November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City: State: Texas Zip Code: 77046

Country: US

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): 575

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City: State: LA Zip Code: 70764

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 30

Houston

3 Greenway Plaza, Suite 1150

Shintech Inc.

225-685-1199

jbell@shin-tech.com

Shintech Louisiana, LLC - Plaquemine Plant

26270 Hwy 405 South River Road

Plaquemine 

James S. Bell
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P-1

Process Equipment ID: P-WWS

Wastewater Feed Rate (lb/hr): 23,681

Feed Temperature (°F): 180

Feed Inlet Pressure (psia): 24.7

Liquid Loading Rate (liters/m2): 13,257

Steam Feed Rate (lb/hr): 1,500

Steam to Feed Ratio (kg steam/liter of wastewater): 0.069

Operating Temperature (°F): 216

Operating Pressure (psig): 1.2

Total Number of Stages: 12

Overall Calculated Tray Efficiency: 0.998

Stripping Factor:

Flow configuration (countercurrent, cocurrent): Countercurrent

Number of Actual Trays: 12

Column Height (meters): 8.2

Year Equipment Installed: 2008

Equipment Currently Regulated Under (cite regulations): 40 CFR 61.64(e); 65(b) and 40 CFR 63.43 

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

); 65(b) and 40 CFR 63.43 

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 10,742 liters/hour

 liters

m design rate or capacity, please provide those values:

22,710 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 P-Ca 88,000 198,000 165,000 Estimated 365 P-Ca PVC Slurry Centrifuge RECYC Plaquemine Wastewater Treatment Yes

P-1 P-Cb 88,000 198,000 165,000 Estimated 365 P-Cb PVC Slurry Centrifuge RECYC Plaquemine Wastewater Treatment Yes

P-1 P-Cc 88,000 198,000 165,000 Estimated 365 P-Cc PVC Slurry Centrifuge RECYC Plaquemine Wastewater Treatment Yes

P-1 P-Cd 88,000 198,000 165,000 Estimated 365 P-Cd PVC Slurry Centrifuge RECYC Plaquemine Wastewater Treatment Yes

Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1 P-WWS Steam Stripping Continuous P-WWS 57,600 87,120 68,112 Measured 365 WWT Plaquemine Wastewater Treatment Yes

Table 3. PVC Process Wastewater Destination Codes Table

Code

Wastewater treatment system WWT Provide name of the wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall

Discharge to POTW, no treatment POTWRAW Provide name of POTW

Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW

Zero discharge or alternative disposal method ZEROALT Describe method

Recycle to process RECYC Describe where in the process the stream is recycled

Other OTHER Describe

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5 6 7

Min Max Average

The Min, Max and Average are calculated from the 32 day campaign.

Operating Days Per 

Year

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process 

equipment and its destination?

Originating PVC Process 

Equipment Description

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 

below)

Associated Destination 

Information

(Refer to Table 3 below)

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

Centrifuge water

PVC Process 

Wastewater 

Stream ID

Centrifuge water

Originating PVC Process 

Equipment ID

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination 

Information

2

Flow Rate 

Determination 

Method

Centrifuge water

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Centrifuge water

PVC Process 

Wastewater 

Treatment 

System ID

Flow Rate 

Determination 

Method

Operating Days 

Per Year

Type of Process 

Wastewater 

Treatment System

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

Destination Description Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

PVC Process 

Wastewater 

Treatment 

System ID

Operating Days 

Per Year

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or 

continuous 

operation?

Flow Rate 

Determination 

Method

NA

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

Process Wastewater Stream Flow Rate 

(gallons per day)

1

Source of Process Wastewater Stream
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

CAS No. HAP Analysis Method Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

107211 Ethylene glycol SW-846-8015C 4 Non-detect 4 Non-detect 4 Non-detect UJ 10 Non-detect UJ

67561 Methanol SW-846-8015C 57 J 58 J 58 J 62 J

75070 Acetaldehyde SW-846-8315A 4.98 J 5.4 5.37 5.29

50000 Formaldehyde SW-846-8315A 0.15 Non-detect UJ 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

51285 2,4-dinitrophenol SW-846-8270D 0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect 0.175 Non-detect

98862 Acetophenone SW-846-8270D 4.16 4.27 3.54 3.88

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

123319 Hydroquinone SW-846-8270D 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

108952 Phenol SW-846-8270D 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

79345 1,1,2,2-tetrachloroethane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

106990 1,3-butadiene SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

540841 2,2,4-trimethylpentane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

71432 Benzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

108907 Chlorobenzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

67663 Chloroform SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

126998 Chloroprene SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

98828 Cumene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

75003 Ethyl chloride (Chloroethane) SW-846-8260B 0.01 J 0.01 0.011 0.01

100414 Ethylbenzene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B 0.031 0.037 0.036 0.041

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

74873 Methyl chloride (Chloromethane) SW-846-8260B 0.01 0.01 0.008 0.013

75092 Methylene chloride SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

110543 n-Hexane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

108883 Toluene SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

79005 1,1,2-Trichloroethane SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

108054 Vinyl acetate SW-846-8260B 0.002 Non-detect R 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

593602 Vinyl bromide SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

75014 Vinyl chloride EPA Method 107 0.015 J 0.02 0.03 0.023

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B 0.002 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

1330207 Xylenes (isomers and mixtures) SW-846-8260B 0.004 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B 0.57 0.638 0.582 0.673

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Suspension Suspension Suspension Suspension

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

SP-PL-1-1

130029-1

SP-PL-1-2 SP-PL-1-3 SP-PL-1-4

130029-4 130029-5 130029-6

1

215.6

42.6

01/03/13

2

45.8 44 43.6

3

216.1

4

01/04/13 01/05/13

216 216

01/06/13

Flow Rate Determination Method --> Measured Measured Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect UJ 10 Non-detect UJ 10 Non-detect UJ 10 Non-detect UJ

63 J 69 J 63 J 57 J

4.25 5.62 6.08 5.92

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect UJ

1.75 4.6 4.71 2.97

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.01 0.014 0.002 J 0.003 J

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.024 0.032 0.03 0.024

0.001 Non-detect 0.002 J 0.001 Non-detect 0.002 Non-detect

0.007 0.008 0.003 J 0.004 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.02 0.043 0.008 J 0.05

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.004 Non-detect

0.266 0.487 0.723 0.641

Suspension Suspension Suspension Suspension

SP-PL-1-5 SP-PL-1-6

130029-7 130029-8

SP-PL-1-7

Measured Measured

SP-PL-1-8

215.6 215.6

49.9 59.3

5 7 8

43.4

6

Measured

215.8 215.1

60.5

01/07/13 01/08/13 01/09/13 01/10/13

130029-9 130029-10

Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect

41 J 50 J 61 J 63 J

5.38 5.61 4.64 5.68

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect UJ 0.175 Non-detect UJ

3.37 3.44 4.24 3.19

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.014 0.013 0.019 0.009 J

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.065 0.035 0.032 0.028

0.002 Non-detect 0.002 Non-detect 0.002 J 0.002 Non-detect

0.016 0.013 0.01 0.007 J

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect UJ 0.002 Non-detect UJ 0.001 Non-detect UJ 0.002 Non-detect UJ

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.048 0.057 J 0.104 J 0.021

0.002 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.895 0.583 0.519 0.658

01/12/13 01/13/13 01/14/13

Suspension Suspension Suspension

Measured Measured

SP-PL-1-10

214.7

Measured

SP-PL-1-9 SP-PL-1-12

50.2

Suspension

47..5 47

9 10 11 12

215.6 215.1

01/11/13

215.4

130029-11 130029-12

Measured

130029-14

SP-PL-1-11

130029-13

54.3
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect

65 J 56 J 86 J 49 J

5 4.2 4.98 6.18

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect

3.51 3.43 4.3 4.34

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect R 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.015 0.016 0.011 0.008 J

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.034 0.032 0.038 0.038

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.008 J 0.01 J 0.009 J 0.009 J

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect UJ 0.002 Non-detect R 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.025 0.045 0.035 0.027

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.692 0.452 0.604 0.856

16

Suspension Suspension Suspension Suspension

13 14

01/15/13

15

01/16/13 01/17/13 01/18/13

47.2

Measured Measured

47.2

Measured

130029-15

214.7 215.4 216

Measured

SP-PL-1-15 SP-PL-1-16

130029-16 130029-17

SP-PL-1-13 SP-PL-1-14

130029-20

49.3

216.3

50.8
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect

55 J 60 J 61 J 52 J

4.09 5.33 5.9 7.81

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect

3.43 3.75 3.96 4.08

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.021 0.018 0.014 0.003 J

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.028 0.028 0.027 0.006

0.001 J 0.001 J 0.001 Non-detect 0.001 Non-detect

0.01 0.01 0.009 0.002 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect UJ

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.099 J 0.082 J 0.042 0.047

0.001 Non-detect 0.001 Non-detect 0.001 Non-detect 0.001 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.365 0.363 0.36 0.085

19 20

01/21/13 01/22/13

17 18

Suspension Suspension Suspension Suspension

Measured Measured

01/19/13 01/20/13

Measured Measured

130029-21 130029-22 130029-23

SP-PL-1-17 SP-PL-1-18 SP-PL-1-19 SP-PL-1-20

130208-1

215.6 215.8

45 45.5 44.7 44.1

215.6 215.8
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect

56 J 53 J 56 J 57 J

8.31 6.55 5.06 4.96

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect

4.47 3.99 4.1 4.61

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.002 Non-detect 0.002 Non-detect 0.003 J 0.002 Non-detect

0.011 0.01 0.008 J 0.01

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.038 0.044 0.025 0.039

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.009 J 0.01 J 0.004 Non-detect 0.007 J

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect UJ 0.002 Non-detect UJ 0.002 Non-detect 0.002 Non-detect

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.03 0.041 0.073 J 0.02

0.002 Non-detect 0.002 Non-detect 0.002 Non-detect 0.002 Non-detect

0.004 Non-detect 0.004 Non-detect 0.004 Non-detect 0.004 Non-detect

0.58 0.574 0.538 0.6

21

01/23/13 01/24/13

Suspension Suspension

46 46.2

216.1

Measured

215.8

130208-5

48.1

216 215.8

130208-2

SP-PL-1-21 SP-PL-1-22 SP-PL-1-23 SP-PL-1-24

130208-3 130208-4

22 23 24

Suspension Suspension

01/26/13

Measured Measured

01/25/13

Measured

43.1
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect 10 Non-detect 10 Non-detect 10 Non-detect

60 J 60 J 56 J 65 J

5.07 5.08 4.01 5.86

0.15 Non-detect 0.15 Non-detect 0.15 Non-detect 0.15 Non-detect

0.175 Non-detect 0.175 Non-detect 0.175 Non-detect 0.175 Non-detect

3.83 5.02 4.22 4.78

0.125 Non-detect 0.125 Non-detect 0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect 0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect 0.025 Non-detect 0.025 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.007 0.011 0.018 0.012

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.021 0.036 0.035 0.06

0.001 Non-detect 0.002 Non-detect 0.001 J 0.002 Non-detect

0.004 J 0.006 J 0.008 0.008 J

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.037 0.03 0.091 J 0.058 J

0.001 Non-detect 0.002 Non-detect 0.001 Non-detect 0.002 Non-detect

0.002 Non-detect 0.004 Non-detect 0.002 Non-detect 0.004 Non-detect

0.356 0.59 0.454 1.13

215.6

130208-6

SP-PL-1-25

25

Measured

Suspension

01/27/13

48.2 52.9

215.8 215.4 214.9

130208-8 130208-9

27 28

01/28/13 01/29/13 01/30/13

26

Suspension Suspension Suspension

SP-PL-1-26 SP-PL-1-27 SP-PL-1-28

130208-7

Measured

46.2 45

Measured Measured
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

5. Enter any notes or additional information relevant to the sampling or analysis.

Company Shintech Inc.

Facility Shintech Louisiana, LLC - Plaquemine Plant

PVC Process Wastewater Treatment System ID P-WWS

CAS No. HAP Analysis Method

107211 Ethylene glycol SW-846-8015C

67561 Methanol SW-846-8015C

75070 Acetaldehyde SW-846-8315A

50000 Formaldehyde SW-846-8315A

51285 2,4-dinitrophenol SW-846-8270D

98862 Acetophenone SW-846-8270D

117817 Bis(2-ethylhexyl) phthalate (DEHP) SW-846-8270D

123319 Hydroquinone SW-846-8270D

108952 Phenol SW-846-8270D

79345 1,1,2,2-tetrachloroethane SW-846-8260B

106990 1,3-butadiene SW-846-8260B

540841 2,2,4-trimethylpentane SW-846-8260B

71432 Benzene SW-846-8260B

108907 Chlorobenzene SW-846-8260B

67663 Chloroform SW-846-8260B

126998 Chloroprene SW-846-8260B

98828 Cumene SW-846-8260B

75003 Ethyl chloride (Chloroethane) SW-846-8260B

100414 Ethylbenzene SW-846-8260B

107062 Ethylene dichloride (1,2-Dichloroethane) SW-846-8260B

75343 Ethylidene dichloride (1,1-Dichloroethane) SW-846-8260B

74873 Methyl chloride (Chloromethane) SW-846-8260B

75092 Methylene chloride SW-846-8260B

110543 n-Hexane SW-846-8260B

108883 Toluene SW-846-8260B

71556 Methyl chloroform (1,1,1-Trichloroethane) SW-846-8260B

79005 1,1,2-Trichloroethane SW-846-8260B

108054 Vinyl acetate SW-846-8260B

593602 Vinyl bromide SW-846-8260B

75014 Vinyl chloride EPA Method 107

75354 Vinylidene chloride (1,1-Dichloroethylene) SW-846-8260B

1330207 Xylenes (isomers and mixtures) SW-846-8260B

108101 4-Methyl 2-pentanone (MIBK) SW-846-8260B

Resin Type (suspension, dispersion, bulk, etc.) -->

Sample Date -->

Lab Sample ID -->

Lab Report ID -->

Analysis Date -->

Stream Temperature (degrees F) -->

Stream Flow Rate (gallons per minute) -->

Flow Rate Determination Method -->

Refer to Lab Reports Refer to Lab Reports Refer to Lab Reports 

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect? Note(s)

10 Non-detect UJ 10 Non-detect

53 J 53 J

4.05 5.17 6.17

0.15 Non-detect 0.568 0.431 J

0.175 Non-detect 0.175 Non-detect

4.79 3.49

0.125 Non-detect 0.125 Non-detect

0.25 Non-detect 0.25 Non-detect

0.025 Non-detect 0.025 Non-detect

0.002 Non-detect 0.001 Non-detect

0.004 Non-detect 0.002 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.004 Non-detect 0.002 Non-detect

0.002 Non-detect 0.001 Non-detect

0.01 0.036

0.002 Non-detect 0.001 Non-detect

0.024 0.044

0.002 Non-detect 0.002 J

0.004 Non-detect 0.014

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect 0.001 Non-detect

0.002 Non-detect UJ 0.001 Non-detect UJ

0.002 Non-detect 0.001 Non-detect

0.046 J 0.182 J 0.223 J

0.002 Non-detect 0.001 Non-detect

0.004 Non-detect 0.002 Non-detect

0.315 0.368

Measured

Suspension Suspension

29 30

01/31/13 02/01/13

44 40

SP-PL-1-29 SP-PL-1-30

215.6 216

Measured

130208-10 130208-11

31

02/02/13

Suspension

44.9

Measured

215.8

130208-12

SP-PL-1-31