**Freeport McMoran Inc., Miami Smelter stack parameters** from Google Earth, approx. at 110.857W, 33.413N formerly Phelps Dodge sjb 2013-08-23; updated 12-10
**WRAP stack parameters and emissions from web site CALPUFF input file (e.g. src06_az_010101.inp)**

source, per FMMI letter Source # SRCNAM X Coordinate (km) Y Coordinate

(km) Stack Height

(m) Tail Gas Stack 1AZ15 -1280.01 -631.582 60.96 Vent Fume Stack 2AZ16 -1280.01 -631.582 76.2 Rod Plant Shaft Furnace 3AZ17 -1280.01 -631.582 19.51 Roofline Fugitives 4AZ19 -1280.01 -631.582 10 Roofline Fugitives 5AZ20 -1280.01 -631.582 10 In CALPOST, PM25 was treated as PMF, cf. fine soil; no PM10 or PMC
**WRAP stack parameters and emissions from spreadsheet az_emis_May31_2007.xls**

source, per FMMI letter SRC Pn LCC X (km) LCC Y

(km) Stack

height(m)

Tail Gas Stack src06 AZ15 -1280.052-631.4428 60.960 Vent Fume Stack src06 AZ16 -1280.052-631.4428 76.200 Rod Plant Shaft Furnace src06 AZ17 -1280.052-631.4428 19.507 Roofline Fugitives src06 AZ19 -1272.413-632.6131Fugitive Emission Roofline Fugitives src06 AZ20 -1280.052-631.4428Fugitive Emission 7.638798AZ19 is over 7 km from the others; but this was not used in actual modeling, per above

**ADEQ SIP emissions** Listed here to help with correspondence of source codes and names

**emissions (SIP, p.153, pdf.165)**

Emissions Unit SO2 emissions (lb/hr) PM

emissions (lb/hr) SO2 g/s PM g/s Acid Plant Tailgas Stack (Converters 1-5) 820 20.4 103.318 2.570 Vent Fume Stack (Electric Furnace Stack) 312 56.3 39.311 7.094 Shaft Furnace Stack 0.03 4.11 0.004 0.518 Smelter Fugitives 1288 48.55 162.285 6.117 Rod Plant Fugitives 0 0.1 0.000 0.013 Emissions about the same as from WRAP spreadsheet and CALPUFF input file SIP says that in July 17, 2007 letter, PDMI disputed the stack parameters that ADEQ had provided to WRAP; but no correction listed PDMI also stated that Rod Plant Shaft Furnace across the highway is not part of source subject to BART

**FMMI letter to EPA, July 22, 2013 (EPA Data Request with cover letter final.pdf), Item 7**

**10.11 – ADEQ Modeled Emissions from FMMI**

Sources Identified in the Summary of WRAP RMC BART Modeling for Arizona dated May 25, 2007Source Ty pe easting northing elevation (m) Stack

height(m)

AZ15 Tail Gas Stack point 513,301 3,697,182 1096 60.96 AZ16 Vent Fume Stack point 513,301 3,697,182 1096 76.20 AZ17 Rod Plant Shaft Furnace point 513,301 3,697,182 1096 19.51 AZ19 Roofline Fugitives fugitive 521,049 3,697,195 1096 Fugitive AZ20 Roofline Fugitives fugitive 513,301 3,697,182 1096 Fugitive

Source Ty pe easting northing elevation (m) Stack

height(m)
(AZ15) Tail Gas Stack point 513,195 3,697,246 1085 65.00 (AZ16) Vent Fume Stack point 513,355 3,696,918 1095 65.00

Aisle Scrubber Stack point 513,356 3,697,103 1081 65.00 AZ19 Roofline Monitor (Converter) buoyant 513,224 3,697,128 1085 31.18 line 513,278 3,697,105 AZ20 Roofline Monitor (ELF) buoyant 513,261 3,697,066 1085 52.43 line 513,271 3,697,087 UTM coordinates are all for UTM Zone 12, with NAD83 datum

Roof Converter center 513251 3697117 Roof ELF center 513269.5 3697086

**Convert UTM to LCC by using Tail Gas Stack as center, apply other units' east & north offset from it**

Offset of Tail Gas Stack from previous coords Original WRAP AZ15, LCC km Tail gas FMM minus WRAP,m -106 64 Tail Gas Stack
Offset from Tail Gas Stack, updated coords, m **Updated coords, LCC km** main Tail Gas Stack 0 0 Tail Gas Stack

Vent Fume Stack 160 -328 Vent Fume Stack Aisle Scrubber Stack 161 -143 Aisle Scrubber Stack roof_convrtr

Roof Converter 1 29 -118 Roof Converter 1 Roof Converter 2 83 -141 Roof Converter 2 roof_ELFRoof ELF 1 66 -180 Roof ELF 1

Roof ELF 2 76 -159 Roof ELF 2

roof_convrtr

Roof Converter center 56 -130 Roof Converter roof_ELFRoof ELF center 75 -161 Roof ELF

**FIP proposal stack parameters** UTM coordinates (m) UTM coordinates (m)

Updates to Source Parameters & New Emission SourcesPoint sources

Source # SRCNAM X Coordinate (km) Y Coordinate

(km) Stack Height

(m) Base

Elevation (m) Stack Diameter

(m) 1 main -1280.116 -631.518 65.00 1085 2.111 2 vent_stack -1279.956 -631.846 65.00 1095 3.048
Buoyant Line sources Notes

building length XL 41.0meters Average of FMMI's lengths building height HBL 41.81meters Average of FMMI's heights building width WBL 25.0meters Est. from photo line source width WML 4.0meters Average of FMMI's widths separation between buildings DXL 50meters Est. from photo buoyancy parameter FPRIMEL 1371.6m4/s3 Calc. from velocity, dimensions, temperature

Source # SRCNAM Beg. X Coordinate (km) Beg. Y

Coordinate (km) End. X

Coordinate (km) End. Y

Coordinate (km) Release Height

(m) 1 roof_convrtr -1280.087 -631.636 -1280.03 -631.659 31.18 2 roof_ELF -1280.05 -631.698 -1280.04 -631.677 52.43

Alternative, with roof monitor fugitives modeled as point sources

Source # SRCNAM X Coordinate (km) Y Coordinate

(km) Stack Height

(m) Base

Elevation (m) Stack Diameter

(m) 1 main -1280.116 -631.518 65.00 1085 2.111 2 roof_conv_pt -1280.060 -631.648 31.18 1085 17.29 3 roof_ELF_pt -1280.042 -631.679 52.43 1085 10.88from Google Earth, approx. at 110.857W, 33.413N lbhr_per_gs sjb 2013-08-23; updated 12-10
**WRAP stack parameters and emissions from web site CALPUFF input file (e.g. src06_az_010101.inp)**

Base Elevation (m) Stack

Diameter (m)Exit Vel.

(m/s) Exit Temp.

(deg. K) Bldg. DwashSO2 SO4 NOX HNO3 1095.76 1.83 24.08 323.15 0 103.32 0 0 0 1095.76 6.71 3.93 309.26 0 39.31 0 0 0 1095.76 1.77 7.68 644.26 0 0 0 0.85 0 1095.76 10 0.1 295 0 162.29 0 3.15 0 1095.76 10 0.1 295 0 0 0 0.58 0 In CALPOST, PM25 was treated as PMF, cf. fine soil; no PM10 or PMC

Elevation (m) Stack

diameter(m ) Exit velocity(m/ s) Exit temperatu re (K) SO2 Rate

(g/s) NOX Rate

(g/s) PM25

Rate (g/s)SO2 Rate

(lb/hr) NOX Rate

(lb/hr)
1095.756 1.829 24.079 323.150 103.320 0.000 2.570 820.01 0.00 1095.756 6.706 3.932 309.261 39.312 0.000 5.834 312.01 0.00 1095.756 1.768 7.681 644.261 0.004 0.847 0.518 0.03 6.72 1095.756Fugitive Emission Fugitive Emission

Ambient 162.288 3.149 6.117 1288.02 24.99 1095.756Fugitive Emission Fugitive Emission

Ambient 0.000 0.576 0.001 0.00 4.57 AZ19 is over 7 km from the others; but this was not used in actual modeling, per above
Listed here to help with correspondence of source codes and names appendix D "Arizona BART – Supplemental Information", Table 13.1 p.93 pdf.95

SIP says that in July 17, 2007 letter, PDMI disputed the stack parameters that ADEQ had provided to WRAP; but no correction listed PDMI also stated that Rod Plant Shaft Furnace across the highway is not part of source subject to BART

Sources Identified in the Summary of WRAP RMC BART Modeling for Arizona dated May 25, 2007 Acid plant tail gas system Copper converter capture system Natural gas and steam injection **Table 13.1 – Current Air Pollution Control Equipment and Emission Limits for Equipment Subject-to-BART at** 

**the FMMI Smelter**

Current Control

Hoboken Converters Remelt/Mold Pouring Acid plant tail gas system
Wet scrubber and wet electrostatic precipitatorEmissions Units Subjectto-BART Electric Furnace (Process Gases) Electric Furnace (Captured Fugitive Emissions) Hoboken ConvertersStack

diameter(m) Exit

temperature (K) Exit

velocity (m/s) 1.83 323.2 24.08 6.71 309.3 3.932 1.77 644.3 7.681 Fugitive Ambient Fugitivefugitive src. sep. Fugitive Ambient Fugitive -7,748 -13 7.7 km separation... ! Line source buoyancy parameter from BLP user guide, p.2-7, pdf.55 F' = g*L*Wm*w*(Ts - Ta)/Ts Stack diameter(m) Exit

temperature (K) Exit

velocity (m/s) 2.111 297.2 20.00 assume T_ambient: 295 3.048 ambient 18.50 9.202 ambient 10.00 L, length Wm, width(Ts-Ta)/Ts 58.69 x 4 ambient+17 16.60 58.69 40.054487 fugitive src. sep. 23.26 x 4 316 10.16 37 -62 23.26 40.071186 -7 -18 XL WML 41.0 4.0

HBL41.8

**Convert UTM to LCC by using Tail Gas Stack as center, apply other units' east & north offset from it** Original WRAP AZ15, LCC km Tail Gas Stack -1280.01 -631.582
**Updated coords, LCC km** easting northing Tail Gas Stack -1280.116 -631.518 Vent Fume Stack -1279.956 -631.846 Aisle Scrubber Stack -1279.955 -631.661 Roof Converter 1 -1280.087 -631.636XBEGL YBEGL Roof Converter 2 -1280.033 -631.659XENDL YENDL -1280.05 -631.698XBEGL YBEGL -1280.04 -631.677XENDL YENDL

Roof Converter -1280.060 -631.648 -1280.042 -631.679 Dimensions Dimensions

F' = g*L*Wm*w*(Ts - Ta)/TsExit Vel. (m/s) Exit Temp. (deg. K) Notes 20.00 297.2 From FMMI 18.50 295 From FMMI; ambient modeled as 295

Calc. from velocity, dimensions, temperature

Base Elevation (m) Notes 1085 From FMMI 1085 From FMMI

Exit Vel. (m/s) Exit Temp.

(deg. K) Notes 20.00 297.2 From FMMI 16.60 312 From FMMI; diam. of circle area = L*W 10.16 316 From FMMI; diam. of circle area = L*W Ambient T assumed to be 295 K7.936648

NO3 PM25 0 2.57 0 5.83 0 0.52 0 6.12 0 0

PM25 Rate (lb/hr) 20.40 46.30 4.11 48.55 0.01from BLP user guide, p.2-7, pdf.55 F' = g*L*Wm*w*(Ts - Ta)/Ts

w = exit velocity

Building F' length width 2083.2 25

660.1 25 FPRIMEL XL WBL 1371.6 25.0