OAR Box 1413 

Prepped by Ollie Stewart 

Document Number: 

82) 11-1-83 

Docket Number: 

A-94-52 

Printed 7/9/2008 3:11:24 PM Sheet 82 of 114 

P.1 
P.2 

State of Wisconsin \ DEPARTMENT OF NATURAL RESOURCES 

Tommy G. Thompson, Governor 

George E. Meyer, Secretary 

William R. Selbig, Regional Director 

Oshkosh Service Center 

905 Bay Shore Drive 

P.O. Box 2565 

Oshkosh, Wisconsin 54903 

Telephone 920-424-3050 

FAX 920-424-4404 

August 25, 1998 

Madeleine Strum 

US EPA OAQPS ESA 

MD13 

Research Triangle Park, NC 27711 

Dear Ms. Strum: 

m'? ? 

PPA 4,1**. r\ u".K. 

SUBJECT: Custom Fiberglass Moldings, Inc. 

I Have enclosed to Wisconsin Operation Permit Application for Custom Fiberglass Molding, Inc. They are located 

in Weyauwega, Wisconsin, an attainment/unclassified area for all pollutants. 

You really didn't decide whether you wanted to add the facility to your database or not so I'm sending the 

application and if you decide not to use it you can trash it. 

I want to tank you for your time on the phone. 

Sincerely, 

&^ijf1JH,Jf^ r- Jy > 

Craig T. Steiwler, P.E 

Air Management Engineer 

Oshkosh Service Center 

(920)424-3050 

Quality Natural Resources Management 

Through Excellent Customer Service 
P.3 

: of Wisconsin 

irunent of Natural Resources 

• INSTRUCTIONS ON REVERSE SIDE 

^Uit)|nffie!and 

mailing: address 

Eacflity^ccEuiqn 

Parent corporation 

Responsible 

official 

Pen__Jt?cicm^tfpa*siSn 

FACILITY ©ENTTFICATION 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-100 11-93 Infonnation attached? _ (y/n) 

Name 

Stre£t^ 

C^S^;|Zip^oBe 

Strict Address 

i^I|GoSty 

Name 

Street or Route 

City, State, Zip Code 

Country (if not U.S.) 

Name 

Telephone 

Name 

l a(T/iM rinp-ft/^ a Mn<i-.i,:)c J'.:-.. 

E ^R&O t iTTLr ri(Uf.\ ."-. C . 

fl x 26n t cm r n ur. . i'i o 

i,-)f^Aw\.)F(^x y L)AL4fij.fA 

flit * D/C/HKn 

P ArT CM-) I'^T. 

°\ 3. 0 - 8 L -i 'J. (. i. o 

Da*'*. 

Title DI-^FCTQ^ pc t.ArrT-j A,ox-\ h\fi ii.rre. 

one 

SKgcoaif: ^ Q Cj Ox 

^ P - 2 lal - 7^ 0 

Ejuajita|^^ ^JLLD. '-yQjX-^O-a ^ J J 

Primaiy activity of the operating establishment f)no0or ,„ r F , ,i.rA QCA%i PAKTS: 

T^piplperfflt "'/' /x"' 

D Construction pennit I 

Anticipated start date for construction: 

Anticipated start date for operation: ^T/U PftA*-*^ Si 

This application is requesting an expedited 

review (see instructions) 

Operation Permit 

• Part 70 Source Application 

Jfe^Non - Part 70 Source Application 

• Synthetic Minor, Non - Pan 70 

Source Application 

• Yes JtlSfNo 

D Elective operation permit 

. If facility is located in an area designated as "nonattainment", indicate the pollutant for the 

nonattainment designation. 

ATTA INMFrvTT A Wc-A 

., List all air pollution permits and orders issued to this facility. 

^Th^flxZ /WLxZ AJO A\(L pOlAUTWlO PfilH.T S /S^gft . 

^ 
P.4 

: of Wisconsin 

inmeni of Natural Resources 

FACILITY PLOT PLAN 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-101 11-93 

of this form is required by the Department for any air pollution control pennit application filed pursuant to s. 144.392 or 

.3925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

sss you complete and submit this form. It is not the Department's intention to use any personally identifiable information fra;: 

form for any other purpose. 

irder for a comprehensive air quality analysis to be accomplished, a facility plot plan MUST be included with the pennit 

lication. This facility plot plan must include all of the following items or the pennit application will be deemed incomplete: 

FOR DEPARTMENT USE ONLY 

.OMPLETE INCOMPLETE NOT APPUCABLE 

• • 

• 

• 

• 

D 

• 

• 

• 

• 

• 

• 

• 

• • 

2

-*^__j*}-'*-.'^-r**>-**'*-i*-' -.^ "»«v • v*^«*"v / «^'^>- t ^rf. <W j w»^', ^ ^*^»»*yr&^<*#*-<m-^94ri*xx.y.%r-vy, 

. -The -maximum heightof e^<ound-nriexcludingfstaclc height)! 

J>TM_TM»VWX 1 *A_„W_. « :.>)/A/__iyuMM»^'M«W.'>\«--^v.vlnwM^££v ^ 

gHdeiiiifyfrdirect-^jf^^ 

»?-f^-)*-$*«^_,%-tf-*.*-K*^a-^^ 

y.^TadditionaBgegionalinw^ 

2^uxroundmgma__Jiy^roa^^ 

there any outdoor storage piles on the facility site? 

, what material does the pile(s) consist of? 

• Yes X No 

there any dirt roads or unpaved parking lots on the facility site? 

* 

Yes • No 

2L 
P.5 

f Wisconsin SOURCE AND SITE DESCRIPTIONS 

ment of Namral Resources AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-102 11-93 Infonnation attached? _(y/n) 

>f this form is required by the Department for any air pollution control pennit application filed pursuant to s. 144.392 or 

925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

s you complete and submit this form. It is not the Department's intention to use any personally identifiable information from 

orm for any other purpose. 

Briefly describe the proposed project or existing JJnit(s) to be permitted. Attached supplemental forms as needed. 

C CiSTC-A f 113 IT ILGt A*. S P-AOL OIKJC /$ A ro fSjiiSTIroc MANO. r*£Tut\.c 0 F /. u TUpc\~ 

Aloi) SIZES OF /"-iGl-'lfccvr pArxTSj DlSTfliduTirQ T h liu c<--T T h £ k-S A AI 0 OU_T.J_ 

5£AS. JX rJ Thi. rAbtr,oF4tTt*t\i-tot pilot ers ij € Ui € /lESWi -Gft-r<M*r$-

MATT/MG - C^oPPCO Sm, u o ./^T^O , - recede Sfcco. T S ^ 0 roc^ c nertlJ , 

IjC ALSO OO J<*f-»-t /'A iwTwt Of PAar\, Ar~ex\. -|- H E p^ aTy i n / , 0 L ; (J f<. 

£ Sf £ I OIA FO<\- 0ETA^i\ 

Site Description \%,0 ACWtS LoCaTiZO 0 <u 7 fi t 0 o <VNL- N, O F /- m x t Jliuci . •£«.. 

/.toO '

 M ^ V /0 , Tht/L C /S OWE Al/.t«v /3t-U(.D/»uc OK, S rr£ 

foFTixJ ?<?iO THt" 9. UlOGS IS A WJAilC HO Ui t /-"<J»v CHfK'M, . 

STO>\AC£. . 

/ C 0 i u J3U,<CD.K»C S-izgs if f .Appall,*. X . FeK----Sire 'FUAUOATIQ^ HAP 

/.OC^TIO O ./VuiAriii.^ t i)p $ iGfv*4Ttc *J -4^ o '3u.<(.<->. wc H£tCt,T 

) 5'CAc I'O MA«] 4 

S't" £ /^^f-JOv x ~77T 
P.6 

of Wisconsin SOURCE DESCRIPTION - SUPPLEMENTAL 

ctment of Naaual Resources AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-102A 11-93 Infonnation attached? __ (y/n) 

of this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

3925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

ss you complete and submit this form. It is not the Department's intention to use any personally identifiable information ircm 

form for any other purpose. 

List all significant existing or proposed air pollution units, operations, and activities at the facility. A shon narrative of the 

inventory of air pollution emissions unit (e.g., boiler, printing line, etc.) followed by equipment specifications will suffice. If 

the facility consists of several individual emission units, present this infonnation in an outline format. (See instruction 

booklet for an example Unit description.) 

JJJ 

A PP L /CA T/drJ * 

FOTL ; pO] SOI - GeuOAT BOOTH A NO SXHAU$T* 

POI- S0(L\ A^iNAjitxjc /uur*j AND FXH/.«wr 

POI- S03<^ 

POZ- SOL/~- yVHK/r. roc HUE JGOC-H^MO EXHAIUTI 

pOLl - SOS- TaiHhiM t AilCA A»o ZXHAurr' 

: BtfS" SOL- SPACE h£ATItOL Ato0 EJMAUST.' 

PCS - -SCZSD2 - Too^c o r m» n^'fa,^) 

fO£- SOI r^Wor-W^H0C0S [Gfu^r] 

p Jt" £ I IVQIU\0UA.. Fo.Uij- 101A F0(L EACH 
P.7 

of Wisconsin SOURCE DESCRIPTION - SUPPLEMENTAL 

«m«U of Natural Resources AIR POLLUTION CONTROL PERMIT APPUCATION . 

Form 4530-102B 11-93 Information attached? _ (y/n) 

of this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

3925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

ss you complete and submit this form. It is not the Department's intention to use any personally identifiable information .icm 

form for any other purpose. 

Mark all insignificant existing or proposed air pollution units, operations, and activities at the facility listed below. If not 

listed, provide a short narrative of the inventory of air pollution emissions unit (e.g., boiler, printing line, etc.) followed byequipment specifications. If the facility consists of several individual emission units, present this infonnation in an outline 

format (See instruction booklet for an example Unit description.) 

^Maintenance of Grounds, Equipment, and Buildings (lawn care, painting, etc.) 

• Boiler, Turbine, and HVAC System Maintenance 

b_( Pollution Control Equipment Maintenance 

Js( Internal Combustion Engines Used for Warehousing and Material Transport 

ffl Fire Control Equipment 

JS( Janitorial Activities 

^Office Activities 

^Convenience Water Heating 

jfcf Convenience Space Heating (< 5 million BTU/hr Burning Gas, Liquid, or Wood) 

• Fuel Oil Storage Tanks (< 10,000 gal.) 

D Stockpiled Contaminated Soils 

D Demineralization and Oxygen Scavenging of Water for Boilers 

• Purging of Natural Gas Lines 

^Sanitary Sewer and Plumbing Venting 

• 

• 

D 

• 

• 

• 

• 

€0 
P.8 

H State cf Wisconsin 

Department of Natural Resources 

INDEX OF AIR POULUTION PERMIT APPUCATION FORMS 

Form 4530-134 11-93 

I. ADMINISTRATION 

TUs application contains tbe 

following forms: -

JsL Form 4530-100, Facility Identification 

J2^ Form 4530-101. Facility Plot Plan 

J l Fonns 4530-102, -102A. ind -102B, Source and Site Descriptions 

IL EMISSIONS SOURCE 

DESCRIPTION 

This application contains the 

following forms (one form for each 

facility boiler, printing operation, 

etc.): 

* 

• 

0 

o 

a 

e 

0 

Form 4530-103, Stack Identification 

Form 4530-104, Boiler or Furnace Operation 

Form 4530-105, Storage Tanks 

Form 4530-106, Incineration 

Form 4530-107, Printing Operations 

Form 4530-108. Painting and Coating Operations 

Form 4530-109, Miscellaneous Processes 

Total Number 

of This Form 

6 

1 6 

S 

in. AIR POLLUTION CONTROL 

SYSTEM 

This application contains the 

foUowing forms: 

0 

D 

0 

0 

0 

O 

a 

a 

Form 4530-110. Miscellaneous 

Form 4530-111, Condensers 

Form 4530-1 l i Adsorbers 

Form 4530-113. Catalytic or Thennal Oxidation 

Form 4530-114, Cyclones/Settling Chamben 

Form 4530-115, Electrostatic Precipitators 

Form 4530-116. Wet Collection Systems 

Form 4530-117. Baghouses/Fabric Filters 

Total Number 

of This Form 

IV. COMPLIANCE 

DEMONSTRATION 

This application contains the 

following fonns (one for each 

facility boiler, printing operation. 

etc.): ' 

D Form 4530-118, Compliance Certification • Monitoring and Reporting 

0 Fann 4530-119, Continuous Fmhtton Monitoring 

D Form 4530-120, Periodic Emission Monitoring Using Poitable Monitors 

0 Form 4530-121. Control System Parameters or Operation Parameten of a 

Process 

D Form 4530-122, Monitoring Maintenance Procedures 

O Form 4530-123, Stack Testing 

D Form 4530-124, Fuel Sampling and Analysis 

O Form 4530-125, Recordkeeping 

Total Number 

of This Form 

~^~ 
P.9 

V. EMISSION SUMMARY AND 

COMPLIANCE O-KT1HCATI0N 

This application contains the 

following forms quantifying 

emissions, certifying compliance 

with applicable requirements, and 

developing a compliance plan 

B Fonn 4530-126, Emission Unit Hazardous Air Pollutant Summary 

D Form 4530-127, Facility Hazardous Air Pollutant Summaiy 

D Form 4530-128. Emission Unit Summaiy 

0 Form 4530-129, Facility Emissions Summaiy 

0 Fonn 4530-130, Cunent Emissions Requirements and Status of Unit 

D Form 4530-131, Emission Unit Compliance Plan - Commitments and Schedule 

0 Form 4530-132, Current Eitiiwont Requirements and Status of Facility 

O Form 4530-133, Facility Requirement Compliance Plan Commitments and 

Schedule 

Total Number "i 

of This Form j 

JT *. 

VI. SIGNATURE OF RESPONSIBLE OFFICIAL 

B. 

STATEMENT OF COMPLETENESS 

I have reviewed this application in its entirety and, based on information and belief formed after reasonable inquiry, I certify 

that the statements and information contained in this application are true, accurate and complete. 

Wmm^^^M^^mm^^mim^^m^^ (<*eck one box only) 

TfflsTlS NOTA REQUIREMENT OF NON-PART 70 SOURCES. 

fe I certify that the facility described in this air pollution pennit implication is fully in compliance with all applicable 

requirements. 

• I certify that the facility described in this air pollution permit application is fully in compliance with all applicable 

requirements, except for the following emissions unit(s): 

(list all non-complying units) 

Printed or Typed Njme 

QWH £11, Ofjium 

Signature DatesSigned 

y-n.d-'W' 

SEND ALL MATERIALS TO: 

WISCONSIN DEPARTMENT OF NATURAL RESOURCES 

BUREAU OF AIR MANAGEMENT 

PERMITS SECTION 

P.O. BOX 7921 

MADISON, WI 53707-7921 

[J 
P.10 

V. EMISSION SUMMARY AND 

COMPUANCE CERTTHCATION 

This application contain! the 

following forms quantifying 

emissions, certifying compliance 

with applicable requirements, and 

developing a compliance plan 

• Form 4530-126. Emifrirm Unit Hazardous Air Pollutant Summaiy 

D Fonn 4530-127. Facility Hazardous Air Pollutant Summaiy 

D Form 4530-128. Emiimnn Unit Summary 

Q Form 4530-129, Fadlity Emissions Summaiy 

0 Form 4530-130. Cunent Firmiiont Requirements and Status of Unit 

0 Fm— 4530.111, Fmixfinn Unit Co»7>pl"-_"«J PltW - Co-pTM"TMTM" and Schedule 

0 Form 4530-132, Cunntt Emission Requirements and Status of Facility 

D Form 4530-133. Facility Requirement Compliance. Plan Commitments and 

Schedule 

Total Number 

of This Form 

^ 

VL SIGNATURE OF RESPONSIBLE OFFICIAL 

B. 

STATEMENT OF COMPLETENESS 

I have reviewed this application in its entirety and, based on infonnation and belief formed after reasonable inquiry, I certify 

that the statements and infonnation contained in this application are true, accurate and complete. 

l^L^rrW^JW^^^^^^^^^^^^^^^ (check one box only) 

THIS IS NOT A REQUIREMENT OF NON-PART 70 SOURCES. 

fe I certify that the facility described in diis air pollution pennit application is fully in compliance widi all applicable 

requirements. 

• I certify that die facility described in this air pollution pennit application is fully in compliance with all applicable 

requirements, except for the following emissions unit(s): 

(list all non-complying units) 

OWHtm. ouiugn. 

y-id-isSEND ALL MATERIALS TO: 

WISCONSIN DEPARTMENT OF NATURAL RESOURCES 

BUREAU OF AIR MANAGEMENT 

PERMITS SECTION 

P.O. BOX 7921 

MADISON, WI 53707-7921 

Q 
P.11 

. 

SITE PLAN 

Approximate Scale: f = 400' 

A PPBW ix HEeder associates 

FIGURE 1 

LEGEND 

fa Materia/ Handling 

^ Practice 

-*— Drainage Way 

60 

I 

Approximate 

Scale In Feet 

012396 

SW15451A 

SITE EVALUATION MAP 

CUSTOM FIBERGLASS MOLDING 

WEYAUWEGA, WISCONSIN 

//-) 

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P.15 

16/09/1998 11:54 414-265-9199 HASTINGS AIR ENERGY PAGE 81 

HASTINGS AIR-ENERGY CONTROL 

141 Wwl Vine sSlrect » Milwaukee, Wisconsin 53:12 

414-265-3600 . 1-800-236-8450 • Fax: 414-265-9199 

To: feo& Hy iX DftN\ From: £wG 

Company: C-UaWv\<Uftfl\<vWa r^cAi-w^ Company: Hastings Air-Energy Contr 

Fax Number: ^2- 0 %k ? 2 k \ S 

ntrol 

Fax Number: 414-265-9199 

Date: \b0uti^& Time: \\\ *& Number of Pages Sent: c-3- Onci.i<Jing cover Sheet) 

Comments: V4JL)LO &A>. 

riease call if you are misting any port oftlis transmission. 

AM i, 4. ^^k ^ <3<JL M 

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P 

7/n'.'- message is intended only for the use ofthe individual or entity ofwhich it is addressed ond may contain information that 

is privileged, confidential, and exempt from disclosure under applicable law. If the reader of this message is not the intended 

recipient, you are hereby notified that any dissemination, distribution, or copying of this communication is strictly prohibited 

If you receive this communication in error, please notify us immediately by telephone and return the original message to the 

sender via first class mail. Thank you! 

.:\.cn».u»-(nee.do< 

•3* 
t)b/k*y/i998 il:5 4 <u4-__b&-yiyy HAbliN'jb A1K tNLKUi ••••at. O i 

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,4//? to/? ff STING LABORATORIES, INC. 

1912 PRODUCTION DRIVE LOUISVILLE, KENTUCKY 4021)9 

• mmm^***m^^m^^~mm^*^^^mm^^m»mmmimrm*'*rim-w^mt-Mmmmmtmmmmm-9 _-...- _I._II._-.. . , _ . . .. 

ASHRAE AIR FILTER TEST STANDARD 52-76 

STATICALLY TESTED DEVICES 

TEST REQUESTED 8Y ^yftg g &M? &*n&?W«> 

MANUFACTURER /fafl f A ^ AWW** ' 

PRODUCT NAME 

REPORT NO. /^/ f 

TEST NO. -Z. 

SHEET NO 1 

HOW LABORATORY PROCURED TEST SAMPLE ^^^y/jfrKg ? Av's9tt^j<&*7aVte£iC 

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RATED PERFORMANCE DATA FROM MANUFACTURERS CATALOG NO. DATED 

AIR FLOW CAPACITY 

INITIAL RESISTANCE 

FINAL RESISTANCE 

INITIAL ATMOSPHERIC DUST SPOT EFFICIENCY 

AVERAGE ATMOSPHERIC DUST SPOT EFFICIENCY 

AVERAGE SYNTHETIC DUST WEIGHT ARRESTANCE 

ASHRAE DUST HOLDING CAPACITY 

> 

TEST Al R F LOW RATE S2£4£/$& 

INITIAL RESISTANCE 

FINAL RESISTANCE 

INITIAL ATMOSPHERIC DUST SPOT EFFICIENCY 

AVERAGE ATMOSPHERIC DUST SPOT EFFICIENCY 

AVERAGE SYNTHETIC DUST WEIGHT ARRESTANCE 

ASHRAE DUST HOLDING CAPACITY 

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TEST SECTION DUCT SI2E jg-4/#. X__?*?/*/. DUST FEEDING RATE^,<9_1/vtS,£,aC>&T 

SEE BACK SIDE (PAGE IA) FOR PERFORMANCE CURVES 

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FACE DIMENSIONS *&fa+W. XJ&4**.A4M* . 

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TYPE MEDIA rAfr/l'MA****' J-M-v/gttf W OfM/r^ 

TYPE & AMOUNT ADHESIVE A/gtSa* 

DATE TEST SUPERVISOR ENfilNEEWNG APPROVAA 

J4 
P.17 

HASTINGS AIR-ENERGY CONTROL 

"A DIVISION OF HASTINGS DISTRIBUTING. INC. 

141 W. VINE STREET 

MILWAUKEE, Wl 53212-3993 

(414) 265-3600 • 1-800-236-8450 

INVOICE 

NUMBER 

123 2 1 

DATE PAGE 

03-20-9 8 

CUSTOM FIBERGLASS MOLDING 

E538G LITTLE RIVER ROAD 

WEYAUWEGA. WI 54983 

SHIP 

TO 

CUSTOM F IBERGLASS MOLD I. HG 

E5830 LITTLE RIVER ROAD 

WEYAUWEGA, WI 5 49£:3 

YOUR ORDER 

-jDou^"*"" 

.UK E FER A 

TERMS 

2 % 1 0 DAYS , 3 X COD , NE T 3 0 

ITEM NO./DESCRIPTION 

3-25-1/2R!0 1 

POLYESTE R 

2 5 " WID E X.1/2 ' 

1 3 5 FEET/ROL L 

TACK Y DR Y 

fknAjL ~r*jb> c-v\ iiiiiii 

4^ 4 ^ /t^ . W<L 

V/2% SERVICE CHARGE PER 

MONTH ASSESSED INVOICES 

OVER 30 DAYS 

U/M 

EA 

QTY. ORDERED 

yji] 

THANK YOU FOR YOUR ORDER! 

/S~ 

ORDER #/DATE |SAIESREP.| WHS f 

919 0 

0 1-20-9 7 

QTY. SHIPPED B/0 

jk> 

0 1 U P 

UNIT PRICE 

. J 5 . V o 

.9-

* fr 

Wis e 

Wise . Co u 

'ft 

rj f 

jS;a. Le s Ta x •*•.* s 

y Sale s T__ ;••: 

TOTAL DUE 

SHIP VIA 

AMOUNT 

1 67-. 8 

WHITE-CUSTOMER • CANARY-CUSTOMER • PINK-FILE 
P.18 

jfwiscomin SOURCE DESCRIPTION - SUPPLEMENTAL 

tment of Nuaral Resources AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-102A 11-93 Infonnation attached? _ (y/n) 

Df this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

(925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

is you complete and submit this form. It is not the Department's: intention to use any personally identifiable infonnation from 

"onn for any other purpose. 

List all significant existing or proposed air pollution units, operations, and activities at the facility. A short narrative of the 

inventory of air pollution emissions unit (e.g., boiler, printing line, etc) followed by equipment specifications will suffice. If . 

the facility consists of several individual emission units, present this information in an outline format. (See instruction 

booklet for an example Unit description.) ,- r . • n 

VO\ - §0 \ xJiELCoATivc Process.' 

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& 
P.19 

of Wisconsin 

-tment of Natural Resources 

INSTRUCTIONS ON REVERSE SIDE 

STACK IDENTIFICATION 

AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-103 11-93 Infonnation attached? _ (y/n) 

Facility name: 

1T/.M. Fi(\£tu&Cj.*r MOLPJioc 

3. Stack: identificaticm number 

SOL 

Exhausting Unit(s),use Unit idendfii_^on'-mmbef,-_Tbm-Lppropria 107, 108'and/or 109 

50-104 4530-106 4530-107 4530-108 4530-109 

Identify this stack on the plot plan required on Fonn 4530-101 

Indicate by checking: 

_-_T This stack has an actual exhaust point. D This stack serves to identify fugitive emissions. 

If this stack has an actual exhaust point, then provide the ^o^i ^ :st^;par_mete--s 

Discharge height above groundJweT; /<*./)$ (feet) 

Inside dimensions* at outlet (check 'one*a_££complete): 

JST Circular -SL (feet) . • rectangular , length (feet) width (feet) 

ExHa^gl^^rate; 

Maximum Hffl/fl (ACFM) 

Fi^|ust|^^mpOTi^|i_n§ffi^ 1%° (°F) 

Exhaust gas moisture content: Normal volume percent Maximum volume percent 

Ex^ui>t;g^'disclfa^^dirlKH^ D Up D Down Horizontal 

l-rthisst^eq^pj-^Jwfo^^ -flf Yes O No 

exhaust gases from the stack? r\ . _ , _ C/.rt . , _ - _,__. , , , 

__: _ : : (S)(\-Ar(-\) Coat-1^ FOiX. \A ^e:ru Pr\nrircTlQfJ • 

* Complete the appropriate Air Pennit Application Forms(s) 4530-104, 106,107, 108 or 109 for each Unit • 

exhausting through this stack. 

1 ^ 
P.20 

•jf Wisconsin 

•uncut of Natural Resources 

PAINTING AND COATING OPERATIONS 

AIR POLLUTION CONTROL PERMIT APPLICATION 

Fonn 4530-108 11-93 Information attached? _ (y/n) 

INSTRUCTIONS ON REVERSE SIDE 

Facility name:(J u m ^ piftBAt , A f f MOW... * 

S^k:^idm|^cation nirmber: QQ J 

2. 

4. 

Facility identification number 

Process;number: Q/\ i 

Unit description: 

£ZhAU<rr STA-CK O /R( noen. 

Indicate the control technology status. Uncontrolled • Controlled 

If the process is amtcblled, rater the" control deyiceJnumba-(s) from.the appropriate form(s): 

4530-110. 

4530-114 

4530-111, 

4530-115 

4530-112. 

4530-116 

4530-113, 

4530-117 

Application technique and transfer efficiency (%): r • HVLP , 

Date of con-^ctio^crlastmoda^dpm /97 ? 

Normal operating .schedule: fn hrs/day 

Oven curing (complete if applicable): 

Number of ovens 

Total Maximum Energy input to each oven: 

,5" davs/wk 

Specify oven 

/C 6. #„ 

l£<i days/yr 

fuels 

Describe all of the coatings' and solvents' composition (as applied) that are used by this unit. 

OnSSSSSafS 

-^S-feti-Mi 

_-^&-l"J*"»"-"* 

ft3iH 

_KS__L 

gal/hr gal/yr gal/yr 

Solids 

% 

f. 

W 

voc 

% 

gw 

Water 

% 

h. 

W 

Coating 

or VOC 

Density 

lbs/gal 

ELrOAT 1.01 /3m-v 'UW.aL IAL 

EC Pen-Oanoe •OW 2os:n ~?Oa1<. "7.ff 

>tal coatings 

G>£(rCOAT »* 

ACTUAL. G/UJ jp/uj-ro > uoe cos P/vG*c v 3s? 0 

X /§"MALJ /^o* j 9t3.f*iOALj- /J/L ^ * - A)AS TMIT M0/L //.;_< 

st the thinning solvi 

ean-up solvents / 

ean-up solvents 

Lher (specify) 

:

*** For this emi 

DESCPJPT... 

and its attachment(s) to this form. This is not a requirement or non-rat i . v 

'*** Please complete the Air Pollution Control Pennit Application Forms 4530-126 and 4530-128 for this Unit. ***** 

.ting categories (ct. eg. - column b. above) should be entered as follows: 1 - for air dried coatings; 2 - for clear coatings; 3 

cured coatings; 4 - for extreme performance coatings; 5 - for other (specify) 

0-118, ***** 

0-118 

1 
P.21 

nf Wisconsin 

xment of Natural Resources 

INSTRUCTIONS ON REVERSE SIDE 

EMISSION UNIT HAZARDOUS AiK nJlJLUiAiNl _.UM_VIAKI 

AIR POLLUTION CONTROL PERMTT APPUCATION 

Form 4530-126 11-93 Information attached? _ (y/n) 

Facility name: Q' 

C_.<T/»M FmenfiiLAii MoiDMJLTat. 2. Wim^Mm^c^aawivIo!^ 

Stack identification number __HL 4. tJniHdeiiitificafibri® ML 

Unit material description: Q ELC 6JTT > 

Complete the following summary of hazardous air emissions from this unit. Attach sample calculations and emission .omary 

factor references. Attached? /ySC 

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IfclntanrCAS. ..^j ? 

loo-m~s 

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P.22 

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P.23 

jy 

MATERIAL SAFETY DATA SHEET Page i 

FOR GELCOATS, RESINS, AND RELATED MATERIALS/ tVlfrrph 

ared by- BK 

of Preparation- 01-25-95 

factureri NESTE POLYESTER 

ess : 5106 Wheeler Ave. 

Fort Smith, AR 72901 

,->/ 

For: CUSTOM FIBERGLASSS /«LDING / ¥ 

E5880 LITTLE;RIVER RD

 L 

WEYAUWEGA WI 54983 

70-?$-' 

iphone No. : (501) 646-7865 CHEMTREC (800) 424-9300 U 

SECTION I PRODUCT IDENTIFICATION 

ifacturer' s Code Identification : 

luc t Class: 

le Name: .'817^JHITE|B||pg3a^ 

! Information: Health- 2 

Reactivity- 1 

WG-30799 Revision 12 

Flammability- 3 

Personal Protective Equipment- I 

;ty Glasses, Gloves, & Combination Dust and Vapor Respirator 

SECTION II HAZARDOUS INGREDIENTS 

1ATERIAL 

STYRENE 

JY WT: 

CAS# 100-42-5 

34.48 

)SURE LIMIT: 

ACGIH TLV/TWA 

OSHA PEL 

TLV-STEL 

SR LIMITS: 

*C 2B 

50 PPM 

50 PPM 

100 PPM 

It************************************************************** * ****** * A 

This product contains one or more reported carcinogens or suspected 

i-inogens which are noted NTP, IARC, or OSHA-Z in the other limits 

Dmmended column. 

k **************** * * * * * * * * * ************************************* * A- * -A * * -A- A Afc*********************************************************************** 

This product contains pigments which may become a dust nuisance when 

_>ved by abrasive blasting, sanding, or grinding. 

************************************************************************ 

SECTION III PHYSICAL DATA 

ling Range: High- 295.0 F 

or Pressure: 4.30 MMHG @68 

or Density: Heavier Than Air 

poration Rate: Slower than Ether 

ght per Gallon: 11.05 

: .010 

sical State: LIQUID 

earance: WHITE 

Low- 295.0 
P.24 

********************************************************************** * 

NESTE POLYESTER 

-30799 MATERIAL SAFETY DATA SHEET Page 2 

817 WHITE GEL COAT 

********************************************************************** * 

: AROMATIC 

r Solubility: INSOLUBLE 

umber: 1866 RESIN SOLUTION, FLAMMABLE 

•SECTION IV FIRE AND EXPLOSION HAZARD DATA 

Flammability Classification: Class IC DOT: Flammable Liquid 

al Flashpoint TCC: 89.0 F 

osion Level: Lower- 1.1 Upper- 6.1 

^ter stream can scatter flames. A spray of water may be used to cool 

:-exposed containers. 

NGUISHING MEDIA 

Foam, C02, Dry Chemical, Water Fog 

; fighters should use self-contained breathing apparatus with full 

ipiece. 

IUAL FIRE AND EXPLOSION HAZARD: 

> containers tightly closed. Isolate from heat, electrical equipment, 

*ks, and open flame. Vapors may be heavier than air and may travel 

tg the ground before ignition/flashing back to vapor source. Keep 

ling or cutting equipment away from product. 

SECTION V HEALTH HAZARD DATA 

CCTS OF EXCESSIVE OVEREXPOSURE 

_rts have associated repeated and prolonged occupational overexposure to 

/ents with permanent brain and nervous system damage. Intentional 

lse by deliberately concentrating and inhaling the contents may be 

nful or fatal. Do not breathe vapors or spray mist. Wear an approite, properly fitted respirator (NIOSH/MSHA approved) during and after 

Lication unless air monitoring demonstrates vapor/mist levels are below 

Licable limits. Follow respirator manufacturer's directions for 

pirator use. 

Drs of this product may cause irritation of the eyes, nose, throat, 

jr respiratory tract, mucous membranes, and skin. 

3T AID 

CONTACT: Flush with luke warm water for 15 minutes. Seek physician 

sdiately. 

M CONTACT: Flush wash with copious amounts of luke warm water. Remove 

taminated clothing promptly. Wash thoroughly with soap and water. 

ELATION: Remove exposed individial to fresh air. Restore breathing 

required. Contact a physician immediately. 

ESTION: Rinse mouth immediately. Give exposed individual 6 to 8 ounces 

liquid. (Never give anything by mouth to an unconscious person.) Do 

induce vomiting unless advised by a physician. Contact a physician 

sdiately. 

International Agency for Research on Cancer (IARC) has classified 

rene as a possible human carcinogen (class 2B). The IARC 2B 

ssification is not based on significant new evidence that-styrene might 

a carcinogen, but on a revised IARC classification scheme and new data 

styrene oxide. 
P.25 

v **************************************************** * * A: * A- * * * * A A A- A A A A- A A 

NESTE POLYESTER 

-30799 MATERIAL SAFETY DATA SHEET Page 3 

817 WHITE GEL COAT 

fcA***************************************************************AAAA*A 

SECTION VI REACTIVITY DATA 

ITIONS TO AVOID 

d exposure to sparks, open flame; hot surfaces, and all sources nf heat 

ignition. 

UCT STABILITY: Stable; hazardous decomposition not expected; thi-inna! 

imposition may produce toxic oxides of carbon and/or nitrogen. 

MPATIBILITY (Materials to Avoid) 

product is incompatible with strong acids, peroxides, and other 

izing agents, organic metal soaps. 

SECTION VII SPILL OR LEAK PROCEDURES 

S TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

upwind and away from spill unless wearing appropriate protective. 

pment. Stop and/or contain discharge if it may be done safely. Keep 

sources of ignition away. Ventilate area of spill. Use non-sparking 

s for cleanup. Cover with inert material to reduce fumes. Keep out of 

ns, sewers, or waterways. Contact fire authorities. Notify local 

th and pollution control agencies. Call spill response teams if large 

1. 

"E DISPOSAL METHOD 

OT FLUSH TO SEWER, WATERSHED, OR WATERWAY. 

>ose of in accordance with local, state and federal regulations. Do not 

nerate closed containers. 

SECTION VIII SAFE HANDLING AND USE INFORMATION 

•I LAT ION 

ventilation as required to control vapor concentrations. Avoid 

.onged or repeated breathing of vapors. If exposure exceeds TLV, uae a 

_H-approved respirator to prevent overexposure. 

ACTIVE GLOVES 

lired for prolonged or repeated contact. Wear resistant gloves such as 

iral rubber, neoprene, buna N or nitrile. An apron should be worn to 

Id skin contact. 

'IRATORY PROTECTION 

outdoor or open areas use (NIOSH/MSHA approved) mechanical filter 

>irator to remove solid airborne particles of overspray during 

ay application. In restricted ventilation areas use (NIOSH/MSHA 

roved) chemical-mechanical filters designed to remove a combination of 

ciiculate and gas and vapor. In confined areas use (NIOSH/MSHA approved) 

line type respirators or hoods. Respiratory protection may also be 

__ssary in any later manufacturing operations in which the product may 

-.me airborne in the form of vapor or dust. 

SECTION IX SPECIAL PRECAUTIONS 

DLING AND STORAGE: Use in accordance with good industrial workplace 

ctices; avoid unnecessary contact; wash thoroughly after handling; store 

a dry area away form excessive heat. 

ER PRECAUTIONS: For industrial use only. 
P.26 

A A ***************************************************** * A A A A A A A A A A A A A A A 

NESTE POLYESTER 

-30799 MATERIAL SAFETY DATA SHEET Page H 

817 WHITE GEL COAT 

A ************************************************************ * A A A A A A A A A 

onnel should avoid inhalation of vapors. Personal contact with the 

uct should be avoided. Should contact be made, remove saturated 

hing and flush affected skin areas with water. Containers of this 

rial may be hazardous when emptied. Since emptied containers :••-• *•.••_ i;; 

uct residues (vapor, liquid, and/or solid), all hazard pr-f.raur i •;!..••: 

n in this sheet must be observed. 

* 

CE - Reports have associated repeated and prolonged occupational 

exposure to solvents with permanent brain and nervous system damage, 

ntional misuse by deliberately concentrating and inhaling the contents 

be harmful or fatal. 

SECTION IX (B) DOT INFORMATION 

imable Liquid 3 Packing Group III 

SECTION X Section 313 Toxic Chemicals 

; product contains the following toxic chemicals subject to the 

irting requirements of section 313 of the Emergency Planning and 

tunity Right-To-Know Act of 1986 and of 40 CFR 372: 

rical CAS Number Weight % 

(ENE 100-42-5 V. .•.;". 

THE INFORMATION CONTAINED HEREIN IS INFORMATION RECEIVED 

FROM OUR RAW MATERIAL SUPPLIERS AND OTHER SOURCES AND 

IS BELIEVED TO BE RELIABLE. THIS DATA IS NOT TO BE TAKEN 

AS A WARRANTY OR REPRESENTATION FOR WHICH NESTE POLYESTER 

ASSUMES LEGAL RESPONSIBILITY 
P.27 

MATERIAL SAFETY DATA SHEET 

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Elf Atochetn North America Customer Service: 

2000 Market Street 1-800-55B-5575 Busin,-33 Hours 

Philadelphia, PA 19103 Information: 

1-800-558-5575 Business Hours 

EMERGENCY TELEPHONE NUMBERS: 

CHEMTREC: (800) 424-9300 (24 hours) or (202) 483-7616 

MEDICAL: Rocky Mountain Poison Control Center 

(303) 623-5716 (24 hours) 

NAME USED ON LABEL: LUPERSOL DDM-9 

CHEMICAL NAME: Methylethyl ketone peroxide blend 

CHEMICAL FAMILY: Organic Peroxide - Ketone Peroxide 

PRODUCT USE: Polymerization initiator 

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS 

Typical OSHA 

Identity CAS No. % Hazard 

2,2,4-Trimethyl-l,3-pentane- 6846-50-0 23.8 N 

diol diisobutyrate 

Dimethyl phthalate 131-11-3 32.0 Y 

Methylethyl ketone peroxides 1338-23-4 35.0 Y 

Hexylene glycol 107-41-5 6.0 Y 

Hydrogen peroxide 7722-84-1 3.7 Y 

Methyl ethyl ketone 78-93-3 1.0 Y 

Water 7732-18-5 1.5 N . 

TSCA Inventory Status: 

This product is TSCA compliant. The components are either on the TSCA 

inventory or are exempt as impurities. 

The substance(s) marked with a Y in the OSHA Hazard column above, are 

those identified as hazardous chemicals under the criteria of chs: OSHA 

Hazard Communication Standard (29 CFR 1910.1200). 

Section 3 - HAZARDS IDENTIFICApJpEX

 0hHht*,dby 

IUM mwvncM-cnufrWr 

EMERGENCY OVERVIEW: ff^TT^V SXTSffi^'eAv 

Clear oil y liquid, ketone- odor SSSSJtSlcJJ 

61. Paul MN 

Gennantown, 

(1512)645-94! 

(414)253-66.!3 FAX 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 1 of. 13 

ELF ATOCHEM NORTH AMERICA, INC. 
P.28 

MATERIAL SAFETY DATA SHEET 

Section 3 - HAZARDS IDENTIFICATION 

DANGER! 

ORGANIC PEROXIDE 

CAUSES EYE BURNS 

MAY CAUSE BLINDNESS 

MAY CAUSE SKIN IRRITATION 

MAY CAUSE ALLERGIC SKIN REACTION 

HARMFUL IF SWALLOWED 

POTENTIAL HEALTH EFFECTS: 

Skin contact and inhalation are expected to be the primary routes of 

exposure to Lupersol DDM-9. Based on its composition, Lupeisol DDM-9 

is anticipated to be moderately toxic if swallowed, slightly toxic if 

absorbed through skin, practically non-toxic if inhaled, moderately 

irritating to skin and corrosive to eyes. Prolonged or repeated 

contact may cause an allergic skin reaction. Overexposure tc vapor 

may lead to digestive disorders, narcosis and central nervou£3 system 

(CNS) effects such as headache, dizziness, loss of coordination, loss 

of consciousness or convulsions. If swallowed, Lupersol DDM-S" may 

cause CNS effects as noted above, irritation of 'the mouth, throat and 

stomach and, in severe cases, death. 

Section 4 - FIRST AID MEASURES 

IF IN EYES: 

Immediately flush with plenty of water for at least 15 minut5£ . Get 

medical attention immediately. 

IF ON SKIN: 

Immediately wash with soap and plenty of water. Remove contaminated 

clothing and shoes. Get medical attention if symptoms occur. Wash 

clothing before reuse. Destroy contaminatd shoes. Thoroughly clean 

shoes before reuse. 

IF SWALLOWED: 

Induce vomiting immediately as directed by medical personnel. Get 

medical attention. Contact a Poison Control Center. NEVER GIVE 

ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. 

IF INHALED: 

Remove to fresh air. 

Zl Section 5 - FIRE FIGHTING MEASURES 

Flash Point (Test Method): 58»C / 137°F (CC) 

Autoignition Temperature: NE 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 2 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

ZCo. 
P.29 

MATERIAL SAFETY DATA SHEET 

Section 5 - FIRE FIGHTING MEASURES 

Flammable Limits: Upper: NE 

Lower: NE 

EXTINGUISHING MEDIA: 

Water fog, water spray, dry chemical, foam 

SPECIAL FIRE FIGHTING PROCEDURES: 

Fire fighters and others who may be exposed to products, of combustion 

should wear full fire fighting turn out gear, (full Bunker Gear) and 

self-contained breathing apparatus (pressure-demand NIOSH approved or 

equivalent). Fire fighting equipment should be thoroughly 

decontaminated after use. 

If a large amount is involved, evacuate area and fight fire from a 

safe distance. Do not use a solid stream of water. A solid stream of 

water can spread fire. Use water spray to disperse any flammaole 

mists and vapors which have not ignited. 

FIRE AND EXPLOSION HAZARDS:

 4 

Contact with incompatible materials or exposure to temperatures 

exceeding SADT (Section 9) may result in a self acceleratinci 

decomposition reaction with release of flammable vapors which vnay 

autoignite. 

Section 6 - ACCIDENTAL RELEASE MEASURES 

IF A SPILL OR LEAK OCCURS: 

Use inert, noncombustible absorbent material. Sweep cr scoop up using 

non-sparking tools and remove. 

Section 7 - HANDLING & STORAGE 

HANDLING: 

Do not get in eyes, on skin.or on clothing. 

Do not taste or swallow. 

Avoid breathing vapor or mist. 

Wash thoroughly after handling. 

Use only with adequate ventilation. 

Contact with incompatible materials or exposure to temperature.. 

exceeding SADT (See Section 9) may result in a self accelerating 

decomposition reaction with release of flammable vapors which nay 

autoignite. 

Keep away from heat sparks and flame. 

Avoid contamination. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 3 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

£-# 
P.30 

MATERIAL SAFETY DATA SHEET 

Section 7 - HANDLING & STORAGE 

Use explosion proof equipment. 

Keep container closed. 

STORAGE: 

Store below 100°F(38°C) to maintain active oxygen content. 

Detached storage is preferred. 

Avoid excessive heat and store out of direct sunlight in a -icol 

well-ventilated place. 

Store away from combustibles and incompatible materials. 

Section 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION 

ENGINEERING CONTROLS: 

Investigate engineering technicjues to reduce exposures belov/ airborne 

exposure limits. Provide ventilation if necessary to control exposure 

levels below airborne exposure limits. Dilution ventilation 

acceptable, but local mechanical exhaust ventilation preferred, if 

practical, at sources of air contamination such as open process 

equipment. Consult ACGIH ventilation manual or NFPA Standard 91 for 

design of exhaust systems. 

EYE PROTECTION: 

Where there is potential for eye contact, wear chemical gogcles and 

have eye flushing equipment immediately available. 

SKIN PROTECTION: 

Wear appropriate chemical resistant protective clothing and chemical 

resistant gloves to prevent skin contact. Latex, nitrile, r.eoprene,. 

PVC or other impermeable gloves should be worn when handling this 

material. Wear face shield and chemical resistant clothing such as a 

rubber apron where splashing may occur. Rinse contaminated skin 

promptly. Wash contaminated clothing and clean protective equipment 

before reuse. Wash skin thoroughly after handling. 

RESPIRATORY PROTECTION: 

Avoid breathing vapors or mists. Use NIOSH approved full face organic 

vapor and mist respirator when airborn exposure limits are exceeded. 

If used, full facepiece replaces need for chemical goggles cr face 

shield. Consult respirator manufacturer if exposure limits are 

greater than ten times the the recommended exposure limits. Observe 

respirator use limitations specified by NIOSH or the manufacturer. 

For emergency and other conditions where exposure limit may bv 

significantly exceeded, use. an approved full face positive-pressure 

self-contained breathing apparatus or positive-pressure airline with 

auxiliary self-contained air supply. Respiratory protection programs 

must comply with 29 CFR 1910.134. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 4 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

ZB 
P.31 

MATERIAL SAFETY DATA SHEET 

Section 8 - EXPOSURE CONTROLS & 

AIRBORNE EXPOSURE GUIDELINES 

OSHA PEL 

TWA STEL 

2,2,4-Trimethyl-l,3-pent 

NE NE 

Dimethyl phthalate 

5 mg/m3 NE 

I 

CEILING 

PERSONAL 

TWA 

ane-diol diisobutyrate 

NE 

NE 

Methylethyl ketone peroxides 

NE NE 

Hexylene glycol 

NE NE 

Hydrogen peroxide 

1 ppm NE 

Methyl ethyl ketone 

200 ppm 300 ppm 

Water 

NE NE 

Section 9 -

Boiling Point, C: 

Freezing Point, C: 

Specific Gravity: 

Vapor Pressure @ 20 C: 

Vapor Density: 

air*=l 

Evaporation Rate: 

Butyl acetate=l 

% Volatiles: 

Solubility in Water: 

0.7 ppm 

25 ppm 

NE 

NE 

NE 

NE 

5mg/m3 

NE 

NE 

1 ppm 

200 ppm 

NE 

PROTECTION 

ACGIH TLV 

STZL 

NE 

NE 

0.2 ppm 

25 ppm 

NE 

300 ppm 

i 

NE 

PHYSICAL & CHEMICAL DATA 

NE 

below -30°C 

1.0840 min. 

4.8mraHg®68F 

NE 

NE 

NE 

Slight 

CEILING 

ME 

NE: 

0 .2 ppm 

2 5 ppm 

STE; 

ME 

NE 

Appearance and Odor: 

Clear oily liquid, ketone odor 

SADT = 70°C - 45 lbs. in a 5 gallon container. 

SADT - Self Accelerating Decomposition Temperature. Lowest 

temperature at which the tested package size will undergo a se 

accelerating decomposition reaction. This reaction will genei 

flammable vapors which may autoignite. The length of time to 

a decomposition reaction, after the SADT has been reached or e 

is dependent upon how much the SADT has been exceeded and the 

of time needed for the reaction exotherm (heat spike from inci 

decomposition rate) to initiate a rapid decomposition reactior 

Typically, SADT is inversely proportional to package size. Lc 

packages will have a lower SADT due to a smaller ratio of heat 

1:: 

ate 

generate 

xceeded, 

length 

easing 

rger 

MSDS CODE: 129000 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, 

Date: 

Page: 

INC. 

31/06/97 

5 Of 13 

Tfi 
P.32 

MATERIAL SAFETY DATA SHEET 

Section 9 - PHYSICAL t CHEMICAL DATA 

transfer rea to volume of product 

Section 10 - STABILITY & REACTIVITY 

STABILITY: 

This material is chemically unstable and should only be haniled under 

specified conditions. See HANDLING AND STORAGE section of :his MSDS 

for specified conditions. 

INCOMPATABILITY: 

Contamination with foreign materials such as strong acids, .strong 

alkalis, strong oxidizers, transition metal salts, reaction 

accelerators/promoters or reducing agents may result in a self 

accelerating decompostion reaction. 

Rust, copper and brass are not compatible with MEK peroxide 

316 stainless steel, glass, polyethylene, polytetrafluoroethylene and 

polypropylene are preferred materials for contact with MEK peroxide. 

Acetone may react with residual hydrogen peroxide to form insoluble 

shock-sensitive diacetyl peroxide crystals. 

HAZARDOUS DECOMPOSITION PRODUCTS: 

Decomposition products are flammable. 

HAZARDOUS POLYMERIZATION: 

Does not occur. 

Section 11 - TOXICOLOGICAL INFORMATION 

Elf Atochem North America, Inc. has not conducted toxicity studies on 

Lupersol DDM-9, and no information on this or similar mixture's was 

found in a search of the scientific literature. However, the 

components of this material have been tested and the data are 

summarized below. 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

Following an allergic skin reaction in a paint sprayer, patch 

testing produced an allergic skin reaction with MEKP as well as 

other components of the paint. However, subsequent patch tc:sting 

did not produce allergic skin reactions in 34 healthy subjects. 

Swallowing of MEKP was reported to cause liver injury in one case 

report. 

Single exposure (acute) studies on 40-60V MEKP in dimethyl phthalate 

indicate that it is moderately toxic to rats if swallowed (LD50 4 84 

mg/kg), slightly toxic to rabbits if absorbed through skin (LD50 

MSDS CODE: 129000 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, INC. 

Date: Cl/06/97 

Page: 6 of 13 

3C» *ZJ 
P.33 

MATERIAL SAFETY DATA SHEET 

Section 11 - TOXICOLOGICAL INFORMATION 

4,000 mg/kg), practically non-toxic to rats if inhaled (4-hr LC50 

17-50 mg/l),. corrosive to rabbit eyes and moderately irritating co 

rabbit skin (4-hr exposure, 4.5/8.0). Repeated oral admir.istracion 

of MEKP was reported to result in decreased body weight, mild liver 

and kidney injury and death in rats. Following repeated application 

of MEKP in dimethyl phthalate to the skin of rats and mice. severe 

skin damage and animal deaths (only at the highest dose levels) were 

the primary effects. Spleen and bone marrow changes considered 

secondary to the severe skin damage were noted in animals at the 

high doses. Higher doses applied to rat and mouse skin fcr a 

shorter time produced similar effects. Long-term repeated skin 

application of MEKP in dimethyl phthalate was reported to enhance 

skin tumor production in mice irradiated with UVB. MEKP has 

produced genetic changes in standard tests using bacterial or animal 

cells. However, no genetic changes occurred in a standard test 

using animals. 

2,2,4-TRIMETHYL-l,3-PENTANEDIOL DIISOBUTYRATE: 

Acute studies indicate that 2,2,4-trimethyl-l,»3-pentanedicl 

diisobutyrate is no more than slightly toxic to rats if swallowed 

(LD50 >3,200 mg/kg), practically non-toxic to guinea pigs al" 

absorbed through skin (LDSO >20 ml/kg) , practically non-tc:c:.c to 

rats if inhaled (6-hr LC50 >5.3 mg/l), slightly irritating to rabbit 

eyes and slightly irritating to guinea pig skin. No skin allergy 

was observed in guinea pigs following repeated exposures to 

2,2,4-trimethyl-l,3-pentanediol diisobutyrate in controlled skin 

contact studies. Increased liver weights, which were probably 

adaptive changes due to the induction of drug metabolizing enzymes 

in these tissues, were observed in rats or dogs fed 

2,2,4-trimethyl-l,3-pentanediol diisobutyrate (up to 1%) in their 

feed for up to 103 days. 2,2,4-Trimethyl-l,3-pentanediol 

diisobutyrate is eliminated in the excreta of rats followinc- a 

single oral dose with little or no retention in the tissues} or 

organs. 

HEXYLENE GLYCOL: 

Skin application of 50% hexylene glycol in water showed only minimal 

irritation in human volunteers, while repeated application of 

consumer products containing up to 1% hexylene glycol did not show 

irritant or sensitizing effects in humans. Patch tests have shown 

sensitization responses in individuals working with cutting oils 

containing hexylene glycol. 

Acute studies indicate that hexylene glycol is slightly tox:.c to 

rats, rabbits, mice and guinea pigs if swallowed (LD50 2,80C-4,700 

mg/kg), practically non-toxic to rabbits if absorbed through skin 

(LD50 12,300 mg/kg), severely irritating to rabbit eyes and 

moderately irritating to rabbit skin. No deaths occurred :.r:. rats 

exposed to about 160 ppm hexylene glycol for 8-hours. Rata and 

rabbits exposed to hexylene glycol (0.7 mg/l) for 9 days d:.ci not 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 7 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

3_ 
P.34_ 

MATERIAL SAFETY DATA SHEET 

1 Section 11 - TOXICOLOGICAL INFORMATION 

show any adverse effects. Hexylene glycol in the diet at up to 150 

mg daily for 4 months produced no adverse effects on growth, 

behavior or fertility in rats. Changes in the kidney wer.i noted at 

20 0 mg/day. Hexylene glycol has not produced genetic changes or 

chromosomal effects in standard tests using bacterial or animal 

cells. 

METHYL ETHYL KETONE (MEK): 

Repeated exposure of humans to MEK controlled skin contact: studies 

produced no skin irritation or skin allergy. Central nervous system 

(CNS) effects and peripheral neuropathy have been reported in the 

industrial setting following exposure to mixtures containing MEK* 

however, these mixtures contained other solvents known to cause 

nervous sytem injury. 

Acute studies indicate that MEK is no more than slightly toxic to 

rats if swallowed (LDSO 2,700 to 5,600 mg/kg), practically non-toxic 

to rabbits if absorbed through skin (LDSO 5,000 to 13,000 mg/kg) or 

rats if inhaled (4-hr LC50 11,700 ppm) and moderately irritating to 

rabbit eyes and skin. Following repeated inhalation exposure, 

slight changes in organ weights and blood chemistry were reported in 

rat3. No evidence of nervous system injury following lone-term 

inhalation exposure to MEK has been observed 'in rats, chickens, mice 

or cats. Animal studies have shown MEK to increase the severity of, 

or shorten the onset of, irreversible nervous system effects; due to 

n-hexane and methyl butyl ketone, as well as effects of chloroform 

and carbon tetrachloride. MEK did not increase the incidence of 

tumors in long-term skin application studies in mice. A small 

number of major birth defects were reported in rats exposed to MEK 

by inhalation during pregnancy at a level (3,000 ppm) which produced 

toxic effects in the offspring, but not in the mothers. However, no 

birth defects were found in a second repeat study with rats using 

very similar exposure conditions, while adverse effects were noted 

in the mothers and their offspring. In mice exposed to 3000 ppm MEK 

by inhalation during pregnancy, toxic effects were observed in the 

mothers (mild effects only) and their offspring. MEK has generally 

produced no genetic changes in standard tests using animals and 

animal or bacterial cells. A positive response was reported in one 

assay using yeast cells. 

Section 12 - ECOLOGICAL INFORMATION 

ECOTOXICOLOGICAL INFORMATION 

Elf Atochem North America, Inc. has not conducted ecological effect 

studies on Lupersol DDM-9, and no information on this or similar 

mixtures was found in a search of the scientific literature. However, 

the components of this material have been tested and :he data are 

MSDS CODE: 129000 Date: C1/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 8 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

33 
P.35 

MATERIAL SAFETY DATA SHEET 

Section 12 - ECOLOGICAL INFORMATION 

summarized below. 

ECOTOXICOLOGICAL INFORMATION: 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

MEKP is slightly toxic to guppies (96-hr LC50 44.2 mg/l). 

2,2,4-TRIMETHYL-l,3-PENTANEDIOL DIISOBUTYRATE: 

2,2,4-Trimethyl-l,3-pentanediol diisobutyrate is no more chan 

moderately toxic to most aquatic organisms on an acute basi:;i with 

LC50 values >1.55 mg/l for the fathead minnow, ramshorn sr--.il, 

aquatic earthworm, sideswimmer, pill bug and flatworm. It :.s no 

more than moderately toxic to daphnid (EC50 >1.46 mg/l). 

HEXYLENE GLYCOL: 

Hexylene glycol has been reported to be practically non-tox:.c to a 

variety of aquatic organisms by acute toxicity testing. Fre.shwater 

fish including rainbow trout, bluegill sunfish, fathead minnow, 

mosquito fish, goldfish and channel catfish had LC50 values in 

excess of 1,000 mg/l and generally were in the range of B# 000 to 

10,000 mg/l. Aquatic invertebrates such as Daphnia and crayfish had 

EC50 values greater than 2,800 mg/l. 

METHYL ETHYL KETONE (MEK): 

MEK is practically non-toxic to goldfish, brine shrimp, Daphnia 

magna, fathead minnow, mosquito fish, bluegill sunfish and golden 

orfe (LC50s >1,000 mg/l). MEK inhibits fungal growth and is 

reported to be bacteriostatic to several microorganisms (Escherichia 

coli, Salmonella typhimurium, Staphylococcus aureus, Leucor.ostoc 

citrovorum and Streptococcus thermophilus) at level3 of 10-100 mg/l. 

Growth inhibition has also been reported for freshwater al-ja.e at 

levels ranging from 120 mg/l (blue-green algae) to 4,300 m:r/l (green 

algae) . 

CHEMICAL FATE INFORMATION: 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

MEKP was reported to be readily biodegradable in a closed nettle 

system. An EC50 of 16 mg/l was reported in an activated sludge 

respiration inhibition test. 

2,2,4-TRIMETHYL-1,3 -PENTANEDIOL DIISOBUTYRATE: 

In a 28-day modified Sturm Test, 2,2,4-trimethyl-l, 3-penta.^ediol 

diisobutyrate was found to undergo 32-59% degradation to C02. The 

bioconcentration factor without metabolism was estimated tc- be 670 

and with metabolism 1-40. The log Pow of 2,2,4-trimethyl-1,3-

pentanediol diisobutyrate is estimated to be 4.1. 

HEXYLENE GLYCOL: 

Chemical oxygen demand (COD) and biological oxygen demand (30D) 

indicated that hexylene glycol is readily biodegraded. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 9 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

33) 
P.36 

MATERIAL SAFETY DATA SHEET 

Section 12 - ECOLOGICAL INFORMATION 

METHYL ETHYL KETONE (MEK): 

Extensive data suggests that MEK is readily biodegradable It is 

non-toxic to sludge microorganisms at concentrations up to 300 ug/l 

Section 13 - DISPOSAL CONSIDERATIONS 

Dispose in accordance with federal, state and local regulations. 

Dilution followed by incineration is the preferred metRod. Dilution 

ratio of 10:1 in a clean, compatible, combustible solvent (i.e. Fuel 

Oil #2, mineral oil) will reduce reactivity hazard during incineration 

and transportation. 

Section 14 - TRANSPORT INFORMATION 

DOT PROPER SHIPPING NAME: 

Organic Peroxide Type D Liquid 

TECHNICAL SHIPPING NAME: 

Methyl Ethyl Ketone Peroxide(s), <45% 

DOT HAZARD CLASS: 5.2 

UN NUMBER: 3105 

PACKING GROUP: II 

PRODUCT RQ (LBS): 

See below 

Section 15 - REGULATORY INFORMATION 

SARA HAZARD CLASSIFICATION 

Immediate (Acute) Health: yes 

Delayed (Chronic) Health: no 

Sudden Release of Pressure: no 

Reactive: yes 

Fire: yes 

SARA Title III, Section 302: 

This product does not contain any chemicals currently on the 

Extremely Hazardous Substance List, Section 302, SARA Title ..II, 

above the OSHA de minimis concentration. 

SARA Title III, Section 313: 

This product contains: 

Dimethyl phthalate 

131-11-3 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: ID of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

4 
P.37 

MATERIAL SAFETY DATA SHEET 

Section 15 - REGULATORY INFORMATION 

Methyl ethyl ketone 

78-93-3 

which are listed on the Toxic Chemical List, Section 313, S.VRA 

Title III. 

CERCLA RQ 

This product contains: 

Dimethyl phthalate 

131-11-3 5000 lbs. 

Methylethyl ketone peroxides 

1338-23-4 10 lbs. 

Methyl ethyl ketone 

78-93-3 5000 lbs. 

California Propostion 65: 

This product does not contain any chemicals currently listec on 

the California List of known Carcinogens. 

California Propostion 65: » 

This product does not contain any chemicals currently listed on 

the California List of known Reproductive Toxins. 

Pennsylvania Right-to-Know 

Hazardous Substance List 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the Pennsylvania Hazardous Substance List. 

Pennsylvania Right-to-Know 

Environmental Hazardous Substance List 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the Pennsylvania Environmental Hazardous 

Substance List. 

MSDS CODE: 129000 Date: O.L/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 11 ot lJ 

ELF ATOCHEM NORTH AMERICA, INC. 

_J 
P.38 

MATERIAL SAFETY DATA SHEET 

Section 15 - REGULATORY INFORMATION 

Pennsylvania Right-to-Know. 

Special Hazardous Substance List 

This product does not contain any chemicals currently on ;he 

Pennsylvania Special Hazardous Substance List, above the CSHA 

de minimis concentration. 

Massachusetts Right-to-Know 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 ., 

which are listed on the Massachusetts Hazardous Substance LLst 

New Jersey Right-to-Know 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

133B-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the New Jersey Hazardous Substance Lis*; 

Section 16 - OTHER 

Legend 

N/A - Not Applicable 

NE - Not Established 

NJTSN - New Jersey Trade Secret Number 

Lupersol, Luperco, Luperox, Peroximon and Retilox are registered 

trademarks of Elf Atochem, North America, Inc. 

MSDS CODE: 129000 Date: C1/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 12 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

3>(JO> 
P.39 

MATERIAL SAFETY DATA SHEET 

Section 16 - OTHER 

Issued: 01/06/97 Rev. 0 

Supersedes: 07/12/95 

Elf Atochem North America, Inc. believes that the information and 

recommendations contained herein (including data and statement:*)) 

are accurate as of the date thereof. NO WARRANTY OF FITNESS 101 ANY 

PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OP. ANY OTHER WARRANTY, 

EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. 

The information provided herein relates to the specific produc :. 

designated and may no be valid where such product is used in 

combination with any other materials or in any process. Further, since 

the conditions and methods of use of the product and of the ir. format ion 

referred to herein are beyond the cbntrol of Elf Atochem, Elf Atochem 

expressly disclaims any and all liability as to any results obtained 

or arising from any use of the product or reliance on such information. 

MSDS CODE: 129000 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, INC. 

Date: 01/06/97 

Page: li of 13 

r3-
P.40 

SOURCE DESCRIPTION - SUPPLEMENTAL 

al Resources AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-102A 11-93 Information attached? _ (y/n) 

_ .___;. iorm is required by the Department for any air pollution control pennit application filed pursuant to s. 144.392 or 

.925, Wis Stats. Completion of this fonn is mandatory. The Department will not consider or act upon your application 

is you complete and submit this form. It is not the Department's intention to use any personally identifiable infonnation from 

:orm for any other purpose. 

List all significant existing or proposed air pollution units, operations, and activities at the facility. A shon narrative of the 

inventory of air pollution emissions unit (e.g., boiler, printing line, etc) followed by equipment specifications will suffice. If 

the facility consists of several individual emission units, present this information in an outline format (See instruction 

booklet for an example Unit description.) Comor o P^ocnr's Pd-SOl - P01-S03, 

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Resources 

STACK IDENTIFICATION 

AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-103 11-93 Infonnation attached? _ (y/n) 

" • - TIONS ON REVERSE SIDE 

^ acuity name: 

iTdJA Fl&F^/Afr MOLT.IU6 

2. l^^jtpSM^afi^n^ffien 3. Su^ili^tifif^dn^umben 

S0X - SD?. 

EMaustin^ 109 

30-104 4530-106 4530-107 4530-108 4530-109 

Identify this stack on the plot plan required on Form 4530-101 

£3 This stack has an actual exhaust point. • This stack serves to identify fugitive emissions. 

If this stack has an actual exlmstpwint, then-provide the fbUow^ ^k?p^ameters 

Discharge height above ground Jewel: . (feet) Ly

 ,Ovv / O^P (> '3 3 ' (TK THZ OTHZ*., 

Inside dimensions at outlet (check one and complete): 

. W- K I 

J i Circular J^wV^^BS ' **'*s • D rectangular , length (feet) width (feet) 

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l^^Si^P^Mi^iffi_i^§ffl!?*ii J3*£_ (°p) 

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exhausf gases from, the stack? 

*** Complete the appropriate Air Pennit Application Forms(s) 4530-104, 106,107, 108 or 109 for each Unit ***•* 

exhausting through this stack. 

~1~H£S£ % STACKS. j \ n-E Senuive. 3 , pts.oc^i< ^aLAWi»+Ti*tj+t~T*<>ir-iui) 

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P.42 

/ Vanii-l Resources 

' - • TIONS ON REVERSE SIDE 

PAINTING AND COATING OPERATIONS 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-108 11-93 Infonnation attached? _ (y/n) 

~'iy name:Pt_«<r_)K £t.r.a^e./A.rt Mdi r>/_.<_ 

Sjt^^idmaGc^on.}h^ba: <? AQ _.r> ;*»--•» 

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Process; number: 

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EXHAlsCT STACIC 

Poi 

Indicate the control technology status: ^Uncontrolled D Controlled 

If the processes cpjErttblled," ent^ the'contfol devicernumb«(s) from die appropriate form(s): 

4530-110. 

4530-114 

4530-111, 

4530-115 

4530-112. 

4530-116 

4530-113. 

4530-117 

Application* technique and transfer efficiency (%): 

Date o^-cqnsmictiim-w.li-sLoiqdi^^pa 

Nonnal-operating schedule: _£_ hrs/day 

Oven curing (complete if applicable): 

Number of ovens 

Total Maximum Energy input to each oven: 

&.S °)n FLour.AA-rrn. m* 

*T days/wk 2.SH days/yr 

Specify oven fuels 

Describe all of the coatings' and solvents' composition (as applied) that are used by this unit. 

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P.43 

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INSTRUCTIONS ON REVERSE SIDE 

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11 A T E R I A I... S A !:" E T Y D A T A S H E. E T 

COATINGS,. RESINS.. AND RELATED MATERIALS 

•iUFACTURED BY:: ' EMERGENCY CONTACT:: CHEMTREC 

>i h o r t e r.. T e <:: hn o I O G :i. es., I n <::.. 

;> East Cottage Place 

r Den te rs v :i. 11 e ,, I! 60110 

::0R!'lATI0M CONTACT:: 1-800--882--1371 

TE OF PREP s 5/20/94 SUPERSEDES DATE:: 5/1 

ECTION I :-R0DUCT I DENT IFI CAT' I ON 

ODUCT' NAME:: 

2 7216 

ODUCT CLASS:: .. ._„„,.,,,,.., . .... 

SATURATED POLYESTER RESIN l^wi^fe^^**: ^ 

iIPPING DESCRIPTIONS 

.SIN SOLUTION,, 

3 UN 1866,, PG III 

(MARINE POLLUTANT., CONTAINS STYRENE MONOMER) 

(INTERNAL REF .. ti 16 

;;:CTION rx. HAZARDOUS INGREDIENTS 

iZARDOUS MATERIALS IDENTIFICATION SYSTEM 

•ALTH:: 2 * FLAMMABILITY:: 3 

::ACTIV:I:TY:: :I. 

-IGREDIENT 

CAS NO.. 

TYRENE 

100-42 -5 

WT„ TLV 

:

'ERCENT ppm fnq/m3 

SOURCE 

50 ,.0000 21 5, .00 TWA/ACGIH 

100 ,,0000 425..00 FEDERAL PEL 

100 ,,0000 42 5.. 00 STEL/ACGIH 

IDLH \ 

opm PR 

(mm 

:

 ftp OF: 

ESSUr 

Ha <<•<! 

i"-

SECT'ION !".:• i..i v <: HYSICAL DATA 

OILING RANGE:: 277--410 p 

PEC I FIC GRAVITY 1.. 098 

APOR DENSITY (AIR^l) :: 21.982 

OLATILE ORGANIC CONTENT (VOC):: 

PERCENT VOLATILE BY VOL:: 

EVAPORATION RATE (n-Bu Ac:==: 

VAPOR PRESSURE (mm Hq<<!68F) 

406 qrams/liter 

PPEARAMCE AND ODOR? light straw colored solution 

GLUBILITY IN WATERS neqliqible 

•tyrene 

SECTION IV. "IRE AND EXPLOSION HAZARD DATA 

LASH POINT:: 86 DEG.. F SETAFLASH GSHA CLASSIFICATION: 

L.AMMABLE LIMITS ";'. BY VOLUME IN AIR AT 212 DEG.. F:: 

LOWER EXPLOSION LIMIT;: • 1 .. 10 

UPPER EXPLOSION LIMIT:: 7..00 

XTINGUISHING MEDIA:; 

Use -foam., carbon dioxide or chemical i::i. re ,Tiqhtina 

r-1- ' 
P.47 

ECT I ON IV.. IRE AND EXPLOSION HAZARD DATA 732 7216 (CONT., } 

Kee::. containers tightly closed,, Isolate from heat, 

electrical equipment., sparks and open flame.. Closed 

containers may ex Diode when exposed to extreme Tie at,. 

ECIAL FIRE FIGHTING PROCEDURES 

'The use of self--con tained breathing apparatus is recommended 

for fire fighters,. Water spray may be used for cooling 

containers to prevent possible pressure build-up and autoignition or explosion when exposed to extreme heat,. 

Avoid spreading burning liquid with water used for cooling.. 

SECTION V. HEALTH HAZARD DATA 

iRESHOLD LIMIT VALUE:: 

See Sec:tion II.. 

•ECTS OF OVEREXPOSURE:: 

- EYES CONTACT:; 

Severe irritation., redness., tearing and blurred vision.. 

• SKIN CONTACT:: 

Prolonged or repeated exposure can cause moderate irritation., 

defa11inq ,, dermati tis and sens:i. tizatior... 

• INHALATIONS 

Excessive inhalation of vapors can cause nasal and respirator) 

i i- i'i tation., -dizziness., weakness., fatigue,, nausea and headache, 

High concentrations may result in narcosis,. (Central Nervous 

Syste _ n d e p re s s i on) 

• INGESTION. 

Can cause gastrointestinal irritation., nausea., vomiting and 

diarrhea,, Aspiration of material into lungs can cause 

chemical pneumonitis which can be fatal.. 

ironic exposure may cause damage to the Central Nervous System, 

••jsoiratory System,, Lungs., Eyes,, S k:i. n ., Gastrointestinal Tract... 

i.ver,, Spleen and Kidneys,, 

THER HEALTH EFFECT'S:: 

vised upon a re-evaluation of previous, negative and equivocal data 

"id <->s\ increased incidence of lung tumors after' oral administration 

"i voting adult mice., the International Agency for Research on 

yu"!cer (IARC) has listed styrene among those materials 'for which 

here :i.s limited evidence for carcinogenicity in animals.. 

:'GENCY AND FIRST AID PROCEDURES 

EYES CONTACT:: 

Flush with clean., lukewarm water for at least 15 minutes., 

occasionally lifting the eyelids., Obtain medical attention,, 

SKIN CONTACT:: 

Remove contaminated clothing.. Wash affected skin areas 

thoroughly with soap and water., Wash contaminated clothing 

thoroughly before re—use„ 

INHALATION:: 

4^>" 
*•••• - r .•'•' . > i i HEALTH HAZARD DATA 

Remove t,:::, -fresh air,. Apply artificial respiration or administer 

oxygen, if necessary,, Call a physician immediately,, 

INGESTION:: 

Keep person warm,, quiet and get immediate medical attention,. 

Do not induce vomiting,, because aspiration 'of material into 

the lungs 'from vomiting can cause chemical pneumonitis which: 

can be Ta ta 1 „ 

.ECTI ON V I REACTIVITY DATA 

ABILITY ! 

Stable under normal conditions.. Avoid exposure to excess!1 

(COMPATIBILITY:: 

Avoid contact with strong mineral acids 

noiyfiler'x xation catalysts ., 

Pt-.T I.... .1. (.1 <..:'-.::• < \nd 

iZARDOUS POLYMERIZATION: 

Can Occur.. 

iZARDOUS DECOMPOSITION PRODUCTS:: 

Thermal decompositio n may yiel d carbon dioxid e and/o r monoxide., 

il... IFORNIA SCAQMD RULE 443., I s 

Thi s produc t contain s photochemicall y reactiv e volatil e ora< 

compound (s ) ,. Refer t o Sectio n I I and 

SECTION VII,, SPILL OR LEAK PROCEDURES 

"EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: 

Evacuate all non-essential personnel,. Remove all sources of 

ign ition.. Ventilate the area.. Equip employees with appropriate 

protection equipment (See Section VIII),. Dike around soi 1 led 

material.. Cover spill with inert absorbent material and shove! 

with non-sparking tools into container,, Remove containers to a 

area and seal„ 

i •::> i .'::. .i.nSPOSA ' .1. -.:: L METHOD:: 

Waste material must be disposed of in accordance withfedera] 

state., and local environmental reuulatory controls.. 

SECTION VIII SPECIAL PROTECTION INFORMATION 

.PIRATORY PROTECT'ION;; 

Avoid breathing vapor' or mist,. If exposure may or does exe:. 

occupational exposure limits (SEC. IV) use a NIOSH —approved 

!"•! rator to prevent overexposure,, In accord with 29CF'R 1910, 

use either a full—face,, atmosphere—supplying respirator or' 

ai r —purifying respirator for organic vapors,, 
ECTION VIII. SPEC I Al... F'RO'TECT I ON INFORI'IAT I ON 732 7216 (CONT „ ) 

NTILATIOHs 

Local exhaust must be sufficient to keep airborne vapor 

co n centra t i o n s b e I o w t h e TI... V I i m i t „ E xhaust a :i. r' may need 

cleaned by scrubbers or filters to reduce environmental 

con tamination .. 

OTECTIVE GLOVES:: 

P o 1 y v :i. n y 1 a I <:: o h o 1 g I o v e s „ 

E PROTECTIONS 

S p 1 a s h g o g g 1 e s.. 

HER PROTECTIVE EQUIPMENTs 

F'olyvinyl alcohol apron,, Eye bath and safety shower,, To 

repeated or prolonged skin contact,, wear impervious clotl 

boots.. 

.ZARDOUS MATERIALS IDENTIFICATION SYSTEMs 

See first page of MSDS.. 

prevent 

rino *no 

SECTION IX. SPEC I Al... PRECAUT IONS 

^CAUTIONS TO BE TAKEN IN HANDL.ING AHD STORING:: 

Drums:: Protect against physical damage.. Outside or detached 

storage preferred,, 

Bulk:: Storage should be in standard flammable liguid storage 

tanks., 

•IER PRECAUTIONS:: 

All equipment should be grounded and bonded to reduce 

eiectr i city ha>:•:ard „ Use non•••• spar king tooIs „ 

static 

Overexposure to material has apparently been found to cause 

following effects i.n laboratory animals:: liver abnormalities 

kidney damaqe., I unci cla ma cie.. 

th. 

RECENT' DATA DOES NOT' SUPPORT THE CHANGE IN THE CLASSIFICATION 

BY I ARC: OF STYRENE TO BE A SUSPECTED CARCINOGEN., 

At the conclusion of a major notice and comment 

rulemaking revising its air contaminants regulations,, OSHA concluded that the "current 

evidence on styrene's carcinogenicity does not 

support its classification in the final rule as 

a carcinogen„ 

1989) :; see also 

Fe .eq „ 430 (Jan., 19, 

54 Feci,. Req „ at 2364,, In th 

same rulemaking., the National Institute for 

Occupational Safety and Health (NIOSH) commented that there "seems to be little basis 

4fr 
SPECIAL. PRECAUTIONS 

P.50 

from the experimental animal investigations or 

ep:i.demiCJ 1 ogi c stucl ies to con c 1 tide' at this time 

that styrene is carcinogenic," Moreover'., other 

scientists have independently concluded that 

styrene does not present a carcinogenic risk 

to humans.. I„ C „ llunro,, et al ., "A Review of 

Styrene Pbarmacokinetics ancl Carcinoaenicit.y" 

( Ju I y 21 , :!. 989 ) (Can "To x I n c „ 

Drinking Water Docket No,, I 

J 2.. S 6 „ Atta c h m e n t C ) -

D., Documen t 11 

OTHER COMMENT; 

recommend that containers be either professionally reconditioned 

i-" reuse by certified firms or properly disposed of by certified 

rms to help reduce the possibility erf an accident,, Disposal of 

n tain ers should be in accordance with appl i cable federal,, s'h'-e ...-.; 

cal laws and regulations. "Empty" drums should not be given to 

dl vidua Is.. 

e information in this MSDS was obtained from sources which we 

iieve are reliable,, However, the information is provided without 

y representation or warranty., expressed or implied,, regarding iti 

curacy or completeness., 

e conditions of handling,, storage,,' use and disposal of the prod 

e beyond our control and may be beyond our knowledge-?.. For this 

her reasons,, we dc? not assume responsibility and expressly disc 

ability for loss,, damage or expense arising out of or in any wa. 

nnected with the handling, storage,, use or disposal ie product 

4: 
P.51 

E N- V I R 0 N M E l-l T A I... D A T A S H E E "T 

;i..K'K;K*: MUST NOT BE DETACHED FROM MATERIAL SAFETY DATA SHEET ')<?.<:**:>!< 

ofc IF MSDS IS COPIED AND REDISTRIBUTED, THIS NOTICE MUST BE ATTACHED ***(< 

iNUFACTURED BY:: McWhorter Technologies DATE OF LAST CHANGE:: 94/02/19 

400 East Cottage Place 

Carpentersville., II 60110 

.ODUCT NAME:: 732 7216 

-.ODUCT CLASS:: UNSATURATED POLYESTER RESIN 

SECTION I .. PRODUCT IDENTIFICATION/COMPOSITION 

".OD COMPONENT CAS NUMBER PERCENT 

P UNSATURATED POLYESTER RESIN MIXTURE 100 

TYPICAL DISTRIBUTION OF HAZARDOUS COMPONENTSSTYRENE 

I O'".--.:: t '•'•''••••'. 

SECTION II. SARA TITLE III INFORMATION 

W D EHS RO (LBS) EHS TPO. (LBS) SEC 313 311/312 CATEGORIES 

(*1) (*2) (#3) (*4) 

P 53,024 1 3 4 5 

1 YES 1 3 4 5 

7 - -—FOOTNOTES •-•-••-

!. •••= REPORTABLE QUANTITY OF' EXTREMELY HAZARDOUS SUBSTANCE., SARA SEC ..302/304 

Z -• THRESHOLD PLANNING QUANTITY,, EXTREMELY HAZARDOUS. SUBSTANCE,, SARA SEC „ 302 

3 == TOXIC CHEMICAL,, SARA SEC 313 

•'. » HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING 

1 ••••••• FIRE HAZARD 2 ***• SUDDEN RELEAS E OF PRESSUR E HAZAR

3 ••••••• REACTIVE HAZARD 4 »• IMMEDIATE (ACUTE) HEALTH HAZARD 

5 •- DELAYED (CHRONIC) HEALTH HAZARD 

SECTION III„ DOT/CERCLA INFORMATION 

•IE CERCLA REPORTABLE QUANTITY (RQ) FOR THI.;; MIXTURE IS 8:1.4 LBS,. 

•ITCH IS BASED ON THE RQ OF EACH INGREDIENT AND ITS PERCENT IN MIXTURE.. 

SECTION IV.. ADDITIONAL REGULATORY INFORMATION 

FIE F'OLYMER ANJ) ALL. COMPONENTS OF' THIS PRODUCT ARE PRESENT ON THE UNITED 

TATES TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL. SUBSTANCES INVENTORY. 

HE POLYMER AND AU... .COMPONENTS OF' THIS PRODUCT ARE PRESENT ON "CHE CANADIAN 

HVI RONMENTAL PROTECTION ACT (CEPA) DOMESTIC SUBSTANCES • LIST (DSL)., 

49 
; INFORMATION IN THIS MSDS AND ENVIRONMENTAL DATA SHEET WAS OBTAINED 

)M SOURCES WHICFI WE BELIEVE ARE RELIABLE,, HOWEVER,. THE INFORMATION ] 

JVIDED WITHOUT ANY REPRESENTATION OR WARRANTY., EXPRESSED OR IMPLIED, 

iARDING ITS ACCURACY OR COMPLETENESS. 

P.52 

:CTION V U x c:>CLi-ii! Ii::.i'-. .... i i.!! II M , 
P.53 

MATERIAL SAFETY DATA SHEET 

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

Elf Atochem North America Customer Service: 

2000 Market Street 1-800-558-5575 Busine!S.3 Hours 

Philadelphia, PA 19103 Information: 

1-800-558-5575 Business Hours 

EMERGENCY TELEPHONE NUMBERS: 

CHEMTREC: (800) 424-9300 (24 hours) or (202) 483-7616 

MEDICAL: Rocky Mountain Poison Control Center 

(303) 623-5716 (24 hours) 

NAME USED ON LABEL: LUPERSOL DDM-9 

CHEMICAL NAME: Methylethyl ketone peroxide blend 

CHEMICAL FAMILY: Organic Peroxide - Ketone Peroxide 

PRODUCT USE: Polymerization initiator 

Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS 

Identity CAS 

6846-50-0 

131-11-3 

1338-23-4 

107-41-5 

7722-84-1 

'78-93-3 

7732-18-5 

No. 

Typical 

V 

23 .8 

32.0 

35.0 

S.O 

0.7 

1.0 

1.5 

OSHA 

Hazard 

N 

Y 

Y 

Y 

Y 

Y 

N 

2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 

Dimethyl phthalate 

Methylethyl ketone peroxides 

Hexylene glycol 

Hydrogen peroxide 

Methyl ethyl ketone 

Water 

TSCA Inventory Status: 

This product is TSCA compliant. The components are either on the TSCA 

inventory or are exempt as impurities. 

The substance(s) marked with a Y in the OSHA Hazard column above, are 

chose identified as hazardous chemicals under the criteria of chs: OSHA 

Hazard Communication Standard (29 CFR 1910.1200). 

Section 3 - HAZARDS IDENTIFICA^^O^A DWbfcdfcy 

VUM-_3_£_aCAL-C:3MMM¥-

Sit.Pau!,MN 

EMERGENCY OVERVIEW: ^0" ^ ft^S^..'-?-1 __»v 

Clear oily liquid, ketone- odor SISSS.^TM 

MSDS CODE: 129000 Date: Cl/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 1 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

61 
P.54 

MATERIAL SAFETY DATA SHEET 

Section 3 - HAZARDS IDENTIFICATION 

DANGER! 

ORGANIC PEROXIDE 

CAUSES EYE BURNS 

MAY CAUSE BLINDNESS 

MAY CAUSE SKIN IRRITATION 

MAY CAUSE ALLERGIC SKIN REACTION 

HARMFUL IF SWALLOWED 

POTENTIAL HEALTH EFFECTS: 

Skin contact and inhalation are expected to be the primary routes of 

exposure to Lupersol DDM-9. Based on its composition, Lupeisol DDM-9 

is anticipated to be moderately toxic if swallowed, slightly toxic if 

absorbed through skin, practically non-toxic if inhaled, moderately 

irritating to skin and corrosive to eyes. Prolonged or repeated 

contact may cause an allergic skin reaction. Overexposure tc vapor 

may lead to digestive disorders, narcosis and central nervou.3 system 

(CNS) effects such as headache, dizziness, loss of coordination, loss 

of consciousness or convulsions. If swallowed, Lupersol DDM-S' may 

cause CNS effects as noted above, irritation of 'the mouth, throat and 

stomach and, in severe cases, death. 

Section 4 - FIRST AID MEASURES 

IF IN EYES: 

Immediately flush with plenty of water for at least 15 minutsE 

medical attention immediately. 

Get 

IF ON SKIN: 

Immediately wash with soap and plenty of water. Remove contaminated 

clothing and shoes. Get medical attention if symptoms occur. Wash 

clothing before reuse. Destroy contaminatd shoes. Thoroughly clean 

shoes before reuse. 

IF SWALLOWED: 

Induce vomiting immediately as directed by medical personnel. Get 

medical attention. Contact a Poison Control Center. NEVER GIVE 

ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. 

IF INHALED: 

Remove to fresh air. 

Section 5 FIRE FIGHTING MEASURES 

Flash Point (Test Method) 

Autoignition Temperature: 

58°C / 137°F (CC) 

NE 

MSDS CODE: 1290 00 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, INC. 

Date: 01/06/97 

Page: 2 of 13 
P.55 

MATERIAL SAFETY DATA SHEET 

Section 5 - FIRE FIGHTING MEASURES 

Flammable Limits: Upper: NE 

Lower: NE 

EXTINGUISHING MEDIA: 

Water fog, water spray, dry chemical, foam 

SPECIAL FIRE FIGHTING PROCEDURES: 

Fire fighters and others who may be exposed to products of combustion 

should wear full fire fighting turn out gear (full Bunker Gear) and 

self-contained breathing apparatus (pressure-demand NIOSH approved or 

equivalent). Fire fighting equipment should be thoroughly 

decontaminated after use. 

If a large amount is involved, evacuate area and fight fire from a 

safe distance. Do not use a solid stream of water. A solid stream of 

water can spread fire. Use water spray to disperse any flammable 

mists and vapors which have not ignited. 

FIRE AND EXPLOSION HAZARDS: ' 

Contact with incompatible materials or exposure to temperature is 

exceeding SADT (Section 9) may result in a self accelerating 

decomposition reaction with release of flammable vapors which 'nay 

autoignite. 

Section 6 - ACCIDENTAL RELEASE MEASURES 

IF A SPILL OR LEAK OCCURS: 

Use inert, noncombustible absorbent material. Sweep cr scoop up using 

non-sparking tools and remove. 

Section 7 - HANDLING & STORAGE 

HANDLING: 

Do not get in eyes, on skin or on clothing. 

Do not taste or swallow. 

Avoid breathing vapor or mist. 

Wash thoroughly after handling. 

Use only with adequate ventilation. 

Contact with incompatible materials or exposure to temperature-.*•_;• 

exceeding SADT (See Section 9) may result in a self accelerating 

decomposition reaction with release of flammable vapors which nay 

autoignite. 

Keep away from heat sparks and flame. 

Avoid contamination. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: "i" of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

S3, 
P.56 

MATERIAL SAFETY DATA SHEET 

Section 7 - HANDLING & STORAGE 

Use explosion proof equipment. 

Keep container closed. 

STORAGE: 

Store below 100°F(38°C) to maintain active oxygen content. 

Detached storage is preferred. 

Avoid excessive heat and store out of direct sunlight in a -:col 

well-ventilated place. 

Store away from combustibles and incompatible materials. 

Section 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION 

ENGINEERING CONTROLS: 

Investigate engineering techniques to reduce exposures belov/ airborne 

exposure limits. Provide ventilation if necess&ry to control exposure 

levels below airborne exposure limits. Dilution ventilation 

acceptable, but local mechanical exhaust ventilation preferred, if 

practical, at sources of air contamination such as open process 

equipment. Consult ACGIH ventilation manual or NFPA Standard 91 for 

design of exhaust systems. 

EYE PROTECTION: 

Where there is potential for eye contact, wear chemical gogel*3s and 

have eye flushing equipment immediately available. 

SKIN PROTECTION: 

Wear appropriate chemical resistant protective clothing and chemical 

resistant gloves to prevent skin contact. Latex, nitrile, reoprene, 

PVC or other impermeable gloves should be worn when handling this 

material. Wear face shield and chemical resistant clothing stich as a 

rubber apron where splashing may occur. Rinse contaminated skin 

promptly. Wash contaminated clothing and clean protective eguipment 

before reuse. Wash skin thoroughly after handling. 

RESPIRATORY PROTECTION: 

Avoid breathing vapors or mists. Use NIOSH approved full face organic 

vapor and mist respirator when airborn exposure limits are exceeded. 

If used, full facepiece replaces need for chemical goggles cr face 

shield. Consult respirator manufacturer if exposure limits are 

greater than ten times the the recommended exposure limits. Observe 

respirator use limitations specified by NIOSH or the manufacturer. 

For emergency and other conditions where exposure limit may bv. 

significantly exceeded, use. an approved full face positive-pre:ssure 

self-contained breathing apparatus or positive-pressure airline with 

auxiliary self-contained air supply. Respiratory protection programs 

must comply with 29 CFR 1910.134. 

MSDS CODE: 129000 Date: C'l/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 4 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 
P.57 

MATERIAL SAFETY DATA SHEET 

Section 8 - EXPOSURE CONTROLS £_ 

AIRBORNE EXPOSURE GUIDELINES 

OSHA PEL 

TWA STEL 

2,2,4-Trimethyl-l, 3-

NE NE 

Dimethyl phthalate 

5 mg/m3 NE 

-pent 

: 

CEILING 

PERSONAL 

TWA 

ane-diol diisobutyrate 

NE 

NE 

Methylethyl ketone peroxides 

NE NE 

Hexylene glycol 

NE NE 

Hydrogen peroxide 

1 ppm NE 

Methyl ethyl ketone 

200 ppm 300 

Water 

NE NE 

Section 

Boiling Point, C: 

Freezing Point, C: 

Specific Gravity: 

Vapor Pressure @ 20 

Vapor Density: 

air=l 

Evaporation Rate: 

Butyl acetate=l 

% Volatiles: 

Solubility in Water: 

Appearance and Odor 

ppm 

9 -

C: 

Clear oily liquid, 

0.7 ppm 

25 ppm 

NE 

NE 

NE 

NE 

5mg/m3 

NE 

NE 

1 ppm 

200 ppm 

NE 

PROTECTION 

ACGIH TLV 

ST2L 

NE 

NE 

0.2 ppm 

25 ppm 

NE 

300 ppm 

i 

NE 

PHYSICAL Sc CHEMICAL DATA 

NE 

below -30°C 

1.0840 min. 

4.8mraHg@68F 

NE 

NE 

NE 

Slight 

ketone odor 

CEILING 

NE 

ME: 

0.2 ppm 

21 ppm 

NTE; 

VTE 

NE 

SADT = 70°C - 45 lbs. in a 5 gallon container. 

SADT - Self Accelerating Decomposition Temperature Lowest 

temperature at which the tested package size will undergo a se 

accelerating decomposition reaqtion. This reaction will genei 

flammable vapors which may autoignite. The length of time to 

a decomposition reaction, after the SADT has been reached or e 

is dependent upon how much the SADT has been exceeded and the 

of time needed for the reaction exotherm (heat spike from inc*e 

decomposition rate) to initiate a rapid decomposition reactior 

Typically, SADT is inversely proportional to package size. La 

packages will have a lower SADT due to a smaller ratio of heat 

1:: 

ate 

generate 

xceeded, 

length 

easing 

rger 

MSDS CODE: 129000 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, 

Date: 

Page: 

31/06/97 

5 of 13 

INC. 
P.58 

MATERIAL SAFETY DATA SHEET 

Section 9 - PHYSICAL...- CHEMICAL DATA 

cransfer rea to volume of product. 

Section 10 - STABILITY & REACTIVITY 

STABILITY: 

This material is chemically unstable and should only be haniled under 

specified conditions. See HANDLING AND STORAGE section of :his MSDS 

for specified conditions. 

INCOMPATABILITY: 

Contamination with foreign materials such as strong acids, strong 

alkalis, strong oxidizers, transition metal salts, reaction 

accelerators/promoters or reducing agents may result in a self 

accelerating decompostion reaction. 

Rust, copper and brass are not compatible with MEK peroxide 

316 stainless steel, glass, polyethylene, polytetrafluoroethylene and 

polypropylene are preferred materials for contact with MEK peroxide. 

Acetone may react with residual hydrogen peroxide to form insoluble 

shock-sensitive diacetyl peroxide crystals. 

HAZARDOUS DECOMPOSITION PRODUCTS: 

Decomposition products are flammable. 

HAZARDOUS POLYMERIZATION: 

Does not occur. 

Section 11 - TOXICOLOGICAL INFORMATION 

Elf Atochem North America, Inc. has not conducted toxicity studies on 

Lupersol DDM-9, and no information on this or similar mixturefs was 

found in a search of the scientific literature. However, the 

components of this material have been tested and the data are 

summarized below. 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

Following an allergic skin reaction in a paint sprayer, patch 

testing produced an allergic skin reaction with MEKP as well as 

other components of the paint. However, subsequent patch testing 

did not produce allergic skin reactions in 34 healthy subjects. 

Swallowing of MEKP was reported to cause liver injury in one case 

report. 

Single exposure (acute) studies on 40-60V MEKP in dimethyl phthalate 

indicate that it is moderately toxic to rats if swallowed (LD50 484 

mg/kg), slightly toxic to rabbits if absorbed through skin (LD50 

MSDS CODE: 129000 

PRODUCT: LUPERSOL DDM-9 

ELF ATOCHEM NORTH AMERICA, INC. 

Date: Cl/06/97 

Page: 6 of 13 
P.59 

MATERIAL SAFETY DATA SHEET 

Section 11 - TOXICOLOGICAL INFORMATION 

4,000 mg/kg), practically non-toxic to rats if inhaled (4-h.:: LC50 

17-50 mg/l), corrosive to rabbit eyes and moderately irritating to 

rabbit skin (4-hr exposure, 4.5/8.0). Repeated oral admir..i.;_ tra tion 

of MEKP was reported to result in decreased body weight, mild liver 

and kidney injury and death in rats. Following repeated application 

of MEKP in dimethyl phthalate to the skin of rats and mice ', severe 

skin damage and animal deaths (only at the highest dose levels) were 

the primary effects. Spleen and bone marrow changes considered 

secondary to the severe skin damage were noted in animals at che 

high doses. Higher doses applied to rat and mouse skin fcr a 

shorter time produced similar effects. Long-term repeated skin 

application of MEKP in dimethyl phthalate was reported to enhance 

skin tumor production in mice irradiated with UVB. MEKP ha.-

produced genetic changes in standard tests using bacterial or animal 

cells. However, no genetic changes occurred in a standard test 

using animals. 

2,2,4-TRIMETHYL-l,3-PENTANEDIOL DIISOBUTYRATE: 

Acute studies indicate that 2,2,4-trimethyl-l_»3-pentanedic_. 

diisobutyrate is no more than slightly toxic to rats if swal.lowed 

(LD50 >3,200 mg/kg), practically non-toxic to guinea pigs il: 

absorbed through skin (LDSO >20 ml/kg) , practically non-tcxz.c to 

rats if inhaled (6-hr LC50 >5.3 mg/l), slightly irritating to rabbit 

eyes and slightly irritating to guinea pig skin. No skin al.lergy 

was observed in guinea pigs following repeated exposures to 

2, 2, 4-trimethyl-l,3-pentanediol diisobutyrate in controlled skin 

contact studies. Increased liver weights, which were probably 

adaptive changes due to the induction of drug metabolizing enzymes 

in these tissues, were observed in rats or dogs fed 

2,2,4-trimethyl-l,3-pentanediol diisobutyrate (up to 1%) in their 

feed for up to 103 days. 2,2,4-Trimethyl-1,3-pentanediol 

diisobutyrate is eliminated in the excreta of rats followinc;* a 

single oral dose with little or no retention in the tissues or 

organs. 

HEXYLENE GLYCOL: 

Skin application of 50% hexylene glycol in water showed cn..y minimal 

irritation in human volunteers, while repeated application of 

consumer products containing up to 1% hexylene glycol did not show 

irritant orJsensitizing effects in humans. Patch tests have shown 

sensitization responses in individuals working with cutting oils 

containing hexylene glycol. 

Acute studies indicate that hexylene glycol is slightly tox;.c to 

rats, rabbits, mice and guinea pigs if swallowed (LDSO 2,80C-4,700 

mg/kg), practically non-toxic to rabbits if absorbed through skin 

(LD50 12,300 mg/kg), severely irritating to rabbit eyes and 

moderately irritating to rabbit skin. No deaths occurred :.r:. rats 

exposed to about. 160 ppm hexylene glycol for 8-hours. Rats- and 

rabbits exposed to hexylene glycol (0.7 mg/l) for 9 days d._d not 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 7 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 
P.60 

MATERIAL SAFETY DATA SHEET 

Section 11 - TOXICOLOGICAL INFORMATION 

show any adverse effects. Hexylene glycol in the diet at up to 150 

mg daily for 4 months produced no adverse effects on growth! 

behavior or fertility in rats. Changes in the kidney were noted at 

20 0 mg/day. Hexylene glycol has not produced genetic changes or 

chromosomal effects in standard tests using bacterial or animal 

cells. 

METHYL ETHYL KETONE (MEK): 

Repeated exposure of humans to MEK controlled skin contact: studies 

produced no skin irritation or skin allergy. Central nervous system 

(CNS) effects and peripheral neuropathy have been reported in the 

industrial setting following exposure to mixtures containi.nq MEK; 

however, these mixtures contained other solvents known to cause 

nervous sytem injury. 

Acute studies indicate that MEK is no more than slightly toxic to 

rats if swallowed (LD50 2,700 to 5,600 mg/kg), practically non-toxic 

to rabbits if absorbed through skin (LDSO 5,000 to 13,000 mg/kg) or 

rats if inhaled (4-hr LC50 11,700 ppm) and moderately iriitating to 

rabbit eyes and skin. Following repeated inhalation exposure, 

slight changes in organ weights and blood chemistry were reported in 

rats. No evidence of nervous system injury following long-term 

inhalation exposure to MEK has been observed in rats, chickens, mice 

or cats. Animal studies have shown MEK to increase the severity of, 

or shorten the onset of, irreversible nervous system effects; due to 

n-hexane and methyl butyl ketone, as well as effects of chloroform 

and carbon tetrachloride. MEK did not increase the incidence of 

tumors in long-term skin application studies in mice. A small 

number of major birth defects were reported in rats exposed to MEK 

by inhalation during pregnancy at a level (3,000 ppm) which produced 

toxic effects in the offspring, but not in the mothers. However, no 

birth defects were found in a second repeat study with rats using 

very similar exposure conditions, while adverse effects were noted 

in the mothers and their offspring. In mice exposed to 3000 ppm MEK 

by inhalation during pregnancy, toxic effects were observed in the 

mothers (mild effects only) and their offspring. MEK has generally 

produced no genetic changes in standard tests using animals and 

animal or bacterial cells. A positive response was reported in one 

assay using yeast cells. 

Section 12 - ECOLOGICAL INFORMATION 

ECOTOXICOLOGICAL INFORMATION 

Elf Atochem North America, Inc. has not conducted ecological effect 

studies on Lupersol DDM-9, and no information on this or similar 

mixtures was found in a search of the scientific literature. However, 

the components of this material have been tested and :he data are 

MSDS CODE: 129000 Date: C1/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 8 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 
P.61 

MATERIAL SAFETY DATA SHEET 

Section 12 - ECOLOGICAL INFORMATION 

summarized below. 

ECOTOXICOLOGICAL INFORMATION: 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

MEKP is slightly toxic to guppies (96-hr LC50 44.2 mg/l). 

2,2,4-TRIMETHYL-1,3-PENTANEDIOL DIISOBUTYRATE: 

2, 2,4-Trimethyl-l,3-pentanediol diisobutyrate is no more than 

moderately toxic to most aquatic organisms on an acute basi:. with 

LC50 values >1.55 mg/l for the fathead minnow, ramshorn sra.i.1, 

aquatic earthworm, sideswimmer, pill bug and flatworm. It :.s no 

more than moderately toxic to daphnid (EC50 >1.46 mg/l). 

HEXYLENE GLYCOL: 

Hexylene glycol has been reported to be practically non-tox:.c to a 

variety of aquatic organisms by acute toxicity testing. Fretshwater 

fish including rainbow trout, bluegill sunfish, fathead minnow, 

mosquito fish, goldfish and channel catfish had LC50 values in 

excess of 1,000 rag/1 and generally were in the range of 8,000 to 

10,000 mg/l. Aquatic invertebrates such as Daphnia and crayfish had 

EC50 values greater than 2,800 mg/l. 

METHYL ETHYL KETONE (MEK): 

MEK is practically non-toxic to goldfish, brine shrimp, Daphnia 

magna, fathead minnow, mosquito fish, bluegill sunfish and golden 

orfe (LCSOs >1,000 mg/l). MEK inhibits fungal growth and is 

reported to be bacteriostatic to several microorganisms (Escherichia 

coli, Salmonella typhimurium, Staphylococcus aureus, Leucor.ostoc 

citrovorum and Streptococcus thermophilus) at level3 of 10-1.00 mg/l. 

Growth inhibition has also been reported for freshwater al^a.e at 

levels ranging from 120 mg/l (blue-green algae) to 4,300 m?/l (green 

algae). 

CHEMICAL FATE INFORMATION: 

METHYL ETHYL KETONE PEROXIDE STRUCTURES (MEKP): 

MEKP was reported to be readily biodegradable in a closed nettle 

system. An EC50 of 16 mg/l was reported in an activated sludge 

respiration inhibition test. 

2,2,4-TRIMETHYL-1,3 -PENTANEDIOL DIISOBUTYRATE: 

In a 28-day modified Sturm Test, 2,2,4-crimethyl-l, 3-penta:iediol 

diisobutyrate was found to undergo 32-59% degradation to C02. The 

bioconcentration factor without metabolism was estimated to be 670 

and with metabolism 1-40. The log Pow of 2,2,4-trimethyl-1,3-

pentanediol diisobutyrate is estimated to be 4.1. 

HEXYLENE GLYCOL: 

Chemical oxygen demand (COD) and biological oxygen demand (30D) 

indicated that hexylene glycol is readily biodegraded. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 9 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

git 
P.62 

MATERIAL SAFETY DATA SHEET 

Section 12 - ECOLOGICAL INFORMATION 

METHYL ETHYL KETONE (MEK): 

Extensive data suggests that MEK is readily biodegradable It is 

non-toxic to sludge microorganisms at concentrations up tc; 300 ug/l 

Section 13 - DISPOSAL CONSIDERATIONS 

Dispose in accordance with federal, state and local regulations. 

Dilution followed by incineration is the preferred metEod. Dilution 

ratio of 10:1 in a clean, compatible, combustible solvent (i.e. Fuel 

Oil #2, mineral oil) will reduce reactivity hazard during incineration 

and transportation. 

Section 14 - TRANSPORT INFORMATION 

DOT PROPER SHIPPING NAME: 

Organic Peroxide Type D Liquid 

TECHNICAL SHIPPING NAME: 

Methyl Ethyl Ketone Peroxide(s), <45% 

DOT HAZARD CLASS: 5.2 

UN NUMBER: 3105 

PACKING GROUP: II 

PRODUCT RQ (LBS): 

See below 

Section 15 - REGULATORY INFORMATION 

SARA HAZARD CLASSIFICATION 

Immediate (Acute) Health: yes 

Delayed (Chronic) Health: no 

Sudden Release of Pressure: no 

Reactive: yes 

Fire: yes 

SARA Title III, Section 302: 

This product does not contain any chemicals currently on the 

Extremely Hazardous Substance List, Section 302, SARA Title ;!II 

above the OSHA de minimis concentration. 

SARA Title III, Section 313: 

This product contains: 

Dimethyl phthalate 

131-11-3 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 13 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

G>Q> 
P.63 

MATERIAL SAFETY DATA SHEET 

Section 15 - REGULATORY INFORMATION 

Methyl ethyl ketone 

78-93-3 

which are listed on the Toxic Chemical List, Section 313, SA3A 

Title III. 

CERCLA RQ 

This product contains: 

Dimethyl phthalate 

131-11-3 5000 lbs. 

Methylethyl ketone peroxides 

1338-23-4 10 lbs. 

Methyl ethyl ketone 

78-93-3 5000 lbs. 

California Propostion 65: 

This product does not contain any chemicals currently listec on 

the California List of known Carcinogens. 

California Propostion 65: _ 

This product does not contain any chemicals currently listed on 

the California List of known Reproductive Toxins. 

Pennsylvania Right-to-Know 

Hazardous Substance List 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the Pennsylvania Hazardous Substance List. 

Pennsylvania Right-to-Know 

Environmental Hazardous Substance List 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the Pennsylvania Environmental Hazardous 

Substance List. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: U ot IJ 

ELF ATOCHEM NORTH AMERICA, INC. 

_U 
P.64 

MATERIAL SAFETY DATA SHEET 

Section 15 - REGULATORY INFORMATION 

Pennsylvania Right-to-Know 

Special Hazardous Substance List 

This product does not contain any chemicals currently on :he 

Pennsylvania Special Hazardous Substance List, above the CSHA 

de minimis concentration. 

Massachusetts Right-to-Know 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 t 

which are listed on the Massachusetts Hazardous Substance LLst 

New Jersey Right-to-Know 

This product contains: 

Dimethyl phthalate 

131-11-3 

Methylethyl ketone peroxides 

1338-23-4 

Hexylene glycol 

107-41-5 

Hydrogen peroxide 

7722-84-1 

Methyl ethyl ketone 

78-93-3 

which are listed on the New Jersey Hazardous Substance Lis-.: 

Section 16 - OTHER 

Legend 

N/A - Not Applicable 

NE - Not Established 

NJTSN - New Jersey Trade Secret Number 

Lupersol, Luperco, Luperox, Peroximon and Retilox are register.:-;. 

trademarks of Elf Atochem, North America, Inc. 

MSDS CODE: 129000 Date: C1/06/97 

PRODUCT: LUPERSOL DDM-9 Page: 12 of 13 

ELF ATOCHEM NORTH AMERICA, INC. 

G% 
P.65 

MATERIAL SAFETY DATA SHEET 

Section 16 - OTHER | 

Issued: 01/06/97 Rev.- 0 

Supersedes: 07/12/95 

Elf Atochem North America, Inc. believes that the information and 

recommendations contained herein (including data and statements) 

are accurate as of the date thereof. NO WARRANTY OF FITNESS TOX ANY 

PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, 

EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. 

The information provided herein relates to the specific produc-: 

designated and may no be valid where such product is used in 

combination with any other materials or in any process. Further, since 

the conditions and methods of use of the product and of the ir.formation 

referred to herein are beyond the cbntrol of Elf Atochem, Elf Atochem 

expressly disclaims any and all liability as to any results obtained 

or arising from any use of the product or reliance on such information. 

MSDS CODE: 129000 Date: 01/06/97 

PRODUCT: LUPERSOL DDM-9 Page: li of 13 

ELF ATOCHEM NORTH AMERICA, INC. 
P.66 

f -Wisconsin SOURCE DESCRIPTION - SUPPLEMENTAL 

new of Namral Resources AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-1Q2A 11-93 Infonnation attached? _ (y/n) 

if this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

; you complete and submit this form. It is not the Department's intention to use any personally identifiable information a-cia 

"inn for any other purpose. 

List all significant existing or proposed air pollution units, operations, and activities at the facility. A short narrative of the 

inventory of air pollution emissions unit (e.g., boiler, printing line, etc.) followed by equipment specifications will suffice. If 

the facility consists of several individual emission units, present this information in an outline format. (See instruction 

booklet for an example Unit description.) 'Qr\ o _ c. r^.,, 

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P.67 

of Wisconsin STACK IDENTIFICATION 

irancnt of Natural Resources AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-103 11-93 Information attached? _ (y/n) 

• INSTRUCTIONS ON REVERSE SIDE 

Facility name: 2. E^^^^ti^ifiapn^l ^ 3. S^^iidenMc_Hon number. 

ExhaustirigUnitfs),-use-Unit idenft^^ 109 

30-104 4530-106 4530-107 4530-108 4530-109 

Identify this stack on the plot plan required on Form 4530-101 

Jjf This stack has an acmal exhaust point. • This stack serves to identify fugitive emissions, 

this stack has-an acmal exhanst;i»inU then-proyide^ihe;^^ 

Discharge hei^tTa^ve'sra-^lcvel: /Hg-" (feet) 

Inside dimensions at outlet (check one and^complete): 

D Circular (feet) JS_frectangular /Q. / length (feet) QL. width (feet) 

"^a^silwirate ; 

Nonla^^P^kCFM ) Maximum 2SLU3. (ACFM) 

Exni£to.gasitemperstture^(normal):; ~ __ (°F) 

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Is tfas fl^ equippea*.with<a ra^at_OT^ flPYes DNo 

exh'ausfgases from the stack?"" \ "~ f 0 \ ~ ^ fl ^" ' V^X " \ZFKTT „^ Fc + i°s. 

'* Complete the appropriate Air Permit Application Fonns(s) 4530-104, 106, 107, 108 or 109 for each Unit ***** 

exhausting through this stack. 
P.68 

: of Wisconsin 

artment of Natural Resources 

; INSTRUCTIONS ON REVERSE SIDE 

PAINTING AND COATING OPERATIONS 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-108

 :r

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Facility name: Q FM^LA« Mh.mo . 2. Facil^ddm-ific^tion-nu-nber. 

Stackvidentificationnumben 4. I?roce^tom|>a: P03 

u Unit description: 

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Oven curing (complete if applicable): 

Number of ovens 

Total Maximum Energy input to each oven: 

Specify oven fuels. 

). Describe all of the coatings' and solvents' composition (as applied] 

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!st the thinning solvents used with the coatings identified above. 

lean-up solvents ^/e^ , / O.W16L ___U__ SFO 6,511 

lean-up solvents purtpotr c 

ther (specify) THi>->uf'x-

_*** po r jjjjj emissions unit identify the method of compliance demonstration by completing Form 4530-118, ***** 

DESCRIPTION OF METHODS USED FOR DETERMINING COMPLIANCE. Attach Form 4530-118 

and its attachments) to this form. This is not a requirement of non-Pan 70 sources. 

'*** Please complete the Air Pollution Control Pennit Applicatioa Farms 4530-126 and 4530-128 for this Unit ***** 

ating categories (ct eg. • column b. above) should be entered as follows: 1 - for air dried coatings; 2 - for clear coatings; 3 

cured coatings; 4 - for extreme performance coatings; 5 - for other (specify) . 

C0l0 
P.69 

of Wisconsin 

tment of Natural Resources 

INSTRUCTIONS ON REVERSE SIDE 

EMISSION UNTT HAZARDOUS AIR POLLUTANT SUMMARY 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Fonn 4530-126 11-93 Information attached? _ (y/n) 

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Complete the following summary of hazardous air emissions from this unit Attach sample calculations and emission 

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61 
9 7 —Section 1 — 

Product Identification 

P 

mi 

Material Safety Data Sheet 

The Sherwin-Williams Co. 

101 Prospect Ave. N.W. 

Cleveland, OH 441 15 

Emergency telephone number 

Inlormation telephone number 

Dale of preparation 

(216) 566-2917 

(216) 566-2902 

September I. 1997 

OI9v7. Ihe Sheiwln-Wililams Co. 

POLANE® ^Redtmem^ 

— Section 2 — 

C AS No. Hazardous Ingredient 

i (percent by weigM) 

5 

108-88-3 * Toluene. 

100-41-4 " Ethylbenzene 

1330-20-7 * Xylene. 

78-93-3 * Methyl Ethyl Ketone. 

108-10-1 * Meihyl Isobutyl Ketone. 

110-43-0 Meihyl n-Amyl Kelone. 

108-94-1 Cyclohexanone 

108-21-4 Isopropyl Acetate. 

, 123-86-4 n-Butyl Acetate. 

ACGIH OSHA Vapor 

TLV PEL Units Pressure 

<STEL> <STEL> (mm Hg) 

50 J!? ^ PPM (Skin) 22.0 

100 100 

<125> <125>

 PP M 7 '1 

1 0 0

 '00 pp M s g 

<150> <150>

 KK M 6 9 

200 200 DD , . ,. _ 

<300> <300>

 PP M 70 0 

50 50 

<?5> <75>

 PP M 16 0 

50 100 PPM 2.1 

25 25 PPM (Skin) 2.0 

250 250 

<310> <310>

 PP M 47 5 

150 150 „„, . .. . 

<200> <200>

 PP M 10 ° 

Weight per Gallon (lbs.) 

.^ VOC (Volatile Organic Compounds) - lbs./gal. 

Ir\ 5 Photochemically Reactive 

4 ^ Flash Point (*F) 

"" OOL Storage Category 

Flammabilily Classilicalion (Flammable - Combustible) 

| HMIS (NFPA) Rating (health - llammability - reactivity) 

MAK 

R6K30 

100 

6.76 

6.76 

No 

100 

2 

Combustible 

2 2 0 

Cyclohexanone 

R6K32 

100 

7.66 

7.86 

No 

1 11 

2 

Combustible 

3 2 0 

K69 Thinner 

R7K69 

530-2138 

530-2146 

530-2641 

15 

9 

52 

24 

7.04 

7.03 

Yes 

35 

IB 

Flammable 

2 3 0 

KB4 Thinner 

R7K84 

S30-2tS3 

530-2161 

530-2658 

20 

36 

45 

7.25 

7.25 

No 

35 

IB 

Flammable 

2 3 0 

K94 Thinner 

R7K94 

530-2179 

530-2187 

530-2666 

20 

25 

27 

28 

7.09 

7.09 

No 

21 

IB 

Flammable 

2 3 0 

Retarder 

R7K216 

4 

71 

24 

7.68 

7.68 

No 

92 

I C 

Flammable 

3 3 0 

SOL-POL 

W&Sara m 

12 

1 

7 

59 

6 

15 

'\f$jffi0i\W. 

i)t_-«~i--'•• ' " 

No 

30 

1B 

Flammable 

3 3 0 

Reducer 

R7 K B50 

21 

35 

22 

22 

6.96 

6.95 

No 

30 

IB 

Flammable 

2 3 0 

P 

t 

p 

c 

t 

H 

T 

8 

r 

W 

f 

I 

0 

H 

I 

Ingredient subject IO the reporting requirements ol Ihe Superlund Amendmenis and Reauthorization Act (SARA) Section 313. 40 CFR 372.65 C 

->-->--> MSDS Text Page Follows •*•*•> 
POLANE® Reducers SOL-POL 

Section 3 — Physical Data 

PRODUCT WEIGHT 

SPECIFTC CRAVITY 

3 0 IL-.VC RANCE 

•VLATtLC VOLUME 

Sec TABLE 

0.81-0.9. 

11J-330 •!• 

100 > 

f\'AP0«.4T/0« PJX rVAPOR DENSITY 

MELT IHC POI.VT 

SOLUBILITY TN HATES 

Slowe r Chan Ether 

Heavie r Chan Air 

N A. 

N A. 

Section 4 — Fire And Explosion Hazard Data 

F-..<--0M8_LITY CLASSIFICATION FLASH POINT See TABLE LEL 1 .0 UEL 10. 0 

Se e TABLE 

EXTINGUISHING MEDIA 

Carbon Oioxlde , Dry Ch—mlcal. Fo—m 

UNUSUAL FIRE AMD EXPLOSION HAZARDS 

Keep containers tightly closed. Isolate from heat, electrical equipment. spark9. and open 

(lame. Closed containers nay explode when exposed to extreme heat. Application to hot 

surfaces requires special precautions. During emergency conditions overexposure to 

decomposition products may cause a health hazard. Symptoms may not be immediately apparent. 

Obtain medical attention. 

SPECIAL FIRE FIGHTING PROCEDURES 

Full protective equipment Including self-contained breathing apparatus should b e used. 

w ate r spray may be Ineffective. If water ls used, fog noszles are preferable. Water may be 

used to cool closed containers to prevent pressure build-up and possible autoignition or 

explosion when exposed to extreme heat. 

Section 5 — Health Hazard Data 

ROUTES OF EXPOSURE 

Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. 

To minimize exposure, follow recommendations for proper use. ventilation, and personal 

protective equipment. 

ACUT E Health Hazards 

EFFECTS OF OVEREXPOSURE 

Irritation of eyes.: sxin and respiratory system. May cause nervous system depression. 

Extreme overexposure may result in unconsciousness and possibly death. 

SICNS AND SYMPTOMS OF OVEREXPOSURE 

Headache, dizziness, nausea, and loss of coordination are indications ot excessive exposure 

to vapors or spray mists. 

Redness ahd itching or burnlno sensation may Indicate eye or excessive skin exposure. 

KEOrCAL CONDITIONS AGGRAVATED BY EXPOSURE 

None generally recognized. 

EMERGENCY AND FIRST AID PROCEDURES 

If INHALED: If affected, remove from exposure. Restore breathing. 

If on SKIN: Hash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

Flush eyes with large amounts of water for 15 minutes. 

Never give anything by mouth to an unconscious person. 

Keep warm and quiet. 

Give several glasses of water. Seek medical attention. 

Cet medical attention. 

DO NOT INDUCE 

If ln EYES: 

If SWALLOWED 

VOMITING. 

CHRONI C Health Hazards 

No ingredient ln these products is an IARC. NTP or OSHA listed carcinogen. 

Reports have associated repeated and prolonged overexpcsure to solvents with permanent brain 

and nervous system damage. 

Prolonged overexposure to solvent ingredients ln the following products may cause adverse 

effects to organ systems: 

u r i na ry 

urinary, 

ur Inary. 

urinary. 

• Cyclohexinone t Methyl Amy. Ketone 

• KS9 Thinner 

' R7KS50 i Retarder R7K21C 

• R7XB29. KS4 Thinner _ K9I 

1iver. 

liver, 

liver, 

liver. 

cardiovascular, reproductive 

blood forming, reproductive 

blocd forming, cardinvascular. reproductive 

Section 6 — Reactivity Data 

STABILITY - Stabl e 

CONDITIONS TO AVOID 

None known. 

-.voo.fPATia.L/Ty 

None known. 

HAZARDOUS DECOMPOSITION PRODUCTS 

By tire : Carbon Dioxide . Carbon J 

HAZARDOUS POLYMER IZATICN - Wil! Not 

lon.j t i y. 

Occ-ir 

Section 7 — Spill Or Leak Procedures 

STEPS TO BE TTUC-M IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove al l source s of ignition . Ventilat e and remove wit h In-srt absorbent 

WASTE DISPOSAL METHOD 

Waste from thes e products may be hazardous as define d under the Resourc e Conservatio n ind 

Recovery Act IRCRA) «0 CFR .6 1 Waste must be teste d for ignitabilit y t o determin e the 

applicabl e EPA hazardous wast*: numbers. Waste from products containin g Methyl Ethy l Ketone m.i 

als o requir e testin g for extractabi1ity . 

Incinerat e in approved facility . Do no t Incinerat e close d container . Dispos e of in 

accordanc e wit h Federal . State , and Local regulation s regardin g pollution . 

Section 8 — Protection Information 

PRECAUTIONS TO BE TAXES IN USE 

U s e only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact 

with skin and eyes. Wash hands after using. 

VEfTTlLATION 

Local exhaust preferable. General exhaust acceptable if the exposure to materials in 

Section XI is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94. 

1910.107. 1910.108. 

RESPIRATORY PROTECTION 

If personal exposure cannot be controlled below applicable limits by ventilation, wear 

a properly (itted organic vapcr/particulate respirator approved by NIOSH/MSHA (or protection 

against materials in Section II. 

PROTECTIVE GLOVES 

Wear gloves which are recoircnended by glove supplier for protection against materials in 

Section XI. 

iTE PROTECTION 

Wear safety spectacles with unperforated sideshields. 

Section 9 — Precautions 

COL STORAGE CATEGORY - See TABLE 

PRECAUTIONS TO BE TAKEN IN HAKDLING AND STORING 

Keep away froa heat, sparks, and open flame. 

During use and until all vapors are gone : Keep area ventilated - Dc not smoke • 

Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and 

appliances, and any other sources of ignition. 

Consult NFPA Code. Man approved Bonding and Grounding procedures. 

Keep container closed when not in use . • Transfer only to approved containers with complete 

and appropriate labeling. Do r.ot take Internally. Keep out of the reach of children. 

OTHER PRECAUTIONS 

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful 

or fatal. 

Section 10 — Other Regulatory Information 

CALIFORNIA PROPOSITION S$ 

WARNING: K*9 Thinner. KS4 Thinner. K94 Thinner and R7KB-9 contain chemicals known to the 

State of California to cause cancer and birth defects or other reproductive harm. 

TSCA CERTIFICATION 

All chemicals in these products are listed, or are exempt from listing, on the TSCA 

Inventory. 

The above Information pertains to these products as currently formulated, and is based on 

the infonnation available at this time. Addition of additives or othe: coatings materials to 

.nese products may substantially alter the composition and hazards of the products. Since 

conditions of use are outside our control, we make no warranties, express or implied, and asr.u.-, 

r.c liability in connection with .my use of this information. 
JUN-10-98 WED 09:27 AM ICAFE 

Jun-lO-98 08:00 

FAX NO. 14147741560 

TH- $arf yyi,)J^„, FROM: *C^ _ 

CO: 

DEPT 

FAX# J___m___zL 

rr-ft,_t„.gMTQ xjj. jU^ryx^JX*. 

I ICAFE j 

. PHONE: (414) 774-0910 

FAX/ (414)774*1560 

P. 01 

P.O l 

P.73 

*jiU. TD10-4R 

DIVISION* High Volume Low Pressure - HVLP 

HIGH VOLUME LOW PRESSURE SPRAYING 

HVLP (high volume low pressure) spraying has quickly 

become the biggest trend in finishing today. HVLP uses 

approximately the same volume of air as a conventional 

spray gun, but at lower pressures to atomize the fluid. 

Reducing air pressure at the nozzle reduces the velocity 

of the air stream and atomized fluid. This in tum has a 

positive effect by reducing the "bounce back" of material 

from the surface being coated. The resulting spray is high 

in transfer efficiency. 

REASON FOR HVLP 

World-wide concern over air quality and hazardous emissions has generated an enormous interest in HVLP spray 

equipment. Assuming a leading role in mandating more 

environmentally sound painting operations, the California 

South Coast Air Quality Management District (SCAQMD) 

has specified HVLP spray guns as one of only two types 

of spray equipment approved for use within its district 

(the Los Angeles basin). 

Similar legislation has been adopted, or is now under consideration, in many other industrialized areas throughout 

the United Slates. As these areas introduce their own rules, 

the KPA will require then; to be as strict, or stricter, as the 

California legislation. High transfer efficient equipment 

may ultimately be a requirement of operating in the finishing industry. 

Recognizing that the essential characteristic of HVLP is 

low air velocity created by low atomizing pressures, the 

SCAQMD defines HVLP as any device that atomizes paint 

with an operating pressure at the air nozzle between 0.1 

and 10 PSIG. 

Overspray Is a major problem for many companies ln the 

finishing industry. Virtually all spray finishing operations 

can be adversely affected by overspray and this can result 

in costly maintenance and downtime. 

Ba Milne Transf»r Efficiency 

Of Spray Coating Methods 

HVLP 

Airless Electrostatic 

Air-Assisted Airless Electrostatic 

Air Electrostatic 

Air-Assisted Airless 

Airless Spray 

Air Spray 

65 V. 

SCAQMD 

Minimum 

Note: AU figures ars considered 'Baseline .Actual T.E. varies due lo an 

unlimited number of variable. 

HVLP spraying can be tsvo to three times as efficient 

as conventional air spray which can cut material costs 

and wast., 

efficient. This meonslnat over two gallons of paint are 

wasted, due to overspray, for every three gallons that are 

sprayed. With HVLP spraying at an efficiency rate of 05% 

to 85%, as little as one pint of paint would be wasted for 

every gallon sprayed. 

Another major problem for finishers is waste disposal. 

By using an HVLP system, with its high transfer efficiency, 

waste disposal costs are lowered. 

Productivity will likely increase with an HVLP system 

because fewer passes are needed to build up the same 

film thickness since more material is applied with each 

pass due to HVLP's high transfer efficiency. 

HVLP vs. ELECTROSTATIC 

When comparing HVLP and electrostatic spraying you must 

consider the part that ls to be sprayed. Unlike electrostatic, 

HVLP works equally as well with nonconductive parts like 

plastics and wood as it does with metal substrates. 

Operators of painting equipment are also directly affected 

by overspray. Tlte fumes emitted into the nlrean bo hazardous lo their health. Visibility ln the spraying area is also 

reduced by fumes and this contributes to mistakes and 

low productivity. 

TRANSFER EFFICIENCY 

A higher transfer efficiency improves the quality of tiie 

work place by reducing unnecessary pollution and It 

improves the quality of products by providing an 

excellent finish. 

^IIICAP - CSG 

. a* rx rx 

HVIP ELECTROSTATIC (Air) 

ADVANTAGES 

• High Transfer Efficiency 

• Low Cost (Air Restricted) 

• Easy To Operate 

• Sprays Into Recesses 

• More Rugged 

UMITATIONS 

• Lower Producllon Speed 

• Difficult To Atomize Seme Coalings 

« Hign Cost (Turbine) 

• High Energy Ute (Air Restricted) 

UMITATIONS 

• Parts Must 80 Conouctive 

• High Cost 

« High Vol.ege Stigma 

• Faraday Cogo Elfcct 

ADVANTAGES 

» High Tfans'e.* Efficiency 

• High Production Speeds 

• Excellent FinlsH 

• "Wrap* Around Coverage 
P.74 

Binks MODEL 2001 & 2001V H.T.E., LPLV SPRAY GUNS 

The following five (5) items are needed to convert your model 2001 or 2001V Spray Gun to an H.T.E.. LPLV Gun: 

GUN HEAD 

(D 

Standard 65 Series Fluid 

Needle, e.g., 65, 265, 365, 

465, 565 

20-4445 "O" Ring (It is recommended that this 

" 0" Ring be used in place of the 54-918 Gasket) 

54-3359 

FLUID 

STRAINER 

ASSEMBLY 

INSTALLATION INSTRUCTIONS 

INSTALLATION INSTRUCTIONS 

1. Remove the conventional air atomizing setup, namely 

the air nozzle, fluid nozzle, and O-Ring. 

2. Insert the 20-4445 O-Ring. DO NOT SUBSTITUTE. 

3. Attach the 66A Fluid Nozzle utilizing a 5-476 Fluid 

Nozzle Wrench. DO NOT OVERTIGHTEN. 

4. Insert the fluid tip assembly into the 66 A A Air Nozzle. 

As an assembly, thread the air nozzle-fluid tip assembly 

combination onto the gun. 

OPERATING INSTRUCTIONS 

1. Since the fluid tip assembly has a relatively small 

orifice, the fluid material must be free of large particles. Should particles be present it will be necessary to 

strain the material. 

2. Set the fluid pressure at 45-80 PSI. Warning: Do 

not exceed 100 PSI. 

3. Set the atomizing air pressure at 5-I0 PSI. 

4. The gun is now ready for spraying. 

5. Spray a sample product. If the film is too thick, decrease the fluid pressure or change to a smaller Huid tip 

assembly. 

6. If the degree of atomization is insufficient, it may be 

necessary to increase the air pressure. DO NOT exceed 

30 PSI. Increased air pressure will cause a loss of 

transfer efficiency. Always use the lowest possible Huid 

and air pressures. 

FLUID TIP -

A \(\- C. A p . -

Patent Pending 

~4-Z n 
P.75 

11:02 ®60> 274 5313 PBE JOBBERS. .^, -j-j-*- o ©002/020 

MATERIAL SAFETY OATA SHEET • 

EMERGENCY 24 HR. PHONE.- CHEMTREC - 1-300-424-9 3 0 0 

NEPA 

^ A Health 2 

PRODUCT, EKCEL WASH THINNER ,..-,&^*'l\( & Fire 4 

.?*>•••

 ! * Reactivity 0 

•^SiM^^ 0 1 ^ Special -

- - - •••••.••••••••* EMIS, PP I H 

55cH6M I , ..tJ&gLI-_Rl,,tyFoRMA-groN' 

PACKAGING SERVICE COMPANY, INC. 

P.O . Bo x 87 5 

PEARLAJMD, TEXAS 7758 1 

Telephon e (713 ) 48S-14S 7 

REVISED 10/94 

CWLT01 

SE6M6M II , l_A2Afiflolte IMriftEDlBna ; ICKSfrlTY INFORMATION " • 

.AZARDOUS COMPON_2NTS-(CAS Number) OSHA 'P'EL" ACGIH TLV OTHER-'" 

.CETONE (67-64-1)- OSHA TWA 1000 ppm 

ACGIH TWA 750 ppm, STEL IOOO ppa 

CETHYL ALCOHOL (67-56-1) OSHA TWA 200 ppm, 

ACGIH 200 ppm, 

TLV SJON STEL 250 ppm 

'ETROLEUM DISTILLATE (64742-89-8) RECOMMENDED TWA lOOppm 

uUENE (108-88-3) OSHA TWA 200ppm*, 

ACGIH TWA lOOppm, STEL 150ppm 

•CEILING 300ppm ACCEPTABLE MAXIMUM PEAK ABOVE THE ACCEPTANCE 

CEILING CONCENTRATION FOR AN 8 HOURSHIFT =* SOOpprn FOR 10 

MINUTES. 

KCM6M III, J?HY5I(-ALyeHEt-I(-AL <mftAcTEais-JlCg 

Oiiajag Point, ND Melting Pomt , NA 

pecific Gravity (H20=l), 0.79 

apor Press-ore, ND Vapor Density (Air=l), >i.o 

vapor ation Rate (BuAcr=i) , >i 

olubility in Water, PARTIALLY 

ppearance and Odor, CLEAR LIQUID, ALCOHOL TO PETROLEUM ODOR. < ,: 

gGTlON IV, FIRE AND EXPLOSION HAZARD DAT A — 

iasn Point (Metnoct) , BSLoW 50 FT ~ ~"~*~ 

Lammable Limits; Lower, 1 Upper, 36 

ctinguashing Media, DRZ POWDER, CARBON DIOXIDE (C02), "ALCOHOL" FOAM, 

3E WATER TO COOL CONTAINERS. DANGER I ALCOHOL MAY BURN WITH AN 

^VISIBLE FLAME. 

yoc LB P'^ CA.-. 6 -S9-] 
P.76 

01/06/98 11:02 Q60 8 274 5313 PBE JOBBERS 1003/02 0 

Mi' L SAFETY DATA SHEET 

EMERGENCY 2 4 h iONE - CHEMTREC - 1-800-424-920 0 

EXCEL WASH THINNER " 

Slc.__L.Lbin iv , glftfi AN6 !UL»LQsl6tt HA&kSifl "CEASA. corittmUEfl 

*£?*:?.?;**. *'ir e Figntin g Procedures, APPROACH FIRE FROM UPWiHD slDE. AVOID 

3REATHING.SMOKE, FUMES, MIST, OR VAPORS ON THE DOWNWIND SIDE . 

.JSfliSS 112 ^

 WEA R

 PROTECTIVE CLOTHING, AND SELF CONTAINED BREATHING 

Tw ^ s

. ^ a l Fir e an d Explosio n Hazards, CONTAINERS MAY RUPTURE FROM 

;^T^^ i PRESSURE I F CONFINED TO FIRE AREA. COOL WITH .WATER. GET NON 

ESSENTIAL PEOPLE OUT OF THE AREAn " 

ggl'IOM V."ft__Ac_3IVIT¥ TO6AMA?_reg" 

"STASILITV! — 

•roduct is; STABLE 

. '. , INCOMPATAB ILITY 

•Sterials to avoid, OXIDIZERS OR OXIDIZING MATERIALS. 

£f5E_,ous Decomposition or Byproducts, FROM FIRE; SMOKE, CARBON 

IOXIDE, CARBON MONOXIDE. 

azardous.Polymerization, WILL NOT OCCUR. 

2CTI0N VI, HEALTH HAZARD "DATA 

loOTES Of £MTR!_ 

nhalation ? POSSIBLE (IRRITANT/NARCOTIC) 

In/Eyes ? POSSIBLE (IRRITANT) 

igestion ? UNLIKELY (IRRITANT/NaRCOTIC) 

HEALTH HA2ARDS 

sute , INHALATION OF VAPORS MAY BE NARCOTIC OR ANESTHETIC. INGESTION OF 

CQUID WILL CAUSE GASTROINTESTINAL DISTRESS, IRRITATION, AND POSSIBLY 

ttTSEA. LIQUID OR VAPORS MAY BE IRRITATING TO SKIN AITD EYES. 

ironic . KIDNEY AND LIVER DAMAGE POSSIBLE, CONTAINS TOLUENE. 

:SUAL DISTURBANCES, METABOLIC ACIDOSIS FROM INGESTION OF METHANOL. 

CARCINOGEN! CITY 

•ste d in ; NTP? NO IARC Monographs ? NO OSHA Regulated ? NO 

g n s an d Symptoms o f Exposure , SYMPTOMS OF OVEREXPOSURE, IN ORDER: 

ADACHE, FATIGUE, NAUSEA, VISUAL IMPAIRMENT, ACIDOSIS, CONVULSIONS, 

RCULATORY COLLAPSE, RESPIRATORY FAILURE, DEATH. INGESTION MAY CAUSE--

INDNESS'-OR BE FATAL. 

dica l Condition s Generall y Aggravate d b y Expc_.ure, BREATHING 

SORDERS. DERMATITIS. 

Pag e 2 
P.77 

01/015/98 11:03 ©608 274 531'-. PBE JOBBERS ©004/020 

MATERIAL SAFETY DATA SHEET 

EMERGENCY 24 HR. PHON - CH2_MTREC - 1-8QO-424-93 00 

EKCTL WASH THINNER 

SECTION VI, HEALTH J-AZARD DATA, CONTINUED ~ 

•jmergency ana Fxssx. Aid Srbceaures, IWHALAKotf: A£_4oVS VICTIM To PRESH" 

kIR AND, IF NEEDED, IMMEDIATELY BEGIN ARTIFICIAL RESPIRATION. GIVE 

JXYGEN IF BREATHING IS LABORED. GET EMERGENCY. MEDICAL HELP. CONTACT 

'HYSICIAN IMMEDIATELY. ; 

•LUSH EYES AND SKIN WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS 

lEVELOP AND PERSIST.. 

NGESTION: INDUCE VOMITING IF VICTIM IS CONSCIOUS BY • GIVING WATER THEN 

TICK FINGERS DOWN THROAT. GET MEDICAL. ATTENTION. NEVER GIVE 

NCONSCIOUS PERSON ANYTHING BY MOUTH. 

IfcfllcM VII, ^CAU-I-IOH.3 Foft .SATE HANDLING AMfi Ust 

taps to £>e taxen in case material is released or spi-Liea, Sfc_Ai_il_ " 

PILLS, PICK UP WITH ABSORBENT MEDIA. STORE AS HAZARDOUS WASTE. 

ARGE SPILLS, CONTAIN WITH DIKES, PICK UP WITH VACUUM TRUCK. HANDLE AS 

AZARDOUS WASTE- NOTIFY PROPER LOCAL, STATE, AND FEDERAL AGENCIES. 

aste disposal method, EPA APPROVED EAZARDOUS WASTE DISPOSAL SITE. 

OLLQW APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. 

recautions to be taXen in handling and storage, STORE IN A COOL PLACE 

*AY FROM IGNITION SOURCES. 

fORE AWAY FROM OXIDIZERS OR MATERIALS BEARING A YELLOW "DOT" LABEL. 

rher precautions, CLEAN UP LEAKS IMMEDIATELY TO PREVENT SOIL OR WATER 

3NTAMINATION. 

iCTION VlJX, CONTROL MEASURES '''... 

jspirator y protection , (IF C0NcENTaA*ridN''R£AcHES,,,dR £XCi___Ds TLV), 

IOSH APPROVED ORGANIC VAPOR MASK REQUIRED. 

sntilation ; Loca l Exhaust, RECOMMENDED Special , 

Mechanical , RECOMMENDED Other , 

•otectiv e Gloves, CHEMICAL RESISTANT GAUNTLET TYPE GLOVES. 

•e Protection , CHEMICAL GOGGLES OR FULL FACE SHIELD. 

h e r Protectiv e Equipment, "BOOTS, APRONS, DRENCH SHOWERS, EYE WASH.*'AS 

:£DED FOR-PROTECTION AGAINST SPILLS AND/OR SPLASHES. 

r k Hygieni c Practices , AVOID CONTACT WITH SKIN, EYES, AND CLOTHING. 

TER HANDLING THIS PRODUCT, WASH HANDS BEFORE EATING, DRINKING, OR 

OKING. IF CONTACT OCCURS, REMOVE CONTAMINATED CLOTHING. IF NEEDED, 

KE FIRST AID ACTION SHOWN IN SECTION VI. 

UNDER CONTAMINATED CLOTHING BEFORE REUSE. 

Page 3 
P.78 

0.1/06/98 11:04 ©608.7 4 53 PBE JOBBERS @005/02<)_ 

t 

t 

• MATERX-vL SAFETY DA£A SHEET 

EMERGENCY 2 4 BR. PHONE - CHEMTREC - 1-800-424-930 0 

EXCEL WASH THINNER 

rTIOM IX, TRANsPdMA'TIO-; mgoftriAJIoH 

1

 Prope r Shippin g Name, Hazard Class. , UN/NA Number, RQ (i x Needed)" 

PAINT RELATE_."MATERIAL, 3 (FLAMMABLE LIQUID), UN 1263 , F<TII, 

RQ (TOLUENE, ACETONE, AND METHANOL) 

TION X, OTHER DATA 

. Hazards," l-Acute ISJS. 2-^hronic* V>-^ •-t~E'i-iTTrm-*-.r-.*i •'

 T-r-y 2E3 

4-Sudden Release of Pressure NO 5-Reactive NC , 

,CLA RQ 8,333 (TOLUENE) •" 

RQ 20,000 (ACETONE) 

RQ 27,777 (METHANOL) 

ardous Waste Number D001 IGNITABLE 

Title III YES 

Threshold Planning Quantity, NONE • 

Reportable Quantity, NONE 

Section 313, Toxic Materials: 

Chemical Name CAS Number 

ACETONE 67<_.$4-_l 

METHANOL 67_56_-l 

TOLUENE 108-88-3 

-

Weight" 

25-30% 

15-20% 

<15% 

an Air Act YES, SECT, ill 

an Water Act YES; SECT. 304, 307, 311 

CC SUBSTANCES CONTROL ACT (TSCA) , 40 CFR 710 

rces -ofthe raw materials used in this mixture assure that all 

ileal ingredients present are in compliance with Sect. .8(b) 

neal Substance Inventory, or are otherwise in compliance with 

i. 

lot applicable : ND-Data not available 

:ancer Suspect Agent OX-Oxidizer COR-Corxosive 

•-Calculated EST-Estimated 

•-Short Time Exposure Limit TLV-Threshold Limit Value 

•Permissable Exposure Limit TWA-Time Weighted Average, 8 hours 

', PPI-Hazardous Material Identification System, Personal Protection 

Index 

data presented is true and correct to the best of our knowledge and 

ef, however, neither seller nor preparer makes any warranties, . : -

: 

ess or-implied, concerning the information presented. The user'is 

ibned- to perform his own hazard evaluation and to rely upon his own 

ruinations. CWLT01 . 

Form essentially the same as OSHA Form 174 Dated September 19as 

Page 4 

"4Cp 
P.79 

3/6/98 PAGE 1/4 RightFAX 

y < -

527-4370 

MATERIAL SAFETY DATA SHEET 

.CTURER'S NAME 

. SHERWIN-WILLIAMS COMPANY 

. Prospec t Avenue N.W. 

.veland , OH 44115 

)F PREPARATION 

-MAR-98 

EMERGENCY TELEPHONE NO, 

(216) 566-2917 

INFORMATION TELEPHONE NO. 

(216) 566-2902 •- £d<M<?£- S"-"-,'L 

Section I — PRODUCT IDENTIFICATION 

:T NUMBER HMIS CODES 

Health 

3W2327-4 370 Flammability 

Reactivity 

:T NAME 

_,ANE* T Plus Custom Polyurethane Enamel, BEN J. MOORE #879 WHITE 

:T CLASS 

se component for 2-package Polyurethane Coating 

Section II — 

31 ENT 

5 Nc. 

HAZARDOUS INGREDIENTS 

% by WT 

2 

3 

0 

W

1 

STEL 

2 

STEL i-i 7 

STEL 

6 

STEL 

44 

ACGIH 

TLV 

50 

100 

150 

50 

250 

310 

150 

200 

10 

OSHA 

PEL 

100 

150 

100 

150 

100 

250 

310 

150 

200 

15(5) 

UNITS 

PPM 

PPM 

PPM 

PPM 

PPM 

PPM 

PPM 

PPM 

PPM 

(Skin) 

(Skin) 

MG/M3 as Dust 

V.P. 

22.00 

5.90 

2.14 

47.50 

10.00 

+ * + 

ne. 

108-88-3 

330-20-7 

1 n-Amyl Ketone, 

110-43-0 

opyl Acetate. 

108-21-4 

yl Acetate. 

123-86-4 

um Carbonate. 

471-34-1 

ium Dioxide. 

463-67-7 

*** Total Dust (Respirable Fraction) 

19 10 10(5) MG/M3 as Dust *** 

*** Total Dust (Respirable Fraction) 

Section III — PHYSICAL DATA 

ODUCT WEIGHT 

IFIC GRAVITY -

OILING POINT 

ATILE VOLUME 

Theoretical) 

- 14.28 lb./gal. EVAPORATION RATE — Slower than Ether 

-1.72 VAPOR DENSITY — Heavier than Air 

185-308 F MELTING POINT — N.A. 

37 % SOLUBILITY IN WATER -- N.A. 

2.67 lb. 320 gm. (less Federally Exempt Solvents) 

Section IV — FIRE AND EXPLOSION HAZARD DATA 

POINT LEL 

5 F TCC 1.0 

ABILITY CLASSIFICATION 

D LABEL — Flammable, Flash below 100. F 

UEL 

7 . 9 lOT Fn. C A u ~ l^.*i% 

l/O c L (ii '°* - G.AC-- Q..L1 

I txj Fo n ,y t\/±c.c &)*.c.F 
P.80 

w. w, ww rnu L i.1 1 lil6ill.l'n A 

F63W2327-4 370 page 2 

JGUISHING MEDIA 

irbon Dioxide, Dry Chemical, Foam 

JAL FIRE AND EXPLOSION HAZARDS 

_ep containers tightly closed. Isolate from heat, electrical 

jment, sparks, and open flame. Closed containers may explode when 

3ed to extreme heat. Application to hot .surfaces requires special 

autions. During emergency conditions overexposure to decomposition 

icts may cause a health hazard. Symptoms may not be immediately 

rent. Obtain medical attention. 

IAL FIRE FIGHTING PROCEDURES 

ill protective equipment including self-contained breathing apparatus 

Ld be used. Water spray may be ineffective. If water is used, fog 

Les are preferable. Water may be used to cool closed containers to 

mt pressure build-up and possible autoignition or explosion when 

.ed to extreme heat. 

Section V — HEALTH HAZARD DATA 

CS OF EXPOSURE 

.posure may be by INHALATION and/or SKIN or EYE contact, depending on 

Ltions of use. To minimize exposure, follow recommendations for proper 

ventilation, and personal protective equipment. 

a Health Hazards 

_TS OF OVEREXPOSURE 

rritation of eyes, skin and respiratory system. May cause nervous 

_m depression. Extreme overexposure may result in unconsciousness and 

Lbly death. 

3 AND SYMPTOMS OF OVEREXPOSURE 

_adache, dizziness, nausea, and loss of coordination are indications cf 

ssive exposure to vapors or spray mists. 

*dness and itching or burning sensation may indicate eye or excessive 

exposure. 

:AL CONDITIONS AGGRAVATED BY EXPOSURE 

iy cause allergic respiratory and/or skin reaction in susceptible 

)ns or sensitization. This effect may be delayed several hours after 

*ure. 

"ENCY AND FIRST AID PROCEDURES 

: INHALED: If any breathing problems occur during use,' LEAVE THE 

AREA and get fresh air. If problems remain or occur 

later, IMMEDIATELY get medical attention. 

: on SKIN: Wash affected area thoroughly with soap and water. 

Remove contaminated clothing and launder before re-use. 

: in EYES: Flush eyes with large amounts of water for 15 minutes. 

Get medical attention. 

: SWALLOWED: Get medical attention. 

IIC Health Hazards 

; ingredient in this product is an IARC, NTP or OSHA listed carcinogen, 

rclcnged overexposure to solvent ingredients in Section II may cause 

:se effects to the liver, urinary, blood forming, cardiovascular and 

•ductive systems. 

irsons sensitive to isocyanates will experience increased allergic 

:ion on repeated exposure. 

its exposed to titanium dioxide dust at 250 mg./m3 developed lung 

;r, however, such exposure levels are not attainable in the workplace. 

;pcrts have associated repeated and prolonged overexposure to solvents 

permanent brain and nervous system damage. 

mtinued cn page 3 

~y^& 
P.81 

W/W / WW I-_-_\_t__ U / 1 11 J. fill tl" t\I\ 

F63W2327-4370 page 3 

Section VI — REACTIVITY DATA 

3ILITY — Stable 

DITIONS TO AVOID 

>Ione known. 

3MPATIBILITY . 

\

7

one known. 

\RDOUS DECOMPOSITION PRODUCTS 

3y fire: Carbon Dioxide, Carbon Monoxide 

\RDOUS POLYMERIZATION 

'Jill not occur 

Section VII — SPILL OR LEAK PROCEDURES 

?S TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

Remove all sources of ignition. Ventilate and remove with inert 

*>rbent. 

CE DISPOSAL METHOD 

'Jaste from this product may be hazardous as defined under the Resource 

servation and Recovery Act (RCRA) 40 CFR 261. 

•Jaste must be tested for ignitability to determine the applicable EPA 

ardous waste numbers. 

[ncinerate in approved facility. Do not incinerate closed container. 

pose of in accordance with Federal, State, and Local regulations 

arding pollution. 

Section VIII — PROTECTION INFORMATION 

:AUTIONS TO BE TAKEN IN USE 

•JO PERSON SHOULD USE THIS PRODUCT, OR BE IN THE AREA WHERE IT IS BEING 

}, IF THEY HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF 

{ EVER HAD A REACTION TO ISOCYANATES. 

Jse only with adequate ventilation. Avoid breathing vapor and spray 

:. Avoid contact with skin and eyes. Wash hands after using. 

Phis coating may contain materials classified as nuisance particulates 

sted "as Dust" in Section II) which may be present at hazardous levels 

/ during sanding or abrading of the dried film. If no specific dusts 

listed in Section II, the. applicable limits for nuisance dusts are 

[H TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL 

ng./m3 (total dust), 5 mg./m3 (respirable fraction). 

PILATION 

jocal exhaust preferable. General exhaust acceptable if the exposure tc 

srials in Section II is maintained below applicable exposure limits, 

sr to OSHA Standards 1910.94, 1910.107, 1910.108. 

PIRATORY PROTECTION 

'Jhere overspray is present, a positive pressure air supplied respirator 

L9C NIOSH/MSHA approved) should be worn. If unavailable, a properly 

:ed organic vapor/particulate respirator approved by NIOSH/MSHA for 

zection against materials in Section II may be effective. Follov; 

_>irator manufacturer's directions for use. Wear the respirator for the 

Le time of spraying and until all vapors and mists are gone. NO PERSONS 

JLD BE ALLOWED IN THE AREA WHERE THIS PRODUCT IS BEING USED UNLESS 

CPPED WITH THE SAME RESPIRATOR PROTECTION RECOMMENDED FOR THE PAINTERS. 

•Jhen sanding or abrading the dried film, wear a dust/mist respirator 

roved by NIOSH/MSHA for dust which may be generated from this product, 

;rlying paint, or the abrasive. 

Continued on page 4 
P.82 

F63W2327-4370 page 4 

.CTIVE GLOVES 

iar gloves which are recommended by glove supplier for protection 

ist materials in Section II. 

PROTECTION 

>ar safety spectacles with unperforated sideshields. 

I PROTECTIVE EQUIPMENT 

;e barrier cream on exposed skin. 

Section IX -- PRECAUTIONS 

STORAGE CATEGORY 

. 

IUTIONS TO BE TAKEN IN HANDLING AND STORING 

.ntents are FLAMMABLE. Keep away from heat, sparks, and open flame, 

iring use and until all vapors are gone: Keep area ventilated - Do net 

. - Extinguish all flames, pilot lights, and heaters - Turn off stoves, 

:ric tools and appliances, and any other sources of ignition. 

>nsult NFPA Code. Use approved Bonding and Grounding procedures. 

_ep container closed when not in use. Transfer only to approved 

liners with complete and appropriate labeling. Do not take internally, 

out of the reach of children. 

I 'PRECAUTIONS 

lis product must be mixed with other components before use. Before 

Lng the packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS, 

ltentional misuse by deliberately concentrating and inhaling the 

=nts can be harmful or fatal. 

Section X — OTHER REGULATORY INFORMATION 

313 (40 CFR 372.65C) SUPPLIER NOTIFICATION 

^S No. CHEMICAL/COMPOUND % by WT % Element 

L08-88-3 Toluene. 1 

330-20-7 Xylene. 2 

TORNIA PROPOSITION 65 

IRNING: This product contains chemicals known to the State of 

:crnia to cause cancer and birth defects or other reproductive harm. 

CERTIFICATION 

Ll chemicals in this product are listed, or are exempt from listing, 

ie TSCA Inventory. 

ie above information pertains to this product as currently formulated, 

Ls based on the information available at this time. Addition of 

:ers or other additives to this product may substantially alter the 

jsition and hazards of the product. Since conditions of use are 

Lde our control, we make no warranties, express or implied, and assume 

Lability in connection with any use of this information. 
0 [0658] 

P.83 

ENVIRONMENTAL DATA SHEET 

(Certified Product Data Sheet) 

THE SHERWIN-WILLIAMS COMPANY 

101 Prospect Avenue N.W. 

Cleveland, OH 44115 

06-MAR-98 

his document includes all data required by 40 CFR 63.801(a) for a 

ified Product Data Sheet under criteria specified in 40 CFR 63.805(a). 

.11 data given below are MAXIMUM THEORETICAL VALUES based on the product 

URRENTLY FORMULATED. Variations may occur on individual batches due to 

stments made during production. 

UCT 

63W2327-4 370 

* - Trade Mark 

OLANE* T Plus Custom Polyurethane Enamel, BENJ. MOORE #879 WHITE 

UCT WEIGHT 

14.28 lb/gal 

SPECIFIC GRAVITY 

1.72 

RD CATEGORY (for SARA 311/312) 

cute Fire 

FLASH POINT 

35 F TCC 

I SARA 

I 302 

I EHS 

1 N 

1 N 

1 N 

1 N 

1 N 

CERC. 

Y 

Y 

N 

N 

Y 

SARA 

313 

TC 

Y 

Y 

N 

N 

N 

HAPS 

112 

Y 

Y 

N 

N 

N 

Pet 

by 

Wt 

1 

2 

1 

7 

6 

Pet | 

by I 

Vol | 

3 1 

3 1 

3 1 

15 | 

11 1 

TILE INGREDIENTS 

oluene. 

108-88-3 

ylene. 

1330-20-7 

ethyl n-Amyl Ketone, 

110-43-0 

sopropyl Acetate. 

106-21-4 

-Butyl Acetate. 

123-86-4 

.ntinued on page 2 

.©,!,' 
P.84 

F63W2327-4370 page 2 

.TILE ORGANIC COMPOUNDS (follows EPA VOC Data Sheet) 

Coatin g Densit y —_^-^T4 . 28 lb/ga l 

Tota l Volatile s 18.7 %.. by wt, 

1711 g/1 

37.0 % by vol. 

Federally exempt solvents: 

Water 

Organic Volatiles 

Percent Non-Volatile 

VOC Content -p^— 2.67 lb/gal 

0.0 % by vol. 

37.0 % by vol. 

63.0 % by vol. 

1. 

2. 

2.67 lb/gal 

4.24 lb/gal 

0.23 lb/lb 

.RDOUS AIR POLLUTANTS 

'olatile HAPS Pounds per Gallon 

'olatile HAPS Pounds per Gallon of Solids 

'olatile HAPS Pounds per Pound of Solids 

QUALITY DATA 

>ensity of Organic Solvent Blend 

'hotochemically Reactive 

E DISPOSAL 

0.0 % by wt. 

18.7 % by wt. 

81.3 % by wt. 

320 g/1 total 

320 g/1 less exempt solvents 

508 g/1 solids 

0.23 kg/kg solids 

0.68 lbs/gal 

0.04 lbs/lb 

7.22 lbs/gal 

YES 

aste from this product may be hazardous as defined under' the Resource 

ervation and Recovery Act (RCRA) 40 CFR 261. 

aste must be tested for ignitability to determine the applicable EPA 

rdous waste numbers. 

:Sz_, 
P.85 

MATERIAL SAFETY DATA SHEET 

jSA^..W_w^'_*w!»&>'7nj;V 

DQUCT NAME: FOURSEAL PRIMER HMIS CODES: H F R P 

HOUCT CODE: 48-9001 2* 3 2 G 

__=============== SECTION I - MANUFACTURER IDENTIFICATION ================= 

vlUFACTURER'S NAME: LILLY INDUSTRIES, INC. 

->RESS: 28335 Clay Street , Elkhart , I N 46517 

IRGENCY PHONE: (800) 424-9300 INFORMATION PHONE: (800) 397-1062 

IE REVISED : 01-03-94 NAME OF PREPARER : 

"--=== = SECTION I I - HAZARDOUS INGREDIENTS/SARA II I INFORMATION ========= 

j OCCUPATIONAL EXPOSURE LIMITS VAPOR PRESSURE WEIGHT 

fiOOUi COKPONEKTS , CAS NUMBER OSHA PEL ACGIH TLV OTHER an Hg 6 TEHP PERCENT 

" OE MONOMER 100-42-S SOppi 50ppn 4.5 68F 25 

HYL ETHYL KETONE • 78-93-3 200pp» 200pps 70.2 66f S 

IK 108-10-1 SOPPK SOPPH 1.0 50F 3 

ickates toii c cheoical(s) subject to the reporting requireients of section 313 of Titl e U I and of 40 CFR 372. 

s ipfcraation tust be included in al l HSDSs that are copied and distributed for thi s naterial. 

\Z0<- L es P/^ GAL 3-7*/ 

=-.,_=.= === = ==== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============= 

ILI.NG RANGE: 175 to 293 Oeg F SPECIFIC GRAVITY (H20=l): 1.3 

POR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER 

LUBILITY IN WATER: Insoluble 

PEARANCE AND ODOR: Free-flowing liquid. Hydrocarbon odor. 

__.-_=:__:=_======== SECTION IV - FIRE AND EXPLOSION HAZARD DATA ===== 

ASH POINT: 23 Deg F METHOD USED: TCC 

AhMABLE LIMITS IN AIR BY VOLUME- LOUIER: 1.1% UPPER: 11.5% 

TINGUISHING MEOIA: FOAM, ALCOHOL FOAM, C02, DRY CHEMICAL, WATER FOG 

E-IAL FIREFIGHTING .PROCEDURES 

•_.sd containers aa/ be cooled nith water to prevent pressure build-up. 

it fighters should wear self-contained breathing apparatus. 

USUA L FIR E AND EXPLOSIO N HAZARD S 

!;te trot, heat, sparks, electrical equipaent and open flane. 

->*eo containers aay explode when exposed to eitrene heat. 

,84 
P.86 

i-9001 MATERIAL SAFETY DATA SHEET PAGE 2 OF 3 

:=__:_.==.=_================ SECTION V - REACTIVITY DATA ======= = = = === = = ======== 

ABILITY : STABLE 

.NDITIONS TO AVOID 

ai.nation of large aasses may allow build-up of exothermic heat. 

-.COMPATIBILITY (MATERIALS TO AVOID) 

•id accidental contact Nith peroxides. 

•.ZARDOUS DECOMPOSITION OR BYPRODUCTS 

roor. fi.no.ide and lou eolecular weight hydrocarbons. 

-.ZARDOUS POLYMERIZATION: MAY OCCUR 

'tt in a cool place. 

z=-. ================== SECTION V I - HEALTH HAZARD DATA ====================== 

•(HALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE 

:.5s_ve breathing of vapors can cause respiratory irritation, nausea and even asphyxiation. 

CIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE 

in contact can cause noderate irritation (rash/dermatitis) 

•c vortact will cause severe irritation or burns. 

( I N ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE 

'ins'Le prolonged exposure is not likely to result in the material being absorbed through the skin in haroful anounts. 

•.GESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE 

-estion nay cause irritation of the mouth,throat and gastro-intestinal tract. 

iALTH HAZARDS (ACUTE AND CHRONIC) 

.exposure can cause respiratory irritation and nausea. 

epeated excessive exposures to high aoounts nay cause central nervous systen,liver and kidney effects. 

^RCINOGENICITY: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO 

* listed ss a carcinogen. 

EDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE 

ceatod excessive exposure nay aggravate pre-existing liver and kidney disease. 

1ERGENCY AND FIRST AID PROCEDURES 

esn skin thoroughly uith soap and uater. 

iush eyes nith large aoounts of water and get nedical attention. 

*..ove person to fresh air and give artificial respiration if necessary. Get nedical attention. 

' swallowed, do not induce voniting; sunaon a physician. Voniting nay lead to cheiiical pneumonitis uhich can be fatal 

.&£" 
P.87 

5-9001 MATERIAL SAFETY DATA SHEET PAGE 3 OF' 3 

:========= SECTION VI I - PRECAUTIONS FOR SAFE HANDLING AND USE 

EPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED 

t.oi'e ill sources of ignition. Ventilate the area. Clean up spills with inert absorbent using non-sparking utensils. 

'?p out of drains .sewers and waterways. 

1 STE DISPOSA L METHOD 

• not flush to sewer .watershed or waterway. 

5."JSB of in accordance with local .state and federal regulations. 

, not incinerate closed containers. 

^ECAUTIONS TO BE TAKEN IN HANDLING AND STORING 

.ore away fron sources of heat or ignition. Keep containers closed when not in use. 

THER PRECAUTIONS 

> not Lake internally. 

*r industrial use only. 

rovnc container when pouring to prevent build-up of static charge. 

================== SECTION VII I - CONTROL MEASURES 

ISPIRATORY PROTECTION 

Ttv is exceeded, use cheaical respirator nith an organic vapor cartridge with prefilter or an air-supplied respirator 

•litn self-contained breathing apparatus. 

UNTILATION 

;av/ solvent vapors should be reioved fron the lower levels of the working area. In spray application areas engineerng s*d administrative control can be instituted to eaintain exposure level belov SOppi for styrene. 

ROTECTIVE GLOVES 

c-arene or polyvinyl alcohol for repeated contact. 

YE PROTECTION 

ar'ety glasses for protection against spray or splashes. 

THER PROTECTIVE CLOTHING OR EQUIPMENT 

rsvs-nt prolonged skin contact with contaiinated clothing. Wash contaiinated clothing before reuse. 

ORK/HYGIENIC PRACTICES 

_sh hands before eating or stoking. 

======================= = SECTION I X - DISCLAIMER ========================= = 

ISCLAIMER 

r>_ iffornation contained herein is infornation received froa our raw aaterial suppliers and other sources and is 

jlieved to be reliable. This data is not to be taken as a warranty or representation for which tilly Industries Inc. 

5su.iei legal responsibility. 

85* 
P.88 

i)2 OS iiS 09:5.3 S608 274 531-3 PBE JOBBERS 0 ©001/004 

^A^;£*? ^ 

0*fofc^ :TU>Xx_ 

MATERIAL SAFETY DATA SHEET 

Page 1 of 4 

HORTON PAINT COMPANY 

U S Chemical & Plastics, Inc 

Alco Industries Complies 

600 NOVA DRIVE SE 

JjASSILLON. OH^44646 

(330) 830-6000 

FOR CHEMICAL EMERGENCY SPILL, LEAK, FIRE 

EXPOSURE OR ACCIDENT, CALL DAY OR NIGHT IN 

USA: CHEN-REC 1-800-424-9300 

= a =s ^ ts a a tn at = = l sssa s s=s tf 3 a a a *• a a = 

SECTION I - IDENTIFICATION OF PRODUCT 

PRODUCT NAMEiiiOEi'.G.lossjWet Look Hardener 

PRODUCT C0DE:^9?-8^ :..'•« 

SYNONYM OR CROSS REFERENCE:t Hardener and Activator for Paints 

SCHEDULE B #; 3815.90.OOOO-O 

£=9»=3Bssa_-osBaaassasse!9tBiHBiaRssnssSsi!!SHi_iPsacs-Bpass3 ^ 

SECTION II - HAZARDOUS INGREDIENTS 

INGREDIENTS 

n-Butyl Acetate 

Ethyl Acetate 

Aromatic Hydrocarbons 

Hexyl Acetate 

WEIGHT % 

20-25% 

35-45% 

5-10% 

15-20% 

Propylene Glycol Monomethyl 

Ether Acetate 

Isophorone Diisocyanate 

Hexamethylene 

Diisocyanate 

2-Butoxyethyl Acetate 

10-15% 

<0.1% 

<0.3% 

2-5% 

CAS NUMBER 

123-86-4 

K1-7B-6 

64742-95-6 

83230-35-7 

108-65-6 

4093-71-9 

822-06-0 

112-07-2 

TLV/PELACGIH: TLV: ISO ppm 

OSHA PEL: 150 ppm 

STEL« 200 ppm 

ACGIH; TLV 400 ppm 

OSHA PELs 400 ppm 

ACGIH TLV* 2 5 

N/E 

N/3 

ACGIH TLV: 0.01 ppm 

ACGIH TLV: O.CO 5 

N/E 

ppm 

ppm 

T prv 6/fL . S.^" 

3 .so 

i w »«-=-=•==•=-_ ; = I*Q SI B ei -sj =r *= =s ss s= = as sS a • s s = =£=±*=;-asies«si 

SECTION H I - PHYSICAL DATE 

APPEARANCE: Viscous, clear to straw 

colored liquid 

SPECIFIC GRAVITY: 1.02 

VAPOR PRESSURE (iranHg): N/Av 

BOILING POINT: 169-2e7°F 

HELTING POINT: N/Ap 

VAPOR DENSITY: Heavier than air 

EVAPORATION RATE: (Diethyl Ether = 1) 

Slower than Diethyl Ether 

VOIATILES BY HEIGHT: Approximately 50% 

SOLUBILITY IN WATER: Miscible 

VOC: 492 Grams/Liter 

SCo 
P.89 

ii. 'JS i.i'J:54 'fl'iii.i-5 _7 4 531-3 I'UL .Ji.ibL'Lk'.i y U U1' • I.I M 4 

Page 2 of 4 (99-3) 

SECTION IV - FIRE AND EXPLOSION DATE 

FLASH PQINT T 2^¥JJ¥E Seta Flash Closed Cup 

LOWER FLAMMABLE LIMIT %: N/E 

UPPER FLAHHABLE LIMIT %; N/E 

F-CRE fciXTj-HGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam. 

SPECIAL FIRE FIGHTING PROCEDURES: Fight like a fuel oil fire. Cool fire exposed containers 

with water spray. Fire Fighter should wear OSHA/NIOSH approved self-contained breathing 

apparatus. 

UNUSUAL FIRE AND EXPLOSION HAZARD: (Conditions of Flammability) Closed containers exposed 

to high temperatures, such as fire conditions may rupture. 

:_i33a-i«_ia)_asC-!3asS5_ir_;3_lari--UMa_i-==s=====^^cr_;s = =;tfti=_;_!_ 

SECTION V - HEALTH HA_iARD/TOXICOLOGICAL PROPERTIES 

OVEREXPOSURE EFFECTS: 

ACUTE EFFECTS: 

EYES - Contact with eyes can cause irritation, redness, tearing, blurred. 

vision, and/or swelling. 

SKIN - Contact with skin can cause irritation, (minor itching, burning and/or 

redness), Dermatitis, defatting may be readily absorbed through the skin. 

3*?*HAI_ATION - Inhalation of vapors can cause nasal and respiratory irritation, 

dizziness, weakness, fatigue, nausea, headache, possible unconsciousness 

and/or asphyxiation. Aspiration of material into lungs may result in chemical 

pneumonitis which can be fatal. May be toxic. 

INGESTION - Ingestion can cause gastrointestinal irritation, nausea, vomiting, 

diarrhea. 

CHRONIC EFFECTS:. 

Overexposure to this material has apparently been known to cause the following 

effects in lab animals: liver, kidney, lung, blood, and central nervous 

system damage. May cause skin and/or respiratory sensitization 

CARCINOGENIC YES 

TERATOGEN YES 

MUTAGEN YES 

ISOCYANATE WARNING: 

X 

X 

X 

NO 

NO 

.NO 

ALIPHATIC POLYISOCYANATE OR POLYMERIC ISOPHORONE DIISOCYANATE OR POLYISOCYANATE: 

Repeated exposure may cause allergic skin rash, itching,, swelling. Repeated over-exposure... 

to isocyanates may cause lung injury, including a decrease in lung function, v/hich may be 

permanent. Over-exposure may cause asthma-like reactions with shortness of breath, wheezing, 

cough which may be permanent or permanent lung sensitization. This effect may be delayed for 

several hours after exposure. Individuals with pre-existing lung disease, asthma or 

breathing difficulties may have increased susceptibility to the toxicity of excessive 

exposure. 

1, 6 HEXAMETKY1ENE DIISOCYANATE: May cause temporary upper respiratory and/or lung 

irritation with cough, difficult breathing, or shortness of breath. Over-exposure may cause 

asthma-like reactions with shortness of breath, wheezing, cough or permanent lung 

sensitization. This effect maybe delayed for several hours after exposure. Prolonged skin 

contact may cause chemical burns. Liquid splashes in the eye may result in chemical burns. 

Individuals with pre-existing lung disease, asthma or breathing difficulties may have 

increased susceptibility to the toxicity of excessive exposures. 

3-f. 
P.90 

i.'S 'LS 09:55 ©60S 274 5-313 PBE JOBBERS 1)00.3/00.1 

Page 3 of 4 (99-8) 

ROUTES OF EXPOSURE: Inhalation , skin 

ipas^Qoa a 

FIRST AID: 

INHALATION -If inhaled, remove victim from exposure to well ventilated area. Make 

him/her comfortably warm, but not hot. Use oxygen or artificial respiration as 

required. Consult a physician. 

StODX - For skin contact, wash promptly with soap and excess water. Consult a physician. 

EYES - For eye contact, flush promptly with excess water. Consult a physician. 

INGESTION - If ingested, do not induce vomiting. Call a physician immediately. 

SECTION VI - REACTIVITY DATA 

STABILITY: stable "" 

CONDITIONS TO AVOID: Open flames, sparks, heat, electrical and static discharge. 

INCOMPATIBILITY MATERIALS TO AVOID: Strong acids, alkalies, oxidizers. 

HAZARDOUS DECOMPOSITION PRODUCTS: Unknown other than Carbon Dioxide, Carbon Monoxide and 

Carbon 

HAZARDOUS POLYMERIZATION: Will not occur. 

i = B=====i==-===== = = a = ==±i.ii3=-_==3ei_aaoa3ca3»s_; : 

SECTION VII - SPILL AND DISPOSAL PROCEDURE 

SPILLS, LEAK OR RELEASE.* Ventilate area. Remove all possible sources of ignition. Avoid 

prolonged breathing of vapor. Contain spill v/ith inert absorbent. Pour decontamination 

fluid over spill. Typical decontamination solutions are: 20% Tergltol TMN10, 80% water or 

0-10% Ammonia, 2-5% detergent, balance water. For large spills, it may be necessary to use 

a respirator to keep exposure levels below TLV/PEL limits 

WASTE DISPOSAL: Dispose of in accordance with local, state, and federal regulations. 

= = = **:-i*i=-i33^«aEO«go a = aaaoo-iita3*:*DiiooBBBnB*pao*:*3=a===-:==c=£= ^ BraBoccaoiin a 

SECTION VII - PROTECTION INFORMATION 

RESPIRATORY PROTECTION:. If TLV/PEL limits ar e exceeded, use NIOSH/MSHA approved respirato r 

to remove vapors. Use an air supplied respirato r if necessary. For isocyanates, use TC-19C 

positiv e pressur e supplied respirato r or equivalent. 

VENTILATION: Use adequate ventilatio n in volume and pattern to keep TLV/PEL below 

recommended levels. Explosion-proof ventilatio n maybe required. 

PROTECTIVE GLOVES: To prevent prolonged exposure, use rubber gloves, solvents nuiy be 

absorbed through the skin . 

EYE PROTECTION: Safety Glasses or goggles with splash guards or side shields. 

OTHER PROTECTIVE EQUIPMENT: Wear protectiv e clothin g as required to prevent skin contact. 

SECTION IX - HANDLING AND STORAGE PRECAUTIONS 

STORAGE AND HANDLING: Use v/ith adequate ventilation . Harmful or fata l if swallowed J 

Extremely flammable. Avoid contact with eyes and skin. Avoid breathing vapors. May cause 

lung irritatio n and allergi c respirator y reaction . Do not store the product above 100°F/38°C. 

Do not flame, cut, braze weld or melt empty containers. Keep the product away from heat, 

open flame, and othe r sources of ignition . Avoid contact with strong acids, alkalie s and 

oxidizers. 

88 
P.91 

i2'0S'9S 09:55 ©COS 274 5.31-3 PBE JOBBERS ©004/004 

Page 4 of 4 (99-3 

SECTION X - ADDITIONAL INFORMATION 

^d = = 3=!_-itf3sa = C£ 3 = '-=scsr c = sBoaaDCiaaDBiiaia 

SHIPPING INFORMATION; Please comply with OOT regulations in USA 

HMIS RATING: Health __2_ 4 » Extreme 

Eire 3 3 = High 

Reactivity O 2 » Moderate 

Personal Protection - See Section VII 1 » Slight 

O = Insignificant 

CALIFORNIA PROPOSITION 65: Trace amounts of some chemicals known to the State of California 

to cause cancer, birth defects or other reproductive harm may be present in this product. 

DO HOT FLAME CUT, WELD, OR MELT EMPTY CONTAINERS 

**£ = s= ==: s :£ *s :*£=*::*= ~^ :*£:= := = = := s ~^ = ~=-K :-===-s s ==s s s 

ABBREVIATIONS: 

IARC •= International Agency for Research N/AV = Not Available 

on Cancer 

ACGIH * American Conference of Governmental N/AP • Not Applicable 

Industrial Hygienists 

NIOSH **• National Institute of Occupational N/E = Not Established 

Safety and Health 

DOT *» Department of Transportation NTP = National Toxicology Program 

TLV - Threshold Limit Value PEL = Permissible Emission Level 

REFERENCES 

1. ACGIH. Threshold Limit Values and Biological Exposure Indices for 1988-89 

2. Material Safety Data Sheets of raw materials 

3. Dangerous Properties of Industrial Materials,' 7th Edition, N. Irving Sax and 

Richard J. Lewis. 

PREPARED BY.* MORTON PAINT COMPANY 

U S Chemical & Plastics, Inc 

i-Uco Industries Companies 

6CO NOVA DRIVE SE 

MASSILLON, OH 44646 

(330) 830-6000 

PREPARED ON May 9,. 1995 

SUPERCEDES January 13, 1994 

The information in the Material Safety Data Sheet has been compiled from our experience and 

data presented in various technical publications. It is the user's responsibility to 

determine the suitability of this information for the adoption of the safety precautions as 

may be necessary. We reserve the right to revise Material Safety Data Sheets from time to 

time as new technical information becomes available. The user has the responsibility to 

contact the Company to make sure that the sheet is the latest one issued. 

©-? 
P.92 

w_.cor_.in SOURCE DESCRIPTION - SUPPLEMENTAL 

•eui of Natural Reeource. AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-102A 11-93 Information attached? W (y/n) 

' this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

•25, Wis Stats. Completion of this form is.mandatory. The Department will not consider or act upon your application 

you complete and submit this form. It is not the Department's intention to use any personally identifiable information 

bis form for any other purpose. 

,ist all significant existing or proposed air pollution units, operations, and activities at the facility. A short narrative of the 

nventory of air pollution emissions unit (e.g., boiler, printing line, etc.) followed by equipment specifications will suffice, 

f the facility consists of several individual emission units, present this information in an outline format. (See instruction 

>ooklet for an example Unit description.) 

pOH SOS 

PAWTS FH.0r\ OTHE/V pHOCESf tlwCS " AO.C XliXoucnT -/A/To THl$ A l\E A 

FOS\r TH-IKKIW G r 7~/I M-A KI / ro t Qototuri oF TAK/toG JM/JU . DIE 

on-.»o*as Aoo curroot o]{ EXCESS F10£n. G£A<{ EOerj . TH>< Pnocesj 

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<;?z~ 
P.94 

of wiK=on.i_ SOURCE DESCRIPTION - SUPPLEMENTAL 

nmen. of N.tunl Re_o_r.e. AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-102A 11-93 Information attached? V (y/n) 

of this form is required by the Department for any air pollution control permit apphcation filed pursuant to s. 144.392 or 

3925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

ss you complete and submit this form. It is not the Department's intention to use any personally identifiable information 

i this form for any other purpose. 

List all sienificant existmg or proposed air pollution units, operations, and activities at the facility. A short narrative of the 

inventory of air pollution emissions imit (e.g., boiler, printing line, etc.) followed by equipment specifications will suffice. 

If the facility consists of several individual emission units, present this information in an outline format. (See instruction 

booklet for an example Umt description.) ... ^ 

805"- Soc 

'fUErte AT-TC 5" liVF»n.er> HPAr^a s TH^I*. O^T TH £ j-=*oT/<\-e FAcury 

THEA S A^ £ ALSO 1 Hlt H gFTit.fcT Fu^'« < Cfl w,3V-of 0 7H ^ Afti 

THE OFFICE Arxs'A li HE*TLii) Dy. FicCTtlK. I3s.se /io*TM HFMTtzsxt. 

THF IfUMflF D HE*TCfi< AIX.C M c pum«,c OtsrSiQG Alti A\.o»c UjTHE 

"X_ fUAVaKCtEs, EACH HEATBIL H •* * ITS OUK) STACK (^EX HAUiT^ . 

LP PUHCHASEQ IN /<?9T toAS. "7 9 ?5"« 1 G>ACS. 

?2J 
P.95 

Wisconsin 

icnt of Natural Resources 

BOILER OR FURNACE OPERATION 

AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-104 11-93 Information attache-? _ (,y/n) 

^STRUCTIONS ON REVERSE SIDE 

Facility name: 0u „ ^ FlMT^CLA« 

StackTidentifi^^niSQbw: $ () (9 

2. F_^iliity||i^ni^c^bhVnum 

4. ^6^atfw^emwi!6er. [1^ o£~ 

Unit description: 

xTFA . -Tt\>FAT\Far\ 5 f/Mir.t -^ 1 FCa4jx^___t-. 

io.1^^^^^^:^^^^^^^^^^^^^ ^ ^Uncontrolled D Controlled 

. - :(

w

--•-*•>•••/-• »V*TM^^ 

If the boder/furnacejs. controUed, enter the ^qontrpl. device numba*(s) from, the appropnate forms: 

4530-110. 

4530-114' 

4530-111 

4530-115 

4530-112, 

4530-116 

4530-113 

4530-117 

FMJI& I -r^FA^F £L Maximum.continuous rating: 

(St. Wt l>..'/(-» 

tnmBTU/hr I ga , .„ 

Manufacturer £) A W TA <Q ^ £ f. 0 ~7 9. Model number ~~] J\ 3 IC 

TizJJMJJx^^SJ^xW^SS^^Tixza.l\aix. /<m i^K *(< _L 

Fuels and firing conditions: 

Primary fuel Backup fuel #1 Backup fuel #2 Backup fuel #_ 

name i~£ L P. 

er heating value 

inum sulfur content (Wt.%) 

imum ash content (Wt.%) 

ss Combustion Air (%0-) 

ture content (as fired) (%) i^teSE 

..t\)^ii_-<.»;*_?*>4 s^rt-*.--.. 

imum hourly consumption 

al yearly consumption 

rrxaa^^X^^^^^p. 

BH»BB?jW 2S^_. ~7 9g_r.?. fi/H<T 

For this emissions unit, identify the method of comphance demonstration by completing Form 4530-118, 

DESCRIPTION OF METHODS USED FOR DETERMINING COMPLIANCE. Attach Form 4530-11S 

and its attachment(s) to this form. This is not a requirement of non-Part 70 sources. 

Please complete the Air Pollution Control Pennit AppUcation Forms 4530-126 and 4530-128 for this Uait. 

r: 
O>AHT0N> 3C"C0~7 ( G/WlN6fA.] 

CEILIAJ G HEATER. ZiHAUiT ZLOLJEHS BO5-S0C 

VEflTlCAL HEl&hT U ItlAlVxj HATS ^ ' To fo/> -P flLOtoSO. 

QIAM.ETBO. L\" QjUVFA-flFD HE ATS US /»>&* EFFIOB^T FUANAC^S Q) 

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BTU. OUT PUT SSOOO 

C p n SO 

F<U£L L.p. 

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A.e. 

P.97 

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u 

11%S..i QALS U.IJLQ ^7 

'ftr 1 
P.98 

ofWiKxn-m SOURCE DESCRIPTION - SUPPLEMENTAL 

ranent of Nuanl Resources AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-102A 11-93 Infonnation attached? _ (y/n) 

of this form is required by the Department for any air pollution control permit application filed pursuant to s. 144.392 or 

3925, Wis Stats. Completion of this form is mandatory. The Department will not consider or act upon your application 

ss you complete and submit this form. It is not the Department's, intention to use any personally identifiable information frcia 

form for any other purpose. 

List all significant existing or proposed air pollution'units, operations, and activities at the facility. A short narrative of the 

inventoiy of air pollution emissions unit (e.g., boiler, printing line, etc) followed by equipment specifications will suffice. If 

tbe facility consists of several individual emission units, present this information in an outline format (See instruction 

booklet for an example Unit description.) Q A cr o A r* o -N - • -r -

r^J > - JOJ- ^,Oj ' lOu:.. ,.f,,t-. OF •<.,'•'-.•.' 

l''A- -X vS ~ }t J Ji>J~ 

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c 

1 ("i 

'96n 
P.99 

of Wisconsin 

•tment of Natural Resources 

INS1RUCTIONS ON REVERSE SIDE 

STACK IDENTinCATION 

AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-103 11-93 Infonnation attached? _ (y/n) 

Facility name: FacU^j^tific^afnuml^^ 3. Stacki-idehtification nuniber. 

E^ausMg^^ 109 

10-104 4530-106 4530-107 4530-108 4530-109 

Identify this stack on the plot plan required on Form 4530-101 

Inmc^b^q^kimg^ 

£3 This stack has an acmal exhaust point. D This stack serves to identify fugitive emissions. 

If;ihisist_xfeb^aiEac_uafcexE_fo 

sSSiiar ^ --/ '<*\ / Q~9 ^J ^ THT »T« % 

^••.*V_v-:i'*'"WVV"*:'"*'-*«*^*i*-»'^>^^ 

feidefd_ineiBions)iat|wUey(checfc7.onejffl_^ 

^Circular q.s't*.fa___fi l*c" * • D rectangular length (feet) width (feet) 

E^aus]^gw|rate; 

Normll^SS^Pi.Al-Bifi Oo*Bjwto Maximum °ISS1.I$ (ACFM) C<"*a..vfo, 

E^ust|ga^temp^sfi^(noncMl); 7 o ( F) 

Exhaust gas moisture content Nonnal volume percent Maximum volume percent 

Exliaust.ias;diSciargeiQl.ectio_£ D Up 

_.v...v>.>_._.w w*-^*» * .^»W..,AAV...-....,^W/.*Kv,V..M..W ...Vrt.» • rt » 

D Down j_Olorizont__ 

fth_ss.rtaek<eqti_ppMswithiah*_u_±afc^ u Yes «_TNo 

exl^^ga ^ 

*« Complete the appropriate Air Pennit Apphcation Forms(s) 4530-104, 106, 107, 108 or 109 for each Unit 

exhausting through this stack. 

THBS£ 0- STAC**. /\Wl SUflUlwt 5L PrS.otF<< f LA^\ »"OAT/-VC )+[Tooiik>(,J 

?V 
ie of Wisconsin 

parunent of Natural Resources 

•E INSTRUCTIONS ON REVERSE SIDE 

PAINTING AND COATING OPERATIONS 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-108 11-93 Infonnation attached? ,(y/n) 

Facility name: /i , „ r,-.-^,, . 2. Facility ;ide_u_fication:numbeT: 

§^^M!Jr!^J^iJ^7i°ffiS^^ Soo - £D"* Process; number: Pd* 

la. Unit description: 

jjMliji^^|}^^ IS Uncontrolled • Controlled 

If thepfccessis coiatoll^imteKt-ie c61blrol-devicKiinmber6).firom oieappfopn^|orm(s): 

4530-110. 

4530-114 

4530-111, 

4530-115 

4530-112. 

4530-116 

4530-113, 

4530-117 

). 

.. 

5. 

). 

^^H(^o*rie<^mique and transfer efficiency (%): p ( ol j p n A-,. f ,-x - ??S "/;> 

Date of construction: dr.lastniodlficati'oir / 9 "z' § 

Normaloperking«±.edule: V hrs/dav .0 0 days/wk _7*-/ davs/yr 

Oven curing (complete if applicable): 

Number of ovens Specify oven fuels 

Total Maximum Energy input to each overc 

10. Describe all of the coatings' and solvents' composition (as applied) that are used by this unit. 

Solid-

's. 

f. 

voc 

% 

gWatcr 

% 

h. 

Coating 

or vex: 

Density 

gal/hr gal/yr g«Vyr W W W lbs/gal 

fll-fO'o-ni -Z.S8 'iostr.i 2HH °l.t<. HS1Z 

a-pemoL^ i.Hr. 1 CAV/tuT Q.1*) '151.1 ____£_ 

S.<7£ L-C°J 

Total coatings 

List the thinning solvents used with the coatings identified above. 

j 

Clean-up solvents 

Clean-up solvents 

Other (specify) 

ACr TnuF. . 

***** For this emissions unit, identify the method of comphance demonstration by completing Form 4530-118, ***** 

DESCRIPTION OF METHODS USED FOR DETERMINING COMPLIANCE. Attach Fonn 4530-118 

and its attachments) to this form. This is not a requirement of non-Part 70 sources. 

Please complete the Air Pollution Control Permit Application Forms 4530-126 and 4530-128 for this Unit. *»*»* 

bating categories (cL eg. - column b. above) should be entered as follows: 1 - for air dried coatings; 2 - for clear coatings; 3 

nr cured coatings; 4 - for extreme performance coatings; 5 - for other (specify) . 

%sr 
p.1 

c of Wisconsin 

>airtmeht of Natural Resources 

E INSTRUCTIONS ON REVERSE SIDE 

EMISSION UNIT HAZARDOUS AIR POLLUl ANT SUMMAK* 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Fonn 4530-126 11-93 Information attached? ,(y/n) 

Facility name: £uiro„ FlRf/lclA<, „,„,„„,.. 2. Ea^^^^^rajiiml>e n 

StacKdgi^^6n;iiumt>CT; "ft? - ^ 4. E0mlHdei5tific^oh: number POS 

Unit material description: / oc c i >^>G fLf<; /*-> 

Complete the following summary of hazardous air emissions from this unit Attach sample calculations and emission 

factor references. Attached? 

Units Units 

/00 - Hi - V l^n°i L&S 10-i.hn LPA Q-Qf-.fr TPY 

2>3£- 2^ - H Q.g^fT MS. ~7> x>8 (-A* ft- OO?, 

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1A*/Hu< ^ ThF.Mj.nrjn. = Acn^L. £ f-t i.l L*>JI _2>1 &Aj:; ^ */ H ^ 

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TPY 

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Qy(C FI-1 I VTF A - "tnr/ti U T Pfl-C,,* * ^ 0 *^ 6/iC

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?_9 
P.2 

7ao( ••*"• 

ORGANIC PEROXIDES 

Material Safety Data Sheet 

Elf Atochern Code: 124 

TRADENAME LUPERSOL DHD-9 

CHEMICAL NAME Methyl Ethyl Ketone Peroxide 

MOLECULAR FORMULA Mixture of C4H10O4 

and CgH-igOg 

Revision Date: OV/12/95 

Sipersedes Form Dated: 36/1J/95 

CHEMICAL FAMILY Organic Peroxide 

SYNONYMS 2-ButBnor*! Pnroxide 

HA2ARDOUS INGREDIENTS 

•Materials or Components RQ. lbs. X M/ W 

Methyl ethyl ketone peroxide structures 10 33.3 

account for 8.7 • 9.OX active oxygen 

Hexylene glycol 6.0 

Dimethyl phthalate* SOOO 56.2 

Methyl ethyl ketone* 5000 1.0 

Hydrogen peroxide 1.5 

CAS Mo. 

13JS-23-« 

107-41-5 

131-11-3 

78-93-3 

7722-84-1 

Halprd Data 

ACGIH STEL = (!-.:• ppn (Celling) 

OSHA TLV = :!!> spm (Ceiling) 

OSHA PEL/TUi*. • 5 mg/ui3 

OSHA PEL/TIM • 200 ppm 

OSHA PEL/TUit • 1 ppm 

•This product contains toxic chemicals subject to the reporting requirements of section 313 of the Erergcrcy Planning and 

Ccnraxiity Rlght-To-Know Act of 1986 and of 40 CFR 372. 

This product is listed on the U. S. EPA, TSCA Inventory. As of the date on which this MSDS uas prepared, those chemicals are 

not listed under California Proposition 65 and are nat classified as carcinogenic by IARC, NTP, or OSHA. 

SHIPPING INFORMATION 

D.O.T. SHIPPING NAME Organic Peroxide Type 0, Liquid 

(Methyl ethyl ketone peroxide(s) S45X) 

HAZARD CLASSIFICATION 5.2 

I.D. NUNBER UN3105 

FREIGHT CLASSIFICATION Chemists NOtBN 

IM0G CODE PAGE 5225 

PHYSICAL PROPERTIES 

MELTING/FREEZING POINT, *C Below -20 

HOLECULAR WEIGNT N/A 

SPECIFIC GRAVITY (HjO « 1), 25/25*C 1 .OMO It in. 

•S.A.D.T 60eC, 40# CUbe 

•Self accelerating Decomposition Temperature 

VAPOR PRESSURE H/E 

VAPOR DENSITY (Air = 1) N/E 

X VOLATILES BY VOLUME M/E 

APPEARANCE I OOOR Clear liquid, ketcne odor 

S0LU81LITY IN H-J3 Insoluble 

FIRE ANO EXPLOSION OATA 

FLASH POINT, "C/'F 

EXTINGUISHING MEDIA 

SPECIAL FIRE FIGHTING PROCEDURES. 

UNUSUAL FIRE I EXPLOSION HAZARDS. 

.66/151 

Uater Fog, Dry Chemical, Foam, Uater Spray 

If large a*ount is involved, evacuate am and fight Hre 

froa safe distance. Cool curroutding Material uith uater. 

Contamination, Teaperature • Can deconpose uith force if 

confined during exposure to fire . 

REACTIVITY DATA 

STABILITY Unstabl e 

CONDITIONS CONTRIBUTING TO INSTABILITY Thermal 6eco«tx>sition, contamination 

INCOMPATIBILITY (avoid contact uith) Strong acids, strong alkalis , strong axiciztsrs, acetone, 

transition metal salts , promoters and recic ng agents 

HAZARDOUS OECa-tfOSIT ION PROOUCT S Decomposition products are f I Burnable and nia-. eutoignite 

CONDITIONS TO AVOID Heat, flrwnes, sparks, ignition sources, cc«i lamination 

Page 1 of 3 

elf atochem 

ZHO 

Ell Atochem Nonh America, Inc. • Fine Chemicals Group • Organic Peroxides • 2000 Markut Sireei • Phiiadelpnia, Pfi \c. 103 3222 

Phone (800) 550-5575 - Fax: (215) 419-7413 - ">&Mr emergency No: Chemlrec (800) 424-9300 
P.3 

MATERIAL SAFETY SHEET 

LUPERSOL DHD-9 

SPILL OR LEAK 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Use absorbent material, sweep or scoop n> uiirg non-sparking 

tools and dispose of imnediately. 

UASTE DISPOSAL METHOO Consult with an Elf Atochea representative for the telephone 

nunber of your state's hazardous uaste agency. 

TOXICITY 

TOXICOLOGICAL INFORMATION - Methvl Ethvl Ketone Peroxide 

Data fron the scientific literature on methyl ethyl ketone peroxide (MEKP) ere siamarized below. 

Single exposure (acute) studies on 40-60X MEKP in dimethyl phthalate indicate: 

Oral • Moderately toxic to rats (U>so*464 ng/kg) 

Oermal - Slightly toxic to rabbits (L0M4,000 ms/fcg) 

Inhalation - Practically non-toxic to rats (4-hr LCgo,17-50 mg/L) 

Eye Irritation - Corrosive to rabbits 

Skin Irritation - Moderately irritating to rabbits (4-hr exposure, 4.5/8.0) 

Repeated oral administration or intraperitoneal injection (7-weeks) of MEKP (97 mg/kg/day) uas reported to result In decreased 

body ueight, saitd liver injury and death in rats. Following repeated skin application (13-ueeks) of MEKP in dimethyl phthalatt 

at doses up to 107 ag/rat/day and 35.7 mg/mouse/day, severe skin damage and animal deaths (only at the highest doie levels) wer« 

the primary effects in rats and mice. Spleen and bone marrow changes, considered secondary to the severe skin CMroige, were noted 

in animals at the high doses. Higher doses Cup to 810 and 1600 mg/kg/day in rats and nice, respectively) availed to rat and 

mouse skin for a shorter time (2-weeks) produced siailar effects. Long-term repeated skin application (25-iMeks) of MEHP In 

dimethyl phthalate was reported to enhance skin tumor production in mice irradiated with UV8. MEKP has produced icnetic changes 

in standard tests using bacterial or animal cells. However, no genetic changes occurred in a standard los: (bone marrow 

micronucleus) using mice from the 13-week skin application stud/. 

ECOLOGICAy INFORMATION • Methvl Ethvl Ketone Peroxide 

Ecotoxicological infonnation: 

96-hr ICjofiW*/: M. 2 mg/L, slightly toxic 

Chemical fate information: 

Methyl ethyl ketone peroxide (MEKP) uas evaluated for biodegradability in a closed bottle system anj -.'as reported to 

be readily biodegradable. An ECS Q of 16 mg MEKP/L activated sludge uas reported In an activated slutige respiration 

inhibition test. 

HEALTH HAZARD INFORMATION 

POTENTIAL HEALTH EFFECTS • Methvl Ethyl Ketone Peroxide 

Skin contact snd Inhalation are expected to be ths primary routes of occupational exposure to methyl ethyl Ketone peroxide 

(KEKP). MEKP can be destructive to tissue, producing burns on contact with any body tissues. Contact with (he eyes can cause 

severs irritation and injury, possibly with loss of sight. While swallowing of KEKP fs unlikely, if swallowed chis material can 

cause severs irritation snd injury to the mouth, throat, stomach and liver, liver failure and respiratory distress; death mBy 

follow. Overexposure to MEKP vapors may cause eye and respiratory tract irritation, with headache and dizzine*:*. Allergic skin 

response is rare, but has be-en reported for MEKP. This material is considered, on the basis of single exposure (acute) animal 

tests, to be moderately toxic after ingestion. 

EMERGENCY FIRST AID: 

INGESTION Do HOT induce vomiting. Get emergency medical attention for gavage. 

DERMAL FlusKwith soap and water. Get medical attention. 

EYE CONTACT IMMEDIATELY flush with plenty of water for at least 15 ainutea. Get ne-iicol attention. 

INHALATION Remove to fresh air. If not breathing, give artificial respiration. Get i.-.adical attention. 

SPECIAL PROTECTION INFORMATION 

VENTILATION REQUIREMENTS... Use with adequate ventilation. Local exhaust. 

EYE Safety glasses, goggles, face shield. 

HAND (Glove Type) Heoprene, nitrite rubber. 

•RESPIRATOR TYPE Supplied air respirator with full face piece, hood or helmet. 

OTHER PROTECTIVE EQUIPMENT. Eyewash station. 

•Use only NIOSH/MSHA approved equipment 

Page 2 of 3 
P.4 

ORGANIC PEROXIDES 

Material Safety Data Sheet 

MATERIAL SAFETY SHEET 

LUPERSOL DHD-9 

LABEL PRECAUTIONS 

PRECAUTIONARY LABELING Uash thoroughly after handling 

Do not get in eyes, on skin or clothing 

Do not store near combustibles 

Empty container aay contain hazardous residues 

Keep container closed 

Kemp away froa heat, sparks, and flames 

Oo not reuse container 

OTHER STORAGE ANO 

HANDLING CONDITIONS Store below 100'F (36*0 to maintain active oxygen content 

PREPAREO BY: ADDRESS: PHONE: 

Organic Peroxides Regulatory 2000 Market Street, Phila., PA 19103 V800-55S-!575 

NOTES: N/E • Not Established 

N/A * Hot Applicable 

Elf Atochem North America, Inc. believes that th* information and recommended orm contained herein Cin:ltding data and 

statements) are accurate as of the date hereof. NO UARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF ^MERCHANTABILITY, 

OR ANY OTHER UARRANTY, EXPRESS OH IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein 

relates only to the apecific product designated and may not be valid Whera such product is used in combination with any other 

materials or in any process. Further, since the condition* and methods of uae of the product and of the inf imation referred 

to herein are beyond th* control of Elf Atocham, Elf Atochem expressly disclaims any and all liability •• to an, results obtained 

or arising from any use of the product, or reliance on such information. 

7/12/95 <1) 

Page 3 of 3 

elF atochem 

AIO 

Ell Atochem North America, Inc. • Fine Chemicals Group • Organic Peroxides • 2000 Market Street - Philadelphia, PA 19103-3222 

Phone: (800) 558-5575 • Fax: (215) 419-7413 • 24 Hr. Emergency No: Chemtrec (800) 424-9300 
P.5 

10. 

w ORUH CONPANIES 

2130 ENERGY PARK DRIVE 

ST PAUL, MN 55108 

TELEPHONE: 612-645-9224 

FAX: 612-645-9452 

October 03, 1997 

SAFETY DIRECTOR 

CUSTOM FIBERGLASS MOLDING 

E 5880 LITTLE RIVER ROAD 

WEYAUWEGA, WI 54983 

DEAR VALUED CUSTOMER: 

IN ACCORDANCE WITH THE HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FROM THE 

OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA). WE ARE ENCLOSING A SAFETY DATA 

SHEET (MSDS) ON THE FOLLOWING: 

PRODUCT DESCRIPTION VENDOR 

AOC E-010-01 ALPHA/OWENS-CORNING 

THE MSDS'S SHOULD BE UTILIZED FOR THE EDUCATION AND TRAINING OF YOUR EMPLOYEES AS TO 

THE PROPERTIES, HAZARDS. AND PROTECTION REQUIREMENTS RELATED TO THE PRODUCTS WHICH 

YOU PURCHASE FROM WORUM COMPANIES 

SINCERELY YOURS. 

RICK REMACKEL 

MATERIAL SAFETY DATA SHEET COORDINATOR 

./.°2>L *& 
P.6 

Page: 1 of 9 

Prepared: 14 December 1995 

,",ow.».

 0<"""" e

 MSDS No.: 9512 UV1 

MATERIAL SAFETY DATA SHEET 

Section 1: Product and Company Information 

Product Name: E010-01 Vinyl Ester Resin containing Styrene 

Manufacturer: AlphaVOwens-Corning L.L.C, P. O. Box 610, Collierville. TN 38027-0610 

Telephone: 901-854-2800 (8am-6pm CT weekdays). 

Emergency Contacts: 

Manufacturer ONLY (24 HOURS/DAY): 901-854-2800, 

CHEMTREC (24 hours everyday): 800-424-9300. 

CANUTEC (Canada - 24 hours everyday): 613-996-6666. 

Health and Technical Contacts: 

Health Issues Information (8am-5pm CT): 901-854-2800, 

Technical Product Information (8am-5pm ET): 519-821-5130. 

Section 2: Composition and Ingredient Information 

Common Name Chemical Name CAS No. Wt, % 

Vinyl Ester Resin Epichlorohydrin, Bisphenol A, 36425-15-7 50-70 

Methacrylic Acid Polymer 

Styrene Monomer Vinyl Benzene 100-42-5 30-50 

Note: See Section 8 of MSDS for exposure limit data for these ingredients. 

Section 3: Hazards Identification 

J 

J 

J 

Appearance and Odor: Viscous liquid with an aromatic odor. 

Primary Route(s) of Exposure: inhalation, skin, eye 

Potantial Health Effects: 

ACUTE (short term): This product if inhaled may cause upper respiratory irritation and possible 

central nervous system effects including headaches, nausea, vomiting, dizziness, drowsiness, lo-;s 

N/A = Not Applicable UID = Nol Determined 
P.7 

Page: 2 of 9 

*j<^^*^m-m Prepared: 14 Decembei H-J95 

•«•'"••-"-"" • MSDS No.: 951;:VV1 

MATERIAL SAFETY DATA SHEET 

of coordination, impaired judgment, and general weakness. It may cause dryness, cracking, 

tenderness and irritation of the skin. Direct contact with this product may res jit in immediate 

irritation to the eyes with redness, burning, tearing and blurred vision. It may cause mouth, thioat 

and gastrointestinal irritation, nausea, vomiting, and diarrhea if ingested. Aspiration of material ir to 

the lungs can cause chemical pneumonitis which can be fatal. See Section 3 for exposure controls. 

CHRONIC (long term): Styrene is a possible cancer hazard (IARC Group 2B). Prolonged 

exposure may result in nausea, loss of appetite, general weakness, changes in blood chemistry, 

and peripheral and central nervous system activity. Prolonged or repeated skin contact may rusult 

in dermatitis marked by rough, dry cracking skin. Prolonged or repeated eye exposures to vapors 

may cause irritation to the lining of the eyelids. In laboratory animals, chronic exposure to styr=n = 

at high concentrations has been found to cause liver abnormalities, kidney damage and lung 

damage. In addition, preliminary results of inhalation studies indicate that laboratory rats expose j 

to 800 ppm styrene via inhalation showed evidence of hearing loss. Relevance to humans renains 

unclear. See Section 11 of MSDS for additional toxicological data. 

Medical Conditions Aggravated by Exposure: Persons with a history of chronic respiratory dijns se, 

skin disease, or central or peripheral nervous system disorders may be at increased risk for worsiining 

their conditions from exposure to this product. 

Section 4: First Aid Measures J 

Inhalation: Move person lo fresh air. Administer cardiac or pulmonary resuscitation (CPR) if a pulse 

is not detectable or if unable to breathe. Provide oxygen if breathing is difficult. Obtain immediate 

medical assistance. 

Eye Contact: Flush eyes with running water for at least 15 minutes. Seek medical attention 

immediately. 

Skin Contact: Wash with mild soap and running water. Seek medicai attention if irritation persis:;;. 

Ingestion: Do not induce vomiting. Prevent aspiration. Transport to hospital immediately. 

Note to physician: Perform gastric lavage in accordance with procedures for ingestion of petrolourn 

products. 

Section 5: Fire Fighting Measures 

Rash Point and Method: 87°F (31 *c) - 97°F (36 *c) Method - Setaflash Closed Cup 

Flammability Limits (%t: LFL: 0.9 - Styrene 

N/A = Nol Applicable N/D = Not Determined 
P.8 

Page: 3 of 9 

Prepared: 14 Decembei 1995 

.t-.A/ow-.-co^NflNo MSDS No.:95i;iV-V1 

MATERIAL SAFETY DATA SHEET 

UFL: 6 8 - Styrene 

Auto Ignition Temperature : 914°F (4908C) - Styrene 

Extinguishing Media: Foam, C02 or dry chemical. 

Unusual Fire and Explosion Hazards: Product is a NFPA Class 1C flammable liquid. Prevent -.static 

and other electrical sparking. Ambient temperatures above 77°F (25°C), or heat from fire may ca JS<; 

polymerization, heat generation, and vapor expansion. Excessive heat may cause closed contairors 

to rupture. Keep cool with water spray. 

Fire Fighting Instructions: Treat as a flammable liquid type fire. In a sustained fire wear 

self-contained breathing apparatus and full protective bunker turnout gear. 

Hazardous Combustion Products: Primary combustion products are carbon monoxide, carbon 

dioxide, and low molecular weight hydrocarbons. Other undetermined compounds could be release 1 

in small quantities. 

Section 6: Accidental Release Measures ] 

Releases of this product to the land, water and air may require reporting to local, state and federal 

agencies. 

Land Spill: Prevent material from entering sewers or waterways. Remove all sources of ignition 

(flames, hot surfaces, and electrical static or frictional sparks). Ventilate area. Absorb with inert 

materials (vermiculite or sand) and place in a closed container for disposal as solid waste. Wash area 

well with trisodium phosphate and water. Resin that may have been mixed with peroxide initiators; p-ior 

to spillage should be mixed with inert material and removed to an open area. Allow time to gel and 

cure. 

Water Spill: Material is mostly insoluble. The material will sink to the bottom leaving a styrene 

monomer sheen. Styrene is harmful to aquatic life in very low concentrations. Notify local 

environmental, health and wildlife authorities, and water intake operators. Contain with booms to 

minimize spread on water. Collect floating material with sorbents and vacuum/collect sunken soli is 

Disperse any remaining residue to reduce aquatic harm. 

Air Release: Spills ofthis material may release styrene and volatile organic compounds into the air 

Spills should be cleaned or covered to prevent volatilization of styrene. 

Section 7: Handling and Storage J 

Storage Temperature: Store below 77°F (25°C) 

N/A = Not Applicable N/D = Nol Determined 
P.9 

Page: 4 of 9 

Prepared: 14 December 1!)95 

flflr..,.*........!.. MSDS No.: 951:!1<-V1 

MATERIAL SAFETY DATA SHEET 

Storage Pressure: N/A 

General: Store below 77°F (25°C). The storage drum, when emptied, can contain vapor, liquid cr 

solid residues that may be hazardous. Keep away from heat, sparks, flames and direct sunlight. DO 

NOT cut, puncture or weld on or near this container. Do not apply air or gas pressure to this cont airer 

which is not rated for pressure. Containers should be bonded and grounded during transfer of 

material. In bulk storage, check vent and flame arrestor for plugging by formation of polymer. 

; : 

Section 8: Exposure Controls and Personal Protection 

Ingredient OSHA PEL ACGIH TLV 

Vinyl Ester Resin None Established None Established 

Styrene Monomer 100 ppm (8-hr TWA) 50 ppm (3-hr TWA) 

200 ppm (ceiling) 100 ppm (STEL) 

600 ppm, 5 minutes in any (skin notation) 

3 hrs. (peak) 

Engineering Controls: General dilution ventilation and/or local exhaust ventilation should be pre vided 

as necessary to minimize exposures. 

Personal Protection: 

Respiratory Protection: If irritation occurs, or if the TLV or PEL is exceeded, use a NIOSH/MSHA 

approved air purifying respiratorwith organic vapor cartridges or canisters, or supplied air 

respirators. Use respiratory protection in accordance with your company's respiratory protectian 

program, local regulations, or OSHA regulations under 29 CFR 1910.134. 

Skin Protection: Wear long sleeved shirt, long pants and chemical resistant gloves such as 

polyvinyl alcohol, polyethylene or viton. 

Eye Protection: Chemical protective goggles and/or face shield must be worn whenever possibility 

exists for eye contact. 

Work/Hygienic Practices: Handle in accordance with good industrial hygiene and safety practices 

These include avoiding unnecessary exposures and proper selection and use of personal protect ve 

equipment. Launder contaminated clothing before reuse. Safety showers and eye wash stations 

should be available. Use explosion proof motors and equipment. Containers should be grounded 

and/or bonded when material is transferred. 

Section 9: Physical and Chemical Properties J 

N/A = Not Applicable N/D = Not Determined 
P.10 

/K { If Page: 5 of 9 

ff VI - 11 , Prepared: 14 Decembei 1!395 

'

l

'"""""" ' "••" " MSDS No.: 951:'. W-V1 

MATERIAL SAFETY DATA SHEET 

Vapor Pressure (mm Hg (S> 20°C): N/D 

Vapor Density (Air=1t: N/D 

Specific Gravity (water=1): 1.1 Boiling Point: >95°F (>35°C) 

Solubility in Water: Insoluble Viscosity: 10 -1000 mPas 

fit!: N/A Physical State: Liquid 

Appearance: Viscous liquid Freezing Point: Not Available 

Odor Type: Aromatic 

Evaporation Rate/n-Butyl Acetate=1): N/D 

Section 10: Stability and Reactivity 1 

General: Stable below 77°F (25"C) 

Incompatible Materials and Conditions to Avoid: Peroxides, oxidizers, acids and bases. Amt'iei it 

temperatures over 77°F (25°C), or heat from fire situations may cause polymerization, heat generation, 

and vapor expansion. May cause closed container to rupture. 

Hazardous Decomposition Products: Oxides of carbon and low molecular weight hydrocarbons;. 

See Section 5 of MSDS for combustion products statement. 

Hazardous Polymerization: May occur. Avoid excessive heat, contamination and prolonged storage 

above 77°F (25°C). 

Section 11: Toxicological Information 

CARCINOGENICITY: The 

ingredient as a carcinogen: 

Inaredient 

Vinyl Ester Resin 

Styrene Monomer 

following table indicates whether 

ACGIH 

No 

No 

IARC 

No 

Yes 

or not each 

NTP 

No 

No 

agency has listed each 

OSHA 

No 

No 

J 

N/A = Nol Applicable N/D = Not Determined 

/PS 
P.11 

ADC 

* l PIIA/OWGMC*>CORNIN a 

TOXICITY: 

Ingredient 

Page: i5 cf 9 

Prepared: 14 December 1995 

MSDS No.: 951214V1 

MATERIAL SAFETY DATA SHEET 

LD^ Oral 

(g^g) 

LDM Dermal 

(g/kg) 

Vinyl Ester Resin Not Available Not Available 

Styrene Monomer5.0 (rat) Not Available 24 (rat) 

L-Ca Inhalation 

(g/m5.4 hrs.) 

Not Available 

Styrene Monomer: In March, 1987, the International Agency for Research on Cancer (IARC) 

reclassified styrene as possibly carcinogenic to human (Group 2B) due to "inadequate evidence ir 

humans", "limited evidence in animals" and "other relevant data". Previously, styrene was classifiud as 

a Group 3 compound (not classified as to carcinogenicity to humans). The IARC working group 

determined that the weight of data on genetic and related effects, together with the consideration that 

styrene metabolized in humans and animals to styrene oxide for which there is sufficient evidence of 

carcinogenicity in experimental animals and has been classified by IARC as probably carcinogenic to 

humans (Group 2A), was sufficient reason to recommend the change in classification. 

J 

J 

Section 12: Ecological Information 

This product may cause harm to animals, plants or fish. 

Section 13: Disposal Considerations 

RCRA Hazard Class: Characteristic hazardous waste (D001) due to ignitability. 

Section 14: Transport Information 

DOT Shipping Names: Resin Solution 

Hazard Class or Division: 3 

Identification No.: UN1866 

Label(s) required (if not excepted): Flammable Liquid 

Special Provisions: B1.B52 

Secondary: none 

Packing Group: III 

Packaging Exceptions: 173.150 

N/A = Not Applicable N/D = Not Determined 

,/o^ 
P.12 

J \ | I f Page: 7 of 9 

ff \LJL M Prepared: 14 December 1995 

U„.,.W.K..».. 1 « MSD S No . 951i:v.vi 

MATERIAL SAFETY DATA SHEET 

T7. T30 

Non-bulk Packaging: 173.203 Bulk packaging: 173.242 

EPA Hazardous Substances: Styrene EQ: 1000 lbs 

Quantity Limitations: Passenger Aircraft: 60 liters 

Cargo Aircraft: 220 liters 

Marine Pollutants: Styrene monomer, inhibited 

Freight Description: Plastic liquid, NOI (NMFC) 

Hazardous Material Shipping Description: Resin solution, 3. UN1866, PG III. RQ 

Monomer), Marine Pollutant (Styrene monomer) 

ERG Number: 26 

Transportation of Dangerous Goods - Canada 

Proper Shipping Name: Resin Solution 

TDG Hazard Classification: (Primary): Class 3 (Secondary): None 

IMO Classification: Class 3.3 

ICAO/IATA Classification: 3 

Product Identification Number: UN1866 

Packing Group: III 

Control Temperature: None 

Emergency Temperature: None 

Schedule XII Quantity Restriction: None 

Reportable Quantity for US Shipments: 1000 lbs. (Styrene) 

IATA Packing Instructions: Passenger/Cargo: 309 

Cargo Only: 310 

Limited Quantity: Y309 

Maximum Net Quantity per Package: Passenger/Cargo: 60 liters 

Cargo Only: 220 liters 

Limited Quantity: 10 liters 

N/A = Nol Applicable N/D = Not Determined 

y/o 
P.13 

/ \ P""1 P~ Page: 8 of 9 

f ^ * " - Prepared: 14 Decembei 1U95 

.I...IA,OW^..O0.H.»<. MSDS No.: 951:!1<IV1 

MATERIAL SAFETY DATA SHEET 

Special Provisions: None 

Section 15: Regulatory Information J 

TSCA Status: Each ingredient is on the Inventory. 

NSR Status (Canada): Each ingredient is on the DSL. 

SARA Title III: Hazard Categories: 

Acute Health: Yes 

Chronic Health: Yes 

Fire Hazard: Yes 

Pressure Hazard: No 

Reactivity Hazard: Yes 

Reportable Ingredients: 

Sec. 302/304: Styrene 

Sec. 313: Styrene 

California Proposition 65: Styrene oxide is listed as known to the State of California to cause cuneer. 

Styrene oxide is a metabolite of styrene monomer. 

Clean Air Act: Styrene is listed as a hazardous air pollutant. 

WHMIS (Canada): Status: controlled product 

WHMIS Classifications: B2 - flammable liquid 

D2A - possible carcinogen 

Section 16: Other Information J 

HMIS 

2 

3 

1 

NFPA 

2 

3 

1 

HMIS and NFPA Hazard Rating: Cajfiflojy 

Acute Health 

Flammability 

Reactivity 

NFPA Unusual Hazards: None. 

HMIS Personal Protection: To be supplied by user depending upon use. 

Prepared by: Safety and Environmental Services Department, Alpha/Owens-Corning. L.L.C 

Revision Summary: This is an original MSDS prepared December 14, 1995. Read this informator 

carefully. 

N/A = Not Applicable N/D = Not Determined 
P .M 

of Wixoosa SOURCE DESCRIPTION - SUPPLEMENTAL 

•mam of Nuanl RWOUJWJ AIR POLLUTION CONTROL PERMIT APPLICATION 

Form 4530-102A 11-93 Infonnation attached? _ (y/n) 

of this form is required by the Department for any air polhtkai coi^ l pennit application filed pursuant to s. 144/392 or 

3925, Wis Stats. Completion of this form is mandatory;$Tl!e' Department will not consider cr act upon your application 

ss you complete and submit this form. It is not the Department's intention to use any personally identifiable information irein 

form for any other purpose. 

List all significant existing or proposed air pollution units, operations, and activities at the facility. A short narrative of the 

inventory of air pollution emissions unit (e.g., boiler, printing line, ete.) followed by equipment specifications will suffice. If 

the facility consists of several individual emission units, present this infonnation in an outline format. (See instruction 

booklet for an example Unit description.) f * /") / o -» , r^ 

/ - -J L-- - o Ql f Oot ivt Or 0V E" U HOtD S 

Q P I C 0 A T ; 

r5~ wJ TH E }V\A*JU r A nurs..r.>c or tJ.a o .^.JLOJ Th e .-if /vifpor ro fir A Qd'\Tio<-

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JJ2-
P.15 

i of Wisconsin 

aranent of Namral Resources 

= INSTRUCTIONS ON REVERSE SIDE 

EMISSION UNIT HAZARDOUS AIK POLLUTANT SUMMAKY 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-126 11-93 Infonnation attached? _ (y/n) 

Facility aame Cu ^ r , A f ,,_, A M M „ , l1(10 t " 

Sticlc^dientificatiofflinnbef:' ^ [) \ 

2. Fa]^ty|ic^tificffi 

4. gmj^ra^a^n^ffl(sa : - PQ ^ -

IJnitsm^nalld^rMjtiaK y ,, , t , n ,- , „ -<-

Complete the following summary of hazardous air emissions from this unit Attach sample calculations and emission 

factor references.- Attacheid? 

- PoUutant CAS ~ <• 

/OO-HZ-^T 

m s yi--/ 

—n O o*_ . o 

I <J ~ i —* j 

ry- D- 3 

! Q~)~ Ll i - S 

~?l-ri- i-<- | 

tfFS-£ FlCt*A.ft 

tt£ Hl/L p S^ f 

A* TH £nrnric»L 

r> x • r E n ITT CO 

•* Actual-cmissions- "*.' 

/3d.i ? 

I ) 1 • HX 

\ZHC 

I 8*. 01 

F

LO. on 

. S- 0 | 

no A;OT rt 

/•<— \ » 

H U LP [=.f 

A CT6C * (_ 

* TL 0* 

= Tb T^ L «o r 

/ cn . 

Units •• 

LQS 

c<2£ 

<-/3i 

L'35 

L O i 

i-'i i 

zp-mrBcr 

FuZo-^u 

Af 

f MK f 

i s 

P / v C->»i 

".Maxiinum-,fte*oreacal emissions? 

r^i^n 

j 002.- 7 s-

'io . ; i 

5 6-7 - .-L 

6 0 ."i | 

iS-o3 > 

£ FFlClG^tAr, 

t 

tiS% 

fi^rs-V 0-H 0*^ 1 

jl- A)/) ^ C ^ 

1/ 

Units 

^'35 

<- '"ii 

L >U 

• ISIS 

1

-'M 

(.6 5 

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-> W H / 

• I =^ *?,) 

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0 • 1 $r 

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i 

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TPY 

TPY 

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TPY 

TPY 

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TPY 

TPY 

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TPY 

TPY 

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TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

TPY 

MS 
P.16 

te of Wisconsin 

janment of Natural Resources 

PAINTING AND COATING OPERATIONS 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-108 11-93 Information attached? _ (y/n) 

£ INSTRUCTIONS ON REVERSE SIDE 

. Facility name: Cu5Tj , M fl?FlXQ.LM<> M;7, n , ^ 

S^feidentifi-cato o Q / . 

2. Facfli^;idenrification:number: 

4. ProceKjnumber: Pf)f 

a. Unit description: 

/5XHAu<,T <TA(ic U / l3i 0L)/?,\. . -

Indic-ateith£iOT[i'^^ B Uncontrolled • Controlled 

If the process is c»ntrolle^enterlthe|Conlrolidevic^nnmb^ 

4530-110. 

4530-114 

4530-111. 

4530-115 

4530-112. 

4530-116 

4530-113. 

4530-117 

Applii^prr'&xhmgue and transfer efficiency (%): HVLP 

Date.ofEconstructioh!

;

cfff.lastmbdificatibm / ot n %, 

NorniaI-<br«rarmg'achedule: Q hrs/day 

Oven curing (complete if applicable): 

Number bf ovens 

Total Maximum Energy input to each oven: 

.OL days/wk 

Specify oven 

LS%. 

fuels 

2

L

I days/yr 

0. Describe all of the coatings' and solvents' composition (as applied) that are used by this unit 

«*•.» - -tm 

ISL IrlK/fc 0>F.\ (fit. I Q.3k /OS" 35" lSl*- 3.g7 

) H ft - 1 /-'•<P>•""•,,„ Q-0Ql'r3 _L_L i20. &,<K £<£<? 

rotal coatings 

,ist the thinning solvents used with the coatings identified above. 

I 

^lean-up solvents 

^lean-up solvents 

)ther (specify) 

Ace roioz 

* 

:**** p o r jjjjj emissions unit, identify the method of compliance demonstration by completing Form 4530-118, ***** 

DESCRIPTION OF METHODS USED FOR DETERMINING COMPLIANCE. Attach Fonn 4530-118 

and its attachments) to this form. This is not a requirement of non-Part 70 sources. 

'  Please complete the Air Pollution Control Permit Application Forms 4530-126 and 4530-128 for this Unit ** *** 

mating categories (ct. eg. - column b. above) should be entered as follows: 1 - for air dried coatmgs; 2 - for clear coatings; 3 

r cured coatings; 4 - for extreme performance coatings; 5 - for other (specify) _ _ 

n4 
P.17 

ue of Wisconsin 

:pamnent of Namral Resources 

•E INSTRUCTIONS ON REVERSE SIDE 

Facility name: 

Uiro-^ F.P.r'\-Cij>,(( Mo to i>M c. 

STACK IDENTIFICATION 

AIR POLLUTION CONTROL PERMIT APPUCATION 

Form 4530-103 11-93 Information attached? _ (y/n) 

I. -MKausiSil0e$papm 

1530-104 4530-106 4530-107 4530-108 4530-109 

Identify this stack on the plot plan required on Form 4530-101 

Indicate 

[e-uw^r^ 

This stack has an actual exhaust point. • This stack serves to identify fugitive emissions. 

Ifithis;Stad£rh^:an5actoaljexhanst;poinfe 

• 

• 

1 

1. 

2. 

}. 

Diraarggil^^jabovefgrotmajfeveb £'0rttfeet) 

•••:««•.•« M-.^A . .VT"W. •vS»»>J«i-.*' -.-.**»rt^«***;>.-: •*». •*•*.-•:-- v/*..v.v>!«**» ' *;«•» •••J^*-*.*.*.*.*.***^" * * 

Inside dimensiomiat outlet(chwk-onefaoatcomp 

fl Circular SL (feet) • rectangular length (feet) 

AH-'1** '**VW^'*W^,*«WW«««Wf( 

3whausj^ow|ratej 

NonEffi^^il^pCEKO Maximum 0^39. 99(ACFM) 

Exwuistigas|ttmperarures(normal): IS. (°F) 

Exhaust gas moisture content: Normal volume percent 

Exhaust ga^iscfialje^rectijpi D Up • Down 

• -y **#«»W »**«"*?' ** -» »

vw*w*w>y*-»»»t « _ ^ vt i v * <v_ •:y*;-xw'*y-w-*»''r**>>*»»»gs^a,

**r'^^ );^:*."W>Vf*>W*-*,M'iw-ylIMw^rjajt-;*,-v>y 

is this stai^jequippwiwith.a ra^a^|ag^^^-^g^to|u^^^|0|W^^e 

exhaust gases^fronTthe "stack? iO., . , p, . ,_„.,, „, _ 

width (feet) 

Maximum volume percent 

9 Horizontal 

S Yes D No 

»*** Complete the appropriate Air Permit Application Forms(s) 4530-104. 106, 107, 108 or 109 for each Unit ***** 

exhausting through this stack. 

/>6~ 
P.18 

ORGANIC PEROXIDES 

Material Safety Data Sheet 

Elf Atochem Code: 124 

TRADENAME LUPERSOL DHD-9 

CHEMICAL NAME Methyl Ethyl Ketone Peroxide 

MOLECULAR FORMULA Mixture of C4H10O4 

end C-aHigOfl 

Revision Date: 0,712/95 

Supersedes Form Dated: 36/13/95 

CHEMICAL FAMILY Organii; Peroxide 

SYNOMYNS 2-6utanor>! Peroxide 

HA2AR00US INGREDIENTS 

Hazard Data 

ACGIH STEL = Cl.:!: ppm (Cel I ing) 

OSHA TLV = :!!> -jp« (CeilIns) 

OSHA PEl/TUit • 5 ir-a/BV 

OSHA PEL/TWA « 200 ppm 

OSHA PEL/TWi*. • 1 ppn 

*This product contains toxic chemicals subject to the reporting requirements of section 313 of the Erergcrcy Pleming and 

Comunity Right-To-Know Act of 1986 and of 40 CFR 372. 

This product is listed on the U. S. EPA, TSCA Inventory. As of the date on uhich this MSOS uas prepared, those chemicals are 

not listed under California Proposition 65 and are not classified as carcinogenic by IARC, NTP, or OSHA. 

SHIPPING INFORMATION 

Materials or Components 

Methyl ethyl ketone peroxide structures 

accotnt for A.7 - 9.OX active oxygen 

Hexylene glycol 

Dimethyl phthalate* 

Methyl ethyl Icetone* 

Hydrogen peroxide 

ftQ- I••*>?• 

10 

5000 

5000 

S_»/H 

33.3 

6.0 

56.2 

1.0 

1.5 

CAS Uo. 

1JJ8-Z3-4 

107-41-5 

131-11-3 

78-93-3 

7722-84-1 

D.O.T. SHIPPING NAME Organic Peroxide Type D, Liquid 

(Methyl ethyl ketone peroxide(s) S45X) 

HAZARD CLASSIFICATION 5.2 

I.D. NUMBER UH3105 

FREIGHT CLASSIFICATION Chemists N0IBN 

IMOG CODE PAGE 5225 

PHYSICAL PROPERTIES 

MELTING/FREEZING POINT, *C Below -20 

HOLECULAR WEIGHT H/A 

SPECIFIC CRAVITT (HjO « 1), 25/25°C 1.O840 Min. 

•S.A.D.T 60T, 40# Ciix 

•Self accelerating Deccnposition Temperature 

VAPOR PRESSURE N/E 

VAPOR DENSITY (Air = 1) M/E 

X VOLATILES BY VOLUME N/E 

APPEARANCE & ODOR Clear liquid, ketone odor 

SOLUBILITY IN H~p Insoluble 

FIRE AHD EXPLOSION OATA 

FLASH POINT, "C/'F 

EXTINGUISHING MEDIA 

SPECIAL FIRE FIGHTING PROCEDURES. 

UWUSUAL FIRE i EXPLOSION HAZARDS. 

.66/151 

Uater Fog, Dry Chemical, Foam, Water Spray 

If large aaount is involved, evacuate aria snd fight fir* 

fron aafe distance. Cool surrowJing naterial with uater. 

Contamination, Teaperature - Can decompose uith force if 

confined during exposure to fire . 

REACTIVITY DATA 

STABILITY Unstable 

CONDITIONS CONTRIBUTING TO INSTABILITY Then«l deco«t»sition, contamination 

INCOMPATIBILITY (avoid contact with) Strong acids, strong alkali**, strong oxicinirs , acetone, 

transition metal salts , promoters and recic ng agents 

HAZARDOUS DECOMPOSITION PROOUCTS Decomposition products are flomnrable and nia- autoignite 

CONDITIONS TO AVOID Keat, flames, sparks, ignition sources, cc*v:amination 

Page 1 of 3 

elf atochem 

AIO 

Ell Atochem North America. Inc. • Fine Chemicals Group • Organic Peroxides • 2000 Market Street • Philadelphia, P/* i?103 3222 

Phone: (800) 558-5575 • Fax: (215) 419-7413 • 24 Hr. Emergency No: Chemtrec (800) 424-9300 
P.19 

MATERIAL SAFETY SHEET 

LUPERSOL DHD-9 

SPILL OR LEAK 

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Use absorbent material, sueep or scoop cp Uiir-9 non-sparking 

tools and dispose of imnediately. 

WASTE DISPOSAL METHOO Consult uith an Elf Atochea representative foe the telephone 

number of your state's hazardous waste eg-mcy. 

TOXICITY 

TOXICOLOGICAL INFORMATION - Methvl Ethvl Ketone Peroxide 

Data from the scientific literature on nethyl ethyl ketone peroxide (MEKP) are summarized below. 

Single exposura (acute) studies on 40-60X MEKP in dimethyl phthalate indicate: 

Oral • Moderately toxic to rets (LD*jn484 ng/kg) 

Oernal - Slightly toxic to rabbits (L0M 4,000 mg/kg) 

Inhalation - Practically non-toxic to rats (4-hr LC5017-50 ng/L) 

Eye Irritation - Corrosive to rabbits 

Skin Irritation - Moderately Irritating to rabbits (4-hr exposure, 4.5/9.0) 

Repeated oral adWni strati on or intraperitoneal injection < 7-weeks) of MEKP (97 mg/kg/day) was reported to reiul t in decreased 

body weight, Bt Id liver Injury and death fn rats. Following repeated skin application (15-weeks) of MEKP in diwthyl phthalati 

at doses ip to 107 •g/rat/day and 35.7 ag/mouse/day, severe skin damage and aniatal deaths (only at the highest doie levels) were 

the primary effects in rats and mice. Spleen end bone Marrow changes, considered secondary to the severe skin ct-mige, were noted 

in animals at the high doses. Higher doses (tp to 810 and 1-BO0 ng/kg/day in rats and nice, respectively) allied to rat and 

mouse skin for a shorter time (2-weeks) produced siailar effects. Long-tern repeated skin application (25-i«:eks) of MEKP In 

dimethyl phthalate was reported to enhance skin tumor production in nice irradiated with UVB. MEKP has produced tenet ic changes 

in standard tests using bacterial or animal cells. However, no genetic changes occurred in a standard H.'s: (bone marrow 

micronucleus) using nice frcn the 13-week skin application stud/. 

ECOLOGICAL INFORMATION • Methvl Ethvl Ketone Peroxide 

Ecotoxicological Information: 

96-hr LCsoguppy: 44.2 mg/L, slightly toxic 

Chemical fate information: 

Methyl ethyl ketone peroxide (MEKP) was evaluated for biodegradability In a closed bottle systea and vas reported to 

be readily biodegradable. An ECsoof 16 mg MEKP/L activated sludge wes reported in an activated slucige respiration 

inhibition test. 

HEALTH HAZARD INFORMATION 

POTENTIAL HEALTH EFFECTS • Methvl Ethyl Ketone Peroxide 

Skin contact and inhalation are expected to be the primary routes of occupational exposure to methyl ethyl ketone peroxide 

(KEKP). MEKP can be destructive to tissue, producing burns on contact with any body tissues. Contact with lhe eyes can cause 

severe Irritation and injury, possibly with loss of sight. While swallowing of MEKP is unlikely, if swallowed I'hts material can 

cause severe irritation and injury to the mouth, throat, stonach and liver, liver failure and respiratory distress; death aay 

follow. Overexposure to MEKP vapors may cause eye and respiratory tract irritation, with headache and dlzzine*:*. Allergic skin 

response is rare, but has been reported for MEKP. This material is considered, on the basis of single exposure (acute) animal 

tests, to be moderately toxic after ingestion. 

EMERGENCY FIRST AlDl 

INGESTION Do HOT induce vomiting. Get emergency medical attention for gavage. 

DERMAL flusiTwith soap and water. Get medical attention. 

EYE CONTACT IMMEDIATELY flush with plenty of water for at least 15 minutes. Get nwiical attention. 

INHALATION Remove to frash air. If not breathing, give artificial respiration. Get lasdieel attention. 

SPECIAL PROTECTION INFORMATION 

VENTILATION REQUIREMENTS... Use with adequate ventilation. Local exhaust. 

EYE Safety glasses, goggles, face shield. 

HAND (Glove Type) Neoprene, nitrile rtiaber. 

•RESPIRATOR TYPE Stpplled air respirator with full face piece, hood or helmet. 

OTHER PROTECTIVE EQUIPMENT. Eyewash a tat ion. 

•Use only NIOSH/MSKA approved equipment 

Page 2 of 3 

/ '.J 
P.20 

ORGANIC PEROXIDES 

Material Safety Data Sheet 

MATERIAL SAFETY SHEET 

LUPERSOL DH0-9 

LABEL PRECAUTIONS 

PIE-CAUTIONARY LABELING. 

OTHER STORAGE ANO 

HANDLING CONDITIONS. 

Wash thoroughly after handling 

Do not get in eyes, on akin or clothing 

Do not store near combustibles 

Empty container aay contain hazardous residues 

Keep container closed 

Keep away frcm heat, sparks, and fl i 

Oo not reuse container 

Store below 100*F (3-8'C) to maintain active oxygen content 

PREPARED BY: 

Organic Peroxides Regulatory 

ADDRESS: 

2000 Market Street, Pttlta., PA 1910S 

PHONE: 

1-B00-55S-:575 

NOTES: N/E • Not Established 

N/A » Hot Applicable 

Elf Atochem North America, Inc. believes that tha Infonaation and recoaamndations contained herein (inrliding data and 

statements) are accurate as of the date hereof. MO UARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, UARRANTY OF ^MERCHANTABILITY, 

OR ANY OTHER UARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information jfovlded herein 

relates only to the apecific product designated and may not be valid where audi product is used in ccafeinaton with any other 

materials or in any process. Further, aince the conditions and methods of uae of the product and of the inf creation referred 

to herein are beyond the control of Elf Atocham, Elf Atochem expreea I y disc la iaa any and all liability •• to -trt, n-sultt obtained 

or arising from any use of the product or reliance on such inforamtlon. 

7/12/95 O ) 

Page 3 of J 

elF atochem 

ZKIO 

EH Atochem North America, inc. • Fine Chemicals Group • Organic Peroxides • 2000 Market Street - Philadelphia, PA 19103-3222 

Phone: (800) 558-5575 • Fax: (215) 419-7413 • 24 Hr. Emergency No: Chermrec (800) 424-9300 
P.21 

1/01-777 

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