AQS Site IDStateCountyLatitudeLongitudeSulfatesNitratesCrustalOC

010730023AL Jefferson33.55306-86.815 3.7 0.8 1.1 3.0 010732003AL Jefferson33.49972-86.9242 3.40.8 1.5 4.0 010890014AL Madison34.68767-86.5864 3.3 1.0 0.6 3.1 011011002AL Montgomery 32.40712-86.2564 3.3 0.6 0.7 3.5 011130001AL Russell32.47678-84.9991 3.2 0.7 0.64.8 040191028AZ Pima32.29515-110.982 1.2 0.6 1.3 1.5 051190007AR Pulaski34.75619-92.2813 2.9 1.0 0.9 3.2 060070002CA Butte39.75737-121.843 060070008CA Butte39.76154-121.842 060190011CA Fresno36.78532-119.774 1.64.9 0.84.6 060250005CA Imperial32.67619-115.484 1.6 1.6 2.9 4.8 060371103CA Los Angeles34.06659-118.227 060631009CA Plumas39.80833-120.472 0.7 0.5 0.711.6 060670006CA Sacramento38.61378-121.368 1.1 2.1 0.5 3.7 060670010CA Sacramento38.55823-121.493 1.1 2.3 0.6 3.3 060730003CA San Diego32.79119-116.942 2.1 2.8 0.6 3.4 060731002CA San Diego33.12771-117.075 2.2 2.7 0.6 3.7 060850005CA Santa Clara37.3485-121.895 1.2 2.1 0.4 3.3 060990005CA Stanislaus37.64158-120.995 1.5 4.8 0.8 3.8 061072002CA Tulare36.33218-119.291 1.9 6.1 1.04.6 061112002CA Ventura34.27574-118.685 1.8 2.5 0.8 2.4 080010006CO Adams39.82601-104.937 1.0 1.4 1.5 2.4 080310025CO Denver39.70401-104.998 080310026CO Denver39.77949-105.005 110010043DC District of Columbia 38.92185-77.0132 3.3 1.5 0.5 2.9 120111002FL Broward26.08314-80.2376 2.3 0.6 1.1 1.2 120573002FL Hillsborough 27.96565-82.2304 2.6 0.6 0.8 2.3 120730012FL Leon30.43972-84.3464 2.7 0.40.6 3.8 130210007GA Bibb32.77745-83.6411 3.0 0.5 1.1 4.7 130890002GA DeKalb33.68797-84.2905 3.0 0.6 0.5 3.7 131150003GA Floyd34.26054-85.3233 3.5 0.6 0.7 4.1 132150011GA Muscogee32.42905-84.9316 3.1 0.5 0.64.6 081230008CO Weld40.20939-104.824 1.0 1.8 1.6 1.8 090090027CT New Haven41.3014-72.9029 2.3 1.3 0.4 2.6 100010003DE Kent 39.155-75.5181 2.9 1.7 0.3 2.1 100032004DE New Castle39.73944-75.5581 3.5 2.5 0.5 2.9 201730010KS Sedgwick37.70207-97.3148 2.2 1.8 1.1 2.2 202090021KS Wyandotte39.11722-94.6356 2.4 1.9 0.9 3.6 210190017KY Boyd38.45934-82.64044.0 1.0 0.5 3.4 210430500KY Carter38.23887-82.9881 3.9 0.6 0.3 2.22010-2012 3-Year Average Speciation Measurements210670012KY Fayette38.06503-84.49764.0 1.6 0.5 2.7

211170007KY Kenton39.0725-84.525 220330009LA East Baton Rouge 30.46198-91.1792 3.6 0.9 1.0 3.1 240053001MDBaltimore39.31083-76.4744 3.4 1.8 0.4 3.3 240330030MDPrince George's 39.05528-76.8783 3.1 1.1 0.5 2.5 250130008MAHampden42.19438-72.5551 2.0 0.9 0.2 2.7 260810020MI Kent42.98417-85.6713 2.6 2.5 0.5 2.9 260910007MI Lenawee41.99557-83.9466 3.0 2.6 0.3 2.2 261130001MI Missaukee44.31056-84.8919 1.9 1.0 0.2 1.5 261150005MI Monroe41.76389-83.4719 3.2 2.5 0.4 2.4 261470005MI St. Clair42.95334-82.4562 2.7 1.8 0.3 2.5 261630001MI Wayne42.22862-83.2082 3.0 2.40.5 2.5 261630015MI Wayne42.30279-83.1065 3.5 2.5 1.1 2.8 261630033MI Wayne42.30667-83.1488 2.9 2.3 1.4 3.1 270031002MNAnoka45.13768-93.2076 270530963MNHennepin44.95366-93.2582 1.7 2.40.6 2.5 271095008MNOlmsted43.99691-92.4504 280490019MS Hinds32.33037-90.1662 280670002MSJones31.68864-89.1351 3.3 0.7 0.9 4.0 132450091GA Richmond33.43335-82.0222 3.1 0.7 0.64.1 132950002GA Walker34.97889-85.301 3.1 0.7 0.5 4.5 150030010HI Honolulu21.32374-158.089 160010010ID Ada 43.6007-116.348 0.7 1.3 0.8 2.8 170310057IL Cook41.91286-87.7227 3.1 3.40.9 3.5 170310076IL Cook 41.7514-87.7135 2.7 2.7 0.5 2.7 170314201IL Cook 42.14-87.7992 2.8 2.8 0.5 2.6 170434002IL DuPage41.77107-88.1525 2.8 2.8 0.5 2.7 171190024IL Madison38.70063-90.1448 180190006IN Clark38.27768-85.7402 4.4 1.7 0.9 3.5 180372001IN Dubois38.39144-86.9292 4.3 2.40.5 2.9 180390008IN Elkhart41.6569-85.9684 2.9 2.9 0.4 3.2 180650003IN Henry40.00953-85.5235 3.3 2.7 0.3 2.1 180890022IN Lake41.60668-87.3047 3.3 2.9 1.0 3.0 180892004IN Lake 41.5855-87.4745 180970078IN Marion39.8111-86.1145 3.6 2.7 0.5 3.1 181630021IN Vanderburgh 38.01325-87.5779 4.0 1.9 0.5 3.0 300490004MTLewis and Clark 46.85051-111.987 300930005MTSilver Bow46.0024-112.501 310550019NE Douglas41.24749-95.9731 2.3 2.7 1.2 2.0 320030540NV Clark36.14347-115.079 320310016NV Washoe39.52508-119.808 0.7 0.9 0.8 2.7 340130003NJ Essex40.72099-74.1929 2.7 1.7 0.4 3.3 340273001NJ Morris40.78763-74.6763 2.4 1.1 0.2 1.8 340390004NJ Union40.64144-74.2084 2.9 1.9 0.7 3.1350010023NMBernalillo35.1343-106.585 0.9 0.6 1.0 2.3

360010005NY Albany42.64225-73.7546 2.2 1.2 0.5 2.7 360050110NY Bronx40.81618-73.902 360310003NY Essex44.39308-73.8589 360551007NY Monroe43.14618-77.5482 2.4 1.5 0.3 1.9 361010003NY Steuben42.09142-77.2098 2.6 0.9 0.2 1.5 370210034NC Buncombe35.6075-82.5833 3.2 0.6 0.4 2.9 370350004NC Catawba35.72889-81.3656 3.1 1.0 0.4 3.8 370570002NC Davidson35.81444-80.2625 3.1 0.9 0.4 3.8 370670022NC Forsyth36.11056-80.2267 3.1 1.0 0.4 3.2 371190041NC Mecklenburg35.2401-80.7857 3.2 0.9 0.5 3.5 371590021NC Rowan35.55187-80.395 3.1 0.8 0.4 3.5 371830014NC Wake35.85611-78.5742 3.2 0.8 0.5 3.5 380171004ND Cass46.93375-96.8554 1.4 1.7 1.5 1.4 390610040OH Hamilton39.12886-84.5044.0 2.1 0.5 2.7 390811001OH Jefferson40.32207-80.6063 4.8 1.6 0.5 3.1 390870012OH Lawrence38.50811-82.6593 4.0 1.1 0.8 3.2 390933002OH Lorain41.46307-82.1143 3.1 2.0 0.7 2.8 390950026OH Lucas41.62063-83.6423 3.3 2.5 0.5 2.5 390990014OH Mahoning41.09594-80.6585 3.3 1.9 1.1 2.8 391130032OH Montgomery 39.76066-84.1877 3.7 2.5 0.5 3.0 391351001OH Preble39.83562-84.7205 391510017OH Stark40.78688-81.3942 3.5 2.4 1.0 3.2 391530023OH Summit41.08796-81.54164.4 2.6 0.4 2.8 401091037OK Oklahoma35.61413-97.4751 2.4 1.5 0.9 2.1 401431127OK Tulsa 36.2049-95.9765 2.9 1.5 0.9 2.9 410350004OR Klamath42.1903-121.731 410370001OR Lake42.18922-120.354 410392013OR Lane43.74435-122.48 420110011PA Berks40.38335-75.9686 3.2 2.6 0.3 2.6 420210011PA Cambria40.30972-78.915 420270100PA Centre40.81139-77.877 3.1 1.3 0.3 2.2 420290100PA Chester39.83446-75.7682 420430401PA Dauphin40.24699-76.847 420710007PA Lancaster40.04667-76.2833 3.3 2.9 0.3 3.1 420950025PA Northampton 40.62806-75.3411 421010055PA Philadelphia39.92252-75.1868 3.4 2.1 0.5 3.0 421011002PA Philadelphia40.03598-75.0024 421255001PA Washington40.44528-80.4208 421290008PA Westmoreland 40.30469-79.5057 421330008PA York39.96528-76.6994 3.4 2.40.6 3.0 440070022RI Providence41.80778-71.4151 440071010RI Providence41.84157-71.3608 450190049SC Charleston32.79098-79.9587450250001SC Chesterfield34.61537-80.1988 3.1 0.6 0.4 2.9

450450015SC Greenville34.8439-82.4146 3.2 0.8 0.5 4.0 450790007SC Richland34.09396-80.9623 460990008SD Minnehaha43.54792-96.7008 1.9 2.3 0.6 1.7 470370023TN Davidson36.17633-86.7389 3.5 1.3 0.5 3.2 470654002TN Hamilton35.05093-85.293 3.5 0.8 0.7 4.0 470931020TN Knox36.01919-83.8738 3.5 0.7 0.5 3.4 470990002TN Lawrence35.11597-87.47 3.0 0.7 0.7 2.5 471251009TN Montgomery 36.51471-87.328 3.5 1.3 0.5 2.9 471451001TN Roane35.91676-84.5036 481130069TX Dallas32.81995-96.8601 2.9 1.2 1.2 2.6 481410044TX El Paso31.7657-106.455 1.3 0.7 2.9 2.6 482030002TX Harrison32.66899-94.1675 2.9 0.5 0.9 4.0 490110004UT Davis40.90297-111.8840.9 2.2 0.8 1.8 490353006UT Salt Lake40.73639-111.872 1.0 2.6 1.0 2.3 490494001UT Utah40.34139-111.7140.9 2.5 1.0 2.0 500070012VT Chittenden44.48028-73.2144 1.6 1.0 0.4 2.5 510870014VA Henrico37.55652-77.4003 3.3 0.9 0.4 3.1 530110013WAClark45.64833-122.587 0.9 0.7 0.3 3.7 530530029WAPierce47.1864-122.452 1.0 0.7 0.3 3.9 530611007WASnohomish48.05432-122.172 530770009WAYakima46.59806-120.499 540391005WVKanawha38.36618-81.6937 4.0 1.1 0.6 3.5 540511002WVMarshall39.91596-80.7339 540690010WVOhio40.11488-80.701 550090005WI Brown 44.507-87.993 550270001WI Dodge43.46611-88.6211 2.1 2.3 0.4 1.9 550790026WI Milwaukee43.061-87.912 2.4 2.5 0.4 2.4 551198001WI Taylor45.20389-90.6001 1.8 1.6 0.3 1.7 551330027WI Waukesha43.02008-88.2151 2.4 2.5 0.7 2.6

* These data were derived with the SANDWICH algorithm to represent PM2.5 composition. For simplification purposes, the SANDWICH component called "passive" (which is nominally 0.5 ug/m3) was allocated in proportion to the concentration value of the five PM2.5 constituents which now sum to the FRM mass.EC SulfatesNitratesCrustalOC EC SulfatesNitratesCrustal

0.8 4.5 0.1 1.1 6.9 0.8 3.9 0.9 1.2 0.7 4.1 0.1 1.5 5.9 0.8 3.6 0.8 1.8 0.5 4.1 0.3 0.6 5.2 0.5 3.6 1.2 0.7 0.6 3.9 0.0 0.8 5.40.6 3.5 0.7 1.0 0.8 3.9 0.1 0.6 6.9 0.8 3.5 0.9 0.7 0.4 1.5 0.0 1.4 1.7 0.5 1.0 0.6 0.9 0.6 3.5 0.3 0.9 6.1 0.6 3.0 1.1 0.9 0.7 1.0 0.6

0.8 2.0 3.0 0.8 7.5 0.8 1.7 4.7 0.7 0.8 2.0 0.2 3.0 8.40.9 1.6 1.4 2.0 2.64.1 0.9 1.0 0.8 0.1 0.7 8.5 1.1 0.5 0.40.8 0.7 1.4 1.0 0.6 5.7 0.7 1.2 2.3 0.6 0.6 1.4 1.2 0.64.6 0.6 0.9 2.3 0.6 0.8 2.6 0.40.6 6.2 0.8 2.1 3.0 0.5 0.6 2.7 0.3 0.6 5.9 0.6 2.1 3.0 0.6 0.6 1.6 0.6 0.5 6.0 0.6 1.3 2.0 0.4 0.6 1.9 3.40.8 5.40.6 1.5 4.2 0.9 0.6 2.4 3.6 1.1 6.5 0.6 1.64.8 0.9 0.5 2.3 0.3 0.8 5.2 0.5 1.7 2.5 0.5 1.0 1.3 0.8 1.6 2.8 1.0 1.1 1.6 1.3 1.2 1.9 1.0

0.7 4.2 0.6 0.5 4.40.7 4.0 1.7 0.5 0.4 3.1 0.0 1.2 2.1 0.4 2.6 0.8 1.0 0.4 3.3 0.0 0.9 2.9 0.5 2.9 0.6 0.8 0.7 3.2 0.0 0.64.8 0.7 2.9 0.5 0.8 0.7 3.6 0.1 1.2 7.40.8 3.40.7 1.3 1.2 3.6 0.1 0.5 6.0 1.3 3.3 0.8 0.6 1.2 4.1 0.1 0.7 6.4 1.2 4.0 0.8 0.9 0.6 3.7 0.1 0.6 6.5 0.6 3.5 0.7 0.9 0.6 1.2 0.8 1.7 2.9 0.6 1.0 2.1 1.6 1.0 2.9 0.40.44.0 1.0 2.2 1.2 0.4 0.4 3.7 0.9 0.3 3.0 0.4 3.7 2.0 0.4 0.7 4.2 1.40.5 3.7 0.8 4.2 3.3 0.5 0.4 2.7 1.2 1.1 3.1 0.4 2.2 1.7 0.9 0.6 2.9 1.2 0.9 4.0 0.6 2.4 2.1 0.9 0.7 4.8 0.5 0.5 4.2 0.7 4.6 1.40.5 0.4 4.5 0.3 0.3 3.6 0.4 5.0 0.9 0.3 2010-2012 3-Year Average SANDWICHed* Speciation Measurements0.5 5.0 0.8 0.6 3.5 0.6 4.7 2.1 0.5

0.7 4.40.0 1.1 4.2 0.7 3.8 1.0 1.2 0.8 4.2 0.9 0.44.6 0.8 3.7 1.9 0.5 0.6 3.7 0.5 0.5 3.5 0.6 3.5 1.40.6 0.5 2.40.40.3 4.1 0.6 2.0 0.8 0.3 0.6 3.2 1.8 0.5 3.5 0.6 2.7 2.8 0.6 0.4 3.6 1.8 0.3 3.2 0.4 3.1 2.7 0.4 0.2 2.40.7 0.2 2.5 0.2 1.9 0.8 0.2 0.6 4.0 1.7 0.5 3.0 0.6 3.2 2.9 0.4 0.4 3.4 1.0 0.4 3.7 0.5 2.6 1.5 0.4 0.8 3.7 1.6 0.5 3.40.8 3.0 2.40.5 0.8 4.3 1.6 1.1 2.9 0.9 3.8 2.8 1.1 0.8 3.6 1.5 1.5 3.7 0.8 3.0 2.3 1.3

0.5 2.1 1.8 0.6 3.6 0.5 1.8 2.5 0.6 1.9 3.0 0.5

0.7 4.0 0.1 1.0 5.8 0.7 3.3 0.9 1.3 0.6 3.8 0.1 0.6 6.40.6 3.9 0.9 0.7 0.7 3.7 0.1 0.5 5.5 0.7 3.3 1.0 0.6

0.5 1.0 0.7 0.9 3.5 0.6 0.7 1.2 0.9 0.8 3.7 2.40.9 4.7 0.9 3.2 4.3 0.8 0.7 3.4 1.8 0.5 4.8 0.8 2.8 3.0 0.5 0.6 3.4 2.1 0.5 4.0 0.6 3.0 3.3 0.5 0.6 3.4 2.1 0.5 4.2 0.6 3.0 3.5 0.6 3.7 2.4 2.6 0.8 5.40.9 0.9 4.8 0.8 4.9 2.3 0.8 0.5 5.3 1.40.5 4.6 0.6 4.9 3.0 0.4 0.6 3.6 2.1 0.44.5 0.6 3.0 3.6 0.4 0.5 4.1 1.7 0.3 3.8 0.5 3.5 3.7 0.3 1.1 4.0 2.3 1.04.6 1.1 3.4 3.4 1.0 3.5 3.6 0.7 0.7 4.4 1.8 0.5 4.40.7 3.8 3.40.5 0.5 4.9 1.1 0.64.7 0.6 4.5 2.40.6

0.4 2.8 2.2 1.2 3.2 0.4 2.5 3.3 1.2

0.7 0.9 0.40.8 3.40.7 0.6 1.0 0.8 0.9 3.40.6 0.5 3.9 0.9 2.7 1.40.4 0.4 3.1 0.3 0.3 3.1 0.4 2.8 1.0 0.3 1.6 3.6 0.8 0.7 4.3 1.6 3.0 1.8 0.80.6 1.2 0.1 1.1 3.3 0.6 0.8 0.7 0.7

0.7 2.7 0.7 0.6 3.7 0.7 2.5 1.2 0.5

0.5 2.9 0.9 0.4 3.7 0.6 2.4 1.40.4 0.2 3.2 0.40.2 3.0 0.3 3.2 0.9 0.2 0.5 3.8 0.1 0.44.40.6 3.7 0.7 0.5 0.8 3.8 0.3 0.4 5.2 0.8 3.8 1.3 0.5 0.7 3.8 0.2 0.5 5.7 0.7 3.7 1.1 0.5 0.6 3.8 0.3 0.4 3.8 0.6 4.0 1.2 0.5 0.6 3.8 0.2 0.5 5.1 0.6 3.8 1.1 0.5 0.5 3.8 0.2 0.4 5.2 0.5 3.8 1.0 0.5 0.6 3.9 0.2 0.5 4.7 0.6 3.8 0.9 0.5 0.3 1.8 1.3 1.7 2.9 0.3 1.6 1.8 1.6 0.7 4.9 1.3 0.5 4.6 0.7 4.4 2.5 0.4 0.9 5.7 0.8 0.5 3.0 0.9 4.9 1.8 0.5 0.8 4.6 0.5 0.84.8 0.9 5.0 1.5 0.7 0.6 3.8 1.3 0.7 3.6 0.6 3.1 2.2 0.6 0.6 4.0 1.8 0.5 3.9 0.6 3.1 2.8 0.6 0.7 4.1 1.3 1.1 3.6 0.8 3.9 2.5 1.2 0.7 4.6 1.6 0.5 4.3 0.8 3.9 3.40.5

0.8 4.3 1.6 1.1 4.6 0.8 3.8 3.2 1.3 0.7 5.2 1.7 0.5 3.40.7 4.0 2.7 0.4 0.4 2.9 0.8 0.9 4.2 0.4 2.4 1.5 0.7 0.4 3.40.8 1.0 5.0 0.5 2.9 1.6 0.9 0.5 0.6 0.5 0.5 0.2 0.8 0.40.1 0.3 0.6 4.0 1.40.3 4.3 0.7 3.5 2.6 0.3 4.5 1.5 1.1 0.4 3.8 0.6 0.3 3.3 0.4 3.3 1.3 0.3

0.7 4.1 1.5 0.3 4.8 0.7 3.6 3.0 0.3

0.9 4.2 1.0 0.5 4.3 1.0 3.4 2.2 0.5

0.7 4.2 1.40.64.40.8 3.7 2.40.6

3.5 0.7 0.60.4 3.7 0.1 0.44.6 0.4 3.8 0.8 0.4

0.7 3.9 0.2 0.5 5.7 0.7 3.8 1.0 0.6

0.3 2.3 1.7 0.7 3.9 0.3 2.2 2.9 0.6 0.8 4.3 0.6 0.64.5 0.8 3.7 1.7 0.6 0.8 4.2 0.1 0.7 5.1 0.8 3.8 1.0 0.7 0.7 4.1 0.1 0.5 5.6 0.8 4.1 0.8 0.5 0.3 3.7 0.1 0.8 3.7 0.3 3.2 0.7 1.0 0.4 4.3 0.6 0.5 4.2 0.4 3.8 1.8 0.5 3.6 0.6 0.5 0.6 3.5 0.3 1.3 4.2 0.7 2.8 1.3 1.1 0.8 1.6 0.1 3.04.7 0.8 1.1 0.8 2.4 0.6 3.5 0.0 0.9 5.9 0.6 3.2 0.5 0.8 0.5 1.2 1.8 0.9 3.40.5 0.9 2.40.7 0.6 1.3 2.2 1.1 3.6 0.7 1.0 3.4 1.2 0.5 1.2 2.0 1.1 3.5 0.5 0.9 2.9 1.1 0.4 2.1 0.6 0.4 3.7 0.4 1.8 1.0 0.3 0.6 4.1 0.2 0.44.0 0.6 4.0 1.0 0.4 0.7 1.2 0.1 0.44.7 0.7 0.9 0.6 0.3 0.8 1.3 0.1 0.3 5.2 0.8 1.1 0.7 0.3 1.0 0.7 0.3

1.0 4.8 0.40.6 5.0 1.0 4.8 1.5 0.6

4.8 1.9 1.1

0.3 2.6 1.6 0.44.2 0.3 2.2 2.40.3 0.5 3.0 1.7 0.5 4.5 0.6 2.5 2.5 0.5 0.2 2.2 1.2 0.3 3.5 0.3 1.6 1.40.3 0.6 2.9 1.8 0.7 5.2 0.6 2.5 2.9 0.7

* These data were derived with the SANDWICH algorithm to represent PM2.5 composition. For simplification purposes, the SANDWICH component called "passive" (which is nominally 0.5 ug/m3) was allocated in proportion to the concentration value of the five PM2.5 constituents which now sum to the FRM mass.OC EC SulfatesNitratesCrustalOC EC SulfatesNitrates

3.6 1.0 4.9 0.2 1.3 7.0 1.1 4.0 0.8 4.0 0.8 4.3 0.2 1.9 5.5 0.8 3.8 0.8 3.1 0.5 4.5 0.5 0.7 5.1 0.5 3.6 0.9 3.5 0.7 4.2 0.1 1.1 5.0 0.7 3.6 0.5 5.1 0.9 4.3 0.3 0.7 7.1 0.9 3.6 0.5 1.6 0.4 1.3 0.1 1.0 2.0 0.5 1.3 0.6 3.6 0.7 3.7 0.40.9 6.3 0.7 3.1 1.1 4.40.7 1.0 0.3 0.7 4.5 0.7 1.1 1.8

4.3 0.7 2.1 2.9 0.7 6.8 0.8 1.6 5.5 4.0 0.7 2.0 0.2 2.0 7.9 0.7 1.6 1.6 8.3 1.5 3.3 0.9 0.9 4.9 1.6 9.7 1.0 0.7 0.0 0.9 6.4 1.1 0.7 0.4 3.40.7 1.5 1.2 0.64.8 0.7 1.2 2.5 3.0 0.6 1.2 1.2 0.7 3.7 0.6 1.2 2.9 3.5 0.8 2.7 0.3 0.5 6.5 0.8 2.3 2.9 4.0 0.7 2.8 0.5 0.7 6.0 0.7 2.1 2.7 3.0 0.6 1.7 0.5 0.4 5.7 0.6 1.3 2.2 3.7 0.7 1.9 2.2 1.0 5.2 0.7 1.7 6.7 4.1 0.6 2.1 2.3 0.9 5.8 0.6 2.1 7.2 2.3 0.5 2.2 0.3 0.5 5.2 0.5 1.9 2.5 2.4 1.0 1.40.9 1.4 3.2 1.1 1.1 1.3 2.2 0.9 1.5 1.3 1.1 3.1 0.9 1.1 1.4

3.0 0.6 5.0 0.8 0.64.40.7 3.3 1.4 1.3 0.4 3.3 0.0 1.1 2.2 0.4 2.40.6 2.3 0.4 3.5 0.0 0.9 3.2 0.5 2.8 0.6 3.8 0.7 3.40.0 0.84.9 0.7 2.9 0.4 4.7 0.8 3.9 0.1 1.3 7.8 0.8 3.2 0.4 3.6 1.3 3.9 0.2 0.6 6.2 1.4 3.3 0.5 4.7 0.9 4.8 0.3 0.9 7.0 1.0 3.7 0.5 5.0 0.7 4.1 0.2 0.9 6.8 0.8 3.40.4 1.5 0.5 1.3 1.1 1.7 2.6 0.6 1.0 1.8 2.5 0.8 2.8 0.3 0.5 3.8 0.9 2.6 1.3 2.7 0.5 4.6 1.2 0.4 3.8 0.5 2.6 1.7 3.3 0.8 5.0 2.3 0.6 3.1 0.8 3.2 2.0 2.0 0.4 2.7 1.2 1.0 2.8 0.4 2.3 2.0 3.40.6 2.9 1.5 0.9 3.6 0.7 2.5 1.8 3.40.7 5.7 0.8 0.5 3.6 0.7 4.2 0.9 2.40.4 5.8 0.6 0.3 3.40.4 3.7 0.5 Speciation Measurements 2010 Annual Average Speciation Measurements SANDWICHed*2.9 0.6 5.8 1.3 0.6 3.5 0.6 4.3 1.5

3.2 0.7 4.7 0.0 1.3 4.0 0.7 3.9 0.9 3.2 0.7 4.6 1.1 0.5 4.40.8 3.4 1.7 2.5 0.6 4.3 0.7 0.6 3.2 0.7 3.0 1.0 2.3 0.4 2.5 0.3 0.3 4.0 0.5 2.1 1.0 3.0 0.6 3.4 2.1 0.6 3.2 0.7 2.5 2.4 2.5 0.4 3.9 2.0 0.4 2.9 0.5 3.1 2.5 1.6 0.2 2.3 0.5 0.2 2.40.2 2.0 1.0 2.5 0.6 4.0 2.2 0.5 2.9 0.6 3.4 2.1 2.6 0.4 3.3 0.9 0.4 3.40.5 2.6 1.8 2.6 0.8 3.7 1.7 0.5 3.1 0.9 3.2 2.6 3.3 1.0 4.7 2.0 1.1 2.6 1.0 3.3 2.3 3.3 0.8 3.7 1.6 1.4 3.8 0.9 2.9 2.2 1.9 2.3 2.6 0.5 2.3 2.0 0.7 3.5 0.6 1.8 2.4 2.6 0.5 2.4 2.6 0.6 3.5 0.6 3.2 0.7 4.8 0.8 4.2 0.2 1.4 5.6 0.8 3.6 0.7 4.2 0.7 4.9 0.2 0.7 6.40.7 2.9 0.6 4.1 0.7 4.0 0.3 0.64.3 0.7 3.5 0.5 1.2 0.3 2.0 0.5 0.9 0.6 1.0 1.9 0.5 0.8 1.6 3.7 0.9 4.0 3.40.84.9 0.9 3.2 3.0 3.0 0.9 3.5 2.2 0.64.6 0.9 2.9 2.7 2.8 0.6 3.6 2.6 0.5 3.2 0.7 2.9 2.7 3.0 0.7 3.7 2.8 0.64.0 0.7 3.0 2.8 3.3 0.8 4.4 1.7 2.7 5.3 0.8 3.8 1.8 3.7 0.8 6.0 1.6 0.9 5.1 0.8 4.6 1.5 3.1 0.6 6.0 2.2 0.5 4.2 0.6 4.6 2.3 3.6 0.6 3.8 3.0 0.44.6 0.6 3.0 2.5 2.6 0.4 4.4 2.8 0.3 4.2 0.4 3.6 2.2 3.3 1.2 4.1 2.8 1.04.5 1.2 3.6 3.0 3.2 0.9 4.3 3.0 0.7 4.2 0.9 3.3 0.7 4.7 2.6 0.5 4.40.7 4.0 2.4 3.1 0.5 5.5 1.8 0.64.3 0.6 4.4 1.7 0.7 0.3

1.9 0.4 3.0 2.9 1.2 2.8 0.4 2.4 2.4 1.0 0.8 2.6 0.7 0.8 0.5 0.8 3.3 0.8 0.7 0.9 3.4 1.0 3.40.40.4 3.3 1.0 2.9 1.7 2.0 0.4 3.6 0.3 0.3 2.7 0.4 2.5 0.9 2.9 1.5 3.8 0.7 0.9 3.4 1.6 3.3 1.91.9 0.6 1.1 0.1 0.7 2.5 0.6 0.9 0.7

2.8 0.7 3.0 0.7 0.6 3.40.7 2.1 1.3

1.5 0.3 2.0 0.4 3.0 0.9 0.4 3.2 0.5 2.4 1.5 1.5 0.3 3.9 0.40.2 2.8 0.3 2.6 0.8 2.9 0.6 4.40.2 0.5 4.7 0.6 3.5 0.5 4.1 0.9 4.7 0.5 0.5 5.40.9 3.1 0.8 4.2 0.7 4.7 0.40.5 6.2 0.8 3.1 0.7 3.3 0.6 4.9 0.6 0.5 4.40.6 3.0 0.8 3.5 0.7 4.7 0.40.6 5.0 0.7 3.2 0.8 3.8 0.6 4.7 0.40.5 5.40.6 3.0 0.7 3.6 0.6 4.7 0.3 0.64.6 0.6 3.3 0.7 1.6 0.3 1.9 1.6 1.7 2.8 0.3 1.5 1.7 3.0 0.7 5.5 1.9 0.5 4.6 0.7 4.3 2.0 3.2 0.9 5.9 1.0 0.5 3.5 0.9 5.4 1.6 3.2 1.0 5.7 0.9 0.84.6 1.0 3.8 0.9 2.7 0.6 3.9 1.5 0.7 3.5 0.7 3.4 2.0 2.7 0.6 3.9 2.3 0.64.6 0.6 3.5 2.3 3.2 0.8 4.8 2.0 1.3 3.9 0.8 3.4 1.7 3.2 0.8 4.9 2.6 0.5 4.7 0.8 3.8 2.0 3.7 2.4 3.8 0.9 4.7 2.5 1.44.40.9 3.5 2.1 3.2 0.6 4.9 1.8 0.44.8 0.6 4.8 2.6 2.0 0.4 2.9 0.8 0.8 3.9 0.4 2.6 1.9 2.7 0.4 3.5 0.9 0.9 4.9 0.5 3.2 1.7 6.40.9 0.6 0.1 0.5 7.8 1.0 0.7 0.8 4.7 0.6 0.6 0.0 0.9 5.1 0.6 0.7 0.4 4.9 0.6 0.7 0.0 0.3 6.2 0.6 0.7 0.2 2.6 0.6 4.4 1.6 0.3 3.40.7 3.2 2.1 3.6 0.8 5.5 1.0 1.1 3.9 0.9 2.2 0.4 4.1 0.6 0.3 3.40.5 3.2 1.3

3.1 0.7 4.5 1.8 0.3 4.3 0.8 3.2 2.4

3.1 1.1 4.4 1.1 0.64.0 1.2 3.9 1.9 3.0 1.3

2.9 0.8 4.6 1.5 0.6 3.9 0.8 3.3 2.0

2.3 0.9 2.7 0.5 4.3 0.1 0.6 3.9 0.53.0 0.4 4.6 0.3 0.5 4.7 0.5 3.0 0.5

4.1 0.8 4.7 0.40.6 5.9 0.8 3.3 0.6 3.3 0.6 1.6 0.3 2.7 2.6 0.7 3.8 0.3 2.0 2.3 3.40.9 4.6 1.1 0.7 4.5 0.9 3.9 1.2 4.1 0.8 4.7 0.2 0.7 5.3 0.9 4.0 0.7 3.6 0.9 4.9 0.1 0.5 6.3 0.9 3.6 0.5 2.5 0.3 3.9 0.2 1.1 3.40.4 3.40.6 2.8 0.4 4.7 1.1 0.6 3.5 0.4 3.8 1.1 3.8 1.0 4.3 0.1 0.5 6.4 1.0 2.40.6 3.40.5 1.2 4.40.6 3.3 1.3 2.9 0.9 1.40.1 2.6 3.6 0.9 1.40.7 3.5 0.5 3.8 0.0 0.8 5.2 0.6 3.0 0.5 1.5 0.5 1.2 2.0 0.7 3.1 0.5 1.0 2.5 2.1 0.6 1.3 3.1 1.3 3.5 0.7 1.1 2.7 1.8 0.4 1.1 2.5 1.1 3.1 0.5 1.0 2.9 2.2 0.4 2.3 0.7 0.3 3.5 0.4 1.5 1.0 3.0 0.6 5.1 0.40.5 3.5 0.6 3.3 0.8 3.0 0.6 1.2 0.1 0.3 4.0 0.7 1.0 0.7 3.5 0.8 1.3 0.0 0.44.9 0.9 1.0 0.8 3.5 0.8 1.3 0.0 0.3 4.9 0.8 1.1 0.8 0.7 1.5 3.8 1.1 5.9 0.9 0.64.6 1.1 4.1 1.0

3.1 0.8 5.7 1.4 1.2 3.8 0.8

2.0 0.3 2.7 1.8 0.44.1 0.4 2.2 2.2 2.5 0.6 3.1 1.8 0.5 4.5 0.6 2.5 2.7 1.7 0.2 2.1 0.9 0.4 3.8 0.3 2.0 1.9 3.0 0.6 3.1 2.2 0.7 5.5 0.7 2.7 2.6

* These data were derived with the SANDWICH algorithm to represent PM2.5 composition. For simplification purposes, the SANDWICH component called "passive" (which is nominally 0.5 ug/m3) was allocated in proportion to the concentration value of the five PM2.5 constituents which now sum to the FRM mass.CrustalOC EC SulfatesNitratesCrustalOC EC Sulfates

1.0 2.8 0.7 4.9 0.1 1.1 7.1 0.7 3.1 1.3 4.40.7 4.5 0.1 1.3 6.6 0.8 2.9 0.5 3.3 0.5 4.5 0.2 0.5 5.7 0.5 2.8 0.5 3.5 0.6 4.3 0.0 0.5 5.40.6 2.8 0.4 5.0 0.7 4.3 0.0 0.5 7.2 0.7 2.6 1.5 1.5 0.4 1.7 0.0 1.7 1.7 0.5 1.3 0.7 2.7 0.5 3.8 0.3 0.8 6.3 0.5 2.6 0.6 7.7 1.4 1.3 0.9 0.7 8.4 1.5

0.7 4.9 0.8 2.1 3.7 0.8 7.40.8 1.4 2.64.6 0.8 2.0 0.2 2.7 7.6 0.8 1.8

0.612.4 1.1 0.9 0.0 0.6 9.1 1.1 0.7 0.5 3.8 0.7 1.5 1.5 0.5 6.0 0.7 1.0 0.5 3.5 0.6 1.5 2.0 0.5 5.0 0.6 1.1 0.7 3.6 0.8 2.9 0.40.7 5.8 0.8 1.9 0.6 3.6 0.6 2.8 0.40.6 5.7 0.6 2.2 0.4 3.6 0.7 1.6 0.8 0.5 6.3 0.7 1.1 0.7 4.7 0.7 2.2 5.8 0.8 6.0 0.7 1.3 1.04.8 0.6 2.7 4.9 1.0 6.8 0.6 1.8 0.7 2.40.5 2.40.3 0.8 5.0 0.6 1.7 1.6 2.5 1.0 1.3 0.8 1.7 2.4 1.1 0.9 1.2 2.1 0.7 1.40.7 1.3 2.6 0.8

0.4 2.9 0.6 4.1 0.6 0.44.0 0.6 2.7 0.8 1.3 0.4 3.0 0.0 0.9 2.1 0.4 2.1 0.6 2.40.4 3.40.0 0.6 3.0 0.5 2.3 0.4 3.9 0.7 3.5 0.0 0.5 5.1 0.7 2.2 0.9 4.9 0.7 3.6 0.0 1.0 8.40.8 2.6 0.4 3.8 1.3 3.8 0.0 0.4 6.3 1.3 2.6 0.5 3.8 1.4 4.40.0 0.5 6.5 1.4 2.8 0.44.6 0.6 3.9 0.0 0.5 6.8 0.6 2.4 1.7 1.7 0.6 1.2 0.9 1.8 2.5 0.6 0.9 0.4 2.6 1.0 3.2 0.40.44.1 1.0 2.1 0.3 1.6 0.3 3.3 0.8 0.3 2.0 0.4 2.5 0.4 2.7 0.7 4.0 1.1 0.4 3.8 0.7 3.0 1.1 2.3 0.4 2.8 1.4 1.2 3.2 0.4 2.2 0.7 3.6 0.6 3.0 1.2 0.84.2 0.6 2.3 0.4 3.2 0.6 4.9 0.40.44.1 0.6 3.3 0.2 1.9 0.3 4.40.2 0.3 3.1 0.4 3.0

2011 Annual Average Speciation Measurements SANDWICHed*0.5 2.5 0.5 5.3 0.8 0.6 3.3 0.6 3.2

0.7 3.2 0.7 4.7 0.1 0.7 4.2 0.8 3.1 0.4 3.3 0.8 4.2 0.8 0.44.1 0.9 3.1 0.4 2.40.5 3.6 0.40.4 3.6 0.6 2.8 0.2 3.1 0.6 2.5 0.5 0.3 4.2 0.7 1.8 0.4 2.8 0.6 3.2 1.6 0.5 3.6 0.6 2.5 0.3 2.0 0.4 3.8 1.7 0.3 3.2 0.4 2.7 0.2 1.40.2 2.5 0.8 0.2 2.5 0.2 1.9 0.4 2.1 0.5 4.3 1.3 0.5 2.7 0.5 3.0 0.3 2.2 0.4 3.3 1.1 0.3 3.40.4 2.9 0.5 2.5 0.8 3.9 1.7 0.6 3.1 0.8 2.7 0.9 2.6 0.7 4.1 1.5 0.9 2.7 0.8 3.3 0.9 2.7 0.8 3.6 1.4 1.0 3.2 0.8 2.9 0.4 2.1 0.4 2.3 1.8 0.4 2.8 0.5 1.5 0.6 2.40.5 2.2 1.9 0.6 3.3 0.5 1.5

0.5 3.9 0.6 3.8 0.1 0.6 6.6 0.7 0.9 4.1 0.6 4.5 0.0 0.9 6.1 0.7 2.8 0.5 4.1 0.5 3.5 0.0 0.5 6.7 0.5 2.5 0.44.5 0.7 4.0 0.0 0.4 5.9 0.7 2.6 0.4-0.1 0.1 1.8 0.0 0.5 1.1 0.1 1.2 0.7 2.8 0.6 1.0 1.2 0.8 3.3 0.6 0.7 1.0 3.40.9 4.0 1.9 1.1 4.6 0.9 2.7 0.5 2.6 0.7 3.6 1.8 0.5 4.3 0.7 2.4 0.4 2.3 0.5 3.5 2.1 0.4 3.8 0.6 2.6 0.5 2.7 0.6 3.7 2.1 0.5 4.0 0.6 2.2 3.3 3.8 0.9 4.5 0.9 3.4 6.1 1.0 0.8 3.3 0.7 5.6 0.6 0.9 4.7 0.8 3.7 0.4 2.8 0.5 5.7 1.40.44.6 0.6 3.4 0.4 2.9 0.6 3.7 1.6 0.44.5 0.6 2.6 0.3 2.0 0.4 4.5 1.1 0.3 3.8 0.4 2.8 0.8 2.9 1.0 4.3 2.3 0.84.3 1.1 2.9

0.4 3.0 0.7 4.9 1.6 0.5 4.3 0.7 3.1 0.5 2.8 0.5 5.3 0.9 0.5 4.7 0.5 3.3 0.2 1.0 0.1 0.9 0.1 0.3 1.8 0.1 0.7

0.8 2.0 0.4 2.9 1.8 0.9 3.7 0.4 1.9 1.1 2.9 1.0 1.3 0.1 1.2 4.5 1.1 1.2 0.8 3.0 0.8 0.9 0.5 0.8 3.6 0.8 0.7 0.4 3.8 0.9 3.7 0.6 0.44.6 1.0 2.5 0.2 1.7 0.3 3.1 0.1 0.2 3.2 0.4 2.1 0.6 3.3 1.7 4.1 0.7 0.7 5.0 1.8 2.41.1 2.7 0.6 1.2 0.2 1.2 3.7 0.7 1.0

0.5 2.9 0.8 2.6 0.8 0.6 3.9 0.8 1.9

0.1 1.1 0.1 1.9 0.1 0.2 2.0 0.1 1.5 0.3 2.1 0.5 3.0 1.0 0.3 4.1 0.5 2.3 0.2 1.3 0.2 3.2 0.40.2 2.8 0.2 2.1 0.3 2.7 0.5 4.1 0.1 0.3 4.0 0.5 2.3 0.3 3.6 0.7 3.8 0.1 0.3 4.8 0.8 2.4 0.4 3.3 0.6 3.9 0.1 0.44.9 0.6 2.4 0.2 2.5 0.5 3.6 0.3 0.2 3.0 0.5 2.4 0.4 3.5 0.6 3.9 0.2 0.4 5.2 0.6 2.5 0.3 3.2 0.5 3.7 0.1 0.3 4.9 0.5 2.5 0.4 3.6 0.5 4.0 0.2 0.44.6 0.6 2.5 1.2 1.3 0.3 1.8 1.3 1.3 2.9 0.3 1.2 0.4 2.5 0.6 5.3 1.2 0.44.8 0.6 3.3 0.4 3.0 0.9 6.40.8 0.4 2.7 0.9 3.9 0.6 2.9 0.8 4.2 0.40.64.7 0.8 3.3 0.4 2.7 0.6 4.1 1.3 0.5 3.6 0.6 2.8 0.5 2.3 0.6 4.3 1.6 0.5 3.3 0.6 3.2 0.9 2.40.7 4.2 1.1 0.9 3.1 0.7 2.7 0.4 2.7 0.6 4.8 1.1 0.44.0 0.7 3.3 0.3 2.1 0.6 4.5 1.6 0.3 3.7 0.7 2.8 0.8 2.8 0.7 4.4 1.2 0.84.2 0.7 3.2 0.3 2.9 0.6 5.8 1.6 0.3 3.0 0.6 4.3 0.8 2.3 0.4 3.1 1.0 0.9 4.3 0.4 2.1 0.7 3.0 0.4 3.6 1.0 0.7 5.0 0.5 2.6 0.5 7.5 1.0 0.9 0.3 0.6 8.8 1.0 0.7 7.40.9 0.9 0.2 0.8 7.1 0.9 0.2 6.5 0.7 1.0 0.0 0.2 8.0 0.7 0.3 2.2 0.6 4.1 1.0 0.3 3.7 0.6 2.9

0.2 1.9 0.4 3.9 0.6 0.2 2.8 0.4 2.9

3.0 0.3 2.7 0.6 4.0 1.2 0.3 3.7 0.6 3.0 2.6 0.4 3.1 0.9 4.8 0.8 0.4 3.8 0.9 2.8 0.3 2.5 0.6 3.8 0.3 0.3 4.2 0.6 2.4

0.5 2.7 0.6 4.1 1.1 0.6 3.8 0.7 3.2

0.3 2.2 0.5 2.8 0.3 0.3 4.0 0.5 2.10.3 2.9 0.4 3.6 0.0 0.3 4.6 0.4 2.3

0.4 3.7 0.6 4.0 0.0 0.4 5.3 0.7 2.5 0.5 3.7 0.6 3.9 0.1 0.5 5.5 0.6 2.4 0.6 1.6 0.3 2.4 1.8 0.64.0 0.3 1.5 0.4 3.2 0.7 4.7 0.40.5 4.40.8 2.8 0.5 4.1 0.8 4.6 0.0 0.5 5.3 0.8 2.8 0.4 3.0 0.6 4.2 0.1 0.5 5.3 0.7 2.8 0.6 2.5 0.3 4.1 0.2 0.6 3.5 0.3 2.6 0.4 3.2 0.4 4.6 0.40.44.7 0.4 3.0

1.1 2.8 0.7 4.0 0.2 1.1 4.0 0.7 2.6 3.5 2.40.7 1.7 0.1 3.6 6.0 0.8 1.4 0.6 5.2 0.7 3.5 0.0 0.6 7.1 0.7 2.7 0.8 1.6 0.5 1.2 2.3 0.9 3.2 0.5 0.9 0.8 2.3 0.7 1.4 2.5 0.9 3.2 0.7 0.9 0.9 2.0 0.5 1.3 2.6 1.0 3.0 0.5 0.9 0.4 2.5 0.4 1.9 0.6 0.5 3.6 0.4 1.6 0.3 3.1 0.6 4.0 0.2 0.3 4.0 0.6 2.5 0.3 4.6 0.8 1.2 0.3 0.3 5.6 0.9 0.9 0.2 4.2 0.8 1.3 0.2 0.3 5.3 0.9 0.9 0.2 4.2 0.8 1.40.1 0.2 5.5 0.9 0.5 4.0 0.7 0.9 1.2 0.5 4.8 0.7 0.7 0.5 3.0 0.9 5.0 0.3 0.5 4.7 0.9 3.1 3.6

1.9 0.3 1.8 0.3 2.7 1.5 0.3 4.1 0.3 2.1 0.4 2.40.5 3.1 1.9 0.44.5 0.6 2.3 0.3 1.7 0.2 2.5 1.5 0.3 3.3 0.3 1.7 0.6 2.5 0.6 3.2 1.9 0.6 5.2 0.6 2.2NitratesCrustalOC EC SulfatesNitratesCrustalOC EC

0.7 0.9 2.5 0.6 3.7 0.1 1.0 6.6 0.7 0.7 1.4 3.5 0.6 3.5 0.1 1.4 5.7 0.7 0.8 0.5 3.0 0.5 3.40.1 0.5 4.8 0.5 0.5 0.7 3.6 0.5 3.3 0.0 0.7 5.8 0.6 0.5 0.64.3 0.7 3.1 0.0 0.6 6.6 0.7 0.5 1.6 1.5 0.4 1.6 0.0 1.7 1.6 0.5 0.9 1.1 3.3 0.6 3.1 0.2 1.1 5.8 0.7

4.40.9 4.7 0.8 1.8 2.3 1.0 8.2 0.8 1.84.0 5.9 1.0 2.1 0.2 4.2 9.6 1.0

0.6 0.712.8 1.0 1.0 0.2 0.7 9.9 1.1 1.6 0.5 4.0 0.7 1.2 0.40.5 6.40.7 1.7 0.6 3.3 0.5 1.40.5 0.6 5.0 0.6 2.6 0.5 3.2 0.7 2.40.3 0.5 6.40.8 2.40.7 3.40.5 2.7 0.1 0.7 6.0 0.6 2.1 0.4 3.3 0.6 1.40.5 0.5 6.1 0.6 3.6 0.7 3.1 0.5 1.7 2.2 0.7 5.2 0.5 6.2 1.2 4.8 0.7 2.4 3.6 1.2 7.0 0.7 2.4 1.1 2.3 0.5 2.1 0.2 1.1 5.40.5 1.2 1.6 2.40.9 1.1 0.7 1.7 2.7 0.9

1.5 0.5 2.8 0.7 3.40.40.5 4.6 0.8 0.6 1.4 1.1 0.4 2.8 0.0 1.5 2.0 0.4 0.6 1.0 2.2 0.4 2.9 0.0 1.1 2.6 0.5 0.40.6 3.6 0.7 2.8 0.0 0.7 4.5 0.8 0.5 1.1 4.5 0.7 3.1 0.0 1.2 6.1 0.7 0.5 0.5 3.8 1.1 3.1 0.0 0.6 5.5 1.2 0.6 0.6 3.9 1.2 3.3 0.0 0.6 5.7 1.2 0.40.5 4.1 0.5 2.9 0.0 0.6 6.0 0.6 1.6 1.5 2.2 0.6 1.1 0.5 1.6 3.5 0.7 1.5 0.4 2.7 1.1 2.6 0.5 0.5 4.1 1.2 1.6 0.3 2.1 0.4 3.1 0.8 0.3 3.40.4 2.0 0.4 2.7 0.7 3.7 0.9 0.5 4.3 0.7 1.5 1.2 2.3 0.4 2.7 0.9 1.2 3.2 0.5 1.7 1.0 3.8 0.6 2.8 0.8 1.1 4.2 0.7 0.8 0.5 3.5 0.7 3.9 0.2 0.64.9 0.7 0.40.3 2.40.3 3.5 0.0 0.3 4.1 0.3 2012 Annual Average Speciation Measurements SANDWICHed*1.3 0.5 2.6 0.5 3.9 0.40.6 3.8 0.5

0.8 1.2 2.8 0.6 3.8 0.0 1.2 4.40.7 1.9 0.4 3.40.8 3.7 0.8 0.4 5.3 0.8 1.0 0.4 2.6 0.6 3.40.40.4 3.8 0.6 1.0 0.2 2.7 0.5 2.2 0.3 0.2 4.3 0.6 2.3 0.5 2.8 0.6 3.1 1.5 0.5 3.7 0.6 2.5 0.3 2.1 0.4 3.2 1.7 0.3 3.6 0.4 1.1 0.2 1.5 0.2 2.40.8 0.2 2.5 0.2 2.5 0.5 2.5 0.6 3.7 1.6 0.5 3.40.6 2.2 0.4 2.7 0.5 3.6 1.2 0.44.2 0.5 2.3 0.5 2.40.7 3.4 1.3 0.64.0 0.8 2.3 1.2 2.7 0.8 4.1 1.3 1.3 3.6 0.9 2.5 1.9 3.2 0.9 3.5 1.6 2.04.2 0.9 1.9 0.5 2.2 0.4 1.8 1.40.5 4.1 0.5 2.2 0.5 2.40.5 1.9 1.6 0.64.1 0.5

0.6 0.6 3.2 0.5 3.3 0.1 0.7 5.6 0.6 0.6 0.64.0 0.6 3.0 0.0 0.6 6.0 0.6 0.6 0.5 4.9 0.7 3.1 0.0 0.5 6.3 0.7 0.3 0.4-0.1 0.1 1.8 0.0 0.5 1.6 0.1 1.1 0.8 3.6 0.6 0.9 0.40.9 5.40.6 2.7 0.8 3.2 0.8 3.3 1.8 0.84.7 0.8 2.3 0.5 2.5 0.7 3.0 1.3 0.5 5.6 0.7 2.5 0.5 2.6 0.6 3.2 1.6 0.64.9 0.6 2.2 0.4 2.5 0.6 2.7 1.40.5 4.6 0.6

1.4 1.0 3.40.8 4.5 0.5 1.04.6 0.8 1.8 0.5 2.8 0.5 4.2 0.7 0.5 4.9 0.5 2.5 0.4 3.0 0.5 3.2 1.8 0.44.40.6 2.0 0.3 1.7 0.6 3.5 1.3 0.3 3.40.7 2.5 1.1 2.9 1.1 3.4 1.7 1.1 4.9 1.2

2.3 0.6 2.9 0.6 3.8 1.40.64.5 0.6 1.5 0.5 3.1 0.5 4.0 0.6 0.6 5.1 0.5 0.3 0.3 2.0 0.1 0.9 0.2 0.3 3.3 0.1

2.5 1.5 2.0 0.4 2.3 1.9 1.6 3.2 0.4 0.8 1.8 3.0 0.9 1.40.0 1.9 4.3 1.0 0.8 0.8 2.5 0.6 0.9 0.2 0.8 3.3 0.7 1.9 0.5 2.7 0.8 3.1 0.8 0.5 3.9 0.8 1.3 0.3 1.9 0.4 2.6 0.5 0.3 3.6 0.4 2.0 0.6 3.0 1.4 3.0 0.8 0.64.4 1.50.6 1.2 2.3 0.6 1.2 0.1 1.3 3.8 0.6

1.2 0.5 2.5 0.6 2.40.5 0.6 3.8 0.6

0.3 0.1 1.0 0.1 1.9 0.1 0.2 2.0 0.2 1.5 0.4 1.7 0.7 2.8 0.8 0.4 3.9 0.7 0.9 0.2 1.6 0.2 2.6 0.3 0.3 3.3 0.3 0.6 0.5 3.2 0.5 2.8 0.0 0.5 4.40.6 0.9 0.4 3.8 0.8 2.8 0.1 0.4 5.3 0.8 0.9 0.5 3.9 0.7 2.9 0.1 0.5 6.0 0.8 0.8 0.4 3.8 0.7 2.9 0.1 0.44.1 0.7 0.8 0.5 3.5 0.6 3.0 0.0 0.5 5.2 0.6 0.7 0.4 3.40.5 3.0 0.0 0.4 5.2 0.5 0.7 0.5 3.40.6 3.0 0.1 0.5 4.8 0.6 1.4 1.8 1.3 0.2 1.6 0.9 2.0 2.8 0.3 1.7 0.5 2.6 0.6 4.0 0.8 0.5 4.3 0.7 1.40.5 3.2 0.8 4.6 0.7 0.6 2.9 0.9 0.7 1.0 3.6 0.8 3.8 0.1 1.1 5.2 0.8 1.8 0.9 2.9 0.6 3.4 1.1 1.0 3.7 0.6 2.5 0.5 2.5 0.5 3.8 1.6 0.5 3.8 0.6 1.6 1.2 2.8 0.7 3.3 0.9 1.3 3.7 0.7 2.0 0.7 3.0 0.7 4.0 1.2 0.7 4.2 0.7 2.1 0.4 2.0 0.5 3.5 1.2 0.4 3.40.6 2.0 1.0 3.1 0.7 3.9 1.2 1.0 5.2 0.8 2.5 0.6 2.40.8 4.9 1.5 0.6 2.3 0.8 1.2 1.1 2.1 0.4 2.5 0.5 1.1 4.40.4 1.2 1.2 2.9 0.5 3.1 0.5 1.2 5.2 0.5

3.0 0.4 2.9 0.7 3.5 1.7 0.4 5.6 0.7

1.5 0.3 2.3 0.4 3.5 0.7 0.3 3.6 0.5

2.8 0.5 2.8 0.9 3.8 1.5 0.5 5.3 0.9 3.2 0.4 3.5 0.8 3.8 1.7 0.4 6.2 0.8 1.9 0.6 3.0 0.8 3.3 0.40.6 5.9 0.8 2.2 0.5 3.0 0.8 3.5 1.0 0.5 5.1 0.9 1.6 0.4 2.40.6 2.9 0.6 0.44.5 0.7

2.7 0.6 3.3 0.8 3.9 1.5 0.6 5.40.8

1.1 0.3 2.5 0.5 2.6 0.40.3 4.7 0.50.5 0.5 2.8 0.4 2.9 0.1 0.5 4.6 0.4

0.9 0.44.0 0.7 3.0 0.1 0.5 5.8 0.8 0.5 0.5 3.6 0.6 2.9 0.0 0.64.9 0.7 1.6 0.7 1.8 0.3 1.8 0.8 0.8 3.9 0.3 1.0 0.5 3.0 0.7 3.5 0.2 0.5 4.7 0.7 0.8 0.9 3.8 0.8 3.40.0 0.9 4.7 0.8 0.7 0.5 3.7 0.7 3.3 0.1 0.6 5.2 0.7 0.6 0.5 2.5 0.3 3.1 0.0 0.64.2 0.3 1.1 0.5 2.9 0.4 3.6 0.2 0.64.3 0.4

1.1 1.5 2.6 0.6 3.1 0.2 1.64.0 0.7 0.5 2.7 2.40.8 1.8 0.0 2.84.5 0.8 0.5 1.1 3.40.5 3.2 0.0 1.2 5.5 0.5 1.8 0.9 2.3 0.5 1.1 1.2 1.0 3.9 0.5 1.5 1.0 2.6 0.6 1.1 1.0 1.1 4.2 0.7 1.7 1.1 2.40.5 1.1 1.0 1.2 4.40.5 1.0 0.3 2.6 0.4 2.0 0.40.3 4.0 0.5 0.9 0.4 3.2 0.6 3.1 0.1 0.44.40.6 0.7 0.4 3.5 0.6 1.2 0.1 0.44.5 0.7 0.7 0.2 4.0 0.7 1.2 0.0 0.3 5.5 0.8

1.3 0.64.8 0.7 0.9 0.6 0.7 6.5 0.7 0.8 0.7 3.7 1.0 3.6 0.2 0.8 5.6 1.0 0.9 1.2 4.0 0.8 4.2 0.3 1.2 5.7 0.8

1.9 0.3 2.1 0.4 2.4 1.3 0.3 4.3 0.4 2.2 0.4 1.9 0.3 2.5 1.5 0.5 4.2 0.3 2.2 0.4 2.40.5 2.8 1.40.5 4.40.5 1.6 0.3 1.7 0.2 2.2 1.3 0.4 3.40.2 2.1 0.8 2.40.5 2.6 1.40.84.9 0.5201020102010201020112011201120112012

1 2 3 4 1 2 3 4 1 3.5 4.3 4.7 3.3 4.04.3 5.0 2.9 2.8 3.5 3.44.2 3.2 3.44.44.7 2.7 2.6 3.9 3.44.3 3.0 3.5 4.1 4.2 2.8 2.5 3.2 4.1 3.5 3.1 3.3 4.1 4.4 2.5 2.2 3.5 4.1 3.6 2.7 3.1 4.1 5.0 2.1 2.4 0.7 0.9 1.3 1.0 0.8 1.4 1.8 1.1 0.8 2.6 3.1 3.8 2.6 3.3 3.1 3.7 2.3 2.6 0.5 0.9 0.8 0.7 0.7 1.2 1.40.9 0.7

1.7 1.4 2.1 1.4 1.3 1.3 2.1 1.9 1.1 0.9 1.9 2.3 1.3 0.9 1.7 2.4 1.3 1.1 1.2 2.9 4.4 1.7 1.2 2.6 0.5 0.8 0.5 0.40.40.9 0.8 0.6 0.5 0.9 1.1 1.7 1.0 0.8 1.2 1.8 1.1 0.7 0.8 0.8 1.2 0.8 0.8 1.1 1.8 1.2 0.8 1.2 2.4 3.4 1.5 1.1 2.5 3.9 1.6 1.2 1.0 3.1 3.4 1.1 0.9 2.3 4.0 1.5 1.2 1.3 1.3 1.6 1.0 0.9 1.2 1.7 1.3 0.8 1.6 1.4 1.6 1.3 1.8 1.1 1.9 2.1 1.0 1.4 1.6 2.0 1.5 1.8 1.7 2.5 2.3 1.6 1.0 2.1 2.5 1.1 0.8 2.1 3.6 1.1 0.9 1.4 1.3 0.9 1.0 1.0 1.1 1.3 0.9 0.9 1.3 1.40.9 1.1 0.9 1.2 1.3 0.9 1.0

3.2 4.2 5.6 3.1 3.0 3.3 4.6 2.3 2.6 2.9 2.6 2.5 2.5 3.0 3.1 1.7 1.7 2.3 2.8 3.3 2.7 2.7 3.2 3.4 2.7 1.8 2.4 3.4 3.5 2.2 2.4 3.2 3.9 2.9 1.7 2.4 3.44.1 3.5 2.5 2.3 4.04.4 2.0 2.6 3.4 3.9 3.4 2.5 3.2 4.2 3.8 1.9 2.5 4.44.04.8 2.9 3.44.5 4.6 2.3 2.5 3.7 4.0 3.4 2.8 3.04.2 4.6 2.0 2.1 1.3 1.2 0.8 0.7 0.8 1.2 1.1 0.7 0.7 2.1 2.6 2.4 1.7 2.5 2.7 3.4 1.8 2.1 3.4 3.2 5.4 2.6 2.9 3.3 2.1 2.1 2.5 5.9 3.44.8 2.6 3.8 3.5 3.7 2.0 3.0 2.5 1.9 2.6 1.7 2.4 3.0 2.2 1.6 1.9 3.3 2.5 2.1 1.6 3.0 2.9 2.5 1.7 2.1 4.9 4.7 4.9 4.1 3.84.3 6.0 2.6 3.0 5.04.6 6.44.0 3.84.04.9 2.1 2.7 Speciation Measurements Sulfates4.5 4.5 5.44.2 3.9 4.2 6.7 2.2 2.7

4.1 4.7 3.7 4.7 3.7 3.4 3.9 4.44.5 2.7 2.7 3.4 3.5 4.9 3.0 3.3 3.84.0 2.4 2.8 3.6 3.04.6 2.8 2.7 3.3 3.9 2.1 2.5 1.7 2.1 2.6 1.7 2.3 2.0 2.3 1.5 1.9 2.1 2.5 3.3 2.8 2.5 2.4 3.1 2.0 2.6 2.5 3.3 4.0 2.7 3.0 3.3 4.4 1.7 3.2 1.2 2.0 2.3 1.8 2.1 2.0 2.3 1.7 2.6 2.9 2.84.6 2.4 2.9 3.8 5.1 1.9 3.6 1.4 2.9 3.6 2.5 2.3 2.6 3.7 2.0 3.4 2.8 2.84.0 2.3 2.7 3.44.5 2.2 3.0 2.5 4.5 5.2 3.1 2.8 3.2 5.1 2.0 3.8 2.2 3.4 3.4 2.9 3.0 2.3 4.3 1.9 4.0 2.5 1.6 1.6 1.7 1.9 2.4 1.8 1.6 1.6 2.4 1.6 1.5 1.6 2.0 2.2 1.8 1.8 1.6

3.5 3.2 2.6 3.1 3.7 3.4 2.7 2.4 3.2 3.5 3.5 3.1 3.7 4.5 4.0 2.4 2.7 3.5 4.84.4 3.0 2.5 3.9 3.7 1.6 2.5 3.5 3.3 4.2 2.3 3.6 3.5 4.3 2.4 2.1 1.7 1.40.8 0.7 1.5 0.8 0.6 0.6 0.8 0.8 0.8 0.8 0.8 0.5 3.3 2.9 3.7 3.1 3.3 3.4 3.7 2.5 3.5 2.3 3.3 3.3 2.5 3.1 2.7 3.8 2.2 2.0 2.2 3.5 3.3 2.9 3.4 2.3 3.5 2.2 2.4 2.5 3.8 2.9 2.9 3.2 3.2 3.7 2.0 2.7 3.7 3.5 4.3 3.44.3 4.1 5.1 1.5 2.4 4.2 4.9 5.84.5 4.1 4.6 7.7 2.1 3.2 5.0 5.2 5.3 4.2 4.7 4.1 7.1 2.6 2.9 2.1 2.9 3.7 3.3 3.0 3.04.2 1.9 3.2 3.4 2.8 3.9 4.0 3.4 3.3 5.7 2.1 2.6 3.1 3.5 3.6 3.44.4 3.04.7 2.1 3.2 2.9 4.0 3.9 3.0 3.1 3.2 4.5 3.7 3.2 4.7 3.5 3.4 3.7 6.6 2.4 3.0 4.44.3 5.5 3.7 4.2 4.6 6.3 2.5 2.7 0.9 0.6 0.6 0.5 0.6 0.7 3.4 2.1 2.6 2.0 1.9 3.2 2.9 1.6 2.2 0.8 0.5 1.2 1.5 0.8 0.7 0.40.8 0.7 0.40.40.8 0.9 0.6 0.4 2.2 2.7 3.8 2.1 2.8 3.1 3.8 2.1 2.4 2.5 2.9 3.7 2.1 2.0 2.3 3.8 1.9 2.1 2.7 3.3 3.9 2.1 3.0 3.44.1 2.6 2.60.8 1.0 0.9 0.7 0.5 1.1 1.2 0.8 0.6

1.9 2.5 3.8 1.6 2.2 1.8 2.9 1.7 1.8 3.2 3.4 1.6 1.5 2.0 1.0 1.5 1.9 2.4 3.2 1.9 2.2 2.6 3.1 1.8 2.4 2.3 3.7 4.5 2.2 2.5 2.3 4.0 1.8 2.1 4.1 3.84.6 2.2 2.5 4.2 5.4 2.1 1.9 3.8 3.9 4.9 2.6 2.7 4.0 3.9 1.8 2.4 3.7 4.04.5 2.8 3.0 3.7 3.8 2.0 2.4 4.1 4.5 4.3 3.2 2.1 4.0 3.4 2.4 2.3 3.64.04.7 3.0 2.8 3.9 4.3 1.9 2.5 3.84.44.4 2.7 2.9 3.8 3.5 1.8 2.6 3.5 4.64.4 2.7 2.7 3.64.8 2.2 2.2 2.2 1.3 1.3 1.5 1.7 1.7 1.4 1.1 1.5 4.04.2 5.9 3.5 4.04.1 6.8 2.4 2.9 4.2 5.7 5.3 4.6 5.1 5.4 7.2 4.1 4.4 5.3 4.9 5.3 4.5 4.7 2.0 5.4 2.9 2.8 2.8 3.44.2 2.1 3.2 3.1 4.9 2.4 3.3 2.9 2.84.0 2.7 3.0 3.6 5.7 1.7 4.2 3.7 4.5 4.5 2.9 3.1 2.9 5.4 2.4 3.0 4.1 3.3 5.0 3.4 3.44.0 5.9 2.1 2.9 3.6 3.5 5.1 2.4 2.8 3.4 3.8 5.1 2.9 3.44.1 4.1 2.5 3.4 3.4 3.5 5.7 3.44.0 5.3 6.3 3.6 6.0 2.4 2.3 2.7 2.3 2.9 3.5 2.3 1.6 1.9 3.2 3.1 3.3 2.1 4.4 3.2 2.6 2.4 2.1 0.3 0.6 0.6 0.40.4 1.0 0.8 0.6 0.3 0.40.6 0.5 0.40.5 1.3 0.7 0.5 0.5 0.2 0.5 0.6 0.40.4 1.0 0.9 0.5 0.3 3.2 3.3 4.9 2.7 2.8 3.64.5 2.0 2.8 4.3 5.0 5.3 3.4 3.1 3.8 3.8 2.6 1.9 3.7 5.3 1.8 3.3

3.6 3.5 3.5 4.9 2.4 3.2 3.5 4.5 1.7 3.3 3.1 3.3 3.5 4.4 2.5 2.9 5.7 4.6 2.2 2.8 2.3 3.5 4.3 2.0 2.4

3.5 3.7 4.7 2.9 2.8 3.84.7 1.9 3.3 1.7 2.4 3.4

2.1 1.7 2.4 2.3 2.5 1.8 2.2 3.3 3.9 3.6 3.23.64.3 4.6 2.8 2.5 3.9 3.9 1.8 2.6

3.9 4.04.7 2.6 2.6 3.9 4.8 1.8 2.5 2.84.1 4.5 2.0 2.3 3.1 1.6 1.9 2.1 2.0 2.0 2.4 1.6 1.5 4.1 3.9 3.8 3.04.1 3.4 5.0 2.8 2.2 4.2 3.5 4.4 2.9 4.9 3.9 4.6 2.5 2.4 5.1 4.1 4.9 2.4 2.7 4.9 4.8 2.0 2.8 3.2 3.1 3.8 2.8 3.5 3.44.0 2.5 2.4 3.8 3.7 4.4 3.1 3.7 3.6 5.1 2.5 2.0 4.8 3.5 2.9 3.0 3.5 4.1 6.0 2.0 3.3 3.4 2.5 3.6 3.8 3.4 2.4 2.3 0.9 1.3 1.40.9 0.9 1.6 1.7 1.3 1.0 2.4 3.7 3.9 2.8 2.7 3.6 3.4 2.2 2.5 1.2 0.9 0.9 0.8 0.9 0.9 1.0 1.0 0.9 1.5 0.8 1.0 0.9 1.3 0.9 1.1 1.0 0.7 1.1 0.8 0.9 0.7 0.8 1.1 1.2 0.7 0.8 1.7 1.5 2.6 1.3 1.7 1.2 1.4 1.6 1.8 3.84.4 5.0 2.9 2.9 3.7 4.2 2.4 2.4 0.8 0.9 1.40.6 0.7 0.8 1.2 1.1 0.8 0.9 1.0 1.5 0.8 0.8 0.9 1.6 0.9 0.6 0.6 1.2 1.7 0.6 0.7 1.2 1.7 0.8 0.6 0.7 0.8 0.6 0.5 0.9 0.9 0.6 5.9 4.2 5.8 3.5 3.64.4 5.9 2.4 2.9 5.9 2.6 3.4 4.3 4.7 5.9 4.2 3.64.8 8.8 2.0 2.3 2.1 2.2 2.5 1.9 2.0 2.3 2.4 1.9 2.3 2.3 2.6 2.8 2.2 2.2 2.5 3.3 2.2 2.9 1.5 1.6 1.7 1.9 1.9 2.3 1.6 2.2 2.4 2.0 2.7 2.6 2.7 2.2 3.0 3.4 2.0 2.9201220122012 201020102010201020112011

2 3 4 1 2 3 4 1 2 3.5 3.5 2.7 1.6 0.6 0.5 1.0 1.3 0.5 3.7 3.0 2.5 1.3 0.5 0.4 1.0 1.3 0.5 3.3 3.2 2.1 2.2 0.5 0.4 1.6 1.40.5 3.4 2.7 2.7 1.3 0.40.3 0.8 0.9 0.4 3.3 2.3 2.5 2.0 0.40.40.9 0.9 0.4 1.4 1.9 0.9 1.1 0.3 0.2 0.8 1.0 0.3 3.2 2.5 2.3 2.1 0.5 0.4 1.5 2.2 0.5 1.6 1.0 0.40.4 2.0 1.9 0.7 0.8 1.3 0.7 1.6 1.8 1.2 7.6 1.6 1.4 8.2 5.8 1.3 1.8 2.6 1.5 1.8 1.2 0.8 1.6 2.40.8 4.04.8 3.7 4.1 4.9 2.8 1.1 1.1 0.3 0.7 0.3 0.2 0.5 0.5 0.3 1.2 1.3 0.6 4.2 0.8 0.8 3.3 3.7 0.8 1.4 1.40.9 3.8 0.7 0.8 3.8 3.0 0.8 2.4 3.1 0.9 2.9 3.2 3.1 2.9 2.0 2.2 2.7 2.9 1.9 3.2 3.7 2.7 2.2 1.7 2.1 1.4 1.6 0.7 2.8 1.2 1.7 2.5 2.6 1.0 1.4 1.6 1.3 5.8 1.5 1.6 7.9 9.40.9 2.4 2.2 1.1 5.6 2.2 2.7 8.7 6.9 2.4 2.1 2.6 1.3 2.4 2.8 2.4 2.3 1.7 2.5 1.0 0.9 0.7 3.3 1.40.4 1.4 2.0 0.8 1.3 1.2 3.7 1.40.4 2.1 1.8 1.0

0.6 2.6 3.2 2.4 2.4 1.2 0.6 2.4 2.5 0.8 2.6 1.9 1.6 1.2 0.7 0.5 0.7 0.8 0.6 2.6 2.0 2.0 0.8 0.6 0.40.7 0.8 0.5 2.3 2.1 2.0 0.7 0.40.3 0.6 0.6 0.3 3.1 2.3 2.2 1.3 0.5 0.3 0.40.5 0.4 2.9 3.0 1.9 1.40.5 0.3 1.0 0.8 0.3 3.5 3.0 2.2 1.40.5 0.3 1.1 0.6 0.4 3.0 2.3 2.2 1.40.40.3 0.6 0.5 0.4 1.2 1.2 0.6 3.9 1.6 0.6 2.4 2.6 1.1 2.0 2.2 2.1 1.4 1.5 0.6 1.2 1.8 1.2 2.2 2.9 2.5 3.8 1.40.7 2.2 2.7 1.3 2.9 3.3 2.7 7.5 1.7 0.8 3.2 4.2 1.2 2.9 2.0 1.9 4.0 0.5 0.4 1.9 4.40.8 2.8 2.4 2.0 6.3 0.8 0.5 0.9 4.7 0.9 3.64.1 2.4 2.7 0.5 0.4 1.9 1.7 0.6 3.0 3.9 2.2 2.1 0.3 0.2 1.1 0.9 0.3 Speciation Measurements Nitrates3.64.1 2.2 3.7 1.0 0.7 2.9 2.7 0.9 4.9 0.8 3.8 3.2 2.7 1.3 0.8 0.5 1.3 1.40.8 3.1 3.7 2.7 2.9 1.3 0.7 2.7 3.1 1.0 2.6 3.7 2.3 2.1 1.2 0.4 1.7 2.1 0.6 1.6 2.0 1.8 0.9 0.6 0.4 1.2 1.8 0.6 2.5 2.7 2.2 4.3 0.9 0.9 5.1 4.6 1.8 2.4 2.8 2.3 4.7 0.9 1.2 4.04.7 1.8 1.8 1.9 1.3 0.5 0.3 0.2 2.1 2.0 0.3 2.2 3.9 2.4 5.7 0.9 1.2 3.6 3.8 1.1 2.6 3.3 2.4 1.2 1.0 0.7 3.2 3.1 1.2 2.6 3.1 2.3 4.6 1.1 0.9 3.1 4.8 1.9 3.0 3.8 2.6 4.2 1.3 1.1 4.6 3.9 1.7 3.1 2.0 2.4 3.4 1.1 0.9 3.7 4.2 1.4 1.4 1.2 1.5 4.9 1.1 1.3 1.2 1.7 5.7 1.1 0.5 2.7 5.4 1.2 8.0 1.1 0.6 2.4 3.6 0.40.4 1.0 1.2 0.4 3.5 2.7 2.3 1.9 0.5 0.40.9 1.1 0.5 2.9 2.5 2.2 1.9 0.7 0.40.7 1.0 0.5 3.3 2.8 2.3 1.7 0.40.3 1.5 0.7 0.5 1.2 0.9 1.3 0.40.3 0.8 0.8 0.7 2.3 0.5 0.4 1.7 2.7 0.5 2.4 3.1 1.8 9.3 1.6 1.1 5.3 5.9 3.1 2.1 3.0 2.5 5.8 1.5 0.8 3.8 5.0 2.2 2.3 3.5 2.4 6.5 0.9 0.84.9 6.3 1.5 2.1 2.6 1.6 6.6 1.7 0.7 5.0 5.7 2.1 2.4 0.2 4.6 0.9 0.7 3.5 4.5 1.1 3.7 5.0 2.9 4.8 0.8 0.7 3.0 2.7 0.9 3.44.6 2.7 6.3 1.40.7 3.7 4.9 1.1 2.3 2.8 2.1 5.6 1.2 1.0 6.5 4.2 2.1 2.9 3.1 2.6 7.2 1.6 1.1 5.04.2 1.8 2.7 2.9 2.7 6.3 1.0 0.8 5.4 5.8 2.1 7.1 1.5 0.9 5.1 5.2 2.1 3.3 3.0 3.0 7.2 1.1 0.9 4.3 4.8 1.6 3.44.3 2.7 4.6 1.0 0.6 3.3 3.6 0.9 0.7 0.7 0.6 0.5 0.2

0.4 1.6 2.0 1.8 1.7 8.2 1.3 0.7 3.04.9 1.4 1.4 1.8 0.7 1.0 1.40.3 1.0 1.0 0.4 2.0 0.40.2 1.2 1.7 0.3 2.7 2.5 2.3 1.8 1.40.6 1.9 2.3 1.9 1.9 2.3 1.9 1.4 1.1 0.4 1.40.8 1.0 2.7 1.8 2.6 2.7 1.6 0.8 1.9 2.5 1.81.2 1.3 0.6 1.2 0.3 0.2 0.8 1.0 0.4

1.9 2.1 1.9 2.1 0.7 0.4 1.6 2.8 0.6 2.6 1.9 1.5 1.6 1.2 0.6 0.3 2.0 2.6 2.1 2.7 0.7 0.3 1.8 2.9 0.8 1.9 2.6 1.9 1.40.5 0.2 1.4 1.40.6 2.8 2.5 2.1 1.0 0.5 0.4 1.0 0.7 0.4 2.6 2.5 2.0 1.7 0.9 0.7 2.0 1.5 0.6 2.7 2.5 2.0 1.8 0.5 0.5 1.5 1.3 0.6 2.3 2.9 2.0 1.6 0.7 0.5 2.1 2.0 0.4 2.9 2.7 1.9 1.5 0.6 0.5 1.6 1.6 0.4 2.7 2.6 2.0 1.5 0.6 0.4 1.4 1.2 0.6 2.5 3.0 2.1 1.40.7 0.4 1.1 1.40.5 1.3 0.9 1.3 4.5 0.7 0.3 1.9 3.8 1.0 3.3 4.2 2.8 5.6 1.0 0.8 2.5 4.2 1.3 3.2 4.6 3.5 3.1 0.7 0.4 2.8 3.3 0.9 3.5 4.5 2.3 3.2 0.5 0.4 2.1 2.3 0.2 2.5 3.3 2.2 5.2 0.9 0.8 2.1 3.8 1.2 2.9 3.3 2.3 5.5 0.8 0.9 4.04.7 1.5 2.6 3.2 2.0 5.2 0.8 0.7 3.4 3.2 1.2 3.5 3.8 2.8 7.6 1.2 0.9 3.8 2.7 2.3 2.7 3.0 2.6 4.8 1.7 3.3 3.5 2.7 6.9 1.3 1.0 3.7 3.8 1.6 3.7 4.2 3.1 5.2 1.6 0.8 3.2 4.9 1.3 2.8 2.0 1.7 3.0 0.7 0.4 1.9 3.8 0.8 3.3 2.8 2.1 3.40.7 0.5 2.0 3.9 0.7 0.7 0.7 1.0 0.3 0.3 0.7 1.40.4 0.8 0.7 0.3 0.2 0.1 0.40.7 0.2 0.7 0.8 0.2 0.1 0.0 0.2 0.2 0.2 3.0 3.0 2.6 3.8 2.2 1.2 3.1 3.0 2.0 3.0 0.7 0.4 2.1 2.6 3.1 2.7 2.2 0.9 0.4 1.6 1.6 1.8

2.3 2.8 3.2 2.5 3.2 3.0 2.6 4.7 2.6 1.8 3.0 3.5 2.1 2.6 2.5 2.3 3.2 2.8 2.5 3.8 1.8 1.0 2.1 3.1 1.6 2.3 2.7 2.1 1.7 1.0

4.2 2.7

2.2 3.4 3.4 2.6 3.9 1.8 1.1 2.9 2.9 1.8 1.2 0.8 0.5 1.8 2.4 2.1 0.5 1.0 1.6 0.7 1.1 0.5 0.40.82.7 1.9 2.1 1.5 0.40.4 1.0 1.0 0.4

2.4 2.9 2.2 0.8 0.5 0.4 2.2 1.0 0.4 3.0 2.4 1.9 1.40.4 1.5 1.5 1.4 6.8 0.9 0.6 3.3 3.9 2.5 3.3 3.7 2.0 3.9 0.6 0.4 1.9 1.8 0.7 3.5 3.0 2.3 1.5 0.5 0.5 1.3 0.9 0.6 3.4 2.5 2.3 1.1 0.40.4 1.1 0.8 0.4 2.7 3.1 2.1 1.1 0.40.3 1.2 1.40.4 3.44.1 2.3 4.0 0.6 0.5 1.9 1.9 0.5 0.8 0.40.2 1.1 0.6 0.3 3.5 2.7 1.9 2.3 0.6 0.7 1.5 2.0 0.7 1.5 1.9 1.2 1.6 0.40.3 0.8 0.9 0.4 3.5 2.6 2.1 0.6 0.40.40.6 0.9 0.5 0.9 1.1 0.7 5.7 0.8 0.3 2.64.8 0.6 0.9 1.1 0.7 8.8 0.7 0.3 3.9 5.6 0.6 1.0 1.1 0.6 7.5 1.1 0.4 2.8 7.1 0.6 1.4 1.9 1.4 2.1 0.5 0.3 1.3 1.9 0.5 2.5 2.9 2.3 1.5 0.6 0.4 1.3 1.6 0.5 0.9 1.40.6 0.8 0.5 0.5 0.7 1.1 0.3 1.0 1.7 0.4 0.9 0.6 0.5 0.8 1.2 0.4 0.7 0.6 0.9 0.8 0.9 0.7 0.8 0.8 0.7 1.6 2.6 2.2 0.2 3.9 3.1 2.3 3.1 0.6 0.5 1.6 1.6 0.8 3.7 4.8 2.7 4.3 0.6 0.4 2.2 2.2 0.8 2.2 1.8 1.3 2.0 2.1 1.8 4.7 1.0 0.8 3.1 4.1 1.9 2.1 2.6 1.5 3.9 1.40.9 3.9 4.2 2.4 1.7 1.2 1.6 1.40.5 0.5 3.3 3.1 1.5 1.7 2.5 1.5 4.3 1.2 0.9 5.3 3.8 2.8201120112012201220122012 201020102010

3 4 1 2 3 4 1 2 3 0.40.8 1.0 0.5 0.4 1.0 0.7 1.4 1.7 0.3 0.9 0.9 0.40.40.9 0.9 1.9 2.5 0.3 1.2 1.2 0.6 0.4 1.1 0.3 1.1 1.0 0.2 0.5 0.6 0.40.3 0.7 0.4 1.5 1.6 0.3 0.6 0.8 0.40.3 0.7 0.3 0.6 1.3 0.3 0.9 0.7 0.40.40.6 0.5 1.2 0.8 0.4 1.3 1.3 0.5 0.4 1.3 0.4 1.0 1.5 0.5 4.2 1.1 0.7 0.5 0.5 1.1 0.5 0.6 1.8 1.613.2 9.5 1.3 1.6 5.3 0.40.5 1.3 0.8 2.5 2.2 1.2 1.0 2.8 1.6 2.1 2.2 1.2 0.8 0.7 0.2 0.6 0.7 0.5 0.3 0.9 0.7 0.9 1.2 0.9 4.4 2.7 0.8 0.9 1.8 0.3 0.8 0.9 0.9 6.9 2.5 1.0 1.0 2.5 0.40.7 0.8 3.4 3.9 2.3 2.7 2.5 3.0 0.6 0.5 0.5 3.1 3.7 2.0 2.8 2.4 2.5 0.7 0.6 0.7 1.5 3.8 3.2 1.5 1.9 1.7 0.40.40.4 1.415.3 5.5 1.6 1.3 5.9 0.5 0.7 1.4 2.716.913.6 3.0 2.7 5.6 0.5 0.7 1.7 3.7 2.0 1.9 2.4 2.5 2.9 0.40.6 0.6 0.4 2.1 2.7 0.6 0.4 1.4 1.2 1.1 1.5 0.5 2.2 3.9 0.9 0.5 1.0 1.0 1.2 1.5 0.7 1.7 2.1 0.9 0.7 2.4 0.5 0.8 0.5 0.5 0.5 0.7 0.5 0.6 0.5 0.4 1.5 1.7 0.40.5 0.7 0.6 0.5 0.6 0.3 1.3 1.4 0.2 0.3 0.5 0.3 0.2 0.4 0.2 1.0 1.5 0.3 0.40.8 0.5 0.40.6 0.7 1.9 2.2 0.2 0.6 0.8 0.40.40.6 0.3 1.1 0.7 0.3 0.5 0.9 0.40.3 0.7 0.4 1.5 1.0 0.2 0.40.5 0.40.2 0.7 0.6 1.3 1.1 0.9 2.8 2.0 0.9 1.0 2.5 1.1 1.1 2.2 1.0 1.1 2.6 0.9 0.7 2.1 0.3 0.6 0.4 1.4 1.3 3.0 0.8 0.5 2.1 0.2 0.6 0.5 0.8 1.8 3.4 1.2 0.8 2.8 0.5 0.7 0.5 0.4 2.4 2.1 0.9 0.4 2.7 0.5 1.0 1.3 0.4 1.2 2.4 1.0 0.6 2.9 0.7 1.0 0.8 0.3 1.0 1.1 0.5 0.5 1.1 0.40.5 0.7 0.1 0.6 0.40.3 0.2 0.6 0.2 0.40.3 Speciation Measurements Nitrates0.7 1.8 1.7 0.7 0.7 1.9 0.3 0.6 0.6 0.3 0.5 0.5 1.1 1.0 0.6 0.6 1.0 0.5 1.3 2.1 0.8 1.9 2.6 1.1 0.7 3.1 0.40.7 0.5 0.4 1.0 1.6 0.6 0.4 1.6 0.40.8 0.8 0.3 1.3 1.7 0.6 0.5 1.4 0.2 0.40.2 0.8 2.4 3.1 1.3 0.7 4.2 0.3 0.8 0.4 1.0 2.4 3.9 1.2 0.84.0 0.3 0.7 0.3 0.2 1.6 2.40.5 0.3 1.3 0.1 0.40.1 0.9 2.64.0 1.3 1.0 3.6 0.3 0.7 0.4 0.8 1.9 3.5 1.5 0.6 3.0 0.2 0.5 0.4 1.1 2.6 3.3 1.3 1.0 3.7 0.40.7 0.5 1.2 2.44.0 1.3 0.9 2.9 0.6 1.6 1.1 1.1 2.3 4.1 1.40.6 3.8 0.8 1.3 1.1 0.5 2.6 3.1 0.7 0.4 3.3 0.6 2.5 3.4 1.0 0.4 3.8 0.40.8 0.5 0.40.6 0.4 0.3 1.0 0.8 0.4 0.8 2.2 0.3 0.8 0.8 0.40.40.9 0.4 1.1 2.1 0.40.5 1.0 0.5 0.3 0.7 0.3 1.0 1.1 0.3 0.7 0.9 0.40.3 0.7 0.5 1.0 0.5 0.2 0.2 0.3 0.3 0.2 0.3 0.3 2.8 1.5 0.40.7 1.6 0.3 0.7 1.9 1.0 2.04.3 1.3 1.1 4.3 0.5 1.1 0.7 1.0 2.5 2.6 1.4 1.04.4 0.40.7 0.5 0.7 2.5 3.5 1.5 0.7 4.3 0.2 0.6 0.5 0.9 2.6 3.4 1.1 0.9 3.4 0.3 0.6 0.3 0.7 0.8 2.1 0.6 0.1 1.4 2.4 2.7 0.7 1.7 1.7 0.8 0.9 2.3 0.40.9 0.9 0.7 2.4 2.3 1.0 1.0 2.9 0.3 0.5 0.5 1.0 2.7 4.2 1.1 0.9 3.8 0.2 0.5 0.3 0.8 2.2 3.0 0.9 0.8 3.4 0.2 0.40.3 0.9 3.2 3.9 1.1 0.9 4.1 0.7 1.3 1.0 1.0 0.5 1.0 0.6 0.7 2.5 3.0 1.2 0.9 3.9 0.3 0.6 0.5 0.6 1.8 2.0 0.8 0.7 2.5 0.40.7 0.6 0.1 0.3 0.5 0.2 0.2 0.5 1.1 0.4 0.6 2.64.8 1.0 0.6 3.4 0.9 1.8 1.0 0.3 1.2 1.0 0.40.5 1.0 0.2 1.5 1.2 0.40.4 1.1 1.0 0.8 0.8 0.8 1.9 2.7 1.2 0.7 3.2 0.3 0.40.4 0.4 1.2 2.1 0.7 0.4 2.2 0.2 0.40.2 1.1 2.4 2.8 1.2 0.7 3.2 0.6 1.1 1.10.2 1.2 0.8 0.40.3 0.9 0.5 1.2 0.5

0.4 1.3 1.9 0.6 0.4 1.8 0.40.8 0.6 0.6 0.9 0.1 0.3 0.5 0.2 0.1 0.5 0.4 1.8 2.2 0.7 0.4 2.6 0.3 0.6 0.4 0.3 1.1 1.3 0.40.2 1.6 0.2 0.40.2 0.3 0.5 0.8 0.6 0.5 0.7 0.2 0.9 0.6 0.40.8 1.5 0.6 0.5 1.1 0.2 0.8 0.6 0.40.6 1.40.7 0.4 1.1 0.3 0.6 0.7 0.3 0.6 1.3 0.40.4 1.2 0.2 0.8 0.8 0.3 0.8 1.1 0.5 0.4 1.0 0.40.7 0.8 0.3 0.6 1.2 0.40.4 1.0 0.2 0.8 0.7 0.3 0.7 1.0 0.5 0.4 1.0 0.3 0.9 0.6 0.4 1.6 2.5 0.8 0.3 2.2 0.4 1.8 1.6 0.7 1.9 2.2 0.9 0.7 2.8 0.3 0.5 0.5 0.5 1.9 2.7 0.6 0.6 1.8 0.40.40.6 0.3 0.9 1.0 0.6 0.40.8 0.7 0.9 0.6 0.6 2.2 3.2 0.9 0.6 2.5 0.4 1.3 0.4 0.7 2.4 5.4 1.2 0.9 2.5 0.3 0.7 0.5 0.7 1.8 2.8 0.8 0.6 2.0 1.2 1.5 0.8 0.8 2.3 2.3 1.0 0.9 3.7 0.40.6 0.4 0.8 2.3 2.8 1.5 0.7 3.2 0.9 2.1 3.2 1.1 0.8 2.8 0.6 2.1 1.4 1.0 3.1 5.6 1.1 0.7 2.6 0.3 0.7 0.5 0.3 2.6 1.7 0.6 0.5 2.0 0.40.7 1.3 0.3 1.8 1.9 0.6 0.6 1.9 0.6 1.0 1.3 0.2 1.2 1.0 0.3 0.3 0.6 0.6 0.4 0.1 0.40.5 0.2 0.3 0.6 0.7 1.3 0.2 0.2 0.2 0.2 0.2 0.3 0.40.3 1.4 2.2 5.0 1.9 1.2 3.9 0.2 0.5 0.3 0.7 1.4 1.1 0.6 1.2 2.40.8 0.4 2.3 0.2 0.40.2 3.7 4.5 1.7 1.04.0 1.9 2.1 4.8 2.0 1.5 4.4 0.2 0.5 0.3

2.7 1.40.7 2.9 1.0 2.1 3.3 1.40.7 3.5 0.3 0.9 0.6 0.7 1.7 2.6 0.7 0.7 2.5 0.3 1.4

1.0 1.0 2.1 4.4 1.5 1.2 3.6 0.5 0.7 0.6 0.2 0.9 0.4 0.5 0.9 1.8 0.5 0.4 1.8 0.1 0.3 0.6 1.00.2 0.4 1.0 0.40.3 0.6 0.2 0.6 0.8

0.3 0.7 1.8 0.40.4 1.0 0.2 1.0 0.8 0.3 0.5 0.8 0.40.3 0.7 0.7 2.2 2.1 1.0 0.5 2.8 0.2 0.7 0.6 0.4 1.9 1.40.6 0.6 1.5 0.3 0.7 1.0 0.40.8 1.1 0.6 0.5 1.1 0.3 1.2 0.9 0.3 0.6 1.1 0.5 0.40.9 0.3 0.5 0.6 0.2 0.6 0.9 0.3 0.3 0.9 0.4 1.2 1.8 0.4 1.5 1.1 0.7 0.6 1.8 0.3 0.6 0.9 0.2 0.3 0.8 0.6 0.6 2.0 1.6 0.6 0.7 1.5 0.5 1.1 2.2 0.3 1.1 0.8 0.40.40.6 1.4 3.1 1.5 0.3 0.5 0.6 0.3 0.40.6 0.3 0.7 1.9 0.3 4.3 3.8 0.6 0.5 2.2 0.40.9 0.9 0.3 4.4 3.3 0.5 0.4 1.9 1.7 1.4 1.1 0.4 3.64.1 0.8 0.6 1.4 0.6 0.9 2.0 0.2 1.3 1.8 0.5 0.4 1.4 0.3 0.6 0.3 0.3 1.0 1.2 0.6 0.4 1.3 0.3 0.7 0.6 0.3 1.3 0.8 0.5 0.7 0.7 0.3 0.3 0.4 0.5 1.0 0.8 0.6 0.7 0.6 0.6 0.3 0.2 0.6 0.9 0.9 0.40.3 0.2 0.3 3.4 2.2 0.40.5 2.1 0.7 0.4 1.2 1.2 0.6 0.4 1.0 0.5 0.7 0.7 0.3 1.1 1.40.6 0.4 1.3 0.6 1.2 1.2 1.0

3.1 3.7 0.8 0.6 2.3 0.6 2.2 3.4 1.1 0.6 3.6 0.1 0.40.6 0.7 3.3 4.4 1.1 0.8 2.7 0.3 0.6 0.5 0.4 2.4 3.40.40.2 2.6 0.3 0.6 0.2 0.8 3.04.40.7 0.7 2.6 0.40.9 0.7201020112011201120112012201220122012

4 1 2 3 4 1 2 3 4 1.2 1.4 1.0 0.9 0.9 0.8 0.8 1.2 0.8 1.9 1.4 1.8 0.9 1.0 1.7 0.9 1.7 1.0 0.40.3 0.8 0.5 0.40.3 0.6 0.7 0.3 0.6 0.3 0.7 0.7 0.40.7 0.6 1.0 0.5 0.5 0.3 0.7 0.5 0.3 0.40.6 0.9 0.4 0.9 1.5 2.0 1.6 1.0 1.6 1.9 1.0 1.7 0.7 0.40.9 1.0 0.6 0.7 0.9 2.0 0.7 0.40.3 0.5 1.2 0.5 0.4 1.3 0.6 1.3 0.6 0.5 0.40.5 1.3 0.8 0.6 0.8 1.3 1.0 2.0 2.5 2.3 2.6 2.8 2.9 3.2 3.3 6.7 0.9 0.9 1.1 0.3 0.5 0.5 0.8 0.5 0.5 1.1 0.7 0.3 0.40.3 0.40.7 0.5 0.3 0.6 0.6 0.4 0.6 0.40.5 0.6 0.6 0.40.7 0.7 0.6 0.5 0.5 0.6 0.5 1.0 0.6 0.6 0.40.5 0.5 0.5 0.5 0.6 0.7 0.7 0.8 0.6 0.5 0.5 0.5 0.3 0.40.7 0.5 0.5 0.40.5 1.0 0.40.5 1.1 0.9 0.5 0.9 1.0 0.3 0.6 0.40.7 1.9 0.9 1.0 1.2 1.8 0.8 0.40.40.7 0.7 1.2 1.6 1.7 0.7 0.4 1.2 1.1 2.1 1.7 1.5 1.2 2.0 0.9 2.2 0.9 0.9 1.5 1.5 0.8 0.9 1.3 1.1 1.0 0.3 0.2 0.40.3 0.5 0.40.5 0.6 0.4 0.5 0.5 0.8 1.6 0.3 0.4 1.5 3.6 0.3 0.3 0.3 0.6 1.0 0.3 0.5 1.0 2.1 0.5 0.40.3 0.6 0.6 0.3 0.40.4 1.40.3 0.40.7 1.7 0.9 0.40.8 1.4 1.40.8 0.40.2 0.5 0.5 0.3 0.40.5 0.8 0.4 0.7 0.40.7 0.6 0.3 0.5 0.7 0.6 0.5 0.40.3 0.7 0.5 0.3 0.3 0.6 0.9 0.4 1.8 1.0 1.7 1.9 2.0 0.6 2.6 1.5 1.2 0.40.40.40.40.40.40.5 0.40.4 0.2 0.2 0.40.3 0.2 0.2 0.5 0.3 0.2 0.5 0.40.40.3 0.40.40.5 0.40.5 0.9 0.7 1.3 1.8 0.7 0.6 1.3 1.3 1.4 1.1 0.40.7 1.0 0.8 0.7 1.1 1.40.9 0.40.3 0.40.40.40.3 0.7 0.6 0.5 0.3 0.2 0.3 0.2 0.2 0.2 0.3 0.5 0.2

Speciation Measurements Crustal0.6 0.40.5 0.7 0.7 0.5 0.6 0.7 0.4

1.0 0.40.7 1.0 0.6 0.5 0.9 2.5 0.8 0.3 0.3 0.40.40.40.40.5 0.5 0.3 0.40.3 0.40.40.5 0.3 0.5 0.40.4 0.2 0.3 0.3 0.2 0.2 0.2 0.3 0.2 0.2 0.8 0.3 0.3 0.6 0.40.40.6 0.7 0.3 0.3 0.2 0.3 0.3 0.2 0.2 0.5 0.3 0.3 0.1 0.1 0.2 0.2 0.2 0.2 0.3 0.3 0.1 0.3 0.2 0.40.8 0.40.40.7 0.5 0.4 0.3 0.2 0.40.3 0.3 0.3 0.5 0.40.3 0.40.40.7 0.6 0.40.40.8 0.5 0.5 1.1 0.8 1.1 1.0 0.7 1.3 1.9 0.9 0.8 2.1 0.9 0.8 1.1 1.0 1.5 2.4 2.3 1.6

0.2 0.3 0.40.40.3 0.6 0.6 0.4 1.0 0.5 0.7 0.5 0.5 0.3 0.6 0.8 0.5 0.7 0.6 0.3 0.7 0.8 0.3 0.3 0.5 1.7 1.0 1.3 0.8 0.40.3 0.6 1.3 0.3 0.6 0.2 0.6 0.7 0.3 0.40.6 1.1 0.3 0.40.3 0.5 0.40.3 0.40.6 0.6 0.4

0.40.40.40.3 0.8 0.6 0.1 0.2 0.8 0.5 0.6 1.5 0.40.3 0.7 1.5 0.7 0.8 0.4 1.2 1.7 0.8 0.5 1.1 1.0 0.6 0.5 0.3 0.6 0.5 0.40.2 0.7 0.8 0.4 0.5 0.2 0.40.40.40.3 0.6 0.9 0.3 1.1 0.40.6 0.7 0.3 0.3 0.6 0.5 0.4 3.9 2.8 3.8 1.9 4.8 2.1 3.6 0.0 1.2 0.6 0.9 0.8 1.0 1.0 1.1 1.2 0.7 0.5 0.3 0.6 0.40.3 0.3 0.6 0.8 0.3 0.5 0.3 0.40.40.40.3 0.5 0.40.3 0.3 0.3 0.5 0.3 0.2 0.2 0.5 0.3 0.3 0.9 1.0 0.8 0.8 0.6 0.9 1.5 1.0 1.0 0.6 0.5 1.2 0.7 0.5 0.3 0.6 0.5 0.40.40.6 0.9 0.4 0.6 0.40.8 0.5 0.3 0.3 0.6 0.8 0.4

0.2 0.2 0.40.1 0.2 0.40.5 0.1 0.6 0.9 0.40.7 1.1 1.1 1.2 1.6 2.3 0.7 0.9 0.9 0.9 1.3 1.3 1.7 2.2 1.6 1.6 0.5 1.0 0.5 0.7 0.9 0.7 1.2 0.6 0.6 0.40.3 0.40.5 0.5 0.40.6 0.6 0.4 0.2 0.1 0.2 0.3 0.2 0.2 0.3 0.3 0.2 0.6 0.40.6 0.7 0.7 0.5 0.7 0.6 0.60.5 0.8 1.8 1.0 0.7 0.9 1.9 0.9 1.0

0.40.5 0.6 0.3 0.7 0.40.6 0.6 0.4

0.1 0.2 0.2 0.1 0.1 0.2 0.2 0.1 0.2 0.3 0.3 0.3 0.3 0.3 0.5 0.40.3 0.1 0.1 0.2 0.2 0.2 0.2 0.3 0.3 0.2 0.2 0.2 0.5 0.40.2 0.3 0.6 0.7 0.2 0.3 0.2 0.5 0.3 0.2 0.3 0.5 0.6 0.3 0.40.3 0.5 0.40.3 0.3 0.5 0.6 0.5 0.3 0.2 0.40.2 0.2 0.2 0.40.7 0.3 0.3 0.3 0.5 0.40.3 0.3 0.40.7 0.3 0.3 0.2 0.5 0.3 0.2 0.2 0.40.6 0.2 0.3 0.3 0.5 0.5 0.3 0.3 0.5 0.7 0.3 2.6 0.3 0.6 2.2 1.7 0.7 2.1 3.6 1.0 0.40.3 0.5 0.40.3 0.40.7 0.40.6 0.5 0.3 0.40.40.3 0.5 0.7 0.6 0.3 0.8 0.5 0.2 0.8 0.9 1.3 1.2 0.8 0.8 0.5 0.2 0.40.40.7 0.8 0.9 0.9 1.0 0.7 0.3 0.40.5 0.7 0.40.6 0.6 0.3 1.3 0.8 0.8 0.9 0.9 0.6 1.7 1.4 1.1 0.5 0.2 0.5 0.40.40.40.7 0.8 0.7

0.2 0.40.2 0.2 0.2 0.3 0.7 0.3 1.2 0.6 0.8 0.9 0.9 1.2 1.0 1.1 0.6 0.2 0.2 0.5 0.3 0.3 0.5 1.0 0.5 0.3 0.6 0.6 1.0 1.3 0.40.6 1.1 1.8 0.7 0.6 0.5 0.8 1.0 0.5 0.7 0.8 2.1 1.1 0.3 0.6 0.3 0.7 0.40.5 0.5 1.3 0.8 0.7 0.6 1.1 0.40.6 0.9 1.5 0.1 0.2 0.2 0.3 0.1 0.1 0.3 0.5 0.2 0.2 0.3 0.2 0.3 0.3 0.40.40.3 1.3 0.2 0.1 0.3 0.2 0.2 0.3 0.3 0.3 0.3 0.2 0.40.5 0.5 0.4 0.2 0.2 0.3 0.3 0.3 0.40.40.40.4 0.40.5 0.9 0.5 0.40.3 0.40.40.40.3 0.6 0.5 0.4

0.2 0.40.3 0.40.3 0.5 0.40.3 0.5 0.4

0.4 0.40.40.5 0.7 0.5 0.5 0.8 0.6 0.5

0.2 0.2 0.2 0.3 0.2 0.3 0.5 0.3 0.2 0.40.2 0.1 0.5 0.5 0.2 0.2 0.5 1.0 0.2

0.3 0.3 0.7 0.40.2 0.2 0.5 0.8 0.3

0.3 0.7 0.6 0.3 0.3 0.5 0.8 0.4 1.1 0.2 0.4 1.0 0.6 0.5 1.0 1.0 0.5 0.5 0.3 0.6 0.5 0.40.40.6 0.7 0.4 0.40.40.6 0.5 0.40.5 1.2 1.1 0.8 0.40.2 0.8 0.40.40.40.6 0.8 0.4 0.7 0.40.9 0.6 0.40.5 0.7 0.7 0.3 0.3 0.2 0.5 0.5 0.3 0.40.6 0.8 0.4 0.2 0.2 0.40.4 0.6 0.6 1.1 2.1 0.6 0.9 1.0 3.0 1.0 3.7 3.2 6.2 2.5 2.1 2.5 2.8 2.5 2.8 0.3 0.3 1.0 0.9 0.3 0.6 0.8 2.3 0.7 0.5 0.5 0.9 1.0 0.7 0.8 1.3 1.1 0.6 0.6 0.8 0.9 0.8 0.7 0.9 1.2 1.0 0.8 0.8 0.7 1.2 1.0 0.8 1.0 1.7 1.1 0.6 0.1 0.2 0.7 0.5 0.2 0.40.40.3 0.2 0.3 0.2 0.40.3 0.3 0.3 0.40.6 0.3 0.2 0.40.1 0.3 0.3 0.2 0.3 0.7 0.3 0.3 0.3 0.2 0.3 0.2 0.2 0.3 0.40.1 0.3 0.3 0.2 0.2 0.3 0.3 0.5 0.5 0.2 0.7 0.40.40.6 1.1 0.4 0.5 0.3 0.6 0.40.5 0.6 0.7 0.8 0.8 0.6 1.3 1.9 0.9 1.0 0.9 1.0 0.7 0.8 0.9 0.2 0.2 0.40.40.2 0.3 0.2 0.2 0.3 0.5 0.5 0.5 0.6 0.2 0.5 0.2 0.40.40.40.40.5 0.5 0.3 0.3 0.2 0.3 0.2 0.3 0.3 0.5 0.40.2 0.7 0.5 0.6 0.9 0.5 0.7 1.0 0.9 0.5201020102010201020112011201120112012

1 2 3 4 1 2 3 4 1 3.4 5.2 2.9 3.1 2.6 3.0 2.9 2.9 2.0 3.4 3.8 3.7 5.1 3.7 5.3 5.5 3.3 3.3 3.0 2.9 3.0 3.6 2.84.1 3.6 2.6 3.2 3.5 3.1 2.84.5 2.9 4.1 3.7 3.0 3.5 5.7 5.5 3.0 6.4 5.4 7.3 4.2 3.2 5.5 2.1 1.2 0.9 2.1 2.1 0.9 1.0 2.0 2.0 2.7 3.7 3.5 4.6 2.9 2.8 2.5 2.5 1.6 5.4 1.6 3.2 7.511.2 1.8 2.915.1 7.8

5.5 2.0 3.5 6.4 5.1 1.8 3.3 9.3 7.0 3.1 3.44.3 5.2 4.9 3.1 3.4 7.1 6.5 9.9 7.1 8.3 7.810.0 8.2 15.8 5.8 3.214.216.3 5.6 2.824.927.2 4.9 1.1 2.0 5.3 4.4 1.2 2.2 7.5 6.5 3.7 1.1 2.84.4 3.0 1.5 2.6 7.04.0 4.5 1.8 2.4 5.1 3.7 1.9 2.6 6.3 3.2 5.1 2.5 3.0 5.6 3.3 1.8 3.1 6.1 3.3 3.5 1.8 2.64.2 4.0 2.0 2.3 6.1 4.5 3.8 1.5 4.1 5.3 5.0 1.8 2.5 9.6 3.8 4.1 3.04.7 4.7 4.3 2.44.5 7.9 7.0 1.9 2.0 3.3 2.2 1.7 2.1 3.5 2.4 1.5 3.2 1.7 2.1 2.7 2.2 1.6 2.7 3.3 2.8 3.2 1.8 1.7 2.3 1.8 1.8 2.3 2.4 2.6

3.1 2.8 3.6 2.7 2.0 3.0 3.3 3.1 2.3 2.3 0.8 0.5 1.5 1.6 2.0 0.7 0.8 1.3 2.3 2.2 1.9 2.9 2.9 2.8 1.8 2.1 3.0 3.5 3.4 2.4 6.1 5.0 3.6 3.8 3.3 5.0 4.9 5.3 3.8 5.0 5.5 5.5 5.6 3.1 4.8 2.7 4.1 3.2 4.5 3.9 4.4 3.3 3.5 4.0 3.6 5.0 3.9 6.2 3.64.7 3.7 3.1 3.8 5.3 6.4 3.64.7 4.1 6.1 4.5 3.6 5.0 1.4 1.1 1.7 1.9 1.5 1.2 2.0 2.3 1.6 2.3 2.6 2.4 2.7 2.4 2.2 2.8 3.0 2.4 2.2 2.5 3.5 2.5 1.6 2.2 1.1 1.6 2.1 3.5 2.9 3.8 3.0 2.4 2.7 3.0 2.6 2.7 1.5 1.8 2.7 2.1 2.3 2.8 2.0 2.3 1.8 3.5 3.0 3.1 4.0 3.3 3.9 2.9 4.44.0 3.3 3.2 3.3 3.9 2.7 3.1 3.5 3.3 3.5 2.0 2.3 2.8 2.6 1.5 2.3 2.4 1.4 2.0 Speciation Measurements Organic Carbon2.6 1.9 3.4 3.7 1.9 2.6 3.6 1.8 2.5

3.0 2.1 2.7 3.2 2.84.1 3.3 3.1 3.0 3.5 2.2 3.3 2.8 3.3 3.4 3.2 2.9 3.1 3.8 3.4 2.2 2.9 2.6 2.3 1.8 2.6 2.8 2.3 2.1 1.7 2.7 2.4 2.6 3.1 2.04.3 2.8 3.3 2.5 2.7 3.3 3.7 2.6 2.5 2.9 3.0 2.3 2.0 2.7 2.7 2.7 2.2 1.9 2.2 1.8 1.8 1.0 2.0 2.1 1.40.9 1.8 2.0 1.0 1.6 2.2 2.4 2.6 3.0 1.9 1.8 2.8 1.9 2.0 1.3 2.9 3.2 3.0 2.0 2.3 2.6 1.8 2.5 2.3 2.0 3.2 2.7 2.5 2.4 2.6 2.3 1.9 2.4 3.5 3.7 3.5 2.5 2.2 3.4 2.2 2.6 2.2 3.5 3.8 3.6 2.7 2.3 3.4 2.6 3.0 1.9 2.2 2.2 2.2 1.7 2.7 2.2 3.0 2.6 2.5 2.2 2.5 2.5 2.0 2.7 2.4 2.6 2.7

3.6 3.1 3.5 3.1 5.3 3.7 3.4 2.1 4.6 3.5 3.9 7.0 3.44.44.8 3.7 2.9 4.44.6 3.1 4.8 2.64.4 6.3 3.1 5.4 4.3 2.7 2.8 6.64.1 4.4 3.9 5.4 5.8 0.0-0.1-0.1-0.2-0.1 2.0 1.1 2.4 2.6 2.7 1.1 3.3 4.1 1.9 3.6 2.9 3.9 4.4 2.9 3.5 3.6 3.6 3.3 3.1 2.6 3.2 3.1 2.2 2.8 2.9 2.4 2.2 2.6 1.9 3.0 3.4 2.4 1.9 2.4 2.4 1.9 2.4 2.8 3.5 3.3 2.5 3.0 3.2 1.9 2.2 2.5 2.6 3.84.5 3.8 3.8 3.9 3.8 2.2 3.5 2.8 3.5 5.0 2.7 3.4 3.8 3.3 3.0 3.3 2.4 3.3 3.3 3.1 3.1 3.0 2.2 2.6 2.6 2.5 4.7 4.4 2.7 2.6 3.2 3.1 2.9 2.1 2.1 2.5 3.8 2.0 2.3 2.2 1.3 1.5 3.2 2.5 3.8 3.6 3.2 3.1 3.2 1.9 2.5 3.1 2.6 3.7 3.4 2.6 2.7 3.2 2.7 3.1 3.5 3.8 2.9 3.2 3.4 2.6 2.6 2.6 2.8 3.5 3.5 2.9 3.2 3.2 2.1 3.0 0.3 0.5 2.5 0.8 0.3 9.6 1.7 2.2 2.2 1.4 1.6 2.5 2.1 2.0 2.0 3.0 3.8 1.3 1.7 4.9 4.3 3.4 1.2 2.3 3.4 3.3 1.3 2.9 4.6 2.8 2.44.1 4.1 3.0 2.8 3.0 5.1 4.2 2.3 1.9 2.2 2.2 1.6 0.8 1.7 2.3 1.8 1.8 2.7 3.1 3.0 2.9 2.8 3.2 3.5 3.8 2.92.6 1.1 1.2 2.6 2.6 3.9 1.6 2.8 2.1

2.1 2.9 2.8 3.5 3.5 2.2 3.4 2.5 2.3 2.7 3.5 0.6 0.9 2.6 0.40.4 1.5 2.1 2.4 1.9 2.0 2.3 2.4 1.9 1.6 1.1 1.8 1.9 1.3 1.0 1.2 1.8 1.3 1.1 2.4 2.8 3.0 3.2 2.4 3.2 2.8 2.4 3.0 4.0 3.5 3.5 5.4 3.5 4.1 3.5 3.44.7 4.1 3.4 3.4 6.2 3.2 3.4 3.3 3.3 3.9 2.3 3.2 3.7 3.9 2.1 2.6 2.4 3.0 3.8 2.9 3.7 3.3 4.3 2.9 4.1 3.2 3.9 3.7 3.0 3.7 3.3 5.1 2.7 3.1 3.4 3.6 3.1 2.5 4.1 3.8 3.8 3.1 3.64.3 3.2 3.4 1.2 1.8 2.1 1.5 0.8 0.9 1.8 1.7 0.9 2.8 2.3 3.5 3.2 2.2 2.5 2.7 2.4 2.3 2.5 2.9 3.3 4.2 2.3 2.9 3.1 3.5 3.5 3.5 3.0 3.1 3.3 2.0 3.3 3.1 3.04.4 2.1 2.7 3.2 2.8 2.2 2.3 3.6 2.8 2.7 2.3 2.5 2.8 3.1 2.1 2.0 3.2 2.1 2.7 2.7 2.9 3.4 3.8 2.0 2.0 3.2 2.5 2.5 3.0 2.6 3.5 3.8 2.0 3.0 2.9 2.7 2.5 2.2 2.3 2.1 1.8 1.8 3.8 3.44.04.0 2.4 2.8 3.0 2.9 3.1 2.6 3.5 3.3 3.5 2.3 3.5 3.4 2.3 2.5 1.2 1.7 3.1 2.1 2.1 2.6 2.2 2.2 1.6 2.9 2.9 2.5 2.4 3.1 3.9 2.6 2.5 2.5 10.2 2.2 0.912.310.1 4.4 2.513.111.2 5.9 1.7 2.4 8.513.8 2.6 2.710.512.5 9.2 1.5 1.5 7.310.0 2.5 2.411.012.7 2.3 2.9 2.7 2.4 1.8 2.1 2.6 2.1 3.3 3.3 3.1 3.2 4.9 2.0 2.5 2.1 2.3 1.2 2.1 2.3 2.2 2.6

2.9 2.9 3.4 3.0 3.0 2.3 2.6 2.9 2.8 3.5 1.9 2.6 3.8 3.1 2.7 2.2 3.7 3.7 2.7 2.7 1.4 3.0 2.9 2.7 2.1

2.8 3.2 2.8 3.0 2.1 2.7 3.5 2.4 3.2 1.8 2.3 2.7

1.4 2.5 2.2 1.7 2.5 2.3 2.7 3.1 2.3 1.7 3.63.1 3.2 3.2 2.7 2.1 3.5 3.6 2.2 3.0

2.9 4.2 3.8 5.8 3.2 4.7 4.1 3.04.8 3.8 3.7 4.0 3.3 3.9 1.3 1.6 1.9 1.8 1.0 1.2 2.0 2.0 1.2 3.6 2.8 3.04.3 2.8 2.9 3.5 3.4 3.1 3.44.0 3.7 5.2 4.0 5.2 3.9 3.5 3.9 4.0 3.2 3.5 3.9 2.2 4.2 3.0 2.5 3.3 2.0 2.8 2.5 2.8 1.9 3.2 2.8 2.0 2.4 2.2 2.4 3.3 3.2 2.2 3.44.1 3.0 2.7 2.44.3 3.9 4.7 2.2 4.4 6.0 2.3 1.9 2.4 2.8 2.7 3.4 2.4 2.7 2.3 3.8 1.5 1.64.7 3.1 2.9 1.7 2.1 2.3 3.0 3.5 3.6 3.810.3 3.2 3.8 3.3 2.7 1.7 0.8 1.7 1.7 1.6 0.7 1.8 2.5 1.7 2.8 1.0 1.8 2.7 2.4 1.2 2.2 3.2 2.2 2.6 0.9 1.9 1.6 2.2 1.4 1.8 2.5 1.9 1.7 2.5 2.7 2.0 2.1 1.8 3.8 2.5 2.6 2.6 3.0 3.5 3.0 2.4 3.2 3.0 3.6 3.1 3.6 1.3 1.9 5.3 7.5 1.0 1.6 8.2 4.9 4.7 1.5 1.8 6.3 7.5 0.9 1.8 6.4 6.1 4.8 1.6 2.3 5.4 6.3 1.6 2.1 6.7 4.5 3.9 6.6 6.7 0.8 2.6 6.1 5.5 3.5 3.3 4.1 4.4 2.6 3.2 3.2 3.0 3.7 1.7 3.5 5.0 3.1 2.6 3.0 3.9 2.6 2.4 3.3 1.8 1.6 1.9 1.8 2.3 1.8 1.5 1.8 2.0 1.9 2.0 2.2 2.4 3.0 2.5 2.1 2.3 2.6 2.5 2.4 1.2 1.8 2.3 1.6 1.3 1.7 1.9 1.8 1.7 2.3 2.7 3.4 3.8 1.8 2.7 2.9 2.5 2.6201220122012 201020102010201020112011

2 3 4 1 2 3 4 1 2 2.3 2.0 3.6 1.1 1.3 0.7 1.0 0.6 0.7 4.0 3.4 3.4 0.7 0.7 0.7 1.1 0.7 0.8 3.2 2.8 2.8 0.5 0.40.5 0.6 0.5 0.5 3.3 2.64.8 1.0 0.40.40.9 0.7 0.5 3.4 2.9 5.2 1.0 0.7 0.4 1.3 0.9 0.6 0.9 1.1 1.9 0.6 0.3 0.3 0.6 0.6 0.2 3.6 3.2 4.5 0.6 0.6 0.6 0.8 0.5 0.4 2.7 0.6 0.2 0.5 1.3 1.3 0.7 2.44.1 4.5 2.3 3.2 6.2 1.0 0.3 0.5 1.2 0.8 0.3 5.1 3.2 8.8 0.6 0.6 0.8 0.8 0.9 0.4 1.9 1.1 1.4 1.8 1.6 1.0 7.0 3.413.6 1.6 0.7 0.4 1.4 1.5 0.5 1.6 2.7 5.2 1.0 0.2 0.4 1.1 0.8 0.2 1.9 3.6 3.9 0.7 0.3 0.5 0.9 0.5 0.3 1.9 2.2 5.6 0.9 0.40.5 1.2 0.8 0.4 2.4 2.9 4.9 0.9 0.40.5 1.0 0.6 0.3 2.2 2.4 3.9 0.6 0.2 0.4 1.0 0.8 0.3 2.3 3.2 3.3 0.7 0.3 0.6 1.2 0.7 0.3 3.84.04.2 0.6 0.3 0.6 0.8 0.6 0.3 2.1 3.4 2.2 0.5 0.3 0.6 0.6 0.40.4 1.4 3.0 2.2 1.40.6 0.8 1.3 1.0 0.5 2.1 3.1 1.1 0.6 0.6 1.0 0.8 0.5

2.2 2.2 3.1 3.4 0.7 0.5 0.6 0.7 0.5 0.5 1.1 0.7 1.1 0.6 0.3 0.3 0.5 0.5 0.4 2.2 1.3 2.2 0.5 0.3 0.3 0.7 0.5 0.4 2.6 2.84.1 0.8 0.5 0.3 1.2 0.9 0.5 4.4 3.7 4.9 0.9 0.7 0.5 1.0 0.8 0.7 3.5 3.2 4.4 1.1 1.4 1.4 1.5 1.1 1.3 4.2 3.1 4.4 0.7 0.9 0.6 1.6 1.3 1.6 3.9 3.04.8 0.9 0.7 0.5 0.8 0.6 0.7 2.4 3.1 1.9 0.5 0.3 0.5 0.8 0.5 0.3 2.3 2.7 3.3 0.8 0.9 0.7 1.0 0.8 0.8 1.6 2.2 2.4 0.5 0.40.5 0.5 0.3 0.3 2.5 2.9 2.9 0.9 0.6 0.7 1.0 0.6 0.6 2.9 2.3 2.1 0.40.3 0.40.40.40.4 3.7 3.6 3.8 0.6 0.5 0.7 0.7 0.5 0.5 3.7 3.2 3.7 0.7 0.7 0.7 0.8 0.5 0.6 2.8 2.6 2.0 0.40.3 0.5 0.5 0.3 0.4 Speciation Measurements Elemental Carbon2.8 2.8 2.4 0.5 0.40.5 0.8 0.40.5 0.7 0.7 2.8 2.5 3.8 0.7 0.7 0.6 0.9 0.7 0.7 2.7 2.9 4.7 0.7 0.6 0.6 1.0 0.9 0.6 2.5 3.0 3.0 0.6 0.6 0.7 0.7 0.40.5 2.4 2.6 2.4 0.3 0.5 0.40.6 0.8 0.4 2.7 3.2 3.2 0.5 0.6 0.7 0.8 0.5 0.5 2.1 2.4 2.1 0.40.40.5 0.5 0.40.3 1.1 2.1 1.0 0.1 0.2 0.2 0.2 0.1 0.2 2.1 2.9 2.8 0.5 0.40.8 0.7 0.40.4 2.7 2.9 2.5 0.2 0.5 0.5 0.6 0.40.4 2.3 3.0 2.5 0.8 0.7 1.0 0.8 0.6 0.7 2.6 3.1 2.3 0.6 1.1 1.1 1.1 0.6 0.6 2.9 3.7 3.1 0.5 0.7 1.0 1.1 0.6 0.7 2.1 2.5 2.4 0.3 0.4 2.2 3.0 2.6 0.5 0.40.5 0.6 0.5 0.4 0.5 0.40.5 0.6 3.7 0.5 0.5 0.7 0.6 0.7 3.5 2.9 3.6 0.8 0.6 0.6 1.2 0.6 0.5 3.2 2.9 4.6 0.7 0.6 0.4 1.0 0.5 0.5 4.4 3.4 6.0 0.7 0.5 0.5 0.9 0.5 0.7 -0.1 0.0-0.2 0.1 0.1 1.4 8.3 2.7 0.5 0.3 0.40.6 0.6 0.3 2.5 4.3 2.8 0.8 0.7 0.9 1.0 0.6 0.9 2.4 3.0 2.4 1.0 0.7 0.9 0.8 0.6 0.8 2.7 3.5 2.6 0.5 0.5 0.8 0.8 0.40.4 1.9 3.2 2.6 0.5 0.6 0.7 0.8 0.5 0.6 1.7 4.8 0.6 0.6 1.0 1.0 0.8 0.9 3.4 3.6 3.6 0.6 0.7 0.8 1.1 0.6 0.7 2.8 3.2 2.7 0.6 0.40.6 0.7 0.5 0.5 2.5 3.5 3.1 0.5 0.40.7 0.8 0.40.5 1.6 2.1 1.7 0.40.3 0.40.6 0.3 0.4 2.8 3.6 2.6 1.0 1.2 1.4 1.0 1.1 0.8 0.7 0.9 1.0 0.9 0.6 0.7 3.1 3.1 2.9 0.6 0.6 0.8 0.9 0.6 0.7 3.0 3.3 2.9 0.5 0.5 0.6 0.6 0.5 0.5 0.9 6.0 0.6 0.1 0.1

6.8 1.4 1.6 2.7 1.8 0.40.40.40.40.3 0.4 1.4 2.04.4 1.0 1.2 0.3 1.5 2.9 2.7 1.0 0.3 0.5 1.0 0.9 0.3 2.7 3.0 3.0 0.8 1.1 1.1 1.0 0.9 0.8 1.6 2.3 1.9 0.40.40.40.40.2 0.3 2.8 2.8 3.5 1.2 1.7 1.7 1.5 1.2 1.61.6 2.0 3.2 0.7 0.3 0.40.8 0.8 0.5

2.4 2.7 2.7 0.5 0.6 0.6 0.9 0.8 0.5 2.1 1.4 1.4 1.3 0.6 0.1 0.1 1.4 1.9 1.9 0.3 0.5 0.5 0.5 0.40.4 1.6 2.1 1.8 0.2 0.3 0.3 0.3 0.2 0.2 3.7 2.3 3.7 0.6 0.5 0.6 0.6 0.40.5 3.2 2.9 4.4 0.8 0.6 0.7 1.3 0.7 0.8 3.2 3.0 5.6 0.8 0.5 0.6 1.1 0.5 0.6 3.5 3.3 4.6 0.5 0.5 0.6 0.8 0.40.5 3.1 2.9 4.2 0.6 0.6 0.5 0.8 0.5 0.6 3.4 3.04.1 0.6 0.40.40.8 0.40.5 3.1 3.2 3.9 0.5 0.6 0.5 0.8 0.5 0.5 1.1 2.1 1.2 0.3 0.3 0.3 0.3 0.2 0.2 2.7 2.7 2.7 0.5 0.6 0.8 0.8 0.40.6 3.2 3.3 3.0 0.8 0.7 0.9 1.0 0.6 0.9 3.6 3.2 3.0 1.1 0.9 0.9 1.0 0.5 1.0 3.0 3.4 2.5 0.40.5 0.7 0.8 0.40.5 2.4 3.0 2.0 0.5 0.5 0.6 0.7 0.40.5 3.0 3.5 2.3 0.6 0.8 0.9 0.9 0.5 0.6 3.2 3.4 3.0 0.6 0.8 0.9 1.0 0.5 0.7 1.9 2.3 2.0 0.5 0.7 3.3 3.3 2.8 0.7 0.9 1.0 0.9 0.5 0.7 2.5 2.6 1.8 0.40.6 0.6 0.7 0.40.6 2.5 2.3 1.9 0.3 0.3 0.40.5 0.40.3 3.4 2.9 2.9 0.5 0.40.3 0.5 0.5 0.5 2.6 6.7 1.40.3 0.2 1.8 1.3 0.6 1.5 5.6 0.7 0.3 0.4 1.0 1.6 0.4 2.5 3.8 1.1 0.2 0.2 0.7 1.0 0.3 2.1 3.0 3.4 0.5 0.7 0.7 0.7 0.40.5 0.8 0.7 0.6 1.2 1.9 2.1 2.4 0.40.40.5 0.5 0.3 0.4

2.7 2.5 2.8 3.2 2.8 3.3 4.2 0.6 0.7 0.7 0.8 0.40.5 2.3 3.3 4.4 3.2 3.0 3.3 1.1 1.3 1.2 0.9 0.7 0.8 2.0 2.8 2.9 0.40.6

2.5 1.7

3.2 3.0 3.3 3.7 0.7 0.8 0.8 0.8 0.5 0.5 0.5 0.40.5 1.8 2.6 3.0 0.3 0.6 0.5 0.3 0.6 0.40.3 0.62.7 3.0 2.4 0.5 0.40.40.40.3 0.5

3.7 3.1 4.5 0.7 0.7 0.6 1.2 0.6 0.6 3.3 3.4 3.8 0.7 0.5 2.1 2.4 1.5 0.3 0.3 0.3 0.40.2 0.3 2.8 3.0 3.2 0.7 0.8 0.7 1.2 0.5 0.7 3.9 2.9 4.7 0.7 0.8 0.7 1.1 0.7 0.8 3.6 3.2 4.7 0.8 0.8 0.9 1.0 0.5 0.7 2.4 2.7 2.5 0.40.3 0.3 0.40.3 0.3 2.6 3.5 2.7 0.40.40.40.5 0.3 0.4 1.2 1.2 0.8 0.9 0.6 0.7 3.0 2.4 2.8 0.6 0.5 0.5 0.8 0.7 0.6 2.2 2.1 3.0 1.2 0.5 0.6 1.2 1.0 0.5 4.2 2.84.0 0.5 0.7 0.40.6 1.1 0.4 1.1 4.8 1.8 0.6 0.3 0.3 0.6 0.5 0.2 1.5 4.1 2.6 0.9 0.40.40.9 0.7 0.4 1.3 4.6 1.8 0.6 0.3 0.3 0.5 0.6 0.3 2.2 3.2 2.5 0.3 0.3 0.40.40.40.3 2.7 3.2 3.8 0.6 0.5 0.6 0.7 0.5 0.6 1.6 3.64.0 0.7 0.3 0.4 1.0 1.3 0.2 1.7 3.3 5.0 1.0 0.3 0.4 1.5 1.40.2 1.1 0.40.5 1.1 1.3 0.3 1.2 6.8 5.6 0.8 1.3 1.1 0.2 3.9 3.44.0 0.9 0.9 1.1 1.40.7 0.9 3.4 2.9 4.6 0.7 0.6 0.7 1.1 0.5 0.6 2.2 3.0 1.7 1.7 2.3 1.7 0.3 0.3 0.3 0.40.3 0.3 2.3 3.3 1.6 0.5 0.5 0.7 0.6 0.40.4 1.4 2.6 1.1 0.2 0.2 0.2 0.3 0.2 0.2 2.2 3.4 1.5 0.6 0.6 0.7 0.8 0.5 0.6201120112012201220122012 201020102010

3 4 1 2 3 4 1 2 3 0.8 0.7 0.6 0.5 0.40.9 4.4 5.3 5.6 0.7 0.7 0.8 0.6 0.5 0.7 4.44.04.9 0.5 0.5 0.5 0.5 0.3 0.5 4.84.2 5.2 0.5 0.6 0.6 0.5 0.3 0.7 4.1 4.84.1 0.5 0.8 1.1 0.5 0.40.8 4.4 5.04.4 0.2 0.6 0.6 0.2 0.3 0.6 1.0 1.3 1.7 0.40.5 0.40.6 0.5 1.1 3.2 3.7 4.4 1.0 2.8 2.4 1.0 0.7 1.3 1.1 0.6 1.3 1.5 0.5 1.6 1.2 0.3 0.5 1.1 2.0 1.9 2.9 0.7 1.2 1.1 0.7 0.5 1.7 1.1 2.4 2.8 1.4 3.8 5.6 0.3 2.1 2.0 0.6 0.2 1.4 0.6 1.1 0.8 0.4 1.2 1.2 0.3 0.3 0.9 1.2 1.4 2.2 0.4 1.1 0.7 0.3 0.40.7 1.0 1.1 1.6 0.5 1.40.9 0.40.4 1.3 1.6 3.04.4 0.4 1.0 0.7 0.40.5 0.6 1.3 4.04.5 0.4 1.3 0.8 0.3 0.40.8 1.6 1.7 2.1 0.4 1.5 0.6 0.3 0.40.6 1.9 2.0 2.1 0.5 1.0 1.0 0.40.6 0.7 1.7 2.1 2.7 0.7 0.7 0.40.3 0.5 0.6 1.3 2.8 3.2 1.1 1.5 1.3 0.5 0.8 1.0 1.6 1.7 1.2 0.8 0.9 1.0 0.6 0.7 1.6 1.9 1.2 1.0 0.6 0.9 0.6 0.7 0.6 0.9 3.9 5.2 7.0 0.3 0.3 0.40.40.3 0.4 3.7 3.2 3.3 0.3 0.5 0.6 0.3 0.2 0.5 3.7 3.8 3.2 0.5 0.7 1.1 0.5 0.40.9 4.2 4.0 2.8 0.6 0.8 0.8 0.6 0.4 1.0 4.2 4.64.0 1.1 1.5 1.3 0.9 0.9 1.4 4.44.44.0 1.5 1.1 1.3 1.3 1.0 1.1 5.44.7 5.5 0.5 0.6 0.8 0.5 0.3 0.7 4.64.5 3.9 0.5 0.9 0.7 0.40.5 0.9 1.5 1.6 1.1 1.0 1.3 1.2 1.0 1.1 1.2 2.6 3.2 3.0 0.3 0.40.40.2 0.40.4 4.1 4.1 6.8 0.7 0.8 0.8 0.5 0.6 0.9 6.3 4.4 6.2 0.3 0.5 0.40.40.40.5 3.0 2.5 3.0 0.5 0.6 0.8 0.5 0.6 0.7 3.9 3.2 2.5 0.7 0.6 0.7 0.6 0.6 0.7 6.0 5.7 5.9 0.40.3 0.3 0.3 0.3 0.3 6.0 5.4 7.0 Speciation Measurements Elemental Carbon0.7 0.5 0.6 0.5 0.5 0.5 5.5 5.9 6.9 4.9 6.0 0.7 0.8 0.7 0.5 0.5 0.7 4.9 5.5 4.3 0.7 1.1 1.0 0.5 0.7 1.0 4.1 4.5 6.3 0.6 0.7 0.5 0.5 0.6 0.7 4.6 3.6 5.6 0.8 0.6 0.7 0.5 0.40.5 2.2 2.7 3.1 0.6 0.6 0.5 0.5 0.6 0.7 2.5 3.44.4 0.40.40.40.3 0.40.4 2.9 4.2 5.1 0.2 0.2 0.3 0.2 0.2 0.2 1.7 2.6 2.7 0.7 0.6 0.6 0.5 0.7 0.5 3.3 3.7 6.0 0.5 0.3 0.5 0.5 0.5 0.5 1.7 3.7 4.6 1.0 0.8 0.5 0.7 0.9 0.7 3.2 3.7 5.1 1.1 0.7 0.8 0.9 0.9 0.7 2.9 5.8 6.5 0.9 0.9 0.9 0.8 0.9 0.8 2.64.3 4.3 0.5 0.5 0.40.40.40.5 0.6 0.5 0.40.40.5 0.6 2.8 2.4 2.0 2.7 2.4 2.4 0.6 0.7 0.5 0.5 4.0 3.7 0.7 0.7 0.6 0.5 0.40.7 4.2 4.3 4.2 0.5 0.6 0.8 0.40.3 0.9 4.4 6.0 5.3 0.7 0.8 0.8 0.7 0.5 0.8 4.04.1 4.9 0.1 0.1 0.1 0.1 0.1 0.1 0.6 0.9 0.5 0.3 0.9 0.6 1.0 0.9 0.9 0.9 1.1 0.8 0.7 1.0 0.7 3.6 3.84.7 0.8 0.7 0.6 0.7 0.8 0.6 2.7 4.2 4.2 0.6 0.7 0.5 0.5 0.7 0.6 2.3 4.64.1 0.7 0.5 0.5 0.40.6 0.6 2.9 4.9 3.6 0.8 1.1 0.8 0.6 0.9 4.3 4.2 5.2 0.9 0.8 0.8 0.7 0.7 0.8 5.1 6.1 7.1 0.6 0.5 0.5 0.40.5 0.5 5.9 6.7 6.6 0.7 0.6 0.6 0.5 0.6 0.5 2.5 3.84.7 0.5 0.40.6 0.7 0.6 0.6 4.0 3.7 5.1 1.3 0.9 1.0 1.4 1.2 0.8 3.7 4.5 4.4 0.9 3.3 5.2 5.0 0.8 0.6 0.6 0.6 0.7 0.6 4.3 4.2 6.0 0.6 0.5 0.6 0.5 0.5 0.5 5.1 5.6 6.7 0.1 0.1 0.1 0.1 0.3 0.1 1.4 0.8 0.5 0.40.5 0.3 0.5 0.4 3.9 2.7 3.1 0.6 1.8 1.3 0.40.5 1.4 0.5 1.3 0.9 0.3 0.5 0.8 0.6 1.1 1.0 1.0 0.9 0.7 0.6 0.7 1.0 2.7 3.5 4.9 0.40.40.40.3 0.40.5 3.2 3.84.6 2.3 2.0 1.3 1.2 1.4 1.8 3.3 4.3 5.00.3 0.8 0.7 0.3 0.3 1.0 1.0 1.3 1.2

0.9 0.8 0.6 0.5 0.6 0.7 2.3 3.2 4.5 3.9 4.4 0.2 0.1 0.1 0.2 0.2 0.1 0.6 0.6 0.5 0.6 0.8 0.9 2.3 3.1 4.1 0.3 0.2 0.2 0.2 0.3 0.3 3.04.5 5.2 0.5 0.5 0.6 0.5 0.40.7 5.04.5 5.4 0.7 0.9 1.1 0.5 0.5 0.9 4.7 4.8 6.1 0.6 0.6 0.8 0.5 0.5 1.0 4.7 5.0 5.6 0.40.6 0.8 0.5 0.5 0.9 4.9 5.6 5.3 0.6 0.8 0.7 0.40.40.7 4.5 4.8 5.8 0.5 0.7 0.5 0.40.40.7 4.9 5.2 5.3 0.6 0.6 0.7 0.40.40.8 4.6 5.8 5.2 0.3 0.3 0.2 0.2 0.2 0.2 2.6 1.7 1.6 0.8 0.7 0.6 0.7 0.7 0.7 4.7 5.4 7.5 1.0 1.1 0.9 0.8 0.8 0.8 5.0 7.0 6.6 0.8 0.9 1.0 0.8 0.7 0.6 5.8 5.7 6.0 0.8 0.7 0.6 0.6 0.7 0.5 3.2 4.4 5.3 0.8 0.6 0.6 0.5 0.6 0.4 3.4 3.7 5.1 0.9 0.8 0.7 0.7 0.8 0.6 4.3 5.7 5.7 0.7 0.7 0.7 0.8 0.7 0.6 4.84.4 6.3 0.8 0.6 0.6 0.5 0.6 0.5 0.7 0.8 0.8 0.7 0.8 0.6 4.1 4.9 6.5 0.8 0.6 0.6 0.8 1.0 0.6 3.7 4.5 7.3 0.3 0.5 0.40.40.3 0.4 3.0 2.9 3.1 0.40.5 0.5 0.40.3 0.6 4.0 3.8 3.9 0.2 1.6 1.7 0.40.6 0.40.8 0.8 0.4 1.1 1.40.2 0.7 0.5 0.8 0.6 0.2 1.1 1.2 0.3 0.5 0.3 0.9 1.0 0.7 0.7 0.8 0.40.7 0.8 3.9 4.3 6.4 5.2 6.1 6.3 0.40.5 0.5 0.3 0.40.6 3.9 4.7 4.8 0.6 1.0 0.6 0.9 1.0 0.7 0.7 0.8 0.5 0.7 1.0 4.1 4.5 6.3

0.7 0.6 0.8 1.0 1.0 1.0 0.8 0.7 0.8 1.0 4.1 4.6 5.6 0.6 0.8 0.5 0.40.6 0.9 0.5 0.4

0.9 0.8 0.8 0.8 0.7 0.8 1.0 4.2 4.8 5.9 2.2 3.04.4 0.5 0.6 0.6 0.3 0.40.6 2.4 4.3 4.64.20.40.40.5 0.40.3 0.4 4.5 4.9 5.3

0.6 0.6 1.1 0.5 0.40.9 4.9 4.8 5.8 0.5 0.7 0.8 0.5 0.5 0.8 0.40.40.3 0.3 0.3 0.3 3.6 2.1 2.5 0.8 0.9 0.7 0.7 0.6 0.7 4.9 5.04.6 0.8 0.8 0.9 0.7 0.6 1.0 5.3 4.4 5.3 0.8 0.6 0.7 0.7 0.5 0.9 6.2 4.8 5.6 0.3 0.3 0.40.3 0.2 0.3 4.0 3.84.4 0.5 0.5 0.40.40.40.4 4.64.8 5.5 0.8 6.1 4.4 3.4 0.6 0.9 0.6 0.6 0.5 0.8 2.5 3.9 4.0 0.5 0.8 0.9 0.5 0.5 1.2 1.1 1.7 1.8 0.5 0.6 0.5 0.5 0.5 0.5 3.04.3 4.5 0.40.7 0.6 0.3 0.5 0.6 1.5 1.2 1.2 0.6 1.0 0.7 0.40.6 0.8 1.9 1.1 1.3 0.3 0.8 0.6 0.3 0.5 0.5 1.4 1.2 1.1 0.40.5 0.5 0.3 0.5 0.5 2.1 2.0 3.3 0.6 0.8 0.6 0.40.5 0.7 4.9 5.6 6.1 0.3 1.40.9 0.3 0.5 0.7 1.0 1.2 1.7 0.4 1.3 1.1 0.3 0.5 0.9 1.2 1.4 1.8 0.5 1.3 1.0 0.8 1.5 2.1 0.4 1.1 1.0 0.2 0.6 1.0 0.9 0.9 1.0 1.0 0.9 0.8 1.1 7.1 5.3 7.1 0.40.8 1.0 0.6 0.6 0.8 1.0 5.0 5.7 6.9

0.3 0.3 0.3 0.40.4 0.3 0.40.40.3 0.3 0.3 2.5 2.9 3.1 0.6 0.7 0.6 0.40.6 0.4 2.7 3.4 3.6 0.2 0.3 0.3 0.2 0.2 0.2 2.0 2.1 2.1 0.8 0.6 0.6 0.5 0.6 0.4 2.4 3.6 3.2201020112011201120112012201220122012

4 1 2 3 4 1 2 3 4 4.2 5.1 5.2 5.8 3.6 3.44.04.0 3.3 3.9 4.2 5.1 5.3 3.4 3.1 4.4 3.5 3.0 3.84.5 5.04.9 3.5 3.1 3.9 4.0 2.7 3.9 4.3 4.84.8 3.1 2.7 4.0 3.2 3.3 3.3 4.0 5.1 5.6 2.5 2.9 3.8 2.8 2.9 1.3 1.0 1.9 2.3 1.5 1.1 1.8 2.4 1.2 3.3 4.1 3.7 4.3 2.9 3.1 3.7 3.0 2.8 0.9 0.9 1.6 1.7 1.0 0.9 2.1 1.0 1.7 0.9 1.8 1.6 1.7 2.7 2.4 1.4 2.1 2.3 1.5 1.7 1.2 2.2 2.8 1.6 1.4 2.2 3.1 1.8 2.2 1.4 3.3 0.5 0.5 1.1 1.1 0.7 0.6 1.3 1.5 0.4 1.2 1.0 1.5 2.2 1.3 0.9 1.5 1.7 0.8 1.1 1.0 1.4 2.1 1.6 1.0 1.7 1.7 1.1 1.9 1.4 3.1 4.9 2.0 1.5 3.0 3.8 1.1 1.4 1.2 3.0 5.1 1.8 1.6 3.4 3.6 2.1 1.3 1.1 1.4 2.1 1.6 1.0 1.7 2.0 1.0 1.6 2.1 1.5 2.4 2.7 1.3 1.9 2.2 1.6 1.9 2.2 2.3 3.3 3.0 2.0 3.1 2.9 1.4 1.5 1.1 2.64.6 1.4 1.2 2.6 3.2 1.6 1.3 1.2 1.3 1.6 1.1 1.1 1.3 1.2 0.9 1.5 1.1 1.5 1.6 1.1 1.3 1.7 1.5 0.7 3.8 3.7 4.1 5.5 2.9 3.3 3.3 3.9 3.0 3.0 3.7 3.6 2.4 2.4 3.0 3.4 2.7 2.1 3.3 4.1 4.0 3.4 2.3 3.0 3.3 2.7 2.5 2.7 3.84.5 3.4 2.2 3.0 3.1 2.8 2.5 2.9 2.7 4.5 4.9 2.5 3.2 3.7 2.9 2.6 3.04.1 4.7 4.2 2.2 3.1 3.3 3.6 2.3 3.64.4 5.2 5.2 2.7 2.9 4.0 3.4 2.7 3.3 3.5 4.7 5.1 2.4 2.7 3.6 2.8 2.7 0.9 1.0 1.6 1.5 0.9 0.7 1.5 1.5 0.8 2.2 3.1 3.44.1 2.3 2.6 2.6 2.7 2.7 3.3 3.5 4.2 2.8 2.8 3.0 2.8 3.5 3.1 3.04.5 4.5 4.4 2.6 3.7 3.7 4.1 3.3 2.2 2.9 3.8 2.6 2.0 2.3 3.6 2.4 2.3 2.0 3.6 3.5 3.0 2.1 2.6 3.4 2.9 2.5 5.1 4.8 5.2 6.7 3.1 3.7 4.3 4.7 2.9 4.7 4.64.8 5.6 2.5 3.2 3.5 4.5 2.7

Sulfates SANDWICHed*5.2 4.9 5.3 8.1 2.8 3.44.4 5.2 2.8

4.3 5.0 5.2 5.3 3.2 3.2 4.5 3.9 3.4 3.7 4.1 4.84.9 3.0 3.5 3.84.4 3.2 3.4 3.44.04.3 2.5 3.2 3.1 4.4 2.7 2.1 2.8 2.6 2.6 1.9 2.4 1.9 2.4 2.2 3.4 3.0 3.1 4.0 2.5 3.1 3.2 3.4 2.6 3.2 3.5 4.2 5.5 2.1 3.7 3.0 3.5 2.6 2.3 2.5 2.6 2.7 2.1 3.0 2.4 2.4 1.7 3.0 3.5 4.9 6.3 2.44.3 2.9 4.7 2.9 3.0 2.7 3.44.6 2.5 4.1 3.3 4.0 3.0 2.8 3.1 4.3 5.6 2.7 3.7 3.4 3.8 2.8 3.7 3.3 4.0 6.4 2.5 4.7 3.7 4.7 3.2 3.5 3.5 3.0 5.4 2.44.7 3.8 2.4 2.9

2.9 2.1 2.1 2.1 2.2 1.8 1.6 1.8 2.0 2.8 2.1 1.9 2.0 2.3 1.7 1.5 2.0 2.0 3.3 3.9 4.3 3.9 3.2 3.04.2 4.04.7 5.5 4.7 2.9 3.1 4.1 3.1 2.9 3.7 3.44.5 4.4 1.9 3.0 3.4 2.9 2.6 2.9 4.64.04.7 2.9 2.5 3.8 3.3 2.8

2.4 2.1 1.3 1.2 2.2 1.9 1.4 1.8 1.1 1.0 1.2 1.0 1.0 0.6 1.1 1.1 0.9 3.7 3.84.3 4.6 3.2 4.0 3.0 3.9 2.1 3.1 3.7 3.44.7 2.7 2.4 2.7 3.7 3.1 3.4 3.9 2.9 4.3 2.8 2.8 3.04.2 2.8 3.5 3.7 4.04.7 2.5 3.2 2.7 3.2 1.8 4.0 5.3 4.9 6.0 1.7 2.8 2.9 0.3 5.5 5.2 5.6 9.0 2.5 4.04.6 6.0 3.5 5.0 5.7 5.2 8.8 3.1 3.5 4.3 5.9 3.3 4.0 3.5 3.9 5.2 2.3 3.7 3.0 3.6 2.6 4.84.1 4.4 6.8 2.6 3.2 3.8 3.8 3.0 3.9 5.2 3.9 5.6 2.5 3.7 3.3 3.6 3.2 3.6 3.7 4.0 5.6 4.2 4.04.7 7.9 2.9 3.5 4.2 3.8 3.6 4.5 5.2 5.8 7.3 3.0 3.3 4.2 5.2 3.2

1.2 0.9 0.8 0.7 0.8 1.0 0.9 0.8 0.6 2.4 2.2 4.1 3.4 1.9 2.6 2.5 2.3 2.0 1.0 0.6 1.6 1.9 1.1 0.9 1.7 2.3 0.9 0.6 0.5 1.1 1.2 0.8 0.5 1.3 1.3 0.5 2.6 3.4 3.9 4.7 2.7 3.1 3.4 3.1 2.8 2.8 2.6 3.04.3 2.4 2.7 2.4 2.8 2.4 2.7 3.64.3 5.1 3.3 3.3 3.4 2.2 3.10.9 0.7 1.5 1.6 1.0 0.8 1.6 1.6 0.8

2.0 2.6 2.3 3.4 2.1 2.2 2.3 2.5 2.4

2.1 1.9 2.3 1.4 2.0 2.0 2.1 1.7 2.4 2.6 3.3 3.8 2.3 2.9 2.5 3.2 2.6 2.8 3.2 2.9 4.7 2.3 2.7 2.2 3.2 2.4 2.8 3.1 5.0 5.9 2.6 2.4 3.4 3.0 2.4 3.2 3.64.84.5 2.3 2.9 3.1 3.0 2.4 3.4 3.9 4.64.4 2.6 3.0 3.2 2.9 2.5 4.0 2.7 4.7 4.0 3.0 3.0 2.7 3.4 2.5 3.6 3.64.7 4.9 2.3 3.0 3.4 3.3 2.3 3.4 3.84.7 4.0 2.2 3.3 3.2 3.0 2.4 3.3 3.5 4.3 5.6 2.6 2.8 3.0 3.5 2.6 1.8 2.0 2.1 1.8 1.4 1.8 1.7 1.1 1.6 4.3 4.9 5.1 8.1 2.9 3.64.1 5.1 3.4 5.0 5.4 6.8 8.5 5.0 5.2 3.8 5.5 4.0 5.3 4.9 2.2 6.2 3.5 3.3 4.1 5.0 2.7 2.6 3.84.0 5.6 2.9 3.9 3.04.0 2.7 3.2 3.5 4.6 7.0 2.04.4 3.64.2 2.8 3.5 3.5 3.7 6.5 3.0 3.7 3.2 3.8 2.4 4.1 4.2 5.0 7.4 2.6 3.64.44.8 3.4

4.3 4.5 6.3 3.0 3.4 3.6 3.7 3.2 3.44.1 5.2 5.1 3.1 4.04.2 4.3 3.2 4.2 4.3 6.8 7.9 4.2 6.44.7 5.0 3.6 2.8 3.5 4.3 2.8 2.0 2.4 3.2 2.4 2.1 2.5 4.9 3.8 3.0 2.9 2.6 3.9 3.2 2.6 0.5 0.6 1.4 1.1 0.7 0.5 0.9 0.9 0.5 0.6 1.6 0.9 0.6 0.6 1.1 0.9 0.6 0.5 1.4 1.3 0.7 0.5 1.1 1.1 3.3 3.44.5 5.9 2.4 3.3 3.9 3.8 3.2 4.3 3.2 2.44.9 5.9 2.3 3.9 3.4 3.5 3.2 2.8 4.3 3.7 4.0 3.1 2.9 3.7 4.5 5.9 2.0 3.84.2 3.9 3.1 3.9 3.4 3.1 2.8 3.2 3.6 6.9 5.8 2.9 3.5 4.1 3.5 3.2

3.1 4.5 5.1 2.5 3.0 2.8 3.3 2.6 4.7 3.3

2.6 3.5 3.44.8 5.9 2.3 3.9 4.3 4.5 3.1

2.1 3.0 2.9 3.0 2.3 2.8 2.3 2.8 2.6 4.03.5 3.2 4.5 4.4 2.3 3.2 3.3 2.4 2.5

3.3 3.5 4.7 5.4 2.3 3.3 2.7 3.4 2.7

3.64.5 5.0 2.4 2.8 3.5 3.0 2.3 2.6 2.3 2.4 3.0 1.9 1.9 1.9 1.8 1.7 3.7 5.3 4.3 5.7 3.6 2.84.04.6 2.4 3.7 5.5 4.7 5.3 3.1 3.1 4.1 3.6 2.8 2.9 3.5 5.6 5.2 2.5 3.6 3.9 3.0 2.9 3.44.5 4.1 4.5 3.1 3.0 3.3 3.6 2.6 3.9 4.84.4 6.0 3.0 2.64.1 4.9 2.9 3.5 4.3 4.7 6.4 3.2 4.7 4.5 4.0 2.9 2.9 4.1 3.2 2.4 1.2 1.1 2.0 2.2 1.6 1.3 1.8 2.4 1.5 3.3 3.2 4.04.0 2.6 3.04.1 3.2 2.5 0.9 1.1 1.3 1.3 1.3 1.1 1.2 1.40.9 1.1 1.6 1.3 1.4 1.3 0.9 1.2 1.40.9 0.8 1.1 1.4 1.7 1.0 1.0 1.3 1.40.8 1.7 2.1 1.6 1.7 2.1 2.2 1.8 2.4 1.8 3.7 3.9 4.5 4.8 3.0 2.9 3.0 3.4 2.9 0.8 0.9 1.1 1.5 1.3 1.0 1.3 1.7 0.8 1.0 1.0 1.3 2.0 1.1 0.8 1.3 2.0 0.6 0.8 0.8 1.5 2.1 1.0 0.8 1.0 0.8 0.8 1.2 1.1 0.8 1.1 1.0 0.9 4.2 4.6 5.3 7.0 2.8 3.64.6 3.6 2.8 6.7 3.04.04.4 5.3 3.1 5.2 4.5 5.8 9.8 2.4 2.6 2.9 2.3 1.6 2.2 2.4 3.0 3.0 2.3 2.8 2.6 2.6 2.1 2.6 2.6 3.1 4.0 2.7 3.4 2.7 3.2 1.8 2.2 2.3 2.8 2.0 2.6 2.8 2.2 1.7 2.0 3.1 2.6 3.7 4.2 2.4 3.3 2.1 3.1 1.8201020102010201020112011201120112012

1 2 3 4 1 2 3 4 1 0.7 0.0 0.0 0.1 0.40.0 0.0 0.0 0.1 0.7 0.0 0.0 0.1 0.40.0 0.0 0.0 0.1 1.5 0.0 0.0 0.6 0.7 0.0 0.0 0.2 0.3 0.3 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 1.1 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.0 0.0 0.0 0.1 0.0 1.3 0.0 0.0 0.5 0.8 0.0 0.0 0.3 0.4 0.0 0.0 0.0 1.2 0.9 0.0 0.0 2.8 0.1

5.6 0.0 0.0 6.1 4.0 0.0 0.010.9 7.3 0.40.0 0.0 0.40.1 0.0 0.0 0.6 0.4 1.0 1.40.4 1.0 2.0 0.3 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 2.8 0.0 0.0 1.9 2.6 0.0 0.0 3.2 1.2 2.40.0 0.0 2.4 1.9 0.0 0.0 6.2 1.0 0.6 0.2 0.1 0.40.1 0.0 0.0 1.6 0.5 1.1 0.6 0.0 0.1 0.0 0.0 0.0 1.6 0.0 1.3 0.0 0.0 0.7 1.3 0.0 0.0 1.9 1.7 4.1 0.0 0.04.7 9.7 0.0 0.013.5 4.2 3.2 0.0 0.0 6.0 5.1 0.0 0.014.511.4 0.6 0.1 0.0 0.40.2 0.3 0.5 0.2 0.3 2.8 0.5 0.0 0.5 1.40.0 0.0 1.6 2.3 3.40.40.0 1.4 1.0 0.0 0.0 1.9 3.8

1.6 0.2 0.0 1.4 1.7 0.0 0.0 0.5 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.7 0.0 0.0 0.3 0.0 0.0 0.0 0.2 0.1 0.8 0.0 0.0 0.3 0.0 0.0 0.0 0.0 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.8 0.6 0.0 1.2 1.7 0.0 0.0 1.8 0.9 0.8 0.0 0.0 0.6 1.3 0.1 0.0 0.3 1.1 3.3 0.1 0.0 1.5 2.0 0.2 0.5 0.4 1.9 6.2 0.3 0.0 2.5 3.7 0.1 0.0 0.6 2.4 3.6 0.0 0.0 1.2 4.1 0.0 0.0 1.6 1.5 6.1 0.0 0.0 0.1 4.3 0.0 0.0 0.4 1.4 2.2 0.0 0.0 1.1 1.2 0.0 0.0 0.3 0.3 1.8 0.0 0.0 0.5 0.5 0.0 0.0 0.1 0.0 Nitrates SANDWICHed*3.3 0.0 0.0 1.9 2.1 0.0 0.0 0.9 0.7

4.6 0.0 0.0 0.0 0.0 0.0 0.3 0.0 0.0 0.1 0.0 2.3 0.2 0.0 1.9 2.3 0.1 0.0 0.6 1.3 1.40.2 0.0 1.0 1.40.0 0.0 0.2 0.7 0.40.0 0.0 0.8 1.40.0 0.0 0.6 0.7 4.1 0.0 0.04.44.5 0.6 0.0 1.3 2.4 4.5 0.0 0.0 3.7 4.6 0.7 0.0 1.4 3.2 0.1 0.0 0.0 1.9 1.9 0.0 0.0 1.2 2.1 5.6 0.0 0.0 3.1 3.7 0.3 0.0 1.2 3.0 0.9 0.0 0.0 2.6 3.0 0.40.0 1.0 2.6 4.5 0.0 0.0 2.5 4.9 0.6 0.0 1.4 2.4 4.0 0.0 0.04.1 4.0 0.8 0.0 1.4 3.1 3.2 0.0 0.0 3.1 4.3 0.40.0 1.1 3.3 5.0 0.3 0.0 2.0 2.7 5.8 0.0 0.0 2.1 5.6 0.2 0.0 1.8 3.1 8.7 0.0 0.0 1.6

0.0 0.0 0.1 0.3 0.0 0.0 0.1 0.0 0.9 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.9 0.0 0.0 0.40.1 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 1.6 0.0 0.0 1.0 2.5 0.0 0.0 2.4 1.0 9.40.0 0.04.3 6.0 1.40.0 0.4 3.2 5.7 0.2 0.0 2.9 4.9 0.8 0.0 1.5 1.7 6.3 0.0 0.04.2 6.6 0.1 0.0 1.5 2.7 6.9 0.0 0.04.2 5.7 0.7 0.0 1.9 2.8 4.2 0.0 0.0 2.4 3.8 0.0 0.0 0.0 1.0 4.40.0 0.0 1.8 1.8 0.0 0.0 0.8 0.6 5.6 0.0 0.0 3.1 4.1 0.0 0.0 1.5 1.1 5.7 0.0 0.0 6.1 4.0 0.5 0.0 1.7 3.6 7.2 0.0 0.04.0 3.3 0.0 0.0 1.3 1.9 6.5 0.0 0.04.8 5.8 0.7 0.0 2.7 3.1 7.40.0 0.04.4 5.0 0.7 0.0 7.0 0.0 0.0 3.44.2 0.3 0.0 1.7 2.2 4.3 0.0 0.0 2.7 2.7 0.0 0.0 1.0 0.9 0.40.0 0.0 0.2 0.4 1.1 8.9 0.0 0.0 2.7 5.1 0.0 0.0 1.9 4.5 0.1 0.3 0.0 0.0 0.1 0.0 1.3 0.0 0.0 0.5 1.0 0.0 0.0 0.8 0.3 0.9 0.0 0.0 0.8 1.6 0.40.0 0.5 1.4 0.7 0.0 0.0 0.6 0.2 0.0 0.0 0.3 0.9 2.0 0.0 0.0 0.8 1.7 0.3 0.0 0.8 1.40.5 0.0 0.0 0.1 0.3 0.0 0.0 0.7 0.0

1.6 0.0 0.0 1.1 2.7 0.0 0.0 0.6 1.1 1.9 0.1 0.40.0 0.0 0.0 0.1 2.40.0 0.0 1.0 2.8 0.0 0.0 1.1 1.4 0.7 0.0 0.0 0.8 1.0 0.0 0.0 0.6 0.6 0.40.0 0.0 0.40.1 0.0 0.0 0.1 0.1 0.9 0.0 0.0 1.3 0.5 0.0 0.0 0.0 0.3 0.9 0.0 0.0 0.9 0.40.0 0.0 0.0 0.3 0.9 0.0 0.0 1.4 1.3 0.0 0.0 0.0 0.2 0.7 0.0 0.0 0.9 0.8 0.0 0.0 0.0 0.1 0.8 0.0 0.0 0.6 0.40.0 0.0 0.0 0.1 0.6 0.0 0.0 0.40.6 0.0 0.0 0.0 0.2 4.8 0.0 0.0 1.5 4.1 0.2 0.0 0.9 1.7 5.6 0.0 0.0 1.9 3.6 0.3 0.0 1.0 1.3 2.3 0.0 0.0 1.7 2.1 0.0 0.0 1.1 1.8 2.2 0.0 0.0 1.4 1.40.0 0.0 0.2 0.3 5.0 0.0 0.0 1.2 3.9 0.2 0.0 1.1 2.5 5.40.0 0.0 3.64.7 0.3 0.0 1.44.3 5.0 0.0 0.0 2.9 3.1 0.3 0.0 1.1 2.2 7.7 0.0 0.0 2.8 2.1 1.0 0.0 1.4 1.5 4.6 0.40.0 1.5 2.3 7.0 0.0 0.0 3.2 3.5 0.3 0.0 1.1 2.3 4.6 0.3 0.0 2.44.7 0.0 0.0 1.7 4.4 1.9 0.0 0.0 1.2 2.6 0.0 0.0 1.5 0.5 2.3 0.0 0.0 1.4 3.0 0.0 0.0 1.0 1.0 0.2 0.0 0.0 0.1 0.7 0.0 0.0 0.5 0.2 0.0 0.0 0.0 0.0 0.5 0.0 0.0 0.1 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 3.3 0.5 0.0 2.5 2.5 0.6 0.0 1.1 3.8 2.6 0.0 0.0 1.4 1.6 0.0 0.0 0.9 1.2 0.5 0.0 0.5 1.0

3.2 4.1 0.6 0.0 2.4 3.0 0.7 0.0 1.0 3.6 0.0 3.1 0.40.0 0.8 2.3 0.2 0.0 0.7 2.0 0.7 0.0 0.0 0.4 1.2

3.3 0.40.0 2.2 2.40.9 0.0 1.2 3.6 0.8 0.0 0.0

0.0 0.4 1.2 0.0 0.0 0.1 0.6 0.2 0.0 0.0 0.10.7 0.0 0.0 0.40.2 0.0 0.0 0.0 0.2

0.1 0.0 0.0 1.5 0.1 0.0 0.0 0.0 0.4 0.6 0.0 0.0 0.0 0.0 7.40.0 0.0 2.9 4.3 1.40.0 1.6 0.9 3.5 0.0 0.0 0.8 1.0 0.0 0.0 0.8 0.3 0.6 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.1 0.2 0.0 0.0 0.3 0.2 0.0 0.0 0.0 0.3 0.40.0 0.0 0.3 0.7 0.0 0.0 0.0 0.0 3.7 0.0 0.0 0.9 1.2 0.0 0.0 0.5 0.2 0.1 0.0 0.0 0.40.2 0.0 0.0 1.3 0.0 0.0 0.5 0.40.0 0.0 0.6 0.4 0.5 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.1 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 5.6 0.0 0.0 2.2 5.0 0.0 0.04.2 3.5 8.9 0.0 0.0 3.6 5.8 0.0 0.04.2 2.8 7.5 0.0 0.0 2.6 7.5 0.0 0.0 3.0 3.6 1.9 0.0 0.0 0.9 1.7 0.0 0.0 0.6 1.1 0.9 0.0 0.0 0.6 0.8 0.0 0.0 0.1 0.4 0.2 0.0 0.0 0.1 0.6 0.0 0.0 0.5 0.1 0.0 0.0 0.0 0.0 0.6 0.0 0.0 0.3 0.1 0.0 0.0 0.0 0.1 0.3 0.0 0.0 0.3 0.4 0.6 2.1 1.7 0.0 0.0 3.1 1.4 2.6 0.0 0.0 0.9 0.9 0.0 0.0 0.3 0.4 0.0 0.40.6 4.1 0.0 0.0 1.4 1.7 0.1 0.0 2.4 3.2 4.5 0.0 0.0 2.64.1 0.40.0 1.3 2.8 3.7 0.2 0.0 3.2 4.1 1.40.0 2.3 3.4 0.6 0.0 0.0 3.0 3.2 0.6 0.0 2.0 3.2 4.40.0 0.04.4 3.7 1.8 0.0 2.1 3.6201220122012 201020102010201020112011

2 3 4 1 2 3 4 1 2 0.0 0.0 0.2 0.7 1.5 1.7 1.2 1.4 1.1 0.0 0.0 0.2 1.0 2.0 2.5 1.9 1.5 1.9 0.0 0.0 0.2 0.4 1.1 1.1 0.40.3 0.9 0.0 0.0 0.0 0.5 1.6 1.7 0.6 0.3 0.7 0.0 0.0 0.0 0.3 0.7 1.40.5 0.3 0.7 0.0 0.0 0.0 0.6 1.40.9 1.0 1.6 2.2 0.0 0.0 0.4 0.5 1.0 1.6 0.7 0.40.9 0.0 0.5 0.5 1.2 0.40.3 0.5 0.0 0.0 0.9 0.0 0.0 1.9 0.5 0.6 1.3 0.5 0.40.6 0.0 0.0 0.3 1.6 2.2 2.2 2.1 2.6 2.4 1.2 0.9 0.8 0.9 1.0 1.2 0.0 0.0 0.6 0.7 1.0 1.40.3 0.5 0.5 0.0 0.0 0.4 0.3 0.9 0.9 0.40.40.4 0.0 0.0 0.8 0.40.8 0.9 0.6 0.40.5 0.2 0.0 0.6 0.6 0.5 0.5 0.5 0.6 0.7 0.2 0.0 0.0 0.7 0.7 0.7 0.6 0.5 0.5 0.0 0.1 0.1 0.40.40.40.5 0.5 0.3 0.0 0.04.4 0.6 0.8 1.4 1.1 0.40.5 0.0 0.0 3.0 0.5 0.8 1.8 0.7 0.5 0.8 0.0 0.1 0.6 0.5 0.6 0.6 0.40.40.7 0.0 0.0 0.7 1.2 1.2 1.7 1.3 1.2 2.3 0.3 0.0 1.0 1.1 1.3 1.0 1.0 1.6

0.8 0.0 0.0 1.1 0.5 0.8 0.6 0.3 0.2 0.4 0.0 0.0 0.0 0.4 1.6 1.9 0.5 0.5 0.8 0.0 0.0 0.0 0.3 1.3 1.5 0.3 0.40.6 0.0 0.0 0.0 0.3 1.0 1.6 0.40.40.7 0.0 0.0 0.0 0.7 2.0 2.2 0.40.8 1.8 0.0 0.0 0.0 0.3 1.1 0.7 0.40.2 0.5 0.0 0.0 0.1 0.4 1.6 1.0 0.8 0.40.7 0.0 0.0 0.0 0.7 1.3 1.1 0.40.3 0.7 0.0 0.0 1.2 1.2 1.2 2.3 2.0 1.1 1.8 0.0 0.0 1.1 0.3 0.6 0.40.5 0.40.5 0.0 0.0 1.1 0.2 0.7 0.6 0.2 0.2 0.5 0.0 0.0 1.3 0.5 0.7 0.6 0.5 0.40.4 0.0 0.0 2.2 0.5 1.1 1.4 1.0 0.7 1.3 0.0 0.0 1.8 0.7 1.0 0.8 1.1 0.40.8 0.0 0.0 0.3 0.40.5 0.7 0.5 0.40.5 0.0 0.0 0.1 0.3 0.40.3 0.3 0.2 0.3 Crustal SANDWICHed*0.0 0.0 1.0 0.3 0.6 0.7 0.6 0.40.5 0.40.6 0.0 0.0 0.0 0.5 1.4 2.3 1.0 0.40.8 0.0 0.0 2.0 0.40.7 0.5 0.40.3 0.5 0.0 0.0 0.8 0.40.8 0.8 0.5 0.3 0.4 0.0 0.0 0.6 0.2 0.40.3 0.3 0.3 0.3 0.1 0.0 3.5 0.3 0.9 0.40.8 0.40.4 0.0 0.0 3.4 0.40.7 0.3 0.3 0.2 0.4 0.0 0.0 1.0 0.1 0.5 0.1 0.2 0.1 0.2 0.0 0.0 3.2 0.40.7 0.40.3 0.2 0.4 0.1 0.0 2.1 0.3 0.6 0.40.40.2 0.4 0.1 0.0 2.9 0.40.7 0.5 0.40.40.7 0.0 0.0 2.1 0.7 1.6 1.1 1.1 0.8 1.1 0.1 0.0 3.1 0.9 1.4 1.2 2.2 0.9 0.9 0.0 0.0 2.7 0.2 0.3 0.1 0.0 3.3 0.40.8 0.5 1.0 0.5 0.7 0.40.7 0.5 0.7 0.0 0.8 2.3 0.6 0.3 0.7 0.0 0.0 0.2 0.4 1.2 2.2 1.8 1.1 1.4 0.0 0.0 0.0 0.3 1.0 1.1 0.6 0.3 0.6 0.0 0.0 0.1 0.5 1.1 0.5 0.40.3 0.5 0.0 0.0 0.0 0.40.5 0.0 0.0 0.6 0.40.8 2.1 0.9 0.5 0.6 0.1 0.04.0 0.5 1.1 0.7 0.9 0.4 1.2 0.1 0.0 3.6 0.40.8 0.6 0.5 0.3 0.6 0.1 0.0 3.6 0.2 0.6 0.6 0.5 0.2 0.5 0.0 0.0 2.8 0.40.6 0.3 1.2 0.40.6 0.0 0.0 1.4 2.5 2.84.0 2.9 3.9 0.0 0.0 1.2 0.40.9 1.0 1.2 0.6 1.0 0.0 0.0 1.9 0.3 0.6 0.5 0.5 0.3 0.6 0.0 0.0 3.5 0.3 0.5 0.3 0.5 0.3 0.4 0.0 0.0 3.1 0.2 0.5 0.3 0.40.3 0.5 0.1 0.0 3.6 0.7 1.4 1.0 0.9 1.0 0.9 0.5 1.1 0.6 0.6 0.5 1.2 0.1 0.0 3.2 0.40.7 0.5 0.5 0.3 0.6 0.0 0.0 1.4 0.40.7 0.6 0.6 0.40.8 0.0 0.0 0.4 0.2 0.2

0.7 0.4 0.0 0.0 2.9 0.9 2.0 1.1 0.9 0.40.8 0.0 0.0 0.1 1.0 0.9 1.0 0.0 0.0 0.3 1.0 0.9 0.9 0.6 1.1 0.6 0.1 0.0 1.9 0.3 0.40.5 0.40.3 0.4 0.0 0.0 1.2 0.2 0.5 0.2 0.2 0.2 0.2 0.0 0.0 1.9 0.6 1.1 1.1 0.6 0.40.70.0 0.0 0.2 0.5 1.3 0.5 0.6 0.9 1.9

0.0 0.0 1.0 0.40.8 0.6 0.5 0.5 0.6 0.6 0.9 0.0 0.0 0.1 0.1 0.3 0.0 0.0 1.9 0.3 0.6 0.40.3 0.3 0.3 0.0 0.0 0.8 0.2 0.5 0.2 0.2 0.1 0.2 0.0 0.0 0.1 0.2 1.0 0.6 0.2 0.2 0.5 0.0 0.0 0.1 0.3 0.9 0.6 0.3 0.2 0.5 0.0 0.0 0.2 0.3 0.7 0.7 0.40.3 0.5 0.0 0.0 0.2 0.2 0.8 0.8 0.3 0.2 0.4 0.0 0.0 0.0 0.40.7 0.8 0.3 0.3 0.5 0.0 0.0 0.0 0.2 0.8 0.7 0.3 0.2 0.5 0.0 0.0 0.0 0.3 0.9 0.6 0.3 0.3 0.5 0.0 0.0 1.8 0.4 1.9 1.8 2.7 0.3 0.7 0.0 0.0 1.8 0.3 0.6 0.5 0.40.3 0.5 0.0 0.0 1.0 0.40.5 0.6 0.5 0.3 0.4 0.0 0.0 0.1 0.7 0.9 0.7 0.9 0.5 0.2 0.0 0.0 2.0 0.4 1.3 0.5 0.5 0.3 0.5 0.1 0.0 2.1 0.3 0.8 0.6 0.7 0.3 0.5 0.0 0.0 1.3 1.2 1.6 0.8 1.40.8 0.9 0.0 0.0 3.2 0.40.6 0.40.6 0.2 0.6 0.0 0.0 2.4 0.2 0.4 0.0 0.0 2.3 0.6 2.2 1.5 1.3 0.6 0.9 0.0 0.0 1.7 0.3 0.7 0.5 0.3 0.2 0.5 0.0 0.0 1.4 0.40.7 1.40.6 0.6 1.0 0.0 0.0 1.1 0.6 1.0 1.40.7 0.5 0.8 0.0 0.0 0.6 0.6 0.40.3 0.6 0.4 0.0 0.0 0.7 0.8 1.40.8 0.7 0.7 0.0 0.0 0.3 0.40.3 0.2 0.2 0.2 0.5 0.0 2.4 0.2 0.5 0.3 0.3 0.2 0.3 0.7 1.4 1.1 1.3 0.0 0.0 1.8 0.2 0.40.2 0.2 0.1 0.3

2.3 0.0 0.0 2.8 0.0 0.0 3.0 0.2 0.5 0.3 0.2 0.2 0.4 0.2 0.0 1.6 0.1 0.0 1.9 0.3 0.9 0.6 0.40.3 0.5 0.0 0.0 1.2 0.3 0.4

0.0 0.8

0.3 0.0 0.0 2.5 0.5 0.7 0.7 0.40.40.6 0.3 0.9 0.4 0.0 0.0 1.0 0.1 0.2 0.3 0.3 0.3 0.6 1.1 0.40.0 0.0 0.0 0.2 0.6 0.9 0.2 0.1 0.5

0.0 0.0 0.0 0.2 1.1 0.8 0.3 0.40.7 0.0 0.0 0.0 0.3 0.7 0.0 0.0 2.1 0.2 0.8 0.6 1.1 0.2 0.5 0.0 0.0 0.5 0.3 0.7 1.1 0.5 0.3 0.6 0.0 0.0 0.0 0.4 1.2 0.9 0.40.5 0.6 0.0 0.0 0.2 0.3 0.6 0.6 0.40.2 0.8 0.0 0.0 0.0 0.4 1.3 1.9 0.8 0.4 1.0 0.0 0.0 0.8 0.3 0.6 1.0 0.3 0.2 0.6 0.3 0.8 0.6 0.2 0.2 0.4 0.0 0.0 0.3 0.5 1.2 2.3 0.7 0.6 1.1 0.0 0.0 0.0 1.5 3.4 1.6 3.8 3.3 6.3 0.0 0.0 0.1 0.3 0.7 2.0 0.40.3 1.0 0.0 0.0 1.3 0.5 1.0 1.0 0.5 0.6 1.0 0.0 0.0 1.1 1.8 1.5 1.2 0.6 0.8 1.1 0.0 0.0 0.4 0.6 1.0 2.1 0.8 0.7 1.4 0.0 0.0 0.6 0.3 0.6 0.3 0.2 0.3 0.8 0.0 0.0 0.1 0.3 0.7 0.6 0.3 0.2 0.4 0.0 0.0 0.1 0.3 0.40.40.2 0.40.2 0.0 0.0 0.0 0.6 0.3 0.2 0.3 0.3 0.2 0.40.3 0.3 0.3 0.3 0.2 0.0 0.0 1.1 0.7 0.5 0.5 0.3 0.0 0.0 0.2 0.6 0.7 0.7 0.5 0.3 0.6 0.0 0.0 0.7 1.2 1.3 1.1 1.1 0.7 0.8 0.0 0.0 1.8 0.1 0.0 3.0 0.1 0.40.6 0.3 0.2 0.2 0.1 0.0 2.1 0.3 0.7 0.5 0.5 0.2 0.4 0.0 0.0 2.2 0.3 0.6 0.2 0.3 0.2 0.3 0.0 0.0 2.1 0.40.9 0.7 0.8 0.5 0.6201120112012201220122012 201020102010

3 4 1 2 3 4 1 2 3 0.9 0.9 0.9 0.9 1.3 0.8 3.5 8.2 8.3 1.0 1.1 1.8 1.0 1.8 1.1 3.7 6.2 6.3 0.5 0.40.40.7 0.8 0.4 3.5 5.3 6.1 0.7 0.5 0.7 0.6 1.0 0.5 3.9 5.84.5 0.5 0.3 0.40.6 0.9 0.4 6.5 8.5 5.2 1.7 1.1 1.8 2.2 1.1 1.8 2.7 1.5 1.6 1.0 0.6 0.7 1.0 2.1 0.7 4.3 6.4 7.3 1.3 0.5 0.4 1.4 5.7 1.6 3.0 0.7 1.40.7 1.3 0.8 0.6 0.9 1.4 1.0 9.1 3.1 5.3 2.7 2.9 3.0 3.3 3.4 6.9 6.8 7.7 9.6 4.64.6 5.0 0.9 0.5 0.5 1.1 0.8 0.3 10.4 2.9 1.4 0.7 0.5 0.40.7 0.6 0.4 6.2 2.3 3.7 0.6 0.7 0.5 0.8 0.8 0.6 4.6 1.1 4.0 0.5 1.0 0.6 0.6 0.5 0.5 7.3 5.7 5.2 0.6 0.7 0.8 0.9 0.6 0.5 6.6 5.44.7 0.40.7 0.5 0.5 0.40.5 5.4 5.1 5.4 1.2 0.9 0.5 0.9 1.0 0.3 4.8 2.2 6.7 2.0 0.9 1.0 1.2 1.9 0.8 5.7 4.1 5.7 0.7 1.2 1.7 1.7 0.7 0.4 4.4 5.9 6.3 1.8 1.6 1.3 2.2 1.0 2.4 3.5 3.0 3.4 1.6 0.9 0.9 1.3 1.2 3.1 3.0 3.4 1.1 0.40.5 0.40.5 0.6 0.4 5.2 3.6 5.0 1.8 0.3 0.4 1.6 3.8 0.3 3.0 2.2 1.2 1.1 0.3 0.5 1.0 2.3 0.5 3.4 3.2 2.1 0.6 0.3 0.40.4 1.40.3 4.5 4.9 2.6 0.9 0.40.8 1.5 1.5 0.9 6.0 9.7 8.2 0.5 0.3 0.5 0.5 0.8 0.4 3.6 7.4 7.4 0.6 0.40.5 0.7 0.7 0.5 4.2 7.5 8.2 0.5 0.3 0.3 0.6 0.9 0.4 5.6 9.7 5.8 2.1 2.1 0.7 2.7 1.6 1.3 1.8 2.2 3.1 0.40.5 0.40.5 0.5 0.4 3.1 3.84.2 0.3 0.2 0.2 0.5 0.40.2 2.1 3.9 5.8 0.3 0.40.40.5 0.5 0.5 1.8 3.1 4.7 1.9 0.7 0.7 1.4 1.4 1.5 2.5 2.5 3.4 1.0 0.8 0.7 1.2 1.5 1.0 3.0 3.6 3.6 0.40.40.3 0.7 0.7 0.5 2.8 3.44.4 0.2 0.3 0.2 0.40.6 0.2 1.3 3.6 6.0 Crustal SANDWICHed*0.7 0.7 0.6 0.6 0.7 0.4 3.0 2.64.3 2.2 2.2 1.0 0.6 0.6 0.9 2.6 0.9 3.04.2 3.5 0.40.40.40.5 0.5 0.3 3.1 4.4 5.9 0.40.5 0.3 0.5 0.40.4 1.6 3.7 4.8 0.2 0.2 0.2 0.3 0.2 0.2 2.9 4.64.4 0.7 0.40.40.6 0.7 0.4 2.7 3.04.1 0.3 0.2 0.2 0.5 0.3 0.3 1.6 3.6 3.6 0.2 0.2 0.2 0.40.3 0.1 1.5 3.2 3.6 0.8 0.40.40.7 0.6 0.4 1.2 2.9 4.3 0.3 0.3 0.3 0.6 0.40.3 1.84.04.4 0.6 0.5 0.40.8 0.6 0.5 2.4 2.44.5 1.0 0.8 1.3 2.0 1.0 0.8 2.1 2.6 3.4 1.1 1.1 1.6 2.5 2.4 1.6 1.9 3.7 5.7 0.5 0.5 0.3 0.6 0.6 0.4 0.6 0.5 0.3 0.7 0.8 0.5 3.0 3.44.3 2.4 3.2 4.3 0.8 0.3 0.3 0.5 6.7 5.4 0.8 0.5 0.3 0.6 1.40.4 4.8 5.6 5.6 0.7 0.3 0.40.6 1.1 0.3 5.7 7.3 6.3 0.5 0.40.40.6 0.6 0.4 2.6 3.8 5.9 0.5 0.40.9 0.7 0.2 0.2 1.6 0.5 0.40.8 1.6 0.8 2.8 0.9 1.5 1.8 0.8 0.5 1.1 1.0 0.6 3.44.5 5.7 0.6 0.5 0.2 0.7 0.9 0.4 4.04.6 5.5 0.40.40.3 0.7 0.9 0.4 1.6 2.4 5.0 0.7 0.40.3 0.6 0.5 0.4 2.8 3.8 5.4 2.0 5.0 2.2 3.7 0.0 4.1 5.8 5.5 0.8 1.1 1.1 1.2 1.2 0.7 4.1 4.1 5.7 0.5 0.3 0.3 0.7 0.8 0.3 3.7 3.4 5.0 0.40.40.40.6 0.40.3 3.6 3.6 6.1 0.3 0.3 0.2 0.5 0.3 0.3 3.3 3.7 4.1 0.9 0.6 1.0 1.6 1.0 1.0 4.0 3.5 5.5 0.7 3.1 3.4 5.1 0.5 0.40.40.7 0.9 0.4 3.1 4.4 5.0 0.6 0.3 0.3 0.6 0.9 0.4 2.64.6 5.7 0.5 0.1 0.3 0.40.5 0.1 0.6 10.3 1.1 1.2 1.3 1.7 2.5 0.7 2.1 2.5 4.0 1.4 1.4 1.8 2.3 1.7 1.6 0.7 0.9 0.7 1.3 0.7 0.6 4.7 1.7 2.6 0.5 0.5 0.40.6 0.7 0.4 2.1 3.4 5.0 0.3 0.2 0.2 0.40.3 0.2 1.5 3.2 3.7 0.8 0.7 0.6 0.8 0.6 0.6 3.2 3.3 3.81.1 0.7 1.0 2.0 1.0 1.1 2.8 2.3 2.0

0.40.8 0.5 0.6 0.7 0.5 2.7 3.9 3.3 2.2 3.9 0.2 0.1 0.1 0.3 0.2 0.1 0.40.40.3 0.5 0.5 0.3 2.0 3.1 4.4 0.2 0.2 0.2 0.3 0.3 0.2 1.8 3.3 4.1 0.40.2 0.3 0.7 0.7 0.3 3.1 5.0 6.4 0.3 0.3 0.3 0.5 0.7 0.3 5.04.7 5.8 0.40.3 0.3 0.5 0.7 0.5 5.4 5.4 6.3 0.2 0.2 0.2 0.40.7 0.3 2.64.6 5.4 0.40.3 0.3 0.5 0.8 0.4 2.8 5.4 6.1 0.3 0.2 0.3 0.40.6 0.2 4.4 5.5 5.8 0.5 0.3 0.40.5 0.7 0.4 2.6 5.7 6.0 2.4 1.8 0.7 2.3 3.8 1.0 2.4 3.6 2.9 0.5 0.40.40.7 0.40.6 3.9 3.5 6.2 0.40.3 0.5 0.8 0.6 0.4 2.1 2.9 4.6 0.8 1.0 1.4 1.2 0.8 0.8 4.6 3.8 6.1 0.40.7 0.8 1.0 1.0 1.1 2.7 2.64.5 0.5 0.8 0.40.6 0.6 0.3 4.5 4.0 5.6 1.0 0.9 0.7 1.8 1.5 1.1 2.7 3.5 5.2 0.5 0.40.5 0.7 0.9 0.8 3.1 3.7 6.2 0.3 0.3 0.2 0.3 0.7 0.3 0.9 0.9 1.2 1.1 1.1 0.6 2.7 3.9 5.4 0.3 0.3 0.5 1.0 0.5 0.3 4.4 5.04.9 1.40.40.7 1.2 1.9 0.8 3.4 3.1 5.4 1.1 0.5 0.7 0.9 2.2 1.2 4.9 5.3 5.1 0.8 0.5 0.5 0.5 1.3 12.7 2.7 1.9 1.3 0.40.6 1.1 1.6 6.3 2.2 3.6 0.3 0.1 0.1 0.40.5 10.9 2.3 2.7 0.3 0.3 0.3 0.40.40.3 2.9 3.9 4.0 2.9 3.7 4.0 0.2 0.2 0.3 0.40.3 0.3 2.7 3.84.3 0.3 0.40.5 0.5 0.4 0.3 0.3 0.40.5 0.40.4 3.84.44.8

0.40.5 0.9 0.5 0.40.40.40.6 0.5 0.4 3.1 4.7 3.9 0.3 0.40.3 0.5 0.40.4 0.5 0.4

0.5 0.7 0.6 0.6 0.8 0.6 0.5 3.04.7 4.2 3.1 4.1 5.6 0.3 0.3 0.3 0.5 0.3 0.2 4.6 3.9 3.9 2.90.5 0.2 0.3 0.6 1.1 0.2 3.7 5.5 5.6

0.40.2 0.2 0.5 0.8 0.3 3.9 6.1 6.5 0.6 0.3 0.40.6 0.9 0.4 1.1 0.6 0.5 1.0 1.0 0.5 4.2 3.4 3.9 0.6 0.40.40.6 0.8 0.4 3.8 3.7 5.3 0.5 0.40.5 1.2 1.2 0.9 3.7 5.2 5.8 0.40.40.40.6 0.8 0.4 5.1 6.3 7.3 0.6 0.40.6 0.7 0.7 0.3 3.6 3.4 3.6 0.6 0.3 0.40.6 0.8 0.4 1.6 3.7 4.8 0.4 4.8 6.5 8.9 2.2 0.6 1.0 1.0 3.2 1.0 5.4 3.84.5 2.6 2.2 2.7 3.0 2.6 3.0 4.1 1.7 2.4 0.9 0.3 0.7 0.9 2.40.8 3.5 5.8 6.3 1.1 0.7 0.9 1.4 1.2 0.6 2.8 1.84.5 0.9 0.7 0.9 1.4 1.1 0.9 4.9 1.6 2.8 1.1 0.8 1.1 1.8 1.2 0.7 3.9 2.3 4.0 0.6 0.3 0.40.5 0.3 0.2 3.1 3.7 4.3 0.40.3 0.3 0.5 0.6 0.3 1.9 3.5 5.3 0.40.3 0.2 0.40.7 0.3 4.4 1.8 3.1 0.3 0.3 0.2 0.3 0.40.1 6.3 2.2 3.4 0.2 0.3 0.3 5.8 2.44.6 0.8 0.40.40.7 1.2 0.5 4.4 0.40.5 0.7 0.7 0.9 0.8 3.04.7 6.3 0.6 1.4 1.9 1.0 1.0 0.9 0.9 1.9 4.4 5.4

0.2 0.2 0.40.40.2 0.3 0.5 0.5 0.5 0.6 0.2 4.1 3.7 4.2 0.5 0.40.40.6 0.5 0.3 4.1 3.84.8 0.3 0.40.3 0.5 0.40.2 2.6 3.5 4.3 0.9 0.5 0.8 1.1 0.9 0.5 4.64.6 5.4201020112011201120112012201220122012

4 1 2 3 4 1 2 3 4 8.0 5.4 8.2 8.1 6.7 5.3 7.4 6.8 6.7 5.84.3 8.9 8.5 4.7 4.9 6.4 6.4 5.1 5.44.2 7.2 7.44.1 4.2 5.3 5.5 4.4 6.04.0 6.3 7.5 3.8 5.3 5.7 4.8 7.4 8.0 6.410.7 7.1 4.5 7.3 5.6 5.5 7.9 2.1 2.6 1.1 1.1 2.0 2.1 0.7 1.3 2.2 7.1 5.3 7.1 6.9 5.8 5.5 5.3 6.0 6.5 7.511.5 2.1 2.517.3 8.2 1.8 1.3 3.1 4.5 9.9 7.0 3.6 5.113.911.2 3.8 5.811.9 7.5 7.8 6.2 6.6 9.911.710.3 6.210.1 5.2 6.2 4.3 10.812.2 4.4 1.818.119.6 5.0 2.612.2 7.2 5.7 3.5 4.210.3 8.9 3.5 5.3 8.1 5.0 3.8 3.1 4.3 8.6 5.1 3.8 5.6 5.7 7.7 5.84.7 5.2 7.5 5.9 5.7 6.1 8.1 7.1 5.2 4.2 5.4 8.1 4.9 5.8 5.5 7.7 6.8 5.8 5.2 4.8 9.2 6.9 6.2 5.4 6.0 7.1 4.6 3.1 4.212.1 6.0 3.9 4.7 6.1 7.8 7.4 3.8 5.610.5 9.9 6.1 5.3 6.7 4.1 3.8 5.6 6.6 3.8 2.9 6.0 6.8 5.7 3.2 1.9 1.5 3.1 2.9 2.5 2.2 4.6 1.5 2.8 2.1 2.5 3.1 2.6 1.7 4.64.3 2.3 3.8 2.64.6 5.0 3.9 3.3 4.2 5.4 5.7 2.5 3.1 3.1 0.6 1.6 2.3 1.9 1.6 2.4 3.9 3.6 3.8 2.1 2.5 3.7 2.6 1.0 3.1 7.4 6.0 5.1 5.5 4.0 5.5 3.2 3.7 5.4 7.4 8.410.3 9.7 5.3 6.5 6.3 5.1 6.3 6.4 5.2 8.1 7.1 4.84.6 5.1 5.5 6.6 8.1 5.1 8.7 7.44.7 4.8 5.9 5.5 6.7 6.0 5.6 8.9 7.84.7 6.4 6.1 5.5 6.1 3.1 1.7 2.4 3.0 3.0 2.1 3.5 5.1 3.3 3.9 3.5 3.84.84.2 4.6 3.1 3.84.9 3.4 2.4 3.0 0.6 1.9 4.0 3.0 3.6 2.9 2.6 1.64.4 5.2 3.9 4.6 3.9 4.64.2 2.9 3.4 3.8 2.4 3.4 3.0 3.7 3.2 2.7 4.3 3.1 5.2 4.2 4.2 4.1 4.3 4.44.2 3.8 2.2 3.7 6.6 3.8 3.9 5.9 5.1 4.9 2.9 1.4 3.8 5.1 2.1 2.84.8 5.3 3.4

Organic Carbon SANDWICHed*4.2 2.2 3.7 5.2 2.0 3.04.2 4.6 3.6

5.4 2.84.84.64.64.44.3 4.2 4.9 4.1 3.1 4.1 4.3 5.0 3.9 5.1 5.8 6.5 2.6 1.5 4.6 5.1 3.1 2.3 3.8 5.2 3.9 3.9 4.1 3.1 6.2 3.5 3.4 3.9 5.64.2 3.1 3.0 3.5 3.9 4.1 3.3 3.44.2 4.1 2.8 2.5 3.0 3.7 3.7 3.0 3.44.3 3.7 1.3 1.1 3.2 3.9 1.9 2.5 2.1 3.5 2.0 3.1 1.7 2.3 3.8 3.0 2.9 2.9 4.3 3.5 3.4 2.5 3.5 4.5 3.2 4.1 4.3 4.3 4.1 3.0 1.9 3.2 4.0 3.3 2.9 3.6 5.3 4.4 2.3 2.2 1.8 3.8 2.9 3.7 2.44.7 3.5 3.9 2.8 2.5 3.6 3.84.0 3.1 6.3 3.4

2.0 2.9 3.2 3.2 2.6 3.3 5.6 5.0 3.1 2.9 3.0 3.9 3.5 2.6 3.5 5.44.9 4.0 4.9 4.5 9.2 7.0 5.7 3.7 6.6 6.4 3.8 6.5 8.2 5.7 4.9 6.9 5.4 5.4 6.2 4.0 7.610.7 4.3 7.2 5.3 5.4 6.4 4.9 3.1 6.5 8.0 6.2 6.2 6.6 5.7 6.8

1.6 1.5 0.5 1.0 1.4 1.8 1.3 1.7 2.4 2.7 1.1 4.0 5.5 3.4 2.012.04.2 5.9 3.5 6.2 5.1 3.64.04.1 6.04.9 4.4 2.9 5.3 4.7 4.1 5.64.8 6.3 5.7 4.1 2.1 3.8 5.6 3.84.6 3.8 6.5 4.7 4.1 3.3 4.5 4.8 3.5 4.2 2.9 6.5 4.9 5.8 5.2 6.9 7.4 5.1 4.2 5.4 14.1 6.3 3.44.8 6.3 4.3 3.84.6 5.5 4.6 4.7 4.3 4.9 5.6 3.44.3 4.7 5.5 5.2 5.0 3.64.3 5.3 4.9 4.6 3.4 5.3 4.0 5.8 3.04.5 5.2 2.6 2.8 3.5 4.7 2.6 5.1 3.9 4.84.9 3.7 4.44.8 5.7 4.6 5.1 3.2 4.1 5.1 5.2 3.04.6 5.44.1 3.7 4.6 5.04.7 4.2 3.7 5.6 6.1 3.44.5 4.6 6.64.7

0.6 1.2 3.7 1.5 0.8 2.1 8.7 1.7 8.2 2.5 2.5 5.1 4.4 2.7 2.7 2.6 3.9 3.7 4.6 5.5 3.2 3.0 6.4 6.3 3.1 3.1 4.9 4.3 3.9 1.6 3.2 5.6 3.9 1.8 3.8 3.7 2.7 3.2 4.8 5.64.6 2.9 4.04.1 4.5 2.3 1.4 3.7 4.9 2.7 2.7 4.04.4 3.3 3.3 3.6 5.3 5.6 5.5 4.4 3.9 4.2 5.23.0 2.9 7.3 1.5 3.0 2.7 3.44.1 4.9

3.9 4.2 2.4 6.3 2.8 3.2 3.84.3 4.1

1.1 1.84.1 1.1 1.4 2.9 2.6 1.1 3.2 3.1 4.84.9 3.5 3.3 3.8 5.1 3.6 2.0 1.5 2.8 5.2 1.9 1.7 3.64.2 3.6 4.3 2.84.7 5.2 3.3 4.3 5.0 3.3 5.2 6.0 3.6 5.2 5.7 4.6 6.1 4.5 4.5 6.3 7.5 3.6 5.4 6.5 4.2 5.8 5.1 4.9 8.0 5.1 1.5 3.1 4.1 3.3 2.9 4.44.44.6 5.6 3.4 6.2 6.1 5.1 4.84.9 4.9 6.1 6.0 3.6 5.1 6.04.9 4.44.9 5.0 6.5 4.1 3.1 5.0 6.3 4.04.5 4.4 5.2 5.0 2.4 1.4 2.4 3.1 4.9 2.3 1.4 3.8 3.8 5.0 3.2 5.1 6.5 4.3 3.64.1 5.6 3.9 4.5 1.2 2.84.8 1.9 1.9 3.7 4.0 2.0 3.9 1.9 7.5 5.8 3.6 6.3 5.5 5.1 3.9 4.2 3.0 2.8 5.1 3.8 3.44.1 4.2 2.9 4.3 2.5 2.84.8 3.0 3.8 3.7 4.9 3.0 4.0 1.5 2.84.6 3.6 2.8 3.84.7 3.6 5.9 2.84.6 5.1 3.7 3.44.8 5.0 3.7

2.9 3.7 4.9 3.2 2.4 3.2 4.1 3.8 5.7 3.1 4.64.1 4.9 5.64.5 6.1 4.8 4.8 2.0 3.9 4.0 2.2 0.8 3.1 3.7 1.6 3.5 4.4 5.3 3.8 3.8 3.2 4.9 5.04.4 4.1 3.9 7.04.84.2 4.4 5.7 5.84.8 13.711.3 4.8 3.415.813.1 3.1 8.8 8.212.7 1.6 2.311.612.1 1.6 6.7 8.911.3 3.8 3.713.111.4 2.3 5.2 2.9 2.64.2 4.3 3.7 7.44.9 5.2 5.0 4.8 2.9 1.6 2.8 3.1 3.64.0 3.0 3.7 3.8 4.6 6.5 4.6 5.2 4.8 4.3 2.84.2 3.5 4.4 8.7 4.6 5.6 6.2 5.4 6.4 5.1 6.7 4.2 3.2 2.9 5.8 3.1 3.7 5.7 5.4 5.4

2.3 4.7 5.3 4.3 3.2 4.0 5.3 5.5 4.6 2.3

4.9 3.5 2.7 4.1 5.0 3.5 6.7 4.2 5.0 5.5

4.6 3.6 3.7 5.3 3.44.5 3.7 5.2 5.4 4.94.1 3.3 6.0 6.1 3.1 4.2 3.9 5.7 4.4

7.0 3.4 6.7 7.04.2 6.3 5.3 4.8 6.5

4.6 5.3 7.44.6 5.3 4.9 4.7 4.6 3.6 2.9 3.84.3 4.9 3.04.1 4.2 4.2 5.3 3.1 4.3 6.2 3.84.3 4.7 4.9 5.1 6.5 4.7 6.5 6.04.1 4.6 5.0 3.8 5.6 6.4 3.5 8.1 5.9 3.7 4.2 5.9 5.3 5.6 2.9 2.04.7 5.1 2.4 3.3 4.2 5.1 4.1 4.1 2.8 5.1 6.9 3.8 3.7 3.7 5.5 4.5 5.2 3.1 6.8 8.5 3.8 3.1 5.7 3.5 3.8 3.6 5.0 3.8 3.7 6.0 5.810.64.2 3.2 3.6 5.9 4.3 4.4 5.412.7 5.6 5.84.44.2 7.1 4.8 5.7 3.4 3.7 1.3 3.44.2 2.8 1.9 7.7 3.2 4.7 3.7 1.5 3.04.8 3.2 3.0 6.44.0 2.2 2.9 2.7 2.9 3.6 3.0 3.8 7.4 3.3 3.2 3.4 2.64.9 3.3 3.9 3.9 4.2 3.9 3.1 2.3 4.44.7 4.4 3.7 3.6 5.0 5.4 6.6 8.1 2.2 2.6 9.2 5.0 2.2 4.8 5.9 7.9 8.7 1.6 2.7 8.2 6.9 3.1 5.0 6.9 7.0 7.7 2.5 3.5 8.3 5.2 7.5 7.2 0.8 3.0 8.2 7.0 1.5 8.9 8.8 4.5 3.2 5.1 6.5 4.1 4.5 5.9 6.6 5.3 3.7 4.3 5.2 5.5 5.9 6.1 3.4 1.7 3.6 6.9 4.2 4.3 4.04.9 3.9 4.64.04.3 4.1 3.84.2 3.5 4.9 4.4 5.2 3.7 4.9 4.64.7 4.7 3.9 5.6 3.6 4.8 2.3 3.8 3.5 3.6 3.0 2.9 4.8 3.1 7.2 4.5 5.1 5.5 5.6 5.7 3.6 5.84.3201020102010201020112011201120112012

1 2 3 4 1 2 3 4 1 1.1 1.3 0.8 1.0 0.7 0.7 0.8 0.8 0.6 0.8 0.8 0.7 1.1 0.7 0.8 0.8 0.8 0.8 0.6 0.5 0.5 0.7 0.5 0.5 0.6 0.6 0.5 1.0 0.40.4 1.0 0.7 0.5 0.6 0.7 0.7 1.1 0.8 0.4 1.4 1.0 0.6 0.5 0.8 1.2 0.7 0.3 0.3 0.6 0.7 0.2 0.2 0.7 0.7 0.7 0.7 0.6 0.8 0.5 0.40.40.6 0.4 0.6 0.3 0.6 1.3 1.3 0.7 1.1 2.9 2.5

1.0 0.3 0.5 1.2 0.9 0.3 0.6 1.6 1.2 0.7 0.6 0.8 0.9 1.0 0.40.7 1.2 1.1 2.0 1.2 1.4 1.9 1.7 1.0 1.7 0.8 0.4 1.5 1.5 0.6 0.3 2.1 2.0 1.0 0.2 0.4 1.1 0.9 0.3 0.4 1.3 1.2 0.7 0.3 0.5 0.9 0.6 0.3 0.4 1.2 0.8 0.9 0.40.6 1.3 0.9 0.40.5 1.5 0.9 0.9 0.40.5 1.0 0.6 0.3 0.5 1.1 0.8 0.6 0.3 0.4 1.0 0.8 0.3 0.4 1.40.8 0.7 0.40.6 1.2 0.7 0.3 0.4 1.5 0.6 0.6 0.3 0.6 0.8 0.6 0.3 0.5 1.1 1.0 0.5 0.40.6 0.7 0.5 0.40.7 0.7 0.4 1.40.7 0.8 1.4 1.1 0.5 1.2 1.6 1.3 1.2 0.7 0.7 1.1 0.8 0.5 0.8 1.0 1.0

0.7 0.6 0.6 0.7 0.5 0.5 0.6 0.9 0.7 0.7 0.3 0.3 0.5 0.5 0.40.40.3 0.5 0.5 0.40.3 0.7 0.6 0.5 0.40.5 0.7 0.8 0.5 0.4 1.2 0.9 0.6 0.5 0.8 1.2 1.0 0.7 0.5 1.0 0.9 0.7 0.7 0.8 0.9 1.1 1.5 1.4 1.6 1.1 1.4 1.2 1.6 1.3 0.7 0.9 0.6 1.6 1.4 1.6 1.6 1.2 1.4 1.0 0.7 0.5 0.8 0.6 0.7 0.5 0.6 0.8 0.5 0.40.5 0.8 0.6 0.40.6 0.9 0.7 0.8 0.9 0.8 1.1 0.9 0.9 1.1 1.3 1.3 0.5 0.40.5 0.6 0.40.3 0.3 0.40.5 0.9 0.6 0.8 1.1 0.7 0.6 0.7 0.9 0.8 0.40.3 0.40.5 0.40.40.3 0.5 0.5 0.6 0.5 0.7 0.8 0.5 0.6 0.6 0.6 0.8 0.7 0.7 0.7 0.8 0.5 0.7 0.7 0.7 0.8 0.40.40.5 0.5 0.3 0.40.40.3 0.4 Elemental Carbon SANDWICHed*0.6 0.5 0.5 0.8 0.5 0.5 0.7 0.5 0.6

0.7 0.8 0.8 0.7 0.6 0.9 0.8 0.7 0.8 0.9 0.7 0.7 0.7 0.7 1.0 0.9 0.6 0.7 1.1 1.0 0.6 0.6 0.7 0.7 0.5 0.5 0.6 0.7 0.6 0.40.5 0.5 0.6 0.8 0.40.8 0.6 0.8 0.6 0.6 0.7 0.9 0.5 0.5 0.6 0.7 0.5 0.40.40.5 0.6 0.40.40.5 0.40.4 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.3 0.5 0.5 0.8 0.8 0.40.40.8 0.6 0.6 0.2 0.5 0.5 0.6 0.40.40.5 0.40.5 0.9 0.7 1.0 0.9 0.7 0.7 1.0 0.8 0.6 0.6 1.1 1.2 1.2 0.6 0.6 1.1 0.8 0.9 0.5 0.8 1.0 1.1 0.6 0.7 1.0 0.9 0.9 0.3 0.40.5 0.5 0.4 0.5 0.5 0.6 0.6 0.5 0.40.6 0.6 0.4 0.5 0.5 0.6 0.6

0.6 0.5 0.7 0.6 0.7 0.6 0.8 0.5 0.9 0.6 0.6 1.2 0.7 0.6 0.7 0.8 0.6 0.8 0.6 0.4 1.1 0.5 0.5 0.6 0.6 0.8 0.8 0.5 0.6 1.0 0.6 0.7 0.7 0.9 0.9 0.2 0.1 0.1 0.1 0.1 0.5 0.3 0.5 0.7 0.7 0.3 0.6 0.9 0.6 0.8 0.7 1.0 1.1 0.6 0.9 1.0 1.2 0.8 1.0 0.8 0.9 0.9 0.6 0.8 0.8 0.7 0.6 0.5 0.5 0.8 0.9 0.5 0.5 0.7 0.7 0.5 0.6 0.7 0.8 0.9 0.6 0.6 0.8 0.5 0.6 0.6 0.7 1.1 1.1 0.9 1.0 0.9 1.2 0.8 0.7 0.7 0.9 1.1 0.6 0.7 0.9 0.9 0.9 0.7 0.5 0.6 0.7 0.5 0.6 0.6 0.5 0.5 0.5 0.5 0.7 0.8 0.5 0.6 0.7 0.6 0.6 0.40.3 0.40.6 0.40.40.5 0.40.6 1.1 1.2 1.5 1.1 1.1 0.9 1.40.9 1.0 0.7 0.9 1.0 1.0 0.6 0.7 1.0 0.6 0.6 0.8 0.9 0.6 0.7 0.8 0.6 0.6 0.5 0.5 0.6 0.7 0.5 0.5 0.6 0.5 0.6 0.1 0.1 0.1 0.1 0.1 1.4 0.40.5 0.40.40.3 0.5 0.6 0.40.5 1.1 1.3 0.3 0.7 1.9 1.4 1.0 0.40.6 1.1 1.0 0.40.6 1.40.9 0.8 1.2 1.1 1.1 1.0 0.9 1.0 1.0 0.7 0.40.40.40.40.2 0.40.40.5 0.4 1.3 1.8 1.8 1.5 1.2 1.6 2.3 2.1 1.40.8 0.3 0.5 0.9 0.9 0.5 0.40.9 0.7

0.5 0.7 0.7 0.9 0.9 0.6 1.0 0.8 0.7 2.2 1.5 0.1 0.1 0.2 0.1 0.1 0.3 0.5 0.5 0.5 0.40.5 0.6 0.6 0.5 0.2 0.3 0.3 0.3 0.2 0.2 0.3 0.3 0.2 0.7 0.5 0.6 0.7 0.40.5 0.5 0.6 0.6 0.8 0.7 0.7 1.40.7 0.8 0.7 0.9 1.2 0.8 0.5 0.7 1.1 0.6 0.6 0.6 0.7 0.9 0.5 0.6 0.6 0.9 0.5 0.5 0.40.7 0.9 0.7 0.6 0.6 0.9 0.6 0.6 0.6 0.8 0.7 0.6 0.5 0.5 0.8 0.40.5 0.5 0.7 0.6 0.5 0.7 0.6 0.8 0.6 0.5 0.6 0.7 0.7 0.3 0.3 0.3 0.40.2 0.3 0.40.3 0.3 0.6 0.6 0.8 0.9 0.5 0.6 0.8 0.7 0.6 0.9 0.8 1.0 1.1 0.6 0.9 1.1 1.1 1.0 1.1 1.0 0.9 1.1 0.5 1.1 0.8 0.9 1.0 0.40.5 0.8 0.9 0.40.5 0.8 0.8 0.6 0.5 0.5 0.7 0.8 0.5 0.5 0.9 0.6 0.7 0.6 0.9 0.9 0.9 0.5 0.7 0.9 0.9 0.8 0.6 0.8 0.9 1.0 0.5 0.7 0.7 0.8 0.7 0.5 0.7 0.8 0.6 0.6 0.7 1.0 1.0 1.0 0.5 0.7 0.8 0.8 0.8 0.40.7 0.7 0.8 0.40.7 0.9 0.6 0.6 0.3 0.40.40.5 0.40.40.40.5 0.4 0.5 0.5 0.40.5 0.5 0.5 0.40.5 0.5 1.5 0.40.2 1.8 1.40.6 0.3 1.7 1.7 0.8 0.40.4 1.0 1.7 0.5 0.5 1.2 1.5 1.1 0.3 0.2 0.8 1.1 0.3 0.3 1.1 1.3 0.5 0.7 0.8 0.7 0.40.5 0.7 0.7 0.8 0.9 0.7 0.6 1.3 0.40.5 0.5 0.5 0.3 0.40.40.5 0.5

1.1 0.7 0.8 0.8 0.8 0.5 0.5 0.7 0.7 0.8 0.7 1.2 1.4 1.3 1.0 0.7 0.8 1.0 1.0 0.8 0.5 0.6 0.7 0.8 0.6

0.7 0.9 0.8 0.8 0.5 0.6 0.8 0.8 0.8 0.5 0.5 0.5

0.3 0.6 0.6 0.40.5 0.6 0.6 0.6 0.40.3 0.60.6 0.40.40.5 0.40.5 0.40.5 0.5

0.7 0.7 0.6 1.2 0.7 0.6 0.6 0.7 1.2 0.7 0.5 0.6 0.7 0.8 0.3 0.3 0.3 0.40.2 0.3 0.40.40.3 0.8 0.9 0.8 1.2 0.5 0.7 0.9 0.9 0.8 0.8 0.8 0.7 1.1 0.7 0.8 0.8 0.8 0.9 0.9 0.9 0.9 1.1 0.5 0.7 0.8 0.7 0.7 0.40.40.3 0.40.40.40.40.3 0.4 0.40.40.40.5 0.3 0.40.5 0.5 0.5 1.2 1.2 0.8 0.9 0.6 0.7 0.8 0.6 0.5 0.6 0.8 0.7 0.6 0.6 0.9 0.7 1.3 0.5 0.7 1.2 1.1 0.6 0.5 0.9 1.0 0.5 0.7 0.40.6 1.1 0.5 0.5 0.7 0.5 0.6 0.3 0.40.7 0.5 0.3 0.5 0.8 0.6 0.9 0.40.5 1.0 0.7 0.40.6 1.0 0.8 0.7 0.3 0.40.5 0.6 0.3 0.40.8 0.7 0.3 0.40.40.40.40.3 0.5 0.5 0.5 0.7 0.5 0.6 0.7 0.5 0.6 0.6 0.8 0.7 0.8 0.40.4 1.1 1.40.3 0.4 1.5 1.0 1.1 0.40.4 1.6 1.40.3 0.4 1.4 1.2 1.1 0.40.5 1.1 1.3 0.40.5 1.4 1.1 0.8 1.4 1.2 0.2 0.4 1.2 1.0 0.9 0.9 1.1 1.5 0.8 0.9 1.0 1.1 1.1 0.5 0.9 1.0 0.7 0.6 0.8 1.2 0.5 0.6 1.0 0.40.4 0.40.3 0.40.40.3 0.3 0.40.40.4 0.5 0.5 0.7 0.7 0.5 0.40.6 0.8 0.6 0.2 0.2 0.2 0.3 0.2 0.3 0.2 0.3 0.3 0.6 0.6 0.7 0.8 0.5 0.6 0.8 0.6 0.6201220122012

2 3 4 0.6 0.5 1.0 0.6 0.5 0.7 0.5 0.40.6 0.5 0.3 0.8 0.5 0.40.9 0.2 0.3 0.6 0.7 0.5 1.1 1.0 0.7 1.4 1.6 0.40.5 1.2 0.7 0.5 1.8

0.7 0.2 1.4 0.3 0.3 1.0 0.40.40.7 0.40.4 1.3 0.40.5 0.6 0.3 0.40.8 0.3 0.40.6 0.40.6 0.7 0.40.5 0.6 0.6 0.8 1.1 0.6 0.7 1.1 0.7 0.7 1.0 0.40.3 0.4 0.40.3 0.6 0.5 0.4 1.0 0.6 0.5 1.1 0.9 1.0 1.4 1.3 1.0 1.1 0.5 0.3 0.7 0.40.5 1.0 1.1 1.2 1.3 0.3 0.40.5 0.6 0.7 0.9 0.5 0.40.6 0.6 0.6 0.7 0.7 0.6 0.8 0.40.3 0.30.5 0.5 0.5

0.6 0.5 0.8 0.6 0.7 1.0 0.5 0.6 0.7 0.5 0.40.5 0.5 0.7 0.7 0.3 0.40.4 0.2 0.2 0.2 0.5 0.7 0.5 0.5 0.5 0.5 0.8 0.9 0.7 1.0 0.9 0.7 0.8 1.0 0.8 0.5 0.40.5 0.5 0.5 0.6

0.6 0.5 0.40.7 0.40.40.9 0.7 0.5 0.8 0.1 0.1 0.1 0.3 1.0 0.6 0.7 1.0 0.7 0.7 0.8 0.7 0.5 0.7 0.6 0.5 0.7 0.6 0.6 1.0 0.7 0.7 0.9 0.40.5 0.5 0.5 0.6 0.5 0.8 0.7 0.7 1.5 1.2 0.9

0.6 0.7 0.6 0.5 0.5 0.5 0.1 0.3 0.1

1.4 0.3 0.5 0.4 0.40.5 1.5 0.3 0.5 0.9 0.7 0.8 1.0 0.3 0.40.5 1.2 1.5 1.90.3 0.4 1.1

0.5 0.6 0.7

0.2 0.2 0.1 0.7 0.9 0.9 0.2 0.3 0.3 0.5 0.40.7 0.6 0.6 1.0 0.6 0.6 1.0 0.6 0.5 1.0 0.5 0.5 0.8 0.40.40.7 0.5 0.5 0.8 0.2 0.3 0.2 0.7 0.7 0.7 0.8 0.8 0.8 0.8 0.7 0.7 0.6 0.7 0.6 0.5 0.7 0.4 0.7 0.8 0.6 0.8 0.8 0.7 0.5 0.6 0.5 0.8 0.9 0.7 0.9 1.1 0.6 0.40.3 0.4 0.5 0.3 0.6 0.40.6 0.3 0.7 0.40.5 0.5 0.8 0.8

0.3 0.40.6

0.6 0.7 0.9 1.1 0.5 0.8 1.1 0.6 0.9 1.0 0.7 0.8 1.1 0.5 0.6 0.9

0.5 0.4

0.9 0.7 0.8 1.0

0.3 0.40.60.40.40.4

0.5 0.5 0.9 0.5 0.5 0.9 0.3 0.3 0.3 0.7 0.6 0.7 0.7 0.7 1.0 0.7 0.6 0.9 0.3 0.2 0.4 0.40.40.4

0.6 0.5 0.8 0.5 0.5 1.2 0.5 0.5 0.6 0.40.6 0.6 0.40.6 0.9 0.3 0.5 0.6 0.40.5 0.5 0.5 0.5 0.8 0.3 0.5 0.8 0.40.5 0.9

0.3 0.7 1.0 1.0 0.8 1.1 0.7 0.6 0.9

0.40.5 0.4 0.3 0.3 0.3 0.5 0.6 0.4 0.2 0.2 0.2 0.6 0.6 0.4