p 

# MOR-FREETM 139 0 A / M OR-FREE C-33
Sol v entl ess Lam i nati ng A dhesi v e

D e s c r i ption M o r

- F r ee 13 90 A + Mor

- F r e e C- 33 is a s o lv ent le s s , t w o c o m ponent, po l y ur et han e a dhes iv e s y s t em w h ic h is app li ed at l o w t e m per a t ur e. T h is a d h e s i ve s y s t em is us e d f o r f ilm / f ilm r e tortapp lic at ions

. T h is adhes ive

s y s t em is patente d , U. S. P a tent Num ber 5,73 1,0 9 0.

T y p i cal Pro p ert i e s * ( P ol y e s t er ) ( I s o c y ana t e ) M o r- F r ee 1 3 90 A M o r- F r ee C- 33 S o l i ds 100% 100% V i sco si t y 77 ° F 3700 c p s 1800 - 400 0 c p s W e ight/G allo n 9.85 lb 9.75 lb A p p ear anc e Clear

, Ye ll o w Clear Odor ------ -- P r acti cal l y n one------- M i x i n g Ra tio 100 pb w 100. 0 pb w 100 pb v 100. 0 pb v S h e l f Lif e 360 da y s 360 da y s ( u nope ned c o nta i n e r s )

*T hes e item s ar e pr ov ide d f o r gen eral inf o r m atio n on l y

. T h e y ar e approx im ate va lues an d ar e not

cons ider e d p a rt of a pr od uc t s pec if icati on.

M o r

- F r ee 13 90 A + Mor

- F r e e C- 33 m a y r eac t or in ter a c t w i t h ot her c o m ponents of l a m i nations. Reta in ed

v o lat iles ( s ol v e nts or water ) , s lip ad d i t i v e s , an tib l oc k agents an d i n k s are s o m e of the c o m pon ents th at

m a y c aus e p r opert y c h a n g e s of the l a m i nated str u c t ur e. If Mor

- F r ee 1 3 90 A + M o r- F r ee C- 33 i s us e d o n h i g h s l i p f ilm s ( C O F < 0.2) or with high s l ip LD P E / L DP E l a m i natio ns , th e n th e us e r m u s tver i fy th at p o te nti a l f ilm pr opert y c h an ges du e to the lam i n a ti on p r oc e s s and m a te r i als

, ar e a c c eptabl e f o r the end

u s e per f o r m a n c e r equir e m ents

.

P r o c essin g M o r

- F r ee 13 90 A + Mor

- F r e e C- 33 m u s tbe us e d on m a c h in es w h ic h ha ve bee n s p ec ia ll y d e s i g ned f o r solv ent les s la m i nati ons

. S u c h eq uip m ent a llo w s the a dhesi v e to b e f e d thr o ugh a m e ter / m i x / d i s pens e d e v i c e a nd p r ov ides web t e ns ion c o ntr o ls des ig ned f o r adhe s i v e s w i t h l o w i n it ia l ta ck

.

M o r

- F r ee 13 90 A + Mor

- F r e e C- 33 cur e s s u f f i c i e n t l y f o rf u rt h e r pr oc es sing in 5 - 7 d a y s @ 2 5 o C

. A v o i d h o t

r o om c u r e f o r f i r s t 48hou r s . Al lo w 14 da y s c u r e @ 25 o C be f o r e r e tort in g

.

P r ehe ati ng t h e adh es iv e a n d c o r eactan tis n o t re quir e d und er nor m a l u s e to lo wer the vis c o s i t y . T he

a p p lic at ion r o l l s s hou ld b e heat ed t o ap pr ox im a t el y 11 0 ° - 1 3 0°F or hi g her dep en d i n g on l i ne sp eed

.

W h en pr oc ess i ng M o r

- F r e e 139 0A + Mor

- F r ee C- 33 , th e s a f e t y r u les f o r wor k ing with is oc y a n a t e s

m u s tbe obs e r ved

.

For s hort tr ia l r uns t he ad h e s i v e c a n be b a tc h m i x ed. W e r e c o m m end pr epar a t io n of no m o r e adhes iv e th an c a n b e u s ed w i t h i n 5- 1 0 m i nute s . Ho wev e r , th e u s e o f a m e ter / m i x / dis pens e dev ic e which contin uous l y m i x e s the a d h e s i v e at the c h os en r a t i o, c ontr o ls t he f eed in g of the a p pl ic ati on un i t, a nd s t o p s p r oduc ti on au tom a tic a l l y i n c a s e of m a c h ine f a ilur es , is ind i spe n s abl e fo r ex tend ed tr ials and n o r m al

r oduc ti on.

Mor

- F r ee 139 0A /C -33 J u n e 2 007 Page 1 of 5 

# PACKAG ING AN D BUILDIN G MATE RIALS

ADHESIVE S AND SE ALA N TSCleaning Dep endin g o n the desi gn of the meter/mix/dispen se unit, it should be clea ned b e fore the ad h e sive become s insoluble by pro g re ssive cu ri ng, if the machine sto p s for more than 1 5 minutes. M e thylene chlo ride can be used to flush the mixing and meteri ng units wh ere a non-fla mma ble solve n t is requi re d. Con s ult the Material Safe ty Data Sheet from the methylene chlori de su pplie r for safe h andlin g.

If the applicat ion unit and mixing device are co mbu s ti on pro o f, they may be clea ned with e s te rs o r keton e s su ch as ethyl acet ate and MEK.

Several com m ercially avai lable solvents are saf e and effective for flushi ng an d cl eanin g Mor-F r ee adhe sive re si due s from sol v entless lami nators and m e ter/mix/disp ensi ng eq uip m ent that do not have comb ustio n p r oof ratin g s. We recomme nd co ntactin g either Dynal oy , Inc. (800-669-570 9; www.dynal oy.com ) o r Dan k o Indu strie s (630 -8 82-607 0) for cl eani n g solvent re commen dation s . Always

con s ult the solvent sup p lie r’s MSD fo r safety information before use.

Safet y , Hand lin g and Stor age

• Mor-Fre e 139 0A and its co reacta nt can b e store d fo r 6 months in ai rtight, close d , origin al co nta i ners in dry room s at temperatu r es of 70 ° F±1 5 ° F. Ope ned contai ners sh ould be u s e d as qui ckly as possibl e.

• Store in a wel l ventilated area awayfrom heat and igni tion sou r ces.

• Follow g ood manufa c turi n g and ha ndlin g pra c tice s.

• Wa sh tho r ou ghly after han dling. Wa sh contami nated goggle s , face shiel d , and gloves. Professio nall ylaunder con t aminated cl o t hing before re-u se.

• ATTENTIO N! Containe r can be ha za rd ous whe n em pty. Follow label wa rnin gs even after co ntainer is empty. Do not reu s e em pty c ontaine r without pr ofe ssi onal cleani ng.

• Refer to Mate rial Safety Da ta Sheet for more info rma t ion.

Mor-F r ee 13 90A / C -33 Jun e 20 07 P a ge 2 of 5

### P o tL i f e Cu rv e @ 130 ° F ( 54.4° C) M o r- F r ee 139 0A + C- 33 (100: 100 p b w )

0 2000 4000 6000 8000 10000 12000 14000

0 5 10 15 20 25 30

T i m e , M i nut e sViscosity, CPS



### T e mp erat u r e vs. V i sco si t yCu rve M o r- F r ee 1390A + C- 33 ( 100: 100 p b w )

0 500 1000 1500 2000 2500 3000 3500 4000 4500 5000

90 100 110 120 130 140

T e mp er at u r e o f M i xt u r e, °FViscosity,CPS

Mor-F ree is a reg i stered tradema r k of Rohm and H aas Compan y. These suggestions and data ar e based on inform at ion we believe to be reliable. T h e y a r e offe red i n good faith, but w i thout guarantee , as conditions and method of use of ou r products are b e y ond ou r control. We recommend that the pr ospective user determine the sui t ability of ou r mat e rials and sugges tions before ado pting them on a c o mmercial scale.

Suggestions for uses of our pro d u cts or the inclusion of descriptive material from pa tents and the citation of specific p a tents in this publication should not be und erst ood as recomme nding the use of our pr o ducts in violation of an y pa t ent or as pe rmission or lic ense to use an y p a tent s of the Rohm an d Haas Compan y.

V i sit us at htt p :/ /ww w .rohmhaa s

. c o m /A dhe siv e sS eal ant s R ohm a n d H a a s C o mpa n y , Midw e s t T e ch nic a l C ent er, 25 31 T e c h n o lo gy D r i v e, S u ite 30 1, E l g i n, IL 6 0 1 2 4 P hon e: 84 7- 64 9- 380 0 F a x : 847 -6 49- 37 60

Mor-F r ee 13 90A / C -33 Jun e 20 07 P a ge 3 of 5

### Rohm and Haas Foo d and Drug Opinion

Product Na me: MOR-F R EE(TM) 13 90A

Regula t ion Number Complies Limitations Opinion Date 21CF R 1 75.1 0 5 Y May 04, 2000 21CF R 1 75.3 0 0 Y Aug 09, 2000 21CF R 1 77.1 3 9 0 A 1 May 04, 2000

Paragraph (c )(2)(ii)

21CF R 1 77.1 395 A 1 Aug 09, 2000

Legend : A Affirmed as compliant ba sed on mig r ati on studi es Y Yes, this prod uct is cl eared

.

Limitations : 1 A = AFFIRMED AS COMPLIANT BASED UPON MIGRATION STUDIES. THE CO MBINATION O F MOR-F R EE 1390A/MO R -FREE CO RE ACTANT C-33 MAY BE USED AS AN ADHESI V E LAYER IN MULTILAMI N ATE FOOD PACKAGING MATERIALS WITH ALL FOOD TYPES AND WITH NO LIMITATI ONS AS TO THE T YPE OF FOOD-CONTACT LAYER USED IN C O MPLIANCE WITH T H E F E DERAL FO OD, D R U G , AND COSMETIC ACT.

Regula t ions :

21CF R 175. 105 ADHESIVES 21CF R 175. 300 RESINO US AND POLYM E RIC C O ATINGS 21CF R 177. 1390 LAMINATE STRUCT URES FOR USE AT TEMPERATURES OF 250F AND ABOVE 21CF R 177. 1395 LAMINATE STRU CT U R ES FOR U SE AT TEMPERATURES BETWEEN 120F AND 25 0F

Disclaimer: This informati on rel a tes specifically to th is product. We believe this information to be accu rate a nd relia ble a s of this date. We recomm end that our customers make their own det ermi nation on the suitability of this prod uct for their part i cula r appli c at ion. We cann ot guara n tee that the indire ct food additive s/food-co ntac t status of this prod uct will remai n un ch ange d ind e finitely; therefore we re co mmend th at you perio dically verify its status.

Mor-F r ee 13 90A / C -33 Jun e 20 07 P a ge 4 of 5

### Rohm and Haas Foo d and Drug Opinion

Name: MOR-FREE (T M) C-33



### Regulation Com p lies 

### Opinion Date Limitations

21CF R 175.1 0 5 L 09/24/2001 ▪ FOR USE ONLY IN T H E P R EPARAT ION OF POLYURET H ANE RESINS.
21CF R 177.1 3 9 0 A 02/02/2006 ▪ A = A FFIR M ED AS COMPLIANT BA SED UPON MIGRA T ION ST UDIES. T H E COMBINATION OF MOR-FREE 1390A/M OR-FREE C-33 MAY BE USED AS AN A D HESIVE LAY E R IN MULT ILAMINA T E FO OD P A CKA GING M A T E RIALS WIT H ALL FOOD T YPES AND WIT H NO LIMIT A T I ONS AS T O T H E TYPE OF FOOD-CON T A CT LAYER USED IN COMPLIANCE WITH T H E FEDERAL FOOD, DRUG, AND COSMET IC ACT

.

▪ T he combi nat ion of Mor-F re e L75 X15 4 /Mo r-F ree C-33 m a y be used as a n ad hesiv e la yer i n multilam i n a te food p a cka gin g materials

w i t h all fo od t y pes an d w i th n o limitati ons as to the type of foodcontact la yer u s ed in com p li a n ce w i th the F e dera l F ood, Dr ug, and Cosmetic Act.
21CF R 177.1 3 9 5 A 02/02/2006 ▪ In accorda n c e w i t h the lim itations as d e scr ibe d un der 21CF R 177.1 3 9 0 abov e. 21CF R 177.1 6 8 0 L 09/24/2001 ▪ FOR USE ONLY IN T H E P R EPARAT ION OF POLYURET H ANE RESINS.



### Legend:
L Yes, this prod uct is cleared w i t h limitatio n s noted N No, this prod u c t is not cleared Y Yes, th is p r o d u c t is cleared

. A Af fir m ed as c o mp lian t b ase d o n mig r ation stu d i es.



### Regulations: 21CF R 175.1 0 5 A d h esi v e s 21CF R 177.1 3 9 0 L a min a te stru ctu r es fo r u s e at temp eratu r es o f 250F an d ab o v e 21CF R 177.1 3 9 5 L a min a te stru ctu r es fo r u s e at temp eratu r es b e tw een 120F an d 250F 21CF R 177.1 6 8 0 Poly ure t ha ne re s i ns



### Disclaimer: This information rel a te s sp ecifi c ally to this prod uct. We believe this informati on to be accu rate and reliabl e as of this date. We re com m end that ou r cu stome r s make thei r o w n dete r min a t ion on the su itability of this produ ct for their pa rticul a r appli c ation. We can n o tguarante e that the indire ct food addi ti ves/food-co ntact statu s of this produ ct wi ll remain unchan ged in definitely; therefore we recommen d that you perio dica lly verify its status

Mor-F r ee 13 90A / C -33 Jun e 20 07 P a ge 5 of 5