

130029-9 130029-10 Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect 41 J 50 J 61 J 63 J 5.38 5.61 4.64 5.68 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect UJ 3.37 3.44 4.24 3.19 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.014 0.013 0.019 0.009 J 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.065 0.035 0.032 0.028 0.002 Non-detect 0.002 Non-detect 0.002 J 0.002 Non-detect 0.016 0.013 0.01 0.007 J 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect UJ 0.002 Non-detect UJ 0.001 Non-detect UJ 0.002 Non-detect UJ 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.048 0.057 J 0.104 J 0.021 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.895 0.583 0.519 0.658 01/12/13 01/13/13 01/14/13 Suspension Suspension Suspension

Measured Measured

SP-PL-1-10 214.7 Measured

SP-PL-1-9 SP-PL-1-12 50.2 Suspension 47..5 47 **9 10**  **12 11** 

215.6 215.1 01/11/13

215.4

130029-11 130029-12 Measured

130029-14 SP-PL-1-11 130029-13 54.3

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect 65 J 56 J 86 J 49 J 5 4.2 4.98 6.18 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 3.51 3.43 4.3 4.34 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect R 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.015 0.016 0.011 0.008 J 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.034 0.032 0.038 0.038 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.008 J 0.01 J 0.009 J 0.009 J 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect UJ 0.002 Non-detect R 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.025 0.045 0.035 0.027 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.692 0.452 0.604 0.856 **16**

Suspension Suspension Suspension Suspension **13 14**  01/15/13 **15** 01/16/13 01/17/13 01/18/13

47.2 Measured Measured 47.2 Measured

130029-15 215.4 216 214.7 Measured

SP-PL-1-16 SP-PL-1-15 130029-16 130029-17 SP-PL-1-13 SP-PL-1-14 130029-20 49.3

216.3 50.8

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect 55 J 60 J 61 J 52 J 4.09 5.33 5.9 7.81 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 3.43 3.75 3.96 4.08 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.021 0.018 0.014 0.003 J 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.028 0.028 0.027 0.006 0.001 J 0.001 J 0.001 Non-detect 0.001 Non-detect 0.01 0.01 0.009 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.099 J 0.082 J 0.042 0.047 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.365 0.363 0.36 0.085 **19 20**  01/21/13 01/22/13 **17 18** 

Suspension Suspension Suspension Suspension

Measured Measured 01/19/13 01/20/13

Measured Measured

130029-21 130029-22 130029-23 SP-PL-1-17 SP-PL-1-18 SP-PL-1-19 SP-PL-1-20 130208-1 215.6 215.8 44.1 45 45.5 44.7

215.6 215.8

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect 56 J 53 J 56 J 57 J 8.31 6.55 5.06 4.96 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 4.47 3.99 4.1 4.61 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.003 J 0.002 Non-detect 0.011 0.01 0.008 J 0.01 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.038 0.044 0.025 0.039 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.009 J 0.01 J 0.004 Non-detect 0.007 J 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect UJ 0.002 Non-detect UJ 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.03 0.041 0.073 J 0.02 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.58 0.574 0.538 0.6 **21** 01/23/13 01/24/13 Suspension Suspension 46 46.2

216.1 Measured 215.8

130208-5 48.1

216 215.8

130208-2 SP-PL-1-21 SP-PL-1-22 SP-PL-1-23 SP-PL-1-24 130208-3 130208-4 **22 23**  **24**

Suspension Suspension 01/26/13

Measured Measured 01/25/13

Measured 43.1

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect 60 J 60 J 56 J 65 J 5.07 5.08 4.01 5.86 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 3.83 5.02 4.22 4.78 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.007 0.011 0.018 0.012 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.021 0.036 0.035 0.06 0.001 Non-detect 0.002 Non-detect 0.001 J 0.002 Non-detect 0.004 J 0.006 J 0.008 0.008 J 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.037 0.03 0.091 J 0.058 J 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect 0.356 0.59 0.454 1.13 215.6

130208-6 SP-PL-1-25 **25**

Measured Suspension 01/27/13

48.2 52.9

215.8 215.4 214.9

130208-8 130208-9 **27 28**  01/28/13 01/29/13 01/30/13 **26**

Suspension Suspension Suspension

SP-PL-1-26 SP-PL-1-27 SP-PL-1-28 130208-7 Measured 46.2 45 Measured Measured

### November 8, 2012 CA **A Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastew** **ater PVC Production Process Wastew** **ater Sampling and A nalysis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** Shintech Inc. **Facility** Shintech Louisiana, LLC - Plaquemine Plant **PVC Process Wastewater Treatment System ID** P-WWS

**CAS No. HAP**  **Analysis Method**

107211 Ethylene glycol SW-846-8015C 67561 Methanol SW-846-8015C 75070 Acetaldehyde SW-846-8315A 50000 Formaldehyde SW-846-8315A 51285 2,4-dinitrophenol SW-846-8270D 98862 Acetophenone SW-846-8270D 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 123319 Hydroquinone SW-846-8270D 108952 Phenol SW-846-8270D 79345 1,1,2,2-tetrachloroethane SW-846-8260B 106990 1,3-butadiene SW-846-8260B 540841 2,2,4-trimethylpentane SW-846-8260B 71432 Benzene SW-846-8260B 108907 Chlorobenzene SW-846-8260B 67663 Chloroform SW-846-8260B 126998 Chloroprene SW-846-8260B 98828 Cumene SW-846-8260B 75003 Ethyl chloride (Chloroethane) SW-846-8260B 100414 Ethylbenzene SW-846-8260B 107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 74873 Methyl chloride (Chloromethane) SW-846-8260B 75092 Methylene chloride SW-846-8260B 110543 n-Hexane SW-846-8260B 108883 Toluene SW-846-8260B 71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 79005 1,1,2-Trichloroethane SW-846-8260B 108054 Vinyl acetate SW-846-8260B 593602 Vinyl bromide SW-846-8260B 75014 Vinyl chloride EPA Method 107 75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 1330207 Xylenes (isomers and mixtures) SW-846-8260B 108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B **Resin Type (suspension, dispersion, bulk, etc.) --> Sample Date -->** 

**Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  **Stream Flow Rate (gallons per minute) --> Flow Rate Determination Method -->** 

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports

**Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)** 

10 Non-detect UJ 10 Non-detect 53 J 53 J 4.05 5.17 6.17 0.15 Non-detect 0.568 0.431 J 0.175 Non-detect 0.175 Non-detect 4.79 3.49 0.125 Non-detect 0.125 Non-detect 0.25 Non-detect 0.25 Non-detect 0.025 Non-detect 0.025 Non-detect 0.002 Non-detect 0.001 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.01 0.036 0.002 Non-detect 0.001 Non-detect 0.024 0.044 0.002 Non-detect 0.002 J 0.004 Non-detect 0.014 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect UJ 0.001 Non-detect UJ 0.002 Non-detect 0.001 Non-detect 0.046 J 0.182 J 0.223 J 0.002 Non-detect 0.001 Non-detect 0.004 Non-detect 0.002 Non-detect 0.315 0.368 Measured Suspension Suspension **29 30**  01/31/13 02/01/13

44 40

SP-PL-1-29 SP-PL-1-30 215.6 216 Measured

130208-10 130208-11 **31** 02/02/13 Suspension 44.9 Measured 215.8

130208-12 SP-PL-1-31