## June 25. 2008 Office ofPollution Prevention and Toxics (7407) U.S. Environmental Protection Agency EPA East. Room

**64~8** 

## 1200 Pennsylvania Ave
.. NW Washington, DC 20460 Subject: SignificantNew Use Notice Dear Sirs/Madams, p. 1 

# S-o<&-/

The attached is a SignificantNewUse Notice (SNUN) that is being submitted in accordance with the requirements ofthe SignificantNew Use Rule for the substance regulated at 40 CFR 721.5185. That substance is 2-Propen-1-one, 1-(4-morpho1inyl)- CASRN 5117-12-4 It

## is ourunderstanding from discussions with the Agency's Ms. Tracy Pennington that the Agency is preparing to publish a Federal Register (FR) Notice that would align the published SNUR with the underlying Modified Consent Order (MCO). The purpose ofthis SNUN is to seek the reduced regulatory requirements ofthe MCO priorto the pending FR publicationofthe SNUR modification as the date ofthis FRNotice publication is uncertain. The SNUN substance will be used by as a monomer used to manufacture a new polymer that is the subject of a concurrently submitted Premanufacture Notice (Pl\tfN) (see TSCA User Fee TS-08JB1W). An additional purpose of this SNUN is to extend having to comply with the MCO requirements to customers ofthe new polymer which will contain several hundred parts per million ofthe unreacted SNUN substance. The SNUN substance was originally Pl\1N'd by and the MCO was subsequently assigned to kttcrofauthorization from Sincerely. . (Sec and 40 CFR 721.5185 and attached

### U.S. ENVIRONMENTAL PROTECTION AGENCY 

# PREMANUFACTURE NOTICE**~CES** 

## I 

# IIIIi:1:111i/!ii 

## 11!1:fli!ill:;i 

# W II'!

# II,;II!:II 

# II J:l II,**431Jt'UUll1.10tJ~** nter the total numoer or pages in the Premanufacture Notice 

# ... GENERAL INSTRUCTIONS
• You mustprovide all information requested in this form to the extent that it is known to or reasonably ascertainable by you. Make reasonable estimates ifyou do not have actual data. • Before you complete this form, you should readthe "Instructions Manual for Premanufacture Notification" (the Instructions Manual is available from the Toxic Substances Control Act(TSCA) Information Service by calling 202-554-1404, or faxing 202-554-5603). Ifa user fee has been remitted for this notice (40 CFR 700.45), indicate in the boxes above the TS-user fee identification numberyou have generated. Remember, your user fee ID number must also appearon yourcorresponding fee remittance, which is sent to EPA. HQ AccountingOperations Branch (PM-226), P.O. 360399M. Pittsburgh, PA 15251-6399,Attn. TSCA User fee.
Part I-GENERAL INFORMATION You must provide the currently correct Chemical Abstracts (CA) Name ofthe new chemical substance, even ifyou claim the identity as confidential. You may authorize another person to submit chemical identity information for you, but your submission will not be complete and the review will not begin until EPA receives this information. A letter in support ofyour submission should reference yourTS user fee identification number. You must submit an original and two copies ofthis notice including all test data. Ifyou claimed any information as confidential, a single sanitized copy must also be submitted.
Part II- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Ifthere are several manufacture, processing, oruse operations to be described in Part II, sections A and B ofthis notice, reproduce the sections as needed.
Part Ill-LIST OF ATTACHMENTS Attach additional sheets ifthere is not enough space to answer a question fully. Label each continuation sheet with the corresponding section heading. In Part Ill, list these attachments, any test data or otherdata and any optional information included in the notice.

OPTIONAL INFORMATION You may include any information that you want EPAto consider in evaluating the new substance. On page II ofthis form, space has been provided for you to described pollution prevention and recycling information you may have regarding the new substance. So-called
..binding
.. boxes are included throughout this form for you to indicate your willingness to be bound to certain statements you make in this section, such as use, production volume, protective equipment
. This option is intended to reduce delays that routinely accompany the development ofconsent orders or Significant New Use Rules. Except in the case ofexemption applications (such as TMEA, LVE, LOREX) where certain information provided in such notification is binding on the submitter when the Agency approves the excmptton applicatiOn, checkmg a bmdmg box m thiS nottce does not by itselfprohibit the submitter from later deviating from the infonnation (except chemical identity) reported in the form.
CONFIDENTIALITY CLAIMS You mav claim anv information in this notice as confidential. To assert a claim on the form,**m~k** (X)**th~** confidential box next to the information that 10u claim as confidential. To assert a claim in an attachment, ctrcle or brackei the information 10u claim as confidential. lfvou claim infonnation in the nottces as confidential you ;nust abo prO\ide a 'anitized version ofthe mitice ltncluding attachments). For addtttonal mstructions on claiming mfonnation as confidential. read the Instntctions Manual. 

# D Mark 1 x) 1fany mfonnatton in this nottee 1s claimed as confidential. EPA FORM 7710-25 (Rev 5-95) TEST DATA AND OTHER DATA You are required to submitall test data in yourpossession orcontrol and to provide a description ofall otherdata known to or reasonably ascertainable byyou, ifthese data are related tothe health and environmental effects on the manufacture, processing, distribution in commerce. use, ordisposal ofthe newchemical substance. Standard literature citations may be submitted for data in the open scientific literature. Complete testdata (written in English) not summaries ofdata mustbe submitted ifthey do not apoear in the ooen literature. You should clearly identifY whethertestdata is on the substance oron an analog. Also. thechemical composition ofthe tested material should be characterized. Following are examples oftestdata and otherdata. Data should be submitted according to the requirements of§720.50 ofthe Premanufacture Notification Rule (40 CFR Part 720)

Test Data (Check Below any included in this notice) Environmental fate data Health effects data Environmental effects data PhysicaUChemical Properties• 

### 0 Yes 

### 0 Yes 

### 0 Yes 

### 0 Yes Other data 

### 0 Yes Risk assessments Structure/activity relationships Test data not in the possession or control ofthe submitter A physical and chemical properties worksheet is located on the last page ofthis form. TYPE OF NOTICE (Check Only One) 

# 0 0**~** 

# 0 PlviN (Premanufacture Notice) r-·**~;** c..,.__, INTERMEDIATE PMN (submitted in sequence with'final product PMN) SNUN (Significant Ne\\ Use Notice) TMEA (Test Marketing Exemption Application) 

# 0 LYE tLow Volume

### Exemption):~·**~0** CFR 71J.50(Cl(:l)l 

# 0 LOREX (Lo\\ Release/Low Exposure Exemption) 

## i,']l CFR 723.50(C)\2) 

# 0 LVE Modification IS THIS A CONSOLIDATED PMN? " ofchemicals 

# 0 0 LOREX Modtficatton Yes**~** (Prcnot1ce Communtcation ::: req111rcd. enter :: on page .l) Replaces previous editions ofEPA Form 77I0-25.

# 3!~6oG

### p.3 Public reporting burden for this collection ofinformation is estimated to average II0 hours per response, including time for reviewing instructions, searching existing data sources. gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding the burden estimate orany other aspect ofthis collection ofinformation. including suggestions for reducing this burden, to Chief, Information Policy Branch, PM-223. U.S. Environmental ProtectionAgency, 401 M. St., S.W., Washington, D.C. 20460; and to the Office ofManagement and Budget, Paperwork Reduction Act (2070-0012). Washington. D.C. 20503. 

## CERTIFICATION I certifythat to the best ofmy knowledge and belief: 1. The company named in Part I, section A, subsection I a ofthis notice form intends to manufacture or import for a commercial purpose, otherthan in small quantities solely for research and development, the substance identified in Part I, Section B. 

### 2. All information provided in this notice is complete and truthful as ofthe date ofsubmission. 3. I am submitting with this notice all test data in my possession orcontrol and a description ofall otherdata known to or reasonably ascertainable by me as required by §720.50 ofthe Premanufacture Notification Rule. Additional Certification Statements: Ifyou are submittinga PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following user fee certification statementthat applies: 

## [8:1 The Company named in Part I, Section A has remitted the fee of$2500 specified in 40 CFR 700.45(b), or 

# D The Company named in Part I, Section A has remitted the fee of$1000 for an Intermediate PMN (defined @ 40 CFR 700.43) in accordance with 40 CFR 700.45(b), or 

# D The Company named in Part I Section A is a small business concern under40 CFR 700.43 and has remitted a fee of$100 in accordance with 40 CFR 700.45(b). Ifyou are submitting a low volume exemption (LVE) application in accordance with 40 CFR723.50(c)(l) ora Low release and low exposureexemption (LoRex) application in accordance with 40 CFR723.50(c)(2), check the following certification statements: 

# D The manufacturer submittingthis notice intends to manufacture or importthe new chemical substance for commercial purposes, otherthan in small quantities solely for research and development, underthe terms of40 CFR 723.50. 

# D The manufacturer is familiar with the terms ofthis section and will comply with those terms; and 

# D The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

# D Ifthis application is for an LYE in accordance with 40 CFR 723.50(c)(l), the manufacturer intends to commence manufacture ofthe exempted substance for commercial purposes within 1year ofthe date ofthe expiration ofthe 30 day review period. The accuracy ofthe statements you make in this notice should reOect your best prediction ofthe anticipated facts regarding the chemical substance described herein. Any knowinl! and willful misinterpretation is subiect to criminal Penaltv pursuantto 18

### t;sc 1001. Signature and title ofAuthorized Official (Original Signature Requrred) Date
Signature ofagent · (ifapplicable) Date

EPA FORM 7710-25 (R.:v. 5-95) Pag.: 2 Confidential 

### XIa. Person Submitting Notice (in U.S.)

b. Agent (if applicable) 

### p.4

Company

City, State, Code

Mailing address (number and street)
Code

c. Ifyou are submitting this notice as part ofajoint submission, mark (X) this box.

# ----------------------+ Joint Submitter (if applicable) Name official

4.

5.
6. Contact (in U.S.) Company
address (number and street) City, State, ZIP Code

Company Mailing City, State, ZIPCode

you (PC) concerning this notice and EPA assigned a PC Numberto the notice, enter the number.

you the chcrmcal substance covered by this notice. enter the exemption number assigned by EPA. Ifyou previously submitted a PMN for this substance enter the PMN number assigned by EPA (i.e. withdra\\n or incomplclctctc+).---+ Ifyou for the ass1 Type ofNotice- Mark (X) I. X SNl!N- Processing 

# D Binding Option Mark (X)
EPA FORM 7710-25 (Rev 5-95) 2. 

# D

Page 3 Import Only Mark (X) ifnone Mark (X) ifnone Mark tX)
Binding Option Mark 1 

# D

3. 

# D Both 

### X

### p.5

name ofthe substance based on conventions.

Ifanother person will submitchemical identity information for you (for either Item I or 2), mark (X) the box attheright. and address ofthat in a continuation sheet. 1. Class I or 2 chemical substances (for definitions ofclass 1 and class 2 substances, see the Instructions Manual) a. Class ofsubstance

- Mark (X) I 

# D Class I or 2 

# D Class 2 b. Chemical name (Currently correct Chemical Abstracts (CA) Name that is consistent with TSCA Inventory listings for similar substances. For Class I substances a CAIndexName mustbe provided. ForClass 2 substances either a CA Index Name orCAPreferred Name must be provided, which ever is appropriate based on CA9CI nomenclature rules and conventions). 

### 2-Propen-1-one, 1-(4-morpholinyl)-

c. 

# D information reported in this notice: (check one). 

## [gl Method 2 (Other Source)



### 5117-12-4

e. For a I substance, a complete correct chemical structure diagram. For a class 2 substance- (I)List then·nm.ema1e precursor substances with their respective CAS Registry Numbers. (2) Describe the nature ofthe reaction orprocess. (3) Indicate the range ofcomposition and the typical composition (where appropriate). (4) Provide a correctrepresentative orpartial chemical structure diagram. as comolete as can be known. ifone can bereasonablv ascertained.

Mark (X) this box attach a continuation sheet.
EPA FORM 7710-25 (Rev. 5-95) Page 4 

### X

X

## p.G

Confidential a. Indicate the number-average weight ofthe lowest molecular weight composition ofthe polymer you intend to manufacture. Indicate maximum weight percent oflow molecular weight species (not including residual monomers, reactants, or solvents) below 500 and below 1,000 absolute molecularweight ofthat composition. Describe the methods ofmeasurement orthe basis for your estimates: GPC 

# D Other 

# 0: (SpecifY) i) lowest number average molecularweight: ii) maximum weight%below 500 molecular weight: iii) maximum weight%below 1000 molecular weight:
You must make separate confidentiality monomeror residual information. Mark (X) the ''Confidential" box next to any item you claim as confidential (I) Provide the specific chemical name and CAS Registry Number (ifa number exists) ofeach monomerorother reactant used in the manufacture of the polymer. (2) Mark (X) this column ifentry in column (I) is confidential. (3) Indicate the typical weight percent ofeach monomer or other reactant in the polymer. (4) Mark (X) the identity column ifyou want a monomer orother reactant used at two weight percent or less to be listed as part ofthepolymer description on the TSCA Chemical Substance Inventory. (5) Mark (X) this column ifentries in columns (3) and (4) are confidential. (6) Indicate the maximum weight percentofeach monomer orother reactant that may be present as a residual in the polymer as manufactured for commercial purposes. this

% % % % 

## •;. %

c. Please identifY which method you used to develop orobtain the specified chemical identity information reported in this 

# D Method I (CAS Inventory Expert Service- a copy ofthe identification report 

## [8J Method 2 (other source) obtained from CAS Inventory Expert Servicemustbe submitted as as attachment to this

correct TSCA Inventory listings for similar polymers.

e. Provide a correct representative or partial chemical structure diagram. as complete as can

Mark (X)this box i attach a continutation sheet. 

## Pa EPA FORM 7710-25 (Rev. 5-95)

### p. 

### 7 Section 8- CHEMICAL IDENTITY INFORMATION3. Impurities (a) IdentitY each impurity that may be reasonably anticipallxl to he pR-sent in the chemical substance as manulacturl'd for commercial purpose. Provide the CAS Registry Number ifavailable. Ifthere are unidcntitkxl impurities. cnter"'unidentifil'd
... Estimate the maximum ofeach estimatetheirtotal %. Maximum



# 0 Mark (X) this box ifyou attach a continuation sheet. 5. Trade identification- List trade names for the new chemical substance identitil'd in subsection I or2. 

# 0 Mark (X) this box ifyou attach a continuation sheet. 6. Generic chemical name - Ifyou claim chemical identitY as confidential, you must provide a generic name for your substance that reveals the specific chemical identity ofthe new chemical substanceto the maximum extent possible. Referto the TSCA Chemical Substance Inventory, 1985 Edition, Appendix Bfor guidance on developing generic names.

Mark (X) this box if attach a continuation sheet. percent %
% %
% % % % Contidential



### X

Contidential

7. Byproducts- Desc1ibe any byproducts resulting from the manufacture. processing. use, or substance. Provide the CAS Registry Number ifavailable. CAS Reg Number

EPA FORM 7710-25 (Rev. 5-95) Page6

### p.8 Mark (X) the "Confidential" box next to any item you claim as confidential. 1. 

### Production volume- Estimate the maximum production volume during the first 12 months ofproduction. Also estimate the maximum production volume for any consecutive 12-month period during the first three years ofproduction. Estimates should be on 100% 

### new chemical substance basis. For a Low Volume Exemption application, ifyou choose to have your notice reviewed at a lower production volume than 10,000 

### kg!yr, specifY the volume and mark (x) in the binding box. Ifgranted, you are bound to this volume Maximum first 12-month production (kglyr) Maximum 12-month production (kglyr) Conti- Binding 

### (100% new chemical substance basis) 

### (100% new chemical substancebasis) dential Option Mark (x) 

## X 2. Use Information-- You must make separate confidentiality claims for the description ofthe category ofuse, the percent ofproduction volume devoted to each category, the formulation of the new substance, and other use information. Mark (X)

### the ··confidential'' Box next to any item you claim as confidential. a. (I)-- 

### Describe each intended category ofuse ofthe new chemical substance by function and application
.. (2)
-- Mark (X) 

### this column ifentry column (I) 

### is confidential business information (CBI). (3)
-- 

### Indicate your willingness to have the information provided in column (I)

### binding. (4) -- 

### Estimate the percent oftotal production for the first three years devoted to each category ofuse. (5)
-- 

### Mark (X)

### this column ifentry in column (4) 

### is confidential business information (CBI). (6) -- 

### Estimate the percent ofthe new substance as formulated in mixtures, suspensions, emulsions, solutions, orgels as manufactured for commercial purposes at sites under your control associated with each category ofuse. (7)
-- 

### Mark (X)

### this column ifentry in column (6) 

### is confidential business information (CBI). (8) -- 

### Indicate % 

### ofproduct volume expected for the listed ''use" sectors. Mark more than one box ifappropriate. Mark (X) 

### to indicate your willingness to have the use type provided in (8) 

### binding. (9) -- 

### Mark (X)

### this column ifentry(ies) in column (8) 

### is (are) confidential business information I

### CBI). Categoryofuse (l) CBI Binding 

### Produc- CBI %in CBI %ofsubstanceexpected peruse CBI Option 

### tion% Form- (8) 

### (by function and application i.e. adispersive dye Mark(x) 

### ulation Site- Con-* Indus- Com- Binding (3) 

### for finishing polyesterfibers) (2) (4) (5) (6) (7) 

### limited sumer trial mercia! Option j9) 

### X X X X % % % Of. % % % % % % % % % % 

### * Ifyou have identified a"consumer" use, please provide on acontinuation sheet adetailed description ofthe use(s) ofthis chemical substance in consumerproducts.

In addition include estimates ofthe concentration ofthe new chemical substance as expected in consumerproducts and describe the chemical reactions by which this substance loses its identity in the consumerproduct. 0Mark (X)

### this box ifyou attach acontinuation sheet. b. Generic Ifyou claim any category ofuse description in subsection 2aas confidential, enterageneric description ofthatcategory. Read the use Instructions Manual forexamples ofgeneric use descriptions. description 

### Contained use in energy production
.. 

# D Mark (X)

### this box ifyou attach acontinuation sheet. 3. 

### Hazard Information

-- Include in the notice acopy ofreasonable facsimile ofany hazard \\aming statement. label. material safety data sheet. or other Binding



### information \\hich \\ill be provided to any person who is reasonabl} likely to be exposed to this substance regarding protectiveequipmentorpractices

**Op1i~.o1n** 

### for the safe handing. transport use. ordisposal ofthe new substance. List in part III 

### hazard information you include. \larl (x) 

# D Mark (X)

### this box if}OU attach hazard infom1ation. 

## Part 11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Section A-- INDUSTRIAL SITES CONTROLLED BY THE SUBMITTER Mark (X)

### the
..Confidential
.. box nextto any ih:m )OU EPA 

### FORM 7710-25 (Rev. 5-95) 

### Page 7 

# • claim as contidential

### p.9 Complete section A for each type manufacture. processing. oruse operation the new chemical substance at industrial sites you control. Importers do not have to complete this section for operations outside the U.S.; however. you may still have reporting requirements if there are further industrial after You must describe these s. See instructions manual I.

Ifthe same operation will occur at more than one site, enter the number ofsites. Identify the

additional sites on a continuation sheet, and ifany ofthe sites have significantly different production rates or operations, include all the information requested in this section for those sites as attachments.

2. Continuous Batches/year Confidential



# .X

X X

d. Process description Mark (X) to indicate your willingness to have your process description binding. 

# X (I) Diagram the major unit operation steps and chemical conversions. Include interim storage and transport containers (specifY- e.g. 5gallon pails, 55 gallon drum, rail car. tank truck, etc.). (2) Provide the identity, the approximate weight (by kg/day orkg/batch on a 100% new chemical substance basis). and entry point ofall starting materials and feedstocks (including reactants, solvents, catalysts, etc.), and ofall products, recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily orper batch.). (3) Identity by number the points ofrelease, including small or intermittent releases, to the environment ofthe new chemical substance.

EPA FORM 7710-25 (Rev 5-95) Page 8

# . D.1Q 2. Occupational Exposure-- You must make separate confidentiality claims for the description ofworker activity. physical form ofthe new chemical substance. numberofworks exposed. and duration ofactivity. Mark (X} the
..Confidential" box next to any item you claim as confidential. (I) --Describethe activities (i.e. bag dumping, tote filling, unloading drums. sampling, cleaning. etc.) in which workers may be exposed to the substance. (2) --Mark (X) this column ifentry in column (I) is confidential business information (CBI). (3} --Describe any protective equipment and engineering controls used to protect workers. (4) and (6) --Indicate your willingness to have the information provided in column (3) or (5) binding. (5) --Indicate the physical form(s) ofthe new chemical substance (e.g
.. solid: crystal, granule. powder. or dust) and% new chemical substance (ifpart ofa mixture) at the time ofexposure. (7) --Mark (X} this column ifentry in column (5) is confidential business information (CBI). (8) --Estimatethe maximum number ofworkers involved in each activity for all sites combined. (9} --Mark (X) this column ifentry in column (8) is confidential business information (CBI). (I0) and (II)-- Estimate the maximum duration ofthe activity for any worker in hours per day and days per year. (12)

-- Mark (X) this columnifentries in columns (I0) and (II) are confidential business information (CBI). Worker activity CBI Protective Equipment/ Binding Physical forms(s) Binding CBI #of CBI Maximu duration CBI m (i.e
.. bag dumping, filling drums) Engineering Controls Option and 0 /0 new Option Workers Hrs/day Days/yr Mark(x) substance Mark(x) Exposed (I) (2) (3) (4) (5) (6) (7) (8) (9) (10) (II) (12) 

### X

[ ] Mark (X) this box ifyou attach a continuation sheet. 3. Environmental Release and Disposal-- You must make separate confidentiality claims for the release number and the amount ofthe new chemical substance released and other release and disposal information. Mark (X) the ··confidential" box next to each item you claim as confidential. (I) --Enterthe number ofeach release point identified in the process description, part II, section A, subsection Id(3). (2) --Estimate the amount ofthe new substance released (a) directly to the environmentor (b) into control technology (in kg/day or kg/batch). (3) --Mark (X) this column ifentries in columns (I) and (2) are confidential business information (CBI). (4) --Identify the media (stack air, fugitive air (optional-see Instruction Manual). surface water, on-site or off-site land or incineration, POTW, or other (specify)) to which the new substance will be released from that release point. (5) --a. Describe control technology, ifany, and control efficiency that will be used to limit the release ofthe new substance tothe environment. For releases disposed ofon land, characterize the disposal method and state whether it is approved for disposal ofRCRA hazardous waste. On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to secondary or tertiary on-site treatment. b. Estimate the amount released to the environment after control technology (in kg/day). (6) --Mark (X) this column ifentries in columns (4) and (5) are confidential business information (CBI). (7) --Identify the destination(s) ofreleases to water. Please supply NPDES (National Pollutant Discharge Elimination System) numbers for direct discharges or NPDES numbers ofthe POTW (Publici Owned Treatment Works). Mark (X) ifthe POTW name orNPDES #is confidential business information (CBI). Release Amount ofnew substance CBI Media of Control technology and efficiency (you may wish to optionally attach efficiency data) CBI Number released release

(I) (2a) (2b) c g. stackaar Binding (3) (4) (Sa) Mark(X) (5b) (6) 

### X

(7) Mark (X) the 

# D POTW provide name(s) below: CBI [] Navigable 

# D Other- Specify provide NPDES # CBI dcstination(s) of 

# r--x- waterway 

### X releases to water.



# J Mark (X) this box ifyou attach a continuation sheet.

EPA**FOR~** 7710-25 (Rev 5-95) Page 9

### p. 11 

## Part11-- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE-- Continued Section B -- INDUSTRIAL SITES CONTROLLED BY OTHERS Complete section Bfortypical processing or use operations involving the new chemical substance at sites you do not control. Importers do not have to complete this section for operations outside the U.S.; however, you must report any processing oruse activities after import. See the Instructions Manual. Complete a separate section B for each type of processing. or use operation involving the newchemicalsubstance. Ifthe same operation is performed at more than one site describe the typical operation common to these sites. Identifv additional sites on acontinuation sheet. 1. Operation Description --To claim information in thissection as confidential, circle orbracket the specific information thatyou claim as confidential. (I)-- Diagram the major unit operation steps and chemical conversions. including interim storage and transport containers (specify- e.g. 5gallon pails. 55 gallon drums. rail cars, tank trucks. etc). On the diagram. identify by letter and briefly describe each worker activity. (2) --Provide the identity, the approximate weight (by kg/day orkg/batch, on an I00% new chemical substancebasis), and entry point ofall feedstocks (including reactants, solvents and catalysts, etc) and all products. recycle streams, and wastes. Include cleaning chemicals (note frequency ifnot used daily or perbatch). (3)
-- IdentifY by number the points ofrelease, including small or intermittent releases, to the environment ofthe new chemical substance. (4) Please enter the# ofsites (remember to identifY the locations of these sites on acontinuation sheet):
#ofsites



## [X] CBI 

# D Mark (X) this box ifyou attach acontinuation sheet. 2. Worker Exposure/Environmental Release (I) --From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. (2) --Estimatethe numberofworkers exposed for all sites combined. (4) --Estimatethe typical duration ofexposure perworker in (a) hours per day and (b) days per year. (6) --Describe physical form ofexposure and%new chemical substance (ifin mixture), and any protective equipment and engineering controls. ifany, used to protect workers. (7) --Estimatethe percent ofthe new substance as formulated when packaged orused as afinal product. (9) --From the process diagram above, enter the number ofeach release point. Complete 9-13 for each release point identified. (I0)
-- Estimate the amount ofthe new substance released (a) directly to the environment or (b) into control technology to the environment (in kg/day or kg/batch). (12) --Describe media ofrelease i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site oroff-site land or incineration, POTW, or other (specify) and control technology, ifany, that will be used to limit the release ofthe new substance to the environment. (14) --Identify byproducts which may result from the operation.

(3}, (5), (8). (I 1), (13) and (15) --Mark (X) this column ifany ofthe proceeding entries are confidential business information (CBO. Letter #of CBI Duration CBI Protective Equip. I

**~~in** CBI Release Amount of CBI Media ofRelease CBI

of Workers of Engineering Controls/ Fonn- Number New & Control Act- Exposed Exposure Physical Form and % ulation Substance Technology ivity new substance Released (I) (2) (J) (4a) (4b) (5) (6) (7) (8) (9) (lOa) (JOb) (II) (12) (13) 

### X

14)
-- Byproducts: (15) 

# D Mark (X)this box if)OU attach 

### acontinuation sheet. EPA fORM 7710-25 (R.:v. 5-95) Page 10

### p.12 

# OPTIONALPOLLUTION PREVENTIONINFORMATION To claim information in this section as confidential circle or bracket the specific information that you claim as confidential. 

## Inthis section you may provide information notreported elsewhere in this form regarding your efforts to reduce orminimizepotential risks associated with activities surrounding manufacturing, processing, use and disposal ofthe PMN substance. Please include new informationpertinent to pollutionprevention, including source reduction, recycling activities and saferprocesses orproducts available due to the new chemical substance. Sourcereduction includesthe reduction in the amount ortoxicity ofchemical wastes by technological modification, process and procedure modification, product reformulation, rawmaterials substitution, and/or inventory control. Recycling refers to the reclamation ofuseful chemical components from wastes that would otherwise be treated orreleased as air emissions orwater discharges, orland disposal. Descriptions ofpollution prevention, source reduction and recycling should emphasize potential risk reduction subsequentto compliance withexisting regulatory requirements and can be either quantitative orqualitative. The EPA is interested in the information to assess overall netreductions in toxicity orenvironmental releases and exposures, not the shifting ofrisks to otherenvironmental media or non-environmental areas (e.g., occupational orconsumer exposure). In addition, information onthe relative costorperformance characteristics ofthe PMN substance to potential alternatives may be provided. 

## All information provided in this section will be taken into consideration during the review ofthis substance. See Instructions Manual and Pollution Prevention Guidance manualfor guidance and examples. Describe the expected net benefits, such as (I)

### an overall reduction in risk to human health orthe environment; (2) a reduction in the volume manufactured; (3) a reduction in the generation ofwaste materials through recycling, source reduction orother means; (4) a reduction in potential toxicity orhuman exposure and/or environmental release; (5) an increase in productperformance, a decrease in the cost ofproduction and/or improved operation efficiency ofthe new chemical substance in comparison to existing chemical substances used in similarapplication; or(6) the extent to which the new chemical substance may be a substitute for an existing substance that poses a greater overall risk to human health orthe environment.



# D Mark (X) this box ifyou attach a continuation sheet. EPA FORM 7710-25 (R.:v 5-95) Page II

### p.13 

# Part III-- LIST OF ATTACHMENTS Attach continuation sheets for sections ofthe fonn and test data and otherdata (including physical/chemical properties and structure/activity information), and optional infonnation after this page. Clearly identify the attachment and the section ofthe fonn to which it relates, ifappropriate. Number consecutively the pages ofthe attachments. In the column below, enter the inclusive page numbers ofeach attachment. Mark (X) the '·Confidential"' box next to any attachment name you claim as confidential. Read the Instructions Manual for guidance on how to claim any information in an attachment as confidential. You must include with the sanitized copy ofthe notice form a sanitized version ofany attachment in which you claim information as confidential. Attachment name Attachment Contipagenumber(s) dential 

### Material Safetv Data Sheet (MSDS) 

### Letter ofAuthorization 14

[ ] Mark (X)

### this box 

### ifyou attach acontinuation sheet. Enterthe attachment name and number. EPA FORM 7710-25 

### (Rev 5-95) 

### Page 12

### p.14 PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET To assist EPA·s review ofphysical and chemical properties data. please complete the following worksheet for data you provide and include it in the notice. IdentifY the property measured. the page ofthe notice on which the property appears. the value ofthe property. the units in which the property is measured (as necessary), and whether ornot the property is claimed as confidential. The physical state ofthe neat substance should be provided. These measured properties should be for the neat (I00% pure) chemical substance. Properties that are measured for mixtures or formulations should be so noted (% PMN substance in _). You are notrequired to submitthis worksheet; however, EPA strongly recommends that you do so. as it will simplifY review and ensure that confidential information is properly protected. You should submitthis worksheet as a supplement to your submission oftest data. This worksheet is not asubstitute for submission oftest data. Property

(a) 

### Physical state ofneat substance Vaporpressure @Temperature 

# oc Density/relative density Solubility 

### @ Temperature 

# oc

Solvent Solubility in water@Temperature 

# oc Meltingtemperature Boiling 

### I sublimation temperature@ torr pressure Spectra Dissociation constant Particle size distribution Octanol 

### I waterpartit.ion coefficient Henry's Law constant Volitalization from water Volitalization from soil _l)_H@_concentration Flammability ExQiodability_ Adsorption I 

### coefficient Other

- Specify Mark Page Value (X) if number provided (b) (c) 

### (s) (I) 

### (g)
Torr glcm3



### giL giL 

# oc oc Measured o Conti· Estimate dential Mark(X) (MorE) (d)



### ATTACHMENT PAGE 13.. II '
.. 

# .

# .

U.S. Environmental Protection Agency New Chemicals Branch OPPT Document Control Office(7407M) 1200 Pennsylvania Avenue Washington, D.C. 20460 Dear Ladies and Gentlemen: June 19, 2008

has advised us that it intendsto submit a significant newuse notice (SNUN) for
. p.15



## which is the subject ofPremanufactureNotice (PMN) ,a Consent OrderetTective December4, 1998, a significant new use rule (SNUR) at , and a Modified Consent Orderdated October 18, 2002. We understand that a revised SNURreflecting the Modified Consent Order is being prepared, but has not yet beenpublished. The original PMN was submitted by our affiliate,
,. which also was a party to the original Consent Order. assigned the Consent Order to us and we submitted the assignment to Lorraine Passe ofthe EPA'sNew Chemicals Branch by letter dated June 1, 2004. We hereby authorize the EPA to reference all information submitted in connection with PMN , including information submitted to obtain the Modified Consent Order, in the EPA's review ofthe SNUN to be submittedby Some ofthe information submitted in support ofthe PMN was confidential business information (CBI). The CBI should be used and referenced only by the EPA. Sincerely,

Department

**~tanager**



## An affiliate of92b12757385 

### p.16 06:25:34 a.m. 07-24-2008 16/29



## July 24, 2008 

# COMPAf.RI
. 

# ,.,' SANITIZED Ms. Tracey Pennington, Program Manager Office ofPollution Prevention and Toxics (7405M) U.S. Environmental Protection Agency Fax#: 202-564-9490 Subject: SNUN S-08-0007 (TSCA User FeeTS-08JB2W) DearMs. Pennington, 

# -
As you requested ofme yesterday afternoon, accompanying this fax please find the currentMSDS (sanitized and un-sanitized) forthis SNUN substancefrom the supplier we will be purchasing from once this SNUN and PMN review periods expire and we are able to commence commercial manufacture ofthe PMN substance P-08-0501 whichuses this SNlJN substance. Iam also includingrevised PMN pages 1and 12 for the sanitized andun-sanitzed versions ofthis SNUN to showthe increase in the number ofpages inthe SNUN and showing this MSDS as an attachment to the SNUN. IfIcan be ofany further assistance please feel free to call me directly at 281-275-7471 or e-mail me at michael.curl@bakerpetrolite.com. Sincerely,



# II~'JP~~~J~P,I!~~~

**~o<g-** 

# oo192812757385 06.25.42 a.m. 07-24-2008 

### p.17 17/29 

### U.S. ENVIRONMENTAL PROTECTION AGENCY 

# EPA PREMANUFACTURE NOTICE

GENERAL INSTRUCTIONS You mustprovide all infonnation requested in this form tothe extentthat it is known to orreasonably ascertainableby you. Makereasonable estimates not have actual data.

. ...

**~·** Beforeyou completethisfonn, you should read the "Instructions Manual for Premanufacture Notification" (the Instructions Manual is availablefrom the Toxic Substances Control Act (TSCA) Infonnation Serviceby calling202-554-1404, or fux.ing 202-554-5603).

- Ifa userfee has been remitted for this notice (40 CFR 700.45), indicate in the boxes abovetheTS-user fee identification numberyou havegenerated. Rcmembet, your userfee ID numbermust alsoappear on yourcorresponding fee remittance,

**~ich** is sentto EPA, HQ Accounting OperationsBranch {PM-226), P.O. 360399M,Pittsburgh, PA 15251-6399, Attn. TSCA Userfee. PartI-GENERALINFORMATION Y

oo must provide the currently COITeCt Chemical Abstracts (CA) Name ofthe new chemical substance, even ifyou claim the identityas confidential. You may authorile anotherperson to submitchemical identity information for you, but your submission will not becomplete and the reviewwill not begin until EPA receives this information. A letterin supportofyour submission should reference yourTS user fcc identification number. You must submit an original and two copies ofthis notice including alltCSI data. Ifyou claimedany informationas confidential. a single sanitizedcopy must also be submitted. Part D- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE Ifthere arc several manufacture, processing, orusc operations to be described inPart II, sections Aand Bofthis notice, reproduce the sections as needed. Part III-LIST OF ATTACHMENTS Attach additional sheets ifthere is notenough space to answer aquestionfully. Label each continuation sbeetwith the c<XTCSponding sectionheading. In Part III,list these attachments, anytest data orotherdata and any optional information included in the notice.
OPTIONAL INFORMATION You may include any info110ationthatyou want EPA toconsider in evaluating the new substance. Onpage II ofthis form, space has beenprovided for you to described pollutionprevention andrecycling informationyou may haveregardingthe new substance. So-called "binding"boxes are included throughoutthis form for youto indicateyour willingness to beboundto certain statementsyou make in this section, such as use, production volume. protective equipment . . . This option is intendedto reduce delays thatroutinely accompany the development ofconsent orders orSignificantNew Use Rules. Except in the case ofexemption applications (such as TMEA, L VE, LOREX) where certain info11nationprovided in suchnotification is binding onthe subminerwhen the Agency approves the exemption application, checking abindingbox in this notice

**~by**itselfprohibit the subminerfrom laterdeviating from the infonnation

**(e~cept** chemical identity) reported inthe form. CONFIDENTIALITY CLAIMS You may claim any information in this notice as confidential. To assert aclaim on the form, mark (X) the confidential box nextto the info110ationthat you claim as confidential. To assert aclaim in an attachment, circle orbracket the information you claim as confidential. Jfvouclaim info11nation in tbe ootices as conli!lentia! yoo must alsoprovide a sanitized ymionofthe notjce Cineluding attachments>. Foradditional instructions on claiming information as confidential, readthe Instructions Manual. 

# 0 Mark (x) ifany information in this notice is claimedas confidential. EPA FORM 7710-25 (Rev. 5-95) TEST DATA AND OTHER DATA You are required to submitall testdata inyourpossession orcontrol and to provide adescription ofall otherdataknown to orreasonably ascertainable by you, ifthese data are related 10the healthand environmental effects onthe manufacture, processing, distribution incommerce, use, ordisposal ofthenew chemical substance. Standard literaturecitations maybesubmitted for data inthe open scientific literature. Complete testdata(written in English) not swnmaries ofdata. must beSUbmitted ifthevdo notappear in the open lilerature. You should clearly identitY whethertestdatais onthe substanceoronan analog. Also, the chemical composition ofthetestedmaterial should be characterized. Following arc examples oftestdata and otherdata. Data should he submitted accordingto the requirements of§720.50 ofthe Premanulilcture Notification Rule (40CFR Part 720)

Test Data (Check Below any included in this notice) Environmental fate data Health effects data Environmental effects data 0 Yes 

### 0 Yes 

### D Yes PhysicaVCbemicalProperties• 

### D Yes Otherdata D Yes Risk assessments Structure/activityrelationships TCSI data not in thepossession orcontrol ofthe submitter • Aphysical and chemical properties worksheet is located on the last page ofthis form. TYPE OFNOTICE (Check Only One) 

# D D

**~** 

# D PMN (!'remanufacture Notice) INTERMEDIATE PMN (submined in sequence with final product PMN) SNUN (Significant New Use Notice) TMEA (Test Marketing Exemption Application) 

# 0 LVE(Low Volume Exemption)@ 40CFR 723.50(c)(l) 

# 0 LOREX (Low Release/Low Exposure Exemption)@ 40 CFR 723.50(c)(2) 

# D L VE Modification IS TIUS ACONSOLIDA TED PMN? # ofchemicals 

# D 

# D LOREX Modification Yes (Prenotice Communication #required, enter# on page 3) Replaces previouseditions ofEPA Fonn 1710-25.

### p.18 92tl12757385 06:26:08 a.m. 07-24-2008 18/29 

# PartIII-- LIST OFATTACHMENTS Attach continuation sheets for sections ofthe fonn and test data and otherdata (including physical/chemical propenies and structure/activity infonnation), and optional infonnation afterthis page. Clearly identify the attachmentand the section ofthefonn to which itrelates, ifappropriate. Numberconsecutively the pages ofthe attachments. In the column below, enterthe inclusivepage numbers ofeach attachment. Mark (X) the "Confidential" box nextto any attachmentname you claim 

### as confidential. Readthe Instructions Manual forguidanceon how to claim any infonnation in an attachment

### as confidential. You must include with the sanitized copy ofthe noticefonn asanitized version ofany attachment in whichyou claim infonnation 

### as confidential. Attachmentname Attachment Conti·

**~enumbe~}** dential 

### 15-25 Material SafetvData SheetlMSDS) 

### LetterofAuthorization 14



## j ] Mark (X) lhisbox ifyou attach acontinuation sheet. Enterlhe attachmentname andnumber. EPA FORM 7710-25 (Rev. 5-95) Page 1292ll12757385

·-._. 

### p.19 06:2617am. 07-24-2008 19/29 

### Supplier and Prep.-ar of thia MS DS :
Telephone 

### Fax 

# Acryloxl Morpho Iina· Material Safety Data Sheet Section 

### 1: Chamic11 Product and Company Identification Identity Acrytoyl Morpholine (A 

### CMO) Popular Name ACMO Chemical Name **Morpholine~4·(1-oxo--2-propenyl)·** 

### Chemical Formula C 7 

### H 11 

### NO,


## cA

## s(Chemical Abstract 5117-12-4 

### Service)Number Manufacturer's Name Manufacturer's Address Emergency Telephone 1-800-424-9300(C H EMT R EC, 

## u. 

# s. A. ) Number Information Telephone -· 

### Number .. 

# . 

# . . Date Prepared September 21 I 

### 2006 Section 2: Hazardous Ingredients/Identity Information Component: ACMO does not contain other hazardous ingredients.

Page 1 of 1 1 September 21 1 

### 2006 Acryloyl Morpholine**9~12757385**



### . 

# ._,



# .._.

.......... 06 26:25 a.m. 07-24-2008


### Section 3· Haz•dous /Identification Appearance Routes of Exposure Permluible Exposure Limits Target Organs Signs and Symptoms of Exposure

Medical conditions generally known to be aggravated 

### by exposure 

### to the material Health Hazards

Carcinogenicity Clear and low odor liquid. inhalation, contact With 

### skin or eyes, ingestion OSHA Permissible Exposure limit: None established ACGIH ThreShold limit Value: None established Skin, eyes, 

### mucous membranes, liver, respiratory system Eye irritation The inhalation of high vapor concentration may cause a headache And nausea. No applicable information found.

Acute oral toxicity LD 110

# =588mg/kg(rats) Acute dermal toxicity LD I o= 

### No leas than 2.0g/kg(rata) 

### Acute inhalation toxicity LC 110

## = No less than 5.28 mgll 

### (rats,1 and 

### 4 hour) 13-week Oral toxicity [OECD 408) NOEL=20mglkg/day(rats) Reproduction/developmental toxicity screening test (OECD 422) NOEL::75mg/kg/day(rats) Neurotoxicity screening 

### battery [EPA OPPTS 870.6200] NOEL::75mglkg/day(rats) 13-week Inhalation toxicity [OECD 413) NOEL<0.0124mg/Uday(rata) Primary Irritation lndex(PII)= 0.5 Mutageniclty{Bacteriologlcal 

### test): negative Mouse micronucleus test(Non-bacteriologlcal test In vivo):negative NOTE: ACMO 

### Is a new Chemical substance that has not yet been fully tested according to the EPA regulations under the Toxic Substances Control Act. Therefore user should assume that ACMO may cause internal organ effects, reproductive effects. National Toxicology Program(N T P):Not listed NT P Annual Report on Carcinogens, 7th Ed.:Not listed International Agency for Research on Cancer, Monographs: No OSHA Regulated(29 C.F.R 11910 Subpart Z):No 

# liD Page2 of 1 1 

### September 21 , 2006

Acryloyl Morpholine 

### p. 2

## 9ot2992"812757385 

### p.21 06:26 39 a.m. 07-24-2008 21 /29 

### Section 

### 4" First Aid Measures Emergency and First Ald 

### Procedures

Eye Contact

Skin Contact:

Ingeation(swallowed):

Inhalation: CALL A POISON CENTER OR A PHYSICIAN IMMEDIATELY 

### If a knoWn 

### exposure occurs or If a poisoning is suspected, do not wait 

### for symptoms to develop. Immediately start 

### the recommended procedures below and simultaneous ly contact a poison center, a physician, and/or the nearest hospital. Inform the person contacted of the extent of exposure, describe the victim's symptoms and follow the advice given. Immediately 

### wash eyes with running water for 15 minutes. Consult 

## a physician. 

### Do not apply oil or oily ointments unless ordered by 

### a physiCian. Immediately 

### wash skin with plenty of water. Remove contaminated clothes. If 

### irritation develops, consult 

### a physician. Dilute 

### with water by giving glasses of water to the victim, 

### then induce vomiting by sticking finger down the victim's throat Do not make an unconscious person vomit 

### Get medical attention Immediately. Remove the victim 

## to fresh air. Get medical attention immediately. If the victim Is not breathing, clear victim's airway and start mouth-to-mouth artificial 

### respiration, which may 

### be supplemented 

### by the use of a bag-mask 

## or other N 

### J 0 S H 

### approved respirator or manually triggered oxygen supply capable of delivering 

## one liter 

### per second or more. If the victim Is breathing, supplemental oxygen may be given from a demand-type or continuous-flow inhaler, preferably with a physician's advice.



# ll Page 3 of 

### 1 1 September 21
. 2006

Acryloyl Morpholine92'812757385 06.26.50 a.m. 07-24-2008 

### Section 5· Fire and Explosion 

### Hazard Data Flash Point 250.7'F, 126.5'C (using the Pensky-Martens Closed Tester 

### method) Flammable Limits Lowest Limit (Q80'C, 200Torr): 2.5% Highest Limit (@100'C, 200Torr): 25.0% Extinguishing Media water spray, dry chemical powder, carbon dioxide, foam Special Fire Fighting Wear self-contaminated breathing apparatus and protective clothing Procedures to prevent contact with skin and

**~es.** 

### Unusual Fire 

### and Sealed contafners 

### may rupture explosively if heated. 

## Keep any 

### driftS Explosion 

### Hazards 

## or containers 

## cool 

## with water spray while fightina any fire. Containers that rupture explosively may autolgnite. Autolgnitlon Temperature 452.3'F, 233.5'C

Section 

## 8: Accidental Rei••• M8Murea Small Quantities 

### Large Quantities Take up with an absorbent material and place Into non-leaking containers. Seal tightly 

### for property disposal with other hazardous wastes. Collect the product and place Into non-leaking containers in order to isolate from 

### woril:ers and environment 

### Properly dispose 

### by transportation to a 

### permitted disposal facility for disposal as a hazardous 

### waste by Incineration 

### or landfill in compliance 

### with federal, 

### state, and 

### local regulations. Do not dispose to sewers, lakes, rivers or streams.



# ti Page 4 of 

### 1 1 September 21 , 2006

Acryloyl Morpholine 

### p.22 22/2992'812757385 06:27 03 a.m. 07-24-2008 

### Section 7: Handling, 

### Storat;

# e. and Disposal Precautions

Protective Clothing and 

### Respirator Equipment Each person who Is reasonably likely 

### to be 

### dermally exposed 

### to ACMO through direct handling of the substance 

### or because the substance 

### becomes airboma as vapor, should wear the following personal protective equipment that selected in accordance with 29 CER 1910.132 

### through 29 

### CFR 1910.138. Also. ACMO 

### should not be 

### used In non-closed systems. (1)Gioves:

Gloves that 

### provides an Impervious barrier to prevent dermal expoaure ·When each 

### person Is reasonably likely to be exposed 

## to 100%ACMO,



### gloves in the following specification should be 

### wom. Material 

### Use restriction time in hours 

### Safety 414H EVOHIPE laminate : 8.0 Ansell Edmont Neoprene 

### 'I 865 : 6.5



## ...**$.o.'Y~**

## ..

## Nitrtlet
. .Rutltlt.(
...

**~** 

## ..

**'I.7.~**

## ...•...

**~**

## .........................

**~** 

## •. Q

........................... •When eaCh person is reasonably likely 

### to be 

### exposed 

### to mixtures

containing ACMO, gloves meeting ASTM test F739-96 and F1194-89 should be wom. Glove 

### permeability 

### test data must be submitted to EPA and 

### approved for each new mixture that will 

### be used (except for research and development) within one year after commencement of 

### commercial use. Please contact for further information in glove 

## test requirements. (2)Ciothing:

Clothing which covers 

### any other exposed areas of the arms, legs and 

## torso (3)Respirator: • NIOSH approved respirator Category 23C or Category 19C 

### Type 

# c

in 

### compliance with 

### OSHA



## t'\ Page 5 of 1 1 

### September 21 , 2006

Acryloyl Morpholine92812757385 06 27:13 a.m. 07-24-2008


### Sec tlon 7: Handling, Stor.!Mle. and

**Dl~osal** 

### Precautions Storage and Handling Precautions

Waste Disposal Method



## '-' •Store drums inside a warehouse and where air is available. • Store drums at temperatures under 9 5• F,3 5•

## c. ·Supply water through Insulated and heat-traced lines to prevent

freeze-up In cold weather. 

### •Oo not store drums near sources of heat or fire or in direct sunlight. 

### •Oo not heat drums with 

### steam or electrical equipment. 

### •Do not store drums In more than 

## two layers and 

## two lines in groups



### of 48 drums. Have aisle of fourteen (14) feet minimum on all sides.

•Place into non-leaking containers and seal tightly. Transport

the 

### material to a permitted facility for proper disposal by incineration or landfill 

### with other hazardous wastes in accordance with 

### federal, state and local regulations. • Do 

### not discharge this product into sewers, rivers, lakes or streams. N

# oT E : State and local regulations may be more stringent than federal regulations.



# ?o Page 

# e of 

### 1 1 

### September 21 , 2006 Acryloyl Morpholine 

### p.24 24/2992812757385 06.27.20 a.m. 07-24-2008


### Secf 8 Ex 

## t UPera al P 

## t f I

### On 

# . (posure con ro on ro ec 1on General requirement 

# '._
Signs and Symptoms of Exposure
Precautions 

## to Avoid Ingestion
Precautions to Avoid Skin Contact
Precautions to Avoid Eye Contact
Precautions to Avoid Inhalation Use ACMO in enclosed equipment such as closed-top blending tanks and 

### enclosed UV 

### or EB 

### curing equipment Any potential exposure should be limited 

## to Incidental exposure during container filling and pouring and 

### roll application and cleaning activities. Signs or symptoms of exposure include odors ancl eye, skin or respiratory irritation. However, exposure should 

### be 

### avoided even in the absence of signs or symptom•. Keep all food in area separate from storage and use locations. Prohibit eating, drinking and smoking in areas where there is 

## a potential for 

### significant exposure to this material. Thoroughly wash hands and face 

### before eating_. Use 

### impervious clothing and gloves. and footwear selected with regard use-condition-exposure potential. Provide an eye walh and an emergency 

### safety shower in 

### all areas where this material is handled or stored. 

### See Section 

### 7. Use goggles and 

## a face shield selected with regard to usecondition-exposure potential. Provide eye-wash fountains or other means of washing the eyes 

### with a genUe flow of 

## tap water in all areas wheret his material Is handled or stored. Store and handle this material in well ventilated areas. NIOSH approved respirator Category 23C 

### or Category 19C Type 

### C In 

### compliance with OSHA should be 

### wom when workers are 

### reasonably likely to 

### be exposed.

Page 7 

### of 1 1 

### September 21 • 2006



### Acryloyl Morpholine 

### p. 25 25/2992812757385


### Section 9: 

### Physical and Chemical Propertlea



# . 

# ,_ Appearance Odor Boiling Point(01 atm) Freezing 

### Temperature Vapor Pressure(mmHg @ 

### 25' C} 

### Vapor Density Relative Density(04 2 0 ) 

### Evaporation Rate(

### Butyl Acetate=1) Viscosity Solubility in Water Partition Coefficient Hygroscoprcity 

### p.26 06:27 31 a.m. 07-24-2008 26/29



### clear and colorless liquid above -8' 

# c Low 

### 471' F I 

### 244'

# c 17.6' F, -8' C 

### 7.73x1o-:s 

## 4.9 1.1185 

### 0.02 12C.I).S.(at 77' F) 

### Soluble In water and 

### other ordinary organic solvents. Log P 

# =.0.46 

## at 20.5' C 1.8g/100g(at 20' C SORH%)



### Page 8 

### of 1 1 

### September 21 , 2006

Aayloyl 

### Morphollne

### p.27 92812757385 06:27 38 a.m. 07-24-2008 27/29 

### Section 10: 

### Stability and 

### Reactivity

Chemical Stability This product is stable when propef'ly inhibited and stored under 95" F in the dartc. cool place where a gas mixture of 5-2196 oxygen exists. Condition 

## to Avoid This product may become unstable when subjected to temperatures above 95' F,light 

### or polymerization catalylta. 

## Do not mix with other chemieals or purge 

### with Inert gas. Keep 

### away from 

### peroxides or other catalysts 

### as this chemical may autoignite. Do not handle In an oxygen(alr) free atmosphere since the presence 

### the oxygen is necessary for M E H Q 

### to function effectively. Avoid contamination of 

### monomer with 

### polymerized A

# cM0 

### that might be present In localized or hot stagnant areas such as dead-head pumps or 

### heated transfer 

### lines. Incompatibility with Peroxides and 

### peroxide and free-radical forming compounds(such Other Materials 

### as aldehydes, ethers, azides, etc)promote polymerization. Hazardous 

### Decomposition No applicable Information found. And Byproducts Hazardous Polymerization Hazardous polymeriZation may occur In
. when this product Is exposed 

## to temperatures above 95' F, 

### light, or polymerization catalysts such 

### as peroxides and percjxide and free radical forming compounds. Maintain the level of ME H Q 

### inhibitor at approximately 1,000 

### ppm. Do not use an inert atmosphere, but maintain at lent 10 % void volume above A

# cM

# o because the presence of alr(2196 oxygen)is required 

### for the MEHQ 

### inhibitor to 

### be effective.



## Sect I 

### f ton 11: Toxicological 

### n ormation Oral median lethal dose (LD5 0 ) 

### Dermal median lethal dose (LO 8 0) 

### Inhalation median lethal concentratlon(LDu) Primary Irritation Index Eye Irritation SensitizationfOECD406,Buehler Method] Chronic Effect Toxicologically synergistic products 

## 588 mglkg bodywelght (rats) 

### greater than 

### 2,000 mglkg bodywelght (rats) 

### !greater than 5.28 mg/1 

### (1 and 4hour, rats) 0.5 (mildly irritating to 

### rabbit skin) severely irritating No signs of skin sensitization No applicable information found No applicable information found Page 9 of 

### 1 1 

### September 21 , 

### 2006 Acryloyl Morpholine91812757385

\.

# - Secton 11: Toxlcolog.

## c n ormat on 

### I al I 

### f 13-week Oral toxicity [OECO 408) Reproduction/developmental toxicity screening 

## test [OECO 422] Neurotoxicity screening 

### battery [EPA OPPTS 870.6200] 13-week 

### Inhalation toxlcity[OECD 413] 

### Mutagenicity(Bacteriological test) 

### Mouse micronucleus test (Non-bacteriological test In vivo}: 

## p.28 06 27.51 a.m. 07-24-2008 28/29



### NOEL•20mglkg/day{rats) NOEL=75mglkglday(rats} NOEL=75mglkglday(rats)
NOEL<0.0124mg/Uday(rats) Negative Negative


## Secl E I !call f atl 

### ton 12: coogt norm 

## on

....__. The EC 110 

### value 

### foe" immobilization to 

### daJ)hnia magna 

### in water(SUCI"' as 

### lakes, rivers, 

### and streams) is 330mg/1(24hours), 

### 120mgn(48hours). Concentration of this substance aboVe 

### 120mg/l did not cause abnormalities in 

### algal growth. The ECa0

### (respiration Inhibition} value for this substance 

### with activated sewage sludge 

### Is_g_raater than 100mgl1 (three-nours). This substance Is 

### not readily biodegradable.

Section 13: Transl)ort Information Hazard Class Not regulated for transport via IMO, ICAO Not regulated for transport. USA DOT 49CFR Packing group Not applicable 

## UN/NA Not applicable identlfication number Reportable Quantity(R Q} 

### Not applicable for transport



### Page 1 0 

### ofl 1 September 21 , 2006



### Acryloyl Morpholine9:!'812757385 06 28:01 a.m. 07-24-2008 

# s 14 R lat 

### 1

**~** 

# ar

ectlon 

# . tegu ory norm ton Toxic Substance Control ACMO is authorized for sales pursuant to a voluntary consent Act(TSCA) order between and the EPA. The EPA has issued· a significant new Ult

**ry~ANUR)** 

### under

**SectionM~(2)J:#Jfili.G:iAJor** 

### Aci'YIDYI Mo ··'·

**..ak.~FR721.5185.**



### (~clOS:i 

## .o i1

**;;-u~** 

### ;hiid10iMfYTIIU:J:k C E RC LA/Superfund This chemical substance is not 

### listed, but see reporting 40 C. F.R. § 

### 117, 302 requirements for unlisb!id substances In 40 C.F.R. §§ 

### 302.5 and 302.6 S A R A/Superfund 

### This chemical substance is 

### not listed. Amendments and Reauthorization Act of 1988 S A R A

### /Section 302- This chemical substance Is not 

### listed in Appendix A or 

### B as an Extremely 

### Hazardous 

### Extremely Hazardous Substance. Substance 40C.F.R.§355 SA RA/Sectlon 311 This chemical substance Is 

### not 

### listed, but see the reporting and 312· 40 requirements In 40 C.F.R. §370.21 for reporting each hazardous C. F.R. § 370 chemical for which in MSOS Is required 

### by OSHA. SARA/Section 313· 

### This chemical substance 

### is not 

### listed. LIST OF Toxic Chemicals 40 C. F.R. 372

The information 

### in this Material Safety 

### Data Sheet relates specifically to the product designated and may not be valid for the product when used with other materials or particular processes. While believes 

### the data set forth herein are accurate. makes no warranty with respect to thereto and expressly disclaims all liability for reliance thereon. Such data are offered 

### solely for your consideration Investigation, and verification. It is the user's responsibility to determine the 

### suitability of 

### any material for a specific use and 

### to adopt safety precautions as may be 

### necessary.

Page 1 1 

### of 1 1 

### September 21 , 2006 Acryloyl Morpholine 

### p.29 29/29