# OAR Box 1413 Prepped by Ollie Stewart



## Document

Number: 

# 82 ) 11-1-8 3 Docket Number: 

# A-94-5 2

Printed 7/9/2008 3:11:24

PM Sheet 82 of 114 P. 1P. 2
Stat e o f Wisconsi n \ DEPARTMEN TO F NATURA L RESOURCE S Tomm y G . Thompson , Governo r Georg e E . Meyer , Secretary Willia m R . Selbig , Regiona l Directo r Oshkos h Servic e Center 90 5 Bay Shor e Driv e P.O . Box 256 5 Oshkosh , Wisconsi n 5490 3 Telephon e 920-424-305

0 FA X920-424-440 4 August 25 , 199 8 Madelein e Stru m U S EP A OAQPS ES A MD1 3 Researc hTriangle Park , N

C 2771 1 Dea r Ms . Strum : 

# m'? ?
PPA 4,1** . r \ u".K . SUBJECT : CustomFiberglas s Moldings , Inc . I Hav e enclosedt o Wisconsi

n Operation Permi

t Application fo

r Custo mFiberglas s Molding , Inc . The y ar e located i n Weyauwega, Wisconsin , a n attainment/unclassifiedare afo r al l pollutants . Yo u reall y didn' t decide whethe

r yo u wante dto ad dthe facilit

y to you r databas e o

r no t so I' msending th

e application an

dif yo u decide not

to us e i t yo u ca n trashit . I wan t t o tan k yo u fo r your time o n the phone . Sincerely , 

# &^ijf1J

H,Jf 

# ^ r- Jy > Craig T . Steiwler

, P. E Ai r Managemen

t Enginee r Oshkos hServic e Cente

r (920)424-305 0

Quality Natural Resources

Management Through Excellent

Customer

ServiceP. 3

: o f Wisconsi n irunen to f Natura l Resource s

• INSTRUCTIONS O

N REVERS ESIDE ^Uit)|nffie!an d mailing : addres s Eacflity^ccEuiq

n Paren t corporatio n

Responsible officia l Pen__Jt?cicm^tfpa*siSn FACILIT Y ©ENTTFICATIO

N AI RPOLLUTIO

N CONTRO

LPERMI T APPUCATIO N For m 4530-10 0 11-9 3 Infonnatio n attached ? _(y/n ) Nam e Stre£t ^ C^S^;|Zip^oB e Stric t Addres s i^I|GoSt y Nam e Street o r Rout e City , State , Zi

p Cod e Countr y (i f not U.S. ) Nam e Telephone Nam e l a(T/i M rinp-ft/^ aMn<i-.i,:)c J'.:-..

E^R&O t

iTTLr ri(Uf.\ ."-

. C . fl x 26n t

cm r n ur. . i'i o i,-)f^Aw\.)F(^x

y L)AL4fij.fA

flit * D/C/HKn PAr T CM- ) I'^T. °\ 3 . 0 - 8 L -i 'J. (. i. o Da*'*. Titl e DI-^FCTQ^ pc t.ArrT-j

A ,ox-\ h\fi ii.rre. on e SKgcoaif : ^ Q Cj Ox ^ P - 2 lal - 7^ 0 Ejuajita|^ ^ ^JLLD
. '-yQjX-^O- a^ J J Primaiy activit

y o f the operating establishmen t f) no0or ,„ r

F , ,i. rA QCA%iPAKTS: T^piplperffl t

"'/ ' / x " ' D Construction penni t

I Anticipate dstar

t dat e fo r construction : Anticipate dstar

t dat e fo r operation : ^T/

U PftA*-*^Si Thi s applicatio n i s requesting a n expedited review (see instructions ) Operatio n Permit

• Par t 7 0 Sourc e Application Jfe^Non - Par

t 7 0 Sourc e Applicatio n

• Synthetic Minor , No

n - Pa n 7 0 Sourc e Applicatio n
• Ye s JtlSfN o D Electiv e operatio n permit

. I f facilit y i s locate din a

n are adesignatedas "nonattainment" , indicat e the pollutan

t fo r the nonattainmen

t designation . 

# ATTAINMFrvT TAWc-A

. , Lis t all ai r pollutio n permit s an dorders issue dt o thi s facility .
^Th^flxZ /WLxZ

AJ O A\(L

pOlAUTWlO PfilH.T S /S^gft .

^P. 4

: o f Wisconsi n inmen i o f

Natura l Resource s FACILIT Y PLO T PLA

N AI RPOLLUTIO

N CONTROLPERMI

T APPUCATION For m4530-10 1 11-9 3 o f thi s for mi s requiredb

y the Department

fo r an y ai r pollution contro l penni t

application filedpursuan

t t o s . 144.39 2 or .3925 , Wi s Stats . Completion o f thi s for mi s mandatory . Th

e Departmen

t wil l no t conside r or act upo n you r application ss s yo u complet e an dsubmit thi s form . It

i s no t th e Department' s intentio n t o us e an y personall

y identifiable informatio

n fra; : for mfo r an y othe r purpose . irde r fo r acomprehensive ai

r qualit y analysi s t o be accomplished , afacilit y plo t pla n MUS T be includedwit

hth e penni t lication . Thi s facilit

y plot pla n mus t include all o

f th e followin g items o r

the penni t

application wil

l b e deeme

dincomplete : FO RDEPARTMENT US E ONL Y .OMPLET E INCOMPLET E NO T APPUCABL E 

# •• 

# • • • D 

# • • • • • • •
•• 2 -*^__j*}-'*-.'^-r**>-**'*-i*- ' -. ^ "»«v • v*^«*"v / «^'^>- t ^rf . <W j w»^', ^ ^*^»»*yr&^<*#*-<m-^ 94ri*xx.y. % r-vy,
. -Th e -maximu mheighto f

e^<ound-nriexcludingfstacl c height) !

J>TM_TM»VWX 1 *A_„W_. « :.>)/A/__iyuMM»^'M«W.'>\«--^v.vlnwM^££v ^ gHdeiiiifyfrdirect-^jf^ ^

»?-f^-)*-$*«^_,%-tf-*.*-K*^a-^ ^ y.^TadditionaBgegionalinw ^ 2^uxroundmgma__Jiy^roa^ ^
there an y outdoor storag e pile s o n th

e facilit y site ?

, wha t materia l doe s the pile(s ) consis t

of ? • Ye s 

# X N o

there an y dir t road s o r unpavedparkin g lot s on th e facilit y site ? * Ye s • N o



# 2LP. 5

f Wisconsi n SOURC EAN D SITEDESCRIPTIONS men to f Namra l Resource s AI RPOLLUTIO N CONTRO L PERMI T APPUCATIO N For m4530-10 2 11-9 3 Infonnatio n attached ? _(y/n ) > f thi s for mi s require db

y the Departmen

t fo r an y air pollutio n contro l penni t

application filedpursuan

t to s . 144.39 2 or 925 , Wi s Stats . Completion o f thi s for mi s mandatory . The Departmen t will no t conside r o r ac t upon you r applicatio n s you complete andsubmi t thi s form . It

i s no t the Department' s intention t o us e an y personall

y identifiable information fro m ormfo r an y othe r purpose . Briefly describ e the proposedproject o r existing JJnit(s ) t o b e permitted . Attachedsupplementa l form s as needed . C CiSTC- A f 11 3 I T ILG t A*
. S P-AO

L OIKJC / $ A ro

fSjiiSTIroc

MANO. r*£Tut\.c

0 F /. u TUpc\~ Aloi) SIZES

OF /"-iGl-'lfccv rpArxTSj DlSTfliduTirQ

T h liu c<-- T T h £ k- S A A I 0 OU_T.J
_ 5£AS. J

X rJ Thi. rAbtr,oF4tTt*t\i-tot pilot ers ij € Ui € /lESWi

-Gft-r<M*r$ - MATT/M G - C^oPPC O Sm, u o ./^T^O , - recede Sfcco. T S ^ 0 roc^ c nertlJ , IjC ALSO

OO J<*f-»-

t /' A iwTw

t Of PAar\, Ar~ex\. -|- H E p^ aTy i n / , 0 L ; (J f< .

£ Sf £ I

OIAFO<\-

0ETA^i\

Sit e Descriptio n \%,0 ACWtS

LoCaTiZO

0 < u 7 fi t 0 o <VNL - N , O F /- m xt Jliuci
. •£«.
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/.OC^TIO O ./VuiAriii.^ t i)p $ iGfv*4Ttc

*J -4^ o '3u.<(.<->
. w cH£tCt,T 

## ) 5'CA c I' O MA«] 4 S't" £ /^^f-JOv x~77TP. 6

o f Wisconsi n SOURC EDESCRIPTIO

N - SUPPLEMENTA

L ctmen tof Naaua l Resource

s AI RPOLLUTIO N CONTRO L PERMI T APPUCATIO N For m4530-102A 11-9 3 Infonnatio n attached ? _ _(y/n ) o f thi s for mi s require db y the Departmen t fo r an y air pollutio n contro l permi

t application filedpursuan

t t o s . 144.39 2 or 3925 , Wi s Stats . Completio n o f thi s for mi s mandatory . The Departmen t wil l not conside r or act upo n you r applicatio n s s you complete an dsubmit thi s form . I t

i s no t the Department' s intention to us e an y personally identifiable information irc m for mfo r an y other purpose . Lis t al l significant

existin g or

proposedair

pollutio n units , operations , an dactivitie s a

t the facility . A sho n narrativ e of the inventor y o f air pollutio n emission s unit

(e.g. , boiler , printin g line , etc. ) followe db y equipmen

t specification s wil

l suffice . I

f the facilit y consist s o

f severa l individua l emission units , presen

t thi s infonnation i

n a n outline format . (See instructio n booklet for a n exampl e Unit

description. ) 

# JJJ AP P L/C AT/drJ * 

## FOTL; pO]

SOI - GeuOAT

BOOTH

ANO SXHAU$T* 

## POI- S0(L\ A^iNAjitxjc /uur* j AND FXH/.«wr POI- S03<^ POZ- SO L 

## /~- yVHK/r
. ro c HUE

JGOC-H^M O EXHAIUTI 

## pO L 

## l - SOS- TaiHhiM t AilCAA»o ZXHAurr' : BtfS " SOL-

SPACE

h 

## £ ATItOLAto0



## EJMAUST.' PCS - -SCZSD2

- Too^c

o rm» n^'fa,^) 

## fO£- SOI r^ W 

## or- W 

## ^H0C0 S 

## [Gfu^r ] p Jt" £ I

IVQIU\0UA.. Fo.Uij - 101AF0(LEACHP. 7

o f Wisconsi n SOURC EDESCRIPTION - SUPPLEMENTA L «m« U of Natura l Resource s AI RPOLLUTIO N CONTRO L PERMI T APPUCATIO N . For m4530-102B 11-9 3 Information attached ? _(y/n )

of thi s for mi s require dby the Departmen t fo r an y air pollutio n contro l permit

application filedpursuan

t t o s . 144.39 2 o

r 3925 , Wi s Stats . Completion o f thi s for mi s mandatory . Th

e Departmen

t wil l not conside r or ac t upon you r application s s yo u complet e andsubmit

thi s form . I

t i s not th e Department' s intention t

o us e an y personally identifiable informatio n .ic m for mfo r an y other purpose . Mar k al l insignificant

existin g or

proposedair

pollutio n units , operations , an dactivitie s at

th e facilit y liste dbelow . I

f no t listed , provide ashor

t narrativ e of

th e inventor y o f air pollutio n emission s unit

(e.g. , boiler , printin g line , etc. ) followe dby
equipmen t specifications . If

the facilit y consist s of

severa l individua

l emission units , present

thi s infonnatio n in a

n outline forma t (See instructio n booklet

fo r a n example Unit

description. ) ^Maintenanc e of

Grounds , Equipment , an

dBuilding s (lawn care , painting , etc. )

• Boiler , Turbine , andHVA C Syste mMaintenanc e b_ ( Pollutio n Contro l Equipmen t Maintenanc e Js ( Interna l Combustio n Engine s Usedfo r Warehousing andMateria l Transpor t ffl Fir e Contro l Equipment JS ( Janitoria

l Activitie s ^Offic e Activitie s ^Convenienc e Wate

r Heating jfc f Convenienc e Spac e Heating ( < 5 million BTU/h r Burning Gas , Liquid , o

r Wood )

• Fuel Oil Storag e Tanks ( < 10,000 gal. ) D StockpiledContaminate dSoil s D Demineralizatio n an

dOxyge n Scavengin

g o f Wate r fo r Boiler s

• Purging o f

Natural Ga s Line s ^Sanitar y Sewer

andPlumbing Venting 

# • • D 

# • • • • €0P. 8

HStat e c f Wisconsi n Departmento f

Natura l Resource s INDE X O F AI RPOULUTIO N PERMI T APPUCATIO N FORM S For m 4530-13 4 11-9 3

I . ADMINISTRATIO N

TU s application contain s tb e followin g forms : - JsL For m 4530-100 , Facility Identificatio n J2^ For

m 4530-101 . Facility Plo tPlan J l Fonn s 4530-102 , -102A . in d -102B , Sourc e and Site Description s
I L EMISSION S SOURC E

DESCRIPTIO N Thi s applicatio n contain s th e followin g forms (on e for m fo reac h facility boiler , printing operation , etc.) : * 

## • 0 

## o a 

## e 0 For

m 4530-103 , StackIdentificatio n For m 4530-104 , Boile ro rFurnace Operatio n For m 4530-105 , Storag e Tank s For m 4530-106 , Incineratio n For m 4530-107 , Printin g Operation s For m 4530-108 . Paintin g an d Coatin g Operation s For m 4530-109 , Miscellaneou s Processe s Total Numbe r o f Thi s For m 

# 6 

# 1 

# 6 S

in. AI RPOLLUTIO N CONTRO L

SYSTE M Thi s applicatio n contain s th e foUowin g forms : 0 D 0 0 0 O 

## a a For

m 4530-110 . Miscellaneou s For m 4530-111 , Condensers For m 4530- 1 l i Adsorbers For m 4530-113 . Catalyti co rThenna l Oxidatio n For m 4530-114 , Cyclones/Settlin g Chambe n For m 4530-115 , Electrostati cPrecipitators For m 4530-116 . We tCollectio n System s For m 4530-117 . Baghouses/Fabri cFilter s Total Number o f Thi s For m

IV . COMPLIANC E

DEMONSTRATIO N Thi s applicatio n contain s th e followin g fonn s (on e fo reac h facility boiler , printing operation . etc.) : ' D For m 4530-118 , Complianc e Certificatio n • Monitorin g an d Reporting 0 Fan n 4530-119 , Continuou s Fmhtto n Monitorin g D For

m 4530-120 , Periodi cEmissio n Monitorin g Usin g Poitabl e Monitor s 0 For

m 4530-121 . Control Syste m Parameters o rOperation Parameten o f a Proces s D For

m 4530-122 , Monitorin g Maintenanc e Procedure s O For

m 4530-123 , StackTesting D For

m 4530-124 , Fue l Samplin g and Analysi s O For

m 4530-125 , Recordkeepin g Total Number o f Thi s For m

~^~P. 9

V . EMISSIO N SUMMAR Y AN D

COMPLIANC E O-KT1HCATI0 N Thi s applicatio n contain s th e followin g forms quantifyin g emissions , certifyin g complianc e with applicabl e requirements , and developin g acomplianc e pla n B Fon n 4530-126 , Emissio n Uni tHazardous Ai rPollutantSummar y D For

m 4530-127 , Facility Hazardous Ai rPollutantSummai y D For

m 4530-128 . Emissio n Uni tSummai y 0 For

m 4530-129 , Facility Emission s Summai y 0 Fon n 4530-130 , Cunen tEmission s Requirement s and Statu s o f

Uni t D For

m 4530-131 , Emissio n Uni tComplianc e Plan - Commitments and Schedul e 0 For

m 4530-132 , Curren

tEitiiwon tRequirement s and Statu s o f

Facility O For

m 4530-133 , Facility RequirementComplianc e Plan Commitments an d Schedul e Tota l Numbe r" i o f Thi s For

m j 

# J T * .

VI . SIGNATUR

EO FRESPONSIBL

EOFFICIA

L



### B . STATEMEN

T O FCOMPLETENES S I hav e reviewedthi s application i n it s entiret

y and , basedon information an dbelief forme dafte r reasonable inquiry , I certif y tha t the statement s an

dinformation containedin thi s applicatio n ar e true , accurat

e an dcomplete . 

## Wmm^^^M^^mm^^mim^^m^^(<*ec k on e bo x only ) TfflsTl S NOT A REQUIREMEN T O FNON-PAR

T 7 0 SOURCES . fe I certif

y tha t the facilit y describedin thi s air

pollutio n penni t

implication i s full

y in complianc e wit

hal l applicabl e requirements .

• I certif

y tha t the facilit y describedin thi s air

pollutio n permit

application i s full

y in complianc e wit

hall applicabl e requirements , except

fo r the following emission s unit(s) : (lis t al l non-complying units )
Printedo r Type dNjm e 

## QWH



## £11, 

# Ofjiu m Signatur e DatesSigned 

# y-n.d-'W' SEN D ALLMATERIALS TO : WISCONSI

N DEPARTMEN

T O FNATURA

LRESOURCES BUREA U O FAI RMANAGEMEN

T PERMIT S SECTIO

N P.O . BO X 792 1 MADISON , W

I 53707-792 1



# [JP.1 0
V . EMISSIO N SUMMAR Y AN D

COMPUANC E CERTTHCATION Thi s applicatio n contain ! th e followin g forms quantifyin g emissions , certifyin g complianc e with applicabl e requirements , and developin g acomplianc e plan • For m 4530-126 . Emifrir

m Uni tHazardous Ai rPollutantSummai y D Fon n 4530-127 . Facilit y Hazardou s Ai rPollutan tSummai y D For

m 4530-128 . Emiimnn Uni tSummar y Q For

m 4530-129 , Fadlit y Emission s Summai y 0 For

m 4530-130 . Cunen tFirmiion tRequirements and Status o f Uni t 0 Fm— 4530.111 , Fmixfinn Uni tCo»7>pl"-_"« J Plt W - Co-pTM"TMTM " and Schedul e 0 For

m 4530-132 , Cunnt tEmissio n Requirement s and Status o f

Facility D For

m 4530-133 . Facility Requiremen tCompliance . Plan Commitment s and Schedul e Tota l Numbe r o f Thi s For m ^



### V L SIGNATURE O F RESPONSIBL E OFFICIAL



### B . STATEMEN T O F COMPLETENES S I hav e reviewed thi s applicatio n in it s entiret y and , base d o n infonnatio n an d belie f forme d afterreasonabl e inquiry , I certif y tha tthe statements and infonnatio n containe d i n thi s applicatio n ar e true , accurat

e an d complete . l^L^rrW^JW^^^^^^^^^^^^^^^ (chec kon e bo x only ) THI S I S NO T A REQUIREMEN T O F NON-PAR T 7 0 SOURCES . fe I certif

y tha tth e facility describe d i n dii s ai rpollutio n penni tapplicatio n i s full y i n complianc e widi al l applicabl e requirements.

• I certif

y tha tdi e facilit y describe d i n thi s ai rpollutio n penni tapplicatio n i s full y i n complianc e wit h al l applicabl e requirements, excep tfo rthe followin g emission s unit(s) :

(lis tal l non-complyin g units ) 

## OWHtm. 

# ouiugn
.y-id-isSEN D AL L MATERIAL S TO : WISCONSI N DEPARTMEN T O F NATURA L RESOURCE S

BUREA U O F AI RMANAGEMEN T PERMIT S SECTIO N P.O . BO X 792 1 MADISON , W I 53707-792 1



# QP.1 1

.



## SIT E PLA N Approximate

Scale: f = 400' 

# A PPBW

i x HE
ede rassociate s

FIGUR E 1



## LEGEN D fa Materia/

Handling ^ Practice -* —Drainage

Way

6 0 I Approximat e Scal e I n Fee t

01239 6 SW15451 A 

# SITEEVALUATIO N MA P CUSTO M FIBERGLAS S MOLDIN G

WEYAUWEGA , WISCONSI N 

### //- ) i iP.1 2



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16/09/199 8 11:5 4 414-265-919 9 HASTING S AI R ENERGY PAG E 8 1



# HASTINGS AIR-ENERG Y CONTRO

L 14 1 Ww l Vin e sSlrec

t » Milwaukee , Wisconsi n53:1 2 414-265-360 0 . 1-800-236-845 0 • Fax : 414-265-919 9



### To : 

# feo& Hy

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# £w G Company : C-UaWv\<Uftfl\<vW ar^cAi-w ^ Company : Hasting s Air-Energ y Cont r Fa x Number : ^2- 0 %k ? 2 k \ S ntro l Fa x Number : 414-265-919 9 Date : 

## \b0uti^ & Time : \\\ * & Numbe

r o f Page s Sent : c-3

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# V4JL)L O &A>
. riease call if you are misting any port oftlis transmission. 

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only for the use ofthe individual or entity ofwhich it

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ond may contain information that is privileged, confidential, and exempt from disclosure under

applicable law. If

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### sender via first class mail. Thank

you! .:\.cn».u»-(nee.do < 

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STATICALL YTESTE D DEVICE S TES TREQUESTE D 8 Y^yftg g &M? &*n&?W«> 

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# J 4P.1 7

HASTING S AIR-ENERG Y CONTRO L "ADIVISION

OF HASTINGS

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### INVOIC E
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03-20-9 8

CUSTO M FIBERGLAS S MOLDIN G E538 G LITTL E RIVE R ROA D WEYAUWEGA . W I 5498 3 SHI P T O CUSTO M F IBERGLAS S MOL D I. H G E583 0 LITTL E RIVE R ROA D WEYAUWEGA , W I 5 49£: 3

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### jfwiscomi nSOURC E DESCRIPTION - SUPPLEMENTAL tmen t of Nuara l Resource s AI RPOLLUTIO N CONTRO L PERMI T APPLICATIO N 

### For m 4530-102 A 11-9 3 Infonnatio nattached ? _ (y/n ) D f thi s for mi s require db y th e Departmen t fo r an y ai r pollutio ncontro l permi t

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t o s . 144.39 2 o r (925 , Wi s Stats . Completio no f thi s formi s mandatory . Th e Departmen t wil l no t consider o r ac t upo nyou r applicatio n i s yo u complet e an dsubmi t

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severa l individua l emissio nunits , presen t thi s informatio ni nanoutlin e format . (Se e instructio n bookle t fo r a nexampl e Uni t

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# I

&P.1 9

of Wisconsi n -tmen to f Natura l Resource s INSTRUCTIONS O

N REVERS ESIDE STAC K IDENTIFICATIO

N AI RPOLLUTIO

N CONTRO

LPERMI T APPLICATIO

N For m4530-10 3 11-9 3 Infonnation attached ? _ (y/n) Facilit y name : 1T/.M . Fi(\£tu&Cj.*r

MOLPJioc 3 . Stack : identificatic mnumbe r 

# SOL Exhausting Unit(s),us e Unit idendfii_^on'-mmbef,-_Tbm-Lppropria107 , 108'and/or 109 50-10 4 4530-10 6 4530-107 4530-10 8 4530-109 Identif y thi s stack

on the plo t

pla n requiredo

n Fon n 4530-10 1 Indicat e b y checking : _-_ T Thi s stack

ha s a n actua l exhaus t point . D Thi s stac

k serve s to identif

y fugitiv e emissions . I f thi s stac k ha s an actual exhaus t

point , then provide the ^o^i ^ :st^;par_mete-- s Discharg e height

abov e groundJweT ; /<*./)$(feet ) Inside dimensions * a

t outlet (check 'one*a_££complete) : JS T Circula r -S L(feet ) . • rectangular , lengt h(feet ) widt

h(feet ) ExHa^gl^^rate ; Maximu mHffl/fl (ACFM

) Fi^|ust|^^mpOTi^|i_n§ffi ^ 1%°(°F) Exhaus t ga s moistur

e content : Norma

l volum

e percent Maximu m volum

e percen t Ex^ui>t;g^'disclfa^^dirlKH ^ D U p D Down Horizonta l l-rthisst^eq^pj-^Jwfo^ ^ -fl f Yes O No exhaus t gase s fromth e stack ? r\ . _, _C/ . r t . , _- _,__. , , ,

__ : _ : : (S)(\-Ar(-\) Coat- 1 ^FOiX. \A ^e:ru Pr\nrircTlQfJ • * Complet

e the appropriat

e Air Penni t Application Forms(s ) 4530-104 , 106,107 , 10 8 o r 10 9 fo r eac hUni t • exhausting throughthi s stack .



## 1 ^P.2 0

•j f Wisconsi n •uncu to f Natura l Resource s PAINTIN GAN D COATIN

GOPERATIONS AI RPOLLUTIO

N CONTRO

LPERMI T APPLICATIO

N Fonn 4530-10 8 11-9 3 Information attached ? _(y/n ) INSTRUCTION S O

N REVERS ESIDE Facilit y name:(J u m ^ piftBAt , A f f MOW... * S^k : ^idm|^catio n nirmber : QQ J 

### 2 . 4 . Facilit

y identification number Process;number : Q/\ i Unit description : 

### £ZhAU<rr

STA-CK



### O /R( 

### noen. Indicat e the contro l technology status . Uncontrolled• Controlled I f th e proces s i s amtcblled , rater the " contro l deyiceJnumba-(s ) from.the appropriat e form(s) : 4530-110. 4530-11 4 4530-111 ,

4530-11 5 4530-112 .

4530-11 6 4530-113 ,

4530-11 7 Applicatio n technique an

dtransfe r efficiency (%) : r

• 

## HVLP , Date o f con-^ctio^crlastmoda^dp m/97 ? Norma l operatin g .schedule : fn hrs/da y Oven curin g (complet

e i f applicable) : Numbe r o f oven s Total MaximumEnergy inpu t t o eac hoven : ,5 " davs/w k Specif y ove n 

## / C 6. #„ l£<idays/y

r fuel s Describ e al l o f

th e coatings ' an dsolvents ' compositio n(a s applied ) tha t ar e use db y thi s unit . OnSSSSSafS
-^S-feti-M i _-^&-l" J *"»"-" * 

# ft3iH _KS__ L gal/h r gal/y r gal/y r Solid s % f . W 

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% g

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# IAL E C Pen-Oanoe •OW 

## 2os:n ~?Oa1<. "7.f f

>tal coating s G>£(rCOAT » * ACTUAL. G/U J 

## jp/uj-r o > uoe co s P/vG* c v 3s? 0

X /§"MAL J /^o* j 9t3.f*iOALj
- /J/ L^ * - A)A

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ean-up solvent s / ean-up solvent s Lhe r (specify ) : ** * For thi s em i DESCPJPT.. . an dit s attachment(s ) to thi s form . Thi s i s not arequiremen

t o r non-rat i . v '** * Pleas e complet

e the Ai r Pollution Contro l Penni t

Application Form s 4530-12 6 an d4530-12 8 fo

r thi s Unit . **** * .tin g categorie s (ct . eg . - colum n b . above) shouldbe entereda s follows : 1 - fo

r ai r driedcoatings ; 2 - fo

r clea r coatings ; 3 curedcoatings ; 4 - fo

r extrem e performance coatings ; 5 - fo r othe r (specify) 0-118 , **** * 0-11 8



# 1P.2 1

n f Wisconsi n xmen to f Natura l Resource s INSTRUCTION S O

N REVERS ESIDE EMISSION UNI T HAZARDOU S Ai KnJlJLUiAiN l _.UM_VIAK I AI RPOLLUTIO

N CONTRO

LPERMT T APPUCATION For m4530-12 6 11-9 3 Information attached ? _ (y/n) Facilit y name : Q'

C_.<T/» M FmenfiiLAiiMoiDMJLTat. 2. Wim^Mm^c^aawivIo!^ Stack identificatio n numbe r 

### __HL 4 . tJniHdeiiitificafibri ® 

# ML Uni t materia l description : Q ELC 6JTT > Complet e th e following summar

y o f hazardou s ai

r emission s fromthi s unit . Attac hsampl e calculation s an

demission .omar y facto r references . Attached ? /yS C S&f e - -- - ••':"- - IfclntanrCAS . ..^j ? 

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# •ED "P.2 3 

# jy MATERIA L SAFET Y DAT ASHEE T Pag e i FO RGELCOATS , RESINS , AN D RELATE

D MATERIALS /

tVlfrrph are d by
- B K o f Preparation
- 01-25-9 5 facturer i NEST E POLYESTE R es s : 510 6 Wheele r Ave .

For t Smith , A

R 7290 1 ,-> /



### For : 

## S /«LDIN G / ¥ CUSTO M FIBERGLAS S E588 0 LITTLE;RIVE R R D L 

### WEYAUWEG AW I 5498 3 

# 70-?$- ' iphon e No . : (501 ) 646-786 5 CHEMTRE C (800 ) 424-930 0 

### U SECTIO N I PRODUC T IDENTIFICATIO N ifacturer' s Cod e Identification : luc t Class : l e Name : .'817^JHITE|B||pg3a ^ ! Information : Health
- 2

Reactivity
- 1 WG-3079 9 Revisio n 1 2 Flammability
- 3 Persona l Protectiv e Equipment
- I ;t yGlasses , Gloves , & Combinatio n Dus t and Vapo r Respirato r

SECTIO NI I HAZARDOU S INGREDIENT S 1ATERIA L STYREN E J Y WT : CAS # 100-42- 5

34.4 8 )SUR E LIMIT : ACGI H TLV/TW A OSH APE L TLV-STE L S R LIMITS : * C 2 B 5 0 PP M 5 0 PP M 10 0 PP M

It************************************************************** * ****** * A 

### Thi s produc t contain s on e o r mor e reporte d carcinogen s o r suspecte d i-inogen s whic h ar e note d NTP , IARC , o r OSHA- Z i n th e othe r limit s Dmmende d column . k **************** * * * * * * * * * ************************************* * A - * - A * * -A - A Afc*********************************************************************** 

### Thi s produc t contain s pigment s whic h ma ybecom e a dus t nuisanc e whe n _>ve d byabrasiv e blasting , sanding , o r grinding . *********************************************************************** * 

### SECTIO NII I PHYSICA L DAT A lin g Range : High
- 295. 0 F o r Pressure : 4.3 0 MMH G @6 8 o r Density : Heavie r Tha n Ai r poratio n Rate : Slowe r tha n Ethe r gh t pe r Gallon : 11.0 5 : .01 0 sica l State : LIQUI D earance : WHIT E Low - 295. 0P.2 4

********************************************************************** * 

### NEST E POLYESTE R -3079 9 MATERIA L SAFET Y DAT ASHEE T Pag e 2 81 7 WHIT E GE L COA T ********************************************************************** * 

### : AROMATI C r Solubility : INSOLUBL E umber : 186 6 RESI NSOLUTION , FLAMMABL E

•SECTIO NI V

FIR E AN D EXPLOSIO NHAZAR D DAT A Flammabilit yClassification : Clas s I C DOT : Flammabl e Liqui d a l Flashpoin t TCC : 89. 0 F osio n Level : Lower - 1. 1 Upper - 6. 1 ^ter strea mca n scatte r flames . Aspra yo f wate r ma yb e use d t o coo l :-expose d containers . NGUISHIN G MEDI A Foam , C02 , Dr yChemical , Wate r Fo g ; fighter s shoul d us e self-containe d breathin g apparatu s wit h ful l ipiece . IUA L FIR E AN D EXPLOSIO NHAZARD : > container s tightl yclosed . Isolat e fro mheat , electrica l equipment , *ks , an d ope n flame . Vapor s ma yb e heavie r tha n ai r an d ma ytrave l t g th e groun d befor e ignition/flashin g bac k t o vapo r source . Kee p lin g o r cuttin g equipmen t awa yfro mproduct .

SECTIO NV

HEALT H HAZAR D DAT A CCT S O F EXCESSIV E OVEREXPOSUR E _rt s hav e associate d repeate d an d prolonge d occupationa l overexposur e t o /ent s wit h permanen t brai n an d nervou s syste mdamage . Intentiona l ls e bydeliberatel yconcentratin g an d inhalin g th e content s ma yb e nfu l o r fatal . D o no t breath e vapor s o r spra ymist . Wea r a n appro ite , properl yfitte d respirato r (NIOSH/MSH Aapproved ) durin g an d afte r Licatio n unles s ai r monitorin g demonstrate s vapor/mis t level s ar e belo w Licabl e limits . Follo wrespirato r manufacturer' s direction s fo r pirato r use . Dr s o f thi s produc t ma ycaus e irritatio n o f th e eyes , nose , throat , j r respirator ytract , mucou s membranes , an d skin . 3 T AI D CONTACT : Flus h wit h luk e war mwate r fo r 1 5 minutes . See k physicia n sdiately . M CONTACT : Flus h was h wit h copiou s amount s o f luk e war mwater . Remov e taminate d clothin g promptly . Was h thoroughl ywit h soa p an d water . ELATION : Remov e expose d individia l t o fres h air . Restor e breathin g required . Contac t a physicia n immediately . ESTION : Rins e mout h immediately . Giv e expose d individua l 6 t o 8 ounce s liquid . (Neve r giv e anythin g b ymout h t o a n unconsciou s person. ) D o induc e vomitin g unles s advise d b ya physician . Contac t a physicia n sdiately . Internationa l Agenc yfo r Researc h o n Cance r (IARC ) ha s classifie d ren e a s a possibl e huma n carcinoge n (clas s 2B) . Th e IAR C 2 B ssificatio n i s no t base d o n significan t ne wevidenc e that-styren e migh t a carcinogen , bu t o n a revise d IAR C classificatio n schem e an d ne wdat a styren e oxide .P.2 5

v **************************************************** * * A : * A - * * * * AAA

- AAAA

- AA 

### NEST E POLYESTE R -3079 9 MATERIA L SAFET Y DAT ASHEE T Pag e 3 81 7 WHIT E GE L COA T fcA***************************************************************AAAA*A 

### SECTIO NV I REACTIVIT Y DAT A ITION S T O AVOI D d exposur e t o sparks , ope n flame ; ho t surfaces , and al l source s n f hea t ignition . UC T STABILITY : Stable ; hazardou s decompositio n no t expected ; thi-inna ! impositio n ma yproduc e toxi c oxide s o f carbo n and/o r nitrogen . MPATIBILIT Y (Material s t o Avoid ) produc t i s incompatibl e wit h stron g acids , peroxides , an d othe r izin g agents , organi c meta l soaps .

SECTIO NVI I SPIL L O R LEA K PROCEDURE S S T O B E TAKE NI NCAS E MATERIA L I S RELEASE D O R SPILLE D upwin d an d awa yfro mspil l unles s wearin g appropriat e protective . pment . Sto p and/o r contai n discharg e i f i t ma yb e don e safely . Kee p source s o f ignitio n away . Ventilat e are a o f spill . Us e non-sparkin g s fo r cleanup . Cove r wit h iner t materia l t o reduc e fumes . Kee p ou t o f ns , sewers , o r waterways . Contac t fir e authorities . Notif yloca l t h an d pollutio n contro l agencies . Cal l spil l respons e team s i f larg e 1 . " E DISPOSA L METHO D O T FLUS H T O SEWER , WATERSHED , O R WATERWAY . >os e o f i n accordanc e wit h local , stat e an d federa l regulations . D o no t nerat e close d containers .

SECTIO NVII I SAF E HANDLIN G AN D US E INFORMATIO N

• I LA T IO N ventilatio n a s require d t o contro l vapo r concentrations . Avoi d .onge d o r repeate d breathin g o f vapors . I f exposur e exceed s TLV , ua e a _H-approve d respirato r t o preven t overexposure . ACTIV E GLOVE S lire d fo r prolonge d o r repeate d contact . Wea r resistan t glove s suc h a s ira l rubber , neoprene , bun a No r nitrile . A n apro n shoul d b e wor n t o I d ski n contact . 'IRATOR Y PROTECTIO N outdoo r o r ope n area s us e (NIOSH/MSH Aapproved ) mechanica l filte r >irato r t o remov e soli d airborn e particle s o f overspra ydurin g a yapplication . I n restricte d ventilatio n area s us e (NIOSH/MSHA roved ) chemical-mechanica l filter s designe d t o remov e a combinatio n o f ciiculat e an d ga s an d vapor . I n confine d area s us e (NIOSH/MSHAapproved ) lin e typ e respirator s o r hoods . Respirator yprotectio n ma yals o b e __ssar yi n anylate r manufacturin g operation s i n whic h th e produc t ma y -.m e airborn e i n th e for mo f vapo r o r dust .

SECTIO NI X SPECIA L PRECAUTION S DLING AN D STORAGE : Us e i n accordanc e wit h goo d industria l workplac e ctices ; avoi d unnecessar ycontact ; was h thoroughl yafte r handling ; stor e a dr yare a awa yfor mexcessiv e heat . E R PRECAUTIONS : Fo r industria l us e only .P.2 6

AA***************************************************** * AAAA AAAAAAA AAAA 

### NEST E POLYESTE R -3079 9 MATERIA L SAFET Y DAT ASHEE T Pag e H 81 7 WHIT E GE L COA T A************************************************************ * AAAAA A AAA 

### onne l shoul d avoi d inhalatio n o f vapors . Persona l contac t wit h th e uc t shoul d b e avoided . Shoul d contac t b e made , remov e saturate d hin g an d flus h affecte d ski n area s wit h water . Container s o f thi s ria l ma yb e hazardou s whe n emptied . Sinc e emptie d container s :••- • *•.••

_i; ; uc t residue s (vapor , liquid , and/o r solid) , al l hazar d pr-f.rau r i •;!..•• : n i n thi s shee t mus t b e observed . * 

### C E - Report s hav e associate d repeate d an d prolonge d occupationa l exposur e t o solvent s wit h permanen t brai n and nervou s syste mdamage , ntiona l misus e b ydeliberatel yconcentratin g an d inhalin g th e content s b e harmfu l o r fatal . SECTIO NI X (B ) DO T INFORMATIO N imabl e Liqui d 3 Packin g Grou p II I

SECTIO NX Sectio n 31 3 Toxi c Chemical s ; produc t contain s th e followin g toxi c chemical s subjec t t o th e irting requirement s o f sectio n 31 3 o f th e Emergenc yPlannin g an d tunityRight-To-Kno wAc t o f 198 6 an d o f 4 0 CF R 372 : rica l CA S Numbe r Weigh t % (EN E 100-42- 5 V . .•.;" .
TH E INFORMATIO NCONTAINE D HEREI NI S INFORMATIO NRECEIVE D FRO M OU R RA W MATERIA L SUPPLIER S AN D OTHE R SOURCE S AN D I S BELIEVE D T O B E RELIABLE . THI S DAT AI S NO T T O B E TAKE N A S AWARRANT Y O R REPRESENTATIO NFO R WHIC H NEST E POLYESTE R ASSUME S LEGA L RESPONSIBILIT YP.2 7



### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 - CHEMICA L PRODUC T AN D COMPAN Y IDENTIFICATION El f Atochetn Nort h Americ a Custome r Service : 200 0 Marke t Stree t 1-800-55B-557 5 Busin,-3 3 Hour s Philadelphia , P A1910 3 Information : 1-800-558-557 5 Busines s Hour s EMERGENC Y TELEPHON E NUMBERS : CHEMTREC : (800 ) 424-930 0 (2 4 hours ) o r (202 ) 483-761 6 MEDICAL : Rock

yMountai n Poiso n Contro l Cente r (303 ) 623-571 6 (2 4 hours ) NAM E USE D O NLABEL : LUPERSO L DDM- 9 CHEMICAL NAME : Methylethy l keton e peroxid e blend CHEMICAL FAMILY : Organi c Peroxid e - Keton e Peroxid e PRODUC T USE : Polymerizatio n initiato r

Sectio n 2 - COMPOSITION/INFORMATIONO NINGREDIENT S Typica l OSHA Identit yCA S No . % Hazar d 2,2,4-Trimethyl-l,3-pentane
- 6846-50- 0 23. 8 N dio l diisobutyrat e Dimethy l phthalat e 131-11- 3 32. 0 Y Methylethy l keton e peroxide s 1338-23- 4 35. 0 Y Hexylen e glyco l 107-41- 5 6. 0 Y Hydroge n peroxid e 7722-84- 1 3. 7 Y Methy l ethy l keton e 78-93- 3 1. 0 Y Wate r 7732-18- 5 1. 5 N. TSC AInventor yStatus : Thi s produc t i s TSC Acompliant . Th e component s ar e eithe r o n th e TSC A inventoryo r ar e exemp t a s impurities . Th e substance(s ) marke d wit h a Y i n th e OSH AHazar d colum

n above , ar e thos e identifie d a s hazardou s chemical s unde r th e criteri a o f chs : OSH A Hazar d Communicatio n Standar d (2 9 CFR 1910.1200) . Sectio n 3 - HAZARD S IDENTIFICApJpE X 0hHht 

### * ,dby 

### IU M mwvncM-cnufrWr EMERGENC

Y OVERVIEW

: ff^TT^V SXTSffi^'eA v 

### Clea roil y liquid , ketone - odo rSSSSJtSlcJ J 61 . Pau l M N Gennantown , (1512)645-94 ! (414)253-66.! 3 FA

X


### MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 of . 1 3 EL F ATOCHE M NORT H AMERICA , INC .P.2 8



### MATERIAL SAFET Y DATASHEE T Sectio n 3 - HAZARD S IDENTIFICATION DANGER ! ORGANI C PEROXID E CAUSE S EY E BURN S MA Y CAUS E BLINDNES S MA Y CAUS E SKI NIRRITATION MA Y CAUS E ALLERGI C SKI NREACTION HARMFU L I F SWALLOWE D POTENTIAL HEALT H EFFECTS : Ski n contac t an d inhalatio n ar e expecte d t o b e the primar yroute s o f exposur e t o Luperso l DDM-9 . Base d o n it s composition , Lupeiso l DDM- 9 i s anticipate d t o b e moderatel ytoxi c i f swallowed , slightl ytoxi c i f absorbe d throug h skin , practicall ynon-toxi c i f inhaled , moderatel y irritatin g t o ski n an d corrosiv e t o eyes . Prolonge d o r repeate d contac t ma ycaus e a n allergi c ski n reaction . Overexposur e t c vapo r ma ylea d t o digestiv e disorders , narcosi s an d centra l nervou£ 3 syste m (CNS ) effect s suc h a s headache , dizziness , los s o f coordination , los s o f consciousnes s o r convulsions . I f swallowed , Luperso l DDM-S " ma y caus e CN S effect s a s note d above , irritatio n o f 'th e mouth , throa t an d stomac h and , i n sever e cases , death .

Sectio n 4 - FIRS T AI D MEASURE S
I F I NEYES : Immediatel yflus h wit h plent yo f wate r fo r a t leas t 1 5 minut5 £ . Ge t medica l attentio n immediately . I F O NSKIN : Immediatel ywas h wit h soap and plent yo f water . Remov e contaminate d clothin g and shoes . Ge t medica l attentio n i f symptom s occur . Was h clothin g befor e reuse . Destro ycontaminat d shoes . Thoroughl yclea n shoe s befor e reuse . I F SWALLOWED : Induc e vomitin g immediatel ya s directe d b ymedica l personnel . Ge t medica l attention . Contac t a Poiso n Contro l Center . NEVE R GIV E ANYTHING B Y MOUT H T O A NUNCONSCIOU S PERSON . I F INHALED : Remov e t o fres h air . 

# Z l

Sectio n 5 - FIR E FIGHTIN G MEASURE S 

### Flas h Poin t (Tes t Method) : 58» C / 137° F (CC ) Autoignitio n Temperature : N E
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 2 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

# ZCo.P.2 9



### MATERIA L SAFET Y DAT ASHEE T Sectio n 5 - FIR E FIGHTIN G MEASURE S Flammabl e Limits : Upper : N E Lower : N E EXTINGUISHING MEDIA : Wate r fog , wate r spray , drychemical , foa m SPECIAL FIR E FIGHTING PROCEDURES : Fir e fighter s an d other s wh o ma yb e expose d t o products , o f combustio n shoul d wea r ful l fir e fightin g tur n ou t gear , (ful l Bunke r Gear ) and self-containe d breathin g apparatu s (pressure-deman d NIOS H approve d o r equivalent) . Fir e fightin g equipmen t shoul d b e thoroughl y decontaminate d afte r use . I f a larg e amoun t i s involved , evacuat e are a an d figh t fir e froma saf e distance . D o no t us e a soli d strea mo f water . Asoli d streamo f wate r ca n sprea d fire . Us e wate r spra yt o dispers e an yflammaol e mist s an d vapor s whic h hav e no t ignited . FIR E AN D EXPLOSIO NHAZARDS : 4 

### Contac t wit h incompatibl e material s o r exposur e t o temperature s exceedin g SAD T (Sectio n 9 ) ma yresul t i n a sel f acceleratinc i decompositio n reactio n wit h releas e o f flammabl e vapor s whic h vna y autoignite . Sectio n 6 - ACCIDENTAL RELEAS E MEASURE S
I F ASPIL L O R LEA K OCCURS : Us e inert , noncombustibl e absorben t material . Swee p c r scoo p u p usin g non-sparkin g tool s and remove .

Sectio n 7 - HANDLIN G & STORAG E HANDLING : D o no t ge t i n eyes , o n skin.o r o n clothing . D o no t tast e o r swallow . Avoi d breathin g vapo r o r mist . Was h thoroughl yafte r handling . Us e onl ywit h adequat e ventilation . Contac t wit h incompatibl e material s o r exposur e t o temperature. . exceedin g SAD T (Se e Sectio n 9 ) ma yresul t i n a sel f acceleratin g decompositio n reactio n wit h releas e o f flammabl e vapor s whic h na y autoignite . Kee p awayfromhea t spark s an d flame . Avoi d contamination . MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 3 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DAT ASHEE T Sectio n 7 - HANDLING & STORAG E Us e explosio n proo f equipment . Kee p containe r closed . STORAGE : Stor e belo w100°F(38°C ) t o maintai n activ e oxyge n content . Detache d storag e i s preferred . Avoi d excessiv e hea t an d stor e ou t o f direc t sunligh t i n a -icol well-ventilate d place . Stor e awa yfro m

combustible s an d incompatibl e materials . Sectio n 8 - EXPOSUR E CONTROL S & PERSONA L PROTECTIO N
ENGINEERING CONTROLS : Investigat e engineerin g technicjue s t o reduc e exposure s belov / airborn e exposur e limits . Provid e ventilatio n i f necessar yt o contro l exposur e level s belo wairborn e exposur e limits . Dilutio n ventilatio n acceptable , bu t loca l mechanica l exhaus t ventilatio n preferred , i f practical , a t source s o f ai r contaminatio n suc h a s ope n proces s equipment . Consul t ACGI H ventilatio n manua l o r NFP AStandar d 9 1 fo r desig n o f exhaus t systems . EY E PROTECTION : Wher e ther e i s potentia l fo r ey e contact , wea r chemica l gogcle s and hav e ey e flushin g equipmen t immediatel yavailable . SKI NPROTECTION : Wea r appropriat e chemica l resistan t protectiv e clothin g and chemica l resistan t glove s t o preven t ski n contact . Latex , nitrile , r.eoprene, . PV C o r othe r impermeabl e glove s shoul d b e wor n whe n handling thi s material . Wea r fac e shiel d and chemica l resistan t clothin g suc h a s a rubbe r apro n wher e splashin g ma yoccur . Rins e contaminate d ski n promptly . Was h contaminate d clothin g and clea n protectiv e equipmen t befor e reuse . Was h ski n thoroughl yafte r handling . RESPIRATOR Y PROTECTION : Avoi d breathin g vapor s o r mists . Us e NIOS H approve d ful l fac e organi c vapo r an d mis t respirato r whe n airbor n exposur e limit s ar e exceeded . I f used , ful l facepiec e replace s nee d fo r chemica l goggle s c r fac e shield . Consul t respirato r manufacture r i f exposur e limit s ar e greate r tha n te n time s th e th e recommende d exposur e limits . Observ e respirato r us e limitation s specifie d b yNIOS H o r th e manufacturer . Fo r emergenc yan

d othe r condition s wher e exposur e limi t ma ybv significantl yexceeded , use . a n approve d ful l fac e positive-pressur e self-containe d breathin g apparatu s o r positive-pressur e airlin e wit h auxiliar yself-containe d ai r supply . Respirator yprotectio n program s mus t compl ywit h 2 9 CF R 1910.134 . MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 4 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

# Z BP.3 1



### MATERIA L SAFET Y DAT ASHEE T Sectio n 8 - EXPOSUR E CONTROL S & AIRBORN E EXPOSUR E GUIDELINE S OSHAPE L TW ASTE L 2,2,4-Trimethyl-l,3-pen t N E N E Dimethy l phthalat e 5 mg/m 3 N E I 

### CEILIN G PERSONAL

TW A ane-dio l diisobutyrat e N E N E Methylethy l keton e peroxide s N E N E Hexylen e glyco l N E N E Hydroge n peroxid e 1 pp mN E Methy l ethy l keton e 20 0 ppm30 0 pp m Wate r N E N E

Sectio n 9 - Boilin g Point , C : Freezin g Point , C : Specifi c Gravity : Vapo r Pressur e @ 2 0 C : Vapo r Density : air*= l Evaporatio n Rate : Buty l acetate= l % Volatiles : Solubilit yi n Water : 0. 7 ppm 2 5 pp m N E N E N E N E

5mg/m 3 N E N E 1 pp m 20 0 ppm N E PROTECTION

ACGI H TLV STZ L N E N E 0. 2 ppm 2 5 ppm N E 30 0 ppm i 

### NE PHYSICAL & CHEMICA L DATA N E belo w-30° C 1.084 0 min . 4.8mraHg®68 F N E N E N E Sligh t CEILING M E NE : 

### 0 . 2 pp m 2 5 pp m STE ; M E 

### NE

Appearanc e and Odor : Clea r oil yliquid , keton e odo r SAD T = 70° C - 4 5 lbs . i n a 5 gallo n container . SAD T - Sel f Acceleratin g Decompositio n Temperature . Lowes t temperatur e a t whic h th e teste d packag e siz e wil l underg o a s e acceleratin g decompositio n reaction . Thi s reactio n wil l gene i flammabl e vapor s whic h mayautoignite . Th e lengt h o f tim e t o a decompositio n reaction , afte r the SAD T ha s bee n reache d o r e i s dependen t upo n ho wmuc h the SAD T ha s bee n exceede d an d th e o f time neede d fo r th e reactio n exotherm(hea t spik e fro minc i decompositio n rate ) t o initiat e a rapi d decompositio n reactio r Typically , SAD T i s inversel yproportiona l t o packag e size . L c package s wil l hav e a lowe r SAD T du e t o a smalle r rati o o f hea t 1: : at e generat e xceeded , lengt h easin g rge r

MSD S CODE : 12900 0 PRODUCT : LUPERSO L DDM- 9 EL F ATOCHE M NORT H AMERICA , Date : Page : INC . 31/06/9 7 5 O f 1 3 

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### MATERIA L SAFET Y DATASHEE T Sectio n 9 - PHYSICAL t CHEMICA L DAT A transfe r re a t o volum e o f produc t

Sectio n 1 0 - STABILIT Y & REACTIVIT Y
STABILITY : Thi s materia l i s chemicall yunstabl e an d shoul d onl yb e hanile d unde r specifie d conditions . Se e HANDLING AND STORAG E sectio n o f :hi s MSD S fo r specifie d conditions . INCOMPATABILITY : Contaminatio n wit h foreig n material s suc h a s stron g acids , .stron g alkalis , stron g oxidizers , transitio n meta l salts , reactio n accelerators/promoter s o r reducin g agent s ma yresul t i n a sel f acceleratin g decompostio n reaction . Rust , coppe r and bras s ar e no t compatibl e wit h ME K peroxid e 31 6 stainles s steel , glass , polyethylene , polytetrafluoroethylen e an d polypropylen e ar e preferre d material s fo r contac t wit h ME K peroxide . Aceton e ma yreac t wit h residua l hydroge n peroxid e t o for minsolubl e shock-sensitiv e diacety l peroxid e crystals . HAZARDOU S DECOMPOSITIO NPRODUCTS : Decompositio n product s ar e flammable . HAZARDOU S POLYMERIZATION : Doe s no t occur .

Sectio n 1 1 - TOXICOLOGICA L INFORMATION El f Atoche m

Nort h America , Inc . ha s no t conducte d toxicit ystudie s o n Luperso l DDM-9 , and n o informatio n o n thi s o r simila r mixture' s wa s found i n a searc h o f th e scientifi c literature . However , the component s o f thi s materia l hav e bee n teste d and th e dat a ar e summarize d below . METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : Following a n allergi c ski n reactio n i n a pain t sprayer , patc h testin g produce d a n allergi c ski n reactio n wit h MEK P a s wel l a s othe r component s o f th e paint . However , subsequen t patc h tc:stin g di d no t produc e allergi c ski n reaction s i n 3 4 health ysubjects . Swallowin g o f MEK P wa s reporte d t o caus e live r injuryi n on e cas e report . Singl e exposur e (acute ) studie s o n 40-60 V MEK P i n dimethy l phthalat e indicat e tha t i t i s moderatel ytoxi c t o rat s i f swallowe d (LD5 0 4 8 4 mg/kg) , slightl ytoxi c t o rabbit s i f absorbe d through ski n (LD5 0
MSD S CODE : 12900 0 PRODUCT : LUPERSO L DDM- 9 EL F ATOCHE M NORT H AMERICA , INC . Date : Cl/06/9 7 Page : 6 o f 1 3 

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### MATERIAL SAFET Y DATASHEE T Sectio n 1 1 - TOXICOLOGICAL INFORMATION 4,00 0 mg/kg) , practicall ynon-toxi c t o rat s i f inhale d (4-h r LC5 0 17-5 0 mg/l), . corrosiv e t o rabbi t eye s and moderatel yirritatin g c o rabbi t ski n (4-h

r exposure , 4.5/8.0) . Repeate d ora l admir.istracio n o f MEK P wa s reporte d t o resul t i n decrease d bodyweight , mil d live r an d kidne yinjur yand deat h i n rats . Followin g repeate d applicatio n o f MEK P i n dimethy l phthalat e t o th e ski n o f rat s and mice . sever e ski n damag e and anima l death s (onl ya t th e highes t dos e levels ) wer e the primar yeffects . Splee n an d bon e marro wchange s considere d secondar yt o th e sever e ski n damag e wer e note d i n animal s a t the high doses . Highe r dose s applie d t o ra t and mous e ski n fc r a shorte r tim e produce d simila r effects . Long-termrepeate d ski n applicatio n o f MEK P i n dimethy l phthalat e wa s reporte d t o enhanc e ski n tumo r productio n i n mic e irradiate d wit h UVB . MEK P ha s produce d geneti c change s i n standar d test s usin g bacteria l o r anima l cells . However , n o geneti c change s occurre d i n a standar d tes t using animals . 2,2,4-TRIMETHYL-l,3-PENTANEDIO L DIISOBUTYRATE : Acut e studie s indicat e tha t 2,2,4-trimethyl-l,»3-pentanedic l diisobutyrat e i s n o mor e tha n slightl ytoxi c t o rat s i f swallowe d (LD5 0 >3,20 0 mg/kg) , practicall ynon-toxi c t o guine a pig s al " absorbe d throug h ski n (LDSO >2 0 ml/kg ) , practicall ynon-tc:c:. c t o rat s i f inhale d (6-h r LC5 0 >5. 3 mg/l) , slightl yirritatin g t o rabbi t eye s and slightl yirritatin g t o guine a pi g skin . N o ski n allergy wa s observe d i n guine a pig s followin g repeate d exposure s t o 2,2,4-trimethyl-l,3-pentanedio l diisobutyrat e i n controlle d ski n contac t studies . Increase d live r weights , whic h wer e probabl y adaptiv e change s du e t o th e inductio n o f dru g metabolizin g enzyme s i n thes e tissues , wer e observe d i n rat s o r dog s fe d 2,2,4-trimethyl-l,3-pentanedio l diisobutyrat e (u p t o 1% ) i n thei r fee d fo r u

p t o 10 3 days . 2,2,4-Trimethyl-l,3-pentanedio l diisobutyrat e i s eliminate d i n th e excret a o f rat s followinc
- a singl e ora l dos e wit h littl e o r n o retentio n i n th e tissues } o r organs . HEXYLEN E GLYCOL : Ski n applicatio n o f 50 % hexylen e glyco l i n wate r showe d onl yminima l irritatio n i n huma n volunteers , whil e repeate d applicatio n o f consume r product s containin g u p t o 1 % hexylen e glyco l di d no t sho w irritan t o r sensitizin g effect s i n humans . Patc h test s hav e show n sensitizatio n response s i n individual s workin g wit h cuttin g oil s containin g hexylen e glycol . Acut e studie s indicat e tha t hexylen e glyco l i s slightl ytox:. c t o rats , rabbits , mic e an d guine a pig s i f swallowe d (LD5 0 2,80C-4,70 0 mg/kg) , practicall ynon-toxi c t o rabbit s i f absorbe d throug h ski n (LD5 0 12,30 0 mg/kg) , severel yirritatin g t o rabbi t eye s an d moderatel yirritatin g t o rabbi t skin . N o death s occurre d :.r: . rat s expose d t o abou t 16 0 pp mhexylen e glyco l fo r 8-hours . Rat a an d rabbit s expose d t o hexylen e glyco l (0. 7 mg/l ) fo r 9 day s d:.c i no t
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 7 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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_P.34 _



### MATERIAL SAFET Y DATASHEE T 

# 1 Sectio n 1 1 - TOXICOLOGICAL INFORMATION sho wan yadvers e effects . Hexylen e glyco l i n th e die t a t u p t o 15 0 m g dail yfo r 4 month s produce d n o advers e effect s o n growth , behavio r o r fertilit yi n rats . Change s i n th e kidne ywer. i note d a t 2 0 0 mg/day . Hexylen e glyco l ha s no t produce d geneti c change s o r chromosoma l effect s i n standar d test s usin g bacteria l o r anima l cells . METHY L ETHY L KETON E (MEK) : Repeate d exposur e o f human s t o ME K controlle d ski n contact : studie s produce d n o ski n irritatio n o r ski n allergy . Centra l nervou s system (CNS ) effect s an

d periphera l neuropath yhav e bee n reporte d i n th e industria l settin g followin g exposur e t o mixture s containin g MEK * however , thes e mixture s containe d othe r solvent s known t o caus e nervou s syte m

injury . Acut e studie s indicat e tha t ME K i s n o mor e tha n slightl ytoxi c t o rat s i f swallowe d (LDSO 2,70 0 t o 5,60 0 mg/kg) , practicall ynon-toxi c t o rabbit s i f absorbe d throug h ski n (LDS O 5,00 0 t o 13,00 0 mg/kg ) o r rat s i f inhale d (4-h r LC5 0 11,70 0 ppm ) an d moderatel yirritatin g t o rabbi t eye s an d skin . Followin g repeate d inhalatio n exposure , sligh t change s i n orga n weight s and bloo d chemistr ywer e reporte d i n rat3 . N o evidenc e o f nervou s syste minjur yfollowin g lone-term inhalatio n exposur e t o ME K ha s bee n observe d 'i n rats , chickens , mic e o r cats . Anima l studie s hav e shown ME K t o increas e th e severit yof , o r shorte n th e onse t of , irreversibl e nervou s syste meffects ; du e t o n-hexan e an d methy l buty l ketone , a s wel l a s effect s o f chloroform and carbo n tetrachloride . ME K di d no t increas e th e incidenc e o f tumor s i n long-termski n applicatio n studie s i n mice . Asmal l numbe r o f majo r birt h defect s wer e reporte d i n rat s expose d t o ME K b yinhalatio n durin g pregnanc ya t a leve l (3,00 0 ppm ) whic h produce d toxi c effect s i n th e offspring , bu t no t i n th e mothers . However , n o birt h defect s wer e foun d i n a second repea t stud ywit h rat s using verysimila r exposur e conditions , whil e advers e effect s wer e note d i n th e mother s and thei r offspring . I n mic e expose d t o 300 0 ppmME K b yinhalatio n durin g pregnancy , toxi c effect s wer e observe d i n th e mother s (mil d effect s only ) and thei r offspring . ME K ha s generall y produce d n o geneti c change s i n standar d test s usin g animal s an d anima l o r bacteria l cells . Apositiv e respons e wa s reporte d i n on e assayusin g yeas t cells .

Sectio n 1 2 - ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION El f Atoche m

Nort h America , Inc . ha s no t conducte d ecologica l effec t studie s o n Luperso l DDM-9 , and n o informatio n o n thi s o r simila r mixture s wa s found i n a searc h o f th e scientifi c literature . However , the component s o f thi s materia l hav e bee n teste d an d :he dat a ar e
MSD S CODE : 12900 0 Date : C1/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 8 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIAL SAFET Y DATASHEE T Sectio n 1 2 - ECOLOGICAL INFORMATION summarize d below . ECOTOXICOLOGICA L INFORMATION : METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : MEK P i s slightl ytoxi c t o guppie s (96-hr LC5 0 44. 2 mg/l) . 2,2,4-TRIMETHYL-l,3-PENTANEDIO L DIISOBUTYRATE : 2,2,4-Trimethyl-l,3-pentanedio l diisobutyrat e i s n o mor e cha n moderatel ytoxi c t o mos t aquati c organism s o n a n acut e basi:; i wit h LC5 0 value s >1.5 5 mg/ l fo r th e fathea d minnow , ramshor n sr--.il , aquati c earthworm , sideswimmer , pil l bu g an d flatworm . I t :. s n o mor e tha n moderatel ytoxi c t o daphni d (EC5 0 >1.4 6 mg/l) . HEXYLEN E GLYCOL : Hexylen e glyco l ha s bee n reporte d t o b e practicall ynon-tox:. c t o a variet yo f aquati c organism s byacut e toxicit ytesting . Fre.shwate r fis h includin g rainbo wtrout , bluegil l sunfish , fathea d minnow , mosquit o fish , goldfis h and channe l catfis h ha d LC5 0 value s i n exces s o f 1,00 0 mg/ l and generall ywer e i n th e rang e o f B # 

### 00 0 t o 10,00 0 mg/l . Aquati c invertebrate s suc h a s Daphni a and crayfis h ha d EC5 0 value s greate r tha n 2,80 0 mg/l . METHY L ETHY L KETON E (MEK) : ME K i s practicall ynon-toxi c t o goldfish , brin e shrimp , Daphni a magna , fathea d minnow , mosquit o fish , bluegil l sunfis h and golde n orf e (LC50 s >1,00 0 mg/l) . ME K inhibit s funga l growt h an d i s reporte d t o b e bacteriostati c t o severa l microorganism s (Escherichi a coli , Salmonell a typhimurium , Staphylococcu s aureus , Leucor.osto c citrovoru

m an d Streptococcu s thermophilus ) a t level 3 o f 10-10 0 mg/l . Growt h inhibitio n ha s als o bee n reporte d fo r freshwate r al-ja. e a t level s rangin g fro m 12 0 mg/ l (blue-gree n algae ) t o 4,30 0 m:r/ l (gree n algae ) . CHEMICAL FAT E INFORMATION : METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : MEK P wa s reporte d t o b e readil ybiodegradabl e i n a close d nettl e system . A n EC5 0 o f 1 6 mg/ l wa s reporte d i n a n activate d sludg e respiratio n inhibitio n test . 2,2,4-TRIMETHYL-1, 3 -PENTANEDIO L DIISOBUTYRATE : I n a 28-da ymodifie d Stur m Test , 2,2,4-trimethyl-l , 3-penta.^edio l diisobutyrat e wa s found t o underg o 32-59 % degradatio n t o C02 . Th e bioconcentratio n facto r withou t metabolis mwa s estimate d tc - b e 67 0 an d wit h metabolis m

1-40 . Th e lo g Po wo f 2,2,4-trimethyl-1,3
- pentanedio l diisobutyrat e i s estimate d t o b e 4.1 . HEXYLEN E GLYCOL : Chemica l oxyge n deman d (COD ) and biologica l oxyge n deman d (30D ) indicate d tha t hexylen e glyco l i s readil ybiodegraded .
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 9 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 2 - ECOLOGICAL INFORMATION METHY L ETHY L KETON E (MEK) : Extensiv e dat a suggest s tha t ME K i s readil ybiodegradabl e I t i s non-toxi c t o sludg e microorganism s a t concentration s u p t o 30 0 ug/ l Sectio n 1 3 - DISPOSA L CONSIDERATION S Dispos e i n accordanc e wit h federal , stat e and loca l regulations . Dilutio n followe d b yincineratio n i s th e preferre d metRod . Dilutio n rati o o f 10: 1 i n a clean , compatible , combustibl e solven t (i.e . Fue l Oi l #2 , minera l oil ) wil l reduc e reactivit yhazar d durin g incineratio n an d transportation .

Sectio n 1 4 - TRANSPOR T INFORMATION DO T PROPE R SHIPPING NAME : Organi c Peroxid e Typ e D Liqui d TECHNICA L SHIPPING NAME : Methy l Ethy l Keton e Peroxide(s) , <45 % DO T HAZAR D CLASS : 5. 2 UNNUMBER : 310 5 PACKING GROUP : I I PRODUC T R Q (LBS) : Se e belo w Sectio n 1 5 - REGULATOR Y INFORMATION
SAR AHAZAR D CLASSIFICATIO N Immediat e (Acute ) Health : ye s Delaye d (Chronic ) Health : n o Sudde n Releas e o f Pressure : n o Reactive : ye s Fire : ye s SAR ATitl e III , Sectio n 302 : Thi s produc t doe s no t contai n an ychemical s currentl yo n the Extremel yHazardou s Substanc e List , Sectio n 302 , SAR ATitl e ..II , abov e th e OSHAd e minimi s concentration . SAR ATitl e III , Sectio n 313 : Thi s produc t contains : Dimethy l phthalat e 131-11- 3
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : I D o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DATASHEE T Sectio n 1 5 - REGULATOR Y INFORMATION Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Toxi c Chemica l List , Sectio n 313 , S.VR A Titl e III . CERCL AR Q Thi s produc t contains : Dimethy l phthalat e 131-11- 3 500 0 lbs . Methylethy l keton e peroxide s 1338-23- 4 1 0 lbs . Methy l ethy l keton e 78-93- 3 500 0 lbs . Californi a Propostio n 65 : Thi s produc t doe s no t contai n an ychemical s currentl yliste c o n the Californi a Lis t o f known Carcinogens . Californi a Propostio n 65 : » Thi s produc t doe s no t contai n an ychemical s currentl yliste d o n th e Californi a Lis t o f known Reproductiv e Toxins . Pennsylvani a Right-to-Kno w Hazardou s Substanc e Lis t Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Pennsylvani a Hazardou s Substanc e List . Pennsylvani a Right-to-Kno w Environmenta l Hazardou s Substanc e Lis t Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Pennsylvani a Environmenta l Hazardou s Substanc e List . MSD S CODE : 12900 0 Date : O.L/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 1 o t lJ EL F ATOCHE M NORT H AMERICA , INC .



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### MATERIA L SAFET Y DATASHEE T Sectio n 1 5 - REGULATORY INFORMATION Pennsylvani a Right-to-Know . Specia l Hazardou s Substanc e Lis t Thi s produc t doe s no t contai n anychemical s currentl yo n ;h e Pennsylvani a Specia l Hazardou s Substanc e List , abov e th e CSHA d e minimi s concentration . Massachusett s Right-to-Kno w Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 . , whic h ar e liste d o n th e Massachusett s Hazardou s Substanc e LLs t Ne wJerse yRight-to-Kno w Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 133B-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Ne wJerse yHazardou s Substanc e Lis* ;

Sectio n 1 6 - OTHE R
Legend N/ A- No t Applicabl e N E - No t Establishe d NJTS N- Ne wJerse yTrad e Secre t Numbe r Lupersol , Luperco , Luperox , Peroximo n and Retilo x ar e registere d trademark s o f El f Atochem , Nort h America , Inc . MSD S CODE : 12900 0 Date : C1/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 2 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DATASHEE T Sectio n 1 6 - OTHE R Issued : 01/06/9 7 Rev. 0 Supersedes : 07/12/9 5 El f Atoche mNort h America , Inc . believe s tha t th e informatio n and recommendation s containe d herei n (including dat a an d statement:*) ) ar e accurat e a s o f th e dat e thereof . N O WARRANT Y O F FITNES S 101 AN Y PARTICULA

R PURPOSE , WARRANT Y O F MERCHANTABILITY , OP . ANY OTHE R WARRANTY , EXPRES S O R IMPLIED , I S MAD E CONCERNIN G TH E INFORMATIONPROVIDE D HEREIN . Th e informatio n provide d herei n relate s t o th e specifi c produ c : . designate d an d ma yn o b e vali d wher e suc h produc t i s use d i n combinatio n wit h an yothe r material s o r i n an yprocess . Further , sinc e th e condition s an d method s o f us e o f th e produc t an d o f th e ir . forma t io n referre d t o herei n ar e beyon d th e cbntro l o f El f Atochem , El f Atoche m expressl ydisclaim s anyand al l liabilit ya s t o anyresult s obtaine d o r arisin g froman yus e o f th e produc t o r relianc e o n suc h information .

MSD S CODE : 12900 0 PRODUCT : LUPERSO L DDM- 9 EL F ATOCHE M NORT H AMERICA , INC . Date : 01/06/9 7 Page : lio f 1 3 

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### " E T Y D AT AS H E . E T COATINGS, . RESINS. . AN D RELATE D MATERIAL S •iUFACTURE D BY: : ' EMERGENC Y CONTACT: : CHEMTRE C >i h o r t e r. . T e <: : h n o I O G:i . es. , I n <::. . 

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### SECT'IO N !".: • i.. i v < : 

### HYSICA L DAT A OILIN G RANGE: : 277--41 0 p PE C I FI C GRAVIT Y 1. . 09 8 APO R DENSIT Y (AIR^l ) : : 21.98 2 OLATIL E ORGANI C CONTEN T (VOC): : PERCEN T VOLATIL E B Y VOL: : EVAPORATIO NRAT E (n-B u Ac:== : VAPO R PRESSUR E (m mHq<<!68F ) 40 6 qrams/lite r PPEARAMC E AN D ODOR ? ligh t stra wcolore d solutio n GLUBILIT Y I NWATER S neqliqibl e •tyren e SECTIO NIV . "IR E AN D EXPLOSIO NHAZAR D DAT A LAS H POINT: : 8 6 DEG. . F SETAFLAS H GSH ACLASSIFICATION : L.AMMABL E LIMIT S ";'. B Y VOLUM E I NAI R A T 21 2 DEG. . F: : LOWE R EXPLOSIO NLIMIT; : • 1 . . 1 0 UPPE R EXPLOSIO NLIMIT: : 7..0 0 XTINGUISHIN G MEDIA: ; Us e -foam. , carbo n dioxid e o r chemica l i : 

### :i . r e ,Tiqhtin a r-1
- 'P.4 7

EC T I O NIV. . IR E AN D EXPLOSIO NHAZAR D DAT A 73 2 721 6 (CONT. , }
Kee:: . container s tightl yclosed, , Isolat e fro mheat , electrica l equipment. , spark s an d ope n flame. . Close d container s ma ye x Diod e whe n expose d t o extrem e Ti e at, . ECIA L FIR E FIGHTIN G PROCEDURE S 'Th e us e o f self--co n taine d breathin g apparatu s i s recommende d fo r fir e fighters, . Wate r spra yma yb e use d fo r coolin g container s t o preven t possibl e pressur e build-u p an d auto ignitio n o r explosio n whe n expose d t o extrem e heat, . Avoi d spreadin g burnin g liqui d wit h wate r use d fo r cooling. . SECTIO NV . HEALT H HAZAR D DAT A iRESHOL D LIMI T VALUE: : Se e Sec:tio n II. . •ECT S O F OVEREXPOSURE: :

- EYE S CONTACT: ; Sever e irritation. , redness. , tearin g an d blurre d vision. . • SKI NCONTACT: : Prolonge d o r repeate d exposur e ca n caus e moderat e irritation. , defa11in q, , dermat i ti s an d sens:i . ti z atior.. . • INHALATION S Excessiv e inhalatio n o f vapor s ca n caus e nasa l an d respirator ) i i
- i' i tation. , -dizziness. , weakness. , fatigue, , nause a an d headache , Hig h concentration s ma yresul t i n narcosis, . (Centra l Nervou s Syst e _n d e p r e s s i on )
• INGESTION . Ca n caus e gastrointestina l irritation. , nausea. , vomitin g an d diarrhea, , Aspiratio n o f materia l int o lung s ca n caus e chemica l pneumoniti s whic h ca n b e fatal. . ironi c exposur e ma ycaus e damag e t o th e Centra l Nervou s System , ••jsoirator

ySystem, , Lungs. , Eyes, , S k:i . n . , Gastrointestina l Tract.. . i.ver, , Splee n an d Kidneys, , THE R HEALT H EFFECT'S: : vise d upo n a re-evaluatio n o f previous , negativ e an d equivoca l dat a "i d <->s\ increase d incidenc e o f lun g tumor s after ' ora l administratio n " i votin g adul t mice. , th e Internationa l Agenc yfo r Researc h o n yu"!ce r (IARC ) ha s liste d styren e amon g thos e material s 'fo r whic h her e :i.s limite d evidenc e fo r carcinogenicit yi n animals. .
: 'GENC Y AN D FIRS T AI D PROCEDURE S EYE S CONTACT: : Flus h wit h clean. , lukewar mwate r fo r a t leas t 1 5 minutes. , occasionall yliftin g th e eyelids. , Obtai n medica l attention, , SKI NCONTACT: : Remov e contaminate d clothing. . Was h affecte d ski n area s thoroughl ywit h soa p an d water. , Was h contaminate d clothin g thoroughl ybefor e re—use „ INHALATION: : 

# 4^> "*••• • - r .•'•' . > i i HEALT H HAZAR D DAT A

Remov e t, ::: , -fres h air, . Appl yartificia l respiratio n o r administe r oxygen , i f necessary, , Cal l a physicia n immediately, , INGESTION: : Kee p perso n warm, , quie t an d ge t immediat e medica l attention, . D o no t induc e vomiting, , becaus e aspiratio n 'o f materia l int o th e lung s 'fro

mvomitin g ca n caus e chemica l pneumoniti s which : ca n b e T a t a 1 „ .ECT I O N V I REACTIVIT YDAT A ABILITY ! Stabl e unde r norma l conditions. . Avoi d exposur e t o excess! 1 (COMPATIBILITY: : Avoi d contac t wit h stron g minera l acid s noiyfiler' x xatio n catalyst s . , Pt-. T I... . .1 . (. 1 <..:'-.::•

< \n d iZARDOU S POLYMERIZATION : Ca n Occur.
. iZARDOU S DECOMPOSITIO N PRODUCTS: : Therma l decompositio n ma yyiel d carbo n dioxid e and/o rmonoxide. , il..
. IFORNI ASCAQM D RUL E 443. , I s Thi s produc t contain s photochemicall yreactiv e volatil e ora < compoun d (s ) , . Refe rt o Sectio n I I an d
SECTIO NVII, , SPIL L O R LEA K PROCEDURE S "EP S T O B E TAKE NI NCAS E MATERIA L I S RELEASE D O R SPILLED : Evacuat e al l non-essentia l personnel, . Remov e al l source s o f ig n ition. . Ventilat e th e area. . Equi p employee s wit h appropriat e protectio n equipmen t (Se e Sectio n VIII), . Dik e aroun d so i 1 le d material. . Cove r spil l wit h iner t absorben t materia l an d shove ! wit h non-sparkin g tool s int o container, , Remov e container s t o a are a an d seal „
i •:: > i .':: . .i. ' .1 . -.: : nSPOSA L METHOD: : Wast e materia l mus t b e dispose d o f i n accordanc e withfedera ] state. , an d loca l environmenta l reuulator ycontrols. . SECTIO NVII I SPECIA L PROTECTIO NINFORMATIO N .PIRATOR Y PROTECT'ION; ; Avoi d breathin g vapor ' o r mist, . I f exposur e ma yo r doe s exe: . occupationa l exposur e limit s (SEC . IV ) us e a NIOS H —approve d !"• ! rato r t o preven t overexposure, , I n accor d wit h 29CF' R 1910 , us e eithe r a full—face, , atmosphere—supplyin g respirato r or ' a i r —purifyin g respirato r fo r organi c vapors, ,ECTIO NVIII . SPE C I Al.. . F'RO'TEC T I O NINFORI'IA

T I O N 73 2 721 6 (CON T „ )

NTILATIOH s Loca l exhaus t mus t b e sufficien t t o kee p airborn e vapo r c o n centr a t i o n s b e I o wt h e TI.. . V I i m i t „ E xhaus t a :i

. r ' ma ynee d cleane d b

yscrubber s o r filter s t o reduc e environmenta l co n taminatio n . . OTECTIV E GLOVES: : P o 1 yv:i . n y1 a I <: : o h o 1 g I o ve s „ E PROTECTION S S p 1 a s h g o g g 1 e s. . HE R PROTECTIV E EQUIPMENT s F'olyviny l alcoho l apron, , Ey e bat h an d safet yshower, , T o repeate d o r prolonge d ski n contact, , wea r imperviou s clot l boots. . .ZARDOU S MATERIAL S IDENTIFICATIO NSYSTEM s Se e firs t pag e o f MSDS. . preven t rin o *no

SECTIO NIX . SPE C I Al.. . PRECAU T ION S ^CAUTION S T O B E TAKE NI NHANDL.ING AH D STORING: : Drums: : Protec t agains t physica l damage. . Outsid e o r detache d

storag e preferred, , Bulk: : Storag e shoul d b e i n standar d flammabl e ligui d storag e tanks. , •IE R PRECAUTIONS: : Al l equipmen t shoul d b e grounde d an d bonde d t o reduc e eiect r i cit yha>:•:ar d „ Us e non••• • spa r kin g tooI s „ stati c Overexposur e t o materia l ha s apparentl ybee n foun d t o caus e followin g effect s i.n laborator yanimals: : live r abnormalitie s kidne ydamaqe. , I unc i cl a m a cie. . th .
RECENT ' DAT ADOE S NOT ' SUPPOR T TH E CHANG E I NTH E CLASSIFICATIO N B Y I ARC : O F STYREN E T O B E ASUSPECTE D CARCINOGEN. , A t th e conclusio n o f a majo r notic e an d commen t rulemakin g revisin g it s ai r contaminant s regu lations, , OSH Aconclude d tha t th e "curren t evidenc e o n styrene' s carcinogenicit ydoe s no t suppor t it s classificatio n i n th e fina l rul e a s a carcinogen „ 1989 ) : ; se e als o F e .e q„ 43 0 (Jan. , 19 , 5 4 Feci, . Re q„ a t 2364, , I n t h sam e rulemaking. , th e Nationa l Institut e fo r Occupationa l Safet yan d Healt h (NIOSH ) com mente d tha t ther e "seem s t o b e littl e basi s



# 4frSPECIAL . PRECAUTION S P.5 0

fro mth e experimenta l anima l investigation s o r ep:i.demiC J 1 og i c stuc l ie s t o co n c 1 tide ' a t thi s tim e tha t styren e i s carcinogenic, " Moreover'. , othe r scientist s hav e independentl yconclude d tha t styren e doe s no t presen t a carcinogeni c ris k t o humans. . I „ C „ llunro, , e t a l . , " ARevie wo f Styren e Pbarmacokinetic s anc l Carcino a enicit.y " ( J u I y21 , :! . 98 9 ) (Ca n "T o x I n c „ Drinkin g Wate r Docke t No, , I J 2. . S 6 „ Att a c h me n t C ) - D. , Docume n t 1 1

OTHE R COMMENT ; recommen d tha t container s b e eithe r professionall yreconditione d i- " reus e b

ycertifie d firm s o r properl ydispose d o f b ycertifie d rm s t o hel p reduc e th e possibilit yer f a n accident, , Disposa l o f n tai n er s shoul d b e i n accordanc e wit h app l i cabl e federal, , s'h'- e ...-. ; ca l law s an d regulations . "Empty " drum s shoul d no t b e give n t o d l vidu a Is. . e informatio n i n thi s MSD S wa s obtaine d fro msource s whic h w e iiev e ar e reliable, , However , th e informatio n i s provide d withou t yrepresentatio n o r warranty. , expresse d o r implied, , regardin g it i curac yo r completeness. , e condition s o f handling, , storage,, ' us e an d disposa l o f th e pro d e beyon d ou r contro l an d ma yb e beyon d ou r knowledge-?. . Fo r thi s he r reasons, , w e dc ? no t assum e responsibilit yan d expressl ydis c abilit yfo r loss, , damag e o r expens e arisin g ou t o f o r i n an ywa . nnecte d wit h th e handling , storage, , us e o r disposa l i e produc t



# 4 :P.5 1

E N - V I R 0 NM E l-

l T AI.. . D AT AS H E E " T ;i..K'K;K* : MUS T NO T B E DETACHE D FRO M MATERIA L SAFET Y DAT ASHEE T ')<?.<:**:>! < of c I F MSD S I S COPIE D AN D REDISTRIBUTED , THI S NOTIC E MUS T B E ATTACHE D ***( < iNUFACTURE D BY: : McWhorte r Technologie s DAT E O F LAS T CHANGE: : 94/02/1 9 40 0 Eas t Cottag e Plac e Carpentersville. , I I 6011 0 .ODUC T NAME: : 73 2 721 6 -.ODUC T CLASS: : UNSATURATE D POLYESTE R RESI N SECTIO NI . . PRODUC T IDENTIFICATION/COMPOSITIO N ".O D COMPONEN T CA S NUMBE R PERCEN T P UNSATURATE D POLYESTE R RESI N MIXTUR E 10 0

TYPICA L DISTRIBUTIO NO F HAZARDOU S COMPONENTS STYREN E
I O'".--.:: t '•'•''••••' . SECTIO NII . SAR ATITL E II I INFORMATIO N W D EH S R O (LBS ) EH S TPO . (LBS ) SE C 31 3 311/31 2 CATEGORIE S

(*1 ) (*2 ) (#3 ) (*4 ) P 53,02 4 1 3 4 5 1 YE S 1 3 4 5 7 - -—FOOTNOTE S •-•-•• - ! . ••• = REPORTABL E QUANTIT Y OF ' EXTREMEL Y HAZARDOU S SUBSTANCE. , SAR ASE C ..302/30 4 Z -• THRESHOL D PLANNIN G QUANTITY, , EXTREMEL Y HAZARDOUS . SUBSTANCE, , SAR ASE C „ 30 2 3 = = TOXI C CHEMICAL, , SAR ASE C 31 3 •' . » HAZAR D CATEGOR Y FO R SAR ASEC . 311/31 2 REPORTIN G 1 ••••••• FIR E HAZAR D 2 *** • SUDDE NRELEAS E O F PRESSUR E HAZAR D 3 ••••••• REACTIV E HAZAR D 4 » • IMMEDIAT E (ACUTE ) HEALT H HAZAR D 5 • - DELAYE D (CHRONIC ) HEALT H HAZAR D SECTIO NIII „ DOT/CERCL AINFORMATIO N •I E CERCL AREPORTABL E QUANTIT Y (RQ ) FO R THI.; ; MIXTUR E I S 8:1. 4 LBS, . •ITC H I S BASE D O NTH E R Q O F EAC H INGREDIEN T AN D IT S PERCEN T I NMIXTURE. . SECTIO NIV. . ADDITIONA L REGULATOR Y INFORMATIO N FI E F'OLYME R ANJ ) ALL . COMPONENT S OF ' THI S PRODUC T AR E PRESEN T O NTH E UNITE D TATE S TOXI C SUBSTANCE S CONTRO L AC T (TSCA ) CHEMICAL . SUBSTANCE S INVENTORY . H E POLYME R AN D AU.. . .COMPONENT S OF ' THI S PRODUC T AR E PRESEN T O N"CH E CANADIA N HV I RONMENTA L PROTECTIO NAC T (CEPA ) DOMESTI C SUBSTANCE S • LIS T (DSL). , 

# 4 9

### ; INFORMATIO NI NTHI S MSD S AN D ENVIRONMENTA L DATASHEE T WA S OBTAINE D

) M SOURCE S WHICF I W E BELIEV E AR E RELIABLE, , HOWEVER, . TH E INFORMATIO N] JVIDE D WITHOU T AN Y REPRESENTATIO NO R WARRANTY. , EXPRESSE D O R IMPLIED , iARDIN G IT S ACCURAC Y O R COMPLETENESS . P.5 2

:CTIO N V U xc:>CLi-ii ! Ii::.i'-. ... . i i.! ! II M ,P.5 3



### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 - CHEMICA L PRODUC T AN D COMPAN Y IDENTIFICATIO N El f Atoche mNort h Americ a Custome r Service : 200 0 Marke t Stree t 1-800-558-557 5 Busine!S. 3 Hour s Philadelphia , P A1910 3 Information : 1-800-558-557 5 Busines s Hour s EMERGENC Y TELEPHON E NUMBERS : CHEMTREC : (800 ) 424-930 0 (2 4 hours ) o r (202 ) 483-761 6 MEDICAL : Rock yMountai n Poiso n Contro l Cente r

(303 ) 623-571 6 (2 4 hours ) NAM E USE D O NLABEL : LUPERSO L DDM- 9 CHEMICA L NAME : Methylethy l keton e peroxid e blen d CHEMICA L FAMILY : Organi c Peroxid e - Keton e Peroxid e PRODUC T USE : Polymerizatio n initiato r

Sectio n 2 - COMPOSITION/INFORMATIO NO NINGREDIENT S Identit y CAS 6846-50- 0 131-11- 3 1338-23- 4 107-41- 5 7722-84- 1 '78-93- 3 7732-18- 5 

### No . Typica l 

## V 2 3 . 8 32. 0 35. 0 

### S. O 0. 7 1. 0 1. 5 OSH A

Hazar d 

### N Y Y Y Y Y N 

### 2,2,4-Trimethyl-1,3-pentane
dio l diisobutyrat e Dimethy l phthalat e Methylethy l keton e peroxide s Hexylen e glyco l Hydroge n peroxid e Methy l ethy l keton e Wate r TSC AInventor yStatus : Thi s produc t i s TSC Acompliant . Th e component s ar e eithe r o n th e TSC A inventor yo r ar e exemp t a s impurities . Th e substance(s ) marke d wit h a Y i n th e OSH AHazar d colum n above , ar e chos e identifie d a s hazardou s chemical s unde r th e criteri a of chs : OSH A Hazar d Communicatio n Standar d (2 9 CF R 1910.1200) .

Sectio n 3 - HAZARD S IDENTIFICA^^O^ ADWbfcdfc y VUM-_3_£_aCAL-C:3MMM¥ - 

### Sit.Pau!,M N EMERGENC Y OVERVIEW : ^0" ^ ft^S^..'-?- 1 

### __» v Clea r oil yliquid , ketone
- odo r SISSS.^ TM

MSD S CODE : 12900 0 Date : Cl/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

# 6 1P.5 4



### MATERIAL SAFET Y DATASHEE T Sectio n 3 - HAZARD S IDENTIFICATION DANGER ! ORGANI C PEROXID E CAUSE S EY E BURN S MAY CAUS E BLINDNES S MA Y CAUS E SKI NIRRITATION MA Y CAUS E ALLERGI C SKI NREACTION HARMFU L I F SWALLOWE D POTENTIA

L HEALT H EFFECTS : Ski n contac t an d inhalatio n ar e expecte d t o b e th e primar yroute s o f exposur e t o Luperso l DDM-9 . Base d o n it s composition , Lupeiso l DDM- 9 i s anticipate d t o b e moderatel ytoxi c i f swallowed , slightl ytoxi c i f absorbe d throug h skin , practicall ynon-toxi c i f inhaled , moderatel y irritatin g t o ski n an d corrosiv e t o eyes . Prolonge d o r repeate d contac t ma ycaus e a n allergi c ski n reaction . Overexposur e t c vapo r ma ylead t o digestiv e disorders , narcosi s and centra l nervou. 3 syste m (CNS ) effect s suc h a s headache , dizziness , los s o f coordination , los s o f consciousnes s o r convulsions . I f swallowed , Luperso l DDM-S ' ma y caus e CN S effect s a s note d above , irritatio n o f 'th e mouth , throa t and stomac h and , i n sever e cases , death .

Sectio n 4 - FIRS T AI D MEASURE S
I F I NEYES : Immediatel yflus h wit h plent yo f wate r fo r a t leas t 1 5 minuts E medica l attentio n immediately . Ge t I F O NSKIN : Immediatel ywas h wit h soa p and plent yo f water . Remov e contaminate d clothin g an

d shoes . Ge t medica l attentio n i f symptom s occur . Was h clothin g befor e reuse . Destro ycontaminat d shoes . Thoroughl yclea n shoe s befor e reuse . I F SWALLOWED : Induc e vomitin g immediatel ya s directe d b ymedica l personnel . Ge t medica l attention . Contac t a Poiso n Contro l Center . NEVE R GIV E ANYTHIN G BY MOUT H T O ANUNCONSCIOU S PERSON . I F INHALED : Remov e t o fres h air .

Sectio n 5 FIR E FIGHTING MEASURE S Flas h Poin t (Tes t Method ) Autoignitio n Temperature : 58° C / 137° F (CC ) N E
MSD S CODE : 129 0 0 0 PRODUCT : LUPERSO L DDM- 9 EL F ATOCHE M NORT H AMERICA , INC . Date : 01/06/9 7 Page : 2 o f 1 3P.5 5



### MATERIA L SAFET Y DAT ASHEE T Sectio n 5 - FIR E FIGHTIN G MEASURE S Flammabl e Limits : Upper : N E Lower : N E EXTINGUISHING MEDIA : Wate r fog , wate r spray , dr ychemical , foa m SPECIA L FIR E FIGHTING PROCEDURES : Fir e fighter s an d other s wh o ma yb e expose d t o product s o f combustio n shoul d wea r ful l fir e fightin g tur n ou t gea r (ful l Bunke r Gear ) an d self-containe d breathin g apparatu s (pressure-demand NIOS H approve d o r equivalent) . Fir e fightin g equipmen t shoul d b e thoroughl y decontaminate d afte r use . I f a larg e amoun t i s involved , evacuat e are a and figh t fir e froma saf e distance . D o no t us e a soli d strea mo f water . Asoli d strea mo f wate r ca n sprea d fire . Us e wate r spra yt o dispers e an yflammabl e mist s an

d vapor s whic h hav e no t ignited . FIR E AN D EXPLOSIO NHAZARDS : ' Contac t wit h incompatibl e material s o r exposur e t o temperatur e i s exceedin g SAD T (Sectio n 9 ) ma yresul t i n a sel f acceleratin g decompositio n reactio n wit h releas e o f flammabl e vapor s whic h 'na y autoignite . Sectio n 6 - ACCIDENTAL RELEAS E MEASURE S
I F ASPIL L O R LEAK OCCURS : Us e inert , noncombustibl e absorben t material . Swee p c r scoo p u p usin g non-sparkin g tool s an d remove .

Sectio n 7 - HANDLING & STORAG E HANDLING : D o no t ge t i n eyes , o n ski n o r o n clothing . D o no t tast e o r swallow . Avoi d breathin g vapo r o r mist . Was h thoroughl yafte r handling . Us e onl ywit h adequat e ventilation . Contac t wit h incompatibl e material s o r exposur e t o temperature-.*•_; • exceedin g SAD T (Se e Sectio n 9 ) ma yresul t i n a sel f acceleratin g decompositio n reactio n wit h releas e o f flammabl e vapor s whic h na y autoignite . Kee p awa

yfromhea t spark s an d flame . Avoi d contamination . MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : "i " o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

# S3 ,P.5 6



### MATERIA L SAFET Y DAT ASHEE T Sectio n 7 - HANDLING & STORAG E Us e explosio n proo f equipment . Kee p containe r closed . STORAGE : Stor e belo w100°F(38°C ) t o maintai n activ e oxyge n content . Detache d storag e i s preferred . Avoi d excessiv e hea t and stor e ou t o f direc t sunligh t i n a -:co l well-ventilate d place . Stor e awa yfrom

combustible s and incompatibl e materials . Sectio n 8 - EXPOSUR E CONTROL S & PERSONAL PROTECTIO N
ENGINEERING CONTROLS : Investigat e engineerin g technique s t o reduc e exposure s belov / airborn e exposur e limits . Provid e ventilatio n i f necess&r yt o contro l exposur e level s belo wairborn e exposur e limits . Dilutio n ventilatio n acceptable , bu t loca l mechanica l exhaus t ventilatio n preferred , i f practical , a t source s o f ai r contaminatio n suc h a s ope n proces s equipment . Consul t ACGI H ventilatio n manua l o r NFP AStandar d 9 1 fo r desig n o f exhaus t systems . EY E PROTECTION : Wher e ther e i s potentia l fo r ey e contact , wea r chemica l gogel*3 s an d hav e ey e flushin g equipmen t immediatel yavailable . SKI NPROTECTION : Wea r appropriat e chemica l resistan t protectiv e clothin g and chemica l resistan t glove s t o preven t ski n contact . Latex , nitrile , reoprene , PV C o r othe r impermeabl e glove s shoul d b e wor n whe n handlin g thi s material . Wea r fac e shiel d an d chemica l resistan t clothin g stic h a s a rubbe r apro n wher e splashin g ma yoccur . Rins e contaminate d ski n promptly . Was h contaminate d clothin g and clea n protectiv e eguipmen t befor e reuse . Was h ski n thoroughl yafte r handling . RESPIRATOR Y PROTECTION : Avoi d breathin g vapor s o r mists . Us e NIOS H approve d ful l fac e organi c vapo r an d mis t respirato r whe n airbor n exposur e limit s ar e exceeded . I f used , ful l facepiec e replace s nee d fo r chemica l goggle s c r fac e shield . Consul t respirato r manufacture r i f exposur e limit s ar e greate r tha n te n time s th e th e recommende d exposur e limits . Observ e respirato r us e limitation s specifie d byNIOS H o r th e manufacturer . Fo r emergenc yan

d othe r condition s wher e exposur e limi t ma ybv. significantl yexceeded , use . a n approve d ful l fac e positive-pre:ssur e self-containe d breathin g apparatu s o r positive-pressur e airlin e wit h auxiliar yself-containe d ai r supply . Respirator yprotectio n program s mus t compl ywit h 2 9 CF R 1910.134 . MSD S CODE : 12900 0 Date : C'l/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 4 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC .P.5 7



### MATERIAL SAFET Y DAT ASHEE T Sectio n 8 - EXPOSUR E CONTROL S £ _ AIRBORN E EXPOSUR E GUIDELINE S OSHA PE L TWASTE L 2,2,4-Trimethyl-l , 3
- N E N E Dimethy l phthalat e 5 mg/m 3 N E -pen t : 

### CEILING PERSONAL

TW A ane-dio l diisobutyrat e N E N E Methylethy l keton e peroxide s N E N E Hexylen e glyco l N E N E Hydroge n peroxid e 1 pp mN E Methy l ethy l keton e 20 0 pp m 30 0 Wate r N E N E

Sectio n Boilin g Point , C : Freezin g Point , C : Specifi c Gravity : Vapo r Pressur e @ 2 0 Vapo r Density : air= l Evaporatio n Rate : Buty l acetate= l % Volatiles : Solubilit yi n Water : Appearanc e and Odo r pp m
9 -

C :

Clea r oil yliquid , 0. 7 pp m 2 5 pp m N E N E N E N E

5mg/m 3 N E N E 1 pp m 20 0 pp m N E PROTECTION

ACGI H TLV ST2 L NE N E 0. 2 ppm 2 5 ppm N E 30 0 pp m i 

### NE PHYSICAL Sc CHEMICAL DAT A N E belo w-30° C 1.084 0 min . 4.8mraHg@68 F N E N E N E Sligh t keton e odo r CEILING N E ME : 

### 0. 2 pp m 21 pp m 

### NTE ; 

### VT E N E

SAD T = 70° C - 4 5 lbs . i n a 5 gallo n container . Lowes t SAD T - Sel f Acceleratin g Decompositio n Temperatur e temperatur e a t whic h th e teste d packag e siz e wil l underg o a s e acceleratin g decompositio n reaqtion . Thi s reactio n wil l gene i flammabl e vapor s whic h ma yautoignite . Th e lengt h o f tim e t o a decompositio n reaction , afte r th e SAD T ha s bee n reache d o r e i s dependen t upo n ho wmuc h th e SAD T ha s bee n exceede d an d th e o f time neede d fo r th e reactio n exotherm(hea t spik e fro minc* e decompositio n rate ) t o initiat e a rapi d decompositio n reactio r Typically , SAD T i s inversel yproportiona l t o packag e size . L a package s wil l hav e a lowe r SAD T du e t o a smalle r rati o o f hea t 1: : at e generat e xceeded , lengt h easin g rge r

MSD S CODE : 12900 0 PRODUCT : LUPERSO L DDM- 9 EL F ATOCHE M NORT H AMERICA , Date : Page : 31/06/9 7

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### MATERIA L SAFET Y DAT ASHEE T Sectio n 9 - PHYSICAL... - CHEMICAL DAT A cransfe r re a t o volum e o f product .

Sectio n 1 0 - STABILIT Y & REACTIVIT Y
STABILITY : Thi s materia l i s chemicall yunstabl e and shoul d onl yb e hanile d unde r specifie d conditions . Se e HANDLING AND STORAG E sectio n o f :hi s MSD S fo r specifie d conditions . INCOMPATABILITY : Contaminatio n wit h foreig n material s suc h a s stron g acids , stron g alkalis , stron g oxidizers , transitio n meta l salts , reactio n accelerators/promoter s o r reducin g agent s ma yresul t i n a sel f acceleratin g decompostio n reaction . Rust , coppe r an d bras s ar e no t compatibl e wit h ME K peroxid e 31 6 stainles s steel , glass , polyethylene , polytetrafluoroethylen e an d polypropylen e ar e preferre d material s fo r contac t wit h ME K peroxide . Aceton e ma yreac t wit h residua l hydroge n peroxid e t o for minsolubl e shock-sensitiv e diacety l peroxid e crystals . HAZARDOU S DECOMPOSITIO NPRODUCTS : Decompositio n product s ar e flammable . HAZARDOU S POLYMERIZATION : Doe s no t occur .

Sectio n 1 1 - TOXICOLOGICA L INFORMATIO N 

### El f Atoche mNort h America , Inc . ha s no t conducte d toxicit ystudie s o n Luperso l DDM-9 , and n o informatio n o n thi s o r simila r mixturef s wa s foun d i n a searc h o f th e scientifi c literature . However , th e component s o f thi s materia l hav e bee n teste d and th e dat a ar e summarize d below . METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : Following a n allergi c ski n reactio n i n a pain t sprayer , patc h testing produce d a n allergi c ski n reactio n wit h MEK P a s wel l a s othe r component s o f th e paint . However , subsequen t patc h testin g di d no t produc e allergi c ski n reaction s i n 3 4 health ysubjects . Swallowin g o f MEK P wa s reporte d t o caus e live r injuryi n on e cas e report . Singl e exposur e (acute ) studie s o n 40-60 V MEK P i n dimethy l phthalat e indicat e tha t i t i s moderatel ytoxi c t o rat s i f swallowe d (LD5 0 48 4 mg/kg) , slightl ytoxi c t o rabbit s i f absorbe d through ski n (LD5 0
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### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 1 - TOXICOLOGICAL INFORMATION 4,00 0 mg/kg) , practicall ynon-toxi c t o rat s i f inhale d (4-h.: : LC5 0 17-5 0 mg/l) , corrosiv e t o rabbi t eye s an d moderatel yirritatin g t o rabbi t ski n (4-h

r exposure , 4.5/8.0) . Repeate d ora l admir..i.;

_tr a tio n o f MEK P wa s reporte d t o resul t i n decrease d bod yweight , mil d live r an d kidne yinjur yand deat h i n rats . Followin g repeate d applicatio n o f MEK P i n dimethy l phthalat e t o th e ski n o f rat s and mic e ', sever e ski n damag e and anima l death s (onl ya t th e highes t dos e levels ) wer e th e primar yeffects . Splee n and bon e marro wchange s considere d secondar yt o th e sever e ski n damag e wer e note d i n animal s a t ch e high doses . Highe r dose s applie d t o ra t and mous e ski n fc r a shorte r tim e produce d simila r effects . Long-termrepeate d ski n applicatio n o f MEK P i n dimethy l phthalat e wa s reporte d t o enhanc e ski n tumo r productio n i n mic e irradiate d wit h UVB . MEK P ha.
- produce d geneti c change s i n standar d test s usin g bacteria l o r anima l cells . However , n o geneti c change s occurre d i n a standar d tes t usin g animals . 2,2,4-TRIMETHYL-l,3-PENTANEDIO L DIISOBUTYRATE : Acut e studie s indicat e tha t 2,2,4-trimethyl-l_»3-pentanedic_ . diisobutyrat e i s n o mor e tha n slightl ytoxi c t o rat s i f swal.lowe d (LD5 0 >3,20 0 mg/kg) , practicall ynon-toxi c t o guine a pig s il : absorbe d throug h ski n (LDS O >2 0 ml/kg ) , practicall ynon-tcxz. c t o rat s i f inhale d (6-h r LC5 0 >5. 3 mg/l) , slightl yirritating t o rabbi t eye s an d slightl yirritatin g t o guine a pi g skin . N o ski n al.lerg y wa s observe d i n guine a pig s followin g repeate d exposure s t o 2 , 2 , 4-trimethyl-l,3-pentanedio l diisobutyrat e i n controlle d ski n contac t studies . Increase d live r weights , whic h wer e probabl y adaptiv e change s du e t o th e inductio n o f dru g metabolizin g enzyme s i n thes e tissues , wer e observe d i n rat s o r dog s fed 2,2,4-trimethyl-l,3-pentanedio l diisobutyrat e (u p t o 1% ) i n thei r fee d fo r u

p t o 10 3 days . 2,2,4-Trimethyl-1,3-pentanedio l diisobutyrat e i s eliminate d i n th e excret a o f rat s followinc; * a singl e ora l dos e wit h littl e o r n o retentio n i n the tissue s o r organs . HEXYLEN E GLYCOL : Ski n applicatio n o f 50 % hexylen e glyco l i n wate r showe d cn.. yminima l irritatio n i n huma n volunteers , whil e repeate d applicatio n o f consume r product s containin g u p t o 1 % hexylen e glyco l di d no t sho w irritan t or J 

### sensitizin g effect s i n humans . Patc h test s hav e show n sensitizatio n response s i n individual s workin g wit h cuttin g oil s containin g hexylen e glycol . Acut e studie s indicat e tha t hexylen e glyco l i s slightl ytox;. c t o rats , rabbits , mic e and guine a pig s i f swallowe d (LDS O 2,80C-4,70 0 mg/kg) , practicall ynon-toxi c t o rabbit s i f absorbe d throug h ski n (LD5 0 12,30 0 mg/kg) , severel yirritatin g t o rabbi t eye s an d moderatel yirritatin g t o rabbi t skin . N o death s occurre d :.r: . rat s expose d t o about . 16 0 pp mhexylen e glyco l fo r 8-hours . Rats - an d rabbit s expose d t o hexylen e glyco l (0. 7 mg/l ) fo r 9 day s d._ d no t
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 7 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC .P.6 0



### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 1 - TOXICOLOGICAL INFORMATION sho wan yadvers e effects . Hexylen e glyco l i n th e die t a t u p t o 15 0 mg dail yfo r 4 month s produce d n o advers e effect s o n growth ! behavio r o r fertilit yi n rats . Change s i n th e kidne ywer e note d a t 2 0 0 mg/day . Hexylen e glyco l ha s no t produce d geneti c change s o r chromosoma l effect s i n standar d test s usin g bacteria l o r anima l cells . METHY L ETHY L KETON E (MEK) : Repeate d exposur e o f human s t o ME K controlle d ski n contact : studie s produce d n o ski n irritatio n o r ski n allergy . Centra l nervou s syste m (CNS ) effect s an

d periphera l neuropath yhav e bee n reporte d in th e industria l settin g followin g exposur e t o mixture s contain i.n q MEK ; however , thes e mixture s containe d othe r solvent s know n t o caus e nervou s syte minjury . Acut e studie s indicat e tha t ME K i s n o mor e tha n slightl ytoxi c t o rat s i f swallowe d (LD5 0 2,70 0 t o 5,60 0 mg/kg) , practicall ynon-toxi c t o rabbit s i f absorbe d throug h ski n (LDS O 5,00 0 t o 13,00 0 mg/kg ) o r rat s i f inhale d (4-h r LC5 0 11,70 0 ppm ) and moderatel yiriitatin g t o rabbi t eye s an d skin . Followin g repeate d inhalatio n exposure , sligh t change s i n orga n weight s an d bloo d chemistr ywer e reporte d i n rats . N o evidenc e o f nervou s syste minjur yfollowin g long-term inhalatio n exposur e t o ME K ha s bee n observe d i n rats , chickens , mic e o r cats . Anima l studie s hav e show n ME K t o increas e the severit yof , o r shorte n th e onse t of , irreversibl e nervou s syste meffects ; du e t o n-hexan e and methy l buty l ketone , a s wel l a s effect s o f chloroform and carbo n tetrachloride . ME K di d no t increas e th e incidenc e o f tumor s i n long-termski n applicatio n studie s i n mice . Asmal l numbe r o f majo r birt h defect s wer e reporte d i n rat s expose d t o ME K b yinhalatio n durin g pregnanc ya t a leve l (3,00 0 ppm ) whic h produce d toxi c effect s i n th e offspring , bu t no t i n th e mothers . However , n o birt h defect s wer e found i n a second repea t stud ywit h rat s using ver ysimila r exposur e conditions , whil e advers e effect s wer e note d i n th e mother s and thei r offspring . I n mic e expose d t o 300 0 pp mME K b yinhalatio n durin g pregnancy , toxi c effect s wer e observe d i n th e mother s (mil d effect s only ) an d thei r offspring . ME K ha s generall y produce d n o geneti c change s i n standar d test s usin g animal s and anima l o r bacteria l cells . Apositiv e respons e wa s reporte d i n on e assayusin g yeas t cells .

Sectio n 1 2 - ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION El f Atoche m

Nort h America , Inc . ha s no t conducte d ecologica l effec t studie s o n Luperso l DDM-9 , an d n o informatio n o n thi s o r simila r mixture s wa s found i n a searc h o f th e scientifi c literature . However , th e component s o f thi s materia l hav e bee n teste d an d :he dat a ar e
MSD S CODE : 12900 0 Date : C1/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 8 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC .P.6 1



### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 2 - ECOLOGICAL INFORMATIO N summarize d below . ECOTOXICOLOGICA L INFORMATION : METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : MEK P i s slightl ytoxi c t o guppie s (96-h r LC5 0 44. 2 mg/l) . 2,2,4-TRIMETHYL-1,3-PENTANEDIO L DIISOBUTYRATE : 2 , 2,4-Trimethyl-l,3-pentanedio l diisobutyrat e i s n o mor e tha n moderatel ytoxi c t o mos t aquati c organism s o n a n acut e basi: . wit h LC5 0 value s >1.5 5 mg/ l fo r th e fathea d minnow , ramshor n sra.i.1 , aquati c earthworm , sideswimmer , pil l bu g an d flatworm . I t :. s n o mor e tha n moderatel ytoxi c t o daphni d (EC5 0 >1.4 6 mg/l) . HEXYLEN E GLYCOL : Hexylen e glyco l ha s bee n reporte d t o b e practicall ynon-tox:. c t o a variet yo f aquati c organism s byacut e toxicit ytesting . Fretshwate r fis h includin g rainbo wtrout , bluegil l sunfish , fathea d minnow , mosquit o fish , goldfis h and channe l catfis h ha d LC5 0 value s i n exces s o f 1,00 0 rag/1 an d generall ywer e i n the rang e o f 8,00 0 t o 10,00 0 mg/l . Aquati c invertebrate s suc h a s Daphni a and crayfis h ha d EC5 0 value s greate r tha n 2,80 0 mg/l . METHY L ETHY L KETON E (MEK) : ME K i s practicall ynon-toxi c t o goldfish , brin e shrimp , Daphni a magna , fathea d minnow , mosquit o fish , bluegil l sunfis h and golde n orf e (LCSO s >1,00 0 mg/l) . ME K inhibit s funga l growt h an d i s reporte d t o b e bacteriostati c t o severa l microorganism s (Escherichi a coli , Salmonell a typhimurium , Staphylococcu s aureus , Leucor.osto c citrovoru

man d Streptococcu s thermophilus ) a t level 3 o f 10-1.0 0 mg/l . Growt h inhibitio n ha s als o bee n reporte d fo r freshwate r al^a. e a t level s rangin g from 12 0 mg/ l (blue-gree n algae ) t o 4,30 0 m?/ l (gree n algae) . CHEMICA L FAT E INFORMATION : METHY L ETHY L KETON E PEROXID E STRUCTURE S (MEKP) : MEK P wa s reporte d t o b e readil ybiodegradabl e i n a close d nettl e system . A n EC5 0 o f 1 6 mg/ l wa s reporte d i n a n activate d sludg e respiratio n inhibitio n test . 2,2,4-TRIMETHYL-1, 3 -PENTANEDIO L DIISOBUTYRATE : I n a 28-daymodifie d SturmTest , 2,2,4-crimethyl-l , 3-penta:iedio l diisobutyrat e wa s found t o underg o 32-59 % degradatio n t o C02 . Th e bioconcentratio n facto r withou t metabolis mwa s estimate d t o be 67 0 and wit h metabolis m 1-40 . Th e lo g Po wo f 2,2,4-trimethyl-1,3
- pentanedio l diisobutyrat e i s estimate d t o b e 4.1 . HEXYLEN E GLYCOL : Chemica l oxyge n deman d (COD ) an d biologica l oxyge n deman d (30D ) indicate d tha t hexylen e glyco l i s readil ybiodegraded .
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 9 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIAL SAFET Y DAT ASHEE T Sectio n 1 2 - ECOLOGICAL INFORMATION METHY L ETHY L KETON E (MEK) : Extensiv e dat a suggest s tha t ME K is readil ybiodegradabl e I t i s non-toxi c t o sludg e microorganism s a t concentration s u p tc ; 30 0 ug/ l Sectio n 1 3 - DISPOSA L CONSIDERATION S Dispos e i n accordanc e wit h federal , stat e and loca l regulations . Dilutio n followe d b yincineratio n i s th e preferre d metEod . Dilutio n rati o o f 10: 1 i n a clean , compatible , combustibl e solven t (i.e . Fue l Oi l #2 , minera l oil ) wil l reduc e reactivit yhazar d durin g incineratio n an d transportation .

Sectio n 1 4 - TRANSPOR T INFORMATION DO T PROPE R SHIPPING NAME : Organi c Peroxid e Typ e D Liqui d TECHNICA L SHIPPING NAME : Methy l Ethy l Keton e Peroxide(s) , <45 % DO T HAZAR D CLASS : 5. 2 U NNUMBER : 310 5 PACKIN G GROUP : I I PRODUC T R Q (LBS) : Se e belo w Sectio n 1 5 - REGULATOR Y INFORMATION
SAR AHAZAR D CLASSIFICATIO N Immediat e (Acute ) Health : ye s Delaye d (Chronic ) Health : n o Sudde n Releas e o f Pressure : n o Reactive : ye s Fire : ye s SAR ATitl e III , Sectio n 302 : Thi s produc t doe s no t contai n an ychemical s currentl yo n th e Extremel yHazardou s Substanc e List , Sectio n 302 , SAR ATitl e ;!II abov e th e OSHAd e minimi s concentration . SAR ATitl e III , Sectio n 313 : Thi s produc t contains : Dimethy l phthalat e 131-11- 3
MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 3 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DATASHEE T Sectio n 1 5 - REGULATORY INFORMATION Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Toxi c Chemica l List , Sectio n 313 , SA3 A Titl e III . CERCL AR Q Thi s produc t contains : Dimethy l phthalat e 131-11- 3 500 0 lbs . Methylethy l keton e peroxide s 1338-23- 4 1 0 lbs . Methy l ethy l keton e 78-93- 3 500 0 lbs . Californi a Propostio n 65 : Thi s produc t doe s no t contai n an ychemical s currentl yliste c o n the Californi a Lis t o f known Carcinogens . Californi a Propostio n 65 : _ Thi s produc t doe s no t contai n anychemical s currentl yliste d o n th e Californi a Lis t o f known Reproductiv e Toxins . Pennsylvani a Right-to-Kno w Hazardou s Substanc e Lis t Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Pennsylvani a Hazardou s Substanc e List . Pennsylvani a Right-to-Kno w Environmenta l Hazardou s Substanc e Lis t Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Pennsylvani a Environmenta l Hazardou s Substanc e List . MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : U o t I J EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DAT ASHEE T Sectio n 1 5 - REGULATOR Y INFORMATIO N Pennsylvani a Right-to-Kno w Specia l Hazardou s Substanc e Lis t Thi s produc t doe s no t contai n an ychemical s currentl yo n :h e Pennsylvani a Specia l Hazardou s Substanc e List , abov e th e CSHA d e minimi s concentration . Massachusett s Right-to-Kno w Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 t 

### whic h ar e liste d o n th e Massachusett s Hazardou s Substanc e LLs t Ne wJerse yRight-to-Kno w Thi s produc t contains : Dimethy l phthalat e 131-11- 3 Methylethy l keton e peroxide s 1338-23- 4 Hexylen e glyco l 107-41- 5 Hydroge n peroxid e 7722-84- 1 Methy l ethy l keton e 78-93- 3 whic h ar e liste d o n th e Ne wJerse yHazardou s Substanc e Lis-. :

Sectio n 1 6 - OTHE R
Legend N/ A- No t Applicabl e N E - No t Establishe d NJTS N- Ne wJerse yTrad e Secre t Numbe r Lupersol , Luperco , Luperox , Peroximo n an d Retilo x ar e register.:-; . trademark s o f El f Atochem , Nort h America , Inc . MSD S CODE : 12900 0 Date : C1/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : 1 2 o f 1 3 EL F ATOCHE M NORT H AMERICA , INC . 

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### MATERIA L SAFET Y DATASHEE T Sectio n 1 6 - OTHE R | Issued : 01/06/9 7 Rev. - 0 Supersedes : 07/12/9 5 El f Atoche m

Nort h America , Inc . believe s tha t the informatio n and recommendation s containe d herei n (including dat a an d statements ) ar e accurat e a s o f th e dat e thereof . N O WARRANT Y O F FITNES S TO X AN Y PARTICULA

R PURPOSE , WARRANT Y O F MERCHANTABILITY , O R ANY OTHE R WARRANTY , EXPRES S O R IMPLIED , I S MAD E CONCERNING TH E INFORMATIONPROVIDE D HEREIN . Th e informatio n provide d herei n relate s t o th e specifi c produc- : designate d and ma yn o b e vali d wher e suc h produc t i s use d i n combinatio n wit h an yothe r material s o r i n an yprocess . Further , sinc e th e condition s an d method s o f us e o f th e produc t an d o f th e ir.formation referre d t o herei n ar e beyon d th e cbntro l o f El f Atochem , El f Atoche m expressl ydisclaim s an yan d al l liabilit ya s t o an yresult s obtaine d o r arisin g from

an yus e o f th e produc t o r relianc e o n suc h information .

MSD S CODE : 12900 0 Date : 01/06/9 7 PRODUCT : LUPERSO L DDM- 9 Page : l i o f 1 3 EL F ATOCHE M NORT H AMERICA , INC .P.6 6

f -Wisconsi n SOURC EDESCRIPTIO N - SUPPLEMENTA L new o f Namra l Resource s AI RPOLLUTIO N CONTRO LPERMI T APPLICATIO N For m4530-1Q2 A 11-9 3 Infonnatio n attached ? _(y/n ) i f thi s formi s require db y th e Departmen t fo r an y ai r pollutio n contro l permi t applicatio n filedpursuan t t o s . 144.39 2 o r 925 , Wi s Stats . Completio n o f thi s for mi s mandatory . Th e Departmen t wil l no t conside r o r ac t upo n you r

applicatio n ; yo u complet e an dsubmi t thi s form . I t

i s no t th e Department' s intentio n t o us e an y personall y identifiabl e informatio n a-ci a "in n fo r an y othe r

purpose . Lis t al l significan t

existin g o r

propose dai r

pollutio n units , operations , an dactivitie s at th e facility . A shor t

narrativ e o f

th e inventory o f

ai r pollutio n emission s uni t (e.g. , boiler , printin g line , etc. ) followe db y equipmen t specification s wil l suffice . If th e facility consist s o f

severa l individua l emissio n units , presen t thi s informatio n i n a n outlin e format . (Se e instructio n bookle t fo r a n exampl e Uni t

description. ) 'Qr\ o _ c . r^.,,
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o f Wisconsi n STAC K IDENTIFICATION irancn tof Natura l Resource s AI RPOLLUTIO N CONTRO L PERMI T APPLICATIO N For m4530-10 3 11-9 3 Information attached ? _(y/n) • INSTRUCTIONS O

N REVERS ESIDE Facilit y name : 2 . E^^^^ti^ifiapn^l ^ 3 . S^^iidenMc_Ho n number . ExhaustirigUnitfs),-use-Uni t idenft^ ^ 10 9 30-104 4530-10 6 4530-107 4530-10 8 4530-109 Identif y thi s stack

o n the plo t

pla n requiredo

n For m4530-10 1 Jj f Thi s stack

ha s a n acma l exhaus t point . • Thi s stac

k serve s t o identif

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outle t (check one and^complete) : D Circula r (feet) JS_frectangula r /Q. / lengt h(feet ) QL . widt h(feet ) "^a^silwirate ; Nonla^^P^kCFM ) Maximu m2SLU3. (ACFM) Exni£to.gasitemperstture^(normal): ; ~ _ _(°F ) I_>H.WAW»:AM70.'A,,'^.,W.'VCI:.;^^.«M^A_>.'^>.V'W, , AWVW./ W-****H____L__^_____-_ > * * Exhaus t ga s moistur

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l volum

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' * Complet

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e Ai r Permit Application Fonns(s ) 4530-104 , 106 , 107 , 10 8 o r 10 9 fo r eac hUni t **** * exhaustin g throughthi s stack .P.6 8

: o f Wisconsi n artmen to f Natura l Resource s ; INSTRUCTION

S O N REVERS

E SID E PAINTIN

G AN D COATIN

G OPERATION

S AI RPOLLUTIO

N CONTRO

L PERMI T APPUCATIO

N For m 4530-108 :

r11-9 3 Infonnatio n attached? _

(y/n) Facilit y name : Q FM^LA« Mh.mo . 2 . Facil^ddm-ific^tion-nu-nber. Stackvidentificationnumbe n 4
. I?roce^tom|>a : 

# P03 u Uni tdescription : JA IK.TIK-' C L \tOF P^itJ T {1-oGT-h .."" ' |^i^^i^^^I|te^Splbg-^!^i ^ Uncontrolle d D Controlle

d IfctheiprocesssisfcontiDll^e^ ^ 4530-110 . 4530-11 4 4530-111 .

4530-11 5 4530-112 .

4530-11 6 4530-113 .

4530-11 7 |jJi^^M--M^t nMfae ffidency(%) ; g ^ 1QQ\ A\W ATftua^^f t l-^lUaO 

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f the coatings ' an

dsolvents ' composition (a s applied ] 

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N O F METHOD

S USE D FO RDETERMININ

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# C0l0P.6 9

o f Wisconsi n tmen to f Natura l Resource s 

### INSTRUCTION S ONREVERS ESID E EMISSIONUNT T HAZARDOU S AI

RPOLLUTAN

T SUMMAR

Y AIRPOLLUTIONCONTROLPERMIT APPUCATIO N Fon n4530-12 6 11-9 3 Informationattached ? _(y/n ) Facilityname : 0li

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# 6 19 7 —Sectio n 1 —

Produc t Identificatio n 

# P mi 

# Materia l Safet yDat a Shee t Th e Sherwin-William s Co . 10 1 Prospec t Ave . N.W . Cleveland , O H 44 1 1 5 Emergenc y telephon e numbe r Inlormatio n telephon e numbe r Dal e of preparatio n (216 ) 566-291 7 (216 ) 566-290 2 Septembe r I . 199 7 OI9v7 . Ih e Sheiwln-Wililam s Co . 

# POLANE®

^Redtmem^

—Sectio n 2 — C A S No . Hazardou s Ingredien t i (percen t b y weigM ) 5 108-88- 3 * Toluene . 100-41- 4 " Ethylbenzen e 1330-20- 7 * Xylene . 78-93- 3 * Methy l Ethy l Ketone . 108-10- 1 * Meihy l Isobuty l Ketone . 110-43- 0 Meihy l n-Amy l Kelone . 108-94- 1 Cyclohexanon e 108-21- 4 Isopropy l Acetate .
, 123-86- 4 n-Buty l Acetate . ACGI H OSH A Vapo r TL V PE L Unit s Pressur e <STEL > <STEL > (m m Hg ) 5 0 J!? ^ PP M (Skin ) 22. 0 10 0 10 0 <125 > <125 > PP M 7 ' 1 1 0 0 '0 0 pp M s g <150 > <150 > KK M 6 9 20 0 20 0 DD , . ,. _ <300 > <300 > PP M 70 0 5 0 5 0 <?5 > <75 > PP M 16 0 5 0 10 0 PP M 2. 1 2 5 2 5 PP M (Skin ) 2. 0 25 0 25 0 <310 > <310 > PP M 47 5 15 0 15 0 „„, . .. . <200 > <200 > PP M 10 ° Weigh t pe r Gallo n (lbs. )

. ^ VO C (Volatil e Organi c Compounds ) - lbs./gal . Ir \ 5 Photochemicall y Reactiv e 4 ^ Flas h Poin t (*F )

" " OO L Storag e Categor y

Flammabilil y Classilicalio n (Flammabl e - Combustible ) | HMI S (NFPA ) Ratin g (healt h - llammabilit y - reactivity ) MA K R6K3 0

10 0

6.7 6 6.7 6 N o 10 0 2 Combustibl e 2 2 0 Cyclohexanon e

R6K3 2

10 0

7.6 6 7.8 6 N o 1 1 1 2 Combustibl e 3 2 0 K6 9 Thinne r

R7K6 9 530-2138 530-214 6 530-264 1 1 5 9 5 2
2 4

7.0 4 7.0 3 Ye s 3 5 I B Flammabl e 2 3 0 KB

4 Thinne r R7K8 4 S30-2tS3 530-216 1 530-2658 2 0

3 6 4 5 7.2 5 7.2 5 N o 3 5 I B Flammabl e 2 3 0 K9 4 Thinne r

R7K9 4 530-217 9 530-2187 530-266 6 2 0

2 5

2 7 2 8 7.0 9 7.0 9 N o 2 1 I B Flammabl e 2 3 0 Retarde r

R7K21 6

4

7 1
2 4 7.6 8 7.6 8 N o 9 2 I C Flammabl e 3 3 0 

# SOL-POL

W&Sara m

1 2 1 7 5 9

6
1 5 

### '\f$jffi0i\W.
i)t_-«~i--'•• ' " N o 3 0 1 B Flammabl e 3 3 0 Reduce r

R 7 K B5 0

2 1
3 5
2 2 2 2 6.9 6 6.9 5 N o 3 0 I B Flammabl e 2 3 0 P

t p c t H T 8 r W f I 0 H I

Ingredien t subjec t IO th e reportin g requirement s o l Ih e Superlun d Amendmeni s an d Reauthorizatio n Act (SARA ) Sectio n 313 . 4 0 CF R 372.6 5 C



### ->-->--> MSDS

Text Page Follows •*•*•>

# POLANE®

Reducers SOL-POL Sectio n 3 —Physica l Dat a PRODUC T WEIGHT SPECIFTC

CRAVITY 3 0 IL-.V C RANCE •VLATtLC

VOLUME Se c TABL E

0.81-0.9 . 11J-33 0 •! • 10 0 > f\'AP0«.4T/0 « PJXrVAPO RDENSITY MELT IHC POI.V T SOLUBILITY

T N HATES Slowe rCha n Ethe r

Heavie rCha n Ai r N A . N A . Sectio n 4 —Fire An d Explosio n Hazar d Dat a Se e TABL

E LE

L 1 . 0 UEL10. 0 F-..<--0M8_LIT Y CLASSIFICATION FLASH

POINT Se e TABL

E EXTINGUISHING MEDIA Carbo n Oioxlde , Dr y Ch—mlcal . Fo— m UNUSUAL FIREAM D EXPLOSION HAZARDS Kee pcontainer s tightl y closed . Isolat e fro m heat , electrica l equipment . spark9 . an d ope n (lame . Close dcontainer s na y explod e whe nexpose dt o extrem e heat . Applicatio nt o ho t surface s require s specia l precautions . Durin g emergenc y condition s overexposur e t o decompositio nproduct s ma y caus e a healt hhazard . Symptom s ma y no t b e immediatel y apparent . Obtai nmedica l attention . SPECIA L FIREFIGHTING PROCEDURES Ful l protectiv e equipmen t Includin g self-containe dbreathin g apparatu s shoul db e used . w ate r spra y

ma y b e Ineffective . I f wate r l s used , fo g noszle s ar e preferable . Wate r ma y b e use dt o coo l close dcontainer s t o preven t pressur e build-u pan d possibl e autoignitio no r explosio nwhe nexpose dt o extrem e heat . Sectio n 5 —Healt h Hazar d Dat a ROUTES OFEXPOSURE Exposur e ma y

b e b y INHALATIO N

and/o r SKI N

o r EY E contact , dependin g o ncondition s o f use . T o minimiz e exposure , follo w recommendation s fo r prope r use . ventilation , an d persona l protectiv e equipment . ACUT E Healt hHazard s EFFECTS OFOVEREXPOSURE Irritatio no f eyes. : sxi nan d respirator y system . Ma y

caus e nervou s syste m depression . Extrem e overexposur e ma y resul t i nunconsciousnes s an d possibl y death . SICNS AND SYMPTOMS OFOVEREXPOSURE Headache , dizziness , nausea , an d los s o f coordinatio nar e indication s o t excessiv e exposur e t o vapor s o r spra y mists . Rednes s ah ditchin g o r burnln o sensatio nma y Indicat e ey e o r excessiv e ski nexposure . KEOrCA L CONDITIONS AGGRAVATED BY EXPOSURE Non e generall y

recognized . EMERGENCY

AND FIRST

AID PROCEDURES I f INHALED : I f affected , remov e fro m exposure . Restor e breathing . I f o nSKIN : Has haffecte dare a thoroughl y wit hsoa pan d water . Remov e contaminate dclothin g an d launde r befor e re-use . Flus heye s wit hlarg e amount s o f wate r fo r 1 5 minutes . Neve r giv e anythin g b y mout ht o a nunconsciou s person . Kee pwar m an d quiet .

Giv e severa l glasse s o f water . See k medica l attention . Ce t medica l attention . D O NO T INDUC E I f l nEYES : I f SWALLOWE D VOMITING . CHRONI C Healt hHazard s N o ingredien t l nthes e product s i s a nIARC . NT P o r OSH A liste dcarcinogen . Report s hav e associate drepeate dan d prolonge doverexpcsur e t o solvent s wit hpermanen t brai n an dnervou s syste m damage . Prolonge doverexposur e t o solven t ingredient s l nth e followin g product s ma y caus e advers e effect s t o orga nsystems : ur i n a r y urinary , u r Inary . urinary . • Cyclohexinone t Methyl Amy . Keton e • KS9 Thinner 'R7KS50 i Retarde r R7K21C • R7XB29. KS4

Thinner
_K9I 1iver . liver , liver , liver . cardiovascular , reproductiv e

bloo dforming , reproductiv e bloc dforming , cardinvascular . reproductiv e Sectio n 6 —Reactivit yDat a STABILITY

- Stabl e CONDITIONS TO AVOID Non e known . -.voo.fPATia.L/T

y Non e known . HAZARDOUS DECOMPOSITION PRODUCTS B y tire : Carbo n Dioxide . Carbo n J HAZARDOUS POLYMER IZATICN - Wil ! No t lon.j t i y.

Occ-i r Sectio n 7 —Spil l O rLea k Procedure s STEP S T

O B E TTUC-

M I N CAS E MATERIAL IS RELEASED OR SPILLED Remov e al l source s o f ignition . Ventilat e an d remov e wit h In-sr tabsorben t WAST E DISPOSAL METHOD Wast e fro m thes e product s ma y b e hazardou s a s define d unde rth e Resourc e Conservatio n in d Recover y Ac tIRCRA) « 0 CF R.6 1 Wast e mus tb e teste d fo rignitabilit y t o determin e th e applicabl e EP

A hazardou s wast* : numbers . Wast e fro m product s containin g Methy l Ethy l Keton e m. i als o requir e testin g fo rextractabi1ity . Incinerat e i n approve d facility . D o no tIncinerat e close d container . Dispos e o f i n accordanc e wit h Federal . State , an d Loca l regulation s regardin g pollution . Sectio n 8 —Protectio n Informatio n PRECAUTIONS TO BETAXES IN USE U s e onl y

wit hadequat e ventilation . Avoi dbreathin g vapo r an d spra y mist . Avoi dcontac t wit hski nan d eyes . Was hhand s afte r using . VEfTTlLATION Loca l exhaus t preferable . Genera l exhaus t acceptabl e i f th e exposur e t o material s i n Sectio nX I i s maintaine dbelo w applicabl e exposur e limits . Refe r t o OSH A Standard s 1910.94 . 1910.107 . 1910.108 . RESPIRATORY

PROTECTION I f persona l exposur e canno t b e controlle dbelo w applicabl e limit s by ventilation , wea r a properl y

(itte dorgani c vapcr/particulat e respirato r approve db y NIOSH/MSH A

(o r protectio n agains t material s i nSectio nII . PROTECTIVEGLOVES Wea r glove s whic har e recoircnende db y glov e supplie r fo r protectio nagains t material s i n Sectio nXI . iT E PROTECTION Wea r safet y

spectacle s wit hunperforate dsideshields . Sectio n 9 —Precaution s COL STORAGECATEGORY - Se e TABL E PRECAUTIONS T O BETAKEN IN HAKDLING AND STORING Kee pawa y

fro a heat , sparks , an d ope nflame . Durin g us e an d unti l al l vapor s ar e gone : Kee pare a ventilate d- D c no t smok e • Extinguis hal l flames , pilo t lights , an d heater s - Tur nof f stoves , electri c tool s an d appliances , an d an y othe r source s o f ignition . Consul t NFP A

Code . Man approve dBondin g an d Groundin g procedures . Kee pcontaine r close dwhe nno t i nuse . • Transfe r onl y t o approve dcontainer s wit hcomplet e an dappropriat e labeling . D o r.ot tak e Internally . Kee pou t o f th e reac ho f children . OTHE RPRECAUTION S Intentiona l misus e b y deliberatel y

concentratin g an d inhalin g th e content s ca nb e harmfu l o r fatal . Sectio n 1 0 —Othe r Regulator yInformatio n CALIFORNIA PROPOSITION S$ WARNING : K* 9 Thinner . KS 4 Thinner . K9 4 Thinne r an d R7KB- 9 contai nchemical s know nt o th e Stat e o f Californi a t o caus e cance r an d birt hdefect s o r othe r reproductiv e harm . TSCA CERTIFICATION Al l chemical s i nthes e product s ar e listed , o r ar e exemp t fro m listing , o nth e TSC A Inventory .

Th e abov e Informatio npertain s t o thes e product s a s currentl y formulated , an d i s base do n th e infonnatio navailabl e a t thi s time . Additio no f additive s o r othe : coating s material s t o .nes e product s ma y substantiall y

alte r th e compositio nan d hazard s o f th e products . Sinc e condition s o f us e ar e outsid e ou r control , w e mak e n o warranties , expres s o r implied , an d asr.u.- , r. c liabilit y

i nconnectio nwit h.m y us e o f thi s information .

## JUN-10-9 8 WE D09:2 7 A M ICAF E Jun-lO-9 8 08:0 0 

## FA XNO . 1414774156 0 TH - $arf yyi,)J^„, FROM

: *C^
_ CO : DEP T FAX # J___m___zL rr- f t,_t„.gMT Q xjj. jU^ryx^JX*.



### I ICAF E j

. PHONE : (414 ) 774-091 0 FAX / (414)774*156 0 

### P. 0 1 P.O l P.7 3

*jiU. TD10-4 R 

# DIVISION * Hig h Volum e Lo wPressur e - HVLP HIG H VOLUM E LO W PRESSUR E SPRAYIN G HVL P(highvolume low pressure ) sprayin g ha s quickly become th e bigges t

tren di n finishing today . HVL Puse s approximately th e same volume o f ai r a s aconventiona

l spra y gun , bu t a t lower pressure s t o atomiz e th e fluid. Reducing ai r

pressur e a t

th e nozzl e reduce s th e velocit y o f th e ai r streaman datomize dfluid. Thi s in tu mha s a positiv e effect

b y reducin g th e "bounc e back " o f material fro mth e surfac e bein g coated . The resultin g spra y i s hig h in transfer efficiency . REASO N FO R HVL P World-wid e concern over

ai r qualit y an dhazardou s emis
sion s ha s generate da

n enormou s interes t

in HVL Pspra y equipment . Assuming aleadin g rol e i n mandatin g mor e environmentally soun dpaintin g operations , th e Californi a Sout hCoas t Ai r Qualit y Managemen

t Distric t (SCAQMD

) ha s specifiedHVL

Pspray gun s a s on e o

f only tw o type s o f spra y equipment

approve dfo

r us e withi n it s distric t (th e Lo s Angele s basin) . Simila r legislatio n ha s bee n adopted , o r i s now under

con sideration , i

n man y othe r industrialize darea s throughout th e Unite dSlates . As thes e area s introduc e thei r ow n rules , th e KP A will require then ; t o b e a s strict , o r stricter , a s th e Californi alegislation . Hig

htransfe r efficien t equipmen

t ma y ultimatel y b e arequiremen t of operatin g in th e finishin g industry . Recognizing tha

t th e essential characteristi c o f HVL Pi s lo w ai r velocit y create dby low atomizin g pressures , the SCAQM D define s HVL

Pa s an y devic e that

atomize s paint wit ha n operatin g pressur e at

th e air nozzl e between 0. 1 an d1 0 PSIG . Overspra y I s amajo

r proble mfo

r man y companie s l n th e finishin g industry . Virtuall

y all spray finishing operation s ca n b e adversel y affecte db y overspray an dthi s ca n result i n costly maintenanc e an ddowntime . B a Miln e Transf» r Efficiency O f Spra y Coatin g Method s
HVL P Airles s Electrostati c Air-Assiste d Airles s Electrostati c Ai r Electrostati c Air-Assiste d Airles s Airles s Spra y Ai r Spra y 6 5 V . SCAQM D Minimu m Note : A U figure s ar s considere d 'Baselin e .Actua l T.E . varie s du e l o a n unlimite d numbe r o f variable . HVL Psprayin g ca

n b e tsv o t o thre e time s as efficien

t a s conventional ai r

spra y whichca

n cu t materia l cost s an dwast. , efficient . Thi s meonslnat

ove r tw o gallon s o

f paint are wasted , du e t o overspray , fo r ever y thre e gallon s tha t

are sprayed . Wit

hHVL Pspraying a

t a n efficienc y rat e o f 05 % t o 85% , a s littl e a s on e pin

t o f paint wouldb e waste dfo

r ever y gallo n sprayed . Anothe r major problemfo

r finishers i s wast

e disposal . B y using a n HVL Psystem , wit

hit s hig htransfer efficiency , wast e disposal cost s ar

e lowered . Productivit

y wil l likel y increas e wit

ha n HVL Psystem becaus e fewer

passe s ar e neede dt o buil du

p th e same filmthicknes s sinc e mor

e materia l i s applie dwit

heac h pas s du e t o HVLP' s hig

htransfer efficiency . HVL P vs . ELECTROSTATI C Whe n comparin g HVL

Pan delectrostati c spraying yo u must consider th e par t tha t l s t o b e sprayed . Unlik

e electrostatic , HVL Pwork s equally a s well wit hnonconductiv e part s lik

e plastic s an dwoo da s i

t doe s wit hmeta l substrates . Operator s o

f paintin g equipment

are als o directly affected b y overspray . Tlt

e fume s emitte dinto th e nlrea n b o haz
ardou s lo their

health . Visibilit

y l n th e spraying are ai s als o reduce db y fume s an dthi s contribute s t o mistake s and low productivity . TRANSFE R EFFICIENC Y Ahighe r transfer efficiency improve s th e qualit y o f tiie wor k plac e b y reducin g unnecessary pollutio n andI t improve s th e qualit

y o f product s b

y providin g a

n excellent finish. 

## ^IIICAP - CS G

. a* rx rx HVI P ELECTROSTATI C (Air ) ADVANTAGE S

•Hig h Transfe r Efficienc y •Lo wCos t (Ai r Restricted ) •Eas y T o Operat e •Spray s Int o Recesse s •Mor e Rugge d

UMITATION S

•Lowe r Producllo n Spee d •Difficul t T o Atomiz e Sem e Coaling s « Hig n Cos t (Turbine ) •Hig h Energ y Ut e (Ai r Restricted ) UMITATION S

•Part s Mus t 8 0 Conouctiv e •Hig h Cos t « Hig h Vol.eg e Stigm a •Farada y Cog o Elfcc t

ADVANTAGE S
» Hig h Tfans'e. * Efficienc y •Hig h Productio n Speed s •Excellen t Finls H •"Wrap * Aroun d Coverag eP.7 4

Bink s MODE L 200 1 & 2001 V H.T.E. , LPL V SPRA YGUN S Th e followin

g five (5 ) item s are neede dto conver t you r mode l 200 1 o r 2001 V Spra

y Gun t o a n H.T.E. . LPL

V Gun : GU N HEA D 

# ( D Standard 65 Serie s Flui d Needle , e.g. , 65 , 265 , 365 , 465 , 565 20-4445 "O " Rin g (I t i s recommende d tha t thi s " 0 " Rin g b e use d i n plac e o f th e 54-91 8 Gasket)

54-335 9 FLUI D STRAINE R ASSEMBL

Y

INSTALLATIO N INSTRUCTION S INSTALLATIO N INSTRUCTION S 1 . Remove th e conventional ai r atomizin g setup , namely the air nozzle , fluidnozzle , an

dO-Ring . 2 . Inser t th e 20-444 5 O-Ring . D O NO T SUBSTITUTE . 3 . Attac hth e 66 A Flui dNozzl e utilizin g a5-47 6 Flui d Nozzl e Wrench . D O NO T OVERTIGHTEN . 4 . Inser t th e fluidti p assembly int o th e 6 6 A A Ai r Nozzle . A s a n assembly , threadth e ai r

nozzle-flui dti p assembl

y combinatio n onto th e gun . OPERATIN G INSTRUCTION S 1 . Sinc e th e fluidti p assembl y ha s arelativel y smal l orifice , th e fluidmateria l mus t b e fre e of

larg e parti
cles . Shoul dparticle s b e present i t will b e necessar

y to strain the material . 2 . Set th e fluidpressur e a

t 45-8 0 PSI . Warning : D o 

### no texcee d 10

0 PSI . 3 . Se t th e atomizin g ai

r pressur e a t 5-I 0 PSI . 4 . Th e gun i s no

w read y fo r spraying . 5 . Spra y asampl e product . I

f th e filmi s to o thick , de
creas e the flui

dpressur e o r chang e t o asmaller

Hui dti p assembly . 6 . I f th e degre e of

atomizatio n i s insufficient , i t ma y b e necessar y to increas e the ai

r pressure . D O NOT excee d 3 0 PSI . Increase dai r

pressur e wil l caus e alos s o f transfe r efficiency . Alway s us e the lowest possibl e Hui

d an dair pressures . 

### FLUID TIP

- A \(\- C . A p . -
Paten t Pendin g 

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### .AZARDOU S COMPON_2NTS-(CA S Number ) OSH A'P'EL" ACGIH TL V OTHER

- 

### ' " .CETONE (67-64-1)
- OSH ATW A100 0 pp m ACGI H TW A75 0 ppm , STE L IOO O pp a CETHYL ALCOHO L (67-56-1 ) OSH ATWA20 0 ppm , ACGIH 20 0 ppm , TL V SJO NSTE L 25 0 pp m 'ETROLEU M DISTILLAT E (64742-89-8 ) RECOMMENDE D TW AlOOpp m uUEN E (108-88-3 ) OSH ATW A200ppm* , ACGI H TWAlOOppm , STE L 150pp m •CEILIN G 300pp mACCEPTABL E MAXIMU M PEAK ABOV E TH E ACCEPTANC E CEILIN G CONCENTRATIO NFO R A N8 HOURSHIF T = * SOOpprn FO R 1 0 MINUTES . KCM6 M III , J?HY5I(-ALyeHEt-I(-A L <mftAcTEais-JlC g Oiiaja g Point , N D Meltin g Pomt , N A pecifi c Gravit y(H20=l) , 0.7 9 apo r Press-ore , N D Vapo r Densit y(Air=l) , >i. o vapo r atio n Rat e (BuAcr=i ) , > i olubilit yi n Water , PARTIALL Y ppearanc e an d Odor , CLEA R LIQUID , ALCOHO L T O PETROLEUM ODOR . < 

### , : 

### gGTlO NIV , F IRE AN D EXPLOSIO NHAZAR D DAT A

### — ias n Poin t (Metnoct ) , BSLo W 5 0 FT ~ ~"~* ~ Lammabl e Limits ; Lower , 1 Upper , 3 6 ctinguashin g Media , DR Z POWDER , CARBO NDIOXID E (C02) , "ALCOHOL " FOAM , 3 E WATE R T O COO L CONTAINERS . DANGE R I ALCOHO L MA Y BUR NWIT H A N ^VISIBL E FLAME . 

## yoc LB P'^ CA.-. 

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## Decompositio n o r Byproducts , FRO M FIRE ; SMOKE , CARBO N IOXIDE , CARBONMONOXIDE . azardous.Polymerization , WIL L NO T OCCUR . 2CTI0 NVI , HEALT H HAZAR D "DAT A loOTE S O f

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Pag e 2P.7 7

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## MATERIA L SAFET Y DAT

ASHEE T EMERGENC Y 2 4 HR . PHO N- CH2_MTRE C - 1-8QO-424-9 3 0 0 EKCT L WAS H THINNE R SECTIO NVI , HEALT H J-AZAR D DATA , CONTINUE D ~ 

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### 2-^hronic * V>- ^ •-t~E'i-iTTrm-*-.r-.* i • ' T-r



### - y2E 3 4-Sudde n Releas e o f Pressur e N O 5-Reactiv e NC , ,CL AR Q 8,33 3 (TOLUENE ) •" R Q 20,00 0 (ACETONE ) R Q 27,77 7 (METHANOL ) ardou s Wast e Numbe r D00 1 IGNITABL E Titl e II I YE S Threshol d Plannin g Quantity , NON E • Reportabl e Quantity , NON E Sectio n 313 , Toxi c Materials : Chemica l Nam e CA S Numbe r ACETON E 67<_.$4-_ l METHANO L 67


### _ 56 

### _- l TOLUEN E 108-88- 3 - 

### Weight " 25-30 % 15-20 % <15 % a n Ai r Ac t YES , SECT , il l a n Wate r Ac t YES ; SECT . 304 , 307 , 31 1 C C SUBSTANCE S CONTRO L AC T (TSCA ) , 4 0 CF R 71 0 rce s -ofth e ra wmaterial s use d i n thi s mixtur e assur e tha t al l ilea l ingredient s presen t ar e i n complianc e wit h Sect . .8(b ) nea l Substanc e Inventory , o r ar e otherwis e i n complianc e wit h i . 

### lo t applicabl e : ND-Dat a no t availabl e :ance r Suspec t Agen t OX-Oxidize r COR-Corxosiv e •-Calculate d EST-Estimate d •-Shor t Tim e Exposur e Limi t TLV-Threshol d Limi t Valu e •Permissabl e Exposur e Limi t TWA-Tim e Weighte d Average , 8 hour s ' , PPI-Hazardou s Materia l Identificatio n System , Persona l Protectio n Inde x dat a presente d i s tru e an d correc t t o th e bes t o f ou r knowledg e an d ef , however , neithe r selle r no r prepare r make s an ywarranties , . : - : 

### es s or-implied , concernin g th e informatio n presented . Th e user'i s ibned
- t o perfor m hi s ow n hazar d evaluatio n an d t o rel yupo n hi s ow n ruinations . CWLT0 1 .

For messentiall yth e sam e a s OSH AFor m17 4 Date d Septembe r 19a s Pag e 4 

# "4C pP.7 9 

### 3/6/9 8 PAG E 1/ 4 RightFA X 

## y< -

527-437 0 MATERIA LSAFET

Y DAT A SHEE T
.CTURER' S NAM

E

. SHERWIN-WILLIAM S COMPAN Y

. Prospec t

Avenu e N.W . .veland , O

H 4411 5 ) FPREPARATIO N -MAR-9 8 

### EMERGENC Y TELEPHONE NO , (216 ) 566-291 7

INFORMATIO

NTELEPHONE NO . (216 ) 566-290 2 •- £d<M < 

### ?£
- S"-"- , 

### ' L Sectio n I —

PRODUC T IDENTIFICATIO N : T NUMBE R HMI S CODE S Healt h 3W2327- 4 37 0 Flammabilit y Reactivit y : T NAM E _,ANE * T Plu s Custo m Polyurethan e Enamel , BE NJ . MOOR E #87 9 WHIT E : T CLAS S s e componen t fo r 2-packag e Polyurethan e Coatin g Sectio n I I — 3 1 EN T 5 Nc . HAZARDOU S INGREDIENT S % b yW T 2 3 0

W 1 STE L 2 STE Li-i 

### 7 STE L 6 STE L 4 4 ACGI H TL V 5 0 10 0 15 0 5 0 25 0 31 0 15 0 20 0 1 0 OSH A PE L 10 0 15 0 10 0 15 0 10 0 25 0 31 0 15 0 20 0 15(5 ) UNIT S PP M PP M PP M PP M PP M PP M PP M PP M PP M (Skin ) (Skin )

MG/M 3 a s Dus t V.P .

22.0 0 5.9 0 2.1 4 47.5 0 10.0 0

+ * + 

### ne . 108-88- 3 330-20- 7 1 n-Amy l Ketone , 110-43- 0 opy l Acetate . 108-21- 4 y l Acetate . 123-86- 4 u mCarbonate . 471-34- 1 iu mDioxide . 463-67- 7 ** * Tota l Dus t (Respirabl e Fraction ) 1 9 1 0 10(5 ) MG/M 3 a s Dus t ** * ** * Tota l Dus t (Respirabl e Fraction ) Sectio n II I —PHYSICA L DAT A ODUC T WEIGH T IFI C GRAVITY - OILIN G POIN T ATIL E VOLUM E Theoretical ) - 14.2 8 lb./gal . EVAPORATIONRAT E — Slowe r than Ethe r -1.7 2 VAPO R DENSITY —Heavie r than Ai r 185-30 8 F MELTING POIN T —N.A . 3 7 % SOLUBILITY I NWATE R - - N.A . 2.6 7 lb . 32 0 gm . (les s Federall yExemp t Solvents ) Sectio n IV

—FIR E AND EXPLOSIO NHAZAR D DAT

A POIN T LE L 5 F TC C 1. 0 ABILIT Y CLASSIFICATION D LABE L —Flammable , Flas h belo w100 . F UE L 7 . 9 lOT

Fn. C Au ~ l^.*i% l/O c L

(ii'°*
- G.AC-
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w . w , ww rnu L i.1 1 lil6ill.l'n A 

### F63W2327- 4 37 0 pag e 2 JGUISHIN

G MEDI A irbo n Dioxide , Dr

yChemical , Foa

m JA L FIRE AND EXPLOSIONHAZARD S _e p container s tightl yclosed . Isolat e fromheat , electrica l jment , sparks , an

d ope n flame . Close d container s ma yexplod e whe n 3e d t o extrem e heat . Applicatio n t o ho t .surface s require s specia l autions . During emergenc ycondition s overexposur e t o decompositio n ict s ma ycaus e a healt h hazard . Symptom s ma yno t b e immediatel y rent . Obtai n medica l attention . IA L FIRE FIGHTIN

G PROCEDURE S il l protectiv e equipmen t including self-containe d breathing apparatu s L d be used . Wate r spra ymayb e ineffective . I f wate r i s used , fo g Le s ar e preferable . Wate r mayb e use d t o coo l close d container s t o m t pressur e build-u p an d possibl e autoignitio n o r explosio n whe n .e d t o extreme heat . Sectio n V

—HEALTH HAZAR

D DAT A C S O F EXPOSUR E .posur e ma yb e b

yINHALATIO

Nand/o r SKI No r EY E contact , depending o n Ltion s o f use . T o minimiz e exposure , follo wrecommendation s fo r prope r ventilation , an

d persona l protectiv e equipment . a Healt h Hazard s _T S O F OVEREXPOSUR E rritation o f eyes , ski n an d respiratorysystem . Maycaus e nervou s

_ mdepression . Extreme overexposur e mayresul t i n unconsciousnes s an d Lbl ydeath . 3 AND SYMPTOM S O F OVEREXPOSUR E _adache , dizziness , nausea , an d los s o f coordinatio n ar e indication s c f ssiv e exposur e t o vapor s o r spra ymists . *dnes s an

d itching o r burning sensatio n ma yindicat e ey e o r excessiv e exposure . :A L CONDITION S AGGRAVATE D BY EXPOSUR E i ycaus e allergi c respiratoryand/o r ski n reactio n i n susceptibl e )n s o r sensitization . Thi s effec t ma yb e delaye d severa l hour s afte r *ure . "ENC Y AN D FIRS T AI D PROCEDURE S : INHALED : I f an ybreathing problem s occu r during use, ' LEAVE TH E ARE Aan d ge t fres h air . I f problem s remai n o r occu r later , IMMEDIATELY ge t medica l attention . : o n SKIN : Was h affecte d are a thoroughl ywit h soa p an d water . Remov e contaminate d clothin g an d launde r befor e re-use . : i n EYES : Flus h eye s wit h larg e amount s o f wate r fo r 1 5 minutes .

Ge t medica l attention . : SWALLOWED : Ge t medica l attention . II C Healt h Hazard s ; ingredien t i n thi s produc t i s an IARC , NT P o r OSH Aliste d carcinogen , rclcnge d overexposur e t o solven t ingredient s i n Sectio n I I ma ycaus e :s e effect s t o the liver , urinary , bloo d forming , cardiovascula r an d •ductiv e systems . irsons sensitiv e t o isocyanate s wil l experienc e increase d allergi c :io n o n repeate d exposure . its expose d t o titaniu mdioxid e dus t a t 25 0 mg./m 3 develope d lun g ;r , however , such exposur e level s ar e no t attainabl e i n th e workplace . ;pcrt s hav e associate d repeate d an d prolonge d overexposur e t o solvent s permanen t brai n an

d nervou s systemdamage . mtinue d c n pag e 3 ~y^&P.8 1 W/W / W W I-_-_\_t_

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1 1 1 J

. fill tl " t\I\ 

### F63W2327-437 0 pag e 3 Sectio n V I —REACTIVITY DAT A 3ILIT Y —Stabl e DITION S T O AVOI D >Ion e known . 3MPATIBILIT Y . \ 7 on e known . 

### \RDOU S DECOMPOSITIONPRODUCT S 3 yfire : Carbo n Dioxide , Carbo n Monoxid e \RDOU S POLYMERIZATION 'Jill no t occu r Sectio n VI I —

SPIL L OR LEA

K PROCEDURE S ? S T O B E TAKE NI NCAS E MATERIAL I S RELEASE D O R SPILLE D Remove al l source s o f ignition . Ventilat e an d remov e wit h iner t *>rbent . C E DISPOSAL METHO D 'Jast e fromthi s produc t mayb e hazardou s a s define d unde r th e Resourc e servatio n an

d RecoveryAc t (RCRA ) 4 0 CFR 261 . •Jast e mus t b e teste d fo r ignitabilit yt o determin e th e applicabl e EP A ardou s wast e numbers . [ncinerat e i n approve d facility . Do no t incinerat e close d container . pos e o f i n accordanc e wit h Federal , State , an d Loca l regulation s ardin g pollution . Sectio n VII I —PROTECTIONINFORMATIO N :AUTION S T O B E TAKE NI NUS E •J O PERSONSHOUL D US E THI S PRODUCT , O R B E I NTH E ARE AWHER E I T I S BEIN G } , I F THE Y HAVE CHRONI C (LONG-TERM ) LUN G O R BREATHIN

G PROBLEM S O R I F { EVE R HA

D AREACTIONT O ISOCYANATES . Js e onl ywit h adequat e ventilation . Avoi d breathin g vapo r an d spra y : . Avoi d contac t wit h ski n an d eyes . Was h hand s afte r using . Phi s coatin g maycontai n material s classifie d a s nuisanc e particulate s ste d "a s Dust " i n Sectio n II ) whic h maybe presen t a t hazardou s level s / durin g sanding o r abradin g o f th e drie d film . I f no specifi c dust s liste d i n Sectio n II , the . applicabl e limit s fo r nuisanc e dust s ar e [ H TLV 1 0 mg./m 3 (tota l dust) , 3 mg./m 3 (respirabl e fraction) , OSH APE L ng./m 3 (tota l dust) , 5 mg./m 3 (respirabl e fraction) . PILATIO N joca l exhaus t preferable . Genera l exhaus t acceptabl e i f th e exposur e t c srial s i n Sectio n I I i s maintaine d belo wapplicabl e exposur e limits , sr t o OSHAStandard s 1910.94 , 1910.107 , 1910.108 . PIRATOR Y PROTECTIO

N 'Jher e oversprayi s present , a positiv e pressur e ai r supplie d respirato r L9 C NIOSH/MSH

Aapproved ) shoul d b e worn . I f unavailable , a properl y :e d organi c vapor/particulat e respirato r approve d b yNIOSH/MSH

Afo r zectio n agains t material s i n Sectio n I I ma yb e effective . Follov ; _>irato r manufacturer' s direction s fo r use . Wea r the respirato r fo r th e L e time o f spraying and unti l al l vapor s an d mist s ar e gone . N O PERSON S JL D B E ALLOWE D I NTH E ARE AWHER E THI S PRODUC T I S BEIN G USE D UNLES S CPPE D WIT H TH E SAME RESPIRATO R PROTECTIO NRECOMMENDE D FO

R TH E PAINTERS . •Jhe n sandin g o r abrading th e drie d film , wea r a dust/mis t respirato r roved byNIOSH/MSH

Afo r dus t whic h mayb e generate d fro mthi s product , ;rlyin g paint , o r th e abrasive . Continue d o n pag e 4P.8 2



### F63W2327-437 0 pag e 4 .CTIV E GLOVE S ia r glove s whic h ar e recommende d b yglov e supplie r fo r protectio n is t material s i n Sectio n II . PROTECTIO

N >a r safet yspectacle s wit h unperforate d sideshields . I PROTECTIV

E EQUIPMENT ; e barrie r crea

m o n expose d skin . Sectio n I X - - PRECAUTION S STORAG E CATEGORY

. 

### IUTIONS T O B E TAKE NI NHANDLIN G AN D STORIN

G .ntent s ar e FLAMMABLE . Kee p awa yfro mheat , sparks , an

d ope n flame , irin g us e an

d unti l al l vapor s ar e gone : Kee p are a ventilate d - D o ne t

. - Extinguis h al l flames , pilo t lights , an d heater s - Tur n of f stoves , :ri c tool s an

d appliances , an

d an yothe r source s o f ignition . >nsul t NFP ACode . Us e approve d Bonding an d Grounding procedures . _e p containe r close d whe n no t i n use . Transfe r onl yt o approve d liner s wit h complet e an d appropriat e labeling . D o no t tak e internally , ou t o f the reac h o f children . I 'PRECAUTIONS li s produc t mus t b e mixe d wit h othe r component s befor e use . Befor e Ln g th e packages , READ AN D FOLLO W WARNIN

G LABEL S O NAL L COMPONENTS , ltentiona l misus e b ydeliberatel yconcentrating an d inhaling th e =nt s can be harmfu l o r fatal . Sectio n X —

OTHE R REGULATOR

Y INFORMATIO

N 31 3 (4 0 CFR 372.65C ) SUPPLIE R NOTIFICATIO N

^S No . CHEMICAL/COMPOUND % b yW T % Elemen t L08-88- 3 Toluene . 1 330-20- 7 Xylene . 2 TORNI APROPOSITION6 5 IRNING : Thi s produc t contain s chemical s know n t o the Stat e o f :crni a t o caus e cance r an d birt h defect s o r othe r reproductiv e harm . CERTIFICATION L l chemical s i n thi s produc t ar e listed , o r ar e exemp t fro mlisting , i e TSCAInventory .

i e above informatio n pertain s t o thi s produc t a s currentl yformulated , L s base d o n th e informatio n availabl e a t thi s time . Additio n o f :er s o r othe r additive s t o thi s produc t maysubstantiall yalte r th e jsition an

d hazard s o f th e product . Sinc e condition s o f us e ar e Ld e ou r control , w e mak e n o warranties , expres s o r implied , an d assum e Labilityi n connectio n wit h an yus e o f thi s information .

### 0 [0658 ] P.8 3



### ENVIRONMENTA

L DAT ASHEE T (Certifie d Produc t Dat a Sheet ) TH E SHERWIN-WILLIAM S COMPAN Y 10 1 Prospec t Avenu e N.W . Cleveland , OH 4411 5 06-MAR-9 8 hi s documen t include s al l dat a require d b y4 0 CF R 63.801(a ) fo r a ifie d Produc t Dat a Shee t unde r criteri a specifie d i n 4 0 CF R 63.805(a) . .11 dat a give n belo war e MAXIMU M THEORETICAL VALUE S base d o n the produc t URRENTL Y FORMULATED . Variation s ma yoccu r o n individua l batche s du e t o stment s mad e durin g production . UC T 63W2327- 4 37 0 * - Trad e Mar k OLANE * T Plu s Custo mPolyurethan e Enamel , BENJ . MOOR E #87 9 WHIT E UC T WEIGH T 14.2 8 lb/ga l SPECIFI C GRAVITY 1.7 2 R D CATEGORY (fo r SAR A311/312 ) cut e Fir e FLAS H POIN T 3 5 F TC C

I SAR A I 30 2 I EH S 1 N 1 N 1 N 1 N 1 N CERC .

Y Y N N Y SAR

A 31 3 T C Y Y N N N HAP S 11 2

Y Y N N N Pe t 

### b y W t 1 2 1 7 6 Pe t | b yI 

### Vo l | 3 1 3 1 3 1 1 5 | 1 1 1 TIL E INGREDIENT S oluene . 108-88- 3 ylene . 1330-20- 7 ethy l n-Amy l Ketone , 110-43- 0 sopropy l Acetate . 106-21- 4 -Buty l Acetate . 123-86- 4

.ntinued o n pag e 2 

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### F63W2327-437 0 pag e 2 .TIL EORGANI

C COMPOUND

S (follow s EP

A VO C Dat aSheet ) Coatin g Densit y —_^-^T 4 . 2 8 lb/ga l Tota l Volatile s 

### 18. 7 %. . b ywt , 171 1 g/ 1

37. 0 % b

yvol . Federall yexemp t solvents : Wate r Organi c Volatile s Percen t Non-Volatil e VO C Conten t -p^— 2.6 7 lb/ga l 0. 0 % b yvol . 37. 0 % b

yvol . 63. 0 % b

yvol .
1 . 2 . 2.6 7 lb/ga l 4.2 4 lb/ga l 0.2 3 lb/l b .RDOU S AI R POLLUTANT S 'olatil e HAP S Pound s pe r Gallo n 'olatil e HAP S Pound s pe r Gallo n o f Solid s 'olatil e HAP S Pound s pe r Poun d o f Solid s QUALIT Y DAT

A >ensit yo f Organi c Solven t Blen d 'hotochemicall yReactiv e E DISPOSA

L 0. 0 % b ywt . 18. 7 % b

ywt . 81. 3 % b

ywt . 32 0 g/ 1 tota l 32 0 g/ 1 les s exemp t solvent s 50 8 g/ 1 solid s 0.2 3 kg/kg solid s

0.6 8 lbs/ga l 0.0 4 lbs/l b
7.2 2 lbs/ga l YE S

ast e fro

m thi s produc t mayb e hazardou s a s define d under ' the Resourc e ervatio n an

d RecoveryAc t (RCRA ) 4 0 CF R 261 . ast e mus t b e teste d fo r ignitabilit yt o determin e the applicabl e EPA rdou s wast e numbers .



# :Sz_,P.8 5



### MATERIA L SAFET Y DAT ASHEE T jSA^..W_w^'_*w!»&>'7nj; V 

### DQUCT NAME : FOURSEAL PRIME R HMI S CODES : H F R P HOUCT CODE : 48-900 1 2 * 3 2 G __============== = SECTIO NI - MANUFACTURE R IDENTIFICATION================ = vlUFACTURER' S NAME : LILL YINDUSTRIES , INC . ->RESS : 2833 5 Cla y Street , Elkhart , I N 4651 7 IRGENC YPHONE : (800 ) 424-930 0 INFORMATIO N PHONE : (800 ) 397-106 2 I E REVISE D : 01-03-9 4 NAM E O F PREPARE R : "--=== = SECTIO N I I - HAZARDOU S INGREDIENTS/SAR A II I INFORMATIO N ======== =

j OCCUPATIONA L EXPOSUR E LIMIT S VAPO R PRESSUR E WEIGH T fiOOU i COKPONEKT

S , CA S NUMBE R OSH APE L ACGI H TL

VOTHE R a n H g 6 TEH P PERCENT " O E MONOME

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=-.,_=. = == = = === = SECTIONII I - PHYSICAL/CHEMICA L CHARACTERISTIC S ============ = ILI.N G RANGE : 17 5 t o 29 3 Oe g F SPECIFI C GRAVIT Y (H20=l) : 1. 3 PO R DENSITY : HEAVIE R THA NAI R EVAPORATIO NRATE : SLOWE R THA NETHE R LUBILIT Y I NWATER : Insolubl e PEARANC E AN

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= SECTIO NI

V - FIR E AND EXPLOSIO NHAZAR D DAT A==== = AS H POINT : 2 3 De g F METHO D USED : TC C AhMABL E LIMIT S INAI R BY VOLUME - LOUIER : 1.1 % UPPER : 11.5 % TINGUISHIN

G MEOIA : FOAM , ALCOHO L FOAM , C02 , DR Y CHEMICAL , WATE R FO G E-IAL FIREFIGHTING .PROCEDURE S •_.sd container s aa/

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rself-containe d breathin g apparatus . USUA L FIR E AN D EXPLOSIO N HAZARD S !;t e trot , heat , sparks , electrica l equipaen t and ope n flane . ->*e o container s aa

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n expose d t o eitren e heat . 

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f larg e aasse

s ma yallo wbuild-u p o

f exothermicheat
. -.COMPATIBILIT Y(MATERIAL S TO AVOID ) •i d accidenta l contac

t Nit h peroxides
. •.ZARDOU S DECOMPOSITIO N O R BYPRODUCT S roor . fi.no.id e an

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. -.ZARDOU S POLYMERIZATION : MA YOCCU R 'tt i n a coo l place
. z=- . ================= = SECTIO N V I - HEALT H HAZAR D DAT A===================== = •(HALATIO N HEALT H RISK S AN D SYMPTOM S O F EXPOSUR E :.5s_v e breathin g o

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e sever e irritatio n orburns
. ( I N ABSORPTIO N HEALT H RISK S AN D SYMPTOM S O F EXPOSUR E 'ins'L e prolonge

d exposur e i s no t likel yto resul t i n th e materia l being absorbe d throug h th e ski n i n harofu l anounts . •.GESTIO N HEALT H RISK S AN D SYMPTOM S O F EXPOSUR E -estio n na ycaus e irritatio n o

f the mouth,throa

t an d gastro-intestina l tract . iALT H HAZARD S (ACUT E AN D CHRONIC ) .exposur e ca ncaus e respirator y irritatio nan

dnausea . epeate dexcessiv e exposure s t o hig haoount s nay caus e centra l nervou s systen,live r andkidney effects . ^RCINOGENICITY : NTP ? N O IAR C MONOGRAPHS ? N O OSH AREGULATED ? N O * liste d s s a carcinogen
. EDICA L CONDITION S GENERALL YAGGRAVATE D BYEXPOSUR E ceato d excessiv e exposur e na yaggravat e pre-existin g live ran

d kidne ydisease
. 1ERGENC YAN D FIRS TAI D PROCEDURE S es n ski n thoroughlyuit h soa p an d uater . ius h eye s nit h larg e aoount

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# .&£ "P.8 7

5-900 1 MATERIA L SAFET YDAT ASHEE TPAG E 3 OF ' 3 :======== = SECTIO N VI I - PRECAUTION S FO R SAF E HANDLIN G AN D US E EP S TO B E TAKE N I N CAS E MATERIA L I S RELEASE D O R SPILLE D t.oi' e il l source s of

ignition . Ventilat e th e area . Clea n u p spill s with iner tabsorbentusin g non-sparkin g utensils . '? p outo f drain s .sewers an

d waterways . 1 ST E DISPOSA L METHO D • notflus h t o sewer.watershe d o rwaterway . 5."JS B of i n accordance wit

h loca l .stat e an

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f hea to rignition . Kee

p container s close d whe

n noti n use .
THE R PRECAUTION S > no tLak e internally . * rindustria l us e only . rovn ccontaine rwhe

n pouring t o preven tbuild-u p o f stati ccharge .

================= = SECTIO N VII I - CONTRO L MEASURE S ISPIRATOR YPROTECTIO N Tt vi s exceeded , us e cheaica l respirato rnit h a n organi cvaporcartridg e with prefilte ro ra n air-supplie d respirato r •lit n self-containe d breathin g apparatus . UNTILATIO N ;av / solven tvapor s shoul d b

e reiove d fro n th e lowerlevel s o f th e workin

g area . I

n spra y applicatio n area s engineer n g s*d administrativ e contro l ca n b e institute d t o eaintai n exposure leve l belo vSOpp i forstyrene . ROTECTIV E GLOVE S c-aren e o rpolyviny l alcoho l fo

rrepeate d contact . Y E PROTECTIO N ar'et y glasse s fo rprotectio n agains tspra y orsplashes . THE RPROTECTIV E CLOTHIN G O REQUIPMEN T rsvs-n tprolonge d ski n contac twit h contaiinate d clothing . Was h contaiinate d clothin g befor e reuse . ORK/HYGIENI C PRACTICE S _s h hand s befor e eatin g o

rstoking .
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Y U S Chemica l & Plastics , In c 

### Alco Industries Complies 60 0 NOV ADRIVE S E JjASSILLON . OH^4464 6 (330 ) 830-600 0 FO R CHEMICA

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SECTIO NI - IDENTIFICATIO NO F PRODUCT PRODUC T NAMEiiiOEi'.G.lossjWe t Loo k Hardene r PRODUC T C0DE:^9?-8 ^ :..'•« SYNONY M OR CROS S REFERENCE: t Hardene r an d Activato r fo r Paint s SCHEDUL E B # ; 3815.90.OOOO- O £=9»=3Bssa_-osBaaassasse!9tBiHBiaRssnssSsi!!SHi_iPsacs-Bpass3 ^ SECTIO NI I - HAZARDOU S INGREDIENT S INGREDIENT S n-Buty l Acetat e Ethy l Acetat e Aromati c Hydrocarbon s Hexy l Acetat e WEIGH T % 20-25 % 35-45 % 5-10 % 15-20 % Propylen e Glyco l Monomethy l Ethe r Acetat e Isophoron e Diisocyanat e Hexamethylen e Diisocyanat e 2-Butoxyethy l Acetat e 10-15 % <0.1 % <0.3 % 2-5 % CAS NUMBE R

123-86- 4 K1-7B- 6 64742-95- 6 83230-35- 7 108-65- 6 4093-71- 9 822-06- 0 112-07- 2 TLV/PEL
ACGIH : TLV : IS O pp

m OSH APEL : 15 0 pp

m STEL « 20 0 pp

m ACGIH ; TL

V 40 0 pp m OSH APEL s 40 0 pp

m ACGI H TLV * 2 5 

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### N/ E pp m

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p VAPO R DENSITY : Heavie r tha n ai r EVAPORATIO

NRATE : (Diethyl Ethe r = 1 ) Slowe r tha

n Diethy l Ethe r VOIATILE S B Y HEIGHT : Approximatel y50 % SOLUBILIT

Y INWATER : Miscibl e VOC : 49 2 Grams/Lite r



## SC oP.8 9

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I M 4

Pag e 2 o f 4 (99-3 ) SECTIO NI V

- FIR E AN D EXPLOSIO NDAT E FLAS H PQINT T 2^¥JJ¥E Set a Flas h Close d Cu p LOWE R FLAMMABL E LIMI T % : N/ E UPPE R FLAHHABL E LIMI T % ; N/ E F-CR E fciXTj-HGUISHING MEDIA : Carbo n Dioxide , Dr yChemical , Foam . SPECIA L FIR E FIGHTIN G PROCEDURES : Figh t lik e a fue l oi l fire . Coo l fir e expose d container s wit h wate r spray . Fir e Fighte r shoul d wea r OSHA/NIOS H approve d self-containe d breathin g apparatus . UNUSUA L FIR E AN D EXPLOSIO NHAZARD : (Condition s o f Flammability ) Close d container s expose d t o hig h temperatures , suc h a s fir e condition s ma yrupture . :_i33a-i«_ia)_asC-!3asS5_ir_;3_lari--UMa_i-==s=====^^cr_; s = =;tfti=_;_! _ SECTIO NV

- HEALT H HA_iARD/TOXICOLOGICAL PROPERTIE S OVEREXPOSUR E EFFECTS : ACUT E EFFECTS :

EYE S - Contact wit h eye s ca n caus e irritation , redness , tearing , blurred . vision , and/o r swelling . SKI N- Contac t wit h ski n ca n caus e irritation , (mino r itching , burnin g and/o r redness) , Dermatitis , defattin g ma yb e readil yabsorbe d throug h th e skin . 3*?*HAI_ATIO

N- Inhalatio n o f vapor s ca n caus e nasa l an d respirator yirritation , dizziness , weakness , fatigue , nausea , headache , possibl e unconsciousnes s and/o r asphyxiation . Aspiratio n o f materia l int o lung s ma yresul t i n chemica l pneumoniti s whic h ca n b e fatal . Ma yb e toxic . INGESTIO N- Ingestio n ca n caus e gastrointestina l irritation , nausea , vomiting , diarrhea . CHRONI C EFFECTS: .

Overexposur e t o thi s materia l ha s apparentl ybee n know n t o caus e th e followin g effect s i n la b animals : liver , kidney , lung , blood , an d centra l nervou s syste m damage . Ma ycaus e ski n and/o r respirator ysensitizatio n CARCINOGENI C YE S TERATOGE NYE S MUTAGE NYE S ISOCYANATE

WARNING: 

### X

X X N O N O 

### .N O
ALIPHATI C POLYISOCYANAT E O R POLYMERI C ISOPHORON E DIISOCYANAT E O R POLYISOCYANATE : Repeate d exposur e ma ycaus e allergi c ski n rash , itching, , swelling . Repeate d over-exposure.. . t o isocyanate s ma ycaus e lun g injury , includin g a decreas e i n lun g function , v/hic h ma yb e permanent . Over-exposur e ma ycaus e asthma-lik e reaction s wit h shortnes s o f breath , wheezing , coug h whic h ma yb e permanent o r permanen t lun g sensitization . Thi s effec t ma yb e delaye d fo r severa l hour s afte r exposure . Individual s wit h pre-existin g lun g disease , asthm a o r breathin g difficultie s ma yhav e increase d susceptibilit yt o th e toxicit yo f excessiv e exposure . 1 , 6 HEXAMETKY1EN E DIISOCYANATE : Ma ycaus e temporar yuppe r respirator yand/o r lun g irritatio n wit h cough , difficult breathing , o r shortnes s o f breath . Over-exposur e ma ycaus e asthma-lik e reaction s wit h shortnes s o f breath , wheezing , coug h o r permanen t lun g sensitization . Thi s effec t mayb e delaye d fo r severa l hour s afte r exposure . Prolonge d ski n contac t ma ycaus e chemica l burns . Liqui d splashe s i n th e ey e ma yresult i n chemica l burns . Individual s wit h pre-existin g lun g disease , asthm a o r breathin g difficultie s ma yhav e increase d susceptibilit yt o th e toxicit yo f excessiv e exposures . 

# 3-f .P.9 0

i.' S 'L S 09:5 5 ©60 S 27 4 5-31 3 PB EJOBBER

S 1)00.3/00. 1 Pag e 3 o f

4 (99-8 ) ROUTE S O FEXPOSURE : Inhalation , ski n ipas^Qoa a FIRS T AID : INHALATIO N-I f inhaled , remov e victi mfro mexposur e t o wel l ventilate d area . Mak e him/he r comfortabl ywarm , bu t no t hot . Us e oxyge n o r artificia l respiratio n a s required . Consul t a physician . StOD X - Fo r ski n contact , was h promptl ywit h soa p and exces s water . Consul t a physician . EYE S - Fo r ey e contact , flus h promptl ywit h exces s water . Consul t a physician . INGESTIO N- I f ingested , d o not induc e vomiting . Cal l a physicia n immediately . SECTIO NV I - REACTIVIT Y DAT A STABILITY : stabl e " " CONDITION S T O AVOID : Ope n flames , sparks , heat , electrica l and stati c discharge . INCOMPATIBILIT Y MATERIAL S T O AVOID : Stron g acids , alkalies , oxidizers . HAZARDOU S DECOMPOSITIO NPRODUCTS : Unknow n othe r tha n Carbo n Dioxide , Carbo n Monoxid e an d Carbo n HAZARDOU

S POLYMERIZATION : Wil l no t occur . i = B=====i==-===== = = a = ==±i.ii3=-_==3ei_aaoa3ca3»s_; : SECTIO NVI I - SPIL L AN D DISPOSA L PROCEDUR E SPILLS , LEA K O R RELEASE. * Ventilat e area . Remov e al l possibl e source s o f ignition . Avoi d prolonge d breathin g o f vapor. Contai n spil l v/it h iner t absorbent . Pou r decontaminatio n flui d ove r spill . Typica l decontaminatio n solution s are : 20 % Terglto l TMN10 , 80 % wate r o r 0-10 % Ammonia , 2-5 % detergent , balanc e water. Fo r larg e spills , i t ma yb e necessar yt o us e a respirato r t o kee p exposur e level s belo wTLV/PE L limit s WAST E DISPOSAL : Dispos e o f i n accordanc e wit h local , state , and federa l regulations .

= = = **:-i*i=-i33^«aEO«go a = aaaoo-iita3*:*DiiooBBBnB*pao*:*3=a===-:==c=£= ^ BraBoccaoiin a SECTIO N VI I - PROTECTIO

N INFORMATIO

N RESPIRATOR

Y PROTECTION: . I f

TLV/PE Llimit s ar e exceeded , us e NIOSH/MSH A approve drespirato r t o remov e vapors . Us e a n ai r supplie drespirato r i f necessary . Fo r

isocyanates , us e TC-19 C positiv e pressur e supplie drespirato r o r equivalent . VENTILATION : Us e adequat e ventilatio n i n volum e an dpatter n t o kee p TLV/PELbelo w recommende dlevels . Explosion-proo f ventilatio n mayb e required . PROTECTIV

EGLOVES : T o preven t prolonge dexposure , us e rubbe r gloves , solvent s nui y b e absorbe dthroug hth e skin . EY EPROTECTION : Safet y Glasse s o r goggle s wit hsplas hguard s o r sid e shields . OTHE RPROTECTIV

EEQUIPMENT : Wea

r protectiv e clothin g a s require dt o preven t ski n contact . SECTIO N I X - HANDLIN

GAN D STORAG

EPRECAUTION

S STORAG EAN D HANDLING: Us e v/it hadequat e ventilation . Harmfu l o r fata l i f

swallowe dJ Extremel y flammable . Avoi dcontac t wit heye s an dskin . Avoi dbreathin g vapors . Ma y caus e lun g irritatio n an dallergi c respirator y reaction . D o no t stor e th e produc t

abov e 100°F/38°C . D o no t flame , cut , braz e wel do r mel t empt y containers . Keep th e produc t awa y fro mheat , ope n flame , an dothe r source s o f

ignition . Avoi dcontac t wit hstron g acids , alkalie s an d oxidizers . 

# 8 8P.9 1

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4 (99- 3 SECTIO N X - ADDITIONA

LINFORMATIO

N ^ d = = 3=!_-itf3s a= C£ 3 = '-=scsr c= sBoaaDCiaaDBiiai a SHIPPIN G INFORMATION ; Pleas e compl ywit h OO T regulation s i n US A HMI S RATING : Healt h __2

_4 » Extrem e Eir e 3 3 = Hig h Reactivit yO 2 » Moderat e Persona l Protection - Se e Sectio n VI I 1 » Sligh t O = Insignifican t CALIFORNI APROPOSITIO N65 : Trac e amount s o f som e chemical s know

n t o th e Stat e o f Californi a t o caus e cancer , birt h defect s o r othe r reproductiv e har mma yb e presen t in thi s product . D O HO T FLAME CUT , WELD , O R MEL T EMPT Y CONTAINER S

** £ = s = == : s : £ * s :*£=*::* = ~ ^ :*£: = : = = = : = s ~ ^ = ~=- K :-===- s s ==s s s ABBREVIATIONS : IARC • = Internationa l Agenc yfo r Researc h N/A V = No t Availabl e on Cance r ACGI H * America n Conferenc e o f Governmenta l N/A P • No t Applicabl e Industria l Hygienist s NIOS H ** • Nationa l Institut e o f Occupationa l N/ E = No t Establishe d Safet yan

d Healt h DO T * » Departmen t o f Transportatio n NT P = Nationa l Toxicolog yProgra

m TL V - Threshol d Limi t Valu e PE L = Permissibl e Emission Leve l REFERENCE S 1 . ACGIH . Threshol d Limi t Value s an d Biologica l Exposur e Indice s fo r 1988-8 9 2 . Materia l Safet yDat a Sheet s o f rawmaterial s 3 . Dangerou s Propertie s o f Industria l Materials, ' 7t h Edition , N . Irvin g Sax an

d Richard J . Lewis . PREPARE D BY. * MORTO NPAIN T COMPAN

Y U S Chemica l & Plastics , In c i-Uc o Industries Companies 6C O NOV ADRIV E S E MASSILLON , O H 4464 6 (330 ) 830-600 0 PREPARE D O

NMay9, . 199 5 SUPERCEDE S Januar y13 , 199 4 Th e informatio n i n the Materia l Safet yDat a Shee t ha s bee n compiled fro mou r experienc e and dat a presente d i n variou s technica l publications . I t i s th e user' s responsibilit yt o determin e th

e suitabilit yo f thi s informatio n fo r the adoption o f th e safetyprecaution s a s mayb e necessary . W e reserve th e righ t t o revis e Materia l SafetyDat a Sheet s fro mtim e t o tim e a s ne wtechnica l information become s available . Th e use r ha s th

e responsibilit yt o contac t th e Compan

yt o mak e sur e tha t th e shee t i s th e lates t on e issued .



# ©- ?P.9 2

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4530-11 6 4530-11 3

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# ORGANIC

PEROXIDES Materia l Safet

y Dat a Shee t

El f Atocher

nCode : 12 4
TRADENAM E LUPERSO L DHD- 9 CHEMICA L NAM E Methyl Ethy l Keton e Peroxid e MOLECULARFORMULA

Mixtur e o f C4H10O 4

an dCgH-igO

g Revisio nDate : OV/12/9 5 Sipersede s For

m Dated : 36/1J/9 5 CHEMICA L FAMILYOrgani c Peroxid e SYNONYM S 2-ButBnor* ! Pnroxid e
HA2ARDOU S INGREDIENT S RQ . lbs . XM/ W •Material s o r Component s Methyl ethy l keton e peroxid e structure s 1 0 33. 3 accoun t fo

r 8. 7 • 9.O Xactiv e oxyge n Hexylen e glycol 6. 0 Dimethy l phthalate * SOO O 56. 2 Methy l ethy l ketone * 500 0 1. 0 Hydroge nperoxid e 1. 5 CA S Mo . 13JS-23- « 107-41- 5 131-11- 3 78-93- 3 7722-84- 1 Halpr dDat a

ACGI H STE L = (!-.:

• pp n(Celling ) OSHA TL V = :!! > sp m (Ceiling ) OSHA PEL/TUi* . • 5 mg/ui 3 OSH A PEL/TI M

• 20 0 pp

m OSH A PEL/TUi t • 1 pp

m •Thi s produc t contain s toxi c chemical s subjec t t o th e reportin g requirement s o f sectio n31 3 o f th e Erergcrc y Plannin g and Ccnraxiit

y Rlght-To-Kno w

Ac t o f 198 6 an d o f 4 0 CF R372 . Thi s produc t i s listedo nth e U . S . EPA , TSC A Inventory . A s o f th e dat e o nwhic hthi s MSD S ua s prepared , thos e chemical s ar e no t liste dunder Californi a Propositio n6 5 and ar e na t classifie da s carcinogeni c by IARC , NTP , o r OSHA . SHIPPINGINFORMATION D.O.T . SHIPPIN GNAM

E Organi c Peroxid e Typ e 0 , Liqui d (Methy l ethy l keton e peroxide(s ) S45X ) HAZARD CLASSIFICATIO N 5. 2 I.D . NUNBERUN310 5 FREIGH T CLASSIFICATIO N Chemist s NOtBN IM0 GCOD E PAG E 522 5 PHYSICA L PROPERTIE S MELTING/FREEZINGPOINT , * C Belo w -2 0 HOLECULA RWEIGN T N/ A SPECIFI C GRAVIT Y(Hj O « 1) , 25/25* C 1 .OM O I t in . •S.A.D. T 60 e C , 40 # CUb e •Sel f acceleratin g Decompositio nTemperatur e VAPO RPRESSUR E H/ E VAPORDENSIT Y(Ai r = 1 ) N/ E XVOLATILE S BYVOLUM E M/ E APPEARANC E I

OOORClea r liquid , ketcn e odo r S0LU81LIT YI

N H-J 3 Insolubl e
FIR E ANO EXPLOSIO N

OAT A FLAS H POINT , "C/' F EXTINGUISHINGMEDI A SPECIA L FIR E FIGHTINGPROCEDURES . UNUSUA L FIR E I EXPLOSION

HAZARDS . .66/15 1 Uate r Fog , Dr y Chemical , Foam , Uate r Spra y I f larg e a*oun t i s involved , evacuat e am an d figh t Hr e fro a saf e distance . Coo l curroutdin g Materia l uit h uater . Contamination , Teaperatur e •Ca n deconpos e uit h forc e i f confine d durin g exposur e t o fire . REACTIVIT YDAT

A STABILIT Y Unstabl e CONDITION S CONTRIBUTIN G T O INSTABILIT YTherma l 6eco«tx>sition , contaminatio n INCOMPATIBILITY(avoi d contac t uith ) Stron g acids , stron g alkalis , stron g axiciztsrs , acetone , transitio n meta l salts , promoter s an d reci c n g agent s HAZARDOU

S OECa-tfOSI TIO N PROOUC TS Decompositio n product s ar e f I Burnabl e an d nia- . eutoignit e CONDITION S T

O AVOI D Heat , flrwnes , sparks , ignitio n sources , cc« i laminatio n
Pag e 1 o f 3 

# el f atoche m ZH O El l Atoche m Non h America , Inc
. • Fin e Chemical s Grou p • Organi cPeroxide s • 200 0 Marku t Siree i • Phiiadelpnia , Pfi \ c
. 10 3 322 2 Phon e (800 ) 550-557 5 - Fax : (215 ) 419-741 3 - ">&Mr emergenc yNo : Chemlre c(800 ) 424-930 0P. 3

MATERIA L SAFET YSHEE T LUPERSO L DHD- 9
SPIL L O RLEA K STEP S T O B E TAKEN

IF MATERIAL I S RELEASE D ORSPILLE D Us e absorben t material , swee po r scoo pn > uiir g non-sparkin g tool s an ddispos e o f imnediately . UAST E DISPOSAL METHO O Consul t wit ha nEl f Atoche a representativ e fo r the telephon e nunbe r o f you r state' s hazardou s uast e agency . TOXICIT Y TOXICOLOGICAL INFORMATIO N - Methv l Ethv l Keton e Peroxid e Dat a fro nth e scientifi c literatur e o nmethy l ethy l keton e peroxid e (MEKP ) er e siamarize dbelow . Singl e exposur e (acute ) studie s o n40-60 XMEK P i ndimethy l phthalat e indicate :

Ora l • Moderatel y

toxi c t o rat s (U>so*46 4 ng/kg ) Oerma l - Slightl y

toxi c t o rabbit s (L0 M 4,00 0 ms/fcg ) Inhalatio n- Practicall y non-toxi c t o rat s (4-hr LCgo,17-5 0 mg/L ) Ey e Irritatio n- Corrosiv e t o rabbit s Ski nIrritatio n- Moderatel y irritating t o rabbit s (4-h r exposure , 4.5/8.0 ) Repeate dora l administratio nor intraperitonea l injectio n(7-weeks ) o f MEK P (9 7 mg/kg/day ) ua s reporte dt o resul t Indecrease d bod y ueight , sait

dlive r injury

an ddeat hi nrats . Followin g repeate dski napplicatio n(13-ueeks ) o f MEK P i ndimethy l phthalat t a t dose s up t o 10 7 ag/rat/da y an d35. 7 mg/mouse/day , sever e ski ndamag e andanima l death s (onl y a t th e highes t doi e levels ) wer « th e primar y

effect s i nrat s andmice . Splee nandbon e marro w changes , considere dsecondar y t o th e sever e ski nCMroige , wer e note d i nanimal s a t th e hig hdoses . Highe r dose s Cupt o 81 0 and160 0 mg/kg/da y i nrat s andnice , respectively ) availe dt o ra t an d mous e ski nfo r a shorte r time (2-weeks ) produce dsiaila r effects . Long-term repeate dski napplicatio n(25-iMeks ) o f MEH P I n dimethy l phthalat e wa s reporte dt o enhanc e ski ntumo r productio ni nmic e irradiate dwit hUV8 . MEK P ha s produce dicneti c change s i nstandar dtest s usin g bacteria l o r anima l cells . However , n o geneti c change s occurre di na standar dlos : (bon e marro w micronucleus ) using mic e fro m th e 13-wee k ski napplicatio nstud/ . ECOLOGICA

y INFORMATION

• Methv l Ethv l Keton e Peroxid e Ecotoxicologica l infonnation :

96-h r ICjofiW*/ : M. 2 mg/L , slightl y toxi c Chemica l fat e information :

Methy l ethy l keton e peroxid e (MEKP ) ua s evaluate dfo r biodegradabilit y i na close dbottl e system an j -.'a

s reporte dt o b e readil y

biodegradable . A nECS Q o f 1 6 mg MEKP/ L activate dsludg e ua s reporte dI na nactivate dslutig e respiratio n inhibitio ntest . HEALT H HAZAR D INFORMATIO N POTENTIA L HEALT H EFFECT S • Methv l Ethy l Keton e Peroxid e Ski ncontac t sn dInhalatio nar e expecte dt o b e th s primar y route s o f occupationa l exposur e t o methy l ethy l Keton e peroxid e (KEKP) . MEK P ca nb e destructiv e t o tissue , producing burn s o ncontac t wit han y body tissues . Contac t wit h(h e eye s ca ncaus e sever s irritatio nan dinjury , possibl y wit hlos s o f sight . Whil e swallowin g o f KEK P f s unlikely , i f swallowe dchi s materia l ca n caus e sever s irritatio nsndinjur y t o the mouth , throat , stomac han dliver , live r failur e an drespirator y

distress ; deat hmBy follow . Overexposur e t o MEK P vapor s ma y caus e eye an

drespirator y

trac t irritation , wit hheadach e an ddizzine*:* . Allergi c ski n respons e i s rare , bu t ha s be-e nreporte dfo r MEKP . Thi s materia l i s considered , o nthe basi s o f singl e exposur e (acute ) anima l tests , t o b e moderatel y toxi c afte r ingestion . EMERGENCYFIRS T AID :

INGESTION

D o HO T induc e vomiting . Ge t emergenc y medica l attentio nfor gavage . DERMA L FlusKwit hsoa pan dwater . Ge t medica l attention . EY E CONTAC T IMMEDIATELYflus hwit hplent y o f wate r fo r a t leas t 1 5 ainutea . Ge t ne-iico l attention . INHALATIO

N Remov e t o fres hair . I f no t breathing , giv e artificia l respiration . Ge t i.-.adica l attention . SPECIAL PROTECTION

INFORMATIO

N VENTILATIO N

REQUIREMENTS.. . Us e wit hadequat e ventilation . Loca l exhaust . EY E Safet y glasses , goggles , fac e shield . HAND (Glov e Type ) Heoprene , nitrit e rubber . •RESPIRATO RTYP E Supplie dai r respirato r wit hful l fac e piece , hoo do r helmet . OTHE RPROTECTIV E EQUIPMENT . Eyewas hstation . •Us e onl y

NIOSH/MSHA

approve dequipmen t

Pag e 2 o f 3P. 4 

# ORGANIC

PEROXIDES Materia l Safety Dat a Sheet

MATERIA L SAFET YSHEE T LUPERSO L DHD- 9 LABE L PRECAUTION S PRECAUTIONARYLABELINGUas hthoroughl y afte r handlin g D o no t ge t i neyes , o nski no r clothin g D o no t stor e nea r combustible s Empt y containe r aa y

contai nhazardou s residue s Kee pcontaine r close d Kem pawa y fro a heat , sparks , andflame s O o no t reus e containe r OTHERSTORAG E AN O HANDLIN GCONDITION S Stor e below 100' F (36* 0 t o maintai nactiv e oxyge nconten t PREPARE O BY : ADDRESS : PHONE : Organi c Peroxide s Regulator y 200 0 Marke t Street , Phila. , P A 1910 3 V800-55S-!57 5 NOTES : N/ E • No t Establishe d N/ A * Ho t Applicabl e
El f Atochem

Nort hAmerica , Inc . believe s tha t th * informatio nan d recommende dor m containe dherei nCin:ltdin g dat a an d statements ) ar e accurat e a s o f th e dat e hereof . N O UARRANT YO F FITNES S FO RAN YPARTICULARPURPOSE , WARRANT YO F ^MERCHANTABILITY , O RAN YOTHE RUARRANTY , EXPRES S O H IMPLIED , I S MADE CONCERNINGTH E INFORMATIO N PROVIDE DHEREIN . Th e informatio nprovide dherei n relate s onl y

t o th e apecifi c produc t designate dandma y no t b e vali dWher a suc hproduc t i s use dincombinatio nwit han y othe r material s o r i nany

process . Further , sinc e th e condition * an dmethod s o f ua e o f th e produc t an do f th e in f imatio nreferre d t o herei nar e beyon dth * contro l o f El f Atocham , El f Atoche m expressl y

disclaim s an

y an dal l liabilit y

• • t o an, result s obtaine d o r arising from

any us e o f th e product , or relianc e o nsuc hinformation . 7/12/9 5 <1 )

Pag e 3 o f 3 

# el F atoche m 

# AI O El l Atoche m Nort h America , Inc
. • Fin e Chemical s Grou p • Organi cPeroxide s • 200 0 Marke t Stree t - Philadelphia , P A19103-322 2 Phone : (800 ) 558-557 5 • Fax : (215 ) 419-741 3 • 2 4 Hr
. Emergenc yNo : Chemtre c(800 ) 424-930 0P. 5 

# 10. 

# w ORU H CONPANIE S

213 0 ENERG

Y PAR KDRIVE S T PAUL , M N 5510 8 TELEPHONE : 612-645-9224 FAX : 612-645-945 2

Octobe r 03 , 1997 SAFET Y DIRECTO R CUSTO M FIBERGLAS S MOLDIN G E588 0 LITTL

ERIVERROA D WEYAUWEGA , W

I 5498 3
DEA RVALUE

D CUSTOMER : I N ACCORDANC EWIT H TH EHAZARD COMMUNICATIO N STANDAR D (2 9 CF

R1910.1200 ) FRO M TH E OCCUPATIONA

LSAFETY AN D HEALTH ADMINISTRATIO N (OSHA) . WEAREENCLOSIN GA SAFETY DATA SHEE T (MSDS ) ON TH

EFOLLOWING :

PRODUC T DESCRIPTIO N VENDOR AO C E-010-0 1 ALPHA/OWENS-CORNIN G

TH EMSDS' S SHOUL

D B EUTILIZED FO RTH EEDUCATIO N AN D TRAININ GOFYOU REMPLOYEE S A S T O TH EPROPERTIES , HAZARDS . AN D PROTECTION REQUIREMENT S RELATE D TO TH

EPRODUCT S WHICH YOU PURCHAS EFRO M WORUM COMPANIE S SINCEREL

Y YOURS .

RIC K REMACKE

L MATERIA

LSAFET

Y DAT A SHEE T COORDINATO R



# ./.°2>L * &P. 6

Page : 1 o f 9 Prepared : 1 4 Decembe r199 5 ,",ow.»
. 0 <"""" e MSD S No. : 951 2 UV 1



### MATERIA L SAFET

YDAT A SHEE T 

## Sectio n 1 : Product an d Compan y Informatio n
Produc t Name : E010-0 1 Viny l Este rResi n containin g Styren e Manufacturer : AlphaVOwens-Cornin g L.L.C , P
. O
. Bo x610 , Collierville
. T N 38027-061 0

Telephone : 901-854-280 0 (8am-6p m C Tweekdays)
. Emergenc yContacts :

Manufacture rONL

Y(2 4 HOURS/DAY) : 901-854-2800 , CHEMTRE C (2 4 hours everyday) : 800-424-9300
. CANUTE C (Canad a - 2 4 hours everyday) : 613-996-6666
. Healt h an d Technica l Contacts :

Healt h Issue s Informatio n (8am-5p m CT) : 901-854-2800 , Technica l Produc

t Informatio n (8am-5p m ET) : 519-821-5130
. 

## Sectio n 2 : Compositio n an d Ingredien t Informatio n
Commo n Nam e Chemica l Nam e CAS No
. Wt , % Viny l Este rResi n Epichlorohydrin , Bispheno l A , 36425-15- 7 50-7 0 Methacryli cAci d Polyme r Styren e Monome rViny l Benzen e 100-42- 5 30-5 0 Note: Se e Sectio n 8 of MSD S fo rexposure limi t dat a fo rthes e ingredients
. 

## Sectio n 3 : Hazard s Identificatio n 

# J

J J

Appearanc e an d Odor : Viscou s liqui d wit h a n aromati codor
. PrimaryRoute(s ) o f Exposure : inhalation , skin , eye Potantia l Healt h Effects : ACUT E (shor t term) : Thi s produc t i f inhale d ma

ycaus e uppe rrespirator yirritatio n an d possibl e centra l nervou s syste m effect s includin g headaches , nausea , vomiting , dizziness , drowsiness , lo-; s
N/ A= No t Applicable UID

= No l Determine dP. 7

Page : 2 o f 9 *j<^^*^m-m

Prepared : 1 4 Decembe i H-J9 5 •«•'"••-"-"" • MSD S No. : 951;:VV 1



## MATERIA L SAFET YDAT A

SHEE T o f coordination , impaire d judgment , an d genera l weakness
. I t ma ycaus e dryness , cracking , tendernes s an d irritatio n of th e skin
. Direc t contac t wit h thi s produc

t ma yre s ji t i n immediat e irritatio n t o th e eye s wit h redness , burning , tearin g an d blurre d vision
. I t ma ycaus e mouth , thioa t an d gastrointestina l irritation , nausea , vomiting , an d diarrhe a i f ingested
. Aspiratio n o f materia l i rt o th e lung s ca n caus e chemica l pneumoniti s whic h ca n be fatal
. Se e Sectio n 3 fo rexposur e controls
. CHRONI C (lon g term) : Styren e i s a possibl e cance rhazar d (IAR C Grou p 2B)
. Prolonge d exposur e ma

yresul t i n nausea , los s of appetite , genera l weakness , change s i n bloo d chemistry , an d periphera l an d centra l nervou s syste m activity
. Prolonge d o rrepeate d ski n contact ma yrusul t i n dermatiti s marke d b

yrough , dr

ycrackin g skin
. Prolonge d o rrepeate d ey e exposure s t o vapors ma ycaus e irritatio n t o th e linin g o f th e eyelids
. I n laborator yanimals , chroni cexposur e t o styr= n = at hig h concentration s has bee n foun d t o caus e live rabnormalities , kidne ydamag e an d lun g damage
. I n addition , preliminar yresult s of inhalatio n studie s indicat e tha t laborator yrat s expos e j t o 80 0 pp m styren e vi a inhalatio n showe d evidenc e o f hearin g loss
. Relevanc e t o human s renain s unclear
. Se e Sectio n 1 1 o f MSD S fo radditiona l toxicologica l data
. Medica l Condition s Aggravate d b yExposure : Person s wit h a histor yo f chroni crespirator

ydijn s se , ski n disease , o rcentra l o rperiphera l nervou s syste m disorders ma ybe a t increase d ris k

fo rworsiinin g thei rcondition s fro m exposure t o thi s product
. 

## Sectio n 4 : Firs t Ai d Measure s 

# J

Inhalation : Mov e perso n l o fres h air
. Administe rcardia co rpulmonar yresuscitatio n (CPR ) i f a puls e i s not detectabl e o ri f unabl e t o breathe
. Provid e oxyge n i f breathin g i s difficult
. Obtai n immediat e medica l assistance
. Ey e Contact : Flus h eye s wit h runnin g wate rfo ra t least 1 5 minutes
. See k medica l attentio n immediately
. Ski n Contact : Was h wit h mil d soa p an d runnin g water . See k medica i attentio n i f irritatio n persis:;;
. Ingestion : D o no t induc e vomiting
. Preven t aspiration
. Transpor t t o hospita l immediately
. Not e t o physician : Perfor m gastri clavag e i n accordanc e wit h procedure s fo ringestio n o f petrolour n products
. 

## Sectio n 5 : Fire Fightin g Measure s

Ras h Poin t an d Method : 87° F (3 1 * c) - 97° F (36 * c ) Metho d - Setaflas h Close d Cu p Flammabilit yLimit s (%t : LFL : 0. 9 - Styren e

N/ A= No l Applicabl e N/ D = No t Determine dP. 8

Page : 3 o f 9 Prepared : 1 4 Decembe i 199 5 .t-.A/ow-.-co^NflN o MSD S No.:95i;iV-V 1 

### MATERIA L SAFET

YDAT A SHEE T UFL : 6 8 - Styren e Aut o Ignitio n Temperatur e : 914° F (490 8 C ) - Styren e Extinguishin g Media : Foam , C0 2 o rdr ychemical
. Unusua l Fir e an d Explosio n Hazards : Produc t i s a NFP AClas s 1 C flammable liquid
. Preven t -.stati c an d othe relectrica l sparking
. Ambien t temperature s abov e 77° F (25°C) , o rhea t fro m fir e ma

yc a JS< ; polymerization , hea

t generation , an d vapo rexpansion
. Excessive hea t ma ycaus e close d contairor s t o rupture . Kee p coo l wit h wate rspray . Fir e Fightin g Instructions : Treat as a flammable liqui d typ e fire
. I n a sustaine d fir e wea r self-containe d breathin g apparatu s an d ful l protective bunke rturnou t gear . Hazardou s Combustio n Products : Primar ycombustio n product s are carbo n monoxide , carbo n dioxide , an d lo wmolecula rweigh t hydrocarbons
. Othe rundetermine d compound s coul d b e releas e 1 i n smal l quantities
. 

## Sectio n 6 : Accidenta l Releas e Measure s 

# ]
Release s o f thi s product t o th e land , wate ran d ai rma yrequire reportin g t o local , stat e an d federa l agencies
. Lan d Spill : Preven t materia l fro m enterin g sewer s o rwaterways . Remove al l source s o f ignitio n (flames , ho t surfaces , an d electrica l stati co rfrictiona l sparks)
. Ventilat e area . Absor b wit h iner t material s (vermiculit e o rsand ) an d plac e i n a close d containe rfo rdisposa l a s soli d waste . Was h are a wel l wit h trisodiu m phosphat e an d water . Resi n tha t ma yhav e bee n mixe d wit h peroxid e initiators ; p-io r t o spillag e shoul d b e mixe d wit h iner t materia l an d remove d t o a n ope n area . Allo wtim e t o ge l an d cure . Wate rSpill : Materia l i s mostl yinsoluble
. Th e materia l wil l sin k t o th e botto m leavin g a styren e monome rsheen
. Styren e i s harmfu l t o aquati clif e i n ver ylowconcentrations
. Notif yloca l environmental , healt h an d wildlif e authorities , an d wate rintake operators . Contai n wit h boom s t o minimiz e sprea d o n water . Collect floatin g materia l wit h sorbent s an d vacuum/collect sunke n sol i i s Dispers e an yremainin g residu e t o reduce aquati charm
. Ai rRelease : Spill s ofthi s materia l ma yreleas e styren e an d volatil e organi ccompound s int o th e ai r Spill s shoul d b e cleane d o rcovere d t o preven t volatilizatio n o f styrene . 

## Sectio n 7 : Handlin g an d Storag e 

# J Storag e Temperature : Store below77° F (25°C )

N/ A = No t Applicabl e N/ D = No l Determine dP. 9

Page : 4 of 9 Prepared : 1 4 Decembe r1!)95 flflr..,.*........!.. MSD S No. : 951:!1<-V 1 

### MATERIA L SAFETYDAT ASHEE T Storag e Pressure : N/

A General : Store belo w77° F (25°C)
. Th e storag e drum , whe n emptied , ca n contai n vapor , liqui d c r soli d residue s tha t ma

yb e hazardous
. Kee p awa yfro m heat , sparks , flame s an d direct sunlight
. D O NOTcut , puncture o rwel d o n o rnea rthi s container
. D o not appl yai ro rga s pressure t o thi s con t aire r whic h i s not rate d fo rpressure . Containers shoul d be bonde d an d grounde d durin g transfe ro f material
. I n bul k

storage , chec k

ven t an d flam e arresto rfo rpluggin g b yformatio n o f polymer
.

; : 

## Sectio n 8 : Exposure Control s an d Persona l Protectio n Ingredien t OSH APE L ACGI H TL V Viny l Este rResi n Non e Establishe d Non e Establishe d Styren e Monome r10 0 pp m (8-h rTWA) 5 0 pp m (3-h rTWA ) 20 0 pp m (ceiling ) 10 0 pp m (STEL ) 60 0 ppm , 5 minute s i n an y(ski n notation ) 3 hrs
. (peak

) Engineerin g Controls : Genera l dilutio n ventilatio n and/o rloca l exhaus t ventilatio n shoul d be pr e vide d a s necessar

yt o minimiz e exposures . Persona l Protection : Respirator yProtection : I f irritatio n occurs , o ri f th e TLV o rPE L i s exceeded , us e a NIOSH/MSH A approve d ai rpurifyin g respiratorwit h organi cvapo rcartridge s o rcanisters , o rsupplie d ai r respirators
. Us e respirator yprotectio n i n accordanc e wit h you rcompany' s respirator yprotectia n program , loca l regulations , o rOSH Aregulation s unde r2 9 CF R 1910.134
. Ski n Protection : Wea rlon g sleeve d shirt , lon g pant s an d chemica l resistan t glove s suc h a s polyviny l alcohol , polyethylen e o rviton
. Eye Protection : Chemica l protectiv e goggle s and/o rfac e shiel d mus t b e wor n wheneve rpossibility exist s fo rey e contact . Work/Hygieni cPractices : Handl e i n accordanc e wit h goo d industria l hygien e an d safet ypractice s Thes e includ e avoidin g unnecessar yexposure s an d prope rselectio n an d us e o f persona l protec t v e equipment
. Launde rcontaminate d clothin g befor e reuse . Safet yshowers an d ey e was h station s shoul d b e available
. Us e explosio n proof motors an d equipment
. Containers shoul d b e grounde d and/o rbonde d whe n materia l i s transferred
. 

## Sectio n 9 : Physica l an d Chemica l Propertie s 

# J

N/ A= Not Applicabl e N/ D = No t Determine dP.1 0

/K { I f Page : 5 o f 9 ff VI - 1 1 , Prepared : 1 4 Decembe i 1!39 5 ' l '"""""" ' "••" " MSD S No. : 951:'
. W-V1



## MATERIA L SAFET YDAT A

SHEE T Vapo rPressur e (m m H g (S > 20°C) : N/D Vapo rDensit y(Air=1t : N/ D Specifi cGravit y(water=1) : 1. 1 Boilin g Point : >95° F (>35°C ) Solubilit yi n Water : Insolubl e Viscosity : 1 0 -100 0 mPa s fit!: N/ APhysica l State : Liqui d Appearance : Viscou s liqui d Freezin g Point : Not Availabl e Odo rType : Aromati c Evaporatio n Rate/n-Buty l Acetate=1) : N/D 

## Sectio n 10 : Stabilit

y an d Reactivity 

# 1

General : Stabl e below77° F (25"C ) Incompatibl e Material s an d Condition s t o Avoid : Peroxides , oxidizers , acid s an d bases
. Amt'ie i i t temperature s ove r77° F (25°C) , o rheat fro m fir e situation s ma ycaus e polymerization , heat generation , an d vapo rexpansion
. Ma ycaus e close d containe rto rupture . Hazardou s Decompositio n Products : Oxide s of carbo n an d lo wmolecula rweigh t hydrocarbons;
. Se e Sectio n 5 o f MSD S fo rcombustio n product s statement . Hazardou s Polymerization : Ma yoccur . Avoi d excessiv e heat , contaminatio n an d prolonge d storag e abov e 77° F (25°C)
. 

## Sectio n 11 : Toxicologica l Informatio n CARCINOGENICITY : Th e ingredien t a s a carcinogen : Inaredien t Viny l Este rResi n Styren e Monome r followin g tabl e indicate s whethe r ACGI H N o N o IAR C

N o Ye s o rno

t eac h NT P N o N o agenc

yhas liste d eac h OSH A N o N o 

# J

N/ A= No l Applicabl e N/D = No t Determine d 

## /PSP.1 1 

# AD C

* l PIIA/OWGMC*>CORNIN a

TOXICITY : Ingredien t Page : i 5 c f 9 Prepared : 1 4 Decembe r199 5 MSD S No. : 951214V 1 

### MATERIA L SAFET

YDAT A SHEE T

LD ^ Ora l (g^g ) LD M Derma l

(g/kg ) Viny l Este rResi n Not Availabl e Not Availabl e Styren e Monomer5. 0 (rat ) Not Availabl e 2 4 (rat ) L-C a Inhalatio n (g/m 5

. 4 hrs. ) Not Availabl e Styren e Monomer : I n March , 1987 , th e Internationa l Agenc yfo rResearc h o n Cance r(IARC ) reclassifie d styren e a s possibl ycarcinogeni ct o huma n (Grou p 2B ) du e t o "inadequat e evidenc e i r humans" , "limite d evidenc e i n animals " an d "othe rrelevan t data"
. Previously , styren e wa s classifiu d a s a Grou p 3 compoun d (no t classifie d a s t o carcinogenicit yt o humans)
. Th e IAR C workin g grou p determine d tha t th e weigh t o f dat a o n geneti can d relate d effects , togethe rwit h th e consideratio n tha t styren e metabolize d i n human s an d animal s t o styren e oxid e fo rwhic h ther e i s sufficien t evidenc e o f carcinogenicityi n experimenta l animal s an d has bee n classifie d b yIAR C a s probabl ycarcinogeni ct o human s (Grou p 2A) , wa s sufficien t reaso n t o recommen d th e chang e i n classification
. 

# J

J Sectio n 12 : Ecologica l Informatio n
Thi s product ma

ycaus e har m t o animals , plant s o rfish
. 

## Sectio n 13 : Disposa l Consideration s
RCR AHazar d Class : Characteristi chazardou s wast e (D001 ) du e t o ignitability
. 

## Sectio n 14 : Transport Informatio n
DOTShippin g Names : Resi n Solutio n Hazar d Clas s o rDivision : 3 Identificatio n No. : UN186 6 Label(s ) require d (i f no t excepted) : Flammabl e Liqui d Specia l Provisions : B1.B5 2 Secondary : non e Packin g Group : II I Packagin g Exceptions : 173.15 0 N/ A= No t Applicable N/

D = No t Determine

d 

# ,/o^P.1 2

J \ | I f Page : 7 o f 9 ff \LJL M Prepared : 1 4 Decembe r199 5 U„.,.W.K..».. 1 « MSD S No . 9 51i: v.v i 

### MATERIA L SAFET

YDAT A SHEE T T7
. T3 0 Non-bul k Packaging : 173.20 3 Bul k packaging : 173.24 2 EP AHazardou s Substances : Styren e EQ : 100 0 lb s Quantit yLimitations : Passenge rAircraft : 6 0 liters Carg o Aircraft : 22 0 liter s Marin e Pollutants : Styren e monomer , inhibite d Freigh t Description : Plasti cliquid , NO I (NMFC ) Hazardou s Materia l Shippin g Description : Resi n solution , 3
. UN1866 , P G III
. R Q Monomer) , Marin e Pollutan t (Styren e monomer) ER G Number : 2 6 

## Transportatio n of Dangerou s Good s - Canad a Prope rShippin g Name : Resi n Solutio n TD G Hazar d Classification : (Primary) : Clas s 3 (Secondary) : Non e IM O Classification : Clas s 3. 3 ICAO/IATAClassification : 3 Produc t Identificatio n Number : UN186 6 Packin g Group : II I Contro l Temperature : Non e EmergencyTemperature : Non e Schedul e XI I Quantit yRestriction : Non e Reportabl e Quantit yfo rU S Shipments : 100 0 lbs
. (Styrene ) IAT APackin g Instructions : Passenger/Cargo : 30 9 Carg o Only : 31 0 Limite d Quantity : Y30 9 Maximu m Ne t Quantit ype rPackage : Passenger/Cargo : 6 0 liters Carg o Only : 22 0 liters Limite d Quantity : 1 0 liters

N/ A= Nol Applicable N/

D = No t Determine

d 

### y/oP.1 3



## / \ P"" 1 P ~ Page : 8 o f9 f ^ * " - Prepared : 1 4 Decembe i 1U9 5 .I...IA,OW^..O 0 .H.»<
. MSD S No. : 951:!1<IV 1



## MATERIA L SAFET YDAT A

SHEE T Specia l Provisions : Non e 

## Sectio n 15 : Regulator

y Informatio n 

# J

TSC AStatus : Eac h ingredien t i s o n th e Inventory
. NS R Statu s (Canada) : Eac h ingredien t i s o n th e DSL
. SAR ATitl e III : Hazar d Categories : Acut e Health : Ye s Chroni cHealth : Ye s Fire Hazard : Ye s Pressure Hazard : N o ReactivityHazard : Ye s Reportabl e Ingredients : Sec
. 302/304 : Styren e Sec
. 313 : Styren e Californi a Propositio n 65 : Styren e oxid e i s liste d a s know n t o th e Stat e of Californi a t o caus e cuneer . Styren e oxid e i s a metabolit e of styren e monomer . Clea n Ai rAct : Styren e i s liste d a s a hazardou s ai rpollutant
. WHMI S ( Canada): Status : controlle d produc t WHMI S Classifications : B2 - flammabl e liqui d D2A- possibl e carcinoge n 

## Sectio n 16 : Othe r Informatio n 

# J

HMI S 2 3 1 NFP

A 2 3 1 HMI S an d NFPAHazar d Rating : Cajfifloj y Acut e Healt h Flammabilit

y Reactivit y NFPAUnusua l Hazards : None
. HMI S Persona l Protection : T o b e supplie d b yuse rdependin g upo n use . Prepare d by : Safet

yan d Environmenta l Service s Department , Alpha/Owens-Corning
. L.L. C Revisio n Summary : Thi s i s a n origina l MSD S prepare d Decembe r14 , 1995
. Rea d thi s informato r carefully
.
N/ A = No t Applicabl e N/

D = No t Determine

dP . M

of Wixoos a

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## n4P.1 7

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### />6 ~P.1 8 

# ORGANIC

PEROXIDES Materia l Safety Dat a Shee t

El f Atoche m Code : 12 4

TRADENAM E LUPERSO L DHD- 9 CHEMICA L NAME Methy l Ethy l Keton e Peroxid e MOLECULA

R FORMUL

A Mixtur e o f C4H10O4 en d C-aHigOf l Revisio n Date : 0,712/9 5 Supersede s For m Dated : 36/13/9 5 CHEMICAL FAMIL

YOrganii ; Peroxid e SYNOMYN

S 2-6utanor> ! Peroxid e

HA2AR00U S INGREDIENT S Hazar d Dat a ACGI H STE L = Cl.:! : pp m (Ce l I ing ) OSH A TL V = :!!> -jp « (CeilIns ) OSH A PEl/TUi t •5 ir-a/B V OSH A PEL/TW

A « 20 0 pp

m OSH A PEL/TWi* . •1 pp n *Thi s produc t contain s toxi c chemical s subjec t t o th e reportin g requirement s o f sectio n 31 3 o f th e Erergcrc y Plemin g an d Comunit y Right-To-Kno wAc t o f 198 6 an d o f 4 0 CF R 372 . Thi s produc t i s liste d o n th e U . S . EPA , TSC A Inventory . A s o f th e dat e o n uhic h thi s MSO S ua s prepared , thos e chemical s ar e no t liste d unde r Californi a Propositio n 6 5 an d ar e no t classifie d a s carcinogeni c b y IARC , NTP , o r OSHA . SHIPPIN G INFORMATIO N Material s o r Component s Methy l ethy l keton e peroxid e structure s accotn t fo r A. 7 - 9.O Xactiv e oxyge n Hexylen e glyco l Dimethy l phthalate * Methy l ethy l Icetone * Hydroge n peroxid e ft Q - I••*>? • 1 0 500 0 500 0 S_»/ H

33. 3 6. 0 56. 2 1. 0 1. 5 CA

S Uo . 1JJ8-Z3- 4 107-41- 5 131-11- 3 78-93- 3 7722-84- 1

D.O.T . SHIPPIN G NAM E Organi c Peroxid e Typ e D , Liqui d (Methy l ethy l keton e peroxide(s ) S45X ) HAZAR D CLASSIFICATIO N 5. 2 I.D . NUMBE

R UH310 5 FREIGHTCLASSIFICATIO N Chemist s N0IB N IMO G COD E PAG E 522 5 PHYSICA L PROPERTIE S MELTING/FREEZIN G POINT , * C Belo w-2 0 HOLECULA

R WEIGH TH/ A SPECIFI C CRAVITT(Hj O « 1) , 25/25° C 1.O84 0 Min . •S.A.D. T 60T , 40 #Cii x •Sel f acceleratin g Deccnpositio nTemperatur e VAPO RPRESSUR E N/ E VAPO RDENSIT Y(Ai r = 1 ) M/ E X VOLATILE S B

YVOLUM E N/ E APPEARANC E & ODO RClea r liquid , keton e odo r SOLUBILIT YI

N H~p Insolubl e FIR E AH DEXPLOSIO N

OAT A FLASH POINT , "C/' F EXTINGUISHIN G MEDI A SPECIA L FIR E FIGHTIN G PROCEDURES. UWUSUA L FIR E i

EXPLOSIO N HAZARDS . .66/15 1 Uate r Fog , Dr y Chemical , Foam , Wate r Spra y I f larg e aaoun t i s involved , evacuat e ari a sn d figh t fir * fro n aaf e distance . Coo l surrowJin g nateria l wit h uater . Contamination , Teaperatur e - Ca n decompos e uit h forc e i f confine d durin g exposur e t o fire . REACTIVITYDAT

A STABILITYUnstabl e CONDITION S CONTRIBUTIN G T O INSTABILIT YThen« l deco«t»sition , contaminatio n INCOMPATIBILITY(avoi d contac t with ) Stron g acids , stron g alkali** , stron g oxicinirs , acetone , transitio n meta l salts , promoter s an d reci c n g agent s HAZARDOU

S DECOMPOSITIO N PROOUCT S Decompositio n product s ar e flomnrabl e an d nia - autoignit e CONDITION S T

O AVOI D Keat , flames , sparks , ignitio n sources , cc*v:aminatio n
Pag e 1 o f 3 

# el f atoche m 

# AI O
El l Atoche m Nort h America . Inc . •Fin e Chemical s Grou p •Organi c Peroxide s •200 0 Marke t Stree t •Philadelphia , P/ * i?10 3 322 2 Phone : (800 ) 558-557 5 •Fax : (215 ) 419-741 3 •2 4 Hr . Emergenc y No : Chemtre c (800 ) 424-930 0P.1 9

MATERIA L SAFET

YSHEE T LUPERSOL DHD- 9 SPIL L O R LEAK STEP S T O B E TAKE N

IF MATERIAL I S RELEASE D ORSPILLE D Us e absorben t material , suee po r scoo pc pUiir- 9 non-sparkin g tool s and dispos e o f imnediately . WAST E DISPOSAL METHO O Consul t uit ha nEl f Atoche a representativ e fo e the telephon e numbe r o f you r state' s hazardou s wast e eg-mcy . TOXICIT Y TOXICOLOGICAL INFORMATION - Methv l Ethv l Keton e Peroxid e Dat a fro

m th e scientifi c literatur e o nnethy l ethy l keton e peroxid e (MEKP ) ar e summarize dbelow . Singl e exposur a (acute ) studie s o n40-60 XMEK P i ndimethy l phthalat e indicate :

Ora l • Moderatel y

toxi c t o ret s (LD*jn48 4 ng/kg ) Oerna l - Slightl y

toxi c t o rabbit s (L0 M 4,00 0 mg/kg ) Inhalatio n- Practicall y non-toxi c t o rat s (4-h r LC5017-5 0 ng/L ) Ey e Irritatio n- Corrosiv e t o rabbit s Ski nIrritatio n- Moderatel y Irritating t o rabbit s (4-h r exposure , 4.5/9.0 ) Repeate dora l adWn i strat i o no r intraperitonea l injectio n< 7-weeks ) o f MEK P (9 7 mg/kg/day ) wa s reporte dt o reiu l t i ndecrease d bod y weight , B

t I dlive r Injury

an d deat hfnrats . Followin g repeatedski napplicatio n(15-weeks ) o f MEK P i ndiwthy l phthalat i a t dose s i pt o 10 7 •g/rat/da y and 35. 7 ag/mouse/day , sever e ski ndamag e and aniata l death s (onl y a t th e highes t doi e levels ) wer e th e primar y

effect s i nrat s an

d mice . Splee nen

dbon e Marro w

changes , considere dsecondar y t o th e sever e ski nct-mige , wer e note d i nanimal s a t th e hig hdoses . Highe r dose s (t p t o 81 0 and 1-BO 0 ng/kg/da y

i nrat s an d nice , respectively ) allie dt o ra t an d mous e ski nfo r a shorte r tim e (2-weeks ) producedsiaila r effects . Long-ter nrepeate dski napplicatio n(25-i«:eks ) o f MEK P In dimethy l phthalat e wa s reporte dt o enhanc e ski ntumo r productio ni nnic e irradiate dwit hUVB . MEK P ha s produce dtene t ic change s i nstandar dtest s usin g bacteria l o r anima l cells . However , n o geneti c change s occurre di na standar dH.'s : (bon e marro w micronucleus ) usin g nic e frc nth e 13-wee k ski napplicatio nstud/ . ECOLOGICA

L INFORMATIO

N • Methv l Ethv l Keton e Peroxid e Ecotoxicologica l Information :

96-h r LCsoguppy : 44. 2 mg/L , slightl y toxi c Chemica l fat e information :

Methy l ethy l keton e peroxid e (MEKP ) wa s evaluate dfo r biodegradabilit y I na close dbottl e syste a and vas reporte dt o b e readil y

biodegradable . A nECsoo f 1 6 mg MEKP/ L activate dsludg e we s reporte di na nactivate dslucig

e respiratio n inhibitio ntest . HEALT H HAZARD INFORMATIO N POTENTIA L HEALT H EFFECT S • Methv l Ethy l Keton e Peroxid e Ski ncontac t and inhalatio nar e expecte dt o b e th e primar y route s o f occupationa l exposur e t o methy l ethy l keton e peroxid e (KEKP) . MEK P ca nbe destructiv e t o tissue , producin g burn s o ncontac t wit han y body tissues . Contac t wit hlh e eye s cancaus e sever e Irritatio nand injury , possibl y wit hlos s o f sight . Whil e swallowin g o f MEK P i s unlikely , i f swallowe dI'ht s materia l ca n caus e sever e irritatio nand injur y t o the mouth , throat , stonac hand liver , live r failur e an d respirator y

distress ; deat haay follow . Overexposur e t o MEK P vapor s ma y caus e ey e an

d respirator y

trac t irritation , wit hheadach e an d dlzzine*:* . Allergi c ski n respons e i s rare , bu t ha s bee nreporte dfo r MEKP . Thi s materia l i s considered , o nth e basi s o f singl e exposur e (acute ) anima l tests , t o b e moderatel y toxi c afte r ingestion . EMERGENCYFIRS T AlD l

INGESTION

D o HO T induc e vomiting . Ge t emergenc y medica l attentio nfo r gavage . DERMA L flusiTwit hsoa pand water . Ge t medica l attention . EY E CONTAC T IMMEDIATELYflus hwit hplent y o f wate r fo r a t leas t 1 5 minutes . Ge t nwiica l attention . INHALATION

Remov e t o fras hair . I f no t breathing , giv e artificia l respiration . Ge t lasdiee l attention . SPECIA L PROTECTION

INFORMATIO

N VENTILATIO N

REQUIREMENTS.. . Us e wit hadequat e ventilation . Loca l exhaust . EY E Safet y glasses , goggles , fac e shield . HAND (Glov e Type ) Neoprene , nitril e rtiaber . •RESPIRATO RTYP E Stpplle dai r respirato r wit hful l fac e piece , hoo do r helmet . OTHE RPROTECTIV E EQUIPMENT . Eyewas ha ta t ion . •Us e onl y

NIOSH/MSK

A approvedequipmen t

Pag e 2 o f 3 

## / '.JP.2 0 

# ORGANIC

PEROXIDES Materia l Safety Dat a Sheet

MATERIA L SAFET YSHEE T LUPERSO L DH0- 9 LABE L PRECAUTION

S PIE-CAUTIONAR

YLABELING .

OTHE R STORAG

E AN O HANDLIN G CONDITIONS. Was h thoroughl y afte r handlin g D o no t ge t i n eyes , o n aki n o r clothin g D o no t stor e nea r combustible s Empt y containe r aa

y contai n hazardou s residue s Keep containe r close d Keep awa

y frc m heat , sparks , an d fl i O o no t reus e containe r Stor e belo

w100* F (3-8'C ) t o maintai n activ e oxyge n conten t
PREPARE D BY : Organi c Peroxide s Regulator y ADDRESS : 200 0 Marke t Street , Pttlta. , PA 1910 S PHONE : 1-B00-55S-:57 5
NOTES : N/ E • No t Establishe d

N/ A » Ho t Applicabl e
El f Atoche m

Nort hAmerica , Inc . believe s tha t th a Infonaatio nan d recoaamndation s containe dherei n(inrlidin g dat a an d statements ) ar e accurat e a s o f th e dat e hereof . M O UARRANT YO F FITNES S FORANYPARTICULARPURPOSE , UARRANT YO F ^MERCHANTABILITY , O RAN YOTHE RUARRANTY , EXPRES S O RIMPLIED , I S MADE CONCERNIN GTH E INFORMATIO

N PROVIDE D HEREIN . Th e informatio njfovlde dherei n relate s onl y

t o the apecifi c produc t designate dan d ma y no t b e vali dwher e aud i produc t i s use dinccafeinato nwit han y othe r material s o r i nan

y process . Further , ainc e th e condition s an d method s o f ua e o f th e produc t an d o f th e inf creatio nreferre d t o herei nar e beyon dth e contro l o f El f Atocham , El f Atoche m expree a I y

dis c l a ia a an y

an dal l liabilit y

• • t o -trt, n-sult t obtaine d o r arisin g fro

m an y us e of th e produc t o r relianc e o nsuc hinforamtlon . 7/12/9 5 O )

Pag e 3 o f J 

# el F atoche m ZKI O E H Atoche m Nort h America , inc . •Fin e Chemical s Grou p •Organi c Peroxide s •200 0 Market Street - Philadelphia , P A 19103-322 2 Phone : (800 ) 558-557 5 •Fax : (215 ) 419-741 3 •2 4 Hr . Emergency No : Chermre c (800 ) 424-930 0P.2 1 

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